National Library of Energy BETA

Sample records for monazite sand ce

  1. PROCESSING OF MONAZITE SAND

    DOE Patents [OSTI]

    Calkins, G.D.; Bohlmann, E.G.

    1957-12-01

    A process for the recovery of thorium, uranium, and rare earths from monazite sands is presented. The sands are first digested and dissolved in concentrated NaOH, and the solution is then diluted causing precipitation of uranium, thorium and rare earth hydroxides. The precipitate is collected and dissolved in HCl, and the pH of this solution is adjusted to about 6, precipitating the hydroxides of thorium and uranium but leaving the rare earths in solution. The rare earths are then separated from the solution by precipitation at a still higher pH. The thorium and uranium containing precipitate is redissolved in HNO/sub 3/ and the two elements are separated by extraction into tributyl phosphate and back extraction with a weakly acidic solution to remove the thorium.

  2. METHOD OF PROCESSING MONAZITE SAND

    DOE Patents [OSTI]

    Welt, M.A.; Smutz, M.

    1958-08-26

    A process is described for recovering thorium, uranium, and rare earth values from monazite sand. The monazite sand is first digested with sulfuric acid and the resulting "monazite sulfate" solution is adjusted to a pH of between 0.4 and 3.0, and oxalate anions are added causing precipitation of the thorium and the rare earths as the oxalates. The oxalate precipitate is separated from the uranium containing supernatant solution, and is dried and calcined to the oxides. The thorium and rare earth oxides are then dissolved in nitric acid and the solution is contacted with tribntyl phosphate whereby an organic extract phase containing the cerium and thorium values is obtained, together with an aqueous raffinate containing the other rare earth values. The organic phase is then separated from the aqueous raffinate and the cerium and thorium are back extracted with an aqueous medium.

  3. METHOD OF PROCESSING MONAZITE SAND

    DOE Patents [OSTI]

    Calkins, G.D.

    1957-10-29

    A method is given for the pretreatment of monazite sand with sodium hydroxide. When momazite sand is reacted with sodium hydroxide, the thorium, uranium, and rare earths are converted to water-insoluble hydrous oxides; but in the case of uranium, the precipitate compound may at least partly consist of a slightly soluble uranate. According to the patent, monazite sand is treated with an excess of aqueous sodium hydroxide solution, and the insoluble compounds of thorium, uranium, and the rare earths are separated from the aqueous solution. This solution is then concentrated causing sodium phosphate to crystallize out. The crystals are removed from the remaining solution, and the solution is recycled for reaction with a mew supply of momazite sand.

  4. Phase transition and possible metallization in CeVO{sub 4} under pressure

    SciTech Connect (OSTI)

    Garg, Alka B.; Shanavas, K.V.; Wani, B.N.; Sharma, Surinder M.

    2013-07-15

    Phase stability of CeVO{sub 4} under pressure has been investigated using synchrotron based angle dispersive x-ray diffraction (ADXRD), electrical resistance and first principles calculations. The results indicate that the ambient zircon structure of the compound transforms to a low symmetry monoclinic monazite phase beyond 3.8 GPa with nearly 8.6% volume discontinuity. Beyond 11 GPa, the pattern could be fitted to a similar monazite structure which is about 12.7% denser and has a much larger monoclinic beta angle. On pressure release the first monoclinic phase is recovered. The electrical resistance data show a large drop in resistance with pressure indicating substantial narrowing down of the band gap. Electronic structure calculations support these observations and suggest possible pressure induced metallization in this material. - Pressure induced structural phase transition in CeVO{sub 4} as observed by x- ray diffraction (pressure vs. volume) and possible metallization in CeVO{sub 4} through electrical resistance and first principles electronic structure calculations. - Highlights: Structural and electrical behavior of CeVO{sub 4} under pressure studied using x-ray diffraction and electrical resistance measurements and first principles calculations. Two successive structural transitions confirmed by experiment and theory: zirconmonazite Imonazite II. Band gap collapse and possible metallization is indicated by electrical resistance measurements and electronic structure calculations under pressure. Novel observation of lower bulk modulus in the high pressure phase (both by experiment and calculations) explained through structural analysis.

  5. SAND78-1735

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    printing a copy of any digitized SAND Report, you are required to update the markings to current standards. SAND 78-1735 Unlimited Release Printed February 1979 SOME VARIABILITY ...

  6. SAND2010-3950C

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    is SAND2010-3950C. SAND2010-3950C Outline Outline * Performance Assessment methodology * Defining modeling objectives * Conceptual model development * Interface with site...

  7. Basaltic island sand provenance

    SciTech Connect (OSTI)

    Marsaglia, K.M. . Dept. of Geological Sciences)

    1992-01-01

    The Hawaiian Islands are an ideal location to study basaltic sand provenance in that they are a series of progressively older basaltic shield volcanoes with arid to humid microclimates. Sixty-two sand samples were collected from beaches on the islands of Hawaii, Maui, Oahu and Kauai and petrographically analyzed. The major sand components are calcareous bioclasts, volcanic lithic fragments, and monomineralic grains of dense minerals and plagioclase. Proportions of these components vary from island to island, with bioclastic end members being more prevalent on older islands exhibiting well-developed fringing reef systems and volcanic end members more prevalent on younger, volcanically active islands. Climatic variations across the island of Hawaii are reflected in the percentage of weathered detritus, which is greater on the wetter, northern side of the island. The groundmass of glassy, basaltic lithics is predominantly black tachylite, with lesser brown sideromelane; microlitic and lathwork textures are more common than holohyaline vitric textures. Other common basaltic volcanic lithic fragments are holocrystalline aggregates of silt-sized pyroxene or olivine, opaque minerals and plagioclase. Sands derived from alkalic lavas are texturally and compositionally indistinguishable from sands derived from tholeiitic lavas. Although Hawaiian basaltic sands overlap in composition with magmatic arc-derived sands in terms of their relative QFL, QmPK and LmLvLs percentages, they are dissimilar in that they lack felsic components and are more enriched in lathwork volcanic lithic fragments, holocrystalline volcanic lithic fragments, and dense minerals.

  8. SAND2008-2008

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SAND2008-2008 Unlimited Release Printed April 2008 Flatback Airfoil Wind Tunnel Experiment Jonathon P. Baker, C.P. "Case" van Dam, and Benson L. Gilbert Department of Mechanical ...

  9. SAND2009-2993

    Office of Scientific and Technical Information (OSTI)

    SAND2009-2993 Unlimited Release Printed May 2009 Radar Cross Section of Triangular Trihedral Reflector with Extended Bottom Plate Armin W. Doerry and Billy C. Brock Prepared by...

  10. Hydrocarbon rims on monazite in Permian-Triassic arenites, northern Perth Basin, Western Australia: Pointers to the former presence of oil

    SciTech Connect (OSTI)

    Rasmussen, B.; Glover, J.E. ); Alexander, R. )

    1989-02-01

    Black opaque hydrocarbon rims about 0.05 mm thick are preserved around detrital monazite grains in Permian-Triassic arenites of the norther Perth Basin, Western Australia. Chromatographic analysis indicates derivation from oil chemically like that elsewhere in the sequence, and the rims seem to be remnants of oil, which was largely flushed away. The hydrocarbon rims may have adhered to the monazite grains because of irradiation; they are not found on other grains. Monazite-rich heavy mineral bands are probably responsible for abnormally high radioactivity recorded locally by gamma-ray logs in wells penetrating the sandstones. A preliminary search has revealed similar rims around monazite in other Western Australian arenites ranging in age from Silurian to Cretaceous. Thin-section examination of heavy mineral concentrations may therefore be a useful, simple technique to indicate the former presence of hydrocarbons in dry arenites.

  11. CE Geothermal | Open Energy Information

    Open Energy Info (EERE)

    Geothermal Jump to: navigation, search Name: CE Geothermal Place: California Sector: Geothermal energy Product: CE Geothermal previously owned the assets of Western States...

  12. SAND92-7293

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CONTRACTOR REPORT SAND92-7293 Unlimited Release UC-235 Wind Effects on Convective Heat Loss From a Cavity Receiver for a Parabolic Concentrating Solar Collector Robert Y. Ma Department of Mechanical Engineering California State Polytechnic University Pomoma, CA 91768 Prepared by Sandia National Laboratories Albuquerque, New Mexico 87185 and Livermore, California 94550 for the United States Department of Energy under Contract DE-AC04-76DP00789 SANDIA NATIONAL LABORATORIES TECHNICAL LIBRARY

  13. SAND94-1057

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    c.1 CONTRACTOR REPORT SAND94- 1057 Unlimited Release UC-276 The Interconnection of Photovoltaic Power Systems with the Utility Grid: An Overview for Utility Engineers Dr. Robert H. Wills, P.E. Principal Electrical Engineer Solar Design Associates, Inc. Architects and Engineers Harvard, MA Prepared by Sandia National Laboratories Albuquerque, New Mexico 87185 and Livermore, California 94550 for the United States Department of Energy under Contract DE-AC04-94AL85000 Printed June 1994 Approved for

  14. Compressive behavior of fine sand.

    SciTech Connect (OSTI)

    Martin, Bradley E.; Kabir, Md. E.; Song, Bo; Chen, Wayne

    2010-04-01

    The compressive mechanical response of fine sand is experimentally investigated. The strain rate, initial density, stress state, and moisture level are systematically varied. A Kolsky bar was modified to obtain uniaxial and triaxial compressive response at high strain rates. A controlled loading pulse allows the specimen to acquire stress equilibrium and constant strain-rates. The results show that the compressive response of the fine sand is not sensitive to strain rate under the loading conditions in this study, but significantly dependent on the moisture content, initial density and lateral confinement. Partially saturated sand is more compliant than dry sand. Similar trends were reported in the quasi-static regime for experiments conducted at comparable specimen conditions. The sand becomes stiffer as initial density and/or confinement pressure increases. The sand particle size become smaller after hydrostatic pressure and further smaller after dynamic axial loading.

  15. Sand Mountain Electric Coop | Open Energy Information

    Open Energy Info (EERE)

    Sand Mountain Electric Coop Jump to: navigation, search Name: Sand Mountain Electric Coop Place: Alabama Phone Number: Rainsville Area: 256---638---2153; Henagar Area:...

  16. SAND2012-8323P

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    FUEL-ASSEMBLY SHAKER TEST PLAN Tests for Determining Loads on Used Nuclear Fuel under ... SAND2012-8323P Fuel Assembly Shaker Test ii September 2012 Sandia National ...

  17. Tar Sands | Open Energy Information

    Open Energy Info (EERE)

    jobs are considered, an even larger job growth number is found. The net value of oil sands rose from 1.3 billion to 22.8 billion over that same period. This resulted in a...

  18. SAND2010-3276C

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Albuquerque, NM, 2002. 9. Ong, C. H. and Tsai, S.W., "Design, Manufacture and Testing of a Bend-Twist D-Spar," SAND99-1324, Sandia National Laboratories, Albuquerque,...

  19. International Refrigeration: Order (2012-CE-1510) | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    International Refrigeration: Order (2012-CE-1510) International Refrigeration: Order (2012-CE-1510) July 20, 2012 DOE ordered International Refrigeration Products to pay an 8,000 ...

  20. CE Solar | Open Energy Information

    Open Energy Info (EERE)

    Czech Republic Zip: 686 01 Product: Czech PV system integrator primarily building plants for Energy 21 in the Czech Republic. References: CE Solar1 This article is a stub....

  1. Treating tar sands formations with karsted zones

    DOE Patents [OSTI]

    Vinegar, Harold J.; Karanikas, John Michael

    2010-03-09

    Methods for treating a tar sands formation are described herein. The tar sands formation may have one or more karsted zones. Methods may include providing heat from one or more heaters to one or more karsted zones of the tar sands formation to mobilize fluids in the formation. At least some of the mobilized fluids may be produced from the formation.

  2. SAND 2004-0281P

    National Nuclear Security Administration (NNSA)

    SAND 2004-0281P March 2004 Issued by Sandia National Laboratories, operated for the United States Department of Energy by Sandia Corporation. Notice: This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, nor any of their contractors, subcontractors, or their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for

  3. CRAD, NNSA - Conduct of Engineering (CE) | Department of Energy

    Office of Environmental Management (EM)

    Conduct of Engineering (CE) CRAD, NNSA - Conduct of Engineering (CE) CRAD for Conduct of Engineering (CE). Criteria Review and Approach Documents (CRADs) that can be used to...

  4. Almo: Order (2012-CE-1416) | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    PDF icon 2012-CE-1416AlmoOrder More Documents & Publications Almo: Proposed Penalty (2012-CE-1416) International Refrigeration: Order (2012-CE-1510) Commercial Display Systems: ...

  5. School Air: Proposed Penalty (2016-CE-43004) | Department of...

    Energy Savers [EERE]

    School Air: Proposed Penalty (2016-CE-43004) (15.74 KB) More Documents & Publications School Air: Order (2016-CE-43004) Temspec: Proposed Penalty (2016-CE-43002) Crane: Proposed ...

  6. Atosa: Proposed Penalty (2015-CE-42037) | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Atosa: Proposed Penalty (2015-CE-42037) (15.43 KB) More Documents & Publications Atosa: Order (2015-CE-42037) Utility: Proposed Penalty (2016-CE-42007) Crane: Proposed Penalty ...

  7. RPI: Proposed Penalty (2015-CE-42065) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    RPI: Proposed Penalty (2015-CE-42065) (16.14 KB) More Documents & Publications RPI: Order (2015-CE-42065) Utility: Proposed Penalty (2016-CE-42007) Crane: Proposed Penalty ...

  8. November 2015 | SAND2015-XXXX M

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    | SAND2015-XXXX M Solar Basics for Homebuilders | Page 1 Solar photovoltaic (PV) energy systems are new in many residential real estate markets, and a growing number of ...

  9. CE: Proposed Penalty (2013-SE-1429)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that CE North America, LLC, privately labeled and distributed noncompliant freezers in the U.S.

  10. CE: Compromise Agreement (2013-SE-1429)

    Broader source: Energy.gov [DOE]

    DOE and CE North America entered into a Compromise Agreement to resolve a case involving the distribution in commerce of noncompliant freezers.

  11. Secure Fuels from Domestic Resources - Oil Shale and Tar Sands...

    Office of Environmental Management (EM)

    Secure Fuels from Domestic Resources - Oil Shale and Tar Sands Secure Fuels from Domestic Resources - Oil Shale and Tar Sands Profiles of Companies Engaged in Domestic Oil Shale ...

  12. Photoelectron spectra of CeO{sup −} and Ce(OH){sub 2}{sup −}

    SciTech Connect (OSTI)

    Ray, Manisha; Felton, Jeremy A.; Kafader, Jared O.; Topolski, Josey E.; Jarrold, Caroline Chick

    2015-02-14

    The photoelectron spectrum of CeO{sup −} exhibits what appears to be a single predominant electronic transition over an energy range in which numerous close-lying electronic states of CeO neutral are well known. The photoelectron spectrum of Ce(OH){sub 2}{sup −}, a molecule in which the Ce atom shares the same formal oxidation state as the Ce atom in CeO{sup −}, also exhibits what appears to be a single transition. From the spectra, the adiabatic electron affinities of CeO and Ce(OH){sub 2} are determined to be 0.936 ± 0.007 eV and 0.69 ± 0.03 eV, respectively. From the electron affinity of CeO, the CeO{sup −} bond dissociation energy was determined to be 7.7 eV, 0.5 eV lower than the neutral bond dissociation energy. The ground state orbital occupancies of both CeO{sup −} and Ce(OH){sub 2}{sup −} are calculated to have 4f 6s{sup 2} Ce{sup +} superconfigurations, with open-shell states having 4f5d6s superconfiguration predicted to be over 1 eV higher in energy. Low-intensity transitions observed at higher electron binding energies in the spectrum of CeO{sup −} are tentatively assigned to the {sup 1}Σ{sup +} (Ω = 0) state of CeO with the Ce{sup +2}⍰6s{sup 2} superconfiguration.

  13. Oil Sands Feedstocks | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sands Feedstocks Oil Sands Feedstocks Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. 2006_deer_fairbridge.pdf (1.94 MB) More Documents & Publications Energy Independence for North America - Transition to the Hydrogen Economy Emissions from Heavy-Duty Diesel Engine with EGR using Oil Sands Derived Fuels The Influence of Molecular Structure of Distillate Fuels on HFRR

  14. Microsoft Word - SAND2011-1094.docx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... The d States the best e 3 SAND2011-1094 Unlimited Release Printed March 2011 Wind Turbine ... 31. Emerging NDE Technology and Challenges at the beginning of the 3rd Millennium. ...

  15. SAND78-0962 VOL 3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    .( SAND78-0962 ECONOMIC ANALYSIS OF DARRIEUS VERTICAL-AXIS WIND TURBINE SYSTEMS FOR THE GENERATION OF UTILITY GRID ELECTRICAL POWER VOLUME III: POINT DESIGNS Robert D. Grover Emil...

  16. SAND78-0962 VOL 2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SAND78-0962 ECONOMIC ANALYSIS OF DARRIEUS VERTICAL AXIS WIND TURBINE SYSTEMS FOR THE GENERATION OF UTILITY GRID ELECTRICAL POWER VOLUME II - THE ECONOMIC OPTIMIZATION MODEL W. N....

  17. SANDIA REPORT SAND93-1076

    Office of Scientific and Technical Information (OSTI)

    SAND93-1076 * uqo UnlimitedRelease 1 Pdnted November 1993 :ii l Standard Testing Procedures for Optical Fiber and Unshielded Twisted Pair at Sandia National Laboratories R. L. ...

  18. Treating tar sands formations with dolomite

    DOE Patents [OSTI]

    Vinegar, Harold J.; Karanikas, John Michael

    2010-06-08

    Methods for treating a tar sands formation are described herein. The tar sands formation may include dolomite and hydrocarbons. Methods may include providing heat at less than the decomposition temperature of dolomite from one or more heaters to at least a portion of the formation. At least some of the hydrocarbon fluids are mobilized in the formation. At least some of the hydrocarbon fluids may be produced from the formation.

  19. California Ethanol Power CE P | Open Energy Information

    Open Energy Info (EERE)

    Power CE P Jump to: navigation, search Name: California Ethanol & Power (CE+P) Place: Florida Product: US ethanol project developer. References: California Ethanol & Power...

  20. Palmetto Clean Energy (PaCE) Program

    Office of Energy Efficiency and Renewable Energy (EERE)

    PaCE funding comes from the customers of participating utilities who voluntarily choose to support the program through an additional charge on their monthly utility bills. Of the $4, $3.50 goes t...

  1. CeCap LLP | Open Energy Information

    Open Energy Info (EERE)

    Name: CeCap LLP Place: London, United Kingdom Zip: W1S 2LQ Product: London-based investment boutique which provides investment advice to, and invests in, small to mediun size...

  2. Creating fluid injectivity in tar sands formations

    DOE Patents [OSTI]

    Stegemeier, George Leo; Beer, Gary Lee; Zhang, Etuan

    2012-06-05

    Methods for treating a tar sands formation are described herein. Methods for treating a tar sands may include heating a portion of a hydrocarbon layer in the formation from one or more heaters located in the portion. The heat may be controlled to increase the permeability of at least part of the portion to create an injection zone in the portion with an average permeability sufficient to allow injection of a fluid through the injection zone. A drive fluid and/or an oxidizing fluid may be provided into the injection zone. At least some hydrocarbons including mobilized hydrocarbons are produced from the portion.

  3. Creating fluid injectivity in tar sands formations

    DOE Patents [OSTI]

    Stegemeier, George Leo; Beer, Gary Lee; Zhang, Etuan

    2010-06-08

    Methods for treating a tar sands formation are described herein. Methods for treating a tar sands may include heating a portion of a hydrocarbon layer in the formation from one or more heaters located in the portion. The heat may be controlled to increase the permeability of at least part of the portion to create an injection zone in the portion with an average permeability sufficient to allow injection of a fluid through the injection zone. A drive fluid and/or an oxidizing fluid may be provided into the injection zone. At least some hydrocarbons are produced from the portion.

  4. Future of heavy crude and tar sands

    SciTech Connect (OSTI)

    Meyer, R.F.; Steele, C.T.

    1981-01-01

    The 106 papers which were presented at the First International Conference on the Future of Heavy Crude and Tar Sands, held in Edmonton, Alberta are incorporated in this volume. They are grouped under the following sections: (1) role of heavy crude oils and tar sands in world energy; (2) major known occurrences; (3) chemistry and geochemistry; (4) geology; (5) resource evaluation techniques; (6) production research and pilot projects; (7) current production; (8) upgrading and refining; (9) transportation; (10) environmental research; (11) economics; (12) technological problems; (13) institutional factors; and (14) bibliography. All papers have been abstracted and indexed. (ATT)

  5. Wind profiles on the stoss slope of sand dunes: Implications for eolian sand transport

    SciTech Connect (OSTI)

    Frank, A.; Kocurek, G. (Univ. of Texas, Austin, TX (United States). Dept. of Geological Sciences)

    1993-04-01

    Starting with the work of R.A. Bagnold it has been recognized that the shear stress exerted by the wind on sand grains is the driving force for eolian sand transport. Calculation of accurate rates of sand transport is essential for prediction of migration rates of sand dunes in modern environments as well as reconstructing paleoclimates (wind speed and direction) from eolian deposits. Because a sand dune is a streamlined obstacle in the path of the wind, continuity necessitates that the flow field is compressed over the windward side of a dune and shear stress should progressively increase up the slope as the flow accelerates. However, airflow measurements over 14 dunes (at White Sands, New Mexico; Algodones, CA; and Padre Island, TX) show that compression of the flow field occurs very close to the surface and as a consequence, the overlying flow actually shows an overall decrease in shear stress up the slope. Measurements commonly collected in the overlying zone are not representative of the near-surface, sand-driving wind. Furthermore, near-surface compression of the flow field implies that a pressure gradient exists that would render the current transport models inappropriate for sloping surfaces that dominate natural sandy desert terrains.

  6. File:OilSands.pdf | Open Energy Information

    Open Energy Info (EERE)

    OilSands.pdf Jump to: navigation, search File File history File usage File:OilSands.pdf Size of this preview: 463 599 pixels. Other resolution: 464 600 pixels. Go to page 1 2...

  7. Well completion process for formations with unconsolidated sands

    DOE Patents [OSTI]

    Davies, David K.; Mondragon, III, Julius J.; Hara, Philip Scott

    2003-04-29

    A method for consolidating sand around a well, involving injecting hot water or steam through well casing perforations in to create a cement-like area around the perforation of sufficient rigidity to prevent sand from flowing into and obstructing the well. The cement area has several wormholes that provide fluid passageways between the well and the formation, while still inhibiting sand inflow.

  8. Hybridized Nature of Pseudogap in Kondo Insulators CeRhSb and CeRhAs

    SciTech Connect (OSTI)

    Kumigashira, H.; Takahashi, T.; Yoshii, S.; Kasaya, M.

    2001-08-06

    We studied the electronic structure of Kondo insulators CeRhSb and CeRhAs using high-resolution photoemission spectroscopy. We found that the 4f -derived density of states shows a depletion (pseudogap) at E{sub F} in contrast to metallic Kondo materials. It was found that the size of the f pseudogap is smaller than that of conduction electrons (c pseudogap) while both scale well with the Kondo temperature. The present results indicate that the hybridization between 4f and conduction electrons near E{sub F} is essential for the Kondo gap in the Ce-based compounds.

  9. Solvent extraction of Southern US tar sands

    SciTech Connect (OSTI)

    Penney, W.R.

    1990-01-01

    The Department of Chemical Engineering at the University of Arkansas, in association with Diversified Petroleum Recovery, Inc. (DPR) of Little Rock, Arkansas, has been developing a solvent extraction process for the recovery of bitumen from tar sands for the past five years. The unique feature of the process is that the bitumen is recovered from the solvent by contacting with a co-solvent, which causes the bitumen to precipitate. The overall purpose of this project is to study both the technical and economic feasibility of applying this technology for recovery of bitumen from tar sands by (1) investigating the socioeconmic factors which affect (a) plant siting and (b) the market value of recovered bitumen; (2) operating a process demonstration unit at the rate of 1 lb/hr recovered bitumen while producing clean sand and recyclable solvents; and (3) determine the economic conditions which will make a bitumen recovery project economical. DPR has analyzed the historical trends of domestic production, consumption, discoveries and reserves of crude oil. They have started an investigation of the volatility in the price of crude oil and of gasoline prices and of the differential between gasoline and crude oil. DPR continues to analyze the geographical movement and demand for asphalt products. Utah does not appear economically attractive as a site for a bitumen from tar sands asphalt plant. Oklahoma sites are now being studied. This report also contains the quarterly progress report from a University of Nevada study to determine bitumen composition, oxygen uptake rates, and viscosities of Alabama and Utah bitumens. Both reports have been indexed separately for inclusion on the data base.

  10. SAND76-0260 Unlimited Release

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SAND76-0260 Unlimited Release Printed July 1976 . POWER SUPPLIES FOR SPACE SYSTEMS QUALITY ASSURANCE BY SANDIA LABORATORIES Robert L. Hannigan Robert R. Harnar Electronic and Electrical Devices Division 951 2 Sandia Laboratories Albuquerque, NM 87115 AB STRAC T This report summarizes the Sandia Laboratories participation in Quality Assurance programs for Radioisotopic Thermoelectric Generators which have been used i n space systems over the past 10 years. Basic elements of this QA program a r e

  11. EA-1581: Sand Hills Wind Project, Wyoming

    Broader source: Energy.gov [DOE]

    The Bureau of Land Management, with DOE’s Western Area Power Administration as a cooperating agency, was preparing this EA to evaluate the environmental impacts of a proposal to construct, operate, and maintain the Sand Hills Wind Energy Facility on private and federal lands in Albany County, Wyoming. If the proposed action had been implemented, Western would have interconnected the proposed facility to an existing transmission line. This project has been canceled.

  12. Guide to preparing SAND reports. Revised

    SciTech Connect (OSTI)

    Locke, T.K.

    1996-04-01

    This guide contains basic information needed to produce a SAND report. Its guidelines reflect DOE regulation and Sandia policy. The guide includes basic writing instructions in an annotated sample report; guidance for organization, format, and layout of reports produced by line organizations; and information about conference papers, journal articles, and brochures. The appendixes contain sections on Sandia`s preferred usage, equations, references, copyrights and permissions, and publishing terms.

  13. CONTENTS Gas Hydrate-Bearing Sand

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CONTENTS Gas Hydrate-Bearing Sand Reservoir Systems in the Offshore of India: Results of the India National Gas Hydrate Program Expedition 02 ..............1 The Potential for Abiotic Methane in Arctic Gas Hydrates .................9 Coupled Thermo-Hydro-Chemo- Mechanical (THCM) Models for Hydrate-Bearing Sediments ....13 Emerging Issues in the Development of Geologic Models for Gas Hydrate Numerical Simulation ................19 Announcements ...................... 23 * DOE/NETL FY2016 Methane

  14. Goodman Manufacturing: Order (2012-CE-1509) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2-CE-1509) Goodman Manufacturing: Order (2012-CE-1509) August 7, 2012 DOE ordered Goodman Manufacturing Company L.P. to pay an 8,000 civil penalty after finding Goodman...

  15. Spin reorientation and Ce-Mn coupling in antiferromagnetic oxypnictide CeMnAsO

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Qiang; Tian, Wei; Peterson, Spencer G.; Dennis, Kevin W.; Vaknin, David

    2015-02-18

    Structure and magnetic properties of high-quality polycrystlline CeMnAsO, a parent compound of the “1111”-type oxypnictides, have been investigated using neutron powder diffraction and magnetization measurements. We find that CeMnAsO undergoes a C-type antiferromagnetic order with Mn2+(S = 5/2) moments pointing along the c axis below a relatively high Néel temperature of TN = 347(1) K. Below TSR = 35 K, two simultaneous transitions occur where the Mn moments reorient from the c axis to the ab plane preserving the C-type magnetic order, and Ce moments undergo long-range AFM ordering with antiparallel moments pointing in the ab plane. Another transition tomore » a noncollinear magnetic structure occurs below 7 K. The ordered moments of Mn and Ce at 2 K are 3.32(4) μB and 0.81(4)μB, respectively. We find that CeMnAsO primarily falls into the category of a local-moment antiferromagnetic insulator in which the nearest-neighbor interaction (J1) is dominant with J2 < J1/2 in the context of J1 – J2 – Jc model. The spin reorientation transition driven by the coupling between Ce and the transition metal seems to be common to Mn, Fe, and Cr ions, but not to Co and Ni ions in the isostructural oxypnictides. As a result, a schematic illustration of magnetic structures in Mn and Ce sublattices in CeMnAsO is presented.« less

  16. Utility: Order (2016-CE-42007) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CE-42007) Utility: Order (2016-CE-42007) January 5, 2016 DOE ordered Utility Refrigerator to pay a $8,000 civil penalty after finding Utility had failed to certify that certain models of commercial refrigerator equipment comply with the applicable energy conservation standards. The Order adopted a Compromise Agreement, which reflected settlement terms between DOE and Utility. Utility: Order (2016-CE-42007) (22.13 KB) More Documents & Publications Utility: Proposed Penalty (2016-CE-42007) Bu

  17. RPI: Order (2015-CE-42065) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Order (2015-CE-42065) RPI: Order (2015-CE-42065) November 6, 2015 DOE ordered RPI Industries, Inc. to pay a $8,000 civil penalty after finding RPI had failed to certify that certain models of commercial refrigeration equipment comply with the applicable energy conservation standards. The Order adopted a Compromise Agreement, which reflected settlement terms between DOE and RPI. RPI: Order (2015-CE-42065) (21.12 KB) More Documents & Publications RPI: Proposed Penalty (2015-CE-42065) Wolverine

  18. Policy Analysis of the Canadian Oil Sands Experience

    SciTech Connect (OSTI)

    None, None

    2013-09-01

    For those who support U.S. oil sands development, the Canadian oil sands industry is often identified as a model the U.S. might emulate, yielding financial and energy security benefits. For opponents of domestic oil sands development, the Canadian oil sands experience illustrates the risks that opponents of development believe should deter domestic policymakers from incenting U.S. oil sands development. This report does not seek to evaluate the particular underpinnings of either side of this policy argument, but rather attempts to delve into the question of whether the Canadian experience has relevance as a foundational model for U.S. oil sands development. More specifically, this report seeks to assess whether and how the Canadian oil sands experience might be predictive or instructive in the context of fashioning a framework for a U.S. oil sands industry. In evaluating the implications of these underpinnings for a prospective U.S. oil sands industry, this report concentrates on prospective development of the oil sands deposits found in Utah.

  19. Eolian cover sands: a sedimentologic model and paleoenvironmental implications

    SciTech Connect (OSTI)

    Lea, P.D.

    1985-01-01

    In periglacial areas, accumulations of eolian sand commonly form low-relief blankets without well-developed dunes. Internally, these sandsheet deposits exhibit subhorizontal lamination rather than high-angle cross-bedding. Such cover sands of late-Pleistocene age mantle extensive areas in northern Europe, but have been reported more rarely from North America. The processes by which cover sands, as opposed to dunes, accumulate have not yet been determined conclusively. Wind ripples and sand dunes do not form a continuum; flow separation and avalanching and negligible in the former and vital in the latter. Accretion of a sand patch into a mound sufficient to cause flow separation and dune growth requires a consistently available supply of loose sand. In cover-sand areas, sand may be immobilized prior to dune development by several factors: (1) a sparse vegetation cover, (2) moist ground conditions, (3) snow cover, and (4) a shallow permafrost table and/or an ice-cemented active layer. Detailed sedimentologic studies may allow discrimination among these various controls. The importance of the individual controlling factors can vary seasonally in a given deposit, as well as between deposits in different paleogeographic settings. However, all factors imply more mesic conditions than those associated with many dune deposits. The association of cover sands with paraboloid dunes is also consistent with somewhat moist conditions. The relatively mesic nature of cover sands controls their Pleistocene distribution; they become decreasingly important relative to dunes in maritime-to-continental transects across Alaska and northern Europe.

  20. Oil shale, tar sands, and related materials

    SciTech Connect (OSTI)

    Stauffer, H.C.

    1981-01-01

    This sixteen-chapter book focuses on the many problems and the new methodology associated with the commercialization of the oil shale and tar sand industry. Topics discussed include: an overview of the Department of Energy's oil shale R, D, and D program; computer simulation of explosive fracture of oil shale; fracturing of oil shale by treatment with liquid sulfur dioxide; chemistry of shale oil cracking; hydrogen sulfide evolution from Colorado oil shale; a possible mechanism of alkene/alkane production in oil shale retorting; oil shale retorting kinetics; kinetics of oil shale char gasification; a comparison of asphaltenes from naturally occurring shale bitumen and retorted shale oils: the influence of temperature on asphaltene structure; beneficiation of Green River oil shale by density methods; beneficiation of Green River oil shale pelletization; shell pellet heat exchange retorting: the SPHER energy-efficient process for retorting oil shale; retorted oil shale disposal research; an investigation into the potential economics of large-scale shale oil production; commercial scale refining of Paraho crude shale oil into military specification fuels; relation between fuel properties and chemical composition; chemical characterization/physical properties of US Navy shale-II fuels; relation between fuel properties and chemical composition: stability of oil shale-derived jet fuel; pyrolysis of shale oil residual fractions; synfuel stability: degradation mechanisms and actual findings; the chemistry of shale oil and its refined products; the reactivity of Cold Lake asphaltenes; influence of thermal processing on the properties of Cold Lake asphaltenes: the effect of distillation; thermal recovery of oil from tar sands by an energy-efficient process; and hydropyrolysis: the potential for primary upgrading of tar sand bitumen.

  1. Heating tar sands formations while controlling pressure

    DOE Patents [OSTI]

    Stegemeier, George Leo [Houston, TX; Beer, Gary Lee [Houston, TX; Zhang, Etuan [Houston, TX

    2010-01-12

    Methods for treating a tar sands formation are described herein. Methods may include heating at least a section of a hydrocarbon layer in the formation from a plurality of heaters located in the formation. A pressure in the majority of the section may be maintained below a fracture pressure of the formation. The pressure in the majority of the section may be reduced to a selected pressure after the average temperature reaches a temperature that is above 240.degree. C. and is at or below pyrolysis temperatures of hydrocarbons in the section. At least some hydrocarbon fluids may be produced from the formation.

  2. Heating tar sands formations to visbreaking temperatures

    DOE Patents [OSTI]

    Karanikas, John Michael; Colmenares, Tulio Rafael; Zhang, Etuan; Marino, Marian; Roes, Augustinus Wilhelmus Maria; Ryan, Robert Charles; Beer, Gary Lee; Dombrowski, Robert James; Jaiswal, Namit

    2009-12-22

    Methods for treating a tar sands formation are described herein. Methods may include heating at least a section of a hydrocarbon layer in the formation from a plurality of heaters located in the formation. The heat may be controlled so that at least a majority of the section reaches an average temperature of between 200.degree. C. and 240.degree. C., which results in visbreaking of at least some hydrocarbons in the section. At least some visbroken hydrocarbon fluids may be produced from the formation.

  3. SAND2011-9306 Unlimited Release

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SAND2011-9306 Unlimited Release Printed November 2011 Reference Model 2: "Rev 0" Rotor Design Matt Barone, Todd Griffith, and Jonathan Berg Sandia National Laboratories P.O. Box 5800 Albuquerque, New Mexico 87185-1124 Abstract The preliminary design for a three-bladed cross-flow rotor for a reference marine hydrokinetic turbine is presented. A rotor performance design code is described, along with modifications to the code to allow prediction of blade support strut drag as well as

  4. Testing the Delaware sand filter's effectiveness for treating stormwater runoff

    SciTech Connect (OSTI)

    Leszczynska, D.; Dzurik, A.

    1998-07-01

    The use of the Delaware Sand Filter for treatment of ultra-urban stormwater is investigated for Florida applications. An experimental Delaware filter is designed in conjunction with a typical sand filter as part of a street improvement project in Tallahassee, Florida. The design allows for testing of different filter media in an attempt to determine the suitability of the Delaware Sand Filter in hot climates with numerous heavy rainfall episodes.

  5. Oil Shale and Oil Sands Development Robert Keiter; John Ruple...

    Office of Scientific and Technical Information (OSTI)

    Conjunctive Surface and Groundwater Management in Utah: Implications for Oil Shale and Oil Sands Development Robert Keiter; John Ruple; Heather Tanana; Rebecca Holt 29 ENERGY...

  6. RFC Sand Creek Development LLC | Open Energy Information

    Open Energy Info (EERE)

    Colorado Zip: 80014 Product: Subsidiary of Republic Financial Corporation set up to invest in Sand Creek Energy LLC, a planned gas to liquid facility. Coordinates: 39.325162,...

  7. Sand Springs, Oklahoma: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Sand Springs, Oklahoma: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 36.1398102, -96.108891 Show Map Loading map... "minzoom":false,"mapping...

  8. Dynamic Behavior of Sand: Annual Report FY 11 (Technical Report...

    Office of Scientific and Technical Information (OSTI)

    ... Sponsoring Org: USDOE Country of Publication: United States Language: English Subject: 71 ... SAND; SENSITIVITY; SIMULATION; TARGETS; TESTING; WEAPONS Word Cloud More Like This Full ...

  9. Sand Dunes Hot Spring Aquaculture Low Temperature Geothermal...

    Open Energy Info (EERE)

    Dunes Hot Spring Aquaculture Low Temperature Geothermal Facility Jump to: navigation, search Name Sand Dunes Hot Spring Aquaculture Low Temperature Geothermal Facility Facility...

  10. Reuse of waste cutting sand at Lawrence Livermore National Laboratory

    SciTech Connect (OSTI)

    Mathews, S., LLNL

    1998-02-25

    Lawrence Livermore National Laboratory (LLNL) examined the waste stream from a water jet cutting operation, to evaluate the possible reuse of waste garnet sand. The sand is a cutting agent used to shape a variety of materials, including metals. Nearly 70,000 pounds of waste sand is generated annually by the cutting operation. The Environmental Protection Department evaluated two potential reuses for the spent garnet sand: backfill in utility trenches; and as a concrete constituent. In both applications, garnet waste would replace the sand formerly purchases by LLNL for these purposes. Findings supported the reuse of waste garnet sand in concrete, but disqualified its proposed application as trench backfill. Waste sand stabilized in ac concrete matrix appeared to present no metals-leaching hazard; however, unconsolidated sand in trenches could potentially leach metals in concentrations high enough to threaten ground water quality. A technical report submitted to the San Francisco Bay Regional Water Quality Control Board was reviewed and accepted by that body. Reuse of waste garnet cutting sand as a constituent in concrete poured to form walkways and patios at LLNL was approved.

  11. Montana Sand and Gravel Operations General Permit - Example Authorizat...

    Open Energy Info (EERE)

    OpenEI Reference LibraryAdd to library PermittingRegulatory Guidance - Supplemental Material: Montana Sand and Gravel Operations General Permit - Example AuthorizationPermitting...

  12. White Sands, New Mexico: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Sands, New Mexico: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 32.38319, -106.481499 Show Map Loading map... "minzoom":false,"mappingservic...

  13. TESTING OF TMR SAND MANTIS FINAL REPORT

    SciTech Connect (OSTI)

    Krementz, D; William Daugherty, W

    2007-06-12

    Screening tests of Sand Mantis candidate materials selected for erosion resistance have been completed. The results of this testing identified that over a relatively short period of operation (<1 hour), measurable erosion will occur in each of the candidate zoom tube materials given equal operating exposure. Additionally, this testing has shown that erosion of the rubber discharge hose directly downstream of the vehicle could be expected to limit the service life of the discharge hose. On the basis of these test results, SRNL recommends the following; {lg_bullet} redesign of critical system components (e.g., zoom tube, discharge hose) should be conducted to improve system characteristics relative to erosion and capitalize on the results of this testing, {lg_bullet} continued efforts to deploy the Sand Mantis should include testing to better define and optimize operating parameters, and gain an understanding of system dynamics, {lg_bullet} discontinue wear testing with the selected materials pending redesign of critical system components (1st recommendation) and inclusion of other candidate materials. The final selection of additional candidate materials should be made following design changes, but might include a Stellite alloy or zirconia.

  14. Water Dissociation on CeO2(100) and CeO2(111) Thin Films

    SciTech Connect (OSTI)

    Mullins, David R; Albrecht, Peter M; Chen, Tsung-Liang; Calaza, Florencia C; Biegalski, Micahel; Christen, Hans; Overbury, Steven {Steve} H

    2012-01-01

    This study reports and compares the adsorption and dissociation of water on oxidized and reduced CeO{sub 2}(100) and CeO{sub 2}(111) thin films. Water adsorbs dissociatively on both surfaces. On fully oxidized CeO{sub 2}(100) the resulting surface hydroxyls are relatively stable and recombine and desorb as water over a range from 200 to 600 K. The hydroxyls are much less stable on oxidized CeO{sub 2}(111), recombining and desorbing between 200 and 300 K. Water produces 30% more hydroxyls on reduced CeO{sub 1.7}(100) than on oxidized CeO{sub 2}(100). The hydroxyl concentration increases by 160% on reduced CeO{sub 1.7}(111) compared to oxidized CeO{sub 2}(111). On reduced CeO{sub 1.7}(100) most of the hydroxyls still recombine and desorb as water between 200 and 750 K. Most of the hydroxyls on reduced CeO{sub 1.7}(111) react to produce H{sub 2} at 560 K, leaving O on the surface. A relatively small amount of H{sub 2} is produced from reduced CeO{sub 1.7}(100) between 450 and 730 K. The differences in the adsorption and reaction of water on CeO{sub X}(100) and CeO{sub X}(111) are attributed to different adsorption sites on the two surfaces. The adsorption site on CeO{sub 2}(100) is a bridging site between two Ce cations. This adsorption site does not change when the ceria is reduced. The adsorption site on CeO{sub 2}(111) is atop a single Ce cation, and the proton is transferred to a surface O in a site between three Ce cations. When the CeO{sub X}(111) is reduced, vacancy sites are produced which allows the water to adsorb and dissociate on the 3-fold Ce cation sites.

  15. Role of Ce4+ in the scintillation mechanism of codoped Gd3Ga3Al2O12:Ce

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wu, Yuntao; Meng, Fang; Li, Qi; Koschan, Merry; Melcher, Charles L.

    2014-10-17

    To control the time-response performance of widely used cerium-activated scintillators in cutting-edge medical-imaging devices, such as time-of-flight positron-emission tomography, a comprehensive understanding of the role of Ce valence states, especially stable Ce4+, in the scintillation mechanism is essential. However, despite some progress made recently, an understanding of the physical processes involving Ce4+ is still lacking. The aim of this work is to clarify the role of Ce4+ in scintillators by studying Ca2+ codoped Gd3Ga3Al2O12∶Ce (GGAG∶Ce). By using a combination of optical absorption spectra and x-ray absorption near-edge spectroscopies, the correlation between Ca2+codoping content and the Ce4+ fraction is seen. The energy-levelmore »diagrams of Ce3+ and Ce4+ in the Gd3Ga3Al2O12 host are established by using theoretical and experimental methods, which indicate a higher position of the 5d1 state of Ce4+ in the forbidden gap in comparison to that of Ce3+. Underlying reasons for the decay-time acceleration resulting from Ca2+ codoping are revealed, and the physical processes of the Ce4+-emission model are proposed and further demonstrated by temperature-dependent radioluminescence spectra under x-ray excitation.« less

  16. Role of Ce4+ in the scintillation mechanism of codoped Gd3Ga3Al2O12:Ce

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wu, Yuntao; Meng, Fang; Li, Qi; Koschan, Merry; Melcher, Charles L.

    2014-10-17

    To control the time-response performance of widely used cerium-activated scintillators in cutting-edge medical-imaging devices, such as time-of-flight positron-emission tomography, a comprehensive understanding of the role of Ce valence states, especially stable Ce4+, in the scintillation mechanism is essential. However, despite some progress made recently, an understanding of the physical processes involving Ce4+ is still lacking. The aim of this work is to clarify the role of Ce4+ in scintillators by studying Ca2+ codoped Gd3Ga3Al2O12∶Ce (GGAG∶Ce). By using a combination of optical absorption spectra and x-ray absorption near-edge spectroscopies, the correlation between Ca2+codoping content and the Ce4+ fraction is seen. The energy-levelmore » diagrams of Ce3+ and Ce4+ in the Gd3Ga3Al2O12 host are established by using theoretical and experimental methods, which indicate a higher position of the 5d1 state of Ce4+ in the forbidden gap in comparison to that of Ce3+. Underlying reasons for the decay-time acceleration resulting from Ca2+ codoping are revealed, and the physical processes of the Ce4+-emission model are proposed and further demonstrated by temperature-dependent radioluminescence spectra under x-ray excitation.« less

  17. Zebra processes of oil recovery using fireflood and waterflood in alternate sands in a multi-sand environment

    SciTech Connect (OSTI)

    Chu, C.

    1995-12-31

    This paper presents a new process of oil recovery, namely, the zebra process, which is specifically advantageous to use in heavy oil reservoirs that exist in multiple sands. This process uses firefloods and waterfloods in alternate sands. The firefloods serve as formation preheaters which reduce the oil viscosities in the neighboring sands so that these sands, normally not amenable to waterfloods because of high viscosity, can be waterflooded with ease. The exciting news is that the air compression cost in firefloods can be reduced by a factor of three with a proper application of the zebra process. This great savings in air compression cost is possible because the heat that is normally lost to the overburden and underburden in firefloods is now being put to good use, by preheating the neighboring sands. Examples are given on zebraing several idealized sand-shale sequences involving three-, five-, six-, and seven-sand reservoirs, and also zebraing two actual sand-shale sequences, both involving five-sand reservoirs.

  18. The extraction of bitumen from western tar sands. Annual report

    SciTech Connect (OSTI)

    Oblad, A.G.; Bunger, J.W.; Deo, M.D.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1990-07-01

    Topics discussed include: characterization of bitumen impregnated sandstone, water based tar sand separation technology, electrophoretic characterization of bitumen and fine mineral particles, bitumen and tar sand slurry viscosity, the hot water digestion-flotation process, electric field use on breaking water-in-oil emulsions, upgrading of bitumens and bitumen-derived liquids, solvent extraction.

  19. The extraction of bitumen from western tar sands

    SciTech Connect (OSTI)

    Oblad, A.G.; Bunger, J.W.; Deo, M.D.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1990-07-01

    Topics discussed include: characterization of bitumen impregnated sandstone, water based tar sand separation technology, electrophoretic characterization of bitumen and fine mineral particles, bitumen and tar sand slurry viscosity, the hot water digestion-flotation process, electric field use on breaking water-in-oil emulsions, upgrading of bitumens and bitumen-derived liquids, solvent extraction.

  20. China shows increasing interest in heavy oil and oil sands

    SciTech Connect (OSTI)

    Not Available

    1986-12-01

    China and Canadian and US groups are cooperating in several areas to develop the heavy oil, asphalt, and oil sand deposits of China. The agreements dealing with exploration and upgrading are briefly described. The majority of the paper describes the occurrences of heavy oil, asphalt, and oil sands in China. 1 figure.

  1. Acoustic sand detector for fluid flowstreams

    DOE Patents [OSTI]

    Beattie, Alan G. (Corrales, NM); Bohon, W. Mark (Frisco, TX)

    1993-01-01

    The particle volume and particle mass production rate of particulate solids entrained in fluid flowstreams such as formation sand or fracture proppant entrained in oil and gas production flowstreams is determined by a system having a metal probe interposed in a flow conduit for transmitting acoustic emissions created by particles impacting the probe to a sensor and signal processing circuit which produces discrete signals related to the impact of each of the particles striking the probe. The volume or mass flow rate of particulates is determined from making an initial particle size distribution and particle energy distribution and comparing the initial energy distribution and/or the initial size distribution with values related to the impact energies of a predetermined number of recorded impacts. The comparison is also used to recalibrate the system to compensate for changes in flow velocity.

  2. Direct Production of Silicones From Sand

    SciTech Connect (OSTI)

    Larry N. Lewis; F.J. Schattenmann: J.P. Lemmon

    2001-09-30

    Silicon, in the form of silica and silicates, is the second most abundant element in the earth's crust. However the synthesis of silicones (scheme 1) and almost all organosilicon chemistry is only accessible through elemental silicon. Silicon dioxide (sand or quartz) is converted to chemical-grade elemental silicon in an energy intensive reduction process, a result of the exceptional thermodynamic stability of silica. Then, the silicon is reacted with methyl chloride to give a mixture of methylchlorosilanes catalyzed by cooper containing a variety of tract metals such as tin, zinc etc. The so-called direct process was first discovered at GE in 1940. The methylchlorosilanes are distilled to purify and separate the major reaction components, the most important of which is dimethyldichlorosilane. Polymerization of dimethyldichlorosilane by controlled hydrolysis results in the formation of silicone polymers. Worldwide, the silicones industry produces about 1.3 billion pounds of the basic silicon polymer, polydimethylsiloxane.

  3. Method and apparatus for hydrocarbon recovery from tar sands

    DOE Patents [OSTI]

    Westhoff, J.D.; Harak, A.E.

    1988-05-04

    A method and apparatus for utilizing tar sands having a broad range of bitumen content is disclosed. More particularly, tar sands are pyrolyzed in a cyclone retort with high temperature gases recycled from the cyclone retort to produce oil and hydrocarbon products. The spent tar sands are then burned at 2000/degree/F in a burner to remove residual char and produce a solid waste that is easily disposable. The process and apparatus have the advantages of being able to utilize tar sands having a broad range of bitumen content and the advantage of producing product gases that are free from combustion gases and thereby have a higher heating value. Another important advantage is rapid pyrolysis of the tar sands in the cyclone so as to effectively utilize smaller sized reactor vessels for reducing capitol and operating costs. 1 fig., 1 tab.

  4. Method and apparatus for hydrocarbon recovery from tar sands

    DOE Patents [OSTI]

    Westhoff, James D.; Harak, Arnold E.

    1989-01-01

    A method and apparatus for utilizing tar sands having a broad range of bitumen content is disclosed. More particularly, tar sands are pyrolyzed in a cyclone retort with high temperature gases recycled from the cyclone retort to produce oil and hydrocarbon products. The spent tar sands are then burned at 2000.degree. F. in a burner to remove residual char and produce a solid waste that is easily disposable. The process and apparatus have the advantages of being able to utilize tar sands having a broad range of bitumen content and the advantage of producing product gases that are free from combustion gases and thereby have a higher heating value. Another important advantage is rapid pyrolysis of the tar sands in the cyclone so as to effectively utilize smaller sized reactor vessels for reducing capitol and operating costs.

  5. Crane: Order (2016-CE-52001) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Order (2016-CE-52001) Crane: Order (2016-CE-52001) January 21, 2016 DOE ordered Crane Merchandising Systems, Inc. to pay a $16,000 civil penalty after finding Crane had failed to certify that certain models of refrigerated bottled or canned beverage vending machines comply with the applicable energy conservation standards. The Order adopted a Compromise Agreement, which reflected settlement terms between DOE and Crane. Crane: Order (2016-CE-52001) (23.16 KB) More Documents & Publications

  6. Atosa: Order (2015-CE-42037) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Order (2015-CE-42037) Atosa: Order (2015-CE-42037) August 31, 2015 DOE ordered Atosa Catering Equipment, Inc. to pay a $8,000 civil penalty after finding Atosa had failed to certify that certain models of self-contained commercial refrigeration equipment with doors comply with the applicable energy conservation standards. The Order adopted a Compromise Agreement, which reflected settlement terms between DOE and Atosa. Atosa: Order (2015-CE-42037) (26.71 KB) More Documents & Publications

  7. Herbeau: Order (2015-CE-28005) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Order (2015-CE-28005) Herbeau: Order (2015-CE-28005) March 9, 2016 DOE ordered Herbeau Creations of America, Inc. to pay a $8,000 civil penalty after finding Herbeau had failed to certify that certain models of faucets and showerheads comply with the applicable water conservation standards. The Order adopted a Compromise Agreement, which reflected settlement terms between DOE and Herbeau. Herbeau: Order (2015-CE-28005) (16.61 KB) More Documents & Publications Herbeau: Proposed Penalty

  8. Temspec: Order (2016-CE-43002) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Order (2016-CE-43002) Temspec: Order (2016-CE-43002) March 21, 2016 DOE ordered Temspec Incorporated to pay a $8,000 civil penalty after finding Temspec had failed to certify that certain models of single package vertical air conditioning and heating equipment comply with the applicable energy conservation standards. The Order adopted a Compromise Agreement, which reflected settlement terms between DOE and Temspec. Temspec: Order (2016-CE-43002) (92.11 KB) More Documents & Publications

  9. CE2 Capital Partners LLC | Open Energy Information

    Open Energy Info (EERE)

    Capital Partners LLC Jump to: navigation, search Name: CE2 Capital Partners LLC Place: Solana Beach, California Zip: 92075 Sector: Carbon, Renewable Energy Product:...

  10. PQL: Order (2013-CE-27001) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PQL: Order (2013-CE-27001) PQL: Order (2013-CE-27001) August 7, 2015 DOE ordered P.Q.L, Inc. to pay a $12,500 civil penalty after finding PQL had failed to certify that certain models of medium base compact fluorescent lamps comply with the applicable energy conservation standards. The Order adopted a Compromise Agreement, which reflected settlement terms between DOE and PQL. PQL: Order (2013-CE-27001) (17.34 KB) More Documents & Publications PQL: Proposed Penalty (2013-CE-27001) PQL: Order

  11. Thermoelectric Couple Demonstration of (In, Ce)-based Skutterudite...

    Broader source: Energy.gov (indexed) [DOE]

    Presents recent accomplishments and couple test results with these (In, Ce)-based skutterudite TE materials and potential impacts TE power system performance in military and ...

  12. Lattice Disorder And Size-Induced Kondo Behavior in CeAl(2) And CePt(2+X)

    SciTech Connect (OSTI)

    Han, S.-W.; Booth, C.H.; Bauer, E.D.; Huang, P.H.; Chen, Y.Y.; Lawrence, J.M.; /LBL, Berkeley /Chonbuk Natl. U. /Los Alamos /Taiwan, Inst. Phys. /UC, Irvine

    2007-07-19

    When the particle size of CeAl{sub 2} and CePt{sub 2+x} samples is reduced to the nanometer scale, antiferromagnetism is suppressed and Kondo behavior dominates. We find that the Kondo temperature T{sub K} can either decrease (CeAl{sub 2}) or increase (CePt{sub 2+x}) in the nanoparticles relative to the bulk. Extended x-ray absorption fine-structure data show that the Ce-Al and Ce-Pt environments are significantly distorted in the nanoparticles. While such distortions should strongly affect magnetic and electronic properties, we find they cannot explain the observed changes in T{sub K}. Changes in the conduction density of states or other parameters must, therefore, play a significant role.

  13. Lattice disorder and size-induced Kondo behavior in CeAl2 andCePt2+x

    SciTech Connect (OSTI)

    Han, S.-W.; Booth, C.H.; Bauer, E.D.; Huang P.H.; Chen, Y.Y.; Lawrence, J.M.

    2006-03-14

    When the particle size of CeAl{sub 2} and CePt{sub 2+x} samples is reduced to the nanometer scale, antiferromagnetism is suppressed and Kondo behavior dominates. We find that the Kondo temperature T{sub K} can either decrease (CeAl{sub 2}) or increase (CePt{sub 2+x}) in the nanoparticles relative to the bulk. Extended x-ray absorption fine-structure data show that the Ce-Al and Ce-Pt environments are significantly distorted in the nanoparticles. While such distortions should strongly affect magnetic and electronic properties, we find they cannot explain the observed changes in T{sub K}. Changes in the conduction density of states or other parameters must, therefore, play a significant role.

  14. Montana Notice of Intent: Sand and Gravel General Permit (MDEQ...

    Open Energy Info (EERE)

    Form NOI) Jump to: navigation, search OpenEI Reference LibraryAdd to library Form: Montana Notice of Intent: Sand and Gravel General Permit (MDEQ Form NOI) Abstract Form to be...

  15. Heavy oil and tar sands recovery and upgrading. International technology

    SciTech Connect (OSTI)

    Schumacher, M.M.

    1982-01-01

    This work provides an in-depth assessment of international technology for the recovery and upgrading of heavy crude oil and tar sands. The technologies included are currently in use, under development, or planned; emphasis is placed on post-1978 activities. The heavy oil technologies and processes considered include methods relating to the exploitation of heavy oil reservoirs, such as production from underground workings, all types of improved or enhanced recovery, subsurface extraction, and well rate stimulation. The tar sands section includes sizing the resource base and reviewing and evaluating past, present, and planned research and field developments on processes for mining, producing, extracting, and upgrading very heavy oils recovered from tar sands, e.g., bitumen recovery from tar sands where primary production was impossible because of the oil's high viscosity. 616 references.

  16. SANDIA REPORT SAND2013-5238 Unlimited Release

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5238 Unlimited Release July 2013 Water Use and Supply Concerns for Utility-Scale Solar ... SAND2013-5238 Unlimited Release July 2013 Water Use and Supply Concerns for Utility-Scale ...

  17. Creating and maintaining a gas cap in tar sands formations

    DOE Patents [OSTI]

    Vinegar, Harold J. (Bellaire, TX); Karanikas, John Michael (Houston, TX); Dinkoruk, Deniz Sumnu (Houston, TX); Wellington, Scott Lee (Bellaire, TX)

    2010-03-16

    Methods for treating a tar sands formation are disclosed herein. Methods for treating a tar sands formation may include providing heat to at least part of a hydrocarbon layer in the formation from one or more heaters located in the formation. Pressure may be allowed to increase in an upper portion of the formation to provide a gas cap in the upper portion. At least some hydrocarbons are produced from a lower portion of the formation.

  18. Nondestructive Evaluation and Monitoring Projects NASA White Sands Test

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Facility (WSTF) | Department of Energy Nondestructive Evaluation and Monitoring Projects NASA White Sands Test Facility (WSTF) Nondestructive Evaluation and Monitoring Projects NASA White Sands Test Facility (WSTF) These slides were presented at the Onboard Storage Tank Workshop on April 29, 2010. nondestructiveevaluation_nasa_ostw.pdf (1.93 MB) More Documents & Publications Non Destructive Evaluation (NDE) Methods for Certification and Production/Performance Monitoring of Composite

  19. Western tight gas sands advanced logging workshop proceedings

    SciTech Connect (OSTI)

    Jennings, J B; Carroll, Jr, H B

    1982-04-01

    An advanced logging research program is one major aspect of the Western Tight Sands Program. Purpose of this workshop is to help BETC define critical logging needs for tight gas sands and to allow free interchange of ideas on all aspects of the current logging research program. Sixteen papers and abstracts are included together with discussions. Separate abstracts have been prepared for the 12 papers. (DLC)

  20. The extraction of bitumen from western tar sands. Annual report, July 1990--July 1991

    SciTech Connect (OSTI)

    Oblad, A.G.; Bunger, J.W.; Deo, M.D.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1992-04-01

    Contents of this report include the following: executive summary; characterization of the native bitumen from the Whiterocks oil sand deposit; influence of carboxylic acid content on bitumen viscosity; water based oil sand separation technology; extraction of bitumen from western oil sands by an energy-efficient thermal method; large- diameter fluidized bed reactor studies; rotary kiln pyrolysis of oil sand; catalytic upgrading of bitumen and bitumen derived liquids; ebullieted bed hydrotreating and hydrocracking; super critical fluid extraction; bitumen upgrading; 232 references; Appendix A--Whiterocks tar sand deposit bibliography; Appendix B--Asphalt Ridge tar sand deposit bibliography; and Appendix C--University of Utah tar sands bibliography.

  1. Processing of transparent polycrystalline AlON:Ce3+ scintillators

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chen, Ching -Fong; Yang, Pin; King, Graham; Tegtmeier, Eric L.

    2015-10-23

    A new polycrystalline ceramic scintillator is reported for potential use in radiation detection and medical imaging applications. The goal was to develop cerium-activated aluminum oxynitride (AlON:Ce3+) ceramics, which can be produced using ceramic processes in comparison to the high-cost, low-yield single-crystal growth technique. A phase pure AlON:Ce3+ powder with cubic symmetry was successfully synthesized at high temperature under a reducing atmosphere to convert Ce4+ to Ce3+ in the solid solution. We explored two different activator concentrations (0.5 and 1.0 mol%). Fully dense and transparent AlON:Ce3+ ceramics were produced by a liquid-phase-assisted pressureless sintering. The crystal field splitting around the Ce3+more » activator in the AlON was comparable to the splitting induced by Br₋ and the Cl₋ ligands, which produced an emission spectrum perfectly matching the maximum quantum efficiency range of the photomultiplier tube for radiation detection. Both optical excitation and radiation ionizations in AlON:Ce3+ were demonstrated. Lastly, challenges and mechanisms related to the radioluminescence efficiency are discussed.« less

  2. Evidence of dynamical spin shielding in Ce from spin-resolved...

    Office of Scientific and Technical Information (OSTI)

    Evidence of dynamical spin shielding in Ce from spin-resolved photoelectron spectroscopy Citation Details In-Document Search Title: Evidence of dynamical spin shielding in Ce from ...

  3. Sedimentary structures and textures of Rio Orinoco channel sands, Venezuela and Colombia

    SciTech Connect (OSTI)

    McKee, E.D.

    1989-01-01

    The majority of the sedimentary structures in the channel sands of the Orinoco River are planar cross-strata that are products of sand-wave deposition. Sands in these deposits are mostly medium-grained. Eolian dunes form on top of the sand waves when they are exposed to the trade winds at low river stages. The windblown sands are typically fine-grained.

  4. Maxlite: Order (2010-CE-2701) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Maxlite: Order (2010-CE-2701) Maxlite: Order (2010-CE-2701) In the Matter of Maxlite, SK America, Inc. (general service flourescent lamps), DOE Case Number 2010-CE-2701, Adopting Order and Compromise Agreement. Order adopting accompanying Compromise Agreement. DOE found that Maxlite failed to submit compliance certifications for its products under 10 C.F.R. Section 430.62, and here assesses a civil penalty of $5,000 (if paid within 30 days) or of $10,000 (if paid between 31-60 days). Maxlite

  5. Paragon Sales: Order (2012-CE-1417) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Order (2012-CE-1417) July 30, 2012 DOE ordered Paragon Sales Co., Inc., to pay a 6,000 civil penalty after finding Paragon Sales had failed to certify that certain models of...

  6. Manitowoc Foodservice: Order (2012-CE-5309) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Order (2012-CE-5309) July 20, 2012 DOE ordered Manitowoc Foodservice to pay an 6,000 civil penalty after finding Manitowoc Foodservice had failed to certify that Manitowoc...

  7. Electrolux: Order (2012-CE-1901) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Order (2012-CE-1901) July 27, 2012 DOE ordered Electrolux North America to pay a 6,500 civil penalty after finding Electrolux had failed to certify that certain dishwashers comply...

  8. Haier: Order (2011-CE-2104) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Haier: Order (2011-CE-2104) June 12, 2012 DOE ordered Haier to pay an 20,000 civil penalty after finding Haier had failed to certify that Haier residential clothes...

  9. Danby Products: Order (2012-CE-1415) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Order (2012-CE-1415) August 9, 2012 DOE ordered Danby Products to pay a 9,900 civil penalty after finding Danby had failed to certify that certain models of refrigerators...

  10. CE2 Carbon Capital LLC | Open Energy Information

    Open Energy Info (EERE)

    Carbon Capital LLC Jump to: navigation, search Name: CE2 Carbon Capital LLC Place: California Sector: Carbon, Renewable Energy Product: US-based carbon trader that looks to take...

  11. Utility: Proposed Penalty (2016-CE-42007) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Proposed Penalty (2016-CE-42007) Utility: Proposed Penalty (2016-CE-42007) November 30, 2015 DOE alleged in a Notice of Proposed Civil Penalty that Utility Refrigerator failed to certify certain commercial refrigerator equipment as compliant with the applicable energy conservation standards. DOE regulations require a manufacturer (which includes importers) to submit reports certifying that its products have been tested and meet the applicable energy conservation standards. This civil penalty

  12. Fujitsu: Order (2015-CE-16014) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fujitsu: Order (2015-CE-16014) Fujitsu: Order (2015-CE-16014) October 27, 2015 DOE ordered Fujitsu General America, Inc. to pay a $8,000 civil penalty after finding Fujitsu had failed to certify that certain models of central air conditioners and heat pumps comply with the applicable energy conservation standards prior to distributing them in commerce. The Order adopted a Compromise Agreement, which reflected settlement terms between DOE and Fujitsu. DOE regulations require a manufacturer (which

  13. Lochinvar: Order (2016-CE-24001) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lochinvar: Order (2016-CE-24001) Lochinvar: Order (2016-CE-24001) November 2, 2015 DOE ordered Lochinvar, LLC, to pay a $8,000 civil penalty after finding Lochinvar had failed to certify that certain models of pool heaters comply with the applicable energy conservation standard. The Order adopted a Compromise Agreement, which reflected settlement terms between DOE and Lochinvar. DOE regulations require a manufacturer (which includes importers) to submit reports certifying that its products have

  14. Systemair: Order (2016-CE-43003) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Systemair: Order (2016-CE-43003) Systemair: Order (2016-CE-43003) February 23, 2016 DOE ordered Systemair, Inc., to pay a $8,000 civil penalty after finding Systemair had failed to certify that its single package vertical air conditioning and heating equipment comply with the applicable energy conservation standards. The Order adopted a Compromise Agreement, which reflected settlement terms between DOE and Systemair. DOE regulations require a manufacturer (which includes importers) to submit

  15. Temspec: Proposed Penalty (2016-CE-43002) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Proposed Penalty (2016-CE-43002) Temspec: Proposed Penalty (2016-CE-43002) February 5, 2016 DOE alleged in a Notice of Proposed Civil Penalty that Temspec Incorporated failed to certify various basic models of single package vertical air conditioning and heating equipment as compliant with the applicable energy conservation standards. DOE regulations require a manufacturer (which includes importers) to submit reports certifying that its products have been tested and meet the applicable energy

  16. Ca2+-Doped CeBr3 Scintillating Materials

    SciTech Connect (OSTI)

    Guss, Paul; Foster, Michael E.; Wong, Bryan M.; Doty, F. Patrick; Shah, Kanai; Squillante, Michael R.; Shirwadkar, Urmila; Hawrami, Rastgo; Tower, Josh; Yuan, Ding

    2014-01-21

    Despite the outstanding scintillation performance characteristics of cerium tribromide (CeBr3) and cerium-activated lanthanum tribromide, their commercial availability and application are limited due to the difficulties of growing large, crack-free single crystals from these fragile materials. This investigation employed aliovalent doping to increase crystal strength while maintaining the optical properties of the crystal. One divalent dopant (Ca2+) was used as a dopant to strengthen CeBr3 without negatively impacting scintillation performance. Ingots containing nominal concentrations of 1.9% of the Ca2+ dopant were grown. Preliminary scintillation measurements are presented for this aliovalently doped scintillator. Ca2+-doped CeBr3 exhibited little or no change in the peak fluorescence emission for 371 nm optical excitation for CeBr3. The structural, electronic, and optical properties of CeBr3 crystals were studied using the density functional theory within the generalized gradient approximation. The calculated lattice parameters are in good agreement with the experimental data. The energy band structures and density of states were obtained. The optical properties of CeBr3, including the dielectric function, were calculated.

  17. Investigation of guided waves propagation in pipe buried in sand

    SciTech Connect (OSTI)

    Leinov, Eli; Cawley, Peter; Lowe, Michael J.S.

    2014-02-18

    The inspection of pipelines by guided wave testing is a well-established method for the detection of corrosion defects in pipelines, and is currently used routinely in a variety of industries, e.g. petrochemical and energy. When the method is applied to pipes buried in soil, test ranges tend to be significantly compromised because of attenuation of the waves caused by energy radiating into the soil. Moreover, the variability of soil conditions dictates different attenuation characteristics, which in-turn results in different, unpredictable, test ranges. We investigate experimentally the propagation and attenuation characteristics of guided waves in pipes buried in fine sand using a well characterized full scale experimental apparatus. The apparatus consists of an 8 inch-diameter, 5.6-meters long steel pipe embedded over 3 meters of its length in a rectangular container filled with fine sand, and an air-bladder for the application of overburden pressure. Longitudinal and torsional guided waves are excited in the pipe and recorded using a transducer ring (Guided Ultrasonics Ltd). Acoustic properties of the sand are measured independently in-situ and used to make model predictions of wave behavior in the buried pipe. We present the methodology and the systematic measurements of the guided waves under a range of conditions, including loose and compacted sand. It is found that the application of overburden pressure modifies the compaction of the sand and increases the attenuation, and that the measurement of the acoustic properties of sand allows model prediction of the attenuation of guided waves in buried pipes with a high level of confidence.

  18. Comparison of the high-pressure behavior of the cerium oxides Ce2O3 and CeO2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lipp, M. J.; Jeffries, J. R.; Cynn, H.; Park Klepeis, J. -H.; Evans, W. J.; Mortensen, D. R.; Seidler, G. T.; Xiao, Y.; Chow, P.

    2016-02-09

    We studied the high-pressure behavior of Ce2O3 using angle-dispersive x-ray diffraction to 70 GPa and compared with that of CeO2. Up to the highest pressure Ce2O3 remains in the hexagonal phase (space group 164, P ¯32/m1) typical for the lanthanide sesquioxides. We did not observe a theoretically predicted phase instability for 30 GPa. The isothermal bulk modulus and its pressure derivative for the quasihydrostatic case are B0 = 111 ± 2 GPa, B'0 = 4.7 ± 0.3, and for the case without pressure-transmitting medium B0 = 104 ±4 GPa, B'0 = 6.5 ± 0.4. Starting from ambient-pressure magnetic susceptibility measurementsmore » for both oxides in highly purified form,we find that the Ce atom in Ce2O3 behaves like a trivalent Ce3+ ion (2.57μB per Ce atom) in contrast to previously published data. Since x-ray emission spectroscopy of the Lγ (4d3/2 → 2p1/2) transition is sensitive to the 4f -electron occupancy, we also followed the high-pressure dependence of this line for both oxides up to 50 GPa. We observed no change of the respective line shape, indicating that the 4f -electron configuration is stable for both materials. We posit from this data that the 4f electrons do not drive the volume collapse of CeO2 from the high-symmetry, low-pressure fluorite structure to the lower-symmetry orthorhombic phase.« less

  19. Patriotic Sands Form the Science of Summer | GE Global Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Patriotic Sands Form the Science of Summer Click to email this to a friend (Opens in new window) Share on Facebook (Opens in new window) Click to share (Opens in new window) Click to share on LinkedIn (Opens in new window) Click to share on Tumblr (Opens in new window) Patriotic Sands Form the Science of Summer Adam Rasheed 2012.07.03 Happy 4th of July everyone! As we gear up to celebrate Independence Day with fireworks and barbecues in the sweltering heat, we wanted to figure out a fun way to

  20. Case study of a multiple sand waterflood, Hewitt Unit, OK

    SciTech Connect (OSTI)

    Ruble, D.B.

    1982-03-01

    Twenty-two sands in the Hewitt field have been flooded simultaneously by Exxon Co. U.S.A.'s Hewitt Unit, and a case history of the operations is detailed. A multiple sand waterflood project requires special optimization methods to improve oil recovery. Injection and production surveillance programs and optimization methods used are highlighted. These include injection wellbore design, injection distribution, production stimulation, polymer augmented injection, and infill drilling. Successful application of these techniques has increased ultimate recovery from this waterflood operation. 3 refs.

  1. Western Gas Sands Project: stratigrapy of the Piceance Basin

    SciTech Connect (OSTI)

    Anderson, S.

    1980-08-01

    The Western Gas Sands Project Core Program was initiated by US DOE to investigate various low permeability, gas bearing sandstones. Research to gain a better geological understanding of these sandstones and improve evaluation and stimulation techniques is being conducted. Tight gas sands are located in several mid-continent and western basins. This report deals with the Piceance Basin in northwestern Colorado. This discussion is an attempt to provide a general overview of the Piceance Basin stratigraphy and to be a useful reference of stratigraphic units and accompanying descriptions.

  2. Heavy liquid beneficiation developed for Alabama tar sands

    SciTech Connect (OSTI)

    Not Available

    1986-12-01

    The tar sand deposits in the State of Alabama contain about 1.8 billion barrels of measured and more than 4 billion barrels of speculative in-place bitumen. A comprehensive research program is in progress for the separation of bitumen from these deposits. In general, Alabama tar sands are oil wetted, low grade and highly viscous in nature. In view of these facts, a beneficiation strategy has been developed to recover bitumen enriched concentrate which can be used as a feed material for further processing. Heavy liquid separation tests and results are discussed. A 77% zinc bromide solution, specific gravity of 2.4, was used for the tests. 2 figures.

  3. Milling of Sand Blocks to Make Casting Moulds

    SciTech Connect (OSTI)

    Lopez de Lacalle, L. N.; Rodriguez, A.; Lamikiz, A.; Penafiel, F. J. [Department of Mechanical Engineering, University of the Basque Country, ETSII, c/Alameda de Urquijo s/n, 48013 Bilbao (Spain)

    2011-01-17

    In this paper a full procedure to make moulds in sand for direct casting of metallic parts is presented. The technology aims at unique pieces or art pieces, where only one prototype or components is required, but lead times are much reduced. The key of the procedure is to achieve enough tool life when milling with carbide tools, avoiding the risk of sand destruction or damage.The use of inverse techniques is a common input due to the industrial sectors where the direct milling is interesting. Two examples of moulds are presented, evaluating times and costs. A special study of tool wear is also presented.

  4. Effects of CeO2 Support Facets on VOx/CeO2 Catalysts in Oxidative Dehydrogenation of Methanol

    SciTech Connect (OSTI)

    Li, Yan; Wei, Zhehao; Gao, Feng; Kovarik, Libor; Peden, Charles HF; Wang, Yong

    2014-05-13

    CeO2 supports with dominating facets, i.e., low index (100), (110) and (111) facets, are prepared. The facet effects on the structure and catalytic performance of supported vanadium oxide catalysts are investigated using oxidative dehydrogenation of methanol as a model reaction. In the presence of mixed facets, Infrared and Raman characterizations demonstrate that surface vanadia species preferentially deposit on CeO2 (100) facets, presumably because of its higher surface energy. At the same surface vanadium densities, VOx species on (100) facets show better dispersion, followed by (110) and (111) facets. The VOx species on CeO2 nanorods with (110) and (100) facets display higher activity and lower apparent activation energies compared to that on CeO2 nanopolyhedras with dominating (111) facets and CeO2 nanocubes with dominating (100) facets. The higher activity for VOx/CeO2(110) might be related to the more abundant oxygen vacancies present on the (110) facets, evidenced from Raman spectroscopic measurements.

  5. Ecology of Pacific Northwest coastal sand dunes: a community profile

    SciTech Connect (OSTI)

    Wiedemann, A.M.

    1984-03-01

    Sand dunes occur in 33 localities along the 950 km of North American Pacific coast between the Straits of Juan de Fuca (49/sup 0/N) and Cape Mendocino (40/sup 0/). The dune landscape is a mosaic of dune forms: transverse ridge, oblique dune, retention ridge, foredune, parabola dune, sand hummock, blowout, sand plain, deflation plain, dune ridge, swale, remnant forest, and ponds and lakes. These forms are the basic morphological units making up the four dune systems: parallel ridge, parabola dune, transverse ridge, and bay dune. Vegetation is well-developed on stabilized dunes. Of the 21 plant communities identified, nine are herbaceous, five are shrub, and seven are forest. A wide variety of vertebrate animals occur in seven distinct habitats: open dunes, grassland and meadow, shrub thicket, forest, marsh, riparian, and lakes and ponds. Urban development, increased rate of stabilization due to the introduction of European beachgrass (Ammophila arenaria (L.) Link), and massive disturbance resulting from heavy off-road vehicle traffic are the greatest threats to the long-term survival and stability of a number of sand dune habitats. Two animals and three plants dependent on dune habitats are listed as rare, threatened, or endangered. 93 references, 52 figures, 13 tables.

  6. Sediment volume in the north polar sand seas of Mars

    SciTech Connect (OSTI)

    Lancaster, N.; Greeley, R. (Arizona State Univ., Tempe (USA))

    1990-07-10

    Data from studies of the cross-sectional area of terrestrial transverse dunes have been combined with maps of dune morphometry derived from Viking orbiter images to generate new estimates of sediment thickness and dune sediment volume in the north polar sand seas of Mars. A relationship between dune spacing and equivalent sediment thickness (EST) was developed from field data on Namibian and North American dunes and was applied to data on dune spacing and dune cover measured on Viking orbiter images to generate maps of dune sediment thickness for Martian north polar sand seas. There are four major sand seas in the north polar region of Mars, covering an area of 6.8 x 10{sup 5} km{sup 2}. Equivalent sediment thickness ranges between 0.5 and 6.1 m with a mean of 1.8 m. The sand seas contain a total of 1158 km{sup 3} of dune sediment, which may have been derived by erosion of polar layered deposits and concentrated in its present location by winds that change direction seasonally.

  7. An Update on NiCE Support for BISON

    SciTech Connect (OSTI)

    McCaskey, Alex; Billings, Jay Jay; Deyton, Jordan H.; Wojtowicz, Anna

    2015-09-01

    The Nuclear Energy Advanced Modeling and Simulation program (NEAMS) from the Department of Energy s Office of Nuclear Energy has funded the development of a modeling and simulation workflow environment to support the various codes in its nuclear energy scientific computing toolkit. This NEAMS Integrated Computational Environment (NiCE) provides extensible tools and services that enable efficient code execution, input generation, pre-processing visualizations, and post-simulation data analysis and visualization for a large portion of the NEAMS Toolkit. A strong focus for the NiCE development team throughout FY 2015 has been support for the Multiphysics Object Oriented Simulation Environment (MOOSE) and the NEAMS nuclear fuel performance modeling application built on that environment, BISON. There is a strong desire in the program to enable and facilitate the use of BISON throughout nuclear energy research and industry. A primary result of this desire is the need for strong support for BISON in NiCE. This report will detail improvements to NiCE support for BISON. We will present a new and improved interface for interacting with BISON simulations in a variety of ways: (1) improved input model generation, (2) embedded mesh and solution data visualizations, and (3) local and remote BISON simulation launch. We will also show how NiCE has been extended to provide support for BISON code development.

  8. In situ recovery of oil from Utah tar sand: a summary of tar sand research at the Laramie Energy Technology Center

    SciTech Connect (OSTI)

    Marchant, L.C.; Westhoff, J.D.

    1985-10-01

    This report describes work done by the United States Department of Energy's Laramie Energy Technology Center from 1971 through 1982 to develop technology for future recovery of oil from US tar sands. Work was concentrated on major US tar sand deposits that are found in Utah. Major objectives of the program were as follows: determine the feasibility of in situ recovery methods applied to tar sand deposits; and establish a system for classifying tar sand deposits relative to those characteristics that would affect the design and operation of various in situ recovery processes. Contents of this report include: (1) characterization of Utah tar sand; (2) laboratory extraction studies relative to Utah tar sand in situ methods; (3) geological site evaluation; (4) environmental assessments and water availability; (5) reverse combustion field experiment, TS-1C; (6) a reverse combustion followed by forward combustion field experiment, TS-2C; (7) tar sand permeability enhancement studies; (8) two-well steam injection experiment; (9) in situ steam-flood experiment, TS-1S; (10) design of a tar sand field experiment for air-stream co-injection, TS-4; (11) wastewater treatment and oil analyses; (12) economic evaluation of an in situ tar sand recovery process; and (13) appendix I (extraction studies involving Utah tar sands, surface methods). 70 figs., 68 tabs.

  9. TO:

    Office of Legacy Management (LM)

    would buy from the Davison Chemical Company thorium hydrcxide which they had processed. ... would in turn supply the AEC the thorium hydroxide they processed from the monazite sands. ...

  10. Homoleptic Ce(III) and Ce(IV) Nitroxide Complexes: Significant Stabilization of the 4+ Oxidation State

    SciTech Connect (OSTI)

    Bogart, Justin A.; Lewis, Andrew J.; Medling, Scott A.; Piro, Nicholas A.; Carroll, Patrick J.; Booth, Corwin H.; Schelter, Eric J.

    2014-06-25

    Electrochemical experiments performed on the complex Ce-IV[2-((BuNO)-Bu-t)py](4), where [2-((BuNO)-Bu-t)py](-) = N-tert-butyl-N-2-pyridylnitroxide, indicate a 2.51 V stabilization of the 4+ oxidation state of Ce compared to [(Bu4N)-Bu-n](2)[Ce(NO3)(6)] in acetonitrile and a 2.95 V stabilization compared to the standard potential for the ion under aqueous conditions. Density functional theory calculations suggest that this preference for the higher oxidation state is a result of the tetrakis(nitroxide) ligand framework at the Ce cation, which allows for effective electron donation into, and partial covalent overlap with, vacant 4f orbitals with delta symmetry. The results speak to the behavior of CeO2 and related solid solutions in oxygen uptake and transport applications, in particular an inherent local character of bonding that stabilizes the 4+ oxidation state. The results indicate a cerium(IV) complex that has been stabilized to an unprecedented degree through tuning of its ligand-field environment.

  11. The extraction of bitumen from western oil sands. Final report, July 1989--September 1993

    SciTech Connect (OSTI)

    Oblad, A.G.; Bunger, J.W.; Dahlstrom, D.A.; Deo, M.D.; Fletcher, J.V.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1994-03-01

    Research and development of surface extraction and upgrading processes of western tar sands are described. Research areas included modified hot water, fluidized bed, and rotary kiln pyrolysis of tar sands for extraction of bitumen. Bitumen upgrading included solvent extraction of bitumen, and catalytic hydrotreating of bitumen. Characterization of Utah tar sand deposits is also included.

  12. Numerical solution of sand transport in hydraulic fracturing

    SciTech Connect (OSTI)

    Daneshy, A.A.; Crichlow, H.B.

    1980-02-07

    A numerical solution is developed for the deposition of a propping agent inside a hydraulic fracture. Such parameters as fluid leak-off into the formation, increase in sand concentration caused by leak-off, non-Newtonian fracturing fluids, hindered settling velocity, and an up-to-date geometry are taken into consideration. Three examples investigate the proppant deposition for low-, medium-, and high-viscosity fracturing fluids.

  13. EA-1978: Sand Creek Winds, McCone County, Montana

    Office of Energy Efficiency and Renewable Energy (EERE)

    Western Area Power Administration (Western) is preparing an EA to analyze the potential environmental impacts of the proposed Sand Creek Winds Project, a 75-MW wind farm between the towns of Circle and Wolf Point in McCone County, Montana. The proposed wind farm would interconnect to Western’s existing Wolf Point to Circle 115-kV transmission line approximately 18 miles north of Wolf Point.

  14. SANDIA REPORT SAND2014-3416 Unlimited Release

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SANDIA REPORT SAND2014-3416 Unlimited Release Printed April 2014 Safety, Codes and Standards for Hydrogen Installations: Hydrogen Fueling System Footprint Metric Development A.P. Harris, Daniel E. Dedrick, Chris LaFleur, Chris San Marchi Prepared by Sandia National Laboratories Albuquerque, New Mexico 87185 and Livermore, California 94550 Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin

  15. Heavy oil and tar sands recovery and upgrading: international technology

    SciTech Connect (OSTI)

    Schumacher, M.M.

    1982-01-01

    This book provides an in-depth assessment of international technology for the recovery and upgrading of heavy crude oil and tar sands. The technologies included are currently in use, under development, or planned; emphasis is placed on post-1978 activities. The heavy oil technologies and processes considered in Part I include methods relating to the exploitation of heavy oil reservoirs, such as production from undergorun workings, all types of improved or enhanced recovery, subsurface extraction, and well rate stimulation. Furthermore, even though heavy crudes are understood to include only those liquid or semiliquid hydrocarbons with a gravity of 20/sup 0/API or less, technology applied to lighter crude oils with in situ viscosities of the same order of magnitude as some US heavy oils is also included. The scope of the tar sands section (Part II) includes sizing the resource base and reviewing and evaluatin past, present, and planned research and field developments on processes for mining, producing, extracting, and upgrading very heavy oils recovered from tar sands, e.g., bitumen recovery from tar sands where primary production was impossible because of the oil's high viscosity. On the production side, very heavy oil is defined as having a gravity less than 10/sup 0/ to 12/sup 0/API and greater than 100,000-centipoise viscosity at 50/sup 0/F. On the upgrading side, hydrocarbons whose characteristics dictated additional processing prior to conventional refining into salable products (1050+/sup 0/ material) were included, regardless of origin, in order to encompass all pertinent upgrading technologies.

  16. SANDIA REPORT SAND2014-1535 Unlimited Release

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    SANDIA REPORT SAND2014-1535 Unlimited Release Printed March 2014 The Advanced Microgrid Integration and Interoperability Ward Bower, Ward Bower Innovations LLC Dan Ton, U.S. Department of Energy; Office of Electricity Delivery & Energy Reliability Ross Guttromson, Sandia National Laboratories Steve Glover, Sandia National Laboratories Jason Stamp, Sandia National Laboratories Dhruv Bhatnagar, Sandia National Laboratories Jim Reilly, Reilly Associates Prepared by Sandia National Laboratories

  17. High resolution evaluation techniques in thinly laminated shaly sands

    SciTech Connect (OSTI)

    Coll, C.; Chacartegui, F.; Suarez, O.; Alvarez, G. ); Monsegui, G.; Lambertini, R.; Haines, P. )

    1993-02-01

    Significant hydrocarbon production may occur from thin layers which were previously considered non-economic. Improved processing methods for detecting and evaluating thin beds have shown these reservoirs to be attractive prospects. Such thinly bedded laminated shale-sand sequences exist within some of the producing formations in Venezuela. These shale sand packages may contain significant bypassed or undeveloped reserves. A new technique using deconvolution of the deep resistivity through the microresistivity curves (Microlog) identifies potential thinly bedded reservoirs. This methodology appears to be the most reliable permeability indicator of the prospective intervals within the Misoa Formation at Ceuta Field in Maracaibo Lake. The prospective intervals within this field have been calibrated with cores and with sedimentological information. This calibration shows only two lithofacies contained hydrocarbons previously not evaluated as oil saturated by traditional methods. These facies exhibited low values for deep resistivity curves which indicated high levels of water saturation. Deep resistivity deconvolution processing has been successfully applied to solve this problem in the Ceuta field. The resulting resistivity curve exhibits a vertical resolution of better than 1 ft., while retaining the essential advantages of deep resistivity curve. Laminated sand analyses were carried out and prove to be very useful in the integration of petrophysical and sedimentological data for detection of prospective intervals.

  18. Insulation from basaltic stamp sand. Final technical report

    SciTech Connect (OSTI)

    Williams, F. D.

    1981-04-01

    A Midwest Appropriate Technology Grant was awarded to determine the technical and economic feasibility of producing mineral-fiber insulation directly from extensive deposits of basaltic sand produced during former mining and milling operations in the Keweenaw Peninsula region of Michigan's Upper Peninsula. The amounts of local basaltic sands available and representative chemical compositions were determined. The variation of viscosity with temperature and chemical composition was estimated. Samples were melted and either pulled or blown into fiber. In all cases fiber could be made with a reasonable tensile strength to ensure usefulness. It was concluded that it was technically feasible to produce fibers from basaltic stamp sands of the Upper Peninsula of Michigan. A technical feasibility study using published data, a cost and design analysis of a basalt fiber production plant, a market survey of fiber needs, and an economic analysis for investing in a basalt fiber venture was undertaken. These studies concluded that the local production of basaltic insulation was both feasible and economically reasonable. It was suggested that the plant be located in a region of greater population density with lower utility costs. A representative one-third of these studies is included as appendices A, B, C, and D.

  19. Angle Resolved Thermal Conductivity of CeCoIn5 along the Nodal...

    Office of Scientific and Technical Information (OSTI)

    Angle Resolved Thermal Conductivity of CeCoIn5 along the Nodal Direction Citation Details In-Document Search Title: Angle Resolved Thermal Conductivity of CeCoIn5 along the Nodal ...

  20. Effect of Sodium on the Catalytic Properties of VOx/CeO2 Catalysts...

    Office of Scientific and Technical Information (OSTI)

    addition greatly alters the nature of the active sites by V-O-Ce bond cleavage and V-O-Na bond formation, leading to significantly reduced activity of the VOxCeO2 catalysts. ...

  1. SEMI-ANNUAL REPORTS FOR CE FLNG, LLC (CAMBRIDGE) - DK. NO. 12...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CE FLNG, LLC (CAMBRIDGE) - DK. NO. 12-123-LNG - ORDER 3193 SEMI-ANNUAL REPORTS FOR CE FLNG, LLC (CAMBRIDGE) - DK. NO. 12-123-LNG - ORDER 3193 PDF icon April 2013 PDF icon October...

  2. DOI-BLM-ID-110-2009-3825-CE | Open Energy Information

    Open Energy Info (EERE)

    110-2009-3825-CE Jump to: navigation, search NEPA Document Collection for: DOI-BLM-ID-110-2009-3825-CE CX at Crane Creek Geothermal Area for GeothermalExploration Crane Creek...

  3. NMR studies of field induced magnetism in CeCoIn5 (Journal Article...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: NMR studies of field induced magnetism in CeCoIn5 Citation Details In-Document Search Title: NMR studies of field induced magnetism in CeCoIn5 You are accessing ...

  4. Investigation of the physical properties of the tetragonal CeMAl4Si2...

    Office of Scientific and Technical Information (OSTI)

    the tetragonal CeMAl4Si2 (M Rh, Ir, Pt) compounds Prev Next Title: Investigation of the physical properties of the tetragonal CeMAl4Si2 (M Rh, Ir, Pt) compounds The ...

  5. Evaluation of production samples of the scintillators LaBr3:Ce andLaCl3:Ce

    SciTech Connect (OSTI)

    Choong, Woon-Seng; Derenzo, Stephen E.; Moses, William W.

    2005-09-15

    We report on the evaluation of the performance of two recently developed scintillator materials, LaCl{sub 3}:Ce and LaBr{sub 3}:Ce, at the task of gamma ray spectroscopy. Their performance is compared to a standard scintillator used for gamma ray spectroscopy--a 25 mm diameter 25 mm tall cylinder of NaI:Tl. We measure the pulse height, energy resolution, and full-energy efficiency of production LaBr{sub 3}:Ce and LaCl{sub 3}:Ce scintillation crystals of different sizes and geometries for a variety of gamma-ray energies. Using production rather than specially selected crystals will establish whether immediate large-scale use is feasible. The crystal is excited by gamma rays from one of six isotopic sources ({sup 125}I, {sup 241}Am, {sup 57}Co, {sup 22}Na, {sup 137}Cs, and {sup 60}Co) placed 15 cm away from the scintillator. Our measurements show that both LaCl{sub 3} and LaBr{sub 3} outperform NaI:Tl in almost all cases. They outperform NaI:Tl at all energies for the photopeak fraction and counting rate measurements, and for energy resolution at higher energies (above 200 keV for LaCl{sub 3} and 75 keV for LaBr{sub 3}). The performance of production crystals is excellent and these scintillators should be considered for immediate use in systems where stopping power and energy resolution are crucial.

  6. CO Oxidation mechanism on CeO2-supported Au nanoclusters

    SciTech Connect (OSTI)

    Kim H. Y.; Henkelman, G.

    2013-09-08

    To reveal the richer chemistry of CO oxidation by CeO2 supported Au Nanoclusters(NCs)/Nanoparticles, we design Au13 and Au12 supported on a flat and a stepped-CeO2 model (Au/CeO2) and study various kinds of CO oxidation mechanisms at the Au-CeO2 interface and the Au NC as well.

  7. Neutron scattering of CeNi at the SNS-ORNL: A preliminary report

    SciTech Connect (OSTI)

    Mirmelstein, A. [Russian Federal Nuclear Center VNIITF, Snezhinsk, Russia; Podlesnyak, Andrey A [ORNL; Kolesnikov, Alexander I [ORNL; Saporov, B. [Oak Ridge National Laboratory (ORNL); Sefat, A.S. [Oak Ridge National Laboratory (ORNL); Tobin, J. G. [Lawrence Livermore National Laboratory (LLNL)

    2014-01-01

    This is a preliminary report of a neutron scattering experiment used to investigate 4f electron behavior in Ce.

  8. The extraction of bitumen from western oil sands: Volume 2. Final report

    SciTech Connect (OSTI)

    Oblad, A.G.; Dahlstrom, D.A.; Deo, M.D.; Fletcher, J.V.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1997-11-26

    The program is composed of 20 projects, of which 17 are laboratory bench or laboratory pilot scale processes or computer process simulations that are performed in existing facilities on the University of Utah campus in north-east Salt Lake City. These tasks are: (1) coupled fluidized-bed bitumen recovery and coked sand combustion; (2) water-based recovery of bitumen; (3) oil sand pyrolysis in a continuous rotary kiln reactor; (4) oil sand pyrolysis in a large diameter fluidized bed reactor; (5) oil sand pyrolysis in a small diameter fluidized bed reactor; (6) combustion of spent sand in a transport reactor; (7) recovery and upgrading of oil sand bitumen using solvent extraction methods; (8) fixed-bed hydrotreating of Uinta Basin bitumens and bitumen-derived hydrocarbon liquids; (9) ebullieted bed hydrotreating of bitumen and bitumen derived liquids; (10) bitumen upgrading by hydropyrolysis; (11) evaluation of Utah`s major oil sand deposits for the production of asphalt, high-energy jet fuels and other specialty products; (12) characterization of the bitumens and reservoir rocks from the Uinta Basin oil sand deposits; (13) bitumen upgrading pilot plant recommendations; (14) liquid-solid separation and fine tailings thickening; (15) in-situ production of heavy oil from Uinta Basin oil sand deposits; (16) oil sand research and development group analytical facility; and (17) process economics. This volume contains reports on nine of these projects, references, and a bibliography. 351 refs., 192 figs., 65 tabs.

  9. Assessment of the KE Basin Sand Filter Inventory In Support of Hazard Categorization

    SciTech Connect (OSTI)

    Ross, Steven B.; Young, Jonathan

    2005-09-28

    In 1978, the water cleaning system for the KE Basin was upgraded by adding a sand filter and ion exchange columns. Basin water containing finely divided solids is collected by three surface skimmers and pumped to the sand filter. Filtrate from the sand filter is further treated in the ion exchange modules. The suspended solids accumulate in the sand until the pressure drop across the filter reaches established operating limits, at which time the sand filter is backwashed. The backwash is collected in the NLOP, where the solids are allowed to settle as sludge. Figure 2-1 shows a basic piping and instrumentation diagram depicting the relationship among the basin skimmers, sand filter, and NLOP. During the course of deactivation and decommissioning (D&D) of the K-Basins, the sand filter and its media will need to be dispositioned. The isotopic distribution of the sludge in the sand filter has been estimated in KE Basin Sand Filter Monolith DQO (KBC-24705). This document estimates the sand filter contribution to the KE hazard categorization using the data from the DQO.

  10. The extraction of bitumen from western oil sands: Volume 1. Final report

    SciTech Connect (OSTI)

    Oblad, A.G.; Dahlstrom, D.A.; Deo, M.D.; Fletcher, J.V.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1997-11-26

    The program is composed of 20 projects, of which 17 are laboratory bench or laboratory pilot scale processes or computer process simulations that are performed in existing facilities on the University of Utah campus in north-east Salt Lake City. These tasks are: (1) coupled fluidized-bed bitumen recovery and coked sand combustion; (2) water-based recovery of bitumen; (3) oil sand pyrolysis in a continuous rotary kiln reactor; (4) oil sand pyrolysis in a large diameter fluidized bed reactor; (5) oil sand pyrolysis in a small diameter fluidized bed reactor; (6) combustion of spent sand in a transport reactor; (7) recovery and upgrading of oil sand bitumen using solvent extraction methods; (8) fixed-bed hydrotreating of Uinta Basin bitumens and bitumen-derived hydrocarbon liquids; (9) ebullieted bed hydrotreating of bitumen and bitumen derived liquids; (10) bitumen upgrading by hydropyrolysis; (11) evaluation of Utah`s major oil sand deposits for the production of asphalt, high-energy jet fuels and other specialty products; (12) characterization of the bitumens and reservoir rocks from the Uinta Basin oil sand deposits; (13) bitumen upgrading pilot plant recommendations; (14) liquid-solid separation and fine tailings thickening; (15) in-situ production of heavy oil from Uinta Basin oil sand deposits; (16) oil sand research and development group analytical facility; and (17) process economics. This volume contains an executive summary and reports for five of these projects. 137 figs., 49 tabs.

  11. Lattice Disorder and Size-Induced Kondo Behavior in CeAl{sub 2} and CePt{sub 2+x}

    SciTech Connect (OSTI)

    Han, S.-W.; Booth, C. H.; Bauer, E. D.; Huang, P. H.; Chen, Y. Y.; Lawrence, J. M.

    2006-09-01

    When the size of CeAl{sub 2} and CePt{sub 2+x} particles is reduced to the nanometer scale, antiferromagnetism is suppressed and Kondo behavior predominates, with the Kondo temperature T{sub K} either decreasing (CeAl{sub 2}) or increasing (CePt{sub 2+x}) relative to the bulk. Local structure measurements show that these nanoparticles are significantly distorted. While such distortions should strongly affect magnetic and electronic properties, we find they cannot explain the observed changes in T{sub K}. Other size-induced changes to the electronic structure must, therefore, play a significant role.

  12. Thermoelectric Couple Demonstration of (In, Ce)-based Skutterudite

    Broader source: Energy.gov (indexed) [DOE]

    Powered Vehicle | Department of Energy Presentation given at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. deer10_schock.pdf (2.44 MB) More Documents & Publications Thermoelectric Conversion of Waste Materials for Automotive Energy Recovery | Department of Energy

    Presents recent accomplishments and couple test results with these (In, Ce)-based skutterudite TE materials and potential impacts TE power system

  13. Production from multiple zones of a tar sands formation

    DOE Patents [OSTI]

    Karanikas, John Michael; Vinegar, Harold J

    2013-02-26

    A method for treating a tar sands formation includes providing heat to at least part of a hydrocarbon layer in the formation from a plurality of heaters located in the formation. The heat is allowed to transfer from the heaters to at least a portion of the formation. Fluids are produced from the formation through at least one production well that is located in at least two zones in the formation. The first zone has an initial permeability of at least 1 darcy. The second zone has an initial of at most 0.1 darcy. The two zones are separated by a substantially impermeable barrier.

  14. Renewable Energy Opportunities at White Sands Missile Range, New Mexico

    SciTech Connect (OSTI)

    Chvala, William D.; Solana, Amy E.; States, Jennifer C.; Warwick, William M.; Weimar, Mark R.; Dixon, Douglas R.

    2008-09-01

    The document provides an overview of renewable resource potential at White Sands Missile Range (WSMR) based primarily upon analysis of secondary data sources supplemented with limited on-site evaluations. The effort was funded by the U.S. Army Installation Management Command (IMCOM) as follow-on to the 2005 DoD Renewable Energy Assessment. This effort focuses on grid-connected generation of electricity from renewable energy sources and also ground source heat pumps (GSHPs) for heating and cooling buildings, as directed by IMCOM.

  15. User`s manual for SNL-SAND-II code

    SciTech Connect (OSTI)

    Griffin, P.J.; Kelly, J.G.; VanDenburg, J.W.

    1994-04-01

    Sandia National Laboratories, in the process of characterizing the neutron environments at its reactor facilities, has developed an enhanced version of W. McElroy`s original SAND-II code. The enhanced input, output, and plotting interfaces make the code much easier to use. The basic physics and operation of the code remain unchanged. Important code enhancements include the interfaces to the latest ENDF/B-VI and IRDF-90 dosimetry-quality cross sections and the ability to use silicon displacement-sensitive devices as dosimetry sensors.

  16. Systems and methods for producing hydrocarbons from tar sands formations

    DOE Patents [OSTI]

    Li, Ruijian; Karanikas, John Michael

    2009-07-21

    A system for treating a tar sands formation is disclosed. A plurality of heaters are located in the formation. The heaters include at least partially horizontal heating sections at least partially in a hydrocarbon layer of the formation. The heating sections are at least partially arranged in a pattern in the hydrocarbon layer. The heaters are configured to provide heat to the hydrocarbon layer. The provided heat creates a plurality of drainage paths for mobilized fluids. At least two of the drainage paths converge. A production well is located to collect and produce mobilized fluids from at least one of the converged drainage paths in the hydrocarbon layer.

  17. Preliminary examination of oil bonding at sand surfaces and its influence on hot water separation

    SciTech Connect (OSTI)

    Hupka, J.; Budzich, M.; Miller, J.D.

    1991-01-01

    The efficiency of water-based separation of oil from sand particles is dependent on the nature of the oil-sand association and a preliminary examination of this bonding has been completed. The degree of hydration of the sand surface at the time of contact with oil was related to the subsequent efficiency of the oil-sand separation process. Variables which influence hot water separation were correlated by multiple linear regression, and a second order experimental model was obtained. The processing temperature appeared to be the most significant variable, followed by digestion time and pH. Oil-coated sand particles which had intrinsic water left on their surface during sample preparation were easily processed in hot water separation experiments, and 64 to 90% of the oil was removed. On the other hand, only 1 to 23% separation and oil recovery was possible when a calcinated sand-oil mixture was used.

  18. Preliminary examination of oil bonding at sand surfaces and its influence on hot water separation

    SciTech Connect (OSTI)

    Hupka, J.; Budzich, M.; Miller, J.D.

    1991-12-31

    The efficiency of water-based separation of oil from sand particles is dependent on the nature of the oil-sand association and a preliminary examination of this bonding has been completed. The degree of hydration of the sand surface at the time of contact with oil was related to the subsequent efficiency of the oil-sand separation process. Variables which influence hot water separation were correlated by multiple linear regression, and a second order experimental model was obtained. The processing temperature appeared to be the most significant variable, followed by digestion time and pH. Oil-coated sand particles which had intrinsic water left on their surface during sample preparation were easily processed in hot water separation experiments, and 64 to 90% of the oil was removed. On the other hand, only 1 to 23% separation and oil recovery was possible when a calcinated sand-oil mixture was used.

  19. Sand transport and deposition in horizontal multiphase trunklines of subsea satellite developments

    SciTech Connect (OSTI)

    Oudeman, P. )

    1993-11-01

    Gravel packing is unattractive as a way to protect against the effects of sand production in subsea wells because it involves additional completion costs, loss of productivity, and difficulties in subsequent recompletion/well servicing operations. On the other hand, omitting gravel packs means that subsea developments must be designed and operated so that they can tolerate sand production. An experimental study was carried out on sand transport and deposition in multiphase flow in modeled subsea flowlines to address the problem and sand collection in horizontal trunklines, which could lead to reduced line throughput, pigging problems, enhanced pipe-bottom erosion, or even blockage. This study led to the definition of a new model for sand transport in multiphase flow, which was used to establish the risk of sand deposition in trunklines connecting a subsea development to nearby production platform.

  20. Preparation and thermochromic properties of Ce-doped VO{sub 2} films

    SciTech Connect (OSTI)

    Song, Linwei; Zhang, Yubo; Huang, Wanxia; Shi, Qiwu; Li, Danxia; Zhang, Yang; Xu, Yuanjie

    2013-06-01

    Graphical abstract: This effect of doping concentration on the phase transition temperature of VO{sub 2} films demonstrates that the phase transition temperature is decreasing along with the increase of the Ce dopant concentrations. After doping Ce, the transition temperature of VO{sub 2} film changes appreciably. Highlights: ► Ce-doped VO{sub 2} films were prepared on muscovite substrate by inorganic sol–gel method for the first time. ► The cerium existing in the VO{sub 2} films in the form of Ce{sup 4+} and Ce{sup 3+} was substituted for part of V atoms in the lattice. ► Ce doping could remarkably reduce the particle size of the Ce-doped films compared with undoped films. ► The phase transition temperature of Ce-doped VO{sub 2} films decreased appreciably with maintaining high-quality phase transition. - Abstract: Mixture of cerium (III) nitrate hexahydrate and vanadium pentaoxide powder were used as precursor to prepare Ce-doped VO{sub 2} films on the muscovite substrate by inorganic sol–gel method. SEM, XRD and XPS were used to investigate the morphologies and structures of VO{sub 2} films. The results show that the VO{sub 2} films grow on the muscovite substrate with preferred orientated (0 1 1) plane and the Ce exists in the form of Ce{sup 4+} and Ce{sup 3+} replacing part of V atoms in the lattice. The infrared transmittance change was measured from room temperature to the temperature above the metal–insulator transition. The films have excellent thermochromic performance. The metal–insulator transition temperature of VO{sub 2} films changes appreciably with Ce doped, which decreases by 4.5 °C per 1 at.% doping. Furthermore, Ce doping could remarkably reduce the particle size of VO{sub 2} films.

  1. Appraisal of the tight sands potential of the Sand Wash and Great Divide Basins. Final report, June 1989--June 1991

    SciTech Connect (OSTI)

    Not Available

    1993-08-01

    The volume of future tight gas reserve additions is difficult to estimate because of uncertainties in the characterization and extent of the resource and the performance and cost-effectiveness of stimulation and production technologies. Ongoing R&D by industry and government aims to reduce the risks and costs of producing these tight resources, increase the certainty of knowledge of their geologic characteristics and extent, and increase the efficiency of production technologies. Some basins expected to contain large volumes of tight gas are being evaluated as to their potential contribution to domestic gas supplies. This report describes the results of one such appraisal. This analysis addresses the tight portions of the Eastern Greater Green River Basin (Sand Wash and Great Divide Subbasins in Northwestern Colorado and Southwestern Wyoming, respectively), with respect to estimated gas-in-place, technical recovery, and potential reserves. Geological data were compiled from public and proprietary sources. The study estimated gas-in-place in significant (greater than 10 feet net sand thickness) tight sand intervals for six distinct vertical and 21 areal units of analysis. These units of analysis represent tight gas potential outside current areas of development. For each unit of analysis, a ``typical`` well was modeled to represent the costs, recovery and economics of near-term drilling prospects in that unit. Technically recoverable gas was calculated using reservoir properties and assumptions about current formation evaluation and extraction technology performance. Basin-specific capital and operating costs were incorporated along with taxes, royalties and current regulations to estimate the minimum required wellhead gas price required to make the typical well in each of unit of analysis economic.

  2. Determining sand-body geometries for waterflood reservoirs: Examples from Oklahoma

    SciTech Connect (OSTI)

    Kreisa, R.D.; Pinero, E. )

    1987-02-01

    Waterflood projects require an accurate knowledge of reservoir geometry and well-to-well continuity. However, sandstones with thin, multiple-pay zones can be extremely difficult to correlate with confidence. Two case studies of Pennsylvanian sandstones in Oklahoma illustrate how a model for the depositional history of such reservoirs can be an effective tool for determining reservoir continuity. In contrast, correlation criteria such as similar wireline log signatures and relative sand-body thicknesses are not reliable in many situations. In Southwest Logan field (Beaver County), 5 to 15-ft thick reservoir sands formed as shallow marine sand ridges. Their dimensions were approximated from height-to-width ratios of modern sand ridges. Then the reservoir sands were mapped using wireline logs and core data. Individual reservoir sands were approximately 1-2 km wide and stacked en echelon vertically. Thus, a line-drive waterflood pattern oriented parallel to the axes of the ridges is recommended. Tatums field (Carter County) consists of 5 to 50-ft thick sandstones deposited in various deltaic environments. Distributary channel sands have good continuity downdip, but are narrow and lenticular across depositional strike. Crevasse splay and other bay-fill sands were deposited marginal to the channels and are extremely discontinuous. This depositional model can be used to improve flood patterns for these sands, leading to improved sweep efficiency. In both examples, for effective mapping, the depositional facies models have been used to register reservoir quality and wireline log signatures.

  3. Non-Incineration Treatment to Reduce Benzene and VOC Emissions from Green Sand Molding Systems

    SciTech Connect (OSTI)

    Fred S. Cannon; Robert C. Voigt

    2002-06-28

    Final report describing laboratory, pilot scale and production scale evaluation of advanced oxidation systems for emissions and cost reduction in metal casting green sand systems.

  4. Evaluation of water saturation in oil-bearing shaly sands

    SciTech Connect (OSTI)

    Martinovic, S.; Vojnovic, V. )

    1990-06-01

    The physical properties of shaly formations are difficult to evaluate because the shale component strongly affects geophysical well log and laboratory test data. This is particularly true in the case of water saturation. On the other hand, the accuracy of in-situ hydrocarbon estimates depends directly on the accuracy of water saturation values. The most important interpretation models for water saturation rely on double-layer models. These interpretation models compute highly probably water saturation values of oil-bearing shaly sands using sound mathematical and physical postulates. Certain disadvantages, such as the inability to evaluate some crucial parameters directly from geophysical well logs, simplifications along the system-model line, inherent deficiencies of logging techniques, etc., give rise to errors and other problems which are more or less solved at this stage of development. A simple program for water saturation of oil-bearing shaly sands was designed and tested. The program uses equations based on double layer models. Program listing and test results also are presented.

  5. Geology and resources of the Tar Sand Triangle, southeastern Utah

    SciTech Connect (OSTI)

    Dana, G.F.; Oliver, R.L.; Elliott, J.R.

    1984-05-01

    The Tar Sand Triangle is located in southeastern Utah between the Dirty Devil and Colorado Rivers and covers an area of about 200 square miles. The geology of the area consists of gently northwest dipping strata exposed in the box canyons and slopes of the canyonlands morphology. Strata in the area range in age from Jurassic to Permian. The majority of tar sand saturation is found in the Permian White Rim Sandstone Member of the Cutler Formation. The White Rim Sandstone Member consists of a clean, well-sorted sandstone which was deposited in a shallow marine environment. Resources were calculated from analytical data from the three coreholes drilled by the Laramie Energy Technology Center and other available data. The total in-place resources, determined from this study, are 6.3 billion barels. Previous estimates ranged from 2.9 to 16 million barrels. More coring and analyses will be necessary before a more accurate determination of resources can be attempted. 8 references, 11 figures, 7 tables.

  6. On the heat capacity of Ce{sub 3}Al

    SciTech Connect (OSTI)

    Singh, Durgesh Samatham, S. Shanmukharao Venkateshwarlu, D. Gangrade, Mohan Ganesan, V.

    2014-04-24

    Electrical resistivity and heat capacity measurements on Cerium based dense Kondo compound Ce{sub 3}Al have been reported. Clear signatures of first order structural transition at 108K, followed by a Kondo minimum and coherence are clearly seen in resistivity. The structural transition is robust and is not affected by magnetic fields. Heat capacity measurements reveal an anomalous enhancement in the heavy fermion character upon magnetic fields. Vollhardt invariance in specific heat C(T.H) curves have been observed at T=3.7K and at H ≈ 6T.

  7. Guide to Preparing SAND Reports and other communication products : quick reference guide.

    SciTech Connect (OSTI)

    Not Available

    2009-10-01

    This Quick Reference Guide supplements the more complete Guide to Preparing SAND Reports and Other Communication Products. It provides limited guidance on how to prepare SAND Reports at Sandia National Laboratories. Users are directed to the in-depth guide for explanations of processes.

  8. Wastewater treatment by sand filtration. (Latest citations from the Selected Water Resources Abstracts database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1993-09-01

    The bibliography contains citations concerning the use of sand filtration in the treatment of wastewaters. Treatment systems for both domestic and industrial effluents are discussed. Designs, processes, and performance evaluations of sand filters, columns, and mounds used as primary filtering mechanisms are included. (Contains a minimum of 244 citations and includes a subject term index and title list.)

  9. Wastewater treatment by sand filtration. (Latest citations from the Selected Water Resources Abstracts database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1994-04-01

    The bibliography contains citations concerning the use of sand filtration in the treatment of wastewaters. Systems and filtration processes for municipal, domestic, and industrial wastewater treatment are discussed. Designs and performance evaluations of sand filters are included. (Contains a minimum of 247 citations and includes a subject term index and title list.)

  10. Preliminary relative permeability estimates of methanehydrate-bearing sand

    SciTech Connect (OSTI)

    Seol, Yongkoo; Kneafsey, Timothy J.; Tomutsa, Liviu; Moridis,George J.

    2006-05-08

    The relative permeability to fluids in hydrate-bearingsediments is an important parameter for predicting natural gas productionfrom gas hydrate reservoirs. We estimated the relative permeabilityparameters (van Genuchten alpha and m) in a hydrate-bearing sand by meansof inverse modeling, which involved matching water saturation predictionswith observations from a controlled waterflood experiment. We used x-raycomputed tomography (CT) scanning to determine both the porosity and thehydrate and aqueous phase saturation distributions in the samples. X-rayCT images showed that hydrate and aqueous phase saturations arenon-uniform, and that water flow focuses in regions of lower hydratesaturation. The relative permeability parameters were estimated at twolocations in each sample. Differences between the estimated parametersets at the two locations were attributed to heterogeneity in the hydratesaturation. Better estimates of the relative permeability parametersrequire further refinement of the experimental design, and betterdescription of heterogeneity in the numerical inversions.

  11. Injury experience in sand and gravel mining, 1990

    SciTech Connect (OSTI)

    Not Available

    1991-12-31

    This Mine Safety and Health Administration (MSHA) informational report reviews in detail the occupational injury and illness experience of sand and gravel mining in the United States for 1990. Data reported by operators of mining establishments concerning work injuries are summarized by work location, accident classification, part of body injured, nature of injury, and occupation. Related information on employment, worktime, and operating activity also is presented. Data reported by independent contractors performing certain work at mining locations are depicted separately in this report. For ease of comparison with other metal and nonmetallic mineral mining industries and with coal mining, summary reference tabulations are included at the end of both the operator and the contractor sections of this report.

  12. Injury experience in sand and gravel mining, 1992

    SciTech Connect (OSTI)

    Reich, R.B.; Hugler, E.C.

    1994-05-01

    This Mine Safety and Health Administration (MSHA) informational report reviews in detail the occupational injury and illness experience of sand and gravel mining in the United States for 1992. Data reported by operators of mining establishments concerning work injuries are summarized by work location, accident classification, part of body injured, nature of injury, and occupation. Related information on employment, worktime, and operating activity also is presented. Data reported by independent contractors performing certain work at mining locations are depicted separately in this report. For ease of comparison with other metal and nonmetallic mineral mining industries and with coal mining, summary reference tabulations are included at the end of both the operator and the contractor sections of this report.

  13. Injury experience in sand and gravel mining, 1990

    SciTech Connect (OSTI)

    Not Available

    1991-01-01

    This Mine Safety and Health Administration (MSHA) informational report reviews in detail the occupational injury and illness experience of sand and gravel mining in the United States for 1990. Data reported by operators of mining establishments concerning work injuries are summarized by work location, accident classification, part of body injured, nature of injury, and occupation. Related information on employment, worktime, and operating activity also is presented. Data reported by independent contractors performing certain work at mining locations are depicted separately in this report. For ease of comparison with other metal and nonmetallic mineral mining industries and with coal mining, summary reference tabulations are included at the end of both the operator and the contractor sections of this report.

  14. Injury experience in sand and gravel mining, 1989

    SciTech Connect (OSTI)

    Not Available

    1990-01-01

    This Mine Safety and Health Administration (MSHA) informational report reviews in detail the occupational injury and illness experience of sand and gravel mining in the United States for 1989. Data reported by operators of mining establishments concerning work injuries are summarized by work location, accident classification, part of body injured, nature of injury, and occupation. Related information on employment, worktime, and operating activity also is presented. Data reported by independent contractors performing certain work at mining locations are depicted separately in this report. For ease of comparison with other metal and nonmetallic mineral mining industries and with coal mining, summary reference tabulations are included at the end of both the operator and the contractor sections of this report. 3 figs., 38 tabs.

  15. Centrifuge modeling of LNAPL transport in partially saturated sand

    SciTech Connect (OSTI)

    Esposito, G.; Allersma, H.G.B.; Selvadurai, A.P.S.

    1999-12-01

    Model tests were performed at the Geotechnical Centrifuge Facility of Delft University of Technology, The Netherlands, to examine the mechanics of light nonaqueous phase liquid (LNAPL) movement in a partially saturated porous granular medium. The experiment simulated a 2D spill of LNAPL in an unsaturated sand prepared at two values of porosity. The duration of the centrifuge model tests corresponded to a prototype equivalent of 110 days. The choice of modeling a 2D flow together with the use of a transparent container enabled direct visual observation of the experiments. Scaling laws developed in connection with other centrifuge modeling studies were used to support the test results. Tests were conducted at two different centrifuge accelerations to verify, by means of the modeling of models technique, the similitude between the different experiments. The paper presents details of the experimental methodologies and the measuring techniques used to evaluate the final distribution of water and LNAPL content in the soils.

  16. Design of a sand filter for stormwater quality enhancement

    SciTech Connect (OSTI)

    Urbonas, B.R.

    1999-01-01

    The use of sand and other media filters is gaining acceptance in the field of urban stormwater structural best management practice. Much work has been done to develop local design guidance, such as in the State of Delaware and in Austin, Texas. Also, considerable field testing of these devices has occurred during the last 10 years. This paper consolidates much of the earlier work and provides the technical basis for the design of media filters for stormwater runoff treatment at any location in the US. The approach uses the unit processes known to exist in urban stormwater runoff and within filter devices. The suggested design is based on hydraulic capacity of the filter media, which, in turn, is a function of the total suspended particulates removed by the filter.

  17. Measurement of Moisture Content in Sand, Slag, and Crucible Materials

    SciTech Connect (OSTI)

    Gray, J.H.

    1999-09-20

    The deinventory process at Rocky Flats (RFETS) has included moisture content measurements of sand, slag, and crucible (SSC) materials by performing weight loss measurements at 210 degrees - 220 degrees Celsius on representative samples prior to packaging for shipment. Shipping requirements include knowledge of the moisture content. Work at the Savannah River Technology Center (SRTC) showed that the measurement at 210 degrees - 220 degrees Celsius did not account for all of the moisture. The objective of the work in this report was to determine if the measurement at 210 degrees - 220 degrees Celsius at RFETS could be used to set upper bounds on moisture content and therefore, eliminate the need for RFETS to unpack, reanalyze and repack the material.

  18. Preliminary relative permeability estimates of methanehydrate-bearing sand

    SciTech Connect (OSTI)

    Seol, Yongkoo; Kneafsey, Timothy J.; Tomutsa, Liviu; Moridis,George J.

    2006-05-08

    The relative permeability to fluids in hydrate-bearing sediments is an important parameter for predicting natural gas production from gas hydrate reservoirs. We estimated the relative permeability parameters (van Genuchten alpha and m) in a hydrate-bearing sand by means of inverse modeling, which involved matching water saturation predictions with observations from a controlled waterflood experiment. We used x-ray computed tomography (CT) scanning to determine both the porosity and the hydrate and aqueous phase saturation distributions in the samples. X-ray CT images showed that hydrate and aqueous phase saturations are non-uniform, and that water flow focuses in regions of lower hydrate saturation. The relative permeability parameters were estimated at two locations in each sample. Differences between the estimated parameter sets at the two locations were attributed to heterogeneity in the hydrate saturation. Better estimates of the relative permeability parameters require further refinement of the experimental design, and better description of heterogeneity in the numerical inversions.

  19. Injury experience in sand and gravel mining, 1991

    SciTech Connect (OSTI)

    Not Available

    1993-10-01

    This Mine Safety and Health Administration (MSHA) informational report reviews in detail the occupational injury and illness experience of sand and gravel mining in the United States for 1991. Data reported by operators of mining establishments concerning work injuries are summarized by work location, accident classification, part of body injured, nature of injury, and occupation. Related information on employment, worktime, and operating activity also is presented. Data reported by independent contractors performing certain work at mining locations are depicted separately in this report. For ease of comparison with other metal and nonmetallic mineral mining industries and with coal mining, summary reference tabulations are included at the end of both the operator and the contractor sections of this report.

  20. Magnetic properties and photoabsorption of the Mn-doped CeO{sub 2} nanorods

    SciTech Connect (OSTI)

    Xia, Chuanhui; Science College of Chongqing Jiaotong University, Chongqing 400074 ; Hu, Chenguo; Chen, Peng; Wan, Buyong; He, Xiaoshan; Tian, Yongshu; Chongqing Communication College, Chongqing 400035

    2010-07-15

    Mn-doped CeO{sub 2} nanorods have been prepared from CeO{sub 2} particles through a facile composite-hydroxide-mediated (CHM) approach. The analysis from X-ray photoelectron spectroscopy indicates that the manganese doped in CeO{sub 2} exists as Mn{sup 2+}. The magnetic measurement of the Mn-doped CeO{sub 2} nanorods exhibits an enhanced ferromagnetic property at room temperature with a remanence magnetization (Mr) of 1.36 x 10{sup -3} emu/g and coercivity (Hc) of 22 Oe. Comparative UV-visible spectra reveal the shift of the absorption peak of the CeO{sub 2} from ultraviolet region to visible light region after being doped with Mn. The room temperature ferromagnetic properties and light absorption of the Mn-doped CeO{sub 2} nanorods would have potential applications in photocatalysis and building of photovoltaic devices.

  1. The influence of nano-architectured CeOx supports in RhPd/CeO₂ for the catalytic ethanol steam reforming reaction

    SciTech Connect (OSTI)

    Divins, N. J.; Senanayake, S. D.; Casanovas, A.; Xu, W.; Trovarelli, A.; Llorca, J.

    2015-01-19

    The ethanol steam reforming (ESR) reaction has been tested over RhPd supported on polycrystalline ceria in comparison to structured supports composed of nanoshaped CeO₂ cubes and CeO₂ rods tailored towards the production of hydrogen. At 650-700 K the hydrogen yield follows the trend RhPd/CeO₂-cubes > RhPd/CeO₂ -rods > RhPd/CeO₂- polycrystalline, whereas at temperatures higher than 800 K the catalytic performance of all samples is similar and close to the thermodynamic equilibrium. The improved performance of RhPd/CeO₂-cubes and RhPd/CeO₂ -rods for ESR at low temperature is mainly ascribed to higher water-gas shift activity and a strong interaction between the bimetallic - oxide support interaction. STEM analysis shows the existence of RhPd alloyed nanoparticles in all samples, with no apparent relationship between ESR performance and RhPd particle size. X-ray diffraction under operating conditions shows metal reorganization on {100} and {110} ceria crystallographic planes during catalyst activation and ESR, but not on {111} ceria crystallographic planes. The RhPd reconstructing and tuned activation over ceria nanocubes and nanorods is considered the main reason for better catalytic activity with respect to conventional catalysts based on polycrystalline ceria

  2. The influence of nano-architectured CeOx supports in RhPd/CeO₂ for the catalytic ethanol steam reforming reaction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Divins, N. J.; Senanayake, S. D.; Casanovas, A.; Xu, W.; Trovarelli, A.; Llorca, J.

    2015-01-19

    The ethanol steam reforming (ESR) reaction has been tested over RhPd supported on polycrystalline ceria in comparison to structured supports composed of nanoshaped CeO₂ cubes and CeO₂ rods tailored towards the production of hydrogen. At 650-700 K the hydrogen yield follows the trend RhPd/CeO₂-cubes > RhPd/CeO₂ -rods > RhPd/CeO₂- polycrystalline, whereas at temperatures higher than 800 K the catalytic performance of all samples is similar and close to the thermodynamic equilibrium. The improved performance of RhPd/CeO₂-cubes and RhPd/CeO₂ -rods for ESR at low temperature is mainly ascribed to higher water-gas shift activity and a strong interaction between the bimetallic -more » oxide support interaction. STEM analysis shows the existence of RhPd alloyed nanoparticles in all samples, with no apparent relationship between ESR performance and RhPd particle size. X-ray diffraction under operating conditions shows metal reorganization on {100} and {110} ceria crystallographic planes during catalyst activation and ESR, but not on {111} ceria crystallographic planes. The RhPd reconstructing and tuned activation over ceria nanocubes and nanorods is considered the main reason for better catalytic activity with respect to conventional catalysts based on polycrystalline ceria« less

  3. Center for Excitonics (CE) | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    Center for Excitonics (CE) Energy Frontier Research Centers (EFRCs) EFRCs Home Centers EFRC External Websites Research Science Highlights News & Events Publications History Contact BES Home Centers Center for Excitonics (CE) Print Text Size: A A A FeedbackShare Page CE Header Director Marc Baldo Lead Institution Massachusetts Institute of Technology Year Established 2009 Mission To supersede traditional electronics with devices that use excitonics to mediate the flow of energy. Research

  4. Capillary electrophoresis-fluorescence line narrowing system (CE-FLNS) for on-line structural characterization

    DOE Patents [OSTI]

    Jankowiak, R.J.; Small, G.J.; Shields, P.A.

    1999-04-27

    Capillary electrophoresis (CE) is interfaced with low temperature fluorescence line-narrowing (FLN) spectroscopy for on-line structural characterization of separated molecular analytes. 21 figs.

  5. Capillary electrophoresis-fluorescence line narrowing system (CE-FLNS) for on-line structural characterization

    DOE Patents [OSTI]

    Jankowiak, Ryszard J.; Small, Gerald J.; Shields, Peter A.

    1999-04-27

    Capillary electrophoresis (CE) is interfaced with low temperature fluorescence line-narrowing (FLN) spectroscopy for on-line structural characterization of separated molecular analytes.

  6. Proactive Design of n-Type (In, Ce) Filled Skutterudites Enabling...

    Broader source: Energy.gov (indexed) [DOE]

    More Documents & Publications Proactive Design of n-Type (In, Ce) Filled Skutterudites Enabling High-Temperature Waste Heat Recovery Thermoelectric Couple Demonstration of (In, ...

  7. Ethanol Steam Reforming on Co/CeO2: The Effect of ZnO Promoter

    SciTech Connect (OSTI)

    Davidson, Stephen; Sun, Junming; Wang, Yong

    2013-12-02

    A series of ZnO promoted Co/CeO2 catalysts were synthesized and characterized using XRD, TEM, H2-TPR, CO chemisorption, O2-TPO, IR-Py, and CO2-TPD. The effects of ZnO on the catalytic performances of Co/CeO2 were studied in ethanol steam reforming. It was found that the addition of ZnO facilitated the oxidation of Co0 via enhanced oxygen mobility of the CeO2 support which decreased the activity of Co/CeO2 in C–C bond cleavage of ethanol. 3 wt% ZnO promoted Co/CeO2 exhibited minimum CO and CH4 selectivity and maximum CO2 selectivity. This resulted from the combined effects of the following factors with increasing ZnO loading: (1) enhanced oxygen mobility of CeO2 facilitated the oxidation of CHx and CO to form CO2; (2) increased ZnO coverage on CeO2 surface reduced the interaction between CHx/CO and Co/CeO2; and (3) suppressed CO adsorption on Co0 reduced CO oxidation rate to form CO2. In addition, the addition of ZnO also modified the surface acidity and basicity of CeO2, which consequently affected the C2–C4 product distributions.

  8. Luminescence properties of LaF{sub 3}:Ce nanoparticles encapsulated by oleic acid

    SciTech Connect (OSTI)

    Kim, Jaewoo; Lee, Jun-Hyung; An, Hyejin; Lee, Jungkuk; Park, Seong-Hee; Seo, Young-Soo; Miller, William H.

    2014-09-15

    Highlights: In-situ hydrophobization of water dispersible LaF{sub 3}:Ce nanoparticles was achieved. Oleic acid surface modification of the nanoparticles was verified by IR spectra. Quantum yields of LaF{sub 3}:Ce and OA-LaF{sub 3}:Ce nanoparticles were evaluated. Quantum yields of LaF{sub 3}:Ce are strongly dependent on OA surface modification. - Abstract: Cerium ions doped lanthanum fluoride (LaF{sub 3}:Ce) nanopowder as well as LaF{sub 3}:Ce nanopowder whose surfaces was modified by oleic acid (OA) were synthesized by using an in-situ hydrothermal process under the various doping concentrations. Based on the XRD spectra and TEM images, it was confirmed that the crystalline structured hexagonal LaF{sub 3}:Ce nanopowder was synthesized. Oleic acid was efficient for conversion of the water dispersible LaF{sub 3}:Ce nanoparticles to hydrophobic ones. Surface modification was verified by FTIR absorption spectrum as well as TEM images, showing no agglomeration between 5 and 10 nm scaled particles. Photoluminescence based on 5d ? 4f electronic transition of cerium ions excited at ?{sub ex} ?256 nm for both neat and OA encapsulated LaF{sub 3}:Ce nanoparticles decreases as the cerium concentration increases, while the quantum yields of OA encapsulated nanoparticles were much lower than the neat particles due to low photon transmittance of OA at the range longer than ?350 nm.

  9. Polymer treatments for D Sand water injection wells: Sooner D Sand Unit Weld County, Colorado. Final report, April 1997

    SciTech Connect (OSTI)

    Cannon, T.J.

    1998-10-01

    Polymer-gel treatments in injection wells were evaluated for improving sweep efficiency in the D Sandstone reservoir at the Sooner Unit, Weld County, Colorado. Polymer treatments of injection wells at the Sooner Unit were expected to improve ultimate recovery by 1.0 percent of original-oil-in-place of 70,000 bbl of oil. The Sooner D Sand Unit was a demonstration project under the US Department of Energy Class I Oil Program from which extensive reservoir data and characterization were obtained. Thus, successful application of polymer-gel treatments at the Sooner Unit would be a good case-history example for other operators of waterfloods in Cretaceous sandstone reservoirs in the Denver Basin.

  10. Thermal Variation of Ce Valence in Mixed ValenceKondo Lattice Systems CeT2(Si1-xGex)2 with T= Mn and Ni

    SciTech Connect (OSTI)

    Liang,G.; Croft, M.

    2008-01-01

    The results on the thermal variation of Ce L3-valence in CeT2(Si1-xGex)2 series with 0{le}x{le}1 and T=Mn and Ni are reported. It is observed that for both series, the Ce valence increases with decreasing temperature and has little thermal variation for samples in the nearly trivalent regime. The magnitude of this thermal variation in the T=Mn series is much greater than in the T=Ni series. The results are explained by the degenerate Anderson model and correlated with the specific heat data.

  11. The record of sea level rise by tidal sand bodies of the English Channel

    SciTech Connect (OSTI)

    Berne, S; Lericolais, G. (Ifremer, Plouzane, (France)); Lafont, F. (Universite d'Orsay (France))

    1990-05-01

    Improvements of very high resolution seismic reflection provide new information about internal structures of modern sand bodies. This allows us to reconstruct their recent history, which is related to the Holocene sea level rise. A major distinction is found between inner shelf sand bodies, dominated by autocyclic processes, and outer shelf sand bodies, where allocyclic processes are invoked to explain the apparent contradiction between internal structures and present-day dynamics. On the inner shelf, evidence of the migration of tidal dunes (sand waves) has been obtained by repeated surveys using accurate positioning systems. Major bounding surfaces are thought to result from the action of tidal current and/or from episodic storms. A rough estimation of the age of these sand bodies can be proposed. On the outer shelf, some dunes of the English Channel exhibit cross-beds indicative of a past net bed-load transport at the opposite of present days dynamics, inherited from different tidal conditions when sea level was between 20 and 40 m lower. Some large tidal sand banks (e.g., the Sark Bank near the Channel Islands) display a more complicated pattern. The upper part of the sand bank is the result of the migration of very large dunes climbing at positive angles, whereas the lower part shows major erosional surfaces, attributed to the action of storms during lower sea levels.

  12. Magnetic structure of the antiferromagnetic Kondo lattice compounds CeRhAl4Si2 and CeIrAl4Si2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ghimire, N. J.; Calder, S.; Janoschek, M.; Bauer, E. D.

    2015-06-01

    In this article, we have investigated the magnetic ground state of the antiferromagnetic Kondo-lattice compounds CeMAl4Si2(M = Rh, Ir) using neutron powder diffraction. Although both of these compounds show two magnetic transitions TN1 and TN2 in the bulk properties measurements, evidence for magnetic long-range order was only found below the lower transition TN2. Analysis of the diffraction profiles reveals a commensurate antiferromagnetic structure with a propagation vector k = (0, 0, 1/2). The magnetic moment in the ordered state of CeRhAl4Si2 and CeIrAl4Si2 were determined to be 1.14(2) and 1.41(3) μB/Ce, respectively, and are parallel to the crystallographic c-axis inmore » agreement with magnetic susceptibility measurements.« less

  13. Excess Foundry Sand Characterization and Experimental Investigation in Controlled Low-Strength Material and Hot-Mixing Asphalt

    SciTech Connect (OSTI)

    Pauul J. Tikalsky

    2004-10-31

    This report provides technical data regarding the reuse of excess foundry sand. The report addresses three topics: (1) a statistically sound evaluation of the characterization of foundry sand, (2) a laboratory investigation to qualify excess foundry sand as a major component in controlled low-strength material (CLSM), and (3) the identification of the best methods for using foundry sand as a replacement for natural aggregates for construction purposes, specifically in asphalt paving materials. The survival analysis statistical technique was used to characterize foundry sand over a full spectrum of general chemical parameters, metallic elements, and organic compounds regarding bulk analysis and leachate characterization. Not limited to characterization and environmental impact, foundry sand was evaluated by factor analyses, which contributes to proper selection of factor and maximization of the reuse marketplace for foundry sand. Regarding the integration of foundry sand into CLSM, excavatable CLSM and structural CLSM containing different types of excess foundry sands were investigated through laboratory experiments. Foundry sand was approved to constitute a major component in CLSM. Regarding the integration of foundry sand into asphalt paving materials, the optimum asphalt content was determined for each mixture, as well as the bulk density, maximum density, asphalt absorption, and air voids at N{sub ini}, N{sub des}, and N{sub max}. It was found that foundry sands can be used as an aggregate in hot-mix asphalt production, but each sand should be evaluated individually. Foundry sands tend to lower the strength of mixtures and also may make them more susceptible to moisture damage. Finally, traditional anti-stripping additives may decrease the moisture sensitivity of a mixture containing foundry sand, but not to the level allowed by most highway agencies.

  14. Excess Foundry Sand Characterization and Experimental Investigation in Controlled Low-Strength Material and Hot-Mixing Asphalt

    SciTech Connect (OSTI)

    Tikalsky, Paul J.; Bahia, Hussain U.; Deng, An; Snyder, Thomas

    2004-10-15

    This report provides technical data regarding the reuse of excess foundry sand. The report addresses three topics: a statistically sound evaluation of the characterization of foundry sand, a laboratory investigation to qualify excess foundry sand as a major component in controlled low-strength material (CLSM), and the identification of the best methods for using foundry sand as a replacement for natural aggregates for construction purposes, specifically in asphalt paving materials. The survival analysis statistical technique was used to characterize foundry sand over a full spectrum of general chemical parameters, metallic elements, and organic compounds regarding bulk analysis and leachate characterization. Not limited to characterization and environmental impact, foundry sand was evaluated by factor analyses, which contributes to proper selection of factor and maximization of the reuse marketplace for foundry sand. Regarding the integration of foundry sand into CLSM, excavatable CLSM and structural CLSM containing different types of excess foundry sands were investigated through laboratory experiments. Foundry sand was approved to constitute a major component in CLSM. Regarding the integration of foundry sand into asphalt paving materials, the optimum asphalt content was determined for each mixture, as well as the bulk density, maximum density, asphalt absorption, and air voids at Nini, Ndes, and Nmax. It was found that foundry sands can be used as an aggregate in hot-mix asphalt production, but each sand should be evaluated individually. Foundry sands tend to lower the strength of mixtures and also may make them more susceptible to moisture damage. Finally, traditional anti-stripping additives may decrease the moisture sensitivity of a mixture containing foundry sand, but not to the level allowed by most highway agencies.

  15. Ternary ceramic alloys of Zr-Ce-Hf oxides

    DOE Patents [OSTI]

    Becher, P.F.; Funkenbusch, E.F.

    1990-11-20

    A ternary ceramic alloy is described which produces toughening of zirconia and zirconia composites through the stress transformation from tetragonal phase to monoclinic phase. This alloy, having the general formula Ce[sub x]Hf[sub y]Zr[sub 1[minus]x[minus]y]O[sub 2], is produced through the addition of appropriate amounts of ceria and hafnia to the zirconia. Typically, improved toughness is achieved with about 5 to about 15 mol % ceria and up to about 40 mol % hafnia. The preparation of alloys of these compositions are given together with data as to the densities, tetragonal phase content, hardness and fracture toughness. The alloys are useful in preparing zirconia bodies as well as reinforcing ceramic composites. 1 fig.

  16. Ternary ceramic alloys of ZR-CE-HF oxides

    DOE Patents [OSTI]

    Becher, Paul F.; Funkenbusch, Eric F.

    1990-01-01

    A ternary ceramic alloy which produces toughening of zirconia and zirconia composites through the stress transformation from tetragonal phase to monoclinic phase. This alloy, having the general formula Ce.sub.x Hf.sub.y Zn.sub.1-x-y O.sub.2, is produced through the addition of appropriate amounts of ceria and hafnia to the zirconia. Typically, improved toughness is achieved with about 5 to about 15 mol % ceria and up to about 40 mol % hafnia. The preparation of alloys of these compositions are given together with data as to the densities, tetragonal phase content, hardness and fracture toughness. The alloys are useful in preparing zirconia bodies as well as reinforcing ceramic composites.

  17. Inelastic magnetic neutron scattering in CePd{sub 3}.

    SciTech Connect (OSTI)

    Lawrence, J. M.; Fanelli, V. R.; Goremychkin, E. A.; Osborn, R.; Bauer, E. D.; McClellan, K. J.; Christianson, A. D.; Univ. of California at Irvine; LANL; ORNL

    2008-01-01

    We have performed time-of-flight neutron scattering measurements on a single crystal of the intermediate valence compound CePd{sub 3}. At 10 K, a Kondo-esque inelastic magnetic scattering peak occurs near {Delta}E = 60 meV with maximum intensity for momentum transfer Q near the (1/2, 1/2, 0) zone boundary. Spectral weight is transferred to lower energy as Q varies until at zone center the intensity at 60 meV is considerably weaker. These results are in qualitative accord with predictions of the Anderson lattice. The Q-dependence may resolve an older controversy concerning the low-temperature scattering. We discuss the relationship of these results to our recent results in YbAl{sub 3}.

  18. Preparation and properties of ce-doped TiO{sub 2} photocatalyst

    SciTech Connect (OSTI)

    Yan, Ningning; Zhu, Zhongqi; Zhang, Jin; Zhao, Zongyan; Liu, Qingju

    2012-08-15

    Highlights: ? The cerium ion doped TiO{sub 2} (Ce-TiO{sub 2}) powders were prepared and characterized. ? The spectrum absorption region of Ce-TiO{sub 2} is red-shifted to visible light. ? The recombination of photo-generated electron-hole pairs of Ce-TiO{sub 2} is inhibited. ? The photocatalytic activity was effected by Ce ion content and greatly improved. -- Abstract: TiO{sub 2} nanoparticles doped with different content of Ce ion were prepared by solgel method. The samples were characterized by XRD, XPS, TEM, UVVis, and PL, the photocatalytic activity was evaluated by photocatalytic degradation of methylene blue (MB) under the irradiation of fluorescent lamp. The results indicate that Ce ion is incorporated into the lattice of TiO{sub 2}, which can restrain the increase of grain size, broaden the absorption region to visible light, and inhibit the recombination of the photo-generated electron and hole pairs. Moreover, the photocatalytic activity of Ce-TiO{sub 2} in MB degradation is evidently enhanced. The MB degradation rate of the sample with Ce:Ti = 0.33% (molar ratio) in 8 h is 90.03%, which is much higher than that of P25 (68.19%).

  19. Ethanol Steam Reforming on Co/CeO2: The Effect of ZnO Promoter...

    Office of Scientific and Technical Information (OSTI)

    Ethanol Steam Reforming on CoCeO2: The Effect of ZnO Promoter Citation Details In-Document Search Title: Ethanol Steam Reforming on CoCeO2: The Effect of ZnO Promoter A series of ...

  20. Guide to preparing SAND reports and other communication products.

    SciTech Connect (OSTI)

    Not Available

    2011-09-01

    This guide describes the R&A process, Common Look and Feel requirements, and preparation and publishing procedures for communication products at Sandia National Laboratories. Samples of forms and examples of published communications products are provided. This guide takes advantage of the wealth of material now available on the Web as a resource. Therefore, it is best viewed as an electronic document. If some of the illustrations are too small to view comfortably, you can enlarge them on the screen as needed. The format of this document is considerably different than that usually expected of a SAND Report. It was selected to permit the large number of illustrations and examples to be placed closer to the text that references them. In the case of forms, covers, and other items that are included as examples, a link to the Web is provided so that you can access the items and download them for use. This guide details the processes for producing a variety of communication products at Sandia National Laboratories. Figure I-1 shows the general publication development process. Because extensive supplemental material is available from Sandia on the internal web or from external sources (Table I-1), the guide has been shortened to make it easy to find information that you need.

  1. CO Oxidation at the Interface of Au Nanoclusters and the Stepped-CeO2(111) Surface

    SciTech Connect (OSTI)

    Kim H. Y.; Henkelman, G.

    2013-01-14

    To reveal the richer chemistry of CO oxidation by CeO2 supported Au Nanoclusters NCs)/Nanoparticles, we design a Au12 supported on a stepped-CeO2 model (Au/CeO2-step) and study various kinds of CO oxidation mechanisms at the interface of the Au/CeO2-step: oxygen spillover from the CeO2 to the Au NCs;2 CO oxidation by the O2 bound to the Au-Ce3+ interface;3 and CO oxidation by the Mars-van Krevelen (M-vK) mechanism.4 DFT+U calculations show that lattice oxygen at the CeO2 step edge oxidizes CO bound to Au NCs by the M-vK mechanism. CO2 desorption determines the rate of CO oxidation and the vacancy formation energy (Evac) is a reactivity descriptor for CO oxidation. The maximum Evac that insures spontaneous CO2 production is higher for the Au/CeO2-step than the Au/CeO2-surface suggesting that the CeO2-step is a better supporting material than the CeO2-surface for CO oxidation by the Au/CeO2. Our results also suggest that for CO oxidation by Au NCs supported on nano- or meso-structured CeO2, which is the case of industrial catalysts, the M-vK mechanism accounts for a large portion of the total activity.

  2. High Curie temperature of Ce-Fe-Si compounds with ThMn12 structure

    SciTech Connect (OSTI)

    Zhou, C; Pinkerton, FE; Herbst, JF

    2015-01-15

    We report the discovery of ternary CeFe(12-x)Si(x)compounds possessing the ThMn12 structure. The samples were prepared by melt spinning followed by annealing. In contrast to other known Ce Fe-based binary and ternary compounds, CeFe12-xSix compounds exhibit exceptionally high Curie temperatures whose values increase with added Si substitution. The highest T. = 583 K in CeFe10Si2 rivals that of the well-established Nd2Fe14B compound. We ascribe the T-c behavior to a combination of Si-induced 3d band structure changes and partial Ce3+ stabilization. (C) 2014 Published by Elsevier Ltd.

  3. EA-1978: Sand Creek Winds, McCone County, Montana | Department...

    Broader source: Energy.gov (indexed) [DOE]

    analyze the potential environmental impacts of the proposed Sand Creek Winds Project, a 75-MW wind farm between the towns of Circle and Wolf Point in McCone County, Montana. The...

  4. Use of the dual-screen thru-tubing sand control method

    SciTech Connect (OSTI)

    Freiman, O.H.; Johnson, K.J.

    1995-12-31

    This paper will describe a new sand control method used in area of Ecuador, South America where workover rigs are not readily available. Sand production had been significantly affecting maintenance costs on surface and downhole production equipment and had impacted performance of the downhole jet pump, subsequently causing a decrease in well production. By installing a small-diameter, sintered metal gravel-pack screen across the perforation interval and placing the gravel-pack sand with coiled tubing, the sand production was successfully controlled. The procedure and equipment used to perform this technique as well as post job data that provide results obtained will also be presented. Noteworthy advantages, such as recompletion without removal of the existing production completion string and without use of a workover rig, will also be discussed.

  5. Use of the dual-screen thru-tubing sand control method

    SciTech Connect (OSTI)

    Freiman, O.H.; Johnson, K.J.

    1994-12-31

    This paper describes a new sand control method used in an area of Ecuador, South America where workover rigs are not readily available. Sand production had been significantly affecting maintenance costs on surface and downhole production equipment and had impacted performance of the downhole jet pump, subsequently causing a decrease in well production. By installing a small-diameter, sintered metal gravel-pack screen across the perforation interval and placing the gravel-pack sand with coiled tubing, the sand production was successfully controlled. The procedure and equipment used to perform this technique as well as post job data that provide results obtained is also presented. Noteworthy advantages, such as recompletion without removal of the existing production completion string and without use of a workover rig, is also discussed.

  6. BETO-Funded Study Finds Increased Carbon Intensity from Canadian Oil Sands

    Office of Energy Efficiency and Renewable Energy (EERE)

    A recently released study from Argonne National Laboratory shows that gasoline and diesel refined from Canadian oil sands have a higher carbon impact than fuels derived from conventional domestic crude sources.

  7. Integration of High Temperature Gas-cooled Reactor Technology with Oil Sands Processes

    SciTech Connect (OSTI)

    L.E. Demick

    2011-10-01

    This paper summarizes an evaluation of siting an HTGR plant in a remote area supplying steam, electricity and high temperature gas for recovery and upgrading of unconventional crude oil from oil sands. The area selected for this evaluation is the Alberta Canada oil sands. This is a very fertile and active area for bitumen recovery and upgrading with significant quantities piped to refineries in Canada and the U.S Additionally data on the energy consumption and other factors that are required to complete the evaluation of HTGR application is readily available in the public domain. There is also interest by the Alberta oil sands producers (OSP) in identifying alternative energy sources for their operations. It should be noted, however, that the results of this evaluation could be applied to any similar oil sands area.

  8. APEX Workflows LANL, NERSC, SNL SAND2016-2371 O LA-UR-15-29113

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    APEX Workflows LANL, NERSC, SNL SAND2016-2371 O LA-UR-15-29113 March 17, 2016 1 Introduction The Department of Energy (DOE) compute facilities operate as resources for the National ...

  9. Characterization Report on Sand, Slag, and Crucible Residues and on Fluoride Residues

    SciTech Connect (OSTI)

    Murray, A.M.

    1999-02-10

    This paper reports on the chemical characterization of the sand, slag, and crucible (SS and C) residues and the fluoride residues that may be shipped from the Rocky Flats Environmental Technology Site (RFETS) to Savannah River Site (SRS).

  10. Well-to-Wheels Greenhouse Gas Emissions of Canadian Oil Sands...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    This range can be compared to 4.4 g CO2eMJ for U.S. conventional crude oil recovery. Depending on the extraction technology and product type output of oil sands projects, the ...

  11. Paleontological overview of oil shale and tar sands areas in Colorado, Utah, and Wyoming.

    SciTech Connect (OSTI)

    Murphey, P. C.; Daitch, D.; Environmental Science Division

    2009-02-11

    In August 2005, the U.S. Congress enacted the Energy Policy Act of 2005, Public Law 109-58. In Section 369 of this Act, also known as the ''Oil Shale, Tar Sands, and Other Strategic Unconventional Fuels Act of 2005,'' Congress declared that oil shale and tar sands (and other unconventional fuels) are strategically important domestic energy resources that should be developed to reduce the nation's growing dependence on oil from politically and economically unstable foreign sources. In addition, Congress declared that both research- and commercial-scale development of oil shale and tar sands should (1) be conducted in an environmentally sound manner using management practices that will minimize potential impacts, (2) occur with an emphasis on sustainability, and (3) benefit the United States while taking into account concerns of the affected states and communities. To support this declaration of policy, Congress directed the Secretary of the Interior to undertake a series of steps, several of which are directly related to the development of a commercial leasing program for oil shale and tar sands. One of these steps was the completion of a programmatic environmental impact statement (PEIS) to analyze the impacts of a commercial leasing program for oil shale and tar sands resources on public lands, with an emphasis on the most geologically prospective lands in Colorado, Utah, and Wyoming. For oil shale, the scope of the PEIS analysis includes public lands within the Green River, Washakie, Uinta, and Piceance Creek Basins. For tar sands, the scope includes Special Tar Sand Areas (STSAs) located in Utah. This paleontological resources overview report was prepared in support of the Oil Shale and Tar Sands Resource Management Plan Amendments to Address Land Use Allocations in Colorado, Utah, and Wyoming and PEIS, and it is intended to be used by Bureau of Land Management (BLM) regional paleontologists and field office staff to support future projectspecific analyses

  12. Emissions from Heavy-Duty Diesel Engine with EGR using Oil Sands Derived

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuels | Department of Energy Heavy-Duty Diesel Engine with EGR using Oil Sands Derived Fuels Emissions from Heavy-Duty Diesel Engine with EGR using Oil Sands Derived Fuels 2003 DEER Conference Presentation: National Research Council Canada, Ottawa, Ontario, Canada 2003_deer_neill.pdf (860.57 KB) More Documents & Publications Development of Advanced Combustion Technologies for Increased Thermal Efficiency Biodiesel Research Update Effect of the Composition of Hydrocarbon Streams on HCCI

  13. An Investigation for Disposal of Drill Cuttings into Unconsolidated Sandstones and Clayey Sands

    SciTech Connect (OSTI)

    Mese, Ali; Dvorkin, Jack; Shillinglaw, John

    2000-09-11

    This project include experimental data and a set of models for relating elastic moduli/porosity/texture and static-to-dynamic moduli to strength and failure relationships for unconsolidated sands and clayey sands. The results of the project should provide the industry with a basis for wider use of oil base drilling fluids in water sensitive formations by implementing drill cutting injection into existing wells at abandoned formations and controlling fracture geometry to prevent ground water contamination.

  14. Experience from topside and subsea use of the erosion based sand monitoring system

    SciTech Connect (OSTI)

    Braaten, N.A.; Blakset, T.J.; Morton, D.

    1995-12-31

    This paper describes the use of an erosion based on-line sand monitoring system, both for topside and subsea applications. It shows the practical use of the system, both from a safety point of view, with the probe giving early warning of sand production/erosion, in addition to being a tool for optimizing the production from the oil/gas wells. The probe works equally well in all flow regimes, single or multiphase flow.

  15. Stability of nickel-coated sand as gravel-pack material for thermal wells

    SciTech Connect (OSTI)

    Sacuta, A.; Nguyen, D.M.; Kissel, G.A. )

    1988-11-01

    Laboratory flow tests have been carried out to study the stability of various nickel-coated sands under aqueous steam temperature and pH conditions that may exist in thermal recovery operations. Other gravel-pack materials tested include Ottawa sand, sintered bauxite, cement clinker, zirconium oxide, and nickel pellets. A comparison was made between the performances of these materials after exposure to identical thermal and hydrolytic conditions. Test results indicate that nickel-coated sands are highly resistant to dissolution at temperatures as high as 300/sup 0/C (570/sup 0/F) and to solution pH's from 4.75 to 11. Weight losses measured after a 72-hour period were less than 1%. In contrast, weight losses from sintered bauxite, zirconium oxide, and Ottawa sand dissolution tests were 30 to 70 times higher under the same conditions. Cement clinker losses were in the intermediate range under alkaline conditions. API standard crushing and acid-solubility tests for proppants also were performed on nickel-coated sands. These results were favorable in that they exceeded the recommended standards. This study of nickel-coated sand stability and mechanical strength has demonstrated its high potential for application as either a gravel-pack material or proppant in thermal recovery operations.

  16. FIELD TESTING & OPTIMIZATION OF CO2/SAND FRACTURING TECHNOLOGY

    SciTech Connect (OSTI)

    Raymond L. Mazza

    2004-11-30

    These contract efforts involved the demonstration of a unique liquid free stimulation technology which was, at the beginning of these efforts, in 1993 unavailable in the US. The process had been developed, and patented in Canada in 1981, and held promise for stimulating liquid sensitive reservoirs in the US. The technology differs from that conventionally used in that liquid carbon dioxide (CO{sub 2}), instead of water is the base fluid. The CO{sub 2} is pumped as a liquid and then vaporizes at reservoir conditions, and because no other liquids or chemicals are used, a liquid free fracture is created. The process requires a specialized closed system blender to mix the liquid CO{sub 2} with proppant under pressure. These efforts were funded to consist of up to 21 cost-shared stimulation events. Because of the vagaries of CO{sub 2} supplies, service company support and operator interest only 19 stimulation events were performed in Montana, New Mexico, and Texas. Final reports have been prepared for each of the four demonstration groups, and the specifics of those demonstrations are summarized. A summary of the demonstrations of a novel liquid-free stimulation process which was performed in four groups of ''Candidate Wells'' situated in Crockett Co., TX; San Juan Co., NM; Phillips Co., MT; and Blaine Co., MT. The stimulation process which employs CO{sub 2} as the working fluid and the production responses were compared with those from wells treated with conventional stimulation technologies, primarily N{sub 2} foam, excepting those in Blaine Co., MT where the reservoir pressure is too low to clean up spent stimulation liquids. A total of 19 liquid-free CO{sub 2}/sand stimulations were performed in 16 wells and the production improvements were generally uneconomic.

  17. Studies on Ca2+-Doped CeBr3 Scintillating Materials

    SciTech Connect (OSTI)

    Guss, P. [NSTec; Foster, M. E. [SNL; Wong, B. M. [SNL; Doty, F. P. [SNL; Shah, K. [RMD; Squillante, M. [RMD; Glodo, J. [RMD; Yuan, D. [NSTec

    2013-07-03

    Despite the outstanding scintillation performance characteristics of cerium tribromide (CeBr3) and cerium-activated lanthanum tribromide (LaBr3:Ce), their commercial availability and application is limited due to the difficulties of growing large, crack-free single crystals from these fragile materials. The objective of this investigation was to employ aliovalent doping to increase crystal strength while maintaining the optical properties of the crystal. One divalent dopant (Ca2+) was investigated as a dopant to strengthen CeBr3 without negatively impacting scintillation performance. Ingots containing nominal concentrations of 1.9% of the Ca2+ dopant were grown. Preliminary scintillation measurements are presented for this aliovalently doped scintillator. Ca2+-doped CeBr3 exhibited little or no change in the peak fluorescence emission for 371 nm optical excitation for CeBr3. The structural, electronic, and optical properties of CeBr3 crystals were investigated using the density functional theory within generalized gradient approximation. The calculated lattice parameters are in good agreement with the experimental data. The energy band structures and density of states were obtained. The optical properties of CeBr3, including the dielectric function, were calculated.

  18. Processing of transparent polycrystalline AlON:Ce3+ scintillators

    SciTech Connect (OSTI)

    Chen, Ching -Fong; Yang, Pin; King, Graham; Tegtmeier, Eric L.

    2015-10-23

    A new polycrystalline ceramic scintillator is reported for potential use in radiation detection and medical imaging applications. The goal was to develop cerium-activated aluminum oxynitride (AlON:Ce3+) ceramics, which can be produced using ceramic processes in comparison to the high-cost, low-yield single-crystal growth technique. A phase pure AlON:Ce3+ powder with cubic symmetry was successfully synthesized at high temperature under a reducing atmosphere to convert Ce4+ to Ce3+ in the solid solution. We explored two different activator concentrations (0.5 and 1.0 mol%). Fully dense and transparent AlON:Ce3+ ceramics were produced by a liquid-phase-assisted pressureless sintering. The crystal field splitting around the Ce3+ activator in the AlON was comparable to the splitting induced by Br₋ and the Cl₋ ligands, which produced an emission spectrum perfectly matching the maximum quantum efficiency range of the photomultiplier tube for radiation detection. Both optical excitation and radiation ionizations in AlON:Ce3+ were demonstrated. Lastly, challenges and mechanisms related to the radioluminescence efficiency are discussed.

  19. SEMI-ANNUAL REPORTS FOR CE FLNG, LLC (CAMBRIDGE) - DK. NO. 12-123-LNG -

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ORDER 3193 | Department of Energy CE FLNG, LLC (CAMBRIDGE) - DK. NO. 12-123-LNG - ORDER 3193 SEMI-ANNUAL REPORTS FOR CE FLNG, LLC (CAMBRIDGE) - DK. NO. 12-123-LNG - ORDER 3193 April 2013 (330.47 KB) October 2013 (475.93 KB) April 2014 (137.83 KB) October 2014 (455.98 KB) April 2015 (566.96 KB) October 2015 (125.7 KB) April 2016 (98.14 KB) More Documents & Publications CE FLNG, LLC - FE DKT. NO. 12-123-LNG - ORDER 3193 EIS-0497: Notice of Intent to Prepare an Environmental Impact

  20. Antiferromagnetic Kondo lattice in the layered compound CePd1-xBi₂ and

    Office of Scientific and Technical Information (OSTI)

    comparison to the superconductor LaPd1-xBi₂ (Journal Article) | SciTech Connect Antiferromagnetic Kondo lattice in the layered compound CePd1-xBi₂ and comparison to the superconductor LaPd1-xBi₂ Citation Details In-Document Search Title: Antiferromagnetic Kondo lattice in the layered compound CePd1-xBi₂ and comparison to the superconductor LaPd1-xBi₂ The layered compound CePd1-xBi₂ with the tetragonal ZrCuSi₂-type structure was obtained from excess Bi flux. Magnetic

  1. Magnitude of the magnetic exchange interaction in the heavy-fermion antiferromagnet CeRhIn?

    SciTech Connect (OSTI)

    Das, Pinaki [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Lin, S. -Z. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Ghimire, N.? J. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Huang, K. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Univ. of California, San Diego, La Jolla, CA (United States); Ronning, F. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Bauer, E.? D. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Thompson, J.? D. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Batista, C.? D. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Ehlers, G. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Janoschek, M. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

    2014-12-01

    We have used high-resolution neutron spectroscopy experiments to determine the complete spin wave spectrum of the heavy-fermion antiferromagnet CeRhIn?. The spin wave dispersion can be quantitatively reproduced with a simple frustrated J??J? model that also naturally explains the magnetic spin-spiral ground state of CeRhIn? and yields a dominant in-plane nearest-neighbor magnetic exchange constant J?=0.74(3)??meV. Our results pave the way to a quantitative understanding of the rich low-temperature phase diagram of the prominent CeTIn? (T = Co, Rh, Ir) class of heavy-fermion materials.

  2. Dune-dammed lakes of the Nebraska Sand Hills: Geologic setting and paleoclimatic implications

    SciTech Connect (OSTI)

    Loope, D.B.; Swinehart, J.B. (Univ. of Nebraska, Lincoln, NE (United States))

    1992-01-01

    Within the western half of this grass-stabilized dunefield, about 1,000 interdune lakes are grouped into two clusters here named the Blue and Birdwood lake basins. In the lake basins, those parts of the valley not filled by dune sand are occupied by modern lakes and Holocene lake sediments. The Blue Creek dam is mounded transverse to flow; spill-over of the lake basin takes place over bedrock on the east side of the dam when lake level is 2 m higher than present. The permeability of dune sand prevents massive overflow, and thereby contributes to the integrity and longevity of the dam. Preserved lake sediments in the basin indicate that Blue Creek was obstructed prior to 13,000 yr BP, probably during glacial maximum (18,000 yr BP). Extensive peats dated at 1,500-1,000 yr BP lie directly on fluvial sand and gravel along the Calamus River, a stream that presently discharges a nearly constant 350 cfs. These sediments indicate blockage of streams also took place when linear dunes were active in the eastern Sand Hills in Late Holocene time. With the onset of an arid episode, dunes forming an interfluves curtail the severity of runoff events. As the regional water table drops, drainages go dry and dunes move uncontested into blocking positions. Although drainages of the eastern Sand Hills appear to have repeatedly broken through sand-blocked channels, the Blue and Birdwood lake basins are still blocked by Late Pleistocene dune dams. The repeated episodes of stream blockage and interbedded lake sediments and dune sands behind the extant dams record several strong fluctuations in Holocene climate. Recently proposed climatic models indicate that the northward flow of warm, moist air from the Gulf of Mexico is enhanced when the Gulf's surface temperature is low and the Bermuda high is intensified and in a western position. When the Bermuda high moves eastward, the core of the North American continent becomes desiccated.

  3. SOLVING THE SHUGART QUEEN SAND PENASCO UNIT DECLINING PRODUCTION PROBLEM

    SciTech Connect (OSTI)

    Lowell Deckert

    2000-08-25

    The Penasco Shugart Queen Sand Unit located in sections 8, 9, 16 & 17, T18S, 31E Eddy County New Mexico is operated by MNA Enterprises Ltd. Co. Hobbs, NM. The first well in the Unit was drilled in 1939 and since that time the Unit produced 535,000 bbl of oil on primary recovery and 375,000 bbl of oil during secondary recovery operations that commenced in 1973. The Unit secondary to primary ratio is 0.7, but other Queen waterfloods in the area had considerably larger S/P ratios. On June 25 1999 MNA was awarded a grant under the Department of Energy's ''Technology Development with Independents'' program. The grant was used to fund a reservoir study to determine if additional waterflood reserves could be developed. A total of 14 well bores that penetrate the Queen at 3150 ft are within the Unit boundaries. Eleven of these wells produced oil during the past 60 years. Production records were pieced together from various sources including the very early state production records. One very early well had a resistivity log, but nine of the wells had no logs, and four wells had gamma ray-neutron count-rate perforating logs. Fortunately, recent offset deep drilling in the area provided a source of modern logs through the Queen. The logs from these wells were used to analyze the four old gamma ray-neutron logs within the Unit. Additionally the offset well log database was sufficient to construct maps through the unit based on geostatistical interpolation methods. The maps were used to define the input parameters required to simulate the primary and secondary producing history. The history-matched simulator was then used to evaluate four production scenarios. The best scenario produces 51,000 bbl of additional oil over a 10-year period. If the injection rate is held to 300 BWPD the oil rate declines to a constant 15 BOPD after the first year. The projections are reasonable when viewed in the context of the historical performance ({approx}30 BOPD with a {approx}600 BWPD

  4. Lattice instabilities in heavy fermion superconductors. [CeCu/sub 2/Si/sub 2/; CeAl/sub 3/; CeCu/sub 6/; UBe/sub 13/; UPt/sub 3/

    SciTech Connect (OSTI)

    Wohlleben, D.

    1987-01-01

    This paper shows that while in nonsuperconducting HF systems such as CeCu/sub 6/, CeAl/sub 3/ and stoichiometric CeCu/sub 2/Si/sub 2/, the large electronic ..gamma.. is due to a very narrow f band, in the three HF superconductors UBe/sub 13/, UPt/sub 3/ and nonstochiometric CeCu/sub 2/Si/sub 2/, it is not. The f band of these systems, as measured by their response to magnetic fields in three different ways, is much wider than suggested by the large ..gamma... According to their actual f band width, the HF superconductors belong into the Bantam Fermion class. It is argued that most of the large ..gamma.. of the HF superconductors is not of electronic origin and that it is instead caused by the precursor of a martensitic phase transition of the lattice or by a crystallographic phase mixture, i.e., that it is due to the displacive degrees of freedom. This suggests that the superconductivity of all three HF superconductors is caused by some special, low energy phonons rather than by a narrow f band. 52 refs., 4 figs., 3 tabs.

  5. A comparison of the structure and localized magnetism in Ce{sub 2}PdGa{sub 12} with the heavy fermion CePdGa{sub 6}

    SciTech Connect (OSTI)

    Macaluso, Robin T. [Department of Chemistry, Louisiana State University, Baton Rouge, LA 70803 (United States); Millican, Jasmine N. [Department of Chemistry, Louisiana State University, Baton Rouge, LA 70803 (United States); Nakatsuji, Satoru [Department of Physics, Kyoto University, Kyoto, Japan 606-8502 (Japan); Lee, Han-Oh [Department of Physics, University of California, Davis, CA 95616 (United States); Carter, B. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Moreno, Nelson O. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Fisk, Zachary [Department of Physics, University of California, Davis, CA 95616 (United States); Chan, Julia Y. [Department of Chemistry, Louisiana State University, Baton Rouge, LA 70803 (United States)]. E-mail: jchan@lsu.edu

    2005-11-15

    Single crystals of Ce{sub 2}PdGa{sub 12} have been synthesized in Ga flux and characterized by X-ray diffraction. This compound crystallizes in the tetragonal P4/nbm space group, Z=2 with lattice parameters of a=6.1040(2)A and c=15.5490(6)A. It shows strongly anisotropic magnetism and orders antiferromagnetically at T{sub N}{approx}11K. A field-induced metamagnetic transition to the ferromagnetic state is observed below T{sub N}. Structure-property relationships with the related heavy-fermion antiferromagnet CePdGa{sub 6} are discussed.

  6. Determination of the Surface Structure of CeO2(111) by Low-Energy...

    Office of Scientific and Technical Information (OSTI)

    Title: Determination of the Surface Structure of CeO2(111) by Low-Energy Electron Diffraction. Abstract not provided. Authors: McCarty, Kevin F. ; Siegel, David A ; El Gabaly ...

  7. ASKO Appliances: Order (2012-CE-19/2004) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (2012-CE-192004) July 20, 2012 DOE ordered ASKO Appliances, Inc. to pay a 36,500 civil penalty after finding ASKO had failed to certify that certain models of residential...

  8. Acetaldehyde Adsorption and Reaction onCeO2(100) Thin Films

    SciTech Connect (OSTI)

    Mullins, David R; Albrecht, Peter M

    2013-01-01

    This study reports and compares the adsorption and dissociation of acetaldehyde on oxidized and reduced CeOX(100) thin films. Acetaldehyde reacts and decomposes on fully oxidized CeO2(100) whereas it desorbs molecularly at low temperature on CeO2(111). The primary products are CO, CO2 and water along with trace amounts of crotonaldehyde and acetylene. The acetaldehyde adsorbs as the 2-acetaldehyde species, dioxyethylene. Decomposition proceeds by dehydrogenation through acetate and enolate intermediates. The reaction pathway is similar on the reduced CeO2-X(100) surface however the inability to react with surface O on the reduced surface results in H2 rather than H2O desorption and C is left on the surface rather than producing CO and CO2. C-O bond cleavage in the enolate intermediate followed by reaction with surface H results in ethylene desorption.

  9. Chemical stability and Ce doping of LiMgAlF6 neutron scintillator

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Du, M. H.

    2014-11-13

    We perform density functional calculations to investigate LiMgAlF6 as a potential neutron scintillator material. The calculations of enthalpy of formation and phase diagram show that single-phase LiMgAlF6 can be grown but it should be more difficult than growing LiCaAlF6 and LiSrAlF6. Moreover, the formation energy calculations for substitutional Ce show that the concentration of Ce on the Al site is negligible but a high concentration (>1 at.%) of Ce on the Mg site is attainable provided that the Fermi level is more than 5 eV lower than the conduction band minimum. Acceptor doping should promote Ce incorporation in LiMgAlF6.

  10. Switching of the Spin-Density-Wave in CeCoIn5 probed by Thermal...

    Office of Scientific and Technical Information (OSTI)

    Switching of the Spin-Density-Wave in CeCoIn5 probed by Thermal Conductivity Citation ... Visit OSTI to utilize additional information resources in energy science and technology. A ...

  11. Switching of the Spin-Density-Wave in CeCoIn5 probed by Thermal...

    Office of Scientific and Technical Information (OSTI)

    Title: Switching of the Spin-Density-Wave in CeCoIn5 probed by Thermal Conductivity Authors: Kim, Duk Young 1 ; Lin, Shizeng 1 ; Weickert, Franziska 2 ; Bauer, Eric Dietzgen ...

  12. Pressure-Induced Structural Phase Transition in CeNi: X-ray and...

    Office of Scientific and Technical Information (OSTI)

    Pressure-Induced Structural Phase Transition in CeNi: X-ray and Neutron Scattering Studies and First-Principles Calculations Citation Details In-Document Search Title: ...

  13. Pressure tuning of competing magnetic interactions in intermetallic CeFe2

    SciTech Connect (OSTI)

    Wang, Jiyang; Feng, Yejun; Jaramillo, R.; van Wezel, Jasper; Canfield, Paul C.; Rosenbaum, T.F.

    2012-07-20

    We use high-pressure magnetic x-ray diffraction and numerical simulation to determine the low-temperature magnetic phase diagram of stoichiometric CeFe2. Near 1.5 GPa we find a transition from ferromagnetism to antiferromagnetism, accompanied by a rhombohedral distortion of the cubic Laves crystal lattice. By comparing pressure and chemical substitution we find that the phase transition is controlled by a shift of magnetic frustration from the Ce-Ce to the Fe-Fe sublattice. Notably the dominant Ce-Fe magnetic interaction, which sets the temperature scale for the onset of long-range order, remains satisfied throughout the phase diagram but does not determine the magnetic ground state. Our results illustrate the complexity of a system with multiple competing magnetic energy scales and lead to a general model for magnetism in cubic Laves phase intermetallic compounds.

  14. NMR studies of field induced magnetism in CeCoIn5 (Journal Article...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: NMR studies of field induced magnetism in CeCoIn5 Citation Details In-Document Search Title: ... Publication Date: 2009-01-01 OSTI Identifier: 972060 Report ...

  15. Magnetic Hardening of CeFe11Ti and the Effect of TiC Addition...

    Office of Scientific and Technical Information (OSTI)

    Magnetic Hardening of CeFe11Ti and the Effect of TiC Addition Citation ... Publication Date: 2015-04-01 OSTI Identifier: 1221660 Report Number(s): IS-J 8423 Journal ID: ISSN ...

  16. Hyperfine field and magnetic structure in the B phase of CeCoIn5...

    Office of Scientific and Technical Information (OSTI)

    We re-analyze Nuclear Magnetic Resonance (NMR) spectra observed at low temperatures and high magnetic fields in the field-induced B-phase of CeCoInsub 5. The NMR spectra are ...

  17. f-electron correlations in nonmagnetic Ce studied by means of...

    Office of Scientific and Technical Information (OSTI)

    f-electron correlations in nonmagnetic Ce studied by means of spin-resolved resonant photoemission Citation Details In-Document Search Title: f-electron correlations in nonmagnetic ...

  18. Ex Parte Communications in Connection with Docket No EERE-2014-BT-CE-0019

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Conservation Program: Certification, Compliance, Labeling, and Enforcement for Electric Motors and Small Electric Motors; Proposed Rule | Department of Energy No EERE-2014-BT-CE-0019 Energy Conservation Program: Certification, Compliance, Labeling, and Enforcement for Electric Motors and Small Electric Motors; Proposed Rule Ex Parte Communications in Connection with Docket No EERE-2014-BT-CE-0019 Energy Conservation Program: Certification, Compliance, Labeling, and Enforcement for

  19. Structure and magnetic properties of LnMnSbO ( Ln=La and Ce)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Qiang; Kumar, C. M. N.; Tian, Wei; Dennis, Kevin W.; Goldman, Alan I.; Vaknin, David

    2016-03-11

    Here, a neutron powder diffraction (NPD) study of LnMnSbO (Ln = La or Ce) reveals differences between the magnetic ground state of the two compounds due to the strong Ce-Mn coupling compared to La-Mn. The two compounds adopt the P4/nmm space group down to 2 K, and whereas magnetization measurements do not show obvious anomaly at high temperatures, NPD reveals a C-type antiferromagnetic (AFM) order below TN = 255K for LaMnSbO and 240 K for CeMnSbO. While the magnetic structure of LaMnSbO is preserved to base temperature, a sharp transition at TSR = 4.5K is observed in CeMnSbO due tomore » a spin-reorientation (SR) transition of the Mn2+ magnetic moments from pointing along the c axis to the ab plane. The SR transition in CeMnSbO is accompanied by a simultaneous long-range AFM ordering of the Ce moments, which indicates that the Mn SR transition is driven by the Ce-Mn coupling. The ordered moments are found to be somewhat smaller than those expected for Mn2+ (S = 5/2) in insulators, but large enough to suggest that these compounds belong to the class of local-moment antiferromagnets. The lower TN found in these two compounds compared to the As-based counterparts (TN = 317 for LaMnAsO, TN = 347K for CeMnAsO) indicates that the Mn-Pn (Pn=As or Sb) hybridization that mediates the superexchange Mn-Pn-Mn coupling is weaker for the Sb-based compounds.« less

  20. Mitsubishi Electric: Consent Decree (2011-CE-01/0202) | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Mitsubishi Electric: Consent Decree (2011-CE-01/0202) Mitsubishi Electric: Consent Decree (2011-CE-01/0202) May 7, 2010 In this consent degree, the Air-Conditioning, Heating and Refrigeration Institute (AHRI) agrees to pay $5,000 on behalf of Mitsubishi Electric & Electronics, USA, Inc. Mitsubishi Electric agreed that the required certification reports were not filed with DOE; however, Mitsubishi had an agreement with AHRI for AHRI to submit those reports on Mitsubishi's behalf.

  1. Results for aliovalent doping of CeBr{sub 3} with Ca{sup 2+}

    SciTech Connect (OSTI)

    Guss, Paul; Foster, Michael E.; Wong, Bryan M.; Patrick Doty, F.; Shah, Kanai; Squillante, Michael R.; Shirwadkar, Urmila; Hawrami, Rastgo; Tower, Joshua; Yuan, Ding

    2014-01-21

    Despite the outstanding scintillation performance characteristics of cerium tribromide (CeBr{sub 3}) and cerium-activated lanthanum tribromide, their commercial availability and application are limited due to the difficulties of growing large, crack-free single crystals from these fragile materials. This investigation employed aliovalent doping to increase crystal strength while maintaining the optical properties of the crystal. One divalent dopant (Ca{sup 2+}) was used as a dopant to strengthen CeBr{sub 3} without negatively impacting scintillation performance. Ingots containing nominal concentrations of 1.9% of the Ca{sup 2+} dopant were grown, i.e., 1.9% of the CeBr{sub 3} molecules were replaced by CaBr{sub 2} molecules, to match our target replacement of 1 out of 54 cerium atoms be replaced by a calcium atom. Precisely the mixture was composed of 2.26 g of CaBr{sub 2} added to 222.14 g of CeBr{sub 3}. Preliminary scintillation measurements are presented for this aliovalently doped scintillator. Ca{sup 2+}-doped CeBr{sub 3} exhibited little or no change in the peak fluorescence emission for 371?nm optical excitation for CeBr{sub 3}. The structural, electronic, and optical properties of CeBr{sub 3} crystals were studied using the density functional theory within the generalized gradient approximation. Calculated lattice parameters are in agreement with the experimental data. The energy band structures and density of states were obtained. The optical properties of CeBr{sub 3}, including the dielectric function, were calculated.

  2. Reevaluation of Stevens sand potential - Maricopa depocenter, southern San Joaquin basin, California

    SciTech Connect (OSTI)

    Kolb, M.M.; Parks, S.L. )

    1991-02-01

    During the upper Miocene in the Southern San Joaquin basin surrounding highlands contributed coarse material to a deep marine basin dominated by fine grained silicious bioclastic deposition. these coarse deposits became reservoirs isolated within the silicious Antelope Shale Member of the Monterey Formation. In the southern Maricopa depocenter these Stevens sands are productive at Yowlumne, Landslide, Aqueduct, Rio Viejo, San Emidio Nose, Paloma, and Midway-Sunset fields, and are major exploration targets in surrounding areas. In the ARCO Fee lands area of the southern Maricopa depocenter, Stevens sands occur as rapidly thickening lens-shaped bodies that formed as channel, levee, and lobe deposits of deep-marine fan systems. These fans were fed from a southerly source, with apparent transport in a north-northwesterly direction. Sands deflect gently around present-day structural highs indicating that growth of structures influenced depositional patterns. Correlations reveal two major fan depositional intervals bounded by regional N, O, and P chert markers. Each interval contains numerous individual fan deposits, with many lobes and channels recognizable on three-dimensional seismic data. In addition to these basinal sand plays presently being evaluated, ARCO is pursuing a relatively new trend on Fee lands along the southern basin margin, where correlation to mountain data reveals Stevens sands trend into the steeply dipping beds of the mountain front. This area, the upturned Stevens,' has large reserve potential and producing analogies at Metson, Leutholtz, Los Lobos, and Pleito Ranch fields.

  3. The extraction of bitumen from western oil sands. Annual report, July 1991--July 1992

    SciTech Connect (OSTI)

    Oblad, A.G.; Bunger, J.W.; Dahlstrom, D.A.; Deo, M.D.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1992-08-01

    The University of Utah tar sand research and development program is concerned with research and development on Utah is extensive oil sands deposits. The program has been intended to develop a scientific and technological base required for eventual commercial recovery of the heavy oils from oil sands and processing these oils to produce synthetic crude oil and other products such as asphalt. The overall program is based on mining the oil sand, processing the mined sand to recover the heavy oils and upgrading them to products. Multiple deposits are being investigated since it is believed that a large scale (approximately 20,000 bbl/day) plant would require the use of resources from more than one deposit. The tasks or projects in the program are organized according to the following classification: Recovery technologies which includes thermal recovery methods, water extraction methods, and solvent extraction methods; upgrading and processing technologies which covers hydrotreating, hydrocracking, and hydropyrolysis; solvent extraction; production of specialty products; and environmental aspects of the production and processing technologies. These tasks are covered in this report.

  4. Regional aeolian dynamics and sand mixing in the Gran Desierto: Evidence from Landsat thematic mapper images

    SciTech Connect (OSTI)

    Blount, G.; Greeley, R.; Christensen, P.R. (Arizona State Univ., Tempe (USA)); Smith, M.O.; Adams, J.B. (Univ. of Washington, Seattle (USA))

    1990-09-10

    Spatial variations in sand composition were mapped on a regional scale in a terrestrial sand sea, the Gran Desierto of Sonora, Mexico. Mesoscale mapping on a satellite image base allowed quantitative interpretation of the dynamic development of sand sheets and dunes. The results were used to interpret the Quaternary geologic history of the tectonically active region at the mouth of the Colorado River. Landsat thematic mapper multispectral images were used to predict the abundance of different mineralogies of sand grains in a mixed aeolian terrain. A spectral mixing model separated the effects of vegetation and topographically induced shading and shadow from the effects produced by different mineral and rock types. Compositions determined remotely agreed well with samples from selected areas within the spectral limitations of the thematic mapper. A simple discrimination capability for active versus inactive sand surfaces is demonstrated based upon differences in the percentage of low-albedo accessory grains occurring on dormant aeolian surfaces. A technique for discriminating between low-albedo materials and macroscopic shade is implemented by combing thermal images with the results of the spectral mixing model. The image analysis revealed important compositional variations over large areas that were not readily apparent in the field.

  5. An Update on Improvements to NiCE Support for RELAP-7

    SciTech Connect (OSTI)

    McCaskey, Alex; Wojtowicz, Anna; Deyton, Jordan H.; Patterson, Taylor C.; Billings, Jay Jay

    2015-01-01

    The Multiphysics Object-Oriented Simulation Environment (MOOSE) is a framework that facilitates the development of applications that rely on finite-element analysis to solve a coupled, nonlinear system of partial differential equations. RELAP-7 represents an update to the venerable RELAP-5 simulator that is built upon this framework and attempts to model the balance-of-plant concerns in a full nuclear plant. This report details the continued support and integration of RELAP-7 and the NEAMS Integrated Computational Environment (NiCE). RELAP-7 is fully supported by the NiCE due to on-going work to tightly integrate NiCE with the MOOSE framework, and subsequently the applications built upon it. NiCE development throughout the first quarter of FY15 has focused on improvements, bug fixes, and feature additions to existing MOOSE-based application support. Specifically, this report will focus on improvements to the NiCE MOOSE Model Builder, the MOOSE application job launcher, and the 3D Nuclear Plant Viewer. This report also includes a comprehensive tutorial that guides RELAP-7 users through the basic NiCE workflow: from input generation and 3D Plant modeling, to massively parallel job launch and post-simulation data visualization.

  6. Antiferromagnetic ordering in the doped Kondo insulator CeRhSb

    SciTech Connect (OSTI)

    Menon, L.; Malik, S.K.

    1997-06-01

    CeRhSb, the so-called {open_quotes}Kondo insulator,{close_quotes} is a mixed-valent compound showing a gap formation in the electronic density of states. On the other hand, CePdSb is ferromagnetically ordered with a Curie temperature of {approximately}17 K. We have carried out magnetic susceptibility and electrical resistivity measurements on CeRh{sub 1{minus}x}Pd{sub x}Sb (0{le}x{le}1.0), to study the ground-state properties of this system. For small Pd doping in CeRhSb, up to 20{percent}, the gap continually diminishes and no magnetic ordering is observed down to 2 K. In the region 0.3{le}x{le}0.4, as soon as the gap is suppressed, an antiferromagnetic ground state is observed. In the region 0.5{le}x{lt}0.7, the compounds are not single phase. At the CePdSb end, in the region 0.7{le}x{le}1, the ground state is ferromagnetic. The observation of an antiferromagnetic phase in the phase diagram of CeRh{sub 1{minus}x}Pd{sub x}Sb, where neither end is antiferromagnetic, is interesting and is discussed in the light of some recent theoretical models. {copyright} {ital 1997} {ital The American Physical Society}

  7. Structure and scintillation yield of Ce-doped AlGa substituted yttrium garnet

    SciTech Connect (OSTI)

    Sidletskiy, Oleg; Kononets, Valerii; Lebbou, Kheirreddine; Neicheva, Svetlana; Voloshina, Olesya; Bondar, Valerii; Baumer, Vyacheslav; Belikov, Konstantin; Gektin, Alexander; Grinyov, Boris; Joubert, Marie-France

    2012-11-15

    Highlights: ? Range of Y{sub 3}(Al{sub 1?x}Ga{sub x}){sub 5}O{sub 12}:Ce solid solution crystals are grown from melt by the Czochralski method. ? Light yield of mixed crystals reaches 130% of the YAG:Ce value at x ? 0.4. ? ?1% of antisite defects is formed in YGG:Ce, but no evidence of this is obtained for the rest of crystals. -- Abstract: Structure and scintillation yield of Y{sub 3}(Al{sub 1?x}Ga{sub x}){sub 5}O{sub 12}:Ce solid solution crystals are studied. Crystals are grown from melt by the Czochralski method. Distribution of host cations in crystal lattice is determined. Quantity of antisite defects in crystals is evaluated using XRD and atomic emission spectroscopy data. Trend of light output at Al/Ga substitution in Y{sub 3}(Al{sub 1?x}Ga{sub x}){sub 5}O{sub 12}:Ce is determined for the first time. Light output in mixed crystals reaches 130% comparative to Ce-doped yttriumaluminum garnet. Luminescence properties at Al/Ga substitution are evaluated.

  8. Effects of placement method on geotechnical behavior of hydraulic fill sands

    SciTech Connect (OSTI)

    Lee, K.M.; Shen, C.K.; Leung, D.H.K.; Mitchell, J.K.

    1999-10-01

    Results of an investigation of the geotechnical behavior of a hydraulic sand placed at a land reclamation site in Hong Kong are presented and interpreted. The study was conducted to aid in developing guidelines for quality control of hydraulic landfill placement. The work described consisted of: (1) field investigations; (2) static and cyclic triaxial testing; and (3) calibration chamber tests to study the cone penetration test versus D, relationships for marine sands obtained from the reclamation sites. The results of this study clearly indicate that the placement technique is the single most important factor controlling the geotechnical behavior of a given type of sand when placed as a hydraulic fill. The weakest zone is generally located just beneath the water level where fill deposition is placed by pipeline discharge.

  9. Luminescence properties and electronic structure of Ce{sup 3+}-doped gadolinium aluminum garnet

    SciTech Connect (OSTI)

    Dotsenko, V.P.; Berezovskaya, I.V.; Voloshinovskii, A.S.; Zadneprovski, B.I.; Efryushina, N.P.

    2015-04-15

    Highlights: • The luminescence properties of Ce{sup 3+} ions in (Y, Gd){sub 3}Al{sub 5}O{sub 12} are analyzed. • The Gd{sup 3+} → Y{sup 3+} substitution leads to increasing of Ce{sup 3+} noncubic crystal field splitting parameter. • The excitation spectra for the Ce{sup 3+} emission in GdAG contain bands at 6.67, 7.75, and 9.76 eV. • These features are due to the Ce{sup 3+}-bound exciton formation and O 2p → Al 3s, 3p transitions. • Contributions from Al atoms to the conduction-band density of states are quite essential. - Abstract: Yttrium-gadolinium aluminum garnets (YGdAG) doped with Ce{sup 3+} ions have been prepared by co-precipitation method. The luminescent properties of Ce{sup 3+} ions in Gd{sub 3(1−x)}Ce{sub 3x}Al{sub 5}O{sub 12} (x = 0.01) have been studied upon excitation in the 2–20 eV region. The substitution of Gd{sup 3+} for Y{sup 3+} in the garnet structure results in broadening the emission band and shifting its maximum towards the longer wavelengths. It was found that in addition to the 4f → 5d excitation bands of Ce{sup 3+} ions, the excitation spectra for the Ce{sup 3+} emission contain bands at 6.67, 7.75, and 9.76 eV. These bands are attributed to the Ce{sup 3+}-bound exciton formation and O 2p → Al 3s, 3p transitions, respectively. Although gadolinium states dominate near the bottom of the conduction band of Gd{sub 3}Al{sub 5}O{sub 12}, contributions from Al{sub tetr} and Al{sub oct} atoms to the conduction-band density of states are evaluated as quite essential.

  10. Western Gas Sands Project: production histories of the Piceance and Uinta basins of Colorado and Utah

    SciTech Connect (OSTI)

    Anderson, S.; Kohout, J.

    1980-11-20

    Current United States geological tight sand designations in the Piceance and Uinta Basins' Western Gas Sands Project include the Mesaverde Group, Fort Union and Wasatch Formations. Others, such as the Dakota, Cedar Mountain, Morrison and Mancos may eventually be included. Future production from these formations will probably be closely associated with existing trends. Cumulative gas production through December 1979, of the Mesaverde Group, Fort Union and Wasatch Formations in the Piceance and Uinta Basins is less than 275 billion cubic feet. This contrasts dramatically with potential gas in place estimates of 360 trillion cubic feet. If the geology can be fully understood and engineering problems surmounted, significant potential reserves can be exploited.