Sample records for moisture rh atmospheric

  1. Atmospheric Moisture Transports from Ocean to Land and Global Energy Flows in Reanalyses

    E-Print Network [OSTI]

    Fasullo, John

    Atmospheric Moisture Transports from Ocean to Land and Global Energy Flows in Reanalyses KEVIN E energy and hydrological cycles from eight current atmospheric reanalyses and their depiction of changes over time. A brief evaluation of the water and energy cycles in the latest version of the NCAR climate

  2. Atmospheric Moisture Budget and Spatial Resolution Dependence of Precipitation Extremes in Aquaplanet Simulations

    SciTech Connect (OSTI)

    Yang, Qing; Leung, Lai-Yung R.; Rauscher, Sara; Ringler, Todd; Taylor, Mark

    2014-05-01T23:59:59.000Z

    This study investigates the resolution dependency of precipitation extremes in an aqua-planet framework. Strong resolution dependency of precipitation extremes is seen over both tropics and extra-tropics, and the magnitude of this dependency also varies with dynamical cores. Moisture budget analyses based on aqua-planet simulations with the Community Atmosphere Model (CAM) using the Model for Prediction Across Scales (MPAS) and High Order Method Modeling Environment (HOMME) dynamical cores but the same physics parameterizations suggest that during precipitation extremes moisture supply for surface precipitation is mainly derived from advective moisture convergence. The resolution dependency of precipitation extremes mainly originates from advective moisture transport in the vertical direction. At most vertical levels over the tropics and in the lower atmosphere over the subtropics, the vertical eddy transport of mean moisture field dominates the contribution to precipitation extremes and its resolution dependency. Over the subtropics, the source of moisture, its associated energy, and the resolution dependency during extremes are dominated by eddy transport of eddies moisture at the mid- and upper-troposphere. With both MPAS and HOMME dynamical cores, the resolution dependency of the vertical advective moisture convergence is mainly explained by dynamical changes (related to vertical velocity or omega), although the vertical gradients of moisture act like averaging kernels to determine the sensitivity of the overall resolution dependency to the changes in omega at different vertical levels. The natural reduction of variability with coarser resolution, represented by areal data averaging (aggregation) effect, largely explains the resolution dependency in omega. The thermodynamic changes, which likely result from non-linear feedback in response to the large dynamical changes, are small compared to the overall changes in dynamics (omega). However, after excluding the data aggregation effect in omega, thermodynamic changes become relatively significant in offsetting the effect of dynamics leading to reduce differences between the simulated and aggregated results. Compared to MPAS, the simulated stronger vertical motion with HOMME also results in larger resolution dependency. Compared to the simulation at fine resolution, the vertical motion during extremes is insufficiently resolved/parameterized at the coarser resolution even after accounting for the natural reduction in variability with coarser resolution, and this is more distinct in the simulation with HOMME. To reduce uncertainties in simulated precipitation extremes, future development in cloud parameterizations must address their sensitivity to spatial resolution as well as dynamical cores.

  3. Moisture absorption in hybrid composites

    E-Print Network [OSTI]

    Clark, Dan Laro

    1983-01-01T23:59:59.000Z

    . Calculated Moisture Profile: 8/F1552/F1858' ' 95~ RH Calculated Moisture Profile: F1558/F1852/F1558. 49'C, 954 RH. Calculated Moisture Profile: F155, 8. 49 C, 95% RH. Calculated Moisture Profile: F18518. 49'C, 95% RH. Effect of F185 Coating on F155.... Calculated Moisture Profile F18518-. 49'C, 95% RH. 1. 4 1. 05 0 . 35 I I I / / / I F155 18 F 1 8 5 1/F 1 5 5 8/Fl 85 0 0 16 25 32. 5 48. 75 Time(Hours) Figure 28. Effect of F185 Coating on F155 Core: 49'C, 95o HEI. Us Ut 1. 4 1. 05 7 . 35 I...

  4. Soil moisture regulates the biological response of elevated atmospheric CO2 concentrations in a coupled

    E-Print Network [OSTI]

    Niyogi, Dev

    and Atmospheric Sciences, Purdue University, United States b Departments of Geography and Atmospheric and Oceanic Sciences, University of California at Los Angeles, United States Received 16 March 2005; received surface model, dynamically coupled to an atmospheric boundary layer and surface energy balance scheme

  5. Moisture budget of the Arctic atmosphere from TOVS satellite data David G. Groves

    E-Print Network [OSTI]

    Francis, Jennifer

    and radiative heating of the atmosphere. These, in turn, affect surface temperature, ice growth and melt and hemispheric atmospheric processes affect the Arctic Ocean. The lack of humidity data over the Arctic Ocean. Our method yields an average annual net precipitation of 15.1 cm yrÀ1 over the polar cap (poleward

  6. International H2O Project (IHOP) 2002: Datasets Related to Atmospheric Moisture and Rainfall Prediction

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Schanot, Allen [IHOP 2002 PI; Friesen, Dick [IHOP 2002 PI

    IHOP 2002 was a field experiment that took place over the Southern Great Plains of the United States from 13 May to 25 June 2002. The chief aim of IHOP_2002 was improved characterization of the four-dimensional (4-D) distribution of water vapor and its application to improving the understanding and prediction of convection. The region was an optimal location due to existing experimental and operational facilities, strong variability in moisture, and active convection [copied from http://www.eol.ucar.edu/projects/ihop/]. The project's master list of data identifies 146 publicly accessible datasets.

  7. ARM - Measurement - Atmospheric moisture

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadap Documentation TDMADAP : XDC documentationBarrow, AlaskaWhenimage ARM Dataparticlemoisture ARM

  8. IMPACTS OF SOIL MOISTURE VARIABILITY ON CONVECTIVE PRECIPITATION IN THE CENTRAL PLAINS THROUGH LAND-ATMOSPHERE FEEDBACKS

    E-Print Network [OSTI]

    Jones, Aubrey R.

    2008-08-20T23:59:59.000Z

    of cummulative precipitation for a) FC b) 50FC c) WP ............ 31 Figure 4. Precipitation summed over the domain for the 12 day period for each model run............................................................................................................................ 66 Figure 17. Scatter plots of soil moisture versus Bowen ratio (top) a) FC b) 50FC c) WP and soil moisture versus net radiation (bottom) d) FC e) 50FC f) WP for the 4 km runs...

  9. Radiosondes Corrected for Inaccuracy in RH Measurements

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Miloshevich, Larry

    Corrections for inaccuracy in Vaisala radiosonde RH measurements have been applied to ARM SGP radiosonde soundings. The magnitude of the corrections can vary considerably between soundings. The radiosonde measurement accuracy, and therefore the correction magnitude, is a function of atmospheric conditions, mainly T, RH, and dRH/dt (humidity gradient). The corrections are also very sensitive to the RH sensor type, and there are 3 Vaisala sensor types represented in this dataset (RS80-H, RS90, and RS92). Depending on the sensor type and the radiosonde production date, one or more of the following three corrections were applied to the RH data: Temperature-Dependence correction (TD), Contamination-Dry Bias correction (C), Time Lag correction (TL). The estimated absolute accuracy of NIGHTTIME corrected and uncorrected Vaisala RH measurements, as determined by comparison to simultaneous reference-quality measurements from Holger Voemel's (CU/CIRES) cryogenic frostpoint hygrometer (CFH), is given by Miloshevich et al. (2006).

  10. Soil moisture in complex terrain: quantifying effects on atmospheric boundary layer flow and providing improved surface boundary conditions for mesoscale models

    E-Print Network [OSTI]

    Daniels, Megan Hanako

    2010-01-01T23:59:59.000Z

    74 ii Soil Moisture Sensors: Decagon ECH2O Capacitance133 A.10 Soil types corresponding to each75 Soil Moisture and Temperature Probe

  11. RH Packaging Operations Manual

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2003-09-17T23:59:59.000Z

    This procedure provides operating instructions for the RH-TRU 72-B Road Cask, Waste Shipping Package. In this document, ''Packaging'' refers to the assembly of components necessary to ensure compliance with the packaging requirements (not loaded with a payload). ''Package'' refers to a Type B packaging that, with its radioactive contents, is designed to retain the integrity of its containment and shielding when subject to the normal conditions of transport and hypothetical accident test conditions set forth in 10 CFR Part 71. Loading of the RH 72-B cask can be done two ways, on the RH cask trailer in the vertical position or by removing the cask from the trailer and loading it in a facility designed for remote-handling (RH). Before loading the 72-B cask, loading procedures and changes to the loading procedures for the 72-B cask must be sent to CBFO at sitedocuments@wipp.ws for approval.

  12. Soil moisture modeling and scaling using passive microwave remote sensing

    E-Print Network [OSTI]

    Das, Narendra N.

    2007-04-25T23:59:59.000Z

    Soil moisture in the shallow subsurface is a primary hydrologic state governing land-atmosphere interaction at various scales. The primary objectives of this study are to model soil moisture in the root zone in a distributed manner and determine...

  13. Soil moisture in complex terrain: quantifying effects on atmospheric boundary layer flow and providing improved surface boundary conditions for mesoscale models

    E-Print Network [OSTI]

    Daniels, Megan Hanako

    2010-01-01T23:59:59.000Z

    groundwater, land-surface, and mesoscale atmospheric model-and modification of mesoscale circulations. , Mon. Wea.J. Davis, The effects of mesoscale surface heterogeneity on

  14. RH Packaging Program Guidance

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2008-01-12T23:59:59.000Z

    The purpose of this program guidance document is to provide the technical requirements for use, operation, inspection, and maintenance of the RH-TRU 72-B Waste Shipping Package (also known as the "RH-TRU 72-B cask") and directly related components. This document complies with the requirements as specified in the RH-TRU 72-B Safety Analysis Report for Packaging (SARP), and Nuclear Regulatory Commission (NRC) Certificate of Compliance (C of C) 9212. If there is a conflict between this document and the SARP and/or C of C, the C of C shall govern. The C of C states: "...each package must be prepared for shipment and operated in accordance with the procedures described in Chapter 7.0, Operating Procedures, of the application." It further states: "...each package must be tested and maintained in accordance with the procedures described in Chapter 8.0, Acceptance Tests and Maintenance Program of the Application." Chapter 9.0 of the SARP tasks the Waste Isolation Pilot Plant (WIPP) Management and Operating (M&O) Contractor with assuring the packaging is used in accordance with the requirements of the C of C. Because the packaging is NRC-approved, users need to be familiar with Title 10 Code of Federal Regulations (CFR) §71.8, "Deliberate Misconduct." Any time a user suspects or has indications that the conditions of approval in the C of C were not met, the U.S. Department of Energy (DOE) Carlsbad Field Office (CBFO) shall be notified immediately. The CBFO will evaluate the issue and notify the NRC if required.In accordance with 10 CFR Part 71, "Packaging and Transportation of Radioactive Material," certificate holders, packaging users, and contractors or subcontractors who use, design, fabricate, test, maintain, or modify the packaging shall post copies of (1) 10 CFR Part 21, "Reporting of Defects and Noncompliance," regulations, (2) Section 206 of the Energy Reorganization Act of 1974, and (3) NRC Form 3, Notice to Employees. These documents must be posted in a conspicuous location where the activities subject to these regulations are conducted. This document details the instructions to be followed to operate, maintain, and test the RH-TRU 72-B packaging. This Program Guidance standardizes instructions for all users. Users shall follow these instructions or equivalent approved instructions. Following these instructions assures that operations meet the requirements of the SARP.

  15. RH Packaging Program Guidance

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2006-11-07T23:59:59.000Z

    The purpose of this program guidance document is to provide the technical requirements for use, operation, inspection, and maintenance of the RH-TRU 72-B Waste Shipping Package and directly related components. This document complies with the requirements as specified in the RH-TRU 72-B Safety Analysis Report for Packaging (SARP), and Nuclear Regulatory Commission (NRC) Certificate of Compliance (C of C) 9212. If there is a conflict between this document and the SARP and/or C of C, the C of C shall govern. The C of C states: "...each package must be prepared for shipment and operated in accordance with the procedures described in Chapter 7.0, Operating Procedures, of the application." It further states: "...each package must be tested and maintained in accordance with the procedures described in Chapter 8.0, Acceptance Tests and Maintenance Program of the Application." Chapter 9.0 of the SARP tasks the Waste Isolation Pilot Plant (WIPP) Management and Operating (M&O) Contractor with assuring the packaging is used in accordance with the requirements of the C of C. Because the packaging is NRC-approved, users need to be familiar with 10 Code of Federal Regulations (CFR) §71.8, "Deliberate Misconduct." Any time a user suspects or has indications that the conditions of approval in the C of C were not met, the U.S. Department of Energy (DOE) Carlsbad Field Office (CBFO) shall be notified immediately. CBFO will evaluate the issue and notify the NRC if required. In accordance with 10 CFR Part 71, "Packaging and Transportation of Radioactive Material," certificate holders, packaging users, and contractors or subcontractors who use, design, fabricate, test, maintain, or modify the packaging shall post copies of (1) 10 CFR Part 21, "Reporting of Defects and Noncompliance," regulations, (2) Section 206 of the Energy Reorganization Act of 1974, and (3) NRC Form 3, Notice to Employees. These documents must be posted in a conspicuous location where the activities subject to these regulations are conducted. This document details the instructions to be followed to operate, maintain, and test the RH-TRU 72-B packaging. This Program Guidance standardizes instructions for all users. Users shall follow these instructions or equivalent approved instructions. Following these instructions assures that operations meet the requirements of the SARP.

  16. RH Packaging Program Guidance

    SciTech Connect (OSTI)

    Washington TRU Solutions, LLC

    2003-08-25T23:59:59.000Z

    The purpose of this program guidance document is to provide technical requirements for use, operation, inspection, and maintenance of the RH-TRU 72-B Waste Shipping Package and directly related components. This document complies with the requirements as specified in the RH-TRU 72-B Safety Analysis Report for Packaging (SARP), and Nuclear Regulatory Commission (NRC) Certificate of Compliance (C of C) 9212. If there is a conflict between this document and the SARP and/or C of C, the SARP and/or C of C shall govern. The C of C states: ''...each package must be prepared for shipment and operated in accordance with the procedures described in Chapter 7.0, ''Operating Procedures,'' of the application.'' It further states: ''...each package must be tested and maintained in accordance with the procedures described in Chapter 8.0, ''Acceptance Tests and Maintenance Program of the Application.'' Chapter 9.0 of the SARP tasks the Waste Isolation Pilot Plant (WIPP) Management and Operating (M&O) contractor with assuring the packaging is used in accordance with the requirements of the C of C. Because the packaging is NRC approved, users need to be familiar with 10 CFR {section} 71.11, ''Deliberate Misconduct.'' Any time a user suspects or has indications that the conditions of approval in the C of C were not met, the Carlsbad Field Office (CBFO) shall be notified immediately. CBFO will evaluate the issue and notify the NRC if required. This document details the instructions to be followed to operate, maintain, and test the RH-TRU 72-B packaging. This Program Guidance standardizes instructions for all users. Users shall follow these instructions. Following these instructions assures that operations are safe and meet the requirements of the SARP. This document is available on the Internet at: ttp://www.ws/library/t2omi/t2omi.htm. Users are responsible for ensuring they are using the current revision and change notices. Sites may prepare their own document using the word-for-word steps in th is document, in sequence, including Notes and cautions. Site specific information may be included as necessary. The document, and revisions, must then be submitted to CBFO at sitedocuments@wipp.ws for approval. A copy of the approval letter from CBFO shall be available for audit purposes. Users may develop site-specific procedures addressing preoperational activities, quality assurance (QA), hoisting and rigging, and radiation health physics to be used with the instructions contained in this document. Users may recommend changes to this document by submitting their recommendations (in writing) to the WIPP M&O Contractor RH Packaging Maintenance Engineer for evaluation. If approved, the change(s) will be incorporated into this document for use by ALL users. Before first use and every 12 months after, user sites will be audited to this document to ensure compliance. They will also be audited within one year from the effective date of revisions to this document.

  17. Comment on "Catalytic Activity of the Rh Surface Oxide: CO Oxidation over Rh(111)

    E-Print Network [OSTI]

    Goodman, Wayne

    . Obviously, heating Rh in pure oxygen to T ) 230 °C and above will lead to the formation of surface Rh oxideComment on "Catalytic Activity of the Rh Surface Oxide: CO Oxidation over Rh(111) under Realistic suggest the importance of a surface oxide phase for high CO2 formation in CO-O2 reactions. However

  18. Characterization of Rh films on Ta(110)

    SciTech Connect (OSTI)

    Jiang, L.Q.; Ruckman, M.W.; Strongin, M.

    1989-01-01T23:59:59.000Z

    The surface and electronic structure of Rh films on Ta(110) up to several monolayers thick on Ta(110) are characterized by photoemission, Auger emission, low energy electron diffraction and low energy ion scattering. From the variation of the Rh Auger peak-to-peak intensity as a function of evaporation time, Rh/Ta(110) appears to grow in the Stranski-Krastanov mode at room temperature. However, the LEIS data show that the Rh adatoms begin to cluster on Ta(110) before growth of the monolayer is completed. Diffuse LEED scattering suggests that the Rh films are disordered. Photoemission shows that Rh chemisorption on Ta(110) generates two peaks located at 1.2 and 2. 5 eV binding energy during the initial phase of thin film growth (0 < {Theta} < 0.5 ML). By 0.75 ML Rh coverage, those states merge into a broad structure centered near 2 eV binding energy. Photoemission peaks typical of a Rh(111) surface are seen at higher coverages ({Theta} > 3.7 ML). Photoemission data for CO covered surfaces show that CO dissociates on the Rh/Ta(110) surface for Rh coverages less than 2.5 ML and also show that the Rh clusters develop at least one site capable of molecular CO adsorption above 0.3 ML Rh coverage. 38 refs., 5 figs.

  19. Combination moisture and hydrogen getter

    DOE Patents [OSTI]

    Not Available

    1982-04-29T23:59:59.000Z

    A combination moisture and hydrogen getter comprises (a) a moisture getter comprising a readily oxidizable metal; and (b) a hydrogen getter comprising (i) a solid acetylenic compound and (ii) a hydrogenation catalyst. A method of scavenging moisture from a closed container uses the combination moisture and hydrogen getter to irreversibly chemically reduce the moisture and chemically bind the reusltant hydrogen.

  20. Practical Considerations of Moisture in Baled Biomass Feedstocks

    SciTech Connect (OSTI)

    William A. Smith; Ian J. Bonner; Kevin L. Kenney; Lynn M. Wendt

    2013-01-01T23:59:59.000Z

    Agricultural residues make up a large portion of the immediately available biomass feedstock for renewable energy markets. Current collection and storage methods rely on existing feed and forage practices designed to preserve nutrients and properties of digestibility. Low-cost collection and storage practices that preserve carbohydrates across a range of inbound moisture contents are needed to assure the economic and technical success of the emerging biomass industry. This study examines the movement of moisture in storage and identifies patterns of migration resulting from several on-farm storage systems and their impacts on moisture measurement and dry matter recovery. Baled corn stover and energy sorghum were stored outdoors in uncovered, tarp-covered, or wrapped stacks and sampled periodically to measure moisture and dry matter losses. Interpolation between discrete sampling locations in the stack improved bulk moisture content estimates and showed clear patterns of accumulation and re-deposition. Atmospheric exposure, orientation, and contact with barriers (i.e., soil, tarp, and wrap surfaces) were found to cause the greatest amount of moisture heterogeneity within stacks. Although the bulk moisture content of many stacks remained in the range suitable for aerobic stability, regions of high moisture were sufficient to support microbial activity, thus support dry matter loss. Stack configuration, orientation, and coverage methods are discussed relative to impact on moisture management and dry matter preservation. Additionally, sample collection and data analysis are discussed relative to assessment at the biorefinery as it pertains to stability in storage, queuing, and moisture carried into processing.

  1. Atmospheric Radiation Measurement Climate Research Facility ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    improving our understanding of how clouds and atmospheric moisture interact with solar radiation and the effects of these interactions on climate. Photo courtesy Argonne National...

  2. Control of Moisture Ingress into Photovoltaic Modules

    SciTech Connect (OSTI)

    Kempe, M. D.

    2005-02-01T23:59:59.000Z

    During long-term exposure of photovoltaic modules to environmental stress, the ingress of water into the module is correlated with decreased performance. By using diffusivity measurements for water through encapsulants such as ethylene vinyl acetate (EVA), we have modeled moisture ingress using a finite-element analysis with atmospheric data from various locations such as Miami, Florida. This analysis shows that because of the high diffusivity of EVA, even an impermeable glass back-sheet alone is incapable of preventing significant moisture ingress from the edges for a 20-year lifecycle. This result has led us to investigate ways to protect modules from moisture through the use of different encapsulating chemistries and materials.

  3. Mechanism of olefin production on Pt, Rh, and Pd catalysts

    SciTech Connect (OSTI)

    Huff, M.; Schmidt, L.D. [Univ. of Minnesota, Minneapolis, MN (United States)

    1995-12-01T23:59:59.000Z

    The partial oxidation of ethylene, propylene, and butylene in an autothermal reactor at atmospheric pressure with contact times less that {approximately}10 milliseconds leads to high selectivities to mono-olefins over Pt/Al{sub 2}O{sub 3}, synthesis gas over Rh/Al{sub 2}O{sub 3}, and rapid carbon deposition and deactivation over Pd/Al{sub 2}O{sub 3} at complete oxygen conversion and high alkane conversion. In all cases, thermodynamics predicts carbon deposition. We will show how the product distributions vary with choice of catalyst and reaction conditions. We will use an elementary step model based on surface reaction rates on the various metals obtained from the surface science literature to simulate these experimental results. The dominant reaction pathways on the different metals can be explained by the relative preference for {beta} elimination reactions on Pt, nearly even split between {alpha} and {beta} elimination on Rh, and rapid {alpha} elimination on Pd.

  4. Bimetallic Ni-Rh catalysts with low amounts of Rh for the steam and autothermal reforming of n-butane for fuel-cell applications.

    SciTech Connect (OSTI)

    Ferrandon, M.; Kropf, A. J.; Krause, T.; Chemical Sciences and Engineering Division

    2010-05-15T23:59:59.000Z

    Mono-metallic nickel and rhodium catalysts and bimetallic Ni-Rh catalysts supported on La-Al{sub 2}O{sub 3}, CeZrO{sub 2} and CeMgOx were prepared and evaluated for catalyzing the steam and autothermal reforming of n-butane. The binary Ni-Rh supported on La-Al{sub 2}O{sub 3} catalysts with low weight loading of rhodium exhibited higher H{sub 2} yields than Ni or Rh alone. The Ni-Rh/CeZrO{sub 2} catalyst exhibited higher performance and no coke formation, compared to the same metals on other supports. A NiAl{sub 2}O{sub 4} spinel phase was obtained on all Ni and Ni-Rh catalysts supported on La-Al{sub 2}O{sub 3}. The presence of rhodium stabilized the spinel phase as well as NiOx species upon reforming while Ni alone was mostly reduced into metallic species. Extended X-ray absorption fine-structure analysis showed evidence of Ni-Rh alloy during preparation and even further after an accelerated aging at 900C in a H{sub 2}/H{sub 2}O atmosphere.

  5. Fiber optic moisture sensor

    DOE Patents [OSTI]

    Kirkham, R.R.

    1984-08-03T23:59:59.000Z

    A method and apparatus for sensing moisture changes by utilizing optical fiber technology. One embodiment uses a reflective target at the end of an optical fiber. The reflectance of the target varies with its moisture content and can be detected by a remote unit at the opposite end of the fiber. A second embodiment utilizes changes in light loss along the fiber length. This can be attributed to changes in reflectance of cladding material as a function of its moisture content. It can also be affected by holes or inserts interposed in the cladding material and/or fiber. Changing light levels can also be coupled from one fiber to another in an assembly of fibers as a function of varying moisture content in their overlapping lengths of cladding material.

  6. Balloon-borne sounding system (BBSS): Vaisala-processed winds, press., temp, and RH

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Coulter, Richard; Ritsche, Michael

    Balloon-borne sounding system (BBSS): Vaisala-processed winds, press., temp, and RH. The balloon-borne sounding system (SONDE) provides in situ measurements (vertical profiles) of both the thermodynamic state of the atmosphere, and the wind speed and direction.

  7. Check for chirality in {sup 102}Rh

    SciTech Connect (OSTI)

    Tonev, D.; Goutev, N.; Yavahchova, M. S.; Petkov, P.; Angelis, G. de; Bhowmik, R. K.; Singh, R. P.; Muralithar, S.; Madhavan, N.; Kumar, R.; Raju, M. Kumar; Kaur, J.; Mahanto, G.; Singh, A.; Kaur, N.; Garg, R.; Sukla, A.; Marinov, Ts. K.; Brant, S. [Bulgarian Academy of Sciences, Institute for Nuclear Research and Nuclear Energy, Sofia (Bulgaria) and INFN, Laboratori Nazionali di Legnaro, Legnaro (Italy); Inter-University Accelerator Center, New Delhi (India); Nuclear Physics Department, Andhra University, Visakhapatnam (India); Department of Physics, Punjab University, Chandigarh (India); Inter-University Accelerator Center, New Delhi (India); Department of Physics, Punjab University, Chandigarh (India); Department of Physics and Astrophysics, Delhi University, New Delhi (India); Department of Physics, Banaras Hindu University, Varanasi (India); Bulgarian Academy of Sciences, Institute for Nuclear Research and Nuclear Energy, Sofia (Bulgaria); Department of Physics, Faculty of Science, Zagreb University, Zagreb (Croatia)

    2012-10-20T23:59:59.000Z

    Excited states in {sup 102}Rh, populated by the fusion-evaporation reaction {sup 94}Zr({sup 11}B,3n){sup 102}Rh at a beam energy of 36 MeV, were studied using the INGA spectrometer at IUAC, New Delhi. The angular correlations and the electromagnetic character of some of the gamma-ray transitions observed were investigated in details. A new chiral candidate sister band was found in the level-scheme of {sup 102}Rh. Lifetimes of exited states in {sup 102}Rh were measured by means of the Doppler-shift attenuation technique. The experimental results do not support the presence of static chirality in {sup 102}Rh.

  8. Moisture Metrics Project

    SciTech Connect (OSTI)

    Schuchmann, Mark

    2011-08-31T23:59:59.000Z

    the goal of this project was to determine the optimum moisture levels for biomass processing for pellets commercially, by correlating data taken from numerous points in the process, and across several different feedstock materials produced and harvested using a variety of different management practices. This was to be done by correlating energy consumption and material through put rates with the moisture content of incoming biomass ( corn & wheat stubble, native grasses, weeds, & grass straws), and the quality of the final pellet product.This project disseminated the data through a public website, and answering questions form universities across Missouri that are engaged in biomass conversion technologies. Student interns from a local university were employed to help collect data, which enabled them to learn firsthand about biomass processing.

  9. Origin of room temperature ferromagnetic moment in Rh-rich Rh/Fe multilayer thin films

    E-Print Network [OSTI]

    Laughlin, David E.

    films of FeRh was done by electron beam melting on amorphous substrates3 but the low extent of ordering

  10. Differential atmospheric tritium sampler

    DOE Patents [OSTI]

    Griesbach, O.A.; Stencel, J.R.

    1987-10-02T23:59:59.000Z

    An atmospheric tritium sampler is provided which uses a carrier gas comprised of hydrogen gas and a diluting gas, mixed in a nonexplosive concentration. Sample air and carrier gas are drawn into and mixed in a manifold. A regulator meters the carrier gas flow to the manifold. The air sample/carrier gas mixture is pulled through a first moisture trap which adsorbs water from the air sample. The moisture then passes through a combustion chamber where hydrogen gas in the form of H/sub 2/ or HT is combusted into water. The manufactured water is transported by the air stream to a second moisture trap where it is adsorbed. The air is then discharged back into the atmosphere by means of a pump.

  11. University Policy No.: RH8100 Classification: Research

    E-Print Network [OSTI]

    Victoria, University of

    1 University Policy No.: RH8100 Classification: Research Approving Authority: Board of Governors RESEARCH POLICY Effective Date: January 2010 Supersedes: June 2002 Last Editorial Change: Mandated Review: January 2017 PURPOSE 1.00 The purpose of this policy is to set out the manner in which research

  12. Reaction-Driven Restructuring of Rh-Pd and Pt-Pd Core-Shell Nanoparticles

    SciTech Connect (OSTI)

    Tao, Feng; Grass, Michael E.; Zhang, Yawen; Butcher, Derek R.; Renzas, James R.; Liu, Zhi; Chung, Jen Y.; Mun, Bongjin S.; Salmeron, Miquel; Somorjai, Gabor A.

    2009-06-17T23:59:59.000Z

    The structure and composition of core-shell Rh{sub 0.5}Pd{sub 0.5} and Pt{sub 0.5}Pd{sub 0.5} nanoparticle catalysts were studied in situ, during oxidizing, reducing, and catalytic reactions involving NO, O{sub 2}, CO, and H{sub 2} using X-ray photoelectron spectroscopy in the Torr pressure range. The Rh{sub 0.5}Pd{sub 0.5} nanoparticles undergo dramatic and reversible changes in composition and chemical state in response to oxidizing or reducing conditions. Under oxidizing conditions the Rh atoms segregate to the shell region while in reducing atmospheres the Pd atoms diffuse to the shell region. In contrast no significant segregation of Pd or Pt atoms was found in Pt{sub 0.5}Pd{sub 0.5} nanoparticles. The distinct behavior in restructuring and chemical response of Rh{sub 0.5}Pd{sub 0.5} and Pt{sub 0.5}Pd{sub 0.5} nanoparticle catalysts under the same reaction conditions illustrates the flexibility and tunability of the structure of bimetallic nanoparticle catalysts during catalytic reactions.

  13. Differential atmospheric tritium sampler

    DOE Patents [OSTI]

    Griesbach, Otto A. (Langhorne, PA); Stencel, Joseph R. (Skillman, NJ)

    1990-01-01T23:59:59.000Z

    An atmospheric tritium sampler is provided which uses a carrier gas comprised of hydrogen gas and a diluting gas, mixed in a nonexplosive concentration. Sample air and carrier gas are drawn into and mixed in a manifold. A regulator meters the carrier gas flow to the manifold. The air sample/carrier gas mixture is pulled through a first moisture trap which adsorbs water from the air sample. The mixture then passes through a combustion chamber where hydrogen gas in the form of H.sub.2 or HT is combusted into water. The manufactured water is transported by the air stream to a second moisture trap where it is adsorbed. The air is then discharged back into the atmosphere by means of a pump.

  14. Moisture Research - Optimizing Wall Assemblies

    SciTech Connect (OSTI)

    Arena, L.; Mantha, P.

    2013-05-01T23:59:59.000Z

    The Consortium for Advanced Residential Buildings (CARB) evaluated several different configurations of wall assemblies to determine the accuracy of moisture modeling and make recommendations to ensure durable, efficient assemblies. WUFI and THERM were used to model the hygrothermal and heat transfer characteristics of these walls.

  15. Anomalous emissions of 103mRh biphoton transitions

    E-Print Network [OSTI]

    Yao Cheng; Bing Xia

    2009-08-06T23:59:59.000Z

    In this report, the anomalous emissions, centered on the one half transition energy 39.76/2 keV, are observed from the long-lived Mossbauer state of 103mRh excited by bremsstrahlung exposure. Strong coupling with identical nuclei in Rh crystals opens cascade channels for biphoton transitions.

  16. A Comparative Study between Co and Rh for Steam Reforming of...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    between Co and Rh for Steam Reforming of Ethanol. A Comparative Study between Co and Rh for Steam Reforming of Ethanol. Abstract: Rh and Co-based catalyst performance was compared...

  17. The moisture budget in relation to convection

    E-Print Network [OSTI]

    Scott, Robert Wilson

    1976-01-01T23:59:59.000Z

    Analyses of the local rate-of-change of moisture in the layer from 900-750 mb . . . . . . , . . . , . . . . . . 23 Analyses of the local rate-of-change of moisture in the layer from 750-500 mb 24 Vertical profiles of the net vertical boundary flux... of moisture related to MDR 26 10 Analyses of the net vertical boundary flux of moisture in the layer from 900-750 mb 28 Analyses of the net vertical boundary flux of moisture in the layer from 750-500 mb 29 12 Analyses of the net vertical boundary flux...

  18. Ch.7 Water and Atmospheric Moisture Learning Objective One

    E-Print Network [OSTI]

    Pan, Feifei

    's water originated from icy comets and hydrogen-oxygen-laden debris. Outgassing is a process by which formation Breaking roads Breaking pipes Damaging vehicle's engine Sinking ships #12;Iceberg King H +_ + _ Hydrogen bond Negatively charged at O side Positively charged at H side #12;Three States

  19. 2015 Pearson Education, Inc. Chapter 7 Water and Atmospheric Moisture

    E-Print Network [OSTI]

    Pan, Feifei

    Education, Inc. Where did Earth's Water Come From? · Earth's water originated from icy comets and hydrogen pipes · Damaging vehicle's engine · Sinking ships #12;© 2015 Pearson Education, Inc. Iceberg King George, Inc. Three States of Water (H2O) H O H + + Hydrogen bond Negatively charged at O side Positively

  20. atmospheric moisture content: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    option in this regards because of its renewable, abundant, environment friendly nature. Gasification systems require high temperatures and an oxygenstarved environment to convert...

  1. atmospheric moisture transports: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    option in this regards because of its renewable, abundant, environment friendly nature. Gasification systems require high temperatures and an oxygenstarved environment to convert...

  2. atmospheric moisture budget: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    option in this regards because of its renewable, abundant, environment friendly nature. Gasification systems require high temperatures and an oxygenstarved environment to convert...

  3. atmospheric moisture transport: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    option in this regards because of its renewable, abundant, environment friendly nature. Gasification systems require high temperatures and an oxygenstarved environment to convert...

  4. Three-minute oscillations above sunspot umbra observed with SDO/AIA and NoRH

    E-Print Network [OSTI]

    Reznikova, V E; Sych, R A; Nakariakov, V M

    2011-01-01T23:59:59.000Z

    Three-minute oscillations over sunspot's umbra in AR 11131 were observed simultaneously in UV/EUV emission by SDO/AIA and in radio emission by Nobeyama Radioheliograph (NoRH). We use 24-hours series of SDO and 8-hours series of NoRH observations to study spectral, spatial and temporal variations of pulsations in the f = 5 - 9 mHz range at different layers of solar atmosphere. High spatial and temporal resolution of SDO/AIA in combination with longduration observations allowed us to trace the variations of the cut-off frequency and spectrum of oscillations across the umbra. We found that higher frequency oscillations are more pronounced closer to the umbra's center, while the lower frequencies concentrate to the peripheral parts. We interpreted this discovery as a manifestation of variation of the magnetic field inclination across the umbra at the level of temperature-minimum. This interpretation has been used for diagnostics of sunspot atmosphere on this level.

  5. A Satellite Study of Tropical Moist Convection and Environmental Variability: A Moisture and Thermal Budget Analysis

    E-Print Network [OSTI]

    Masunaga, Hirohiko

    radiometer and scatterometer aboard different platforms. Satellite measurements of atmospheric parameters of moisture and dry static energy and their vertical flux at cloud base from satellite observations alone convergence for highly organized systems; 2) FT diabatic heating is largely offset on an instantaneous basis

  6. Evaluation of ERS Scatterometer soil moisture products over a half-degree region in Southwestern France

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    . Based on a high resolution soil moisture simulation (1km²) validated at the local scale, the ERS in the water and energy exchanges between the land surface and the atmosphere. Several authors have shown027231 #12;Aeronautics and Space Administration (NASA) sensors such as the AMSR-E radiometer (since 2002

  7. Fuel moisture influences on fire-altered carbon in masticated fuels: An experimental study

    E-Print Network [OSTI]

    ] Biomass burning is a significant contributor to atmospheric carbon emissions but may also provide mastication (mechanical forest thinning) and fire convert biomass to black carbon is essential moisture and its role in dictating both the quantity and quality of the carbon produced in masticated fuel

  8. Moisture Control | Department of Energy

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122Commercial602 1,39732onMake Your NextHow EMMinutes: EMMissionof EnergyMoisture

  9. Moisture levels at which rice grains will not fissure from moisture adsorption

    E-Print Network [OSTI]

    Kamau, John Mugeto

    1985-01-01T23:59:59.000Z

    MOISTURE LEVELS AT WHICH RICE GRAINS WILL NOT FISSURE FROM MOISTURE ADSORPTION A Thesis JOHN MUGETO KAMAU Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE... August 1985 Major Subject: Agricultural Engineering MOISTURE LEVELS AT WHICH RICE GRAINS WILL NQT FISSURE FROM MOISTURE ADSORPTION A Thesis JOHN MUGETO KAMAU Approved as to style and content by: Otto R. Kunze (Chairman of Committee) Calvin B...

  10. PREDICTION OF MOISTURE CONTENT AND MOISTURE GRADIENT OF AN OVERLAID PARTICLEBOARD1

    E-Print Network [OSTI]

    PREDICTION OF MOISTURE CONTENT AND MOISTURE GRADIENT OF AN OVERLAID PARTICLEBOARD1 Qinglin Wu and HPL backer. A model based on the diffusion theory was developed to predict MC and moisture distribution for a multi-ply wood composite panel. The model's prediction of the mean MC for a three-layer PB

  11. Moisture Penetration Through Optical Fiber Coatings

    E-Print Network [OSTI]

    Matthewson, M. John

    Moisture Penetration Through Optical Fiber Coatings J. L. Armstrong, M. J. Matthewson and C. R for measuring the diffusion coefficients of water vapor through optical fiber polymer coatings has been. Kurkjian #12;732 International Wire & Cable Symposium Proceedings 1998 Moisture Penetration Through Optical

  12. Catalyst and process development for hydrogen preparation from future fuel cell feedstocks. Quarterly progress report, January 1, 1980-March 31, 1980. [Pt/Rh, Pd, Pt, Rh, Ni/Rh, Rh/Re, Ni

    SciTech Connect (OSTI)

    Yarrington, R M; Feins, I R; Hwang, H S

    1980-04-01T23:59:59.000Z

    Catalysts are being screened to steam reform hydrocarbons in an autothermal reformer (STR). Twenty-one samples have been screened in a 1-in.-diam (ATR) reactor using No. 2 oil as the hydrocarbon feed. A series of platinum-rhodium catalysts were evaluated to study the effect of varying compositions. A sample containing 1.7% Pt/0.3% Rh was most active but the difference among the samples was within the range of test variability. Development of a more realistic test has been started. The effect of O/sub 2//C level on the gas composition leaving the catalytic partial oxidation section has been determined. The amount of unreacted oil increases as O/sub 2//C level decreases. The unreacted oil is more aromatic than the feedstock. The gas composition contains considerably more olefins as the O/sub 2//C level decreases. Post-run catalyst characterization indicates that the catalyst carrier does not deteriorate in the ATR test. A drastic decrease in CO chemisorption is noted on the Pt/Rh samples. This decline in CO chemisorption could either be due to metal sintering or to carbon deposition on the metal. Other analysis are required to determine which is causing the decline in CO chemisorption. Very low coke levels were found on Pt, Rh, and Pt/Rh samples. Addition of Rh to nickel reduces the coke level over that observed for nickel catalysts.

  13. Vadose Zone Soil Moisture Wicking Using Super Absorbent Polymers...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Vadose Zone Soil Moisture Wicking Using Super Absorbent Polymers. Vadose Zone Soil Moisture Wicking Using Super Absorbent Polymers. Abstract: Super-absorbent polymers (SAPs) have...

  14. UNCORRECTEDPROOF One-dimensional soil moisture prole retrieval by assimilation of

    E-Print Network [OSTI]

    Walker, Jeff

    moisture and surface temperature data into a soil moisture and heat transfer model. The direct insertion

  15. Precipitation and soil impacts on partitioning of subsurface moisture in Avena barbata: Observations from a greenhouse experiment

    SciTech Connect (OSTI)

    Salve, R.; Torn, M.S.

    2011-03-01T23:59:59.000Z

    The primary objective of this study was to assess the impact of two grassland soils and precipitation regimes on soil-moisture dynamics. We set up an experiment in a greenhouse, and monitored soil moisture dynamics in mesocosms planted with Avena barbata, an annual species found in California grasslands. By repeating the precipitation input at regular intervals, we were able to observe plant manipulation of soil moisture during well-defined periods during the growing season. We found that the amount of water partitioned to evapotranspiration, seepage, and soil storage varied among different growth stages. Further, both soil type and precipitation regimes had a significant impact on redistributing soil moisture. Whereas in the low-precipitation treatments most water was released to the atmosphere as evapotranspiration, major losses from the high-precipitation treatment occurred as gravity drainage. Observations from this study emphasize the importance of understanding intra-seasonal relationships between vegetation, soil, and water.

  16. Moisture Flux Convergence in Regional and Global Climate Models: Implications for Droughts in the Southwestern United States Under Climate Change

    SciTech Connect (OSTI)

    Gao, Yanhong; Leung, Lai-Yung R.; Salathe, E.; Dominguez, Francina; Nijssen, Bart; Lettenmaier, D. P.

    2012-05-10T23:59:59.000Z

    The water cycle of the southwestern United States (SW) is dominated by winter storms that maintain a positive annual net precipitation. Analysis of the control and future climate from four pairs of regional and global climate models (RCMs and GCMs) shows that the RCMs simulate a higher fraction of transient eddy moisture fluxes because the hydrodynamic instabilities associated with flow over complex terrain are better resolved. Under global warming, this enables the RCMs to capture the response of transient eddies to increased atmospheric stability that allows more moisture to converge on the windward side of the mountains by blocking. As a result, RCMs simulate enhanced transient eddy moisture convergence in the SW compared to GCMs, although both robustly simulate drying due to enhanced moisture divergence by the divergent mean flow in a warmer climate. This enhanced convergence leads to reduced susceptibility to hydrological change in the RCMs compared to GCMs.

  17. The Soil Moisture Active Passive (SMAP) Mission

    E-Print Network [OSTI]

    Entekhabi, Dara

    The Soil Moisture Active Passive (SMAP) mission is one of the first Earth observation satellites being developed by NASA in response to the National Research Council's Decadal Survey. SMAP will make global measurements of ...

  18. Ocean-atmosphere-land feedbacks on the western North Pacific-East Asian summer climate

    E-Print Network [OSTI]

    Chou, Chia

    . They include local processes associated with net heat flux into the atmosphere and soil moisture, ventilation, ventilation and the IRH mechanism, also induce an east-west asymmetry of the summer monsoon rain zones. In Asia, ventilation by moisture advection is particularly important and the IRH mechanism tends to favor

  19. Evidence for Methane -Complexes in Reductive Elimination Reactions from TpRh(L)(CH3)H

    E-Print Network [OSTI]

    Jones, William D.

    , the methyl deuteride complex TpRh(L)(CH3)D is observed to rearrange to TpRh(L)(CH2D)H prior to loss of CH3D

  20. Ethanol synthesis from syngas over Rh-based/SiO2 catalysts: A...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    synthesis from syngas over Rh-basedSiO2 catalysts: A combined experimental and theoretical modeling study. Ethanol synthesis from syngas over Rh-basedSiO2 catalysts: A combined...

  1. The Role of Ir in Ternary Rh-Based Catalysts for Syngas Conversion...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Role of Ir in Ternary Rh-Based Catalysts for Syngas Conversion to C2+ Oxygenates. The Role of Ir in Ternary Rh-Based Catalysts for Syngas Conversion to C2+ Oxygenates....

  2. Monitoring and controlling moisture during carpet and textile drying

    SciTech Connect (OSTI)

    Robinson, J.W.

    1995-02-01T23:59:59.000Z

    Industrial dryer/moisture control is usually performed by feedback type systems, i.e., sensors indirectly measure moisture content (MC) of the product after it leaves the dryer, or exhaust temperature from the last zone is used as an indicator of the existing MC. Such a control system is inherently weak because of the {open_quotes}after-the-fact{close_quotes} nature of the MC data. A feedback system may be improved by adding feedforward loops to handle disturbances to the system, e.g., variations in entering MC and feed rate. Such additions to the control system are expensive and require higher expertise for operating and maintaining. If the MC of the product could be measured inside the dryer, a control system could be offered that would be superior to feedback/feedforward types. This has not been possible up to this time because no MC sensor was capable of withstanding the atmosphere inside dryers. Moreover, the sample size would not have been large enough to be representative.

  3. INDICATOR: LAKE ERIE ICE COVER Winter ice cover on Lake Erie affects the amount of heat and moisture transferred

    E-Print Network [OSTI]

    102 INDICATOR: LAKE ERIE ICE COVER Background Winter ice cover on Lake Erie affects the amount of heat and moisture transferred between the lake and the atmosphere. During winter, ice and snow can decrease the amount of light available below the ice surface for photosynthesis. In the absence of an ice

  4. Investigations of Possible Low-Level Temperature and Moisture Anomalies During the AMIE Field Campaign on Manus Island

    SciTech Connect (OSTI)

    Long, CN; Holdridge, DJ

    2012-11-19T23:59:59.000Z

    This document discusses results stemming from the investigation of near-surface temperature and moisture “oddities” that were brought to light as part of the Atmospheric Radiation Measurement (ARM) Madden-Julian Oscillation (MJO) Investigation Experiment (AMIE), Dynamics of the Madden-Julian Oscillation (DYNAMO), and Cooperative Indian Ocean experiment on intraseasonal variability in the Year 2011 (CINDY2011) campaigns.

  5. Energy Balance Partitioning and Net Radiation Controls on Soil Moisture – Precipitation Feedbacks

    E-Print Network [OSTI]

    Jones, Aubrey R.; Brunsell, Nathaniel A.

    2009-01-14T23:59:59.000Z

    in determining regional weather and climate. Although this idea has been widely accepted, an under- standing of the physical processes and the scales over which these interactions occur remains somewhat limited. Improving the current understanding... of these relationships has important implications for increasing predictability of local weather and climate. According to Barros and Hwu (Barros and Hwu 2002), the basis of studies on land–atmosphere interactions is the idea that moisture and energy gradients across a...

  6. MoistureMap: A soil moisture monitoring, prediction and reporting system for sustainable land and water management

    E-Print Network [OSTI]

    Walker, Jeff

    9 MoistureMap: A soil moisture monitoring, prediction and reporting system for sustainable land soil moisture monitoring, prediction and reporting system (MoistureMap) for Australia uncertainty at 1km resolution, by assimilating (i) low-resolution passive microwave-derived surface soil

  7. How do elevated [CO2], warming, and reduced precipitation interact to affect soil moisture and LAI in an old field ecosystem?

    SciTech Connect (OSTI)

    Dermody, Orla [University of Tennessee, Knoxville (UTK); Weltzin, Jake [University of Tennessee, Knoxville (UTK); Engel, Elizabeth C. [University of Tennessee, Knoxville (UTK); Allen, Phillip [University of Tennessee, Knoxville (UTK); Norby, Richard J [ORNL

    2007-01-01T23:59:59.000Z

    Soil moisture content and leaf area index (LAI) are properties that will be particularly important in mediating whole system responses to the combined effects of elevated atmospheric [CO2], warming and altered precipitation. Warming and drying will likely reduce soil moisture, and this effect may be exacerbated when these factors are combined. However, elevated [CO2] may increase soil moisture contents and when combined with warming and drying may partially compensate for their effects. The response of LAI to elevated [CO2] and warming will be closely tied to soil moisture status and may mitigate or exacerbate the effects of global change on soil moisture. Using open-top chambers (4-m diameter), the interactive effects of elevated [CO2], warming, and differential irrigation on soil moisture availability were examined in the OCCAM (Old-Field Community Climate and Atmospheric Manipulation) experiment at Oak Ridge National Laboratory in eastern Tennessee. Warming consistently reduced soil moisture contents and this effect was exacerbated by reduced irrigation. However, elevated [CO2] partially compensated for the effects of warming and drying on soil moisture. Changes in LAI were closely linked to soil moisture status. LAI was determined using an AccuPAR ceptometer and both the leaf area duration (LAD) and canopy size were increased by irrigation and elevated [CO2]. The climate of the southeastern United States is predicted to be warmer and drier in the future. This research suggests that although elevated [CO2] will partially ameliorate the effects of warming and drying, losses of soil moisture will increase from old field ecosystems in the future.

  8. Measuring soil moisture with imaging radars

    SciTech Connect (OSTI)

    Dubois, P.C.; Zyl, J. van [California Inst. of Tech., Pasadena, CA (United States). Jet Propulsion Lab.] [California Inst. of Tech., Pasadena, CA (United States). Jet Propulsion Lab.; Engman, T. [NASA Goddard Space Flight Center, Greenbelt, MD (United States)] [NASA Goddard Space Flight Center, Greenbelt, MD (United States)

    1995-07-01T23:59:59.000Z

    An empirical algorithm for the retrieval of soil moisture content and surface Root Mean Square (RMS) height from remotely sensed radar data was developed using scatterometer data. The algorithm is optimized for bare surfaces and requires two copolarized channels at a frequency between 1.5 and 11 GHz. It gives best results for kh {le} 2.5, {mu}{sub {upsilon}}{le}35%, and {theta}{ge}30{degree}. Omitting the usually weaker hv-polarized returns makes the algorithm less sensitive to system cross-talk and system noise, simplify the calibration process and adds robustness to the algorithm in the presence of vegetation. However, inversion results indicate that significant amounts of vegetation (NDVI>0.4) cause the algorithm to underestimate soil moisture and overestimate RMS height. A simple criteria based on the {sigma}{sub hv}{sup 0}/{sigma}{sub vv}{sup 0} ratio is developed to select the areas where the inversion is not impaired by the vegetation. The inversion accuracy is assessed on the original scatterometer data sets but also on several SAR data sets by comparing the derived soil moisture values with in-situ measurements collected over a variety of scenes between 1991 and 1994. Both spaceborne (SIR-C) and airborne (AIRSAR) data are used in the test. Over this large sample of conditions, the RMS error in the soil moisture estimate is found to be less than 4.2% soil moisture.

  9. Distributed fiber optic moisture intrusion sensing system

    DOE Patents [OSTI]

    Weiss, Jonathan D. (Albuquerque, NM)

    2003-06-24T23:59:59.000Z

    Method and system for monitoring and identifying moisture intrusion in soil such as is contained in landfills housing radioactive and/or hazardous waste. The invention utilizes the principle that moist or wet soil has a higher thermal conductance than dry soil. The invention employs optical time delay reflectometry in connection with a distributed temperature sensing system together with heating means in order to identify discrete areas within a volume of soil wherein temperature is lower. According to the invention an optical element and, optionally, a heating element may be included in a cable or other similar structure and arranged in a serpentine fashion within a volume of soil to achieve efficient temperature detection across a large area or three dimensional volume of soil. Remediation, moisture countermeasures, or other responsive action may then be coordinated based on the assumption that cooler regions within a soil volume may signal moisture intrusion where those regions are located.

  10. Influence of Moisture on Heating in Feeds.

    E-Print Network [OSTI]

    Richardson, L. R.; Halick, J. V.

    1953-01-01T23:59:59.000Z

    investigation was supported in part by a grant-in-aid from ~uthwestern Sugar and Molasses Company, New York, through urtesy of A. I. Kaplan, president. ?e are indebted to E. I. du Pont de Nemours and Company, ngton, Del. through the courtesy of F. M. Jornlin..., standards for the moisture content of all in- gredients used in feeds should be reevaluated. The absence of heating in molasses feeds will not be insured by establishing a standard for the moisture content of molasses alone. Standardr for molasses...

  11. Atmospheric Neutrinos

    E-Print Network [OSTI]

    Thomas K. Gaisser

    2006-12-11T23:59:59.000Z

    This paper is a brief overview of the theory and experimental data of atmospheric neutrino production at the fiftieth anniversary of the experimental discovery of neutrinos.

  12. Modeling studies of gas movement and moisture migration at Yucca Mountain, Nevada

    SciTech Connect (OSTI)

    Tsang, Y.W.; Pruess, K. [Lawrence Berkeley Lab., CA (United States)

    1991-06-01T23:59:59.000Z

    Modeling studies on moisture redistribution processes that are mediated by gas phase flow and diffusion have been carried out. The problem addressed is the effect of a lowered humidity of the soil gas at the land surface on moisture removal from Yucca Mountain, the potential site for a high-level nuclear waste repository. At the land surface, humid formation gas contacts much drier atmospheric air. Near this contact, the humidity of the soil gas may be considerably lower than at greater depth, where the authors expect equilibrium with the liquid phase and close to 100% humidity. The lower relative humidity of the soil gas may be modeled by imposing, at the land surface, an additional negative capillary suction corresponding to vapor pressure lowering according to Kelvin`s Equation, thus providing a driving force for the upward movement of moisture in both the vapor and liquid phases. Sensitivity studies show that moisture removal from Yucca Mountain arising from the lowered-relative-humidity boundary condition is controlled by vapor diffusion. There is much experimental evidence in the soil literature that diffusion of vapor is enhanced due to pore-level phase change effects by a few orders of magnitude. Modeling results presented here will account for this enhancement in vapor diffusion.

  13. The effects of post-condensation exchange on the isotopic composition of water in1 the atmosphere2

    E-Print Network [OSTI]

    Field, Robert

    of the water vapor and the amount of previous2 rainfall from the air mass as the dominant controls on the isotopic composition of3 atmospheric moisture. These formed the basis of the Rayleigh distillation model4 16 O, causing the progressive8 isotopic depletion of the air mass at it loses moisture. In its most

  14. Assessment of NGNP Moisture Ingress Events

    SciTech Connect (OSTI)

    Bill Landman

    2011-04-01T23:59:59.000Z

    An assessment of modular HTGR moisture ingress events, making use of a phenomena identification and ranking process, was conducted by a panel of experts in the related areas for the U.S. next generation nuclear plant (NGNP) design. Consideration was given mainly to the prismatic core gas-cooled reactor configurations incorporating a steam generator within the primary circuit.

  15. 1. Control moisture. 2. Clean regularly.

    E-Print Network [OSTI]

    , water heaters, and fireplaces that burn fuel must vent to the outside. Stoves, ovens, and cook on the things we do to affect how healthy our home is. Step 1. Control Moisture Water and excessive humidity of pesticides. Food and water attract pests. Controlling food and water helps to minimize pests. Sealing

  16. Measurements of moisture suction in hot mix asphalt mixes 

    E-Print Network [OSTI]

    Kassem, Emad Abdel-Rahman

    2006-10-30T23:59:59.000Z

    with different bond energies and exhibited different field performance in terms of resistance to moisture damage. The suction measurements in sand asphalt specimens were used to calculate the moisture diffusion coefficient. The results revealed that water...

  17. Evaluation of moisture damage within asphalt concrete mixes 

    E-Print Network [OSTI]

    Shah, Brij D.

    2004-09-30T23:59:59.000Z

    as bond energy in order to predict moisture damage. Mixtures with the two types of bitumen and each aggregate with and without hydrated lime were evaluated. The hydrated lime substantially improved the resistance of the mixture to moisture damage....

  18. Towards tailoring the magnetocaloric response in FeRh-based ternary compounds

    SciTech Connect (OSTI)

    Barua, Radhika, E-mail: barua.r@husky.neu.edu; Jiménez-Villacorta, Félix; Lewis, L. H. [Department of Chemical Engineering, Northeastern University, Boston, Massachusetts 02115 (United States)

    2014-05-07T23:59:59.000Z

    In this work, we demonstrate that the magnetocaloric response of FeRh-based compounds may be tailored for potential magnetic refrigeration applications by chemical modification of the FeRh lattice. Alloys of composition Fe(Rh{sub 1?x}A{sub x}) or (Fe{sub 1?x}B{sub x})Rh (A?=?Cu, Pd; B?=?Ni; 0?Rh-based systems were determined using isothermal M(H) curves measured in the vicinity of the magnetostructural temperature (T{sub t}). It is found that the FeRh working temperature range (?T{sub FWHM}) may be chemically tuned over a wide temperature range, 100?K???T???400?K. While elemental substitution consistently decreases the magnetic entropy change (?S{sub mag}) of the FeRh-based ternary alloys from that of the parent FeRh compound (?S{sub mag},{sub FeRh}???17?J/kg?K; ?S{sub mag,FeRh-ternary?=}?7–14?J/kg?K at H{sub app}?=?2?T), the net refrigeration capacity (RC), defined as the amount of heat that can be transferred during one magnetic refrigeration cycle, of the modified systems is significantly higher (RC{sub FeRh}???150?J/kg; RC{sub FeRh-ternary?=}?170–210?J/kg at H{sub app}?=?2?T). These results are attributed to stoichiometry-induced changes in the FeRh electronic band structure and beneficial broadening of the magnetostructural transition due to local chemical disorder.

  19. Effect of varying moisture levels on sorghum stand establishment

    E-Print Network [OSTI]

    Kanyenji, Ben Machaki

    1991-01-01T23:59:59.000Z

    to germinate, emerge, and survive under low moisture situations. At the lowest moisture level (20% water holding capacity of the potted soil/media; 264 water on dry weight basis), germination was reduced by 50 percent. Hegari and CSM388 had the highest... germination performance at this moisture level. Seedling emergence was decreased by 60 percent from performance under optimum moisture (454 water holding capacity potted soil/media) and cultivers such as Segaolane and CSM388 had the highest emergence...

  20. Mn Monolayer Modified Rh for Syngas-to-Ethanol Conversion: A First-Principles Study

    SciTech Connect (OSTI)

    Li, Fengyu [University of Puerto Rico; Jiang, Deen [ORNL; Zeng, X.C. [University of Nebraska, Lincoln; Chen, Zhongfang [University of Puerto Rico

    2012-01-01T23:59:59.000Z

    Rh is unique in its ability to convert syngas to ethanol with the help of promoters. We performed systematic first-principles computations to examine the catalytic performance of pure and Mn modified Rh(100) surfaces for ethanol formation from syngas. CO dissociation on the surface as well as CO insertion between the chemisorbed CH{sub 3} and the surface are the two key steps. The CO dissociation barrier on the Mn monolayer modified Rh(100) surface is remarkably lowered by {approx}1.5 eV compared to that on Rh(100). Moreover, the reaction barrier of CO insertion into the chemisorbed CH{sub 3} group on the Mn monolayer modified Rh(100) surface is 0.34 eV lower than that of methane formation. Thus the present work provides new mechanistic insight into the role of Mn promoters in improving Rh's selectivity to convert syngas to ethanol.

  1. Greening the terrestrial biosphere: simulated feedbacks on atmospheric heat and energy circulation

    E-Print Network [OSTI]

    Cowling, Sharon A.

    Greening the terrestrial biosphere: simulated feedbacks on atmospheric heat and energy circulation on atmospheric exchange of heat and moisture. Our CONTROL simulation had a mean global net primary production (NPP) of 56.3 GtCyr-1 which is half that of our scenario value of 115.1 GtCyr-1 . LAI and latent energy

  2. Process for treating moisture laden coal fines

    DOE Patents [OSTI]

    Davis, Burl E. (New Kensington, PA); Henry, Raymond M. (Gibsonia, PA); Trivett, Gordon S. (South Surrey, CA); Albaugh, Edgar W. (Birmingham, AL)

    1993-01-01T23:59:59.000Z

    A process is provided for making a free flowing granular product from moisture laden caked coal fines, such as wet cake, by mixing a water immiscible substance, such as oil, with the caked coal, preferably under low shear forces for a period of time sufficient to produce a plurality of free flowing granules. Each granule is preferably comprised of a dry appearing admixture of one or more coal particle, 2-50% by weight water and the water immiscible substance.

  3. The effect of soil moisture levels on evapotranspiration from cotton and grain sorghum

    E-Print Network [OSTI]

    Schneider, Arland David

    1964-01-01T23:59:59.000Z

    measured value of soil t moisture. Substituting these values into Equations (I), (2) and (3) gave the following three equations: SM =be ct t SM =bK t t SM = d ? b log (t+c ) t (5) (6) The next logical step would have been to evaluate... as several atmospheres pressure which is sufficient tc move water to the leaves of even the tallest trees. The flew cf water can be governed by either the rate at which it is extracted from the soil or the rate at which it moves through the plants...

  4. Note: Large area deposition of Rh single and Rh/W/Cu multilayer thin films on stainless steel substrate by pulsed laser deposition technique

    SciTech Connect (OSTI)

    Mostako, A. T. T.; Khare, Alika, E-mail: alika@iitg.ernet.in [Department of Physics, Indian Institute of Technology Guwahati, Guwahati 781039 (India)] [Department of Physics, Indian Institute of Technology Guwahati, Guwahati 781039 (India)

    2014-04-15T23:59:59.000Z

    Mirror like thin films of single layer Rh and multilayer Rh/W/Cu are deposited on highly polished 50 mm diameter stainless steel substrate by Pulsed Laser Deposition (PLD) technique for first mirror application in fusion reactors. For this, the conventional PLD technique has been modified by incorporating substrate rastering stage for large area deposition via PLD. Process optimization to achieve uniformity of deposition as estimated from fringe visibility and thickness is also discussed.

  5. Resource Assessment Edited by J.R. Hatch and R.H. Affolter

    E-Print Network [OSTI]

    Chapter D Resource Assessment Edited by J.R. Hatch and R.H. Affolter Chapter D of Resource.S. Geological Survey National Coal Resource Assessment Click here to return to Disc 1 Volume Table of Contents........................................................................................ 3 Previous Resource Assessments of Illinois Basin Coals, by J.R. Hatch and R.H. Affolter

  6. Carbon supported PtRh catalysts for ethanol oxidation in alkaline direct ethanol fuel cell

    E-Print Network [OSTI]

    Zhao, Tianshou

    Carbon supported PtRh catalysts for ethanol oxidation in alkaline direct ethanol fuel cell S and Technology, Clear Water Bay, Kowloon, Hong Kong SAR, China a r t i c l e i n f o Article history: Received 26 carbon supported PtRh catalysts and compare their catalytic activities with that of Pt/C in alkaline

  7. Surface Science Letters P) reactions with small alkenes adsorbed on Rh, Au, and ice

    E-Print Network [OSTI]

    Sibener, Steven

    Surface Science Letters O(3 P) reactions with small alkenes adsorbed on Rh, Au, and ice K.D. Gibson the reaction of O(3 P) with 1- and 2-butene on the surface of Rh(111) and ice, and propene on the surface of Au(111) and amorphous ice and propene adsorbed on Au(111). These experiments were done at cryogenic

  8. Dissociation of water on oxygen-covered Rh^111 A. Shavorskiy,1

    E-Print Network [OSTI]

    Schnadt, Joachim

    to the somewhat unusual situation that these water layers are actually hydrophobic due to the lack of hydrogenDissociation of water on oxygen-covered Rh^111 A. Shavorskiy,1 T. Eralp,1 E. Ataman,2 C. Isvoranu,2 November 2009; published online 4 December 2009 The adsorption of water and coadsorption with oxygen on Rh

  9. High density adsorbed oxygen on Rh,,111... and enhanced routes to metallic oxidation using atomic oxygen

    E-Print Network [OSTI]

    Sibener, Steven

    High density adsorbed oxygen on Rh,,111... and enhanced routes to metallic oxidation using atomic oxygen K. D. Gibson, Mark Viste, Errol C. Sanchez, and S. J. Sibener The James Franck Institute; accepted 30 November 1998 Exposure of Rh 111 to atomic oxygen leads to the facile formation of a full

  10. Moisture and temperature effects in composite materials 

    E-Print Network [OSTI]

    Fang, Gwo-Ping

    1987-01-01T23:59:59.000Z

    ) Chairman of Advisory Committee: Dr. Y. Weitsman Th1s thesis concerns env1ronmental effects in graphite/epoxy composites, with emphas1s on environmentally induced damage. The thesis consists of two major parts. The first part presents an experimental 1... weight gain (in %) of a 12-ply unidirectional AS4/3502 graphite/epoxy laminate during exposure to 346'K, 95% R. H. environment. Data (i) and predictions of Flck's law (solid line) Moisture content (ln %) of a 12-ply unidirectional AS4/3502 graphite...

  11. Atmospheric Aerosols Workshop | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Atmospheric Aerosols Workshop Atmospheric Aerosols Workshop EMSL Science Theme Advisory Panel Workshop - Atmospheric Aerosol Chemistry, Climate Change, and Air Quality. Baer DR, BJ...

  12. Synthesis, characterization, and catalytic activity of Rh-based lanthanum zirconate pyrochlores for higher alcohol synthesis

    SciTech Connect (OSTI)

    Abdelsayed, Victor; Shekhawat, Dushyant; Poston, James A., Jr.; Spivey, James J.

    2013-05-01T23:59:59.000Z

    Two lanthanum zirconate pyrochlores (La{sub 2}Zr{sub 2}O{sub 7}; LZ) were prepared by Pechini method and tested for higher alcohols selectivity. In one, Rh was substituted into the pyrochlore lattice (LRZ, 1.7 wt%) while for the second, Rh was supported on an unsubstituted La{sub 2}Zr{sub 2}O{sub 7} (R/LZ, 1.8 wt%). X-ray photoelectron spectroscopy (XPS) and temperature programmed reduction (TPR) results show that the surface reducibility depends on whether the Rh is in (or supported on) the LZ pyrochlore. Rhodium in the LRZ is more reducible than rhodium supported on the R/LZ pyrochlore, likely due to the presence of a perovskite phase (LaRhO{sub 3}; identified by XRD), in which rhodium is more reducible. The formation of the perovskite accompanies that of the pyrochlore. CO hydrogenation results show higher ethanol selectivity for R/LZ than LRZ, possibly due to the strong interaction between Rh and LZ on the R/LZ, forming atomically close Rh{sup +}/Rh{sup 0} sites, which have been suggested to favor ethanol production.

  13. Additivity of detector responses of a portable direct-reading 10. 2 eV photoionization detector and a flame ionization gas chromatograph for atmospheres of multicomponent organics: use of PID/FID ratios

    SciTech Connect (OSTI)

    Lee, I.N.; Hee, S.S.Q.; Clark, C.S.

    1987-05-01T23:59:59.000Z

    The H-Nu PI-101 with a photoionization detector (PID) of 10.2 eV and Century OVA-128 equipped with a flame ionization detector (FID) were evaluated for the additivity of their responses to a defined mixtures of dissimilar organic vapors at a 0 and 90% relative humidity (RH). The responses of both instruments were additive as long as the effect of RH was accounted for the PID. The PI-101 was not as precise as the Century OVA-128 for 90% RH atmospheres. PID/FID ratios did not change in the presence of 90% RH as long as the effect of RH also was accounted for in the PID reading. The compounds investigated included: toluene, benzaldehyde; 1,2,4-trichlorobenzene, methyl chloroform, methylene dichloride, methyl ethyl ketone, ethanol and acetonitrile.

  14. Soil Moisture and the Drought in Texas Todd Caldwell

    E-Print Network [OSTI]

    Yang, Zong-Liang

    Neutron scatter 50 2 2010 AmeriFlux Dielectric 215 1 2005 NEON ?? 20 1 ~2011 West Texas Mesonet: 79 sitesSoil Moisture and the Drought in Texas Todd Caldwell Bridget Scanlon Michael Young Di Long Water;Soil Moisture and the Drought in Texas I. How is drought linked to water resources? II. Where does soil

  15. High-R Walls for Remodeling: Wall Cavity Moisture Monitoring

    SciTech Connect (OSTI)

    Wiehagen, J.; Kochkin, V.

    2012-12-01T23:59:59.000Z

    The focus of the study is on the performance of wall systems, and in particular, the moisture characteristics inside the wall cavity and in the wood sheathing. Furthermore, while this research will initially address new home construction, the goal is to address potential moisture issues in wall cavities of existing homes when insulation and air sealing improvements are made.

  16. Soil Moisture Measurement in Heterogeneous Terrain Merlin, O.1

    E-Print Network [OSTI]

    Walker, Jeff

    , uncertainty assessment, soil moisture patterns. EXTENDED ABSTRACT Reliable soil moisture measurement over such data, portable electronic sensors offer a practical alternative to gravimetric measurements % v/v in clay. On the other hand, the real component of the measured relative DC is found to be more

  17. Moisture Management for High R-Value Walls

    SciTech Connect (OSTI)

    Lepage, R.; Schumacher, C.; Lukachko, A.

    2013-11-01T23:59:59.000Z

    The following report explains the moisture-related concerns for High R-value wall assemblies and discusses past Building America research work that informs this study. Hygrothermal simulations were prepared for several common approaches to High R-value wall construction in six cities (Houston, Atlanta, Seattle, St. Louis, Chicago, and International Falls) representing a range of climate zones (2, 3, 4C, 4, 5A, and 7, respectively). The simulations are informed by experience gained from past research in this area and validated by field measurement and forensic experience. The modeling program was developed to assess the moisture durability of the wall assemblies based on three primary sources of moisture: construction moisture, air leakage condensation, and bulk water leakage. The peak annual moisture content of the wood based exterior sheathing was used to comparatively analyze the response to the moisture loads for each of the walls in each given city. Walls which experienced sheathing moisture contents between 20% and 28% were identified as risky, whereas those exceeding 28% were identified as very high risk. All of the wall assemblies perform well under idealized conditions. However, only the walls with exterior insulation, or cavity insulation which provides a hygrothermal function similar to exterior insulation, perform adequately when exposed to moisture loads. Walls with only cavity insulation are particularly susceptible to air leakage condensation. None of the walls performed well when a precipitation based bulk water leak was introduced to the backside of the sheathing, emphasizing the importance of proper flashing details.

  18. Measurements of moisture suction in hot mix asphalt mixes

    E-Print Network [OSTI]

    Kassem, Emad Abdel-Rahman

    2006-10-30T23:59:59.000Z

    The presence of moisture in hot mix asphalt (HMA) causes loss of strength and durability of the mix, which is referred to as moisture damage. This study deals with the development of experimental methods for measuring total suction in HMA, which can...

  19. Moisture Management of High-R Walls (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2013-12-01T23:59:59.000Z

    The following report explains the moisture-related concerns for High R-value wall assemblies and discusses past Building America research work that informs this study. Hygrothermal simulations were prepared for several common approaches to High R-value wall construction in six cities (Houston, Atlanta, Seattle, St. Louis, Chicago, and International Falls) representing a range of climate zones (2, 3, 4C, 4, 5A, and 7, respectively). The simulations are informed by experience gained from past research in this area and validated by field measurement and forensic experience. The modeling program was developed to assess the moisture durability of the wall assemblies based on three primary sources of moisture: construction moisture, air leakage condensation, and bulk water leakage. The peak annual moisture content of the wood based exterior sheathing was used to comparatively analyze the response to the moisture loads for each of the walls in each given city. Walls which experienced sheathing moisture contents between 20% and 28% were identified as risky, whereas those exceeding 28% were identified as very high risk. All of the wall assemblies perform well under idealized conditions. However, only the walls with exterior insulation, or cavity insulation which provides a hygrothermal function similar to exterior insulation, perform adequately when exposed to moisture loads. Walls with only cavity insulation are particularly susceptible to air leakage condensation. None of the walls performed well when a precipitation based bulk water leak was introduced to the backside of the sheathing, emphasizing the importance of proper flashing details.

  20. The moisture budget in relation to convection 

    E-Print Network [OSTI]

    Scott, Robert Wilson

    1976-01-01T23:59:59.000Z

    : x10-6g cm-2s-1) 30 (, 'j I" '~, ". :, ', :, ':: P, ' r 0 (a) 0600 GMT, 24 April 1975 . . . ~t' . '. a--'-, . ' ' P) D (b) 0600 GiXT, 25 April 1975 Analyses of the net vertacal boundary flux of moisture in the layer from 500-350 mb... 120 4 060 , J 16O I 2 1" , 090 ~ J 120 32+ r I 24~ 190 12 10 (b) 700 mb Fig. 3. Synoptic charts for 0600 GMT on 24 April 1975. 16 86. 16 04 08 I 12 I I f 08 I 08 I L 08 12 16 (a) Surface 20 - 8 A 4X 4 0 ) O2O ~~(~ -2 J--4...

  1. Atmospheric Aerosol Systems | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Science Themes Atmospheric Aerosol Systems Overview Atmospheric Aerosol Systems Biosystem Dynamics & Design Energy Materials & Processes Terrestrial & Subsurface Ecosystems...

  2. Executive Summary By J.R. Hatch and R.H. Affolter

    E-Print Network [OSTI]

    Chapter A Executive Summary By J.R. Hatch and R.H. Affolter Chapter A of Resource Assessment Coal Resource Assessment Click here to return to Disc 1 Volume Table of Contents #12;AII Contents) ............................... 5 Coal Resource Assessment

  3. Policy and practice concerning women with an RhD negative blood type : a midwifery perspective 

    E-Print Network [OSTI]

    Harkness, Mairi

    2014-07-05T23:59:59.000Z

    In May 2002 the National Institute for Clinical Excellence (NICE) made the recommendation that all pregnant women with an RhD negative blood type should be offered routine antenatal anti-D immunoglobulin (Ig) prophylaxis ...

  4. Highly Active and Stable MgAl2O4 Supported Rh and Ir Catalysts...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and stability for methane steam reforming in the presence of simulated biomass-derived syngas. It was found that highly dispersed 2 nm Rh and 1 nm Ir clusters were formed on the...

  5. Moisture burst structure in satellite water vapor imagery

    E-Print Network [OSTI]

    Ulsh, David Joel

    1988-01-01T23:59:59.000Z

    The moisture burst is a tropical synoptic-scale weather event that typically originates along the ITCZ and has been defined previously in window-channel infrared imagery. This research uses 6. 7-micrometer water vapor absorption band imagery to composite 35... moisture burst events during the North Pacific cool season of 1983-1984. Composite maps are constructed at four times, each 24 h apart, during the life cycle of the moisture burst. A comparative baseline is provided by an additional composite of 35 dates...

  6. Evaluation of the Effective Moisture Penetration Depth Model for Estimating Moisture Buffering in Buildings

    SciTech Connect (OSTI)

    Woods, J.; Winkler, J.; Christensen, D.

    2013-01-01T23:59:59.000Z

    This study examines the effective moisture penetration depth (EMPD) model, and its suitability for building simulations. The EMPD model is a compromise between the simple, inaccurate effective capacitance approach and the complex, yet accurate, finite-difference approach. Two formulations of the EMPD model were examined, including the model used in the EnergyPlus building simulation software. An error in the EMPD model we uncovered was fixed with the release of EnergyPlus version 7.2, and the EMPD model in earlier versions of EnergyPlus should not be used.

  7. INTRODUCTIONTOTHE SOLAR ATMOSPHERE

    E-Print Network [OSTI]

    ? #12;WHAT ISTHE SOLAR ATMOSPHERE? #12;#12;1-D MODEL ATMOSPHERE · Averaged over space and time · GoodINTRODUCTIONTOTHE SOLAR ATMOSPHERE D. Shaun Bloomfield Trinity College Dublin #12;OUTLINE · What is the solar atmosphere? · How is the solar atmosphere observed? · What structures exist and how do they evolve

  8. Thermal Effects of Moisture in Rigid Insulation Board

    E-Print Network [OSTI]

    Crow, G. W.

    The impact of moisture in rigid roof insulation upon energy consumption is often assumed to be a simple function of the conductance. This paper will show that there are complex interactions between conductance, thermal mass, and climate. The energy...

  9. Measurement of Moisture Content in Sand, Slag, and Crucible Materials

    SciTech Connect (OSTI)

    Gray, J.H.

    1999-09-20T23:59:59.000Z

    The deinventory process at Rocky Flats (RFETS) has included moisture content measurements of sand, slag, and crucible (SSC) materials by performing weight loss measurements at 210 degrees - 220 degrees Celsius on representative samples prior to packaging for shipment. Shipping requirements include knowledge of the moisture content. Work at the Savannah River Technology Center (SRTC) showed that the measurement at 210 degrees - 220 degrees Celsius did not account for all of the moisture. The objective of the work in this report was to determine if the measurement at 210 degrees - 220 degrees Celsius at RFETS could be used to set upper bounds on moisture content and therefore, eliminate the need for RFETS to unpack, reanalyze and repack the material.

  10. Building America Top Innovations Hall of Fame Profile ? Moisture...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2. House-as-a-System Solutions 2.1 New Homes with Whole-House Packages Moisture and Ventilation Solutions in Hot, Humid Climates: Florida Manufactured Housing Research by Building...

  11. Moisture Risk in Unvented Attics Due to Air Leakage Paths

    SciTech Connect (OSTI)

    Prahl, D.; Shaffer, M.

    2014-11-01T23:59:59.000Z

    IBACOS completed an initial analysis of moisture damage potential in an unvented attic insulated with closed-cell spray polyurethane foam. To complete this analysis, the research team collected field data, used computational fluid dynamics to quantify the airflow rates through individual airflow (crack) paths, simulated hourly flow rates through the leakage paths with CONTAM software, correlated the CONTAM flow rates with indoor humidity ratios from Building Energy Optimization software, and used Warme und Feuchte instationar Pro two-dimensional modeling to determine the moisture content of the building materials surrounding the cracks. Given the number of simplifying assumptions and numerical models associated with this analysis, the results indicate that localized damage due to high moisture content of the roof sheathing is possible under very low airflow rates. Reducing the number of assumptions and approximations through field studies and laboratory experiments would be valuable to understand the real-world moisture damage potential in unvented attics.

  12. Thermal Effects of Moisture in Rigid Insulation Board 

    E-Print Network [OSTI]

    Crow, G. W.

    1992-01-01T23:59:59.000Z

    The impact of moisture in rigid roof insulation upon energy consumption is often assumed to be a simple function of the conductance. This paper will show that there are complex interactions between conductance, thermal mass, and climate. The energy...

  13. Moisture Diffusion in Asphalt Binders and Fine Aggregate Mixtures

    E-Print Network [OSTI]

    Vasconcelos, Kamilla L.

    2011-08-08T23:59:59.000Z

    cost in highway maintenance and vehicle operations. One key mechanism of how moisture reaches the asphalt-aggregate interface is by its permeation or diffusion through the asphalt binder or mastic. Different techniques are available for diffusion...

  14. Evaluation of Moisture Susceptibility of Warm Mix Asphalt

    E-Print Network [OSTI]

    Garcia Cucalon, Maria Lorena

    2013-05-03T23:59:59.000Z

    . To evaluate WMA moisture susceptibility during this critical period, standard laboratory tests were used for three field projects each with an HMA control mixtures and multiple WMA mixtures. Different specimen types were also evaluated to capture differences...

  15. The spatial and temporal organization of soil moisture 

    E-Print Network [OSTI]

    Vogel, Gregor Klaus

    1995-01-01T23:59:59.000Z

    THE SPATIAL AND TEMPORAL ORGANIZATION OF SOIL MOISTURE A Thesis by GREGOR KLAUS VOGEL Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE December... 1995 Major Subject: Water Resources Engineering THE SPATIAL AND TEMPORAL ORGANIZATION OF SOIL MOISTURE A Thesis by GREGOR KLAUS VOGEL Submitted to Texas ARM University in partial fulfillment of the requirements for the degree of MASTER...

  16. Evaluation of moisture damage within asphalt concrete mixes

    E-Print Network [OSTI]

    Shah, Brij D.

    2004-09-30T23:59:59.000Z

    with load cycles. The analysis demonstrates the need to consider mixture compliance as well as bond energy in order to predict moisture damage. Mixtures with the two types of bitumen and each aggregate with and without hydrated lime were... evaluated. The hydrated lime substantially improved the resistance of the mixture to moisture damage. iv To my parents. v ACKNOWLEDGMENTS I would like to extend my sincere thanks to everyone who helped...

  17. Comparative Investigation of Benzene Steam Reforming over Spinel Supported Rh and Ir Catalysts

    SciTech Connect (OSTI)

    Mei, Donghai; Lebarbier, Vanessa MC; Rousseau, Roger J.; Glezakou, Vassiliki Alexandra; Albrecht, Karl O.; Kovarik, Libor; Flake, Matthew D.; Dagle, Robert A.

    2013-06-01T23:59:59.000Z

    In a combined experimental and first-principles density functional theory (DFT) study, benzene steam reforming (BSR) over MgAl2O4 supported Rh and Ir catalysts was investigated. Experimentally, it has been found that both highly dispersed Rh and Ir clusters (1-2 nm) on the MgAl2O4 spinel support are stable during the BSR in the temperature range of 700-850?C. Compared to the Ir/MgAl2O4 catalyst, the Rh/MgAl2O4 catalyst is more active with higher benzene turnover frequency and conversion. At typical steam conditions with the steam-to-carbon ratio > 12, the benzene conversion is only a weak function of the H2O concentration in the feed. This suggests that the initial benzene decomposition step rather than the benzene adsorption is most likely the rate-determined step in BSR over supported Rh and Ir catalysts. In order to understand the differences between the two catalysts, we followed with a comparative DFT study of initial benzene decomposition pathways over two representative model systems for each supported metal (Rh and Ir) catalysts. A periodic terrace (111) surface and an amorphous 50-atom metal cluster with a diameter of 1.0 nm were used to represent the two supported model catalysts under low and high dispersion conditions. Our DFT results show that the decreasing catalyst particle size enhances the benzene decomposition on supported Rh catalysts by lowering both C-C and C-H bond scission. The activation barriers of the C-C and the C-H bond scission decrease from 1.60 and 1.61 eV on the Rh(111) surface to 1.34 and 1.26 eV on the Rh50 cluster. For supported Ir catalysts, the decreasing particle size only affects the C-C scission. The activation barrier of the C-C scission of benzene decreases from 1.60 eV on the Ir(111) surface to 1.35 eV on the Ir50 cluster while the barriers of the C-H scission are practically the same. The experimentally measured higher BSR activity on the supported highly dispersed Rh catalyst can be rationalized by the thermodynamic limitation for the very first C-C bond scission of benzene on the small Ir50 catalyst. The C-C bond scission of benzene on the small Ir50 catalyst is highly endothermic although the barrier is competitive with the barriers of both the C-C and the C-H bond-breakings on the small Rh50 catalyst. The calculations also imply that, for the supported Rh catalysts the C-C and C-H bond scissions are competitive, independently of the Rh cluster sizes. After the initial dissociation step via either the C-C or the C-H bond scission, the C-H bond breaking seems to be more favorable rather than the C-C bond breaking on the larger Rh terrace surface. This work was financially supported by the United States Department of Energy’s Office of Biomass Program’s. Computing time was granted by a user project at the Molecular Science Computing Facility in the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory.

  18. A comparison of LH responses to intracerebroventricular, subcutaneous and intravenous administration of small doses of GnRH in cattle

    E-Print Network [OSTI]

    Rund, Lauretta Ann

    1982-01-01T23:59:59.000Z

    of Small Doses of GnRH in Cattle. (August 1982) Lauretta Ann Rund, B. S. , University of Illinois Chairman of Advisory Committee: Dr. Max Amoss The majority of studies investigating gonadotropin releasing hormone (GnRH) control of gonadotropin secreti.... on in cattle have utilized large doses of GnRH. The magnitude of endogenous pulsatile LH release would suggest that a much smaller amount of GnRH would produce the desired LH release. In an effort to determine the optimum dose and method of administration...

  19. A method of determining the dissolved oxygen in the moisture of a porous medium and some oxygen diffusion studies

    E-Print Network [OSTI]

    Runkles, Jack Ralph

    1952-01-01T23:59:59.000Z

    this dissolved oxygen The sample chamber apparatus gives ocnsplcte seal of the bottle from the atmosphere The ohsabor does not require a large ameunt Of nitrogen Sb remove all the oxygen from it, It is easily portable and light in weight The proposed method... METHOD QF DETRHRIUIHO THE DISSOLVED OXmEK IE THE MOISTURE OF A POROUS ERDD% @AD SMfE QXYOEB DKFFUSIOE STUDIES ' INTRO DUO fQRF, I Oxygen, bas been known to be important in plant growth fox maay years There has been a great deal of xesearoh...

  20. CO2 CH4 flux Air temperature Soil temperature and Soil moisture, Barrow, Alaska 2013 ver. 1

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Margaret Torn

    This dataset consists of field measurements of CO2 and CH4 flux, as well as soil properties made during 2013 in Areas A-D of Intensive Site 1 at the Next-Generation Ecosystem Experiments (NGEE) Arctic site near Barrow, Alaska. Included are i) measurements of CO2 and CH4 flux made from June to September (ii) Calculation of corresponding Gross Primary Productivity (GPP) and CH4 exchange (transparent minus opaque) between atmosphere and the ecosystem (ii) Measurements of Los Gatos Research (LGR) chamber air temperature made from June to September (ii) measurements of surface layer depth, type of surface layer, soil temperature and soil moisture from June to September.

  1. Radiative Transfer in the Midwave Infrared Applicable to Full Spectrum Atmospheric

    E-Print Network [OSTI]

    Kerekes, John

    of the radiative effects in the MWIR is needed. The MWIR is characterized by a unique combination of reduced solar conditions are stressing (e.g., high moisture, heavy aerosol/particulate loading, partial cloud cover, lowRadiative Transfer in the Midwave Infrared Applicable to Full Spectrum Atmospheric Characterization

  2. Behavior of trace and companion elements of ULC-IF steel grades during RH-treatment

    SciTech Connect (OSTI)

    Jungreithmeier, A.; Viertauer, A.; Presslinger, H. [Voest-Alpine Stahl Linz GmbH (Austria)

    1996-12-31T23:59:59.000Z

    A large number of metallurgical reactions are caused by lowering the partial pressure during vacuum treatment. One of these reactions is the volatilization of elements with high vapor pressure. The concentration of trace and companion elements during RH-treatment mostly changes because of cooling scrap, deoxidation agents and ferro-alloy additions, slag/metal reactions, vaporization and also because of reactions with the RH-vessel lining. These changes in the concentration of trace and companion elements during RH-treatment are exemplified for ULC-IF (ultra low carbon--interstitial free) steel grades. The elements which are considered are chromium, nickel, molybdenum, copper, vanadium, tin, zinc, lead, phosphorus, sulfur and nitrogen. Calculations of the theoretical equilibrium solubility using thermodynamic data--in dependence of pressure and temperature--correspond well with the values obtained during steel production operations. 67 refs.

  3. Validation of Atmospheric Infrared Sounder temperature and moisture profiles over tropical oceans and their impact

    E-Print Network [OSTI]

    Pu, Zhaoxia

    ] Tropical cyclones are one of the costliest and deadliest natural disasters in the United States and other the potential for economic damage and deaths. However, due to the lack of the conventional observations over/I satellite rainfall rates results in improvements in hurricane track forecasts in the GEOS global model [Hou

  4. Investigation of SGP Atmospheric Moisture Budget for CLASIC Â… Recycling Study

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn12 Investigation Peer Review 2012 May 9, 2012 Subject: Budget

  5. Old-field Community, Climate and Atmospheric Manipulation

    SciTech Connect (OSTI)

    Aimee Classen

    2009-11-01T23:59:59.000Z

    We are in the process of finishing a number of laboratory, growth chamber and greenhouse projects, analyzing data, and writing papers. The projects reported addressed these subjects: How do climate and atmospheric changes alter aboveground plant biomass and community structure; Effects of multiple climate changes factors on plant community composition and diversity: what did we learn from a 5-year open-top chamber experiment using constructed old-field communities; Do atmospheric and climatic change factors interact to alter woody seedling emergence, establishment and productivity; Soil moisture surpasses elevated CO{sub 2} and temperature in importance as a control on soil carbon dynamics; How do climate and atmospheric changes alter belowground root and fungal biomass; How do climate and atmospheric changes alter soil microarthropod and microbial communities; How do climate and atmospheric changes alter belowground microbial function; Linking root litter diversity and microbial functioning at a micro scale under current and projected CO{sub 2} concentrations; Multifactor climate change effects on soil ecosystem functioning depend on concurrent changes in plant community composition; How do climate and atmospheric changes alter aboveground insect populations; How do climate and atmospheric changes alter festuca endophyte infection; How do climate and atmospheric changes soil carbon stabilization.

  6. Cooling effect in emissions of 103mRh excited by bremsstrahlung

    E-Print Network [OSTI]

    Yao Cheng; Bing Xia; Chinping Chen

    2009-04-29T23:59:59.000Z

    Nonlinear characteristic emissions of K alpha, K beta and gamma with a significant triplet splitting at room temperature are observed from the long-lived nuclear state of 103mRh excited by bremsstrahlung irradiation. A pronounced phase-transition-like narrowing of the emission profiles occurs immediately after the sample is cooled down to 77 K. The room temperature profiles reappear again abruptly and almost reversibly as the temperature drifts freely back to approximately the ice point after the filling of liquid nitrogen is stopped. These emission properties at 300 K and at low temperature may indicate that the 103mRh nuclei are in collective states.

  7. CO oxidation trends on Pt-group metals from ultrahigh vacuum to near atmospheric pressures: A combined in situ PM-IRAS and reaction kinetics study

    E-Print Network [OSTI]

    Goodman, Wayne

    CO oxidation trends on Pt-group metals from ultrahigh vacuum to near atmospheric pressures Accepted for publication 14 October 2008 Available online 5 November 2008 Keywords: Pt-group metals CO a c t The CO oxidation reaction on Pt-group metals (Pt, Rh, and Pd) has been investigated at low (610À

  8. Rh-Based Mixed Alcohol Synthesis Catalysts: Characterization and Computational Report

    SciTech Connect (OSTI)

    Albrecht, Karl O.; Glezakou, Vassiliki Alexandra; Rousseau, Roger J.; Engelhard, Mark H.; Varga, Tamas; Colby, Robert J.; Jaffe, John E.; Li, Xiaohong S.; Mei, Donghai; Windisch, Charles F.; Kathmann, Shawn M.; Lemmon, Teresa L.; Gray, Michel J.; Hart, Todd R.; Thompson, Becky L.; Gerber, Mark A.

    2013-08-01T23:59:59.000Z

    The U.S. Department of Energy is conducting a program focused on developing a process for the conversion of biomass to bio-based fuels and co-products. Biomass-derived syngas is converted thermochemically within a temperature range of 240 to 330°C and at elevated pressure (e.g., 1200 psig) over a catalyst. Ethanol is the desired reaction product, although other side compounds are produced, including C3 to C5 alcohols; higher (i.e., greater than C1) oxygenates such as methyl acetate, ethyl acetate, acetic acid and acetaldehyde; and higher hydrocarbon gases such as methane, ethane/ethene, propane/propene, etc. Saturated hydrocarbon gases (especially methane) are undesirable because they represent a diminished yield of carbon to the desired ethanol product and represent compounds that must be steam reformed at high energy cost to reproduce CO and H2. Ethanol produced by the thermochemical reaction of syngas could be separated and blended directly with gasoline to produce a liquid transportation fuel. Additionally, higher oxygenates and unsaturated hydrocarbon side products such as olefins also could be further processed to liquid fuels. The goal of the current project is the development of a Rh-based catalyst with high activity and selectivity to C2+ oxygenates. This report chronicles an effort to characterize numerous supports and catalysts to identify particular traits that could be correlated with the most active and/or selective catalysts. Carbon and silica supports and catalysts were analyzed. Generally, analyses provided guidance in the selection of acceptable catalyst supports. For example, supports with high surface areas due to a high number of micropores were generally found to be poor at producing oxygenates, possibly because of mass transfer limitations of the products formed out of the micropores. To probe fundamental aspects of the complicated reaction network of CO with H2, a computational/ theoretical investigation using quantum mechanical and ab initio molecular dynamics calculations was initiated in 2009. Computational investigations were performed first to elucidate understanding of the nature of the catalytically active site. Thermodynamic calculations revealed that Mn likely exists as a metallic alloy with Rh in Rh-rich environments under reducing conditions at the temperatures of interest. After determining that reduced Rh-Mn alloy metal clusters were in a reduced state, the activation energy barriers of numerous transition state species on the catalytically active metal particles were calculated to compute the activation barriers of several reaction pathways that are possible on the catalyst surface. Comparison of calculations with a Rh nanoparticle versus a Rh-Mn nanoparticle revealed that the presence of Mn enabled the reaction pathway of CH with CO to form an adsorbed CHCO species, which was a precursor to C2+ oxygenates. The presence of Mn did not have a significant effect on the rate of CH4 production. Ir was observed during empirical catalyst screening experiments to improve the activity and selectivity of Rh-Mn catalysts. Thus, the addition of Ir to the Rh-Mn nanoparticles also was probed computationally. Simulations of Rh-Mn-Ir nanoparticles revealed that, with sufficient Ir concentrations, the Rh, Mn and Ir presumably would be well mixed within a nanoparticle. Activation barriers were calculated for Rh-Mn-Ir nanoparticles for several C-, H-, and O-containing transitional species on the nanoparticle surface. It was found that the presence of Ir opened yet another reactive pathway whereby HCO is formed and may undergo insertion with CHx surface moieties. The reaction pathway opened by the presence of Ir is in addition to the CO + CH pathway opened by the presence of Mn. Similar to Mn, the presence of Ir was not found to not affect the rate of CH4 production.

  9. The Influence of Moisture and Temperature on Cotton Root Rot.

    E-Print Network [OSTI]

    Taubenhaus, J. J. (Jacob Joseph); Dana, B. F. (Bliss F.)

    1928-01-01T23:59:59.000Z

    . BAYLES, B. S., Superintendent J. PAUL LUSK, S. M., Plant Patholog Teachers in the School of Arnicultnre Carryine Coo~erative Projects on the Statit -- . G W ADRIANCE M S ~srociate~~rofessor of Horticulture S ' W 'BI~SING ~h D 'kro&sor of Entomology V... of the season. This initial moisture supply, together mith the additions during the growing season, permitted the continued development of root rot throughout the entire season. ,It the INFLUENCE OF MOISTURE AND TEMPERATURE ON COTTON ROOT ROT 9 end...

  10. Moisture Sensor for Sulfur Hexafluoride (SF6)-filled Circuit Breakers

    SciTech Connect (OSTI)

    Sauers, I.

    2001-04-27T23:59:59.000Z

    Measurements at ORNL were made on the Kahn moisture sensor which Doble Engineering wants to evaluate for use in SF{sub 6} circuit breakers. Test conducted at ORNL indicate that vacuum conditions, as might be found in SF{sub 6} circuit breakers prior to filling with SF{sub 6}, could lead to significant changes in calibration, resulting in erroneous readings of moisture content. Similar effects might also be observed in cases where SF{sub 6} byproducts are present, due the reactivity of some of these byproducts with water.

  11. System design description for surface moisture measurement system (SMMS)

    SciTech Connect (OSTI)

    Vargo, G.F.

    1996-09-23T23:59:59.000Z

    The SMMS has been developed to measure moisture in the top few centimeters of tank waste. The SMMS development was initiated by the preliminary findings of SAR-033, and does not necessarily fulfill any established DQO. After the SAR-033 is released, if no significant changes are made, moisture measurements in the organic waste tanks will rapidly become a DQO. The SMMS was designed to be installed in any 4 inch or larger riser, and to allow maximum adjustability for riser lengths, and is used to deploy a sensor package on the waste surface within a 6 foot radius about the azimuth. The first sensor package will be a neutron probe.

  12. Investigation of moisture content variations in highway subgrades and bases

    E-Print Network [OSTI]

    Jenkins, Edward Donald

    1957-01-01T23:59:59.000Z

    , temperature gradient, hydraulic gradient, and textural radient, Frost action is caused. by a freezing temperature which forms ice crystals and draws moisnure from the soil pores. This creates a hvdraulic gradient for tI e movement of moisture in the liq... and the remedies are fairly well-known and used. in highway construction. There are three conditions required for detrimental frost action to occur: (1) a frost susceptible soil; (2) a freezing temperature; and ($) a water source. The movement 10 of moisture...

  13. Remote monitoring of soil moisture using airborne microwave radiometers

    E-Print Network [OSTI]

    Kroll, Charles Lindsey

    1973-01-01T23:59:59.000Z

    REMOTE MONITORING OF SOIL MOISTURE USING AIRBORNE MICROWAVE RADIOMETERS A Thesis by CHARLES LINDSEY J(ROLL Submitted to the Graduate College of Texas A)M University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE... August 1973 Major Subject: Electrical Engineering REMOTE MONITORING OF SOIL MOISTURE USING AIRBORNE MICROWAVE RADIOMETERS A Thesis by CHARLES LINDSEY KROLL Approved as to style and content by: man o Co mrtt Hca o D artmc c Ill l c r Mem e Member...

  14. Stresses in adhesive joints due to moisture sorption 

    E-Print Network [OSTI]

    Jen, Ming-Hwa Robert

    1980-01-01T23:59:59.000Z

    for the Case of 2 Moisture Absorpt1on. . . . . . . . . . . . . . . . . . 53 The Non-Dimensional Peel Stress p and the Interlaminar Shear Stresses T and T vs. the Non-Dimensional D1stance x for the Case of Moi stfre Absorption . . . . . . . . . 54 The Non...-Dimensional Displacement W2 of the Outer-Adherends vs. the Non-Dimens1onal Distance x for the Case of Moisture Desorption . . . . . . . . . . . . . . . . . . 55 The Non-Dimensional Peel Stress p and the Interlaminar Shear Stresses T and T2 vs. the Non-D1mens1onal...

  15. Predicting farm machinery operation time with a soil moisture mode

    E-Print Network [OSTI]

    Bordovsky, James Paul

    1978-01-01T23:59:59.000Z

    -1972 . 76 Figure Page 24. Measured and computed plant available soil moisture in the top 30 cm of the soil profile on watershed Y-8 at Riesel, Texas during 1969, 1970, and 1972 79-81 25. Measured and computed plant available soil moisture in the top... for September, October, and November, 1977 97-99 32. Observed and calculated trafficability data at Corpus Christi, Texas for July, September, October, and November, 1977 . . 101-104 A-1 . The value of PM when S = O. l and S = 0. 25 and aM is the independ...

  16. DIGESTION DURING PREGNANCY AND LACTATION IN SHEEP R.H. WESTON

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    DIGESTION DURING PREGNANCY AND LACTATION IN SHEEP R.H. WESTON C. S. /. R. O., Division of Animal on changes in the digestive function in the sheep during pregnancy and lactation although such information) digestion in the stomach and intestines. Some of the data are reported here and the studies will be reported

  17. Structural and dynamic properties of propane coordinated to TpRh(CNR) from a confrontation

    E-Print Network [OSTI]

    Jones, William D.

    Structural and dynamic properties of propane coordinated to TpRh(CNR) from a confrontation between] in interaction with propane. Two complexes have been found as minima coordinated through either a methyl the methylene complex of propane into a methyl complex of pro- pane. This latter reaction has a much lower

  18. Thermodynamics and superconductivity of Th7(Fe, Ru, Os, Co, Rh, Ir)3 system

    SciTech Connect (OSTI)

    Smith, James L [Los Alamos National Laboratory; Lashley, Jason C [Los Alamos National Laboratory; Volz, Heather M [Los Alamos National Laboratory; Fisher, Robert A [Los Alamos National Laboratory

    2008-01-01T23:59:59.000Z

    Expanding the temperature range of previous specific-heat measurements on the Th7(Fe, Ru, Os, Co, Rh, Ir)3 system, we measure the effect of transition-metal substitution on total entropy (S{sub 298 k}), electronic specific heat ({gamma}), and Debye temperature ({Theta}D). In addition we measure the pressure dependence, up to 10 kbar, of the superconducting transition.

  19. Association of intracellular calcium oscillations with release of gonadotropin-releasing hormone (GnRH) from GT1-1 neuronal cells

    E-Print Network [OSTI]

    Gilmore, Chrystal Dawn

    1999-01-01T23:59:59.000Z

    the relationship of GnRH release with [Ca²?][] oscillations using the GT1-1 neuronal cell line. GnRH release was measured by radioimmunoassay of media incubated with GT1-1 neuronal cells for 1 hr with control or test substances to induce release of GnRH. [Ca...

  20. Effect of prostaglandin E? (PGE?) on the release of gonadotropin-releasing hormone (GnRH) from infundibular explants of cattle

    E-Print Network [OSTI]

    Stephens, Tyler Paul

    2001-01-01T23:59:59.000Z

    GnRH neuronal terminals located in the infundibulum of rodents have been shown to release GnRH when stimulated with PGE? in vivo and in vitro. The effect of PGE? on the release of GnRH has not been determined in cattle. Thus, the objective...

  1. Derivation of Soil Moisture Retention Characteristics from Saturated Hydraulic Conductivity

    E-Print Network [OSTI]

    Kumar, C.P.

    systems require knowledge of the relationships between soil moisture content (), soil water pressure (h, and evapotranspiration. The soil factors include soil matric potential and water content relationship, saturated content of soil. The relation between matric potential and volumetric water content in a soil is termed

  2. SOIL MOISTURE CHARACTERISTICS IN UPPER PART OF HINDON RIVER CATCHMENT

    E-Print Network [OSTI]

    Kumar, C.P.

    of the contribution of various parts of a watershed to the ground water storage. Convenient and reliable techniques for the water demand of the vegetation, as well as for the recharge of the ground water storage. A fair into ground water aquifers. For analytical studies on soil moisture regime, critical review and accurate

  3. Integrating soil moisture and groundwater into climate models

    E-Print Network [OSTI]

    Krakauer, Nir Y.

    dNm dt =m Nm1- Nm -h Nh min1, Nm State transition to oscillatory solutions with efficient hunting: same initial and boundary conditions, but soil moisture set to seasonal climatology from DYNA experiments: Irrigation Simulate equilibrium climate with a mixed- layer ocean, year-2000 or 2050 (A1B

  4. Moisture Distribution and Flow During Drying of Wood and Fiber

    SciTech Connect (OSTI)

    Zink-Sharp, Audrey; Hanna, Robert B.

    2001-12-28T23:59:59.000Z

    New understanding, theories, and techniques for moisture flow and distribution were developed in this research on wood and wood fiber. Improved understanding of the mechanisms of flake drying has been provided. Observations of flake drying and drying rate curves revealed that rate of moisture loss consisted of two falling rate periods and no constant rate drying period was observed. Convective heat transfer controls the first period, and bound water diffusion controls the second period. Influence of lower drying temperatures on bending properties of wood flakes was investigated. Drying temperature was found to have a significant influence on bending stiffness and strength. A worksheet for calculation of the energy required to dry a single strandboard flake was developed but has not been tested in an industrial setting yet. A more complete understanding of anisotropic transverse shrinkage of wood is proposed based on test results and statistical analysis. A simplified mod el of a wood cell's cross-section was drawn for calculating differential transverse shrinkage. The model utilizes cell wall thickness and microfibrillar packing density and orientation. In spite of some phenomena of cell wall structure not yet understood completely, the results might explain anisotropic transverse shrinkage to a major extent. Boundary layer theory was found useful for evaluating external moisture resistance during drying. Simulated moisture gradients were quire comparable to the actual gradients in dried wood. A mathematical procedure for determining diffusion and surface emission coefficients was also developed. Thermal conductivity models of wood derived from its anatomical structure were created and tested against experimental values. Model estimations provide insights into changes in heat transfer parameters during drying. Two new techniques for measuring moisture gradients created in wood during drying were developed. A new technique that utilizes optical properties of cobalt chloride was developed for nondestructive determination of surface moisture content. Fundamental new understanding of drying characteristics in wood and fiber has been provided that can be used by researchers to improve drying of wood and fiber. The three techniques for measuring moisture content and gradients provided in this study are efficient, practical, and economical - easy to apply by industry and researchers. An energy consumption worksheet is provided as a first step toward reducing energy consumed during drying of lumber and strandboard flakes. However, it will need additional verification and testing.

  5. Preliminary non-destructive assessment of moisture content, hydration and dielectric properties of Portland cement concrete 

    E-Print Network [OSTI]

    Avelar Lezama, Ivan

    2007-04-25T23:59:59.000Z

    Moisture availability is a focal point in the structural development of young concrete. Under low humidity and hot weather conditions, concrete loses moisture rapidly as it hardens, and it is very difficult, if not impossible, ...

  6. Moisture degradation in FRP bonded concrete systems : an interface fracture approach

    E-Print Network [OSTI]

    Au, Ching, 1977-

    2005-01-01T23:59:59.000Z

    (cont.) characterization, and kink criterion implementation, form a synergistic analysis of the mechanistic debonding behavior affected by moisture. Results have shown that moisture affected debonding is a highly complex ...

  7. A Coupled Micromechanical Model of Moisture-Induced Damage in Asphalt Mixtures: Formulation and Applications 

    E-Print Network [OSTI]

    Caro Spinel, Silvia

    2011-02-22T23:59:59.000Z

    The deleterious effect of moisture on the structural integrity of asphalt mixtures has been recognized as one of the main causes of early deterioration of asphalt pavements. This phenomenon, usually referred to as moisture damage, is defined...

  8. DEVELOPMENT OF A RAPID TEST TO DETERMINE MOISTURE SENSTIVITY OF HMA (SUPERPAVE) MIXTURES

    E-Print Network [OSTI]

    Shiwakoti, Harihar

    2007-12-14T23:59:59.000Z

    Exiting test methods to determine moisture sensitivity in hot mix asphalt are time consuming and inconsistent. This research focused on wheel tracking devices to develop a rapid test method to evaluate moisture sensitivity. The Asphalt Pavement...

  9. SOLID WOOD PRODUCTS I TECHNICAL NOTE CALIBRATION OF MOISTURE METERS FOR

    E-Print Network [OSTI]

    tanks, and boats, the kiln and allowed to cool. They were content (MC) of wood. However, the cor and electrical resis- cypress have been supplied by moisture handled or conditioned. One moisture tance

  10. NASA's Soil Moisture Active Passive (SMAP) Mission and Opportunities for Applications Users

    E-Print Network [OSTI]

    Brown, Molly E.

    Water in the soil—both its amount (soil moisture) and its state (freeze/thaw)—plays a key role in water and energy cycles, in weather and climate, and in the carbon cycle. Additionally, soil moisture touches upon human ...

  11. The Soil Moisture Active and Passive Mission (SMAP): Science and Applications

    E-Print Network [OSTI]

    Entekhabi, Dara

    The soil moisture active and passive mission (SMAP) will provide global maps of soil moisture content and surface freeze/thaw state. Global measurements of these variables are critical for terrestrial water and carbon cycle ...

  12. Atmospheric Transport of Radionuclides

    SciTech Connect (OSTI)

    Crawford, T.V.

    2003-03-03T23:59:59.000Z

    The purpose of atmospheric transport and diffusion calculations is to provide estimates of concentration and surface deposition from routine and accidental releases of pollutants to the atmosphere. This paper discusses this topic.

  13. Is It Homogeneous or Heterogeneous Catalysis Derived from [RhCp*Cl2]2? In Operando-XAFS, Kinetic and Crucial Kinetic Poisoning Evidence for Subnanometer Rh4 Cluster-Based Benzene Hydrogenation Catalysis

    SciTech Connect (OSTI)

    Bayram, Ercan; Linehan, John C.; Fulton, John L.; Roberts, John A.; Szymczak, Nathaniel; Smurthwaite, Tricia D.; Ozkar, Saim; Balasubramanian, Mahalingam; Finke, Richard G.

    2011-11-23T23:59:59.000Z

    Determining the true, kinetically dominant catalytically active species, in the classic benzene hydrogenation system pioneered by Maitlis and co-workers 34 years ago starting with [RhCp*Cl2]2 (Cp* = [{eta}5-C5(CH3)5]), has proven to be one of the most challenging case studies in the quest to distinguish single-metal-based 'homogeneous' from polymetallic, 'heterogeneous' catalysis. The reason, this study will show, is the previous failure to use the proper combination of (i) operando spectroscopy to determine the dominant form(s) of the precatalyst's mass under catalysis (i.e., operating) conditions, plus then and crucially also (ii) the previous lack of the necessary kinetic studies, catalysis being a 'wholly kinetic phenomenon' as J. Halpern long ago noted. An important contribution from this study will be to reveal the power of quantitiative kinetic poisoning experiments for distinguishing single-metal, or in this case subnanometer Rh4 cluster-based catalysis from larger, polymetallic Rh(0)n nanoparticle catalysis, at least under favorable conditions. The combined operando-XAFS (X-ray absorption fine structure) spectroscopy and kinetic evidences provide a compelling case for Rh4-based, with average stoichiometry 'Rh4Cp*2.4Cl4Hc', benzene hydrogenation catalysis in 2-propanol with added Et3N and at 100 C and 50 atm initial H2 pressure. The results also reveal, however, that if even ca. 1.4% of the total soluble Rh(0)n had formed nanoparticles, then those Rh(0)n nanoparticles would have been able to account for all the observed benzene hydrogenation catalytic rate (using commercial, ca. 2 nm, polyethyleneglycol-dodecylether hydrosol stabilized Rh(0)n nanoparticles as a model system). The results 'especially the poisoning methodology developed and employed' are of significant, broader interest since determining the nature of the true catalyst continues to be a central, often vexing issue in any and all catalytic reactions. The results are also of fundamental interest in that they add to a growing body of evidence indicating that certain, appropriately ligated, coordinatively unsaturated, subnanometer M4 transition-metal clusters can be relatively robust catalysts. Also demonstrated herein is that Rh4 clusters are poisoned by Hg(0), demonstrating for the first time that the classic Hg(0) poisoning test of 'homogeneous' vs 'heterogeneous'catalysts cannot distinguish Rh4-based subnanometer catalysts from Rh(0)n nanoparticle catalysts, at least for the present examples of these two specific, Rh-based catalysts.

  14. How atmospheric ice forms | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    atmospheric ice forms How atmospheric ice forms Released: September 08, 2014 New insights into atmospheric ice formation could improve climate models This study advances our...

  15. Atmospheric Pressure Reactor System | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Atmospheric Pressure Reactor System Atmospheric Pressure Reactor System The atmospheric pressure reactor system is designed for testing the efficiency of various catalysts for the...

  16. Climate Sciences: Atmospheric Thermodynamics

    E-Print Network [OSTI]

    Russell, Lynn

    1 Climate Sciences: Atmospheric Thermodynamics Instructor: Lynn Russell, NH343 http://aerosol.ucsd.edu/courses.html Text: Curry & Webster Atmospheric Thermodynamics Ch1 Composition Ch2 Laws Ch3 Transfers Ch12 Energy Climate Sciences: Atmospheric Thermodynamics Instructor: Lynn Russell, NH343 http

  17. Terrestrial Planet Atmospheres. The Moon's Sodium Atmosphere

    E-Print Network [OSTI]

    Walter, Frederick M.

    ;Origins of Atmospheres · Outgassing ­ Volcanoes expel water, CO2, N2, H2S, SO2 removed by the Fme convecFon reaches deserts #12;Water and Ice Clouds #12;H2SO4

  18. Direct Functionalization of Nitrogen Heterocycles via Rh-Catalyzed C-H Bond Activation

    SciTech Connect (OSTI)

    Lewis, Jared; Bergman, Robert; Ellman, Jonathan

    2008-02-04T23:59:59.000Z

    Nitrogen heterocycles are present in many compounds of enormous practical importance, ranging from pharmaceutical agents and biological probes to electroactive materials. Direct funtionalization of nitrogen heterocycles through C-H bond activation constitutes a powerful means of regioselectively introducing a variety of substituents with diverse functional groups onto the heterocycle scaffold. Working together, our two groups have developed a family of Rh-catalyzed heterocycle alkylation and arylation reactions that are notable for their high level of functional-group compatibility. This Account describes their work in this area, emphasizing the relevant mechanistic insights that enabled synthetic advances and distinguished the resulting transformations from other methods. They initially discovered an intramolecular Rh-catalyzed C-2-alkylation of azoles by alkenyl groups. That reaction provided access to a number of di-, tri-, and tetracyclic azole derivatives. They then developed conditions that exploited microwave heating to expedite these reactions. While investigating the mechanism of this transformation, they discovered that a novel substrate-derived Rh-N-heterocyclic carbene (NHC) complex was involved as an intermediate. They then synthesized analogous Rh-NHC complexes directly by treating precursors to the intermediate [RhCl(PCy{sub 3}){sub 2}] with N-methylbenzimidazole, 3-methyl-3,4-dihydroquinazolein, and 1-methyl-1,4-benzodiazepine-2-one. Extensive kinetic analysis and DFT calculations supported a mechanism for carbene formation in which the catalytically active RhCl(PCy{sub 3}){sub 2} fragment coordinates to the heterocycle before intramolecular activation of the C-H bond occurs. The resulting Rh-H intermediate ultimately tautomerizes to the observed carbene complex. With this mechanistic information and the discovery that acid co-catalysts accelerate the alkylation, they developed conditions that efficiently and intermolecularly alkylate a variety of heterocycles, including azoles, azolines, dihydroquinazolines, pyridines, and quinolines, with a wide range of functionalized olefins. They demonstrated the utility of this methodology in the synthesis of natural products, drug candidates, and other biologically active molecules. In addition, they developed conditions to directly arylate these heterocycles with aryl halides. The initial conditions that used PCy{sub 3} as a ligand were successful only for aryl iodides. However, efforts designed to avoid catalyst decomposition led to the development of ligands based on 9-phosphabicyclo[4.2.1]nonane (Phoban) that also facilitated the coupling of aryl bromides. They then replicated the unique coordination environment, stability, and catalytic activity of this complex using the much simpler tetrahydrophosphepine ligands and developed conditions that coupled aryl bromides bearing diverse functional groups without the use of a glovebox or purified reagents. With further mechanistic inquiry, they anticipate that researchers will better understand the details of the aforementioned Rh-catalyzed C-H bond functionalization reactions, resulting in the design of more efficient and robust catalysts, expanded substrate scope, and new transformations.

  19. Magnetism and superconductivity in U?PtxRh(1–x)C?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wakeham, N.; Ni, Ni; Bauer, E. D.; Thompson, J. D.; Tegtmeier, E.; Ronning, F.

    2015-01-01T23:59:59.000Z

    We report the phase diagram of the doping series U?PtxRh(1–x)C?, studied through measurements of resistivity, specific heat, and magnetic susceptibility. The Néel temperature of U?Rh?C? of ~ 22 K is suppressed with increasing Pt content, reaching zero temperature close to x = 0.7, where we observed signatures of increased quantum fluctuations. In addition, evidence is presented that the antiferromagnetic state undergoes a spin-reorientation transition upon application of an applied magnetic field. This transition shows non-monotonic behavior as a function of x, peaking at around x = 0.3. Superconductivity is observed for x ? 0.9, with Tc increasing with increasing x.more »The reduction in Tc and increase in residual resistivity with decreasing Pt content is inconsistent with the extension of the Abrikosov-Gor'kov theory to unconventional superconductivity.« less

  20. Colloidally Synthesized Monodisperse Rh Nanoparticles Supported on SBA-15 for Size- and Pretreatment-Dependent Studies of CO Oxidation

    E-Print Network [OSTI]

    Grass, Michael E.

    2010-01-01T23:59:59.000Z

    303 K for sorption measurements with H 2 (Praxair, 99.999%)or CO (Praxair, 99.99%). As-synthesized Rh(X)/SBA-15 samplesFlow rates of oxygen ( Praxair, 99.995%), carbon monoxide (

  1. CO Oxidation on Pt-Group Metals from Ultrahigh Vacuum to Near Atmospheric Pressures. F. Gao, Y. Cai, K. K. Gath, Y. Wang, M. S. Chen, Q. L. Guo, and D. W. Goodman*

    E-Print Network [OSTI]

    Goodman, Wayne

    CO Oxidation on Pt-Group Metals from Ultrahigh Vacuum to Near Atmospheric Pressures. 1. Rhodium FVised Manuscript ReceiVed: NoVember 3, 2008 The CO oxidation reaction on Rh(111) was studied both at low pressures reactor at various gaseous reactant compositions. Surface CO and O coverages were determined using

  2. Adequacy of a Small Quantity Site RH-TRU Waste Program in Meeting Proposed WIPP Characterization Objectives

    SciTech Connect (OSTI)

    Biedscheid, J.; Stahl, S.; Devarakonda, M.; Peters, K.; Eide, J.

    2002-02-26T23:59:59.000Z

    The first remote-handled transuranic (RH-TRU) waste is expected to be permanently disposed of at the Waste Isolation Pilot Plant (WIPP) during Fiscal Year (FY) 2003. The first RH-TRU waste shipments are scheduled from the Battelle Columbus Laboratories (BCL) to WIPP in order to facilitate compliance with BCL Decommissioning Project (BCLDP) milestones. Milestones requiring RH-TRU waste containerization and removal from the site by 2004 in order to meet a 2006 site closure goal, established by Congress in the Defense Facilities Closure Projects account, necessitated the establishment and implementation of a site-specific program to direct the packaging of BCLDP RH-TRU waste prior to the finalization of WIPP RH-TRU waste characterization requirements. The program was designed to collect waste data, including audio and videotape records of waste packaging, such that upon completion of waste packaging, comprehensive data records exist from which compliance with final WIPP RH-TRU waste characterization requirements can be demonstrated. With the BCLDP data records generated to date and the development by the U.S. Department of Energy (DOE)-Carlsbad Field Office (CBFO) of preliminary documents proposing the WIPP RH-TRU waste characterization program, it is possible to evaluate the adequacy of the BCLDP program with respect to meeting proposed characterization objectives. The BCLDP characterization program uses primarily acceptable knowledge (AK) and visual examination (VE) during waste packaging to characterize RH-TRU waste. These methods are used to estimate physical waste parameters, including weight percentages of metals, cellulosics, plastics, and rubber in the waste, and to determine the absence of prohibited items, including free liquids. AK combined with computer modeling is used to estimate radiological waste parameters, including total activity on a waste container basis, for the majority of BCLDP RH-TRU waste. AK combined with direct analysis is used to characterize radiological parameters for the small populations of the RH-TRU waste generated by the BCLDP. All characterization based on AK is verified. Per its design for comprehensive waste data collection, the BCLDP characterization program using AK and waste packaging procedures, including VE during packaging, meets the proposed WIPP RH-TRU waste characterization objectives. The conservative program design implemented generates certification data that will be adequate to meet any additional program requirements that may be imposed by the CBFO.

  3. Colloidally Synthesized Monodisperse Rh Nanoparticles Supported on SBA-15 for Size- and Pretreatment-Dependent Studies of CO Oxidation

    SciTech Connect (OSTI)

    Grass, Michael E.; Joo, Sang Hoon; Somorjai, Gabor A.

    2009-02-12T23:59:59.000Z

    A particle size dependence for CO oxidation over rhodium nanoparticles of 1.9-11.3 nm has been investigated and determined to be modified by the existence of the capping agent poly(vinylpyrrolidone) (PVP). The particles were prepared using a polyol reduction procedure with PVP as the capping agent. The Rh nanoparticles were subsequently supported on SBA-15 during hydrothermal synthesis to produce Rh/SBA-15 supported catalysts for size-dependent catalytic studies. CO oxidation by O{sub 2} at 40 Torr CO and 100 Torr O{sub 2} was investigated over two series of Rh/SBA-15 catalysts: as-synthesized Rh/SBA-15 covering the full range of Rh sizes and the same set of catalysts after high temperature calcination and reduction. The turnover frequency at 443 K increases from 0.4 to 1.7 s{sup -1} as the particle size decreases from 11.3 to 1.9 nm for the as-synthesized catalysts. After calcination and reduction, the turnover frequency is between 0.1 and 0.4 s{sup -1} with no particle size dependence. The apparent activation energy for all catalysts is {approx}30 kcal mol{sup -1} and is independent of particle size and thermal treatment. Infrared spectroscopy of CO on the Rh nanoparticles indicates that the heat treatments used influence the mode of CO adsorption. As a result, the particle size dependence for CO oxidation is altered after calcination and reduction of the catalysts. CO adsorbs at two distinct bridge sites on as-synthesized Rh/SBA-15, attributable to metallic Rh(0) and oxidized Rh(I) bridge sites. After calcination and reduction, however, CO adsorbs only at Rh(0) atop sites. The change in adsorption geometry and oxidation activity may be attributable to the interaction between PVP and the Rh surface. This capping agent affect may open new possibilities for the tailoring of metal catalysts using solution nanoparticle synthesis methods.

  4. Evolution of moisture convergence in a mesoscale convective complex

    E-Print Network [OSTI]

    Bercherer, John Phillip

    1990-01-01T23:59:59.000Z

    Committee: Dr. Keuneth C. Brundidge Two separate Mesoscale Convective Complexes (MCCs) were investigated to determine if a characteristic surface moisture convergence (MC) signature existed on the mesoscale during their lifecycle. The first storm (Case 1... convergence, a bandpass filtering technique was utilized. It was found that MC could identify the general area of initial thunderstorm activity 2 h prior to its development for both cases. During the initial development stage of Case 1, advection...

  5. Hazards and operability study for the surface moisture monitoring system

    SciTech Connect (OSTI)

    Board, B.D.

    1996-04-04T23:59:59.000Z

    The Hanford Nuclear Reservation Tank Farms` underground waste tanks have been used to store liquid radioactive waste from defense materials production since the 1940`s. Waste in certain of the tanks may contain material in the form of ferrocyanide or various organic compounds which could potentially be susceptible to condensed phase chemical reactions. Because of the presence of oxidizing materials (nitrate compounds) and heat sources (radioactive decay and chemical reactions), the ferrocyanide or organic material could potentially fuel a propagating exothermic reaction with undesirable consequences. Analysis and experiments indicate that the reaction propagation and/or initiation may be prevented by the presence of sufficient moisture in the waste. Because the reaction would probably be initiated at the surface of the waste, evidence of sufficient moisture concentration would help provide evidence that the tank waste can continue to be safely stored. The Surface Moisture Measurement System (SMMS) was developed to collect data on the surface moisture in the waste by inserting two types of probes (singly) into a waste tank-a neutron probe and an electromagnetic inductance (EMI) probe. The sensor probes will be placed on the surface of the waste utilizing a moveable deployment arm to lower them through an available riser. The movement of the SMMS within the tank will be monitored by a camera lowered through an adjacent riser. The SMMS equipment is the subject of this study. Hazards and Operability Analysis (HAZOP) is a systematic technique for assessing potential hazards and/or operability problems for a new activity. It utilizes a multidiscipline team of knowledgeable individuals in a systematic brainstorming effort. The results of this study will be used as input to an Unreviewed Safety Question determination.

  6. [DELTA T dryer/moisture control system]. Final technical report

    SciTech Connect (OSTI)

    Not Available

    1995-01-01T23:59:59.000Z

    Drying Technology, Inc. was awarded a grant for the purpose of extending DELTA T dryer/moisture control technology into additional industries. Ultimate purpose of the grant was to save energy and improve efficiency in the process industries. Results indicate that these objectives have been met and will continue as this new technology is duplicated in the present industries and also is extended into other industries as well.

  7. The structure of a late-spring moisture burst

    E-Print Network [OSTI]

    Stockton, Jay Richard

    1986-01-01T23:59:59.000Z

    masses from tropical air masses. McGuirk et ol. (1983) developed a moisture burst climatology for the months of November through Apnl, utilizing Geostationary Operational Environmental Satelhte-West (GOES-W) IR imagery taken every six hours. Four... in the area. c) Point comparisons outside of the active burst regions show systematic overpredictions of mean relative humidity and underpredictions of temporal variability by ECMWF analyses with respect to observations. d) Satellite channel radiance data...

  8. Nondestructive NMR technique for moisture determination in radioactive materials.

    SciTech Connect (OSTI)

    Aumeier, S.; Gerald, R.E. II; Growney, E.; Nunez, L.; Kaminski, M.

    1998-12-04T23:59:59.000Z

    This progress report focuses on experimental and computational studies used to evaluate nuclear magnetic resonance (NMR) spectroscopy and magnetic resonance imaging (MRI) for detecting, quantifying, and monitoring hydrogen and other magnetically active nuclei ({sup 3}H, {sup 3}He, {sup 239}Pu, {sup 241}Pu) in Spent nuclear fuels and packaging materials. The detection of moisture by using a toroid cavity NMR imager has been demonstrated in SiO{sub 2} and UO{sub 2} systems. The total moisture was quantified by means of {sup 1}H NMR detection of H{sub 2}O with a sensitivity of 100 ppm. In addition, an MRI technique that was used to determine the moisture distribution also enabled investigators to discriminate between bulk and stationary water sorbed on the particles. This imaging feature is unavailable in any other nondestructive assay (NDA) technique. Following the initial success of this program, the NMR detector volume was scaled up from the original design by a factor of 2000. The capacity of this detector exceeds the size specified by DOE-STD-3013-96.

  9. EMSL - Atmospheric Aerosol Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    scienceatmospheric The Atmospheric Aerosol Systems Science Theme focuses on understanding the chemistry, physics and molecular-scale dynamics of aerosols for model...

  10. Atmospheric Neutrino Fluxes

    E-Print Network [OSTI]

    Thomas K. Gaisser

    2005-02-18T23:59:59.000Z

    Starting with an historical review, I summarize the status of calculations of the flux of atmospheric neutrinos and how they compare to measurements.

  11. Atmospheric Dynamics II Instructor

    E-Print Network [OSTI]

    AT602 Atmospheric Dynamics II 2 credits Instructor: David W. J. Thompson davet: An Introduction to Dynamic Meteorology, 5th Edition, Academic Press (recommended) · Marshall, J., and Plumb, R. A., 2008: Atmosphere, Ocean, and Climate Dynamics: An Introductory Text, Academic Press. · Vallis, G. K

  12. Atmospheric Thermodynamics Composition

    E-Print Network [OSTI]

    Russell, Lynn

    1 Atmospheric Thermodynamics Ch1 Composition Ch2 Laws Ch3 Transfers Ch12 EnergyBalance Ch4 Water Ch Sciences: Atmospheric Thermodynamics Instructor: Lynn Russell, NH343 http #12;2 Review from Ch. 1 · Thermodynamic quantities · Composition · Pressure · Density · Temperature

  13. Using electrical resistance probes for moisture determination in switchgrass windrows

    SciTech Connect (OSTI)

    Chesser Jr., G. D.; Davis, J. D.; Purswell, J. L.; Lemus, R.

    2011-08-01T23:59:59.000Z

    Determining moisture levels in windrowed biomass is important for both forage producers and researchers. Energy crops such as switchgrass have been troublesome when using the standard methods set for electrical resistance meters. The objectives of this study were to i) develop the methodologies needed to measure MC in switchgrass using electrical resistance meters, ii) to determine the effects of pressure and probe orientation on MC measurement and iii) to generate MC calibration equations for electrical resistance meters using switchgrass in the senescence growth stage. Two meters (Meter 1, Farmex HT-PRO; Meter 2, Delmhorst F-2000) were selected based on commercial availability. A forage compression apparatus was designed and constructed with on-farm materials and methods to provide a simple system of applying pressure achievable by any forage producer or researcher in the field. Two trials were performed to test four levels of moisture contents (10, 20, 30, and 40%), five pressures (0, 1.68, 3.11, 4.55, 6.22 kN/m 2; 0, 35, 65, 95, 130 lb/ft 2), and two probe orientations (axial and transverse) in a 4x5x2 factorial design. Results indicated that meter accuracy increased as pressure increased. Regression models accounted for 91% and 81% of the variation for Meter 1 and Meter 2 at a pressure of 4.55 kN/m 2 (95 lb/ft 2) and a transverse probe orientation. Calibration equations were developed for both meters to improve moisture measurement accuracy for farmers and researchers in the field.

  14. A soil moisture availability model for crop stress prediction

    E-Print Network [OSTI]

    Gay, Roger Franklin

    1983-01-01T23:59:59.000Z

    wet so11 profile [Ritch1e et al. , 1972] . . . . . . . . . . . . . . 12 Relationships between the ratio of actual evaporation (Ea) to pan evaporat1on (E an) as a function of the available soil water in Rule and Bragg soybean [Burch et al. , 1978...] F1gure Interact1ons between soil-moisture status and other components of a general crop yield model . . . . . . . . . . . . . . . 16 Figure Root densit1es for ra1nfed Ruse and Bragg soybean, 98 days after planting [Burch et al. , 1978...

  15. Transient Analysis for Thermal and Moisture Behavior of Building Elements

    E-Print Network [OSTI]

    Guo, X.; Chen, Y.

    2006-01-01T23:59:59.000Z

    (,0)mx m= (10) 3.SOLVING METHOD Applying the Laplace transformation to Eqs.(3), (4), (5), (6), (7) and (8) with respect to t , they become 2 00 dTLSTTSm dx ??=?? + m (11) 2 00 dmDSmmST dx T? ?=?? + (12) 11 11 1 11 (,) [(,) ] (1... diffusivity approaches unity. So far, there have been many studies[3,8]concerned with the interactive effect between temperature and moisture, experimentally or analytically. However, for the convenience of analysis, most of the analytical investigations...

  16. Determination of moisture in solids using high frequency methods

    E-Print Network [OSTI]

    Burton, Melven Boyd

    1953-01-01T23:59:59.000Z

    ~, An induction-Ccpacit Oscillator of Unusual Fre uenc Stabi lit-, Proc ~ I. -". ". , larch, 1948 ~ (14) Glass':one, Samuel, Textbook of Physical Chemistry? D. Tan Nostrand Companv, Ino. , New York, 1947 pp 417 (15) Ibid, pp, 333 ... and low melting solids ~ . '. :eascrement of a change in a physical consL'ant ro deucrcc ne moisture content is incorporated in many methods' The chango in dielectric constant has been used with some success (0, 7 ' 8), 'cut s. "a' n it has boon more...

  17. Synthesis, structure and chemical bonding of CaFe{sub 2?x}Rh{sub x}Si{sub 2} (x=0, 1.32, and 2) and SrCo{sub 2}Si{sub 2}

    SciTech Connect (OSTI)

    Hlukhyy, Viktor, E-mail: viktor.hlukhyy@lrz.tu-muenchen.de; Hoffmann, Andrea V.; Fässler, Thomas F.

    2013-07-15T23:59:59.000Z

    The finding of superconductivity in Ba{sub 0.6}K{sub 0.4}Fe{sub 2}As{sub 2} put the attention on the investigation of compounds that crystallize with ThCr{sub 2}Si{sub 2} structure type such as AT{sub 2}X{sub 2} (A=alkali/alkaline earth/rare earth element; T=transition metal and X=element of the 13–15th group). In this context the silicides CaFe{sub 2}Si{sub 2}, CaFe{sub 0.68(6)}Rh{sub 1.32(6)}Si{sub 2}, CaRh{sub 2}Si{sub 2} and SrCo{sub 2}Si{sub 2} have been synthesized by reaction of the elements under an argon atmosphere. Single crystals were obtained by special heat treatment in welded niobium/tantalum ampoules. The compounds were investigated by means of powder and single crystal X-ray diffraction. All compounds crystallize in the ThCr{sub 2}Si{sub 2}-type structure with space group I4/mmm (No. 139): a=3.939(1) Å, c=10.185(1) Å, R{sub 1}=0.045, 85 F{sup 2} values, 8 variable parameters for CaFe{sub 2}Si{sub 2}; a=4.0590(2) Å, c=9.9390(8) Å, R{sub 1}=0.030, 90 F{sup 2} values, 10 variable parameters for CaFe{sub 0.68(6)}Rh{sub 1.32(6)}Si{sub 2}; a=4.0695(1) Å, c=9.9841(3) Å, R{sub 1}=0.031, 114 F{sup 2} values, 9 variable parameters for CaRh{sub 2}Si{sub 2}; and a=3.974(1) Å, c=10.395(1) Å, R{sub 1}=0.036, 95 F{sup 2} values, 8 variable parameters for SrCo{sub 2}Si{sub 2}. The structure of SrCo{sub 2}Si{sub 2} contains isolated [Co{sub 2}Si{sub 2}]{sup 2?} 2D-layers in the ab-plane whereas in CaFe{sub 2?x}Rh{sub x}Si{sub 2} the [T{sub 2}Si{sub 2}] layers (T=Fe and Rh) are interconnected along the c-axis via Si3Si bonds resulting in a three-dimentional (3D) [T{sub 2}Si{sub 2}]{sup 2?} polyanions and therefore belong to the so-called collapsed form of the ThCr{sub 2}Si{sub 2}-type structure. The SrCo{sub 2}Si{sub 2} and CaRh{sub 2}Si{sub 2} are isoelectronic to the parent 122 iron–pnictide superconductors AeFe{sub 2}As{sub 2} (Ae=alkaline earth elements), whereas CaFe{sub 2}Si{sub 2} is a full substituted variant (As/Si) of CaFe{sub 2}As{sub 2}. The crystal chemistry and chemical bonding in the title compounds are discussed in terms of LMTO band structure calculations and a topological analysis using the Electron Localization Function (ELF). - Graphical abstract: The SrCo{sub 2}Si{sub 2} and CaFe{sub 2?x}Rh{sub x}Si{sub 2} (x==0, 1.32, and 2) crystallize in the ThCr{sub 2}Si{sub 2}-type. The structure of SrCo{sub 2}Si{sub 2} contains isolated [Co{sub 2}Si{sub 2}]{sup 2?} layers in the ab-plane, whereas the [T{sub 2}Si{sub 2}] layers in CaFe{sub 2?x}Rh{sub x}Si{sub 2} are interconnected along the c-axis via Si3Si bonds resulting in a [T{sub 2}Si{sub 2}]{sup 2?} network. - Highlights: • Synthesis and structure of ternary silicides SrCo{sub 2}Si{sub 2} and CaFe{sub 2?x}Rh{sub x}Si{sub 2} (x=0, 1.32, and 2). • The SrCo{sub 2}Si{sub 2} and CaRh{sub 2}Si{sub 2} are isoelectronic to the parent 122 iron–pnictide superconductors AeFe{sub 2}As{sub 2}. • CaFe{sub 2}Si{sub 2} is a full substituted variant (As/Si) of superconductor CaFe{sub 2}As{sub 2}. • The title compounds demonstrate the tunable Si3Si distances.

  18. Production of High Quality Dust Control Foam to Minimize Moisture Addition to Coal

    E-Print Network [OSTI]

    Termine, F.; Jordan, S. T.

    PRODUCTION OF HIGH QUALITY DUST CONTROL FOAM TO MINIMIZE MOISTURE ADDITION TO COAL Frank Tenni ne Steve T. Jordan BETZ Laboratories, Trevose, PA Inc. ABSTRACT Foam is displacing wet suppression as the method of choice for controlling... fugitive emissions from coal. Coal treated by wet suppression consumes through moisture addition, a heat energy equivalent of 1 ton out of every 500 tons fired. The application of foam requires less than 10% of the moisture usually required for wet...

  19. A study of the troxler nuclear soil density and moisture gauges

    E-Print Network [OSTI]

    Friedenwald, Robert Lane

    1963-01-01T23:59:59.000Z

    Be 60 source was used in moisture determinations and a Co source in density measurements. Average deviations of 0. 8 pounds of water per cubic foot of soil were reported for moisture measurements. Density measurements varied by 3 pounds per cubic... foot. It was found that moisture readings may be affected by chemically bound water but for mineral soils, soil type generally has little effect on the calibration of these instruments. Goldberg et al (15) in 1955 constructed a sensitive, r liable...

  20. Mid- and Far-Infrared Reflection/Absorption Spectroscopy (IRAS) Studies of NO on Rh Single Crystal Surfaces

    SciTech Connect (OSTI)

    Peden, Charles HF; He, Ting; Pilling, M.; Hirschmugl, Carol J.; Gardner, P.

    2001-02-01T23:59:59.000Z

    The NO/CO reaction over Rh metal in automobile catalytic converters is critical to the control of emissions of these pollutant molecules. As part of a program to determine the elementary mechanism(s) of this reaction, we have been performing mid- and far-infrared reflection/absorption spectroscopic (IRAS) measurements of the adsorption and co-adsorption and co-adsorption of NO and CO on Rh single crystal surfaces. Of particular interest is the low-frequency range of the IRAS spectra where we hoped to observe features due to metal-N stretching and/or bending vibrational motions. In particular, we hoped to obtain information regarding the site-requirements for the dissociation of the NO molecule on various Rh single crystal surfaces. An important result from our earlier work is that the selectivity of the reaction for the two nitrogen-containing products, N2 and N2O, is a strong function of the Rh surface structure. On the basis of ancillary data, we suggested that the location of adsorbed NO and N-atoms (formed from dissociation of adsorbed NO) on various Rh surfaces could, perhaps account for the selectivity differences.

  1. The influence of nano-architectured CeOx supports in RhPd/CeO? for the catalytic ethanol steam reforming reaction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Divins, N. J.; Senanayake, S. D.; Casanovas, A.; Xu, W.; Trovarelli, A.; Llorca, J.

    2015-09-01T23:59:59.000Z

    The ethanol steam reforming (ESR) reaction has been tested over RhPd supported on polycrystalline ceria in comparison to structured supports composed of nanoshaped CeO? cubes and CeO? rods tailored towards the production of hydrogen. At 650-700 K the hydrogen yield follows the trend RhPd/CeO?-cubes > RhPd/CeO? -rods > RhPd/CeO?- polycrystalline, whereas at temperatures higher than 800 K the catalytic performance of all samples is similar and close to the thermodynamic equilibrium. The improved performance of RhPd/CeO?-cubes and RhPd/CeO? -rods for ESR at low temperature is mainly ascribed to higher water-gas shift activity and a strong interaction between the bimetallic -more »oxide support interaction. STEM analysis shows the existence of RhPd alloyed nanoparticles in all samples, with no apparent relationship between ESR performance and RhPd particle size. X-ray diffraction under operating conditions shows metal reorganization on {100} and {110} ceria crystallographic planes during catalyst activation and ESR, but not on {111} ceria crystallographic planes. The RhPd reconstructing and tuned activation over ceria nanocubes and nanorods is considered the main reason for better catalytic activity with respect to conventional catalysts based on polycrystalline ceria« less

  2. Dendrimer Templated Synthesis of One Nanometer Rh and Pt Particles Supported on Mesoporous Silica: Catalytic Activity for Ethylene and Pyrrole Hydrogenation.

    E-Print Network [OSTI]

    Huang, Wenyu

    2009-01-01T23:59:59.000Z

    Scheme 2) and pyrrole hydrogenation (Scheme 3). Synthesis ofSynthesis of One Nanometer Rh and Pt Particles Supported on Mesoporous Silica: Catalytic Activity for Ethylene and Pyrrole

  3. Advanced MR moisture sensor market feasibility analysis. Executive summary

    SciTech Connect (OSTI)

    NONE

    1995-02-01T23:59:59.000Z

    This paper briefly documents activities, background information, and results of marketing studies on the Magnetic Resonance Advanced Moisture Sensor (AMS). The main goals of the study are to identify industrial uses to guide development efforts, to become familiar with the industrial and magnetic resonance research capabilities/resources at the Southwest Research Institute (SwRI), and to develop a summary data sheet describing the AMS product for use with a broad mail survey of potential users. The studies are being performed through an alliance of Quantum Magnetics, US DOE, SwRI, The Townsend Agency, and PAI Partners. Efforts are being focused on NIR, Raman, and other optical spectroscopies as process measurement tools for onstream applications. Domestic and world markets for process analytical instrumentation, process moisture instrumentation, and nuclear magnetic resonance instrumentation are summarized. Three applications are identified as the most promising for magnetic resonance instrumentation: (1) polymer production, (2) pharmaceuticals preparation, and (3) prepared food processing. It is estimated that the process magnetic resonance market could reach $5 to $10 million annually by the end of this decade.

  4. Temperature and moisture dependence of dielectric constant for silica aerogels

    SciTech Connect (OSTI)

    Hrubesh, L.H., LLNL

    1997-03-01T23:59:59.000Z

    The dielectric constants of silica aerogels are among the lowest measured for any solid material. The silica aerogels also exhibit low thermal expansion and are thermally stable to temperatures exceeding 500{degrees}C. However, due to the open porosity and large surface areas for aerogels, their dielectric constants are strongly affected by moisture and temperature. This paper presents data for the dielectric constants of silica aerogels as a function of moisture content at 25{degrees}C, and as a function of temperature, for temperatures in the range from 25{degrees}C to 450{degrees}C. Dielectric constant data are also given for silica aerogels that are heat treated in dry nitrogen at 500{degrees}C, then cooled to 25{degrees}C for measurements in dry air. All measurements are made on bulk aerogel spheres at 22GHz microwave frequency, using a cavity perturbation method. The results of the dependence found here for bulk materials can be inferred to apply also to thin films of silica aerogels having similar nano-structures and densities.

  5. Exchange interaction in hexagonal MnRhP from first-principles studies

    SciTech Connect (OSTI)

    Liu, X. B., E-mail: liuxubo@uta.edu; Zhang, Qiming; Ping Liu, J., E-mail: pliu@uta.edu [Department of Physics, University of Texas at Arlington, Arlington, Texas 76019 (United States); Yue, M. [College of Material Science and Engineering, Beijing University of Technology, 100022 Beijing (China); Altounian, Z. [Centre for the Physics of Materials and Department of Physics, McGill University, Montreal, Quebec H3A 2T8 (Canada)

    2014-05-07T23:59:59.000Z

    Electronic structure and magnetic properties for MnRhP have been studied from a first-principles density functional calculation. The calculated lattice constants, a?=?6.228 Å and c?=?3.571?Å, are in good agreement with the experimental values of a?=?6.223 Å and c?=?3.585?Å. The calculated moment of Mn is 3.1 ?{sub B}/atom, resulting in a total moment of 3.0 ?{sub B}/atom due to small moments induced at Rh and P sites. The magnetic moment of Mn decreases with unit cell size. The exchange interactions are dominated by positive Mn-Mn exchange coupling (J{sub Mn?Mn}), implying a stable ferromagnetic ordering in Mn sublattice. In particular, J{sub Mn?Mn} shows a maximum value (1.5 mRy) at the the optimized unit cell size. The structural distortion or unit cell size change will affect J{sub Mn?Mn}, which is intimately related to the magneto-elastic and magneto-caloric effect.

  6. Atmospheric optical calibration system

    DOE Patents [OSTI]

    Hulstrom, Roland L. (Bloomfield, CO); Cannon, Theodore W. (Golden, CO)

    1988-01-01T23:59:59.000Z

    An atmospheric optical calibration system is provided to compare actual atmospheric optical conditions to standard atmospheric optical conditions on the basis of aerosol optical depth, relative air mass, and diffuse horizontal skylight to global horizontal photon flux ratio. An indicator can show the extent to which the actual conditions vary from standard conditions. Aerosol scattering and absorption properties, diffuse horizontal skylight to global horizontal photon flux ratio, and precipitable water vapor determined on a real-time basis for optical and pressure measurements are also used to generate a computer spectral model and for correcting actual performance response of a photovoltaic device to standard atmospheric optical condition response on a real-time basis as the device is being tested in actual outdoor conditions.

  7. Atmospheric optical calibration system

    DOE Patents [OSTI]

    Hulstrom, R.L.; Cannon, T.W.

    1988-10-25T23:59:59.000Z

    An atmospheric optical calibration system is provided to compare actual atmospheric optical conditions to standard atmospheric optical conditions on the basis of aerosol optical depth, relative air mass, and diffuse horizontal skylight to global horizontal photon flux ratio. An indicator can show the extent to which the actual conditions vary from standard conditions. Aerosol scattering and absorption properties, diffuse horizontal skylight to global horizontal photon flux ratio, and precipitable water vapor determined on a real-time basis for optical and pressure measurements are also used to generate a computer spectral model and for correcting actual performance response of a photovoltaic device to standard atmospheric optical condition response on a real-time basis as the device is being tested in actual outdoor conditions. 7 figs.

  8. Atmospheric Science: An introductory survey 1. Introduction to the atmosphere

    E-Print Network [OSTI]

    Folkins, Ian

    Sound Convergence Zone #12;Terrain effects #12;Von Karman vortex streets #12;Atmosphere in Earth system

  9. Peel and Shear Fracture Characterization of Debonding in FRP Plated Concrete Affected by Moisture

    E-Print Network [OSTI]

    Entekhabi, Dara

    polymer CFRP plated concrete systems by mechanically testing accelerated moisture conditioned mesoscalePeel and Shear Fracture Characterization of Debonding in FRP Plated Concrete Affected by Moisture fracture toughness as the quantification parameter of the CFRP-epoxy-concrete trilayer system, which

  10. Monitoring Soil Moisture and Drought Using a Thermal TwoSource Energy Balance Model

    E-Print Network [OSTI]

    Kuligowski, Bob

    Monitoring Soil Moisture and Drought Using a Thermal TwoSource Energy Balance Model Christopher. In general, dry soil or stressed vegetation heats up more rapidly than wet soil or unstressed vegetation, using one dual polarized channel (either Cband or Xband) for the retrieval of soil moisture

  11. Using moisture transport properties of rice seed components for identifying fissure resistance

    E-Print Network [OSTI]

    Thomas, Audrey Elizabeth

    2002-01-01T23:59:59.000Z

    , LaGrue, Lemont, and Cypress. Equilibrium moisture content (EMC) tests exposed 200 grams of brown rice to identify how the four varieties compare in their ability to hold moisture at a specific condition. Cypress, Lemont, and LaGrue tended to hold...

  12. SOIL MOISTURE RETENTION CHARACTERISTICS AT RD 838 OF I. G. N. P. STAGE -II

    E-Print Network [OSTI]

    Kumar, C.P.

    aquifers. For analytical studies on soil moisture regime, critical review and accurate assessment among soil moisture characteristic curves are attributed primarily to the differences in pore size structures. In addition, the curves generally show hysteresis according to the wetting or drying of soils

  13. NEC Hazardous classification and compliance regarding the surface moisture monitor measurement system

    SciTech Connect (OSTI)

    Bussell, J.H., WHC

    1996-06-12T23:59:59.000Z

    The National Electrical Code, NFPA 70, and National Fire Protection Association requirements for use of Surface Moisture Monitor Systems in classified locations are discussed. The design and configuration of the surface moisture monitor are analyzed with respect to how they comply with requirements of the National Electrical Code requirements, articles 500-504.

  14. SOIL MOISTURE CHARACTERIZATION USING MULTI-ANGULAR POLARIMETRIC RADARSAT-2 DATASETS

    E-Print Network [OSTI]

    Boyer, Edmond

    SOIL MOISTURE CHARACTERIZATION USING MULTI-ANGULAR POLARIMETRIC RADARSAT-2 DATASETS Hongquan Wang to be a solution to improve the effectiveness of bare soil char- acterization. However, the potential single and multiple incidence angle acquisitions is investigated against in situ soil moisture

  15. Dynamic Effects on Moisture Transport in Asphalt Concrete M. Emin Kutay1

    E-Print Network [OSTI]

    Aydilek, Ahmet

    Dynamic Effects on Moisture Transport in Asphalt Concrete M. Emin Kutay1 and Ahmet H. Aydilek2 2007 133:7 406 CE Database subject headings: Moisture; Asphalt concrete; Dynamics; Hydraulic and Magdalena 2002 ; however, limited research has been conducted in modeling dynamic flow in porous geomedia

  16. Importance of moisture transport, snow cover and soil freezing to ground temperature predictions

    E-Print Network [OSTI]

    Importance of moisture transport, snow cover and soil freezing to ground temperature predictions moisture transport, snow accumulation and melting, and soil freezing and thawing are investigated transport, snow cover, and soil freezing. 1. Introduction Prediction of ground temperature is an important

  17. Optimization of stomatal conductance for maximum carbon gain under dynamic soil moisture

    E-Print Network [OSTI]

    Katul, Gabriel

    Optimization of stomatal conductance for maximum carbon gain under dynamic soil moisture Stefano Accepted 26 September 2013 Available online 9 October 2013 Keywords: Optimization Photosynthesis Soil moisture Stomatal conductance Transpiration a b s t r a c t Optimization theories explain a variety

  18. ''Nuclear Winter'': A diagnosis of atmospheric general circulation model simulations

    SciTech Connect (OSTI)

    Covey, C.; Thompson, S.L.; Schneider, S.H.

    1985-06-20T23:59:59.000Z

    We investigate the adiabatic and diabatic thermal balance of an atmospheric general circulation model (GCM) under two conditions: the control case, representing today's atmosphere, and a ''nuclear winter'' scenario in which virtually all sunlight in northern hemisphere and mid-latitudes is absorbed in the upper troposphere by prescribed dense smoke clouds hypothesized to result from the burning of many cities in a nuclear war. We also examine the changes in moisture and cloudiness simulated by the model. Our object is to examine the reliability of existing simulations of the climatic response to assumed dense, widespread, high-altitude smoke and to identify improvements needed in model parameterizations. We find that in the smoke-perturbed case our model simulation of land surface temperature is particularly influenced (i.e., warmed) by parameterized diffusion of heat downward from the lower troposphere. In turn the lower troposphere over land is supplied with heat transported from the relatively warm oceans. Thermal balance in the perturbed atmosphere as a whole is dominated by intense solar heating of the upper troposphere smoke layer in mid-latitudes balanced by parameterized dry convection and large-scale dynamical heat transport. Clouds largely disappear in the mid to upper troposphere in smoke-affected regions as a consequence of a decrease in local relative humidity that results from temperature increases and, to a smaller extent, from a reduction of vertical moisture transport. The computation of substantial downward vertical heat diffusion into the lowest model layer is almost certainly an overestimate for the smoke-perturbed conditions of high vertical stability.

  19. Synthesis and thermoelectric properties of Ce(Ru0.67Rh0.33)4Sb12. Geoff D. Staneff1

    E-Print Network [OSTI]

    Asimow, Paul D.

    Synthesis and thermoelectric properties of Ce(Ru0.67Rh0.33)4Sb12. Geoff D. Staneff1 , Paul D compositions show promise for thermoelectric applications. Current work was undertaken with a nominal composition of Ce(Ru0.67Rh0.33)4Sb12 to experimentally verify its potential as an n-type thermoelectric

  20. Method and apparatus for fuel gas moisturization and heating

    DOE Patents [OSTI]

    Ranasinghe, Jatila (Niskayuna, NY); Smith, Raub Warfield (Ballston Lake, NY)

    2002-01-01T23:59:59.000Z

    Fuel gas is saturated with water heated with a heat recovery steam generator heat source. The heat source is preferably a water heating section downstream of the lower pressure evaporator to provide better temperature matching between the hot and cold heat exchange streams in that portion of the heat recovery steam generator. The increased gas mass flow due to the addition of moisture results in increased power output from the gas and steam turbines. Fuel gas saturation is followed by superheating the fuel, preferably with bottom cycle heat sources, resulting in a larger thermal efficiency gain compared to current fuel heating methods. There is a gain in power output compared to no fuel heating, even when heating the fuel to above the LP steam temperature.

  1. Moisture corrections in neutron coincidence counting of PuO/sub 2/

    SciTech Connect (OSTI)

    Stewart, J.E.; Menlove, H.O.

    1987-01-01T23:59:59.000Z

    Passive neutron coincidence counting is capable of 1% assay accuracy for pure, well-characterized PuO/sub 2/ samples that contain plutonium masses from a few tens of grams to several kilograms. Moisture in the sample can significantly bias the assay high by changing the (..cap alpha..,n) neutron production, the sample multiplication, and the detection efficiency. Monte Carlo calculations and an analytical model of coincidence counting have been used to quantify the individual and cumulative effects of moisture biases for two PuO/sub 2/ sample sizes and a range of moisture levels from 0 to 9 wt %. Results of the calculations suggest a simple correction procedure for moisture bias that is effective from 0 to 3 wt % H/sub 2/O. The procedure requires that the moisture level in the sample be known before the coincidence measurement.

  2. Synthesis and thermoelectric properties of the novel A-site deficient Zn{sub 0.5}Rh{sub 2}O{sub 4} compound

    SciTech Connect (OSTI)

    Nakamura, Yuta [Interdisciplinary Graduate School of Medicine and Engineering, University of Yamanashi, 4-3-11 Takeda, Kofu, Yamanashi 400-8511 (Japan); Kakemoto, Hirofumi [Clean Energy Research Center, University of Yamanashi, 4-3-11 Takeda, Kofu, Yamanashi 400-8511 (Japan); Nishiyama, Shin [Graduate School of Engineering, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba, Chiba 263-8522 (Japan); Irie, Hiroshi, E-mail: hirie@yamanashi.ac.jp [Clean Energy Research Center, University of Yamanashi, 4-3-11 Takeda, Kofu, Yamanashi 400-8511 (Japan)

    2012-08-15T23:59:59.000Z

    A novel thermoelectric material, A-site-deficient spinel Zn{sub 0.5}Rh{sub 2}O{sub 4}, was prepared by subtracting Li ions from Li{sub 0.5}Zn{sub 0.5}Rh{sub 2}O{sub 4} immersed in a K{sub 2}S{sub 2}O{sub 8} aqueous solution. The electric conductivity ({sigma}) increased 6-fold after extracting Li ({sigma}=8.8 S/cm (Li{sub 0.5}Zn{sub 0.5}Rh{sub 2}O{sub 4}), 50 S/cm (Zn{sub 0.5}Rh{sub 2}O{sub 4}) at 600 Degree-Sign C), whereas the Seebeck coefficient (S) only slightly increased (S=203 {mu}V/K (Li{sub 0.5}Zn{sub 0.5}Rh{sub 2}O{sub 4}), 216 {mu}V/K (Zn{sub 0.5}Rh{sub 2}O{sub 4}) at 600 Degree-Sign C). In Zn{sub 0.5}Rh{sub 2}O{sub 4}, a mixed-valence configuration of Rh{sup 3+} and Rh{sup 4+} at a ratio of 1 to 1 and a half-deficient A-site were realized, resulting in high {sigma} and even slightly increased S, which were likely attributed to the rather high power factor of 2.3 Multiplication-Sign 10{sup -4} W/m K{sup 2} at 600 Degree-Sign C. Our findings demonstrate that controlling the Rh{sup 4+}/Rh{sup 3+} ratio is a promising method for enhancing the thermoelectric properties. - Graphical abstract: Temperature dependence of power factor (PF) of Li{sub 0.5}Zn{sub 0.5}Rh{sub 2}O{sub 4}, Li{sub 0.25}Zn{sub 0.5}Rh{sub 2}O{sub 4}, and Zn{sub 0.5}Rh{sub 2}O{sub 4} thin films. Highlights: Black-Right-Pointing-Pointer A-site-deficient Zn{sub 0.5}Rh{sub 2}O{sub 4} was prepared by subtracting Li from Li{sub 0.5}Zn{sub 0.5}Rh{sub 2}O{sub 4}. Black-Right-Pointing-Pointer A mixed-valence configuration with a Rh{sup 4+}/Rh{sup 3+} ratio of 1 was likely realized. Black-Right-Pointing-Pointer Such a configuration lead to an enhanced {sigma} of 50S/cm and S of 216 {mu}V/K at 600 Degree-Sign C. Black-Right-Pointing-Pointer Controlling the Rh{sup 4+}/Rh{sup 3+} ratio is a candidate for enhancing the thermoelectricity.

  3. GnRH-induced LH release in heifers: effect of nutrient restriction during gestation

    E-Print Network [OSTI]

    Killen, James Harold

    1983-01-01T23:59:59.000Z

    OF GESTATION Seasonal r SG2 Variabl m SE mean CS 32 31 a 3 2 a 5. 6 28. 95 1. 15 b 26 2. 9 ~ 1 b 26 4 ' 9 . 1 a 21 17. 97 1. 48 SGwhei fera in SGI entered the study on or before June 8, 1981 and heifer s in SG2 entered the study on or after... SG2 a iable an SE n m SE LHPK LHCX LHlf 12 12 48. 92 13. 89 86. 86 22. 52 21. 98 5. 75 18 49. 94 14. 34 ie 94. 78 18 24 ~ 21 6. 38 LHPmpeak LH response to GnRH&ngr'm1) ~ LHC=area under the LH response curve in units. L~ean LH r esponse...

  4. Dynamic Analysis of Moisture Transport Through Walls and Associated Cooling Loads in the Hot/Humid Climate of Florianopolis, Brazil 

    E-Print Network [OSTI]

    Mendes, N.; Winkelmann, F. C.; Lamberts, R.; Philippi, P. C.; Da Cunha, Neto, J. A. B.

    1996-01-01T23:59:59.000Z

    . The simulation results were compared to those obtained by pure conduction heat transfer without moisture effects. Also analyzed were the influence on cooling loads of high moisture content due to rain soaking of materials. and the influence of solar radiation...

  5. Energetics of C-H Bond Activation of Fluorinated Aromatic Hydrocarbons Using a [TpRh(CNneopentyl)] Complex

    E-Print Network [OSTI]

    Jones, William D.

    Energetics of C-H Bond Activation of Fluorinated Aromatic Hydrocarbons Using a [Tp activation of fluorinated aromatic hydrocarbons by [TpRh(CNneopentyl)] resulted in the formation of products of homogeneous transition-metal catalysts to activate and functionalize C-H bonds of hydrocarbons for industrial

  6. RH-TRU Waste Shipments from Battelle Columbus Laboratories to the Hanford Nuclear Facility for Interim Storage

    SciTech Connect (OSTI)

    Eide, J.; Baillieul, T. A.; Biedscheid, J.; Forrester, T,; McMillan, B.; Shrader, T.; Richterich, L.

    2003-02-26T23:59:59.000Z

    Battelle Columbus Laboratories (BCL), located in Columbus, Ohio, must complete decontamination and decommissioning (D&D) activities for nuclear research buildings and grounds by 2006, as directed by Congress. Most of the resulting waste (approximately 27 cubic meters [m3]) is remote-handled (RH) transuranic (TRU) waste destined for disposal at the Waste Isolation Pilot Plant (WIPP). The BCL, under a contract to the U.S. Department of Energy (DOE) Ohio Field Office, has initiated a plan to ship the TRU waste to the DOE Hanford Nuclear Facility (Hanford) for interim storage pending the authorization of WIPP for the permanent disposal of RH-TRU waste. The first of the BCL RH-TRU waste shipments was successfully completed on December 18, 2002. This BCL shipment of one fully loaded 10-160B Cask was the first shipment of RH-TRU waste in several years. Its successful completion required a complex effort entailing coordination between different contractors and federal agencies to establish necessary supporting agreements. This paper discusses the agreements and funding mechanisms used in support of the BCL shipments of TRU waste to Hanford for interim storage. In addition, this paper presents a summary of the efforts completed to demonstrate the effectiveness of the 10-160B Cask system. Lessons learned during this process are discussed and may be applicable to other TRU waste site shipment plans.

  7. ETME 422 -REFRIGERATION & HVAC SYSTEMS FALL 2011 LEC -10:00 -10:50am M W F RH 312

    E-Print Network [OSTI]

    Dyer, Bill

    10/31/2011 ETME 422 - REFRIGERATION & HVAC SYSTEMS FALL 2011 LEC - 10:00 - 10:50am M W F RH 312. -- Refrigeration and heating, ventilating and air-conditioning (HVAC) for comfort and industrial applications, low temperature refrigeration cycles; air distribution and fan-duct analysis, design/selection of HVAC

  8. Ternary PtSnRhSnO2 nanoclusters: synthesis and electroactivity for ethanol oxidation fuel cell reaction

    E-Print Network [OSTI]

    Frenkel, Anatoly

    Ternary PtSnRh­SnO2 nanoclusters: synthesis and electroactivity for ethanol oxidation fuel cell. Ethanol becomes an attractive fuel in the fuel cell reactions compared with methanol and hydrogen, because­4 A major impediment to the commercialization of ethanol fuel cell stacks is the difficulty in designing

  9. Investigation of the Mechanism of Alkane Reductive Elimination and Skeletal Isomerization in TpRh(CNneopentyl)(R)H Complexes: The

    E-Print Network [OSTI]

    Jones, William D.

    metal deuteride complexes, TpRh- (L)(R)D, and the scrambling of the deuterium label into the R elimination are shown to be the result of an inverse equilibrium isotope effect between the alkyl hydride(deuteride exchange between a metal deuteride complex and its alkyl ligands prior to reductive elimination,7

  10. Catalytic conversion of syngas into C2 oxygenates over Rh-based catalysts--Effect of carbon supports

    E-Print Network [OSTI]

    Bao, Xinhe

    Catalytic conversion of syngas into C2 oxygenates over Rh-based catalysts--Effect of carbon synthesis other than grain fermentation, e.g. from syngas, because syngas can be conveniently manufactured we first undertake a brief overview of the catalyst development for syngas conversion to C2

  11. EXPERIENCE FROM TWO SMALL QUANTITY RH-TRU WASTE SITES IN NAVIGATING THROUGH AN EVOLVING REGULATORY LANDSCAPE

    SciTech Connect (OSTI)

    Biedscheid, Jennifer; Devarakonda, Murthy; Eide, Jim; Kneff, Dennis

    2003-02-27T23:59:59.000Z

    Two small quantity transuranic (TRU) waste generator sites have gained considerable experience in navigating through a changing regulatory landscape in their efforts to remove the TRU waste from their sites and proceed with site remediation. The Battelle Columbus Laboratories Decommissioning Project (BCLDP) has the objectives of decontaminating nuclear research buildings and associated grounds and remediating to a level of residual contamination allowing future use without radiological restrictions. As directed by Congress, BCLDP must complete decontamination and decommissioning activities by the end of Fiscal Year (FY) 2006. This schedule requires the containerization of all TRU waste in 2002. BCLDP will generate a total of approximately 27 cubic meters (m3) of remote-handled (RH) TRU waste. Similarly, the Energy Technology Engineering Center (ETEC) is scheduled to close in 2006 pursuant to an agreement between the U.S. Department of Energy (DOE) and Boeing Canoga Park, the management and operating contractor for ETEC. ETEC had 11.0 m3 of RH-TRU and contact-handled (CH) TRU waste in storage, with the requirement to remove this waste in 2002 in order to meet their site closure schedule. The individual milestones for BCLDP and ETEC necessitated the establishment of site-specific programs to direct packaging and characterization of RH-TRU waste before the regulatory framework for the WIPP disposal of RH-TRU waste is finalized. The lack of large infrastructure for characterization activities, as well as the expedited schedules needed to meet regulatory milestones, provided both challenges and opportunities that are unique to small quantity sites. Both sites have developed unique programs for waste characterization based on the same premise, which directs comprehensive waste data collection efforts such that additional characterization will not be required following the finalization of the WIPP RH-TRU waste program requirements. This paper details the BCLDP program evolution in terms of strategy, innovative solutions to waste characterization, and development of alternative transportation options. Preliminary indications from various regulatory and oversight agencies and professional organizations are that the BCLDP RH-TRU waste characterization program is the ''model WIPP certification program'' and will satisfy anticipated regulatory expectations. This paper also summarizes how BCLDP lessons learned and their development of new resources were applied to the RH-TRU waste characterization and disposition program at ETEC.

  12. Caribbean and Pacific moisture sources on the Isthmus of Panama revealed from stalagmite and surface water d18

    E-Print Network [OSTI]

    Asmerom, Yemane

    Caribbean and Pacific moisture sources on the Isthmus of Panama revealed from stalagmite values from Panama and Costa Rica. The d18 O values decrease with distance from the Caribbean Sea a contribution of both Caribbean and Pacific sourced moisture to the isthmus. We estimated the Pacific moisture

  13. Recent Advances in Profile Soil Moisture Retrieval Jeffrey P. Walker, Garry R. Willgoose and Jetse D. Kalma

    E-Print Network [OSTI]

    Walker, Jeff

    and agriculture. The significance of soil moisture is its role in the partitioning of energy at the ground surface for hydrologic, climatic and agricultural studies, such observations of surface soil moisture must be related to accept remote sensing data as input to track soil moisture status in time. As surface observations

  14. Dynamics of Atmospheres

    E-Print Network [OSTI]

    Read, Peter L.

    transfer ­ Solar heating of surface, and atmosphere via dust absorption ­ Infrared CO2 band cooling (especially around 667 cm-1) ­ nonLTE near-infrared heating of CO2 and nonLTE cooling effects above ~60-80 km. Baroclinic waves, scales, heat and momentum transport, seasonal occurrence. Qualitative treatment

  15. Laboratory for Atmospheric and

    E-Print Network [OSTI]

    Mojzsis, Stephen J.

    . Along with this growth came a new building on campus and a new name: the Laboratory for Atmospheric of the Sun to the outermost fringes of the solar system. With LASP's continuing operations role in the planet traditional and stable approach based on federal agency funding of research grant

  16. Development of the prototype Munitions Case Moisture Meter, Model ORNL-1. Final report

    SciTech Connect (OSTI)

    Agouridis, D.C.; Gayle, T.M.; Griest, W.H.

    1993-02-24T23:59:59.000Z

    There is a great need for a rapid and simple means of determining the moisture content in combustible cartridge case (ccc) munitions. Previous studies have demonstrated that accumulation of moisture in ccc rounds, such as the M829, leads to softening of the case wall and weakening of the adhesive joint. Moisture in the ccc can lead to incomplete combustion of the case upon firing the round. Currently, there are no facile methods for measuring the moisture content. A prototype portable meter for non-destructive and rapid estimation of moisture in ccc has been developed. The Munitions Case Moisture Meter Model ORNL-1 demonstrates the feasibility of developing an instrument based on the moisture dependence of dielectric properties, to measure moisture in ccc munitions in storage and in the field. These instruments are simple, inexpensive, lightweight, portable, low-power battery operated, and intrinsically safe. They provide nondestructive, noninvasive, and rapid measurements. Calibration data for the prototype are not available at this time. Therefore, calibration of the meter and the development of a scale reading directly moisture content in munitions rounds could not be completed. These data will be supplied by the US Army from its tests of the meter with actual munitions. However, experimental results on empty cccs in laboratory conditions demonstrate satisfactory performance of the instrument. Additional work is needed to bring the prototype to its optimum usefulness and accuracy for field measurements. This includes: Calibration of the meter scale with full-up munitions; Data and evaluation procedures to adjust the performance of the meter for different environmental conditions such as temperature and humidity; and Studies of the dielectric properties of moist ccc materials, as a function of frequency and temperature, are needed for adjustment of the meter for optimal performance.

  17. Development of the prototype Munitions Case Moisture Meter, Model ORNL-1

    SciTech Connect (OSTI)

    Agouridis, D.C.; Gayle, T.M.; Griest, W.H.

    1993-02-24T23:59:59.000Z

    There is a great need for a rapid and simple means of determining the moisture content in combustible cartridge case (ccc) munitions. Previous studies have demonstrated that accumulation of moisture in ccc rounds, such as the M829, leads to softening of the case wall and weakening of the adhesive joint. Moisture in the ccc can lead to incomplete combustion of the case upon firing the round. Currently, there are no facile methods for measuring the moisture content. A prototype portable meter for non-destructive and rapid estimation of moisture in ccc has been developed. The Munitions Case Moisture Meter Model ORNL-1 demonstrates the feasibility of developing an instrument based on the moisture dependence of dielectric properties, to measure moisture in ccc munitions in storage and in the field. These instruments are simple, inexpensive, lightweight, portable, low-power battery operated, and intrinsically safe. They provide nondestructive, noninvasive, and rapid measurements. Calibration data for the prototype are not available at this time. Therefore, calibration of the meter and the development of a scale reading directly moisture content in munitions rounds could not be completed. These data will be supplied by the US Army from its tests of the meter with actual munitions. However, experimental results on empty cccs in laboratory conditions demonstrate satisfactory performance of the instrument. Additional work is needed to bring the prototype to its optimum usefulness and accuracy for field measurements. This includes: Calibration of the meter scale with full-up munitions; Data and evaluation procedures to adjust the performance of the meter for different environmental conditions such as temperature and humidity; and Studies of the dielectric properties of moist ccc materials, as a function of frequency and temperature, are needed for adjustment of the meter for optimal performance.

  18. Isolating Effects of Water Table Dynamics, Terrain, and Soil Moisture Heterogeneity on the Atmospheric Boundary Layer Using Coupled Models

    E-Print Network [OSTI]

    Rihani, Jehan

    2010-01-01T23:59:59.000Z

    boundary conditions of wind, potential temperature, andvariables such as winds, potential temperature, rainfall,variables such as wind speed, potential temperature, and

  19. Moisture in Molasses as a Factor in the Heating of Feeds.

    E-Print Network [OSTI]

    Halick, John V.; Richardson, L. R.

    1952-01-01T23:59:59.000Z

    sugars after inversion, moisture, Brix and ash. Moist.ure was determined by the vacuum oven drying method and ranged from 19 to over 31 percent. Over 71.0 percent of the samples contained 26 percent or more of lwater. If 10 percent of molasses... in a feed contain a normal amount of water, the extra water added in the molasses might raise the moisture content to an unsafe level. Different values for solids were obtained by the Brix and the vacuum oven drying methods, Brix is an unreliable...

  20. Measurements of Backsheet Moisture Permeation and Encapsulant-Substrate Adhesion: Preprint

    SciTech Connect (OSTI)

    Jorgensen, G.; Terwilliger, K.; Barber, G.; Kennedy, C.; McMahon, T.

    2001-10-01T23:59:59.000Z

    Presented at the 2001 NCPV Program Review Meeting: Measurements of backsheet moisture permeation and encapsulant-substrate adhesion. At the March 2001 NCPV workshop on ''Moisture Ingress and High-Voltage Isolation'', industry participants identified several properties associated with PV module durability that are critical for commercial success. These include interface conductivity, adhesion of encapsulants to substrate materials as a function of in-service exposure conditions, and moisture permeation through backsheet materials as a function of temperature. Electrical data is discussed in a companion paper; adhesion and water vapor transmission rate (WVTR) measurements are presented herein.

  1. Experimental Study of Multi-type Macromolecule Porosity Moisture-Conditioned Material

    E-Print Network [OSTI]

    Huang, X.; Fan, Y.; Di, Y.

    2006-01-01T23:59:59.000Z

    MATERIALS AND EXPERIMENTAL DEVICES 4.1 The Experimental Materials (1) Porous materials: Concrete blocks, weight for 550Kg/m3, pore rate of 73%, saturated humidity rate of 45%, dimensions of 300?600?80mm. (2) Combined with the moisture conditioned... on buildings or wallpaper to adjust humidity. 2) Concrete blocks: 300?600?80mm. (3) Combined with the moisture conditioned plate and porous materials 1) Moisture conditioned plate: Absorbent resin adsorption salt solution, forms a Gel, mixed the Gel...

  2. SIO 217a Atmospheric and Climate Sciences I: Atmospheric Thermodynamics

    E-Print Network [OSTI]

    Russell, Lynn

    SIO 217a Atmospheric and Climate Sciences I: Atmospheric Thermodynamics Course Syllabus and Lecture Schedule Instructor: Lynn Russell, 343 NH, 534-4852, lmrussell@ucsd.edu Text: Thermodynamics of Atmospheres of Thermodynamics (Work, Heat, First Law, Second Law, Heat Capacity, Adiabatic Processes) 5-Oct F Hurricane Example

  3. THREE-MINUTE OSCILLATIONS ABOVE SUNSPOT UMBRA OBSERVED WITH THE SOLAR DYNAMICS OBSERVATORY/ATMOSPHERIC IMAGING ASSEMBLY AND NOBEYAMA RADIOHELIOGRAPH

    SciTech Connect (OSTI)

    Reznikova, V. E.; Shibasaki, K. [Nobeyama Solar Radio Observatory/NAOJ, Nagano 384-1305 (Japan); Sych, R. A. [Key Laboratory of Solar Activity, NAOC, Beijing 100012 (China); Nakariakov, V. M., E-mail: reznik@nro.nao.ac.jp [Physics Department, University of Warwick, Coventry CV4 7AL (United Kingdom)

    2012-02-20T23:59:59.000Z

    Three-minute oscillations over a sunspot's umbra in AR 11131 were observed simultaneously in UV/EUV emission by the Solar Dynamics Observatory (SDO)/Atmospheric Imaging Assembly (AIA) and in radio emission by the Nobeyama Radioheliograph (NoRH). We use 24 hr series of SDO and 8 hr series of NoRH observations to study spectral, spatial, and temporal variations of pulsations in the 5-9 mHz frequency range at different layers of the solar atmosphere. High spatial and temporal resolution of SDO/AIA in combination with long-duration observations allowed us to trace the variations of the cutoff frequency and spectrum of oscillations across the umbra. We found that higher frequency oscillations are more pronounced closer to the umbra's center, while the lower frequencies concentrate on the peripheral parts. We interpreted this discovery as a manifestation of variation of the magnetic field inclination across the umbra at the level of temperature minimum. Possible implications of this interpretation for the diagnostics of sunspot atmospheres are discussed.

  4. Pluto's Atmosphere Does Not Collapse

    E-Print Network [OSTI]

    Olkin, C B; Borncamp, D; Pickles, A; Sicardy, B; Assafin, M; Bianco, F B; Buie, M W; de Oliveira, A Dias; Gillon, M; French, R G; Gomes, A Ramos; Jehin, E; Morales, N; Opitom, C; Ortiz, J L; Maury, A; Norbury, M; Ribas, F B; Smith, R; Wasserman, L H; Young, E F; Zacharias, M; Zacharias, N

    2013-01-01T23:59:59.000Z

    Combining stellar occultation observations probing Pluto's atmosphere from 1988 to 2013 and models of energy balance between Pluto's surface and atmosphere, we conclude that Pluto's atmosphere does not collapse at any point in its 248-year orbit. The occultation results show an increasing atmospheric pressure with time in the current epoch, a trend present only in models with a high thermal inertia and a permanent N2 ice cap at Pluto's north rotational pole.

  5. Structural and magnetic properties in the polymorphs of CeRh{sub 0.5}Ge{sub 1.5}

    SciTech Connect (OSTI)

    Kalsi, Deepti; Subbarao, Udumula [New Chemistry Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore-560064 (India); Rayaprol, Sudhindra [UGC-DAE Consortium for Scientific Research, R-5 Shed, B.A.R.C Campus, Trombay, Mumbai-400085 (India); Peter, Sebastian C., E-mail: sebastiancp@jncasr.ac.in [New Chemistry Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore-560064 (India)

    2014-04-01T23:59:59.000Z

    We investigate the structural and magnetic properties in the polymorphs of a new compound CeRh{sub 0.5}Ge{sub 1.5}. Depending upon the starting materials, and the slightly different synthesis method, we find that CeRh{sub 0.5}Ge{sub 1.5} compound exists in two different space groups. The first compound, ?-CeRh{sub 0.5}Ge{sub 1.5} crystallizes in tetragonal ?-ThSi{sub 2} structure type in space group I4{sub 1}/amd with lattice parameters, a=4.2034(6) Å and c=14.770(3) Å. In this structure, the cerium atoms occupy the position between the Rh/Ge tetrahedral layers. On the other hand, the second compound, namely ?-CeRh{sub 0.5}Ge{sub 1.5} crystallizes in the AlB{sub 2} type hexagonal structure in space group P6/mmm, with lattice parameters, a=4.2615(7) Å and c=4.1813(9) Å. The crystal structure of ?-CeRh{sub 0.5}Ge{sub 1.5} consists of two dimensional Rh/Ge hexagonal units and the cerium atoms are sandwiched between them. Magnetization studies exhibit magnetic ordering, as evident from a sharp peak in the plot of magnetic susceptibility measured as a function of temperature in a fixed magnetic field, in ?-CeRh{sub 0.5}Ge{sub 1.5} and ?-CeRh{sub 0.5}Ge{sub 1.5} at 3.6 K and 12 K, respectively. Structural and magnetic properties of both compounds are presented and discussed here. - Graphical abstract: Two polymorphs of a new compound CeRh{sub 0.5}Ge{sub 1.5} in the ?-ThSi{sub 2} and AlB{sub 2} structure types were synthesized by arc melting. The magnetic measurements of both CeRh{sub 0.5}Ge{sub 1.5} phases suggest spin-glass behavior. - Highlights: • A new compound CeRh{sub 0.5}Ge{sub 1.5} in two difference phases was synthesized by arc melting. • The crystal structure of both compounds was determined from the single crystal XRD. • Isothermal relaxation measurements suggesting spin-glass like anomalies in both phases.

  6. Compaction Effects on Uniformity, Moisture Diffusion, and Mechanical Properties of Asphalt Pavements

    E-Print Network [OSTI]

    Kassem, Emad Abdel-Rahman Ahmed

    2011-08-08T23:59:59.000Z

    in gyratory specimens were related to the mixture mechanical properties measured using the Overlay and Hamburg tests. The second part of this study focused on studying the relationship between air void distribution and moisture diffusion. A laboratory test...

  7. TEMPERATURE AND MOISTURE EFFECTS ON COMPOSITE MATERIALS FOR WIND TURBINE BLADES

    E-Print Network [OSTI]

    TEMPERATURE AND MOISTURE EFFECTS ON COMPOSITE MATERIALS FOR WIND TURBINE BLADES by Mei Li A thesis graduate students in the composite materials group for their help and kindness. Finally, thanks to my dear

  8. Investigation of Conditions for Moisture Damage in Asphalt Concrete and Appropriate Laboratory Test Methods

    E-Print Network [OSTI]

    Lu, Qing

    2005-01-01T23:59:59.000Z

    of Asphalt Concrete-Physical Testing. ” Final Report, #930-of Asphalt Concrete: Chemical Testing. ” Alabama Highwayconcrete mixes, it is preferred to use a mix that would have good moisture resistance under laboratory testing

  9. Investigation of Conditions for Moisture Damage in Asphalt Concrete and Appropriate Laboratory Test Methods

    E-Print Network [OSTI]

    Harvey, John T; Lu, Qing

    2005-01-01T23:59:59.000Z

    of Asphalt Concrete-Physical Testing. ” Final Report no.of Asphalt Concrete: Chemical Testing. ” Alabama Highwayconcrete mixes, it is preferable to use a mix that would have good moisture resistance under laboratory testing

  10. Estimation of soil moisture in paddy field using Artificial Neural Networks

    E-Print Network [OSTI]

    Arif, Chusnul; Setiawan, Budi Indra; Doi, Ryoichi

    2013-01-01T23:59:59.000Z

    In paddy field, monitoring soil moisture is required for irrigation scheduling and water resource allocation, management and planning. The current study proposes an Artificial Neural Networks (ANN) model to estimate soil moisture in paddy field with limited meteorological data. Dynamic of ANN model was adopted to estimate soil moisture with the inputs of reference evapotranspiration (ETo) and precipitation. ETo was firstly estimated using the maximum, average and minimum values of air temperature as the inputs of model. The models were performed under different weather conditions between the two paddy cultivation periods. Training process of model was carried out using the observation data in the first period, while validation process was conducted based on the observation data in the second period. Dynamic of ANN model estimated soil moisture with R2 values of 0.80 and 0.73 for training and validation processes, respectively, indicated that tight linear correlations between observed and estimated values of s...

  11. OVERSTORY-IMPOSED HETEROGENEITY IN SOLAR RADIATION AND SOIL MOISTURE IN A SEMIARID WOODLAND

    E-Print Network [OSTI]

    Breshears, David D.; Rich, Paul M.; Barnes, Fairley J.; Katherine, Campbell

    1997-01-01T23:59:59.000Z

    plants and the intercanopy patches that separate them, yielding an overstory with intermediate closure. Field measurements of microclimate at the scale of canopy patches, particularly for near-ground solar radiation and soil moisture, are largely lacking...

  12. The effects of aggregate gradation on moisture diffusivity in a cementious based material

    E-Print Network [OSTI]

    Szecsy, Richard

    1993-01-01T23:59:59.000Z

    Gravel), and the presence of fly ash (10% by cement weight or none). Also developed, is an experimental laboratory procedure which measures the moisture diffusivity of a cementious material. The method and procedure for measuring diffusivity developed...

  13. PATTERNS OF LEAF WETTABILITY ALONG AN EXTREME MOISTURE GRADIENT IN WESTERN PATAGONIA, ARGENTINA

    E-Print Network [OSTI]

    Brewer, Carol

    PATTERNS OF LEAF WETTABILITY ALONG AN EXTREME MOISTURE GRADIENT IN WESTERN PATAGONIA, ARGENTINA Patagonia, Argentina. Morphological and structural characteristics of leaves significantly affected leaf surfaces. Keywords: leaf wetness, morphology, water droplet, Patagonia, gradient. Introduction A large

  14. Moisture sensor based on evanescent wave light scattering by porous sol-gel silica coating

    DOE Patents [OSTI]

    Tao, Shiquan; Singh, Jagdish P.; Winstead, Christopher B.

    2006-05-02T23:59:59.000Z

    An optical fiber moisture sensor that can be used to sense moisture present in gas phase in a wide range of concentrations is provided, as well techniques for making the same. The present invention includes a method that utilizes the light scattering phenomenon which occurs in a porous sol-gel silica by coating an optical fiber core with such silica. Thus, a porous sol-gel silica polymer coated on an optical fiber core forms the transducer of an optical fiber moisture sensor according to an embodiment. The resulting optical fiber sensor of the present invention can be used in various applications, including to sense moisture content in indoor/outdoor air, soil, concrete, and low/high temperature gas streams.

  15. The effects of soil moisture on pecan weevil emergence and predicting drought delay

    E-Print Network [OSTI]

    Schraer, Stephen Martin

    1996-01-01T23:59:59.000Z

    soils. Drought conditions, induced on soil plots, as well as natural soil conditions were used to assess the effects of soil particle size distribution and soil moisture on soil hardness. Soil hardness can be determined by the following: 572...

  16. Modeling land surface processes of the midwestern United States : predicting soil moisture under a warmer climate

    E-Print Network [OSTI]

    Winter, Jonathan (Jonathan Mark)

    2010-01-01T23:59:59.000Z

    This dissertation seeks to quantify the response of soil moisture to climate change in the midwestern United States. To assess this response, a dynamic global vegetation model, Integrated Biosphere Simulator, was coupled ...

  17. Measurement of moisture and total reducing sugars using Near Infrared Spectroscopy

    E-Print Network [OSTI]

    Mehrubeoglu, Mehrube

    1995-01-01T23:59:59.000Z

    industrial applications. In this project, the accuracy and feasibility of measuring moisture and total reducing sugar content in a vegetable medium using a Near Infrared Spectroscopy technique was investigated as an alternative to slow and tedious classical...

  18. The Effect of Moisture Absorption on the Physical Properties of Polyurethane Shape Memory Polymer Foams

    E-Print Network [OSTI]

    Yu, Ya-Jen

    2012-07-16T23:59:59.000Z

    The effect of moisture absorption on the glass transition temperature (Tg) and stress/strain behavior of network polyurethane shape memory polymer (SMP) foams has been investigated. With our ultimate goal of engineering polyurethane SMP foams...

  19. MODEL 9975 SHIPPING PACKAGE: IMPACT OF CAPLUG REMOVAL ON FIBERBOARD MOISTURE LEVEL

    SciTech Connect (OSTI)

    Daugherty, W.

    2011-06-23T23:59:59.000Z

    Two 9975 shipping packages were removed from KAC and provided to SRNL for test purposes, after both packages were found to exceed the 1 inch maximum criterion for the axial gap at the top of the package. Package 9975-01818 was found with an axial gap of 1.437 inch, and an estimated 2.5 liters of excess moisture in the lower fiberboard layers. Package 9975-02287 was found with an axial gap of 1.008 inch, and only slightly elevated moisture levels relative to typical packages. Prior data from the 9975 Surveillance Program has shown that the 9975 drum provides a degree of isolation, and will tend to preserve fiberboard moisture levels for an extended period of time. Both packages were provided to SRNL to identify whether removal of the 4 caplugs in each package would allow moisture to escape the package. Following testing with the caplugs removed for approximately 1 year, this report documents the findings from this effort. Two 9975 shipping packages removed from service in K-Area Complex (KAC) due to an excessive axial gap have been tested in SRNL to determine if caplug removal would facilitate the reduction of excess fiberboard moisture. An additional question to be answered through this testing was whether the resulting moisture loss would reduce the axial gap, reversing the effect seen during storage with excess moisture present. These packages have completed approximately 1 year in test, during which time the weight of each package has steadily decreased as a result of moisture migration out of the package. However, elevated moisture levels still remain in the packages. During this test period, the bottom fiberboard layers of package 9975-01818 (which contained the greater amount of excess moisture) experienced further compaction, and the axial gap of both packages has increased. This effort has shown that removal of the caplugs may not be a sufficient measure to rehabilitate packages with excess moisture or excess axial gaps in a timely manner. However, this measure might make a meaningful contribution in combination with other actions (to be determined). It is recommended that the caplug removal tests in SRNL be discontinued at this time.

  20. The influence of particle-size distribution and moisture levels on the formation of soil hardpans

    E-Print Network [OSTI]

    Bauer, Herman John

    1963-01-01T23:59:59.000Z

    THE INFLUENCE OF PARTICLE-SIZE DISTRIBUTION AND MOISTURE LEVELS ON THE FORMATION OF SOIL HARDPANS A Thesis By HERMAN J. BAUER Submitted to the Graduate School of the Agricultural and Mechanical College of Texas in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE January, 1963 Major Subject: Soil Physics THE INFLUENCE OF PARTICLE-SIZE DISTRIBUTION AND MOISTURE LEVELS ON THE FORMATION OF SOIL HARDPANS A Thesis By HERMAN J. BAUER Approved as to style and content...

  1. The influence of particle-size distribution and moisture levels on the formation of soil hardpans 

    E-Print Network [OSTI]

    Bauer, Herman John

    1963-01-01T23:59:59.000Z

    THE INFLUENCE OF PARTICLE-SIZE DISTRIBUTION AND MOISTURE LEVELS ON THE FORMATION OF SOIL HARDPANS A Thesis By HERMAN J. BAUER Submitted to the Graduate School of the Agricultural and Mechanical College of Texas in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE January, 1963 Major Subject: Soil Physics THE INFLUENCE OF PARTICLE-SIZE DISTRIBUTION AND MOISTURE LEVELS ON THE FORMATION OF SOIL HARDPANS A Thesis By HERMAN J. BAUER Approved as to style and content...

  2. Elemental Analyses of Hanford Surface Neutron Moisture Measurement Calibration Standard Samples

    SciTech Connect (OSTI)

    Watson, W.T., Westinghouse Hanford

    1996-07-31T23:59:59.000Z

    Elemental analyses have been performed on twenty samples taken from the moisture standards prepared to use in performing experimental calibrations of the surface neutron moisture measurement system. These standards consisted of mixtures of sand, hydrated alumina, and boron carbide. Elemental analyses were performed primarily to discover the quantities of any strong thermal neutron absorbers that may have been present in the mixture in unknown trace quantities.

  3. Effect of external stress on moisture diffusion in an epoxy resin and its composite material

    E-Print Network [OSTI]

    Henson, Michael Chamberlain

    1986-01-01T23:59:59.000Z

    EFFECT OF EXTERNAL STRESS ON MOISTURE DIFFUSION IN AN EPOXY RESIN AND ITS C(MPOSITE MATERIAL A Thesis by MICHAEL CHAMBERLAIN HENSON Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement... for the degree of MASTER OF SCIENCE May 1986 Major Subject: Civil Engineering EFFECT OF EXTERNAL STRESS ON MOISTURE DIFFUSION IN AN EPOXY RESIN AND ITS CCNPOSITE MATERIAL A Thesis by MICHAEL CHAMBERLAIN HENSON Approved as to style and content by: (Y...

  4. The effects of grain moisture content and grain temperature on the penetration of hydrogen cyanide

    E-Print Network [OSTI]

    Kunz, Sidney E

    1962-01-01T23:59:59.000Z

    THE EFFECTS QF CRAIN MOISTURE CONTENT AND GRAIN TEMiPERATURE ON THE &NETRATION OF HYDROGEN CYANIDE A Thesis SIDNEY EDMUND KUNZ Submitted to the Graduate School of ths Agricultural and Mechanical College of Texas in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE (Mionth) 1262 (Year) Mayor Subject ghtdlggllQJLK THE EFFECTS OF GRAIN MOISTURE CONTENT JBD GRAIN TEMPERATURE ON THE PENETRATION OF HYDROGEN CYANIDE A Thesis SIDNEY EDNUND KUNZ Approved as to style...

  5. Distribution of soil and leaf water potentials of mature grapefruit trees under three soil moisture regimes

    E-Print Network [OSTI]

    Prathapar, Sanmugam Ahembaranathan

    1982-01-01T23:59:59.000Z

    DISTRIBUTION OF SOIL AND LEAF WATER POTENTIALS OF MATURE GRAPEFRUIT TREES UNDER THREE SOIL MOISTURE REGIMES A Thesis by SANMUGAM AHEMBARANATHAN PRATHAPAP, Submitted to the Graduate College of Texas A&M University in partial fulfillment... of the requirement for the degree of MASTER OF SCIENCE May 1982 Major Subject; Agricultural Engineering DISTRIBUTION OF SOIL AND LEAF WATER POTENTIALS OF MATURE GRAPEFRUIT TREES UNDER THREE SOIL MOISTURE REGIMES A Thesis by SANMUGAM AHEMBARANATHAN PRATHAPAR...

  6. Dual frequency microwave radiometer measurements of soil moisture for bare and vegetated rough surfaces

    E-Print Network [OSTI]

    Lee, Siu Lim

    1974-01-01T23:59:59.000Z

    DUAL FREQUENCY MICROWAVE RADIOMETER MEASUREMENTS OF SOIL MOISTURE FOR BARE AND VEGETATED ROUGH SURFACES A Thesis by SIU LIM LEE Submitted to the Graduate College of Texas A(M University in partial fulfillment of the requirement for the degree... of MASTER OF SCIENCE August 1974 Major Subject: Electrical Engineering DUAL FREQUENCY MICROWAVE RADIOMETER MEASUREMENTS OF' SOIL MOISTURE FOR BARE AND VEGETATED ROUGH SURFACES A Thesis by SIU LIM LEE Approved as to style and content by: (C rman...

  7. Evaluation of oil shale bitumen as a pavement asphalt additive to reduce moisture damage susceptibility

    SciTech Connect (OSTI)

    Robertson, R.E.; Harnsberger, P.M.; Wolf, J.M.

    1991-01-01T23:59:59.000Z

    An unrefined shale bitumen was evaluated as an agent to reduce moisture damage susceptibility of asphalt aggregate mixtures. Some activity was observed but less than might have been expected based on the molecular weight and nitrogen content of the bitumen. The counter effects of free carboxylic acids, which are known to be variable in asphalt and which are also present in the unrefined bitumen, appear to diminish the activity of the bitumen to inhibit moisture damage. 5 refs., 1 tab.

  8. Potential Soil Moisture Products from the Aquarius Radiometer and Scatterometer Using an Observing System Simulation Experiment

    SciTech Connect (OSTI)

    Luo, Yan [I.M. Systems Group at NOAA/NCEP/EMC; Feng, Xia [George Mason University; Houser, Paul [George Mason University; Anantharaj, Valentine G [ORNL; Fan, Xingang [Western Kentucky University, Bowling Green; De Lannoy, Gabrielle [Ghent University, Belgium; Zhan, Xiwu [NOAA/NESDIS Center for Satellite Applications and Research; Dabbiru, Lalitha [Mississippi State University (MSU)

    2013-01-01T23:59:59.000Z

    Using an observing system simulation experiment (OSSE), we investigate the potential soil moisture retrieval capability of the National Aeronautics and Space Administration (NASA) Aquarius radiometer (L-band 1.413 GHz) and scatterometer (L-band, 1.260 GHz). We estimate potential errors in soil moisture retrievals and identify the sources that could cause those errors. The OSSE system includes (i) a land surface model in the NASA Land Information System, (ii) a radiative transfer and backscatter model, (iii) a realistic orbital sampling model, and (iv) an inverse soil moisture retrieval model. We execute the OSSE over a 1000 2200 km2 region in the central United States, including the Red and Arkansas river basins. Spatial distributions of soil moisture retrieved from the radiometer and scatterometer are close to the synthetic truth. High root mean square errors (RMSEs) of radiometer retrievals are found over the heavily vegetated regions, while large RMSEs of scatterometer retrievals are scattered over the entire domain. The temporal variations of soil moisture are realistically captured over a sparely vegetated region with correlations 0.98 and 0.63, and RMSEs 1.28% and 8.23% vol/vol for radiometer and scatterometer, respectively. Over the densely vegetated region, soil moisture exhibits larger temporal variation than the truth, leading to correlation 0.70 and 0.67, respectively, and RMSEs 9.49% and 6.09% vol/vol respectively. The domain-averaged correlations and RMSEs suggest that radiometer is more accurate than scatterometer in retrieving soil moisture. The analysis also demonstrates that the accuracy of the retrieved soil moisture is affected by vegetation coverage and spatial aggregation.

  9. The nature of the first order isostructural transition in GdRhSn

    SciTech Connect (OSTI)

    Gupta, Sachin [Indian Institute of Technology Bombay; Suresh, K G [Indian Institute of Technology Bombay; Nigam, A K [Tara Institute of Fundamental Resarch; Mudryk, Y [Ames Laboratory; Paudyal, D [Ames Laboratory; Pecharsky, V K [Ames Laboratory; Gschneidner, Karl A [Ames Laboratory

    2014-11-01T23:59:59.000Z

    We present structural, magnetic, thermal, magnetocaloric, and electrical transport properties of polycrystalline GdRhSn. Magnetization data show that it orders antiferromagnetically at TN = 16.2 K. The compound has the ZrNiAl type hexagonal crystal structure at room temperature and undergoes a first order iso-structural transition in the paramagnetic state at 245 K. The unit cell volume change at the transition is small (-0.07 %) but discontinuous, in agreement with the first-order nature of the transition observed by magnetic, transport, and heat capacity measurements. The anisotropic changes of the lattice parameters are ?a/a = 0.28 % and ?c/c = -0.64 % on cooling. A substantial change in the 4f and conduction electron hybridization, giving rise to an increased integrated DOS, occurs when the high temperature phase transforms to the low temperature phase. A moderate magnetocaloric effect at TN (?SM = -6.5 J/kg K and ?Tad = 4.5 K for ?H= 50 kOe) has been measured using both magnetization and heat capacity data

  10. R.H. Saunders GS concrete growth mitigation project instrumentation and finite element analysis

    SciTech Connect (OSTI)

    Adeghe, L.; Hindy, A.; Ho, M.S. [Hydroelectric Business Unit, Ontario Hydro, Toronto, Ontario (Canada)

    1995-12-31T23:59:59.000Z

    In 1991, concrete expansion due to Alkali-Silica Reaction (ASR), was diagnosed as the cause of operational and structural problems at R.H. Saunders Generating Station. Reestablishment of contraction joints between the generating units by cutting slots was initiated in January 1993 to relieve accumulated stresses and allow further expansion without deforming the turbine-generators. An integral part of the remedial measure is the installation of an extensive instrumentation system and development of detailed finite element models of the powerhouse structures. In total, two hundred and thirty five instruments have been installed. The instruments include surface extensometers, borehole extensometers, crackmeters, stressmeters, pendulums, thermocouples, borehole convergence meters and strain gauges. All the instruments are monitored continuously by an Automatic Data Acquisition System (ADAS) which allows instrument data to be evaluated remotely. This instrumentation system is being used to collect data on the structural concrete expansion and response to slot cutting. To complement the instrumentation data, three different finite element models have been developed for use. The models range from a very detailed representation of a single powerhouse unit to a less detailed model of the sixteen-unit powerhouse. The finite element models have been calibrated to reflect measured data and subsequently used to estimate the location and frequency of future cuts.

  11. Magnetism and superconductivity in U?PtxRh(1–x)C?

    SciTech Connect (OSTI)

    Wakeham, N. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Ni, Ni [Univ. of California, Los Angeles, CA (United States); Bauer, E. D. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Thompson, J. D. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Tegtmeier, E. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Ronning, F. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2015-01-01T23:59:59.000Z

    We report the phase diagram of the doping series U?PtxRh(1–x)C?, studied through measurements of resistivity, specific heat, and magnetic susceptibility. The Néel temperature of U?Rh?C? of ~ 22 K is suppressed with increasing Pt content, reaching zero temperature close to x = 0.7, where we observed signatures of increased quantum fluctuations. In addition, evidence is presented that the antiferromagnetic state undergoes a spin-reorientation transition upon application of an applied magnetic field. This transition shows non-monotonic behavior as a function of x, peaking at around x = 0.3. Superconductivity is observed for x ? 0.9, with Tc increasing with increasing x. The reduction in Tc and increase in residual resistivity with decreasing Pt content is inconsistent with the extension of the Abrikosov-Gor'kov theory to unconventional superconductivity.

  12. Asymmetric “melting” and “freezing” kinetics of the magnetostructural phase transition in B2-ordered FeRh epilayers

    SciTech Connect (OSTI)

    Vries, M. A. de, E-mail: m.a.devries@ed.ac.uk [School of Physics and Astronomy, University of Leeds, Leeds LS2 9JT (United Kingdom); School of Chemistry, University of Edinburgh, Edinburgh EH9 3JJ (United Kingdom); Loving, M.; Lewis, L. H. [Department of Chemical Engineering, Northeastern University, Boston, Massachusetts 02115 (United States); McLaren, M.; Brydson, R. M. D. [Institute for Materials Research, University of Leeds, Leeds LS2 9JT (United Kingdom); Liu, X. [Condensed Matter Physics and Materials Science Department, Brookhaven National Laboratory, Upton, New York 11973 (United States); Beijing National Laboratory for Condensed Matter Physics, and Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Collaborative Innovation Center of Quantum Matter, Beijing 100871 (China); Langridge, S. [ISIS, Harwell Science and Innovation Campus, Science and Technology Facilities Council, Rutherford Appleton Laboratory, Didcot, Oxon OX11 0QX (United Kingdom); Marrows, C. H., E-mail: c.h.marrows@leeds.ac.uk [School of Physics and Astronomy, University of Leeds, Leeds LS2 9JT (United Kingdom)

    2014-06-09T23:59:59.000Z

    Synchrotron X-ray diffraction was used to study the phase transformation processes during the magnetostructural transition in a B2-ordered FeRh (001)-oriented epilayer grown on MgO by sputtering. Out-of-plane lattice constant measurements within the hysteretic regime of the transition reveal a microstructure consistent with the coexistence of lattice-expanded and contracted phases in spatially distinct regions. It was found that the phase separation is more pronounced during cooling than heating. Furthermore, whilst lattice-expanded domains that span the height of the film can be undercooled by several kelvins, there is no equivalent superheating. This asymmetry between the cooling and heating processes in FeRh is consistent with the difference in the kinetics of generic freezing and melting transitions.

  13. Synthesis, Crystal and Electronic Structure of the Quaternary Magnetic EuTAl4Si2 (T = Rh and Ir) Compounds

    SciTech Connect (OSTI)

    Maurya, Arvind [Tata Institute of Fundamental Research; Thamizhavel, Arumugam [Tata Institute of Fundamental Research; Provino, Alessia [University of Genova; Pani, Marcella [University of Genova; Manfrinetti, Pietro [University of Genova; Paudyal, Durga [Ames Laboratory; Dhar, Sudesh Kumar [Tata Institute of Fundamental Research

    2014-01-22T23:59:59.000Z

    Single crystals of the quaternary europium compounds EuRhAl4Si2 and EuIrAl4Si2 were synthesized by using the Al–Si binary eutectic as a flux. The structure of the two quaternary compounds has been refined by single crystal X-ray diffraction. Both compounds are stoichiometric and adopt an ordered derivative of the ternary KCu4S3 structure type (tetragonal tP8, P4/mmm). The two compounds reported here represent the first example of a quaternary and truly stoichiometric 1:1:4:2 phase crystallizing with this structure type. In light of our present results, the structure of the BaMg4Si3 compound given in literature as representing a new prototype is actually isotypic with the KCu4S3 structure. Local spin density approximation including the Hubbard U parameter (LSDA + U) calculations show that Eu ions are in the divalent state, with a significant hybridization between the Eu 5d, Rh (Ir) 4d (5d), Si 3p and Al 3p states. Magnetic susceptibility measured along the [001] direction confirms the divalent nature of the Eu ions in EuRhAl4Si2 and EuIrAl4Si2, which order magnetically near 11 and 15 K, respectively.

  14. NO Adsorption and Dissociation on Rh(111): PM-IRAS Study W. T. Wallace, Y. Cai, M. S. Chen, and D. W. Goodman*

    E-Print Network [OSTI]

    Goodman, Wayne

    -modulation infrared reflection absorption spectroscopy to study the adsorption/ dissociation of NO on Rh(111). While that the N atoms may diffuse into the near-surface metal region. The latter conclusion followed because

  15. ARM - Atmospheric Heat Budget

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearchSOLICITATIONIMODI FICATION OFMaterialsAnnual Reports27,ListAtmospheric Heat

  16. ARM - Atmospheric Pressure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearchSOLICITATIONIMODI FICATION OFMaterialsAnnual Reports27,ListAtmospheric

  17. Atmospheric PSF Interpolation

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem Not Found Item Not Found The itemAIR SEPARATION BYAbrasion andArticle)Atmospheric

  18. atmospheres thin atmospheres: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to optical depth perturbations. In Earth-type atmospheres sustained planetary greenhouse effect with a stable ground surface temperature can only exist at a particular...

  19. FINAL REPORT FOR MOISTURE EFFECTS ON COMPACTION OF FIBERBOARD IN A 9975 SHIPPING PACKAGE

    SciTech Connect (OSTI)

    Stefek, T.; Daugherty, W.; Estochen, E.

    2013-09-17T23:59:59.000Z

    Compaction of lower layers in the fiberboard assembly has been observed in 9975 packages that contain elevated moisture. Lab testing has resulted in a better understanding of the relationship between the fiberboard moisture level and compaction of the lower fiberboard assembly, and the behavior of the fiberboard during transport. In laboratory tests of cane fiberboard, higher moisture content has been shown to correspond to higher total compaction, greater rate of compaction, and continued compaction over a longer period of time. In addition, laboratory tests have shown that the application of a dynamic load results in higher fiberboard compaction compared to a static load. The test conditions and sample geometric/loading configurations were chosen to simulate the regulatory requirements for 9975 package input dynamic loading. Dynamic testing was conducted to acquire immediate and cumulative changes in geometric data for various moisture levels. Two sample sets have undergone a complete dynamic test regimen, one set for 27 weeks, and the second set for 47 weeks. The dynamic input, data acquisition, test effects on sample dynamic parameters, and results from this test program are summarized and compared to regulatory specifications for dynamic loading. Compaction of the bottom fiberboard layers due to the accumulation of moisture is one possible cause of an increase in the axial gap at the top of the package. The net compaction of the bottom layers will directly add to the axial gap. The moisture which caused this compaction migrated from the middle region of the fiberboard assembly (which is typically the hottest). This will cause the middle region to shrink axially, which will also contribute directly to the axial gap. Measurement of the axial gap provides a screening tool for identifying significant change in the fiberboard condition. The data in this report provide a basis to evaluate the impact of moisture and fiberboard compaction on 9975 package performance during storage at the Savannah River Site (SRS).

  20. Using Whole-House Field Tests to Empirically Derive Moisture Buffering Model Inputs

    SciTech Connect (OSTI)

    Woods, J.; Winkler, J.; Christensen, D.; Hancock, E.

    2014-08-01T23:59:59.000Z

    Building energy simulations can be used to predict a building's interior conditions, along with the energy use associated with keeping these conditions comfortable. These models simulate the loads on the building (e.g., internal gains, envelope heat transfer), determine the operation of the space conditioning equipment, and then calculate the building's temperature and humidity throughout the year. The indoor temperature and humidity are affected not only by the loads and the space conditioning equipment, but also by the capacitance of the building materials, which buffer changes in temperature and humidity. This research developed an empirical method to extract whole-house model inputs for use with a more accurate moisture capacitance model (the effective moisture penetration depth model). The experimental approach was to subject the materials in the house to a square-wave relative humidity profile, measure all of the moisture transfer terms (e.g., infiltration, air conditioner condensate) and calculate the only unmeasured term: the moisture absorption into the materials. After validating the method with laboratory measurements, we performed the tests in a field house. A least-squares fit of an analytical solution to the measured moisture absorption curves was used to determine the three independent model parameters representing the moisture buffering potential of this house and its furnishings. Follow on tests with realistic latent and sensible loads showed good agreement with the derived parameters, especially compared to the commonly-used effective capacitance approach. These results show that the EMPD model, once the inputs are known, is an accurate moisture buffering model.

  1. Sandia National Laboratories: atmospheric chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and atmospheric chemistry that is expected to benefit auto and engine manufacturers, oil and gas utilities, and other industries that employ combustion models. A paper...

  2. Electronmagnetic induction probe calibration for electrical conductivity measurements and moisture content determination of Hanford high level waste

    SciTech Connect (OSTI)

    Wittekind, W.D., Westinghouse Hanford

    1996-05-23T23:59:59.000Z

    Logic of converting EMI measured electrical conductivity to moisture with expected uncertainty. Estimates from present knowledge, assumptions, and measured data. Archie`s Law has been used since the 1940`s to relate electrical conductivity in porous media to liquid volume fraction. Measured electrical conductivity to moisture content uses: Porosity, Interstitial liquid electrical conductivity, Solid particle density,Interstitial liquid density, and interstitial liquid water content. The uncertainty of assumed values is calculated to determine the final moisture wt.% result uncertainty.

  3. ATS 351, Spring 2010 Water in the Atmosphere 55 points

    E-Print Network [OSTI]

    Rutledge, Steven

    , will increase the relative humidity. q RH = a ctual vap or pressure saturation vapo r pressu re x10 0% e) (5

  4. STATUS REPORT FOR MOISTURE EFFECTS ON COMPACTION OF FIBERBOARD IN A 9975 SHIPPING PACKAGE

    SciTech Connect (OSTI)

    Stefek, T.; Daugherty, W.; Estochen, E.

    2011-06-23T23:59:59.000Z

    Compaction of lower layers in the fiberboard overpack has been observed in 9975 packages that contain elevated moisture. Lab testing has resulted in a better understanding of the relationship between the fiberboard moisture level and compaction of the lower fiberboard assembly, and the behavior of the fiberboard during transport. In laboratory tests, higher moisture content has been shown to correspond to higher total compaction of fiberboard material, greater rate of compaction, and continued compaction over a longer period of time. In addition, laboratory tests have shown that the application of a dynamic load results in higher fiberboard compaction. The test conditions and sample geometric/loading configurations were chosen to simulate the regulatory requirements for 9975 package input dynamic loading. Dynamic testing was conducted over a period of six months to acquire immediate and cumulative changes in geometric data for various moisture levels. Currently, one sample set has undergone a complete dynamic test regimen, while testing of another set is still in-progress. The dynamic input, data acquisition, test effects on sample dynamic parameters, and interim results from this test program are summarized and compared to regulatory specifications for dynamic loading. This will provide a basis from which to evaluate the impact of moisture and fiberboard compaction on the safety basis for transportation (Safety Analysis Report for Packaging) and storage (facility Documented Safety Analysis) at the Savannah River Site (SRS).

  5. ELSEVIER AtmosphericResearch 38 (1995) 207-235 ATMOSPHERIC

    E-Print Network [OSTI]

    Moelders, Nicole

    ELSEVIER AtmosphericResearch 38 (1995) 207-235 ATMOSPHERIC RESEARCH On the parameterization of ice and water substance mixing ratio fields were only strongly altered by turning off the ice phase of these schemes includes ice processes. But in mid- latitudes and also in tropics the ice phase is an important

  6. ATMOSPHERIC ELSEVIER AtmosphericResearch 44 (1997) 231-241

    E-Print Network [OSTI]

    Reading, University of

    ATMOSPHERIC RESEARCH ELSEVIER AtmosphericResearch 44 (1997) 231-241 Error analysis of backscatter;accepted 14 February 1997 Abstract Ice sphere backscatter has been calculated using both Mie theory as a reasonable approximation for rv 1997 Elsevier Science B.V. 1. Introduction Cirrus clouds play

  7. Variation in soil moisture and N availability modulates carbon and water exchange in a California grassland experiment

    E-Print Network [OSTI]

    St. Clair, S.B.

    2010-01-01T23:59:59.000Z

    in soil moisture and N availability modulates carbon andamount and timing, N availability, and plant communityparticularly as water availability was increased. These

  8. Plant Response and Environmental Data from the Oldfield Community Climate and Atmospheric Manipulation (OCCAM) Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The Oldfield Community Climate and Atmospheric Manipulation (OCCAM) project is a joint effort of ORNL and the University of Tennessee to investigate community and ecosystem response to global change, specifically looking at the interactive effects of atmospheric carbon dioxide, surface temperatures, and soil moisture. The plants studied for their response to warming temperatures, elevated carbon dioxide, and altered water availability include C3 and C4 grasses, forbs, and legumes. These plants are typical of an old-field ecosystem that establishes itself on unused agricultural land. The results of the research focus on species abundance, production, phenology, and what is going on chemically below ground. Data are currently available from 2003 through July, 2008.

  9. Low-temperature conversion of high-moisture biomass: Topical report, January 1984--January 1988

    SciTech Connect (OSTI)

    Sealock, L.J. Jr.; Elliott, D.C.; Butner, R.S.; Neuenschwander, G.G.

    1988-10-01T23:59:59.000Z

    Pacific Northwest Laboratory (PNL) is developing a low-temperature, catalytic process that converts high-moisture biomass feedstocks and other wet organic substances to useful gaseous and liquid fuels. The advantage of this process is that it works without the need for drying or dewatering the feedstock. Conventional thermal gasification processes, which require temperatures above 750/degree/C and air or oxygen for combustion to supply reaction heat, generally cannot utilize feedstocks with moisture contents above 50 wt %, as the conversion efficiency is greatly reduced as a result of the drying step. For this reason, anaerobic digestion or other bioconversion processes traditionally have been used for gasification of high-moisture feedstocks. However, these processes suffer from slow reaction rates and incomplete carbon conversion. 50 refs., 21 figs., 22 tabs.

  10. Space Science : Atmosphere Greenhouse Effect

    E-Print Network [OSTI]

    Johnson, Robert E.

    Space Science : Atmosphere Greenhouse Effect Part-5a Solar + Earth Spectrum IR Absorbers Grey Atmosphere Greenhouse Effect #12;Radiation: Solar and Earth Surface B"(T) Planck Ideal Emission Integrate at the carbon cycle #12;However, #12;Greenhouse Effect is Complex #12;PLANETARY ENERGY BALANCE G+W fig 3-5

  11. ANALYSIS OF THE AXIAL GAP VS FIBERBOARD MOISTURE CONTENT IN A 9975 SHIPPING PACKAGE

    SciTech Connect (OSTI)

    Daugherty, W.

    2013-09-30T23:59:59.000Z

    The fiberboard assembly within a 9975 shipping package contains a modest amount of moisture, which can migrate to the cooler regions of the package when an internal heat load is present. Typically, this leads to increased moisture levels in the bottom fiberboard layers, along with elevated chloride levels which can leach from the fiberboard. Concerns have been raised that this condition could lead to corrosion of the stainless steel drum. It has been postulated that checking the axial gap at the top of the package against the current 1 inch maximum criterion provides a sufficient indication regarding the integrity of the fiberboard and drum. This report estimates the increase in axial gap that might be expected for a given moisture increase in the bottom fiberboard layers, and the likelihood that the increase will create a nonconforming condition that will lead to identification of the moisture increase. Using data relating the fiberboard moisture content with the degree of compaction under load, the present analysis indicates that the axial gap will increase by 0.282 inch as the bottom fiberboard layers approach the saturation point. This increase will cause approximately 58% of packages with otherwise nominal package component dimensions to fail the axial gap criterion, based on a survey of axial gap values recorded in K-Area surveillance activities. As the moisture content increases above saturation, the predicted increase in axial gap jumps to 0.405 inch, which would result in 92% or more of all packages failing the axial gap criterion. The data and analysis described in this report are specific to cane fiberboard. While it is expected that softwood fiberboard will behave similarly, such behavior has not yet been demonstrated.

  12. Ch4. Atmosphere and Surface Energy Balances

    E-Print Network [OSTI]

    Pan, Feifei

    ;Energy Pathways #12;Solar radiation transfer in the atmosphere Solar radiation Reflection Atmosphere or performing any work. #12;Solar radiation transfer in the atmosphere Solar radiation Reflection Transmission or water. #12;Solar radiation transfer in the atmosphere Solar radiation Reflection Transmission Atmosphere

  13. Influence of moisture on the behavior of aerosols

    SciTech Connect (OSTI)

    Adams, R.E.; Longest, A.W.; Tobias, M.L.

    1986-01-01T23:59:59.000Z

    The behavior of aerosols assumed to be characteristic of those generated during light water reactor (LWR) accident sequences and released into containment has been studied in the Nuclear Safety Pilot Plant (NSPP) located at the Oak Ridge National Laboratory (ORNL). It has been observed that in a saturated steam-air environment a change occurs in the shape of aerosol agglomerates of U/sub 3/O/sub 8/ aerosol, Fe/sub 2/O/sub 3/ aerosol, and mixed U/sub 3/O/sub 8/-Fe/sub 2/O/sub 3/ aerosol from branched-chain to spherical, and that the rate of reduction in the airborne aerosol mass concentration is increased relative to the rate observed in a dry atmosphere. The effect of a steam-air environment on the behavior of concrete aerosol is different. The shape of the agglomerated concrete aerosol is intermediate between branched-chain and spherical and the effect on the rate of reduction in airborne mass concentration appears to be slight. In a related project the shape of an agglomerated Fe/sub 2/O/sub 3/ aerosol was observed to change from branched-chain to spherical at, or near, 100% relative humidity.

  14. Tropical synoptic scale moisture fields observed from the Nimbus-7 SMMR

    E-Print Network [OSTI]

    Fink, Jeffrey David

    1989-01-01T23:59:59.000Z

    TROPICAL SYNOPTIC SCALE MOISTURE FIELDS OBSERVED FROM THE NIMBUS ? 7 SMMR A Thesis by JEFFREY DAVID FINK Submitted to the OfFice of Graduate Studies of Texas AkM University in partial fulfillment of the requirements for the degree of MASTER... ( iliember) AIarshnll J. 1VIcVnrlnnd ( (tlemb er ) James Il. Scoggins (Read of Departnrent) i%lay 1989 ns ABSTRACT Tropical Synoptic Scale Moisture Fields Observed from the NIMBUS ? 7 SMMR. (May 1989) Jefl'rey David Fink, B. S. , Texas A...

  15. Study of the moisture-fertility requirements of cotton in the Brazos River Valley, 1957

    E-Print Network [OSTI]

    Keese, Carroll Wayne

    1958-01-01T23:59:59.000Z

    of the moisture level imposed, and that water was not used efficiently from the two to five-foot zone. Hamilton and Stanberry (2) investigated the effects of varying rates of nitrogen fertilizer on the need of cotton for irrigation at Yuma, Arizona...LIBRARY II a III COLLEI:. e& 7EXAs STUDY OF THE MOISTURE-FERTILITY REQUIREMENTS OF COTTON IN THE BRAZOS RIVER VALLEY - 1957 A Thesis by CARROLL VIAYNE KEESE Submitted to the Graduate School of the Agricultural and Mechanical College...

  16. The effects of soil moisture on the phytotoxicity of a microwave field

    E-Print Network [OSTI]

    Whatley, Thomas Lamar

    1974-01-01T23:59:59.000Z

    THF. FFFECTS OF SOIL MOISTURE ON THE PHYTOTOXICITY OF A MICROWAVE FIELD A Thesis THOMAS LAMAR WHATLEY Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE... August 1974 Ma5or Sub)ect: Agronomy THE EFFECTS OF SOIL MOISTURE ON THE PHYTOTOXICITY OF A MICROHAVE FIELD A Thesis by THOMAS LAMAR VHATLEY Approved as to style and content by: (Chairman of Committee) (Head of Department) Member) ( t) August...

  17. A climatology of tropical moisture bursts in the eastern North Pacific Ocean

    E-Print Network [OSTI]

    Smith, Neil Ray

    1986-01-01T23:59:59.000Z

    A CLIil'IATOLOGY OF TROFICAL MOISTURE BURSTS IN THF. EASTERN NORTH PACIFIC OCEAN A Theseus NEIL R A Y SMITH Submitted to the Graduate College of' Texas AKIil University in partial fulfil)nient of the requirements I'o. the degree of MASTER... OF SCIENCE December 1986 M;i;iir Subject: Meteorology A CLIMATOLOGY OF TROPICAL MOISTURE BURSTS IN THE EASTERN NORTH PACIFIC OCEAN A Thesis NEIL RAY SMITH Approved as to style and content by: James P. McE uirk (Co-Chairman) ylmer H, Thompson (Co...

  18. Modeling Atmospheric Aerosols V. Rao Kotamarthi

    E-Print Network [OSTI]

    Modeling Atmospheric Aerosols V. Rao Kotamarthi and Yan Feng Climate Research Section Environmental Science Division Argonne National Laboratory #12;Outline Atmospheric Aerosols and gas phase heterogeneous reactions Regional Scales and Atmospheric Aerosols Regional Scale Aerosols: Ganges Valley Aerosol

  19. Examining the Relationship between Antecedent Soil Moisture and Summer Precipitation in the U.S. Great Plains

    E-Print Network [OSTI]

    Meng, Lei

    2010-01-14T23:59:59.000Z

    ............................................................................................. 67 5.2 Spatial variations in the soil moisture-precipitation relationship............ 67 5.3 Temporal variations in the soil moisture-precipitation relationship ....... 71 5.4 Persistence of spatial patterns in SM anomalies... ..................................... 74 5.5 Temporal variations in the relationship between GP summer precipitation and Ni?o SSTs ................................................................... 75 5.6 SST persistence versus SM persistence...

  20. Effect of grid size on runoff and soil moisture for a variable-source-area hydrology model

    E-Print Network [OSTI]

    Walter, M.Todd

    landscapes are dependent on the distribution and pattern of soil moisture and water transport. In this paper for efficient manage- ment of water quality [U.S. Environmental Protection Agency, 1994, 1995, 1996Effect of grid size on runoff and soil moisture for a variable-source-area hydrology model Wen

  1. Fragmentation Energetics of Clusters Relevant to Atmospheric...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Clusters Relevant to Atmospheric New Particle Formation. Fragmentation Energetics of Clusters Relevant to Atmospheric New Particle Formation. Abstract: The exact mechanisms by...

  2. SOIL MOISTURE RETENTION CHARACTERISTICS AND HYDRAULIC CONDUCTIVITY FOR DIFFERENT AREAS IN INDIA IN SELECTED STATES

    E-Print Network [OSTI]

    Kumar, C.P.

    systems require knowledge of the relationships between soil moisture content (), soil water pressure (h and water content relationship, hydraulic conductivity and water content relationship of the soil, saturated conductivity is affected markedly by the volumetric water content of soil. The relation between matric

  3. MOISTURE EFFECT ON DURABILITY OF AXIALLY LOADED CONCRETE-FILLED TUBULAR FRP PILES

    E-Print Network [OSTI]

    MOISTURE EFFECT ON DURABILITY OF AXIALLY LOADED CONCRETE-FILLED TUBULAR FRP PILES Miguel Pando, Ph_rizkalla@ncsu.edu ABSTRACT Fiber reinforced polymer (FRP) composite piles are a possible foundation alternative for projects located in harsh marine environments. Problems associated with traditional pile materials used in harsh

  4. Feasibility study of prompt gamma neutron activation for NDT measurement of moisture in stone and brick

    SciTech Connect (OSTI)

    Livingston, R. A.; Al-Sheikhly, M. [Materials Science and Engineering Dept., U. of Maryland, College Park MD 20742 (United States); Grissom, C.; Aloiz, E. [Museum Conservation Institute, Smithsonian Institution, Washington DC 20746 (United States); Paul, R. [Chemical Sciences Division, NIST, Gaithersburg MD 20899 (United States)

    2014-02-18T23:59:59.000Z

    The conservation of stone and brick architecture or sculpture often involves damage caused by moisture. The feasibility of a NDT method based on prompt gamma neutron activation (PGNA) for measuring the element hydrogen as an indication of water is being evaluated. This includes systematic characterization of the lithology and physical properties of seven building stones and one brick type used in the buildings of the Smithsonian Institution in Washington, D.C. To determine the required dynamic range of the NDT method, moisture-related properties were measured by standard methods. Cold neutron PGNA was also used to determine chemically bound water (CBW) content. The CBW does not damage porous masonry, but creates an H background that defines the minimum level of detection of damaging moisture. The CBW was on the order of 0.5% for all the stones. This rules out the measurement of hygric processes in all of the stones and hydric processed for the stones with fine scale pore-size distributions The upper bound of moisture content, set by porosity through water immersion, was on the order of 5%. The dynamic range is about 10–20. The H count rates were roughly 1–3 cps. Taking into account differences in neutron energies and fluxes and sample volume between cold PGNA and a portable PGNA instrument, it appears that it is feasible to apply PGNA in the field.

  5. Passive microwave soil moisture downscaling using evaporative fraction Olivier Merlin1

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    stations (METFLUX) and six flights of the L-band Push Broom Microwave Radiometer (PBMR). For each PBMR fraction (EF), which is the ratio of the evapotranspiration to the total energy available at the surface, especially for high soil moisture values. Those results illustrate the potential use of high

  6. Soil moisture variability of root zone profiles within SMEX02 remote sensing footprints

    E-Print Network [OSTI]

    as the par- titioning of incoming solar radiation and long wave radia- tion into outgoing long wave radiation.e., various active and passive microwave sensors), which provide mean sur- face soil moisture (0­5 cm) values footprints can provide a blueprint to design ground-based experiments and net- works and to efficiently use

  7. Characterization of fracture patterns and hygric properties for moisture flow modelling in cracked concrete

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    of building materials is far from complete. The pore structure of the material itself may change over time assessment, not only of building and building components, but of any built structure in general structures, as well as on the health and comfort of their occupants. Any analysis of moisture transfer

  8. The Effects of Roof Membrane Color on Moisture Accumulation in Low-slope Commercial Roof Systems

    SciTech Connect (OSTI)

    Kehrer, Manfred [ORNL

    2011-01-01T23:59:59.000Z

    The use of highly reflective roof membrane systems is being promoted and in some cases required in energy codes and green building codes and standards. Highly reflective membranes, which typically are light in color, have demonstrated reduced overall energy consumption in cooling dominated climate. These membranes also are theorized to reduce the heat island effect. Concern has been expressed about using highly reflective roof membrane systems in cool to cold climate zones because they potentially increase moisture accumulation in roof systems. Roof membranes are vapor retarders. The theory is that highly reflective membranes reflect the heat that could enter the roof assembly, potentially providing a condensing surface on the cold side of the roof assembly during winter months. The other concern is that roof systems using highly reflective membranes will not get hot enough during the summer months to dry out moisture that may have condensed or otherwise entered the roof assembly. This study focuses on mechanically attached, highly reflective, single-ply roof systems installed on low-slope (less than 2:12) structures in cool to cold climate zones. Three sources of data are considered when determining the moisture accumulation potential of these systems. 1.Test roof cuts taken during the winter months 2.Modeling data from a building envelope model specifically designed to evaluate moisture accumulation 3.Data from previous studies to determine the effects of roof membrane color on the drying rate of low-slope roof assemblies

  9. ASSESSMENT OF BISCUIT MOISTURE AND BISCUIT BROWNING Jens Michael Carstensen1

    E-Print Network [OSTI]

    weight moisture measurements. The data set includes biscuits from different lines and both hot and cooled. The imaging system, VideometerLab (www.videometer.com) captures 18 high resolution spectral images representations may be estimated in both the biscuit center region and in the edge/corner region. CIELAB

  10. Uncertainties in Estimating Moisture Fluxes over the Intra-Americas Sea ALBERTO M. MESTAS-NUEZ

    E-Print Network [OSTI]

    by these uncertainties. Therefore, NCEP­ NCAR reanalysis, with its global coverage and long-term record, can be used-third of all the summer moisture that enters the continental United States is transported by the GPLLJ (Helfand United States. Future re- search aimed at understanding summer precipitation must therefore deal

  11. Monitoring ET, Soil Moisture Saves Farmers Water, Energy, Time and Money

    E-Print Network [OSTI]

    Nebraska-Lincoln, University of

    Monitoring ET, Soil Moisture Saves Farmers Water, Energy, Time and Money By Sandi Alswager Karstens irrigation," said Gary Zoubek, extension educator in York County. "Using these tools not only saves energy that these two tools used together can save two to three inches of irrigation water per season, he said

  12. Effectiveness of vertical moisture barriers in highway pavements on expansive soils

    E-Print Network [OSTI]

    Jayatilaka, Ranasinghege

    1993-01-01T23:59:59.000Z

    finite element program, FLODEF, which couples moisture flow and elasticity was calibrated to reproduce the field observations of the suction in each of the locations. The program was then used to perform a study of the effects of climatic zone, degree...

  13. Evapotranspiration and regional probabilities of soil moisture stress in rainfed crops, southern India

    E-Print Network [OSTI]

    Biggs, Trent

    India Trent W. Biggs a, *, Prasanta K. Mishra b , Hugh Turral c a Department of Geography, San Diego 0902; fax: +1 619 594 4938. E-mail addresses: tbiggs@mail.sdsu.edu (T.W. Biggs), pkmbellary in press as: Biggs, T.W. et al., Evapotranspiration and regional probabilities of soil moisture stress

  14. The effects of moisture and particle size of feedlot biomass on co-firing burner performance 

    E-Print Network [OSTI]

    Chen, Chen-Jung

    2001-01-01T23:59:59.000Z

    increased from 350 ppm to 650 ppm while CO decreased from 46,000 ppm to 18,000 ppm (data measured at the first probe, 6" from the burner). The external water injection used to simulate high moisture FB decreased the pollutant emissions (NO[]) from 570 ppm...

  15. UNCORRECTEDPROOF 1 Towards deterministic downscaling of SMOS soil moisture using MODIS derived soil

    E-Print Network [OSTI]

    Boyer, Edmond

    of environmental applications including meteor- 33 ology, hydrology, water resource management and climatology. 34UNCORRECTEDPROOF 1 Towards deterministic downscaling of SMOS soil moisture using MODIS derived soil Kerr b 4 a Civil and Environmental Engineering, The University of Melbourne, Australia 5 b Centre d

  16. Hillslope-scale soil moisture estimation with a physically-based ecohydrology model and L-band microwave remote sensing observations from space

    E-Print Network [OSTI]

    Flores, Alejandro Nicolas

    2009-01-01T23:59:59.000Z

    Soil moisture is a critical hydrosphere state variable that links the global water, energy, and carbon cycles. Knowledge of soil moisture at scales of individual hillslopes (10's to 100's of meters) is critical to advancing ...

  17. Environmental Chemistry II (Atmospheric Chemistry)

    E-Print Network [OSTI]

    Dibble, Theodore

    SYLLABUS FOR Environmental Chemistry II (Atmospheric Chemistry) FCH 511 Fall 2013 Theodore S/explaining the trends in J as a function of altitude and solar zenith angle. The second involves analyzing real

  18. THE MARTIAN ATMOSPHERIC BOUNDARY LAYER

    E-Print Network [OSTI]

    Spiga, Aymeric

    THE MARTIAN ATMOSPHERIC BOUNDARY LAYER A. Petrosyan,1 B. Galperin,2 S. E. Larsen,3 S. R. Lewis,4 A [Haberle et al., 1993a; Larsen et al., 2002; Hinson et al., 2008]. At night, convection is inhibited

  19. Atmospheric science and power production

    SciTech Connect (OSTI)

    Randerson, D. (ed.)

    1984-07-01T23:59:59.000Z

    This is the third in a series of scientific publications sponsored by the US Atomic Energy Commission and the two later organizations, the US Energy Research and Development Adminstration, and the US Department of Energy. The first book, Meteorology and Atomic Energy, was published in 1955; the second, in 1968. The present volume is designed to update and to expand upon many of the important concepts presented previously. However, the present edition draws heavily on recent contributions made by atmospheric science to the analysis of air quality and on results originating from research conducted and completed in the 1970s. Special emphasis is placed on how atmospheric science can contribute to solving problems relating to the fate of combustion products released into the atmosphere. The framework of this book is built around the concept of air-quality modeling. Fundamentals are addressed first to equip the reader with basic background information and to focus on available meteorological instrumentation and to emphasize the importance of data management procedures. Atmospheric physics and field experiments are described in detail to provide an overview of atmospheric boundary layer processes, of how air flows around obstacles, and of the mechanism of plume rise. Atmospheric chemistry and removal processes are also detailed to provide fundamental knowledge on how gases and particulate matter can be transformed while in the atmosphere and how they can be removed from the atmosphere. The book closes with a review of how air-quality models are being applied to solve a wide variety of problems. Separate analytics have been prepared for each chapter.

  20. Laser Atmospheric Studies with VERITAS

    E-Print Network [OSTI]

    C. M. Hui; for the VERITAS collaboration

    2007-09-25T23:59:59.000Z

    As a calibrated laser pulse propagates through the atmosphere, the amount of Rayleigh-scattered light arriving at the VERITAS telescopes can be calculated precisely. This technique was originally developed for the absolute calibration of ultra-high-energy cosmic-ray fluorescence telescopes but is also applicable to imaging atmospheric Cherenkov telescopes (IACTs). In this paper, we present two nights of laser data taken with the laser at various distances away from the VERITAS telescopes and compare it to Rayleigh scattering simulations.

  1. A RhxSy/C Catalyst for the Hydrogen Oxidation and Hydrogen Evolution Reactions in HBr

    SciTech Connect (OSTI)

    Masud, Jahangir [Univ. of Kansas, Lawrence, KS (United States); Nguyena, Trung V. [Univ. of Kansas, Lawrence, KS (United States); Singh, Nirala [Univ. of California, Santa Barbara, CA (United States); McFarland, Eric [Univ. of California, Santa Barbara, CA (United States); Ikenberry, Myles [Kansas State Univ., Manhattan, KS (United States); Hohn, Keith [Kansas State Univ., Manhattan, KS (United States); Pan, Chun-Jern [National Taiwan University of Science & Technology, Tapei (Taiwan); Hwang, Bing-Joe [National Taiwan University of Science & Technology, Tapei (Taiwan)

    2015-01-01T23:59:59.000Z

    Rhodium sulfide (Rh2S3) on carbon support was synthesized by refluxing rhodium chloride with ammonium thiosulfate. Thermal treatment of Rh2S3 at high temperatures (600°C to 850°C) in presence of argon resulted in the transformation of Rh2S3 into Rh3S4, Rh17S15 and Rh which were characterized by TGA/DTA, XRD, EDX, and deconvolved XPS analyses. The catalyst particle size distribution ranged from 3 to 12 nm. Cyclic voltammetry and rotating disk electrode measurements were used to evaluate the catalytic activity for hydrogen oxidation and evolution reactions in H2SO4 and HBr solutions. The thermally treated catalysts show high activity for the hydrogen reactions. The exchange current densities (io) of the synthesized RhxSy catalysts in H2-saturated 1M H2SO4 and 1M HBr for HER and HOR were 0.9 mA/cm2 to 1.0 mA/cm2 and 0.8 to 0.9 mA/cm2, respectively. The lower io values obtained in 1M HBr solution compared to in H2SO4 might be due to the adsorption of Br- on the active surface. Stable electrochemical active surface area (ECSA) of RhxSy catalyst was obtained for CV scan limits between 0 V and 0.65 V vs. RHE. Scans with upper voltage limit beyond 0.65 V led to decreased and unreproducible ECSA measurements.

  2. Highly Active and Stable MgAl2O4 Supported Rh and Ir Catalysts for Methane Steam Reforming: A Combined Experimental and Theoretical Study

    SciTech Connect (OSTI)

    Mei, Donghai; Glezakou, Vassiliki Alexandra; Lebarbier, Vanessa MC; Kovarik, Libor; Wan, Haiying; Albrecht, Karl O.; Gerber, Mark A.; Rousseau, Roger J.; Dagle, Robert A.

    2014-07-01T23:59:59.000Z

    In this work we present a combined experimental and theoretical investigation of stable MgAl2O4 spinel-supported Rh and Ir catalysts for the steam methane reforming (SMR) reaction. Firstly, catalytic performance for a series of noble metal catalysts supported on MgAl2O4 spinel was evaluated for SMR at 600-850°C. Turnover rate at 850°C follows the order: Pd > Pt > Ir > Rh > Ru > Ni. However, Rh and Ir were found to have the best combination of activity and stability for methane steam reforming in the presence of simulated biomass-derived syngas. It was found that highly dispersed ~2 nm Rh and ~1 nm Ir clusters were formed on the MgAl2O4 spinel support. Scanning Transition Electron Microscopy (STEM) images show that excellent dispersion was maintained even under challenging high temperature conditions (e.g. at 850°C in the presence of steam) while Ir and Rh catalysts supported on Al2O3 were observed to sinter at increased rates under the same conditions. These observations were further confirmed by ab initio molecular dynamics (AIMD) simulations which find that ~1 nm Rh and Ir particles (50-atom cluster) bind strongly to the MgAl2O4 surfaces via a redox process leading to a strong metal-support interaction, thus helping anchor the metal clusters and reduce the tendency to sinter. Density functional theory (DFT) calculations suggest that these supported smaller Rh and Ir particles have a lower work function than larger more bulk-like ones, which enables them to activate both water and methane more effectively than larger particles, yet have a minimal influence on the relative stability of coke precursors. In addition, theoretical mechanistic studies were used to probe the relationship between structure and reactivity. Consistent with the experimental observations, our theoretical modeling results also suggest that the small spinel-supported Ir particle catalyst is more active than the counterpart of Rh catalyst for SMR. This work was financially supported by the United States Department of Energy (DOE)’s Bioenergy Technologies Office (BETO) and performed at the Pacific Northwest National Laboratory (PNNL). PNNL is a multi-program national laboratory operated for DOE by Battelle Memorial Institute. Computing time was granted by a user proposal at the Molecular Science Computing Facility in the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL) located at PNNL. Part of the computational time was provided by the National Energy Research Scientific Computing Center (NERSC).

  3. Figure S1.Technical diagram of the 1-by-3 tandem differential mobility analyzer (cf. schematic diagram shown in Figure 1). Relative humidity sensors are located at positions RH,

    E-Print Network [OSTI]

    DMAmono, and after the efflorescence test of RH0 - back to RH0 ( = 5). The three rows successively show mobility diameter. Distributions having aqueous particles are shown in red and those having solid particles humidity generation a. Aerosol generation 20 20 Ejector Pump Excess Nebulizer OR Mixing region ORVB VB

  4. Effect of process variables on the density and durability of the pellets made from high moisture corn stover

    SciTech Connect (OSTI)

    Jaya Shankar Tumuluru

    2014-03-01T23:59:59.000Z

    A flat die pellet mill was used to understand the effect of high levels of feedstock moisture content in the range of 28–38% (w.b.), with die rotational speeds of 40–60 Hz, and preheating temperatures of 30–110 °C on the pelleting characteristics of 4.8 mm screen size ground corn stover using an 8 mm pellet die. The physical properties of the pelletised biomass studied are: (a) pellet moisture content, (b) unit, bulk and tapped density, and (c) durability. Pelletisation experiments were conducted based on central composite design. Analysis of variance (ANOVA) indicated that feedstock moisture content influenced all of the physical properties at P < 0.001. Pellet moisture content decreased with increase in preheating temperature to about 110 °C and decreasing the feedstock moisture content to about 28% (w.b.). Response surface models developed for quality attributes with respect to process variables has adequately described the process with coefficient of determination (R2) values of >0.88. The other pellet quality attributes such as unit, bulk, tapped density, were maximised at feedstock moisture content of 30–33% (w.b.), die speeds of >50 Hz and preheating temperature of >90 °C. In case of durability a medium moisture content of 33–34% (w.b.) and preheating temperatures of >70 °C and higher die speeds >50 Hz resulted in high durable pellets. It can be concluded from the present study that feedstock moisture content, followed by preheating, and die rotational speed are the interacting process variables influencing pellet moisture content, unit, bulk and tapped density and durability.

  5. Oxidation of Methanol on 2nd and 3rd Row Group VIII Transition Metals (Pt, Ir, Os, Pd, Rh, and Ru): Application to Direct Methanol

    E-Print Network [OSTI]

    Goddard III, William A.

    Oxidation of Methanol on 2nd and 3rd Row Group VIII Transition Metals (Pt, Ir, Os, Pd, Rh, and Ru): Application to Direct Methanol Fuel Cells Jeremy Kua and William A. Goddard III* Contribution from functional theory (B3LYP)], we calculated the 13 most likely intermediate species for methanol oxidation

  6. Systematics of the temperature-dependent interplane resistivity in Ba(Fe1-xMx)?As? (M=Co, Rh, Ni, and Pd)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tanatar, M. A.; Ni, N.; Thaler, A.; Bud’ko, S. L.; Canfield, P. C.; Prozorov, R.

    2011-07-01T23:59:59.000Z

    Temperature-dependent interplane resistivity ?c(T) was measured systematically as a function of transition-metal substitution in the iron-arsenide superconductors Ba(Fe1-xMx)?As?, M=Ni, Pd, Rh. The data are compared with the behavior found in Ba(Fe1-xCox)?As?, revealing resistive signatures of pseudogap. In all compounds we find resistivity crossover at a characteristic pseudogap temperature T* from nonmetallic to metallic temperature dependence on cooling. Suppression of T* proceeds very similarly in cases of Ni and Pd doping and much faster than in similar cases of Co and Rh doping. In cases of Co and Rh doping an additional minimum in the temperature-dependent ?c emerges for high dopings, when superconductivity is completely suppressed. These features are consistent with the existence of a charge gap covering part of the Fermi surface. The part of the Fermi surface affected by this gap is notably larger for Ni- and Pd-doped compositions than in Co- and Rh-doped compounds.

  7. Photocytotoxicity of a New Rh2(II,II) Complex: Increase in Cytotoxicity upon Irradiation Similar to That of PDT Agent Hematoporphyrin

    E-Print Network [OSTI]

    Turro, Claudia

    Photocytotoxicity of a New Rh2(II,II) Complex: Increase in Cytotoxicity upon Irradiation Similar, Texas 77842, and Food and Drug Administration, College Park, Maryland 20740 Received January 17, 2005- calating complex 1 towards Hs-27 human skin cells in the dark and upon irradiation with visible light

  8. Tuning the Curie temperature of L1{sub 0} ordered FePt thin films through site-specific substitution of Rh

    SciTech Connect (OSTI)

    Xu, Dongbin, E-mail: dongbin.xu@seagate.com [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Department of Materials Science and Engineering, National University of Singapore, Singapore 117576 (Singapore); Sun, Cheng-Jun, E-mail: cjsun@aps.anl.gov, E-mail: msecgm@nus.edu.sg; Heald, Steve M. [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Chen, Jing-Sheng; Chow, Gan Moog, E-mail: cjsun@aps.anl.gov, E-mail: msecgm@nus.edu.sg [Department of Materials Science and Engineering, National University of Singapore, Singapore 117576 (Singapore); Zhou, Tie-Jun [Data Storage Institute, Agency for Science, Technology and Research (A-STAR), Singapore 117608 (Singapore); Bergman, Anders; Sanyal, Biplab [Department of Physics and Astronomy, Uppsala University, Box 516, 751 20 Uppsala (Sweden)

    2014-10-14T23:59:59.000Z

    In structurally ordered magnetic thin films, the Curie temperature (T{sub C}) of ferromagnetic films depends on the exchange integral of the short range ordered neighboring atoms. The exchange integral may be adjusted by controlling the elemental substitutional concentration at the lattice site of interest. We show how to control the T{sub C} in high anisotropy L1{sub 0} Fe{sub 50}Pt{sub 50} magnetic thin films by substituting Rh into the Pt site. Rh substitution in L1{sub 0} FePt modified the local atomic environment and the corresponding electronic properties, while retaining the ordered L1{sub 0} phase. The analysis of extended x-ray Absorption Fine Structure spectra shows that Rh uniformly substitutes for Pt in L1{sub 0} FePt. A model of antiferromagnetic defects caused by controlled Rh substitution of the Pt site, reducing the T{sub C,} is proposed to interpret this phenomenon and its validity is further examined by ab initio density functional calculations.

  9. Syntheses, crystal structures, and properties of EuRhIn, EuIr{sub 2}, and EuIrSn{sub 2}

    SciTech Connect (OSTI)

    Poettgen, R.; Hoffmann, R.D.; Moeller, M.H.; Kotzyba, G.; Kuennen, B.; Rosenhahn, C.; Mosel, B.D. [Univ. Muenster (Germany)] [Univ. Muenster (Germany)

    1999-06-01T23:59:59.000Z

    The title compounds were prepared from the elements by reactions in sealed tantalum tubes in a high-frequency furnace. Their structures were refined from single crystal X-ray diffractometer data: Pnma, a = 744.4(1) pm, b = 434.15(9) pm, c = 845.5(1) pm, wR2 = 0.0433, 658 F{sup 2} values, 20 variables for EuRhIn, Rd3m, a = 756.5(1) pm, wR2 = 0.0349, 94 F{sup 2} values, 5 variables for EuIr{sub 2}, and Cmcm, a = 434.78(3) pm, b = 1124.0(1) pm, c = 751.20(5) pm, wR2 = 0.0561, 565 F{sup 2} values, 16 variables for EuIrSn{sub 2}. EuRhIn crystallizes with a TiNiSi type structure that consists of strongly puckered Rh{sub 3}In{sub 3} hexagons. The europium atoms fill the channels within the three-dimensional [RhIn] polyanion. EuRhIn orders ferromagnetically at 22.0(5) K with a saturation magnetic moment of 6.7(1) {mu}{sub B}/Eu at 4 k and 5.5 T. The divalent character of the europium atoms in EuRhIn was determined from temperature dependent susceptibility (7.9 {mu}{sub B}/Eu in the high-temperature part) and {sup 151}Eu Moessbauer spectroscopic experiments. The latter show an isomer shift of {delta} = {minus}8.30(2) mm/s at 78 K. At 4.2 K full magnetic hyperfine field splitting subjected to significant quadrupole splitting of {Delta}E{sub Q} = 8 mm/s is observed. EuRhIn is a metallic conductor with a room temperature value of 58 {micro}{Omega}cm for the specific resistivity. The structure of the Laves phase EuIr{sub 2} is confirmed on the basis of single crystal X-ray data. The iridium atoms form a tetrahedral network with Ir-Ir distances of 268 pm. EuIrSn{sub 2} adopts a MgCuAl{sub 2} type structure that may be described as an iridium-filled variant of a distorted CaIn{sub 2}-like sublattice of composition EuSn{sub 2}. The tin atoms in the distorted and puckered hexagonal network have shorter (303 and 322 pm) and longer (343 pm) tin-tin contacts. 40 refs., 9 figs., 5 tabs.

  10. Oscillations of solar atmosphere neutrinos

    E-Print Network [OSTI]

    G. L. Fogli; E. Lisi; A. Mirizzi; D. Montanino; P. D. Serpico

    2006-11-10T23:59:59.000Z

    The Sun is a source of high energy neutrinos (E > 10 GeV) produced by cosmic ray interactions in the solar atmosphere. We study the impact of three-flavor oscillations (in vacuum and in matter) on solar atmosphere neutrinos, and calculate their observable fluxes at Earth, as well as their event rates in a kilometer-scale detector in water or ice. We find that peculiar three-flavor oscillation effects in matter, which can occur in the energy range probed by solar atmosphere neutrinos, are significantly suppressed by averaging over the production region and over the neutrino and antineutrino components. In particular, we find that the relation between the neutrino fluxes at the Sun and at the Earth can be approximately expressed in terms of phase-averaged ``vacuum'' oscillations, dominated by a single mixing parameter (the angle theta_23).

  11. Cumulant expansions for atmospheric flows

    E-Print Network [OSTI]

    Ait-Chaalal, Farid; Meyer, Bettina; Marston, J B

    2015-01-01T23:59:59.000Z

    The equations governing atmospheric flows are nonlinear, and consequently the hierarchy of cumulant equations is not closed. But because atmospheric flows are inhomogeneous and anisotropic, the nonlinearity may manifests itself only weakly through interactions of mean fields with disturbances such as thermals or eddies. In such situations, truncations of the hierarchy of cumulant equations hold promise as a closure strategy. We review how truncations at second order can be used to model and elucidate the dynamics of turbulent atmospheric flows. Two examples are considered. First, we study the growth of a dry convective boundary layer, which is heated from below, leading to turbulent upward energy transport and growth of the boundary layer. We demonstrate that a quasilinear truncation of the equations of motion, in which interactions of disturbances among each other are neglected but interactions with mean fields are taken into account, can successfully capture the growth of the convective boundary layer. Seco...

  12. Substrate Moisture Content Effects on Growth and Shelf Life of Angelonia angustifolia

    E-Print Network [OSTI]

    Bingham, Alison

    2012-07-16T23:59:59.000Z

    [Impatiens walleriana (Hook.)], petunia, salvia [Salvia splendens Sellow (ex Roemer & J.A. Schultes)] and vinca [Catharanthus roseus (L.) G. Don.] for an extended period of time despite varying plant sizes with little to no runoff and wastage of water... moisture sensors and solenoid valves interfaced to an irrigation controller. When ? dropped below the set point, the controller opened solenoid valves and the impatiens, petunias, salvia, and vinca were irrigated and substrate water content was returned...

  13. Influence of Airflow on Laboratory Storage of High Moisture Corn Stover

    SciTech Connect (OSTI)

    Lynn M. Wendt; Ian J. Bonner; Amber N. Hoover; Rachel M. Emerson; William A. Smith

    2014-04-01T23:59:59.000Z

    Storing high moisture biomass for bioenergy use is a reality in many areas of the country where wet harvest conditions and environmental factors prevent dry storage from being feasible. Aerobic storage of high moisture biomass leads to microbial degradation and self-heating, but oxygen limitation can aid in material preservation. To understand the influence of oxygen presence on high moisture biomass (50 %, wet basis), three airflow rates were tested on corn stover stored in laboratory reactors. Temperature, carbon dioxide production, dry matter loss, chemical composition, fungal abundance, pH, and organic acids were used to monitor the effects of airflow on storage conditions. The results of this work indicate that oxygen availability impacts both the duration of self-heating and the severity of dry matter loss. High airflow systems experienced the greatest initial rates of loss but a shortened microbially active period that limited total dry matter loss (19 %). Intermediate airflow had improved preservation in short-term storage compared to high airflow systems but accumulated the greatest dry matter loss over time (up to 27 %) as a result of an extended microbially active period. Low airflow systems displayed the best performance with the lowest rates of loss and total loss (10 %) in storage at 50 days. Total structural sugar levels of the stored material were preserved, although glucan enrichment and xylan loss were documented in the high and intermediate flow conditions. By understanding the role of oxygen availability on biomass storage performance, the requirements for high moisture storage solutions may begin to be experimentally defined.

  14. Biochemical changes in the proteins of sorghum grain during moisture reconstitution

    E-Print Network [OSTI]

    Billings, Toby Jackson

    1972-01-01T23:59:59.000Z

    MICROORGANISM INHABITING SORGHUM GRAIN AFTER RECONSTITUTION Medium Growth Acid Gas MR VP Nitrate Reduction Mannose yes yes no Glucose yes yes no Sucrose yes no no Gal actos e yes yes no Mannitol Starch Maltose yes yes yes no no yes...BIOCHEMICAL CHANGES IN THE PROTEINS OF SORGHUM GRAIN DURING MOISTURE RECONSTITUTION A Thesis by TOBY JACKSON BILLINGS Submitted to the Graduate College of the Texas A&M University in partial fulfillment of the requirement for the degree...

  15. Effect of external stress on moisture diffusion in an epoxy resin and its composite material 

    E-Print Network [OSTI]

    Henson, Michael Chamberlain

    1986-01-01T23:59:59.000Z

    ) Michael Chamberlain Henson, B. S. , Texas A&N University Chairman of Advisory Comnittee: Dr. Y. Weitsman The effects of stress on moisture diffusion in a graphite epoxy composrte material have been studied experimentally by examining the correspondrng... diffusion at all stress levels while the graphite epoxy generated results indicative of Non-Fickean, . concentration dependent diffusion at different levels of stress. The external stress affected both materials in a similar manner, causing...

  16. Effect of an external stress on moisture diffusion in composite materials 

    E-Print Network [OSTI]

    Porth, Edward John

    1983-01-01T23:59:59.000Z

    . . 49 LIST OF FIGURES Figure Page Cure Cycle for Hexcel F155 Graphite/Epoxy. . Cure Cycle for Narmco M329-7 Adhesive. Final Configuration of the Graphite/Epoxy and Stainless Steel Tensile Coupons. Load Frame Used to Stress Tensile Coupons During...-ply laminates absorbed more moisture than unidirectional laminates. However, it was also noted that cross-ply laminates are less compact than unidirectional laminates. Gillat and Broutman [5] subjected bidirectional graphite/epoxy laminates to external loads...

  17. Moisture performance of sealed attics in the mixed-humid climate

    SciTech Connect (OSTI)

    Boudreaux, Philip R [ORNL; Pallin, Simon B [ORNL; Jackson, Roderick K [ORNL

    2013-12-01T23:59:59.000Z

    Oak Ridge National Laboratory studied 8 homes in the mixed-humid climate, 4 with vented attics and 4 with sealed attics. ORNL wanted to understand the moisture performance of the sealed attic and how it affected the interior environment. We found that the attic and interior of sealed attic homes were more humid than the attic and interior observed in vented attic homes. This is due to the lack of ventilation in the sealed attic. Historically attics have been vented to dehumidify the attic and interior of the home. A sealed attic design greatly reduces the venting potential and thus this drying pathway and can cause elevated interior moisture over a vented attic home. Despite the elevated attic and interior moisture in the sealed attic homes, so far no mold or material degradation has been found. The roof sheathing moisture content has stayed below 20%, indicating low potential for material degradation. Also the relative humidity at the roof sheathing has stayed within the ASHRAE 160 design criteria except for a short time during the 2011/2012 winter. This was due to a combination of the sealed attic design (minimal venting to the outside) and the duct work not being operated in the attic which usually provides a dehumidification pathway. It was also found that when the humidity was controlled using the HVAC system, it resulted in 7% more cooling energy consumption. In the mixed-humid climate this reduces the cost effectiveness of the sealed attic design as a solution for bringing ducts into a semi-conditioned space. Because of this we are recommending the other alternatives be used to bringing ducts into the conditioned space in both new construction and retrofit work in the mixed-humid climate.

  18. Preliminary non-destructive assessment of moisture content, hydration and dielectric properties of Portland cement concrete

    E-Print Network [OSTI]

    Avelar Lezama, Ivan

    2007-04-25T23:59:59.000Z

    PRELIMINARY NON-DESTRUCTIVE ASSESSMENT OF MOISTURE CONTENT, HYDRATION AND DIELECTRIC PROPERTIES OF PORTLAND CEMENT CONCRETE A Thesis by IVAN AVELAR LEZAMA Submitted to the Office of Graduate Studies of Texas A... AND DIELECTRIC PROPERTIES OF PORTLAND CEMENT CONCRETE A Thesis by IVAN AVELAR LEZAMA Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE...

  19. Size reduction of high- and low-moisture corn stalks by linear knife grid system

    SciTech Connect (OSTI)

    Womac, A.R. [University of Tennessee; Igathinathane, C. [Mississippi State University (MSU); Sokhansanj, Shahabaddine [ORNL; Narayan, S. [First American Scientific Co.

    2009-04-01T23:59:59.000Z

    High- and low-moisture corn stalks were tested using a linear knife grid size reduction device developed for first-stage size reduction. The device was used in conjunction with a universal test machine that quantified shearing stress and energy characteristics for forcing a bed of corn stalks through a grid of sharp knives. No published engineering performance data for corn stover with similar devices are available to optimize performance; however, commercial knife grid systems exist for forage size reduction. From the force displacement data, mean and maximum ultimate shear stresses, cumulative and peak mass-based cutting energies for corn stalks, and mean new surface area-based cutting energies were determined from 4 5 refill runs at two moisture contents (78.8% and 11.3% wet basis), three knife grid spacings (25.4, 50.8, and 101.6 mm), and three bed depths (50.8, 101.6, and 152.4 mm). In general, the results indicated that peak failure load, ultimate shear stress, and cutting energy values varied directly with bed depth and inversely with knife grid spacing. Mean separation analysis established that high- and low-moisture conditions and bed depths 101.6 mm did not differ significantly (P < 0.05) for ultimate stress and cutting energy values, but knife grid spacing were significantly different. Linear knife grid cutting energy requirements for both moisture conditions of corn stalks were much smaller than reported cutting energy requirements. Ultimate shear stress and cutting energy results of this research should aid the engineering design of commercial scale linear knife gird size reduction equipment for various biomass feedstocks.

  20. Tertiary nitrogen heterocyclic material to reduce moisture-induced damage in asphalt-aggregate mixtures

    DOE Patents [OSTI]

    Plancher, Henry (Laramie, WY); Petersen, Joseph C. (Laramie, WY)

    1982-01-01T23:59:59.000Z

    Asphalt-aggregate roads crack when subjected to freezing and thawing cycles. Herein, the useful life of asphalts are substantially improved by a minor amount of a moisture damage inhibiting agent selected from compounds having a pyridine moiety, including acid salts of such compounds. A shale oil fraction may serve as the source of the improving agent and may simply be blended with conventional petroleum asphalts.

  1. Impact of Hillslope-Scale Organization of Topography, Soil Moisture, Soil Temperature, and Vegetation on Modeling Surface Microwave Radiation Emission

    E-Print Network [OSTI]

    Flores, Alejandro N.

    Microwave radiometry will emerge as an important tool for global remote sensing of near-surface soil moisture in the coming decade. In this modeling study, we find that hillslope-scale topography (tens of meters) influences ...

  2. Dynamic Analysis of Moisture Transport Through Walls and Associated Cooling Loads in the Hot/Humid Climate of Florianopolis, Brazil

    E-Print Network [OSTI]

    Mendes, N.; Winkelmann, F. C.; Lamberts, R.; Philippi, P. C.; Da Cunha, Neto, J. A. B.

    1996-01-01T23:59:59.000Z

    We describe the use of a dynamic model of combined heat and mass transfer to analyze the effects on cooling loads of transient moisture storage and transport through walls with porous building materials, under varying boundary conditions...

  3. A wireless soil moisture smart sensor web using physics-based optimal control: Concept and initial demonstrations

    E-Print Network [OSTI]

    Moghaddam, Mahta

    This paper introduces a new concept for a smart wireless sensor web technology for optimal measurements of surface-to-depth profiles of soil moisture using in-situ sensors. The objective of the technology, supported by the ...

  4. Moisture and temperature effects on curvature of anti-symmetric cross-ply graphite/epoxy laminates 

    E-Print Network [OSTI]

    Lott, Randall Stephen

    1980-01-01T23:59:59.000Z

    MOISTURE AND TEMPERATURE EFFECTS ON CURVATURE OF ANTI-SYMMETRIC CROSS-PLY GRAPHITE/EPOXY LAMINATES A Thesis by RANDALL STEPHEN LOTT Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement... for the degree of MASTER OF SCIENCE December 1980 Major Subject: Mechanical Engineering MOISTURE AND TEMPERATURE EFFECTS ON CURVATURE OF ANTI-SYMMETRIC CROSS-PLY GRAPHITE/EPOXY LAMINATES A Thesis by RANDALL STEPHEN LOTT Approved as to style and content...

  5. HEATING THE ATMOSPHERE ABOVE SUNSPOTS

    E-Print Network [OSTI]

    Rucklidge, Alastair

    become fragmented and twisted, and where they generate the necessary energy to heat the solar coronaHEATING THE ATMOSPHERE ABOVE SUNSPOTS David Alexander and Neal E. Hurlburt Lockheed Martin Solar, University of Cambridge, Cambridge, CB3 9EW, UK Abstract We present our results of a hybrid model of sunspots

  6. Space Science: Atmosphere Thermal Structure

    E-Print Network [OSTI]

    Johnson, Robert E.

    Space Science: Atmosphere Part -2 Thermal Structure Review tropospheres Absorption of Radiation Adiabatic Lapse Rate ~ 9 K/km Slightly smaller than our estimate Pressure ~3000ft under ocean surface thickness (positive up) is the solar zenith angle Fs is the solar energy flux at frequency (when

  7. Method and apparatus for simulating atmospheric absorption of solar energy due to water vapor and CO{sub 2}

    DOE Patents [OSTI]

    Sopori, B.L.

    1995-06-20T23:59:59.000Z

    A method and apparatus for improving the accuracy of the simulation of sunlight reaching the earth`s surface includes a relatively small heated chamber having an optical inlet and an optical outlet, the chamber having a cavity that can be filled with a heated stream of CO{sub 2} and water vapor. A simulated beam comprising infrared and near infrared light can be directed through the chamber cavity containing the CO{sub 2} and water vapor, whereby the spectral characteristics of the beam are altered so that the output beam from the chamber contains wavelength bands that accurately replicate atmospheric absorption of solar energy due to atmospheric CO{sub 2} and moisture. 8 figs.

  8. atmospheric chemical vapour: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    data from ambient moisture have required complicated on a battery-operated Stirling cycle cooler, which is simple to operate, does not require any consumables Yakir, Dan...

  9. atmospheric water vapour: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    transmission spectrum. We used two different ESO spectrographs to take penumbra and umbra high-resolution spectra from 3100 to 10400AA. A change in moisture above the...

  10. Sulfuryl fluoride in the global atmosphere

    E-Print Network [OSTI]

    Muhle, J.

    The first calibrated high-frequency, high-precision, in situ atmospheric and archived air measurements of the fumigant sulfuryl fluoride (SO[subscript 2]F[subscript 2]) have been made as part of the Advanced Global Atmospheric ...

  11. ATMOSPHERIC SCIENCE LETTERS Atmos. Sci. Let. (2012)

    E-Print Network [OSTI]

    Gerber, Edwin

    2012-01-01T23:59:59.000Z

    ATMOSPHERIC SCIENCE LETTERS Atmos. Sci. Let. (2012) Published online in Wiley Online Library using National Centers for Environmental Prediction/National Center for Atmospheric Research (NCEP) concentrations and sea- surface temperatures (SSTs). These integrations enable the relative role of ozone

  12. Al{sub 2}O{sub 3} multi-density layer structure as a moisture permeation barrier deposited by radio frequency remote plasma atomic layer deposition

    SciTech Connect (OSTI)

    Jung, Hyunsoo [Division of Materials Science and Engineering, Hanyang University, Seoul 133-791 (Korea, Republic of); Samsung Display Co. Ltd., Tangjeong, Chungcheongnam-Do 336-741 (Korea, Republic of); Jeon, Heeyoung [Department of Nano-scale Semiconductor Engineering, Hanyang University, Seoul 133-791 (Korea, Republic of); Choi, Hagyoung; Ham, Giyul; Shin, Seokyoon [Division of Materials Science and Engineering, Hanyang University, Seoul 133-791 (Korea, Republic of); Jeon, Hyeongtag, E-mail: hjeon@hanyang.ac.kr [Division of Materials Science and Engineering, Hanyang University, Seoul 133-791 (Korea, Republic of); Department of Nano-scale Semiconductor Engineering, Hanyang University, Seoul 133-791 (Korea, Republic of)

    2014-02-21T23:59:59.000Z

    Al{sub 2}O{sub 3} films deposited by remote plasma atomic layer deposition have been used for thin film encapsulation of organic light emitting diode. In this study, a multi-density layer structure consisting of two Al{sub 2}O{sub 3} layers with different densities are deposited with different deposition conditions of O{sub 2} plasma reactant time. This structure improves moisture permeation barrier characteristics, as confirmed by a water vapor transmission rate (WVTR) test. The lowest WVTR of the multi-density layer structure was 4.7 × 10{sup ?5} gm{sup ?2} day{sup ?1}, which is one order of magnitude less than WVTR for the reference single-density Al{sub 2}O{sub 3} layer. This improvement is attributed to the location mismatch of paths for atmospheric gases, such as O{sub 2} and H{sub 2}O, in the film due to different densities in the layers. This mechanism is analyzed by high resolution transmission electron microscopy, elastic recoil detection, and angle resolved X-ray photoelectron spectroscopy. These results confirmed that the multi-density layer structure exhibits very good characteristics as an encapsulation layer via location mismatch of paths for H{sub 2}O and O{sub 2} between the two layers.

  13. 1997 Atmospheric Chemistry Colloquium for Emerging Senior Scientists

    SciTech Connect (OSTI)

    Paul H. Wine

    1998-11-23T23:59:59.000Z

    DOE's Atmospheric Chemistry Program is providing partial funding for the Atmospheric Chemistry Colloquium for Emerging Senior Scientists (ACCESS) and FY 1997 Gordon Research Conference in Atmospheric Chemistry

  14. atmospheric nitrogen fluorescence: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: Greenhouse Effect and Atmospheric Warming Atmosphere absorbs heat energy A real greenhouse traps heatCh4. Atmosphere and Surface Energy Balances...

  15. atmospheric energy redistribution: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    16 Ch4. Atmosphere and Surface Energy Balances Geosciences Websites Summary: Greenhouse Effect and Atmospheric Warming Atmosphere absorbs heat energy A real greenhouse traps...

  16. atmospheric pressure surface: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    K. 27 Ch4. Atmosphere and Surface Energy Balances Geosciences Websites Summary: Greenhouse Effect and Atmospheric Warming Atmosphere absorbs heat energy A real greenhouse traps...

  17. Radar range measurements in the atmosphere.

    SciTech Connect (OSTI)

    Doerry, Armin Walter

    2013-02-01T23:59:59.000Z

    The earth's atmosphere affects the velocity of propagation of microwave signals. This imparts a range error to radar range measurements that assume the typical simplistic model for propagation velocity. This range error is a function of atmospheric constituents, such as water vapor, as well as the geometry of the radar data collection, notably altitude and range. Models are presented for calculating atmospheric effects on radar range measurements, and compared against more elaborate atmospheric models.

  18. Sampling and characterization of aerosols formed in the atmospheric hydrolysis of UF/sub 6/

    SciTech Connect (OSTI)

    Bostick, W.D.; McCulla, W.H.; Pickrell, P.W.; Branam, D.A.

    1983-01-01T23:59:59.000Z

    When gaseous UF/sub 6/ is released into the atmosphere, it rapidly reacts with ambient moisture to form an aerosol of uranyl fluoride and HF. As part of our Safety Analysis program, we have performed several experimental releases of UF/sub 6/ (from natural uranium) in contained volumes in order to investigate techniques for sampling and characterizing the aerosol materials. The aggregrate particle morphology and size distribution have been found to be dependent upon several conditions, including the relative humidity at the time of the release and the elapse time after the release. Aerosol composition and settling rate have been investigated using isokinetic samplers for the separate collection of UO/sub 2/F/sub 2/ and HF, and via laser spectroscopic remote sensing (Mie scatter and infrared spectroscopy). 8 references.

  19. Sampling, characterization, and remote sensing of aerosols formed in the atmospheric hydrolysis of uranium hexafluoride

    SciTech Connect (OSTI)

    Bostick, W.D.; McCulla, W.H.; Pickrell, P.W.

    1984-05-01T23:59:59.000Z

    When gaseous uranium hexafluoride (UF/sub 6/) is released into the atmosphere, it rapidly reacts with ambient moisture to form an aerosol of uranyl fluoride (UO/sub 2/F/sub 2/) and hydrogen fluoride (HF). As part of our Safety Analysis program, we have performed several experimental releases of HF/sub 6/ in contained volumes in order to investigate techniques for sampling and characterizing the aerosol materials. The aggregate particle morphology and size distribution have been found to be dependent upon several conditions, including the temperature of the UF/sub 6/ at the time of its release, the relative humidity of the air into which it is released, and the elapsed time after the release. Aerosol composition and settling rate have been investigated using stationary samplers for the separate collection of UO/sub 2/F/sub 2/ and HF and via laser spectroscopic remote sensing (Mie scatter and infrared spectroscopy). 25 refs., 16 figs., 5 tabs.

  20. Proof of the Atmospheric Greenhouse Effect

    E-Print Network [OSTI]

    Smith, Arthur P

    2008-01-01T23:59:59.000Z

    A recently advanced argument against the atmospheric greenhouse effect is refuted. A planet without an infrared absorbing atmosphere is mathematically constrained to have an average temperature less than or equal to the effective radiating temperature. Observed parameters for Earth prove that without infrared absorption by the atmosphere, the average temperature of Earth's surface would be at least 33 K lower than what is observed.

  1. Atmospheric Lifetime of Fossil Fuel Carbon Dioxide

    E-Print Network [OSTI]

    Scherer, Norbert F.

    Atmospheric Lifetime of Fossil Fuel Carbon Dioxide David Archer,1 Michael Eby,2 Victor Brovkin,3 released from combustion of fossil fuels equilibrates among the various carbon reservoirs of the atmosphere literature on the atmospheric lifetime of fossil fuel CO2 and its impact on climate, and we present initial

  2. Atmospheric-pressure plasma jet

    DOE Patents [OSTI]

    Selwyn, Gary S. (Los Alamos, NM)

    1999-01-01T23:59:59.000Z

    Atmospheric-pressure plasma jet. A .gamma.-mode, resonant-cavity plasma discharge that can be operated at atmospheric pressure and near room temperature using 13.56 MHz rf power is described. Unlike plasma torches, the discharge produces a gas-phase effluent no hotter than 250.degree. C. at an applied power of about 300 W, and shows distinct non-thermal characteristics. In the simplest design, two concentric cylindrical electrodes are employed to generate a plasma in the annular region therebetween. A "jet" of long-lived metastable and reactive species that are capable of rapidly cleaning or etching metals and other materials is generated which extends up to 8 in. beyond the open end of the electrodes. Films and coatings may also be removed by these species. Arcing is prevented in the apparatus by using gas mixtures containing He, which limits ionization, by using high flow velocities, and by properly shaping the rf-powered electrode. Because of the atmospheric pressure operation, no ions survive for a sufficiently long distance beyond the active plasma discharge to bombard a workpiece, unlike low-pressure plasma sources and conventional plasma processing methods.

  3. Ternary lithium stannides Li{sub x}T{sub 3}Sn{sub 7-x} (T=Rh, Ir)

    SciTech Connect (OSTI)

    Sreeraj, Puravankara [Institut fuer Anorganische und Analytische Chemie, NRW Graduate School of Chemistry, and Sonderforschungsbereich 458, Universitaet Muenster, Corrensstrasse 30, 48149 Muenster (Germany); Kurowski, Daniel [Institut fuer Anorganische und Analytische Chemie, NRW Graduate School of Chemistry, and Sonderforschungsbereich 458, Universitaet Muenster, Corrensstrasse 30, 48149 Muenster (Germany); Hoffmann, Rolf-Dieter [Institut fuer Anorganische und Analytische Chemie, NRW Graduate School of Chemistry, and Sonderforschungsbereich 458, Universitaet Muenster, Corrensstrasse 30, 48149 Muenster (Germany); Wu Zhiyun [Institut fuer Anorganische und Analytische Chemie, NRW Graduate School of Chemistry, and Sonderforschungsbereich 458, Universitaet Muenster, Corrensstrasse 30, 48149 Muenster (Germany); Poettgen, Rainer [Institut fuer Anorganische und Analytische Chemie, NRW Graduate School of Chemistry, and Sonderforschungsbereich 458, Universitaet Muenster, Corrensstrasse 30, 48149 Muenster (Germany)]. E-mail: pottgen@uni-muenster.de

    2005-11-15T23:59:59.000Z

    The ternary stannides Li{sub x}Rh{sub 3}Sn{sub 7-x} (x=0.45, 0.64, 0.80) and Li{sub x}Ir{sub 3}Sn{sub 7-x} (x=0.62 and 0.66) were synthesized from the elements in sealed tantalum tubes in a water-cooled sample chamber of an induction furnace. The samples were characterized by X-ray diffraction on powders and single crystals. The stannides adopt the cubic Ir{sub 3}Ge{sub 7}-type structure (space group Im3-bar m, Z=4). In this structure type the tin atoms occupy the Wyckoff positions 12d and 16f and form two interpenetrating frameworks consisting of cubes and square antiprisms. The rhodium and iridium atoms center the square antiprisms and are arranged in pairs. With increasing lithium substitution the lattice parameter of Ir{sub 3}Sn{sub 7} (936.7) decreases via 932.2pm (x=0.62) to 931.2pm (x=0.66), while the Ir-Ir distance remains almost the same (290pm). A similar trend is observed for the rhodium compounds. The lithium atoms substitute Sn on both framework sites. However, the 16f site shows a substantially larger preference for Li occupation. This is in contrast to the isotypic magnesium based compounds.

  4. Kinetic and Performance Studies of the Regeneration Phase of Model Pt/Ba/Rh NOx Traps for Design and Optimization

    SciTech Connect (OSTI)

    Michael Harold; Vemuri Balakotaiah

    2010-05-31T23:59:59.000Z

    In this project a combined experimental and theoretical approach was taken to advance our understanding of lean NOx trap (LNT) technology. Fundamental kinetics studies were carried out of model LNT catalysts containing variable loadings of precious metals (Pt, Rh), and storage components (BaO, CeO{sub 2}). The Temporal Analysis of Products (TAP) reactor provided transient data under well-characterized conditions for both powder and monolith catalysts, enabling the identification of key reaction pathways and estimation of the corresponding kinetic parameters. The performance of model NOx storage and reduction (NSR) monolith catalysts were evaluated in a bench scale NOx trap using synthetic exhaust, with attention placed on the effect of the pulse timing and composition on the instantaneous and cycle-averaged product distributions. From these experiments we formulated a global model that predicts the main spatio-temporal features of the LNT and a mechanistic-based microkinetic models that incorporates a detailed understanding of the chemistry and predicts more detailed selectivity features of the LNT. The NOx trap models were used to determine its ability to simulate bench-scale data and ultimately to evaluate alternative LNT designs and operating strategies. The four-year project led to the training of several doctoral students and the dissemination of the findings as 47 presentations in conferences, catalysis societies, and academic departments as well 23 manuscripts in peer-reviewed journals. A condensed review of NOx storage and reduction was published in an encyclopedia of technology.

  5. Flexible Ultra Moisture Barrier Film for Thin-Film Photovoltaic Applications

    SciTech Connect (OSTI)

    David M. Dean

    2012-10-30T23:59:59.000Z

    Flexible Thin-film photovoltaic (TFPV) is a low cost alternative to incumbent c-Si PV products as it requires less volume of costly semiconductor materials and it can potentially reduce installation cost. Among the TFPV options, copper indium gallium diselenide (CIGS) has the highest efficiency and is believed to be one of the most attractive candidates to achieve PV cost reduction. However, CIGS cells are very moisture sensitive and require module water vapor transmission rate (WVTR) of less than 1x10-4 gram of water per square meter per day (g-H2O/m2/day). Successful development and commercialization of flexible transparent ultra moisture barrier film is the key to enable flexible CIGS TFPV products, and thus enable ultimate PV cost reduction. At DuPont, we have demonstrated at lab scale that we can successfully make polymer-based flexible transparent ultra moisture barrier film by depositing alumina on polymer films using atomic layer deposition (ALD) technology. The layer by layer ALD approach results in uniform and amorphous structure which effectively reduces pinhole density of the inorganic coating on the polymer, and thus allow the fabrication of flexible barrier film with WVTR of 10-5 g-H2O/m2/day. Currently ALD is a time-consuming process suitable only for high-value, relatively small substrates. To successfully commercialize the ALD-on-plastic technology for the PV industry, there is the need to scale up this technology and improve throughput. The goal of this contract work was to build a prototype demonstrating that the ALD technology could be scaled-up for commercial use. Unfortunately, the prototype failed to produce an ultra-barrier film by the close of the project.

  6. Moisture effects in low-slope roofs: Drying rates after water addition with various vapor retarders

    SciTech Connect (OSTI)

    Pedersen, C.R. [Technical Univ. of Denmark, Lyngby (Denmark); Petrie, T.W. [Marquette Univ., Milwaukee, WI (United States). Dept. of Mechanical Engineering; Courville, G.E.; Desjarlais, A.O.; Childs, P.W.; Wilkes, K.E. [Oak Ridge National Lab., TN (United States)

    1992-10-01T23:59:59.000Z

    Tests have been conducted in the Large Scale Climate Simulator (LSCS) of the US. Building Envelope Research Center at the Oak Ridge National Laboratory (ORNL) to investigate downward drying rates of various unvented, low-slope roof systems. A secondary objective was to study heat flow patterns so as to understand how to control latent heat effects on impermeable heat flux transducers. Nine test sections were tested simultaneously. The sections had a p deck above fibrous-glass insulation and were examples of cold-deck systems. These five sections had various vapor retarder systems on a gypsum board ceiling below the insulation. The other four sections had a lightweight insulating concrete deck below expanded polystyrene insulation and the same vapor retarder systems, and were examples of warm-deck systems. The cold-deck systems had materials that were relatively permeable to water vapor, while the materials in the warm-deck systems were less permeable. All test sections were topped by an impermeable roofing membrane. The test sections were instrumented with thermocouples between all layers and with small heat flux transducers at the bottom and top of the fibrous-glass insulation and in the middle of the expanded polystyrene insulation. Two different kinds of moisture probes were used to qualitatively monitor the movement of the moisture. The heat flux measurements showed that heat conduction dominates the system using impermeable insulation materials, with only a slight increase due to increased thermal conductivity of wet expanded polystyrene. There was significant transfer of latent heat in the test sections with permeable insulation, causing the peak heat fluxes to increase by as much as a factor of two. With temperatures imposed that are typical of summer days, latent heat transfer associated with condensation and evaporation of moisture in the test sections was measured to be as important as the heat transfer by conduction.

  7. Cavitation controlled acoustic probe for fabric spot cleaning and moisture monitoring

    DOE Patents [OSTI]

    Sheen, Shuh-Haw (Naperville, IL); Chien, Hual-Te (Naperville, IL); Raptis, Apostolos C. (Downers Grove, IL)

    1997-01-01T23:59:59.000Z

    A method and apparatus are provided for monitoring a fabric. An acoustic probe generates acoustic waves relative to the fabric. An acoustic sensor, such as an accelerometer is coupled to the acoustic probe for generating a signal representative of cavitation activity in the fabric. The generated cavitation activity representative signal is processed to indicate moisture content of the fabric. A feature of the invention is a feedback control signal is generated responsive to the generated cavitation activity representative signal. The feedback control signal can be used to control the energy level of the generated acoustic waves and to control the application of a cleaning solution to the fabric.

  8. Responses of bitterweed (Hymenoxys odorata) to 2, 4-D in relation to soil moisture

    E-Print Network [OSTI]

    Sultemeier, George Wayne

    1961-01-01T23:59:59.000Z

    aoistme for shoat three weehs battee syrayfsg with 2, ~ oa iTass 7. Taboos clay lhsdaD clay Ososa clay Valesa clog Valera else' shallow yhase Irioa alar Ceyrsssed 16. 3 1702 2$og sSoae ylents ia this sell asterisk sai yro4aee4 seek... and herbicidal aotion at time of spraying on ths several clay soil types. Mater is universally a component of soils, although ths amounts present may wary from hygrosopio to a quantity sufficient to saturate the soil. FLaM moisture samples msy be oompared...

  9. Surface soil moisture estimation with the electrically scanning microwave radiometer (ESMR)

    E-Print Network [OSTI]

    Theis, Sidney Wayne

    1979-01-01T23:59:59.000Z

    that is important in determining the ability of a plant to uptake water and that determines the state of saturation of a soil. Matric potential is very important for crop modeling and runoff prediction. Roe et al. (1971) observed that the emissivity of a mooth... that were approximately 15 to 20 cm high. For an area covered with thick turfted grass to a height of 20 cm, Barton (1978) obtained a poor relationship between soil moisture and emissivity for both the ESHR and a 2. 65-cm radiometer. The ESHR response...

  10. Phase relationship equation for moisture induced shrink and swell of soils

    E-Print Network [OSTI]

    Hoffmann, Stacey Bruemmer

    1997-01-01T23:59:59.000Z

    to the w moisture content prior to swell, a = air void coefficient equal to the ratio of air volume change (AV?) to the initial air volume (V?), n(1-S) = ratio of VA to the initial total volume (Vr). The shrinkage form of PREMISS (1. 2), also derived... in Chapter VI, is: AV hw = Sn ? (t + a, ?j r where a? = the air void constant equal to the ratio of dV? to the change in water volume (dV~). The parameters S, n and w are readily obtained from soil samples. Means of obtaining the change im water...

  11. Soil temperature, soil moisture and thaw depth, Barrow, Alaska, Ver. 1

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Sloan, V.L.; J.A. Liebig; M.S. Hahn; J.B. Curtis; J.D. Brooks; A. Rogers; C.M. Iversen; R.J. Norby

    This dataset consists of field measurements of soil properties made during 2012 and 2013 in areas A-D of Intensive Site 1 at the Next-Generation Ecosystem Experiments (NGEE) Arctic site near Barrow, Alaska. Included are i) weekly measurements of thaw depth, soil moisture, presence and depth of standing water, and soil temperature made during the 2012 and 2013 growing seasons (June - September) and ii) half-hourly measurements of soil temperature logged continuously during the period June 2012 to September 2013.

  12. Wiedemann-Franz law and nonvanishing temperature scale across the field-tuned quantum critical point of YbRh2Si2

    SciTech Connect (OSTI)

    Reid, J.-Ph. [Universite de Sherbrooke; Tanatar, Makariy [Ames Laboratory; Daou, R. [Universite de Sherbrooke; Hu, Rongwei [Brookhaven National Laboratory; Petrovic, C. [Brookhaven National Laboratory; Taillefer, Louis [Brookhaven National Laboratory

    2014-01-23T23:59:59.000Z

    The in-plane thermal conductivity kappa and electrical resistivity rho of the heavy-fermion metal YbRh2Si2 were measured down to 50 mK for magnetic fields H parallel and perpendicular to the tetragonal c axis, through the field-tuned quantum critical point H-c, at which antiferromagnetic order ends. The thermal and electrical resistivities, w L0T/kappa and rho, show a linear temperature dependence below 1 K, typical of the non-Fermi-liquid behavior found near antiferromagnetic quantum critical points, but this dependence does not persist down to T = 0. Below a characteristic temperature T-star similar or equal to 0.35 K, which depends weakly on H, w(T) and rho(T) both deviate downward and converge as T -> 0. We propose that T-star marks the onset of short-range magnetic correlations, persisting beyond H-c. By comparing samples of different purity, we conclude that the Wiedemann-Franz law holds in YbRh2Si2, even at H-c, implying that no fundamental breakdown of quasiparticle behavior occurs in this material. The overall phenomenology of heat and charge transport in YbRh2Si2 is similar to that observed in the heavy-fermion metal CeCoIn5, near its own field-tuned quantum critical point.

  13. Thermodynamic Studies of [H2Rh(diphosphine)2]+ and [HRh(diphosphine)2(CH3CN)]2+ Complexes in Acetonitrile

    SciTech Connect (OSTI)

    Aaron D. Wilson; Alexander J. M. Miller; Daniel L. DuBois; Jay A. Labinger; John E. Bercaw

    2011-04-01T23:59:59.000Z

    Thermodynamic studies of a series of [H2Rh(PP)2]+ and [HRh(PP)2(CH3CN)]2+ complexes have been carried out in acetonitrile. Seven different diphosphine (PP) ligands were selected to allow variation of the electronic properties of the ligand substituents, the cone angles, and the natural bite angles (NBAs). Oxidative addition of H2 to [Rh(PP)2]+ complexes is favored by diphosphine ligands with large NBAs, small cone angles, and electron donating substituents, with the NBA being the dominant factor. Large pKa values for [HRh(PP)2(CH3CN)]2+ complexes are favored by small ligand cone angles, small NBAs, and electron donating substituents with the cone angles playing a major role. The hydride donor abilities of [H2Rh(PP)2]+ complexes increase as the NBAs decrease, the cone angles decrease, and the electron donor abilities of the substituents increase. These results indicate that if solvent coordination is involved in hydride transfer or proton transfer reactions, the observed trends can be understood in terms of a combination of two different steric effects, NBAs and cone angles, and electron-donor effects of the ligand substituents.

  14. Thermodynamic Studies of [H2Rh(diphosphine)2]+ and [HRh(diphosphine)2(CH3CN)]2+ Complexes in Acetonitrile

    SciTech Connect (OSTI)

    Wilson, Aaron D.; Miller, Alexander J.; DuBois, Daniel L.; Labinger, Jay A.; Bercaw, John E.

    2010-04-19T23:59:59.000Z

    Thermodynamic studies of a series of [H2Rh(PP)2]+ and [HRh(PP)2(CH3CN)]2+ complexes have been carried out in acetonitrile. Seven different diphosphine (PP) ligands were selected to allow variation of the electronic properties of the ligand substituents, the cone angles, and the natural bite angles (NBAs). Oxidative addition of H2 to [Rh(PP)2]+ complexes is favored by diphosphine ligands with large NBAs, small cone angles, and electron donating substituents, with the NBA being the dominant factor. Large pKa values for [HRh(PP)2(CH3CN)]2+ complexes are favored by small ligand cone angles, small NBAs, and electron donating substituents with the cone angles playing a major role. The hydride donor abilities of [H2Rh(PP)2]+ complexes increase as the NBAs decrease, the cone angles decrease, and the electron donor abilities of the substituents increase. These results indicate that if solvent coordination is involved in hydride transfer or proton transfer reactions, the observed trends can be understood in terms of a combination of two different steric effects, NBAs and cone angles, and electron-donor effects of the ligand substituents. This work was supported by the US Department of Energy Basic Energy Sciences' Chemical Sciences, Geosciences & Biosciences Division. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.

  15. Catalyst and process development for hydrogen preparation from future fuel cell feedstocks. Quarterly progress report, October 1, 1979-December 31, 1979. [Pt/Rh, Ni/Rh, Ni/Pt/Rh, Ni, Ni/Ru, Ni/Pt, Ni/Co

    SciTech Connect (OSTI)

    Yarrington, R M; Feins, I R; Hwang, H S; Mayer, C P

    1980-01-01T23:59:59.000Z

    Twelve steam reforming catalysts were evaluated using an autothermal reforming screening unit. Duplicate tests were run with two samples to determine test variability. The samples tested contained either base metals, precious metals, or combinations of base and precious metals. The test was capable of distinguishing among samples where gross variations in composition are the main factor; for example, catalysts containing 2% by weight precious metals are more active than catalysts containing 15% by weight nickel. The results show a decrease in hydrocarbon breakthrough as the weight of nickel charged to the constant volume reactor increases. A commercial nickel catalyst, G90C, appears slightly better than some Engelhard prepared samples of equal nickel concentrations due to the higher density of G90C. Visual observation of the used catalysts show that samples containing only precious metals (Pt/Rh) did not coke during the run. The samples containing only base metals (nickel, cobalt) were coked and were magnetic. Samples containing 14.5% nickel by weight with 0.5% precious metals by weight added were not coked, were not magnetic, and had a blue colored core as compared to the black core of the virgin samples. Some speculation about deactivation mechanisms based on these observations are made.

  16. Building America Webinar: High Performance Enclosure Strategies: Part II, New Construction- August 13, 2014- Moisture Monitoring Results in an R-40 Wall

    Broader source: Energy.gov [DOE]

    This presentation, Moisture Monitoring Results in an R-40 Wall, was presented at the Building America webinar, High Performance Enclosure Strategies, Part II, on August 13, 2014.

  17. An Infrared Spectral Library for Atmospheric Environmental Monitoring...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    An Infrared Spectral Library for Atmospheric Environmental Monitoring. An Infrared Spectral Library for Atmospheric Environmental Monitoring. Abstract: Infrared (IR) spectroscopy...

  18. atmospheric research community: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    University Corporation for Atmospheric Research Geosciences Websites Summary: University Corporation for Atmospheric Research CIGNA DENTAL PREFERRED PROVIDER INSURANCE EFFECTIVE...

  19. Radius of influence for a cosmic-ray soil moisture probe : theory and Monte Carlo simulations.

    SciTech Connect (OSTI)

    Desilets, Darin

    2011-02-01T23:59:59.000Z

    The lateral footprint of a cosmic-ray soil moisture probe was determined using diffusion theory and neutron transport simulations. The footprint is radial and can be described by a single parameter, an e-folding length that is closely related to the slowing down length in air. In our work the slowing down length is defined as the crow-flight distance traveled by a neutron from nuclear emission as a fast neutron to detection at a lower energy threshold defined by the detector. Here the footprint is defined as the area encompassed by two e-fold distances, i.e. the area from which 86% of the recorded neutrons originate. The slowing down length is approximately 150 m at sea level for neutrons detected over a wide range of energies - from 10{sup 0} to 10{sup 5} eV. Both theory and simulations indicate that the slowing down length is inversely proportional to air density and linearly proportional to the height of the sensor above the ground for heights up to 100 m. Simulations suggest that the radius of influence for neutrons >1 eV is only slightly influenced by soil moisture content, and depends weakly on the energy sensitivity of the neutron detector. Good agreement between the theoretical slowing down length in air and the simulated slowing down length near the air/ground interface support the conclusion that the footprint is determined mainly by the neutron scattering properties of air.

  20. Investigation of factors influencing infrared roof moisture surveys using a mathematical model

    SciTech Connect (OSTI)

    Childs, K.W.; Courville, G.E.; Childs, P.W.

    1983-01-01T23:59:59.000Z

    In low sloped roofing systems using porous insulation, the presence of water can significantly degrade thermal performance. Because of the different thermal characteristics of wet and dry insulation, there is often a surface temperature differential between areas of wet and dry insulation. Under the right circumstances, the areas of wet insulation can be detected by means of infrared sensing techniques. To better define the conditions under which infrared techniques can distinguish between areas of wet and dry insulation, a mathematical model was developed. This model is a one-dimensional, transient heat transfer model of a roofing system. The model considers conduction through the roof, insolation, radiant exchange between roof and sky, convective heat transfer between the roof and air, and the influence of moisture trapped in insulation. For one particular roof system, a parametric study was undertaken using this model to determine the influence of moisture content, outside air temperature, wind speed, insolation, sky temperature, and other factors on the roof surface temperature. Preliminary recommendations for employing thermal sensing techniques to locate wet insulation are developed.

  1. Investigation of factors influencing infrared roof moisture surveys using a mathematical model

    SciTech Connect (OSTI)

    Childs, K.W.; Courville, G.E.; Childs, P.W.

    1984-01-01T23:59:59.000Z

    In low sloped roofing systems using porous insulation, the presence of water can significantly degrade thermal performance. Because of the different thermal characteristics of wet and dry insulation, there is often a surface temperature differential between areas of wet and dry insulation. Under the right circumstances, the areas of wet insulation can be detected by means of infrared sensing techniques. To better define the conditions under which infrared techniques can distinguish between areas of wet and dry insulation, a mathematical model was developed. This model is a one-dimensional, transient heat transfer model of a roofing system. The model considers conduction through the roof, insulation, radiant exchange between roof and sky, convective heat transfer between the roof and air, and the influence of moisture trapped in insulation. For one particular roof system, a parametric study was undertaken using this model to determine the influence of moisture content, outside air temperature, wind speed, insulation, sky temperature, and other factors on the roof surface temperature. Preliminary recommendations for employing thermal sensing techniques to locate wet insulation are developed. 11 references, 12 figures.

  2. In situ electrokinetic control of moisture and nutrients in unsaturated soils

    SciTech Connect (OSTI)

    Lindgren, E.R.; Brady, P.V.

    1994-12-31T23:59:59.000Z

    Many DOE facilities have unsaturated soils contaminated with metals and organic solvents. Because of the large volumes, in situ remediation is often the most economically attractive remediation technique. The success of many in situ treatment technologies depends critically on the degree to which the movement of water and desired ions can be engineered in the vadose zone. Bioremediation efforts in the vadose zone are limited by the ability to provide moisture and nutrients to contaminant-metabolizing microorganisms. An in situ electrokinetic remediation process has been developed at Sandia National Laboratories (SNL) for use in unsaturated soils, and is presently undergoing field demonstration. The electrokinetic process is not limited by low soil permeabilities and, therefore, provides a level of control not achievable by hydraulic means. Moisture is added to the subsurface in a controlled fashion such that the field capacity is never exceeded, preventing the unwanted mobilization of dissolved contaminants by saturated wetting fronts. The Sandia electrokinetic process can potentially transport both water and nutrients for bioremediation efforts and is compatible with vapor phase in situ techniques such as bioventing. The approach should as bioventing. The approach should lend itself to the directed transport of biodegradable chelating agents and complexed metals from contaminated soils.

  3. Pulse atmospheric fluidized bed combustion

    SciTech Connect (OSTI)

    Not Available

    1989-03-01T23:59:59.000Z

    The overall objective of the program is the development of a pulsed atmospheric fluidized-bed combustion (PAFBC) technology to burn coal and to provide heat and steam to commercial, institutional, and small industrial applications at a reasonable price in an environmentally acceptable manner. During this reporting period, a total of eight shakedown and debugging coal combustion tests were performed in the AFBC. A start-up procedure was established, system improvements implemented, and preliminary material and heat balances made based on these tests. The pulse combustor for the AFBC system was fabricated and installed and a series of tests was conducted on the system. 17 figs., 5 tabs.

  4. NETL SOFC: Atmospheric Pressure Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Saleshttp://www.fnal.gov/directorate/nalcal/nalcal02_07_05_files/nalcal.gif Directorate -AdvancedMIRTBD525AdaptingWaterTerryAtmospheric

  5. Researching Complex Heat, Air and Moisture Interactions for a Wide-Range of Building Envelope Systems and Environmental Loads

    SciTech Connect (OSTI)

    Karagiozis, A.N.

    2007-05-15T23:59:59.000Z

    This document serves as the final report documenting work completed by Oak Ridge National Laboratory (ORNL) and the Fraunhofer Institute in Building Physics (Holzkirchen, Germany) under an international CRADA No. 0575 with Fraunhofer Institute of Bauphysics of the Federal Republic of Germany for Researching Complex Heat, Air and Moisture Interactions for a Wide Range of Building Envelope Systems and Environmental Loads. This CRADA required a multi-faceted approach to building envelope research that included a moisture engineering approach by blending extensive material property analysis, laboratory system and sub-system thermal and moisture testing, and advanced moisture analysis prediction performance. The Participant's Institute for Building physics (IBP) and the Contractor's Buildings Technology Center (BTC) identified potential research projects and activities capable of accelerating and advancing the development of innovative, low energy and durable building envelope systems in diverse climates. This allowed a major leverage of the limited resources available to ORNL to execute the required Department of Energy (DOE) directives in the area of moisture engineering. A joint working group (ORNL and Fraunhofer IBP) was assembled and a research plan was executed from May 2000 to May 2005. A number of key deliverables were produced such as adoption of North American loading into the WUFI-software. in addition the ORNL Weather File Analyzer was created and this has been used to address environmental loading for a variety of US climates. At least 4 papers have been co-written with the CRADA partners, and a chapter in the ASTM Manual 40 on Moisture Analysis and Condensation Control. All deliverables and goals were met and exceeded making this collaboration a success to all parties involves.

  6. A soil moisture budget analysis of Texas using basic climatic data while assuming a possible warming trend across the state

    E-Print Network [OSTI]

    Bjornson, Brian Matthew

    1990-01-01T23:59:59.000Z

    of the slope (dashed lines) of the regression line of precipitation on mean temperature for the Lower Valley. 35. Isopleths of MTRANGE (in 'F) for Texas during August. 71 36. Percentage of monthly soil moisture (SM) for the High Plains for a O'F (control... are significant at the 95% confidence interval. 74 37. Percentage of monthly soil moisture (SM) for the High Plains for a O'F (control), I' F, 2'F, 3'F, and 4'F increase in the mean annual temperature of Texas. Mean monthly temperatures increase non...

  7. Flexible Residential Test Facility: Impact of Infiltration and Ventilation on Measured Cooling Season Energy and Moisture Levels

    SciTech Connect (OSTI)

    Parker, D.; Kono, J.; Vieira, R.; Fairey, P.; Sherwin, J.; Withers, C.; Hoak, D.; Beal, D.

    2014-05-01T23:59:59.000Z

    Air infiltration and ventilation in residential buildings is a very large part of the heating loads, but empirical data regarding the impact on space cooling has been lacking. Moreover, there has been little data on how building tightness might relate to building interior moisture levels in homes in a hot and humid climate. To address this need, BA-PIRC has conducted research to assess the moisture and cooling load impacts of airtightness and mechanical ventilation in two identical laboratory homes in the hot-humid climate over the cooling season.

  8. Soil moisture in complex terrain: quantifying effects on atmospheric boundary layer flow and providing improved surface boundary conditions for mesoscale models

    E-Print Network [OSTI]

    Daniels, Megan Hanako

    2010-01-01T23:59:59.000Z

    red indicates “water towers” generated by kinematic wavethe kinematic wave equation will begin to collect water onred indicates “water towers” generated by kinematic wave

  9. Influence of synoptic weather events on the isotopic composition of atmospheric moisture in a coastal city of the western United States

    E-Print Network [OSTI]

    Farlin, James; Lai, Chun-Ta; Yoshimura, Kei

    2013-01-01T23:59:59.000Z

    of global reanalysis, Mon. Weather Rev. , 136(8), 2983–2998.to investigate synoptic weather in?uences on air mixing inthat encompass synoptic weather cycles and extreme weather

  10. Soil moisture in complex terrain: quantifying effects on atmospheric boundary layer flow and providing improved surface boundary conditions for mesoscale models

    E-Print Network [OSTI]

    Daniels, Megan Hanako

    2010-01-01T23:59:59.000Z

    direction, (b) wind speed, (c) potential temperature, and (Airport of potential temperature, wind speed, winderrors (bias) for potential temperature, wind speed, wind

  11. Atmospheric neutrino flux at INO site

    SciTech Connect (OSTI)

    Honda, Morihiro [Institute for Cosmic Ray Research, University of Tokyo, 5-1-5 Kashiwa-no-ha, Kashiwa, Chiba 277-8582 (Japan)

    2011-11-23T23:59:59.000Z

    To illustrate the calculation of the atmospheric neutrino flux, we briefly explain our calculation scheme and important components, such as primary cosmic ray spectra, interaction model, and geomagnetic model. Then, we calculate the atmospheric neutrino flux at INO site in our calculation scheme. We compare the calculated atmospheric neutrino fluxes predicted at INO with those at other major neutrino detector sites, especially that at SK site.

  12. Toxicity of atmospheric aerosols on marine phytoplankton

    E-Print Network [OSTI]

    2009-01-01T23:59:59.000Z

    metals added from these aerosols to the bioassay incubationsreleased to seawater from the aerosol filters after Author4605 CHEMISTRY Atmospheric aerosol deposition CHEMISTRY

  13. Urban Atmospheres captures a unique, synergistic moment

    E-Print Network [OSTI]

    Paulos, Eric

    Urban Atmospheres captures a unique, synergistic moment ­ expanding urban populations, rapid EDITORS Eric Paulos Intel Research eric@paulos.net Tom Jenkins Royal College of Art thomas

  14. Characterizing orbit uncertainty due to atmospheric uncertainty

    E-Print Network [OSTI]

    Wilkins, Matthew Paul

    2000-01-01T23:59:59.000Z

    is implemented to model errors in the atmospheric density model. This study shows that the Kalman filter computes a believable and more realistic covariance....

  15. Physics Potential of Future Atmospheric Neutrino Searches

    E-Print Network [OSTI]

    Thomas Schwetz

    2008-12-12T23:59:59.000Z

    The potential of future high statistics atmospheric neutrino experiments is considered, having in mind currently discussed huge detectors of various technologies (water Cerekov, magnetized iron, liquid Argon). I focus on the possibility to use atmospheric data to determine the octant of $\\theta_{23}$ and the neutrino mass hierarchy. The sensitivity to the $\\theta_{23}$-octant of atmospheric neutrinos is competitive (or even superior) to long-baseline experiments. I discuss the ideal properties of a fictitious atmospheric neutrino detector to determine the neutrino mass hierarchy.

  16. Super-Kamiokande atmospheric neutrino results

    E-Print Network [OSTI]

    Toshiyuki Toshito; the Super-Kamiokande collaboration

    2001-05-14T23:59:59.000Z

    We present atmospheric neutrino results from a 79 kiloton year (1289 days) exposure of the Super-Kamiokande detector. Our data are well explained by $\

  17. atmospheres: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to optical depth perturbations. In Earth-type atmospheres sustained planetary greenhouse effect with a stable ground surface temperature can only exist at a particular...

  18. atmosphere: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to optical depth perturbations. In Earth-type atmospheres sustained planetary greenhouse effect with a stable ground surface temperature can only exist at a particular...

  19. atmospherics: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to optical depth perturbations. In Earth-type atmospheres sustained planetary greenhouse effect with a stable ground surface temperature can only exist at a particular...

  20. Simulation of soil moisture and evapotranspiration in a soil profile during the 1999 MAP-Riviera Campaign Hydrology and Earth System Sciences, 7(6), 903919 (2003) EGU

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    -Riviera Campaign 903 Hydrology and Earth System Sciences, 7(6), 903919 (2003) © EGU Simulation of soil moisture and evapotranspiration scheme in hydrological models. This study presents the validation of soil moisture soil plot at the edge of a corn field. The hydrological model PREVAH was driven using three

  1. An integral-balance nonlinear model to simulate changes in soil moisture, groundwater and surface runoff dynamics at the hillslope scale

    E-Print Network [OSTI]

    Jay, Laurent O.

    An integral-balance nonlinear model to simulate changes in soil moisture, groundwater and surface-state integral-balance model for soil moisture and groundwater dynamics. Development of the model was motivated. Ã? 2014 Elsevier Ltd. All rights reserved. 1. Introduction Recent studies on the modeling

  2. Response of global soil consumption of atmospheric methane to changes in atmospheric climate and nitrogen deposition

    E-Print Network [OSTI]

    Zhuang, Qianlai

    Soil consumption of atmospheric methane plays an important secondary role in regulating the atmospheric CH4 budget, next to the dominant loss mechanism involving reaction with the hydroxyl radical (OH). Here we used a ...

  3. Parallization of Stellar Atmosphere Codes

    E-Print Network [OSTI]

    P. Hoeflich

    2002-09-19T23:59:59.000Z

    Parallel computing has turned out to be the enabling technology to solve complex physical systems. However, the transition from shared memory, vector computers to massively parallel, distributed memory systems and, recently, to hybrid systems poses new challenges to the scientist. We want to present a cook-book (with a very strong, personal bias) based on our experience with parallization of our existing codes. Some of the general tools and communication libraries are discussed. Our approach includes a mixture of algorithm, domain and physical module based parallization. The advantages, scalability and limitations of each are discussed at some examples. We want show that it becomes easier to write parallel code with increasing complexity of the physical problem making stellar atmosphere codes beyond the classical assumptions very suitable.

  4. Limits to the lunar atmosphere

    SciTech Connect (OSTI)

    Morgan, T.H. (National Aeronautics and Space Administration, Washington, D.C. (USA)); Shemansky, D.E. (Univ. of Arizona, Tucson (USA))

    1991-02-01T23:59:59.000Z

    The presence of sodium and potassium on the Moon implies that other more abundant species should be present. Volatile molecules like H{sub 2}O are significantly more abundant than sodium in any of the proposed external atmospheric sources. Source mechanisms which derive atoms from the surface should favor abundant elements in the regolith. It is therefore puzzling that the Apollo ultraviolet spectrometer experiment set limits on the density of oxygen of N{sub O} < 5 {times} 10{sup 2} cm{sup {minus}3}, and that the Apollo Lunar Atmospheric Composition Experiment data imply N{sub O} < 50 cm{sup {minus}3} above the subsolar point. These limits are surprisingly small relative to the measured value for sodium. A simple consideration of sources and sinks predicts significantly greater densities of oxygen. It is possible but doubtful that the Apollo measurements occur ed during an epoch in which source rates were small. A preferential loss process for oxygen on the darkside of the Moon is considered in which ionization by electron capture in surface collisions leads to escape through acceleration in the local electric field. Cold trapping in permanently shadowed regions as a net sink is considered and discounted, but the episodic nature of cometary insertion may allow formation of ice layers which act as a stablized source of OH. On the basis of an assumed meteoroid impact source, the authors predict a possible emission brightness of {approximately} 50 R in the OH(A {minus} X)(0,0) band above the lunar bright limb. A very uncertain small comet source of H{sub 2}O could raise this value by more than two orders of magnitude.

  5. Acoustic wave (AW) based moisture sensor for use with corrosive gases

    DOE Patents [OSTI]

    Pfeifer, K.B.; Frye, G.C.; Schneider, T.W.

    1996-11-05T23:59:59.000Z

    Moisture corrosive gas stream is measured as a function of the difference in resonant frequencies between two acoustic wave (AW) devices, each with a film which accepts at least one of the components of the gas stream. One AW is located in the gas stream while the other is located outside the gas stream but in the same thermal environment. In one embodiment, the film is a hydrophilic material such as SiO{sub 2}. In another embodiment, the SiO{sub 2} is covered with another film which is impermeable to the corrosive gas, such that the AW device in the gas stream measures only the water vapor. In yet another embodiment, the film comprises polyethylene oxide which is hydrophobic and measures only the partial pressure of the corrosive gas. Other embodiments allow for compensation of drift in the system. 8 figs.

  6. Hygric Redistribution in Insulated Assemblies: Retrofitting Residential Envelopes Without Creating Moisture Issues

    SciTech Connect (OSTI)

    Smegal, J.; Lstiburek, J.

    2013-01-01T23:59:59.000Z

    The Building America program has recognized that most of the current housing stock is in need of energy related retrofits. One of the best ways of reducing the space conditioning energy consumption is to improve the thermal performance of the enclosure by adding exterior board foam insulation. This report quantifies the amount of water that can become trapped in the drainage cavity of typical wall systems, and measures the effect of water trapped in the drainage cavity on the moisture content of the sheathing. This study also attempts to explain the discrepancy between hygrothermal simulations and field performance of low permeance, low R-value exterior insulation (e.g. 3/4-in. foil faced polyisocyanurate) in cold climates.

  7. Test Plan to Evaluate the Relationship Among IAQ, Comfort, Moisture, and Ventilation in Humid Climates

    SciTech Connect (OSTI)

    Widder, Sarah H.; Martin, Eric

    2013-03-15T23:59:59.000Z

    This experimental plan describes research being conducted by Pacific Northwest National Laboratory (PNNL), in coordinatation with Florida Solar Energy Center (FSEC), Florida HERO, and Lawrence Berkeley National Laboratory (LBNL) to evaluate the impact of ventilation rate on interior moisture levels, temperature distributions, and indoor air contaminant concentrations. Specifically, the research team will measure concentrations of indoor air contaminants, ventilation system flow rates, energy consumption, and temperature and relative humidity in ten homes in Gainesville, FL to characterize indoor pollutant levels and energy consumption associated with the observed ventilation rates. PNNL and FSEC have collaboratively prepared this experimental test plan, which describes background and context for the proposed study; the experimental design; specific monitoring points, including monitoring equipment, and sampling frequency; key research questions and the associated data analysis approach; experimental logistics, including schedule, milestones, and team member contact information; and clearly identifies the roles and responsibilities of each team in support of project objectives.

  8. Sidewall tensiometer and method of determining soil moisture potential in below-grade earthen soil

    DOE Patents [OSTI]

    Hubbell, Joel M. (Idaho Falls, ID); Sisson, James B. (Idaho Falls, ID)

    2001-01-01T23:59:59.000Z

    A sidewall tensiometer to in situ determine below-grade soil moisture potential of earthen soil includes, a) a body adapted for insertion into an opening in earthen soil below grade, the body having lateral sidewalls; b) a laterally oriented porous material provided relative to the body lateral sidewalls, the laterally oriented porous material at least in part defining a fluid chamber within the body; c) a pressure a sensor in fluid communication with the fluid chamber; and d) sidewall engaging means for engaging a portion of a sidewall of an earth opening to laterally urge the porous material into hydraulic communication with earthen soil of another portion of the opening sidewall. Methods of taking tensiometric measurements are also disclosed.

  9. In situ changes in the moisture content of heated, welded tuff based on thermal neutron measurements

    SciTech Connect (OSTI)

    Ramirez, A.L.; Carlson, R.C.; Buscheck, T.A.

    1991-07-01T23:59:59.000Z

    Thermal neutron logs were collected to monitor changes in moisture content within a welded tuff rock mass heated from a borehole containing an electrical heater which remained energized for 195 days. Thermal neutron measurements were made in sampling boreholes before, during and after heating. The results generally corroborated our conceptual understanding of hydrothermal flow as well as most of the numerical modeling conducting for this study. Conceptual models have been developed in conjunction with the numerical model calculations to explain differences in the drying and re-wetting behavior above and below the heater. Numerical modeling indicated that the re-wetting of the dried-out zone was dominated by the binary diffusion of water vapor through fractures. Saturation gradients in the rock matrix resulted in relative humidity gradients which drove water vapor (primarily along fractures) back to the dried-out zone where it condensed along the fracture walls and was imbibed by the matrix. 4 refs., 28 figs.

  10. Temperature and RH Targets

    Broader source: Energy.gov [DOE]

    Presented by Vishal O Mittal of the Florida Solar Energy Center at the High Temperature Membrane Working Group Meeting, San Francisco, September 14, 2006.

  11. Microsoft Word - ORNL RH

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHighandSWPA / SPRA / USACE LMI-EFRCAddendum 1April 1,5 BONNEVILLE2NEWS

  12. Microsoft Word - SRS RH

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHighandSWPA / SPRA / USACE625 FINAL ENVIRONMENTAL ASSESSMENT2 3.670TheFOR

  13. RH TRU Waste Program

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)IntegratedSpeedingTechnicalPurchase, Delivery, andSmart SensorsData -Madison Physics

  14. RH_SRS_Shipment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's Possible forPortsmouth/Paducah47,193.70COMMUNITYResponses:December 11,

  15. Exterior Insulation Finish System (EIFS) Walls ORNL provides the tools to enable industry to engineer durable, moisture-tolerant

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    Exterior Insulation Finish System (EIFS) Walls ORNL provides the tools to enable industry the insulating value of walls and the energy efficiency of buildings. The EIFS concept came to America from in both moisture control and insulating value. EIFS's are inherently superior on thermal performance

  16. Evaluation of SMOS Retrievals of Soil Moisture over the Central United States with Currently Available In-situ Observations

    E-Print Network [OSTI]

    Robock, Alan

    SMOS retrievals by comparing them to in-situ soil moisture observations4 for the top 5 cm at several.01% of the total water on the planet [Prigent et al.,20 2005]. But soil water content is important for many reasons, such as agriculture. Soil water21 content also has an important influence on climate, as it determines

  17. Wall Design Redundancy for Improving the Moisture Performance of Building Cladding Systems in Hot-Humid Climates

    E-Print Network [OSTI]

    Graham, C. W.

    2000-01-01T23:59:59.000Z

    An investigation of approximately 4,000 buildings in the hot-humid climate locations of the United States where the potential for decay of hygroscopic building materials or corrosion of metals is moderate-to-severe found that redundant moisture...

  18. Interactive effects of vegetation, soil moisture and bulk density on depth of burning of thick organic soils

    E-Print Network [OSTI]

    Benscoter, Brian W.

    5, Canada. D University of Alberta, Department of Renewable Resources, Edmonton, AB, T6G 2H1, Canada consumption. We experimentally altered soil moisture profiles of peat monoliths collected from several. Additional keywords: bog, boreal, carbon, fire, ground-layer fuels, peat, peatland, Sphagnum, smouldering

  19. Interactive effects of vegetation, soil moisture and bulk density on depth of burning of thick organic soils

    E-Print Network [OSTI]

    Turetsky, Merritt

    5, Canada. D University of Alberta, Department of Renewable Resources, Edmonton, AB, T6G 2H1, Canada consumption. We experimentally altered soil moisture profiles of peat monoliths collected from several. Additional keywords: bog, boreal, carbon, fire, ground-layer fuels, peat, peatland, smouldering, Sphagnum

  20. A dual-pass variational data assimilation framework for estimating soil moisture profiles from AMSR-E microwave

    E-Print Network [OSTI]

    influences the partitioning of surface available energy into sensible and latent heat fluxes and henceA dual-pass variational data assimilation framework for estimating soil moisture profiles from AMSR, we have designed a dual-pass assimilation (DP-En4DVar) framework to optimize the model state

  1. Variation in soil moisture and N availability modulates carbon and water exchange in a California grassland experiment

    SciTech Connect (OSTI)

    St. Clair, S.B.; Sudderth, E.; Fischer, M.L.; Torn, M.S.; Stuart, S.; Salve, R.; Eggett, D.; Ackerly, D.

    2009-03-15T23:59:59.000Z

    Variability in the magnitude and timing of precipitation is predicted to change under future climate scenarios. The primary objective of this study was to understand how variation in precipitation patterns consisting of soil moisture pulses mixed with intermittent dry down events influence ecosystem gas fluxes. We characterized the effects of precipitation amount and timing, N availability, and plant community composition on whole ecosystem and leaf gas exchange in a California annual grassland mesocosm study system that allowed precise control of soil moisture conditions. Ecosystem CO2 and fluxes increased significantly with greater precipitation and were positively correlated with soil moisture. A repeated 10 day dry down period following 11 days of variable precipitation inputs strongly depressed net ecosystem CO2 exchange (NEE) across a range of season precipitation totals, and plant community types. Ecosystem respiration (Re), evapotranspiration (ET) and leaf level photosynthesis (Amax) showed greatest sensitivity to dry down periods in low precipitation plots. Nitrogen additions significantly increased NEE, Re and Amax, particularly as water availability was increased. These results demonstrate that N availability and intermittent periods of soil moisture deficit (across a wide range of cumulative season precipitation totals) strongly modulate ecosystem gas exchange.

  2. Real time detection of soil moisture and nitrates using on-board in-situ impedance spectroscopy

    E-Print Network [OSTI]

    Kumar, Ratnesh

    Real time detection of soil moisture and nitrates using on-board in-situ impedance spectroscopy across a pair of electrodes immersed in that medium. We make accurate measurements on soil impedance over multiple frequen- cies using an in-situ soil-sensor we have designed. The impedance values are then used

  3. SOURCE: UNIVERSITY OF CALIFORNIA PAVEMENT RESEARCH CENTER FIGURE 1 Moisture-induced stripping in asphalt treated base layer

    E-Print Network [OSTI]

    California at Berkeley, University of

    SOURCE: UNIVERSITY OF CALIFORNIA PAVEMENT RESEARCH CENTER FIGURE 1 Moisture-induced stripping in asphalt treated base layer PAVEMENT TECHNOLOGY UPDATE This Technology Transfer Program publication is provided by the University of California Pavement Research Center. The University of California Pavement

  4. 2392 IEEE TRANSACTIONS ON GEOSCIENCE AND REMOTE SENSING, VOL. 41, NO. 10, OCTOBER 2003 Soil Moisture Mapping Using ESTAR Under

    E-Print Network [OSTI]

    2392 IEEE TRANSACTIONS ON GEOSCIENCE AND REMOTE SENSING, VOL. 41, NO. 10, OCTOBER 2003 Soil of the entire region. Index Terms--Microwave, remote sensing, soil moisture. I. INTRODUCTION THE FUNDAMENTAL regional heat fluxes [15], and to validate distributed land surface models in order to study the scaling

  5. Soil animal responses to moisture availability are largely scale, not ecosystem dependent: insight from a cross-site

    E-Print Network [OSTI]

    Wall, Diana

    Soil animal responses to moisture availability are largely scale, not ecosystem dependent: insight Cruces, NM 88012, USA, 4 USDA ARS Grassland Soil and Water Research Laboratory, Temple, TX 76502, USA, 5 Abstract Climate change will result in reduced soil water availability in much of the world either due

  6. Detection of nitroesters and moisture in combustible cartridge case wall by indicator strips and instruments. Final report

    SciTech Connect (OSTI)

    Ho, C.H.; Moneyhun, J.H.; Agouridis, D.C.; Gayle, T.M.; Hurst, G.B.; Griest, W.H.

    1992-09-30T23:59:59.000Z

    Nitroester migration into the case wall from the propellant and moisture accumulation within the case have been identified as important internal and external (respectively) factors which contribute to the physical deterioration of combustible cartridge case (ccc) munitions. The latter factor also may hinder proper ignition of the ccc and cause incomplete combustion in firing. Visual indicators sensitive to these factors and affixed to ccc rounds would allow quality assurance specialists or gun crews in the field to rapidly determine the potential reliability of individual rounds. Previous work in this task identified chemistries suitable for the detection of nitroesters and moisture in the ccc wall. A version of the Griess reaction was modified for a dry colorimetric indicator which in the presence of nitroglycerin (NG) or diethyleneglycol dinitrate (DEGDN) generates a brilliant red color. Inorganic salts such as cupric chloride, which changes from brown to blue-green upon hydration, were suggested as promising visual indicators of moisture. This report describes the development and preliminary testing of prototype nitroester and moisture indicator strips, and the scoping of two instrumental techniques, infrared spectroscopy and electrical capacitance, which could lead to portable instruments for rapid and nondestructive testing of ccc in the field.

  7. Effects of cropping-system-related soil moisture and nutrient dynamics on the sustainability of semiarid dryland agriculture

    E-Print Network [OSTI]

    Norton, Jay B.

    Effects of cropping-system-related soil moisture and nutrient dynamics on the sustainability are to evaluate sustainability of conservation cropping systems in order to improve management approaches of semiarid dryland agriculture Project Summary We propose to investigate cropping-system-related soil

  8. A Pacific Moisture Conveyor Belt and Its Relationship to a Significant Precipitation Event in the Semiarid Southwestern United States

    E-Print Network [OSTI]

    Williams, Justin

    with the University of Wisconsin- Nonhydrostatic Modeling System, as well as analysis data, surface observations with different influence factors can be distinguished. 1) Close to the COL center, moist tropical air is overrun extraordinary cool season precipitation events in western North America to bands of enhanced moisture transport

  9. ., ~., t.o -., '-'~ Effect of moisture content on the composting of pig-manure sawdust litter disposed from the

    E-Print Network [OSTI]

    Tiquia-Arashiro, Sonia M.

    '- ., ~., t.o - ., '-'~ Effect of moisture content on the composting of pig-manure sawdust litter-situ composting, has been developed as one of the recommended methods in Hong Kong to treat pig waste. The system microbial biomass, which is similar to an immature compost. In order to improve the quality of the spent

  10. Influence of radar frequency on the relationship between bare surface soil moisture vertical profile and radar backscatter

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    produced from Envisat ASAR and TerraSAR-X data, acquired over bare soils with in situ measurements heterogeneity into account in the backscatter model. Key words: SAR, AIEM, soil moisture profile, bare soil hal in the L, C, and X frequency bands, empirical and semi-empirical models are often calibrated using soil

  11. Association of intracellular calcium oscillations with release of gonadotropin-releasing hormone (GnRH) from GT1-1 neuronal cells 

    E-Print Network [OSTI]

    Gilmore, Chrystal Dawn

    1999-01-01T23:59:59.000Z

    was back in Texas. Juliana Paschoal for the trips to the Camp Cooley Ranch, making sure I went out, and her friendship. I had a great time Nann Greene who is a wonderful person that was always willing to help and knew the PREP section forwards... AND SUMMARY. REFERENCES. . VITA. 4 6 7 9 11 12 15 17 20 20 21 24 24 29 32 37 38 43 58 LIST OF FIGURES FIGURE I Release of CmRH from GT1-I neuronal cells during nondepolarization and depolarization ? a comparison of four separate...

  12. Doctoral Programs Atmospheric, Oceanic & Space Sciences

    E-Print Network [OSTI]

    Eustice, Ryan

    University of Michigan Space Research Building 2455 Hayward Street Ann Arbor, MI 48109-2143 aoss Katherine E. White, Ann Arbor ©The Regents of the University of Michigan Research areas Atmospheric Science Atmospheric Dynamics Climate, Climate Modeling & Climate Change Clouds & Precipitation Paleoclimate, Ice

  13. Human effects on the global atmosphere

    SciTech Connect (OSTI)

    Johnston, H.S.

    1984-01-01T23:59:59.000Z

    This review considers whether human activities can significantly change important functions of the global atmosphere by altering the amount or distribution of certain trace species. It deals with three specific topics: stratopheric ozone, the role of species other than carbon dioxide on the greenhouse effect, and certain recently recognized atmospheric consequences of a large scale nuclear war. 64 references, 10 figures, 2 tables.

  14. ATMOSPHERIC SCIENCE LETTERS Atmos. Sci. Let. (2013)

    E-Print Network [OSTI]

    Lee, Sukyoung

    2013-01-01T23:59:59.000Z

    ATMOSPHERIC SCIENCE LETTERS Atmos. Sci. Let. (2013) Published online in Wiley Online Library Sciences, Seoul National University, Seoul, South Korea *Correspondence to: C. Yoo, Center for Atmosphere). A number of studies have shown that the MJO plays an important role in modulating the extratropical cir

  15. ATOMIC IONIZATION AND OPACITIES IN PULSAR ATMOSPHERES

    E-Print Network [OSTI]

    ATOMIC IONIZATION AND OPACITIES IN PULSAR ATMOSPHERES Hydrogen Atmospheres J. VENTURA Physics.g. Pavlov et al., 1995; Zavlin et al., 1995, 1996; #12; 2 J. VENTURA ET AL. Rajagopal and Romani, 1996 the past three years. As is well known (Canuto and Ventura, 1977; Ruder et al., 1994), the external strong

  16. Atmospheric neutrino flux calculation using the NRLMSISE00 atmospheric model

    E-Print Network [OSTI]

    Honda, M; Kajita, T; Kasahara, K; Midorikawa, S

    2015-01-01T23:59:59.000Z

    In this paper, we extend the calculation of the atmospheric neutrino flux~\\cite{hkkm2004,hkkms2006,hkkm2011} to the sites in polar and tropical regions. In our earliest full 3D-calculation~\\cite{hkkm2004}, we used DPMJET-III~\\cite{dpm} for the hadronic interaction model above 5~GeV, and NUCRIN~\\cite{nucrin} below 5~GeV. We modified DPMJET-III as in Ref.~\\cite{hkkms2006} to reproduce the experimental muon spectra better, mainly using the data observed by BESS group~\\cite{BESSTeVpHemu}. In a recent work~\\cite{hkkm2011}, we introduced JAM interaction model for the low energy hadronic interactions. JAM is a nuclear interaction model developed with PHITS (Particle and Heavy-Ion Transport code System)~\\cite{phits}. In Ref.~\\cite{hkkm2011}, we could reproduce the observed muon flux at the low energies at balloon altitude with DPMJET-III above 32 GeV and JAM below that better than the combination of DPMJET-III above 5~GeV and NUCRIN below that. Besides the interaction model, we have also improved the calculation sche...

  17. Atmospheric sampling glow discharge ionization source

    DOE Patents [OSTI]

    McLuckey, S.A.; Glish, G.L.

    1989-07-18T23:59:59.000Z

    An atmospheric sampling glow discharge ionization source that can be used in combination with an analytical instrument which operates at high vacuum, such as a mass spectrometer. The atmospheric sampling glow discharge ionization source comprises a chamber with at least one pair of electrodes disposed therein, an inlet for a gaseous sample to be analyzed and an outlet communicating with an analyzer which operates at subatmospheric pressure. The ionization chamber is maintained at a pressure below atmospheric pressure, and a voltage difference is applied across the electrodes to induce a glow discharge between the electrodes, so that molecules passing through the inlet are ionized by the glow discharge and directed into the analyzer. The ionization source accepts the sample under atmospheric pressure conditions and processes it directly into the high vacuum instrument, bridging the pressure gap and drawing off unwanted atmospheric gases. The invention also includes a method for analyzing a gaseous sample using the glow discharge ionization source described above. 3 figs.

  18. Accepted Manuscript Process modeling for soil moisture using sensor network data

    E-Print Network [OSTI]

    Clark, James S.

    in the department of Electrical Engineering, Northern Arizona University, Flagstaff, AZ 86011 , USA. 1 #12 in agriculture, per- colation, and soil chemistry. Precipitation, temperature, atmospheric demand and topography of Mathematics and Statistics, Texas Tech University, Lubbock, TX 79409, USA. A. E. Gelfand (alan

  19. Interaction between surface and atmosphere in a convective boundary layer /

    E-Print Network [OSTI]

    Garai, Anirban

    2013-01-01T23:59:59.000Z

    of cold fluid constitute most of the heat transport andevent cold air descends to the ground, heat transport fromcold air during sweep events. The convective boundary layer has a great influence on moisture transport,

  20. The Upper Atmosphere of HD17156b

    E-Print Network [OSTI]

    T. T. Koskinen; A. D. Aylward; S. Miller

    2008-11-28T23:59:59.000Z

    HD17156b is a newly-found transiting extrasolar giant planet (EGP) that orbits its G-type host star in a highly eccentric orbit (e~0.67) with an orbital semi-major axis of 0.16 AU. Its period, 21.2 Earth days, is the longest among the known transiting planets. The atmosphere of the planet undergoes a 27-fold variation in stellar irradiation during each orbit, making it an interesting subject for atmospheric modelling. We have used a three-dimensional model of the upper atmosphere and ionosphere for extrasolar gas giants in order to simulate the progress of HD17156b along its eccentric orbit. Here we present the results of these simulations and discuss the stability, circulation, and composition in its upper atmosphere. Contrary to the well-known transiting planet HD209458b, we find that the atmosphere of HD17156b is unlikely to escape hydrodynamically at any point along the orbit, even if the upper atmosphere is almost entirely composed of atomic hydrogen and H+, and infrared cooling by H3+ ions is negligible. The nature of the upper atmosphere is sensitive to to the composition of the thermosphere, and in particular to the mixing ratio of H2, as the availability of H2 regulates radiative cooling. In light of different simulations we make specific predictions about the thermosphere-ionosphere system of HD17156b that can potentially be verified by observations.

  1. Mass spectrometric approaches for chemical characterisation of atmospheric aerosols: critical

    E-Print Network [OSTI]

    Nizkorodov, Sergey

    Mass spectrometric approaches for chemical characterisation of atmospheric aerosols: critical. Atmospheric aerosols have profound effects on the environment through several physicochemical processes on the respiratory and cardiovascular systems. Understanding aerosol atmospheric chemistry and its environmental

  2. Atmospheric science encompasses meteorology and climatology, as well as fields such as atmospheric chemistry and remote sensing.Atmospheric

    E-Print Network [OSTI]

    Oceanography and Meteorology Building.The Doppler weather radar on the roof of the building is a campus Mobile Atmospheric Research and Teaching Radar (SMART-R).This radar is used in national and international

  3. Pulsed atmospheric fluidized bed combustion

    SciTech Connect (OSTI)

    Not Available

    1989-11-01T23:59:59.000Z

    In order to verify the technical feasibility of the MTCI Pulsed Atmospheric Fluidized Bed Combustor technology, a laboratory-scale system was designed, built and tested. Important aspects of the operational and performance parameters of the system were established experimentally. A considerable amount of the effort was invested in the initial task of constructing an AFBC that would represent a reasonable baseline against which the performance of the PAFBC could be compared. A summary comparison of the performance and emissions data from the MTCI 2 ft {times} 2 ft facility (AFBC and PAFBC modes) with those from conventional BFBC (taller freeboard and recycle operation) and circulating fluidized bed combustion (CFBC) units is given in Table ES-1. The comparison is for typical high-volatile bituminous coals and sorbents of average reactivity. The values indicated for BFBC and CFBC were based on published information. The AFBC unit that was designed to act as a baseline for the comparison was indeed representative of the larger units even at the smaller scale for which it was designed. The PAFBC mode exhibited superior performance in relation to the AFBC mode. The higher combustion efficiency translates into reduced coal consumption and lower system operating cost; the improvement in sulfur capture implies less sorbent requirement and waste generation and in turn lower operating cost; lower NO{sub x} and CO emissions mean ease of site permitting; and greater steam-generation rate translates into less heat exchange surface area and reduced capital cost. Also, the PAFBC performance generally surpasses those of conventional BFBC, is comparable to CFBC in combustion and NO{sub x} emissions, and is better than CFBC in sulfur capture and CO emissions even at the scaled-down size used for the experimental feasibility tests.

  4. atmospheric pressure ionization: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for Atmospheric Pressure, in Vivo, and Imaging Mass. For example, atmospheric pressure infrared MALDI (AP IR-MALDI), capable of producing ions from small ionization (DESI),5...

  5. atmospheric carbon emissions: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    oxide (N2O) 13 Paris-Sud XI, Universit de 13 Atmospheric Lifetime of Fossil Fuel Carbon Dioxide Geosciences Websites Summary: Atmospheric Lifetime of Fossil Fuel Carbon...

  6. atmospheric oxygenation recorded: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    cores may contain high quality records of atmospheric deposition. The qualitative Short, Daniel 3 Bistability of atmospheric oxygen and the Great Oxidation Geosciences Websites...

  7. atmospheric optical turbulence: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Next Page Last Page Topic Index 1 Atmospheric Turbulence and its Influence on Adaptive Optics Physics Websites Summary: Atmospheric Turbulence and its Influence on Adaptive Optics...

  8. atmospheric ion measurements: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the Atmospheric CERN Preprints Summary: We report the first observation in a high energy neutrino telescope of cascades induced by atmospheric electron neutrinos and by...

  9. Comparative Analysis of Urban Atmospheric Aerosol by Particle...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Analysis of Urban Atmospheric Aerosol by Particle-Induced X-ray Emission (PIXE), Proton Elastic Scattering Analysis Comparative Analysis of Urban Atmospheric Aerosol by...

  10. Atmospheric Solids Analysis Probe Mass Spectrometry: A New Approach...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Atmospheric Solids Analysis Probe Mass Spectrometry: A New Approach for Airborne Particle Analysis. Atmospheric Solids Analysis Probe Mass Spectrometry: A New Approach for Airborne...

  11. A Volcanologist'S Review Of Atmospheric Hazards Of Volcanic Activity...

    Open Energy Info (EERE)

    atmospheric hazards caused by explosive volcanic activity. The hazard posed by fine silicate ash with long residence time in the atmosphere is probably much less serious than...

  12. Diesel and Gasoline Engine Emissions: Characterization of Atmosphere...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Characterization of Atmosphere Composition and Health Responses to Inhaled Emissions Diesel and Gasoline Engine Emissions: Characterization of Atmosphere Composition and Health...

  13. Fehner and Gosling, Atmospheric Nuclear Weapons Testing, 1951...

    Energy Savers [EERE]

    Atmospheric Nuclear Weapons Testing, 1951-1963. Battlefield of the Cold War: The Nevada Test Site, Volume I Fehner and Gosling, Atmospheric Nuclear Weapons Testing, 1951-1963....

  14. atmospheric global electric: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    global atmospheric iron cycle, and combustion this paper. Key Words aerosol deposition, climate change, deserts Abstract Atmospheric inputs of iron sources of iron are...

  15. atmospheric dispersion coefficient: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the earth surface. In general, the atmospheric motion is driven by the intense solar energy arriving at the equator 3 A GIS-based atmospheric dispersion model Computer...

  16. atmospheric dispersion calculations: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the earth surface. In general, the atmospheric motion is driven by the intense solar energy arriving at the equator 4 A GIS-based atmospheric dispersion model Computer...

  17. atmospheric dispersion experiment: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the earth surface. In general, the atmospheric motion is driven by the intense solar energy arriving at the equator 2 A GIS-based atmospheric dispersion model Computer...

  18. atmospheric climate model: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Curry & Webster Atmospheric Thermodynamics Ch1 Composition Ch2 Laws Ch3 Transfers Ch12 Energy Russell, Lynn 10 Climate Sciences: Atmospheric Thermodynamics Environmental...

  19. atmosphere box model: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    GloveBoxes Glove boxes allow the user to perform operations in an atmosphere 8 University Corporation for Atmospheric Research PO Box 3000 Boulder, Colorado 80307 Geosciences...

  20. Oxygen detected in atmosphere of Saturn's moon Dione

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oxygen detected in atmosphere of Saturn's moon Dione Oxygen detected in atmosphere of Saturn's moon Dione Scientists and an international research team have announced discovery of...

  1. atmospheric modeling system: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    14 Causes and implications of persistent atmospheric carbon dioxide biases in Earth System Models University of California eScholarship Repository Summary: Atmosphere and Ocean...

  2. atmospheric co2 content: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Of Physics Version 4 Gerlich and Ralf D. Tscheuschner Abstract The atmospheric greenhouse effect, an idea that many authors Of The Atmospheric CO2 Greenhouse Effects . . . 3...

  3. atmospheric chemistry simulations: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Environmental Sciences and Ecology Websites Summary: , nitrogen and oxygen The Greenhouse Effect Atmospheric Aerosols Atmospheric chemical kinetics including and oral reports to...

  4. atmospheric sciences exposure: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    annual reviews of faculty performance in accordance 8 Space Science : Atmosphere Greenhouse Effect Physics Websites Summary: Space Science : Atmosphere Greenhouse Effect Part-5a...

  5. atmospheric chemistry project: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Environmental Sciences and Ecology Websites Summary: , nitrogen and oxygen The Greenhouse Effect Atmospheric Aerosols Atmospheric chemical kinetics including and oral reports to...

  6. atmospheric co2 concentrations: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Of Physics Version 4 Gerlich and Ralf D. Tscheuschner Abstract The atmospheric greenhouse effect, an idea that many authors Of The Atmospheric CO2 Greenhouse Effects . . . 3...

  7. atmospheric co2 concentration: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Of Physics Version 4 Gerlich and Ralf D. Tscheuschner Abstract The atmospheric greenhouse effect, an idea that many authors Of The Atmospheric CO2 Greenhouse Effects . . . 3...

  8. atmospheric co2 laser: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Of Physics Version 4 Gerlich and Ralf D. Tscheuschner Abstract The atmospheric greenhouse effect, an idea that many authors Of The Atmospheric CO2 Greenhouse Effects . . . 3...

  9. atmospheric loading effects: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    large solar proton Paris-Sud XI, Universit de 7 Space Science : Atmosphere Greenhouse Effect Physics Websites Summary: Space Science : Atmosphere Greenhouse Effect Part-5a...

  10. atmospheric chemistry programme: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Environmental Sciences and Ecology Websites Summary: , nitrogen and oxygen The Greenhouse Effect Atmospheric Aerosols Atmospheric chemical kinetics including and oral reports to...

  11. atmospheric co2 measurements: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Of Physics Version 4 Gerlich and Ralf D. Tscheuschner Abstract The atmospheric greenhouse effect, an idea that many authors Of The Atmospheric CO2 Greenhouse Effects . . . 3...

  12. atmospheric co2 variations: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Of Physics Version 4 Gerlich and Ralf D. Tscheuschner Abstract The atmospheric greenhouse effect, an idea that many authors Of The Atmospheric CO2 Greenhouse Effects . . . 3...

  13. atmospheric chemistry experiment: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Environmental Sciences and Ecology Websites Summary: , nitrogen and oxygen The Greenhouse Effect Atmospheric Aerosols Atmospheric chemical kinetics including and oral reports to...

  14. atmospheric science people: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    annual reviews of faculty performance in accordance 9 Space Science : Atmosphere Greenhouse Effect Physics Websites Summary: Space Science : Atmosphere Greenhouse Effect Part-5a...

  15. atmospheric chemistry: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Environmental Sciences and Ecology Websites Summary: , nitrogen and oxygen The Greenhouse Effect Atmospheric Aerosols Atmospheric chemical kinetics including and oral reports to...

  16. atmospheric sciences: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    annual reviews of faculty performance in accordance 8 Space Science : Atmosphere Greenhouse Effect Physics Websites Summary: Space Science : Atmosphere Greenhouse Effect Part-5a...

  17. atmospheric co2 mixing: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Of Physics Version 4 Gerlich and Ralf D. Tscheuschner Abstract The atmospheric greenhouse effect, an idea that many authors Of The Atmospheric CO2 Greenhouse Effects . . . 3...

  18. atmospheric aerosols basic: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of atmospheric aerosol. Aplin, KL 2012-01-01 13 1. Introduction The atmospheric greenhouse effect is the basic mechanism Environmental Sciences and Ecology Websites Summary: 1....

  19. atmospheric deposition microbial: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mercury in the Global Atmosphere: Chemistry, deposition, and land-atmosphere interactions Environmental Management and Restoration Websites Summary: Mercury in the Global...

  20. atmospheric deposition nutrient: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mercury in the Global Atmosphere: Chemistry, deposition, and land-atmosphere interactions Environmental Management and Restoration Websites Summary: Mercury in the Global...

  1. Visualizing Storms from NCAR's Atmosphere Model at NERSC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Atmosphere Model Visualizing Storms from NCAR's Atmosphere Model CCSM-sprabhat.png Global warming will likely change the statistics of tropical cyclones and hurricanes. In this...

  2. Adaptive control for Mars atmospheric flight

    E-Print Network [OSTI]

    Restrepo, Carolina Isabel

    2009-05-15T23:59:59.000Z

    landing accuracy requirements for a manned space vehicle make it necessary to ?y a controlled entry trajectory rather than a more robust ballistic entry trajectory used for some robotic missions. The large variations in Mars atmospheric properties make a...

  3. Composition and Reactions of Atmospheric Aerosol Particles

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    large portion of the microscopic particles floating in the air originate from incomplete combustion of coal and oil and from dust storms. Once in the atmosphere, they can have...

  4. HYPERsensarium : an archive of atmospheric conditions

    E-Print Network [OSTI]

    Shaw, Kelly E. (Kelly Evelyn)

    2013-01-01T23:59:59.000Z

    HYPERsensarium proposes a tangible interface of atmospheres for public experience through an archive of historical and projected weathers. While architecture's purpose has long been to act as the technical boundary between ...

  5. The porous atmosphere of eta Carinae

    E-Print Network [OSTI]

    Nir J. Shaviv

    2000-02-09T23:59:59.000Z

    We analyze the wind generated by the great 20 year long super-Eddington outburst of eta-Carinae. We show that using classical stellar atmospheres and winds theory, it is impossible to construct a consistent wind model in which a sufficiently small amount of mass, like the one observed, is shed. One expects the super-Eddington luminosity to drive a thick wind with a mass loss rate substantially higher than the observed one. The easiest way to resolve the inconsistency is if we alleviate the implicit notion that atmospheres are homogeneous. An inhomogeneous atmosphere, or "porous", allows more radiation to escape while exerting a smaller average force. Consequently, such an atmosphere yields a considerably lower mass loss rate for the same total luminosity. Moreover, all the applications of the Eddington Luminosity as a strict luminosity limit should be revised, or at least reanalyzed carefully.

  6. Space Science: Atmospheres Evolution of planets

    E-Print Network [OSTI]

    Johnson, Robert E.

    ;Atmospheres / Evolution Heat Sources Compressional Energy Trapped Radioactive Material Tidal Interactions, same A) the surface temperature,Tg, increases. WOW! Simple #12;Temperature vs. time in an Early Epoch

  7. MIDDLE ATMOSPHERE DYNAMICS AT707 (3 credits)

    E-Print Network [OSTI]

    ., Holton, J. R., Leovy, C. B., Academic Press, 489 pp. · Atmospheric and Oceanic Fluid Dynamics, 2006 Review Articles: · Haynes, P. H., 2005: Stratospheric Dynamics. Annu. Rev. Fluid Mech., 37, 263­ 293

  8. Tensiometer and method of determining soil moisture potential in below-grade earthen soil

    DOE Patents [OSTI]

    Hubbell, Joel M. (Idaho Falls, ID); Sisson, James B. (Idaho Falls, ID)

    1997-01-01T23:59:59.000Z

    A portable tensiometer to in situ determine below-grade soil moisture potential of earthen soil includes, a) a body having opposing first and second ends and being adapted for complete insertion into earthen soil below grade; b) a porous material provided at the first body end, the porous material at least in part defining a fluid chamber within the body at the first body end, the fluid chamber being fluidically sealed within the body but for the porous material; c) a degassed liquid received within the fluid chamber; d) a pressure transducer mounted in fluid communication with the fluid chamber; e) the body, pressure transducer and degassed liquid having a combined mass; f) a flexible suspension line connected to the body adjacent the second body end, the flexible line being of sufficient strength to gravitationally freely self suspend the combined mass; and c) the combined mass being sufficient to effectively impart hydraulic communication between below-grade earthen soil contacted by the porous material under the weight of the combined mass. Tensiometers configured to engage the sidewalls of an earthen opening are also disclosed. Methods of taking tensiometric measurements are also disclosed.

  9. Tensiometer and method of determining soil moisture potential in below-grade earthen soil

    DOE Patents [OSTI]

    Hubbell, J.M.; Sisson, J.B.

    1997-07-08T23:59:59.000Z

    A portable tensiometer to in-situ determine below-grade soil moisture potential of earthen soil includes, (a) a body having opposing first and second ends and being adapted for complete insertion into earthen soil below grade; (b) a porous material provided at the first body end, the porous material at least in part defining a fluid chamber within the body at the first body end, the fluid chamber being fluidically sealed within the body but for the porous material; (c) a degassed liquid received within the fluid chamber; (d) a pressure transducer mounted in fluid communication with the fluid chamber; (e) the body, pressure transducer and degassed liquid having a combined mass; (f) a flexible suspension line connected to the body adjacent the second body end, the flexible line being of sufficient strength to gravitationally freely self suspend the combined mass; and (g) the combined mass being sufficient to effectively impart hydraulic communication between below-grade earthen soil contacted by the porous material under the weight of the combined mass. Tensiometers configured to engage the sidewalls of an earthen opening are also disclosed. Methods of taking tensiometric measurements are also disclosed. 12 figs.

  10. Tensiometer and method of determining soil moisture potential in below-grade earthen soil

    DOE Patents [OSTI]

    Hubbell, Joel M. (Idaho Falls, ID); Mattson, Earl D. (Albuquerque, NM); Sisson, James B. (Idaho Falls, ID)

    1998-01-01T23:59:59.000Z

    A tensiometer to in situ determine below-grade soil moisture, potential of earthen soil includes, a) an apparatus adapted for insertion into earthen soil below grade, the apparatus having a below-grade portion, and, comprising; b) a porous material provided in the below-grade portion, the porous material at least in part defining a below-grade first fluid chamber; c) a first fluid conduit extending outwardly of the first fluid chamber; d) a first controllable isolation valve provided within the first fluid conduit, the first controllable isolation valve defining a second fluid chamber in fluid communication with the first fluid chamber through the first fluid conduit and the isolation valve, the first controllable isolation valve being received within the below-grade portion; and e) a pressure transducer in fluid communication with the first fluid chamber, the pressure transducer being received within the below-grade portion. An alternate embodiment includes an apparatus adapted for insertion into earthen soil below grade, the apparatus having a below-grade portion, and including: i) a porous material provided in the below-grade portion, the porous material at least in part defining a below-grade first fluid chamber; and ii) a pressure sensing apparatus in fluid communication with the first fluid chamber, the pressure sensing apparatus being entirely received within the below-grade portion. A method is also disclosed using the above and other apparatus.

  11. Tensiometer and method of determining soil moisture potential in below-grade earthen soil

    DOE Patents [OSTI]

    Hubbell, J.M.; Mattson, E.D.; Sisson, J.B.

    1998-06-02T23:59:59.000Z

    A tensiometer to in-situ determine below-grade soil moisture, potential of earthen soil includes, (a) an apparatus adapted for insertion into earthen soil below grade, the apparatus having a below-grade portion, and, comprising; (b) a porous material provided in the below-grade portion, the porous material at least in part defining a below-grade first fluid chamber; (c) a first fluid conduit extending outwardly of the first fluid chamber; (d) a first controllable isolation valve provided within the first fluid conduit, the first controllable isolation valve defining a second fluid chamber in fluid communication with the first fluid chamber through the first fluid conduit and the isolation valve, the first controllable isolation valve being received within the below-grade portion; and (e) a pressure transducer in fluid communication with the first fluid chamber, the pressure transducer being received within the below-grade portion. An alternate embodiment includes an apparatus adapted for insertion into earthen soil below grade, the apparatus having a below-grade portion, and including: (1) a porous material provided in the below-grade portion, the porous material at least in part defining a below-grade first fluid chamber; and (2) a pressure sensing apparatus in fluid communication with the first fluid chamber, the pressure sensing apparatus being entirely received within the below-grade portion. A method is also disclosed using the above and other apparatus. 6 figs.

  12. Lookup tables to compute high energy cosmic ray induced atmospheric ionization and changes in atmospheric chemistry

    E-Print Network [OSTI]

    Dimitra Atri; Adrian L. Melott; Brian C. Thomas

    2010-05-03T23:59:59.000Z

    A variety of events such as gamma-ray bursts and supernovae may expose the Earth to an increased flux of high-energy cosmic rays, with potentially important effects on the biosphere. Existing atmospheric chemistry software does not have the capability of incorporating the effects of substantial cosmic ray flux above 10 GeV . An atmospheric code, the NASA-Goddard Space Flight Center two-dimensional (latitude, altitude) time-dependent atmospheric model (NGSFC), is used to study atmospheric chemistry changes. Using CORSIKA, we have created tables that can be used to compute high energy cosmic ray (10 GeV - 1 PeV) induced atmospheric ionization and also, with the use of the NGSFC code, can be used to simulate the resulting atmospheric chemistry changes. We discuss the tables, their uses, weaknesses, and strengths.

  13. Air Activation Following an Atmospheric Explosion

    SciTech Connect (OSTI)

    Lowrey, Justin D.; McIntyre, Justin I.; Prichard, Andrew W.; Gesh, Christopher J.

    2013-03-13T23:59:59.000Z

    In addition to thermal radiation and fission products, nuclear explosions result in a very high flux of unfissioned neutrons. Within an atmospheric nuclear explosion, these neutrons can activate the various elemental components of natural air, potentially adding to the radioactive signature of the event as a whole. The goal of this work is to make an order-of-magnitude estimate of the total amount of air activation products that can result from an atmospheric nuclear explosion.

  14. Trace analysis of atmospheric organic bases

    E-Print Network [OSTI]

    Clark, Dwayne C.

    1984-01-01T23:59:59.000Z

    chromatographic fractions for NS analyses ( 121) and its use as a thin layer chromatography (TLC) adsorbent ( 122). The National Institute of Occupational Safety and Health (NIOSH) recommends its use in the analysis of many industrial vapors ( 113 - 120... analysis of atmospheric organic bases were investigated; the study included (1) the analysis of submarine charcoal filter bed samples for nitrogen bases and (2) the use of metallic tetraphenylporphines (TPP) as specific adsorbents for atmospheric...

  15. Quantum light in the turbulent atmosphere

    E-Print Network [OSTI]

    A. A. Semenov; W. Vogel

    2009-08-12T23:59:59.000Z

    Nonclassical properties of light propagating through the turbulent atmosphere are studied. We demonstrate by numerical simulation that the probability distribution of the transmission coefficient, which characterizes the effects of the atmosphere on the quantum state of light, can be reconstructed by homodyne detection. Nonclassical photon-statistics and, more generally, nonclassical Glauber-Sudarshan functions appear to be more robust against turbulence for weak light fields rather than for bright ones.

  16. Atmospheric State, Cloud Microphysics and Radiative Flux

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Mace, Gerald

    Atmospheric thermodynamics, cloud properties, radiative fluxes and radiative heating rates for the ARM Southern Great Plains (SGP) site. The data represent a characterization of the physical state of the atmospheric column compiled on a five-minute temporal and 90m vertical grid. Sources for this information include raw measurements, cloud property and radiative retrievals, retrievals and derived variables from other third-party sources, and radiative calculations using the derived quantities.

  17. Flexible Residential Test Facility: Impact of Infiltration and Ventilation on Measured Heating Season Energy and Moisture Levels

    SciTech Connect (OSTI)

    Vieira, R.; Parker, D.; Fairey, P.; Sherwin, J.; Withers, C.; Hoak, D.

    2013-09-01T23:59:59.000Z

    Two identical laboratory homes designed to model existing Florida building stock were sealed and tested to 2.5 ACH50. Then, one was made leaky with 70% leakage through the attic and 30% through windows, to a tested value of 9 ACH50. Reduced energy use was measured in the tighter home (2.5 ACH50) in the range of 15% to 16.5% relative to the leaky (9 ACH50) home. Internal moisture loads resulted in higher dew points inside the tight home than the leaky home. Window condensation and mold growth occurred inside the tight home. Even cutting internal moisture gains in half to 6.05 lbs/day, the dew point of the tight home was more than 15 degrees F higher than the outside dry bulb temperature. The homes have single pane glass representative of older Central Florida homes.

  18. Magnitude and reactivity consequences of moisture ingress into the modular High-Temperature Gas-Cooled Reactor core

    SciTech Connect (OSTI)

    Smith, O.L. (Oak Ridge National Lab., TN (United States))

    1992-12-01T23:59:59.000Z

    Inadvertent admission of moisture into the primary system of a modular high-temperature gas-cooled reactor has been identified in US Department of Energy-sponsored studies as an important safety concern. The work described here develops an analytical methodology to quantify the pressure and reactivity consequences of steam-generator tube rupture and other moisture-ingress-related incidents. Important neutronic and thermohydraulic processes are coupled with reactivity feedback and safety and control system responses. The rate and magnitude of steam buildup are found to be dominated by major system features such as break size compared with safety valve capacity and reliability and less sensitive to factors such as heat transfer coefficients. The results indicate that ingress transients progress at a slower pace than previously predicted by bounding analyses, with milder power overshoots and more time for operator or automatic corrective actions.

  19. Experimental investigation of moisture and temperature conditioning of C600/5208 graphite/epoxy composite material 

    E-Print Network [OSTI]

    Grieger, Kenneth Allen

    1979-01-01T23:59:59.000Z

    I XPERIMENTAI INVESTIGATION OF MOI TURE AND TE11PERATURF CONDITIONING OF CGOO/5208 GRAPHITE/EPOXY COMPOSITE MATL'RIAL KENNETH AILEN GRIFGFR Su5&ritted to the Graduate College of Texa. s AQh University in partial fulfillment of the requirement... for the degree of MASTER OF SCIFNCE December 1979 Majo, Subject: Ae&ospace Engineering EXPERINENTAL INVESTIGATION OF MOISTURE AND TENPERATURE CONDITIONING OF C600/5208 GRAPHITE/EPOXY COMPOSITE HATERIAL A Thesis by -KENNETH ALLEN GRIEGER Approved...

  20. New nonlinear mechanisms of midlatitude atmospheric low-frequency variability

    E-Print Network [OSTI]

    and Atmospheric Research Utrecht, Utrecht University, Princetonplein 5, 3584 CC Utrecht, The Netherlands Abstract

  1. Electronic structure of Ce?RhIn?: A two-dimensional heavy-fermion system studied by angle-resolved photoemission spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jiang, Rui; Petrovic, C.; Mou, Daixing; Liu, Chang; Zhao, Xin; Yao, Yongxin; Ryu, Hyejin; Ho, Kai -Ming; Kaminski, Adam

    2015-04-01T23:59:59.000Z

    We use angle-resolved photoemission spectroscopy (ARPES) to study the 2D heavy fermion superconductor, Ce?RhIn?. The Fermi surface is rather complicated and consists of several hole and electron pockets with one of the sheets displaying strong nesting properties with a q-vector of (0.32, 0.32) ?/a. We do not observe kz dispersion of the Fermi sheets, which is consistent with the expected 2D character of the electronic structure. Comparison of the ARPES data to band structure calculations suggests that a localized picture of the f-electrons works best. While there is some agreement in the overall band dispersion and location of the Fermimore »sheets, the model does not reproduce all observed bands and is not completely accurate for those it does. Our data paves the way for improving the band structure calculations and the general understanding of the transport and thermodynamical properties of this material.« less

  2. Analysis ofRH TRU Wastes for Containment in Lead Shielded Containers INV-SAR-08, Revision 0 Page I Of~'P~8tJ},f1-

    E-Print Network [OSTI]

    .2 Cellulose, Plastic, Rubber, Steel and Lead Associated with Shielded Container Emplacement 6 4.3 Number of 30-gallon Containers, 3-Packs and Stacks for Shielded Containers 8 4.4 Mass of Plastic, Steel, and LeadAnalysis ofRH TRU Wastes for Containment in Lead Shielded Containers INV-SAR-08, Revision 0 Page I

  3. Testing a hypothesis concerning the quantitative dependence of evapotranspiration on availability of moisture 

    E-Print Network [OSTI]

    Covey, Winton Guy

    1959-01-01T23:59:59.000Z

    used (items 1 - 10) and the following results are tabulated in Appendix A: 11. Friction velocity ? u (cm/sec) 2 12. Evaporative heat flux ? q (cal/cm sec) e 13 . Surface temperature ? 0 ( 'C) . 0 14. Saturation vapor pressure at surface temperature... ? millibars (mb). The conversion fac 1 cal = 4. 185 1 mb = 1. 000 tora for energy and pressure are: 7 2 2 x 10 gm cm /sec , and 3 2 0 x 10 gm/cm sec from many aspects; for example, (I) it is an addition of water vapor to the atmosphere; (2) it is a...

  4. Magnetized Atmospheres around Accreting Neutron Stars

    E-Print Network [OSTI]

    S. Zane; R. Turolla; A. Treves

    2000-02-01T23:59:59.000Z

    We present a detailed investigation of atmospheres around accreting neutron stars with high magnetic field ($B\\gtrsim 10^{12}$ G) and low luminosity ($L\\lesssim 10^{33}$ erg/s). We compute the atmospheric structure, intensity and emergent spectrum for a plane-parallel, pure hydrogen medium by solving the transfer equations for the normal modes coupled to the hydrostatic and energy balance equations. The hard tail found in previous investigations for accreting, non-magnetic neutron stars with comparable luminosity is suppressed and the X-ray spectrum, although still harder than a blackbody at the star effective temperature, is nearly planckian in shape. Spectra from accreting atmospheres, both with high and low fields, are found to exhibit a significant excess at optical wavelengths above the Rayleigh-Jeans tail of the X-ray continuum.

  5. Atmospheric Pressure Plasma Process And Applications

    SciTech Connect (OSTI)

    Peter C. Kong; Myrtle

    2006-09-01T23:59:59.000Z

    This paper provides a general discussion of atmospheric-pressure plasma generation, processes, and applications. There are two distinct categories of atmospheric-pressure plasmas: thermal and nonthermal. Thermal atmospheric-pressure plasmas include those produced in high intensity arcs, plasma torches, or in high intensity, high frequency discharges. Although nonthermal plasmas are at room temperatures, they are extremely effective in producing activated species, e.g., free radicals and excited state atoms. Thus, both thermal and nonthermal atmosphericpressure plasmas are finding applications in a wide variety of industrial processes, e.g. waste destruction, material recovery, extractive metallurgy, powder synthesis, and energy conversion. A brief discussion of recent plasma technology research and development activities at the Idaho National Laboratory is included.

  6. Super Kamiokande results: atmospheric and solar neutrinos

    E-Print Network [OSTI]

    M. Ishitsuka; for the Super-Kamiokande Collaboration

    2004-06-28T23:59:59.000Z

    Atmospheric neutrino and solar neutrino data from the first phase of Super-Kamiokande (SK-I) are presented. The observed data are used to study atmospheric and solar neutrino oscillations. Zenith angle distributions from various atmospheric neutrino data samples are used to estimate the neutrino oscillation parameter region. In addition, a new result of the $L/E$ measurement is presented. A dip in the $L/E$ distribution was observed in the data, as predicted from the sinusoidal flavor transition probability of neutrino oscillation. The energy spectrum and the time variation such as day/night and seasonal differences of solar neutrino flux are measured in Super-Kamiokande. The neutrino oscillation parameters are strongly constrained from those measurements.

  7. A Community Atmosphere Model with Superparameterized Clouds

    SciTech Connect (OSTI)

    Randall, David; Branson, Mark; Wang, Minghuai; Ghan, Steven J.; Craig, Cheryl; Gettelman, A.; Edwards, Jim

    2013-06-18T23:59:59.000Z

    In 1999, National Center for Atmospheric Research (NCAR) scientists Wojciech Grabowski and Piotr Smolarkiewicz created a "multiscale" atmospheric model in which the physical processes associated with clouds were represented by running a simple high-resolution model within each grid column of a lowresolution global model. In idealized experiments, they found that the multiscale model produced promising simulations of organized tropical convection, which other models had struggled to produce. Inspired by their results, Colorado State University (CSU) scientists Marat Khairoutdinov and David Randall created a multiscale version of the Community Atmosphere Model (CAM). They removed the cloud parameterizations of the CAM, and replaced them with Khairoutdinov's high-resolution cloud model. They dubbed the embedded cloud model a "super-parameterization," and the modified CAM is now called the "SP-CAM." Over the next several years, many scientists, from many institutions, have explored the ability of the SP-CAM to simulate tropical weather systems, the day-night changes of precipitation, the Asian and African monsoons, and a number of other climate processes. Cristiana Stan of the Center for Ocean-Land-Atmosphere Interactions found that the SP-CAM gives improved results when coupled to an ocean model, and follow-on studies have explored the SP-CAM's utility when used as the atmospheric component of the Community Earth System Model. Much of this research has been performed under the auspices of the Center for Multiscale Modeling of Atmospheric Processes, a National Science Foundation (NSF) Science and Technology Center for which the lead institution is CSU.

  8. Measuring Atmospheric Neutrino Oscillations with Neutrino Telescopes

    E-Print Network [OSTI]

    Ivone F. M. Albuquerque; George F. Smoot

    2001-03-28T23:59:59.000Z

    Neutrino telescopes with large detection volumes can demonstrate that the current indications of neutrino oscillation are correct or if a better description can be achieved with non-standard alternatives. Observations of contained muons produced by atmospheric neutrinos can better constrain the allowed region for oscillations or determine the relevant parameters of non-standard models. We analyze the possibility of neutrino telescopes measuring atmospheric neutrino oscillations. We suggest adjustments to improve this potential. An addition of four densely-instrumented strings to the AMANDA II detector makes observations feasible. Such a configuration is competitive with current and proposed experiments.

  9. Controlled atmosphere for fabrication of cermet electrodes

    DOE Patents [OSTI]

    Ray, S.P.; Woods, R.W.

    1998-08-11T23:59:59.000Z

    A process is disclosed for making an inert electrode composite wherein a metal oxide and a metal are reacted in a gaseous atmosphere at an elevated temperature of at least about 750 C. The metal oxide is at least one of the nickel, iron, tin, zinc and zirconium oxides and the metal is copper, silver, a mixture of copper and silver or a copper-silver alloy. The gaseous atmosphere has an oxygen content that is controlled at about 5--3000 ppm in order to obtain a desired composition in the resulting composite. 2 figs.

  10. Controlled atmosphere for fabrication of cermet electrodes

    DOE Patents [OSTI]

    Ray, Siba P. (Murrysville, PA); Woods, Robert W. (New Kensington, PA)

    1998-01-01T23:59:59.000Z

    A process for making an inert electrode composite wherein a metal oxide and a metal are reacted in a gaseous atmosphere at an elevated temperature of at least about 750.degree. C. The metal oxide is at least one of the nickel, iron, tin, zinc and zirconium oxides and the metal is copper, silver, a mixture of copper and silver or a copper-silver alloy. The gaseous atmosphere has an oxygen content that is controlled at about 5-3000 ppm in order to obtain a desired composition in the resulting composite.

  11. Final Report: Process Models of the Equilibrium Size & State of Organic/Inorganic Aerosols for the Development of Large Scale Atmospheric Models & the Analysis of Field Data

    SciTech Connect (OSTI)

    Wexler, Anthony Stein [UC Davis] [UC Davis; Clegg, Simon Leslie [UC Davis] [UC Davis

    2013-10-26T23:59:59.000Z

    Our work addressed the following elements of the Call for Proposals: (i) “to improve the theoretical representation of aerosol processes studied in ASP laboratory or field studies”, (ii) “to enhance the incorporation of aerosol process information into modules suitable for large-scale or global atmospheric models”, and (iii) “provide systematic experimental validation of process model predictions ... using data from targeted laboratory and field experiments”. Achievements to the end of 2012 are described in four previous reports, and include: new models of densities and surface tensions of pure (single solute) and mixed aqueous solutions of typical aerosol composition under all atmospheric conditions (0 to 100% RH and T > 150 K); inclusion of these models into the widely used Extended Aerosol Inorganics model (E-AIM, http://www.aim.env.uea.ac.uk/aim/aim.php); the addition of vapor pressure calculators for organic compounds to the E-AIM website; the ability of include user-defined organic compounds and/or lumped surrogates in gas/aerosol partitioning calculations; the development of new equations to represent the properties of soluble aerosols over the entire concentration range (using methods based upon adsorption isotherms, and derived using statistical mechanics), including systems at close to zero RH. These results are described in publications 1-6 at the end of this report, and on the “News” page of the E-AIM website (http://www.aim.env.uea.ac.uk/aim/info/news.html). During 2012 and 2013 we have collaborated in a combined observation and lab-based study of the water uptake of the organic component of atmospheric aerosols (PI Gannet Hallar, of the Desert Research Institute). The aerosol samples were analyzed using several complementary techniques (GC/MS, FT-ICR MS, and ion chromatography) to produce a very complete organic “speciation” including both polar and non-polar compounds. Hygroscopic growth factors of the samples were measured, and we have just completed comparisons of the data with our process model predictions based upon the inorganic and organic composition of the samples.

  12. Organic acid preservation of high-moisture sorghum grain and its feeding value for growing-finishing swine

    E-Print Network [OSTI]

    Knabe, Darrell Albert

    1973-01-01T23:59:59.000Z

    to the 24 to 36% moisture grain when it was harvested in mid-July but extensive mold growth was noted in one bin after 70 days. This required that it be retreated which raised the acid content from about 1. 5 to 3. 4 percent. The failure of the grain... effective in preserving the grain harvested in mid-July that was used in the second group feeding trial. Ho mold growth was found in the three bins and essentially no microbial growth could be plated from grains preserved with 1. 1/ acid after six weeks...

  13. Microlensing Effects in Atmospheres of Substars

    E-Print Network [OSTI]

    L. A. Berdina; A. A. Minakov

    2007-12-10T23:59:59.000Z

    The purpose of the present work is the study of focusing properties of atmospheres of substars that is necessary for adequate interpreting of observational data and for solving the inverse problem consisting in recovery parameters of 'microlenses' (substars) and sources (quasars). Amplification factor for a quasar image as projected onto the field of microlenses-substars was computed for optical and radio wavelengths.

  14. CHARACTERIZATION OF CLOUDS IN TITAN'S TROPICAL ATMOSPHERE

    SciTech Connect (OSTI)

    Griffith, Caitlin A.; Penteado, Paulo [Department of Planetary Sciences, University of Arizona, Tucson, AZ 85719 (United States); Rodriguez, Sebastien [Laboratoire AIM, Universite Paris 7/CNRS/CEA-Saclay, DSM/IRFU/SAp (France); Le Mouelic, Stephane [Laboratoire de Planetologie et Geodynamique, CNRS, UMR-6112, Universite de Nantes, 44000 Nantes (France); Baines, Kevin H.; Buratti, Bonnie; Sotin, Christophe [Jet Propulsion Laboratory, Pasadena, CA 91109 (United States); Clark, Roger [U.S. Geological Survey, Denver, CO 80225 (United States); Nicholson, Phil [Department of Astronomy, Cornell University, Ithaca, NY (United States); Jaumann, Ralf [Institute of Planetary Exploration, Deutsche Zentrum, fuer Luft- und Raumfahrt (Germany)

    2009-09-10T23:59:59.000Z

    Images of Titan's clouds, possible over the past 10 years, indicate primarily discrete convective methane clouds near the south and north poles and an immense stratiform cloud, likely composed of ethane, around the north pole. Here we present spectral images from Cassini's Visual Mapping Infrared Spectrometer that reveal the increasing presence of clouds in Titan's tropical atmosphere. Radiative transfer analyses indicate similarities between summer polar and tropical methane clouds. Like their southern counterparts, tropical clouds consist of particles exceeding 5 {mu}m. They display discrete structures suggestive of convective cumuli. They prevail at a specific latitude band between 8 deg. - 20 deg. S, indicative of a circulation origin and the beginning of a circulation turnover. Yet, unlike the high latitude clouds that often reach 45 km altitude, these discrete tropical clouds, so far, remain capped to altitudes below 26 km. Such low convective clouds are consistent with the highly stable atmospheric conditions measured at the Huygens landing site. Their characteristics suggest that Titan's tropical atmosphere has a dry climate unlike the south polar atmosphere, and despite the numerous washes that carve the tropical landscape.

  15. Atmospheric dispersion in mountain valleys and basins

    SciTech Connect (OSTI)

    Allwine, K.J.

    1992-01-01T23:59:59.000Z

    The primary goal of the research is to further characterize and understand dispersion in valley and basin atmospheres. A secondary, and related goal, is to identify and understand the dominant physical processes governing this dispersion. This has been accomplished through a review of the current literature, and analyses of recently collected data from two field experiments. This work should contribute to an improved understanding of material transport in the atmospheric boundary layer. It was found that dispersion in a freely draining valley (Brush Creek valley, CO) atmosphere is much greater than in an enclosed basin (Roanoke, VA) atmosphere primarily because of the greater wind speeds moving past the release point and the greater turbulence levels. The development of a cold air pool in the Roanoke basin is the dominant process governing nighttime dispersion in the basin, while the nighttime dispersion in the Brush Creek valley is dominated by turbulent diffusion and plume confinement between the valley sidewalls. The interaction between valley flows and above ridgetops flows is investigated. A ventilation rate'' of material transport between the valley and above ridgetop flows is determined. This is important in regional air pollution modeling and global climate modeling. A simple model of dispersion in valleys, applicable through a diurnal cycle, is proposed.

  16. Atmospheric dispersion in mountain valleys and basins

    SciTech Connect (OSTI)

    Allwine, K.J.

    1992-01-01T23:59:59.000Z

    The primary goal of the research is to further characterize and understand dispersion in valley and basin atmospheres. A secondary, and related goal, is to identify and understand the dominant physical processes governing this dispersion. This has been accomplished through a review of the current literature, and analyses of recently collected data from two field experiments. This work should contribute to an improved understanding of material transport in the atmospheric boundary layer. It was found that dispersion in a freely draining valley (Brush Creek valley, CO) atmosphere is much greater than in an enclosed basin (Roanoke, VA) atmosphere primarily because of the greater wind speeds moving past the release point and the greater turbulence levels. The development of a cold air pool in the Roanoke basin is the dominant process governing nighttime dispersion in the basin, while the nighttime dispersion in the Brush Creek valley is dominated by turbulent diffusion and plume confinement between the valley sidewalls. The interaction between valley flows and above ridgetops flows is investigated. A ``ventilation rate`` of material transport between the valley and above ridgetop flows is determined. This is important in regional air pollution modeling and global climate modeling. A simple model of dispersion in valleys, applicable through a diurnal cycle, is proposed.

  17. Air Resources Laboratory Atmospheric Tracer Technology

    E-Print Network [OSTI]

    The continuous (near real time) sulfur hexafluoride (SF6 ) analyzers are portable systems that make measurements of atmospheric SF6 concentrations with a response time of just under one second. The rapid response time in Gaussian plume transport and dispersion models. The SF6 analyzers include a computer controlled calibration

  18. 1999 Gordon Research Conference on Atmospheric Chemistry

    SciTech Connect (OSTI)

    Storm, C.

    2000-08-01T23:59:59.000Z

    The Gordon Research Conference (GRC) on Atmospheric Chemistry was held at Salve Regina University in Newport, Rhode Island, June 13-18, 1999. The conference was well attended with 151 participants. The attendees represented the spectrum of endeavor in this field coming from academia, industry, and government laboratories, both US and foreign scientists, senior researchers, young investigators, and students.

  19. Ocean Atmosphere Sea Ice Soil User's Guide

    E-Print Network [OSTI]

    OASIS3 Ocean Atmosphere Sea Ice Soil User's Guide oasis3 prism 2­2, June 2004 Sophie Valcke 1 to realize a coupled simulation with OASIS3. The aim of OASIS3 is to provide a flexible and user friendly. OASIS3 synchronizes the exchanges of coupling fields between the models being coupled, and performs 2D

  20. Ocean Atmosphere Sea Ice Soil User's Guide

    E-Print Network [OSTI]

    OASIS3 Ocean Atmosphere Sea Ice Soil User's Guide oasis3 prism 2­3, August 2004 Sophie Valcke 1 to realize a coupled simulation with OASIS3. The aim of OASIS3 is to provide a flexible and user friendly. OASIS3 synchronizes the exchanges of coupling fields between the models being coupled, and performs 2D