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Note: This page contains sample records for the topic "mono alkyl ester" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Methods of making alkyl esters  

DOE Patents (OSTI)

A method comprising contacting an alcohol, a feed comprising one or more glycerides and equal to or greater than 2 wt % of one or more free fatty acids, and a solid acid catalyst, a nanostructured polymer catalyst, or a sulfated zirconia catalyst in one or more reactors, and recovering from the one or more reactors an effluent comprising equal to or greater than about 75 wt % alkyl ester and equal to or less than about 5 wt % glyceride.

Elliott, Brian (Wheat Ridge, CO)

2010-08-03T23:59:59.000Z

2

(2-ethylhexyl)-mono (2-ethylhexyl) ester Phosphonic acid  

Science Conference Proceedings (OSTI)

Comparison among different extractants, as (2-ethylhexyl)-mono (2-ethylhexyl) ester Phosphonic acid (P507), Secondary-octyl phenoxy acetic acid (CA-12) and  ...

3

A Detailed Chemical Kinetic Reaction Mechanism for Oxidation of Four Small Alkyl Esters in Laminar Premixed Flames  

Science Conference Proceedings (OSTI)

A detailed chemical kinetic reaction mechanism has been developed for a group of four small alkyl ester fuels, consisting of methyl formate, methyl acetate, ethyl formate and ethyl acetate. This mechanism is validated by comparisons between computed results and recently measured intermediate species mole fractions in fuel-rich, low pressure, premixed laminar flames. The model development employs a principle of similarity of functional groups in constraining the H atom abstraction and unimolecular decomposition reactions in each of these fuels. As a result, the reaction mechanism and formalism for mechanism development are suitable for extension to larger oxygenated hydrocarbon fuels, together with an improved kinetic understanding of the structure and chemical kinetics of alkyl ester fuels that can be extended to biodiesel fuels. Variations in concentrations of intermediate species levels in these flames are traced to differences in the molecular structure of the fuel molecules.

Westbrook, C K; Pitz, W J; Westmoreland, P R; Dryer, F L; Chaos, M; Osswald, P; Kohse-Hoinghaus, K; Cool, T A; Wang, J; Yang, B; Hansen, N; Kasper, T

2008-02-08T23:59:59.000Z

4

(2-ethylhexyl)-mono  

Science Conference Proceedings (OSTI)

Comparison among different extractants, as (2-ethylhexyl)-mono (2-ethylhexyl) ester Phosphonic acid (P507), Secondary-octyl phenoxy acetic acid (CA-12) and  ...

5

Alkylate  

U.S. Energy Information Administration (EIA) Indexed Site

Day) Day) Product: Alkylate Aromatics Asphalt & Road Oil Isomers Isobutane Isopentane & Isohexane Isooctane Lubricants Marketable Petroleum Coke Hydrogen Sulfur Period: Annual (as of January 1) Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Product Area 2008 2009 2010 2011 2012 2013 View History U.S. 1,260,985 1,260,923 1,248,514 1,262,443 1,246,875 1,269,361 1982-2013 PAD District 1 110,229 110,229 95,500 108,629 79,429 91,429 1982-2013 Delaware 11,729 11,729 0 11,729 11,729 11,729 1982-2013 Florida 0 0 0 0 0 0 2007-2013 Georgia 0 0 0 0 0 0 2006-2013 Maryland 0 0 0 0 0 0 2007-2013 New Jersey 40,200 40,200 36,200 37,200 37,200 37,200 1982-2013

6

Metal salts of alkyl catechol dithiophosphoric acids and oil compositions containing the salts  

Science Conference Proceedings (OSTI)

Metal salts of alkyl catechol esters of dithiophosphoric acid suitable as additives in oil compositions are disclosed in this patent. Oil compositions containing the salts of such esters show improved extreme pressure/anti-wear and anit-oxidant properties.

Yamaguchi, E.S.; Liston, T.V.

1988-03-08T23:59:59.000Z

7

PREPARATION OF ALKYL PYROPHOSPHATE EXTRACTANTS  

DOE Patents (OSTI)

A process for providing superior solvent extractants for metal recovery processes is given wherein the extractant comprises an alkyl pyrophosphoric acid ester dissolved in an organic solvent diluent. Finely divided solid P/sub 2/O/ sub 5/ is slurried in an organic solvent-diluent selected from organic solvents such as kerosene, benzene, chlorobenzene, toluene, etc. An alcohol selected from the higher alcohols having 4 to 17 carbon atoms. e.g.. hexanol-1. heptanol-3, octanol-1. 2.6-dimethyl-heptanol-4, and decanol-1, is rapidly added to the P/sub 2/O/sub 5/ slurry in the amount of about 2 moles of alcohol to 1 mole of P/sub 2/ O/sub 5/. The temperature is maintained below about 110 deg C during the course of the P/sub 2/O/sub 5/-alcohol reaction. An alkyl pyrophosphate extractant compound is formed as a consequence of the reaction process. The alkyl pyrophosphate solvent-diluent extractant phase is useful in solvent extraction metal recovery processes.

Levine, C.A.; Skiens, W.E.; Moore, G.R.

1960-08-01T23:59:59.000Z

8

Mono County geothermal activity  

SciTech Connect

Three geothermal projects have been proposed or are underway in Mono County, California. The Mammoth/Chance geothermal development project plans to construct a 10-MW geothermal binary power plant which will include 8 production and 3 injection wells. Pacific Lighting Energy Systems is also planning a 10-MW binary power plant consisting of 5 geothermal wells and up to 4 injection wells. A geothermal research project near Mammoth Lakes has spudded a well to provide a way to periodically measure temperature gradient, pressure, and chemistry of the thermal waters and to investigate the space-heating potential of the area in the vicinity of Mammoth Lakes. All three projects are briefly described.

Lyster, D.L.

1986-01-01T23:59:59.000Z

9

Solid Catalyst – Alkylation  

This is a method used to reactivate solid/liquid catalysts used in INL’s super critical process to produce alkylates. The method brings the catalyst ...

10

Stereoconvergent Amine-Directed Alkyl–Alkyl Suzuki Reactions of Unactivated Secondary Alkyl Chlorides  

E-Print Network (OSTI)

A new family of stereoconvergent cross-couplings of unactivated secondary alkyl electrophiles has been developed, specifically, arylamine-directed alkyl–alkyl Suzuki reactions. This represents the first such investigation ...

Lu, Zhe

11

Methods of making alkyl esters - Energy Innovation Portal  

... % of one or more free fatty acids, and a solid acid catalyst, a nanostructured polymer catalyst, or a sulfated zirconia catalyst in one or more reactors, ...

12

Methyl Ester Sulfonates Supplement  

Science Conference Proceedings (OSTI)

Methyl Ester Sulfonates Supplement 18509 September 2006 Supplement September 2006.pdf Chemithon 3179

13

QUANTIFICATION OF PARENT AND ALKYL POLYCYCLIC ...  

Science Conference Proceedings (OSTI)

QUANTIFICATION OF PARENT AND ALKYL POLYCYCLIC AROMATIC HYDROCARBONS IN CRUDE OIL SAMPLES USING COMPREHENSIVE ...

14

Mild Catalytic methods for Alkyl-Alkyl Bond Formation  

DOE Green Energy (OSTI)

Overview of Research Goals and Accomplishments for the Period 07/01/06 – 06/30/07: Our overall research goal is to transform the rapidly emerging synthetic chemistry involving alkyl-alkyl cross-couplings into more of a mechanism-based field so that that new, rationally-designed catalysts can be performed under energy efficient conditions. Our specific objectives for the previous year were 1) to obtain a proper electronic description of an active catalyst for alkyl-alkyl cross-coupling reactions and 2) to determine the effect of ligand structure on the rate, scope, selectivity, and functional group compatibility of C(sp3)-C(sp3) cross-coupling catalysis. We have completed both of these initial objectives and established a firm base for further studies. The specific significant achievements of the current grant period include: 1) we have performed magnetic and computational studies on (terpyridine)NiMe, an active catalyst for alkyl-alkyl cross couplings, and have discovered that the unpaired electron resides heavily on the terpyridine ligand and that the proper electronic description of this nickel complex is a Ni(II)-methyl cation bound to a reduced terpyridine ligand; 2) we have for the first time shown that alkyl halide reduction by terpyridyl nickel catalysts is substantially ligand based; 3) we have shown by isotopic labeling studies that the active catalyst (terpyridine)NiMe is not produced via a mechanism that involves the formation of methyl radicals when (TMEDA)NiMe2 is used as the catalyst precursor; 4) we have performed an extensive ligand survey for the alkyl-alkyl cross-coupling reactions and have found that electronic factors only moderately influence reactivity in the terpyridine-based catalysis and that the most dramatic effects arise from steric and solubility factors; 5) we have found that the use of bis(dialkylphosphino)methanes as ligands for nickel does not produce active catalysts for cross-coupling but rather leads to bridging hydride complexes of varying geometries; 6) we have determined that the geometry of aforementioned bridging hydride complexes is largely determined by external forces such as hydrogen bonding interactions and crystal packing forces; 7) we have found that the rate of reductive elimination of alkane from a (pyridyl-2-pyrrolide)AuMe2 complex is severely inhibited due to the rigid geometry of the pyridyl-2-pyrrolide ligand; 8) we have prepared, structurally characterized, and explored the reactivity of 1-adamantylzinc reagents as model nucleophiles for sterically challenging alkyl-alkyl cross-coupling reactions. The continued success of this work will lead to alkyl-alkyl cross-coupling catalysts with broad scope and selectivities. The work has potential to significantly impact science and technologies of interest to the DOE as the chemistry is focused on developing useful reactions using reagents that can be directly prepared from petroleum and natural gas feedstocks. Moreover, the developing synthetic chemistry can profoundly affect the way materials, fine chemicals, and drugs are made. Since the methodology we are developing can shorten existing synthetic protocols, proceed at room temperature, and operate under environmentally benign conditions, it can greatly reduce energy expenditures, especially considering the contribution of the chemical manufacturing field to the gross domestic product.

David A Vicic

2009-08-10T23:59:59.000Z

15

GlycidylEsters  

Science Conference Proceedings (OSTI)

AOCS, P.O. Box 17190, Urbana, IL 61803-7190 USA www.aocs.org FOR IMMEDIATE RELEASE May 10, 2012 AOCS/JOCS Releases First Validated Direct Method for Glycidyl Fatty Acid Esters Marks first joint analytic

16

Biodiesel | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

fatty acid methyl esters, or long-chain mono alkyl esters. It is produced from renewable sources such as new and used vegetable oils and animal fats and is a cleaner-burning...

17

Synthesis of an acid addition salt of delta-aminolevulinic acid from 5-bromo levulinic acid esters  

DOE Patents (OSTI)

A process is disclosed for preparing an acid addition salt of delta-aminolevulinic acid comprising. The process involves dissolving a lower alkyl 5-bromolevulinate and an alkali metal diformylamide in an organic solvent selected from the group consisting of acetonitrile, methanol, tetrahydrofuran, 2-methyltetrahydrofuran and methylformate or mixtures to form a suspension of an alkyl 5-(N,N-diformylamino) levulinate ester; and hydrolyzing the alkyl 5-(N,N-diformylamino) levulinate with an inorganic acid to form an acid addition salt of delta-amino levulinic acid.

Moens, L.

1999-05-25T23:59:59.000Z

18

Theory Of Alkyl Terminated Silicon Quantum Dots  

DOE Green Energy (OSTI)

We have carried out a series of ab-initio calculations to investigate changes in the optical properties of Si quantum dots as a function of surface passivation. In particular, we have compared hydrogen passivated dots with those having alkyl groups at the surface. We find that, while on clusters with reconstructed surfaces a complete alkyl passivation is possible, steric repulsion prevents full passivation of Si dots with unreconstructed surfaces. In addition, our calculations show that steric repulsion may have a dominant effect in determining the surface structure, and eventually the stability of alkyl passivated clusters, with results dependent on the length of the carbon chain. Alkyl passivation weakly affects optical gaps of silicon quantum dots, while it substantially decreases ionization potentials and electron affinities and affect their excited state properties. On the basis of our results we propose that alkyl terminated quantum dots may be size selected taking advantage of the change in ionization potential as a function of the cluster size.

Reboredo, F; Galli, G

2004-08-19T23:59:59.000Z

19

Alkylation of organic aromatic compounds  

DOE Patents (OSTI)

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a molecular sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene to about the mid point of the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 figures.

Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

1993-09-07T23:59:59.000Z

20

Alkylation of organic aromatic compounds  

DOE Patents (OSTI)

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a molecular sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 fig.

Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

1994-06-14T23:59:59.000Z

Note: This page contains sample records for the topic "mono alkyl ester" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Alkylation of organic aromatic compounds  

DOE Patents (OSTI)

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 fig.

Smith, L.A. Jr.

1989-07-18T23:59:59.000Z

22

Alkylation of organic aromatic compounds  

DOE Patents (OSTI)

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene to about the mid point of the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

Smith, Jr., Lawrence A. (Bellaire, TX); Arganbright, Robert P. (Seabrook, TX); Hearn, Dennis (Houston, TX)

1993-01-01T23:59:59.000Z

23

Alkylation of organic aromatic compounds  

DOE Patents (OSTI)

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

Smith, Jr., Lawrence A. (Bellaire, TX); Arganbright, Robert P. (Seabrook, TX); Hearn, Dennis (Houston, TX)

1994-01-01T23:59:59.000Z

24

Alkylation of organic aromatic compounds  

DOE Patents (OSTI)

Aromatic compounds are alkylated in a combination reactor/distillation column comprising a vessel suitable for operating between 70 C and 500 C and from 0.5 to 20 atmospheres pressure; an inert distillation packing in the lower one-third of said vessel; solid acidic catalytic material such as zeolites or an acidic cation exchange resin supported in the middle one-third of said vessel; and inert distillation packing in the upper one-third of said vessel. A benzene inlet is located near the upper end of the vessel; an olefin inlet is juxtaposed with said solid acidic catalytic material; a bottoms outlet is positioned near the bottom of said vessel for removing said cumene and ethyl benzene; and an overhead outlet is placed at the top of said vessel for removing any unreacted benzene and olefin.

Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

1993-01-05T23:59:59.000Z

25

Alkylation of organic aromatic compounds  

DOE Patents (OSTI)

Aromatic compounds are alkylated in a combination reactor/distillation column comprising a vessel suitable for operating between 70.degree. C. and 500.degree. C. and from 0.5 to 20 atmospheres pressure; an inert distillation packing in the lower one-third of said vessel; solid acidic catalytic material such as zeolites or an acidic cation exchange resin supported in the middle one-third of said vessel; and inert distillation packing in the upper one-third of said vessel. A benzene inlet is located near the upper end of the vessel; an olefin inlet is juxtaposed with said solid acidic catalytic material; a bottoms outlet is positioned near the bottom of said vessel for removing said cumene and ethyl benzene; and an overhead outlet is placed at the top of said vessel for removing any unreacted benzene and olefin.

Smith, Jr., Lawrence A. (Bellaire, TX); Arganbright, Robert P. (Seabrook, TX); Hearn, Dennis (Houston, TX)

1993-01-01T23:59:59.000Z

26

Alkylation of organic aromatic compounds  

DOE Patents (OSTI)

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

Smith, Jr., Lawrence A. (Houston, TX)

1989-01-01T23:59:59.000Z

27

MONO FOR CROSS-PLATFORM CONTROL SYSTEM ENVIRONMENT  

SciTech Connect

Mono is an independent implementation of the .NET Frameworkby Novell that runs on multiple operating systems (including Windows,Linux and Macintosh) and allows any .NET compatible application to rununmodified. For instance Mono can run programs with graphical userinterfaces (GUI) developed with the C# language on Windows with VisualStudio (a full port of WinForm for Mono is in progress). We present theresults of tests we performed to evaluate the portability of our controlssystem .NET applications from MS Windows to Linux.

Nishimura, Hiroshi; Timossi, Chris

2006-10-19T23:59:59.000Z

28

Electrochemical method for producing a biodiesel mixture comprising fatty acid alkyl esters and glycerol  

SciTech Connect

The present invention relates to an integrated method and system for the simultaneous production of biodiesel from free fatty acids (via esterification) and from triglycerides (via transesterification) within the same reaction chamber. More specifically, one preferred embodiment of the invention relates to a method and system for the production of biodiesel using an electrodeionization stack, wherein an ion exchange resin matrix acts as a heterogeneous catalyst for simultaneous esterification and transesterification reactions between a feedstock and a lower alcohol to produce biodiesel, wherein the feedstock contains significant levels of free fatty acid. In addition, because of the use of a heterogeneous catalyst, the glycerol and biodiesel have much lower salt concentrations than raw biodiesel produced by conventional transesterification processes. The present invention makes it much easier to purify glycerol and biodiesel.

Lin, YuPo J; St. Martin, Edward J

2013-08-13T23:59:59.000Z

29

Alternative Fuels Data Center: North Dakota Laws and Incentives...  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

that is comprised of mono-alkyl esters of long chain fatty acids derived from vegetable oil or animal fats and that meets ASTM D6751. Green diesel is defined as a fuel produced...

30

Enhancement of alkylation catalysts for improved supercritical fluid regeneration  

DOE Patents (OSTI)

A method of modifying an alkylation catalyst to reduce the formation of condensed hydrocarbon species thereon. The method comprises providing an alkylation catalyst comprising a plurality of active sites. The plurality of active sites on the alkylation catalyst may include a plurality of weakly acidic active sites, intermediate acidity active sites, and strongly acidic active sites. A base is adsorbed to a portion of the plurality of active sites, such as the strongly acidic active sites, selectively poisoning the strongly acidic active sites. A method of modifying the alkylation catalyst by providing an alkylation catalyst comprising a pore size distribution that sterically constrains formation of the condensed hydrocarbon species on the alkylation catalyst or by synthesizing the alkylation catalyst to comprise a decreased number of strongly acidic active sites is also disclosed, as is a method of improving a regeneration efficiency of the alkylation catalyst.

Ginosar, Daniel M. (Idaho Falls, ID); Petkovic, Lucia M. (Idaho Falls, ID)

2010-12-28T23:59:59.000Z

31

Enhancement of alkylation catalysts for improved supercritical fluid regeneration  

DOE Patents (OSTI)

A method of modifying an alkylation catalyst to reduce the formation of condensed hydrocarbon species thereon. The method comprises providing an alkylation catalyst comprising a plurality of active sites. The plurality of active sites on the alkylation catalyst may include a plurality of weakly acidic active sites, intermediate acidity active sites, and strongly acidic active sites. A base is adsorbed to a portion of the plurality of active sites, such as the strongly acidic active sites, selectively poisoning the strongly acidic active sites. A method of modifying the alkylation catalyst by providing an alkylation catalyst comprising a pore size distribution that sterically constrains formation of the condensed hydrocarbon species on the alkylation catalyst or by synthesizing the alkylation catalyst to comprise a decreased number of strongly acidic active sites is also disclosed, as is a method of improving a regeneration efficiency of the alkylation catalyst.

Ginosar, Daniel M. (Idaho Falls, ID); Petkovic, Lucia (Idaho Falls, ID)

2009-09-22T23:59:59.000Z

32

PROCESS FOR PRODUCING ALKYL ORTHOPHOSPHORIC ACID EXTRACTANTS  

DOE Patents (OSTI)

A process is given for producing superior alkyl orthophosphoric acid extractants for use in solvent extraction methods to recover and purify various metals such as uranium and vanadium. The process comprises slurrying P/sub 2/O/ sub 5/ in a solvent diluent such as kerosene, benzene, isopropyl ether, and the like. An alipbatic alcohol having from nine to seventeen carbon atoms, and w- hcrein ihc OH group is situated inward of the terminal carbon atoms, is added to the slurry while the reaction temperature is mainiained below 60 deg C. The alcohol is added in the mole ratio of about 2 to l, alcohol to P/sub 2/O/sub 5/. A pyrophosphate reaotion product is formed in the slurry-alcohol mixture. Subsequently, the pyrophosphate reaction product is hydrolyzed with dilute mineral acid to produce the desired alkyl orthophosphoric aeid extractant. The extraetant may then be separated and utilized in metal-recovery, solvent- extraction processes. (AEC)

Grinstead, R.R.

1962-01-23T23:59:59.000Z

33

Mono inverter Multi parallel PMSM -Structure and Control strategy  

E-Print Network (OSTI)

a new and original Mono inverter Multi parallel Permanent Magnet Synchronous Motor (PMSM) system. To obtain the stability of such a system, each of the motor synchronisms should always be respected regardless of their load torque. In this case, only one motor, called "master motor", will be self

Paris-Sud XI, Université de

34

Topological insulating phases in mono and bilayer graphene  

E-Print Network (OSTI)

We analyze the influence of different quadratic interactions giving rise to time reversal invariant topological insulating phases in mono and bilayer graphene. We make use of the effective action formalism to determine the dependence of the Chern Simons coefficient on the different interactions.

Alberto Cortijo; Adolfo G. Grushin; Maria A. H. Vozmediano

2010-07-21T23:59:59.000Z

35

North Shore Mono Lake Geothermal Area | Open Energy Information  

Open Energy Info (EERE)

Shore Mono Lake Geothermal Area Shore Mono Lake Geothermal Area Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermal Resource Area: North Shore Mono Lake Geothermal Area Contents 1 Area Overview 2 History and Infrastructure 3 Regulatory and Environmental Issues 4 Exploration History 5 Well Field Description 6 Geology of the Area 7 Geofluid Geochemistry 8 NEPA-Related Analyses (0) 9 Exploration Activities (0) 10 References Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"TERRAIN","zoom":6,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"500px","height":"300px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":38.048205,"lon":-119.080047,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

36

New 3-MCPD (glycidol ester) method  

Science Conference Proceedings (OSTI)

A direct method for the determination of fatty acid esters of both 3-MCPD and glyci¬dol has been published in the Journal of the American Oil Chemists’ Society (JAOCS). New 3-MCPD (glycidol ester) method inform Magazine algae algal AOCS biomass bu

37

Process for the preparation of an energetic nitrate ester  

SciTech Connect

A process for the preparation of an energetic nitrate ester compound and related intermediates is provided.

Chavez, David E; Naud, Darren L; Hiskey, Michael A

2013-12-17T23:59:59.000Z

38

Synthesis of a new energetic nitrate ester  

DOE Green Energy (OSTI)

Nitrate esters have been known as useful energetic materials since the discovery of nitroglycerin by Ascanio Sobrero in 1846. The development of methods to increase the safety and utility of nitroglycerin by Alfred Nobel led to the revolutionary improvement in the utility of nitroglycerin in explosive applications in the form of dynamite. Since then, many nitrate esters have been prepared and incorporated into military applications such as double-based propellants, detonators and as energetic plasticizers. Nitrate esters have also been shown to have vasodilatory effects in humans and thus have been studied and used for treatments of ailments such as angina. The mechanism of the biological response towards nitrate esters has been elucidated recently. Interestingly, many of the nitrate esters used for military purposes are liquids (ethylene glycol dinitrate, propylene glycol dinitrate, etc). Pentaerythritol tetranitrate (PETN) is one of the only solid nitrate esters, besides nitrocellulose, that is used in any application. Unfortunately, PETN melting point is above 100 {sup o}C, and thus must be pressed as a solid for detonator applications. A more practical material would be a melt-castable explosive, for potential simplification of manufacturing processes. Herein we describe the synthesis of a new energetic nitrate ester (1) that is a solid at ambient temperatures, has a melting point of 85-86 {sup o}C and has the highest density of any known nitrate ester composed only of carbon, hydrogen, nitrogen and oxygen. We also describe the chemical, thermal and sensitivity properties of 1 as well as some preliminary explosive performance data.

Chavez, David E [Los Alamos National Laboratory

2008-01-01T23:59:59.000Z

39

Tensile Fracture Mechanisms for SiCf(SCS-6)/Ti Alloys Based Mono ...  

Science Conference Proceedings (OSTI)

May 1, 2007 ... For the mono-composites having the nonlinear load-displacement relationship the second load-displacement curves after first unloading were ...

40

MAGNESIUM MONO POTASSIUM PHOSPHATE GROUT FOR P-REACTOR VESSEL IN-SITU DECOMISSIONING  

Science Conference Proceedings (OSTI)

The objective of this report is to document laboratory testing of magnesium mono potassium phosphate grouts for P-Reactor vessel in-situ decommissioning. Magnesium mono potassium phosphate cement-based grout was identified as candidate material for filling (physically stabilizing) the 105-P Reactor vessel (RV) because it is less alkaline than portland cement-based grout (pH of about 12.4). A less alkaline material ({ash), and (4) Ceramicrete{reg_sign} magnesium mono potassium phosphate-based grouts prepared at Argonne National Laboratory. Boric acid was evaluated as a set retarder in the magnesium mono potassium phosphate mixes.

Langton, C.; Stefanko, D.

2011-01-05T23:59:59.000Z

Note: This page contains sample records for the topic "mono alkyl ester" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Mono-Like Ingot/Wafers Made of Solar-Grade Silicon for Solar Cells ...  

Science Conference Proceedings (OSTI)

About this Abstract. Meeting, 2012 TMS Annual Meeting & Exhibition. Symposium , Solar Cell Silicon. Presentation Title, Mono-Like Ingot/Wafers Made of ...

42

Aryl hydrocarbon mono-oxygenase activity in human lymphocytes  

SciTech Connect

Aryl hydrocarbon mono-oxygenase (AHM), an enzyme of key importance in metabolism of xenobiotic chemicals such as polynuclear aromatic hydrocarbons (PNA), is present in human lymphocytes. Studies investing the relation of activity of AHM in human lymphocytes to parameters such as disease state, PNA exposure, in vitro mitogen stimulation, etc. have been summarized in this report. Some studies have demonstrated increased AHM activity in lymphocytes from cigarette smokers (compared to nonsmokers), and in lung cancer patients when compared to appropriate control groups. These observations are confused by extreme variability in human lymphocyte AHM activities, such variability arising from factors such as genetic variation in AHM activity, variation in in vitro culture conditions which affect AHM activity, and the problematical relationship of common AHM assays to actual PNA metabolism taking place in lymphocytes. If some of the foregoing problems can be adequately addressed, lymphocyte AHM activity could hold the promise of being a useful biomarker system for human PNA exposure.

Griffin, G.D.; Schuresko, D.D.

1981-06-01T23:59:59.000Z

43

DYNAMIC SIMULATION OF MONO-TUBE CAVITY RECEIVERS FOR DIRECT STEAM GENERATION  

E-Print Network (OSTI)

-tracing study of the heat flux distribution inside the steam receiver is used to spatially refine the modelDYNAMIC SIMULATION OF MONO-TUBE CAVITY RECEIVERS FOR DIRECT STEAM GENERATION José Zapata 1 , John dish has been in operation since 2010 with a mono-tube steam cavity receiver, the SG4 system

44

Why is the AMOC mono-stable in Coupled General Circulation Models?  

Science Conference Proceedings (OSTI)

This paper is concerned with the question: why do Coupled General Circulation Models (CGCM) seem to be biased towards a mono-stable AMOC? In particular, we investigate whether the mono-stable behavior of the CGCMs is caused by a bias of model ...

Wei Liu; Zhengyu Liu; Esther C. Brady

45

Affinity labelling enzymes with esters of aromatic sulfonic acids  

DOE Patents (OSTI)

Novel esters of aromatic sulfonic acids are disclosed. The specific esters are nitrophenyl p- and m-amidinophenylmethanesulfonate. Also disclosed is a method for specific inactivation of the enzyme, thrombin, employing nitrophenyl p-amidinophenylmethanesulfonate.

Wong, Show-Chu (Riverhead, NY); Shaw, Elliott (Shoreham, NY)

1977-01-01T23:59:59.000Z

46

Laser System for Livermore's Mono Energetic Gamma-Ray Source  

SciTech Connect

A Mono-energetic Gamma-ray (MEGa-ray) source, based on Compton scattering of a high-intensity laser beam off a highly relativistic electron beam, requires highly specialized laser systems. To minimize the bandwidth of the {gamma}-ray beam, the scattering laser must have minimal bandwidth, but also match the electron beam depth of focus in length. This requires a {approx}1 J, 10 ps, fourier-transform-limited laser system. Also required is a high-brightness electron beam, best provided by a photoinjector. This electron source requires a second laser system with stringent requirements on the beam including flat transverse and longitudinal profiles and fast rise times. Furthermore, these systems must be synchronized to each other with ps-scale accuracy. Using a novel hyper-dispersion compressor configuration and advanced fiber amplifiers and diode-pumped Nd:YAG amplifiers, we have designed laser systems that meet these challenges for the X-band photoinjector and Compton-scattering source being built at Lawrence Livermore National Laboratory.

Gibson, D; Albert, F; Bayramian, A; Marsh, R; Messerly, M; Ebbers, C; Hartemann, F

2011-03-14T23:59:59.000Z

47

Geothermal systems of the Mono Basin-Long Valley region, eastern California and western Nevada  

DOE Green Energy (OSTI)

The region that includes Mono Basin, Long Valley, the Bridgeport-Bodie Hills area, and Aurora, in eastern California and western Nevada was studied to determine the possible causes and interactions of the geothermal anomalies in the Mono Basin-Long Valley region as a whole. A special goal of the study was to locate possible shallow bodies of magma and to determine their influence on the hydrothermal systems in the region. (ACR)

Higgins, C.T.; Flynn, T.; Chapman, R.H.; Trexler, D.T.; Chase, G.R.; Bacon, C.F.; Ghusn, G. Jr.

1985-01-01T23:59:59.000Z

48

Ester, Alaska: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

Ester, Alaska: Energy Resources Ester, Alaska: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 64.8472222°, -148.0144444° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":64.8472222,"lon":-148.0144444,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

49

MAGNESIUM MONO POTASSIUM PHOSPHATE GROUT FOR P-REACTOR VESSEL IN-SITU DECOMISSIONING  

SciTech Connect

The objective of this report is to document laboratory testing of magnesium mono potassium phosphate grouts for P-Reactor vessel in-situ decommissioning. Magnesium mono potassium phosphate cement-based grout was identified as candidate material for filling (physically stabilizing) the 105-P Reactor vessel (RV) because it is less alkaline than portland cement-based grout (pH of about 12.4). A less alkaline material ({<=} 10.5) was desired to address a potential materials compatibility issue caused by corrosion of aluminum metal in highly alkaline environments such as that encountered in portland cement grouts. Information concerning access points into the P-Reactor vessel and amount of aluminum metal in the vessel is provided elsewhere. Fresh and cured properties were measured for: (1) commercially blended magnesium mono potassium phosphate packaged grouts, (2) commercially available binders blended with inert fillers at SRNL, (3) grouts prepared from technical grade MgO and KH{sub 2}PO{sub 4} and inert fillers (quartz sands, Class F fly ash), and (4) Ceramicrete{reg_sign} magnesium mono potassium phosphate-based grouts prepared at Argonne National Laboratory. Boric acid was evaluated as a set retarder in the magnesium mono potassium phosphate mixes.

Langton, C.; Stefanko, D.

2011-01-05T23:59:59.000Z

50

Removal and Degradation of Phorbol Esters during Pre-treatment ...  

Science Conference Proceedings (OSTI)

Dec 10, 2008 ... degradation products in these fractions could not be ruled out. Keywords Phorbol esters Á Transesterification Á. Biodiesel Á Biofuel Á Jatropha.

51

Methods of producing alkylated hydrocarbons from an in situ heat treatment process liquid  

DOE Patents (OSTI)

A method for producing alkylated hydrocarbons is disclosed. Formation fluid is produced from a subsurface in situ heat treatment process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes olefins. The liquid stream is fractionated to produce at least a second gas stream including hydrocarbons having a carbon number of at least 3. The first gas stream and the second gas stream are introduced into an alkylation unit to produce alkylated hydrocarbons. At least a portion of the olefins in the first gas stream enhance alkylation.

Roes, Augustinus Wilhelmus Maria (Houston, TX); Mo, Weijian (Sugar Land, TX); Muylle, Michel Serge Marie (Houston, TX); Mandema, Remco Hugo (Houston, TX); Nair, Vijay (Katy, TX)

2009-09-01T23:59:59.000Z

52

Use of neural networks and decision fusion for lithostratigraphic correlation with sparse data, Mono-Inyo Craters, California  

Science Conference Proceedings (OSTI)

We explore the use of multiple artificial neural networks combined within the framework of the Dempster-Shafer Theory of Evidence to construct a hybrid information processing system for the correlation of tephra layers. The working hypothesis is that ... Keywords: Artificial neural network, California, Dempster-Shafer Theory, Mono-Inyo Craters, North mono eruption, Tephrastratigraphy, Tephrochronology, Theory of Evidence

M. Bursik; G. Rogova

2006-12-01T23:59:59.000Z

53

Stripes of Partially Fluorinated Alkyl Chains: Dipolar Langmuir Monolayers  

E-Print Network (OSTI)

Stripe-like domains of Langmuir monolayers formed by surfactants with partially fluorinated lipid anchors (F-alkyl lipids) are observed at the gas-liquid phase coexistence. The average periodicity of the stripes, measured by fluorescence microscopy, is in the micrometer range, varying between 2 and 8 microns. The observed stripe-like patterns are stabilized due to dipole-dipole interactions between terminal -CF3 groups. These interactions are particularly strong as compared with non-fluorinated lipids due to the low dielectric constant of the surrounding media (air). These long-range dipolar interactions tend to elongate the domains, in contrast to the line tension that tends to minimize the length of the domain boundary. This behavior should be compared with that of the lipid monolayer having alkyl chains, and which form spherical micro-domains (bubbles) at the gas-liquid coexistence. The measured stripe periodicity agrees quantitatively with a theoretical model. Moreover, the reduction in line tension by adding traces (0.1 mol fraction) of cholesterol results, as expected, in a decrease in the domain periodicity.

Matthias F. Schneider; David Andelman; Motomu Tanaka

2005-01-16T23:59:59.000Z

54

Year/PAD District Alkylates Aromatics Road Oil  

U.S. Energy Information Administration (EIA) Indexed Site

Alkylates Alkylates Aromatics Road Oil and Lubricants Petroleum Coke (MMcfd) Hydrogen Sulfur (short tons/day) Production Capacity Asphalt Isomers Marketable Table 7. Operable Production Capacity of Petroleum Refineries, January 1, 1981 to January 1, 2013 (Thousand Barrels per Stream Day, Except Where Noted) a JAN 1, 1981 974 299 765 131 234 276 2,054 NA JAN 1, 1982 984 290 740 162 242 267 1,944 NA JAN 1, 1983 960 237 722 212 241 296 2,298 NA JAN 1, 1984 945 218 800 208 241 407 2,444 NA JAN 1, 1985 917 215 767 219 243 424 2,572 NA JAN 1, 1986 941 276 804 258 246 356 2,357 NA JAN 1, 1987 974 287 788 326 250 364 2,569 23,806 JAN 1, 1988 993 289 788 465 232 368 2,418 27,639 JAN 1, 1989 1,015 290 823 469 230 333 2,501 28,369 JAN 1, 1990 1,030 290 844 456 232 341 2,607 24,202

55

Nickel-catalyzed Suzuki-Miyaura reactions of unactivated halides with alkyl boranes and planar-chiral borabenzene catalysts for Diels-Alder reactions  

E-Print Network (OSTI)

Part I describes the expansion in scope of a nickel-catalyzed coupling reaction of unactivated alkyl bromides and alkyl boranes to include unactivated alkyl chlorides. The new method is adapted for use outside of a glove ...

Lu, Zhe

2010-01-01T23:59:59.000Z

56

Methane, Nonmethane Hydrocarbons, Alkyl Nitrates, and Chlorinated Carbon  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Trace Gases in Whole-Air Samples Atmospheric Trace Gases in Whole-Air Samples Methane, Nonmethane Hydrocarbons, Alkyl Nitrates, and Chlorinated Carbon Compounds including 3 Chlorofluorocarbons (CFC-11, CFC-12, and CFC-113) in Whole-air Samples graphics Graphics data Data Investigator Donald Blake Department of Chemistry, University of California Irvine, California, 92697 USA Period of Record April 1979 - December 2012 Methods Whole-air samples are collected in conditioned, evacuated, 2-L stainless steel canisters; each canister is filled to ambient pressure over a period of about 1 minute (approximately 20 seconds to 2 minutes). These canisters are returned to the University of California at Irvine for chromatographic analysis. Analysis for methane includes gas chromatography with flame ionization, as

57

Quantitation of Glycidyl Esters via Stable Isotope Dilution Analysis  

Science Conference Proceedings (OSTI)

Quantitation of Glycidyl Esters via Stable Isotope Dilution Analysis Michael Granvogl and Peter Schieberle Technical University of Munich, Chair for Food Chemistry and German Research Centre for Food Chemistry, Lise-Meitner-Str. 34, Freising, Germ

58

Mono Hot Springs Pool & Spa Low Temperature Geothermal Facility | Open  

Open Energy Info (EERE)

Hot Springs Pool & Spa Low Temperature Geothermal Facility Hot Springs Pool & Spa Low Temperature Geothermal Facility Jump to: navigation, search Name Mono Hot Springs Pool & Spa Low Temperature Geothermal Facility Facility Mono Hot Springs Sector Geothermal energy Type Pool and Spa Location Fresno, California Coordinates 36.7477272°, -119.7723661° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[]}

59

Evidence for alkyl intermediates during Fischer-Tropsch synthesis and their relation to hydrocarbon products  

SciTech Connect

Fisher-Tropsch synthesis mechanisms have been postulated in which alkyl fragments are both the chain-growing intermediate and the precursor to hydrocarbon products. The conversion of CO/H/sub 2/ into small alkyl fragments was investigated by scavenging C/sub 1/-C/sub 3/ alkyl species from the surface of an iron catalyst during Fischer-Tropsch synthesis. The experiments were performed in a steady-state mode revealing that pyridine did not inhibit or poison the Fischer-Tropsch reaction, rather it suppressed the overall rate slightly. Scavenged ..cap alpha..-alkylpyridine distributions were dependent upon synthesis variables and displayed a dependence which was proportional to the dependence upon synthesis variables and displayed a dependence which was proportional to the dependence of C/sub 1/-C/sub 3/ Fischer-Tropsch products. These dependences are used to demonstrate that alkyl fragments are the immediate precursors to Fischer-Tropsch products.

Wang, C.J.; Ekerdt, J.G.

1984-04-01T23:59:59.000Z

60

Intramolecular Heck couplings of unactivated alkyl electrophiles : synthetic and mechanistic studies  

E-Print Network (OSTI)

A method for the palladium-catalyzed intramolecular Heck coupling of unactivated alkyl bromides and chlorides is described. The optimal catalyst system was composed of Pd2(MeO-dba)3 as the metal source and N-heterocyclic ...

Firmansjah, Luke

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mono alkyl ester" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Molecular Simulation Study of Alkyl Monolayers on Si(111) Luzheng Zhang  

E-Print Network (OSTI)

Molecular Simulation Study of Alkyl Monolayers on Si(111) Luzheng Zhang Department of Chemical of Washington, Seattle, Washington 98195 Received April 30, 2001 Molecular mechanics and molecular dynamics) surface. The optimal molecular packing was found basedontheconsiderationofthreemajorfactors

Zhang, Luzheng

62

Compositions of alkyl 4-[o-(substituted amino)phenyl]-3-thioallophanates and methods of use  

DOE Patents (OSTI)

Various alkyl 4-[o-(substituted amino)phenyl]-3-thioallophanates are useful as fungicides and mite ovicides. An exemplary specie is methyl 4-(o-butyramidophenyl)-3-thioallophanate.

Adams, Charles De Witt (Newark, DE)

1977-03-01T23:59:59.000Z

63

Effects of alkyl polyglycoside (APG) on composting of agricultural wastes  

Science Conference Proceedings (OSTI)

Composting is the biological degradation and transformation of organic materials under controlled conditions to promote aerobic decomposition. To find effective ways to accelerate composting and improve compost quality, numerous methods including additive addition, inoculation of microorganisms, and the use of biosurfactants have been explored. Studies have shown that biosurfactant addition provides more favorable conditions for microorganism growth, thereby accelerating the composting process. However, biosurfactants have limited applications because they are expensive and their use in composting and microbial fertilizers is prohibited. Meanwhile, alkyl polyglycoside (APG) is considered a 'green' surfactant. This study aims to determine whether APG addition into a compost reaction vessel during 28-day composting can enhance the organic matter degradation and composting process of dairy manure. Samples were periodically taken from different reactor depths at 0, 3, 5, 7, 14, 21, and 28 days. pH levels, electrical conductivity (EC), ammonium and nitrate nitrogen, seed germination indices, and microbial population were determined. Organic matter and total nitrogen were also measured. Compared with the untreated control, the sample with APG exhibited slightly increased microbial populations, such as bacteria, fungi, and actinomycetes. APG addition increased temperatures without substantially affecting compost pH and EC throughout the process. After 28 days, APG addition increased nitrate nitrogen concentrations, promoted matter degradation, and increased seed germination indices. The results of this study suggest that the addition of APG provides more favorable conditions for microorganism growth, slightly enhancing organic matter decomposition and accelerating the composting process, improving the compost quality to a certain extent.

Zhang Fabao [Soil and Fertilizer Institute, Guangdong Academy of Agricultural Sciences, Guangdong Key Laboratory of Nutrient Cycling and Farmland Conservation, Guangzhou 510640 (China); Gu Wenjie, E-mail: guwenjie1982@yahoo.cn [Soil and Fertilizer Institute, Guangdong Academy of Agricultural Sciences, Guangdong Key Laboratory of Nutrient Cycling and Farmland Conservation, Guangzhou 510640 (China); Xu Peizhi; Tang Shuanhu; Xie Kaizhi; Huang Xu; Huang Qiaoyi [Soil and Fertilizer Institute, Guangdong Academy of Agricultural Sciences, Guangdong Key Laboratory of Nutrient Cycling and Farmland Conservation, Guangzhou 510640 (China)

2011-06-15T23:59:59.000Z

64

Monodisperse SiC/vinyl ester nanocomposites: Dispersant formulation, synthesis, and characterization  

E-Print Network (OSTI)

Processing and properties of SiC/vinyl ester nanocomposites.design of experiments for SiC/vinyl ester nanocomposites.of nanocrystalline cubic SiC films. Jpn. J. Appl. Phys. 37,

Yong, Virginia; Hahn, H. Thomas

2011-01-01T23:59:59.000Z

65

Validation of Quantitative Method for Glycidol Fatty Acid Esters in Edible Oils  

Science Conference Proceedings (OSTI)

Validation of Quantitative Method for Glycidol Fatty Acid Esters (GEs) in Edible Oils Hiroki Shiro, Naoki Kondo and Yoshinori Masukawa

66

Bound 3-MCPD in Foods, Vegetable Oils and Fats (3-MCPD Esters)  

Science Conference Proceedings (OSTI)

Reference papers for bound 3-MCPD (3-Monochloropropane-1,2-diol and 3-MCPD esters)in foods, vegetable oils, and fats. Bound 3-MCPD in Foods, Vegetable Oils and Fats (3-MCPD Esters) 3-MCPD 2-diol 3-MCPD 3-MCPD Esters 3-monochloropropane-1 acid analysis ao

67

Mono-hydroxy methoxychlor alters levels of key sex steroids and steroidogenic enzymes in cultured mouse antral follicles  

SciTech Connect

Methoxychlor (MXC) is an organochlorine pesticide that reduces fertility in female rodents by decreasing antral follicle numbers and increasing follicular death. MXC is metabolized in the body to mono-hydroxy MXC (mono-OH). Little is known about the effects of mono-OH on the ovary. Thus, this work tested the hypothesis that mono-OH exposure decreases production of 17{beta}-estradiol (E{sub 2}) by cultured mouse antral follicles. Antral follicles were isolated from CD-1 mice (age 35-39 days) and exposed to dimethylsulfoxide (DMSO), or mono-OH (0.1-10 {mu}g/mL) for 96 h. Media and follicles were collected for analysis of sex steroid levels and mRNA expression, respectively. Mono-OH treatment (10 {mu}g/mL) decreased E{sub 2} (DMSO: 3009.72 {+-} 744.99 ng/mL; mono-OH 0.1 {mu}g/mL: 1679.66 {+-} 461.99 ng/mL; 1 {mu}g/mL: 1752.72 {+-} 532.41 ng/mL; 10 {mu}g/mL: 45.89 {+-} 33.83 ng/mL), testosterone (DMSO: 15.43 {+-} 2.86 ng/mL; mono-OH 0.1 {mu}g/mL: 17.17 {+-} 4.71 ng/mL; 1 {mu}g/mL: 13.64 {+-} 3.53 ng/mL; 10 {mu}g/mL: 1.29 {+-} 0.23 ng/mL), androstenedione (DMSO: 1.92 {+-} 0.34 ng/mL; mono-OH 0.1 {mu}g/mL: 1.49 {+-} 0.43 ng/mL; 1 {mu}g/mL: 0.64 {+-} 0.31 ng/mL; 10 {mu}g/mL: 0.12 {+-} 0.06 ng/mL) and progesterone (DMSO: 24.11 {+-} 4.21 ng/mL; mono-OH 0.1 {mu}g/mL: 26.77 {+-} 4.41 ng/mL; 1 {mu}g/mL: 20.90 {+-} 3.75 ng/mL; 10 {mu}g/mL: 9.44 {+-} 2.97 ng/mL) levels. Mono-OH did not alter expression of Star, Hsd3b1, Hsd17b1 and Cyp1b1, but it did reduce levels of Cyp11a1, Cyp17a1 and Cyp19a1 mRNA. Collectively, these data suggest that mono-OH significantly decreases levels of key sex steroid hormones and the expression of enzymes required for steroidogenesis.

Craig, Zelieann R., E-mail: zelieann@gmail.co [Department of Comparative Biosciences, University of Illinois, Urbana, IL (United States); Leslie, Traci C., E-mail: traci.leslie@gmail.co [Department of Comparative Biosciences, University of Illinois, Urbana, IL (United States); Hatfield, Kimberly P., E-mail: kpm9786@yahoo.co [Program in Toxicology and Department of Epidemiology and Preventive Medicine, University of Maryland School of Medicine, Baltimore, MD 21201 (United States); Gupta, Rupesh K., E-mail: drrupesh@illinois.ed [Department of Comparative Biosciences, University of Illinois, Urbana, IL (United States); Flaws, Jodi A., E-mail: jflaws@illinois.ed [Department of Comparative Biosciences, University of Illinois, Urbana, IL (United States)

2010-12-01T23:59:59.000Z

68

Synthesis and chemistry of cationic d sup 0 metal alkyl complexes  

DOE Green Energy (OSTI)

The long term goals of this project are to design and synthesize highly unsaturated, electrophilic metal complexes and to explore their use as catalysts, reagents, and/or model systems for olefin polymerization and C-H activation chemistry. During the 1990 budget year we have focused our attention on (i) the ligand C-H activation chemistry of Cp{sub 2}Zr(CH{sub 3})(THF){sup +} and related cationic, d{sup o} Zr alkyl complexes, and (ii) the synthesis of new classes of group 4 metal alkyl complexes with non-Cp{sub 2}M ligand environments.

Jordan, R.F.

1990-01-01T23:59:59.000Z

69

Refiners look at H sub 2 SO sub 4 alkylation and catalytic reforming  

Science Conference Proceedings (OSTI)

Sulfuric acid alkylation and catalytic reforming drew many questions at the most recent National Petroleum Refiners Association (NPRA) question and answer session on refining and petrochemical technology. At this annual meeting, presubmitted questions are answered by a panel of experts. For more information on the meeting's format, see OGJ, Mar. 16, p. 37. This third and final article in the series of excerpts from the 1991 NPRA Q and A Session examines such pertinent alkylation topics as tertiary amyl methyl ether (TAME) raffinate processing and unit operation during acid runaway. Also discussed are skewed platinum/rhenium reforming catalyst and how catalyst life affects reformate aromatics levels.

Not Available

1992-04-27T23:59:59.000Z

70

COMBUSTION AND FLAME 24, 27-34 (1975) 27 Flame Emission Studies of Ozone with Metal Alkyls  

E-Print Network (OSTI)

COMBUSTION AND FLAME 24, 27-34 (1975) 27 Flame Emission Studies of Ozone with Metal Alkyls: Zn (CH3 of combustion. Premixed [2, 3] anddiffusion [4] flames of metal alkyl compounds have been carried out to deter- tageous to study the combustion of polyatomic molecules under single-collision conditions, i

Zare, Richard N.

71

Oligonucleoside alkyl or arylphosphonate derivatives capable of crosslinking with or cleaving nucleic acids  

DOE Patents (OSTI)

A composition for inactivating a target nucleic acid which comprises an oligonucleoside alkyl or arylphosphonate analogue which is complementary to the sequence of the target nucleic acid is provided. It includes a functional group which reacts with the target nucleic acid to render the target nucleic acid inactive or nonfunctional. 16 figs.

Miller, P.S.; Ts' o, P.O.P.

1999-06-15T23:59:59.000Z

72

Comparative Study of Low-temperature PECVD of Amorphous Silicon using Mono-, Di-, Trisilane and Cyclohexasilane  

SciTech Connect

The hydrogenated amorphous silicon a-Si:H films were grown by plasma-enhanced chemical vapor deposition (PECVD) using liquid cyclohexasilane Si{sub 6}H{sub 12} (CHS). The growth rate of a-Si:H was studied as a function of substrate temperatures in the range of 30 C < T < 450 C using deposition conditions that were optimized for monosilane SiH{sub 4}. The same parameters were used for a-Si:H films grown using disilane (Si{sub 2}H{sub 6}) and trisilane (Si{sub 3}H{sub 8}) precursors. It was found that the a-Si:H film growth rate for CHS is lower with respect to those for mono-, di- and trisilane in an Ar plasma. Addition of {approx}10% of H{sub 2} dramatically increases the deposition rate for CHS-based films to {_}nm/min - a 700% increase. The as-deposited films were characterized by FTIR and Raman spectroscopy to probe the hydrogen content and local bonding environment. It was found that the films grown using Ar/H{sub 2} mixtures as carrier gas have a reduced hydrogen content relative to polysilane fragments indicating higher quality amorphous silicon.

Konstantin Pokhodnya; Joseph Sandstrom; Xuliang Dai; Philip Boudjouk; Douglas L. Schulz

2009-06-08T23:59:59.000Z

73

UNDERSTANDING CURE INHIBITION IN CARBON FIBER REINFORCED VINYL ESTER RESIN COMPOSITES.  

E-Print Network (OSTI)

??The effect of neat and oxidized carbon fiber reinforcements on vinyl ester resin free radical polymerization was investigated. First, the free radical polymerization of neat… (more)

Tweed-Kent, Sean

2008-01-01T23:59:59.000Z

74

An unusual mono-substituted Keggin anion-chain based 3D framework with 24-membered macrocycles as linker units  

Science Conference Proceedings (OSTI)

A new compound, [Cu{sup I}(H{sub 2}O)(Hbpp){sub 2}] Subset-Of {l_brace}[Cu{sup I}(bpp)]{sub 2}[PW{sub 11}Cu{sup II}O{sub 39}]{r_brace} (1) (bpp=1,3-bis(4-pyridyl)propane), has been hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction. In compound 1, the unusual -A-B-A-B- array mono-substituted Keggin anion-chains and 24-membered (Cubpp){sub 2} cation-macrocycles are linked together to form a (2, 4) connected 3D framework with channels of ca. 9.784 Multiplication-Sign 7.771 A{sup 2} along two directions, in which the [Cu(H{sub 2}O)(Hbpp){sub 2}] coordination fragments as guest components are trapped. The photocatalytic experiments of compound 1 were performed, which show a good catalytic activity of compound 1 for photodegradation of RhB. Furthermore, the IR, TGA and electrochemical properties of compound 1 were investigated. - Graphical abstract: An unusual example of mono-substituted Keggin anion-chain based hybrid compound that possesses a 3D structure has been synthesized, which offers a feasible route for synthesis of such compounds. Highlights: Black-Right-Pointing-Pointer The first example of -A-B-A-B- array mono-substituted Keggin chain is observed. Black-Right-Pointing-Pointer An unusual three dimensional structure based mono-substituted Keggin anion-chains. Black-Right-Pointing-Pointer The photocatalysis and electrochemical properties of the title compound were studied.

Pang Haijun [Key Laboratory of Green Chemical Engineering and Technology College of Heilongjiang Province, College of Chemical and Environmental Engineering, Harbin University of Science and Technology, Harbin 150040 (China); Ma Huiyuan, E-mail: mahy017@163.com [Key Laboratory of Green Chemical Engineering and Technology College of Heilongjiang Province, College of Chemical and Environmental Engineering, Harbin University of Science and Technology, Harbin 150040 (China); Yu Yan; Yang Ming; Xun Ye [Key Laboratory of Green Chemical Engineering and Technology College of Heilongjiang Province, College of Chemical and Environmental Engineering, Harbin University of Science and Technology, Harbin 150040 (China); Liu Bo, E-mail: liubo200400@vip.sina.com [Key Laboratory of Green Chemical Engineering and Technology College of Heilongjiang Province, College of Chemical and Environmental Engineering, Harbin University of Science and Technology, Harbin 150040 (China)

2012-02-15T23:59:59.000Z

75

Solid catalyzed isoparaffin alkylation at supercritical fluid and near-supercritical fluid conditions  

DOE Patents (OSTI)

This invention relates to an improved method for the alkylation reaction of isoparaffins with olefins over solid catalysts including contacting a mixture of an isoparaffin, an olefin and a phase-modifying material with a solid acid catalyst member under alkylation conversion conditions at either supercritical fluid, or near-supercritical fluid conditions, at a temperature and a pressure relative to the critical temperature(T.sub.c) and the critical pressure(P.sub.c) of the reaction mixture. The phase-modifying phase-modifying material is employed to promote the reaction's achievement of either a supercritical fluid state or a near-supercritical state while simultaneously allowing for decreased reaction temperature and longer catalyst life.

Ginosar, Daniel M. (Idaho Falls, ID); Fox, Robert V. (Idaho Falls, ID); Kong, Peter C. (Idaho Falls, ID)

2000-01-01T23:59:59.000Z

76

Workshop on the Increased Use of Ethanol and Alkylates in Automotive Fuels in California  

SciTech Connect

The goals of the Workshop are to: (1) Review the existing state of knowledge on (a) physicochemical properties, multi-media transport and fate, exposure mechanisms and (b) release scenarios associated with the production, distribution, and use of ethanol and alkylates in gasoline; (2) Identify key regulatory, environmental, and resource management issues and knowledge gaps associated with anticipated changes in gasoline formulation in California; and (3) Develop a roadmap for addressing issues/knowledge gaps.

Rice, D W

2001-05-04T23:59:59.000Z

77

Synthesis of acid addition salt of delta-aminolevulinic acid from 5-bromo levulinic acid esters  

DOE Patents (OSTI)

A process of preparing an acid addition salt of delta-aminolevulinc acid comprising: a) dissolving a lower alkyl 5-bromolevulinate and hexamethylenetetramine in a solvent selected from the group consisting of water, ethyl acetate, chloroform, acetone, ethanol, tetrahydrofuran and acetonitrile, to form a quaternary ammonium salt of the lower alkyl 5-bromolevulinate; and b) hydrolyzing the quaternary ammonium salt with an inorganic acid to form an acid addition salt of delta-aminolevulinic acid.

Moens, Luc (Lakewood, CO)

2003-06-24T23:59:59.000Z

78

Anti-friction properties of ester additives during hot rolling of aluminum{copyright}  

Science Conference Proceedings (OSTI)

Heavy esters of polyhydric alcohols, such as glycerol and synthetic polyols, are commonly used as additives in aluminum hot rolling lubricants. The presence of several hydroxyl groups allows a varying degree of esterification leading to the formation of full and partial esters. These esters are rarely separated from the main additive, and thus may be present in the finished rolling lubricant, affecting its anti-friction properties. The objective of this work was to examine the anti-friction properties of these potential ester contaminants during rolling on a laboratory hot rolling mill. Two lubricant application methods were examined; as emulsion and direct (neat oil) application. The anti-friction properties of additives were found to depend on their chemical structure and the lubricant applications method. In emulsified oils, partial esters of glycerol were found to greatly reduce friction in comparison to triglycerides, while the partial esters of synthetic polyols exhibited only a weak anti-friction effect. There was no frictional advantage observed which could be associated with using the partial esters in direct application mode. Moreover, under these conditions, the anti-friction properties of the completely esterified synthetic polyols were significantly lower than those of triglycerides, while in emulsions they were comparable. 11 refs., 7 figs., 3 tabs.

Januszkiewicz, K.R.; Bekmesian, G.; Heenan, D.F. [Alcan International Limited, Ontario (Canada)] [and others

1995-08-01T23:59:59.000Z

79

Biodiesel Basics | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Biodiesel Basics Biodiesel Basics Biodiesel Basics July 30, 2013 - 2:43pm Addthis Looking for Biodiesel stations? Checkout the Alternative Fuels Data Center station locator. Biodiesel station locator Biodiesel is a domestically produced, renewable fuel that can be manufactured from vegetable oils, animal fats, or recycled restaurant greases. What is Biodiesel? Biodiesel is a liquid fuel made up of fatty acid alkyl esters, fatty acid methyl esters, or long-chain mono alkyl esters. It is produced from renewable sources such as new and used vegetable oils and animal fats and is a cleaner-burning replacement for petroleum-based diesel fuel. It is nontoxic and biodegradable. Like petroleum diesel, biodiesel is used to fuel compression-ignition (diesel) engines. B20, which is 20% biodiesel and 80% petroleum diesel, is

80

Anticancer activity of botanical alkyl hydroquinones attributed to topoisomerase II poisoning  

SciTech Connect

Cytotoxic alkyl hydroquinone compounds have been isolated from many plants. We previously isolated 3 structurally similar cytotoxic alkyl hydroquinone compounds from the sap of the lacquer tree Rhus succedanea L. belonging to the sumac family, which have a long history of medicinal use in Asia. Each has an unsaturated alkyl chain attached to the 2-position of a hydroquinone ring. One of these isolates, 10'(Z),13'(E),15'(E)-heptadecatrienylhydroquinone [HQ17(3)], being the most cytotoxic, was chosen for studying the anticancer mechanism of these compounds. We found that HQ17(3) was a topoisomerase (Topo) II poison. It irreversibly inhibited Topo II{alpha} activity through the accumulation of Topo II-DNA cleavable complexes. A cell-based assay showed that HQ17(3) inhibited the growth of leukemia HL-60 cells with an EC{sub 50} of 0.9 {mu}M, inhibited the topoisomerase-II-deficient cells HL-60/MX2 with an EC{sub 50} of 9.6 {mu}M, and exerted no effect on peripheral blood mononuclear cells at concentrations up to 50 {mu}M. These results suggest that Topo II is the cellular drug target. In HL-60 cells, HQ17(3) promptly inhibited DNA synthesis, induced chromosomal breakage, and led to cell death with an EC{sub 50} about one-tenth that of hydroquinone. Pretreatment of the cells with N-acetylcysteine could not attenuate the cytotoxicity and DNA damage induced by HQ17(3). However, N-acetylcysteine did significantly reduce the cytotoxicity of hydroquinone. In F344 rats, intraperitoneal injection of HQ17(3) for 28 days induced no clinical signs of toxicity. These results indicated that HQ17(3) is a potential anticancer agent, and its structural features could be a model for anticancer drug design.

Huang, C.-P. [Department of Clinical Laboratory Sciences and Medical Biotechnology, National Taiwan University, Taipei, Taiwan (China); Fang, W.-H.; Lin, L.-I. [Department of Clinical Laboratory Sciences and Medical Biotechnology, National Taiwan University, Taipei, Taiwan (China); Department of Laboratory Medicine, National Taiwan University Hospital, National Taiwan University, Taipei, Taiwan (China); Chiou, Robin Y. [Department of Food Science, National Chiayi University, Chiayi, Taiwan (China); Kan, L.-S. [Institute of Chemistry, Academia Sinica, Taipei, Taiwan (China); Chi, N.-H.; Chen, Y.-R.; Lin, T.-Y. [Department of Clinical Laboratory Sciences and Medical Biotechnology, National Taiwan University, Taipei, Taiwan (China); Lin, S.-B. [Department of Clinical Laboratory Sciences and Medical Biotechnology, National Taiwan University, Taipei, Taiwan (China); Department of Laboratory Medicine, National Taiwan University Hospital, National Taiwan University, Taipei, Taiwan (China)], E-mail: sblin@ntu.edu.tw

2008-03-15T23:59:59.000Z

Note: This page contains sample records for the topic "mono alkyl ester" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Epoxidized Glycidyl Esters of Soy/Linseed Oil: Synthesis and Thermal Properties  

Science Conference Proceedings (OSTI)

Synthesis and Properties of Glycidyl Esters of Epoxidized Fatty Acids Rongpeng Wang & Thomas Schuman Department of Chemistry Missouri University of Science and Technology (Formerly University of Missouri-Rolla) A Sustainable Polymer Industr

82

Plug repairs of marine glass fiber / vinyl ester laminates subjected to uniaxial tension  

E-Print Network (OSTI)

Glass fiber/vinyl ester composite laminates are currently being used and proposed for the hulls, bulkheads, and superstructures of large ships. This thesis examines the effectiveness of the repair of such laminates using ...

Michelis, Alexandros

2009-01-01T23:59:59.000Z

83

Emulsion polymerization of ethylene-vinyl acetate-branched vinyl ester using a pressure reactor system.  

E-Print Network (OSTI)

??A new pressure reactor system was designed to synthesize a novel branched ester-ethylene-vinyl acetate (BEEVA) emulsion polymer. The reactor system was capable of handling pressure… (more)

Tan, Chee Boon.

2008-01-01T23:59:59.000Z

84

High-Octane Fuel from Refinery Exhaust Gas: Upgrading Refinery Off-Gas to High-Octane Alkylate  

Science Conference Proceedings (OSTI)

Broad Funding Opportunity Announcement Project: Exelus is developing a method to convert olefins from oil refinery exhaust gas into alkylate, a clean-burning, high-octane component of gasoline. Traditionally, olefins must be separated from exhaust before they can be converted into another source of useful fuel. Exelus’ process uses catalysts that convert the olefin to alkylate without first separating it from the exhaust. The ability to turn up to 50% of exhaust directly into gasoline blends could result in an additional 46 million gallons of gasoline in the U.S. each year.

None

2009-12-01T23:59:59.000Z

85

Effect of radical fluorination on mono- and bi-layer graphene in Ar/F{sub 2} plasma  

SciTech Connect

Fluorinated graphene has the possibility to achieve unique properties and functions in graphene. We propose a highly controlled fluorination method utilizing fluorine radicals in Ar/F{sub 2} plasma. To suppress ion bombardments and improve the reaction with fluorine radicals on graphene, the substrate was placed 'face down' in the plasma chamber. Although monolayer graphene was more reactive than bilayer, fluorination of bilayer reached the level of I{sub D}/I{sub G} {approx} 0.5 in Raman D peak intensity at 532 nm excitation. Annealing fluorinated samples proved reversibility of radical fluorination for both mono- and bi-layer graphenes. X-ray photoelectron spectroscopy showed the existence of carbon-fluorine bonding.

Tahara, K.; Iwasaki, T.; Hatano, M. [Department of Physical Electronics, Tokyo Institute of Technology, Tokyo 152-8552 (Japan); Matsutani, A. [Semiconductor and MEMS Processing Center, Technical Department, Tokyo Institute of Technology, Tokyo 226-8503 (Japan)

2012-10-15T23:59:59.000Z

86

Self-cooling mono-container fuel cell generators and power plants using an array of such generators  

DOE Patents (OSTI)

A mono-container fuel cell generator (10) contains a layer of interior insulation (14), a layer of exterior insulation (16) and a single housing (20) between the insulation layers, where fuel cells, containing electrodes and electrolyte, are surrounded by the interior insulation (14) in the interior (12) of the generator, and the generator is capable of operating at temperatures over about 650.degree. C., where the combination of interior and exterior insulation layers have the ability to control the temperature in the housing (20) below the degradation temperature of the housing material. The housing can also contain integral cooling ducts, and a plurality of these generators can be positioned next to each other to provide a power block array with interior cooling.

Gillett, James E. (Greensburg, PA); Dederer, Jeffrey T. (Valencia, PA); Zafred, Paolo R. (Pittsburgh, PA)

1998-01-01T23:59:59.000Z

87

Self-cooling mono-container fuel cell generators and power plants using an array of such generators  

DOE Patents (OSTI)

A mono-container fuel cell generator contains a layer of interior insulation, a layer of exterior insulation and a single housing between the insulation layers, where fuel cells, containing electrodes and electrolyte, are surrounded by the interior insulation in the interior of the generator, and the generator is capable of operating at temperatures over about 650 C, where the combination of interior and exterior insulation layers have the ability to control the temperature in the housing below the degradation temperature of the housing material. The housing can also contain integral cooling ducts, and a plurality of these generators can be positioned next to each other to provide a power block array with interior cooling. 7 figs.

Gillett, J.E.; Dederer, J.T.; Zafred, P.R.

1998-05-12T23:59:59.000Z

88

Fluoroalkyl and Alkyl Chains Have Similar Hydrophobicities in Binding to the “Hydrophobic Wall” of Carbonic Anhydrase  

DOE Green Energy (OSTI)

The hydrophobic effect, the free-energetically favorable association of nonpolar solutes in water, makes a dominant contribution to binding of many systems of ligands and proteins. The objective of this study was to examine the hydrophobic effect in biomolecular recognition using two chemically different but structurally similar hydrophobic groups, aliphatic hydrocarbons and aliphatic fluorocarbons, and to determine whether the hydrophobicity of the two groups could be distinguished by thermodynamic and biostructural analysis. This paper uses isothermal titration calorimetry (ITC) to examine the thermodynamics of binding of benzenesulfonamides substituted in the para position with alkyl and fluoroalkyl chains (H{sub 2}NSO{sub 2}C{sub 6}H{sub 4}-CONHCH{sub 2}(CX{sub 2}){sub n}CX{sub 3}, n = 0-4, X = H, F) to human carbonic anhydrase II (HCA II). Both alkyl and fluoroalkyl substituents contribute favorably to the enthalpy and the entropy of binding; these contributions increase as the length of chain of the hydrophobic substituent increases. Crystallography of the protein-ligand complexes indicates that the benzenesulfonamide groups of all ligands examined bind with similar geometry, that the tail groups associate with the hydrophobic wall of HCA II (which is made up of the side chains of residues Phe131, Val135, Pro202, and Leu204), and that the structure of the protein is indistinguishable for all but one of the complexes (the longest member of the fluoroalkyl series). Analysis of the thermodynamics of binding as a function of structure is compatible with the hypothesis that hydrophobic binding of both alkyl and fluoroalkyl chains to hydrophobic surface of carbonic anhydrase is due primarily to the release of nonoptimally hydrogen-bonded water molecules that hydrate the binding cavity (including the hydrophobic wall) of HCA II and to the release of water molecules that surround the hydrophobic chain of the ligands. This study defines the balance of enthalpic and entropic contributions to the hydrophobic effect in this representative system of protein and ligand: hydrophobic interactions, here, seem to comprise approximately equal contributions from enthalpy (plausibly from strengthening networks of hydrogen bonds among molecules of water) and entropy (from release of water from configurationally restricted positions).

J Mecinovic; P Snyder; K Mirica; S Bai; E Mack; R Kwant; D Moustakas; A Heroux; G Whitesides

2011-12-31T23:59:59.000Z

89

Raman Scattering Sensor for Control of the Acid Alkylation Process in Gasoline Production  

SciTech Connect

Gasoline refineries utilize a process called acid alkylation to increase the octane rating of blended gasoline, and this is the single most expensive process in the refinery. For process efficiency and safety reasons, the sulfuric acid can only be used while it is in the concentration range of 98 to 86 %. The conventional technique to monitor the acid concentration is time consuming and is typically conducted only a few times per day. This results in running higher acid concentrations than they would like to ensure that the process proceeds uninterrupted. Maintaining an excessively high acid concentration costs the refineries millions of dollars each year. Using SBIR funding, Process Instruments Inc. has developed an inline sensor for real time monitoring of acid concentrations in gasoline refinery alkylation units. Real time data was then collected over time from the instrument and its responses were matched up with the laboratory analysis. A model was then developed to correlate the laboratory acid values to the Raman signal that is transmitted back to the instrument from the process stream. The instrument was then used to demonstrate that it could create real-time predictions of the acid concentrations. The results from this test showed that the instrument could accurately predict the acid concentrations to within ~0.15% acid strength, and this level of prediction proved to be similar or better then the laboratory analysis. By utilizing a sensor for process monitoring the most economic acid concentrations can be maintained. A single smaller refinery (50,000 barrels/day) estimates that they should save over $120,000/year, with larger refineries saving considerably more.

Uibel, Rory, H.; Smith, Lee M.; Benner, Robert, E.

2006-04-19T23:59:59.000Z

90

An investigation in the hygrothermal degradation of an E- glass/vinyl-ester composite in humid and immersion environments  

E-Print Network (OSTI)

relaxation behavior on sized carbon fiber-vinyl ester matrixaspects of epoxy- carbon fiber composite laminates inaspects of epoxy/carbon fiber composite laminates in

Svetlik, Stephanie Laura

2008-01-01T23:59:59.000Z

91

Viscosity of aqueous and cyanate ester suspensions containing alumina nanoparticles  

DOE Green Energy (OSTI)

The viscosities of both aqueous and cyanate ester monomer (BECy) based suspensions of alumina nanoparticle were studied. The applications for these suspensions are different: aqueous suspensions of alumina nanoparticles are used in the production of technical ceramics made by slip casting or tape casting, and the BECy based suspensions are being developed for use in an injection-type composite repair resin. In the case of aqueous suspensions, it is advantageous to achieve a high solids content with low viscosity in order to produce a high quality product. The addition of a dispersant is useful so that higher solids content suspensions can be used with lower viscosities. For BECy suspensions, the addition of nanoparticles to the BECy resin is expected to enhance the mechanical properties of the cured composite. The addition of saccharides to aqueous suspensions leads to viscosity reduction. Through DSC measurements it was found that the saccharide molecules formed a solution with water and this resulted in lowering the melting temperature of the free water according to classic freezing point depression. Saccharides also lowered the melting temperature of the bound water, but this followed a different rule. The shear thinning and melting behaviors of the suspensions were used to develop a model based on fractal-type agglomeration. It is believed that the structure of the particle flocs in these suspensions changes with the addition of saccharides which leads to the resultant viscosity decrease. The viscosity of the BECy suspensions increased with solids content, and the viscosity increase was greater than predicted by the classical Einstein equation for dilute suspensions. Instead, the Mooney equation fits the viscosity behavior well from 0-20 vol% solids. The viscosity reduction achieved at high particle loadings by the addition of benzoic acid was also investigated by NMR. It appears that the benzoic acid interacts with the surface of the alumina particle which may be the cause of the viscosity reduction. The flow behavior of alumina particles in water and BECy is markedly different. Aqueous alumina suspensions are shear thinning at all alumina loadings and capable of 50 vol% loading before losing fluidity whereas BECy/alumina suspensions show Newtonian behavior up to 5 vol%, and above 5 vol% show shear thinning at all shear rates. Highly loaded suspensions (i.e. 20vol% alumina) exhibit shear thinning at low and moderate shear rates and shear thickening at higher shear rates. The maximum particle loading for a fluid suspension, in this case, appears to be about 20 vol%. The difference in the viscosity of these suspensions must be related to the solvent-particle interactions for each system. The reason is not exactly known, but there are some notable differences between BECy and water. Water molecules are {approx}0.28 nm in length and highly hydrogen bonded with a low viscosity (1 mPa's) whereas in the cyanate ester (BECy) system, the solvent molecule is about 1.2 nm, in the largest dimension, with surfaces of varied charge distribution throughout the molecule. The viscosity of the monomer is also reasonably low for organic polymer precursor, about 7 mPa's. Nanoparticles in water tend to agglomerate and form flocs which are broken with the shear force applied during viscosity measurement. The particle-particle interaction is very important in this system. In BECy, the particles appear to be well dispersed and not as interactive. The solvent-particle interaction appears to be most important. It is not known exactly how the alumina particles interact with the monomer, but NMR suggests hydrogen bonding. These hydrogen bonds between the particle and monomer could very well affect the viscosity. A conclusion that can be reached in this work is that the presence of hydroxyl groups on the surface of the alumina particles is significant and seems to affect the interactions between other particles and the solvent. Thus, the hydrogen bonding between particles, particle/additive and/or particle/solvent dictates the behavior of nanos

Lawler, Katherine

2009-08-05T23:59:59.000Z

92

ESTER, Enel integrated System for TEsts on stoRage (Smart Grid Project) |  

Open Energy Info (EERE)

ESTER, Enel integrated System for TEsts on stoRage (Smart Grid Project) ESTER, Enel integrated System for TEsts on stoRage (Smart Grid Project) Jump to: navigation, search Project Name ESTER, Enel integrated System for TEsts on stoRage Country Italy Headquarters Location Livorno, Italy Coordinates 43.551876°, 10.308011° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":43.551876,"lon":10.308011,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

93

Process for the generation of .alpha., .beta.-unsaturated carboxylic acids and esters using niobium catalyst  

DOE Patents (OSTI)

A process using a niobium catalyst includes the step of reacting an ester or carboxylic acid with oxygen and an alcohol in the presence a niobium catalyst to respectively produce an .alpha.,.beta.-unsaturated ester or carboxylic acid. Methanol may be used as the alcohol, and the ester or carboxylic acid may be passed over the niobium catalyst in a vapor stream containing oxygen and methanol. Alternatively, the process using a niobium catalyst may involve the step of reacting an ester and oxygen in the presence the niobium catalyst to produce an .alpha.,.beta.-unsaturated carboxylic acid. In this case the ester may be a methyl ester. In either case, niobium oxide may be used as the niobium catalyst with the niobium oxide being present on a support. The support may be an oxide selected from the group consisting of silicon oxide, aluminum oxide, titanium oxide and mixtures thereof. The catalyst may be formed by reacting niobium fluoride with the oxide serving as the support. The niobium catalyst may contain elemental niobium within the range of 1 wt % to 70 wt %, and more preferably within the range of 10 wt % to 30 wt %. The process may be operated at a temperature from 150 to 450.degree. C. and preferably from 250 to 350.degree. C. The process may be operated at a pressure from 0.1 to 15 atm. absolute and preferably from 0.5-5 atm. absolute. The flow rate of reactants may be from 10 to 10,000 L/kg.sub.(cat) /h, and preferably from 100 to 1,000 L/kg.sub.(cat) /h.

Gogate, Makarand Ratnakav (Durham, NC); Spivey, James Jerome (Cary, NC); Zoeller, Joseph Robert (Kingsport, TN)

1999-01-01T23:59:59.000Z

94

Lower hybrid instability driven by mono-energy {alpha}-particles with finite pitch angle spread in a plasma  

Science Conference Proceedings (OSTI)

A kinetic formalism of lower hybrid wave instability, driven by mono-energy {alpha}-particles with finite pitch angle spread, is developed. The instability arises through cyclotron resonance interaction with high cyclotron harmonics of {alpha}-particles. The {alpha}-particles produced in D-T fusion reactions have huge Larmor radii ({approx}10 cm) as compared to the wavelength of the lower hybrid wave, whereas their speed is an order of magnitude smaller than the speed of light in vacuum. As a result, large parallel phase velocity lower hybrid waves, suitable for current drive in tokamak, are driven unstable via coupling to high cyclotron harmonics. The growth rate decreases with increase in pitch angle spread of the beam. At typical electron density of {approx}10{sup 19} m{sup -3}, magnetic field {approx}4 Tesla and {alpha}-particle concentration {approx}0.1%, the large parallel phase velocity lower hybrid wave grows on the time scale of 20 ion cyclotron periods. The growth rate decreases with plasma density.

Kumar, Pawan; Singh, Vishwesh; Tripathi, V. K. [Department of Physics, IIT Delhi, New Delhi-110016 (India)

2013-02-15T23:59:59.000Z

95

Transition metal ion-assisted photochemical generation of alkyl halides and hydrocarbons from carboxylic acids  

Science Conference Proceedings (OSTI)

Near-UV photolysis of aqueous solutions of propionic acid and aqueous Fe3+ in the absence of oxygen generates a mixture of hydrocarbons (ethane, ethylene and butane), carbon dioxide, and Fe2+. The reaction becomes mildly catalytic (about five turnovers) in the presence of oxygen which converts a portion of alkyl radicals to oxidizing intermediates that reoxidize Fe2+. The photochemistry in the presence of halide ions (X? = Cl?, Br?) generates ethyl halides via halogen atom abstraction from FeXn3?n by ethyl radicals. Near-quantitative yields of C2H5X are obtained at ?0.05 M X?. Competition experiments with Co(NH3)5Br2+ provided kinetic data for the reaction of ethyl radicals with FeCl2+ (k = (4.0 ± 0.5) × 106 M?1 s?1) and with FeBr2+ (k = (3.0 ± 0.5) × 107 M?1 s?1). Photochemical decarboxylation of propionic acid in the presence of Cu2+ generates ethylene and Cu+. Longer-chain acids also yield alpha olefins as exclusive products. These reactions become catalytic under constant purge with oxygen which plays a dual role. It reoxidizes Cu+ to Cu2+, and removes gaseous olefins to prevent accumulation of Cu+(olefin) complexes and depletion of Cu2+. The results underscore the profound effect that the choice of metal ions, the medium, and reaction conditions exert on the photochemistry of carboxylic acids.

Carraher, Jack; Pestovsky, Oleg; Bakac, Andreja

2012-03-14T23:59:59.000Z

96

Experimental and Computational Thermochemical Study of 2-and 3-Thiopheneacetic Acid Methyl Esters  

E-Print Network (OSTI)

, biodiagnostics, electronic and optoelectronic devices, and conductive polymers. The present study reports acid methyl esters. The enthalpies of combustion and vaporization were measured by a rotating-bomb of the compounds studied was carried out. Calculated enthalpies of formation, using atomization and isodesmic

Chickos, James S.

97

Lithium Diisopropylamide-Mediated Reactions of Imines, Unsaturated Esters, Epoxides, and Aryl Carbamates  

E-Print Network (OSTI)

Lithium Diisopropylamide-Mediated Reactions of Imines, Unsaturated Esters, Epoxides, and Aryl: Several reactions mediated by lithium diisopropylamide (LDA) with added hexamethylphos- phoramide (HMPA, and selectivities of organolithium reactions.1 A preponderance of what is known about solvation of lithium ions

Collum, David B.

98

Combustion chemical kinetics of biodiesel and related compounds (methyl and ethyl esters): Experiments and  

E-Print Network (OSTI)

1 Combustion chemical kinetics of biodiesel and related compounds (methyl and ethyl esters and reduced exhaust emissions have led to the emergence of new fuels and combustion devices. Over the past ten years, considerable effort has gone into understanding combustion phenomena in relation to emerging fuel

99

Carcinogenic heavy metals replace Ca{sup 2+} for DNA binding and annealing activities of mono-ubiquitinated annexin A1 homodimer  

Science Conference Proceedings (OSTI)

Mono-ubiquitinated annexin A1 was purified from rat liver nuclei. The homodimer form of mono-ubiquitinated annexin A1 was able to unwind dsDNA in a Mg{sup 2+}- and ATP-dependent manner, and to anneal ssDNA in a Ca{sup 2+}-dependent manner. Phospholipids decreased the concentration of Ca{sup 2+} required for maximal annealing activity. Heavy metals such as As{sup 3+}, Cr{sup 6+}, Pb{sup 2+} and Cd{sup 2+} substituted for Ca{sup 2+} in the ssDNA binding and annealing activities of annexin A1. While these metals inhibited the unwinding of dsDNA by nuclear annexin A1 in the presence of Mg{sup 2+} and ATP, they enhanced dsDNA-dependent ATPase activity of annexin A1. Heavy metals may have produced dsDNA, a substrate for the DNA unwinding reaction, via the DNA annealing reaction. DNA synthesomes were isolated from L5178Y tk(+/-) mouse lymphoma cells in exponential growth, and were found to contain helicase activities. The As{sup 3+}- or Cr{sup 6+}-induced increases in ssDNA binding activity of DNA synthesomes were reduced by a mono-specific anti-annexin A1 antibody, but not by anti-Ig antibody. Anti-annexin A1 antibody also blocked the inhibitory and stimulatory effects of As{sup 3+} or Cr{sup 6+} towards DNA unwinding and annealing activities of DNA synthesomes. Based on these observations, it can be concluded that the effects of heavy metals on DNA annealing and unwinding activities are mediated, at least in substantial part, through actions of the mono-ubiquitinated annexin A1 homodimer.

Hirata, Aiko; Corcoran, George B.; Hirata, Fusao, E-mail: fhirata@wayne.ed

2010-10-01T23:59:59.000Z

100

Coupled Dynamic Analysis of Large-Scale Mono-Column Offshore Wind Turbine with a Single Tether Hinged in Seabed  

E-Print Network (OSTI)

The increased interest in the offshore wind resource in both industry and academic and the extension of the wind field where offshore wind turbine can be deployed has stimulated quite a number of offshore wind turbines concepts. This thesis presents a design of mono-column platform supported for 5 MW baseline wind turbine developed by the National Renewable Energy Laboratory (NREL), with a single tether anchored to the seabed. The design, based on the pioneer concept SWAY, results from parametric optimized design processes which account for important design considerations in the static and dynamic view, such as the stability, natural frequency, performance requirements as well as the economic feasibility. Fully coupled aero-hydro-servo-elastic model is established in the time-domain simulation tool FAST (Fatigue, Aerodynamics, Structures, and Turbulence) with the hydrodynamic coefficients from HydroGen, an indoor program providing same outputs as the commercial software WAMIT. The optimized model is verified by imitating the frequency-domain approach in FAST and thus comparing the results with the frequency-domain calculations. A number of simulations with various wind and wave conditions are run to explore the effect of wind speed and wave significant height in various water depths. By modifying the optimized model to a downwind turbine with the nacelle rigidly mounted on the tower and the single tether connected to the platform by a subsea swivel, the modified models are more closed to the original SWAY-concept wind turbine. These models are compared based on the platform motion, tether tension, displacement, nacelle velocity and acceleration, resonant behavior as well as the damping of the coupled systems. The results of these comparisons prove the advantage of the modified model in performance. The modified model has also clarified itself a good candidate for deep water deployment.

Chen, Jieyan

2012-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "mono alkyl ester" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Retention indices, relative response factors, and mass spectra of trifluoroethyl and heptafluorobutyl esters of carboxylic acids determined by capillary GC/MS  

SciTech Connect

The GC/MS characteristics of carboxylic acid esters prepared from fluorine-containing alcohols were compared to those of methyl esters. The GC retention of 2,2,2-trifluoroethyl (TFE) esters was less than, and 2,2,3,3,4,4,4-heptafluoro-1-butyl (HFB) esters approximately equivalent to that of methyl esters. The peak shape of both TFE and HFB esters was slightly superior to that of methyl esters. Mass spectra of TFE and HFB aliphatic esters show significantly more intense molecular and key fragment ions than those of methyl esters. Also, owing to their significantly higher molecular weights, TFE or HFB ester molecular ions and most fragment ions of interest occur at significantly higher m/z values than most potential interfering ions. The GC retention indices, relative GC/MS total ion current response factors, and 70 eV electron impact mass spectra of about 70 TFE and 70 HFB carboxylic acid esters are reported. Results from analysis of a TFE/HFB esterified petroleum carboxylic acid concentrate are discussed in detail. 26 refs., 17 figs., 3 tabs.

Yu, S.K.-T.; Vrana, R.P.; Green, J.B.

1990-11-01T23:59:59.000Z

102

Evaluation of bisphenol E cyanate ester for the resin-injection repair of advanced composites  

SciTech Connect

This thesis is a compilation of a general introduction and literature review that ties together the subsequent chapters which consist of two journal articles that have yet to be submitted for publication. The overall topic relates to the evaluation and application of a new class of cyanate ester resin with unique properties that lend it applicable to use as a resin for injection repair of high glass transition temperature polymer matrix composites. The first article (Chapter 2) details the evaluation and optimization of adhesive properties of this cyanate ester and alumina nanocomposites under different conditions. The second article (Chapter 3) describes the development and evaluation of an injection repair system for repairing delaminations in polymer matrix composites.

Wilber Yaote Lio

2009-12-19T23:59:59.000Z

103

Grease Basics  

Science Conference Proceedings (OSTI)

...Silicones Chlorofluorocarbon Alkylated benzene Phosphate esters Polyphenyl ethers Chemical structures are shown in Fig. 4, whereas Table 2

104

Single event kinetic modeling of solid acid alkylation of isobutane with butenes over proton-exchanged Y-Zeolites  

E-Print Network (OSTI)

Complex reaction kinetics of the solid acid alkylation of isobutane with butenes over a proton-exchanged Y-zeolite has been modeled at the elementary step level. Starting with a computer algorithm that generated the reaction network based on the fundamentals of the carbenium ion chemistry, the formation of over 100+ product species has been modeled in order to gain understanding of the underlying phenomena leading to rapid catalyst deactivation and product selectivity shifts observed in experimental runs. An experimental investigation of the solid acid alkylation process was carried out in a fixed bed catalytic reactor operating with an excess of isobutane under isothermal conditions at moderate temperatures (353-393 K) in liquid phase. Experimental data varying with run-time for a set of butene space-times and reaction temperatures were collected for parameter estimation purposes. A kinetic model was formulated in terms of rate expressions at the elementary step level including a rigorous modeling of deactivation through site coverage. The single event concept was applied to each rate coefficient at the elementary step level to achieve a significant reduction in the number of model parameters. Based on the identification of structural changes leading to the creation or destruction of symmetry axes and chiral centers in an elementary step, formulae have been developed for the calculation of the number of single events. The Evans-Polanyi relationship and the concept of stabilization energy were introduced to account for energy levels in surface-bonded carbenium ions. A novel functional dependency of the stabilization energy with the nature of the carbenium ion and the carbon number was proposed to account for energy effects from the acid sites on the catalyst. Further reductions in the number of parameters and simplification of the equations for the transient pseudohomogeneous one-dimensional plug-flow model of the reactor were achieved by means of thermodynamic constraints. Altogether, the single event concept, the Evans-Polanyi relationship, the stabilization energy approach and the thermodynamic constraints led to a set of 14 parameters necessary for a complete description of solid acid alkylation at the elementary step level.

Martinis Coll, Jorge Maximiliano

2004-12-01T23:59:59.000Z

105

Selected alkyl(phenyl)-N,N-dialkylcarbamoylmethylphosphine oxides as extractants for Am(III) from nitric acid media  

SciTech Connect

A new series of neutral bifunctional extractants, alkyl(phenyl)-N,N-dialkyl-carbamoylmethylphosphine oxides, has been prepared and studied as extractants for Am(III) from nitric acid media. Two types of alkyl(phenyl)-N,N-dialkyl CMPO compounds were prepared, one containing N,N-diethyl groups and the other containing N,N-diisobutyl groups. The N,N-diethyl series contained hexyl(phenyl) and 6-methylheptyl(phenyl) derivatives, abbreviated H phi DECMPO and 6-MH phi DECMPO, respectively. The N,N-diisobutyl series contained the n-octyl(phenyl), 6-methylheptyl(phenyl), and the 2-ethylhexyl(phenyl) derivatives, abbreviated O phi D(IB)CMPO, 6-MH phi D(IB)CMPO, and 2-EH phi D(IB)CMPO, respectively. Third power extractant dependencies for the extraction of Am(III) from 0.5 and 3 M HNO/sub 3/ were obtained at low (< 0.25 M) concentrations of extractant, but higher power dependencies were obtained above 0.25 M extractant from 3 M HNO/sub 3/. The H phi DECMPO, 6-MH phi DECMPO, 6-MH phi D(IB)CMPO, and O phi D(IB)CMPO (all 0.5 M in diethylbenzene (DEB)) are significantly better extractants than DHDECMPO for Am(III) from 1 to 6 M HNO/sub 3/. These same extractants have lower D/sub Am/ values than DHDECMPO at low acidities. H phi DECMPO and O phi D(IB)CMPO also have better selectivity for Am(III) over Fe(III) than DHDECMPO. H phi DECMPO in DEB has a strong tendency toward the formation of a second liquid organic phase on extracting macroconcentrations of Nd(III) and U(VI) from 3 M HNO/sub 3/; however, this behavior is substantially diminished with the O phi D(IB)CMPO and 6-MH phi D(IB)CMPO compounds.

Horwitz, E.P.; Kalina, D.G.; Kaplan, L.; Mason, G.W.; Diamond, H.

1982-01-01T23:59:59.000Z

106

Gas chromatographic determination of microamounts of glycols and their esters in aqueous medium using adsorption on activated charcoal  

SciTech Connect

Rapid growth of production of glycols and their derivatives, especially methyl and ethyl esters, and wide use of these substances in various branches of the national economy (1) inevitably necessitate analytical monitoring of their content in waste waters and various water bodies. The authors studied the scope of gas-chromatographic determination of microamounts of glycols and their esters in aqueous media at the sanitary standards level (10/sup -5/%) using activated charcoal for their adsorption concentration from aqueous solutions, desorption from the charcoal by ethanol, and evaporationconcentration of the alcoholic solutions. The quantitative concentration characteristics were studied with reference to ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, triethyleneglycol, tripropylene glycol, tetraethylene glycol, ethylcellosolve, ethyl carbitol, and monoethyl ester of triethylene glycol.

Begunov, G.A.; Titovskaya, V.N.; Galenko, A.V.

1987-11-10T23:59:59.000Z

107

1,4-Addition of Lithium Diisopropylamide to Unsaturated Esters: Role of Rate-Limiting Deaggregation, Autocatalysis,  

E-Print Network (OSTI)

1,4-Addition of Lithium Diisopropylamide to Unsaturated Esters: Role of Rate-Limiting Deaggregation, Autocatalysis, Lithium Chloride Catalysis, and Other Mixed Aggregation Effects Yun Ma, Alexander C. Hoepker.edu Abstract: Lithium diisopropylamide (LDA) in tetrahydrofuran at -78 °C undergoes 1,4-addition

Collum, David B.

108

Healthful LipidsChapter 29 Plant Stanol Ester as a Cholesterol-Lowering Ingredient of Benecol® Foods  

Science Conference Proceedings (OSTI)

Healthful Lipids Chapter 29 Plant Stanol Ester as a Cholesterol-Lowering Ingredient of Benecol® Foods Health Nutrition Biochemistry eChapters Health - Nutrition - Biochemistry AOCS Press 89C37A138F35620F9CA206DED39897BE AOCS Pre

109

Sensitive, coupled assay for plasminogen activator using a thiol ester substrate for plasmin  

SciTech Connect

Several assays for plasminogen activator employ a direct assay method. These are remarkably sensitive methods, yet they suffer in comparison to the sensitivity of coupled methods. Coupling the assay with plasminogen not only amplifies the sensitivity by the multiplicative effect of plasmin, but insures that only those proteases specific for plasminogen are assayed. The choice of substrate for plasmin is critical. A thiol ester substrate, thiobenzyl benzyloxy-carbonyl-L-lysinate (Z-Lys-SBzl), has been synthesized which combines high k/sub cat/ with alkaline stability. In an effort to characterize the plasminogen activator from hepatoma tissue culture (HTC) and its hormonally-controlled inhibitor, Z-Lys-SBzl was used in a coupled approach providing an assay which is superior to the /sup 125/I-fibrinolytic assay. It is also extremely sensitive to plasminogen activator and can be used for routine analysis of purification as well as kinetic and binding studies. (ERB)

Coleman, P L; Green, G D.J.

1980-01-01T23:59:59.000Z

110

Reaction pathway in vapour phase hydrogenation of maleic anhydride and its esters to {gamma}-butyrolactone  

SciTech Connect

The catalytic reactivity of maleic anhydride (MA), succinic anhydride (SA) and their dimethyl esters (dimethyl maleate and dimethyl succinate) in the vapour phase hydrogenation to {gamma}-butyrolacetone (GBL) was investigated. In order to obtain general data, both a multicomponent catalyst (CAT 1: Cu/Zn/Mg/Cr = 40:5:5:50, atomic ratio %), obtained by reduction of a nonstoichiometric spinel-type precursor, and a commercial catalyst (CAT 2: Cu/Mn/Ba/Cr = 44:8:1:47, atomic ratio %) were used. The MA/GBL solution exhibited the highest GBL production, while the SA/GBL solution was converted only partially due to a competitive adsorption of GBL on the active sites, as evidenced by the similar reactivities observed with pure anhydrides. The best carbon balances were observed with the esters, probably the result of lowest light hydrocarbon synthesis and tar formation. With all the feedstocks, the activity of CAT 2 is higher than that of CAT 1, which, however, gives the best yield in GBL due its lower activity in the overhydrogenation and hydrogenolysis reaction. It was found that n-butanol (BuOH) and butyric acid (BuA) derived mainly from GBL. On this basis, the reactivities of the main products observed were investigated separately, confirming the stability of tetrahydrofuran (THF), which reacted only at high temperature with low conversions to ethanol. On the other hand, GBL gave rise to overhydrogenation and/or hydrogenolysis, with high conversion (mainly with CAT 2), confirming its key role in both reactions. Furthermore, the formation in the catalytic tests with BuA and BuOH of n-butanal, notwithstanding the high H{sub 2}/organic ratio, implies that it is the main intermediate in the hydrogenolysis reactions. A new reaction scheme is proposed, pointing out the key role of GBL as the {open_quotes}intersection{close_quotes} of two possible reaction pathways, giving rise to THF or overhydrogenation and hydrogenolysis products, respectively. 44 refs., 4 figs., 6 tabs.

Messori, M.; Vaccari, A. [Universita degli Studi di Bologna (Italy)

1994-11-01T23:59:59.000Z

111

Plug repairs of marine glass fiber / vinyl ester laminates subjected to in-plane shear stress or in-plane bending moment  

E-Print Network (OSTI)

Glass fiber / vinyl ester composite laminates represent an important class of modem fiber composites being proposed or used in state-of-the-art shipbuilding. This thesis examined the effectiveness of chopped strand mat ...

Urrutia Valenzuela, Roberto

2010-01-01T23:59:59.000Z

112

The effects of nitric acid and silane surface treatments on carbon fibers and carbon/vinyl ester composites before and after seawater exposure.  

E-Print Network (OSTI)

??This research focuses on carbon fiber treatment by nitric acid and 3- (trimethoxysilyl)propyl methacrylate silane, and how this affects carbon/vinyl ester composites. These composites offer… (more)

Langston, Tye A.

2008-01-01T23:59:59.000Z

113

Lipid Analysis and Lipidomics: New Techniques & Application-Ch 6Structural Analysis of Unsaturated Fatty Acid Methyl Ester Isomers with Acetonitrile Covalent Adduct Chemical Ionization  

Science Conference Proceedings (OSTI)

Lipid Analysis and Lipidomics: New Techniques & Application-Ch 6 Structural Analysis of Unsaturated Fatty Acid Methyl Ester Isomers with Acetonitrile Covalent Adduct Chemical Ionization Methods and Analyses eChapters Methods - Analyses Book

114

Advances in Conjugated Linoleic Acid Research, Volume 3Chapter 6 Structural Characterization of CLA Methyl Esters with Acetonitrile Chemical Ionization Tandem Mass Spectrometry  

Science Conference Proceedings (OSTI)

Advances in Conjugated Linoleic Acid Research, Volume 3 Chapter 6 Structural Characterization of CLA Methyl Esters with Acetonitrile Chemical Ionization Tandem Mass Spectrometry Health Nutrition Biochemistry eChapters Health - Nutrition

115

Biobased Surfactants and Detergents Synthesis, Properties, and ApplicationsChapter 10 Basic Properties of Sucrose Fatty Acid Esters and Their Applications  

Science Conference Proceedings (OSTI)

Biobased Surfactants and Detergents Synthesis, Properties, and Applications Chapter 10 Basic Properties of Sucrose Fatty Acid Esters and Their Applications Surfactants and Detergents eChapters Surfactants - Detergents Press ...

116

Biobased Surfactants and Detergents Synthesis, Properties, and ApplicationsChapter 12 Synthesis of Saccharide Fatty Acid Ester Biosurfactants Catalyzed by Lipase  

Science Conference Proceedings (OSTI)

Biobased Surfactants and Detergents Synthesis, Properties, and Applications Chapter 12 Synthesis of Saccharide Fatty Acid Ester Biosurfactants Catalyzed by Lipase Surfactants and Detergents eChapters Surfactants - Detergents Press ...

117

Monitored natural attenuation of manufactured gas plant tar mono- and polycyclic aromatic hydrocarbons in ground water: a 14-year field study  

Science Conference Proceedings (OSTI)

Site 24 was the subject of a 14-year (5110-day) study of a ground water plume created by the disposal of manufactured gas plant (MGP) tar into a shallow sandy aquifer approximately 25 years prior to the study. The ground water plume in 1988 extended from a well-defined source area to a distance of approximately 400 m down gradient. A system of monitoring wells was installed along six transects that ran perpendicular to the longitudinal axis of the plume centerline. The MGP tar source was removed from the site in 1991 and a 14-year ground water monitored natural attenuation (MNA) study commenced. The program measured the dissolved mono- and polycyclic aromatic hydrocarbons (MAHs and PAHs) periodically over time, which decreased significantly over the 14-year period. Naphthalene decreased to less than 99% of the original dissolved mass, with mass degradation rates of 0.30 per year (half-life 2.3 years). Bulk attenuation rate constants for plume centerline concentrations over time ranged from 0.33 {+-} 0.09 per year (half-life 2.3 {+-} 0.8 years) for toluene and 0.45 {+-} 0.06 per year (half-life 1.6 {+-} 0.2 years) for naphthalene. The hydrogeologic setting at Site 24, having a sandy aquifer, shallow water table, clay confining layer, and aerobic conditions, was ideal for demonstrating MNA. However, these results demonstrate that MNA is a viable remedial strategy for ground water at sites impacted by MAHs and PAHs after the original source is removed, stabilized, or contained.

Neuhauser, E.F.; Ripp, J.A.; Azzolina, N.A.; Madsen, E.L.; Mauro, D.M.; Taylor, T. [Foth Infrastructure & Environment LLC, Green Bay, WI (United States)

2009-07-01T23:59:59.000Z

118

Mechanism for the hydrolysis of organophosphates and investigations into the stereoselective hydrolysis of organophosphorus Esters by Phosphotriesterase.  

E-Print Network (OSTI)

Phosphotriesterase (PTE) is a zinc metalloenzyme that catalyzes the hydrolysis of organophosphorus compounds. Metal ion roles during binding and catalysis are probed by comparing the kinetic properties of Zn/Zn, Cd/Cd, and Zn/Cd PTE with a variety of phosphate trisesters. The metal in the ?-site of the binuclear metal center modulates the pKa values determined from pH-rate profiles. These results suggest that the ?-metal is responsible for activating the nucleophilic hydroxide. In an effort to determine the function of the ?-metal, the kinetic parameters for diethyl p-chlorophenyl thiophosphate are compared with diethyl p-chlorophenyl phosphate. The thiophosphate substrate is hydrolyzed 20 to 100-times faster than the phosphate substrate for Zn/Zn, Cd/Cd, and Zn/Cd PTE. When Cd2+ occupies the ?-site, the inverse thio effect increases which suggests polarization by the ?-metal on the phosphoryl oxygen or sulfur bond. The catalytic roles of Asp 233, His 254, and Asp 301 are determined by comparing the kinetic parameters of a series of alanine and asparagine mutations with paraoxon and diethyl p-chlorophenyl phosphate. The increased rate of hydrolysis for diethyl p-chlorophenyl phosphate with the mutants is consistent with the existence of a proton relay system from Asp 301 to His 254 to Asp 233. A detailed mechanism for the hydrolysis of organophosphates by PTE has been proposed. PTE hydrolyzes a number of chiral organophosphorus esters. The pKa of the leaving group phenol is altered for a series of chiral phosphate, phosphonate, and phosphinate esters. The stereoselectivity of wild-type, G60A, and I106G/F132G/H257Y PTE is enhanced as the pKa value of the leaving group phenol increases for phosphate, phosphonate, and phosphinate esters. In addition to improving the stereoselectivity of phosphotriesterase, mutations that affect the size of the active site of PTE are screened to identify a mutant enzyme that preferentially hydrolyzes the opposite isomer of wild-type PTE. The rate constants and stereoselectivity ratios for a number of active site mutants have been determined. H254Y/L303T PTE reverses the stereoselective preference of phosphonate and phosphinate substrates. The PTE stereoselectivity of O-methyl, O-phenyl acetylphenyl phosphate is reversed 970-fold by I106G/F132G/H257Y. A reversal mutant was resolved for phosphate, phosphonate, and phosphinate esters.

Aubert, Sarah Dwyer

2004-12-01T23:59:59.000Z

119

Rare Metal Extraction & Processing Symposium - Programmaster.org  

Science Conference Proceedings (OSTI)

Comparison among different extractants, as (2-ethylhexyl)-mono (2-ethylhexyl) ester Phosphonic acid (P507), Secondary-octyl phenoxy acetic acid (CA-12) and  ...

120

Properties of thermo-chemically surface treated carbon fibers and of their epoxy and vinyl ester composites  

SciTech Connect

High strength carbon fibers were surface treated by a continuous gas phase thermo-chemical surface treatment. The surface and the mechanical properties of the fibers were investigated before and after treatment and compared to the properties obtained with a conventional industrial electro-chemical surface treatment. An increase of the oxygen atomic content from 3 % to 20 % with a preferential generation of carboxylic acid functionalities and hydroxyl groups was highlighted after the thermo-chemical surface treatment, compared to an oxygen atomic content of 7 % and a wide variety of oxygen moieties with the electro-chemical surface treatment. The tensile strength of the fibers increased slightly after the thermo-chemical surface treatment and remained the same after the electro-chemical surface treatment. Short beam shear and 90 flexural tests of composites revealed that the improvement of interfacial adhesion with a vinyl ester matrix was limited, revealing that oxidation of the carbon fiber surface alone cannot tremendously improve the mechanical properties of carbon fiber-vinyl ester composites. Atomic force microscopy showed that the creation of roughness with both surface treatments at a nanometric scale. Although the surface is slightly rougher after the electro-chemical surface treatment and is expected to lead to higher adhesion due to mechanical interlocking between the fiber surface and the matrix, the effect of covalent bonding coming from the high concentration of chemical groups on the surface results in higher adhesion strength, as obtained with the thermo-chemical surface treatment.

Vautard, Frederic [ORNL; Ozcan, Soydan [ORNL; Meyer III, Harry M [ORNL

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mono alkyl ester" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Kinetics and mechanisms of the reactions of alkyl radicals with oxygen and with complexes of Co(III), Ru(III), and Ni(III)  

Science Conference Proceedings (OSTI)

The kinetics of the reactions of C{sub 2}H{sub 5} radical with Co(NH{sub 3}){sub 5}X{sup 2+}, Ru(NH{sub 3}){sub 5}X{sup 2+}, and Co(dmgH){sub 2} (X) (Y) (X = Br, Cl, N{sub 3}, SCN; Y = H{sub 2}O, CH{sub 3}CN) complexes were studied using laser flash photolysis of ethylcobalt complexes. The kinetics were obtained by the kinetic probe method. Some relative rate constants were also determined by a competition method based on ethyl halide product ratios. The kinetics of colligation reactions of a series of alkyl radicals with {beta}-Ni(cyclam){sup 2+} were studied using flaser flash photolysis of alkylcobalt complexes. Again, the kinetics were obtained by employing the kinetic probe competition method. The kinetics of the unimolecular homolysis of a series of RNi(cyclam)H{sub 2}O{sup 2+} were studied. Activation parameters were obtained for the unimolecular homolysis of C{sub 2}H{sub 5}Ni(cyclam)H{sub 2}O{sup 2+}. Kinetic and thermodynamic data obtained from these reactions were compared with those for the {sigma}-bonded organometallic complexes. The kinetics of the unimolecular homolysis of a series of RNi(cyclam)H{sub 2}O{sup 2+} complexes were studied by monitoring the formation of the oxygen insertion product RO{sub 2}Ni(cyclam)H{sub 2}O{sup 2+}. The higher rate constants for the reactions of alkyl radicals with oxygen in solution, as compared with those measured in the gas phase, were discussed. 30 refs.

Kelley, D.

1990-10-08T23:59:59.000Z

122

Guiding optimal biofuels : a comparative analysis of the biochemical production of ethanol and fatty acid ethyl esters from switchgrass.  

SciTech Connect

In the current study, processes to produce either ethanol or a representative fatty acid ethyl ester (FAEE) via the fermentation of sugars liberated from lignocellulosic materials pretreated in acid or alkaline environments are analyzed in terms of economic and environmental metrics. Simplified process models are introduced and employed to estimate process performance, and Monte Carlo analyses were carried out to identify key sources of uncertainty and variability. We find that the near-term performance of processes to produce FAEE is significantly worse than that of ethanol production processes for all metrics considered, primarily due to poor fermentation yields and higher electricity demands for aerobic fermentation. In the longer term, the reduced cost and energy requirements of FAEE separation processes will be at least partially offset by inherent limitations in the relevant metabolic pathways that constrain the maximum yield potential of FAEE from biomass-derived sugars.

Paap, Scott M.; West, Todd H.; Manley, Dawn Kataoka; Dibble, Dean C.; Simmons, Blake Alexander; Steen, Eric J. [Joint BioEnergy Institute, Emeryville, CA; Beller, Harry R. [Lawrence Berkeley National Laboratory, Berkeley, CA; Keasling, Jay D. [Lawrence Berkeley National Laboratory, Berkeley, CA; Chang, Shiyan [Tsinghua University, Beijing, PR China

2013-01-01T23:59:59.000Z

123

Incorporating Amino Acid Esters into Catalysts for Hydrogen Oxidation: Steric and Electronic Effects and the Role of Water as a Base  

Science Conference Proceedings (OSTI)

Four derivatives of a hydrogen oxidation catalyst, [Ni(PCy2NBn-R2)]2+ (Cy=cyclohexyl, Bn=benzyl, R= OMe, COOMe, CO-Alanine-methyl ester or CO-Phenylalanine-methyl ester), have been prepared to investigate steric and electronic effects on catalysis. Each complex was characterized spectroscopically and electrochemically, and thermodynamic data were determined. Crystal structures are also reported for the -OMe and -COOMe derivatives. All four catalysts were found to be active for H2 oxidation. The methyl ester (R = COOMe) and amino acid ester containing complexes (R = CO-Alanine-methyl ester or CO-Phenylalanine-methyl ester) had slower rates (4 s-1) than that of the parent complex (10 s-1), in which R = H, consistent with the lower amine pKa’s and less favorable ?GH2’s found for these electron-withdrawing substituents. Dynamic processes for the amino acid ester containing complexes were also investigated and found not to hinder catalysis. The electron-donating methoxy ether derivative (R = OMe) was prepared to compare electronic effects and has a similar catalytic rate as the parent complex. In the course of these studies, it was found that water could act as a weak base for H2 oxidation, although catalytic turnover requires a significantly higher potential and utilizes a different sequence of catalytic steps than when using a base with a higher pKa. Importantly, these catalysts provide a foundation upon which larger peptides can be attached to [Ni(PCy2NBn2)2]2+ hydrogen oxidation catalysts in order to more fully investigate and implement the effects of the outer-coordination sphere. This work was funded by the DOE Office of Science Early Career Research Program through the Office of Basic Energy Sciences (SL and WJS), by the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the US Department of Energy, Office of Science, Office of Basic Energy Sciences (JR), and by the US DOE Basic Energy Sciences, Chemical Sciences, Geoscience and Biosciences Division (AMA, AJ). Pacific Northwest National Laboratory is operated by Battelle for the U.S. Department of Energy.

Lense, Sheri; Ho, Ming-Hsun; Chen, Shentan; Jain, Avijita; Raugei, Simone; Linehan, John C.; Roberts, John A.; Appel, Aaron M.; Shaw, Wendy J.

2012-10-08T23:59:59.000Z

124

Alternative Fuels Data Center: Biodiesel Definition  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Biodiesel Definition Biodiesel Definition to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Definition on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Definition on Twitter Bookmark Alternative Fuels Data Center: Biodiesel Definition on Google Bookmark Alternative Fuels Data Center: Biodiesel Definition on Delicious Rank Alternative Fuels Data Center: Biodiesel Definition on Digg Find More places to share Alternative Fuels Data Center: Biodiesel Definition on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Biodiesel Definition Biodiesel is defined as a renewable, biodegradable, mono alkyl ester combustible liquid fuel that is derived from agricultural plant oils or animal fats and meets ASTM specification D6751-11b. A biodiesel blend is a

125

Alternative Fuels Data Center: Biodiesel Definition  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Biodiesel Definition Biodiesel Definition to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Definition on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Definition on Twitter Bookmark Alternative Fuels Data Center: Biodiesel Definition on Google Bookmark Alternative Fuels Data Center: Biodiesel Definition on Delicious Rank Alternative Fuels Data Center: Biodiesel Definition on Digg Find More places to share Alternative Fuels Data Center: Biodiesel Definition on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Biodiesel Definition Biodiesel is defined as a fuel comprised of mono-alkyl esters of long chain fatty acids derived from vegetable oils or animal fats, either in pure form or mixed in any combination with petroleum-based diesel fuel. The

126

Alternative Fuels Data Center: Biodiesel Definition  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Biodiesel Definition Biodiesel Definition to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Definition on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Definition on Twitter Bookmark Alternative Fuels Data Center: Biodiesel Definition on Google Bookmark Alternative Fuels Data Center: Biodiesel Definition on Delicious Rank Alternative Fuels Data Center: Biodiesel Definition on Digg Find More places to share Alternative Fuels Data Center: Biodiesel Definition on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Biodiesel Definition Biodiesel fuel is defined as a mono alkyl ester of long chain fatty acids derived from vegetable oils or animal fats for use in compression-ignition engines and meets the requirements of the ASTM specification D6751 in

127

Alternative Fuels Data Center: Biodiesel Definition and Specification  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Biodiesel Definition Biodiesel Definition and Specification to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Definition and Specification on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Definition and Specification on Twitter Bookmark Alternative Fuels Data Center: Biodiesel Definition and Specification on Google Bookmark Alternative Fuels Data Center: Biodiesel Definition and Specification on Delicious Rank Alternative Fuels Data Center: Biodiesel Definition and Specification on Digg Find More places to share Alternative Fuels Data Center: Biodiesel Definition and Specification on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Biodiesel Definition and Specification Biodiesel is defined as a fuel that is comprised of mono-alkyl esters of

128

Alternative Fuels Data Center: Biodiesel Definition and Specifications  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Biodiesel Definition Biodiesel Definition and Specifications to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Definition and Specifications on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Definition and Specifications on Twitter Bookmark Alternative Fuels Data Center: Biodiesel Definition and Specifications on Google Bookmark Alternative Fuels Data Center: Biodiesel Definition and Specifications on Delicious Rank Alternative Fuels Data Center: Biodiesel Definition and Specifications on Digg Find More places to share Alternative Fuels Data Center: Biodiesel Definition and Specifications on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Biodiesel Definition and Specifications Biodiesel is defined as a fuel that is comprised only of mono-alkyl esters

129

Alternative Fuels Data Center: Biodiesel and Green Diesel Definitions  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Biodiesel and Green Biodiesel and Green Diesel Definitions to someone by E-mail Share Alternative Fuels Data Center: Biodiesel and Green Diesel Definitions on Facebook Tweet about Alternative Fuels Data Center: Biodiesel and Green Diesel Definitions on Twitter Bookmark Alternative Fuels Data Center: Biodiesel and Green Diesel Definitions on Google Bookmark Alternative Fuels Data Center: Biodiesel and Green Diesel Definitions on Delicious Rank Alternative Fuels Data Center: Biodiesel and Green Diesel Definitions on Digg Find More places to share Alternative Fuels Data Center: Biodiesel and Green Diesel Definitions on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Biodiesel and Green Diesel Definitions Biodiesel is defined as a fuel that is comprised of mono-alkyl esters of

130

Alternative Fuels Data Center: Biodiesel and Renewable Fuel Definitions  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Biodiesel and Biodiesel and Renewable Fuel Definitions to someone by E-mail Share Alternative Fuels Data Center: Biodiesel and Renewable Fuel Definitions on Facebook Tweet about Alternative Fuels Data Center: Biodiesel and Renewable Fuel Definitions on Twitter Bookmark Alternative Fuels Data Center: Biodiesel and Renewable Fuel Definitions on Google Bookmark Alternative Fuels Data Center: Biodiesel and Renewable Fuel Definitions on Delicious Rank Alternative Fuels Data Center: Biodiesel and Renewable Fuel Definitions on Digg Find More places to share Alternative Fuels Data Center: Biodiesel and Renewable Fuel Definitions on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Biodiesel and Renewable Fuel Definitions Biodiesel is defined as a renewable, biodegradable, mono alkyl ester

131

Alternative Fuels Data Center: Biodiesel Producer Requirements  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Biodiesel Producer Biodiesel Producer Requirements to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Producer Requirements on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Producer Requirements on Twitter Bookmark Alternative Fuels Data Center: Biodiesel Producer Requirements on Google Bookmark Alternative Fuels Data Center: Biodiesel Producer Requirements on Delicious Rank Alternative Fuels Data Center: Biodiesel Producer Requirements on Digg Find More places to share Alternative Fuels Data Center: Biodiesel Producer Requirements on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Biodiesel Producer Requirements Biodiesel is defined as a fuel that is composed of mono-alkyl esters of long-chain fatty acids derived from plant or animal matter, meets the

132

Alternative Fuels Data Center: Biodiesel Definition  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Definition Definition to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Definition on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Definition on Twitter Bookmark Alternative Fuels Data Center: Biodiesel Definition on Google Bookmark Alternative Fuels Data Center: Biodiesel Definition on Delicious Rank Alternative Fuels Data Center: Biodiesel Definition on Digg Find More places to share Alternative Fuels Data Center: Biodiesel Definition on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Biodiesel Definition Biodiesel is a renewable special fuel that is composed of mono-alkyl esters of long chain fatty acids, derived from vegetable oils or animal fats, and meets the requirements of the ASTM specification D6751. (Reference New

133

Development and application of a redox indicator method for the kinetics of oxidation of vanadium(II) ions by hydrogen peroxide and alkyl hydroperoxides  

SciTech Connect

The addition of the methyl viologen radical cation (PQ/sup .+/) to solutions of V(H/sub 2/O)/sub 6//sup 2 +/ and hydrogen peroxide or alkyl hydroperoxide provides a method for measuring the initial reaction rate. The kinetic data so obtained are consistent with the rate equation -d(peroxide)/dt = k/sub 1/(V/sup 2 +/)(peroxide). Kinetic data are given for H/sub 2/O/sub 2/ (k/sub 1/ = 15.4 M/sup -1/ s/sup -1/ at 25.0/sup 0/C) and for RC(CH/sub 3/)/sub 2/OOH, with R = CH/sub 3/ (3.0 M/sup -1/ s/sup -1/), C/sub 2/H/sub 5/ (5.2 M/sup -1/ s/sup -1/), and CH/sub 2/C/sub 6/H/sub 5/ (4.8 M/sup -1/ s/sup -1/). 27 references, 2 figures, 2 tables.

Kim, H.P.; Espenson, J.H.; Bakac, A.

1987-12-02T23:59:59.000Z

134

Accurate and Reliable Quantification of Total Microalgal Fuel Potential as Fatty Acid Methyl Esters by in situ Transesterfication  

DOE Green Energy (OSTI)

In the context of algal biofuels, lipids, or better aliphatic chains of the fatty acids, are perhaps the most important constituents of algal biomass. Accurate quantification of lipids and their respective fuel yield is crucial for comparison of algal strains and growth conditions and for process monitoring. As an alternative to traditional solvent-based lipid extraction procedures, we have developed a robust whole-biomass in situ transesterification procedure for quantification of algal lipids (as fatty acid methyl esters, FAMEs) that (a) can be carried out on a small scale (using 4-7 mg of biomass), (b) is applicable to a range of different species, (c) consists of a single-step reaction, (d) is robust over a range of different temperature and time combinations, and (e) tolerant to at least 50% water in the biomass. Unlike gravimetric lipid quantification, which can over- or underestimate the lipid content, whole biomass transesterification reflects the true potential fuel yield of algal biomass. We report here on the comparison of the yield of FAMEs by using different catalysts and catalyst combinations, with the acid catalyst HCl providing a consistently high level of conversion of fatty acids with a precision of 1.9% relative standard deviation. We investigate the influence of reaction time, temperature, and biomass water content on the measured FAME content and profile for 4 different samples of algae (replete and deplete Chlorella vulgaris, replete Phaeodactylum tricornutum, and replete Nannochloropsis sp.). We conclude by demonstrating a full mass balance closure of all fatty acids around a traditional lipid extraction process.

Laurens, L. M. L.; Quinn, M.; Van Wychen, S.; Templeton, D. W.; Wolfrum, E. J.

2012-04-01T23:59:59.000Z

135

Epidermal growth factor (EGF)-stimulated inositol phosphate formation in hepatocytes is abolished by pertussis toxin and phorbol esters  

SciTech Connect

The EGF-stimulated rise in intracellular Ca/sup 2 +/ (Ca/sup 2 +/)/sub i/ and Ca/sup 2 +/-dependent protein phosphorylation events in isolated hepatocytes are blocked by pertussis toxin and phorbol ester pretreatment. The present study characterized the EGF-stimulated formation of inositol 1,4,5-trisphosphate (Ins(1,4,5)P/sub 3/) and inositol 1,3,4-trisphosphate (Ins(1,3,4)P/sub 3/) in hepatocytes using HPLC methodology to separate the InsP/sub 3/ isomers. Both 66 nM EGF and 10 nM angiotensin II (ANG II) caused a rapid increase in the Ins(1,4,5)P/sub 3/ isomer although EGF-stimulated formation was smaller. At a concentration of ANG II (0.1 nM) which gave an equivalent rise in (Ca/sup 2 +/)/sub i/ as 66 nM EGF, the kinetics and magnitude of Ins(1,4,5)P/sub 3/ formation were similar. EGF or ANG II-stimulated formation of the Ins(1,3,4)P/sub 3/ isomer was more gradual and increased beyond the level of Ins(1,4,5)P/sub 3/ after 60 sec. The initial EGF and ANG II-stimulated increase in both InsP/sub 3/ isomers was not affected by removing external Ca/sup 2 +/ with a 10-fold excess of EGTA. Pretreatment of rats with pertussis toxin for 72 hrs blocked the ability of EGF to increase Ins(1,4,5)P/sub 3/ but did not affect the increase due to ANG II. Three main pretreatment of cells with 1 ..mu..g/ml phorbol 12-myristate-13-acetate (PMA) also inhibited the EGF-stimulated Ins(1,4,5)P/sub 3/ formation. PMA slightly attenuated Ins(1,4,5)P/sub 3/ formation stimulated by 0.1 nM ANG II but not enough to affect the Ca/sup 2 +/ signal. These data suggest that the signal transduction system used by EGF receptors to increase Ins (1,4,5)P/sub 3/ in hepatocytes is somehow different from that used by ANG II receptors.

Johnson, R.M.; Garrison, J.C.

1987-05-01T23:59:59.000Z

136

Induction of transcription from the long terminal repeat of Moloney murine sarcoma provirus by UV-irradiation, x-irradiation, and phorbol ester  

SciTech Connect

The long terminal repeat (LTR) of Moloney murine sarcoma virus (Mo-MuSV) was used as a model system to study the stress response of mammalian cells to physical carcinogens. The chloramphenicol acetyltransferase (CAT) gene was inserted between two Mo-MuSV LTRs, and the LTR-CAT-LTR construct was used for virus production and was integrated into the genome of NIH 3T3 cells in the proviral form. This construct was used to assure that the integrated CAT gene was driven by the promoter of the LTR. Expression of the CAT gene was stimulated 4-fold by UV irradiation, and the peak of activity was observed at 18 hr. In contrast, stimulation of the CAT expression after x-irradiation was 2-fold and occurred at 6 hr. Phorbol myristate acetate also stimulated CAT activity 4-fold with a peak at 6 hr. Down-regulation of protein kinase C blocked totally the response to x-irradiation but only partially the response to UV. The protein kinase inhibitor H7 blocked the response to treatment by UV, x-ray, and phorbol ester.

Lin, C.S.; Goldthwait, D.A.; Samols, D. (Case Western Reserve Univ., Cleveland, OH (USA))

1990-01-01T23:59:59.000Z

137

PROPERTY CHANGES OF CYANATE ESTER/EPOXY INSULATION SYSTEMS CAUSED BY AN ITER-LIKE DOUBLE IMPREGNATION AND BY REACTOR IRRADIATION  

Science Conference Proceedings (OSTI)

Because of the double pancake design of the ITER TF coils the insulation will be applied in several steps. As a consequence, the conductor insulation as well as the pancake insulation will undergo multiple heat cycles in addition to the initial curing cycle. In particular the properties of the organic resin may be influenced, since its heat resistance is limited. Two identical types of sample consisting of wrapped R-glass/Kapton layers and vacuum impregnated with a cyanate ester/epoxy blend were prepared. The build-up of the reinforcement was identical for both insulation systems; however, one system was fabricated in two steps. In the first step only one half of the reinforcing layers was impregnated and cured. Afterwards the remaining layers were wrapped onto the already cured system, before the resulting system was impregnated and cured again. The mechanical properties were characterized prior to and after irradiation to fast neutron fluences of 1 and 2x10{sup 22} m{sup -2}(E>0.1 MeV) in tension and interlaminar shear at 77 K. In order to simulate the pulsed operation of ITER, tension-tension fatigue measurements were performed in the load controlled mode. The results do not show any evidence for reduced mechanical strength caused by the additional heat cycle.

Prokopec, R.; Humer, K.; Fillunger, H.; Maix, R. K.; Weber, H. W. [Atominstitut, Vienna University of Technology, 1020 Wien (Austria)

2010-04-08T23:59:59.000Z

138

Solid Catalyzed Isoparaffin Alkylation at Supercritical Fluid ...  

Energy Innovation Portal. Home » INL » Marketing Summaries. Site Map; Printable Version; ... Avoids the use of hydro-fluoric and concentrated sulfuric acids.

139

Development of high temperature liquid lubricants for low-heat rejection heavy duty diesel engines  

DOE Green Energy (OSTI)

Objective was to develop a liquid lubricant that will allow advanced diesel engines to operate at top ring reversal temperatures approaching 500 C and lubricant sump temperatures approaching 250 C. Base stock screening showed that aromatic esters and diesters has the lowest deposit level, compared to polyol esters, poly-alpha-olefins, or refined mineral oil of comparable viscosity. Classical aryl and alkyl ZDP antiwear additives are ineffective in reducing wear with aromatic esters; the phosphate ester was a much better antiwear additive, and polyol esters are more amenable to ZDP treatment. Zeolites and clays were evaluated for filtration.

Wiczynski, T.A.; Marolewski, T.A.

1993-03-01T23:59:59.000Z

140

Precise Regression Benchmarking with Random Effects: Improving Mono Benchmark Results  

E-Print Network (OSTI)

Benchmarking as a method of assessing software performance is known to su#er from random fluctuations that distort the observed performance. In this paper, we focus on the fluctuations caused by compilation.

Tomas Kalibera; Petr Tuma

2006-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mono alkyl ester" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Mono County, California: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

9218608°, -118.9528645° 9218608°, -118.9528645° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":37.9218608,"lon":-118.9528645,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

142

NBS Mono115: Lab-Fixed Components of Elec. Dipole ...  

Science Conference Proceedings (OSTI)

3.1. Laboratory-Fixed Components of the Electric Dipole Moment Operator ?. ... 2.9) to the overall parity selection rule for electric dipole transitions . ...

143

Coaxial Mono-Energetic Gamma Generator for Active Interrogation  

E-Print Network (OSTI)

number DE-AC02- 05CH11231. Sandia National Laboratories is alaboratory operated by Sandia Corporation, a Lockheed MartinRoad, Berkeley, CA 94720 Sandia National Laboratories,

Ludewigt, Bernhard A.

2010-01-01T23:59:59.000Z

144

Coaxial Mono-Energetic Gamma Generator for Active Interrogation  

E-Print Network (OSTI)

of Energy's National Nuclear Security Administration underof Homeland Security, Domestic Nuclear Detection Office

Ludewigt, Bernhard A.

2010-01-01T23:59:59.000Z

145

The Dependence of Donor:Acceptor Ratio on the Photovoltaic Performances of Blended poly (3-octylthiophene-2,5-diyl) and (6,6)-phenyl C{sub 71} butyric acid methyl ester Bulk Heterojunction Organic Solar Cells  

Science Conference Proceedings (OSTI)

Bulk heterojunction organic solar cells using blended poly (3-octylthiophene-2,5-diyl)(P3OT) and (6,6)-phenyl C{sub 71} butyric acid methyl ester (PC{sub 71}BM) have been fabricated. P3OT and PC{sub 71}BM were used as the electron donor (D) and acceptor (A), respectively. Both materials were mixed and dissolved in dichlorobenzene with three different D:A ratios i.e. 1:3, 1:1 and 3:1 (weight) while maintained at the concentration of 2 wt%(26 mg/ml). The blended thin films were sandwiched between the indium tin oxide (ITO) coated glass and the aluminum film. This paper reports the influence of donor:acceptor ratio on the performance of solar cell devices measured by current-voltage measurement both in the dark and under 1.5 AM solar illumination. It was found that all devices showed the photovoltaic effect with poor diode behavior and the donor:acceptor ratio significantly influenced on the performance of bulk heterojunction organic solar cells.

Fauzia, Vivi [Department of Physics, Faculty of Mathematics and Natural Sciences, University of Indonesia, Kampus UI Depok, Depok 16424 (Indonesia); Institute of Microengineering and Nanoelectronics (IMEN), Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia); Umar, Akrajas Ali; Salleh, Muhamad Mat [Institute of Microengineering and Nanoelectronics (IMEN), Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia); Yahya, Muhammad [School of Applied Physics, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia)

2010-10-24T23:59:59.000Z

146

Phosphate ester hydrolysis catalyzed by metallomicelles  

Science Conference Proceedings (OSTI)

Two long-chained cupric ion complexes were synthesized and found to possess remarkable catalytic activity toward phosphate triesters, diesters, and other phosphorus(V) compounds (including some particularly toxic and persistent materials). The complexes form metallomicelles which bind substrates with enzyme-like efficiency (K/sub assoc/ > 10/sup 5/ M). Rate accelerations approach the 10/sup 5/-fold level with turnover behavior. Possible reasons for the huge rate accelerations include enhanced electrophilicity of the micellized metal (demonstrated by polarography) and enhanced acidity of copper-bound water (demonstrated by rate vs pH studies).

Menger, F.M.; Gan, L.H.; Johnson, E.; Durst, D.H.

1987-04-29T23:59:59.000Z

147

Chemical Dynamics Beamline Publications 340. K. N. Urness, A. Golan, J. W. Daily, M. R. Nimlos, J. F. Stanton, M. Ahmed, and G. B. Ellison, "Pyrolysis  

E-Print Network (OSTI)

. Kroll, "Chemical Sinks of Organic Aerosol: Kinetics and Products of the Heterogeneous Oxidation Detailed Chemical Kinetic Mechanism for Oxidation of Four Small Alkyl Esters in Laminar Premixed Flames. Ahmed, and S. R. Leone, "The multiplexed chemical kinetic photoionization mass spectrometer: a new

148

Biodiesel – SSC Process  

:  INL’s biodiesel-SSC uses solid catalyst under super-critical fluid conditions to produce biodiesel from a full range of lipid feedstock. This invention provides in a single-phase process for producing alkyl esters from triglycerides or fatty acid ...

149

Universal detectors for determination of lipids in biodiesel production  

Science Conference Proceedings (OSTI)

Biodiesel is often produced by reacting plant or animal oils with an alcohol to form the desired alkyl esters as fuel, and this transesterification is typically achieved using a base. This also produces free glycerol and acylglycerols as impurities in the

150

Alkylation is an important source for octane in gasoline - Today ...  

U.S. Energy Information Administration (EIA)

Petroleum & Other Liquids. Crude oil, gasoline, heating oil, diesel, propane, and other liquids including biofuels and natural gas liquids. Natural Gas

151

Structure of Ionic Liquids with Linear, Branched and Cyclic Alkyl...  

NLE Websites -- All DOE Office Websites (Extended Search)

and Edward W. Castner J. Phys. Chem. B 117, Just Accepted (2013). Find paper at ACS Publications Abstract: X-ray scattering and molecular dynamics simulations have been...

152

Adsorption of alkyl amides: monolayer structures and mixing behaviour  

E-Print Network (OSTI)

using Low Energy Electron Diffraction (LEED) and X-ray and neutron diffraction techniques. Studies of molecular adsorbates such as nitrogen [19-22], oxygen [23], hydrogen [24-26] and carbon monoxide [22] can also be found in literature. A variety of 2... to exhibit three phases, including a commensurate solid phase [27]. Chapter 1 Introduction 1-6 1.2.2 Diatomics Figure 1-4 ( 3 x 3 ) R30o commensurate structure of N2 on graphite and the triangular incommensurate phase calculated using LEED...

Bhinde, Tej

2011-02-08T23:59:59.000Z

153

Cationic Ir(III) alkyl and hydride complexes: stoichiometric ...  

80 S.R. Klei et al./Journal of Molecular Catalysis A: Chemical 189 (2002) 79–94 platinum(II) catalyst capable of converting methane to methyl bisulfate, which could ...

154

Evaluation of Alumina From Alkylation Process in Reduction Cells  

Science Conference Proceedings (OSTI)

... Heat Exchanger Solution for Aluminium Off-Gas Cooling and Heat Recovery ... The Effect of Calcium Fluoride on Alumina Solubility in Low Temperature ...

155

Evaluation Of Alumina From Alkylation Process In Reduction Cells  

Science Conference Proceedings (OSTI)

Design and Manufacture of Fluidized Bed Reactor in Pilot Scale for Multiple ..... The Effect of Circulating Coal Slurry Water Hardness on Coal Preparation.

156

Early transitional metal alkyl, alkylidene, and alkylidyne chemistry  

E-Print Network (OSTI)

CHAPTER 1. Zirconium and hafnium complexes of several new unsymmetric diamide ligands have been prepared and their proficiency in olefin polymerization reactions evaluated. The first set of supporting ligands examined are ...

Tonzetich, Zachary John

2007-01-01T23:59:59.000Z

157

Alkylation is an important source for octane in gasoline - Today ...  

U.S. Energy Information Administration (EIA)

Greenhouse gas data, voluntary report- ing, electric power plant emissions. ... (like temperature and pressure) along with different safety considerations.

158

Preparation of Propylene Glycol Fatty Acid Ester or Other Glycol, or Polyol Fatty Acid Esters  

This technology provides an alternate method to synthesize a key type of PVC plasticizer described in US 6,797,753 (see separate description entitled ...

159

A review of chromatographic characterization techniques for biodiesel and biodiesel blends.  

Science Conference Proceedings (OSTI)

This review surveys chromatographic technology that has been applied to the characterization of biodiesel and its blends. Typically, biodiesel consists of fatty acid methyl esters produced by transesterification of plant or animal derived triacylglycerols. Primary attention is given to the determination of trace impurities in biodiesel, such as methanol, glycerol, mono-, di-, and triacylglycerols, and sterol glucosides. The determination of the fatty acid methyl esters, trace impurities in biodiesel, and the determination of the biodiesel content of commercial blends of biodiesel in conventional diesel are also addressed.

Pauls, R. E. (Chemical Sciences and Engineering Division)

2011-05-01T23:59:59.000Z

160

Environmental overview of geothermal development: the Mono-Long Valley KGRA  

DOE Green Energy (OSTI)

Major issues and concerns relating to geothermal development were identified and assessed in seven broad areas: (1) air quality, (2) archaeology and cultural resources, (3) geology, (4) natural ecosystems, (5) noise, (6) socioeconomics, and (7) water quality. Existing data for each of these areas was identified and evaluated to determine if the data can be used to help resolve major issues. Finally, specific areas where additional data are needed to ensure that geothermal development is environmentally acceptable were recommended.

Strojan, C.L.; Romney, E.M. (eds.) [eds.

1979-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mono alkyl ester" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

The Conformation of the Poly(ethylene glycol) Chain in Mono ...  

Science Conference Proceedings (OSTI)

... of the lysozyme conjugates, as determined by CD (data not ... instrument NG327 and at Oak Ridge National Laboratory (ORNL) using the 30 ...

2012-02-03T23:59:59.000Z

162

GEOTHERMAL SYSTEMS OF THE MONO BASIN-LONG VALLEY REGION, EASTERN...  

NLE Websites -- All DOE Office Websites (Extended Search)

H. , 1972, Geology and mineral deposits of Esmeralda County, Nevada: Nevada Bureau of Mines and Geology Bulletin 78, 80 p. Alpha, T.R., Bailey, R.A., and Morley, J.M., 1983,...

163

Solutions of Boltzmann`s Equation for Mono-energetic Neutrons in an Infinite Homogeneous Medium  

DOE R&D Accomplishments (OSTI)

Boltzman's equation is solved for the case of monoenergetic neutrons created by a plane or point source in an infinite medium which has spherically symmetric scattering. The customary solution of the diffusion equation appears to be multiplied by a constant factor which is smaller than 1. In addition to this term the total neutron density contains another term which is important in the neighborhood of the source. It varies as 1/r{sup 2} in the neighborhood of a point source. (auth)

Wigner, E. P.

1943-11-30T23:59:59.000Z

164

SYNTHESE EN FRANAIS TITRE: NEUTRONIC STUDY OF THE MONO-RECYCLING OF AMERICIUM IN PWR  

E-Print Network (OSTI)

& Schittkowski (1981) . . . . . . . 94 3.6.2 Example 2: Nuclear Reactor Reload Pattern Design . 95 3.6.3 Example techniques. In particular: · In Section 3.6.2, we present a small but difficult instance of a nuclear reactor Optimization in Continuous and Mixed-Integer Nonlinear Programming Theory, Algorithms, Software

165

On the mono- and cross-language detection of text reuse and plagiarism  

Science Conference Proceedings (OSTI)

Plagiarism, the unacknowledged reuse of text, has increased in recent years due to the large amount of texts readily available. For instance, recent studies claim that nowadays a high rate of student reports include plagiarism, making manual plagiarism ... Keywords: cross-language plagiarism detection, plagiarism detection, text similarity

Alberto Barrón-Cedeńo

2010-07-01T23:59:59.000Z

166

INCORPORATION OF MONO SODIUM TITANATE AND CRYSTALLINE SILICOTITANATE FEEDS IN HIGH LEVEL NUCLEAR WASTE GLASS  

Science Conference Proceedings (OSTI)

Four series of glass compositions were selected, fabricated, and characterized as part of a study to determine the impacts of the addition of Crystalline Silicotitanate (CST) and Monosodium Titanate (MST) from the Small Column Ion Exchange (SCIX) process on the Defense Waste Processing Facility (DWPF) glass waste form and the applicability of the DWPF process control models. All of the glasses studied were considerably more durable than the benchmark Environmental Assessment (EA) glass. The measured Product Consistency Test (PCT) responses were compared with the predicted values from the current DWPF durability model. One of the KT01-series and two of the KT03-series glasses had measured PCT responses that were outside the lower bound of the durability model. All of the KT04 glasses had durabilities that were predictable regardless of heat treatment or compositional view. In general, the measured viscosity values of the KT01, KT03, and KT04-series glasses are well predicted by the current DWPF viscosity model. The results of liquidus temperature (T{sub L}) measurements for the KT01-series glasses were mixed with regard to the predictability of the T{sub L} for each glass. All of the measured T{sub L} values were higher than the model predicted values, although most fell within the 95% confidence intervals. Overall, the results of this study show a reasonable ability to incorporate the anticipated SCIX streams into DWPF-type glass compositions with TiO{sub 2} concentrations of 4-5 wt % in glass.

Fox, K.; Johnson, F.; Edwards, T.

2010-11-23T23:59:59.000Z

167

Production of biodiesel using expanded gas solvents  

Science Conference Proceedings (OSTI)

A method of producing an alkyl ester. The method comprises providing an alcohol and a triglyceride or fatty acid. An expanding gas is dissolved into the alcohol to form a gas expanded solvent. The alcohol is reacted with the triglyceride or fatty acid in a single phase to produce the alkyl ester. The expanding gas may be a nonpolar expanding gas, such as carbon dioxide, methane, ethane, propane, butane, pentane, ethylene, propylene, butylene, pentene, isomers thereof, and mixtures thereof, which is dissolved into the alcohol. The gas expanded solvent may be maintained at a temperature below, at, or above a critical temperature of the expanding gas and at a pressure below, at, or above a critical pressure of the expanding gas.

Ginosar, Daniel M [Idaho Falls, ID; Fox, Robert V [Idaho Falls, ID; Petkovic, Lucia M [Idaho Falls, ID

2009-04-07T23:59:59.000Z

168

The Esterification of Naphthenic Acids for Methyl Ester Production .  

E-Print Network (OSTI)

??The remediation of tailings water, a by-product of bitumen extraction, is of utmost importance to the Athabasca oil sands industry due to its toxicity to… (more)

Dastjerdi, Zahra

2010-01-01T23:59:59.000Z

169

“Super Phos” esters: the key to higher-performance products  

Science Conference Proceedings (OSTI)

Robert L. Reierson, winner of the 2012 Samuel Rosen Memorial Award recognizing accomplishments in surfactant chemistry, describes how phosphation process control makes it possible to systematically design and adjust product compositions to deliver maximum

170

New Directing Groups for Metal-Catalyzed Asymmetric Carbon–Carbon Bond-Forming Processes: Stereoconvergent Alkyl–Alkyl Suzuki Cross-Couplings of Unactivated Electrophiles  

E-Print Network (OSTI)

The ability of two common protected forms of amines (carbamates and sulfonamides) to serve as directing groups in Ni-catalyzed Suzuki reactions has been exploited in the development of catalytic asymmetric methods for ...

Wilsily, Ashraf

171

Copper-catalyzed asymmetric allylic alkylation and asymmetric conjugate addition in natural product synthesis.  

E-Print Network (OSTI)

??In dit proefschrift wordt de koper-gekatalyseerde hetero AAA en ACA toegepast in de totaalsynthese van een aantal biologisch actieve moleculen. In het tweede deel van… (more)

Huang, Yange

2013-01-01T23:59:59.000Z

172

The Structure and Phase Diagram of Chiral Alkyl-Serine Monolayers on Mercury  

Science Conference Proceedings (OSTI)

The structure of liquid-mercury-supported Langmuir films (LFs) of chiral serine-modified fatty acid molecules was studied as a function of length, n = 8-22 carbons, temperature, T = 5-25 C, and surface coverage, A {approx} 40-200 {angstrom}{sup 2} per molecule, for both homochiral and heterochiral compounds. Using surface pressure {pi}-area A isotherms and surface-specific synchrotron X-ray diffraction methods the phase diagram was determined in detail. No lateral order was found for phases comprising surface-parallel molecules, in contrast with unmodified fatty acid LFs on mercury. For phases comprising standing-up molecules, long range lateral order was found for n {>=} 12, but no order for n = 8. The molecules in the ordered phases are extended, and tilt rigidly by {approx}40{sup o} from the surface normal. The homochiral LFs pack in an oblique, single-molecule, unit cell. The heterochiral LFs pack in a body-centered rectangular unit cell, containing two molecules. Unlike unmodified fatty acid LFs, the structure of the standing-up phase does not vary with n, T or A. The interactions underlying these characteristics, and the role of chirality, are discussed.

L Tamam; D Medina; T Menahem; Y Mastai; E Sloutskin; S Yefet; M Deutsch

2011-12-31T23:59:59.000Z

173

Novel mixed organoboranes for the reductive alkylation of p-benzoquinone  

E-Print Network (OSTI)

catecholborane. Nevertheless, the catechol group should showsuggested that adding catechol to the trialkylborane andto establish that the catechol would not react with the

Hincapié, Gloria

2011-01-01T23:59:59.000Z

174

Reactivity of Bis(amino)cyclopropenylidenes (BACs) and Cyclic(alkyl)(amino)carbenes (CAACs):  

E-Print Network (OSTI)

s catalyst Unexpected formation of [(BAC) 2 Rh(COD)][(COD)RhCl 2 ] Synthesisof (BAC) 2 Ni(COD) Rapid Exchange of ?-coordinated COD

Kuchenbeiser, Glenn Richard

2009-01-01T23:59:59.000Z

175

Reactivity of Bis(amino)cyclopropenylidenes (BACs) and Cyclic(alkyl)(amino)carbenes (CAACs):  

E-Print Network (OSTI)

Bruker AXS Inc. : Madison, Wisconsin, USA, 2003 . SADABS ;AXS Inc. : Madison, Wisconsin, USA, 2004. SAINT; versionAXS Inc. : Madison, Wisconsin, USA, 2003. SHELXTL; version

Kuchenbeiser, Glenn Richard

2009-01-01T23:59:59.000Z

176

Alkyl-methylimidazolium ionic liquids affect the growth and fermentative metabolism of Clostridium sp  

SciTech Connect

In this study, the effect of ionic liquids, 1-ethyl-3-methylimidazolium acetate [EMIM][Ac], 1-ethyl-3-methylimidazolium diethylphosphate [EMIM][DEP], and 1-methyl-3-methylimidazolium dimethylphosphate [MMIM][DMP] on the growth and glucose fermentation of Clostridium sp. was investigated. Among the three ionic liquids tested, [MMIM][DMP] was found to be least toxic. Growth of Clostridium sp. was not inhibited up to 2.5, 4 and 4 g L{sup -1} of [EMIM][Ac], [EMIM][DEP] and [MMIM][DMP], respectively. [EMIM][Ac] at <2.5 g L{sup -1}, showed hormetic effect and stimulated the growth and fermentation by modulating medium pH. Total organic acid production increased in the presence of 2.5 and 2 g L{sup -1} of [EMIM][Ac] and [MMIM][DMP]. Ionic liquids had no significant influence on alcohol production at <2.5 g L{sup -1}. Total gas production was affected by ILs at {ge}2.5 g L{sup -1} and varied with type of methylimidazolium IL. Overall, the results show that the growth and fermentative metabolism of Clostridium sp. is not impacted by ILs at concentrations below 2.5 g L{sup -1}.

Nancharaiah, Y.V.; Francis, A.

2011-06-01T23:59:59.000Z

177

Aggregation behavior of hexaoxyethyleneglycol myristate and hexaoxyethyleneglycol mono (1-methyltridecane) ether and dynamics of their micelles in aqueous solution  

Science Conference Proceedings (OSTI)

The title surfactants have similar critical micelle concentrations and cloud temperatures. Their micellar solutions have been investigated by time resolved fluorescence quenching in the range 2--25 c. The micelle aggregation numbers of both surfactants do not differ much, and increase with temperature. Aggregation numbers are large, suggesting anisotropic micelles, and the results show that the micelles are polydisperse. Fast intermicellar exchange of material becomes detectable on the fluorescence timescale ([approximately]1 [mu]s) above T [approx] 10 C, i.e., some 35--40 C below the cloud temperature of the solution. This exchange probably occurs via micelle collisions with temporary merging. Overall the behavior of these two surfactants is very similar to that of the other ethoxylated nonionic surfactants previously examined.

Alami, E.; Zana, R. (Inst. Charles Sadron, Strasbourg (France)); Van Os, N.M.; Jong, B. de; Kerkhof, F.J.M. (Koninklijke/Shell Lab., Amsterdam, (Netherlands)); Rupert, L.A.M. (Thornton Research Centre, Chester, (United Kingdom))

1993-10-01T23:59:59.000Z

178

Saturated hydraulic conductivity determined by on ground mono-offset Ground-Penetrating Radar inside a single ring infiltrometer  

E-Print Network (OSTI)

In this study we show how to use GPR data acquired along the infiltration of water inside a single ring infiltrometer to inverse the saturated hydraulic conductivity. We used Hydrus-1D to simulate the water infiltration. We generated water content profiles at each time step of infiltration, based on a particular value of the saturated hydraulic conductivity, knowing the other van Genuchten parameters. Water content profiles were converted to dielectric permittivity profiles using the Complex Refractive Index Method relation. We then used the GprMax suite of programs to generate radargrams and to follow the wetting front using arrival time of electromagnetic waves recorded by a Ground-Penetrating Radar (GPR). Theoretically, the 1D time convolution between reflectivity and GPR signal at any infiltration time step is related to the peak of the reflected amplitude recorded in the corresponding trace in the radargram. We used this relation ship to invert the saturated hydraulic conductivity for constant and fallin...

Léger, Emmanuel; Coquet, Yves

2013-01-01T23:59:59.000Z

179

Interactions between Copper(II) Complexes of Mono-, Bis-, and Tris(macrocyclic) Ligands and Inorganic or Organic Guests  

E-Print Network (OSTI)

] Department of Chemistry, State University of New York, College at Buffalo, 1300 Elmwood Ave, Buffalo, NY-N,N -(2-aminoethyl)propane-1,3-diamine] with formaldehyde and melamine (melamine = 2,4,6-tri- amino-1

Nazarenko, Alexander

180

Molecular water oxidation catalyst  

DOE Patents (OSTI)

A dimeric composition of the formula: ##STR1## wherein L', L", L'", and L"" are each a bidentate ligand having at least one functional substituent, the ligand selected from bipyridine, phenanthroline, 2-phenylpyridine, bipyrimidine, and bipyrazyl and the functional substituent selected from carboxylic acid, ester, amide, halogenide, anhydride, acyl ketone, alkyl ketone, acid chloride, sulfonic acid, phosphonic acid, and nitro and nitroso groups. An electrochemical oxidation process for the production of the above functionally substituted bidentate ligand diaqua oxo-bridged ruthenium dimers and their use as water oxidation catalysts is described.

Gratzel, Michael (St. Sulpice, CH); Munavalli, Shekhar (Bel Air, MD); Pern, Fu-Jann (Lakewood, CO); Frank, Arthur J. (Lakewood, CO)

1993-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mono alkyl ester" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Definition: Biodiesel | Open Energy Information  

Open Energy Info (EERE)

Biodiesel Biodiesel A renewable fuel that can be produced from a wide range of vegetable oils or animal fats. May be used either as a replacement for or as a component of diesel fuel. Additional technical definition: ASTM D6751 - 11b.[1][2] View on Wikipedia Wikipedia Definition Biodiesel refers to a vegetable oil- or animal fat-based diesel fuel consisting of long-chain alkyl esters. Biodiesel is typically made by chemically reacting lipids (e.g. , vegetable oil, animal fat) with an alcohol producing fatty acid esters. Biodiesel is meant to be used in standard diesel engines and is thus distinct from the vegetable and waste oils used to fuel converted diesel engines. Biodiesel can be used alone, or blended with petrodiesel. Biodiesel can also be used as a low carbon

182
183
185

Kinetics and Mechanism of Hydrogen-Atom Abstraction from Rhodium Hydrides by Alkyl Radicals in Aqueous Solutions  

DOE Green Energy (OSTI)

The kinetics of the reaction of benzyl radicals with [L{sup 1}(H{sub 2}O)RhH{l_brace}D{r_brace}]{sup 2+} (L{sup 1}=1,4,8,11-tetraazacyclotetradecane) were studied directly by laser-flash photolysis. The rate constants for the two isotopologues, k=(9.3 {+-} 0.6) x 10{sup 7} M{sup -1} s{sup -1} (H) and (6.2 {+-} 0.3) x 10{sup 7} M{sup -1} s{sup -1} (D), lead to a kinetic isotope effect k{sub H}/k{sub D}=1.5 {+-} 0.1. The same value was obtained from the relative yields of PhCH{sub 3} and PhCH{sub 2}D in a reaction of benzyl radicals with a mixture of rhodium hydride and deuteride. Similarly, the reaction of methyl radicals with {l_brace}[L{sup 1}(H{sub 2}O)RhH]{sup 2+} + [L{sup 1}(H{sub 2}O)RhD]{sup 2+}{r_brace} produced a mixture of CH{sub 4} and CH{sub 3}D that yielded k{sub H}/k{sub D}=1.42 {+-} 0.07. The observed small normal isotope effects in both reactions are consistent with reduced sensitivity to isotopic substitution in very fast hydrogen-atom abstraction reactions. These data disprove a literature report claiming much slower kinetics and an inverse kinetic isotope effect for the reaction of methyl radicals with hydrides of L{sup 1}Rh.

Pestovsky, Oleg; Veysey, Stephen W.; Bakac, Andrej

2011-03-22T23:59:59.000Z

186

Comparison of the use of sulfonate-derivatives of ethoxylated and/or propoxylated alkyl phenols in enhanced oil recovery  

SciTech Connect

Nonyl phenol has been ethoxylated and/or propoxylated: the results of the characterization of product non-ionic surfactants by NMR, hplc, and FAB-ms are described. These were then sulfonated and measurements of their phase equilibria: thermal and chemical stability: interfacial tension, viscosity, and contact angles, and rate and extent of adsorption were carried out as a function of temperature, salinity, and concentration, and in the presence and absence of co-surfactants and cosolvents to determine their EOR potential. Such properties are explained in terms of their molecular characteristics: these are related to de-oiling and surfactant flood results.

Lawrence, S.A.; Pilc, J.; Sermon, P.A.; Skidmore, P.G.; Hurd, B.G.; Broadhurst, P.V.

1988-05-01T23:59:59.000Z

187

Molecular Dynamics Study of a Surfactant-Mediated Decane-Water Interface: Effect of Molecular Architecture of Alkyl Benzene Sulfonate  

E-Print Network (OSTI)

Molecular Dynamics Study of a Surfactant-Mediated Decane-Water Interface: Effect of Molecular; In Final Form: May 25, 2004 The effect of molecular architecture of a surfactant, particularly and molecular alignment at the interface, than other surfactants simulated in this study. Furthermore

Goddard III, William A.

188

/sup 11/B and /sup 13/C NMR studies on silica modified by borate esters  

Science Conference Proceedings (OSTI)

/sup 11/B and /sup 13/C NMR has been applied along with programmed desorption and boron analysis to the surface of aerosol specimens modified by trimethoxyborane and dimethoxybutylborane. It is concluded that methanol is coordinated to the boron atoms in the dimethoxyborosilyl groups.

Kasperskii, V.A.; Brei, V.V.; Gorlov, Yu.I.; Chuiko, A.A.

1988-07-01T23:59:59.000Z

189

Dispersant optimization using design of experiments for SiC/vinyl ester nanocomposites  

E-Print Network (OSTI)

×, respectively. Strain 0.5 wt. % SiC with MPS and W966 #1 (didn't break) 0.5 wt. % SiC with MPS and W966 #2 neat #1 (bend test Strain 1 vol. % SiC with 1-octanol and decane

Yong, V; Hahn, H T

2005-01-01T23:59:59.000Z

190

Laboratory Investigations of Natural Ester Fluids to Better Predict Field Performance and Diagnostics  

Science Conference Proceedings (OSTI)

Fault development in transformers leads to increased formation of fault gases (H2, CH4, C2H2, C2H4, C2H6, CO, and CO2), moisture, and volatile organic compounds (VOCs). Although considerable research has been conducted for mineral-oil-filled transformers and industry standards established for dissolved gas analysis (DGA), very little information exists for vegetable oils and vegetable/mineral oil blends. The research work undertaken in this project is intended to determine the types and quantities of fau...

2007-11-30T23:59:59.000Z

191

207_06 Structural Analysis of Unsaturated Fatty Acid Methyl Ester Isomers with Acetonitrile Covalent  

Science Conference Proceedings (OSTI)

AOCS Press, Urbana, IL 61802 ©2006 by AOCS Press. All rights reserved. No part of this PDF may be repro-

192

Biodegradable microfluidic scaffolds for tissue engineering from amino alcohol-based poly(ester amide) elastomers  

E-Print Network (OSTI)

Biodegradable polymers with high mechanical strength, flexibility and optical transparency, optimal degradation properties and biocompatibility are critical to the success of tissue engineered devices and drug delivery ...

Wang, Jane

193

Indirect Determination of 3-MCPD and Glycidyl Esters in Oils and Fats. Correct or Wrong  

Science Conference Proceedings (OSTI)

K. Hrncirik & A. Ermacora 102nd AOCS Annual Meeting & Expo, May 1-4, 2011 Cincinnati, OH, USA 1 Karel Hrncirik, Alessia Ermacora Unilever R&D, The Netherlands 102nd AOCS Annual Meeting & Expo May 1-4, 2010 ? Duke En

194

Characterization of gaseous and particulate emissions from combustion of algae based methyl ester biodiesel.  

E-Print Network (OSTI)

??The advantages to using biodiesel in place of petroleum diesel are also accompanied by disadvantages. Biodiesel is usually made from crops that are also used… (more)

Fisher, Bethany Cheryl

2009-01-01T23:59:59.000Z

195

Monodisperse SiC/vinyl ester nanocomposites: Dispersant formulation, synthesis, and characterization  

E-Print Network (OSTI)

and S.F. Zhandarov: Carbon fibers and composites with epoxyepoxy resin com- posites, 22 carbon fiber filled epoxy resin

Yong, Virginia; Hahn, H. Thomas

2011-01-01T23:59:59.000Z

196

Advanced Biocatalytic Processing of Heterogeneous Lignocellulosic Feedstocks to a Platform Chemical Intermediate (Lactic acid Ester)  

SciTech Connect

The development of commercial boi-based processes and products derived from agricultural waste biomass has the potential for significant impact on the economy and security of our nation. Adding value, rather than disposing of the waste of agriculture, can solve an environmental problem and reduce our dependence on foreign sources of fossil fuel for production of chemicals, materials and fuels.

Dr. Sharon Shoemaker

2004-09-03T23:59:59.000Z

197

Phosphine-catalyzed asymmetric additions of malonate esters to gamma-substituted allenoates and allenamides  

E-Print Network (OSTI)

Because carbonyl groups are ubiquitous in organic chemistry, the ability to synthesize functionalized carbonyl compounds, particularly enantioselectively, is an important objective. We have developed a straightforward and ...

Sinisi, Riccardo

198

Hydrogen Bond-Assisted Supramolecular Self-Assembly of Doubly Discotic Supermolecules Based on Porphyrin and Triphenylene  

DOE Green Energy (OSTI)

Hydrogen bonding is a powerful driving force for the supramolecular self-assembly of discotic mesogens, and molecular shape also plays an important role in such systems. To study these effects, doubly discotic supermolecules have been synthesized by linking a meso-tetraphenylporphine-4,4{prime},4{double_prime},4(triple prime)-tetracarboxylic acid (Py) core with four triphenylenes (Tp) arms via either amide or ester bonds. The spacer length between the Py core and Tp disks was C6 and C10, and the alkyl arm length in the Tp disks was C5 and C12, respectively. Compared to the ester-linked Py(Tp){sub 4} supermolecules, the amide-linked samples exhibited rich crystalline and liquid-crystalline phases, suggesting that the intracolumnar hydrogen-bonding among trans amide bonds was the primary driving force for the self-assembly. X-ray diffraction (XRD) was used to understand the supramolecular self-assembly of the amide-linked Py(Tp){sub 4} doubly discotic supermolecules. When the spacer length was no shorter than or similar to the triphenylene alkyl arm length, a rectangular boardlike molecular shape was adopted and thus lamellar structures were obtained. When the spacer length was much shorter than the triphenylene alkyl arms, an ellipsoidal overall molecular shape resulted, and thus a regular columnar phase was obtained. From this study, we speculated that hydrogen-bond-induced microphase separation between moieties with different electron affinities in doubly discotic supermolecules may be useful for the practical applications of organic electronics.

Miao, J.; Zhu, L

2010-01-01T23:59:59.000Z

199

Catalytic applications of mono- and dinuclear complexes containing metal-carbon sigma bonds. Final report, November 1, 1993--October 31, 1996  

SciTech Connect

This report discusses results from several studies involved in the project. Investigations include: vibrational models for surface olefins and alkylidenes; mechanism of the formation and fragmentation of diosmacyclobutanes; reaction of dienes and allenes with diosmacyclobutanes; determination by nematic phase NMR of the structure of mononuclear and dinuclear ethylene complexes of osmium; and generation of ``coordinatively unsaturated`` complexes by protonation of methyl osmium complexes.

Norton, J.R.

1996-12-31T23:59:59.000Z

200

Stopping the growth of particles to silica-supported mono-nuclear Ru hydride surface species by tuning silica with surface silanes  

E-Print Network (OSTI)

chemical grafting of Ru(COD)(COT) through a covalent Ru-Siof a pentane solution of Ru(COD)(COT) under 3 bars of H 2 inhigh temperatures of grafted Ru(COD)(COT), leading to stable

Berthoud, Romain

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mono alkyl ester" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Microbial process for the preparation of acetic acid as well as solvent for its extraction from the fermentation broth  

DOE Patents (OSTI)

A modified water-immiscible solvent useful in the extraction of acetic acid from aqueous streams is a substantially pure mixture of isomers of highly branched di-alkyl amines. This solvent is substantially devoid of mono-alkyl amines and alcohols. Solvent mixtures formed of such a modified solvent with a desired cosolvent, preferably a low boiling hydrocarbon which forms an azeotrope with water are useful in the extraction of acetic acid from aqueous gaseous streams. An anaerobic microbial fermentation process for the production of acetic acid employs such solvents, under conditions which limit amide formation by the solvent and thus increase the efficiency of acetic acid recovery. Methods for the direct extraction of acetic acid and the extractive fermentation of acetic acid also employ the modified solvents and increase efficiency of acetic acid production. Such increases in efficiency are also obtained where the energy source for the microbial fermentation contains carbon dioxide and the method includes a carbon dioxide stripping step prior to extraction of acetic acid in solvent.

Gaddy, James L. (Fayetteville, AR); Clausen, Edgar C. (Fayetteville, AR); Ko, Ching-Whan (Fayetteville, AR); Wade, Leslie E. (Corpus Christi, TX); Wikstrom, Carl V. (Fayetteville, AR)

2002-01-01T23:59:59.000Z

202

Bellona rapport nr. 6 -2002 Bjrnar Kruse Sondre Grinna Cato Buch  

E-Print Network (OSTI)

Distillation High Vacuum Distillation Hydrotreating Isomerisation Catalytic Reforming Alkylation Polymerisation Atmospheric Distillation High Vacuum Distillation Hydrotreating Isomerisation Catalytic Reforming Alkylation

Krothapalli, Anjaneyulu

203

Succinoglycan: A new biopolymer for the oil field  

SciTech Connect

The succinoglycans are a family of extracellular, water-soluble polysaccharides produced by a number of Agrobacterium, Rhizobium and related bacteria. They have a repeating octasaccharide which contains seven glucose units and one galactose unit. There are four sugars in the backbone repeat and four in the side chain which is terminated by a pyruvate ketal. Their name derives from the presence of succinate as the mono-ester, at a frequency of approximately one per repeat. The position of substitution of the succinate is not yet not known, neither is that of acetate which is present in some strains. Polymers from different organisms have different proportions of the acid substituents and they have slightly different physical properties, particularly viscosity. Many strains, particularly the Rhizobia, produce polysaccharide only at a low rate, and much effort has been spent on obtaining a strain that produces a good polymer at a high rate.

Clarke-Sturman, A.J.; Den Ottelander, D.; Sturla, P.L.

1988-05-01T23:59:59.000Z

204

Biodiesel research progress 1992-1997  

DOE Green Energy (OSTI)

The US Department of Energy (DOE) Office of Fuels Development began evaluating the potential of various alternative fuels, including biodiesel, as replacement fuels for traditional transportation fuels. Biodiesel is derived from a variety of biological materials from waste vegetable grease to soybean oil. This alkyl ester could be used as a replacement, blend, or additive to diesel fuel. This document is a comprehensive summary of relevant biodiesel and biodiesel-related research, development demonstration, and commercialization projects completed and/or started in the US between 1992 and 1997. It was designed for use as a reference tool to the evaluating biodiesel`s potential as a clean-burning alternative motor fuel. It encompasses, federally, academically, and privately funded projects. Research projects are presented under the following topical sections: Production; Fuel characteristics; Engine data; Regulatory and legislative activities; Commercialization activities; Economics and environment; and Outreach and education.

Tyson, K.S. [ed.

1998-04-01T23:59:59.000Z

205

Antimicrobial Polymer  

DOE Patents (OSTI)

A polymeric composition having antimicrobial properties and a process for rendering the surface of a substrate antimicrobial are disclosed. The polymeric composition comprises a crosslinked chemical combination of (i) a polymer having amino group-containing side chains along a backbone forming the polymer, (ii) an antimicrobial agent selected from metals, metal alloys, metal salts, metal complexes and mixtures thereof, and (iii) a crosslinking agent containing functional groups capable of reacting with the amino groups. In one example embodiment, the polymer is a polyamide formed from a maleic anhydride or maleic acid ester monomer and alkylamines thereby producing a polyamide having amino substituted alkyl chains on one side of the polyamide backbone; the crosslinking agent is a phosphine having the general formula (A).sub.3 P wherein A is hydroxyalkyl; and the metallic antimicrobial agent is selected from chelated silver ions, silver metal, chelated copper ions, copper metal, chelated zinc ions, zinc metal and mixtures thereof.

McDonald, William F. (Utica, OH); Wright, Stacy C. (Flint, MI); Taylor, Andrew C. (Ann Arbor, MI)

2004-09-28T23:59:59.000Z

206

Antimocrobial Polymer  

DOE Patents (OSTI)

A polymeric composition having antimicrobial properties and a process for rendering the surface of a substrate antimicrobial are disclosed. The composition comprises a crosslinked chemical combination of (i) a polymer having amino group-containing side chains along a backbone forming the polymer, (ii) an antimicrobial agent selected from quaternary ammonium compounds, gentian violet compounds, substituted or unsubstituted phenols, biguanide compounds, iodine compounds, and mixtures thereof, and (iii) a crosslinking agent containing functional groups capable of reacting with the amino groups. In one embodiment, the polymer is a polyamide formed from a maleic anhydride or maleic acid ester monomer and alkylamines thereby producing a polyamide having amino substituted alkyl chains on one side of the polyamide backbone; the crosslinking agent is a phosphine having the general formula (A)3P wherein A is hydroxyalkyl; and the antimicrobial agent is chlorhexidine, dimethylchlorophenol, cetyl pyridinium chloride, gentian violet, triclosan, thymol, iodine, and mixtures thereof.

McDonald, William F. (Utica, OH); Huang, Zhi-Heng (Walnut Creek, CA); Wright, Stacy C. (Columbus, GA)

2005-09-06T23:59:59.000Z

207

Asymmetric Hydrogenations of Chiral Acyclic Alkenes for Important Chiron Syntheses  

E-Print Network (OSTI)

Hydrogenation of "largely unfunctionalized" alkenes has been an active area of research for about a decade. Many catalysts have been prepared but we noticed that comparatively few substrates have been studied and none of these hydrogenations provided useful chirons for the organic synthesis area. That motivated us to investigate asymmetric hydrogenations of chiral acyclic alkenes, which are seldom used for hydrogenations and usually the reactions are fully substrate controlled. It emerged that such reactions could provide a concise entry points into chirons that can be used to prepare many natural products. Asymmetric hydrogenations of functionalized, but not coordinatively functionalized, alkenes have been used to prepare several chirons for syntheses ofpolyketide natural products using our N,carbene Crabtree's catalyst analog. Starting from optically active starting materials (eg Roche esters, lactic acid, glyceraldehyde dimethyl ketals, amino acids), highly optically active chiral alkenes can be made in several steps with high yield. With the iridium catalyzed asymmetric hydrogenations, chiral ethers, 1,3-hydroxymethyl chiron, alpha-methyl-beta-hydroxy-gamma-methyl chiron, alpha-methyl-gamma-alkyl-gamma-amino acid can be obtained with high stereoselectivities. With those well developed methodologies, (-)-dihydromyoporone, (-)-spongidepsin, (-)-invictolide have been prepared with high efficiency. Not like the vinyl acetate, which can be hydrogenated quite well with many Rh catalysts, the alkyl vinyl ether does not have a coordination functional group nearby, hence it is a difficult substrate for asymmetric hydrogenation and there are relatively few iv reports. Also the simple alkyl enol ether is quite acid sensitive and the Pfatlz's type N,PIr catalysts cannot hydrogenate the simple alkyl enol ethers well under the standard hydrogenation conditions. We explored many alkyl enol ethers and found some of them can be hydrogenated efficiently (50 bar H2, 1 mol percent N,carbene-Ir catalyst, 25 degree C) with high enantioselectivities (up to 98 percent ee). This study led us to suspect that more protons were produced when N,P-Ir catalyst precursors were used relative to the corresponding carbene catalyst since the former only gave complex mixture when being used. DF calculations and several other experiments supported this postulation.

Zhu, Ye

2011-05-01T23:59:59.000Z

208

NIST MS Data Program  

Science Conference Proceedings (OSTI)

... Spectra that produce top matches with NIST 98 Acetic acid, 1-methylethyl ester Acetic acid, butyl ester Butanoic acid, 3-oxo-, methyl ester 1-Butanol ...

2009-11-20T23:59:59.000Z

209

Nuclear Magnetic Resonance Investigation of Dynamics in Poly(Ethylene Oxide) Based Lithium Polyether-ester-sulfonate Ionomers  

SciTech Connect

Nuclear magnetic resonance (NMR) spectroscopy has been utilized to investigate the dynamics of poly(ethylene oxide)-based lithium sulfonate ionomer samples that have low glass transition temperatures. 1H and 7Li spin-lattice relaxation times (T1) of the bulk polymer and lithium ions, respectively, were analyzed in samples with a range of ion contents. The temperature dependence of T1 values along with the presence of minima in T1 enabled correlation times and activation energies to be obtained for both the segmental motion of the polymer backbone and the hopping motion of lithium cations. Similar activation energies of both the polymer and lithium ions in the lower ion content samples indicate that the polymer segmental motion and lithium ion hopping motion are correlated even though their respective correlation times differ significantly. A divergent trend is observed for correlation times and activation energies of the highest ion content sample due to the presence of ionic aggregation. Details about the polymer and cation dynamics on the nanosecond timescale are discussed and complement the findings of X-ray scattering and Quasi Elastic Neutron Scattering experiments.

Roach, David J.; Dou, Shichen; Colby, Ralph H.; Mueller, Karl T.

2012-01-07T23:59:59.000Z

210

In-cylinder pressure characteristics of a CI engine using blends of diesel fuel and methyl esters of beef tallow  

Science Conference Proceedings (OSTI)

A Cummins N14-410 diesel engine was operated on 12 fuels produced by blending methyl tallowate, methyl soyate, and ethanol with no. 2 diesel fuel. Engine in-cylinder pressure data were used to evaluate engine performance. Peak cylinder pressures for each fuel blend at all engine speeds were lower than peak pressure for diesel fuel with the exception of the 80% diesel, 13% methyl tallowate, and 7% ethanol; and the 80% diesel, 6.5% methyl tallowate, 6.5% methyl soyate and 7% ethanol blends. The indicated mean effective pressure (IMEP) values for all fuel blends were less than for diesel fuel. The differences in IMEP values correlated with differences in power output of the engine. Similarly, maximum rates of pressure rise for most fuel blends were less than for diesel fuel. It was concluded that the fuel blends used in this study would have no detrimental long-term effects on engine performance, wear, and knock. 6 refs., 4 figs., 7 tabs.

Ali, Y.; Hanna, M.A.; Borg, J.E. [Univ. of Nebraska, Lincoln, NE (United States)

1996-05-01T23:59:59.000Z

211

Effects of POSS fiber sizing on the mechanical and thermal properties of carbon/vinyl ester composites.  

E-Print Network (OSTI)

??The degradation of polymer composites in moist environments is a limiting factor in the advancement of composite technology. The key to mitigate this degradation is… (more)

Powell, Felicia M.

2009-01-01T23:59:59.000Z

212

Kinetic Model Development for the Combustion of Particulate Matter from Conventional and Soy Methyl Ester Diesel Fuels  

DOE Green Energy (OSTI)

The primary objective of this research has been to investigate how the oxidation characteristics of diesel particulate matter (PM) are affected by blending soy-based biodiesel fuel with conventional ultra low sulfur diesel (ULSD) fuel. PM produced in a light duty engine from different biodiesel-conventional fuel blends was subjected to a range of physical and chemical measurements in order to better understand the mechanisms by which fuel-related changes to oxidation reactivity are brought about. These observations were then incorporated into a kinetic model to predict PM oxidation. Nanostructure of the fixed carbon was investigated by HR-TEM and showed that particulates from biodiesel had a more open structure than particulates generated from conventional diesel fuel, which was confirmed by BET surface area measurements. Surface area evolution with extent of oxidation reaction was measured for PM from ULSD and biodiesel. Biodiesel particulate has a significantly larger surface area for the first 40% of conversion, at which point the samples become quite similar. Oxidation characteristics of nascent PM and the fixed carbon portion were measured by temperature programmed oxidation (TPO) and it was noted that increased biodiesel blending lowered the light-off temperature as well as the temperature where the peak rate of oxidation occurred. A shift in the oxidation profiles of all fuels was seen when the mobile carbon fraction was removed, leaving only the fixed carbon, however the trend in temperature advantage of the biofuel blending remained. The mobile carbon fraction was measured by temperature programmed desorption found to generally increase with increasing biodiesel blend level. The relative change in the light-off temperatures for the nascent and fixed carbon samples was found to be related to the fraction of mobile carbon. Effective Arrhenius parameters for fixed carbon oxidation were directly measured with isothermal, differential oxidation experiments. Normalizing the reaction rate to the total carbon surface area available for reaction allowed for the definition of a single reaction rate with constant activation energy (112.5 {+-} 5.8 kJ/mol) for the oxidation of PM, independent of its fuel source. A kinetic model incorporating the surface area dependence of fixed carbon oxidation rate and the impact of the mobile carbon fraction was constructed and validated against experimental data.

Strzelec, Andrea [ORNL

2009-12-01T23:59:59.000Z

213

J. Am. Chem. SOC.1992, 114,1313-1314 7313 appear to be much better isoelectronic isosteres of sulfate esters  

E-Print Network (OSTI)

,N,N',N'-tetramethylbenzidine -3.17 1.39 X 10" 5.91 X lo9 aniline -3.02 1.55 X 1Olo 7.06 X lo9 p-dimethoxybenzene -2.73 1.17 X 1OIo

Yeh, Syun-Ru

214

Process and catalyst for carbonylating olefins  

DOE Patents (OSTI)

Disclosed is an improved catalyst system and process for preparing aliphatic carbonyl compounds such as aliphatic carboxylic acids, alkyl esters of aliphatic carboxylic acids and anhydrides of aliphatic carboxylic acids by carbonylating olefins in the presence of a catalyst system comprising (1) a first component selected from at least one Group 6 metal, i.e., chromium, molybdenum, and/or tungsten and (2) a second component selected from at least one of certain halides and tertiary and quaternary compounds of a Group 15 element, i.e., nitrogen, phosphorus and/or arsenic, and (3) as a third component, a polar, aprotic solvent. The process employing the improved catalyst system is carried out under carbonylating conditions of pressure and temperature discussed herein. The process constitutes and improvement over known processes since it can be carried out at moderate carbonylation conditions without the necessity of using an expensive noble metal catalyst, volatile, toxic materials such as nickel tetracarbonyl, formic acid or a formate ester. Further, the addition of a polar, aprotic solvent to the catalyst system significantly increases, or accelerates, the rate at which the carbonylation takes place.

Zoeller, Joseph Robert (Kingsport, TN)

1998-06-02T23:59:59.000Z

215

Kinetic solvation pressure: a measure of environmental effects on reaction rates. 1. Application to hydrophobic systems  

SciTech Connect

A quantity termed kinetic solvation pressure is defined as (/partial derivative//Delta/G/sup /double dagger////partial derivative//anti/V)/sub T/, where /anti/V is the reactant molar volume. It is identified with the difference in the amount of isothermal work, per unit volume expansion necessary to create a solvation cavity in a particular medium, upon transition-state complex formation. The quantity was evaluated for the hydrolysis of carboxylic esters mediated by different hydrophobic catalysts and was found to be equal to +26 J cm/sup /minus/3/ for the acid-catalyzed hydrolysis of n-alkyl acetates in water solvent; but it becomes negative when macro- or supramolecular acids were used as catalysts: /minus/16 J cm/sup /minus/3/ for Dowex 50W-X2, /minus/43J cm/sup /minus/3/ for poly(styrenesulfonic acid), /minus/64 J cm/sup /minus/3/ for dodecylsulfuric acid micelles. These results suggest the action of hydrophobic forces in enhancing the catalytic power of the supermolecules, relative to aqueous hydrogen ion. No such effect is seen in aqueous acetone or when more hydrophilic acetates are used as substrates. Kinetic solvation pressure for enzyme-catalyzed ester hydrolysis is five times more negative than for the resin system, indicating the full action of hydrophobic forces in the catalytic process.

Mata-Segreda, J.F.

1988-08-31T23:59:59.000Z

216

doi:10.4061/2011/615803 Review Article Production and Use of Lipases in Bioenergy: A Review from the Feedstocks to Biodiesel Production  

E-Print Network (OSTI)

License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. Lipases represent one of the most reported groups of enzymes for the production of biofuels. They are used for the processing of glycerides and fatty acids for biodiesel (fatty acid alkyl esters) production. This paper presents the main topics of the enzymebased production of biodiesel, from the feedstocks to the production of enzymes and their application in esterification and transesterification reactions. Growing technologies, such as the use of whole cells as catalysts, are addressed, and as concluding remarks, the advantages, concerns, and future prospects of enzymatic biodiesel are presented. 1. Lipid Feedstocks The main feedstocks which present paramount importance for the application of lipases are fats and oils. Such materials are primarily composed of triglycerides, which are glycerol esters with saturated and unsaturated fatty acids, from vegetable, animal, or microbial origins. One of the distinguishable characteristics between fats and oils is the occurrence of unsaturated and saturated fatty acids in the

Bernardo Dias Ribeiro; Aline Machado De Castro; Maria Alice Zarur Coelho; Denise Maria; Guimarăes Freire

2011-01-01T23:59:59.000Z

217

Self-assembly and soft material preparation of binary organogels via aminobenzimidazole/benzothiazole and acids with different alkyl substituent chains  

Science Conference Proceedings (OSTI)

The gelation behaviors of binary organogels composed of aminobenzimidazole/benzothiazole derivatives and benzoic acid with single-/multialkyl substituent chain in various organic solvents were designed and investigated. Their gelation behaviors in 20 ...

Tifeng Jiao, Keren Ma, Xihai Shen, Qingrui Zhang, Xiujin Li, Jingxin Zhou, Faming Gao

2013-01-01T23:59:59.000Z

218

Experimental study of the oxidation of methyl oleate in a jet-stirred reactor  

SciTech Connect

The experimental study of the oxidation of a blend containing n-decane and a large unsaturated ester, methyl oleate, was performed in a jet-stirred reactor over a wide range of temperature covering both low and high temperature regions (550-1100 K), at a residence time of 1.5 s, at quasi atmospheric pressure with high dilution in helium (n-decane and methyl oleate inlet mole fractions of 1.48 x 10{sup -3} and 5.2 x 10{sup -4}) and under stoichiometric conditions. The formation of numerous reaction products was observed. At low and intermediate temperatures, the oxidation of the blend led to the formation of species containing oxygen atoms like cyclic ethers, aldehydes and ketones deriving from n-decane and methyl oleate. At higher temperature, these species were not formed anymore and the presence of unsaturated species was observed. Because of the presence of the double bond in the middle of the alkyl chain of methyl oleate, the formation of some specific products was observed. These species are dienes and esters with two double bonds produced from the decomposition paths of methyl oleate and some species obtained from the addition of H-atoms, OH and HO{sub 2} radicals to the double bond. Experimental results were compared with former results of the oxidation of a blend of n-decane and methyl palmitate performed under similar conditions. This comparison allowed highlighting the similarities and the differences in the reactivity and in the distribution of the reaction products for the oxidation of large saturated and unsaturated esters. (author)

Bax, Sarah; Hakka, Mohammed Hichem; Glaude, Pierre-Alexandre; Herbinet, Olivier; Battin-Leclerc, Frederique [Laboratoire Reactions et Genie des Procedes, Nancy Universite, CNRS, ENSIC, BP 20451, 1 rue Grandville, 54001 Nancy (France)

2010-06-15T23:59:59.000Z

219

Surfactant loss control in chemical flooding: Spectroscopic and calorimetric study of adsorption and precipitation on reservoir minerals. Quarterly technical progress report, October 1, 1993--December 31, 1993  

Science Conference Proceedings (OSTI)

The aim of this contract is to elucidate the mechanisms underlying adsorption and surface precipitation of flooding surfactants on reservoir minerals. Effect of surfactant structure, surfactant combinations and other inorganic and polymeric species and solids of relevant mineralogy will also be determined. A multi-pronged approach consisting of micro & nano spectroscopy, microcalorimetry, electrokinetics, surface tension and wettability win be used to achieve the goals. The results of this study should help in controlling surfactant loss in chemical flooding and also in developing optimum structures and conditions for efficient chemical flooding processes. Adsorption/desorption of tetradecyl trimethyl ammonium chloride (TTAC) and sodium dodecyl sulfate (SDS)/octaethylene glycol mono n-decyl ether (C{sub 12}EO{sub 8}) surfactant mixtures at the kaolinite-water and alumina-water interfaces was studied during this quarter. The microstructure of the adsorbed layer was investigated using spectroscopic techniques. Effect of the hydrocarbon chain length of octaethylene glycol mono n-alkyl ether (C{sub n}EO{sub 8}) type nonionic surfactants on the adsorption of 1:1 mixtures of sodium dodecyl sulfate (SDS)/C{sub n}EO{sub 8} at the kaolinite/water interface was studied. The adsorption of SDS was enhanced by the presence of C{sub 10}EO{sub 8} but this effect was not as significant as those by C{sub 12--16}EO{sub 8}. Interestingly, once the hydrocarbon chain length of the nonionic surfactant exceeded that of the SDS (12) there was no further enhancement of SDS adsorption.

Somasundaran, P.

1994-02-22T23:59:59.000Z

220

Available Technologies: Using Novel Enzymes To Produce ...  

Controlled placement of ester linkages may result in enhanced combustion properties; Esters and lactones are more hydrophobic than their corresponding ...

Note: This page contains sample records for the topic "mono alkyl ester" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Production of levulinic acid, furfural, and gamma valerolactone from C.sub.5 and C.sub.6 carbohydrates in mono- and biphasic systems using gamma-valerolactone as a solvent  

DOE Patents (OSTI)

A method to make levulinic acid (LA), furfural, or gamma-valerolactone (GVL). React cellulose (and/or other C.sub.6 carbohydrates) or xylose (and/or other C.sub.5 carbohydrates) or combinations thereof in a monophasic reaction medium comprising GVL and an acid; or (ii) a biphasic reaction system comprising an organic layer comprising GVL, and a substantially immiscible aqueous layer. At least a portion of the cellulose (and/or other C.sub.6 carbohydrates), if present, is converted to LA and at least a portion of the xylose (and/or other C.sub.5 carbohydrates), if present, is converted into furfural.

Dumesic, James A.; Alonso, David Martin; Gurbuz, Elif I.; Wettstein, Stephanie G.

2013-03-19T23:59:59.000Z

222

Productization and Manufacturing Scaling of High-Efficiency Solar Cell and Module Products Based on a Disruptive Low-Cost, Mono-Crystalline Technology: Final Technical Progress Report, April 1, 2009 - December 30, 2010  

DOE Green Energy (OSTI)

Final report for PV incubator subcontract with Solexel, Inc. The purpose of this project was to develop Solexel's Unique IP, productize it, and transfer it to manufacturing. Silicon constitutes a significant fraction of the total solar cell cost, resulting in an industry-wide drive to lower silicon usage. Solexel's disruptive Solar cell structure got around these challenges and promised superior light trapping, efficiency and mechanical strength, despite being significantly thinner than commercially available cells. Solexel's successful participation in this incubator project became evident as the company is now moving into commercial production and position itself to be competitive for the next Technology Pathway Partnerships (TPP) funding opportunity.

Fatemi, H.

2012-07-01T23:59:59.000Z

223

Chemical agent decontamination composition comprising a ...  

U.S. Energy Information Administration (EIA)

Title: Chemical agent decontamination composition comprising a perfluorinated alkyl bromide Date: 05/13/2008

224

Formation of methyl ester of 2-methylglyceric acid from thymine glycol residues: a convenient new method for determining radiation damage to DNA  

Science Conference Proceedings (OSTI)

Thymine glycol residues in DNA or thymidine were converted to methyl 2-methylglycerate by reaction with alkaline borohydride followed by methanolic HCl. The product was labeled either from (/sup 3/H)DNA or from (/sup 3/H)borohydride and was followed by cochromatography with authentic /sup 14/C-labeled material. Following acid hydrolysis, the identity of 2-methylglyceric acid was confirmed by high-resolution mass spectrometry, NMR, IR, and elemental analysis. Treatment of DNA or thymidine with X-irradiation, with H/sub 2/O/sub 2/ and Fe/sup 2 +/, with H/sub 2/O/sub 2/, Cu/sup 2 +/, and ascorbate, and with H/sub 2/O/sub 2/ and ultraviolet light, permanganate, or sonication all produced methyl 2-methylglycerate in varying amounts after alkaline borohydride and methanolic HCl, whereas untreated DNA did not. The data indicate that certain oxidants including hydroxyl radicals generated by chemical means or from radiolysis of water convert thymine residues to thymine glycols in DNA, which can be determined as methyl 2-methylglycerate.

Schellenberg, K.A.; Shaeffer, J.

1986-04-08T23:59:59.000Z

225

Down-regulation of four putative arabinoxylan feruloyl transferase genes from family PF02458 reduces ester-linked ferulate content in rice cell walls  

E-Print Network (OSTI)

materials for ef?cient bioethanol production. In: Olsson L,BE (2004) Global potential bioethanol production from wasted

Piston, Fernando; Uauy, Cristobal; Fu, Lianhai; Langston, James; Labavitch, John; Dubcovsky, Jorge

2010-01-01T23:59:59.000Z

226

I. Pt-Catalyzed Tandem Epoxide Fragmentation/Pentannulation of Propargylic Esters II. Progress Toward the Kopsia Family of Indole Alkaloids  

E-Print Network (OSTI)

N H NO 2 BnO N H xylenes, catechol BnO N H 2 , Pd/C NH 2 BnOBnO N H NO 2 BnO N H xylenes, catechol 3-(2-Nitroethyl)-5-1.1 equiv. ), and 3-methyl-catechol (250 mg, 2.3 mmol, 0.1

Pujanauski, Brian Gerard

2010-01-01T23:59:59.000Z

227

Effect of protein kinase C inhibitors on the actions of phorbol esters on vascular tone and adrenergic transmission in the isolated rat kidney  

SciTech Connect

The effect of protein kinase C (PKC) inhibitors 1-(5-isoquinoline-sulfonyl)-2-methylpiperazine (H-7), polymyxin B (PMB), D-sphingosine (SPH), sangivamycin (SNG) and staurosporin (ST) on the action of PKC activators phorbol 12,13-dibutyrate (PDBu) and 12-o-tetradecanoylphorbol-13-acetate (TPA), on adrenergic neuroeffector events was investigated to determine the contribution of PKC in adrenergic transmission in the rat kidney. Infusion of TPA (5 x 10(-6) mM) or PDBu (6 x 10(-6) mM) produced renal vasoconstriction and enhanced the overflow of tritium elicited by periarterial renal nerve stimulation (RNS) (2 Hz) in the isolated rat kidney perfused with Tyrode's solution and prelabeled with (3H)norepinephrine. H-7 (2.7 x 10(-3) mM) and ST (2 x 10(-5) mM) did not alter RNS-induced overflow of tritium but attenuated the vasoconstrictor response to RNS and exogenous NE. PMB (1 x 10(-8) mM) and SPH (3.3 x 10(-4) mM) but not SNG (3.3 x 10(-3) mM) attenuated the RNS-induced overflow of tritium but increased the basal renal vascular tone and enhanced the vasoconstrictor response to RNS and exogenous NE. H-7, PMB, SPH, SNG or ST failed to alter the effects of PDBu to increase basal vascular tone and the overflow of tritium and the increase in renal vasoconstriction to RNS. PMB at 1 x 10(-9) mM but not at 1 x 10(-8) mM and SPH (3.3 x 10(-4) mM) but not H-7, SNG or ST inhibited the effect of TPA to increase the overflow of tritium. The effect of TPA on the vasoconstrictor response to RNS or to increase basal vascular tone was not altered by PKC inhibitors. These data suggest that in the rat kidney, PKC is either resistant to the actions of H-7, PMB, SPH, SNG and ST, or PDBu and TPA produce renal vasoconstriction and facilitate adrenergic transmission by a mechanism unrelated to PKC activation.

Sehic, E.; Malik, K.U. (Univ. of Tennessee, Memphis (USA))

1990-05-01T23:59:59.000Z

228

Radial-Basis-Function-Network-Based Prediction of Performance and Emission Characteristics in a Bio Diesel Engine Run on WCO Ester  

E-Print Network (OSTI)

Radial basis function neural networks (RBFNNs), which is a relatively new class of neural networks, have been investigated for their applicability for prediction of performance and emission characteristics of a diesel ...

Kumar, Shiva

2012-01-01T23:59:59.000Z

229

Down-regulation of four putative arabinoxylan feruloyl transferase genes from family PF02458 reduces ester-linked ferulate content in rice cell walls  

E-Print Network (OSTI)

feedstock for biofuel production. It has been estimated thatcell walls, both for biofuel production or to improve the

Piston, Fernando; Uauy, Cristobal; Fu, Lianhai; Langston, James; Labavitch, John; Dubcovsky, Jorge

2010-01-01T23:59:59.000Z

230

Down-regulation of four putative arabinoxylan feruloyl transferase genes from family PF02458 reduces ester-linked ferulate content in rice cell walls  

E-Print Network (OSTI)

cell wall in grasses. Keywords Biofuels Á Digestibility Áa broader adaptation of biofuels. One of the limitations foryield and composition for biofuels. Crop Sci 47:2211–2227

Piston, Fernando; Uauy, Cristobal; Fu, Lianhai; Langston, James; Labavitch, John; Dubcovsky, Jorge

2010-01-01T23:59:59.000Z

231

Identification of cis-acting sequences responsible for phorbol ester induction of human serum amyloid A gene expression via a nuclear factor kB-like transcription factor  

Science Conference Proceedings (OSTI)

The authors have analyzed the 5'-flanking region of one of the genes coding for the human acute-phase protein, serum amyloid A (SAA). They found that SAA mRNA could be increased fivefold in transfected cells by treatment with phorbol 12-myristate 13-acetate (PMA). To analyze this observation further, they placed a 265-base-pair 5' SAA fragment upstream of the reporter chloramphenicol acetyltransferase (CAT) gene and transfected this construct into HeLa cells. PMA treatment of these transient transfectants resulted in increased CAT expression. Nuclear proteins from PMA-treated HeLa cells bound to this DNA fragment, and methylation interference analysis showed that the binding was specific to the sequence GGGACTTTCC (between -82 and -91), a sequence previously described by others as the binding site for the nuclear factor NF/kappa/B. In a cotransfection competition experiment, they could abolish PMA-induced CAT activity by using cloned human immunodeficiency virus long-terminal-repeat DNA containing the NF/kappa/B-binding sequence. The same long-terminal-repeat DNA containing mutant NF/kappa/B-binding sequences did not affect CAT expression, which suggested that binding by an NF/kappa/B-like factor is required for increased SAA transcription.

Edbrooke, M.R.; Cheshire, J.K.; Woo, P.; Burt, B.W.

1989-05-01T23:59:59.000Z

232

Mechanism of photoreductive stripping of iron(III) in a liquid-liquid extraction system and its application for a hydrometallurgical process  

SciTech Connect

The mechanism of the photoreductive stripping of iron(III) in the liquid-liquid extraction process was investigated by employing (2-ethylhexyl)phosphonic acid mono(2-ethylhexyl) ester (EHPNA) and bis(2-ethylhexyl)phosphoric acid (D2EHPA) as extractants, n-dodecane and kerosene as diluents, and a xenon lamp as the light source. The photoreductive stripping of iron(III) progressed by photoirradiation following an initial induction period caused by dissolved oxygen in the extraction system. The iron(III)-extractant complex was photoexcited in the organic phase and photoreduced to the iron(II) complex by electron donation from the water at the aqueous/organic interface. A kinetic study of the photoreductive stripping of iron(III) revealed that the photochemical reduction of iron(III) was the rate-determining step. The removal of iron from a simulated zinc refinery residue solution by using liquid-liquid extraction combined with photochemical reduction of iron was also investigated, showing that the rare metals in the refinery residue, gallium and indium, were recovered effectively and leaving almost all iron(III) in the aqueous phase.

Nishihama, Syouhei; Hirai, Takayuki; Komasawa, Isao

1999-12-01T23:59:59.000Z

233

Genome analysis and physiological comparison of Alicycliphilus denitrificans strains BC and K601T  

Science Conference Proceedings (OSTI)

The genomes of the Betaproteobacteria Alicycliphilus denitrificans strains BC and K601T have been sequenced to get insight into the physiology of the two strains. Strain BC degrades benzene with chlorate as electron acceptor. The cyclohexanol-degrading denitrifying strain K601T is not able to use chlorate as electron acceptor, while strain BC cannot degrade cyclohexanol. The 16S rRNA sequences of strains BC and K601T are identical and the fatty acid methyl ester patterns of the strains are similar. Basic Local Alignment Search Tool (BLAST) analysis of predicted open reading frames of both strains showed most hits with Acidovorax sp. JS42, a bacterium that degrades nitro-aromatics. The genomes include strain-specific plasmids (pAlide201 in strain K601T and pAlide01 and pAlide02 in strain BC). Key genes of chlorate reduction in strain BC were located on a 120 kb megaplasmid (pAlide01), which was absent in strain K601T. Genes involved in cyclohexanol degradation were only found in strain K601T. Benzene and toluene are degraded via oxygenase-mediated pathways in both strains. Genes involved in the meta-cleavage pathway of catechol are present in the genomes of both strains. Strain BC also contains all genes of the ortho-cleavage pathway. The large number of mono- and dioxygenase genes in the genomes suggests that the two strains have a broader substrate range than known thus far.

Oosterkamp, Margreet J. [Wageningen University and Research Centre, The Netherlands; Veuskens, Teun [Wageningen University and Research Centre, The Netherlands; Saia, Flavia Talarico [Wageningen University and Research Centre, The Netherlands; Weelink, Sander A.B. [Wageningen University and Research Centre, The Netherlands; Goodwin, Lynne A. [Los Alamos National Laboratory (LANL); Daligault, Hajnalka E. [Los Alamos National Laboratory (LANL); Bruce, David [Los Alamos National Laboratory (LANL); Detter, J. Chris [U.S. Department of Energy, Joint Genome Institute; Tapia, Roxanne [Los Alamos National Laboratory (LANL); Han, Cliff [Los Alamos National Laboratory (LANL); Land, Miriam L [ORNL; Hauser, Loren John [ORNL; Langenhoff, A. M. [Deltares, The Netherlands; Gerritse, Jan [Deltares, The Netherlands; Van Berkel, Willem J. H. [Wageningen University and Research Centre, The Netherlands; Pieper, Dietmar [HZI - Helmholtz Centre for Infection Research, Braunschweig, Germany; Junca, Howard [CorpoGen, Bogota Colombia; Smidt, Hauke [Wageningen University and Research Centre, The Netherlands; Schraa, Gosse [Wageningen University and Research Centre, The Netherlands; Davids, Mark [Wageningen University and Research Centre, The Netherlands; Schaap, Peter J [Wageningen University and Research Centre, The Netherlands; Plugge, Caroline M. [Wageningen University and Research Centre, The Netherlands; Stams, Alfons J. M. [Wageningen University and Research Centre, The Netherlands

2013-01-01T23:59:59.000Z

234

Oligomeric Dithienopyrrole-Thienopyrrolodione (DTP-TPD) Donor-Acceptor Copolymer for Organic Photovoltaics: Preprint  

DOE Green Energy (OSTI)

A new donor-acceptor copolymer system based upon a dithienopyrrole (DTP) donor moiety and a thienopyrrolodione (TPD) accepting moiety has been designed and synthesized for organic photovoltaic (OPV) applications. The TPD accepting moiety has recently gained significant attention in the OPV community and is being incorporated into a number of different polymer systems. In contrast, the DTP donor moiety has received only limited attention, likely due in part to synthetic difficulties relating to the monomer. In our hands, the bis(trimethyltin)-DTP monomer was indelibly contaminated with ~5% of the mono-destannylated DTP, which limited the Stille polymerization with the dibromo-TPD monomer (>99% pure) to produce material with Mn ~ 4130 g/mol (PDI = 1.10), corresponding to around eight repeat units. Despite this limitation, UV-visible absorption spectroscopy demonstrates strong absorption for this material with a band gap of ~1.6 eV. Cyclic voltammetry indicates a highest occupied molecular orbital (HOMO) energy level of -5.3 eV, which is much lower than calculations predicted. Initial bulk heterojunction OPV devices fabricated with the fullerene acceptor phenyl C61 butyric acid methyl ester (PCBM) exhibit Voc ~ 700 mV, which supports the deep HOMO value obtained from CV. These results suggest the promise of this copolymer system.

Hammond, S. R.; Braunecker, W.; Garcia, A.; Larsen, R.; Owczarczyk, Z.; Olson, D.; Ginley, D.

2011-07-01T23:59:59.000Z

235

Figure S1. Relative contribution to total OH reactivity (a), of observed VOCs to calculated OH reactivity (b) and alkyl nitrate production (c,d) in the afternoon (12pm  

E-Print Network (OSTI)

.0050 0.65 i-butane 0.77 0.02 2.31E-12(4) 0.00088 0.086 n-Butane 2.2 0.077 2.51E-12(2) 0.011 0.26 n 0.05* 0.1 5.08E-12(2) 0.00048 0.0086 #12;4 2,3-dimethyl butane 0.17* 0.14 2.32E-12(10) 0.00048 0

Meskhidze, Nicholas

236

Modeling the Geometric Electronic and Redox Properties of Iron(lll)-Containing Amphiphiles with Asymmetric [NNO] Headgroups  

DOE Green Energy (OSTI)

Two iron(III)-containing amphiphiles 1 and 2 have been synthesized with the [NN'O] ligands HL{sup tBu-ODA} (2-((octadecyl(pyridin-2-ylmethyl)amino)methyl)-4,6-di-tert-butylphenol) and HL{sup I-ODA} (2-((octadecyl(pyridin-2-ylmethyl)amino)methyl)-4,6-diiodophenol), respectively. Compound 1 is monometallic, whereas EXAFS data suggest that 2 is a mixture of mono- and bimetallic species. The archetypical [Fe{sup III}(L{sup NN'O}){sub 2}]{sup +} complexes 3-9 have been isolated and characterized in order to understand the geometric, electronic, and redox properties of the amphiphiles. Preference for a monometallic or bimetallic nuclearity is dependent on (i) the nature of the solvent used for synthesis and (ii) the type of the substituent in the phenol moiety. In methanol, the tert-butyl-, methoxy-, and chloro-substituted 3, 4, and 5 are monometallic species, whereas the bromo- and iodo-substituted 6 and 7 form bimetallic complexes taking advantage of stabilizing methoxo bridges generated by solvent deprotonation. In dichloromethane, the bromo- and iodo-substituted 8 and 9 are monometallic species; however, these species favor meridional coordination in opposition to the facial coordination observed for the tert-butyl- and methoxy-substituted compounds. Molecular structures for species 5, 7, 8, and 9 have been solved by X-ray diffraction. Furthermore, the electronic spectrum of the amphiphile 1 was expected to be similar to those of facial/cis archetypes with similar substituents, but close resemblance was observed with the profile for those meridional/cis species, suggesting a similar coordination mode. This trend is discussed based on DFT calculations, where preference for the meridional/cis coordination mode appears related to the presence of tertiary amine nitrogen on the ligand, as when a long alkyl chain is attached to the [NN'O] headgroup.

R Shakya; M Allard; M Johann; M Heeg; E Rentschler; J Shearer; B McGarvey; C Verani

2011-12-31T23:59:59.000Z

237

Decontamination of water using nitrate selective ion exchange resin  

DOE Patents (OSTI)

A method for nitrate decontamination of water which involves passing the water through a bed of alkyl phosphonium anion exchange resin which has pendant alkyl groups of C[sub 3] or larger.

Lockridge, J.E.; Fritz, J.S.

1990-07-31T23:59:59.000Z

238

VarPetrRef 1 VARIETY AND THE EVOLUTION OF REFINERY PROCESSING  

E-Print Network (OSTI)

. Catalytic reforming followed as a means of upgrading the octane of gasoline range materials principally): Catalytic reforming, Isomerization, Alkylation, Catalytic polymerization, MTBE and Hydrotreating. The last Distillation Visbreaking Hydrotreating Hydrocracking Thermal Reforming Alkylation MTBE Catalytic Reform ing

Paris-Sud XI, Université de

239

Decontamination of water using nitrate selective ion exchange resin  

DOE Patents (OSTI)

A method for nitrate decontamination of water which involves passing the water through a bed of alkyl phosphonium anion exchange resin which has pendant alkyl groups of C.sub.3 or larger.

Lockridge, James E. (Ames, IA); Fritz, James S. (Ames, IA)

1990-07-31T23:59:59.000Z

240

Weekly Petroleum Status Report  

U.S. Energy Information Administration (EIA) Indexed Site

5 5 Alcohol. The family name of a group of organic chemical compounds composed of carbon, hydrogen, and oxygen. The series of molecules vary in chain length and are composed of a hydrocarbon plus a hydroxyl group; CH3-(CH2)n-OH (e.g., methanol, ethanol, and tertiary butyl alcohol). Alkylate. The product of an alkylation reaction. It usually refers to the high octane product from alkylation units. This alkylate is used in

Note: This page contains sample records for the topic "mono alkyl ester" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

TMS 2011: Exhibitor Details  

Science Conference Proceedings (OSTI)

Typical applications include Aluminium smelting, Refineries (esp. HF Alkylation), Petrochemical and Chemical Plants, Gas Production and Processing, Green ...

242

This is a working document prepared by the Energy Information ...  

U.S. Energy Information Administration (EIA)

downstream processing technologies (hydro-cracker, fluid cat-cracker, coker, reformer, alkylation, and polymerization) for further processing and upgrading.

243

Formation mechanisms and quantification of organic nitrates in atmospheric aerosol  

E-Print Network (OSTI)

Atmospheric submicron aerosol . . . . . . . 2.3 Partitioningon SOA organic aerosol formation alkyl nitrate and secondaryPeroxy radical fate . . . . . . Aerosol . . . . . . . .

Rollins, Andrew Waite

2010-01-01T23:59:59.000Z

244

Morphological Phase Behavior of Poly(RTIL)-Containing Diblock Copolymer Melts  

Science Conference Proceedings (OSTI)

The development of nanostructured polymeric systems containing directionally continuous poly(ionic liquid) (poly(IL)) domains has considerable implications toward a range of transport-dependent, energy-based technology applications. The controlled, synthetic integration of poly(IL)s into block copolymer (BCP) architectures provides a promising means to this end, based on their inherent ability to self-assemble into a range of defined, periodic morphologies. In this work, we report the melt-state phase behavior of an imidazolium-containing alkyl-ionic BCP system, derived from the sequential ring-opening metathesis polymerization (ROMP) of imidazolium- and alkyl-substituted norbornene monomer derivatives. A series of 16 BCP samples were synthesized, varying both the relative volume fraction of the poly(norbornene dodecyl ester) block (f{sub DOD} = 0.42-0.96) and the overall molecular weights of the block copolymers (M{sub n} values from 5000-20,100 g mol{sup -1}). Through a combination of small-angle X-ray scattering (SAXS) and dynamic rheology, we were able to delineate clear compositional phase boundaries for each of the classic BCP phases, including lamellae (Lam), hexagonally packed cylinders (Hex), and spheres on a body-centered-cubic lattice (S{sub BCC}). Additionally, a liquid-like packing (LLP) of spheres was found for samples located in the extreme asymmetric region of the phase diagram, and a persistent coexistence of Lam and Hex domains was found in lieu of the bicontinuous cubic gyroid phase for samples located at the intersection of Hex and Lam regions. Thermal disordering was opposed even in very low molecular weight samples, detected only when the composition was highly asymmetric (f{sub DOD} = 0.96). Annealing experiments on samples exhibiting Lam and Hex coexistence revealed the presence of extremely slow transition kinetics, ultimately selective for one or the other but not the more complex gyroid phase. In fact, no evidence of the bicontinuous network was detected over a 2 month annealing period. The ramifications of these results for transport-dependent applications targeting the use of highly segregated poly(IL)-containing BCP systems are carefully considered.

Scalfani, Vincent F.; Wiesenauer, Erin F.; Ekblad, John R.; Edwards, Julian P.; Gin, Douglas L.; Bailey, Travis S. (CSU); (Colorado)

2012-10-23T23:59:59.000Z

245

Petroleum Supply Monthly  

Gasoline and Diesel Fuel Update (EIA)

0 0 December 2011 Alcohol. The family name of a group of organic chemical compounds composed of carbon, hydrogen, and oxygen. The series of molecules vary in chain length and are composed of a hydrocarbon plus a hydroxyl group; CH3-(CH2)n-OH (e.g., methanol, ethanol, and tertiary butyl alcohol). Alkylate. The product of an alkylation reaction. It usually refers to the high octane product from alkylation units. This alkylate is used in blending high octane gasoline. Alkylation. A refining process for chemically combining isobutane with olefin hydrocarbons (e.g., propylene, butylene) through the control of temperature and pressure in the presence of an acid catalyst,

246

Petroleum Supply Monthly  

U.S. Energy Information Administration (EIA) Indexed Site

September 2013 September 2013 Alcohol. The family name of a group of organic chemical compounds composed of carbon, hydrogen, and oxygen. The series of molecules vary in chain length and are composed of a hydrocarbon plus a hydroxyl group; CH3-(CH2)n-OH (e.g., methanol, ethanol, and tertiary butyl alcohol). Alkylate. The product of an alkylation reaction. It usually refers to the high octane product from alkylation units. This alkylate is used in blending high octane gasoline. Alkylation. A refining process for chemically combining isobutane with olefin hydrocarbons (e.g., propylene, butylene) through the control of temperature and pressure in the presence of an acid catalyst,

247

Methods of making transportation fuel  

SciTech Connect

A method for producing alkylated hydrocarbons is disclosed. Formation fluid is produced from a subsurface in situ heat treatment process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes olefins. The liquid stream is fractionated to produce at least a second gas stream including hydrocarbons having a carbon number of at least 3. The first gas stream and the second gas stream are introduced into an alkylation unit to produce alkylated hydrocarbons. At least a portion of the olefins in the first gas stream enhance alkylation. The alkylated hydrocarbons may be blended with one or more components to produce transportation fuel.

Roes, Augustinus Wilhelmus Maria (Houston, TX); Mo, Weijian (Sugar Land, TX); Muylle, Michel Serge Marie (Houston, TX); Mandema, Remco Hugo (Houston, TX); Nair, Vijay (Katy, TX)

2012-04-10T23:59:59.000Z

248

Pyrolysis of shale oil residual fractions  

SciTech Connect

The freezing point of JP-5, the Navy jet fuel, has been related to the n-alkane content, specifically n-hexadecane. In general, jet fuels from shale oil have the highest n-alkanes. The formation of n-alkanes in the jet fuel distillation range can be explained if large n-alkanes are present in the crude oil source. Quantities of large n-alkanes are insufficient, however, to explain the amounts found - up to 37% n-alkanes in the jet fuel range. Other possible precursors to small straight chain molecules are substituted cyclic compounds. Attack in the side chain obviously afford a path to an n-alkane. Aromatic hydrocarbons, esters, acids, amines, and ethers also have the potential to form n-alkanes if an unbranched alkyl chain is present in the molecule. Investigations showed that the best yield of the JP-5 cut comes at different times for the various fractions, but a time in the 60 to 120 min range would appear to be the optimum time for good yield at 450/sup 0/C. The longer time would be preferred with respect to lower potential n-alkane yield. None of the fractions gave n-alkane yields approaching the 37% amount found in the Shale-I JP-5. A temperature different than the 450/sup 0/C used here might affect the conversion percentage. Further the combined saturate, aromatic, and polar fractions may interact under pyrolysis conditions to give higher potential n-alkane yields than the fractions stressed independently.

Hazlett, R.N.; Beal, E.; Vetter, T.; Sonntag, R.; Moniz, W.

1980-01-01T23:59:59.000Z

249

Novel Fischer-Tropsch catalysts  

DOE Patents (OSTI)

Novel polymer-supported metal complexes of the formula: PS --R Me(CO).sub.n H.sub.m where: PS represents a divinylbenzene crosslinked polystyrene in which the divinylbenzene crosslinking is greater than 1% and less than about 18%; R represents a cycloalkadienyl radical of 4 through 6 carbon atoms; Me represents a Group VIII metal; CO represents a carbonyl radical; H represents hydrogen; n represents an integer varying from 0 through 3; m represents an integer varying from 0 through 2 inclusively with the further provision that 2n+m must total 18 when added to the electrons in R and Me, or n+m must total 0; are prepared by: brominating PS --H by treating same with bromine in the presence of a thallium salt in a partially or fully halogenated solvent to form PS --Br; treating said PS --Br so produced with a lithium alkyl of 1 through 12 carbon atoms in an aromatic solvent to produce PS --Li; substituting said PS-- Li so produced by reaction with a 2-cycloalkenone of 4 to 6 carbon atoms in the presence of an ether solvent and using a water work-up to form a cycloalkenylalcohol-substituted PS ; dehydrating said alcohol so produced by heating under a vacuum to produce a cycloalkadienyl-substituted PS ; reacting the cycloalkadienyl-substituted PS with metal carbonyl in the presence of a partially or fully halogenated hydrocarbon, aromatic hydrocarbon of 6 through 8 carbon atoms, ethers, or esters of 4 through 10 carbon atoms as a solvent to produce a polystyrene-supported cycloalkadienyl metal carbonyl. The novel compounds are used as improved Fischer-Tropsch catalysts particularly for the conversion of CO+H.sub.2 to gaseous and liquid hydrocarbons at milder conditions than with prior catalysts.

Vollhardt, Kurt P. C. (Kensington, CA); Perkins, Patrick (Berkeley, CA)

1981-01-01T23:59:59.000Z

250

Novel Fischer-Tropsch catalysts  

DOE Patents (OSTI)

Novel polymer-supported metal complexes of the formula: PS --R Me(CO).sub.n H.sub.m where: PS represents a divinylbenzene crosslinked polystyrene in which the divinylbenzene crosslinking is greater than 1% and less than about 18%; R represents a cycloalkadienyl radical of 4 through 6 carbon atoms; Me represents a Group VIII metal; CO represents a carbonyl radical; H represents hydrogen; n represents an integer varying from 0 through 3; m represents an integer varying from 0 through 2 inclusively with the further provision that 2n+m must total 18 when added to the electrons in R and Me, or n+m must total 0; are prepared by: brominating PS --H by treating same with bromine in the presence of a thallium salt in a partially or fully halogenated solvent to form PS --Br; treating said PS --Br so produced with a lithium alkyl of 1 through 12 carbon atoms in an aromatic solvent to produce PS --Li; substituting said PS-- Li so produced by reaction with a 2-cycloalkenone of 4 to 6 carbon atoms in the presence of an ether solvent and using a water work-up to form a cycloalkenylalcohol-substituted PS ; dehydrating said alcohol so produced by heating under a vacuum to produce a cycloalkadienyl-substituted PS ; reacting the cycloalkadienyl-substituted PS with metal carbonyl in the presence of a partially or fully halogenated hydrocarbon, aromatic hydrocarbon of 6 through 8 carbon atoms, ethers, or esters of 4 through 10 carbon atoms as a solvent to produce a polystyrene-supported cycloalkadienyl metal carbonyl. The novel compounds are used as improved Fischer-Tropsch catalysts particularly for the conversion of CO+H.sub.2 to gaseous and liquid hydrocarbons at milder conditions than with prior catalysts.

Vollhardt, Kurt P. C. (Kensington, CA); Perkins, Patrick (Berkeley, CA)

1980-01-01T23:59:59.000Z

251

Novel Fischer-Tropsch catalysts  

DOE Patents (OSTI)

Novel polymer-supported metal complexes of the formula PS -R Me(CO).sub.n H.sub.m where: PS represents a divinylbenzene crosslinked polystyrene in which the divinylbenzene crosslinking is greater than 1% and less than about 18%; R represents a cycloalkadienyl radical of 4 through 6 carbon atoms; Me represents a Group VIII metal; CO represents a carbonyl radical; H represents hydrogen; n represents an integer varying from 0 through 3; m represents an integer varying from 0 through 2 inclusively with the further provision that 2n+m must total 18 when added to the electrons in R and Me, or n+m must total 0; are prepared by: brominating PS -H by treating same with bromine in the presence of a thallium salt in a partially or fully halogenated solvent to form PS -Br; treating said PS -Br so produced with a lithium alkyl of 1 through 12 carbon atoms in an aromatic solvent to produce PS -Li; substituting said PS - Li so produced by reaction with a 2-cycloalkenone of 4 to 6 carbon atoms in the presence of an ether solvent and using a water work-up to form a cycloalkenylalcohol-substituted PS ; dehydrating said alcohol so produced by heating under a vacuum to produce a cycloalkadienyl-substituted PS ; reacting the cycloalkadienyl-substituted PS with metal carbonyl in the presence of a partially or fully halogenated hydrocarbon, aromatic hydrocarbon of 6 through 8 carbon atoms, ethers, or esters of 4 through 10 carbon atoms as a solvent to produce a polystyrene-supported cycloalkadienyl metal carbonyl. The novel compounds are used as improved Fischer-Tropsch catalysts particularly for the conversion of CO+H.sub.2 to gaseous and liquid hydrocarbons at milder conditions than with prior catalysts.

Vollhardt, Kurt P. C. (Kensington, CA); Perkins, Patrick (Berkeley, CA)

1981-01-01T23:59:59.000Z

252

Electrogenerated Chemiluminescence and Fluorescence Lifetime Spatial Heterogeneity of Poly (2-methoxy-5-(2-ethylhexyloxy)-1, 4-phenylenevinylene) in Presence of [6,6]-phenyl-C61-butyric Acid Methyl Ester  

SciTech Connect

In this paper, we studied the luminescence property and fluorescence lifetime mapping of MEH-PPV/PCBM system by using electrogenerated chemiluminescence (ECL) and time-correlated single photo counting (TC-SPC) technologies. The ECL results showed that the oxidation peak of MEH-PPV near 0.7 V (vs. SCE) and ECL response of films shifted positively towards 1.2 V when in the presence of PCBM. At the same time, the oxidation peak current density of MEH-PPV increases while the ECL response decreased with the loading of PCBM in the composite films. The fluorescence lifetime images clearly show that the lifetime fluctuation is effected by different substrates and MEH-PPV/PCBM ratios. Meanwhile, the lifetime of MEH-PPV decreases with the increasing of film thickness. The lifetimes of MEH-PPV films on TiO2 substrate are lower than them of films on cover slips.

Geng, Hongwei; Pan, Shanlin; Hu, Dehong

2013-04-01T23:59:59.000Z

253

Synthesis of N-formyl-3,4-di-t-butoxycarbonyloxy-6(trimethylstannyl)-L-phenylalanine ethyl ester and its regioselective radiofluorodestannylation to 6-[{sup 18}F]fluoro-1-dopa  

DOE Patents (OSTI)

A process is revealed for forming a 6-fluoro derivative of compounds in the L-Dopa family comprising the steps of protecting the groups attached to the benzene ring in the compound followed by serially reacting the protected compound with (a) iodine and silver trifluoroacetic acid; (b) Bb{sub 3}; (c) dit-butyldicarbonate; (d) hexamethyltin; (e) a fluoro compound; (f) hydrobromic acid; and (g) raising the pH to {<=}7. 1 fig.

Satyamurthy, N.; Barrio, J.R.; Bishop, A.J.; Namavari, M.; Bida, G.T.

1996-04-23T23:59:59.000Z

254

Synthesis of N-formyl-3,4-di-t-butoxycarbonyloxy-6-(trimethylstannyl)-L-phenylalanine ethyl ester and its regioselective radiofluorodestannylation to 6- .sup.18 F!fluoro-1-dopa  

DOE Patents (OSTI)

A process for forming a 6-fluoro derivative of compounds in the L-Dopa family comprising the steps of protecting the groups attached to the benzene ring in the compound followed by serially reacting the protected compound with (a) iodine and silver trifluoroacetic acid; (b) Bb.sub.3 ; (c) dit-butyldicarbonate; (d) hexamethyltin; (e) a fluoro compound; (f) hydrobromic acid; and (g) raising the pH to .ltoreq.7.

Satyamurthy, Nagichettiar (Los Angeles, CA); Barrio, Jorge R. (Agoura Hills, CA); Bishop, Allyson J. (Wahnemuhle, DE); Namavari, Mohammad (Los Angeles, CA); Bida, Gerald T. (Shreveport, LA)

1996-01-01T23:59:59.000Z

255

Nevada Regional Science Bowl | U.S. DOE Office of Science (SC...  

Office of Science (SC) Website

NV 89121 Regional Date: February 1, 2013 Fee: NA Regional Geographic Area: Nevada, Utah, and the following counties in California: Sierra, Nevada, Placer, Inyo, Mono, Alpine...

256

Nevada Regional High School Science Bowl | U.S. DOE Office of...  

Office of Science (SC) Website

NA Regional Geographic Information: Nevada, Utah, and the following counties in California: Alpine, Inyo, Mono, Nevada, Plumas, Sierra Team Approval Process Teams are approved...

257

SSRLUOEC Minutes 2/03  

NLE Websites -- All DOE Office Websites (Extended Search)

being investigated for critical equipment. LN monos are particularly sensitive to long power outages. Some DOE funding is being provided for the first phase of an LN distribution...

258

ARE Update Volume 12, Number 5  

E-Print Network (OSTI)

of Mono Lake or how much Exxon should be forced to pay todamages from the Exxon Valdez disaster. Second, Michael has

2009-01-01T23:59:59.000Z

259

Nevada Regional Middle School Science Bowl | U.S. DOE Office...  

Office of Science (SC) Website

in California: Sierra, Nevada, Placer, Inyo, Mono, Alpine, Plumas Date of Electric Car Competition: 382014 Please contact the regional coordinator for more information on...

260

Native Meadow Restoration Project  

NLE Websites -- All DOE Office Websites (Extended Search)

mono-culture switchgrass Additional areas added for switchgrass with acceptance into Biofuel Initiative Program Roundup application to remove existing non-native grasses and...

Note: This page contains sample records for the topic "mono alkyl ester" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Raman spectroscopy and x-ray diffraction of phase transitions in Cr2O3 to 61 GPa Sang-Heon Shim*  

E-Print Network (OSTI)

Radiation Laboratory SSRL using mono- chromatic x-ray beams ( 0.4959 Ă? at CHESS and 0.7277 Ă? at SSRL

Duffy, Thomas S.

262

Effects of Cooling Rate on Microstructure in En-Ac43000 Gravity ...  

Science Conference Proceedings (OSTI)

Chillers of different dimensions and materials, including water cooled ones, were placed at one side of the casting in order to obtain mono-dimensional heat flux ...

263

Publications Portal  

Science Conference Proceedings (OSTI)

... and using 3-D shape information for aggregates (sand, gravel) have ... with mono-size conductive (steel) or insulating (glass) spherical inclusions ...

2012-09-17T23:59:59.000Z

264

Comparative studies of etching mechanisms of CR-39 in NaOH/H2O and NaOH/ethanol  

E-Print Network (OSTI)

of scission of the carbonate ester bond in CR-39 by the hydroxide ion through basic hydro- lysis of ester-39 detectors during etching in NaOH/ethanol has also shown that sodium car- bonate is present

Yu, K.N.

265

TETRAHEDRON Tetrahedron Letters 40 (1999) 2287-2290  

E-Print Network (OSTI)

1, phosphonate ester 5 was prepared starting from the readily accessible oxazole car- boxaldehyde 6 % overall yield from 9.1° Hydro- lysis of the C9 pivaloate ester and subsequent oxidation11 gave aldehyde 11

Williams, David R.

266

3-MCPD in Other Applications  

Science Conference Proceedings (OSTI)

3-MCPD(3-Monochloropropane-1,2-diol) reference papers. 3-MCPD in Other Applications 3-MCPD 2-diol 3-MCPD 3-MCPD Esters 3-monochloropropane-1 acid analysis aocs april articles certified chemists chloropropanediol contaminants detergents esters fats fatty

267

Resources for Process Contaminants  

Science Conference Proceedings (OSTI)

Detailed information regarding 3-MCPD esters and a reference list by topic. Resources for Process Contaminants 3-MCPD 2-diol 3-MCPD 3-MCPD Esters 3-monochloropropane-1 acid analysis aocs april articles certified chemists chloropropanediol contaminants de

268

AOCS Official Method Dc 4-59  

Science Conference Proceedings (OSTI)

Ester Sulfites AOCS Official Method Dc 4-59 Methods Methods and Analyses Analytical Chemistry Methods Downloads Methods Downloads DEFINITION The determination of ester SO 3 is dependent upon the hydro

269

Characterization of Biodiesel Oxidation and Oxidation Products  

DOE Green Energy (OSTI)

Features a literature review of 130 technical references pertaining to fatty oil and fatty ester stability chemistry in biodiesel fuels.

Not Available

2005-08-01T23:59:59.000Z

270

Sorbent Assisted Catalyst for the One-Pot Sequestration and Conversion of Renewable Feedstocks into Fuels  

algae oils, by not utilizing current methods of fatty acid conversion to methyl ester, makes this technology economically attractive.

271

unknown title  

E-Print Network (OSTI)

Combustion chemical kinetics of biodiesel and related compounds (methyl and ethyl esters): Experiments and modeling – Advances and future refinements

Lucie Coniglio; Hayet Bennadji; Pierre Alex; Re Glaude; Olivier Herbinet; Francis Billaud

2013-01-01T23:59:59.000Z

272

unknown title  

E-Print Network (OSTI)

A human skin multifunctional O-acyltransferase that catalyzes the synthesis of acylglycerols, waxes, and retinyl esters

Chi-liang Eric Yen; Charles H. Brown Iv; Mara Monetti; Robert V. Farese

2005-01-01T23:59:59.000Z

273

Glossary - U.S. Energy Information Administration (EIA)  

U.S. Energy Information Administration (EIA) Indexed Site

petroleum petroleum Alcohol: The family name of a group of organic chemical compounds composed of carbon, hydrogen, and oxygen. The series of molecules vary in chain length and are composed of a hydrocarbon plus a hydroxyl group; CH(3)-(CH(2))n-OH (e.g., methanol, ethanol, and tertiary butyl alcohol). Alkylate: The product of an alkylation reaction. It usually refers to the high-octane product from alkylation units. This alkylate is used in blending high octane gasoline. Alkylation: A refining process for chemically combining isobutane with olefin hydrocarbons (e.g., propylene, butylene) through the control of temperature and pressure in the presence of anacid catalyst, usually sulfuric acid or hydrofluoric acid. The product alkylate, an isoparaffin, has high octane value and is blended with motor and aviation gasoline to

274

@Title = Definitions of Petroleum Products and Other Terms  

U.S. Energy Information Administration (EIA) Indexed Site

Definitions of Petroleum Products and Other Terms (Revised January 2010) Alcohol. The family name of a group of organic chemical compounds composed of carbon, hydrogen, and oxygen. The series of molecules vary in chain length and are composed of a hydrocarbon plus a hydroxyl group; CH 3 - (CH 2 )n-OH (e.g., methanol, ethanol, and tertiary butyl alcohol). Alkylate. The product of an alkylation reaction. It usually refers to the high octane product from alkylation units. This alkylate is used in blending high octane gasoline. Alkylation. A refining process for chemically combining isobutane with olefin hydrocarbons (e.g., propylene, butylene) through the control of temperature and pressure in the presence of an acid catalyst, usually sulfuric acid or hydrofluoric acid. The product, alkylate, an

275

PSADEFS.CHP:Corel VENTURA  

Gasoline and Diesel Fuel Update (EIA)

Definitions Definitions of Petroleum Products and Other Terms Alcohol. The family name of a group of organic chemical compounds composed of carbon, hydrogen, and oxygen. The series of molecules vary in chain length and are composed of a hydrocarbon plus a hydroxyl group; CH 3 - (CH 2 )n-OH (e.g., methanol, ethanol, and tertiary butyl alcohol). Alkylate. The product of an alkylation reaction. It usu- ally refers to the high octane product from alkylation units. This alkylate is used in blending high octane gaso- line. Alkylation. A refining process for chemically combining isobutane with olefin hydrocarbons (e.g., propylene, buty- lene) through the control of temperature and pressure in the presence of an acid catalyst, usually sulfuric acid or hydrofluoric acid. The product, alkylate, an isoparaffin, has high octane value and is blended with motor and aviation gasoline to improve the antiknock

276

AOCS Official Method Cd 29a-13  

Science Conference Proceedings (OSTI)

2- and 3-MCPD Fatty Acid Esters and Glycidol Fatty Acid Esters in Edible Oils and Fats by Acid Transesterification AOCS Official Method Cd 29a-13 3-MCPD 2-diol 3-MCPD 3-MCPD Esters 3-monochloropropane-1 acid analysis aocs april articles certified chemist

277

East Brawley East MesaHeber  

E-Print Network (OSTI)

East Brawley Glamis Dunes East MesaHeber Salton Sea South Brawley Randsburg Sespe Hot Springs Coso Randsburg Sespe Hot Springs Coso Hot Springs Mono - Long Valley Bodie Saline Valley Calistoga The Geysers Hot Springs Mono - Long Valley Bodie Saline Valley Calistoga The Geysers Lassen Wendel - Amedee Glass

278

FIRST BERKELEY CATALYSIS AND SURFACE SCIENCE CONFERENCE JULY 1980  

E-Print Network (OSTI)

Arco Chemical Company Ashland Oil, Inc. Celanese CorporationCarbide Corporation Union Oil Co. of California iii FIRSTboth distillates and lube oils; alkylation of benzene with

Authors, Various

2013-01-01T23:59:59.000Z

279

NN3, Conductance Statistics of Molecular Junctions Fabricated with ...  

Science Conference Proceedings (OSTI)

The I-V curves are dominated by a tunneling behavior as usually observed in the MMM junctions of alkyl chains. The TVS (transient voltage spectroscopy) ...

280

Modern Records of Radiatively Important Halogenated Compounds...  

NLE Websites -- All DOE Office Websites (Extended Search)

at CDIAC sites: Methane, Nonmethane Hydrocarbons, Alkyl Nitrates, and Chlorinated Carbon Compounds including three Chlorofluorocarbons (CFC-11, CFC-12, and CFC-113) in...

Note: This page contains sample records for the topic "mono alkyl ester" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Exceptionally Low-Temperature Carbon Hydrogen/ 2 Carbon ...  

transformation in solution.1 Most of the classical methods for ... sors are nearly always metal alkyls or aryls: ... Supporting Information Available: ...

282

ThermoML Data for JCT  

Science Conference Proceedings (OSTI)

... Title: Application of 1-alkyl-3-methylpyridinium bis(trifluoromethylsulfonyl)imide ionic liquids for the ethanol removal from its mixtures with alkanes. ...

283

xml version="1.0" encoding="UTF-8"?>

Note: This page contains sample records for the topic "mono alkyl ester" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a
real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Surface Water Temperatures At Shore Stations, United States West Coast 1984  

E-Print Network (OSTI)

off the rocks near the water intake for the laboratory. MonoStation Off rocks near water intake for laboratory Trinidadthat monitors the cool- ing intake water for the generators.

Scripps Institution of Oceanography

1985-01-01T23:59:59.000Z

302

Surface Water Temperatures At Shore Stations, United States West Coast 1986  

E-Print Network (OSTI)

off the rocks near the water intake for the laboratory. MonoStation Off rocks near water intake for laboratory Farallónthat monitors the cool­ ing intake water for the generators.

Scripps Institution of Oceanography

1987-01-01T23:59:59.000Z

303

Surface Water Temperatures At Shore Stations, United States West Coast 1983  

E-Print Network (OSTI)

off the rocks near the water intake for the laboratory. MonoStation Off rocks near water intake for laboratory Granitethat monitors the cool­ ing intake water for the generators.

Scripps Institution of Oceanography

1984-01-01T23:59:59.000Z

304

AOCS Official Method Cd 11b-91  

Science Conference Proceedings (OSTI)

Determination of Mono- and Diglycerides by Capillary Gas Chromatography AOCS Official Method Cd 11b-91 Methods Methods and Analyses Analytical Chemistry Methods Downloads Methods Downloads DEFINITION This metho

305

Package of Homojunction of Fully Conjugated Heterocyclic Aromatic Rigid-rod Polymer Light Emitting Diodes.  

E-Print Network (OSTI)

??The focus of this study is mono-layer polymer light emitting diode (PLED). The emitting layer is poly-p-phenylenebenzobisoxazole (PBO). PBO is a fully conjugated heterocyclic aromatic… (more)

Liao, Hung-chi

2004-01-01T23:59:59.000Z

306

--No Title--  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

kW Proven Energy wind turbines on 49 foot mono-poles * Grid connection SMA Windy Boy inverter * Performance monitoring software Based on one year of electricity use and assuming...

307

Page not found | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

results. Download CX-002867: Categorical Exclusion Determination California-Tribe-Big Sandy Rancheria Band of Western Mono Indians CX(s) Applied: B2.5, B5.1 Date: 07012010...

308

The Effects of Bleached Kraft Pulp-Mill Effluent on Periphyton DOE FRAP 1996-08  

E-Print Network (OSTI)

phenolics are a family of compounds comprised of three main classes, phenols, guaiacols and catechols - Catechols 0.51 + 0.10a 1.11 + 0.03a 2.45 + 0.21b Total Mono - Chlorinated Phenolics 0.68 + 0.12a 3.22 + 0 was also apparent when mono-, di-, tri-- and tetra- chlorinated phenolics and total catechols were

309

n. Numero POD N. Presa Indirizzo del punto di prelievo C.A.P. Comune Prov. Distributore Disponibile  

E-Print Network (OSTI)

usi MT L 01/03/11 20 NO 7 IT001E00097953 10349128060481 Balbi (via), 5 16126 Genova GE ENEL 247 Multi001E00097951 10349128020022 Balbi (via), 22 16126 Genova GE ENEL 120 Mono Altri usi BT L 01/03/11 20 NO 24 IT001E11957555 1034912820238 Balbi (via), 30 int. 23 16126 Genova GE ENEL 5 Mono Altri usi BT L 01

Genova, UniversitĂ  degli Studi di

310

Process for separation of the rare earths by solvent extraction  

DOE Patents (OSTI)

Production rates for solvent extraction separation of the rare earths and yttrium from each other can be improved by the substitution of di(2-ethylhexyl) mono-thiophosphoric acid for di(2-ethylhexyl) phosphoric acid. The di(2-ethylhexyl) mono-thiophosphoric acid does not form an insoluble polymer at approximately 50% saturation as does the former extractant, permitting higher feed solution concentration and thus greater throughput.

Mason, George W. (Clarendon Hills, IL); Lewey, Sonia (Joliet, IL)

1977-04-05T23:59:59.000Z

311

AN ASSESSMENT OF THE NATIONAL INSTITUTE OF ...  

Science Conference Proceedings (OSTI)

... of SRMs for use in the biofuel industry should receive ... A new effort on biofuels centered around alcohol mixtures and biodiesel (esters from ...

2011-07-03T23:59:59.000Z

312

Genomic Prospecting for Microbial Biodiesel Production  

E-Print Network (OSTI)

and Kato, N. (2002) Wax ester production from n-alkanes bycoli engineered for fuel production. Microbiology 152: 2529-Increased fatty acid production in potato by engineering of

Lykidis, Athanasios

2008-01-01T23:59:59.000Z

313

Strategies and Technologies for Improving Air Quality Around Ports  

E-Print Network (OSTI)

methyl ester soybean oil/diesel fuel blends. Bioresour.T. , Hydrotreated vegetable oil as fuel for heavy dutywith residual fuel oils. Journal of Aerosol Science, 2002.

Khan, Mohammad Yusuf

2013-01-01T23:59:59.000Z

314

Table 10.4 Biodiesel Overview, 2001-2011 - U.S. Energy Information ...  

U.S. Energy Information Administration (EIA)

Electricity. Sales, revenue and prices, power plants, fuel use, stocks, ... imports data for Harmonized Tariff Schedule codes 3824.90.40.20, "Fatty Esters

315

PRODUCTION OF HIGHER QUALITY BIO-OILS BY IN-LINE ESTERIFICATION OF ...  

The pyrolysis oil product can have an increased ester content and an increased stability when compared to a condensed pyrolysis oil product not ... Biomass and Biofuels;

316

Microbial Reduction of Furfurals to Furan Alcohols by a ...  

Wind Energy; Partners (27) Visual Patent Search; Success ... or esterified with acids to form esters that can be components of bio-diesel or ...

317

Transportation and its Infrastructure  

E-Print Network (OSTI)

methyl esters (DME) and Fischer-Tropsch liquids, as well astransport fuels using Fischer-Tropsch or other conversionconcluded that biodiesel, Fischer-Tropsch synthetic kerosene

2007-01-01T23:59:59.000Z

318

Monomers from Renewable Resources: C-H Functionalization of Saturated Fatty Acids.  

E-Print Network (OSTI)

??Saturated fatty acids were used to prepare renewable monomers and polymers. For instance, the alpha-acidity of these fatty acid esters was used to synthesize malonate… (more)

Kolb, Nicolai

2013-01-01T23:59:59.000Z

319

MINISTRIO DA EDUCAO UNIVERSIDADE FEDERAL DO PARAN  

E-Print Network (OSTI)

lise, Polímero: Ester de Celulose, Diâmetro de poro: 0,80µm, Diâmetro: 47mm, Pacote com 100 unidades

Paraná, Universidade Federal do

320

ThermoML Data for JCT  

Science Conference Proceedings (OSTI)

... equilibria for the ternary (water + acetic acid + toluene) system ... aqueous solutions of butyric acid with n ... halobenzoic esters and of their parent acids. ...

Note: This page contains sample records for the topic "mono alkyl ester" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Properties and Applications  

Science Conference Proceedings (OSTI)

Table 5   Developmental high-temperature polyimide resins...ester; BAPP, 2,2-bis (4-aminophenoxyphenyl) propane;

322

Synthesis of D-Glucose-1-C14 and D-Mannose-1-C14  

Science Conference Proceedings (OSTI)

... The product weighed 470 mg, rep- resenting a ... ing formation of esters, condensation products, and the ... The alco- holic liquors were neutralized with ...

2006-03-29T23:59:59.000Z

323

A preliminary report on zinc-induced resistance to nitrogen mustard toxicity in mice  

SciTech Connect

Previous studies with cultured human normal fibroblasts indicated that treatment of cells with zinc before exposure to alkylating agents enhanced cell survival by seven- to nine-fold. To establish whether a similar zinc-induced protective response could be elicited in vivo, a set of preliminary experiments was carried out in which Balb/cJ mice were treated with zinc chloride (2 mg/kg body weight) or saline by intraperitoneal (ip) injection at 48, 36, 24, and 12 h before ip administration of 4 mg/kg of the alkylating agent nitrogen mustard. Of the animals that received saline before nitrogen mustard, 57% were killed compared with only 20% in the group treated with zinc before administration of the alkylating agent. These results (which almost certainly were achieved with less than optimal induction conditions) provide evidence for the existence, in vivo, of a zinc-inducible process that reduces alkylating agent lethality. 12 refs., 4 figs.

Shackelford, M.E.; Tobey, R.A.

1988-12-01T23:59:59.000Z

324

Directory of Operable Petroleum Refineries on Tables 38 and 39  

U.S. Energy Information Administration (EIA)

ExxonMobil Refg & Supply Co. Billings..... 4,300 0 12,700 0 0 0 2,100 24 0 Alkylates Aromatics Asphalt and RoadOil Isomers Lubricants Marketable Petroleum Coke ...

325

Polymers for electronics and chemical sensing applications  

E-Print Network (OSTI)

The incorporation of molecular structures such as shape persistent molecular frameworks, strong hydrogen bond donor groups or perfluoro-alkyl groups can result in considerable gains in the performance of some established ...

Amara, John Paul

2006-01-01T23:59:59.000Z

326

Table Definitions, Sources, and Explanatory Notes  

Gasoline and Diesel Fuel Update (EIA)

Production Capacity of Operable Petroleum Refineries Production Capacity of Operable Petroleum Refineries Definitions Key Terms Definition Alkylate The product of an alkylation reaction. It usually refers to the high octane product from alkylation units. This alkylate is used in blending high octane gasoline. Aromatics Hydrocarbons characterized by unsaturated ring structures of carbon atoms. Commercial petroleum aromatics are benzene, toluene, and xylene (BTX). Asphalt A dark-brown-to-black cement-like material containing bitumens as the predominant constituent obtained by petroleum processing; used primarily for road construction. It includes crude asphalt as well as the following finished products: cements, fluxes, the asphalt content of emulsions (exclusive of water), and petroleum distillates blended with asphalt to make cutback asphalts. Note: The conversion factor for asphalt is 5.5 barrels per short ton.

327

Exchange of Type II DockerinContaining Subunits of the C. thermocellum...  

NLE Websites -- All DOE Office Websites (Extended Search)

proteins invivo. SNAP- tag is a mutant of the O 6 -alkylguanine-DNA alkyl transferase human DNA repair protein which has increased activity against its substrate O 6...

328

I. Total Synthesis of Smenochromene B and Halenaquinone and II. Studies on the Chemical and Biological Properties of Azobenzene Photoswitches  

E-Print Network (OSTI)

residue as well as the catechol alkylation pattern. Figurebut to ring contracted methoxy catechol 1.32. Formally, onlydeprotection of methoxy catechol 1.32 all failed. It quickly

Kienzler, Michael A

2010-01-01T23:59:59.000Z

329

AOCS Official Method Tg 3a-64  

Science Conference Proceedings (OSTI)

Iodine Value of Fatty Quaternary Ammonium Chlorides, Modified Wijs Method AOCS Official Method Tg 3a-64 Methods Downloads Methods Downloads DEFINITION The iodine value is a measure of the unsaturation of the alkyl

330

AOCS Official Method Tg 2a-64  

Science Conference Proceedings (OSTI)

Iodine Value of Fatty Amines, Modified Wijs Method AOCS Official Method Tg 2a-64 Methods Downloads Methods Downloads DEFINITION The iodine value is a measure of the unsaturation of the alkyl group or groups and is

331

A new class of photoresponsive surfactants  

E-Print Network (OSTI)

In this thesis, a new class of nonionic, photoresponsive surfactants consisting of a polar di(ethylene oxide) head group attached to an alkyl spacer of between two and eight methylene groups, coupled through an ether linkage ...

Shang, Tiangang, 1969-

2005-01-01T23:59:59.000Z

332

AOCS Official Method Dc 6-59  

Science Conference Proceedings (OSTI)

Alkalinity AOCS Official Method Dc 6-59 Methods Methods and Analyses Analytical Chemistry Methods Downloads Methods Downloads DEFINITION This method determines the alkalinity or acidity of fatty alkyl sulfates.

333

AOCS Official Method Dc 7-59  

Science Conference Proceedings (OSTI)

Sodium Sulfate AOCS Official Method Dc 7-59 Methods Methods and Analyses Analytical Chemistry Methods Downloads Methods Downloads DEFINITION This method determines the sodium sulfate in fatty alkyl sulfates by

334

AOCS Official Method Dc 8-59  

Science Conference Proceedings (OSTI)

Unsulfated Material AOCS Official Method Dc 8-59 Methods Methods and Analyses Analytical Chemistry Methods Downloads Methods Downloads DEFINITION This method determines unsulfated fatty alcohols in fatty alkyl

335

Hydrophobic Polycationic Coatings Disinfect Poliovirus and Rotavirus Solutions  

E-Print Network (OSTI)

Coating surfaces with N-alkylated polyethylenimines (PEIs), namely branched N,N-hexyl,methyl-PEI via covalent attachment to glass or linear N,N-dodecyl,methyl-PEI by physical deposition (“painting”) onto polyethylene, ...

Larson, Alyssa Maxine

336

MATERIALS AND MOLECULAR RESEARCH DIVISION. ANNUAL REPORT 1981  

E-Print Network (OSTI)

Isotope Effects on Fischer-Tropsch Synthesis over SupportedSe'iactivity of Iron Fischer-Tropsch Catalysts," LBL-13578.On the Purported Fischer-Tropsch Alkylation of Benzene: The

Authors, Various

2010-01-01T23:59:59.000Z

337

Quaternary ammonium polyethyleneimine: antibacterial activity  

Science Conference Proceedings (OSTI)

Quaternary ammonium polyethyleneimine- (QA-PEI-) based nanoparticles were synthesized using two synthetic methods, reductive amination and N-alkylation. According to the first method, QA-PEI nanoparticles were synthesized by cross-linking with glutaraldehyde ...

Ira Yudovin-Farber; Jacob Golenser; Nurit Beyth; Ervin I. Weiss; Abraham J. Domb

2010-01-01T23:59:59.000Z

338

Progress in nucleophilic catalysis and development of nickel-catalyzed cross-couplings of propargylic halides  

E-Print Network (OSTI)

Chapter 1 describes the development of two organocatalytic processes. The first is a 13-alkylation reaction of Michael acceptors, and represents a novel umpolung process catalyzed by N-heterocyclic carbenes. The second ...

Smith, Sean W. (Sean Wesley)

2009-01-01T23:59:59.000Z

339

The versatile E. coli adaptive response protein AlkB mitigates toxicity and mutagenicity of etheno-, ethano-, and methyl-modified bases in vivo  

E-Print Network (OSTI)

The Escherichia coli AlkB protein is an exceptionally versatile DNA repair enzyme. Its expression is induced upon exposure to alkylating agents as part of the Ada-mediated adaptive response. This member of the ac-ketoglu ...

Frick, Lauren Elizabeth

2007-01-01T23:59:59.000Z

340

Self-Assembly and Mass Transport in Membranes for Artificial Photosynthesis  

E-Print Network (OSTI)

orientation of colloidal CdSe nanorods in composite thinwere obtained from Polymer Source. CdSe nanorod preparationAlkyl passivated CdSe nanorods were synthesized following

Modestino, Miguel Antonio

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mono alkyl ester" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

SEPARATION OF CURIUM AND AMERICIUM  

DOE Patents (OSTI)

Curium and americium are contained in an anhydrous molten salt medium having a low melting point. Curium is preferentially extracted from the molten salt by a hot organic solvent containing preferably less than 10% alkyl phosphate. (AEC)

Fields, P.R.; Isaac, N.M.

1962-02-20T23:59:59.000Z

342

Publications  

NLE Websites -- All DOE Office Websites (Extended Search)

Sun, Xiao-Guang Clear All Filters 2005 Sun, Xiao-Guang, Jun Hou, and John B. Kerr. "Comb-shaped single ion conductors based on polyacrylate ethers and lithium alkyl sulfonate."...

343

Lubricants or lubricant additives composed of ionic liquids containing ammonium cations  

Science Conference Proceedings (OSTI)

A lubricant or lubricant additive is an ionic liquid alkylammonium salt. The alkylammonium salt has the structure R.sub.xNH.sub.(4-x).sup.+,[F.sub.3C(CF.sub.2).sub.yS(O).sub.2].sub.2N.sup- .- where x is 1 to 3, R is independently C.sub.1 to C.sub.12 straight chain alkyl, branched chain alkyl, cycloalkyl, alkyl substituted cycloalkyl, cycloalkyl substituted alkyl, or, optionally, when x is greater than 1, two R groups comprise a cyclic structure including the nitrogen atom and 4 to 12 carbon atoms, and y is independently 0 to 11. The lubricant is effective for the lubrication of many surfaces including aluminum and ceramics surfaces.

Qu, Jun (Knoxville, TN); Truhan, Jr.,; John J. (Cookeville, TN); Dai, Sheng (Knoxville, TN); Luo, Huimin (Knoxville, TN); Blau, Peter J. (Knoxville, TN)

2010-07-13T23:59:59.000Z

344

Ultraviolet absorbing copolymers  

DOE Patents (OSTI)

Photostable and weather stable absorping copolymers have been prepared from acrylic esters such as methyl methacrylate containing 0.1 to 5% of an 2-hydroxy-allyl benzophenone, preferably the 4,4' dimethoxy derivative thereof. The pendant benzophenone chromophores protect the acrylic backbone and when photoexcited do not degrade the ester side chain, nor abstract hydrogen from the backbone.

Gupta, Amitava (Pasadena, CA); Yavrouian, Andre H. (La Crescenta, CA)

1982-01-01T23:59:59.000Z

345

Free 3-MCPD in Foods  

Science Conference Proceedings (OSTI)

Reference list for Free 3-MCPD(3-Monochloropropane-1,2-diol )in Foods. Free 3-MCPD in Foods 3-MCPD 2-diol 3-MCPD 3-MCPD Esters 3-monochloropropane-1 acid analysis aocs april articles certified chemists chloropropanediol contaminants detergents esters fat

346

Low toxicity method of inhibiting sickling of sickle erythrocytes  

DOE Patents (OSTI)

A low toxicity method of inhibiting sickling of sickle erythrocytes which comprises intermixing the erythrocytes with an effective anti-sickling amount of a water-soluble imidoester of the formula RC(=NH)OR' wherein R is an alkyl group of 1 - 8 carbon atoms, particularly 1 - 4 carbon atoms, and R' is an alkyl group of 1 - 4 carbon atoms, specifically methyl or ethyl acetimidate.

Packer, Lester (Orinda, CA); Bymun, Edwin N. (Oakland, CA)

1977-01-01T23:59:59.000Z

347

Combination of chemical reduction and tandem mass spectrometry for the characterization of sulfur-containing fuel constituents  

SciTech Connect

Tandem mass spectrometry has been combined with a calcium/mixed amines reduction system to characterize an SRC-II middle distillate fraction for sulfur-containing polynuclear aromatic hydrocarbons. Parent scans, which characterize a complex mixture for all components which fragment to common structural moieties, were used to identify alkyl-benzothiophenes and dibenzothiophenes as well as alkyl-benzothiophene sulfones. 15 references, 5 figures, 1 table.

Wood, K.V.; Cooks, R.G.; Laugal, J.A.; Benkeser, R.A.

1985-03-01T23:59:59.000Z

348

PROCESS FOR THE RECOVERY OF URANIUM FROM PHOSPHATIC ORE  

DOE Patents (OSTI)

A proccss is described for the recovery of uranium from phosphatic products derived from phosphatic ores. It has been discovered that certain alkyl phosphatic, derivatives can be employed in a direct solvent extraction operation to recover uranium from solid products, such as superphosphates, without first dissolving such solids. The organic extractants found suitable include alkyl derivatives of phosphoric, pyrophosphoric, phosof the derivative contains from 4 to 7 carbon atoms. A diluent such as kerosene is also used.

Long, R.L.

1959-04-14T23:59:59.000Z

349

Method for producing hydrophobic aerogels  

SciTech Connect

A method for treating a dried monolithic aerogel containing non-dispersed particles, with an organometallic surface modifying agent to produce hydrophobic aerogels. The dried, porous hydrophobic aerogels contain a protective layer of alkyl groups, such as methyl groups, on the modified surfaces of the pores of the aerogel. The alkyl groups at the aerogel surface typically contain at least one carbon-metal bond per group.

Hrubesh, Lawrence W. (Pleasanton, CA); Poco, John F. (Livermore, CA); Coronado, Paul R. (Livermore, CA)

1999-01-01T23:59:59.000Z

350

Amine derivatives of thio-bis-lactone acids in combination with coadditive hydrocarbons are flow improvers for middle distillate fuel oils  

Science Conference Proceedings (OSTI)

Amine salts, amino acids, amino acid salts bis-amides and imides of oil-soluble thio-bis-(C12-50 alkyl lactone acid), e.g. a secondary hydrogenated tallow amide of dithio-bis-(C16-c24 alkyl lactone carboxylic acid), are useful in combination with a coadditive hydrocarbon such as an amorphous hydrocarbon or a hydrogenated polybutadiene in improving the cold flow properties of distillate hydrocarbon oils.

Brois, S.J.; Feldman, N.; Gutierrez, A.

1981-02-17T23:59:59.000Z

351

Polyethylene composites containing a phase change material having a C14 straight chain hydrocarbon  

DOE Patents (OSTI)

A composite useful in thermal energy storage, said composite being formed of a polyethylene matrix having a straight chain alkyl hydrocarbon incorporated therein, said polyethylene being crosslinked to such a degree that said polyethylene matrix is form stable and said polyethylene matrix is capable of absorbing at least 10% by weight of said straight chain alkyl hydrocarbon; the composite is useful in forming pellets or sheets having thermal energy storage characteristics.

Salyer, Ival O. (Dayton, OH)

1987-01-01T23:59:59.000Z

352

ARM - Publications: Science Team Meeting Documents  

NLE Websites -- All DOE Office Websites (Extended Search)

Physical Retrieval of PWV and CLW with MonoRTM Using ARM MWR Data Physical Retrieval of PWV and CLW with MonoRTM Using ARM MWR Data Clough, S.A.(a), Cady-Pereira, K.(a), Boukabara, S.(a), and Liljegren, J.C.(b), Atmospheric and Environmental Research, Inc. (a), Argonne National Laboratory (b) Twelfth Atmospheric Radiation Measurement (ARM) Science Team Meeting The newly developed radiative transfer model, MonoRTM, has been utilized as the forward model in a physical retrieval method to obtain Precipitable Water Vapor (PWV) and Cloud Liquid Water (CLW) using ARM MWR data. The dependence of the forward model on water vapor and oxygen has been carefully analyzed in the context of the ARM dataset covering a three-year period from 1996 to 1998. A detailed error analysis for the forward model brightness temperatures at 23.8 GHz and 31.4 GHz has been has been

353

An Experimental and Kinetic Modeling Study of Methyl Decanoate Combustion  

DOE Green Energy (OSTI)

Biodiesel is a mixture of long chain fatty acid methyl esters derived from fats and oils. This research study presents opposed-flow diffusion flame data for one large fatty acid methyl ester, methyl decanoate, and uses the experiments to validate an improved skeletal mechanism consisting of 648 species and 2998 reactions. The results indicate that methyl decanoate is consumed via abstraction of hydrogen atoms to produce fuel radicals, which lead to the production of alkenes. The ester moiety in methyl decanoate leads to the formation of low molecular weight oxygenated compounds such as carbon monoxide, formaldehyde, and ketene.

Sarathy, S M; Thomson, M J; Pitz, W J; Lu, T

2009-12-04T23:59:59.000Z

354

Electric current-producing device having sulfone-based electrolyte  

DOE Patents (OSTI)

Electrolytic solvents and applications of such solvents including electric current-producing devices. For example, a solvent can include a sulfone compound of R1--SO2--R2, with R1 being an alkyl group and R2 a partially oxygenated alkyl group, to exhibit high chemical and thermal stability and high oxidation resistance. For another example, a battery can include, between an anode and a cathode, an electrolyte which includes ionic electrolyte salts and a non-aqueous electrolyte solvent which includes a non-symmetrical, non-cyclic sulfone. The sulfone has a formula of R1--SO2--R2, wherein R1 is a linear or branched alkyl or partially or fully fluorinated linear or branched alkyl group having 1 to 7 carbon atoms, and R2 is a linear or branched or partially or fully fluorinated linear or branched oxygen containing alkyl group having 1 to 7 carbon atoms. The electrolyte can include an electrolyte co-solvent and an electrolyte additive for protective layer formation.

Angell, Charles Austen (Mesa, AZ); Sun, Xiao-Guang (Tempe, AZ)

2010-11-16T23:59:59.000Z

355

Comparing Surfaces and Engineered Interfaces using Self-Assembled Monolayers (SAMs) and Injected SAMs Silanes  

SciTech Connect

The objective of this study was to show a comparison between property changes by formation of a self-assembled monolayer on the surface of PPG synthetic precipitated silica, which is a technique developed at PNNL, and by adding the SAMs silane chemical directly into the mixing bowl. These coatings have the potential to greatly increase the bond strength and enhance other properties between the particle and the rubber matrix of a rubber compound. Tensile testing measured peak stress and elongation at break. The increase in tensile strength shows how well the polymer-filler interfacial adhesion is doing. The study used five different SAM systems with a sulfur cured styrene butadiene rubber (SBR) tire rubber formulation. The three propylsilanes were propyl triethoxysilane, allyl triethoxysilane and 3-mercaptopropyl triethoxysilane. Five combinations of silanes were used in this study. The application of the silanes were 100% propyl triethoxy silane (100% Alkyl); a 10/90 mixture of allyl and propyl triethoxy silanes (10% vinyl/90% alkyl); a 50/50 mixture of the allyl and propyl (50% vinyl/50% alkyl); a 10/90mixture of 3-mercaptopropyl trimethoxysilane and propyl trimethoxysilane (10% mercaptan/90% alkyl) and lastly a 50/50 3-mercaptopropyl and propylsilanes (50% mercaptan/alkyl). The data not only shows improvement with SAMs, the peak stress data (ultimate strength) shows that the by changing the amount of silane content can change the physical properties

Morris, Mark J.; Simmons, Kevin L.

2003-11-01T23:59:59.000Z

356

AOCS Official Method Ce 2-66  

Science Conference Proceedings (OSTI)

Preparation of Methyl Esters of Fatty Acids AOCS Official Method Ce 2-66 Methods Methods and Analyses Analytical Chemistry Methods Downloads Methods Downloads DEFINITION This method provides a means for prepari

357

AOCS Official Method Ch 1-91  

Science Conference Proceedings (OSTI)

Preparation of Methyl Esters of Long-Chain Fatty Acids AOCS Official Method Ch 1-91 Methods Methods and Analyses Analytical Chemistry Methods Downloads Methods Downloads DEFINITION This method provides a means

358

2011 Annual Meeting Abstacts  

Science Conference Proceedings (OSTI)

Abstracts from Health and Nutrition presented at the 102ndrd AOCS Annual Meeting. 2011 Annual Meeting Abstacts Health acid analysis aocs april articles chloropropanediol contaminants detergents dietary fats division divisions esters fats fatty food foods

359

2009 Annual Meeting Abstacts  

Science Conference Proceedings (OSTI)

Abstracts from Health and Nutrition presented at the 100th AOCS Annual Meeting. 2009 Annual Meeting Abstacts Health acid analysis aocs april articles chloropropanediol contaminants detergents dietary fats division divisions esters fats fatty food foods g

360

Resources Process Contaminants  

Science Conference Proceedings (OSTI)

General Information on process contaminants(3-MCPD). Reference list included. Resources Process Contaminants 3-MCPD 2-diol 3-MCPD 3-MCPD Esters 3-monochloropropane-1 acid analysis aocs april articles certified chemists chloropropanediol contaminants dete

Note: This page contains sample records for the topic "mono alkyl ester" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

3-MCPD Update 8/6/10  

Science Conference Proceedings (OSTI)

“Indirect” Method for the Determination of 3-MCPD Esters: Hydrolysis Time and Recovery Considerations for the Acid Hydrolysis Method J. D. Pinkston, D. P. Iannelli, T. R. Mertens The Procter & Gamble Company, Winton Hill Business Center, 63

362

AOCS Official Method Ty 1a-76  

Science Conference Proceedings (OSTI)

Dicarboxylic Acid Composition by Gas-Liquid Chromatography of Dimethyl Esters AOCS Official Method Ty 1a-76 Methods Downloads Methods Downloads DEFINITION This method relates standard conditions for the separation

363

Presentations and Papers on Process Contaminants (3-MCPD)  

Science Conference Proceedings (OSTI)

Presentations and papers 3-MCPD EFL, ILSI World Conference on Oilseed Processing, Fats & Oils Processing, Biofuels & Applications Presentations and Papers on Process Contaminants (3-MCPD) 3-MCPD 2-diol 3-MCPD 3-MCPD Esters 3-monochloropropane-1 acid anal

364

Lipid Oxidation Pathways, Volume 2  

Science Conference Proceedings (OSTI)

This book complements Lipid Oxidation Pathways, Volume 1. Lipid Oxidation Pathways, Volume 2 Health acid analysis aocs april articles chloropropanediol contaminants detergents dietary fats division divisions esters fats fatty food foods glycidol Health h

365

Choline, Phospholipids, Health, and Disease  

Science Conference Proceedings (OSTI)

The proceedings of the 7th International Congress on Phospholipids. Choline, Phospholipids, Health, and Disease Health acid analysis aocs april articles chloropropanediol contaminants detergents dietary fats division divisions esters fats fatty food food

366

2009 Annual Meeting Abstacts  

Science Conference Proceedings (OSTI)

Abstracts from Industrial Oil Products presented at the 100th AOCS Annual Meeting. 2009 Annual Meeting Abstacts Health acid analysis aocs april articles chloropropanediol contaminants detergents dietary fats division divisions esters fats fatty food food

367

2012 Annual Meeting Abstacts  

Science Conference Proceedings (OSTI)

Abstracts from Industrial Oil Products presented at the 103rd AOCS Annual Meeting. 2012 Annual Meeting Abstacts Health acid analysis aocs april articles chloropropanediol contaminants detergents dietary fats division divisions esters fats fatty food food

368

2010 Annual Meeting Abstacts  

Science Conference Proceedings (OSTI)

Abstracts from Health and Nutrition presented at the 101st AOCS Annual Meeting. 2010 Annual Meeting Abstacts Health acid analysis aocs april articles chloropropanediol contaminants detergents dietary fats division divisions esters fats fatty food foods g

369

Process Contaminants (3-MCPD)  

Science Conference Proceedings (OSTI)

General information on process contaminants(3-MCPD). Reference list included. Process Contaminants (3-MCPD) 3-MCPD 2-diol 3-MCPD 3-MCPD Esters 3-monochloropropane-1 acid analysis aocs april articles certified chemists chloropropanediol contaminants deter

370

On the origins of enzyme inhibitor selectivity and promiscuity: a case study of protein kinase binding to staurosporine  

E-Print Network (OSTI)

Ala alanine AMP adenosine 5?-monophosphate ANP phosphoaminophosphonic acid-adenylate ester APE alanine-proline-glutamate Arg arginine Asn asparagine Asp aspartate ATP adenosine 5?-triphosphate BUB1 budding uninhibited by benzimidazoles 1...

Tanramluk, Duangrudee

2010-02-09T23:59:59.000Z

371

Effect of Biodiesel Composition on Engine Emissions from a DDC Series 60 Diesel Engine: Final Report; Report 2 in a Series of 6  

DOE Green Energy (OSTI)

NREL conducted an investigation of various biodiesel fuels produced from waste oils in order to determine the effect of biodiesel source material and ester molecular structure, nitrogen oxides, and certain unregulated pollutants.

Graboski, M. S.; McCormick, R. L.; Alleman, T. L.; Herring, A. M.

2003-02-01T23:59:59.000Z

372

AOCS Official Method Ca 14b-96  

Science Conference Proceedings (OSTI)

Quantification of Free Glycerin in Selected Glycerides and Fatty Acid Methyl Esters by HPLC with Laser Light-Scattering Detection AOCS Official Method Ca 14b-96 Methods Methods and Analyses Analytical Chemistry Methods Downloads Methods Downloads ...

373

2008 Annual Meeting Abstacts  

Science Conference Proceedings (OSTI)

Abstracts from Health and Nutrition presented at the 99th AOCS Annual Meeting. 2008 Annual Meeting Abstacts Health acid analysis aocs april articles chloropropanediol contaminants detergents dietary fats division divisions esters fats fatty food foods gl

374

2011 Annual Meeting Abstacts  

Science Conference Proceedings (OSTI)

Abstracts from Industrial Oil Products presented at the 102nd AOCS Annual Meeting. 2011 Annual Meeting Abstacts Health acid analysis aocs april articles chloropropanediol contaminants detergents dietary fats division divisions esters fats fatty food food

375

Local Heating of Discrete Droplets Using Magnetic Porous Silicon-Based Photonic Crystals  

E-Print Network (OSTI)

,, Austin M. Derfus,§ Ester Segal, Kenneth S. Vecchio, Sangeeta N. Bhatia,§, and Michael J. Sailor fluorophores Cy3 and Cy5 to quantify the melting/ rebinding reaction by fluorescence resonance energy transfer

Bhatia, Sangeeta

376

2013 Annual Meeting Abstacts  

Science Conference Proceedings (OSTI)

Abstracts from Industrial Oil Products presented at the 104th AOCS Annual Meeting. 2013 Annual Meeting Abstacts Health acid analysis aocs april articles chloropropanediol contaminants detergents dietary fats division divisions esters fats fatty food food

377

In vitro and in vivo mRNA delivery using lipid-enveloped pHresponsive polymer nanoparticles  

E-Print Network (OSTI)

Biodegradable core?shell structured nanoparticles with a poly(?-amino ester) (PBAE) core enveloped by a phospholipid bilayer shell were developed for in vivo mRNA delivery with a view toward delivery of mRNA-based vaccines. ...

Su, Xingfang

378

Polyelectrolyte multilayers for tunable release of antibiotics and other therapeutics  

E-Print Network (OSTI)

Polyelectrolyte multilayers (PEMs) were fabricated via the layer-by-layer (LbL) deposition process, incorporating hydrolytically degradable poly([beta]-amino esters) to result in biodegradable PEMs that can release active ...

Chuang, Helen F

2008-01-01T23:59:59.000Z

379

STATEMENT OF CONSIDERATIONS REQUEST BY CARGILL, INC. FOR AN ADVANCE...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

its salts and esters, acrylamide, malonates and 1, 3-propanedial using a chemical catalysis. The work under this agreement is expected to take place over a period of about...

380

Biodiesel fuels could reduce dependence on foreign oil  

Science Conference Proceedings (OSTI)

this article reports on a test project by the University of Nebraska and Kansas State University which examines the effects of ester-blend biodiesel from tallow compared with conventional diesel fuel on engine performance, durability, and emissions.

NONE

1994-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "mono alkyl ester" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

2013 Annual Meeting Abstacts Listing  

Science Conference Proceedings (OSTI)

Abstracts from Industrial Oil Products presented at the 104th AOCS Annual Meeting. 2013 Annual Meeting Abstacts Listing Health acid analysis aocs april articles chloropropanediol contaminants detergents dietary fats division divisions esters fats fatty f

382

Energy Basics: Biofuels  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

The biomass-derived ethyl or methyl esters can be blended with conventional diesel fuel or used as a neat fuel (100% biodiesel). Learn more about biodiesel basics. Biofuel...

383

Fatty Acid-Producing Microbes for Generating Medium- and Long ...  

... this process results in a heterogeneous mixture of fatty acid esters and unwanted side ... Lennen R.M., Braden D.J., ... (DOE BER Office of Science DE-FC02 ...

384

Performance degradation of P3HT:PCBM Polymer/fullerene photovoltaic cells under gamma irradiation.  

E-Print Network (OSTI)

??The gamma radiation damage effect on polymer-based hybrid photovoltaic cells consisting of a blend of poly-3-hexylthiophene (P3HT) and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) is investigated.… (more)

Todd, Aaron

2009-01-01T23:59:59.000Z

385

Energy-absorbent Material and Method of Making  

This invention relates to materials that absorb and dissipate energy and/or selectively allow energy to be transmitted – in particular, polymeric materials that include polyol(s) such as polyethers, polyesters, polyether/esters, acrylics, plus other ...

386

Regulatory Resources for Process Contaminants (3-MCPD)  

Science Conference Proceedings (OSTI)

Regulatory information and references for 3-MCPD(3-Monochloropropane-1,2-diol )process contaminants. Regulatory Resources for Process Contaminants (3-MCPD) 3-MCPD 2-diol 3-MCPD 3-MCPD Esters 3-monochloropropane-1 acid analysis aocs april articles certifi

387

2008 Annual Meeting Abstacts  

Science Conference Proceedings (OSTI)

Abstracts from Industrial Oil Products presented at the 99th AOCS Annual Meeting. 2008 Annual Meeting Abstacts Health acid analysis aocs april articles chloropropanediol contaminants detergents dietary fats division divisions esters fats fatty food foods

388

AOCS Official Method Ce 1-62  

Science Conference Proceedings (OSTI)

Fatty Acid Composition by Packed Column Gas Chromatography AOCS Official Method Ce 1-62 Methods Methods and Analyses Analytical Chemistry Methods Downloads Methods Downloads DEFINITION Methyl esters of fatty ac

389

Open Archive TOULOUSE Archive Ouverte (OATAO) OATAO is an open access repository that collects the work of Toulouse researchers and  

E-Print Network (OSTI)

and trends concerning cellulosic materials processed in scCO2 such as cellulose drying to obtain aerogels for cellulose esters and ether synthesis, and fibres and film fabrication. These materials are used in coatings

Recanati, Catherine

390

Shear and Extensional Rheology of Cellulose/Ionic Liquid Solutions Simon J. Haward1*  

E-Print Network (OSTI)

-anhydroglucopyranose building blocks are substituted by ethers or esters. 1-4 The extensive inter-chain and intra-chain hydrogen and other desirable properties that drive its use in textile fibers, films, nanoparticles, aerogels

391

NIST: Freq. Interstellar Molec. Micro. Trans. - Table 1  

Science Conference Proceedings (OSTI)

... C 2 H 4 O 2, Methyl ester formic acid (methyl formate), CH 3 OCHO, [107-31-3], Bro75. C 2 H 4 O 2, Acetic acid, CH 3 COOH, [64-19-7], Meh97. ...

392

2010 Annual Meeting Abstacts  

Science Conference Proceedings (OSTI)

Abstracts from Industrial Oil Products presented at the 101st AOCS Annual Meeting. 2010 Annual Meeting Abstacts Health acid analysis aocs april articles chloropropanediol contaminants detergents dietary fats division divisions esters fats fatty food food

393

Comparing the biodiesel and biogasoil production from different natural triglycerides  

Science Conference Proceedings (OSTI)

Regarding the sustainable mobility, product quality and environmental aspects fatty acids methyl esters and biogasoils were compared. They were produced by the transesterification and special hydrocracking (including the isomerization, as well) of triglycerides, ... Keywords: biodiesel, biogasoil, feedstock supply, quality comparison

Jenö Hancsók; Zoltán Varga; Sándor Kovács; Tamás Kasza

2011-12-01T23:59:59.000Z

394

2013 Annual Meeting Abstacts Listing  

Science Conference Proceedings (OSTI)

Abstracts from Health and Nutrition presented at the 104th AOCS Annual Meeting. 2013 Annual Meeting Abstacts Listing Health acid analysis aocs april articles chloropropanediol contaminants detergents dietary fats division divisions esters fats fatty foo

395

2013 Annual Meeting Abstacts  

Science Conference Proceedings (OSTI)

Abstracts from Health and Nutrition presented at the 104th AOCS Annual Meeting. 2013 Annual Meeting Abstacts Health acid analysis aocs april articles chloropropanediol contaminants detergents dietary fats division divisions esters fats fatty food foods g

396

2012 Annual Meeting Abstacts  

Science Conference Proceedings (OSTI)

Abstracts from Health and Nutrition presented at the 103rd AOCS Annual Meeting. 2012 Annual Meeting Abstacts Health acid analysis aocs april articles chloropropanediol contaminants detergents dietary fats division divisions esters fats fatty food foods g

397

Horizontal Surface Tension Gradients Induced in Monolayers by Gravity Water Wave Action  

Science Conference Proceedings (OSTI)

Surface tension gradients have been measured for three different monolayers (oleyl alcohol, palmitic acid methyl ester and cetyl trimethyl ammonium bromide) spread on a wavy water surface (waves with 1-Hz frequency; 2 cm wave height). The wave-...

Philipp A. Lange; Heinrich Hühnerfuss

1984-10-01T23:59:59.000Z

398

TITLE BLOCK  

Science Conference Proceedings (OSTI)

SAMPLING AND ANALYSIS OF COMMERCIAL FATS AND OILS METHOD NUMBER: Joint AOCS/JOCS Official Method Cd 28-10 APPROVAL: Official Method with full collaborative data TITLE: Glycidyl Fatty Acid Esters in Edible Oils DEFINITION: This meth

399

Analytical Division Seed Oil Translation Table  

Science Conference Proceedings (OSTI)

seed oil translation table nomencalture Analytical Division Seed Oil Translation Table Analytical Chemistry Analytical Chemistry aocs articles atomic)FluorometryDifferential scanning calorimetry chemistry Chromatography (liquid detergents esters fats fo

400

Asphaltenes-based polymer nano-composites  

Science Conference Proceedings (OSTI)

Inventive composite materials are provided. The composite is preferably a nano-composite, and comprises an asphaltene, or a mixture of asphaltenes, blended with a polymer. The polymer can be any polymer in need of altered properties, including those selected from the group consisting of epoxies, acrylics, urethanes, silicones, cyanoacrylates, vulcanized rubber, phenol-formaldehyde, melamine-formaldehyde, urea-formaldehyde, imides, esters, cyanate esters, allyl resins.

Bowen, III, Daniel E

2013-12-17T23:59:59.000Z

Note: This page contains sample records for the topic "mono alkyl ester" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Rapid brain scanning radiopharmaceutical  

DOE Patents (OSTI)

A method for detecting the blood flow in animals, particularly in the brain, is provided wherein a detectable amount of a novel radioactive compound of the formula I is administered to one animal: ##STR1## wherein R.sub.1 and R.sub.2 are independently alkyl of 1 to 6 carbon atoms or benzyl; R.sub.3 is alkyl of 1 to 6 carbon atoms, benzyl, cyclopropylalkyl of 4 to 6 carbon atoms, or cyanoalkyl of 2 to 6 carbon atoms; R.sub.4 is hydrogen, benzyl or alkyl of 1 to 6 carbon atoms; with the provisos that R.sub.4 is not isopropyl and when R.sub.4 is methyl, R.sub.3 is not benzyl; and X is a radioactive halogen.

Sargent, III, Thornton W. (Berkeley, CA); Shulgin, Alexander T. (Lafayette, CA); Mathis, Chester A. (Oakland, CA)

1987-01-01T23:59:59.000Z

402

SLURRY SOLVENT EXTRACTION PROCESS FOR THE RECOVERY OF METALS FROM SOLID MATERIALS  

DOE Patents (OSTI)

A solvent extraction process is described for recovering uranium from low grade uranium bearing minerals such as carnotit or shale. The finely communited ore is made up as an aqueous slurry containing the necessary amount of acid to solubilize the uranium and simultaneously or subsequently contacted with an organic solvent extractant such as the alkyl ortho-, or pyro phosphoric acids, alkyl phosphites or alkyl phosphonates in combination with a diluent such as kerosene or carbon tetrachlorids. The extractant phase is separated from the slurry and treated by any suitable process to recover the uranium therefrom. One method for recovering the uranium comprises treating the extract with aqueous HF containing a reducing agent such as ferrous sulfate, which reduces the uranium and causes it to be precipitated as uranium tetrafluoride.

Grinstead, R.R.

1959-01-20T23:59:59.000Z

403

Carboxy, carboalkoxy and carbamile substituted isonitrile radionuclide complexes  

DOE Patents (OSTI)

A coordination complex comprising a radionuclide selected from the class consisting of radioactive isotopes of Tc, Ru, Co, Pt and Re and an isonitrile ligand of the formula: (CNX)R, where X is a lower alkyl group having 1 to 4 carbon atoms, wherein R is selected from the group consisting of COOR.sup.1 and CONR.sup.2 R.sup.3 where R.sup.1 can be H, a pharmaceutically acceptable cation, or a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms. R.sup.2, and R.sup.3 can be H, or a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms, and R.sup.2 and R.sup.3 can be the same of different is disclosed. Kits that can be used to form these complexes are also disclosed.

Jones, Alun G. (Newton Centre, MA); Davison, Alan (Needham, MA); Kronauge, James (Cambridge, MA); Abrams, Michael J. (Allston, MA)

1989-01-01T23:59:59.000Z

404

No-carrier-added [.sup.18 F]-N-fluoroalkylspiroperidols  

DOE Patents (OSTI)

There is disclosed radioligands labeled with the position emitting radionuclide [.sup.18 F] suitable for dynamic study in living humans with position emission transaxial tomography. These new [.sup.18 F]-N-fluoroalkylspiroperidols, wherein the alkyl group contains from 2-6 carbon atoms, exhibit extremely high affinity for the dopamine receptors and provide enhanced uptake and retention in the brain concomitant with reduced radiation burden. These characteristics all combine to make these new radioligands useful for mapping dopamine receptors in normal and disease states in the living brain. Additionally, a new synthetic procedure for these radioligands as well as a new procedure for preparing the radiolabeled alkyl halide alkylating reagents are also disclosed.

Shiue, Chyng-Yann (East Setauket, NY); Wolf, Alfred P. (Setauket, NY); Bai, Lan-Qin (Upton, NY); Teng, Ren-Tui (Upton, NY)

1989-01-01T23:59:59.000Z

405

Carboxy, carboalkoxy and carbamile substituted isonitrile radionuclide complexes  

DOE Patents (OSTI)

A coordination complex comprising a radionuclide selected from the class consisting of radioactive isotopes of Tc, Ru, Co, Pt and Re and an isonitrile ligand of the formula: (CNX)R, where X is a lower alkyl group having 1 to 4 carbon atoms, wherein R is selected from the group consisting of COOR.sup.1 and CONR.sup.2 R.sup.3 where R.sup.1 can be H, a pharmaceutically acceptable cation, or a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms, R.sup.2, and R.sup.3 can be H, or a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms, and R.sup.2 and R.sup.3 can be the same or different is disclosed. Kits that can be used to form these complexes are also disclosed.

Jones, Alun G. (Newton Centre, MA); Davison, Alan (Needham, MA); Kronauge, James (Cambridge, MA); Abrams, Michael J. (Allston, MA)

1988-04-05T23:59:59.000Z

406

Biodiesel fuel from animal fat. Ancillary studies on transesterification of beef tallow  

Science Conference Proceedings (OSTI)

Transesterification of beef tallow was investigated. The solubility of ethanol in beef tallow was much higher than that of methanol. At 100 C the solubility of methanol was 19% (w/w). The solubility of ethanol in beef tallow reached 100% (w/w) at about 68 C. For the distribution of methanol between beef tallow methyl esters (BTME) and glycerol, the percentage of total methanol in the glycerol phase was higher than that in the fatty acid methyl ester (FAME) phase in a simulated system at room temperature. At 65--80 C, however, the percentage of total methanol in FAME (60% (w/w)) was higher than that in glycerol (40% (w/w)) in a 90:10 (w/w) blend of FAME and glycerol. This coincided with the methanol distribution in the transesterified product. The process for making beef tallow methyl esters should recover methanol using vacuum distillation, separate the ester and glycerol phases, and then wash the beef tallow methyl esters with warm water. At neutral pH, the separation of ester and glycerol and water washing was easier because it reduced emulsion formation.

Ma, F.; Clements, L.D.; Hanna, M.A. [Univ. of Nebraska, Lincoln, NE (United States)] [Univ. of Nebraska, Lincoln, NE (United States)

1998-09-01T23:59:59.000Z

407

Pistachio, Pistacia vera (Anacardiaceae)  

E-Print Network (OSTI)

40000 Composition: Sugar: 19% Protein: > 20% Oil: 50% Saturated 13% Mono-unsaturated 68% Poly held Americans hostage in the US embassy in Iran in the late 1970's. Iran was the world's leading pistachio producer at that time, and the lack of exportation from this country following the revolution sent

Gepts, Paul

408

Nano-line width control and standards using Lateral Pattern Definition technique  

Science Conference Proceedings (OSTI)

Lateral Pattern Definition technique was adopted for manufacturing nano-size width standards. Narrow oxide fences, 40nm to 100nm wide were manufactured using very simple technological instrumentation. Poly-Si and mono-Si step technology versions were ... Keywords: Lateral Pattern Definition, Nanometrology, Width standards

Micha? Zaborowski; Dariusz Szmigiel; Teodor Gotszalk; Katerina Ivanova; Yanko Sarov; Tzvetan Ivanov; Burkhard E. Volland; Ivo W. Rangelow; Piotr Grabiec

2006-04-01T23:59:59.000Z

409

Process for cementing geothermal wells  

DOE Patents (OSTI)

A pumpable slurry of coal-filled furfuryl alcohol, furfural, and/or a low molecular weight mono- or copolymer thereof containing, preferably, a catalytic amount of a soluble acid catalyst is used to cement a casing in a geothermal well.

Eilers, Louis H. (Inola, OK)

1985-01-01T23:59:59.000Z

410

Aircraft-produced Ice Particles (APIPs) in Supercooled Clouds and the Probable Mechanism for their Production  

Science Conference Proceedings (OSTI)

This paper presents the results of studies of aircraft-produced ice particles (APIPs) in supercooled fog over Mono Lake, California. The King Air 200T cloud physics aircraft of the University of Wyoming and three other aircraft (a Piper Aztec, a ...

William L. Woodley; Thomas J. Henderson; Bernard Vonnegut; Glenn Gordon; Robert Breidenthal; Shirley M. Holle

1991-11-01T23:59:59.000Z

411

Separation of gonadotropic fractions with different species specificities from tuna pituitaries  

SciTech Connect

Eight different gonadotropic glycoprotein fractions were separated from the acetone-dried powder of yellow fin tuna pituitary glands by successive chromatographies on Superose 12 for gel filtration and Mono Q for anion exchange using the Pharmacia fast protein liquid chromatography system. This was preceded by preliminary separations using an ammonium sulfate precipitation method and affinity chromatography on concanavalin A-Sepharose. For biological characterization, we employed two radioreceptor assay systems, one using goby testis plasma membranes and silver carp GTH as the receptor and radioligand, respectively, and the other using testis plasma membranes of the yellow fin tuna and gonadotropin of the same species, respectively. We also employed two testicular cyclic AMP accumulation bioassay methods in vitro, one with the goby testis and the other with the mackerel testis. The least acidic fraction after Mono Q was further separated into four subfractions by rechromatography with Mono Q. They were strongly active in the tuna and mackerel assays but almost inactive in the goby assays. They were referred to as tuna-type tuna gonadotropin. In contrast, the most acidic fraction obtained after the first Mono Q was active in the goby assays but almost inactive in the tuna and mackerel assays. It was referred to as goby-type tuna gonadotropin. The intermediate fractions were active on both assays and are considered to be mixtures of tuna-type and goby-type gonadotropins. The reason for the presence of gonadotropin inactive to homologous species is discussed from the evolutionary viewpoint.

Ando, H.; Ishii, S.

1988-05-01T23:59:59.000Z

412

Canola Oil: The Myths Debunked You're looking for more information about canola -the seed, the oil and the meal. Maybe you've  

E-Print Network (OSTI)

Canola Oil: The Myths Debunked You're looking for more information about canola - the seed, the oil's the truth. We promise. Q: What is canola oil? A: Canola oil is the healthiest of all commonly used cooking oils. It is lowest in saturated fat, high in cholesterol-lowering mono-unsaturated fat and the best

Balasundaram, Balabhaskar "Baski"

413

Regimes of polymer behaviour in drop-on-demand ink-jetting  

E-Print Network (OSTI)

and Ian M Hutchings, University of Cambridge, Cambridge UK; Oliver G Harlen, Claire McIlroy and Neil F Morrison, University of Leeds, Leeds UK Abstract A recent model for the drop-on-demand (DoD) jetting of mono-disperse linear polymer solutions...

Hoath, S.D.; Hutchings, I.M.; Harlen, O.G.; McIIroy, C.; Morrison, N.F.

2012-01-01T23:59:59.000Z

414

REVUE DE PHYSIQUE APPLIQUEE Colloque C4, Supplement au n04, Tome 24, avril 1989  

E-Print Network (OSTI)

REVUE DE PHYSIQUE APPLIQUEE Colloque C4, Supplement au n04, Tome 24, avril 1989 SILICA AEROGELS permettant d' elaborer des aerogels mono1ithi- ques sont precisees. L'analyse structurale des aerogels montre du solvant employe. L'evolution de la structure des aerogels en fonction de la temperature est 6

Paris-Sud XI, Université de

415

DOI: 10.1002/adma.200602792 Filling Fraction Dependent Properties of Inverse Opal Metallic  

E-Print Network (OSTI)

/grant number DAAD19-03-1- 0227. Some experiments were performed in the Center for Micro- analysis of Materials with previous observation on mono- layer cavity structures.[15] Our data is con- sistent with a model whereb). The result of this etching can be structurally modeled as an increase in the diameter

Braun, Paul

416

Boron nitride substrates for high-quality graphene electronics  

E-Print Network (OSTI)

Boron nitride substrates for high-quality graphene electronics C. R. Dean1,2 *, A. F. Young3 , I and J. Hone2 * Graphene devices on standard SiO2 substrates are highly disor- dered, exhibiting report the fabrication and characterization of high-quality exfoliated mono- and bilayer graphene devices

Shepard, Kenneth

417

Multifractal scaling behavior analysis for existing dams  

Science Conference Proceedings (OSTI)

The fractal theory was used to describe long term behavior of dam structures by means of determining (mono-) fractal exponents. Many records do not exhibit a simple monofractal scaling behavior, which can be accounted for by a single scaling exponent. ... Keywords: Dam, Long term behavior, Multifractal detrended fluctuation analysis, Observation time series

Huaizhi Su, Zhiping Wen, Feng Wang, Bowen Wei, Jiang Hu

2013-09-01T23:59:59.000Z

418

Study of the collision of one rapid sphere on 3D packings: Experimental and numerical results  

Science Conference Proceedings (OSTI)

We report on experimental studies of the collision process between an incident bead and a three-dimensional packing of mono-size beads. The understanding of such a process and the resulting ejection of grains is, in particular, crucial to describe aeolian ... Keywords: DEM modelisation, Granular transport, Saltation

L. Oger; M. Ammi; A. Valance; D. Beladjine

2008-01-01T23:59:59.000Z

419

Planar Vacuum Diode With Monoenergetic Electrons  

E-Print Network (OSTI)

The paper analyses volt-ampere characteristics of a planar vacuum diode with mono-energetic electrons, emitted by the cathode (an electron beam). The movement of the electron beam in the volume of the diode is described. An analytic dependence of the volt-ampere characteristics in an unlimited and limited by the field mode of the electron beam is derived.

Dimitar G. Stoyanov

2007-06-06T23:59:59.000Z

420

Ultra hard x rays from krypton clusters heated by intense laser fields R. C. Issac,a)  

E-Print Network (OSTI)

with gas-phase targets, x-ray sources derived from solid tar- gets have superior x-ray yields in the hard x. Hulin, P. Mono, J. Abdallah, Jr., A. Y. Faenov, I. Y. Skobelev, A. I. Magunov, and T. A. Pikuz, JETP

Strathclyde, University of

Note: This page contains sample records for the topic "mono alkyl ester" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

ACEEE Int. J. on Control System and Instrumentation, Vol. 03, No. 01, Feb2012 DOI:01.IJCSI.03.01.527  

E-Print Network (OSTI)

photovoltaic model of PV cell, module, and array model applicable for mono crystalline, poly crystalline (threefold over the same period). Commercial Photovoltaic cells were first developed in Bell lab in 1954 of designed PV systems prior to installation. II. PHOTOVOLTAIC CELL Solar cells consist of a p-n junction

Paris-Sud XI, Université de

422

S  

NLE Websites -- All DOE Office Websites (Extended Search)

t olerable slope e rrors. * Preliminary F EA s hows t hat a d irectly---cooled, " hockey p uck" s tyle mono c rystal c an s upport > 2 k W w ith s lope e rrors s mall c...

423

Process for reducing aromatic compounds in ethylenediamine with calcium  

DOE Patents (OSTI)

Olefins are produced by containing an organic compound having at least one benzene ring with ethylenediamine and calcium metal, the calcium metal being used in large excess or alternatively in conjunction with an inert abrasive particulate substance. Substantially all of the organic compounds are converted to corresponding cyclic olefins, largely mono-olefins.

Benkeser, R.A.; Laugal, J.A.; Rappa, A.

1985-08-06T23:59:59.000Z

424

Process for reducing aromatic compounds in ethylenediamine with calcium  

DOE Patents (OSTI)

Olefins are produced by containing an organic compound having at least one benzene ring with ethylenediamine and calcium metal, the calcium metal being used in large excess or alternatively in conjunction with an inert abrasive particulate substance. Substantially all of the organic compounds are converted to corresponding cyclic olefins, largely mono-olefins.

Benkeser, Robert A. (West Lafayette, IN); Laugal, James A. (Lostant, IL); Rappa, Angela (Baltimore, MD)

1985-01-01T23:59:59.000Z

425

Ris-R-1211(EN) Development of Optically Stimulated  

E-Print Network (OSTI)

with Oklahoma State University. This apparatus uses blue (or green) light emitting diodes as the stimulation developed for the commer- cially available Risø TL/OSL reader. The first is a blue (470 nm) light emitting diode (LED) array, developed in response to requests for a more intense mono- chromatic and convenient

426

Data Sources: California Department of Fish and Game  

E-Print Network (OSTI)

Dume SMR Point Vicente SMR Naples SMCA Crystal Cove SMCA Dana Point SMCA Point Dume SMCA San Diego Closure 2 Bolsa Chica SMR Batiquitos Lagoon SMR San Elijo Lagoon SMR Swami's SMCA Tijuana River Mouth SMCA River Sisquoc River Santa Cr uzCr eek Santa Ynez Ri ver Mono Cree k San Antonio Creek Santa Ynez R iver

Hampton, Randy

427

Einladung/Programm VDI-Expertenforum  

E-Print Network (OSTI)

using several simulated observer filters including; non-prewhitening matched filter with eye, Hotelling, and channelized Hotelling. Using the VIP-Man phantom as a representative patient, a CsI flat panel detector and a small lesion in the left lung was examined as a test case. Energy was varied mono-energetically while

Stein, Oliver

428

Analysis of electromigration induced early failures in Cu interconnects for 45nm node  

Science Conference Proceedings (OSTI)

Bi-directional current stressing was used for monitoring electromigration (EM) lifetime evolution in 45nm node interconnects. Experimental results show that an initial bimodal distribution of lifetimes can be modified into a more robust mono-modal distribution. ... Keywords: Bi-directional current, Cu interconnects, Electromigration, FEM modeling

L. Arnaud; F. Cacho; L. Doyen; F. Terrier; D. Galpin; C. Monget

2010-03-01T23:59:59.000Z

429

Formation of NiGe through germanium oxide on Ge(001) substrate  

Science Conference Proceedings (OSTI)

Germanium based devices are of interest due to their performance potential. The use of germanium as source and drain requires low resistance access achieved by the formation of germanide (metal-germanium compound). The nickel mono-germanide (NiGe) is ...

F. Nemouchi, V. Carron, J. L. LáBáR, L. Vandroux, Y. Morand, T. Morel, J. P. Barnes

2013-07-01T23:59:59.000Z

430

Software application implement in java for electrical lines dimensioning  

Science Conference Proceedings (OSTI)

In this paper it was present a software package implemented in java useful for dimensioning of low voltage lines mono phase and three phases (AC and DC). The modeled networks are tree type. This software with graphical user interface allows the estimation ... Keywords: computer software, electrical lines, java, optimal dimensioning

Cristian Abrudean; Manuela Panoiu

2008-11-01T23:59:59.000Z

431

SSRL BEAM PORT SCHEDULE  

NLE Websites -- All DOE Office Websites (Extended Search)

2A50 -Lippard 2A50 -Lippard 5A89 -Stout MAINTAP MAINTAP 4A80 -Weis 4A80 -Weis 1X36 -Ng 1X36 -Ng 9-1 PX Mono MAINTAP MAINTAP -Change 4A80 -Weis -Change 1X36 -Ng 1X36 -Ng...

432

Chlorofluorocarbons  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Trace Gases » Chlorofluorocarbons Atmospheric Trace Gases » Chlorofluorocarbons Chlorofluorocarbons CFC-11 (trichlorofluoromethane - CFCl2) Advanced Global Atmospheric Gases Experiment (AGAGE, Prinn et al.) Methane, Nonmethane Hydrocarbons, Alkyl Nitrates, and Chlorinated Carbon Compounds including 3 Chlorofluorocarbons (CFC-11, CFC-12, and CFC-113) in Whole-air Samples (Blake) Globally Averaged Atmospheric CFC-11 Concentrations: Monthly and Annual Data for the Period 1975-1992 (Khalil and Rasmussen) Atmospheric CFC, CCl4, and SF6 Historical Update (Bullister) CFC-12 (dichlorodifluoromethane - CF2Cl2) Advanced Global Atmospheric Gases Experiment (AGAGE, Prinn et al.) Methane, Nonmethane Hydrocarbons, Alkyl Nitrates, and Chlorinated Carbon Compounds including 3 Chlorofluorocarbons (CFC-11, CFC-12, and

433

KEROGEN OIL VALUE ENHANCEMENT RESEARCH  

SciTech Connect

Three general categories of products from the Estonia Kukersite kerogen oil were defined: pure compounds, broad range concentrates, and sweet refinery feedstock. Product development and market research center on these three categories. Further attempts were made to identify and test chemical approaches for producing lower alkyl resorcinols (what the market requires) from higher alkyl resorcinols. The approaches and process conditions tested have not yet produced satisfactory results. Progress was made to interest industry in the phenolic products producible. A sample of oil from the Galoter retort was received from Estonia and characterization of this sample was initiated. The sample was batch extracted and results of yields and selectivity are reported.

James W. Bunger, Ph.D.; Christopher P. Russell, Ph.D.; Donald E. Cogswell, M.S.

2002-05-22T23:59:59.000Z

434

Process for removing NO sub x emissions from combustion effluents  

SciTech Connect

This patent describes a method of removing NO from a stream of combustion products injecting an alkyl amine into the stream to effect reduction of NO to N{sub 2}, wherein the alkyl amine comprises methyl amine, and the process is conducted at a temperature within the range of 350{degrees} C at a molar ratio to amine within the range of about 0.2 to 2.0 without a NO reduction catalyst, the method being capable of at least about a 50% conversion of NO in the combustion products to N{sub 2}.

Ham, D.O.; Moniz, G.A.; Gouveia, M.J.

1992-06-09T23:59:59.000Z

435

Method for extracting lanthanides and actinides from acid solutions  

SciTech Connect

A process for the recovery of actinide and lanthanide values from aqueous acidic solutions with an organic extractant having the formula: ##STR1## where .phi. is phenyl, R.sup.1 is a straight or branched alkyl or alkoxyalkyl containing from 6 to 12 carbon atoms and R.sup.2 is an alkyl containing from 3 to 6 carbon atoms. The process is suitable for the separation of actinide and lanthanide values from fission product values found together in high level nuclear reprocessing waste solutions.

Horwitz, E. Philip (Naperville, IL); Kalina, Dale G. (Naperville, IL); Kaplan, Louis (Lombard, IL); Mason, George W. (Clarendon Hills, IL)

1985-01-01T23:59:59.000Z

436

pubs.acs.org/Biochemistry Published on Web 09/20/2010 r 2010 American Chemical Society 9046 Biochemistry 2010, 49, 90469057  

E-Print Network (OSTI)

by Site-Specific Chemical Alkylation M. Adil Khan, Joel Moktar, Patrick J. Mott, Mary Vu, Aaron H. Mc- hydroxymyristate chain at position 2 of lipid A (endotoxin) (Figure 1A) (1-3). In Escherichia coli and related pathway (8-10). Transcription of the pagP gene is governed by the PhoP/PhoQ regulon, which con- trols

Bishop, Russell

437

Lithium Ion Solvation: Amine and Unsaturated Hydrocarbon Solvates of Lithium Hexamethyldisilazide (LiHMDS)  

E-Print Network (OSTI)

Lithium Ion Solvation: Amine and Unsaturated Hydrocarbon Solvates of Lithium Hexamethyldisilazide, and 13C NMR spectroscopic studies of 6Li-15N labeled lithium hexamethyldisilazide ([6Li,15N]- Li ligand structure and lithium amide aggregation state is a complex and sensitive function of amine alkyl

Collum, David B.

438

Method of synthesizing pyrite nanocrystals  

DOE Patents (OSTI)

A method of synthesizing pyrite nanocrystals is disclosed which in one embodiment includes forming a solution of iron (III) diethyl dithiophosphate and tetra-alkyl-ammonium halide in water. The solution is heated under pressure. Pyrite nanocrystal particles are then recovered from the solution.

Wadia, Cyrus; Wu, Yue

2013-04-23T23:59:59.000Z

439

Method for preparing polyolefin composites containing a phase change material  

DOE Patents (OSTI)

A composite useful in thermal energy storage, said composite being formed of a polyolefin matrix having a phase change material such as a crystalline alkyl hydrocarbon incorporated therein. The composite is useful in forming pellets, sheets or fibers having thermal energy storage characteristics; methods for forming the composite are also disclosed.

Salyer, Ival O. (Dayton, OH)

1990-01-01T23:59:59.000Z

440

Polyolefin composites containing a phase change material  

DOE Patents (OSTI)

A composite useful in thermal energy storage, said composite being formed of a polyolefin matrix having a phase change material such as a crystalline alkyl hydrocarbon incorporated therein, said polyolefin being thermally form stable; the composite is useful in forming pellets, sheets or fibers having thermal energy storage characteristics; methods for forming the composite are also disclosed.

Salyer, Ival O. (Dayton, OH)

1991-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mono alkyl ester" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Synthesis and reactivity of molybdenum organometallic complexes supported by amide ligands  

E-Print Network (OSTI)

Chapter 1. Synthesis and Reactivity of Molybdenum Alkyl Complexes Supported by a Diamidoamine Ligand. The synthesis of a new diamidoamine ligand, CH3N[CH2CH2NH(3-(CF3)C6H4)]2 (H2L) is reported. Molybdenum complexes of the ...

Hock, Adam S. (Adam Scott)

2007-01-01T23:59:59.000Z

442

Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen  

DOE Patents (OSTI)

A process for selective thermal oxidation or photooxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation and photooxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls in solvent free zeolites under dark thermal conditions or under irradiation with visible light. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts.

Frei, Heinz (Berkeley, CA); Blatter, Fritz (Basel, CH); Sun, Hai (Saint Charles, MO)

1999-01-01T23:59:59.000Z

443

Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen  

DOE Patents (OSTI)

A process for a combined selective thermal oxidation and photooxidation of hydrocarbons adsorbed onto zeolite matrices. A highly combined selective thermal oxidation and photooxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls in solvent free zeolites under dark thermal conditions or under irradiation with visible light. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts.

Frei, Heinz (Berkeley, CA); Blatter, Fritz (Basel, CH); Sun, Hai (Saint Charles, MO)

2001-01-01T23:59:59.000Z

444

Selective thermal oxidation of hydrocarbons in zeolites by oxygen  

DOE Patents (OSTI)

A process for selective thermal oxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls is carried out in solvent free zeolites under dark thermal conditions. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts.

Frei, Heinz (Berkeley, CA); Blatter, Fritz (Basel, CH); Sun, Hai (Saint Charles, MO)

2000-01-01T23:59:59.000Z

445

Enhanced immunological and detoxification responses in Pacific oysters, Crassostrea gigas, exposed1 to chemically dispersed oil2  

E-Print Network (OSTI)

to chemically dispersed oil2 3 Luna-Acosta, A.a,* , Kanan, R.b , Le Floch, S.b , Huet, V.a , Pineau P;Abstract: The aim of this study was to evaluate the effects of chemically dispersed oil on an20 of the chemical dispersant. After 2 days of exposure to chemically dispersed28 oil, alkylated naphthalenes

Paris-Sud XI, Université de

446

Acceptorless Photocatalytic Dehydrogenation for Alcohol Decarbonylation and Imine Synthesis  

Science Conference Proceedings (OSTI)

It has come to light: Renewed interest in conversions of highly oxygenated materials has motivated studies of the organometallic-catalyzed photocatalytic dehydrogenative decarbonylation of primary alcohols into alkanes, CO, and H2 (see scheme). Methanol, ethanol, benzyl alcohol, and cyclohexanemethanol are readily decarbonylated. The photocatalysts are also active for amine dehydrogenation to give N-alkyl aldimines and H2.

Ho, Hung-An; Manna, Kuntal; Sadow, Aaron D.

2012-07-29T23:59:59.000Z

447

Process for biological material carbon-carbon bond formation  

DOE Patents (OSTI)

A process for providing vicinal dimethyl long chain between alkyl groups of organic compounds is described. The process uses intact or disrupted cells of various species of bacteria, particularly Thermoanaerobacter sp., Sarcina sp. and Butyrivibrio sp. The process can be conducted in an aqueous reaction mixture at room temperatures.

Hollingsworth, Rawle I. (Haslett, MI); Jung, Seunho (Kuyngkido, KR); Mindock, Carol A. (Lansing, MI)

1998-01-01T23:59:59.000Z

448

Process for biological material carbon-carbon bond formation  

DOE Patents (OSTI)

A process for providing vicinal dimethyl long chain between alkyl groups of organic compounds is described. The process uses intact or disrupted cells of various species of bacteria, particularly Thermoanaerobacter sp., Sarcina sp. and Butyrivibrio sp. The process can be conducted in an aqueous reaction mixture at room temperatures. 8 figs.

Hollingsworth, R.I.; Jung, S.; Mindock, C.A.

1998-12-22T23:59:59.000Z

449

Surface functionalization of metal?organic polyhedron for homogeneous cyclopropanation catalysis  

Science Conference Proceedings (OSTI)

A super-paddlewheel (comprised of two paddlewheels) metal-organic polyhedron (MOP) containing surface hydroxyl groups was synthesized and characterized. Condensation reactions with linear alkyl anhydrides lead to new MOPs with enhanced solubility. As a result, the surface-modified MOP 4 was demonstrated as a homogeneous Lewis-acid catalyst.

Lu, Weigang; Yuan, Daqiang; Yakovenko, Andrey; Zhou, Hong-Cai (TAM)

2012-03-13T23:59:59.000Z

450

Improved method for extracting lanthanides and actinides from acid solutions  

DOE Patents (OSTI)

A process for the recovery of actinide and lanthanide values from aqueous acidic solutions uses a new series of neutral bi-functional extractants, the alkyl(phenyl)-N,N-dialkylcarbamoylmethylphosphine oxides. The process is suitable for the separation of actinide and lanthanide values from fission product values found together in high-level nuclear reprocessing waste solutions.

Horwitz, E.P.; Kalina, D.G.; Kaplan, L.; Mason, G.W.

1983-07-26T23:59:59.000Z

451

Electrode compositions  

DOE Patents (OSTI)

An electrode composition is described for use as an electrode in a non-aqueous battery system. The electrode composition contains an electrically active powder in a solid polymer and, as a dispersant, a C{sub 8}-C{sub 15} alkyl capped oligomer of a hexanoic acid that is electrochemically inert at 2.5--4.5 volts.

Block, J.; Fan, X.

1998-10-27T23:59:59.000Z

452

Electrode compositions  

DOE Patents (OSTI)

An electrode composition for use as an electrode in a non-aqueous battery system. The electrode composition contains an electrically active powder in a solid polymer and, as a dispersant, a C.sub.8 -C.sub.15 alkyl capped oligomer of a hexanoic acid that is electrochemically inert at 2.5-4.5 volts.

Block, Jacob (Rockville, MD); Fan, Xiyun (Orange, TX)

1998-01-01T23:59:59.000Z

453

DEVELOPMENT AND CONSTRUCTION OF LOW-CRACKING HIGH-PERFORMANCE CONCRETE (LC-HPC) BRIDGE  

E-Print Network (OSTI)

; Seven-coordination; Pentafluorophenyl 1. Introduction In 1972, Wilkinson announced the synthesis with the cations were completely absent in the solid state. Metal-coordinated alkyl and aryl ligands bear partial it is insol- uble. 1 H- and 19 F-NMR spectra of solutions prepared by the low-temperature dissolution of 1

Peterson, Blake R.

454

Phenyl boron-based compounds as anion receptors for non-aqueous battery electrolytes  

SciTech Connect

Novel fluorinated boronate-based compounds which act as anion receptors in non-aqueous battery electrolytes are provided. When added to non-aqueous battery electrolytes, the fluorinated boronate-based compounds of the invention enhance ionic conductivity and cation transference number of non-aqueous electrolytes. The fluorinated boronate-based anion receptors include different fluorinated alkyl and aryl groups.

Lee, Hung Sui (East Setauket, NY); Yang, Xiao-Qing (Port Jefferson Station, NY); McBreen, James (Bellport, NY); Sun, Xuehui (Middle Island, NY)

2002-01-01T23:59:59.000Z

455

Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen  

DOE Patents (OSTI)

A process is described for selective thermal oxidation or photooxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation and photooxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls in solvent free zeolites under dark thermal conditions or under irradiation with visible light. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts. 19 figs.

Frei, H.; Blatter, F.; Sun, H.

1999-06-22T23:59:59.000Z

456

Ris-M-2348 ACCELERATOR DEPARTMENT  

E-Print Network (OSTI)

RADIATION 22 4.1 Radiochromic dye film dose meters 22 4.2 Calorimetry 22 4.3 International dose by additional exposure to radiation or alkylating agents 28 #12;Page 5.4 it-reactivation in Acinetobacter. A description is given of work in the fields of irradiation technology, radiation chemistry, physical dosim

457

1996 worldwide refining survey  

Science Conference Proceedings (OSTI)

Data are presented on the capacity of refineries for the following processes: vacuum distillation, coking, catalytic cracking, catalytic reforming, catalytic hydrocracking, catalytic hydrorefining, and catalytic hydrotreating. Production capacities are also noted for alkylation, polymerization/dimerization, aromatics, isomerization, lubricants, oxygenates, hydrogen, coke, sulfur, and asphalts. Country totals are given, as well as the data for individual companies within each country, state, or province.

NONE

1996-12-23T23:59:59.000Z

458

Fractionation of reformate: A new variant of gasoline production technology  

Science Conference Proceedings (OSTI)

The Novo-Ufa Petroleum Refinery is the largest domestic producer of the unique high-octane unleaded automotive gasolines AI-93 and AI-95 and the aviation gasolines B-91/115 and B-92. The base component for these gasolines is obtained by catalytic reforming of wide-cut naphtha; this basic component is usually blended with certain other components that are expensive and in short supply: toluene, xylenes, and alkylate. For example, the unleaded gasoline AI-93 has been prepared by blending reformate, alkylate, and toluene in a 65:20:15 weight ratio; AI-95 gasoline by blending alkylate and xylenes in an 80:20 weight ratio; and B-91/115 gasoline by compounding a reformate obtained with light straight-run feed, plus alkylate and toluene, in a 55:35:10 weight ratio. Toluene and xylenes have been obtained by process schemes that include the following consecutive processes: redistillation of straight-run naphtha cuts to segregate the required narrow fraction; catalytic reforming (Platforming) of the narrow toluene-xylene straight-run fraction; azeotropic distillation of the reformate to recover toluene and xylenes. A new technology based on the use of reformate fractions is proposed.

Karakuts, V.N.; Tanatarov, M.A.; Telyashev, G.G. [and others

1995-07-01T23:59:59.000Z

459

Hydrocarbon Processing`s refining processes `96  

Science Conference Proceedings (OSTI)

The paper compiles information on the following refining processes: alkylation, benzene reduction, benzene saturation, catalytic cracking, catalytic reforming, coking, crude distillation, deasphalting, deep catalytic cracking, electrical desalting, ethers, fluid catalytic cracking, hydrocracking, hydrogenation, hydrotreating, isomerization, resid catalytic cracking, treating, and visbreaking. The application, products, a description of the process, yield, economics, installation, and licensor are given for each entry.

NONE

1996-11-01T23:59:59.000Z

460

Worldwide refining  

Science Conference Proceedings (OSTI)

The paper consists of several tables compiling data on refinery capacities by country, by state, and by company. The capacity data are given by process as well as by final product. Processes include vacuum distillation, thermal operations, catalytic cracking, catalytic reforming, catalytic hydrocracking, catalytic hydrorefining, and catalytic hydrotreating. Products include alkylates, polymers, and dimers; aromatics and isomers; oxygenates; hydrogen; asphalts; and coke.

Williamson, M.

1994-12-19T23:59:59.000Z

Note: This page contains sample records for the topic "mono alkyl ester" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Advanced control and information systems `97  

Science Conference Proceedings (OSTI)

Data are presented on advanced control and information systems, describing specific application, control strategy, economics, commercial installations, and licensor. Uses include alkylation, amine treating, catalytic reforming, cryogenic separation, catalytic cracking, hydrocracking, hydrogen production, LNG separation, lube oils, olefins, plant scheduling, polymers, refineries, steam reforming, and utilities.

NONE

1997-09-01T23:59:59.000Z

462

104 Royal Swedish Academy of Sciences 2001 Ambio Vol. 30 No. 2, March 2001 http://www.ambio.kva.se  

E-Print Network (OSTI)

gasoline easier. Russian refineries can run their catalytic reformers at full capacity while their through) using catalytic reforming alone (V. N. Styazhkin, Chief Engineer, Khabarovsk refinery, 1999, pers. comm gasoline usually re- quires petroleum refinery upgrades for construction of modern alkylation and catalytic

Thomas, Valerie

463

Worldwide refining  

Science Conference Proceedings (OSTI)

Data are presented on refining capacity by country and by company within each country. Capacity data are divided into the following processes: vacuum distillation, thermal operations, catalytic cracking, catalytic reforming, catalytic hydrocracking, catalytic hydrorefining, and catalytic hydrotreating. Production capacity is divided into: alkylation/polymerization/dimerization; aromatics/isomerization; lubricants; oxygenates; hydrogen; petroleum coke; and asphalts.

NONE

1995-12-18T23:59:59.000Z

464

Importance of Solubilizing Group and Backbone Planarity in Low Band Gap Polymers for High Performance Ambipolar field-effect Transistors  

Science Conference Proceedings (OSTI)

We investigated the performance of ambipolar field-effect transistors based on a series of alternating low band gap polymers of oligothiophene and diketopyrrolopyrrole (DPP). The polymers contain oligothiophene units of terthiophene [T3] and thiophene-thienothiophene-thiophene [T2TT] and DPP units carrying branched alkyl chains of 2-hexyldecyl [HD] or 2-octyldodecyl [OD]. The structural variation allows us to do a systematic study on the relationship between the interchain stacking/ordering of semiconducting polymers and their resulting device performance. On the basis of synchrotron X-ray diffraction and atomic force microscopy measurements on polymer films, we found that longer branched alkyl side chains, i.e., OD, and longer and more planar oligothiophene, i.e., T2TT, generate the more crystalline structures. Upon thermal annealing, the crystallinity of the polymers was largely improved, and polymers containing a longer branched alkyl chain responded faster because longer alkyl chains have larger cohesive forces than shorter chains. For all the polymers, excellent ambipolar behavior was observed with a maximum hole and electron mobility of 2.2 and 0.2 cm{sup 2} V{sup -1} s{sup -1}, respectively.

Lee, Joong Suk; Son, Seon Kyoung; Song, Sanghoon; Kim, Hyunjung; Lee, Dong Ryoul; Kim, Kyungkon; Ko, Min Jae; Choi, Dong Hoon; Kim, BongSoo; Cho, Jeong Ho (UST-Korea); (KUS); (Sungkyunkwan); (Soongsil U); (Sogang)

2012-06-13T23:59:59.000Z

465

Advances in Process Intensification through Multifunctional Reactor Engineering  

SciTech Connect

This project was designed to advance the art of process intensification leading to a new generation of multifunctional chemical reactors utilizing pulse flow. Experimental testing was performed in order to fully characterize the hydrodynamic operating regimes associated with pulse flow for implementation in commercial applications. Sandia National Laboratories (SNL) operated a pilot-scale multifunctional reactor experiment for operation with and investigation of pulse flow operation. Validation-quality data sets of the fluid dynamics, heat and mass transfer, and chemical kinetics were acquired and shared with Chemical Research and Licensing (CR&L). Experiments in a two-phase air-water system examined the effects of bead diameter in the packing, and viscosity. Pressure signals were used to detect pulsing. Three-phase experiments used immiscible organic and aqueous liquids, and air or nitrogen as the gas phase. Hydrodynamic studies of flow regimes and holdup were performed for different types of packing, and mass transfer measurements were performed for a woven packing. These studies substantiated the improvements in mass transfer anticipated for pulse flow in multifunctional reactors for the acid-catalyzed C4 paraffin/olefin alkylation process. CR&L developed packings for this alkylation process, utilizing their alkylation process pilot facilities in Pasadena, TX. These packings were evaluated in the pilot-scale multifunctional reactor experiments established by Sandia to develop a more fundamental understanding of their role in process intensification. Lummus utilized the alkylation technology developed by CR&L to design and optimize the full commercial process utilizing multifunctional reactors containing the packings developed by CR&L and evaluated by Sandia. This hydrodynamic information has been developed for multifunctional chemical reactors utilizing pulse flow, for the acid-catalyzed C4 paraffin/olefin alkylation process, and is now accessible for use in other technologies.

Timothy O’Hern, Lindsey Evans, Jim Miller, Marcia Cooper, John Torczynski, Donovan Pena, and Walt Gill, SNL, Will Groten, Arvids Judzis, Richard Foley, Larry Smith, and Will Cross, CR& L / CDTECH; T. Vogt, Lummus Technology / CDTECH.

2011-06-27T23:59:59.000Z

466

Advances in Process Intensification through Multifunctional Reactor Engineering  

SciTech Connect

This project was designed to advance the art of process intensification leading to a new generation of multifunctional chemical reactors utilizing pulse flow. Experimental testing was performed in order to fully characterize the hydrodynamic operating regimes associated with pulse flow for implementation in commercial applications. Sandia National Laboratories (SNL) operated a pilot-scale multifunctional reactor experiment for operation with and investigation of pulse flow operation. Validation-quality data sets of the fluid dynamics, heat and mass transfer, and chemical kinetics were acquired and shared with Chemical Research and Licensing (CR&L). Experiments in a two-phase air-water system examined the effects of bead diameter in the packing, and viscosity. Pressure signals were used to detect pulsing. Three-phase experiments used immiscible organic and aqueous liquids, and air or nitrogen as the gas phase. Hydrodynamic studies of flow regimes and holdup were performed for different types of packing, and mass transfer measurements were performed for a woven packing. These studies substantiated the improvements in mass transfer anticipated for pulse flow in multifunctional reactors for the acid-catalyzed C4 paraffin/olefin alkylation process. CR&L developed packings for this alkylation process, utilizing their alkylation process pilot facilities in Pasadena, TX. These packings were evaluated in the pilot-scale multifunctional reactor experiments established by Sandia to develop a more fundamental understanding of their role in process intensification. Lummus utilized the alkylation technology developed by CR&L to design and optimize the full commercial process utilizing multifunctional reactors containing the packings developed by CR&L and evaluated by Sandia. This hydrodynamic information has been developed for multifunctional chemical reactors utilizing pulse flow, for the acid-catalyzed C4 paraffin/olefin alkylation process, and is now accessible for use in other technologies.

Timothy O’Hern, Lindsey Evans, Jim Miller, Marcia Cooper, John Torczynski, Donovan Pena, and Walt Gill, SNL

2011-02-01T23:59:59.000Z

467

Manufacturing Science and Technology: Technologies  

NLE Websites -- All DOE Office Websites (Extended Search)

3 foot diameter cyanate ester / fiberglass laminated antenna 3 foot diameter cyanate ester / fiberglass laminated antenna 3 foot diameter cyanate ester / fiberglass laminated antenna Composites PDF format (145 kb) Polymer composite materials are composed of fibers in an organic matrix and can be useful in applications that require a high strength-to-weight ratio. Sandia's MS&T staff will work with you from part design, through mold and tooling design, and on through fabrication. The department is capable of fabricating small and large complex parts and will help you choose the most economical technique for your composite needs. Capabilities: The Center has a comprehensive program on the mechanical engineering design, tooling and fixturing, lay-out, complete processing of the composite structure, and technology transfer of composite structures for a

468

Detailed chemical kinetic mechanism for the oxidation of biodiesel fuels blend surrogate.  

DOE Green Energy (OSTI)

Detailed chemical kinetic mechanisms were developed and used to study the oxidation of two large unsaturated esters: methyl-5-decenoate and methyl-9-decenoate. These models were built from a previous methyl decanoate mechanism and were compared with rapeseed oil methyl esters oxidation experiments in a jet stirred reactor. A comparative study of the reactivity of these three oxygenated compounds was performed and the differences in the distribution of the products of the reaction were highlighted showing the influence of the presence and the position of a double bond in the chain. Blend surrogates, containing methyl decanoate, methyl-5-decenoate, methyl-9-decenoate and n-alkanes, were tested against rapeseed oil methyl esters and methyl palmitate/n-decane experiments. These surrogate models are realistic kinetic tools allowing the study of the combustion of biodiesel fuels in diesel and homogeneous charge compression ignition engines.

Herbinet, O; Pitz, W J; Westbrook, C K

2009-07-21T23:59:59.000Z

469

Advanced electrodialysis and pervaporation for fermentation-derived organic acids production.  

DOE Green Energy (OSTI)

Lactate esters produced from carbohydrate have potential markets as nontoxic replacements for halogenated and toxic solvents and as feedstocks for large-volume chemicals and polymers. Argonne National Laboratory has developed a novel process for the production of high-purity lactate esters from carbohydrate. The process uses advanced electrodialysis and pervaporation technologies to overcome major technical barriers in product separation; more specifically, the process involves cation elimination without the generation of salt waste and efficient esterification for final purification. This patented process requires little energy input, is highly efficient and selective, eliminates the large volumes of salt waste produced by conventional processes, and significantly reduces manufacturing costs. The enabling membrane separation technologies make it technically and commercially feasible for lactate esters to penetrate the potential markets.

Tsai, S. P.

1998-11-18T23:59:59.000Z

470

CX-002867: Categorical Exclusion Determination | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

7: Categorical Exclusion Determination 7: Categorical Exclusion Determination CX-002867: Categorical Exclusion Determination California-Tribe-Big Sandy Rancheria Band of Western Mono Indians CX(s) Applied: B2.5, B5.1 Date: 07/01/2010 Location(s): California Office(s): Energy Efficiency and Renewable Energy Energy Efficiency and Conservation Block Grant Program. The Big Sandy Rancheria Band of Western Mono Indians of California proposes to 1) replace old appliances with energy star appliances and 2) make energy efficiency retrofits/upgrades on several homes including insulation, siding and windows, and upgrading homes to increase their capacity to retain heated/cooled air. DOCUMENT(S) AVAILABLE FOR DOWNLOAD CX-002867.pdf More Documents & Publications CX-002789: Categorical Exclusion Determination

471

 

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

This determination is limited to conducting and analyzing an energy audit only. Subsequent activities may not be conducted with EECBG funds This determination is limited to conducting and analyzing an energy audit only. Subsequent activities may not be conducted with EECBG funds without additional environmental review by DOE. X - B5.1 Actions to conserve energy The Tribe proposes hire a certified energy professional to perform an energy audit on the Cold Springs Community Center. The information resulting from this audit would guide energy efficiency retrofit activities to be performed as a separately funded EECBG activity. Energy Efficiency and Conservation Block Grants Cold Springs Rancheria of Mono Indians Community Center Energy Efficiency Audit Cold Springs Rancheria of Mono Indians California Dec 14, 2009 Mary Martin Print Form for Records Submit via E-mail Billie Newland Digitally signed by Billie Newland

472

Property:Mooring Configuration | Open Energy Information  

Open Energy Info (EERE)

Mooring Configuration Mooring Configuration Jump to: navigation, search Property Name Mooring Configuration Property Type Text Pages using the property "Mooring Configuration" Showing 25 pages using this property. (previous 25) (next 25) M MHK Technologies/Aegir Dynamo + Gravity base with tension leg platform MHK Technologies/AirWEC + Single point slack moored MHK Technologies/Aquantis + Proprietary MHK Technologies/Atlantis AN 150 + mono pylon MHK Technologies/Atlantis AR 1000 + Site specific design mono pylon or gravity base structure The AR 1000 deployed at EMEC makes use of a GBS foundation MHK Technologies/Atlantis AS 400 + N A MHK Technologies/C Plane + Tethered MHK Technologies/CETO Wave Energy Technology + Anchored MHK Technologies/Centipod + Proprietary MHK Technologies/Current Electric Generator + The anchors for the Current Electric Generator will be made from concrete and will be a gravity base

473

Project 307  

NLE Websites -- All DOE Office Websites (Extended Search)

INTEGRATING MONO ETHANOL AMINE (MEA) INTEGRATING MONO ETHANOL AMINE (MEA) REGENERATION WITH CO 2 COMPRESSION AND PEAKING TO REDUCE CO 2 CAPTURE COSTS Background In Phase I, Trimeric Corporation, in collaboration with the University of Texas at Austin, performed engineering and economic analyses necessary to determine the feasibility of novel MEA processing schemes aimed at reducing the cost of CO 2 capture from flue gas. These novel MEA-based CO 2 capture schemes are designed for integration into coal-fired power plants with the aim of reducing costs and improving efficiency. Primary Project Goal The primary goal of this project was to reduce the cost of MEA scrubbing for the recovery of CO 2 from flue gas by improved process integration. CONTACTS Sean I. Plasynski Sequestration Technology Manager

474

Lanthanide-cyclodextrin complexes as probes for elucidating optical purity by NMR spectroscopy  

Science Conference Proceedings (OSTI)

A multidentate ligand is bonded to cyclodextrins by the reaction of diethylenetriaminepentaacetic dianhydride with 6-mono- and 2-mono(ethylenediamine) derivatives of cyclodextrin. Adding Dy(III) to the cyclodextrin derivatives enhances the enantiomeric resolution in the [sup 1]H NMR spectra of carbionoxamine maleate, doxylamine succinate, pheniramine maleate, propranolol hydrochloride, and tryptophan. The enhancement is more pronounced with the secondary derivative. The Dy(III)-induced shifts can be used to elucidate the geometry of cyclodextrin-substrate inclusion complexes. Lanthanide-induced shifts are reported for complexes of aspartame, tryptophan, propranolol, and 1-anilino-8-naphthalenesulfonate with cyclodextrins, and the relative magnitudes of the shifts agree with previously reported structures of the complexes. 37 refs., 9 figs., 5 tabs.

Wenzel, T.J.; Bogyo, M.S.; Lebeau, E.L. (Bates College, Lewiston, ME (United States))

1994-06-01T23:59:59.000Z

475

Method for cleaning solution used in nuclear-fuel reprocessing. [DOE patent application  

DOE Patents (OSTI)

A nuclear fuel processing solution containing: (1) hydrocarbon diluent; (2) tri-n-butyl phosphate or tri-2-ethylhexyl phosphate; and (3) monobutyl phosphate, dibutyl phosphate, mono-2-ethylhexyl phosphate, di-2-ethylhexyl phosphate, or a complex formed by plutonium, uranium, or a fission product thereof with monobutyl phosphate, dibutyl phosphate, mono-2-ethylhexyl phosphate, or di-2-ethylhexyl phosphate is contacted with silica gel having alkali ions absorbed thereon to remove any degradation products from said solution. The principal impurities removed from TBP solvent by the process of this invention are monobutyl phosphate, dibutyl phosphate, UO/sub 2//sup 2 +/, Pu/sup 4 +/, and fission products of plutonium and uranium complexed with monobutyl phosphate or dibutyl phosphate. Nitric acid is also removed from the TBP solution by the treated silica gel. Conventional adsorption column techniques are applicable for the process of the invention.

Tallent, O.K.; Dodson, K.E.; Mailen, J.C.

1981-05-12T23:59:59.000Z

476

Trapping and diffusion of fission products in ThO2 and CeO2  

Science Conference Proceedings (OSTI)

The trapping and diffusion of Br, Rb, Cs and Xe in ThO2 and CeO{sub 2} have been studied using an Ab Initio total energy method in the local-density approximation of density functional theory. Fission products incorporated in cation mono-vacancy, cation-anion di-vacancy and Schottky defect sites are found to be stable, with the cation mono-vacancy being the preferred site in most cases. In both oxides, Rb and Cs are the most likely to be trapped, and Xe is more difficult to incorporate than other fission products. The energy barriers for migration of each species in ThO{sub 2} and CeO{sub 2} are also calculated. Alkali metals are relatively more mobile than other fission products, and bromine is the least mobile.

Xiao, Haiyan [University of Tennessee, Knoxville (UTK); Zhang, Yanwen [ORNL; Weber, William J [ORNL

2011-01-01T23:59:59.000Z

477

Signature Metabolites at Manufactured Gas Plant Sites  

Science Conference Proceedings (OSTI)

This report presents results of research to demonstrate the biodegradation component of natural attenuation at former manufactured gas plant (MGP) sites. Researchers developed a target compound list of signature metabolites, biochemical intermediates of mono- and polycyclic aromatic hydrocarbon (MAH and PAH) biodegradation. They identified and tested appropriate methods of chemical analysis for these metabolites in MGP groundwater and sediments. Emphasis was placed on identifying natural microbiological ...

2008-10-14T23:59:59.000Z

478

Experimental co-digestion of corn stalk and vermicompost to improve biogas production  

SciTech Connect

Anaerobic co-digestion of corn stalk and vermicompost (VC) as well as mono-digestion of corn stalk were investigated. Batch mono-digestion experiments were performed at 35 {+-} 1 {sup o}C and initial total solid loading (TSL) ranged from 1.2% to 6.0%. Batch co-digestion experiments were performed at 35 {+-} 1 {sup o}C and initial TSL of 6% with VC proportions ranged from 20% to 80% of total solid (TS). For mono-digestion of corn stalk, a maximum methane yield of 217.60 {+-} 13.87 mL/g TS{sub added} was obtained at initial TSL of 4.8%, and acidification was found at initial TSL of 6.0% with the lowest pH value of 5.10 on day 4. Co-digestion improved the methane yields by 4.42-58.61% via enhancing volatile fatty acids (VFAs) concentration and pH value compared with mono-digestion of corn stalk. The maximum biogas yield of 410.30 {+-} 11.01 mL/g TS{sub added} and methane yield of 259.35 {+-} 13.85 mL/g TS{sub added} were obtained for 40% VC addition. Structure analysis by X-ray diffractometry (XRD) showed that the lowest crystallinity of 35.04 of digested corn stalk was obtained from co-digestion with 40% VC, which decreased 29.4% compared to 49.6 obtained from un-treated corn stalk. It is concluded that co-digestion with VC is beneficial for improving biodigestibility and methane yield from corn stalk.

Chen Guangyin [State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing 210093 (China); Zheng Zheng, E-mail: zzhenghj@fudan.edu.c [State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing 210093 (China); Department of Environmental Science and Engineering, Fudan University, Shanghai 200433 (China); Yang Shiguan [National Engineering Laboratory of Biomass Power Generation Equipment, School of Renewable Energy, North China Electric Power University, Beijing 102206 (China); Fang Caixia; Zou Xingxing; Luo Yan [State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing 210093 (China)

2010-10-15T23:59:59.000Z

479

DotDFS: A Grid-based high-throughput file transfer system  

Science Conference Proceedings (OSTI)

DotGrid platform is a Grid infrastructure integrated with a set of open and standard protocols recently implemented on the top of Microsoft .NET in Windows and MONO .NET in UNIX/Linux. DotGrid infrastructure along with its proposed protocols provides ... Keywords: Concurrent systems, Data grids, Event-driven architecture, File transfer protocols, Grid computing, Grid security, High throughput file transfer, Modeling parallel TCP throughput

Alireza Poshtkohi; M. B. Ghaznavi-Ghoushchi

2011-02-01T23:59:59.000Z

480

Adiposity measures and risk of cardiovascular disease  

E-Print Network (OSTI)

ratio PAI Plasminogen activator inhibitor PHS Physicians' Health Study PROMIS Pakistan Risk of Myocardial Infarction Study PSC Prospective Studies Collaboration RDR Regression dilution ratio ROS Reactive oxygen species RR Risk ratio SBP Systolic... the arterial wall where they are oxidised by macrophages and smooth muscle cells. Additional mono-nuclear cells such as monocytes are attracted to the site of damage, where they engulf LDL cholesterol and become foam cells.10,13,14 Accumulation of foam cells...

Wormser, David

2012-01-10T23:59:59.000Z

Note: This page contains sample records for the topic "mono alkyl ester" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

An investigation of two homologous series of carboxylic acids in Black Trona Water from the Green River Basin  

SciTech Connect

Two series of carboxylic acids were identified in the dialysate from a sample of Black Trona Water from the Green River Basin of Wyoming. One of the series consists of straight-chain dicarboxylic acids ranging in carbon number from four to fourteen. This series had been observed by previous workers. The other series, much less abundant than the dicarboxylic acids, appears to be a series of homologous tricarboxylic acids that are derivatives of succinic acid. The structures of these compounds were determined by analysis of the mass spectra of their methyl esters and trideuteromethyl esters. Definitive biological precursors of this unusual class of compounds could not be assigned.

Branthaver, J.F.; Thomas, K.P.; Logan, E.R.; Barden, R.E.

1988-01-01T23:59:59.000Z

482

Oxidation Potentials of Functionalized Sulfone Solvents for High-Voltage Li-Ion Batteries: A Computational Study  

Science Conference Proceedings (OSTI)

New electrolytes with large electrochemical windows are needed to meet the challenge for high-voltage Li-ion batteries. Sulfone as an electrolyte solvent boasts of high oxidation potentials. Here we examine the effect of multiple functionalization on sulfone's oxidation potential. We compute oxidation potentials for a series of sulfone-based molecules functionalized with fluorine, cyano, ester, and carbonate groups by using a quantum chemistry method within a continuum solvation model. We find that multifunctionalization is a key to achieving high oxidation potentials. This can be realized through either a fluorether group on a sulfone molecule or sulfonyl fluoride with a cyano or ester group.

Shao, Nan [ORNL; Sun, Xiao-Guang [ORNL; Dai, Sheng [ORNL; Jiang, Deen [ORNL

2012-01-01T23:59:59.000Z

483

In-situ stabilization of radioactive zirconium swarf  

DOE Patents (OSTI)

The method for treating ignitable cutting swarf in accordance with the present invention involves collecting cutting swarf in a casting mold underwater and injecting a binder mixture comprising vinyl ester styrene into the vessel to fill void volume; and form a mixture comprising swarf and vinyl ester styrene; and curing the mixture. The method is especially useful for stabilizing the ignitable characteristics of radioactive zirconium cutting swarf, and can be used to solidify zirconium swarf, or other ignitable finely divided material, underwater. The process could also be performed out of water with other particulate wastes. 6 figs.

Hess, C.C.

1999-08-31T23:59:59.000Z

484

In-situ stabilization of radioactive zirconium swarf  

DOE Patents (OSTI)

The method for treating ignitable cutting swarf in accordance with the present invention involves collecting cutting swarf in a casting mold underwater and injecting a binder mixture comprising vinyl ester styrene into the vessel to fill void volume; and form a mixture comprising swarf and vinyl ester styrene; and curing the mixture. The method is especially useful for stabilizing the ignitable characteristics of radioactive zirconium cutting swarf, and can be used to solidify zirconium swarf, or other ignitable finely divided material, underwater. The process could also be performed out of water with other particulate wastes.

Hess, Clay C. (Idaho Falls, ID)

1999-01-01T23:59:59.000Z

485

In-situ stabilization of radioactive zirconium swarf  

DOE Patents (OSTI)

The method for treating ignitable cutting swarf in accordance with the present invention involves collecting cutting swarf in a casting mold underwater and injecting a binder mixture comprising vinyl ester styrene into the vessel to fill void volume; and form a mixture comprising swarf and vinyl ester styrene; and curing the mixture. The method is especially useful for stabilizing the ignitable characteristics of radioactive zirconium cutting swarf, and can be used to solidify zirconium swarf, or other ignitable finely divided material, underwater. The process could also be performed out of water with other particulate wastes.

Hess, Clay C.

1997-12-01T23:59:59.000Z

486

Tfe3 expression is closely associated to macrophage terminal differentiation of human hematopoietic myeloid precursors  

SciTech Connect

The MItf-Tfe family of basic helix-loop-helix leucine zipper (bHLH-Zip) transcription factors encodes four family members: MItf, Tfe3, TfeB and TfeC. In vitro, each protein of the family binds DNA in a homo- or heterodimeric form with other family members. Tfe3 is involved in chromosomal translocations recurrent in different tumors and it has been demonstrated, by in vivo studies, that it plays, redundantly with MItf, an important role in the process of osteoclast formation, in particular during the transition from mono-nucleated to multi-nucleated osteoclasts. Since mono-nucleated osteoclasts derive from macrophages we investigated whether Tfe3 might play a role upstream during hematopoietic differentiation. Here we show that Tfe3 is able to induce mono-macrophagic differentiation of U937 cells, in association with a decrease of cell proliferation and an increase of apoptosis. We also show that Tfe3 does not act physiologically during commitment of CD34+ hematopoietic stem cells (HSCs), since it is not able to direct HSCs toward a specific lineage as observed by clonogenic assay, but is a strong actor of terminal differentiation since it allows human primary myeloblasts' maturation toward the macrophage lineage.

Zanocco-Marani, Tommaso [Dipartimento di Scienze Biomediche, Sezione di Chimica Biologica, Universita di Modena e Reggio Emilia, Via Campi 287, 41100, Modena (Italy); Vignudelli, Tatiana [Dipartimento di Scienze Biomediche, Sezione di Chimica Biologica, Universita di Modena e Reggio Emilia, Via Campi 287, 41100, Modena (Italy); Gemelli, Claudia [Dipartimento di Scienze Biomediche, Sezione di Chimica Biologica, Universita di Modena e Reggio Emilia, Via Campi 287, 41100, Modena (Italy); Pirondi, Sara [Dipartimento di Scienze Biomediche, Sezione di Chimica Biologica, Universita di Modena e Reggio Emilia, Via Campi 287, 41100, Modena (Italy); Testa, Anna [Dipartimento di Scienze Biomediche, Sezione di Chimica Biologica, Universita di Modena e Reggio Emilia, Via Campi 287, 41100, Modena (Italy); Montanari, Monica [Dipartimento di Scienze Biomediche, Sezione di Chimica Biologica, Universita di Modena e Reggio Emilia, Via Campi 287, 41100, Modena (Italy); Parenti, Sandra [Dipartimento di Scienze Biomediche, Sezione di Chimica Biologica, Universita di Modena e Reggio Emilia, Via Campi 287, 41100, Modena (Italy); Tenedini, Elena [Dipartimento di Scienze Biomediche, Sezione di Chimica Biologica, Universita di Modena e Reggio Emilia, Via Campi 287, 41100, Modena (Italy); Grande, Alexis [Dipartimento di Scienze Biomediche, Sezione di Chimica Biologica, Universita di Modena e Reggio Emilia, Via Campi 287, 41100, Modena (Italy); Ferrari, Sergio [Dipartimento di Scienze Biomediche, Sezione di Chimica Biologica, Universita di Modena e Reggio Emilia, Via Campi 287, 41100, Modena (Italy)]. E-mail: sergio@unimo.it

2006-12-10T23:59:59.000Z

487

Protein Bridges DNA Base and Nucleotide Excision Repair Pathways  

NLE Websites -- All DOE Office Websites (Extended Search)

Protein Bridges DNA Base and Nucleotide Excision Repair Pathways Print Protein Bridges DNA Base and Nucleotide Excision Repair Pathways Print Alkyltransferase proteins (AGT) protect cells from the biological effects of DNA damage caused by the addition of alkyl groups (alkylation). Alkyltransferase-like proteins (ATLs) can do the same, but they lack the reactive cysteine residue that allows the alkyltransferase function, and the mechanism for cell protection has remained unknown. To address this mystery, a British-American team lead by researchers at the Scripps Research Institute recently applied a combination of x-ray structural, biochemical, and genetic studies to ATLs in the yeast Schizosaccharomyces pombe without and with damaged DNA. By showing how a process called non-enzymatic nucleotide flipping activates ATL-initiated DNA repair, their results may improve our understanding of genomic integrity and responses to DNA damage relevant to pathogens and cancer development.

488

Protein Bridges DNA Base and Nucleotide Excision Repair Pathways  

NLE Websites -- All DOE Office Websites (Extended Search)

Protein Bridges DNA Base and Nucleotide Excision Repair Pathways Print Protein Bridges DNA Base and Nucleotide Excision Repair Pathways Print Alkyltransferase proteins (AGT) protect cells from the biological effects of DNA damage caused by the addition of alkyl groups (alkylation). Alkyltransferase-like proteins (ATLs) can do the same, but they lack the reactive cysteine residue that allows the alkyltransferase function, and the mechanism for cell protection has remained unknown. To address this mystery, a British-American team lead by researchers at the Scripps Research Institute recently applied a combination of x-ray structural, biochemical, and genetic studies to ATLs in the yeast Schizosaccharomyces pombe without and with damaged DNA. By showing how a process called non-enzymatic nucleotide flipping activates ATL-initiated DNA repair, their results may improve our understanding of genomic integrity and responses to DNA damage relevant to pathogens and cancer development.

489

Protein Bridges DNA Base and Nucleotide Excision Repair Pathways  

NLE Websites -- All DOE Office Websites (Extended Search)

Protein Bridges DNA Base and Nucleotide Excision Repair Pathways Print Protein Bridges DNA Base and Nucleotide Excision Repair Pathways Print Alkyltransferase proteins (AGT) protect cells from the biological effects of DNA damage caused by the addition of alkyl groups (alkylation). Alkyltransferase-like proteins (ATLs) can do the same, but they lack the reactive cysteine residue that allows the alkyltransferase function, and the mechanism for cell protection has remained unknown. To address this mystery, a British-American team lead by researchers at the Scripps Research Institute recently applied a combination of x-ray structural, biochemical, and genetic studies to ATLs in the yeast Schizosaccharomyces pombe without and with damaged DNA. By showing how a process called non-enzymatic nucleotide flipping activates ATL-initiated DNA repair, their results may improve our understanding of genomic integrity and responses to DNA damage relevant to pathogens and cancer development.

490

Method for extracting lanthanides and actinides from acid solutions by modification of Purex solvent  

DOE Patents (OSTI)

A process is described for the recovery of actinide and lanthanide values from aqueous solutions with an extraction solution containing an organic extractant having the formula as shown in a diagram where [phi] is phenyl, R[sup 1] is a straight or branched alkyl or alkoxyalkyl containing from 6 to 12 carbon atoms and R[sup 2] is an alkyl containing from 3 to 6 carbon atoms and phase modifiers in a water-immiscible hydrocarbon diluent. The addition of the extractant to the Purex process extractant, tri-n-butylphosphate in normal paraffin hydrocarbon diluent, will permit the extraction of multivalent lanthanide and actinide values from 0.1 to 12.0 molar acid solutions. 6 figs.

Horwitz, E.P.; Kalina, D.G.

1986-03-04T23:59:59.000Z

491

Regeneration of Polyborzaylene  

NLE Websites -- All DOE Office Websites (Extended Search)

Regeneration of Polyborzaylene Regeneration of Polyborzaylene Regeneration of Polyborzaylene Method of producing ammonia borane, comprising providing polyborazylene; digesting the polyborazylene with a dithiol-containing agent to produce a boro-sulfide compound and a byproduct; converting the byproduct to the boro-sulfide product of step (b) by reaction with a first alkyl-tin hydride; and, converting the boro-sulfide compound produced in steps (b) and (c) to ammonia borane by reaction with a second alkyl-tin hydride. Available for thumbnail of Feynman Center (505) 665-9090 Email Regeneration of Polyborzaylene Method of producing ammonia borane, comprising providing polyborazylene; digesting the polyborazylene with a dithiol-containing agent to produce a boro-sulfide compound and a byproduct; converting the byproduct to the

492

Workbook Contents  

U.S. Energy Information Administration (EIA) Indexed Site

Alkylate " Alkylate " ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","U.S., PAD Districts, and States",46,"Annual",2013,"6/30/1982" ,"Data 2","U.S. Territories (not included in U.S. Total)",3,"Annual",2013,"6/30/1982" ,"Release Date:","6/21/2013" ,"Next Release Date:","6/20/2014" ,"Excel File Name:","pet_pnp_capprod_a_(na)_8pa_bsd_a.xls" ,"Available from Web Page:","http://www.eia.gov/dnav/pet/pet_pnp_capprod_a_(na)_8pa_bsd_a.htm" ,"Source:","Energy Information Administration"

493

Protein Bridges DNA Base and Nucleotide Excision Repair Pathways  

NLE Websites -- All DOE Office Websites (Extended Search)

Protein Bridges DNA Base and Protein Bridges DNA Base and Nucleotide Excision Repair Pathways Protein Bridges DNA Base and Nucleotide Excision Repair Pathways Print Wednesday, 28 October 2009 00:00 Alkyltransferase proteins (AGT) protect cells from the biological effects of DNA damage caused by the addition of alkyl groups (alkylation). Alkyltransferase-like proteins (ATLs) can do the same, but they lack the reactive cysteine residue that allows the alkyltransferase function, and the mechanism for cell protection has remained unknown. To address this mystery, a British-American team lead by researchers at the Scripps Research Institute recently applied a combination of x-ray structural, biochemical, and genetic studies to ATLs in the yeast Schizosaccharomyces pombe without and with damaged DNA. By showing how a process called non-enzymatic nucleotide flipping activates ATL-initiated DNA repair, their results may improve our understanding of genomic integrity and responses to DNA damage relevant to pathogens and cancer development.

494

Comb-shaped single ion conductors based on polyacrylate ethers and lithium  

NLE Websites -- All DOE Office Websites (Extended Search)

Comb-shaped single ion conductors based on polyacrylate ethers and lithium Comb-shaped single ion conductors based on polyacrylate ethers and lithium alkyl sulfonate Title Comb-shaped single ion conductors based on polyacrylate ethers and lithium alkyl sulfonate Publication Type Journal Article Year of Publication 2005 Authors Sun, Xiao-Guang, Jun Hou, and John B. Kerr Journal Electrochimica Acta Volume 50 Pagination 1139-1147 Keywords ionic conductivity, plasticizer, polyacrylate ethers, single ion conductor Abstract Comb-shaped single ion conductors have been synthesized by sulfonation of small molecule chloroethyleneglycols, which, after ion exchange to the Li+ salt were then converted to the acrylate by reaction with acryloyl chloride and copolymerized with polyethylene glycol monomethyl ether acrylate (Mn = 454, n = 8) (PAE8-co-E3SO3Li);

495

Aqueous foam surfactants for geothermal drilling fluids: 1. Screening  

DOE Green Energy (OSTI)

Aqueous foam is a promising drilling fluid for geothermal wells because it will minimize damage to the producing formation and would eliminate the erosion problems of air drilling. Successful use of aqueous foam will require a high foaming surfactant which will: (1) be chemically stable in the harsh thermal and chemical environment, and (2) form stable foams at high temperatures and pressures. The procedures developed to generate and test aqueous foams and the effects of a 260/sup 0/C temperature cycle on aqueous surfactant solutions are presented. More than fifty selected surfactants were evaluated with representatives from the amphoteric, anionic, cationic, and nonionic classes included. Most surfactants were severely degraded by this temperature cycle; however, some showed excellent retention of their properties. The most promising surfactant types were the alkyl and alkyl aryl sulfonates and the ethoxylated nonionics.

Rand, P.B.

1980-01-01T23:59:59.000Z

496

ION EXCHANGE SUBSTANCES BY SAPONIFICATION OF ALLYL PHOSPHATE POLYMERS  

DOE Patents (OSTI)

An ion exchange resin having a relatively high adsorption capacity tor uranyl ion as compared with many common cations is reported. The resin comprises an alphyl-allyl hydrogen phosphate polymer, the alphyl group being either allyl or a lower alkyl group having up to 5 carbon atoins. The resin is prepared by polymerizing compounds such as alkyl-diallyl phosphate and triallyl phosphate in the presence of a free radical generating substance and then partially hydrolyzing the resulting polymer to cause partial replacement of organic radicals by cations. A preferred free radical gencrating agent is dibenzoyl peroxide. The partial hydrolysis is brought about by refluxing the polymer with concentrated aqueous NaOH for three or four hours.

Kennedy, J.

1959-04-14T23:59:59.000Z

497

Method for extracting lanthanides and actinides from acid solutions by modification of purex solvent  

SciTech Connect

A process for the recovery of actinide and lanthanide values from aqueous solutions with an extraction solution containing an organic extractant having the formula: ##STR1## where .phi. is phenyl, R.sup.1 is a straight or branched alkyl or alkoxyalkyl containing from 6 to 12 carbon atoms and R.sup.2 is an alkyl containing from 3 to 6 carbon atoms and phase modifiers in a water-immiscible hydrocarbon diluent. The addition of the extractant to the Purex process extractant, tri-n-butylphosphate in normal paraffin hydrocarbon diluent, will permit the extraction of multivalent lanthanide and actinide values from 0.1 to 12.0 molar acid solutions.

Horwitz, E. Philip (Naperville, IL); Kalina, Dale G. (Naperville, IL)

1986-01-01T23:59:59.000Z

498

Characterization of carbonaceous materials using extraction with supercritical pentane  

Science Conference Proceedings (OSTI)

The use of carbonaceous adsorbents is limited by irreversible adsorption of some compounds so the use of supercritical pentane as an extracting solvent was examined. Carbon black appeared to be broken down slowly, but continuously, by the penane. To see if other types of carbon behaved similarly, high purity graphite, technical grade graphites, active carbons, and charcoals were examined. The extracts were characterized by uv spectroscopy, packed column chromatography using flame ionization and flame photometric detectors, and capillary GC/MS. The extracts were characteristic for each class of carbonaceous material. The high purity graphite yielded large, polycyclic aromatic compounds; the technical grade graphites yielded alkanes and alkyl-substituted benzenes and naphthalenes; the active carbons yielded alkanes, dienes, and small amounts of alkyl-substituted benzenes; and the charcoals yielded almost entirely alkanes in small amounts.

Fetzer, J.C.; Graham, J.A.; Arrendale, R.R.; Klee, M.S.; Rogers, L.B.

1980-05-30T23:59:59.000Z

499

Selection of best neural network for estimating properties of diesel-biodiesel blends  

Science Conference Proceedings (OSTI)

Soybean oil was transesterified with methanol in the presence of alkaline catalyst to produce methyl esters commonly known as biodiesel. Biodiesel and diesel blends were prepared and tested in laboratory for flash point, fire point, viscosity and density. ... Keywords: artificial neural network, biodiesel, density, fire point, flash point, transesterification, viscosity

Jatinder Kumar; Ajay Bansal

2007-02-01T23:59:59.000Z

500

Methodology Formation Mitigation of Process Contaminants (3-MCPD)  

Science Conference Proceedings (OSTI)

3-MCPD (3-Monochloropropane-1,2-diol )Methodology,Formation,and Mitigation reference papers. Methodology Formation Mitigation of Process Contaminants (3-MCPD) 3-MCPD 2-diol 3-MCPD 3-MCPD Esters 3-monochloropropane-1 acid analysis aocs april articles cert