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  1. File:NREL-brazil-dir.pdf | Open Energy Information

    Open Energy Info (EERE)

    brazil-dir.pdf Jump to: navigation, search File File history File usage Brazil - Annual Direct Normal Solar Radiation Size of this preview: 776 600 pixels. Full resolution...

  2. Business System Clause - Berta Schreiber, Dir, Office of Policy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Business System Clause - Berta Schreiber, Dir, Office of Policy (MA-61) Business System Clause - Berta Schreiber, Dir, Office of Policy (MA-61) 2014 DOE Project Management Workshop ...

  3. Index of /spc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    spc Icon Name Last modified Size Description [DIR] Parent Directory - [DIR] images/ 10-Dec-2007 14:38 -

  4. Index of /safety

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    safety Icon Name Last modified Size Description [DIR] Parent Directory - [DIR] hazardousradioactive..> 17-Apr-2013 12:29 -

  5. Title: Freedom of Information Request DIR DIV NAME MGR DEP AMA

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Title: Freedom of Information Request DIR DIV NAME MGR DEP AMA FMD HRM PRO AMCP AMMS ISI PIC SES DIR DIV NAME SSD AMRC AMSE EMD OOD SED OCC OCE Riehle, Dorothy (Actionee) ORP PNSO...

  6. Business System Clause - Berta Schreiber, Dir, Office of Policy (MA-61) |

    Energy Savers [EERE]

    Department of Energy Business System Clause - Berta Schreiber, Dir, Office of Policy (MA-61) Business System Clause - Berta Schreiber, Dir, Office of Policy (MA-61) 2014 DOE Project Management Workshop PDF icon Business System Clause - Berta Schreiber, Dir, Office of Policy (MA-61) More Documents & Publications Agenda Agenda_2015 APM Workshop_Final Acquisition Letter No. AL 2013-11

  7. Index of /xafs13

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    xafs13 Icon Name Last modified Size Description [DIR] Parent Directory -

  8. PM Update - Steve Meador, Acting Dir for Proj Assessment-SC, Jack Surash,

    Energy Savers [EERE]

    Dep Asst Secretary for APM-EM, Bob Raines, Assoc. Administrator for APM-NNSA | Department of Energy Update - Steve Meador, Acting Dir for Proj Assessment-SC, Jack Surash, Dep Asst Secretary for APM-EM, Bob Raines, Assoc. Administrator for APM-NNSA PM Update - Steve Meador, Acting Dir for Proj Assessment-SC, Jack Surash, Dep Asst Secretary for APM-EM, Bob Raines, Assoc. Administrator for APM-NNSA 2014 DOE Project Management Workshop PDF icon PM Update - Steve Meador, Acting Dir for Proj

  9. PM Update - Steve Meador, Acting Dir for Proj Assessment-SC,...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Update - Steve Meador, Acting Dir for Proj Assessment-SC, Jack Surash, Dep Asst Secretary for APM-EM, Bob Raines, Assoc. Administrator for APM-NNSA PM Update - Steve Meador, Acting...

  10. File:NREL-africa-dir.pdf | Open Energy Information

    Open Energy Info (EERE)

    navigation, search File File history File usage Africa - Annual Direct Normal Solar Radiation (PDF) Size of this preview: 776 600 pixels. Full resolution (1,650 1,275...

  11. Simulations of the infrared, Raman, and 2D-IR photon echo spectra of water in nanoscale silica pores

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Burris, Paul C.; Laage, Damien; Thompson, Ward H.

    2016-05-20

    Vibrational spectroscopy is frequently used to characterize nanoconfined liquids and probe the effect of the confining framework on the liquid structure and dynamics relative to the corresponding bulk fluid. However, it is still unclear what molecular-level information can be obtained from such measurements. In this Paper, we address this question by using molecular dynamics (MD) simulations to reproduce the linear infrared (IR), Raman, and two-dimensional IR (2D-IR) photon echo spectra for water confined within hydrophilic (hydroxyl-terminated) silica mesopores. To simplify the spectra the OH stretching region of isotopically dilute HOD in D2O is considered. An empirical mapping approach is usedmore » to obtain the OH vibrational frequencies, transition dipoles, and transition polarizabilities from the MD simulations. The simulated linear IR and Raman spectra are in good general agreement with measured spectra of water in mesoporous silica reported in the literature. The key effect of confinement on the water spectrum is a vibrational blueshift for OH groups that are closest to the pore interface. The blueshift can be attributed to the weaker hydrogen bonds (H-bonds) formed between the OH groups and silica oxygen acceptors. Non-Condon effects greatly diminish the contribution of these OH moieties to the linear IR spectrum, but these weaker H-bonds are readily apparent in the Raman spectrum. The 2D-IR spectra have not yet been measured and thus the present results represent a prediction. Lastly, the simulated spectra indicate that it should be possible to probe the slower spectral diffusion of confined water compared to the bulk liquid by analysis of the 2D-IR spectra.« less

  12. Index of /nnpss/photos

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    nnpss/photos [ICO] Name Last modified Size Description [DIR] Parent Directory - [DIR] DurhamBullsGame/ 07-Jul-2011 17:46 - [DIR] Farewell/ 07-Jul-2011 17:48 - [IMG] GroupPhoto_HIGH_RESOLUTION.jpg 07-Jul-2011 14:44 4.8M [IMG] GroupPhoto_LOW_RESOLUTION.jpg 07-Jul-2011 14:44 428K [IMG] GroupPhoto_MEDIUM_RESOLUTION.jpg 07-Jul-2011 14:44 5.0M [DIR] Lectures/ 07-Jul-2011 17:58 - [DIR] PosterSession/ 07-Jul-2011 17:50 - [DIR] WelcomeReception/ 07-Jul-2011 17:47 -

  13. Index of /documents/public/root/material/1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 [ICO] Name Last modified Size Description [DIR] Parent Directory - [DIR] C++Examples/ 03-Jun-2012 22:34 - [ ] IntroductiontoROOT.pdf 03-Jun-2012 22:28 868K [ ] IntroductiontoROOTClasses.pdf 03-Jun-2012 22:30 511K [DIR] ROOTExamples/ 03-Jun-2012 22:39 - [ ] ROOTTarBall_1.tar 03-Jun-2012 22:41

  14. Index of /documents/public/root/material/2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 [ICO] Name Last modified Size Description [DIR] Parent Directory - [DIR] C++Examples/ 03-Jun-2012 22:34 - [ ] IntroductiontoROOT.pdf 03-Jun-2012 22:28 868K [ ] IntroductiontoROOTClasses.pdf 03-Jun-2012 22:30 511K [DIR] ROOTExamples/ 03-Jun-2012 22:39 - [ ] ROOTTarBall_1.tar 03-Jun-2012 22:42

  15. Index of /radsafe/files

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    radsafe/files [ICO] Name Last modified Size Description [DIR] Parent Directory - [ ] directions for the radiation detector.doc 23-Jul-1999 00:13 38K [DIR] groundloop/ 13-May-2016 00:26 - [DIR] logs/ 13-May-2016 20:33 - [ ] test.eps 16-Nov-2010 08:28 25K

  16. File:NREL-afg-10km-dir.pdf | Open Energy Information

    Open Energy Info (EERE)

    search File File history File usage Afghanistan - Annual Direct Normal Solar Radiation Size of this preview: 776 600 pixels. Full resolution (1,650 1,275 pixels,...

  17. A low-temperature extraction-solvothermal route to the fabrication of micro-sized MoS{sub 2} spheres modified by Cyanex 301

    SciTech Connect (OSTI)

    Shi Huaqiang; Fu Xun . E-mail: fuxun4483@163.com; Zhou Xiaodong; Wang Debao; Hu Zhengshui

    2006-06-15

    Mono-dispersed molybdenum disulfide micro-spheres with the diameter of 1-3 {mu}m have been successfully synthesized via extraction-solvothermal method at 150 deg. C. The extractant Cyanex 301 (di-(2,4,4-trimethylpentyl) dithiophosphinic acid) acted as phase transferring agent, reductant, sulfur source and morphology-controlling agent in the whole procedure. The obtained MoS{sub 2} micro-spheres were characterized by XRD, EDS, SEM, TEM, HRTEM, IR, UV-Vis and TG, respectively. The influences of reaction conditions were discussed while a mechanism was proposed to explain the formation of the micro-spheres. Moreover, the tribological properties of liquid paraffin (LP) containing Cyanex 301-modified MoS{sub 2} micro-spheres were also evaluated on a four-ball machine, showing that the obtained MoS{sub 2} product was an excellent oil additive in LP and such lubricant had good anti-wear and friction-reducing properties. - Graphical abstract: Mono-dispersed MoS{sub 2} micro-spheres with the diameter of 1-3 {mu}m were synthesized in gasoline via extraction-solvothermal method at 150 deg. C. The MoS{sub 2} product could be well dispersed into organic solvents again and the tribological properties of liquid paraffin (LP) containing MoS{sub 2} micro-spheres were improved.

  18. SU-E-J-151: Dosimetric Evaluation of DIR Mapped Contours for Image Guided Adaptive Radiotherapy with 4D Cone-Beam CT

    SciTech Connect (OSTI)

    Balik, S; Weiss, E; Williamson, J; Hugo, G; Jan, N; Zhang, L; Roman, N; Christensen, G

    2014-06-01

    Purpose: To estimate dosimetric errors resulting from using contours deformably mapped from planning CT to 4D cone beam CT (CBCT) images for image-guided adaptive radiotherapy of locally advanced non-small cell lung cancer (NSCLC). Methods: Ten locally advanced non-small cell lung cancer (NSCLC) patients underwent one planning 4D fan-beam CT (4DFBCT) and weekly 4DCBCT scans. Multiple physicians delineated the gross tumor volume (GTV) and normal structures in planning CT images and only GTV in CBCT images. Manual contours were mapped from planning CT to CBCTs using small deformation, inverse consistent linear elastic (SICLE) algorithm for two scans in each patient. Two physicians reviewed and rated the DIR-mapped (auto) and manual GTV contours as clinically acceptable (CA), clinically acceptable after minor modification (CAMM) and unacceptable (CU). Mapped normal structures were visually inspected and corrected if necessary, and used to override tissue density for dose calculation. CTV (6mm expansion of GTV) and PTV (5mm expansion of CTV) were created. VMAT plans were generated using the DIR-mapped contours to deliver 66 Gy in 33 fractions with 95% and 100% coverage (V66) to PTV and CTV, respectively. Plan evaluation for V66 was based on manual PTV and CTV contours. Results: Mean PTV V66 was 84% (range 75% 95%) and mean CTV V66 was 97% (range 93% 100%) for CAMM scored plans (12 plans); and was 90% (range 80% 95%) and 99% (range 95% 100%) for CA scored plans (7 plans). The difference in V66 between CAMM and CA was significant for PTV (p = 0.03) and approached significance for CTV (p = 0.07). Conclusion: The quality of DIR-mapped contours directly impacted the plan quality for 4DCBCT-based adaptation. Larger safety margins may be needed when planning with auto contours for IGART with 4DCBCT images. Reseach was supported by NIH P01CA116602.

  19. Modified cyanobacteria

    SciTech Connect (OSTI)

    Vermaas, Willem F J.

    2014-06-17

    Disclosed is a modified photoautotrophic bacterium comprising genes of interest that are modified in terms of their expression and/or coding region sequence, wherein modification of the genes of interest increases production of a desired product in the bacterium relative to the amount of the desired product production in a photoautotrophic bacterium that is not modified with respect to the genes of interest.

  20. Index of /documents/public/root/material/6

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    root/material/6 [ICO] Name Last modified Size Description [DIR] Parent Directory - [DIR] C++Examples/ 03-Jun-2012 22:34 - [ ] CompPhysMethods.pdf 06-Jun-2012 09:11 8.0M [ ] IntroductiontoROOT.pdf 03-Jun-2012 22:28 868K [ ] IntroductiontoROOTClasses.pdf 03-Jun-2012 22:30 511K [DIR] ROOTExamples/ 03-Jun-2012 22:39 - [ ] ROOTTarBall_1.tar 05-Jun-2012 22:04 2.

  1. Index of /documents/public/root/material/3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 [ICO] Name Last modified Size Description [DIR] Parent Directory - [ ] IntrotoROOTDataStructures.pdf 15-Jul-2009 11:01 1.1M [DIR] ROOT_Data_Structures/ 12-Jul-2009 16:01 - [ ] TarBall_Data_Structure_Programs.tar 13-Jul-2009 17:19 4

  2. Index of /userresources

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    userresources Icon Name Last modified Size Description [DIR] Parent Directory - [DIR] documents/ 04-Sep-2014 10:17 - [TXT] export.html 28-May-2013 15:25 12K [DIR] forms/ 24-Mar-2009 14:39 - [DIR] lclsuo/ 29-Apr-2009 13:02 - [DIR] mailingList/ 28-Aug-2008 14:58 - [ ] snippet_useagreement..> 06-Jun-2011 11:20 2.4K [ ] ssrl-publications-20..> 29-Apr-2016 10:27 458 [DIR] ssrluo/ 16-Nov-2011 08:09 - [ ] test_snippet.php 06-Jun-2011 11:21 3.0K [ ] uf-access-list.disabled 06-Jan-2015 00:17 86 [ ]

  3. Index of /documents/public/summerlectures

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    summerlectures [ICO] Name Last modified Size Description [DIR] Parent Directory - [ ] BuildingBlocks-NN-Interactions-Ahmed.pptx 10-Jun-2013 09:41 11M [ ] Electronics.ppt 10-Jun-2013 09:41 2

  4. Two Keggin-type heteropolytungstates with transition metal as a central atom: Crystal structure and magnetic study with 2D-IR correlation spectroscopy

    SciTech Connect (OSTI)

    Chai, Feng [Department of Chemistry, Fuzhou University, Fuzhou 350108 (China); Chen, YiPing, E-mail: ypchen007@sina.com [Department of Chemistry, Fuzhou University, Fuzhou 350108 (China); State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (China); You, ZhuChai; Xia, ZeMin; Ge, SuZhi; Sun, YanQiong; Huang, BiHua [Department of Chemistry, Fuzhou University, Fuzhou 350108 (China)

    2013-06-01

    Two Keggin-type heteropolytungstates, [Co(phen)?]?[CoW??O??]9H?O 1 (phen=1,10-phenanthroline) and [Fe(phen)?]?[FeW??O??]H?OH?O 2, have been synthesized via the hydrothermal technique and characterized by single crystal X-ray diffraction analyses, IR, XPS, TG analysis, UVDRS, XRD, thermal-dependent and magnetic-dependent 2D-COS IR (two-dimensional infrared correlation spectroscopy). Crystal structure analysis reveals that the polyanions in compound 1 are linked into 3D supramolecule through hydrogen bonding interactions between lattice water molecules and terminal oxygen atoms of polyanion units, and [Co(phen)?]? cations distributed in the polyanion framework with many hydrogen bonding interactions. The XPS spectra indicate that all the Co atoms in 1 are +2 oxidation state, the Fe atoms in 2 existing with +2 and +3 mixed oxidation states. - Graphical abstract: The magnetic-dependent synchronous 2D correlation IR spectra of 1 (a), 2 (b) over 050 mT in the range of 6001000 cm?, the obvious response indicate two Keggin polyanions skeleton susceptible to applied magnetic field. Highlights: Two Keggin-type heteropolytungstates with transition metal as a central atom has been obtained. Compound 1 forms into 3D supramolecular architecture through hydrogen bonding between water molecules and polyanions. Magnetic-dependent 2D-IR correlation spectroscopy was introduced to discuss the magnetism of polyoxometalate.

  5. Index of /documents/public/root/material/5

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5 [ICO] Name Last modified Size Description [DIR] Parent Directory - [ ] An_Introduction_to_GCC-Brian_Gough.pdf 29-Jul-2009 14:02 526K [TXT] Makefile 07-Jun-2012 00:05 571 [TXT] README 29-Jul-2009 17:54 1.4K [ ] all_files.tar 07-Jun-2012 00:05 3.2M [DIR] application/ 14-Jul-2009 14:24 - [DIR] geant4/ 28-Jul-2009 11:50 - [DIR] inheritance/ 12-Jul-2009 03:48 - [ ] perdue_root_071509.pdf 15-Jul-2009 14:55 893K [DIR] simple/ 12-Jul-2009 03:48 - README: The pdf of the talk has internal bookmarks

  6. Index of /safety/hazardousradioactivematerials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    safety/hazardousradioactivematerials Icon Name Last modified Size Description [DIR] Parent Directory - [DIR] documents/ 17-Apr-2013 12:30 - [IMG] example-1.jpg 17-Apr-2013 12:30 25K [IMG] example-2.jpg 17-Apr-2013 12:30 32K [ ] notifications.php 13-Jan-2014 10:39 12K [DIR] notifications/ 17-Apr-2013 12:30 - [ ] smtp.php 17-Apr-2013 12:30 7.4K [ ] upload-notice.php 17-Apr-2013 12:30 8.6K

  7. Modified Embedded Atom Method

    Energy Science and Technology Software Center (OSTI)

    2012-08-01

    Interatomic force and energy calculation subroutine to be used with the molecular dynamics simulation code LAMMPS (Ref a.). The code evaluated the total energy and atomic forces (energy gradient) according to a cubic spline-based variant (Ref b.) of the Modified Embedded Atom Method (MEAM) with a additional Stillinger-Weber (SW) contribution.

  8. Hopper Job Size Charts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Job Size Charts Hopper Job Size Charts Fractional Jobs The following charts show the fraction of hours used on Hopper in each of five job-core-size bins: 2014 Usage by Job Size Chart 2013 2012 2011 Large Jobs The following charts show the fraction of hours used on Hopper by jobs using greater than 16,384 cores: 2014 2013 2012 Usage by Job Size Chart 2011 Last edited: 2016-05-02 09:20:42

  9. Edison Job Size Charts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reports » Edison Job Size Charts Edison Job Size Charts Fraction of Hours Used per Job Size Note: Interactive charts with current and past Cori and Edison data are now available on MyNERSC This chart shows the fraction of hours used on Edison in each of 5 job-core-size bins. 2015 Usage by Job Size Chart 2014 Fraction of Hours Used by Big Jobs This chart shows the fraction of hours used on Edison by jobs using 16,384 or more cores. 2015 Usage by Job Size Chart 2014 Last edited: 2016-04-21

  10. Modified Faraday cup

    DOE Patents [OSTI]

    Elmer, J.W.; Teruya, A.T.; O`Brien, D.W.

    1996-09-10

    A tomographic technique for measuring the current density distribution in electron beams using electron beam profile data acquired from a modified Faraday cup to create an image of the current density in high and low power beams is disclosed. The modified Faraday cup includes a narrow slit and is rotated by a stepper motor and can be moved in the x, y and z directions. The beam is swept across the slit perpendicular thereto and controlled by deflection coils, and the slit rotated such that waveforms are taken every few degrees from 0{degree} to 360{degree} and the waveforms are recorded by a digitizing storage oscilloscope. Two-dimensional and three-dimensional images of the current density distribution in the beam can be reconstructed by computer tomography from this information, providing quantitative information about the beam focus and alignment. 12 figs.

  11. Modified Faraday cup

    DOE Patents [OSTI]

    Elmer, John W.; Teruya, Alan T.; O'Brien, Dennis W.

    1996-01-01

    A tomographic technique for measuring the current density distribution in electron beams using electron beam profile data acquired from a modified Faraday cup to create an image of the current density in high and low power beams. The modified Faraday cup includes a narrow slit and is rotated by a stepper motor and can be moved in the x, y and z directions. The beam is swept across the slit perpendicular thereto and controlled by deflection coils, and the slit rotated such that waveforms are taken every few degrees form 0.degree. to 360.degree. and the waveforms are recorded by a digitizing storage oscilloscope. Two-din-tensional and three-dimensional images of the current density distribution in the beam can be reconstructed by computer tomography from this information, providing quantitative information about the beam focus and alignment.

  12. Modified clay sorbents

    DOE Patents [OSTI]

    Fogler, H. Scott; Srinivasan, Keeran R.

    1990-01-01

    A novel modified clay sorbent and method of treating industrial effluents to remove trace pollutants, such as dioxins, biphenyls, and polyaromatics such as benzo(a)pyrene and pentachlorophenol. The novel clay sorbent has a composite structure in which the interlayer space of an expandable clay, such as smectite, is filled with polyvalent or multivalent inorganic cations which forces weaker surfactant cations to locate on the surface of the clay in such an orientation that the resulting composite is hydrophilic in nature. A specific example is cetylpyridinium-hydroxy aluminum-montmorillonite. In certain embodiments, a non-expanding clay, such as kaolinite, is used and surfactant cations are necessarily located on an external surface of the clay. A specific example is cetylpyridinium-kaolinite.

  13. Does size matter?

    SciTech Connect (OSTI)

    Carreras, B. A.; Physics Department, College of Natural Science and Mathematics and Geophysical Institute, University of Alaska, Fairbanks, Alaska 99775; Physics Department, Universidad Carlos III de Madrid, Madrid ; Newman, D. E.; Dobson, Ian

    2014-06-15

    Failures of the complex infrastructures society depends on having enormous human and economic cost that poses the question: Are there ways to optimize these systems to reduce the risks of failure? A dynamic model of one such system, the power transmission grid, is used to investigate the risk from failure as a function of the system size. It is found that there appears to be optimal sizes for such networks where the risk of failure is balanced by the benefit given by the size.

  14. Demoing the Modified TALON Robot

    Broader source: Energy.gov [DOE]

    A technician at Idaho National Laboratory demonstrates the modified TALON robot; which is being sent to assist emergency workers at Japan's Fukishima nuclear reactor.

  15. File:Construction SW NOI modified 7-18-2011.pdf | Open Energy...

    Open Energy Info (EERE)

    7-18-2011.pdf Jump to: navigation, search File File history File usage File:Construction SW NOI modified 7-18-2011.pdf Size of this preview: 463 599 pixels. Other...

  16. Modified Acyl-ACP desaturase

    DOE Patents [OSTI]

    Cahoon, Edgar B.; Shanklin, John; Lindqvist, Ylva; Schneider, Gunter

    1999-03-30

    Disclosed is a method for modifying the chain length and double bond positional specificities of a soluble plant fatty acid desaturase. More specifically, the method involves modifying amino acid contact residues in the substrate binding channel of the soluble fatty acid desaturase which contact the fatty acid. Specifically disclosed is the modification of an acyl-ACP desaturase. Amino acid contact residues which lie within the substrate binding channel are identified, and subsequently replaced with different residues to effect the modification of activity.

  17. Modified acyl-ACP desaturase

    DOE Patents [OSTI]

    Cahoon, Edgar B.; Shanklin, John; Lindgvist, Ylva; Schneider, Gunter

    1998-01-06

    Disclosed is a methods for modifying the chain length and double bond positional specificities of a soluble plant fatty acid desaturase. More specifically, the method involves modifying amino acid contact residues in the substrate binding channel of the soluble fatty acid desaturase which contact the fatty acid. Specifically disclosed is the modification of an acyl-ACP desaturase. Amino acid contact residues which lie within the substrate binding channel are identified, and subsequently replaced with different residues to effect the modification of activity.

  18. Aerosol mobility size spectrometer

    DOE Patents [OSTI]

    Wang, Jian; Kulkarni, Pramod

    2007-11-20

    A device for measuring aerosol size distribution within a sample containing aerosol particles. The device generally includes a spectrometer housing defining an interior chamber and a camera for recording aerosol size streams exiting the chamber. The housing includes an inlet for introducing a flow medium into the chamber in a flow direction, an aerosol injection port adjacent the inlet for introducing a charged aerosol sample into the chamber, a separation section for applying an electric field to the aerosol sample across the flow direction and an outlet opposite the inlet. In the separation section, the aerosol sample becomes entrained in the flow medium and the aerosol particles within the aerosol sample are separated by size into a plurality of aerosol flow streams under the influence of the electric field. The camera is disposed adjacent the housing outlet for optically detecting a relative position of at least one aerosol flow stream exiting the outlet and for optically detecting the number of aerosol particles within the at least one aerosol flow stream.

  19. Miniature modified Faraday cup for micro electron beams

    DOE Patents [OSTI]

    Teruya, Alan T.; Elmer, John W.; Palmer, Todd A.; Walton, Chris C.

    2008-05-27

    A micro beam Faraday cup assembly includes a refractory metal layer with an odd number of thin, radially positioned traces in this refractory metal layer. Some of the radially positioned traces are located at the edge of the micro modified Faraday cup body and some of the radially positioned traces are located in the central portion of the micro modified Faraday cup body. Each set of traces is connected to a separate data acquisition channel to form multiple independent diagnostic networks. The data obtained from the two diagnostic networks are combined and inputted into a computed tomography algorithm to reconstruct the beam shape, size, and power density distribution.

  20. ARM - Measurement - Cloud droplet size

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    droplet size Linear size (e.g. radius or diameter) of a cloud particle Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the...

  1. Index of /datasets/files/41/pub/PUBID8_0001/Exist

    Open Energy Info (EERE)

    Size DIR Parent Directory - DIR Sim1 18-Apr-2012 11:06 - 429 Throttled (bot load) Error 429 Throttled (bot load) Throttled (bot load) Guru Meditation: XID: 653191375 Varnish...

  2. Index of /datasets/files/41/pub/PUBID8_0001/MaxTech

    Open Energy Info (EERE)

    Size DIR Parent Directory - DIR Sim1 18-Apr-2012 11:06 - 429 Throttled (bot load) Error 429 Throttled (bot load) Throttled (bot load) Guru Meditation: XID: 653191376 Varnish...

  3. Index of /documents/public/root/material/4

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Size Description DIR Parent Directory - ROOTGUIs.pdf 14-Jul-2009 00:34 1.1M DIR ROOTGUIPROGRAMS 13-Jul-2009 18:24 - TarBallGUIPrograms.tar 13-Jul-2009 18:25 15...

  4. Modified acyl-ACP desaturase

    DOE Patents [OSTI]

    Cahoon, E.B.; Shanklin, J.; Lindgvist, Y.; Schneider, G.

    1998-01-06

    Disclosed is a method for modifying the chain length and double bond positional specificities of a soluble plant fatty acid desaturase. More specifically, the method involves modifying amino acid contact residues in the substrate binding channel of the soluble fatty acid desaturase which contact the fatty acid. Specifically disclosed is the modification of an acyl-ACP desaturase. Amino acid contact residues which lie within the substrate binding channel are identified, and subsequently replaced with different residues to effect the modification of activity. 1 fig.

  5. Modified Acyl-ACP desaturase

    DOE Patents [OSTI]

    Cahoon, E.B.; Shanklin, J.; Lindqvist, Y.; Schneider, G.

    1999-03-30

    Disclosed is a method for modifying the chain length and double bond positional specificities of a soluble plant fatty acid desaturase. More specifically, the method involves modifying amino acid contact residues in the substrate binding channel of the soluble fatty acid desaturase which contact the fatty acid. Specifically disclosed is the modification of an acyl-ACP desaturase. Amino acid contact residues which lie within the substrate binding channel are identified, and subsequently replaced with different residues to effect the modification of activity. 2 figs.

  6. Usage by Job Size Table

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Usage by Job Size Table Usage by Job Size Table page loading animation Usage Query Interface System All Hopper Edison Cori Carver Planck Matgen Franklin Hopper 1 Magellan Dirac...

  7. ARM - Campaign Instrument - psp-eppley-modified

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    us a note below or call us at 1-888-ARM-DATA. Send Campaign Instrument : Modified Eppley PSP (PSP-EPPLEY-MODIFIED) Instrument Categories Radiometric Campaigns Diffuse Shortwave IOP...

  8. Adhesives from modified soy protein

    DOE Patents [OSTI]

    Sun, Susan; Wang, Donghai; Zhong, Zhikai; Yang, Guang

    2008-08-26

    The, present invention provides useful adhesive compositions having similar adhesive properties to conventional UF and PPF resins. The compositions generally include a protein portion and modifying ingredient portion selected from the group consisting of carboxyl-containing compounds, aldehyde-containing compounds, epoxy group-containing compounds, and mixtures thereof. The composition is preferably prepared at a pH level at or near the isoelectric point of the protein. In other preferred forms, the adhesive composition includes a protein portion and a carboxyl-containing group portion.

  9. Electrochemical apparatus comprising modified disposable rectangular

    Office of Scientific and Technical Information (OSTI)

    cuvette (Patent) | SciTech Connect Electrochemical apparatus comprising modified disposable rectangular cuvette Citation Details In-Document Search Title: Electrochemical apparatus comprising modified disposable rectangular cuvette Electrochemical apparatus includes a disposable rectangular cuvette modified with at least one hole through a side and/or the bottom. Apparatus may include more than one cuvette, which in practice is a disposable rectangular glass or plastic cuvette modified by

  10. Degradative and Morphological Characterization of POSS Modified...

    Office of Scientific and Technical Information (OSTI)

    Degradative and Morphological Characterization of POSS Modified Nanohybrid Polyurethane Elastomers Citation Details In-Document Search Title: Degradative and Morphological ...

  11. Electrochemical Apparatus with Disposable and Modifiable Parts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    research Benefits: Incorporates disposable, commercially available cuvettes Modifiable design Allows multiple experiments using a single solution Designed for interface with...

  12. ARM - Measurement - Hydrometeor Size Distribution

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of hydrometeors observed in a given size range. Categories Atmospheric State, Cloud Properties Instruments The above measurement is considered scientifically relevant for the...

  13. Considerations for the use of the modified line reversal technique for gas temperature measurement

    SciTech Connect (OSTI)

    Winkleman, B.C.

    1993-06-01

    Several areas related to the successful and accurate application of modified line reversal are discussed. Initially, generalized modified line reversal equations are developed. A review of basic line reversal theory is presented followed by development of correction factors for optical system effects. Image size and their effect on accurate determinations of spectral radiances is discussed. Temperature biases introduced by image vignetting is calculated. Measured image irradiances are given.

  14. Method of modifying a surface

    DOE Patents [OSTI]

    Renk, Timothy J.; Sorensen, Neil R.; Senft, Donna Cowell; Buchheit, Jr., Rudolph G.; Thompson, Michael O.; Grabowski, Kenneth S.

    2000-01-01

    The present invention provides a surface modification method that provides beneficial changes in surface properties, can modify a surface to a greater depth than previous methods, and that is suitable for industrial application. The present method comprises applying a thin-film coating to a surface of a substrate, then subjecting the coated surface to an ion beam. The ion beam power pulse heats the coated surface, leading to alloying between the material in the coating and the material of the substrate. Rapid cooling of the alloyed layer after an ion beam pulse can lead to formation of metastable alloys and microstructures not accessible by conventional alloying methods or intense ion beam treatment of the substrate alone.

  15. SUMMARY OF 2009 RHEOLOGY MODIFIER PROGRAM

    SciTech Connect (OSTI)

    Hansen, E.

    2009-12-08

    The overall objective of the EM-31 Rheological Modifiers and Wetting Agents program is to utilize commercially available rheology modifiers to increase the solids fraction of radioactive sludge based waste streams, resulting in an increase in throughput and decreasing the overall processing time. The program first investigates the impact of rheology modifiers on slurry simulants and then utilizes the most effective rheology modifiers on radioactive slurries. The work presented in this document covers the initial investigation of rheology modifier testing with simulants. This task is supported by both the Savannah River National Laboratory (SRNL) and Pacific Northwest National Laboratory (PNNL). The SRNL EM-31 task, for this year, was to investigate the use of rheology modifiers on simulant Defense Waste Processing Facility (DWPF) melter feeds. The task is to determine, based on the impact of the rheology modifier, if there are rheology modifiers that could reduce the water content of the slurry going to the DWPF melter, hence increasing the melt rate by decreasing the water loading. The rheology modifier in essence would allow a higher solids content slurry to have the same type of rheology or pumpability of a lower solids slurry. The modifiers selected in this report were determined based on previous modifiers used in high level waste melter feed simulants, on-going testing performed by counterparts at PNNL, and experiences gain through use of modifiers in other Department of Energy (DOE) processes such as grout processing. There were 12 rheology modifiers selected for testing, covering both organic and inorganic types and they were tested at four different concentrations for a given melter feed. Five different DWPF melter feeds were available and there was adequate material in one of the melter feeds to increase the solids concentration, resulting in a total of six simulants for testing. The mass of melter feed available in each simulant was not adequate for testing each rheology modifier, hence based on the changes in rheology for a given rheology modifier, rheology modifiers were either dropped or added between simulants. Three rheology modifiers were used on all simulants. The results from this testing indicate that citric acid or polycarboxylate based rheology modifiers are the most effective in reducing the yield stress, by as much as 70% at the higher rheology modifier additions and were effective on most of the tested simulants. These rheology modifiers are organic, hence the can also be used as reductants in melter operations. The most effective non-organic rheology modifiers, sodium metasilicate reduced the yield stress by 10%. It is recommended that both citric acid and commercially available polycarboxylate rheology modifiers be further investigated. Different molecular weight polycarboxylates and different types of polycarboxylates used in other industries must be considered. These polycarboxylates are extensively utilized in the cement, ceramic, and water treatment processes, hence readily available. Future work on DWPF melter feeds involving rheology modifiers should include, assuming the present method of processing sludge through DPWF does not change, is: (1) Investigate the use of polycarboxylate in various processes and procure polycarboxylates for testing. Limit rheology modifier selection and future testing between four and eight different types. (2) Test rheology modifiers on at least two different chemical types or bounding DWPF SME product simulants. Test to include the impact of boiling and the effectiveness in reducing water content via rheology versus weight percent curves. (3) Based on selected modifiers, perform testing on actual radioactive melter feed based on results from simulant testing.

  16. Method for sizing hollow microspheres

    DOE Patents [OSTI]

    Farnum, E.H.; Fries, R.J.

    1975-10-29

    Hollow Microspheres may be effectively sized by placing them beneath a screen stack completely immersed in an ultrasonic bath containing a liquid having a density at which the microspheres float and ultrasonically agitating the bath.

  17. Nonderivative modified gravity: a classification

    SciTech Connect (OSTI)

    Comelli, D.; Nesti, F.; Pilo, L. E-mail: fabrizio.nesti@irb.hr

    2014-11-01

    We analyze the theories of gravity modified by a generic nonderivative potential built from the metric, under the minimal requirement of unbroken spatial rotations. Using the canonical analysis, we classify the potentials V according to the number of degrees of freedom (DoF) that propagate at the nonperturbative level. We then compare the nonperturbative results with the perturbative DoF propagating around Minkowski and FRW backgrounds. A generic V implies 6 propagating DoF at the non-perturbative level, with a ghost on Minkowski background. There exist potentials which propagate 5 DoF, as already studied in previous works. Here, no V with unbroken rotational invariance admitting 4 DoF is found. Theories with 3 DoF turn out to be strongly coupled on Minkowski background. Finally, potentials with only the 2 DoF of a massive graviton exist. Their effect on cosmology is simply equivalent to a cosmological constant. Potentials with 2 or 5 DoF and explicit time dependence appear to be a further viable possibility.

  18. Guidance Regarding Refinancing, Restructuring, or Modifying Loan...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Regarding Refinancing, Restructuring, or Modifying Loan Agreements Entered into by an Energy Services Company Under a Federal Energy Savings Performance Contract Guidance Regarding...

  19. Modified Accelerated Cost-Recovery System (MACRS)

    Office of Energy Efficiency and Renewable Energy (EERE)

    Under the federal Modified Accelerated Cost-Recovery System (MACRS), businesses may recover investments in certain property through depreciation deductions. The MACRS establishes a set of class...

  20. Nanoparticles modified with multiple organic acids

    DOE Patents [OSTI]

    Cook, Ronald Lee; Luebben, Silvia DeVito; Myers, Andrew William; Smith, Bryan Matthew; Elliott, Brian John; Kreutzer, Cory; Wilson, Carolina; Meiser, Manfred

    2007-07-17

    Surface-modified nanoparticles of boehmite, and methods for preparing the same. Aluminum oxyhydroxide nanoparticles are surface modified by reaction with selected amounts of organic acids. In particular, the nanoparticle surface is modified by reactions with two or more different carboxylic acids, at least one of which is an organic carboxylic acid. The product is a surface modified boehmite nanoparticle that has an inorganic aluminum oxyhydroxide core, or part aluminum oxyhydroxide core and a surface-bonded organic shell. Organic carboxylic acids of this invention contain at least one carboxylic acid group and one carbon-hydrogen bond. One embodiment of this invention provides boehmite nanoparticles that have been surface modified with two or more acids one of which additional carries at least one reactive functional group. Another embodiment of this invention provides boehmite nanoparticles that have been surface modified with multiple acids one of which has molecular weight or average molecular weight greater than or equal to 500 Daltons. Yet, another embodiment of this invention provides boehmite nanoparticles that are surface modified with two or more acids one of which is hydrophobic in nature and has solubility in water of less than 15 by weight. The products of the methods of this invention have specific useful properties when used in mixture with liquids, as filler in solids, or as stand-alone entities.

  1. File:NREL-asia-dir.pdf | Open Energy Information

    Open Energy Info (EERE)

    Countries Bhutan, China, Nepal, Mongolia, India, North Korea, South Korea, Vietnam, Laos, Thailand, Cambodia, Philippines, Bangladesh UN Region Southern Asia, Eastern Asia,...

  2. Chemically modified graphite for electrochemical cells

    DOE Patents [OSTI]

    Greinke, Ronald Alfred (Medina, OH); Lewis, Irwin Charles (Strongsville, OH)

    1998-01-01

    This invention relates to chemically modified graphite particles: (a) that are useful in alkali metal-containing electrode of a electrochemical cell comprising: (i) the electrode, (ii) a non-aqueous electrolytic solution comprising an organic aprotic solvent which solvent tends to decompose when the electrochemical cell is in use, and an electrically conductive salt of an alkali metal, and (iii) a counterelectrode; and (b) that are chemically modified with fluorine, chlorine, iodine or phosphorus to reduce such decomposition. This invention also relates to electrodes comprising such chemically modified graphite and a binder and to electrochemical cells containing such electrodes.

  3. Chemically modified graphite for electrochemical cells

    DOE Patents [OSTI]

    Greinke, R.A.; Lewis, I.C.

    1998-05-26

    This invention relates to chemically modified graphite particles: (a) that are useful in alkali metal-containing electrode of a electrochemical cell comprising: (1) the electrode, (2) a non-aqueous electrolytic solution comprising an organic aprotic solvent which solvent tends to decompose when the electrochemical cell is in use, and an electrically conductive salt of an alkali metal, and (3) a counter electrode; and (b) that are chemically modified with fluorine, chlorine, iodine or phosphorus to reduce such decomposition. This invention also relates to electrodes comprising such chemically modified graphite and a binder and to electrochemical cells containing such electrodes. 3 figs.

  4. Review Of Rheology Modifiers For Hanford Waste

    SciTech Connect (OSTI)

    Pareizs, J. M.

    2013-09-30

    As part of Savannah River National Laboratory (SRNL)'s strategic development scope for the Department of Energy - Office of River Protection (DOE-ORP) Hanford Tank Waste Treatment and Immobilization Plant (WTP) waste feed acceptance and product qualification scope, the SRNL has been requested to recommend candidate rheology modifiers to be evaluated to adjust slurry properties in the Hanford Tank Farm. SRNL has performed extensive testing of rheology modifiers for use with Defense Waste Processing Facility (DWPF) simulated melter feed - a high undissolved solids (UDS) mixture of simulated Savannah River Site (SRS) Tank Farm sludge, nitric and formic acids, and glass frit. A much smaller set of evaluations with Hanford simulated waste have also been completed. This report summarizes past work and recommends modifiers for further evaluation with Hanford simulated wastes followed by verification with actual waste samples. Based on the review of available data, a few compounds/systems appear to hold the most promise. For all types of evaluated simulated wastes (caustic Handford tank waste and DWPF processing samples with pH ranging from slightly acidic to slightly caustic), polyacrylic acid had positive impacts on rheology. Citric acid also showed improvement in yield stress on a wide variety of samples. It is recommended that both polyacrylic acid and citric acid be further evaluated as rheology modifiers for Hanford waste. These materials are weak organic acids with the following potential issues: The acidic nature of the modifiers may impact waste pH, if added in very large doses. If pH is significantly reduced by the modifier addition, dissolution of UDS and increased corrosion of tanks, piping, pumps, and other process equipment could occur. Smaller shifts in pH could reduce aluminum solubility, which would be expected to increase the yield stress of the sludge. Therefore, it is expected that use of an acidic modifier would be limited to concentrations that do not appreciably change the pH of the waste; Organics are typically reductants and could impact glass REDOX if not accounted for in the reductant addition calculations; Stability of the modifiers in a caustic, radioactive environment is not known, but some of the modifiers tested were specifically designed to withstand caustic conditions; These acids will add to the total organic carbon content of the wastes. Radiolytic decomposition of the acids could result in organic and hydrogen gas generation. These potential impacts must be addressed in future studies with simulants representative of real waste and finally with tests using actual waste based on the rheology differences seen between SRS simulants and actual waste. The only non-organic modifier evaluated was sodium metasilicate. Further evaluation of this modifier is recommended if a reducing modifier is a concern.

  5. Strategy Guideline: HVAC Equipment Sizing

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Strategy Guideline: HVAC Equipment Sizing Arlan Burdick IBACOS, Inc. February 2012 This report received minimal editorial review at NREL NOTICE This report was prepared as an account of work sponsored by an agency of the United States government. Neither the United States government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information,

  6. Strategy Guideline: HVAC Equipment Sizing

    SciTech Connect (OSTI)

    Burdick, A.

    2012-02-01

    The heating, ventilation, and air conditioning (HVAC) system is arguably the most complex system installed in a house and is a substantial component of the total house energy use. A right-sized HVAC system will provide the desired occupant comfort and will run efficiently. This Strategy Guideline discusses the information needed to initially select the equipment for a properly designed HVAC system. Right-sizing of an HVAC system involves the selection of equipment and the design of the air distribution system to meet the accurate predicted heating and cooling loads of the house. Right-sizing the HVAC system begins with an accurate understanding of the heating and cooling loads on a space; however, a full HVAC design involves more than just the load estimate calculation - the load calculation is the first step of the iterative HVAC design procedure. This guide describes the equipment selection of a split system air conditioner and furnace for an example house in Chicago, IL as well as a heat pump system for an example house in Orlando, Florida. The required heating and cooling load information for the two example houses was developed in the Department of Energy Building America Strategy Guideline: Accurate Heating and Cooling Load Calculations.

  7. Size exclusion deep bed filtration: Experimental and modelling uncertainties

    SciTech Connect (OSTI)

    Badalyan, Alexander You, Zhenjiang; Aji, Kaiser; Bedrikovetsky, Pavel; Carageorgos, Themis; Zeinijahromi, Abbas

    2014-01-15

    A detailed uncertainty analysis associated with carboxyl-modified latex particle capture in glass bead-formed porous media enabled verification of the two theoretical stochastic models for prediction of particle retention due to size exclusion. At the beginning of this analysis it is established that size exclusion is a dominant particle capture mechanism in the present study: calculated significant repulsive Derjaguin-Landau-Verwey-Overbeek potential between latex particles and glass beads is an indication of their mutual repulsion, thus, fulfilling the necessary condition for size exclusion. Applying linear uncertainty propagation method in the form of truncated Taylor's series expansion, combined standard uncertainties (CSUs) in normalised suspended particle concentrations are calculated using CSUs in experimentally determined parameters such as: an inlet volumetric flowrate of suspension, particle number in suspensions, particle concentrations in inlet and outlet streams, particle and pore throat size distributions. Weathering of glass beads in high alkaline solutions does not appreciably change particle size distribution, and, therefore, is not considered as an additional contributor to the weighted mean particle radius and corresponded weighted mean standard deviation. Weighted mean particle radius and LogNormal mean pore throat radius are characterised by the highest CSUs among all experimental parameters translating to high CSU in the jamming ratio factor (dimensionless particle size). Normalised suspended particle concentrations calculated via two theoretical models are characterised by higher CSUs than those for experimental data. The model accounting the fraction of inaccessible flow as a function of latex particle radius excellently predicts normalised suspended particle concentrations for the whole range of jamming ratios. The presented uncertainty analysis can be also used for comparison of intra- and inter-laboratory particle size exclusion data.

  8. DNA polymerase having modified nucleotide binding site for DNA sequencing

    DOE Patents [OSTI]

    Tabor, S.; Richardson, C.

    1997-03-25

    A modified gene encoding a modified DNA polymerase is disclosed. The modified polymerase incorporates dideoxynucleotides at least 20-fold better compared to the corresponding deoxynucleotides as compared with the corresponding naturally-occurring DNA polymerase. 6 figs.

  9. DNA polymerase having modified nucleotide binding site for DNA sequencing

    DOE Patents [OSTI]

    Tabor, Stanley; Richardson, Charles

    1997-01-01

    Modified gene encoding a modified DNA polymerase wherein the modified polymerase incorporates dideoxynucleotides at least 20-fold better compared to the corresponding deoxynucleotides as compared with the corresponding naturally-occurring DNA polymerase.

  10. Lithium modified zeolite synthesis for conversion of biodiesel-derived glycerol to polyglycerol

    SciTech Connect (OSTI)

    Ayoub, Muhammad; Abdullah, Ahmad Zuhairi; Inayat, Abrar

    2014-10-24

    Basic zeolite has received significant attention in the catalysis community. These zeolites modified with alkaline are the potential replacement for existing zeolite catalysts due to its unique features with added advantages. The present paper covers the preparation of lithium modified zeolite Y (Li-ZeY) and its activity for solvent free conversion of biodiesel-derived glycerol to polyglycerol via etherification process. The modified zeolite was well characterized by X-ray diffraction (XRD), Scanning Electron Microscope (SEM) and Nitrogen Adsorption. The SEM images showed that there was no change in morphology of modified zeolite structure after lithium modification. XRD patterns showed that the structure of zeolite was sustained after lithium modification. The surface properties of parent and modified zeolite was also observed N{sub 2} adsortion-desorption technique and found some changes in surface area and pore size. In addition, the basic strength of prepared materials was measured by Hammet indicators and found that basic strength of Li-ZeY was highly improved. This modified zeolite was found highly thermal stable and active heterogamous basic catalyst for conversion of solvent free glycerol to polyglycerol. This reaction was conducted at different temperatures and 260 C was found most active temperature for this process for reaction time from 6 to 12 h over this basic catalyst in the absence of solvent.

  11. Modified Microgrid Concept for Rural Electrification in Africa...

    Open Energy Info (EERE)

    Modified Microgrid Concept for Rural Electrification in Africa Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Modified Microgrid Concept for Rural Electrification in...

  12. A new design for a disposable and modifiable electrochemical...

    Office of Scientific and Technical Information (OSTI)

    A new design for a disposable and modifiable electrochemical cell Citation Details In-Document Search Title: A new design for a disposable and modifiable electrochemical cell ...

  13. In-situ characterization of plasma modified surfaces by vibrational...

    Office of Scientific and Technical Information (OSTI)

    of plasma modified surfaces by vibrational sum frequency generation spectroscopy. Citation Details In-Document Search Title: In-situ characterization of plasma modified surfaces ...

  14. Surface modified CFx cathode material for ultrafast discharge...

    Office of Scientific and Technical Information (OSTI)

    Surface modified CFx cathode material for ultrafast discharge and high energy density Prev Next Title: Surface modified CFx cathode material for ultrafast discharge and high...

  15. Webinar: Genetically Modified Algae: A Risk-Benefit Assessment...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Algae: A Risk-Benefit Assessment Webinar: Genetically Modified Algae: A Risk-Benefit Assessment Genetically Modified (GM) Algae: A Risk-Benefit Assessment PDF icon...

  16. Plants having modified response to ethylene

    DOE Patents [OSTI]

    Meyerowitz, E.M.; Chang, C.; Bleecker, A.B.

    1998-10-20

    The invention includes transformed plants having at least one cell transformed with a modified ETR nucleic acid. Such plants have a phenotype characterized by a decrease in the response of at least one transformed plant cell to ethylene as compared to a plant not containing the transformed plant cell. Tissue and/or temporal specificity for expression of the modified ETR nucleic acid is controlled by selecting appropriate expression regulation sequences to target the location and/or time of expression of the transformed nucleic acid. The plants are made by transforming at least one plant cell with an appropriate modified ETR nucleic acid, regenerating plants from one or more of the transformed plant cells and selecting at least one plant having the desired phenotype. 67 figs.

  17. Plants having modified response to ethylene

    DOE Patents [OSTI]

    Meyerowitz, E.M.; Chang, C.; Bleecker, A.B.

    1997-11-18

    The invention includes transformed plants having at least one cell transformed with a modified ETR nucleic acid. Such plants have a phenotype characterized by a decrease in the response of at least one transformed plant cell to ethylene as compared to a plant not containing the transformed plant cell. Tissue and/or temporal specificity for expression of the modified ETR nucleic acid is controlled by selecting appropriate expression regulation sequences to target the location and/or time of expression of the transformed nucleic acid. The plants are made by transforming at least one plant cell with an appropriate modified ETR nucleic acid, regenerating plants from one or more of the transformed plant cells and selecting at least one plant having the desired phenotype. 31 figs.

  18. Plants having modified response to ethylene

    DOE Patents [OSTI]

    Meyerowitz, Elliott M.; Chang, Caren; Bleecker, Anthony B.

    1997-01-01

    The invention includes transformed plants having at least one cell transformed with a modified ETR nucleic acid. Such plants have a phenotype characterized by a decrease in the response of at least one transformed plant cell to ethylene as compared to a plant not containing the transformed plant cell. Tissue and/or temporal specificity for expression of the modified ETR nucleic acid is controlled by selecting appropriate expression regulation sequences to target the location and/or time of expression of the transformed nucleic acid. The plants are made by transforming at least one plant cell with an appropriate modified ETR nucleic acid, regenerating plants from one or more of the transformed plant cells and selecting at least one plant having the desired phenotype.

  19. Plants having modified response to ethylene

    DOE Patents [OSTI]

    Meyerowitz, Elliot M.; Chang, Caren; Bleecker, Anthony B.

    1998-01-01

    The invention includes transformed plants having at least one cell transformed with a modified ETR nucleic acid. Such plants have a phenotype characterized by a decrease in the response of at least one transformed plant cell to ethylene as compared to a plant not containing the transformed plant cell. Tissue and/or temporal specificity for expression of the modified ETR nucleic acid is controlled by selecting appropriate expression regulation sequences to target the location and/or time of expression of the transformed nucleic acid. The plants are made by transforming at least one plant cell with an appropriate modified ETR nucleic acid, regenerating plants from one or more of the transformed plant cells and selecting at least one plant having the desired phenotype.

  20. Electrochemical apparatus comprising modified disposable rectangular cuvette

    DOE Patents [OSTI]

    Dattelbaum, Andrew M; Gupta, Gautam; Morris, David E

    2013-09-10

    Electrochemical apparatus includes a disposable rectangular cuvette modified with at least one hole through a side and/or the bottom. Apparatus may include more than one cuvette, which in practice is a disposable rectangular glass or plastic cuvette modified by drilling the hole(s) through. The apparatus include two plates and some means of fastening one plate to the other. The apparatus may be interfaced with a fiber optic or microscope objective, and a spectrometer for spectroscopic studies. The apparatus are suitable for a variety of electrochemical experiments, including surface electrochemistry, bulk electrolysis, and flow cell experiments.

  1. Hazards of explosives dusts: Particle size effects

    SciTech Connect (OSTI)

    Cashdollar, K L; Hertzberg, M; Green, G M

    1992-02-01

    At the request of the Department of Energy, the Bureau of Mines has investigated the hazards of military explosives dispersed as dust clouds in a 20-L test chamber. In this report, the effect of particle size for HMX, HNS, RDX, TATB, and TNT explosives dusts is studied in detail. The explosibility data for these dusts are also compared to those for pure fuel dusts. The data show that all of the sizes of the explosives dusts that were studied were capable of sustaining explosions as dust clouds dispersed in air. The finest sizes (<10 [mu]m) of explosives dusts were less reactive than the intermediate sizes (20 to 60 [mu]m); this is opposite to the particle size effect observed previously for the pure fuel dusts. At the largest sizes studied, the explosives dusts become somewhat less reactive as dispersed dust clouds. The six sizes of the HMX dust were also studied as dust clouds dispersed in nitrogen.

  2. Sandia Modifies Delft3D Turbine Model

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Modifies Delft3D Turbine Model - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs

  3. Theoretical priors on modified growth parametrisations

    SciTech Connect (OSTI)

    Song, Yong-Seon; Hollenstein, Lukas; Caldera-Cabral, Gabriela; Koyama, Kazuya E-mail: Lukas.Hollenstein@unige.ch E-mail: Kazuya.Koyama@port.ac.uk

    2010-04-01

    Next generation surveys will observe the large-scale structure of the Universe with unprecedented accuracy. This will enable us to test the relationships between matter over-densities, the curvature perturbation and the Newtonian potential. Any large-distance modification of gravity or exotic nature of dark energy modifies these relationships as compared to those predicted in the standard smooth dark energy model based on General Relativity. In linear theory of structure growth such modifications are often parameterised by virtue of two functions of space and time that enter the relation of the curvature perturbation to, first, the matter over- density, and second, the Newtonian potential. We investigate the predictions for these functions in Brans-Dicke theory, clustering dark energy models and interacting dark energy models. We find that each theory has a distinct path in the parameter space of modified growth. Understanding these theoretical priors on the parameterisations of modified growth is essential to reveal the nature of cosmic acceleration with the help of upcoming observations of structure formation.

  4. Investigation of thermochemical biorefinery sizing and environmental...

    Office of Scientific and Technical Information (OSTI)

    Investigation of thermochemical biorefinery sizing and environmental sustainability impacts for conventional supply system and distributed pre-processing supply system designs...

  5. V-127: Samba Bug Lets Remote Authenticated Users Modify Files...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    7: Samba Bug Lets Remote Authenticated Users Modify Files V-127: Samba Bug Lets Remote Authenticated Users Modify Files April 5, 2013 - 6:00am Addthis PROBLEM: A vulnerability was...

  6. Reduced-Order Model Based Feedback Control For Modified Hasegawa...

    Office of Scientific and Technical Information (OSTI)

    Reduced-Order Model Based Feedback Control For Modified Hasegawa-Wakatani Model Citation Details In-Document Search Title: Reduced-Order Model Based Feedback Control For Modified ...

  7. Boron modified molybdenum silicide and products

    DOE Patents [OSTI]

    Meyer, Mitchell K.; Akinc, Mufit

    1999-02-02

    A boron-modified molybdenum silicide material having the composition comprising about 80 to about 90 weight % Mo, about 10 to about 20 weight % Si, and about 0.1 to about 2 weight % B and a multiphase microstructure including Mo.sub.5 Si.sub.3 phase as at least one microstructural component effective to impart good high temperature creep resistance. The boron-modified molybdenum silicide material is fabricated into such products as electrical components, such as resistors and interconnects, that exhibit oxidation resistance to withstand high temperatures in service in air as a result of electrical power dissipation, electrical resistance heating elements that can withstand high temperatures in service in air and other oxygen-bearing atmospheres and can span greater distances than MoSi.sub.2 heating elements due to improved creep resistance, and high temperature structural members and other fabricated components that can withstand high temperatures in service in air or other oxygen-bearing atmospheres while retaining creep resistance associated with Mo.sub.5 Si.sub.3 for structural integrity.

  8. Boron modified molybdenum silicide and products

    DOE Patents [OSTI]

    Meyer, M.K.; Akinc, M.

    1999-02-02

    A boron-modified molybdenum silicide material is disclosed having the composition comprising about 80 to about 90 weight % Mo, about 10 to about 20 weight % Si, and about 0.1 to about 2 weight % B and a multiphase microstructure including Mo{sub 5}Si{sub 3} phase as at least one microstructural component effective to impart good high temperature creep resistance. The boron-modified molybdenum silicide material is fabricated into such products as electrical components, such as resistors and interconnects, that exhibit oxidation resistance to withstand high temperatures in service in air as a result of electrical power dissipation, electrical resistance heating elements that can withstand high temperatures in service in air and other oxygen-bearing atmospheres and can span greater distances than MoSi{sub 2} heating elements due to improved creep resistance, and high temperature structural members and other fabricated components that can withstand high temperatures in service in air or other oxygen-bearing atmospheres while retaining creep resistance associated with Mo{sub 5}Si{sub 3} for structural integrity. 7 figs.

  9. Chemically modified carbonic anhydrases useful in carbon capture systems

    DOE Patents [OSTI]

    Novick, Scott; Alvizo, Oscar

    2013-01-15

    The present disclosure relates to chemically modified carbonic anhydrase polypeptides and soluble compositions, homogenous liquid formulations comprising them. The chemically modified carbonic anhydrase polypeptides have improved properties relative to the same carbonic anhydrase polypeptide that is not chemically modified including the improved properties of increased activity and/or stability in the presence of amine compounds, ammonia, or carbonate ion. The present disclosure also provides methods of preparing the chemically modified polypeptides and methods of using the chemically modified polypeptides for accelerating the absorption of carbon dioxide from a gas stream into a solution as well as for the release of the absorbed carbon dioxide for further treatment and/or sequestering.

  10. Chemically modified carbonic anhydrases useful in carbon capture systems

    DOE Patents [OSTI]

    Novick, Scott J; Alvizo, Oscar

    2013-10-29

    The present disclosure relates to chemically modified carbonic anhydrase polypeptides and soluble compositions, homogenous liquid formulations comprising them. The chemically modified carbonic anhydrase polypeptides have improved properties relative to the same carbonic anhydrase polypeptide that is not chemically modified including the improved properties of increased activity and/or stability in the presence of amine compounds, ammonia, or carbonate ion. The present disclosure also provides methods of preparing the chemically modified polypeptides and methods of using the chemically modified polypeptides for accelerating the absorption of carbon dioxide from a gas stream into a solution as well as for the release of the absorbed carbon dioxide for further treatment and/or sequestering.

  11. Astrophysical black holes in screened modified gravity

    SciTech Connect (OSTI)

    Davis, Anne-Christine; Jha, Rahul; Muir, Jessica; Gregory, Ruth E-mail: r.a.w.gregory@durham.ac.uk E-mail: jlmuir@umich.edu

    2014-08-01

    Chameleon, environmentally dependent dilaton, and symmetron gravity are three models of modified gravity in which the effects of the additional scalar degree of freedom are screened in dense environments. They have been extensively studied in laboratory, cosmological, and astrophysical contexts. In this paper, we present a preliminary investigation into whether additional constraints can be provided by studying these scalar fields around black holes. By looking at the properties of a static, spherically symmetric black hole, we find that the presence of a non-uniform matter distribution induces a non-constant scalar profile in chameleon and dilaton, but not necessarily symmetron gravity. An order of magnitude estimate shows that the effects of these profiles on in-falling test particles will be sub-leading compared to gravitational waves and hence observationally challenging to detect.

  12. Radionuclide partitioning in the modified Unex process

    SciTech Connect (OSTI)

    Babain, V.; Smirnov, I.; Alyapyshev, M.; Todd, T.A.; Law, J.D.; Herbst, R.S.; Paulenova, A.

    2008-07-01

    The Universal Extraction (UNEX) process has been developed for simultaneous extraction of long-lived radionuclides (cesium, strontium, actinides, and lanthanides) from acidic solutions in one extraction cycle. Modification of this organic solvent through the use of diamides of dipicolinic acid instead of CMPO increases the extraction capacity of UNEX solvent toward lanthanides and actinide metals, allowing for the processing of spent nuclear fuel. The possibility of radionuclide group separation using the modified UNEX solvent [HCCD (chlorinated cobalt dicarbollide), TBDPA (tetrabutyl-diamide of dipicolinic acid), PEG in FS-1 3 (phenyl-trifluoromethyl-sulfone)] is being investigated. Individual strip products, including a) actinides and lanthanides, b) strontium, and c) cesium, can be obtained by selective stripping from UNEX solvent. Such partitioning will make it possible to transform the Cs/Sr product into the most stable matrices for long-term storage and to further process the actinide/lanthanide product for recycling to a nuclear reactor. (authors)

  13. ARM - Measurement - Cloud particle size distribution

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from you Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Cloud particle size distribution The number of cloud particles present in any given volume of air...

  14. " Row: Employment Sizes within NAICS Codes...

    U.S. Energy Information Administration (EIA) Indexed Site

    " 311 - 339","ALL MANUFACTURING INDUSTRIES" ,"Employment Size" ," Under 50",562.6,4.7,2.4 ," 50-99",673.1,5.1,2.4 ," 100-249",1072.799927,6.459656809,2.981380066 ," ...

  15. " Row: Employment Sizes within NAICS Codes...

    U.S. Energy Information Administration (EIA) Indexed Site

    " 311 - 339","ALL MANUFACTURING INDUSTRIES" ,"Employment Size" ," Under 50",507.3,6.7,3.4,2.6 ," 50-99",561.6,6.7,3.2,3 ," 100-249",913.6,9.2,4.4,2 ," ...

  16. Method of precisely modifying predetermined surface layers of a workpiece by cluster ion impact therewith

    DOE Patents [OSTI]

    Friedman, L.; Beuhler, R.J.; Matthew, M.W.; Ledbetter, M.

    1984-06-25

    A method of precisely modifying a selected area of a workpiece by producing a beam of charged cluster ions that is narrowly mass selected to a predetermined mean size of cluster ions within a range of 25 to 10/sup 6/ atoms per cluster ion, and accelerated in a beam to a critical velocity. The accelerated beam is used to impact a selected area of an outer surface of the workpiece at a preselected rate of impacts of cluster ions/cm/sup 2//sec in order to effect a precise modification in that selected area of the workpiece.

  17. Method of precisely modifying predetermined surface layers of a workpiece by cluster ion impact therewith

    DOE Patents [OSTI]

    Friedman, Lewis; Buehler, Robert J.; Matthew, Michael W.; Ledbetter, Myron

    1985-01-01

    A method of precisely modifying a selected area of a workpiece by producing a beam of charged cluster ions that is narrowly mass selected to a predetermined mean size of cluster ions within a range of 25 to 10.sup.6 atoms per cluster ion, and accelerated in a beam to a critical velocity. The accelerated beam is used to impact a selected area of an outer surface of the workpiece at a preselected rate of impacts of cluster ions/cm.sup.2 /sec. in order to effect a precise modification in that selected area of the workpiece.

  18. Investigations of initiation spot size effects

    SciTech Connect (OSTI)

    Clarke, Steven A; Akinci, Adrian A; Leichty, Gary; Schaffer, Timothy; Murphy, Michael J; Munger, Alan; Thomas, Keith A

    2010-01-01

    As explosive components become smaller, a greater understanding of the effect of initiation spot size on detonation becomes increasingly critical. A series of tests of the effect of initiation spot size will be described. A series of DOI (direct optical initiation) detonators with initiation spots sizes from {approx}50 um to 1000um have been tested to determine laser parameters for threshold firing of low density PETN pressings. Results will be compared with theoretical predictions. Outputs of the initiation source (DOI ablation) have been characterized by a suite of diagnostics including PDV and schlieren imaging. Outputs of complete detonators have been characterized using PDV, streak, and/or schlieren imaging. At present, we have not found the expected change in the threshold energy to spot size relationship for DOI type detonators found in similar earlier for projectiles, slappers and EBWs. New detonators designs (Type C) are currently being tested that will allow the determination of the threshold for spot sizes from 250 um to 105um, where we hope to see change in the threshold vs. spot size relationship. Also, one test of an extremely small diameter spot size (50um) has resulted in preliminary NoGo only results even at energy densities as much as 8 times the energy density of the threshold results presented here. This gives preliminary evidence that 50um spot may be beyond the critical initiation diameter. The constant threshold energy to spot size relationship in the data to date does however still give some insight into the initiation mechanism of DOI detonators. If the DOI initiation mechanism were a 1D mechanism similar to a slapper or a flyer impact, the expected inflection point in the graph would have been between 300um and 500um diameter spot size, within the range of the data presented here. The lack of that inflection point indicates that the DOI initiation mechanism is more likely a 2D mechanism similar to a sphere or rod projectile. We expect to see a three region response as the results from the smaller spot size Type C detonators are completed.

  19. Sizing a New Water Heater | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sizing a New Water Heater Sizing a New Water Heater Is your water heater the right size for you house? | Photo credit ENERGY STAR Is your water heater the right size for you ...

  20. System Configured For Applying Multiple Modifying Agents To A Substrate.

    DOE Patents [OSTI]

    Propp, W. Alan; Argyle, Mark D.; Janikowski, Stuart K.; Fox, Robert V.; Toth, William J.; Ginosar, Daniel M.; Allen, Charles A.; Miller, David L.

    2005-11-08

    The present invention is related to the modifying of substrates with multiple modifying agents in a single continuous system. At least two processing chambers are configured for modifying the substrate in a continuous feed system. The processing chambers can be substantially isolated from one another by interstitial seals. Additionally, the two processing chambers can be substantially isolated from the surrounding atmosphere by end seals. Optionally, expansion chambers can be used to separate the seals from the processing chambers.

  1. System configured for applying multiple modifying agents to a substrate

    DOE Patents [OSTI]

    Propp, W. Alan; Argyle, Mark D.; Janikowski, Stuart K.; Fox, Robert V.; Toth, William J.; Ginosar, Daniel M.; Allen, Charles A.; Miller, David L.

    2003-11-25

    The present invention is related to the modifying of substrates with multiple modifying agents in a single continuous system. At least two processing chambers are configured for modifying the substrate in a continuous feed system. The processing chambers can be substantially isolated from one another by interstitial seals. Additionally, the two processing chambers can be substantially isolated from the surrounding atmosphere by end seals. Optionally, expansion chambers can be used to separate the seals from the processing chambers.

  2. Method of modifying a volume mesh using sheet extraction

    DOE Patents [OSTI]

    Borden, Michael J.; Shepherd, Jason F.

    2007-02-20

    A method and machine-readable medium provide a technique to modify a hexahedral finite element volume mesh using dual generation and sheet extraction. After generating a dual of a volume stack (mesh), a predetermined algorithm may be followed to modify the volume mesh of hexahedral elements. The predetermined algorithm may include the steps of determining a sheet of hexahedral mesh elements, generating nodes for merging, and merging the nodes to delete the sheet of hexahedral mesh elements and modify the volume mesh.

  3. Highly Charged Ion (HCI) Modified Tunnel Junctions

    SciTech Connect (OSTI)

    Pomeroy, J. M.; Grube, H. [Atomic Physics Division, National Institute of Standards and Technology (NIST) 100 Bureau Dr., MS 8423, Gaithersburg, MD 20899-8423 (United States)

    2009-03-10

    The neutralization energy carried by highly charged ions (HCIs) provides an alternative method for localizing energy on a target's surface, producing features and modifying surfaces with fluences and kinetic energy damage that are negligible compared to singly ionized atoms. Since each HCI can deposit an enormous amount of energy into a small volume of the surface (e.g., Xe{sup 44+} delivers 51 keV of neutralization energy per HCI), each individual HCI's interaction with the target can produce a nanoscale feature. Many studies of HCI-surface features have characterized some basic principles of this unique ion-surface interaction, but the activity reported here has been focused on studying ensembles of HCI features in ultra-thin insulating films by fabricating multi-layer tunnel junction devices. The ultra-thin insulating barriers allow current to flow by tunneling, providing a very sensitive means of detecting changes in the barrier due to highly charged ion irradiation and, conversely, HCI modification provides a method of finely tuning the transparency of the tunnel junctions that spans several orders of magnitude for devices produced from a single process recipe. Systematic variation of junction bias, temperature, magnetic field and other parameters provides determination of the transport mechanism, defect densities, and magnetic properties of these nano-features and this novel approach to device fabrication.

  4. Calibration of a Modified Californium Shuffler

    SciTech Connect (OSTI)

    Sadowski, E.T.; Armstrong, F.; Oldham, R.; Ceo, R.; Williams, N.

    1995-06-01

    A californium shuffler originally designed to assay hollow cylindrical pieces of UA1 has been modified to assay solid cylinders. Calibration standards were characterized via chemical analysis of the molten UA1 taken during casting of the standards. The melt samples yielded much more reliable characterization data than drill samples taken from standards after the standards had solidified. By normalizing one well-characterized calibration curve to several standards at different enrichments, a relatively small number of standards was required to develop an enrichment-dependent calibration. The precision of this shuffler is 0.65%, and the typical random and systematic uncertainties are 0.53% and 0.73%, respectively, for a six minute assay of an ingot containing approximately 700 grams of {sup 235}U. This paper will discuss (1) the discrepancies encountered when UA1 standards were characterized via melt samples versus drill samples, (2) a calibration methodology employing a small number of standards, and (3) a comparison of results from a previously unused shuffler with an existing shuffler. A small number of UA1 standards have been characterized using samples from the homogeneous molten state and have yielded enrichment-dependent and enrichment-independent calibration curves on two different shufflers.

  5. Comment on ''Modifying the variational principle in theaction...

    Office of Scientific and Technical Information (OSTI)

    Comment on ''Modifying the variational principle in the action-integral-functional derivation of time-dependent density-functional theory'' Citation Details In-Document Search ...

  6. CHARACTERIZATION OF NEAR NET-SHAPE CASTABLE RARE EARTH MODIFIED...

    Office of Scientific and Technical Information (OSTI)

    CHARACTERIZATION OF NEAR NET-SHAPE CASTABLE RARE EARTH MODIFIED ALUMINUM ALLOYS FOR HIGH TEMPERATURE APPLICATION Citation Details In-Document Search Title: CHARACTERIZATION OF NEAR ...

  7. Surface modified CFx cathode material for ultrafast discharge...

    Office of Scientific and Technical Information (OSTI)

    CFx. The modified CFx, consisting of an in situ generated shell component of F-graphene layers, possesses good electronic conductivity and removes the transporting barrier...

  8. Method of modifying a volume mesh using sheet insertion

    DOE Patents [OSTI]

    Borden, Michael J.; Shepherd, Jason F.

    2006-08-29

    A method and machine-readable medium provide a technique to modify a hexahedral finite element volume mesh using dual generation and sheet insertion. After generating a dual of a volume stack (mesh), a predetermined algorithm may be followed to modify (refine) the volume mesh of hexahedral elements. The predetermined algorithm may include the steps of locating a sheet of hexahedral mesh elements, determining a plurality of hexahedral elements within the sheet to refine, shrinking the plurality of elements, and inserting a new sheet of hexahedral elements adjacently to modify the volume mesh. Additionally, another predetermined algorithm using mesh cutting may be followed to modify a volume mesh.

  9. Highly Active and Selective Metal-modified Zeolite Catalysts...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Active and Selective Metal-modified Zeolite Catalysts for Low Temperature Conversion of Methanol and Dimethyl Ether to Gasoline-range Branched Hydrocarbons National Renewable...

  10. Size separation of analytes using monomeric surfactants

    DOE Patents [OSTI]

    Yeung, Edward S.; Wei, Wei

    2005-04-12

    A sieving medium for use in the separation of analytes in a sample containing at least one such analyte comprises a monomeric non-ionic surfactant of the of the general formula, B-A, wherein A is a hydrophilic moiety and B is a hydrophobic moiety, present in a solvent at a concentration forming a self-assembled micelle configuration under selected conditions and having an aggregation number providing an equivalent weight capable of effecting the size separation of the sample solution so as to resolve a target analyte(s) in a solution containing the same, the size separation taking place in a chromatography or electrophoresis separation system.

  11. Larger sized wire arrays on 1.5 MA Z-pinch generator

    SciTech Connect (OSTI)

    Safronova, A. S. Kantsyrev, V. L. Weller, M. E. Shlyaptseva, V. V. Shrestha, I. K. Esaulov, A. A. Stafford, A.; Chuvatin, A. S.; Coverdale, C. A.; Jones, B.

    2014-12-15

    Experiments on the UNR Zebra generator with Load Current Multiplier (LCM) allow for implosions of larger sized wire array loads than at standard current of 1 MA. Advantages of larger sized planar wire array implosions include enhanced energy coupling to plasmas, better diagnostic access to observable plasma regions, and more complex geometries of the wire loads. The experiments with larger sized wire arrays were performed on 1.5 MA Zebra with LCM (the anode-cathode gap was 1 cm, which is half the gap used in the standard mode). In particular, larger sized multi-planar wire arrays had two outer wire planes from mid-atomic-number wires to create a global magnetic field (gmf) and plasma flow between them. A modified central plane with a few Al wires at the edges was put in the middle between outer planes to influence gmf and to create Al plasma flow in the perpendicular direction (to the outer arrays plasma flow). Such modified plane has different number of empty slots: it was increased from 6 up to 10, hence increasing the gap inside the middle plane from 4.9 to 7.7 mm, respectively. Such load configuration allows for more independent study of the flows of L-shell mid-atomic-number plasma (between the outer planes) and K-shell Al plasma (which first fills the gap between the edge wires along the middle plane) and their radiation in space and time. We demonstrate that such configuration produces higher linear radiation yield and electron temperatures as well as advantages of better diagnostics access to observable plasma regions and how the load geometry (size of the gap in the middle plane) influences K-shell Al radiation. In particular, K-shell Al radiation was delayed compared to L-shell mid-atomic-number radiation when the gap in the middle plane was large enough (when the number of empty slots was increased up to ten)

  12. Strategic Petroleum Reserve: Analysis of size options

    SciTech Connect (OSTI)

    Not Available

    1990-02-01

    This report presents the results of the deliberations of the interagency group formed to study the costs and benefits of expanding the size of the SPR. The study concentrated on severe oil supply disruptions involving sharp reductions in world oil production that were 2 to 4 times larger than the largest 1970s interruption. The disruption sizes and estimated probability of occurrence of these scenarios were supplied by the CIA. The most critical part of the CIA's analysis was the assessment of likelihood of these cases occurring. The CIA approached the likelihood problem by combining an examination of past oil supply disruptions with qualitative analysis of important oil market and regional trends. The study group then used statistical techniques and probability distributions to synthesize the historical data with CIA evaluations of as yet unobserved events. The SPR size study assumed direct purchases of SPR oil and did not assume the use of alternative financing mechanisms. Members of the working group with foreign policy and national security responsibilities provided an in-depth review of strategic considerations affecting SPR size. A number of prior studies, some classified, have addressed the strategic importance and insurance value of the SPR to the US and its allies. The results of these studies have also been incorporated in the current effort. 10 refs., 5 figs.

  13. " Row: Employment Sizes within NAICS Codes...

    U.S. Energy Information Administration (EIA) Indexed Site

    " 311 - 339","ALL MANUFACTURING INDUSTRIES" ,"Employment Size" ," Under 50",395.7,4.3,2.3,3.6 ," 50-99",663.4,6.8,3.3,5 ," 100-249",905.8,7.9,3.8,3.6 ," 250-499",1407.1,11.1,5....

  14. " Row: Employment Sizes within NAICS Codes...

    U.S. Energy Information Administration (EIA) Indexed Site

    " 311 - 339","ALL MANUFACTURING INDUSTRIES" ,"Employment Size" ," Under 50",625.5,3.3,1.7 ," 50-99",882.3,5.8,2.5 ," 100-249",1114.9,5.8,2.5 ," 250-499",2250.4,8,3.7 ," ...

  15. Perihelion precession for modified Newtonian gravity

    SciTech Connect (OSTI)

    Schmidt, Hans-Juergen

    2008-07-15

    We calculate the perihelion precession {delta} for nearly circular orbits in a central potential V(r). Differently from other approaches to this problem, we do not assume that the potential is close to the Newtonian one. The main idea in the deduction is to apply the underlying symmetries of the system to show that {delta} must be a function of r{center_dot}V{sup ''}(r)/V{sup '}(r) and to use the transformation behavior of {delta} in a rotating system of reference. This is equivalent to say that the effective potential can be written in a one-parameter set of possibilities as the sum of centrifugal potential and potential of the central force. We get the following universal formula valid for V{sup '}(r)>0 reading {delta}(r)=2{pi}{center_dot}[(1/{radical}(3+r{center_dot}V{sup ''}(r)/V{sup '}(r)))-1]. It has to be read as follows: a circular orbit at this value r exists and is stable if and only if this {delta} is well-defined as real; and if this is the case, then the angular difference from one perihelion to the next one for nearly circular orbits at this r is exactly 2{pi}+{delta}(r). Then we apply this result to examples of recent interest like modified Newtonian gravity and linearized fourth-order gravity. In the second part of the paper, we generalize this universal formula to static spherically symmetric space-times ds{sup 2}=-e{sup 2{lambda}}{sup (r)}dt{sup 2}+e{sup 2{mu}}{sup (r)}dr{sup 2}+r{sup 2}d{omega}{sup 2}; for orbits near r it reads {delta}=2{pi}{center_dot}[(e{sup {mu}}{sup (r)}/{radical}(3-2r{center_dot}{lambda}{sup '}(r)+r{center_dot}{lambda}{sup ''}(r)/{lambda}{sup '}(r)))-1] and can be applied to a large class of theories. For the Schwarzschild black hole with mass parameter m>0 it leads to {delta}=2{pi}{center_dot}[(1/{radical}(1-(6m/r)))-1], a surprisingly unknown formula. It represents a strict result and is applicable for all values r>6m and is in good agreement with the fact that stable circular orbits exist for r>6m only. For r>>m, one can develop in powers of m and get the well-known approximation {delta}{approx_equal}(6{pi}m/r)

  16. Small- and Medium-Size Building Automation and Control System...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Small- and Medium-Size Building Automation and Control System Needs: Scoping Study Small- and Medium-Size Building Automation and Control System Needs: Scoping Study Michael ...

  17. Real-Time Simultaneous Measurements of Size, Density, and Composition...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Simultaneous Measurements of Size, Density, and Composition of Single Ultrafine Diesel Tailpipe Particles Real-Time Simultaneous Measurements of Size, Density, and Composition of ...

  18. Reduce Pumping Costs Through Optimum Pipe Sizing | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reduce Pumping Costs Through Optimum Pipe Sizing This tip sheet discusses how to reduce pumping system costs through optimum pipe sizing. PUMPING SYSTEMS TIP SHEET 9 PDF icon ...

  19. Scalable Heuristics for Planning, Placement and Sizing of Flexible...

    Office of Scientific and Technical Information (OSTI)

    Sizing of Flexible AC Transmission System Devices Citation Details In-Document Search Title: Scalable Heuristics for Planning, Placement and Sizing of Flexible AC Transmission ...

  20. CBEI: Coordinating RTUs in Small and Medium Sized Commercial...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Coordinating RTUs in Small and Medium Sized Commercial Buildings - 2015 Peer Review CBEI: Coordinating RTUs in Small and Medium Sized Commercial Buildings - 2015 Peer Review ...

  1. Sandia Energy - Self-Regulated Fabrication of Size-Controlled...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Self-Regulated Fabrication of Size-Controlled Quantum Nanostructures Home Highlights - Energy Research Self-Regulated Fabrication of Size-Controlled Quantum Nanostructures Previous...

  2. Versatile Diesel Particulate Filter Cartridge Any Size, Any Shape...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Versatile Diesel Particulate Filter Cartridge Any Size, Any Shape Versatile Diesel Particulate Filter Cartridge Any Size, Any Shape Presentation given at DEER 2006, August 20-24, ...

  3. Small- and Medium-Size Building Automation and Control System...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Small- and Medium-Size Building Automation and Control System Needs: Scoping Study Small- and Medium-Size Building Automation and Control System Needs: Scoping Study Emerging ...

  4. Magnetic agglomeration method for size control in the synthesis...

    Office of Scientific and Technical Information (OSTI)

    Magnetic agglomeration method for size control in the synthesis of magnetic nanoparticles Title: Magnetic agglomeration method for size control in the synthesis of magnetic ...

  5. Idaho Application for Permit to Construct Modify or Maintain...

    Open Energy Info (EERE)

    Construct Modify or Maintain an Injection Well - Form 42-39-1 Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- RegulationRegulation: Idaho...

  6. Wide size range fast integrated mobility spectrometer

    DOE Patents [OSTI]

    Wang, Jian

    2013-10-29

    A mobility spectrometer to measure a nanometer particle size distribution is disclosed. The mobility spectrometer includes a conduit and a detector. The conduit is configured to receive and provide fluid communication of a fluid stream having a charged nanometer particle mixture. The conduit includes a separator section configured to generate an electrical field of two dimensions transverse to a dimension associated with the flow of the charged nanometer particle mixture through the separator section to spatially separate charged nanometer particles of the charged nanometer particle mixture in said two dimensions. The detector is disposed downstream of the conduit to detect concentration and position of the spatially-separated nanometer particles.

  7. First-principles studies on vacancy-modified interstitial diffusion

    Office of Scientific and Technical Information (OSTI)

    mechanism of oxygen in nickel, associated with large-scale atomic simulation techniques (Journal Article) | SciTech Connect First-principles studies on vacancy-modified interstitial diffusion mechanism of oxygen in nickel, associated with large-scale atomic simulation techniques Citation Details In-Document Search Title: First-principles studies on vacancy-modified interstitial diffusion mechanism of oxygen in nickel, associated with large-scale atomic simulation techniques Authors: Fang, H

  8. Method for modifying trigger level for adsorber regeneration

    DOE Patents [OSTI]

    Ruth, Michael J.; Cunningham, Michael J.

    2010-05-25

    A method for modifying a NO.sub.x adsorber regeneration triggering variable. Engine operating conditions are monitored until the regeneration triggering variable is met. The adsorber is regenerated and the adsorbtion efficiency of the adsorber is subsequently determined. The regeneration triggering variable is modified to correspond with the decline in adsorber efficiency. The adsorber efficiency may be determined using an empirically predetermined set of values or by using a pair of oxygen sensors to determine the oxygen response delay across the sensors.

  9. Is the proton electromagnetic form factor modified in nuclei? (Conference)

    Office of Scientific and Technical Information (OSTI)

    | SciTech Connect SciTech Connect Search Results Conference: Is the proton electromagnetic form factor modified in nuclei? Citation Details In-Document Search Title: Is the proton electromagnetic form factor modified in nuclei? Guided by the recent experimental confirmation of the validity of the Effective Momentum Approximation (EMA) in quasi-elastic scattering off nuclei, we have re-examined the extraction of the Longitudinal and Transverse Response Functions in medium-weight and heavy

  10. Is the proton electromagnetic form factor modified in nuclei? (Conference)

    Office of Scientific and Technical Information (OSTI)

    | SciTech Connect Conference: Is the proton electromagnetic form factor modified in nuclei? Citation Details In-Document Search Title: Is the proton electromagnetic form factor modified in nuclei? × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and is provided as a public service. Visit OSTI to utilize additional information resources in energy science and technology.

  11. Degradative and Morphological Characterization of POSS Modified Nanohybrid

    Office of Scientific and Technical Information (OSTI)

    Polyurethane Elastomers (Journal Article) | SciTech Connect Degradative and Morphological Characterization of POSS Modified Nanohybrid Polyurethane Elastomers Citation Details In-Document Search Title: Degradative and Morphological Characterization of POSS Modified Nanohybrid Polyurethane Elastomers Authors: Lewicki, J P ; Pielichowski, K ; Jancia, M ; Hebda, E ; Albo, R F ; Maxwell, R S Publication Date: 2014-02-06 OSTI Identifier: 1144750 Report Number(s): LLNL-JRNL-649713 DOE Contract

  12. Guidance Regarding Refinancing, Restructuring, or Modifying Loan Agreements

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Entered into by an Energy Services Company Under a Federal Energy Savings Performance Contract | Department of Energy Regarding Refinancing, Restructuring, or Modifying Loan Agreements Entered into by an Energy Services Company Under a Federal Energy Savings Performance Contract Guidance Regarding Refinancing, Restructuring, or Modifying Loan Agreements Entered into by an Energy Services Company Under a Federal Energy Savings Performance Contract Document addresses potential refinancing,

  13. Hanford Waste Treatment Plant Support Task Order Modified | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Hanford Waste Treatment Plant Support Task Order Modified Hanford Waste Treatment Plant Support Task Order Modified March 11, 2013 - 12:00pm Addthis Media Contact Lynette Chafin, 513-246-0461 Lynette.Chafin@emcbc.doe.gov Cincinnati - The Department of Energy (DOE) today awarded a modification to a task order to Aspen Resources Limited, Inc. of Boulder, Colorado for support of the Waste Treatment and Immobilization Plant (WTP) at the Hanford Site. The modification increased the value

  14. Fluorine-Modified Polyaromatic Hydrocarbons for Organic Electronics -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Innovation Portal Advanced Materials Advanced Materials Find More Like This Return to Search Fluorine-Modified Polyaromatic Hydrocarbons for Organic Electronics Colorado State University Contact CSU About This Technology Technology Marketing Summary A chemical synthesis that modifies PAHs via addition of perfluoroalkyl groups. The resulting compounds are novel organic semiconductors with potential application to flexible OLED displays and organic photovoltaics (OPVs). Description The

  15. LNG fleet increases in size and capabilities

    SciTech Connect (OSTI)

    Linser, H.J. Jr.; Drudy, M.J.; Endrizzi, F.; Urbanelli, A.A.

    1997-06-02

    The LNG fleet as of early 1997 consisted of 99 vessels with total cargo capacity of 10.7 million cu m, equivalent to approximately 4.5 million tons. One of the newest additions to the fleet, the 137,000-cu m tanker Al Zubarah, is five times the size of the original commercial vessel Methane Princess. Al Zubarah`s first loading of more than 60,000 tons occurred in December 1996 for deliver to Japanese buyers from the newly commissioned Qatargas LNG plant at Ras Laffan. That size cargo contains enough clean-burning energy to heat 60,000 homes in Japan for 1 month. Measuring nearly 1,000 ft long, the tanker is among the largest in the industry fleet and joined 70 other vessels of more than 100,000 cu m. Most LNG tankers built since 1975 have been larger-capacity vessels. The paper discusses LNG shipping requirements, containment systems, vessel design, propulsion, construction, operations and maintenance, and the future for larger vessels.

  16. Parameterizing Size Distribution in Ice Clouds

    SciTech Connect (OSTI)

    DeSlover, Daniel; Mitchell, David L.

    2009-09-25

    PARAMETERIZING SIZE DISTRIBUTIONS IN ICE CLOUDS David L. Mitchell and Daniel H. DeSlover ABSTRACT An outstanding problem that contributes considerable uncertainty to Global Climate Model (GCM) predictions of future climate is the characterization of ice particle sizes in cirrus clouds. Recent parameterizations of ice cloud effective diameter differ by a factor of three, which, for overcast conditions, often translate to changes in outgoing longwave radiation (OLR) of 55 W m-2 or more. Much of this uncertainty in cirrus particle sizes is related to the problem of ice particle shattering during in situ sampling of the ice particle size distribution (PSD). Ice particles often shatter into many smaller ice fragments upon collision with the rim of the probe inlet tube. These small ice artifacts are counted as real ice crystals, resulting in anomalously high concentrations of small ice crystals (D < 100 m) and underestimates of the mean and effective size of the PSD. Half of the cirrus cloud optical depth calculated from these in situ measurements can be due to this shattering phenomenon. Another challenge is the determination of ice and liquid water amounts in mixed phase clouds. Mixed phase clouds in the Arctic contain mostly liquid water, and the presence of ice is important for determining their lifecycle. Colder high clouds between -20 and -36 oC may also be mixed phase but in this case their condensate is mostly ice with low levels of liquid water. Rather than affecting their lifecycle, the presence of liquid dramatically affects the cloud optical properties, which affects cloud-climate feedback processes in GCMs. This project has made advancements in solving both of these problems. Regarding the first problem, PSD in ice clouds are uncertain due to the inability to reliably measure the concentrations of the smallest crystals (D < 100 m), known as the small mode. Rather than using in situ probe measurements aboard aircraft, we employed a treatment of ice cloud optical properties formulated in terms of PSD parameters in combination with remote measurements of thermal radiances to characterize the small mode. This is possible since the absorption efficiency (Qabs) of small mode crystals is larger at 12 m wavelength relative to 11 m wavelength due to the process of wave resonance or photon tunneling more active at 12 m. This makes the 12/11 m absorption optical depth ratio (or equivalently the 12/11 m Qabs ratio) a means for detecting the relative concentration of small ice particles in cirrus. Using this principle, this project tested and developed PSD schemes that can help characterize cirrus clouds at each of the three ARM sites: SGP, NSA and TWP. This was the main effort of this project. These PSD schemes and ice sedimentation velocities predicted from them have been used to test the new cirrus microphysics parameterization in the GCM known as the Community Climate Systems Model (CCSM) as part of an ongoing collaboration with NCAR. Regarding the second problem, we developed and did preliminary testing on a passive thermal method for retrieving the total water path (TWP) of Arctic mixed phase clouds where TWPs are often in the range of 20 to 130 g m-2 (difficult for microwave radiometers to accurately measure). We also developed a new radar method for retrieving the cloud ice water content (IWC), which can be vertically integrated to yield the ice water path (IWP). These techniques were combined to determine the IWP and liquid water path (LWP) in Arctic clouds, and hence the fraction of ice and liquid water. We have tested this approach using a case study from the ARM field campaign called M-PACE (Mixed-Phase Arctic Cloud Experiment). This research led to a new satellite remote sensing method that appears promising for detecting low levels of liquid water in high clouds typically between -20 and -36 oC. We hope to develop this method in future research.

  17. Offshore Lubricants Market Size | OpenEI Community

    Open Energy Info (EERE)

    Offshore Lubricants Market Size Home There are currently no posts in this category. Syndicate content...

  18. Coal Fired Power Generation Market Size | OpenEI Community

    Open Energy Info (EERE)

    Coal Fired Power Generation Market Size Home There are currently no posts in this category. Syndicate...

  19. Sizing a New Water Heater | Department of Energy

    Energy Savers [EERE]

    Heat & Cool » Water Heating » Sizing a New Water Heater Sizing a New Water Heater Is your water heater the right size for you house? | Photo credit ENERGY STAR® Is your water heater the right size for you house? | Photo credit ENERGY STAR® A properly sized water heater will meet your household's hot water needs while operating more efficiently. Therefore, before purchasing a water heater, make sure it's the correct size. Here you'll find information about how to size these systems:

  20. New program sizes pressure-relief drums

    SciTech Connect (OSTI)

    Durand, A.A.; Osorio, R.A.; Suarez, R.H.

    1996-05-06

    In accordance with API Recommended Practice 521, a new procedure has been developed for the design of relief drums. The calculation method determines by convergence the most economical length-to-diameter ratio for gas-liquid separation vessels. Drum sizing is based on the separation of a two-phase stream, taking into account the special condition of intermittent flow. Design parameters such as settling velocity and residence time also must be calculated to determine an optimum design. A new program based on a programmable algorithm can be converted from basic language to any other computer language to facilitate vessel-design computations. The program quickly and efficiently computes design values for relief systems used in refineries and petrochemical plants.

  1. Impact of aerosol size representation on modeling aerosol-cloud interactions: AEROSOL SIZE REPRESENTATION

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Y.; Easter, R. C.; Ghan, S. J.; Abdul-Razzak, H.

    2002-11-07

    We use a 1-D version of a climate-aerosol-chemistry model with both modal and sectional aerosol size representations to evaluate the impact of aerosol size representation on modeling aerosol-cloud interactions in shallow stratiform clouds observed during the 2nd Aerosol Characterization Experiment. Both the modal (with prognostic aerosol number and mass or prognostic aerosol number, surface area and mass, referred to as the Modal-NM and Modal-NSM) and the sectional approaches (with 12 and 36 sections) predict total number and mass for interstitial and activated particles that are generally within several percent of references from a high resolution 108-section approach. The modal approachmore » with prognostic aerosol mass but diagnostic number (referred to as the Modal-M) cannot accurately predict the total particle number and surface areas, with deviations from the references ranging from 7-161%. The particle size distributions are sensitive to size representations, with normalized absolute differences of up to 12% and 37% for the 36- and 12-section approaches, and 30%, 39%, and 179% for the Modal-NSM, Modal-NM, and Modal-M, respectively. For the Modal-NSM and Modal-NM, differences from the references are primarily due to the inherent assumptions and limitations of the modal approach. In particular, they cannot resolve the abrupt size transition between the interstitial and activated aerosol fractions. For the 12- and 36-section approaches, differences are largely due to limitations of the parameterized activation for non-log-normal size distributions, plus the coarse resolution for the 12-section case. Differences are larger both with higher aerosol (i.e., less complete activation) and higher SO2 concentrations (i.e., greater modification of the initial aerosol distribution).« less

  2. Graphene Modified LiFePO4 Cathode Materials for High Power Lithium ion Batteries

    SciTech Connect (OSTI)

    Zhou, X.; Wang, F.; Zhu, Y.; Liu, Z.

    2011-01-24

    Graphene-modified LiFePO{sub 4} composite has been developed as a Li-ion battery cathode material with excellent high-rate capability and cycling stability. The composite was prepared with LiFePO{sub 4} nanoparticles and graphene oxide nanosheets by spray-drying and annealing processes. The LiFePO{sub 4} primary nanoparticles embedded in micro-sized spherical secondary particles were wrapped homogeneously and loosely with a graphene 3D network. Such a special nanostructure facilitated electron migration throughout the secondary particles, while the presence of abundant voids between the LiFePO{sub 4} nanoparticles and graphene sheets was beneficial for Li{sup +} diffusion. The composite cathode material could deliver a capacity of 70 mAh g{sup -1} at 60C discharge rate and showed a capacity decay rate of <15% when cycled under 10C charging and 20C discharging for 1000 times.

  3. Photoresponsive Release from Azobenzene-Modified Single Cubic Crystal NaCl/Silica Particles

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jiang, Xingmao; Liu, Nanguo; Assink, Roger A.; Jiang, Yingbing; Brinker, C. Jeffrey

    2011-01-01

    Azobenzene ligands were uniformly anchored to the pore surfaces of nanoporous silica particles with single crystal NaCl using 4-(3-triethoxysilylpropylureido)azobenzene (TSUA). The functionalization delayed the release of NaCl significantly. The modified particles demonstrated a photocontrolled release by trans/cis isomerization of azobenzene moieties. The addition of amphiphilic solvents, propylene glycol (PG), propylene glycol propyl ether (PGPE), and dipropylene glycol propyl ether (DPGPE) delayed the release in water, although the wetting behavior was improved and the delay is the most for the block molecules with the longest carbon chain. The speedup by UV irradiation suggests a strong dependence of diffusion on the switchablemore » pore size. TGA, XRD, FTIR, and NMR techniques were used to characterize the structures.« less

  4. Systems and methods of varying charged particle beam spot size

    DOE Patents [OSTI]

    Chen, Yu-Jiuan

    2014-09-02

    Methods and devices enable shaping of a charged particle beam. A modified dielectric wall accelerator includes a high gradient lens section and a main section. The high gradient lens section can be dynamically adjusted to establish the desired electric fields to minimize undesirable transverse defocusing fields at the entrance to the dielectric wall accelerator. Once a baseline setting with desirable output beam characteristic is established, the output beam can be dynamically modified to vary the output beam characteristics. The output beam can be modified by slightly adjusting the electric fields established across different sections of the modified dielectric wall accelerator. Additional control over the shape of the output beam can be excreted by introducing intentional timing de-synchronization offsets and producing an injected beam that is not fully matched to the entrance of the modified dielectric accelerator.

  5. Development of effective modified cellulase for cellulose hydrolysis process

    SciTech Connect (OSTI)

    Park, J.W.; Kajiuchi, Toshio . Dept. of Chemical Engineering)

    1995-02-20

    Cellulase was modified with amphilic copolymers made of [alpha]-allyl-[omega]-methoxy polyoxyalkylene (POA) and maleic acid anhydride (MAA) to improve the cellulose hydrolytic reactivity and cellulase separation. Amino groups of the cellulase molecule are covalently coupled with the MAA functional groups of the copolymer. At the maximum degree of modification (DM) of 55%, the modified cellulase activity retained more than 80% of the unmodified native cellulase activity. The modified cellulase shows greater stability against temperature, pH, and organic solvents, and demonstrated greater conversion of substrate than native cellulase does. Cellulase modification is also useful for controlling strong adsorption of cellulase onto substrate. Moreover, cellulase modified with the amphiphilic copolymer displays different separation characteristics which are new. One is a reactive two-phase partition and another is solubility in organic solvents. It appears that these characteristics of modified cellulase work very effectively in the hydrolysis of cellulose as a total system, which constitutes the purification of cellulase from culture broth, hydrolysis of cellulose, and recovery of cellulase from the reaction mixture.

  6. The modified equation for spinless particles and superalgebra

    SciTech Connect (OSTI)

    Sadeghi, J.; Rostami, M.; Sadeghi, Z.

    2013-09-15

    In this paper we consider modified wave equations for spinless particles in an external magnetic field. We consider 4-potentials which guarantee Lorentz' and Coulomb's conditions. The new variable for modified wave equation leads us to consider the associated Laguerre differential equation. We take advantage of the factorization method in Laguerre differential equation and solve the modified equation. In order to obtain the wave function, energy spectrum and its quantization, we will establish conditions for the orbital quantum number. We account such orbital quantum number and obtain the raising and lowering operators. If we want to have supersymmetry partners, we need to apply the shape invariance condition. This condition for the partner potential will help us find the limit of ? as ?=?(l)

  7. Acidity characterization of a titanium and sulfate modified vermiculite

    SciTech Connect (OSTI)

    Hernandez, W.Y.; Centeno, M.A.; Odriozola, J.A.; Moreno, S.; Molina, R.

    2008-07-01

    A natural vermiculite has been modified with titanium and sulfated by the intercalation and impregnation method in order to optimize the acidity of the clay mineral, and characterization of samples were analyzed by X-ray fluorescence (XRF), X-ray diffraction (XRD), nitrogen adsorption isotherms, diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) and temperature programmed desorption with ammonia (TPD-NH{sub 3}). All the modified solids have a significantly higher number of acidic sites with respect to the parent material and in all of these, Broensted as well as Lewis acidity are identified. The presence of sulfate appears not to increase the number of acidic centers in the modified clay. For the materials sulfated with the intercalation method, it is observed that the strength of the acidic sites found in the material increases with the nominal sulfate/metal ratio. Nevertheless, when elevated quantities of sulfur are deposited, diffusion problems in the heptane reaction appear.

  8. Method of detecting luminescent target ions with modified magnetic microspheres

    DOE Patents [OSTI]

    Shkrob, Ilya A; Kaminski, Michael D

    2014-05-13

    This invention provides methods of using modified magnetic microspheres to extract target ions from a sample in order to detect their presence in a microfluidic environment. In one or more embodiments, the microspheres are modified with molecules on the surface that allow the target ions in the sample to form complexes with specific ligand molecules on the microsphere surface. In one or more embodiments, the microspheres are modified with molecules that sequester the target ions from the sample, but specific ligand molecules in solution subsequently re-extract the target ions from the microspheres into the solution, where the complexes form independent of the microsphere surface. Once the complexes form, they are exposed to an excitation wavelength light source suitable for exciting the target ion to emit a luminescent signal pattern. Detection of the luminescent signal pattern allows for determination of the presence of the target ions in the sample.

  9. Impedimetric investigation of gold nanoparticles - guanine modified electrode

    SciTech Connect (OSTI)

    Vulcu, A.; Pruneanu, S.; Berghian-Grosan, C.; Olenic, L.; Muresan, L. M.; Barbu-Tudoran, L.

    2013-11-13

    In this paper we report the preparation of a modified electrode with gold nanoparticles and guanine. The colloidal suspension of gold nanoparticles was obtained by Turkevich method and was next analyzed by UV-Vis spectroscopy and Transmission Electron Microscopy (TEM). The gold electrode was modified by self-assembling the gold nanoparticles with guanine, the organic molecule playing also the role of linker. The electrochemical characteristics of the bare and modified electrode were investigated by Electrochemical Impedance Spectroscopy (EIS). A theoretical model was developed based on an electrical equivalent circuit which contain solution resistance (R{sub s}), charge transfer resistance (R{sub ct}), Warburg impedance (Z{sub W}) and double layer capacitance (C{sub dl})

  10. ANALYSIS OF OUT OF DATE MCU MODIFIER LOCATED IN SRNL

    SciTech Connect (OSTI)

    Crawford, C.

    2014-10-22

    SRNL recently completed density measurements and chemical analyses on modifier samples stored in drums within SRNL. The modifier samples date back to 2008 and are in various quantities up to 40 gallons. Vendor information on the original samples indicates a shelf life of 5 years. There is interest in determining if samples that have been stored for more than the 5 year shelf life are still acceptable for use. The Modular Caustic Side Solvent Extraction Unit (MCU) Solvent component Cs-7SB [(2,2,3,3- tetraflouropropoxy)-3-(4-sec-butylphenoxy)-2-propanol, CAS #308362-88-1] is used as a diluent modifier to increase extractant solubility and provide physical characteristics necessary for diluent trimming.

  11. Massive gravitational waves in Chern-Simons modified gravity

    SciTech Connect (OSTI)

    Myung, Yun Soo; Moon, Taeyoon E-mail: tymoon@inje.ac.kr

    2014-10-01

    We consider the nondynamical Chern-Simons (nCS) modified gravity, which is regarded as a parity-odd theory of massive gravity in four dimensions. We first find polarization modes of gravitational waves for θ=x/μ in nCS modified gravity by using the Newman-Penrose formalism where the null complex tetrad is necessary to specify gravitational waves. We show that in the Newman–Penrose formalism, the number of polarization modes is one in addition to an unspecified Ψ{sub 4}, implying three degrees of freedom for θ=x/μ. This compares with two for a canonical embedding of θ=t/μ. Also, if one introduces the Ricci tensor formalism to describe a massive graviton arising from the nCS modified gravity, one finds one massive mode after making second-order wave equations, which is compared to five found from the parity-even Einstein–Weyl gravity.

  12. Improving Geologic and Engineering Models of Midcontinent Fracture and Karst-Modified Reservoirs Using New 3-D Seismic Attributes

    SciTech Connect (OSTI)

    Susan Nissen; Saibal Bhattacharya; W. Lynn Watney; John Doveton

    2009-03-31

    Our project goal was to develop innovative seismic-based workflows for the incremental recovery of oil from karst-modified reservoirs within the onshore continental United States. Specific project objectives were: (1) to calibrate new multi-trace seismic attributes (volumetric curvature, in particular) for improved imaging of karst-modified reservoirs, (2) to develop attribute-based, cost-effective workflows to better characterize karst-modified carbonate reservoirs and fracture systems, and (3) to improve accuracy and predictiveness of resulting geomodels and reservoir simulations. In order to develop our workflows and validate our techniques, we conducted integrated studies of five karst-modified reservoirs in west Texas, Colorado, and Kansas. Our studies show that 3-D seismic volumetric curvature attributes have the ability to re-veal previously unknown features or provide enhanced visibility of karst and fracture features compared with other seismic analysis methods. Using these attributes, we recognize collapse features, solution-enlarged fractures, and geomorphologies that appear to be related to mature, cockpit landscapes. In four of our reservoir studies, volumetric curvature attributes appear to delineate reservoir compartment boundaries that impact production. The presence of these compartment boundaries was corroborated by reservoir simulations in two of the study areas. Based on our study results, we conclude that volumetric curvature attributes are valuable tools for mapping compartment boundaries in fracture- and karst-modified reservoirs, and we propose a best practices workflow for incorporating these attributes into reservoir characterization. When properly calibrated with geological and production data, these attributes can be used to predict the locations and sizes of undrained reservoir compartments. Technology transfer of our project work has been accomplished through presentations at professional society meetings, peer-reviewed publications, Kansas Geological Survey Open-file reports, Master's theses, and postings on the project website: http://www.kgs.ku.edu/SEISKARST.

  13. Minimum length, extra dimensions, modified gravity and black hole remnants

    SciTech Connect (OSTI)

    Maziashvili, Michael

    2013-03-01

    We construct a Hilbert space representation of minimum-length deformed uncertainty relation in presence of extra dimensions. Following this construction, we study corrections to the gravitational potential (back reaction on gravity) with the use of correspondingly modified propagator in presence of two (spatial) extra dimensions. Interestingly enough, for r?0 the gravitational force approaches zero and the horizon for modified Schwarzschild-Tangherlini space-time disappears when the mass approaches quantum-gravity energy scale. This result points out to the existence of zero-temperature black hole remnants in ADD brane-world model.

  14. Ductile fracture toughness of modified A 302 Grade B Plate materials, data analysis. Volume 1

    SciTech Connect (OSTI)

    McCabe, D.E.; Manneschmidt, E.T.; Swain, R.L.

    1997-01-01

    The goal of this work was to develop ductile fracture toughness data in the form of J-R curves for modified A302 grade B plate materials typical of those used in reactor pressure vessels. A previous experimental study on one heat of A302 grade B plate showed decreasing J-R curves with increased specimen thickness. This characteristic has not been observed in tests made on recent production materials of A533 grade B and A508 class 2 pressure vessel steels. It was unknown if the departure from norm for the material was a generic characteristic for all heats of A302 grade B steels or unique to that particular plate. Seven heats of modified A302 grade B steel and one heat of vintage A533 grade B steel were tested for chemical content, tensile properties, Charpy transition temperature curves, drop-weight nil-ductility transition (NDT) temperature, and J-R curves. Tensile tests were made in the three principal orientations and at four temperatures, ranging from room temperature to 550F. Charpy V-notch transition temperature curves were obtained in longitudinal, transverse, and short transverse orientations. J-R curves were made using four specimen sizes (1/2T, 1T, 2T, and 4T). The fracture mechanics-based evaluation method covered three test orientations and three test temperatures (80, 400, and 550F). However, the coverage of these variables was contingent upon the amount of material provided. Drop-weight NDT temperature was determined for the T-L orientation only. None of the heats of modified A302 grade B showed size effects of any consequence on the J-R curve behavior. Crack orientation effects were present, but none were severe enough to be reported as atypical. A test temperature increase from 180 to 550F produced the usual loss in J-R curve fracture toughness. Generic J-R curves and curve fits were generated to represent each heat of material. This volume deals with the evaluation of data and the discussion of technical findings. 8 refs., 18 figs., 8 tabs.

  15. The influence of size, shape, and surface coating on the stability of aqueous nanoparticle suspensions

    SciTech Connect (OSTI)

    Mulvihill, M.J.; Habas, S.E.; La Plante, I.J.; Wan, J.; Mokari, T.

    2010-09-03

    In response to the rapid development and emerging commercialization of nanoparticles, fundamental studies concerning the fate of nanoparticles in the environment are needed. Precise control over the nanoparticle size, shape, and surface coating of cadmium selenide particles modified with thiolate ligands has been used to analyze the effects of nanoparticle design on their stability in aqueous environments. Nanoparticle stability was quantified using the concept of critical coagulation concentration (CCC) in solutions of sodium chloride. These investigations characterized the instability of the ligand coatings, which varied directly with chain length of the capping ligands. The stability of the ligand coatings were characterized as a function of time, pH, and ionic strength. Ligand dissociation has been shown to be a primary mechanism for nanoparticle aggregation when short-chain (C2-C6) ligands are used in the ligand shell. Stable nanoparticle suspensions prepared with long chain ligands (C11) were used to characterize nanoparticle stability as a function of size and shape. A linear relationship between particle surface area and the CCC was discovered and was found to be independent of nanoparticle shape. Quantitative analysis of nanoparticle size, shape, and surface coating demonstrated the importance of ligand stability and particle surface area for the prediction of nanoparticle stability.

  16. Solar Trackers Market Size | OpenEI Community

    Open Energy Info (EERE)

    Solar Trackers Market Size Home John55364's picture Submitted by John55364(100) Contributor 12 May, 2015 - 03:54 Solar Trackers Market - Global Industry Analysis, Size, Share,...

  17. CBEI: AHU FDD in Small and Medium Sized Commercial Buildings...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AHU FDD in Small and Medium Sized Commercial Buildings - 2015 Peer Review CBEI: AHU FDD in Small and Medium Sized Commercial Buildings - 2015 Peer Review Presenter: Jin Wen, Drexel ...

  18. Global Nuclear Energy Partnership Triples in Size to 16 Members...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Global Nuclear Energy Partnership Triples in Size to 16 Members Global Nuclear Energy Partnership Triples in Size to 16 Members September 16, 2007 - 2:33pm Addthis Nations Sign On...

  19. Method of storing radioactive wastes using modified tobermorite

    DOE Patents [OSTI]

    Komarneni, Sridhar; Roy, Della M.

    1985-01-01

    A new cation exchanger is a modified tobermorite containing aluminum isomorphously substituted for silicon and containing sodium or potassium. The exchanger is selective for lead, rubidium, cobalt and cadmium and is selective for cesium over calcium or sodium. The tobermorites are compatable with cement and are useful for the long-term fixation and storage of radioactive nuclear wastes.

  20. Method for determining aerosol particle size device for determining aerosol particle size

    DOE Patents [OSTI]

    Novick, Vincent J.

    1998-01-01

    A method for determining the mass median diameter D of particles contained in a fluid is provided wherein the data of the mass of a pre-exposed and then a post-exposed filter is mathematically combined with data concerning the pressure differential across the same filter before and then after exposure to a particle-laden stream. A device for measuring particle size is also provided wherein the device utilizes the above-method for mathematically combining the easily quantifiable data.

  1. Quantum-size-controlled photoelectrochemical etching of semiconductor

    Office of Scientific and Technical Information (OSTI)

    nanostructures (Patent) | SciTech Connect Patent: Quantum-size-controlled photoelectrochemical etching of semiconductor nanostructures Citation Details In-Document Search Title: Quantum-size-controlled photoelectrochemical etching of semiconductor nanostructures Quantum-size-controlled photoelectrochemical (QSC-PEC) etching provides a new route to the precision fabrication of epitaxial semiconductor nanostructures in the sub-10-nm size regime. For example, quantum dots (QDs) can be

  2. Synthesis and Size-Dependent Crystallization of Colloidal Germanium

    Office of Scientific and Technical Information (OSTI)

    Telluride (Journal Article) | SciTech Connect Synthesis and Size-Dependent Crystallization of Colloidal Germanium Telluride Citation Details In-Document Search Title: Synthesis and Size-Dependent Crystallization of Colloidal Germanium Telluride Colloidal nanocrystals have long been used to study the dependence of phase stability and transitions on size. Both structural phase stability and phase transitions change dramatically in the nanometre size regime where the surface plays a significant

  3. Femtosecond laser-induced size reduction of carbon nanodots in solution: Effect of laser fluence, spot size, and irradiation time

    SciTech Connect (OSTI)

    Nguyen, Vanthan; Yan, Lihe Si, Jinhai; Hou, Xun

    2015-02-28

    Photoluminescent carbon nanodots (C-dots) with size tunability and uniformity were fabricated in polyethylene glycol (PEG{sub 200N}) solution using femtosecond laser ablation method. The size distributions and photoluminescence (PL) properties of C-dots are well controlled by adjusting the combined parameters of laser fluence, spot size, and irradiation time. The size reduction efficiency of the C-dots progressively increases with decreasing laser fluence and spot size. The optimal PL spectra are red-shifted and the quantum yields decrease with the increase in C-dots size, which could be attributed to the more complex surface functional groups attached on C-dots induced at higher laser fluence and larger spot size. Moreover, an increase in irradiation time leads to a decrease in size of C-dots, but long-time irradiation will result in the generation of complex functional groups on C-dots, subsequently the PL spectra are red-shifted.

  4. Resonant wave-particle interactions modified by intrinsic Alfvenic turbulence

    SciTech Connect (OSTI)

    Wu, C. S.; Lee, K. H.; Wang, C. B.; Wu, D. J.

    2012-08-15

    The concept of wave-particle interactions via resonance is well discussed in plasma physics. This paper shows that intrinsic Alfven waves can qualitatively modify the physics discussed in conventional linear plasma kinetic theories. It turns out that preexisting Alfven waves can affect particle motion along the ambient magnetic field and, moreover, the ensuing force field is periodic in time. As a result, the meaning of the usual Landau and cyclotron resonance conditions becomes questionable. It turns out that this effect leads us to find a new electromagnetic instability. In such a process intrinsic Alfven waves not only modify the unperturbed distribution function but also result in a different type of cyclotron resonance which is affected by the level of turbulence. This instability might enable us to better our understanding of the observed radio emission processes in the solar atmosphere.

  5. Modified Newmark model for seismic displacements of compliant slopes

    SciTech Connect (OSTI)

    Kramer, S.L.; Smith, M.W.

    1997-07-01

    Newmark sliding block analyses are widely used for estimation of permanent displacements of slopes in earthquakes. The conventional Newmark model, however, neglects the dynamic response of the material above a potential failure surface. Decoupled procedures have been developed to account for that response, but they neglect the effects of permanent displacements on the response. A modified Newmark analysis that considers the dynamic response, including the effects of permanent displacements, of the material above the failure surface is presented. The modified Newmark analysis shows that the decoupled approach produces somewhat conservative estimates of permanent displacements for stiff and/or shallow failure masses, but that it may produce unconservative estimates for failure masses that are soft and/or deep. Many slopes of large, lined landfills may fall into this latter category. The notion of a slope spectrum, which illustrates the effect of the natural period of a potential failure mass on permanent slope displacement, is also introduced.

  6. THE SIZE DISTRIBUTION OF THE NEPTUNE TROJANS AND THE MISSING INTERMEDIATE-SIZED PLANETESIMALS

    SciTech Connect (OSTI)

    Sheppard, Scott S.; Trujillo, Chadwick A.

    2010-11-10

    We present an ultra-deep survey for Neptune Trojans using the Subaru 8.2 m and Magellan 6.5 m telescopes. The survey reached a 50% detection efficiency in the R band at m{sub R} = 25.7 mag and covered 49 deg{sup 2} of sky. m{sub R} = 25.7 mag corresponds to Neptune Trojans that are about 16 km in radius (assuming an albedo of 0.05). A paucity of smaller Neptune Trojans (radii < 45 km) compared with larger ones was found. The brightest Neptune Trojans appear to follow a steep power-law slope (q = 5 {+-} 1) similar to the brightest objects in the other known stable reservoirs such as the Kuiper Belt, Jupiter Trojans, and main belt asteroids. We find a roll-over for the Neptune Trojans that occurs around a radius of r = 45 {+-} 10 km (m{sub R} = 23.5 {+-} 0.3), which is also very similar to the other stable reservoirs. All the observed stable regions in the solar system show evidence for Missing Intermediate-Sized Planetesimals (MISPs). This indicates a primordial and not collisional origin, which suggests that planetesimal formation proceeded directly from small to large objects. The scarcity of intermediate- and smaller-sized Neptune Trojans may limit them as being a strong source for the short period comets.

  7. A modified method for barium titanate nanoparticles synthesis

    SciTech Connect (OSTI)

    Ashiri, R.; Nemati, Ali; Sasani Ghamsari, M.; Sanjabi, S.; Aalipour, M.

    2011-12-15

    Graphical abstract: TEM micrograph of BaTiO{sub 3} powders synthesized at 800 Degree-Sign C for 1 h and SAED pattern (inset) of BaTiO{sub 3} powders. In this research, a modified, cost efficient and quick sol-gel procedure was used for preparation of BaTiO{sub 3} nanoparticles. Highlights: Black-Right-Pointing-Pointer A modified process was used for preparation. Black-Right-Pointing-Pointer The modified process led to preparation of finer BaTiO{sub 3} nanoparticles in shorter period of time and lower temperature contrary to previous researches. Black-Right-Pointing-Pointer The proposed procedure seems to be more preferable for mass production. -- Abstract: In this research, a modified, cost effective sol-gel procedure applied to synthesize BaTiO{sub 3} nanoparticles. XRD and electron microscopy (SEM and TEM) applied for microstructural characterization of powders. The obtained results showed that the type of precursors, their ratio and the hydrolysis conditions had a great effect on time, temperature and therefore the costs of the synthesis process. By selection, utilization of optimized precursor's type, hydrolysis conditions, fine cubic BaTiO{sub 3} nanoparticles were synthesized at low temperature and in short time span (1 h calcination at 800 Degree-Sign C). The proposed procedure seems to be more preferable for mass production. The result indicated that the polymorphic transformation to tetragonal (ferroelectric characteristic) occurred at 900 Degree-Sign C, which might be an indication of being nanosized.

  8. Resorption Rate Tunable Bioceramic: Si, Zn-Modified Tricalcium Phosphate

    SciTech Connect (OSTI)

    Xiang Wei

    2006-08-09

    This dissertation is organized in an alternate format. Several manuscripts which have already been published or are to be submitted for publication have been included as separate chapters. Chapter 1 is a general introduction which describes the dissertation organization and introduces the human bone and ceramic materials as bone substitute. Chapter 2 is the background and literature review on dissolution behavior of calcium phosphate, and discussion of motivation for this research. Chapter 3 is a manuscript entitled ''Si,Zn-modified tricalcium phosphate: a phase composition and crystal structure study'', which was published in ''Key Engineering Materials'' [1]. Chapter 4 gives more crystal structure details by neutron powder diffraction, which identifies the position for Si and Zn substitution and explains the stabilization mechanism of the structure. A manuscript entitled ''Crystal structure analysis of Si, Zn-modified Tricalcium phosphate by Neutron Powder Diffraction'' will be submitted to Biomaterials [2]. Chapter 5 is a manuscript, entitled ''Dissolution behavior and cytotoxicity test of Si, Zn-modified tricalcium phosphate'', which is to be submitted to Biomaterials [3]. This paper discusses the additives effect on the dissolution behavior of TCP, and cytotoxicity test result is also included. Chapter 6 is the study of hydrolysis process of {alpha}-tricalcium phosphate in the simulated body fluid, and the phase development during drying process is discussed. A manuscript entitled ''Hydrolysis of {alpha}-tricalcium phosphate in simulated body fluid and phase transformation during drying process'' is to be submitted to Biomaterials [4]. Ozan Ugurlu is included as co-authors in these two papers due to his TEM contributions. Appendix A is the general introduction of the materials synthesis, crystal structure and preliminary dissolution result. A manuscript entitled ''Resorption rate tunable bioceramic: Si and Zn-modified tricalcium phosphate'' was published in Ceramic Engineering and Science Proceedings (the 29th International Conference on Advanced Ceramics and Composites - Advances in Bioceramics and Biocomposites) [5].

  9. Modified Yeast to Boost Biofuel Yields - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Modified Yeast to Boost Biofuel Yields Great Lakes Bioenergy Research Center Contact GLBRC About This Technology Technology Marketing Summary Producing biofuel on an industrial scale requires efficient fermentation of cellulosic plant material. Glucose and xylose are two of the most abundant sugars found in biomass. The yeast most commonly used for fermentation - Saccharomyces cerevisiae - can ferment glucose but not xylose. Researchers hope to improve fermentation by identifying/mutating

  10. Modified Yeast with Enhanced Tolerance for GVL Biomass Solvent - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Modified Yeast with Enhanced Tolerance for GVL Biomass Solvent Great Lakes Bioenergy Research Center Contact GLBRC About This Technology Technology Marketing Summary Gamma-valerolactone (GVL) is an inexpensive solvent derived from biomass that can be used to break apart tough lignocellulose into fermentable sugars including xylose and glucose. GVL-based techniques are a potentially transformative breakthrough in biofuel production (for more information see WARF reference

  11. Modified electrochemical properties of organic quinoxaline via electrolyte

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    interactions in propylene carbonate - Joint Center for Energy Storage Research 4, 2015, Research Highlights Modified electrochemical properties of organic quinoxaline via electrolyte interactions in propylene carbonate Theoretical gravimetric capacity of quinoxaline : 410 mAh/g Solubility > 5M in carbonate solvents Scientific Achievement Quinoxalines are highly sensitive to solvent and electrolyte interactions. For example, bare quinoxaline is active in acetonitrile at DFT-predicted

  12. Structure formation in a nonlocally modified gravity model

    SciTech Connect (OSTI)

    Park, Sohyun; Dodelson, Scott

    2013-01-01

    We study a nonlocally modified gravity model proposed by Deser and Woodard which gives an explanation for current cosmic acceleration. By deriving and solving the equations governing the evolution of the structure in the Universe, we show that this model predicts a pattern of growth that differs from standard general relativity (+dark energy) at the 10-30% level. These differences will be easily probed by the next generation of galaxy surveys, so the model should be tested shortly.

  13. Grass Modified for Easier Bioprocessing - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Grass Modified for Easier Bioprocessing Great Lakes Bioenergy Research Center Contact GLBRC About This Technology Technology Marketing Summary Manufacturing paper and producing biofuels is difficult because the lignin in plant cell walls is tough to degrade. Current techniques are energy intensive and use harsh chemicals. In the case of biofuels, costly pretreatments are required to alter the lignin and help enzymes produce sugars for fermentation. Grass lignins contain large amounts of

  14. The role of vector fields in modified gravity scenarios

    SciTech Connect (OSTI)

    Tasinato, Gianmassimo; Koyama, Kazuya; Khosravi, Nima E-mail: kazuya.koyama@port.ac.uk

    2013-11-01

    Gravitational vector degrees of freedom typically arise in many examples of modified gravity models. We start to systematically explore their role in these scenarios, studying the effects of coupling gravitational vector and scalar degrees of freedom. We focus on set-ups that enjoy a Galilean symmetry in the scalar sector and an Abelian gauge symmetry in the vector sector. These symmetries, together with the requirement that the equations of motion contain at most two space-time derivatives, only allow for a small number of operators in the Lagrangian for the gravitational fields. We investigate the role of gravitational vector fields for two broad classes of phenomena that characterize modified gravity scenarios. The first is self-acceleration: we analyze in general terms the behavior of vector fluctuations around self-accelerating solutions, and show that vanishing kinetic terms of vector fluctuations lead to instabilities on cosmological backgrounds. The second phenomenon is the screening of long range fifth forces by means of Vainshtein mechanism. We show that if gravitational vector fields are appropriately coupled to a spherically symmetric source, they can play an important role for defining the features of the background solution and the scale of the Vainshtein radius. Our general results can be applied to any concrete model of modified gravity, whose low-energy vector and scalar degrees of freedom satisfy the symmetry requirements that we impose.

  15. Characterization and thermal stability of cobalt-modified 1-D nanostructured trititanates

    SciTech Connect (OSTI)

    Morgado, Edisson; Abreu, Marco A.S. de

    2009-01-15

    One-dimensional (1-D) nanostructured sodium trititanates were obtained via alkali hydrothermal method and modified with cobalt via ion exchange at different Co concentrations. The resulting cobalt-modified trititanate nanostructures (Co-TTNS) were characterized by TGA, XRD, TEM/SAED, DRS-UV-Vis and N{sub 2} adsorption techniques. Their general chemical formula was estimated as Na{sub x}Co{sub y/2}H{sub 2-x-y}Ti{sub 3}O{sub 7}.nH{sub 2}O and they maintained the same nanostructured and multilayered nature of the sodium precursor, with the growth direction of nanowires and nanotubes along [010]. As a consequence of the Co{sup 2+} incorporation replacing sodium between trititanate layers, two new diffraction lines became prominent and the interlayer distance was reduced with respect to that of the precursor sodium trititanate. Surface area was slightly increased with cobalt intake whereas pore size distribution was hardly affected. Besides, Co{sup 2+} incorporation in trititanate crystal structure also resulted in enhanced visible light photon absorption as indicated by a strong band-gap narrowing. Morphological and structural thermal transformations of Co-TTNS started nearly 400 deg. C in air and the final products after calcination at 800 deg. C were found to be composed of TiO{sub 2}-rutile, CoTiO{sub 3} and a bronze-like phase with general formula Na{sub 2x}Ti{sub 1-x}Co{sub x}O{sub 2}. - Graphical abstract: Co{sup 2+} incorporation in 1D-trititanate crystal nanostructure (Co-TTNS) causes reduction in interlayer distance by comparison with its sodium precursor (Na-TTNS) and leads to enhanced visible light photon absorption efficiency due to a strong band-gap narrowing.

  16. CBEI: Coordinating RTUs in Small and Medium Sized Commercial Buildings -

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2015 Peer Review | Department of Energy Coordinating RTUs in Small and Medium Sized Commercial Buildings - 2015 Peer Review CBEI: Coordinating RTUs in Small and Medium Sized Commercial Buildings - 2015 Peer Review Presenter: James Braun, Purdue University View the Presentation PDF icon CBEI: Coordinating RTUs in Small and Medium Sized Commercial Buildings - 2015 Peer Review More Documents & Publications Control and Diagnostics for Rooftop Units - 2014 BTO Peer Review CBEI: Lessons

  17. SBA Increases Size Standards for Waste Remediation Services &

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Information/Admin Support | Department of Energy Increases Size Standards for Waste Remediation Services & Information/Admin Support SBA Increases Size Standards for Waste Remediation Services & Information/Admin Support December 12, 2012 - 10:22am Addthis John H. Hale III John H. Hale III Director, Office of Small and Disadvantaged Business Utilization Earlier this week, the U.S. Small Business Administration announced that they have revised size definitions for small businesses in

  18. Quantum-size-controlled photoelectrochemical etching of semiconductor nanostructures

    DOE Patents [OSTI]

    Fischer, Arthur J.; Tsao, Jeffrey Y.; Wierer, Jr., Jonathan J.; Xiao, Xiaoyin; Wang, George T.

    2016-03-01

    Quantum-size-controlled photoelectrochemical (QSC-PEC) etching provides a new route to the precision fabrication of epitaxial semiconductor nanostructures in the sub-10-nm size regime. For example, quantum dots (QDs) can be QSC-PEC-etched from epitaxial InGaN thin films using narrowband laser photoexcitation, and the QD sizes (and hence bandgaps and photoluminescence wavelengths) are determined by the photoexcitation wavelength.

  19. Measuring the Raindrop Size Distribution, ARM's Efforts at Darwin...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the Raindrop Size Distribution, ARM's Efforts at Darwin and SGP Bartholomew, Mary Jane Brookhaven National Laboratory Category: Instruments ARM has purchased two impact...

  20. Solar Trackers Market - Global Industry Analysis, Size, Share...

    Open Energy Info (EERE)

    Solar Trackers Market - Global Industry Analysis, Size, Share, Growth, Trends and Forecast, 2010 - 2020 Home > Groups > Increase Natural Gas Energy Efficiency John55364's picture...

  1. Characterization of Vertical Velocity and Drop Size Distribution...

    Office of Scientific and Technical Information (OSTI)

    Additional insights into the form of the raindrop size distribution are provided using available dual-frequency Doppler velocity observations at SGP. The analysis suggests that ...

  2. Correlating Size and Composition-Dependent Effects with Magnetic...

    Office of Scientific and Technical Information (OSTI)

    Correlating Size and Composition-Dependent Effects with Magnetic, Mssbauer, and Pair Distribution Function Measurements in a Family of Catalytically Active Ferrite Nanoparticles ...

  3. CBEI - Coordinating RTUs in Small & Medium Sized Commercial Buildings

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    controls for SMSCBs (small and medium-size commercial buildings) are rarely implemented because of poor overall economics. Low-touch, low-cost control implementations are needed. ...

  4. Overview of Detailed Chemical Speciation and Particle Sizing...

    Broader source: Energy.gov (indexed) [DOE]

    The Impact of Oil Consumption Mechanisms on Diesel Exhaust Particle Size Distributions and Detailed Exhaust Chemical Composition Microsoft PowerPoint - DEER03-P.ppt Development and ...

  5. Building America Webinar: HVAC Right-Sizing Part 1-Calculating...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the key criteria required to create accurate heating and cooling load calculations. ... HVAC Right-Sizing Part 1: Calculating Loads ZERH Webinar: Low Load HVAC in Zero Energy ...

  6. TVA - Mid-Sized Renewable Standard Offer Program | Department...

    Broader source: Energy.gov (indexed) [DOE]

    kWh Summary The Tennessee Valley Authority (TVA) now compliments the small generation Green Power Providers Program by providing incentives for mid-sized renewable energy...

  7. Development of Model Filtration Media for Investigating Size...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Development of Model Filtration Media for Investigating Size-Dependent Filtration Efficiency A novel method for fabricating custom porous filtration media for emission control has ...

  8. CBEI: HVAC Packages for Small and Medium Sized Commercial Buildings...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CBEI: HVAC Packages for Small and Medium Sized Commercial Buildings - 2015 Peer Review Presenter: Russell Taylor, United Technologies Research Center View the Presentation PDF icon ...

  9. Efficient Algorithm for Locating and Sizing Series Compensation...

    Office of Scientific and Technical Information (OSTI)

    Compensation Devices in Large Transmission Grids: Model Implementation We explore optimization methods for planning the placement, sizing and operations of Flexible Alternating...

  10. Nano-sized structured layered positive electrode materials to...

    Office of Scientific and Technical Information (OSTI)

    positive electrode materials to enable high energy density and high rate capability lithium batteries Title: Nano-sized structured layered positive electrode materials to ...

  11. Property:Incentive/EligSysSize | Open Energy Information

    Open Energy Info (EERE)

    minimum
    Recycled Energy: 15 Megawatt maximum Alameda Municipal Power - Solar Photovoltaics Rebate Program (California) + Maximum size is 1 MW or 110% of customer's...

  12. Size and composition-controlled fabrication of VO2 nanocrystals...

    Office of Scientific and Technical Information (OSTI)

    by terminated cluster growth Citation Details In-Document Search Title: Size and composition-controlled fabrication of VO2 nanocrystals by terminated cluster growth You are ...

  13. Size and composition-controlled fabrication of VO2 nanocrystals...

    Office of Scientific and Technical Information (OSTI)

    by terminated cluster growth Citation Details In-Document Search Title: Size and composition-controlled fabrication of VO2 nanocrystals by terminated cluster growth A physical ...

  14. Neutrons measure phase behavior in pores at Angstrom size (Journal...

    Office of Scientific and Technical Information (OSTI)

    Nanoporous carbons can also serve as electrode material for supercapacitors and batteries. The researchers successfully determined that the most efficiently condensing pore size in ...

  15. Droplet sizes, dynamics and deposition in vertical annular flow

    SciTech Connect (OSTI)

    Lopes, J C.B.; Dukler, A E

    1985-10-01

    The role of droplets in vertical upwards annular flow is investigated, focusing on the droplet size distributions, dynamics, and deposition phenomena. An experimental program was performed based on a new laser optical technique developed in these laboratories and implemented here for annular flow. This permitted the simultaneous measurement of droplet size, axial and radial velocity. The dependence of droplet size distributions on flow conditions is analyzed. The Upper-Log Normal function proves to be a good model for the size distribution. The mechanism controlling the maximum stable drop size was found to result from the interaction of the pressure fluctuations of the turbulent flow of the gas core with the droplet. The average axial droplet velocity showed a weak dependence on gas rates. This can be explained once the droplet size distribution and droplet size-velocity relationship are analyzed simultaneously. The surprising result from the droplet conditional analysis is that larger droplet travel faster than smaller ones. This dependence cannot be explained if the drag curves used do not take into account the high levels of turbulence present in the gas core in annular flow. If these are considered, then interesting new situations of multiplicity and stability of droplet terminal velocities are encountered. Also, the observed size-velocity relationship can be explained. A droplet deposition is formulated based on the particle inertia control. This permitted the calculation of rates of drop deposition directly from the droplet size and velocities data.

  16. Modified Anti-de-Sitter Metric, Light-Front Quantized QCD, and...

    Office of Scientific and Technical Information (OSTI)

    Modified Anti-de-Sitter Metric, Light-Front Quantized QCD, and Conformal Quantum Mechanics Citation Details In-Document Search Title: Modified Anti-de-Sitter Metric, Light-Front...

  17. Method of producing submicron size particles and product produced thereby

    DOE Patents [OSTI]

    Bourne, R.S.; Eichman, C.C.; Welbon, W.W.

    1988-05-11

    Submicron size particles are produced by using a sputtering process to deposit particles into a liquid. The liquid is processed to recover the particles therefrom, and the particles have sizes in the range of twenty to two hundred Angstroms. Either metallic or non-metallic particles can be produced, and the metallic particles can be used in ''metallic inks.'' 4 figs.

  18. Characterization of modified 9 Cr-1 Mo steel extruded pipe

    SciTech Connect (OSTI)

    Sikka, V.K.; Hart, M.D.

    1985-04-01

    The fabrication of hot-extruded pipe of modified 9 Cr-1 Mo steel at Cameron Iron Works is described. The report also deals with the tempering response; tensile, Charpy impact, and creep properties; and microstructure of the hot-extruded pipe. The tensile properties of the pipe are compared with the average and average -1.65 standard error of estimate curves for various product forms of several commercial heats of this alloy. The creep-rupture properties are compared with the average curve for various product forms of the commercial heats.

  19. Hydrogen peroxide modified sodium titanates with improved sorption capabilities

    DOE Patents [OSTI]

    Nyman, May D.; Hobbs, David T.

    2009-02-24

    The sorption capabilities (e.g., kinetics, selectivity, capacity) of the baseline monosodium titanate (MST) sorbent material currently being used to sequester Sr-90 and alpha-emitting radioisotopes at the Savannah River Site are significantly improved when treated with hydrogen peroxide; either during the original synthesis of MST, or, as a post-treatment step after the MST has been synthesized. It is expected that these peroxide-modified MST sorbent materials will have significantly improved sorption capabilities for non-radioactive cations found in industrial processes and waste streams.

  20. Dielectric behavior of barium modified strontium bismuth titanate ceramic

    SciTech Connect (OSTI)

    Nayak, P.; Badapanda, T.; Anwar, S.; Panigrahi, S.

    2014-04-24

    Barium Modified Strontium Bismuth Titanate(SBT) ceramic with general formula Sr1?xBaxBi4Ti4O15 is prepared by solid state reaction route. The structural analysis of the ceramics was done by X-ray diffraction technique. The X-ray patterns show that all the compositions are of single phase with orthorhombic structure. The temperature dependent dielectric behavior shows that the transition temperature decreases with Ba content but the maximum dielectric constant increases. The decreases of the transition with increase in Ba{sup 2+} ion, may be due to the decrease of orthorhombicity by the incorporation of Ba{sup 2+} ion in SBT lattice.

  1. Methods for modifying monofilaments, bundles of monofilaments, and fibrous structural material

    DOE Patents [OSTI]

    Allen, Charles A.; Argyle, Mark D.; Fox, Robert V.; Ginosar, Daniel M.; Janikowski, Stuart K.; Miller, David L.; Propp, W. Alan; Toth, William J.

    2002-12-17

    The present invention is related to the modifying of substrates such as monofilaments, bundles of monofilaments, and fibrous structural material with a modifying agent. The modifying agent is suspended or dissolved in a supercritical fluid, near-critical fluid, superheated fluid, superheated liquid, or a liquified gas and is deposited by rapidly altering the pressure in a chamber to deposit the modifying material onto the substrate.

  2. Nanocomposite fibers and film containing polyolefin and surface-modified carbon nanotubes

    DOE Patents [OSTI]

    Chu,Benjamin (Setauket, NY); Hsiao, Benjamin S. (Setauket, NY)

    2010-01-26

    Methods for modifying carbon nanotubes with organic compounds are disclosed. The modified carbon nanotubes have enhanced compatibility with polyolefins. Nanocomposites of the organo-modified carbon nanotubes and polyolefins can be used to produce both fibers and films having enhanced mechanical and electrical properties, especially the elongation-to-break ratio and the toughness of the fibers and/or films.

  3. Generalized Gibbs state with modified Redfield solution: Exact agreement up to second order

    SciTech Connect (OSTI)

    Thingna, Juzar; Wang, Jian-Sheng; Haenggi, Peter

    2012-05-21

    A novel scheme for the steady state solution of the standard Redfield quantum master equation is developed which yields agreement with the exact result for the corresponding reduced density matrix up to second order in the system-bath coupling strength. We achieve this objective by use of an analytic continuation of the off-diagonal matrix elements of the Redfield solution towards its diagonal limit. Notably, our scheme does not require the provision of yet higher order relaxation tensors. Testing this modified method for a heat bath consisting of a collection of harmonic oscillators we assess that the system relaxes towards its correct coupling-dependent, generalized quantum Gibbs state in second order. We numerically compare our formulation for a damped quantum harmonic system with the nonequilibrium Green's function formalism: we find good agreement at low temperatures for coupling strengths that are even larger than expected from the very regime of validity of the second-order Redfield quantum master equation. Yet another advantage of our method is that it markedly reduces the numerical complexity of the problem; thus, allowing to study efficiently large-sized system Hilbert spaces.

  4. Carbon dioxide pressure swing adsorption process using modified alumina adsorbents

    DOE Patents [OSTI]

    Gaffney, T.R.; Golden, T.C.; Mayorga, S.G.; Brzozowski, J.R.; Taylor, F.W.

    1999-06-29

    A pressure swing adsorption process for absorbing CO[sub 2] from a gaseous mixture containing CO[sub 2] comprises introducing the gaseous mixture at a first pressure into a reactor containing a modified alumina adsorbent maintained at a temperature ranging from 100 C and 500 C to adsorb CO[sub 2] to provide a CO[sub 2] laden alumina adsorbent and a CO[sub 2] depleted gaseous mixture and contacting the CO[sub 2] laden adsorbent with a weakly adsorbing purge fluid at a second pressure which is lower than the first pressure to desorb CO[sub 2] from the CO[sub 2] laden alumina adsorbent. The modified alumina adsorbent which is formed by depositing a solution having a pH of 3.0 or more onto alumina and heating the alumina to a temperature ranging from 100 C and 600 C, is not degraded by high concentrations of water under process operating conditions. 1 fig.

  5. Carbon dioxide pressure swing adsorption process using modified alumina adsorbents

    DOE Patents [OSTI]

    Gaffney, Thomas Richard; Golden, Timothy Christopher; Mayorga, Steven Gerard; Brzozowski, Jeffrey Richard; Taylor, Fred William

    1999-01-01

    A pressure swing adsorption process for absorbing CO.sub.2 from a gaseous mixture containing CO.sub.2 comprising introducing the gaseous mixture at a first pressure into a reactor containing a modified alumina adsorbent maintained at a temperature ranging from 100.degree. C. and 500.degree. C. to adsorb CO.sub.2 to provide a CO.sub.2 laden alumina adsorbent and a CO.sub.2 depleted gaseous mixture and contacting the CO.sub.2 laden adsorbent with a weakly adsorbing purge fluid at a second pressure which is lower than the first pressure to desorb CO.sub.2 from the CO.sub.2 laden alumina adsorbent. The modified alumina adsorbent which is formed by depositing a solution having a pH of 3.0 or more onto alumina and heating the alumina to a temperature ranging from 100.degree. C. and 600.degree. C., is not degraded by high concentrations of water under process operating conditions.

  6. Morphological studies on block copolymer modified PA 6 blends

    SciTech Connect (OSTI)

    Poindl, M., E-mail: marcus.poindl@ikt.uni-stuttgart.de, E-mail: christian.bonten@ikt.uni-stuttgart.de; Bonten, C., E-mail: marcus.poindl@ikt.uni-stuttgart.de, E-mail: christian.bonten@ikt.uni-stuttgart.de [Institut fr Kunststofftechnik, University of Stuttgart (Germany)

    2014-05-15

    Recent studies show that compounding polyamide 6 (PA 6) with a PA 6 polyether block copolymers made by reaction injection molding (RIM) or continuous anionic polymerization in a reactive extrusion process (REX) result in blends with high impact strength and high stiffness compared to conventional rubber blends. In this paper, different high impact PA 6 blends were prepared using a twin screw extruder. The different impact modifiers were an ethylene propylene copolymer, a PA PA 6 polyether block copolymer made by reaction injection molding and one made by reactive extrusion. To ensure good particle matrix bonding, the ethylene propylene copolymer was grafted with maleic anhydride (EPR-g-MA). Due to the molecular structure of the two block copolymers, a coupling agent was not necessary. The block copolymers are semi-crystalline and partially cross-linked in contrast to commonly used amorphous rubbers which are usually uncured. The combination of different analysis methods like atomic force microscopy (AFM), transmission electron microscopy (TEM) and scanning electron microscopy (SEM) gave a detailed view in the structure of the blends. Due to the partial cross-linking, the particles of the block copolymers in the blends are not spherical like the ones of ethylene propylene copolymer. The differences in molecular structure, miscibility and grafting of the impact modifiers result in different mechanical properties and different blend morphologies.

  7. Galaxy cluster lensing masses in modified lensing potentials

    SciTech Connect (OSTI)

    Barreira, Alexandre; Li, Baojiu; Jennings, Elise; Merten, Julian; King, Lindsay; Baugh, Carlton M.; Pascoli, Silvia

    2015-10-28

    In this study, we determine the concentration–mass relation of 19 X-ray selected galaxy clusters from the Cluster Lensing and Supernova Survey with Hubble survey in theories of gravity that directly modify the lensing potential. We model the clusters as Navarro–Frenk–White haloes and fit their lensing signal, in the Cubic Galileon and Nonlocal gravity models, to the lensing convergence profiles of the clusters. We discuss a number of important issues that need to be taken into account, associated with the use of non-parametric and parametric lensing methods, as well as assumptions about the background cosmology. Our results show that the concentration and mass estimates in the modified gravity models are, within the error bars, the same as in Λ cold dark matter. This result demonstrates that, for the Nonlocal model, the modifications to gravity are too weak at the cluster redshifts, and for the Galileon model, the screening mechanism is very efficient inside the cluster radius. However, at distances ~ [2–20] Mpc/h from the cluster centre, we find that the surrounding force profiles are enhanced by ~ 20–40% in the Cubic Galileon model. This has an impact on dynamical mass estimates, which means that tests of gravity based on comparisons between lensing and dynamical masses can also be applied to the Cubic Galileon model.

  8. Applying a Modified Triad Approach to Investigate Wastewater lines

    SciTech Connect (OSTI)

    Pawlowicz, R.; Urizar, L.; Blanchard, S.; Jacobsen, K.; Scholfield, J.

    2006-07-01

    Approximately 20 miles of wastewater lines are below grade at an active military Base. This piping network feeds or fed domestic or industrial wastewater treatment plants on the Base. Past wastewater line investigations indicated potential contaminant releases to soil and groundwater. Further environmental assessment was recommended to characterize the lines because of possible releases. A Remedial Investigation (RI) using random sampling or use of sampling points spaced at predetermined distances along the entire length of the wastewater lines, however, would be inefficient and cost prohibitive. To accomplish RI goals efficiently and within budget, a modified Triad approach was used to design a defensible sampling and analysis plan and perform the investigation. The RI task was successfully executed and resulted in a reduced fieldwork schedule, and sampling and analytical costs. Results indicated that no major releases occurred at the biased sampling points. It was reasonably extrapolated that since releases did not occur at the most likely locations, then the entire length of a particular wastewater line segment was unlikely to have contaminated soil or groundwater and was recommended for no further action. A determination of no further action was recommended for the majority of the waste lines after completing the investigation. The modified Triad approach was successful and a similar approach could be applied to investigate wastewater lines on other United States Department of Defense or Department of Energy facilities. (authors)

  9. Galaxy cluster lensing masses in modified lensing potentials

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Barreira, Alexandre; Li, Baojiu; Jennings, Elise; Merten, Julian; King, Lindsay; Baugh, Carlton M.; Pascoli, Silvia

    2015-10-28

    In this study, we determine the concentration–mass relation of 19 X-ray selected galaxy clusters from the Cluster Lensing and Supernova Survey with Hubble survey in theories of gravity that directly modify the lensing potential. We model the clusters as Navarro–Frenk–White haloes and fit their lensing signal, in the Cubic Galileon and Nonlocal gravity models, to the lensing convergence profiles of the clusters. We discuss a number of important issues that need to be taken into account, associated with the use of non-parametric and parametric lensing methods, as well as assumptions about the background cosmology. Our results show that the concentrationmore » and mass estimates in the modified gravity models are, within the error bars, the same as in Λ cold dark matter. This result demonstrates that, for the Nonlocal model, the modifications to gravity are too weak at the cluster redshifts, and for the Galileon model, the screening mechanism is very efficient inside the cluster radius. However, at distances ~ [2–20] Mpc/h from the cluster centre, we find that the surrounding force profiles are enhanced by ~ 20–40% in the Cubic Galileon model. This has an impact on dynamical mass estimates, which means that tests of gravity based on comparisons between lensing and dynamical masses can also be applied to the Cubic Galileon model.« less

  10. Synthesis and CO{sub 2} adsorption study of modified MOF-5 with multi-wall carbon nanotubes and expandable graphite

    SciTech Connect (OSTI)

    Ullah, Sami E-mail: azmibustam@petronas.com.my E-mail: lkhlfh@gmail.com E-mail: nadiariazz@gmail.com; Bustam, M. A. E-mail: azmibustam@petronas.com.my E-mail: lkhlfh@gmail.com E-mail: nadiariazz@gmail.com; Shariff, A. M. E-mail: azmibustam@petronas.com.my E-mail: lkhlfh@gmail.com E-mail: nadiariazz@gmail.com; Elkhalifah, Ali E. I. E-mail: azmibustam@petronas.com.my E-mail: lkhlfh@gmail.com E-mail: nadiariazz@gmail.com; Murshid, G. E-mail: azmibustam@petronas.com.my E-mail: lkhlfh@gmail.com E-mail: nadiariazz@gmail.com; Riaz, Nadia E-mail: azmibustam@petronas.com.my E-mail: lkhlfh@gmail.com E-mail: nadiariazz@gmail.com

    2014-10-24

    MOF-5 was synthesized by solvothermal method and its reactivation under anhydrous conditions. This research is conducted to investigate the effect of MOF-5 and MOF-5 modified with multi-wall carbon nanotubes (MWCNTs) and expandable graphite (EG) on the performance of CO{sub 2} adsorption. The synthesized MOFs were characterized using Field emission scanning electron microscopy (FESEM) for surface morphology, Thermogravimetric analysis (TGA) for thermal stability, X-ray diffraction (XRD) for crystals plane, Brunauer-Emmet-Teller (BET) for surface area and CO{sub 2} adsorption. The result had showed that the modified MOF-5 enhanced the CO{sub 2} adsorption compared to the pure MOF-5. The increment in the CO{sub 2} uptake capacities of MOF materials was attributed to the decrease in the pore size and enhancement of micropore volume of MOF-5 by multi-walled carbon nanotube and EG incorporation. The BET surface area of the synthesized MOF-5@MWCNTs is more than MOF-5. The CO{sub 2} sorption capacities of MOF-5 and MOF-5@MWCNTs were observed to increase from 0.00008 to 0.00048 mol g-1 at 298 K and 1 bar. The modified MOF-5@MWCNTs resulted in the highest CO{sub 2} adsorption followed by the modified MOF-5@ EG and lastly, MOF-5.

  11. The influence of aluminum grain size on alumina nanoporous structure

    SciTech Connect (OSTI)

    Feil, A. F.; Costa, M. V. da; Amaral, L.; Teixeira, S. R.; Migowski, P.; Dupont, J.; Machado, G.; Peripolli, S. B.

    2010-01-15

    An approach to control the interpore distances and nanopore diameters of 150-nm-thick thin aluminum films is reported here. The Al thin films were grown by sputtering on p-type silicon substrate and anodized with a conventional anodization process in a phosphoric acid solution. It was found that interpore distance and pore diameter are related to the aluminum grain size and can be controlled by annealing. The grain contours limit the sizes of alumina cells. This mechanism is valid for grain sizes supporting only one alumina cell and consequently only one pore.

  12. Pore-size-distribution of cationic polyacrylamide hydrogels. Progress report

    SciTech Connect (OSTI)

    Kremer, M.; Prausnitz, J.M.

    1992-06-01

    The pore size distribution of a AAm/MAPTAC (acrylamide copolymerized with (3-methacrylamidopropyl)trimethylammonium chloride) hydrogel was investigated using Kuga`s mixed-solute-exclusion method, taking into account the wall effect. A Brownian-motion model is also used. Results show the feasibility of determining pore-size distribution of porous materials using the mixed-solute-exclusion method in conjunction with solution of the Fredholm equation; good agreement was obtained with experiment, even for bimodal pore structures. However, different pore size distributions were calculated for the two different probe-solutes (Dextran and poly(ethylene glycol/oxide)). Future work is outlined. 32 figs, 25 refs.

  13. Pore-size-distribution of cationic polyacrylamide hydrogels

    SciTech Connect (OSTI)

    Kremer, M.; Prausnitz, J.M.

    1992-06-01

    The pore size distribution of a AAm/MAPTAC (acrylamide copolymerized with (3-methacrylamidopropyl)trimethylammonium chloride) hydrogel was investigated using Kuga's mixed-solute-exclusion method, taking into account the wall effect. A Brownian-motion model is also used. Results show the feasibility of determining pore-size distribution of porous materials using the mixed-solute-exclusion method in conjunction with solution of the Fredholm equation; good agreement was obtained with experiment, even for bimodal pore structures. However, different pore size distributions were calculated for the two different probe-solutes (Dextran and poly(ethylene glycol/oxide)). Future work is outlined. 32 figs, 25 refs.

  14. Modified carbohydrate-chitosan compounds, methods of making the same and methods of using the same

    DOE Patents [OSTI]

    Venditti, Richard A; Pawlak, Joel J; Salam, Abdus; El-Tahlawy, Khaled Fathy

    2015-03-10

    Compositions of matter are provided that include chitosan and a modified carbohydrate. The modified carbohydrate includes a carbohydrate component and a cross linking agent. The modified carbohydrate has increased carboxyl content as compared to an unmodified counterpart carbohydrate. A carboxyl group of the modified carbohydrate is covalently bonded with an amino group of chitosan. The compositions of matter provided herein may include cross linked starch citrate-chitosan and cross linked hemicellulose citrate-chitosan, including foams thereof. These compositions yield excellent absorbency and metal chelation properties. Methods of making cross linked modified carbohydrate-chitosan compounds are also provided.

  15. Nanoscale size dependence parameters on lattice thermal conductivity of Wurtzite GaN nanowires

    SciTech Connect (OSTI)

    Mamand, S.M.; Omar, M.S.; Muhammad, A.J.

    2012-05-15

    Graphical abstract: Temperature dependence of calculated lattice thermal conductivity of Wurtzite GaN nanowires. Highlights: Black-Right-Pointing-Pointer A modified Callaway model is used to calculate lattice thermal conductivity of Wurtzite GaN nanowires. Black-Right-Pointing-Pointer A direct method is used to calculate phonon group velocity for these nanowires. Black-Right-Pointing-Pointer 3-Gruneisen parameter, surface roughness, and dislocations are successfully investigated. Black-Right-Pointing-Pointer Dislocation densities are decreases with the decrease of wires diameter. -- Abstract: A detailed calculation of lattice thermal conductivity of freestanding Wurtzite GaN nanowires with diameter ranging from 97 to 160 nm in the temperature range 2-300 K, was performed using a modified Callaway model. Both longitudinal and transverse modes are taken into account explicitly in the model. A method is used to calculate the Debye and phonon group velocities for different nanowire diameters from their related melting points. Effect of Gruneisen parameter, surface roughness, and dislocations as structure dependent parameters are successfully used to correlate the calculated values of lattice thermal conductivity to that of the experimentally measured curves. It was observed that Gruneisen parameter will decrease with decreasing nanowire diameters. Scattering of phonons is assumed to be by nanowire boundaries, imperfections, dislocations, electrons, and other phonons via both normal and Umklapp processes. Phonon confinement and size effects as well as the role of dislocation in limiting thermal conductivity are investigated. At high temperatures and for dislocation densities greater than 10{sup 14} m{sup -2} the lattice thermal conductivity would be limited by dislocation density, but for dislocation densities less than 10{sup 14} m{sup -2}, lattice thermal conductivity would be independent of that.

  16. A stochastic method for stand-alone photovoltaic system sizing

    SciTech Connect (OSTI)

    Cabral, Claudia Valeria Tavora; Filho, Delly Oliveira; Martins, Jose Helvecio; Toledo, Olga Moraes

    2010-09-15

    Photovoltaic systems utilize solar energy to generate electrical energy to meet load demands. Optimal sizing of these systems includes the characterization of solar radiation. Solar radiation at the Earth's surface has random characteristics and has been the focus of various academic studies. The objective of this study was to stochastically analyze parameters involved in the sizing of photovoltaic generators and develop a methodology for sizing of stand-alone photovoltaic systems. Energy storage for isolated systems and solar radiation were analyzed stochastically due to their random behavior. For the development of the methodology proposed stochastic analysis were studied including the Markov chain and beta probability density function. The obtained results were compared with those for sizing of stand-alone using from the Sandia method (deterministic), in which the stochastic model presented more reliable values. Both models present advantages and disadvantages; however, the stochastic one is more complex and provides more reliable and realistic results. (author)

  17. Particle size and shape distributions of hammer milled pine

    SciTech Connect (OSTI)

    Westover, Tyler Lott; Matthews, Austin Colter; Williams, Christopher Luke; Ryan, John Chadron Benjamin

    2015-04-01

    Particle size and shape distributions impact particle heating rates and diffusion of volatized gases out of particles during fast pyrolysis conversion, and consequently must be modeled accurately in order for computational pyrolysis models to produce reliable results for bulk solid materials. For this milestone, lodge pole pine chips were ground using a Thomas-Wiley #4 mill using two screen sizes in order to produce two representative materials that are suitable for fast pyrolysis. For the first material, a 6 mm screen was employed in the mill and for the second material, a 3 mm screen was employed in the mill. Both materials were subjected to RoTap sieve analysis, and the distributions of the particle sizes and shapes were determined using digital image analysis. The results of the physical analysis will be fed into computational pyrolysis simulations to create models of materials with realistic particle size and shape distributions. This milestone was met on schedule.

  18. TVA - Mid-Sized Renewable Standard Offer Program | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    0.036kWh Summary The Tennessee Valley Authority (TVA) now compliments the small generation Green Power Providers Program by providing incentives for mid-sized renewable energy...

  19. Model catalysis by size-selected cluster deposition

    SciTech Connect (OSTI)

    Anderson, Scott

    2015-11-20

    This report summarizes the accomplishments during the last four years of the subject grant. Results are presented for experiments in which size-selected model catalysts were studied under surface science and aqueous electrochemical conditions. Strong effects of cluster size were found, and by correlating the size effects with size-dependent physical properties of the samples measured by surface science methods, it was possible to deduce mechanistic insights, such as the factors that control the rate-limiting step in the reactions. Results are presented for CO oxidation, CO binding energetics and geometries, and electronic effects under surface science conditions, and for the electrochemical oxygen reduction reaction, ethanol oxidation reaction, and for oxidation of carbon by water.

  20. 1999 Commercial Building Characteristics--Detailed Tables--Size...

    U.S. Energy Information Administration (EIA) Indexed Site

    Complete Set of 1999 CBECS Detailed Tables Detailed Tables- of Buildings Table B6. Building Size, Number of Buildings b6.pdf (PDF file), b6.xls (Excel spreadsheet file), b6.txt...

  1. Size Effect of Ruthenium Nanoparticles in Catalytic Carbon Monoxide Oxidation

    SciTech Connect (OSTI)

    Joo, Sang Hoon; Park, Jeong Y.; Renzas, J. Russell; Butcher, Derek R.; Huang, Wenyu; Somorjai, Gabor A.

    2010-04-04

    Carbon monoxide oxidation over ruthenium catalysts has shown an unusual catalytic behavior. Here we report a particle size effect on CO oxidation over Ru nanoparticle (NP) catalysts. Uniform Ru NPs with a tunable particle size from 2 to 6 nm were synthesized by a polyol reduction of Ru(acac){sub 3} precursor in the presence of poly(vinylpyrrolidone) stabilizer. The measurement of catalytic activity of CO oxidation over two-dimensional Ru NPs arrays under oxidizing reaction conditions (40 Torr CO and 100 Torr O{sub 2}) showed an activity dependence on the Ru NP size. The CO oxidation activity increases with NP size, and the 6 nm Ru NP catalyst shows 8-fold higher activity than the 2 nm catalysts. The results gained from this study will provide the scientific basis for future design of Ru-based oxidation catalysts.

  2. Photoluminescent 1-2 nm sized silicon nanoparticles: A surface...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Photoluminescent 1-2 nm sized silicon nanoparticles: A surface-dependent system Authors: Romero, J.J., Llansola-Portols, M.J., Dell'Arciprete, M.L., Rodrguez, H.B., Moore,...

  3. Global Nuclear Energy Partnership Triples in Size to 16 Members...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Global Nuclear Energy Partnership Triples in Size to 16 Members September 16, 2007 - 2:33pm Addthis Nations Sign On to International Cooperation for Safe Expansion of Nuclear ...

  4. TVA- Mid-Sized Renewable Standard Offer Program

    Broader source: Energy.gov [DOE]

    The Tennessee Valley Authority (TVA) now compliments the small generation Green Power Providers Program by providing incentives for mid-sized renewable energy generators between 50kW and 20MW to...

  5. Concentrations and Size Distributions of Particulate Matter Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Concentrations and Size Distributions of Particulate Matter Emissions from Catalyzed Trap-Equipped Heavy-duty Diesel Vehicles Operating on Ultra-low Sulfur EC-D Fuel Concentrations ...

  6. Knowledge-based sizing of cogeneration plant in buildings

    SciTech Connect (OSTI)

    Williams, J.M.; Griffiths, A.J.; Knight, I.P.

    1998-10-01

    Cogeneration is now accepted as a cost-effective and environmentally friendly means of meeting some of a building`s heating and power needs. Cogeneration plants have been installed in many buildings throughout the United Kingdom. Because of commercial pressures, building owners and cogeneration companies are keen to reduce the time and money involved in sizing units, and a decision support tool has been developed to aid the engineer in selecting the unit size. An initial assessment of the sizing can be made with only knowledge of the building`s type, size, and location, which enables the model to be used in new build situations. For an existing building, the accuracy of the predictions can then be progressively improved by providing more information about the building`s energy use, enabling the optimum unit to be identified. This paper briefly describes the model and demonstrates its use through an example feasibility study.

  7. TVA - Mid-Sized Renewable Standard Offer Program | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    generation Green Power Providers Program by providing incentives for mid-sized renewable energy generators between 50kW and 20MW to enter into long term price contracts. The goal...

  8. Size Dependence of Two-Photon Absorption in Semiconductor Quantum...

    Office of Scientific and Technical Information (OSTI)

    In this work, we combine experiment and modeling to systematically investigate the size dependence of the degenerate two-photon absorption (TPA) of below-band-gap radiation in CdSe ...

  9. Evolution of droplet size distribution and autoconversion parameterization

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in turbulent clouds Evolution of droplet size distribution and autoconversion parameterization in turbulent clouds McGraw, Robert Brookhaven National Laboratory Liu, Yangang Brookhaven National Laboratory Category: Modeling Effects from turbulence-induced fluctuations in water vapor saturation on cloud droplet growth are examined using a Brownian diffusion model [McGraw and Liu, 2006]. The model predicts diffusive broadening of the droplet size distribution, tempered by enhanced

  10. Size Effects in the Electrochemical Alloying and Cycling of

    Office of Scientific and Technical Information (OSTI)

    Electrodeposited Aluminum with Lithium. (Journal Article) | SciTech Connect Size Effects in the Electrochemical Alloying and Cycling of Electrodeposited Aluminum with Lithium. Citation Details In-Document Search Title: Size Effects in the Electrochemical Alloying and Cycling of Electrodeposited Aluminum with Lithium. Abstract not provided. Authors: Hudak, Nicholas ; Huber, Dale L. Publication Date: 2011-10-01 OSTI Identifier: 1106948 Report Number(s): SAND2011-7589J 464917 DOE Contract

  11. AVTA: Full-Size Electric Vehicle Specifications and Test Procedures |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Full-Size Electric Vehicle Specifications and Test Procedures AVTA: Full-Size Electric Vehicle Specifications and Test Procedures PDF icon EV America Test Specifications PDF icon ETA-TP001 Implementation of SAE Standard J1263, February 1996 - Road Load Measurement and Dynamometer Simulation Using Coastdown Techniques PDF icon ETA-TP002 Implementation of SAE Standard J1666, May 1993 - Electric Vehicle Acceleration, Gradeability, and Deceleration Test Procedure PDF icon

  12. Characterization of Vertical Velocity and Drop Size Distribution Parameters

    Office of Scientific and Technical Information (OSTI)

    in Widespread Precipitation at ARM Facilities (Journal Article) | SciTech Connect Characterization of Vertical Velocity and Drop Size Distribution Parameters in Widespread Precipitation at ARM Facilities Citation Details In-Document Search Title: Characterization of Vertical Velocity and Drop Size Distribution Parameters in Widespread Precipitation at ARM Facilities Extended, high-resolution measurements of vertical air motion and median volume drop diameter D0 in widespread precipitation

  13. Microsoft PowerPoint - ARM2007LetterSize.ppt

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Remote sensing microphysical retrieval and cloud microphysics parameterizations rely on a knowledge of the shape of cloud drop size distributions (DSD). These are often approximated by Gamma, lognormal, or, more specifically by Khrgian-Mazin, Marshall-Palmer type distributions. We ask the question which functional form approximates best the drop size distributions in drizzling stratocumulus? Specifically, we evaluate the accuracy of lognormal and Gamma-type distributions in approximating higher

  14. Scalable Heuristics for Planning, Placement and Sizing of Flexible AC

    Office of Scientific and Technical Information (OSTI)

    Transmission System Devices (Technical Report) | SciTech Connect Technical Report: Scalable Heuristics for Planning, Placement and Sizing of Flexible AC Transmission System Devices Citation Details In-Document Search Title: Scalable Heuristics for Planning, Placement and Sizing of Flexible AC Transmission System Devices Aiming to relieve transmission grid congestion and improve or extend feasibility domain of the operations, we build optimization heuristics, generalizing standard AC Optimal

  15. Size selective absorption of DNA tetrahedra in ATO nanomaterials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Size selective absorption of DNA tetrahedra in ATO nanomaterials 22 Jun 2011 A group of Center for Bio-inspired Solar Fuel Production researchers collaborating on Subtask 2 (Water oxidation catalyst) and Subtask 5 (Functional nanostructured transparent electrode materials) have found that transparent and conducting antimony tin oxide with controlled pore size incorporates DNA nanocages with high affinity and without damage. Results of the study have been published in the June 2011 issue of ACS

  16. Modified Magnicon for High-Gradient Accelerator R&D

    SciTech Connect (OSTI)

    Jay L. Hirshfield

    2011-12-19

    Analysis, and low-power cold tests are described on a modified design intended for the Ka-band pulsed magnicon now in use for high-gradient accelerator R and D and rare elementary particle searches at the Yale University Beam Physics Laboratory. The modification is mainly to the output cavity of the magnicon, which presently operates in the TM310 mode. It is proposed to substitute for this a dual-chamber TE311 cavity structure. The first chamber is to extract about 40% of the beam power (about 25 MW) at 34.272 GHz, while the second chamber is to convey the power to four WR-28 output waveguides. Minor design changes are also proposed for the penultimate 11.424 GHz cavity and the beam collector. The intention of these design changes is to allow the magnicon to operate reliably 24/7, with minor sensitivity to operating parameters.

  17. Surface modified stainless steels for PEM fuel cell bipolar plates

    DOE Patents [OSTI]

    Brady, Michael P [Oak Ridge, TN; Wang, Heli [Littleton, CO; Turner, John A [Littleton, CO

    2007-07-24

    A nitridation treated stainless steel article (such as a bipolar plate for a proton exchange membrane fuel cell) having lower interfacial contact electrical resistance and better corrosion resistance than an untreated stainless steel article is disclosed. The treated stainless steel article has a surface layer including nitrogen-modified chromium-base oxide and precipitates of chromium nitride formed during nitridation wherein oxygen is present in the surface layer at a greater concentration than nitrogen. The surface layer may further include precipitates of titanium nitride and/or aluminum oxide. The surface layer in the treated article is chemically heterogeneous surface rather than a uniform or semi-uniform surface layer exclusively rich in chromium, titanium or aluminum. The precipitates of titanium nitride and/or aluminum oxide are formed by the nitriding treatment wherein titanium and/or aluminum in the stainless steel are segregated to the surface layer in forms that exhibit a low contact resistance and good corrosion resistance.

  18. Vector field models of modified gravity and the dark sector

    SciTech Connect (OSTI)

    Zuntz, J.; Ferreira, P. G.; Zlosnik, T. G; Bourliot, F.; Starkman, G. D.

    2010-05-15

    We present a comprehensive investigation of cosmological constraints on the class of vector field formulations of modified gravity called generalized Einstein-aether models. Using linear perturbation theory we generate cosmic microwave background and large-scale structure spectra for general parameters of the theory, and then constrain them in various ways. We investigate two parameter regimes: a dark matter candidate where the vector field sources structure formation, and a dark energy candidate where it causes late-time acceleration. We find that the dark matter candidate does not fit the data, and identify five physical problems that can restrict this and other theories of dark matter. The dark energy candidate does fit the data, and we constrain its fundamental parameters; most notably we find that the theory's kinetic index parameter n{sub ae} can differ significantly from its {Lambda}CDM value.

  19. Modifying gravity with the aether: An alternative to dark matter

    SciTech Connect (OSTI)

    Zlosnik, T. G; Ferreira, P. G; Starkman, G. D.

    2007-02-15

    There is evidence that Newton and Einstein's theories of gravity cannot explain the dynamics of a universe made up solely of baryons and radiation. To be able to understand the properties of galaxies, clusters of galaxies and the universe on the whole it has become commonplace to invoke the presence of dark matter. An alternative approach is to modify the gravitational field equations to accommodate observations. We propose a new class of gravitational theories in which we add a new degree of freedom, the Aether, in the form of a vector field that is coupled covariantly, but nonminimally, with the space-time metric. We explore the Newtonian and non-Newtonian limits, discuss the conditions for these theories to be consistent and explore their effect on cosmology.

  20. Lithium intercalation behavior of surface modified carbonaceous materials

    SciTech Connect (OSTI)

    Tran, T.D.; Murguia, L.X.; Song, X.; Kinoshita, K.

    1997-07-17

    The surface properties of several well-characterized commercial carbon materials were modified by thermal and chemical treatments. The reversible capacities for lithium intercalation of a sponge green coke and a fuel green coke for lithium intercalation increased by as much as 25% after heat treatment in both reducing (5% H{sub 2}/Ar) and oxidizing (CO{sub 2}) environments. The irreversible capacity loss increased significantly with CO{sub 2} treatment at 800{degrees}C. The trend of larger capacity losses with CO{sub 2} treatment is also observed with a synthetic graphite (SFG6) which was produced by heat treatment at about 3000{degrees}C. Carbon fibers that were first impregnated with LiOH solution followed by reaction with CO{sub 2} to form Li{sub 2}CO{sub 3} tended to show lower irreversible capacity losses.

  1. Decreasing transmembrane segment length greatly decreases perfringolysin O pore size

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lin, Qingqing; Li, Huilin; Wang, Tong; London, Erwin

    2015-04-08

    Perfringolysin O (PFO) is a transmembrane (TM) β-barrel protein that inserts into mammalian cell membranes. Once inserted into membranes, PFO assembles into pore-forming oligomers containing 30–50 PFO monomers. These form a pore of up to 300 Å, far exceeding the size of most other proteinaceous pores. In this study, we found that altering PFO TM segment length can alter the size of PFO pores. A PFO mutant with lengthened TM segments oligomerized to a similar extent as wild-type PFO, and exhibited pore-forming activity and a pore size very similar to wild-type PFO as measured by electron microscopy and a leakagemore » assay. In contrast, PFO with shortened TM segments exhibited a large reduction in pore-forming activity and pore size. This suggests that the interaction between TM segments can greatly affect the size of pores formed by TM β-barrel proteins. PFO may be a promising candidate for engineering pore size for various applications.« less

  2. Decreasing transmembrane segment length greatly decreases perfringolysin O pore size

    SciTech Connect (OSTI)

    Lin, Qingqing; Li, Huilin; Wang, Tong; London, Erwin

    2015-04-08

    Perfringolysin O (PFO) is a transmembrane (TM) β-barrel protein that inserts into mammalian cell membranes. Once inserted into membranes, PFO assembles into pore-forming oligomers containing 30–50 PFO monomers. These form a pore of up to 300 Å, far exceeding the size of most other proteinaceous pores. In this study, we found that altering PFO TM segment length can alter the size of PFO pores. A PFO mutant with lengthened TM segments oligomerized to a similar extent as wild-type PFO, and exhibited pore-forming activity and a pore size very similar to wild-type PFO as measured by electron microscopy and a leakage assay. In contrast, PFO with shortened TM segments exhibited a large reduction in pore-forming activity and pore size. This suggests that the interaction between TM segments can greatly affect the size of pores formed by TM β-barrel proteins. PFO may be a promising candidate for engineering pore size for various applications.

  3. Residential Variable-Capacity Heat Pumps Sized to Heating Loads

    SciTech Connect (OSTI)

    Munk, Jeffrey D.; Jackson, Roderick K.; Odukomaiya, Adewale; Gehl, Anthony C.

    2014-01-01

    Variable capacity heat pumps are an emerging technology offering significant energy savings potential and improved efficiency. With conventional single-speed systems, it is important to appropriately size heat pumps for the cooling load as over-sizing would result in cycling and insufficient latent capacity required for humidity control. These appropriately sized systems are often under-sized for the heating load and require inefficient supplemental electric resistance heat to meet the heating demand. Variable capacity heat pumps address these shortcomings by providing an opportunity to intentionally size systems for the dominant heating season load without adverse effects of cycling or insufficient dehumidification in the cooling season. This intentionally-sized system could result in significant energy savings in the heating season, as the need for inefficient supplemental electric resistance heat is drastically reduced. This is a continuation of a study evaluating the energy consumption of variable capacity heat pumps installed in two unoccupied research homes in Farragut, a suburb of Knoxville, Tennessee. In this particular study, space conditioning systems are intentionally sized for the heating season loads to provide an opportunity to understand and evaluate the impact this would have on electric resistance heat use and dehumidification. The results and conclusions drawn through this research are valid and specific for portions of the Southeastern and Midwestern United States falling in the mixed-humid climate zone. While other regions in the U.S. do not experience this type of climate, this work provides a basis for, and can help understand the implications of other climate zones on residential space conditioning energy consumption. The data presented here will provide a framework for fine tuning residential building EnergyPlus models that are being developed.

  4. Methods for producing partially digested restriction DNA fragments and for producing a partially modified PCR product

    DOE Patents [OSTI]

    Wong, Kwong-Kwok

    2000-01-01

    The present invention is an improved method of making a partially modified PCR product from a DNA fragment with a polymerase chain reaction (PCR). In a standard PCR process, the DNA fragment is combined with starting deoxynucleoside triphosphates, a primer, a buffer and a DNA polymerase in a PCR mixture. The PCR mixture is then reacted in the PCR producing copies of the DNA fragment. The improvement of the present invention is adding an amount of a modifier at any step prior to completion of the PCR process thereby randomly and partially modifying the copies of the DNA fragment as a partially modified PCR product. The partially modified PCR product may then be digested with an enzyme that cuts the partially modified PCR product at unmodified sites thereby producing an array of DNA restriction fragments.

  5. Effect of particle size reduction on anaerobic sludge digestion

    SciTech Connect (OSTI)

    Koutsospyros, A.D.

    1990-01-01

    The majority of organic pollutants in primary sludge are suspended in the form of particulate rather than soluble matter. Microbial organisms cannot assimilate this material without initial solubilization. In anaerobic digestion, the initial size breakdown is accomplished by hydrolytic bacteria. The extent of solubilization is limited by the size of particulate matter. Thus, size reduction prior to digestion is a sound alternative. Size reduction pretreatment was achieved by means of ultrasonic waves. Sonication proved an effective method for size reduction of particulate matter in primary sludge. In addition, although the method produced relatively high amounts of finely dispered solids, the filtration properties of resulting sludges were not affected. Chemical characteristics of sludge, important in anaerobic digestion, were not affected, at least within the attempted range of sonication time and amplitude. The effect of size reduction of primary sludge solids was studied under batch and semi-continuous feed conditions. Preliminary batch digestion experiments were conducted in five 1.5 liter reactors that accepted sonicated feeds of varying pretreatment at four different feed loads (3.3-13.3% by volume). The digestion efficiency and gas production were increased by as much as 30 percent as a result of sonication without any deterioration in the filtration properties of the digester effluent. At higher feed loads the digester efficiency dropped drastically and significant deterioration of the effluent filtration properties from all reactors was evident. Semi-continuous runs were conducted in four reactors. Solids retention time (SRT) was varied from 8 to 20 days. Process efficiency and gas production were enhanced as a result of sonication. Process improvement was more evident under short SRT (8-10 days).

  6. Modified Ni-Cu catalysts for ethanol steam reforming

    SciTech Connect (OSTI)

    Dan, M.; Mihet, M.; Almasan, V.; Borodi, G.; Katona, G.; Muresan, L.; Lazar, M. D.

    2013-11-13

    Three Ni-Cu catalysts, having different Cu content, supported on γ-alumina were synthesized by wet co-impregnation method, characterized and tested in the ethanol steam reforming (ESR) reaction. The catalysts were characterized for determination of: total surface area and porosity (N{sub 2} adsorption - desorption using BET and Dollimer Heal methods), Ni surface area (hydrogen chemisorption), crystallinity and Ni crystallites size (X-Ray Diffraction), type of catalytic active centers (Hydrogen Temperature Programmed Reduction). Total surface area and Ni crystallites size are not significantly influenced by the addition of Cu, while Ni surface area is drastically diminished by increasing of Cu concentration. Steam reforming experiments were performed at atmospheric pressure, temperature range 150-350°C, and ethanol - water molar ration of 1 at 30, using Ar as carrier gas. Ethanol conversion and hydrogen production increase by the addition of Cu. At 350°C there is a direct connection between hydrogen production and Cu concentration. Catalysts deactivation in 24h time on stream was studied by Transmission Electron Microscopy (TEM) and temperature-programmed reduction (TPR) on used catalysts. Coke deposition was observed at all studied temperatures; at 150°C amorphous carbon was evidenced, while at 350°C crystalline, filamentous carbon is formed.

  7. Level: National Data; Row: Employment Sizes within NAICS Codes;

    U.S. Energy Information Administration (EIA) Indexed Site

    4 Consumption Ratios of Fuel, 2006; Level: National Data; Row: Employment Sizes within NAICS Codes; Column: Energy-Consumption Ratios; Unit: Varies. Consumption Consumption per Dollar Consumption per Dollar of Value NAICS per Employee of Value Added of Shipments Code(a) Economic Characteristic(b) (million Btu) (thousand Btu) (thousand Btu) Total United States 311 - 339 ALL MANUFACTURING INDUSTRIES Employment Size Under 50 562.6 4.7 2.4 50-99 673.1 5.1 2.4 100-249 1,072.8 6.5 3.0 250-499 1,564.3

  8. Level: National Data; Row: Employment Sizes within NAICS Codes;

    U.S. Energy Information Administration (EIA) Indexed Site

    4 Consumption Ratios of Fuel, 2010; Level: National Data; Row: Employment Sizes within NAICS Codes; Column: Energy-Consumption Ratios; Unit: Varies. Consumption Consumption per Dollar Consumption per Dollar of Value NAICS per Employee of Value Added of Shipments Code(a) Economic Characteristic(b) (million Btu) (thousand Btu) (thousand Btu) Total United States 311 - 339 ALL MANUFACTURING INDUSTRIES Employment Size Under 50 625.5 3.3 1.7 50-99 882.3 5.8 2.5 100-249 1,114.9 5.8 2.5 250-499 2,250.4

  9. Metal oxide porous ceramic membranes with small pore sizes

    DOE Patents [OSTI]

    Anderson, Marc A.; Xu, Qunyin

    1992-01-01

    A method is disclosed for the production of metal oxide ceramic membranes of very small pore size. The process is particularly useful in the creation of titanium and other transition metal oxide membranes. The method utilizes a sol-gel process in which the rate of particle formation is controlled by substituting a relatively large alcohol in the metal alkoxide and by limiting the available water. Stable, transparent metal oxide ceramic membranes are created having a narrow distribution of pore size, with the pore diameter being manipulable in the range of 5 to 40 Angstroms.

  10. Metal oxide porous ceramic membranes with small pore sizes

    DOE Patents [OSTI]

    Anderson, Marc A.; Xu, Qunyin

    1991-01-01

    A method is disclosed for the production of metal oxide ceramic membranes of very small pore size. The process is particularly useful in the creation of titanium and other transition metal oxide membranes. The method utilizes a sol-gel process in which the rate of particle formation is controlled by substituting a relatively large alcohol in the metal alkoxide and by limiting the available water. Stable, transparent metal oxide ceramic membranes are created having a narrow distribution of pore size, with the pore diameter being manipulable in the range of 5 to 40 Angstroms.

  11. Size-Selective Incorporation of DNA Nanocages into Nanoporous

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Antimony-Doped Tin Oxide Materials Size-Selective Incorporation of DNA Nanocages into Nanoporous Antimony-Doped Tin Oxide Materials Authors: Simmons, C. R., Schmitt, D., Wei, X., Han, D., Volosin, A. M., Ladd, D. M., Seo, D.-K., Liu, Y., and Yan, H. Title: Size-Selective Incorporation of DNA Nanocages into Nanoporous Antimony-Doped Tin Oxide Materials Source: ACS Nano Year: 2011 Volume: 5 Pages: 6060-6068 ABSTRACT: A conductive nanoporous antimony-doped tin oxide (ATO) powder has been

  12. AVLIS modified direct denitration: UO{sub 3} powder evaluation

    SciTech Connect (OSTI)

    Slagle, O.D.; Davis, N.C.; Parchen, L.J.

    1994-02-01

    The evaluation study demonstrated that AVLIS-enriched uranium converted to UO{sub 3} can be used to prepare UO{sub 3} pellets having densities in the range required for commercial power reactor fuel. Specifically, the program has demonstrated that MDD (Modified Direct Denitration)-derived UO{sub 2} powders can be reduced to sinterable UO{sub 2} powder using reduction techniques that allow control of the final powder characteristics; the resulting UO{sub 2} powders can be processed/sintered using standard powder preparation and pellet fabrication techniques to yield pellets with densities greater than 96% TD; pellet microstructures appear similar to those of power reactor fuel, and because of the high final pellet densities, it is expected that they would remain stable during in-reactor operation; the results of the present study confirm the results of a similar study carried out in 1982 (Davis and Griffin 1992). The laboratory processes were selected on the basis that they could be scaled up to standard commercial fuel processing. However, larger scale testing may be required to establish techniques compatible with commercial fuel fabrication techniques.

  13. Radical-cured block copolymer-modified thermosets

    SciTech Connect (OSTI)

    Redline, Erica M.; Francis, Lorraine F.; Bates, Frank S.

    2013-01-10

    Poly(ethylene-alt-propylene)-b-poly(ethylene oxide) (PEP-PEO) diblock copolymers were synthesized and added at 4 wt % to 2,2-bis[4-(2-hydroxy-3-methacryloxypropoxy)phenyl]propane (BisGMA), a monomer that cures using free radical chemistry. In separate experiments, poly(ethylene glycol) dimethacrylate (PEGDMA) was combined as a secondary monomer with BisGMA and the monomers were loaded with 4 wt % PEP-PEO. The diblock copolymers self-assembled into well-dispersed spherical micelles with PEP cores and PEO coronas. No appreciable change in the final extent of cure of the thermosets was caused by the addition of diblock copolymer, except in the case of BisGMA, where the addition of the block copolymer increased extent of cure by 12%. Furthermore, the extent of cure was increased by 29% and 37% with the addition of 25 and 50 wt % PEGDMA, respectively. Elastic modulus and fracture resistance were also determined, and the values indicate that the addition of block copolymers does not significantly toughen the thermoset materials. This finding is surprising when compared with the large increase in fracture resistance seen in block copolymer-modified epoxies, and an explanation is proposed.

  14. Gold Binding by Native and Chemically Modified Hops Biomasses

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    López, M. Laura; Gardea-Torresdey, J. L.; Peralta-Videa, J. R.; de la Rosa, G.; Armendáriz, V.; Herrera, I.; Troiani, H.; Henning, J.

    2005-01-01

    Heavy metals from mining, smelting operations and other industrial processing facilities pollute wastewaters worldwide. Extraction of metals from industrial effluents has been widely studied due to the economic advantages and the relative ease of technical implementation. Consequently, the search for new and improved methodologies for the recovery of gold has increased. In this particular research, the use of cone hops biomass ( Humulus lupulus ) was investigated as a new option for gold recovery. The results showed that the gold binding to native hops biomass was pH dependent from pH 2 to pH 6, with a maximum percentage bindingmore » at pH 3. Time dependency studies demonstrated that Au(III) binding to native and modified cone hops biomasses was found to be time independent at pH 2 while at pH 5, it was time dependent. Capacity experiments demonstrated that at pH 2, esterified hops biomass bound 33.4 mg Au/g of biomass, while native and hydrolyzed hops biomasses bound 28.2 and 12.0 mg Au/g of biomass, respectively. However, at pH 5 the binding capacities were 38.9, 37.8 and 11.4 mg of Au per gram of native, esterified and hydrolyzed hops biomasses, respectively.« less

  15. Modified pseudomonas oleovorans phaC1 nucleic acids encoding bispecific polyhydroxyalkanoate polymerase

    DOE Patents [OSTI]

    Srienc, Friedrich; Jackson, John K.; Somers, David A.

    2000-01-01

    A genetically engineered Pseudomonas oleovorans phaC1 polyhydroxyalkanoate (PHA) polymerase having tailored substrate specificity is provided. The modified PHA polymerase is preferably a "bispecific" PHA polymerase capable of copolymerizing a short chain length monomer and a medium chain length monomer is provided. Methods for making the modified PHA polymerase and for making nucleic acids encoding the modified PHA polymerase are also disclosed, as are methods of producing PHA using the modified PHA polymerase. The invention further includes methods to assay for altered substrate specificity.

  16. Modified T4 Lysozyme Fusion Proteins Facilitate G Protein-Coupled...

    Office of Scientific and Technical Information (OSTI)

    Proteins Facilitate G Protein-Coupled Receptor Crystallogenesis Citation Details In-Document Search Title: Modified T4 Lysozyme Fusion Proteins Facilitate G Protein-Coupled ...

  17. Method of producing titanium-modified austenitic steel having improved swelling resistance

    DOE Patents [OSTI]

    Megusar, Janez; Grant, Nicholas J.

    1989-01-01

    A process for improving the swelling resistance of a titanium-modified austenitic stainless steel that involves a combination of rapid solidification and dynamic compaction techniques.

  18. 01-02-2003 - Hazards from Modifying Finished Products | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hazards from Modifying Finished Products Document Number: NA Effective Date: 01/2003 File (public): PDF icon 01-02-2003(2)

  19. EIS-0407: Amended Notice of Intent to Modify the Scope of the...

    Broader source: Energy.gov (indexed) [DOE]

    Refinery Project near Hugoton, Kansas Amended Notice of Intent to Modify the Scope of the Environmental Impact Statement for the Abengoa Refinery Project near Hugoton, Kanasas,...

  20. Colloidally Synthesized Monodisperse Rh Nanoparticles Supported on SBA-15 for Size- and Pretreatment-Dependent Studies of CO Oxidation

    SciTech Connect (OSTI)

    Grass, Michael E.; Joo, Sang Hoon; Somorjai, Gabor A.

    2009-02-12

    A particle size dependence for CO oxidation over rhodium nanoparticles of 1.9-11.3 nm has been investigated and determined to be modified by the existence of the capping agent poly(vinylpyrrolidone) (PVP). The particles were prepared using a polyol reduction procedure with PVP as the capping agent. The Rh nanoparticles were subsequently supported on SBA-15 during hydrothermal synthesis to produce Rh/SBA-15 supported catalysts for size-dependent catalytic studies. CO oxidation by O{sub 2} at 40 Torr CO and 100 Torr O{sub 2} was investigated over two series of Rh/SBA-15 catalysts: as-synthesized Rh/SBA-15 covering the full range of Rh sizes and the same set of catalysts after high temperature calcination and reduction. The turnover frequency at 443 K increases from 0.4 to 1.7 s{sup -1} as the particle size decreases from 11.3 to 1.9 nm for the as-synthesized catalysts. After calcination and reduction, the turnover frequency is between 0.1 and 0.4 s{sup -1} with no particle size dependence. The apparent activation energy for all catalysts is {approx}30 kcal mol{sup -1} and is independent of particle size and thermal treatment. Infrared spectroscopy of CO on the Rh nanoparticles indicates that the heat treatments used influence the mode of CO adsorption. As a result, the particle size dependence for CO oxidation is altered after calcination and reduction of the catalysts. CO adsorbs at two distinct bridge sites on as-synthesized Rh/SBA-15, attributable to metallic Rh(0) and oxidized Rh(I) bridge sites. After calcination and reduction, however, CO adsorbs only at Rh(0) atop sites. The change in adsorption geometry and oxidation activity may be attributable to the interaction between PVP and the Rh surface. This capping agent affect may open new possibilities for the tailoring of metal catalysts using solution nanoparticle synthesis methods.

  1. Method of controlling crystallite size in nuclear-reactor fuels

    DOE Patents [OSTI]

    Lloyd, Milton H.; Collins, Jack L.; Shell, Sam E.

    1985-01-01

    Improved spherules for making enhanced forms of nuclear-reactor fuels are prepared by internal gelation procedures within a sol-gel operation and are accomplished by first boiling the concentrated HMTA-urea feed solution before engaging in the spherule-forming operation thereby effectively controlling crystallite size in the product spherules.

  2. Method of controlling crystallite size in nuclear-reactor fuels

    DOE Patents [OSTI]

    Lloyd, M.H.; Collins, J.L.; Shell, S.E.

    Improved spherules for making enhanced forms of nuclear-reactor fuels are prepared by internal gelation procedures within a sol-gel operation and are accomplished by first boiling the concentrated HMTA-urea feed solution before engaging in the spherule-forming operation thereby effectively controlling crystallite size in the product spherules.

  3. THE STICKINESS OF MICROMETER-SIZED WATER-ICE PARTICLES

    SciTech Connect (OSTI)

    Gundlach, B.; Blum, J.

    2015-01-01

    Water ice is one of the most abundant materials in dense molecular clouds and in the outer reaches of protoplanetary disks. In contrast to other materials (e.g., silicates), water ice is assumed to be stickier due to its higher specific surface energy, leading to faster or more efficient growth in mutual collisions. However, experiments investigating the stickiness of water ice have been scarce, particularly in the astrophysically relevant micrometer-sized region and at low temperatures. In this work, we present an experimental setup to grow aggregates composed of ?m-sized water-ice particles, which we used to measure the sticking and erosion thresholds of the ice particles at different temperatures between 114 K and 260 K. We show with our experiments that for low temperatures (below ?210 K), ?m-sized water-ice particles stick below a threshold velocity of 9.6 m s{sup 1}, which is approximately 10times higher than the sticking threshold of ?m-sized silica particles. Furthermore, erosion of the grown ice aggregates is observed for velocities above 15.3 m s{sup 1}. A comparison of the experimentally derived sticking threshold with model predictions is performed to determine important material properties of water ice, i.e., the specific surface energy and the viscous relaxation time. Our experimental results indicate that the presence of water ice in the outer reaches of protoplanetary disks can enhance the growth of planetesimals by direct sticking of particles.

  4. Amino resin modified polymer gels for permeability control

    SciTech Connect (OSTI)

    Shu, P.

    1989-03-07

    An aqueous cross-linked gel formed by a polysaccharide polymer, an aminoplast resin, and transitional metal ions is described, comprising: (a) water; (b) about 0.2 to about 5.0 wt. percent of a cross-linkable polysaccharide polymer selected from the group consisting of polysaccharide bipolymers and cellulose derivatives having at least one functional group selected from a member of the group consisting of an amine, an amide, a hydroxyl, or a thiol group; (c) about 0.02 to about 5.0 wt. percent of an aminoplast resin which reinforces the polymer; and (d) sufficient transitional metal ions to form a gel of a size and strength sufficient to close one or more permeable zones in a formation under substantially all pH conditions.

  5. Amino resin modified xanthan polymer gels for permeability profile control

    SciTech Connect (OSTI)

    Shu, P.

    1988-01-05

    A process for closing pores in a hydrocarbonaceous fluid bearing formation to obtain improved sweep efficiency during a water flood oil recovery operation wherein the process comprises injecting into the formation a gellable composition is described comprising: (a) water; (b) about 0.2 to about 5.0 wt. percent of a cross linkable polysaccharide biopolymer having at least one functional group selected from a member of the group consisting of an amine, an amide, a hydroxyl, or a thiol group; (c) about 0.02 to about 5.0 wt. percent of an aminoplast resin which reinforces the biopolymer; and (d) sufficient transitional metal ions to form a gel of a size and strength sufficient to close one or more permeable zones in the formation under substantially all pH conditions.

  6. Silica aerogels modified by functional and nonfunctional organic groups

    SciTech Connect (OSTI)

    Schubert, U.; Huesing, N.; Schwertfeger, F. [Universitaet Wien (Austria)

    1996-12-31

    Organically substituted silica aerogels were prepared from RSi(OR`){sub 3}/Si(OR`){sub 4} mixtures, followed by supercritical drying. The typical microstructure and the resulting physical properties of silica aerogels are retained, if the portion of R-Si units is below 10-20%. However, new properties are supplemented, such as hydrophobicity (which makes the aerogels insensitive towards moisture), a higher compliance, and the possibility to incorporate functional organic groups. Controlled pyrolysis of the organically substituted aerogels allows to coat the inner surface of the aerogels with nanometer-sized carbon structures. This results in a very efficient infrared opacification and improved heat insulation properties at high temperatures. 5 refs., 2 figs.

  7. Screen bowl centrifuge: a high-efficiency particle size separator

    SciTech Connect (OSTI)

    Mohanty, M.K.; Zhang, B.; Khanna, N.; Palit, A.; Dube, B.

    2008-05-15

    Over the years, screen bowl centrifuges have been widely used for dewatering fine coal in coal preparation plants in the United States and elsewhere. It is generally recognized in the engineering and scientific communities that screen bowl centrifuges provide some degree of particle size separation while dewatering fine coal in a common application. However, the extent of differential partitioning of coarse and fine particles achievable by a screen bowl centrifuge has not been systematically studied in the past. The present investigation was aimed at conducting a parametric study using a statistically designed experimental program to better understand and optimize the size classification performance of a screen bowl centrifuge. A continuously operating screen bowl centrifuge having a bowl diameter of 0.5 m was used for this study at the Illinois Coal Development Park. Three key operating parameters, i.e., feed flow rate, feed solid content and pool depth, were varied to conduct a total of 17 experiments using a three-level factorial test matrix. Some of the best size separation performances achieved in this study may be described as having an imperfection value of 0.13 at an effective separation size (d(50c)) of 38 mu m and an imperfection value of 0.27 at an effective separation size (d(50c)) of 2.8 mu m. Due to an effective separation of ultrafine high ash materials, the ash content of the screen bowl feed was reduced from 22.3% to a minimum of 8.84% with a combustible recovery of 84.1% and an ash rejection of 71.6%. A higher combustible recovery of 92.1% was achieved at a product ash content of 12.5% with a d(50c) of 2.8 mu m and imperfection of 0.27.

  8. 2009 Cellulosomes, Cellulases & Other Carbohydrate Modifying Enzymes GRC

    SciTech Connect (OSTI)

    Harry Gilbert

    2009-07-26

    The 2009 Gordon Conference on Cellulosomes, Cellulases & Other Carbohydrate Modifying Enzymes will present cutting-edge research on the enzymatic degradation of cellulose and other plant cell wall polysaccharides. The Conference will feature a wide range of topics that includes the enzymology of plant structural degradation, regulation of the degradative apparatus, the mechanism of protein complex assembly, the genomics of cell wall degrading organisms, the structure of the substrate and the industrial application of the process particularly within the biofuel arena. Indeed the deployment of plant cell wall degrading enzymes in biofuel processes will be an important feature of the meeting. It should be emphasized that the 2009 Conference will be expanded to include, in addition to cellulase research, recent advances in other plant cell wall degrading enzymes, and contributions from people working on hemicellulases and pectinases will be particularly welcome. Invited speakers represent a variety of scientific disciplines, including biochemistry, structural biology, genetics and cell biology. The interplay between fundamental research and its industrial exploitation is a particularly important aspect of the meeting, reflecting the appointment of the chair and vice-chair from academia and industry, respectively. The meeting will provide opportunities for junior scientists and graduate students to present their work in poster format and exchange ideas with more established figures in the field. Indeed, some poster presenters will be selected for short talks. The collegial atmosphere of this Conference, with programmed discussion sessions as well as opportunities for informal gatherings in the afternoons and evenings, provides an avenue for scientists from different disciplines to brainstorm and promotes cross-disciplinary collaborations in the various research areas represented. The Conference is likely to be heavily subscribed so we would recommend that you submit your application/abstract to the GRC web site as soon as possible.

  9. LEACHING OF TITANIUM FROM MONOSODIUM TITANATE AND MODIFIED MST

    SciTech Connect (OSTI)

    Taylor-Pashow, K.; Fondeur, F.; Fink, S.

    2012-08-01

    Analysis of a fouled coalescer and pre-filters from Actinide Removal Process/Modular Caustic Side Solvent Extraction Unit (ARP/MCU) operations showed evidence of Ti containing solids. Based on these results a series of tests were planned to examine the extent of Ti leaching from monosodium titanate (MST) and modified monosodium titanate (mMST) in various solutions. The solutions tested included a series of salt solutions with varying free hydroxide concentrations, two sodium hydroxide concentrations, 9 wt % and 15 wt %, nitric and oxalic acid solutions. Overall, the amount of Ti leached from the MST and mMST was much greater in the acid solutions compared to the sodium hydroxide or salt solutions, which is consistent with the expected trend. The leaching data also showed that increasing hydroxide concentration, whether pure NaOH solution used for filter cleaning in ARP or the waste salt solution, increased the amount of Ti leached from both the MST and mMST. For the respective nominal contact times with the MST solids - for filter cleaning or the normal filter operation, the dissolved Ti concentrations are comparable suggesting either cause may contribute to the increased Ti fouling on the MCU coalescers. Tests showed that Ti containing solids could be precipitated from solution after the addition of scrub acid and a decrease in temperature similar to expected in MCU operations. FTIR analysis of these solids showed some similarity to the solids observed on the fouled coalescer and pre-filters. Although only a cursory study, this information suggests that the practice of increasing free hydroxide in feed solutions to MCU as a mitigation to aluminosilicate formation may be offset by the impact of formation of Ti solids in the overall process. Additional consideration of this finding from MCU and SWPF operation is warranted.

  10. Small cell foams containing a modified dense star polymer or dendrimer as a nucleating agent

    DOE Patents [OSTI]

    Hedstrand, David M.; Tomalia, Donald A.

    1995-01-01

    A small cell foam having a modified dense star polymer or dendrimer is described. This modified dense star polymer or dendrimer has a highly branched interior of one monomeric composition and an exterior structure of a different monomeric composition capable of providing a hydrophobic outer shell and a particle diameter of from about 5 to about 1,000 nm with a matrix polymer.

  11. Small cell foams containing a modified dense star polymer or dendrimer as a nucleating agent

    DOE Patents [OSTI]

    Hedstrand, D.M.; Tomalia, D.A.

    1995-02-28

    A small cell foam having a modified dense star polymer or dendrimer is described. This modified dense star polymer or dendrimer has a highly branched interior of one monomeric composition and an exterior structure of a different monomeric composition capable of providing a hydrophobic outer shell and a particle diameter of from about 5 to about 1,000 nm with a matrix polymer.

  12. Synthesis of 3'-, or 5'-, or internal methacrylamido-modified oligonucleotides

    DOE Patents [OSTI]

    Golova, Julia B.; Chernov, Boris K.

    2010-04-27

    New modifiers were synthesized for incorporation of a methacrylic function in 3'-, 5'- and internal positions of oligonucleotides during solid phase synthesis. A modifier was used for synthesis of 5'-methacrylated oligonucleotides for preparation of microarrays by a co-polymerization method.

  13. Magnetic agglomeration method for size control in the synthesis of magnetic nanoparticles

    DOE Patents [OSTI]

    Huber, Dale L.

    2011-07-05

    A method for controlling the size of chemically synthesized magnetic nanoparticles that employs magnetic interaction between particles to control particle size and does not rely on conventional kinetic control of the reaction to control particle size. The particles are caused to reversibly agglomerate and precipitate from solution; the size at which this occurs can be well controlled to provide a very narrow particle size distribution. The size of particles is controllable by the size of the surfactant employed in the process; controlling the size of the surfactant allows magnetic control of the agglomeration and precipitation processes. Agglomeration is used to effectively stop particle growth to provide a very narrow range of particle sizes.

  14. Table B6. Building Size, Number of Buildings, 1999

    U.S. Energy Information Administration (EIA) Indexed Site

    B6. Building Size, Number of Buildings, 1999" ,"Number of Buildings (thousand)" ,"All Buildings ","Building Size" ,,"1,001 to 5,000 Square Feet","5,001 to 10,000 Square Feet","10,001 to 25,000 Square Feet","25,001 to 50,000 Square Feet","50,001 to 100,000 Square Feet","100,001 to 200,000 Square Feet","200,001 to 500,000 Square Feet","Over 500,000 Square Feet" "All Buildings

  15. DNA fragment sizing and sorting by laser-induced fluorescence

    DOE Patents [OSTI]

    Hammond, Mark L.; Jett, James H.; Keller, Richard A.; Marrone, Babetta L.; Martin, John C.

    1996-01-01

    A method is provided for sizing DNA fragments using high speed detection systems, such as flow cytometry to determine unique characteristics of DNA pieces from a sample. In one characterization the DNA piece is fragmented at preselected sites to produce a plurality of DNA fragments. The DNA piece or the resulting DNA fragments are treated with a dye effective to stain stoichiometrically the DNA piece or the DNA fragments. The fluorescence from the dye in the stained fragments is then examined to generate an output functionally related to the number of nucleotides in each one of the DNA fragments. In one embodiment, the intensity of the fluorescence emissions from each fragment is linearly related to the fragment length. The distribution of DNA fragment sizes forms a characterization of the DNA piece for use in forensic and research applications.

  16. A novel hybrid (wind-photovoltaic) system sizing procedure

    SciTech Connect (OSTI)

    Hocaoglu, Fatih O.; Gerek, Oemer N.; Kurban, Mehmet

    2009-11-15

    Wind-photovoltaic hybrid system (WPHS) utilization is becoming popular due to increasing energy costs and decreasing prices of turbines and photovoltaic (PV) panels. However, prior to construction of a renewable generation station, it is necessary to determine the optimum number of PV panels and wind turbines for minimal cost during continuity of generated energy to meet the desired consumption. In fact, the traditional sizing procedures find optimum number of the PV modules and wind turbines subject to minimum cost. However, the optimum battery capacity is either not taken into account, or it is found by a full search between all probable solution spaces which requires extensive computation. In this study, a novel description of the production/consumption phenomenon is proposed, and a new sizing procedure is developed. Using this procedure, optimum battery capacity, together with optimum number of PV modules and wind turbines subject to minimum cost can be obtained with good accuracy. (author)

  17. Method and apparatus for physical separation of different sized nanostructures

    DOE Patents [OSTI]

    Roberts, Christopher B.; Saunders, Steven R.

    2012-07-10

    The present application provides apparatuses and methods for the size-selective fractionation of ligand-capped nanoparticles that utilizes the tunable thermophysical properties of gas-expanded liquids. The nanoparticle size separation processes are based on the controlled reduction of the solvent strength of an organic phase nanoparticle dispersion through increases in concentration of the antisolvent gas, such as CO.sub.2, via pressurization. The method of nanomaterial separation contains preparing a vessel having a solvent and dispersed nanoparticles, pressurizing the chamber with a gaseous antisolvent, and causing a first amount of the nanoparticles to precipitate, transporting the solution to a second vessel, pressurizing the second vessel with the gaseous antisolvent and causing further nanoparticles to separate from the solution.

  18. Buildings","Building Size"

    U.S. Energy Information Administration (EIA) Indexed Site

    B7. Building Size, Floorspace, 1999" ,"Total Floorspace (million square feet)" ,"All Buildings","Building Size" ,,"1,001 to 5,000 Square Feet","5,001 to 10,000 Square Feet","10,001 to 25,000 Square Feet","25,001 to 50,000 Square Feet","50,001 to 100,000 Square Feet","100,001 to 200,000 Square Feet","200,001 to 500,000 Square Feet","Over 500,000 Square Feet" "All Buildings

  19. Buildings","Building Size"

    U.S. Energy Information Administration (EIA) Indexed Site

    A5. Building Size, Number of Buildings for All Buildings (Including Malls), 2003" ,"Number of Buildings (thousand)" ,"All Buildings","Building Size" ,,"1,001 to 5,000 Square Feet","5,001 to 10,000 Square Feet","10,000 to 25,000 Square Feet","25,001 to 50,000 Square Feet","50,001 to 100,000 Square Feet","100,001 to 200,000 Square Feet","200,001 to 500,000 Square Feet","Over 500,000 Square

  20. Buildings","Building Size"

    U.S. Energy Information Administration (EIA) Indexed Site

    A6. Building Size, Floorspace for All Buildings (Including Malls), 2003" ,"Total Floorspace (million square feet)" ,"All Buildings","Building Size" ,,"1,001 to 5,000 Square Feet","5,001 to 10,000 Square Feet","10,000 to 25,000 Square Feet","25,001 to 50,000 Square Feet","50,001 to 100,000 Square Feet","100,001 to 200,000 Square Feet","200,001 to 500,000 Square Feet","Over 500,000 Square

  1. Buildings*","Building Size"

    U.S. Energy Information Administration (EIA) Indexed Site

    B6. Building Size, Number of Buildings for Non-Mall Buildings, 2003" ,"Number of Buildings (thousand)" ,"All Buildings*","Building Size" ,,"1,001 to 5,000 Square Feet","5,001 to 10,000 Square Feet","10,000 to 25,000 Square Feet","25,001 to 50,000 Square Feet","50,001 to 100,000 Square Feet","100,001 to 200,000 Square Feet","200,001 to 500,000 Square Feet","Over 500,000 Square Feet"

  2. Buildings*","Building Size"

    U.S. Energy Information Administration (EIA) Indexed Site

    B7. Building Size, Floorspace for Non-Mall Buildings, 2003" ,"Total Floorspace (million square feet)" ,"All Buildings*","Building Size" ,,"1,001 to 5,000 Square Feet","5,001 to 10,000 Square Feet","10,000 to 25,000 Square Feet","25,001 to 50,000 Square Feet","50,001 to 100,000 Square Feet","100,001 to 200,000 Square Feet","200,001 to 500,000 Square Feet","Over 500,000 Square Feet"

  3. Method for measuring the size distribution of airborne rhinovirus

    SciTech Connect (OSTI)

    Russell, M.L.; Goth-Goldstein, R.; Apte, M.G.; Fisk, W.J.

    2002-01-01

    About 50% of viral-induced respiratory illnesses are caused by the human rhinovirus (HRV). Measurements of the concentrations and sizes of bioaerosols are critical for research on building characteristics, aerosol transport, and mitigation measures. We developed a quantitative reverse transcription-coupled polymerase chain reaction (RT-PCR) assay for HRV and verified that this assay detects HRV in nasal lavage samples. A quantitation standard was used to determine a detection limit of 5 fg of HRV RNA with a linear range over 1000-fold. To measure the size distribution of HRV aerosols, volunteers with a head cold spent two hours in a ventilated research chamber. Airborne particles from the chamber were collected using an Andersen Six-Stage Cascade Impactor. Each stage of the impactor was analyzed by quantitative RT-PCR for HRV. For the first two volunteers with confirmed HRV infection, but with mild symptoms, we were unable to detect HRV on any stage of the impactor.

  4. Enhanced Nanoparticle Size Control by Extending LaMer's Mechanism

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nanoparticle Size Control by Extending LaMer's Mechanism - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense

  5. Synthesis of micro-sized interconnected Si-C composites

    DOE Patents [OSTI]

    Wang, Donghai; Yi, Ran; Dai, Fang

    2016-02-23

    Embodiments provide a method of producing micro-sized Si--C composites or doped Si--C and Si alloy-C with interconnected nanoscle Si and C building blocks through converting commercially available SiO.sub.x (0

  6. Size and weight graded multi-ply laminar electrodes

    DOE Patents [OSTI]

    Liu, Chia-Tsun; Demczyk, Brian G.; Rittko, Irvin R.

    1984-01-01

    An electrode is made comprising a porous backing sheet, and attached thereto a catalytically active layer having an electrolyte permeable side and a backing layer contacting side, where the active layer comprises a homogeneous mixture of active hydrophobic and hydrophilic agglomerates with catalyst disposed equally throughout the active layer, and where the agglomerate size increases from the electrolyte permeable side to the backing sheet contacting side.

  7. Finite-size instabilities in nuclear energy density functionals

    SciTech Connect (OSTI)

    Hellemans, V.; Heenen, P.-H.; Bender, M.

    2012-10-20

    The systematic lack of convergence of self-consistent mean-field calculations with certain parameterizations of the Skyrme energy density functional has been attributed to the appearance of finite-size instabilities. In this contribution, we investigate what happens at the instability associated with the C{sub 0}{sup {Delta}s}s{sub 0} Dot-Operator {Delta}s{sub 0} term in a high-spin state of the superdeformed band in {sup 194}Hg.

  8. ARM - Publications: Science Team Meeting Documents: Stratocumulus cell size

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and emittance at the ARM TWP Darwin site - implications for observations from CALIPSO Stratocumulus cell size and emittance at the ARM TWP Darwin site - implications for observations from CALIPSO Platt, C. Colorado State University and CSIRO Atmospheric Research Bennett, John CSIRO Atmospheric Research The NASA CALIPSO satellite instrument due to be launched in mid-2005 will carry a two-wavelength polarisation lidar and a scanning filter infrared radiometer viewing in the nadir. Preliminary

  9. Development of Model Filtration Media for Investigating Size-Dependent

    Broader source: Energy.gov (indexed) [DOE]

    Filtration Efficiency | Department of Energy A novel method for fabricating custom porous filtration media for emission control has been developed. Controlled pore sizes could be used to optimize high-capture efficiency with low backpressure. PDF icon p-25_strzelec.pdf More Documents & Publications Fuel-Neutral Studies of Particulate Matter Transport Emissions Fuel-Neutral Studies of Particulate Matter Transport Emissions Diesel Particulate Oxidation Model: Combined Effects of Fixed

  10. Water holding capacities of fly ashes: Effect of size fractionation

    SciTech Connect (OSTI)

    Sarkar, A.; Rano, R.

    2007-07-01

    Water holding capacities of fly ashes from different thermal power plants in Eastern India have been compared. Moreover, the effect of size fractionation (sieving) on the water holding capacities has also been determined. The desorption rate of water held by the fly ash fractions at ambient temperature (25-30{sup o}C) has been investigated. The effect of mixing various size fractions of fly ash in increasing the water holding capacities of fly ash has been studied. It is observed that the fly ash obtained from a thermal power plant working on stoker-fired combustor has the highest water holding capacity, followed by the one that works on pulverized fuel combustor. Fly ash collected from super thermal power plant has the least water holding capacity (40.7%). The coarser size fractions of fly ashes in general have higher water holding capacities than the finer ones. An attempt has been made to correlate the results obtained, with the potential use in agriculture.

  11. Analytical determination of critical crack size in solar cells

    SciTech Connect (OSTI)

    Chen, C.P.

    1988-05-01

    Although solar cells usually have chips and cracks, no material specifications concerning the allowable crack size on solar cells are available for quality assurance and engineering design usage. Any material specifications that the cell manufacturers use were developed for cosmetic reasons that have no technical basis. Therefore, the Applied Solar Energy Corporation (ASEC) has sponsored a continuing program for the fracture mechanics evaluation of GaAs. Fracture mechanics concepts were utilized to develop an analytical model that can predict the critical crack size of solar cells. This model indicates that the edge cracks of a solar cell are more critical than its surface cracks. In addition, the model suggests that the material specifications on the allowable crack size used for Si solar cells should not be applied to GaAs solar cells. The analytical model was applied to Si and GaAs solar cells, but it would also be applicable to the semiconductor wafers of other materials, such as a GaAs thin film on a Ge substrate, using appropriate input data.

  12. Effect of organic solvents on particle size of Mn{sub 3}O{sub 4} nanoparticles synthesized by a solvothermal method

    SciTech Connect (OSTI)

    Song, Rui; Feng, Shouhua; Wang, Hongjun; Hou, Changmin

    2013-06-15

    In this paper, a modified simple solvothermal method is employed to synthesize Mn{sub 3}O{sub 4} nanocrystals using four different solvents: acetone, ethanol, N,N-dimethylformamide (DMF), and dimethyl sulfoxide (DMSO). Mn{sub 3}O{sub 4} nanoparticles with a tetragonal hausmannite nano-structure are characterized by powder X-ray diffraction (XRD), transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), Fourier transform infrared spectroscopy (FTIR), as well as superconducting quantum interference device magnetometer (SQUID). The Mn{sub 3}O{sub 4} particle size is found to have a strong dependency on the solvent used. A reaction scheme is proposed to understand this dependency, suggesting that the solvent coordinating capability has a critical effect on Mn{sub 3}O{sub 4} particle size. The stronger the coordinating capability of the solvent is, the smaller the Mn{sub 3}O{sub 4} particle size is. In addition, magnetic properties of the nano-structured Mn{sub 3}O{sub 4} are also tested and discussed. - Graphical abstract: The comparison of the particle size of Mn{sub 3}O{sub 4} nanoparticles synthesized using different solvents and HRTEM image of Mn{sub 3}O{sub 4} individual nanoparticle revealed its single-crystal nature. - Highlights: • Mn{sub 3}O{sub 4} nanocrystals were synthesized using different solvents by a solvothermal method. • The particle size of Mn{sub 3}O{sub 4} nanocrystal is found to have a strong dependency on the solvent used. • A reaction mechanism is proposed to explain the difference of particle size of Mn{sub 3}O{sub 4} nanocrystals. • Magnetic properties of Mn{sub 3}O{sub 4} nanocrystals with different particle size are tested and compared.

  13. Method for sizing and desizing yarns with liquid and supercritical carbon dioxide solvent

    DOE Patents [OSTI]

    Fulton, J.L.; Yonker, C.R.; Hallen, R.R.; Baker, E.G.; Bowman, L.E.; Silva, L.J.

    1999-01-26

    Disclosed is a method of sizing and desizing yarn, or more specifically to a method of coating yarn with size and removing size from yarn with liquid carbon dioxide solvent. 3 figs.

  14. Method for sizing and desizing yarns with liquid and supercritical carbon dioxide solvent

    DOE Patents [OSTI]

    Fulton, John L. (Richland, WA); Yonker, Clement R. (Richland, WA); Hallen, Richard R. (Richland, WA); Baker, Eddie G. (Richland, WA); Bowman, Lawrence E. (Richland, WA); Silva, Laura J. (Richland, WA)

    1999-01-01

    Disclosed is a method of sizing and desizing yarn, or more specifically to a method of coating yarn with size and removing size from yarn with liquid carbon dioxide solvent.

  15. Improved flywheel materials : characterization of nanofiber modified flywheel test specimen.

    SciTech Connect (OSTI)

    Boyle, Timothy J.; Bell, Nelson Simmons; Ehlen, Mark Andrew; Anderson, Benjamin John; Miller, William Kenneth

    2013-09-01

    As alternative energy generating devices (i.e., solar, wind, etc) are added onto the electrical energy grid (AC grid), irregularities in the available electricity due to natural occurrences (i.e., clouds reducing solar input or wind burst increasing wind powered turbines) will be dramatically increased. Due to their almost instantaneous response, modern flywheel-based energy storage devices can act a mechanical mechanism to regulate the AC grid; however, improved spin speeds will be required to meet the necessary energy levels to balance thesegreen' energy variances. Focusing on composite flywheels, we have investigated methods for improving the spin speeds based on materials needs. The so-called composite flywheels are composed of carbon fiber (C-fiber), glass fiber, and aglue' (resin) to hold them together. For this effort, we have focused on the addition of fillers to the resin in order to improve its properties. Based on the high loads required for standard meso-sized fillers, this project investigated the utility of ceramic nanofillers since they can be added at very low load levels due to their high surface area. The impact that TiO2 nanowires had on the final strength of the flywheel material was determined by athree-point-bend' test. The results of the introduction of nanomaterials demonstrated an increase instrength' of the flywheel's C-fiber-resin moiety, with an upper limit of a 30% increase being reported. An analysis of the economic impact concerning the utilization of the nanowires was undertaken and after accounting for new-technology and additional production costs, return on improved-nanocomposite investment was approximated at 4-6% per year over the 20-year expected service life. Further, it was determined based on the 30% improvement in strength, this change may enable a 20-30% reduction in flywheel energy storage cost (%24/kW-h).

  16. MODIFIED REVERSE OSMOSIS SYSTEM FOR TREATMENT OF PRODUCED WATERS

    SciTech Connect (OSTI)

    T.M. Whitworth; Liangxiong Li

    2002-09-15

    This report describes work performed during the second year of the project ''Modified reverse osmosis system for treatment of produced waters.'' We performed two series of reverse osmosis experiments using very thin bentonite clay membranes compacted to differing degrees. The first series of 10 experiments used NaCl solutions with membranes that ranged between 0.041 and 0.064mm in thickness. Our results showed compaction of such ultra-thin clay membranes to be problematic. The thickness of the membranes was exceeded by the dimensional variation in the machined experimental cell and this is believed to have resulted in local bypassing of the membrane with a resultant decrease in solute rejection efficiency. In two of the experiments, permeate flow was varied as a percentage of the total flow to investigate results of changing permeate flow on solute rejection. In one experiment, the permeate flow was varied between 2.4 and 10.3% of the total flow with no change in solute rejection. In another experiment, the permeate flow was varied between 24.6 and 52.5% of the total flow. In this experiment, the solute rejection rate decreased as the permeate occupied greater fractions of the total flow. This suggests a maximum solute rejection efficiency for these clay membranes for a permeate flow of between 10.3 and 24.6% of the total; flow. Solute rejection was found to decrease with increasing salt concentration and ranged between 62.9% and 19.7% for chloride and between 61.5 and 16.8% for sodium. Due to problems with the compaction procedure and potential membrane bypassing, these rejection rates are probably not the upper limit for NaCl rejection by bentonite membranes. The second series of four reverse osmosis experiments was conducted with a 0.057mm-thick bentonite membrane and dilutions of a produced water sample with an original TDS of 196,250 mg/l obtained from a facility near Loco Hill, New Mexico, operated by an independent. These experiments tested the separation efficiency of the bentonite membrane for each of the dilutions. We found that membrane efficiency decreased with increasing solute concentration and with increasing TDS. The rejection of SO{sub 4}{sup 2-} was greater than Cl{sup -}. This may be because the SO{sub 4}{sup 2-} concentration was much lower than the Cl{sup -} concentration in the waters tested. The cation rejection sequence varied with solute concentration and TDS. The solute rejection sequence for multi-component solutions is difficult to predict for synthetic membranes; it may not be simple for clay membranes either. The permeate flows in our experiments were 4.1 to 5.4% of the total flow. This suggests that very thin clay membranes may be useful for some separations. Work on development of a spiral-wound clay membrane module found that it is difficult to maintain compaction of the membrane if the membrane is rolled and then inserted in the outer tube. A different design was tried using a cylindrical clay membrane and this also proved difficult to assemble with adequate membrane compaction. The next step is to form the membrane in place using hydraulic pressure on a thin slurry of clay in either water or a nonpolar organic solvent such as ethanol. Technology transfer efforts included four manuscripts submitted to peer-reviewed journals, two abstracts, and chairing a session on clays as membranes at the Clay Minerals Society annual meeting.

  17. MODIFIED REVERSE OSMOSIS SYSTEM FOR TREATMENT OF PRODUCED WATERS

    SciTech Connect (OSTI)

    T.M. Whitworth; Liangxiong Li

    2002-09-15

    This report describes work performed during the first year of the project ''Modified Reverse Osmosis System for Treatment of Produced Waters.'' This research project has two objectives. The first objective is to test the use of clay membranes in the treatment of produced waters by reverse osmosis. The second objective is to test the ability of a system patented by the New Mexico Tech Research Foundation to remove salts from reverse osmosis waste streams as a solid. We performed 12 experiments using clay membranes in cross-flow experimental cells. We found that, due to dispersion in the porous frit used adjacent to the membrane, the concentration polarization layer seems to be completely (or nearly completely) destroyed at low flow rates. This observation suggests that clay membranes used with porous frit material many reach optimum rejection rates at lower pumping rates than required for use with synthetic membranes. The solute rejection efficiency decreases with increasing solution concentration. For the membranes and experiments reported here, the rejection efficiency ranged from 71% with 0.01 M NaCl solution down to 12% with 2.3 M NaCl solution. More compacted clay membranes will have higher rejection capabilities. The clay membranes used in our experiments were relatively thick (approximately 0.5 mm). The active layer of most synthetic membranes is only 0.04 {micro}m (0.00004 mm), approximately 1250 times thinner than the clay membranes used in these experiments. Yet clay membranes as thin as 12 {micro}m have been constructed (Fritz and Eady, 1985). Since Darcy's law states that the flow through a material of constant permeability is inversely proportional to it's the material's thickness, then, based on these experimental observations, a very thin clay membrane would be expected to have much higher flow rates than the ones used in these experiments. Future experiments will focus on testing very thin clay membranes. The membranes generally exhibited reasonable stable rejection rates over time for chloride for a range of concentrations between 0.01 and 2.5 M. One membrane ran in excess of three months with no apparent loss of usability. This suggests that clay membranes may have a long useable life. Twenty different hyperfiltration-induced solute precipitation experiments were either attempted or completed and are reported here. The results of these experiments suggest that hyperfiltration-induced solute precipitation is possible, even for very soluble substances such as NaCl. However, the precipitation rates obtained in the laboratory do not appear to be adequate for commercial application at this time. Future experiments will focus on making the clay membranes more compact and thinner in order to obtain higher flux rates. Two alternative methods of removing solutes from solution, for which the New Mexico Tech Research Foundation is preparing patent applications, are also being investigated. These methods will be described in the next annual report after the patent applications are filed. Technology transfer efforts included two meetings (one in Farmington NM, and one in Hobbs, NM) where the results of this research were presented to independent oil producers and other interested parties. In addition, members of the research team gave seven presentations concerning this research and because of this research project T. M. (Mike) Whitworth was asked to sit on the advisory board for development of a new water treatment facility for the City of El Paso, Texas. Several papers are in preparation for submission to peer-reviewed journals based on the data presented in this report.

  18. Mechanistic study of methanol synthesis from CO₂ and H₂ on a modified

    Office of Scientific and Technical Information (OSTI)

    model Mo₆S₈ cluster (Journal Article) | SciTech Connect Mechanistic study of methanol synthesis from CO₂ and H₂ on a modified model Mo₆S₈ cluster Citation Details In-Document Search Title: Mechanistic study of methanol synthesis from CO₂ and H₂ on a modified model Mo₆S₈ cluster We report the methanol synthesis from CO₂ and H₂ on metal (M = K, Ti, Co, Rh, Ni, and Cu)-modified model Mo₆S₈ catalyst using density functional theory (DFT). The results show that the

  19. Modifying the response of Ehrlich ascites tumor cells to nitrogen mustard

    Office of Scientific and Technical Information (OSTI)

    (HN/sub 2/) by vincristine, Ca and liposomes (Conference) | SciTech Connect Conference: Modifying the response of Ehrlich ascites tumor cells to nitrogen mustard (HN/sub 2/) by vincristine, Ca and liposomes Citation Details In-Document Search Title: Modifying the response of Ehrlich ascites tumor cells to nitrogen mustard (HN/sub 2/) by vincristine, Ca and liposomes Though vincristine (0.5mg/kg) has no significant carcinostatic effect on Ehrlich ascites tumor cells, it does modify the

  20. Testing the Time-Reversal Modified Universality of the Sivers Function

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Testing the Time-Reversal Modified Universality of the Sivers Function Citation Details In-Document Search Title: Testing the Time-Reversal Modified Universality of the Sivers Function We derive the time-reversal modified universality for both quark and gluon Sivers functions from the parity and time-reversal invariance of QCD. We calculate the single transverse-spin asymmetry of inclusive lepton from the decay of W bosons in polarized proton-proton

  1. Table B10. Employment Size Category, Number of Buildings, 1999

    U.S. Energy Information Administration (EIA) Indexed Site

    0. Employment Size Category, Number of Buildings, 1999" ,"Number of Buildings (thousand)" ,"All Buildings","Number of Workers" ,,"Fewer than 5 Workers","5 to 9 Workers","10 to 19 Workers","20 to 49 Workers","50 to 99 Workers","100 to 249 Workers","250 or More Workers" "All Buildings ................",4657,2376,807,683,487,174,90,39 "Building Floorspace" "(Square

  2. Micro-size gas turbines create market opportunities

    SciTech Connect (OSTI)

    Scott, W.G.

    1997-09-01

    Power plants in the 25 to 250 kW-size range will enable utilities, IPPs and ESCOs to provide economic power for a variety of applications. Small, low-cost, highly efficient gas turbines provide the utility industry with a four-generation technology that features numerous benefits and potential applications. These include firm power to isolated communities, commercial centers and industries; peak shaving for utility systems to reduce the incremental cost of additional loads; peak shaving for large commercial and industrial establishments to reduce demand charges, as well as standby, emergency power and uninterruptible power supply (UPS).

  3. Ductility and work hardening in nano-sized metallic glasses

    SciTech Connect (OSTI)

    Chen, D. Z.; Gu, X. W.; An, Q.; Goddard, W. A.; Greer, J. R.

    2015-02-09

    In-situ nano-tensile experiments on 70 nm-diameter free-standing electroplated NiP metallic glass nanostructures reveal tensile true strains of ∼18%, an amount comparable to compositionally identical 100 nm-diameter focused ion beam samples and ∼3 times greater than 100 nm-diameter electroplated samples. Simultaneous in-situ observations and stress-strain data during post-elastic deformation reveal necking and work hardening, features uncharacteristic for metallic glasses. The evolution of free volume within molecular dynamics-simulated samples suggests a free surface-mediated relaxation mechanism in nano-sized metallic glasses.

  4. Size reduction techniques for vital compliant VHDL simulation models

    DOE Patents [OSTI]

    Rich, Marvin J.; Misra, Ashutosh

    2006-08-01

    A method and system select delay values from a VHDL standard delay file that correspond to an instance of a logic gate in a logic model. Then the system collects all the delay values of the selected instance and builds super generics for the rise-time and the fall-time of the selected instance. Then, the system repeats this process for every delay value in the standard delay file (310) that correspond to every instance of every logic gate in the logic model. The system then outputs a reduced size standard delay file (314) containing the super generics for every instance of every logic gate in the logic model.

  5. Neutrons measure phase behavior in pores at Angstrom size

    SciTech Connect (OSTI)

    Bardoel, Agatha A; Melnichenko, Yuri B

    2012-01-01

    Researchers have measured the phase behavior of green house gases in pores at the Angstrom-level, using small angle neutron scattering (SANS) at the Oak Ridge National Laboratory's High Flux Isotope Reactor. Yuri Melnichenko, an instrument scientist on the General Purpose Small Angle Neutron Scattering (GP SANS) Diffractometer at ORNL's High Flux Isotope Reactor, his postdoctoral associate Lilin He and collaborators Nidia Gallego and Cristian Contescu from the Material Sciences Division (ORNL) were engaged in the work. They were studying nanoporous carbons to assess their attractiveness as storage media for hydrogen, with a view to potential use for on-board hydrogen storage for transportation applications. Nanoporous carbons can also serve as electrode material for supercapacitors and batteries. The researchers successfully determined that the most efficiently condensing pore size in a carbon nanoporous material for hydrogen storage is less than one nanometer. In a paper recently published by the Journal of the American Chemical Society, the collaborators used small angle neutron scattering to study how hydrogen condenses in small pores at ambient temperature. They discovered that the surface-molecule interactions create internal pressures in pores that may exceed the external gas pressure by a factor of up to 50. 'This is an exciting result,' Melnichenko said, 'as you achieve extreme densification in pores 'for free', i.e. without spending any energy. These results can be used to guide the development of new carbon adsorbents tailored to maximize hydrogen storage capacities.' Another important factor that defines the adsorption capacity of sub-nanometer pores is their shape. In order to get accurate structural information and maximize sorption capacity, it is important that pores are small and of approximately uniform size. In collaboration with Drexel University's Yury Gogotsi who supplied the samples, Melnichenko and his collaborators used the GP SANS instrument to study how the size and shape of pores in sub-nanometer porous carbons varies, depending on the manufacturing conditions. While small angle X-ray scattering (SAXS) can do the job too, Melnichenko says, the SANS method broke new ground in analyzing the shape and behavior of pores at subnanometer size, when subjected to varying synthesis temperature. 'We found that these very small pores are in fact spherical, and that when we change the synthesis conditions, they become elongated, even 'slit-like', and all of this on a subnanometer scale,' Melnichenko said.

  6. The intrinsic two-dimensional size of Sagittarius A*

    SciTech Connect (OSTI)

    Bower, Geoffrey C.; Markoff, Sera; Brunthaler, Andreas; Falcke, Heino; Law, Casey; Maitra, Dipankar; Clavel, M.; Goldwurm, A.; Morris, M. R.; Witzel, Gunther; Meyer, Leo; Ghez, A. M.

    2014-07-20

    We report the detection of the two-dimensional structure of the radio source associated with the Galactic Center black hole, Sagittarius A*, obtained from Very Long Baseline Array observations at a wavelength of 7 mm. The intrinsic source is modeled as an elliptical Gaussian with major-axis size 35.4 12.6 R{sub S} in position angle 95 east of north. This morphology can be interpreted in the context of both jet and accretion disk models for the radio emission. There is supporting evidence in large angular-scale multi-wavelength observations for both source models for a preferred axis near 95. We also place a maximum peak-to-peak change of 15% in the intrinsic major-axis size over five different epochs. Three observations were triggered by detection of near infrared (NIR) flares and one was simultaneous with a large X-ray flare detected by NuSTAR. The absence of simultaneous and quasi-simultaneous flares indicates that not all high energy events produce variability at radio wavelengths. This supports the conclusion that NIR and X-ray flares are primarily due to electron excitation and not to an enhanced accretion rate onto the black hole.

  7. Size-dependent structure of silver nanoparticles under high pressure

    SciTech Connect (OSTI)

    Koski, Kristie Jo

    2008-12-31

    Silver noble metal nanoparticles that are<10 nm often possess multiply twinned grains allowing them to adopt shapes and atomic structures not observed in bulk materials. The properties exhibited by particles with multiply twinned polycrystalline structures are often far different from those of single-crystalline particles and from the bulk. I will present experimental evidence that silver nanoparticles<10 nm undergo a reversible structural transformation under hydrostatic pressures up to 10 GPa. Results for nanoparticles in the intermediate size range of 5 to 10 nm suggest a reversible linear pressure-dependent rhombohedral distortion which has not been previously observed in bulk silver. I propose a mechanism for this transitiion that considers the bond-length distribution in idealized multiply twinned icosahedral particles. Results for nanoparticles of 3.9 nm suggest a reversible linear pressure-dependent orthorhombic distortion. This distortion is interpreted in the context of idealized decahedral particles. In addition, given these size-dependent measurements of silver nanoparticle compression with pressure, we have constructed a pressure calibration curve. Encapsulating these silver nanoparticles in hollow metal oxide nanospheres then allows us to measure the pressure inside a nanoshell using x-ray diffraction. We demonstrate the measurement of pressure gradients across nanoshells and show that these nanoshells have maximum resolved shear strengths on the order of 500 MPa to IGPa.

  8. Compressor Selection and Equipment Sizing for Cold Climate Heat Pumps

    SciTech Connect (OSTI)

    Shen, Bo; Abdelaziz, Omar; Rice, C Keith

    2014-01-01

    In order to limit heating capacity degradation at -25 C (-13 F) ambient to 25%, compared to the nominal rating point capacity at 8.3 C (47 F), an extensive array of design and sizing options were investigated, based on fundamental equipment system modeling and building energy simulation. Sixteen equipment design options were evaluated in one commercial building and one residential building, respectively in seven cities. The energy simulation results were compared to three baseline cases: 100% electric resistance heating, a 9.6 HSPF single-speed heat pump unit, and 90% AFUE gas heating system. The general recommendation is that variable-speed compressors and tandem compressors, sized such that their rated heating capacity at a low speed matching the building design cooling load, are able to achieve the capacity goal at low ambient temperatures by over-speeding, for example, a home with a 3.0 ton design cooling load, a tandem heat pump could meet this cooling load running a single compressor, while running both compressors to meet heating load at low ambient temperatures in a cold climate. Energy savings and electric resistance heat reductions vary with building types, energy codes and climate zones. Oversizing a heat pump can result in larger energy saving in a less energy efficient building and colder regions due to reducing electric resistance heating. However, in a more energy-efficient building or for buildings in warmer climates, one has to consider balance between reduction of resistance heat and addition of cyclic loss.

  9. Method of assembly of molecular-sized nets and scaffolding

    DOE Patents [OSTI]

    Michl, Josef; Magnera, Thomas F.; David, Donald E.; Harrison, Robin M.

    1999-01-01

    The present invention relates to methods and starting materials for forming molecular-sized grids or nets, or other structures based on such grids and nets, by creating molecular links between elementary molecular modules constrained to move in only two directions on an interface or surface by adhesion or bonding to that interface or surface. In the methods of this invention, monomers are employed as the building blocks of grids and more complex structures. Monomers are introduced onto and allowed to adhere or bond to an interface. The connector groups of adjacent adhered monomers are then polymerized with each other to form a regular grid in two dimensions above the interface. Modules that are not bound or adhered to the interface are removed prior to reaction of the connector groups to avoid undesired three-dimensional cross-linking and the formation of non-grid structures. Grids formed by the methods of this invention are useful in a variety of applications, including among others, for separations technology, as masks for forming regular surface structures (i.e., metal deposition) and as templates for three-dimensional molecular-sized structures.

  10. Method of assembly of molecular-sized nets and scaffolding

    DOE Patents [OSTI]

    Michl, J.; Magnera, T.F.; David, D.E.; Harrison, R.M.

    1999-03-02

    The present invention relates to methods and starting materials for forming molecular-sized grids or nets, or other structures based on such grids and nets, by creating molecular links between elementary molecular modules constrained to move in only two directions on an interface or surface by adhesion or bonding to that interface or surface. In the methods of this invention, monomers are employed as the building blocks of grids and more complex structures. Monomers are introduced onto and allowed to adhere or bond to an interface. The connector groups of adjacent adhered monomers are then polymerized with each other to form a regular grid in two dimensions above the interface. Modules that are not bound or adhered to the interface are removed prior to reaction of the connector groups to avoid undesired three-dimensional cross-linking and the formation of non-grid structures. Grids formed by the methods of this invention are useful in a variety of applications, including among others, for separations technology, as masks for forming regular surface structures (i.e., metal deposition) and as templates for three-dimensional molecular-sized structures. 9 figs.

  11. Particle impactor assembly for size selective high volume air sampler

    DOE Patents [OSTI]

    Langer, Gerhard

    1988-08-16

    Air containing entrained particulate matter is directed through a plurality of parallel, narrow, vertically oriented impactor slots of an inlet element toward an adjacently located, relatively large, dust impaction surface preferably covered with an adhesive material. The air flow turns over the impaction surface, leaving behind the relatively larger particles according to the human thoracic separation system and passes through two elongate exhaust apertures defining the outer bounds of the impaction collection surface to pass through divergent passages which slow down and distribute the air flow, with entrained smaller particles, over a fine filter element that separates the fine particles from the air. The elongate exhaust apertures defining the impaction collection surface are spaced apart by a distance greater than the lengths of elongate impactor slots in the inlet element and are oriented to be normal thereto. By appropriate selection of dimensions and the number of impactor slots air flow through the inlet element is provided a nonuniform velocity distribution with the lower velocities being obtained near the center of the impactor slots, in order to separate out particles larger than a certain predetermined size on the impaction collection surface. The impaction collection surface, even in a moderately sized apparatus, is thus relatively large and permits the prolonged sampling of air for periods extending to four weeks.

  12. High-nitrogen-metal complexes as burning-rate modifiers for the aluminum-water propellant system

    SciTech Connect (OSTI)

    Tappan, Bryce C; Mason, Benjamin A

    2009-01-01

    The reactions of electropositive metals, such as aluminum, with water have long been utilized in explosive and propellant formulations, but until recently this has mostly been limited to the water formed as a product gas from the decomposition of another energetic system . Recently, however, with the increased availability of nano-particulate materials, the direct reaction of nano-aluminum (nAl) with water as an oxidizer has been investigated as a propellant system due to high reaction temperatures and the production of hydrogen as the primary gaseous species. This system could be useful for intra-planetary travel where non-terrestrial water is harvested for the oxidizer. Here we present the study of nAl, mixed at a stoichiometric ratio with water ({Phi} = 1) with the highly water soluble metal complexes of bis(tetrazolato)amine (BTA) added at 5, 15,30 and 50 wt% in the case of FeBTA and 5 and 15 wt% in the case of NiBTA and CoBTA. The basic structure of the BTA complexes is shown below where M = Fe, Ni or Co, and x = 3 for Fe and Co and x = 2 for Ni. The particle size of nAl studied was primarily 38 nm with various studies with the particle size of 80 nm. The FeBT A at a loading of 15 wt% gave the highest burning rate enhancement (4.6x at {approx}6.8 MPa), while retaining a low pressure exponent (0.21 compared to 0.24 for nA/H{sub 2}O). At 15 wt% the Ni and Co increased the burning rate, but also increased the pressure exponents. The burning rate of the FeBTA modified material with 80 nm Al decreased as the weight percent of FeBTA was increased, which also tracked decrease in the calculated specific impulse of the mixtures.

  13. Structure and Electrochemistry of Vanadium-Modified LiFePO4 ...

    Office of Scientific and Technical Information (OSTI)

    Citation Details In-Document Search Title: Structure and Electrochemistry of Vanadium-Modified LiFePO4 Authors: Hong, Jian ; Wang, Xiao-Liang ; Wang, Qi ; Omenya, Fredrick O. ; ...

  14. Efficient inverted polymer solar cells based on conjugated polyelectrolyte and zinc oxide modified ITO electrode

    SciTech Connect (OSTI)

    Yuan, Tao; Zhu, Xiaoguang; Tu, Guoli; Zhou, Lingyu; Zhang, Jian

    2015-02-23

    Efficient inverted polymer solar cells (PSCs) were constructed by utilizing a conjugated polyelectrolyte PF{sub EO}SO{sub 3}Na and zinc oxide to modify the indium tin oxide (ITO) electrode. The ITO electrode modified by PF{sub EO}SO{sub 3}Na and zinc oxide possesses high transparency, increased electron mobility, smoothened surface, and lower work function. PTB7:PC{sub 71}BM inverted PSCs containing the modified ITO electrode achieved a high power conversion efficiency (PCE) of 8.49%, exceeding that of the control device containing a ZnO modified ITO electrode (7.48%). Especially, PCE-10:PC{sub 71}BM inverted polymer solar cells achieved a high PCE up to 9.4%. These results demonstrate a useful approach to improve the performance of inverted polymer solar cells.

  15. Polymer blend containing a modified dense star polymer or dendrimer and a matrix polymer

    DOE Patents [OSTI]

    Hedstrand, D.M.; Tomalia, D.A.

    1995-02-28

    Dense star polymers or dendrimers, modified by capping with a hydrophobic group capable of providing a hydrophobic outer shell, act as molecular nucleating agents in forming a polymer blend.

  16. Polymer blend containing a modified dense star polymer or dendrimer and a matrix polymer

    DOE Patents [OSTI]

    Hedstrand, David M.; Tomalia, Donald A.

    1995-01-01

    Dense star polymers or dendrimers, modified by capping with a hydrophobic group capable of providing a hydrophobic outer shell, act as molecular nucleating agents in forming a polymer blend.

  17. EIS-0283-S2: Amended Notice of Intent to Modify the Scope of...

    Energy Savers [EERE]

    For more information on this project, see the project webpage: http:energy.govnode299815. Download Document PDF icon EIS-0283-S2: Amended Notice of Intent to Modify the...

  18. EIS-0283-S2: Amended Notice of Intent to Modify the Scope of...

    Broader source: Energy.gov (indexed) [DOE]

    For more information on this project, see the project webpage: http:energy.govnode299815. Download Document EIS-0283-S2: Amended Notice of Intent to Modify the Scope of...

  19. System configured for applying a modifying agent to a non-equidimensional substrate

    DOE Patents [OSTI]

    Janikowski; Stuart K. , Argyle; Mark D. , Fox; Robert V. , Propp; W. Alan , Toth; William J. , Ginosar; Daniel M. , Allen; Charles A. , Miller; David L.

    2007-07-10

    The present invention is related to systems and methods for modifying various non-equidimensional substrates with modifying agents. The system comprises a processing chamber configured for passing the non-equidimensional substrate therethrough, wherein the processing chamber is further configured to accept a treatment mixture into the chamber during movement of the non-equidimensional substrate through the processing chamber. The treatment mixture can comprise of the modifying agent in a carrier medium, wherein the carrier medium is selected from the group consisting of a supercritical fluid, a near-critical fluid, a superheated fluid, a superheated liquid, and a liquefied gas. Thus, the modifying agent can be applied to the non-equidimensional substrate upon contact between the treatment mixture and the non-equidimensional substrate.

  20. System configured for applying a modifying agent to a non-equidimensional substrate

    DOE Patents [OSTI]

    Janikowski, Stuart K.; Toth, William J.; Ginosar, Daniel M.; Allen, Charles A.; Argyle, Mark D.; Fox, Robert V.; Propp, W. Alan; Miller, David L.

    2003-09-23

    The present invention is related to systems and methods for modifying various non-equidimensional substrates with modifying agents. The system comprises a processing chamber configured for passing the non-equidimensional substrate therethrough, wherein the processing chamber is further configured to accept a treatment mixture into the chamber during movement of the non-equidimensional substrate through the processing chamber. The treatment mixture can comprise of the modifying agent in a carrier medium, wherein the carrier medium is selected from the group consisting of a supercritical fluid, a near-critical fluid, a superheated fluid, a superheated liquid, and a liquefied gas. Thus, the modifying agent can be applied to the non-equidimensional substrate upon contact between the treatment mixture and the non-equidimensional substrate.

  1. Modified Anti-de-Sitter Metric, Light-Front Quantized QCD, and...

    Office of Scientific and Technical Information (OSTI)

    Modified Anti-de-Sitter Metric, Light-Front Quantized QCD, and Conformal Quantum Mechanics Dosch, Hans Gunter; U. Heidelberg, ITP; Brodsky, Stanley J.; SLAC; de Teramond, Guy F.;...

  2. EIS-0463: Amended Notice of Intent To Modify the Scope of the...

    Office of Environmental Management (EM)

    of the EIS and Conduct Additional Public Scoping Meetings, Notice of Floodplains and Wetlands Involvement EIS-0463: Amended Notice of Intent To Modify the Scope of the EIS and...

  3. T-606: Sun Java System Access Manager Lets Remote Users Partially Modify Data and Remote Authenticated Users Partially Access Data

    Broader source: Energy.gov [DOE]

    Sun Java System Access Manager Lets Remote Users Partially Modify Data and Remote Authenticated Users Partially Access Data.

  4. Modified T4 Lysozyme Fusion Proteins Facilitate G Protein-Coupled Receptor

    Office of Scientific and Technical Information (OSTI)

    Crystallogenesis (Journal Article) | SciTech Connect Modified T4 Lysozyme Fusion Proteins Facilitate G Protein-Coupled Receptor Crystallogenesis Citation Details In-Document Search Title: Modified T4 Lysozyme Fusion Proteins Facilitate G Protein-Coupled Receptor Crystallogenesis Authors: Thorsen, Thor Seneca ; Matt, Rachel ; Weis, William I. ; Kobilka, Brian K. [1] + Show Author Affiliations (Stanford-MED) Publication Date: 2014-11-01 OSTI Identifier: 1182298 Resource Type: Journal Article

  5. CHARACTERIZATION OF NEAR NET-SHAPE CASTABLE RARE EARTH MODIFIED ALUMINUM

    Office of Scientific and Technical Information (OSTI)

    ALLOYS FOR HIGH TEMPERATURE APPLICATION (Conference) | SciTech Connect Conference: CHARACTERIZATION OF NEAR NET-SHAPE CASTABLE RARE EARTH MODIFIED ALUMINUM ALLOYS FOR HIGH TEMPERATURE APPLICATION Citation Details In-Document Search Title: CHARACTERIZATION OF NEAR NET-SHAPE CASTABLE RARE EARTH MODIFIED ALUMINUM ALLOYS FOR HIGH TEMPERATURE APPLICATION Authors: Sims, Zachary C [1] ; Rios, Orlando [1] ; McCall, S. K. [2] ; Ott, Dr. Ryan T. [3] ; Van Buuren, Tony [2] + Show Author Affiliations

  6. A modified post damping ring bunch compressor beamline for the TESLA linear collider

    SciTech Connect (OSTI)

    Philippe R.-G. Piot; Winfried Decking

    2004-03-23

    We propose a modified bunch compressor beamline, downstream of the damping ring, for the TESLA linear collider. This modified beamline uses a third harmonic radio-frequency section based on the 3.9 GHz superconducting cavity under development at Fermilab. In our design the beam deceleration is about {approx}50 MeV instead of {approx}450 MeV in the original design proposed.

  7. Cuprous-chloride-modified nanoporous alumina membranes for ethylene-ethane separation

    SciTech Connect (OSTI)

    Lin, Y.S.; Wang, Y.; Ji, W.; Higgins, R.J.

    1999-06-01

    This paper reports an attempt to synthesize a CuCl-modified {gamma}-alumina membrane for separation of ethylene from ethane. CuCl was effectively coated in the 4 nm pore {gamma}-alumina top layers of disk-shaped and tubular alumina membranes by the reservoir method. Permeation of a single gas and binary mixture of ethylene and ethane was measured to characterize separation properties of the modified membranes. Pure ethylene permeance of the CuCl-modified membrane is 10--40% lower than that predicted from the pure ethane permeance by the Knudsen theory. This result is explained by a model based on the adsorbed layer of ethylene via {pi}-complexation. Such an adsorbed layer hinders the diffusion of ethylene in the nanopores of CuCl-modified {gamma}-alumina. Multiple gas permeation measurements on the CuCl-modified membranes show a separation factor for ethylene over ethane larger than the Knudsen value. This confirms a positive contribution of the surface flow of ethylene to the permeance of ethylene in the multiple gas permeation system. A maximum separation factor for ethylene over ethane of 1.4 is obtained for the CuCl-modified membrane at 60 C.

  8. Strengthening of metallic alloys with nanometer-size oxide dispersions

    DOE Patents [OSTI]

    Flinn, J.E.; Kelly, T.F.

    1999-06-01

    Austenitic stainless steels and nickel-base alloys containing, by wt. %, 0.1 to 3.0% V, 0.01 to 0.08% C, 0.01 to 0.5% N, 0.05% max. each of Al and Ti, and 0.005 to 0.10% O, are strengthened and ductility retained by atomization of a metal melt under cover of an inert gas with added oxygen to form approximately 8 nanometer-size hollow oxides within the alloy grains and, when the alloy is aged, strengthened by precipitation of carbides and nitrides nucleated by the hollow oxides. Added strengthening is achieved by nitrogen solid solution strengthening and by the effect of solid oxides precipitated along and pinning grain boundaries to provide temperature-stabilization and refinement of the alloy grains. 20 figs.

  9. Medium-size high-temperature gas-cooled reactor

    SciTech Connect (OSTI)

    Peinado, C.O.; Koutz, S.L.

    1980-08-01

    This report summarizes high-temperature gas-cooled reactor (HTGR) experience for the 40-MW(e) Peach Bottom Nuclear Generating Station of Philadelphia Electric Company and the 330-MW(e) Fort St. Vrain Nuclear Generating Station of the Public Service Company of Colorado. Both reactors are graphite moderated and helium cooled, operating at approx. 760/sup 0/C (1400/sup 0/F) and using the uranium/thorium fuel cycle. The plants have demonstrated the inherent safety characteristics, the low activation of components, and the high efficiency associated with the HTGR concept. This experience has been translated into the conceptual design of a medium-sized 1170-MW(t) HTGR for generation of 450 MW of electric power. The concept incorporates inherent HTGR safety characteristics (a multiply redundant prestressed concrete reactor vessel (PCRV), a graphite core, and an inert single-phase coolant) and engineered safety features (core auxiliary cooling, relief valve, and steam generator dump systems).

  10. Strengthening of metallic alloys with nanometer-size oxide dispersions

    DOE Patents [OSTI]

    Flinn, John E. (Idaho Falls, ID); Kelly, Thomas F. (Madison, WI)

    1999-01-01

    Austenitic stainless steels and nickel-base alloys containing, by wt. %, 0.1 to 3.0% V, 0.01 to 0.08% C, 0.01 to 0.5% N, 0.05% max. each of Al and Ti, and 0.005 to 0.10% O, are strengthened and ductility retained by atomization of a metal melt under cover of an inert gas with added oxygen to form approximately 8 nanometer-size hollow oxides within the alloy grains and, when the alloy is aged, strengthened by precipitation of carbides and nitrides nucleated by the hollow oxides. Added strengthening is achieved by nitrogen solid solution strengthening and by the effect of solid oxides precipitated along and pinning grain boundaries to provide temperature-stabilization and refinement of the alloy grains.

  11. Oscillating magnetocaloric effect in size-quantized diamagnetic film

    SciTech Connect (OSTI)

    Alisultanov, Z. Z.

    2014-03-21

    We investigate the oscillating magnetocaloric effect on a size-quantized diamagnetic film in a transverse magnetic field. We obtain the analytical expression for the thermodynamic potential in case of the arbitrary spectrum of carriers. The entropy change is shown to be the oscillating function of the magnetic field and the film thickness. The nature of this effect is the same as for the de Haas–van Alphen effect. The magnetic part of entropy has a maximal value at some temperature. Such behavior of the entropy is not observed in magneto-ordered materials. We discuss the nature of unusual behavior of the magnetic entropy. We compare our results with the data obtained for 2D and 3D cases.

  12. Size-exclusion chromatography system for macromolecular interaction analysis

    DOE Patents [OSTI]

    Stevens, Fred J.

    1988-01-01

    A low pressure, microcomputer controlled system employing high performance liquid chromatography (HPLC) allows for precise analysis of the interaction of two reversibly associating macromolecules such as proteins. Since a macromolecular complex migrates faster than its components during size-exclusion chromatography, the difference between the elution profile of a mixture of two macromolecules and the summation of the elution profiles of the two components provides a quantifiable indication of the degree of molecular interaction. This delta profile is used to qualitatively reveal the presence or absence of significant interaction or to rank the relative degree of interaction in comparing samples and, in combination with a computer simulation, is further used to quantify the magnitude of the interaction in an arrangement wherein a microcomputer is coupled to analytical instrumentation in a novel manner.

  13. Energy Efficiency Services Sector: Workforce Size and Expectations for Growth

    SciTech Connect (OSTI)

    Goldman, Charles; Fuller, Merrian C.; Stuart, Elizabeth; Peters, Jane S.; McRae, Marjorie; Albers, Nathaniel; Lutzenhiser, Susan; Spahic, Mersiha

    2010-03-22

    The energy efficiency services sector (EESS) is poised to become an increasingly important part of the U.S. economy. Climate change and energy supply concerns, volatile and increasing energy prices, and a desire for greater energy independence have led many state and national leaders to support an increasingly prominent role for energy efficiency in U.S. energy policy. The national economic recession has also helped to boost the visibility of energy efficiency, as part of a strategy to support economic recovery. We expect investment in energy efficiency to increase dramatically both in the near-term and through 2020 and beyond. This increase will come both from public support, such as the American Recovery and Reinvestment Act (ARRA) and significant increases in utility ratepayer funds directed toward efficiency, and also from increased private spending due to codes and standards, increasing energy prices, and voluntary standards for industry. Given the growing attention on energy efficiency, there is a concern among policy makers, program administrators, and others that there is an insufficiently trained workforce in place to meet the energy efficiency goals being put in place by local, state, and federal policy. To understand the likelihood of a potential workforce gap and appropriate response strategies, one needs to understand the size, composition, and potential for growth of the EESS. We use a bottom-up approach based upon almost 300 interviews with program administrators, education and training providers, and a variety of EESS employers and trade associations; communications with over 50 sector experts; as well as an extensive literature review. We attempt to provide insight into key aspects of the EESS by describing the current job composition, the current workforce size, our projections for sector growth through 2020, and key issues that may limit this growth.

  14. Diode magnetic-field influence on radiographic spot size

    SciTech Connect (OSTI)

    Ekdahl, Carl A. Jr.

    2012-09-04

    Flash radiography of hydrodynamic experiments driven by high explosives is a well-known diagnostic technique in use at many laboratories. The Dual-Axis Radiography for Hydrodynamic Testing (DARHT) facility at Los Alamos was developed for flash radiography of large hydrodynamic experiments. Two linear induction accelerators (LIAs) produce the bremsstrahlung radiographic source spots for orthogonal views of each experiment ('hydrotest'). The 2-kA, 20-MeV Axis-I LIA creates a single 60-ns radiography pulse. For time resolution of the hydrotest dynamics, the 1.7-kA, 16.5-MeV Axis-II LIA creates up to four radiography pulses by slicing them out of a longer pulse that has a 1.6-{micro}s flattop. Both axes now routinely produce radiographic source spot sizes having full-width at half-maximum (FWHM) less than 1 mm. To further improve on the radiographic resolution, one must consider the major factors influencing the spot size: (1) Beam convergence at the final focus; (2) Beam emittance; (3) Beam canonical angular momentum; (4) Beam-motion blur; and (5) Beam-target interactions. Beam emittance growth and motion in the accelerators have been addressed by careful tuning. Defocusing by beam-target interactions has been minimized through tuning of the final focus solenoid for optimum convergence and other means. Finally, the beam canonical angular momentum is minimized by using a 'shielded source' of electrons. An ideal shielded source creates the beam in a region where the axial magnetic field is zero, thus the canonical momentum zero, since the beam is born with no mechanical angular momentum. It then follows from Busch's conservation theorem that the canonical angular momentum is minimized at the target, at least in principal. In the DARHT accelerators, the axial magnetic field at the cathode is minmized by using a 'bucking coil' solenoid with reverse polarity to cancel out whatever solenoidal beam transport field exists there. This is imperfect in practice, because of radial variation of the total field across the cathode surface, solenoid misalignments, and long-term variability of solenoid fields for given currents. Therefore, it is useful to quantify the relative importance of canonical momentum in determining the focal spot, and to establish a systematic methodology for tuning the bucking coils for minimum spot size. That is the purpose of this article. Section II provides a theoretical foundation for understanding the relative importance of the canonical momentum. Section III describes the results of simulations used to quantify beam parameters, including the momentum, for each of the accelerators. Section IV compares the two accelerators, especially with respect to mis-tuned bucking coils. Finally, Section IV concludes with a methodology for optimizing the bucking coil settings.

  15. Development of a Low NOx Medium sized Industrial Gas Turbine Operating on Hydrogen-Rich Renewable and Opportunity Fuels

    SciTech Connect (OSTI)

    Srinivasan, Ram

    2013-07-31

    This report presents the accomplishments at the completion of the DOE sponsored project (Contract # DE-FC26-09NT05873) undertaken by Solar Turbines Incorporated. The objective of this 54-month project was to develop a low NOx combustion system for a medium sized industrial gas turbine engine operating on Hydrogen-rich renewable and opportunity Fuels. The work in this project was focused on development of a combustion system sized for 15MW Titan 130 gas turbine engine based on design analysis and rig test results. Although detailed engine evaluation of the complete system is required prior to commercial application, those tasks were beyond the scope of this DOE sponsored project. The project tasks were organized in three stages, Stages 2 through 4. In Stage 2 of this project, Solar Turbines Incorporated characterized the low emission capability of current Titan 130 SoLoNOx fuel injector while operating on a matrix of fuel blends with varying Hydrogen concentration. The mapping in this phase was performed on a fuel injector designed for natural gas operation. Favorable test results were obtained in this phase on emissions and operability. However, the resulting fuel supply pressure needed to operate the engine with the lower Wobbe Index opportunity fuels would require additional gas compression, resulting in parasitic load and reduced thermal efficiency. In Stage 3, Solar characterized the pressure loss in the fuel injector and developed modifications to the fuel injection system through detailed network analysis. In this modification, only the fuel delivery flowpath was modified and the air-side of the injector and the premixing passages were not altered. The modified injector was fabricated and tested and verified to produce similar operability and emissions as the Stage 2 results. In parallel, Solar also fabricated a dual fuel capable injector with the same air-side flowpath to improve commercialization potential. This injector was also test verified to produce 15-ppm NOx capability on high Hydrogen fuels. In Stage 4, Solar fabricated a complete set of injectors and a combustor liner to test the system capability in a full-scale atmospheric rig. Extensive high-pressure single injector rig test results show that 15-ppm NOx guarantee is achievable from 50% to 100% Load with fuel blends containing up to 65% Hydrogen. Because of safety limitations in Solar Test Facility, the atmospheric rig tests were limited to methane-based fuel blends. Further work to validate the durability and installed engine capability would require long-term engine field test.

  16. Index of /datasets/files/41/pub

    Open Energy Info (EERE)

    PUBID82185 22-May-2012 00:11 - DIR PUBID82188 22-May-2012 00:11 - DIR PUBID82189 22-May-2012 00:11 - DIR PUBID82190 22-May-2012 00:11 - DIR PUBID82191...

  17. Enhanced photocatalytic degradation of methylene blue by metal-modified silicon nanowires

    SciTech Connect (OSTI)

    Brahiti, N.; Hadjersi, T.; Menari, H.; Amirouche, S.; El Kechai, O.

    2015-02-15

    Highlights: SiNWs modified with Pd, Au and Pt were used as photocatalysts to degrade MB. Yield of photodegardation increases with UV irradiation time. SiNWs modified with Pd nanoparticles show the best photocatalytic activity. A degradation of 97% was obtained after 200 min of UV irradiation. - Abstract: Silicon nanowires (SiNWs) modified with Au, Pt and Pd nanoparticles were used as heterogeneous photocatalysts for the photodegradation of methylene blue in water under UV light irradiation. The modification of SiNWs was carried out by deposition of metal nanoparticles using the electroless metal deposition (EMD) technique. The effect of metal nanoparticles deposition time on the photocatalytic activity was studied. It was found that the photocatalytic activity of modified SiNWs was enhanced when the deposition time of metal nanoparticles was increased. In addition of modified SiNWs with Pt, Au and Pd nanoparticles, oxidized silicon substrate (Ox-Si), oxidized silicon nanowires (Ox-SiNWs) and hydrogen-terminated silicon nanowires (H-SiNWs) were also evaluated for the photodegradation of methylene blue.

  18. Decomposition pathways of C2 oxygenates on Rh-modified tungsten carbide surfaces

    SciTech Connect (OSTI)

    Kelly, Thomas G.; Ren, Hui; Chen, Jingguang G.

    2015-03-27

    Ethanol decomposition on tungsten monocarbide (WC) and Rh-modified WC was investigated using ultrahigh vacuum (UHV) surface science experiments and density functional theory (DFT) calculations. DFT calculations indicated that the binding energies of ethanol and its decomposition intermediates on WC(0001) were modified by Rh, with Rh/WC(0001) showing similar values to those on Rh(111). Through temperature-programmed desorption (TPD) experiments on polycrystalline WC and Rh-modified WC, it was shown that the selectivity for ethanol decomposition was different on these surfaces. On WC, the C-O bond of ethanol was preferentially broken to produce ethylene; on Rh-modified WC, the C-C bond was broken to produce carbon monoxide and methane. In addition, high-resolution electron energy loss spectroscopy (HREELS) was used to determine likely surface intermediates. On Rh-modified WC, ethanol first formed ethoxy through O-H scission, then reacted through an aldehyde intermediate to form the C1 products.

  19. Decomposition pathways of C2 oxygenates on Rh-modified tungsten carbide surfaces

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kelly, Thomas G.; Ren, Hui; Chen, Jingguang G.

    2015-03-27

    Ethanol decomposition on tungsten monocarbide (WC) and Rh-modified WC was investigated using ultrahigh vacuum (UHV) surface science experiments and density functional theory (DFT) calculations. DFT calculations indicated that the binding energies of ethanol and its decomposition intermediates on WC(0001) were modified by Rh, with Rh/WC(0001) showing similar values to those on Rh(111). Through temperature-programmed desorption (TPD) experiments on polycrystalline WC and Rh-modified WC, it was shown that the selectivity for ethanol decomposition was different on these surfaces. On WC, the C-O bond of ethanol was preferentially broken to produce ethylene; on Rh-modified WC, the C-C bond was broken to producemore » carbon monoxide and methane. In addition, high-resolution electron energy loss spectroscopy (HREELS) was used to determine likely surface intermediates. On Rh-modified WC, ethanol first formed ethoxy through O-H scission, then reacted through an aldehyde intermediate to form the C1 products.« less

  20. Solvation of fluoro-acetonitrile in water by 2D-IR spectroscopy: A combined experimental-computational study

    SciTech Connect (OSTI)

    Cazade, Pierre-Andr; Das, Akshaya K.; Tran, Halina; Klsi, Felix; Hamm, Peter; Bereau, Tristan; Meuwly, Markus

    2015-06-07

    The solvent dynamics around fluorinated acetonitrile is characterized by 2-dimensional infrared spectroscopy and atomistic simulations. The lineshape of the linear infrared spectrum is better captured by semiempirical (density functional tight binding) mixed quantum mechanical/molecular mechanics simulations, whereas force field simulations with multipolar interactions yield lineshapes that are significantly too narrow. For the solvent dynamics, a relatively slow time scale of 2 ps is found from the experiments and supported by the mixed quantum mechanical/molecular mechanics simulations. With multipolar force fields fitted to the available thermodynamical data, the time scale is considerably fasteron the 0.5 ps time scale. The simulations provide evidence for a well established CFHOH hydrogen bond (population of 25%) which is found from the radial distribution function g(r) from both, force field and quantum mechanics/molecular mechanics simulations.

  1. Evaluation of moist processes during intense precipitation in km-scale NWP models using remote sensing and in-situ data: Impact of microphysics size distribution assumptions

    SciTech Connect (OSTI)

    VanWeverberg, K.; vanLipzig, N. P. M.; Delobbe, L.

    2011-02-01

    This study investigates the sensitivity of moist processes and surface precipitation during three extreme precipitation events over Belgium to the representation of rain, snow and hail size distributions in a bulk one-moment microphysics parameterisation scheme. Sensitivities included the use of empirically derived relations to calculate the slope parameter and diagnose the intercept parameter of the exponential snow and rain size distributions and sensitivities to the treatment of hail/graupel. A detailed evaluation of the experiments against various high temporal resolution and spatially distributed observational data was performed to understand how moist processes responded to the implemented size distribution modifications. Net vapor consumption by microphysical processes was found to be unaffected by snow or rain size distribution modifications, while it was reduced replacing formulations for hail by those typical for graupel, mainly due to intense sublimation of graupel. Cloud optical thickness was overestimated in all experiments and all cases, likely due to overestimated snow amounts. The overestimation slightly deteriorated by modifying the rain and snow size distributions due to increased snow depositional growth, while it was reduced by including graupel. The latter was mainly due to enhanced cloud water collection by graupel and reduced snow depositional growth. Radar reflectivity and cloud optical thickness could only be realistically represented by inclusion of graupel during a stratiform case, while hail was found indispensable to simulate the vertical reflectivity profile and the surface precipitation structure. Precipitation amount was not much altered by any of the modifications made and the general overestimation was only decreased slightly during a supercell convective case.

  2. Scaling Semantic Graph Databases in Size and Performance

    SciTech Connect (OSTI)

    Morari, Alessandro; Castellana, Vito G.; Villa, Oreste; Tumeo, Antonino; Weaver, Jesse R.; Haglin, David J.; Choudhury, Sutanay; Feo, John T.

    2014-08-06

    In this paper we present SGEM, a full software system for accelerating large-scale semantic graph databases on commodity clusters. Unlike current approaches, SGEM addresses semantic graph databases by only employing graph methods at all the levels of the stack. On one hand, this allows exploiting the space efficiency of graph data structures and the inherent parallelism of graph algorithms. These features adapt well to the increasing system memory and core counts of modern commodity clusters. On the other hand, however, these systems are optimized for regular computation and batched data transfers, while graph methods usually are irregular and generate fine-grained data accesses with poor spatial and temporal locality. Our framework comprises a SPARQL to data parallel C compiler, a library of parallel graph methods and a custom, multithreaded runtime system. We introduce our stack, motivate its advantages with respect to other solutions and show how we solved the challenges posed by irregular behaviors. We present the result of our software stack on the Berlin SPARQL benchmarks with datasets up to 10 billion triples (a triple corresponds to a graph edge), demonstrating scaling in dataset size and in performance as more nodes are added to the cluster.

  3. Electric mergers: Transmission pricing, market size, and effects on competition

    SciTech Connect (OSTI)

    Legato, C.D.

    1996-06-01

    The prospect of deregulation has introducted a wave of mergers among electric utilities. Most of these mergers would fail an antitrust review because, by combining generation assets of interconnected utilities, they have substantially reduced potential competition in generation. In fact, one can predict that most mergers of utilities that operate within the same power pool or reliability region will be anticompetitive, even if they are not interconnected. Using an antitrust analysis, this article illustrates the potential anticompetitive effects of mergers between interconnected utilities. It concludes that the relevant geographic market will be an area in which a single, area-wide transmission price is charged. Moreover, it concludes that this area and, hence, the relevant market will likely span an area no larger than the Mid-American Interconnected Network or the Virginia/Carolina subregion of the Southeastern Reliability Council. Assuming markets of this size, the data on resulting concentration will show severe consequences for mergers of the sort that were announced in 1995 and 1996.

  4. Simultaneous effect of modified gravity and primordial non-Gaussianity in large scale structure observations

    SciTech Connect (OSTI)

    Mirzatuny, Nareg; Khosravi, Shahram; Baghram, Shant; Moshafi, Hossein E-mail: khosravi@mail.ipm.ir E-mail: hosseinmoshafi@iasbs.ac.ir

    2014-01-01

    In this work we study the simultaneous effect of primordial non-Gaussianity and the modification of the gravity in f(R) framework on large scale structure observations. We show that non-Gaussianity and modified gravity introduce a scale dependent bias and growth rate functions. The deviation from ?CDM in the case of primordial non-Gaussian models is in large scales, while the growth rate deviates from ?CDM in small scales for modified gravity theories. We show that the redshift space distortion can be used to distinguish positive and negative f{sub NL} in standard background, while in f(R) theories they are not easily distinguishable. The galaxy power spectrum is generally enhanced in presence of non-Gaussianity and modified gravity. We also obtain the scale dependence of this enhancement. Finally we define galaxy growth rate and galaxy growth rate bias as new observational parameters to constrain cosmology.

  5. Neutronic Study of Slightly Modified Water Reactors and Application to Transition Scenarios

    SciTech Connect (OSTI)

    Chambon, Richard; Guillemin, Perrine; Nuttin, Alexis; Bidaud, A.

    2007-07-01

    In this paper we have studied slightly modified water reactors and their applications to transition scenarios. The PWR and CANDU reactors have been considered. New fuels based on Thorium have been tested: Thorium/Plutonium and Thorium/Uranium- 233, with different fissile isotope contents. Changes in the geometry of the assemblies were also explored to modify the moderation ratio, and consequently the neutron flux spectrum. A core equivalent assembly methodology was introduced as an exploratory approach and to reduce the computation time. Several basic safety analyses were also performed. We have finally developed a new scenario code, named OSCAR (Optimized Scenario Code for Advanced Reactors), to study the efficiency of these modified reactors in transition to Gen IV reactors or in symbiotic fleet. (authors)

  6. Plants having modified response to ethylene by transformation with an ETR nucleic acid

    DOE Patents [OSTI]

    Meyerowitz, Elliott M.; Chang, Caren; Bleecker, Anthony B.

    2001-01-01

    The invention includes transformed plants having at least one cell transformed with a modified ETR nucleic acid. Such plants have a phenotype characterized by a decrease in the response of at least one transformed plant cell to ethylene as compared to a plant not containing the transformed plant cell. Tissue and/or temporal specificity for expression of the modified ETR nucleic acid is controlled by selecting appropriate expression regulation sequences to target the location and/or time of expression of the transformed nucleic acid. The plants are made by transforming at least one plant cell with an appropriate modified ETR nucleic acid, regenerating plants from one or more of the transformed plant cells and selecting at least one plant having the desired phenotype.

  7. Simulation of a photovoltaic/thermal heat pump system having a modified collector/evaporator

    SciTech Connect (OSTI)

    Xu, Guoying; Deng, Shiming; Zhang, Xiaosong; Yang, Lei; Zhang, Yuehong

    2009-11-15

    A new photovoltaic/thermal heat pump (PV/T-HP) system having a modified collector/evaporator (C/E) has been developed and numerically studied. Multi-port flat extruded aluminum tubes were used in the modified C/E, as compared to round copper tubes used in a conventional C/E. Simulation results suggested that a better operating performance can be achieved for a PV/T-HP system having such a modified C/E. In addition, using the meteorological data in both Nanjing and Hong Kong, China, the simulation results showed that this new PV/T-HP system could efficiently generate electricity and thermal energy simultaneously in both cities all-year-round. Furthermore, improved operation by using variable speed compressor has been designed and discussed. (author)

  8. INNOVATIVE TECHNIQUES AND TECHNOLOGY APPLICATION IN MANAGEMENT OF REMOTE HANDLED AND LARGE SIZED MIXED WASTE FORMS

    SciTech Connect (OSTI)

    BLACKFORD LT

    2008-02-04

    CH2M HILL Hanford Group, Inc. (CH2M HILL) plays a critical role in Hanford Site cleanup for the U. S. Department of Energy, Office of River Protection (ORP). CH2M HILL is responsible for the management of 177 tanks containing 53 million gallons of highly radioactive wastes generated from weapons production activities from 1943 through 1990. In that time, 149 single-shell tanks, ranging in capacity from 50,000 gallons to 500,000 gallons, and 28 double-shell tanks with a capacity of 1 million gallons each, were constructed and filled with toxic liquid wastes and sludges. The cleanup mission includes removing these radioactive waste solids from the single-shell tanks to double-shell tanks for staging as feed to the Waste Treatment Plant (WTP) on the Hanford Site for vitrification of the wastes and disposal on the Hanford Site and Yucca Mountain repository. Concentrated efforts in retrieving residual solid and sludges from the single-shell tanks began in 2003; the first tank retrieved was C-106 in the 200 East Area of the site. The process for retrieval requires installation of modified sluicing systems, vacuum systems, and pumping systems into existing tank risers. Inherent with this process is the removal of existing pumps, thermo-couples, and agitating and monitoring equipment from the tank to be retrieved. Historically, these types of equipment have been extremely difficult to manage from the aspect of radiological dose, size, and weight of the equipment, as well as their attendant operating and support systems such as electrical distribution and control panels, filter systems, and mobile retrieval systems. Significant effort and expense were required to manage this new waste stream and resulted in several events over time that were both determined to be unsafe for workers and potentially unsound for protection of the environment. Over the last four years, processes and systems have been developed that reduce worker exposures to these hazards, eliminate violations of RCRA storage regulations, reduce costs for waste management by nearly 50 percent, and create a viable method for final treatment and disposal of these waste forms that does not impact retrieval project schedules. This paper is intended to provide information to the nuclear and environmental clean-up industry with the experience of CH2M HILL and ORP in managing these highly difficult waste streams, as well as providing an opportunity for sharing lessons learned, including technical methods and processes that may be applied at other DOE sites.

  9. ON THE SIZE, SHAPE, AND DENSITY OF DWARF PLANET MAKEMAKE

    SciTech Connect (OSTI)

    Brown, M. E.

    2013-04-10

    A recent stellar occultation by the dwarf planet Makemake provided an excellent opportunity to measure the size and shape of one of the largest objects in the Kuiper belt. The analysis of these results provided what were reported to be precise measurements of the lengths of the projected axes, the albedo, and even the density of Makemake, but these results were, in part, derived from qualitative arguments. We reanalyzed the occultation timing data using a quantitative statistical description, and, in general, found the previously reported results on the shape of Makemake to be unjustified. In our solution, in which we use our inference from photometric data that Makemake is being viewed nearly pole-on, we find a 1{sigma} upper limit to the projected elongation of Makemake of 1.02, with measured equatorial diameter of 1434 {+-} 14 km and a projected polar diameter of 1422 {+-} 14 km, yielding an albedo of 0.81{sup +0.01}{sub -0.02}. If we remove the external constraint on the pole position of Makemake, we find instead a 1{sigma} upper limit to the elongation of 1.06, with a measured equatorial diameter of 1434{sup +48}{sub -18} km and a projected polar diameter of 1420{sup +18}{sub -24} km, yielding an albedo of 0.81{sup +0.03}{sub -0.05}. Critically, we find that the reported measurement of the density of Makemake was based on the misapplication of the volatile retention models. A corrected analysis shows that the occultation measurements provide no meaningful constraint on the density of Makemake.

  10. Sandia Energy - Glitter-Sized Photovoltaic Cells in Utility-Scale...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Glitter-Sized Photovoltaic Cells in Utility-Scale Solar Power Systems Home Renewable Energy Energy News Photovoltaic Solar Glitter-Sized Photovoltaic Cells in Utility-Scale Solar...

  11. Effect of Engine-Out NOx Control Strategies on PM Size Distribution...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Engine-Out NOx Control Strategies on PM Size Distribution in Heavy-Duty Diesel Engines Developed for 2010 Effect of Engine-Out NOx Control Strategies on PM Size Distribution in ...

  12. Better Buildings Alliance, Advanced Rooftop Unit Campaign: RTU Sizing Guidance (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2014-09-01

    This fact sheet discusses the causes and consequences of incorrect RTU sizing (with respect to cooling tonnage and supply fan horsepower) and points to resources that can help ensure accurate sizing calculations.

  13. WORKING DRAFT Last Modified 7/13/2014 9:34 PM Pacific Standard Time

    U.S. Energy Information Administration (EIA) Indexed Site

    DRAFT Last Modified 7/13/2014 9:34 PM Pacific Standard Time Printed 7/13/2014 9:36 PM Pacific Standard Time China Energy Demand Perspective EIA presentation July 2014 CONFIDENTIAL AND PROPRIETARY Any use of this material without specific permission of McKinsey & Company is strictly prohibited Last Modified 7/13/2014 9:34 PM Pacific Standard Time Printed 7/13/2014 9:36 PM Pacific Standard Time McKinsey & Company | 1 Key Points On Asian Energy Demand We have developed a granular view of

  14. Modified magnetism within the coherence volume of superconducting Fe1+delta

    Office of Scientific and Technical Information (OSTI)

    SexTe1-x (Journal Article) | SciTech Connect Modified magnetism within the coherence volume of superconducting Fe1+delta SexTe1-x Citation Details In-Document Search Title: Modified magnetism within the coherence volume of superconducting Fe1+delta SexTe1-x Authors: Leiner J. ; Thampy V. ; Christianson, A. D. ; Abernathy, D. L. ; Stone, M. B. ; Lumsden, M. D. ; Sefat, A. S. ; Sales, B. C. ; Hu, Jin ; Mao, Zhiqiang ; Bao, Wei ; Broholm, C. Publication Date: 2014-09-01 OSTI Identifier: 1174093

  15. Biofouling-resistant ceragenin-modified materials and structures for water treatment

    DOE Patents [OSTI]

    Hibbs, Michael; Altman, Susan J.; Jones, Howland D. T.; Savage, Paul B.

    2013-09-10

    This invention relates to methods for chemically grafting and attaching ceragenin molecules to polymer substrates; methods for synthesizing ceragenin-containing copolymers; methods for making ceragenin-modified water treatment membranes and spacers; and methods of treating contaminated water using ceragenin-modified treatment membranes and spacers. Ceragenins are synthetically produced antimicrobial peptide mimics that display broad-spectrum bactericidal activity. Alkene-functionalized ceragenins (e.g., acrylamide-functionalized ceragenins) can be attached to polyamide reverse osmosis membranes using amine-linking, amide-linking, UV-grafting, or silane-coating methods. In addition, silane-functionalized ceragenins can be directly attached to polymer surfaces that have free hydroxyls.

  16. A new design for a disposable and modifiable electrochemical cell (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect Journal Article: A new design for a disposable and modifiable electrochemical cell Citation Details In-Document Search Title: A new design for a disposable and modifiable electrochemical cell Authors: Dattelbaum, Andrew M [1] ; Gupta, Gautam [1] + Show Author Affiliations Los Alamos National Laboratory Publication Date: 2011-09-09 OSTI Identifier: 1095867 Report Number(s): LA-UR-11-05239; LA-UR-11-5239 DOE Contract Number: AC52-06NA25396 Resource Type: Journal

  17. Use of modified smooth exterior scaling method as an absorbing potential and its application

    SciTech Connect (OSTI)

    Kalita, Dhruba J.; Gupta, Ashish K.

    2011-03-07

    Here, we propose a new complex path to achieve better absorption during the propagation of a wavepacket. In the proposed modified smooth exterior scaling (SES) method, scaling function, {theta}(x), has been chosen as a real function rather than complex (as used in a conventional smooth exterior scaling method). It greatly reduces the artificial reflections from the boundary edges. This modified SES method is applied to study the multiphoton dissociation of H{sub 2}{sup +} in intense laser field. The resonance states are calculated accurately.

  18. Evaluation of products recovered from scrap tires for use as asphalt modifiers

    SciTech Connect (OSTI)

    McKay, J.

    1992-05-01

    Western Research Institute performed rheological tests and water sensitivity tests on asphalt cements that had been modified with carbonous residues obtained from the pyrolysis of scrap tires and waste motor oil. These tests are part of an ongoing program at the University of Wyoming Chemical Engineering Department to evaluate, as asphalt additives, solid carbonous products recovered from the scrap tire and waste motor oil pyrolysis experiments conducted at the University. The tests showed that carbonous residues increased the viscosity and decreased the elasticity of AC-10 and AC-20 asphalts. The tests also indicatedthat asphalt cements modified with carbonous residues were less sensitive to water damage and age embrittlement than unmodified asphalt cements.

  19. Process for preparing chemically modified micas for removal of cesium salts from aqueous solution

    DOE Patents [OSTI]

    Yates, Stephen Frederic; DeFilippi, Irene; Gaita, Romulus; Clearfield, Abraham; Bortun, Lyudmila; Bortun, Anatoly

    2000-09-05

    A chemically modified mica composite formed by heating a trioctahedral mica in an aqueous solution of sodium chloride having a concentration of at least 1 mole/liter at a temperature greater than 180 degrees Centigrade for at least 20 hours, thereby replacing exchangeable ions in the mica with sodium. Formation is accomplished at temperatures and pressures which are easily accessed by industrial equipment. The reagent employed is inexpensive and non-hazardous, and generates a precipitate which is readily separated from the modified mica.

  20. Building America Webinar: HVAC Right-Sizing Part 1-Calculating Loads |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy HVAC Right-Sizing Part 1-Calculating Loads Building America Webinar: HVAC Right-Sizing Part 1-Calculating Loads During this webinar, Building America Research Team IBACOS highlighted the key criteria required to create accurate heating and cooling load calculations. Current industry rules of thumb, perceptions and barriers to right-sizing HVAC were also discussed. File webinar_hvac_calculatingloads_20110428.wmv More Documents & Publications HVAC Right-Sizing Part 1:

  1. Comparing Server Energy Use and Efficiency Using Small Sample Sizes

    SciTech Connect (OSTI)

    Coles, Henry C.; Qin, Yong; Price, Phillip N.

    2014-11-01

    This report documents a demonstration that compared the energy consumption and efficiency of a limited sample size of server-type IT equipment from different manufacturers by measuring power at the server power supply power cords. The results are specific to the equipment and methods used. However, it is hoped that those responsible for IT equipment selection can used the methods described to choose models that optimize energy use efficiency. The demonstration was conducted in a data center at Lawrence Berkeley National Laboratory in Berkeley, California. It was performed with five servers of similar mechanical and electronic specifications; three from Intel and one each from Dell and Supermicro. Server IT equipment is constructed using commodity components, server manufacturer-designed assemblies, and control systems. Server compute efficiency is constrained by the commodity component specifications and integration requirements. The design freedom, outside of the commodity component constraints, provides room for the manufacturer to offer a product with competitive efficiency that meets market needs at a compelling price. A goal of the demonstration was to compare and quantify the server efficiency for three different brands. The efficiency is defined as the average compute rate (computations per unit of time) divided by the average energy consumption rate. The research team used an industry standard benchmark software package to provide a repeatable software load to obtain the compute rate and provide a variety of power consumption levels. Energy use when the servers were in an idle state (not providing computing work) were also measured. At high server compute loads, all brands, using the same key components (processors and memory), had similar results; therefore, from these results, it could not be concluded that one brand is more efficient than the other brands. The test results show that the power consumption variability caused by the key components as a group is similar to all other components as a group. However, some differences were observed. The Supermicro server used 27 percent more power at idle compared to the other brands. The Intel server had a power supply control feature called cold redundancy, and the data suggest that cold redundancy can provide energy savings at low power levels. Test and evaluation methods that might be used by others having limited resources for IT equipment evaluation are explained in the report.

  2. Modified two-fluid model of conductivity for superconducting surface resistance calculation. Master's thesis

    SciTech Connect (OSTI)

    Linden, D.S.

    1993-05-01

    The traditional two-fluid model of superconducting conductivity was modified to make it accurate, while remaining fast, for designing and simulating microwave devices. The modification reflects the BCS coherence effects in the conductivity of a superconductor, and is incorporated through the ratio of normal to superconducting electrons. This modified ratio is a simple analytical expression which depends on frequency, temperature and material parameters. This modified two-fluid model allows accurate and rapid calculation of the microwave surface impedance of a superconductor in the clean and dirty limits and in the weak- and strong-coupled regimes. The model compares well with surface resistance data for Nb and provides insight into Nb3Sn and Y1Ba2Cu3O(7-delta). Numerical calculations with the modified two-fluid model are an order of magnitude faster than the quasi-classical program by Zimmermann (1), and two to five orders of magnitude faster than Halbritter's BCS program (2) for surface resistance.

  3. Modified Baryonic Dynamics: two-component cosmological simulations with light sterile neutrinos

    SciTech Connect (OSTI)

    Angus, G.W.; Gentile, G.; Diaferio, A.; Famaey, B.; Heyden, K.J. van der E-mail: diaferio@ph.unito.it E-mail: gianfranco.gentile@ugent.be

    2014-10-01

    In this article we continue to test cosmological models centred on Modified Newtonian Dynamics (MOND) with light sterile neutrinos, which could in principle be a way to solve the fine-tuning problems of the standard model on galaxy scales while preserving successful predictions on larger scales. Due to previous failures of the simple MOND cosmological model, here we test a speculative model where the modified gravitational field is produced only by the baryons and the sterile neutrinos produce a purely Newtonian field (hence Modified Baryonic Dynamics). We use two-component cosmological simulations to separate the baryonic N-body particles from the sterile neutrino ones. The premise is to attenuate the over-production of massive galaxy cluster halos which were prevalent in the original MOND plus light sterile neutrinos scenario. Theoretical issues with such a formulation notwithstanding, the Modified Baryonic Dynamics model fails to produce the correct amplitude for the galaxy cluster mass function for any reasonable value of the primordial power spectrum normalisation.

  4. A practical and theoretical definition of very small field size for radiotherapy output factor measurements

    SciTech Connect (OSTI)

    Charles, P. H. Crowe, S. B.; Langton, C. M.; Trapp, J. V.; Cranmer-Sargison, G.; Thwaites, D. I.; Kairn, T.; Knight, R. T.; Kenny, J.

    2014-04-15

    Purpose: This work introduces the concept of very small field size. Output factor (OPF) measurements at these field sizes require extremely careful experimental methodology including the measurement of dosimetric field size at the same time as each OPF measurement. Two quantifiable scientific definitions of the threshold of very small field size are presented. Methods: A practical definition was established by quantifying the effect that a 1 mm error in field size or detector position had on OPFs and setting acceptable uncertainties on OPF at 1%. Alternatively, for a theoretical definition of very small field size, the OPFs were separated into additional factors to investigate the specific effects of lateral electronic disequilibrium, photon scatter in the phantom, and source occlusion. The dominant effect was established and formed the basis of a theoretical definition of very small fields. Each factor was obtained using Monte Carlo simulations of a Varian iX linear accelerator for various square field sizes of side length from 4 to 100 mm, using a nominal photon energy of 6 MV. Results: According to the practical definition established in this project, field sizes ?15 mm were considered to be very small for 6 MV beams for maximal field size uncertainties of 1 mm. If the acceptable uncertainty in the OPF was increased from 1.0% to 2.0%, or field size uncertainties are 0.5 mm, field sizes ?12 mm were considered to be very small. Lateral electronic disequilibrium in the phantom was the dominant cause of change in OPF at very small field sizes. Thus the theoretical definition of very small field size coincided to the field size at which lateral electronic disequilibrium clearly caused a greater change in OPF than any other effects. This was found to occur at field sizes ?12 mm. Source occlusion also caused a large change in OPF for field sizes ?8 mm. Based on the results of this study, field sizes ?12 mm were considered to be theoretically very small for 6 MV beams. Conclusions: Extremely careful experimental methodology including the measurement of dosimetric field size at the same time as output factor measurement for each field size setting and also very precise detector alignment is required at field sizes at least ?12 mm and more conservatively?15 mm for 6 MV beams. These recommendations should be applied in addition to all the usual considerations for small field dosimetry, including careful detector selection.

  5. Method and apparatus for sizing and separating warp yarns using acoustical energy

    DOE Patents [OSTI]

    Sheen, S.H.; Chien, H.T.; Raptis, A.C.; Kupperman, D.S.

    1998-05-19

    A slashing process is disclosed for preparing warp yarns for weaving operations including the steps of sizing and/or desizing the yarns in an acoustic resonance box and separating the yarns with a leasing apparatus comprised of a set of acoustically agitated lease rods. The sizing step includes immersing the yarns in a size solution contained in an acoustic resonance box. Acoustic transducers are positioned against the exterior of the box for generating an acoustic pressure field within the size solution. Ultrasonic waves that result from the acoustic pressure field continuously agitate the size solution to effect greater mixing and more uniform application and penetration of the size onto the yarns. The sized yarns are then separated by passing the warp yarns over and under lease rods. Electroacoustic transducers generate acoustic waves along the longitudinal axis of the lease rods, creating a shearing motion on the surface of the rods for splitting the yarns. 2 figs.

  6. Method and apparatus for sizing and separating warp yarns using acoustical energy

    DOE Patents [OSTI]

    Sheen, Shuh-Haw; Chien, Hual-Te; Raptis, Apostolos C.; Kupperman, David S.

    1998-01-01

    A slashing process for preparing warp yarns for weaving operations including the steps of sizing and/or desizing the yarns in an acoustic resonance box and separating the yarns with a leasing apparatus comprised of a set of acoustically agitated lease rods. The sizing step includes immersing the yarns in a size solution contained in an acoustic resonance box. Acoustic transducers are positioned against the exterior of the box for generating an acoustic pressure field within the size solution. Ultrasonic waves that result from the acoustic pressure field continuously agitate the size solution to effect greater mixing and more uniform application and penetration of the size onto the yarns. The sized yarns are then separated by passing the warp yarns over and under lease rods. Electroacoustic transducers generate acoustic waves along the longitudinal axis of the lease rods, creating a shearing motion on the surface of the rods for splitting the yarns.

  7. Extracting magnetic cluster size and its distributions in advanced perpendicular recording media with shrinking grain size using small angle x-ray scattering

    SciTech Connect (OSTI)

    Mehta, Virat; Ikeda, Yoshihiro; Takano, Ken; Terris, Bruce D.; Hellwig, Olav; Wang, Tianhan; Wu, Benny; Graves, Catherine; Dürr, Hermann A.; Scherz, Andreas; Stöhr, Jo

    2015-05-18

    We analyze the magnetic cluster size (MCS) and magnetic cluster size distribution (MCSD) in a variety of perpendicular magnetic recording (PMR) media designs using resonant small angle x-ray scattering at the Co L{sub 3} absorption edge. The different PMR media flavors considered here vary in grain size between 7.5 and 9.5 nm as well as in lateral inter-granular exchange strength, which is controlled via the segregant amount. While for high inter-granular exchange, the MCS increases rapidly for grain sizes below 8.5 nm, we show that for increased amount of segregant with less exchange the MCS remains relatively small, even for grain sizes of 7.5 and 8 nm. However, the MCSD still increases sharply when shrinking grains from 8 to 7.5 nm. We show evidence that recording performance such as signal-to-noise-ratio on the spin stand correlates well with the product of magnetic cluster size and magnetic cluster size distribution.

  8. Research on the chemical mechanism in the polyacrylate latex modified cement system

    SciTech Connect (OSTI)

    Wang, Min; Wang, Rumin; Zheng, Shuirong; Farhan, Shameel; Yao, Hao; Jiang, Hao

    2015-10-15

    In this paper, the chemical mechanism in the polyacrylate latex modified cement system was investigated by Fourier transform infrared spectra (FT-IR), X-ray photoelectron spectroscopy (XPS), gel permeation chromatography (GPC) and compact pH meter. All results have shown that the chemical reactions in the polyacrylate modified system can be divided into three stages. The hydration reactions of cement can produce large amounts of Ca(OH){sub 2} (calcium hydroxide) and lead the whole system to be alkali-rich and exothermic at the first stage. Subsequently, this environment can do great contributions to the hydrolysis of ester groups in the polyacrylate chains, resulting in the formation of carboxyl groups at the second stage. At the third stage, the final crosslinked network structure of the product was obtained by the reaction between the carboxyl groups in the polyacrylate latex chains and Ca(OH){sub 2}.

  9. Improving the efficiency and availability analysis of a modified reheat regenerative Rankine cycle

    SciTech Connect (OSTI)

    Bassily, A.M.

    1999-07-01

    Reheating in a reheat regenerative steam power cycle increases efficiency by increasing the average temperature of heat reception, but also increases the irreversibility of feed water heaters by raising the temperature of the superheated steam used for the regenerative process. This paper introduces some modifications to the regular reheat regenerative steam power cycle that reduce the irreversibility of the regenerative process. An availability analysis of the modified cycle and the regular reheat regenerative cycle as well as a comparison study between both cycles is done. The results indicate that a gain in energy efficiency of up to 2.5% as the steam generator pressure varies is obtained when applying such modifications at the same conditions of pressure, temperature's number of reheating stages, and feed water heaters. The availability analysis showed that such increase in efficiency is due to the reduction of the irreversibility of the regeneration process of the modified cycle.

  10. Process for producing modified microorganisms for oil treatment at high temperatures, pressures and salinity

    DOE Patents [OSTI]

    Premuzic, E.T.; Lin, M.

    1996-02-20

    This invention relates to the preparation of new, modified organisms, through challenge growth processes, that are viable in the extreme temperature, pressure and pH conditions and salt concentrations of an oil reservoir and that are suitable for use in microbial enhanced oil recovery. The modified microorganisms of the present invention are used to enhance oil recovery and remove sulfur compounds and metals from the crude oil. The processes are comprised of steps which successively limit the carbon sources and increase the temperature, pressure and salinity of the media. This is done until microbial strains are obtained that are capable of growing in essentially crude oil as a carbon source and at a temperature range from about 70 C to 90 C, at a pressure range from about 2,000 to 2,500 psi and at a salinity range from about 1.3 to 35%. 68 figs.

  11. Process for producing modified microorganisms for oil treatment at high temperatures, pressures and salinity

    DOE Patents [OSTI]

    Premuzic, Eugene T.; Lin, Mow

    1996-02-20

    This invention relates to the preparation of new, modified organisms, through challenge growth processes, that are viable in the extreme temperature, pressure and pH conditions and salt concentrations of an oil reservoir and that are suitable for use in microbial enhanced oil recovery. The modified microorganisms of the present invention are used to enhance oil recovery and remove sulfur compounds and metals from the crude oil. The processes are comprised of steps which successively limit the carbon sources and increase the temperature, pressure and salinity of the media. This is done until microbial strains are obtained that are capable of growing in essentially crude oil as a carbon source and at a temperature range from about 70.degree. C. to 90.degree. C., at a pressure range from about 2,000 to 2,500 psi and at a salinity range from about 1.3 to 35%.

  12. A modified version of the geomechanics classification for entry design in underground coal mines

    SciTech Connect (OSTI)

    Newman, D.A.; Bieniawski, Z.T.

    1985-01-01

    The Geomechanics Classification was modified for entry and roof support design in underground room-and-pillar coal mines. Adjustment multipliers were introduced to incorporate the influence of strata weatherability, high horizontal stresses, and the roof support reinforcement factor into the existing classification system. Sixty-two case histories of both standing and fallen mine roof were collected from two mines in the northern Appalachian coalfield. Twenty-seven engineering and geologic parameters were recorded for each case. A partial correlation analysis was carried out on the cases to establish which parameters have a significant impact upon the supported stand-up time of coal mine roof. Survival analysis, a statistical technique used in medical research to assess the effect of a drug or treatment on a patient's life expectancy, was conducted together with stepwise multiple regression to derive values for the adjustment multipliers. A practical example is included to illustrate the application of the modified Geomechanics Classification to underground coal mine design.

  13. Fluoro-alcohol phase modifiers and process for cesium solvent extraction

    DOE Patents [OSTI]

    Bonnesen, Peter V.; Moyer, Bruce A.; Sachleben, Richard A.

    2003-05-20

    The invention relates to a class of phenoxy fluoro-alcohols, their preparation, and their use as phase modifiers and solvating agents in a solvent composition for the extraction of cesium from alkaline solutions. These phenoxy fluoro-alcohols comply with the formula: ##STR1## in which n=2 to 4; X represents a hydrogen or a fluorine atom, and R.sup.2 -R.sup.6 are hydrogen or alkyl substituents. These phenoxy fluoro-alcohol phase modifiers are a necessary component to a robust solvent composition and process useful for the removal of radioactive cesium from alkaline nuclear waste streams. The fluoro-alcohols can also be used in solvents designed to extract other cesium from acidic or neutral solutions.

  14. Power flattening on modified CANDLE small long life gas-cooled fast reactor

    SciTech Connect (OSTI)

    Monado, Fiber; Su'ud, Zaki; Waris, Abdul; Basar, Khairul; Ariani, Menik; Sekimoto, Hiroshi

    2014-09-30

    Gas-cooled Fast Reactor (GFR) is one of the candidates of next generation Nuclear Power Plants (NPPs) that expected to be operated commercially after 2030. In this research conceptual design study of long life 350 MWt GFR with natural uranium metallic fuel as fuel cycle input has been performed. Modified CANDLE burn-up strategy with first and second regions located near the last region (type B) has been applied. This reactor can be operated for 10 years without refuelling and fuel shuffling. Power peaking reduction is conducted by arranging the core radial direction into three regions with respectively uses fuel volume fraction 62.5%, 64% and 67.5%. The average power density in the modified core is about 82 Watt/cc and the power peaking factor decreased from 4.03 to 3.43.

  15. CBEI: AHU FDD in Small and Medium Sized Commercial Buildings - 2015 Peer

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Review | Department of Energy AHU FDD in Small and Medium Sized Commercial Buildings - 2015 Peer Review CBEI: AHU FDD in Small and Medium Sized Commercial Buildings - 2015 Peer Review Presenter: Jin Wen, Drexel View the Presentation PDF icon CBEI: AHU FDD in Small and Medium Sized Commercial Buildings - 2015 Peer Review More Documents & Publications Compatible and Cost-Effective Fault Diagnostic Solutions for Air Handling Unit-Variable Air Volume and Air Handling Unit-Constant Air Volume

  16. CBEI: HVAC Packages for Small and Medium Sized Commercial Buildings - 2015

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Peer Review | Department of Energy HVAC Packages for Small and Medium Sized Commercial Buildings - 2015 Peer Review CBEI: HVAC Packages for Small and Medium Sized Commercial Buildings - 2015 Peer Review Presenter: Russell Taylor, United Technologies Research Center View the Presentation PDF icon CBEI: HVAC Packages for Small and Medium Sized Commercial Buildings - 2015 Peer Review More Documents & Publications CBEI: FDD for Advanced RTUs - 2015 Peer Review CBEI: Lessons Learned from

  17. CBEI: Lessons Learned from Integrated Retrofits in Small and Medium Sized

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Commercial Buildings - 2015 Peer Review | Department of Energy Lessons Learned from Integrated Retrofits in Small and Medium Sized Commercial Buildings - 2015 Peer Review CBEI: Lessons Learned from Integrated Retrofits in Small and Medium Sized Commercial Buildings - 2015 Peer Review Presenter: Mark Stutman, PSU View the Presentation PDF icon CBEI: Lessons Learned from Integrated Retrofits in Small and Medium Sized Commercial Buildings - 2015 Peer Review More Documents & Publications

  18. CBEI: Packaged Masonry Wall Retrofit Solution for Small and Medium Sized

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Commercial Buildings - 2015 Peer Review | Department of Energy Packaged Masonry Wall Retrofit Solution for Small and Medium Sized Commercial Buildings - 2015 Peer Review CBEI: Packaged Masonry Wall Retrofit Solution for Small and Medium Sized Commercial Buildings - 2015 Peer Review Presenter: Mugdha Mokashi, Bayer Materials View the Presentation PDF icon CBEI: Packaged Masonry Wall Retrofit Solution for Small and Medium Sized Commercial Buildings - 2015 Peer Review More Documents &

  19. Size Dependence of Two-Photon Absorption in Semiconductor Quantum Dots

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Size Dependence of Two-Photon Absorption in Semiconductor Quantum Dots Citation Details In-Document Search Title: Size Dependence of Two-Photon Absorption in Semiconductor Quantum Dots Quantum confinement plays an important role in the optical properties of semiconductor quantum dots (QDs). In this work, we combine experiment and modeling to systematically investigate the size dependence of the degenerate two-photon absorption (TPA) of below-band-gap

  20. Current Size and Remaining Market Potential of the U.S. Energy Service

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Company Industry | Department of Energy Current Size and Remaining Market Potential of the U.S. Energy Service Company Industry Current Size and Remaining Market Potential of the U.S. Energy Service Company Industry The study analyzes the size, growth and trends in the U.S. energy service company (ESCO) industry, drawing on information provided by industry executives and experts in 2012. The report also provides a preliminary estimate of remaining investment potential and annual blended

  1. Energy Department Helps Manufacturers of Small and Mid-Size Wind Turbines

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Meet Certification Requirements | Department of Energy Helps Manufacturers of Small and Mid-Size Wind Turbines Meet Certification Requirements Energy Department Helps Manufacturers of Small and Mid-Size Wind Turbines Meet Certification Requirements October 1, 2015 - 1:04pm Addthis Energy Department Helps Manufacturers of Small and Mid-Size Wind Turbines Meet Certification Requirements Mark Higgins Operations Supervisor, Wind & Water Power Technologies Office On October 1, the Energy

  2. Process for modifying the metal ion sorption capacity of a medium

    DOE Patents [OSTI]

    Lundquist, Susan H. (White Bear Township, MN)

    2002-01-01

    A process for modifying a medium is disclosed that includes treating a medium having a metal ion sorption capacity with a solution that includes: A) an agent capable of forming a complex with metal ions; and B) ions selected from the group consisting of sodium ions, potassium ions, magnesium ions, and combinations thereof, to create a medium having an increased capacity to sorb metal ions relative to the untreated medium.

  3. Ultrasonic processor reduces drill-cuttings size and eliminates subsea mounds

    SciTech Connect (OSTI)

    Gaddy, D.E.

    1997-10-06

    Drill cuttings size reduction using ultrasonics eliminated a subsea clean-up and significantly reduced the environmental impact in a North Sea drilling project. Reduction in cuttings size allows for a wider areal dispersion when released into the ocean because they are held in suspension longer than larger sizes. Thus, ocean currents carry the smaller cuttings farther away from the well template, leaving a much wider footprint than larger cuttings sizes. This eliminates the pile-up of cuttings that otherwise would contaminate and harm the marine habitat.

  4. Size Effects in the Electrochemical Alloying and Cycling ofElectrodep...

    Office of Scientific and Technical Information (OSTI)

    Title: Size Effects in the Electrochemical Alloying and Cycling of Electrodeposited Aluminum with Lithium. Abstract not provided. Authors: Hudak, Nicholas ; Huber, Dale L. ...

  5. What Is the Size of the Atomic Nucleus? | U.S. DOE Office of...

    Office of Science (SC) Website

    What Is the Size of the Atomic Nucleus? Nuclear Physics (NP) NP Home About Research Facilities Science Highlights Benefits of NP Funding Opportunities Nuclear Science Advisory ...

  6. D0 Silicon Upgrade: Liquid & Gas Nitrogen Line Sizing for D-Zero...

    Office of Scientific and Technical Information (OSTI)

    ... Yucca Mountain Site Characterization Office, Las Vegas, NV ... Language: English Subject: 43 PARTICLE ACCELERATORS; ... PRESSURE DROP; SILICON; SIZE; SOLENOIDS; STORAGE; VALVES ...

  7. Flutter Speed Predictions for MW-Sized Wind Turbine Blades Don...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Flutter Speed Predictions for MW-Sized Wind Turbine Blades Don W. Lobitz Sandia National ... Leishman, J. G., "Challenges in Modelling the Unsteady Aerodynamics of Wind Turbines," ...

  8. Size Dependence of the Bandgap of Plasma Synthesized Silicon Nanoparticles Through Direct Introduction of Sulfur Hexafluoride

    SciTech Connect (OSTI)

    Theingi, S.; Guan, T. Y.; Kendrick, C.; Klafehn, G.; Gorman, B. P.; Taylor, P. C.; Lusk, M. T.; Stradins, Pauls; Collins, R. T.

    2015-10-19

    Developing silicon nanoparticle (SiNP) synthesis techniques that allow for straightforward control of nanoparticle size and associated optical properties is critical to potential applications of these materials. In addition, it is, in general, hard to probe the absorption threshold in these materials due to silicon's low absorption coefficient. In this study, size is controlled through direct introduction of sulfur hexafluoride (SF6) into the dilute silane precursor of plasma synthesized SiNPs. Size reduction by nearly a factor of two with high crystallinity independent of size is demonstrated. Optical absorption spectra of the SiNPs in the vicinity of the bandgap are measured using photothermal deflection spectroscopy. Bandgap as a function of size is extracted taking into account the polydispersity of the samples. A systematic blue shift inabsorption edge due to quantum confinement in the SiNPs is observed with increasing flow of SF6. Photoluminescence (PL) spectra show a similar blue shift with size. However, a ~300 meV difference in energy between emission and absorption for all sizes suggests that PL emission involves a defect related process. While PL may allow size-induced shifts in the bandgap of SiNPs to be monitored, it cannot be relied on to give an accurate value for the bandgap as a function of size.

  9. Disorder and size effects on Kondo interactions and magneticcorrelations in CePt2 nanoscrystals

    SciTech Connect (OSTI)

    Chen, Y.Y.; Huang, P.H.; Ou, M.N.; Wang, C.R.; Yao, Y.D.; Lee,T.K.; Ho, M.Y.; Lawrence, J.M.; Booth, C.H.

    2006-12-12

    The evolution of the Kondo effect and magnetic correlations with size reduction in CePt{sub 2} nanoparticles (3.1-26 nm) is studied by analysis of the temperature-dependent specific heat and magnetic susceptibility. The antiferromagnetic correlations diminish with size reduction. The Kondo effect predominates at small particle size with trivalent, small Kondo temperature (T{sub K}) magnetic regions coexisting with strongly mixed valent, large T{sub K} nonmagnetic regions. We discuss the role of structural disorder, background density of states and the electronic quantum size effect on the results.

  10. Impact of magnification and size bias on the weak lensing power...

    Office of Scientific and Technical Information (OSTI)

    and peak statistics Citation Details In-Document Search Title: Impact of magnification and size bias on the weak lensing power spectrum and peak statistics Authors: Liu J. ...

  11. Effect of particle size and doses of olivine addition on carbon...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    11012015 Keywords anaerobic digestion, biogas upgrading, carbon sequestration, mMineral ... 2) placement of olivine in the digester, and 3) olivine particle size and concentration. ...

  12. Geometric and Electronic Properties of Graphene Modified by External N-Containing Groups

    SciTech Connect (OSTI)

    Wang, Xinde; Cai, Qiuxia; Zhuang, Guilin; Zhong, Xing; Mei, Donghai; Li, Xiaonian; Wang, Jianguo

    2014-10-14

    By means of the first-principles spin polarized density functional theory (DFT) calculations, we investigated structures and electronic properties of external nitrogen-containing groups (pyridine derivatives) modified graphene via single or double bonding mode. This study of single-bond pyridine derivatives modified graphene (SBPG) shows that the ortho-carbon is the most favorable adsorption site for pyridine derivatives on graphene, as confirmed by bader charge analysis. The external stability of pyridine derivatives on graphene by [2+2] cycloaddition is caused by the match between frontier orbitals of pyridine derivatives and those of graphene, which leading to the formation of stronger chemical bonds. Interestingly, electronic structure analysis reveals that the spin-up and spin-down parts DOS of SBPG clearly split, while it is not found for double-bonds pyridine derivatives modified graphene (DBPG). This work was supported by the 973 project (2013CB733501) and the National Natural Science Foundation of China ( 21101137, 21136001, 21176221, 21306169 and 91334013). D. Mei is supported by the US Department of Energy, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences. Pacific Northwest National Laboratory (PNNL) is a multiprogram national laboratory operated for DOE by Battelle.

  13. The radiation chemistry of Cs-7SB, a solvent modifier used in Cs and Sr extraction

    SciTech Connect (OSTI)

    Mincher, B.J.; Martin, L.R.; Elias, G.; Mezyk, S.P.

    2008-07-01

    The solvent modifier 1-(2,2,3,3-tetrafluoro-propoxy)-3-(4-sec-butylphenoxy)-2-propanol, (Cs- 7SB) is used in conjunction with calixarenes and crown ethers dissolved in alkane diluents for the extraction of Cs and Sr from highly radioactive solutions. Its purpose is to solvate the ligands and the resulting ligand-metal complexes in the organic phase. Given this role, and its relatively high concentration in the formulations used for solvent extraction, radiolytic degradation of Cs-7SB might decrease the extraction efficiency of these elements as the solvent accumulates absorbed radiation dose. This work presents the results of studies of Cs-7SB using post-radiolysis gas chromatography with electron-capture detection and solvent-extraction distribution-ratio measurements. Also presented is the kinetic analysis of the bimolecular rate constant for the modifier's reaction with nitrogen trioxide and nitrogen dioxide radicals, major radiolytically-produced radical species in irradiated aqueous nitric acid. Although Cs-7SB was found to undergo reactions with nitrogen-centered radicals, little decrease in extraction efficiency was found. It is concluded the modifier, always present at concentrations much higher than the ligands, acts as a radical scavenger, protecting ligands from radiolytic attack. (authors)

  14. Photocatalytic CO{sub 2} reduction by CH{sub 4} over montmorillonite modified TiO{sub 2} nanocomposites in a continuous monolith photoreactor

    SciTech Connect (OSTI)

    Tahir, Muhammad; Tahir, Beenish

    2015-03-15

    Highlights: TiO{sub 2}/MMT supported monolith photo-reactor was tested for CO{sub 2} reduction with CH{sub 4}. MMT inhibited crystal growth and enhanced TiO{sub 2} photo-activity in monolith reactor. CO{sub 2} was reduced by CH{sub 4} to CO, CH{sub 3}OH, C{sub 2}H{sub 6}, C{sub 3}H{sub 6} and C{sub 3}H{sub 8} in a monolith reactor. CO yield over TiO{sub 2}/MMT was 237.5 ?mol g-catal.{sup ?1} h{sup ?1}, a 2.52 fold than TiO{sub 2}. Stability test revealed TiO{sub 2}/MMT partially lost photo-activity in reused cyclic runs. - Abstract: In this study, the performance of montmorillonite (MMT) modified TiO{sub 2} nanocomposites for photocatalytic CO{sub 2} reduction with CH{sub 4} in a continuous monolith photoreactor has been investigated. The MMT modified TiO{sub 2} nanocomposites were dip-coated over monolith channels and were characterized by XRD, SEM, TEM, XPS, N{sub 2}-adsorptiondesorption and UVvis spectroscopy. The MMT produced anatase phase of TiO{sub 2} and reduced TiO{sub 2} crystallite size from 19 nm to 13 nm. CO was the major reduction product with a yield rate of 237.5 ?mol g-catal.{sup ?1} h{sup ?1} over 10 wt.% MMT-loaded TiO{sub 2} at 100 C, and CO{sub 2}/CH{sub 4} feed ratio 1.0. The photoactivity of MMT-loaded TiO{sub 2} monolithic catalyst was 2.52 times higher than bare TiO{sub 2}. Likewise, low concentrations of C{sub 2}H{sub 6}, CH{sub 3}OH, C{sub 3}H{sub 6} and C{sub 3}H{sub 8} were detected in the products mixture. These results inferred MMT modified TiO{sub 2} and monolith photoreactor were beneficial for enhancing photocatalysis process with appreciable productivity. The stability test revealed photoactivity of MMT-loaded TiO{sub 2} nanocomposites partially diminished in recycle runs.

  15. Grain size dependent mechanical properties of nanocrystalline diamond films grown by hot-filament CVD

    SciTech Connect (OSTI)

    Wiora, M; Bruehne, K; Floeter, A; Gluche, P; Willey, T M; Kucheyev, S O; Van Buuren, A W; Hamza, A V; Biener, J; Fecht, H

    2008-08-01

    Nanocrystalline diamond (NCD) films with a thickness of {approx}6 {micro}m and with average grain sizes ranging from 60 to 9 nm were deposited on silicon wafers using a hot-filament chemical vapor deposition (HFCVD) process. These samples were then characterized with the goal to identify correlations between grain size, chemical composition and mechanical properties. The characterization reveals that our films are phase pure and exhibit a relatively smooth surface morphology. The levels of sp{sup 2}-bonded carbon and hydrogen impurities are low, and showed a systematic variation with the grain size. The hydrogen content increases with decreasing grain size, whereas the sp{sup 2} carbon content decreases with decreasing grain size. The material is weaker than single crystalline diamond, and both stiffness and hardness decrease with decreasing grain size. These trends suggest gradual changes of the nature of the grain boundaries, from graphitic in the case of the 60 nm grain size material to hydrogen terminated sp{sup 3} carbon for the 9 nm grain size material. The films exhibit low levels of internal stress and freestanding structures with a length of several centimeters could be fabricated without noticeable bending.

  16. Quantitative Reflectance Spectra of Solid Powders as a Function of Particle Size

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Myers, Tanya L.; Brauer, Carolyn S.; Su, Yin-Fong; Blake, Thomas A.; Tonkyn, Russell G.; Ertel, Alyssa B.; Johnson, Timothy J.; Richardson, Robert L.

    2015-05-19

    We have recently developed vetted methods for obtaining quantitative infrared directional-hemispherical reflectance spectra using a commercial integrating sphere. In this paper, the effects of particle size on the spectral properties are analyzed for several samples such as ammonium sulfate, calcium carbonate, and sodium sulfate as well as one organic compound, lactose. We prepared multiple size fractions for each sample and confirmed the mean sizes using optical microscopy. Most species displayed a wide range of spectral behavior depending on the mean particle size. General trends of reflectance vs. particle size are observed such as increased albedo for smaller particles: for mostmorewavelengths, the reflectivity drops with increased size, sometimes displaying a factor of 4 or more drop in reflectivity along with a loss of spectral contrast. In the longwave infrared, several species with symmetric anions or cations exhibited reststrahlen features whose amplitude was nearly invariant with particle size, at least for intermediate- and large-sized sample fractions; that is, > ~150 microns. Trends of other types of bands (Christiansen minima, transparency features) are also investigated as well as quantitative analysis of the observed relationship between reflectance vs. particle diameter.less

  17. Influence of grain size on the constitutive response and substructure evolution of MONEL 400

    SciTech Connect (OSTI)

    Gray, G.T. III, Chen, S.R.; Vecchio, K.S.

    1999-05-01

    The influence of grain size on the constitutive behavior (strain-rate and temperature dependence of the yield stress and strain hardening) and substructure evolution of MONEL 400 was investigated. Increasing the grain size from 9.5 to 202 {micro}m was seen to reduce the quasi-static yield strength from 290 to 115 MPa, while having a minimal effect on the work-hardening response. Increasing the strain rate from quasi-static to dynamic strain rates (3000 s{sup {minus}1}) was seen to increase the yield and overall flow-stress levels, but has no effect on the strong grain-size dependency exhibited of this alloy. The persistent influence of grain size to large strains is inconsistent with previous d{sup {minus}1/2} pileup grain-size modeling in the literature, which predicts convergence at large strains. Substructure evolution differences between the grain interiors and adjacent to grain boundaries supports differential defect storage processes which are consistent with previously published work-hardening d{sup {minus}1} modeling arguments for grain size-dependent strengthening in polycrystals. The integration of grain-size dependency into constitutive modeling using the mechanical threshold stress (MTS) model is discussed. The MTS model is shown to provide a robust constitutive description capturing yielding, large-strain work hardening, and grain-size effects simultaneously. The MTS model is, additionally, shown to satisfactorily address the experimentally observed transients due to strain-rate or temperature-path dependency.

  18. Preparation of 1,3,5-triamo-2,4,6-trinitrobenzene of submicron particle size

    DOE Patents [OSTI]

    Rigdon, Lester P.; Moody, Gordon L.; McGuire, Raymond R.

    2001-05-01

    A method is disclosed for the preparation of very small particle size, relatively pure 1,3,5-triamino-2,4,6-trinitrobenzene (TATB). Particles of TATB prepared according to the disclosed method are of submicron size and have a surface area in the range from about 3.8 to 27 square meters per gram.

  19. Preparation of 1,3,5-triamino-2,4,6-trinitrobenzene of submicron particle size

    DOE Patents [OSTI]

    Rigdon, Lester P.; Moody, Gordon L.; McGuire, Raymond R.

    2001-01-01

    A method is disclosed for the preparation of very small particle size, relatively pure 1,3,5-triamino-2,4,6-trinitrobenzene (TATB). Particles of TATB prepared according to the disclosed method are of submicron size and have a surface area in the range from about 3.8 to 27 square meters per gram.

  20. Morphological changes in ultrafast laser ablation plumes with varying spot size

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Harilal, S. S.; Diwakar, P. K.; Polek, M. P.; Phillips, M. C.

    2015-06-04

    We investigated the role of spot size on plume morphology during ultrafast laser ablation of metal targets. Our results show that the spatial features of fs LA plumes are strongly dependent on the focal spot size. Two-dimensional self-emission images showed that the shape of the ultrafast laser ablation plumes changes from spherical to cylindrical with an increasing spot size from 100 to 600 ?m. The changes in plume morphology and internal structures are related to ion emission dynamics from the plasma, where broader angular ion distribution and faster ions are noticed for the smallest spot size used. The present resultsmoreclearly show that the morphological changes in the plume with spot size are independent of laser pulse width.less

  1. Enantioselective hydrogenation. III. Methyl pyruvate hydrogenation catalyzed by alkaloid-modified iridium

    SciTech Connect (OSTI)

    Simons, K.E.; Johnston, P.; Plum, H.; Wells, P.B.; Ibbotson, A.

    1994-12-01

    Enantioselective hydrogenation of methyl pyruvate, MeCOCOOMe to methyl lactate, MeCH(OH)COOMe, is catalyzed in solution at room temperature by supported iridium catalysts modified with cinchona alkaloids. Modification with cinchonidine or quinine yields R-lactate in excess, whereas modification with cinchonine or quinidine favors S-lactate formation. Ir/SiO{sub 2} catalysts (20%) calcined at 393 to 573 K and reduced at 523 to 593 K were highly active for racemic hydrogenation in the absence of a modifier (rates typically 1.8 mol h{sup -1} g{sub cat}{sup -1}) and were comparably active when modified with cinchonidine but gave an enantiomeric excess of about 30%. Use of higher calcination or reduction temperatures led to substantially inferior activity and selectivity. The high rates recorded for both racemic and enantioselective reactions are dependent on the catalysts being activated before use by a procedure involving exposure of the catalyst to air after the initial reduction. Use of a Cl-free precursor gave an Ir/SiO{sub 2} catalyst (20%) of superior activity but inferior enantioselectivity. Ir/CaCO{sub 3} (5%) was more active for racemic hydrogenation than for enantioselective hydrogenation, but provided the highest value of the enantiomeric excess 39%. Kinematics of reaction are reported. Exchange of H for D in 10,11-dihydrocinchonidine at room temperature over Ir/CaCO{sub 3} occurred in the quinoline moiety but not in the quinuclidine ring system, indicating that the alkaloid was adsorbed to the Ir surface via the interaction of its {pi}-electron system. For both silica-supported and calcium carbonate-supported Ir, the presence of chloride ion in the catalyst was advantageous for the achievement of enantioselectivity. 25 refs., 2 figs., 3 tabs.

  2. Trivalent Lanthanide/Actinide Separation Using Aqueous-Modified TALSPEAK Chemistry

    SciTech Connect (OSTI)

    Travis S. Grimes; Richard D. Tillotson; Leigh R. Martin

    2014-05-01

    TALSPEAK is a liquid/liquid extraction process designed to separate trivalent lanthanides (Ln3+) from minor actinides (MAs) Am3+ and Cm3+. Traditional TALSPEAK organic phase is comprised of a monoacidic dialkyl bis(2-ethylhexyl)phosphoric acid extractant (HDEHP) in diisopropyl benzene (DIPB). The aqueous phase contains a soluble aminopolycarboxylate diethylenetriamine-N,N,N,N,N-pentaacetic acid (DTPA) in a concentrated (1.0-2.0 M) lactic acid (HL) buffer with the aqueous acidity typically adjusted to pH 3.0. TALSPEAK balances the selective complexation of the actinides by DTPA against the electrostatic attraction of the lanthanides by the HDEHP extractant to achieve the desired trivalent lanthanide/actinide group separation. Although TALSPEAK is considered a successful separations scheme, recent fundamental studies have highlighted complex chemical interactions occurring in the aqueous and organic phases during the extraction process. Previous attempts to model the system have shown thermodynamic models do not accurately predict the observed extraction trends in the p[H+] range 2.5-4.8. In this study, the aqueous phase is modified by replacing the lactic acid buffer with a variety of simple and longer-chain amino acid buffers. The results show successful trivalent lanthanide/actinide group separation with the aqueous-modified TALSPEAK process at pH 2. The amino acid buffer concentrations were reduced to 0.5 M (at pH 2) and separations were performed without any effect on phase transfer kinetics. Successful modeling of the aqueous-modified TALSPEAK process (p[H+] 1.6-3.1) using a simplified thermodynamic model and an internally consistent set of thermodynamic data is presented.

  3. Long range ordered alloys modified by group IV-B metals

    DOE Patents [OSTI]

    Liu, Chain T.; Inouye, Henry; Schaffhauser, Anthony C.

    1983-01-01

    Ductile long range ordered alloys having high critical ordering temperatures exist in the (V,M)(Fe,Ni,Co).sub.3 system having the composition comprising by weight 20.6%-22.6% V, 14-50% Fe, 0-64% Co, and 0-40% Ni, and 0.4-1.4% M, where M is a metal selected from the group consisting of Ti, Zr, Hf, and their mixtures. These modified alloys have an electron density no greater than 8.00 and exhibit marked increases at elevated temperature in ductility and other mechanical properties over previously known ordered alloys.

  4. Production And Artile Of Iron/Surfactant-Modified Zeolite Pellets To Retain And Destroy Water Pollutants

    DOE Patents [OSTI]

    BOWMAN, ROBERT S.; [et al

    2001-07-17

    A method of producing a pollutant adsorption and degradation article, and such article, are provided. At least one adsorbent is mixed with at least one pollutant transforming agent to form a mixture. This mixture is compacted to form a porous, highly permeable article. If necessary, the article can be modified with surfactant either after the compacting step or by adding the surfactant to the mixture prior to the compacting step. In addition, if necessary, a binding agent can be added to the mixture prior to the compacting step.

  5. Low amplitude impact of PBX 9501: Modified Steven spigot gun tests

    SciTech Connect (OSTI)

    Idar, D.J.; Lucht, R.A.; Straight, J.W.

    1998-12-01

    Low-velocity mechanical impact and subsequent high explosive (HE) reaction are of concern in credible accident scenarios involving the handling, transport, and storage of nuclear weapons. Using modified Steven spigot gun tests, the authors have investigated the high-explosive violent-reaction (HEVR) potential of PBX 9501 to low-amplitude insult. Reliable modeling predictions require that one identify the relevant parameters and behavioral responses that are key to the reaction mechanism(s) in PBX 9501. Additional efforts have been targeted at identifying relevant differences in the response between baseline and stockpile-aged PBX 9501 to low-velocity impacts.

  6. Surface Modified Particles By Multi-Step Addition And Process For The Preparation Thereof

    DOE Patents [OSTI]

    Cook, Ronald Lee (Lakewood, CO); Elliott, Brian John (Superior, CO); Luebben, Silvia DeVito (Golden, CO); Myers, Andrew William (Arvada, CO); Smith, Bryan Matthew (Boulder, CO)

    2006-01-17

    The present invention relates to a new class of surface modified particles and to a multi-step surface modification process for the preparation of the same. The multi-step surface functionalization process involves two or more reactions to produce particles that are compatible with various host systems and/or to provide the particles with particular chemical reactivities. The initial step comprises the attachment of a small organic compound to the surface of the inorganic particle. The subsequent steps attach additional compounds to the previously attached organic compounds through organic linking groups.

  7. Highly efficient inverted organic solar cells using amino acid modified indium tin oxide as cathode

    SciTech Connect (OSTI)

    Li, Aiyuan; Nie, Riming; Deng, Xianyu; Wei, Huaixin; Li, Yanqing; Tang, Jianxin; Zheng, Shizhao; Wong, King-Young

    2014-03-24

    In this paper, we report that highly efficient inverted organic solar cells were achieved by modifying the surface of indium tin oxide (ITO) using an amino acid, Serine (Ser). With the modification of the ITO surface, device efficiency was significantly enhanced from 0.63% to 4.17%, accompanied with an open circuit voltage (Voc) that was enhanced from 0.30?V to 0.55?V. Ultraviolet and X-ray photoelectron spectroscopy studies indicate that the work function reduction induced by the amino acid modification resulting in the decreased barrier height at the ITO/organic interface played a crucial role in the enhanced performances.

  8. Nickel nano-particle modified nitrogen-doped amorphous hydrogenated diamond-like carbon film for glucose sensing

    SciTech Connect (OSTI)

    Zeng, Aiping; Jin, Chunyan; Cho, Sang-Jin; Seo, Hyun Ook; Kim, Young Dok; Lim, Dong Chan; Kim, Doo Hwan; Hong, Byungyou; Boo, Jin-Hyo

    2012-10-15

    Electrochemical method has been employed in this work to modify nitrogen-doped hydrogen amorphous diamond-like carbon (N-DLC) film to fabricate nickel nano-particle-modified N-DLC electrodes. The electrochemical behavior of the nickel nano-particle-modified N-DLC electrodes has been characterized at the presence of glucose in electrolyte. Meanwhile, the N-DLC film structure and the morphology of metal nano-particles on the N-DLC surface have been investigated using micro-Raman spectroscopy and atomic force microscopy. The nickel nano-particle-modified N-DLC electrode exhibits a high catalytic activity and low background current. This result shows that the nickel nano-particle deposition on N-DLC surface could be a promising method to fabricate novel electrode materials for glucose sensing.

  9. Improving biofuel feedstocks by modifying xylan biosynthesis (2013 DOE JGI Genomics of Energy and Environment 8th Annual User Meeting)

    SciTech Connect (OSTI)

    Lau, Jane

    2013-03-01

    Jane Lau of the Joint BioEnergy Institute on "Improving biofuel feedstocks by modifying xylan biosynthesis" at the 8th Annual Genomics of Energy & Environment Meeting on March 28, 2013 in Walnut Creek, Calif.

  10. T-676: Apple iOS Certificate Chain Validation Flaw Lets Certain Remote Users Access or Modify SSL/TLS Sessions

    Broader source: Energy.gov [DOE]

    Apple iOS Certificate Chain Validation Flaw Lets Certain Remote Users Access or Modify SSL/TLS Sessions.

  11. Finite-size effects on the radiative energy loss of a fast parton in hot

    Office of Scientific and Technical Information (OSTI)

    and dense strongly interacting matter (Journal Article) | SciTech Connect Finite-size effects on the radiative energy loss of a fast parton in hot and dense strongly interacting matter Citation Details In-Document Search Title: Finite-size effects on the radiative energy loss of a fast parton in hot and dense strongly interacting matter We consider finite-size effects on the radiative energy loss of a fast parton moving in a finite-temperature, strongly interacting medium, using the

  12. Experimental study of Siphon breaker about size effect in real scale reactor design

    SciTech Connect (OSTI)

    Kang, S. H.; Ahn, H. S.; Kim, J. M.; Joo, H. M.; Lee, K. Y.; Seo, K.; Chi, D. Y.; Kim, M. H.

    2012-07-01

    Rupture accident within the pipe of a nuclear reactor is one of the main causes of a loss of coolant accident (LOCA). Siphon-breaking is a passive method that can prevent a LOCA. In this study, either a line or a hole is used as a siphon-breaker, and the effect of various parameters, such as the siphon-breaker size, pipe rupture point, pipe rupture size, and the presence of an orifice, are investigated using an experimental facility similar in size to a full-scale reactor. (authors)

  13. Microsoft Word - GRS Review_OMB White Paper - Real Property Right-sizing

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Carbon Reduction August 7 2009 _2_.docx | Department of Energy GRS Review_OMB White Paper - Real Property Right-sizing and Carbon Reduction August 7 2009 _2_.docx Microsoft Word - GRS Review_OMB White Paper - Real Property Right-sizing and Carbon Reduction August 7 2009 _2_.docx PDF icon Microsoft Word - GRS Review_OMB White Paper - Real Property Right-sizing and Carbon Reduction August 7 2009 _2_.docx More Documents & Publications Executive Branch Management Scorecard 2013 guidance

  14. Size-Dependent Pressure-Induced Amorphization in Nanoscale TiO{sub 2}

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Size-Dependent Pressure-Induced Amorphization in Nanoscale TiO{sub 2} Citation Details In-Document Search Title: Size-Dependent Pressure-Induced Amorphization in Nanoscale TiO{sub 2} We investigated the size-dependent high-pressure phase transition behavior of nanocrystalline anatase TiO{sub 2} with synchrotron x-ray diffraction and Raman spectroscopy to 45 GPa at ambient temperature. Pressure-induced amorphization results in a high-density amorphous (HDA)

  15. Particle size effect of hydrogen-induced lattice expansion of palladium nanoclusters.

    SciTech Connect (OSTI)

    Ingham, B.; Toney, M. F.; Hendy, S. C.; Cox, T.; Fong, D. D.; Eastman, J. A.; Fuoss, P. H.; Stevens, K. J.; Lassesson, A.; Brown, S. A.; Ryan, M. P.; Materials Science Division; Industrial Research Ltd.; Stanford Synchrotron Radiation Lab.; Victoria Univ. of Wellington; Quest Reliability Ltd.; Univ. of Canterbury; Imperial Coll.

    2008-12-01

    In situ synchrotron x-ray diffraction experiments on bare palladium nanoclusters prepared by inert-gas aggregation and size selected (1.7-6.0 nm) show significant changes in lattice parameter upon hydrogen loading and a narrowing of the miscibility gap, as the cluster size decreases. The results show that the miscibility gap is open for all cluster sizes studied, in contrast to previous literature results from surfactant-encapsulated palladium clusters. We interpret these results by showing that the nature of the surface is critical in the hydrogenation behavior of the nanoclusters.

  16. Particle Size Effect of Hydrogen-Induced Lattice Expansion of Palladium Nanoclusters

    SciTech Connect (OSTI)

    Ingham, B.; Toney, M.F.; Hendy, S.C.; Cox, T.; Fong, D.D.; Eastman, J.A.; Fuoss, P.H.; Stevens, K.J.; Lassesson, A.; Brown, S.A.; Ryan, M.P.

    2009-05-18

    In situ synchrotron x-ray diffraction experiments on bare palladium nanoclusters prepared by inert-gas aggregation and size selected (1.7-6.0 nm) show significant changes in lattice parameter upon hydrogen loading and a narrowing of the miscibility gap, as the cluster size decreases. The results show that the miscibility gap is open for all cluster sizes studied, in contrast to previous literature results from surfactant-encapsulated palladium clusters. We interpret these results by showing that the nature of the surface is critical in the hydrogenation behavior of the nanoclusters.

  17. Increased InAs quantum dot size and density using bismuth as a surfactant

    SciTech Connect (OSTI)

    Dasika, Vaishno D.; Krivoy, E. M.; Nair, H. P.; Maddox, S. J.; Park, K. W.; Yu, E. T.; Bank, S. R.; Jung, D.; Lee, M. L.

    2014-12-22

    We have investigated the growth of self-assembled InAs quantum dots using bismuth as a surfactant to control the dot size and density. We find that the bismuth surfactant increases the quantum dot density, size, and uniformity, enabling the extension of the emission wavelength with increasing InAs deposition without a concomitant reduction in dot density. We show that these effects are due to bismuth acting as a reactive surfactant to kinetically suppress the surface adatom mobility. This mechanism for controlling quantum dot density and size has the potential to extend the operating wavelength and enhance the performance of various optoelectronic devices.

  18. Plasma size and power scaling of ion temperature gradient driven turbulence

    SciTech Connect (OSTI)

    Idomura, Yasuhiro; Nakata, Motoki

    2014-02-15

    The transport scaling with respect to plasma size and heating power is studied for ion temperature gradient driven turbulence using a fixed-flux full-f gyrokinetic Eulerian code. It is found that when heating power is scaled with plasma size, the ion heat diffusivity increases with plasma size in a local limit regime, where fixed-gradient ?f simulations predict a gyro-Bohm scaling. In the local limit regime, the transport scaling is strongly affected by the stiffness of ion temperature profiles, which is related to the power degradation of confinement.

  19. Pyroelectric response of ferroelectric nanowires: Size effect and electric energy harvesting

    SciTech Connect (OSTI)

    Morozovska, A. N.; Eliseev, E. A.; Svechnikov, S. V.; Kalinin, Sergei V

    2010-01-01

    The size effect on pyroelectric response of ferroelectric nanowires is analyzed. The pyroelectric coefficient strongly increases with the wire radius decrease and diverges at critical radius Rcr corresponding to the size-driven transition into paraelectric phase. Size-driven enhancement of pyroelectric coupling leads to the giant pyroelectric current and voltage generation by the polarized ferroelectric nanoparticles in response to the temperature fluctuation. The maximum efficiency of the pyroelectric energy harvesting and bolometric detection is derived, and is shown to approach the Carnot limit for low temperatures.

  20. Modified rubisco large subunit n-methyltransferase useful for targeting molecules to the active-site vicinity of ribulose-1,5-bisphosphate

    DOE Patents [OSTI]

    Houtz, Robert L.

    2012-03-20

    The present invention generally relates to a modified Rubisco large subunit .sup..epsilon.N-Methyltransferase (Rubisco LSMT, or RLSMT). The present invention also relates to a modified RLSMT-carbonic anhydrase (RLSMT-CA). This modified RLSMT-CA improves the efficiency of the reduction of CO.sub.2 during photosynthesis, which may increase plant growth rates. The present invention also relates to nucleic acids encoding the modified RLSMT-CA or modified RLSMT. Also, the present invention relates to cells including the modified RLSMT-CA or modified RLSMT, plants containing the modified RLSMT-CA or modified RLSMT, and methods using compositions of the present invention. In addition, the present invention relates to antibodies conjugated to CA which may bind to Rubisco, and antibodies which bind a modified RLSMT-CA. The invention also relates to modified forms of the LS and SS of Rubisco where the modified forms are fusions with CA or biologically active fragments thereof. The present invention provides methods of altering Rubisco carboxylase activity and altering plant growth.

  1. Surface modified CFx cathode material for ultrafast discharge and high energy density

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dai, Yang; Zhu, Yimei; Cai, Sendan; Wu, Lijun; Yang, Weijing; Xie, Jingying; Wen, Wen; Zheng, Jin-Cheng; Zheng, Yi

    2014-11-10

    Li/CFx primary possesses the highest energy density of 2180 W h kg⁻¹ among all primary lithium batteries. However, a key limitation for the utility of this type of battery is in its poor rate capability because the cathode material, CFx, is an intrinsically poor electronic conductor. Here, we report on our development of a controlled process of surface de-fluorination under mild hydrothermal conditions to modify the highly fluorinated CFx. The modified CFx, consisting of an in situ generated shell component of F-graphene layers, possesses good electronic conductivity and removes the transporting barrier for lithium ions, yielding a high-capacity performance andmore » an excellent rate-capability. Indeed, a capacity of 500 mA h g⁻¹ and a maximum power density of 44 800 W kg⁻¹ can be realized at the ultrafast rate of 30 C (24 A g⁻¹), which is over one order of magnitude higher than that of the state-of-the-art primary lithium-ion batteries.« less

  2. Enhanced modified faraday cup for determination of power density distribution of electron beams

    DOE Patents [OSTI]

    Elmer, John W. (Danville, CA); Teruya, Alan T. (Livermore, CA)

    2001-01-01

    An improved tomographic technique for determining the power distribution of an electron or ion beam using electron beam profile data acquired by an enhanced modified Faraday cup to create an image of the current density in high and low power ion or electron beams. A refractory metal disk with a number of radially extending slits, one slit being about twice the width of the other slits, is placed above a Faraday cup. The electron or ion beam is swept in a circular pattern so that its path crosses each slit in a perpendicular manner, thus acquiring all the data needed for a reconstruction in one circular sweep. The enlarged slit enables orientation of the beam profile with respect to the coordinates of the welding chamber. A second disk having slits therein is positioned below the first slit disk and inside of the Faraday cup and provides a shield to eliminate the majority of secondary electrons and ions from leaving the Faraday cup. Also, a ring is located below the second slit disk to help minimize the amount of secondary electrons and ions from being produced. In addition, a beam trap is located in the Faraday cup to provide even more containment of the electron or ion beam when full beam current is being examined through the center hole of the modified Faraday cup.

  3. Modified biokinetic model for uranium from analysis of acute exposure to UF6

    SciTech Connect (OSTI)

    Fisher, D.R.; Kathren, R.L.; Swint, M.J. )

    1991-03-01

    Urinalysis measurements from 31 workers acutely exposed to uranium hexafluoride (UF6) and its hydrolysis product UO2F2 (during the 1986 Gore, Oklahoma UF6-release accident) were used to develop a modified recycling biokinetic model for soluble U compounds. The model is expressed as a five-compartment exponential equation: yu(t) = 0.086e-2.77t + 0.0048e-0.116t + 0.00069e-0.0267t + 0.00017 e-0.00231t + 2.5 x 10(-6) e-0.000187t, where yu(t) is the fractional daily urinary excretion and t is the time after intake, in days. The excretion constants of the five exponential compartments correspond to residence half-times of 0.25, 6, 26, 300, and 3,700 d in the lungs, kidneys, other soft tissues, and in two bone volume compartments, respectively. The modified recycling model was used to estimate intake amounts, the resulting committed effective dose equivalent, maximum kidney concentrations, and dose equivalent to bone surfaces, kidneys, and lungs.

  4. THERMAL ENHANCEMENT CARTRIDGE HEATER MODIFIED TECH MOD TRITIUM HYDRIDE BED DEVELOPMENT PART I DESIGN AND FABRICATION

    SciTech Connect (OSTI)

    Klein, J.; Estochen, E.

    2014-03-06

    The Savannah River Site (SRS) tritium facilities have used 1{sup st} generation (Gen1) LaNi{sub 4.25}Al{sub 0.75} (LANA0.75) metal hydride storage beds for tritium absorption, storage, and desorption. The Gen1 design utilizes hot and cold nitrogen supplies to thermally cycle these beds. Second and 3{sup rd} generation (Gen2 and Gen3) storage bed designs include heat conducting foam and divider plates to spatially fix the hydride within the bed. For thermal cycling, the Gen2 and Gen 3 beds utilize internal electric heaters and glovebox atmosphere flow over the bed inside the bed external jacket for cooling. The currently installed Gen1 beds require replacement due to tritium aging effects on the LANA0.75 material, and cannot be replaced with Gen2 or Gen3 beds due to different designs of these beds. At the end of service life, Gen1 bed desorption efficiencies are limited by the upper temperature of hot nitrogen supply. To increase end-of-life desorption efficiency, the Gen1 bed design was modified, and a Thermal Enhancement Cartridge Heater Modified (TECH Mod) bed was developed. Internal electric cartridge heaters in the new design to improve end-of-life desorption, and also permit in-bed tritium accountability (IBA) calibration measurements to be made without the use of process tritium. Additional enhancements implemented into the TECH Mod design are also discussed.

  5. Surface modified CFx cathode material for ultrafast discharge and high energy density

    SciTech Connect (OSTI)

    Dai, Yang; Zhu, Yimei; Cai, Sendan; Wu, Lijun; Yang, Weijing; Xie, Jingying; Wen, Wen; Zheng, Jin-Cheng; Zheng, Yi

    2014-11-10

    Li/CFx primary possesses the highest energy density of 2180 W h kg⁻¹ among all primary lithium batteries. However, a key limitation for the utility of this type of battery is in its poor rate capability because the cathode material, CFx, is an intrinsically poor electronic conductor. Here, we report on our development of a controlled process of surface de-fluorination under mild hydrothermal conditions to modify the highly fluorinated CFx. The modified CFx, consisting of an in situ generated shell component of F-graphene layers, possesses good electronic conductivity and removes the transporting barrier for lithium ions, yielding a high-capacity performance and an excellent rate-capability. Indeed, a capacity of 500 mA h g⁻¹ and a maximum power density of 44 800 W kg⁻¹ can be realized at the ultrafast rate of 30 C (24 A g⁻¹), which is over one order of magnitude higher than that of the state-of-the-art primary lithium-ion batteries.

  6. Magnetorheological finishing of chemical-vapor deposited zinc sulfide via chemically and mechanically modified fluids

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Salzman, Sivan; Romanofsky, Henry J.; Giannechini, Lucca J.; Jacobs, Stephen D.; Lambropoulos, John C.

    2016-02-19

    In this study, we describe the anisotropy in the material removal rate (MRR) of the polycrystalline, chemical-vapor deposited zinc sulfide (ZnS).We define the polycrystalline anisotropy via microhardness and chemical erosion tests for four crystallographic orientations of ZnS: (100), (110), (111), and (311). Anisotropy in the MRR was studied under magnetorheological finishing (MRF) conditions. Three chemically and mechanically modified magnetorheological (MR) fluids at pH values of 4, 5, and 6 were used to test the MRR variations among the four single-crystal planes. When polishing the single-crystal planes and the polycrystalline with pH 5 and pH 6MR fluids, variations were found inmore » the MRR among the four single-crystal planes and surface artifacts were observed on the polycrystalline material. When polishing the single-crystal planes and the polycrystalline with the modified MR fluid at pH 4, however, minimal variation was observed in the MRR among the four orientations and a reduction in surface artifacts was achieved on the polycrystalline material.« less

  7. Dynamic impact and pressure analysis of the insensitive munitions container PA103 with modified design features

    SciTech Connect (OSTI)

    Handy, K.D.

    1993-06-01

    This report presents analytical analyses of the insensitive munitions container PA103, with modified design features for a static internal pressure of 500 psi and for a dynamic impact resulting from a 7-ft free fall onto a rigid surface. The modified design features addressed by the analyses were the inclusion of a score pattern on the container cylindrical body and a plastic plate (fuse) sandwiched between metal flanges on the container end. The objectives of both the pressure and impact analyses were to determine if the induced stresses at the score patterns in the cylindrical body of the container were sufficient to induce failure. Analytical responses of the container to the imposed loads were obtained with finite element analysis methodology. The computer codes ABAQUS and VEC/DYNA3D were used to obtain the results. Results of the pressure analysis indicate that failure of the container body would be expected to occur at the score pattern for a static internal pressure of 500 psi. Also, results from three impact orientations for a 7-ft drop indicate that membrane stresses in the vicinity of the score pattern are above critical crack growth stress magnitudes, especially at low ([minus]60[degrees]F) temperatures.

  8. Dynamic impact and pressure analysis of the insensitive munitions container PA103 with modified design features

    SciTech Connect (OSTI)

    Handy, K.D.

    1993-06-01

    This report presents analytical analyses of the insensitive munitions container PA103, with modified design features for a static internal pressure of 500 psi and for a dynamic impact resulting from a 7-ft free fall onto a rigid surface. The modified design features addressed by the analyses were the inclusion of a score pattern on the container cylindrical body and a plastic plate (fuse) sandwiched between metal flanges on the container end. The objectives of both the pressure and impact analyses were to determine if the induced stresses at the score patterns in the cylindrical body of the container were sufficient to induce failure. Analytical responses of the container to the imposed loads were obtained with finite element analysis methodology. The computer codes ABAQUS and VEC/DYNA3D were used to obtain the results. Results of the pressure analysis indicate that failure of the container body would be expected to occur at the score pattern for a static internal pressure of 500 psi. Also, results from three impact orientations for a 7-ft drop indicate that membrane stresses in the vicinity of the score pattern are above critical crack growth stress magnitudes, especially at low ({minus}60{degrees}F) temperatures.

  9. Analysis of higher harmonic contamination with a modified approach using a grating analyser

    SciTech Connect (OSTI)

    Gupta, Rajkumar Modi, Mohammed H.; Lodha, G. S.; Kumar, M.; Chakera, J. A.

    2014-04-15

    Soft x-ray spectra of the toroidal grating monochromator (TGM) at the reflectivity beamline of Indus-1 synchrotron source are analyzed for higher harmonic contribution. A diffraction grating of central line spacing 1200 l/mm is used to disperse the monochromatic beam received from TGM to quantify the harmonic contents in the 50–360 Å wavelength range. In order to calculate the harmonic contamination, conventionally the intensity of higher order peak is divided by first order peak intensity of the desired wavelength. This approach is found to give wrong estimate as first order peak itself is overlapped by higher order peaks. In the present study, a modified approach has been proposed to calculate harmonic contamination where the intensity contributions of overlapping orders have been removed from the first order diffraction peak of the desired wavelength. It is found that the order contamination in the TGM spectra is less than 15% in the wavelength range of 90–180 Å. The total harmonic contribution increases from 6%–60% in the wavelength range of 150–260 Å. The critical wavelength of Indus-1 is 61 Å hence the harmonic contamination below 90 Å is significantly low. The results obtained with modified approach match well with those obtained by quantitative analysis of multilayer reflectivity data. The obtained higher harmonics data are used to fit the transmission of aluminum edge filter in the 120–360 Å wavelength range.

  10. A modified Stillinger-Weber potential for TlBr and its polymorphic extension

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhou, Xiaowang; Foster, Michael E.; Jones, Reese E.; Doty, F. Patrick; Yang, Pin; Fan, Hongyou

    2015-04-30

    TlBr is promising for g- and x- radiation detection, but suffers from rapid performance degradation under the operating external electric fields. To enable molecular dynamics (MD) studies of this degradation, we have developed a Stillinger-Weber type of TlBr interatomic potential. During this process, we have also addressed two problems of wider interests. First, the conventional Stillinger-Weber potential format is only applicable for tetrahedral structures (e.g., diamond-cubic, zinc-blende, or wurtzite). Here we have modified the analytical functions of the Stillinger-Weber potential so that it can now be used for other crystal structures. Second, past modifications of interatomic potentials cannot always bemore » applied by a broad community because any new analytical functions of the potential would require corresponding changes in the molecular dynamics codes. Here we have developed a polymorphic potential model that simultaneously incorporates Stillinger-Weber, Tersoff, embedded-atom method, and any variations (i.e., modified functions) of these potentials. As a result, we have implemented this polymorphic model in MD code LAMMPS, and demonstrated that our TlBr potential enables stable MD simulations under external electric fields.« less

  11. STABILITY OF COSMIC-RAY MODIFIED SHOCKS: TWO-FLUID APPROACH

    SciTech Connect (OSTI)

    Saito, Tatsuhiko; Hoshino, Masahiro; Amano, Takanobu

    2013-10-01

    The stability of cosmic-ray modified shocks (CRMSs) is studied by means of numerical simulations. Owing to the nonlinear feedback of cosmic-ray (CR) acceleration, a downstream state of the modified shock can no longer be uniquely determined for given upstream parameters. It is known that up to three distinct solutions exist, which are characterized by CR production efficiency as the 'efficient', 'intermediate', and 'inefficient' branches. The stability of these solutions is investigated by performing direct time-dependent simulations of a two-fluid model. It is found that both the efficient and inefficient branches are stable even against a large-amplitude perturbation, while the intermediate one is always unstable and evolves into the inefficient state as a result of nonlinear time development. This bistable feature is robust in a wide range of parameters and does not depend on the injection model. Fully nonlinear time evolution of a hydrodynamic shock with injection results in the least efficient state in terms of CR production, consistent with the bistable feature. This suggests that the CR production efficiency in supernova remnant shocks may be lower than previously discussed in the framework of the nonlinear shock acceleration theory considering the efficient solution of the CRMS.

  12. Compaction comparison testing using a modified impact soil tester and nuclear density gauge

    SciTech Connect (OSTI)

    Erchul, R.A.

    1999-07-01

    The purpose of this paper is to compare test results of a modified Impact Soil Tester (IST) on compacted soil with data obtained from the same soil using a nuclear density gauge at the US Army Corp of Engineer's Buena Vista Flood Wall project in Buena Vista, Virginia. The tests were run during construction of the earth flood wall during the summer of 1996. This comparison testing demonstrated the credibility of the procedure developed for the IST as a compacting testing device. The comparison data was obtained on a variety of soils ranging from silty sands to clays. The Flood Wall comparison compaction data for 90% Standard Proctor shows that the results of the IST as modified are consistent with the nuclear density gauge 89% of the time for all types of soil tested. However, if the soils are more cohesive than the results are consistent with the nuclear density gauge 97% of the time. In addition these comparison tests are in general agreement with comparison compaction testing using the same testing techniques and methods of compacted backfill in utility trenches conducted earlier for the Public Works Department, Chesterfield County, Virginia.

  13. Modified Streamflows 1990 Level of Irrigation : Columbia River and Coastal Basins, 1928-1989.

    SciTech Connect (OSTI)

    United States. Bonneville Power Administration; A.G. Crook Company

    1993-04-01

    The annual operation plans described in the following sections require detailed system regulation computer model studies. These system regulation studies are necessary to evaluate potential new projects and to develop operational rule curves for the existing system of projects. The objective is to provide a basis for evaluating alternative system regulation scenarios. This provides essential input for optimizing the management of existing projects and planning future projects for the most beneficial use of the water supply and resources in the entire region. Historical streamflows per se are inadequate for system regulation studies because the pattern of observed flow has continually changed with each successive stage of irrigation and e development. The problem, therefore, is to adjust for past operation of storage projects and to determine the necessary adjustments that should be made to recorded flows to reflect current stages of irrigation development. Historical flows which have been adjusted to a common level of irrigation development by correcting for the effects of diversion demand, return flow, and change-of-contents and evaporation in upstream reservoirs and lakes are referred to as modified flows. This report describes the development of irrigation depletion adjustments and modified flows for the 1990 level of development for the 61-year period 1928--1989. incremental depletion adjustments were computed in this report for each month of the 61-year period to adjust the effects of actual irrigation in each year up to that which would have been experienced with the irrigation as practiced in 1990.

  14. Size-Controlled Synthesis of Porphyrinic Metal-Organic Framework and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Functionalization for Targeted Photodynamic Therapy | Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Size-Controlled Synthesis of Porphyrinic Metal-Organic Framework and Functionalization for Targeted Photodynamic Therapy

  15. Finite-size effects on the radiative energy loss of a fast parton...

    Office of Scientific and Technical Information (OSTI)

    This is done by introducing the concept of a radiation rate in the presence of finite-size effects. This effectively extends the finite-temperature approach of Arnold, Moore, and ...

  16. The Importance of Domain Size and Purity in High-Efficiency Organic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Importance of Domain Size and Purity in High-Effi... Why are efficient and affordable solar cells so highly coveted? Volume. The amount of solar energy lighting up ...

  17. Phosphorus removal from slow-cooled steelmaking slags: Grain size determination and liberation studies

    SciTech Connect (OSTI)

    Fregeau-Wu, E.; Iwasaki, I.

    1995-07-01

    The major obstacle in recycling steelmaking slags to the blast furnace is their phosphorus content. Removal of the phosphorus, which is primarily associated with the silicate and phosphate phases, would allow for greater recycle of these slags for their iron, manganese, and lime contents. Calculations show that separation of the silicates from the oxide phases would remove nearly 90% of the phosphorus from the slag. The variable grain size of the as-received slag made liberation by fine grinding difficult. Therefore, slow-cooling experiments were undertaken to improve the grain size distribution. The grain size distributions were determined using in-situ image analysis. The samples were ground to their apparent liberation size and high gradient magnetic separation was used to separate the magnetic oxides from the nonmagnetic silicates and phosphates. Liberation analysis and modeling was performed on selected separation products for discussion of benefication characteristics.

  18. Cooperative storage of shared files in a parallel computing system with dynamic block size

    DOE Patents [OSTI]

    Bent, John M.; Faibish, Sorin; Grider, Gary

    2015-11-10

    Improved techniques are provided for parallel writing of data to a shared object in a parallel computing system. A method is provided for storing data generated by a plurality of parallel processes to a shared object in a parallel computing system. The method is performed by at least one of the processes and comprises: dynamically determining a block size for storing the data; exchanging a determined amount of the data with at least one additional process to achieve a block of the data having the dynamically determined block size; and writing the block of the data having the dynamically determined block size to a file system. The determined block size comprises, e.g., a total amount of the data to be stored divided by the number of parallel processes. The file system comprises, for example, a log structured virtual parallel file system, such as a Parallel Log-Structured File System (PLFS).

  19. Phase transformations of nano-sized cubic boron nitride to white graphene and white graphite

    SciTech Connect (OSTI)

    Dang, Hongli; Liu, Yingdi; Xue, Wenhua; Anderson, Ryan S.; Sewell, Cody R.; Xue, Sha; Crunkleton, Daniel W.; Shen, Yaogen; Wang, Sanwu

    2014-03-03

    We report quantum-mechanical investigations that predict the formation of white graphene and nano-sized white graphite from the first-order phase transformations of nano-sized boron nitride thin-films. The phase transformations from the nano-sized diamond-like structure, when the thickness d > 1.4 nm, to the energetically more stable nano-sized white graphite involve low activation energies of less than 1.0 eV. On the other hand, the diamond-like structure transforms spontaneously to white graphite when d ≤ 1.4 nm. In particular, the two-dimensional structure with single-layer boron nitride, the so-called white graphene, could be formed as a result of such transformation.

  20. Effect on the Pore-Size Dependence of an Organic Electrolyte Supercapacitor

    SciTech Connect (OSTI)

    Jiang, Deen; Jin, Zhehui; Henderson, Douglous; Wu, Jianzhong

    2012-01-01

    Organic electrolytes such as tetraethylammonium tetrafluoroborate dissolved in acetonitrile (TEA-BF{sub 4}/ACN) are widely used in commercial supercapacitors and academic research, but conflicting experimental results have been reported regarding the dependence of surface-area-normalized capacitance on the pore size. Here we show from a classical density functional theory the dependence of capacitance on the pore size from 0.5 to 3.0 nm for a model TEA-BF{sub 4}/ACN electrolyte. We find that the capacitance-pore size curve becomes roughly flat after the first peak around the ion diameter, and the peak capacitance is not significantly higher than the large-pore average. We attribute the invariance of capacitance with the pore size to the formation of an electric double-layer structure that consists of counterions and highly organized solvent molecules. This work highlights the role of the solvent molecules in modulating the capacitance and reconciles apparently conflicting experimental reports.

  1. The Effects of Transient Emotional State and Workload on Size Scaling in Perspective Displays

    SciTech Connect (OSTI)

    Tuan Q. Tran; Kimberly R. Raddatz

    2006-10-01

    Previous research has been devoted to the study of perceptual (e.g., number of depth cues) and cognitive (e.g., instructional set) factors that influence veridical size perception in perspective displays. However, considering that perspective displays have utility in high workload environments that often induce high arousal (e.g., aircraft cockpits), the present study sought to examine the effect of observers emotional state on the ability to perceive and judge veridical size. Within a dual-task paradigm, observers ability to make accurate size judgments was examined under conditions of induced emotional state (positive, negative, neutral) and high and low workload. Results showed that participants in both positive and negative induced emotional states were slower to make accurate size judgments than those not under induced emotional arousal. Results suggest that emotional state is an important factor that influences visual performance on perspective displays and is worthy of further study.

  2. Current Size and Remaining Market Potential of the U.S. Energy Service Company Industry

    Broader source: Energy.gov [DOE]

    "This report contains information on Current Size and Remaining Market Potential of the U.S. Energy Service Company Industry, prepared for the U.S. Department of Energy Office of Energy Efficiency and Renewable Energy, Weatherization and Intergovernmental Program."

  3. Title 43 CFR 3206.12 What are the Minimum and Maximum Lease Sizes...

    Open Energy Info (EERE)

    .12 What are the Minimum and Maximum Lease Sizes? Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- Federal RegulationFederal Regulation: Title 43...

  4. Current Size and Remaining Market Potential of the U.S. Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The study analyzes the size, growth and trends in the U.S. energy service company (ESCO) industry, drawing on information provided by industry executives and experts in 2012. The ...

  5. Influence of pH on the quantum-size-controlled photoelectrochemical...

    Office of Scientific and Technical Information (OSTI)

    Influence of pH on the quantum-size-controlled photoelectrochemical etching of epitaxial InGaN quantum dots Citation Details In-Document Search This content will become publicly ...

  6. Colorado - C.R.S. 42-4-510, Permits for Excess Size and Weight...

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: Colorado - C.R.S. 42-4-510, Permits for Excess Size and WeightLegal Abstract Statute regulating...

  7. Colorado - C.R.S. 42-4-510 (3), Permits for Excess Size and Weight...

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: Colorado - C.R.S. 42-4-510 (3), Permits for Excess Size and WeightLegal Abstract Statute outlining...

  8. Geek-Up[6.24.11]: Dust-sized 'Dragonfly' Device and Tiny Microvalves

    Broader source: Energy.gov [DOE]

    A dust-size "dragonfly-inspired" device -- which won a Sandia Lab design contest -- may ultimately enable the creation of tiny microvalves for experiments in biological research laboratories and medical facilities.

  9. Energy Department Helps Manufacturers of Small and Mid-Size Wind Turbines Meet Certification Requirements

    Broader source: Energy.gov [DOE]

    NREL has awarded four subcontracts to manufacturers of small and mid-size wind turbines to improve their turbine design and manufacturing processes while reducing costs and improving efficiency as...

  10. InGaN Quantum Dot Fabrication using Quantum Size Controlled

    Office of Scientific and Technical Information (OSTI)

    Photoelectrochemical Etching. (Conference) | SciTech Connect InGaN Quantum Dot Fabrication using Quantum Size Controlled Photoelectrochemical Etching. Citation Details In-Document Search Title: InGaN Quantum Dot Fabrication using Quantum Size Controlled Photoelectrochemical Etching. Abstract not provided. Authors: Fischer, Arthur Joseph ; Xiao, Xiaoyin ; Lu, Ping ; Tsao, Jeffrey Yeenien ; Wang, George T. ; Koleske, Daniel ; Subramania, Ganapathi Subramanian ; Coltrin, Michael Elliott

  11. HVAC Right-Sizing Part 1: Calculating Loads | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Right-Sizing Part 1: Calculating Loads HVAC Right-Sizing Part 1: Calculating Loads This webinar, presented by IBACOS (a Building America Research Team) will highlight the key criteria required to create accurate heating and cooling load calculations, following the guidelines of the Air Conditioning Contractors of America (ACCA) Manual J version 8 PDF icon webinar_hvac_calculatingloads_20110428.pdf More Documents & Publications 2014-08-28 Issuance: Energy Conservation Standards for Packaged

  12. Spontaneous radiation of a finite-size dipole emitter in hyperbolic media

    SciTech Connect (OSTI)

    Poddubny, Alexander N.; Belov, Pavel A.; Kivshar, Yuri S.

    2011-08-15

    We study the radiative decay and Purcell effect for a finite-size dipole emitter placed in a homogeneous uniaxial medium. We demonstrate that the radiative rate is strongly enhanced when the signs of the medium longitudinal and transverse dielectric constants are opposite, and that the isofrequency contour corresponds to a hyperbolic medium. We reveal that the Purcell enhancement factor remains finite even in the absence of losses and that it depends on the emitter size.

  13. Effect of particle size and doses of olivine addition on carbon dioxide

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    sequestration during anaerobic digestion of sewage sludge at ambient and mesophilic temperatures | Argonne National Laboratory particle size and doses of olivine addition on carbon dioxide sequestration during anaerobic digestion of sewage sludge at ambient and mesophilic temperatures Title Effect of particle size and doses of olivine addition on carbon dioxide sequestration during anaerobic digestion of sewage sludge at ambient and mesophilic temperatures Publication Type Journal Article

  14. Quantum-Size-Controlled Photoelectrochemical Fabrication of Epitaxial InGaN

    Office of Scientific and Technical Information (OSTI)

    Quantum Dots (Journal Article) | SciTech Connect Quantum-Size-Controlled Photoelectrochemical Fabrication of Epitaxial InGaN Quantum Dots Citation Details In-Document Search Title: Quantum-Size-Controlled Photoelectrochemical Fabrication of Epitaxial InGaN Quantum Dots Authors: Xiao, Xiaoyin ; Fischer, Arthur J. ; Wang, George T. ; Lu, Ping ; Koleske, Daniel D. ; Coltrin, Michael E. ; Wright, Jeremy B. ; Liu, Sheng ; Brener, Igal ; Subramania, Ganesh ; Tsao, Jeffrey Y. Publication Date:

  15. Dynamical Expansion of HII Regions From Ultracompact to Compact Sizes in

    Office of Scientific and Technical Information (OSTI)

    Turbulent, Self-Gravitating Molecular Clouds (Technical Report) | SciTech Connect Technical Report: Dynamical Expansion of HII Regions From Ultracompact to Compact Sizes in Turbulent, Self-Gravitating Molecular Clouds Citation Details In-Document Search Title: Dynamical Expansion of HII Regions From Ultracompact to Compact Sizes in Turbulent, Self-Gravitating Molecular Clouds Authors: Low, Mordecai-Mark Mac ; Toraskar, Jayashree ; /Amer. Museum Natural Hist. ; Oishi, Jeffrey S. ; /Amer.

  16. Method and apparatus for controlled size distribution of gel microspheres formed from aqueous dispersions

    DOE Patents [OSTI]

    Ryon, Allen D.; Haas, Paul A.; Vavruska, John S.

    1984-01-01

    The present invention is directed to a method and apparatus for making a population of dense, closely size-controlled microspheres by sol-gel procedures wherein said microspheres are characterized by a significant percentage of said population being within a predetermined, relatively narrow size range. Microsphere populations thus provided are useful in vibratory-packed processes for nuclear fuels to be irradiated in LWR- and FBR-type nuclear reactors.

  17. Small- and Medium-Size Building Automation and Control System Needs:

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Scoping Study | Department of Energy Small- and Medium-Size Building Automation and Control System Needs: Scoping Study Small- and Medium-Size Building Automation and Control System Needs: Scoping Study Emerging Technologies Project for the 2013 Building Technologies Office's Program Peer Review PDF icon emrgtech05_brambley_040213.pdf More Documents & Publications Advanced Building Control Solutions PNNL: VOLTTRON Commercialization (CBI/ET Open Call) - 2015 Peer Review U.S. Industrial

  18. Strain and particle size of palladium powders by time-of-flight neutron diffraction

    SciTech Connect (OSTI)

    Lawson, A.C.; Conant, J.W.; Talcott, C.L.; David, M.A.; Vaninetti, J.; Goldstone, J.A.; Williams, A.; Von Dreele, R.B.; Roof, R.B.; Hitterman, R.L.; Richardson, J.W. Jr.; Faber, J. Jr.

    1989-01-01

    We have determined the strain and particle size for several samples of palladium powder by time-of-flight neutron powder diffraction on two different diffractometers and by x-ray powder diffraction. The results are compared and found to be in fair agreement. The time-of-flight method gives good enough precision to reveal deficiencies in the simple models used for strain and particle size line broadening. 6 refs., 4 figs., 2 tabs.

  19. Role of grain size on the martensitic transformation and ultra-fast

    Office of Scientific and Technical Information (OSTI)

    superelasticity in shape memory alloys (Journal Article) | DOE PAGES Role of grain size on the martensitic transformation and ultra-fast superelasticity in shape memory alloys This content will become publicly available on May 30, 2017 « Prev Next » Title: Role of grain size on the martensitic transformation and ultra-fast superelasticity in shape memory alloys Authors: Morrison, Keith R. ; Cherukara, Mathew J. ; Kim, Hojin ; Strachan, Alejandro Publication Date: 2015-08-01 OSTI

  20. Apparatus and method for the determination of grain size in thin films

    DOE Patents [OSTI]

    Maris, Humphrey J

    2000-01-01

    A method for the determination of grain size in a thin film sample comprising the steps of measuring first and second changes in the optical response of the thin film, comparing the first and second changes to find the attenuation of a propagating disturbance in the film and associating the attenuation of the disturbance to the grain size of the film. The second change in optical response is time delayed from the first change in optical response.

  1. Apparatus and method for the determination of grain size in thin films

    DOE Patents [OSTI]

    Maris, Humphrey J

    2001-01-01

    A method for the determination of grain size in a thin film sample comprising the steps of measuring first and second changes in the optical response of the thin film, comparing the first and second changes to find the attenuation of a propagating disturbance in the film and associating the attenuation of the disturbance to the grain size of the film. The second change in optical response is time delayed from the first change in optical response.

  2. Low pressure shock initiation of porous HMX for two grain size distributions and two densities

    SciTech Connect (OSTI)

    Gustavsen, R.L.; Sheffield, S.A.; Alcon, R.R.

    1995-09-01

    Shock initiation measurements have been made on granular HMX (octotetramethylene tetranitrainine) for two particle size distributions and two densities. Samples were pressed to either 65% or 73% of crystal density from fine ({approx} 10 {mu}m grain size) and coarse (broad distribution of grain sizes peaking at {approx} 150 {mu}m) powders. Planar shocks of 0.2--1 GPa were generated by impacting gas gun driven projectiles on plastic targets containing the HMX. Wave profiles were measured at the input and output of the {approx} 3.9 mm thick HMX layer using electromagnetic particle velocity gauges. The initiation behavior for the two particle size distributions was very different. The coarse HMX began initiating at input pressures as low as 0.5 GPa. Transmitted wave profiles showed relatively slow reaction with most of the buildup occurring at the shock front. In contrast, the fine particle HMX did not begin to initiate at pressures below 0.9 GPa. When the fine powder did react, however, it did so much faster than the coarse HMX. These observations are consistent with commonly held ideas about bum rates being correlated to surface area, and initiation thresholds being correlated with the size and temperature of the hot spots created by shock passage. For each size, the higher density pressings were less sensitive than the lower density pressings.

  3. Heat exchanger sizing for vertical closed-loop ground-source heat pumps

    SciTech Connect (OSTI)

    Cane, R.L.D.; Clemes, S.B.; Morrison, A.; Hughes, P.J.

    1995-12-31

    A building energy simulation program has been used in conjunction with a ground heat exchanger sizing algorithm to develop general guidelines on how to size vertical ground heat exchangers for closed-loop ground-source heat pump systems in large buildings. The analysis considered three commercial building types of varying size with different internal loads and heat pump efficiencies. Each building variation was simulated in seven cities, three in the US and four in Canada. The ground heat exchanger sizing algorithm has been previously validated against actual system data. The analysis results showed a strong correlation between heat exchanger length required and annual energy rejected to the ground, if the building was cooling-dominated, or annual energy extracted from the ground, if the building was heating-dominated. The resulting sizing guidelines recommend hour-by-hour energy analysis to determine the energy extracted from and rejected to the building water loop. Using this information the designer will have available easy-to-use, accurate sizing guidelines that should result in more economical installations than those based on previous ``rule of thumb`` guidelines.

  4. Measurements of Aerosol Charge and Size Distribution for Graphite, Gold, Palladium, and Silver Nanoparticles

    SciTech Connect (OSTI)

    Simones, Matthew P.; Gutti, Veera R.; Meyer, Ryan M.; Loyalka, Sudarshan K.

    2011-11-01

    The role of charge on aerosol evolution and hence the nuclear source term has been an issue of interest, and there is a need for both experimental techniques and modeling for quantifying this role. Our focus here is on further exploration of a tandem differential mobility analyzer (TDMA) technique to simultaneously measure both the size and charge (positive, negative and neutral) dependent aerosol distributions. We have generated graphite, gold, silver, and palladium nanoparticles (aerosol) using a spark generator. We measure the electrical mobility-size distributions for these aerosols using a TDMA, and from these data we deduce the full charge-size distributions. We observe asymmetry in the particle size distributions for negative and positive charges. This asymmetry could have a bearing on the dynamics of charged aerosols, indicating that the assumption of symmetry for size distributions of negatively and positively charged particles in source term simulations may not be always appropriate. Also, the experimental technique should find applications in measurements of aerosol rate processes that are affected by both particle charge and size (e.g. coagulation, deposition, resuspension), and hence in modeling and simulation of the nuclear source term.

  5. Using the depth-velocity-size diagram to interpret equilibrium bed configurations in river flows

    SciTech Connect (OSTI)

    Southard, J.B. (Massachusetts Institute of Technology, Cambridge, MA (USA))

    1990-05-01

    Data from flume studies that report equilibrium bed configuration as well as water temperature, flow depth, flow velocity, and sediment size were used to develop the best approximation to the relationships among the various bed phases (ripples, dunes, lower regime plane bed, upper regime plane bed, and antidunes) in a three-axis graph (depth-velocity-size diagram) with dimensionless measures of mean flow depth, mean flow velocity, and sediment size along the axis. Relationships are shown in a series of depth-velocity and velocity-size sections through the diagram. Boundaries between bed-phase stability fields are drawn as surfaces that minimize, misplacement of data points. A large subset of the data, for which reliable values of bed shear stress are reported, was also used to represent the stability relationships in a graph of dimensionless boundary shear stress against dimensionless sediment size, but with results less useful for fluvial flow interpretation. The diagram covers about one order of magnitude in flow depth. To be useful for river flows, the diagram must be extrapolated in flow depth by about one more order of magnitude, but this is not a serious problem for approximate work. The depth-velocity-size diagram permits prediction of equilibrium bed configuration in river flows when the approximate flow depth and mean flow velocity are known. Because the diagram is essentially dimensionless, the effect of water temperature (via the fluid viscosity) on the bed configuration is easily accounted for by use of the diagram.

  6. Mechanistic study of methanol synthesis from CO₂ and H₂ on a modified model Mo₆S₈ cluster

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Cheng; Liu, Ping

    2015-01-12

    We report the methanol synthesis from CO₂ and H₂ on metal (M = K, Ti, Co, Rh, Ni, and Cu)-modified model Mo₆S₈ catalyst using density functional theory (DFT). The results show that the catalytic behavior of a Mo₆S₈ cluster is changed significantly due to the modifiers, via the electron transfer from M to Mo₆S₈ and therefore the reduction of the Mo cation (ligand effect) and the direct participation of M in the reaction (ensemble effect) to promote some elementary steps. With the most positively charged modifier, the ligand effect in the case of K-Mo₆S₈ is the most obvious among themore » systems studied; however it cannot compete with the ensemble effect, which plays a dominate role in determining activity via the electrostatic attraction in particular to stabilize the CHxOy species adsorbed at the Mo sites of Mo₆S₈. In comparison, the ligand effect is weaker and the ensemble effect is more important when the other modifiers are used. In addition, the modifiers also vary the optimal reaction pathway for methanol synthesis on Mo₆S₈, ranging from the reverse water-gas shift (RWGS) + CO hydrogenation as that of Mo₆S₈ to the formate pathway. Finally, K is able to accelerate the methanol synthesis on Mo₆S₈ the most; while the promotion by Rh is relatively small. Using the modifiers like Ti, Co, Ni, and Cu, the activity of Mo₆S₈ is decreased instead. The relative stability between *HCOO and *HOCO is identified as a descriptor to capture the variation in mechanism and scales well with the estimated activity. Our study not only provides better understanding of the reaction mechanism and actives on the modified Mo₆S₈, but also predicts some possible candidates, which can be used a promoter to facilitate the CH₃OH synthesis on Mo sulfides.« less

  7. Visible light activated photocatalytic behaviour of rare earth modified commercial TiO{sub 2}

    SciTech Connect (OSTI)

    Tobaldi, D.M.; Seabra, M.P.; Labrincha, J.A.

    2014-02-01

    Highlights: RE gave more surface hydroxyl groups attached to the photocatalyst's surface. RE gave the modified and fired samples a high specific surface area. Photocatalytic activity was assessed in gassolid phase under visible-light exposure. Thermal treated RE-TiO{sub 2}s showed a superior visible-light photocatalytic activity. La-TiO{sub 2} was the best performing photocatalyst. - Abstract: A commercial TiO{sub 2} nanopowder, Degussa P25, was modified with several rare earth (RE) elements in order to extend its photocatalytic activity into the visible range. The mixtures were prepared via solid-state reaction of the precursor oxides, and thermally treated at high temperature (900 and 1000 C), with the aim of investigating the photocatalytic activity of the thermally treated samples. This thermal treatment was chosen for a prospective application as a surface layer in materials that need to be processed at high temperatures. The photocatalytic activity (PCA) of the samples was assessed in gassolid phase monitoring the degradation of isopropanol (IPA) under visible-light irradiation. Results showed that the addition of the REs lanthanum, europium and yttrium to TiO{sub 2} greatly improved its photocatalytic activity, despite the thermal treatment, because of the presence of more surface hydroxyl groups attached to the photocatalyst's surface, together with a higher specific surface area (SSA) of the modified and thermally treated samples, with regard to the unmodified and thermally treated Degussa P25. The samples doped with La, Eu and Y all had excellent PCA under visible-light irradiation, even higher than the untreated Degussa P25 reference sample, despite their thermal treatment at 900 C, with lanthanum producing the best results (i.e. the La-, Eu- and Y-TiO{sub 2} samples, thermally treated at 900 C, had, respectively, a PCA equal to 26, 27 and 18 ppm h{sup ?1} in terms of acetone formation versus 15 ppm h{sup ?1} for the 900 C thermally treated Degussa P25). On the other hand, CeTiO{sub 2}s had no significant photocatalytic activity.

  8. A generalized force-modified potential energy surface (G-FMPES) for mechanochemical simulations

    SciTech Connect (OSTI)

    Subramanian, Gopinath; Mathew, Nithin; Leiding, Jeffery A.

    2015-10-05

    We describe the modifications that a spatially varying external load produces on a Born-Oppenheimer potential energy surface (PES) by calculating static quantities of interest. The effects of the external loads are exemplified using electronic structure calculations (at the HF/6-31G** level) of two different molecules: ethane and hexahydro-1,3,5-trinitro-s-triazine (RDX). The calculated transition states and The Hessian matrices of stationary points show that spatially varying external loads shift the stationary points and modify the curvature of the PES, thereby affecting the harmonic transition rates by altering both the energy barrier as well as the prefactor. The harmonic spectra of both molecules are blue-shifted with increasing compressive “pressure.” Some stationary points on the RDX-PES disappear under application of the external load, indicating the merging of an energy minimum with a saddle point.

  9. Porous Vycor membranes modified by chemical vapor deposition of boron nitride for gas separation

    SciTech Connect (OSTI)

    Levy, R.A.; Ravindranath, C.; Krasnoperov, L.N.; Opyrchal, J.; Ramos, E.S.

    1997-01-01

    This study focuses on the characterization of porous Vycor membranes modified by chemical vapor deposition of boron nitride (B-N-C-H) for gas separation. The B-N-C-H films were deposited on mesoporous Vycor tubes using triethylamine borane complex and ammonia as precursors. The effects of deposition temperature and reactant flow geometry on permselectivity of membranes with respect to various permeant gases were investigated. High selectivities (up to 50,000) were achieved between small molecules (He, H{sub 2}) and large molecules (N{sub 2}, Ar, C{sub 6}H{sub 5}CH{sub 3}). The measured activation energies for the He and H{sub 2} permeability are 9.5 kcal/mol and 12 kcal/mol, respectively. The membranes synthesized at lower temperatures and lower ammonia flow rates showed good mechanical and chemical stability.

  10. Detection of Hydrogen Spillover in Palladium-Modified Activated Carbon Fibers During Hydrogen Adsorption

    SciTech Connect (OSTI)

    Contescu, Cristian I; Brown, Craig; Liu, Yun; Bhat, Vinay V; Gallego, Nidia C

    2009-01-01

    Palladium-modified activated carbon fibers (Pd-ACF) are being evaluated for adsorptive hydrogen storage at near-ambient conditions because of their enhanced hydrogen uptake in comparison to Pd-free activated carbon fibers (ACF). The net uptake enhancement (at room temperature and 20 bar) is in excess of the amount corresponding to formation of Pd hydride, and is usually attributed to hydrogen spillover. In this paper, inelastic neutron scattering was used to demonstrate the formation of new C-H bonds in Pd-containing activated carbon fibers after exposure to hydrogen at 20 oC and 1.6 MPa, at the expense of physisorbed H2. This finding is a post-factum proof of the atomic nature of H species formed in presence of a Pd catalyst, and of their subsequent spillover and binding to the carbon support. Chemisorption of hydrogen may explain the reduction in hydrogen uptake from first to second adsorption cycle.

  11. High sensitive formaldehyde graphene gas sensor modified by atomic layer deposition zinc oxide films

    SciTech Connect (OSTI)

    Mu, Haichuan; Zhang, Zhiqiang; Wang, Keke; Xie, Haifen, E-mail: hfxie@ecust.edu.cn [Department of Physics, School of Science, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237 (China); Zhao, Xiaojing; Liu, Feng [Department of Physics, Shanghai Normal University, 100 Guilin Road, Shanghai 200234 (China)

    2014-07-21

    Zinc oxide (ZnO) thin films with various thicknesses were fabricated by Atomic Layer Deposition on Chemical Vapor Deposition grown graphene films and their response to formaldehyde has been investigated. It was found that 0.5?nm ZnO films modified graphene sensors showed high response to formaldehyde with the resistance change up to 52% at the concentration of 9 parts-per-million (ppm) at room temperature. Meanwhile, the detection limit could reach 180 parts-per-billion (ppb) and fast response of 36?s was also obtained. The high sensitivity could be attributed to the combining effect from the highly reactive, top mounted ZnO thin films, and high conductive graphene base network. The dependence of ZnO films surface morphology and its sensitivity on the ZnO films thickness was also investigated.

  12. A source of PCB contamination in modified high-volume air samplers

    SciTech Connect (OSTI)

    Basu, I.; O'Dell, J.M.; Arnold, K.; Hites, R.A.

    2000-02-01

    Modified Anderson High Volume (Hi-Vol) air samplers are widely used for the collection of semi-volatile organic compounds (such as PCBs) from air. The foam gasket near the main air flow path in these samplers can become contaminated with PCBs if the sampler or the gasket is stored at a location with high indoor air PCB levels. Once the gasket is contaminated, it releases PCBs back into the air stream during sampling, and as a result, incorrectly high air PCB concentrations are measured. This paper presents data demonstrating this contamination problem using measurements from two Integrated Atmospheric Deposition Network sites: one at Sleeping Bear Dunes on Lake Michigan and the other at Point Petre on Lake Ontario. The authors recommend that these gaskets be replaced by Teflon tape and that the storage history of each sampler be carefully tracked.

  13. On the Sensitivity of Neutrino Telescopes to a Modified Dispersion Relation

    SciTech Connect (OSTI)

    Bustamante, M.; Gago, A. M.; Bazo, J. L.; Miranda, O. G.

    2008-07-02

    We consider a modified dispersion relation and its effect on the flavour ratios of high-energy neutrinos originated at distant astrophysical sources such as active galactic nuclei. This dispersion relation arise naturally in different new physics (NP) effects such as violation of CPT invariance, of the equivalence principle and of Lorentz invariance. It is a common notion in the literature that by using the flux of high-energy neutrinos expected from distant astrophysical sources, the sensitivity to possible NP effects may be improved beyond the current bounds. However, performing a realistic analysis that takes into account the expected number of events in future neutrino telescopes, we find that the average detected flavour ratios with and without the inclusion of new physics have essentially the same value, making difficult to obtain an improved bound for this type of new physics.

  14. A Mechanistic Study of Chemically Modified Inorganic Membranes for Gas and Liquid Separations

    SciTech Connect (OSTI)

    Way, J Douglas

    2011-01-21

    This final report will summarize the progress made during the period August 1, 1993 - October 31, 2010 with support from DOE grant number DE-FG03-93ER14363. The objectives of the research have been to investigate the transport mechanisms in micro- and mesoporous, metal oxide membranes and to examine the relationship between the microstructure of the membrane, the membrane surface chemistry, and the separation performance of the membrane. Examples of the membrane materials under investigation are the microporous silica hollow fiber membrane manufactured by PPG Industries, chemically modified mesoporous oxide membranes, and polymer membranes containing microporous oxides (mixed matrix membranes). Analytical techniques such as NMR, FTIR and Raman spectroscopy, thermal analysis, and gas adsorption were used to investigate membrane microstructure and to probe the chemical interactions occurring at the gas-membrane interface.

  15. A generalized force-modified potential energy surface (G-FMPES) for mechanochemical simulations

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Subramanian, Gopinath; Mathew, Nithin; Leiding, Jeffery A.

    2015-10-05

    We describe the modifications that a spatially varying external load produces on a Born-Oppenheimer potential energy surface (PES) by calculating static quantities of interest. The effects of the external loads are exemplified using electronic structure calculations (at the HF/6-31G** level) of two different molecules: ethane and hexahydro-1,3,5-trinitro-s-triazine (RDX). The calculated transition states and The Hessian matrices of stationary points show that spatially varying external loads shift the stationary points and modify the curvature of the PES, thereby affecting the harmonic transition rates by altering both the energy barrier as well as the prefactor. The harmonic spectra of both molecules aremore » blue-shifted with increasing compressive “pressure.” Some stationary points on the RDX-PES disappear under application of the external load, indicating the merging of an energy minimum with a saddle point.« less

  16. Ultrahigh-energy cosmic-ray bounds on nonbirefringent modified Maxwell theory

    SciTech Connect (OSTI)

    Klinkhamer, F. R.; Risse, M.

    2008-01-01

    A particularly simple Lorentz-violating modification of the Maxwell theory of photons maintains gauge invariance, CPT, and renormalization. This modified Maxwell theory, coupled to standard Dirac particles, involves 19 dimensionless 'deformation parameters'. Ten of these parameters lead to birefringence and are already tightly constrained by astrophysics. New bounds on the remaining nine nonbirefringent parameters can be obtained from the absence of vacuum Cherenkov radiation for ultrahigh-energy cosmic rays (UHECRs). Using selected UHECR events recorded at the Pierre Auger Observatory and assigning pseudorandom directions (i.e., assuming large-scale isotropy), Cherenkov bounds are found at the 10{sup -18} level, which improve considerably upon current laboratory bounds. Future UHECR observations may reduce these Cherenkov bounds to the 10{sup -23} level.

  17. Centrifugal contactor modified for end stage operation in a multistage system

    DOE Patents [OSTI]

    Jubin, Robert T.

    1990-01-01

    A cascade formed of a plurality of centrifugal contactors useful for countercurrent solvent extraction processes such as utilizable for the reprocessing of nuclear reactor fuels is modified to permit operation in the event one or both end stages of the cascade become inoperative. Weir assemblies are connected to each of the two end stages by suitable conduits for separating liquids discharged from an inoperative end stage based upon the weight of the liquid phases uses in the solvent extraction process. The weir assembly at one end stage is constructed to separate and discharge the heaviest liquid phase while the weir assembly at the other end stage is constructed to separate and discharge the lightest liquid phase. These weir assemblies function to keep the liquid discharge from an inoperative end stages on the same weight phase a would occur from an operating end stage.

  18. Preparation of transition metal nanoparticles and surfaces modified with (co)polymers synthesized by RAFT

    DOE Patents [OSTI]

    McCormick, III, Charles L.; Lowe, Andrew B.; Sumerlin, Brent S.

    2011-12-27

    A new, facile, general one-phase method of generating thiol-functionalized transition metal nanoparticles and surfaces modified by (co)polymers synthesized by the RAFT method is described. The method includes the steps of forming a (co)polymer in aqueous solution using the RAFT methodology, forming a colloidal transition metal precursor solution from an appropriate transition metal; adding the metal precursor solution or surface to the (co)polymer solution, adding a reducing agent into the solution to reduce the metal colloid in situ to produce the stabilized nanoparticles or surface, and isolating the stabilized nanoparticles or surface in a manner such that aggregation is minimized. The functionalized surfaces generated using these methods can further undergo planar surface modifications, such as functionalization with a variety of different chemical groups, expanding their utility and application.

  19. Preparation of transition metal nanoparticles and surfaces modified with (CO) polymers synthesized by RAFT

    DOE Patents [OSTI]

    McCormick, III, Charles L.; Lowe, Andrew B.; Sumerlin, Brent S.

    2006-10-25

    A new, facile, general one-phase method of generating thiol-functionalized transition metal nanoparticles and surface modified by (co)polymers synthesized by the RAFT method is described. The method includes the steps of forming a (co)polymer in aqueous solution using the RAFT methodology, forming a collidal transition metal precursor solution from an appropriate transition metal; adding the metal precursor solution or surface to the (co)polymer solution, adding a reducing agent into the solution to reduce the metal colloid in situ to produce the stabilized nanoparticles or surface, and isolating the stabilized nanoparticles or surface in a manner such that aggregation is minimized. The functionalized surfaces generated using these methods can further undergo planar surface modifications, such as fuctionalization with a variety of different chemical groups, expanding their utility and application.

  20. Preparation of transition metal nanoparticles and surfaces modified with (CO)polymers synthesized by RAFT

    DOE Patents [OSTI]

    McCormick, III., Charles L.; Lowe, Andrew B.; Sumerlin, Brent S.

    2006-11-21

    A new, facile, general one-phase method of generating thio-functionalized transition metal nanoparticles and surfaces modified by (co)polymers synthesized by the RAFT method is described. The method includes the stops of forming a (co)polymer in aqueous solution using the RAFT methodology, forming a colloidal transition metal precursor solution from an appropriate transition metal; adding the metal precursor solution or surface to the (co)polymer solution, adding a reducing agent into the solution to reduce the metal colloid in situ to produce the stabilized nanoparticles or surface, and isolating the stabilized nanoparticles or surface in a manner such that aggregation is minimized. The functionalized surfaces generated using these methods can further undergo planar surface modifications, such as functionalization with a variety of different chemical groups, expanding their utility and application.

  1. Low-Potential Stable NADH Detection at Carbon-Nanotube-Modified Glassy Carbon Electrodes

    SciTech Connect (OSTI)

    Musameh, Mustafa; Wang, Joseph; Merkoci, Arben; Lin, Yuehe )

    2002-11-22

    Carbon-nanotube (CNT) modified glassy-carbon electrodes exhibiting strong and stable electrocatalytic response toward NADH are described. A substantial (490 mV) decrease in the overvoltage of the NADH oxidation reaction (compared to ordinary carbon electrodes) is observed using single-wall and multi-wall carbon-nanotube coatings, with oxidation starting at ca.?0.05V (vs. Ag/AgCl; pH 7.4). Furthermore, the NADH amperometric response of the coated electrodes is extremely stable, with 96 and 90% of the initial activity remaining after 60min stirring of 2x10-4M and 5x10-3M NADH solutions, respectively (compared to 20 and 14% at the bare surface). The CNT-coated electrodes thus allow highly-sensitive, low-potential, stable amperometric sensing. Such ability of carbon-nanotubes to promote the NADH electron-transfer reaction suggests great promise for dehydrogenase-based amperometric biosensors.

  2. Phase Behavior and Domain Size in Sphingomyelin-Containing Lipid Bilayers

    SciTech Connect (OSTI)

    Petruzielo, Robin S [Cornell University; Heberle, Frederick A [ORNL; Drazba, Paul [ORNL; Katsaras, John [ORNL; Feigenson, Gerald [Cornell University

    2013-01-01

    Membrane raft size measurements are crucial to understanding the stability and functionality of rafts in cells. The challenge of accurately measuring raft size is evidenced by the disparate reports of domain sizes, which range from nanometers to microns for the ternary model membrane system sphingomyelin (SM)/1-palmitoyl-2-oleoyl-sn-glycero-3-phosphocholine (POPC)/cholesterol (Chol). Using F rster resonance energy transfer (FRET) and differential scanning calorimetry (DSC), we established phase diagrams for porcine brain SM (bSM)/dioleoyl-sn-glycero-3-phosphocholine (DOPC)/Chol and bSM/POPC/Chol at 15 and 25 C. By combining two techniqueswith different spatial sensitivities, namely FRET and small-angle neutron scattering (SANS),we have significantly narrowed the uncertainty in domain size estimates for bSM/POPC/Chol mixtures. Compositional trends in FRET data revealed coexisting domains at 15 and 25 C for bothmixtures, while SANS measurements detected no domain formation for bSM/POPC/Chol. Together these results indicate that liquid domains in bSM/POPC/Chol are between 2 and 7 nmin radius at 25 C: that is, domains must be on the order of the 2 6 nmF rster distance of the FRET probes, but smaller than the ~7 nm minimum cluster size detectable with SANS. However, for palmitoyl SM (PSM)/POPC/Chol at a similar composition, SANS detected coexisting liquid domains. This increase in domain size upon replacing the natural SMcomponent (which consists of amixture of chain lengths) with synthetic PSM, suggests a role for SM chain length in modulating raft size in vivo.

  3. TREATMENT OF PRODUCED OIL AND GAS WATERS WITH SURFACTANT-MODIFIED ZEOLITE

    SciTech Connect (OSTI)

    Lynn E. Katz; R.S. Bowman; E.J. Sullivan

    2003-11-01

    Co-produced water from the oil and gas industry accounts for a significant waste stream in the United States. It is by some estimates the largest single waste stream in the country, aside from nonhazardous industrial wastes. Characteristics of produced water include high total dissolved solids content, dissolved organic constituents such as benzene and toluene, an oil and grease component, and chemicals added during the oil-production process. While most of the produced water is disposed via reinjection, some must be treated to remove organic constituents before the water is discharged. Current treatment options are successful in reducing the organic content; however, they cannot always meet the levels of current or proposed regulations for discharged water. Therefore, an efficient, cost-effective treatment technology is needed. Surfactant-modified zeolite (SMZ) has been used successfully to treat contaminated ground water for organic and inorganic constituents. In addition, the low cost of natural zeolites makes their use attractive in water-treatment applications. This report summarizes the work and results of this four-year project. We tested the effectiveness of surfactant-modified zeolite (SMZ) for removal of BTEX with batch and column experiments using waters with BTEX concentrations that are comparable to those of produced waters. The data from our experimental investigations showed that BTEX sorption to SMZ can be described by a linear isotherm model, and competitive effects between compounds were not significant. The SMZ can be readily regenerated using air stripping. We field-tested a prototype SMZ-based water treatment system at produced water treatment facilities and found that the SMZ successfully removes BTEX from produced waters as predicted by laboratory studies. When compared to other existing treatment technologies, the cost of the SMZ system is very competitive. Furthermore, the SMZ system is relatively compact, does not require the storage of potentially hazardous chemicals, and could be readily adapted to an automated system.

  4. Structural resistance of chemically modified 1-D nanostructured titanates in inorganic acid environment

    SciTech Connect (OSTI)

    Marinkovic, Bojan A.; Fredholm, Yann C.; Morgado, Edisson

    2010-10-15

    Sodium containing one-dimensional nanostructured layered titanates (1-D NSLT) were produced both from commercial anatase powder and Brazilian natural rutile mineral sands by alkali hydrothermal process. The 1-D NSLT were chemically modified with proton, cobalt or iron via ionic exchange and all products were additionally submitted to intensive inorganic acid aging (pH = 0.5) for 28 days. The morphology and crystal structure transformations of chemically modified 1-D NSLT were followed by transmission electron microscopy, powder X-ray diffraction, selected area electron diffraction and energy dispersive spectroscopy. It was found that the original sodium rich 1-D NSLT and cobalt substituted 1-D NSLT were completely converted to rutile nanoparticles, while the protonated form was transformed in a 70%-30% (by weight) anatase-rutile nanoparticles mixture, very similar to that of the well-known TiO{sub 2}-photocatalyst P25 (Degussa). The iron substituted 1-D NSLT presented better acid resistance as 13% of the original structure and morphology remained, the rest being converted in rutile. A significant amount of remaining 1-D NSLT was also observed after the acid treatment of the product obtained from rutile sand. The results showed that phase transformation of NSLT into titanium dioxide polymorph in inorganic acid conditions were controllable by varying the exchanged cations. Finally, the possibility to transform, through acid aging, 1-D NSLT obtained from Brazilian natural rutile sand into TiO{sub 2}-polymorphs was demonstrated for the first time to the best of authors' knowledge, opening path for producing TiO{sub 2}-nanoproducts with different morphologies through a simple process and from a low cost precursor.

  5. SIZE DISTRIBUTION AND RATE OF PRODUCTION OF AIRBORNE PARTICULATE MATTER GENERATED DURING METAL CUTTING

    SciTech Connect (OSTI)

    M.A. Ebadian, Ph.D.; S.K. Dua, Ph.D., C.H.P.; Hillol Guha, Ph.D.

    2001-01-01

    During deactivation and decommissioning activities, thermal cutting tools, such as plasma torch, laser, and gasoline torch, are used to cut metals. These activities generate fumes, smoke and particulates. These airborne species of matter, called aerosols, may be inhaled if suitable respiratory protection is not used. Inhalation of the airborne metallic aerosols has been reported to cause ill health effects, such as acute respiratory syndrome and chromosome damage in lymphocytes. In the nuclear industry, metals may be contaminated with radioactive materials. Cutting these metals, as in size reduction of gloveboxes and tanks, produces high concentrations of airborne transuranic particles. Particles of the respirable size range (size < 10 {micro}m) deposit in various compartments of the respiratory tract, the fraction and the site in the respiratory tract depending on the size of the particles. The dose delivered to the respiratory tract depends on the size distribution of the airborne particulates (aerosols) and their concentration and radioactivity/toxicity. The concentration of airborne particulate matter in an environment is dependent upon the rate of their production and the ventilation rate. Thus, measuring aerosol size distribution and generation rate is important for (1) the assessment of inhalation exposures of workers, (2) the selection of respiratory protection equipment, and (3) the design of appropriate filtration systems. Size distribution of the aerosols generated during cutting of different metals by plasma torch was measured. Cutting rates of different metals, rate of generation of respirable mass, as well as the fraction of the released kerf that become respirable were determined. This report presents results of these studies. Measurements of the particles generated during cutting of metal plates with a plasma arc torch revealed the presence of particles with mass median aerodynamic diameters of particles close to 0.2 {micro}m, arising from condensation of vaporized material and subsequent rapid formation of aggregates. Particles of larger size, resulting from ejection of melted material or fragments from the cutting zone, were also observed. This study presents data regarding the metal cutting rate, particle size distribution, and their generation rate, while using different cutting tools and metals. The study shows that respirable particles constitute only a small fraction of the released kerf.

  6. The impact of size distribution assumptions in a bulk one-moment microphysics scheme on simulated surface precipitation and storm dynamics during a low-topped supercell case in Belgium

    SciTech Connect (OSTI)

    Van Weverberg, K.; VanLipzig, N. P. M.; Delobbe, L.

    2011-04-01

    In this research the impact of modifying the size distribution assumptions of the precipitating hydrometeors in a bulk one-moment microphysics scheme on simulated surface precipitation and storm dynamics has been explored for long-lived low-topped supercells in Belgium. It was shown that weighting the largest precipitating ice species of the microphysics scheme to small graupel results in an increase of surface precipitation because of counteracting effects. On the one hand, the precipitation formation process slowed down, resulting in lower precipitation efficiency. On the other hand, latent heat release associated with freezing favored more intense storms. In contrast to previous studies finding decreased surface precipitation when graupel was present in the microphysics parameterization, storms were rather shallow in the authors simulations. This left little time for graupel sublimation. The impact of size distribution assumptions of snow was found to be small, but more realistic size distribution assumptions of rain led to the strongest effect on surface precipitation. Cold pools shrunk because of weaker rain evaporation at the cold pool boundaries, leading to a decreased surface rain area.

  7. Size dependent compressibility of nano-ceria: Minimum near 33 nm

    SciTech Connect (OSTI)

    Rodenbough, Philip P.; Song, Junhua; Chan, Siu-Wai; Walker, David; Clark, Simon M.; Kalkan, Bora

    2015-04-20

    We report the crystallite-size-dependency of the compressibility of nanoceria under hydrostatic pressure for a wide variety of crystallite diameters and comment on the size-based trends indicating an extremum near 33 nm. Uniform nano-crystals of ceria were synthesized by basic precipitation from cerium (III) nitrate. Size-control was achieved by adjusting mixing time and, for larger particles, a subsequent annealing temperature. The nano-crystals were characterized by transmission electron microscopy and standard ambient x-ray diffraction (XRD). Compressibility, or its reciprocal, bulk modulus, was measured with high-pressure XRD at LBL-ALS, using helium, neon, or argon as the pressure-transmitting medium for all samples. As crystallite size decreased below 100 nm, the bulk modulus first increased, and then decreased, achieving a maximum near a crystallite diameter of 33 nm. We review earlier work and examine several possible explanations for the peaking of bulk modulus at an intermediate crystallite size.

  8. Ultrashort laser ablation of bulk copper targets: Dynamics and size distribution of the generated nanoparticles

    SciTech Connect (OSTI)

    Tsakiris, N.; Gill-Comeau, M.; Lewis, L. J.; Anoop, K. K.; Ausanio, G.; Bruzzese, R.; Amoruso, S.

    2014-06-28

    We address the role of laser pulse fluence on expansion dynamics and size distribution of the nanoparticles produced by irradiating a metallic target with an ultrashort laser pulse in a vacuum, an issue for which contrasting indications are present in the literature. To this end, we have carried out a combined theoretical and experimental analysis of laser ablation of a bulk copper target with ?50 fs, 800?nm pulses, in an interval of laser fluencies going from few to several times the ablation threshold. On one side, molecular dynamics simulations, with two-temperature model, describe the decomposition of the material through the analysis of the evolution of thermodynamic trajectories in the material phase diagram, and allow estimating the size distribution of the generated nano-aggregates. On the other side, atomic force microscopy of less than one layer nanoparticles deposits on witness plates, and fast imaging of the nanoparticles broadband optical emission provide the corresponding experimental characterization. Both experimental and numerical findings agree on a size distribution characterized by a significant fraction (?90%) of small nanoparticles, and a residual part (?10%) spanning over a rather large size interval, evidencing a weak dependence of the nanoparticles sizes on the laser pulse fluence. Numerical and experimental findings show a good degree of consistency, thus suggesting that modeling can realistically support the search for experimental methods leading to an improved control over the generation of nanoparticles by ultrashort laser ablation.

  9. Morphologically and size uniform monodisperse particles and their shape-directed self-assembly

    DOE Patents [OSTI]

    Collins, Joshua E.; Bell, Howard Y.; Ye, Xingchen; Murray, Christopher Bruce

    2015-11-17

    Monodisperse particles having: a single pure crystalline phase of a rare earth-containing lattice, a uniform three-dimensional size, and a uniform polyhedral morphology are disclosed. Due to their uniform size and shape, the monodisperse particles self assemble into superlattices. The particles may be luminescent particles such as down-converting phosphor particles and up-converting phosphors. The monodisperse particles of the invention have a rare earth-containing lattice which in one embodiment may be an yttrium-containing lattice or in another may be a lanthanide-containing lattice. The monodisperse particles may have different optical properties based on their composition, their size, and/or their morphology (or shape). Also disclosed is a combination of at least two types of monodisperse particles, where each type is a plurality of monodisperse particles having a single pure crystalline phase of a rare earth-containing lattice, a uniform three-dimensional size, and a uniform polyhedral morphology; and where the types of monodisperse particles differ from one another by composition, by size, or by morphology. In a preferred embodiment, the types of monodisperse particles have the same composition but different morphologies. Methods of making and methods of using the monodisperse particles are disclosed.

  10. Hydrocracking and hydroisomerization of long-chain alkanes and polyolefins over metal-promoted anion-modified transition metal oxides

    DOE Patents [OSTI]

    Venkatesh, Koppampatti R.; Hu, Jianli; Tierney, John W.; Wender, Irving

    2001-01-01

    A method of cracking a feedstock by contacting the feedstock with a metal-promoted anion-modified metal oxide catalyst in the presence of hydrogen gas. The metal oxide of the catalyst is one or more of ZrO.sub.2, HfO.sub.2, TiO.sub.2 and SnO.sub.2, and the feedstock is principally chains of at least 20 carbon atoms. The metal-promoted anion-modified metal oxide catalyst contains one or more of Pt, Ni, Pd, Rh, Ir, Ru, (Mn & Fe) or mixtures of them present between about 0.2% to about 15% by weight of the catalyst. The metal-promoted anion-modified metal oxide catalyst contains one or more of SO.sub.4, WO.sub.3, or mixtures of them present between about 0.5% to about 20% by weight of the catalyst.

  11. Field investigation of the relationship between battery size and PV system performance

    SciTech Connect (OSTI)

    Stevens, J.; Kratochvil, J. [Sandia National Labs., Albuquerque, NM (United States); Harrington, S. [Ktech Corp., Albuquerque, NM (United States)

    1993-07-01

    Four photovoltaic-powered lighting systems were installed in a National Forest Service campground in June of 1991. These systems have identical arrays, loads and charge controllers. The only difference was in the rated capacity of the battery bank for each system. The battery banks all use the same basic battery as a building block with the four systems utilizing either one battery, two batteries, three batteries or four batteries. The purpose of the experiment is to examine the effect of the various battery sizes on the ability of the system to charge the battery, energy available to the load, and battery lifetime. Results show an important trend in system performance concerning the impact of charge controllers on the relation between array size and battery size which results in an inability to achieve the days of battery storage originally designed for.

  12. The effects of size reduction techniques on TCLP analysis of solidified mixed waste

    SciTech Connect (OSTI)

    Thiel, R.D.; McLaurin, A.W.; Kochen, R.L.

    1993-07-01

    The Rocky Flats Plant (RFP) generates and stores mixed wastes that are subject to regulation under the Resource Conservation and Recovery Act (RCRA) Land Disposal Restrictions (LDR). Low level mixed wastes at RFP are destined for disposal at the Nevada Test Site (NTS), and thus must meet stringent NTS Waste Acceptance Criteria (WAC), including free liquids, dispersible solids, and Toxicity Characteristic Leaching Procedure (TCLP) requirements. TCLP requires size reduction of the waste form to less than 0.95 centimeters. This can be accomplished by cutting, crushing, or grinding. These classic size reduction methods have the effect of exposing more surface area of the waste. Stabilization technologies under investigation at RFP include polymer encapsulation by co-extruding the waste with low density polyethylene and microwave melting. The objective of this study is to evaluate the effects of different size reduction methods on TCLP results for polyethylene-encapsulated and microwave melted surrogate waste.

  13. Density-functional errors in ionization potential with increasing system size

    SciTech Connect (OSTI)

    Whittleton, Sarah R.; Sosa Vazquez, Xochitl A.; Isborn, Christine M.; Johnson, Erin R.

    2015-05-14

    This work investigates the effects of molecular size on the accuracy of density-functional ionization potentials for a set of 28 hydrocarbons, including series of alkanes, alkenes, and oligoacenes. As the system size increases, delocalization error introduces a systematic underestimation of the ionization potential, which is rationalized by considering the fractional-charge behavior of the electronic energies. The computation of the ionization potential with many density-functional approximations is not size-extensive due to excessive delocalization of the incipient positive charge. While inclusion of exact exchange reduces the observed errors, system-specific tuning of long-range corrected functionals does not generally improve accuracy. These results emphasize that good performance of a functional for small molecules is not necessarily transferable to larger systems.

  14. Measurement of the soot concentration and soot particle sizes in propane oxygen flames

    SciTech Connect (OSTI)

    Bockhorn, H.; Fetting, F.; Meyer, U.; Reck, R.; Wannemacher, G.

    1981-01-01

    Soot concentrations and particle sizes were measured by light scattering and probe measurements in the burnt gas region of atmospheric pressure propane-oxygen flames and propane-oxygen flames to which hydrogen or ammonia were added. The results show that the soot concentrations in propane-oxygen flames, to which hydrogen is added are lower compared to propane-oxygen flames. The decrease of soot concentration is much stronger when ammonia is added. Associated with the reduction of soot concentration is a reduction of mean particle size of the soot particles and a lower breadth of the particle size distributions. Electron micrographs of soot particles from the probe measurements showed that soot particles from flames with high soot concentrations (propane oxygen flames) are aggregates with chain or cluster structure while the structure of the particles from flames with lower soot concentration (propane oxygen flames with hydrogen or ammonia added) is more compact. 24 refs.

  15. Measurement of particle size, velocity and temperature in the plasma spray coating process

    SciTech Connect (OSTI)

    Fincke, J.R.; Swank, W.D.

    1991-01-01

    The quality and uniformity of coatings fabricated by the plasma spray process is controlled by the condition of the particles on impact. In this work a measurement technique for simultaneously obtaining particle size, velocity, and temperature is used to characterize the particle spray field. Particle size and velocity are obtained from a combination laser particle sizing system and laser Doppler velocimeter (LDV). The particle temperature is determined by a two-color pyrometer technique and the relative particle number density is derived from the data rate. The fraction of unheated or unprocessed particles which result from temperature and velocity fluctuations is also obtained. This fraction can approach 10% by mass of the total particle flow. 17 refs., 10 figs.

  16. Controlling atomistic processes on Pb films via quantum size effects and lattice rotation

    SciTech Connect (OSTI)

    Binz, Steven

    2012-06-14

    The two main techniques used to record the data in this dissertation were Spot Profile Analysis - Low Energy Electron Diffraction (SPA-LEED) and Scanning Tunneling Microscopy (STM). A specific data analysis technique for LEED data called G(S) curves is described in depth. G(S) curves can provide a great deal of structural information about the surface; including step heights, island size, and island separation. The effects of quantum size effects (QSE) on the diffusion and critical island sizes of Pb and In on Pb #12;films are reported. Pb depositions on the 2D In phases {radical}3 and {radical}31 to see how the phases affect the Pb growth and its strong QSE are reported.

  17. Nano-sized particles, processes of making, compositions and uses thereof

    DOE Patents [OSTI]

    O'Brien, Stephen; Yin, Ming

    2012-05-22

    The present invention describes methods for preparing high quality nanoparticles, i.e., metal oxide based nanoparticles of uniform size and monodispersity. The nanoparticles advantageously comprise organic alkyl chain capping groups and are stable in air and in nonpolar solvents. The methods of the invention provide a simple and reproducible procedure for forming transition metal oxide nanocrystals, with yields over 80%. The highly crystalline and monodisperse nanocrystals are obtained directly without further size selection; particle size can be easily and fractionally increased by the methods. The resulting nanoparticles can exhibit magnetic and/or optical properties. These properties result from the methods used to prepare them. Also advantageously, the nanoparticles of this invention are well suited for use in a variety of industrial applications, including cosmetic and pharmaceutical formulations and compositions.

  18. Size-effects on the optical properties of zirconium oxide thin films

    SciTech Connect (OSTI)

    Ramana, C. V.; Vemuri, R. S.; Fernandez, I.; Campbell, A. L.

    2009-12-07

    Zirconium oxide (ZrO{sub 2}) thin films with an average crystallite-size (L) ranging from 5 to 25 nm were grown by sputter deposition onto optical grade quartz substrates. The optical properties of grown ZrO{sub 2} films were evaluated using optical transmission and reflectance spectroscopic measurements. The size-effects were significant on the optical characteristics of ZrO{sub 2} films. The bandgap energy (E{sub g}) was found to increase from 5.78 to 6.07 eV with decreasing L values from 20 to 7 nm. A direct, linear inverse L-E{sub g} relationship found for ZrO{sub 2} films suggest that tuning optical properties for desired applications can be achieved by controlling the size.

  19. Consideration of Grain Size Distribution in the Diffusion of Fission Gas to Grain Boundaries

    SciTech Connect (OSTI)

    Paul C. Millett; Yongfeng Zhang; Michael R. Tonks; S. B. Biner

    2013-09-01

    We analyze the accumulation of fission gas on grain boundaries in a polycrystalline microstructure with a distribution of grain sizes. The diffusion equation is solved throughout the microstructure to evolve the gas concentration in space and time. Grain boundaries are treated as infinite sinks for the gas concentration, and we monitor the cumulative gas inventory on each grain boundary throughout time. We consider two important cases: first, a uniform initial distribution of gas concentration without gas production (correlating with post-irradiation annealing), and second, a constant gas production rate with no initial gas concentration (correlating with in-reactor conditions). The results show that a single-grain-size model, such as the Booth model, over predicts the gas accumulation on grain boundaries compared with a polycrystal with a grain size distribution. Also, a considerable degree of scatter, or variability, exists in the grain boundary gas accumulation when comparing all of the grain boundaries in the microstructure.

  20. A NEW RECIPE FOR OBTAINING CENTRAL VOLUME DENSITIES OF PRESTELLAR CORES FROM SIZE MEASUREMENTS

    SciTech Connect (OSTI)

    Tassis, Konstantinos; Yorke, Harold W. [Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA 91109 (United States)

    2011-07-10

    We propose a simple analytical method for estimating the central volume density of prestellar molecular cloud cores from their column density profiles. Prestellar cores feature a flat central part of the column density and volume density profiles of the same size indicating the existence of a uniform-density inner region. The size of this region is set by the thermal pressure force which depends only on the central volume density and temperature of the core, and can provide a direct measurement of the central volume density. Thus, a simple length measurement can immediately yield a central density estimate independent of any dynamical model for the core and without the need for fitting. Using the radius at which the column density is 90% of the central value as an estimate of the size of the flat inner part of the column density profile yields an estimate of the central volume density within a factor of two for well-resolved cores.