Sample records for mo magnesium oxide

  1. Solid Oxide Membrane (SOM) Electrolysis of Magnesium: Scale-Up...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oxide Membrane (SOM) Electrolysis of Magnesium: Scale-Up Research and Engineering for Light-Weight Vehicles Solid Oxide Membrane (SOM) Electrolysis of Magnesium: Scale-Up Research...

  2. An EPR study of ¹?O? on magnesium oxide 

    E-Print Network [OSTI]

    Wong, Ning-Bew

    1971-01-01T23:59:59.000Z

    AN EPR STUDY OF 0 ON MAGNESIUM OXIDE A Thesis by NING-SEW WONG Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE May 1971 Major Subject: Chemistry AN EPR... STUDY OF 0 ON MAGNESIUM OXIDE A Thesis by NING-BEN WONG Approved as to style and content by: (Chairman of Committe (Head of Department) (Member) (Member) May 1971 ABSTRACT 17 An EPR Study of 0 on Magnesium Oxide (May, 1971) Ning-Bew Wong, B...

  3. The oxidative dimerization of methane over promoted and unpromoted magnesium oxide monoliths

    E-Print Network [OSTI]

    Aigler, Jane Marie

    1989-01-01T23:59:59.000Z

    for the degree of MASTER OF SCIENCE May 1989 Major Subject: Chemistry THE OXIDATIVE DIMERIZATION OF METHANE OVER PROMOTED AND UNPROMOTED MAGNESIUM OxiDE MONOLITHS A Thesis by JANE MARIE AIGLER Approved as to style and content by: uns or (Chair of Commi... ee) os e (Member) nt ony (Member) a (Head of Department) May 1989 ABSTRACT The Oxidative Dimerization of Methane over Promoted and Unpromoted Magnesium Oxide Monoliths. (May 1989) Jane Marie Aigier, B. S. , Pennsylvania State University...

  4. Catalytic Properties of Supported MoO3 Catalysts for Oxidative Dehydrogenation of Propane

    E-Print Network [OSTI]

    Iglesia, Enrique

    Catalytic Properties of Supported MoO3 Catalysts for Oxidative Dehydrogenation of Propane Kaidong The effects of MoOx structure on propane oxidative dehydrogenation (ODH) rates and selectivity were examined with those obtained on MoOx/ZrO2. On MoOx/Al2O3 catalysts, propane turnover rate increased with increasing Mo

  5. Carbon dioxide adsorbents containing magnesium oxide suitable for use at high temperatures

    DOE Patents [OSTI]

    Mayorga, Steven Gerard (Allentown, PA); Weigel, Scott Jeffrey (Allentown, PA); Gaffney, Thomas Richard (Allentown, PA); Brzozowski, Jeffrey Richard (Macungie, PA)

    2001-01-01T23:59:59.000Z

    Adsorption of carbon dioxide from gas streams at temperatures in the range of 300 to 500.degree. C. is carried out with a solid adsorbent containing magnesium oxide, preferably promoted with an alkali metal carbonate or bicarbonate so that the atomic ratio of alkali metal to magnesium is in the range of 0.006 to 2.60. Preferred adsorbents are made from the precipitate formed on addition of alkali metal and carbonate ions to an aqueous solution of a magnesium salt. Atomic ratios of alkali metal to magnesium can be adjusted by washing the precipitate with water. Low surface area adsorbents can be made by dehydration and CO.sub.2 removal of magnesium hydroxycarbonate, with or without alkali metal promotion. The process is especially valuable in pressure swing adsorption operations.

  6. Effect of Mo Dispersion Size and Water Vapor on Oxidation of Two-Phase Directionally Solidified NiAl-9Mo In-Situ Composites

    SciTech Connect (OSTI)

    Brady, Michael P [ORNL] [ORNL; Bei, Hongbin [ORNL] [ORNL; Meisner, Roberta Ann [ORNL] [ORNL; Lance, Michael J [ORNL] [ORNL; Tortorelli, Peter F [ORNL] [ORNL

    2014-01-01T23:59:59.000Z

    Oxidation of two-phase NiAl-9Mo eutectics with 3 different growth rates/2nd phase Mo dispersion sizes were investigated at 900 C in air and air with 10% water vapor. Good oxidation resistance via alumina formation was observed in dry air, with Mo volatilization loss minimized by fine submicron Mo dispersions. However, extensive Mo volatilization and in-place internal oxidation of prior Mo phase regions was observed in wet air oxidation. Ramifications of this phenomenon for the development of multi-phase high-temperature alloys are discussed

  7. Oxidation Behavior and Chlorination Treatment to Improve Oxidation Resistance of Nb-Mo-Si-B Alloys

    SciTech Connect (OSTI)

    Vikas Behrani

    2004-12-19T23:59:59.000Z

    This thesis is written in an alternate format. The thesis is composed of a general introduction, two original manuscripts, and a general conclusion. References cited within each chapter are given at the end of each chapter. The general introduction starts with the driving force behind this research, and gives an overview of previous work on boron doped molybdenum silicides, Nb/Nb{sub 5}Si{sub 3} composites, boron modified niobium silicides and molybdenum niobium silicides. Chapter 2 focuses on the oxidation behavior of Nb-Mo-Si-B alloys. Chapter 3 contains studies on a novel chlorination technique to improve the oxidation resistance of Nb-Mo-Si-B alloys. Chapter 4 summarizes the important results in this study.

  8. Oxidation, Reduction, and Condensation of Alcohols over (MO3)3 (M=Mo, W) Nanoclusters

    SciTech Connect (OSTI)

    Fang, Zongtang; Li, Zhenjun; Kelley, Matthew S.; Kay, Bruce D.; Li, Shenggang; Hennigan, Jamie M.; Rousseau, Roger J.; Dohnalek, Zdenek; Dixon, David A.

    2014-10-02T23:59:59.000Z

    The reactions of deuterated methanol, ethanol, 1-propanol, 1-butanol, 2-propanol, 2-butanol and t-butanol over cyclic (MO3)3 (M = Mo, W) clusters were studied experimentally with temperature programmed desorption (TPD) and theoretically with coupled cluster CCSD(T) theory and density functional theory. The reactions of two alcohols per M3O9 cluster are required to provide agreement with experiment for D2O release, dehydrogenation and dehydration. The reaction begins with the elimination of water by proton transfers and forms an intermediate dialkoxy species which can undergo further reaction. Dehydration proceeds by a ? hydrogen transfer to a terminal M=O. Dehydrogenation takes place via an ? hydrogen transfer to an adjacent MoVI = O atom or a WVI metal center with redox involved for M = Mo and no redox for M = W. The two channels have comparable activation energies. H/D exchange to produce alcohols can take place after olefin is released or via the dialkoxy species depending on the alcohol and the cluster. The Lewis acidity of the metal center with WVI being larger than MoVI results in the increased reactivity of W3O9 over Mo3O9 for dehydrogenation and dehydration.

  9. Photo-oxidation method using MoS2 nanocluster materials

    DOE Patents [OSTI]

    Wilcoxon, Jess P. (Albuquerque, NM)

    2001-01-01T23:59:59.000Z

    A method of photo-oxidizing a hydrocarbon compound is provided by dispersing MoS.sub.2 nanoclusters in a solvent containing a hydrocarbon compound contaminant to form a stable solution mixture and irradiating the mixture to photo-oxide the hydrocarbon compound. Hydrocarbon compounds of interest include aromatic hydrocarbon and chlorinated hydrocarbons. MoS.sub.2 nanoclusters with an average diameter less than approximately 10 nanometers are shown to be effective in decomposing potentially toxic aromatic and chlorinated hydrocarbons, such as phenol, pentachlorophenol, chlorinated biphenols, and chloroform, into relatively non-toxic compounds. The irradiation can occur by exposing the MoS.sub.2 nanoclusters and hydrocarbon compound mixture with visible light. The MoS.sub.2 nanoclusters can be introduced to the toxic hydrocarbons as either a MoS.sub.2 solution or deposited on a support material.

  10. Thermal Property Evaluation of Cerium Dioxide and Cerium Dioxide Magnesium Oxide Powders for Testing Plutonium

    SciTech Connect (OSTI)

    HOYT, R C

    2002-06-01T23:59:59.000Z

    Ceric oxide (CeO{sub 2}) and mixtures of CeO{sub 2} -magnesium oxide (MgO) have been utilized at the Plutonium Finishing Plant (PFP) as surrogate materials to represent plutonium dioxide (PuO{sub 2}) and impure PuO{sub 2} containing impurities such as MgO during verification tests on PFP's stabilization furnaces. Magnesium oxide was selected during furnace testing as the impurity of interest since much of the impure PuO{sub 2} to be stabilized and packaged at the PFP contains significant amounts of MgO from solution stabilization work. The issue being addressed in this study is whether or not heating the surrogate materials to 950 C adequately simulates heating PuO{sub 2} powders to 950 C. This paper evaluates some of the thermal properties of these oxides, as related to the heating of powders of these materials where heat transfer within the powders is governed primarily by conduction. Detailed heat transfer modeling was outside the scope of this paper.

  11. Oxidation and creep behavior of Mo*5*Si*3* based materials

    SciTech Connect (OSTI)

    Meyer, M.

    1995-06-19T23:59:59.000Z

    Mo{sub 5}Si{sub 3} shows promise as a high temperature creep resistant material. The high temperature oxidation resistance of Mo{sub 5}Si{sub 3} has been found to be poor, however, limiting its use in oxidizing atmospheres. Undoped Mo{sub 5}Si{sub 3} exhibits mass loss in the temperature range 800{degrees}-1200{degrees}C due to volatilization of molybdenum oxide, indicating that the silica scale does not provide a passivating layer. The addition of boron results in protective scale formation and parabolic oxidation kinetics in the temperature range of 1050{degrees}-1300{degrees}C. The oxidation rate of Mo{sub 5}Si{sub 3} was decreased by 5 orders of magnitude at 1200{degrees}C by doping with less than two weight percent boron. Boron doping eliminates catastrophic {open_quote}pest{close_quote} oxidation at 800{degrees}C. The mechanism for improved oxidation resistance of boron doped Mo{sub 5}Si{sub 3} is due to scale modification by boron.

  12. Oxidation, Reduction, and Condensation of Alcohols over (MO3...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Alcohols over (MO3)3 (MMo, W) Nanoclusters . Abstract: The reactions of deuterated methanol, ethanol, 1-propanol, 1-butanol, 2-propanol, 2-butanol and t-butanol over cyclic...

  13. Ultra-thin Titanium Oxide Films on Accession #s 00936, 00937,00938 Mo(112), Measured by XPS Technique: XPS

    E-Print Network [OSTI]

    Goodman, Wayne

    Ultra-thin Titanium Oxide Films on Accession #s 00936, 00937,00938 Mo(112), Measured by XPS preparation methods were employed to grow a well-ordered ultra-thin titanium oxide film on Mo(J (2), The tirst: photoemission; titanium oxide; tllin film PACS: 81.15.Gh. 79,60.Dp SPECIMEN DESCRIPTION (Accession #00936) Host

  14. Monolayers of MoS{sub 2} as an oxidation protective nanocoating material

    SciTech Connect (OSTI)

    Sen, H. Sener [UNAM-National Nanotechnology Research Center, Bilkent University, Ankara 06800 (Turkey); Sahin, H.; Peeters, F. M. [Department of Physics, University of Antwerp, 2610 Antwerp (Belgium); Durgun, E., E-mail: durgun@unam.bilkent.edu.tr [UNAM-National Nanotechnology Research Center, Bilkent University, Ankara 06800 (Turkey); Institute of Materials Science and Nanotechnology, Bilkent University, Ankara 06800 (Turkey)

    2014-08-28T23:59:59.000Z

    First-principle calculations are employed to investigate the interaction of oxygen with ideal and defective MoS{sub 2} monolayers. Our calculations show that while oxygen atoms are strongly bound on top of sulfur atoms, the oxygen molecule only weakly interacts with the surface. The penetration of oxygen atoms and molecules through a defect-free MoS{sub 2} monolayer is prevented by a very high diffusion barrier indicating that MoS{sub 2} can serve as a protective layer for oxidation. The analysis is extended to WS{sub 2} and similar coating characteristics are obtained. Our calculations indicate that ideal and continuous MoS{sub 2} and WS{sub 2} monolayers can improve the oxidation and corrosion-resistance of the covered surface and can be considered as an efficient nanocoating material.

  15. Method for production of magnesium

    DOE Patents [OSTI]

    Diaz, A.F.; Howard, J.B.; Modestino, A.J.; Peters, W.A.

    1998-07-21T23:59:59.000Z

    A continuous process for the production of elemental magnesium is described. Magnesium is made from magnesium oxide and a light hydrocarbon gas. In the process, a feed stream of the magnesium oxide and gas is continuously fed into a reaction zone. There the magnesium oxide and gas are reacted at a temperature of about 1400 C or greater in the reaction zone to provide a continuous product stream of reaction products, which include elemental magnesium. The product stream is continuously quenched after leaving the reaction zone, and the elemental magnesium is separated from other reaction products. 12 figs.

  16. Method for production of magnesium

    DOE Patents [OSTI]

    Diaz, Alexander F. (Cambridge, MA); Howard, Jack B. (Winchester, MA); Modestino, Anthony J. (Hanson, MA); Peters, William A. (Lexington, MA)

    1998-01-01T23:59:59.000Z

    A continuous process for the production of elemental magnesium is described. Magnesium is made from magnesium oxide and a light hydrocarbon gas. In the process, a feed stream of the magnesium oxide and gas is continuously fed into a reaction zone. There the magnesium oxide and gas are reacted at a temperature of about 1400.degree. C. or greater in the reaction zone to provide a continuous product stream of reaction products, which include elemental magnesium. The product stream is continuously quenched after leaving the reaction zone, and the elemental magnesium is separated from other reaction products.

  17. A practical grinding-assisted dry synthesis of nanocrystalline NiMoO{sub 4} polymorphs for oxidative dehydrogenation of propane

    SciTech Connect (OSTI)

    Chen Miao, E-mail: chenmiao@sinochem.com [Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433 (China); Zhejiang Chemical Industry Research Institute, Hangzhou 310023 (China); Wu Jialing; Liu Yongmei [Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433 (China); Cao Yong, E-mail: yongcao@fudan.edu.cn [Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433 (China); Guo Li [Zhejiang Chemical Industry Research Institute, Hangzhou 310023 (China); He Heyong; Fan Kangnian [Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433 (China)

    2011-12-15T23:59:59.000Z

    A practical two-stage reactive grinding-assisted pathway waste-free and cost-effective for the synthesis of NiMoO{sub 4} has been successfully developed. It was demonstrated that proper design in synthetic strategy for grinding plays a crucial role in determining the ultimate polymorph of NiMoO{sub 4}. Specifically, direct grinding (DG) of MoO{sub 3} and NiO rendered {alpha}-NiMoO{sub 4} after annealing, whereas sequential grinding (SG) of the two independently pre-ground oxides followed by annealing generated {beta}-NiMoO{sub 4} solid solution. Characterizations in terms of Raman and X-ray diffraction suggest the creation of {beta}-NiMoO{sub 4} precursor in the latter alternative is the key aspect for the formation of {beta}-NiMoO{sub 4}. The DG-derived {alpha}-NiMoO{sub 4} tested by oxidative dehydrogenation of propane exhibited superior activity in contrast to its analog synthesized via conventional coprecipitation. It is suggested that the favorable chemical composition facilely obtained via grinding in contrast to that by coprecipitation was essential for achieving a more selective production of propylene. - Graphical Abstract: Grinding-assisted synthesis of NiMoO{sub 4} offers higher and more reproducible activities in contrast to coprecipitation for oxidative dehydrogenation of propane, and both {alpha}- and {beta}-NiMoO{sub 4} can be synthesized. Highlights: Black-Right-Pointing-Pointer NiMoO{sub 4} was prepared through grinding-assisted pathway. Black-Right-Pointing-Pointer Direct/sequential grinding rendered {alpha}-, {beta}-NiMoO{sub 4}, respectively. Black-Right-Pointing-Pointer Grinding-derived {alpha}-NiMoO{sub 4} showed high and reproducible activity for oxidative dehydrogenation of propane.

  18. Occupancy and site distribution of europium in barium magnesium aluminate Eu Mossbauer spectroscopy

    E-Print Network [OSTI]

    Boolchand, Punit

    Occupancy and site distribution of europium in barium magnesium aluminate by 151 Eu Mo¨ssbauer Mo¨ssbauer spectroscopy. Analysis of the Mo¨ssbauer line shapes reveals a pentamodal or higher site

  19. Unveiling Structure-Property Relationships in Sr2Fe1.5Mo0.5O6-, an Electrode Material for Symmetric Solid Oxide Fuel Cells

    E-Print Network [OSTI]

    Carter, Emily A.

    Solid Oxide Fuel Cells Ana B. Munoz-García, Daniel E. Bugaris, Michele Pavone,,§ Jason P. Hodges, Ashfia oxide fuel cells (SOFCs) can convert a wide variety of fuels with simpler and cheaper designs than those oxide fuel cell electrode material Sr2Fe1.5Mo0.5O6- (SFMO). Rietveld refinement of powder neutron

  20. Synthesis and characterization of the ((CO)/sub 4/MoS/sub 2/MS/sub 2/)/sup 2 -/ and ((CO)/sub 4/MoS/sub 2/MS/sub 2/Mo(CO)/sub 4/)/sup 2 -/ ions (M = Mo, W): species containing group VI (6) metals in widely separated formal oxidation states

    SciTech Connect (OSTI)

    Rosenhein, L.D.; McDonald, J.W.

    1987-10-07T23:59:59.000Z

    Dinuclear and trinuclear sulfide-bridged complexes of the types (Et/sub 4/N)/sub 2/(MS/sub 4/(Mo(CO)/sub 4/)) and (Et/sub 4/N)/sub 2/(MS/sub 4/(Mo(CO)/sub 4/)/sub 2/) were prepared by the reaction of one or two equivalents of Mo(CO)/sub 4/(C/sub 7/H/sub 8/) (C/sub 7/H/sub 8/ = norbornadiene) with (Et/sub 4/N)/sub 2/(MS/sub 4/) (M = Mo, W) in methyl alcohol. Elemental analyses were consistent with the proposed formulae. Infrared spectra of all four compounds contain strong bands in the carbonyl region and low-energy bands characteristic of terminal and bridging M-S vibrations in linear, polynuclear, and sulfido-bridged species. Electrochemical experimental results support the hypothesis that the di- and trinuclear species contain both M(IV) (M = Mo, W) and Mo(0) oxidation states in the same complex. 33 references, 2 tables.

  1. Ethanol Conversion on Cyclic (MO3)3 (M = Mo, W) Clusters. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Conversion on Cyclic (MO3)3 (M Mo, W) Clusters. Ethanol Conversion on Cyclic (MO3)3 (M Mo, W) Clusters. Abstract: Oxides of molybdenum and tungsten are an important class of...

  2. Production of magnesium metal

    DOE Patents [OSTI]

    Blencoe, James G. (Harriman, TN) [Harriman, TN; Anovitz, Lawrence M. (Knoxville, TN) [Knoxville, TN; Palmer, Donald A. (Oliver Springs, TN) [Oliver Springs, TN; Beard, James S. (Martinsville, VA) [Martinsville, VA

    2010-02-23T23:59:59.000Z

    A process of producing magnesium metal includes providing magnesium carbonate, and reacting the magnesium carbonate to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The carbon dioxide is used as a reactant in a second process. In another embodiment of the process, a magnesium silicate is reacted with a caustic material to produce magnesium hydroxide. The magnesium hydroxide is reacted with a source of carbon dioxide to produce magnesium carbonate. The magnesium carbonate is reacted to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The invention further relates to a process for production of magnesium metal or a magnesium compound where an external source of carbon dioxide is not used in any of the reactions of the process. The invention also relates to the magnesium metal produced by the processes described herein.

  3. Methane Activation by Transition-Metal Oxides, MOx (M ) Cr, Mo, W; x ) 1, 2, 3) Xin Xu,# Francesco Faglioni, and William A. Goddard, III*

    E-Print Network [OSTI]

    Goddard III, William A.

    The efficient catalytic conversion of methane to petrochemical feedstocks and liquid fuels is a great technicalMethane Activation by Transition-Metal Oxides, MOx (M ) Cr, Mo, W; x ) 1, 2, 3) Xin Xu,# Francesco, 2002 Recent experiments on the dehydrogenation-aromatization of methane (DHAM) to form benzene using

  4. Production of magnesium metal

    DOE Patents [OSTI]

    Blencoe, James G. (Harriman, TN); Anovitz, Lawrence M. (Knoxville, TN); Palmer, Donald A. (Oliver Springs, TN); Beard, James S. (Martinsville, VA)

    2012-04-10T23:59:59.000Z

    A process of producing magnesium metal includes providing magnesium carbonate, and reacting the magnesium carbonate to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The carbon dioxide is used as a reactant in a second process. In another embodiment of the process, a magnesium silicate is reacted with a caustic material to produce magnesium hydroxide. The magnesium hydroxide is reacted with a source of carbon dioxide to produce magnesium carbonate. The magnesium carbonate is reacted to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The invention also relates to the magnesium metal produced by the processes described herein.

  5. Magnesium-phosphate-glass cements with ceramic-type properties

    DOE Patents [OSTI]

    Sugama, T.; Kukacka, L.E.

    1982-09-23T23:59:59.000Z

    Rapid setting magnesium phosphate (Mg glass) cementitious materials consisting of magnesium phosphate cement paste, polyborax and water-saturated aggregate, exhibits rapid setting and high early strength characteristics. The magnesium glass cement is prepared from a cation-leachable powder and a bivalent metallic ion-accepting liquid such as an aqueous solution of diammonium phosphate and ammonium polyphosphate. The cation-leachable powder includes a mixture of two different magnesium oxide powders processed and sized differently which when mixed with the bivalent metallic ion-accepting liquid provides the magnesium glass cement consisting primarily of magnesium ortho phosphate tetrahydrate, with magnesium hydroxide and magnesium ammonium phosphate hexahydrate also present. The polyborax serves as a set-retarder. The resulting magnesium mono- and polyphosphate cements are particularly suitable for use as a cementing matrix in rapid repair systems for deteriorated concrete structures as well as construction materials and surface coatings for fireproof structures.

  6. Magnesium phosphate glass cements with ceramic-type properties

    DOE Patents [OSTI]

    Sugama, Toshifumi (Mastic Beach, NY); Kukacka, Lawrence E. (Port Jefferson, NY)

    1984-03-13T23:59:59.000Z

    Rapid setting magnesium phosphate (Mg glass) cementitious materials consisting of magnesium phosphate cement paste, polyborax and water-saturated aggregate exhibiting rapid setting and high early strength characteristics. The magnesium glass cement is prepared from a cation-leachable powder and a bivalent metallic ion-accepting liquid such as an aqueous solution of diammonium phosphate and ammonium polyphosphate. The cation-leachable powder includes a mixture of two different magnesium oxide powders processed and sized differently which when mixed with the bivalent metallic ion-accepting liquid provides the magnesium glass cement consisting primarily of magnesium ortho phosphate tetrahydrate, with magnesium hydroxide and magnesium ammonium phosphate hexahydrate also present. The polyborax serves as a set-retarder. The resulting magnesium mono- and polyphosphate cements are particularly suitable for use as a cementing matrix in rapid repair systems for deteriorated concrete structures as well as construction materials and surface coatings for fireproof structures.

  7. az31 wrought magnesium: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MgOTiB2. Open Access Theses and Dissertations Summary: ??The stoichiometric Self-propagating High-temperature Synthesis (SHS) thermite reaction involving magnesium oxide...

  8. Better Catalysts through Microscopy: Nanometer Scale M1/M2 Intergrown Heterostructure in Mo-V-M Complex Oxides

    SciTech Connect (OSTI)

    He, Qian [ORNL; Woo, Jungwon [University of Cincinnati; Belianinov, Alex [ORNL; Guliants, Vadim V. [University of Cincinnati; Borisevich, Albina Y [ORNL

    2015-01-01T23:59:59.000Z

    In recent decades, catalysis research has transformed from the predominantly empirical field to one where it is possible to control the catalytic properties via characterization and modification of the atomic-scale active centers. Many phenomena in catalysis, such as synergistic effect, however, transcend the atomic scale and also require the knowledge and control of the mesoscale structure of the specimen to harness. In this paper, we use our discovery of atomic-scale epitaxial interfaces in molybdenum vanadium based complex oxide catalysts systems (i.e., MoVMO, M = Ta, Te, Sb, Nb, etc.) to achieve control of the mesoscale structure of this complex mixture of very different active phases. We can now achieve true epitaxial intergrowth between the catalytically critical M1 and M2 phases in the system that are hypothesized to have synergistic interactions, and demonstrate that the resulting catalyst has improved selectivity in the initial studies. Finally, we highlight the crucial role atomic scale characterization and mesoscale structure control play in uncovering the complex underpinnings of the synergistic effect in catalysis.

  9. Development of the ReaxFF reactive force field for mechanistic studies of catalytic selective oxidation processes on BiMoOx

    E-Print Network [OSTI]

    van Duin, Adri

    report the use of ReaxFF to study the activation and conversion of propene to acrolein by various metal acrolein. The propene reations on V2O5 occur at lower temperatures than on Bi2O3 or Bi2Mo3O12. The results-metal­ oxide (MMO) catalysts, accounts for the majority of the 8 billion pounds of acrolein produced annually

  10. Adsorption of propane, isopropyl, and hydrogen on cluster models of the M1 phase of Mo-V-Te-Nb-O mixed metal oxide catalyst

    SciTech Connect (OSTI)

    Govindasamy, Agalya [University of Cincinnati; Muthukumar, Kaliappan [University of Cincinnati; Yu, Junjun [University of Cincinnati; Xu, Ye [ORNL; Guliants, Vadim V. [University of Cincinnati

    2010-01-01T23:59:59.000Z

    The Mo-V-Te-Nb-O mixed metal oxide catalyst possessing the M1 phase structure is uniquely capable of directly converting propane into acrylonitrile. However, the mechanism of this complex eight-electron transformation, which includes a series of oxidative H-abstraction and N-insertion steps, remains poorly understood. We have conducted a density functional theory study of cluster models of the proposed active and selective site for propane ammoxidation, including the adsorption of propane, isopropyl (CH{sub 3}CHCH{sub 3}), and H which are involved in the first step of this transformation, that is, the methylene C-H bond scission in propane, on these active site models. Among the surface oxygen species, the telluryl oxo (Te=O) is found to be the most nucleophilic. Whereas the adsorption of propane is weak regardless of the MO{sub x} species involved, isopropyl and H adsorption exhibits strong preference in the order of Te=O > V=O > bridging oxygens > empty Mo apical site, suggesting the importance of TeO{sub x} species for H abstraction. The adsorption energies of isopropyl and H and consequently the reaction energy of the initial dehydrogenation of propane are strongly dependent on the number of ab planes included in the cluster, which points to the need to employ multilayer cluster models to correctly capture the energetics of surface chemistry on this mixed metal oxide catalyst.

  11. Y{sub 2}MoSe{sub 3}O{sub 12} and Y{sub 2}MoTe{sub 3}O{sub 12}: Solid-state synthesis, structure determination, and characterization of two new quaternary mixed metal oxides containing asymmetric coordination environment

    SciTech Connect (OSTI)

    Bang, Seong-eun; Pan, Zhi; Kim, Yeong Hun; Lee, Dong Woo; Ok, Kang Min, E-mail: kmok@cau.ac.kr

    2013-12-15T23:59:59.000Z

    Two new quaternary yttrium molybdenum selenium/tellurium oxides, Y{sub 2}MoSe{sub 3}O{sub 12} and Y{sub 2}MoTe{sub 3}O{sub 12} have been prepared by standard solid-state reactions using Y{sub 2}O{sub 3}, MoO{sub 3}, and SeO{sub 2} (or TeO{sub 2}) as reagents. Single-crystal X-ray diffraction was used to determine the crystal structures of the reported materials. Although both of the materials contain second-order Jahn–Teller (SOJT) distortive cations and are stoichiometrically similar, they reveal different structural features: while Y{sub 2}MoSe{sub 3}O{sub 12} shows a three-dimensional framework consisting of YO{sub 8}, MoO{sub 6}, and SeO{sub 3} groups, Y{sub 2}MoTe{sub 3}O{sub 12} exhibits a layered structure composed of YO{sub 8}, MoO{sub 4}, TeO{sub 3}, and TeO{sub 4} polyhedra. With the Mo{sup 6+} cations in Y{sub 2}MoSe{sub 3}O{sub 12}, a C{sub 3}-type intraoctahedral distortion toward a face is observed, in which the direction of the out-of-center distortion for Mo{sup 6+} is away from the oxide ligand linked to a Se{sup 4+} cation. The Se{sup 4+} and Te{sup 4+} cations in both materials are in asymmetric coordination environment attributed to the lone pairs. Elemental analyses, infrared spectroscopy, thermal analyses, intraoctahedral distortions, and dipole moment calculations for the compounds are also presented. - Graphical abstract: Y{sub 2}MoSe{sub 3}O{sub 12} reveals a three-dimensional framework consisting of YO{sub 8}, MoO{sub 6}, and SeO{sub 3} polyhedra, whereas Y{sub 2}MoTe{sub 3}O{sub 12} exhibits a layered structure composed of YO{sub 8}, MoO{sub 4}, TeO{sub 3}, and TeO{sub 4} groups. - Highlights: • Two new selenite and tellurite (Y{sub 2}MoQ{sub 3}O{sub 12}; Q=Se and Te) are synthesized. • Y{sub 2}MoQ{sub 3}O{sub 12} contain second-order Jahn–Teller distortive cations in asymmetric environments. • The intra-octahedral distortion of the Mo{sup 6+} is influenced by the Se{sup 4+}.

  12. Criticality Safety Scoping Study for the Transport of Weapons-Grade Mixed-Oxide Fuel Using the MO-1 Shipping Package

    SciTech Connect (OSTI)

    Dunn, M.E.; Fox, P.B.

    1999-05-01T23:59:59.000Z

    This report provides the criticality safety information needed for obtaining certification of the shipment of mixed-oxide (MOX) fuel using the MO-1 [USA/9069/B()F] shipping package. Specifically, this report addresses the shipment of non-weapons-grade MOX fuel as certified under Certificate of Compliance 9069, Revision 10. The report further addresses the shipment of weapons-grade MOX fuel using a possible Westinghouse fuel design. Criticality safety analysis information is provided to demonstrate that the requirements of 10 CFR S 71.55 and 71.59 are satisfied for the MO-1 package. Using NUREG/CR-5661 as a guide, a transport index (TI) for criticality control is determined for the shipment of non-weapons-grade MOX fuel as specified in Certificate of Compliance 9069, Revision 10. A TI for criticality control is also determined for the shipment of weapons-grade MOX fuel. Since the possible weapons-grade fuel design is preliminary in nature, this report is considered to be a scoping evaluation and is not intended as a substitute for the final criticality safety analysis of the MO-1 shipping package. However, the criticality safety evaluation information that is presented in this report does demonstrate the feasibility of obtaining certification for the transport of weapons-grade MOX lead test fuel using the MO-1 shipping package.

  13. Thermodynamics of the conversion of calcium and magnesium fluorides to the parent metal oxides and hydrogen fluoride

    SciTech Connect (OSTI)

    West, M.H.; Axler, K.M.

    1997-02-01T23:59:59.000Z

    The authors have used thermodynamic modeling to examine the reaction of calcium fluoride (CaF{sub 2}) and magnesium fluoride (MgF{sub 2}) with water (H{sub 2}O) at elevated temperatures. The calculated, equilibrium composition corresponds to the global free-energy minimum for the system. Optimum, predicted reaction temperatures and reactant mole ratios are reported for the recovery of hydrogen fluoride (HF), a valuable industrial feedstock. Complete conversion of MgF{sub 2} is found at 1,000 C and a ratio of 40 moles of H{sub 2}O per 1 mole of MgF{sub 2}. For CaF{sub 2}, temperatures as high as 1,400 C are required for complete conversion at a corresponding mole ratio of 40 moles of H{sub 2}O per 1 mole of CaF{sub 2}. The authors discuss the presence of minor chemical constituents as well as the stability of various potential container materials for the pyrohydrolysis reactions at elevated temperatures. CaF{sub 2} and MgF{sub 2} slags are available as wastes at former uranium production facilities within the Department of Energy Complex and other facilities regulated by the Nuclear Regulatory Commission. Recovery of HF from these wastes is an example of environmental remediation at such facilities.

  14. STEM HAADF Image Simulation of the Orthorhombic M1 Phase in the Mo-V-Nb-Te-O Propane Oxidation Catalyst

    SciTech Connect (OSTI)

    D Blom; X Li; S Mitra; T Vogt; D Buttrey

    2011-12-31T23:59:59.000Z

    A full frozen phonon multislice simulation of high angle annular dark field scanning transmission electron microscopy (HAADF STEM) images from the M1 phase of the Mo-V-Nb-Te-O propane oxidation catalyst has been performed by using the latest structural model obtained using the Rietveld method. Simulated contrast results are compared with experimental HAADF images. Good agreement is observed at ring sites, however significant thickness dependence is noticed at the linking sites. The remaining discrepancies between the model based on Rietveld refinement and image simulations indicate that the sampling of a small volume element in HAADF STEM and averaging elemental contributions of a disordered site in a crystal slab by using the virtual crystal approximation might be problematic, especially if there is preferential Mo/V ordering near the (001) surface.

  15. Ballistic performance comparison of monolayer transition metal dichalcogenide MX{sub 2} (M = Mo, W; X = S, Se, Te) metal-oxide-semiconductor field effect transistors

    SciTech Connect (OSTI)

    Chang, Jiwon; Register, Leonard F.; Banerjee, Sanjay K. [Microelectronics Research Center, The University of Texas at Austin, Austin, Texas 78758 (United States)

    2014-02-28T23:59:59.000Z

    We study the transport properties of monolayer MX{sub 2} (M?=?Mo, W; X?=?S, Se, Te) n- and p-channel metal-oxide-semiconductor field effect transistors (MOSFETs) using full-band ballistic non-equilibrium Green's function simulations with an atomistic tight-binding Hamiltonian with hopping potentials obtained from density functional theory. We discuss the subthreshold slope, drain-induced barrier lowering (DIBL), as well as gate-induced drain leakage (GIDL) for different monolayer MX{sub 2} MOSFETs. We also report the possibility of negative differential resistance behavior in the output characteristics of nanoscale monolayer MX{sub 2} MOSFETs.

  16. Oxidative Dehydrogenation of Propane over V2O5/MoO3/Al2O3 and V2O5/Cr2O3/Al2O3: Structural Characterization and Catalytic Function

    E-Print Network [OSTI]

    Bell, Alexis T.

    Oxidative Dehydrogenation of Propane over V2O5/MoO3/Al2O3 and V2O5/Cr2O3/Al2O3: Structural of stoichiometric reduction in H2, and the oxidative dehydrogenation of propane. VOx domains on Al2O3 modified The oxidative dehydrogenation (ODH) of propane provides an attractive route for the synthesis of propene.1

  17. Structures, Mechanisms, and Kinetics of Ammoxidation and Selective Oxidation of Propane Over the M2 Phase of MoVNbTeO Catalysts

    SciTech Connect (OSTI)

    Goddard, William A. [California Inst. of Technology (CalTech), Pasadena, CA (United States). Materials and Process Simulation Center; Liu, Lianchi [California Inst. of Technology (CalTech), Pasadena, CA (United States). Materials and Process Simulation Center; Mueller, Jonathan E. [California Inst. of Technology (CalTech), Pasadena, CA (United States). Materials and Process Simulation Center; Pudar, Sanja [California Inst. of Technology (CalTech), Pasadena, CA (United States). Materials and Process Simulation Center; Nielsen, Robert J. [California Inst. of Technology (CalTech), Pasadena, CA (United States). Materials and Process Simulation Center

    2011-07-01T23:59:59.000Z

    We report here first-principles-based predictions of the structures, mechanisms, and activation barriers for propane activation by the M2 phase of the MoVNbTeO multi-metal oxide catalysts capable of the direct conversion of propane to acrylonitrile. Our approach is to combine extensive quantum mechanical (QM) calculations to establish the mechanisms for idealized representations of the surfaces for these catalytic systems and then to modify the parameters in the ReaxFF reactive force field for molecular dynamics (MD) calculations to describe accurately the activation barriers and reaction mechanisms of the chemical reactions over complex mixed metal oxides. The parameters for ReaxFF are derived entirely from QM without the use of empirical data so that it can be applied to novel systems on which there is little or no data. To understand the catalysis in these systems it is essential to determine the surface structures that control the surface chemistry. High quality three-dimensional (3D) Rietveld structures are now available for the M1 and M2 phases of the MoVNbTeO catalysts.

  18. Effects of dietary potassium and sodium on magnesium and potassium balance in lambs

    E-Print Network [OSTI]

    Poe, Julie Hamilton

    1984-01-01T23:59:59.000Z

    . Molasses in a 1:1 mixture with magnesium oxide (Horvath et al. , 1967) or magnesium acetate (Ross and Gibson, 1969) has prevented low serum Mg levels. Magnesium alloy bullets have been designed to lodge in the reticulo-rumen and slowly release Mg...

  19. Method for magnesium sulfate recovery

    DOE Patents [OSTI]

    Gay, R.L.; Grantham, L.F.

    1987-08-25T23:59:59.000Z

    A method is described for obtaining magnesium sulfate substantially free from radioactive uranium from a slag containing the same and having a radioactivity level of at least about 7,000 pCi/gm. The slag is ground to a particle size of about 200 microns or less. The ground slag is then contacted with a concentrated sulfuric acid under certain prescribed conditions to produce a liquid product and a solid product. The particulate solid product and a minor amount of the liquid is then treated to produce a solid residue consisting essentially of magnesium sulfate substantially free of uranium and having a residual radioactivity level of less than 1,000 pCi/gm. In accordance with the preferred embodiment of the invention, a catalyst and an oxidizing agent are used during the initial acid treatment and a final solid residue has a radioactivity level of less than about 50 pCi/gm.

  20. Formation of chemically bonded ceramics with magnesium dihydrogen phosphate binder

    DOE Patents [OSTI]

    Wagh, Arun S.; Jeong, Seung-Young

    2004-08-17T23:59:59.000Z

    A new method for combining magnesium oxide, MgO, and magnesium dihydrogen phosphate to form an inexpensive compactible ceramic to stabilize very low solubility metal oxides, ashes, swarfs, and other iron or metal-based additives, to create products and waste forms which can be poured or dye cast, and to reinforce and strengthen the ceramics formed by the addition of fibers to the initial ceramic mixture.

  1. Climate VISION: Private Sector Initiatives: Magnesium: Resources...

    Office of Scientific and Technical Information (OSTI)

    Industry Associations International Magnesium Association Founded in 1943, the mission of the International Magnesium Association (IMA) is to promote the use of the metal magnesium...

  2. Process for converting magnesium fluoride to calcium fluoride

    DOE Patents [OSTI]

    Kreuzmann, A.B.; Palmer, D.A.

    1984-12-21T23:59:59.000Z

    This invention is a process for the conversion of magnesium fluoride to calcium fluoride whereby magnesium fluoride is decomposed by heating in the presence of calcium carbonate, calcium oxide or calcium hydroxide. Magnesium fluoride is a by-product of the reduction of uranium tetrafluoride to form uranium metal and has no known commercial use, thus its production creates a significant storage problem. The advantage of this invention is that the quality of calcium fluoride produced is sufficient to be used in the industrial manufacture of anhydrous hydrogen fluoride, steel mill flux or ceramic applications.

  3. Electrodeposition of magnesium and magnesium/aluminum alloys

    DOE Patents [OSTI]

    Mayer, Anton (Los Alamos, NM)

    1988-01-01T23:59:59.000Z

    Electrolytes and plating solutions for use in processes for electroplating and electroforming pure magnesium and alloys of aluminum and magnesium and also electrodeposition processes. An electrolyte of this invention is comprised of an alkali metal fluoride or a quaternary ammonium halide, dimethyl magnesium and/or diethyl magnesium, and triethyl aluminum and/or triisobutyl aluminum. An electrolyte may be dissolved in an aromatic hydrocarbon solvent to form a plating solution. The proportions of the component compounds in the electrolyte are varied to produce essentially pure magnesium or magnesium/aluminum alloys having varying selected compositions.

  4. Electrodeposition of magnesium and magnesium/aluminum alloys

    DOE Patents [OSTI]

    Mayer, A.

    1988-01-21T23:59:59.000Z

    Electrolytes and plating solutions for use in processes for electroplating and electroforming pure magnesium and alloys of aluminum and magnesium and also electrodeposition processes. An electrolyte of this invention is comprised of an alkali metal fluoride or a quaternary ammonium halide, dimethyl magnesium and/or diethyl magnesium, and triethyl aluminum and/or triisobutyl aluminum. An electrolyte may be dissolved in an aromatic hydrocarbon solvent to form a plating solution. The proportions of the component compounds in the electrolyte are varied to produce essentially pure magnesium or magnesium/aluminum alloys having varying selected compositions.

  5. Efficient One-Step Electrolytic Recycling of Low-Grade and Post-Consumer Magnesium Scrap

    SciTech Connect (OSTI)

    Adam C. Powell, IV

    2012-07-19T23:59:59.000Z

    Metal Oxygen Separation Technologies, Inc. (abbreviated MOxST, pronounced most) and Boston University (BU) have developed a new low-cost process for recycling post-consumer co-mingled and heavily-oxidized magnesium scrap, and discovered a new chemical mechanism for magnesium separations in the process. The new process, designated MagReGenTM, is very effective in laboratory experiments, and on scale-up promises to be the lowest-cost lowest-energy lowest-impact method for separating magnesium metal from aluminum while recovering oxidized magnesium. MagReGenTM uses as little as one-eighth as much energy as today's methods for recycling magnesium metal from comingled scrap. As such, this technology could play a vital role in recycling automotive non-ferrous metals, particularly as motor vehicle magnesium/aluminum ratios increase in order to reduce vehicle weight and increase efficiency.

  6. High temperature oxidation and NaCl-induced accelerated corrosion of hot-dip aluminized 9Cr-1Mo and 310 stainless steel 

    E-Print Network [OSTI]

    Tsaur, Charng-Cheng

    2005-02-17T23:59:59.000Z

    The behaviors of high temperature corrosion on hot-dip aluminized on 9Cr-1Mo and 310 stainless steels when catalyzed by NaCl and cyclic heating environment were studied experimentally. The corrosion behavior and morphological ...

  7. Effects of dietary potassium and sodium on magnesium and potassium balance in lambs 

    E-Print Network [OSTI]

    Poe, Julie Hamilton

    1984-01-01T23:59:59.000Z

    of magnesium oxide and trace mineralized salt with either molasses, cottonseed meal, dry sugarcane or steamed bone meal was consumed by lactating beef cows at a significantly (P), 05) higher level than magnesium oxide and trace mineralized salt (1:1) alone...EFFECTS OF DIETARY POTASSIUM AND SODIUM ON MAGNESIUM AND POTASSIUM BALANCE IN LAMBS A Thesis by JULIE HAMILTON POE Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER...

  8. MO. REV. MO. MAGNETIC CLEANLINESS GUIDELINES

    E-Print Network [OSTI]

    Rathbun, Julie A.

    MO. REV. MO. ATM-865 MAGNETIC CLEANLINESS GUIDELINES PAGE 1 Of 3 DATE 4/6/70 The purpose of this ATM is to update the ALSEP Magnetic Cleanliness Guidelines as delineated in A TM-294, dated 1 June. ATM-865 MAGNETIC CLEANLINESS GUIDELINES PAGE 2 OF 3 DATE 4/6/70 A review of the ALSEP Magnetic

  9. Synthesis of magnesium diboride by magnesium vapor infiltration process (MVIP)

    DOE Patents [OSTI]

    Serquis, Adriana C. (Los Alamos, NM); Zhu, Yuntian T. (Los Alamos, NM); Mueller, Frederick M. (Los Alamos, NM); Peterson, Dean E. (Los Alamos, NM); Liao, Xiao Zhou (Los Alamos, NM)

    2003-01-01T23:59:59.000Z

    A process of preparing superconducting magnesium diboride powder by heating an admixture of solid magnesium and amorphous boron powder or pellet under an inert atmosphere in a Mg:B ratio of greater than about 0.6:1 at temperatures and for time sufficient to form said superconducting magnesium diboride. The process can further include exposure to residual oxygen at high synthesis temperatures followed by slow cooling. In the cooling process oxygen atoms dissolved into MgB.sub.2 segregated to form nanometer-sized coherent Mg(B,O) precipitates in the MgB.sub.2 matrix, which can act as flux pinning centers.

  10. accumulate magnesium protoporphyrin: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    previous work that the exchangeable magnesium behaves similarly to exchangeable calcium. Daniel L. Gilbert 12 Constraining magnesium cycling in marine sediments using magnesium...

  11. Ethanol Conversion on Cyclic (MO3)3 (M = Mo, W) Clusters

    SciTech Connect (OSTI)

    Li, Zhenjun; Fang, Zongtang; Kelley, Matthew S.; Kay, Bruce D.; Rousseau, Roger J.; Dohnalek, Zdenek; Dixon, David A.

    2014-03-06T23:59:59.000Z

    Oxides of molybdenum and tungsten are an important class of catalytic materials with applications ranging from isomerization of alkanes and alkenes, partial oxidation of alcohols, selective reduction of nitric oxide and metathesis of alkeness.[1-10] While many studies have focused on the structure - function relationships, the nature of high catalytic activity is still being extensively investigated. There is a general agreement that the activity of supported MOx (M = W, Mo) catalysts is correlated with the presence of acidic sites, where the catalytic activity is strongly affected by the type of oxide support, delocalization of electron density, structures of tungsten oxide domains and presence of protons

  12. MoRu/Be multilayers for extreme ultraviolet applications

    DOE Patents [OSTI]

    Bajt, Sasa C. (Livermore, CA); Wall, Mark A. (Stockton, CA)

    2001-01-01T23:59:59.000Z

    High reflectance, low intrinsic roughness and low stress multilayer systems for extreme ultraviolet (EUV) lithography comprise amorphous layers MoRu and crystalline Be layers. Reflectance greater than 70% has been demonstrated for MoRu/Be multilayers with 50 bilayer pairs. Optical throughput of MoRu/Be multilayers can be 30-40% higher than that of Mo/Be multilayer coatings. The throughput can be improved using a diffusion barrier to make sharper interfaces. A capping layer on the top surface of the multilayer improves the long-term reflectance and EUV radiation stability of the multilayer by forming a very thin native oxide that is water resistant.

  13. High temperature oxidation and NaCl-induced accelerated corrosion of hot-dip aluminized 9Cr-1Mo and 310 stainless steel

    E-Print Network [OSTI]

    Tsaur, Charng-Cheng

    2005-02-17T23:59:59.000Z

    investigated by weight gain kinetics, metallographs, depths of attack, metal losses, and X-ray analyses. The results of 310SS deposited with salt mixtures show that weight gain kinetics in simple oxidation reveals a steady-state parabolic rate law after 3 hr...

  14. Re Effects on Phase Stability and Mechanical Properties of MoSS+Mo3Si+Mo5SiB2 alloys

    SciTech Connect (OSTI)

    Yang, Ying [ORNL; Bei, Hongbin [ORNL; George, Easo P [ORNL; Tiley, Jaimie [Air Force Research Laboratory, Wright-Patterson AFB, OH

    2013-01-01T23:59:59.000Z

    Because of their high melting points and good oxidation resistance Mo-Si-B alloys are of interest as potential ultrahigh-temperature structural materials. But their major drawbacks are poor ductility and fracture toughness at room temperature. Since alloying with Re has been suggested as a possible solution, we investigate here the effects of Re additions on the microstructure and mechanical properties of a ternary alloy with the composition Mo-12.5Si-8.5B (at.%). This alloy has a three-phase microstructure consisting of Mo solid-solution (MoSS), Mo3Si, and Mo5SiB2 and our results show that up to 8.4 at.% Re can be added to it without changing its microstructure or forming any brittle phase at 1600 C. Three-point bend tests using chevron-notched specimens showed that Re did not improve fracture toughness of the three-phase alloy. Nanoindentation performed on the MoSS phase in the three-phase alloy showed that Re increases Young s modulus, but does not lower hardness as in some Mo solid solution alloys. Based on our thermodynamic calculations and microstructural analyses, the lack of a Re softening effect is attributed to the increased Si levels in the Re-containing MoSS phase since Si is known to increase its hardness. This lack of softening is possibly why there is no Re-induced improvement in fracture toughness.

  15. Final Report on the Safety Assessment of Aluminum Silicate, Calcium Silicate, Magnesium Aluminum

    E-Print Network [OSTI]

    Ahmad, Sajjad

    Final Report on the Safety Assessment of Aluminum Silicate, Calcium Silicate, Magnesium Aluminum Silicate, Magnesium Silicate, Magnesium Trisilicate, Sodium Magnesium Silicate, Zirconium Silicate, Attapulgite, Bentonite, Fuller's Earth, Hectorite, Kaolin, Lithium Magnesium Silicate, Lithium Magnesium

  16. Synthesis of superconducting magnesium diboride objects

    DOE Patents [OSTI]

    Finnemore, Douglas K. (Ames, IA); Canfield, Paul C. (Ames, IA); Bud'ko, Sergey L. (Ames, IA); Ostenson, Jerome E. (Ames, IA); Petrovic, Cedomir (Ames, IA); Cunningham, Charles E. (Ames, IA); Lapertot, Gerard (Grenoble, FR)

    2003-08-15T23:59:59.000Z

    A process to produce magnesium diboride objects from boron objects with a similar form is presented. Boron objects are reacted with magnesium vapor at a predetermined time and temperature to form magnesium diboride objects having a morphology similar to the boron object's original morphology.

  17. Synthesis Of Superconducting Magnesium Diboride Objects.

    DOE Patents [OSTI]

    Finnemore, Douglas K. (Ames, IA); Canfield, Paul C. (Ames, IA); Bud'ko, Sergey L. (Ames, IA); Ostenson, Jerome E. (Ames, IA); Petrovic, Cedomir (Ames, IA); Cunningham, Charles E. (Ames, IA); Lapertot, Gerard (Grenoble, FR)

    2003-07-08T23:59:59.000Z

    A process to produce magnesium diboride objects from boron objects with a similar form is presented. Boron objects are reacted with magnesium vapor at a predetermined time and temperature to form magnesium diboride objects having a morphology similar to the boron object's original morphology.

  18. Switchable mirrors based on nickel-magnesium films

    SciTech Connect (OSTI)

    Richardson,Thomas J.; Slack, Jonathan L.; Armitage, Robert D.; Kostecki, Robert; Farangis, Baker; Rubin, Michael D.

    2001-01-16T23:59:59.000Z

    A new type of electrochromic mirror electrode based on reversible uptake of hydrogen in nickel magnesium alloy films is reported. Thin,magnesium-rich Ni-Mg films prepared on glass substrates by cosputtering from Ni and Mg targets are mirror-like in appearance and have low visible transmittance. Upon exposure to hydrogen gas or on reduction in alkaline electrolyte, the films take up hydrogen and become transparent. When hydrogen is removed, the mirror properties are recovered. The transition is believed to result from reversible formation of Mg2NiH4 and MgH2. A thin overlayer of palladium was found to enhance the kinetics of hydrogen insertion and extraction,and to protect the metal surface against oxidation.

  19. Electrical transport behavior of nonstoichiometric magnesium-zinc ferrite

    SciTech Connect (OSTI)

    Ghatak, S. [Department of Physics, National Institute of Technology, Deemed University, Mahatma Gandhi Avenue, Durgapur 713209, West Bengal (India)] [Department of Physics, National Institute of Technology, Deemed University, Mahatma Gandhi Avenue, Durgapur 713209, West Bengal (India); Sinha, M. [Department of Physics, University of Burdwan, Golapbag, Burdwan 713104, West Bengal (India)] [Department of Physics, University of Burdwan, Golapbag, Burdwan 713104, West Bengal (India); Meikap, A.K., E-mail: meikapnitd@yahoo.com [Department of Physics, National Institute of Technology, Deemed University, Mahatma Gandhi Avenue, Durgapur 713209, West Bengal (India); Pradhan, S.K. [Department of Physics, University of Burdwan, Golapbag, Burdwan 713104, West Bengal (India)] [Department of Physics, University of Burdwan, Golapbag, Burdwan 713104, West Bengal (India)

    2010-08-15T23:59:59.000Z

    This paper presents the direct current conductivity, alternate current conductivity and dielectric properties of nonstoichiometric magnesium-zinc ferrite below room temperature. The frequency exponent (s) of conductivity shows an anomalous temperature dependency. The magnitude of the temperature exponent (n) of dielectric permittivity strongly depends on frequency and its value decreases with increasing frequency. The grain boundary contribution is dominating over the grain contribution in conduction process and the temperature dependence of resistance due to grain and grain boundary contribution exhibits two activation regions. The ferrite shows positive alternating current magnetoconductivity. The solid state processing technique was used for the preparation of nanocrystalline ferrite powder from oxides of magnesium, zinc and iron. The X-ray diffraction methods were used in determining the structure and composition of obtained ferrite, while multimeter, impedance analyzer, liquid nitrogen cryostat and electromagnet were used in the study of conducting and dielectric properties of ferrite.

  20. Substrate and method for the formation of continuous magnesium diboride and doped magnesium diboride wire

    DOE Patents [OSTI]

    Suplinskas, Raymond J. (Haverhill, MA); Finnemore, Douglas (Ames, IA); Bud'ko, Serquei (Ames, IA); Canfield, Paul (Ames, IA)

    2007-11-13T23:59:59.000Z

    A chemically doped boron coating is applied by chemical vapor deposition to a silicon carbide fiber and the coated fiber then is exposed to magnesium vapor to convert the doped boron to doped magnesium diboride and a resultant superconductor.

  1. Climate VISION: Private Sector Initiatives: Magnesium

    Office of Scientific and Technical Information (OSTI)

    Leading magnesium producers and casting companies are working with the U.S. Environmental Protection Agency (EPA) to alleviate the global environmental threat of climate...

  2. Coordination Chemistry in magnesium battery electrolytes: how...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a safe, cost-effective, and high energy density technology for large scale energy storage. However, the development of magnesium battery has been hindered by the limited...

  3. Climate VISION: Private Sector Initiatives: Magnesium: Resources...

    Office of Scientific and Technical Information (OSTI)

    Washington in February of 2002. The paper briefly describes the issues surrounding climate change and the Magnesium Industry, and gives an overview of the SF6 Emission...

  4. Climate VISION: Private Sector Initiatives: Magnesium: Resources...

    Office of Scientific and Technical Information (OSTI)

    Plant Assessments Greenhouse Gas Protocol (PDF 190 KB) Download Acrobat Reader Paper written by Bill Palmer, Cheminfo Services, Inc. Molten magnesium and its alloys are volatile...

  5. Climate VISION: Private Sector Initiatives: Magnesium: Work Plans

    Office of Scientific and Technical Information (OSTI)

    Magnesium Association has developed a work plan for achieving the industry's Climate VISION commitment. Read the International Magnesium Association Work Plan (PDF 92 KB)...

  6. Local environment and composition of magnesium gallium layered...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    environment and composition of magnesium gallium layered double hydroxides determined from solid-state 1H and 71Ga NMR Local environment and composition of magnesium gallium...

  7. Tissue magnesium and calcium concentration in relation to magnesium and calcium intake in rats 

    E-Print Network [OSTI]

    Pinkham, Carrie Stanton

    1987-01-01T23:59:59.000Z

    , gestation, and lactation. The diets fed were as follows: low magnesium (200 mg Ng/kg and 5, 000 mg Ca/kg); calcium? supplemented (1, 200 mg Ng/kg and 16, 000 mg Ca/kg); low magnesium, calcium-supplemented (200 mg Ng/kg and 16, 000 mg Ca/kg); and control... was affected adversely by magnesium restriction; litter size was smaller and mortality rates the highest in animals fed the 1 cw magnesium diet. Pups of the magnesium ? restricted dams were lightest on Days 3 and 6 of lactation, while the pups of the dams...

  8. 9 Cr-- 1 Mo steel material for high temperature application

    DOE Patents [OSTI]

    Jablonski, Paul D; Alman, David; Dogan, Omer; Holcomb, Gordon; Cowen, Christopher

    2012-11-27T23:59:59.000Z

    One or more embodiments relates to a high-temperature, titanium alloyed, 9 Cr-1 Mo steel exhibiting improved creep strength and oxidation resistance at service temperatures up to 650.degree. C. The 9 Cr-1 Mo steel has a tempered martensite microstructure and is comprised of both large (0.5-3 .mu.m) primary titanium carbides and small (5-50 nm) secondary titanium carbides in a ratio of. from about 1:1.5 to about 1.5:1. The 9 Cr-1 Mo steel may be fabricated using exemplary austenizing, rapid cooling, and tempering steps without subsequent hot working requirements. The 9 Cr-1 Mo steel exhibits improvements in total mass gain, yield strength, and time-to-rupture over ASTM P91 and ASTM P92 at the temperature and time conditions examined.

  9. Introduction THE YERINGTON DISTRICT, Nevada, contains porphyry Cu(Mo),

    E-Print Network [OSTI]

    Barton, Mark D.

    55 Introduction THE YERINGTON DISTRICT, Nevada, contains porphyry Cu(Mo), Cu skarn, Fe oxide with the Jurassic Yerington batholith, which serves as either host rock or as source for heat and ma- terials of the Yerington Porphyry Copper District: Magmatic to Nonmagmatic Sources of Hydrothermal Fluids, Their Flow Paths

  10. Multimetal Oxide Catalysts DOI: 10.1002/anie.200902574

    E-Print Network [OSTI]

    Goddard III, William A.

    of propane to acrolein and acrylic acid as well as the oxidation of various alcohols.[1a,4] Mo3VOx, which

  11. Magnesium Front End Design and Development

    Broader source: Energy.gov (indexed) [DOE]

    by: Alan A. Luo and R. C. McCune Presented by: James Quinn, General Motors Unibody Architecture 3-piece Mg front end (bodyframe) USAMP AMD 603 - Magnesium Front End Design and...

  12. Magnesium Research and Technology Development: Project 48976

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advise DOE on criticalkey funding areas for Mg 3 z z Approach Approach Approach Increase automotive industry awareness in the use of Mg Develop and maintain the Magnesium R&D...

  13. Climate VISION: Private Sector Initiatives: Magnesium

    Office of Scientific and Technical Information (OSTI)

    atmosphere, SF6 will persist for 3,200 years and is more than 23,000 times as strong a global warming gas as carbon dioxide (CO2). Read the U.S. and International Magnesium...

  14. Synthesis and Characterization of Magnesium-Silicon and Magnesium-Tin Solid Solutions for Thermoelectric Applications

    E-Print Network [OSTI]

    Hu, Fang

    2012-07-16T23:59:59.000Z

    time curves have been researched in this thesis for fully reacted magnesium-silicide & magnesium-stannide green ingots with doping materials i.e. antimony, bismuth by different doping ratios. These ingots were ground by a high energy ball miller...

  15. Synthesis and Characterization of Magnesium-Silicon and Magnesium-Tin Solid Solutions for Thermoelectric Applications 

    E-Print Network [OSTI]

    Hu, Fang

    2012-07-16T23:59:59.000Z

    time curves have been researched in this thesis for fully reacted magnesium-silicide & magnesium-stannide green ingots with doping materials i.e. antimony, bismuth by different doping ratios. These ingots were ground by a high energy ball miller...

  16. Hydrogen storage characteristics of nanograined free-standing magnesium–nickel films

    E-Print Network [OSTI]

    2009-01-01T23:59:59.000Z

    free-standing magnesium–nickel ?lms Matthew Rogers · StevenFree-standing magnesium–nickel (Mg–Ni) ?lms with extensivefree- standing magnesium–nickel ?lms. Magnesium hydride (MgH

  17. Single Phase Melt Processed Powellite (Ba,Ca) MoO{sub 4} For The Immobilization Of Mo-Rich Nuclear Waste

    SciTech Connect (OSTI)

    Brinkman, Kyle [Savannah River Site (SRS), Aiken, SC (United States); Marra, James [Savannah River Site (SRS), Aiken, SC (United States); Fox, Kevin [Savannah River Site (SRS), Aiken, SC (United States); Reppert, Jason [Savannah River Site (SRS), Aiken, SC (United States); Crum, Jarrod [Paci fic Northwest National Laboratory , Richland, WA (United States); Tang, Ming [Los Alamos National Laboratory , Los Alamos, NM (United States)

    2012-09-17T23:59:59.000Z

    Crystalline and glass composite materials are currently being investigated for the immobilization of combined High Level Waste (HLW) streams resulting from potential commercial fuel reprocessing scenarios. Several of these potential waste streams contain elevated levels of transition metal elements such as molybdenum (Mo). Molybdenum has limited solubility in typical silicate glasses used for nuclear waste immobilization. Under certain chemical and controlled cooling conditions, a powellite (Ba,Ca)MoO{sub 4} crystalline structure can be formed by reaction with alkaline earth elements. In this study, single phase BaMoO{sub 4} and CaMoO{sub 4} were formed from carbonate and oxide precursors demonstrating the viability of Mo incorporation into glass, crystalline or glass composite materials by a melt and crystallization process. X-ray diffraction, photoluminescence, and Raman spectroscopy indicated a long range ordered crystalline structure. In-situ electron irradiation studies indicated that both CaMoO{sub 4} and BaMoO{sub 4} powellite phases exhibit radiation stability up to 1000 years at anticipated doses with a crystalline to amorphous transition observed after 1 X 10{sup 13} Gy. Aqueous durability determined from product consistency tests (PCT) showed low normalized release rates for Ba, Ca, and Mo (<0.05 g/m{sup 2}).

  18. Friction Stir and Ultrasonic Solid State Joining of Magnesium...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Ultrasonic Solid State Joining of Magnesium to Steel Friction Stir and Ultrasonic Solid State Joining of Magnesium to Steel 2012 DOE Hydrogen and Fuel Cells Program and Vehicle...

  19. Texture Control by Selective Deformation Mechanism Activation in Magnesium Alloy

    E-Print Network [OSTI]

    Foley, David Christopher

    2014-07-01T23:59:59.000Z

    The need for high strength, light weight structures in automotive and aerospace applications has driven a resurgence of interest in magnesium and its alloys. Unlike aluminum, wrought magnesium typically has a high degree of mechanical anisotropy...

  20. Texture Control by Selective Deformation Mechanism Activation in Magnesium Alloy 

    E-Print Network [OSTI]

    Foley, David Christopher

    2014-07-01T23:59:59.000Z

    The need for high strength, light weight structures in automotive and aerospace applications has driven a resurgence of interest in magnesium and its alloys. Unlike aluminum, wrought magnesium typically has a high degree of mechanical anisotropy...

  1. AMD 601 High Integrity -Magnesium Automotive Components (HI-MAC...

    Energy Savers [EERE]

    601 High Integrity -Magnesium Automotive Components (HI-MAC) AMD 601 High Integrity -Magnesium Automotive Components (HI-MAC) Presentation from the U.S. DOE Office of Vehicle...

  2. The magnesium nutrition of American upland and Egyptian cottons 

    E-Print Network [OSTI]

    Helmy, Hussein

    1956-01-01T23:59:59.000Z

    ~ ~ ~ ~ ~ ~ ~ ~ 19 ~ ~ ~ SS ~ ~ ~ ~ ~ ~ ~ S7 LIST OF TABLES Page Effect of magnesium on stem he1ghts . . . 52 Relation of magnesium supply to average fresh and dry weight of cotton plants at 45 days ~ ~ \\ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ 55 Relation of magnesium supply... to average fresh and dry weight of cotton plants at 85 days ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ 54 Relation of magnesium supply to average number of flowers produced per plant 1n three day intervals, percentage shedding, percentage boll-set and rel- ative...

  3. Electrodeposition of aluminium, aluminium/magnesium alloys, and magnesium from organometallic electrolytes

    SciTech Connect (OSTI)

    Mayer, A.

    1988-01-01T23:59:59.000Z

    The electrodeposition of aluminum, magnesium, and the combination of these metals from nonaqueous media is discussed. Plating baths for depositing Al/Mg alloys or for plating essentially pure Mg were developed. These solutions contain alkali meal fluoride or quaternary ammonium halide/aluminium alkyl complexes and dialkyl magnesium dissolved in aromatic hydrocarbons. Alloy deposits over the whole composition range can be plated from these solutions by varying the relative quantities of the aluminium and magnesium alkyls and by changing the bath-operating parameters. 18 refs., 4 figs.

  4. SOLID STATE JOINING OF MAGNESIUM TO STEEL

    SciTech Connect (OSTI)

    Jana, Saumyadeep; Hovanski, Yuri; Pilli, Siva Prasad; Field, David P.; Yu, Hao; Pan, Tsung-Yu; Santella, M. L.

    2012-06-04T23:59:59.000Z

    Friction stir welding and ultrasonic welding techniques were applied to join automotive magnesium alloys to steel sheet. The effect of tooling and process parameters on the post-weld microstructure, texture and mechanical properties was investigated. Static and dynamic loading were utilized to investigate the joint strength of both cast and wrought magnesium alloys including their susceptibility and degradation under corrosive media. The conditions required to produce joint strengths in excess of 75% of the base metal strength were determined, and the effects of surface coatings, tooling and weld parameters on weld properties are presented.

  5. AEC Lowman Station - coal switching and magnesium-enhanced lime scrubbing to lower operating costs

    SciTech Connect (OSTI)

    Inkenhaus, W.; Babu, M.; Smith, K. [Dravo Lime Co., Pittsburgh, PA (United States); Loper, L. [Alabama Electric Coopreative, Leroy, AL (United States)

    1997-12-31T23:59:59.000Z

    AEC`s Lowman Station is located in Leroy, Alabama. There are three coal-fired boilers at this station. Unit 1 is capable of generating 85 MW without a flue gas desulfurization, FGD, system. Units 2 and 3, with a total of 516 MW output capacity, are equipped with FGD systems. The FGD plant was designed for wet limestone FGD with natural oxidation. Lowman Station burned low sulfur, 1.3 to 1.8% sulfur, coal. In January of 1996 AEC switched Units 2 and 3 from limestone to magnesium-enhanced lime FGD operation. It was determined that the plant could take advantage of the higher SO{sub 2} removal efficiency of the magnesium-enhanced lime system. Major benefits resulting from this conversion were AEC`s ability to switch to a lower cost high sulfur coal while meeting the stringent SO{sub 2} emission requirements. Power cost savings resulted from the lower liquid to gas ratio required by the magnesium-enhanced lime process. Three recirculation pumps per module were reduced to a single operating pump per module, lowering the scrubber pressure drop. Significant cost reduction in the operating costs of the ball mill was realized due to modifications made to slake lime instead of grinding limestone. Prior to switching, personnel from AEC and Dravo Lime Company ran a four week test on magnesium-enhanced lime to obtain scrubber performance data including SO{sub 2} removal efficiencies on the modules while burning a 1.8% sulfur coal. This paper discusses the plant modifications that were needed to make the switch, cost justifications due to coal switching, and AEC`s operating experiences to date. AEC and Dravo Lime Company working together as a team conducted detailed cost studies, followed by extensive field tests and implemented the plant modifications. This plant continues to operate burning higher sulfur coal with the magnesium-enhanced lime FGD system.

  6. Assessment of the magnesium primary production technology. Final report

    SciTech Connect (OSTI)

    Flemings, M.C.; Kenney, G.B.; Sadoway, D.R.; Clark, J.P.; Szekely, J.

    1981-02-01T23:59:59.000Z

    At current production levels, direct energy savings achievable in primary magnesium production are 1.2 milliquads of energy per annum. Were magnesium to penetrate the automotive market to an average level of 50 pounds per vehicle, the resultant energy savings at the production stage would be somewhat larger, but the resulting savings in gasoline would conserve an estimated 325 milliquads of energy per year. The principal barrier to more widespread use of magnesium in the immediate future is its price. A price reduction of magnesium of 10% would lead to widespread conversion of aluminum die and permanent mold castings to magnesium. This report addresses the technology of electrolytic and thermic magnesium production and the economics of expanded magnesium production and use.

  7. Sol-gel preparation of lead magnesium niobate (PMN) powders and thin films

    DOE Patents [OSTI]

    Boyle, T.J.

    1999-01-12T23:59:59.000Z

    A method of preparing a lead magnesium niobium oxide (PMN), Pb(Mg{sub 1/3}Nb{sub 2/3})O{sub 3}, precursor solution by a solvent method wherein a liquid solution of a lead-complex PMN precursor is combined with a liquid solution of a niobium-complex PMN precursor, the combined lead- and niobium-complex liquid solutions are reacted with a magnesium-alkyl solution, forming a PMN precursor solution and a lead-based precipitate, and the precipitate is separated from the reacted liquid PMN precursor solution to form a precipitate-free PMN precursor solution. This precursor solution can be processed to form both ferroelectric powders and thin films. 3 figs.

  8. Sol-Gel Preparation Of Lead Magnesium Ni Obate (Pmn) Powdersand Thin Films

    DOE Patents [OSTI]

    Boyle, Timothy J. (Albuquerque, NM)

    1999-01-12T23:59:59.000Z

    A method of preparing a lead magnesium niobium oxide (PMN), Pb(Mg.sub.1/3 Nb.sub.2/3)O.sub.3, precursor solution by a solvent method wherein a liquid solution of a lead-complex PMN precursor is combined with a liquid solution of a niobium-complex PMN precursor, the combined lead- and niobium-complex liquid solutions are reacted with a magnesium-alkyl solution, forming a PMN precursor solution and a lead-based precipitate, and the precipitate is separated from the reacted liquid PMN precursor solution to form a precipitate-free PMN precursor solution. This precursor solution can be processed to form both ferroelectric powders and thin films.

  9. Appendix MgO: Magnesium Oxide as an Engineered Barrier

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative FuelsSanta3 TableimpurityAppeals8I CulturalMMgO-2014

  10. Evaluation of Residual Stress Levels in Plasma Electrolytic Oxidation Coatings using a Curvature Method

    E-Print Network [OSTI]

    Dean, J.; Gu, T.; Clyne, T. W.

    2014-11-09T23:59:59.000Z

    Experimental estimates have been made of typical levels of residual stress in plasma electrolytic oxidation (PEO) coatings formed on aluminium and magnesium alloy substrates. This has been done via measurement of the curvature exhibited by thin...

  11. Fabrication and testing of oxidized porous silicon field emitter strips 

    E-Print Network [OSTI]

    Madduri, Vasanta Bhanu

    1992-01-01T23:59:59.000Z

    Fig. 1 Cross-section of Thin-film Field Emission Structure (After Spindt, et al. [7] ). Mo Silicon dioxide Silicon substrate Axis of rotation ~' Evaporant Aluminum release layer Mo SiO Si Evaporant Deposition for cone formation Etch off... release layer Fig. 2 Fabrication Procedure to Produce Mo Cones silicon substrates with 1-1, 5 pm of thermally grown oxide on them. Holes of 1. 5-2 ltm diameter are micro-machined in the oxide layer using electron beam lithography. Mo serves as an etch...

  12. The carburization of transition metal molybdates (MxMoO?, M= Cu, Ni or Co) and the generation of highly active metal/carbide catalysts for CO? hydrogenation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rodriguez, Jose A.; Xu, Wenqian; Ramirez, Pedro J.; Stachiola, Dario; Brito, Joaquin L.

    2015-05-06T23:59:59.000Z

    A new approach has been tested for the preparation of metal/Mo?C catalysts using mixed-metal oxide molybdates as precursors. Synchrotron-based in situ time-resolved X-ray diffraction was used to study the reduction and carburization processes of Cu?(MoO?)?(OH)?, a-NiMoO? and CoMoO?•nH?O by thermal treatment under mixtures of hydrogen and methane. In all cases, the final product was ?-Mo?C and a metal phase (Cu, Ni, or Co), but the transition sequence varied with the different metals, and it could be related to the reduction potential of the Cu²?, Ni²? and Co²? cations inside each molybdate. The synthesized Cu/Mo?C, Ni/Mo?C and Co/Mo?C catalysts were highlymore »active for the hydrogenation of CO?. The metal/Mo?C systems exhibited large variations in the selectivity towards methanol, methane and CnH?n?? (n > 2) hydrocarbons depending on the nature of the supported metal and its ability to cleave C-O bonds. Cu/Mo?C displayed a high selectivity for CO and methanol production. Ni/Mo?C and Co/Mo?C were the most active catalysts for the activation and full decomposition of CO?, showing high selectivity for the production of methane (Ni case) and CnH?n?? (n > 2) hydrocarbons (Co case).« less

  13. The carburization of transition metal molybdates (MxMoO?, M= Cu, Ni or Co) and the generation of highly active metal/carbide catalysts for CO? hydrogenation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rodriguez, Jose A. [Brookhaven National Lab. (BNL), Upton, NY (United States); Xu, Wenqian [Brookhaven National Lab. (BNL), Upton, NY (United States); Ramirez, Pedro J. [Brookhaven National Lab. (BNL), Upton, NY (United States); Univ. Central De Venezuela, Caracas (Venesuela); Stachiola, Dario [Brookhaven National Lab. (BNL), Upton, NY (United States); Brito, Joaquin L. [Inst. Venezolano de Investigaciones Cientificas, Caracas (Venezuela)

    2015-05-06T23:59:59.000Z

    A new approach has been tested for the preparation of metal/Mo?C catalysts using mixed-metal oxide molybdates as precursors. Synchrotron-based in situ time-resolved X-ray diffraction was used to study the reduction and carburization processes of Cu?(MoO?)?(OH)?, a-NiMoO? and CoMoO?•nH?O by thermal treatment under mixtures of hydrogen and methane. In all cases, the final product was ?-Mo?C and a metal phase (Cu, Ni, or Co), but the transition sequence varied with the different metals, and it could be related to the reduction potential of the Cu²?, Ni²? and Co²? cations inside each molybdate. The synthesized Cu/Mo?C, Ni/Mo?C and Co/Mo?C catalysts were highly active for the hydrogenation of CO?. The metal/Mo?C systems exhibited large variations in the selectivity towards methanol, methane and CnH?n?? (n > 2) hydrocarbons depending on the nature of the supported metal and its ability to cleave C-O bonds. Cu/Mo?C displayed a high selectivity for CO and methanol production. Ni/Mo?C and Co/Mo?C were the most active catalysts for the activation and full decomposition of CO?, showing high selectivity for the production of methane (Ni case) and CnH?n?? (n > 2) hydrocarbons (Co case).

  14. Ductility Enhancement of Molybdenum Phase by Nano-sizedd Oxide Dispersions

    SciTech Connect (OSTI)

    Bruce Kang

    2008-07-31T23:59:59.000Z

    The present research is focused on ductility enhancement of molybdenum (Mo) alloys by adding nano-sized oxide particles to the alloy system. The research approach includes: (1) determination of microscopic mechanisms responsible for the macroscopic ductility enhancement effects through atomistic modeling of the metal-ceramic interface; (2) subsequent computer simulation-aided optimization of composition and nanoparticle size of the dispersion for improved performance; (3) synthesis and characterization of nanoparticle dispersion following the guidance from atomistic computational modeling analyses (e.g., by processing a small sample of Mo alloy for evaluation); and (4) experimental testing of the mechanical properties to determine optimal ductility enhancement.Through atomistic modeling and electronic structure analysis using full-potential linearized muffin-tin orbital (FP-LMTO) techniques, research to date has been performed on a number of selected chromium (Cr) systems containing nitrogen (N) and/or magnesium oxide (MgO) impurities. The emphasis has been on determining the properties of the valence electrons and the characteristics of the chemical bonds they formed. It was found that the brittle/ductile behavior of this transitional metal system is controlled by the relative population of valence charges: bonds formed by s valence electrons yield metallic, ductile behavior, whereas bonds formed by d valence electrons lead to covalent, brittle behavior. The presence of valence bands from impurities also affects the metal bonding, thereby explaining the detrimental and beneficial effects induced by the inclusion of N impurities and MgO dispersions. These understandings are useful for optimizing ductility enhancement effects on the dispersion materials.

  15. Long-term corrosion of Cr-Mo steels in superheated steam at 482 and 538/sup 0/C. [21/4 Cr-1 Mo; 9 Cr-1 Mo; Sumitomo 9 Cr-2 Mo; Sandvik HT-9

    SciTech Connect (OSTI)

    Griess, J.C.; DeVan, J.H.; Maxwell, W.A.

    1980-01-01T23:59:59.000Z

    The corrosion of several Cr-Mo ferritic steels was investigated in superheated steam at an operating power plant. Tests were conducted at 482 and 538/sup 0/C (900 and 1000/sup 0/F) in a once-through loop for times up to 28,000 h. Chromium concentrations ranged from 2.0 to 11.3%, and the effect of surface preparation on corrosion was investigated. Only one of many specimens showed evidence of exfoliation at 482/sup 0/C, but at 538/sup 0/C exfoliation occurred on at least some of the specimens of most materials; the exceptions were the alloy with the highest chromium content (Sandvik HT-9), one heat of 9 Cr-1 Mo steel with the highest silicon content, and Sumitomo 9 Cr-2 Mo steel, which was in test for only 19,000 h. Parabolic oxidation kinetics adequately described the corrosion process for about the first year, after which corrosion rates were constant and lower than predicted from extrapolation of the initial part of the penetration versus time curves. With chromium concentrations between 2 and 9%, corrosion behavior was independent of chromium content, and corrosion was only slightly less with Sandvik HT-9. Corrosion was nearly independent of surface preparation, but in two cases the presence of mill scale on the surface prior to steam exposure seemed to retard oxidation in steam. 11 figures, 5 tables.

  16. Structure of Co-Mo/UPSILON-Al/sub 7/O/sub 3/ catalysts and relationship to HDS and hydrogenation activity. [Hydrodesulfurization (HDS)

    SciTech Connect (OSTI)

    Bennet, B.A. (Imperial Coll., London, England); Chadwick, D.; Jawahery, A.R.; Breysse, M.; Vrinat, M.

    1982-09-01T23:59:59.000Z

    From Mossbauer spectroscopy studies of catalysts of typical industrial compositions and activity measurements it was shown that catalysts containing the ''Co-Mo-S'' phase have relatively higher hydrodesulfurization (HDS) activities. It was also found that the use of Co in the first impregnation step favored the formation of Co/sub 9/S/sub 8/ (in addition to Co in alumina), while the reverse impregnation order produced mainly the ''Co-Mo-S'' phase. Avoiding Co/sub 3/O/sub 4/ formation in the oxide precursor was important for the formation of the ''Co-Mo-S'' phase and this was achieved by the impregnation of Mo before Co. There was also evidence that when Co was used in the second impregnation step, there was significant Mo, Co interaction. This interaction my produce a CoMo surface phase which is disordered and well dispersed and sulfides to the ''Co-Mo-S'' phase. (JMT)

  17. Lead magnesium niobate actuator for micropositioning

    DOE Patents [OSTI]

    Swift, C.D.; Bergum, J.W.

    1994-10-25T23:59:59.000Z

    An improved lead magnesium niobate actuator is disclosed comprising a cylindrical lead magnesium niobate crystal stack mounted in a cylindrical casing wherein a bias means, such as one or more belleville washers, is located between one end of the crystal stack and a partially closed end of the casing; and adjustment means are provided which bear against the opposite end of the crystal stack, whereby an adjustable compressive force is constantly applied against the crystal stack, whether the crystal stack is actuated in an extended position, or is in an unactuated contracted position. In a preferred embodiment, cooling ports are provided for the circulation of coolant in the actuator to cool the crystal stack, and provision is made for removal and replacement of the crystal stack without disconnecting the actuator from the external device being actuated. 3 figs.

  18. Lead magnesium niobate actuator for micropositioning

    DOE Patents [OSTI]

    Swift, Charles D. (Livermore, CA); Bergum, John W. (Concord, CA)

    1994-01-01T23:59:59.000Z

    An improved lead magnesium niobate actuator is disclosed comprising a cylindrical lead magnesium niobate crystal stack mounted in a cylindrical casing wherein a bias means, such as one or more belleville washers, is located between one end of the crystal stack and a partially closed end of the casing; and adjustment means are provided which bear against the opposite end of the crystal stack, whereby an adjustable compressive force is constantly applied against the crystal stack, whether the crystal stack is actuated in an extended position, or is in an unactuated contracted position. In a preferred embodiment, cooling ports are provided for the circulation of coolant in the actuator to cool the crystal stack, and provision is made for removal and replacement of the crystal stack without disconnecting the actuator from the external device being actuated.

  19. MoS{sub 2} nanotube exfoliation as new synthesis pathway to molybdenum blue

    SciTech Connect (OSTI)

    Visic, B., E-mail: bojana.visic@ijs.si [Jozef Stefan Institute, Jamova cesta 39, SI-1000 Ljubljana (Slovenia); Gunde, M. Klanjsek [National Institute of Chemistry, Hajdrihova 19, SI-1000 Ljubljana (Slovenia)] [National Institute of Chemistry, Hajdrihova 19, SI-1000 Ljubljana (Slovenia); Kovac, J.; Iskra, I. [Jozef Stefan Institute, Jamova cesta 39, SI-1000 Ljubljana (Slovenia)] [Jozef Stefan Institute, Jamova cesta 39, SI-1000 Ljubljana (Slovenia); Jelenc, J.; Remskar, M. [Jozef Stefan Institute, Jamova cesta 39, SI-1000 Ljubljana (Slovenia) [Jozef Stefan Institute, Jamova cesta 39, SI-1000 Ljubljana (Slovenia); Centre of Excellence Namaste, Jamova cesta 39, SI-1000 Ljubljana (Slovenia)

    2013-02-15T23:59:59.000Z

    Graphical abstract: . Display Omitted Highlights: ? New synthesis approach to obtaining molybdenum blue via exfoliated MoS{sub 2} nanotubes. ? Material is prone to self assembly and is stable in high vacuum. ? Molecules are as small as 2 nm and their clusters are up to tens of nanometers. ? Change in absorption and oxidation states from the precursor MoS{sub 2}. -- Abstract: Molybdenum blue-type materials are usually obtained by partially reducing Mo{sup VI+} in acidic solutions, while in the presented method it is formed in ethanol solution of exfoliated MoS{sub 2} nanotubes, where the MoS{sub 2} flakes are the preferential location for their growth. Material was investigated by means of scanning electron and atomic force microscopy, showing the structure and self assembly, while also confirming that it is stable in high vacuum with molecules as small as 1.6 nm and the agglomerates of few tens of nanometres. The ultraviolet–visible and photoelectron spectrometry show the change in absorption properties and oxidation states from MoS{sub 2} structure to molybdenum blue, while the presence of sulphur suggests that this is a new type of molybdenum blue material.

  20. Impurity control and corrosion resistance of magnesium-aluminum alloy

    SciTech Connect (OSTI)

    Liu, M. [GM China Lab] [GM China Lab; Song, GuangLing [ORNL] [ORNL

    2013-01-01T23:59:59.000Z

    The corrosion resistance of magnesium alloys is very sensitive to the contents of impurity elements such as iron. In this study, a series of diecast AXJ530 magnesium alloy samples were prepared with additions of Mn and Fe. Through a comprehensive phase diagram calculation and corrosion evaluation, the mechanisms for the tolerance limit of Fe in magnesium alloy are discussed. This adds a new dimension to control the alloying impurity in terms of alloying composition design and casting conditions.

  1. Electrodeposition of high Mo content Ni-Mo alloys under forced convection

    SciTech Connect (OSTI)

    Podlaha, E.J.; Matlosz, M.; Landolt, D. (Ecole Polytechnique Federale de Lausanne, Lausanee (Switzerland). Dept. des materiaux)

    1993-10-01T23:59:59.000Z

    Bright, compact, adherent, metallic Ni-Mo alloys, containing over 48 wt % Mo have been electrodeposited from an aqueous solution. The Mo content, which is the highest achieved so far in induced codeposition of Ni-Mo, was determined by X-ray fluorescence spectroscopy. The absence of oxygen was verified by Auger electron spectroscopy. Electrodeposition experiments were performed on rotating cylinder electrodes and demonstrate that the Mo content of the alloy is strongly influenced by convective transport.

  2. antenatal magnesium sulfate: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    was reduced by 30 % at 48 hours of the treatment. Results. After magnesium sulfate infusion, 90 % prolonged their pregnancy for>48 hours. Combination therapy was effective in 95...

  3. Climate VISION: Private Sector Initiatives: Magnesium: GHG Inventory...

    Office of Scientific and Technical Information (OSTI)

    GHG Inventory Protocols The Magnesium Industry Partnership's SF6 emissions tracking and reporting software tool (Excel based) can be accessed by visiting the Partnership's...

  4. Climate VISION: Private Sector Initiatives: Magnesium: GHG Information

    Office of Scientific and Technical Information (OSTI)

    GHG Information The magnesium industry directly emits SF6 from its primary metal production, parts casting, and recycling operations. In 2005, the industry's SF6 emissions were...

  5. Magnesium Front End Research and Development AMD 604

    Broader source: Energy.gov (indexed) [DOE]

    and sheet forming Improved high-volume manufacturing techniques for joining and corrosion protection of magnesium structures. Improved knowledge base in Mg...

  6. Magnesium Front End Research and Development AMD 604

    Broader source: Energy.gov (indexed) [DOE]

    high volume manufacturing techniques for joining of Mg - Large- scale joining and corrosion protection of magnesium structures. * Corrosion: Durability of Mg-intensive...

  7. AMD 601 High Integrity -Magnesium Automotive Components (HI-MAC...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Neutral or Less Than Current Aluminum Components USAMP AMD 601 - High Integrity Magnesium Automotive Components (HI-MAC) edm2@chrysler.com February 28, 2008 Approach Scientific...

  8. Magnesium behavior and structural defects in Mg+ ion implanted...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    irradiation with magnesium as the major metallic transmutant; the others include aluminum, beryllium and phosphorus in addition to helium and hydrogen gaseous species. The...

  9. Method for the production of {sup 99m}Tc compositions from {sup 99}Mo-containing materials

    DOE Patents [OSTI]

    Bennett, R.G.; Christian, J.D.; Grover, S.B.; Petti, D.A.; Terry, W.K.; Yoon, W.Y.

    1998-09-01T23:59:59.000Z

    An improved method is described for producing {sup 99m}Tc compositions from {sup 99}Mo compounds. {sup 100}Mo metal or {sup 100}MoO{sub 3} is irradiated with photons in a particle (electron) accelerator to ultimately produce {sup 99}MoO{sub 3}. This composition is then heated in a reaction chamber to form a pool of molten {sup 99}MoO{sub 3} with an optimum depth of 0.5--5 mm. A gaseous mixture thereafter evolves from the molten {sup 99}MoO{sub 3} which contains vaporized {sup 99}MoO{sub 3}, vaporized {sup 99m}TcO{sub 3}, and vaporized {sup 99m}TcO{sub 2}. This mixture is then combined with an oxidizing gas (O{sub 2(g)}) to generate a gaseous stream containing vaporized {sup 99m}Tc{sub 2}O{sub 7} and vaporized {sup 99}MoO{sub 3}. Next, the gaseous stream is cooled in a primary condensation stage in the reaction chamber to remove vaporized {sup 99}MoO{sub 3}. Cooling is undertaken at a specially-controlled rate to achieve maximum separation efficiency. The gaseous stream is then cooled in a sequential secondary condensation stage to convert vaporized {sup 99m}Tc{sub 2}O{sub 7} into a condensed {sup 99m}Tc-containing reaction product which is collected. 1 fig.

  10. Method for the production of .sup.99m Tc compositions from .sup.99 Mo-containing materials

    DOE Patents [OSTI]

    Bennett, Ralph G. (Idaho Falls, ID); Christian, Jerry D. (Idaho Falls, ID); Grover, S. Blaine (Idaho Falls, ID); Petti, David A. (Idaho Falls, ID); Terry, William K. (Idaho Falls, ID); Yoon, Woo Y. (Idaho Falls, ID)

    1998-01-01T23:59:59.000Z

    An improved method for producing .sup.99m Tc compositions from .sup.99 Mo compounds. .sup.100 Mo metal or .sup.100 MoO.sub.3 is irradiated with photons in a particle (electron) accelerator to ultimately produce .sup.99 MoO.sub.3. This composition is then heated in a reaction chamber to form a pool of molten .sup.99 MoO.sub.3 with an optimum depth of 0.5-5 mm. A gaseous mixture thereafter evolves from the molten .sup.99 MoO.sub.3 which contains vaporized .sup.99 MoO.sub.3, vaporized .sup.99m TcO.sub.3, and vaporized .sup.99m TcO.sub.2. This mixture is then combined with an oxidizing gas (O.sub.2(g)) to generate a gaseous stream containing vaporized .sup.99m Tc.sub.2 O.sub.7 and vaporized .sup.99 MoO.sub.3. Next, the gaseous stream is cooled in a primary condensation stage in the reaction chamber to remove vaporized .sup.99 MoO.sub.3. Cooling is undertaken at a specially-controlled rate to achieve maximum separation efficiency. The gaseous stream is then cooled in a sequential secondary condensation stage to convert vaporized .sup.99m Tc.sub.2 O.sub.7 into a condensed .sup.99m Tc-containing reaction product which is collected.

  11. Development of High-Volume Warm Forming of Low-Cost Magnesium...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Magnesium Sheet AMD 602 Project Team * OEM's - Chrysler, Ford , GM * Contracts - Troy Tooling Technologies - Materials Suppliers * Magnesium Elektron * POSCO * Thyssen * CSIRO *...

  12. Development of High-Volume Warm Forming of Low-Cost Magnesium...

    Broader source: Energy.gov (indexed) [DOE]

    mccarty13.pdf More Documents & Publications Warm Forming of AluminumAMD 307 Magnesium Front End Research And Development (AMD604) Magnesium Front End Design And Development...

  13. Highly conducting SrMoO{sub 3} thin films for microwave applications

    SciTech Connect (OSTI)

    Radetinac, Aldin, E-mail: aldin@oxide.tu-darmstadt.de; Mani, Arzhang; Ziegler, Jürgen; Alff, Lambert; Komissinskiy, Philipp, E-mail: komissinskiy@oxide.tu-darmstadt.de [Institute of Materials Science, TU Darmstadt, Alarich-Weiss-Str. 2, 64287 Darmstadt (Germany); Melnyk, Sergiy; Nikfalazar, Mohammad; Zheng, Yuliang; Jakoby, Rolf [Institute for Microwave Engineering and Photonics, TU Darmstadt, Merckstraße 25, 64283 Darmstadt (Germany)

    2014-09-15T23:59:59.000Z

    We have measured the microwave resistance of highly conducting perovskite oxide SrMoO{sub 3} thin film coplanar waveguides. The epitaxial SrMoO{sub 3} thin films were grown by pulsed laser deposition and showed low mosaicity and smooth surfaces with a root mean square roughness below 0.3?nm. Layer-by-layer growth could be achieved for film thicknesses up to 400?nm as monitored by reflection high-energy electron diffraction and confirmed by X-ray diffraction. We obtained a constant microwave resistivity of 29???·cm between 0.1 and 20?GHz by refining the frequency dependence of the transmission coefficients. Our result shows that SrMoO{sub 3} is a viable candidate as a highly conducting electrode material for all-oxide microwave electronic devices.

  14. High blue-near ultraviolet photodiode response of vertically stacked graphene-MoS{sub 2}-metal heterostructures

    SciTech Connect (OSTI)

    Wi, Sungjin; Chen, Mikai; Nam, Hongsuk; Liu, Amy C.; Meyhofer, Edgar; Liang, Xiaogan, E-mail: xiaoganl@umich.edu [Department of Mechanical Engineering, University of Michigan, Ann Arbor, Michigan 48109 (United States)

    2014-06-09T23:59:59.000Z

    We present a study on the photodiode response of vertically stacked graphene/MoS{sub 2}/metal heterostructures in which MoS{sub 2} layers are doped with various plasma species. In comparison with undoped heterostructures, such doped ones exhibit significantly improved quantum efficiencies in both photovoltaic and photoconductive modes. This indicates that plasma-doping-induced built-in potentials play an important role in photocurrent generation. As compared to indium-tin-oxide/ MoS{sub 2}/metal structures, the presented graphene/MoS{sub 2}/metal heterostructures exhibit greatly enhanced quantum efficiencies in the blue-near ultraviolet region, which is attributed to the low density of recombination centers at graphene/MoS{sub 2} heterojunctions. This work advances the knowledge for making photo-response devices based on layered materials.

  15. Casting Porosity-Free Grain Refined Magnesium Alloys

    SciTech Connect (OSTI)

    Schwam, David [Case Western Reserve University] [Case Western Reserve University

    2013-08-12T23:59:59.000Z

    The objective of this project was to identify the root causes for micro-porosity in magnesium alloy castings and recommend remedies that can be implemented in production. The findings confirm the key role played by utilizing optimal gating and risering practices in minimizing porosity in magnesium castings.?

  16. Promising Magnesium Battery Research at ALS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's Possible forPortsmouth/Paducah47,193.70 HgPromising Magnesium Battery Research at ALS Promising

  17. US WNC MO Site Consumption

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTownDells,1Stocks Nov-14TotalThe Outlook269,023Year69,023USWNC MO Site

  18. /sup 238/PuO/sub 2//Mo-50 wt% Re compatibility at 800 and 1000/sup 0/C

    SciTech Connect (OSTI)

    Schaeffer, D.R.; Teaney, P.E.

    1980-07-18T23:59:59.000Z

    The compatibility of Mo-50 wt % Re with /sup 238/PuO/sub 2/ was investigated after heat treatments of up to 720 days at 800/sup 0/C and 180 days at 1000/sup 0/C. At 800/sup 0/C, a 1-..mu..m thick, continuous layer of molybdenum oxide resulted. At 1000/sup 0/C, the oxide reaction product contained some plutonium and did not appear continuous. At 1000/sup 0/C, a layer of intermetallic formed at the Mo-Re edge, beneath the oxide layer, creating a barrier between the Mo-50 wt % Re and the /sup 238/PuO/sub 2/. The intermetallic layer was promoted by the iron impurity in the /sup 238/PuO/sub 2/.

  19. Development and Application of a ReaxFF Reactive Force Field for Oxidative Dehydrogenation on Vanadium Oxide Catalysts

    E-Print Network [OSTI]

    Goddard III, William A.

    oxidize or ammoxidize pro- pane, with the most promising MMO catalysts containing Mo, V, Te, Ta, and Nb.3 pertinent to this paper is the use of QM to elucidate the mechanism for propane ODH using QM

  20. Isotopic Tracer Studies of Reaction Pathways for Propane Oxidative Dehydrogenation on Molybdenum Oxide Catalysts

    E-Print Network [OSTI]

    Iglesia, Enrique

    Isotopic Tracer Studies of Reaction Pathways for Propane Oxidative Dehydrogenation on Molybdenum of propane over ZrO2-supported MoOx catalysts. Competitive reactions of C3H6 and CH3 13 CH2CH3 showed combustion of propene, or by direct combustion of propane. A mixture of C3H8 and C3D8 undergoes oxidative

  1. Novel Processing of mo-si-b Intermetallics for improved efficiency of power systems

    SciTech Connect (OSTI)

    M.J. Kramer; O. Degirmen; A.J. Thom; M. Akinc

    2004-09-30T23:59:59.000Z

    Multiphase composite alloys based on the Mo-Si-B system are candidate materials for ultra-high temperature applications. In non load-bearing applications such as thermal barrier coatings or heat exchangers in fossil fuel burners, these materials may be ideally suited. Alloys based on the Mo{sub 5}Si{sub 3}B{sub x} phase (Tl phase) possess excellent oxidation resistance to at least 1600 C in synthetic air atmospheres. However, the ability of Tl-based alloys to resist aggressive combustion environments has not yet been determined. The present work seeks to investigate the resistance of these Mo-Si-B alloys to simulated combustion atmospheres. Material was pre-alloyed by combustion synthesis, and samples for testing were prepared by classic powder metallurgical processing techniques. Precursor material synthesized by self-heating-synthesis was sintered to densities exceeding 98% in an argon atmosphere at 1800 C. The approximate phase assemblage of the material was 57% Tl, 29% MoB, 14% MoSi{sub 2} (wt%). The alloy was oxidized from 1000-1100 C in flowing air containing water vapor at 18 Torr. At 1000 C the material achieved a steady state mass loss, and at 1100 C the material undergoes a steady state mass gain. The oxidation rate of these alloys in this temperature regime was accelerated by the presence of water vapor compared to oxidation in dry air. The results of microstructural analysis of the tested alloys will be discussed. Techniques and preliminary results for fabricating near-net-shaped parts will also be presented.

  2. alvos contendo mo: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CaMoO4 crystal scintillators. A high sensitivity experiment to search for neutrinoless double beta decay of 100-Mo by using CaMoO4 scintillators is discussed. Annenkov, A N;...

  3. Ames Lab 101: BAM (Boron-Aluminum-Magnesium)

    ScienceCinema (OSTI)

    Bruce Cook

    2013-06-05T23:59:59.000Z

    Materials scientist, Bruce Cook, discusses the super hard, low friction, and lubricious alloy know as BAM (Boron-Aluminum-Magnesium). BAM was discovered by Bruce Cook and his team a

  4. az91 magnesium alloy: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Page Last Page Topic Index 1 Studies on the inuence of chloride ion and pH on the corrosion and electrochemical behaviour of AZ91D magnesium alloy Engineering Websites Summary:...

  5. Magnesium Replacement of Aluminum Cast Components in a Production...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Replacement of Aluminum Cast Components in a Production V6 Engine to Effect Cost-Effective Mass Reduction Magnesium Replacement of Aluminum Cast Components in a Production V6...

  6. Atomistic full-band simulations of monolayer MoS{sub 2} transistors

    SciTech Connect (OSTI)

    Chang, Jiwon; Register, Leonard F.; Banerjee, Sanjay K. [Microelectronics Research Center, The University of Texas at Austin, Austin, Texas 78758 (United States)] [Microelectronics Research Center, The University of Texas at Austin, Austin, Texas 78758 (United States)

    2013-11-25T23:59:59.000Z

    We study the transport properties of deeply scaled monolayer MoS{sub 2} n-channel metal-oxide-semiconductor field effect transistors (MOSFETs), using full-band ballistic quantum transport simulations, with an atomistic tight-binding Hamiltonian obtained from density functional theory. Our simulations suggest that monolayer MoS{sub 2} MOSFETs can provide near-ideal subthreshold slope, suppression of drain-induced barrier lowering, and gate-induced drain leakage. However, these full-band simulations exhibit limited transconductance. These ballistic simulations also exhibit negative differential resistance (NDR) in the output characteristics associated with the narrow width in energy of the lowest conduction band, but this NDR may be substantially reduced or eliminated by scattering in MoS{sub 2}.

  7. An investigation of magnesium production in silicon by neutron transmutation

    E-Print Network [OSTI]

    Davis, Freddie Joe

    1986-01-01T23:59:59.000Z

    OF SCIENCE May 1986 Major Subject: Nuclear Engineering AN INVESTIGATION OF MAGNESIUM PRODUCTION IN SILICON BY NEUTRON TRANSMUTATION A Thesis by FREDDIE JOE DAVIS, JR. Approved as to style and content by: Ron R. Har t (Chair of Committee) Donald L... University Chairman of Advisory Committee: Dr . Ron R. Hart An investigation of the production of' magnesium in silicon by neutron tr ansmutation is r eported. A 20 mil silicon wafer was irradiated at the Texas A&M University Nuclear Science Center...

  8. Determination of carbon, nitrogen, and oxygen in high purity magnesium 

    E-Print Network [OSTI]

    Roche, Neil Gerard

    1981-01-01T23:59:59.000Z

    DETERMINATION OF CARBON, NITROGEN, AND OXYGEN IN HIGH PURITY MAGNESIUM A Thesis by NEIL GERARD ROCHE Submitted to the Graduate College of Texas A8cM University in partial i'ulfillment of the requirement for the degree of MASTER OF SCIENCE... December 1981 Major Subject: Chemistry DETERMINATION OF CARBON, NITROGEN, AND OXYGEN IN HIGH PURITY MAGNESIUM A Thesis by NEIL GERARD ROCHE Approved as to style and content by: E. A. Schweikert (Chairman of Committee) G. J. Bastiaans (Member) L...

  9. Preparation and structural study from neutron diffraction data of Pr{sub 5}Mo{sub 3}O{sub 16}

    SciTech Connect (OSTI)

    Martinez-Lope, M.J. [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco, E-28049 Madrid, Spain. (Spain); Alonso, J.A., E-mail: ja.alonso@icmm.csic.e [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco, E-28049 Madrid, Spain. (Spain); Sheptyakov, D.; Pomjakushin, V. [Laboratory for Neutron Scattering, Paul Scherrer Institut, CH-5232 Villigen PSI (Switzerland)

    2010-12-15T23:59:59.000Z

    The title compound has been prepared as polycrystalline powder by thermal treatments of mixtures of Pr{sub 6}O{sub 11} and MoO{sub 2} in air. In the literature, an oxide with a composition Pr{sub 2}MoO{sub 6} has been formerly described to present interesting catalytic properties, but its true stoichiometry and crystal structure are reported here for the first time. It is cubic, isostructural with CdTm{sub 4}Mo{sub 3}O{sub 16} (space group Pn-3n, Z=8), with a=11.0897(1) A. The structure contains MoO{sub 4} tetrahedral units, with Mo-O distances of 1.788(2) A, fully long-range ordered with PrO{sub 8} polyhedra; in fact it can be considered as a superstructure of fluorite (M{sub 8}O{sub 16}), containing 32 MO{sub 2} fluorite formulae per unit cell, with a lattice parameter related to that of cubic fluorite (a{sub f}=5.5 A) as a{approx}2a{sub f}. A bond valence study indicates that Mo exhibits a mixed oxidation state between 5+ and 6+ (perhaps accounting for the excellent catalytic properties). One kind of Pr atoms is trivalent whereas the second presents a mixed Pr{sup 3+}-Pr{sup 4+} oxidation state. The similarity of the XRD pattern with that published for Ce{sub 2}MoO{sub 6} suggests that this compound also belongs to the same structural type, with an actual stoichiometry Ce{sub 5}Mo{sub 3}O{sub 16}. -- Graphical Abstract: Formerly formulated as Pr{sub 2}MoO{sub 6}, the title compound is a cubic superstructure of fluorite (a=11.0897(1) A, space group Pn-3n) due to the long-range ordering of PrO{sub 8} scalenohedra and MoO{sub 4} tetrahedral units, showing noticeable shifts of the oxygen positions in order to provide a tetrahedral coordination for Mo ions. A mixed valence Mo{sup 5+}-Mo{sup 6+} is identified, which could account for the excellent catalytic properties of this material. Display Omitted

  10. M5Si3(M=Ti, Nb, Mo) Based Transition-Metal Silicides for High Temperature Applications

    SciTech Connect (OSTI)

    Zhihong Tang

    2007-12-01T23:59:59.000Z

    Transition metal silicides are being considered for future engine turbine components at temperatures up to 1600 C. Although significant improvement in high temperature strength, room temperature fracture toughness has been realized in the past decade, further improvement in oxidation resistance is needed. Oxidation mechanism of Ti{sub 5}Si{sub 3}-based alloys was investigated. Oxidation behavior of Ti{sub 5}Si{sub 3}-based alloy strongly depends on the atmosphere. Presence of Nitrogen alters the oxidation behavior of Ti{sub 5}Si{sub 3} by nucleation and growth of nitride subscale. Ti{sub 5}Si{sub 3.2} and Ti{sub 5}Si{sub 3}C{sub 0.5} alloys exhibited an excellent oxidation resistance in nitrogen bearing atmosphere due to limited dissolution of nitrogen and increased Si/Ti activity ratio. MoSi{sub 2} coating developed by pack cementation to protect Mo-based Mo-Si-B composites was found to be effective up to 1500 C. Shifting coating composition to T1+T2+Mo{sub 3}Si region showed the possibility to extend the coating lifetime above 1500 C by more than ten times via formation of slow growing Mo{sub 3}Si or T2 interlayer without sacrificing the oxidation resistance of the coating. The phase equilibria in the Nb-rich portion of Nb-B system has been evaluated experimentally using metallographic analysis and differential thermal analyzer (DTA). It was shown that Nb{sub ss} (solid solution) and NbB are the only two primary phases in the 0-40 at.% B composition range, and the eutectic reaction L {leftrightarrow} Nb{sub SS} + NbB was determined to occur at 2104 {+-} 5 C by DTA.

  11. MoS2 Nanoribbons Thermoelectric Generators

    E-Print Network [OSTI]

    Arab, Abbas

    2015-01-01T23:59:59.000Z

    In this work, we have designed and simulated new thermoelectric generator based on monolayer and few-layer MoS2 nanoribbons. The proposed thermoelectric generator is composed of thermocouples made of both n-type and p-type MoS2 nanoribbon legs. Density Functional Tight-Binding Non-Equilibrium Green's Function (DFTB-NEGF) method has been used to calculate the transmission spectrum of MoS2 armchair and zigzag nanoribbons. Phonon transmission spectrum are calculated based on parameterization of Stillinger-Weber potential. Thermoelectric figure of merit, ZT, is calculated using these electronic and phonon transmission spectrum. Monolayer and bilayer MoS2 armchair nanoribbons are found to have the highest ZT value for p-type and n-type legs, repectively. Moreover, we have compared the thermoelectric current of doped monolayer MoS2 armchair nanoribbons and SZi thin films. Results indicate that thermoelectric current of MoS2 monolayer nanoribbons is several orders of magnitude higher than that of Si thin films.

  12. Evaluation of the Magnesium Hydroxide Treatment Process for Stabilizing PFP Plutonium/Nitric Acid Solutions

    SciTech Connect (OSTI)

    Gerber, Mark A.; Schmidt, Andrew J.; Delegard, Calvin H.; Silvers, Kurt L.; Baker, Aaron B.; Gano, Susan R.; Thornton, Brenda M.

    2000-09-28T23:59:59.000Z

    This document summarizes an evaluation of the magnesium hydroxide [Mg(OH)2] process to be used at the Hanford Plutonium Finishing Plant (PFP) for stabilizing plutonium/nitric acid solutions to meet the goal of stabilizing the plutonium in an oxide form suitable for storage under DOE-STD-3013-99. During the treatment process, nitric acid solutions bearing plutonium nitrate are neutralized with Mg(OH)2 in an air sparge reactor. The resulting slurry, containing plutonium hydroxide, is filtered and calcined. The process evaluation included a literature review and extensive laboratory- and bench-scale testing. The testing was conducted using cerium as a surrogate for plutonium to identify and quantify the effects of key processing variables on processing time (primarily neutralization and filtration time) and calcined product properties.

  13. Nondestructive evaluation of an environmentally friendly conversion coating for magnesium alloys using optical measurement techniques

    E-Print Network [OSTI]

    Zuniga, David

    2006-10-30T23:59:59.000Z

    Magnesium alloys have one of the highest specific strengths of all construction metals used. Specifically, magnesium alloy castings are used in the aerospace industry to reduce the weight of aerospace vehicles. Coating systems must be employed...

  14. Nondestructive evaluation of an environmentally friendly conversion coating for magnesium alloys using optical measurement techniques 

    E-Print Network [OSTI]

    Zuniga, David

    2006-10-30T23:59:59.000Z

    Magnesium alloys have one of the highest specific strengths of all construction metals used. Specifically, magnesium alloy castings are used in the aerospace industry to reduce the weight of aerospace vehicles. Coating systems must be employed...

  15. Metal oxide/organic interface investigations for photovoltaic devices

    E-Print Network [OSTI]

    Pachoumi, Olympia

    2014-10-07T23:59:59.000Z

    organic photovoltaics is investigated. We show that using these ternary oxides can lead to superior devices by: prevent- ing a dipole forming between the oxide and the active organic layer in a model ZnMO / P3HT:PCBM OPV as well as lead to improved surface...

  16. Development of High-Volume Warm Forming of Low-Cost Magnesium...

    Broader source: Energy.gov (indexed) [DOE]

    Yingbing Luo, George Luckey * GM - Paul Krajewski, Ravi Verma Contracts * Troy Tooling Technologies - Dennis Cedar * Materials Suppliers - Magnesium Elektron - POSCO -...

  17. Blood pressure and red blood cell magnesium, potassium, and calcium responses to dietary fats

    E-Print Network [OSTI]

    Wehrman, Noreen Elaine

    1993-01-01T23:59:59.000Z

    of hypertension. The role of dietary fats in blood pressure regulation is being studied more closely, with careful consideration to their actions on prostaglandin synthesis, membrane fluidity and permeability, and electrolyte balance. This study examined... Page 111 . V1 V11 . 1X Problem Identification. Electrolytes. Magnesium . The Role of Magnesium and Ion Transport . The Relationship Between Magnesium and Potassium. The Relationship Between Magnesium and Calcium. The Relationship Between...

  18. A new approach to studying aqueous reactions using diffuse reflectance infrared Fourier transform spectrometry: application to the uptake and oxidation of SO2 on OH-processed model sea salt aerosol.

    E-Print Network [OSTI]

    Shaka', Huda; Robertson, W H; Finlayson-Pitts, Barbara J

    2007-01-01T23:59:59.000Z

    2 on OH-processed model sea salt aerosolw Huda Shaka’, W. H.point of the magnesium salt but below that of NaCl. ThisOH-processing of the salt. Further uptake and oxidation of

  19. Nanostructured material for advanced energy storage : magnesium battery cathode development.

    SciTech Connect (OSTI)

    Sigmund, Wolfgang M. (University of Florida, Gainesville, FL); Woan, Karran V. (University of Florida, Gainesville, FL); Bell, Nelson Simmons

    2010-11-01T23:59:59.000Z

    Magnesium batteries are alternatives to the use of lithium ion and nickel metal hydride secondary batteries due to magnesium's abundance, safety of operation, and lower toxicity of disposal. The divalency of the magnesium ion and its chemistry poses some difficulties for its general and industrial use. This work developed a continuous and fibrous nanoscale network of the cathode material through the use of electrospinning with the goal of enhancing performance and reactivity of the battery. The system was characterized and preliminary tests were performed on the constructed battery cells. We were successful in building and testing a series of electrochemical systems that demonstrated good cyclability maintaining 60-70% of discharge capacity after more than 50 charge-discharge cycles.

  20. PITTING CORROSION ON MAGNESIUM ALLOYS : A COMPARATIVE STUDY OF FIELD DATA USING EXTREME VALUE

    E-Print Network [OSTI]

    Maume-Deschamps, Véronique

    PITTING CORROSION ON MAGNESIUM ALLOYS : A COMPARATIVE STUDY OF FIELD DATA USING EXTREME VALUE corrosion of the magnesium alloys AZ91D and AM60B combined with different coatings on steel bolts was investigated in field corrosion tests carried out by Volvo Car Corporation. Light metals like magnesium

  1. X-ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin Films

    E-Print Network [OSTI]

    X-ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin Films T. J. Richardsona@lbl.gov Abstract Mixed metal thin films containing magnesium and a first-row transition element exhibit very large of magnesium hydride. Keywords: A. hydrogen storage materials, thin films; C. EXAFS, NEXAFS, X-ray diffraction

  2. Evaluation of microstructural eects on corrosion behaviour of AZ91D magnesium

    E-Print Network [OSTI]

    Zhou, Wei

    . Magnesium and its alloys, with one quarter of the density of steel and only two thirds that of aluminium of the prerequisites for all these applications. The corrosion behaviour of cast magnesium±aluminium alloys couldEvaluation of microstructural eects on corrosion behaviour of AZ91D magnesium alloy Rajan Ambat

  3. Prompt {gamma}-ray spectroscopy of the {sup 104}Mo and {sup 108}Mo fission fragments

    SciTech Connect (OSTI)

    Guessous, A.; Schulz, N.; Bentaleb, M.; Lubkiewicz, E. [Centre de Recherches Nucleaires, Institut National de Physique Nucleaire et de Physique des Particules, Centre National de la Recherche Scientifique, Universite Louis Pasteur, 67037 Strasbourg (France)] [Centre de Recherches Nucleaires, Institut National de Physique Nucleaire et de Physique des Particules, Centre National de la Recherche Scientifique, Universite Louis Pasteur, 67037 Strasbourg (France); Durell, J.L.; Pearson, C.J.; Phillips, W.R.; Shannon, J.A.; Urban, W.; Varley, B.J. [Department of Physics, University of Manchester, M13 9PL (United Kingdom)] [Department of Physics, University of Manchester, M13 9PL (United Kingdom); Ahmad, I.; Lister, C.J.; Morss, L.R.; Nash, K.L.; Williams, C.W. [Argonne National Laboratory, Argonne, Illinois 60439 (United States)] [Argonne National Laboratory, Argonne, Illinois 60439 (United States); Khazrouni, S. [Laboratoire de Physique Nucleaire Appliquee, Faculte des Sciences, Kenitra, Maroc (France)] [Laboratoire de Physique Nucleaire Appliquee, Faculte des Sciences, Kenitra, Maroc (France)

    1996-03-01T23:59:59.000Z

    The level structures of the neutron-rich {sup 104}Mo and {sup 108}Mo nuclei have been investigated by observing prompt {gamma} rays emitted in the spontaneous fission of {sup 248}Cm with the EUROGAM spectrometer. Levels with spins up to 12{h_bar} have been observed and {gamma} branching obtained. The data can be satisfactorily described when {sup 104,108}Mo are considered as axially symmetric nuclei: in {sup 104}Mo, rotational bands based on the ground state, the one-phonon and the two-phonon {gamma}-vibrational states and a quasiparticle state have been observed, whereas in {sup 108}Mo the information is limited to the yrast band and the one phonon {gamma} band. {copyright} {ital 1996 The American Physical Society.}

  4. Tunable MoS{sub 2} bandgap in MoS{sub 2}-graphene heterostructures

    SciTech Connect (OSTI)

    Ebnonnasir, Abbas [Department of Mechanical Engineering and Materials Science Program, Colorado School of Mines, Golden, Colorado 80401 (United States); Department of Materials Science and Engineering, University of California Los Angeles, Los Angeles, California 90095 (United States); Narayanan, Badri; Ciobanu, Cristian V., E-mail: cciobanu@mines.edu, E-mail: kodambaka@ucla.edu [Department of Mechanical Engineering and Materials Science Program, Colorado School of Mines, Golden, Colorado 80401 (United States); Kodambaka, Suneel, E-mail: cciobanu@mines.edu, E-mail: kodambaka@ucla.edu [Department of Materials Science and Engineering, University of California Los Angeles, Los Angeles, California 90095 (United States)

    2014-07-21T23:59:59.000Z

    Using density functional theory calculations with van der Waals corrections, we investigated how the interlayer orientation affects the structure and electronic properties of MoS{sub 2}-graphene bilayer heterostructures. Changing the orientation of graphene with respect to MoS{sub 2} strongly influences the type and the value of the electronic bandgap in MoS{sub 2}, while not significantly altering the binding energy between the layers or the interlayer spacing. We show that the physical origin of this tunable bandgap arises from variations in the S–S interplanar distance (MoS{sub 2} thickness) with the interlayer orientation, variations which are caused by electron transfer away from the Mo–S bonds.

  5. Determination of carbon, nitrogen, and oxygen in high purity magnesium

    E-Print Network [OSTI]

    Roche, Neil Gerard

    1981-01-01T23:59:59.000Z

    the determination of low Z impurities (carbon, nitrogen, and oxygen) is a prerequisite for gaining an understanding of the effects of chemical imperfections on the physical, metallurgical, and chemical properties of magnesium (2). The purpose of this study... of nitrogen was accomplished with a 7. 8 MeV Be beam and 9 3 some modifications of the preceeding He procedure were necessary due to the nature of the ion beam. Sam les and Standards Eleven magnesium ingots were received from Dow Chemical Co. , Texas...

  6. The magnesium nutrition of cotton as influenced by sodium 

    E-Print Network [OSTI]

    Thenabadu, Mervyn Wellesly

    1964-01-01T23:59:59.000Z

    1964 Major Subject. Plant Physic logy THE MAGNESIUM NUTRITION OF COTTON AS INFLUENCED BY SODIUM A Thesis By MERVYN M. THENABADU Approved as to style and content by: Chairman of Commi. e Nun Head of Department Member Mem, er Member Member... REVIEW OF LITERATURE (a) Sodium as a plant nutrient (b) I'he role of magnesium in plant nutrition MATERIALS AND METHODS RESUL:S DISCUSSION 13 21 24 (a) The effect of treatments on grcwth and reproduction (b) The effect of treatments on the ccr...

  7. Exercise training reverses age-induced inducible nitric oxide synthase upregulation

    E-Print Network [OSTI]

    Song, Wook

    2005-02-17T23:59:59.000Z

    muscle, and 2) to identify the mechanisms by which exercise training reduces pro-oxidant signaling. Protein levels and activity of iNOS were measured in 4 groups of male Fischer-344 rats (5 mo and 24 mo, n=10/group), old-control (OC), old-trained (OT...

  8. Surface Science Letters Synthesis of well-ordered ultra-thin titanium oxide films

    E-Print Network [OSTI]

    Goodman, Wayne

    Surface Science Letters Synthesis of well-ordered ultra-thin titanium oxide films on Mo(112) M microscopy (STM); X-ray photoelectron spectroscopy (XPS); Titanium oxide; Surface structure, morphology oxide systems, titanium dioxide has served as the prototypical reducible 0039-6028/$ - see front matter

  9. Elevated Temperature Tensile Tests on DU–10Mo Rolled Foils

    SciTech Connect (OSTI)

    Jason Schulthess

    2014-09-01T23:59:59.000Z

    Tensile mechanical properties for uranium-10 wt.% molybdenum (U–10Mo) foils are required to support modeling and qualification of new monolithic fuel plate designs. It is expected that depleted uranium-10 wt% Mo (DU–10Mo) mechanical behavior is representative of the low enriched U–10Mo to be used in the actual fuel plates, therefore DU-10Mo was studied to simplify material processing, handling, and testing requirements. In this report, tensile testing of DU-10Mo fuel foils prepared using four different thermomechanical processing treatments were conducted to assess the impact of foil fabrication history on resultant tensile properties.

  10. Preparation of amorphous electrochromic tungsten oxide and molybdenum oxide by plasma enhanced chemical vapor deposition

    SciTech Connect (OSTI)

    Tracy, C.E.; Benson, D.K.

    1986-09-01T23:59:59.000Z

    Preliminary experiments have been performed to probe the feasibility of using plasma enhanced chemical vapor deposition (PE--CVD) to prepare electrochromic thin films of tungsten oxide and molybdenum oxide by plasma reaction of WF/sub 6/, W(CO)/sub 6/, and Mo(CO)/sub 6/ with oxygen. Thin films produced in a 300 W, electrodeless, radio-frequency (rf), capacitive discharge were found to be electrochromic when tested with either liquid or solid electrolytes. Optical spectroscopy was performed on two electrochromic coatings after Li/sup +/ ion insertion from a propylene carbonate liquid electrolyte. Broad absorption peaks at --900 nm for WO/sub 3/ and 600 nm for MoO/sub 3/ were observed. Optical results for PE--CVD MoO/sub 3/ films differ from those reported for evaporated MoO/sub 3/ films which have an absorption peak at --800 nm. The shorter wavelength absorption in the PE--CVD MoO/sub 3/ films offers the potential for fabricating electrochromic devices with higher contrast ratios and less color change. Optical emission spectroscopy, Auger, and x-ray diffraction analyses indicate these thin film deposits to be predominantly amorphous tungsten and molybdenum oxides.

  11. Wetting of metals and glasses on Mo

    SciTech Connect (OSTI)

    Saiz, Eduardo; Tomsia, Antoni P.; Saiz, Eduardo; Lopez-Esteban, Sonia; Benhassine, Mehdi; de Coninck, Joel; Rauch, Nicole; Ruehle, Manfred

    2008-01-08T23:59:59.000Z

    The wetting of low melting point metals and Si-Ca-Al-Ti-O glasses on molybdenum has been investigated. The selected metals (Au, Cu, Ag) form a simple eutectic with Mo. Metal spreading occurs under nonreactive conditions without interdiffusion or ridge formation. The metals exhibit low (non-zero) contact angles on Mo but this requires temperatures higher than 1100 C in reducing atmospheres in order to eliminate a layer of adsorbed impurities on the molybdenum surface. By controlling the oxygen activity in the furnace, glass spreading can take place under reactive or nonreactive conditions. We have found that in the glass/Mo system the contact angle does not decrease under reactive conditions. In all cases, adsorption from the liquid seems to accelerate the diffusivity on the free molybdenum surface.

  12. A Life Cycle Assessment of a Magnesium Automotive Front End

    SciTech Connect (OSTI)

    Das, Sujit [ORNL; Dubreuil, Alain [Natural Resources Canada; Bushi, Lindita [GreenhouseGasMeasurement.com; Tharumarajah, Ambalavanar [CSIRO/CAST-CRC

    2009-01-01T23:59:59.000Z

    The Magnesium Front End Research and Development (MFERD) project under the sponsorship of Canada, China and USA aims to develop key technologies and a knowledge base for increased use of magnesium in automobile. The goal of this life cycle assessment (LCA) study is to compare the energy and potential environmental impacts of advanced magnesium based front end parts of a North America built 2007 GM-Cadillac CTS with the standard carbon steel based design. This LCA uses the 'cradle-to-grave' approach by including primary material production, semi-fabrication production, autoparts manufacturing and assembly, transportation, use phase and end-of-life processing of autoparts. This LCA study was done in compliance with international standards ISO 14040:2006 and ISO 14044:2006. Furthermore, the LCA results for aluminum based front end autopart are presented. While weight savings result in reductions in energy use and carbon dioxide emissions during the use of the car, the impacts of fabrication and recycling of lightweight materials are substantial in regard to steel. Pathways for improving sustainability of magnesium use in automobiles through material management and technology improvements including recycling are also discussed.

  13. The magnesium nutrition of American upland and Egyptian cottons

    E-Print Network [OSTI]

    Helmy, Hussein

    1956-01-01T23:59:59.000Z

    of phosphate, it is believed to be involved 1n phospholipM formation and in the synthesis of nucleo-proteins 1n plant cells accord- ing to Trucg gt al . (56). Bear et sic (4) found that oily seeds are especially h1gh in magnesium indicating some close...

  14. The Microstructure of Mechanically Alloyed Nanocrystalline Aluminium-Magnesium

    E-Print Network [OSTI]

    Gubicza, Jenõ

    The Microstructure of Mechanically Alloyed Nanocrystalline Aluminium-Magnesium Jen Gubicza1, mechanical alloying, nanocrystalline Al-Mg alloys Abstract. The effect of the nominal Mg content and the milling time on the microstructure of mechanically alloyed Al(Mg) solid solutions is studied

  15. Effect of tungsten on the electrochromic behaviour of sol-gel dip coated molybdenum oxide thin films

    SciTech Connect (OSTI)

    Dhanasankar, M. [Department of Physics, Kamaraj College of Engineering and Technology, Virudhunagar 626001 (India)] [Department of Physics, Kamaraj College of Engineering and Technology, Virudhunagar 626001 (India); Purushothaman, K.K. [Department of Physics, The Gandhigram Rural Institute - Deemed University, Gandhigram 624302, Tamilnadu (India)] [Department of Physics, The Gandhigram Rural Institute - Deemed University, Gandhigram 624302, Tamilnadu (India); Muralidharan, G., E-mail: muraligru@gmail.com [Department of Physics, The Gandhigram Rural Institute - Deemed University, Gandhigram 624302, Tamilnadu (India)

    2010-05-15T23:59:59.000Z

    The paper describes the results obtained on the performance of Mo oxide and mixed W/Mo oxide thin films for possible electrochromic applications. Mo and W/Mo oxide films were deposited on conductive (FTO) glass substrates using sol-gel dip coating method. The films were annealed at 250 {sup o}C for 30 min. The structure and morphology of Mo and W/Mo oxide films were examined using XRD, SEM and EDS. XRD results indicate the amorphous nature of the Mo and W/Mo oxide films annealed for 30 min. The CV measurements revealed that the films prepared with 10 wt.% of tungsten exhibit maximum anodic/cathodic diffusion coefficient of 24.99/12.71 x 10{sup -11} cm{sup 2}/s. The same film exhibits a maximum transmittance variation ({Delta}T%) of 83.4% at 630 nm and 81.06% at 550 nm with the optical density of 1.00 and 1.13 respectively.

  16. Solid electrolyte based sensor for monitoring the magnesium level during reclamation of aluminum scrap

    SciTech Connect (OSTI)

    Fergus, J.W.; Hui, S. [Auburn Univ., AL (United States). Materials Research and Education Center

    1996-10-01T23:59:59.000Z

    Aluminum alloy scrap often contains excess magnesium which must be removed during recycling by a process referred to as demagging. The efficiency of this process could be improved with an in-situ magnesium sensor, which could be used to optimize the process parameters to the changing magnesium content. The sensor developed in this work consists of a galvanic cell with a magnesium fluoride (MgF{sub 2}) solid electrolyte and a molten magnesium reference electrode. The voltage output of the sensor changes by about 100 mV for the change in magnesium content which occurs during the demagging process (5 wt% to 0.1 wt%) and is in excellent agreement with thermodynamic measurements using molten chloride electrolytes. This paper focuses on the effect of silicon, which is a common alloying element in aluminum alloys, on the output of an electrochemical magnesium sensor.

  17. The effect of a prolonged magnesium restriction on the humoral immune response in maternal rats and their offspring 

    E-Print Network [OSTI]

    Cohill, Diane T

    1987-01-01T23:59:59.000Z

    and to observe alteration in these effects resulting from magnesium supplementation during gestation and lactation. Female weanling Sprague-Dawley rats were provided diets containing adequate (1200 mg Mg/kg diet) or inadequate (200 mg Mg/kg diet) magnesium...), was lower in the magnesium-restricted dams, In the group which had been magnesium restricted during growth but then received supplemental magnesium during gestation and lactation, dams had an improved immune r esponse; but pups did not lt was conc...

  18. Mo Supply Chain for Nuclear Medicine Ladimer S. Nagurney

    E-Print Network [OSTI]

    Nagurney, Anna

    The 99 Mo Supply Chain for Nuclear Medicine Ladimer S. Nagurney Department of Electrical November 13, 2012 #12;Nuclear Medicine: Meeting Patient Needs with 99 Mo Ladimer S. Nagurney The 99 Mo Supply Chain #12;Background and Motivation Study of Nuclear Medicine Supply Chains is a combination

  19. Method for generating a crystalline .sup.99 MoO.sub.3 product and the isolation .sup.99m Tc compositions therefrom

    DOE Patents [OSTI]

    Bennett, Ralph G. (Idaho Falls, ID); Christian, Jerry D. (Idaho Falls, ID); Kirkham, Robert J. (Blackfoot, ID); Tranter, Troy J. (Idaho Falls, ID)

    1998-01-01T23:59:59.000Z

    An improved method for producing .sup.99m Tc compositions. .sup.100 Mo metal is irradiated with photons in a particle (electron) accelerator to produce .sup.99 Mo metal which is dissolved in a solvent. A solvated .sup.99 Mo product is then dried to generate a supply of .sup.99 MoO.sub.3 crystals. The crystals are thereafter heated at a temperature which will sublimate the crystals and form a gaseous mixture containing vaporized .sup.99m TcO.sub.3 and vaporized .sup.99m TcO.sub.2 but will not cause the production of vaporized .sup.99 MoO.sub.3. The mixture is then combined with an oxidizing gas to generate a gaseous stream containing vaporized .sup.99m Tc.sub.2 O.sub.7. Next, the gaseous stream is cooled to a temperature sufficient to convert the vaporized .sup.99m Tc.sub.2 O.sub.7 into a condensed .sup.99m Tc-containing product. The product has high purity levels resulting from the use of reduced temperature conditions and ultrafine crystalline .sup.99 MoO.sub.3 starting materials with segregated .sup.99m Tc compositions therein which avoid the production of vaporized .sup.99 MoO.sub.3 contaminants.

  20. Method for generating a crystalline {sup 99}MoO{sub 3} product and the isolation {sup 99m}Tc compositions therefrom

    DOE Patents [OSTI]

    Bennett, R.G.; Christian, J.D.; Kirkham, R.J.; Tranter, T.J.

    1998-09-01T23:59:59.000Z

    An improved method is described for producing {sup 99m}Tc compositions. {sup 100}Mo metal is irradiated with photons in a particle (electron) accelerator to produce {sup 99}Mo metal which is dissolved in a solvent. A solvated {sup 99}Mo product is then dried to generate a supply of {sup 99}MoO{sub 3} crystals. The crystals are thereafter heated at a temperature which will sublimate the crystals and form a gaseous mixture containing vaporized {sup 99m}TcO{sub 3} and vaporized {sup 99m}TcO{sub 2} but will not cause the production of vaporized {sup 99}MoO{sub 3}. The mixture is then combined with an oxidizing gas to generate a gaseous stream containing vaporized {sup 99m}Tc{sub 2}O{sub 7}. Next, the gaseous stream is cooled to a temperature sufficient to convert the vaporized {sup 99m}Tc{sub 2}O{sub 7} into a condensed {sup 99m}Tc-containing product. The product has high purity levels resulting from the use of reduced temperature conditions and ultrafine crystalline {sup 99}MoO{sub 3} starting materials with segregated {sup 99m}Tc compositions therein which avoid the production of vaporized {sup 99}MoO{sub 3} contaminants. 1 fig.

  1. Role of SrMoO{sub 4} in Sr{sub 2}MgMoO{sub 6} synthesis

    SciTech Connect (OSTI)

    Vasala, S.; Yamauchi, H. [Laboratory of Inorganic Chemistry, Department of Chemistry, School of Chemical Technology, Aalto University, P.O. Box 16100, FI-00076 Aalto (Finland); Karppinen, M., E-mail: maarit.karppinen@aalto.f [Laboratory of Inorganic Chemistry, Department of Chemistry, School of Chemical Technology, Aalto University, P.O. Box 16100, FI-00076 Aalto (Finland)

    2011-05-15T23:59:59.000Z

    Here we investigate the elemental and phase compositions during the solid-state synthesis of the promising SOFC-anode material, Sr{sub 2}MgMoO{sub 6}, and demonstrate that molybdenum does not notably evaporate under the normal synthesis conditions with temperatures up to 1200 {sup o}C due to the formation of SrMoO{sub 4} as an intermediate product at low temperatures, below 600 {sup o}C. However, partial decomposition of the Sr{sub 2}MgMoO{sub 6} phase becomes evident at the higher temperatures ({approx}1500 {sup o}C). The effect of SrMoO{sub 4} on the electrical conductivity of Sr{sub 2}MgMoO{sub 6} is evaluated by preparing a series of Sr{sub 2}MgMoO{sub 6} samples with different amounts of additional SrMoO{sub 4}. Under the reducing operation conditions of an SOFC anode the insulating SrMoO{sub 4} phase is apparently reduced to the highly conductive SrMoO{sub 3} phase. Percolation takes place with 20-30 wt% of SrMoO{sub 4} in a Sr{sub 2}MgMoO{sub 6} matrix, with a notable increase in electrical conductivity after reduction. Conductivity values of 14, 60 and 160 S/cm are determined at 800 {sup o}C in 5% H{sub 2}/Ar for the Sr{sub 2}MgMoO{sub 6} samples with 30, 40 and 50 wt% of added SrMoO{sub 4}, respectively. -- Graphical abstract: SrMoO{sub 4} is formed at low temperatures during the synthesis of Sr{sub 2}MgMoO{sub 6}, which prevents the volatilization of Mo from typical precursor mixtures of this promising SOFC anode material. SrMoO{sub 4} is insulating and it is often found as an impurity in Sr{sub 2}MgMoO{sub 6} samples. It is however readily reduced to highly conducting SrMoO{sub 3}. Composites of Sr{sub 2}MgMoO{sub 6} and SrMoO{sub 3} show increased electrical conductivities compared to pure Sr{sub 2}MgMoO{sub 6} under the reductive operation conditions of an SOFC anode. Display Omitted Highlights: {yields} Sr{sub 2}MgMoO{sub 6} is a promising SOFC anode material. {yields} During the Sr{sub 2}MgMoO{sub 6} synthesis SrMoO{sub 4} is formed at low temperatures. {yields} Formation of SrMoO{sub 4} effectively prevents volatilization of Mo at high temperatures. {yields} Insulating SrMoO{sub 4} reduces to highly conductive SrMoO{sub 3} under SOFC-anode conditions. {yields} Composites of Sr{sub 2}MgMoO{sub 6} and SrMoO{sub 3} show high electrical conductivities.

  2. Development of CaMoO4 crystal scintillators for double beta decay experiment with 100-Mo

    E-Print Network [OSTI]

    A. N. Annenkov; O. A. Buzanov; F. A. Danevich; A. Sh. Georgadze; S. K. Kim; H. J. Kim; Y. D. Kim; V. V. Kobychev; V. N. Kornoukhov; M. Korzhik; J. I. Lee; O. Missevitch; V. M. Mokina; S. S. Nagorny; A. S. Nikolaiko; D. V. Poda; R. B. Podviyanuk; D. J. Sedlak; O. G. Shkulkova; J. H. So; I. M. Solsky; V. I. Tretyak; S. S. Yurchenko

    2007-07-10T23:59:59.000Z

    Energy resolution, alpha/beta ratio, pulse-shape discrimination for gamma rays and alpha particles, temperature dependence of scintillation properties, and radioactive contamination were studied with CaMoO4 crystal scintillators. A high sensitivity experiment to search for neutrinoless double beta decay of 100-Mo by using CaMoO4 scintillators is discussed.

  3. The usefulness of solid oxidants for biostimulation, determined by their kinetics and stoichiometry

    E-Print Network [OSTI]

    Waite, Andrew James

    1996-01-01T23:59:59.000Z

    model for the release of oxygen from these solid additives. The four oxidants were: sodium-percarbonate (Na2CO3'1.5H202) encapsulated in poly(vinyhdene chloride) (PVDC); free sodium-percarbonate crystals; calcium peroxide (CaO2); and magnesium peroxide...

  4. Lithium metal oxide electrodes for lithium batteries

    DOE Patents [OSTI]

    Thackeray, Michael M.; Johnson, Christopher S.; Amine, Khalil; Kang, Sun-Ho

    2010-06-08T23:59:59.000Z

    An uncycled preconditioned electrode for a non-aqueous lithium electrochemical cell including a lithium metal oxide having the formula xLi.sub.2-yH.sub.yO.xM'O.sub.2.(1-x)Li.sub.1-zH.sub.zMO.sub.2 in which 0oxidation state selected from two or more of the first row transition metals or lighter metal elements in the periodic table, and M' is one or more ions with an average tetravalent oxidation state selected from the first and second row transition metal elements and Sn. The xLi.sub.2-yH.sub.y.xM'O.sub.2.(1-x)Li.sub.1-zH.sub.zMO.sub.2 material is prepared by preconditioning a precursor lithium metal oxide (i.e., xLi.sub.2M'O.sub.3.(1-x)LiMO.sub.2) with a proton-containing medium with a pH<7.0 containing an inorganic acid. Methods of preparing the electrodes are disclosed, as are electrochemical cells and batteries containing the electrodes.

  5. The influence of zeta potential and yield stress on the filtration characteristics of a magnesium hydroxide simulant

    SciTech Connect (OSTI)

    Biggs, Simon; Nabi, Rafiq; Poole, Colin [Leeds University/Nexia Solutions URA in Particle Science and Technology, Institute of Particle Science and Engineering, School of Process, Environmental and Materials Engineering, The University of Leeds, Leeds LS2 9JT (United Kingdom); Patel, Ashok [British Nuclear Group, Reactor Sites, Berkeley Centre, Berkeley, Gloucestershire, GL13 9PB (United Kingdom)

    2007-07-01T23:59:59.000Z

    In the UK, irradiated fuels from Magnox reactors are often stored in water-filled ponds under alkaline conditions, so as to minimise corrosion of fuel cladding. This is important to prevent or reduce leakage of soluble fission products and actinides to the pond water. A variety of intermediate level wastes derived from Magnox materials are stored at power stations. Under these alkaline conditions, various species of magnesium are formed, of which magnesium hydroxide is the dominant material. The particle-fluid interactions are significant for the design and operation of facilities for hydraulic retrieval, filtration, dewatering and ion exchange treatment of fuel storage pond water and stored wet Magnox wastes. Here we describe a study of particulate properties and filtration characteristics of oxide particle simulants under laboratory conditions. Cake and medium resistance data were correlated across a range of pH conditions with electro-acoustic zeta potential and shear yield stress measurements, as a function of particle volume fractions. The influence of zeta potential on filtration properties arises directly from the interaction of particles within the sediment cake. (authors)

  6. An examination of the relationship between calcium and magnesium and hypertension

    E-Print Network [OSTI]

    Georghiades, Mary Elizabeth

    1988-01-01T23:59:59.000Z

    !ae thr ee blood parameter s best corre)ated with the dietary intake of calcium and magnesium. No i gni f i cant cor r el at i ons (p (0. 05) were ob . , envs d between the calcium, magnesium, or ca)cium/magnesium ratio of the diet and blood tissues... in alterations in the calcium/magnesium ratio. This topic merits Further investigation. ACKNOWLEDGMENTS The author wishes to express her appreciation to Dr. Karen S. Kubena, her advisory committee chairman. For- pr oper guidance, constructive criticism...

  7. Magnesium and pyridoxine intake and mineral content of selected tissues and physical development in rats 

    E-Print Network [OSTI]

    Edgar, Susan Elaine

    1986-01-01T23:59:59.000Z

    lower f eed intake s than did rats from other dietary treatments. During lactation, dai ly feed consumpt ion was lower in an ima1 s depr ived of magnesium. Approximately 24 hr postpartum, in dams who consumed a magnesium-deficient diet, the heart... and kidney contained significantly more calcium, 150'% and 300% respectively. During lactation, mild magnesium restriction resulted in increased weight loss by dams and decreased weight gain by pupa. In the of f spring of rats dep1 et ed o f magnesium...

  8. Upcoming Management and Operating (M&O) Contract Competition...

    National Nuclear Security Administration (NNSA)

    Upcoming Management and Operating (M&O) Contract Competition | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile...

  9. Interdiffusion between Zr Diffusion Barrier and U-Mo Alloy

    SciTech Connect (OSTI)

    K. Huang; Y. Park; Y. H. Sohn

    2012-12-01T23:59:59.000Z

    U-Mo alloys are being developed as low enrichment uranium fuels under the Reduced Enrichment for Research and Test Reactor (RERTR) program. Significant reactions have been observed between U-Mo fuels and Al or Al alloy matrix. Refractory metal Zr has been proposed as barrier material to reduce the interactions. In order to investigate the compatibility and barrier effects between U-Mo alloy and Zr, solid-to-solid U-10wt.%Mo vs. Zr diffusion couples were assembled and annealed at 600, 700, 800, 900 and 1000 °C for various times. The microstructures and concentration profiles due to interdiffusion and reactions were examined via scanning electron microscopy and electron probe microanalysis, respectively. Intermetallic phase Mo2Zr was found at the interface and its population increased when annealing temperature decreased. Diffusion paths were also plotted on the U-Mo-Zr ternary phase diagrams with good consistency. The growth rate of interdiffusion zone between U-10wt.%Mo and Zr was also calculated under the assumption of parabolic diffusion, and was determined to be about 103 times lower than the growth rate of diffusional interaction layer found in diffusion couples U-10wt.%Mo vs. Al or Al-Si alloy. Other desirable physical properties of Zr as barrier material, such as neutron adsorption rate, melting point and thermal conductivity are presented as supplementary information to demonstrate the great potential of Zr as the diffusion barrier for U-Mo fuel systems in RERTR.

  10. Methane-to-Methanol Conversion by Gas-Phase Transition Metal Oxide Cations: Experiment and Theory

    E-Print Network [OSTI]

    Metz, Ricardo B.

    Methane-to-Methanol Conversion by Gas-Phase Transition Metal Oxide Cations: Experiment and Theory-phase transition metal oxide cations can convert methane to methanol. Methane activation by MO+ is discussed such as methanol has attracted great experimental and theoretical interest due to its importance as an industrial

  11. Mo Year Report Period: EIA ID NUMBER:

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTownDells, Wisconsin:DeploymentSite Name:24,High824 2.839 2.8352.747 2.759 2.699Mo

  12. Continuing investigations for technology assessment of /sup 99/Mo production from LEU (low enriched Uranium) targets

    SciTech Connect (OSTI)

    Vandergrift, G.F.; Kwok, J.D.; Marshall, S.L.; Vissers, D.R.; Matos, J.E.

    1987-01-01T23:59:59.000Z

    Currently much of the world's supply of /sup 99m/Tc for medical purposes is produced from /sup 99/Mo derived from the fissioning of high enriched uranium (HEU). The need for /sup 99m/Tc is continuing to grow, especially in developing countries, where needs and national priorities call for internal production of /sup 99/Mo. This paper presents the results of our continuing studies on the effects of substituting low enriched Uranium (LEU) for HEU in targets for the production of fission product /sup 99/Mo. Improvements in the electrodeposition of thin films of uranium metal are reported. These improvements continue to increase the appeal for the substitution of LEU metal for HEU oxide films in cylindrical targets. The process is effective for targets fabricated from stainless steel or hastaloy. A cost estimate for setting up the necessary equipment to electrodeposit uranium metal on cylindrical targets is reported. Further investigations on the effect of LEU substitution on processing of these targets are also reported. Substitution of uranium silicides for the uranium-aluminum alloy or uranium aluminide dispersed fuel used in other current target designs will allow the substitution of LEU for HEU in these targets with equivalent /sup 99/Mo-yield per target and no change in target geometries. However, this substitution will require modifications in current processing steps due to (1) the insolubility of uranium silicides in alkaline solutions and (2) the presence of significant quantities of silicate in solution. Results to date suggest that both concerns can be handled and that substitution of LEU for HEU can be achieved.

  13. Minerals to Dairy Cows with Focus on Calcium and Magnesium Balance

    E-Print Network [OSTI]

    Minerals to Dairy Cows with Focus on Calcium and Magnesium Balance Cecilia Kronqvist Faculty;Minerals to Dairy Cows with Focus on Calcium and Magnesium Balance Abstract Both clinical and subclinical decreased plasma calcium levels and activated the calcium homeostatic mechanisms. However, there were

  14. SIMULATION OF STRESSES DURING CASTING OF BINARY MAGNESIUM-ALUMINUM ALLOYS M.G. Pokorny1

    E-Print Network [OSTI]

    Beckermann, Christoph

    SIMULATION OF STRESSES DURING CASTING OF BINARY MAGNESIUM-ALUMINUM ALLOYS M.G. Pokorny1 , C, Geesthacht, Germany Keywords: Magnesium Alloys, Casting, Stress Simulation Abstract A visco-plastic deformation model is used to predict thermal stresses during casting of binary Mg-Al alloys. The predictions

  15. Reliability of Laser Welding Process for ZE41A-T5 Magnesium Alloy Sand Castings

    E-Print Network [OSTI]

    Medraj, Mamoun

    Reliability of Laser Welding Process for ZE41A-T5 Magnesium Alloy Sand Castings Haider Al-Kazzaz1, National Research Council Canada, Montreal, Canada Laser welding is a promising joining method for magnesium alloys. The process reliability of 2-mm ZE41A-T5 butt joints welded by a 4 kW Nd:YAG laser

  16. In vitro corrosion and biocompatibility of binary magnesium alloys Xuenan Gu a

    E-Print Network [OSTI]

    Zheng, Yufeng

    In vitro corrosion and biocompatibility of binary magnesium alloys Xuenan Gu a , Yufeng Zheng a Corrosion In vitro Cytotoxicity Hemocompatibility a b s t r a c t As bioabsorbable materials, magnesium was used as control. Their mechanical properties, corrosion properties and in vitro biocompatibilities

  17. Electroless iron plating on pure magnesium for biomedical applications Xingkai Zhang a

    E-Print Network [OSTI]

    Zheng, Yufeng

    : Biomaterials Deposition Corrosion Thin films a b s t r a c t Electroless nickel plating is usually adopted geometries. Electroless nickel plating [10] is usually used to protect the magnesium alloy from corrosionElectroless iron plating on pure magnesium for biomedical applications Xingkai Zhang a , Wei Han a

  18. High Performance Batteries Based on Hybrid Magnesium and Lithium Chemistry

    SciTech Connect (OSTI)

    Cheng, Yingwen; Shao, Yuyan; Zhang, Jiguang; Sprenkle, Vincent L.; Liu, Jun; Li, Guosheng

    2014-01-01T23:59:59.000Z

    Magnesium and lithium (Mg/Li) hybrid batteries that combine Mg and Li electrochemistry, consisting of a Mg anode, a lithium-intercalation cathode and a dual-salt electrolyte with both Mg2+ and Li+ ions, were constructed and examined in this work. Our results show that hybrid (Mg/Li) batteries were able to combine the advantages of Li-ion and Mg batteries, and delivered outstanding rate performance (83% for capacities at 15C and 0.1C) and superior cyclic stability (~5% fade after 3000 cycles).

  19. Heat treated 9 Cr-1 Mo steel material for high temperature application

    DOE Patents [OSTI]

    Jablonski, Paul D.; Alman, David; Dogan, Omer; Holcomb, Gordon; Cowen, Christopher

    2012-08-21T23:59:59.000Z

    The invention relates to a composition and heat treatment for a high-temperature, titanium alloyed, 9 Cr-1 Mo steel exhibiting improved creep strength and oxidation resistance at service temperatures up to 650.degree. C. The novel combination of composition and heat treatment produces a heat treated material containing both large primary titanium carbides and small secondary titanium carbides. The primary titanium carbides contribute to creep strength while the secondary titanium carbides act to maintain a higher level of chromium in the finished steel for increased oxidation resistance, and strengthen the steel by impeding the movement of dislocations through the crystal structure. The heat treated material provides improved performance at comparable cost to commonly used high-temperature steels such as ASTM P91 and ASTM P92, and requires heat treatment consisting solely of austenization, rapid cooling, tempering, and final cooling, avoiding the need for any hot-working in the austenite temperature range.

  20. THE SYNTHESIS OF AN INTERSTRATIFIED LAYERED OXIDE FROM EXFOLIATED PRECURSORS

    E-Print Network [OSTI]

    Rohrer, Gregory S.

    THE SYNTHESIS OF AN INTERSTRATIFIED LAYERED OXIDE FROM EXFOLIATED PRECURSORS RICHARD L. SMITH 15213 ABSTRACT Aqueous suspensions of exfoliated Li0 .25MoO 3 and Na-montmorillonite have been combined solids can be exfoliated and restacked to form new interstratified materials. INTRODUCTION A wide variety

  1. Synthesis of MoS? nano-petal forest supported on carbon nanotubes for enhanced field emission performance

    SciTech Connect (OSTI)

    Murawala, Aditya P.; Loh, Tamie A. J.; Chua, Daniel H. C., E-mail: msechcd@nus.edu.sg [Department of Materials Science and Engineering, National University of Singapore, Singapore 117576 (Singapore)

    2014-09-21T23:59:59.000Z

    We report the fabrication of a three-dimensional forest of highly crystalline two-dimensional (2D) molybdenum disulfide (MoS?) nano-petals encapsulating vertically aligned carbon nanotubes (CNT) in a core-shell configuration. Growth was conducted via magnetron sputtering at room temperature and it was found that the nano-petal morphology was formed only when a critical threshold in sputter deposition time was reached. Below this threshold, an amorphous tubular structure composed of mainly molybdenum oxides dominates instead. The presence of the MoS? nano-petals was shown to impart photoluminescence to the CNTs, in addition to significantly enhancing their electron emission properties, where the turn-on field was lowered from 2.50 V?m?¹ for pristine CNTs to 0.80 V?m?¹ for MoS?-CNT heterostructures fabricated at 30 min sputter deposition time. Photoluminescence was detected at wavelengths of approximately 684 nm and 615 nm, with the band at 684 nm gradually blue-shifting as sputter time was increased. These results demonstrate that it is possible to synthesize 2D MoS? layers without the need for chemical routes and high growth temperatures.

  2. Comparative study of water reactivity with Mo{sub 2}O{sub y}{sup ?} and W{sub 2}O{sub y}{sup ?} clusters: A combined experimental and theoretical investigation

    SciTech Connect (OSTI)

    Ray, Manisha; Waller, Sarah E.; Saha, Arjun; Raghavachari, Krishnan; Jarrold, Caroline Chick, E-mail: cjarrold@indiana.edu [Department of Chemistry, Indiana University, Bloomington, Indiana 47405 (United States)

    2014-09-14T23:59:59.000Z

    A computational investigation of the Mo{sub 2}O{sub y}{sup ?} + H{sub 2}O (y = 4, 5) reactions as well as a photoelectron spectroscopic probe of the deuterated Mo{sub 2}O{sub 6}D{sub 2}{sup ?} product have been carried out to understand a puzzling question from a previous study: Why is the rate constant determined for the Mo{sub 2}O{sub 5}{sup ?} + H{sub 2}O/D{sub 2}O reaction, the terminal reaction in the sequential oxidation of Mo{sub 2}O{sub y}{sup ?} by water, higher than the W{sub 2}O{sub 5}{sup ?} + H{sub 2}O/D{sub 2}O reaction? This disparity was intriguing because W{sub 3}O{sub y}{sup ?} clusters were found to be more reactive toward water than their Mo{sub 3}O{sub y}{sup ?} analogs. A comparison of molecular structures reveals that the lowest energy structure of Mo{sub 2}O{sub 5}{sup ?} provides a less hindered water addition site than the W{sub 2}O{sub 5}{sup ?} ground state structure. Several modes of water addition to the most stable molecular and electronic structures of Mo{sub 2}O{sub 4}{sup ?} and Mo{sub 2}O{sub 5}{sup ?} were explored computationally. The various modes are discussed and compared with previous computational studies on W{sub 2}O{sub y}{sup ?} + H{sub 2}O reactions. Calculated free energy reaction profiles show lower barriers for the initial Mo{sub 2}O{sub y}{sup ?} + H{sub 2}O addition, consistent with the higher observed rate constant. The terminal Mo{sub 2}O{sub y}{sup ?} sequential oxidation product predicted computationally was verified by the anion photoelectron spectrum of Mo{sub 2}O{sub 6}D{sub 2}{sup ?}. Based on the computational results, this anion is a trapped dihydroxide intermediate in the Mo{sub 2}O{sub 5}{sup ?} + H{sub 2}O/D{sub 2}O ? Mo{sub 2}O{sub 6}{sup ?} + H{sub 2}/D{sub 2} reaction.

  3. Catalysts for the selective oxidation of hydrogen sulfide to sulfur

    DOE Patents [OSTI]

    Srinivas, Girish (Thornton, CO); Bai, Chuansheng (Baton Rouge, LA)

    2000-08-08T23:59:59.000Z

    This invention provides catalysts for the oxidation of hydrogen sulfide. In particular, the invention provides catalysts for the partial oxidation of hydrogen sulfide to elemental sulfur and water. The catalytically active component of the catalyst comprises a mixture of metal oxides containing titanium oxide and one or more metal oxides which can be selected from the group of metal oxides or mixtures of metal oxides of transition metals or lanthanide metals. Preferred metal oxides for combination with TiO.sub.2 in the catalysts of this invention include oxides of V, Cr, Mn, Fe, Co, Ni, Cu, Nb, Mo, Tc, Ru, Rh, Hf, Ta, W, Au, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu. Catalysts which comprise a homogeneous mixture of titanium oxide and niobium (Nb) oxide are also provided. A preferred method for preparing the precursor homogenous mixture of metal hydroxides is by coprecipitation of titanium hydroxide with one or more other selected metal hydroxides. Catalysts of this invention have improved activity and/or selectivity for elemental sulfur production. Further improvements of activity and/or selectivity can be obtained by introducing relatively low amounts (up to about 5 mol %)of a promoter metal oxide (preferably of metals other than titanium and that of the selected second metal oxide) into the homogeneous metal/titanium oxide catalysts of this invention.

  4. Neutron Hole States of Mo-93,95

    E-Print Network [OSTI]

    Bindal, P. K.; Youngblood, David H.; Kozub, R. L.

    1977-01-01T23:59:59.000Z

    - topes but less than half is observed for '"Mo. The hole strength distributions for l =1 and 4 are displayed in Fig. 10 for all the Mo isotopes. It is apparent from this figure that the states corres- ponding to lgg/2 2Py/2 and 2P, /, orbitals, which...

  5. Neutrino scattering off the stable even-even Mo isotopes

    SciTech Connect (OSTI)

    Balasi, K. G.; Kosmas, T. S.; Divari, P. C. [Theoretical Physics Section, University of Ioannina, GR 45110 Ioannina (Greece)

    2009-11-09T23:59:59.000Z

    Inelastic neutrino-nucleus reaction cross sections are studied focusing on the neutral current processes. Particularly, we investigate the angular and initial neutrino-energy dependence of the differential and integrated cross sections for low and intermediate energies of the incoming neutrino. The nuclear wave functions for the initial and final nuclear states are constructed in the context of the quasi-particle random phase approximation (QRPA) tested on the reproducibility of the low-lying energy spectrum. The results presented here refer to the isotopes Mo{sup 92}, Mo{sup 94}, Mo{sup 96}, Mo{sup 98} and Mo{sup 100}. These isotopes could play a significant role in supernova neutrino detection in addition to their use in double-beta and neutrinoless double-beta decay experiments (e.g. MOON, NEMO III)

  6. Report on Energy Deposition Calculations on the Magnesium Diboride Superconducting Links for the Cold Powering System Deliverable: D6.6

    E-Print Network [OSTI]

    Bignami, A; Santini, C

    2015-01-01T23:59:59.000Z

    Report on Energy Deposition Calculations on the Magnesium Diboride Superconducting Links for the Cold Powering System

  7. Demonstration of resonant photopumping of Mo VII by Mo XII for a VUV laser near 600 {Angstrom}

    SciTech Connect (OSTI)

    Ilcisin, K.J.; Aumayr, F.; Schwob, J.L.; Suckewer, S.

    1993-09-01T23:59:59.000Z

    We present data of experiments on the resonant photopumping of Mo VII by Mo XII as a method of generating a coherent VUV source near 600 {angstrom}. The experiment is based on a scheme proposed by Feldman and Reader in which the 4p{sup 6} -- 4p{sup 5}6s transition in Mo VII in resonantly photopumped by the 5s {sup 2}S{sub 1/2} -- 4p {sup 2}P{sub 1/2} transition in Mo XII. Results of the laser produced plasma experiments show the successful enhancement of the population of the Mo VII 4p{sup 5}6s upper lasing level when pumped by an adjacent Mo VII plasma. No enhancement was seen in a control experiment where the Mo VII plasma was pumped by a Zr X plasma. Improvements of the intensity of the Mo XII pump source, achieved using an additional pump laser, lead to the generation of a population inversion for the VUV transition.

  8. Sonochemical synthesis and photocatalytic property of zinc oxide nanoparticles doped with magnesium(II)

    SciTech Connect (OSTI)

    Lu, Xianyong, E-mail: xylu@buaa.edu.cn [Key Laboratory of Bio-Inspired Smart Interfacial Science and Technology of Ministry of Education, School of Chemistry and Environment, Beihang University, Beijing 100191 (China)] [Key Laboratory of Bio-Inspired Smart Interfacial Science and Technology of Ministry of Education, School of Chemistry and Environment, Beihang University, Beijing 100191 (China); Liu, Zhaoyue; Zhu, Ying [Key Laboratory of Bio-Inspired Smart Interfacial Science and Technology of Ministry of Education, School of Chemistry and Environment, Beihang University, Beijing 100191 (China)] [Key Laboratory of Bio-Inspired Smart Interfacial Science and Technology of Ministry of Education, School of Chemistry and Environment, Beihang University, Beijing 100191 (China); Jiang, Lei, E-mail: jianglei@iccas.ac.cn [Key Laboratory of Bio-Inspired Smart Interfacial Science and Technology of Ministry of Education, School of Chemistry and Environment, Beihang University, Beijing 100191 (China) [Key Laboratory of Bio-Inspired Smart Interfacial Science and Technology of Ministry of Education, School of Chemistry and Environment, Beihang University, Beijing 100191 (China); Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190 (China)

    2011-10-15T23:59:59.000Z

    Highlights: {yields} Mg-doped ZnO nanoparticles were synthesized by sonochemical strategy. {yields} Mg-doped ZnO nanoparticles present good photocatalytic properties. {yields} The change of band gap contributes to their high efficiency in photocatalyst. -- Abstract: Mg-doped ZnO nanoparticles were successfully synthesized by sonochemical method. The products were characterized by scan electron microscopy (SEM) and X-ray powder diffraction (XRD). SEM images revealed that ZnO doped with Mg(II) nanoparticles and ZnO nanoparticles synthesized by the same strategy all had spherical topography. XRD patterns showed that the doped nanoparticles had the same crystals structures as the pure ZnO nanoparticles. The Mg-doped ZnO nanoparticles had larger lattice volume than the un-doped nanoparticles. X-ray photoelectron spectroscopy (XPS) not only demonstrated the moral ratio of Mg and Zn element on the surface of nanoparticles, but their valence in nanoparticles as well. The Mg-doped ZnO nanoparticles presented good properties in photocatalyst compared with pure ZnO nanoparticles.

  9. Solid Oxide Membrane (SOM) Electrolysis of Magnesium: Scale-Up Research and

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33Frequently AskedEnergyIssues DOE's Nuclear EnergySmart Metersofand

  10. Honeywell Modular Automation System Computer Software Documentation for the Magnesium Hydroxide Precipitation Process

    SciTech Connect (OSTI)

    STUBBS, A.M.

    2001-06-25T23:59:59.000Z

    The purpose of this Computer Software Document (CSWD) is to provide configuration control of the Honeywell Modular Automation System (MAS) in use at the Plutonium Finishing Plant (PFP) for the Magnesium Hydroxide Precipitation Process in Rm 230C/234-5Z. The magnesium hydroxide process control software Rev 0 is being updated to include control programming for a second hot plate. The process control programming was performed by the system administrator. Software testing for the additional hot plate was performed per PFP Job Control Work Package 2Z-00-1703. The software testing was verified by Quality Control to comply with OSD-Z-184-00044, Magnesium Hydroxide Precipitation Process.

  11. Low-Temperature, Solution-Processed Molybdenum Oxide Hole-Collection Layer for Organic Photovoltaics

    SciTech Connect (OSTI)

    Hammond, S. R.; Meyer, J.; Widjonarko, N. E.; Ndione, P. F.; Sigdel, A. K.; Garcia, A.; Miedaner, A.; Lloyd, M. T.; Kahn, A.; Ginley, D. S.; Berry, J. J.; Olson, D. C.

    2012-02-21T23:59:59.000Z

    We have utilized a commercially available metal-organic precursor to develop a new, low-temperature, solution-processed molybdenum oxide (MoO{sub x}) hole-collection layer (HCL) for organic photovoltaic (OPV) devices that is compatible with high-throughput roll-to-roll manufacturing. Thermogravimetric analysis indicates complete decomposition of the metal-organic precursor by 115 C in air. Acetonitrile solutions spin-cast in a N{sub 2} atmosphere and annealed in air yield continuous thin films of MoO{sub x}. Ultraviolet, inverse, and X-ray photoemission spectroscopies confirm the formation of MoO{sub x} and, along with Kelvin probe measurements, provide detailed information about the energetics of the MoO{sub x} thin films. Incorporation of these films into conventional architecture bulk heterojunction OPV devices with poly(3-hexylthiophene) and [6,6]-phenyl-C{sub 61} butyric acid methyl ester afford comparable power conversion efficiencies to those obtained with the industry-standard material for hole injection and collection: poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS). The MoO{sub x} HCL devices exhibit slightly reduced open circuit voltages and short circuit current densities with respect to the PEDOT:PSS HCL devices, likely due in part to charge recombination at Mo{sup 5+} gap states in the MoO{sub x} HCL, and demonstrate enhanced fill factors due to reduced series resistance in the MoO{sub x} HCL.

  12. A novel three dimensional semimetallic MoS{sub 2}

    SciTech Connect (OSTI)

    Tang, Zhen-Kun [Beijing Computational Science Research Center, Beijing 100084 (China); Departments of Physics and Electronics, Hengyang Normal University, Hengyang 421008 (China); Zhang, Hui; Liu, Li-Min, E-mail: limin.liu@csrc.ac.cn [Beijing Computational Science Research Center, Beijing 100084 (China); Liu, Hao [Chengdu Green Energy and Green Manufacturing Technology R and D Center, Chengdu, Sichuan 610207 (China); Lau, Woon-Ming [Beijing Computational Science Research Center, Beijing 100084 (China); Chengdu Green Energy and Green Manufacturing Technology R and D Center, Chengdu, Sichuan 610207 (China)

    2014-05-28T23:59:59.000Z

    Transition metal dichalcogenides (TMDs) have many potential applications, while the performances of TMDs are generally limited by the less surface active sites and the poor electron transport efficiency. Here, a novel three-dimensional (3D) structure of molybdenum disulfide (MoS{sub 2}) with larger surface area was proposed based on first-principle calculations. 3D layered MoS{sub 2} structure contains the basal surface and joint zone between the different nanoribbons, which is thermodynamically stable at room temperature, as confirmed by first principles molecular dynamics calculations. Compared the two-dimensional layered structures, the 3D MoS{sub 2} not only owns the large surface areas but also can effectively avoid the aggregation. Interestingly, although the basal surface remains the property of the intrinsic semiconductor as the bulk MoS{sub 2}, the joint zone of 3D MoS{sub 2} exhibits semimetallic, which is derived from degenerate 3d orbitals of the Mo atoms. The high stability, large surface area, and high conductivity make 3D MoS{sub 2} have great potentials as high performance catalyst.

  13. The magnesium nutrition of cotton as influenced by sodium

    E-Print Network [OSTI]

    Thenabadu, Mervyn Wellesly

    1964-01-01T23:59:59.000Z

    -oa:, cld c:t. r. p alit ir a. clans as inrluenced ty siagnesium ard s jiL I . -'?'g"rs f:ct:o" pi ants at weekls lr ti rvdls as it' flL1 reed oy Htdg;1. S1L'm dl. d s 'dium R eld ls. ? chlcr opr yl contet t 1;. inrlu?. . ced ty magnesium ard sc... 1 . au=? as ol m R La=. te carctencio cnt?nt c:r ir. flu reed by maga siu?m arid sc edt. S o LU'm 615 . be distr ibu" c rr c f day - Ld ccttcr pl Cd 10rs li. l;':LSS? Ci 30 at' s distr ibu7 ic. . cf 6G-day olo cct cn radgr. esrum ar. d...

  14. Method and apparatus for detecting the presence and thickness of carbon and oxide layers on EUV reflective surfaces

    DOE Patents [OSTI]

    Malinowski, Michael E.

    2005-01-25T23:59:59.000Z

    The characteristics of radiation that is reflected from carbon deposits and oxidation formations on highly reflective surfaces such as Mo/Si mirrors can be quantified and employed to detect and measure the presence of such impurities on optics. Specifically, it has been shown that carbon deposits on a Mo/Si multilayer mirror decreases the intensity of reflected HeNe laser (632.8 nm) light. In contrast, oxide layers formed on the mirror should cause an increase in HeNe power reflection. Both static measurements and real-time monitoring of carbon and oxide surface impurities on optical elements in lithography tools should be achievable.

  15. Diffusion Barrier Selection from Refractory Metals (Zr, Mo and Nb) via Interdiffusion Investigation for U-Mo RERTR Fuel Alloy

    SciTech Connect (OSTI)

    K. Huang; C. Kammerer; D. D. Keiser, Jr.; Y. H. Sohn

    2014-04-01T23:59:59.000Z

    U-Mo alloys are being developed as low enrichment monolithic fuel under the Reduced Enrichment for Research and Test Reactor (RERTR) Program. Diffusional interactions between the U-Mo fuel alloy and Al-alloy cladding within the monolithic fuel plate construct necessitate incorporation of a barrier layer. Fundamentally, a diffusion barrier candidate must have good thermal conductivity, high melting point, minimal metallurgical interaction, and good irradiation performance. Refractory metals, Zr, Mo, and Nb are considered based on their physical properties, and the diffusion behavior must be carefully examined first with U-Mo fuel alloy. Solid-to-solid U-10wt.%Mo vs. Mo, Zr, or Nb diffusion couples were assembled and annealed at 600, 700, 800, 900 and 1000 degrees C for various times. The interdiffusion microstructures and chemical composition were examined via scanning electron microscopy and electron probe microanalysis, respectively. For all three systems, the growth rate of interdiffusion zone were calculated at 1000, 900 and 800 degrees C under the assumption of parabolic growth, and calculated for lower temperature of 700, 600 and 500 degrees C according to Arrhenius relationship. The growth rate was determined to be about 10 3 times slower for Zr, 10 5 times slower for Mo and 10 6 times slower for Nb, than the growth rates reported for the interaction between the U-Mo fuel alloy and pure Al or Al-Si cladding alloys. Zr, however was selected as the barrier metal due to a concern for thermo- mechanical behavior of UMo/Nb interface observed from diffusion couples, and for ductile-to-brittle transition of Mo near room temperature.

  16. Effect of Texture on Formability and Mechanical Anisotropy of a Severe Plastically Deformed Magnesium Alloy

    E-Print Network [OSTI]

    Modarres Razavi, Sonia

    2012-02-14T23:59:59.000Z

    Magnesium and its alloys have been considered as alternatives to aluminum alloys and steels for structural applications in automotive and aerospace applications due to their superior specific strength and light-weight. However, they have hexagonal...

  17. High-strain-rate nanoindentation behavior of fine-grained magnesium alloys

    E-Print Network [OSTI]

    Somekawa, Hidetoshi

    The effects of temperature and alloying elements on deformation in the high-strain-rate regime were investigated by testing fine-grained magnesium alloys with an average grain size of 2 ? 3 ?m by a nanoindentation technique. ...

  18. Magnesium Silicate Dissolution Investigated by 29Si MAS, 1H-29Si...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Silicate Dissolution Investigated by 29Si MAS, 1H-29Si CP MAS, 25Mg QCPMG, and 1H-25Mg CP QCPMG NMR. Magnesium Silicate Dissolution Investigated by 29Si MAS, 1H-29Si CP MAS, 25Mg...

  19. Vehicle Technologies Office: Long-Term Lightweight Materials Research (Magnesium and Carbon Fiber)

    Broader source: Energy.gov [DOE]

    The Vehicle Technologies Office supports research into magnesium and carbon fiber reinforced composites, which could reduce the weight of some components by 50-75 percent in the long-term.

  20. az91d magnesium alloy: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Page Last Page Topic Index 1 Studies on the inuence of chloride ion and pH on the corrosion and electrochemical behaviour of AZ91D magnesium alloy Engineering Websites Summary:...

  1. az91d magnesium alloys: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Page Last Page Topic Index 1 Studies on the inuence of chloride ion and pH on the corrosion and electrochemical behaviour of AZ91D magnesium alloy Engineering Websites Summary:...

  2. Vehicle Technologies Office Merit Review 2015: Magnesium-Intensive Front End Sub-Structure Development

    Broader source: Energy.gov [DOE]

    Presentation given by USAMP at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about magnesium-intensive front end sub...

  3. Effect of Texture on Formability and Mechanical Anisotropy of a Severe Plastically Deformed Magnesium Alloy 

    E-Print Network [OSTI]

    Modarres Razavi, Sonia

    2012-02-14T23:59:59.000Z

    Magnesium and its alloys have been considered as alternatives to aluminum alloys and steels for structural applications in automotive and aerospace applications due to their superior specific strength and light-weight. However, they have hexagonal...

  4. Magnesium and pyridoxine intake and mineral content of selected tissues and physical development in rats

    E-Print Network [OSTI]

    Edgar, Susan Elaine

    1986-01-01T23:59:59.000Z

    MAGNESIUM AND PYRIDOXINE INTAKE MINERAL CONTENT OF SELECTED TISSUES PHYSICAL DEVELOPMENT IN RATS A Thesis by SU S AN ELA I NE EDGAR Submitted to the Graduate College of Texas A8rM University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE August 1986 Major Subject: Nutrition MAGNESIUM AND PYRIDOXINE INTAKE MINERAL CONTENT OF SELECTED TISSUES PHYS ICAL DEVELOPMENT IN RATS A Thesis by SUSAN ELAINE EDGAR Approved as to style and content by: 'KAREN...

  5. A study of the role of calcium and magnesium in casein micellar structure in human milk 

    E-Print Network [OSTI]

    Gallaway, Sheila Ann

    1988-01-01T23:59:59.000Z

    ) Karen . Kubena (Member) Wa ne L. R&cko11 (Member) G. C. Smith (Head of Department) December 1988 ABSTRACT A Study of the Role of Calcium and Magnesium in Casein Micellar Structure in Human Milk. (December 1988) Sheila Ann Gallaway, B, S.... , Texas ASM University; M. S. , Texas ASM University Chair of Advisory Committee: Dr. C. W. Dill The effects of EDTA, phosphatase hydrolysis, calcium chloride, and magnesium chloride on human casein micelles were observed using electron microscopy...

  6. Magnesium deficiency and type of protein during gestation and lactation in rats 

    E-Print Network [OSTI]

    Holmes, Kathryn Ellen Hughes

    1988-01-01T23:59:59.000Z

    MAGNESIUM DEFICIENCY AND TYPE OF PROTEIN DURING GESTATION AND LACTATION IN RATS A Thesis by KATHRYN ELLEN HUGHES HOLMES Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree... of MASTER OF SCIENCE August 1988 Major Subject: Nutrition MAGNESIUM DEFICIENCY AND TYPE OF PROTEIN DURING GESTATION AND LACTATION IN RATS A Thesis by KATHRYN ELLEN HUGHES HOLMES Approved as to style and content by: Karen S. Kubena (Chair...

  7. An examination of the relationship between calcium and magnesium and hypertension 

    E-Print Network [OSTI]

    Georghiades, Mary Elizabeth

    1988-01-01T23:59:59.000Z

    AN EXAMINATION QF Tl-IE RELATIONSHIP BETWEEN CALCILIM AND MAGNESIUM AND HYPERTENSION A Thesis by MARY ELIZABETH GEORGHIADES Submitted to the Graduate College of Texas ARM University in partial Fulfillment of the requirements For the degree... of MASTER QF SCIENCE May 1988 Major Subject. : Nutrition AN EXAMINATION OF THE RELATIONSHIP BETWEEN CALCIUM AND MAGNESIUM AND HYPERTENSION A Thesis by MARY ELIZABETH GEORGH I ADES Approved as to style and content by: Karen S. Kubena (Chair...

  8. The tolerance of two varieties of cotton to relatively high levels of sodium and magnesium 

    E-Print Network [OSTI]

    Parekh, Manhar C

    1969-01-01T23:59:59.000Z

    THE TO'ERANCE OF TNO VARIETIES OF COTTON TO RELATIVELY HIGH LEVELS OF SODIUM AND MAGNESIUM A Tnesis by Msnhar C. Parekh Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree...) (Nember) (Nemb ) August 1969 ABSTRACT The Tolerance of Two Varieties of Cotton to Relatively High Levels of Sodium and Magnesium. (August 1969) Masher C. Parekh, B. S. , Gujarat University, Directed by: Dr. H. E. Joham An experiment was conducted...

  9. Mechanical Flow Response and Anisotropy of Ultra-Fine Grained Magnesium and Zinc Alloys 

    E-Print Network [OSTI]

    Al Maharbi, Majid H.

    2011-02-22T23:59:59.000Z

    MECHANICAL FLOW RESPONSE AND ANISOTROPY IN ULTRA-FINE GRAINED MAGNESIUM AND ZINC ALLOYS A Dissertation by MAJID AL MAHARBI Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... of the requirements for the degree of DOCTOR OF PHILOSOPHY December 2009 Major Subject: Materials Science and Engineering MECHANICAL FLOW RESPONSE AND ANISOTROPY IN ULTRA-FINE GRAINED MAGNESIUM AND ZINC ALLOYS A Dissertation by MAJID AL...

  10. Determination of the concentrations of magnesium and aluminum in alloys by laser produced atomic emission spectroscopy 

    E-Print Network [OSTI]

    Ashe, William Monroe

    1997-01-01T23:59:59.000Z

    DETERMINATION OF THE CONCENTRATIONS OF MAGNESIUM AND ALUiiINUM IN ALLOYS BY LASER PRODUCED ATOMIC EMISSION SPECTROSCOPY A Thesis by WILLIAM MONROE ASHE Submitted to the Office of Graduate Studies of Texas A&M University in partial... fulfillment of the reqmrements for the degree of MASTER OF SCIENCE December 1997 Major Subject: Physics DETERMINATION OF THE CONCENTRATIONS OF MAGNESIUM AND ALUMINUM ALLOYS BY LASER PRODUCED ATOMIC EMISSION SPECTROSCOPY A Thesis by WILLIAM MONROE ASHE...

  11. Blood pressure and red blood cell magnesium, potassium, and calcium responses to dietary fats 

    E-Print Network [OSTI]

    Wehrman, Noreen Elaine

    1993-01-01T23:59:59.000Z

    for the degree of MASTER OF SCIENCE August 1993 Major Subject: Nutrition BLOOD PRESSURE AND RED BLOOD CELL MAGNESIUM, POTASSIUM, AND CALCIUM RESPONSES TO DIETARY FATS A Thesis by NOREEN ELAINE WEHRMAN Submitted to Texas A&M University in partial.... Edwards (Head of Department) August 1993 Major Subject: Nutrition ABSTRACT Blood Pressure and Red Blood Cell Magnesium, Potassium, and Calcium Responses to Dietary Fats, (August 1993) Noreen Elaine Wehrman, B. S. , Pennsylvania State University...

  12. Novel Nonflammable Electrolytes for Secondary Magnesium Batteries and High Voltage Electrolytes for Electrochemcial Supercapacitors

    SciTech Connect (OSTI)

    Dr. Brian Dixon

    2008-12-30T23:59:59.000Z

    Magnesium has been used successfully in primary batteries, but its use in rechargeable cells has been stymied by the lack of suitable non-aqueous electrolyte that can conduct Mg+2 species, combined with poor stripping and plating properties. The development of a suitable cathode material for rechargeable magnesium batteries has also been a roadblock, but a nonflammable electrolyte is key. Likewise, the development of safe high voltage electrochemical supercapaitors has been stymied by the use of flammable solvents in the liquid electrolyte; to wit, acetonitrile. The purpose of the research conducted in this effort was to identify useful compositions of magnesium salts and polyphosphate solvents that would enable magnesium ions to be cycled within a secondary battery design. The polyphosphate solvents would provide the solvent for the magnesium salts while preventing the electrolyte from being flammable. This would enable these novel electrolytes to be considered as an alternative to THF-based electrolytes. In addition, we explored several of these solvents together with lithium slats for use as high voltage electrolytes for carbon-based electrochemical supercapacitors. The research was successful in that: 1) Magnesium imide dissolved in a phosphate ester solvent that contains a halogented phosphate ester appears to be the preferred electrolyte for a rechargeable Mg cell. 2) A combination of B-doped CNTs and vanadium phosphate appear to be the cathode of choice for a rechargeable Mg cell by virtue of higher voltage and better reversibility. 3) Magnesium alloys appear to perform better than pure magnesium when used in combination with the novel polyphosphate electrolytes. Also, this effort has established that Phoenix Innovationâ??s family of phosphonate/phosphate electrolytes together with specific lithium slats can be used in supercapacitor systems at voltages of greater than 10V.

  13. Fracture and fatigue resistance of MoSiB alloys for ultrahigh-temperature structural applications

    E-Print Network [OSTI]

    Ritchie, Robert

    Fracture and fatigue resistance of Mo­Si­B alloys for ultrahigh-temperature structural applications­Mo3Si­Mo5SiB2 alloys, which utilize a continuous a-Mo matrix to achieve unprecedented room. Introduction For applications such as aerospace engines and power generation, future advancements are limited

  14. Co-Mo Electric Cooperative- Residential Energy Efficiency Rebate Program

    Broader source: Energy.gov [DOE]

    Co-Mo Electric Cooperative provides rebates to residential and commercial members who install air source, dual fuel, and/or geothermal heat pumps, and certain energy efficient appliances. The...

  15. Q value of the 100Mo Double-Beta Decay

    E-Print Network [OSTI]

    S. Rahaman; V. -V. Elomaa; T. Eronen; J. Hakala; A. Jokinen; J. Julin; A. Kankainen; A. Saastamoinen; J. Suhonen; C. Weber; J. Äystö

    2007-12-20T23:59:59.000Z

    Penning trap measurements using mixed beams of 100Mo - 100Ru and 76Ge - 76Se have been utilized to determine the double-beta decay Q-values of 100Mo and 76Ge with uncertainties less than 200 eV. The value for 76Ge, 2039.04(16) keV is in agreement with the published SMILETRAP value. The new value for 100Mo, 3034.40(17) keV is 30 times more precise than the previous literature value, sufficient for the ongoing neutrinoless double-beta decay searches in 100Mo. Moreover, the precise Q-value is used to calculate the phase-space integrals and the experimental nuclear matrix element of double-beta decay.

  16. On the bonding nature of electron states for the Fe-Mo double perovskite

    SciTech Connect (OSTI)

    Carvajal, E.; Cruz-Irisson, M. [ESIME-Culhuacán, Instituto Politécnico Nacional, Av. Santa Ana 1000, C.P. 04430, México, D.F. (Mexico); Oviedo-Roa, R. [Programa de Investigación en Ingeniería Molecular, Instituto Mexicano del Petróleo, Eje Central Lázaro Cárdenas Norte 152, C.P. 07730, México, D.F. (Mexico); Navarro, O. [Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, A.P. 70-360, 04510, México, D.F. (Mexico)

    2014-05-15T23:59:59.000Z

    The electronic transport as well as the effect of an external magnetic field has been investigated on manganese-based materials, spinels and perovskites. Potential applications of double perovskites go from magnetic sensors to electrodes in solid-oxide fuel cells; besides the practical interests, it is known that small changes in composition modify radically the physical properties of double perovskites. We have studied the Sr{sub 2}FeMoO{sub 6} double perovskite compound (SFMO) using first-principles density functional theory. The calculations were done within the generalized gradient approximation (GGA) scheme with the Perdew-Burke-Ernzerhof (PBE) functional. We have made a detailed analysis of each electronic state and the charge density maps around the Fermi level. For the electronic properties of SFMO it was used a primitive cell, for which we found the characteristic half-metallic behavior density of states composed by e{sub g} and t{sub 2g} electrons from Fe and Mo atoms. Those peaks were tagged as bonding or antibonding around the Fermi level at both, valence and conduction bands.

  17. Transparent Conducting ZnO Thin Films Doped with Al and Mo

    SciTech Connect (OSTI)

    Duenow, J.; Gessert, T.; Wood, D.; Young, D.; Coutts, T.

    2007-01-01T23:59:59.000Z

    Transparent conducting oxide (TCO) thin films are a vital part of photovoltaic cells, flat-panel displays, and electrochromic windows. ZnO-based TCOs, due to the relative abundance of Zn, may reduce production costs compared to those of the prevalent TCO In2O3:Sn (ITO). Undoped ZnO, ZnO:Al (0.5, 1, and 2 wt.% Al2O3), and ZnO:Mo (2 wt.%) films were deposited by RF magnetron sputtering. Controlled incorporation of H2 in the Ar sputtering ambient increased mobility of undoped ZnO by a factor of ~20 to 48 cm2V-1s-1. H2 also appears to catalyze ionization of dopants. This enabled lightly doped ZnO:Al to provide comparable conductivity to the standard 2 wt.%-doped ZnO:Al while demonstrating reduced infrared absorption. Mo was found to be an n-type dopant of ZnO, though material properties did not match those of ZnO:Al. Scattering mechanisms were investigated using temperature-dependent Hall measurements and the method of four coefficients. This abstract is subject to government rights.

  18. Nanoscale Phase Separation In Epitaxial Cr-Mo and Cr-V Alloy Thin Films Studied Using Atom Probe Tomography: Comparison Of Experiments And Simulation

    SciTech Connect (OSTI)

    Devaraj, Arun; Kaspar, Tiffany C.; Ramanan, Sathvik; Walvekar, Sarita K.; Bowden, Mark E.; Shutthanandan, V.; Kurtz, Richard J.

    2014-11-21T23:59:59.000Z

    Tailored metal alloy thin film-oxide interfaces generated using molecular beam epitaxial (MBE) deposition of alloy thin films on a single crystalline oxide substrate can be used for detailed studies of irradiation damage response on the interface structure. However presence of nanoscale phase separation in the MBE grown alloy thin films can impact the metal-oxide interface structure. Due to nanoscale domain size of such phase separation it is very challenging to characterize by conventional techniques. Therefor laser assisted atom probe tomography (APT) was utilized to study the phase separation in epitaxial Cr0.61Mo0.39, Cr0.77Mo0.23, and Cr0.32V0.68 alloy thin films grown by MBE on MgO(001) single crystal substrates. Statistical analysis, namely frequency distribution analysis and Pearson coefficient analysis of experimental data was compared with similar analyses conducted on simulated APT datasets with known extent of phase separation. Thus the presence of phase separation in Cr-Mo films, even when phase separation was not clearly observed by x-ray diffraction, and the absence of phase separation in the Cr-V film were thus confirmed.

  19. The effect of sulfur, magnesium, and various rates of potassium on forage production in some sandy soils of East Texas

    E-Print Network [OSTI]

    Landua, Dennis Paul

    1969-01-01T23:59:59.000Z

    in most of these soils. In a field experiment on Lakeland sand, ryegrass responded to applications of sulfur, but not to potassium or maqnesium, Soil profile analyses indicate that appli- cations of potassium caused magnesium to be displaced downward... the exchangeable potassium and magnesium in a Lakeland fine sand 4 Distribution of potassium, magnesium, and sulfate in a Lakeland fine sand. 48 Effect of fertilizer treatments on total yield of Coastal bermudagrass grown in the field in 1968. . 51 10 Effect...

  20. Intense femtosecond photoexcitation of bulk and monolayer MoS{sub 2}

    SciTech Connect (OSTI)

    Paradisanos, I.; Fotakis, C. [Institute of Electronic Structure and Laser (IESL), Foundation for Research and Technology-Hellas (FORTH), Heraklion 71003 (Greece); Physics Department, University of Crete, Heraklion 71003 (Greece); Kymakis, E. [Center of Materials Technology and Photonics and Electrical Engineering Department, Technological Educational Institute (TEI) of Crete, Heraklion 71003 (Greece); Kioseoglou, G. [Materials Science and Technology Department, University of Crete, Heraklion 71003 (Greece); Stratakis, E., E-mail: stratak@iesl.forth.gr [Institute of Electronic Structure and Laser (IESL), Foundation for Research and Technology-Hellas (FORTH), Heraklion 71003 (Greece); Materials Science and Technology Department, University of Crete, Heraklion 71003 (Greece)

    2014-07-28T23:59:59.000Z

    The effect of femtosecond laser irradiation on bulk and single-layer MoS{sub 2} on silicon oxide is studied. Optical, field emission scanning electron microscopy and Raman microscopy were used to quantify the damage. The intensity of A{sub 1g} and E{sub 2g}{sup 1} vibrational modes was recorded as a function of the number of irradiation pulses. The observed behavior was attributed to laser-induced bond breaking and subsequent atoms removal due to electronic excitations. The single-pulse optical damage threshold was determined for the monolayer and bulk under 800?nm and 1030?nm pulsed laser irradiation, and the role of two-photon versus one photon absorption effects is discussed.

  1. Final Report: Catalytic Hydrocarbon Reactions over Supported Metal Oxides, August 1, 1995 - July 31, 1999

    SciTech Connect (OSTI)

    Ekerdt, John G.

    1999-07-31T23:59:59.000Z

    The research program focused on the catalysis of hydrodesulfurization (HDS) over molybdenum-based catalysts and how catalyst composition, redox ability, structure and neighboring sites control the catalytic properties of metal oxides. We sought to understand the catalytic features/sites that control hydrogenation, hydrogenolysis, and isomerization during HDS. Unprompted silica-supported molybdenum oxides and molybdenum sulfides were studied. Model catalyst systems were prepared from organometallic precursors or cluster compounds to generate supported structures that feature Mo(II) and Mo(IV) cations that are isolated or in ensembles and that have either Mo-O or Mo-S bonds. Conventional MOS{sub 2} catalysts, which contain both edge and rim sites, were be studied. Finally, single-layer MOS{sub 2} structures were also prepared from 2H-MoS{sub 2} powder so that the model systems could be compared against a disulfide catalyst that only involves rim sites. Catalytic reactions for thiophene and tetrahydrothione were studied over the various catalysts. Oxidation states were determined using X-ray photoelectron spectroscopy. X-ray crystallography was used to characterize and follow changes in the MOS{sub 2} structures. The program on metal oxides prepared supported oxides that have a specific structure and oxidation state to serve as model templates for the more complex commercial catalysts and then employed these structures in reaction studies. This focus area examined the relationships between structure and cation redox characteristics in oxidation catalysis. Infrared and Raman spectroscopy were used to characterize the cations and reaction intermediates.

  2. MoSe2 thin films synthesized by solid state reactions between Mo and Se J. Pouzet (1) and J. C. Bernede (2)

    E-Print Network [OSTI]

    Boyer, Edmond

    807 MoSe2 thin films synthesized by solid state reactions between Mo and Se thin films J. Pouzet (1 reaction, induced by annealing, between the Mo and Se constituents in thin films form. The films have been thin films annealed under selenium pressure at only 770 K are well crystallized. The electrical

  3. Fabrication of solid oxide fuel cell by electrochemical vapor deposition

    DOE Patents [OSTI]

    Brian, Riley (Willimantic, CT); Szreders, Bernard E. (Oakdale, CT)

    1989-01-01T23:59:59.000Z

    In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (approximately 1100.degree.-1300.degree. C.) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20-50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

  4. Fabrication of solid oxide fuel cell by electrochemical vapor deposition

    DOE Patents [OSTI]

    Riley, B.; Szreders, B.E.

    1988-04-26T23:59:59.000Z

    In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (/approximately/1100/degree/ /minus/ 1300/degree/C) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20--50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

  5. Coated U(Mo) Fuel: As-Fabricated Microstructures

    SciTech Connect (OSTI)

    Emmanuel Perez; Dennis D. Keiser, Jr.; Ann Leenaers; Sven Van den Berghe; Tom Wiencek

    2014-04-01T23:59:59.000Z

    As part of the development of low-enriched uranium fuels, fuel plates have recently been tested in the BR-2 reactor as part of the SELENIUM experiment. These fuel plates contained fuel particles with either Si or ZrN thin film coating (up to 1 µm thickness) around the U-7Mo fuel particles. In order to best understand irradiation performance, it is important to determine the starting microstructure that can be observed in as-fabricated fuel plates. To this end, detailed microstructural characterization was performed on ZrN and Si-coated U-7Mo powder in samples taken from AA6061-clad fuel plates fabricated at 500°C. Of interest was the condition of the thin film coatings after fabrication at a relatively high temperature. Both scanning electron microscopy and transmission electron microscopy were employed. The ZrN thin film coating was observed to consist of columns comprised of very fine ZrN grains. Relatively large amounts of porosity could be found in some areas of the thin film, along with an enrichment of oxygen around each of the the ZrN columns. In the case of the pure Si thin film coating sample, a (U,Mo,Al,Si) interaction layer was observed around the U-7Mo particles. Apparently, the Si reacted with the U-7Mo and Al matrix during fuel plate fabrication at 500°C to form this layer. The microstructure of the formed layer is very similar to those that form in U-7Mo versus Al-Si alloy diffusion couples annealed at higher temperatures and as-fabricated U-7Mo dispersion fuel plates with Al-Si alloy matrix fabricated at 500°C.

  6. Ab Initio Thermodynamic Model for Magnesium Carbonates and Hydrates

    SciTech Connect (OSTI)

    Chaka, Anne M.; Felmy, Andrew R.

    2014-03-28T23:59:59.000Z

    An ab initio thermodynamic framework for predicting properties of hydrated magnesium carbonate minerals has been developed using density-functional theory linked to macroscopic thermodynamics through the experimental chemical potentials for MgO, water, and CO2. Including semiempirical dispersion via the Grimme method and small corrections to the generalized gradient approximation of Perdew, Burke, and Ernzerhof for the heat of formation yields a model with quantitative agreement for the benchmark minerals brucite, magnesite, nesquehonite, and hydromagnesite. The model shows how small differences in experimental conditions determine whether nesquehonite, hydromagnesite, or magnesite is the result of laboratory synthesis from carbonation of brucite, and what transformations are expected to occur on geological time scales. Because of the reliance on parameter-free first principles methods, the model is reliably extensible to experimental conditions not readily accessible to experiment and to any mineral composition for which the structure is known or can be hypothesized, including structures containing defects, substitutions, or transitional structures during solid state transformations induced by temperature changes or processes such as water, CO2, or O2 diffusion. Demonstrated applications of the ab initio thermodynamic framework include an independent means to evaluate differences in thermodynamic data for lansfordite, predicting the properties of Mg analogs of Ca-based hydrated carbonates monohydrocalcite and ikaite which have not been observed in nature, and an estimation of the thermodynamics of barringtonite from the stoichiometry and a single experimental observation.

  7. Aerosol chemical vapor deposition of metal oxide films

    DOE Patents [OSTI]

    Ott, Kevin C. (4745 Trinity Dr., Los Alamos, NM 87544); Kodas, Toivo T. (5200 Noreen Dr. NE., Albuquerque, NM 87111)

    1994-01-01T23:59:59.000Z

    A process of preparing a film of a multicomponent metal oxide including: forming an aerosol from a solution comprised of a suitable solvent and at least two precursor compounds capable of volatilizing at temperatures lower than the decomposition temperature of said precursor compounds; passing said aerosol in combination with a suitable oxygen-containing carrier gas into a heated zone, said heated zone having a temperature sufficient to evaporate the solvent and volatilize said precursor compounds; and passing said volatilized precursor compounds against the surface of a substrate, said substrate having a sufficient temperature to decompose said volatilized precursor compounds whereby metal atoms contained within said volatilized precursor compounds are deposited as a metal oxide film upon the substrate is disclosed. In addition, a coated article comprising a multicomponent metal oxide film conforming to the surface of a substrate selected from the group consisting of silicon, magnesium oxide, yttrium-stabilized zirconium oxide, sapphire, or lanthanum gallate, said multicomponent metal oxide film characterized as having a substantially uniform thickness upon said FIELD OF THE INVENTION The present invention relates to the field of film coating deposition techniques, and more particularly to the deposition of multicomponent metal oxide films by aerosol chemical vapor deposition. This invention is the result of a contract with the Department of Energy (Contract No. W-7405-ENG-36).

  8. The viability of aluminum Zintl anion moieties within magnesium-aluminum clusters

    SciTech Connect (OSTI)

    Wang, Haopeng; Jae Ko, Yeon; Zhang, Xinxing; Gantefoer, Gerd; Bowen, Kit H., E-mail: kiran@mcneese.edu, E-mail: akandalam@wcupa.edu, E-mail: kbowen@jhu.edu [Department of Chemistry, Johns Hopkins University, Baltimore, Maryland 21218 (United States); Schnoeckel, Hansgeorg [Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, 76128 Karlsruhe (Germany)] [Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, 76128 Karlsruhe (Germany); Eichhorn, Bryan W. [Department of Chemistry, University of Maryland, College Park, Maryland 20742 (United States)] [Department of Chemistry, University of Maryland, College Park, Maryland 20742 (United States); Jena, Puru [Department of Physics, Virginia Commonwealth University, Richmond, Virginia 23284 (United States)] [Department of Physics, Virginia Commonwealth University, Richmond, Virginia 23284 (United States); Kiran, Boggavarapu, E-mail: kiran@mcneese.edu, E-mail: akandalam@wcupa.edu, E-mail: kbowen@jhu.edu [Department of Chemistry, McNeese State University, Lake Charles, Louisiana 70609 (United States)] [Department of Chemistry, McNeese State University, Lake Charles, Louisiana 70609 (United States); Kandalam, Anil K., E-mail: kiran@mcneese.edu, E-mail: akandalam@wcupa.edu, E-mail: kbowen@jhu.edu [Department of Physics, West Chester University, West Chester, Pennsylvania 19383 (United States)

    2014-03-28T23:59:59.000Z

    Through a synergetic combination of anion photoelectron spectroscopy and density functional theory based calculations, we have investigated the extent to which the aluminum moieties within selected magnesium-aluminum clusters are Zintl anions. Magnesium-aluminum cluster anions were generated in a pulsed arc discharge source. After mass selection, photoelectron spectra of Mg{sub m}Al{sub n}{sup ?} (m, n = 1,6; 2,5; 2,12; and 3,11) were measured by a magnetic bottle, electron energy analyzer. Calculations on these four stoichiometries provided geometric structures and full charge analyses for the cluster anions and their neutral cluster counterparts, as well as photodetachment transition energies (stick spectra). Calculations revealed that, unlike the cases of recently reported sodium-aluminum clusters, the formation of aluminum Zintl anion moieties within magnesium-aluminum clusters was limited in most cases by weak charge transfer between the magnesium atoms and their aluminum cluster moieties. Only in cases of high magnesium content, e.g., in Mg{sub 3}Al{sub 11} and Mg{sub 2}Al{sub 12}{sup ?}, did the aluminum moieties exhibit Zintl anion-like characteristics.

  9. Influence of recycled fine aggregates on the resistance of mortars to magnesium sulfate attack

    SciTech Connect (OSTI)

    Lee, Seung-Tae [Department of Civil Engineering, Kunsan National University, 68 Miryong-dong, Kunsan, Jeonbuk 573-701 (Korea, Republic of)], E-mail: stlee@kunsan.ac.kr

    2009-08-15T23:59:59.000Z

    The influence of recycled fine aggregates, which had been reclaimed from field-demolished concretes, on the resistance of mortar specimens to magnesium sulfate attack was investigated. Mortar specimens were prepared with recycled fine aggregates at different replacement levels (0%, 25%, 50%, 75% and 100% of natural fine aggregate by mass). The mortar specimens were exposed to 4.24% magnesium sulfate solution for about 1 year at ambient temperature, and regularly monitored for visual appearance, compressive strength loss and expansion. Additionally, in order to identify products of magnesium sulfate attack, mortar samples incorporating 0%, 25% and 100% replacement levels of the recycled fine aggregates were examined by X-ray diffraction (XRD) technique. Experimental results confirmed that the use of recycled fine aggregates up to a maximum 50% replacement level is effective under severe magnesium sulfate environment, irrespective of type of recycled fine aggregates. However, the worse performance was observed in mortar specimens incorporating 100% replacement level. It was found that the water absorption of recycled fine aggregates affected deterioration of mortar specimens, especially at a higher replacement level. XRD results indicated that the main cause of deterioration of the mortar specimens was primarily due to the formation of gypsum and thaumasite by magnesium sulfate attack. In addition, it appeared that the conversion of C-S-H into M-S-H by the attack probably influenced mechanical deterioration of mortar specimens with recycled fine aggregates.

  10. Analysis of the flow imbalance on the profile shape during the extrusion of thin magnesium sheets

    SciTech Connect (OSTI)

    Gall, Sven [Forschungszentrum Strangpressen, Technische Universität Berlin, Gustav-Meyer-Allee 25, Berlin, 13355, Germany, and Metallische Werkstoffe, Technische Universität Berlin, Ernst-Reuter-Platz 1, Berlin, 10587 (Germany); Müller, Sören [Forschungszentrum Strangpressen, Technische Universität Berlin, Gustav-Meyer-Allee 25, Berlin, 13355 (Germany); Reimers, Walter [Metallische Werkstoffe, Technische Universität Berlin, Ernst-Reuter-Platz 1, Berlin, 10587 (Germany)

    2013-12-16T23:59:59.000Z

    The extrusion process facilitates the production of magnesium sheets featuring a very thin thickness as well as excellent surface properties by using a single process step only. However, the extrusion of the magnesium sheets applying not optimized process parameters, e.g. low billet temperature or/ and poorly deformable magnesium alloy, produce pronounced buckling and waving of the extruded sheets as well as a variation of accuracy in profile shape along the cross section. The present investigation focuses on the FEM-simulation of the extrusion of magnesium sheets in order to clarify the origin of the mentioned effects. The simulations identify the flow imbalance during extrusion as the main critical factor. Due to the flow imbalance after passing the die a large compression stress zone is formed causing the buckling and waving of the thin sheets. Furthermore, the simulations of the magnesium sheet extrusion reveal that the interaction of the material flow gradients along the width and along the thickness direction near the die orifice lead to the variation of the accuracy in profile shape.

  11. Multiphonon resonant Raman scattering in MoS{sub 2}

    SciTech Connect (OSTI)

    Go?asa, K., E-mail: Katarzyna.Golasa@fuw.edu.pl; Grzeszczyk, M.; Wysmo?ek, A.; Babi?ski, A. [Faculty of Physics, University of Warsaw, ul. Ho?a 69, 00-681 Warszawa (Poland); Leszczy?ski, P.; Faugeras, C.; Nicolet, A. A. L.; Potemski, M. [Laboratoire National des Champs Magnétiques Intenses, CNRS-UJF-UPS-INSA, 25, avenue des Martyrs, 38042 Grenoble (France)

    2014-03-03T23:59:59.000Z

    Optical emission spectrum of a resonantly (??=?632.8?nm) excited molybdenum disulfide (MoS{sub 2}) is studied at liquid helium temperature. More than 20 peaks in the energy range spanning up to 1400?cm{sup ?1} from the laser line, which are related to multiphonon resonant Raman scattering processes, are observed. The attribution of the observed lines involving basic lattice vibrational modes of MoS{sub 2} and both the longitudinal (LA(M)) and the transverse (TA(M) and/or ZA(M)) acoustic phonons from the vicinity of the high-symmetry M point of the MoS{sub 2} Brillouin zone is proposed.

  12. Formation and distribution of neutral vanadium, niobium, and tantalum oxide clusters: Single photon ionization at 26.5 eV

    E-Print Network [OSTI]

    Rocca, Jorge J.

    Formation and distribution of neutral vanadium, niobium, and tantalum oxide clusters: Single photon 2006; accepted 7 September 2006; published online 25 October 2006 Neutral vanadium, niobium neutral clusters of vanadium, niobium, and tantalum oxides are of the general form MO2 0,1 M2O5 y. M2O5

  13. Identification of phases in the interaction layer between U-Mo-Zr/Al and U-Mo-Zr/Al-Si

    SciTech Connect (OSTI)

    Varela, C.L. Komar; Arico, S.F.; Mirandou, M.; Balart, S.N. [Departamento Materiales, GIDAT, GAEN, CNEA, Avda. Gral Paz 1499, B1650KNA, San Martin (Argentina); Gribaudo, L.M. [Departamento Materiales, GIDAT, GAEN, CNEA, Avda. Gral Paz 1499, B1650KNA, San Martin (Argentina); CONICET, Avda. Rivadavia 1917, C1033AAJ, Buenos Aires (Argentina)

    2008-07-15T23:59:59.000Z

    Out-of-pile diffusion experiments were performed between U-7wt.% Mo-1wt.% Zr and Al or Al A356 (7,1wt.% Si) at 550 deg. C. In this work morphological characterization and phase identification on both interaction layer are presented. They were carried out by the use of different techniques: optical and scanning electron microscopy, X-Ray diffraction and WDS microanalysis. In the interaction layer U-7wt.% Mo-1wt.% Zr/Al, the phases UAl{sub 3}, UAl{sub 4}, Al{sub 20}Mo{sub 2}U and Al{sub 43}Mo{sub 4}U{sub 6} were identified. In the interaction layer U-7wt.% Mo-1wt.% Zr/Al A356, the phases U(Al, Si) with 25at.% Si and Si{sub 5}U{sub 3} were identified. This last phase, with a higher Si concentration, was identified with XRD Synchrotron radiation performed at the National Synchrotron Light Laboratory (LNLS), Campinas, Brasil. (author)

  14. Hydrotreatment of Athabasca bitumen derived gas oil over Ni-Mo, Ni-W, and Co-Mo catalysts

    SciTech Connect (OSTI)

    Diaz-Real, R.A.; Mann, R.S.; Sambi, I.S. (Univ. of Ottawa, Ontario (Canada). Dept. of Chemical Engineering)

    1993-07-01T23:59:59.000Z

    The hydrotreatment of Athabasca bitumen derived heavy gas oil containing 4.08% S and 0.49% N was carried out in a trickle bed reactor over Ni-W, Ni-Mo, and Co-Mo catalysts supported on zeolite-alumina-silica at 623-698 K, LHSV of 1-4, gas flow rate 890 m[sup 3][sub H2]/m[sup 3][sub oil] (5,000 sef/bbl), and pressure of 6.89 MPa. Analyses for viscosity, density, aniline point, ASTM mid boiling point distillation, C/H ratio, and percentage of N and S in the final product were carried out to characterize the product oil. The amounts of N and S removed indicated the hydrodenitrogenation and hydrodesulfurization activity of the catalysts. Results of zeolite-alumina-silica-supported catalysts are compared to those obtained with commercially available Ni-Mo, Ni-W, and Co-Mo on [gamma]-alumina. Ni-Mo supported on zeolite-alumina-silica was most active and could remove as much as 99 % S and 89% N present in the oil at 698 K. The data for HDN and HDS fitted the pseudo first order model. The kinetic model is described in detail.

  15. MAGNESIUM ISOTOPE RATIOS IN {omega} CENTAURI RED GIANTS

    SciTech Connect (OSTI)

    Da Costa, G. S.; Norris, John E.; Yong, David [Research School of Astronomy and Astrophysics, Australian National University, Canberra, ACT 0200 (Australia)

    2013-05-20T23:59:59.000Z

    We have used the high-resolution observations obtained at the Anglo-Australian Telescope with Ultra-High Resolution Facility (R {approx} 100,000) and at Gemini-S with b-HROS (R {approx} 150,000) to determine magnesium isotope ratios for seven {omega} Cen red giants that cover a range in iron abundance from [Fe/H] = -1.78 to -0.78 dex, and for two red giants in M4 (NGC 6121). The {omega} Cen stars sample both the ''primordial'' (i.e., O-rich, Na- and Al-poor) and the ''extreme'' (O-depleted, Na- and Al-rich) populations in the cluster. The primordial population stars in both {omega} Cen and M4 show ({sup 25}Mg, {sup 26}Mg)/{sup 24}Mg isotopic ratios that are consistent with those found for the primordial population in other globular clusters with similar [Fe/H] values. The isotopic ratios for the {omega} Cen extreme stars are also consistent with those for extreme population stars in other clusters. The results for the extreme population stars studied indicate that the {sup 26}Mg/{sup 24}Mg ratio is highest at intermediate metallicities ([Fe/H] < -1.4 dex), and for the highest [Al/Fe] values. Further, the relative abundance of {sup 26}Mg in the extreme population stars is notably higher than that of {sup 25}Mg, in contrast to model predictions. The {sup 25}Mg/{sup 24}Mg isotopic ratio in fact does not show any obvious dependence on either [Fe/H] or [Al/Fe] nor, intriguingly, any obvious difference between the primordial and extreme population stars.

  16. Structural studies of magnesium nitride fluorides by powder neutron diffraction

    SciTech Connect (OSTI)

    Brogan, Michael A. [School of Chemistry, University of Nottingham, Nottingham NG7 2RD (United Kingdom); Hughes, Robert W. [WestCHEM, School of Chemistry, University of Glasgow, Glasgow G12 8QQ (United Kingdom); Smith, Ronald I. [ISIS Pulsed Neutron and Muon Source, Science and Technology Facilities Council, Rutherford Appleton Laboratory, Harwell Oxford, Didcot OX11 0QX (United Kingdom); Gregory, Duncan H., E-mail: Duncan.Gregory@glasgow.ac.uk [WestCHEM, School of Chemistry, University of Glasgow, Glasgow G12 8QQ (United Kingdom)

    2012-01-15T23:59:59.000Z

    Samples of ternary nitride fluorides, Mg{sub 3}NF{sub 3} and Mg{sub 2}NF have been prepared by solid state reaction of Mg{sub 3}N{sub 2} and MgF{sub 2} at 1323-1423 K and investigated by powder X-ray and powder neutron diffraction techniques. Mg{sub 3}NF{sub 3} is cubic (space group: Pm3m) and has a structure related to rock-salt MgO, but with one cation site vacant. Mg{sub 2}NF is tetragonal (space group: I4{sub 1}/amd) and has an anti-LiFeO{sub 2} related structure. Both compounds are essentially ionic and form structures in which nitride and fluoride anions are crystallographically ordered. The nitride fluorides show temperature independent paramagnetic behaviour between 5 and 300 K. - Graphical abstract: Definitive structures of the ternary magnesium nitride fluorides Mg{sub 3}NF{sub 3} and the lower temperature polymorph of Mg{sub 2}NF have been determined from powder neutron diffraction data. The nitride halides are essentially ionic and exhibit weak temperature independent paramagnetic behaviour. Highlights: Black-Right-Pointing-Pointer Definitive structures of Mg{sub 3}NF{sub 3} and Mg{sub 2}NF were determined by neutron diffraction. Black-Right-Pointing-Pointer Nitride and fluoride anions are crystallographically ordered in both structures. Black-Right-Pointing-Pointer Both compounds exhibit weak, temperature independent paramagnetic behaviour. Black-Right-Pointing-Pointer The compounds are essentially ionic with ionicity increasing with F{sup -} content.

  17. Lightning arrestor connector lead magnesium niobate qualification pellet test procedures.

    SciTech Connect (OSTI)

    Tuohig, W. (Honeywell FM& T, Kansas City, MO); Mahoney, Patrick A.; Tuttle, Bruce Andrew; Wheeler, Jill Susanne

    2009-02-01T23:59:59.000Z

    Enhanced knowledge preservation for DOE DP technical component activities has recently received much attention. As part of this recent knowledge preservation effort, improved documentation of the sample preparation and electrical testing procedures for lead magnesium niobate--lead titanate (PMN/PT) qualification pellets was completed. The qualification pellets are fabricated from the same parent powders used to produce PMN/PT lightning arrestor connector (LAC) granules at HWF&T. In our report, the procedures for fired pellet surface preparation, electrode deposition, electrical testing and data recording are described. The dielectric measurements described in our report are an information only test. Technical reasons for selecting the electrode material, electrode size and geometry are presented. The electrical testing is based on measuring the dielectric constant and dissipation factor of the pellet during cooling from 280 C to 220 C. The most important data are the temperature for which the peak dielectric constant occurs (Curie Point temperature) and the peak dielectric constant magnitude. We determined that the peak dielectric constant for our procedure would be that measured at 1 kHz at the Curie Point. Both the peak dielectric constant and the Curie point parameters provide semi-quantitative information concerning the chemical and microstructural homogeneity of the parent material used for the production of PMN/PT granules for LACs. Finally, we have proposed flag limits for the dielectric data for the pellets. Specifically, if the temperature of the peak dielectric constant falls outside the range of 250 C {+-} 30 C we propose that a flag limit be imposed that will initiate communication between production agency and design agency personnel. If the peak dielectric constant measured falls outside the range 25,000 {+-} 10,000 we also propose that a flag limit be imposed.

  18. Comparison of Crevice Corrosion of Fe-Based Amorphous Metal and Crystalline Ni-Cr-Mo Alloy

    SciTech Connect (OSTI)

    Shan, X; Ha, H; Payer, J H

    2008-07-24T23:59:59.000Z

    The crevice corrosion behaviors of an Fe-based bulk metallic glass alloy (SAM1651) and a Ni-Cr-Mo crystalline alloy (C-22) were studied in 4M NaCl at 100 C with cyclic potentiodynamic polarization and constant potential tests. The corrosion damage morphologies, corrosion products and the compositions of corroded surfaces of these two alloys were studied with optical 3D reconstruction, Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS) and Auger Electron Spectroscopy (AES). It was found that the Fe-based bulk metallic glass (amorphous alloy) SAM1651 had a more positive breakdown potential and repassivation potential than crystalline alloy C-22 in cyclic potentiodynamic polarization tests and required a more positive oxidizing potential to initiate crevice corrosion in constant potential test. Once crevice corrosion initiated, the corrosion propagation of C-22 was more localized near the crevice border compared to SAM1651, and SAM1651 repassivated more readily than C-22. The EDS results indicated that the corrosion products of both alloys contained high amount of O and were enriched in Mo and Cr. The AES results indicated that a Cr-rich oxide passive film was formed on the surfaces of both alloys, and both alloys were corroded congruently.

  19. Studies on the inuence of chloride ion and pH on the corrosion and electrochemical behaviour of AZ91D magnesium alloy

    E-Print Network [OSTI]

    Zhou, Wei

    alloys weigh $35% lower than their aluminium counterparts at equal stiness [1]. In addition, these alloys of cast AZ91 magnesium alloy. In AZ91, magnesium and the principal alloying element aluminium, have91D magnesium alloy R. AMBAT, N.N. AUNG and W. ZHOU School of Mechanical and Production Engineering

  20. An Investigation into the Oxidation State of Molybdenum in Simplified High Level Nuclear Waste Glass Compositions

    E-Print Network [OSTI]

    Sheffield, University of

    An Investigation into the Oxidation State of Molybdenum in Simplified High Level Nuclear Waste of Mo in glasses containing simplified simulated high level nuclear waste (HLW) streams has been originating from the reprocessing of spent nuclear fuel. Experiments using simulated nuclear waste streams

  1. DOI: 10.1002/chem.200700579 Selective Catalytic Oxidation of Ethanol to Acetic Acid on Dispersed

    E-Print Network [OSTI]

    Iglesia, Enrique

    % ethanol conversion) were much higher than in previous re- ports. The presence of TiO2 during syn- thesisDOI: 10.1002/chem.200700579 Selective Catalytic Oxidation of Ethanol to Acetic Acid on Dispersed Mo, easily separated from organic reactants and products, and gas-phase process- es that avoid solid

  2. Hybrid Energy Cell for Degradation of Methyl Orange by Self-Powered Electrocatalytic Oxidation

    E-Print Network [OSTI]

    Wang, Zhong L.

    Hybrid Energy Cell for Degradation of Methyl Orange by Self- Powered Electrocatalytic Oxidation Ya of superoxidative hydroxyl radical on the anode. Here, we report a hybrid energy cell that is used for a self-powered electrocatalytic process for the degradation of MO without using an external power source. The hybrid energy cell

  3. Oxidation catalyst

    DOE Patents [OSTI]

    Ceyer, Sylvia T. (Cambridge, MA); Lahr, David L. (Cambridge, MA)

    2010-11-09T23:59:59.000Z

    The present invention generally relates to catalyst systems and methods for oxidation of carbon monoxide. The invention involves catalyst compositions which may be advantageously altered by, for example, modification of the catalyst surface to enhance catalyst performance. Catalyst systems of the present invention may be capable of performing the oxidation of carbon monoxide at relatively lower temperatures (e.g., 200 K and below) and at relatively higher reaction rates than known catalysts. Additionally, catalyst systems disclosed herein may be substantially lower in cost than current commercial catalysts. Such catalyst systems may be useful in, for example, catalytic converters, fuel cells, sensors, and the like.

  4. Structure And Radiation Damage Behavior Of Epitaxial CrxMo1-x...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    And Radiation Damage Behavior Of Epitaxial CrxMo1-x Alloy Thin Films On MgO. Structure And Radiation Damage Behavior Of Epitaxial CrxMo1-x Alloy Thin Films On MgO. Abstract:...

  5. Adsorption of Potassium on the MoS2(100) Surface: A First-Principles...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Potassium on the MoS2(100) Surface: A First-Principles Investigation. Adsorption of Potassium on the MoS2(100) Surface: A First-Principles Investigation. Abstract: Periodic density...

  6. High Capacity MoO3 Nanoparticle Li-Ion Battery Anode

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    energy functional were employed.) 10 AccomplishmentStatus Theoretical changes in Li-ion intercalated -MoO 3 Mo Li O * Four Li inserted in a theoretical nanoparticle. * 9 ps...

  7. Domestic production of medical isotope Mo-99 moves a step closer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Domestic production of medical isotope Mo-99 Domestic production of medical isotope Mo-99 moves a step closer Irradiated uranium fuel has been recycled and reused for molybdenum-99...

  8. Corrosion report for the U-Mo fuel concept

    SciTech Connect (OSTI)

    Henager, Jr., Charles H. [Pacific Northwest National Laboratory (PNNL), Richland, WA (US); Bennett, Wendy D. [Pacific Northwest National Laboratory (PNNL), Richland, WA (US); Doherty, Ann L. [Pacific Northwest National Laboratory (PNNL), Richland, WA (US); Fuller, E. S. [Pacific Northwest National Laboratory (PNNL), Richland, WA (US); Hardy, John S. [Pacific Northwest National Laboratory (PNNL), Richland, WA (US); Omberg, Ronald P. [Pacific Northwest National Laboratory (PNNL), Richland, WA (US)

    2014-08-28T23:59:59.000Z

    The Fuel Cycle Research and Development (FCRD) program of the Office of Nuclear Energy (NE) has implemented a program to develop a Uranium-Molybdenum (U-Mo) metal fuel for Light Water Reactors (LWR)s. Uranium-Molybdenum fuel has the potential to provide superior performance based on its thermo-physical properties, which includes high thermal conductivity for less stored heat energy. With sufficient development, it may be able to provide the Light Water industry with a melt-resistant accident tolerant fuel with improved safety response. However, the corrosion of this fuel in reactor water environments needs to be further explored and optimized by additional alloying. The Pacific Northwest National Laboratory has been tasked with performing ex-reactor corrosion testing to characterize the performance of U-Mo fuel. This report documents the results of the effort to characterize and develop the U-Mo metal fuel concept for LWRs with regard to corrosion testing. The results of a simple screening test in buffered water at 30°C using surface alloyed U-10Mo is documented and discussed. The screening test was used to guide the selection of several potential alloy improvements that were found and are recommended for further testing in autoclaves to simulate PWR water conditions more closely.

  9. MO"BIUS-INVARIANT KNOT ENERGIES R.B. KUSNER

    E-Print Network [OSTI]

    Sullivan, John M.

    for divergence-free vector fields which arise in modeling incompressible fluid flow.6,7These new knot energies MO"BIUS-INVARIANT KNOT ENERGIES R.B. KUSNER, Urbana, IL, USA 61801-2975 There has been recent interest in knot energies among mathematicians

  10. MO"BIUS-INVARIANT KNOT ENERGIES R.B. KUSNER

    E-Print Network [OSTI]

    for divergence-free vector fields which arise in modeling incompressible fluid flow.? These new knot energies may MO"BIUS-INVARIANT KNOT ENERGIES R.B. KUSNER, Urbana, IL, USA 61801-2975 There has been recent interest in knot energies among mathematicians

  11. Aerosol chemical vapor deposition of metal oxide films

    DOE Patents [OSTI]

    Ott, K.C.; Kodas, T.T.

    1994-01-11T23:59:59.000Z

    A process of preparing a film of a multicomponent metal oxide including: forming an aerosol from a solution comprised of a suitable solvent and at least two precursor compounds capable of volatilizing at temperatures lower than the decomposition temperature of said precursor compounds; passing said aerosol in combination with a suitable oxygen-containing carrier gas into a heated zone, said heated zone having a temperature sufficient to evaporate the solvent and volatilize said precursor compounds; and passing said volatilized precursor compounds against the surface of a substrate, said substrate having a sufficient temperature to decompose said volatilized precursor compounds whereby metal atoms contained within said volatilized precursor compounds are deposited as a metal oxide film upon the substrate is disclosed. In addition, a coated article comprising a multicomponent metal oxide film conforming to the surface of a substrate selected from the group consisting of silicon, magnesium oxide, yttrium-stabilized zirconium oxide, sapphire, or lanthanum gallate, said multicomponent metal oxide film characterized as having a substantially uniform thickness upon said substrate.

  12. Magnesium transport extraction of transuranium elements from LWR fuel

    DOE Patents [OSTI]

    Ackerman, John P. (Downers Grove, IL); Battles, James E. (Oak Forest, IL); Johnson, Terry R. (Wheaton, IL); Miller, William E. (Naperville, IL); Pierce, R. Dean (Naperville, IL)

    1992-01-01T23:59:59.000Z

    A process of separating transuranium actinide values from uranium values present in spent nuclear oxide fuels which contain rare earth and noble metal fission products. The oxide fuel is reduced with Ca metal in the presence of CaCl.sub.2 and a U-Fe alloy containing not less than about 84% by weight uranium at a temperature in the range of from about 800.degree. C. to about 850.degree. C. to produce additional uranium metal which dissolves in the U-Fe alloy raising the uranium concentration and having transuranium actinide metals and rare earth fission product metals and the noble metal fission products dissolved therein. The CaCl.sub.2 having CaO and fission products of alkali metals and the alkali earth metals and iodine dissolved therein is separated and electrolytically treated with a carbon electrode to reduce the CaO to Ca metal while converting the carbon electrode to CO and CO.sub.2. The Ca metal and CaCl.sub.2 is recycled to reduce additional oxide fuel. The U-Fe alloy having transuranium actinide metals and rare earth fission product metals and the noble metal fission products dissolved therein is contacted with Mg metal which takes up the actinide and rare earth fission product metals. The U-Fe alloy retains the noble metal fission products and is stored while the Mg is distilled and recycled leaving the transuranium actinide and rare earth fission products isolated.

  13. Narrow spectral emission CaMoO{sub 4}: Eu{sup 3+}, Dy{sup 3+}, Tb{sup 3+} phosphor crystals for white light emitting diodes

    SciTech Connect (OSTI)

    Khanna, A. [Smart Lighting Engineering Research Center, 110, 8th Street, Troy, New York, 12180 (United States) [Smart Lighting Engineering Research Center, 110, 8th Street, Troy, New York, 12180 (United States); Electrical, Computer and Systems Engineering Department, Rensselaer Polytechnic Institute, 110, 8th Street, Troy, New York, 12180 (United States); Dutta, P.S., E-mail: duttap@rpi.edu [Smart Lighting Engineering Research Center, 110, 8th Street, Troy, New York, 12180 (United States); Electrical, Computer and Systems Engineering Department, Rensselaer Polytechnic Institute, 110, 8th Street, Troy, New York, 12180 (United States)

    2013-02-15T23:59:59.000Z

    Alkaline earth metal molybdates are promising candidates as a host material for high efficiency narrow spectral emission phosphors. These phosphors could potentially be used for the fabrication of phosphor-converted light emitting diodes (pc-LEDs). Phosphor crystals of calcium molybdate doped with rare earth dopant Ln{sup 3+}(Ln=Eu, Dy, Tb) grown using flux growth method have been shown to exhibit higher excitation efficiency than the powders synthesized by solid-state reaction process. Molybdenum (VI) oxide has been found to be a suitable flux for growing large size optically transparent high quality crystals at a temperature around 1100 Degree-Sign C. Using the excitation wavelengths of 465 nm, 454 nm and 489 nm for CaMoO{sub 4}: Eu{sup 3+}, CaMoO{sub 4}: Dy{sup 3+} and CaMoO{sub 4}: Tb{sup 3+}, respectively, intense emission lines at wavelengths of 615 nm, 575 nm and 550 nm were observed. The optimized doping concentrations of 12%, 2% and 5% for Eu{sup 3+}, Dy{sup 3+} and Tb{sup 3+}, respectively, provided the highest luminescence intensity. - Graphical Abstract: CaMoO{sub 4}: Eu{sup 3+} phosphor crystals grown using a molybdenum (VI) oxide flux exhibited around 1.5 times the emission intensity of powders obtained from solid-state reaction at the same synthesis temperature. These crystals were found to efficiently emit 615 nm red light when excited by near UV light up to a wavelength of 395 nm. Highlights: Black-Right-Pointing-Pointer CaMoO{sub 4}: Ln{sup 3+} (Ln=Eu{sup 3+}, Dy{sup 3+}, Tb{sup 3+}) phosphor crystals were successfully grown using high temperature flux (solutions) containing molybdenum (VI) oxide or lithium chloride. Black-Right-Pointing-Pointer Narrow spectral emission at 615 nm, 575 nm and 550 nm, respectively, was observed from CaMoO{sub 4}: Ln{sup 3+} (Ln=Eu{sup 3+}, Dy{sup 3+}, Tb{sup 3+}) phosphor crystals. Black-Right-Pointing-Pointer The optimized doping concentrations of Eu{sup 3+}, Dy{sup 3+}, Tb{sup 3+} in CaMoO{sub 4} for highest emission intensity were determined to be 12%, 2% and 5%, respectively. Black-Right-Pointing-Pointer The CaMoO{sub 4}: Ln{sup 3+} (Ln=Eu{sup 3+}, Dy{sup 3+}, Tb{sup 3+}) phosphor crystals grown with molybdenum (VI) oxide flux exhibited 50% higher emission intensity compared to the crystals grown with lithium chloride flux and the powders synthesized by solid-state reaction.

  14. Simulation of Stresses during Casting of Binary Magnesium-Aluminum Alloys

    E-Print Network [OSTI]

    Beckermann, Christoph

    Simulation of Stresses during Casting of Binary Magnesium-Aluminum Alloys M.G. POKORNY, C.A. MONROE made for aluminum alloys.[6­8] Recently, Mathier and co-workers[9,10] performed a detailed com- parison between measured and predicted forces in the mush during solidification of dilute aluminum alloys

  15. Hot cracking in tungsten inert gas welding of magnesium alloy AZ91D

    E-Print Network [OSTI]

    Zhou, Wei

    Hot cracking in tungsten inert gas welding of magnesium alloy AZ91D W. Zhou*, T. Z. Long and C. K of the plates were produced using tungsten inert gas (TIG) welding method. The TIG arc was also used to deposit welding beads on some of the thin plates. No cracking was found in the butt joints. However, hot cracking

  16. The Effect of Rare Earth Elements, Temperature and Rolling Speed on the Microstructure Evolution of Magnesium

    E-Print Network [OSTI]

    Barthelat, Francois

    of Magnesium Jie Pan¹, supervised by Mehdi Sanjari¹ and Prof. Stephen Yue¹ ¹Department of Mining and Materials and neodymium additive samples were acquired then subsequently rolled at different temperatures (300°C and 450°C of the precipitate which led to a less pinning effect. ·The neodymium samples have longer grain growth period than

  17. Solid-State Gadolinium-Magnesium Hydride Optical Switch R. Armitage

    E-Print Network [OSTI]

    -state electrochromic device. With positive polarization of the hydride electrode, the visible reflectance approaches 35 and reflecting states. Keywords: gadolinium-magnesium; electrochromic hydride; optical switching device. 2 #12;A conventional electrochromics5 . Optical switching has also been demonstrated by varying the H content

  18. The effect of cooling rate on thermophysical properties of magnesium alloys

    E-Print Network [OSTI]

    Medraj, Mamoun

    been in widespread use in the automotive industry processed mainly by casting. In designing cast automotive compo- nents, it is important to know how these alloys solidify at different cross sections magnesium and aluminum. The samples were cut and mechanically polished to remove any possible contaminated

  19. Magnesium-rich crustal compositions on Mercury: Implications for magmatism from petrologic modeling

    E-Print Network [OSTI]

    Hauck II, Steven A.

    Magnesium-rich crustal compositions on Mercury: Implications for magmatism from petrologic modeling December 2012. [1] We have conducted petrologic modeling of MESSENGER-derived compositions and analog-rich crustal compositions on Mercury: Implications for magmatism from petrologic modeling, J. Geophys. Res

  20. Characterization and thermal behavior of PrMO{sub 3} (M = Co or Ni) ceramic materials obtained from gelatin

    SciTech Connect (OSTI)

    Aquino, F.M., E-mail: flavyma@hotmail.com [Federal University of Rio Grande of Norte, Laboratory of Catalysis and Refining – NUPRAR, Av. Senador Salgado Filho, 3000, CEP 59078-970, Natal-RN (Brazil); Melo, D.M.A. [Federal University of Rio Grande of Norte, Laboratory of Catalysis and Refining – NUPRAR, Av. Senador Salgado Filho, 3000, CEP 59078-970, Natal-RN (Brazil)] [Federal University of Rio Grande of Norte, Laboratory of Catalysis and Refining – NUPRAR, Av. Senador Salgado Filho, 3000, CEP 59078-970, Natal-RN (Brazil); Pimentel, P.M. [Universidade Federal Rural do Semi-Árido, Campus Angicos, CEP 59515-000, Angicos-RN (Brazil)] [Universidade Federal Rural do Semi-Árido, Campus Angicos, CEP 59515-000, Angicos-RN (Brazil); Braga, R.M.; Melo, M.A.F.; Martinelli, A.E.; Costa, A.F. [Federal University of Rio Grande of Norte, Laboratory of Catalysis and Refining – NUPRAR, Av. Senador Salgado Filho, 3000, CEP 59078-970, Natal-RN (Brazil)] [Federal University of Rio Grande of Norte, Laboratory of Catalysis and Refining – NUPRAR, Av. Senador Salgado Filho, 3000, CEP 59078-970, Natal-RN (Brazil)

    2012-09-15T23:59:59.000Z

    Graphical abstract: The micrograph in figure shows sample calcined at temperature 900 °C. The sample exhibits morphology with considerable porosity and the formation of agglomerated nanometric particles. Gelatin provides the system with a large amount of organic matter, which is then removed during calcinations, favoring the appearance of pores in the material. Highlights: ? Oxides with PrNiO{sub 3} and PrCoO{sub 3} were prepared by new method synthesis. ? The gelatin, through its carboxylate groups and amine, is an efficient director. ? The obtained materials have magnetic properties and application in catalysis. ? The decomposition kinetic study of bonding groups of gelatin with metallic ions that takes part in the synthesis of PrMO{sub 3}. -- Abstract: Metal oxides with perovskite-type structure have attracted considerable interest in recent years due to their magnetic and electrical properties, as well as their catalytic activity. In this study, oxides with PrNiO{sub 3} and PrCoO{sub 3} composition were prepared by using gelatin powder as a precursor agent for its use as a catalyst. The powders obtained were calcined at 700 °C and 900 °C and characterized using the X-ray diffraction, thermal analysis (thermogravimetry and differential thermal analysis), infrared spectroscopy, temperature programed reduction and scanning electron microscopy techniques. Thermogravimetric data using the non-isothermal kinetic models of Flynn and Wall and “Model-free Kinetics” were used to determine the activation energy to study the decomposition kinetics of the ligand groups with system's metallic ions that takes part in the synthesis of PrMO{sub 3} (M = Ni or Co).

  1. Surface modification of n-MoS[sub 2] electrodes with a viologen based redox polymer. Persistent attachment of a polysiloxane via a thin SnO[sub 2] adhesion layer

    SciTech Connect (OSTI)

    Huang, J.; Wrighton, M.S. (Massachusetts Inst. of Technology, Cambridge, MA (United States))

    1993-11-01T23:59:59.000Z

    A procedure for surface modification of n-MoS[sub 2] electrodes with a polymer formed hydrolysis of N,N[prime]-bis[p-(trimethoxysilyl)benzyl]-4,4[prime]-bipyr idinium, BPQ[sup 2+], is described. (BPQ[sup 2+])[sub n] is persistently confined onto the surface of n-MoS[sub 2] crystals in a sandwich structure, n-MoS[sub 2]/SnO[sub 2](BPQ[sup 2+])[sub n]. Then n-MoS[sub 2] crystal is first modified by electrochemical deposition of small islands of tin, followed by oxidation to give islands of SnO[sub 2]. The (BPQ[sup 2+])[sub n] is confined onto the resulting surface via standard procedures for this polysiloxane system: electrochemical reduction of the violgen in aqueous electrolyte. The SnO[sub 2] at the interface between n-MoS[sub 2] crystal and (BPQ[sup 2+])[sub n] functions as an adhesive layer to bind the polymer to the MoS[sub 2]. Without SnO[sub 2], the attachment of the coating of (BPQ[sup 2+])[sub n] on MoS[sub 2] is not durable. Although a coating of SnO[sub 2] shifts the flat band potential of the electrode approximately 0.1 V negatively depending on pH and (SnO[sup 2] coverage) the essential behavior of the semiconductor/elestrolyte interface is not significantly altered. 14 refs., 12 figs.

  2. The growth and characterization of LiGd?(Mo0?)? single crystals

    E-Print Network [OSTI]

    Reimund, James Allyn

    1981-01-01T23:59:59.000Z

    ' C/second 37 Pyroelectric Current vs. Temperature dT/dt = 30' C/second 180' Domains (Gd (MoO ) ) 37 39 INTRODUCTION This thesis discusses the growth and some single crystalline properties of lithium-gadolinium-molybdate of the type LiGd (Mo...O ) 3 45' This compound is one of the three thus far discovered compounds of the lithium ? gadolinium-molybdate (LGMO) system. In general, this system can be expressed as Li2Mo04. XGd2(Mo04)3, where LiGd3(MoO, )5 4 5 single crystals synthesize when X...

  3. Methanol Partial Oxidation on MoO3/SiO2 Catalysts: Application...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    is presented in this article. For the first time, this OHT reactor integrates Fourier Transformation infrared (FT-IR) imaging technique and Raman spectroscopy in operando...

  4. Effective hole extraction using MoO{sub x}-Al contact in perovskite CH{sub 3}NH{sub 3}PbI{sub 3} solar cells

    SciTech Connect (OSTI)

    Zhao, Yixin; Nardes, Alexandre M.; Zhu, Kai, E-mail: Kai.Zhu@nrel.gov [Chemical and Materials Science Center, National Renewable Energy Laboratory, Golden, Colorado 80401 (United States)

    2014-05-26T23:59:59.000Z

    We report an 11.4%-efficient perovskite CH{sub 3}NH{sub 3}PbI{sub 3} solar cell using low-cost molybdenum oxide/aluminum (i.e., MoO{sub x}/Al) as an alternative top contact to replace noble/precious metals (e.g., Au or Ag) for extracting photogenerated holes. The device performance of perovskite solar cells using a MoO{sub x}/Al top contact is comparable to that of cells using the standard Ag top contact. Analysis of impedance spectroscopy measurements suggests that using 10-nm-thick MoO{sub x} and Al does not affect charge-recombination properties of perovskite solar cells. Using a thicker (20-nm) MoO{sub x} layer leads to a lower cell performance caused mainly by a reduced fill factor. Our results suggest that MoO{sub x}/Al is promising as a low-cost and effective hole-extraction contact for perovskite solar cells.

  5. Ductility Enhancement of Molybdenum Phase by Nano-sized Oxide Dispersions

    SciTech Connect (OSTI)

    Kang, Bruce

    2008-07-18T23:59:59.000Z

    The objective of this research is to understand and to remedy the impurity effects for room-temperature ductility enhancement of molybdenum (Mo) based alloys by the inclusion of nano-sized metal oxide dispersions. This research combines theoretical, computational, and experimental efforts. The results will help to formulate systematic strategies in searching for better composed Mo-based alloys with optimal mechanical properties. For this project, majority of the research effort was directed to atomistic modeling to identify the mechanisms responsible for the oxygen embrittling and ductility enhancement based on fundamental electronic structure analysis. Through first principles molecular dynamics simulations, it was found that the embrittling impurity species were attracted to the metal oxide interface, consistent with previous experiments. Further investigation on the electronic structures reveals that the presence of embrittling species degrades the quality of the metallic chemical bonds in the hosting matrix in a number of ways, the latter providing the source of ductility. For example, the spatial flexibility of the bonds is reduced, and localization of the impurity states occurs to pin the dislocation flow. Rice’s criterion has been invoked to explain the connections of electronic structure and mechanical properties. It was also found that when impurity species become attracted to the metal oxide interface, some of the detrimental effects are alleviated, thus explaining the observed ductility enhancement effects. These understandings help to develop predictive capabilities to facilitate the design and optimization of Mo and other high temperature alloys (e.g. ODS alloys) for fossil energy materials applications. Based on the theoretical and computational studies, the experimental work includes the preparation of Mo powders mixed with candidate nano-sized metal oxides, which were then vacuum hot-pressed to make the Mo alloys. Several powder mixing methods were evaluated, however, the Mo alloys produced showed little improvement of room-temperature ductility. Finally, toward the end of the research project, a particle mixing process (Hosokawa mechano chemical bonding technology) was applied and the sample Mo alloys showed much improved room-temperature ductility. Follow-up mechanical properties evaluations on the as-processed Mo alloys were carried out using an in-house developed micro-indentation technique which is suitable for in-situ material mechanical properties measurement and ductility/brittle evaluation on small-size sample alloys. Relevant experimental results of the micro-indentation tests are presented.

  6. NEGLIGIBLE CREEP CONDITIONS FOR MOD 9 CR 1 MO STEEL

    SciTech Connect (OSTI)

    Ren, Weiju [ORNL; Riou, Bernard [AREVA Group; Escaravage, Claude [AREVA Group; Swindeman, Robert W [ORNL; Cabrillat, Marie-Th?r?se [CEA Cadarache, St. Paul lex Durance, France; Allais, Lucien [CEA, Saclay, France

    2006-01-01T23:59:59.000Z

    Mod 9 Cr 1 Mo Steel (grade 91) is one of the materials envisaged for the Reactor Pressure Vessel of Very High Temperature Reactors. To avoid the implementation of a surveillance program covering the monitoring of the creep damage throughout the whole life of the reactor, it is recommended to operate the Reactor Pressure Vessel in the negligible creep regime. In this paper, the background of negligible creep criteria available in nuclear Codes is first recalled and their limitations were analyzed. Then, guidance for deriving criteria more appropriate for mod 9 Cr 1 Mo steel is provided. Finally, R&D actions in the U. S. and France to support the new approaches are discussed and recommended.

  7. Dislocations With Edge Components in Nanocrystalline bcc Mo

    SciTech Connect (OSTI)

    G. M. Cheng; W. Z. Xu; W. W. Jian; H. Yuan; M. H. Tsai; Y. T. Zhu; Y. F. Zhang; Paul C. Millett

    2013-07-01T23:59:59.000Z

    We report high-resolution transmission electron microscopy (HRTEM) observation of a high density of dislocations with edge components (approximately 1016 m-2) in nanocrystalline (NC) body-centered cubic (bcc) Mo prepared by high-pressure torsion. We also observed for the first time of the 1/2 <111> and <001> pure edge dislocations in NC Mo. Crystallographic analysis and image simulations reveal that the best way using HRTEM to study dislocations with edge components in bcc systems is to take images along <110> zone axis, from which it is possible to identify 1/2 <111> pure edge dislocations, and edge components of 1/2 <111> and <001> mixed dislocations. The <001> pure edge dislocations can only be identified from <100> zone axis. The high density of dislocations with edge components is believed to play a major role in the reduction of strain rate sensitivity in NC bcc metals and alloys.

  8. Charge and magnetic states of Mn-, Fe-, and Co-doped monolayer MoS{sub 2}

    SciTech Connect (OSTI)

    Lin, Xianqing [State Key Laboratory of Low-Dimensional Quantum Physics, Department of Physics, Tsinghua University, Beijing 100084 (China); Collaborative Innovation Center of Quantum Matter, Beijing 100084 (China); Department of Applied Physics, Zhejiang University of Technology, Hangzhou 310023 (China); Ni, Jun, E-mail: junni@mail.tsinghua.edu.cn [State Key Laboratory of Low-Dimensional Quantum Physics, Department of Physics, Tsinghua University, Beijing 100084 (China); Collaborative Innovation Center of Quantum Matter, Beijing 100084 (China)

    2014-07-28T23:59:59.000Z

    First-principles calculations have been performed to investigate the electronic and magnetic properties of monolayer MoS{sub 2} substitutionally doped with Mn, Fe, and Co in possible charge states (q). We find that the Mn, Fe, and Co dopants substituting for a Mo atom in monolayer MoS{sub 2} (Mn@Mo, Fe@Mo, and Co@Mo) are all magnetic in their neutral and charge states except in the highest positive charge states. Mn@Mo, Fe@Mo, and Co@Mo have the same highest negative charge states of q=?2 for chemical potential of electron just below the conduction band minimum, which corresponds to the electron doping. In the q=?2 state, Mn@Mo has a much larger magnetic moment than its neutral state with the antiferromagnetic coupling between the Mn dopant and its neighboring S atoms maintained, while Fe@Mo and Co@Mo have equal or smaller magnetic moments than their neutral states. The possible charge states of Mn@Mo, Fe@Mo, and Co@Mo and the variation of the magnetic moments for different dopants and charge states are due to the change of the occupation and energy of the anti-bonding defect levels in the band gap. The rich magnetic properties of the neutral and charge states suggest possible realization of the substitutionally Mn-, Fe-, and Co-doped monolayer MoS{sub 2} as dilute magnetic semiconductors.

  9. Oxide strengthened molybdenum-rhenium alloy

    DOE Patents [OSTI]

    Bianco, Robert (Cleveland, OH); Buckman, Jr., R. William (Pittsburgh, PA)

    2000-01-01T23:59:59.000Z

    Provided is a method of making an ODS molybdenum-rhenium alloy which includes the steps of: (a) forming a slurry containing molybdenum oxide and a metal salt dispersed in an aqueous medium, the metal salt being selected from nitrates or acetates of lanthanum, cerium or thorium; (b) heating the slurry in the presence of hydrogen to form a molybdenum powder comprising molybdenum and an oxide of the metal salt; (c) mixing rhenium powder with the molybdenum powder to form a molybdenum-rhenium powder; (d) pressing the molybdenum-rhenium powder to form a molybdenum-rhenium compact; (e) sintering the molybdenum-rhenium compact in hydrogen or under a vacuum to form a molybdenum-rhenium ingot; and (f) compacting the molybdenum-rhenium ingot to reduce the cross-sectional area of the molybdenum-rhenium ingot and form a molybdenum-rhenium alloy containing said metal oxide. The present invention also provides an ODS molybdenum-rhenium alloy made by the method. A preferred Mo--Re-ODS alloy contains 7-14 weight % rhenium and 2-4 volume % lanthanum oxide.

  10. Microstructures and oxidation behavior of some Molybdenum based alloys

    SciTech Connect (OSTI)

    Ray, Pratik Kumar

    2010-12-15T23:59:59.000Z

    The advent of Ni based superalloys revolutionized the high temperature alloy industry. These materials are capable of operating in extremely harsh environments, comprising of temperatures around 1050 C, under oxidative conditions. Demands for increased fuel efficiency, however, has highlighted the need for materials that can be used under oxidative conditions at temperatures in excess of 1200 C. The Ni based superalloys are restricted to lower temperatures due to the presence of a number of low melting phases that melt in the 1250 - 1450 C, resulting in softening of the alloys above 1000 C. Therefore, recent research directions have been skewed towards exploring and developing newer alloy systems. This thesis comprises a part of such an effort. Techniques for rapid thermodynamic assessments were developed and applied to two different systems - Mo-Si alloys with transition metal substitutions (and this forms the first part of the thesis) and Ni-Al alloys with added components for providing high temperature strength and ductility. A hierarchical approach towards alloy design indicated the Mo-Ni-Al system as a prospective candidate for high temperature applications. Investigations on microstructures and oxidation behavior, under both isothermal and cyclic conditions, of these alloys constitute the second part of this thesis. It was seen that refractory metal systems show a marked microstructure dependence of oxidation.

  11. NO. REV. MO. _ ALSEP/LCRU EMC Test Results

    E-Print Network [OSTI]

    Rathbun, Julie A.

    NO. REV. MO. ATM 1050 _ ALSEP/LCRU EMC Test Results PAGE 1 OF 10 DATE 19 August 1971 The results of the ALSEP/LCRU EMC test are reported in this ATM. C~.·--~ s--·~e'Jn~,__')!).Prepared by:__~~~"f--.;;.~-------- Approved by: ~JM.MD. ithian #12;NO. RIV. NO. ATM 1050 ALSEP/LCRU EMC Test Results 2 10PAGE OF Aall

  12. IRRADIATION PERFORMANCE OF U-Mo MONOLITHIC FUEL

    SciTech Connect (OSTI)

    M.K. Meyer; J. Gan; J.-F. Jue; D.D. Keiser; E. Perez; A. Robinson; D.M. Wachs; N. Woolstenhulme; G.L. Hofman; Y.-S. Kim

    2014-04-01T23:59:59.000Z

    High-performance research reactors require fuel that operates at high specific power to high fission density, but at relatively low temperatures. Research reactor fuels are designed for efficient heat rejection, and are composed of assemblies of thin-plates clad in aluminum alloy. The development of low-enriched fuels to replace high-enriched fuels for these reactors requires a substantially increased uranium density in the fuel to offset the decrease in enrichment. Very few fuel phases have been identified that have the required combination of very-high uranium density and stable fuel behavior at high burnup. UMo alloys represent the best known tradeoff in these properties. Testing of aluminum matrix U-Mo aluminum matrix dispersion fuel revealed a pattern of breakaway swelling behavior at intermediate burnup, related to the formation of a molybdenum stabilized high aluminum intermetallic phase that forms during irradiation. In the case of monolithic fuel, this issue was addressed by eliminating, as much as possible, the interfacial area between U-Mo and aluminum. Based on scoping irradiation test data, a fuel plate system composed of solid U-10Mo fuel meat, a zirconium diffusion barrier, and Al6061 cladding was selected for development. Developmental testing of this fuel system indicates that it meets core criteria for fuel qualification, including stable and predictable swelling behavior, mechanical integrity to high burnup, and geometric stability. In addition, the fuel exhibits robust behavior during power-cooling mismatch events under irradiation at high power.

  13. An APFIM and TEM study of Ni{sub 4}Mo precipitation in a commercial Ni-28% Mo-1.4% Fe-0.4% Cr wt. % alloy

    SciTech Connect (OSTI)

    Thomson, R.C.; Brown, N.; Bates, J.S. [Loughborough Univ. (United Kingdom). Inst. of Polymer Technology and Materials Engineering; Russell, K.F.; Miller, M.K. [Oak Ridge National Lab., TN (United States). Metals and Ceramics Div.

    1998-02-01T23:59:59.000Z

    Ni-Mo alloys containing at least 26 wt.% Mo have a negligible corrosion rate in boiling 10% hydrochloric acid and are therefore used in corrosive environments. A series of commercial Ni-Mo alloys has been developed with subtle variations in chemical composition. These alloys usually contain {approximately} 28 wt.% Mo with additions of up to 5% Fe and Cr. A significant amount of research has been performed to understand the microstructure and properties of these alloys, although most of the effort has concentrated on the Ni-Mo binary system. In some alloys with low Fe and Cr contents, a severe embrittlement problem has been observed due to the formation of the Ni{sub 4}Mo (D1{sub a}-ordered) phase within the microstructure. This research focuses on a commercial alloy with nominal composition Ni-28% Mo-1.4% Fe-0.4% Cr-0.1% Mn-0.003 wt.% C. The material supplied was a heat treatment coupon which had been attached to a large vessel during fabrication. Assessment of the chemical analysis of the alloy suggested that detrimental phases could be present or might appear during subsequent repair work. Therefore, it was important to assess the microstructural condition of the vessel, and in particular the kinetics of precipitation of Ni{sub 4}Mo.

  14. Vehicle Technologies Office Merit Review 2015: Scale-Up of Magnesium Production by Fully Stabilized Zirconia Electrolysis

    Broader source: Energy.gov [DOE]

    Presentation given by INFINIUM, Inc. at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about scale-up of magnesium...

  15. An approach to modeling the cost-strength-weight tradeoff in aluminum and magnesium extrusions for automotive applications

    E-Print Network [OSTI]

    Komander, Johann Kasper

    2009-01-01T23:59:59.000Z

    In light of volatile fuel prices and tightening emissions regulations, automobile manufacturers have been increasingly considering the use of light-weight magnesium in their efforts to improve fuel economy. While mainly ...

  16. Vehicle Technologies Office Merit Review 2014: Scale-Up of Magnesium Production by Fully Stabilized Zirconia Electrolysis

    Broader source: Energy.gov [DOE]

    Presentation given by INFINIUM, Inc. at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about scale-up of magnesium...

  17. Identifying barriers to the availability and use of Magnesium Sulphate Injection in resource poor countries: A case study in Zambia

    E-Print Network [OSTI]

    Ridge, Anna L; Bero, Lisa A; Hill, Suzanne R

    2010-01-01T23:59:59.000Z

    barriers to the availability and use of Magnesium Sulphateto identify barriers to the availability and use of MgSO4 infacilitators to the availability and use of MgSO4 identified

  18. Synthesis and Structural Characterization of Magnesium Based Coordination Networks in Different Solvents

    SciTech Connect (OSTI)

    D Banerjee; J Finkelstein; A Smirnov; P Forster; L Borkowski; S Teat; J Parise

    2011-12-31T23:59:59.000Z

    Three magnesium based metal-organic frameworks, Mg{sub 3}(3,5-PDC){sub 3}(DMF){sub 3} {center_dot} DMF [1], Mg(3,5-PDC)(H{sub 2}O) {center_dot} (H{sub 2}O) [3], and Mg{sub 4}(3,5-PDC){sub 4}(DMF){sub 2}(H{sub 2}O){sub 2} {center_dot} 2DMF {center_dot} 4.5H{sub 2}O [4], and a 2-D coordination polymer, [Mg(3,5-PDC)(H{sub 2}O){sub 2}] [2] [PDC = pyridinedicarboxylate], were synthesized using a combination of DMF, methanol, ethanol, and water. Compound 1 [space group P2{sub 1}/n, a = 12.3475(5) {angstrom}, b = 11.1929(5) {angstrom}, c = 28.6734(12) {angstrom}, {beta} = 98.8160(10){sup o}, V = 3916.0(3) {angstrom}{sup 3}] consists of a combination of isolated and corner-sharing magnesium octahedra connected by the organic linkers to form a 3-D network with a 12.2 {angstrom} x 4.6 {angstrom} 1-D channel. The channel contains coordinated and free DMF molecules. In compound 2 [space group C2/c, a = 9.964(5) {angstrom}, b = 12.0694(6) {angstrom}, c = 7.2763(4) {angstrom}, {beta} = 106.4970(6){sup o}, V = 836.70(6) {angstrom}{sup 3}], PDC connects isolated seven coordinated magnesium polyhedra into a layered structure. Compound 3 [space group P6{sub 1}22, a = 11.479(1) {angstrom}, c = 14.735(3) {angstrom}, V = 1681.7(4) {angstrom}{sup 3}] (previously reported) contains isolated magnesium octahedra connected by the organic linker with each other forming a 3D network. Compound 4 [space group P2{sub 1}/c, a = 13.7442(14) {angstrom}, b = 14.2887(15) {angstrom}, c = 14.1178(14) {angstrom}, {beta} = 104.912(2){sup o}, V = 2679.2(5) {angstrom}{sup 3}] also exhibits a 3D network based on isolated magnesium octahedra with square cavities containing both disordered DMF and water molecules. The structural topologies originate due to the variable coordination ability of solvent molecules with the metal center. Water molecules coordinate with the magnesium metal centers preferably over other polar solvents (DMF, methanol, ethanol) used to synthesize the coordination networks. Despite testing multiple desolvation routes, we were unable to measure BET surface areas greater than 51.9 m{sup 2}/g for compound 1.

  19. Synthesis and Structural Characterization of Magnesium Based Coordination Networks in Different Solvents

    SciTech Connect (OSTI)

    Banerjee, Debasis; Finkelstein, Jeffrey; Smirnov, A.; Forster, Paul M.; Borkowski, Lauren A.; Teat, Simon J.; Parise, John B. (UNLV); (SUNYB); (LBNL)

    2012-10-11T23:59:59.000Z

    Three magnesium based metal-organic frameworks, Mg{sub 3}(3,5-PDC){sub 3}(DMF){sub 3} {center_dot} DMF [1], Mg(3,5-PDC)(H{sub 2}O) {center_dot} (H{sub 2}O) [3], and Mg4(3,5-PDC)4(DMF){sub 2}(H{sub 2}O){sub 2} {center_dot} 2DMF {center_dot} 4.5H{sub 2}O [4], and a 2-D coordination polymer, [Mg(3,5-PDC)(H{sub 2}O){sub 2}] [2] [PDC = pyridinedicarboxylate], were synthesized using a combination of DMF, methanol, ethanol, and water. Compound 1 [space group P2{sub 1}/n, a = 12.3475(5) {angstrom}, b = 11.1929(5) {angstrom}, c = 28.6734(12) {angstrom}, {beta} = 98.8160(10){sup o}, V = 3916.0(3) {angstrom}{sup 3}] consists of a combination of isolated and corner-sharing magnesium octahedra connected by the organic linkers to form a 3-D network with a 12.2 {angstrom} x 4.6 {angstrom} 1-D channel. The channel contains coordinated and free DMF molecules. In compound 2 [space group C2/c, a = 9.964(5) {angstrom}, b = 12.0694(6) {angstrom}, c = 7.2763(4) {angstrom}, {beta} = 106.4970(6){sup o}, V = 836.70(6) {angstrom}{sup 3}], PDC connects isolated seven coordinated magnesium polyhedra into a layered structure. Compound 3 [space group P6{sub 1}22, a = 11.479(1) {angstrom}, c = 14.735(3) {angstrom}, V = 1681.7(4) {angstrom}{sup 3}] (previously reported) contains isolated magnesium octahedra connected by the organic linker with each other forming a 3D network. Compound 4 [space group P2{sub 1}/c, a = 13.7442(14) {angstrom}, b = 14.2887(15) {angstrom}, c = 14.1178(14) {angstrom}, {beta} = 104.912(2){sup o}, V = 2679.2(5) {angstrom}{sup 3}] also exhibits a 3D network based on isolated magnesium octahedra with square cavities containing both disordered DMF and water molecules. The structural topologies originate due to the variable coordination ability of solvent molecules with the metal center. Water molecules coordinate with the magnesium metal centers preferably over other polar solvents (DMF, methanol, ethanol) used to synthesize the coordination networks. Despite testing multiple desolvation routes, we were unable to measure BET surface areas greater than 51.9 m{sup 2}/g for compound 1.

  20. Tunneling spectroscopy of superconducting MoN and NbTiN grown by atomic layer deposition

    SciTech Connect (OSTI)

    Groll, Nickolas R., E-mail: ngroll@anl.gov; Klug, Jeffrey A.; Claus, Helmut; Pellin, Michael J.; Proslier, Thomas, E-mail: proslier@anl.gov [Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Cao, Chaoyue; Becker, Nicholas G.; Zasadzinski, John F. [Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Department of Physics, Illinois Institute of Technology, Chicago, Illinois 60616 (United States); Altin, Serdar [Fen Edebiyat Fakultesi, Fizik Bolumu, Inonu Universitesi, 44280 Malatya (Turkey)

    2014-03-03T23:59:59.000Z

    A tunneling spectroscopy study is presented of superconducting MoN and Nb{sub 0.8}Ti{sub 0.2}N thin films grown by atomic layer deposition (ALD). The films exhibited a superconducting gap of 2?meV and 2.4?meV, respectively, with a corresponding critical temperature of 11.5?K and 13.4?K, among the highest reported T{sub c} values achieved by the ALD technique. Tunnel junctions were obtained using a mechanical contact method with a Au tip. While the native oxides of these films provided poor tunnel barriers, high quality tunnel junctions with low zero bias conductance (below ?10%) were obtained using an artificial tunnel barrier of Al{sub 2}O{sub 3} on the film's surface grown ex situ by ALD. We find a large critical current density on the order of 4?×?10{sup 6}?A/cm{sup 2} at T?=?0.8T{sub c} for a 60?nm MoN film and demonstrate conformal coating capabilities of ALD onto high aspect ratio geometries. These results suggest that the ALD technique offers significant promise for thin film superconducting device applications.

  1. High-performance MoS{sub 2} transistors with low-resistance molybdenum contacts

    SciTech Connect (OSTI)

    Kang, Jiahao; Liu, Wei; Banerjee, Kaustav, E-mail: kaustav@ece.ucsb.edu [Department of Electrical and Computer Engineering, University of California, Santa Barbara, California 93106 (United States)

    2014-03-03T23:59:59.000Z

    In this Letter, molybdenum (Mo) is introduced and evaluated as an alternative contact metal to atomically-thin molybdenum disulphide (MoS{sub 2}), and high-performance field-effect transistors are experimentally demonstrated. In order to understand the physical nature of the interface and highlight the role of the various factors contributing to the Mo-MoS{sub 2} contacts, density functional theory (DFT) simulations are employed, which reveal that Mo can form high quality contact interface with monolayer MoS{sub 2} with zero tunnel barrier and zero Schottky barrier under source/drain contact, as well as an ultra-low Schottky barrier (0.1?eV) at source/drain-channel junction due to strong Fermi level pinning. In agreement with the DFT simulations, high mobility, high ON-current, and low contact resistance are experimentally demonstrated on both monolayer and multilayer MoS{sub 2} transistors using Mo contacts. The results obtained not only reveal the advantages of using Mo as a contact metal for MoS{sub 2} but also highlight the fact that the properties of contacts with 2-dimensional materials cannot be intuitively predicted by solely considering work function values and Schottky theory.

  2. The interaction of nitrogen and magnesium deficiences in certain aspects of the physiology of the cotton plant 

    E-Print Network [OSTI]

    Ghosh, Debabrata

    1961-01-01T23:59:59.000Z

    THE INTERACTION OF NITROGEN AND MAGNESIUM DEFICIENCIES IN CERTAIN ASPECTS OF THE PHYSIOLOGY OF THE COTTON PLANT A Thesis By DEBABRATA GHOSH Submitted to the Graduate School of the Agricultural and Mechanical College of Texas in partial... fulfillment of the requirements for the degree of MASTER OF SCIENCE January 1961 Major Subject: plant physiology THE INTERACTION OF NITROGEN AND MAGNESIUM DEFICIENCIES IN CERTAIN ASPECTS OF THE PHYSIOLOGY OF THE COTTON PLANT A Thesis By DEBABRATA...

  3. The determination of the bioavailability and the site of absorption in lambs fed different sources of magnesium 

    E-Print Network [OSTI]

    Hurley, Leigh Anne

    1988-01-01T23:59:59.000Z

    of the animal influences Ng avail- ability. Grace (1972) found that older cows exhibited a sharper decrease in plasma Ng than did younger cows in the early stages of lactation. Magnesium Supplementation The adequacy of dietary Mg levels is probably...THE DETERMINATION OF THE BIOAVAILABILITY AND THE SITE OF ABSORPTION IN LAMBS FED DIFFERENT SOURCES OF MAGNESIUM A Thesis I, EIGH ANNE HURLEY Submitted to the Of f ice of Graduate Studies Texas AAM UniversitY in partial fulfillment...

  4. Ash, calcium, phosphorus and magnesium content of the metacarpus of hereford cows under different nutritional and physiological conditions 

    E-Print Network [OSTI]

    Haque, Mozammel

    1967-01-01T23:59:59.000Z

    ASH, CALCIUM, PHOSPHORUS AND MAGNESIUM CONTENT OF THE METACARPUS OF HEREFORD COWS UNDER DIFFERENT NUTRITIONAL AND PHYSIOLOGICAL CONDITIONS A Thesis By MOZAMMEL HAQUE Submitted to the Graduate College of the Texas A&M University in partial... centages of Calcium, Phosphorus snd Magnesium in Bone Ash for Cows Gi;en Different Treatments During Pre- And Post-Partum Periods 22 10 Analysis of Variance oi Calcium in Bone Ash Dun an's )tultiple tvange Test 1'or Calcium in Bone Ash. Analy...

  5. The effects of exercise and dietary fat on calcium, magnesium, iron, and zinc on selected tissues in rats 

    E-Print Network [OSTI]

    Nguyen, Thuy Huong

    1989-01-01T23:59:59.000Z

    of the requirements for the degree MASTER OF SCIENCE December 1989 Major Subject: Nutrition THE EFFECTS OF EXERCISE AND DIETARY FAT ON CALCIUM, MAGNESIUM, IRON, AND ZINC ON SELECTED TISSUES IN RATS A Thesis by THUY HUONG NGUYEN Approved as to style... and content by: Karen S. ubena (Chair of Committee) L. yne Greene (Member) Barbara C. O' Brien (Member) Gary C. Smith (Head of Department) December 1989 ABSTRACT The Effects of Exercise and Dietary Fat on Calcium, Magnesium, Iron, and Zinc...

  6. The effects of a suboptimal intake of magnesium with soy protein concentrate on parturition, growth, and viability in the rat 

    E-Print Network [OSTI]

    Carson, Sonja D'Awn

    1985-01-01T23:59:59.000Z

    % casein or 20% soy concentrate as the protein source, and supplemented with 700 ppm, 650 ppm, 75 ppm or 0 ppm magnesium. The experiment was conducted from growth throughout lactation. Maternal performance postpartum was adversely affected by sub... prompted research of soy products (23). Few have reported on the effects of feeding rats a suboptimal level of magnesium in a diet based on casein or soy protein concentrate from weanling through gestation and lactation. The objectives of this study...

  7. The effect of sulfur, magnesium, and various rates of potassium on forage production in some sandy soils of East Texas 

    E-Print Network [OSTI]

    Landua, Dennis Paul

    1969-01-01T23:59:59.000Z

    THE EFFECT OF SULFUR, MAGNESIUM, AND VARIOUS RATES OF POTASSIUM ON FORAGE PRODUCTION IN SOME SANDy SOILS OF EAST TEXAS A Thesis by DENNIS PAUL LANDUA Submitted to the Graduate Collccje of Texas AFM Unive, sity in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE Ma 1969 Major Subject Soil Chemistr THE EFFECT OF SULFUR, MAGNESIUM, AND VARIOUS RATES OF POTASSIUM ON FORAGE PRODUCTION IN SOME SANDY SOILS OF EAST TEXAS A Thesis by DENNIS PAUL LANDUA Approved...

  8. Oxidation, carburization and/or sulfidation resistant iron aluminide alloy

    DOE Patents [OSTI]

    Sikka, Vinod K.; Deevi, Seetharama C.; Fleischhauer, Grier S.; Hajaligol, Mohammad R.; Lilly, Jr., A. Clifton

    2003-08-19T23:59:59.000Z

    The invention relates generally to aluminum containing iron-base alloys useful as electrical resistance heating elements. The aluminum containing iron-base alloys have improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The alloy has an entirely ferritic microstructure which is free of austenite and includes, in weight %, over 4% Al, .ltoreq.1% Cr and either .gtoreq.0.05% Zr or Zro.sub.2 stringers extending perpendicular to an exposed surface of the heating element or .gtoreq.0.1% oxide dispersoid particles. The alloy can contain 14-32% Al, .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Zr, .ltoreq.1% C, .ltoreq.0.1% B. .ltoreq.30% oxide dispersoid and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1% rare earth metal, .ltoreq.1% oxygen, .ltoreq.3% Cu, balance Fe.

  9. Lithium metal oxide electrodes for lithium cells and batteries

    DOE Patents [OSTI]

    Thackeray, Michael M.; Johnson, Christopher S.; Amine, Khalil; Kim, Jaekook

    2006-11-14T23:59:59.000Z

    A lithium metal oxide positive electrode for a non-aqueous lithium cell is disclosed. The cell is prepared in its initial discharged state and has a general formula xLiMO2.(1-x)Li2M'O3 in which 0oxidation state and with at least one ion being Ni, and where M' is one or more ions with an average tetravalent oxidation state. Complete cells or batteries are disclosed with anode, cathode and electrolyte as are batteries of several cells connected in parallel or series or both.

  10. Lithium Metal Oxide Electrodes For Lithium Cells And Batteries

    DOE Patents [OSTI]

    Thackeray, Michael M. (Naperville, IL); Johnson, Christopher S. (Naperville, IL); Amine, Khalil (Downers Grove, IL); Kim, Jaekook (Naperville, IL)

    2004-01-20T23:59:59.000Z

    A lithium metal oxide positive electrode for a non-aqueous lithium cell is disclosed. The cell is prepared in its initial discharged state and has a general formula xLiMO.sub.2.(1-x)Li.sub.2 M'O.sub.3 in which 0oxidation state and with at least one ion being Mn or Ni, and where M' is one or more ion with an average tetravalent oxidation state. Complete cells or batteries are disclosed with anode, cathode and electrolyte as are batteries of several cells connected in parallel or series or both.

  11. Lithium metal oxide electrodes for lithium cells and batteries

    DOE Patents [OSTI]

    Thackeray, Michael M. (Naperville, IL); Johnson, Christopher S. (Naperville, IL); Amine, Khalil (Oakbrook, IL)

    2008-12-23T23:59:59.000Z

    A lithium metal oxide positive electrode for a non-aqueous lithium cell is disclosed. The cell is prepared in its initial discharged state and has a general formula xLiMO.sub.2.(1-x)Li.sub.2M'O.sub.3 in which 0oxidation state and with at least one ion being Mn or Ni, and where M' is one or more ion with an average tetravalent oxidation state. Complete cells or batteries are disclosed with anode, cathode and electrolyte as are batteries of several cells connected in parallel or series or both.

  12. Honeywell Modular Automation System Computer Software Documentation for the Magnesium Hydroxide Precipitation Process

    SciTech Connect (OSTI)

    STUBBS, A.M.

    2001-02-01T23:59:59.000Z

    The purpose of this Computer Software Document (CSWD) is to provide configuration control of the Honeywell Modular Automation System (MAS) in use at the Plutonium Finishing Plant (PFP) for the Magnesium Hydroxide Precipitation Process in Rm 23OC/234-52. This CSWD describes hardware and PFP/FFS developed software for control of Magnesium Hydroxide Precipitation process located in room 230, 234-52. The Honeywell and Plant Scape software generate limited configuration reports for the developed control software. These reports are described in the following section and are attached as addendum's. This plan applies to PFP Engineering Manager, Thermal Stabilization Cognizant Engineers, Solutions Stabilization Engineers, and the Shift Technical Advisors responsible for the Honeywell MAS software/hardware and administration of the Honeywell System.

  13. Asphalt Oxidation Kinetics and Pavement Oxidation Modeling

    E-Print Network [OSTI]

    Jin, Xin

    2012-07-16T23:59:59.000Z

    Most paved roads in the United States are surfaced with asphalt. These asphalt pavements suffer from fatigue cracking and thermal cracking, aggravated by the oxidation and hardening of asphalt. This negative impact of asphalt oxidation on pavement...

  14. Yield Asymmetry Design of Magnesium Alloys by Integrated Computational Materials Engineering

    SciTech Connect (OSTI)

    Li, Dongsheng; Joshi, Vineet V.; Lavender, Curt A.; Khaleel, Mohammad A.; Ahzi, Said

    2013-11-01T23:59:59.000Z

    Deformation asymmetry of magnesium alloys is an important factor on machine design in automobile industry. Represented by the ratio of compressive yield stress (CYS) against tensile yield stress (TYS), deformation asymmetry is strongly related to microstructure, characterized by texture and grain size. Modified intermediate phi-model, a polycrystalline viscoplasticity model, is used to predict the deformation behavior of magnesium alloys with different grain sizes. Validated with experimental results, integrated computational materials engineering is applied to find out the route in achieving desired asymmetry by thermomechanical processing. In some texture, for example, rolled texture, CYS/TYS is smaller than 1 under different loading directions. In some texture, for example, extruded texture, asymmetry is large along normal direction. Starting from rolled texture, the asymmetry will increased to close to 1 along rolling direction after compressed to a strain of 0.2. Our model shows that grain refinement increases CYS/TYS. Besides texture control, grain refinement can also optimize the yield asymmetry. After the grain size decreased to a critical value, CYS/TYS reaches to 1 since CYS increases much faster than TYS. By tailoring the microstructure using texture control and grain refinement, it is achievable to optimize yield asymmetry in wrought magnesium alloys.

  15. Process for CO.sub.2 capture using a regenerable magnesium hydroxide sorbent

    DOE Patents [OSTI]

    Siriwardane, Ranjani V; Stevens, Jr., Robert W

    2013-06-25T23:59:59.000Z

    A process for CO.sub.2 separation using a regenerable Mg(OH).sub.2 sorbent. The process absorbs CO.sub.2 through the formation of MgCO.sub.3 and releases water product H.sub.2O. The MgCO.sub.3 is partially regenerated through direct contact with steam, which acts to heat the magnesium carbonate to a higher temperature, provide heat duty required to decompose the magnesium carbonate to yield MgO and CO.sub.2, provide an H.sub.2O environment over the magnesium carbonate thereby shifting the equilibrium and increasing the potential for CO.sub.2 desorption, and supply H.sub.2O for rehydroxylation of a portion of the MgO. The mixture is polished in the absence of CO.sub.2 using water product H.sub.2O produced during the CO.sub.2 absorption to maintain sorbent capture capacity. The sorbent now comprised substantially of Mg(OH).sub.2 is then available for further CO.sub.2 absorption duty in a cyclic process.

  16. Simple Molybdenum(IV) Olefin Complexes of the Type Mo(NR)(X)(Y)(olefin)

    E-Print Network [OSTI]

    Marinescu, Smaranda C.

    Exposure of heptane solutions of Mo(NAr)(CHCMe2Ph)(Me2Pyr)(OAr) (1a; Ar = 2,6-diisopropylphenyl), Mo(NAr)(CHCMe3)(Me2Pyr)[OCMe(CF3)2] (1b), and Mo(NAr)(CHCMe2Ph)(Me2Pyr)(OSiPh3) (1c) to one atmosphere of ethylene for 12 h ...

  17. Propane ammoxidation over the Mo-V-Te-Nb-O M1 phase: Reactivity of surface cations in hydrogen abstraction steps

    SciTech Connect (OSTI)

    Muthukumar, Kaliappan [University of Cincinnati; Yu, Junjun [University of Cincinnati; Xu, Ye [ORNL; Guliants, Vadim V. [University of Cincinnati

    2011-01-01T23:59:59.000Z

    Density functional theory calculations (GGA-PBE) have been performed to investigate the adsorption of C3 (propane, isopropyl, propene, and allyl) and H species on the proposed active center present in the surface ab planes of the bulk Mo-V-Te-Nb-O M1 phase in order to better understand the roles of the different surface cations in propane ammoxidation. Modified cluster models were employed to isolate the closely spaced V=O and Te=O from each other and to vary the oxidation state of the V cation. While propane and propene adsorb with nearly zero adsorption energy, the isopropyl and allyl radicals bind strongly to V=O and Te=O with adsorption energies, {Delta}E, being {le} -1.75 eV, but appreciably more weakly on other sites, such as Mo=O, bridging oxygen (Mo-O-V and Mo-O-Mo), and empty metal apical sites ({Delta}E > -1 eV). Atomic H binds more strongly to Te = O ({Delta}E {le} -3 eV) than to all the other sites, including V = O ({Delta}E = -2.59 eV). The reduction of surface oxo groups by dissociated H and their removal as water are thermodynamically favorable except when both H atoms are bonded to the same Te=O. Consistent with the strong binding of H, Te=O is markedly more active at abstracting the methylene H from propane (E{sub a} {le} 1.01 eV) than V = O (E{sub a} = 1.70 eV on V{sup 5+} = O and 2.13 eV on V{sup 4+} = O). The higher-than-observed activity and the loose binding of Te = O moieties to the mixed metal oxide lattice of M1 raise the question of whether active Te = O groups are in fact present in the surface ab planes of the M1 phase under propane ammoxidation conditions.

  18. Experimental activities supporting commercial U.S. accelerator production of 99-Mo

    SciTech Connect (OSTI)

    Dale, Gregory E [Los Alamos National Laboratory; Chemerisov, Sergey D [ANL; Vandegrift, George F [ANL

    2010-01-01T23:59:59.000Z

    {sup 99m}Tc, the daughter product of {sup 99}Mo, is the most commonly used radioisotope for nuclear medicine in the U.S. Experiments are being performed at Los Alamos National Laboratory and Argonne National Laboratory to demonstrate production of {sup 99}Mo using accelerators. The {sup 100}Mo({gamma},n){sup 99}Mo reaction in an enriched {sup 100}Mo target is currently under investigation. Three scaled low-power production experiments using a 20-MeV electron linac at Argonne have been performed to date. Two of these experiments used natural Mo targets and produced a total of 613 {mu}C of {sup 99}Mo. The third experiment used an enriched {sup 100}Mo target and produced 10.5 mCi of {sup 99}Mo. Following irradiation the targets were dissolved and the low specific activity solution was processed through an ARSII generator from NorthStar Medical Radioisotopes. Yields of {sup 99m}Tc >95% have been observed.

  19. Conceptual design of a new homogeneous reactor for medical radioisotope Mo-99/Tc-99m production

    SciTech Connect (OSTI)

    Liem, Peng Hong [Nippon Advanced Information Service (NAIS Co., Inc.) Scientific Computational Division, 416 Muramatsu, Tokaimura, Ibaraki (Japan); Tran, Hoai Nam [Chalmers University of Technology, Dept. of Applied Physics, Div. of Nuclear Engineering, SE-412 96 Gothenburg (Sweden); Sembiring, Tagor Malem [National Nuclear Energy Agency (BATAN), Center for Reactor Technology and Nuclear Safety, Kawasan Puspiptek, Serpong, Tangerang Selatan, Banten (Indonesia); Arbie, Bakri [PT MOTAB Technology, Kedoya Elok Plaza Blok DA 12, Jl. Panjang, Kebun Jeruk, Jakarta Barat (Indonesia)

    2014-09-30T23:59:59.000Z

    To partly solve the global and regional shortages of Mo-99 supply, a conceptual design of a nitrate-fuel-solution based homogeneous reactor dedicated for Mo-99/Tc-99m medical radioisotope production is proposed. The modified LEU Cintichem process for Mo-99 extraction which has been licensed and demonstrated commercially for decades by BATAN is taken into account as a key design consideration. The design characteristics and main parameters are identified and the advantageous aspects are shown by comparing with the BATAN's existing Mo-99 supply chain which uses a heterogeneous reactor (RSG GAS multipurpose reactor)

  20. Greenfield Alternative Study LEU-Mo Fuel Fabrication Facility

    SciTech Connect (OSTI)

    Washington Division of URS

    2008-07-01T23:59:59.000Z

    This report provides the initial “first look” of the design of the Greenfield Alternative of the Fuel Fabrication Capability (FFC); a facility to be built at a Greenfield DOE National Laboratory site. The FFC is designed to fabricate LEU-Mo monolithic fuel for the 5 US High Performance Research Reactors (HPRRs). This report provides a pre-conceptual design of the site, facility, process and equipment systems of the FFC; along with a preliminary hazards evaluation, risk assessment as well as the ROM cost and schedule estimate.

  1. Phase transitions in the adsorption system Li/Mo(112)

    E-Print Network [OSTI]

    Fedorus, A.; Kolthoff, D.; Koval, V.; Lyuksyutov, Igor F.; Naumovets, AG; Pfnur, H.

    2000-01-01T23:59:59.000Z

    limit can be quasi-one-dimensional. Such model systems are formed upon submonolayer adsorption on surfaces with strongly an- PRB 620163-1829/2000/62~4!/2852~10!/$15.00 n system Li?Mo?112? ,1,3 A. G. Naumovets,1 and H. Pfnu?r2,* , Prospect Nauki 46... W/Re thermocouple and was con- trolled by a computerized feedback circuit with a resolution of 0.01 K. The source of lithium was constructed and outgassed as PRB 62 PHASE TRANSITIONS IN TH described in Ref. 6. The LEED patterns have been taken...

  2. Recovery of Mo/Si multilayer coated optical substrates

    DOE Patents [OSTI]

    Baker, Sherry L. (Pleasanton, CA); Vernon, Stephen P. (Pleasanton, CA); Stearns, Daniel G. (Los Altos, CA)

    1997-12-16T23:59:59.000Z

    Mo/Si multilayers are removed from superpolished ZERODUR and fused silica substrates with a dry etching process that, under suitable processing conditions, produces negligible change in either the substrate surface figure or surface roughness. The two step dry etching process removes SiO.sub.2 overlayer with a fluroine-containing gas and then moves molybdenum and silicon multilayers with a chlorine-containing gas. Full recovery of the initial normal incidence extreme ultra-violet (EUV) reflectance response has been demonstrated on reprocessed substrates.

  3. Recovery of Mo/Si multilayer coated optical substrates

    DOE Patents [OSTI]

    Baker, S.L.; Vernon, S.P.; Stearns, D.G.

    1997-12-16T23:59:59.000Z

    Mo/Si multilayers are removed from superpolished ZERODUR and fused silica substrates with a dry etching process that, under suitable processing conditions, produces negligible change in either the substrate surface figure or surface roughness. The two step dry etching process removes SiO{sub 2} overlayer with a fluroine-containing gas and then moves molybdenum and silicon multilayers with a chlorine-containing gas. Full recovery of the initial normal incidence extreme ultra-violet (EUV) reflectance response has been demonstrated on reprocessed substrates. 5 figs.

  4. DOE - Office of Legacy Management -- Petrolite Corp - MO 08

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA group currentBradleyTableSelling Corp - CTOregonPetrolite Corp - MO 08 FUSRAP

  5. Fabrication of Chemically Doped, High Upper Critical Field Magnesium Diboride Superconducting Wires

    SciTech Connect (OSTI)

    Marzik, James, V.

    2005-10-13T23:59:59.000Z

    Controlled chemical doping of magnesium diboride (MgB2) has been shown to substantially improve its superconducting properties to the levels required for high field magnets, but the doping is difficult to accomplish through the usual route of solid state reaction and diffusion. Further, superconducting cables of MgB2 are difficult to fabricate because of the friable nature of the material. In this Phase I STTR project, doped and undoped boron fibers were made by chemical vapor deposition (CVD). Several >100m long batches of doped and undoped fiber were made by CVD codeposition of boron plus dopants. Bundles of these fibers infiltrated with liquid magnesium and subsequently converted to MgB2 to form Mg-MgB2 metal matrix composites. In a parallel path, doped boron nano-sized powder was produced by a plasma synthesis technique, reacted with magnesium to produce doped MgB2 superconducting ceramic bodies. The doped powder was also fabricated into superconducting wires several meters long. The doped boron fibers and powders made in this program were fabricated into fiber-metal composites and powder-metal composites by a liquid metal infiltration technique. The kinetics of the reaction between boron fiber and magnesium metal was investigated in fiber-metal composites. It was found that the presence of dopants had significantly slowed the reaction between magnesium and boron. The superconducting properties were measured for MgB2 fibers and MgB2 powders made by liquid metal infiltration. Properties of MgB2 products (Jc, Hc2) from Phase I are among the highest reported to date for MgB2 bulk superconductors. Chemically doped MgB2 superconducting magnets can perform at least as well as NbTi and NbSn3 in high magnetic fields and still offer an improvement over the latter two in terms of operating temperature. These characteristics make doped MgB2 an effective material for high magnetic field applications, such as magnetic confined fusion, and medical MRI devices. Developing fusion as an energy source will dramatically reduce energy costs, global warming, and radioactive waste. Cheaper and more efficient medical MRI devices could lower examination costs, find potential health problems earlier, and thus also benefit society as a whole. Other potential commercial applications for this material are devices for the generation and storage of electrical power, thus lowering the cost of delivered electricity.

  6. Low cation coordination in oxide melts

    SciTech Connect (OSTI)

    Skinner, Lawrie [State University of New York, Stony Brook] [State University of New York, Stony Brook; Benmore, Chris J [Argonne National Laboratory (ANL)] [Argonne National Laboratory (ANL); Du, Jincheng [University of North Texas] [University of North Texas; Weber, Richard [Argonne National Laboratory (ANL)] [Argonne National Laboratory (ANL); Neuefeind, Joerg C [ORNL] [ORNL; Tumber, Sonia [Materials Development, Inc., Evanston, IL] [Materials Development, Inc., Evanston, IL; Parise, John B [Stony Brook University (SUNY)] [Stony Brook University (SUNY)

    2014-01-01T23:59:59.000Z

    The complete set of Faber-Ziman partial pair distribution functions for a rare earth oxide liquid were measured for the first time by combining aerodynamic levitation, neutron diffraction, high energy x-ray diffraction and isomorphic substitution using Y2 O3 and Ho2 O3 melts. The average Y- O coordination is measured to be 5.5(2), which is significantly less than the octahedral coordination of crystalline Y2 O3 (or Ho2 O3 ). Investigation of high temperature La2 O3 , ZrO2 , SiO2 , and Al2 O3 melts by x-ray diffraction and molecular dynamics simulations also show lower-than-crystal cation- oxygen coordination. These measurements suggest a general trend towards lower M-O coordination compared to their crystalline counterparts. It is found that this coordination number drop is larger for lower field strength, larger radius cations and is negligible for high field strength (network forming) cations. These findings have broad implications for predicting the local structure and related physical properties of metal-oxide melts and oxide glasses.

  7. Porous acicular mullite obtained by controlled oxidation of waste molybdenum disilicide

    SciTech Connect (OSTI)

    Bu?evac, Dušan, E-mail: bucevac@vinca.rs [Vin?a Institute of Nuclear Sciences, University of Belgrade, Belgrade 11001 (Serbia); Dap?evi?, Aleksandra [Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, Belgrade 11120 (Serbia); Maksimovi?, Vesna [Vin?a Institute of Nuclear Sciences, University of Belgrade, Belgrade 11001 (Serbia)

    2014-02-01T23:59:59.000Z

    Highlights: • Waste MoSi{sub 2} heating elements were used as starting material for fabrication of porous acicular mullite. • Calcined MoSi{sub 2} powder was source of SiO{sub 2} and pore former at the same time. • Porous acicular mullite is promising material for filtration of diesel engine exhaust. • Samples with decent mechanical integrity and porosity of more than 60% were fabricated. - Abstract: Porous acicular mullite was fabricated by using waste MoSi{sub 2} heating element and Al{sub 2}O{sub 3}. Careful calcination of the pulverized heating element led to the formation of a mixture of MoO{sub 3} and amorphous SiO{sub 2}. This mixture was employed as both SiO{sub 2} precursor and pore former. The oxidation of MoSi{sub 2} and mullite formation were studied. The effect of fabrication temperature on phase composition, porosity, grain morphology, and compressive strength of sintered mullite was examined. Pure mullite with porosity of more than 60% and compressive strength of ?20 MPa was obtained at temperature as low as 1300 °C. The microstructure consisted of elongated, rectangular, prism-like grains which are known to be effective in filtration of diesel engine exhaust. The increase in sintering temperature caused the change of grain morphology and reduction in compressive strength.

  8. Long-Term Oxidation of Candidate Cast Iron and Advanced Austenitic Stainless Steel Exhaust System Alloys from 650-800 C in Air with Water Vapor

    SciTech Connect (OSTI)

    Brady, Michael P [ORNL; Muralidharan, Govindarajan [ORNL; Leonard, Donovan N [ORNL; Haynes, James A [ORNL

    2014-01-01T23:59:59.000Z

    The oxidation behavior of SiMo cast iron, Ni-resist D5S cast iron, cast chromia-forming austenitic stainless steels of varying Cr/Ni content based on CF8C plus, HK, and HP, and a developmental cast alumina-forming austenitic (AFA) stainless steel of interest for diesel exhaust system components were studied for up to 5000 h at 650-800 C in air with 10% H2O. At 650 C, the Ni-resist D5S exhibited moderately better oxidation resistance than did the SiMo cast iron. However, the D5S suffered from oxide scale spallation issues at 700 C and higher, whereas the oxide scales formed on SiMo cast iron remained adherent from 700-800 C despite oxide scales hundreds of microns thick. The oxidation of the SiMo cast iron exhibited unusual temperature dependence, with periods of slower oxidation kinetics at 750-800 C compared to 650-700 C due to continuous silica-rich scale formation at the higher temperatures. The oxidation of the cast chromia-forming austenitics trended with the level of Cr and Ni additions, with small mass losses consistent with Cr oxy-hydroxide volatilization processes for the higher 25Cr/25-35Ni HK and HP type alloys, and transition to rapid Fe-base oxide formation and scale spallation in the lower 19Cr/12Ni CF8C plus type alloy. In contrast, small positive mass changes consistent with protective alumina scale formation were observed for the cast AFA alloy under all conditions studied. Implications of these findings for diesel exhaust system components are discussed.

  9. Identification of single nucleotides in MoS2 nanopores

    E-Print Network [OSTI]

    Jiandong Feng; Ke Liu; Roman D. Bulushev; Sergey Khlybov; Dumitru Dumcenco; Andras Kis; Aleksandra Radenovic

    2015-05-07T23:59:59.000Z

    Ultrathin membranes have drawn much attention due to their unprecedented spatial resolution for DNA nanopore sequencing. However, the high translocation velocity (3000-50000 nt/ms) of DNA molecules moving across such membranes limits their usability. To this end, we have introduced a viscosity gradient system based on room-temperature ionic liquids (RTILs) to control the dynamics of DNA translocation through a nanometer-size pore fabricated in an atomically thin MoS2 membrane. This allows us for the first time to statistically identify all four types of nucleotides with solid state nanopores. Nucleotides are identified according to the current signatures recorded during their transient residence in the narrow orifice of the atomically thin MoS2 nanopore. In this novel architecture that exploits high viscosity of RTIL, we demonstrate single-nucleotide translocation velocity that is an optimal speed (1-50 nt/ms) for DNA sequencing, while keeping the signal to noise ratio (SNR) higher than 10. Our findings pave the way for future low-cost and rapid DNA sequencing using solid-state nanopores.

  10. Characterization of U-Mo Foils for AFIP-7

    SciTech Connect (OSTI)

    Edwards, Danny J.; Ermi, Ruby M.; Schemer-Kohrn, Alan L.; Overman, Nicole R.; Henager, Charles H.; Burkes, Douglas; Senor, David J.

    2012-11-07T23:59:59.000Z

    Twelve AFIP in-process foil samples, fabricated by either Y-12 or LANL, were shipped from LANL to PNNL for potential characterization using optical and scanning electron microscopy techniques. Of these twelve, nine different conditions were examined to one degree or another using both techniques. For this report a complete description of the results are provided for one archive foil from each source of material, and one unirradiated piece of a foil of each source that was irradiated in the Advanced Test Reactor. Additional data from two other LANL conditions are summarized in very brief form in an appendix. The characterization revealed that all four characterized conditions contained a cold worked microstructure to different degrees. The Y-12 foils exhibited a higher degree of cold working compared to the LANL foils, as evidenced by the highly elongated and obscure U-Mo grain structure present in each foil. The longitudinal orientations for both of the Y-12 foils possesses a highly laminar appearance with such a distorted grain structure that it was very difficult to even offer a range of grain sizes. The U-Mo grain structure of the LANL foils, by comparison, consisted of a more easily discernible grain structure with a mix of equiaxed and elongated grains. Both materials have an inhomogenous grain structure in that all of the characterized foils possess abnormally coarse grains.

  11. Supercapacitor behavior of ?-MnMoO{sub 4} nanorods on different electrolytes

    SciTech Connect (OSTI)

    Purushothaman, K.K., E-mail: purushoth_gri@yahoo.co.in [Department of Physics, TRP Engineering College (SRM Group), Irungalur, Trichy, Tamilnadu (India); Cuba, M. [Department of Physics, Gandhigram Rural Institute – Deemed University, Gandhigram, Tamilnadu (India)] [Department of Physics, Gandhigram Rural Institute – Deemed University, Gandhigram, Tamilnadu (India); Muralidharan, G., E-mail: muralg@rediffmail.com [Department of Physics, Gandhigram Rural Institute – Deemed University, Gandhigram, Tamilnadu (India)

    2012-11-15T23:59:59.000Z

    Graphical abstract: SEM image of ?-MnMoO{sub 4} nanorods on FTO substrate. Highlights: ? Synthesis of ?-MnMoO{sub 4} nanorods by spin coating method. ? First study on the effect of electrolyte on the pseudocapacitance behavior. ? ?-MnMoO{sub 4} nanorods exhibit maximum specific capacitance of 998 F/g. ? At higher scan rates p-TSA electrolyte exhibits superior capacitive behavior. -- Abstract: ?-MnMoO{sub 4} nanorods were prepared on conducting glass substrate via sol–gel spin coating method at the optimum doping level. The effect of electrolyte on the pseudocapacitance behavior of the ?-MnMoO{sub 4} nanorods was studied using para toluene sulfonic acid (p-TSA), sulfuric acid (H{sub 2}SO{sub 4}) and hydrochloric acid (HCl) as electrolytes. X-ray diffraction analysis reveals the formation of ?-MnMoO{sub 4} in monoclinic phase. FTIR spectra contain vibrational bands associated with Mo=O, M–O and Mo–O–Mo bonds. SEM image reveals the formation of nanorods. Supercapacitor behavior has been studied using cyclic voltammetry (CV) analysis. ?-MnMoO{sub 4} nanorods exhibit maximum specific capacitance of 998 F/g at a scan rate of 5 mV/s in H{sub 2}SO{sub 4} electrolyte while a specific capacitance of 784 F/g and 530 F/g have been obtained using p-TSA and HCl electrolytes, respectively. At higher scan rates p-TSA electrolyte exhibits superior capacitive behavior than H{sub 2}SO{sub 4}.

  12. The evidence of cathodic micro-discharges during plasma electrolytic oxidation process

    SciTech Connect (OSTI)

    Nominé, A., E-mail: alexandre.nomine@univ-lorraine.fr [Institut Jean Lamour, UMR 7198 CNRS, Université de Lorraine, Parc de Saurupt, 54011 Nancy (France); National Institute of Science and Technology “MISiS,” 4, Leninskij Prospekt, Moscow 119049 (Russian Federation); Martin, J.; Noël, C.; Henrion, G.; Belmonte, T. [Institut Jean Lamour, UMR 7198 CNRS, Université de Lorraine, Parc de Saurupt, 54011 Nancy (France); Bardin, I. V.; Kovalev, V. L.; Rakoch, A. G. [National Institute of Science and Technology “MISiS,” 4, Leninskij Prospekt, Moscow 119049 (Russian Federation)

    2014-02-24T23:59:59.000Z

    Plasma electrolytic oxidation (PEO) processing of EV31 magnesium alloy has been carried out in fluoride containing electrolyte under bipolar pulse current regime. Unusual PEO cathodic micro-discharges have been observed and investigated. It is shown that the cathodic micro-discharges exhibit a collective intermittent behavior, which is discussed in terms of charge accumulations at the layer/electrolyte and layer/metal interfaces. Optical emission spectroscopy is used to determine the electron density (typ. 10{sup 15}?cm{sup ?3}) and the electron temperature (typ. 7500?K) while the role of F{sup ?} anions on the appearance of cathodic micro-discharges is pointed out.

  13. The effect of dinitrophenol on the development and oxidative metabolism of the chick embryo 

    E-Print Network [OSTI]

    Feldman, Gerald Lewis

    1959-01-01T23:59:59.000Z

    metabolized by all parts of the lens (26, 27). The cortex is glycolytic and produces lactate as the end product of its glucose metabolism. The epithelium, however, possesses the oxidative enzyme systems which completely metabo? lize glucose through...-Kjeldahl procedure. 30 RESULTS The Q0? of 1.0 ml. of a whole homogenate and 2,0 ml? of a cell-free extract of this homogenate prepared from 3 embryos per 10 ml0 of buffer, was found to be 13.0 and 5.2, respectively. The addition of SKYisH eH magnesium sulfate...

  14. Photo-oxidation catalysts

    DOE Patents [OSTI]

    Pitts, J. Roland (Lakewood, CO); Liu, Ping (Irvine, CA); Smith, R. Davis (Golden, CO)

    2009-07-14T23:59:59.000Z

    Photo-oxidation catalysts and methods for cleaning a metal-based catalyst are disclosed. An exemplary catalyst system implementing a photo-oxidation catalyst may comprise a metal-based catalyst, and a photo-oxidation catalyst for cleaning the metal-based catalyst in the presence of light. The exposure to light enables the photo-oxidation catalyst to substantially oxidize absorbed contaminants and reduce accumulation of the contaminants on the metal-based catalyst. Applications are also disclosed.

  15. Lithium metal oxide electrodes for lithium cells and batteries

    DOE Patents [OSTI]

    Thackeray, Michael M. (Naperville, IL); Johnson, Christopher S. (Naperville, IL); Amine, Khalil (Downers Grove, IL); Kim, Jaekook (Naperville, IL)

    2004-01-13T23:59:59.000Z

    A lithium metal oxide positive electrode for a non-aqueous lithium cell is disclosed. The cell is prepared in its initial discharged state and has a general formula xLiMO.sub.2.(1-x)Li.sub.2 M'O.sub.3 in which 0

  16. 2-Stage Melting in 2 Dimensions - Te/mo(110) 

    E-Print Network [OSTI]

    STOLZENBERG, M.; Lyuksyutov, Igor F.; BAUER, E.

    1993-01-01T23:59:59.000Z

    Arsenate and Arsenite Retention and Release in Oxide and Sulfide Dominated Systems Principal Investigator: Richard H. Loeppert Co-Investigators: Amita Jain Klaus Raven Jianlin Wang Soil & Crop Sciences Dept. Texas A&M University College Station, TX... of the specific reagents. Selective extractions also give clues concern- ing the role that suspected biological agents may have on the mobilization and uptake of arsenic. Selective extractions were performed on both oxidized and reduced sediments. Selective...

  17. Fe3O4-LiMo3Se3 Nanoparticle Clusters as Superparamagnetic Nanocompasses

    E-Print Network [OSTI]

    Osterloh, Frank

    -iodopropionic acid treated LiMo3Se3 nanowire bundles with oleic acid-stabilized Fe3O4 nanoparticles of 2.8, 5Fe3O4-LiMo3Se3 Nanoparticle Clusters as Superparamagnetic Nanocompasses Frank E. Osterloh,*, Hiroki A scaleable chemical approach to functional nanoscale analogues of the magnetic compasses in magnetotactic

  18. Hole Selective MoOx Contact for Silicon Solar Cells Corsin Battaglia,,,

    E-Print Network [OSTI]

    Javey, Ali

    Hole Selective MoOx Contact for Silicon Solar Cells Corsin Battaglia,,, Xingtian Yin,,,§, Maxwell Laboratory, Xi'an Jiaotong University, Xi'an, 710049 Shaanxi, People's Republic of China Joint Center/silicon solar cell with a power conversion efficiency of 14.3%. While MoOx is commonly considered

  19. MoIAC Pre-Audit Form Ways to submit this form

    E-Print Network [OSTI]

    Noble, James S.

    information: #12;MoIAC Pre-Audit Form Major Energy Consuming Equipment: Please provide informationMoIAC Pre-Audit Form Ways to submit this form: 1. Fill up the form and fax it to 573-882-2693 Attn: Dr. Bin Wu 2. Print and return this form by mail to: Dr. Bin Wu University of Missouri

  20. Adsorption studies of Mo and V onto ferrihydrite *, L. G. BENNING

    E-Print Network [OSTI]

    Benning, Liane G.

    Adsorption studies of Mo and V onto ferrihydrite L. BRINZA 1, *, L. G. BENNING 1 AND P. J. STATHAM-sorbate experiments, 100% adsorption was observed at pH values below 6 and 8, respectively. Above the point of zero charge (PZC = 7.97) of FHY, the adsorption efficiency for Mo dropped dramatically (20% at pH 8) while V

  1. Stability of Graphene doping with MoO_3 and I_2

    E-Print Network [OSTI]

    D’Arsié, Lorenzo; Esconjauregui, Santiago; Weatherup, Robert; Guo, Yuzheng; Bhardwaj, Sunil; Centeno, Alba; Zurutuza, Amaia; Cepek, Cinzia; Robertson, John

    2014-09-08T23:59:59.000Z

    We dope graphene by evaporation of MoO_3 or by solution-deposition of I_2 and assess the doping stability for its use as transparent electrodes. Electrical measurements show that both dopants increase the graphene sheet conductivity and find that Mo...

  2. Student Financial Aid 11 Jesse Hall University of Missouri Columbia Columbia, MO 65211-1600

    E-Print Network [OSTI]

    Taylor, Jerry

    Student Financial Aid 11 Jesse Hall University of Missouri ­ Columbia Columbia, MO 65211-1600 PHONE;Student Financial Aid 11 Jesse Hall University of Missouri ­ Columbia Columbia, MO 65211-1600 PHONE (573 ________________________________________________________________________________________________________________________ Name of Host Institution (College or University you will be attending or taking additional classes

  3. Ligand Conjugation of Chemically Exfoliated MoS2 Stanley S. Chou,+

    E-Print Network [OSTI]

    Huang, Jiaxing

    Ligand Conjugation of Chemically Exfoliated MoS2 Stanley S. Chou,+ Mrinmoy De,+ Jaemyung Kim,+ Segi and chemical properties. Here, we demonstrate ligand conjugation of chemically exfoliated MoS2 using thiol-nitrilotriacetic acid chelation.13 However, colloidal sur- face modification of water dispersible, chemically exfoliated

  4. Characterization of Single-Walled Carbon Nanotubes (SWNTs) Produced by CO Disproportionation on Co-Mo

    E-Print Network [OSTI]

    Resasco, Daniel

    Characterization of Single-Walled Carbon Nanotubes (SWNTs) Produced by CO Disproportionation on Co Received November 15, 2001. Revised Manuscript Received February 6, 2002 The disproportionation of CO over Co-Mo/SiO2 catalysts with low Co/Mo ratios results in a high selectivity to single-walled carbon

  5. Corrosion Behavior of Solution-Annealed CoCrMo Medical Implant

    E-Print Network [OSTI]

    Shull, Kenneth R.

    ! ! ! Corrosion Behavior of Solution- Annealed CoCrMo Medical Implant Alloys Pooja Panigrahi University June 6, 2011 #12;! ! ""! Corrosion Behavior of Solution-Annealed CoCrMo Medical Implant Alloys and Applied Sciences Northwestern University June 6, 2011 Abstract Corrosion behavior of solution annealed

  6. Double beta decays and solar neutrinos with 100 MOON(Mo Observatory Of Neutrinos)

    E-Print Network [OSTI]

    Washington at Seattle, University of

    nuclear laboratory for spectroscopic studies of neutrinos Neutrinos are key particles for new frontiers) are sensitive and realistic experiments for studying the Majorana nature of the neutrino and the absolute massDouble beta decays and solar neutrinos with 100 Mo ­MOON(Mo Observatory Of Neutrinos)­ May 24, 2005

  7. Posting type Advisory Subject Shifts in Mo-anode XRF element calibration factors

    E-Print Network [OSTI]

    Fischer, Emily V.

    Posting type Advisory Subject Shifts in Mo-anode XRF element calibration factors Module/Species A@crocker.ucdavis.edu Supporting information A molybdenum-anode XRF instrument is used to analyze the heavier elements (Ni, Cu, Zn with lighter deposits were acquired and used in the Mo-anode XRF system. The new calibration foils resulted

  8. Oxidation of propylene over copper oxide catalysts

    E-Print Network [OSTI]

    Billingsley, David Stuart

    1958-01-01T23:59:59.000Z

    results were obtained using an asbestos supported CuO-Cr203 catalyst. Venkataramam and his co-workers (66) studied the catalytic oxidation of ethylene to ethylene oxide by the fluidized bed technique using a static bed of catalyst. Precipitated Ag20... in the air-ethylene ratio to maintain good yields of ethylene oxide. Wan (68) reported the oxidation of ethylene to acetaldehyde by use of a silver catalyst in a 5/16 dnch inner diameter stainless steel tube with a catalyst bed up to 30. 3 centimeters...

  9. Cerium Oxide Coating for Oxidation Reduction

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Award In order to produce power more efficiently and cleanly, the next generation of power plant boilers, turbines, solid oxide fuel cells (SOFCs) and other essential...

  10. Phase transformation of ZnMoO{sub 4} by localized thermal spike

    SciTech Connect (OSTI)

    Agarwal, D. C.; Avasthi, D. K.; Kabiraj, D. [Inter-University Accelerator Center, Aruna Asaf Ali Marg, New Delhi 110067 (India); Varma, S. [Institute of Physics, Sachivalaya Marg, Bhubaneswar 751005 (India); Kremer, Felipe; Ridgway, M. C. [Australian National University, Canberra ACT 0200 (Australia)

    2014-04-28T23:59:59.000Z

    We show that ZnMoO{sub 4} remains in stable phase under thermal annealing up to 1000?°C, whereas it decomposes to ZnO and MoO{sub 3} under transient thermal spike induced by 100?MeV Ag irradiation. The transformation is evidenced by X-ray diffraction (XRD), Raman spectroscopy, and X-ray photoelectron spectroscopy (XPS). Thin films of ZnMoO{sub 4} were synthesized by thermal evaporation and subsequent annealing in oxygen ambient at 600?°C for 4?h. XRD results show that as the irradiation fluence increases, the peak related to ZnMoO{sub 4} decreases gradually and eventually disappear, whereas peaks related to ZnO grow steadily up to fluence of 3?×?10{sup 12} ions/cm{sup 2} and thereafter remain stable till highest fluence. This indicates that polycrystalline ZnMoO{sub 4} film has transformed to polycrystalline ZnO thin film. The Raman lines related to ZnMoO{sub 4} are observed to have disappeared with increasing irradiation fluence. XPS results show modification in bonding and depletion of Mo from near surface region after the ion irradiation. Cross-sectional transmission electron microscopy result shows the formation of ion track of diameter 12–16?nm. These results demonstrate that ion beam methods provide the means to control phase splitting of ZnMoO{sub 4} to ZnO and MoO{sub 3} within nanometric dimension along the ion track. The observation of phase splitting and Mo loss are explained in the framework of ion beam induced thermal spike formalism.

  11. Magnesium cage shows promise for carbon capture http://www.rsc.org/chemistryworld/News/2009/December/01120901.asp[12/2/2009 12:27:18 PM

    E-Print Network [OSTI]

    Yaghi, Omar M.

    Magnesium cage shows promise for carbon capture http://www.rsc.org/chemistryworld/News/2009 Links Tools Magnesium cage shows promise for carbon capture 01 December 2009 US chemists have shown and selectively capture carbon dioxide from a mixture of gases and subsequently release it using little energy

  12. JOURNAL DE PHYSIQUE Colloque C1, suppliment au no 4, Tome 38, Avril 1977, page C1-207 KINETICS OF THE CATION REDISTRIBUTION IN MAGNESIUM FERRITES

    E-Print Network [OSTI]

    Boyer, Edmond

    OF THE CATION REDISTRIBUTION IN MAGNESIUM FERRITES V. A. M. BRABERS and J. KLERK Department of Physics distribution des ions Mg2+et Fe3+sur les sites tetrakdriques et octakdriquesde ferrites de magnesium est Ctudi octahedral and tetrahedral sites in Mg ferrites has been studiedwith dilatometricmeasurements

  13. Magnesium deficiency and type of protein during gestation and lactation in rats

    E-Print Network [OSTI]

    Holmes, Kathryn Ellen Hughes

    1988-01-01T23:59:59.000Z

    to the irregular schedule of cage clean1ng. 13 Animals were observed for physical signs of magnesium deficiency. Upon parturition the stainless steel grids were removed from the cages, and dams and pups were maintained on the wood-chip bedding... in a machine designed for this pur- pose. Clean cages with fresh wood-chip bedding were provided as needed, and clean feeders were provided weekly. All other instruments and glassware used in the study were acid-washed in 10% nitric acid or soaked...

  14. Water and Methanol Adsorption on MgO(100)/Mo(100) Studied by Electron Spectroscopies and Thermal Programmed Desorption

    E-Print Network [OSTI]

    Goodman, Wayne

    Water and Methanol Adsorption on MgO(100)/Mo(100) Studied by Electron Spectroscopies and Thermal, 2000 The adsorption of methanol (CH3OH) and water (D2O) on the MgO(100)/Mo(100) surface at 100 K has covered MgO(100)/Mo(100) surface. On the other hand, the formation of a methanol multilayer desorption

  15. Influence of Co/Mo Ratio on Synthesis of Single-Walled Carbon Nanotubes from Carbon Monoxide

    E-Print Network [OSTI]

    Maruyama, Shigeo

    Influence of Co/Mo Ratio on Synthesis of Single-Walled Carbon Nanotubes from Carbon Monoxide, Bunkyo-ku, Tokyo 113-8656 Co and Mo are often used as catalysts for the catalytic chemical vapor in synthesizing random, vertical and parallel aligned SWNTs on Co and Mo dip-coated quartz substrates from carbon

  16. Nano-Scale Fission Product Phases in an Irradiated U-7Mo Alloy Nuclear Fuel

    SciTech Connect (OSTI)

    Dennis Keiser, Jr.; Brandon Miller; James Madden; Jan-Fong Jue; Jian Gan

    2014-09-01T23:59:59.000Z

    Irradiated nuclear fuel is a very difficult material to characterize. Due to the large radiation fields associated with these materials, they are hard to handle and typically have to be contained in large hot cells. Even the equipment used for performing characterization is housed in hot cells or shielded glove boxes. The result is not only a limitation in the techniques that can be employed for characterization, but also a limitation in the size of features that can be resolved The most standard characterization techniques include light optical metallography (WM), scanning electron microscopy (SEM), and electron probe microanalysis (EPMA). These techniques are applied to samples that are typically prepared using grinding and polishing approaches that will always generate some mechanical damage on the sample surface. As a result, when performing SEM analysis, for example, the analysis is limited by the quality of the sample surface that can be prepared. However, a new approach for characterizing irradiated nuclear fuel has recently been developed at the Idaho National Laboratory (INL) in Idaho Falls, Idaho. It allows for a dramatic improvement in the quality of characterization that can be performed when using an instrument like an SEM. This new approach uses a dual-beam scanning microscope, where one of the beams isa focused ion beam (FIB), which can be used to generate specimens of irradiated fuel (-10µm x 10µm) for microstructural characterization, and the other beam is the electron beam of an SEM. One significant benefit of this approach is that the specimen surface being characterized has received much less damage (and smearing) than is caused by the more traditional approaches, which enables the imaging of nanometer­ sized microstructural features in the SEM. The process details are for an irradiated low-enriched uranium (LEU) U-Mo alloy fuel Another type of irradiated fuel that has been characterized using this technique is a mixed oxide fuel.

  17. Effect of dietary magnesium and calcium on blood lipids and minerals in tissues in rats fed a high fat diet

    E-Print Network [OSTI]

    Conboy-Downs, Jean

    1991-01-01T23:59:59.000Z

    EFFECT OF DIETARY MAGNESIUM AND CALCIUM ON BLOOD LIPIDS AND MINERALS ZN TISSUES IN BATS FED A HIGH FAT DIET A Thesis by JEAN CONBOY-DONNS Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE May 1991 Major Subject: Nutrition EFFECT OF DIETARY MAGNESIUM AND CALCIUM ON BLOOD LIPZDS AND MZNERALS ZN TISSUES IN RATS FED A BIGS FAT DIET A Thesis by JEAN CONBOY-DOWNS Approved as to style...

  18. The determination of the bioavailability and the site of absorption in lambs fed different sources of magnesium

    E-Print Network [OSTI]

    Hurley, Leigh Anne

    1988-01-01T23:59:59.000Z

    followed by a 3-d total collection of feces and urine. Fecal excretions and apparent absorptions of Mg increased (P&. 05) 43 and 320'4 respectively, as Ng intakes increased (P&. 05) from . 96 to 1. 85 g/d intake. Apparent Ng absorptions were . 17, . 51...'% with and average of . 10% in order to meet daily Hg requirements . $0 Magnesium Losses Magnesium is lost from the body by three main zoutes: milk, urine and feces (Allczoft and Burns, 1968). The main route of Ng excretion is by way of the feces (Todd, 1976...

  19. Effect of dietary magnesium and calcium on blood lipids and minerals in tissues in rats fed a high fat diet 

    E-Print Network [OSTI]

    Conboy-Downs, Jean

    1991-01-01T23:59:59.000Z

    EFFECT OF DIETARY MAGNESIUM AND CALCIUM ON BLOOD LIPIDS AND MINERALS ZN TISSUES IN BATS FED A HIGH FAT DIET A Thesis by JEAN CONBOY-DONNS Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE May 1991 Major Subject: Nutrition EFFECT OF DIETARY MAGNESIUM AND CALCIUM ON BLOOD LIPZDS AND MZNERALS ZN TISSUES IN RATS FED A BIGS FAT DIET A Thesis by JEAN CONBOY-DOWNS Approved as to style...

  20. The effects of a marginal intake of magnesium with soy protein concentrate on growth, gestation, and lactation in the rat 

    E-Print Network [OSTI]

    McLaughlin, Cynthia Anne

    1986-01-01T23:59:59.000Z

    THE EFFECTS OF A MARGINAL INTAKE OF MAGNESIUM WITH SOY PROTEIN CONCENTRATE ON GROWTH, GESTATION, AND LACTATION IN THE RAT A Thesis by CYNTHIA ANNE MCLAUGHLIN Submitted to the Graduate College of Texas A&M University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE May 19B6 Major Subject: Nutrrtion THE EFFECTS OF A MARGINAL INTAKE OF MAGNESIUM WITH SOY PROTEIN CONCENTRATE ON GROWTH, GESTATION, AND LACTATION IN THE RAT A Thesis by CYNTHIA ANNE MCLAUGHLIN Approved...

  1. Magnesium behavior and structural defects in Mg+ ion implanted silicon carbide

    SciTech Connect (OSTI)

    Jiang, Weilin; Jung, Hee Joon; Kovarik, Libor; Wang, Zhaoying; Roosendaal, Timothy J.; Zhu, Zihua; Edwards, Danny J.; Hu, Shenyang Y.; Henager, Charles H.; Kurtz, Richard J.; Wang, Yongqiang

    2015-01-01T23:59:59.000Z

    As a candidate material for fusion reactor applications, silicon carbide (SiC) undergoes transmutation reactions under high-energy neutron irradiation with magnesium as the major metallic transmutant; the others include aluminum, beryllium and phosphorus in addition to helium and hydrogen gaseous species. The impact of these transmutants on SiC structural stability is currently unknown. This study uses ion implantation to introduce Mg into SiC. Multiaxial ion-channeling analysis of the as-produced damage state suggests that there are preferred Si <100> interstitial splits. The microstructure of the annealed sample was examined using high-resolution scanning transmission electron microscopy. The results show a high concentration of likely non-faulted tetrahedral voids and possible stacking fault tetrahedra near the damage peak. In addition to lattice distortion, dislocations and intrinsic and extrinsic stacking faults are also observed. Magnesium in 3C-SiC prefers to substitute for Si and it forms precipitates of cubic Mg2Si and tetragonal MgC2. The diffusion coefficient of Mg in 3C-SiC single crystal at 1573 K has been determined to be 3.8±0.4×10e-19 m2/sec.

  2. Manufacture of gradient micro-structures of magnesium alloys using two stage extrusion dies

    SciTech Connect (OSTI)

    Hwang, Yeong-Maw; Huang, Tze-Hui [Department of Mechanical and Electro-Mechanical Engineering, National Sun Yat-Sen University, No. 70, Lien-Hai Rd., Kaohsiung, 804, Taiwan (China); Alexandrov, Sergei [Institute for Problems in Mechanics, Russian Academy of Sciences, Moscow (Russian Federation); Naimark, Oleg Borisovich [Institute of Continuous Media Mechanics, Russian Academy of Sciences, Perm (Russian Federation); Jeng, Yeau-Ren [Department of Mechanical Engineering and Advanced Institute of Manufacturing with High-tech Innovations, National Chung Cheng University, Ming-Hsiung, Chia-Yi 621, Taiwan (China)

    2013-12-16T23:59:59.000Z

    This paper aims to manufacture magnesium alloy metals with gradient micro-structures using hot extrusion process. The extrusion die was designed to have a straight channel part combined with a conical part. Materials pushed through this specially-designed die generate a non-uniform velocity distribution at cross sections inside the die and result in different strain and strain rate distributions. Accordingly, a gradient microstructure product can be obtained. Using the finite element analysis, the forming temperature, effective strain, and effective strain rate distributions at the die exit were firstly discussed for various inclination angles in the conical die. Then, hot extrusion experiments with a two stage die were conducted to obtain magnesium alloy products with gradient micro-structures. The effects of the inclination angle on the grain size distribution at cross sections of the products were also discussed. Using a die of an inclination angle of 15°, gradient micro-structures of the grain size decreasing gradually from 17 ?m at the center to 4 ?m at the edge of product were achieved.

  3. THE MICROSTRUCTURAL LOCATION OF THE INTERGRANULAR METAL OXIDE PHASE IN A ZINC OXIDE VARISTOR

    E-Print Network [OSTI]

    Clarke, D. E

    2011-01-01T23:59:59.000Z

    OXIDE PHASE IN A ZINC OXIDE VARISTOR MICROSI'RUCTIJRALMETAL OXIDE PHASE IN A ZINC OXIDE VARISTOR David R. Clarke

  4. Investigation of the optical properties of MoS{sub 2} thin films using spectroscopic ellipsometry

    SciTech Connect (OSTI)

    Yim, Chanyoung; O'Brien, Maria; Winters, Sinéad [School of Chemistry, Trinity College Dublin, Dublin 2 (Ireland); Centre for Research on Adaptive Nanostructures and Nanodevices (CRANN), Trinity College Dublin, Dublin 2 (Ireland); McEvoy, Niall [Centre for Research on Adaptive Nanostructures and Nanodevices (CRANN), Trinity College Dublin, Dublin 2 (Ireland); Mirza, Inam; Lunney, James G. [Centre for Research on Adaptive Nanostructures and Nanodevices (CRANN), Trinity College Dublin, Dublin 2 (Ireland); School of Physics, Trinity College Dublin, Dublin 2 (Ireland); Duesberg, Georg S., E-mail: duesberg@tcd.ie [School of Chemistry, Trinity College Dublin, Dublin 2 (Ireland); Centre for Research on Adaptive Nanostructures and Nanodevices (CRANN), Trinity College Dublin, Dublin 2 (Ireland); Advanced Materials and BioEngineering Research (AMBER) Centre, Trinity College Dublin, Dublin 2 (Ireland)

    2014-03-10T23:59:59.000Z

    Spectroscopic ellipsometry (SE) characterization of layered transition metal dichalcogenide (TMD) thin films grown by vapor phase sulfurization is reported. By developing an optical dispersion model, the extinction coefficient and refractive index, as well as the thickness of molybdenum disulfide (MoS{sub 2}) films, were extracted. In addition, the optical band gap was obtained from SE and showed a clear dependence on the MoS{sub 2} film thickness, with thinner films having a larger band gap energy. These results are consistent with theory and observations made on MoS{sub 2} flakes prepared by exfoliation, showing the viability of vapor phase derived TMDs for optical applications.

  5. High damage-resistant Mo mirror for high-power TEA CO/sub 2/ laser systems

    SciTech Connect (OSTI)

    Ichikawa, Y.; Yoshida, K.; Tsunawaki, Y.; Yamanaka, M.; Yamanaka, T.; Yamanaka, C.; Okamoto, H.; Matsusue, N.; Kitajima, K.

    1987-09-01T23:59:59.000Z

    A high-purity molybdenum (Mo) mirror was developed by an electron-beam melting method (e.b.m. Mo mirror). For high-power TEA CO/sub 2/ laser, the e.b.m. Mo mirror has two to four times higher surface damage threshold than that of an Au-coated glass mirror and three times longer lifetime than that of a powder metallurgy Mo mirror (p.m. Mo mirror) when laser energy density lower than 60 J/cm/sup 2/ was irradiated with a 0.5-pps repetition rate. It was found that the difference between the e.b.m. Mo mirror and the p.m. Mo mirror at the laser-damage threshold was due to the five surface without voids and the small amount of impurities.

  6. Magnesium aluminate (MgAl2O4) spinel produced via self-heat-sustained (SHS) technique

    E-Print Network [OSTI]

    Azad, Abdul-Majeed

    , conventional solid-state-reaction (SSR), sol-gel, spray drying (atomization) and organic gel-assisted citrateMagnesium aluminate (MgAl2O4) spinel produced via self-heat-sustained (SHS) technique Lim Rooi Pinga,1 , Abdul-Majeed Azadb, *, Teng Wan Dunga a Ceramics Technology Center, SIRIM Berhad, 1 Persiaran

  7. A Comparison of Magnesium and Beryllium Acceptors in GaN Grown by rf-Plasma Assisted Molecular Beam Epitaxy

    E-Print Network [OSTI]

    Myers, Tom

    as a function of substrate temperature and dopant flux for Ga-polarity and N-polarity GaN. Incorporation GaN templates on (0001) sapphire substrates. The doped layers were grown at a rate of 0.25 µmA Comparison of Magnesium and Beryllium Acceptors in GaN Grown by rf-Plasma Assisted Molecular Beam

  8. Aboveground test of an advanced Li$_2$MoO$_4$ scintillating bolometer to search for neutrinoless double beta decay of $^{100}$Mo

    E-Print Network [OSTI]

    T. B. Bekker; N. Coron; F. A. Danevich; V. Ya. Degoda; A. Giuliani; V. D. Grigorieva; N. V. Ivannikova; M. Mancuso; P. de Marcillac; I. M. Moroz; C. Nones; E. Olivieri; G. Pessina; D. V. Poda; V. N. Shlegel; V. I. Tretyak; M. Velazquez

    2014-12-17T23:59:59.000Z

    Large lithium molybdate (Li$_2$MoO$_4$) crystal boules were produced by using the low thermal gradient Czochralski growth technique from deeply purified molybdenum. A small sample from one of the boules was preliminary characterized in terms of X-ray-induced and thermally-excited luminescence. A large cylindrical crystalline element (with a size of $\\oslash 40\\times40$ mm) was used to fabricate a scintillating bolometer, which was operated aboveground at $\\sim 15$ mK by using a pulse-tube cryostat housing a high-power dilution refrigerator. The excellent detector performance in terms of energy resolution and $\\alpha$ background suppression along with preliminary positive indications on the radiopurity of this material show the potentiality of Li$_2$MoO$_4$ scintillating bolometers for low-counting experiment to search for neutrinoless double beta decay of $^{100}$Mo.

  9. Aboveground test of an advanced Li$_2$MoO$_4$ scintillating bolometer to search for neutrinoless double beta decay of $^{100}$Mo

    E-Print Network [OSTI]

    Bekker, T B; Danevich, F A; Degoda, V Ya; Giuliani, A; Grigorieva, V D; Ivannikova, N V; Mancuso, M; de Marcillac, P; Moroz, I M; Nones, C; Olivieri, E; Pessina, G; Poda, D V; Shlegel, V N; Tretyak, V I; Velazquez, M

    2014-01-01T23:59:59.000Z

    Large lithium molybdate (Li$_2$MoO$_4$) crystal boules were produced by using the low thermal gradient Czochralski growth technique from deeply purified molybdenum. A small sample from one of the boules was preliminary characterized in terms of X-ray-induced and thermally-excited luminescence. A large cylindrical crystalline element (with a size of $\\oslash 40\\times40$ mm) was used to fabricate a scintillating bolometer, which was operated aboveground at $\\sim 15$ mK by using a pulse-tube cryostat housing a high-power dilution refrigerator. The excellent detector performance in terms of energy resolution and $\\alpha$ background suppression along with preliminary positive indications on the radiopurity of this material show the potentiality of Li$_2$MoO$_4$ scintillating bolometers for low-counting experiment to search for neutrinoless double beta decay of $^{100}$Mo.

  10. Comparison of the Catalytic Oxidation Reaction on Graphene Oxide and Reduced Graphene Oxide

    E-Print Network [OSTI]

    Kim, Sehun

    Comparison of the Catalytic Oxidation Reaction on Graphene Oxide and Reduced Graphene Oxide Laboratory (PAL), Pohang 790-784, Republic of Korea ABSTRACT: The capacities of graphene oxide (GO) and reduced graphene oxide (rGO) films grown on silicon substrate to cause the aniline to azobenzene oxidation

  11. Magnesium Projects

    Broader source: Energy.gov (indexed) [DOE]

    cyberinfrastructure projects and will be augmented by original research in Computer Science and Software Engineering towards the creation of large, distributed, autonomic and...

  12. Atomistic simulation of the electronic states of adatoms in monolayer MoS{sub 2}

    SciTech Connect (OSTI)

    Chang, Jiwon; Larentis, Stefano; Tutuc, Emanuel; Register, Leonard F.; Banerjee, Sanjay K. [Microelectronics Research Center, The University of Texas at Austin, Austin, Texas 78758 (United States)

    2014-04-07T23:59:59.000Z

    Using an ab initio density functional theory based electronic structure method, we study the effects of adatoms on the electronic properties of monolayer transition metal dichalcogenide Molybdenum-disulfide (MoS{sub 2}). We consider the 1st (Li, Na, K) and 7th (F, Cl, Br) column atoms and metals (Sc, Ti, Ta, Mo, Pd, Pt, Ag, Au). Three high symmetry sites for the adatom on the surface of monolayer MoS{sub 2} are examined as starting points to search for the most energetically stable configuration for each adatom-monolayer MoS{sub 2} system, as well as the type of associated bonding. For the most stable adatom positions, we characterize the emergence of adatom-induced electronic states including any dopant states.

  13. Substrate interactions with suspended and supported monolayer MoS?: Angle-resolved photoemission spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jin, Wencan; Sadowski, Jerzy T.; Yeh, Po-Chun; Zaki, Nader; Zhang, Datong; Liou, Jonathan T.; Dadap, Jerry I.; Herman, Irving P.; Osgood, Jr., Richard M.; Sutter, Peter; et al

    2015-03-01T23:59:59.000Z

    We report the directly measured electronic structure of exfoliated monolayer molybdenum disulfide (MoS?) using micrometer-scale angle-resolved photoemission spectroscopy. Measurements of both suspended and supported monolayer MoS? elucidate the effects of interaction with a substrate. A suggested relaxation of the in-plane lattice constant is found for both suspended and supported monolayer MoS? crystals. For suspended MoS?, a careful investigation of the measured uppermost valence band gives an effective mass at ? and ? of 2.00m? and 0.43m?, respectively. We also measure an increase in the band linewidth from the midpoint of ?? to the vicinity of ? and briefly discuss itsmore »possible origin.« less

  14. Substrate interactions with suspended and supported monolayer MoS?: Angle-resolved photoemission spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jin, Wencan [Columbia Univ., New York, NY (United States); Sadowski, Jerzy T. [Brookhaven National Lab. (BNL), Upton, NY (United States); Yeh, Po-Chun [Columbia Univ., New York, NY (United States); Zaki, Nader [Columbia Univ., New York, NY (United States); Zhang, Datong [Columbia Univ., New York, NY (United States); Liou, Jonathan T. [Columbia Univ., New York, NY (United States); Dadap, Jerry I. [Columbia Univ., New York, NY (United States); Herman, Irving P. [Columbia Univ., New York, NY (United States); Osgood, Jr., Richard M. [Columbia Univ., New York, NY (United States); Sutter, Peter [Brookhaven National Lab. (BNL), Upton, NY (United States); Barinov, Alexey [Elettra Sincrotrone Trieste, Basovizza, Trieste (Italy); Yablonskikh, Mikhail [Elettra Sincrotrone Trieste, Basovizza, Trieste (Italy)

    2015-03-01T23:59:59.000Z

    We report the directly measured electronic structure of exfoliated monolayer molybdenum disulfide (MoS?) using micrometer-scale angle-resolved photoemission spectroscopy. Measurements of both suspended and supported monolayer MoS? elucidate the effects of interaction with a substrate. A suggested relaxation of the in-plane lattice constant is found for both suspended and supported monolayer MoS? crystals. For suspended MoS?, a careful investigation of the measured uppermost valence band gives an effective mass at ? and ? of 2.00m? and 0.43m?, respectively. We also measure an increase in the band linewidth from the midpoint of ?? to the vicinity of ? and briefly discuss its possible origin.

  15. Intrinsic Electronic Transport Properties of High-Quality Monolayer and Bilayer MoS[subscript 2

    E-Print Network [OSTI]

    Baugher, Britton W. H.

    We report electronic transport measurements of devices based on monolayers and bilayers of the transition-metal dichalcogenide MoS[subscript 2]. Through a combination of in situ vacuum annealing and electrostatic gating ...

  16. MO"BIUS ENERGIES FOR KNOTS AND LINKS, SURFACES AND SUBMANIFOLDS

    E-Print Network [OSTI]

    Kusner, Robert B.

    MO"BIUS ENERGIES FOR KNOTS AND LINKS, SURFACES AND SUBMANIFOLDS energies, especially those which are invariant under M"obius transforma- tions of space. We describe computer experiments with such energies, and discuss ways of extending these to energies

  17. Isothermal activation of Mo2O5 ZSM-5 precursors during

    E-Print Network [OSTI]

    Iglesia, Enrique

    Isothermal activation of Mo2O5 21 ­ZSM-5 precursors during methane reactions: effects of reaction to petrochemicals and liquid fuels and chemicals remains a formidable technological challenge.1 Exchanged cations

  18. AB INITIO Modeling of Thermomechanical Properties of Mo-Based Alloys for Fossil Energy Conversion

    SciTech Connect (OSTI)

    Ching, Wai-Yim

    2013-12-31T23:59:59.000Z

    In this final scientific/technical report covering the period of 3.5 years started on July 1, 2011, we report the accomplishments on the study of thermo-mechanical properties of Mo-based intermetallic compounds under NETL support. These include computational method development, physical properties investigation of Mo-based compounds and alloys. The main focus is on the mechanical and thermo mechanical properties at high temperature since these are the most crucial properties for their potential applications. In particular, recent development of applying ab initio molecular dynamic (AIMD) simulations to the T1 (Mo{sub 5}Si{sub 3}) and T2 (Mo{sub 5}SiB{sub 2}) phases are highlighted for alloy design in further improving their properties.

  19. Electronic structure and conductivity of nanocomposite metal (Au,Ag,Cu,Mo)-containing amorphous carbon films

    E-Print Network [OSTI]

    Endrino, Jose L.

    2010-01-01T23:59:59.000Z

    dual-cathode arc deposition (PDC-FCVA) source containingand metal cathodes [2]. The PDC-FCVA system in combinationCu,Mo) incorporation in a-C by PDC-FCVA. The modification of

  20. Combining sedimentological, trace metal (Mn, Mo) and molecular evidence for reconstructing past water-column

    E-Print Network [OSTI]

    Wehrli, Bernhard

    Combining sedimentological, trace metal (Mn, Mo) and molecular evidence for reconstructing past online 22 June 2013 Abstract Here, we present sedimentological, trace metal, and molecular evidence underscores the value of combining sedimentological, geochemical, and microbiological approaches

  1. Enhanced absorption of monolayer MoS{sub 2} with resonant back reflector

    SciTech Connect (OSTI)

    Liu, Jiang-Tao, E-mail: jtliu@semi.ac.cn; Liu, Nian-Hua [Nanoscale Science and Technology Laboratory, Institute for Advanced Study, Nanchang University, Nanchang 330031 (China); Department of Physics, Nanchang University, Nanchang 330031 (China); Wang, Tong-Biao [Department of Physics, Nanchang University, Nanchang 330031 (China); Li, Xiao-Jing [College of Physics and Energy, Fujian Normal University, Fuzhou 350007 (China)

    2014-05-21T23:59:59.000Z

    The optical absorption of monolayer MoS{sub 2} on top of one-dimensional photonic crystal (1DPC) or metal films with spacer layers is theoretically investigated by extracting the permittivity of monolayer MoS{sub 2} from existing experimental results [K. F. Mak et al., Phys. Rev. Lett. 105, 136805 (2010)]. The absorption of graphene with 1DPC across a broad spectral range is substantially enhanced because of the photonic localization at the optical micro-cavity on top of the 1DPC or metal films. The absorption of monolayer MoS{sub 2} can be tuned by varying either the distance between the monolayer MoS{sub 2} and the back reflector or the thickness of the cover layers.

  2. Catalytic hydrocarbon reactions over supported metal oxides. Final report, August 1, 1986--July 31, 1995

    SciTech Connect (OSTI)

    Ekerdt, J.G.

    1995-10-20T23:59:59.000Z

    Oxide catalysis plays a central role in hydrocarbon processing and improvements in catalytic activity or selectivity are of great technological importance because these improvements will translate directly into more efficient utilization of hydrocarbon supplies and lower energy consumption in separation processes. An understanding of the relationships between surface structure and catalytic properties is needed to describe and improve oxide catalysts. The approach has been to prepare supported oxides that have a specific structure and oxidation state and then employ these structures in reaction studies. The current research program is focused on studying the fundamental relationships between structure and reactivity for two important reactions that are present in many oxide-catalyzed processes, partial oxidation and carbon-carbon bond formation. During the course of these studies the author has: (1) developed methods to form and stabilize various Mo and W oxide structures on silica; (2) studied C-H abstraction reactions over the fully oxidized cations; (3) studied C-C bond coupling by metathesis and reductive coupling of aldehydes and ketones over reduced cation structures; and (4) initiated a study of hydrogenation and hydrogenolysis over reduced cation structures.

  3. Diffusional Interactions between U-Mo and Zr at 650°C as a Function of Time

    SciTech Connect (OSTI)

    Y. Park; Y. H. Sohn; D. D. Keiser, Jr.

    2015-01-01T23:59:59.000Z

    Development of monolithic U-Mo alloy fuel (typically U-10wt.%Mo) for the Reduced Enrichment for Research and Test Reactors (RERTR) program requires a use of Zr diffusion barrier to eliminate the diffusional interaction between the fuel alloy and Al-alloy cladding. The application of Zr barrier to the U-Mo fuel requires co-rolling process that utilizes a soaking temperature of 650°C, which represents the highest temperature the fuel system is exposed to during both fuel manufacturing and reactor application. Therefore, in this study, development of phase constituents, microstructure and diffusion kinetics of U-10wt.%Mo and Zr was examined using solid-to-solid diffusion couples annealed at 650°C for 240, 480 and 720 hours. Diffusional interactions were analyzed by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Within the diffusion zone, a single-phase layer of ß-Zr was observed along with a discontinuous layer of Mo2Zr at the interface between the terminal ?-U(Mo) alloy and ß-Zr. In the vicinity of Mo2Zr phase, islands of ß-U and a-Zr phases were also found. In addition, accicular a-Zr phases were observed within the ?-U(Mo). Growth rate of this diffuaional interaction layer was determined to be 8.76 x 10-15 m2/sec, however with an assumption of certain incubation period. Consistency in these observation along with concentration profiles and diffusion paths are presented and discussed with respect to the diffusion couple that was furnace-cooled, annealed at 700°C in our previous study, and isothermal ternary phase diagram at 700°C.

  4. Oxidation Resistant Graphite Studies

    SciTech Connect (OSTI)

    W. Windes; R. Smith

    2014-07-01T23:59:59.000Z

    The Very High Temperature Reactor (VHTR) Graphite Research and Development Program is investigating doped nuclear graphite grades exhibiting oxidation resistance. During a oxygen ingress accident the oxidation rates of the high temperature graphite core region would be extremely high resulting in significant structural damage to the core. Reducing the oxidation rate of the graphite core material would reduce the structural effects and keep the core integrity intact during any air-ingress accident. Oxidation testing of graphite doped with oxidation resistant material is being conducted to determine the extent of oxidation rate reduction. Nuclear grade graphite doped with varying levels of Boron-Carbide (B4C) was oxidized in air at nominal 740°C at 10/90% (air/He) and 100% air. The oxidation rates of the boronated and unboronated graphite grade were compared. With increasing boron-carbide content (up to 6 vol%) the oxidation rate was observed to have a 20 fold reduction from unboronated graphite. Visual inspection and uniformity of oxidation across the surface of the specimens were conducted. Future work to determine the remaining mechanical strength as well as graphite grades with SiC doped material are discussed.

  5. Effects of soil treatments supplemented with two rates of magnesium sulfate on the availability of soil nutrients and on the yield and chemical composition of coastal Bermuda grass 

    E-Print Network [OSTI]

    Evatt, Nathan S

    1951-01-01T23:59:59.000Z

    'ZATZ ON THE AVAILABILITY OF SOIL NUTRIENTS AND ON TH YIELD AND CHENICAL COMPOSITICN GF CO. iSTAL BERNUDA GHASS INTRODUCTION It is known that magnesium is one of' the elements essential for plant growth; however much is to be learned concerning its specific functions... within the plant, Host Texas soils are not deficient, in magnesium (23). Magnesium is reported to be a carrier of the phos- phorus used by the plant. It is entirely possible that the failure to obtain crops of higher phosphorus content upon...

  6. High reflectance and low stress Mo2C/Be multilayers

    DOE Patents [OSTI]

    Bajt, Sasa (Livermore, CA); Barbee, Jr., Troy W. (Palo Alto, CA)

    2001-01-01T23:59:59.000Z

    A material for extreme ultraviolet (EUV) multilayers that will reflect at about 11.3 nm, have a high reflectance, low stress, and high thermal and radiation stability. The material consists of alternating layers of Mo.sub.2 C and Be deposited by DC magnetron sputtering on a substrate, such as silicon. In one example a Mo.sub.2 C/Be multilayer gave 65.2% reflectance at 11.25 nm measured at 5 degrees off normal incidence angle, and consisted of 70 bilayers with a deposition period of 5.78 nm, and was deposited at 0.83 mTorr argon (Ar) sputtering pressure, with the first and last layers being Be. The stress of the multilayer is tensile and only +88 MPa, compared to +330 MPa of a Mo/Be multilayers of the same thickness. The Mo.sub.2 C/Be multilayer was capped with carbon which produced an increase in reflectivity of about 7% over a similar multilayer with no carbon capping material, thus raising the reflectivity from 58.3% to over 65%. The multilayers were formed using either Mo.sub.2 C or Be as the first and last layers, and initial testing has shown the formation of beryllium carbide at the interfaces between the layers which both stabilizes and has a smoothing effect, and appear to be smoother than the interfaces in Mo/Be multilayers.

  7. Effects of thermal treatment on the co-rolled U-Mo fuel foils

    SciTech Connect (OSTI)

    Dennis D. Keiser, Jr.; Tammy L. Trowbridge; Cynthia R. Breckenridge; Brady L. Mackowiak; Glenn A. Moore; Barry H. Rabin; Mitchell K. Meyer

    2014-11-01T23:59:59.000Z

    A monolithic fuel type is being developed to convert US high performance research and test reactors such as Advanced Test Reactor (ATR) at Idaho National Laboratory from highly enriched uranium (HEU) to low-enriched uranium (LEU). The interaction between the cladding and the U-Mo fuel meat during fuel fabrication and irradiation is known to have negative impacts on fuel performance, such as mechanical integrity and dimensional stability. In order to eliminate/minimize the direct interaction between cladding and fuel meat, a thin zirconium diffusion barrier was introduced between the cladding and U-Mo fuel meat through a co-rolling process. A complex interface between the zirconium and U-Mo was developed during the co-rolling process. A predictable interface between zirconium and U-Mo is critical to achieve good fuel performance since the interfaces can be the weakest link in the monolithic fuel system. A post co-rolling annealing treatment is expected to create a well-controlled interface between zirconium and U-Mo. A systematic study utilizing post co-rolling annealing treatment has been carried out. Based on microscopy results, the impacts of the annealing treatment on the interface between zirconium and U-Mo will be presented and an optima annealing treatment schedule will be suggested. The effects of the annealing treatment on the fuel performance will also be discussed.

  8. Photoluminescent BaMoO{sub 4} nanopowders prepared by complex polymerization method (CPM)

    SciTech Connect (OSTI)

    Azevedo Marques, Ana Paula de [Laboratorio de Analise Termica e Materiais, Departamento de Quimica, Universidade Federal do Rio Grande do Norte, 59072-970 Natal, RN (Brazil)]. E-mail: apamarques@liec.ufscar.br; Melo, Dulce M.A. de [Laboratorio de Analise Termica e Materiais, Departamento de Quimica, Universidade Federal do Rio Grande do Norte, 59072-970 Natal, RN (Brazil); Paskocimas, Carlos A. [Departamento de Engenharia Mecanica, Universidade Federal do Rio Grande do Norte, 59072-970 Natal, RN (Brazil); Pizani, Paulo S. [Laboratorio de Semicondutores, Departamento de Fisica, Universidade Federal de Sao Carlos, 13565-905 Sao Carlos, SP (Brazil); Joya, Miryam R. [Laboratorio de Semicondutores, Departamento de Fisica, Universidade Federal de Sao Carlos, 13565-905 Sao Carlos, SP (Brazil); Leite, Edson R. [Laboratorio Interdisciplinar de Eletroquimica e Ceramica, CMDMC, Departamento de Quimica, Universidade Federal de Sao Carlos 13565-905, Sao Carlos, SP (Brazil); Longo, Elson [CMDMC, LIEC, Instituto de Quimica, Universidade Estadual Paulista, 14801-907 Araraquara, SP (Brazil)

    2006-03-15T23:59:59.000Z

    The BaMoO{sub 4} nanopowders were prepared by the Complex Polymerization Method (CPM). The structure properties of the BaMoO{sub 4} powders were characterized by FTIR transmittance spectra, X-ray diffraction (XRD), Raman spectra, photoluminescence spectra (PL) and high-resolution scanning electron microscopy (HR-SEM). The XRD, FTIR and Raman data showed that BaMoO{sub 4} at 300 deg. C was disordered. At 400 deg. C and higher temperature, BaMoO{sub 4} crystalline scheelite-type phases could be identified, without the presence of additional phases, according to the XRD, FTIR and Raman data. The calculated average crystallite sizes, calculated by XRD, around 40 nm, showed the tendency to increase with the temperature. The crystallite sizes, obtained by HR-SEM, were around of 40-50 nm. The sample that presented the highest intensity of the red emission band was the one heat treated at 400 deg. C for 2 h, and the sample that displayed the highest intensity of the green emission band was the one heat treated at 700 deg. C for 2 h. The CPM was shown to be a low cost route for the production of BaMoO{sub 4} nanopowders, with the advantages of lower temperature, smaller time and reduced cost. The optical properties observed for BaMoO{sub 4} nanopowders suggested that this material is a highly promising candidate for photoluminescent applications.

  9. Food and Drug Administration process validation activities to support 99Mo production at Sandia National Laboratories

    SciTech Connect (OSTI)

    McDonald, M.J.; Bourcier, S.C.; Talley, D.G.

    1997-07-01T23:59:59.000Z

    Prior to 1989 {sup 99}Mo was produced in the US by a single supplier, Cintichem Inc., Tuxedo, NY. Because of problems associated with operating its facility, in 1989 Cintichem elected to decommission the facility rather than incur the costs for repair. The demise of the {sup 99}Mo capability at Cintichem left the US totally reliant upon a single foreign source, Nordion International, located in Ottawa Canada. In 1992 the DOE purchased the Cintichem {sup 99}Mo Production Process and Drug Master File (DMF). In 1994 the DOE funded Sandia National Laboratories (SNL) to produce {sup 99}Mo. Although Cintichem produced {sup 99}Mo and {sup 99m}Tc generators for many years, there was no requirement for process validation which is now required by the Food and Drug Administration (FDA). In addition to the validation requirement, the requirements for current Good manufacturing Practices were codified into law. The purpose of this paper is to describe the process validation being conducted at SNL for the qualification of SNL as a supplier of {sup 99}Mo to US pharmaceutical companies.

  10. Punchless Drawing of Magnesium Alloy Sheet under Cold Condition and its Computation

    SciTech Connect (OSTI)

    Yamashita, Minoru [Center for Advanced Die Engineering and Technology, Gifu University, Yanagido Gifu, 501-1193 (Japan); Hattori, Toshio [Department of Mechanical and Systems Engineering, Gifu University, ditto. (Japan); Sato, Joji [Research Institute for Machinery and Materials, Gifu Prefectural Government, 1288 Oze Seki, 501-3265 (Japan)

    2011-01-17T23:59:59.000Z

    The punchless drawing with Maslennikov's technique was applied to the circular cup drawing of magnesium alloy AZ31B sheet under cold condition. The elastic rubber ring was used instead of the 'hard' punch, where the compressed ring dragged the sheet inward the die cavity. Attainable circumferential strain of the blank was increased by this technique with repetitive drawing operation. Thickness of the rubber pad affected little the attainable strain. The shape appearance became better when a harder rubber was used. The cup forming by single drawing operation was also tested using a small die shoulder radius. The LDR of 1.250 was obtained with the straight cup wall. Further, the computation of the punchless drawing was also conducted for the single drawing operation. The computed deformation pattern was well consistent with the corresponding experimental result.

  11. Mechanistic study of methanol synthesis from CO? and H? on a modified model Mo?S? cluster

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Cheng [Yangzhou Univ., Yangzhou, Jiangsu (China); Liu, Ping [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2015-02-06T23:59:59.000Z

    We report the methanol synthesis from CO? and H? on metal (M = K, Ti, Co, Rh, Ni, and Cu)-modified model Mo?S? catalyst using density functional theory (DFT). The results show that the catalytic behavior of a Mo?S? cluster is changed significantly due to the modifiers, via the electron transfer from M to Mo?S? and therefore the reduction of the Mo cation (ligand effect) and the direct participation of M in the reaction (ensemble effect) to promote some elementary steps. With the most positively charged modifier, the ligand effect in the case of K-Mo?S? is the most obvious among the systems studied; however it cannot compete with the ensemble effect, which plays a dominate role in determining activity via the electrostatic attraction in particular to stabilize the CHxOy species adsorbed at the Mo sites of Mo?S?. In comparison, the ligand effect is weaker and the ensemble effect is more important when the other modifiers are used. In addition, the modifiers also vary the optimal reaction pathway for methanol synthesis on Mo?S?, ranging from the reverse water-gas shift (RWGS) + CO hydrogenation as that of Mo?S? to the formate pathway. Finally, K is able to accelerate the methanol synthesis on Mo?S? the most; while the promotion by Rh is relatively small. Using the modifiers like Ti, Co, Ni, and Cu, the activity of Mo?S? is decreased instead. The relative stability between *HCOO and *HOCO is identified as a descriptor to capture the variation in mechanism and scales well with the estimated activity. Our study not only provides better understanding of the reaction mechanism and actives on the modified Mo?S?, but also predicts some possible candidates, which can be used a promoter to facilitate the CH?OH synthesis on Mo sulfides.

  12. Mechanistic study of methanol synthesis from CO? and H? on a modified model Mo?S? cluster

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Cheng; Liu, Ping

    2015-02-06T23:59:59.000Z

    We report the methanol synthesis from CO? and H? on metal (M = K, Ti, Co, Rh, Ni, and Cu)-modified model Mo?S? catalyst using density functional theory (DFT). The results show that the catalytic behavior of a Mo?S? cluster is changed significantly due to the modifiers, via the electron transfer from M to Mo?S? and therefore the reduction of the Mo cation (ligand effect) and the direct participation of M in the reaction (ensemble effect) to promote some elementary steps. With the most positively charged modifier, the ligand effect in the case of K-Mo?S? is the most obvious among themore »systems studied; however it cannot compete with the ensemble effect, which plays a dominate role in determining activity via the electrostatic attraction in particular to stabilize the CHxOy species adsorbed at the Mo sites of Mo?S?. In comparison, the ligand effect is weaker and the ensemble effect is more important when the other modifiers are used. In addition, the modifiers also vary the optimal reaction pathway for methanol synthesis on Mo?S?, ranging from the reverse water-gas shift (RWGS) + CO hydrogenation as that of Mo?S? to the formate pathway. Finally, K is able to accelerate the methanol synthesis on Mo?S? the most; while the promotion by Rh is relatively small. Using the modifiers like Ti, Co, Ni, and Cu, the activity of Mo?S? is decreased instead. The relative stability between *HCOO and *HOCO is identified as a descriptor to capture the variation in mechanism and scales well with the estimated activity. Our study not only provides better understanding of the reaction mechanism and actives on the modified Mo?S?, but also predicts some possible candidates, which can be used a promoter to facilitate the CH?OH synthesis on Mo sulfides.« less

  13. METAL OXIDE NANOPARTICLES

    SciTech Connect (OSTI)

    FERNANDEZ-GARCIA,M.; RODGRIGUEZ, J.A.

    2007-10-01T23:59:59.000Z

    This chapter covers the fundamental science, synthesis, characterization, physicochemical properties and applications of oxide nanomaterials. Explains fundamental aspects that determine the growth and behavior of these systems, briefly examines synthetic procedures using bottom-up and top-down fabrication technologies, discusses the sophisticated experimental techniques and state of the art theory results used to characterize the physico-chemical properties of oxide solids and describe the current knowledge concerning key oxide materials with important technological applications.

  14. Barium oxide, calcium oxide, magnesia, and alkali oxide free glass

    DOE Patents [OSTI]

    Lu, Peizhen Kathy; Mahapatra, Manoj Kumar

    2013-09-24T23:59:59.000Z

    A glass composition consisting essentially of about 10-45 mole percent of SrO; about 35-75 mole percent SiO.sub.2; one or more compounds from the group of compounds consisting of La.sub.2O.sub.3, Al.sub.2O.sub.3, B.sub.2O.sub.3, and Ni; the La.sub.2O.sub.3 less than about 20 mole percent; the Al.sub.2O.sub.3 less than about 25 mole percent; the B.sub.2O.sub.3 less than about 15 mole percent; and the Ni less than about 5 mole percent. Preferably, the glass is substantially free of barium oxide, calcium oxide, magnesia, and alkali oxide. Preferably, the glass is used as a seal in a solid oxide fuel/electrolyzer cell (SOFC) stack. The SOFC stack comprises a plurality of SOFCs connected by one or more interconnect and manifold materials and sealed by the glass. Preferably, each SOFC comprises an anode, a cathode, and a solid electrolyte.

  15. Mixed oxide solid solutions

    DOE Patents [OSTI]

    Magno, Scott (Dublin, CA); Wang, Ruiping (Fremont, CA); Derouane, Eric (Liverpool, GB)

    2003-01-01T23:59:59.000Z

    The present invention is a mixed oxide solid solution containing a tetravalent and a pentavalent cation that can be used as a support for a metal combustion catalyst. The invention is furthermore a combustion catalyst containing the mixed oxide solid solution and a method of making the mixed oxide solid solution. The tetravalent cation is zirconium(+4), hafnium(+4) or thorium(+4). In one embodiment, the pentavalent cation is tantalum(+5), niobium(+5) or bismuth(+5). Mixed oxide solid solutions of the present invention exhibit enhanced thermal stability, maintaining relatively high surface areas at high temperatures in the presence of water vapor.

  16. Enriched Zn$^{100}$MoO$_4$ scintillating bolometers to search for $0 ? 2?$ decay of $^{100}$Mo with the LUMINEU experiment

    E-Print Network [OSTI]

    A. S. Barabash; D. M. Chernyak; F. A. Danevich; A. Giuliani; I. M. Ivanov; E. P. Makarov; M. Mancuso; S. Marnieros; S. G. Nasonov; C. Nones; E. Olivieri; G. Pessina; D. V. Poda; V. N. Shlegel; M. Tenconi; V. I. Tretyak; Ya. V. Vasiliev; M. Velazquez; V. N. Zhdankov

    2014-07-05T23:59:59.000Z

    The LUMINEU project aims at performing a demonstrator underground experiment searching for the neutrinoless double beta decay of the isotope $^{100}$Mo embedded in zinc molybdate (ZnMoO$_4$) scintillating bolometers. In this context, a zinc molybdate crystal boule enriched in $^{100}$Mo to 99.5\\% with a mass of 171 g was grown for the first time by the low-thermal-gradient Czochralski technique. The production cycle provided a high yield (the crystal boule mass was 84\\% of initial charge) and an acceptable level -- around 4\\% -- of irrecoverable losses of the costy enriched material. Two crystals of 59 g and 63 g, obtained from the enriched boule, were tested aboveground at milli-Kelvin temperature as scintillating bolometers. They showed a high detection performance, equivalent to that of previously developed natural ZnMoO$_4$ detectors. These results pave the way to future sensitive searches based on the LUMINEU technology, capable to approach and explore the inverted hierarchy region of the neutrino mass pattern.

  17. Efficient reversible electrodes for solid oxide electrolyzer cells

    DOE Patents [OSTI]

    Elangovan, S.; Hartvigsen, Joseph J.; Zhao, Feng

    2013-01-15T23:59:59.000Z

    An electrolyzer cell is disclosed which includes a cathode to reduce an oxygen-containing molecule, such as H2O, CO.sub.2, or a combination thereof, to produce an oxygen ion and a fuel molecule, such as H.sub.2, CO, or a combination thereof. An electrolyte is coupled to the cathode to transport the oxygen ion to an anode. The anode is coupled to the electrolyte to receive the oxygen ion and produce oxygen gas therewith. In one embodiment, the anode may be fabricated to include an electron-conducting phase having a perovskite crystalline structure or structure similar thereto. This perovskite may have a chemical formula of substantially (Pr(.sub.1-x)La.sub.x)(z-y)A'.sub.yBO(3-.differential.), wherein 0oxide intermixed with magnesium oxide.

  18. Efficient reversible electrodes for solid oxide electrolyzer cells

    DOE Patents [OSTI]

    Elangovan, Singaravelu (South Jordan, UT); Hartvigsen, Joseph J. (Kaysville, UT)

    2011-07-12T23:59:59.000Z

    An electrolyzer cell is disclosed which includes a cathode to reduce an oxygen-containing molecule, such as H2O, CO2, or a combination thereof, to produce an oxygen ion and a fuel molecule, such as H2, CO, or a combination thereof. An electrolyte is coupled to the cathode to transport the oxygen ion to an anode. The anode is coupled to the electrolyte to receive the oxygen ion and produce oxygen gas therewith. In one embodiment, the anode may be fabricated to include an electron-conducting phase having a perovskite crystalline structure or structure similar thereto. This perovskite may have a chemical formula of substantially (Pr(1-x)Lax)(z-y)A'yBO(3-.differential.), wherein 0.ltoreq.x.ltoreq.0.5, 0.ltoreq.y.ltoreq.0.5, and 0.8.ltoreq.z.ltoreq.1.1. In another embodiment, the cathode includes an electron-conducting phase that contains nickel oxide intermixed with magnesium oxide.

  19. Control of absorption of monolayer MoS$_{2}$ thin-film transistor in one-dimensional defective photonic crystal

    E-Print Network [OSTI]

    Yang, Fang-Fang; Xiao, Wen-bo; Liu, Jiang-Tao; Liu, Nian-Hua

    2014-01-01T23:59:59.000Z

    The light absorption and transmission of monolayer MoS$_{2}$ in a one-dimensional defective photonic crystal (d-1DPC) is theoretically investigated. The study shows that the strong interference effect decreases photon density in particular areas of the microcavity. The d-1DPC can reduce light absorption of monolayer MoS$_{2}$ and enhance light transmission. The impact of monolayer MoS$_{2}$ light absorption on the localization effect of photon is investigated when monolayer MoS$_{2}$ and the organic light-emitting diode are located in the same microcavity. However, monolayer MoS$_{2}$ does not reduce the localization effect of light by regulating the position of monolayer MoS$_{2}$ in the microcavity.

  20. Catalytic hydrocarbon reactions over supported metal oxides. Progress report, April 1, 1994--January 31, 1995

    SciTech Connect (OSTI)

    Ekerdt, J.G.

    1995-01-31T23:59:59.000Z

    Oxide catalysis plays a central role in hydrocarbon processing and improvements in catalytic activity or selectivity are of great technological importance because these improvements will translate directly into more efficient utilization of hydrocarbon supplies and lower energy consumption in separation processes. An understanding of the relationships between surface structure and catalytic properties is needed to describe and improve oxide catalysts. Our approach has been to prepare supported oxides that have a specific structure and oxidation state and then employ these structures in reaction studies. Our current research program is focused on studying the fundamental relationships between structure and reactivity for two important reactions that are present in many oxide-catalyzed processes, partial oxidation and carbon-carbon bond formation. Oxide catalysis can be a complex process with both metal cation and oxygen anions participating in the chemical reactions. From an energy perspective carbon-carbon bond formation is particularly relevant to CO hydrogenation in isosynthesis. Hydrogenolysis and hydrogenation form the basis for heteroatom removal in fuels processing. Understanding the catalysis of these processes (and others) requires isolating reaction steps in the overall cycle and determining how structure and composition influence the individual reaction steps. Specially designed oxides, such as we use, permit one to study some of the steps in oxidation, carbon-carbon coupling and heteroatom removal catalysis. During the course of our studies we have: (1) developed methods to form and stabilize various Mo and W oxide structures on silica; (2) studied C-H abstraction reactions over the fully oxidized cations; (3) studied C-C bond coupling by methathesis and reductive coupling of aldehydes and ketones over reduced cation structures; and (4) initiated a study of hydrogenation and hydrogenolysis over reduced cation structures.

  1. The effect of modifications of dietary fat, fiber and sodium with magnesium deficiency on serum lipids and minerals, tissue and femur minerals and femur load force 

    E-Print Network [OSTI]

    Howe, Cathlyn Ann

    1992-01-01T23:59:59.000Z

    THE EFFECT OF MODIFICATIONS OF DIETARY FAT, FIBER AND SODIUM WITH MAGNESIUM DEFICIENCY ON SERUM LIPIDS AND MINERALS, TISSUE AND FEMUR MINERALS AND FEMUR LOAD FORCE A Thesis by CATHLYN ANN HOWE "Submitted to the Office of Graduate Studies oz..." Texas A&M University partial fulfillment of the requirements for the degree of MASTER OF SCIENCE December 1992 Major Subject: Nutrition THE EFFECTS OF MODIFICATIONS OF DIETARY FAT, FIBER AND SODIUM WITH MAGNESIUM DEFICIENCY ON SERUM LIPIDS...

  2. Mineral interactions and absorption in the equine digestive tract: calcium, phosphorus, and magnesium interaction with aluminum, and calcium digestibility of alfalfa in ponies 

    E-Print Network [OSTI]

    Kapusniak, Linda J.

    1987-01-01T23:59:59.000Z

    MINERAL INTERACTIONS AND ABSORPTION IN THE EQUINE DIGESTIVE TRACT: CALCIUM, PHOSPHORUS, AND MAGNESIUM INTERACTION WITH ALUMINUM, AND CALCIUM DIGESTIBILITY OF ALFALFA IN PONIES A Thesis by LINDA J. KAPUSN IAK Subnitted to the Graduate College... of Texas ARM University. in partial fulfillment of the requirenent for the degree of MASTER OF SCIENCE August 1987 Major Subject: Nutrition MINERAL INTER4CTIONS AND ABSORPTION IN THE EQUINE DIGESTIVE TR4CT: C4LCIUM, PHOSPHORUS, AND MAGNESIUM...

  3. An experimental investigation of the effect of sodium chloride on talc solubility and complexing of aqueous magnesium in supercritical hydrothermal fluids 

    E-Print Network [OSTI]

    Grabman, Kenneth Bryan

    1989-01-01T23:59:59.000Z

    AN EXPERIMENTAL INVESTIGATION OF THE EFFECT OF SODIUM CHLORIDE ON TALC SOLUBILITY AND COMPLEXING OF AQUEOUS MAGNESIUM IN SUPERCRITICAL HYDROTHERMAL FLUIDS A Thesis by KENNETH BRYAN GRABMAN Submitted to the Office of Graduate Studies of Texas... MAGNESIUM IN SUPERCRITICAL HYDROTHERMAL FLUIDS A Thesis by KENNETH BRYAN GRABMAN Approved as to style and content by: ~A. Robert K. Popp (Ch of Commi ee) Andrew Haj sh, Jr. (Member) Brann J son (Me ) J Span (Head o Department) December 1989...

  4. Cerium Oxide Coating for Oxidation Reduction

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced. C o w l i t z C oCNMSStaffCerium Oxide Coating for Oxidation

  5. Fuel-sodium reaction product formation in breached mixed-oxide fuel

    SciTech Connect (OSTI)

    Bottcher, J.H.; Lambert, J.D.B.; Strain, R.V.; Ukai, S.; Shibahara, S.

    1988-01-01T23:59:59.000Z

    The run-beyond-cladding-breach (RBCB) operation of mixed-oxide LMR fuel pins has been studied for six years in the Experimental Breeder Reactor-II (EBR-II) as part of a joint program between the US Department of Energy and the Power Reactor and Nuclear Fuel Development Corporation of Japan. The formation of fuel-sodium reaction product (FSRP), Na/sub 3/MO/sub 4/, where M = U/sub 1-y/Pu/sub y/, in the outer fuel regions is the major phenomenon governing RBCB behavior. It increases fuel volume, decreases fuel stoichiometry, modifies fission-product distributions, and alters thermal performance of a pin. This paper describes the morphology of Na/sub 3/MO/sub 4/ observed in 5.84-mm diameter pins covering a variety of conditions and RBCB times up to 150 EFPD's. 8 refs., 1 fig.

  6. Stabilized chromium oxide film

    DOE Patents [OSTI]

    Garwin, Edward L. (Los Altos, CA); Nyaiesh, Ali R. (Palo Alto, CA)

    1988-01-01T23:59:59.000Z

    Stabilized air-oxidized chromium films deposited on high-power klystron ceramic windows and sleeves having a thickness between 20 and 150.ANG. are useful in lowering secondary electron emission yield and in avoiding multipactoring and window failure due to overheating. The ceramic substrate for the film is chosen from alumina, sapphire or beryllium oxide.

  7. Stabilized chromium oxide film

    DOE Patents [OSTI]

    Nyaiesh, A.R.; Garwin, E.L.

    1986-08-04T23:59:59.000Z

    Stabilized air-oxidized chromium films deposited on high-power klystron ceramic windows and sleeves having a thickness between 20 and 150A are useful in lowering secondary electron emission yield and in avoiding multipactoring and window failure due to overheating. The ceramic substrate for the film is chosen from alumina, sapphire or beryllium oxide.

  8. Reducible oxide based catalysts

    DOE Patents [OSTI]

    Thompson, Levi T.; Kim, Chang Hwan; Bej, Shyamal K.

    2010-04-06T23:59:59.000Z

    A catalyst is disclosed herein. The catalyst includes a reducible oxide support and at least one noble metal fixed on the reducible oxide support. The noble metal(s) is loaded on the support at a substantially constant temperature and pH.

  9. Band gap tuning in transition metal oxides by site-specific substitution

    DOE Patents [OSTI]

    Lee, Ho Nyung; Chisholm, Jr., Matthew F; Jellison, Jr., Gerald Earle; Singh, David J; Choi, Woo Seok

    2013-12-24T23:59:59.000Z

    A transition metal oxide insulator composition having a tuned band gap includes a transition metal oxide having a perovskite or a perovskite-like crystalline structure. The transition metal oxide includes at least one first element selected form the group of Bi, Ca, Ba, Sr, Li, Na, Mg, K, Pb, and Pr; and at least one second element selected from the group of Ti, Al, V, Cr, Mn, Fe, Co, Ni, Cu, Zr, Nb, Mo, Ru, Rh, Hf, Ta, W, Re, Os, Ir, and Pt. At least one correlated insulator is integrated into the crystalline structure, including REMO.sub.3, wherein RE is at least one Rare Earth element, and wherein M is at least one element selected from the group of Co, V, Cr, Ni, Mn, and Fe. The composition is characterized by a band gap of less of 4.5 eV.

  10. Effects of rhenium alloying on the microstructures and mechanical properties of directionally solidified NiAl-Mo eutectic alloy

    SciTech Connect (OSTI)

    Misra, A.; Wu, Z.L.; Gibala, R. [Univ. of Michigan, Ann Arbor, MI (United States). Dept. of Materials Science and Engineering

    1997-12-31T23:59:59.000Z

    Low ductility of the reinforcing bcc metal phase at room temperature and weak interfaces can limit the intrinsic toughness and ductility of NiAl-bcc metal eutectic composites. The potential of rhenium (Re) addition, which is known to solid solution soften and lower the ductile-to-brittle transition temperature of various bcc metals, to enhance the ductility and toughness of a directionally solidified NiAl-9 at.% Mo eutectic alloy was investigated. Re partitioned to the bcc metal phase and formed a substitutional solid solution. The interface morphology was changed from a faceted to a non-faceted one. Re alloying caused softening of the Mo fibers, and as a result NiAl-Mo(Re) alloys were softer in compression and flexure and had {approximately}20% higher fracture toughness values as compared to the transverse orientation toughness of NiAl-9Mo alloy. The toughness of the NiAl-Mo(Re) alloys was lower than the longitudinal orientation toughness of the NiAl-9Mo alloy due to the poor alignment of the Mo(Re) phase with the growth direction. The toughening mechanisms have been evaluated and schemes for processing NiAl-Mo(Re) alloys for higher toughness in the longitudinal orientation are suggested. The role of the residual interstitial impurities and partitioning of Ni and Al to Mo fibers on the mechanical properties are highlighted.

  11. An in situ x-ray spectroscopic study of Mo?{sup +} speciation in supercritical aqueous solutions

    SciTech Connect (OSTI)

    Yan, Hao [Missouri State University, Springfield, MO (United States); Mayanovic, Robert A. [Missouri State University, Springfield, MO (United States); Anderson, Alan J. [St. Francis Xavier Univ., Antigonish, NS (Canada); Meredith, Peter R. [St. Francis Xavier Univ., Antigonish, NS (Canada)

    2011-09-01T23:59:59.000Z

    In situ XRF and Mo K-edge XAS measurements were made on the ID20-B beam line at the APS on MoO? in 1 M H?O? aqueous solution, at temperatures between 400 and 600 °C. The samples were analyzed using a modified Bassett-type hydrothermal diamond anvil cell. Our XRF measurements show that MoO? is highly soluble in the supercritical H?O? aqueous fluid. Analysis of XAS spectra shows that the Mo?{sup +} ion exhibits consistent speciation in the H?O? aqueous solution at temperatures ranging from 400 to 600 °C.

  12. Mechanical properties of MoS2/graphene heterostructures Jin-Wu Jiang and Harold S. Park

    E-Print Network [OSTI]

    of the heterostructure is considerably smaller than the MoS2 due to lateral buckling of the outer graphene layers owning

  13. Displacement of the proton in hydrogen-bonded complexes of hydrogen fluoride by beryllium and magnesium ions

    SciTech Connect (OSTI)

    McDowell, Sean A. C. [Department of Biological and Chemical Sciences, University of the West Indies, Cave Hill Campus (Barbados)

    2009-05-14T23:59:59.000Z

    The displacement of the proton by a beryllium ion and by a magnesium ion from hydrogen-bonded complexes of hydrogen fluoride, of varying hydrogen bond strengths, was investigated theoretically using ab initio methods. Stable metal-containing species were obtained from all of the hydrogen-bonded complexes regardless of the strength of the hydrogen bond. It was found that the beryllium ion was energetically very effective in displacing the proton from hydrogen bonds, whereas the magnesium ion was unable to do so. The high stability of the beryllium-containing complexes is mainly due to the strong electrostatic bonding between the beryllium and fluoride atoms. This work supports the recent finding from a multidisciplinary bioinorganic study that beryllium displaces the proton in many strong hydrogen bonds.

  14. Abnormal macropore formation during double-sided gas tungsten arc welding of magnesium AZ91D alloy

    SciTech Connect (OSTI)

    Shen Jun [College of Mechanical Engineering, Chongqing University, Chongqing 400044 (China)], E-mail: shenjun2626@163.com; You Guoqiang; Long Siyuan [College of Mechanical Engineering, Chongqing University, Chongqing 400044 (China); Pan Fusheng [College of Material Science and Engineering, Chongqing University, Chongqing 400044 (China)

    2008-08-15T23:59:59.000Z

    One of the major concerns during gas tungsten arc (GTA) welding of cast magnesium alloys is the presence of large macroporosity in weldments, normally thought to occur from the presence of gas in the castings. In this study, a double-sided GTA welding process was adopted to join wrought magnesium AZ91D alloy plates. Micropores were formed in the weld zone of the first side that was welded, due to precipitation of H{sub 2} as the mushy zone freezes. When the reverse side was welded, the heat generated caused the mushy zone in the initial weld to reform. The micropores in the initial weld then coalesced and expanded to form macropores by means of gas expansion through small holes that are present at the grain boundaries in the partially melted zone. Macropores in the partially melted zone increase with increased heat input, so that when a filler metal is used the macropores are smaller in number and in size.

  15. Elementary Steps of Syngas Reactions on Mo2C(001): Adsorption Thermochemistry and Bond Dissociation

    SciTech Connect (OSTI)

    Medford, Andrew

    2012-02-16T23:59:59.000Z

    Density functional theory (DFT) and ab initio thermodynamics are applied in order to investigate the most stable surface and subsurface terminations of Mo{sub 2}C(001) as a function of chemical potential and in the presence of syngas. The Mo-terminated (001) surface is then used as a model surface to evaluate the thermochemistry and energetic barriers for key elementary steps in syngas reactions. Adsorption energy scaling relations and Broensted-Evans-Polanyi relationships are established and used to place Mo{sub 2}C into the context of transition metal surfaces. The results indicate that the surface termination is a complex function of reaction conditions and kinetics. It is predicted that the surface will be covered by either C{sub 2}H{sub 2} or O depending on conditions. Comparisons to transition metals indicate that the Mo-terminated Mo{sub 2}C(001) surface exhibits carbon reactivity similar to transition metals such as Ru and Ir, but is significantly more reactive towards oxygen.

  16. TEM Characterization of High Burn-up Microstructure of U-7Mo Alloy

    SciTech Connect (OSTI)

    Jian Gan; Brandon Miller; Dennis Keiser; Adam Robinson; James Madden; Pavel Medvedev; Daniel Wachs

    2014-04-01T23:59:59.000Z

    As an essential part of global nuclear non-proliferation effort, the RERTR program is developing low enriched U-Mo fuels (< 20% U-235) for use in research and test reactors that currently employ highly enriched uranium fuels. One type of fuel being developed is a dispersion fuel plate comprised of U-7Mo particles dispersed in Al alloy matrix. Recent TEM characterizations of the ATR irradiated U-7Mo dispersion fuel plates include the samples with a local fission densities of 4.5, 5.2, 5.6 and 6.3 E+21 fissions/cm3 and irradiation temperatures of 101-136?C. The development of the irradiated microstructure of the U-7Mo fuel particles consists of fission gas bubble superlattice, large gas bubbles, solid fission product precipitates and their association to the large gas bubbles, grain subdivision to tens or hundreds of nanometer size, collapse of bubble superlattice, and amorphisation. This presentation will describe the observed microstructures specifically focusing on the U-7Mo fuel particles. The impact of the observed microstructure on the fuel performance and the comparison of the relevant features with that of the high burn-up UO2 fuels will be discussed.

  17. Beta. -MoO sub 3 produced from a novel freeze drying route

    SciTech Connect (OSTI)

    Parise, J.B. (State Univ. of New York, Stony Brook (United States)); McCarron, E.M. III (E.I. Dupont de Nemours and Co., Inc., Wilmington, DE (United States)); Von Dreele, R.; Goldstone, J.A. (Los Alamos National Lab., NM (United States))

    1991-07-01T23:59:59.000Z

    Powdered samples of {beta}-MoO{sub 3} have been produced by the gentle heat treatment of freeze-dried molybdic acid at 350{degree}C for 1 hr. The samples, yellow-green in appearance, contained varying amounts of the thermodynamically stable {alpha}-MoO{sub 3}, depending upon the time and temperature of heat treatment. Neutron diffraction data were collected at 300 K. all peaks, not attributable to {alpha}-MoO{sub 3}, were indexed on the basis of a monoclinic cell, P2{sub 1}/c, {alpha} = 7.1228(7), b = 5.3660(6), c = 5.5665(6), {beta} = 92.01(1){degree}, V = 212.62(6){angstrom}{sup 3}. The structure, which is related to ReO{sub 3}, contains two crystallographically independent octahedra. Both show evidence of disorder at the Mo and O sites. Two distinct orientations of a short mo-O distance, suggestive of the type of molybdenyl bond observed in both the {alpha} and {beta}{prime}-forms, are primarily responsible for the observed disordering.

  18. Liquid generation during sintering of Fe-3.5%Mo powder compacts with elemental boron additions

    SciTech Connect (OSTI)

    Sarasola, M.; Gomez-Acebo, T.; Castro, F

    2004-09-06T23:59:59.000Z

    The mechanisms for liquid generation and the microstructural development during sintering of a Fe-3.5Mo-0.3B alloy were studied. Interrupted sintering experiments followed by water quenching from specific temperatures within the sintering cycle have been carried out. The influence of Mo, both, on the final microstructure and on the behaviour of boron prior to, during and after the formation of the liquid phase, was studied through observation of the quenched samples under LOM and SEM. The study shows that prior to the formation of the liquid phase, boron diffuses into the metallic particles forming inter and intragranular precipitates of the (Fe,Mo){sub 2}B type. At higher temperatures a continuous Fe/Mo/B liquid phase, with excellent wetting characteristics, is formed thus leading to near fully dense materials. The generation of the liquid is based on a eutectic reaction involving the mixed (Fe,Mo){sub 2}B borides previously formed. The development of the microstructure after liquid formation is described.

  19. Electrochemical properties of magnesium doped LiFePO{sub 4} cathode material prepared by sol–gel method

    SciTech Connect (OSTI)

    Zhao, Xiaohui; Baek, Dong-Ho; Manuel, James; Heo, Min-Yeong; Yang, Rong [Department of Chemical and Biological Engineering and Research Institute for Green Energy Convergence Technology, Gyeongsang National University, 900, Gajwa-dong, Jinju 600-701 (Korea, Republic of)] [Department of Chemical and Biological Engineering and Research Institute for Green Energy Convergence Technology, Gyeongsang National University, 900, Gajwa-dong, Jinju 600-701 (Korea, Republic of); Ha, Jong Keun; Ryu, Ho-Suk; Ahn, Hyo-Jun; Kim, Ki-Won [Department of Metallurgical Science and Engineering, Gyeongsang National University, 900, Gajwa-dong, Jinju 600-701 (Korea, Republic of)] [Department of Metallurgical Science and Engineering, Gyeongsang National University, 900, Gajwa-dong, Jinju 600-701 (Korea, Republic of); Cho, Kwon-Koo, E-mail: kkcho66@gnu.ac.kr [Department of Metallurgical Science and Engineering, Gyeongsang National University, 900, Gajwa-dong, Jinju 600-701 (Korea, Republic of)] [Department of Metallurgical Science and Engineering, Gyeongsang National University, 900, Gajwa-dong, Jinju 600-701 (Korea, Republic of); Ahn, Jou-Hyeon, E-mail: jhahn@gnu.ac.kr [Department of Chemical and Biological Engineering and Research Institute for Green Energy Convergence Technology, Gyeongsang National University, 900, Gajwa-dong, Jinju 600-701 (Korea, Republic of)] [Department of Chemical and Biological Engineering and Research Institute for Green Energy Convergence Technology, Gyeongsang National University, 900, Gajwa-dong, Jinju 600-701 (Korea, Republic of)

    2012-10-15T23:59:59.000Z

    Magnesium doped Li{sub 1?2x}Mg{sub x}FePO{sub 4}/C (x = 0.00, 0.01, 0.03, 0.05) cathode materials were synthesized by sol–gel method, and the effect of magnesium doping as well as its content on the electrochemical properties for lithium batteries was also investigated{sub .} Their morphology was studied with field emission scanning electron microscope and Li{sub 1?2x}Mg{sub x}FePO{sub 4} materials showed the olivine phase without impurities. The thin carbon layer of Li{sub 1?2x}Mg{sub x}FePO{sub 4}/C was confirmed by high resolution transmission electron microscopy. The magnesium doped Li{sub 1?2x}Mg{sub x}FePO{sub 4}/C particles were smaller than those undoped. The Li{sub 1?2x}Mg{sub x}FePO{sub 4}/C materials showed better cycling behavior than undoped LiFePO{sub 4}, especially at high C-rate in which Li{sub 0.94}Mg{sub 0.03}FePO{sub 4}/C composition exhibited the best electrochemical properties.

  20. Time exposure performance of Mo-Au Gibbsian segregating alloys for extreme ultraviolet collector optics

    SciTech Connect (OSTI)

    Qiu Huatan; Srivastava, Shailendra N.; Thompson, Keith C.; Neumann, Martin J.; Ruzic, David N

    2008-05-01T23:59:59.000Z

    Successful implementation of extreme ultraviolet (EUV) lithography depends on research and progress toward minimizing collector optics degradation from intense plasma erosion and debris deposition. Thus studying the surface degradation process and implementing innovative methods, which could enhance the surface chemistry causing the mirrors to suffer less damage, is crucial for this technology development. A Mo-Au Gibbsian segregation (GS) alloy is deposited on Si using a dc dual-magnetron cosputtering system and the damage is investigated as a result of time dependent exposure in an EUV source. A thin Au segregating layer is maintained through segregation during exposure, even though overall erosion in the Mo-Au sample is taking place in the bulk. The reflective material, Mo, underneath the segregating layer is protected by this sacrificial layer, which is lost due to preferential sputtering. In addition to theoretical work, experimental results are presented on the effectiveness of the GS alloys to be used as potential EUV collector optics material.

  1. Influence of uranium hydride oxidation on uranium metal behaviour

    SciTech Connect (OSTI)

    Patel, N.; Hambley, D. [National Nuclear Laboratory (United Kingdom); Clarke, S.A. [Sellafield Ltd (United Kingdom); Simpson, K.

    2013-07-01T23:59:59.000Z

    This work addresses concerns that the rapid, exothermic oxidation of active uranium hydride in air could stimulate an exothermic reaction (burning) involving any adjacent uranium metal, so as to increase the potential hazard arising from a hydride reaction. The effect of the thermal reaction of active uranium hydride, especially in contact with uranium metal, does not increase in proportion with hydride mass, particularly when considering large quantities of hydride. Whether uranium metal continues to burn in the long term is a function of the uranium metal and its surroundings. The source of the initial heat input to the uranium, if sufficient to cause ignition, is not important. Sustained burning of uranium requires the rate of heat generation to be sufficient to offset the total rate of heat loss so as to maintain an elevated temperature. For dense uranium, this is very difficult to achieve in naturally occurring circumstances. Areas of the uranium surface can lose heat but not generate heat. Heat can be lost by conduction, through contact with other materials, and by convection and radiation, e.g. from areas where the uranium surface is covered with a layer of oxidised material, such as burned-out hydride or from fuel cladding. These rates of heat loss are highly significant in relation to the rate of heat generation by sustained oxidation of uranium in air. Finite volume modelling has been used to examine the behaviour of a magnesium-clad uranium metal fuel element within a bottle surrounded by other un-bottled fuel elements. In the event that the bottle is breached, suddenly, in air, it can be concluded that the bulk uranium metal oxidation reaction will not reach a self-sustaining level and the mass of uranium oxidised will likely to be small in relation to mass of uranium hydride oxidised. (authors)

  2. Neutrino-nucleus scattering of {sup 95,97}Mo and {sup 116}Cd

    SciTech Connect (OSTI)

    Ydrefors, E. [Royal Institute of Technology (KTH), Alba Nova University Center, SE-10691 Stockholm, Sweden and Department of Physics, P.O. Box 35 (YFL), FI-40014 University of Jyväskylä (Finland); Almosly, W.; Suhonen, J. [Department of Physics, P.O. Box 35 (YFL), FI-40014 University of Jyväskylä (Finland)

    2013-12-30T23:59:59.000Z

    Accurate knowledge about the nuclear responses to supernova neutrinos for relevant nuclear targets is important both for neutrino detection and for astrophysical applications. In this paper we discuss the cross sections for the charged-current neutrino-nucleus scatterings off {sup 95,97}Mo and {sup 116}Cd. The microscopic quasiparticle-phonon model is adopted for the odd-even nuclei {sup 95,97}Mo. In the case of {sup 116}Cd we present cross sections both for the Bonn one-boson-exchange potential and self-consistent calculations based on modern Skyrme interactions.

  3. Characterization of metal contacts for two-dimensional MoS{sub 2} nanoflakes

    SciTech Connect (OSTI)

    Walia, Sumeet, E-mail: madhu.bhaskaran@rmit.edu.au, E-mail: kourosh.kalantar@rmit.edu.au, E-mail: sumeet.walia@rmit.edu.au; Balendhran, Sivacarendran; Sriram, Sharath; Bhaskaran, Madhu, E-mail: madhu.bhaskaran@rmit.edu.au, E-mail: kourosh.kalantar@rmit.edu.au, E-mail: sumeet.walia@rmit.edu.au [Functional Materials and Microsystems Research Group, RMIT University, Melbourne, Victoria 3000 (Australia) [Functional Materials and Microsystems Research Group, RMIT University, Melbourne, Victoria 3000 (Australia); School of Electrical and Computer Engineering, RMIT University, Melbourne, Victoria 3000 (Australia); Wang, Yichao; Ab Kadir, Rosmalini; Sabirin Zoolfakar, Ahmad; Atkin, Paul; Zhen Ou, Jian; Kalantar-zadeh, Kourosh, E-mail: madhu.bhaskaran@rmit.edu.au, E-mail: kourosh.kalantar@rmit.edu.au, E-mail: sumeet.walia@rmit.edu.au [School of Electrical and Computer Engineering, RMIT University, Melbourne, Victoria 3000 (Australia)] [School of Electrical and Computer Engineering, RMIT University, Melbourne, Victoria 3000 (Australia)

    2013-12-02T23:59:59.000Z

    While layered materials are increasingly investigated for their potential in nanoelectronics, their functionality and efficiency depend on charge injection into the materials via metallic contacts. This work explores the characteristics of different metals (aluminium, tungsten, gold, and platinum) deposited on to nanostructured thin films made of two-dimensional (2D) MoS{sub 2} flakes. Metals are chosen based on their work functions relative to the electron affinity of MoS{sub 2}. It is observed, and analytically verified that lower work functions of the contact metals lead to smaller Schottky barrier heights and consequently higher charge carrier injection through the contacts.

  4. Evolution of level density step structures from 56,57-Fe to 96,97-Mo

    E-Print Network [OSTI]

    A. Schiller; E. Tavukcu; L. A. Bernstein; P. E. Garrett; M. Guttormsen; M. Hjorth-Jensen; C. W. Johnson; G. E. Mitchell; J. Rekstad; S. Siem; A. Voinov; W. Younes

    2003-02-24T23:59:59.000Z

    Level densities have been extracted from primary gamma spectra for 56,57-Fe and 96,97-Mo nuclei using (3-He,alpha gamma) and (3-He,3-He') reactions on 57-Fe and 97-Mo targets. The level density curves reveal step structures above the pairing gap due to the breaking of nucleon Cooper pairs. The location of the step structures in energy and their shapes arise from the interplay between single-particle energies and seniority-conserving and seniority-non-conserving interactions.

  5. Oxidative Tritium Decontamination System

    DOE Patents [OSTI]

    Gentile, Charles A. (Plainsboro, NJ), Guttadora, Gregory L. (Highland Park, NJ), Parker, John J. (Medford, NJ)

    2006-02-07T23:59:59.000Z

    The Oxidative Tritium Decontamination System, OTDS, provides a method and apparatus for reduction of tritium surface contamination on various items. The OTDS employs ozone gas as oxidizing agent to convert elemental tritium to tritium oxide. Tritium oxide vapor and excess ozone gas is purged from the OTDS, for discharge to atmosphere or transport to further process. An effluent stream is subjected to a catalytic process for the decomposition of excess ozone to diatomic oxygen. One of two configurations of the OTDS is employed: dynamic apparatus equipped with agitation mechanism and large volumetric capacity for decontamination of light items, or static apparatus equipped with pressurization and evacuation capability for decontamination of heavier, delicate, and/or valuable items.

  6. Non-LTE Abundances of Magnesium, Aluminum and Sulfur in OB Stars Near the Solar Circle

    E-Print Network [OSTI]

    S. Daflon; K. Cunha; V. V. Smith; K. Butler

    2002-12-09T23:59:59.000Z

    Non-LTE abundances of magnesium, aluminum and sulfur are derived for a sample of 23 low-v \\sin i stars belonging to six northern OB associations of the Galactic disk within 1 kpc of the Sun. The abundances are obtained from the fitting of synthetic line profiles to high resolution spectra. A comparison of our results with HII region abundances indicates good agreement for sulfur while the cepheid abundances are higher. The derived abundances of Mg show good overlap with the cepheid results. The aluminum abundances for OB stars are significantly below the cepheid values. But, the OB star results show a dependence with effective temperature and need further investigation. The high Al abundances in the cepheids could be the result of mixing. A discussion of the oxygen abundance in objects near the solar circle suggests that the current mean galactic oxygen abundance in this region is 8.6-8.7 and in agreement with the recently revised oxygen abundance in the solar photosphere. Meaningful comparisons of the absolute S, Al and Mg abundances in OB stars with the Sun must await a reinvestigation of these elements, as well as the meteoritic reference element Si, with 3D hydrodynamical model atmospheres for the Sun. No abundance gradients are found within the limited range in galactocentric distances in the present study. Such variations would be expected only if there were large metallicity gradients in the disk.

  7. Magnesium and Manganese Silicides For Efficient And Low Cost Thermo-Electric Power Generation

    SciTech Connect (OSTI)

    Trivedi, Sudhir B. [Brimrose Technology Corporation; Kutcher, Susan W. [Brimrose Technology Corporation; Rosemeier, Cory A. [Brimrose Technology Corporation; Mayers, David [Brimrose Technology Corporation; Singh, Jogender [Pennsylvania State University

    2013-12-02T23:59:59.000Z

    Thermoelectric Power Generation (TEPG) is the most efficient and commercially deployable power generation technology for harvesting wasted heat from such things as automobile exhausts, industrial furnaces, and incinerators, and converting it into usable electrical power. We investigated the materials magnesium silicide (Mg2Si) and manganese silicide (MnSi) for TEG. MgSi2 and MnSi are environmentally friendly, have constituent elements that are abundant in the earth's crust, non-toxic, lighter and cheaper. In Phase I, we successfully produced Mg2Si and MnSi material with good TE properties. We developed a novel technique to synthesize Mg2Si with good crystalline quality, which is normally very difficult due to high Mg vapor pressure and its corrosive nature. We produced n-type Mg2Si and p-type MnSi nanocomposite pellets using FAST. Measurements of resistivity and voltage under a temperature gradient indicated a Seebeck coefficient of roughly 120 V/K on average per leg, which is quite respectable. Results indicated however, that issues related to bonding resulted in high resistivity contacts. Determining a bonding process and bonding material that can provide ohmic contact from room temperature to the operating temperature is an essential part of successful device fabrication. Work continues in the development of a process for reproducibly obtaining low resistance electrical contacts.

  8. Polymer Stable Magnesium Nanocomposites Prepared by Laser Ablation for Efficient Hydrogen Storage

    E-Print Network [OSTI]

    Makridis, S S; Panagakos, G; Kikkinides, E S; Stubos, A K; Wagener, P; Barcikowski, S

    2013-01-01T23:59:59.000Z

    Hydrogen is a promising alternative energy carrier that can potentially facilitate the transition from fossil fuels to sources of clean energy because of its prominent advantages such as high energy density (142 MJ per kg), great variety of potential sources (for example water, biomass, organic matter), and low environmental impact (water is the sole combustion product). However, due to its light weight, the efficient storage of hydrogen is still an issue investigated intensely. Various solid media have been considered in that respect among which magnesium hydride stands out as a candidate offering distinct advantages. Recent theoretical work indicates that MgH2 becomes less thermodynamically stable as particle diameter decreases below 2 nm. Our DFT (density functional theory) modeling studies have shown that the smallest enthalpy change, corresponding to 2 unit-cell thickness (1.6 {\\AA} Mg/3.0{\\AA} MgH2) of the film, is 57.7 kJ/molMg. This enthalpy change is over 10 kJ per molMg smaller than that of the bulk...

  9. Controlled CO preferential oxidation

    DOE Patents [OSTI]

    Meltser, M.A.; Hoch, M.M.

    1997-06-10T23:59:59.000Z

    Method is described for controlling the supply of air to a PROX (PReferential OXidation for CO cleanup) reactor for the preferential oxidation in the presence of hydrogen wherein the concentration of the hydrogen entering and exiting the PROX reactor is monitored, the difference there between correlated to the amount of air needed to minimize such difference, and based thereon the air supply to the PROX reactor adjusted to provide such amount and minimize such difference. 2 figs.

  10. Background radioactivity of construction materials, raw substance and ready-made CaMoO4 crystals

    E-Print Network [OSTI]

    Busanov, O A; Gavriljuk, Yu M; Gezhaev, A M; Kazalov, V V; Kornoukhov, V N; Kuzminov, V V; Moseev, P S; Panasenko, S I; Ratkevich, S S; Yakimenko, S P

    2013-01-01T23:59:59.000Z

    The results of measurements of natural radioactive isotopes content in different source materials of natural and enriched composition used for CaMoO4 scintillation crystal growing are presented. The crystals are to be used in the experiment to search for double neutrinoless betas-decay of Mo-100.

  11. Pseudo-elastic deformation behavior in a Ti/Mo-based alloy , M. Aindow a,*, S.P. Alpay a

    E-Print Network [OSTI]

    Alpay, S. Pamir

    , and are increasingly finding applications in aerospace, oil well systems and automotive parts [1]. Alloys in the metaPseudo-elastic deformation behavior in a Ti/Mo-based alloy T. Zhou a , M. Aindow a,*, S.P. Alpay 2003 Abstract It is shown that the pseudo-elastic response in a series of Ti­Mo­V­Nb­Al alloys with 8

  12. Solar Energy Materials & Solar Cells 58 (1999) 199}208 The behaviour of Na implanted into Mo thin "lms

    E-Print Network [OSTI]

    Rockett, Angus

    Solar Energy Materials & Solar Cells 58 (1999) 199}208 The behaviour of Na implanted into Mo thin, As ngstro( m Solar Center, P.O. Box 534, SE-751 21 Uppsala, Sweden Department of Materials Science Mo thin "lms used as back contacts for Cu(In,Ga)Se solar cells. The samples were analysed

  13. Giant Two-Photon Absorption Coefficient and Frequency Up-Converted Luminescence in Monolayer MoS2

    E-Print Network [OSTI]

    Li, Yuanxin; Zhang, Saifeng; Zhang, Xiaoyan; Feng, Yanyan; Wang, Kangpeng; Zhang, Long; Wang, Jun

    2015-01-01T23:59:59.000Z

    Strong two-photon absorption (TPA) in monolayer MoS2 is demonstrated in contrast to saturable absorption (SA) in multilayer MoS2 under the excitation of femtosecond laser pulses in the near infrared region. MoS2 in the forms of monolayer single crystal and multilayer triangular islands are grown on either quartz or SiO2/Si by employing the seeding method through chemistry vapor deposition. The nonlinear transmission measurements reveal that monolayer MoS2 possesses a giant nonsaturation TPA coefficient, larger than that of conventional semiconductors. As a result of TPA, two-photon pumped frequency up-converted luminescence is observed directly in the monolayer MoS2. For the multilayer MoS2, the SA response is demonstrated with the ratio of the excited-state absorption cross section to ground-state cross section of 0.18. In addition, the laser damage threshold of the monolayer MoS2 is 97 GW/cm2, larger than that of the multilayer MoS2 of 78 GW/cm2.

  14. ADVANCED OXIDATION PROCESS

    SciTech Connect (OSTI)

    Dr. Colin P. Horwitz; Dr. Terrence J. Collins

    2003-11-04T23:59:59.000Z

    The removal of recalcitrant sulfur species, dibenzothiophene and its derivatives, from automotive fuels is an integral component in the development of cleaner burning and more efficient automobile engines. Oxidative desulfurization (ODS) wherein the dibenzothiophene derivative is converted to its corresponding sulfoxide and sulfone is an attractive approach to sulfur removal because the oxidized species are easily extracted or precipitated and filtered from the hydrocarbon phase. Fe-TAML{reg_sign} activators of hydrogen peroxide (TAML is Tetra-Amido-Macrocyclic-Ligand) catalytically convert dibenzothiophene and its derivatives rapidly and effectively at moderate temperatures (50-60 C) and ambient pressure to the corresponding sulfoxides and sulfones. The oxidation process can be performed in both aqueous systems containing alcohols such as methanol, ethanol, or t-butanol, and in a two-phase hydrocarbon/aqueous system containing tert-butanol or acetonitrile. In the biphasic system, essentially complete conversion of the DBT to its oxidized products can be achieved using slightly longer reaction times than in homogeneous solution. Among the key features of the technology are the mild reaction conditions, the very high selectivity where no over oxidation of the sulfur compounds occurs, the near stoichiometric use of hydrogen peroxide, the apparent lack of degradation of sensitive fuel components, and the ease of separation of oxidized products.

  15. Single-layer MoS{sub 2} roughness and sliding friction quenching by interaction with atomically flat substrates

    SciTech Connect (OSTI)

    Quereda, J. [Departamento de Física de la Materia Condensada, Universidad Autónoma de Madrid, Madrid E-28049 (Spain); Castellanos-Gomez, A. [Kavli Institute of Nanoscience, Delft University of Technology, Lorentzweg 1, 2628 CJ Delft (Netherlands); Agraït, N. [Departamento de Física de la Materia Condensada, Universidad Autónoma de Madrid, Madrid E-28049 (Spain); Instituto Madrileño de Estudios Avanzados en Nanociencia, IMDEA-Nanociencia, E-28049 Madrid (Spain); Instituto de Ciencia de Materiales Nicolás Cabrera, Campus de Cantoblanco, E-28049 Madrid (Spain); Condensed Matter Physics Center (IFIMAC), Universidad Autónoma de Madrid, E-28049 Madrid (Spain); Rubio-Bollinger, G., E-mail: gabino.rubio@uam.es [Departamento de Física de la Materia Condensada, Universidad Autónoma de Madrid, Madrid E-28049 (Spain); Instituto de Ciencia de Materiales Nicolás Cabrera, Campus de Cantoblanco, E-28049 Madrid (Spain); Condensed Matter Physics Center (IFIMAC), Universidad Autónoma de Madrid, E-28049 Madrid (Spain)

    2014-08-04T23:59:59.000Z

    We experimentally study the surface roughness and the lateral friction force in single-layer MoS{sub 2} crystals deposited on different substrates: SiO{sub 2}, mica, and hexagonal boron nitride (h-BN). Roughness and sliding friction measurements are performed by atomic force microscopy. We find a strong dependence of the MoS{sub 2} roughness on the underlying substrate material, being h-BN the substrate which better preserves the flatness of the MoS{sub 2} crystal. The lateral friction also lowers as the roughness decreases, and attains its lowest value for MoS{sub 2} flakes on h-BN substrates. However, it is still higher than for the surface of a bulk MoS{sub 2} crystal, which we attribute to the deformation of the flake due to competing tip-to-flake and flake-to-substrate interactions.

  16. BBA Electives: M&O Comparison Compiled 11/11/09

    E-Print Network [OSTI]

    Michigan, University of

    University ­ Marriott Organizational Development and Change Teams and Work Groups Human Resource Management Compensation Management Labor Relations and Conflict Management Staffing Organizations Motivation and Work MIT1 BBA Electives: M&O Comparison Compiled 11/11/09 University of Michigan ­ Ross School Management

  17. EIS-0475: Disposition of the Bannister Federal Complex, Kansas City, MO

    Broader source: Energy.gov [DOE]

    NNSA/DOE announces its intent to prepare an EIS for the disposition of the Bannister Federal Complex, Kansas City, MO. NNSA previously decided in a separate NEPA review (EA-1592) to relocate its operations from the Bannister Federal Complex to a newly constructed industrial campus eight miles from the current location.

  18. MoDPepInt: An interactive webserver for prediction of modular domain-peptide interactions

    E-Print Network [OSTI]

    Brendel, Volker

    MoDPepInt: An interactive webserver for prediction of modular domain-peptide interactions-Supervised Prediction of SH2-Peptide Interactions from Imbalanced High-Throughput Data PLoS One, 8(5), pp. e62732, 2013-peptide interaction prediction with an application to human SH3 domains Bioinformatics, 29(13), pp. i335-i343, 2013

  19. On the Higher-Order MoM-PO Electromagnetic Modeling of Vehicles

    E-Print Network [OSTI]

    Notaros, Branislav M.

    vehicles (cars, airplanes, helicopters, spacecraft, etc.). From the electromagnetic point of view and accurate higher-order, large-domain hybrid computational technique based on the method of moments (Mo the efficiency and accuracy of the hybrid higher-order computational technique and its advantages over

  20. Enriched Zn$^{100}$MoO$_4$ scintillating bolometers to search for $0 \

    E-Print Network [OSTI]

    Barabash, A S; Danevich, F A; Giuliani, A; Ivanov, I M; Makarov, E P; Mancuso, M; Marnieros, S; Nasonov, S G; Nones, C; Olivieri, E; Pessina, G; Poda, D V; Shlegel, V N; Tenconi, M; Tretyak, V I; Vasiliev, Ya V; Velazquez, M; Zhdankov, V N

    2014-01-01T23:59:59.000Z

    The LUMINEU project aims at performing a demonstrator underground experiment searching for the neutrinoless double beta decay of the isotope $^{100}$Mo embedded in zinc molybdate (ZnMoO$_4$) scintillating bolometers. In this context, a zinc molybdate crystal boule enriched in $^{100}$Mo to 99.5\\% with a mass of 171 g was grown for the first time by the low-thermal-gradient Czochralski technique. The production cycle provided a high yield (the crystal boule mass was 84\\% of initial charge) and an acceptable level -- around 4\\% -- of irrecoverable losses of the costy enriched material. Two crystals of 59 g and 63 g, obtained from the enriched boule, were tested aboveground at milli-Kelvin temperature as scintillating bolometers. They showed a high detection performance, equivalent to that of previously developed natural ZnMoO$_4$ detectors. These results pave the way to future sensitive searches based on the LUMINEU technology, capable to approach and explore the inverted hierarchy region of the neutrino mass p...

  1. Molecular Adsorption to LiMo3Se3 Nanowire Film Chemiresistors

    E-Print Network [OSTI]

    Chiang, Shirley

    Molecular Adsorption to LiMo3Se3 Nanowire Film Chemiresistors Xiubin Qi, Frank E. Osterloh,*, S. A that the temporal and steady-state resistance changes of the films depend on the time following the adsorption and on the number of molecules that adsorb to the nanowire films at a given pressure. The adsorption ability

  2. Investigation of Double Beta Decay of 100Mo to Excited States of 100Ru

    SciTech Connect (OSTI)

    A. J. Caffrey; The NEMO-3 Collaboration

    2014-05-01T23:59:59.000Z

    Double beta decay of 100Mo to the excited states of daughter nuclei has been studied using a 600 cm3 low-background HPGe detector and an external source consisting of 2588 g of 97.5% enriched metallic 100Mo, which was formerly inside the NEMO-3 detector and used for the NEMO-3 measurements of 100Mo. The half-life for the two-neutrino double beta decay of 100Mo to the excited View the MathML source state in 100Ru is measured to be T1/2=[7.5±0.6(stat)±0.6(syst)]·1020 yr. For other (0?+2?) transitions to the View the MathML source, View the MathML source, View the MathML source, View the MathML source and View the MathML source levels in 100Ru, limits are obtained at the level of ~(0.25–1.1)·1022 yr.

  3. Magnetic cluster excitations in the antiferromagnetic phase of a-MnMoO4 

    E-Print Network [OSTI]

    Ochsenbein, Stefan T; Chaboussant, Gregory; Sieber, Andreas; Gudel, Hans U; Janssen, Stefan; Furrer, Albert; Attfield, J. Paul

    2003-01-01T23:59:59.000Z

    The tetramer-based compound a-MnMoO4 exhibits four prominent peaks in the inelastic neutron scattering (INS) spectrum between 0.5 and 2.0 meV below 10 K. They are assigned to magnetic excitations of the (Mn2+)4 rhombus ...

  4. Irradiation Performance of U-Mo Alloy Based ‘Monolithic’ Plate-Type Fuel – Design Selection

    SciTech Connect (OSTI)

    A. B. Robinson; G. S. Chang; D. D. Keiser, Jr.; D. M. Wachs; D. L. Porter

    2009-08-01T23:59:59.000Z

    A down-selection process has been applied to the U-Mo fuel alloy based monolithic plate fuel design, supported by irradiation testing of small fuel plates containing various design parameters. The irradiation testing provided data on fuel performance issues such as swelling, fuel-cladding interaction (interdiffusion), blister formation at elevated temperatures, and fuel/cladding bond quality and effectiveness. U-10Mo (wt%) was selected as the fuel alloy of choice, accepting a somewhat lower uranium density for the benefits of phase stability. U-7Mo could be used, with a barrier, where the trade-off for uranium density is critical to nuclear performance. A zirconium foil barrier between fuel and cladding was chosen to provide a predictable, well-bonded, fuel-cladding interface, allowing little or no fuel-cladding interaction. The fuel plate testing conducted to inform this selection was based on the use of U-10Mo foils fabricated by hot co-rolling with a Zr foil. The foils were subsequently bonded to Al-6061 cladding by hot isostatic pressing or friction stir bonding.

  5. Lithium Intercalation in Graphene/MoS2 Composites: First-Principles Insights

    E-Print Network [OSTI]

    Shao, Xiji; Pang, Rui; Shi, Xingqiang

    2015-01-01T23:59:59.000Z

    As a storage material for Li-ion batteries, graphene/molybdenum disulfide (Gr/MoS2) composites have been intensively studied in experiments. But the relevant theoretical works from first-principles are lacking. In the current work, van-der-Waals-corrected density functional theory calculations are performed to investigate the interaction of Li in Gr/MoS2 composites. Three interesting features are revealed for the intercalated Gr/Li(n)/MoS2 composites (n = 1 to 9). One is the reason for large Li storage capacity of Gr/MoS2: due to the binding energies per Li atom increase with the increasing number of intercalated Li atoms. Secondly, the band gap opening of Gr is found, and the band gap is enlarged with the increasing number of intercalated Li atoms, up to 160 meV with nine Li; hence these results suggest an efficient way to tune the band gap of graphene. Thirdly, the Dirac cone of Gr always preserve for different number of ionic bonded Li atoms.

  6. This is MoFo. Scientific/Technical Patent Analysts/Agents

    E-Print Network [OSTI]

    Straight, Aaron

    This is MoFo. Scientific/Technical Patent Analysts/Agents (Los Angeles, CA; McLean, VA; Palo Alto level patent analysts/agents for our Los Angeles, Palo Alto, San Diego and San Francisco offices of business strategies. Patent analysts/agents participate in domestic and foreign patent prosecution

  7. 2008 IEEE Swarm Intelligence Symposium St. Louis MO USA, September 21-23, 2008

    E-Print Network [OSTI]

    Havens, Timothy

    2008 IEEE Swarm Intelligence Symposium St. Louis MO USA, September 21-23, 2008 Roach Infestation of the PSO algorithm, entitled Roach Infestation Optimization (RIO), that is inspired by recent discoveries discoveries in the behavior of cockroaches are the inspiration for our proposed algorithm, Roach Infestation

  8. Safety Analysis Using Coloured Petri Nets Seung Mo Cho, Hyoung Seok Hong, and Sung Deok Cha

    E-Print Network [OSTI]

    as an example. 1. Introduction Software control in safety-critical systems such as aerospace, military, nuclearSafety Analysis Using Coloured Petri Nets Seung Mo Cho, Hyoung Seok Hong, and Sung Deok Cha Department of Computer Science Korea Advanced Institute of Science and Technology (KAIST) 373-1, Kusong

  9. A Network Model and Computational Approach Mo Supply Chain for Nuclear Medicine

    E-Print Network [OSTI]

    Nagurney, Anna

    A Network Model and Computational Approach for the 99 Mo Supply Chain for Nuclear Medicine Ladimer S. Nagurney1 and Anna Nagurney2 1Department of Electrical and Computer Engineering University University of Massachusetts - Amherst, Massachusetts 01003 Fall 2011 Joint Meeting Of The New England

  10. ZnMoO4: a promising bolometer for neutrinoless double beta decay searches

    E-Print Network [OSTI]

    J. W. Beeman; F. Bellini; S. Capelli; L. Cardani; N. Casali; I. Dafinei; S. Di Domizio; F. Ferroni; E. N. Galashov; L. Gironi; F. Orio; L. Pattavina; G. Pessina; G. Piperno; S. Pirro; V. N. Shlegel; Ya. V. Vasilyev; C. Tomei; M. Vignati

    2012-02-01T23:59:59.000Z

    We investigate the performances of two ZnMoO4 scintillating crystals operated as bolometers, in view of a next generation experiment to search the neutrinoless double beta decay of Mo-100. We present the results of the alpha vs beta/gamma discrimination, obtained through the scintillation light as well as through the study of the shape of the thermal signal alone. The discrimination capability obtained at the 2615 keV line of Tl-208 is 8 sigma, using the heat-light scatter plot, while it exceeds 20 sigma using the shape of the thermal pulse alone. The achieved FWHM energy resolution ranges from 2.4 keV (at 238 keV) to 5.7 keV (at 2615 keV). The internal radioactive contaminations of the ZnMoO4 crystals were evaluated through a 407 hours background measurement. The obtained limit is < 32 microBq/kg for Th-228 and Ra-226. These values were used for a Monte Carlo simulation aimed at evaluating the achievable background level of a possible, future array of enriched ZnMoO4 crystals.

  11. Interlayer growth in Mo/B{sub 4}C multilayered structures upon thermal annealing

    SciTech Connect (OSTI)

    Nyabero, S. L.; Kruijs, R. W. E. van de; Yakshin, A. E.; Zoethout, E.; Bosgra, J.; Loch, R. A. [FOM Dutch Institute for Fundamental Energy Research (DIFFER), P.O. Box 1207, 3430 BE Nieuwegein (Netherlands); Blanckenhagen, G. von [Carl Zeiss SMT GmbH, Rudolf-Eber-Strasse 2, 73447 Oberkochen (Germany); Bijkerk, F. [FOM Dutch Institute for Fundamental Energy Research (DIFFER), P.O. Box 1207, 3430 BE Nieuwegein (Netherlands); MESA Institute for Nanotechnology, University of Twente, P.O. Box 217, 7500 AE Enschede (Netherlands)

    2013-04-14T23:59:59.000Z

    Both multilayer period thickness expansion and compaction were observed in Mo/B{sub 4}C multilayers upon annealing, and the physical causes for this were explored in detail. Using in situ time-dependent grazing incidence X-ray reflectometry, period changes down to picometer-scale were resolved. It was shown that the changes depend on the thickness of the B{sub 4}C layers, annealing temperature, and annealing time. Although strong stress relaxation during annealing was observed, it was excluded as a cause for period expansion. Auger electron spectroscopy and wide angle X-ray diffraction measurements revealed the growth of interlayers, with associated period changes influenced by the supply of B and C atoms to the growing compound interlayers. For multilayers with a Mo thickness of 3 nm, two regimes were recognized, depending on the deposited B{sub 4}C thickness: in multilayers with B{sub 4}C {<=} 1.5 nm, the supply of additional Mo into the already formed MoB{sub x}C{sub y} interlayer was dominant and led to densification, resulting in period compaction. For multilayers with B{sub 4}C {>=} 2 nm, the B and C enrichment of interlayers formed low density compounds and yielded period expansion.

  12. TURBO EQUALIZATIONWITH AN UNKNOWN CHANNEL SeongwookSong', Andrew C. Singer2,Koeng-MoSun?

    E-Print Network [OSTI]

    Singer, Andrew C

    TURBO EQUALIZATIONWITH AN UNKNOWN CHANNEL SeongwookSong', Andrew C. Singer2,Koeng-MoSun? l t 2Univ the method of turbo equalization originally de- veloped by Douillard, et al. [3]. In its original form, turbo and without training data. The resultingjoint channeland data estimator is shown to outperform standard turbo

  13. TheElectronMicroscopyCore(EMC) UniversityofMissouriColumbia,MO65211

    E-Print Network [OSTI]

    Noble, James S.

    TheElectronMicroscopyCore(EMC) UniversityofMissouriColumbia,MO65211 The. The EMC houses two field emission SEM's, a Hitachi cold-field SEM (S-4700) and a FEI thermal FE SEM imaging and chemical analysis from their SEM/EDS systems. AdditionalSupportby: FormoreInformationortoregistergoto:http://www.emc

  14. RobeRt & LauRie bean taishoff inciting a MoRe incLusive

    E-Print Network [OSTI]

    McConnell, Terry

    RobeRt & LauRie bean taishoff inciting a MoRe incLusive coLLege caMpus syRacuse univeRsity scho. Thanks to her expertise--and the generosity of Robert Taishoff '86 and Laurie Bean Taishoff '84--the

  15. Incremental Development for Automotive Software in AutoMoDe Andreas Bauer1

    E-Print Network [OSTI]

    Braun, Peter

    Incremental Development for Automotive Software in AutoMoDe Andreas Bauer1 Jan Romberg1 Bernhard Validas AG 3 ETAS GmbH 4 PMSF IT Consulting 5 Robert Bosch GmbH Abstract Automotive software development. To facilitate the design and evolution of heterogeneous automotive software, suitable views for each level

  16. Interaction Layer Characteristics in U-xMo Dispersion/Monolithic Fuels

    SciTech Connect (OSTI)

    D. L. Porter

    2010-11-01T23:59:59.000Z

    Published data concerning the interaction layer (IL) formed between U-xMo fuel alloy and aluminum (Al)-based matrix or cladding materials was reviewed, including the effects of silicon (Si) content in the matrix/cladding, molybdenum (Mo) content in the fuel, pre irradiation thermal treatments, irradiation, and test temperature. The review revealed that tests conducted in the laboratory produce results different from those conducted in an irradiation environment. However, the laboratory testing relates well to thermal treatments performed prior to irradiation and helps in understanding the effects that these pre irradiation treatments have on in reactor performance. A pre-formed, Si-enriched IL seems to be important in delaying the onset of rapid growth of fission gas bubbles at low irradaiiation temperatures. Several other conclusions can be drawn: 1. An IL with phases akin to UAl3 is desired for optimum fuel performance, but at low temperatures, and especially in an irradiation atmosphere, the desired (Al+Si)/(U+Mo) ratio of three is difficult to produce. When the fuel operating temperature is low, it is important to create a pre-irradiation IL, enriched in Si. This pre-formed IL is relatively stable, performs well in terms of swelling resistance, and prevents rapid IL growth during irradiation. 2. At higher operating temperatures (>150–170°C), IL formation in reactor may not be so dependent on pre-irradiation IL formation, especially at high burnup; a pre-fabricated IL seems to be less stable at high burnup and high operating temperature. Moreover, the (Al+SI)/(U+Mo) ratio of three occurs more often at higher temperature. For these two reasons, it is important at high operating temperature to also have a matrix with significant Si content to create an IL in reactor with the right characteristics. 3. Out-of-reactor testing seems to indicate that Si in the matrix material is required in some concentration (2%, 5%, ?) to provide for a thin, Si-enriched IL formed before irradiation of a fuel plate. It ensures that the IL contains beneficial phases, or prevents formation of some known to promote poor fuel performance. Significant progress has been made in determining the desired characteristics of the IL. 4. The use of a fuel with stable gamma phase appears to allow more predictable performance regarding both a beneficial pre-irradiation layer, and the fuel performance (low swelling) to high burnup. Destabilization of the gamma phase may create problems with IL breakaway growth. 5. A theory whereby prevention of the U6Mo4Al43 complex phase in interaction layers formed during fabrication may be a key to good irradiation performance. Si additions to the matrix allow for solubility of Mo in the desirable (U,Mo)(Al,Si)3 or perhaps (U,Mo)(Al,Si)4 phase, helping to prevent formation of the complex phase. Keeping alloy Mo content as low as possible may also help so long as decomposition does not occur in fabrication, forcing Mo into the interaction layer. This theory may explain a number of apparent anomalies observed in testing results. 6. More work is needed in order to prescribe the conditions to best produce a beneficial IL. Another necessity is a better understanding of any correlation between beneficial characteristics of the pre-fabricated IL and the irradiation conditions to which it will be subjected.

  17. First-principles study of the interfacial adhesion between SiO2 and MoSi2 D. E. Jiang1 and Emily A. Carter2

    E-Print Network [OSTI]

    Carter, Emily A.

    the energy efficiency and per- formance of gas turbine engines requires structural materials able to operate on MoSi2, a potential high-temperature coating material for metals. This silica scale protects MoSi2 the potential of MoSi2 as a high-temperature structural material and coating. DOI: 10.1103/PhysRevB.72

  18. METALS AND MATERIALS International, Vol. 13, No. 6 (2007), pp. 463~468 Comparative Study on Mechanical Properties of MoSiN Multilayer Films

    E-Print Network [OSTI]

    Boo, Jin-Hyo

    2007-01-01T23:59:59.000Z

    -grown MoSiN thin films, argon and nitrogen plasmas ignited by RF and pulse DC under vacuum conditions were) and Ti-covered Si(100) substrates, as well as silicon nitride substrates. Titanium and its alloy have of a MoSi2 source in the presence of nitrogen plasma and MoSiN films have shown good thermal stability

  19. A Feasibility Study of Steelmaking by Molten Oxide Electrolysis (TRP9956)

    SciTech Connect (OSTI)

    Donald R. Sadoway; Gerbrand Ceder

    2009-12-31T23:59:59.000Z

    Molten oxide electrolysis (MOE) is an extreme form of molten salt electrolysis, a technology that has been used to produce tonnage metals for over 100 years - aluminum, magnesium, lithium, sodium and the rare earth metals specifically. The use of carbon-free anodes is the distinguishing factor in MOE compared to other molten salt electrolysis techniques. MOE is totally carbon-free and produces no CO or CO2 - only O2 gas at the anode. This project is directed at assessing the technical feasibility of MOE at the bench scale while determining optimum values of MOE operating parameters. An inert anode will be identified and its ability to sustain oxygen evalution will be demonstrated.

  20. Oxidation of propylene over copper oxide catalysts 

    E-Print Network [OSTI]

    Billingsley, David Stuart

    1958-01-01T23:59:59.000Z

    sulfate of either sodium, potassium, lithium, rubidium or cesium. The active agent was prepared in the form of a slurry which was deposited on the carrier by agitating the two materials together. The carrier was alumina or silicon carbide. Oxidation... welded on each end. On the bottom of the tank was a drain connection which was closed; the tank also contained a thermometer well. The tank was connected to the vent system through a needle valve and also through a safety valve which was set...

  1. Processing, Microstructure and Creep Behavior of Mo-Si-B-Based Intermetallic Alloys for Very High Temperature Structural Applications

    SciTech Connect (OSTI)

    Vijay Vasudevan

    2008-03-31T23:59:59.000Z

    This research project is concerned with developing a fundamental understanding of the effects of processing and microstructure on the creep behavior of refractory intermetallic alloys based on the Mo-Si-B system. In the first part of this project, the compression creep behavior of a Mo-8.9Si-7.71B (in at.%) alloy, at 1100 and 1200 C was studied, whereas in the second part of the project, the constant strain rate compression behavior at 1200, 1300 and 1400 C of a nominally Mo-20Si-10B (in at.%) alloy, processed such as to yield five different {alpha}-Mo volume fractions ranging from 5 to 46%, was studied. In order to determine the deformation and damage mechanisms and rationalize the creep/high temperature deformation data and parameters, the microstructure of both undeformed and deformed samples was characterized in detail using x-ray diffraction, scanning electron microscopy (SEM) with back scattered electron imaging (BSE) and energy dispersive x-ray spectroscopy (EDS), electron back scattered diffraction (EBSD)/orientation electron microscopy in the SEM and transmission electron microscopy (TEM). The microstructure of both alloys was three-phase, being composed of {alpha}-Mo, Mo{sub 3}Si and T2-Mo{sub 5}SiB{sub 2} phases. The values of stress exponents and activation energies, and their dependence on microstructure were determined. The data suggested the operation of both dislocation as well as diffusional mechanisms, depending on alloy, test temperature, stress level and microstructure. Microstructural observations of post-crept/deformed samples indicated the presence of many voids in the {alpha}-Mo grains and few cracks in the intermetallic particles and along their interfaces with the {alpha}-Mo matrix. TEM observations revealed the presence of recrystallized {alpha}-Mo grains and sub-grain boundaries composed of dislocation arrays within the grains (in Mo-8.9Si-7.71B) or fine sub-grains with a high density of b = 1/2<111> dislocations (in Mo-20Si-10B), which are consistent with the values of the respective stress exponents and activation energies that were obtained and provide confirmatory evidence for the operation of diffusional (former alloy) or dislocation (latter alloy) creep mechanisms. In contrast, the intermetallic phases contained very few dislocations, but many cracks. The relative contributions of the {alpha}-Mo and the intermetallic particles to the overall deformation process, including their individual and collective dependence on temperature and strain rate are discussed in light of the present results and those from previous reports.

  2. Modeling of Interaction Layer Growth Between U-Mo Particles and an Al Matrix

    SciTech Connect (OSTI)

    Yeon Soo Kim; G. L. Hofman; Ho Jin Ryu; Jong Man Park; A. B. Robinson; D. M. Wachs

    2013-12-01T23:59:59.000Z

    Interaction layer growth between U-Mo alloy fuel particles and Al in a dispersion fuel is a concern due to the volume expansion and other unfavorable irradiation behavior of the interaction product. To reduce interaction layer (IL) growth, a small amount of Si is added to the Al. As a result, IL growth is affected by the Si content in the Al matrix. In order to predict IL growth during fabrication and irradiation, empirical models were developed. For IL growth prediction during fabrication and any follow-on heating process before irradiation, out-of-pile heating test data were used to develop kinetic correlations. Two out-of-pile correlations, one for the pure Al matrix and the other for the Al matrix with Si addition, respectively, were developed, which are Arrhenius equations that include temperature and time. For IL growth predictions during irradiation, the out-of-pile correlations were modified to include a fission-rate term to consider fission enhanced diffusion, and multiplication factors to incorporate the Si addition effect and the effect of the Mo content. The in-pile correlation is applicable for a pure Al matrix and an Al matrix with the Si content up to 8 wt%, for fuel temperatures up to 200 degrees C, and for Mo content in the range of 6 – 10wt%. In order to cover these ranges, in-pile data were included in modeling from various tests, such as the US RERTR-4, -5, -6, -7 and -9 tests and Korea’s KOMO-4 test, that were designed to systematically examine the effects of the fission rate, temperature, Si content in Al matrix, and Mo content in U-Mo particles. A model converting the IL thickness to the IL volume fraction in the meat was also developed.

  3. Behavior of molybdenum nitrides as materials for electrochemical capacitors: Comparison with ruthenium oxide

    SciTech Connect (OSTI)

    Liu, T.C.; Pell, W.G.; Conway, B.E. [Univ. of Ottawa, Ontario (Canada). Dept. of Chemistry; Roberson, S.L. [North Carolina State Univ., Raleigh, NC (United States). Dept. of Materials Science and Engineering

    1998-06-01T23:59:59.000Z

    Ruthenium oxide (RuO{sub 2}), formed as a thin film on a Ru or Ti metal substrate, exhibits a large specific (cm{sup {minus}2}) and almost constant, electrochemical capacitance over a 1.35 V range in aqueous H{sub 2}SO{sub 4}. This behavior has led to its investigation and use as a material for fabrication of supercapacitor devices. However, its cost has encouraged search for other materials exhibiting similar behavior. Work reported in the present paper evaluates two nitrides of Mo, Mo{sub 2}N and MoN, as substitutes for RuO{sub 2}. It is shown that very similar capacitance behavior to that of RuO{sub 2} films arises, e.g., in cyclic voltammetry and dc charging curves; in the former, almost mirror-image anodic and cathodic current-response profiles, characteristic of a capacitor, arise. However, the nitride materials have a substantially smaller voltage operating range of only some 0.7 V due to electrochemical decomposition above ca. 0.7 V vs. RHE. This limits their usefulness as a substitute for RuO{sub 2}. Of interest is that the nitride films exhibit potential-decay and potential-recovery on open circuit after respective charge and forced discharge. The decay and recovery processes are logarithmic in time, indicating the role of internal faradaic charge redistribution processes.

  4. MAGNESIUM ISOTOPE EVIDENCE FOR SINGLE STAGE FORMATION OF CB CHONDRULES BY COLLIDING PLANETESIMALS

    SciTech Connect (OSTI)

    Olsen, Mia B.; Schiller, Martin; Krot, Alexander N.; Bizzarro, Martin [Centre for Star and Planet Formation, Natural History Museum of Denmark, University of Copenhagen, Copenhagen DK-1350 (Denmark)] [Centre for Star and Planet Formation, Natural History Museum of Denmark, University of Copenhagen, Copenhagen DK-1350 (Denmark)

    2013-10-10T23:59:59.000Z

    Chondrules are igneous spherical objects preserved in chondritic meteorites and believed to have formed during transient heating events in the solar protoplanetary disk. Chondrules present in the metal-rich CB chondrites show unusual chemical and petrologic features not observed in other chondrite groups, implying a markedly distinct formation mechanism. Here, we report high-precision Mg-isotope data for 10 skeletal olivine chondrules from the Hammadah al Hamra 237 (HH237) chondrite to probe the formation history of CB chondrules. The {sup 27}Al/{sup 24}Mg ratios of individual chondrules are positively correlated to their stable Mg-isotope composition (?{sup 25}Mg), indicating that the correlated variability was imparted by a volatility-controlled process (evaporation/condensation). The mass-independent {sup 26}Mg composition (?{sup 26}Mg*) of chondrules is consistent with single stage formation from an initially homogeneous magnesium reservoir if the observed ?{sup 25}Mg variability was generated by non-ideal Rayleigh-type evaporative fractionation characterized by a ? value of 0.5142, in agreement with experimental work. The magnitude of the mass-dependent fractionation (?300 ppm) is significantly lower than that suggested by the increase in {sup 27}Al/{sup 24}Mg values, indicating substantial suppression of isotopic fractionation during evaporative loss of Mg, possibly due to evaporation at high Mg partial pressure. Thus, the Mg-isotope data of skeletal chondrules from HH237 are consistent with their origin as melts produced in the impact-generated plume of colliding planetesimals. The inferred ?{sup 26}Mg* value of –3.87 ± 0.93 ppm for the CB parent body is significantly lower than the bulk solar system value of 4.5 ± 1.1 ppm inferred from CI chondrites, suggesting that CB chondrites accreted material comprising an early formed {sup 26}Al-free component.

  5. Notice of Construction for the Magnesium Hydroxide Precipitation Process at the Plutonium Finishing Plant (PFP)

    SciTech Connect (OSTI)

    JANSKY, M.T.

    1999-12-01T23:59:59.000Z

    The following description and any attachments and references are provided to the Washington State Department of Health (WDOH), Division of Radiation Protection, Air Emissions & Defense Waste (WAC) 246-247, Radiation Protection-Air Emissions. The WAC 246-247-060, ''Applications, registration, and licensing'', states ''This section describes the information requirements for approval to construct, modify, and operate an emission unit. Any NOC requires the submittal of information listed in Appendix A.'' Appendix A (WAC 246-247-1 10) lists the requirements that must be addressed. Additionally, the following description, attachments and references are provided to the US Environmental Protection Agency (EPA) as an NOC, in accordance with Title 40, Code of Federal Regulations (CFR), Part 61, ''National Emission Standards for Hazardous Air Pollutants.'' The information required for submittal to the EPA is specified in 40 CFR 61.07. The potential emissions from this activity are estimated to provide greater than 0.1 millirem per year total effective dose equivalent (TEDE) to the hypothetical offsite maximally exposed individual (MEI), and commencement is needed within a short time. Therefore, this application also is intended to provide notification of the anticipated date of initial startup in accordance with the requirement listed in 40 CFR 61.09(a)(1), and it is requested that approval of this application also will constitute EPA acceptance of this initial startup notification. Written notification of the actual date of initial startup, in accordance with the requirement listed in 40 CFR 61.09(a)(2) will be provided at a later date. This NOC covers the activities associated with the Construction and operation activities involving the magnesium hydroxide precipitation process of plutonium solutions within the Plutonium Finishing Plant (PFP).

  6. Enhanced mercury oxidation

    SciTech Connect (OSTI)

    Gretta, W.J.; Wu, S.; Kikkawa, H. [Hitachi Power Systems America, Basting Ridge, NJ (United States)

    2009-06-15T23:59:59.000Z

    A new catalyst offers a new way to enhance mercury control from bituminous coal-fired power plants. Hitachi has developed an SCR catalyst which satisfies high Hg{sup 0} oxidation and low SO{sub 2} oxidation requirements under high temperatures (716 to 770 F). This triple action catalysts, TRAC can significantly enhance mercury oxidation and reduce or eliminate the need for additional mercury control measures such as activated carbon injection. After laboratory testing, pilot-scale tests confirmed an activity of 1.4-1.7 times higher than that of conventional SCR catalyst. The new catalyst has been successfully applied in a commercial PRB-fired boiler without the need for halogens to be added to the fuel feed or flue gas. 2 figs.

  7. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

    1999-01-01T23:59:59.000Z

    A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

  8. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

    2001-01-01T23:59:59.000Z

    A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

  9. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, S.; Kumar, R.; Krumpelt, M.

    1999-08-24T23:59:59.000Z

    A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

  10. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, S.; Kumar, R.; Krumpelt, M.

    1999-08-17T23:59:59.000Z

    A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

  11. Low temperature oxidation of plutonium

    SciTech Connect (OSTI)

    Nelson, Art J. [Lawrence Livermore National Laboratory, Livermore, California 94551 (United States); Roussel, Paul [AWE, Aldermaston, Reading, Berkshire, RG7 4PR (United Kingdom)

    2013-05-15T23:59:59.000Z

    The initial oxidation of gallium stabilized {delta}-plutonium metal at 193 K has been followed using x-ray photoelectron spectroscopy. On exposure to Langmuir quantities of oxygen, plutonium rapidly forms a trivalent oxide followed by a tetravalent plutonium oxide. The growth modes of both oxides have been determined. Warming the sample in vacuum, the tetravalent oxide reduces to the trivalent oxide. The kinetics of this reduction reaction have followed and the activation energy has been determined to be 38.8 kJ mol{sup -1}.

  12. Characterization of Amorphous Zinc Tin Oxide Semiconductors....

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Amorphous Zinc Tin Oxide Semiconductors. Characterization of Amorphous Zinc Tin Oxide Semiconductors. Abstract: Amorphous zinc tin oxide (ZTO) was investigated to determine the...

  13. MoS{sub 2}@ZnO nano-heterojunctions with enhanced photocatalysis and field emission properties

    SciTech Connect (OSTI)

    Tan, Ying-Hua; Yu, Ke, E-mail: yk5188@263.net; Li, Jin-Zhu; Fu, Hao; Zhu, Zi-Qiang [Key Laboratory of Polar Materials and Devices (Ministry of Education of China), Department of Electronic Engineering, East China Normal University, Shanghai 200241 (China)

    2014-08-14T23:59:59.000Z

    The molybdenum disulfide (MoS{sub 2})@ZnO nano-heterojunctions were successfully fabricated through a facile three-step synthetic process: prefabrication of the ZnO nanoparticles, the synthesis of MoS{sub 2} nanoflowers, and the fabrication of MoS{sub 2}@ZnO heterojunctions, in which ZnO nanoparticles were uniformly self-assembled on the MoS{sub 2} nanoflowers by utilizing polyethyleneimine as a binding agent. The photocatalytic activities of the composite samples were evaluated by monitoring the photodegradation of methylene blue (MB). Compared with pure MoS{sub 2} nanoflowers, the composites show higher adsorption capability in dark and better photocatalytic efficiency due to the increased specific surface area and improved electron-hole pair separation. After irradiation for 100?min, the remaining MB in solution is about 7.3%. Moreover, the MoS{sub 2}@ZnO heterojunctions possess enhanced field emission properties with lower turn-on field of 3.08?V ?m{sup ?1}and lower threshold field of 6.9?V ?m{sup ?1} relative to pure MoS{sub 2} with turn-on field of 3.65?V ?m{sup ?1} and threshold field of 9.03?V ?m{sup ?1}.

  14. Chemical interaction of B{sub 4}C, B, and C with Mo/Si layered structures

    SciTech Connect (OSTI)

    Rooij-Lohmann, V. I. T. A. de; Veldhuizen, L. W.; Zoethout, E.; Yakshin, A. E.; Kruijs, R. W. E. van de [FOM Institute for Plasma Physics Rijnhuizen, P.O. Box 1207, 3430 BE Nieuwegein (Netherlands); Thijsse, B. J. [Department of Materials Science and Engineering, Delft University of Technology, Mekelweg 2, 2628 CD Delft (Netherlands); Gorgoi, M.; Schaefers, F. [Helmholtz-Zentrum Berlin fuer Materialien und Energie GmbH, BESSY II, Albert-Einstein Strasse 15, 12489 Berlin (Germany); Bijkerk, F. [FOM Institute for Plasma Physics Rijnhuizen, P.O. Box 1207, 3430 BE Nieuwegein (Netherlands); MESA Institute for Nanotechnology, University of Twente, P.O. Box 217, 7500 AE Enschede (Netherlands)

    2010-11-15T23:59:59.000Z

    To enhance the thermal stability, B{sub 4}C diffusion barrier layers are often added to Mo/Si multilayer structures for extreme ultraviolet optics. Knowledge about the chemical interaction between B{sub 4}C and Mo or Si, however is largely lacking. Therefore, the chemical processes during annealing up to 600 deg. C of a Mo/B{sub 4}C/Si layered structure have been investigated in situ with hard x-ray photoelectron spectroscopy and ex situ with depth profiling x-ray photoelectron spectroscopy. Mo/B/Si and Mo/C/Si structures have also been analyzed as reference systems. The chemical processes in these systems have been identified, with two stages being distinguished. In the first stage, B and C diffuse and react predominantly with Mo. MoSi{sub x} forms in the second stage. If the diffusion barrier consists of C or B{sub 4}C, a compound forms that is stable up to the maximum probed temperature and annealing time. We suggest that the diffusion barrier function of B{sub 4}C interlayers as reported in literature can be caused by the stability of the formed compound, rather than by the stability of B{sub 4}C itself.

  15. Tetraalklylammonium polyoxoanionic oxidation catalysts

    DOE Patents [OSTI]

    Ellis, P.E.; Lyons, J.E.; Myers, H.K. Jr.; Shaikh, S.N.

    1998-10-06T23:59:59.000Z

    Alkanes are catalytically oxidized in air or oxygen using iron-substituted polyoxoanions (POAs) of the formula: H{sub e{minus}z}[(n-C{sub 4}H{sub 9}){sub 4}N]{sub z}(XM{sub 11}M{prime}O{sub 39}){sup {minus}e}. The M{prime} (e.g., iron(III)/iron(II)) reduction potential of the POAs is affected by selection of the central atom X and the framework metal M, and by the number of tetrabutyl-ammonium groups. Decreased Fe(III)/Fe(II) reduction potential has been found to correlate to increased oxidation activity.

  16. Tetraalykylammonium polyoxoanionic oxidation catalysts

    DOE Patents [OSTI]

    Ellis, Paul E. (Downingtown, PA); Lyons, James E. (Wallingford, PA); Myers, Jr., Harry K. (Cochranville, PA); Shaikh, Shahid N. (Media, PA)

    1998-01-01T23:59:59.000Z

    Alkanes are catalytically oxidized in air or oxygen using iron-substituted polyoxoanions (POAs) of the formula: H.sub.e-z ›(n-C.sub.4 H.sub.9).sub.4 N!.sub.z (XM.sub.11 M'O.sub.39).sup.-e The M' (e.g., iron(III)/iron(II)) reduction potential of the POAs is affected by selection of the central atom X and the framework metal M, and by the number of tetrabutyl-ammonium groups. Decreased Fe(III)/Fe(II) reduction potential has been found to correlate to increased oxidation activity.

  17. Nanostructured transition metal oxides useful for water oxidation catalysis

    DOE Patents [OSTI]

    Frei, Heinz M; Jiao, Feng

    2013-12-24T23:59:59.000Z

    The present invention provides for a composition comprising a nanostructured transition metal oxide capable of oxidizing two H.sub.2O molecules to obtain four protons. In some embodiments of the invention, the composition further comprises a porous matrix wherein the nanocluster of the transition metal oxide is embedded on and/or in the porous matrix.

  18. SOLID OXIDE PLANAR AND TUBULAR SOLID OXIDE FUEL

    E-Print Network [OSTI]

    Mease, Kenneth D.

    SOLID OXIDE PLANAR AND TUBULAR SOLID OXIDE FUEL CELLS Dynamic Simulation Approach Modular Approach: Individual simulation modules for each fuel cell type · Tubular SOFC · Planar SOFC · MCFC · PEM Reformer · Slow pressure transients #12;Fuel Cell Assumptions · H2 electrochemically oxidized only · CO consumed

  19. Oxidative Reforming of Biodiesel Over Molybdenum (IV) Oxide

    E-Print Network [OSTI]

    Collins, Gary S.

    Oxidative Reforming of Biodiesel Over Molybdenum (IV) Oxide Jessica Whalen, Oscar Marin Flores, Su University INTRODUCTION Energy consumption continues to skyrocket worldwide. Biodiesel is a renewable fuel as potential feedstock in solid oxide fuel cells. Petroleum based fuels become scarcer daily, and biodiesel

  20. Epitaxial growth of few-layer MoS2(0001) on FeS2{100}

    E-Print Network [OSTI]

    Liu, T.; Temprano, I.; King, D. A.; Driver, S. M.; Jenkins, S. J.

    2014-11-13T23:59:59.000Z

    ) or self-assembled monolayers have already shown promise in delivering high quality graphene.8 Few-layer MoS2 is most commonly obtained by top-down methods such as lithium intercalation, micro mechanical exfoliation, or liquid-phase exfoliation.2 Attempts... trilayers may be terminated by complete S layers, leading to S–Fe–S–S–Mo–S layering; in this scenario, the epitaxy is driven simply by van der Waals interactions between the layers. In principle, sourcing the S atoms in the MoS2 layer from the bulk FeS2...

  1. Photoresponse properties of large-area MoS{sub 2} atomic layer synthesized by vapor phase deposition

    SciTech Connect (OSTI)

    Luo, Siwei; Qi, Xiang, E-mail: xqi@xtu.edu.cn, E-mail: jxzhong@xtu.edu.cn; Ren, Long; Hao, Guolin; Fan, Yinping; Liu, Yundan; Han, Weijia; Zang, Chen; Li, Jun; Zhong, Jianxin, E-mail: xqi@xtu.edu.cn, E-mail: jxzhong@xtu.edu.cn [Hunan Key Laboratory for Micro-Nano Energy Materials and Devices, People's Republic of China Laboratory for Quantum Engineering and Micro-Nano Energy Technology, and Faculty of Materials and Optoelectronic Physics, Xiangtan University, Hunan 411105 (China)

    2014-10-28T23:59:59.000Z

    Photoresponse properties of a large area MoS{sub 2} atomic layer synthesized by vapor phase deposition method without any catalyst are studied. Scanning electron microscopy, atomic force microscopy, Raman spectrum, and photoluminescence spectrum characterizations confirm that the two-dimensional microstructures of MoS{sub 2} atomic layer are of high quality. Photoelectrical results indicate that the as-prepared MoS{sub 2} devices have an excellent sensitivity and a good reproducibility as a photodetector, which is proposed to be ascribed to the potential-assisted charge separation mechanism.

  2. Examinations of Oxidation and Sulfidation of Grain Boundaries in Alloy 600 Exposed to Simulated Pressurized Water Reactor Primary Water

    SciTech Connect (OSTI)

    Schreiber, Daniel K.; Olszta, Matthew J.; Saxey, David W.; Kruska, Karen; Moore, K. L.; Lozano-Perez, Sergio; Bruemmer, Stephen M.

    2013-06-01T23:59:59.000Z

    High-resolution characterizations of intergranular attack in alloy 600 (Ni-17Cr-9Fe) exposed to 325 °C simulated pressurized water reactor (PWR) primary water have been conducted using a combination of scanning electron microscopy, NanoSIMS, analytical transmission electron microscopy and atom probe tomography. The intergranular attack exhibited a two-stage microstructure that consisted of continuous corrosion/oxidation to a depth of ~200 nm from the surface followed by discrete Cr-rich sulfides to a further depth of ~500 nm. The continuous oxidation region contained primarily nanocrystalline MO-structure oxide particles and ended at Ni-rich, Cr-depleted grain boundaries with spaced CrS precipitates. Three-dimensional characterization of the sulfidized region using site-specific atom probe tomography revealed extraordinary grain boundary composition changes, including total depletion of Cr across a several nm wide dealloyed zone as a result of grain boundary migration.

  3. Staged membrane oxidation reactor system

    DOE Patents [OSTI]

    Repasky, John Michael; Carolan, Michael Francis; Stein, VanEric Edward; Chen, Christopher Ming-Poh

    2013-04-16T23:59:59.000Z

    Ion transport membrane oxidation system comprising (a) two or more membrane oxidation stages, each stage comprising a reactant zone, an oxidant zone, one or more ion transport membranes separating the reactant zone from the oxidant zone, a reactant gas inlet region, a reactant gas outlet region, an oxidant gas inlet region, and an oxidant gas outlet region; (b) an interstage reactant gas flow path disposed between each pair of membrane oxidation stages and adapted to place the reactant gas outlet region of a first stage of the pair in flow communication with the reactant gas inlet region of a second stage of the pair; and (c) one or more reactant interstage feed gas lines, each line being in flow communication with any interstage reactant gas flow path or with the reactant zone of any membrane oxidation stage receiving interstage reactant gas.

  4. Staged membrane oxidation reactor system

    DOE Patents [OSTI]

    Repasky, John Michael; Carolan, Michael Francis; Stein, VanEric Edward; Chen, Christopher Ming-Poh

    2012-09-11T23:59:59.000Z

    Ion transport membrane oxidation system comprising (a) two or more membrane oxidation stages, each stage comprising a reactant zone, an oxidant zone, one or more ion transport membranes separating the reactant zone from the oxidant zone, a reactant gas inlet region, a reactant gas outlet region, an oxidant gas inlet region, and an oxidant gas outlet region; (b) an interstage reactant gas flow path disposed between each pair of membrane oxidation stages and adapted to place the reactant gas outlet region of a first stage of the pair in flow communication with the reactant gas inlet region of a second stage of the pair; and (c) one or more reactant interstage feed gas lines, each line being in flow communication with any interstage reactant gas flow path or with the reactant zone of any membrane oxidation stage receiving interstage reactant gas.

  5. Staged membrane oxidation reactor system

    DOE Patents [OSTI]

    Repasky, John Michael; Carolan, Michael Francis; Stein, VanEric Edward; Chen, Christopher Ming-Poh

    2014-05-20T23:59:59.000Z

    Ion transport membrane oxidation system comprising (a) two or more membrane oxidation stages, each stage comprising a reactant zone, an oxidant zone, one or more ion transport membranes separating the reactant zone from the oxidant zone, a reactant gas inlet region, a reactant gas outlet region, an oxidant gas inlet region, and an oxidant gas outlet region; (b) an interstage reactant gas flow path disposed between each pair of membrane oxidation stages and adapted to place the reactant gas outlet region of a first stage of the pair in flow communication with the reactant gas inlet region of a second stage of the pair; and (c) one or more reactant interstage feed gas lines, each line being in flow communication with any interstage reactant gas flow path or with the reactant zone of any membrane oxidation stage receiving interstage reactant gas.

  6. Doped zinc oxide microspheres

    DOE Patents [OSTI]

    Arnold, W.D. Jr.; Bond, W.D.; Lauf, R.J.

    1993-12-14T23:59:59.000Z

    A new composition and method of making same for a doped zinc oxide microsphere and articles made therefrom for use in an electrical surge arrestor which has increased solid content, uniform grain size and is in the form of a gel. 4 figures.

  7. Highly oxidized superconductors

    DOE Patents [OSTI]

    Morris, Donald E. (Kensington, CA)

    1994-01-01T23:59:59.000Z

    Novel superconducting materials in the form of compounds, structures or phases are formed by performing otherwise known syntheses in a highly oxidizing atmosphere rather than that created by molecular oxygen at atmospheric pressure or below. This leads to the successful synthesis of novel superconducting compounds which are thermodynamically stable at the conditions under which they are formed.

  8. Highly oxidized superconductors

    DOE Patents [OSTI]

    Morris, D.E.

    1994-09-20T23:59:59.000Z

    Novel superconducting materials in the form of compounds, structures or phases are formed by performing otherwise known synthesis in a highly oxidizing atmosphere rather than that created by molecular oxygen at atmospheric pressure or below. This leads to the successful synthesis of novel superconducting compounds which are thermodynamically stable at the conditions under which they are formed. 16 figs.

  9. Optically transparent yttrium oxide

    SciTech Connect (OSTI)

    Hartnett, T.; Greenberg, M.; Gentilman, R.L.

    1988-08-02T23:59:59.000Z

    A body is described comprising at least 99.9% yttrium oxide having a density of at least 99% of theoretically density, a sample of the body having a in-line transmission of at least 73%, over a wavelength range of 2-5 microns with the sample having a thickness of 0.375 inches.

  10. Composite materials with metal oxide attached to lead chalcogenide nanocrystal quantum dots with linkers

    DOE Patents [OSTI]

    Fuke, Nobuhiro; Koposov, Alexey Y; Sykora, Milan; Hoch, Laura

    2014-12-16T23:59:59.000Z

    Composite materials useful for devices such as photoelectrochemical solar cells include a substrate, a metal oxide film on the substrate, nanocrystalline quantum dots (NQDs) of lead sulfide, lead selenide, and lead telluride, and linkers that attach the NQDs to the metal oxide film. Suitable linkers preserve the 1s absorption peak of the NQDs. A suitable linker has a general structure A-B-C where A is a chemical group adapted for binding to a MO.sub.x and C is a chemical group adapted for binding to a NQD and B is a divalent, rigid, or semi-rigid organic spacer moiety. Other linkers that preserve the 1s absorption peak may also be used.

  11. REVIEW OF PLUTONIUM OXIDATION LITERATURE

    SciTech Connect (OSTI)

    Korinko, P.

    2009-11-12T23:59:59.000Z

    A brief review of plutonium oxidation literature was conducted. The purpose of the review was to ascertain the effect of oxidation conditions on oxide morphology to support the design and operation of the PDCF direct metal oxidation (DMO) furnace. The interest in the review was due to a new furnace design that resulted in oxide characteristics that are different than those of the original furnace. Very little of the published literature is directly relevant to the DMO furnace operation, which makes assimilation of the literature data with operating conditions and data a convoluted task. The oxidation behavior can be distilled into three regimes, a low temperature regime (RT to 350 C) with a relatively slow oxidation rate that is influenced by moisture, a moderate temperature regime (350-450 C) that is temperature dependent and relies on more or less conventional oxidation growth of a partially protective oxide scale, and high temperature oxidation (> 500 C) where the metal autocatalytically combusts and oxidizes. The particle sizes obtained from these three regimes vary with the finest being from the lowest temperature. It is surmised that the slow growth rate permits significant stress levels to be achieved that help break up the oxides. The intermediate temperatures result in a fairly compact scale that is partially protective and that grows to critical thickness prior to fracturing. The growth rate in this regime may be parabolic or paralinear, depending on the oxidation time and consequently the oxide thickness. The high temperature oxidation is invariant in quiescent or nearly quiescent conditions due to gas blanketing while it accelerates with temperature under flowing conditions. The oxide morphology will generally consist of fine particles (<15 {micro}m), moderately sized particles (15 < x < 250 {micro}m) and large particles (> 250 {micro}m). The particle size ratio is expected to be < 5%, 25%, and 70% for fine, medium and large particles, respectively, for metal temperatures in the 500-600 C range.

  12. AMoRE: Collaboration for searches for the neutrinoless double-beta decay of the isotope of {sup 100}Mo with the aid of {sup 40}Ca{sup 100}MoO{sub 4} as a cryogenic scintillation detector

    SciTech Connect (OSTI)

    Khanbekov, N. D., E-mail: xanbekov@gmail.com [Institute of Theoretical and Experimental Physics (Russian Federation)

    2013-09-15T23:59:59.000Z

    The AMoRE (Advanced Mo based Rare process Experiment) Collaboration is planning to employ {sup 40}Ca{sup 100}MoO{sub 4} single crystals as a cryogenic Scintillation detector for studying the neutrinoless double-beta decay of the isotope {sup 100}Mo. A simultaneous readout of phonon and scintillation signals is performed in order to suppress the intrinsic background. The planned sensitivity of the experiment that would employ 100 kg of {sup 40}Ca{sup 100}MoO{sub 4} over five years of data accumulation would be T{sub 1/2}{sup 0{nu}} = 3 Multiplication-Sign 10{sup 26} yr, which corresponds to values of the effective Majorana neutrino mass in the range of Left-Pointing-Angle-Bracket m{sub {nu}} Right-Pointing-Angle-Bracket {approx} 0.02-0.06 eV.

  13. Doped palladium containing oxidation catalysts

    DOE Patents [OSTI]

    Mohajeri, Nahid

    2014-02-18T23:59:59.000Z

    A supported oxidation catalyst includes a support having a metal oxide or metal salt, and mixed metal particles thereon. The mixed metal particles include first particles including a palladium compound, and second particles including a precious metal group (PMG) metal or PMG metal compound, wherein the PMG metal is not palladium. The oxidation catalyst may also be used as a gas sensor.

  14. Mesoscale Modeling and Validation of Texture Evolution during Asymmetric Rooling and Static Recrystallization of Magnesium Alloy AZ31B

    SciTech Connect (OSTI)

    Radhakrishnan, Balasubramaniam [ORNL; Gorti, Sarma B [ORNL; Stoica, Grigoreta M [ORNL; Muralidharan, Govindarajan [ORNL; Stoica, Alexandru Dan [ORNL; Wang, Xun-Li [ORNL; Specht, Eliot D [ORNL; Kenik, Edward A [ORNL; Muth, Thomas R [ORNL

    2012-01-01T23:59:59.000Z

    The focus of the present research is to develop an integrated deformation and recrystallization model for magnesium alloys at the microstructural length scale. It is known that in magnesium alloys nucleation of recrystallized grains occurs at various microstructural inhomogeneities such as twins and localized deformation bands. However, there is a need to develop models that can predict the evolution of the grain structure and texture developed during recrystallization and grain growth, especially when the deformation process follows a complicated deformation path such as in asymmetric rolling. The deformation model is based on a crystal plasticity approach implemented at the length scale of the microstructure that includes deformation mechanisms based on dislocation slip and twinning. The recrystallization simulation is based on a Monte Carlo technique that operates on the output of the deformation simulations. The nucleation criterion during recrystallization is based on the local stored energy and the Monte Carlo technique is used to simulate the growth of the nuclei due to local stored energy differences and curvature. The model predictions are compared with experimental data obtained through electron backscatter analysis and neutron diffraction.

  15. Atomistic modeling of nanowires, small-scale fatigue damage in cast magnesium, and materials for MEMS.

    SciTech Connect (OSTI)

    Dunn, Martin L. (University of Colorado, Boulder, CO); Talmage, Mellisa J. (University of Colorado, Boulder, CO); McDowell, David L., 1956- (,-Georgia Institute of Technology, Atlanta, GA); West, Neil (University of Colorado, Boulder, CO); Gullett, Philip Michael (Mississippi State University , MS); Miller, David C. (University of Colorado, Boulder, CO); Spark, Kevin (University of Colorado, Boulder, CO); Diao, Jiankuai (University of Colorado, Boulder, CO); Horstemeyer, Mark F. (Mississippi State University , MS); Zimmerman, Jonathan A.; Gall, K (Georgia Institute of Technology, Atlanta, GA)

    2006-10-01T23:59:59.000Z

    Lightweight and miniaturized weapon systems are driving the use of new materials in design such as microscale materials and ultra low-density metallic materials. Reliable design of future weapon components and systems demands a thorough understanding of the deformation modes in these materials that comprise the components and a robust methodology to predict their performance during service or storage. Traditional continuum models of material deformation and failure are not easily extended to these new materials unless microstructural characteristics are included in the formulation. For example, in LIGA Ni and Al-Si thin films, the physical size is on the order of microns, a scale approaching key microstructural features. For a new potential structural material, cast Mg offers a high stiffness-to-weight ratio, but the microstructural heterogeneity at various scales requires a structure-property continuum model. Processes occurring at the nanoscale and microscale develop certain structures that drive material behavior. The objective of the work presented in this report was to understand material characteristics in relation to mechanical properties at the nanoscale and microscale in these promising new material systems. Research was conducted primarily at the University of Colorado at Boulder to employ tightly coupled experimentation and simulation to study damage at various material size scales under monotonic and cyclic loading conditions. Experimental characterization of nano/micro damage will be accomplished by novel techniques such as in-situ environmental scanning electron microscopy (ESEM), 1 MeV transmission electron microscopy (TEM), and atomic force microscopy (AFM). New simulations to support experimental efforts will include modified embedded atom method (MEAM) atomistic simulations at the nanoscale and single crystal micromechanical finite element simulations. This report summarizes the major research and development accomplishments for the LDRD project titled 'Atomistic Modeling of Nanowires, Small-scale Fatigue Damage in Cast Magnesium, and Materials for MEMS'. This project supported a strategic partnership between Sandia National Laboratories and the University of Colorado at Boulder by providing funding for the lead author, Ken Gall, and his students, while he was a member of the University of Colorado faculty.

  16. Model catalytic oxidation studies using supported monometallic and heterobimetallic oxides

    SciTech Connect (OSTI)

    Ekerdt, J.G.

    1992-02-03T23:59:59.000Z

    This research program is directed toward a more fundamental understanding of the effects of catalyst composition and structure on the catalytic properties of metal oxides. Metal oxide catalysts play an important role in many reactions bearing on the chemical aspects of energy processes. Metal oxides are the catalysts for water-gas shift reactions, methanol and higher alcohol synthesis, isosynthesis, selective catalytic reduction of nitric oxides, and oxidation of hydrocarbons. A key limitation to developing insight into how oxides function in catalytic reactions is in not having precise information of the surface composition under reaction conditions. To address this problem we have prepared oxide systems that can be used to study cation-cation effects and the role of bridging (-O-) and/or terminal (=O) surface oxygen anion ligands in a systematic fashion. Since many oxide catalyst systems involve mixtures of oxides, we selected a model system that would permit us to examine the role of each cation separately and in pairwise combinations. Organometallic molybdenum and tungsten complexes were proposed for use, to prepare model systems consisting of isolated monomeric cations, isolated monometallic dimers and isolated bimetallic dimers supported on silica and alumina. The monometallic and bimetallic dimers were to be used as models of more complex mixed- oxide catalysts. Our current program was to develop the systems and use them in model oxidation reactions.

  17. Graphene and Graphene Oxide: Biofunctionalization and Applications...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Graphene Oxide: Biofunctionalization and Applications in Biotechnology. Graphene and Graphene Oxide: Biofunctionalization and Applications in Biotechnology. Abstract: Graphene...

  18. Model catalytic oxidation studies using supported monometallic and heterobimetallic oxides

    SciTech Connect (OSTI)

    Ekerdt, J.G.

    1991-04-30T23:59:59.000Z

    This research program is directed toward developing a fundamental understanding of how catalyst composition, redox ability, and structure control the catalytic properties of metal oxides. Oxide systems that permit examination of the role of metal oxide cations separately and in pairwise combinations are being developed. Organometallic complexes containing C{sub 3}-allyl, cyclopentadienyl, or carbonyl ligands are exchanged with the hydroxide ligands of silica, alumina, titania, zirconia and magnesia supports. The exchange technique is used to achieve high metal oxide loadings without the formation of supported crystallites over silica. The organometallic route may also lead to oxygen-bridged cations and/or cation pairs over the supports prior to full oxidation. The anchored complex is subsequently oxidized to generate a supported oxide. 2 refs., 1 tab.

  19. Brittle Fracture in a 50Mo-50Re alloy in static tensile testing

    SciTech Connect (OSTI)

    Xu, Jianhui [University of Kentucky, Lexington; Kenik, Edward A [ORNL; Zhai, Tongguang [University of Kentucky, Lexington

    2008-01-01T23:59:59.000Z

    Tensile tests were conducted on 50Mo-50Re alloys, in fully-recrystallized and recovery heat-treated conditions respectively, at a very low strain rate of 10-6 s-1 and room temperature in air. It was found that both these alloys exhibited predominantly cleavage fracture with significant intergranular secondary cracking, compared to the predominantly ductile fracture found in the alloys at a higher strain rate. Cracks were often initiated at grain boundary triple junctions at the low strain rate. Electron back scatter diffraction (EBSD) measurements revealed significantly high misorientation gradients at grain boundaries, especially in the vicinity of some grain boundary triple junctions in the deformed alloys. Transmission electron microscopic (TEM) results verified the existence of significant misorientation taking place at grain boundaries in these alloys. Stress-assisted dynamic embrittlement, possibly due to trace interstitials, was the possible cause for the occurrence of brittle fracture in the 50Mo-50Re alloys at the low strain rate.

  20. Spectroscopy of Double-Beta and Inverse-Beta Decays from 100Mo for Neutrinos

    E-Print Network [OSTI]

    H. Ejiri; J. Engel; R. Hazama; P. Krastev; N. Kudomi; R. G. H. Robertson

    2000-05-15T23:59:59.000Z

    Spectroscopic studies of two beta-rays from 100Mo are shown to be of potential interest for investigating both the Majorana neutrino mass by neutrinoless double beta-decay and low energy solar neutrino's by inverse beta-decay. With a multi-ton 100Mo detector, coincidence studies of correlated beta-beta from neutrinoless double beta-decay, together with the large Q value, permit identification of the neutrino-mass term with a sensitivity of ~ 0.03 eV. Correlation studies of the inverse beta and the successive beta-decay of 100Tc, together with the large capture rates for low energy solar neutrino's, make it possible to detect in realtime individual low energy solar neutrino in the same detector.

  1. Air damping of atomically thin MoS{sub 2} nanomechanical resonators

    SciTech Connect (OSTI)

    Lee, Jaesung; Wang, Zenghui; Feng, Philip X.-L., E-mail: philip.feng@case.edu [Department of Electrical Engineering and Computer Science, Case School of Engineering, Case Western Reserve University, 10900 Euclid Avenue, Cleveland, Ohio 44106 (United States); He, Keliang; Shan, Jie [Department of Physics, College of Arts and Sciences, Case Western Reserve University, 10900 Euclid Avenue, Cleveland, Ohio 44106 (United States)

    2014-07-14T23:59:59.000Z

    We report on experimental measurement of air damping effects in high frequency nanomembrane resonators made of atomically thin molybdenum disulfide (MoS{sub 2}) drumhead structures. Circular MoS{sub 2} nanomembranes with thickness of monolayer, few-layer, and multi-layer up to ?70?nm (?100 layers) exhibit intriguing pressure dependence of resonance characteristics. In completely covered drumheads, where there is no immediate equilibrium between the drum cavity and environment, resonance frequencies and quality (Q) factors strongly depend on environmental pressure due to bulging of the nanomembranes. In incompletely covered drumheads, strong frequency shifts due to compressing-cavity stiffening occur above ?200?Torr. The pressure-dependent Q factors are limited by free molecule flow (FMF) damping, and all the mono-, bi-, and tri-layer devices exhibit lower FMF damping than thicker, conventional devices do.

  2. Improved performance of U-Mo dispersion fuel by Si addition in Al matrix.

    SciTech Connect (OSTI)

    Kim, Y S; Hofman, G L [Nuclear Engineering Division

    2011-06-01T23:59:59.000Z

    The purpose of this report is to collect in one publication and fit together work fragments presented in many conferences in the multi-year time span starting 2002 to the present dealing with the problem of large pore formation in U-Mo/Al dispersion fuel plates first observed in 2002. Hence, this report summarizes the excerpts from papers and reports on how we interpreted the relevant results from out-of-pile and in-pile tests and how this problem was dealt with. This report also provides a refined view to explain in detail and in a quantitative manner the underlying mechanism of the role of silicon in improving the irradiation performance of U-Mo/Al.

  3. Fission induced swelling and creep of U–Mo alloy fuel

    SciTech Connect (OSTI)

    Yeon Soo Kim; G. L. Hofman; J. S. Cheon; A. B. Robinson; D. M. Wachs

    2013-06-01T23:59:59.000Z

    Tapering of U–Mo alloy fuel at the end of plates is attributed to lateral mass transfer by fission induced creep, by which fuel mass is relocated away from the fuel end region where fission product induced fuel swelling is in fact the highest. This mechanism permits U–Mo fuel to achieve high burnup by effectively relieving stresses at the fuel end region, where peak stresses are otherwise expected because peak fission product induced fuel swelling occurs there. ABAQUS FEA was employed to examine whether the observed phenomenon can be simulated using physical–mechanical data available in the literature. The simulation results obtained for several plates with different fuel fabrication and loading scheme showed that the measured data were able to be simulated with a reasonable creep rate coefficient. The obtained creep rate constant lies between values for pure uranium and MOX, and is greater than all other ceramic uranium fuels.

  4. Induced codeposition. 1: An experimental investigation of Ni-Mo alloys

    SciTech Connect (OSTI)

    Podlaha, E.J.; Landolt, D. [Ecole Polytechnique Federale de Lausanne (Switzerland)

    1996-03-01T23:59:59.000Z

    The electrodeposition of nickel-molybdenum alloys was studied on rotating cylinder electrodes. The current density, electrode rotation rate, electrolyte temperature, and species concentrations were shown to influence alloy composition. The mass-transport limiting species were identified for different operating conditions and electrolyte compositions in order to study the rate-limiting steps of induced codeposition. If the concentration of nickel in the electrolyte was much larger than that of molybdate the molybdenum content in the alloy increased with rotation rate. On the other hand, if the concentration of molybdate in the electrolyte was larger than that of nickel the alloy composition was found to be independent of rotation rate. These results were applied to the deposition of compositionally modulated Ni-Mo alloys exhibiting larger periodic variations in Mo concentration than hitherto reported.

  5. Phase transitions in K-doped MoO{sub 2}

    SciTech Connect (OSTI)

    Alves, L. M. S., E-mail: leandro-fisico@hotmail.com; Lima, B. S. de; Santos, C. A. M. dos [Departamento de Engenharia de Materiais, Escola de Engenharia de Lorena-USP, Lorena, São Paulo 12602-810 (Brazil); Rebello, A.; Masunaga, S. H.; Neumeier, J. J. [Department of Physics, Montana State University, P.O. Box 173840, Bozeman, Montana 59717-3840 (United States); Leão, J. B. [NIST Center for Neutron Research, National Institute of Standards and Technology, 100 Bureau Dr. MS 6102, Gaithersburg, Maryland 20899-6102 (United States)

    2014-05-28T23:59:59.000Z

    K{sub 0.05}MoO{sub 2} has been studied by x-ray and neutron diffractometry, electrical resistivity, magnetization, heat capacity, and thermal expansion measurements. The compound displays two phase transitions, a first-order phase transition near room temperature and a second-order transition near 54?K. Below the transition at 54?K, a weak magnetic anomaly is observed and the electrical resistivity is well described by a power-law temperature dependence with exponent near 0.5. The phase transitions in the K-doped MoO{sub 2} compound have been discussed for the first time using neutron diffraction, high resolution thermal expansion, and heat capacity measurements as a function of temperature.

  6. LEXICAL DECISION IN A PHONOLOGICALLY SHALLOW ORTHOGRAPHY* G Lukatela+, Do Popadic+, P. Ognjenovic+, and Mo To Turvey++

    E-Print Network [OSTI]

    +, and Mo To Turvey++ Abstracto The Serbo-Croatian language is written in two alphabets, Roman and Cyrillic shallow writing systems of Serbo-Croatian, lex ical decision proceeds with reference to the phonology

  7. Performance of ZnMoO4 crystal as cryogenic scintillating bolometer to search for double beta decay of molybdenum

    E-Print Network [OSTI]

    L. Gironi; C. Arnaboldi; J. W. Beeman; O. Cremonesi; F. A. Danevich; V. Ya. Degoda; L. I. Ivleva; L. L. Nagornaya; M. Pavan; G. Pessina; S. Pirro; V. I. Tretyak; I. A. Tupitsyna

    2010-10-01T23:59:59.000Z

    Zinc molybdate (ZnMoO4) single crystals were grown for the first time by the Czochralski method and their luminescence was measured under X ray excitation in the temperature range 85-400 K. Properties of ZnMoO4 crystal as cryogenic low temperature scintillator were checked for the first time. Radioactive contamination of the ZnMoO4 crystal was estimated as <0.3 mBq/kg (228-Th) and 8 mBq/kg (226-Ra). Thanks to the simultaneous measurement of the scintillation light and the phonon signal, the alpha particles can be discriminated from the gamma/beta interactions, making this compound extremely promising for the search of neutrinoless Double Beta Decay of 100-Mo. We also report on the ability to discriminate the alpha-induced background without the light measurement, thanks to a different shape of the thermal signal that characterizes gamma/beta and alpha particle interactions.

  8. High yield production of inorganic graphene-like materials (MoS?, WS?, BN) through liquid exfoliation testing key parameters

    E-Print Network [OSTI]

    Pu, Fei, S.B. Massachusetts Institute of Technology

    2012-01-01T23:59:59.000Z

    Inorganic graphene-like materials such as molybdenum disulfide (MoS?), tungsten sulfide (WS?), and boron nitride (BN) are known to have electronic properties. When exfoliated into layers and casted onto carbon nanofilms, ...

  9. Two photon absorption and its saturation of WS2 and MoS2 monolayer and few-layer films

    E-Print Network [OSTI]

    Zhang, Saifeng; McEvoy, Niall; O'Brien, Maria; Winters, Sinéad; Berner, Nina C; Yim, Chanyoung; Zhang, Xiaoyan; Chen, Zhanghai; Zhang, Long; Duesberg, Georg S; Wang, Jun

    2015-01-01T23:59:59.000Z

    The optical nonlinearity of WS2, MoS2 monolayer and few-layer films was investigated using the Z-scan technique with femtosecond pulses from the visible to the near infrared. The dependence of nonlinear absorption of the WS2 and MoS2 films on layer number and excitation wavelength was studied systematically. WS2 with 1~3 layers exhibits a giant two-photon absorption (TPA) coefficient. Saturation of TPA for WS2 with 1~3 layers and MoS2 with 25~27 layers was observed. The giant nonlinearity of WS2 and MoS2 is attributed to two dimensional confinement, a giant exciton effect and the band edge resonance of TPA.

  10. Quantitative Prediction of Surface Segregation in Bimetallic Pt-MAlloy Nanoparticles (M=Ni, Re, Mo)

    SciTech Connect (OSTI)

    Wang, Guofeng; Van Hove, Michel A.; Ross, Phil N.; Baskes,Michael I.

    2005-06-20T23:59:59.000Z

    This review addresses the issue of surface segregation inbimetallic alloy nanoparticles, which are relevant to heterogeneouscatalysis, in particular for electro-catalysts of fuel cells. We describeand discuss a theoretical approach to predicting surface segregation insuch nanoparticles by using the Modified Embedded Atom Method and MonteCarlo simulations. In this manner it is possible to systematicallyexplore the behavior of such nanoparticles as a function of componentmetals, composition, and particle size, among other variables. We choseto compare Pt75Ni25, Pt75Re25, and Pt80Mo20 alloys as example systems forthis discussion, due to the importance of Pt in catalytic processes andits high-cost. It is assumed that the equilibrium nanoparticles of thesealloys have a cubo-octahedral shape, the face-centered cubic lattice, andsizes ranging from 2.5 nm to 5.0 nm. By investigating the segregation ofPt atoms to the surfaces of the nanoparticles, we draw the followingconclusions from our simulations at T= 600 K. (1) Pt75Ni25 nanoparticlesform a surface-sandwich structure in which the Pt atoms are stronglyenriched in the outermost and third layers while the Ni atoms areenriched in the second layer. In particular, a nearly pure Pt outermostsurface layer can be achieved in those nanoparticles. (2) EquilibriumPt75Re25 nanoparticles adopt a core-shell structure: a nearly pure Ptshell surrounding a more uniform Pt-Re core. (3) In Pt80Mo20nanoparticles, the facets are fully occupied by Pt atoms, the Mo atomsonly appear at the edges and vertices, and the Pt and Mo atoms arrangethemselves in an alternating sequence along the edges and vertices. Oursimulations quantitatively agree with previous experimental andtheoretical results for the extended surfaces of Pt-Ni, Pt-Re, and Pt-Moalloys. We further discuss the reasons for the different types of surfacesegregation found in the different alloys, and some of theirimplications.

  11. Co-Rolled U10Mo/Zirconium-Barrier-Layer Monolithic Fuel Foil Fabrication Process

    SciTech Connect (OSTI)

    G. A. Moore; M. C. Marshall

    2010-01-01T23:59:59.000Z

    Integral to the current UMo fuel foil processing scheme being developed at Idaho National Laboratory (INL) is the incorporation of a zirconium barrier layer for the purpose of controlling UMo-Al interdiffusion at the fuel-meat/cladding interface. A hot “co-rolling” process is employed to establish a ~25-µm-thick zirconium barrier layer on each face of the ~0.3-mm-thick U10Mo fuel foil.

  12. An internship with San Tomas hunting camp Freeport-McMoRan, Inc. 

    E-Print Network [OSTI]

    Huggins, J. Grant

    1986-01-01T23:59:59.000Z

    An Internship with San Tomas Hunting Camp Freeport~NoRan, Inc. : A PRCFESSIQRAL PAPER by J. Grant Huggine Submitted to the College of Agriculture of Texas AN University in Rmrtial fulfillment of the requirements for the degree of NASTER GF... AGRICULTURE December 1986 Najor Subject: Wildlife Science Department of Wildife and Fisheries Sciences An Internship with San Tomas Hunting Camp Fr eeport-McMoRan, Inc. by J. Grant Huggins Approved as to style and content by: Wallace G. Klussmann...

  13. AutoMoDe - Model-Based Development of Automotive Software

    E-Print Network [OSTI]

    Ziegenbein, Dirk; Freund, Ulrich; Bauer, Andreas; Romberg, Jan; Schatz, Bernhard

    2011-01-01T23:59:59.000Z

    This paper describes first results from the AutoMoDe (Automotive Model-Based Development) project. The overall goal of the project is to develop an integrated methodology for model-based development of automotive control software, based on problem-specific design notations with an explicit formal foundation. Based on the existing AutoFOCUS framework, a tool prototype is being developed in order to illustrate and validate the key elements of our approach.

  14. Mo-Al{sub 2}O{sub 3} cermet research and development

    SciTech Connect (OSTI)

    Glass, S.J.; Monroe, S.L.; Stephens, J.J.; Moore, R.H. [and others

    1997-08-01T23:59:59.000Z

    This report describes the results to date of a program that was initiated to predict and measure residual stresses in Mo-Al{sub 2}O{sub 3} cermet-containing components and to develop new materials and processes that would lead to the reduction or elimination of the thermal mismatch stresses. The period of performance includes work performed CY95-97. Excessive thermal mismatch stresses had produced cracking in some cermet-containing neutron tube components. This cracking could lead to a loss of hermeticity or decreased tube reliability. Stress predictions were conducted using finite element models of the various components, along with the thermal coefficient of expansion (CTE), Young`s modulus, and strength properties. A significant portion of the program focused on the property measurements for the existing cermet materials, processing conditions, and the measurement technique. The effects of differences in the properties on the predicted residual stresses were calculated for existing designs. Several potential approaches were evaluated for reducing the residual stresses and cracking in cermet-containing parts including reducing the Mo content of the cermet, substituting a ternary alloy with a better CTE match with alumina, and substituting Nb for Mo. Processing modifications were also investigated for minimizing warpage that occurs during sintering due to differential sintering. These modifications include changing the pressing of the 94ND2 alumina and changing to a 96% alumina powder from AlSiMag.

  15. Effect of heat treatment on the mechanical properties of modified 9Cr-1Mo steel

    SciTech Connect (OSTI)

    Sultan F. Alsagabi; Triratna Shrestha; Indrajit Charit; Gabriel P. Potirniche; Michael V. Glazoff

    2014-09-01T23:59:59.000Z

    The modified 9Cr-1Mo steel (Grade 91) is a material of choice in fossil-fuel-fired power plants with increased efficiency, service life, and reduction in emission of greenhouse gases. It is also considered a prospective material for the Next Generation Nuclear Power Plant for application in reactor pressure vessels at temperatures up to 650°C. In this paper, heat treatment of the modified 9Cr-1Mo steel was studied by normalizing and tempering the steel at various temperatures and times, with the ultimate goal of improving its creep resistance and optimizing material hardness. The microstructural evolution of the heat treated steels was correlated with the differential scanning calorimetric results. Optical microscopy, scanning and transmission electron microscopy in conjunction with microhardness profiles and calorimetric plots were used to understand the evolution of microstructure including precipitate structures in modified 9Cr-1Mo steel and relate it to the mechanical behavior of the steel. Thermo- CalcTM calculations were used to support experimental work and provide guidance in terms of the precipitate stability and microstructural evolution. Furthermore, the carbon isopleth and temperature dependencies of the volume fraction of different precipitates were constructed. The predicted and experimentally observed results were found to be in good agreement.

  16. Evolution of collectivity along the N=Z line: The {sup 84}Mo nucleus

    SciTech Connect (OSTI)

    Bucurescu, D.; Ur, C.A.; Marginean, N.; Ionescu-Bujor, M.; Iordachescu, A.; Petrache, C.M. [Horia Hulubei National Institute of Physics and Nuclear Engineering, Bucharest (Romania)] [Horia Hulubei National Institute of Physics and Nuclear Engineering, Bucharest (Romania); Ur, C.A; Bazzacco, D.; Lunardi, S.; Petrache, C.M.; Brandolini, F.; Falconi, G.; Lenzi, S.M.; Venturelli, R. [Dipartimento di Fisica dellUniversita and INFN, Sezione di Padova, Padova (Italy)] [Dipartimento di Fisica dellUniversita and INFN, Sezione di Padova, Padova (Italy); Napoli, D.R.; de Angelis, G.; Gadea, A.; Foltescu, D.; Farnea, E.; Podolyak, Zs.; De Poli, M. [INFN, Laboratori Nazionali di Legnaro, Legnaro (Italy)] [INFN, Laboratori Nazionali di Legnaro, Legnaro (Italy); Rao, M.N. [Universidade de Sao Paolo, Sao Paolo, Brasil (Brazil)] [Universidade de Sao Paolo, Sao Paolo, Brasil (Brazil)

    1997-11-01T23:59:59.000Z

    The reaction {sup 58}Ni({sup 28}Si,2n{gamma}) at 90 MeV incident energy has been used to populate the N=Z nucleus {sup 84}Mo. The GASP array was used together with the ISIS Silicon ball, which allowed a subtraction of the charged particle channels in the {gamma}-{gamma} coincidences. The only known transition 2{sub 1}{sup +}{r_arrow}0{sub 1}{sup +} of 443.8 keV in {sup 84}Mo has been found in coincidence with a {gamma} ray of 673.5{plus_minus}0.4 keV which was assigned as the second (4{sub 1}{sup +}{r_arrow}2{sub 1}{sup +}) yrast transition. The behavior of the resulting yrast line indicates that {sup 84}Mo is a transitional nucleus. The correlation between the excitation energies of the 2{sub 1}{sup +} and 4{sub 1}{sup +} levels of the N=Z nuclei reveals a systematic deviation from the average behavior defined by all collective even-even nuclei. {copyright} {ital 1997} {ital The American Physical Society}

  17. Superconducting and structural properties of {delta}-MoC{sub 0.681} cubic molybdenum carbide phase

    SciTech Connect (OSTI)

    Sathish, C.I. [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan) [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan); Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Guo, Yanfeng, E-mail: GUO.Yanfeng@nims.go.jp [Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)] [Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Wang, Xia [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan) [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan); Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Tsujimoto, Yoshihiro [International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)] [International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Li, Jun [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan) [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan); Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Zhang, Shoubao [International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)] [International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Matsushita, Yoshitaka [Synchrotron X-ray Station at SPring-8, National Institute for Materials Science, 1-1-1 Kouto, Sayo-cho, Hyogo 679-5148 (Japan)] [Synchrotron X-ray Station at SPring-8, National Institute for Materials Science, 1-1-1 Kouto, Sayo-cho, Hyogo 679-5148 (Japan); Shi, Youguo; Tian, Huanfang; Yang, Huaixin; Li, Jianqi [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China)] [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Yamaura, Kazunari, E-mail: YAMAURA.Kazunari@nims.go.jp [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan) [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan); Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)

    2012-12-15T23:59:59.000Z

    The superconducting and lattice properties of {delta}-MoC{sub 0.681} were studied by electromagnetic measurements, synchrotron X-ray diffraction, neutron diffraction, and electron diffraction. The superconducting properties (T{sub c}=12 K) of {delta}-MoC{sub 0.681} were well characterized by a weak coupling model. The carbon vacancies present in the host cubic structure were found to be robust, although the material was synthesized from stoichiometric carbon and Mo powder under a high-pressure of 6 GPa. A thermodynamically-stable structure with ordered vacancies did not account for the robust features of {delta}-MoC{sub 0.681} since the vacancies are unlikely to be ordered in long range in the host structure. A model based on inherent phonon instability theoretically predicted for a stoichiometric MoC phase might be responsible for the robust features of {delta}-MoC{sub 0.681}. - Graphical Abstract: The cubic molybdenum carbide shows an excellent superconductivity with robust carbon vacancies. Inherent phonon instability theoretically predicted for a stoichiometric MoC phase might be responsible for the vacancies rather than a thermodynamically-stable structure with vacancies ordering. Highlights: Black-Right-Pointing-Pointer The 12 K superconductivity is well characterized by a weakly coupling model. Black-Right-Pointing-Pointer Carbon vacancies are robust and disordered in the cubic host structure. Black-Right-Pointing-Pointer Inherent phonon instability might be responsible for the robust carbon vacancies in {delta}-MoC{sub 0.681}.

  18. Low-frequency 1/f noise in MoS{sub 2} transistors: Relative contributions of the channel and contacts

    SciTech Connect (OSTI)

    Renteria, J.; Jiang, C. [Nano-Device Laboratory, Department of Electrical Engineering, Bourns College of Engineering, University of California – Riverside, Riverside, California 92521 (United States); Samnakay, R. [Materials Science and Engineering Program, Bourns College of Engineering, University of California – Riverside, Riverside, California 92521 (United States); Rumyantsev, S. L. [Department of Electrical, Computer, and Systems Engineering, Center for Integrated Electronics, Rensselaer Polytechnic Institute, Troy, New York 12180 (United States); Ioffe Physical-Technical Institute, St. Petersburg 194021 (Russian Federation); Goli, P.; Balandin, A. A., E-mail: balandin@ee.ucr.edu [Nano-Device Laboratory, Department of Electrical Engineering, Bourns College of Engineering, University of California – Riverside, Riverside, California 92521 (United States); Materials Science and Engineering Program, Bourns College of Engineering, University of California – Riverside, Riverside, California 92521 (United States); Shur, M. S. [Department of Electrical, Computer, and Systems Engineering, Center for Integrated Electronics, Rensselaer Polytechnic Institute, Troy, New York 12180 (United States)

    2014-04-14T23:59:59.000Z

    We report on the results of the low-frequency (1/f, where f is frequency) noise measurements in MoS{sub 2} field-effect transistors revealing the relative contributions of the MoS{sub 2} channel and Ti/Au contacts to the overall noise level. The investigation of the 1/f noise was performed for both as fabricated and aged transistors. It was established that the McWhorter model of the carrier number fluctuations describes well the 1/f noise in MoS{sub 2} transistors, in contrast to what is observed in graphene devices. The trap densities extracted from the 1/f noise data for MoS{sub 2} transistors, are 2?×?10{sup 19}?eV{sup ?1}cm{sup ?3} and 2.5?×?10{sup 20}?eV{sup ?1}cm{sup ?3} for the as fabricated and aged devices, respectively. It was found that the increase in the noise level of the aged MoS{sub 2} transistors is due to the channel rather than the contact degradation. The obtained results are important for the proposed electronic applications of MoS{sub 2} and other van der Waals materials.

  19. JOM Volume 63, Number 2 (2011): 48-52 High strain rate compressive response of magnesium-aluminum alloy/fly ash cenosphere composites

    E-Print Network [OSTI]

    Gupta, Nikhil

    2011-01-01T23:59:59.000Z

    , and sound and vibration damping. Low strength of open and closed-cell foams containing gas porosity distribution in syntactic foams is usually much more uniform compared to the gas filled foams. Presence half of which is dumped in landfills. In the present work, a cast magnesium-aluminum alloy, AZ91D

  20. Electron-Atom Superelastic Scattering in Magnesium at Millielectron Volt Energies T. Baynard, A. C. Reber, R. F. Niedziela,| S. A. Darveau, B. Prutzman,# and R. S. Berry*,

    E-Print Network [OSTI]

    Berry, R. Stephen

    Electron-Atom Superelastic Scattering in Magnesium at Millielectron Volt Energies T. Baynard, A. C ReceiVed: July 17, 2007; In Final Form: September 16, 2007 The energy dependence of superelastic electron source to collide with excited atoms. Measurements are made at energies as low as 1.5 me