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Note: This page contains sample records for the topic "mo magnesium oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

IMPROVED MAGNESIUM OXIDE SLIP CASTING METHOD  

DOE Patents (OSTI)

A process for making an aqueous magnesium oxide slip casting slurry comprising the steps of mixing finely ground fused magnesium oxide with water, milling the slurry for at least 30 hours at a temperature of 2-10 deg C (the low temperature during milling inhibiting the formation of hydrated magnesium oxide), discharging the slurry from the mill, adding hydrochloric acid as a deflocculent, and adding a scum inhibitor is presented. (AEC)

Stoddard, S.D.; Nuckolls, D.E.

1963-12-31T23:59:59.000Z

2

Nuclear reactor shield including magnesium oxide  

DOE Patents (OSTI)

An improvement in nuclear reactor shielding of a type used in reactor applications involving significant amounts of fast neutron flux, the reactor shielding including means providing structural support, neutron moderator material, neutron absorber material and other components as described below, wherein at least a portion of the neutron moderator material is magnesium in the form of magnesium oxide either alone or in combination with other moderator materials such as graphite and iron.

Rouse, Carl A. (Del Mar, CA); Simnad, Massoud T. (La Jolla, CA)

1981-01-01T23:59:59.000Z

3

Adsorption of Propane on the Magnesium Oxide (100) Surface and Synthesis of Anodized Aluminum Oxide.  

E-Print Network (OSTI)

??This work is divided into two parts: the adsorption of propane on the magnesium oxide (100) surface and the synthesis of anodized aluminum oxide. The… (more)

Felty, Michael John

2008-01-01T23:59:59.000Z

4

Magnesium oxide inserts for the LECO Carbon Analyzer  

Science Conference Proceedings (OSTI)

LECO carbon analysis of plutonium metal and plutonium oxide at the Rocky Flats Plant generates several hundred kilograms of high silica residues each year. The plutonium in these residues is difficult and expensive to recover using production dissolution processes. A magnesium oxide (MgO) insert has been developed that significantly lowers the plutonium recovery costs without adversely affecting accuracy of the carbon analysis.

Bagaasen, L.M.; Jensen, C.M.

1991-01-16T23:59:59.000Z

5

Near Net-Shaped Magnesium Aluminate Spinel by the Oxidation of ...  

Science Conference Proceedings (OSTI)

The ductile magnesium can endow the precursor with the green strength ..... by Oxidation of Melt Spun Ag-Ho-Ba-Cu Alloy Ribbon," Jpn. J. Appl. Phys., 27[2] ...

6

Improved efficiency in the sulfur dioxide-iodine hydrogen cycle through the use of magnesium oxide  

DOE Green Energy (OSTI)

The reaction of iodine with dry magnesium oxide and magnesium sulfite hexahydrate was studied experimentally as a possible means of improving the efficiency of the sulfur dioxide-iodine cycle. When no extra water was introduced, the maximum product yield was 67% obtained at 423 K. With excess water vapor, a nonporous plug was formed which prevented complete reaction. In the second case, maximum yield was 62% measured at 433 K showing that added water does not increase reaction products. This reaction gives an alternate route for producing hydrogen from water via the sulfur dioxide-iodine process.

Mason, C.F.V.; Bowman, M.G.

1981-01-01T23:59:59.000Z

7

The oxidation of Ba dosed Mo(100) surfaces with O/sub 2/ at moderately high temperatures  

DOE Green Energy (OSTI)

The oxidation of Mo(100) and Ba-covered Mo(100) by O/sub 2/ have been examined at moderately high temperature (700 to 1400/sup 0/K) using x-ray photoelectron spectroscopy. Results indicate that the Ba or BaO overlayer retards but does not prevent oxidation of the underlying Mo surface. The high temperature surface chemistry of the O/Ba/Mo surface is described. 11 refs., 3 figs.

Rogers, J.W. Jr.; Blair, D.S.; Paffett, M.T.

1987-01-01T23:59:59.000Z

8

MAGNESIUM OXIDE AN ENGINEERED BARRIER 2009 EPA WIPP RECERTIFICATION FACT SHEET United States Environmental Protection Agency | Office of Air and Radiation (6608J) | June 2009  

E-Print Network (OSTI)

MAGNESIUM OXIDE ­ AN ENGINEERED BARRIER 2009 EPA WIPP RECERTIFICATION FACT SHEET United States Environmental Protection Agency | Office of Air and Radiation (6608J) | June 2009 http://www.epa.gov/radiation/wipp/index.html MAGNESIUM OXIDE ­ AN ENGINEERED BARRIER Why is MgO Used At WIPP? The U.S. Department of Energy (DOE

9

The optical properties of magnesium oxide containing transition metal ions and defects produced by fast neutron irradiation  

Science Conference Proceedings (OSTI)

The photoluminescence (PL), its excitation (PLE) and optical absorption of MgO crystals containing transition metal ions and defects produced by fast neutron irradiation fluence up to 1020cm-2 (E>0.1 MeV) are investigated. Three ... Keywords: absorption, luminescence spectra, magnesium oxide, radiation defect, transition metal ions

Vera Skvortsova; Laima Trinkler

2010-11-01T23:59:59.000Z

10

Carbon Steel and Magnesium Oxide Dissolution for H-Canyon Process Applications  

DOE Green Energy (OSTI)

H Area Operations is planning to process plutonium-contaminated uranium metal scrap in its efforts to de-inventory excess nuclear materials. The Savannah River Technology Center (SRTC) performed flowsheet development to support the decision to process the scrap in H-Canyon using 2M nitric acid (HNO3) / 0.025M potassium fluoride (KF) and 2 g/L boron. The scrap will be charged to the H-Canyon dissolver via a stainless steel charging bundle with a carbon steel end cap that must dissolve in an appropriate time frame. Experimental work was performed with a range of potential materials to be used to fabricate the bundle end cap. Testing was conducted with samples of metal plate, wire, cans, rods, and rivets to assess their dissolution characteristics in 2M HNO3/ 0.025M KF and 2 g/L boron. Experiments also measured the amount of hydrogen gas generated during carbon steel dissolution using the above dissolver solution. Each material type and its associated dissolution characteristic relate to specific bundle end cap designs being considered. Supplemental studies were conducted to evaluate the behavior and effect of magnesium oxide (MgO) sand on dissolution of uranium metal in 2M HNO3/ 0.025M KF and 2 g/L boron. The potential exists for a small quantity of MgO to be introduced into the dissolution flowsheet due to the use of MgO sand to extinguish uranium metal fires.

PIERCE, RA

2004-04-12T23:59:59.000Z

11

A practical grinding-assisted dry synthesis of nanocrystalline NiMoO{sub 4} polymorphs for oxidative dehydrogenation of propane  

Science Conference Proceedings (OSTI)

A practical two-stage reactive grinding-assisted pathway waste-free and cost-effective for the synthesis of NiMoO{sub 4} has been successfully developed. It was demonstrated that proper design in synthetic strategy for grinding plays a crucial role in determining the ultimate polymorph of NiMoO{sub 4}. Specifically, direct grinding (DG) of MoO{sub 3} and NiO rendered {alpha}-NiMoO{sub 4} after annealing, whereas sequential grinding (SG) of the two independently pre-ground oxides followed by annealing generated {beta}-NiMoO{sub 4} solid solution. Characterizations in terms of Raman and X-ray diffraction suggest the creation of {beta}-NiMoO{sub 4} precursor in the latter alternative is the key aspect for the formation of {beta}-NiMoO{sub 4}. The DG-derived {alpha}-NiMoO{sub 4} tested by oxidative dehydrogenation of propane exhibited superior activity in contrast to its analog synthesized via conventional coprecipitation. It is suggested that the favorable chemical composition facilely obtained via grinding in contrast to that by coprecipitation was essential for achieving a more selective production of propylene. - Graphical Abstract: Grinding-assisted synthesis of NiMoO{sub 4} offers higher and more reproducible activities in contrast to coprecipitation for oxidative dehydrogenation of propane, and both {alpha}- and {beta}-NiMoO{sub 4} can be synthesized. Highlights: Black-Right-Pointing-Pointer NiMoO{sub 4} was prepared through grinding-assisted pathway. Black-Right-Pointing-Pointer Direct/sequential grinding rendered {alpha}-, {beta}-NiMoO{sub 4}, respectively. Black-Right-Pointing-Pointer Grinding-derived {alpha}-NiMoO{sub 4} showed high and reproducible activity for oxidative dehydrogenation of propane.

Chen Miao, E-mail: chenmiao@sinochem.com [Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433 (China); Zhejiang Chemical Industry Research Institute, Hangzhou 310023 (China); Wu Jialing; Liu Yongmei [Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433 (China); Cao Yong, E-mail: yongcao@fudan.edu.cn [Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433 (China); Guo Li [Zhejiang Chemical Industry Research Institute, Hangzhou 310023 (China); He Heyong; Fan Kangnian [Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433 (China)

2011-12-15T23:59:59.000Z

12

Mo-Si-B Based Coating For Oxidation Protection of SiC Composites  

Science Conference Proceedings (OSTI)

... in engine, aircraft and aerospace applications requires an external protective ... from attack due to corrosive combustion environments and active oxidation.

13

Production of magnesium metal  

DOE Patents (OSTI)

A process of producing magnesium metal includes providing magnesium carbonate, and reacting the magnesium carbonate to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The carbon dioxide is used as a reactant in a second process. In another embodiment of the process, a magnesium silicate is reacted with a caustic material to produce magnesium hydroxide. The magnesium hydroxide is reacted with a source of carbon dioxide to produce magnesium carbonate. The magnesium carbonate is reacted to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The invention further relates to a process for production of magnesium metal or a magnesium compound where an external source of carbon dioxide is not used in any of the reactions of the process. The invention also relates to the magnesium metal produced by the processes described herein.

Blencoe, James G. (Harriman, TN); Anovitz, Lawrence M. (Knoxville, TN); Palmer, Donald A. (Oliver Springs, TN); Beard, James S. (Martinsville, VA)

2010-02-23T23:59:59.000Z

14

Magnesium Technology 2009  

Science Conference Proceedings (OSTI)

Feb 1, 2009 ... Print Book and CD-ROM: Magnesium Technology 2007. Hardcover book and CD set: Magnesium Technology 2008 ...

15

Production of magnesium metal  

DOE Patents (OSTI)

A process of producing magnesium metal includes providing magnesium carbonate, and reacting the magnesium carbonate to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The carbon dioxide is used as a reactant in a second process. In another embodiment of the process, a magnesium silicate is reacted with a caustic material to produce magnesium hydroxide. The magnesium hydroxide is reacted with a source of carbon dioxide to produce magnesium carbonate. The magnesium carbonate is reacted to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The invention also relates to the magnesium metal produced by the processes described herein.

Blencoe, James G. (Harriman, TN); Anovitz, Lawrence M. (Knoxville, TN); Palmer, Donald A. (Oliver Springs, TN); Beard, James S. (Martinsville, VA)

2012-04-10T23:59:59.000Z

16

Low-Cost Zero-Emission Primary Magnesium Production by Solid ...  

Science Conference Proceedings (OSTI)

Abstract Scope, Solid Oxide Membrane (SOM) Electrolysis is a new low-cost process for direct extraction of magnesium oxide to pure magnesium and oxygen gas. .... Grain Refinement of AZ91 Alloy by Addition of Ceramic Particles.

17

Magnesium fluoride recovery method  

DOE Patents (OSTI)

A method of obtaining magnesium fluoride substantially free from radioactive uranium from a slag containing the same and having a radioactivity level of at least about 7000 pCi/gm. The slag is ground to a particle size of about 200 microns or less. The ground slag is contacted with an acid under certain prescribed conditions to produce a liquid product and a particulate solid product. The particulate solid product is separated from the liquid and treated at least two more times with acid to produce a solid residue consisting essentially of magnesium fluoride substantially free of uranium and having a residual radioactivity level of less than about 1000 pCi/gm. In accordance with a particularly preferred embodiment of the invention a catalyst and an oxidizing agent are used during the acid treatment and preferably the acid is sulfuric acid having a strength of about 1.0 Normal.

Gay, Richard L. (Canoga Park, CA); McKenzie, Donald E. (Woodland Hills, CA)

1989-01-01T23:59:59.000Z

18

Adsorption of propane, isopropyl, and hydrogen on cluster models of the M1 phase of Mo-V-Te-Nb-O mixed metal oxide catalyst  

Science Conference Proceedings (OSTI)

The Mo-V-Te-Nb-O mixed metal oxide catalyst possessing the M1 phase structure is uniquely capable of directly converting propane into acrylonitrile. However, the mechanism of this complex eight-electron transformation, which includes a series of oxidative H-abstraction and N-insertion steps, remains poorly understood. We have conducted a density functional theory study of cluster models of the proposed active and selective site for propane ammoxidation, including the adsorption of propane, isopropyl (CH{sub 3}CHCH{sub 3}), and H which are involved in the first step of this transformation, that is, the methylene C-H bond scission in propane, on these active site models. Among the surface oxygen species, the telluryl oxo (Te=O) is found to be the most nucleophilic. Whereas the adsorption of propane is weak regardless of the MO{sub x} species involved, isopropyl and H adsorption exhibits strong preference in the order of Te=O > V=O > bridging oxygens > empty Mo apical site, suggesting the importance of TeO{sub x} species for H abstraction. The adsorption energies of isopropyl and H and consequently the reaction energy of the initial dehydrogenation of propane are strongly dependent on the number of ab planes included in the cluster, which points to the need to employ multilayer cluster models to correctly capture the energetics of surface chemistry on this mixed metal oxide catalyst.

Govindasamy, Agalya [University of Cincinnati; Muthukumar, Kaliappan [University of Cincinnati; Yu, Junjun [University of Cincinnati; Xu, Ye [ORNL; Guliants, Vadim V. [University of Cincinnati

2010-01-01T23:59:59.000Z

19

Magnesium Electrolytic Production Process  

Science Conference Proceedings (OSTI)

Oct 1, 1999 ... The process is adopted at magnesium and titanium-magnesium plants of Russia, Kazakhstan, Ukraine. The best modern projects are realised ...

20

Magnesium: Digital Resource Center - BOOK: Magnesium ...  

Science Conference Proceedings (OSTI)

Oct 6, 2008 ... This book presents all aspects of magnesium production, properties and application, including primary production, alloy development, ...

Note: This page contains sample records for the topic "mo magnesium oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

STEM HAADF Image Simulation of the Orthorhombic M1 Phase in the Mo-V-Nb-Te-O Propane Oxidation Catalyst  

Science Conference Proceedings (OSTI)

A full frozen phonon multislice simulation of high angle annular dark field scanning transmission electron microscopy (HAADF STEM) images from the M1 phase of the Mo-V-Nb-Te-O propane oxidation catalyst has been performed by using the latest structural model obtained using the Rietveld method. Simulated contrast results are compared with experimental HAADF images. Good agreement is observed at ring sites, however significant thickness dependence is noticed at the linking sites. The remaining discrepancies between the model based on Rietveld refinement and image simulations indicate that the sampling of a small volume element in HAADF STEM and averaging elemental contributions of a disordered site in a crystal slab by using the virtual crystal approximation might be problematic, especially if there is preferential Mo/V ordering near the (001) surface.

D Blom; X Li; S Mitra; T Vogt; D Buttrey

2011-12-31T23:59:59.000Z

22

Thermodynamics of the conversion of calcium and magnesium fluorides to the parent metal oxides and hydrogen fluoride  

Science Conference Proceedings (OSTI)

The authors have used thermodynamic modeling to examine the reaction of calcium fluoride (CaF{sub 2}) and magnesium fluoride (MgF{sub 2}) with water (H{sub 2}O) at elevated temperatures. The calculated, equilibrium composition corresponds to the global free-energy minimum for the system. Optimum, predicted reaction temperatures and reactant mole ratios are reported for the recovery of hydrogen fluoride (HF), a valuable industrial feedstock. Complete conversion of MgF{sub 2} is found at 1,000 C and a ratio of 40 moles of H{sub 2}O per 1 mole of MgF{sub 2}. For CaF{sub 2}, temperatures as high as 1,400 C are required for complete conversion at a corresponding mole ratio of 40 moles of H{sub 2}O per 1 mole of CaF{sub 2}. The authors discuss the presence of minor chemical constituents as well as the stability of various potential container materials for the pyrohydrolysis reactions at elevated temperatures. CaF{sub 2} and MgF{sub 2} slags are available as wastes at former uranium production facilities within the Department of Energy Complex and other facilities regulated by the Nuclear Regulatory Commission. Recovery of HF from these wastes is an example of environmental remediation at such facilities.

West, M.H.; Axler, K.M.

1997-02-01T23:59:59.000Z

23

Development of the local and average structure of a V?Mo?Nb oxide catalyst with Mo[subscript 5]O[subscript 14]-like structure during synthesis from nanostructured precursors  

SciTech Connect

A combination of X-ray and neutron PDF measurements with powder diffraction and EXAFS data was used to determine the structures of a V-Mo-Nb-oxide catalyst and its poorly crystallized precursors that exhibit the strongest catalytic activities. The crystalline material belongs to space group P{bar 4}2{sub 1}m, a = 22.8, c = 4.002, and is build up of pentagonal MeO{sub 7} bipyramids surrounded by edge sharing Me-octahedrons (Me = Mo, V, Nb). In the average structure all MeO{sub 7} units are at the same z-level, while the local structure analysis shows systematic shifts along [001]. Samples synthesized at 300 C and 400 C exhibit a nanostructure, whose local structure predates the final crystalline structure. Initial nanoparticles are spherical and grow predominantly along the c-axis. The successful analysis required a reverse analysis that took the crystalline material as starting model for the samples synthesized at lower temperatures.

Kardash, Tatyana Yu.; Plyasova, Ludmilla M.; Kochubey, Dmitry I.; Bondareva, Valentina M.; Neder, Reinhard B. (Boreskov); (Nurnbergand)

2012-05-29T23:59:59.000Z

24

Magnesium Technology 2014  

Science Conference Proceedings (OSTI)

Jul 15, 2013 ... Emerging Applications (hydrogen storage, additive manufacturing of ... with an electrolytic process for magnesium production from serpentine.

25

Magnesium Technology Symposium  

Science Conference Proceedings (OSTI)

Conference Tools for Materials Science & Technology 2013 ... Scope, The magnesium technology symposium will cover a broad spectrum of theoretical and ...

26

High temperature oxidation and NaCl-induced accelerated corrosion of hot-dip aluminized 9Cr-1Mo and 310 stainless steel  

E-Print Network (OSTI)

The behaviors of high temperature corrosion on hot-dip aluminized on 9Cr-1Mo and 310 stainless steels when catalyzed by NaCl and cyclic heating environment were studied experimentally. The corrosion behavior and morphological development were investigated by weight gain kinetics, metallographs, depths of attack, metal losses, and X-ray analyses. The results of 310SS deposited with salt mixtures show that weight gain kinetics in simple oxidation reveals a steady-state parabolic rate law after 3 hr, while the kinetics with salt deposits display multi-stage growth rates. NaCl is the main corrosive specie in high-temperature corrosion involving mixtures of NaCl/Na2SO4 and is responsible for the formation of internal attack. Uniform internal attack is the typical morphology of NaCl-induced hot corrosion, while the extent of intergranular attack is more pronounced as the content of Na2SO4 in the mixture is increased. The thermal-cycling test results of 310SS deposited NaCl and coated 7wt%Si/93wt%Al show that the aluminized layers have good corrosion resistance during the first four cycles of testing, while degradation occurs after testing for five cycles. The reason for degradation of aluminized layers is attributed to the formation of interconnecting voids caused by aluminum inward diffusion, chloridation/oxidation cyclic reactions and the penetration of molten NaCl through the voids into the alloy substrate. The 9Cr-1Mo steels coated with 7wt%Si/93wt%Al oxidized at 750, 850, and 950°C in static air show that oxidation kinetics followed a parabolic rate law at 750 and 850 °C. The cracks propagated through the FexAly layer due to the growth of brittle FeAl2 and Fe2Al5 at 750 and 850°C. The voids condensed in the interface of intermetallics and substrate are attributed to the Kirkendall effect. At 950°C, the fast growing aluminide layer has a different expansion coefficient than oxide scale, leading to scale cracking, oxygen penetration, and internal oxidized, evidenced by a rapid mass gain.

Tsaur, Charng-Cheng

2004-12-01T23:59:59.000Z

27

Method for magnesium sulfate recovery  

DOE Patents (OSTI)

A method is described for obtaining magnesium sulfate substantially free from radioactive uranium from a slag containing the same and having a radioactivity level of at least about 7,000 pCi/gm. The slag is ground to a particle size of about 200 microns or less. The ground slag is then contacted with a concentrated sulfuric acid under certain prescribed conditions to produce a liquid product and a solid product. The particulate solid product and a minor amount of the liquid is then treated to produce a solid residue consisting essentially of magnesium sulfate substantially free of uranium and having a residual radioactivity level of less than 1,000 pCi/gm. In accordance with the preferred embodiment of the invention, a catalyst and an oxidizing agent are used during the initial acid treatment and a final solid residue has a radioactivity level of less than about 50 pCi/gm.

Gay, R.L.; Grantham, L.F.

1987-08-25T23:59:59.000Z

28

The Magnesium Industry  

Science Conference Proceedings (OSTI)

...salt lakes (for example, the Great Salt Lake in Utah) or salt deposits as the raw material. Both magnesium and chlorine are produced.

29

Magnesium Technology 2011  

Science Conference Proceedings (OSTI)

Aug 2, 2010 ... Processing Aspects of Magnesium Alloy Stent Tube ... The Effect of Rare Earth Elements on the Texture and Formability of Asymmetrically ...

30

Recycling - Magnesium - TMS  

Science Conference Proceedings (OSTI)

Guidelines to assist in buying and selling of various types of Scrap. ... A cooperative effort between EPA and US magnesium industry to reduce emissions of SF6.

31

Magnesium Technology 2001  

Science Conference Proceedings (OSTI)

Inno\\ ative Vacuum Distillation for Magnesium Recjvcling ........................................... .................... 3 3. Tiunhrri ZJ711. A.irihr Li, "iicioniing .\\lei. '4 lfi-cd I'ii, mid ...

32

WEB RESOURCE: Gas Welding Magnesium  

Science Conference Proceedings (OSTI)

Sep 20, 2007 ... This webpage offers advice on gas welding of magnesium. Launch Site SOURCE: "Gas Welding Magnesium". Weldwell Corporate Website.

33

WEB RESOURCE: Magnesium Welding - Information Sources for ...  

Science Conference Proceedings (OSTI)

Sep 20, 2007 ... This web-based, magnesium welding resource is a compilation of: ... SOURCE: “ Magnesium Welding – Information Sources for Magnesium ...

34

DOE - Office of Legacy Management -- Petrolite Corp - MO 08  

Office of Legacy Management (LM)

Petrolite Corp - MO 08 Petrolite Corp - MO 08 FUSRAP Considered Sites Site: PETROLITE CORP (MO.08) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: St. Louis , Missouri MO.08-1 Evaluation Year: 1987 MO.08-4 Site Operations: Research involving test quantities of radioactive materials. MO.08-2 Site Disposition: Eliminated - Licensed - Potential for contamination remote MO.08-3 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled: Uranium Flouride & Thorium Oxide MO.08-2 Radiological Survey(s): None Indicated Site Status: Eliminated from further consideration under FUSRAP Also see Documents Related to PETROLITE CORP MO.08-1 - Summary Paper; Title: License History for Petrolite Corporation, St. Louis (MO.8); dated 07/16/93; with three attachments (3

35

Magnesium - Rare Earth Alloys  

Science Conference Proceedings (OSTI)

Feb 16, 2010 ... Location: Washington State Convention Center ... The Use of Computer Modeling for Producing DC Cast WE43 Magnesium Alloy Slab: ... However, there is a limited operating window within which favourable textures arise.

36

Process for converting magnesium fluoride to calcium fluoride  

DOE Patents (OSTI)

This invention is a process for the conversion of magnesium fluoride to calcium fluoride whereby magnesium fluoride is decomposed by heating in the presence of calcium carbonate, calcium oxide or calcium hydroxide. Magnesium fluoride is a by-product of the reduction of uranium tetrafluoride to form uranium metal and has no known commercial use, thus its production creates a significant storage problem. The advantage of this invention is that the quality of calcium fluoride produced is sufficient to be used in the industrial manufacture of anhydrous hydrogen fluoride, steel mill flux or ceramic applications.

Kreuzmann, A.B.; Palmer, D.A.

1984-12-21T23:59:59.000Z

37

ASM Specialty Handbook: Magnesium and Magnesium Alloys - TMS  

Science Conference Proceedings (OSTI)

Feb 9, 2007 ... Prepared with the cooperation of the International Magnesium Association, this handbook presents current industrial practices and provides ...

38

Efficient One-Step Electrolytic Recycling of Low-Grade and Post-Consumer Magnesium Scrap  

SciTech Connect

Metal Oxygen Separation Technologies, Inc. (abbreviated MOxST, pronounced most) and Boston University (BU) have developed a new low-cost process for recycling post-consumer co-mingled and heavily-oxidized magnesium scrap, and discovered a new chemical mechanism for magnesium separations in the process. The new process, designated MagReGenTM, is very effective in laboratory experiments, and on scale-up promises to be the lowest-cost lowest-energy lowest-impact method for separating magnesium metal from aluminum while recovering oxidized magnesium. MagReGenTM uses as little as one-eighth as much energy as today's methods for recycling magnesium metal from comingled scrap. As such, this technology could play a vital role in recycling automotive non-ferrous metals, particularly as motor vehicle magnesium/aluminum ratios increase in order to reduce vehicle weight and increase efficiency.

Adam C. Powell, IV

2012-07-19T23:59:59.000Z

39

Investigation of the hydroconversion of rancid lard and lard-gas oil mixture on NiMo/Al2O3 catalyst in oxide and in sulphide state  

Science Conference Proceedings (OSTI)

The necessity to maintain mobility and the increasing energy- and environmentally sound demands necessitated the research, development and utilization of engine fuels from renewable resources. Because of the negative features of the already and generally ... Keywords: NiMo/Al2O3, hydroconversion, hydrogenation, lard, triglyceride

P. Baladincz; J. Hancsók

2011-12-01T23:59:59.000Z

40

Enhancements in Magnesium Die Casting Impact Properties  

SciTech Connect

The need to produce lighter components in transportation equipment is the main driver in the increasing demand for magnesium castings. In many automotive applications, components can be made of magnesium or aluminum. While being lighter, often times the magnesium parts have lower impact and fatigue properties than the aluminum. The main objective of this study was to identify potential improvements in the impact resistance of magnesium alloys. The most common magnesium alloys in automotive applications are AZ91D, AM50 and AM60. Accordingly, these alloys were selected as the main candidates for the study. Experimental quantities of these alloys were melted in an electrical furnace under a protective atmosphere comprising sulfur hexafluoride, carbon dioxide and dry air. The alloys were cast both in a permanent mold and in a UBE 315 Ton squeeze caster. Extensive evaluation of tensile, impact and fatigue properties was conducted at CWRU on permanent mold and squeeze cast test bars of AZ91, AM60 and AM50. Ultimate tensile strength values between 20ksi and 30ksi were obtained. The respective elongations varied between 25 and 115. the Charpy V-notch impact strength varied between 1.6 ft-lb and 5 ft-lb depending on the alloy and processing conditions. Preliminary bending fatigue evaluation indicates a fatigue limit of 11-12 ksi for AM50 and AM60. This is about 0.4 of the UTS, typical for these alloys. The microstructures of the cast specimens were investigated with optical and scanning electron microscopy. Concomitantly, a study of the fracture toughness in AM60 was conducted at ORNL as part of the study. The results are in line with values published in the literature and are representative of current state of the art in casting magnesium alloys. The experimental results confirm the strong relationship between aluminum content of the alloys and the mechanical properties, in particular the impact strength and the elongation. As the aluminum content increases from about 5% in AM50 to over 9% in AZ91, more of the intermetallic Mg17Al12 is formed in the microstructure. For instance, for 15 increase in the aluminum content from AM50 to AM60, the volume fraction of eutectic present in the microstructure increases by 35%! Eventually, the brittle Mg17Al12 compound forms an interconnected network that reduces ductility and impact resistance. The lower aluminum in AM50 and AM60 are therefore a desirable feature in applications that call for higher impact resistance. Further improvement in impact resistance depends on the processing condition of the casting. Sound castings without porosity and impurities will have better mechanical properties. Since magnesium oxidizes readily, good melting and metal transfer practices are essential. The liquid metal has to be protected from oxidation at all times and entrainment of oxide films in the casting needs to be prevented. In this regard, there is evidence that us of vacuum to evacuate air from the die casting cavity can improve the quality of the castings. Fast cooling rates, leading to smaller grain size are beneficial and promote superior mechanical properties. Micro-segregation and banding are two additional defect types often encountered in magnesium alloys, in particular in AZ91D. While difficult to eliminate, segregation can be minimized by careful thermal management of the dies and the shot sleeve. A major source of segregation is the premature solidification in the shot sleeve. The primary solid dendrites are carried into the casting and form a heterogeneous structure. Furthermore, during the shot, segregation banding can occur. The remedies for this kind of defects include a hotter shot sleeve, use of insulating coatings on the shot sleeve and a short lag time between pouring into the shot sleeve and the shot.

David Schwam; John F. Wallace; Yulong Zhu; Srinath Viswanathan; Shafik Iskander

2000-06-30T23:59:59.000Z

Note: This page contains sample records for the topic "mo magnesium oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Molten Salts, Magnesium and Aluminum  

Science Conference Proceedings (OSTI)

Mar 1, 2011 ... Chloride 2011: Practice and Theory of Chloride-Based Metallurgy: Molten Salts, Magnesium and Aluminum Sponsored by: The Minerals, ...

42

Magnesium Workshop Madrid 2013: Home Page  

Science Conference Proceedings (OSTI)

Magnesium Workshop Madrid 2013. An International Workshop on Processing- Microstructure-Mechanical Property of Magnesium Alloys May 21-24, 2013 ...

43

Climate VISION: Private Sector Initiatives: Magnesium: Resources...  

Office of Scientific and Technical Information (OSTI)

in 1943, the mission of the International Magnesium Association (IMA) is to promote the use of the metal magnesium in material selection and encourage innovative applications of...

44

Promising Magnesium Battery Research at ALS  

NLE Websites -- All DOE Office Websites (Extended Search)

AdvancedLightSource Home Science Highlights Industry @ ALS Promising Magnesium Battery Research at ALS Promising Magnesium Battery Research at ALS Print Wednesday, 23...

45

The Magnesium Industry Today: A Global Perspective  

Science Conference Proceedings (OSTI)

World demand for magnesium continues to remain subdued, succumbing to the ... Magnesium Alloy Sheets and Lubricants for Warm-Forming - Friction Effects.

46

It's Elemental - The Element Magnesium  

NLE Websites -- All DOE Office Websites (Extended Search)

Sodium Sodium Previous Element (Sodium) The Periodic Table of Elements Next Element (Aluminum) Aluminum The Element Magnesium [Click for Isotope Data] 12 Mg Magnesium 24.3050 Atomic Number: 12 Atomic Weight: 24.3050 Melting Point: 923 K (650°C or 1202°F) Boiling Point: 1363 K (1090°C or 1994°F) Density: 1.74 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 3 Group Number: 2 Group Name: Alkaline Earth Metal What's in a name? For Magnesia, a district in the region of Thessaly, Greece. Say what? Magnesium is pronounced as mag-NEE-zhi-em. History and Uses: Although it is the eighth most abundant element in the universe and the seventh most abundant element in the earth's crust, magnesium is never found free in nature. Magnesium was first isolated by Sir Humphry Davy, an

47

Switchable Mirrors Based on Nickel-Magnesium Films  

NLE Websites -- All DOE Office Websites (Extended Search)

Switchable Mirrors Based on Nickel-Magnesium Films Switchable Mirrors Based on Nickel-Magnesium Films Title Switchable Mirrors Based on Nickel-Magnesium Films Publication Type Journal Article LBNL Report Number LBNL-47180 Year of Publication 2001 Authors Richardson, Thomas J., Jonathan L. Slack, Robert D. Armitage, Robert Kostecki, Baker Farangis, and Michael D. Rubin Journal Applied Physics Letters Volume 78 Pagination 3047 Call Number LBNL-47180 Abstract An electrochromic mirror electrode based on reversible uptake of hydrogen in nickel magnesium alloy films is reported. Thin, magnesium-rich Ni-Mg films prepared on glass substrates by cosputtering from Ni and Mg targets are mirror-like in appearance and have low visible transmittance. Upon exposure to hydrogen gas or on cathodic polarization in alkaline electrolyte, the films take up hydrogen and become transparent. When hydrogen is removed, the mirror properties are recovered. The transition is believed to result from reversible formation of Mg2NiH4 and MgH2. A thin overlayer of palladium was found to enhance the kinetics of hydrogen insertion and extraction, and to protect the metal surface against oxidation.

48

Microsoft Word - Poster Abstract_2010_MO-SCI.doc  

NLE Websites -- All DOE Office Websites (Extended Search)

* * Presenter High-Temperature Viscous Sealing Glasses for Solid Oxide Fuel Cells Cheol-Woon Kim * , Cindy L. Schwartz, Joe Szabo, Kevin S. Barr, and Ted E. Day MO-SCI Corporation, Rolla, MO 65401 * ckim@mo-sci.com; (573) 364-2338 Richard K. Brow ** and Zhongzhi Tang Department of Materials Science and Engineering and the Graduate Center for Materials Research, Missouri University of Science and Technology, Rolla, MO 65409-1170 ** brow@mst.edu; (573) 341-6812 MO-SCI Corporation and the Missouri University of Science and Technology successfully identified and tested several glass compositions that could be used as viscous seals for Solid Oxide Fuel Cells (SOFCs) through a SBIR Phase I project (DE-SC0002491). The glasses possess desirable viscosity characteristics- that is, they have softening points in the temperature range

49

Kinetics of the chlorination of magnesium oxide  

DOE Green Energy (OSTI)

The chlorination reaction of MgO (MgO + Cl/sub 2/ ..-->.. MgCl/sub 2/ + 1/2 O/sub 2/) was investigated by an apparatus designed to measure the product gas O/sub 2/ concentration. Reaction of a packed bed of 1.0-..mu..-diam particles changed from an initially reaction controlled regime to a diffusion controlled regime as the MgCl/sub 2/ product layer thickened. The ''grain model'' proposed by Szekely, Evans and Sohn approximated the data quite well, except at long reaction times, when the effects of sintering of the product layer and pore closure became pronounced. By using the ''grain model,'' an Arrhenius-type rate expression was determined for the temperature range of 510/sup 0/-643/sup 0/C: k(cm/sec) = 31.8 exp(-28.Okcal/RT). The effective diffusion coefficient for Cl/sub 2/ in the MgCl/sub 2/ product layer was also determined. The preparation method and thermal history of the MgO greatly varied both its surface area and reactivity. The MgO prepared by hydrolyzing MgCl/sub 2/ at 550/sup 0/C was 14 times more reactive and had 23 times less surface area than MgO prepared by dehydrating Mg(OH)/sub 2/ at 550/sup 0/C. Sintering the MgO before reaction reduced its reactivity, while not changing its surface area greatly; indicating that surface diffusion and recrystallization of the MgO might have occurred.

Hesson, R.N.

1979-01-01T23:59:59.000Z

50

Magnesium: Digital Resource Center - ARTICLE: Safe Machining of ...  

Science Conference Proceedings (OSTI)

Sep 7, 2007... Other ==== Miscellaneous Digital Resources in Magnesium. Spacer ... Topic Title: ARTICLE: Safe Machining of Magnesium Parts by Cutting ...

51

MoWitt  

NLE Websites -- All DOE Office Websites (Extended Search)

MoWiTT: Mobile Window Thermal Test Facility The window has come a long way since the days when it was a single pane of glass in a wood frame. Low-emissivity windows were designed...

52

Scaling-Up Solid Oxide Membrane Electrolysis Technology for ...  

Science Conference Proceedings (OSTI)

Presentation Title, Scaling-Up Solid Oxide Membrane Electrolysis Technology for Magnesium Production. Author(s), Soobhankar Pati, Adam Powell, Steve ...

53

Slashing Greenhouse Emissions from Magnesium Production - TMS  

Science Conference Proceedings (OSTI)

Jul 1, 2008 ... Topic Title: Slashing Greenhouse Emissions from Magnesium Production Topic Summary: CSIRO, an Australia's national science agency ...

54

Synthesis of superconducting magnesium diboride objects  

DOE Patents (OSTI)

A process to produce magnesium diboride objects from boron objects with a similar form is presented. Boron objects are reacted with magnesium vapor at a predetermined time and temperature to form magnesium diboride objects having a morphology similar to the boron object's original morphology.

Finnemore, Douglas K. (Ames, IA); Canfield, Paul C. (Ames, IA); Bud' ko, Sergey L. (Ames, IA); Ostenson, Jerome E. (Ames, IA); Petrovic, Cedomir (Ames, IA); Cunningham, Charles E. (Ames, IA); Lapertot, Gerard (Grenoble, FR)

2003-08-15T23:59:59.000Z

55

Synthesis Of Superconducting Magnesium Diboride Objects.  

DOE Patents (OSTI)

A process to produce magnesium diboride objects from boron objects with a similar form is presented. Boron objects are reacted with magnesium vapor at a predetermined time and temperature to form magnesium diboride objects having a morphology similar to the boron object's original morphology.

Finnemore, Douglas K. (Ames, IA); Canfield, Paul C. (Ames, IA); Bud' ko, Sergey L. (Ames, IA); Ostenson, Jerome E. (Ames, IA); Petrovic, Cedomir (Ames, IA); Cunningham, Charles E. (Ames, IA); Lapertot, Gerard (Grenoble, FR)

2003-07-08T23:59:59.000Z

56

Climate VISION: Private Sector Initiatives: Magnesium  

Office of Scientific and Technical Information (OSTI)

Letters of Intent/Agreements Letters of Intent/Agreements International Magnesium Association Logo In response to President Bush's challenge to reduce greenhouse gas emissions, fifteen U.S. companies along with the International Magnesium Association (IMA) have voluntarily committed to eliminate SF6 emissions by 2010. This commitment builds on the efforts of the SF6 Emission Reduction Partnership for the Magnesium Industry, a partnership program that EPA has had with the industry since 1999. These industry leaders represent 100% of domestic primary magnesium production and 90% of U.S. magnesium casting capacity. In addition, the IMA's members operate on five continents and represent 80% of the global magnesium industry. The magnesium industry commonly uses a potent and long-lived greenhouse

57

Switchable mirrors based on nickel-magnesium films  

DOE Green Energy (OSTI)

A new type of electrochromic mirror electrode based on reversible uptake of hydrogen in nickel magnesium alloy films is reported. Thin,magnesium-rich Ni-Mg films prepared on glass substrates by cosputtering from Ni and Mg targets are mirror-like in appearance and have low visible transmittance. Upon exposure to hydrogen gas or on reduction in alkaline electrolyte, the films take up hydrogen and become transparent. When hydrogen is removed, the mirror properties are recovered. The transition is believed to result from reversible formation of Mg2NiH4 and MgH2. A thin overlayer of palladium was found to enhance the kinetics of hydrogen insertion and extraction,and to protect the metal surface against oxidation.

Richardson,Thomas J.; Slack, Jonathan L.; Armitage, Robert D.; Kostecki, Robert; Farangis, Baker; Rubin, Michael D.

2001-01-16T23:59:59.000Z

58

Substrate and method for the formation of continuous magnesium diboride and doped magnesium diboride wire  

DOE Patents (OSTI)

A chemically doped boron coating is applied by chemical vapor deposition to a silicon carbide fiber and the coated fiber then is exposed to magnesium vapor to convert the doped boron to doped magnesium diboride and a resultant superconductor.

Suplinskas, Raymond J. (Haverhill, MA); Finnemore, Douglas (Ames, IA); Bud' ko, Serquei (Ames, IA); Canfield, Paul (Ames, IA)

2007-11-13T23:59:59.000Z

59

Promising Magnesium Battery Research at ALS  

NLE Websites -- All DOE Office Websites (Extended Search)

Promising Magnesium Battery Research Promising Magnesium Battery Research at ALS Promising Magnesium Battery Research at ALS Print Wednesday, 23 January 2013 16:59 toyota battery a) Cross-section of the in situ electrochemical/XAS cell with annotations. b) Drawing and c) photograph of the assembled cell. Alternatives to the current lithium-ion-based car batteries are at the forefront of the automotive industry's research agenda-manufacturers want to build cars with longer battery life, and to do that they're going to have to find new solutions. One promising battery material is magnesium (Mg)-it is more dense than lithium, it is safer, and the magnesium ion carries a two-electron charge, giving it potential as a more efficient energy source. Magnesium has a high volumetric capacity, which could mean

60

Climate VISION: Private Sector Initiatives: Magnesium: Results  

Office of Scientific and Technical Information (OSTI)

plans, the International Magnesium Association and the federal government will begin tracking progress. The results will be measured by metrics developed by the industry, in...

Note: This page contains sample records for the topic "mo magnesium oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Materials Design in Magnesium Alloy Development  

Science Conference Proceedings (OSTI)

This presentation will provide insight into the status of materials design tools in its application to magnesium alloy development as well as provide forecasts as to ...

62

Magnesium: Digital Resource Center -- Background - TMS  

Science Conference Proceedings (OSTI)

WEB RESOURCE: MIL-HDBK-5H: Metallic Materials and Elements for Aerospace Vehicle Structures Link provided to Chapter 4: Magnesium Alloys, 0, 780 ...

63

Magnesium: Digital Resource Center -- Databases - TMS  

Science Conference Proceedings (OSTI)

WEB RESOURCE: MIL-HDBK-5H: Metallic Materials and Elements for Aerospace Vehicle Structures Link provided to Chapter 4: Magnesium Alloys, 0, 958 ...

64

Magnesium: Digital Resource Center -- Background - TMS  

Science Conference Proceedings (OSTI)

WEB RESOURCE: MIL-HDBK-5H: Metallic Materials and Elements for Aerospace Vehicle Structures Link provided to Chapter 4: Magnesium Alloys, 0, 793 ...

65

Magnesium: Digital Resource Center -- Databases - TMS  

Science Conference Proceedings (OSTI)

WEB RESOURCE: MIL-HDBK-5H: Metallic Materials and Elements for Aerospace Vehicle Structures Link provided to Chapter 4: Magnesium Alloys, 0, 1005 ...

66

Magnesium/manganese dioxide electrochemical cell  

SciTech Connect

This patent describes an improvement in a magnesium/manganese dioxide electrochemical cell that has been stored following partial usage and including an alloy of magnesium as the anode, a moist cathode mix of carbon black, manganese dioxide, magnesium hydroxide, barium chromate and lithium chromate as the cathode, and 3.5 to 4.0 normal magnesium perchlorate as the electrolyte. The improvement involves increasing the moisture content of the cathode mix from 34 to 38 percent at the time of making the cell to reduce the self discharge and increase the operating capacity after the cell has been stored following partial usage.

Jarvis, L.P.; Brundage, M.T.; Atwater, T.B.

1989-09-26T23:59:59.000Z

67

Magnesium: Digital Resource Center Text Topic  

Science Conference Proceedings (OSTI)

Feb 11, 2007 ... E. Aghion, B. Bronfin, F. Von Buch, S. Schumann and H. Friedrich. "Dead Sea Magnesium Alloys Newly Developed for High Temperature ...

68

Nanoparticles in Magnesium Alloys: Novel Nanoscale Phenomena ...  

Science Conference Proceedings (OSTI)

Also, the in-situ creation of nanoparticles in magnesium alloy and consequent simultaneous ... Processing and Mechanical Behavior of Unalloyed Plutonium.

69

PDF: Automotive Magnesium Applications and Life Cycle ...  

Science Conference Proceedings (OSTI)

Feb 11, 2007 ... This presentation includes images of a die cast magnesium steering wheel, AZ91D cam cover, AZ91D transmission housing, AM50 door inner, ...

70

Understanding Protective Film Formation by Magnesium Alloys  

Science Conference Proceedings (OSTI)

Abstract Scope, Magnesium-based alloys are the lightest structural metals, and thus ... The present work aims to understand the mechanism(s) of protective film ...

71

Fluid Bed Dehydration of Magnesium Chloride  

Science Conference Proceedings (OSTI)

... is provided based on open literature sources, including papers and patents. ... Demonstration of Solar-Pumped Laser-Induced Magnesium Production from ...

72

Magnesium: Digital Resource Center - ARTICLE: Forming of ...  

Science Conference Proceedings (OSTI)

Sep 20, 2007 ... This paper addresses the formability of magnesium extrusions with respect to rotary-draw bending and hydro-mechanical forming, presenting ...

73

Climate VISION: Private Sector Initiatives: Magnesium: Work Plans  

Office of Scientific and Technical Information (OSTI)

Work Plans EPA's SF6 Emission Reduction Partnership for the Magnesium Industry in cooperation with the International Magnesium Association has developed a work plan for achieving...

74

Hydrogen Storage property of sandwiched magnesium hydride naoparticle...  

NLE Websites -- All DOE Office Websites (Extended Search)

Storage property of sandwiched magnesium hydride naoparticle thin film Title Hydrogen Storage property of sandwiched magnesium hydride naoparticle thin film Publication Type...

75

2003 TMS Annual Meeting: Short Courses--Magnesium Metallurgy ...  

Science Conference Proceedings (OSTI)

Mar 1, 2003 ... Returned to China and started in the magnesium business in 1991 selling metals , including magnesium to the end users. Has worked on the ...

76

9 Cr-- 1 Mo steel material for high temperature application  

DOE Patents (OSTI)

One or more embodiments relates to a high-temperature, titanium alloyed, 9 Cr-1 Mo steel exhibiting improved creep strength and oxidation resistance at service temperatures up to 650.degree. C. The 9 Cr-1 Mo steel has a tempered martensite microstructure and is comprised of both large (0.5-3 .mu.m) primary titanium carbides and small (5-50 nm) secondary titanium carbides in a ratio of. from about 1:1.5 to about 1.5:1. The 9 Cr-1 Mo steel may be fabricated using exemplary austenizing, rapid cooling, and tempering steps without subsequent hot working requirements. The 9 Cr-1 Mo steel exhibits improvements in total mass gain, yield strength, and time-to-rupture over ASTM P91 and ASTM P92 at the temperature and time conditions examined.

Jablonski, Paul D; Alman, David; Dogan, Omer; Holcomb, Gordon; Cowen, Christopher

2012-11-27T23:59:59.000Z

77

Thermodynamic Assessment of Ce-Mo, Mo-La, Mo-Y, Ce-V, La-V ...  

Science Conference Proceedings (OSTI)

In this work, six binary systems, Ce-Mo, Mo-La, Mo-Y, Ce-V, La-V and V-Y were thermodynamically assessed based on available experimental data in the ...

78

US WNC MO Site Consumption  

U.S. Energy Information Administration (EIA) Indexed Site

WNC MO WNC MO Site Consumption million Btu $0 $500 $1,000 $1,500 $2,000 $2,500 US WNC MO Expenditures dollars ALL ENERGY average per household (excl. transportation) 0 3,000 6,000 9,000 12,000 15,000 US WNC MO Site Consumption kilowatthours $0 $300 $600 $900 $1,200 $1,500 US WNC MO Expenditures dollars ELECTRICITY ONLY average per household * Missouri households consume an average of 100 million Btu per year, 12% more than the U.S. average. * Average household energy costs in Missouri are slightly less than the national average, primarily due to historically lower residential electricity prices in the state. * Missouri homes are typically larger than homes in other states and are more likely to be attached or detached single-family housing units.

79

MoS2  

NLE Websites -- All DOE Office Websites (Extended Search)

4 4 Myriam Perez De la Rosa1, Gilles Berhault2, Apurva Mehta3, and Russell R. Chianelli1 1University of Texas at El Paso, Materials Research Technology Institute, El Paso, TX 2Institut de Recherches sur la Catalyse, CNRS, Villeurbanne cedex, France 3Stanford Synchrotron Radiation Laboratory, Menlo Park, CA Figure 1: MoS2 layered structure. As the world economy continues to expand the demand for petroleum based fuel increases and the price of these fuels rises. The rising price of fuel has another consequence: refiners tend to purchase cheaper fuels of poorer quality. These poor quality fuels contain increasing amounts of sulfur and other pollutants leading to a decline in air quality worldwide. A recent New York Times article described the major impact a growing Chinese economy

80

Climate VISION: Private Sector Initiatives: Magnesium  

Office of Scientific and Technical Information (OSTI)

Federal/State Programs Federal/State Programs U.S. EPA's SF6 Emission Reduction Partnership for the Magnesium Industry Leading magnesium producers and casting companies are working with the U.S. Environmental Protection Agency (EPA) to alleviate the global environmental threat of climate change. EPA is very proud to cooperate with the industry through the SF6 Emission Reduction Partnership for the Magnesium Industry and the International Magnesium Association (IMA) to protect the climate. This voluntary initiative is guiding research of new technologies, promoting environmental stewardship, and providing a valuable forum to freely exchange technical information. Significant progress has been made to identify and implement SF6 emission reduction strategies since the partnership's inception.

Note: This page contains sample records for the topic "mo magnesium oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Magnesium Alloys - TMS: Knowledge Resource Center  

Science Conference Proceedings (OSTI)

A.A. Luo, A.K. Sachdev, R.K. Mishra, and R.C. Kubic. An Internal Variable Approach to the Superplastic Deformation of AZ31 Magnesium Alloy [pp. 149] H.S. Lee ...

82

Innovative Vacuum Distillation for Magnesium Recycling  

Science Conference Proceedings (OSTI)

Feb 1, 2001 ... TMS Member price: 10.00. Non-member price: 25.00. TMS Student Member price : 10.00. Product In Stock. Description Magnesium recycling ...

83

Fracture and fatigue properties of Mo-Mo{sub 3}Si-Mo{sub 5}SiB{sub 2} refractory intermetallic alloys at ambient to elevated temperatures (25-1300 degrees Centigrade)  

Science Conference Proceedings (OSTI)

The need for structural materials with high-temperature strength and oxidation resistance coupled with adequate lower-temperature toughness for potential use at temperatures above {approx} 1000 degrees C has remained a persistent challenge in materials science. In this work, one promising class of intermetallic alloys is examined, namely boron-containing molybdenum silicides, with compositions in the range Mo (bal), 12-17 at. percentSi, 8.5 at. percentB, processed using both ingot (I/M) and powder (P/M) metallurgy methods. Specifically, the oxidation (''pesting''), fracture toughness and fatigue-crack propagation resistance of four such alloys, which consisted of {approx}21 to 38 vol. percent a-Mo phase in an intermetallic matrix of Mo3Si and Mo5SiB2 (T2), were characterized at temperatures between 25 degrees and 1300 degrees C. The boron additions were found to confer superior ''pest'' resistance (at 400 degrees to 900 degrees C) as compared to unmodified molybdenum silicides, such as Mo5Si3. Moreover , although the fracture and fatigue properties of the finer-scale P/M alloys were only marginally better than those of MoSi2, for the I/M processed microstructures with coarse distributions of the a-Mo phase, fracture toughness properties were far superior, rising from values above 7 MPa sqrt m at ambient temperatures to almost 12 MPa sqrt m at 1300 degrees C.

Choe, Heeman; Schneibel, J.H.; Ritchie, R.O.

2002-08-01T23:59:59.000Z

84

Single Phase Melt Processed Powellite (Ba,Ca) MoO{sub 4} For The Immobilization Of Mo-Rich Nuclear Waste  

SciTech Connect

Crystalline and glass composite materials are currently being investigated for the immobilization of combined High Level Waste (HLW) streams resulting from potential commercial fuel reprocessing scenarios. Several of these potential waste streams contain elevated levels of transition metal elements such as molybdenum (Mo). Molybdenum has limited solubility in typical silicate glasses used for nuclear waste immobilization. Under certain chemical and controlled cooling conditions, a powellite (Ba,Ca)MoO{sub 4} crystalline structure can be formed by reaction with alkaline earth elements. In this study, single phase BaMoO{sub 4} and CaMoO{sub 4} were formed from carbonate and oxide precursors demonstrating the viability of Mo incorporation into glass, crystalline or glass composite materials by a melt and crystallization process. X-ray diffraction, photoluminescence, and Raman spectroscopy indicated a long range ordered crystalline structure. In-situ electron irradiation studies indicated that both CaMoO{sub 4} and BaMoO{sub 4} powellite phases exhibit radiation stability up to 1000 years at anticipated doses with a crystalline to amorphous transition observed after 1 X 10{sup 13} Gy. Aqueous durability determined from product consistency tests (PCT) showed low normalized release rates for Ba, Ca, and Mo (<0.05 g/m{sup 2}).

Brinkman, Kyle [Savannah River Site (SRS), Aiken, SC (United States); Marra, James [Savannah River Site (SRS), Aiken, SC (United States); Fox, Kevin [Savannah River Site (SRS), Aiken, SC (United States); Reppert, Jason [Savannah River Site (SRS), Aiken, SC (United States); Crum, Jarrod [Paci fic Northwest National Laboratory , Richland, WA (United States); Tang, Ming [Los Alamos National Laboratory , Los Alamos, NM (United States)

2012-09-17T23:59:59.000Z

85

Demonstration of Solar-Pumped Laser-Induced Magnesium ...  

Science Conference Proceedings (OSTI)

About this Abstract. Meeting, 2012 TMS Annual Meeting & Exhibition. Symposium , Magnesium Technology 2012. Presentation Title, Demonstration of ...

86

greenhouse gas balance of magnesium parts for automotive ...  

Science Conference Proceedings (OSTI)

Jul 20, 2012 ... GREENHOUSE GAS BALANCE OF MAGNESIUM PARTS FOR AUTOMOTIVE APPLICATIONS by Simone Ehrenberger, Horst E. Friedrich ...

87

TMS Professional Honors and Awards: LMD Magnesium Award  

Science Conference Proceedings (OSTI)

TMS ENERGY INITIATIVES · KNOWLEDGE ... 2005, “Heated Hydro-Mechanical Deep Drawing of Magnesium Sheet Metal” Gerrit Kurz, University of Hanover.

88

Exfoliated MoS2 Nanocomposite as an Anode Material for Lithium Ion Batteries  

DOE Green Energy (OSTI)

Nanocomposites of molybdenum disulfide (MoS2) and poly(ethylene oxide) (PEO) were prepared by the exfoliation/absorption method that involved the hydrolysis of lithiated MoS2 in an aqueous solution of PEO. The absorption and subsequent interaction of PEO on the colloidal MoS2 formed a nanocomposite which restacked into layered secondary particles. X-ray diffraction and high resolution TEM indicated that highly disordered nanocomposites were produced when the Lix(PEO)yMoS2 stoichiometry was limited to y < 1. An improvement of greater than 5x in capacity accompanied by high cycle stability and efficiency was observed for the disordered nanocomposites providing a novel approach to utilize low-cost MoS2 and similar materials for a high capacity energy storage system.

Xiao, Jie; Choi, Daiwon; Cosimbescu, Lelia; Koech, Phillip K.; Liu, Jun; Lemmon, John P.

2010-05-04T23:59:59.000Z

89

Development of LEU targets for {sup 99}Mo production and their chemical processing status 1993  

SciTech Connect

Most of the world`s supply of {sup 99m}{Tc} for medical purposes is currently produced from {sup 99}Mo derived from the fastening of high enriched uranium (HEU). Substitution of low enriched uranium (LEU) silicide fuel for the HEU alloy and aluminide fuels used in current target designs will allow equivalent {sup 99}Mo yields with little change in target geometries. Substitution of uranium metal for uranium oxide films in other target designs will also allow the substitution of LEU for HEU. In 1993, DOE renewed funding that was terminated in 1990 for development of LEU targets for {sup 99}Mo production. During the past year, our efforts were to (1) renew contact with {sup 99}Mo producers, (2) define the means to test our process for recovering {sup 99}Mo from irradiated LEU-silicide targets, and (3) begin to test our process on spent LEU-silicide miniplates stored at ANL from past fuel development studies.

Vandegrift, G.F.; Hutter, J.C.; Srinivasan, B.; Matos, J.E.; Snelgrove, J.L.

1993-10-01T23:59:59.000Z

90

Climate VISION: Private Sector Initiatives: Magnesium: Resources and Links  

Office of Scientific and Technical Information (OSTI)

Plant Assessments Plant Assessments Greenhouse Gas Protocol (PDF 190 KB) Download Acrobat Reader Paper written by Bill Palmer, Cheminfo Services, Inc. Molten magnesium and its alloys are volatile substances that have a tendency to oxidize explosively in air and require surface protection in casting processes. Save Energy Now Assessments The Save Energy Now assessments program is one way for plants of all sizes to work with the DOE Industrial Technologies Program (ITP). Large plants are eligible to apply for a system level assessment on their steam, process heating, compressed air, fans, or pumping systems. Assessments are conducted over a three day site visit by teams of DOE Energy Experts and plant personnel. The plant personnel are trained to identify energy savings opportunities using the DOE software tools. Most plants find an average of

91

Direct Hydrogenation Magnesium Boride to Magnesium Borohydride: Demonstration of >11 Weight Percent Reversible Hydrogen Storage  

DOE Green Energy (OSTI)

We here for the first time demonstrate direct hydrogenation of magnesium boride, MgB2, to magnesium borohydride, Mg(BH4)2 at 900 bar H2-pressures and 400°C. Upon 14.8wt% hydrogen release, the end-decomposition product of Mg(BH4)2 is MgB2, thus, this is a unique reversible path here obtaining >11wt% H2 which implies promise for a fully reversible hydrogen storage material.

Severa, Godwin; Ronnebro, Ewa; Jensen, Craig M.

2010-11-16T23:59:59.000Z

92

Soft X-ray Spectroscopy of C60/Copper Phthalocyanine/MoO3 Interfaces: Role of Reduced MoO3 on Energetic Band Alignment and Improved Performance  

Science Conference Proceedings (OSTI)

The interfacial electronic structure of C{sub 60}/copper phthalocyanine (CuPc)/molybdenum trioxide (MoO{sub 3}) thin films grown in situ on indium tin oxide (ITO) substrates has been studied using synchrotron radiation-excited photoelectron spectroscopy in an attempt to understand the influence of oxide interlayers on the performance of small molecule organic photovoltaic devices. The MoO{sub 3} layer on ITO is found to significantly increase the work function of the substrate and induces large interface dipoles and band bending at the CuPc/MoO{sub 3} interface. The large band bending confirms the formation of an internal potential that assists hole extraction from the CuPc layer to the electrode. The electronic structure of the MoO{sub 3} layer on ITO was also examined using various soft X-ray spectroscopies to probe the conductive nature of the MoO{sub 3} thin film.

S Cho; L Piper; A DeMasi; A Preston; K Smith; K Chauhan; R Hatton; T Jones

2011-12-31T23:59:59.000Z

93

Improved magnesium/manganese dioxide electrochemical cell  

SciTech Connect

A magnesium/manganese dioxide electrochemical cell, stored following partial usage, is improved by increasing the cathode moisture content at the time of making the cell to reduce the self-discharge and increase the operating capacity after the cell has been stored following partial usage.

Jarvis, L.P.; Brundage, M.T.; Atwater, T.B.

1988-11-10T23:59:59.000Z

94

Assessment of the magnesium primary production technology. Final report  

SciTech Connect

At current production levels, direct energy savings achievable in primary magnesium production are 1.2 milliquads of energy per annum. Were magnesium to penetrate the automotive market to an average level of 50 pounds per vehicle, the resultant energy savings at the production stage would be somewhat larger, but the resulting savings in gasoline would conserve an estimated 325 milliquads of energy per year. The principal barrier to more widespread use of magnesium in the immediate future is its price. A price reduction of magnesium of 10% would lead to widespread conversion of aluminum die and permanent mold castings to magnesium. This report addresses the technology of electrolytic and thermic magnesium production and the economics of expanded magnesium production and use.

Flemings, M.C.; Kenney, G.B.; Sadoway, D.R.; Clark, J.P.; Szekely, J.

1981-02-01T23:59:59.000Z

95

Compaction and Sintering of Mo Powders  

SciTech Connect

To support the development of Mo-99 production by NorthStar Medical Technologies, LLC, Mo metal powders were evaluated for compaction and sintering characteristics as they relate to Mo-100 accelerator target disk fabrication. Powders having a natural isotope distribution and enriched Mo-100 powder were examined. Various powder characteristics are shown to have an effect on both the compaction and sintering behavior. Natural Mo powders could be cold pressed directly to >90% density. All of the powders, including the Mo-100 samples, could be sintered after cold pressing to >90% density. As an example, a compacted Mo-100 disk reached 89.7% density (9.52 g/cm3) after sintering at 1000 C for 1 hr. in flowing Ar/4%H2. Higher sintering temperatures were required for other powder samples. The relationships between processing conditions and the resulting densities of consolidated Mo disks will be presented.

Nunn, Stephen D [ORNL; Kiggans, Jim [ORNL; Bryan, Chris [ORNL

2013-01-01T23:59:59.000Z

96

DOE - Office of Legacy Management -- St Louis Airport - MO 01  

Office of Legacy Management (LM)

Airport - MO 01 Airport - MO 01 FUSRAP Considered Sites St. Louis Airport, MO Alternate Name(s): Airport Site St. Louis Airport Storage Site (SLAPS) Former Robertson Storage Area Robertson Airport MO.01-1 MO.01-2 Location: Brown Road, Robertson, Missouri MO.01-2 Historical Operations: Stored uranium process residues containing uranium, radium, and thorium for the MED and AEC. MO.01-2 MO.01-3 MO.01-4 Eligibility Determination: Eligible MO.01-1 MO.01-7 Radiological Survey(s): Assessment Surveys MO.01-4 MO.01-5 Site Status: Cleanup in progress by U.S. Army Corps of Engineers. MO.01-6 USACE Website Long-term Care Requirements: To be determined upon completion. Also see Documents Related to St. Louis Airport, MO MO.01-1 - DOE Memorandum; Coffman to LaGrone; Subject: Authorization

97

High-quantum efficiency, long-lived luminescing refractory oxides  

DOE Patents (OSTI)

A crystal having a high-quantum efficiency and a long period of luminescence is formed of an oxide selected from the group consisting of magnesium oxide and calcium oxide and possessing a concentration ratio of H.sup.- ions to F centers in the range of about 0.05 to about 10.

Chen, Yok (Oak Ridge, TN); Gonzalez, Roberto (Knoxville, TN); Summers, Geoffrey P. (Stillwater, OK)

1984-01-01T23:59:59.000Z

98

Sol-gel preparation of lead magnesium niobate (PMN) powders and thin films  

DOE Patents (OSTI)

A method of preparing a lead magnesium niobium oxide (PMN), Pb(Mg{sub 1/3}Nb{sub 2/3})O{sub 3}, precursor solution by a solvent method wherein a liquid solution of a lead-complex PMN precursor is combined with a liquid solution of a niobium-complex PMN precursor, the combined lead- and niobium-complex liquid solutions are reacted with a magnesium-alkyl solution, forming a PMN precursor solution and a lead-based precipitate, and the precipitate is separated from the reacted liquid PMN precursor solution to form a precipitate-free PMN precursor solution. This precursor solution can be processed to form both ferroelectric powders and thin films. 3 figs.

Boyle, T.J.

1999-01-12T23:59:59.000Z

99

Sol-Gel Preparation Of Lead Magnesium Ni Obate (Pmn) Powdersand Thin Films  

DOE Patents (OSTI)

A method of preparing a lead magnesium niobium oxide (PMN), Pb(Mg.sub.1/3 Nb.sub.2/3)O.sub.3, precursor solution by a solvent method wherein a liquid solution of a lead-complex PMN precursor is combined with a liquid solution of a niobium-complex PMN precursor, the combined lead- and niobium-complex liquid solutions are reacted with a magnesium-alkyl solution, forming a PMN precursor solution and a lead-based precipitate, and the precipitate is separated from the reacted liquid PMN precursor solution to form a precipitate-free PMN precursor solution. This precursor solution can be processed to form both ferroelectric powders and thin films.

Boyle, Timothy J. (Albuquerque, NM)

1999-01-12T23:59:59.000Z

100

Lead magnesium niobate actuator for micropositioning  

DOE Patents (OSTI)

An improved lead magnesium niobate actuator is disclosed comprising a cylindrical lead magnesium niobate crystal stack mounted in a cylindrical casing wherein a bias means, such as one or more belleville washers, is located between one end of the crystal stack and a partially closed end of the casing; and adjustment means are provided which bear against the opposite end of the crystal stack, whereby an adjustable compressive force is constantly applied against the crystal stack, whether the crystal stack is actuated in an extended position, or is in an unactuated contracted position. In a preferred embodiment, cooling ports are provided for the circulation of coolant in the actuator to cool the crystal stack, and provision is made for removal and replacement of the crystal stack without disconnecting the actuator from the external device being actuated. 3 figs.

Swift, C.D.; Bergum, J.W.

1994-10-25T23:59:59.000Z

Note: This page contains sample records for the topic "mo magnesium oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Electrochemically Induced High Capacity Displacement Reaction of PEO/MoS2/Graphene Nanocomposites with Lithium  

SciTech Connect

MoS2/PEO/graphene composite is successfully prepared and the discharge mechanism of MoS2 as an anode material for Li-ion batteries has been investigated systematically in this work. The simultaneous formation of Li2S and Mo at deep discharge depth has been shown for the first time. The deposition of Mo metal with Li residing on the defects after the first discharge increases the intrinsic electronic conductivity of the electrode leading to a superior cycling stability for over 185 cycles. After the first discharge the amorphous Mo matrix allows a large amount of Li+ ions to repeatedly deposit and being oxidized during cycling while the transition between Li2S and S contribute to the capacity above 2.0 V. The interactions between as-formed Mo and S prevents the dissolution of the intermediate polysulfide thus providing clues to immobilize the soluble species in a Li-S battery. Excellent rate performances are achieved in this MoS2/PEO/graphene composite indicating a fast diffusion path of Li+ ions existing not only in the bulk material but also in the interface between the electrode and the electrolyte.

Xiao, Jie; Wang, Xaojian; Yang, Xiao-Qing; Xun, Shidi; Liu, Gao; Koech, Phillip K.; Liu, Jun; Lemmon, John P.

2011-08-09T23:59:59.000Z

102

Aqueous Phase Glycerol Reforming by PtMo Bimetallic Nano-Particle Catalyst: Product Selectivity and Structural Characterization  

Science Conference Proceedings (OSTI)

A carbon supported PtMo aqueous phase reforming catalyst for producing hydrogen from glycerol was characterized by analysis of the reaction products and pathway, TEM, XPS and XAS spectroscopy. Operando X-ray absorption spectroscopy (XAS) indicates the catalyst consists of bimetallic nano-particles with a Pt rich core and a Mo rich surface. XAS of adsorbed CO indicates that approximately 25% of the surface atoms are Pt. X-ray photoelectron spectroscopy indicates that there is unreduced and partially reduced Mo oxide (MoO{sub 3} and MoO{sub 2}), and Pt-rich PtMo bimetallic nano-particles. The average size measured by transmission electron microscopy of the fresh PtMo nano-particles is about 2 nm, which increases in size to 5 nm after 30 days of glycerol reforming at 31 bar and 503 K. The catalyst structure differs from the most energetically stable structure predicted by density functional theory (DFT) calculations for metallic Pt and Mo atoms. However, DFT indicates that for nano-particles composed of metallic Pt and Mo oxide, the Mo oxide is at the particle surface. Subsequent reduction would lead to the experimentally observed structure. The aqueous phase reforming reaction products and intermediates are consistent with both C-C and C-OH bond cleavage to generate H{sub 2}/CO{sub 2} or the side product CH{sub 4}. While the H{sub 2} selectivity at low conversion is about 75%, cleavage of C-OH bonds leads to liquid products with saturated carbon atoms. At high conversions (to gas), these will produced additional CH{sub 4} reducing the H{sub 2} yield and selectivity.

Stach E. A.; Dietrich, P.J.; Lobo-Lapidus, R.J.; Wu, T.; Sumer, A.; Akatay, M.C.; Fingland, B.R.; Guo, N.; Dumesic, J.A.; Marshall, C.L.; Jellinek, J.; Delgass, W.N.; Ribeiro, F.H.; Miller, J.T.

2012-03-01T23:59:59.000Z

103

Reversible Dehydrogenation of Magnesium Borohydride to Magnesium Triborane in the Solid State Under Moderate Conditions  

DOE Green Energy (OSTI)

Thermal decomposition of magnesium borohydride, Mg(BH4)2, in the solid state was studied by a combination of PCT, TGA/MS and NMR spectroscopy. Dehydrogenation of Mg(BH4)2 at 200 °C, results in the highly selective formation of magnesium triborane, Mg(B3H8)2. This process is reversible at 250 °C under 120 atm H2. Dehydrogenation at higher temperature, > 300 °C, produces a complex mixture of polyborane species. Solution phase 11B NMR spectra of the hydrolyzed decomposition products reveals the formation of the B3H8 anion, boric acid from hydrolysis of the unstable polyboranes (BnHx) (n = 3-11, x >8), and the closoborane B12H12 dianion as a minor product. A BH condensation mechanism involving metal hydride formation is proposed to explain the limited reversible hydrogen storage in magnesium borohydride.

Chong, Marina; Karkamkar, Abhijeet J.; Autrey, Thomas; Orimo, Shin-ichi; Jalisatgi, Satish; Jensen, Craig M.

2011-02-17T23:59:59.000Z

104

Electrochemical properties of sputter-deposited MoO{sub 3} films in lithium microbatteries  

Science Conference Proceedings (OSTI)

Molybdenum oxide (MoO{sub 3}) films were prepared by magnetron sputtering using an Mo target. The films were sputtered in the reactive atmosphere of an argon-oxygen gas mixture under various substrate temperatures, T{sub s}, and oxygen partial pressures, p(O{sub 2}). The effects of the growth conditions on the microstructure were examined using reflection high-energy electron diffraction and x-ray photoelectron spectroscopy. The analyses indicate that stoichiometric and polycrystalline MoO{sub 3} films were obtained at T{sub s} = 445 Degree-Sign C and p(O{sub 2}) = 61%. The applicability of the sputtered MoO{sub 3} films for lithium microbattery application has been demonstrated. The discharge-charge profiles, the kinetics of lithium intercalation process in the film, and the cycling behavior have been investigated in detail to understand the effect of microstructure on the electrochemical performance.

Ramana, C. V.; Atuchin, V. V.; Groult, H.; Julien, C. M. [Department of Mechanical Engineering, University of Texas at El Paso, El Paso, Texas 79968 (United States); Institute of Semiconductor Physics, SB RAS, Novosibirsk, 630090 (Russian Federation); Physicochimie des Electrolytes, Colloiedes et Systemes Analytiques (PECSA), Universite Pierre et Marie Curie-Paris 6, UMR 7195, 4 place Jussieu, 75005 Paris (France)

2012-07-15T23:59:59.000Z

105

Method for the production of {sup 99m}Tc compositions from {sup 99}Mo-containing materials  

DOE Patents (OSTI)

An improved method is described for producing {sup 99m}Tc compositions from {sup 99}Mo compounds. {sup 100}Mo metal or {sup 100}MoO{sub 3} is irradiated with photons in a particle (electron) accelerator to ultimately produce {sup 99}MoO{sub 3}. This composition is then heated in a reaction chamber to form a pool of molten {sup 99}MoO{sub 3} with an optimum depth of 0.5--5 mm. A gaseous mixture thereafter evolves from the molten {sup 99}MoO{sub 3} which contains vaporized {sup 99}MoO{sub 3}, vaporized {sup 99m}TcO{sub 3}, and vaporized {sup 99m}TcO{sub 2}. This mixture is then combined with an oxidizing gas (O{sub 2(g)}) to generate a gaseous stream containing vaporized {sup 99m}Tc{sub 2}O{sub 7} and vaporized {sup 99}MoO{sub 3}. Next, the gaseous stream is cooled in a primary condensation stage in the reaction chamber to remove vaporized {sup 99}MoO{sub 3}. Cooling is undertaken at a specially-controlled rate to achieve maximum separation efficiency. The gaseous stream is then cooled in a sequential secondary condensation stage to convert vaporized {sup 99m}Tc{sub 2}O{sub 7} into a condensed {sup 99m}Tc-containing reaction product which is collected. 1 fig.

Bennett, R.G.; Christian, J.D.; Grover, S.B.; Petti, D.A.; Terry, W.K.; Yoon, W.Y.

1998-09-01T23:59:59.000Z

106

Formation of Vanadate Conversion Coating on AZ31 Magnesium Alloy  

Science Conference Proceedings (OSTI)

In the present investigation, a chromate-free, corrosion-resistant conversion coating using vanadium based solution was applied to AZ31 magnesium alloy.

107

Stress Corrosion Cracking of Aluminium-Free Magnesium Alloys in ...  

Science Conference Proceedings (OSTI)

Presentation Title, Stress Corrosion Cracking of Aluminium-Free Magnesium Alloys in a Simulated Human Body Fluid. Author(s), Lokesh Choudhary, R. K. Singh ...

108

Climate VISION: Private Sector Initiatives: Magnesium: GHG Information  

Office of Scientific and Technical Information (OSTI)

GHG Information The magnesium industry directly emits SF6 from its primary metal production, parts casting, and recycling operations. In 2005, the industry's SF6 emissions were...

109

Fatigue Predictions of Various Joints of Magnesium Alloys  

Science Conference Proceedings (OSTI)

Currently, a front shock tower of passenger vehicle is developed with various magnesium alloys and joining methods. To predict the fatigue behavior of the joints ...

110

Cryoscopic Data for Hall-Héroult Bath Containing Magnesium ...  

Science Conference Proceedings (OSTI)

Presentation Title, Cryoscopic Data for Hall-Héroult Bath Containing Magnesium Fluoride, Calcium Fluoride, Potassium Cryolite, and Sodium Chloride. Author(s) ...

111

Recycling Magnesium Alloy Housings for Notebook Computers - TMS  

Science Conference Proceedings (OSTI)

Jul 1, 2008 ... This article from Fujitsu Laboratories describes two recycling processes for magnesium alloy housings: one for recycling the excess material ...

112

Climate VISION: Private Sector Initiatives: Magnesium: GHG Inventory...  

Office of Scientific and Technical Information (OSTI)

GHG Inventory Protocols The Magnesium Industry Partnership's SF6 emissions tracking and reporting software tool (Excel based) can be accessed by visiting the Partnership's...

113

WEB RESOURCE: Magnesium Wrought Products Flow Chart - TMS  

Science Conference Proceedings (OSTI)

Aug 18, 2007 ... The following flow charts attempt to list important wrought magnesium products being made as extrusions, forgings, sheet and plate. In these ...

114

WEB RESOURCE: Magnesium Cast Products Flow Chart - TMS  

Science Conference Proceedings (OSTI)

Aug 18, 2007 ... The following flow charts attempt to list important cast magnesium products being made as die castings, sand and permanent mold castings ...

115

Rechargeable Magnesium Batteries: Low-Cost Rechargeable Magnesium Batteries with High Energy Density  

Science Conference Proceedings (OSTI)

BEEST Project: Pellion Technologies is developing rechargeable magnesium batteries that would enable an EV to travel 3 times farther than it could using Li-ion batteries. Prototype magnesium batteries demonstrate excellent electrochemical behavior; delivering thousands of charge cycles with very little fade. Nevertheless, these prototypes have always stored too little energy to be commercially viable. Pellion Technologies is working to overcome this challenge by rapidly screening potential storage materials using proprietary, high-throughput computer models. To date, 12,000 materials have been identified and analyzed. The resulting best materials have been electrochemically tested, yielding several very promising candidates.

None

2010-10-01T23:59:59.000Z

116

Stationary storage and purification of hydrogen using nickel-coated magnesium powder. Final technical report  

DOE Green Energy (OSTI)

The following conclusions were reached: (1) The concept of a coating on a magnesium particle serving as a well-supported hydrogen-permselective membrane is sound. (2) Magnesium nitride can be made to coat magnesium particles through chemical vapor deposition within a fluidized bed. (3) Magnesium nitride exhibits the properties necessary for such a coating. (4) Magnesium nitride is not chemically inert to hydrogen in the absence of ammonia at temperatures typically used to hydride/dehydride magnesium.

NONE

1999-12-30T23:59:59.000Z

117

The eects of CO2, CO and H2 co-reactants on methane reactions catalyzed by Mo/H-ZSM-5  

E-Print Network (OSTI)

partial oxidation and autothermal or steam reforming is currently practiced [1±4]. Catalytic pyrolysisThe eects of CO2, CO and H2 co-reactants on methane reactions catalyzed by Mo/H-ZSM-5 Zheng Liu-reactants; methane reactions; Mo/H-ZSM-5 catalyst. 1. Introduction The direct conversion of natural gas

Iglesia, Enrique

118

DOE - Office of Legacy Management -- Latty Avenue Site - MO 04  

NLE Websites -- All DOE Office Websites (Extended Search)

Latty Avenue Site - MO 04 Latty Avenue Site - MO 04 FUSRAP Considered Sites Latty Avenue Site, MO Alternate Name(s): Futura Coatings Futura Chemical Company Facility Hazelwood Interim Storage Site (HISS) Former Cotter Site, Latty Avenue Properties Contemporary Metals Corp. Continental Mining and Milling MO.04-1 MO.04-2 MO.04-5 MO.04-6 MO.06-8 MO.06-11 Location: 9200 Latty Avenue, Hazelwood, Missouri MO.04-1 Historical Operations: Received, stored, and processed uranium residues for the AEC. Storage and processing were licensed by the AEC and NRC and resulted in contamination of uranium and thorium. MO.04-5 MO.04-6 Eligibility Determination: Eligible MO.04-3 MO.04-4 Radiological Survey(s): Assessment Surveys MO.04-2 MO.04-7 MO.04-8 MO.04-9 MO.04-10 MO.04-11 Site Status: Cleanup in progress by U.S. Army Corps of Engineers. MO.04-12

119

Yittria and Alumina Nano-scale Oxide-dispersion-strengthened (ODS)  

Science Conference Proceedings (OSTI)

Effect of Oxide Dispersion Strengthening on Spark Plasma Sintering Kinetics of 13Cr-2Mo ... Synthesis of TiN Nanorods by Thermal Decomposition of Solid/Gas

120

Nano-engineering of magnesium hydride for hydrogen storage  

Science Conference Proceedings (OSTI)

The destabilization of magnesium hydride (MgH"2) by solid-state reaction with Si in a nanoscale under vacuum was studied. The nanostructured Si films were deposited on the nanocrystalline MgH"2/Mg composite substrate by the pulsed laser deposition (PLD). ... Keywords: Destabilization, Magnesium hydride, Microstructure, Nano-engineering, Silicon

J. Bystrzycki; T. P?oci?ski; W. Zieli?ski; Z. Winiewski; M. Polanski; W. Mróz; Z. Bojar; K. J. Kurzd?owski

2009-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "mo magnesium oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Casting Porosity-Free Grain Refined Magnesium Alloys  

SciTech Connect

The objective of this project was to identify the root causes for micro-porosity in magnesium alloy castings and recommend remedies that can be implemented in production. The findings confirm the key role played by utilizing optimal gating and risering practices in minimizing porosity in magnesium castings.?

Schwam, David [Case Western Reserve University] [Case Western Reserve University

2013-08-12T23:59:59.000Z

122

Climate VISION: Private Sector Initiatives: Magnesium: Resources and Links  

Office of Scientific and Technical Information (OSTI)

Technical Information Technical Information Publications CD-ROMs Publications The following publications are available for download as Adobe PDF documents. Download Acrobat Reader Cooperative Study of Magnesium Melt Protection Technologies: Emissions Characterization and Occupational Exposure. (PDF 275 KB) EPA Conference on SF6 and the Environment (2006) presentation by Holger Brandt, Lunt Manufacturing, and Scott Bartos, U.S. EPA. The Alternatives to SF6 for Magnesium Melt Protection brochure, published in Chinese, English, and Japanese language versions, was first introduced to the industry and public at the 63rd Annual World Magnesium Conference in Beijing, China on May 21, 2006. EPA collaborated with the International Magnesium Association (IMA), China Magnesium Association (CMA), and Japan

123

Large-Scale Mercury Control Technology Testing for Lignite-Fired Utilities - Oxidation Systems for Wet FGD  

Science Conference Proceedings (OSTI)

Mercury (Hg) control technologies were evaluated at Minnkota Power Cooperative's Milton R. Young (MRY) Station Unit 2, a 450-MW lignite-fired cyclone unit near Center, North Dakota, and TXU Energy's Monticello Steam Electric Station (MoSES) Unit 3, a 793-MW lignite--Powder River Basin (PRB) subbituminous coal-fired unit near Mt. Pleasant, Texas. A cold-side electrostatic precipitator (ESP) and wet flue gas desulfurization (FGD) scrubber are used at MRY and MoSES for controlling particulate and sulfur dioxide (SO{sub 2}) emissions, respectively. Several approaches for significantly and cost-effectively oxidizing elemental mercury (Hg{sup 0}) in lignite combustion flue gases, followed by capture in an ESP and/or FGD scrubber were evaluated. The project team involved in performing the technical aspects of the project included Babcock & Wilcox, the Energy & Environmental Research Center (EERC), the Electric Power Research Institute, and URS Corporation. Calcium bromide (CaBr{sub 2}), calcium chloride (CaCl{sub 2}), magnesium chloride (MgCl{sub 2}), and a proprietary sorbent enhancement additive (SEA), hereafter referred to as SEA2, were added to the lignite feeds to enhance Hg capture in the ESP and/or wet FGD. In addition, powdered activated carbon (PAC) was injected upstream of the ESP at MRY Unit 2. The work involved establishing Hg concentrations and removal rates across existing ESP and FGD units, determining costs associated with a given Hg removal efficiency, quantifying the balance-of-plant impacts of the control technologies, and facilitating technology commercialization. The primary project goal was to achieve ESP-FGD Hg removal efficiencies of {ge}55% at MRY and MoSES for about a month.

Steven A. Benson; Michael J. Holmes; Donald P. McCollor; Jill M. Mackenzie; Charlene R. Crocker; Lingbu Kong; Kevin C. Galbreath

2007-03-31T23:59:59.000Z

124

Cross sections for electron scattering from magnesium  

SciTech Connect

A B-spline R-matrix (close-coupling) method has been used to perform a systematic study of angle-differential cross sections for electron scattering from neutral magnesium. The calculations cover elastic scattering and excitation of the five excited states (3s3p) {sup 3,1}P{sup o}, (3s3d) {sup 1}D, (3s4s) {sup 1}S, and (3s4p) {sup 1}P{sup o}. A multiconfiguration Hartree-Fock method with nonorthogonal orbitals was employed for an accurate representation of the target wave functions. The close-coupling expansion for the collision problem included 37 bound states of neutral magnesium. Angle-differential cross sections are presented for incident electron energies from 10 to 100 eV. These results, as well as the corresponding angle-integrated cross sections, are compared with various experimental data and predictions from other close-coupling and distorted-wave calculations. In spite of a few remaining discrepancies, the overall agreement between our results and the experimental data is very satisfactory.

Zatsarinny, Oleg; Bartschat, Klaus; Gedeon, Sergey; Gedeon, Viktor; Lazur, Vladimir; Nagy, Elizabeth [Department of Physics and Astronomy, Drake University, Des Moines, Iowa 50311 (United States); Department of Theoretical Physics, Uzhgorod State University, Uzhgorod 88000 (Ukraine)

2009-05-15T23:59:59.000Z

125

Fundamental studies of the mechanism of catalytic reactions with catalysts effective in the gasification of carbon solids and the oxidative coupling of methane. Quarterly report, April 1, 1992--June 30, 1992  

DOE Green Energy (OSTI)

Work continued on the catalytic conversion of methane to produce C{sub 2}, C{sub 3},and C{sub 4} hydrocarbons. Progress is reported on the catalytic effects of Lithium Oxide and Magnesium Oxide catalysts.

Heinemann, H.; Somorjai, G.A.; Perry, D.L.

1992-06-01T23:59:59.000Z

126

Unprecedented {sup 1}/{sub {infinity}}[{beta}-Mo{sub 8}O{sub 26}]{sup 4-} polymeric chains and four novel organic-inorganic hybrids based on Mo-POMs and azaheterocycles templates  

Science Conference Proceedings (OSTI)

Abstrct: Four novel organic-inorganic hybrid materials based on Mo-POMs and organic templates, namely [DEB] [{beta}-Mo{sub 8}O{sub 26}] [NH{sub 4}]{sub 2} (1), [BMIM] [{beta}-Mo{sub 8}O{sub 26}]{sub 0.5}{center_dot}H{sub 2}O (2), [BMIM] [1D-Mo{sub 8}O{sub 26}]{sub 0.5} (3) and {l_brace}3D-[Cu(DIE){sub 2}] [1D-Mo{sub 8}O{sub 26}]{sub 0.5}{r_brace}{sub {infinity}} (4) [DEB= 1,1 Prime -diethyl-4,4 Prime -bipyridinium, BMIM=1,1 Prime -bis(1-methylimidazolium)methylene, DIE=1,2-diimidazoloethane] have been hydrothermally synthesized and characterized by elemental analyses, IR spectroscopy, thermal gravimetric analysis(TGA) and single-crystal X-ray diffraction. Both compounds 1 and 2 are POMs-based supramolecular compounds consisted of independent [{beta}-Mo{sub 8}O{sub 26}]{sup 4-} anions and [DEB]{sup 2+} or [BMIM]{sup 2+} organic cations. Compound 3 is the first external template example of Mo-POMs-based supramolecular network incorporated with novel {sup 1}/{sub {infinity}}[{beta}-Mo{sub 8}O{sub 26}]{sup 4-} polymeric chains. Compound 4 is a rare supramolecular structure that contains octamolybdate {sup 1}/{sub {infinity}}[{beta}-Mo{sub 8}O{sub 26}]{sup 4-} polymeric chains interconnected via DIE ligands to form a 3D net. Moreover, it was indicated that these polyacid compounds had definite catalytic activities on the probe reaction of acetaldehyde oxidation to acetic acid with H{sub 2}O{sub 2}. - Graphical abstract: Four novel organic templated polyoxometalates comprising of 0D, 1D and 3D supramolecular frameworks together with the catalytic activities on the acetaldehyde oxidation to acetic acid were reported. Highlights: Using cation templated self-assembly four novel polyoxometalates were prepared. Compounds 1 and 2 consisted of independent [{beta}-Mo{sub 8}O{sub 26}]{sup 4-} anions and organic cations. Compound 3 is the first external template-assisted POMs with {sup 1}/{sub {infinity}}[{beta}-Mo{sub 8}O{sub 26}]{sup 4-} chain. Compound 4 is a rare 3D net containing {sup 1}/{sub {infinity}}[{beta}-Mo{sub 8}O{sub 26}]{sup 4-} 1D chain and DIE ligands. These compounds had definite catalytic activities on the acetaldehyde oxidation.

Du Haijuan; Zunzhe Shu [College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001 (China); Niu Yunyin, E-mail: niuyy@zzu.edu.cn [College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001 (China); Song Lisha; Zhu Yu [College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001 (China)

2012-06-15T23:59:59.000Z

127

/sup 238/PuO/sub 2//Mo-50 wt% Re compatibility at 800 and 1000/sup 0/C  

DOE Green Energy (OSTI)

The compatibility of Mo-50 wt % Re with /sup 238/PuO/sub 2/ was investigated after heat treatments of up to 720 days at 800/sup 0/C and 180 days at 1000/sup 0/C. At 800/sup 0/C, a 1-..mu..m thick, continuous layer of molybdenum oxide resulted. At 1000/sup 0/C, the oxide reaction product contained some plutonium and did not appear continuous. At 1000/sup 0/C, a layer of intermetallic formed at the Mo-Re edge, beneath the oxide layer, creating a barrier between the Mo-50 wt % Re and the /sup 238/PuO/sub 2/. The intermetallic layer was promoted by the iron impurity in the /sup 238/PuO/sub 2/.

Schaeffer, D.R.; Teaney, P.E.

1980-07-18T23:59:59.000Z

128

Category:Kansas City, MO | Open Energy Information  

Open Energy Info (EERE)

MO MO Jump to: navigation, search Go Back to PV Economics By Location Media in category "Kansas City, MO" The following 16 files are in this category, out of 16 total. SVFullServiceRestaurant Kansas City MO Union Electric Co.png SVFullServiceRestauran... 74 KB SVHospital Kansas City MO Union Electric Co.png SVHospital Kansas City... 66 KB SVLargeHotel Kansas City MO Union Electric Co.png SVLargeHotel Kansas Ci... 66 KB SVLargeOffice Kansas City MO Union Electric Co.png SVLargeOffice Kansas C... 65 KB SVMediumOffice Kansas City MO Union Electric Co.png SVMediumOffice Kansas ... 65 KB SVMidriseApartment Kansas City MO Union Electric Co.png SVMidriseApartment Kan... 74 KB SVOutPatient Kansas City MO Union Electric Co.png SVOutPatient Kansas Ci... 66 KB SVPrimarySchool Kansas City MO Union Electric Co.png

129

Thermophysical Properties of U-10MO Alloy  

Science Conference Proceedings (OSTI)

This report provides an overview of thermophysical properties of unirradiated uranium alloyed with ten weight percent molybdenum (U 10Mo), with particular focus on those material properties needed for modeling of new fuels for HPRRs (High Performance Research Reactors). The report contains both historical data available in the literature on U-10Mo, as well as more recent results conducted by the Global Threat Reduction Initiative fuel development program. The main use of the report is intended as a standard U-10Mo alloy properties reference for reactor models and simulations.

A. M. Phillips; G. S. Mickum; D. E. Burkes

2010-11-01T23:59:59.000Z

130

It's Elemental - Isotopes of the Element Magnesium  

NLE Websites -- All DOE Office Websites (Extended Search)

Sodium Sodium Previous Element (Sodium) The Periodic Table of Elements Next Element (Aluminum) Aluminum Isotopes of the Element Magnesium [Click for Main Data] Most of the isotope data on this site has been obtained from the National Nuclear Data Center. Please visit their site for more information. Naturally Occurring Isotopes Mass Number Natural Abundance Half-life 24 78.99% STABLE 25 10.00% STABLE 26 11.01% STABLE Known Isotopes Mass Number Half-life Decay Mode Branching Percentage 19 4.0 picoseconds Double Proton Emission 100.00% 20 90.8 milliseconds Electron Capture 100.00% Electron Capture with delayed Proton Emission ~ 27.00% 21 122 milliseconds Electron Capture 100.00% Electron Capture with delayed Proton Emission 32.60% Electron Capture with delayed Alpha Decay < 0.50%

131

Enhancing Tensile and Compressive Strength of AZ41 Magnesium ...  

Science Conference Proceedings (OSTI)

Al and 1 wt.% Al with 1.5 vol.% nano-sized Al2O3 (50 nm) particulates in to AZ31 magnesium alloy, respectively, using disintegrated melt deposition technique.

132

Controlling the Biodegradation Rate of Magnesium-Based Implants ...  

Science Conference Proceedings (OSTI)

Author(s), Z. Pu, D. Puleo, O.W. Dillon, Jr., I.S. Jawahir. On-Site ... By proper selection of machining conditions, magnesium-based implants with customized ...

133

SF6 Emission Reduction Partnership for the Magnesium Industry  

Science Conference Proceedings (OSTI)

Topic Summary: A cooperative effort between EPA and US magnesium industry to reduce emissions of SF6. Created On: 7/1/2008 9:12 AM, Topic View:.

134

What is MoWiTT  

NLE Websites -- All DOE Office Websites (Extended Search)

the net energy flow through two window samples in side-by-side tests using ambient weather conditions. MoWiTT characterizes the net energy flow as a function of time and...

135

FeAl and Mo-Si-B Intermetallic Coatings Prepared by Thermal Spraying  

SciTech Connect

FeAl and Mo-Si-B intermetallic coatings for elevated temperature environmental resistance were prepared using high-velocity oxy-fuel (HVOF) and air plasma spray (APS) techniques. For both coating types, the effect of coating parameters (spray particle velocity and temperature) on the microstructure and physical properties of the coatings was assessed. Fe-24Al (wt.%) coatings were prepared using HVOF thermal spraying at spray particle velocities varying from 540 m/s to 700 m/s. Mo-13.4Si-2.6B coatings were prepared using APS at particle velocities of 180 and 350 m/s. Residual stresses in the HVOF FeAl coatings were compressive, while stresses in the APS Mo-Si-B coatings were tensile. In both cases, residual stresses became more compressive with increasing spray particle velocity due to increased peening imparted by the spray particles. The hardness and elastic moduli of FeAl coatings also increased with increasing particle velocity, again due to an increased peening effect. For Mo-Si-B coatings, plasma spraying at 180 m/s resulted in significant oxidation of the spray particles and conversion of the T1 phase into amorphous silica and {alpha}-Mo. The T1 phase was retained after spraying at 350 m/s.

Totemeier, T.C.; Wright, R.N.; Swank, W.D.

2003-04-22T23:59:59.000Z

136

A22: Nanosized Chevrel Phase Materials of Mg-Cu-Mo6S8 System ...  

Science Conference Proceedings (OSTI)

Abstract Scope, Rechargeable magnesium battery might be a candidate of high energy ... Preliminary testing of magnesium battery, comprising Mg foil anodes, ...

137

Preparation and structural study from neutron diffraction data of Pr{sub 5}Mo{sub 3}O{sub 16}  

SciTech Connect

The title compound has been prepared as polycrystalline powder by thermal treatments of mixtures of Pr{sub 6}O{sub 11} and MoO{sub 2} in air. In the literature, an oxide with a composition Pr{sub 2}MoO{sub 6} has been formerly described to present interesting catalytic properties, but its true stoichiometry and crystal structure are reported here for the first time. It is cubic, isostructural with CdTm{sub 4}Mo{sub 3}O{sub 16} (space group Pn-3n, Z=8), with a=11.0897(1) A. The structure contains MoO{sub 4} tetrahedral units, with Mo-O distances of 1.788(2) A, fully long-range ordered with PrO{sub 8} polyhedra; in fact it can be considered as a superstructure of fluorite (M{sub 8}O{sub 16}), containing 32 MO{sub 2} fluorite formulae per unit cell, with a lattice parameter related to that of cubic fluorite (a{sub f}=5.5 A) as a{approx}2a{sub f}. A bond valence study indicates that Mo exhibits a mixed oxidation state between 5+ and 6+ (perhaps accounting for the excellent catalytic properties). One kind of Pr atoms is trivalent whereas the second presents a mixed Pr{sup 3+}-Pr{sup 4+} oxidation state. The similarity of the XRD pattern with that published for Ce{sub 2}MoO{sub 6} suggests that this compound also belongs to the same structural type, with an actual stoichiometry Ce{sub 5}Mo{sub 3}O{sub 16}. -- Graphical Abstract: Formerly formulated as Pr{sub 2}MoO{sub 6}, the title compound is a cubic superstructure of fluorite (a=11.0897(1) A, space group Pn-3n) due to the long-range ordering of PrO{sub 8} scalenohedra and MoO{sub 4} tetrahedral units, showing noticeable shifts of the oxygen positions in order to provide a tetrahedral coordination for Mo ions. A mixed valence Mo{sup 5+}-Mo{sup 6+} is identified, which could account for the excellent catalytic properties of this material. Display Omitted

Martinez-Lope, M.J. [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco, E-28049 Madrid, Spain. (Spain); Alonso, J.A., E-mail: ja.alonso@icmm.csic.e [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco, E-28049 Madrid, Spain. (Spain); Sheptyakov, D.; Pomjakushin, V. [Laboratory for Neutron Scattering, Paul Scherrer Institut, CH-5232 Villigen PSI (Switzerland)

2010-12-15T23:59:59.000Z

138

Potential automotive uses of wrought magnesium alloys  

DOE Green Energy (OSTI)

Vehicle weight reduction is one of the major means available to improve automotive fuel efficiency. High-strength steels, aluminum (Al), and polymers are already being used to reduce weight significantly, but substantial additional reductions could be achieved by greater use of low-density magnesium (Mg) and its alloys. Mg alloys are currently used in relatively small quantities for auto parts, generally limited to die castings (e.g., housings). Argonne National Laboratory`s Center for Transportation Research has performed a study for the Lightweight Materials Program within DOE`s Office of Transportation Materials to evaluate the suitability of wrought Mg and its alloys to replace steel/aluminum for automotive structural and sheet applications. Mg sheet could be used in body nonstructural and semi-structural applications, while extrusions could be used in such structural applications as spaceframes. This study identifies high cost as the major barrier to greatly increased Mg use in autos. Two technical R and D areas, novel reduction technology and better hot-forming technology, could enable major cost reductions.

Gaines, L.; Cuenca, R.; Wu, S. [Argonne National Lab., IL (United States); Stodolsky, F. [Argonne National Lab., IL (United States)]|[Argonne National Lab., Washington, DC (United States)

1996-06-01T23:59:59.000Z

139

M5Si3(M=Ti, Nb, Mo) Based Transition-Metal Silicides for High Temperature Applications  

Science Conference Proceedings (OSTI)

Transition metal silicides are being considered for future engine turbine components at temperatures up to 1600 C. Although significant improvement in high temperature strength, room temperature fracture toughness has been realized in the past decade, further improvement in oxidation resistance is needed. Oxidation mechanism of Ti{sub 5}Si{sub 3}-based alloys was investigated. Oxidation behavior of Ti{sub 5}Si{sub 3}-based alloy strongly depends on the atmosphere. Presence of Nitrogen alters the oxidation behavior of Ti{sub 5}Si{sub 3} by nucleation and growth of nitride subscale. Ti{sub 5}Si{sub 3.2} and Ti{sub 5}Si{sub 3}C{sub 0.5} alloys exhibited an excellent oxidation resistance in nitrogen bearing atmosphere due to limited dissolution of nitrogen and increased Si/Ti activity ratio. MoSi{sub 2} coating developed by pack cementation to protect Mo-based Mo-Si-B composites was found to be effective up to 1500 C. Shifting coating composition to T1+T2+Mo{sub 3}Si region showed the possibility to extend the coating lifetime above 1500 C by more than ten times via formation of slow growing Mo{sub 3}Si or T2 interlayer without sacrificing the oxidation resistance of the coating. The phase equilibria in the Nb-rich portion of Nb-B system has been evaluated experimentally using metallographic analysis and differential thermal analyzer (DTA). It was shown that Nb{sub ss} (solid solution) and NbB are the only two primary phases in the 0-40 at.% B composition range, and the eutectic reaction L {leftrightarrow} Nb{sub SS} + NbB was determined to occur at 2104 {+-} 5 C by DTA.

Zhihong Tang

2007-12-01T23:59:59.000Z

140

Synthesis and Characterization of Magnesium-Silicon and Magnesium-Tin Solid Solutions for Thermoelectric Applications  

E-Print Network (OSTI)

The environmentally friendly n-type Mg2(Si, Sn) thermoelectric solid solutions have a strong potential of commercial utilization in thermoelectric (TE) energy conversion due to their availability, low density (~3.02 g/cm3), and high stability at middle temperature range (400-600 ?C) that are typically observed from waste heat dissipating systems. The bulk materials were prepared from element powders via slow cooking under vacuum condition and current-assisted hot-press sintering. Temperature vs time curves have been researched in this thesis for fully reacted magnesium-silicide & magnesium-stannide green ingots with doping materials i.e. antimony, bismuth by different doping ratios. These ingots were ground by a high energy ball miller, uniaxial cold pressed into half inch pallets and then sintered by Direct Current-assisted hot pressing. Different synthesis conditions such as ball milling, sintering time, pressure, have been compared by SEM images and XRD tests analysis to figure out optimized process parameters. Several samples’ thermal conductivities (?) were plotted as a function of temperature to study different synthesis strategies and doping materials’ effects on phonon scattering inside bulk thermoelectric materials.

Hu, Fang

2012-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "mo magnesium oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Hydrogen Storage Properties of the Tetrahydrofuran Treated Magnesium  

DOE Green Energy (OSTI)

The electronic structure, crystalline feature and morphology of the tetrahydrofuran (THF) treated magnesium, along with its hydriding and dehydriding properties have been investigated. The THF treated magnesium absorbs 6.3 wt per cent hydrogen at 723K and 3.5 MPa. After hydrogenation, in addition to the expected MgH2, a new less-stable hydride phase appears at 673K, but not at a lower temperature. Desorption produces 5.5 wt per cent hydrogen at 723K against a back pressure of 1.3 Pa after 20 cycles of hydriding-dehydriding. The THF treatment improves the kinetics of hydrogen absorption and desorption significantly. From 723K to 623K, the THF treated Mg demonstrates acceptable reaction rates. XPS studies show that tetrahydrofuran treatment causes the electronic energy state of the magnesium surface atoms to change, but the XRD studies show the crystal structure remains unchanged. Metallographic observation of the bulk hydrides of THF treated magnesium reveal they are poly-crystalline wi th the wide-spreading slip bands and twins within the crystals, indicating the phase transformation upon hydriding causes serious stress and distortion. It appears this microstructural deformation explains the much higher energy requirements (higher pressure and temperature) for magnesium hydrogenation than the simple lattice expansion that accompany hydrogen uptake for LaNi5 and FeTi.

AU, MING

2004-05-25T23:59:59.000Z

142

BACKGROUND REVIEW OF THE BRUSH BERYLLIUM AND DIAMOND MAGNESIUM PLANTS  

Office of Legacy Management (LM)

BACKGROUND REVIEW OF THE BRUSH BERYLLIUM AND DIAMOND MAGNESIUM PLANTS BACKGROUND REVIEW OF THE BRUSH BERYLLIUM AND DIAMOND MAGNESIUM PLANTS IN LUCKEY, OHIO October 27, 1989 Prepared for: U.S. Department of Energy Formerly Utilized Sites Remedial Action Program Prepared by: R.F. Weston/Office of Technical Services BACKGROUND REVIEW OF THE BRUSH BERYLLIUM AND DIAMOND MAGNESIUM PLANTS IN LUCKEY, OHIO INTRODUCTION The Department of Energy (DOE) is conducting a program to identify and examine the radiological conditions at sites used in the early years of nuclear energy development by the U.S. Army Corps of Engineer's Manhattan Engineer District (MED) and the Atomic Energy Commission (AEC). This program, the Formerly Utilized Sites Remedial Action Program (FUSRAP), is administered by the Assistant Secretary for Nuclear Energy through the

143

Nanostructured material for advanced energy storage : magnesium battery cathode development.  

SciTech Connect

Magnesium batteries are alternatives to the use of lithium ion and nickel metal hydride secondary batteries due to magnesium's abundance, safety of operation, and lower toxicity of disposal. The divalency of the magnesium ion and its chemistry poses some difficulties for its general and industrial use. This work developed a continuous and fibrous nanoscale network of the cathode material through the use of electrospinning with the goal of enhancing performance and reactivity of the battery. The system was characterized and preliminary tests were performed on the constructed battery cells. We were successful in building and testing a series of electrochemical systems that demonstrated good cyclability maintaining 60-70% of discharge capacity after more than 50 charge-discharge cycles.

Sigmund, Wolfgang M. (University of Florida, Gainesville, FL); Woan, Karran V. (University of Florida, Gainesville, FL); Bell, Nelson Simmons

2010-11-01T23:59:59.000Z

144

Nanostructured material for advanced energy storage : magnesium battery cathode development.  

DOE Green Energy (OSTI)

Magnesium batteries are alternatives to the use of lithium ion and nickel metal hydride secondary batteries due to magnesium's abundance, safety of operation, and lower toxicity of disposal. The divalency of the magnesium ion and its chemistry poses some difficulties for its general and industrial use. This work developed a continuous and fibrous nanoscale network of the cathode material through the use of electrospinning with the goal of enhancing performance and reactivity of the battery. The system was characterized and preliminary tests were performed on the constructed battery cells. We were successful in building and testing a series of electrochemical systems that demonstrated good cyclability maintaining 60-70% of discharge capacity after more than 50 charge-discharge cycles.

Sigmund, Wolfgang M. (University of Florida, Gainesville, FL); Woan, Karran V. (University of Florida, Gainesville, FL); Bell, Nelson Simmons

2010-11-01T23:59:59.000Z

145

Analysis of the potential for new automotive uses of magnesium  

DOE Green Energy (OSTI)

This paper describes the scope of a new project, just initiated, for the Lightweight Materials Program within the Office of Transportation Materials. The Center for Transportation Research and the Energy Technology Division at Argonne National Laboratory will assess the feasibility and technical potential of using magnesium and its alloys in place of steel or aluminum for automotive structural and sheet applications in order to enable more energy-efficient, lightweight passenger vehicles. The analysis will provide an information base to help guide magnesium research and development in the most promising directions.

Stodolsky, F.; Gaines, L.; Cuenca, R.; Wu, S.

1994-12-31T23:59:59.000Z

146

Mo Type Phase in Long-Term Aged INCONEL Alloy  

Science Conference Proceedings (OSTI)

FORMATION OF A PtzMo TYPE PHASE IN LONG-TERM AGED lNCONEL@ ALLOY 686. Michael G. ... formation of a low-temperature iutermetallic Pt*Mo type .

147

MoWiTT: The Mobile Window Thermal Test Facility  

NLE Websites -- All DOE Office Websites (Extended Search)

Airflow schematic MoWiTT: The Mobile Window Thermal Test Facility In the MoWiTT facility, efficient window-and-frame systems are measured to understand the flow of energy through...

148

Accelerator Production Options for 99MO  

SciTech Connect

Shortages of {sup 99}Mo, the most commonly used diagnostic medical isotope, have caused great concern and have prompted numerous suggestions for alternate production methods. A wide variety of accelerator-based approaches have been suggested. In this paper we survey and compare the various accelerator-based approaches.

Bertsche, Kirk; /SLAC

2010-08-25T23:59:59.000Z

149

Role of SrMoO{sub 4} in Sr{sub 2}MgMoO{sub 6} synthesis  

Science Conference Proceedings (OSTI)

Here we investigate the elemental and phase compositions during the solid-state synthesis of the promising SOFC-anode material, Sr{sub 2}MgMoO{sub 6}, and demonstrate that molybdenum does not notably evaporate under the normal synthesis conditions with temperatures up to 1200 {sup o}C due to the formation of SrMoO{sub 4} as an intermediate product at low temperatures, below 600 {sup o}C. However, partial decomposition of the Sr{sub 2}MgMoO{sub 6} phase becomes evident at the higher temperatures ({approx}1500 {sup o}C). The effect of SrMoO{sub 4} on the electrical conductivity of Sr{sub 2}MgMoO{sub 6} is evaluated by preparing a series of Sr{sub 2}MgMoO{sub 6} samples with different amounts of additional SrMoO{sub 4}. Under the reducing operation conditions of an SOFC anode the insulating SrMoO{sub 4} phase is apparently reduced to the highly conductive SrMoO{sub 3} phase. Percolation takes place with 20-30 wt% of SrMoO{sub 4} in a Sr{sub 2}MgMoO{sub 6} matrix, with a notable increase in electrical conductivity after reduction. Conductivity values of 14, 60 and 160 S/cm are determined at 800 {sup o}C in 5% H{sub 2}/Ar for the Sr{sub 2}MgMoO{sub 6} samples with 30, 40 and 50 wt% of added SrMoO{sub 4}, respectively. -- Graphical abstract: SrMoO{sub 4} is formed at low temperatures during the synthesis of Sr{sub 2}MgMoO{sub 6}, which prevents the volatilization of Mo from typical precursor mixtures of this promising SOFC anode material. SrMoO{sub 4} is insulating and it is often found as an impurity in Sr{sub 2}MgMoO{sub 6} samples. It is however readily reduced to highly conducting SrMoO{sub 3}. Composites of Sr{sub 2}MgMoO{sub 6} and SrMoO{sub 3} show increased electrical conductivities compared to pure Sr{sub 2}MgMoO{sub 6} under the reductive operation conditions of an SOFC anode. Display Omitted Highlights: {yields} Sr{sub 2}MgMoO{sub 6} is a promising SOFC anode material. {yields} During the Sr{sub 2}MgMoO{sub 6} synthesis SrMoO{sub 4} is formed at low temperatures. {yields} Formation of SrMoO{sub 4} effectively prevents volatilization of Mo at high temperatures. {yields} Insulating SrMoO{sub 4} reduces to highly conductive SrMoO{sub 3} under SOFC-anode conditions. {yields} Composites of Sr{sub 2}MgMoO{sub 6} and SrMoO{sub 3} show high electrical conductivities.

Vasala, S.; Yamauchi, H. [Laboratory of Inorganic Chemistry, Department of Chemistry, School of Chemical Technology, Aalto University, P.O. Box 16100, FI-00076 Aalto (Finland); Karppinen, M., E-mail: maarit.karppinen@aalto.f [Laboratory of Inorganic Chemistry, Department of Chemistry, School of Chemical Technology, Aalto University, P.O. Box 16100, FI-00076 Aalto (Finland)

2011-05-15T23:59:59.000Z

150

Applications of Computer in Engineering Especially in Electrolysis Magnesium Industry  

Science Conference Proceedings (OSTI)

In modern times, computers have closely connection with everyone, especially scientist and engineer. Computer programs can now solve difficult problems in a fraction of the time it used to take. Computer-Aided engineering is a powerful tool and necessary ... Keywords: CFD, CAE, Electrochemistry, electrolysis, molten magnesium salt

Ze Sun; Bing Li; Jianguo Yu

2009-03-01T23:59:59.000Z

151

REGENERATION OF FISSION-PRODUCT-CONTAINING MAGNESIUM-THORIUM ALLOYS  

DOE Patents (OSTI)

A process of regenerating a magnesium-thorium alloy contaminated with fission products, protactinium, and uranium is presented. A molten mixture of KCl--LiCl-MgCl/sub 2/ is added to the molten alloy whereby the alkali, alkaline parth, and rare earth fission products (including yttrium) and some of the thorium and uranium are chlorinated and

Chiotti, P.

1964-02-01T23:59:59.000Z

152

Reduction of Oxidative Melt Loss of Aluminum and Its Alloys  

Science Conference Proceedings (OSTI)

This project led to an improved understanding of the mechanisms of dross formation. The microstructural evolution in industrial dross samples was determined. Results suggested that dross that forms in layers with structure and composition determined by the local magnesium concentration alone. This finding is supported by fundamental studies of molten metal surfaces. X-ray photoelectron spectroscopy data revealed that only magnesium segregates to the molten aluminum alloy surface and reacts to form a growing oxide layer. X-ray diffraction techniques that were using to investigate an oxidizing molten aluminum alloy surface confirmed for the first time that magnesium oxide is the initial crystalline phase that forms during metal oxidation. The analytical techniques developed in this project are now available to investigate other molten metal surfaces. Based on the improved understanding of dross initiation, formation and growth, technology was developed to minimize melt loss. The concept is based on covering the molten metal surface with a reusable physical barrier. Tests in a laboratory-scale reverberatory furnace confirmed the results of bench-scale tests. The main highlights of the work done include: A clear understanding of the kinetics of dross formation and the effect of different alloying elements on dross formation was obtained. It was determined that the dross evolves in similar ways regardless of the aluminum alloy being melted and the results showed that amorphous aluminum nitride forms first, followed by amorphous magnesium oxide and crystalline magnesium oxide in all alloys that contain magnesium. Evaluation of the molten aluminum alloy surface during melting and holding indicated that magnesium oxide is the first crystalline phase to form during oxidation of a clean aluminum alloy surface. Based on dross evaluation and melt tests it became clear that the major contributing factor to aluminum alloy dross was in the alloys with Mg content. Mg was identified as the primary factor that accelerates dross formation specifically in the transition from two phases to three phase growth. Limiting magnesium oxidation on the surface of molten aluminum therefore becomes the key to minimizing melt loss, and technology was developed to prevent magnesium oxidation on the aluminum surface. This resulted in a lot of the work being focused on the control of Mg oxidation. Two potential molten metal covering agents that could inhibit dross formation during melting and holding consisting of boric acid and boron nitride were identified. The latter was discounted by industry as it resulted in Boron pick up by the melt beyond that allowed by specifications during plant trials. The understanding of the kinetics of dross formation by the industry partners helped them understand how temperature, alloy chemistry and furnace atmosphere (burner controls--e.g. excess air) effected dross formation. This enables them to introduce in their plant process changes that reduced unnecessary holding at high temperatures, control burner configurations, reduce door openings to avoid ingress of air and optimize charge mixes to ensure rapid melting and avoid excess oxidation.

Dr. Subodh K. Das; Shridas Ningileri

2006-03-17T23:59:59.000Z

153

Missouri Department of National Resources Energy Center Mo DNR | Open  

Open Energy Info (EERE)

Department of National Resources Energy Center Mo DNR Department of National Resources Energy Center Mo DNR Jump to: navigation, search Name Missouri Department of National Resources Energy Center (Mo DNR) Place Jefferson City, Missouri Zip 65102 Product Mo DNR manages the Energy Revolving Fund which assists public organisations in Missouri in financing energy efficient projects for their facilities. References Missouri Department of National Resources Energy Center (Mo DNR)[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Missouri Department of National Resources Energy Center (Mo DNR) is a company located in Jefferson City, Missouri . References ↑ "Missouri Department of National Resources Energy Center (Mo

154

Method for generating a crystalline {sup 99}MoO{sub 3} product and the isolation {sup 99m}Tc compositions therefrom  

DOE Patents (OSTI)

An improved method is described for producing {sup 99m}Tc compositions. {sup 100}Mo metal is irradiated with photons in a particle (electron) accelerator to produce {sup 99}Mo metal which is dissolved in a solvent. A solvated {sup 99}Mo product is then dried to generate a supply of {sup 99}MoO{sub 3} crystals. The crystals are thereafter heated at a temperature which will sublimate the crystals and form a gaseous mixture containing vaporized {sup 99m}TcO{sub 3} and vaporized {sup 99m}TcO{sub 2} but will not cause the production of vaporized {sup 99}MoO{sub 3}. The mixture is then combined with an oxidizing gas to generate a gaseous stream containing vaporized {sup 99m}Tc{sub 2}O{sub 7}. Next, the gaseous stream is cooled to a temperature sufficient to convert the vaporized {sup 99m}Tc{sub 2}O{sub 7} into a condensed {sup 99m}Tc-containing product. The product has high purity levels resulting from the use of reduced temperature conditions and ultrafine crystalline {sup 99}MoO{sub 3} starting materials with segregated {sup 99m}Tc compositions therein which avoid the production of vaporized {sup 99}MoO{sub 3} contaminants. 1 fig.

Bennett, R.G.; Christian, J.D.; Kirkham, R.J.; Tranter, T.J.

1998-09-01T23:59:59.000Z

155

Air-Oxidation of a [(Co  

Science Conference Proceedings (OSTI)

Symposium, Bulk Metallic Glasses VIII. Presentation Title, Air-Oxidation of a [(Co 50Cr15C15Mo14B6)97.5Er2.5]93Fe7 Bulk Metallic Glass at 600 - 725 oC.

156

DOE - Office of Legacy Management -- United Nuclear Corp - MO 0-03  

Office of Legacy Management (LM)

United Nuclear Corp - MO 0-03 United Nuclear Corp - MO 0-03 FUSRAP Considered Sites Site: UNITED NUCLEAR CORP. (MO.0-03) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: Mallinckrodt Chemical Works Mallinckrodt Nuclear Corporation MO.0-03-1 MO.0-03-2 Location: Hematite , Missouri MO.0-03-1 Evaluation Year: Circa 1987 MO.0-03-3 Site Operations: Commercial fuel fabrication operation. Licensed to reclaim unirradiated enriched uranium from scrap generated in fuel fabrication and fuel material preparation. MO.0-03-1 MO.0-03-2 MO.0-03-3 MO.0-03-4 Site Disposition: Eliminated - NRC licensed - Commercial operations MO.0-03-3 MO.0-03-5 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled: Uranium MO.0-03-3 Radiological Survey(s): None Indicated

157

Geochemistry of Magnesium Silicate Carbonation in an Aqueous Medium  

NLE Websites -- All DOE Office Websites (Extended Search)

Geochemistry of Magnesium Silicate Geochemistry of Magnesium Silicate Carbonation in an Aqueous Medium (Carbon Mineralization) Jon Benner, Deb Bergfeld, Dave Bish, Darrin Byler, Bill Carey, Steve Chipera, George Guthrie, Klaus Lackner, Hans Ziock Hydrology, Geochemistry, Geology Group Los Alamos National Laboratory LA-UR-01-4206 Approved for public release; distribution is unlimited George Guthrie gguthrie@lanl.gov 505-665-6340 Mineral Carbonation: Conversion of CO 2 into Carbonates * alkali carbonates too soluble * alkaline earth carbonates ideal sources: Ca-silicates (feldspar) Mg-silicates (olivine, serpentine, clays) Mg 2+ + CO 3 2- => MgCO 3 Mg 2 SiO 4 + 4H + => 2Mg 2+ + SiO 2(aq) Ultramafic rocks are an abundant Mg source (~0.2 km) 3 serpentine / GW-yr Challenges for Mineral-Carbonation

158

Hydrogen Storage Properties of Magnesium Base Nanostructured Composite Materials  

DOE Green Energy (OSTI)

In this work, nanostructured composite materials have been synthesized using the mechanical alloying process. The new materials produced have been investigated by X-ray diffraction (XRD), transition electron microscope (TEM), scanning electron microscope (SEM) and electron energy dispersion spectrum (EDS) for their phase compositions, crystal structure, grain size, particle morphology and the distribution of catalyst element. Hydrogen storage capacities and the hydriding-dehydriding kinetics of the new materials have been measured at different temperatures using a Sieverts apparatus. It is observed that mechanical alloying accelerates the hydrogenation kinetics of the magnesium based materials at low temperature, but a high temperature must be provided to release the absorbed hydrogen from the hydrided magnesium based materials. It is believed that the dehydriding temperature is largely controlled by the thermodynamic configuration of magnesium hydride. Doping Mg-Ni nano/amorphous composite materials with lanthanum reduces the hydriding and dehydriding temperature. Although the stability of MgH2 can not be easily reduced by ball milling alone, the results suggest the thermodynamic properties of Mg-Ni nano/amorphous composite materials can be alternated by additives such as La or other effective elements. Further investigation toward understanding the mechanism of additives will be rewarded.

AU, M

2004-04-30T23:59:59.000Z

159

Potential applications of wrought magnesium alloys for passenger vehicles  

DOE Green Energy (OSTI)

Vehicle weight reduction is one of the major means available for improving automotive fuel efficiency. Although high-strength steels, aluminum (Al), and polymers are already being used to achieve significant weight reductions, substantial additional weight reductions could be achieved by increased use of magnesium (Mg) and its alloys, which have very low density. Magnesium alloys are currently used in relatively small quantities for auto parts; use is generally limited to die castings, such as housings. The Center for Transportation Research at Argonne National Laboratory has performed a study for the Lightweight Materials Program within DOE`s Office of Transportation Materials to evaluate the suitability of wrought Mg and its alloys to replace steel or aluminum for automotive structural and sheet applications. This study identifies technical and economic barriers to this replacement and suggests R&D areas to enable economical large-volume use. Detailed results of the study will be published at a later date. Magnesium sheet could be used in body nonstructural and semi-structural applications, while extrusions could be used in such structural applications as spaceframes. Currently, Mg sheet has found limited use in the aerospace industry, where costs are not a major concern. The major barrier to greatly increased automotive use is high cost; two technical R&D areas are identified that could enable major reductions in costs. These are novel reduction technology and better hot-forming technology, possibly operating at lower temperatures and involving superplastic behavior.

Gaines, L.; Cuenca, R.; Stodolsky, F.; Wu, S.

1995-12-31T23:59:59.000Z

160

MoNDian Dark Matter, Entropic Gravity, and Infinite Statistics  

E-Print Network (OSTI)

We propose the concept of MoNDian dark matter which behaves like cold dark matter at cluster and cosmic scales but emulates modified Newtonian dynamics at the galactic scale. The connection between global physics and local galactic dynamics is implemented via entropic gravity. We also give an alternative formulation of MoNDian dark matter by using an effective gravitational Born-Infeld theory. In the latter approach, we show that the quanta of MoNDian dark matter obey infinite statistics.

Y. Jack Ng

2012-12-27T23:59:59.000Z

Note: This page contains sample records for the topic "mo magnesium oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Microstructure Characterization and Processing of U-Mo Alloy Fuels ...  

Science Conference Proceedings (OSTI)

molybdenum (Mo) fuels have been identified as a potential replacement for highly enriched uranium (HEU) dispersion fuels in high performance research ...

162

Interdiffusion between Zr Diffusion Barrier and U-Mo Alloy  

Science Conference Proceedings (OSTI)

U-Mo alloys are being developed as low enrichment uranium fuels under the Reduced Enrichment for Research and Test Reactor (RERTR) program. Significant reactions have been observed between U-Mo fuels and Al or Al alloy matrix. Refractory metal Zr has been proposed as barrier material to reduce the interactions. In order to investigate the compatibility and barrier effects between U-Mo alloy and Zr, solid-to-solid U-10wt.%Mo vs. Zr diffusion couples were assembled and annealed at 600, 700, 800, 900 and 1000 °C for various times. The microstructures and concentration profiles due to interdiffusion and reactions were examined via scanning electron microscopy and electron probe microanalysis, respectively. Intermetallic phase Mo2Zr was found at the interface and its population increased when annealing temperature decreased. Diffusion paths were also plotted on the U-Mo-Zr ternary phase diagrams with good consistency. The growth rate of interdiffusion zone between U-10wt.%Mo and Zr was also calculated under the assumption of parabolic diffusion, and was determined to be about 103 times lower than the growth rate of diffusional interaction layer found in diffusion couples U-10wt.%Mo vs. Al or Al-Si alloy. Other desirable physical properties of Zr as barrier material, such as neutron adsorption rate, melting point and thermal conductivity are presented as supplementary information to demonstrate the great potential of Zr as the diffusion barrier for U-Mo fuel systems in RERTR.

K. Huang; Y. Park; Y. H. Sohn

2012-12-01T23:59:59.000Z

163

Balancing the Properties of Structural Mo-Borosilicide Alloys for ...  

Science Conference Proceedings (OSTI)

Symposium, Advanced Protective Coatings for Refractory Metals and Alloys. Presentation Title, Balancing the Properties of Structural Mo-Borosilicide Alloys for ...

164

MAGNESIUM MONO POTASSIUM PHOSPHATE GROUT FOR P-REACTOR VESSEL IN-SITU DECOMISSIONING  

Science Conference Proceedings (OSTI)

The objective of this report is to document laboratory testing of magnesium mono potassium phosphate grouts for P-Reactor vessel in-situ decommissioning. Magnesium mono potassium phosphate cement-based grout was identified as candidate material for filling (physically stabilizing) the 105-P Reactor vessel (RV) because it is less alkaline than portland cement-based grout (pH of about 12.4). A less alkaline material ({ash), and (4) Ceramicrete{reg_sign} magnesium mono potassium phosphate-based grouts prepared at Argonne National Laboratory. Boric acid was evaluated as a set retarder in the magnesium mono potassium phosphate mixes.

Langton, C.; Stefanko, D.

2011-01-05T23:59:59.000Z

165

The influence of zeta potential and yield stress on the filtration characteristics of a magnesium hydroxide simulant  

Science Conference Proceedings (OSTI)

In the UK, irradiated fuels from Magnox reactors are often stored in water-filled ponds under alkaline conditions, so as to minimise corrosion of fuel cladding. This is important to prevent or reduce leakage of soluble fission products and actinides to the pond water. A variety of intermediate level wastes derived from Magnox materials are stored at power stations. Under these alkaline conditions, various species of magnesium are formed, of which magnesium hydroxide is the dominant material. The particle-fluid interactions are significant for the design and operation of facilities for hydraulic retrieval, filtration, dewatering and ion exchange treatment of fuel storage pond water and stored wet Magnox wastes. Here we describe a study of particulate properties and filtration characteristics of oxide particle simulants under laboratory conditions. Cake and medium resistance data were correlated across a range of pH conditions with electro-acoustic zeta potential and shear yield stress measurements, as a function of particle volume fractions. The influence of zeta potential on filtration properties arises directly from the interaction of particles within the sediment cake. (authors)

Biggs, Simon; Nabi, Rafiq; Poole, Colin [Leeds University/Nexia Solutions URA in Particle Science and Technology, Institute of Particle Science and Engineering, School of Process, Environmental and Materials Engineering, The University of Leeds, Leeds LS2 9JT (United Kingdom); Patel, Ashok [British Nuclear Group, Reactor Sites, Berkeley Centre, Berkeley, Gloucestershire, GL13 9PB (United Kingdom)

2007-07-01T23:59:59.000Z

166

Continuing investigations for technology assessment of /sup 99/Mo production from LEU (low enriched Uranium) targets  

SciTech Connect

Currently much of the world's supply of /sup 99m/Tc for medical purposes is produced from /sup 99/Mo derived from the fissioning of high enriched uranium (HEU). The need for /sup 99m/Tc is continuing to grow, especially in developing countries, where needs and national priorities call for internal production of /sup 99/Mo. This paper presents the results of our continuing studies on the effects of substituting low enriched Uranium (LEU) for HEU in targets for the production of fission product /sup 99/Mo. Improvements in the electrodeposition of thin films of uranium metal are reported. These improvements continue to increase the appeal for the substitution of LEU metal for HEU oxide films in cylindrical targets. The process is effective for targets fabricated from stainless steel or hastaloy. A cost estimate for setting up the necessary equipment to electrodeposit uranium metal on cylindrical targets is reported. Further investigations on the effect of LEU substitution on processing of these targets are also reported. Substitution of uranium silicides for the uranium-aluminum alloy or uranium aluminide dispersed fuel used in other current target designs will allow the substitution of LEU for HEU in these targets with equivalent /sup 99/Mo-yield per target and no change in target geometries. However, this substitution will require modifications in current processing steps due to (1) the insolubility of uranium silicides in alkaline solutions and (2) the presence of significant quantities of silicate in solution. Results to date suggest that both concerns can be handled and that substitution of LEU for HEU can be achieved.

Vandergrift, G.F.; Kwok, J.D.; Marshall, S.L.; Vissers, D.R.; Matos, J.E.

1987-01-01T23:59:59.000Z

167

Scanning Transmission Electron Microscopy Investigations of Complex Oxides  

NLE Websites -- All DOE Office Websites (Extended Search)

Scanning Transmission Electron Microscopy Investigations of Complex Oxides Scanning Transmission Electron Microscopy Investigations of Complex Oxides Monday, May 23, 2011 - 3:30pm SSRL Conference room 137-322 Professor Tom Vogt, NanoCenter & Department of Chemistry, University of South Carolina High-Angle-Annular-Dark-Field/Scanning Transmission Electron Microscopy (HAADF/STEM) is a technique uniquely suited for detailed studies of the structure and composition of complex oxides. The HAADF detector collects electrons which have interact inelastically with the potentials of the atoms in the specimen and therefore resembles the better known Z2 (Z is atomic number) Rutherford scattering. One class of important catalysts consists of bronzes based on pentagonal {Mo6O21} building units; these include Mo5O14 and Mo17O47. In the last 20 years, new materials doped with

168

DOE - Office of Legacy Management -- Rogers Iron Works Co - MO 10  

Office of Legacy Management (LM)

Rogers Iron Works Co - MO 10 Rogers Iron Works Co - MO 10 FUSRAP Considered Sites Site: ROGERS IRON WORKS CO. (MO.10 ) Elimination from consideration under FUSRAP Designated Name: Not Designated Alternate Name: Rogers Iron Co. MO.10-1 Location: Joplin , Missouri MO.10-1 Evaluation Year: 1990 MO.10-2 MO.10-3 Site Operations: Tested C-liner crushing methods. MO.10-1 Site Disposition: Eliminated - Potential for contamination considered remote based on limited quantities of material handled MO.10-3 MO.10-4 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled: Uranium (Trace Amounts) MO.10-2 Radiological Survey(s): None Indicated Site Status: Elimination from consideration under FUSRAP Also see Documents Related to ROGERS IRON WORKS CO. MO.10-1 - National Lead Company of Ohio Analytical Data Sheet 9908;

169

Co-Mo Electric Cooperative - Residential Energy Efficiency Rebate Program |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Co-Mo Electric Cooperative - Residential Energy Efficiency Rebate Co-Mo Electric Cooperative - Residential Energy Efficiency Rebate Program Co-Mo Electric Cooperative - Residential Energy Efficiency Rebate Program < Back Eligibility Commercial Residential Savings Category Heating & Cooling Commercial Heating & Cooling Heat Pumps Appliances & Electronics Water Heating Cooling Maximum Rebate Geothermal Heat Pumps: 10 ton maximum for Residential, 50 ton maximum for Commercial Program Info State Missouri Program Type Utility Rebate Program Rebate Amount Room AC: $50 Water Heater: $50 Air Source Heat Pumps: $150 per ton Dual Fuel Air Source Heat Pumps: $300 per ton Geothermal Heat Pumps (Closed Loop): up to $850 per ton Geothermal Heat Pumps (Open Loop or Replacement): $150 per ton Provider Co-Mo Electric Cooperative Co-Mo Electric Cooperative provides rebates to residential and commercial

170

Mo Year Report Period: EIA ID NUMBER:  

U.S. Energy Information Administration (EIA) Indexed Site

Version No: 2013.01 Mo Year Report Period: EIA ID NUMBER: http://www.eia.gov/survey/form/eia_14/instructions.pdf Mailing Address: Secure File Transfer option available at: (e.g., PO Box, RR) https://signon.eia.doe.gov/upload/noticeoog.jsp Electronic Transmission: The PC Electronic Zip Code - Data Reporting Option (PEDRO) is available. If interested in software, call (202) 586-9659. Email form to: OOG.SURVEYS@eia.doe.gov - - - - Fax form to: (202) 586-9772 Mail form to: Oil & Gas Survey Email address: U.S. Department of Energy Ben Franklin Station PO Box 279 Washington, DC 20044-0279 Questions? Call toll free: 1-800-638-8812 PADD 4 Type of Report (Check One ): (Thousands of dollars) (Thousands of barrels) PADD 2 PADD 3 PAD DISTRICT (a) Revision to Report:

171

MattssonMoVacPrague2009.ppt  

National Nuclear Security Administration (NNSA)

Thomas R Mattsson Thomas R Mattsson Sandia National Laboratories Albuquerque, NM, USA Nils Sandberg -- KTH, Stockholm Richard Armiento -- Univ. Bayreuth, Germany Ann Mattsson -- Sandia National Laboratories Self-diffusion in Mo using the AM05 density functional Sandia is a multiprogram laboratory operated by Sandia Corporation, a Lockheed Martin Company, for the United States Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000. Joint U.S. Russia Conference on Advances in Materials Science Prague, Czech Republic Aug 31-Sept 3, 2009 SAND 2009-2197 C, 2009-3883 C, 2009-4713 C, and 2002-1323 P Vacancy mediated diffusion is the main mechanism for mass transport in solids *Vacancies are important for *Self-diffusion *Defect migration *Radiation damage/ swelling

172

Toluene 4-Monooxygenase and its Complex with Effector Protein T4moD  

Science Conference Proceedings (OSTI)

Toluene 4-monooxygenase (T4MO) is a multiprotein diiron enzyme complex that catalyzes the regiospecific oxidation of toluene to p-cresol. Catalytic function requires the presence of a small protein, called the effector protein. Effector protein exerts substantial control on the diiron hydroxylase catalytic cycle through protein-protein interactions. High-resolution crystal structures of the stoichometric hydroxylase and effector protein complex described here reveal how protein-protein interactions and reduction of the diiron center produce an active site configuration poised for reaction with O{sub 2}. Further information from crystal structures of mutated isoforms of the hydroxylase and a peroxo adduct is combined with catalytic results to give a fuller picture of the geometry of the enzyme-substrate complex used for the high fidelity oxidation of hydrocarbon substrates.

Bailey, Lucas J.; Fox, Brian G. (UW)

2012-10-16T23:59:59.000Z

173

Chemical and mechanical consequences of environmental barrier coating exposure to calcium-magnesium-aluminosilicate.  

Science Conference Proceedings (OSTI)

The success of Si-based ceramics as high-temperature structural materials for gas turbine applications relies on the use of environmental barrier coatings (EBCs) with low silica activity, such as Ba{sub 1-x}Sr{sub x}Al{sub 2}Si{sub 2}O{sub 8} (BSAS), which protect the underlying components from oxidation and corrosion in combustion environments containing water vapor. One of the current challenges concerning EBC lifetime is the effect of sandy deposits of calcium-magnesium-aluminosilicate (CMAS) glass that melt during engine operation and react with the EBC, changing both its composition and stress state. In this work, we study the effect of CMAS exposure at 1300 C on the residual stress state and composition in BSAS-mullite-Si-SiC multilayers. Residual stresses were measured in BSAS multilayers exposed to CMAS for different times using high-energy X-ray diffraction. Their microstructure was studied using a combination of scanning electron microscopy and transmission electron microscopy techniques. Our results show that CMAS dissolves the BSAS topcoat preferentially through the grain boundaries, dislodging the grains and changing the residual stress state in the topcoat to a nonuniform and increasingly compressive stress state with increasing exposure time. The presence of CMAS accelerates the hexacelsian-to-celsian phase transformation kinetics in BSAS, which reacts with the glass by a solution-reprecipitation mechanism. Precipitates have crystallographic structures consistent with Ca-doped celsian and Ba-doped anorthite.

Harder, B.; Ramirez-Rico, J.; Almer, J. D.; Kang, L.; Faber, K. (X-Ray Science Division); (NASA Glenn Research Center); (Univ. of Seville); (Rolls-Royce Corp.); (Northwestern Univ.)

2011-06-01T23:59:59.000Z

174

Potassium, calcium, and magnesium in the tropics and subtropics  

SciTech Connect

The potential for increased food production in the world is undoubtedly greater than even the most optimistic surveys predict. Proper use of adequate amounts of potassium, calcium, and magnesium in fertilizers, soil amendments, crop residues and other byproducts, and minerals will be necessary if crop production potentials are to be realized. Use of these three plant nutrients with others will be an increasingly important part of the exploitation of natural resources as new lands of the tropics and subtropics are brought into production. Most of the increase in food production will come from more intensive use of lands already in production, however, and the soils of these lands will need larger amounts of all plant nutrients if high yields are to be reached and maintained. This report is intended to point out some of the complexities of the soil and fertilizer problems involving potassium, calcium, and magnesium. It is hoped that the information it contains will be helpful in the research, education, and development that will be required to point the way to increased food and crop production on soils of the tropics and subtropics throughout the world.

Munson, R.D.

1982-01-01T23:59:59.000Z

175

Low-temperature electron irradiation and annealing in pure magnesium  

Science Conference Proceedings (OSTI)

In this study of magnesium after 1.0 MeV electron irradiations at 1.55/sup 0/K, it has been observed that the damage production rate in Mg is (3.57 +- 0.03) x 10/sup -26/ ..cap omega..cm/(e/sup -/ cm/sup 2/). There is no evidence for thermal annealing up to 4/sup 0/K. The low temperature recovery in magnesium is found to consist of two broad substages between 4 to 14/sup 0/K, both of which exhibit evidence for correlated and uncorrelated recovery processes. The two substages are found to have very different frequency factors for annealing, and there is evidence that the recovery processes in the second substage are influenced by those in the first. A model for recovery is proposed using the split configuration in the plane which explains the first substage as being due to interstitial migration in the basal plane and the second to migration perpendicular to the plane.

Simester, J.H.

1982-01-01T23:59:59.000Z

176

DOE - Office of Legacy Management -- Tyson Valley Powder Farm - MO 11  

Office of Legacy Management (LM)

Tyson Valley Powder Farm - MO 11 Tyson Valley Powder Farm - MO 11 FUSRAP Considered Sites Site: TYSON VALLEY POWDER FARM (MO.11) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: St. Louis County , Missouri MO.11-1 Evaluation Year: 1987 MO.11-2 Site Operations: Storage of C-Special material (residue from production of uranium metal). MO.11-1 MO.11-2 MO.11-3 Site Disposition: Eliminated - Referred to Army Corps of Engineers MO.11-2 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled: Uranium MO.11-3 Radiological Survey(s): None Indicated Site Status: Eliminated from further consideration under FUSRAP Also see Documents Related to TYSON VALLEY POWDER FARM MO.11-1 - Letter; Dickenson to Duff; Subject: Granted continued use

177

DOE - Office of Legacy Management -- Spencer Chemical Co - MO 0-01  

Office of Legacy Management (LM)

MO 0-01 MO 0-01 FUSRAP Considered Sites Site: SPENCER CHEMICAL CO. (MO.0-01) Eliminated from further consideration under FUSRAP - an AEC licensed operation Designated Name: Not Designated Alternate Name: Jayhawk Works MO.0-01-1 Location: Joplin , Missouri MO.0-01-1 Evaluation Year: 1985 MO.0-01-2 Site Operations: Processed enriched uranium (UF-6) and scrap to produce primarily uranium dioxide (UO-2) under AEC licenses. MO.0-01-3 MO.0-01-4 Site Disposition: Eliminated - No Authority MO.0-01-2 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled: Normal and Enriched Uranium, Thorium MO.0-01-6 Radiological Survey(s): Yes MO.0-01-5 Site Status: Eliminated from further consideration under FUSRAP - an AEC licensed operation Also see Documents Related to SPENCER CHEMICAL CO.

178

(Mo,Cr) in HASTELLOY C-22HS Alloy, a  

Science Conference Proceedings (OSTI)

debate (with question marks in the phase diagrams) such as ?CrMo4Ni5, ? ... diagram at 500, 620 and 700șC show the existence of P phase and. OP6 phase[5

179

Future design mindful of the MoRAS  

Science Conference Proceedings (OSTI)

As human-computer interaction (HCI) expands its scope, the proper context for the design of information technology (IT) is increasingly an interconnected mosaic of responsive adaptive systems (MoRAS) including people's heads, organizations, communities, ...

George W. Furnas

2000-09-01T23:59:59.000Z

180

Developments in realistic design for aperiodic Mo/Si multilayermirrors  

Science Conference Proceedings (OSTI)

Aperiodic multilayers have been designed for various applications, using numeric algorithms and analytical solutions, for many years with varying levels of success. This work developed a more realistic model for simulating aperiodic Mo/Si multilayers to be used in these algorithms by including the formation of MoSi{sub 2}. Using a genetic computer code we were able to optimize a 45{sup o} multilayer for a large bandpass reflection multilayer that gave good agreement with the model.

Aquila, A.L.; Salmassi, F.; Dollar, F.; Liu, Y.; Gullikson, E.M.

2006-04-05T23:59:59.000Z

Note: This page contains sample records for the topic "mo magnesium oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Climate VISION: Private Sector Initiatives: Magnesium: Resources and Links  

Office of Scientific and Technical Information (OSTI)

Software Tools Software Tools The magnesium industry intends to eliminate emissions of SF6 by evaluating and adopting environmentally friendly alternative protective cover gases. The industry may also seek to improve its energy efficiency and therefore reduce its CO2 emissions. DOE has developed the following software tools that may assist companies in such efforts. DOE BestPractices Software Tools DOE BestPractices offers a range of software tools and databases that help manufacturers assess their plant's steam, compressed air, motor, and process heating systems. DOE Plant Energy Profiler Industry experience has shown that many plant utility personnel do not have an adequate understanding of their energy cost structure and where the major focus should be for any energy savings program. This tool will

182

The extended family of hexagonal molybdenum oxide  

SciTech Connect

Over the last 40 years, a large number of isostructural compounds in the system MoO{sub 3}-NH{sub 3}-H{sub 2}O have been published. The reported molecular formulae of 'hexagonal molybdenum oxide' (HEMO) varied from MoO{sub 3}, MoO{sub 3} {center_dot} 0.33NH{sub 3}, MoO{sub 3} {center_dot} nH{sub 2}O (0.09 {le} n {le} 0.69) to MoO{sub 3} {center_dot} mNH{sub 3} {center_dot} nH{sub 2}O (0.09 {le} m {le} 0.20; 0.18 {le} n {le} 0.60). Samples, prepared by the acidification route, were investigated using thermal analysis coupled on-line to a mass spectrometer for evolved gas analysis; X-ray powder diffraction; Fourier Transform Infrared, Raman and Magic-Angle-Spinning {sup 1}H-NMR spectroscopy; Incoherent Inelastic Neutron Scattering. The X-ray study of a selected monocrystal confirmed the presence of the well-known framework of edge-sharing MoO{sub 6} octahedra: Space group P6{sub 3}/m, a = 10.527(1), c =3.7245(7) {angstrom}, {gamma} = 120{sup o}. The structure of the synthesized samples can best be described by the structural formula (NH{sub 4})[Mo{sub x}{open_square}{sub 1/2+p/2}(O{sub 3x + 1/2-p/2})(OH){sub p}] {center_dot} yH{sub 2}O (x 5.9-7.1; p {approx} 0.1; y = 1.2-2.6), which is consistent with the existence of one vacancy for 12-15 molybdenum sites. The 'chimie douce' reaction of MoO{sub 3} {center_dot} 0.155NH{sub 3} {center_dot} 0.440H{sub 2}O with a 1:1 mixture of NO/NO{sub 2} at 100 C resulted in the synthesis of MoO{sub 3} {center_dot} 0.539H{sub 2}O. Tailored nano-sized molybdenum powders can be produced using HEMO as precursor.

Hartl, Monika [Los Alamos National Laboratory; Daemen, Luke [Los Alamos National Laboratory; Lunk, J H [NON LANL; Hartl, H [NON LANL; Frisk, A T [NON LANL; Shendervich, I [NON LANL; Mauder, D [NON LANL; Feist, M [NON LANL; Eckelt, R [NON LANL

2009-01-01T23:59:59.000Z

183

Potential-dependence of the aqueous oxidation of alloy 22 in simulated concentrated well water  

DOE Green Energy (OSTI)

Using x-ray photoemission spectroscopy (XPS), we have identified elemental oxidation state shifts in the passive films of coupons of Alloy 22 polarized anodically at various potentials below the passive-transpassive transition in 90C in a concentrated version of J-13 water. The data suggest a general trend toward higher oxidation states and a narrowing in the distribution of oxidation states of Ni, Cr, and Mo with increasing potential. The relative proportion of Mo in the passive film increases at the highest potentials tested.

Bedrossian, P J

2000-11-01T23:59:59.000Z

184

X-RAY ABSORPTION SPECTROSCOPY OF TRANSITION METAL-MAGNESIUM HYDRIDE FILMS  

NLE Websites -- All DOE Office Websites (Extended Search)

Spectroscopy of Transition Metal-Magnesium Spectroscopy of Transition Metal-Magnesium Hydride Thin Films T. J. Richardson a, *, B. Farangis a , J. L. Slack a , P. Nachimuthu b , R. Pereira b , N. Tamura b , and M. Rubin a a Environmental Energy Technologies Division, b Advanced Light Source, Ernest Orlando Lawrence Berkeley National Laboratory Berkeley, California 94720, USA *Corresponding author, E-mail address: tjrichardson@lbl.gov Abstract Mixed metal thin films containing magnesium and a first-row transition element exhibit very large changes in both reflectance and transmittance on exposure to hydrogen gas. Changes in electronic structure and coordination of the magnesium and transition metal atoms during hydrogen absorption were studied using dynamic in situ transmission mode X-ray absorption

185

An experimental study of magnesium-isotope fractionation in chlorophyll-a photosynthesis  

E-Print Network (OSTI)

Geology, University of California, Davis, CA 95616. whcasey@ucdavis.edu keywords: photosynthesis, magnesium isotopes,Isotope Fractionation in Chlorophyll-a Photosynthesis Jay R. Black Department of Chemistry Department of Geology,

Black, J R; Yin, Q Z; Casey, W H

2006-01-01T23:59:59.000Z

186

The comparison of sulfide CoMo/?-Al2O3 and NiMo/?-Al2O3 catalysts in methyl palmitate and methyl heptanoate hydrodeoxygenation  

Science Conference Proceedings (OSTI)

The hydrodeoxygenation of methyl palmitate and methyl heptanoate as the model compounds of bio-oil in the presence of sulfided CoMo/?-Al2O3 and NiMo/?-Al2O3 catalysts was studied at the temperature ... Keywords: CoMoS/?-Al2O3, NiMoS/?-Al2O3, biofuels, hydrodeoxygenation, methyl heptanoate, methyl palmitate

Irina V. Deliy; Evgenia N. Vlasova; Alexey L. Nuzhdin; Galina A. Bukhtiyarova

2011-12-01T23:59:59.000Z

187

Electrolytic photodissociation of chemical compounds by iron oxide photochemical diodes  

DOE Patents (OSTI)

Chemical compounds can be dissociated by contacting the same with a p/n type semi-conductor photochemical diode having visible light as its sole source of energy. The photochemical diode consists of low cost, readily available materials, specifically polycrystalline iron oxide doped with silicon in the case of the n-type semi-conductor electrode, and polycrystalline iron oxide doped with magnesium in the case of the p-type electrode. So long as the light source has an energy greater than 2.2 electron volts, no added energy source is needed to achieve dissociation.

Somorjai, Gabor A. (Berkeley, CA); Leygraf, Christofer H. (Berkeley, CA)

1985-01-01T23:59:59.000Z

188

Electrolytic photodissociation of chemical compounds by iron oxide electrodes  

DOE Patents (OSTI)

Chemical compounds can be dissociated by contacting the same with a p/n type semi-conductor diode having visible light as its sole source of energy. The diode consists of low cost, readily available materials, specifically polycrystalline iron oxide doped with silicon in the case of the n-type semi-conductor electrode, and polycrystalline iron oxide doped with magnesium in the case of the p-type electrode. So long as the light source has an energy greater than 2.2 electron volts, no added energy source is needed to achieve dissociation.

Somorjai, Gabor A. (Berkeley, CA); Leygraf, Christofer H. (Berkeley, CA)

1984-01-01T23:59:59.000Z

189

Planned Emplacement of Magnesium Oxide in the WIPP Repository 1.0 Overview  

E-Print Network (OSTI)

ISOLATION PILOT PLANT (WIPP) CATEGORY II-H: PUBLIC COMMENTS RECEIVED IN RESPONSE TO THE ANPR DATED 12/17/96 Walter Gerstle - Comments on WIPP Performance Assessment 12/3/96 II-H-02 12/17/96 Don/07/97 Name Illegible, Public Comments on WIPP 1/23/97 II-H-15 03/07/97 Lee Lysne, Margaret Carde - Comments

190

Structure of an n-butane monolayer adsorbed on magnesium oxide (100)  

Science Conference Proceedings (OSTI)

Neutron diffraction has been used to characterize the structure of the solid phase of the completed monolayer of n butane on the MgO(100) surface at low temperature. The monolayer is found to adopt a commensurate (7{radical}(2)x{radical}(2)R45 deg. ) structure with lattice constants a=29.47 A ring and b=4.21 A ring , P{sub 2gg} symmetry and four molecules in the unit cell. Excellent agreement with the experimental diffraction pattern is realized, using a Lorenztian profile to describe the line shape.

Arnold, T. [Oak Ridge National Laboratory, P.O. Box 2008, Oak Ridge, Tennessee 37831 (United States); Chanaa, S.; Cook, R. E. [Department of Chemistry, Buehler Hall, University of Tennessee, Knoxville, Tennessee 37996 (United States); Clarke, S. M. [BP Institute and Department of Chemistry, University of Cambridge, Cambridge (United Kingdom); Larese, J. Z. [Oak Ridge National Laboratory, P.O. Box 2008, Oak Ridge, Tennessee 37831 (United States); Department of Chemistry, Buehler Hall, University of Tennessee, Knoxville, Tennessee 37996 (United States)

2006-08-15T23:59:59.000Z

191

Selective Laser Sintering of Magnesium Powder for Fabrication of ...  

Science Conference Proceedings (OSTI)

Cyclic Oxidation Behavior of Detonation Gun Sprayed Ni-20Cr Coating on a Boiler Steel at 900°C · Distortion Assessment of a Direct Cast Uranium - 6 wt.

192

Synthesis of transition metal nitride by nitridation of metastable oxide precursor  

SciTech Connect

Metastable transition metal oxides were used as precursors to synthesize transition metal nitrides at low temperature. Amorphous MoO{sub 2} was prepared by reduction of (NH{sub 4}){sub 6}Mo{sub 7}O{sub 24} solution with hydrazine. As-synthesized amorphous MoO{sub 2} was transformed into fcc {gamma}-Mo{sub 2}N at 400 Degree-Sign C and then into hexagonal {delta}-MoN by further increasing the temperature to 600 Degree-Sign C under a NH{sub 3} flow. The nitridation temperature employed here is much lower than that employed in nitridation of crystalline materials, and the amorphous materials underwent a unique nitridation process. Besides this, the bimetallic nitride Ni{sub 2}Mo{sub 3}N was also synthesized by nitridating amorphous bimetallic precursor. These results suggested that the nitridation of amorphous precursor possessed potential to be a general method for synthesizing many interstitial metallic compounds, such as nitrides and carbides at low temperature. - graphical abstract: Amorphous oxide was used as new precursor to prepare nitride at low temperature. Pure {gamma}-Mo{sub 2}N and {delta}-MoN were obtained at 400 Degree-Sign C and at 600 Degree-Sign C, respectively. Highlights: Black-Right-Pointing-Pointer We bring out a new method to synthesize transition metal nitrides at low temperature. Black-Right-Pointing-Pointer Both mono- and bimetallic molybdenum nitrides were synthesized at a mild condition. Black-Right-Pointing-Pointer The formation of two different molybdenum nitrides {gamma}-Mo{sub 2}N and {delta}-MoN can be controlled from the same metastable precursor. Black-Right-Pointing-Pointer The nitridation temperature was much lower than that reported from crystalline precursors. Black-Right-Pointing-Pointer The metastable precursor had different reaction process in comparison with crystalline precursor.

Wang, Huamin; Wu, Zijie; Kong, Jing [Key Laboratory of Advanced Energy Materials Chemistry (MOE), College of Chemistry, Nankai University, Tianjin 300071 (China)] [Key Laboratory of Advanced Energy Materials Chemistry (MOE), College of Chemistry, Nankai University, Tianjin 300071 (China); Wang, Zhiqiang, E-mail: zqwang@mail.nankai.edu.cn [Key Laboratory of Advanced Energy Materials Chemistry (MOE), College of Chemistry, Nankai University, Tianjin 300071 (China) [Key Laboratory of Advanced Energy Materials Chemistry (MOE), College of Chemistry, Nankai University, Tianjin 300071 (China); Tianjin Key Laboratory of Water Environment and Resources, Tianjin Normal University, No. 393 Binshui Road, Xiqing Dist., Tianjin 300387 (China); Zhang, Minghui, E-mail: zhangmh@nankai.edu.cn [Key Laboratory of Advanced Energy Materials Chemistry (MOE), College of Chemistry, Nankai University, Tianjin 300071 (China)] [Key Laboratory of Advanced Energy Materials Chemistry (MOE), College of Chemistry, Nankai University, Tianjin 300071 (China)

2012-10-15T23:59:59.000Z

193

Novel Nonflammable Electrolytes for Secondary Magnesium Batteries and High Voltage Electrolytes for Electrochemcial Supercapacitors  

Science Conference Proceedings (OSTI)

Magnesium has been used successfully in primary batteries, but its use in rechargeable cells has been stymied by the lack of suitable non-aqueous electrolyte that can conduct Mg+2 species, combined with poor stripping and plating properties. The development of a suitable cathode material for rechargeable magnesium batteries has also been a roadblock, but a nonflammable electrolyte is key. Likewise, the development of safe high voltage electrochemical supercapaitors has been stymied by the use of flammable solvents in the liquid electrolyte; to wit, acetonitrile. The purpose of the research conducted in this effort was to identify useful compositions of magnesium salts and polyphosphate solvents that would enable magnesium ions to be cycled within a secondary battery design. The polyphosphate solvents would provide the solvent for the magnesium salts while preventing the electrolyte from being flammable. This would enable these novel electrolytes to be considered as an alternative to THF-based electrolytes. In addition, we explored several of these solvents together with lithium slats for use as high voltage electrolytes for carbon-based electrochemical supercapacitors. The research was successful in that: 1) Magnesium imide dissolved in a phosphate ester solvent that contains a halogented phosphate ester appears to be the preferred electrolyte for a rechargeable Mg cell. 2) A combination of B-doped CNTs and vanadium phosphate appear to be the cathode of choice for a rechargeable Mg cell by virtue of higher voltage and better reversibility. 3) Magnesium alloys appear to perform better than pure magnesium when used in combination with the novel polyphosphate electrolytes. Also, this effort has established that Phoenix Innovationâ??s family of phosphonate/phosphate electrolytes together with specific lithium slats can be used in supercapacitor systems at voltages of greater than 10V.

Dr. Brian Dixon

2008-12-30T23:59:59.000Z

194

X-Ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin  

NLE Websites -- All DOE Office Websites (Extended Search)

X-Ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin X-Ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin Films Title X-Ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin Films Publication Type Journal Article LBNL Report Number LBNL-50574 Year of Publication 2002 Authors Richardson, Thomas J., Baker Farangis, Jonathan L. Slack, Ponnusamy Nachimuthu, Rupert C. C. Perera, Nobumichi Tamura, and Michael D. Rubin Journal Journal of Alloys and Compounds Volume 356-357 Start Page 204 Pagination 204-207 Date Published 08/2003 Keywords A. hydrogen storage materials, NEXAFS, thin film s; C. EXAFS, x-ray diffraction Abstract Mixed metal thin films containing magnesium and a first-row transition element exhibit very large changes in both reflectance and transmittance on exposure to hydrogen gas. Changes in electronic structure and coordination of the magnesium and transition metal atoms during hydrogen absorption were studied using dynamic in situ transmission mode X-ray absorption spectroscopy. Mg K-edge and Ni, Co, and Ti L-edge spectra reflect both reversible and irreversible changes in the metal environments. A significant shift in the nickel L absorption edge shows it to be an active participant in hydride formation. The effect on cobalt and titanium is much less dramatic, suggesting that these metals act primarily as catalysts for formation of magnesium hydride.

195

MoWiTT:Mobile Window Thermal Test Facility  

NLE Websites -- All DOE Office Websites (Extended Search)

0 0 MoWiTT: Mobile Window Thermal Test Facility The window has come a long way since the days when it was a single pane of glass in a wood frame. Low-emissivity windows were designed to help buildings retain some of the energy that would have leaked out of less efficient windows. Designing efficient window-and-frame systems requires accurate measurement of the flow of energy through windows in realistic conditions, a capability provided by the Mobile Window Thermal Test facility. Consisting of a pair of outdoor, room-sized calorimeters, MoWiTT measures the net energy flow through two window samples in side-by-side tests using ambient weather conditions. MoWiTT characterizes the net energy flow as a function of time and measures the temperatures, solar fluxes, and

196

Co-Mo Electric Coop Inc | Open Energy Information  

Open Energy Info (EERE)

Mo Electric Coop Inc Mo Electric Coop Inc Jump to: navigation, search Name Co-Mo Electric Coop Inc Place Missouri Utility Id 4063 Utility Location Yes Ownership C NERC Location SERC NERC MRO Yes Activity Distribution Yes References EIA Form EIA-861 Final Data File for 2010 - File1_a[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Utility Rate Schedules Grid-background.png Commercial Multi-Phase Commercial Commercial Single-Phase Over 200 Amps Commercial Commercial Single-Phase Up To 200 Amps Commercial Industrial Industrial Outdoor Lighting HPS 100 W Lighting Outdoor Lighting HPS 150 W Lighting Outdoor Lighting HPS 400 W Lighting Residential Multi-Phase Residential Residential Single-Phase Over 200 Amps Residential

197

DOE - Office of Legacy Management -- Medart Co - MO 09  

Office of Legacy Management (LM)

Medart Co - MO 09 Medart Co - MO 09 FUSRAP Considered Sites Site: MEDART CO. (MO.09 ) Eliminated from consideration under FUSRAP - Facility believed to be torn down and the original site built over Designated Name: Not Designated Alternate Name: None Location: 180 Potomoc Street , St. Louis , Missouri MA.09-4 Evaluation Year: Circa 1990 MA.09-3 Site Operations: Conducted test machining operations on uranium bar stock during the early 1950s. MA.09-2 Site Disposition: Eliminated - Potential for contamination considered remote due limited duration of operations and to site reconstruction MA.09-2 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled: Uranium Metal (test quantities) MA.09-3 Radiological Survey(s): Health and safety monitoring during operations MA.09-3

198

Cleanup of plutonium oxide reduction black salts  

Science Conference Proceedings (OSTI)

This work describes pyrochemical processes employed to convert direc oxide reduction (DOR) black salts into discardable white salt and plutonium metal. The DOR process utilizes calcium metal as the reductant in a molten calcium chloride solvent salt to convert plutonium oxide to plutonium metal. An insoluble plutonium-rich dispersion called black salt sometimes forms between the metal phase and the salt phase. Black salts accumulated for processing were treated by one of two methods. One method utilized a scrub alloy of 70 wt % magnesium/30 wt % zinc. The other method utilized a pool of plutonium metal to agglomerate the metal phase. The two processes were similar in that calcium metal reductant and calcium chloride solvent salt were used in both cases. Four runs were performed by each method, and each method produced greater than 93% conversion of the black salt.

Giebel, R.E.; Wing, R.O.

1986-12-17T23:59:59.000Z

199

U-Mo Plate Blister Anneal Interim Report  

SciTech Connect

Blister thresholds in fuel elements have been a longstanding performance parameter for fuel elements of all types. This behavior has yet to be fully defined for the RERTR U-Mo fuel types. Blister anneal studies that began in 2007 have been expanded to include plates from more recent RERTR experiments. Preliminary data presented in this report encompasses the early generations of the U-Mo fuel systems and the most recent but still developing fuel system. Included is an overview of relevant dispersion fuel systems for the purposes of comparison.

Francine J. Rice; Daniel M. Wachs; Adam B. Robinson; Dennis D. Keiser Jr.; Jan-Fong Jue; Danielle M. Perez; Ross Finlay

2010-10-01T23:59:59.000Z

200

MUTLI-OBJECTIVE OPTIMIZATION OF MICROSTRUCTURE IN WROUGHT MAGNESIUM ALLOYS  

SciTech Connect

The microstructural features that govern the mechanical properties of wrought magnesium alloys include grain size, crystallographic texture, and twinning. Several processes based on shear deformation have been developed that promote grain refinement, weakening of the basal texture, as well as the shift of the peak intensity away from the center of the basal pole figure - features that promote room temperature ductility in Mg alloys. At ORNL, we are currently exploring the concept of introducing nano-twins within sub-micron grains as a possible mechanism for simultaneously improving strength and ductility by exploiting a potential dislocation glide along the twin-matrix interface a mechanism that was originally proposed for face-centered cubic materials. Specifically, we have developed an integrated modeling and optimization framework in order to identify the combinations of grain size, texture and twin spacing that can maximize strength-ductility combinations. A micromechanical model that relates microstructure to material strength is coupled with a failure model that relates ductility to a critical shear strain and a critical hydrostatic stress. The micro-mechanical model is combined with an optimization tool based on genetic algorithm. A multi-objective optimization technique is used to explore the strength-ductility space in a systematic fashion and identify optimum combinations of the microstructural parameters that will simultaneously maximize the strength-ductility in the alloy.

Radhakrishnan, Balasubramaniam [ORNL; Gorti, Sarma B [ORNL; Simunovic, Srdjan [ORNL

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mo magnesium oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Convergent close-coupling calculations of positron-magnesium scattering  

SciTech Connect

The single-center convergent close-coupling method has been applied to positron-magnesium scattering at incident energies from 0.01 to 100 eV. Cross sections are presented for elastic scattering and excitation of 3 {sup 1}P, as well as for the total ionization and total scattering processes. We also provide an estimate of the positronium formation cross section. The results agree very well with the measurements of the total cross section by Stein et al. [Nucl. Instrum. Methods Phys. Res. Sect. B 143, 68 (1998)], and consistent with the positronium formation measurements of Surdutovich et al. [Phys. Rev. A 68, 022709 (2003)] for positron energies above the ionization threshold. For energies below the positronium formation threshold (0.8 eV) we find a large P-wave resonance at 0.17 eV. A similar resonance behavior was found by Mitroy and Bromley [Phys. Rev. Lett. 98, 173001 (2007)] at an energy of 0.1 eV.

Savage, Jeremy S.; Fursa, Dmitry V.; Bray, Igor [ARC Centre for Antimatter-Matter Studies, Curtin University of Technology, GPO Box U1987, Perth, WA 6845 (Australia)

2011-06-15T23:59:59.000Z

202

REDUCTION OF URANIUM HEXAFLUORIDE RETENTION ON BEDS OF MAGNESIUM FLUORIDE USED FOR REMOVAL OF TECHNETIUM HEXAFLUORIDE  

SciTech Connect

The excessive loss of uranium incurred when discarding magnesium fluoride, (the adsorber used to selectively remove technetium hexafluoride from uranium hexafluoride streams) is a problem common to all volatility processes for recovering enriched uranium fuels. As a result of the work described, two schemes for the release of the uranium hexafluoride from the magnesium fluoride and its separation from the technetium hexafluoride are proposed. One scheme depends on preferential thermal desorption of the uranium hexafluoride at 350 deg C and the other on selective adsorption of the uranium hexafluoride on sodium fluoride pellets following the codesorption of the two hexafluorides with fluorine at 500 deg C from the magnesium fluoride pellets. These proposals are aimed at reducing the amount of retained uranium to less than 1 g per 1000 g of discardable magnesium fluoride. In the work reported, the deposition of uranium on magnesium fluoride as a function of heating, fluorination, and hydrogen fluoride pretreatment of the magnesium fluoride pellets prior to exposure to uranium hexafluoride was characterized in a series of gasometric studies. The dependence of the quantity of uranium hexafluoride adsorbed on pressure and temperature was also determined. The data show that physical adsorption is the mechanism for the deposition of most of the uranium hexafluoride on well- stabilized magnesium fluoride pellets. More than 90% of the adsorbate can be removed by heating to 350 deg C. Chemisorption (formation of a double salt) is probably not involved because of the small (<0.05) mole ratio of UF/sub 6//MgF/ sub 2/ observed. (auth)

Katz, S.

1964-01-31T23:59:59.000Z

203

Multifunctional Oxides  

Science Conference Proceedings (OSTI)

3) Electric, ferroelectric, magnetic and photonic properties of oxides 4) Theoretical modeling of epitaxial growth, interfaces and microstructures 5) Composition ...

204

MAGNESIUM MONO POTASSIUM PHOSPHATE GROUT FOR P-REACTOR VESSEL IN-SITU DECOMISSIONING  

SciTech Connect

The objective of this report is to document laboratory testing of magnesium mono potassium phosphate grouts for P-Reactor vessel in-situ decommissioning. Magnesium mono potassium phosphate cement-based grout was identified as candidate material for filling (physically stabilizing) the 105-P Reactor vessel (RV) because it is less alkaline than portland cement-based grout (pH of about 12.4). A less alkaline material ({<=} 10.5) was desired to address a potential materials compatibility issue caused by corrosion of aluminum metal in highly alkaline environments such as that encountered in portland cement grouts. Information concerning access points into the P-Reactor vessel and amount of aluminum metal in the vessel is provided elsewhere. Fresh and cured properties were measured for: (1) commercially blended magnesium mono potassium phosphate packaged grouts, (2) commercially available binders blended with inert fillers at SRNL, (3) grouts prepared from technical grade MgO and KH{sub 2}PO{sub 4} and inert fillers (quartz sands, Class F fly ash), and (4) Ceramicrete{reg_sign} magnesium mono potassium phosphate-based grouts prepared at Argonne National Laboratory. Boric acid was evaluated as a set retarder in the magnesium mono potassium phosphate mixes.

Langton, C.; Stefanko, D.

2011-01-05T23:59:59.000Z

205

Domestic production of medical isotope Mo-99 moves a step closer  

NLE Websites -- All DOE Office Websites (Extended Search)

Domestic production of medical isotope Mo-99 Domestic production of medical isotope Mo-99 moves a step closer Irradiated uranium fuel has been recycled and reused for molybdenum-99...

206

Large-Scale Synthesis of MoS2/ Polymer Derived Ceramic ...  

Science Conference Proceedings (OSTI)

Applications of MoS2 as lithium ion battery anode material are also being explored. Here, we demonstrate exfoliation of MoS2 into single and few layers.

207

Elevated Temperature Compression Testing of the U-10 wt% Mo Alloy  

Science Conference Proceedings (OSTI)

Abstract Scope, In order to satisfy non-proliferation treaties the metallic U-10 wt% Mo (U-10Mo) alloy in low enrichments is under development to replace highly ...

208

ÂżCĂłmo funcionan los HĂ­bridos?  

NLE Websites -- All DOE Office Websites (Extended Search)

¿Cómo funcionan los Híbridos? ¿Cómo funcionan los Híbridos? Diagrama de los componentes de un híbrido completo, incluyen (1) un motor de combustión interna (2) un motor eléctrico, (3) un generador, (4) una aparato de cambio de motor, and (5) una batería de gran capacidad. en inglés Flash Animation: ¿Cómo funcionan los Híbridos? (Requiere versión Flash 6.0 o superior) HTML Version: ¿Cómo funcionan los Híbridos? Los vehículos Híbridos-eléctricos (VHEs) combinan las ventajas de los motores de gasolina con los motores eléctricos y se pueden configurar para diferentes objetivos, como mejorar el ahorro de combustible, aumentar su fuerza, o proveer fuerza adicional para el uso del sistema eléctrico o los componentes electrónicos. Algunas de las tecnologías avanzadas que usan los híbridos típicamente

209

ProMoVer: modular verification of temporal safety properties  

Science Conference Proceedings (OSTI)

This paper describes ProMoVer, a tool for fully automated procedure-modular verification of Java programs equipped with method-local and global assertions that specify safety properties of sequences of method invocations. Modularity at the procedure-level ...

Siavash Soleimanifard; Dilian Gurov; Marieke Huisman

2011-11-01T23:59:59.000Z

210

Comparison of Crevice Corrosion of Fe-Based Amorphous Metal and Crystalline Ni-Cr-Mo Alloy  

SciTech Connect

The crevice corrosion behaviors of an Fe-based bulk metallic glass alloy (SAM1651) and a Ni-Cr-Mo crystalline alloy (C-22) were studied in 4M NaCl at 100 C with cyclic potentiodynamic polarization and constant potential tests. The corrosion damage morphologies, corrosion products and the compositions of corroded surfaces of these two alloys were studied with optical 3D reconstruction, Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS) and Auger Electron Spectroscopy (AES). It was found that the Fe-based bulk metallic glass (amorphous alloy) SAM1651 had a more positive breakdown potential and repassivation potential than crystalline alloy C-22 in cyclic potentiodynamic polarization tests and required a more positive oxidizing potential to initiate crevice corrosion in constant potential test. Once crevice corrosion initiated, the corrosion propagation of C-22 was more localized near the crevice border compared to SAM1651, and SAM1651 repassivated more readily than C-22. The EDS results indicated that the corrosion products of both alloys contained high amount of O and were enriched in Mo and Cr. The AES results indicated that a Cr-rich oxide passive film was formed on the surfaces of both alloys, and both alloys were corroded congruently.

Shan, X; Ha, H; Payer, J H

2008-07-24T23:59:59.000Z

211

Lightning arrestor connector lead magnesium niobate qualification pellet test procedures.  

SciTech Connect

Enhanced knowledge preservation for DOE DP technical component activities has recently received much attention. As part of this recent knowledge preservation effort, improved documentation of the sample preparation and electrical testing procedures for lead magnesium niobate--lead titanate (PMN/PT) qualification pellets was completed. The qualification pellets are fabricated from the same parent powders used to produce PMN/PT lightning arrestor connector (LAC) granules at HWF&T. In our report, the procedures for fired pellet surface preparation, electrode deposition, electrical testing and data recording are described. The dielectric measurements described in our report are an information only test. Technical reasons for selecting the electrode material, electrode size and geometry are presented. The electrical testing is based on measuring the dielectric constant and dissipation factor of the pellet during cooling from 280 C to 220 C. The most important data are the temperature for which the peak dielectric constant occurs (Curie Point temperature) and the peak dielectric constant magnitude. We determined that the peak dielectric constant for our procedure would be that measured at 1 kHz at the Curie Point. Both the peak dielectric constant and the Curie point parameters provide semi-quantitative information concerning the chemical and microstructural homogeneity of the parent material used for the production of PMN/PT granules for LACs. Finally, we have proposed flag limits for the dielectric data for the pellets. Specifically, if the temperature of the peak dielectric constant falls outside the range of 250 C {+-} 30 C we propose that a flag limit be imposed that will initiate communication between production agency and design agency personnel. If the peak dielectric constant measured falls outside the range 25,000 {+-} 10,000 we also propose that a flag limit be imposed.

Tuohig, W. (Honeywell FM& T, Kansas City, MO); Mahoney, Patrick A.; Tuttle, Bruce Andrew; Wheeler, Jill Susanne

2009-02-01T23:59:59.000Z

212

Geochemical Aspects of the Carbonation of Magnesium Silicates in an Aqueous Medium  

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GEOCHEMICAL ASPECTS OF THE CARBONATION OF MAGNESIUM GEOCHEMICAL ASPECTS OF THE CARBONATION OF MAGNESIUM SILICATES IN AN AQUEOUS MEDIUM George D. Guthrie, Jr. (gguthrie@lanl.gov 505-665-6340) J. William Carey (bcarey@lanl.gov 505-667-5540) Deborah Bergfeld (debberrg@lanl.gov 505-667-1812) Darrin Byler (dbyler@lanl.gov 505-665-9562) Steve Chipera (chipera@lanl.gov 505-667-1110) Hans-Joachim Ziock (ziock@lanl.gov 505-667-7265) Hydrology, Geochemistry, & Geology Los Alamos National Laboratory Los Alamos, NM 87545 Klaus Lackner (ksl@lanl.gov 505-667-5694) Theoretical Division, Los Alamos National Laboratory, Los Alamos, NM and Columbia University, New York, NY KEYWORDS: CO 2 sequestration, magnesium silicate, mineral carbonation INTRODUCTION The volume of carbon dioxide associated with the use of fossil fuels to produce

213

Cohesion enhancing effect of magnesium in aluminum grain boundary: A first-principles determination  

SciTech Connect

The effect of magnesium on grain boundary cohesion in aluminum was investigated by means of first-principles calculations using the Rice-Wang model [Rice and Wang, Mater. Sci. Eng. A 107, 23 (1989)]. It is demonstrated that magnesium is a cohesion enhancer with a potency of -0.11 eV/atom. It is further determined through electronic structure and bonding character analysis that the cohesion enhancing property of magnesium is due to a charge transfer mechanism which is unusually strong and overcomes the negative result of the size effect mechanism. Consistent with experimental results, this work clarifies the controversy and establishes that Mg segregation does not contribute to stress corrosion cracking in Al alloys.

Zhang Shengjun; Freeman, Arthur J. [Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208 (United States); Department of Physics and Astronomy, Northwestern University, Evanston, Illinois 60208 (United States); Kontsevoi, Oleg Y. [Department of Physics and Astronomy, Northwestern University, Evanston, Illinois 60208 (United States); Olson, Gregory B. [Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208 (United States)

2012-06-04T23:59:59.000Z

214

Coordination Chemistry in magnesium battery electrolytes: how ligands affect their performance  

Science Conference Proceedings (OSTI)

Magnesium battery is potentially a safe, cost-effective, and high energy density technology for large scale energy storage. However, the development of magnesium battery has been hindered by the limited performance and the lack of fundamental understandings of electrolytes. Here, we present a coordination chemistry study of Mg(BH4)2 in ethereal solvents. The O donor denticity, i.e. ligand strength of the ethereal solvents which act as ligands to form solvated Mg complexes, plays a significant role in enhancing coulombic efficiency of the corresponding solvated Mg complex electrolytes. A new and safer electrolyte is developed based on Mg(BH4)2, diglyme and optimized LiBH4 additive. The new electrolyte demonstrates 100% coulombic efficiency, no dendrite formation, and stable cycling performance with the cathode capacity retention of ~90% for 300 cycles in a prototype magnesium battery.

Shao, Yuyan; Liu, Tianbiao L.; Li, Guosheng; Gu, Meng; Nie, Zimin; Engelhard, Mark H.; Xiao, Jie; Lu, Dongping; Wang, Chong M.; Zhang, Jiguang; Liu, Jun

2013-11-04T23:59:59.000Z

215

Influence of Si Co-doping on electrical transport properties of magnesium-doped boron nanoswords  

Science Conference Proceedings (OSTI)

Magnesium-doped boron nanoswords were synthesized via a thermoreduction method. The as-prepared nanoswords are single crystalline and {beta}-rhombohedral ({beta}-rh) phase. Electrical transport measurements show that variable range hopping conductivity increases with temperature, and carrier mobility has a greater influence than carrier concentration. These results are consistent with the three dimensional Mott's model (M. Cutler and N. F. Mott, Phys. Rev. 181, 1336 (1969)) besides a high density of localized states at the Fermi level compared with bulk {beta}-rh boron. Conductivity of Mg-doped boron nanoswords is significantly lower than that of ''pure'' (free of magnesium) boron nanoswords. Electron energy loss spectroscopy studies confirm that the poorer conductivity arises from silicon against magnesium doping.

Tian Yuan; Lu Hongliang; Tian Jifa; Li Chen; Hui Chao; Shi Xuezhao; Huang Yuan; Shen Chengmin; Gao Hongjun [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China)

2012-03-05T23:59:59.000Z

216

On the Reaction Mechanism of Acetaldehyde Decomposition on Mo(110)  

Science Conference Proceedings (OSTI)

The strong Mo-O bond strength provides promising reactivity of Mo-based catalysts for the deoxygenation of biomass-derived oxygenates. Combining the novel dimer saddle point searching method with periodic spin-polarized density functional theory calculations, we investigated the reaction pathways of a acetaldehyde decomposition on the clean Mo(110) surface. Two reaction pathways were identified, a selective deoxygenation and a nonselective fragmentation pathways. We found that acetaldehyde preferentially adsorbs at the pseudo 3-fold hollow site in the ?2(C,O) configuration on Mo(110). Among four possible bond (?-C-H, ?-C-H, C-O and C-C) cleavages, the initial decomposition of the adsorbed acetaldehyde produces either ethylidene via the C-O bond scission or acetyl via the ?-C-H bond scission while the C-C and the ?-C-H bond cleavages of acetaldehyde leading to the formation of methyl (and formyl) and formylmethyl are unlikely. Further dehydrogenations of ethylidene into either ethylidyne or vinyl are competing and very facile with low activation barriers of 0.24 and 0.31 eV, respectively. Concurrently, the formed acetyl would deoxygenate into ethylidyne via the C-O cleavage rather than breaking the C-C or the C-H bonds. The selective deoxygenation of acetaldehyde forming ethylene is inhibited by relatively weaker hydrogenation capability of the Mo(110) surface. Instead, the nonselective pathway via vinyl and vinylidene dehydrogenations to ethynyl as the final hydrocarbon fragment is kinetically favorable. On the other hand, the strong interaction between ethylene and the Mo(110) surface also leads to ethylene decomposition instead of desorption into the gas phase. This work was financially supported by the National Advanced Biofuels Consortium (NABC). Computing time was granted by a user project (emsl42292) at the Molecular Science Computing Facility in the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL). This work was financially supported by the National Advanced Biofuels Consortium (NABC). Computing time was granted by a user project (emsl42292) at the Molecular Science Computing Facility in the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL). The EMSL is a U.S. Department of Energy (DOE) national scientific user facility located at Pacific Northwest National Laboratory (PNNL) and supported by the DOE Office of Biological and Environmental Research. Pacific Northwest National Laboratory is operated by Battelle for the U.S. Department of Energy.

Mei, Donghai; Karim, Ayman M.; Wang, Yong

2012-02-16T23:59:59.000Z

217

Recovery of Magnesium from Waste Effluent in Nickel Laterite ...  

Science Conference Proceedings (OSTI)

Abstract Scope, Eliminating the environmental threat caused by waste ... Characterization of the Chemical Changes and Surface Properties of Carbonated Waste Cement ... Flux for Basic Oxygen Steel Making Using Waste Oxides of Steel Plant ... Heat Treatment of Black Dross for the Production of a Value Added Material ...

218

Graphitization in C and C-Mo Steels  

Science Conference Proceedings (OSTI)

Following the recent carbon (C) and carbon-molybdenum (C-Mo) steel graphitization experience reported by several Electric Power Research Institute (EPRI) members, it became apparent that the industry could benefit from better predictive guidance to prioritize component inspections and examinations for graphitization. This research effort collected and analyzed the additional experience gained since the last EPRI project on the subject and focused on developing suitably conservative time-temperature predi...

2010-12-23T23:59:59.000Z

219

Fabrication of solid oxide fuel cell by electrochemical vapor deposition  

DOE Patents (OSTI)

In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (approximately 1100.degree.-1300.degree. C.) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20-50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

Brian, Riley (Willimantic, CT); Szreders, Bernard E. (Oakdale, CT)

1989-01-01T23:59:59.000Z

220

Fabrication of solid oxide fuel cell by electrochemical vapor deposition  

DOE Patents (OSTI)

In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (/approximately/1100/degree/ /minus/ 1300/degree/C) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20--50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

Riley, B.; Szreders, B.E.

1988-04-26T23:59:59.000Z

Note: This page contains sample records for the topic "mo magnesium oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Magnesium transport extraction of transuranium elements from LWR fuel  

DOE Patents (OSTI)

A process of separating transuranium actinide values from uranium values present in spent nuclear oxide fuels which contain rare earth and noble metal fission products. The oxide fuel is reduced with Ca metal in the presence of CaCl.sub.2 and a U-Fe alloy containing not less than about 84% by weight uranium at a temperature in the range of from about 800.degree. C. to about 850.degree. C. to produce additional uranium metal which dissolves in the U-Fe alloy raising the uranium concentration and having transuranium actinide metals and rare earth fission product metals and the noble metal fission products dissolved therein. The CaCl.sub.2 having CaO and fission products of alkali metals and the alkali earth metals and iodine dissolved therein is separated and electrolytically treated with a carbon electrode to reduce the CaO to Ca metal while converting the carbon electrode to CO and CO.sub.2. The Ca metal and CaCl.sub.2 is recycled to reduce additional oxide fuel. The U-Fe alloy having transuranium actinide metals and rare earth fission product metals and the noble metal fission products dissolved therein is contacted with Mg metal which takes up the actinide and rare earth fission product metals. The U-Fe alloy retains the noble metal fission products and is stored while the Mg is distilled and recycled leaving the transuranium actinide and rare earth fission products isolated.

Ackerman, John P. (Downers Grove, IL); Battles, James E. (Oak Forest, IL); Johnson, Terry R. (Wheaton, IL); Miller, William E. (Naperville, IL); Pierce, R. Dean (Naperville, IL)

1992-01-01T23:59:59.000Z

222

Magnesium transport extraction of transuranium elements from LWR fuel  

SciTech Connect

This report discusses a process of separating transuranium actinide values from uranium values present in spent nuclear oxide fuels which contain rare earth and noble metal fission products. The oxide fuel is reduced with Ca metal in the presence of CaCl{sub 2} and a U-Fe alloy containing not less than about 84% by weight uranium at a temperature in the range of from about 800{degrees}C to about 850{degrees}C to produce additional uranium metal which dissolves in the U-Fe alloy raising the uranium concentration and having transuranium actinide metals and rare earth fission product metals and the noble metal fission products dissolved therein. The CaCl{sub 2} having CaO and fission products of alkali metals and the alkali earth metals and iodine dissolved therein is separated and electrolytically treated with a carbon electrode to reduce the CaO to Ca metal while converting the carbon electrode to CO and CO{sub 2}. The Ca metal and CaCl{sub 2} is recycled to reduce additional oxide fuel. The U-Fe alloy having transuranium actinide metals and rare earth fission product metals and the noble metal fission products dissolved therein is contacted with Mg metal which takes up the actinide and rare earth fission product metals. The U-Fe alloy retains the noble metal fission products and is stored while the Mg is distilled and recycled leaving the transuranium actinide and rare earth fission products isolated.

Ackerman, J.P.; Battles, J.E.; Johnson, T.R.; Miller, W.E.; Pierce, R.D.

1991-12-31T23:59:59.000Z

223

245 Oxidation Behaviors of Silica Coated Mo-Si-B Alloys  

Science Conference Proceedings (OSTI)

021 Radiation Interactions in Biologically Important Materials ... 050 Investigation of ZnO:N and ZnO:(Al,N) Films for Solar Driven Hydrogen Production ... 070 A Phenomenological Thermodynamic Potential of CaTiO3 Single Crystals.

224

B19 High Temperature Oxidation Behavior of Si-Mo Ferritic Ductile ...  

Science Conference Proceedings (OSTI)

D14 Gold Nanoparticles in Red Ruby Glasses Used for Decoration in Thailand · D15 Soft Magnetic Properties of Nanocrystalline Fe-based P/M Cores Mixed ...

225

Oxidation of the Mo-Si-B Based Coating In Oxygen Deficient ...  

Science Conference Proceedings (OSTI)

... in engine, aircraft and aerospace applications requires an external protective ... Hot Corrosion of SiC Cermaic Matrix Composites in Marine Combustion ...

226

Coupling of oxidative dehydrogenation and aromatization reactions of butane  

Science Conference Proceedings (OSTI)

Coupling of oxidative dehydrogenation and aromatization of butane by using a dual function catalyst has led to a significant enhancement of the yields (from 25 to 40%) and selectivities to aromatics (from 39 to 64%). Butane is converted to aromatics by using either zinc-promoted [Ga]-ZSM-5 or zinc and gallium copromoted [Fe]-ZSM-5 zeolite as a catalyst. However, the formation of aromatics is severely limited by hydrocracking of butane to methane, ethane, and propane due to the hydrogen formed during aromatization reactions. On the other hand, the oxidative dehydrogenation of butane to butene over molybdate catalysts is found to be accompanied by a concurrent undesirable reaction, i.e., total oxidation. When two of these reactions (oxidative dehydrogenation and aromatization of butane) are coupled by using a dual function catalyst they have shown to complement each other. It is believed that the rate-limiting step for aromatization (butane to butene) is increased by adding an oxidative dehydrogenation catalyst (Ga-Zn-Mg-Mo-O). The formation of methane, ethane, and propane was suppressed due to the removal of hydrogen initially formed as water. Studies of ammonia TPD show that the acidities of [Fe]-ZSM-5 are greatly affected by the existence of metal oxides such as Ga[sub 2]O[sub 3], MgO, ZnO, and MoO[sub 3]. 40 refs., 9 figs., 1 tab.

Xu, Wen-Qing; Suib, S.L. (Univ. of Connecticut, Storrs, CT (United States))

1994-01-01T23:59:59.000Z

227

Development and processing of LEU targets for {sup 99}Mo production-overview of the ANL program  

SciTech Connect

Most of the world`s supply of {sup 99m}Tc for medical purposes is currently produced from the decay of {sup 99}Mo derived from the fissioning of high-enriched uranium (HEU). Substitution of low-enriched uranium (LEU) silicide fuel for the HEU alloy and aluminide fuels used in most current target designs will allow equivalent {sup 99}Mo yields with little change in target geometries. Substitution of uranium metal for uranium oxide films in other target designs will also allow the substitution of LEU for HEU. During 1995, we have continued to study the modification of current targets and processes to allow the conversion from HEU to LEU. A uranium-metal-foil target was fabricated at ANL and irradiated to prototypic burnup in the Indonesian RSG-GAS reactor. Postirradiation examination indicated that minor design modifications will be required to allow the irradiated foil to be removed for chemical processing. Means to dissolve and process LEU foil have been developed, and a mock LEU foil target was processed in Indonesia. We have also developed means to dissolve the LEU foil in alkaline peroxide, where it can be used to replace HEU targets that are currently dissolved in base before recovering and purifying the {sup 99}Mo. We have also continued work on the dissolution of U{sub 3}Si{sub 2} and have a firm foundation on dissolving these targets in alkaline peroxide. The technology-exchange agreement with Indonesia is well underway, and we hope to expand our international cooperations in 1996.

Snelgrove, J.L.; Hofman, G.L.; Wiencek, T.C. [and others

1995-09-01T23:59:59.000Z

228

Method to decrease loss of aluminum and magnesium melts  

SciTech Connect

A method to minimize oxidation of metal during melting processes is provided, the method comprising placing solid phase metal into a furnace environ-ment, transforming the solid-phase metal into molten metal phase having a molten metal surface, and creating a barrier between the surface and the environment. Also provided is a method for isolating the surface of molten metal from its environment, the method comprising confining the molten metal to a controlled atmos-phere, and imposing a floating substrate between the surface and the atmosphere.

Hryn, John N. (Naperville, IL); Pellin, Michael J. (Naperville, IL); Calaway, Jr., Wallis F. (Woodridge, IL); Moore, Jerry F. (Naperville, IL); Krumdick, Gregory K. (Crete, IL)

2002-01-01T23:59:59.000Z

229

Statistical pairing fluctuation and phase transition in $^{94}Mo$  

E-Print Network (OSTI)

In the framework of BCS model, we have applied the isothermal probability distribution to take into account the statistical fluctuations in calculation of thermodynamical properties of nuclei. The energy and the heat capacity are calculated in $^{94}Mo$ nucleus using the mean gap parameter. The results are compared with the values obtained based on the most probable values, experimental data as well as some other theoretical models. We have shown that heat capacity versus temperature behaves smoothly instead of singular behaviour predicted by the standard BCS model. Also a smooth peak in heat capacity is observed which is a signature of transition from normal to super fluid phase.

Z. Kargar; V. Dehghani

2013-07-16T23:59:59.000Z

230

Statistical pairing fluctuation and phase transition in $^{94}Mo$  

E-Print Network (OSTI)

In the framework of BCS model, we have applied the isothermal probability distribution to take into account the statistical fluctuations in calculation of thermodynamical properties of nuclei. The energy and the heat capacity are calculated in $^{94}Mo$ nucleus using the mean gap parameter. The results are compared with the values obtained based on the most probable values, experimental data as well as some other theoretical models. We have shown that heat capacity versus temperature behaves smoothly instead of singular behaviour predicted by the standard BCS model. Also a smooth peak in heat capacity is observed which is a signature of transition from normal to super fluid phase.

Kargar, Z

2013-01-01T23:59:59.000Z

231

Greenfield Alternative Study LEU-Mo Fuel Fabrication Facility  

Science Conference Proceedings (OSTI)

This report provides the initial “first look” of the design of the Greenfield Alternative of the Fuel Fabrication Capability (FFC); a facility to be built at a Greenfield DOE National Laboratory site. The FFC is designed to fabricate LEU-Mo monolithic fuel for the 5 US High Performance Research Reactors (HPRRs). This report provides a pre-conceptual design of the site, facility, process and equipment systems of the FFC; along with a preliminary hazards evaluation, risk assessment as well as the ROM cost and schedule estimate.

Washington Division of URS

2008-07-01T23:59:59.000Z

232

Upper critical field of Mo-Ni heterostructures  

SciTech Connect

Upper critical field and its anisotropy have been measured on two very short wavelength Mo-Ni heterostructures of different degrees of perfection, lambda = 13.8A (disordered structure) and lambda = 16.6A (layered structure). In both cases the parallel critical field has an unexpected temperature dependence, a large and temperature dependent anisotropy, and over 60% enhancement over the Clogston-Chandrasekhar limit. Data are fit to the Werthamer-Helfand-Hohenberg theory and the spin-orbit scattering times are found to be 1.79 x 10 T s and 2 x 10 T s, respectively.

Uher, C.; Watson, W.J.; Cohn, J.L.; Schuller, I.K.

1985-12-01T23:59:59.000Z

233

Tensile mechanical properties and strengthening mechanism of hybrid carbon nanotube and silicon carbide nanoparticle-reinforced magnesium alloy composites  

Science Conference Proceedings (OSTI)

AZ91 magnesium alloy hybrid composites reinforced with different hybrid ratios of carbon nanotubes (CNTs) and silicon carbide (SiC) nanoparticulates were fabricated by semisolid stirring assisted ultrasonic cavitation. The results showed that grains ...

Xia Zhou; Depeng Su; Chengwei Wu; Liming Liu

2012-01-01T23:59:59.000Z

234

An approach to modeling the cost-strength-weight tradeoff in aluminum and magnesium extrusions for automotive applications  

E-Print Network (OSTI)

In light of volatile fuel prices and tightening emissions regulations, automobile manufacturers have been increasingly considering the use of light-weight magnesium in their efforts to improve fuel economy. While mainly ...

Komander, Johann Kasper

2009-01-01T23:59:59.000Z

235

Identifying barriers to the availability and use of Magnesium Sulphate Injection in resource poor countries: A case study in Zambia  

E-Print Network (OSTI)

barriers to the availability and use of Magnesium Sulphateto identify barriers to the availability and use of MgSO4 infacilitators to the availability and use of MgSO4 identified

Ridge, Anna L; Bero, Lisa A; Hill, Suzanne R

2010-01-01T23:59:59.000Z

236

Studying the Effect of Carbon on DU-Mo Foil Fabrication for the ...  

Science Conference Proceedings (OSTI)

In support of this program, efforts are ongoing to develop and validate a monolithic depleted uranium molybdenum (DU-Mo) foil fabrication process adaptable for ...

237

Surface Structures of Cubo-octahedral Pt-Mo Catalyst Nanoparticles from Monte Carlo Simulations  

E-Print Network (OSTI)

of Cubo-octahedral Pt-Mo Catalyst Nanoparticles from Montefuel cells, new electrode catalysts that have less preciousto designing Pt bimetallic catalysts is knowledge of the

Wang, Guofeng; Van Hove, M.A.; Ross, P.N.; Baskes, M.I.

2005-01-01T23:59:59.000Z

238

Pressure Water Leaching Molybdenum and Nickel from Mo-Ni ore of ...  

Science Conference Proceedings (OSTI)

Presentation Title, Pressure Water Leaching Molybdenum and Nickel from Mo-Ni ore of Black Shale without Reagent. Author(s), Zhigan Deng. On-Site Speaker ...

239

Disorder effects in half-metallic Sr 2 FeMoO 6 single crystals  

Science Conference Proceedings (OSTI)

Double perovskites such as Sr 2 FeMoO 6 (SFMO) have been predicted to be half-metallic (100% spin polarized). However

Raghava P. Panguluri; Sheng Xu; Yutaka Moritomo; I. V. Solovyev; B. Nadgorny

2009-01-01T23:59:59.000Z

240

Synthesis of molybdenum disulfide (MoS{sub 2}) for lithium ion battery applications  

Science Conference Proceedings (OSTI)

This paper reports the use of a rheological phase reaction method for preparing MoS{sub 2} nanoflakes. The characterization by powder X-ray diffraction indicated that MoS{sub 2} had been formed. High resolution electron microscopy observation revealed that the as-prepared MoS{sub 2} nanoflakes had started to curve and partly form MoS{sub 2} nanotubes. The lithium intercalation/de-intercalation behavior of as-prepared MoS{sub 2} nanoflake electrode was also investigated. It was found that the MoS{sub 2} nanoflake electrode exhibited higher specific capacity, with very high cycling stability, compared to MoS{sub 2} nanoparticle electrode. The possible reasons for the high electrochemical performance of the nanoflakes electrodes are also discussed. The outstanding electrochemical properties of MoS{sub 2} nanoflakes obtained by this method make it possible for MoS{sub 2} to be used as a promising anode material.

Feng Chuanqi [Key Laboratory for Synthesis and Applications of Organic Functional Molecules, Hubei University, Wuhan 430062 (China); Institute for Superconducting and Electronic Materials, University of Wollongong, NSW 2522 (Australia); Ma Jun; Li Hua [Key Laboratory for Synthesis and Applications of Organic Functional Molecules, Hubei University, Wuhan 430062 (China); Zeng Rong [Institute for Superconducting and Electronic Materials, University of Wollongong, NSW 2522 (Australia); Guo Zaiping, E-mail: zguo@uow.edu.au [School of Mechanical, Materials and Mechatronic Engineering, University of Wollongong, NSW 2522 (Australia); Institute for Superconducting and Electronic Materials, University of Wollongong, NSW 2522 (Australia); ARC Centre of Excellence for Electromaterials Science, University of Wollongong, NSW 2522 (Australia); Liu Huakun [Institute for Superconducting and Electronic Materials, University of Wollongong, NSW 2522 (Australia); ARC Centre of Excellence for Electromaterials Science, University of Wollongong, NSW 2522 (Australia)

2009-09-15T23:59:59.000Z

Note: This page contains sample records for the topic "mo magnesium oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Ageing and Toughness of a Mn-Ni-Mo PWR Steel  

Science Conference Proceedings (OSTI)

Abstract Scope, Mn-Ni-Mo steels are widely used in the fabrication of pressurisers, steam generators and pressure vessels of pressurised water reactors (PWR).

242

Utilization of Recycled MoO3 and Mill Scale for Synthesis of High ...  

Science Conference Proceedings (OSTI)

... by ammonia gas neutralization method and reduced by hydrogen to produce a high ... Molybdenum and Nickel from Mo-Ni ore of Black Shale without Reagent.

243

New limit on the neutrinoless double beta decay of /sup 100/Mo  

SciTech Connect

A search for the neutrinoless double beta decay of /sup 100/Mo was conducted using thin Mo films and solid state Si detectors. The experiment has collected 3500 hours of data operating underground in a deep silver mine (3290 M.W.E.). Only one event was found to be consistent with neutrinoless double beta decay. Using this one event, a limit of greater than or equal to 1 x 10/sup 22/ years (1 sigma) is set on the /sup 100/Mo half-life. This is approximately five times larger than the best previous /sup 100/Mo limit.

Krivicich, J.M.

1988-03-01T23:59:59.000Z

244

Experimental activities supporting commercial U.S. accelerator production of 99-Mo  

Science Conference Proceedings (OSTI)

{sup 99m}Tc, the daughter product of {sup 99}Mo, is the most commonly used radioisotope for nuclear medicine in the U.S. Experiments are being performed at Los Alamos National Laboratory and Argonne National Laboratory to demonstrate production of {sup 99}Mo using accelerators. The {sup 100}Mo({gamma},n){sup 99}Mo reaction in an enriched {sup 100}Mo target is currently under investigation. Three scaled low-power production experiments using a 20-MeV electron linac at Argonne have been performed to date. Two of these experiments used natural Mo targets and produced a total of 613 {mu}C of {sup 99}Mo. The third experiment used an enriched {sup 100}Mo target and produced 10.5 mCi of {sup 99}Mo. Following irradiation the targets were dissolved and the low specific activity solution was processed through an ARSII generator from NorthStar Medical Radioisotopes. Yields of {sup 99m}Tc >95% have been observed.

Dale, Gregory E [Los Alamos National Laboratory; Chemerisov, Sergey D [ANL; Vandegrift, George F [ANL

2010-01-01T23:59:59.000Z

245

Oxidation, volatilization, and redistribution of molybdenum from TZM alloy in air  

Science Conference Proceedings (OSTI)

The excellent high temperature strength and thermal conductivity of molybdenum-base alloys provide attractive features for components in advanced magnetic and inertial fusion devices. Refractory metal alloys react readily with oxygen and other gases. Oxidized molybdenum in turn is susceptible to losses from volatile molybdenum trioxide species, MoO{sub 3}(m), in air and the hydroxide, MoO{sub 2}(OH){sub 2}, formed from water vapor. Transport of radioactivity by the volatilization, migration, and re-deposition of these volatile species during a potential accident involving a loss of vacuum or inert environment represents a safety issue. In this report the authors present experimental results on the oxidation, volatilization and re-deposition of molybdenum from TZM in flowing air between 400 and 800 C. These results are compared with calculations obtained from a vaporization mass transfer model using chemical thermodynamic data for vapor pressures of MoO{sub 3}(g) over pure solid MoO{sub 3} and an expression for the vapor pressures of MoO{sub 2}(OH){sub 2} from the literature. Calculations correlate well with experimental data.

Smolik, G.R.; Petti, D.A.; McCarthy, K.A.; Schuetz, S.T.

2000-01-01T23:59:59.000Z

246

Oxidation, Volatilization, and Redistribution of Molybdenum from TZM Alloy in Air  

Science Conference Proceedings (OSTI)

The excellent high temperature strength and thermal conductivity of molybdenum-base alloys provide attractive features for components in advanced magnetic and inertial fusion devices. Refractory metal alloys react readily with oxygen and other gases. Oxidized molybdenum in turn is susceptible to losses from volatile molybdenum trioxide species, (MoO3)m, in air and the hydroxide, MoO2(OH)2, formed from water vapor. Transport of radioactivity by the volatilization, migration, and re-deposition of these volatile species during a potential accident involving a loss of vacuum or inert environment represents a safety issue. In this report we present experimental results on the oxidation, volatilization and re-deposition of molybdenum from TZM in flowing air between 400 and 800°C. These results are compared with calculations obtained from a vaporization mass transfer model using chemical thermodynamic data for vapor pressures of MoO3(g) over pure solid MoO3 and an expression for the vapor pressures of MoO2(OH)2 from the literature. Calculations correlate well with experimental data.

Smolik, Galen Richard; Petti, David Andrew; Mccarthy, Kathryn Ann; Schuetz, Stanley Thomas

2000-01-01T23:59:59.000Z

247

Characterization of U-Mo Foils for AFIP-7  

SciTech Connect

Twelve AFIP in-process foil samples, fabricated by either Y-12 or LANL, were shipped from LANL to PNNL for potential characterization using optical and scanning electron microscopy techniques. Of these twelve, nine different conditions were examined to one degree or another using both techniques. For this report a complete description of the results are provided for one archive foil from each source of material, and one unirradiated piece of a foil of each source that was irradiated in the Advanced Test Reactor. Additional data from two other LANL conditions are summarized in very brief form in an appendix. The characterization revealed that all four characterized conditions contained a cold worked microstructure to different degrees. The Y-12 foils exhibited a higher degree of cold working compared to the LANL foils, as evidenced by the highly elongated and obscure U-Mo grain structure present in each foil. The longitudinal orientations for both of the Y-12 foils possesses a highly laminar appearance with such a distorted grain structure that it was very difficult to even offer a range of grain sizes. The U-Mo grain structure of the LANL foils, by comparison, consisted of a more easily discernible grain structure with a mix of equiaxed and elongated grains. Both materials have an inhomogenous grain structure in that all of the characterized foils possess abnormally coarse grains.

Edwards, Danny J.; Ermi, Ruby M.; Schemer-Kohrn, Alan L.; Overman, Nicole R.; Henager, Charles H.; Burkes, Douglas; Senor, David J.

2012-11-07T23:59:59.000Z

248

CĂłmo funcionan las CĂ©lulas de Combustible  

NLE Websites -- All DOE Office Websites (Extended Search)

Cómo funcionan las Células de Combustible Cómo funcionan las Células de Combustible Diagrama: Como funciona un MPE de combustible de célula. 1. El combustible de hidrógeno es canalizado a través de un campo de placas de flujo para el ånodo al otro lado de la pila de combustible, mientras que el oxígeno del aire se canaliza hacia el cåtodo del otro lado de la celda. 2. En el ånodo, un catalizador de platino hace que el hidrógeno se divida en iones positivos de hidrógeno (protones) y electrones de carga negativa. 3. La Membrana de Electrolito Polimérico (MPE) sólo permite que los iones de carga positiva pasen a través de ella hacia el cåtodo. Los electrones de carga negativa deben viajar a lo largo de un circuito externo hacia el cåtodo, creando una corriente eléctrica. 4. En el cåtodo, los electrones y los iones positivos de hidrógeno se combinan con el oxígeno para formar agua, que fluye fuera de la célula.

249

Oxidation catalyst  

DOE Patents (OSTI)

The present invention generally relates to catalyst systems and methods for oxidation of carbon monoxide. The invention involves catalyst compositions which may be advantageously altered by, for example, modification of the catalyst surface to enhance catalyst performance. Catalyst systems of the present invention may be capable of performing the oxidation of carbon monoxide at relatively lower temperatures (e.g., 200 K and below) and at relatively higher reaction rates than known catalysts. Additionally, catalyst systems disclosed herein may be substantially lower in cost than current commercial catalysts. Such catalyst systems may be useful in, for example, catalytic converters, fuel cells, sensors, and the like.

Ceyer, Sylvia T. (Cambridge, MA); Lahr, David L. (Cambridge, MA)

2010-11-09T23:59:59.000Z

250

SAFETY CONSIDERATIONS FOR HANDLING PLUTONIUM, URANIUM, THORIUM, THE ALKALI METALS, ZIRCONIUM, TITANIUM, MAGNESIUM, AND CALCIUM  

SciTech Connect

BS>This report compiles from various sources safety considerations for work with the special metals plutonium, uranium, thorium, the alkali group, magnesium, titanium, calcium, and zirconium. General criteria to be observed in handling all of these metals and their alloys are listed, as well as characteristics of individual metals with regard to health hazards, pyrophoricity, explosiveness, and other chemical reactions, in both handling and storage. (auth)

Stout, E.L. comp.

1957-09-01T23:59:59.000Z

251

Aerosol chemical vapor deposition of metal oxide films  

DOE Patents (OSTI)

A process of preparing a film of a multicomponent metal oxide including: forming an aerosol from a solution comprised of a suitable solvent and at least two precursor compounds capable of volatilizing at temperatures lower than the decomposition temperature of said precursor compounds; passing said aerosol in combination with a suitable oxygen-containing carrier gas into a heated zone, said heated zone having a temperature sufficient to evaporate the solvent and volatilize said precursor compounds; and passing said volatilized precursor compounds against the surface of a substrate, said substrate having a sufficient temperature to decompose said volatilized precursor compounds whereby metal atoms contained within said volatilized precursor compounds are deposited as a metal oxide film upon the substrate is disclosed. In addition, a coated article comprising a multicomponent metal oxide film conforming to the surface of a substrate selected from the group consisting of silicon, magnesium oxide, yttrium-stabilized zirconium oxide, sapphire, or lanthanum gallate, said multicomponent metal oxide film characterized as having a substantially uniform thickness upon said substrate, and as having a crystalline orientation defined as predominantly C-axis oriented by x-ray diffraction is disclosed.

Ott, K.C.; Kodas, T.T.

1990-04-16T23:59:59.000Z

252

Development of FeNiMoB thin film materials for microfabricated magnetoelastic sensors  

Science Conference Proceedings (OSTI)

Metglas{sup TM} 2826MB foils of 25-30 {mu}m thickness with the composition of Fe{sub 40}Ni{sub 38}Mo{sub 4}B{sub 18} have been used for magnetoelastic sensors in various applications over many years. This work is directed at the investigation of {approx}3 {mu}m thick iron-nickel-molybdenum-boron (FeNiMoB) thin films that are intended for integrated microsystems. The films are deposited on Si substrate by co-sputtering of iron-nickel (FeNi), molybdenum (Mo), and boron (B) targets. The results show that dopants of Mo and B can significantly change the microstructure and magnetic properties of FeNi materials. When FeNi is doped with only Mo its crystal structure changes from polycrystalline to amorphous with the increase of dopant concentration; the transition point is found at about 10 at. % of Mo content. A significant change in anisotropic magnetic properties of FeNi is also observed as the Mo dopant level increases. The coercivity of FeNi films doped with Mo decreases to a value less than one third of the value without dopant. Doping the FeNi with B together with Mo considerably decreases the value of coercivity and the out-of-plane magnetic anisotropy properties, and it also greatly changes the microstructure of the material. In addition, doping B to FeNiMo remarkably reduces the remanence of the material. The film material that is fabricated using an optimized process is magnetically as soft as amorphous Metglas{sup TM} 2826MB with a coercivity of less than 40 Am{sup -1}. The findings of this study provide us a better understanding of the effects of the compositions and microstructure of FeNiMoB thin film materials on their magnetic properties.

Liang Cai; Gooneratne, Chinthaka; Cha, Dongkyu; Chen Long; Kosel, Jurgen [Computer Electrical and Mathematical Sciences and Engineering, King Abdullah University of Science and Technology, 4700 KAUST, Thuwal 23955 (Saudi Arabia); Gianchandani, Yogesh [Department of Electrical Engineering and Computer Science, 1301 Beal Ave., University of Michigan, Ann Arbor, Michigan 48109 (United States)

2012-12-01T23:59:59.000Z

253

Process for CO.sub.2 capture using a regenerable magnesium hydroxide sorbent  

DOE Patents (OSTI)

A process for CO.sub.2 separation using a regenerable Mg(OH).sub.2 sorbent. The process absorbs CO.sub.2 through the formation of MgCO.sub.3 and releases water product H.sub.2O. The MgCO.sub.3 is partially regenerated through direct contact with steam, which acts to heat the magnesium carbonate to a higher temperature, provide heat duty required to decompose the magnesium carbonate to yield MgO and CO.sub.2, provide an H.sub.2O environment over the magnesium carbonate thereby shifting the equilibrium and increasing the potential for CO.sub.2 desorption, and supply H.sub.2O for rehydroxylation of a portion of the MgO. The mixture is polished in the absence of CO.sub.2 using water product H.sub.2O produced during the CO.sub.2 absorption to maintain sorbent capture capacity. The sorbent now comprised substantially of Mg(OH).sub.2 is then available for further CO.sub.2 absorption duty in a cyclic process.

Siriwardane, Ranjani V; Stevens, Jr., Robert W

2013-06-25T23:59:59.000Z

254

Propane ammoxidation over the Mo-V-Te-Nb-O M1 phase: Reactivity of surface cations in hydrogen abstraction steps  

Science Conference Proceedings (OSTI)

Density functional theory calculations (GGA-PBE) have been performed to investigate the adsorption of C3 (propane, isopropyl, propene, and allyl) and H species on the proposed active center present in the surface ab planes of the bulk Mo-V-Te-Nb-O M1 phase in order to better understand the roles of the different surface cations in propane ammoxidation. Modified cluster models were employed to isolate the closely spaced V=O and Te=O from each other and to vary the oxidation state of the V cation. While propane and propene adsorb with nearly zero adsorption energy, the isopropyl and allyl radicals bind strongly to V=O and Te=O with adsorption energies, {Delta}E, being {le} -1.75 eV, but appreciably more weakly on other sites, such as Mo=O, bridging oxygen (Mo-O-V and Mo-O-Mo), and empty metal apical sites ({Delta}E > -1 eV). Atomic H binds more strongly to Te = O ({Delta}E {le} -3 eV) than to all the other sites, including V = O ({Delta}E = -2.59 eV). The reduction of surface oxo groups by dissociated H and their removal as water are thermodynamically favorable except when both H atoms are bonded to the same Te=O. Consistent with the strong binding of H, Te=O is markedly more active at abstracting the methylene H from propane (E{sub a} {le} 1.01 eV) than V = O (E{sub a} = 1.70 eV on V{sup 5+} = O and 2.13 eV on V{sup 4+} = O). The higher-than-observed activity and the loose binding of Te = O moieties to the mixed metal oxide lattice of M1 raise the question of whether active Te = O groups are in fact present in the surface ab planes of the M1 phase under propane ammoxidation conditions.

Muthukumar, Kaliappan [University of Cincinnati; Yu, Junjun [University of Cincinnati; Xu, Ye [ORNL; Guliants, Vadim V. [University of Cincinnati

2011-01-01T23:59:59.000Z

255

Electrodeposition and characterization of nanocrystalline Ni-Mo catalysts for hydrogen production  

Science Conference Proceedings (OSTI)

Ni-Mo nanocrystalline deposits (7-43 nm) with a nodular morphology were prepared by electrodeposition using direct current from citrate-ammonia solutions. They exhibited a single Ni-Mo solid solution phase. The size of the nodules increased as electroplating ...

J. Halim; R. Abdel-Karim; S. El-Raghy; M. Nabil; A. Waheed

2012-01-01T23:59:59.000Z

256

Domestic production of medical isotope Mo-99 moves a step closer  

NLE Websites -- All DOE Office Websites (Extended Search)

Domestic production of medical isotope Mo-99 Domestic production of medical isotope Mo-99 Domestic production of medical isotope Mo-99 moves a step closer Irradiated uranium fuel has been recycled and reused for molybdenum-99 (Mo-99) production, with virtually no losses in Mo-99 yields or uranium recovery. May 13, 2013 From left, Los Alamos scientists Roy Copping, Sean Reilly, and Daniel Rios. Copping examines the Buchi Multivapor P-12 Evaporator, and Reilly and Rios are at the Agilent Technologies Cary 60 UV-Vis Spectrometer. From left, Los Alamos scientists Sean Reilly, Roy Copping, and Daniel Rios. Sean is looking at the Buchi Multivapor P-12 Evaporator, and Roy and Daniel are at the Agilent Technologies Cary 60 UV-Vis Spectrometer. Contact Nancy Ambrosiano Communications Office (505) 667-0471

257

Mo-containing tetrahedral amorphous carbon deposited by dual filtered cathodic vacuum arc with selective pulsed bias voltage  

E-Print Network (OSTI)

only. Fig.2 (a) Electrical resistivity of ta-C:Mo films as aC plasma pulses; (b) Electrical resistivity of the ta-C:MoIt found that the electrical resistivity decreases with an

Pasaja, Nitisak; Sansongsiri, Sakon; Anders, Andre; Vilaithong, Thiraphat; Intasiri, Sawate

2006-01-01T23:59:59.000Z

258

Structural evolution in crystalline MoO{sub 3} nanoparticles with tunable size  

SciTech Connect

In this study MoO{sub 3} nanoparticles were prepared in porous Vycor glass by impregnation-decomposition cycles (IDC) with molybdenum(VI) 2-ethylhexanoate. X-ray diffraction data show that the nanoparticles are crystalline and are in the orthorhombic {alpha}-MoO{sub 3} phase. Raman spectroscopy data also indicate the formation of this phase. The profiles in the Raman spectra changed with the number of IDC, indicating a structural evolution of the MoO{sub 3} nanoparticles. The IDC methodology promoted a linear mass increase and allowed tuning the nanoparticle size. Analysis of HRTEM images revealed that for 3, 5 and 7 IDC, the MoO{sub 3} nanoparticle average diameters are 3.2, 3.6 and 4.2 nm. Diffuse reflectance spectroscopy indicates a consistent red shift in the band gap from 3.35 to 3.29 eV as the size increases from 3.2 to 4.2 nm. This observed red shift in the band gap of the MoO{sub 3} nanoparticles is presumably due to quantum confinement effects. - Graphical abstract: Modification of profile Raman spectra for crystalline MoO{sub 3} nanoparticles in function of the particle size. Highlights: Black-Right-Pointing-Pointer Structural evolution of the MoO{sub 3} nanoparticles as a function of the crystallite size. Black-Right-Pointing-Pointer Tunable optical properties by controlling the MoO{sub 3} nanoparticle size. Black-Right-Pointing-Pointer The impregnation-decomposition methodology allowed tuning the nanoparticle size. Black-Right-Pointing-Pointer The red shift in the band gap of the MoO{sub 3} nanoparticles is due to quantum size effect. Black-Right-Pointing-Pointer The short-distance order in MoO{sub 3} nanoparticle is function to area/volume ratio.

Barros Santos, Elias de; Aparecido Sigoli, Fernando [Functional Materials Laboratory, Institute of Chemistry, University of Campinas, UNICAMP, PO Box 6154, Zip Code 13083-970 Campinas, SP (Brazil); Odone Mazali, Italo, E-mail: mazali@iqm.unicamp.br [Functional Materials Laboratory, Institute of Chemistry, University of Campinas, UNICAMP, PO Box 6154, Zip Code 13083-970 Campinas, SP (Brazil)

2012-06-15T23:59:59.000Z

259

Mo-99/Tc-99m Separation: An Assessment of Technical Options  

Science Conference Proceedings (OSTI)

Several strategies for the effective separation of 99mTc from 99Mo have been developed and validated. Due to the success of column chromatographic separation using acidic alumina coupled with high specific activity fission 99Mo (F 99Mo) for production of 99Mo/99mTc generators, however, most technologies until recently have generated little interest. The reduced availability of F 99Mo and consequently the shortage of 99Mo/99mTc column generators in the recent past have resurrected interest in the production of 99Mo as well as 99mTc by alternate routes. Most of these alternative production processes require separation techniques capable of providing clinical grade 99mTc from low specific activity 99Mo or irradiated Mo targets. For this reason there has been renewed interest in alternate separation routes. This paper reviews the reported separation technologies which include column chromatography, solvent extraction, sublimation and gel systems that have been traditionally used for the fabrication of 99Mo/99mTc generator systems. The comparative advantage, disadvantage, and technical challenges toward adapting the emerging requirements are discussed. New developments such as solid-phase column extraction, electrochemical separation, extraction chromatography, supported liquid membrane (SLM) and thermochromatographic techniques are also being evaluated for their potential application in the changed scenario of providing 99mTc from alternate routes. Based on the analysis provided in this review, it appears that some proven separation technologies can be quickly resurrected for the separation of clinical grade 99mTc from macroscopic levels of reactor or cyclotron irradiated molybdenum targets. Furthermore, emerging technologies can be developed further to respond to the expected changing modes of 99mTc production.

Dash, A [Bhabha Atomic Research Centre, Mumbai, India; Pillai, M R A [Bhabha Atomic Research Centre, Mumbai, India; Knapp Jr, Russ F [ORNL

2013-01-01T23:59:59.000Z

260

Microstructures and oxidation behavior of some Molybdenum based alloys  

Science Conference Proceedings (OSTI)

The advent of Ni based superalloys revolutionized the high temperature alloy industry. These materials are capable of operating in extremely harsh environments, comprising of temperatures around 1050 C, under oxidative conditions. Demands for increased fuel efficiency, however, has highlighted the need for materials that can be used under oxidative conditions at temperatures in excess of 1200 C. The Ni based superalloys are restricted to lower temperatures due to the presence of a number of low melting phases that melt in the 1250 - 1450 C, resulting in softening of the alloys above 1000 C. Therefore, recent research directions have been skewed towards exploring and developing newer alloy systems. This thesis comprises a part of such an effort. Techniques for rapid thermodynamic assessments were developed and applied to two different systems - Mo-Si alloys with transition metal substitutions (and this forms the first part of the thesis) and Ni-Al alloys with added components for providing high temperature strength and ductility. A hierarchical approach towards alloy design indicated the Mo-Ni-Al system as a prospective candidate for high temperature applications. Investigations on microstructures and oxidation behavior, under both isothermal and cyclic conditions, of these alloys constitute the second part of this thesis. It was seen that refractory metal systems show a marked microstructure dependence of oxidation.

Ray, Pratik Kumar

2010-12-15T23:59:59.000Z

Note: This page contains sample records for the topic "mo magnesium oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Surface Structures of Cubo-octahedral Pt-Mo Catalyst Nanoparticles from Monte Carlo Simulations  

DOE Green Energy (OSTI)

The surface structures of cubo-octahedral Pt-Mo nanoparticles have been investigated using the Monte Carlo method and modified embedded atom method potentials that we developed for Pt-Mo alloys. The cubo-octahedral Pt-Mo nanoparticles are constructed with disordered fcc configurations, with sizes from 2.5 to 5.0 nm, and with Pt concentrations from 60 to 90 at. percent. The equilibrium Pt-Mo nanoparticle configurations were generated through Monte Carlo simulations allowing both atomic displacements and element exchanges at 600 K. We predict that the Pt atoms weakly segregate to the surfaces of such nanoparticles. The Pt concentrations in the surface are calculated to be 5 to 14 at. percent higher than the Pt concentrations of the nanoparticles. Moreover, the Pt atoms preferentially segregate to the facet sites of the surface, while the Pt and Mo atoms tend to alternate along the edges and vertices of these nanoparticles. We found that decreasing the size or increasing the Pt concentration leads to higher Pt concentrations but fewer Pt-Mo pairs in the Pt-Mo nanoparticle surfaces.

Wang, Guofeng; Van Hove, M.A.; Ross, P.N.; Baskes, M.I.

2005-03-31T23:59:59.000Z

262

Systematics of magnetic dipole strength in the stable even-mass Mo isotopes  

SciTech Connect

The nuclides {sup 92}Mo, {sup 98}Mo, and {sup 100}Mo have been studied in photon-scattering experiments by using bremsstrahlung produced at an electron energy of 6 MeV at the ELBE accelerator of the Forschungszentrum Rossendorf and at electron energies from 3.2 to 3.8 MeV at the Dynamitron accelerator at the University of Stuttgart. Six dipole transitions in {sup 98}Mo and 19 in {sup 100}Mo were observed for the first time in the energy range from 2 to 4 MeV. The experimental results are compared with predictions of the shell model and with predictions of the quasiparticle random-phase approximation (QRPA) in a deformed basis. The latter show significant contributions of isovector-orbital and isovector-spin vibrations. The change of the magnetic dipole strength in the isotopic chain of the even-mass isotopes from {sup 92}Mo to {sup 100}Mo is discussed. The calculations within the QRPA are extrapolated to the particle-separation energies to estimate the possible influence of M1 strength on the stability of the nuclides against photodissociation in cosmic scenarios.

Rusev, G. [Institut fuer Kern- und Hadronenphysik, Forschungszentrum Rossendorf, D-01314 Dresden (Germany); Institute for Nuclear Research and Nuclear Energy, BAS, BG-1784 Sofia (Bulgaria); Schwengner, R.; Doenau, F.; Erhard, M.; Grosse, E.; Junghans, A.R.; Kaeubler, L.; Kosev, K.; Mallion, S.; Schilling, K.D.; Wagner, A. [Institut fuer Kern- und Hadronenphysik, Forschungszentrum Rossendorf, D-01314 Dresden (Germany); Frauendorf, S. [Institut fuer Kern- und Hadronenphysik, Forschungszentrum Rossendorf, D-01314 Dresden (Germany); Department of Physics, University of Notre Dame, Notre Dame, Indiana 46556 (United States); Kostov, L.K. [Institute for Nuclear Research and Nuclear Energy, BAS, BG-1784 Sofia (Bulgaria); Garrel, H. von; Kneissl, U.; Kohstall, C.; Kreutz, M.; Pitz, H.H.; Scheck, M.; Stedile, F. [Institut fuer Strahlenphysik, Universitaet Stuttgart, D-70569 Stuttgart (Germany)] (and others)

2006-04-15T23:59:59.000Z

263

Tribology and Tool Wear of Hot Dip Galvanized Zinc Magnesium Alloys on Cold Rolled Steel Sheets  

SciTech Connect

Recently zinc based coatings on cold rolled steel with improved functionality in terms of forming and/or corrosion behaviour have been intensively investigated in the steel industry. One of the most promising products are zinc magnesium alloys produced in hot dip galvanizing process. These coatings were already introduced in construction industry a few years ago. With some modifications the improved properties of the coating are also interesting for automotive industry. In the present work the tribological potential of hot dip galvanized zinc magnesium coatings (HDG/ZM) produced at an industrial line under regular production, was studied in terms of sliding properties, adhesive and abrasive tool wear.First a short introduction into surface morphology of HDG/ZM will be given. For the tribological characterization of the material, which is the main topic of the contribution, different tests were performed on hot dip galvanised zinc magnesium material and results were compared with classic hot dip galvanized zinc coating (HDG/Z). The investigations are mainly based on the strip draw test which allows the determination of the friction coefficient directly by using a constant contact pressure. Deep drawing property was tested by forming model cups. The abrasive tool wear was tested using a standard test for material used in automotive industry. The adhesive tool wear was investigated by characterizing the coating material transferred to the tool in the strip draw test.All performed tests show an improved drawability of HDG/ZM compared to classical HDG/Z reference material. However the most promising difference between HDG/ZM and HDG/Z is that galling was found to be less for HDG/ZM than for HDG/Z. Therefore HDG/ZM is an interesting system not only with respect to corrosion protection but also in terms of tribology and provides clear advantages in formability.

Raab, A. E.; Berger, E.; Freudenthaler, J.; Leomann, F.; Walch, C. [Research and Development, Forming Technology voestalpine Stahl GmbH, Voest-Alpine Strasse 3, 4031 Linz (Austria)

2011-05-04T23:59:59.000Z

264

Reactor physics calculations for {sup 99}Mo production at the Annular Core Research Reactor  

SciTech Connect

The isotope {sup 99}Mo would be produced at Sandia using ACRR and the collocated Hot Cell Facility. {sup 99}Mo would be produced by irradiating targets coated with {sup 235}U in the form of highly enriched U{sub 3}O{sub 8}; after 7 days, the target would be removed and the isotope extracted using the Cintichem process. The Monte Carlo neutronics computer code MCNP was used to determine the optimum configuration for production, using various fractions of the US demand. Although ACRR operates at a low power level, the US demand for {sup 99}Mo can be easily met using a reasonable number of targets.

Parma, E.J.

1995-07-01T23:59:59.000Z

265

Local and average structures of the spin-glass pyrochlore Y2Mo2O7 from neutron diffraction and neutron pair distribution function analysis  

Science Conference Proceedings (OSTI)

The observation of canonical spin-glass behavior in the pyrochlore oxide Y{sub 2}Mo{sub 2}O{sub 7} has been a subject of considerable interest as the original structural studies were interpreted in terms of a well-ordered crystallographic model. It is widely held that the stabilization of the spin-glass state requires some level of positional disorder along with frustration. Recent reports from local probe measurements, extended x-ray-absorption fine structure (EXAFS) and {sup 89}Y NMR, have been interpreted in terms of disorder involving the Mo-Mo distances (EXAFS) and multiple Y sites (NMR). This work reports results from temperature-dependent (15--300 K) neutron diffraction (ND) and neutron pair distribution function studies which can provide from the same data set information on both the average and local structures. The principal findings are that: (1) there is no crystallographic phase transition over the temperature region studied within the resolution of the ND data; (2) the diffraction data are well fitted using a fully ordered model but with large and anisotropic displacement parameters for three of the four atomic sites; (3) the pairwise real-space correlation function G(r) shows clear evidence that the principal source of disorder is associated with the Y-O1 atom pairs rather than the Mo-Mo pairs, in disagreement with the interpretation of the EXAFS results; (4) fits to the G(r) improve significantly when anisotropic displacements for all sites are included; (5) inclusion of a split-site position parameter for O1 improves, slightly, both the G(r) fits and the Rietveld fits to the ND data; and (6) for all models the fits become worse as the temperature decreases and as the fitting range decreases. These results are qualitatively consistent with the {sup 89}Y NMR observations and perhaps recent muon-spin-relaxation studies. The issue of static versus dynamic disorder is not resolved, definitively. An estimate of the distribution of exchange constants due to the disorder is made using spin-dimer analysis and compared with the Saunders-Chalker model for the generation of spin-glass behavior from 'weak' disorder on geometrically frustrated lattices.

Proffen, Thomas Ernst [Los Alamos National Laboratory; Kim, Hyunjeong [Los Alamos National Laboratory; Greedan, John [MCMASTER UNIV; Gout, Delphine [ORNL; Lozano - Gorrin, A D [MCMASTER UNIV; Derahkshan, Shahab [MCMASTER UNIV; Bozin, E [COLUMBIA UNIV; Billinge, S J L [COLUMBIA UNIV

2009-01-01T23:59:59.000Z

266

Synthesis and characterization of AlPO{sub 4}-36 and MAPO-36 with different magnesium content  

Science Conference Proceedings (OSTI)

The objective of this work was to perform a systematic study regarding the effect of different synthesis parameters on the crystallization of AlPO{sub 4}-36 and MAPO-36 (aluminophosphate molecular sieve type 36, ATS, structure). MAPO-36 samples were synthesized from gels containing different magnesium contents in order to obtain catalysts with different degrees of acidity. Under the synthesis conditions employed in this work, the formation of AlPO{sub 4}-36 and MAPO-36 increased when the reaction mixture was aged at room temperature; however, small amounts of AlPO{sub 4}-5 always crystallize parallel to the ATS materials. The presence of magnesium in the reaction mixture can also favor the formation of the ATS structure; nevertheless, the synthesis of pure MAPO-36 from reaction mixtures having very low magnesium content was not possible under several conditions. Pseudoboehmite was a better aluminum source than aluminum isopropoxide for the formation of MAPO-36. A practically pure ATS structure was obtained from reaction mixtures containing molar fractions of Mg between 0.033 and 0.133. For higher magnesium contents, traces of another unidentified phase were detected. Energy-dispersive spectrometry analysis indicates a uniform chemical composition of the MAPO-36 particles, and Scanning electron microscopy shows that the ATS samples have a needlelike morphology. Thermogravimetric analysis of ATS samples reveals that the weight loss corresponding to the decomposition of protonated amine is linearly correlated with magnesium content in the solid up to 0.8 mmol of magnesium per gram of solid.

Machado, M.S.; Cardoso, D.; Perez-Pariente, J.; Sastre, E.

1999-11-01T23:59:59.000Z

267

PROCESSING OF HIGH-FIRED URANIUM DIOXIDE FUELS BY A REDUCTION-MERCURY EXTRACTION-OXIDATION PROCESS  

DOE Green Energy (OSTI)

A preliminary flowsheet for the purification of uranium dioxide fuels by a magnesium reduction-- mercury extraction-- steam oxidation process is proposed. Feasibility was indicated by laboratory-scale scouting experiments. Data evaluation indicated 100% reduction of uranium dioxide by magnesium although this figure was not demonstrated, chiefly because of poor choice of materials and design of equipment. Steam oxidation of uranlum tetramercuride produced an oxide with an O/U ratio of 2.43. This ratio was decreased to 2.09 by heating the oxide in a hydrogen atmosphere at 900 deg C for 1 hr. The final product had a surface area of 3.5 m/sup 2//g, and 18% of the panticles were < 1 mu diam. A pellet of the oxide sintered at 1750 deg C had a density of 9.76 g/cc, 89% of theoretical. Decontamination factors demonstrated for ruthenium, cesium, and samarium, when present originally in amounts equivalent to 30,000 Mwd/ton fuel burnup and 60 days' decay, were

Messing, A. F.; Dean, O. C.

1960-08-12T23:59:59.000Z

268

Lithium Metal Oxide Electrodes For Lithium Cells And Batteries  

DOE Patents (OSTI)

A lithium metal oxide positive electrode for a non-aqueous lithium cell is disclosed. The cell is prepared in its initial discharged state and has a general formula xLiMO.sub.2.(1-x)Li.sub.2 M'O.sub.3 in which 0oxidation state and with at least one ion being Mn or Ni, and where M' is one or more ion with an average tetravalent oxidation state. Complete cells or batteries are disclosed with anode, cathode and electrolyte as are batteries of several cells connected in parallel or series or both.

Thackeray, Michael M. (Naperville, IL); Johnson, Christopher S. (Naperville, IL); Amine, Khalil (Downers Grove, IL); Kim, Jaekook (Naperville, IL)

2004-01-20T23:59:59.000Z

269

Lithium metal oxide electrodes for lithium cells and batteries  

DOE Patents (OSTI)

A lithium metal oxide positive electrode for a non-aqueous lithium cell is disclosed. The cell is prepared in its initial discharged state and has a general formula xLiMO.sub.2.(1-x)Li.sub.2M'O.sub.3 in which 0oxidation state and with at least one ion being Mn or Ni, and where M' is one or more ion with an average tetravalent oxidation state. Complete cells or batteries are disclosed with anode, cathode and electrolyte as are batteries of several cells connected in parallel or series or both.

Thackeray, Michael M. (Naperville, IL); Johnson, Christopher S. (Naperville, IL); Amine, Khalil (Oakbrook, IL)

2008-12-23T23:59:59.000Z

270

Forming 6061 Al HIP-Clad DU10Mo Monolithic Fuel Plates  

Science Conference Proceedings (OSTI)

Small scale trials with multi-layer 6061 Al HIP-clad DU10Mo (depleted uranium), co-rolled with Zr, have been performed. Important results include springback ...

271

NTT DoCoMo's competition strategy (before and) after the introduction of the flat rate  

E-Print Network (OSTI)

NTT DoCoMo, which was spun off from NTT in 1992, grew rapidly by increasing the number of subscribers and successfully implementing a new data communication, i-mode. However, when a competitor introduced a flat rate for ...

Yajima, Masaaki

2008-01-01T23:59:59.000Z

272

Solution-reactor-produced Mo-99 using activated carbon to remore I-131  

SciTech Connect

The production of {sup 99}Mo in a solution reactor was explored. Activated charcoal was used to filter the {sup 131}I contaminant from an irradiated fuel solution. Gamma spectroscopy confirmed that the activated carbon trapped a significant amount of {sup 131}I, as well as notable amounts of {sup 133}Xe, {sup 105}Rb, and {sup 140}Ba; the carbon trapped a diminutive amount of {sup 99}Mo. The results promote the idea of solution-reactor-produced {sup 99}Mo. Solution reactors are favorable both energetically and environmentally. A solution reactor could provide enough {sup 99}Mo/{sup 99m}Te to support both the current and future radiopharmaceutical needs of the U.S.

Kitten, S.; Cappiello, C.

1998-06-01T23:59:59.000Z

273

The Thermodynamics of Titanium Formation in 95CrMo Steel  

Science Conference Proceedings (OSTI)

... on the fatigue life of 95CrMo steel which was applied in producing drilling rod. ... Analysis of Residence Time Distribution (RTD) of Fluid Flows in a Four Strand  ...

274

Production of Mixed Alcohols from Bio-syngas over Mo-based Catalyst  

Science Conference Proceedings (OSTI)

A series of Mo-based catalysts prepared by sol-gel method using citric acid as complexant were successfully applied in the high efficient production of mixed alcohols from bio-syngas

Song-bai Qiu; Wei-wei Huang; Yong Xu; Lu Liu; Quan-xin Li

2011-01-01T23:59:59.000Z

275

Friction Stir Lap Welding of Magnesium Alloy to Steel: A Preliminary Investigation  

Science Conference Proceedings (OSTI)

An initial study was made to evaluate the feasibility of joining Magnesium alloy AZ31 sheet to galvanized steel sheet in lap configuration using friction stir welding (FSW). Two different automotive sheet steels were used for comparative evaluation of the dissimilar joining potential; a 0.8mm thick, electro galvanized (EG) mild steel, and a 1.5mm thick hot dipped galvanized (HDG) high-strength, low-alloy steel (HSLA). These steels were joined to 2.33mm thick AZ31B magnesium sheet. A single FSW tool design was used for both dissimilar welds, and process parameters were kept the same. Average peak load for the AZ31-1.5 mm steel weld joint in lap shear mode was found to be 6.3 ± 1.0 kN. For the AZ31-0.8 mm steel weld, joint strength was 5.1 ± 1.5 kN. Microstructural investigation indicates melting of the Zn coating at the interface and subsequent alloying with the Mg sheet resulting in formation of solidified Zn-Mg alloy layer at AZ31/steel interface.

Jana, Saumyadeep; Hovanski, Yuri; Grant, Glenn J.

2010-12-01T23:59:59.000Z

276

U-EXTRACTION--IMPROVEMENTS IN ELIMINATION OF Mo BY USE OF FERRIC ION  

DOE Patents (OSTI)

An improved solvent extraction process is described whereby U may be extracted by a water immiscible organic solvent from an aqueous solution of uranyl nitrate. It has been found that Mo in the presence of phosphate ions appears to form a complex with the phosphate which extracts along with the U. This extraction of Mo may be suppressed by providing ferric ion in the solution prior to the extraction step. The ferric ion is preferably provided in the form of ferric nitrate.

Clark, H.M.; Duffey, D.

1958-06-10T23:59:59.000Z

277

Photoluminescent BaMoO{sub 4} nanopowders prepared by complex polymerization method (CPM)  

SciTech Connect

The BaMoO{sub 4} nanopowders were prepared by the Complex Polymerization Method (CPM). The structure properties of the BaMoO{sub 4} powders were characterized by FTIR transmittance spectra, X-ray diffraction (XRD), Raman spectra, photoluminescence spectra (PL) and high-resolution scanning electron microscopy (HR-SEM). The XRD, FTIR and Raman data showed that BaMoO{sub 4} at 300 deg. C was disordered. At 400 deg. C and higher temperature, BaMoO{sub 4} crystalline scheelite-type phases could be identified, without the presence of additional phases, according to the XRD, FTIR and Raman data. The calculated average crystallite sizes, calculated by XRD, around 40 nm, showed the tendency to increase with the temperature. The crystallite sizes, obtained by HR-SEM, were around of 40-50 nm. The sample that presented the highest intensity of the red emission band was the one heat treated at 400 deg. C for 2 h, and the sample that displayed the highest intensity of the green emission band was the one heat treated at 700 deg. C for 2 h. The CPM was shown to be a low cost route for the production of BaMoO{sub 4} nanopowders, with the advantages of lower temperature, smaller time and reduced cost. The optical properties observed for BaMoO{sub 4} nanopowders suggested that this material is a highly promising candidate for photoluminescent applications.

Azevedo Marques, Ana Paula de [Laboratorio de Analise Termica e Materiais, Departamento de Quimica, Universidade Federal do Rio Grande do Norte, 59072-970 Natal, RN (Brazil)]. E-mail: apamarques@liec.ufscar.br; Melo, Dulce M.A. de [Laboratorio de Analise Termica e Materiais, Departamento de Quimica, Universidade Federal do Rio Grande do Norte, 59072-970 Natal, RN (Brazil); Paskocimas, Carlos A. [Departamento de Engenharia Mecanica, Universidade Federal do Rio Grande do Norte, 59072-970 Natal, RN (Brazil); Pizani, Paulo S. [Laboratorio de Semicondutores, Departamento de Fisica, Universidade Federal de Sao Carlos, 13565-905 Sao Carlos, SP (Brazil); Joya, Miryam R. [Laboratorio de Semicondutores, Departamento de Fisica, Universidade Federal de Sao Carlos, 13565-905 Sao Carlos, SP (Brazil); Leite, Edson R. [Laboratorio Interdisciplinar de Eletroquimica e Ceramica, CMDMC, Departamento de Quimica, Universidade Federal de Sao Carlos 13565-905, Sao Carlos, SP (Brazil); Longo, Elson [CMDMC, LIEC, Instituto de Quimica, Universidade Estadual Paulista, 14801-907 Araraquara, SP (Brazil)

2006-03-15T23:59:59.000Z

278

Solution-reactor-produced-{sup 99}Mo using activated carbon to remove {sup 131}I  

SciTech Connect

This research explores the idea of producing {sup 99}Mo in a solution reactor. The Solution High Energy Burst Assembly (SHEBA), located at the Los Alamos Critical Assembly Facility, was used to facilitate this study. The goal of this study was to build on work previously completed and to investigate a possible mode of radioactive contaminant removal prior to a {sup 99}Mo extraction process. Prior experiments, performed using SHEBA and a single-step sorption process, showed a significant amount of {sup 131}I present along with the {sup 99}Mo on the alumina that was used to isolate the {sup 99}Mo. A high concentration of {sup 131}I and/or other contaminants present in a sample prohibits the Food and Drug Administration from approving an extraction of that nature for radiopharmaceutical use. However, if it were possible to remove the {sup 131}I and other contaminants prior to a {sup 99}Mo extraction, a simple column extraction process might be feasible. Activated charcoal was used to try to filter the {sup 131}I contaminant from an irradiated fuel solution. Gamma spectroscopy confirmed that the activated carbon trapped a significant amount of the {sup 131}I, as well as notable amounts of {sup 133}Xe, {sup 105}Rb, and {sup 140}Ba. Most importantly, the carbon traps a diminutive amount of {sup 99}Mo.

Kitten, S.; Cappiello, C. [Los Alamos National Lab., NM (United States)

1998-09-01T23:59:59.000Z

279

Lipid Oxidation Pathways  

Science Conference Proceedings (OSTI)

This book reviews state-of-the-art developments in the understanding of the oxidation of lipids and its connection with the oxidation of other biological molecules such as proteins and starch. Lipid Oxidation Pathways Hardback Books Health - Nutrition -

280

Selective methane oxidation over promoted oxide catalysts  

DOE Green Energy (OSTI)

Objective was to selectively oxidize methane to C{sub 2} hydrocarbons and to oxygenates, in particular formaldehyde and methanol, in high space time yields under relatively mild reaction conditions. Results in this document are reported under the headings: methane oxidation over silica, methane oxidation over Sr/La{sub 2}O{sub 3} catalysts, and oxidative coupling of methane over sulfate-doped Sr/La{sub 2}O{sub 3} catalysts. 24 refs, 10 figs, 4 tabs.

Klier, K.; Herman, R.G.

1993-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "mo magnesium oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Substrate recovery of Mo-Si multilayer coated optics  

Science Conference Proceedings (OSTI)

Imaging optics in a soft x-ray projection lithography (SXPL) system must meet stringent requirements to achieve high throughput and diffraction limited performance. Errors in the surface figure must be kept to less than {approximately}1 nm and the rms surface roughness must be less than 0.1 nm. The ML coatings must provide high reflectivity (> 60%) at wavelengths in the vicinity of 13 nm. The reflectivity bandpasses of the optics must be aligned within 0.05 nm. Each coating must be uniform across the surface of the optic to within 0.5%. These specifications challenge the limits of the current capabilities in optics fabrication and ML deposition. Consequently a set of qualified SXPL imaging optics is expected to be expensive, costing in the range of 100--250 k$. If the lifetime of the imaging optics is short, the replacement cost could significantly impact the economic competitiveness of the technology. The most likely failure modes for the imaging optics are mechanisms that degrade the ML coatings, but which leave the substrates intact. A potentially low cost solution for salvaging the imaging optics could be to strip the damaged ML coating to recover the substrate and then deposit a new coating. In this paper the authors report on the use of reactive ion etching (RIE) to remove Mo-Si ML coatings from precision optical substrates. The goal of this work was to characterize the etching process both in the ML film and at the substrate, and to determine the effects of the etching on the surface figure and finish of the substrate.

Stearns, D.G.; Baker, S.L.

1993-06-01T23:59:59.000Z

282

Density Functional Theory Simulations Predict New Materials for Magnesium-Ion Batteries (Fact Sheet), NREL Highlights, Science  

SciTech Connect

Multivalence is identified in the light element, B, through structure morphology. Boron sheets exhibit highly versatile valence, and the layered boron materials may hold the promise of a high-energy-density magnesium-ion battery. Practically, boron is superior to previously known multivalence materials, especially transition metal compounds, which are heavy, expensive, and often not benign. Based on density functional theory simulations, researchers at the National Renewable Energy Laboratory (NREL) have predicted a series of stable magnesium borides, MgB{sub x}, with a broad range of stoichiometries, 2 < x < 16, by removing magnesium atoms from MgB{sub 2}. The layered boron structures are preserved through an in-plane topological transformation between the hexagonal lattice domains and the triangular domains. The process can be reversibly switched as the charge transfer changes with Mg insertion/extraction. The mechanism of such a charge-driven transformation originates from the versatile valence state of boron in its planar form. The discovery of these new physical phenomena suggests the design of a high-capacity magnesium-boron battery with theoretical energy density 876 mAh/g and 1550 Wh/L.

2011-10-01T23:59:59.000Z

283

Lithium metal oxide electrodes for lithium cells and batteries  

DOE Patents (OSTI)

A lithium metal oxide positive electrode for a non-aqueous lithium cell is disclosed. The cell is prepared in its initial discharged state and has a general formula xLiMO.sub.2.(1-x)Li.sub.2 M'O.sub.3 in which 0

Thackeray, Michael M. (Naperville, IL); Johnson, Christopher S. (Naperville, IL); Amine, Khalil (Downers Grove, IL); Kim, Jaekook (Naperville, IL)

2004-01-13T23:59:59.000Z

284

Magnesium (Mg)  

Science Conference Proceedings (OSTI)

...J.L. Bernard, R. Caillat, and R. Darras, Progress in Nuclear Energy, Metallurgy and Fuels, Vol 2, Pergamon

285

MCNPX-CINDER'90 Simulation of Photonuclear Mo-99 Production Experiments  

SciTech Connect

The MCNPX and CINDER'90 codes were used to support design of experiments investigating Mo-99 production with a 20-MeV electron beam. Bremsstrahlung photons produced by the electron beam interacting with the target drive the desired Mo-100({gamma},n)Mo-99 reaction, as well as many undesired reactions important to accurate prediction of radiation hazards. MCNPX is a radiation transport code and CINDER'90 is a transmutation code. They are routinely used together for accelerator activation calculations. Low energy neutron fluxes and production rates for nonneutron and high energy neutron induced reactions computed using MCNPX are inputs to CINDER'90. CINDER'90 presently has only a neutron reaction cross section library up to 25 MeV and normally the other reaction rates come from MCNPX physics models. For this work MCNPX photon flux tallies modified by energy response functions prepared from evaluated photonuclear cross section data were used to tally the reaction rates for CINDER'90 input. The cross section evaluations do not provide isomer to ground state yield ratios so a spin based approximation was used. Post irradiation dose rates were calculated using MCNPX with CINDER'90 produced decay photon spectra. The sensitivity of radionuclide activities and dose rates to beam parameters including energy, position, and profile, as well as underlying isomer assumptions, was investigated. Three experimental production targets were irradiated, two natural Mo and one Mo-100 enriched. Natural Mo foils upstream of the targets were used to analyze beam position and profile by exposing Gafchromic film to the foils after each irradiation. Activation and dose rate calculations were rerun after the experiments using measured beam parameters for comparison with measured Mo-99 activities and dose rates.

Kelsey, Charles T. IV [Los Alamos National Laboratory; Chemerizov, Sergey D. [Argonne National Laboratory; Dale, Gregory E. [Los Alamos National Laboratory; Harvey, James T. [NorthStar Medical Radioisotopes; Tkac, Peter [Argonne National Laboratory; Vandegrift, George R III [Argonne National Laboratory

2011-01-01T23:59:59.000Z

286

Overview of DOE'S programs on aluminum and magnesium for automotive application  

DOE Green Energy (OSTI)

The U.S. Department of Energy will present an update and review of its programs in aluminum and magnesium for automotive and heavy-duty vehicle applications. While the main programs focused on vehicle materials are in the Office of Transportation Technologies, contributing efforts will be described in the DOE Office of Industrial Technologies and the DOE Office of Energy Research. The presentation will discuss materials for body/chassis and power train, and will highlight the considerable synergy among the efforts. The bulk of the effort is on castings, sheet, and alloys with a smaller focus on metal matrix composites. Cost reduction and energy savings are the overriding themes of the programs.

Carpenter, J.; Diamond, S.; Dillich, S.; Fitzsimmons, T.; Milliken, J.; Sklad, P.

1999-02-28T23:59:59.000Z

287

Elastic Properties and Internal Friction of Two Magnesium Alloys at Elevated Temperatures  

SciTech Connect

The elastic properties and internal friction of two magnesium alloys were studied from 25 C to 450 C using Resonant Ultrasound Spectroscopy (RUS). The Young's moduli decrease with increasing temperature. At 200 C, a change in the temperature dependence of the elastic constants is observed. The internal friction increases significantly with increasing temperature above 200 C. The observed changes in the temperature dependence of the elastic constants and the internal friction are the result of anelastic relaxation by grain boundary sliding at elevated temperatures. Elastic properties govern the behavior of a materials subjected to stress over a region of strain where the material behaves elastically. The elastic properties, including the Young's modulus (E), shear modulus (G), bulk modulus (B), and Poisson's ratio (?), are of significant interest to many design and engineering applications. The choice of the most appropriate material for a particular application at elevated temperatures therefore requires knowledge of its elastic properties as a function of temperature. In addition, mechanical vibration can cause significant damage in the automotive, aerospace, and architectural industries and thus, the ability of a material to dissipate elastic strain energy in materials, known as damping or internal friction, is also important property. Internal friction can be the result of a wide range of physical mechanisms, and depends on the material, temperature, and frequency of the loading. When utilized effectively in engineering applications, the damping capacity of a material can remove undesirable noise and vibration as heat to the surroundings. The elastic properties of materials can be determined by static or dynamic methods. Resonant Ultrasound Spectroscopy (RUS), used in this study, is a unique and sophisticated non-destructive dynamic technique for determining the complete elastic tensor of a solid by measuring the resonant spectrum of mechanical resonance for a sample of known geometry, dimensions, and mass. In addition, RUS allows determination of internal friction, or damping, at different frequencies and temperatures. Polycrystalline pure magnesium (Mg) exhibits excellent high damping properties. However, the poor mechanical properties limit the applications of pure Mg. Although alloying can improve the mechanical properties of Mg, the damping properties are reduced with additions of alloying elements. Therefore, it becomes necessary to study and develop Mg-alloys with simultaneous high damping capacity and improved mechanical properties. Moreover, studies involving the high temperature dynamic elastic properties of Mg alloys are limited. In this study, the elastic properties and internal friction of two magnesium alloys were studied at elevated temperatures using RUS. The effect of alloy composition and grain size was investigated. The wrought magnesium alloys AZ31 and ZK60 were employed. Table 1 gives the nominal chemical compositions of these two alloys. The ZK60 alloy is a commercial extruded plate with a T5 temper, i.e. solution-treated at 535 C for two hours, quenched in hot water, and aged at 185 C for 24 hours. The AZ31 alloy is a commercial rolled plate with a H24 temper, i.e. strain hardened and partially annealed.

Freels, M.; Liaw, P. K.; Garlea, E.; Morrell, J. S.; Radiovic, M.

2011-06-01T23:59:59.000Z

288

Analysis of the potential for new automotive uses of wrought magnesium  

DOE Green Energy (OSTI)

The Center for Transportation Research at Argonne National Laboratory has performed a study for the Lightweight Materials Program within the US Department of Energy`s Office of Transportation Materials to evaluate the suitability of wrought magnesium and its alloys to replace steel or aluminum for automotive structural and sheet applications. Vehicle weight reduction is one of the major means available for improving automotive fuel efficiency. Although high-strength steels, Al, and polymers are already being used to achieve significant weight reductions, substantial additional weight reductions could be achieved by increased use of Mg (whose density is less than one-fourth that of steel and only two-thirds that of Al). This study shows that Mg sheet could be used in automotive body nonstructural and semistructural applications, whereas extrusions could be used in such structural applications as spaceframes. The primary barrier to such uses of wrought Mg is high cost.

Gaines, L.; Cuenca, R.; Wu, S. [Argonne National Lab., IL (United States); Stodolsky, F. [Argonne National Lab., IL (United States)]|[Argonne National Lab., Washington, DC (United States)

1996-02-01T23:59:59.000Z

289

Multi-Objective Optimization of a Wrought Magnesium Alloy for High Strength and Ductility  

Science Conference Proceedings (OSTI)

An optimization technique is coupled with crystal plasticity based finite element (CPFE) computations to aid the microstructural design of a wrought magnesium alloy for improved strength and ductility. The initial microstructure consists of a collection of sub-micron sized grains containing deformation twins. The variables used in the simulations are crystallographic texture, and twin spacing within the grains. It is assumed that plastic deformation occurs mainly by dislocation slip on two sets of slip systems classified as hard and soft modes. The hard modes are those slip systems that are inclined to the twin planes and the soft mode consists of dislocation glide along the twin plane. The CPFE code calculates the stress-strain response of the microstructure as a function of the microstructural parameters and the length-scale of the features. A failure criterion based on a critical shear strain and a critical hydrostatic stress is used to define ductility. The optimization is based on the sequential generation of an initial population defined by the texture and twin spacing variables. The CPFE code and the optimizer are coupled in parallel so that new generations are created and analyzed dynamically. In each successive generation, microstructures that satisfy at least 90% of the mean strength and mean ductility in the current generation are retained. Multiple generation runs based on the above procedure are carried out in order to obtain maximum strength-ductility combinations. The implications of the computations for the design of a wrought magnesium alloy are discussed. Research sponsored by the Laboratory Directed Research and Development Program of Oak Ridge National Laboratory, managed by UT-Battelle, LLC, for the U. S. Department of Energy.

Radhakrishnan, Balasubramaniam [ORNL; Gorti, Sarma B [ORNL; Patton, Robert M [ORNL; Simunovic, Srdjan [ORNL

2013-01-01T23:59:59.000Z

290

Elementary Steps of Syngas Reactions on Mo2C(001): Adsorption Thermochemistry and Bond Dissociation  

SciTech Connect

Density functional theory (DFT) and ab initio thermodynamics are applied in order to investigate the most stable surface and subsurface terminations of Mo{sub 2}C(001) as a function of chemical potential and in the presence of syngas. The Mo-terminated (001) surface is then used as a model surface to evaluate the thermochemistry and energetic barriers for key elementary steps in syngas reactions. Adsorption energy scaling relations and Broensted-Evans-Polanyi relationships are established and used to place Mo{sub 2}C into the context of transition metal surfaces. The results indicate that the surface termination is a complex function of reaction conditions and kinetics. It is predicted that the surface will be covered by either C{sub 2}H{sub 2} or O depending on conditions. Comparisons to transition metals indicate that the Mo-terminated Mo{sub 2}C(001) surface exhibits carbon reactivity similar to transition metals such as Ru and Ir, but is significantly more reactive towards oxygen.

Medford, Andrew

2012-02-16T23:59:59.000Z

291

van der Waals Epitaxy of MoS2 Layers Using Graphene As Growth Templates  

SciTech Connect

We present a method for synthesizing MoS{sub 2}/Graphene hybrid heterostructures with a growth template of graphene-covered Cu foil. Compared to other recent reports, a much lower growth temperature of 400 C is required for this procedure. The chemical vapor deposition of MoS{sub 2} on the graphene surface gives rise to single crystalline hexagonal flakes with a typical lateral size ranging from several hundred nanometers to several micrometers. The precursor (ammonium thiomolybdate) together with solvent was transported to graphene surface by a carrier gas at room temperature, which was then followed by post annealing. At an elevated temperature, the precursor self-assembles to form MoS{sub 2} flakes epitaxially on the graphene surface via thermal decomposition. With higher amount of precursor delivered onto the graphene surface, a continuous MoS{sub 2} film on graphene can be obtained. This simple chemical vapor deposition method provides a unique approach for the synthesis of graphene heterostructures and surface functionalization of graphene. The synthesized two-dimensional MoS{sub 2}/Graphene hybrids possess great potential toward the development of new optical and electronic devices as well as a wide variety of newly synthesizable compounds for catalysts.

Shi, Yumeng [Massachusetts Institute of Technology (MIT); Zhou, Wu [Vanderbilt University; Lu, Ang-Yu [Academia Sinica, Hefei, China; Fang, Wenjing [Massachusetts Institute of Technology (MIT); Lee, Yi-Hsien [Massachusetts Institute of Technology (MIT); Hsu, Allen Long [Massachusetts Institute of Technology (MIT); Kim, Soo Min [Massachusetts Institute of Technology (MIT); Kim, Ki Kang [Massachusetts Institute of Technology (MIT); Yang, Hui Ying [Singapore University of Technology and Design; Liang, Lain-Jong [Academia Sinica, Hefei, China; Idrobo Tapia, Juan C [ORNL; Kong, Jing [Massachusetts Institute of Technology (MIT)

2012-01-01T23:59:59.000Z

292

Photo-oxidation catalysts  

DOE Patents (OSTI)

Photo-oxidation catalysts and methods for cleaning a metal-based catalyst are disclosed. An exemplary catalyst system implementing a photo-oxidation catalyst may comprise a metal-based catalyst, and a photo-oxidation catalyst for cleaning the metal-based catalyst in the presence of light. The exposure to light enables the photo-oxidation catalyst to substantially oxidize absorbed contaminants and reduce accumulation of the contaminants on the metal-based catalyst. Applications are also disclosed.

Pitts, J. Roland (Lakewood, CO); Liu, Ping (Irvine, CA); Smith, R. Davis (Golden, CO)

2009-07-14T23:59:59.000Z

293

Multifunctional Oxides: Multifunctional Oxides: Synthesis and ...  

Science Conference Proceedings (OSTI)

Using Ultrafast Optical Spectroscopy to Explore Magneoelectric Coupling in Multiferroic Oxide Heterostructures: Y-M Sheu1; S. Trugman1; L Yan1; C-P Chuu 1; ...

294

Asphalt Oxidation Kinetics and Pavement Oxidation Modeling  

E-Print Network (OSTI)

Most paved roads in the United States are surfaced with asphalt. These asphalt pavements suffer from fatigue cracking and thermal cracking, aggravated by the oxidation and hardening of asphalt. This negative impact of asphalt oxidation on pavement performance has not been considered adequately in pavement design. Part of the reason is that the process of asphalt oxidation in pavement is not well understood. This work focused on understanding the asphalt oxidation kinetics and on developing pavement oxidation model that predicts asphalt oxidation and hardening in pavement under environmental conditions. A number of asphalts were studied in laboratory condition. Based on kinetics data, a fast-rate ? constant-rate asphalt oxidation kinetics model was developed to describe the early nonlinear fast-rate aging period and the later constant-rate period of asphalt oxidation. Furthermore, reaction kinetics parameters for the fast-rate and constant-rate reactions were empirically correlated, leading to a simplified model. And the experimental effort and time to obtain these kinetics parameters were significantly reduced. Furthermore, to investigate the mechanism of asphalt oxidation, two antioxidants were studied on their effectiveness. Asphalt oxidation was not significantly affected. It was found that evaluation of antioxidant effectiveness based on viscosity only is not reliable. The asphalt oxidation kinetics model was incorporated into the pavement oxidation model that predicts asphalt oxidation in pavement. The pavement oxidation model mimics the oxidation process of asphalt in real mixture at pavement temperatures. A new parameter, diffusion depth, defined the oxygen diffusion region in the mastic. A field calibration factor accounted for the factors not considered in the model such as the effect of small aggregate particles on oxygen diffusion. Carbonyl area and viscosity of binders recovered from field cores of three pavements in Texas were measured and were used for model calibration and validation. Results demonstrated that the proposed model estimates carbonyl growth over time in pavement, layer-by-layer, quite well. Finally, this work can be useful for incorporating asphalt oxidation into a pavement design method that can predict pavement performance with time and for making strategic decisions such as optimal time for maintenance treatments.

Jin, Xin

2012-05-01T23:59:59.000Z

295

EA-1947: Transfer of the Kansas City Plant, Kansas City, MO | Department of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

EA-1947: Transfer of the Kansas City Plant, Kansas City, MO EA-1947: Transfer of the Kansas City Plant, Kansas City, MO EA-1947: Transfer of the Kansas City Plant, Kansas City, MO SUMMARY This EA evaluates potential environmental impacts of a proposal to transfer the NNSA's KCP property either in whole or in part. This includes considering the No Action Alternative, where NNSA relocates operations from the KCP and maintains ownership of its property; and the Proposed Action Alternative, where NNSA transfers the KCP property for mixed use (industrial, warehouse, commercial, office). Under the proposed action, the EA addresses the potential direct, indirect, and cumulative impacts of using the KCP property for uses consistent with current zoning. NNSA also analyzes the potential environmental impacts of partial and/or complete

296

EA-1947: Transfer of the Kansas City Plant, Kansas City, MO | Department of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

EA-1947: Transfer of the Kansas City Plant, Kansas City, MO EA-1947: Transfer of the Kansas City Plant, Kansas City, MO EA-1947: Transfer of the Kansas City Plant, Kansas City, MO SUMMARY This EA evaluates potential environmental impacts of a proposal to transfer the NNSA's KCP property either in whole or in part. This includes considering the No Action Alternative, where NNSA relocates operations from the KCP and maintains ownership of its property; and the Proposed Action Alternative, where NNSA transfers the KCP property for mixed use (industrial, warehouse, commercial, office). Under the proposed action, the EA addresses the potential direct, indirect, and cumulative impacts of using the KCP property for uses consistent with current zoning. NNSA also analyzes the potential environmental impacts of partial and/or complete

297

EIS-0475: Disposition of the Bannister Federal Complex, Kansas City, MO |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

EIS-0475: Disposition of the Bannister Federal Complex, Kansas EIS-0475: Disposition of the Bannister Federal Complex, Kansas City, MO EIS-0475: Disposition of the Bannister Federal Complex, Kansas City, MO Summary NNSA/DOE announces its intent to prepare an EIS for the disposition of the Bannister Federal Complex, Kansas City, MO. NNSA previously decided in a separate NEPA review (EA-1592) to relocate its operations from the Bannister Federal Complex to a newly constructed industrial campus eight miles from the current location. NOTE: On November 30, 2012, DOE announced the cancellation of this EIS and its intent to prepare an Environmental Assessment (EA-1947). Public Comment Opportunities None available at this time. Documents Available for Download November 30, 2012 EA-1947: Notice of Intent to Prepare an Environmental Assessment and

298

DOE - Office of Legacy Management -- Weldon Spring Chemical Co - MO 03  

NLE Websites -- All DOE Office Websites (Extended Search)

Weldon Spring Chemical Co - MO 03 Weldon Spring Chemical Co - MO 03 FUSRAP Considered Sites Site: Weldon Spring Chemical Co. (MO.03) Designated Name: Alternate Name: Location: Evaluation Year: Site Operations: Site Disposition: Radioactive Materials Handled: Primary Radioactive Materials Handled: Radiological Survey(s): Site Status: Also see Weldon Spring, Missouri, Site Documents Related to Weldon Spring Chemical Co. Summary of Work Session - Focus Area: Monitoring and Maintenance. Summary of Weldon Spring Long-Term Stewardship Plan Public Workshop. Summary of Work Session - Focus Area: Communication and Public Involvement. Land Use and Institutional Controls and Homeland SecurityFocus Area Work SessionWeldon Spring SiteInterpretive CenterDecember 5, 20022 Agenda7:00 p.m.Welcome, Pam Thompson, Manager, Weldon SpringObjective of

299

The development of uranium foil farication technology utilizing twin roll method for Mo-99 irradiation target  

E-Print Network (OSTI)

MDS Nordion in Canada, occupying about 75% of global supply of Mo-99 isotope, has provided the irradiation target of Mo-99 using the rod-type UAl sub x alloys with HEU(High Enrichment Uranium). ANL (Argonne National Laboratory) through co-operation with BATAN in Indonesia, leading RERTR (Reduced Enrichment for Research and Test Reactors) program substantially for nuclear non-proliferation, has designed and fabricated the annular cylinder of uranium targets, and successfully performed irradiation test, in order to develop the fabrication technology of fission Mo-99 using LEU(Low Enrichment Uranium). As the uranium foils could be fabricated in laboratory scale, not in commercialized scale by hot rolling method due to significant problems in foil quality, productivity and economic efficiency, attention has shifted to the development of new technology. Under these circumstances, the invention of uranium foil fabrication technology utilizing twin-roll casting method in KAERI is found to be able to fabricate LEU or...

Kim, C K; Park, H D

2002-01-01T23:59:59.000Z

300

Progress in chemical processing of LEU targets for {sup 99}Mo production -- 1997  

SciTech Connect

Presented here are recent experimental results of the continuing development activities associated with converting current processes for producing fission-product {sup 99}Mo from targets using high-enriched uranium (HEU) to low-enriched uranium (LEU). Studies were focused in four areas: (1) measuring the chemical behavior of iodine, rhodium, and silver in the LEU-modified Cintichem process, (2) performing experiments and calculations to assess the suitability of zinc fission barriers for LEU metal foil targets, (3) developing an actinide separations method for measuring alpha contamination of the purified {sup 99}Mo product, and (4) developing a cooperation with Sandia National Laboratories and Los Alamos National Laboratory that will lead to approval by the US Federal Drug Administration for production of {sup 99}Mo from LEU targets. Experimental results continue to show the technical feasibility of converting current HEU processes to LEU.

Vandegrift, G.F.; Conner, C.; Sedlet, J.; Wygmans, D.G. [Argonne National Lab., IL (United States); Wu, D. [Univ. of Illinois, Urbana, IL (United States); Iskander, F.; Landsberger, S. [Univ. of Texas, Austin, TX (United States)

1997-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "mo magnesium oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

An experimental investigation of double beta decay of /sup 100/Mo  

SciTech Connect

New limits on half-lives for several double beta decay modes of /sup 100/Mo were obtained with a novel experimental system which included thin source films interleaved with a coaxial array of windowless silicon detectors. Segmentation and timing information allowed backgrounds originating in the films to be studied in some detail. Dummy films containing /sup 96/Mo were used to assess remaining backgrounds. With 0.1 mole years of /sup 100/Mo data collected, the lower half-life limits at 90% confidence were 2.7 /times/ 10/sup 18/ years for decay via the two-neutrino mode, 5.2 /times/10/sup 19/ years for decay with the emission of a Majoron, and 1.6 /times/ 10/sup 20/ years and 2.2 /times/ 10/sup 21/ years for neutrinoless 0/sup +/ ..-->.. 2/sup +/ and 0/sup +/ ..-->.. 0/sup +/ transitions, respectively. 50 refs., 38 figs., 11 tabs.

Dougherty, B.L.

1988-11-17T23:59:59.000Z

302

Highly Conductive Textured Molybdenum Doped Indium Oxide Thin Films  

DOE Green Energy (OSTI)

We report on the pulsed laser deposition (PLD) of Mo-doped indium oxide (IMO) films with mobilities of up to 125 cm2/Vsec. Films have been grown from targets with 1-4 wt.% molybdenum. The optimum electrical and optical properties were obtained with the 2% target and yielded a maximum conductivity of 3717 S/cm with mobilities of 99 cm2/V-sec on (100) yttria stabilized zirconia (YSZ) single crystal substrates. Films also exhibit greater than 90% transparency in the visible range. Compared to commercial indium tin oxide (ITO) films, these PLD-grown IMO films have similar conductivity but since they have substantially higher mobility they have a correspondingly lower carrier concentration. The lower carrier concentration should extend the infrared window of the transparency for films of the same conductivity. This may lead to improved performance in a number of applications requiring improved performance TCOs.

Warmsingh, C.; Yoshida, Y.; Readey, D.; Perkins, J.; Parilla, P.; Teplin, C.; Kaydanova, T.; Alleman, J.; Gedvilas, L.; Keyes, B.; Gessert, T.; Coutts, T.; Ginley, D.

2003-05-01T23:59:59.000Z

303

Neutron Sciences - Electrode Material for Solid-oxide Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Theory meets experiment: structure-property relationships in an electrode Theory meets experiment: structure-property relationships in an electrode material for solid-oxide fuel cells Research Contact: Ana B. Munoz-Garcia December 2012, Written by Agatha Bardoel Fuel cell technology is one potentially very efficient and environmentally friendly way to convert the chemical energy of fuels into electricity. Solid-oxide fuel cells (SOFCs) can convert a wide variety of fuels with simpler, cheaper designs than those used in liquid electrolyte cells. Using the Powder Diffractometer at the Spallation Neutron Source, researchers experimentally characterized the promising new SOFC electrode material strontium iron molybdenum oxide─Sr2Fe1.5Mo0.5O6-ή (SFMO). Combining the experimental results with insights from theory showed that the crystal structure is distorted from the ideal cubic simple perovskite

304

Substitution of modified 9 Cr-1 Mo steel for austentic stainless steels  

SciTech Connect

This report describes the current program to develop a high-strength ferritic-martensitic steel. The alloy is essentially Fe-9% Cr-1% Mo with small additions of V and Nb and is known as modifed 9 Cr-1 Mo steel. Its elevated-temperature properties and design allowable stresses match those of type 304 stainless steel for temperatures up to 600/sup 0/C and exceed those of other ferritic steels by factors of 2 to 3. The improved strength of this alloy permits its use in place of stainless steels for many applications.

Sikka, V. K.

1982-04-01T23:59:59.000Z

305

Thermally Driven Crossover from Indirect toward Direct Bandgap in 2D Semiconductors: MoSe2 versus MoS2  

E-Print Network (OSTI)

transition may occur from the adsorbed hydroxyl radi- cals (MOx[·OH]) to the lattice of the metal oxide anode, forming the higher oxide MOx+1, and the oxygen forms oxidizing organic substance to different products [21,23]. Since MOx[·OH] favors electrochemical combustion while MOx+1 favors electrochemical conversion [23

Wu, Junqiao

306

Effect of Mo Back Contact on Na Out-Diffusion and Device Performance of Mo/Cu(In,Ga)Se2/CdS/ZnO Solar Cells: Preprint  

DOE Green Energy (OSTI)

This conference paper describes the molybdenum thin films that were deposited on soda lime glass (SLG) substrates using direct-current planar magnetron sputtering, with a sputtering power density of 1.2 W/cm2. The working gas (Ar) pressure was varied from 0.6 to 16 mtorr to induce changes in the Mo films' morphology and microstructure. Thin films of Cu(In,Ga)Se2 (CIGS) were deposited on the Mo-coated glass using the 3-stage co-evaporation process. The morphology of both the Mo-coated SLG and the CIGS thin films grown on it was examined using high-resolution scanning electron microscopy. Na was depth profiled in the Mo and CIGS films by secondary ion mass spectrometry. The device performance was evaluated under standard conditions of 1000 W/m2 and 25 C. Optimum device performance is found for an intermediate Mo sputtering pressure.

Al-Thani, H. A.; Hasoon, F. S.; Young, M.; Asher, S.; Alleman, J. L.; Al-Jassim, M. M.; Williamson, D. L.

2002-05-01T23:59:59.000Z

307

Single-crystal micro/nanostructures and thin films of lamellar molybdenum oxide by solid-state pyrolysis of organometallic derivatives of a cyclotriphosphazene  

Science Conference Proceedings (OSTI)

The solid-state pyrolysis of organometallic derivatives of a cyclotriphosphazene is demonstrated to be a new, simple and versatile solid-state templating method for obtaining single-crystal micro- and nanocrystals of transition and valve metal oxides. The technique, when applied to Mo-containing organometallics N{sub 3}P{sub 3}[OC{sub 6}H{sub 4}CH{sub 2}CN.Mo(CO){sub 5}]{sub 6} and N{sub 3}P{sub 3}[OC{sub 6}H{sub 4}CH{sub 2}CN.Mo(CO){sub 4} py]{sub 6}, results in stand-alone and surface-deposited lamellar MoO{sub 3} single crystals, as determined by electron and atomic force microscopies and X-ray diffraction. The size and morphology of the resulting crystals can be tuned by the composition of the precursor. X-ray photoelectron and infrared spectroscopies indicate that the deposition of highly lamellar MoO{sub 3} directly on an oxidized (400 nm SiO{sub 2}) surface or (100) single-crystal silicon surfaces yields a layered uniphasic single-crystal film formed by cluster diffusion on the surface during pyrolysis of the metal-carbonyl derivatives. For MoO{sub 3} in its layered form, this provides a new route to an important intercalation material for high energy density battery materials. - Graphical abstract: Lamellar MoO{sub 3} micro- and nanocrystals are prepared by pyrolysis of the organometallics N{sub 3}P{sub 3}[OC{sub 6}H{sub 4}CH{sub 2}CN.Mo(CO){sub 5}]{sub 6} (I) and N{sub 3}P{sub 3}[OC{sub 6}H{sub 4}CH{sub 2}CN.Mo(CO){sub 4} py]{sub 6} (II), in air at 800 {sup o}C. The single-crystal products exhibit a high degree of turbostratic layering (see image). Deposition and subsequent pyrolysis of uniphasic MoO{sub 3} from the precursors is also possible on suitable substrates and supports.

Diaz, Carlos, E-mail: cdiaz@uchile.c [Departamento de Quimica, Facultad de Ciencias, Universidad de Chile, Casilla 653, Santiago (Chile); Lavayen, Vladimir [Departamento de Fisica, Universidad Tecnica Federico Santa Maria, Valparaiso 2390123 (Chile); O'Dwyer, Colm, E-mail: colm.odwyer@ul.i [Department of Physics and Materials and Surface Science Institute, University of Limerick, Limerick (Ireland)

2010-07-15T23:59:59.000Z

308

Recycling Other MMCs  

Science Conference Proceedings (OSTI)

...Reinforcement Matrix alloys Boron fiber Aluminum, titanium Silicon carbide fiber Aluminum, titanium, magnesium, copper Graphite Fiber Aluminum, magnesium Aluminum oxide fiber Aluminum, magnesium Tungsten fiber Nickel, cobalt, iron...

309

ESS 2012 Peer Review - Architectural Diversity of Metal Oxide Nanostructures - Esther Takeuchi, Stony Brook University  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Architectural Diversity of Metal Oxide Nanostructures: Architectural Diversity of Metal Oxide Nanostructures: An Opportunity for the Rational Optimization of Group II Cation Based Batteries. Esther S. Takeuchi, Kenneth J. Takeuchi, Amy C. Marschilok esther.takeuchi@stonybrook.edu, kenneth.takeuchi.1@stonybrook.edu, amy.marschilok@stonybrook.edu Utilize earth abundant, low cost elements with minimal environmental impact as battery materials. Exploit magnesium due to air stability and ~1,000X higher natural abundance than lithium and ~5,000X higher abundance than lead. Cathode materials feature Mn, Fe or V metal centers. Strategy Results Results This project targets some of the unique needs of large scale power storage: 1) reduced cost 2) low environmental impact 3) scalability 4) reversibility

310

Semesterplan WS 2012/13 Chemie (VL) fr Zahnmediziner (1. FS) Stand. 02.10.2012 Mo 22. Okt.  

E-Print Network (OSTI)

Semesterplan WS 2012/13 Chemie (VL) fĂŒr Zahnmediziner (1. FS) Stand. 02.10.2012 Mo 22. Okt;Semesterplan WS 2012/13 Chemie (VL) fĂŒr Zahnmediziner (1. FS) Stand. 02.10.2012 Mo 17. Dez. 10.15 11

Gollisch, Tim

311

Small non-polar complexes exhibiting significant piezoelectric properties: Solvothermal synthesis and crystal structures of MO{sub 5}V(tren){center_dot}H{sub 2}O (M=Mo and W; tren=tris(2-aminoethyl)amine)  

SciTech Connect

The two isostructural complexes MO{sub 5}V(tren){center_dot}H{sub 2}O (M=Mo (1) and W (2)) were synthesized under solvothermal conditions at pH Almost-Equal-To 12 crystallizing in the non-centrosymmetric space group P2{sub 1}2{sub 1}2{sub 1}. The structures are constructed by a distorted tetrahedral [MO{sub 4}]{sup 2-} anion bound via one shared oxygen atom to a severely distorted [V{sup IV}N{sub 4}O]{sup 2+} complex completing the octahedral coordination around the V centre. The two O atoms in the VN{sub 4}O{sub 2} octahedron are in cis position. The two compounds represent rare examples where the [MO{sub 4}]{sup 2-} anion is acting as a ligand. Both compounds exhibit a piezoelectric effect which is more pronounced for M=Mo. The samples are further characterized with IR and UV/Vis spectroscopy and thermal analysis. - Graphical abstract: The complexes [(V(tren)O)(MO4)]{center_dot}H2O (M = Mo, W; tren = tris(2-aminoethyl)amine)) composed of vertex-linked [MO4]{sup 2-} tetrahedron and [VN4O6]{sup 2+}octahedron. Highlights: Black-Right-Pointing-Pointer [MO{sub 4}]{sup 2-} tetrahedron (M=Mo, W) acting as ligand. Black-Right-Pointing-Pointer Jahn-Teller and steric distortion of the [VN{sub 4}O{sub 2}]{sup 2+} octahedron. Black-Right-Pointing-Pointer Non-centrosymmetric complexes exhibiting pronounced piezoelectric effect.

Rasmussen, M.; Naether, C. [Institut fuer Anorganische Chemie, Christian-Albrechts-Universitaet Kiel, Max-Eyth-Str. 2, D-24118 Kiel (Germany)] [Institut fuer Anorganische Chemie, Christian-Albrechts-Universitaet Kiel, Max-Eyth-Str. 2, D-24118 Kiel (Germany); Bismayer, U. [Mineralogisch-Petrographisches Institut, Universitaet Hamburg, Grindelallee 48 20146 Hamburg (Germany)] [Mineralogisch-Petrographisches Institut, Universitaet Hamburg, Grindelallee 48 20146 Hamburg (Germany); Bensch, W., E-mail: wbensch@ac.uni-kiel.de [Institut fuer Anorganische Chemie, Christian-Albrechts-Universitaet Kiel, Max-Eyth-Str. 2, D-24118 Kiel (Germany)

2012-11-15T23:59:59.000Z

312

Energy and Technolgy Assessment of Zinc and Magnesium Casting Plants, Technical Report Close-out, August 25,2006  

Science Conference Proceedings (OSTI)

Twin City Die Castings Company of Minneapolis, Minnesota, Twin City Die Castings Company was awarded project No. DE-FG36-05GO15097 to perform plant wide assessments of ten (10) die casting facilities that produce zinc and magnesium alloy castings in order to determine improvements and potential cost savings in energy use. Mr. Heider filled the role of team leader for the project and utilized the North American Die Casting Association (NADCA) to conduct audits at team participant plants so as to hold findings specific to each plant proprietary. The intended benefits of the project were to improve energy use through higher operational and process efficiency for the plants assessed. An improvement in energy efficiency of 5 – 15% was targeted. The primary objectives of the project was to: 1) Expand an energy and technology tool developed by the NADCA under a previous DOE project titled, “Energy and Technology Assessment for Die Casting Plants” for assessing aluminum die casting plants to be more specifically applicable to zinc and magnesium die casting facilities. 2) Conduct ten (10) assessments of zinc and magnesium die casting plants, within eight (8) companies, utilizing the assessment tool to identify, evaluate and recommend opportunities to enhance energy efficiency, minimize waste, and improve productivity. 3) Transfer the assessment tool to the die casting industry at large.

Twin City Die Castings Company; Tom Heider; North American Die Castings Association

2006-08-25T23:59:59.000Z

313

Hydrotreating studies involving NiMo/silica-doped hydrous titanium oxide (HTO:Si)-coated alumina catalysts  

SciTech Connect

For hydrotreating a petroleum-derived liquid feed at 400 C, LHSV = 2. 5 g/g{sub cat}/h, and 1500 psig hydrogen (H) pressure, both HDS and HDN activities were roughly equivalent for a name/TO:Si-coated Amocat catalyst and a commercial alumina-supported name catalyst (Amocat 1C). Superior HDN performance was exhibited by the name/TO: Si-coated Amocat catalyst at low H pressure (500 psig) and after H pressure cycling (1500-500-1500 psig) relative to Amocat 1C. Consistent with previous results obtained on a coal-derived liquid feed, the HDS/HDN results with the petroleum-derived liquid showed that the performance of the name/TO:Si-coated Amocat catalyst on an active metals weight basis exceeded the performance of Amocat 1C at all test conditions. The name/TO:Si-coated Amocat catalyst also showed potentially increased hydrogenation activity, increased resistance to deactivation, and increased yields of lower boiling point distillate fractions, although further work is needed.

Gardner, T.J.; Miller, J.E.; McLaughlin, L.I.; Trudell, D.E.

1996-07-01T23:59:59.000Z

314

SYNTHESIS, CHARACTERIZATION AND KINETIC STUDIES OF MIXED METAL Mo-V-Nb-Te OXIDE CATALYSTS FOR PROPANE AMMOXIDATION TO ACRYLONITRILE.  

E-Print Network (OSTI)

??The ample abundance and low cost of propane has recently spurred an interest in the manufacture of acrylic acid and acrylonitrile from propane, both important… (more)

BHATT, SALIL R

2006-01-01T23:59:59.000Z

315

MoSi2 and Other Silicides as High Temperature Structural Materials  

Science Conference Proceedings (OSTI)

... R.W. Stusrud, R.A. MacKay,. D.L. Anton, T. Khan, R.D. Kissinger, D.L. Klarstmm ..... 'I. 3 10-S d. 5. Q. H. 3 10= g. 5. E a. E m-7. 'E 5, .- z. 10-8 '. 5 c:3si MoSi2. //II.

316

MoCha-pi, an exogenous coordination calculus based on mobile channels  

Science Conference Proceedings (OSTI)

In this paper we present MoCha-?, an exogenous coordination calculus that is based on mobile channels. A mobile channel is a coordination primitive that allows anonymous point-to-point communication between processes. Our calculus is an extension ... Keywords: calculus, coordination, distributed mobile channels

Juan Guillen-Scholten; Farhad Arbab; Frank de Boer; Marcello Bonsangue

2005-03-01T23:59:59.000Z

317

The MoLE project: an international experiment about mobile learning environment  

Science Conference Proceedings (OSTI)

This paper aims to present an international project, called the MoLE Project, which provided learning resources and tools for personnel in disaster or emergency situations. Thus, it illustrates the interpenetration of e-Learning and field workers with ... Keywords: education, mobile technologies, system evaluation

Marie-Hélène Ferrer, Jacob Hodges, Nathalie Bonnardel

2013-08-01T23:59:59.000Z

318

ON THE COMPETITION BETWEEN FERROMAGNETIC AND ANTIFERROMAGNETIC STATES IN Sr2MnMoO6  

E-Print Network (OSTI)

It is argued that the magnetic behavior of Sr2MnMoO6 is determined by the existence of two total energy minima corresponding to the metallic ferromagnetic and insulating antiferromagnetic states, which may be nearly degenerate depending on the magnitude of the breathing distortion. PACS: 71.20.Be; 71.70.Gm; 72.25.Ba; 75.30.Et

I. V. Solovyev

2002-01-01T23:59:59.000Z

319

High-field superconductivity in some bcc Ti-Mo and Nb-Zr alloys  

Science Conference Proceedings (OSTI)

Zero electrical resistance at unusually high magnetic field strengths has been observed in the bcc alloys Ti-16 a/o (atomic percent) Mo, Nb-12 a/o Zr, and Nb-25 a/o Zr. The maximum highfield zero-resistance current density, Jc, in these ...

R. R. Hake; T. G. Berlincourt; D. H. Leslie

1962-01-01T23:59:59.000Z

320

Spectroscopy of low energy solar neutrinos by MOON -Mo Observatory Of Neutrinos-  

E-Print Network (OSTI)

Spectroscopy of low energy solar neutrinos by MOON -Mo Observatory Of Neutrinos- R. Hazamaa , P Be solar 's. The present status of MOON for the low energy solar experiment is briefly discussed the pp solar flux with good accuracy. 1. INTRODUCTION Realtime studies of the high-energy component of 8

Washington at Seattle, University of

Note: This page contains sample records for the topic "mo magnesium oxide" from the National Library of EnergyBeta (NLEBeta).
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321

To appear in the ACM SIGGRAPH conference proceedings Jeong-Mo Hong  

E-Print Network (OSTI)

To appear in the ACM SIGGRAPH conference proceedings � ��� ����� Ð� � Jeong-Mo Hong£ Korea of viscosity influences the shape of air bubbles in water. In this paper, we extend previous fluid simulation

Frey, Pascal

322

Microstructural Analysis of Irradiated U-Mo Fuel Plates: Recent Results  

Science Conference Proceedings (OSTI)

Microstructural characterization of irradiated dispersion and monolithic RERTR fuel plates using scanning electron microscopy (SEM) is being performed in the Electron Microscopy Laboratory at the Idaho National Laboratory. The SEM analysis of samples from U-Mo dispersion fuel plates focuses primarily on the behavior of the Si that has been added to the Al matrix to improve the irradiation performance of the fuel plate and on the overall behavior of fission gases (e.g., Xe and Kr) that develop as bubbles in the fuel microstructure. For monolithic fuel plates, microstructural features of interest, include those found in the U-Mo foil and at the U-Mo/Zr and Zr/6061 Al cladding interfaces. For both dispersion and monolithic fuel plates, samples have been produced using an SEM equipped with a Focused Ion Beam (FIB). These samples are of very high quality and can be used to uncover some very unique microstructural features that are typically not observed when characterizing samples produced using more conventional techniques. Overall, for the dispersion fuel plates with matrices that contained Si, narrower fuel/matrix interaction layers are typically observed compared to the fuel plates with pure Al matrix, and for the monolithic fuel plates microstructural features have been observed in the U-10Mo foil that are similar to what have been observed in the fuel particles found in U-Mo dispersion fuels. Most recently, more prototypic monolithic fuel samples have been characterized and this paper describes the microstructures that have been observed in these samples.

D. D. Keiser, Jr.; J. Jue; B. D. Miller; J. Gan; A. B. Robinson; P. V. Medvedev

2012-03-01T23:59:59.000Z

323

Transient Heat and Material Flow Modeling of Friction Stir Processing of Magnesium Alloy using Threaded Tool  

SciTech Connect

A three-dimensional transient computational fluid dynamics (CFD) model was developed to investigate the material flow and heat transfer during friction stir processing (FSP) in an AZ31B magnesium alloy. The material was assumed to be a non-Newtonian viscoplastic fluid, and the Zener-Hollomon parameter was used to describe the dependence of material viscosity on temperature and strain rate. The material constants used in the constitutive equation were determined experimentally from compression tests of the AZ31B Mg alloy under a wide range of strain rates and temperatures. A dynamic mesh method, combining both Lagrangian and Eulerian formulations, was used to capture the material flow induced by the movement of the threaded tool pin. Massless inert particles were embedded in the simulation domain to track the detailed history of material flow. The actual FSP was also carried out on a wrought Mg plate where temperature profiles were recorded by embedding thermocouples. The predicted transient temperature history was found to be consistent with that measured during FSP. Finally, the influence of the thread on the simulated results of thermal history and material flow was studied by comparing two models: one with threaded pin and the other with smooth pin surface.

Yu, Zhenzhen [ORNL; Zhang, Wei [ORNL; Choo, Hahn [ORNL; Feng, Zhili [ORNL

2012-01-01T23:59:59.000Z

324

Plutonium and americium recovery from spent molten-salt-extraction salts with aluminum-magnesium alloys  

Science Conference Proceedings (OSTI)

Development work was performed to determine the feasibility of removing plutonium and americium from spent molten-salt-extraction (MSE) salts using Al-Mg alloys. If the product buttons from this process are compatible with subsequent aqueous processing, the complex chloride-to-nitrate aqueous conversion step which is presently required for these salts may be eliminated. The optimum alloy composition used to treat spent 8 wt % MSE salts in the past yielded poor phase-disengagement characteristics when applied to 30 mol % salts. After a limited investigation of other alloy compositions in the Al-Mg-Pu-Am system, it was determined that the Al-Pu-Am system could yield a compatible alloy. In this system, experiments were performed to investigate the effects of plutonium loading in the alloy, excess magnesium, age of the spent salt on actinide recovery, phase disengagement, and button homogeneity. Experimental results indicate that 95 percent plutonium recoveries can be attained for fresh salts. Further development is required for backlog salts generated prior to 1981. A homogeneous product alloy, as required for aqueous processing, could not be produced.

Cusick, M.J.; Sherwood, W.G.; Fitzpatrick, R.F.

1984-04-23T23:59:59.000Z

325

Polymer Stable Magnesium Nanocomposites Prepared by Laser Ablation for Efficient Hydrogen Storage  

E-Print Network (OSTI)

Hydrogen is a promising alternative energy carrier that can potentially facilitate the transition from fossil fuels to sources of clean energy because of its prominent advantages such as high energy density (142 MJ per kg), great variety of potential sources (for example water, biomass, organic matter), and low environmental impact (water is the sole combustion product). However, due to its light weight, the efficient storage of hydrogen is still an issue investigated intensely. Various solid media have been considered in that respect among which magnesium hydride stands out as a candidate offering distinct advantages. Recent theoretical work indicates that MgH2 becomes less thermodynamically stable as particle diameter decreases below 2 nm. Our DFT (density functional theory) modeling studies have shown that the smallest enthalpy change, corresponding to 2 unit-cell thickness (1.6 {\\AA} Mg/3.0{\\AA} MgH2) of the film, is 57.7 kJ/molMg. This enthalpy change is over 10 kJ per molMg smaller than that of the bulk...

Makridis, S S; Panagakos, G; Kikkinides, E S; Stubos, A K; Wagener, P; Barcikowski, S

2013-01-01T23:59:59.000Z

326

Partial oxidation catalyst  

DOE Patents (OSTI)

A two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion. The dehydrogenation portion is a group VIII metal and the oxide-ion conducting portion is selected from a ceramic oxide crystallizing in the fluorite or perovskite structure. There is also disclosed a method of forming a hydrogen rich gas from a source of hydrocarbon fuel in which the hydrocarbon fuel contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion at a temperature not less than about 400.degree. C. for a time sufficient to generate the hydrogen rich gas while maintaining CO content less than about 5 volume percent. There is also disclosed a method of forming partially oxidized hydrocarbons from ethanes in which ethane gas contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion for a time and at a temperature sufficient to form an oxide.

Krumpelt, Michael (Naperville, IL); Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Doshi, Rajiv (Downers Grove, IL)

2000-01-01T23:59:59.000Z

327

Microstructural Characterization of U-7Mo/Al-Si Alloy Matrix Dispersion Fuel Plates Fabricated at 500°C  

Science Conference Proceedings (OSTI)

The starting microstructure of a dispersion fuel plate will impact the overall performance of the plate during irradiation. To improve the understanding of the as-fabricated microstructures of U–Mo dispersion fuel plates, particularly the interaction layers that can form between the fuel particles and the matrix, scanning electron microscopy (SEM) and transmission electron microscopy (TEM) analyses have been performed on samples from depleted U–7Mo (U–7Mo) dispersion fuel plates with either Al–2 wt.% Si(Al–2Si) or AA4043 alloy matrix. It was observed that in the thick interaction layers, U(Al, Si)3 and U6Mo4Al43 were present, and in the thin interaction layers, (U, Mo) (Al, Si)3, U(Al, Si)4, U3Si3Al2, U3Si5, and possibly USi-type phases were observed. The U3Si3Al2 phase contained some Mo. Based on the results of this investigation, the time that a dispersion fuel plate is exposed to a relatively high temperature during fabrication will impact the nature of the interaction layers around the fuel particles. Uniformly thin, Si-rich layers will develop around the U–7Mo particles for shorter exposure times, and thicker, Si-depleted layers will develop for the longer exposure times.

Dennis D. Keiser, Jr.; Jan-Fong Jue; Bo Yao; Emmanuel Perez; Yongho Sohn; Curtis R. Clark

2011-05-01T23:59:59.000Z

328

Efficient reversible electrodes for solid oxide electrolyzer cells  

DOE Patents (OSTI)

An electrolyzer cell is disclosed which includes a cathode to reduce an oxygen-containing molecule, such as H2O, CO2, or a combination thereof, to produce an oxygen ion and a fuel molecule, such as H2, CO, or a combination thereof. An electrolyte is coupled to the cathode to transport the oxygen ion to an anode. The anode is coupled to the electrolyte to receive the oxygen ion and produce oxygen gas therewith. In one embodiment, the anode may be fabricated to include an electron-conducting phase having a perovskite crystalline structure or structure similar thereto. This perovskite may have a chemical formula of substantially (Pr(1-x)Lax)(z-y)A'yBO(3-.differential.), wherein 0.ltoreq.x.ltoreq.0.5, 0.ltoreq.y.ltoreq.0.5, and 0.8.ltoreq.z.ltoreq.1.1. In another embodiment, the cathode includes an electron-conducting phase that contains nickel oxide intermixed with magnesium oxide.

Elangovan, Singaravelu (South Jordan, UT); Hartvigsen, Joseph J. (Kaysville, UT)

2011-07-12T23:59:59.000Z

329

Observations on the oxidation of Mn-modified Ni-base Haynes 230 alloy under SOFC exposure conditions  

Science Conference Proceedings (OSTI)

The commercial Ni-base Haynes 230 alloy (Ni-Cr-Mo-W-Mn) was modified with two increased levels of Mn (1 and 2 wt per cent) and evaluated for its oxidation resistance under simulated SOFC interconnect exposure conditions. Oxidation rate, oxide morphology, oxide conductivity and thermal expansion were measured and compared with commercial Haynes 230. It was observed that additions of higher levels of Mn to the bulk alloy facilitated the formation of a bi-layered oxide scale that was comprised of an outer M3O4 (M=Mn, Cr, Ni) spinel-rich layer at the oxide – gas interface over a Cr2O3-rich sub-layer at the metal – oxide interface. The modified alloys showed higher oxidation rates and the formation of thicker oxide scales compared to the base alloy. The formation of a spinel-rich top layer improved the scale conductivity, especially during the early stages of the oxidation, but the higher scale growth rate resulted in an increase in the area-specific electrical resistance over time. Due to their face-centered cubic crystal structure, both commercial and modified alloys demonstrated a coefficient of thermal expansion that was higher than that of typical anode-supported and electrolyte-supported SOFCs.

Yang, Z Gary; Xia, Gordon; Stevenson, Jeffry W.; Singh, Prabhakar

2005-07-01T23:59:59.000Z

330

Barium oxide, calcium oxide, magnesia, and alkali oxide free glass  

DOE Patents (OSTI)

A glass composition consisting essentially of about 10-45 mole percent of SrO; about 35-75 mole percent SiO.sub.2; one or more compounds from the group of compounds consisting of La.sub.2O.sub.3, Al.sub.2O.sub.3, B.sub.2O.sub.3, and Ni; the La.sub.2O.sub.3 less than about 20 mole percent; the Al.sub.2O.sub.3 less than about 25 mole percent; the B.sub.2O.sub.3 less than about 15 mole percent; and the Ni less than about 5 mole percent. Preferably, the glass is substantially free of barium oxide, calcium oxide, magnesia, and alkali oxide. Preferably, the glass is used as a seal in a solid oxide fuel/electrolyzer cell (SOFC) stack. The SOFC stack comprises a plurality of SOFCs connected by one or more interconnect and manifold materials and sealed by the glass. Preferably, each SOFC comprises an anode, a cathode, and a solid electrolyte.

Lu, Peizhen Kathy; Mahapatra, Manoj Kumar

2013-09-24T23:59:59.000Z

331

Multifunctional Oxide Heterostructures  

Science Conference Proceedings (OSTI)

This book is devoted to the rapidly developing field of oxide thin-films and heterostructures. Oxide materials combined with atomic-scale precision in a heterostructure exhibit an abundance of macroscopic physical properties involving the strong coupling between the electronic, spin, and structural degrees of freedom, and the interplay between magnetism, ferroelectricity, and conductivity. Recent advances in thin-film deposition and characterization techniques made possible the experimental realization of such oxide heterostructures, promising novel functionalities and device concepts.

Tsymbal, E Y [University of Nebraska, Lincoln; Dagotto, Elbio R [ORNL; Eom, Professor Chang-Beom [University of Wisconsin, Madison; Ramesh, Ramamoorthy [University of California, Berkeley

2012-01-01T23:59:59.000Z

332

METAL OXIDE NANOPARTICLES  

SciTech Connect

This chapter covers the fundamental science, synthesis, characterization, physicochemical properties and applications of oxide nanomaterials. Explains fundamental aspects that determine the growth and behavior of these systems, briefly examines synthetic procedures using bottom-up and top-down fabrication technologies, discusses the sophisticated experimental techniques and state of the art theory results used to characterize the physico-chemical properties of oxide solids and describe the current knowledge concerning key oxide materials with important technological applications.

FERNANDEZ-GARCIA,M.; RODGRIGUEZ, J.A.

2007-10-01T23:59:59.000Z

333

Automotive storage of hydrogen using modified magnesium hydrides. Final report, March 1976-March 1978  

DOE Green Energy (OSTI)

Metal hydrides can store more hydrogen per unit volume than normal high pressure or cryogenic techniques. Little energy is required to store the hydrogen in the hydride, and high stability at room temperature ensures low losses over long storage periods. Safety features of metal hydride storage are favorable. Because of its low weight and high hydrogen storage densities, modified magnesium hydride offers the greatest potential for automotive storage of hydrogen. Experimental and analytical work in this program has been directed toward the optimization of this storage system. Due to the relative stability of MgH/sub 2/, modifications of the MgMH/sub x/ (M = metal ion) have been made to decrease the dissociation temperature while retaining high hydrogen capacity. This parameter is crucial since vehicle exhaust will supply the thermal energy to dissociate the hydride in an automobile. System studies indicate that hydride dissociation temperature (T/sub D/) should be 200/sup 0/C to ensure uninterrupted fuel flow at all driving and idle conditions. From experimental data developed in this four task study, we conclude that alloys comprised of Mg, Cu and Ni have come closest to meeting the dissociation temperature goal. Small additions of rare-earth elements to the basic alloy also contribute to a reduction of T/sub D/. The best alloy developed in this program exhibits a T/sub D/ = 223/sup 0/C and a hydrogen capacity near four weight percent compared to a theoretical 7.65 percent for MgH/sub 2/. That alloy has been characterized for dissociation temperature, hydrogen capacity, kinetics, and P-C-T relationships. Dissociation temperature, hydrogen capacity and material cost are reported for each alloy tested in this program.

Rohy, D. A.; Nachman, J. F.; Hammer, A. N.; Duffy, T. E.

1979-01-01T23:59:59.000Z

334

Electrochemical corrosion of iron-magnesium-alumina spinel (FMAS) in molten potassium salts and coal slag  

DOE Green Energy (OSTI)

Iron, magnesium-alumina spinel (FMAS) (0.25 Fe/sub 3/O/sub 4/ . 0.75 MgAl/sub 2/O/sub 4/) has been considered for use as an electrode in magnetohydrodynamic (MHD) generator channels. Predominantly an electronic conductor, FMAS has adequate electrical conductivity (>1 S/m) above 520/sup 0/K. In addition, FMAS can be easily fabricated into a form and sintered in air to >90% theoretical density and has a melting point of 2124 +- 20/sup 0/K. Laboratory tests to measure both the electrochemical and chemical corrosion of FMAS in molten K/sub 2/CO/sub 3/, K/sub 2/SO/sub 4/ and coal slags were developed at the Pacific Northwest Laboratory to evaluate the relative corrosion of FMAS. Under isothermal conditions, a direct electric current was passed between an anode and a cathode through a molten electrolyte. The molten coal slags were synthetic high-calcium, low-iron Montana Rosebud and low-calcium, high-iron Illinois No. 6. Evaluations of electrochemical corrosion were made as functions of current density, temperature, and slag composition. These results were compared to those of FMAS tested without electric current. The corrosion rates and reaction products were investigated by optical microscopy and scanning electron microscopy. Overall, FMAS has too-high an electrochemical corrosion rate to be considered as MHD electrodes in Montana Rosebud coal slag or in systems where only molten potassium salts are present. However, FMAS may be considered for use in high-iron coal slags although the corrosion rates are still quite high even in these slags.

Marchant, D.D.; Griffin, C.W.; Bates, J.L.

1981-01-01T23:59:59.000Z

335

Growth of purified calcium fluoride and magnesium fluoride and degradation of optical properties by defects  

SciTech Connect

This report describes the purification and crystal growth portion of the research undertaken in this program. Several new devices for conducting chemical operations in isolated environments were perfected. The precipitator/decanter system was the most important of these. Without it the very large number of precipitate washing cycles required would have been prohibitive due to the time required using the older design. The purification process improved the purity of both fluorides. Precipitation of the alkaline earth carbonates from an alkaline solution was extremely effective in removing alkali ions. The second stage of the process used ion-exchange to remove transition metal ions and to reduce the concentration of other alkaline earths. The third stage of the process was the precipitation and washing of the product fluoride which proved to be difficult because these fluorides form gels or sols when pure. At an ammonium fluoride concentration near 8M a satisfactory precipitate was obtained. Only after a long resting period could the precipitate be washed without converting to a gel or sol. Magnesium fluoride had a much greater tendency to form gels than the calcium salt. Crystal growth was attempted by a Stockbarger method using HF as the reactive gas. The remainder of this report describes the research on the effect of defects on the optical properties of optical materials. The Landau-Placzek ratio and the method for calculating its theoretical value is described. This establishes a comparison standard for studies of doped crystals discussed in the remaining chapters of this report. As part of the preparation of the crystals for optical studies the distribution coefficients for cadmium, calcium and lead were measured and are reported. 121 refs., 30 figs., 22 tabs.

Fredericks, W.J.; Collins, P.R.

1983-01-01T23:59:59.000Z

336

Microstructure-strength relationships of heavily deformed magnesium-lithium composites containing steel fibers  

SciTech Connect

The successful development of deformation-processed metal-metal composites (DMMC) offers the potential for ductile, high-strength structural materials with high-temperature stability. An infiltration casting process was used to permeate steel wool preforms with molten magnesium-lithium (Mg-Li) alloys. The selected matrix alloys were hexagonal close packed (HCP) Mg-4wt%Li or body centered cubic (BCC) Mg-12wt%Li; the low carbon steel wool fibers were predominantly BCC ferrite. These cast HCP/BCC and BCC/BCC composites were deformed by rolling or by extrusion and swaging. Mechanical properties, microstructure, and texture development of the composites were characterized at various levels of deformation. The HCP/BCC composites had limited formability at temperatures up to 400 C while the BCC/BCC composites had excellent formability during sheet rolling at room temperature but limited formability during swaging at room temperature. The tensile strengths of these HCP/BCC and BCC/BCC composite materials increased moderately with deformation, though less than predicted from rule of mixtures (ROM) calculations. The microstructure was characterized to correlate the filament size to the deformation strain and mechanical properties of the composite material. Stereological measurements of the filament size were used to adjust ROM calculations to reflect the actual deformation strain in the fibers. However, the experimental strengths of these composite materials were still less than ROM predictions, possibly due to the presence of considerably large fibers. Of the many models used to describe the strengthening observed in DMMC materials, the Hall-Petch relationship adequately described the experimental data. Texture development was also characterized to explain the deformation characteristics of the composite materials. Chapters 2, 3 and 4 are not included here. They are being processed separately.

Jensen, J.

1997-10-08T23:59:59.000Z

337

Defect Structure of Oxides  

Science Conference Proceedings (OSTI)

Table 1   Classification of electrical conductors: oxides, sulfides, and nitrides...2 O 4 , NiAl 2 O 4 , (Tl 2 O),

338

Oxidation of gallium arsenide  

DOE Patents (OSTI)

This invention relates to gallium arsenide semiconductors and, more particularly, to the oxidation of surface layers of gallium arsenide semiconductors for semiconductor device fabrication.

Hoffbauer, M.A.; Cross, J.B.

1991-11-16T23:59:59.000Z

339

Oxidation/Coatings  

Science Conference Proceedings (OSTI)

Oct 28, 2009 ... International Symposium on Ceramic Matrix Composites: Oxidation/ ... on combustor liners of a Solar Turbines' industrial gas turbine engine, ...

340

File:USDA-CE-Production-GIFmaps-MO.pdf | Open Energy Information  

Open Energy Info (EERE)

MO.pdf MO.pdf Jump to: navigation, search File File history File usage Missouri Ethanol Plant Locations Size of this preview: 776 × 600 pixels. Full resolution ‎(1,650 × 1,275 pixels, file size: 377 KB, MIME type: application/pdf) Description Missouri Ethanol Plant Locations Sources United States Department of Agriculture Related Technologies Biomass, Biofuels, Ethanol Creation Date 2010-01-19 Extent State Countries United States UN Region Northern America States Missouri External links http://www.nass.usda.gov/Charts_and_Maps/Ethanol_Plants/ File history Click on a date/time to view the file as it appeared at that time. Date/Time Thumbnail Dimensions User Comment current 16:16, 27 December 2010 Thumbnail for version as of 16:16, 27 December 2010 1,650 × 1,275 (377 KB) MapBot (Talk | contribs) Automated bot upload

Note: This page contains sample records for the topic "mo magnesium oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Laser Welding and Post Weld Treatment of Modified 9Cr-1MoVNb Steel [Laser  

NLE Websites -- All DOE Office Websites (Extended Search)

Laser Welding of Metals > Laser Welding of Metals > Laser Welding and Post Weld Treatment of Modified 9Cr-1MoVNb Steel Capabilities Engineering Experimentation Reactor Safety Experimentation Aerosol Experiments System Components Laser Applications Overview Laser Oil & Gas Well Drilling Laser Heat Treatment Laser Welding of Metals On-line Monitoring Laser Beam Delivery Laser Glazing of Railroad Rails High Power Laser Beam Delivery Decontamination and Decommissioning Refractory Alloy Welding Robots Applications Other Facilities Other Capabilities Work with Argonne Contact us For Employees Site Map Help Join us on Facebook Follow us on Twitter NE on Flickr Laser Applications Laboratory Laser Welding of Metals Laser Welding and Post Weld Treatment of Modified 9Cr-1MoVNb Steel Zhiyue Xu Nuclear Engineering Division of Argonne National Laboratory

342

Improved performance of U-Mo dispersion fuel by Si addition in Al matrix.  

SciTech Connect

The purpose of this report is to collect in one publication and fit together work fragments presented in many conferences in the multi-year time span starting 2002 to the present dealing with the problem of large pore formation in U-Mo/Al dispersion fuel plates first observed in 2002. Hence, this report summarizes the excerpts from papers and reports on how we interpreted the relevant results from out-of-pile and in-pile tests and how this problem was dealt with. This report also provides a refined view to explain in detail and in a quantitative manner the underlying mechanism of the role of silicon in improving the irradiation performance of U-Mo/Al.

Kim, Y S; Hofman, G L [Nuclear Engineering Division

2011-06-01T23:59:59.000Z

343

Mo-6%Nb single crystal alloy creep strength demonstration for long life thermionic power systems  

DOE Green Energy (OSTI)

Experimental results of one- and two-dimensional creep testing for single crystal Mo-6%Nb alloy are presented. Three 1-D specimens were creep-tested for up to 3000 hours at 1873 to 1973 K and 5 to 15 MPa. One 2-D specimen tube was creep-tested for 2000 hours at 1873 K/15MPa. Results confirm the high creep strength of Mo-6%Nb for long life (10 to 15 year) TFE emitter application in thermionic space nuclear power systems. After the initial transition stage (about 1000 hours), quasi-steady state 1-D and 2-D creep rates were within 20% of each other suggesting little significant effect of anisotropy. More data points will be needed to define the Sherby-Dom parameters with statistical accuracy. {copyright} 1995 {ital American} {ital Institute} {ital of} {ital Physics}

Rhee, H.S.; Zheng, C.; Kent Koester, J. [Space Power, Inc., 621 River Oaks Parkway, San Jose, California 95134 (United States); Yastrebkov, A.; Nikolaev, Y.; Gontar, A. [Scientific Industrial Association Lutch, Podolsk, Moscow Region (Russian Federation)

1995-01-20T23:59:59.000Z

344

Sr 2 FeMoO 6 Thin Film Growth Using Novel Double Perovskite ...  

Science Conference Proceedings (OSTI)

Facile Native Oxide Based Passivation of Silicon: An Unconventional Approach · Hybrid Polymer-nanocrystal Multilayered Architectures for High-performance ...

345

Production and Characterization of Atomized U-Mo Powder by the Rotating Electrode Process  

SciTech Connect

In order to produce feedstock fuel powder for irradiation testing, the Idaho National Laboratory has produced a rotating electrode type atomizer to fabricate uranium-molybdenum alloy fuel. Operating with the appropriate parameters, this laboratory-scale atomizer produces fuel in the desired size range for the RERTR dispersion experiments. Analysis of the powder shows a homogenous, rapidly solidified microstructure with fine equiaxed grains. This powder has been used to produce irradiation experiments to further test adjusted matrix U-Mo dispersion fuel.

C.R. Clark; B.R. Muntifering; J.F. Jue

2007-09-01T23:59:59.000Z

346

High strength Sn-Mo-Nb-Zr alloy tubes and method of making same  

DOE Patents (OSTI)

Tubes for use in nuclear reactors fabricated from a quaternary alloy comprising 2.5-4.0 wt% Sn, 0.5-1.5 wt% Mo, 0.5-1.5 wt% Nb, balance essentially Zr. The tubes are fabricated by a process of hot extrusion, heat treatment, cold working to size and age hardening, so as to produce a microstructure comprising elongated .alpha. grains with an acicular transformed .beta. grain boundary phase.

Cheadle, Brian A. (Deep River, CA)

1977-01-01T23:59:59.000Z

347

Selective methane oxidation over promoted oxide catalysts. Quarterly report, March 1 - May 31, 1996  

DOE Green Energy (OSTI)

Series of catalysts consisting of MoO{sub 3}, V{sub 2}O{sub 5}, TiO{sub 2}, and SnO{sub 2} impregnated onto oxide supports consisting of SiO{sub 2} (Cab-O-Sil), TiO{sub 2} or SnO{sub 2} were previously prepared and tested for the selective oxidation of methane to oxygenates, and it was found that the V{sub 2}O{sub 5}/SiO{sub 2} catalyst was the most active and most selective toward the formation of formaldehyde. These catalysts have been characterized by laser Raman spectroscopy after dehydration and during the methane oxidation reaction with a CH{sub 4}/02 = 10/1 reaction mixture at 500{degrees}C in a continuous flow in situ reaction cell. With the V{sub 2}O{sub 5}/SiO{sub 2} catalyst (the most active catalyst among those studied), no significant structural changes were revealed by in situ Raman analyses, indicating that the fully oxidized surface sites were related to the high formaldehyde selectivivity. Over the V{sub 2}O{sub 5}/TiO{sub 2} and V{sub 2}O{sub 5}/SnO{sub 2} catalysts, CO and CO{sub 2} were the principal products produced by oxidation of methane. For the first time, in situ Raman analysis clearly showed that for these latter catalysts, the surface vanadium(V) oxide species were partially reduced under the steady-state reaction conditions. The performance of the V{sub 2}O{sub 5}/TiO{sub 2}/SiO{sub 2} catalyst was similar to that of the V{sub 2}O{sub 5}TiO{sub 2} catalyst, consistent with the earlier observation that vanadia was largely bound to the titania overlayer. It appears that formaldehyde selectivity decreased with increasing catalyst reducibility, but no direct correlation of catalyst activity with reductibility was observed.

Klier, K.; Herman, R.G.; Wang, C.-B.

1996-12-31T23:59:59.000Z

348

ESS 2012 Peer Review - Architectural Diversity of Metal Oxide...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

earth abundant, low cost elements with minimal environmental impact as battery materials. Exploit magnesium due to air stability and 1,000X higher natural abundance than...

349

Ni6Cr5MoO18: A compensated half metal predicted from first-principles  

Science Conference Proceedings (OSTI)

NiCrO3 is semiconducting. It contains six molecular units in the conventional cell. By substituting one of the six Cr atoms with Mo in the conventional cell

Jing Wang; Ningning Zu; Zhijian Wu

2013-01-01T23:59:59.000Z

350

Catalytic hydrocarbon reactions over supported metal oxides. Progress report, April 1, 1994--January 31, 1995  

DOE Green Energy (OSTI)

Oxide catalysis plays a central role in hydrocarbon processing and improvements in catalytic activity or selectivity are of great technological importance because these improvements will translate directly into more efficient utilization of hydrocarbon supplies and lower energy consumption in separation processes. An understanding of the relationships between surface structure and catalytic properties is needed to describe and improve oxide catalysts. Our approach has been to prepare supported oxides that have a specific structure and oxidation state and then employ these structures in reaction studies. Our current research program is focused on studying the fundamental relationships between structure and reactivity for two important reactions that are present in many oxide-catalyzed processes, partial oxidation and carbon-carbon bond formation. Oxide catalysis can be a complex process with both metal cation and oxygen anions participating in the chemical reactions. From an energy perspective carbon-carbon bond formation is particularly relevant to CO hydrogenation in isosynthesis. Hydrogenolysis and hydrogenation form the basis for heteroatom removal in fuels processing. Understanding the catalysis of these processes (and others) requires isolating reaction steps in the overall cycle and determining how structure and composition influence the individual reaction steps. Specially designed oxides, such as we use, permit one to study some of the steps in oxidation, carbon-carbon coupling and heteroatom removal catalysis. During the course of our studies we have: (1) developed methods to form and stabilize various Mo and W oxide structures on silica; (2) studied C-H abstraction reactions over the fully oxidized cations; (3) studied C-C bond coupling by methathesis and reductive coupling of aldehydes and ketones over reduced cation structures; and (4) initiated a study of hydrogenation and hydrogenolysis over reduced cation structures.

Ekerdt, J.G.

1995-01-31T23:59:59.000Z

351

Electrical tuning of valley magnetic moment through symmetry control in bilayer MoS2  

SciTech Connect

Crystal symmetry governs the nature of electronic Bloch states. For example, in the presence of time-reversal symmetry, the orbital magnetic moment and Berry curvature of the Bloch states must vanish unless inversion symmetry is broken1. In certain two-dimensional electron systems such as bilayer graphene, the intrinsic inversion symmetry can be broken simply by applying a perpendicular electric field2,3. In principle, this offers the possibility of switching on/off and continuously tuning the magnetic moment and Berry curvature near the Dirac valleys by reversible electrical control4,5. Here we investigate this possibility using polarization-resolved photoluminescence of bilayer MoS2, which has the same symmetry as bilayer graphene but has a bandgap in the visible spectrum6,7 allowing direct optical probing5,8 12. We find that in bilayer MoS2 the circularly polarized photoluminescence can be continuously tuned from 15% to 15% as a function of gate voltage, whereas in structurally non-centrosymmetric monolayer MoS2 the photoluminescence polarization is gate independent. The observations are well explained as resulting from the continuous variation of orbital magnetic moments between positive and negative values through symmetry control.

Wu, Sanfeng [University of Washington, Seattle; Ross, Jason [University of Washington, Seattle; Liu, G. B. [University of Hong Kong, The; Aivazian, Grant [University of Washington, Seattle; Jones, Aaron [University of Washington, Seattle; Fei, Zaiyao [University of Washington, Dept Phys, Seattle, WA; Zhu, Wenguang [University of Tennessee, Knoxville (UTK); Xiao, Di [ORNL; Yao, Wang [University of Hong Kong, The; Cobden, David [University of Washington, Dept Phys, Seattle, WA; Xu, Xiaodong [University of Washington

2013-01-01T23:59:59.000Z

352

Electrical properties of a-C:Mo films produced by dual-cathode filtered cathodic arc plasma deposition  

SciTech Connect

Molybdenum-containing amorphous carbon (a-C:Mo) thin films were prepared using a dual-cathode filtered cathodic arc plasma source with a molybdenum and a carbon (graphite) cathode. The Mo content in the films was controlled by varying the deposition pulse ratio of Mo and C. Film sheet resistance was measured in situ at process temperature, which was close to room temperature, as well as ex situ as a function of temperature (300-515 K) in ambient air. Film resistivity and electrical activation energy were derived for different Mo and C ratios and substrate bias. Film thickness was in the range 8-28 nm. Film resistivity varied from 3.55x10-4 Omega m to 2.27x10-6 Omega m when the Mo/C pulse ratio was increased from 0.05 to 0.4, with no substrate bias applied. With carbon-selective bias, the film resistivity was in the range of 4.59x10-2 and 4.05 Omega m at a Mo/C pulse ratio of 0.05. The electrical activation energy decreased from 3.80x10-2 to 3.36x10-4 eV when the Mo/C pulse ratio was increased in the absence of bias, and from 0.19 to 0.14 eV for carbon-selective bias conditions. The resistivity of the film shifts systematically with the amounts of Mo and upon application of substrate bias voltage. The intensity ratio of the Raman D-peak and G-peak (ID/IG) correlated with the pre-exponential factor (sigma 0) which included charge carrier density and density of states.

Sansongsiri, Sakon; Anders, Andre; Yodsombat, Banchob

2008-01-20T23:59:59.000Z

353

Stabilized chromium oxide film  

DOE Patents (OSTI)

Stabilized air-oxidized chromium films deposited on high-power klystron ceramic windows and sleeves having a thickness between 20 and 150.ANG. are useful in lowering secondary electron emission yield and in avoiding multipactoring and window failure due to overheating. The ceramic substrate for the film is chosen from alumina, sapphire or beryllium oxide.

Garwin, Edward L. (Los Altos, CA); Nyaiesh, Ali R. (Palo Alto, CA)

1988-01-01T23:59:59.000Z

354

Stabilized chromium oxide film  

DOE Patents (OSTI)

Stabilized air-oxidized chromium films deposited on high-power klystron ceramic windows and sleeves having a thickness between 20 and 150A are useful in lowering secondary electron emission yield and in avoiding multipactoring and window failure due to overheating. The ceramic substrate for the film is chosen from alumina, sapphire or beryllium oxide.

Nyaiesh, A.R.; Garwin, E.L.

1986-08-04T23:59:59.000Z

355

TEM Characterization of U-7Mo/Al-2Si Dispersion Fuel Irradiated to Intermediate and High Fission Densities  

SciTech Connect

This paper will discuss the results of TEM analysis that was performed on two samples taken from the low flux and high flux sides of the fuel plate with U-7Mo fuel particles dispersed in U-2Si matrix. The corresponding local fission density of the fuel particles and the peak fuel plate centerline temperature between the low flux and high flux samples are 3.32 x 10{sup 27} f/m{sup 3} and 90 C, and 6.31 x 10{sup 27} f/m{sup 3} and 120 C, respectively. The results of this work showed the presence of a bubble superlattice within the U-7Mo grains that accommodated fission gases (e.g., Xe). The presence of this structure helps the U-7Mo exhibit a stable swelling behavior during irradiation. The Si-rich interaction layers that develop around the fuel particles at the U-7Mo/matrix interface during fuel plate fabrication and irradiation become amorphous during irradiation. The change in bubble distribution at the high fission density suggests that the bubble superlattice is stable as the U-7Mo matrix remains crystalline. It appears that there is a threshold Si content in the fuel particle above which the U-Mo turns to amorphous under irradiation. The threshold Si content is approximately 8 at.% and 4 at.% for low flux and high flux condition, respectively.

J. Gan; D.D. Keiser, Jr.; B.D. Miller; A.B. Robinson; J-F. Jue; P.G. Medvedev; D.M. Wachs

2012-05-01T23:59:59.000Z

356

Oxidative Degradation of Monoethanolamine  

NLE Websites -- All DOE Office Websites (Extended Search)

Oxidative Degradation of Monoethanolamine Oxidative Degradation of Monoethanolamine Susan Chi Gary T. Rochelle* (gtr@che.utexas.edu, 512-471-7230) The University of Texas at Austin Department of Chemical Engineering Austin, Texas 78712 Prepared for presentation at the First National Conference on Carbon Sequestration, Washington, DC, May 14-17, 2001 Abstract Oxidative degradation of monoethanolamine (MEA) was studied under typical absorber condition of 55°C. The rate of evolution of NH 3 , which was indicative of the overall rate of degradation, was measured continuously in a batch system sparged with air. Dissolved iron from 0.0001 mM to 1 mM yields oxidation rates from 0.37 to 2 mM/hr in MEA solutions loaded with 0.4 mole CO 2 / mole MEA. Ethylenediaminetetraacetic acid (EDTA) and N,N-bis(2- hydroxyethyl)glycine effectively decrease the rate of oxidation in the presence of iron by 40 to

357

Combinatorial Exploration of Novel Transparent Conducting Oxide Materials  

DOE Green Energy (OSTI)

High-throughput combinatorial approaches have been used for the discovery and optimization of transparent conducting oxide (TCO) materials for PV applications. We report on current investigations in In-Zn-O, In-Ti-O and In-Mo-O systems. The InZnO system is shown to be amorphous in the best conducting range with a conductivity of ~ 3000 ?-cm-1 for 50%-70% In/Zn. The amorphous InZnO films are very smooth (2..ANG.. rms). In-Ti-O is found to be an excellent high-mobility TCO with mobilities of greater than 80 cm2/v-sec and conductivities of more than 6000 ?-cm-1 for sputtered thin film materials.

Ginley, D. S.; van Hest, M. F. A. M.; Young, D.; Teplin, C. W.; Alleman, J. L.; Dabney, M. S.; Gedvilas, L. M.; Keyes, B. M.; To, B.; Perkins, J. D.; Taylor, M. P.; Readey, D.

2005-11-01T23:59:59.000Z

358

Atomistic modeling of nanowires, small-scale fatigue damage in cast magnesium, and materials for MEMS.  

Science Conference Proceedings (OSTI)

Lightweight and miniaturized weapon systems are driving the use of new materials in design such as microscale materials and ultra low-density metallic materials. Reliable design of future weapon components and systems demands a thorough understanding of the deformation modes in these materials that comprise the components and a robust methodology to predict their performance during service or storage. Traditional continuum models of material deformation and failure are not easily extended to these new materials unless microstructural characteristics are included in the formulation. For example, in LIGA Ni and Al-Si thin films, the physical size is on the order of microns, a scale approaching key microstructural features. For a new potential structural material, cast Mg offers a high stiffness-to-weight ratio, but the microstructural heterogeneity at various scales requires a structure-property continuum model. Processes occurring at the nanoscale and microscale develop certain structures that drive material behavior. The objective of the work presented in this report was to understand material characteristics in relation to mechanical properties at the nanoscale and microscale in these promising new material systems. Research was conducted primarily at the University of Colorado at Boulder to employ tightly coupled experimentation and simulation to study damage at various material size scales under monotonic and cyclic loading conditions. Experimental characterization of nano/micro damage will be accomplished by novel techniques such as in-situ environmental scanning electron microscopy (ESEM), 1 MeV transmission electron microscopy (TEM), and atomic force microscopy (AFM). New simulations to support experimental efforts will include modified embedded atom method (MEAM) atomistic simulations at the nanoscale and single crystal micromechanical finite element simulations. This report summarizes the major research and development accomplishments for the LDRD project titled 'Atomistic Modeling of Nanowires, Small-scale Fatigue Damage in Cast Magnesium, and Materials for MEMS'. This project supported a strategic partnership between Sandia National Laboratories and the University of Colorado at Boulder by providing funding for the lead author, Ken Gall, and his students, while he was a member of the University of Colorado faculty.

Dunn, Martin L. (University of Colorado, Boulder, CO); Talmage, Mellisa J. (University of Colorado, Boulder, CO); McDowell, David L., 1956- (,-Georgia Institute of Technology, Atlanta, GA); West, Neil (University of Colorado, Boulder, CO); Gullett, Philip Michael (Mississippi State University , MS); Miller, David C. (University of Colorado, Boulder, CO); Spark, Kevin (University of Colorado, Boulder, CO); Diao, Jiankuai (University of Colorado, Boulder, CO); Horstemeyer, Mark F. (Mississippi State University , MS); Zimmerman, Jonathan A.; Gall, K (Georgia Institute of Technology, Atlanta, GA)

2006-10-01T23:59:59.000Z

359

Mkha' 'gro dbang mo'i rnam that, the biography of the gter ston ma bde chen chos kyi dbang mo (1868-1927?)  

E-Print Network (OSTI)

, for example, A 'dzom 'Brug pa 'Gro 'dul dPa' bo rDo rje (1842-1924), a famous rdzogs chen master and treasure revealer (see Namkhai 1986, p. 153), who bestowed upon her a long life empowerment when she was 26 (1893); see dBang mo'i rnam thar, p. 824, passim... , Kværne and Nagano eds., 2003, p. 323), gCod, A khrid (see Kværne and Rikey, 1996), Phur pa (see Bon Kanjur, op.cit., pp. 295-297), rDzogs chen Yang rtse Klong chen (Sherab Wangyal, TBMC, New Delhi, 1973), Khro bo rGyud drug gSang ba bSen thub (see Bon...

Rossi, Donatella

2008-01-01T23:59:59.000Z

360

X-Ray Absorption Studies of Vanadium-Containing Metal Oxide Nanocrystals  

Science Conference Proceedings (OSTI)

Metal oxide nanocrystals offer significant potential for use as catalysts or catalyst supports due to their high surface areas and unique chemical properties that result from the high number of exposed corners and edges. However, little is known about the catalytic activity of these materials, especially as oxidation catalysts. This research focused on the preparation, characterization and use of vanadium-containing nanocrystals as selective oxidation catalysts. Three vanadium-containing nanocrystals were prepared using a modified sol-gel procedure: V/MgO, V/SiO2, and vanadium phosphate (VPO). These represent active oxidation catalysts for a number of industrially relevant reactions. The catalysts were characterized by x-ray diffraction and Raman, UV-VIS, infrared and x-ray absorption spectroscopies with the goal of determining the primary structural and chemical differences between nanocrystals and microcrystals. The catalytic activity of these catalysts was also studied in oxidative dehydrogenation of butane and methanol oxidation to formaldehyde. V/MgO nanocrystals were investigated for activity in oxidative dehydrogenation of butane and compared to conventional V/MgO catalysts. Characterization of V/MgO catalysts using Raman spectroscopy and x-ray absorption spectroscopy showed that both types of catalysts contained magnesium orthovanadate at vanadium loadings below 15 weight%, but above that loading, magnesium pyrovanadate may have been present. In general, MgO nanocrystals had roughly half the crystal size and double the surface area of the conventional MgO. In oxidative dehydrogenation of butane, nanocrystalline V/MgO gave higher selectivity to butene than conventional V/MgO at the same conversion. This difference was attributed to differences in vanadium domain size resulting from the higher surface areas of the nanocrystalline support, since characterization suggested that similar vanadium phases were present on both types of catalysts. Experiments in methanol oxidation were used to probe the chemical differences between sol-gel prepared and conventionally prepared metal oxides. Both V/MgO and V/SiO2 were studied. For both catalysts, similar product selectivities were noted for either preparation method, suggesting similar acid/base and redox properties for the catalysts. At lower weight loadings (butane oxidation to maleic anhydride. In this method vanadium (V) triisopropoxide was reacted with orthophosphoric acid in THF to form a gel. Drying this gel under air resulted in an intercalated VOPO4 compound, where solvent molecules were trapped between layers of the vanadium phosphate compound. Higher surface areas could be achieved by drying this gel at high pressure in an autoclave. The amount of solvent (THF) placed in the autoclave was important in this process. Low amounts of solvent led to a lower surface area, as the solvent evaporated before reaching the critical point and collapsed the gel's pores. In addition, vanadium reduction occurred in the autoclave due to reaction of isopropanol with the vanadium phosphate. Higher amounts of THF reduced the concentration of isopropanol, leading to less reduction. Surfaces areas in excess of 100 m2/g were achieved with this method, and the product was confirmed through XPS and IR to be VOHPO4*0.5H2O, the common precursor for industrial VPO catalysts. Furthermore, this product displayed a platelet morphology, which is desirable for butane oxidation. Further work showed that this material could be transformed to (VO)2P2O7 (the industrial catalyst for butane oxidation to maleic anhydride) by heating under nitrogen without losing much surface are

Hohn, Keith, L.

2006-01-09T23:59:59.000Z

Note: This page contains sample records for the topic "mo magnesium oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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361

A Feasibility Study of Steelmaking by Molten Oxide Electrolysis (TRP9956)  

Science Conference Proceedings (OSTI)

Molten oxide electrolysis (MOE) is an extreme form of molten salt electrolysis, a technology that has been used to produce tonnage metals for over 100 years - aluminum, magnesium, lithium, sodium and the rare earth metals specifically. The use of carbon-free anodes is the distinguishing factor in MOE compared to other molten salt electrolysis techniques. MOE is totally carbon-free and produces no CO or CO2 - only O2 gas at the anode. This project is directed at assessing the technical feasibility of MOE at the bench scale while determining optimum values of MOE operating parameters. An inert anode will be identified and its ability to sustain oxygen evalution will be demonstrated.

Donald R. Sadoway; Gerbrand Ceder

2009-12-31T23:59:59.000Z

362

Selective methane oxidation over promoted oxide catalysts. Quarterly technical progress report, September 8, 1992--November 30, 1992  

DOE Green Energy (OSTI)

Support effects on catalytic reactions, especially of highly exothermic oxidation reactions, can be very significant. Since we had shown that a MoO{sub 3}/SiO{sub 2} catalyst, especially when used in a double bed configuration with a Sr/La{sub 2}O{sub 3} catalyst, can selectively oxidize methane to formaldehyde, the role of the SiO{sub 2} support was investigated. Therefore, partial oxidation of methane by oxygen to form formaldehyde, carbon oxides, and C{sub 2} products (ethane and ethene) has been studied over silica catalyst supports (fumed Cabosil and Grace 636 silica gel) in the 630-780{degrees}C temperature range under ambient pressure. When relatively high gas hourly space velocities (GHSV) were utilized, the silica catalysts exhibit high space time yields (at low conversions) for methane partial oxidation to formaldehyde, and the C{sub 2} hydrocarbons were found to be parallel products with formaldehyde. In general, the selectivities toward CO were high while those toward CO{sub 2} were low. Based on the present results obtained by a double catalyst bed experiment, the observations of product composition dependence on the variation of GHSV (i.e. gas residence time), and differences in apparent activation energies of formation of C{sub 2}H{sub 6}, and CH{sub 2}O, a reaction mechanism is proposed for the activation of methane over the silica surface. This mechanism can explain the observed product distribution patterns (specifically the parallel formation of formaldehyde and C{sub 2} hydrocarbons).

Klier, K.; Herman, R.G.; Sun, Q.; Sarkany, J.

1993-01-01T23:59:59.000Z

363

Behavior of molybdenum nitrides as materials for electrochemical capacitors: Comparison with ruthenium oxide  

Science Conference Proceedings (OSTI)

Ruthenium oxide (RuO{sub 2}), formed as a thin film on a Ru or Ti metal substrate, exhibits a large specific (cm{sup {minus}2}) and almost constant, electrochemical capacitance over a 1.35 V range in aqueous H{sub 2}SO{sub 4}. This behavior has led to its investigation and use as a material for fabrication of supercapacitor devices. However, its cost has encouraged search for other materials exhibiting similar behavior. Work reported in the present paper evaluates two nitrides of Mo, Mo{sub 2}N and MoN, as substitutes for RuO{sub 2}. It is shown that very similar capacitance behavior to that of RuO{sub 2} films arises, e.g., in cyclic voltammetry and dc charging curves; in the former, almost mirror-image anodic and cathodic current-response profiles, characteristic of a capacitor, arise. However, the nitride materials have a substantially smaller voltage operating range of only some 0.7 V due to electrochemical decomposition above ca. 0.7 V vs. RHE. This limits their usefulness as a substitute for RuO{sub 2}. Of interest is that the nitride films exhibit potential-decay and potential-recovery on open circuit after respective charge and forced discharge. The decay and recovery processes are logarithmic in time, indicating the role of internal faradaic charge redistribution processes.

Liu, T.C.; Pell, W.G.; Conway, B.E. [Univ. of Ottawa, Ontario (Canada). Dept. of Chemistry; Roberson, S.L. [North Carolina State Univ., Raleigh, NC (United States). Dept. of Materials Science and Engineering

1998-06-01T23:59:59.000Z

364

Evaluating the improvement of corrosion residual strength by adding 1.0 wt.% yttrium into an AZ91D magnesium alloy  

SciTech Connect

The influence of yttrium on the corrosion residual strength of an AZ91D magnesium alloy was investigated detailedly. Scanning electron microscope was employed to analyze the microstructure and the fractography of the studied alloys. The microstructure of AZ91D magnesium alloy is remarkably refined due to the addition of yttrium. The electrochemical potentiodynamic polarization curve of the studied alloy was performed with a CHI 660b electrochemical station in the three-electrode system. The result reveals that yttrium significantly promotes the overall corrosion resistance of AZ91D magnesium alloy by suppressing the cathodic reaction in corrosion process. However, the nucleation and propagation of corrosion pits on the surface of the 1.0 wt.% Y modified AZ91D magnesium alloy indicate that pitting corrosion still emerges after the addition of yttrium. Furthermore, stress concentration caused by corrosion pits should be responsible for the drop of corrosion residual strength although the addition of yttrium remarkably weakens the effect of stress concentration at the tip of corrosion pits in loading process.

Wang Qiang [Key Laboratory of Automobile Materials (Jilin University), Ministry of Education, College of Materials Science and Engineering, Jilin University, Changchun, 130025 (China); Liu Yaohui, E-mail: liuyaohui2005@yahoo.com [Key Laboratory of Automobile Materials (Jilin University), Ministry of Education, College of Materials Science and Engineering, Jilin University, Changchun, 130025 (China); Fang Shijie [Department of Mechanical and Electrical Engineering, Luoyang Institute of Science and Technology, Luoyang 471023 (China); Song Yulai; Zhang Dawei; Zhang Lina; Li Chunfang [Key Laboratory of Automobile Materials (Jilin University), Ministry of Education, College of Materials Science and Engineering, Jilin University, Changchun, 130025 (China)

2010-06-15T23:59:59.000Z

365

Mo Zhou  

NLE Websites -- All DOE Office Websites (Extended Search)

and regional government on appliance standard achievement; evaluate the social impact of appliance labeling program; and analysis of appliance price trend and learning rate to...

366

MO: ZL  

Office of Legacy Management (LM)

Tonawanda, New York," May 1978 (DOEEV-00056). 2. "Radiological Survey of the Ashland Oil Co. (Former Waist Property), Tonewanda, Kew York," May 1978 (DOEEV-00054). 3....

367

Oxidative Tritium Decontamination System  

DOE Patents (OSTI)

The Oxidative Tritium Decontamination System, OTDS, provides a method and apparatus for reduction of tritium surface contamination on various items. The OTDS employs ozone gas as oxidizing agent to convert elemental tritium to tritium oxide. Tritium oxide vapor and excess ozone gas is purged from the OTDS, for discharge to atmosphere or transport to further process. An effluent stream is subjected to a catalytic process for the decomposition of excess ozone to diatomic oxygen. One of two configurations of the OTDS is employed: dynamic apparatus equipped with agitation mechanism and large volumetric capacity for decontamination of light items, or static apparatus equipped with pressurization and evacuation capability for decontamination of heavier, delicate, and/or valuable items.

Gentile, Charles A. (Plainsboro, NJ), Guttadora, Gregory L. (Highland Park, NJ), Parker, John J. (Medford, NJ)

2006-02-07T23:59:59.000Z

368

Analysis of Lipid Oxidation  

Science Conference Proceedings (OSTI)

Analysis of Lipid Oxidation is essential for further developments in analytical methodology and hyphenated techniques, with which more understanding of the reaction kinetics, mechanism, and implications will take place. ...

369

Cathodoluminescence of uranium oxides  

SciTech Connect

The cathodoluminescence of uranium oxide surfaces prepared in-situ from clean uranium exposed to dry oxygen was studied. The broad asymmetric peak observed at 470 nm is attributed to F-center excitation.

Winer, K.; Colmenares, C.; Wooten, F.

1984-08-09T23:59:59.000Z

370

Metal atom oxidation laser  

DOE Patents (OSTI)

A chemical laser which operates by formation of metal or carbon atoms and reaction of such atoms with a gaseous oxidizer in an optical resonant cavity is described. The lasing species are diatomic or polyatomic in nature and are readily produced by exchange or other abstraction reactions between the metal or carbon atoms and the oxidizer. The lasing molecules may be metal or carbon monohalides or monoxides. (auth)

Jensen, R.J.; Rice, W.W.; Beattie, W.H.

1975-10-28T23:59:59.000Z

371

Metal atom oxidation laser  

DOE Patents (OSTI)

A chemical laser which operates by formation of metal or carbon atoms and reaction of such atoms with a gaseous oxidizer in an optical resonant cavity is described. The lasing species are diatomic or polyatomic in nature and are readily produced by exchange or other abstraction reactions between the metal or carbon atoms and the oxidizer. The lasing molecules may be metal or carbon monohalides or monoxides.

Jensen, R.J.; Rice, W.W.; Beattie, W.H.

1975-10-28T23:59:59.000Z

372

Controlled CO preferential oxidation  

DOE Patents (OSTI)

Method is described for controlling the supply of air to a PROX (PReferential OXidation for CO cleanup) reactor for the preferential oxidation in the presence of hydrogen wherein the concentration of the hydrogen entering and exiting the PROX reactor is monitored, the difference there between correlated to the amount of air needed to minimize such difference, and based thereon the air supply to the PROX reactor adjusted to provide such amount and minimize such difference. 2 figs.

Meltser, M.A.; Hoch, M.M.

1997-06-10T23:59:59.000Z

373

Mechanical Properties of Fresh and Irradiated Monolithic U-Mo Fuels  

Science Conference Proceedings (OSTI)

Evolution of the Thermo-mechanical Response of Nitride and Oxide Nuclear Fuels through Microstructurally Explicit Models. Experience of the Fossil Industry  ...

374

ADVANCED OXIDATION PROCESS  

DOE Green Energy (OSTI)

The removal of recalcitrant sulfur species, dibenzothiophene and its derivatives, from automotive fuels is an integral component in the development of cleaner burning and more efficient automobile engines. Oxidative desulfurization (ODS) wherein the dibenzothiophene derivative is converted to its corresponding sulfoxide and sulfone is an attractive approach to sulfur removal because the oxidized species are easily extracted or precipitated and filtered from the hydrocarbon phase. Fe-TAML{reg_sign} activators of hydrogen peroxide (TAML is Tetra-Amido-Macrocyclic-Ligand) catalytically convert dibenzothiophene and its derivatives rapidly and effectively at moderate temperatures (50-60 C) and ambient pressure to the corresponding sulfoxides and sulfones. The oxidation process can be performed in both aqueous systems containing alcohols such as methanol, ethanol, or t-butanol, and in a two-phase hydrocarbon/aqueous system containing tert-butanol or acetonitrile. In the biphasic system, essentially complete conversion of the DBT to its oxidized products can be achieved using slightly longer reaction times than in homogeneous solution. Among the key features of the technology are the mild reaction conditions, the very high selectivity where no over oxidation of the sulfur compounds occurs, the near stoichiometric use of hydrogen peroxide, the apparent lack of degradation of sensitive fuel components, and the ease of separation of oxidized products.

Dr. Colin P. Horwitz; Dr. Terrence J. Collins

2003-11-04T23:59:59.000Z

375

Stability and Lifetime of K-CoMoSx Mixed Alcohol Catalysts  

SciTech Connect

Researchers have studied sulfide-type catalysts for the production of mixed alcohols from synthesis gas for several decades. Despite many advances in the art, these processes are not yet commercial, due in large part to mediocre economics and the added risk associated with uncertainty in catalyst lifetime. This talk will outline some recent studies in the lifetime and stability of K-CoMoSx-type mixed alcohol catalysts. Specifically, studies of long term operation (> 3000h), sulfiding agents, simulated methanol recycle, and morphology (probed via XRD and XPS) will be discussed, with the conclusion that these materials are likely to exhibit acceptable lifetimes in continuous operation.

Hensley, J. E.; Ruddy, D.; Schaidle, J.; Ferrell, J.; Thibodeaux, J.

2013-01-01T23:59:59.000Z

376

FULL SIZE U-10MO MONOLITHIC FUEL FOIL AND FUEL PLATE FABRICATION-TECHNOLOGY DEVELOPMENT  

Science Conference Proceedings (OSTI)

Full-size U10Mo foils are being developed for use in high density LEU monolithic fuel plates. The application of a zirconium barrier layer too the foil is applied using a hot co-rolling process. Aluminum clad fuel plates are fabricated using Hot Isostatic Pressing (HIP) or a Friction Bonding (FB) process. An overview is provided of ongoing technology development activities, including: the co-rolling process, foil shearing/slitting and polishing, cladding bonding processes, plate forming, plate-assembly swaging, and fuel plate characterization. Characterization techniques being employed include, Ultrasonic Testing (UT), radiography, and microscopy.

G. A. Moore; J-F Jue; B. H. Rabin; M. J. Nilles

2010-03-01T23:59:59.000Z

377

Beta-decay properties of Zr and Mo neutron-rich isotopes  

E-Print Network (OSTI)

Gamow-Teller strength distributions, beta-decay half-lives, and beta-delayed neutron emission are investigated in neutron-rich Zr and Mo isotopes within a deformed quasiparticle random-phase approximation. The approach is based on a self-consistent Skyrme Hartree-Fock mean field with pairing correlations and residual separable particle-hole and particle-particle forces. Comparison with recent measurements of half-lives stresses the important role that nuclear deformation plays in the description of beta-decay properties in this mass region.

Sarriguren, P

2010-01-01T23:59:59.000Z

378

Properties of DU-10wt%Mo Alloys Subjected to Various Post-Rolling Heat Treatments  

Science Conference Proceedings (OSTI)

Mechanical properties of depleted uranium-molybdenum (U-Mo) alloys subjected to different post-processing treatments have been obtained using microhardness, quasi-static tensile tests, and scanning electron microscopy failure analysis. U-Mo alloy foils are currently under investigation for potential fuel conversion of high power research reactors to low enriched uranium fuel. Although mechanical properties take on a secondary effect during irradiation, an understanding of the alloy behavior during fabrication and the effects of irradiation on the integrity of the fuel is essential. In general, the microhardness was insensitive to annealing temperature but decreased with annealing duration. Yield strength, Young’s modulus and ultimate tensile strength improved with both increasing annealing temperature and duration. The failure mode was also insensitive to annealing conditions, but was significantly controlled by the impurity concentration of the alloy, especially carbon. Values obtained from literature are also provided with reasonable agreement based on extrapolation of annealing duration, even though processing conditions and applications were quite different in some instances.

Douglas E. Burkes; Ramprashad Prabhakaran; Thomas Hartmann; Jan-Fong Jue; Francine J. Rice

2010-06-01T23:59:59.000Z

379

Development and processing of LEU targets for {sup 99}Mo production  

SciTech Connect

Most of the world`s supply of {sup 99m}Tc for medical purposes is currently produced from the decay of {sup 99}Mo derived from the fissioning of high-enriched uranium (HEU). Substantial progress has been made in developing targets and chemical processes for producing {sup 99}Mo using low-enriched uranium (LEU). Target development has been focused on a uranium-metal foil target as a replacement for the coated-UO{sub 2} Cintichem-type target. Although the first designs were not successful because of ion mixing-induced bonding of the uranium foil to the target tubes, recent irradiations of modified targets have proven successful. Only minor modifications of the Cintichem chemical process are required for the uranium-metal foil targets. A demonstration using prototypically irradiated targets is anticipated in February 1997. Progress has also been made in basic dissolution of both uranium-metal foil and aluminum-clad U{sub 3}Si{sub 2} dispersion fuel targets.

Snelgrove, J.L.; Vandegrift, G.F.; Hofman, G.L.

1997-04-01T23:59:59.000Z

380

Thermal shock behavior of alumina/MoSi2 plasma sprayed laminated composites  

Science Conference Proceedings (OSTI)

Alumina (Al{sub 2}O{sub 3}) is very susceptible to thermal shock, which leads to strength degradation. By reinforcing Al{sub 2}O{sub 3} with molybdenum disilicide (MoSi{sub 2}) layers, the tolerance to damage caused by thermal shock can be improved. The thermal shock resistance of plasma sprayed Al{sub 2}O{sub 3}/MoSi{sub 2} laminated composites were investigated. Three laminate microstructures having different layer thickness were fabricated by atmospheric plasma spraying while maintaining a 50/50-volume fraction. Quenching experiments done on 4-point bend bars showed a gradual decrease in the strength as the change in temperature ({Delta}T) increased. Thermal shock resistant parameters (R{prime} and R-quadruple prime) provided a representative numerical value of the thermal shock resistance for the laminated composites. The corresponding material properties for the different microstructures were determined experimentally in order to calculate the R{prime} and R quadruple prime values. The intermediate layered composite showed the highest R-quadruple prime va1ue at 1061 {micro}m, while the thin layered composite had the highest R{prime} value at 474 W/m.

Castro, R. G. (Richard G.); Petrovic, J. J.; Vaidya, R. U. (Rajendra U.); Mendoza, D. (Daniel)

2001-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mo magnesium oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Experimental study of the electric dipole strength in the even Mo nuclei and its deformation dependence  

E-Print Network (OSTI)

Two methods based on bremsstrahlung were applied to the stable even Mo isotopes for the experimental determination of the photon strength function covering the high excitation energy range above 4 MeV with its increasing level density. Photon scattering was used up to the neutron separation energies Sn and data up to the maximum of the isovector giant resonance(GDR) were obtained by photo-activation. After a proper correction for multi-step processes the observed quasi-continuous spectra of scattered photons show a remarkably good match to the photon strengths derived from nuclear photo effect data obtained previously by neutron detection and corrected in absolute scale using the new activation results. The combined data form an excellent basis to derive a shape dependence of the E1 strength in the even Mo isotopes with increasing deviation from the N = 50 neutron shell, i.e. with the impact of quadrupole deformation and triaxiality. The wide energy coverage of the data allows for a stringent assessment of the dipole sum-rule, and a test of a novel parameterization developed previously which is based upon. This parameterization for the electric dipole strength function in nuclei with A>80 deviates significantly from prescriptions generally used previously. In astrophysical network calculations it may help to quantify the role the p-process plays in the cosmic nucleosynthesis. It also has impact on the accurate analysis of neutron capture data of importance for future nuclear energy systems and waste transmutation.

M. Erhard; A. R. Junghans; C. Nair; R. Schwengner; R. Beyer; J. Klug; K. Kosev; A. Wagner; E. Grosse

2010-01-21T23:59:59.000Z

382

Relationships between processing, microstructure, and properties of a Co-Cr-Mo alloy  

SciTech Connect

STELLITE alloy No. 21 was produced via rapid solidification processing (RSP) in a variety of particulate morphologies (coarse and fine powder, flakes, fibers, and ribbons). The various RSP forms showed similar, fine microstructures with only a slight difference in the scale of the microstructural features. These RSP particulates were consolidated by extrusion, dynamic compaction, and rapid omnidirectional compaction (ROC) at two processing temperatures (1077/sup 0/C and 1121/sup 0/C). Dynamic compaction proved to be unacceptable for this alloy because of non-uniform porosity and the inability to develop a metallurgical bond between particulates. A plot of elongation versus yield strength depicted two yield strength/ductility relationships for the Co-Cr-Mo type alloys. As-ROC'd samples had a low yield strength/ductility relationship. Atomized powder size also affected the strength/ductility relationships of the extruded products. Decreasing powder size increased ductility without effecting yield strength. Processing temperature did not affect the yield strength/ductility relationship. Electrochemical polarization tests were not successful in delineating fine differences between the various types of Co-Cr-Mo alloy while immersion-pitting temperature tests were capable of distinguishing between samples processed from fine and coarse powders. These materials proved susceptible to stress corrosion cracking (SCC) in boiling 30% MgCl/sub 2/.

Anand, V.; Hickl, A.J.; Kumar, P.; Boeck, B.A.; Sanders, T.H. Jr.

1984-01-01T23:59:59.000Z

383

Li2MnO3-LiMO2 (M=Mn, Co, Ni) Solid Solutions With Surface ...  

Science Conference Proceedings (OSTI)

AISI441 Interconnect-Air Electrode Interfacial Study for Solid Oxide ... Evaluation of a Compliant Silicate-based Sealing Glass for Solid Oxide Fuel Cells.

384

Thermally Oxidized Silicon  

NLE Websites -- All DOE Office Websites (Extended Search)

Anneli Munkholm (Lumileds Lighting) and Sean Brennan (SSRL) Anneli Munkholm (Lumileds Lighting) and Sean Brennan (SSRL) Illustration of the silicon positions near the Si-SiO2 interface for a 4° miscut projected onto the ( ) plane. The silicon atoms in the substrate are blue and those in the oxide are red. The small black spots represent the translated silicon positions in the absence of static disorder. The silicon atoms in the oxide have been randomly assigned a magnitude and direction based on the static disorder value at that position in the lattice. The outline of four silicon unit cells is shown in black, whereas the outline of four expanded lattice cells in the oxide is shown in blue One of the most studied devices of modern technology is the field-effect transistor, which is the basis for most integrated circuits. At its heart

385

Methanol partial oxidation reformer  

DOE Patents (OSTI)

A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

Ahmed, S.; Kumar, R.; Krumpelt, M.

1999-08-24T23:59:59.000Z

386

Methanol partial oxidation reformer  

DOE Patents (OSTI)

A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

Ahmed, S.; Kumar, R.; Krumpelt, M.

1999-08-17T23:59:59.000Z

387

MoO3 as combined hole injection layer and tapered spacer in combinatorial multicolor microcavity organic light emitting diodes  

SciTech Connect

Multicolor microcavity ({mu}C) organic light-emitting diode (OLED) arrays were fabricated simply by controlling the hole injection and spacer MoO{sub 3} layer thickness. The normal emission was tunable from {approx}490 to 640 nm and can be further expanded. A compact, integrated spectrometer with two-dimensional combinatorial arrays of {mu}C OLEDs was realized. The MoO{sub 3} yields more efficient and stable devices, revealing a new breakdown mechanism. The pixel current density reaches {approx}4 A/cm{sup 2} and a maximal normal brightness {approx}140 000 Cd/m{sup 2}, which improves photoluminescence-based sensing and absorption measurements.

Liu, R.; Xu, Chun; Biswas, Rana; Shinar, Joseph; Shinar, Ruth

2011-09-01T23:59:59.000Z

388

Low-spin structure of {sup 96}Mo studied with the (n,n{sup '}{gamma}) reaction  

Science Conference Proceedings (OSTI)

Extensive studies of the low-spin excited states in {sub 42}{sup 96}Mo{sub 54} with the (n,n{sup '}{gamma}) reaction have clarified the level scheme below 3.7 MeV excitation energy and determined detailed information about {sup 96}Mo, including lifetimes from the Doppler-shift attenuation method, branching ratios, and multipole mixing ratios. Also, B(E2) and B(M1) values were determined for many transitions, multiphonon states were identified, and several low-spin states were characterized in terms of collective, mixed-symmetry states.

Lesher, S. R.; Yates, S. W. [Department of Physics and Astronomy, University of Kentucky, Lexington, Kentucky 40506-0055 (United States); Department of Physics, University of Richmond, Richmond, Virginia 23173 (United States); McKay, C. J.; Bandyopadhyay, D.; Boukharouba, N.; Fransen, C.; Orce, J. N.; McEllistrem, M. T. [Department of Physics and Astronomy, University of Kentucky, Lexington, Kentucky 40506-0055 (United States); Mynk, M. [Department of Chemistry, University of Kentucky, Lexington, Kentucky 40506-0055 (United States)

2007-03-15T23:59:59.000Z

389

Molecular water oxidation catalyst  

DOE Patents (OSTI)

A dimeric composition of the formula: ##STR1## wherein L', L", L'", and L"" are each a bidentate ligand having at least one functional substituent, the ligand selected from bipyridine, phenanthroline, 2-phenylpyridine, bipyrimidine, and bipyrazyl and the functional substituent selected from carboxylic acid, ester, amide, halogenide, anhydride, acyl ketone, alkyl ketone, acid chloride, sulfonic acid, phosphonic acid, and nitro and nitroso groups. An electrochemical oxidation process for the production of the above functionally substituted bidentate ligand diaqua oxo-bridged ruthenium dimers and their use as water oxidation catalysts is described.

Gratzel, Michael (St. Sulpice, CH); Munavalli, Shekhar (Bel Air, MD); Pern, Fu-Jann (Lakewood, CO); Frank, Arthur J. (Lakewood, CO)

1993-01-01T23:59:59.000Z

390

Tetraalykylammonium polyoxoanionic oxidation catalysts  

DOE Patents (OSTI)

Alkanes are catalytically oxidized in air or oxygen using iron-substituted polyoxoanions (POAs) of the formula: H.sub.e-z ›(n-C.sub.4 H.sub.9).sub.4 N!.sub.z (XM.sub.11 M'O.sub.39).sup.-e The M' (e.g., iron(III)/iron(II)) reduction potential of the POAs is affected by selection of the central atom X and the framework metal M, and by the number of tetrabutyl-ammonium groups. Decreased Fe(III)/Fe(II) reduction potential has been found to correlate to increased oxidation activity.

Ellis, Paul E. (Downingtown, PA); Lyons, James E. (Wallingford, PA); Myers, Jr., Harry K. (Cochranville, PA); Shaikh, Shahid N. (Media, PA)

1998-01-01T23:59:59.000Z

391

Tetraalklylammonium polyoxoanionic oxidation catalysts  

DOE Patents (OSTI)

Alkanes are catalytically oxidized in air or oxygen using iron-substituted polyoxoanions (POAs) of the formula: H{sub e{minus}z}[(n-C{sub 4}H{sub 9}){sub 4}N]{sub z}(XM{sub 11}M{prime}O{sub 39}){sup {minus}e}. The M{prime} (e.g., iron(III)/iron(II)) reduction potential of the POAs is affected by selection of the central atom X and the framework metal M, and by the number of tetrabutyl-ammonium groups. Decreased Fe(III)/Fe(II) reduction potential has been found to correlate to increased oxidation activity.

Ellis, P.E.; Lyons, J.E.; Myers, H.K. Jr.; Shaikh, S.N.

1998-10-06T23:59:59.000Z

392

Biological Properties of Zinc Oxide-Coated Anodized Aluminum Oxide  

Science Conference Proceedings (OSTI)

We used agar diffusion assays to evaluate the activity of zinc oxide-coated ... Zirconia Stabilisation Nano-Confined by Using Electroless Nickel Cladding .... Metal Oxide Nanofibers Produced by a ForceSpinning Method for Battery Electrodes.

393

Effects of Cr-Mo Infiltration Source Structure on the Thickness of Alloy Layer by Double Glow Plasma Surface Metallurgy Technology  

Science Conference Proceedings (OSTI)

To strengthen the growth characteristics of layer on Q235 steel, a new source structure of Cr-Mo infiltration was proposed by plasma surface metallurgy technology. Comparative experiments were carried out on source polar of scrubbing brush structure ... Keywords: Surface alloying, Cr-Mo infiltrated, Plasma surface metallurgy technology, Thickness of layer

Jinyong Xu; Jingchun Zhang; Yajuan Liu; Cheng Gao

2010-03-01T23:59:59.000Z

394

Titanium and Magnesium Co-Alloyed Hematite Thin Films for Photoelectrochemical Water Splitting  

DOE Green Energy (OSTI)

Using a combination of density functional theory calculation and materials synthesis and characterization we examine the properties of charge-compensated Ti and Mg co-alloyed hematite thin films for the application of photoelectrochemical (PEC) water splitting. We find that the charge-compensated co-alloying results in the following effects: (1) It enhances the solubility of Mg and Ti, which leads to reduced electron effective mass and therefore increased electron mobility; (2) It tunes the carrier density and therefore allows the optimization of electrical conductivity; and (3) It reduces the density of charged defects and therefore reduces carrier recombination. As a result, the Ti and Mg co-alloyed hematite thin films exhibit improved water oxidation photocurrent magnitudes as compared to pure hematite thin films. Our results suggest that charge-compensated co-alloying is a plausible approach for engineering hematite for the application of PEC water splitting.

Tang, H.; Yin, W. J.; Matin, M. A.; Wang, H.; Deutsch, T.; Al-Jassim, M. M.; Turner, J. A.; Yan, Y.

2012-04-01T23:59:59.000Z

395

Highly oxidized superconductors  

DOE Patents (OSTI)

Novel superconducting materials in the form of compounds, structures or phases are formed by performing otherwise known synthesis in a highly oxidizing atmosphere rather than that created by molecular oxygen at atmospheric pressure or below. This leads to the successful synthesis of novel superconducting compounds which are thermodynamically stable at the conditions under which they are formed. 16 figs.

Morris, D.E.

1994-09-20T23:59:59.000Z

396

Highly oxidized superconductors  

DOE Patents (OSTI)

Novel superconducting materials in the form of compounds, structures or phases are formed by performing otherwise known syntheses in a highly oxidizing atmosphere rather than that created by molecular oxygen at atmospheric pressure or below. This leads to the successful synthesis of novel superconducting compounds which are thermodynamically stable at the conditions under which they are formed.

Morris, Donald E. (Kensington, CA)

1994-01-01T23:59:59.000Z

397

Hydrous oxide activated charcoal  

SciTech Connect

This patent describes a process for preparing of an ion exchanger, comprising: treating an ionically inert activated charcoal porous support with an aqueous solution of metal oxychloride selected from the group consisting of zirconium and titanium oxychlorides so as to impregnate the pores of the support with the solution; separating the treated support from excess metal oxychloride solution; converting the metal oxychloride to a hydrous metal oxide precipitate in the pores of the support at a pH above 8 and above the pH whereat the hydrous metal oxide and activated charcoal support have opposite zeta potentials and sufficient to hydrolyze the metal oxychloride. It also describes a process for preparing an ion exchanger comprising: treating granulated activated charcoal with a concentrated solution of a metal oxychloride from the group consisting of zirconium and titanium oxychlorides, degassing the mixture; and treating the resultant mixture with a base selected from the group consisting of ammonium hydroxide and alkali metal hydroxides so as to precipitate the oxychloride within the pores of the activated carbon granules as hydrous metal oxide at a pH above 8 and above the pH whereat the hydrous metal oxide and activated charcoal have opposite zeta potentials.

Weller, J.P.

1987-09-08T23:59:59.000Z

398

Doped zinc oxide microspheres  

DOE Patents (OSTI)

A new composition and method of making same for a doped zinc oxide microsphere and articles made therefrom for use in an electrical surge arrestor which has increased solid content, uniform grain size and is in the form of a gel. 4 figures.

Arnold, W.D. Jr.; Bond, W.D.; Lauf, R.J.

1993-12-14T23:59:59.000Z

399

ADVANCED OXIDATION PROCESS  

DOE Green Energy (OSTI)

The design of new, high efficiency and cleaner burning engines is strongly coupled with the removal of recalcitrant sulfur species, dibenzothiophene and its derivatives, from fuels. Oxidative desulfurization (ODS) wherein these dibenzothiophene derivatives are oxidized to their corresponding sulfoxides and sulfones is an approach that has gained significant attention. Fe-TAML{reg_sign} activators of hydrogen peroxide (TAML is Tetra-Amido-Macrocyclic-Ligand) convert in a catalytic process dibenzothiophene and its derivatives to the corresponding sulfoxides and sulfones rapidly at moderate temperatures (60 C) and ambient pressure. The reaction can be performed in both an aqueous system containing an alcohol (methanol, ethanol, or t-butanol) to solubilize the DBT and in a two-phase hydrocarbon/aqueous system where the alcohol is present in both phases and facilitates the oxidation. Under a consistent set of conditions using the FeBF{sub 2} TAML activator, the degree of conversion was found to be t-butanol > methanol > ethanol. In the cases of methanol and ethanol, both the sulfoxide and sulfone were observed while for t-butanol only the sulfone was detected. In the two-phase system, the alcohol may function as an inverse phase transfer agent. The oxidation was carried out using two different TAML activators. In homogeneous solution, approximately 90% oxidation of the DBT could be achieved using the prototype TAML activator, FeB*, by sonicating the solution at near room temperature. In bi-phasic systems conversions as high as 50% were achieved using the FeB* TAML activator and hydrogen peroxide at 100 C. The sonication method yielded only {approx}6% conversion but this may have been due to mixing.

Colin P. Horwitz; Terrence J. Collins

2003-10-22T23:59:59.000Z

400

Structure and composition of clean and hydrogen covered MoRe surfaces  

DOE Green Energy (OSTI)

The clean and hydrogen covered (100) and (110) faces of Mo{sub 0.75}Re{sub 0.23} alloy single crystals show 1x1 structures. By means of LEED structure analyses we have determined the interlayer distances as well as the layer concentrations down to the sixth layer. While the clean (110) surface turns out to be nearly bulklike terminated, the clean (100) face is found to exhibit both an extended oscillatory layer relaxation and composition profile. Hydrogen adsorption at low temperatures does not alter the composition profile and removes the small remaining relaxation for the (110) surface. In case of the (100) face a substancial reduction of the relaxation is observed for the outermost layer distances as well, while deeper layer relaxations are preserved indicating a strong coupling off relaxation and composition profiles. Hydrogen is found to adsorb in quasi-threefold coordinated sites for the (110) and bridge sites for the (100) face.

Hammer, L.; Meyer, S.; Rath, C. [and others

1995-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "mo magnesium oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Small-scale Specimen Testing of Monolithic U-Mo Fuel Foils  

SciTech Connect

The objective of this investigation is to develop a shear punch testing (SPT) procedure and standardize it to evaluate the mechanical properties of irradiated fuels in a hot-cell so that the tensile behavior can be predicted using small volumes of material and at greatly reduced irradiation costs. This is highly important in the development of low-enriched uranium fuels for nuclear research and test reactors. The load-displacement data obtained using SPT can be interpreted in terms of and correlated with uniaxial mechanical properties. In order to establish a correlation between SPT and tensile data, sub-size tensile and microhardness testing were performed on U-Mo alloys. In addition, efforts are ongoing to understand the effect of test parameters (such as specimen thickness, surface finish, punch-die clearance, crosshead velocity and carbon content) on the measured mechanical properties, in order to rationalize the technique, prior to employing it on a material of unknown strength.

Ramprashad Prabhakaran; Douglas E. Burkes; James I. Cole; Indrajit Charit; Daniel M. Wachs

2008-10-01T23:59:59.000Z

402

Synthesis and optical properties of MoS{sub 2} nanoclusters  

DOE Green Energy (OSTI)

Highly crystalline nanoclusters of MoS{sub 2} were synthesized and their optical absorption and photoluminescence spectra were investigated. Key results include: (1) strong quantum confinement effects with decreasing size; (2) preservation of the quasiparticle (or excitonic) nature of the optical response for clusters down to {approximately} 2.5 nm in size which are only two unit cells thick; (3) demonstration that 3-D confinement produces energy shifts which are over an order of magnitude larger than those due to 1-D confinement; (4) observation of large increases in the spin-orbit splittings at the top of the valence band at the K and M points of the Brillouin zone with decreasing cluster size; and (5) observation of photoluminescence due to both direct and surface recombination. Application is to photocatalysts for solar fuel production and detoxification of chemical waste.

Wilcoxon, J.P.; Newcomer, P.P.; Samara, G.A.

1996-12-01T23:59:59.000Z

403

Nuclear Sturcture Along the Neutron Dripline: MoNa-LISA and the dinueutron system  

Science Conference Proceedings (OSTI)

Nuclei with extreme neutron-to-proton ratios were found to present different structures from what was known for the stable ones. With the current facilities we can now study nuclei that lie even beyond the neutron drip line. At the National Superconducting Cyclotron Laboratory at Michigan State University we use the MoNA/Sweeper setup to perform such studies of neutron unbound nuclei. In a typical experiment, a radioactive beam is employed to produce the nucleus of interest. This unbound nucleus immediately decays into a neutron and a remaining charged fragment, both of which are detected and used to reconstruct the original nucleus and study its properties. In this Colloquium, new exciting findings from recent experiments will be presented. These include the first observation of a dineutron decay from 16Be, the exploration of the “south shore” of the Island of Inversion and the first evidence of the decay of the troubling nucleus 26O.

Spyou, Artemis [Michigan State Univeristy

2012-09-05T23:59:59.000Z

404

Thermodynamic modeling and experimental validation of the Fe-Al-Ni-Cr-Mo alloy system  

SciTech Connect

NiAl-type precipitate-strengthened ferritic steels have been known as potential materials for the steam turbine applications. In this study, thermodynamic descriptions of the B2-NiAl type nano-scaled precipitates and body-centered-cubic (BCC) Fe matrix phase for four alloys based on the Fe-Al-Ni-Cr-Mo system were developed as a function of the alloy composition at the aging temperature. The calculated phase structure, composition, and volume fraction were validated by the experimental investigations using synchrotron X-ray diffraction and atom probe tomography. With the ability to accurately predict the key microstructural features related to the mechanical properties in a given alloy system, the established thermodynamic model in the current study may significantly accelerate the alloy design process of the NiAl-strengthened ferritic steels.

Teng, Zhenke [ORNL; Zhang, F [CompuTherm LLC, Madison, WI; Miller, Michael K [ORNL; Liu, Chain T [Hong Kong Polytechnic University; Huang, Shenyan [ORNL; Chou, Y.T. [Multi-Phase Services Inc., Knoxville; Tien, R [Multi-Phase Services Inc., Knoxville; Chang, Y A [ORNL; Liaw, Peter K [University of Tennessee, Knoxville (UTK)

2012-01-01T23:59:59.000Z

405

Development and processing of LEU targets for {sup 99}Mo production  

SciTech Connect

Substituting LEU for HEU in targets for producing fission-product {sup 99}Mo requires changes in target design and chemical processing. We have made significant progress in developing targets and chemical processes for this purpose. Target development was concentrated on a U- metal foil target as a replacement for the coated-UO{sub 2} Cintichem- type target. Although the first designs were not successful because of ion mixing-induced bonding of the U foil to the target tubes, recent irradiations of modified targets have proven successful. It was shown that only minor modifications of the Cintichem chemical process are required for the U-metal foil targets. A demonstration using prototypically irradiated targets is anticipated by the end of 1996. Progress was also made in basic dissolution of both U-metal foil and Al-clad U{sub 3}Si{sub 2} dispersion fuel targets, and work in this area is also continuing.

Snelgrove, J.L.; Vandergrift, G.F.; Hofman, G.L.

1997-02-01T23:59:59.000Z

406

Lipid Oxidation Pathways, Volume 2  

Science Conference Proceedings (OSTI)

This book complements Lipid Oxidation Pathways, Volume 1. Lipid Oxidation Pathways, Volume 2 Health acid analysis aocs april articles chloropropanediol contaminants detergents dietary fats division divisions esters fats fatty food foods glycidol Health h

407

Cholesterol and Phytosterol Oxidation Products  

Science Conference Proceedings (OSTI)

This book comprehensively reviews several aspects of cholesterol oxidation products: cholesterol oxidation mechanisms, analytical determination, origin and content of these compounds in foods and biological samples, and their biological effects, with an em

408

Oxygen sensitive, refractory oxide composition  

DOE Patents (OSTI)

Oxide compositions containing niobium pentoxide and an oxide selected from the group consisting of hafnia, titania, and zirconia have electrical conductivity characteristics which vary greatly depending on the oxygen content.

Holcombe, Jr., Cressie E. (Oak Ridge, TN); Smith, Douglas D. (Knoxville, TN)

1976-01-01T23:59:59.000Z

409

THE MAGNESIUM ISOTOPOLOGUES OF MgH IN THE A {sup 2}{Pi}-X {sup 2}{Sigma}{sup +} SYSTEM  

Science Conference Proceedings (OSTI)

Using laboratory hollow cathode spectra we have identified lines of the less common magnesium isotopologues of MgH, {sup 25}MgH and {sup 26}MgH, in the A {sup 2}{Pi}-X {sup 2}{Sigma}{sup +} system. Based on the previous analysis of {sup 24}MgH, molecular lines have been measured and molecular constants derived for {sup 25}MgH and {sup 26}MgH. Term values and linelists, in both wavenumber and wavelength units, are presented. The A {sup 2}{Pi}-X {sup 2}{Sigma}{sup +} system of MgH is important for measuring the magnesium isotope ratios in stars. Examples of analysis using the new linelists to derive the Mg isotope ratio in a metal poor dwarf and giant are shown.

Hinkle, Kenneth H.; Wallace, Lloyd [National Optical Astronomy Observatories, P.O. Box 26732, Tucson, AZ 85726 (United States); Ram, Ram S.; Bernath, Peter F. [Department of Chemistry, University of York, Heslington, York YO10 5DD (United Kingdom); Sneden, Christopher [Department of Astronomy, University of Texas at Austin, Austin, TX 78712 (United States); Lucatello, Sara, E-mail: hinkle@noao.edu, E-mail: wallace@noao.edu, E-mail: rr662@york.ac.uk, E-mail: pbernath@odu.edu, E-mail: chris@verdi.as.utexas.edu, E-mail: sara.lucatello@oapd.inaf.it [INAF, Osservatorio Astronomico di Padova, Vicolo dell'Osservatorio 5, I-35122 Padova (Italy)

2013-08-15T23:59:59.000Z

410

Microstructural characterization of as-cast biocompatible Co-Cr-Mo alloys  

SciTech Connect

The microstructure of a cobalt-base alloy (Co-Cr-Mo) obtained by the investment casting process was studied. This alloy complies with the ASTM F75 standard and is widely used in the manufacturing of orthopedic implants because of its high strength, good corrosion resistance and excellent biocompatibility properties. This work focuses on the resulting microstructures arising from samples poured under industrial environment conditions, of three different Co-Cr-Mo alloys. For this purpose, we used: 1) an alloy built up from commercial purity constituents, 2) a remelted alloy and 3) a certified alloy for comparison. The characterization of the samples was achieved by using optical microscopy (OM) with a colorant etchant to identify the present phases and scanning electron microscopy (SE-SEM) and energy dispersion spectrometry (EDS) techniques for a better identification. In general the as-cast microstructure is a Co-fcc dendritic matrix with the presence of a secondary phase, such as the M{sub 23}C{sub 6} carbides precipitated at grain boundaries and interdendritic zones. These precipitates are the main strengthening mechanism in this type of alloys. Other minority phases were also reported and their presence could be linked to the cooling rate and the manufacturing process variables and environment. - Research Highlights: {yields}The solidification microstructure of an ASTM-F75 type alloy were studied. {yields}The alloys were poured under an industrial environment. {yields}Carbides and sigma phase identified by color metallography and scanning microscopy (SEM and EDS). {yields}Two carbide morphologies were detected 'blocky type' and 'pearlite type'. {yields}Minority phases were also detected.

Giacchi, J.V., E-mail: jgiacchi@exa.unicen.edu.ar [Consejo Nacional de Investigaciones Cientificas y Tecnicas (CONICET), Av. Rivadavia 1917, C1033AAJ Buenos Aires (Argentina); Instituto de Fisica de Materiales Tandil (IFIMAT-FCE-CICPBA) Facultad de Ciencias Exactas, Universidad Nacional del Centro de la Provincia de Buenos Aires, Pinto 399 B7000GHG Tandil (Argentina); Morando, C.N.; Fornaro, O. [Consejo Nacional de Investigaciones Cientificas y Tecnicas (CONICET), Av. Rivadavia 1917, C1033AAJ Buenos Aires (Argentina); Instituto de Fisica de Materiales Tandil (IFIMAT-FCE-CICPBA) Facultad de Ciencias Exactas, Universidad Nacional del Centro de la Provincia de Buenos Aires, Pinto 399 B7000GHG Tandil (Argentina); Palacio, H.A. [Comision de Investigaciones Cientificas de la Provincia de Buenos Aires (CICPBA), Calle 526 e/10 y 11 B1096APP La Plata (Argentina); Instituto de Fisica de Materiales Tandil (IFIMAT-FCE-CICPBA) Facultad de Ciencias Exactas, Universidad Nacional del Centro de la Provincia de Buenos Aires, Pinto 399 B7000GHG Tandil (Argentina)

2011-01-15T23:59:59.000Z

411

NUMERICAL SIMULATION FOR MECHANICAL BEHAVIOR OF U10MO MONOLITHIC MINIPLATES FOR RESEARCH AND TEST REACTORS  

Science Conference Proceedings (OSTI)

This article presents assessment of the mechanical behavior of U-10wt% Mo (U10Mo) alloy based monolithic fuel plates subject to irradiation. Monolithic, plate-type fuel is a new fuel form being developed for research and test reactors to achieve higher uranium densities within the reactor core to allow the use of low-enriched uranium fuel in high-performance reactors. Identification of the stress/strain characteristics is important for understanding the in-reactor performance of these plate-type fuels. For this work, three distinct cases were considered: (1) fabrication induced residual stresses (2) thermal cycling of fabricated plates; and finally (3) transient mechanical behavior under actual operating conditions. Because the temperatures approach the melting temperature of the cladding during the fabrication and thermal cycling, high temperature material properties were incorporated to improve the accuracy. Once residual stress fields due to fabrication process were identified, solution was used as initial state for the subsequent simulations. For thermal cycling simulation, elasto-plastic material model with thermal creep was constructed and residual stresses caused by the fabrication process were included. For in-service simulation, coupled fluid-thermal-structural interaction was considered. First, temperature field on the plates was calculated and this field was used to compute the thermal stresses. For time dependent mechanical behavior, thermal creep of cladding, volumetric swelling and fission induced creep of the fuel foil were considered. The analysis showed that the stresses evolve very rapidly in the reactor. While swelling of the foil increases the stress of the foil, irradiation induced creep causes stress relaxation.

Hakan Ozaltun & Herman Shen

2011-11-01T23:59:59.000Z

412

Development of an energy-use estimation methodology for the revised Navy Manual MO-303  

SciTech Connect

The U.S. Navy commissioned Pacific Northwest Laboratory (PNL) to revise and/or update the Navy Utilities Targets Manual, NAVFAC MO-303 (U.S. Navy 1972b). The purpose of the project was to produce a current, applicable, and easy-to-use version of the manual for use by energy and facility engineers and staff at all Navy Public Works Centers (PWCs), Public Works Departments (PWDs), Engineering Field Divisions (EFDs), and other related organizations. The revision of the MO-303 manual involved developing a methodology for estimating energy consumption in buildings and ships. This methodology can account for, and equitably allocate, energy consumption within Navy installations. The analyses used to develop this methodology included developing end-use intensities (EUIs) from a vast collection of Navy base metering and billing data. A statistical analysis of the metering data, weather data, and building energy-use characteristics was used to develop appropriate EUI values for use at all Navy bases. A complete Navy base energy reconciliation process was also created for use in allocating all known energy consumption. Initial attempts to use total Navy base consumption values did not produce usable results. A parallel effort using individual building consumption data provided an estimating method that incorporated weather effects. This method produced a set of building EUI values and weather adjustments for use in estimating building energy use. A method of reconciling total site energy consumption was developed based on a {open_quotes}zero-sum{close_quotes} principle. This method provides a way to account for all energy use and apportion part or all of it to buildings and other energy uses when actual consumption is not known. The entire text of the manual was also revised to present a more easily read understood and usable document.

Richman, E.E.; Keller, J.M.; Wood, A.G.; Dittmer, A.L.

1995-01-01T23:59:59.000Z

413

Role of Si on the Diffusional Interactions between U-Mo and Al-Si Alloys at 823 K (550 degrees C)  

Science Conference Proceedings (OSTI)

U-Mo dispersions in Al-alloy matrix and monolithic fuels encased in Al-alloy are under development to fulfill the requirements for research and test reactors to use low-enriched molybdenum stabilized uranium alloys fuels. Significant interaction takes place between the U-Mo fuel and Al during manufacturing and in-reactor irradiation. The interactions products are Al-rich phases with physical and thermal characteristics that adversely affect fuel performance and lead to premature failure. Detailed analysis of the interdiffusion and microstructural development of this system was carried through diffusion couples consisting of U-7wt.%Mo, U-10wt.%Mo and U-12wt.%Mo in contact with pure Al, Al-2wt.%Si, and Al-5wt.%Si, annealed at 823K for 1, 5 and 20 hours. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were employed for the analysis. Diffusion couples consisting of U-Mo vs. pure Al contained UAl3, UAl4, U6Mo4Al43, and UMo2Al20 phases. The addition of Si to the Al significantly reduced the thickness of the interdiffusion zone. The interdiffusion zones developed Al and Si enriched regions, whose locations and size depended on the Si and Mo concentrations in the terminal alloys. In the couples, the (U,Mo)(Al,Si)3 phase was observed throughout interdiffusion zone, and the U6Mo4Al43 and UMo2Al20 phases were observed only where the Si concentrations were low.

E. Perez; Y.H. Sohn; D.D. Keiser, Jr.

2013-01-01T23:59:59.000Z

414

Low temperature plasma enhanced chemical vapor deposition of silicon oxide films using disilane and nitrous oxide  

Science Conference Proceedings (OSTI)

Keywords: disilane, low temperature, nitrous oxide, plasma enhanced chemical vapor deposition, silicon oxide

Juho Song; G. S. Lee; P. K. Ajmera

1995-10-01T23:59:59.000Z

415

Characterization of the Microstructure of Irradiated U-Mo Dispersion Fuel with a Matrix that Contains Si  

SciTech Connect

RERTR U-Mo dispersion fuel plates are being developed for application in research reactors throughout the world. Of particular interest is the irradiation performance of U-Mo dispersion fuels with Si added to the Al matrix. Si is added to improve the performance of U-Mo dispersion fuels. Microstructural examinations have been performed on fuel plates with Al-2Si matrix after irradiation to around 50% LEU burnup. Si-rich layers were observed in many areas around the various U-7Mo fuel particles. In one local area of one of the samples, where the Si-rich layer had developed into a layer devoid of Si, relatively large fission gas bubbles were observed in the interaction phase. There may be a connection between the growth of these bubbles and the amount of Si present in the interaction layer. Overall, it was found that having Si-rich layers around the fuel particles after fuel plate fabrication positively impacted the overall performance of the fuel plate.

D. D. Keiser, Jr.; A. B. Robinson; J. F. Jue; P. Medvedev; M. R. Finlay

2009-03-01T23:59:59.000Z

416

Characterization and Hydrodesulfurization Activity of CoMo Catalysts Supported on Boron-Doped Sol-Gel Alumina  

E-Print Network (OSTI)

desulfurization character of the CoMo catalysts supported on the B- Al2O3 supports, because high hydrogenation, the catalysts were kept in a closed vessel during two hours for aging, and then dried overnight in an oven.29 in the HDS of Kuwait gas oil [14], heavy Kuwait residue oil [15], and Kuwait crude oil [25]. They correlated

Paris-Sud XI, Université de

417

Determining the Specificity of Terms based on Information Theoretic Pum-Mo Ryu and Key-Sun Choi  

E-Print Network (OSTI)

Determining the Specificity of Terms based on Information Theoretic Measures Pum-Mo Ryu and Key@world.kaist.ac.kr, kschoi@world.kaist.ac.kr Abstract This paper introduces new specificity determining methods for terms based on information theoretic measures. The specificity of terms represents the quantity of domain

418

Gd/sub 2/ (MoO/sub 4/)/sub 3/ longitudinal electrooptic modulator at 6328 A  

SciTech Connect

A Gd/sub 2/(MoO/sub 4/)/sub 3/ light modulator operating at low frequencies, from 100 Hz up to 1 MHz, is examined. Experimental results concerning the thermal behavior and stability, frequency response, and linearity performance characteristics of the system are presented. Advantages and disadvantages of the modulator are discussed.

Theophanous, N.G.

1976-08-01T23:59:59.000Z

419

REVIEW OF PLUTONIUM OXIDATION LITERATURE  

Science Conference Proceedings (OSTI)

A brief review of plutonium oxidation literature was conducted. The purpose of the review was to ascertain the effect of oxidation conditions on oxide morphology to support the design and operation of the PDCF direct metal oxidation (DMO) furnace. The interest in the review was due to a new furnace design that resulted in oxide characteristics that are different than those of the original furnace. Very little of the published literature is directly relevant to the DMO furnace operation, which makes assimilation of the literature data with operating conditions and data a convoluted task. The oxidation behavior can be distilled into three regimes, a low temperature regime (RT to 350 C) with a relatively slow oxidation rate that is influenced by moisture, a moderate temperature regime (350-450 C) that is temperature dependent and relies on more or less conventional oxidation growth of a partially protective oxide scale, and high temperature oxidation (> 500 C) where the metal autocatalytically combusts and oxidizes. The particle sizes obtained from these three regimes vary with the finest being from the lowest temperature. It is surmised that the slow growth rate permits significant stress levels to be achieved that help break up the oxides. The intermediate temperatures result in a fairly compact scale that is partially protective and that grows to critical thickness prior to fracturing. The growth rate in this regime may be parabolic or paralinear, depending on the oxidation time and consequently the oxide thickness. The high temperature oxidation is invariant in quiescent or nearly quiescent conditions due to gas blanketing while it accelerates with temperature under flowing conditions. The oxide morphology will generally consist of fine particles ( 250 {micro}m). The particle size ratio is expected to be < 5%, 25%, and 70% for fine, medium and large particles, respectively, for metal temperatures in the 500-600 C range.

Korinko, P.

2009-11-12T23:59:59.000Z

420

REVIEW OF PLUTONIUM OXIDATION LITERATURE  

SciTech Connect

A brief review of plutonium oxidation literature was conducted. The purpose of the review was to ascertain the effect of oxidation conditions on oxide morphology to support the design and operation of the PDCF direct metal oxidation (DMO) furnace. The interest in the review was due to a new furnace design that resulted in oxide characteristics that are different than those of the original furnace. Very little of the published literature is directly relevant to the DMO furnace operation, which makes assimilation of the literature data with operating conditions and data a convoluted task. The oxidation behavior can be distilled into three regimes, a low temperature regime (RT to 350 C) with a relatively slow oxidation rate that is influenced by moisture, a moderate temperature regime (350-450 C) that is temperature dependent and relies on more or less conventional oxidation growth of a partially protective oxide scale, and high temperature oxidation (> 500 C) where the metal autocatalytically combusts and oxidizes. The particle sizes obtained from these three regimes vary with the finest being from the lowest temperature. It is surmised that the slow growth rate permits significant stress levels to be achieved that help break up the oxides. The intermediate temperatures result in a fairly compact scale that is partially protective and that grows to critical thickness prior to fracturing. The growth rate in this regime may be parabolic or paralinear, depending on the oxidation time and consequently the oxide thickness. The high temperature oxidation is invariant in quiescent or nearly quiescent conditions due to gas blanketing while it accelerates with temperature under flowing conditions. The oxide morphology will generally consist of fine particles (<15 {micro}m), moderately sized particles (15 < x < 250 {micro}m) and large particles (> 250 {micro}m). The particle size ratio is expected to be < 5%, 25%, and 70% for fine, medium and large particles, respectively, for metal temperatures in the 500-600 C range.

Korinko, P.

2009-11-12T23:59:59.000Z

Note: This page contains sample records for the topic "mo magnesium oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Multifunctional Oxide - Programmaster.org  

Science Conference Proceedings (OSTI)

Toshihiko Tani, Toyota Motor Engineering and Manufacturing North America, Inc. Scope, Multifunctional oxide ceramics and thin films exhibit fascinating ...

422

Selective methane oxidation over promoted oxide catalysts  

DOE Green Energy (OSTI)

Principal accomplishments have been achieved in all three areas of selective catalytic oxidation of methane that have been pursued in this research project. These accomplishments are centered on the development of catalyst systems that produce high space time yields of C{sub 2} hydrocarbon products, formaldehyde, and methanol from methane/air mixtures at moderate temperatures and at ambient pressure. The accomplishments can be summarized as the following: the SO{sub 4}{sup 2{minus}}/SrO/La{sub 2}O{sub 3} catalyst developed here has been further optimized to produce 2 kg of C{sub 2} hydrocarbons/kg catalyst/hr at 550C; V{sub 2}O{sub 5}SiO{sub 2} catalysts have been prepared that produce up to 1.5 kg formaldehyde/kg catalyst/hr at 630C with CO{sub 2} selectivities; and a novel dual bed catalyst system has been designed and tested that produces over 100 g methanol/kg catalyst/hr at 600C.

Klier, K.; Herman, R.G.

1995-06-01T23:59:59.000Z

423

Oxides for Spintronics - Programmaster.org  

Science Conference Proceedings (OSTI)

About this Abstract. Meeting, Materials Science & Technology 2013. Symposium, Multifunctional Oxides. Presentation Title, Oxides for Spintronics. Author(s) ...

424

MESOPOROUS METAL OXIDE MICROSPHERE ELECTRODE COMPOSITIONS AND ...  

Compositions and methods of making are provided for mesoporous metal oxide microspheres electrodes. The mesoporous metal oxide microsphere ...

425

Controlled CO preferential oxidation  

DOE Green Energy (OSTI)

Method for controlling the supply of air to a PROX reactor for the preferential oxidation in the presence of hydrogen wherein the concentration of the hydrogen entering and exiting the PROX reactor is monitored, the difference therebetween correlated to the amount of air needed to minimize such difference, and based thereon the air supply to the PROX reactor adjusted to provide such amount and minimize such difference.

Meltser, Mark A. (Pittsford, NY); Hoch, Martin M. (Webster, NY)

1997-01-01T23:59:59.000Z

426

Chemical oxidizers treat wastewater  

SciTech Connect

Based on the inherent benefits of these original oxidation systems, a second generation of advanced oxidation processes (AOPs) has emerged. These processes combine key features of the first generation technologies with more sophisticated advances in UV technology, such as the new pulsed plasma xenon flash lamp that emits high-energy, high-intensity UV light. Second generation systems can be equipped with a transmittance controller to prevent lamp fouling or scaling. The coupling of the first generation's technology with the new UV sources provides the rapid destruction of chlorinated and nonchlorinated hydrocarbons and humic acids from contaminated water. It also is effective in the treatment of organic laden gases from soil vapor extraction systems. AOPs may promote the oxidation (and subsequent removal) of heavy metals in water, though few data are available to verify the claim. The success of AOPs, including ozonation with UV light, hydrogen peroxide with UV light and advanced photolysis, is linked with their creation of hydroxyl-free radicals (OH[center dot]) that are effective in eliminating contaminants such as formaldehyde, chlorinated hydrocarbons and chlorinated solvents. Hydroxyl free-radicals are consumed in microsecond reactions and exhibit little substrate selectivity with the exception of halogenated alkanes such as chloroform. They can act as chain carriers. Given their power, hydroxyl free-radicals react with virtually all organic solutes more quickly (especially in water) than any other oxidants, except fluorine. There are projects that have found the combination of some AOPs to be the most efficient organic destruction techniques for the job. For example, one project successfully remediated groundwater contaminated with gasoline and Number 2 diesel through successive treatments of ozone and hydrogen peroxide with ultraviolet light, followed by granular activated carbon. 5 refs., 2 tabs.

Stephenson, F.A. (Dames Moore, Phoenix, AZ (United States))

1992-12-01T23:59:59.000Z

427

Applications of Oxide Superconductors  

Science Conference Proceedings (OSTI)

The discovery of the new family of copper-oxide superconductors has opened an area of exciting new materials science with enormous potential for practical developments in technology and engineering. Research was conducted to understand the basic physical properties and the materials characteristics of the high temperature superconductors that control their electrical and mechanical properties, and determine their potential usefulness. Material properties and current carrying capabilites of the new Bismut...

1993-09-29T23:59:59.000Z

428

Solid Oxide Fuel Cells  

Science Conference Proceedings (OSTI)

Solid oxide fuel cell (SOFC) technology, which offers many advantages over traditional energy conversion systems including low emission and high efficiency, has become increasingly attractive to the utility, automotive, and defense industries (as shown in Figure 1). As an all solid-state energy conversion device, the SOFC operates at high temperatures (700-1,000 C) and produces electricity by electrochemically combining the fuel and oxidant gases across an ionically conducting oxide membrane. To build up a useful voltage, a number of cells or PENs (Positive cathode-Electrolyte-Negative anode) are electrically connected in series in a stack through bi-polar plates, also known as interconnects. Shown in Figure 2 (a) is a schematic of the repeat unit for a planar stack, which is expected to be a mechanically robust, high power-density and cost-effective design. In the stack (refer to Figure 2 (b)), the interconnect is simultaneously exposed to both an oxidizing (air) environment on the cathode side and a reducing (fuels such as hydrogen or natural gas) environment on the anode side for thousands of hours at elevated temperatures (700-1,000 C). Other challenges include the fact that water vapor is likely to be present in both of these environments, and the fuel is likely to contain sulfide impurities. Also, the interconnect must be stable towards any sealing materials with which it is in contact, under numerous thermal cycles. Furthermore, the interconnect must also be stable towards electrical contact materials that are employed to minimize interfacial contact resistance, and/or the electrode materials. Considering these service environments, the interconnect materials should possess the following properties: (1) Good surface stability (resistance to oxidation and corrosion) in both cathodic (oxidizing) and anodic (reducing) atmospheres. (2) Thermal expansion matching to the ceramic PEN and other adjacent components, all of which typically have a coefficient of thermal expansion (CTE) in the range of 10.5-12.0 x 10{sup -6} K{sup -1}. (3) High electrical conductivity through both the bulk material and in-situ formed oxide scales. (4) Satisfactory bulk and interfacial mechanical/thermomechanical reliability and durability at the SOFC operating temperatures. (5) Good compatibility with other materials in contact with interconnects such as seals and electrical contact materials. Until recently, the leading candidate material for the interconnect was doped lanthanum chromite (LaCrO3), which is a ceramic material which can easily withstand the traditional 1000 C operating temperature. However, the high cost of raw materials and fabrication, difficulties in obtaining high-density chromite parts at reasonable sintering temperatures, and the tendency of the chromite interconnect to partially reduce at the fuel gas/interconnect interface, causing the component to warp and the peripheral seal to break, have plagued the commercialization of planar SOFCs for years. The recent trend in developing lower temperature, more cost-effective cells which utilize anode-supported, several micron-thin electrolytes and/or new electrolytes with improved conductivity make it feasible for lanthanum chromite to be supplanted by metals or alloys as the interconnect materials. Compared to doped lanthanum chromite, metals or alloys offer significantly lower raw material and fabrication costs.

Yang, Z Gary; Stevenson, Jeffry W.; Singh, Prabhakar

2003-06-15T23:59:59.000Z

429

Characterization of High Strain Rate Mechanical behavior of AZ31 magnesium alloy using 3D Digital Image Correlation  

Science Conference Proceedings (OSTI)

Characterization of the material mechanical behavior at sub-Hopkinson regime (0.1 to 1000 s{sup -1}) is very challenging due to instrumentation limitations and the complexity of data analysis involved in dynamic loading. In this study, AZ31 magnesium alloy sheet specimens are tested using a custom designed servo-hydraulic machine in tension at nominal strain rates up to 1000 s{sup -1}. In order to resolve strain measurement artifacts, the specimen displacement is measured using 3D Digital Image correlation instead from actuator motion. The total strain is measured up to {approx} 30%, which is far beyond the measurable range of electric resistance strain gages. Stresses are calculated based on the elastic strains in the tab of a standard dog-bone shaped specimen. Using this technique, the stresses measured for strain rates of 100 s{sup -1} and lower show little or no noise comparing to load cell signals. When the strain rates are higher than 250 s{sup -1}, the noises and oscillations in the stress measurements are significantly decreased from {approx} 250 to 50 MPa. Overall, it is found that there are no significant differences in the elongation, although the material exhibits slight work hardening when the strain rate is increased from 1 to 100 s{sup -1}.

Wang, Yanli [ORNL; Xu, Hanbing [ORNL; ERDMAN III, DONALD L [ORNL; Starbuck, J Michael [ORNL; Simunovic, Srdjan [ORNL

2011-01-01T23:59:59.000Z

430

Inconel Inert Anode Current Collector for Solid Oxide Membrane  

Science Conference Proceedings (OSTI)

Abstract Scope, An innovative inert anode current collector is successfully developed and ... During electrolysis at 1423 K, magnesium cations in the flux are reduced at a ... Inclusions from Molten Steel Using a High Frequency Magnetic Field.

431

Effect of Electronic Current on the Solid Oxide Membrane (Som)  

Science Conference Proceedings (OSTI)

During electrolysis, magnesium ions are reduced at the cathode and Mg(g) bubbles out of the flux into a separate condenser. The flux has a small solubility for ...

432

Adsorption of Potassium on the MoS2(100) Surface: A First-Principles Investigation  

DOE Green Energy (OSTI)

Periodic density functional theory calculations were performed to investigate the interaction that potassium with the Mo and S edges of the MoS2(100) surface. Both neutral and cationic (+1) charged potassium-promoted systems at different sulfur coverages were considered. Our calculations indicate that the potassium atom readily donates its single 4s valence electron to the MoS2 structure for the neutral potassium-promoted system, and the neutral and cationic potassium-promoted systems demonstrate a similar adsorption behavior. Moreover, potassium changes the magnetic properties known to occur at the metallic edge surface, which have implications for electron spin dependent surface characterization methods (i.e., electron spin/paramagnetic spectroscopy). Potassium in both the neutral and cationic systems tends to maximize its interactions with the available sulfur atoms at the edge surface, preferring sites over four-fold S hollows on fully sulfided Mo and S edges and over the interstitial gap where two to four edge surface S atoms are available for coordination. As the potassium coverage increases, the adsorption energy per potassium atom, surface work function, and transfer of the K 4s electron to the MoS2(100) surface decreases, which is in line with an increased metallization of the potassium adlayer. The potassium adlayer tends to form chains along the interstitial with K-K distances ~1 Ć, which is notably less than those of bulk bcc K metal (4.61 Ć). Density of states for the potassium-saturated surface suggests enhanced involvement of broad K 3d states beginning just above the Fermi level. Potassium-promotion of MoS2(100) has implications for alcohol catalysis: increasing the surface basicity by increasing the electron charge of the surface, providing hydrogenation-promoting CO site, blocking edge surface that dissociate CO and lead to methanation, and limiting H2 dissociative adsorption to the edge surface and possibly inhibiting the H2 dissociative adsorption via s character electron repulsion. This research was performed in part using the Molecular Science Computing Facility in the William R. Wiley Environmental Molecular Sciences Laboratory, a U.S. Department of Energy (DOE) national scientific user facility located at the Pacific Northwest National Laboratory (PNNL). PNNL is operated by Battelle for DOE.

Andersen, Amity; Kathmann, Shawn M.; Lilga, Michael A.; Albrecht, Karl O.; Hallen, Richard T.; Mei, Donghai

2011-04-15T23:59:59.000Z

433

Investigating the First-Cycle Irreversibility of Lithium Metal Oxide Cathodes for Li Batteries  

DOE Green Energy (OSTI)

Layered lithium metal oxide cathodes typically exhibit irreversibility during the first cycle in lithium cells when cycled in conventional voltage ranges (e.g., 3-4.3 V vs. Li+/Li). In this work, we have studied the first-cycle irreversibility of lithium cells containing various layered cathode materials using galvanostatic cycling and in situ synchrotron X-ray diffraction. When cycled between 3.0 and 4.3 V vs. Li+/Li, the cells containing LiCoO2, LiNi0.8Co0.15Al0.05O2, and Li1.048(Ni1/3Co1/3Mn1/3)0.952O2 as cathodes showed initial coulombic efficiencies of 98.0, 87.0, and 88.6%, respectively, at relatively slow current (8 mA/g). However, the 'lost capacity' could be completely recovered by discharging the cells to low voltages (<2 V vs Li+/Li). During this deep discharge, the same cells exhibited voltage plateaus at 1.17, 1.81, and 1.47 V, respectively, which is believed to be associated with formation of a Li2MO2-like phase (M = Ni, Co, Mn) on the oxide particle surface due to very sluggish lithium diffusion in LieMO2 with {var_epsilon}{yields} 1 (i.e., near the end of discharge). The voltage relaxation curve and in situ X-ray diffraction patterns, obtained from a Li/Li1.048(Ni1/3Co1/3Mn1/3)0.952O2 cell, showed that the oxide cathode reversibly returned to its original state [i.e., Li1.048(Ni1/3Co1/3Mn1/3)0.952O2] during relaxation following the deep discharge to achieve 100% cycle efficiency.

Kang,S.; Yoon , W.; Nam, K.; Yang, X.; Abraham, D.

2008-01-01T23:59:59.000Z

434

Magnesium: Digital Resource Center - BOOK: Magnesium ...  

Science Conference Proceedings (OSTI)

Feb 9, 2007 ... Presents papers related to primary production and market; recycling and environmental issues; alloy development; phase transformations; ...

435

Microstructural evolution during solution treatment of Co-Cr-Mo-C biocompatible alloys  

SciTech Connect

Three different Co-Cr-Mo-C alloys conforming to ASTM F75 standard were poured in an industrial environment and subjected to a conventional solution treatment at 1225 Degree-Sign C for several time intervals. The microstructural changes and transformations were studied in each case in order to evaluate the way in which treatment time influences the secondary phase fraction and clarify the microstructural changes that could occur. To assess how treatment time affects microstructure, optical microscopy and image analyzer software, scanning electron microscopy and energy dispersion spectrometry analysis were employed. The main phases detected in the as-cast state were: {sigma}-phase, M{sub 6}C, and M{sub 23}C{sub 6} carbides. The latter presented two different morphologies, blocky type and lamellar type. Despite being considered the most detrimental feature to mechanical properties, {sigma}-phase and lamellar carbides dissolution took place in the early stages of solution treatment. M{sub 23}C{sub 6} carbides featured two different behaviors. In the alloy obtained by melting an appropriate quantity of alloyed commercial materials, a decrease in size, spheroidization and transformation into M{sub 6}C carbides were simultaneously observed. In the commercial ASTM F75 alloy, in turn, despite being the same phase, only a marked decrease in precipitates size was noticed. These different behaviors could be ascribed to the initial presence of other phases in the alloy obtained from alloyed materials, such as {sigma}-phase and 'pearlitic' carbides, or to the initial precipitate size which was much larger in the first than in the commercial ASTM F75 alloy studied. M{sub 6}C carbides dissolved directly in the matrix as they could not be detected in samples solution-treated for 15 min. - Highlights: Black-Right-Pointing-Pointer Three different Co-Cr-Mo alloys were poured under an industrial environment. Black-Right-Pointing-Pointer Transformation of existing phases followed during conventional solution treatment. Black-Right-Pointing-Pointer In as-cast/treated samples, phases were identified by color metallography, SEM and EDS. Black-Right-Pointing-Pointer M{sub 23}C{sub 6} {yields} M{sub 6}C transformation was corroborated by SEM and EDS analysis. Black-Right-Pointing-Pointer Carbide spheroidization was also detected prior a noticeably carbide size decreasing.

Giacchi, J.V., E-mail: jgiacchi@exa.unicen.edu.ar [IFIMAT, Instituto de Fisica de Materiales Tandil, Facultad de Ciencias Exactas, Universidad Nacional del Centro de la Provincia de Buenos Aires, Pinto 399, B7000GHG Tandil (Argentina); Consejo Nacional de Investigaciones Cientificas y Tecnicas (CONICET), Av. Rivadavia 1917, C1033AA, Buenos Aires (Argentina); Fornaro, O. [IFIMAT, Instituto de Fisica de Materiales Tandil, Facultad de Ciencias Exactas, Universidad Nacional del Centro de la Provincia de Buenos Aires, Pinto 399, B7000GHG Tandil (Argentina); Consejo Nacional de Investigaciones Cientificas y Tecnicas (CONICET), Av. Rivadavia 1917, C1033AA, Buenos Aires (Argentina); Palacio, H. [IFIMAT, Instituto de Fisica de Materiales Tandil, Facultad de Ciencias Exactas, Universidad Nacional del Centro de la Provincia de Buenos Aires, Pinto 399, B7000GHG Tandil (Argentina); Comision de Investigaciones Cientificas de la Provincia de Buenos Aires (CICPBA), Calle 526 e/10 y 11, B1096APP, La Plata (Argentina)

2012-06-15T23:59:59.000Z

436

Oxidation resistant alloys, method for producing oxidation resistant alloys  

DOE Patents (OSTI)

A method for producing oxidation-resistant austenitic alloys for use at temperatures below 800 C. comprising of: providing an alloy comprising, by weight %: 14-18% chromium, 15-18% nickel, 1-3% manganese, 1-2% molybdenum, 2-4% silicon, 0% aluminum and the balance being iron; heating the alloy to 800 C. for between 175-250 hours prior to use in order to form a continuous silicon oxide film and another oxide film. The method provides a means of producing stainless steels with superior oxidation resistance at temperatures above 700 C. at a low cost

Dunning, John S.; Alman, David E.

2002-11-05T23:59:59.000Z

437

Selective Oxidation of Organic Substrates to Partially Oxidized Products  

controlled rate of catalysis, utilizing ozone for oxidation of alcohols to ketones or aldehydes, is made possible with this environmentally friendly and versatile technology.

438

Ultra supercritical steamside oxidation  

SciTech Connect

Ultra supercritical (USC) power plants offer the promise of higher efficiencies and lower emissions, which are part of the U.S. Department of Energy's Vision 21 goals. Most current coal power plants in the U.S. operate at a maximum steam temperature of 538 C. However, new supercritical plants worldwide are being brought into service with steam temperatures of up to 620 C. Vision 21 goals include steam temperatures of up to 760 C. This research examines the steamside oxidation of advanced alloys for use in USC systems. Emphasis is placed on alloys for high- and intermediate-pressure turbine sections. Initial results of this research are presented.

Holcomb, Gordon R.; Covino, Bernard S., Jr.; Bullard, Sophie J.; Cramer, Stephen D.; Ziomek-Moroz, M.; Alman, David A.; Ochs, Thomas L.

2004-01-01T23:59:59.000Z

439

PLATES WITH OXIDE INSERTS  

DOE Patents (OSTI)

Planar-type fuel assemblies for nuclear reactors are described, particularly those comprising fuel in the oxide form such as thoria and urania. The fuel assembly consists of a plurality of parallel spaced fuel plate mennbers having their longitudinal side edges attached to two parallel supporting side plates, thereby providing coolant flow channels between the opposite faces of adjacent fuel plates. The fuel plates are comprised of a plurality of longitudinally extending tubular sections connected by web portions, the tubular sections being filled with a plurality of pellets of the fuel material and the pellets being thermally bonded to the inside of the tubular section by lead.

West, J.M.; Schumar, J.F.

1958-06-10T23:59:59.000Z

440

PREPARATION OF REFRACTORY OXIDE MICROSPHERE  

DOE Patents (OSTI)

A method is described of preparing thorium oxide in the form of fused spherical particles about 1 to 2 microns in diameter. A combustible organic solution of thorium nitrate containing additive metal values is dispersed into a reflected, oxygen-fed flame at a temperature above the melting point of the resulting oxide. The metal additive is aluminum at a proportion such as to provide 1 to 10 weight per cent aluminum oxide in the product, silicon at the same proportion, or beryllium at a proportion of 12 to 25 weight per cent beryllium oxide in the product. A minor proportion of uranium values may also be provided in the solution. The metal additive lowers the oxide melting point and allows fusion and sphere formation in conventional equipment. The product particles are suitable for use in thorium oxide slurries for nuclear reactors. (AEC)

Haws, C.C. Jr.

1963-09-24T23:59:59.000Z

Note: This page contains sample records for the topic "mo magnesium oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Materials System for Intermediate Temperature Solid Oxide Fuel Cell  

DOE Green Energy (OSTI)

AC complex impedance spectroscopy studies were conducted between 600-800 C on symmetrical cells that employed strontium-and-magnesium-doped lanthanum gallate electrolyte, La{sub 0.9}Sr{sub 0.1}Ga{sub 0.8}Mg{sub 0.2}O{sub 3} (LSGM). The objective of the study was to identify the materials system for fabrication and evaluation of intermediate temperature (600-800 C) solid oxide fuel cells (SOFCs). The slurry-coated electrode materials had fine porosity to enhance catalytic activity. Cathode materials investigated include La{sub 1-x}Sr{sub x}MnO{sub 3} (LSM), LSCF (La{sub 1-x}Sr{sub x}Co{sub y}Fe{sub 1-y}O{sub 3}), a two-phase particulate composite consisting of LSM-doped-lanthanum gallate (LSGM), and LSCF-LSGM. The anode materials were Ni-Ce{sub 0.85}Gd{sub 0.15}O{sub 2} (Ni-GDC) and Ni-Ce{sub 0.6}La{sub 0.4}O{sub 2} (Ni-LDC) composites. Experiments conducted with the anode materials investigated the effect of having a barrier layer of GDC or LDC in between the LSGM electrolyte and the Ni-composite anode to prevent adverse reaction of the Ni with lanthanum in LSGM. For proper interpretation of the beneficial effects of the barrier layer, similar measurements were performed without the barrier layer. The ohmic and the polarization resistances of the system were obtained over time as a function of temperature (600-800 C), firing temperature, thickness, and the composition of the electrodes. The study revealed important details pertaining to the ohmic and the polarization resistances of the electrode as they relate to stability and the charge-transfer reactions that occur in such electrode structures.

Uday B. Pal; Srikanth Gopalan

2005-01-24T23:59:59.000Z

442

Glass forming ability of the Mo-Pd system studied by thermodynamic modeling and ion beam mixing  

SciTech Connect

Glass forming ability/range of the Mo-Pd binary metal system was studied by thermodynamic calculations employing Miedema's model and ion beam mixing of multiple metal layers. The thermodynamic calculations predict a narrow composition range of 8-26 at% Pd, within which metallic glass formation is energetically favored, whereas the experimental results showed that ion beam mixing was able to synthesize metallic glasses within a composition range 13-30 at% Pd, which was well in accordance with the prediction. Besides, in the Mo{sub 70}Pd{sub 30} multilayered films, with varying the irradiation dose, a dual-phase metallic glass was formed, and it could be considered as an intermediate state. The possible mechanism for the formation of the metallic glasses was also discussed in terms of the atomic collision theory.

Ding, N.; Li, J. H.; Liu, B. X.

2011-07-01T23:59:59.000Z

443

Feasibility study Part I - Thermal hydraulic analysis of LEU target for {sup 99}Mo production in Tajoura reactor  

SciTech Connect

The Renewable Energies and Water Desalination Research Center (REWDRC), Libya, will implement the technology for {sup 99}Mo isotope production using LEU foil target, to obtain new revenue streams for the Tajoura nuclear research reactor and desiring to serve the Libyan hospitals by providing the medical radioisotopes. Design information is presented for LEU target with irradiation device and irradiation Beryllium (Be) unit in the Tajoura reactor core. Calculated results for the reactor core with LEU target at different level of power are presented for steady state and several reactivity induced accident situations. This paper will present the steady state thermal hydraulic design and transient analysis of Tajoura reactor was loaded with LEU foil target for {sup 99}Mo production. The results of these calculations show that the reactor with LEU target during the several cases of transient are in safe and no problems will occur. (author)

Bsebsu, F.M.; Abotweirat, F. [Reactor Department, Renewable Energies and Water Desalination Research Cente, P.O. Box 30878 Tajoura, Tripoli (Libyan Arab Jamahiriya)], E-mail: Bsebso@yahoo.com, E-mail: abutweirat@yahoo.com; Elwaer, S. [Radiochemistry Department, Renewable Energies and Water Desalination Research Cente, P.O. Box 30878 Tajoura, Tripoli (Libyan Arab Jamahiriya)], E-mail: samiwer@yahoo.com

2008-07-15T23:59:59.000Z

444

Overview of a Welding Development Program for a Ni-Cr-Mo-Gd Alloy  

Science Conference Proceedings (OSTI)

The National Spent Nuclear Fuel Program (NSNFP), located at the Idaho National Laboratory, coordinates and integrates management and disposal of U.S. Department of Energy-owned spent nuclear fuel. These management functions include using the DOE standardized canister for packaging, storage, treatment, transport, and long-term disposal in the Yucca Mountain Repository. Nuclear criticality must be prevented in the postulated event where a waste package is breached and water (neutron moderator) is introduced into the waste package. Criticality control will be implemented by using a new, weldable, corrosion-resistant, neutron-absorbing material to fabricate the welded structural inserts (fuel baskets) that will be placed in the standardized canister. The new alloy is based on the Ni-Cr-Mo alloy system with a gadolinium addition. Gadolinium was chosen as the neutron absorption alloying element because of its high thermal neutron absorption cross section. This paper describes a weld development program to qualify this new material for American Society of Mechanical Engineers (ASME) welding procedures, develop data to extend the present ASME Code Case (unwelded) for welded construction, and understand the weldability and microstructural factors inherent to this alloy.

W. L. Hurt; R. E. Mizia; D. E. Clark

2007-06-01T23:59:59.000Z

445

Coupled spin and valley physics in monolayer MoS2 and group-VI dichalcogenides  

SciTech Connect

We show that inversion symmetry breaking together with spin-orbit coupling leads to coupled spin and valley physics in monolayer MoS2 and group-VI dichalcogenides, making possible controls of spin and valley in these 2D materials. The spin-valley coupling at the valence band edges suppresses spin and valley relaxation, as flip of each index alone is forbidden by the 0.1 eV valley contrasting spin splitting. Valley Hall and spin Hall effects coexist in both electron-doped and hole-doped systems. Optical interband transitions have frequency-dependent polarization selection rules which allow selective photoexcitation of carriers with various combination of valley and spin indices. Photo-induced spin Hall and valley Hall effects can generate long lived spin and valley accumulations on sample boundaries. The physics discussed here provides a route towards the integration of valleytronics and spintronics in multi-valley materials with strong spin-orbit coupling and inversion symmetry breaking.

Xiao, Di [ORNL; Liu, G. B. [University of Hong Kong, The; Feng, wanxiang [Chinese Academy of Sciences; Xu, Xiaodong [University of Washington; Yao, Wang [University of Hong Kong, The

2012-01-01T23:59:59.000Z

446

Window nighttime U-values: A comparison between computer calculations and MoWiTT measurements  

SciTech Connect

The proper specification of window U-values has been a controversial area for many years, and current attempts to incorporate more careful treatment of windows into building standards and utility conservation programs and to define window energy labels has heightened the controversy. In a previous paper (Klems 1979) it was argued that current calculation techniques, as embodied in the computer program WINDOW, accurately represented field-measured window U-values, provided frame corrections and surface heat transfer coefficients were correctly estimated, and that in most cases the calculations were also consistent with test laboratory measurements on the same windows. This means that the calculation could serve both as a standard for deriving calculated U-values and as a method of comparing measurements made under different conditions to determine their consistency. This work has now been extended to form a joint US/Canadian collaborative effort to test current computer programs. For six windows the U-values measured with the MoWiTT under field conditions are compared with detailed U-value calculations for the same conditions using the programs WINDOW and ANSYS. There is good agreement between measurements and calculations. 7 refs., 3 figs., 4 tabs.

Klems, J.H.; Reilly, S.

1989-11-01T23:59:59.000Z

447

Progress in converting {sup 99}Mo production from high- to low-enriched uranium--1999.  

SciTech Connect

Over this past year, extraordinary progress has been made in executing our charter to assist in converting Mo-99 production worldwide from HEU to LEU. Building on the successful development of the experimental LEU-foil target, we have designed a new, economical irradiation target. We have also successfully demonstrated, in collaboration with BATAN in Indonesia, that LEU can be substituted for HEU in the Cintichem target without loss of product yield or purity; in fact, conversion may make economic sense. We are interacting with a number of commercial producers--we have begun active collaborations with the CNEA and ANSTO; we are working to define the scope of collaborations with MDS Nordion and Mallinckrodt; and IRE has offered its services to irradiate and test a target at the appropriate time. Conversion of the CNEA process is on schedule. Other papers presented at this meeting will present specific results on the demonstration of the LEU-modified Cintichem process, the development of the new target, and progress in converting the CNEA process.

Snelgrove, J. L.; Vandegrift, G. F.; Conner, C.; Wiencek, T. C.; Hofman, G. L.

1999-09-29T23:59:59.000Z

448

Continuous lengths of oxide superconductors  

DOE Patents (OSTI)

A layered oxide superconductor prepared by depositing a superconductor precursor powder on a continuous length of a first substrate ribbon. A continuous length of a second substrate ribbon is overlaid on the first substrate ribbon. Sufficient pressure is applied to form a bound layered superconductor precursor powder between the first substrate ribbon and the second substrate ribbon. The layered superconductor precursor is then heat treated to establish the oxide superconducting phase. The layered oxide superconductor has a smooth interface between the substrate and the oxide superconductor.

Kroeger, Donald M. (Knoxville, TN); List, III, Frederick A. (Andersonville, TN)

2000-01-01T23:59:59.000Z

449

Thermal Oxidation of Titanium Wires  

Science Conference Proceedings (OSTI)

Structural and Thermal Study of Al2O3 Produced by Oxidation of Al-Powders Mixed with Corn Starch · Study of Silicon Carbide/Silicon Nitride Composite ...

450

(IV) Oxide and Barium Titanate  

Science Conference Proceedings (OSTI)

In a first investigation of its kind, a commercially available additive manufacturing platform has been applied to “print” metal oxide gas sensors. The M-Lab from ...

451

Enhanced Thermal Conductivity Oxide Fuels  

SciTech Connect

the purpose of this project was to investigate the feasibility of increasing the thermal conductivity of oxide fuels by adding small fractions of a high conductivity solid phase.

Alvin Solomon; Shripad Revankar; J. Kevin McCoy

2006-01-17T23:59:59.000Z

452

Oxides, Steels, and Nuclear Materials  

Science Conference Proceedings (OSTI)

Mar 14, 2012 ... This discussion will be illustrated with examples from solid oxide fuel cells, lithium ion batteries and high-temperature superconductors.

453

11/11/2002 1AVS 49th Int'l Symp. MS-MoA7 (Oct. 29, 2002) -Cho Dynamic Simulation and Optimization  

E-Print Network (OSTI)

'l Symp. MS-MoA7 (Oct. 29, 2002) - Cho Scope & Strategy Multilevel modeling & simulation incorporating dynamics &Multilevel modeling & simulation incorporating dynamics & stochasticsstochastics ESH fluctuations Incorporate capability in models for dynamics & stochastics Process & tool Fundamental science Si

Rubloff, Gary W.

454

Presented at the ASHRAE 2003 Annual Meeting, June 28 July 2, 2003, in Kansas City, MO, and published in ASHRAE Transactions 109, part 2: 733-739  

E-Print Network (OSTI)

LBNL-50219 Presented at the ASHRAE 2003 Annual Meeting, June 28 ­ July 2, 2003, in Kansas City, MO, and published in ASHRAE Transactions 109, part 2: 733-739 The research reported here was funded, in part

455

1: Mass asymmetric fission barriers for {sup 98}Mo; 2: Synthesis and characterization of actinide-specific chelating agents  

SciTech Connect

Excitation functions have been measured for complex fragment emission from the compound nucleus {sup 98}Mo, produced by the reaction of {sup 86}Kr with {sup 12}C. Mass asymmetric fission barriers have been obtained by fitting the excitation functions with a transition state formalism. The extracted barriers are {approximately} 5.7 MeV higher, on average, than the calculations of the Rotating Finite Range Model (RFRM). These data clearly show an isospin dependence of the conditional barriers when compared with the extracted barriers from {sup 90}Mo and {sup 94}Mo. Eleven different liquid/liquid extractants were synthesized based upon the chelating moieties 3,2-HOPO and 3,4-HOPO; additionally, two liquid/liquid extractants based upon the 1,2-HOPO chelating moiety were obtained for extraction studies. The Pu(IV) extractions, quite surprisingly, yielded results that were very different from the Fe(III) extractions. The first trend remained the same: the 1,2-HOPOs were the best extractants, followed closely by the 3,2-HOPOs, followed by the 3,4-HOPOs; but in these Pu(IV) extractions the 3,4-HOPOs performed much better than in the Fe(III) extractions. 129 refs.

Veeck, A.C. [Univ. of California, Berkeley, CA (United States). Dept. of Chemistry]|[Lawrence Livermore National Lab., CA (United States). Glenn T. Seaborg Inst. for Transactinium Science]|[Lawrence Berkeley National Lab., CA (United States). Nuclear Science Div.

1996-08-01T23:59:59.000Z

456

Field Evaluation of the Comanagement of Utility Low-Volume Wastes with High-Volume Coal Combustion By-Products: MO Site  

Science Conference Proceedings (OSTI)

This report documents an investigation into the effects of comanagement of low-volume wastes with high-volume coal combustion by-products at the MO site. The MO site is one of 14 investigated by EPRI to provide background information to the United States Environmental Protection Agency (EPA) for the 2000 Regulatory Determination on comanagement under the Resource Conservation and Recovery Act (RCRA).

2003-09-29T23:59:59.000Z

457

Method for hot pressing beryllium oxide articles  

DOE Patents (OSTI)

The hot pressing of beryllium oxide powder into high density compacts with little or no density gradients is achieved by employing a homogeneous blend of beryllium oxide powder with a lithium oxide sintering agent. The lithium oxide sintering agent is uniformly dispersed throughout the beryllium oxide powder by mixing lithium hydroxide in an aqueous solution with beryllium oxide powder. The lithium hydroxide is converted in situ to lithium carbonate by contacting or flooding the beryllium oxide - lithium hydroxide blend with a stream of carbon dioxide. The lithium carbonate is converted to lithium oxide while remaining fixed to the beryllium oxide particles during the hot pressing step to assure uniform density throughout the compact.

Ballard, A.H.; Godfrey, T.G. Jr.; Mowery, E.H.

1986-10-10T23:59:59.000Z

458

Operation of staged membrane oxidation reactor systems  

DOE Patents (OSTI)

A method of operating a multi-stage ion transport membrane oxidation system. The method comprises providing a multi-stage ion transport membrane oxidation system with at least a first membrane oxidation stage and a second membrane oxidation stage, operating the ion transport membrane oxidation system at operating conditions including a characteristic temperature of the first membrane oxidation stage and a characteristic temperature of the second membrane oxidation stage; and controlling the production capacity and/or the product quality by changing the characteristic temperature of the first membrane oxidation stage and/or changing the characteristic temperature of the second membrane oxidation stage.

Repasky, John Michael

2012-10-16T23:59:59.000Z

459

A high temperature neutron diffraction study of the double perovskite Ba{sub 2}{sup 154}SmMoO{sub 6}  

SciTech Connect

Ba{sub 2}LnMoO{sub 6} double perovskites have been recently shown to display a wide range of interesting magnetic and structural properties; Ba{sub 2}{sup 154}SmMoO{sub 6} exhibits simultaneous antiferromagnetic order and a Jahn-Teller distortion. Here we report a high temperature neutron diffraction study of Ba{sub 2}{sup 154}SmMoO{sub 6} from 353 to 877 K. The results evidence a tetragonal to cubic phase transition at 423 K. Above this temperature the thermal displacement parameters of the oxygen atoms are modelled anisotropically as a result of a transverse vibration of the bridging oxygen. A smooth increase in the cell parameter a is observed with temperature for Ba{sub 2}{sup 154}SmMoO{sub 6}. - Graphical abstract: The high temperature crystal structure of Ba{sub 2}{sup 154}SmMoO{sub 6} evidencing a transverse oxygen vibration. Highlights: Black-Right-Pointing-Pointer A high temperature neutron diffraction study has been performed on an isotopically enriched sample of Ba{sub 2}{sup 154}SmMoO{sub 6}. Black-Right-Pointing-Pointer A cubic-tetragonal phase transition occurs below 423 K. Black-Right-Pointing-Pointer The thermal displacement parameters of the bridging oxygens are modelled anisotropically. Black-Right-Pointing-Pointer There is a transverse vibration of the bridging oxygen.

Wallace, Thomas K. [Department of Chemistry, University of Aberdeen, Meston Walk, Aberdeen AB24 3UE (United Kingdom)] [Department of Chemistry, University of Aberdeen, Meston Walk, Aberdeen AB24 3UE (United Kingdom); Ritter, Clemens [Institut Laue Langevin, 6 rue Jules Horowitz, BP 156, F-38042 Grenoble Cedex 9 (France)] [Institut Laue Langevin, 6 rue Jules Horowitz, BP 156, F-38042 Grenoble Cedex 9 (France); Mclaughlin, Abbie C., E-mail: a.c.mclaughlin@abdn.ac.uk [Department of Chemistry, University of Aberdeen, Meston Walk, Aberdeen AB24 3UE (United Kingdom)

2012-12-15T23:59:59.000Z