Sample records for mo ar tx

  1. Agricultural Grassland, Soil and Water Research Laboratory, Temple, TX

    E-Print Network [OSTI]

    Agricultural Research Service Grassland, Soil and Water Research Laboratory, Temple, TX Monitoring, Modeling and Decision-Making Daren Harmel USDA-ARS, Temple, TX #12;Agricultural Research Service Grassland monitoring, modeling, and decision- making #12;Agricultural Research Service Grassland, Soil and Water

  2. Agricultural Grassland, Soil and Water Research Laboratory, Temple, TX

    E-Print Network [OSTI]

    Agricultural Research Service Grassland, Soil and Water Research Laboratory, Temple, TX Monitoring, Modeling and Decision-Making Daren Harmel USDA-ARS, Temple, TX Agricultural Research Service Grassland monitoring, modeling, and decision- making (if time and interest!!) Agricultural Research Service Grassland

  3. US WSC TX Site Consumption

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTownDells,1Stocks Nov-14TotalThe Outlook269,023Year69,023USWNC MO SiteWSC TX

  4. EIS-0412: TX Energy, LLC, Industrial Gasification Facility Near...

    Broader source: Energy.gov (indexed) [DOE]

    2: TX Energy, LLC, Industrial Gasification Facility Near Beaumont, TX EIS-0412: TX Energy, LLC, Industrial Gasification Facility Near Beaumont, TX February 18, 2009 EIS-0412:...

  5. Table 1 -ESTIMATED REDUCTION IN 1985 COTTON YIELDS RESULTING FROM INSECTDAMAGE TOTAL YIELD 13,622 bales INSECTS Loss in AL AZ AR CA FL GA LA MS MO NM NC OK SC TN TX VA No.

    E-Print Network [OSTI]

    Ray, David

    Average cost for all states nTotal yield for all states o Total acres for all states *Does not include BWE cost

  6. LADY BIRD JOHNSON MIDDLE SCHOOL IRVING, TX

    E-Print Network [OSTI]

    #12;#12;#12;LADY BIRD JOHNSON MIDDLE SCHOOL IRVING, TX 2012 CAUDILL AWARD WINNER The 1st NET ZERO public school in Texas The 1st NET ZERO middle school in the United States The LARGEST NET ZERO school displays building performance and NET ZERO efficiency. #12;LADY BIRD JOHNSON MIDDLE SCHOOL IRVING, TX

  7. CX-100 and TX-100 blade field tests.

    SciTech Connect (OSTI)

    Holman, Adam (USDA-Agriculture Research Service, Bushland, TX); Jones, Perry L.; Zayas, Jose R.

    2005-12-01T23:59:59.000Z

    In support of the DOE Low Wind Speed Turbine (LWST) program two of the three Micon 65/13M wind turbines at the USDA Agricultural Research Service (ARS) center in Bushland, Texas will be used to test two sets of experimental blades, the CX-100 and TX-100. The blade aerodynamic and structural characterization, meteorological inflow and wind turbine structural response will be monitored with an array of 75 instruments: 33 to characterize the blades, 15 to characterize the inflow, and 27 to characterize the time-varying state of the turbine. For both tests, data will be sampled at a rate of 30 Hz using the ATLAS II (Accurate GPS Time-Linked Data Acquisition System) data acquisition system. The system features a time-synchronized continuous data stream and telemetered data from the turbine rotor. This paper documents the instruments and infrastructure that have been developed to monitor these blades, turbines and inflow.

  8. TX-100 manufacturing final project report.

    SciTech Connect (OSTI)

    Ashwill, Thomas D.; Berry, Derek S. (TPI Composites, Inc., Warren, RI)

    2007-11-01T23:59:59.000Z

    This report details the work completed under the TX-100 blade manufacturing portion of the Carbon-Hybrid Blade Developments: Standard and Twist-Coupled Prototype project. The TX-100 blade is a 9 meter prototype blade designed with bend-twist coupling to augment the mitigation of peak loads during normal turbine operation. This structural coupling was achieved by locating off axis carbon fiber in the outboard portion of the blade skins. The report will present the tooling selection, blade production, blade instrumentation, blade shipping and adapter plate design and fabrication. The baseline blade used for this project was the ERS-100 (Revision D) wind turbine blade. The molds used for the production of the TX-100 were originally built for the production of the CX-100 blade. The same high pressure and low pressure skin molds were used to manufacture the TX-100 skins. In order to compensate for the difference in skin thickness between the CX-100 and the TX-100, however, a new TX-100 shear web plug and mold were required. Both the blade assembly fixture and the root stud insertion fixture used for the CX-100 blades could be utilized for the TX-100 blades. A production run of seven TX-100 prototype blades was undertaken at TPI Composites during the month of October, 2004. Of those seven blades, four were instrumented with strain gauges before final assembly. After production at the TPI Composites facility in Rhode Island, the blades were shipped to various test sites: two blades to the National Wind Technology Center at the National Renewable Energy Laboratory in Boulder, Colorado, two blades to Sandia National Laboratory in Albuquerque, New Mexico and three blades to the United States Department of Agriculture turbine field test facility in Bushland, Texas. An adapter plate was designed to allow the TX-100 blades to be installed on existing Micon 65/13M turbines at the USDA site. The conclusion of this program is the kick-off of the TX-100 blade testing at the three testing facilities.

  9. arXiv:physics/0010039 Maximally Informative Statistics

    E-Print Network [OSTI]

    Wolf, David R.

    arXiv:physics/0010039 v1 15 Oct 2000 Maximally Informative Statistics Maximally Informative Statistics David R. Wolf PO 8308, Austin, TX 78713-8308, USA, E-mail: drwolf@realtime.net Dr. Wolf: egeorge@mail.utexas.edu Revision history: April 1996. Presented Bayesian Statistics 6, Valencia, 1998

  10. Role of SrMoO{sub 4} in Sr{sub 2}MgMoO{sub 6} synthesis

    SciTech Connect (OSTI)

    Vasala, S.; Yamauchi, H. [Laboratory of Inorganic Chemistry, Department of Chemistry, School of Chemical Technology, Aalto University, P.O. Box 16100, FI-00076 Aalto (Finland); Karppinen, M., E-mail: maarit.karppinen@aalto.f [Laboratory of Inorganic Chemistry, Department of Chemistry, School of Chemical Technology, Aalto University, P.O. Box 16100, FI-00076 Aalto (Finland)

    2011-05-15T23:59:59.000Z

    Here we investigate the elemental and phase compositions during the solid-state synthesis of the promising SOFC-anode material, Sr{sub 2}MgMoO{sub 6}, and demonstrate that molybdenum does not notably evaporate under the normal synthesis conditions with temperatures up to 1200 {sup o}C due to the formation of SrMoO{sub 4} as an intermediate product at low temperatures, below 600 {sup o}C. However, partial decomposition of the Sr{sub 2}MgMoO{sub 6} phase becomes evident at the higher temperatures ({approx}1500 {sup o}C). The effect of SrMoO{sub 4} on the electrical conductivity of Sr{sub 2}MgMoO{sub 6} is evaluated by preparing a series of Sr{sub 2}MgMoO{sub 6} samples with different amounts of additional SrMoO{sub 4}. Under the reducing operation conditions of an SOFC anode the insulating SrMoO{sub 4} phase is apparently reduced to the highly conductive SrMoO{sub 3} phase. Percolation takes place with 20-30 wt% of SrMoO{sub 4} in a Sr{sub 2}MgMoO{sub 6} matrix, with a notable increase in electrical conductivity after reduction. Conductivity values of 14, 60 and 160 S/cm are determined at 800 {sup o}C in 5% H{sub 2}/Ar for the Sr{sub 2}MgMoO{sub 6} samples with 30, 40 and 50 wt% of added SrMoO{sub 4}, respectively. -- Graphical abstract: SrMoO{sub 4} is formed at low temperatures during the synthesis of Sr{sub 2}MgMoO{sub 6}, which prevents the volatilization of Mo from typical precursor mixtures of this promising SOFC anode material. SrMoO{sub 4} is insulating and it is often found as an impurity in Sr{sub 2}MgMoO{sub 6} samples. It is however readily reduced to highly conducting SrMoO{sub 3}. Composites of Sr{sub 2}MgMoO{sub 6} and SrMoO{sub 3} show increased electrical conductivities compared to pure Sr{sub 2}MgMoO{sub 6} under the reductive operation conditions of an SOFC anode. Display Omitted Highlights: {yields} Sr{sub 2}MgMoO{sub 6} is a promising SOFC anode material. {yields} During the Sr{sub 2}MgMoO{sub 6} synthesis SrMoO{sub 4} is formed at low temperatures. {yields} Formation of SrMoO{sub 4} effectively prevents volatilization of Mo at high temperatures. {yields} Insulating SrMoO{sub 4} reduces to highly conductive SrMoO{sub 3} under SOFC-anode conditions. {yields} Composites of Sr{sub 2}MgMoO{sub 6} and SrMoO{sub 3} show high electrical conductivities.

  11. MO. REV. MO. MAGNETIC CLEANLINESS GUIDELINES

    E-Print Network [OSTI]

    Rathbun, Julie A.

    MO. REV. MO. ATM-865 MAGNETIC CLEANLINESS GUIDELINES PAGE 1 Of 3 DATE 4/6/70 The purpose of this ATM is to update the ALSEP Magnetic Cleanliness Guidelines as delineated in A TM-294, dated 1 June. ATM-865 MAGNETIC CLEANLINESS GUIDELINES PAGE 2 OF 3 DATE 4/6/70 A review of the ALSEP Magnetic

  12. CleanTX Foundation | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual Siteof EnergyInnovationin UrbanCity ofCityClean Economy Network JumpCleanCleanFUELCleanTX

  13. Simple Molybdenum(IV) Olefin Complexes of the Type Mo(NR)(X)(Y)(olefin)

    E-Print Network [OSTI]

    Marinescu, Smaranda C.

    Exposure of heptane solutions of Mo(NAr)(CHCMe2Ph)(Me2Pyr)(OAr) (1a; Ar = 2,6-diisopropylphenyl), Mo(NAr)(CHCMe3)(Me2Pyr)[OCMe(CF3)2] (1b), and Mo(NAr)(CHCMe2Ph)(Me2Pyr)(OSiPh3) (1c) to one atmosphere of ethylene for 12 h ...

  14. NCSEC'07 Plano, TX Risk-Based Quantifiable

    E-Print Network [OSTI]

    Tian, Jeff

    NCSEC'07 Plano, TX Risk-Based Quantifiable Quality Improvement Jeff Tian (tian@engr.smu Risk · Quality for Customers/Users · Quality for Software Organizations March 30, 2007 Jeff Tian, SMU 2800 1536 1 883 737 5396 2583 45 37 9 March 30, 2007 Jeff Tian, SMU #12;NCSEC'07, Plano, TX Slide. 3

  15. Photometry of symbiotic stars XI. EG And, Z And, BF Cyg, CH Cyg, CI Cyg, V1329 Cyg, TX CVn, AG Dra, RW Hya, QW Sge, IV Vir and the LMXB V934 Her

    E-Print Network [OSTI]

    A. Skopal; T. Pribulla; M. Vanko; Z. Velic; E. Semkov; M. Wolf; A. Jones

    2004-02-06T23:59:59.000Z

    We present new photometric observations of EG And, Z And, BF Cyg, CH Cyg, CI Cyg, V1329 Cyg, TX CVn, AG Dra, RW Hya, AR Pav, AG Peg, AX Per, QW Sge, IV Vir and the peculiar M giant V934 Her. The current issue gathers observations of these objects to December 2003.

  16. Hanford Single Shell Tank Leak Causes and Locations - 241-TX Farm

    SciTech Connect (OSTI)

    Girardot, C. L.; Harlow, D> G.

    2014-07-22T23:59:59.000Z

    This document identifies 241-TX Tank Farm (TX Farm) leak causes and locations for the 100 series leaking tanks (241-TX-107 and 241-TX-114) identified in RPP-RPT-50870, Rev. 0, Hanford 241-TX Farm Leak Inventory Assessment Report. This document satisfies the TX Farm portion of the target (T04) in the Hanford Federal Facility Agreement and Consent Order milestone M-045-91F.

  17. austin tx usa: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    78712, USA b Bureau of Economic Geology, Jackson School of Geology, The University of Texas at Austin, Austin, TX 78713, USA c Department of Mathematics Minkoff, Susan E. 50...

  18. txH2O: Volume 4, Number 2 (Complete)

    E-Print Network [OSTI]

    Texas Water Resources Institute

    2008-01-01T23:59:59.000Z

    Farmer Art Director AgriLife Communications & Marketing Danielle Supercinski Assistant Editor Texas Water Resources Institute Visit our web site at http://twri.tamu.edu for more information and to subscribe to tx H 2 O On the cover: The Rio Grande one... Texas Water Resources Institute Tammisha Farmer Art Director AgriLife Communications & Marketing Danielle Supercinski Assistant Editor Texas Water Resources Institute Visit our web site at http://twri.tamu.edu for more information and to subscribe to tx...

  19. txH2O: Volume 5, Number 2 (Complete)

    E-Print Network [OSTI]

    Texas Water Resources Institute

    2009-01-01T23:59:59.000Z

    Supercinski Leslie Jordan Assistant Editors Texas Water Resources Institute Visit our Web site at http://twri.tamu.edu for more information and to subscribe to tx H2O On the cover: The Nueces River and Nueces Bay (pictured) is one of six priority... site at http://twri.tamu.edu for more information and to subscribe to tx H2O On the cover: The Nueces River and Nueces Bay (pictured) is one of six priority river basins for which a environmental flows regime will be established. Photo...

  20. txH20: Volume 7, Number 1 (Complete)

    E-Print Network [OSTI]

    Wythe, Kathy

    2011-01-01T23:59:59.000Z

    Plains Underground Conservation District No. 1, is created. Dallas City Council passes a resolution limiting lawn watering. President Eisenhower declares 244 of the state?s 254 counties as drought disaster counties. Heavy, general rains begin... is funded in part by the U.S. Geological Survey and authorized by the Water Resources Research Act. To subscribe to txH2O or New Waves, TWRI?s monthly e-mail newsletter, visit twri.tamu.edu. Follow us on Twitter at Twitter.com/TxWRI. InsideNeal Wilkins...

  1. txH20: Volume 7, Number 3 (Complete)

    E-Print Network [OSTI]

    Wythe, Kathy

    2012-01-01T23:59:59.000Z

    - based soil moisture data for calibration/ validation of remote sensing platforms in Oklahoma. Editor?s note: The stories in this issue of txH2O are examples of each stage of the research process, beginning with applied research, which... scale. ?We cannot do this using only one technique, so we assimilate data from various platforms, such as ground-level measurements at the #25;nest scale and remote sensing measurements up to the watershed, Fall 2012 tx H2O 11 Left photo...

  2. RAPID/Roadmap/11-TX-c | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere I GeothermalPotentialBiopowerSolidGenerationMethodInformation TexasTexas) Redirecta < RAPID‎TX-aTX-c

  3. Benefits of Multiple TX Powers Robustness to Beacon Node Failure

    E-Print Network [OSTI]

    Chen, Yiling

    the partial failure of the infrastructure. Our system, called MoteTrack, is based on low-power radios coupledAccuracy Benefits of Multiple TX Powers Robustness to Beacon Node Failure Introduction to a wide range of applications. For some, the location tracking system must continue to operate despite

  4. at Texas Tech University 1717 Norfolk Ave. Lubbock, TX 79416

    E-Print Network [OSTI]

    Zhang, Yuanlin

    in the South Plains allowing us to provide the most comprehensive retirement choice in West Texas. Why waitat Texas Tech University #12;1717 Norfolk Ave. · Lubbock, TX 79416 806.281.6200 · carillonlubbock, Betty Jennings, Mary Vines and Fred Wagner THE OFFICIAL RETIREMENT COMMUNITY OF TEXAS TECH ATHLETICS

  5. HASE'07 Panel 4a Dallas, TX Achieving High Assurance

    E-Print Network [OSTI]

    Tian, Jeff

    Jeff Tian (tian@engr.smu.edu) Southern Methodist University Dallas, Texas, USA Contents · HA Jeff Tian, SMU #12;HASE'07, Dallas, TX Slide. 2 Qualitative vs Quantification HA · Many aspects/subsystems. Performance: measurement/modeling. Analysis: statistical/other modeling Nov. 15, 2007 Jeff Tian, SMU #12;HASE

  6. April 11, 2001 Presentation at BRC, Temple, TX. Hydrological Applications of

    E-Print Network [OSTI]

    April 11, 2001 Presentation at BRC, Temple, TX. Hydrological Applications of LST Derived from AVHRR;April 11, 2001 Presentation at BRC, Temple, TX. Outline · Introduction · All about LST · Model Modeling · Drought Indices (KBDI, PDSI) · Conclusion #12;April 11, 2001 Presentation at BRC, Temple, TX

  7. txH2O: Volume 6, Number 1 (Complete)

    E-Print Network [OSTI]

    Texas Water Resources Institute

    2010-01-01T23:59:59.000Z

    , watershed coordinator and Extension program specialist, coordinate specific projects in the Lower Rio Grande Valley and the Pecos River Basin, respectively. The institute has established many partnerships that, in addition to the colleges, units... Parks and Wildlife Department (TPWD), U.S. Fish and Wildlife Service, Synergistic eradication Center?s First Project Tackles Invasive Plant at Treasured Lake txH2O | pg. 5 U.S. Army Corps of Engineers, NRCS, Cypress Valley Navigation District...

  8. txH20; Volume 6, Number 1 (Complete)

    E-Print Network [OSTI]

    Wythe, Kathy

    2010-01-01T23:59:59.000Z

    , watershed coordinator and Extension program specialist, coordinate specific projects in the Lower Rio Grande Valley and the Pecos River Basin, respectively. The institute has established many partnerships that, in addition to the colleges, units... Parks and Wildlife Department (TPWD), U.S. Fish and Wildlife Service, Synergistic eradication Center?s First Project Tackles Invasive Plant at Treasured Lake txH2O | pg. 5 U.S. Army Corps of Engineers, NRCS, Cypress Valley Navigation District...

  9. txH2O: Volume 3, Number 2 (Complete) 

    E-Print Network [OSTI]

    Texas Water Resources Institute

    2007-01-01T23:59:59.000Z

    H 2 Otx Fall 2007 A Publication of the Texas Water Resources Institute Texas Water Resources Institute | Texas Agricultural Experiment Station | Texas Cooperative Extension ?? ?? ?? ?? ?? ?? ?? In This Issue: MANAGING BACTERIA POLLUTION IN TEXAS... Kari Miller Assistant Editors Texas Water Resources Institute Visit our Web site at http://twri.tamu.edu for more information and to subscribe to tx H 2 O On the cover: Low-temperature electron micrograph of a cluster of E. coli bacteria. Each...

  10. Ethanol Conversion on Cyclic (MO3)3 (M = Mo, W) Clusters. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Conversion on Cyclic (MO3)3 (M Mo, W) Clusters. Ethanol Conversion on Cyclic (MO3)3 (M Mo, W) Clusters. Abstract: Oxides of molybdenum and tungsten are an important class of...

  11. txH2O: Volume 4, Number 1 (Complete)

    E-Print Network [OSTI]

    Texas Water Resources Institute

    2008-01-01T23:59:59.000Z

    developed about on-site conditions before a well was drilled and installed can be downloaded. ? U. S. Geological Survey?s Groundwater Data for the Nation program http://waterdata.usgs.gov/nwis/gw A variety of groundwater data, including information... at NASA?s Goddard Space Flight Center, Greenbelt, MD, using data from three different Earth-observing satellite instruments. The presence of the Moon in this image is an artistic addition. Inside volume 4 number 1, Winter 2008 tx H 2 O...

  12. txH20: Volume 7, Number 2 (Complete)

    E-Print Network [OSTI]

    Wythe, Kathy

    2012-01-01T23:59:59.000Z

    rapid and more complete than in other places where we may have a history of not fertilizing appropriately,? Redmon said. ?#31;e moisture part of it looks pre#30;y good. How much of a crop was destroyed is site-to- site speci#28;c.? Hay production...Life Research, the Texas AgriLife Extension Service and the Texas A&M University College of Agriculture and Life Sciences. TWRI is funded in part by the U.S. Geological Survey and authorized by the Water Resources Research Act. To subscribe to txH2O or New...

  13. Staubli TX-90XL robot qualification at the LLIHE.

    SciTech Connect (OSTI)

    Covert, Timothy Todd

    2010-10-01T23:59:59.000Z

    The Light Initiated High Explosive (LIHE) Facility uses a robotic arm to spray explosive material onto test items for impulse tests. In 2007, the decision was made to replace the existing PUMA 760 robot with the Staubli TX-90XL. A qualification plan was developed and implemented to verify the safe operating conditions and failure modes of the new system. The robot satisfied the safety requirements established in the qualification plan. A performance issue described in this report remains unresolved at the time of this publication. The final readiness review concluded the qualification of this robot at the LIHE facility.

  14. txH2O: Volume 6, Number 2 (Complete) 

    E-Print Network [OSTI]

    Texas Water Resources Institute

    2011-01-01T23:59:59.000Z

    drop in the bucket? Texas scientists on the real effects of the Deepwater Horizon oil spill 7 I Developing solutions for sustainable living?the Urban Living Laboratory The world?s largest ?living laboratory? for research on green living 10 I... 26 I Controlling invasive weed Center begins studying giant salvinia-eating weevils 28 I TWRI Briefs 2 tx H2O Winter 2011 Story by Leslie Lee Texas scientists on the real e#31;ects of the Deepwater Horizon oil spill Environmental disaster...

  15. txH20: Volume 6, Number 2 (Complete) 

    E-Print Network [OSTI]

    Wythe, Kathy

    2011-01-01T23:59:59.000Z

    drop in the bucket? Texas scientists on the real effects of the Deepwater Horizon oil spill 7 I Developing solutions for sustainable living?the Urban Living Laboratory The world?s largest ?living laboratory? for research on green living 10 I... 26 I Controlling invasive weed Center begins studying giant salvinia-eating weevils 28 I TWRI Briefs 2 tx H2O Winter 2011 Story by Leslie Lee Texas scientists on the real e#31;ects of the Deepwater Horizon oil spill Environmental disaster...

  16. txH2O: Volume 9, Number 1 (Complete)

    E-Print Network [OSTI]

    Wythe, Kathy

    2014-01-01T23:59:59.000Z

    , was integral in establishing the start of the EARIP project and served as the former program coordinator for EARIP. 10 txH2O Summer 2014 Story by Danielle Kalisek El Paso Water Utilities uses an infiltration or spreading basin to recharge the Hueco... needs. In the 2012 state water plan, accessing new sources of ground- water is projected to provide more than 800,000 acre-feet of water annually by 2060. With the growing water needs in the state and the continuing drought, many are predicting...

  17. txH2O: Volume 4, Number 3 (Complete) 

    E-Print Network [OSTI]

    Texas Water Resources Institute

    2008-01-01T23:59:59.000Z

    On the cover: The City of Kerrville stores excess water from the Guadalupe River in its Aquifer Storage and Recovery facility. Photo by Earl Nottingham, Texas Parks and Wildlife Department. C. Allan Jones Message from the Director Working to Make Every...Life. TWRI is funded in part by the U.S. Geological Survey and authorized by the Water Resources Research Act. To subscribe to tx H2O or New Waves, TWRI?s monthly e-mail newsletter, visit http://twri.tamu.edu. 2 I Saving for dry days Aquifer storage...

  18. EIS-0412: TX Energy, LLC, Industrial Gasification Facility Near Beaumont,

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny:Revised FindingDepartment of EnergyEnergyDepartment of Energy IntentTX

  19. RAPID/Roadmap/13-TX-a | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:Ezfeedflag Jump to:ID8/OrganizationTechProbSolutionsPublicQuanlightR3(2)3-AK-aNV-a <TX-a

  20. RAPID/Roadmap/5-TX-a | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:Ezfeedflag JumpID-f < RAPID‎ | Roadmap Jump to: navigation, searche <caMT-aNV-bTX-a

  1. RAPID/Roadmap/1-TX-a | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere I GeothermalPotentialBiopowerSolidGenerationMethodInformation TexasTexas) Redirect pageNV-a <TX-a <

  2. RAPID/Roadmap/11-TX-a | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere I GeothermalPotentialBiopowerSolidGenerationMethodInformation TexasTexas) Redirecta < RAPID‎TX-a <

  3. RAPID/Roadmap/11-TX-b | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere I GeothermalPotentialBiopowerSolidGenerationMethodInformation TexasTexas) Redirecta < RAPID‎TX-a

  4. RAPID/Roadmap/12-TX-a | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere I GeothermalPotentialBiopowerSolidGenerationMethodInformation TexasTexas)ID-a < RAPID‎ |TX-a <

  5. RAPID/Roadmap/15-TX-a | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere I GeothermalPotentialBiopowerSolidGenerationMethodInformatione < RAPID‎ | Roadmap JumpTX-a <

  6. RAPID/Roadmap/7-TX-c | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere I GeothermalPotentialBiopowerSolidGenerationMethodInformatione <RAPID/Roadmap/7-FD-k <TX-c <

  7. SCOPES'05 Dallas, TX, Sept., 2005 Risk-Based Quality Improvement

    E-Print Network [OSTI]

    Tian, Jeff

    (tian@engr.smu.edu) Southern Methodist University Dallas, Texas, USA Contents · Quality, Reliability for ES Jeff Tian, SMU #12;SCOPES'05, Dallas, TX, Sept., 2005 Slide. 2 Quality, Reliability, and Risk 0. SE Panel: New SE Paradigms for ES Jeff Tian, SMU #12;SCOPES'05, Dallas, TX, Sept., 2005 Slide. 3 Risk

  8. High reflectance and low stress Mo2C/Be multilayers

    DOE Patents [OSTI]

    Bajt, Sasa (Livermore, CA); Barbee, Jr., Troy W. (Palo Alto, CA)

    2001-01-01T23:59:59.000Z

    A material for extreme ultraviolet (EUV) multilayers that will reflect at about 11.3 nm, have a high reflectance, low stress, and high thermal and radiation stability. The material consists of alternating layers of Mo.sub.2 C and Be deposited by DC magnetron sputtering on a substrate, such as silicon. In one example a Mo.sub.2 C/Be multilayer gave 65.2% reflectance at 11.25 nm measured at 5 degrees off normal incidence angle, and consisted of 70 bilayers with a deposition period of 5.78 nm, and was deposited at 0.83 mTorr argon (Ar) sputtering pressure, with the first and last layers being Be. The stress of the multilayer is tensile and only +88 MPa, compared to +330 MPa of a Mo/Be multilayers of the same thickness. The Mo.sub.2 C/Be multilayer was capped with carbon which produced an increase in reflectivity of about 7% over a similar multilayer with no carbon capping material, thus raising the reflectivity from 58.3% to over 65%. The multilayers were formed using either Mo.sub.2 C or Be as the first and last layers, and initial testing has shown the formation of beryllium carbide at the interfaces between the layers which both stabilizes and has a smoothing effect, and appear to be smoother than the interfaces in Mo/Be multilayers.

  9. arXiv:0710.1988v1[hep-lat]10Oct2007 Deflated BiCGStab for linear equations in QCD

    E-Print Network [OSTI]

    Morgan, Ron

    arXiv:0710.1988v1[hep-lat]10Oct2007 Deflated BiCGStab for linear equations in QCD problems Abdou M. Abdel-Rehim Department of Physics, Baylor University, Waco, TX 76798-7316, USA. E-mail: Abdou-NonCommercial-ShareAlike Licence. http://pos.sissa.it/ #12;Deflated BiCGStab for linear equations in QCD problems Abdou M. Abdel

  10. Reservoir Fracture Mapping using Microearthquakes: Austin Chalk, Giddings Field, TX and 76 Field, Clinton Co., KY.

    E-Print Network [OSTI]

    SPE 36651 Reservoir Fracture Mapping using Microearthquakes: Austin Chalk, Giddings Field, TX and enhanced recovery, production operations in fracture- dominated oil and gas reservoirs. Borehole geophones to study reservoir fracture systems. Methods currently applied to study fracture systems include tilt

  11. Electrodeposition of high Mo content Ni-Mo alloys under forced convection

    SciTech Connect (OSTI)

    Podlaha, E.J.; Matlosz, M.; Landolt, D. (Ecole Polytechnique Federale de Lausanne, Lausanee (Switzerland). Dept. des materiaux)

    1993-10-01T23:59:59.000Z

    Bright, compact, adherent, metallic Ni-Mo alloys, containing over 48 wt % Mo have been electrodeposited from an aqueous solution. The Mo content, which is the highest achieved so far in induced codeposition of Ni-Mo, was determined by X-ray fluorescence spectroscopy. The absence of oxygen was verified by Auger electron spectroscopy. Electrodeposition experiments were performed on rotating cylinder electrodes and demonstrate that the Mo content of the alloy is strongly influenced by convective transport.

  12. The Coronae of AR Lac

    E-Print Network [OSTI]

    Huenemoerder, David P.

    We observed the coronally active eclipsing binary AR Lac with the High Energy Transmission Grating on Chandra for a total of 97 ks, spaced over five orbits, at quadratures and conjunctions. Contemporaneous and simultaneous ...

  13. US WNC MO Site Consumption

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTownDells,1Stocks Nov-14TotalThe Outlook269,023Year69,023USWNC MO Site

  14. Stanford University Exploiting Channel Knowledge at the Tx in MISO and MIMO Wireless Exploiting Partial Channel Knowledge at

    E-Print Network [OSTI]

    Paulraj, Arogyaswami

    Stanford University Exploiting Channel Knowledge at the Tx in MISO and MIMO Wireless Exploiting Partial Channel Knowledge at the Transmitter in MISO and MIMO Wireless SPAWC 2003 Rome, Italy June 18 Exploiting Channel Knowledge at the Tx in MISO and MIMO Wireless Outline Introduction · Perfect CSI

  15. File:USDA-CE-Production-GIFmaps-MO.pdf | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are8COaBulkTransmissionSitingProcess.pdf Jump to:ar-80m.pdf Jump to:Originalfaq.pdfFinal.pdf JumpIN.pdfMO.pdf Jump to:

  16. alvos contendo mo: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CaMoO4 crystal scintillators. A high sensitivity experiment to search for neutrinoless double beta decay of 100-Mo by using CaMoO4 scintillators is discussed. Annenkov, A N;...

  17. ACM SIGGRAPH 2002, San Antonio, TX Modeling the Accumulation of Wind-Driven Snow

    E-Print Network [OSTI]

    O'Brien, James F.

    ACM SIGGRAPH 2002, San Antonio, TX Modeling the Accumulation of Wind-Driven Snow Technical Sketch of snow drifts formed by the accumulation of wind-blown snow near buildings and other obstacles. Our method combines previous work on snow accumulation [Fearing] with techniques for incompressible fluid

  18. A Voltage Controlled Nano Addressing Circuit University of Texas, San Antonio TX 78249, USA,

    E-Print Network [OSTI]

    Liu, Bao

    A Voltage Controlled Nano Addressing Circuit Bao Liu University of Texas, San Antonio TX 78249, USA, Abstract. A voltage controlled nano addressing circuit is proposed, which (1) improves yield and enables aggressive scaling with no require- ment of precise layout design, (2) achieves precision of addressing

  19. S/w Quality Assurance CAST-TX 1 Software Quality Assurance

    E-Print Network [OSTI]

    Tian, Jeff

    (tian@engr.smu.edu) Southern Methodist University Dallas, Texas, USA Contents · Software Quality: Why Management Nov. 30, 2002 Prof. Jeff Tian, SMU #12;S/w Quality Assurance CAST-TX 2 Software Quality: Why/usage-based testing and relia- bility engineering measurement and risk management Nov. 30, 2002 Prof. Jeff Tian, SMU

  20. WIND ENERGY HOW MUCH AND WHAT PRICE? NSTA SAN ANTONIO, TX

    E-Print Network [OSTI]

    Collar, Juan I.

    WIND ENERGY ­ HOW MUCH AND WHAT PRICE? NSTA ­ SAN ANTONIO, TX Last Updated 04/14/13 DESCRIPTION this then extractable and transferable to the electrical grid. To understand how much power (energy per unit time household fan, the windmill's turbines will rotate. #12;Suggested questions or activities: 1. Does

  1. TX TX TX TX TX TX TX TX TX OK OK OK OK OK OK OK OK OK LA LA

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    areas. Movment within shaded areas may also be regulated. Updated January 9, 2002 Puerto Rico United States Department of Agriculture - Animal and Plant Health Inspection...

  2. The Efficacy of SEER as a Seasonal Performance Measure for Different Climates 

    E-Print Network [OSTI]

    Henderson, H. I.; Sachs, H. M.

    2006-01-01T23:59:59.000Z

    Data Albuquerque-NM Amarillo-TX Austin-TX Boise-ID Brownsville-TX Columbia-SC Corpus_Christi-TX Elko-NV Fort_Smith-AR Grand_Junction-CO Jackson-MS Kansas_City-MO Little_Rock-AR Lubbock-TXLufkin-TX Memphis-TN Meridian-MS Miles..._City-MT Montgomery-AL Nashville-TN North_Platte-NE Norfolk-NE Pendleton-OR Pierre-SD Pocatello-ID Pueblo-CO Reno-NV Scottsbluff-NE Shreveport-LA Sioux_Falls-SD San_Antonio-TX Tonopah-NV Tucumcari-NM Victoria-TX 6 Tampa-Florida 40 60 80 100 120...

  3. Very-high-order harmonic generation from Ar atoms and Ar+ ions in superintense pulsed laser

    E-Print Network [OSTI]

    Chu, Shih-I

    Very-high-order harmonic generation from Ar atoms and Ar+ ions in superintense pulsed laser fields-high-order harmonic generation HHG from Ar atoms and Ar+ ions by means of the self-interaction-free time-order harmonic generation HHG is one of the most rapidly developing topics in the field of laser-atom molecule

  4. MoS2 Nanoribbons Thermoelectric Generators

    E-Print Network [OSTI]

    Arab, Abbas

    2015-01-01T23:59:59.000Z

    In this work, we have designed and simulated new thermoelectric generator based on monolayer and few-layer MoS2 nanoribbons. The proposed thermoelectric generator is composed of thermocouples made of both n-type and p-type MoS2 nanoribbon legs. Density Functional Tight-Binding Non-Equilibrium Green's Function (DFTB-NEGF) method has been used to calculate the transmission spectrum of MoS2 armchair and zigzag nanoribbons. Phonon transmission spectrum are calculated based on parameterization of Stillinger-Weber potential. Thermoelectric figure of merit, ZT, is calculated using these electronic and phonon transmission spectrum. Monolayer and bilayer MoS2 armchair nanoribbons are found to have the highest ZT value for p-type and n-type legs, repectively. Moreover, we have compared the thermoelectric current of doped monolayer MoS2 armchair nanoribbons and SZi thin films. Results indicate that thermoelectric current of MoS2 monolayer nanoribbons is several orders of magnitude higher than that of Si thin films.

  5. Lessons Learned from Continuous Commissioning of the Robert E. Johnson State Office Building, Austin, TX

    E-Print Network [OSTI]

    Bynum, J.; Claridge, D. E.

    2008-09-22T23:59:59.000Z

    ESL-TR-08-08-03 Lessons Learned from Continuous Commissioning ® of the Robert E. Johnson State Office Building, Austin, TX Submitted to Lawrence Berkeley National Laboratory By David Claridge, Ph.D., P.E. John Bynum Energy....5% annual lighting energy savings or 5.6% annual whole building energy savings based on a DOE-2 simulation analysis. Three main lessons were learned from the experience with the Robert E. Johnson building: • The traditional design...

  6. The environment of deposition of the Dalton Coal (Upper Pennsylvanian), Palo Pinto Co., TX.

    E-Print Network [OSTI]

    Lowenstein, Glenn Robert

    1986-01-01T23:59:59.000Z

    Alkane analysis for coal, overburden and underburden shales, and oil. 56 CHAPTER I INTRODUCTION Previous workers have classified coals by deter- mining whether they are al 1ochthnous (transported) or autochthonous (in situ) accumul ations (Oe...THE ENVIRONMENT OF DEPOSITION OF THE DALTON COAL (UPPER PENNSYI. VANIAN), PALO PINTO CO. , TX. A Thesis by GLENN ROBERT LOWENSTEIN Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for tne...

  7. Prompt {gamma}-ray spectroscopy of the {sup 104}Mo and {sup 108}Mo fission fragments

    SciTech Connect (OSTI)

    Guessous, A.; Schulz, N.; Bentaleb, M.; Lubkiewicz, E. [Centre de Recherches Nucleaires, Institut National de Physique Nucleaire et de Physique des Particules, Centre National de la Recherche Scientifique, Universite Louis Pasteur, 67037 Strasbourg (France)] [Centre de Recherches Nucleaires, Institut National de Physique Nucleaire et de Physique des Particules, Centre National de la Recherche Scientifique, Universite Louis Pasteur, 67037 Strasbourg (France); Durell, J.L.; Pearson, C.J.; Phillips, W.R.; Shannon, J.A.; Urban, W.; Varley, B.J. [Department of Physics, University of Manchester, M13 9PL (United Kingdom)] [Department of Physics, University of Manchester, M13 9PL (United Kingdom); Ahmad, I.; Lister, C.J.; Morss, L.R.; Nash, K.L.; Williams, C.W. [Argonne National Laboratory, Argonne, Illinois 60439 (United States)] [Argonne National Laboratory, Argonne, Illinois 60439 (United States); Khazrouni, S. [Laboratoire de Physique Nucleaire Appliquee, Faculte des Sciences, Kenitra, Maroc (France)] [Laboratoire de Physique Nucleaire Appliquee, Faculte des Sciences, Kenitra, Maroc (France)

    1996-03-01T23:59:59.000Z

    The level structures of the neutron-rich {sup 104}Mo and {sup 108}Mo nuclei have been investigated by observing prompt {gamma} rays emitted in the spontaneous fission of {sup 248}Cm with the EUROGAM spectrometer. Levels with spins up to 12{h_bar} have been observed and {gamma} branching obtained. The data can be satisfactorily described when {sup 104,108}Mo are considered as axially symmetric nuclei: in {sup 104}Mo, rotational bands based on the ground state, the one-phonon and the two-phonon {gamma}-vibrational states and a quasiparticle state have been observed, whereas in {sup 108}Mo the information is limited to the yrast band and the one phonon {gamma} band. {copyright} {ital 1996 The American Physical Society.}

  8. Tunable MoS{sub 2} bandgap in MoS{sub 2}-graphene heterostructures

    SciTech Connect (OSTI)

    Ebnonnasir, Abbas [Department of Mechanical Engineering and Materials Science Program, Colorado School of Mines, Golden, Colorado 80401 (United States); Department of Materials Science and Engineering, University of California Los Angeles, Los Angeles, California 90095 (United States); Narayanan, Badri; Ciobanu, Cristian V., E-mail: cciobanu@mines.edu, E-mail: kodambaka@ucla.edu [Department of Mechanical Engineering and Materials Science Program, Colorado School of Mines, Golden, Colorado 80401 (United States); Kodambaka, Suneel, E-mail: cciobanu@mines.edu, E-mail: kodambaka@ucla.edu [Department of Materials Science and Engineering, University of California Los Angeles, Los Angeles, California 90095 (United States)

    2014-07-21T23:59:59.000Z

    Using density functional theory calculations with van der Waals corrections, we investigated how the interlayer orientation affects the structure and electronic properties of MoS{sub 2}-graphene bilayer heterostructures. Changing the orientation of graphene with respect to MoS{sub 2} strongly influences the type and the value of the electronic bandgap in MoS{sub 2}, while not significantly altering the binding energy between the layers or the interlayer spacing. We show that the physical origin of this tunable bandgap arises from variations in the S–S interplanar distance (MoS{sub 2} thickness) with the interlayer orientation, variations which are caused by electron transfer away from the Mo–S bonds.

  9. Elevated Temperature Tensile Tests on DU–10Mo Rolled Foils

    SciTech Connect (OSTI)

    Jason Schulthess

    2014-09-01T23:59:59.000Z

    Tensile mechanical properties for uranium-10 wt.% molybdenum (U–10Mo) foils are required to support modeling and qualification of new monolithic fuel plate designs. It is expected that depleted uranium-10 wt% Mo (DU–10Mo) mechanical behavior is representative of the low enriched U–10Mo to be used in the actual fuel plates, therefore DU-10Mo was studied to simplify material processing, handling, and testing requirements. In this report, tensile testing of DU-10Mo fuel foils prepared using four different thermomechanical processing treatments were conducted to assess the impact of foil fabrication history on resultant tensile properties.

  10. Wetting of metals and glasses on Mo

    SciTech Connect (OSTI)

    Saiz, Eduardo; Tomsia, Antoni P.; Saiz, Eduardo; Lopez-Esteban, Sonia; Benhassine, Mehdi; de Coninck, Joel; Rauch, Nicole; Ruehle, Manfred

    2008-01-08T23:59:59.000Z

    The wetting of low melting point metals and Si-Ca-Al-Ti-O glasses on molybdenum has been investigated. The selected metals (Au, Cu, Ag) form a simple eutectic with Mo. Metal spreading occurs under nonreactive conditions without interdiffusion or ridge formation. The metals exhibit low (non-zero) contact angles on Mo but this requires temperatures higher than 1100 C in reducing atmospheres in order to eliminate a layer of adsorbed impurities on the molybdenum surface. By controlling the oxygen activity in the furnace, glass spreading can take place under reactive or nonreactive conditions. We have found that in the glass/Mo system the contact angle does not decrease under reactive conditions. In all cases, adsorption from the liquid seems to accelerate the diffusivity on the free molybdenum surface.

  11. Ar Allman Ide-och matematik

    E-Print Network [OSTI]

    Kaijser, Sten

    Napoleon Komplexa Planet: Gauss 1825 Wienkongressen Sydamerika och Grekland fria Trigonometriska serier Victoria I Upprorens °ar 1848 Abraham Lincoln Napoleon III Abstrakt algebra: Boole, Cayley

  12. ARS Energy Water and Sustainability Program

    Broader source: Energy.gov [DOE]

    Presentation covers the ARS Energy Water and Sustainability Program given at the Spring 2010 Federal Utility Partnership Working Group (FUPWG) meeting in Rapid City, South Dakota.

  13. Oxidation, Reduction, and Condensation of Alcohols over (MO3)3 (M=Mo, W) Nanoclusters

    SciTech Connect (OSTI)

    Fang, Zongtang; Li, Zhenjun; Kelley, Matthew S.; Kay, Bruce D.; Li, Shenggang; Hennigan, Jamie M.; Rousseau, Roger J.; Dohnalek, Zdenek; Dixon, David A.

    2014-10-02T23:59:59.000Z

    The reactions of deuterated methanol, ethanol, 1-propanol, 1-butanol, 2-propanol, 2-butanol and t-butanol over cyclic (MO3)3 (M = Mo, W) clusters were studied experimentally with temperature programmed desorption (TPD) and theoretically with coupled cluster CCSD(T) theory and density functional theory. The reactions of two alcohols per M3O9 cluster are required to provide agreement with experiment for D2O release, dehydrogenation and dehydration. The reaction begins with the elimination of water by proton transfers and forms an intermediate dialkoxy species which can undergo further reaction. Dehydration proceeds by a ? hydrogen transfer to a terminal M=O. Dehydrogenation takes place via an ? hydrogen transfer to an adjacent MoVI = O atom or a WVI metal center with redox involved for M = Mo and no redox for M = W. The two channels have comparable activation energies. H/D exchange to produce alcohols can take place after olefin is released or via the dialkoxy species depending on the alcohol and the cluster. The Lewis acidity of the metal center with WVI being larger than MoVI results in the increased reactivity of W3O9 over Mo3O9 for dehydrogenation and dehydration.

  14. Geologic and geophysical investigation of a small water retention structure, Salado, Tx 

    E-Print Network [OSTI]

    Carter, James Lewis

    2002-01-01T23:59:59.000Z

    of a Small Earth Dam Caused by Piping Erosion Initiated by a Leak in Overflow Pipe, Bryan, TX. 4. Map Showing the Location of Roger's Pond . . 5 Structural Setting of the Balcones Fault Zone Along With the Divisions of the Edward's Aquifer 6 NNW... ? SSE Cross-Section of the Strata That Comprises the Water Table Portion of the Edwards Aquifer in Bell County. 12 7 Soils Map of Roger's Pond and Surrounding Area. 14 8 Observation Well Installed Below the Dam on the Downstremn Side. . . . . 9 Turf...

  15. File:03-TX-d - Lease of Public School Fund Land (1).pdf | Open Energy

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand JumpConceptual1WAALandUsePlanning.pdf Jump to: navigation, search File FileInformation -TX-d -

  16. File:03-TX-e - Lease of Texas Parks & Wildlife Department Land (1).pdf |

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand JumpConceptual1WAALandUsePlanning.pdf Jump to: navigation, search File FileInformation -TX-d -Open

  17. File:03-TX-f - Lease of Land Trade Lands.pdf | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand JumpConceptual1WAALandUsePlanning.pdf Jump to: navigation, search File FileInformation -TX-d

  18. Mo Supply Chain for Nuclear Medicine Ladimer S. Nagurney

    E-Print Network [OSTI]

    Nagurney, Anna

    The 99 Mo Supply Chain for Nuclear Medicine Ladimer S. Nagurney Department of Electrical November 13, 2012 #12;Nuclear Medicine: Meeting Patient Needs with 99 Mo Ladimer S. Nagurney The 99 Mo Supply Chain #12;Background and Motivation Study of Nuclear Medicine Supply Chains is a combination

  19. ar da regiao: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    above the transition from evaporitic to continental sediments, it implies that the Fortuna evaporites Elsevier B.V. All rights reserved. Keywords: 40 Ar39 Ar; Volcanism;...

  20. ar usando plantas: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    above the transition from evaporitic to continental sediments, it implies that the Fortuna evaporites Elsevier B.V. All rights reserved. Keywords: 40 Ar39 Ar; Volcanism;...

  1. ar em amostras: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    above the transition from evaporitic to continental sediments, it implies that the Fortuna evaporites Elsevier B.V. All rights reserved. Keywords: 40 Ar39 Ar; Volcanism;...

  2. ar exalado para: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    above the transition from evaporitic to continental sediments, it implies that the Fortuna evaporites Elsevier B.V. All rights reserved. Keywords: 40 Ar39 Ar; Volcanism;...

  3. aquecimento por ar: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    above the transition from evaporitic to continental sediments, it implies that the Fortuna evaporites Elsevier B.V. All rights reserved. Keywords: 40 Ar39 Ar; Volcanism;...

  4. ar condicionado da: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    above the transition from evaporitic to continental sediments, it implies that the Fortuna evaporites Elsevier B.V. All rights reserved. Keywords: 40 Ar39 Ar; Volcanism;...

  5. abdominalfistel syv ar: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    above the transition from evaporitic to continental sediments, it implies that the Fortuna evaporites Elsevier B.V. All rights reserved. Keywords: 40 Ar39 Ar; Volcanism;...

  6. ar na entrada: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    above the transition from evaporitic to continental sediments, it implies that the Fortuna evaporites Elsevier B.V. All rights reserved. Keywords: 40 Ar39 Ar; Volcanism;...

  7. ar isotopic chain: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    above the transition from evaporitic to continental sediments, it implies that the Fortuna evaporites Elsevier B.V. All rights reserved. Keywords: 40 Ar39 Ar; Volcanism;...

  8. ar expirado na: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    above the transition from evaporitic to continental sediments, it implies that the Fortuna evaporites Elsevier B.V. All rights reserved. Keywords: 40 Ar39 Ar; Volcanism;...

  9. ar dzirdes traucjumiem: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    above the transition from evaporitic to continental sediments, it implies that the Fortuna evaporites Elsevier B.V. All rights reserved. Keywords: 40 Ar39 Ar; Volcanism;...

  10. ar por chumbo: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    above the transition from evaporitic to continental sediments, it implies that the Fortuna evaporites Elsevier B.V. All rights reserved. Keywords: 40 Ar39 Ar; Volcanism;...

  11. ar acu vjum: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    above the transition from evaporitic to continental sediments, it implies that the Fortuna evaporites Elsevier B.V. All rights reserved. Keywords: 40 Ar39 Ar; Volcanism;...

  12. ar audiodisku pamatskolas: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    above the transition from evaporitic to continental sediments, it implies that the Fortuna evaporites Elsevier B.V. All rights reserved. Keywords: 40 Ar39 Ar; Volcanism;...

  13. ar selnu bagtintu: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    above the transition from evaporitic to continental sediments, it implies that the Fortuna evaporites Elsevier B.V. All rights reserved. Keywords: 40 Ar39 Ar; Volcanism;...

  14. ar augstu kariesa: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    above the transition from evaporitic to continental sediments, it implies that the Fortuna evaporites Elsevier B.V. All rights reserved. Keywords: 40 Ar39 Ar; Volcanism;...

  15. ar avaliacao da: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    above the transition from evaporitic to continental sediments, it implies that the Fortuna evaporites Elsevier B.V. All rights reserved. Keywords: 40 Ar39 Ar; Volcanism;...

  16. ar em tomografia: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    above the transition from evaporitic to continental sediments, it implies that the Fortuna evaporites Elsevier B.V. All rights reserved. Keywords: 40 Ar39 Ar; Volcanism;...

  17. ar como indicadores: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    above the transition from evaporitic to continental sediments, it implies that the Fortuna evaporites Elsevier B.V. All rights reserved. Keywords: 40 Ar39 Ar; Volcanism;...

  18. ar efter kolecystektomi: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    above the transition from evaporitic to continental sediments, it implies that the Fortuna evaporites Elsevier B.V. All rights reserved. Keywords: 40 Ar39 Ar; Volcanism;...

  19. apsilde ar dmgzm: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    above the transition from evaporitic to continental sediments, it implies that the Fortuna evaporites Elsevier B.V. All rights reserved. Keywords: 40 Ar39 Ar; Volcanism;...

  20. ar para radiodiagnostico: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    above the transition from evaporitic to continental sediments, it implies that the Fortuna evaporites Elsevier B.V. All rights reserved. Keywords: 40 Ar39 Ar; Volcanism;...

  1. ar comprimido estudo: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    above the transition from evaporitic to continental sediments, it implies that the Fortuna evaporites Elsevier B.V. All rights reserved. Keywords: 40 Ar39 Ar; Volcanism;...

  2. ar gazu hromotografijas: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    above the transition from evaporitic to continental sediments, it implies that the Fortuna evaporites Elsevier B.V. All rights reserved. Keywords: 40 Ar39 Ar; Volcanism;...

  3. ar dadm elektronu: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    above the transition from evaporitic to continental sediments, it implies that the Fortuna evaporites Elsevier B.V. All rights reserved. Keywords: 40 Ar39 Ar; Volcanism;...

  4. adaptive response ar: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AR Representation AR Results Conclusion References Automated Reasoning in Modal Logics: A Framework with Applications Branden Fitelson Department of Philosophy Institute for...

  5. Tank 241-TX-118, core 236 analytical results for the final report

    SciTech Connect (OSTI)

    ESCH, R.A.

    1998-11-19T23:59:59.000Z

    This document is the analytical laboratory report for tank 241-TX-118 push mode core segments collected between April 1, 1998 and April 13, 1998. The segments were subsampled and analyzed in accordance with the Tank 241-TX-118 Push Mode Core sampling and Analysis Plan (TSAP) (Benar, 1997), the Safety Screening Data Quality Objective (DQO) (Dukelow, et al., 1995), the Data Quality Objective to Support Resolution of the Organic Complexant Safety Issue (Organic DQO) (Turner, et al, 1995) and the Historical Model Evaluation Data Requirements (Historical DQO) (Sipson, et al., 1995). The analytical results are included in the data summary table (Table 1). None of the samples submitted for Differential Scanning Calorimetry (DSC) and Total Organic Carbon (TOC) exceeded notification limits as stated in the TSAP (Benar, 1997). One sample exceeded the Total Alpha Activity (AT) analysis notification limit of 38.4{micro}Ci/g (based on a bulk density of 1.6), core 236 segment 1 lower half solids (S98T001524). Appropriate notifications were made. Plutonium 239/240 analysis was requested as a secondary analysis. The statistical results of the 95% confidence interval on the mean calculations are provided by the Tank Waste Remediation Systems Technical Basis Group in accordance with the Memorandum of Understanding (Schreiber, 1997) and are not considered in this report.

  6. Tank characterization report for single-shell tank 241-TX-104

    SciTech Connect (OSTI)

    FIELD, J.G.

    1999-05-12T23:59:59.000Z

    A major function of the Tank Waste Remediation System (TWRS) is to characterize waste in support of waste management and disposal activities at the Hanford Site. Analytical data from sampling and analysis and other available information about a tank are compiled and maintained in a tank characterization report (TCR). This report and its appendices serve as the TCR for single-shell tank 241-TX-104. The objectives of this report are (1) to use characterization data in response to technical issues associated with tank 241-TX-104 waste, and (2) to provide a standard characterization of this waste in terms of a best-basis inventory estimate. Section 2.0 summarizes the response to technical issues, Section 3.0 shows the best-basis inventory estimate, Section 4.0 makes recommendations about the safety status of the tank and additional sampling needs. The appendices contain supporting data and information. This report supports the requirements of the Hanford Federal Facility Agreement and Consent Order (Ecology et al. 1997), Milestone M-44-15c, change request M-44-97-03 to ''issue characterization deliverables consistent with the Waste Information Requirements Document developed for FY 1999'' (Adams et al. 1998).

  7. Development of CaMoO4 crystal scintillators for double beta decay experiment with 100-Mo

    E-Print Network [OSTI]

    A. N. Annenkov; O. A. Buzanov; F. A. Danevich; A. Sh. Georgadze; S. K. Kim; H. J. Kim; Y. D. Kim; V. V. Kobychev; V. N. Kornoukhov; M. Korzhik; J. I. Lee; O. Missevitch; V. M. Mokina; S. S. Nagorny; A. S. Nikolaiko; D. V. Poda; R. B. Podviyanuk; D. J. Sedlak; O. G. Shkulkova; J. H. So; I. M. Solsky; V. I. Tretyak; S. S. Yurchenko

    2007-07-10T23:59:59.000Z

    Energy resolution, alpha/beta ratio, pulse-shape discrimination for gamma rays and alpha particles, temperature dependence of scintillation properties, and radioactive contamination were studied with CaMoO4 crystal scintillators. A high sensitivity experiment to search for neutrinoless double beta decay of 100-Mo by using CaMoO4 scintillators is discussed.

  8. Re Effects on Phase Stability and Mechanical Properties of MoSS+Mo3Si+Mo5SiB2 alloys

    SciTech Connect (OSTI)

    Yang, Ying [ORNL; Bei, Hongbin [ORNL; George, Easo P [ORNL; Tiley, Jaimie [Air Force Research Laboratory, Wright-Patterson AFB, OH

    2013-01-01T23:59:59.000Z

    Because of their high melting points and good oxidation resistance Mo-Si-B alloys are of interest as potential ultrahigh-temperature structural materials. But their major drawbacks are poor ductility and fracture toughness at room temperature. Since alloying with Re has been suggested as a possible solution, we investigate here the effects of Re additions on the microstructure and mechanical properties of a ternary alloy with the composition Mo-12.5Si-8.5B (at.%). This alloy has a three-phase microstructure consisting of Mo solid-solution (MoSS), Mo3Si, and Mo5SiB2 and our results show that up to 8.4 at.% Re can be added to it without changing its microstructure or forming any brittle phase at 1600 C. Three-point bend tests using chevron-notched specimens showed that Re did not improve fracture toughness of the three-phase alloy. Nanoindentation performed on the MoSS phase in the three-phase alloy showed that Re increases Young s modulus, but does not lower hardness as in some Mo solid solution alloys. Based on our thermodynamic calculations and microstructural analyses, the lack of a Re softening effect is attributed to the increased Si levels in the Re-containing MoSS phase since Si is known to increase its hardness. This lack of softening is possibly why there is no Re-induced improvement in fracture toughness.

  9. Transparent Conducting ZnO Thin Films Doped with Al and Mo

    SciTech Connect (OSTI)

    Duenow, J.; Gessert, T.; Wood, D.; Young, D.; Coutts, T.

    2007-01-01T23:59:59.000Z

    Transparent conducting oxide (TCO) thin films are a vital part of photovoltaic cells, flat-panel displays, and electrochromic windows. ZnO-based TCOs, due to the relative abundance of Zn, may reduce production costs compared to those of the prevalent TCO In2O3:Sn (ITO). Undoped ZnO, ZnO:Al (0.5, 1, and 2 wt.% Al2O3), and ZnO:Mo (2 wt.%) films were deposited by RF magnetron sputtering. Controlled incorporation of H2 in the Ar sputtering ambient increased mobility of undoped ZnO by a factor of ~20 to 48 cm2V-1s-1. H2 also appears to catalyze ionization of dopants. This enabled lightly doped ZnO:Al to provide comparable conductivity to the standard 2 wt.%-doped ZnO:Al while demonstrating reduced infrared absorption. Mo was found to be an n-type dopant of ZnO, though material properties did not match those of ZnO:Al. Scattering mechanisms were investigated using temperature-dependent Hall measurements and the method of four coefficients. This abstract is subject to government rights.

  10. Justin Yates -Assistant Professor -Industrial and Systems Engineering -Texas A&M University 4079 ETB -College Station, TX, 77843-3131 -(O) 979-458-2337 -(E) jtyates@tamu.edu

    E-Print Network [OSTI]

    Boas, Harold P.

    ETB - College Station, TX, 77843-3131 - (O) 979-458-2337 - (E) jtyates@tamu.edu 1 Education: Ph - Texas A&M University 4079 ETB - College Station, TX, 77843-3131 - (O) 979-458-2337 - (E) jtyates

  11. EIS-0412: Federal Loan Guarantee to Support Construction of the TX Energy LLC, Industrial Gasification Facility near Beaumont, Texas

    Broader source: Energy.gov [DOE]

    The Department of Energy is assessing the potential environmental impacts for its proposed action of issuing a Federal loan guarantee to TX Energy, LLC (TXE). TXE submitted an application to DOE under the Federal loan guarantee program pursuant to the Energy Policy Act of 2005 (EPAct 2005) to support construction of the TXE industrial Gasification Facility near Beaumont, Texas.

  12. Sedimentary processes of the Red River between Denison Dam, TX and Alexandria, LA

    E-Print Network [OSTI]

    Weirich, Thomas Moody - Kenyon

    1990-01-01T23:59:59.000Z

    Figure 1. Location map of study area along the Red River. . . . . . . . . . . . . 2 Figure 2. Location map of reach blocked by the natural raft. . . . . . . . . 12 Figure 3. Suspended sediment concentration and volumetric flow diagram. Figure 4... and sinuosity values between Temple, AR and Alexandria, LA. Table 3. Sinuosity values of the Red River course 1892, 1938, 1983. . 62 Table 4. Sieve analysis of alluvial flood plain samples. . . . . . . . . . . . . . . 76 INTRODUCTION The Red River...

  13. Upcoming Management and Operating (M&O) Contract Competition...

    National Nuclear Security Administration (NNSA)

    Upcoming Management and Operating (M&O) Contract Competition | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile...

  14. MoRu/Be multilayers for extreme ultraviolet applications

    DOE Patents [OSTI]

    Bajt, Sasa C. (Livermore, CA); Wall, Mark A. (Stockton, CA)

    2001-01-01T23:59:59.000Z

    High reflectance, low intrinsic roughness and low stress multilayer systems for extreme ultraviolet (EUV) lithography comprise amorphous layers MoRu and crystalline Be layers. Reflectance greater than 70% has been demonstrated for MoRu/Be multilayers with 50 bilayer pairs. Optical throughput of MoRu/Be multilayers can be 30-40% higher than that of Mo/Be multilayer coatings. The throughput can be improved using a diffusion barrier to make sharper interfaces. A capping layer on the top surface of the multilayer improves the long-term reflectance and EUV radiation stability of the multilayer by forming a very thin native oxide that is water resistant.

  15. Interdiffusion between Zr Diffusion Barrier and U-Mo Alloy

    SciTech Connect (OSTI)

    K. Huang; Y. Park; Y. H. Sohn

    2012-12-01T23:59:59.000Z

    U-Mo alloys are being developed as low enrichment uranium fuels under the Reduced Enrichment for Research and Test Reactor (RERTR) program. Significant reactions have been observed between U-Mo fuels and Al or Al alloy matrix. Refractory metal Zr has been proposed as barrier material to reduce the interactions. In order to investigate the compatibility and barrier effects between U-Mo alloy and Zr, solid-to-solid U-10wt.%Mo vs. Zr diffusion couples were assembled and annealed at 600, 700, 800, 900 and 1000 °C for various times. The microstructures and concentration profiles due to interdiffusion and reactions were examined via scanning electron microscopy and electron probe microanalysis, respectively. Intermetallic phase Mo2Zr was found at the interface and its population increased when annealing temperature decreased. Diffusion paths were also plotted on the U-Mo-Zr ternary phase diagrams with good consistency. The growth rate of interdiffusion zone between U-10wt.%Mo and Zr was also calculated under the assumption of parabolic diffusion, and was determined to be about 103 times lower than the growth rate of diffusional interaction layer found in diffusion couples U-10wt.%Mo vs. Al or Al-Si alloy. Other desirable physical properties of Zr as barrier material, such as neutron adsorption rate, melting point and thermal conductivity are presented as supplementary information to demonstrate the great potential of Zr as the diffusion barrier for U-Mo fuel systems in RERTR.

  16. Mo Year Report Period: EIA ID NUMBER:

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTownDells, Wisconsin:DeploymentSite Name:24,High824 2.839 2.8352.747 2.759 2.699Mo

  17. Catalytic Properties of Supported MoO3 Catalysts for Oxidative Dehydrogenation of Propane

    E-Print Network [OSTI]

    Iglesia, Enrique

    Catalytic Properties of Supported MoO3 Catalysts for Oxidative Dehydrogenation of Propane Kaidong The effects of MoOx structure on propane oxidative dehydrogenation (ODH) rates and selectivity were examined with those obtained on MoOx/ZrO2. On MoOx/Al2O3 catalysts, propane turnover rate increased with increasing Mo

  18. The novel hypoxic cytotoxin, TX-2098 has antitumor effect in pancreatic cancer; possible mechanism through inhibiting VEGF and hypoxia inducible factor-1{alpha} targeted gene expression

    SciTech Connect (OSTI)

    Miyake, Kotaro, E-mail: hif.panc@gmail.com [Department of Surgery, Institute of Health Biosciences, The University of Tokushima Graduate School, Tokushima 770-8503 (Japan)] [Department of Surgery, Institute of Health Biosciences, The University of Tokushima Graduate School, Tokushima 770-8503 (Japan); Nishioka, Masanori; Imura, Satoru; Batmunkh, Erdenebulgan [Department of Surgery, Institute of Health Biosciences, The University of Tokushima Graduate School, Tokushima 770-8503 (Japan)] [Department of Surgery, Institute of Health Biosciences, The University of Tokushima Graduate School, Tokushima 770-8503 (Japan); Uto, Yoshihiro [Department of Biological Science and Technology, Institute of Socio Technosciences, The University of Tokushima Graduate School, Tokushima 770-8503 (Japan)] [Department of Biological Science and Technology, Institute of Socio Technosciences, The University of Tokushima Graduate School, Tokushima 770-8503 (Japan); Nagasawa, Hideko [Laboratory of Pharmaceutical and Medicinal Chemistry, Gifu Pharmaceutical University, Gifu 501-1196 (Japan)] [Laboratory of Pharmaceutical and Medicinal Chemistry, Gifu Pharmaceutical University, Gifu 501-1196 (Japan); Hori, Hitoshi [Department of Biological Science and Technology, Institute of Socio Technosciences, The University of Tokushima Graduate School, Tokushima 770-8503 (Japan)] [Department of Biological Science and Technology, Institute of Socio Technosciences, The University of Tokushima Graduate School, Tokushima 770-8503 (Japan); Shimada, Mitsuo [Department of Surgery, Institute of Health Biosciences, The University of Tokushima Graduate School, Tokushima 770-8503 (Japan)] [Department of Surgery, Institute of Health Biosciences, The University of Tokushima Graduate School, Tokushima 770-8503 (Japan)

    2012-08-01T23:59:59.000Z

    Tumor hypoxia has been considered to be a potential therapeutic target, because hypoxia is a common feature of solid tumors and is associated with their malignant phenotype. In the present study, we investigated the antitumor effect of a novel hypoxic cytotoxin, 3-[2-hydroxyethyl(methyl)amino]-2-quinoxalinecarbonitrile 1,4-dioxide (TX-2098) in inhibiting the expression of hypoxia inducible factor-1{alpha} (HIF-1{alpha}), and consequently vascular endothelial cell growth factor (VEGF) expression in pancreatic cancer. The antitumor effects of TX-2098 under hypoxia were tested against various human pancreatic cancer cell lines using WST-8 assay. VEGF protein induced pancreatic cancer was determined on cell-free supernatant by ELISA. Moreover, nude mice bearing subcutaneously (s.c.) or orthotopically implanted human SUIT-2 were treated with TX-2098. Tumor volume, survival and expression of HIF-1 and associated molecules were evaluated in treatment versus control groups. In vitro, TX-2098 inhibited the proliferation of various pancreatic cancer cell lines. In s.c model, tumors from nude mice injected with pancreatic cancer cells and treated with TX-2098 showed significant reductions in volume (P < 0.01 versus control). Quantitative real-time reverse transcription-PCR analysis revealed that TX-2098 significantly inhibited mRNA expression of the HIF-1 associated molecules, VEGF, glucose transporter 1 and Aldolase A (P < 0.01 versus control). These treatments also prolong the survival in orthotopic models. These results suggest that the effect of TX-2098 in pancreatic cancer might be correlated with the expression of VEGF and HIF-1 targeted molecules. -- Highlights: Black-Right-Pointing-Pointer We designed and synthesized novel hypoxic cytoxin, TX-2098. Black-Right-Pointing-Pointer TX-2098 inhibited the proliferation of human pancreatic cancer cells than TPZ. Black-Right-Pointing-Pointer TX-2098 reduced VEGF protein level than TPZ. Black-Right-Pointing-Pointer TX-2098 inhibited mRNA expression of VEGF, GLUT1 and Aldolase A, not HIF-1{alpha}. Black-Right-Pointing-Pointer TX-2098 improved the survival in orthotopic SUIT-2 xenograft model.

  19. Neutron Hole States of Mo-93,95

    E-Print Network [OSTI]

    Bindal, P. K.; Youngblood, David H.; Kozub, R. L.

    1977-01-01T23:59:59.000Z

    - topes but less than half is observed for '"Mo. The hole strength distributions for l =1 and 4 are displayed in Fig. 10 for all the Mo isotopes. It is apparent from this figure that the states corres- ponding to lgg/2 2Py/2 and 2P, /, orbitals, which...

  20. Neutrino scattering off the stable even-even Mo isotopes

    SciTech Connect (OSTI)

    Balasi, K. G.; Kosmas, T. S.; Divari, P. C. [Theoretical Physics Section, University of Ioannina, GR 45110 Ioannina (Greece)

    2009-11-09T23:59:59.000Z

    Inelastic neutrino-nucleus reaction cross sections are studied focusing on the neutral current processes. Particularly, we investigate the angular and initial neutrino-energy dependence of the differential and integrated cross sections for low and intermediate energies of the incoming neutrino. The nuclear wave functions for the initial and final nuclear states are constructed in the context of the quasi-particle random phase approximation (QRPA) tested on the reproducibility of the low-lying energy spectrum. The results presented here refer to the isotopes Mo{sup 92}, Mo{sup 94}, Mo{sup 96}, Mo{sup 98} and Mo{sup 100}. These isotopes could play a significant role in supernova neutrino detection in addition to their use in double-beta and neutrinoless double-beta decay experiments (e.g. MOON, NEMO III)

  1. University of Texas Arlington Health Services Box 19329 605 S. West St. Arlington, TX 76019 T. 817.272.2771 F. 817.272.3829

    E-Print Network [OSTI]

    Texas at Arlington, University of

    Form 130D University of Texas Arlington Health Services Box 19329 605 S. West St. Arlington, TX, appropriate staff, and The University of Texas at Arlington and its officers, regents, and employees shall

  2. File:USDA-CE-Production-GIFmaps-TX.pdf | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are8COaBulkTransmissionSitingProcess.pdf Jump to:ar-80m.pdf Jump to:Originalfaq.pdfFinal.pdfNM.pdf JumpSD.pdf

  3. Beta decay of 32Ar for fundamental tests

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of 32 Ar and 33 Ar data 1999 result: 0.9980(52) stat (39) syst Adelberger et al., PRL 83 (1999) 1299 But, since then... * Precision measurement of 32 S(p,p) 32 S 3374.7-...

  4. Demonstration of resonant photopumping of Mo VII by Mo XII for a VUV laser near 600 {Angstrom}

    SciTech Connect (OSTI)

    Ilcisin, K.J.; Aumayr, F.; Schwob, J.L.; Suckewer, S.

    1993-09-01T23:59:59.000Z

    We present data of experiments on the resonant photopumping of Mo VII by Mo XII as a method of generating a coherent VUV source near 600 {angstrom}. The experiment is based on a scheme proposed by Feldman and Reader in which the 4p{sup 6} -- 4p{sup 5}6s transition in Mo VII in resonantly photopumped by the 5s {sup 2}S{sub 1/2} -- 4p {sup 2}P{sub 1/2} transition in Mo XII. Results of the laser produced plasma experiments show the successful enhancement of the population of the Mo VII 4p{sup 5}6s upper lasing level when pumped by an adjacent Mo VII plasma. No enhancement was seen in a control experiment where the Mo VII plasma was pumped by a Zr X plasma. Improvements of the intensity of the Mo XII pump source, achieved using an additional pump laser, lead to the generation of a population inversion for the VUV transition.

  5. Guar Varieties and P Fertility at AGCARES, Lamesa, TX, 2001-2003 Calvin Trostle, Texas Cooperative Extension--Lubbock, c-trostle@tamu.edu, (806) 746-6101;

    E-Print Network [OSTI]

    Mukhtar, Saqib

    . Justin Tuggle, CropDocs Consulting, Brownfield, TX, and it was seeded at a rate of ~5 lbs./A due and net return on variable costs: At $12.50-14.25/cwt. (contracted with West Texas Guar, Brownfield, TX, Brownfield) $14.25 $14.00 $12.50 Gross return $78.25 $122.50 $87.50 Variable costs of production $54.25 $56

  6. ar avalanche detector: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (74:20:6), ArCF4CH4 (67:30:3), ArCF4CO2 (65:30:5) mixtures for the HERA-B Muon Detector HEP - Experiment (arXiv) Summary: The Muon Detector of the HERA-B experiment at DESY...

  7. Old Sol's new use Fourteen solar ar-

    E-Print Network [OSTI]

    Inside &ONLINE Old Sol's new use Fourteen solar ar- rays grace the rooftops of two HRES buildings therebelgroupInterahamwefoundheron the road in a remote region in the eastern Democratic Republic of the Congo- ductingfocusgroupinterviewswithmem- bers of the community. Looking horrorin theface HHI researchers don't flinch in examination

  8. A novel three dimensional semimetallic MoS{sub 2}

    SciTech Connect (OSTI)

    Tang, Zhen-Kun [Beijing Computational Science Research Center, Beijing 100084 (China); Departments of Physics and Electronics, Hengyang Normal University, Hengyang 421008 (China); Zhang, Hui; Liu, Li-Min, E-mail: limin.liu@csrc.ac.cn [Beijing Computational Science Research Center, Beijing 100084 (China); Liu, Hao [Chengdu Green Energy and Green Manufacturing Technology R and D Center, Chengdu, Sichuan 610207 (China); Lau, Woon-Ming [Beijing Computational Science Research Center, Beijing 100084 (China); Chengdu Green Energy and Green Manufacturing Technology R and D Center, Chengdu, Sichuan 610207 (China)

    2014-05-28T23:59:59.000Z

    Transition metal dichalcogenides (TMDs) have many potential applications, while the performances of TMDs are generally limited by the less surface active sites and the poor electron transport efficiency. Here, a novel three-dimensional (3D) structure of molybdenum disulfide (MoS{sub 2}) with larger surface area was proposed based on first-principle calculations. 3D layered MoS{sub 2} structure contains the basal surface and joint zone between the different nanoribbons, which is thermodynamically stable at room temperature, as confirmed by first principles molecular dynamics calculations. Compared the two-dimensional layered structures, the 3D MoS{sub 2} not only owns the large surface areas but also can effectively avoid the aggregation. Interestingly, although the basal surface remains the property of the intrinsic semiconductor as the bulk MoS{sub 2}, the joint zone of 3D MoS{sub 2} exhibits semimetallic, which is derived from degenerate 3d orbitals of the Mo atoms. The high stability, large surface area, and high conductivity make 3D MoS{sub 2} have great potentials as high performance catalyst.

  9. Diffusion Barrier Selection from Refractory Metals (Zr, Mo and Nb) via Interdiffusion Investigation for U-Mo RERTR Fuel Alloy

    SciTech Connect (OSTI)

    K. Huang; C. Kammerer; D. D. Keiser, Jr.; Y. H. Sohn

    2014-04-01T23:59:59.000Z

    U-Mo alloys are being developed as low enrichment monolithic fuel under the Reduced Enrichment for Research and Test Reactor (RERTR) Program. Diffusional interactions between the U-Mo fuel alloy and Al-alloy cladding within the monolithic fuel plate construct necessitate incorporation of a barrier layer. Fundamentally, a diffusion barrier candidate must have good thermal conductivity, high melting point, minimal metallurgical interaction, and good irradiation performance. Refractory metals, Zr, Mo, and Nb are considered based on their physical properties, and the diffusion behavior must be carefully examined first with U-Mo fuel alloy. Solid-to-solid U-10wt.%Mo vs. Mo, Zr, or Nb diffusion couples were assembled and annealed at 600, 700, 800, 900 and 1000 degrees C for various times. The interdiffusion microstructures and chemical composition were examined via scanning electron microscopy and electron probe microanalysis, respectively. For all three systems, the growth rate of interdiffusion zone were calculated at 1000, 900 and 800 degrees C under the assumption of parabolic growth, and calculated for lower temperature of 700, 600 and 500 degrees C according to Arrhenius relationship. The growth rate was determined to be about 10 3 times slower for Zr, 10 5 times slower for Mo and 10 6 times slower for Nb, than the growth rates reported for the interaction between the U-Mo fuel alloy and pure Al or Al-Si cladding alloys. Zr, however was selected as the barrier metal due to a concern for thermo- mechanical behavior of UMo/Nb interface observed from diffusion couples, and for ductile-to-brittle transition of Mo near room temperature.

  10. Effect of Mo Dispersion Size and Water Vapor on Oxidation of Two-Phase Directionally Solidified NiAl-9Mo In-Situ Composites

    SciTech Connect (OSTI)

    Brady, Michael P [ORNL] [ORNL; Bei, Hongbin [ORNL] [ORNL; Meisner, Roberta Ann [ORNL] [ORNL; Lance, Michael J [ORNL] [ORNL; Tortorelli, Peter F [ORNL] [ORNL

    2014-01-01T23:59:59.000Z

    Oxidation of two-phase NiAl-9Mo eutectics with 3 different growth rates/2nd phase Mo dispersion sizes were investigated at 900 C in air and air with 10% water vapor. Good oxidation resistance via alumina formation was observed in dry air, with Mo volatilization loss minimized by fine submicron Mo dispersions. However, extensive Mo volatilization and in-place internal oxidation of prior Mo phase regions was observed in wet air oxidation. Ramifications of this phenomenon for the development of multi-phase high-temperature alloys are discussed

  11. 2-Stage Melting in 2 Dimensions - Te/mo(110) 

    E-Print Network [OSTI]

    STOLZENBERG, M.; Lyuksyutov, Igor F.; BAUER, E.

    1993-01-01T23:59:59.000Z

    Arsenate and Arsenite Retention and Release in Oxide and Sulfide Dominated Systems Principal Investigator: Richard H. Loeppert Co-Investigators: Amita Jain Klaus Raven Jianlin Wang Soil & Crop Sciences Dept. Texas A&M University College Station, TX... of the specific reagents. Selective extractions also give clues concern- ing the role that suspected biological agents may have on the mobilization and uptake of arsenic. Selective extractions were performed on both oxidized and reduced sediments. Selective...

  12. Fracture and fatigue resistance of MoSiB alloys for ultrahigh-temperature structural applications

    E-Print Network [OSTI]

    Ritchie, Robert

    Fracture and fatigue resistance of Mo­Si­B alloys for ultrahigh-temperature structural applications­Mo3Si­Mo5SiB2 alloys, which utilize a continuous a-Mo matrix to achieve unprecedented room. Introduction For applications such as aerospace engines and power generation, future advancements are limited

  13. Oxidation, Reduction, and Condensation of Alcohols over (MO3...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Alcohols over (MO3)3 (MMo, W) Nanoclusters . Abstract: The reactions of deuterated methanol, ethanol, 1-propanol, 1-butanol, 2-propanol, 2-butanol and t-butanol over cyclic...

  14. Co-Mo Electric Cooperative- Residential Energy Efficiency Rebate Program

    Broader source: Energy.gov [DOE]

    Co-Mo Electric Cooperative provides rebates to residential and commercial members who install air source, dual fuel, and/or geothermal heat pumps, and certain energy efficient appliances. The...

  15. 9 Cr-- 1 Mo steel material for high temperature application

    DOE Patents [OSTI]

    Jablonski, Paul D; Alman, David; Dogan, Omer; Holcomb, Gordon; Cowen, Christopher

    2012-11-27T23:59:59.000Z

    One or more embodiments relates to a high-temperature, titanium alloyed, 9 Cr-1 Mo steel exhibiting improved creep strength and oxidation resistance at service temperatures up to 650.degree. C. The 9 Cr-1 Mo steel has a tempered martensite microstructure and is comprised of both large (0.5-3 .mu.m) primary titanium carbides and small (5-50 nm) secondary titanium carbides in a ratio of. from about 1:1.5 to about 1.5:1. The 9 Cr-1 Mo steel may be fabricated using exemplary austenizing, rapid cooling, and tempering steps without subsequent hot working requirements. The 9 Cr-1 Mo steel exhibits improvements in total mass gain, yield strength, and time-to-rupture over ASTM P91 and ASTM P92 at the temperature and time conditions examined.

  16. Q value of the 100Mo Double-Beta Decay

    E-Print Network [OSTI]

    S. Rahaman; V. -V. Elomaa; T. Eronen; J. Hakala; A. Jokinen; J. Julin; A. Kankainen; A. Saastamoinen; J. Suhonen; C. Weber; J. Äystö

    2007-12-20T23:59:59.000Z

    Penning trap measurements using mixed beams of 100Mo - 100Ru and 76Ge - 76Se have been utilized to determine the double-beta decay Q-values of 100Mo and 76Ge with uncertainties less than 200 eV. The value for 76Ge, 2039.04(16) keV is in agreement with the published SMILETRAP value. The new value for 100Mo, 3034.40(17) keV is 30 times more precise than the previous literature value, sufficient for the ongoing neutrinoless double-beta decay searches in 100Mo. Moreover, the precise Q-value is used to calculate the phase-space integrals and the experimental nuclear matrix element of double-beta decay.

  17. Ethanol Conversion on Cyclic (MO3)3 (M = Mo, W) Clusters

    SciTech Connect (OSTI)

    Li, Zhenjun; Fang, Zongtang; Kelley, Matthew S.; Kay, Bruce D.; Rousseau, Roger J.; Dohnalek, Zdenek; Dixon, David A.

    2014-03-06T23:59:59.000Z

    Oxides of molybdenum and tungsten are an important class of catalytic materials with applications ranging from isomerization of alkanes and alkenes, partial oxidation of alcohols, selective reduction of nitric oxide and metathesis of alkeness.[1-10] While many studies have focused on the structure - function relationships, the nature of high catalytic activity is still being extensively investigated. There is a general agreement that the activity of supported MOx (M = W, Mo) catalysts is correlated with the presence of acidic sites, where the catalytic activity is strongly affected by the type of oxide support, delocalization of electron density, structures of tungsten oxide domains and presence of protons

  18. MoSe2 thin films synthesized by solid state reactions between Mo and Se J. Pouzet (1) and J. C. Bernede (2)

    E-Print Network [OSTI]

    Boyer, Edmond

    807 MoSe2 thin films synthesized by solid state reactions between Mo and Se thin films J. Pouzet (1 reaction, induced by annealing, between the Mo and Se constituents in thin films form. The films have been thin films annealed under selenium pressure at only 770 K are well crystallized. The electrical

  19. Coated U(Mo) Fuel: As-Fabricated Microstructures

    SciTech Connect (OSTI)

    Emmanuel Perez; Dennis D. Keiser, Jr.; Ann Leenaers; Sven Van den Berghe; Tom Wiencek

    2014-04-01T23:59:59.000Z

    As part of the development of low-enriched uranium fuels, fuel plates have recently been tested in the BR-2 reactor as part of the SELENIUM experiment. These fuel plates contained fuel particles with either Si or ZrN thin film coating (up to 1 µm thickness) around the U-7Mo fuel particles. In order to best understand irradiation performance, it is important to determine the starting microstructure that can be observed in as-fabricated fuel plates. To this end, detailed microstructural characterization was performed on ZrN and Si-coated U-7Mo powder in samples taken from AA6061-clad fuel plates fabricated at 500°C. Of interest was the condition of the thin film coatings after fabrication at a relatively high temperature. Both scanning electron microscopy and transmission electron microscopy were employed. The ZrN thin film coating was observed to consist of columns comprised of very fine ZrN grains. Relatively large amounts of porosity could be found in some areas of the thin film, along with an enrichment of oxygen around each of the the ZrN columns. In the case of the pure Si thin film coating sample, a (U,Mo,Al,Si) interaction layer was observed around the U-7Mo particles. Apparently, the Si reacted with the U-7Mo and Al matrix during fuel plate fabrication at 500°C to form this layer. The microstructure of the formed layer is very similar to those that form in U-7Mo versus Al-Si alloy diffusion couples annealed at higher temperatures and as-fabricated U-7Mo dispersion fuel plates with Al-Si alloy matrix fabricated at 500°C.

  20. ar diffusion coefficient: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    diffusion is examined. Kazuhiko Seki; Saurabh Mogre; Shigeyuki Komura 2014-02-05 4 Fractal diffusion coefficient from dynamical zeta functions Nonlinear Sciences (arXiv)...

  1. ar kr xe: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Detectors, Gas Electron Multipliers, Geiger-mode APDs. . .. 12 85 Neutrinoless Double Beta Decay of 134Xe HEP - Phenomenology (arXiv) Summary: In view of recent great...

  2. ArKion Systems | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:Ezfeedflag JumpID-fTriWildcatAntrim County,Delhi (NCT), IndiaOpenAquate SolarArKion Systems

  3. Agricultural Research Service (ARS) Research Participation Program -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProducts (VAP) VAP7-0973Managed by ORAU Agricultural Research Service (ARS)

  4. Multiphonon resonant Raman scattering in MoS{sub 2}

    SciTech Connect (OSTI)

    Go?asa, K., E-mail: Katarzyna.Golasa@fuw.edu.pl; Grzeszczyk, M.; Wysmo?ek, A.; Babi?ski, A. [Faculty of Physics, University of Warsaw, ul. Ho?a 69, 00-681 Warszawa (Poland); Leszczy?ski, P.; Faugeras, C.; Nicolet, A. A. L.; Potemski, M. [Laboratoire National des Champs Magnétiques Intenses, CNRS-UJF-UPS-INSA, 25, avenue des Martyrs, 38042 Grenoble (France)

    2014-03-03T23:59:59.000Z

    Optical emission spectrum of a resonantly (??=?632.8?nm) excited molybdenum disulfide (MoS{sub 2}) is studied at liquid helium temperature. More than 20 peaks in the energy range spanning up to 1400?cm{sup ?1} from the laser line, which are related to multiphonon resonant Raman scattering processes, are observed. The attribution of the observed lines involving basic lattice vibrational modes of MoS{sub 2} and both the longitudinal (LA(M)) and the transverse (TA(M) and/or ZA(M)) acoustic phonons from the vicinity of the high-symmetry M point of the MoS{sub 2} Brillouin zone is proposed.

  5. Identification of phases in the interaction layer between U-Mo-Zr/Al and U-Mo-Zr/Al-Si

    SciTech Connect (OSTI)

    Varela, C.L. Komar; Arico, S.F.; Mirandou, M.; Balart, S.N. [Departamento Materiales, GIDAT, GAEN, CNEA, Avda. Gral Paz 1499, B1650KNA, San Martin (Argentina); Gribaudo, L.M. [Departamento Materiales, GIDAT, GAEN, CNEA, Avda. Gral Paz 1499, B1650KNA, San Martin (Argentina); CONICET, Avda. Rivadavia 1917, C1033AAJ, Buenos Aires (Argentina)

    2008-07-15T23:59:59.000Z

    Out-of-pile diffusion experiments were performed between U-7wt.% Mo-1wt.% Zr and Al or Al A356 (7,1wt.% Si) at 550 deg. C. In this work morphological characterization and phase identification on both interaction layer are presented. They were carried out by the use of different techniques: optical and scanning electron microscopy, X-Ray diffraction and WDS microanalysis. In the interaction layer U-7wt.% Mo-1wt.% Zr/Al, the phases UAl{sub 3}, UAl{sub 4}, Al{sub 20}Mo{sub 2}U and Al{sub 43}Mo{sub 4}U{sub 6} were identified. In the interaction layer U-7wt.% Mo-1wt.% Zr/Al A356, the phases U(Al, Si) with 25at.% Si and Si{sub 5}U{sub 3} were identified. This last phase, with a higher Si concentration, was identified with XRD Synchrotron radiation performed at the National Synchrotron Light Laboratory (LNLS), Campinas, Brasil. (author)

  6. Hydrotreatment of Athabasca bitumen derived gas oil over Ni-Mo, Ni-W, and Co-Mo catalysts

    SciTech Connect (OSTI)

    Diaz-Real, R.A.; Mann, R.S.; Sambi, I.S. (Univ. of Ottawa, Ontario (Canada). Dept. of Chemical Engineering)

    1993-07-01T23:59:59.000Z

    The hydrotreatment of Athabasca bitumen derived heavy gas oil containing 4.08% S and 0.49% N was carried out in a trickle bed reactor over Ni-W, Ni-Mo, and Co-Mo catalysts supported on zeolite-alumina-silica at 623-698 K, LHSV of 1-4, gas flow rate 890 m[sup 3][sub H2]/m[sup 3][sub oil] (5,000 sef/bbl), and pressure of 6.89 MPa. Analyses for viscosity, density, aniline point, ASTM mid boiling point distillation, C/H ratio, and percentage of N and S in the final product were carried out to characterize the product oil. The amounts of N and S removed indicated the hydrodenitrogenation and hydrodesulfurization activity of the catalysts. Results of zeolite-alumina-silica-supported catalysts are compared to those obtained with commercially available Ni-Mo, Ni-W, and Co-Mo on [gamma]-alumina. Ni-Mo supported on zeolite-alumina-silica was most active and could remove as much as 99 % S and 89% N present in the oil at 698 K. The data for HDN and HDS fitted the pseudo first order model. The kinetic model is described in detail.

  7. alloyed fe-mo powder: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    - TxSpace Summary: The research in this thesis covers the design and implementation of a depleted uranium (DU) powder production system and the initial results of a DU-Zr-Mg alloy...

  8. Representations and Properties of Generalized $A_r$ Statistics

    E-Print Network [OSTI]

    Mohammed Daoud

    2006-06-20T23:59:59.000Z

    A generalization of $A_r$ statistics is proposed and developed. The generalized $A_r$ quantum statistics is completely specified by a set of Jacobson generators satisfying a set of triple algebraic relations. Fock-Hilbert representations and Bargmann-Fock realizations are derived.

  9. Revised isotopic (40 Ar) age for the lamproite volcano of

    E-Print Network [OSTI]

    Utrecht, Universiteit

    Revised isotopic (40 Ar/39 Ar) age for the lamproite volcano of Cabezos Negros, Fortuna Basin (lamproites) of the Fortuna Basin in southeast Spain. This age is significantly older than earlier reported K. Because the volcanic rocks are intercalated in the stratigraphic sequence of the Fortuna Basin directly

  10. Effect of surface derived hydrocarbon impurities on Ar plasma properties

    SciTech Connect (OSTI)

    Fox-Lyon, Nick; Oehrlein, Gottlieb S., E-mail: Oehrlein@umd.edu [Department of Materials Science and Engineering and the Institute for Research and Applied Physics, University of Maryland, College Park, MD 20742 (United States); Godyak, Valery [Department of Electrical Engineering and Computer Science, University of Michigan, Ann Arbor, MI 48109-2122 (United States)

    2014-05-15T23:59:59.000Z

    The authors report on Langmuir probe measurements that show that hydrocarbon surfaces in contact with Ar plasma cause changes of electron energy distribution functions due to the flux of hydrogen and carbon atoms released by the surfaces. The authors compare the impact on plasma properties of hydrocarbon species gasified from an etching hydrocarbon surface with injection of gaseous hydrocarbons into Ar plasma. They find that both kinds of hydrocarbon injections decrease electron density and slightly increase electron temperatures of low pressure Ar plasma. For low percentages of impurities (?1% impurity in Ar plasma explored here), surface-derived hydrocarbon species and gas phase injected hydrocarbon molecules cause similar changes of plasma properties for the same number of hydrocarbon molecules injected into Ar with a decrease in electron density of ?4%.

  11. Texas AgriLife Research & Extension Center, 1102 East FM 1294, Lubbock, TX 79403 (806) 746-6101, FAX (806) 746-4057, ctrostle@ag.tamu.edu

    E-Print Network [OSTI]

    Mukhtar, Saqib

    79403 (806) 746-6101, FAX (806) 746-4057, ctrostle@ag.tamu.edu Guar Update, West Texas currently consists of two primary entities: · West Texas Guar, Brownfield, TX, (806) 637-4662, http://www.westtexasguar.com (Klint Forbes, owner/manager, klint@westtexasguar.com). West Texas Guar currently serves as the only

  12. To be published in In Proceedings of ACM Eye Tracking Research & Applications Symposium, Austin, TX, 2010 Qualitative and Quantitative Scoring and Evaluation of the Eye Movement

    E-Print Network [OSTI]

    Oleg, Komogortsev - Department of Computer Science, Texas State University

    To be published in In Proceedings of ACM Eye Tracking Research & Applications Symposium, Austin, TX, 2010 Qualitative and Quantitative Scoring and Evaluation of the Eye Movement Classification Algorithms presents a set of qualitative and quantitative scores designed to assess performance of any eye movement

  13. Protein degradation in a TX-TL cell-free expression system using ClpXP protease Zachary Z. Sun1

    E-Print Network [OSTI]

    Murray, Richard M.

    ! 1! Protein degradation in a TX-TL cell-free expression system using ClpXP protease AUTHORS that play an important role for in vivo circuit dynamics ­ namely protein degradation and protein dilution-TL with ClpXP, an AAA+ protease pair that selectively degrades tagged proteins [11], to provide finely

  14. Published in Proceedings of Digital Libraries 95, Austin, TX, June, 1995, pp. 39-48. Collection Maintenance in the Digital Library

    E-Print Network [OSTI]

    Ackerman, Mark S.

    Published in Proceedings of Digital Libraries Ô95, Austin, TX, June, 1995, pp. 39-48. Collection Maintenance in the Digital Library Mark S. Ackerman Roy T. Fielding Information and Computer Science Maintenance will be critical to digital libraries, especially those that promote broad access to diverse

  15. Structure And Radiation Damage Behavior Of Epitaxial CrxMo1-x...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    And Radiation Damage Behavior Of Epitaxial CrxMo1-x Alloy Thin Films On MgO. Structure And Radiation Damage Behavior Of Epitaxial CrxMo1-x Alloy Thin Films On MgO. Abstract:...

  16. Adsorption of Potassium on the MoS2(100) Surface: A First-Principles...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Potassium on the MoS2(100) Surface: A First-Principles Investigation. Adsorption of Potassium on the MoS2(100) Surface: A First-Principles Investigation. Abstract: Periodic density...

  17. High Capacity MoO3 Nanoparticle Li-Ion Battery Anode

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    energy functional were employed.) 10 AccomplishmentStatus Theoretical changes in Li-ion intercalated -MoO 3 Mo Li O * Four Li inserted in a theoretical nanoparticle. * 9 ps...

  18. Domestic production of medical isotope Mo-99 moves a step closer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Domestic production of medical isotope Mo-99 Domestic production of medical isotope Mo-99 moves a step closer Irradiated uranium fuel has been recycled and reused for molybdenum-99...

  19. Ar/Ar ages from transitionally magnetized lavas on La Palma, Canary Islands, and the geomagnetic instability timescale

    E-Print Network [OSTI]

    Singer, Bradley S.

    Ar/Ar ages from transitionally magnetized lavas on La Palma, Canary Islands, and the geomagnetic the north and south walls of Barranco de los Tilos on the island of La Palma, Canary Islands, reveals from transitionally magnetized lavas on La Palma, Canary Islands, and the geomagnetic instability

  20. Energy gain spectroscopic study of Ar{sup q+}-Ar collisions at 40 qeV

    SciTech Connect (OSTI)

    Vancura, J.; Kostroun, V.O.

    1992-12-31T23:59:59.000Z

    Energy gain spectra of Ar{sup q+}(8 {le} q {le} 16) on Ar at 40 qeV collision energy and 0.4 qeV energy resolution are presented. Capture into definite states of the projectile is observed which seems to exhibit a definite even-odd projectile charge state dependence.

  1. Corrosion report for the U-Mo fuel concept

    SciTech Connect (OSTI)

    Henager, Jr., Charles H. [Pacific Northwest National Laboratory (PNNL), Richland, WA (US); Bennett, Wendy D. [Pacific Northwest National Laboratory (PNNL), Richland, WA (US); Doherty, Ann L. [Pacific Northwest National Laboratory (PNNL), Richland, WA (US); Fuller, E. S. [Pacific Northwest National Laboratory (PNNL), Richland, WA (US); Hardy, John S. [Pacific Northwest National Laboratory (PNNL), Richland, WA (US); Omberg, Ronald P. [Pacific Northwest National Laboratory (PNNL), Richland, WA (US)

    2014-08-28T23:59:59.000Z

    The Fuel Cycle Research and Development (FCRD) program of the Office of Nuclear Energy (NE) has implemented a program to develop a Uranium-Molybdenum (U-Mo) metal fuel for Light Water Reactors (LWR)s. Uranium-Molybdenum fuel has the potential to provide superior performance based on its thermo-physical properties, which includes high thermal conductivity for less stored heat energy. With sufficient development, it may be able to provide the Light Water industry with a melt-resistant accident tolerant fuel with improved safety response. However, the corrosion of this fuel in reactor water environments needs to be further explored and optimized by additional alloying. The Pacific Northwest National Laboratory has been tasked with performing ex-reactor corrosion testing to characterize the performance of U-Mo fuel. This report documents the results of the effort to characterize and develop the U-Mo metal fuel concept for LWRs with regard to corrosion testing. The results of a simple screening test in buffered water at 30°C using surface alloyed U-10Mo is documented and discussed. The screening test was used to guide the selection of several potential alloy improvements that were found and are recommended for further testing in autoclaves to simulate PWR water conditions more closely.

  2. MO"BIUS-INVARIANT KNOT ENERGIES R.B. KUSNER

    E-Print Network [OSTI]

    Sullivan, John M.

    for divergence-free vector fields which arise in modeling incompressible fluid flow.6,7These new knot energies MO"BIUS-INVARIANT KNOT ENERGIES R.B. KUSNER, Urbana, IL, USA 61801-2975 There has been recent interest in knot energies among mathematicians

  3. MO"BIUS-INVARIANT KNOT ENERGIES R.B. KUSNER

    E-Print Network [OSTI]

    for divergence-free vector fields which arise in modeling incompressible fluid flow.? These new knot energies may MO"BIUS-INVARIANT KNOT ENERGIES R.B. KUSNER, Urbana, IL, USA 61801-2975 There has been recent interest in knot energies among mathematicians

  4. Introduction THE YERINGTON DISTRICT, Nevada, contains porphyry Cu(Mo),

    E-Print Network [OSTI]

    Barton, Mark D.

    55 Introduction THE YERINGTON DISTRICT, Nevada, contains porphyry Cu(Mo), Cu skarn, Fe oxide with the Jurassic Yerington batholith, which serves as either host rock or as source for heat and ma- terials of the Yerington Porphyry Copper District: Magmatic to Nonmagmatic Sources of Hydrothermal Fluids, Their Flow Paths

  5. Combined U-Th/He and 40Ar/39Ar geochronology of post-shield lavas from the Mauna Kea and Kohala volcanoes, Hawaii

    SciTech Connect (OSTI)

    Aciego, S.M.; Jourdan, F.; DePaolo, D.J.; Kennedy, B.M.; Renne, P.R.; Sims, K.W.W.

    2009-10-01T23:59:59.000Z

    Late Quaternary, post-shield lavas from the Mauna Kea and Kohala volcanoes on the Big Island of Hawaii have been dated using the {sup 40}Ar/{sup 39}Ar and U-Th/He methods. The objective of the study is to compare the recently demonstrated U-Th/He age method, which uses basaltic olivine phenocrysts, with {sup 40}Ar/{sup 39}Ar ages measured on groundmass from the same samples. As a corollary, the age data also increase the precision of the chronology of volcanism on the Big Island. For the U-Th/He ages, U, Th and He concentrations and isotopes were measured to account for U-series disequilibrium and initial He. Single analyses U-Th/He ages for Hamakua lavas from Mauna Kea are 87 {+-} 40 ka to 119 {+-} 23 ka (2{sigma} uncertainties), which are in general equal to or younger than {sup 40}Ar/{sup 39}Ar ages. Basalt from the Polulu sequence on Kohala gives a U-Th/He age of 354 {+-} 54 ka and a {sup 40}Ar/{sup 39}Ar age of 450 {+-} 40 ka. All of the U-Th/He ages, and all but one spurious {sup 40}Ar/{sup 39}Ar ages conform to the previously proposed stratigraphy and published {sup 14}C and K-Ar ages. The ages also compare favorably to U-Th whole rock-olivine ages calculated from {sup 238}U - {sup 230}Th disequilibria. The U-Th/He and {sup 40}Ar/{sup 39}Ar results agree best where there is a relatively large amount of radiogenic {sup 40}Ar (>10%), and where the {sup 40}Ar/{sup 36}Ar intercept calculated from the Ar isochron diagram is close to the atmospheric value. In two cases, it is not clear why U-Th/He and {sup 40}Ar/{sup 39}Ar ages do not agree within uncertainty. U-Th/He and {sup 40}Ar/{sup 39}Ar results diverge the most on a low-K transitional tholeiitic basalt with abundant olivine. For the most alkalic basalts with negligible olivine phenocrysts, U-Th/He ages were unattainable while {sup 40}Ar/{sup 39}Ar results provide good precision even on ages as low as 19 {+-} 4 ka. Hence, the strengths and weaknesses of the U-Th/He and {sup 40}Ar/{sup 39}Ar methods are complimentary for basalts with ages of order 100-500 ka.

  6. The growth and characterization of LiGd?(Mo0?)? single crystals

    E-Print Network [OSTI]

    Reimund, James Allyn

    1981-01-01T23:59:59.000Z

    ' C/second 37 Pyroelectric Current vs. Temperature dT/dt = 30' C/second 180' Domains (Gd (MoO ) ) 37 39 INTRODUCTION This thesis discusses the growth and some single crystalline properties of lithium-gadolinium-molybdate of the type LiGd (Mo...O ) 3 45' This compound is one of the three thus far discovered compounds of the lithium ? gadolinium-molybdate (LGMO) system. In general, this system can be expressed as Li2Mo04. XGd2(Mo04)3, where LiGd3(MoO, )5 4 5 single crystals synthesize when X...

  7. Single-crystal sup 40 Ar/ sup 39 Ar dating of the Olorgesailie Formation, southern Kenya rift

    SciTech Connect (OSTI)

    Deino, A. (Geochronology Center of the Inst. of Human Origins, Berkeley, CA (United States)); Potts, R. (Smithsonian Institution, Washington, DC (United States))

    1990-06-10T23:59:59.000Z

    Single-crystal laser fusion {sup 40}Ar/{sup 39}Ar analyses and several conventional bulk fusion {sup 40}K- {sup 40}Ar dates have been used to determine the age of volcaniclastic strata within the Olorgesailie Formation and of associated volcanic and sedimentary units of the southern Kenya rift. In the principal exposures along the southern edge of the Legemunge Plain, the formation spans the interval from approximately 500 to 1,000 ka. Deposition continued to the east along the Ol Keju Nyiro river where a tuff near the top of the formation has been dated at 215 ka. In these exposures, the formation is unconformably overlain by sediments dated at 49 ka. A possible source for the Olorgesailie tephra, the Ol Doinyo Nyokie volcanic complex, contains as ash flow dated at {approximately} 1 Ma, extending the known age range of this complex to encompass that of virtually the entire Olorgesailie Formation in the Legemunge Plain. These geologic examples illustrate the importance of the single-crystal {sup 40}Ar/{sup 39}Ar dating technique whereby contaminant, altered, or otherwise aberrant grains can be identified and eliminated from the determination of eruptive ages for reworked or altered pyroclastic deposits. The authors have presented a computer-modeling procedure based on an inverse-isochron analysis that promotes a more objective approach to trimming {sup 40}Ar/{sup 39}Ar isotope data sets of this type.

  8. MUSCLE ACTIVITY DETECTION FROM MYOELECTRIC SIGNALS BASED ON THE AR-GARCH MODEL

    E-Print Network [OSTI]

    Bouaynaya, Nidhal

    MUSCLE ACTIVITY DETECTION FROM MYOELECTRIC SIGNALS BASED ON THE AR-GARCH MODEL Ghulam Rasool Heteroscedastic (AR-GARCH) process, which captures the heteroscedasticity of the signal. The Akaike information cri- terion test confirms that the AR-GARCH model better fits the EMG signal than the stationary AR

  9. Patterns of Choice: The Prix Ars Electronica Jury Sessions

    E-Print Network [OSTI]

    Offenhuber, Dietmar

    This article investigates the social structures reflected in the annual jury sessions of the Prix Ars Electronica, a major media art competition—the composition, the temporal evolution and ultimately the decisions of these ...

  10. NEGLIGIBLE CREEP CONDITIONS FOR MOD 9 CR 1 MO STEEL

    SciTech Connect (OSTI)

    Ren, Weiju [ORNL; Riou, Bernard [AREVA Group; Escaravage, Claude [AREVA Group; Swindeman, Robert W [ORNL; Cabrillat, Marie-Th?r?se [CEA Cadarache, St. Paul lex Durance, France; Allais, Lucien [CEA, Saclay, France

    2006-01-01T23:59:59.000Z

    Mod 9 Cr 1 Mo Steel (grade 91) is one of the materials envisaged for the Reactor Pressure Vessel of Very High Temperature Reactors. To avoid the implementation of a surveillance program covering the monitoring of the creep damage throughout the whole life of the reactor, it is recommended to operate the Reactor Pressure Vessel in the negligible creep regime. In this paper, the background of negligible creep criteria available in nuclear Codes is first recalled and their limitations were analyzed. Then, guidance for deriving criteria more appropriate for mod 9 Cr 1 Mo steel is provided. Finally, R&D actions in the U. S. and France to support the new approaches are discussed and recommended.

  11. Dislocations With Edge Components in Nanocrystalline bcc Mo

    SciTech Connect (OSTI)

    G. M. Cheng; W. Z. Xu; W. W. Jian; H. Yuan; M. H. Tsai; Y. T. Zhu; Y. F. Zhang; Paul C. Millett

    2013-07-01T23:59:59.000Z

    We report high-resolution transmission electron microscopy (HRTEM) observation of a high density of dislocations with edge components (approximately 1016 m-2) in nanocrystalline (NC) body-centered cubic (bcc) Mo prepared by high-pressure torsion. We also observed for the first time of the 1/2 <111> and <001> pure edge dislocations in NC Mo. Crystallographic analysis and image simulations reveal that the best way using HRTEM to study dislocations with edge components in bcc systems is to take images along <110> zone axis, from which it is possible to identify 1/2 <111> pure edge dislocations, and edge components of 1/2 <111> and <001> mixed dislocations. The <001> pure edge dislocations can only be identified from <100> zone axis. The high density of dislocations with edge components is believed to play a major role in the reduction of strain rate sensitivity in NC bcc metals and alloys.

  12. Charge and magnetic states of Mn-, Fe-, and Co-doped monolayer MoS{sub 2}

    SciTech Connect (OSTI)

    Lin, Xianqing [State Key Laboratory of Low-Dimensional Quantum Physics, Department of Physics, Tsinghua University, Beijing 100084 (China); Collaborative Innovation Center of Quantum Matter, Beijing 100084 (China); Department of Applied Physics, Zhejiang University of Technology, Hangzhou 310023 (China); Ni, Jun, E-mail: junni@mail.tsinghua.edu.cn [State Key Laboratory of Low-Dimensional Quantum Physics, Department of Physics, Tsinghua University, Beijing 100084 (China); Collaborative Innovation Center of Quantum Matter, Beijing 100084 (China)

    2014-07-28T23:59:59.000Z

    First-principles calculations have been performed to investigate the electronic and magnetic properties of monolayer MoS{sub 2} substitutionally doped with Mn, Fe, and Co in possible charge states (q). We find that the Mn, Fe, and Co dopants substituting for a Mo atom in monolayer MoS{sub 2} (Mn@Mo, Fe@Mo, and Co@Mo) are all magnetic in their neutral and charge states except in the highest positive charge states. Mn@Mo, Fe@Mo, and Co@Mo have the same highest negative charge states of q=?2 for chemical potential of electron just below the conduction band minimum, which corresponds to the electron doping. In the q=?2 state, Mn@Mo has a much larger magnetic moment than its neutral state with the antiferromagnetic coupling between the Mn dopant and its neighboring S atoms maintained, while Fe@Mo and Co@Mo have equal or smaller magnetic moments than their neutral states. The possible charge states of Mn@Mo, Fe@Mo, and Co@Mo and the variation of the magnetic moments for different dopants and charge states are due to the change of the occupation and energy of the anti-bonding defect levels in the band gap. The rich magnetic properties of the neutral and charge states suggest possible realization of the substitutionally Mn-, Fe-, and Co-doped monolayer MoS{sub 2} as dilute magnetic semiconductors.

  13. NO. REV. MO. _ ALSEP/LCRU EMC Test Results

    E-Print Network [OSTI]

    Rathbun, Julie A.

    NO. REV. MO. ATM 1050 _ ALSEP/LCRU EMC Test Results PAGE 1 OF 10 DATE 19 August 1971 The results of the ALSEP/LCRU EMC test are reported in this ATM. C~.·--~ s--·~e'Jn~,__')!).Prepared by:__~~~"f--.;;.~-------- Approved by: ~JM.MD. ithian #12;NO. RIV. NO. ATM 1050 ALSEP/LCRU EMC Test Results 2 10PAGE OF Aall

  14. Long-term corrosion of Cr-Mo steels in superheated steam at 482 and 538/sup 0/C. [21/4 Cr-1 Mo; 9 Cr-1 Mo; Sumitomo 9 Cr-2 Mo; Sandvik HT-9

    SciTech Connect (OSTI)

    Griess, J.C.; DeVan, J.H.; Maxwell, W.A.

    1980-01-01T23:59:59.000Z

    The corrosion of several Cr-Mo ferritic steels was investigated in superheated steam at an operating power plant. Tests were conducted at 482 and 538/sup 0/C (900 and 1000/sup 0/F) in a once-through loop for times up to 28,000 h. Chromium concentrations ranged from 2.0 to 11.3%, and the effect of surface preparation on corrosion was investigated. Only one of many specimens showed evidence of exfoliation at 482/sup 0/C, but at 538/sup 0/C exfoliation occurred on at least some of the specimens of most materials; the exceptions were the alloy with the highest chromium content (Sandvik HT-9), one heat of 9 Cr-1 Mo steel with the highest silicon content, and Sumitomo 9 Cr-2 Mo steel, which was in test for only 19,000 h. Parabolic oxidation kinetics adequately described the corrosion process for about the first year, after which corrosion rates were constant and lower than predicted from extrapolation of the initial part of the penetration versus time curves. With chromium concentrations between 2 and 9%, corrosion behavior was independent of chromium content, and corrosion was only slightly less with Sandvik HT-9. Corrosion was nearly independent of surface preparation, but in two cases the presence of mill scale on the surface prior to steam exposure seemed to retard oxidation in steam. 11 figures, 5 tables.

  15. IRRADIATION PERFORMANCE OF U-Mo MONOLITHIC FUEL

    SciTech Connect (OSTI)

    M.K. Meyer; J. Gan; J.-F. Jue; D.D. Keiser; E. Perez; A. Robinson; D.M. Wachs; N. Woolstenhulme; G.L. Hofman; Y.-S. Kim

    2014-04-01T23:59:59.000Z

    High-performance research reactors require fuel that operates at high specific power to high fission density, but at relatively low temperatures. Research reactor fuels are designed for efficient heat rejection, and are composed of assemblies of thin-plates clad in aluminum alloy. The development of low-enriched fuels to replace high-enriched fuels for these reactors requires a substantially increased uranium density in the fuel to offset the decrease in enrichment. Very few fuel phases have been identified that have the required combination of very-high uranium density and stable fuel behavior at high burnup. UMo alloys represent the best known tradeoff in these properties. Testing of aluminum matrix U-Mo aluminum matrix dispersion fuel revealed a pattern of breakaway swelling behavior at intermediate burnup, related to the formation of a molybdenum stabilized high aluminum intermetallic phase that forms during irradiation. In the case of monolithic fuel, this issue was addressed by eliminating, as much as possible, the interfacial area between U-Mo and aluminum. Based on scoping irradiation test data, a fuel plate system composed of solid U-10Mo fuel meat, a zirconium diffusion barrier, and Al6061 cladding was selected for development. Developmental testing of this fuel system indicates that it meets core criteria for fuel qualification, including stable and predictable swelling behavior, mechanical integrity to high burnup, and geometric stability. In addition, the fuel exhibits robust behavior during power-cooling mismatch events under irradiation at high power.

  16. Single Phase Melt Processed Powellite (Ba,Ca) MoO{sub 4} For The Immobilization Of Mo-Rich Nuclear Waste

    SciTech Connect (OSTI)

    Brinkman, Kyle [Savannah River Site (SRS), Aiken, SC (United States); Marra, James [Savannah River Site (SRS), Aiken, SC (United States); Fox, Kevin [Savannah River Site (SRS), Aiken, SC (United States); Reppert, Jason [Savannah River Site (SRS), Aiken, SC (United States); Crum, Jarrod [Paci fic Northwest National Laboratory , Richland, WA (United States); Tang, Ming [Los Alamos National Laboratory , Los Alamos, NM (United States)

    2012-09-17T23:59:59.000Z

    Crystalline and glass composite materials are currently being investigated for the immobilization of combined High Level Waste (HLW) streams resulting from potential commercial fuel reprocessing scenarios. Several of these potential waste streams contain elevated levels of transition metal elements such as molybdenum (Mo). Molybdenum has limited solubility in typical silicate glasses used for nuclear waste immobilization. Under certain chemical and controlled cooling conditions, a powellite (Ba,Ca)MoO{sub 4} crystalline structure can be formed by reaction with alkaline earth elements. In this study, single phase BaMoO{sub 4} and CaMoO{sub 4} were formed from carbonate and oxide precursors demonstrating the viability of Mo incorporation into glass, crystalline or glass composite materials by a melt and crystallization process. X-ray diffraction, photoluminescence, and Raman spectroscopy indicated a long range ordered crystalline structure. In-situ electron irradiation studies indicated that both CaMoO{sub 4} and BaMoO{sub 4} powellite phases exhibit radiation stability up to 1000 years at anticipated doses with a crystalline to amorphous transition observed after 1 X 10{sup 13} Gy. Aqueous durability determined from product consistency tests (PCT) showed low normalized release rates for Ba, Ca, and Mo (<0.05 g/m{sup 2}).

  17. An APFIM and TEM study of Ni{sub 4}Mo precipitation in a commercial Ni-28% Mo-1.4% Fe-0.4% Cr wt. % alloy

    SciTech Connect (OSTI)

    Thomson, R.C.; Brown, N.; Bates, J.S. [Loughborough Univ. (United Kingdom). Inst. of Polymer Technology and Materials Engineering; Russell, K.F.; Miller, M.K. [Oak Ridge National Lab., TN (United States). Metals and Ceramics Div.

    1998-02-01T23:59:59.000Z

    Ni-Mo alloys containing at least 26 wt.% Mo have a negligible corrosion rate in boiling 10% hydrochloric acid and are therefore used in corrosive environments. A series of commercial Ni-Mo alloys has been developed with subtle variations in chemical composition. These alloys usually contain {approximately} 28 wt.% Mo with additions of up to 5% Fe and Cr. A significant amount of research has been performed to understand the microstructure and properties of these alloys, although most of the effort has concentrated on the Ni-Mo binary system. In some alloys with low Fe and Cr contents, a severe embrittlement problem has been observed due to the formation of the Ni{sub 4}Mo (D1{sub a}-ordered) phase within the microstructure. This research focuses on a commercial alloy with nominal composition Ni-28% Mo-1.4% Fe-0.4% Cr-0.1% Mn-0.003 wt.% C. The material supplied was a heat treatment coupon which had been attached to a large vessel during fabrication. Assessment of the chemical analysis of the alloy suggested that detrimental phases could be present or might appear during subsequent repair work. Therefore, it was important to assess the microstructural condition of the vessel, and in particular the kinetics of precipitation of Ni{sub 4}Mo.

  18. [12.7.20044:01pm] [101114] [Page No. 101] {Eserial}4393-van-Pelt/3d/vanPelt-tx08.3d Van Pelt

    E-Print Network [OSTI]

    Stryker, Michael

    . Prog Brain Res.147:103-114. Corrections indicated in red. #12;[12.7.2004­4:01pm] [101­114] [Page No[12.7.2004­4:01pm] [101­114] [Page No. 101] {Eserial}4393-van-Pelt/3d/vanPelt-tx08.3d Van Pelt U N Research, Vol. 147 ISSN 0079-6123 Copyright ß 2005 Elsevier BV. All rights reserved CHAPTER 8 Molecular

  19. High-performance MoS{sub 2} transistors with low-resistance molybdenum contacts

    SciTech Connect (OSTI)

    Kang, Jiahao; Liu, Wei; Banerjee, Kaustav, E-mail: kaustav@ece.ucsb.edu [Department of Electrical and Computer Engineering, University of California, Santa Barbara, California 93106 (United States)

    2014-03-03T23:59:59.000Z

    In this Letter, molybdenum (Mo) is introduced and evaluated as an alternative contact metal to atomically-thin molybdenum disulphide (MoS{sub 2}), and high-performance field-effect transistors are experimentally demonstrated. In order to understand the physical nature of the interface and highlight the role of the various factors contributing to the Mo-MoS{sub 2} contacts, density functional theory (DFT) simulations are employed, which reveal that Mo can form high quality contact interface with monolayer MoS{sub 2} with zero tunnel barrier and zero Schottky barrier under source/drain contact, as well as an ultra-low Schottky barrier (0.1?eV) at source/drain-channel junction due to strong Fermi level pinning. In agreement with the DFT simulations, high mobility, high ON-current, and low contact resistance are experimentally demonstrated on both monolayer and multilayer MoS{sub 2} transistors using Mo contacts. The results obtained not only reveal the advantages of using Mo as a contact metal for MoS{sub 2} but also highlight the fact that the properties of contacts with 2-dimensional materials cannot be intuitively predicted by solely considering work function values and Schottky theory.

  20. Ion acceleration in Ar-Xe and Ar-He plasmas. I. Electron energy distribution functions and ion composition

    SciTech Connect (OSTI)

    Biloiu, Ioana A.; Scime, Earl E. [Department of Physics, West Virginia University, Morganton, West Virginia 26506 (United States)

    2010-11-15T23:59:59.000Z

    Electron energy distribution functions (eedf), ion production, and ion composition are studied in Ar-Xe and Ar-He expanding helicon plasmas. It was found that under the conditions of constant total flow rate, Xe, in addition to Ar, changes the eedf from Maxwellian-like to Druyvesteyn-like with a shortening of the high energy tail at {approx}15 eV. The electron temperature exponentially decreases from {approx}7 eV in pure Ar plasma to {approx}4 eV in pure Xe plasma. Xenon ions dominate the ion population for Xe filling fractions greater than 10%. The plasma density increases by {approx}15% with increasing Xe fraction. For an Ar-He plasma, increasing the helium fraction increases the electron temperature from {approx}7 eV in pure Ar plasma to {approx}14 eV for a He filling fraction of 80%. The plasma density drops by more than three orders of magnitude from 1.14x10{sup 11} cm{sup -3} to 6.5x10{sup 7} cm{sup -3}. However, the inferred ion densities indicate that even at a helium fraction of 80%, argon ions significantly outnumber helium ions.

  1. Experimental activities supporting commercial U.S. accelerator production of 99-Mo

    SciTech Connect (OSTI)

    Dale, Gregory E [Los Alamos National Laboratory; Chemerisov, Sergey D [ANL; Vandegrift, George F [ANL

    2010-01-01T23:59:59.000Z

    {sup 99m}Tc, the daughter product of {sup 99}Mo, is the most commonly used radioisotope for nuclear medicine in the U.S. Experiments are being performed at Los Alamos National Laboratory and Argonne National Laboratory to demonstrate production of {sup 99}Mo using accelerators. The {sup 100}Mo({gamma},n){sup 99}Mo reaction in an enriched {sup 100}Mo target is currently under investigation. Three scaled low-power production experiments using a 20-MeV electron linac at Argonne have been performed to date. Two of these experiments used natural Mo targets and produced a total of 613 {mu}C of {sup 99}Mo. The third experiment used an enriched {sup 100}Mo target and produced 10.5 mCi of {sup 99}Mo. Following irradiation the targets were dissolved and the low specific activity solution was processed through an ARSII generator from NorthStar Medical Radioisotopes. Yields of {sup 99m}Tc >95% have been observed.

  2. Conceptual design of a new homogeneous reactor for medical radioisotope Mo-99/Tc-99m production

    SciTech Connect (OSTI)

    Liem, Peng Hong [Nippon Advanced Information Service (NAIS Co., Inc.) Scientific Computational Division, 416 Muramatsu, Tokaimura, Ibaraki (Japan); Tran, Hoai Nam [Chalmers University of Technology, Dept. of Applied Physics, Div. of Nuclear Engineering, SE-412 96 Gothenburg (Sweden); Sembiring, Tagor Malem [National Nuclear Energy Agency (BATAN), Center for Reactor Technology and Nuclear Safety, Kawasan Puspiptek, Serpong, Tangerang Selatan, Banten (Indonesia); Arbie, Bakri [PT MOTAB Technology, Kedoya Elok Plaza Blok DA 12, Jl. Panjang, Kebun Jeruk, Jakarta Barat (Indonesia)

    2014-09-30T23:59:59.000Z

    To partly solve the global and regional shortages of Mo-99 supply, a conceptual design of a nitrate-fuel-solution based homogeneous reactor dedicated for Mo-99/Tc-99m medical radioisotope production is proposed. The modified LEU Cintichem process for Mo-99 extraction which has been licensed and demonstrated commercially for decades by BATAN is taken into account as a key design consideration. The design characteristics and main parameters are identified and the advantageous aspects are shown by comparing with the BATAN's existing Mo-99 supply chain which uses a heterogeneous reactor (RSG GAS multipurpose reactor)

  3. Greenfield Alternative Study LEU-Mo Fuel Fabrication Facility

    SciTech Connect (OSTI)

    Washington Division of URS

    2008-07-01T23:59:59.000Z

    This report provides the initial “first look” of the design of the Greenfield Alternative of the Fuel Fabrication Capability (FFC); a facility to be built at a Greenfield DOE National Laboratory site. The FFC is designed to fabricate LEU-Mo monolithic fuel for the 5 US High Performance Research Reactors (HPRRs). This report provides a pre-conceptual design of the site, facility, process and equipment systems of the FFC; along with a preliminary hazards evaluation, risk assessment as well as the ROM cost and schedule estimate.

  4. Phase transitions in the adsorption system Li/Mo(112)

    E-Print Network [OSTI]

    Fedorus, A.; Kolthoff, D.; Koval, V.; Lyuksyutov, Igor F.; Naumovets, AG; Pfnur, H.

    2000-01-01T23:59:59.000Z

    limit can be quasi-one-dimensional. Such model systems are formed upon submonolayer adsorption on surfaces with strongly an- PRB 620163-1829/2000/62~4!/2852~10!/$15.00 n system Li?Mo?112? ,1,3 A. G. Naumovets,1 and H. Pfnu?r2,* , Prospect Nauki 46... W/Re thermocouple and was con- trolled by a computerized feedback circuit with a resolution of 0.01 K. The source of lithium was constructed and outgassed as PRB 62 PHASE TRANSITIONS IN TH described in Ref. 6. The LEED patterns have been taken...

  5. Recovery of Mo/Si multilayer coated optical substrates

    DOE Patents [OSTI]

    Baker, Sherry L. (Pleasanton, CA); Vernon, Stephen P. (Pleasanton, CA); Stearns, Daniel G. (Los Altos, CA)

    1997-12-16T23:59:59.000Z

    Mo/Si multilayers are removed from superpolished ZERODUR and fused silica substrates with a dry etching process that, under suitable processing conditions, produces negligible change in either the substrate surface figure or surface roughness. The two step dry etching process removes SiO.sub.2 overlayer with a fluroine-containing gas and then moves molybdenum and silicon multilayers with a chlorine-containing gas. Full recovery of the initial normal incidence extreme ultra-violet (EUV) reflectance response has been demonstrated on reprocessed substrates.

  6. Recovery of Mo/Si multilayer coated optical substrates

    DOE Patents [OSTI]

    Baker, S.L.; Vernon, S.P.; Stearns, D.G.

    1997-12-16T23:59:59.000Z

    Mo/Si multilayers are removed from superpolished ZERODUR and fused silica substrates with a dry etching process that, under suitable processing conditions, produces negligible change in either the substrate surface figure or surface roughness. The two step dry etching process removes SiO{sub 2} overlayer with a fluroine-containing gas and then moves molybdenum and silicon multilayers with a chlorine-containing gas. Full recovery of the initial normal incidence extreme ultra-violet (EUV) reflectance response has been demonstrated on reprocessed substrates. 5 figs.

  7. DOE - Office of Legacy Management -- Petrolite Corp - MO 08

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA group currentBradleyTableSelling Corp - CTOregonPetrolite Corp - MO 08 FUSRAP

  8. Region 2007 2008 2009 2010 2011 2012 New England 183 140 138 140 127 136 -26%

    E-Print Network [OSTI]

    Fernandez, Eduardo

    17% Plains 45 48 50 60 53 59 31% Rocky Mountains 18 18 27 21 21 19 6% Southwest 56 61 61 57 64 83 48 Region Florida Atlantic University CO TX NMAZ UT NV CA OR WA WY ND SD NE KS OK MN WI MI IA MO IL AR AL AK New England Great Lakes Plains Rocky Mountains Far West Florida South west #12;

  9. Multiphoton Double Ionization of Ar and Ne Close to Threshold

    SciTech Connect (OSTI)

    Liu Yunquan [Max-Planck-Institut fuer Kernphysik, D-69117 Heidelberg (Germany); Department of Physics and State Key Laboratory for Mesoscopic Physics, Peking University, Beijing 100871 (China); Ye Difa; Liu Jie [Center for Applied Physics and Technology, Peking University, 100084 Beijing (China); Institute of Applied Physics and Computational Mathematics, 100088 Beijing (China); Rudenko, A. [Max-Planck-Institut fuer Kernphysik, D-69117 Heidelberg (Germany); Max-Planck Advanced Study Group at CFEL, 22607 Hamburg (Germany); Tschuch, S.; Duerr, M.; Moshammer, R.; Ullrich, J. [Max-Planck-Institut fuer Kernphysik, D-69117 Heidelberg (Germany); Siegel, M.; Morgner, U. [Leibniz Universitaet Hannover, Welfengarten 1, D-30167 Hannover (Germany); Gong Qihuang [Department of Physics and State Key Laboratory for Mesoscopic Physics, Peking University, Beijing 100871 (China)

    2010-04-30T23:59:59.000Z

    In kinematically complete studies we explore double ionization (DI) of Ne and Ar in the threshold regime (I>3x10{sup 13} W/cm{sup 2}) for 800 nm, 45 fs pulses. The basic differences are found in the two-electron momentum distributions - 'correlation' (CO) for Ne and 'anticorrelation' (ACO) for Ar - that can be partially explained theoretically within a 3D classical model including tunneling. Transverse electron momentum spectra provide insight into 'Coulomb focusing' and point to correlated nonclassical dynamics. Finally, DI threshold intensities, CO as well as ACO regimes are predicted for both targets.

  10. Identification of single nucleotides in MoS2 nanopores

    E-Print Network [OSTI]

    Jiandong Feng; Ke Liu; Roman D. Bulushev; Sergey Khlybov; Dumitru Dumcenco; Andras Kis; Aleksandra Radenovic

    2015-05-07T23:59:59.000Z

    Ultrathin membranes have drawn much attention due to their unprecedented spatial resolution for DNA nanopore sequencing. However, the high translocation velocity (3000-50000 nt/ms) of DNA molecules moving across such membranes limits their usability. To this end, we have introduced a viscosity gradient system based on room-temperature ionic liquids (RTILs) to control the dynamics of DNA translocation through a nanometer-size pore fabricated in an atomically thin MoS2 membrane. This allows us for the first time to statistically identify all four types of nucleotides with solid state nanopores. Nucleotides are identified according to the current signatures recorded during their transient residence in the narrow orifice of the atomically thin MoS2 nanopore. In this novel architecture that exploits high viscosity of RTIL, we demonstrate single-nucleotide translocation velocity that is an optimal speed (1-50 nt/ms) for DNA sequencing, while keeping the signal to noise ratio (SNR) higher than 10. Our findings pave the way for future low-cost and rapid DNA sequencing using solid-state nanopores.

  11. Characterization of U-Mo Foils for AFIP-7

    SciTech Connect (OSTI)

    Edwards, Danny J.; Ermi, Ruby M.; Schemer-Kohrn, Alan L.; Overman, Nicole R.; Henager, Charles H.; Burkes, Douglas; Senor, David J.

    2012-11-07T23:59:59.000Z

    Twelve AFIP in-process foil samples, fabricated by either Y-12 or LANL, were shipped from LANL to PNNL for potential characterization using optical and scanning electron microscopy techniques. Of these twelve, nine different conditions were examined to one degree or another using both techniques. For this report a complete description of the results are provided for one archive foil from each source of material, and one unirradiated piece of a foil of each source that was irradiated in the Advanced Test Reactor. Additional data from two other LANL conditions are summarized in very brief form in an appendix. The characterization revealed that all four characterized conditions contained a cold worked microstructure to different degrees. The Y-12 foils exhibited a higher degree of cold working compared to the LANL foils, as evidenced by the highly elongated and obscure U-Mo grain structure present in each foil. The longitudinal orientations for both of the Y-12 foils possesses a highly laminar appearance with such a distorted grain structure that it was very difficult to even offer a range of grain sizes. The U-Mo grain structure of the LANL foils, by comparison, consisted of a more easily discernible grain structure with a mix of equiaxed and elongated grains. Both materials have an inhomogenous grain structure in that all of the characterized foils possess abnormally coarse grains.

  12. Supercapacitor behavior of ?-MnMoO{sub 4} nanorods on different electrolytes

    SciTech Connect (OSTI)

    Purushothaman, K.K., E-mail: purushoth_gri@yahoo.co.in [Department of Physics, TRP Engineering College (SRM Group), Irungalur, Trichy, Tamilnadu (India); Cuba, M. [Department of Physics, Gandhigram Rural Institute – Deemed University, Gandhigram, Tamilnadu (India)] [Department of Physics, Gandhigram Rural Institute – Deemed University, Gandhigram, Tamilnadu (India); Muralidharan, G., E-mail: muralg@rediffmail.com [Department of Physics, Gandhigram Rural Institute – Deemed University, Gandhigram, Tamilnadu (India)

    2012-11-15T23:59:59.000Z

    Graphical abstract: SEM image of ?-MnMoO{sub 4} nanorods on FTO substrate. Highlights: ? Synthesis of ?-MnMoO{sub 4} nanorods by spin coating method. ? First study on the effect of electrolyte on the pseudocapacitance behavior. ? ?-MnMoO{sub 4} nanorods exhibit maximum specific capacitance of 998 F/g. ? At higher scan rates p-TSA electrolyte exhibits superior capacitive behavior. -- Abstract: ?-MnMoO{sub 4} nanorods were prepared on conducting glass substrate via sol–gel spin coating method at the optimum doping level. The effect of electrolyte on the pseudocapacitance behavior of the ?-MnMoO{sub 4} nanorods was studied using para toluene sulfonic acid (p-TSA), sulfuric acid (H{sub 2}SO{sub 4}) and hydrochloric acid (HCl) as electrolytes. X-ray diffraction analysis reveals the formation of ?-MnMoO{sub 4} in monoclinic phase. FTIR spectra contain vibrational bands associated with Mo=O, M–O and Mo–O–Mo bonds. SEM image reveals the formation of nanorods. Supercapacitor behavior has been studied using cyclic voltammetry (CV) analysis. ?-MnMoO{sub 4} nanorods exhibit maximum specific capacitance of 998 F/g at a scan rate of 5 mV/s in H{sub 2}SO{sub 4} electrolyte while a specific capacitance of 784 F/g and 530 F/g have been obtained using p-TSA and HCl electrolytes, respectively. At higher scan rates p-TSA electrolyte exhibits superior capacitive behavior than H{sub 2}SO{sub 4}.

  13. Smartphone-Mediated Tourist Experiences: Understanding the Influence of Augmented Reality (AR) Applications in Tourism

    E-Print Network [OSTI]

    Anuar, Faiz Izwan

    2013-04-25T23:59:59.000Z

    The synergy of smartphone, mobile applications (apps) and Augmented Reality (AR) technology has the potential to mediate tourism experiences to great extents. The advent of AR apps on smartphones provides a dynamic solution for tourists by helping...

  14. Thermal History of the Felsite Unit, Geysers Geothermal Field, From Thermal Modeling of 40Ar/39Ar Incremental Heating Data

    SciTech Connect (OSTI)

    T. M. Harrison (U of California); G. B. Dalrymple (Oregon State U); J. B. Hulen (U of Utah); M. A. Lanphere; M. Grove; O. M. Lovera

    1999-08-19T23:59:59.000Z

    An Ar-40/Ar-39 and U-Pb study was performed of the Geysers plutonic complex of the Geysers Geothermal Field in California. Sixty-nine ion microprobe spot analyses of zircons from four granite samples from the plutonic complex that underlies the Geysers geothermal field yielded Pb-207/Pb-206 vs. U-238/Pb-206 concordia ages ranging from 1.13 {+-} 0.04 Ma to 1.25 {+-} 0.04 Ma. The U-Pb ages coincide closely with Ar-40/Ar-39 age spectrum plateau and ''terminal'' ages from coexisting K-feldspars and with the eruption ages of overlying volcanic rocks. The data indicate that the granite crystallized at 1.18 Ma and had cooled below 350 C by {approximately}0.9-1.0 Ma. Interpretation of the feldspar Ar-40/Ar-39 age data using multi-diffusion domain theory indicates that post-emplacement rapid cooling was succeeded either by slower cooling from 350-300 C between 1.0 and 0.4 Ma or transitory reheating to 300-350 C at about 0.4-0.6 Ma. Heat flow calculations constrained with K-feldspar thermal histories and the pre sent elevated regional heal flow anomaly demonstrate that appreciable heat input from sources external to the known Geysers plutonic complex is required to maintain the geothermal system. This requirement is satisfied by either a large, underlying, convecting magma chamber (now solidified) emplaced at 1.2 Ma or episodic intrusion of smaller bodies from 1.2-0.6 Ma.

  15. Training Session: Euless, TX

    Broader source: Energy.gov [DOE]

    This 3.5-hour training provides builders with a comprehensive review of zero energy-ready home construction including the business case, detailed specifications, and opportunities to be recognized...

  16. ~tx410.ptx

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTownDells,1Stocksa. Appliances by Climate6,1996 http://www.eia.doe.govEffects

  17. ~tx421.ptx

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTownDells,1Stocksa. Appliances by Climate6,1996 http://www.eia.doe.govEffects

  18. D&TX

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA group currentBradleyTableSelling Corp -KWatertowni5W 95.5x-L* d!Qwner*. ( ARGONNE

  19. Fe3O4-LiMo3Se3 Nanoparticle Clusters as Superparamagnetic Nanocompasses

    E-Print Network [OSTI]

    Osterloh, Frank

    -iodopropionic acid treated LiMo3Se3 nanowire bundles with oleic acid-stabilized Fe3O4 nanoparticles of 2.8, 5Fe3O4-LiMo3Se3 Nanoparticle Clusters as Superparamagnetic Nanocompasses Frank E. Osterloh,*, Hiroki A scaleable chemical approach to functional nanoscale analogues of the magnetic compasses in magnetotactic

  20. Hole Selective MoOx Contact for Silicon Solar Cells Corsin Battaglia,,,

    E-Print Network [OSTI]

    Javey, Ali

    Hole Selective MoOx Contact for Silicon Solar Cells Corsin Battaglia,,, Xingtian Yin,,,§, Maxwell Laboratory, Xi'an Jiaotong University, Xi'an, 710049 Shaanxi, People's Republic of China Joint Center/silicon solar cell with a power conversion efficiency of 14.3%. While MoOx is commonly considered

  1. MoIAC Pre-Audit Form Ways to submit this form

    E-Print Network [OSTI]

    Noble, James S.

    information: #12;MoIAC Pre-Audit Form Major Energy Consuming Equipment: Please provide informationMoIAC Pre-Audit Form Ways to submit this form: 1. Fill up the form and fax it to 573-882-2693 Attn: Dr. Bin Wu 2. Print and return this form by mail to: Dr. Bin Wu University of Missouri

  2. Adsorption studies of Mo and V onto ferrihydrite *, L. G. BENNING

    E-Print Network [OSTI]

    Benning, Liane G.

    Adsorption studies of Mo and V onto ferrihydrite L. BRINZA 1, *, L. G. BENNING 1 AND P. J. STATHAM-sorbate experiments, 100% adsorption was observed at pH values below 6 and 8, respectively. Above the point of zero charge (PZC = 7.97) of FHY, the adsorption efficiency for Mo dropped dramatically (20% at pH 8) while V

  3. Stability of Graphene doping with MoO_3 and I_2

    E-Print Network [OSTI]

    D’Arsié, Lorenzo; Esconjauregui, Santiago; Weatherup, Robert; Guo, Yuzheng; Bhardwaj, Sunil; Centeno, Alba; Zurutuza, Amaia; Cepek, Cinzia; Robertson, John

    2014-09-08T23:59:59.000Z

    We dope graphene by evaporation of MoO_3 or by solution-deposition of I_2 and assess the doping stability for its use as transparent electrodes. Electrical measurements show that both dopants increase the graphene sheet conductivity and find that Mo...

  4. Student Financial Aid 11 Jesse Hall University of Missouri Columbia Columbia, MO 65211-1600

    E-Print Network [OSTI]

    Taylor, Jerry

    Student Financial Aid 11 Jesse Hall University of Missouri ­ Columbia Columbia, MO 65211-1600 PHONE;Student Financial Aid 11 Jesse Hall University of Missouri ­ Columbia Columbia, MO 65211-1600 PHONE (573 ________________________________________________________________________________________________________________________ Name of Host Institution (College or University you will be attending or taking additional classes

  5. Ligand Conjugation of Chemically Exfoliated MoS2 Stanley S. Chou,+

    E-Print Network [OSTI]

    Huang, Jiaxing

    Ligand Conjugation of Chemically Exfoliated MoS2 Stanley S. Chou,+ Mrinmoy De,+ Jaemyung Kim,+ Segi and chemical properties. Here, we demonstrate ligand conjugation of chemically exfoliated MoS2 using thiol-nitrilotriacetic acid chelation.13 However, colloidal sur- face modification of water dispersible, chemically exfoliated

  6. Characterization of Single-Walled Carbon Nanotubes (SWNTs) Produced by CO Disproportionation on Co-Mo

    E-Print Network [OSTI]

    Resasco, Daniel

    Characterization of Single-Walled Carbon Nanotubes (SWNTs) Produced by CO Disproportionation on Co Received November 15, 2001. Revised Manuscript Received February 6, 2002 The disproportionation of CO over Co-Mo/SiO2 catalysts with low Co/Mo ratios results in a high selectivity to single-walled carbon

  7. Corrosion Behavior of Solution-Annealed CoCrMo Medical Implant

    E-Print Network [OSTI]

    Shull, Kenneth R.

    ! ! ! Corrosion Behavior of Solution- Annealed CoCrMo Medical Implant Alloys Pooja Panigrahi University June 6, 2011 #12;! ! ""! Corrosion Behavior of Solution-Annealed CoCrMo Medical Implant Alloys and Applied Sciences Northwestern University June 6, 2011 Abstract Corrosion behavior of solution annealed

  8. Double beta decays and solar neutrinos with 100 MOON(Mo Observatory Of Neutrinos)

    E-Print Network [OSTI]

    Washington at Seattle, University of

    nuclear laboratory for spectroscopic studies of neutrinos Neutrinos are key particles for new frontiers) are sensitive and realistic experiments for studying the Majorana nature of the neutrino and the absolute massDouble beta decays and solar neutrinos with 100 Mo ­MOON(Mo Observatory Of Neutrinos)­ May 24, 2005

  9. Posting type Advisory Subject Shifts in Mo-anode XRF element calibration factors

    E-Print Network [OSTI]

    Fischer, Emily V.

    Posting type Advisory Subject Shifts in Mo-anode XRF element calibration factors Module/Species A@crocker.ucdavis.edu Supporting information A molybdenum-anode XRF instrument is used to analyze the heavier elements (Ni, Cu, Zn with lighter deposits were acquired and used in the Mo-anode XRF system. The new calibration foils resulted

  10. The arXiv: 14 years of open access scientific communication Simeon Warner

    E-Print Network [OSTI]

    Warner, Simeon

    /09/14 20:22:09 Abstract The arXiv was started in 1991 as a way for high-energy physicists to share publishing. Lessons learned from this development include the importance of community and critical mass how journal publishers have reacted to the arXiv, and ask what the arXiv reveals about the established

  11. Le magn)sme ar)ficiel pour les gaz d'atomes froids Jean Dalibard

    E-Print Network [OSTI]

    Dalibard, Jean

    Le magné)sme ar)ficiel pour les gaz d'atomes froids Jean Dalibard Année 2013-14 Chaire Atomes et rayonnement Magné8sme ar8ficiel pour un atome isolé poten8el vecteur et la simula8on du magné8sme orbital A(r) V

  12. arXiv:physics/001003915Oct2000 Maximally Informative Statistics

    E-Print Network [OSTI]

    George, Edward I.

    arXiv:physics/001003915Oct2000 Maximally Informative Statistics Maximally Informative Statistics: egeorge@mail.utexas.edu Revision history: April 1996. Presented Bayesian Statistics 6, Valencia, 1998 of sufficiency, relevance, and representation. Maximally informative statistics are shown to minimize a Kullback

  13. ARS Agricultural Research Service (USDA) BIA Bureau of Indian Affairs

    E-Print Network [OSTI]

    ACRONYMS ARS Agricultural Research Service (USDA) BIA Bureau of Indian Affairs BLM Bureau of Land Wetlands Inventory ODA Oregon Department of Agriculture ODEQ Oregon Department of Environmental Quality ODF Department of Agriculture USDI United States Department of the Interior USFS United States Forest Service

  14. Advanced Robotics 23 (2009) 13271358 www.brill.nl/ar

    E-Print Network [OSTI]

    Tachi, Susumu

    2009-01-01T23:59:59.000Z

    Advanced Robotics 23 (2009) 1327­1358 www.brill.nl/ar Full paper iSoRA: Humanoid Robot Arm on the development and control of the humanoid robot arm iSoRA, intended for operation in a dynamic unstructured that the proposed approach not only provides safe interaction of the robot arm with a person, but also improves

  15. Auger transition rates for Ar-like ions

    SciTech Connect (OSTI)

    Chung, Sang-Young [Physics Department, POSTECH, San 31 Hyojadong, Nam Ku, Pohang, Kyungbuk 790-784 (Korea, Republic of); Kagawa, Takashi [Department of Physics, Nara Women's University, Nara 630-8506 (Japan); Moribayashi, Kengo [Japan Atomic Energy Agency, 8-1, Umemidai, Kizu-cho, Kyoto 619-0215 (Japan); Kim, Dong Eon [Physics Department, POSTECH, San 31 Hyojadong, Nam Ku, Pohang, Kyungbuk 790-784 (Korea, Republic of)], E-mail: kimd@postech.ac.kr

    2009-03-15T23:59:59.000Z

    The Auger transition rates for Ar-like ions have been calculated by the relativistic configuration interaction code and flexible atomic code. The calculations have been carried out for the atomic numbers from 18 to 54, that is, for argon to xenon. The calculated data for argon is shown to be in a good agreement with experimental data and other calculated data.

  16. DESY 07176 arXiv:0710.2602v1

    E-Print Network [OSTI]

    ########### DESY 07­176 arXiv:0710.2602v1 [hep­ex] 13 Oct 2007 Prospects to Measure the Higgs Boson - Germany The process e + e ! ZH allows to measure the Higgs boson in the recoil mass spectrum against the Z boson without any assumptions on the Higgs boson decay. We performed a full simulation

  17. Photo-oxidation method using MoS2 nanocluster materials

    DOE Patents [OSTI]

    Wilcoxon, Jess P. (Albuquerque, NM)

    2001-01-01T23:59:59.000Z

    A method of photo-oxidizing a hydrocarbon compound is provided by dispersing MoS.sub.2 nanoclusters in a solvent containing a hydrocarbon compound contaminant to form a stable solution mixture and irradiating the mixture to photo-oxide the hydrocarbon compound. Hydrocarbon compounds of interest include aromatic hydrocarbon and chlorinated hydrocarbons. MoS.sub.2 nanoclusters with an average diameter less than approximately 10 nanometers are shown to be effective in decomposing potentially toxic aromatic and chlorinated hydrocarbons, such as phenol, pentachlorophenol, chlorinated biphenols, and chloroform, into relatively non-toxic compounds. The irradiation can occur by exposing the MoS.sub.2 nanoclusters and hydrocarbon compound mixture with visible light. The MoS.sub.2 nanoclusters can be introduced to the toxic hydrocarbons as either a MoS.sub.2 solution or deposited on a support material.

  18. Phase transformation of ZnMoO{sub 4} by localized thermal spike

    SciTech Connect (OSTI)

    Agarwal, D. C.; Avasthi, D. K.; Kabiraj, D. [Inter-University Accelerator Center, Aruna Asaf Ali Marg, New Delhi 110067 (India); Varma, S. [Institute of Physics, Sachivalaya Marg, Bhubaneswar 751005 (India); Kremer, Felipe; Ridgway, M. C. [Australian National University, Canberra ACT 0200 (Australia)

    2014-04-28T23:59:59.000Z

    We show that ZnMoO{sub 4} remains in stable phase under thermal annealing up to 1000?°C, whereas it decomposes to ZnO and MoO{sub 3} under transient thermal spike induced by 100?MeV Ag irradiation. The transformation is evidenced by X-ray diffraction (XRD), Raman spectroscopy, and X-ray photoelectron spectroscopy (XPS). Thin films of ZnMoO{sub 4} were synthesized by thermal evaporation and subsequent annealing in oxygen ambient at 600?°C for 4?h. XRD results show that as the irradiation fluence increases, the peak related to ZnMoO{sub 4} decreases gradually and eventually disappear, whereas peaks related to ZnO grow steadily up to fluence of 3?×?10{sup 12} ions/cm{sup 2} and thereafter remain stable till highest fluence. This indicates that polycrystalline ZnMoO{sub 4} film has transformed to polycrystalline ZnO thin film. The Raman lines related to ZnMoO{sub 4} are observed to have disappeared with increasing irradiation fluence. XPS results show modification in bonding and depletion of Mo from near surface region after the ion irradiation. Cross-sectional transmission electron microscopy result shows the formation of ion track of diameter 12–16?nm. These results demonstrate that ion beam methods provide the means to control phase splitting of ZnMoO{sub 4} to ZnO and MoO{sub 3} within nanometric dimension along the ion track. The observation of phase splitting and Mo loss are explained in the framework of ion beam induced thermal spike formalism.

  19. Water and Methanol Adsorption on MgO(100)/Mo(100) Studied by Electron Spectroscopies and Thermal Programmed Desorption

    E-Print Network [OSTI]

    Goodman, Wayne

    Water and Methanol Adsorption on MgO(100)/Mo(100) Studied by Electron Spectroscopies and Thermal, 2000 The adsorption of methanol (CH3OH) and water (D2O) on the MgO(100)/Mo(100) surface at 100 K has covered MgO(100)/Mo(100) surface. On the other hand, the formation of a methanol multilayer desorption

  20. Influence of Co/Mo Ratio on Synthesis of Single-Walled Carbon Nanotubes from Carbon Monoxide

    E-Print Network [OSTI]

    Maruyama, Shigeo

    Influence of Co/Mo Ratio on Synthesis of Single-Walled Carbon Nanotubes from Carbon Monoxide, Bunkyo-ku, Tokyo 113-8656 Co and Mo are often used as catalysts for the catalytic chemical vapor in synthesizing random, vertical and parallel aligned SWNTs on Co and Mo dip-coated quartz substrates from carbon

  1. Characterization of Vadose Zone Sediments Below the TX Tank Farm: Boreholes C3830, C3831, C3832 and RCRA Borehole 299-W10-27

    SciTech Connect (OSTI)

    Serne, R. Jeffrey; Bjornstad, Bruce N.; Horton, Duane G.; Lanigan, David C.; Lindenmeier, Clark W.; Lindberg, Michael J.; Clayton, Ray E.; Legore, Virginia L.; Orr, Robert D.; Kutnyakov, Igor V.; Baum, Steven R.; Geiszler, Keith N.; Valenta, Michelle M.; Vickerman, Tanya S.

    2008-09-11T23:59:59.000Z

    This report was revised in September 2008 to remove acid-extractable sodium data from Tables 4.8, 4.28,4.43, and 4.59. The sodium data was removed due to potential contamination introduced during the acid extraction process. The rest of the text remains unchanged from the original report issued in April 2004. The overall goal of the Tank Farm Vadose Zone Project, led by CH2M HILL Hanford Group, Inc., is to define risks from past and future single-shell tank farm activities at Hanford. To meet this goal, CH2M HILL Hanford Group, Inc. tasked scientists from Pacific Northwest National Laboratory to perform detailed analyses on vadose zone sediments from within Waste Management Area (WMA) T-TX-TY. This report is the first of two reports written to present the results of these analyses. Specifically, this report contains all the geologic, geochemical, and selected physical characterization data collected on vadose zone sediment recovered from boreholes C3830, C3831, and C3832 in the TX Tank Farm, and from borehole 299-W-10-27 installed northeast of the TY Tank Farm.

  2. Theoretical study of the interaction of Fe, Fe/sup +/, and FeCO with Ar

    SciTech Connect (OSTI)

    Braga, M.; Almeida, A.L.; Taft, C.A.; Hammond, B.L.; Lester W.A. Jr.

    1988-10-15T23:59:59.000Z

    Ab initio Hartree--Fock calculations were performed on FeAr and FeAr/sup +/ in order to determine the interaction of both neutral and singly-ionized Fe atoms trapped in Ar, and on ArFeCO and FeCOAr in order to ascertain the effect of an Ar matrix on the FeCO molecule. Quadrupole splittings and isomer shifts are computed using ab initio orbital populations and charge densities scaled by a relativistic factor. Good agreement between calculated and experimental hyperfine parameters is found in each case. The interaction energy for Fe/sup +/--Ar has been computed by ab initio Hartree--Fock and effective-core potential (ECP) methods. Both approaches yield a minimum between Fe/sup +/ and Ar at approximately 7.6 bohr.

  3. Nome Instituio Pas E-mail Natalia Gabriela Fracassi Instituto Nacional de Tecnologia Agropecuaria Argentina natfracassi@yahoo.com.ar

    E-Print Network [OSTI]

    Agropecuaria Argentina natfracassi@yahoo.com.ar Andre Alexander Held Commonwealth Scientific and Industrial

  4. Investigation of the optical properties of MoS{sub 2} thin films using spectroscopic ellipsometry

    SciTech Connect (OSTI)

    Yim, Chanyoung; O'Brien, Maria; Winters, Sinéad [School of Chemistry, Trinity College Dublin, Dublin 2 (Ireland); Centre for Research on Adaptive Nanostructures and Nanodevices (CRANN), Trinity College Dublin, Dublin 2 (Ireland); McEvoy, Niall [Centre for Research on Adaptive Nanostructures and Nanodevices (CRANN), Trinity College Dublin, Dublin 2 (Ireland); Mirza, Inam; Lunney, James G. [Centre for Research on Adaptive Nanostructures and Nanodevices (CRANN), Trinity College Dublin, Dublin 2 (Ireland); School of Physics, Trinity College Dublin, Dublin 2 (Ireland); Duesberg, Georg S., E-mail: duesberg@tcd.ie [School of Chemistry, Trinity College Dublin, Dublin 2 (Ireland); Centre for Research on Adaptive Nanostructures and Nanodevices (CRANN), Trinity College Dublin, Dublin 2 (Ireland); Advanced Materials and BioEngineering Research (AMBER) Centre, Trinity College Dublin, Dublin 2 (Ireland)

    2014-03-10T23:59:59.000Z

    Spectroscopic ellipsometry (SE) characterization of layered transition metal dichalcogenide (TMD) thin films grown by vapor phase sulfurization is reported. By developing an optical dispersion model, the extinction coefficient and refractive index, as well as the thickness of molybdenum disulfide (MoS{sub 2}) films, were extracted. In addition, the optical band gap was obtained from SE and showed a clear dependence on the MoS{sub 2} film thickness, with thinner films having a larger band gap energy. These results are consistent with theory and observations made on MoS{sub 2} flakes prepared by exfoliation, showing the viability of vapor phase derived TMDs for optical applications.

  5. Triple photoionization of Ne and Ar near threshold

    SciTech Connect (OSTI)

    Bluett, J.B.; Wehlitz, R. [Synchrotron Radiation Center, UW-Madison, Stoughton, Wisconsin 53589 (United States); Lukic, D. [Institute of Physics, 11001 Belgrade (Serbia and Montenegro)

    2004-04-01T23:59:59.000Z

    The triple-photoionization cross section of neon and argon near threshold has been investigated by ion time-of-flight spectrometry. We applied the Wannier power law to our data and confirmed the theoretical Wannier exponent in the cases of Ne and Ar. Our data also agree with previous findings regarding the Wannier exponent and its range of validity for Ne. However, the Wannier power law exhibits a much smaller range of validity of 2 eV for Ar compared to 5 eV for Ne. Also, in contrast to a previous experiment, we do not find a 'second' power law but a gradual decrease of the exponent above the range of validity of the Wannier power law.

  6. High damage-resistant Mo mirror for high-power TEA CO/sub 2/ laser systems

    SciTech Connect (OSTI)

    Ichikawa, Y.; Yoshida, K.; Tsunawaki, Y.; Yamanaka, M.; Yamanaka, T.; Yamanaka, C.; Okamoto, H.; Matsusue, N.; Kitajima, K.

    1987-09-01T23:59:59.000Z

    A high-purity molybdenum (Mo) mirror was developed by an electron-beam melting method (e.b.m. Mo mirror). For high-power TEA CO/sub 2/ laser, the e.b.m. Mo mirror has two to four times higher surface damage threshold than that of an Au-coated glass mirror and three times longer lifetime than that of a powder metallurgy Mo mirror (p.m. Mo mirror) when laser energy density lower than 60 J/cm/sup 2/ was irradiated with a 0.5-pps repetition rate. It was found that the difference between the e.b.m. Mo mirror and the p.m. Mo mirror at the laser-damage threshold was due to the five surface without voids and the small amount of impurities.

  7. Aboveground test of an advanced Li$_2$MoO$_4$ scintillating bolometer to search for neutrinoless double beta decay of $^{100}$Mo

    E-Print Network [OSTI]

    T. B. Bekker; N. Coron; F. A. Danevich; V. Ya. Degoda; A. Giuliani; V. D. Grigorieva; N. V. Ivannikova; M. Mancuso; P. de Marcillac; I. M. Moroz; C. Nones; E. Olivieri; G. Pessina; D. V. Poda; V. N. Shlegel; V. I. Tretyak; M. Velazquez

    2014-12-17T23:59:59.000Z

    Large lithium molybdate (Li$_2$MoO$_4$) crystal boules were produced by using the low thermal gradient Czochralski growth technique from deeply purified molybdenum. A small sample from one of the boules was preliminary characterized in terms of X-ray-induced and thermally-excited luminescence. A large cylindrical crystalline element (with a size of $\\oslash 40\\times40$ mm) was used to fabricate a scintillating bolometer, which was operated aboveground at $\\sim 15$ mK by using a pulse-tube cryostat housing a high-power dilution refrigerator. The excellent detector performance in terms of energy resolution and $\\alpha$ background suppression along with preliminary positive indications on the radiopurity of this material show the potentiality of Li$_2$MoO$_4$ scintillating bolometers for low-counting experiment to search for neutrinoless double beta decay of $^{100}$Mo.

  8. Aboveground test of an advanced Li$_2$MoO$_4$ scintillating bolometer to search for neutrinoless double beta decay of $^{100}$Mo

    E-Print Network [OSTI]

    Bekker, T B; Danevich, F A; Degoda, V Ya; Giuliani, A; Grigorieva, V D; Ivannikova, N V; Mancuso, M; de Marcillac, P; Moroz, I M; Nones, C; Olivieri, E; Pessina, G; Poda, D V; Shlegel, V N; Tretyak, V I; Velazquez, M

    2014-01-01T23:59:59.000Z

    Large lithium molybdate (Li$_2$MoO$_4$) crystal boules were produced by using the low thermal gradient Czochralski growth technique from deeply purified molybdenum. A small sample from one of the boules was preliminary characterized in terms of X-ray-induced and thermally-excited luminescence. A large cylindrical crystalline element (with a size of $\\oslash 40\\times40$ mm) was used to fabricate a scintillating bolometer, which was operated aboveground at $\\sim 15$ mK by using a pulse-tube cryostat housing a high-power dilution refrigerator. The excellent detector performance in terms of energy resolution and $\\alpha$ background suppression along with preliminary positive indications on the radiopurity of this material show the potentiality of Li$_2$MoO$_4$ scintillating bolometers for low-counting experiment to search for neutrinoless double beta decay of $^{100}$Mo.

  9. The production of /sup 38/Ar and /sup 39/Ar by 14-MeV neutrons on /sup 39/K

    SciTech Connect (OSTI)

    Foland, K.A.; Borg, R.J.; Mustafa, M.G.

    1987-02-01T23:59:59.000Z

    The authors have determined the cross sections for the production of /sup 38/Ar and /sup 39/Ar from the (n,n'rho) and (n,rho) reactions by neutrons of -- 14 MeV incident on /sup 39/K. Three potassium-bearing specimens were irradiated with fluences of --10/sup 17/ neutrons, and the argon isotopes were measured by mass spectrometry. Previously reported measurements are in substantial disagreement with our results. Values from the three new measurements are consistent with each other and our computational modeling. Nevertheless, there remains an unexplained increase in the cross sections for both reactions as the neutron energy increases from --14.5 to 14.8 MeV.

  10. sup 40 Ar/ sup 39 Ar age calibration of the litho- and paleomagnetic stratigraphies of the Ngorora Formation, Kenya

    SciTech Connect (OSTI)

    Deino, A.; Drake, R. (Institute of Human Origins, Berkeley, CA (USA)); Tauxe, L. (Scripps Institute of Oceanography, La Jolla, CA (USA)); Monaghan, M. (Univ. of Chicago, IL (USA))

    1990-07-01T23:59:59.000Z

    Precise eruptive ages have been determined by the laser-fusion, single-crystal {sup 40}Ar/{sup 39}Ar method for juvenile volcanic feldspars from reworked and contaminated volcaniclastic rocks of the middle Miocene Ngorora Formation, Kenya Rift Valley. These ages range from 13.06 Ma at the base to 10.51 Ma toward the top of the type section near Kabarsero. Correlation of the local paleomagnetic stratigraphies with the geomagnetic reversal time scale yields magnetochronologic age estimates that are younger than the isotopic ages by an average of 0.18 Ma. Much of the discrepancy can be eliminated if an inferred change in sea-floor spreading rate occurred at 13 Ma or earlier, rather than at 10.42 Ma as previously suggested. Sedimentation rates at Kabarsero calculated from the {sup 40}Ar/{sup 39}Ar results decrease from initial values of {approximately}25 cm/1,000 yr to {approximately}5 cm/1,000 yr toward the top of the section. The initial rapid sedimentation rates characterize the first 0.1 to 0.3 m.y. following emplacement of the underlying, voluminous, basin-filling Tiim Phonolites, indicating that the Baringo Basin at this time may not have existed as a rift valley created by extensional tectonics, but instead may have been a subsidence feature formed in response to removal of large volumes of magma from the lithosphere. A premolar tentatively identified as Proconsul sp. indet. found in the Ngorora Formation near the village of Bartabwa has been dated at {approximately}12.42 Ma, representing perhaps the last known occurrence of this genus in the fossil record.

  11. Atomistic simulation of the electronic states of adatoms in monolayer MoS{sub 2}

    SciTech Connect (OSTI)

    Chang, Jiwon; Larentis, Stefano; Tutuc, Emanuel; Register, Leonard F.; Banerjee, Sanjay K. [Microelectronics Research Center, The University of Texas at Austin, Austin, Texas 78758 (United States)

    2014-04-07T23:59:59.000Z

    Using an ab initio density functional theory based electronic structure method, we study the effects of adatoms on the electronic properties of monolayer transition metal dichalcogenide Molybdenum-disulfide (MoS{sub 2}). We consider the 1st (Li, Na, K) and 7th (F, Cl, Br) column atoms and metals (Sc, Ti, Ta, Mo, Pd, Pt, Ag, Au). Three high symmetry sites for the adatom on the surface of monolayer MoS{sub 2} are examined as starting points to search for the most energetically stable configuration for each adatom-monolayer MoS{sub 2} system, as well as the type of associated bonding. For the most stable adatom positions, we characterize the emergence of adatom-induced electronic states including any dopant states.

  12. Monolayers of MoS{sub 2} as an oxidation protective nanocoating material

    SciTech Connect (OSTI)

    Sen, H. Sener [UNAM-National Nanotechnology Research Center, Bilkent University, Ankara 06800 (Turkey); Sahin, H.; Peeters, F. M. [Department of Physics, University of Antwerp, 2610 Antwerp (Belgium); Durgun, E., E-mail: durgun@unam.bilkent.edu.tr [UNAM-National Nanotechnology Research Center, Bilkent University, Ankara 06800 (Turkey); Institute of Materials Science and Nanotechnology, Bilkent University, Ankara 06800 (Turkey)

    2014-08-28T23:59:59.000Z

    First-principle calculations are employed to investigate the interaction of oxygen with ideal and defective MoS{sub 2} monolayers. Our calculations show that while oxygen atoms are strongly bound on top of sulfur atoms, the oxygen molecule only weakly interacts with the surface. The penetration of oxygen atoms and molecules through a defect-free MoS{sub 2} monolayer is prevented by a very high diffusion barrier indicating that MoS{sub 2} can serve as a protective layer for oxidation. The analysis is extended to WS{sub 2} and similar coating characteristics are obtained. Our calculations indicate that ideal and continuous MoS{sub 2} and WS{sub 2} monolayers can improve the oxidation and corrosion-resistance of the covered surface and can be considered as an efficient nanocoating material.

  13. Substrate interactions with suspended and supported monolayer MoS?: Angle-resolved photoemission spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jin, Wencan; Sadowski, Jerzy T.; Yeh, Po-Chun; Zaki, Nader; Zhang, Datong; Liou, Jonathan T.; Dadap, Jerry I.; Herman, Irving P.; Osgood, Jr., Richard M.; Sutter, Peter; et al

    2015-03-01T23:59:59.000Z

    We report the directly measured electronic structure of exfoliated monolayer molybdenum disulfide (MoS?) using micrometer-scale angle-resolved photoemission spectroscopy. Measurements of both suspended and supported monolayer MoS? elucidate the effects of interaction with a substrate. A suggested relaxation of the in-plane lattice constant is found for both suspended and supported monolayer MoS? crystals. For suspended MoS?, a careful investigation of the measured uppermost valence band gives an effective mass at ? and ? of 2.00m? and 0.43m?, respectively. We also measure an increase in the band linewidth from the midpoint of ?? to the vicinity of ? and briefly discuss itsmore »possible origin.« less

  14. Substrate interactions with suspended and supported monolayer MoS?: Angle-resolved photoemission spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jin, Wencan [Columbia Univ., New York, NY (United States); Sadowski, Jerzy T. [Brookhaven National Lab. (BNL), Upton, NY (United States); Yeh, Po-Chun [Columbia Univ., New York, NY (United States); Zaki, Nader [Columbia Univ., New York, NY (United States); Zhang, Datong [Columbia Univ., New York, NY (United States); Liou, Jonathan T. [Columbia Univ., New York, NY (United States); Dadap, Jerry I. [Columbia Univ., New York, NY (United States); Herman, Irving P. [Columbia Univ., New York, NY (United States); Osgood, Jr., Richard M. [Columbia Univ., New York, NY (United States); Sutter, Peter [Brookhaven National Lab. (BNL), Upton, NY (United States); Barinov, Alexey [Elettra Sincrotrone Trieste, Basovizza, Trieste (Italy); Yablonskikh, Mikhail [Elettra Sincrotrone Trieste, Basovizza, Trieste (Italy)

    2015-03-01T23:59:59.000Z

    We report the directly measured electronic structure of exfoliated monolayer molybdenum disulfide (MoS?) using micrometer-scale angle-resolved photoemission spectroscopy. Measurements of both suspended and supported monolayer MoS? elucidate the effects of interaction with a substrate. A suggested relaxation of the in-plane lattice constant is found for both suspended and supported monolayer MoS? crystals. For suspended MoS?, a careful investigation of the measured uppermost valence band gives an effective mass at ? and ? of 2.00m? and 0.43m?, respectively. We also measure an increase in the band linewidth from the midpoint of ?? to the vicinity of ? and briefly discuss its possible origin.

  15. Intrinsic Electronic Transport Properties of High-Quality Monolayer and Bilayer MoS[subscript 2

    E-Print Network [OSTI]

    Baugher, Britton W. H.

    We report electronic transport measurements of devices based on monolayers and bilayers of the transition-metal dichalcogenide MoS[subscript 2]. Through a combination of in situ vacuum annealing and electrostatic gating ...

  16. MO"BIUS ENERGIES FOR KNOTS AND LINKS, SURFACES AND SUBMANIFOLDS

    E-Print Network [OSTI]

    Kusner, Robert B.

    MO"BIUS ENERGIES FOR KNOTS AND LINKS, SURFACES AND SUBMANIFOLDS energies, especially those which are invariant under M"obius transforma- tions of space. We describe computer experiments with such energies, and discuss ways of extending these to energies

  17. Isothermal activation of Mo2O5 ZSM-5 precursors during

    E-Print Network [OSTI]

    Iglesia, Enrique

    Isothermal activation of Mo2O5 21 ­ZSM-5 precursors during methane reactions: effects of reaction to petrochemicals and liquid fuels and chemicals remains a formidable technological challenge.1 Exchanged cations

  18. AB INITIO Modeling of Thermomechanical Properties of Mo-Based Alloys for Fossil Energy Conversion

    SciTech Connect (OSTI)

    Ching, Wai-Yim

    2013-12-31T23:59:59.000Z

    In this final scientific/technical report covering the period of 3.5 years started on July 1, 2011, we report the accomplishments on the study of thermo-mechanical properties of Mo-based intermetallic compounds under NETL support. These include computational method development, physical properties investigation of Mo-based compounds and alloys. The main focus is on the mechanical and thermo mechanical properties at high temperature since these are the most crucial properties for their potential applications. In particular, recent development of applying ab initio molecular dynamic (AIMD) simulations to the T1 (Mo{sub 5}Si{sub 3}) and T2 (Mo{sub 5}SiB{sub 2}) phases are highlighted for alloy design in further improving their properties.

  19. Electronic structure and conductivity of nanocomposite metal (Au,Ag,Cu,Mo)-containing amorphous carbon films

    E-Print Network [OSTI]

    Endrino, Jose L.

    2010-01-01T23:59:59.000Z

    dual-cathode arc deposition (PDC-FCVA) source containingand metal cathodes [2]. The PDC-FCVA system in combinationCu,Mo) incorporation in a-C by PDC-FCVA. The modification of

  20. Combining sedimentological, trace metal (Mn, Mo) and molecular evidence for reconstructing past water-column

    E-Print Network [OSTI]

    Wehrli, Bernhard

    Combining sedimentological, trace metal (Mn, Mo) and molecular evidence for reconstructing past online 22 June 2013 Abstract Here, we present sedimentological, trace metal, and molecular evidence underscores the value of combining sedimentological, geochemical, and microbiological approaches

  1. Enhanced absorption of monolayer MoS{sub 2} with resonant back reflector

    SciTech Connect (OSTI)

    Liu, Jiang-Tao, E-mail: jtliu@semi.ac.cn; Liu, Nian-Hua [Nanoscale Science and Technology Laboratory, Institute for Advanced Study, Nanchang University, Nanchang 330031 (China); Department of Physics, Nanchang University, Nanchang 330031 (China); Wang, Tong-Biao [Department of Physics, Nanchang University, Nanchang 330031 (China); Li, Xiao-Jing [College of Physics and Energy, Fujian Normal University, Fuzhou 350007 (China)

    2014-05-21T23:59:59.000Z

    The optical absorption of monolayer MoS{sub 2} on top of one-dimensional photonic crystal (1DPC) or metal films with spacer layers is theoretically investigated by extracting the permittivity of monolayer MoS{sub 2} from existing experimental results [K. F. Mak et al., Phys. Rev. Lett. 105, 136805 (2010)]. The absorption of graphene with 1DPC across a broad spectral range is substantially enhanced because of the photonic localization at the optical micro-cavity on top of the 1DPC or metal films. The absorption of monolayer MoS{sub 2} can be tuned by varying either the distance between the monolayer MoS{sub 2} and the back reflector or the thickness of the cover layers.

  2. Role of Penning ionization in the enhancement of streamer channel conductivity and Ar(1s{sub 5}) production in a He-Ar plasma jet

    SciTech Connect (OSTI)

    Sands, Brian L. [UES, Inc., 4401 Dayton-Xenia Rd., Dayton, Ohio 45432 (United States); Huang, Shih K.; Speltz, Jared W.; Niekamp, Matthew A. [Department of Mechanical and Materials Engineering, Wright State University, 3640 Colonel Glenn Hwy., Dayton, Ohio 45435 (United States); Ganguly, Biswa N. [Air Force Research Laboratory, 1950 5th St. Wright Patterson Air Force Base, Ohio 45433 (United States)

    2013-04-21T23:59:59.000Z

    Plasma jet devices that use a helium gas flow mixed with a small percentage of argon have been shown to operate with a larger discharge current and enhanced production of the Ar(1s{sub 5}) metastable state, particularly in the discharge afterglow. In this experiment, time-resolved quantitative measurements of He(2{sup 3}S{sub 1}) and Ar(1s{sub 5}) metastable species were combined with current and spectrally resolved emission measurements to elucidate the role of Penning ionization in a helium plasma jet with a variable argon admixture. The plasma jet was enclosed in a glass chamber through which a flowing nitrogen background was maintained at 600 Torr. At 3%-5% Ar admixture, we observed a {approx}50% increase in the peak circuit current and streamer velocity relative to a pure helium plasma jet for the same applied voltage. The streamer initiation delay also decreased by {approx}20%. Penning ionization of ground-state argon was found to be the dominant quenching pathway for He(2{sup 3}S{sub 1}) up to 2% Ar and was directly correlated with a sharp increase in both the circuit current and afterglow production of Ar(1s{sub 5}) for Ar admixtures up to 1%, but not necessarily with the streamer velocity, which increased more gradually with Ar concentration. Ar(1s{sub 5}) was produced in the afterglow through recombination of Ar{sup +} and dissociative recombination of Ar{sub 2}{sup +} as the local mean electron energy decreased in the plasma channel behind the streamer head. The discharge current and argon metastable enhancement are contingent on the rapid production of He(2{sup 3}S{sub 1}) near the streamer head, >5 Multiplication-Sign 10{sup 12} cm{sup -3} in 30 ns under the conditions of this experiment.

  3. sup 40 Ar/ sup 39 Ar ages of six Apollo 15 impact melt rocks by laser step heating

    SciTech Connect (OSTI)

    Dalrymple, G.B. (Geological Survey, Menlo Park, CA (USA)); Ryder, G. (Lunar and Planetary Inst., Houston, TX (USA))

    1991-06-01T23:59:59.000Z

    The authors have obtained 15 high resolution (21-51 step) {sup 40}Ar/{sup 39}Ar age spectra on six Apollo 15 impact melt rocks of different compositions using a continuous laser system on submilligram subsamples and on single crystal plagioclase clasts. Four of the six samples gave reproducible age spectra with well-defined intermediate temperature plateaus over 48% or more of the {sup 39}AR released; the plateaus are interpreted as crystallization ages. Samples 15304,7,69, 15294,6,21, and 15314,26,156 gave virtually identical plateau ages whose weighted mean is 3,870 {plus minus} 6 Ma. These three melt rocks differ in composition and likely formed in three separate impact events. Sample 15356,9 gave replicate plateau ages that average 3,836 {plus minus} 12 Ma and date a fourth and younger impact event. The age spectra for samples 15308,9 and 15414,3,36 increase with increasing increment temperature and may have been formed in or affected by impacts at about 2,700 Ma and 3,870 Ma, respectively. So far there continues to be no convincing evidence in the lunar record for impact melts older than about 3.9 Ga.

  4. Diffusional Interactions between U-Mo and Zr at 650°C as a Function of Time

    SciTech Connect (OSTI)

    Y. Park; Y. H. Sohn; D. D. Keiser, Jr.

    2015-01-01T23:59:59.000Z

    Development of monolithic U-Mo alloy fuel (typically U-10wt.%Mo) for the Reduced Enrichment for Research and Test Reactors (RERTR) program requires a use of Zr diffusion barrier to eliminate the diffusional interaction between the fuel alloy and Al-alloy cladding. The application of Zr barrier to the U-Mo fuel requires co-rolling process that utilizes a soaking temperature of 650°C, which represents the highest temperature the fuel system is exposed to during both fuel manufacturing and reactor application. Therefore, in this study, development of phase constituents, microstructure and diffusion kinetics of U-10wt.%Mo and Zr was examined using solid-to-solid diffusion couples annealed at 650°C for 240, 480 and 720 hours. Diffusional interactions were analyzed by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Within the diffusion zone, a single-phase layer of ß-Zr was observed along with a discontinuous layer of Mo2Zr at the interface between the terminal ?-U(Mo) alloy and ß-Zr. In the vicinity of Mo2Zr phase, islands of ß-U and a-Zr phases were also found. In addition, accicular a-Zr phases were observed within the ?-U(Mo). Growth rate of this diffuaional interaction layer was determined to be 8.76 x 10-15 m2/sec, however with an assumption of certain incubation period. Consistency in these observation along with concentration profiles and diffusion paths are presented and discussed with respect to the diffusion couple that was furnace-cooled, annealed at 700°C in our previous study, and isothermal ternary phase diagram at 700°C.

  5. Characterization of Vadose Zone Sediments Below the TX Tank Farm: Probe Holes C3830, C3831, C3832 and 299-W10-27

    SciTech Connect (OSTI)

    Serne, R JEFFREY.; Bjornstad, Bruce N.; Horton, Duane G.; Lanigan, David C.; Lindenmeier, Clark W.; Lindberg, Michael J.; Clayton, Ray E.; LeGore, Virginia L.; Orr, Robert D.; Kutnyakov, Igor V.; Baum, Steven R.; Geiszler, Keith N.; Valenta, Michelle M.; Vickerman, Tanya S.

    2004-04-01T23:59:59.000Z

    Pacific Northwest National Laboratory performed detailed analyses on vadose zone sediments from within Waste Management Area T-TX-TY. This report contains all the geologic, geochemical, and selected physical characterization data collected on vadose zone sediment recovered from three probe holes (C3830, C3831, and C3832) in the TX Tank Farm, and from borehole 299-W-10-27. Sediments from borehole 299-W-10-27 are considered to be uncontaminated sediments that can be compared with contaminated sediments. This report also presents our interpretation of the sediment lithologies, the vertical extent of contamination, the migration potential of the contaminants, and the likely source of the contamination in the vadose zone and groundwater below the TX Tank Farm. Sediment from the probe holes was analyzed for: moisture, radionuclide and carbon contents;, one-to-one water extracts (soil pH, electrical conductivity, cation, trace metal, and anion data), and 8 M nitric acid extracts. Overall, our analyses showed that common ion exchange is a key mechanism that influences the distribution of contaminants within that portion of the vadose zone affected by tank liquor. We did not observe significant indications of caustic alteration of the sediment mineralogy or porosity, or significant zones of slightly elevated pH values in the probe holes. The sediments do show that sodium-, nitrate-, and sulfate-dominated fluids are present. The fluids are more dilute than tank fluids observed below tanks at the SX and BX Tank Farms. Three primary stratigraphic units were encountered in each probe hole: (1) backfill material, (2) the Hanford formation, and (3) the Cold Creek unit. Each of the probe holes contain thin fine-grained layers in the Hanford H2 stratigraphic unit that may impact the flow of leaked fluids and effect irregular and horizontal flow. The probe holes could not penetrate below the enriched calcium carbonate strata of the Cold Creek lower subunit; therefore, we did not identify the maximum vertical penetration of the tank related plumes. However, the more elevated portions of the electrical conductivity (EC) profile at probe hole C3830 currently resides at the bottom of a fine-grained thin lens in the Hanford H2 unit at 87 ft bgs. At C3831, we lack good sample coverage to ascertain whether the salt plume has significantly descended into the Cold Creek Unit. There is strong indication at probe hole C3832 that the saline plume has descended into the Cold Creek Unit. The profiles do collectively suggest that the deepest penetration of tank related fluids is found in probe hole C3832. The water potential data from 299-W10-27?s H2 unit, the unit where most of the contaminants reside in the TX probe holes, are consistent with a draining profile. Despite the evidence that elevated EC values may be present in all three probe holes to their depth of refusal, the concentrations of long-term risk drivers are not large. The inventories of potential contaminants of concern, nitrate, technetium-99, uranium, and chromium, are provided. In addition, in situ desorption Kd values for these contaminants are provided. For conservative modeling purposes, we recommend using Kd values of 0 mL/g for nitrate and technetium-99, a value of 1 mL/g for uranium, and 10 mL/g for chromium to represent the entire vadose zone profile from the bottoms of the tanks to the water table. These conservative Kd values along with the provided inventories in the vadose zone sediments obtained from the three probe holes can be used in long-term risk projections that rely on estimates of water recharge and vadose zone and aquifer transport calculations.

  6. MoS{sub 2} nanotube exfoliation as new synthesis pathway to molybdenum blue

    SciTech Connect (OSTI)

    Visic, B., E-mail: bojana.visic@ijs.si [Jozef Stefan Institute, Jamova cesta 39, SI-1000 Ljubljana (Slovenia); Gunde, M. Klanjsek [National Institute of Chemistry, Hajdrihova 19, SI-1000 Ljubljana (Slovenia)] [National Institute of Chemistry, Hajdrihova 19, SI-1000 Ljubljana (Slovenia); Kovac, J.; Iskra, I. [Jozef Stefan Institute, Jamova cesta 39, SI-1000 Ljubljana (Slovenia)] [Jozef Stefan Institute, Jamova cesta 39, SI-1000 Ljubljana (Slovenia); Jelenc, J.; Remskar, M. [Jozef Stefan Institute, Jamova cesta 39, SI-1000 Ljubljana (Slovenia) [Jozef Stefan Institute, Jamova cesta 39, SI-1000 Ljubljana (Slovenia); Centre of Excellence Namaste, Jamova cesta 39, SI-1000 Ljubljana (Slovenia)

    2013-02-15T23:59:59.000Z

    Graphical abstract: . Display Omitted Highlights: ? New synthesis approach to obtaining molybdenum blue via exfoliated MoS{sub 2} nanotubes. ? Material is prone to self assembly and is stable in high vacuum. ? Molecules are as small as 2 nm and their clusters are up to tens of nanometers. ? Change in absorption and oxidation states from the precursor MoS{sub 2}. -- Abstract: Molybdenum blue-type materials are usually obtained by partially reducing Mo{sup VI+} in acidic solutions, while in the presented method it is formed in ethanol solution of exfoliated MoS{sub 2} nanotubes, where the MoS{sub 2} flakes are the preferential location for their growth. Material was investigated by means of scanning electron and atomic force microscopy, showing the structure and self assembly, while also confirming that it is stable in high vacuum with molecules as small as 1.6 nm and the agglomerates of few tens of nanometres. The ultraviolet–visible and photoelectron spectrometry show the change in absorption properties and oxidation states from MoS{sub 2} structure to molybdenum blue, while the presence of sulphur suggests that this is a new type of molybdenum blue material.

  7. Effects of thermal treatment on the co-rolled U-Mo fuel foils

    SciTech Connect (OSTI)

    Dennis D. Keiser, Jr.; Tammy L. Trowbridge; Cynthia R. Breckenridge; Brady L. Mackowiak; Glenn A. Moore; Barry H. Rabin; Mitchell K. Meyer

    2014-11-01T23:59:59.000Z

    A monolithic fuel type is being developed to convert US high performance research and test reactors such as Advanced Test Reactor (ATR) at Idaho National Laboratory from highly enriched uranium (HEU) to low-enriched uranium (LEU). The interaction between the cladding and the U-Mo fuel meat during fuel fabrication and irradiation is known to have negative impacts on fuel performance, such as mechanical integrity and dimensional stability. In order to eliminate/minimize the direct interaction between cladding and fuel meat, a thin zirconium diffusion barrier was introduced between the cladding and U-Mo fuel meat through a co-rolling process. A complex interface between the zirconium and U-Mo was developed during the co-rolling process. A predictable interface between zirconium and U-Mo is critical to achieve good fuel performance since the interfaces can be the weakest link in the monolithic fuel system. A post co-rolling annealing treatment is expected to create a well-controlled interface between zirconium and U-Mo. A systematic study utilizing post co-rolling annealing treatment has been carried out. Based on microscopy results, the impacts of the annealing treatment on the interface between zirconium and U-Mo will be presented and an optima annealing treatment schedule will be suggested. The effects of the annealing treatment on the fuel performance will also be discussed.

  8. Photoluminescent BaMoO{sub 4} nanopowders prepared by complex polymerization method (CPM)

    SciTech Connect (OSTI)

    Azevedo Marques, Ana Paula de [Laboratorio de Analise Termica e Materiais, Departamento de Quimica, Universidade Federal do Rio Grande do Norte, 59072-970 Natal, RN (Brazil)]. E-mail: apamarques@liec.ufscar.br; Melo, Dulce M.A. de [Laboratorio de Analise Termica e Materiais, Departamento de Quimica, Universidade Federal do Rio Grande do Norte, 59072-970 Natal, RN (Brazil); Paskocimas, Carlos A. [Departamento de Engenharia Mecanica, Universidade Federal do Rio Grande do Norte, 59072-970 Natal, RN (Brazil); Pizani, Paulo S. [Laboratorio de Semicondutores, Departamento de Fisica, Universidade Federal de Sao Carlos, 13565-905 Sao Carlos, SP (Brazil); Joya, Miryam R. [Laboratorio de Semicondutores, Departamento de Fisica, Universidade Federal de Sao Carlos, 13565-905 Sao Carlos, SP (Brazil); Leite, Edson R. [Laboratorio Interdisciplinar de Eletroquimica e Ceramica, CMDMC, Departamento de Quimica, Universidade Federal de Sao Carlos 13565-905, Sao Carlos, SP (Brazil); Longo, Elson [CMDMC, LIEC, Instituto de Quimica, Universidade Estadual Paulista, 14801-907 Araraquara, SP (Brazil)

    2006-03-15T23:59:59.000Z

    The BaMoO{sub 4} nanopowders were prepared by the Complex Polymerization Method (CPM). The structure properties of the BaMoO{sub 4} powders were characterized by FTIR transmittance spectra, X-ray diffraction (XRD), Raman spectra, photoluminescence spectra (PL) and high-resolution scanning electron microscopy (HR-SEM). The XRD, FTIR and Raman data showed that BaMoO{sub 4} at 300 deg. C was disordered. At 400 deg. C and higher temperature, BaMoO{sub 4} crystalline scheelite-type phases could be identified, without the presence of additional phases, according to the XRD, FTIR and Raman data. The calculated average crystallite sizes, calculated by XRD, around 40 nm, showed the tendency to increase with the temperature. The crystallite sizes, obtained by HR-SEM, were around of 40-50 nm. The sample that presented the highest intensity of the red emission band was the one heat treated at 400 deg. C for 2 h, and the sample that displayed the highest intensity of the green emission band was the one heat treated at 700 deg. C for 2 h. The CPM was shown to be a low cost route for the production of BaMoO{sub 4} nanopowders, with the advantages of lower temperature, smaller time and reduced cost. The optical properties observed for BaMoO{sub 4} nanopowders suggested that this material is a highly promising candidate for photoluminescent applications.

  9. Synthesis and characterization of the ((CO)/sub 4/MoS/sub 2/MS/sub 2/)/sup 2 -/ and ((CO)/sub 4/MoS/sub 2/MS/sub 2/Mo(CO)/sub 4/)/sup 2 -/ ions (M = Mo, W): species containing group VI (6) metals in widely separated formal oxidation states

    SciTech Connect (OSTI)

    Rosenhein, L.D.; McDonald, J.W.

    1987-10-07T23:59:59.000Z

    Dinuclear and trinuclear sulfide-bridged complexes of the types (Et/sub 4/N)/sub 2/(MS/sub 4/(Mo(CO)/sub 4/)) and (Et/sub 4/N)/sub 2/(MS/sub 4/(Mo(CO)/sub 4/)/sub 2/) were prepared by the reaction of one or two equivalents of Mo(CO)/sub 4/(C/sub 7/H/sub 8/) (C/sub 7/H/sub 8/ = norbornadiene) with (Et/sub 4/N)/sub 2/(MS/sub 4/) (M = Mo, W) in methyl alcohol. Elemental analyses were consistent with the proposed formulae. Infrared spectra of all four compounds contain strong bands in the carbonyl region and low-energy bands characteristic of terminal and bridging M-S vibrations in linear, polynuclear, and sulfido-bridged species. Electrochemical experimental results support the hypothesis that the di- and trinuclear species contain both M(IV) (M = Mo, W) and Mo(0) oxidation states in the same complex. 33 references, 2 tables.

  10. Food and Drug Administration process validation activities to support 99Mo production at Sandia National Laboratories

    SciTech Connect (OSTI)

    McDonald, M.J.; Bourcier, S.C.; Talley, D.G.

    1997-07-01T23:59:59.000Z

    Prior to 1989 {sup 99}Mo was produced in the US by a single supplier, Cintichem Inc., Tuxedo, NY. Because of problems associated with operating its facility, in 1989 Cintichem elected to decommission the facility rather than incur the costs for repair. The demise of the {sup 99}Mo capability at Cintichem left the US totally reliant upon a single foreign source, Nordion International, located in Ottawa Canada. In 1992 the DOE purchased the Cintichem {sup 99}Mo Production Process and Drug Master File (DMF). In 1994 the DOE funded Sandia National Laboratories (SNL) to produce {sup 99}Mo. Although Cintichem produced {sup 99}Mo and {sup 99m}Tc generators for many years, there was no requirement for process validation which is now required by the Food and Drug Administration (FDA). In addition to the validation requirement, the requirements for current Good manufacturing Practices were codified into law. The purpose of this paper is to describe the process validation being conducted at SNL for the qualification of SNL as a supplier of {sup 99}Mo to US pharmaceutical companies.

  11. Mechanistic study of methanol synthesis from CO? and H? on a modified model Mo?S? cluster

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Cheng [Yangzhou Univ., Yangzhou, Jiangsu (China); Liu, Ping [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2015-02-06T23:59:59.000Z

    We report the methanol synthesis from CO? and H? on metal (M = K, Ti, Co, Rh, Ni, and Cu)-modified model Mo?S? catalyst using density functional theory (DFT). The results show that the catalytic behavior of a Mo?S? cluster is changed significantly due to the modifiers, via the electron transfer from M to Mo?S? and therefore the reduction of the Mo cation (ligand effect) and the direct participation of M in the reaction (ensemble effect) to promote some elementary steps. With the most positively charged modifier, the ligand effect in the case of K-Mo?S? is the most obvious among the systems studied; however it cannot compete with the ensemble effect, which plays a dominate role in determining activity via the electrostatic attraction in particular to stabilize the CHxOy species adsorbed at the Mo sites of Mo?S?. In comparison, the ligand effect is weaker and the ensemble effect is more important when the other modifiers are used. In addition, the modifiers also vary the optimal reaction pathway for methanol synthesis on Mo?S?, ranging from the reverse water-gas shift (RWGS) + CO hydrogenation as that of Mo?S? to the formate pathway. Finally, K is able to accelerate the methanol synthesis on Mo?S? the most; while the promotion by Rh is relatively small. Using the modifiers like Ti, Co, Ni, and Cu, the activity of Mo?S? is decreased instead. The relative stability between *HCOO and *HOCO is identified as a descriptor to capture the variation in mechanism and scales well with the estimated activity. Our study not only provides better understanding of the reaction mechanism and actives on the modified Mo?S?, but also predicts some possible candidates, which can be used a promoter to facilitate the CH?OH synthesis on Mo sulfides.

  12. Mechanistic study of methanol synthesis from CO? and H? on a modified model Mo?S? cluster

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Cheng; Liu, Ping

    2015-02-06T23:59:59.000Z

    We report the methanol synthesis from CO? and H? on metal (M = K, Ti, Co, Rh, Ni, and Cu)-modified model Mo?S? catalyst using density functional theory (DFT). The results show that the catalytic behavior of a Mo?S? cluster is changed significantly due to the modifiers, via the electron transfer from M to Mo?S? and therefore the reduction of the Mo cation (ligand effect) and the direct participation of M in the reaction (ensemble effect) to promote some elementary steps. With the most positively charged modifier, the ligand effect in the case of K-Mo?S? is the most obvious among themore »systems studied; however it cannot compete with the ensemble effect, which plays a dominate role in determining activity via the electrostatic attraction in particular to stabilize the CHxOy species adsorbed at the Mo sites of Mo?S?. In comparison, the ligand effect is weaker and the ensemble effect is more important when the other modifiers are used. In addition, the modifiers also vary the optimal reaction pathway for methanol synthesis on Mo?S?, ranging from the reverse water-gas shift (RWGS) + CO hydrogenation as that of Mo?S? to the formate pathway. Finally, K is able to accelerate the methanol synthesis on Mo?S? the most; while the promotion by Rh is relatively small. Using the modifiers like Ti, Co, Ni, and Cu, the activity of Mo?S? is decreased instead. The relative stability between *HCOO and *HOCO is identified as a descriptor to capture the variation in mechanism and scales well with the estimated activity. Our study not only provides better understanding of the reaction mechanism and actives on the modified Mo?S?, but also predicts some possible candidates, which can be used a promoter to facilitate the CH?OH synthesis on Mo sulfides.« less

  13. \\b{eta}-delayed three-proton decay of 31Ar

    E-Print Network [OSTI]

    Lis, A A; Dominik, W; Janas, Z; Pfützner, M; Pomorski, M; Acosta, L; Baraeva, S; Casarejos, E; Duénas-Díaz, J; Dunin, V; Espino, J M; Estrade, A; Farinon, F; Fomichev, A; Geissel, H; Gorshkov, A; Kami?ski, G; Kiselev, O; Knöbel, R; Krupko, S; Kuich, M; Litvinov, Yu A; Marquinez-Durán, G; Martel, I; Mukha, I; Nociforo, C; Ordúz, A K; Pietri, S; Prochazka, A; Sánchez-Benítez, A M; Simon, H; Sitar, B; Slepnev, R; Stanoiu, M; Strmen, P; Szarka, I; Takechi, M; Tanaka, Y; Weick, H; Winfield, J S

    2015-01-01T23:59:59.000Z

    The beta decay of 31Ar, produced by fragmentation of a 36Ar beam at 880 MeV/nucleon, was investigated. Identified ions of 31Ar were stopped in a gaseous time projection chamber with optical readout allowing to record decay events with emission of protons. In addition to \\b{eta}-delayed emission of one and two protons we have clearly observed the beta-delayed three-proton branch. The branching ratio for this channel in 31Ar is found to be 0.07(2)%.

  14. \\b{eta}-delayed three-proton decay of 31Ar

    E-Print Network [OSTI]

    A. A. Lis; C. Mazzocchi; W. Dominik; Z. Janas; M. Pfützner; M. Pomorski; L. Acosta; S. Baraeva; E. Casarejos; J. Duénas-Díaz; V. Dunin; J. M. Espino; A. Estrade; F. Farinon; A. Fomichev; H. Geissel; A. Gorshkov; G. Kami?ski; O. Kiselev; R. Knöbel; S. Krupko; M. Kuich; Yu. A. Litvinov; G. Marquinez-Durán; I. Martel; I. Mukha; C. Nociforo; A. K. Ordúz; S. Pietri; A. Prochazka; A. M. Sánchez-Benítez; H. Simon; B. Sitar; R. Slepnev; M. Stanoiu; P. Strmen; I. Szarka; M. Takechi; Y. Tanaka; H. Weick; J. S. Winfield

    2015-05-29T23:59:59.000Z

    The beta decay of 31Ar, produced by fragmentation of a 36Ar beam at 880 MeV/nucleon, was investigated. Identified ions of 31Ar were stopped in a gaseous time projection chamber with optical readout allowing to record decay events with emission of protons. In addition to \\b{eta}-delayed emission of one and two protons we have clearly observed the beta-delayed three-proton branch. The branching ratio for this channel in 31Ar is found to be 0.07(2)%.

  15. Oxygen-driven relaxation processes in pre-irradiated Ar cryocrystals

    E-Print Network [OSTI]

    Savchenko, E. V; Belov, A. G; Gumenchuk, G. B; Ponomaryov, A. N; Bondybey, V. E

    2006-01-01T23:59:59.000Z

    Excitations of Solid Oxygen ?in Russian?, B. I. Verkin andNUMBER 11 NOVEMBER 2006 Oxygen-driven relaxation processes? Relaxation processes in oxygen-containing Ar cryocrystals

  16. Enriched Zn$^{100}$MoO$_4$ scintillating bolometers to search for $0 ? 2?$ decay of $^{100}$Mo with the LUMINEU experiment

    E-Print Network [OSTI]

    A. S. Barabash; D. M. Chernyak; F. A. Danevich; A. Giuliani; I. M. Ivanov; E. P. Makarov; M. Mancuso; S. Marnieros; S. G. Nasonov; C. Nones; E. Olivieri; G. Pessina; D. V. Poda; V. N. Shlegel; M. Tenconi; V. I. Tretyak; Ya. V. Vasiliev; M. Velazquez; V. N. Zhdankov

    2014-07-05T23:59:59.000Z

    The LUMINEU project aims at performing a demonstrator underground experiment searching for the neutrinoless double beta decay of the isotope $^{100}$Mo embedded in zinc molybdate (ZnMoO$_4$) scintillating bolometers. In this context, a zinc molybdate crystal boule enriched in $^{100}$Mo to 99.5\\% with a mass of 171 g was grown for the first time by the low-thermal-gradient Czochralski technique. The production cycle provided a high yield (the crystal boule mass was 84\\% of initial charge) and an acceptable level -- around 4\\% -- of irrecoverable losses of the costy enriched material. Two crystals of 59 g and 63 g, obtained from the enriched boule, were tested aboveground at milli-Kelvin temperature as scintillating bolometers. They showed a high detection performance, equivalent to that of previously developed natural ZnMoO$_4$ detectors. These results pave the way to future sensitive searches based on the LUMINEU technology, capable to approach and explore the inverted hierarchy region of the neutrino mass pattern.

  17. Dusty Plasma in He-Ar Glow Discharge

    SciTech Connect (OSTI)

    Maiorov, S. A. [A. M. Prokhorov Institute for General Physics under Russian Academy of Sciences, Moscow (Russian Federation); Ramazanov, T. S.; Dzhumagulova, K. N.; Dosbolayev, M. K.; Jumabekov, A. N. [IETP, al-Farabi Kazakh National University, 96a, Tole bi St., Almaty, 050012 (Kazakhstan)

    2008-09-07T23:59:59.000Z

    The paper reports on the first experiments with plasma-dust formations in dc gas discharge plasma for He-Ar mixture. It is shown that under the conventional conditions of the experiments with dusty structures in plasma, the choice of light and heavy gases for the mixture suppresses electron heating in electric field and results in a supersonic jet with high Mach numbers. Distribution functions for drifting ions in the gas mixture are calculated for various mixture concentrations, electric field strengths and gas pressures.

  18. Category:Little Rock, AR | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty EditCalifornia:Power LPInformationCashtonGo Back to PV EconomicsdisplaysAR"

  19. Control of absorption of monolayer MoS$_{2}$ thin-film transistor in one-dimensional defective photonic crystal

    E-Print Network [OSTI]

    Yang, Fang-Fang; Xiao, Wen-bo; Liu, Jiang-Tao; Liu, Nian-Hua

    2014-01-01T23:59:59.000Z

    The light absorption and transmission of monolayer MoS$_{2}$ in a one-dimensional defective photonic crystal (d-1DPC) is theoretically investigated. The study shows that the strong interference effect decreases photon density in particular areas of the microcavity. The d-1DPC can reduce light absorption of monolayer MoS$_{2}$ and enhance light transmission. The impact of monolayer MoS$_{2}$ light absorption on the localization effect of photon is investigated when monolayer MoS$_{2}$ and the organic light-emitting diode are located in the same microcavity. However, monolayer MoS$_{2}$ does not reduce the localization effect of light by regulating the position of monolayer MoS$_{2}$ in the microcavity.

  20. Effects of rhenium alloying on the microstructures and mechanical properties of directionally solidified NiAl-Mo eutectic alloy

    SciTech Connect (OSTI)

    Misra, A.; Wu, Z.L.; Gibala, R. [Univ. of Michigan, Ann Arbor, MI (United States). Dept. of Materials Science and Engineering

    1997-12-31T23:59:59.000Z

    Low ductility of the reinforcing bcc metal phase at room temperature and weak interfaces can limit the intrinsic toughness and ductility of NiAl-bcc metal eutectic composites. The potential of rhenium (Re) addition, which is known to solid solution soften and lower the ductile-to-brittle transition temperature of various bcc metals, to enhance the ductility and toughness of a directionally solidified NiAl-9 at.% Mo eutectic alloy was investigated. Re partitioned to the bcc metal phase and formed a substitutional solid solution. The interface morphology was changed from a faceted to a non-faceted one. Re alloying caused softening of the Mo fibers, and as a result NiAl-Mo(Re) alloys were softer in compression and flexure and had {approximately}20% higher fracture toughness values as compared to the transverse orientation toughness of NiAl-9Mo alloy. The toughness of the NiAl-Mo(Re) alloys was lower than the longitudinal orientation toughness of the NiAl-9Mo alloy due to the poor alignment of the Mo(Re) phase with the growth direction. The toughening mechanisms have been evaluated and schemes for processing NiAl-Mo(Re) alloys for higher toughness in the longitudinal orientation are suggested. The role of the residual interstitial impurities and partitioning of Ni and Al to Mo fibers on the mechanical properties are highlighted.

  1. Method for the production of {sup 99m}Tc compositions from {sup 99}Mo-containing materials

    DOE Patents [OSTI]

    Bennett, R.G.; Christian, J.D.; Grover, S.B.; Petti, D.A.; Terry, W.K.; Yoon, W.Y.

    1998-09-01T23:59:59.000Z

    An improved method is described for producing {sup 99m}Tc compositions from {sup 99}Mo compounds. {sup 100}Mo metal or {sup 100}MoO{sub 3} is irradiated with photons in a particle (electron) accelerator to ultimately produce {sup 99}MoO{sub 3}. This composition is then heated in a reaction chamber to form a pool of molten {sup 99}MoO{sub 3} with an optimum depth of 0.5--5 mm. A gaseous mixture thereafter evolves from the molten {sup 99}MoO{sub 3} which contains vaporized {sup 99}MoO{sub 3}, vaporized {sup 99m}TcO{sub 3}, and vaporized {sup 99m}TcO{sub 2}. This mixture is then combined with an oxidizing gas (O{sub 2(g)}) to generate a gaseous stream containing vaporized {sup 99m}Tc{sub 2}O{sub 7} and vaporized {sup 99}MoO{sub 3}. Next, the gaseous stream is cooled in a primary condensation stage in the reaction chamber to remove vaporized {sup 99}MoO{sub 3}. Cooling is undertaken at a specially-controlled rate to achieve maximum separation efficiency. The gaseous stream is then cooled in a sequential secondary condensation stage to convert vaporized {sup 99m}Tc{sub 2}O{sub 7} into a condensed {sup 99m}Tc-containing reaction product which is collected. 1 fig.

  2. Method for the production of .sup.99m Tc compositions from .sup.99 Mo-containing materials

    DOE Patents [OSTI]

    Bennett, Ralph G. (Idaho Falls, ID); Christian, Jerry D. (Idaho Falls, ID); Grover, S. Blaine (Idaho Falls, ID); Petti, David A. (Idaho Falls, ID); Terry, William K. (Idaho Falls, ID); Yoon, Woo Y. (Idaho Falls, ID)

    1998-01-01T23:59:59.000Z

    An improved method for producing .sup.99m Tc compositions from .sup.99 Mo compounds. .sup.100 Mo metal or .sup.100 MoO.sub.3 is irradiated with photons in a particle (electron) accelerator to ultimately produce .sup.99 MoO.sub.3. This composition is then heated in a reaction chamber to form a pool of molten .sup.99 MoO.sub.3 with an optimum depth of 0.5-5 mm. A gaseous mixture thereafter evolves from the molten .sup.99 MoO.sub.3 which contains vaporized .sup.99 MoO.sub.3, vaporized .sup.99m TcO.sub.3, and vaporized .sup.99m TcO.sub.2. This mixture is then combined with an oxidizing gas (O.sub.2(g)) to generate a gaseous stream containing vaporized .sup.99m Tc.sub.2 O.sub.7 and vaporized .sup.99 MoO.sub.3. Next, the gaseous stream is cooled in a primary condensation stage in the reaction chamber to remove vaporized .sup.99 MoO.sub.3. Cooling is undertaken at a specially-controlled rate to achieve maximum separation efficiency. The gaseous stream is then cooled in a sequential secondary condensation stage to convert vaporized .sup.99m Tc.sub.2 O.sub.7 into a condensed .sup.99m Tc-containing reaction product which is collected.

  3. An in situ x-ray spectroscopic study of Mo?{sup +} speciation in supercritical aqueous solutions

    SciTech Connect (OSTI)

    Yan, Hao [Missouri State University, Springfield, MO (United States); Mayanovic, Robert A. [Missouri State University, Springfield, MO (United States); Anderson, Alan J. [St. Francis Xavier Univ., Antigonish, NS (Canada); Meredith, Peter R. [St. Francis Xavier Univ., Antigonish, NS (Canada)

    2011-09-01T23:59:59.000Z

    In situ XRF and Mo K-edge XAS measurements were made on the ID20-B beam line at the APS on MoO? in 1 M H?O? aqueous solution, at temperatures between 400 and 600 °C. The samples were analyzed using a modified Bassett-type hydrothermal diamond anvil cell. Our XRF measurements show that MoO? is highly soluble in the supercritical H?O? aqueous fluid. Analysis of XAS spectra shows that the Mo?{sup +} ion exhibits consistent speciation in the H?O? aqueous solution at temperatures ranging from 400 to 600 °C.

  4. Mechanical properties of MoS2/graphene heterostructures Jin-Wu Jiang and Harold S. Park

    E-Print Network [OSTI]

    of the heterostructure is considerably smaller than the MoS2 due to lateral buckling of the outer graphene layers owning

  5. arXiv:0904.0927v1[math.AG]6Apr2009 CALCULATING THE PARABOLIC CHERN CHARACTER OF A

    E-Print Network [OSTI]

    Simpson, Carlos

    characters chP ar 1 (E), chP ar 2 (E) and chP ar 3 (E). The basic idea is to use the formula given in [IS2

  6. Elementary Steps of Syngas Reactions on Mo2C(001): Adsorption Thermochemistry and Bond Dissociation

    SciTech Connect (OSTI)

    Medford, Andrew

    2012-02-16T23:59:59.000Z

    Density functional theory (DFT) and ab initio thermodynamics are applied in order to investigate the most stable surface and subsurface terminations of Mo{sub 2}C(001) as a function of chemical potential and in the presence of syngas. The Mo-terminated (001) surface is then used as a model surface to evaluate the thermochemistry and energetic barriers for key elementary steps in syngas reactions. Adsorption energy scaling relations and Broensted-Evans-Polanyi relationships are established and used to place Mo{sub 2}C into the context of transition metal surfaces. The results indicate that the surface termination is a complex function of reaction conditions and kinetics. It is predicted that the surface will be covered by either C{sub 2}H{sub 2} or O depending on conditions. Comparisons to transition metals indicate that the Mo-terminated Mo{sub 2}C(001) surface exhibits carbon reactivity similar to transition metals such as Ru and Ir, but is significantly more reactive towards oxygen.

  7. TEM Characterization of High Burn-up Microstructure of U-7Mo Alloy

    SciTech Connect (OSTI)

    Jian Gan; Brandon Miller; Dennis Keiser; Adam Robinson; James Madden; Pavel Medvedev; Daniel Wachs

    2014-04-01T23:59:59.000Z

    As an essential part of global nuclear non-proliferation effort, the RERTR program is developing low enriched U-Mo fuels (< 20% U-235) for use in research and test reactors that currently employ highly enriched uranium fuels. One type of fuel being developed is a dispersion fuel plate comprised of U-7Mo particles dispersed in Al alloy matrix. Recent TEM characterizations of the ATR irradiated U-7Mo dispersion fuel plates include the samples with a local fission densities of 4.5, 5.2, 5.6 and 6.3 E+21 fissions/cm3 and irradiation temperatures of 101-136?C. The development of the irradiated microstructure of the U-7Mo fuel particles consists of fission gas bubble superlattice, large gas bubbles, solid fission product precipitates and their association to the large gas bubbles, grain subdivision to tens or hundreds of nanometer size, collapse of bubble superlattice, and amorphisation. This presentation will describe the observed microstructures specifically focusing on the U-7Mo fuel particles. The impact of the observed microstructure on the fuel performance and the comparison of the relevant features with that of the high burn-up UO2 fuels will be discussed.

  8. Beta. -MoO sub 3 produced from a novel freeze drying route

    SciTech Connect (OSTI)

    Parise, J.B. (State Univ. of New York, Stony Brook (United States)); McCarron, E.M. III (E.I. Dupont de Nemours and Co., Inc., Wilmington, DE (United States)); Von Dreele, R.; Goldstone, J.A. (Los Alamos National Lab., NM (United States))

    1991-07-01T23:59:59.000Z

    Powdered samples of {beta}-MoO{sub 3} have been produced by the gentle heat treatment of freeze-dried molybdic acid at 350{degree}C for 1 hr. The samples, yellow-green in appearance, contained varying amounts of the thermodynamically stable {alpha}-MoO{sub 3}, depending upon the time and temperature of heat treatment. Neutron diffraction data were collected at 300 K. all peaks, not attributable to {alpha}-MoO{sub 3}, were indexed on the basis of a monoclinic cell, P2{sub 1}/c, {alpha} = 7.1228(7), b = 5.3660(6), c = 5.5665(6), {beta} = 92.01(1){degree}, V = 212.62(6){angstrom}{sup 3}. The structure, which is related to ReO{sub 3}, contains two crystallographically independent octahedra. Both show evidence of disorder at the Mo and O sites. Two distinct orientations of a short mo-O distance, suggestive of the type of molybdenyl bond observed in both the {alpha} and {beta}{prime}-forms, are primarily responsible for the observed disordering.

  9. Oxidation and creep behavior of Mo*5*Si*3* based materials

    SciTech Connect (OSTI)

    Meyer, M.

    1995-06-19T23:59:59.000Z

    Mo{sub 5}Si{sub 3} shows promise as a high temperature creep resistant material. The high temperature oxidation resistance of Mo{sub 5}Si{sub 3} has been found to be poor, however, limiting its use in oxidizing atmospheres. Undoped Mo{sub 5}Si{sub 3} exhibits mass loss in the temperature range 800{degrees}-1200{degrees}C due to volatilization of molybdenum oxide, indicating that the silica scale does not provide a passivating layer. The addition of boron results in protective scale formation and parabolic oxidation kinetics in the temperature range of 1050{degrees}-1300{degrees}C. The oxidation rate of Mo{sub 5}Si{sub 3} was decreased by 5 orders of magnitude at 1200{degrees}C by doping with less than two weight percent boron. Boron doping eliminates catastrophic {open_quote}pest{close_quote} oxidation at 800{degrees}C. The mechanism for improved oxidation resistance of boron doped Mo{sub 5}Si{sub 3} is due to scale modification by boron.

  10. Liquid generation during sintering of Fe-3.5%Mo powder compacts with elemental boron additions

    SciTech Connect (OSTI)

    Sarasola, M.; Gomez-Acebo, T.; Castro, F

    2004-09-06T23:59:59.000Z

    The mechanisms for liquid generation and the microstructural development during sintering of a Fe-3.5Mo-0.3B alloy were studied. Interrupted sintering experiments followed by water quenching from specific temperatures within the sintering cycle have been carried out. The influence of Mo, both, on the final microstructure and on the behaviour of boron prior to, during and after the formation of the liquid phase, was studied through observation of the quenched samples under LOM and SEM. The study shows that prior to the formation of the liquid phase, boron diffuses into the metallic particles forming inter and intragranular precipitates of the (Fe,Mo){sub 2}B type. At higher temperatures a continuous Fe/Mo/B liquid phase, with excellent wetting characteristics, is formed thus leading to near fully dense materials. The generation of the liquid is based on a eutectic reaction involving the mixed (Fe,Mo){sub 2}B borides previously formed. The development of the microstructure after liquid formation is described.

  11. Very-high-order harmonic generation from Ar atoms and Ar+ ions in superintense pulsed laser fields: An ab initio self-interaction-free time-dependent density-functional approach

    E-Print Network [OSTI]

    Carrera, Juan J.; Chu, Shih-I; Tong, Xiao-Min

    2005-06-21T23:59:59.000Z

    We present an ab initio nonpertubative investigation of the mechanisms responsible for the production of very-high-order harmonic generation (HHG) from Ar atoms and Ar+ ions by means of the self-interaction-free time-dependent density...

  12. Asymptotic Inference for AR Models with Heavy-tailed G-GARCH Noises

    E-Print Network [OSTI]

    Ling, Shiqing

    Asymptotic Inference for AR Models with Heavy-tailed G-GARCH Noises Rongmao Zhang Department-tailed G-GARCH(1,1) noises. When the tail index of G-GARCH is within (0, 2), it is shown that the LSE and finance. Keywords: AR model, G-GARCH, heavy-tailed and stable processes 1 #12;1 Introduction Since

  13. The Caribbean Low-Level Jet and Its Relationship with Precipitation in IPCC AR4 Models

    E-Print Network [OSTI]

    Martin, Elinor R.

    The Caribbean Low-Level Jet and Its Relationship with Precipitation in IPCC AR4 Models ELINOR R Report (AR4) shows that all models have the ability to simulate the location and height of the Caribbean Caribbean and, hence, an overly strong CLLJ. The ability of the models to simulate the correlation between

  14. Le magn)sme ar)ficiel pour les gaz d'atomes froids Jean Dalibard

    E-Print Network [OSTI]

    Dalibard, Jean

    Le magné)sme ar)ficiel pour les gaz d'atomes froids Jean Dalibard Année 2013-14 Chaire Atomes et rayonnement Magné8sme ar8ficiel pour un atome isolé (I) #12;Simula8on du magné8sme avec des atomes neutres Le but : réaliser pour

  15. Active species downstream of an ArO surface-wave microwave discharge for biomedicine,

    E-Print Network [OSTI]

    Guerra, Vasco

    Active species downstream of an Ar­O 2 surface-wave microwave discharge for biomedicine, surface.1088/0963-0252/20/3/035006 Active species downstream of an Ar­O2 surface-wave microwave discharge for biomedicine, surface treatment in a 0.5 cm diameter tube at pressures between 1 and 12 mbar. The early afterglow that occurs downstream

  16. Integrating 40 Ar, U-Pb, and astronomical clocks in the

    E-Print Network [OSTI]

    Meyers, Stephen R.

    956 Integrating 40 Ar/39 Ar, U-Pb, and astronomical clocks in the Cretaceous Niobrara Formation, British Geological Survey, Keyworth NG12 5GG, UK 6 U.S. Geological Survey, MS 980, Denver, Colorado 80225 radioiso- topic data with the floating astrochronology for the Niobrara Formation. The ages are determined

  17. Multiproperty empirical interatomic potentials for ArXe and KrXe

    SciTech Connect (OSTI)

    Pack, R.T; Valentini, J.J.; Becker, C.H.; Buss, R.J.; Lee, Y.T.

    1982-12-01T23:59:59.000Z

    Crossed molecular beam measurements of elastic differential cross sections (DCS) for the scattering of Ar and Kr by Xe are reported. Empirical multiparameter M3SV interatomic potentials for the ArXe and KrXe interactions are determined by simultaneously fitting the DCS, the viscosities, and virial coefficients; the results are the most accurate potentials yet reported for these systems.

  18. Atomistic full-band simulations of monolayer MoS{sub 2} transistors

    SciTech Connect (OSTI)

    Chang, Jiwon; Register, Leonard F.; Banerjee, Sanjay K. [Microelectronics Research Center, The University of Texas at Austin, Austin, Texas 78758 (United States)] [Microelectronics Research Center, The University of Texas at Austin, Austin, Texas 78758 (United States)

    2013-11-25T23:59:59.000Z

    We study the transport properties of deeply scaled monolayer MoS{sub 2} n-channel metal-oxide-semiconductor field effect transistors (MOSFETs), using full-band ballistic quantum transport simulations, with an atomistic tight-binding Hamiltonian obtained from density functional theory. Our simulations suggest that monolayer MoS{sub 2} MOSFETs can provide near-ideal subthreshold slope, suppression of drain-induced barrier lowering, and gate-induced drain leakage. However, these full-band simulations exhibit limited transconductance. These ballistic simulations also exhibit negative differential resistance (NDR) in the output characteristics associated with the narrow width in energy of the lowest conduction band, but this NDR may be substantially reduced or eliminated by scattering in MoS{sub 2}.

  19. Highly conducting SrMoO{sub 3} thin films for microwave applications

    SciTech Connect (OSTI)

    Radetinac, Aldin, E-mail: aldin@oxide.tu-darmstadt.de; Mani, Arzhang; Ziegler, Jürgen; Alff, Lambert; Komissinskiy, Philipp, E-mail: komissinskiy@oxide.tu-darmstadt.de [Institute of Materials Science, TU Darmstadt, Alarich-Weiss-Str. 2, 64287 Darmstadt (Germany); Melnyk, Sergiy; Nikfalazar, Mohammad; Zheng, Yuliang; Jakoby, Rolf [Institute for Microwave Engineering and Photonics, TU Darmstadt, Merckstraße 25, 64283 Darmstadt (Germany)

    2014-09-15T23:59:59.000Z

    We have measured the microwave resistance of highly conducting perovskite oxide SrMoO{sub 3} thin film coplanar waveguides. The epitaxial SrMoO{sub 3} thin films were grown by pulsed laser deposition and showed low mosaicity and smooth surfaces with a root mean square roughness below 0.3?nm. Layer-by-layer growth could be achieved for film thicknesses up to 400?nm as monitored by reflection high-energy electron diffraction and confirmed by X-ray diffraction. We obtained a constant microwave resistivity of 29???·cm between 0.1 and 20?GHz by refining the frequency dependence of the transmission coefficients. Our result shows that SrMoO{sub 3} is a viable candidate as a highly conducting electrode material for all-oxide microwave electronic devices.

  20. Time exposure performance of Mo-Au Gibbsian segregating alloys for extreme ultraviolet collector optics

    SciTech Connect (OSTI)

    Qiu Huatan; Srivastava, Shailendra N.; Thompson, Keith C.; Neumann, Martin J.; Ruzic, David N

    2008-05-01T23:59:59.000Z

    Successful implementation of extreme ultraviolet (EUV) lithography depends on research and progress toward minimizing collector optics degradation from intense plasma erosion and debris deposition. Thus studying the surface degradation process and implementing innovative methods, which could enhance the surface chemistry causing the mirrors to suffer less damage, is crucial for this technology development. A Mo-Au Gibbsian segregation (GS) alloy is deposited on Si using a dc dual-magnetron cosputtering system and the damage is investigated as a result of time dependent exposure in an EUV source. A thin Au segregating layer is maintained through segregation during exposure, even though overall erosion in the Mo-Au sample is taking place in the bulk. The reflective material, Mo, underneath the segregating layer is protected by this sacrificial layer, which is lost due to preferential sputtering. In addition to theoretical work, experimental results are presented on the effectiveness of the GS alloys to be used as potential EUV collector optics material.

  1. Dual Feedback Controlled High Performance Ar Seeded ELMy H-mode Discharges in JET including Trace Tritium Experiments

    E-Print Network [OSTI]

    Dual Feedback Controlled High Performance Ar Seeded ELMy H-mode Discharges in JET including Trace Tritium Experiments

  2. Simulation of MGI Efficiency for Plasma Energy Conversion into Ar Radiation in JET and Implications for ITER

    E-Print Network [OSTI]

    Simulation of MGI Efficiency for Plasma Energy Conversion into Ar Radiation in JET and Implications for ITER

  3. Neutrino-nucleus scattering of {sup 95,97}Mo and {sup 116}Cd

    SciTech Connect (OSTI)

    Ydrefors, E. [Royal Institute of Technology (KTH), Alba Nova University Center, SE-10691 Stockholm, Sweden and Department of Physics, P.O. Box 35 (YFL), FI-40014 University of Jyväskylä (Finland); Almosly, W.; Suhonen, J. [Department of Physics, P.O. Box 35 (YFL), FI-40014 University of Jyväskylä (Finland)

    2013-12-30T23:59:59.000Z

    Accurate knowledge about the nuclear responses to supernova neutrinos for relevant nuclear targets is important both for neutrino detection and for astrophysical applications. In this paper we discuss the cross sections for the charged-current neutrino-nucleus scatterings off {sup 95,97}Mo and {sup 116}Cd. The microscopic quasiparticle-phonon model is adopted for the odd-even nuclei {sup 95,97}Mo. In the case of {sup 116}Cd we present cross sections both for the Bonn one-boson-exchange potential and self-consistent calculations based on modern Skyrme interactions.

  4. Characterization of metal contacts for two-dimensional MoS{sub 2} nanoflakes

    SciTech Connect (OSTI)

    Walia, Sumeet, E-mail: madhu.bhaskaran@rmit.edu.au, E-mail: kourosh.kalantar@rmit.edu.au, E-mail: sumeet.walia@rmit.edu.au; Balendhran, Sivacarendran; Sriram, Sharath; Bhaskaran, Madhu, E-mail: madhu.bhaskaran@rmit.edu.au, E-mail: kourosh.kalantar@rmit.edu.au, E-mail: sumeet.walia@rmit.edu.au [Functional Materials and Microsystems Research Group, RMIT University, Melbourne, Victoria 3000 (Australia) [Functional Materials and Microsystems Research Group, RMIT University, Melbourne, Victoria 3000 (Australia); School of Electrical and Computer Engineering, RMIT University, Melbourne, Victoria 3000 (Australia); Wang, Yichao; Ab Kadir, Rosmalini; Sabirin Zoolfakar, Ahmad; Atkin, Paul; Zhen Ou, Jian; Kalantar-zadeh, Kourosh, E-mail: madhu.bhaskaran@rmit.edu.au, E-mail: kourosh.kalantar@rmit.edu.au, E-mail: sumeet.walia@rmit.edu.au [School of Electrical and Computer Engineering, RMIT University, Melbourne, Victoria 3000 (Australia)] [School of Electrical and Computer Engineering, RMIT University, Melbourne, Victoria 3000 (Australia)

    2013-12-02T23:59:59.000Z

    While layered materials are increasingly investigated for their potential in nanoelectronics, their functionality and efficiency depend on charge injection into the materials via metallic contacts. This work explores the characteristics of different metals (aluminium, tungsten, gold, and platinum) deposited on to nanostructured thin films made of two-dimensional (2D) MoS{sub 2} flakes. Metals are chosen based on their work functions relative to the electron affinity of MoS{sub 2}. It is observed, and analytically verified that lower work functions of the contact metals lead to smaller Schottky barrier heights and consequently higher charge carrier injection through the contacts.

  5. Evolution of level density step structures from 56,57-Fe to 96,97-Mo

    E-Print Network [OSTI]

    A. Schiller; E. Tavukcu; L. A. Bernstein; P. E. Garrett; M. Guttormsen; M. Hjorth-Jensen; C. W. Johnson; G. E. Mitchell; J. Rekstad; S. Siem; A. Voinov; W. Younes

    2003-02-24T23:59:59.000Z

    Level densities have been extracted from primary gamma spectra for 56,57-Fe and 96,97-Mo nuclei using (3-He,alpha gamma) and (3-He,3-He') reactions on 57-Fe and 97-Mo targets. The level density curves reveal step structures above the pairing gap due to the breaking of nucleon Cooper pairs. The location of the step structures in energy and their shapes arise from the interplay between single-particle energies and seniority-conserving and seniority-non-conserving interactions.

  6. Background radioactivity of construction materials, raw substance and ready-made CaMoO4 crystals

    E-Print Network [OSTI]

    Busanov, O A; Gavriljuk, Yu M; Gezhaev, A M; Kazalov, V V; Kornoukhov, V N; Kuzminov, V V; Moseev, P S; Panasenko, S I; Ratkevich, S S; Yakimenko, S P

    2013-01-01T23:59:59.000Z

    The results of measurements of natural radioactive isotopes content in different source materials of natural and enriched composition used for CaMoO4 scintillation crystal growing are presented. The crystals are to be used in the experiment to search for double neutrinoless betas-decay of Mo-100.

  7. Pseudo-elastic deformation behavior in a Ti/Mo-based alloy , M. Aindow a,*, S.P. Alpay a

    E-Print Network [OSTI]

    Alpay, S. Pamir

    , and are increasingly finding applications in aerospace, oil well systems and automotive parts [1]. Alloys in the metaPseudo-elastic deformation behavior in a Ti/Mo-based alloy T. Zhou a , M. Aindow a,*, S.P. Alpay 2003 Abstract It is shown that the pseudo-elastic response in a series of Ti­Mo­V­Nb­Al alloys with 8

  8. Solar Energy Materials & Solar Cells 58 (1999) 199}208 The behaviour of Na implanted into Mo thin "lms

    E-Print Network [OSTI]

    Rockett, Angus

    Solar Energy Materials & Solar Cells 58 (1999) 199}208 The behaviour of Na implanted into Mo thin, As ngstro( m Solar Center, P.O. Box 534, SE-751 21 Uppsala, Sweden Department of Materials Science Mo thin "lms used as back contacts for Cu(In,Ga)Se solar cells. The samples were analysed

  9. Ultra-thin Titanium Oxide Films on Accession #s 00936, 00937,00938 Mo(112), Measured by XPS Technique: XPS

    E-Print Network [OSTI]

    Goodman, Wayne

    Ultra-thin Titanium Oxide Films on Accession #s 00936, 00937,00938 Mo(112), Measured by XPS preparation methods were employed to grow a well-ordered ultra-thin titanium oxide film on Mo(J (2), The tirst: photoemission; titanium oxide; tllin film PACS: 81.15.Gh. 79,60.Dp SPECIMEN DESCRIPTION (Accession #00936) Host

  10. Giant Two-Photon Absorption Coefficient and Frequency Up-Converted Luminescence in Monolayer MoS2

    E-Print Network [OSTI]

    Li, Yuanxin; Zhang, Saifeng; Zhang, Xiaoyan; Feng, Yanyan; Wang, Kangpeng; Zhang, Long; Wang, Jun

    2015-01-01T23:59:59.000Z

    Strong two-photon absorption (TPA) in monolayer MoS2 is demonstrated in contrast to saturable absorption (SA) in multilayer MoS2 under the excitation of femtosecond laser pulses in the near infrared region. MoS2 in the forms of monolayer single crystal and multilayer triangular islands are grown on either quartz or SiO2/Si by employing the seeding method through chemistry vapor deposition. The nonlinear transmission measurements reveal that monolayer MoS2 possesses a giant nonsaturation TPA coefficient, larger than that of conventional semiconductors. As a result of TPA, two-photon pumped frequency up-converted luminescence is observed directly in the monolayer MoS2. For the multilayer MoS2, the SA response is demonstrated with the ratio of the excited-state absorption cross section to ground-state cross section of 0.18. In addition, the laser damage threshold of the monolayer MoS2 is 97 GW/cm2, larger than that of the multilayer MoS2 of 78 GW/cm2.

  11. High blue-near ultraviolet photodiode response of vertically stacked graphene-MoS{sub 2}-metal heterostructures

    SciTech Connect (OSTI)

    Wi, Sungjin; Chen, Mikai; Nam, Hongsuk; Liu, Amy C.; Meyhofer, Edgar; Liang, Xiaogan, E-mail: xiaoganl@umich.edu [Department of Mechanical Engineering, University of Michigan, Ann Arbor, Michigan 48109 (United States)

    2014-06-09T23:59:59.000Z

    We present a study on the photodiode response of vertically stacked graphene/MoS{sub 2}/metal heterostructures in which MoS{sub 2} layers are doped with various plasma species. In comparison with undoped heterostructures, such doped ones exhibit significantly improved quantum efficiencies in both photovoltaic and photoconductive modes. This indicates that plasma-doping-induced built-in potentials play an important role in photocurrent generation. As compared to indium-tin-oxide/ MoS{sub 2}/metal structures, the presented graphene/MoS{sub 2}/metal heterostructures exhibit greatly enhanced quantum efficiencies in the blue-near ultraviolet region, which is attributed to the low density of recombination centers at graphene/MoS{sub 2} heterojunctions. This work advances the knowledge for making photo-response devices based on layered materials.

  12. Single-layer MoS{sub 2} roughness and sliding friction quenching by interaction with atomically flat substrates

    SciTech Connect (OSTI)

    Quereda, J. [Departamento de Física de la Materia Condensada, Universidad Autónoma de Madrid, Madrid E-28049 (Spain); Castellanos-Gomez, A. [Kavli Institute of Nanoscience, Delft University of Technology, Lorentzweg 1, 2628 CJ Delft (Netherlands); Agraït, N. [Departamento de Física de la Materia Condensada, Universidad Autónoma de Madrid, Madrid E-28049 (Spain); Instituto Madrileño de Estudios Avanzados en Nanociencia, IMDEA-Nanociencia, E-28049 Madrid (Spain); Instituto de Ciencia de Materiales Nicolás Cabrera, Campus de Cantoblanco, E-28049 Madrid (Spain); Condensed Matter Physics Center (IFIMAC), Universidad Autónoma de Madrid, E-28049 Madrid (Spain); Rubio-Bollinger, G., E-mail: gabino.rubio@uam.es [Departamento de Física de la Materia Condensada, Universidad Autónoma de Madrid, Madrid E-28049 (Spain); Instituto de Ciencia de Materiales Nicolás Cabrera, Campus de Cantoblanco, E-28049 Madrid (Spain); Condensed Matter Physics Center (IFIMAC), Universidad Autónoma de Madrid, E-28049 Madrid (Spain)

    2014-08-04T23:59:59.000Z

    We experimentally study the surface roughness and the lateral friction force in single-layer MoS{sub 2} crystals deposited on different substrates: SiO{sub 2}, mica, and hexagonal boron nitride (h-BN). Roughness and sliding friction measurements are performed by atomic force microscopy. We find a strong dependence of the MoS{sub 2} roughness on the underlying substrate material, being h-BN the substrate which better preserves the flatness of the MoS{sub 2} crystal. The lateral friction also lowers as the roughness decreases, and attains its lowest value for MoS{sub 2} flakes on h-BN substrates. However, it is still higher than for the surface of a bulk MoS{sub 2} crystal, which we attribute to the deformation of the flake due to competing tip-to-flake and flake-to-substrate interactions.

  13. M. Flierl: Coding of Multiview Imagery with Motion and Disparity Compensated Orthogonal Transforms, IEEE ICIP, San Antonio, TX, Sep. 2007. 1 CODING OF MULTIVIEW IMAGERY WITH MOTION AND DISPARITY

    E-Print Network [OSTI]

    Flierl, Markus

    that so called motion-compensated lifted wavelets may substantially deviate from orthonormality due to mo viewpoint video [1] to free viewpoint television (FTV) [2]. All of them require efficient coding

  14. GAS AND DUST ABSORPTION IN THE DoAr 24E SYSTEM

    SciTech Connect (OSTI)

    Kruger, Andrew J. [Department of Physical Science, Wilbur Wright College, 4300 North Narragansett Avenue, Chicago, IL 60634 (United States); Richter, Matthew J. [Department of Physics, University of California at Davis, One Shields Avenue, Davis, CA 95616 (United States); Seifahrt, Andreas [Department of Astronomy and Astrophysics, University of Chicago, 5640 South Ellis Avenue, Chicago, IL 60637 (United States); Carr, John S. [Remote Sensing Division, Naval Research Laboratory, Code 7210, Washington, DC 20375 (United States); Najita, Joan R. [National Optical Astronomy Observatory, Tucson, AZ 85719 (United States); Moerchen, Margaret M. [European Southern Observatory, Alonso de Cordova 3107, Santiago (Chile); Doppmann, Greg W. [W.M. Keck Observatory, 65-1120 Mamalahoa Hwy, Kamuela, HI 96743 (United States)

    2012-11-20T23:59:59.000Z

    We present findings for DoAr 24E, a binary system that includes a classical infrared companion. We observed the DoAr 24E system with the Spitzer Infrared Spectrograph (IRS), with high-resolution, near-infrared spectroscopy of CO vibrational transitions, and with mid-infrared imaging. The source of high extinction toward infrared companions has been an item of continuing interest. Here we investigate the disk structure of DoAr 24E using the column densities, temperature, and velocity profiles of two CO absorption features seen toward DoAr 24Eb. We model the spectral energy distributions found using T-ReCS imaging and investigate the likely sources of extinction toward DoAr 24Eb. We find the lack of silicate absorption and small CO column density toward DoAr 24Eb suggest that the mid-infrared continuum is not as extinguished as the near-infrared, possibly due to the mid-infrared originating from an extended region. This, along with the velocity profile of the CO absorption, suggests that the source of high extinction is likely due to a disk or disk wind associated with DoAr 24Eb.

  15. BBA Electives: M&O Comparison Compiled 11/11/09

    E-Print Network [OSTI]

    Michigan, University of

    University ­ Marriott Organizational Development and Change Teams and Work Groups Human Resource Management Compensation Management Labor Relations and Conflict Management Staffing Organizations Motivation and Work MIT1 BBA Electives: M&O Comparison Compiled 11/11/09 University of Michigan ­ Ross School Management

  16. EIS-0475: Disposition of the Bannister Federal Complex, Kansas City, MO

    Broader source: Energy.gov [DOE]

    NNSA/DOE announces its intent to prepare an EIS for the disposition of the Bannister Federal Complex, Kansas City, MO. NNSA previously decided in a separate NEPA review (EA-1592) to relocate its operations from the Bannister Federal Complex to a newly constructed industrial campus eight miles from the current location.

  17. MoDPepInt: An interactive webserver for prediction of modular domain-peptide interactions

    E-Print Network [OSTI]

    Brendel, Volker

    MoDPepInt: An interactive webserver for prediction of modular domain-peptide interactions-Supervised Prediction of SH2-Peptide Interactions from Imbalanced High-Throughput Data PLoS One, 8(5), pp. e62732, 2013-peptide interaction prediction with an application to human SH3 domains Bioinformatics, 29(13), pp. i335-i343, 2013

  18. On the Higher-Order MoM-PO Electromagnetic Modeling of Vehicles

    E-Print Network [OSTI]

    Notaros, Branislav M.

    vehicles (cars, airplanes, helicopters, spacecraft, etc.). From the electromagnetic point of view and accurate higher-order, large-domain hybrid computational technique based on the method of moments (Mo the efficiency and accuracy of the hybrid higher-order computational technique and its advantages over

  19. Enriched Zn$^{100}$MoO$_4$ scintillating bolometers to search for $0 \

    E-Print Network [OSTI]

    Barabash, A S; Danevich, F A; Giuliani, A; Ivanov, I M; Makarov, E P; Mancuso, M; Marnieros, S; Nasonov, S G; Nones, C; Olivieri, E; Pessina, G; Poda, D V; Shlegel, V N; Tenconi, M; Tretyak, V I; Vasiliev, Ya V; Velazquez, M; Zhdankov, V N

    2014-01-01T23:59:59.000Z

    The LUMINEU project aims at performing a demonstrator underground experiment searching for the neutrinoless double beta decay of the isotope $^{100}$Mo embedded in zinc molybdate (ZnMoO$_4$) scintillating bolometers. In this context, a zinc molybdate crystal boule enriched in $^{100}$Mo to 99.5\\% with a mass of 171 g was grown for the first time by the low-thermal-gradient Czochralski technique. The production cycle provided a high yield (the crystal boule mass was 84\\% of initial charge) and an acceptable level -- around 4\\% -- of irrecoverable losses of the costy enriched material. Two crystals of 59 g and 63 g, obtained from the enriched boule, were tested aboveground at milli-Kelvin temperature as scintillating bolometers. They showed a high detection performance, equivalent to that of previously developed natural ZnMoO$_4$ detectors. These results pave the way to future sensitive searches based on the LUMINEU technology, capable to approach and explore the inverted hierarchy region of the neutrino mass p...

  20. Molecular Adsorption to LiMo3Se3 Nanowire Film Chemiresistors

    E-Print Network [OSTI]

    Chiang, Shirley

    Molecular Adsorption to LiMo3Se3 Nanowire Film Chemiresistors Xiubin Qi, Frank E. Osterloh,*, S. A that the temporal and steady-state resistance changes of the films depend on the time following the adsorption and on the number of molecules that adsorb to the nanowire films at a given pressure. The adsorption ability

  1. Investigation of Double Beta Decay of 100Mo to Excited States of 100Ru

    SciTech Connect (OSTI)

    A. J. Caffrey; The NEMO-3 Collaboration

    2014-05-01T23:59:59.000Z

    Double beta decay of 100Mo to the excited states of daughter nuclei has been studied using a 600 cm3 low-background HPGe detector and an external source consisting of 2588 g of 97.5% enriched metallic 100Mo, which was formerly inside the NEMO-3 detector and used for the NEMO-3 measurements of 100Mo. The half-life for the two-neutrino double beta decay of 100Mo to the excited View the MathML source state in 100Ru is measured to be T1/2=[7.5±0.6(stat)±0.6(syst)]·1020 yr. For other (0?+2?) transitions to the View the MathML source, View the MathML source, View the MathML source, View the MathML source and View the MathML source levels in 100Ru, limits are obtained at the level of ~(0.25–1.1)·1022 yr.

  2. Magnetic cluster excitations in the antiferromagnetic phase of a-MnMoO4 

    E-Print Network [OSTI]

    Ochsenbein, Stefan T; Chaboussant, Gregory; Sieber, Andreas; Gudel, Hans U; Janssen, Stefan; Furrer, Albert; Attfield, J. Paul

    2003-01-01T23:59:59.000Z

    The tetramer-based compound a-MnMoO4 exhibits four prominent peaks in the inelastic neutron scattering (INS) spectrum between 0.5 and 2.0 meV below 10 K. They are assigned to magnetic excitations of the (Mn2+)4 rhombus ...

  3. Irradiation Performance of U-Mo Alloy Based ‘Monolithic’ Plate-Type Fuel – Design Selection

    SciTech Connect (OSTI)

    A. B. Robinson; G. S. Chang; D. D. Keiser, Jr.; D. M. Wachs; D. L. Porter

    2009-08-01T23:59:59.000Z

    A down-selection process has been applied to the U-Mo fuel alloy based monolithic plate fuel design, supported by irradiation testing of small fuel plates containing various design parameters. The irradiation testing provided data on fuel performance issues such as swelling, fuel-cladding interaction (interdiffusion), blister formation at elevated temperatures, and fuel/cladding bond quality and effectiveness. U-10Mo (wt%) was selected as the fuel alloy of choice, accepting a somewhat lower uranium density for the benefits of phase stability. U-7Mo could be used, with a barrier, where the trade-off for uranium density is critical to nuclear performance. A zirconium foil barrier between fuel and cladding was chosen to provide a predictable, well-bonded, fuel-cladding interface, allowing little or no fuel-cladding interaction. The fuel plate testing conducted to inform this selection was based on the use of U-10Mo foils fabricated by hot co-rolling with a Zr foil. The foils were subsequently bonded to Al-6061 cladding by hot isostatic pressing or friction stir bonding.

  4. Lithium Intercalation in Graphene/MoS2 Composites: First-Principles Insights

    E-Print Network [OSTI]

    Shao, Xiji; Pang, Rui; Shi, Xingqiang

    2015-01-01T23:59:59.000Z

    As a storage material for Li-ion batteries, graphene/molybdenum disulfide (Gr/MoS2) composites have been intensively studied in experiments. But the relevant theoretical works from first-principles are lacking. In the current work, van-der-Waals-corrected density functional theory calculations are performed to investigate the interaction of Li in Gr/MoS2 composites. Three interesting features are revealed for the intercalated Gr/Li(n)/MoS2 composites (n = 1 to 9). One is the reason for large Li storage capacity of Gr/MoS2: due to the binding energies per Li atom increase with the increasing number of intercalated Li atoms. Secondly, the band gap opening of Gr is found, and the band gap is enlarged with the increasing number of intercalated Li atoms, up to 160 meV with nine Li; hence these results suggest an efficient way to tune the band gap of graphene. Thirdly, the Dirac cone of Gr always preserve for different number of ionic bonded Li atoms.

  5. This is MoFo. Scientific/Technical Patent Analysts/Agents

    E-Print Network [OSTI]

    Straight, Aaron

    This is MoFo. Scientific/Technical Patent Analysts/Agents (Los Angeles, CA; McLean, VA; Palo Alto level patent analysts/agents for our Los Angeles, Palo Alto, San Diego and San Francisco offices of business strategies. Patent analysts/agents participate in domestic and foreign patent prosecution

  6. 2008 IEEE Swarm Intelligence Symposium St. Louis MO USA, September 21-23, 2008

    E-Print Network [OSTI]

    Havens, Timothy

    2008 IEEE Swarm Intelligence Symposium St. Louis MO USA, September 21-23, 2008 Roach Infestation of the PSO algorithm, entitled Roach Infestation Optimization (RIO), that is inspired by recent discoveries discoveries in the behavior of cockroaches are the inspiration for our proposed algorithm, Roach Infestation

  7. Safety Analysis Using Coloured Petri Nets Seung Mo Cho, Hyoung Seok Hong, and Sung Deok Cha

    E-Print Network [OSTI]

    as an example. 1. Introduction Software control in safety-critical systems such as aerospace, military, nuclearSafety Analysis Using Coloured Petri Nets Seung Mo Cho, Hyoung Seok Hong, and Sung Deok Cha Department of Computer Science Korea Advanced Institute of Science and Technology (KAIST) 373-1, Kusong

  8. A Network Model and Computational Approach Mo Supply Chain for Nuclear Medicine

    E-Print Network [OSTI]

    Nagurney, Anna

    A Network Model and Computational Approach for the 99 Mo Supply Chain for Nuclear Medicine Ladimer S. Nagurney1 and Anna Nagurney2 1Department of Electrical and Computer Engineering University University of Massachusetts - Amherst, Massachusetts 01003 Fall 2011 Joint Meeting Of The New England

  9. ZnMoO4: a promising bolometer for neutrinoless double beta decay searches

    E-Print Network [OSTI]

    J. W. Beeman; F. Bellini; S. Capelli; L. Cardani; N. Casali; I. Dafinei; S. Di Domizio; F. Ferroni; E. N. Galashov; L. Gironi; F. Orio; L. Pattavina; G. Pessina; G. Piperno; S. Pirro; V. N. Shlegel; Ya. V. Vasilyev; C. Tomei; M. Vignati

    2012-02-01T23:59:59.000Z

    We investigate the performances of two ZnMoO4 scintillating crystals operated as bolometers, in view of a next generation experiment to search the neutrinoless double beta decay of Mo-100. We present the results of the alpha vs beta/gamma discrimination, obtained through the scintillation light as well as through the study of the shape of the thermal signal alone. The discrimination capability obtained at the 2615 keV line of Tl-208 is 8 sigma, using the heat-light scatter plot, while it exceeds 20 sigma using the shape of the thermal pulse alone. The achieved FWHM energy resolution ranges from 2.4 keV (at 238 keV) to 5.7 keV (at 2615 keV). The internal radioactive contaminations of the ZnMoO4 crystals were evaluated through a 407 hours background measurement. The obtained limit is < 32 microBq/kg for Th-228 and Ra-226. These values were used for a Monte Carlo simulation aimed at evaluating the achievable background level of a possible, future array of enriched ZnMoO4 crystals.

  10. Interlayer growth in Mo/B{sub 4}C multilayered structures upon thermal annealing

    SciTech Connect (OSTI)

    Nyabero, S. L.; Kruijs, R. W. E. van de; Yakshin, A. E.; Zoethout, E.; Bosgra, J.; Loch, R. A. [FOM Dutch Institute for Fundamental Energy Research (DIFFER), P.O. Box 1207, 3430 BE Nieuwegein (Netherlands); Blanckenhagen, G. von [Carl Zeiss SMT GmbH, Rudolf-Eber-Strasse 2, 73447 Oberkochen (Germany); Bijkerk, F. [FOM Dutch Institute for Fundamental Energy Research (DIFFER), P.O. Box 1207, 3430 BE Nieuwegein (Netherlands); MESA Institute for Nanotechnology, University of Twente, P.O. Box 217, 7500 AE Enschede (Netherlands)

    2013-04-14T23:59:59.000Z

    Both multilayer period thickness expansion and compaction were observed in Mo/B{sub 4}C multilayers upon annealing, and the physical causes for this were explored in detail. Using in situ time-dependent grazing incidence X-ray reflectometry, period changes down to picometer-scale were resolved. It was shown that the changes depend on the thickness of the B{sub 4}C layers, annealing temperature, and annealing time. Although strong stress relaxation during annealing was observed, it was excluded as a cause for period expansion. Auger electron spectroscopy and wide angle X-ray diffraction measurements revealed the growth of interlayers, with associated period changes influenced by the supply of B and C atoms to the growing compound interlayers. For multilayers with a Mo thickness of 3 nm, two regimes were recognized, depending on the deposited B{sub 4}C thickness: in multilayers with B{sub 4}C {<=} 1.5 nm, the supply of additional Mo into the already formed MoB{sub x}C{sub y} interlayer was dominant and led to densification, resulting in period compaction. For multilayers with B{sub 4}C {>=} 2 nm, the B and C enrichment of interlayers formed low density compounds and yielded period expansion.

  11. TURBO EQUALIZATIONWITH AN UNKNOWN CHANNEL SeongwookSong', Andrew C. Singer2,Koeng-MoSun?

    E-Print Network [OSTI]

    Singer, Andrew C

    TURBO EQUALIZATIONWITH AN UNKNOWN CHANNEL SeongwookSong', Andrew C. Singer2,Koeng-MoSun? l t 2Univ the method of turbo equalization originally de- veloped by Douillard, et al. [3]. In its original form, turbo and without training data. The resultingjoint channeland data estimator is shown to outperform standard turbo

  12. TheElectronMicroscopyCore(EMC) UniversityofMissouriColumbia,MO65211

    E-Print Network [OSTI]

    Noble, James S.

    TheElectronMicroscopyCore(EMC) UniversityofMissouriColumbia,MO65211 The. The EMC houses two field emission SEM's, a Hitachi cold-field SEM (S-4700) and a FEI thermal FE SEM imaging and chemical analysis from their SEM/EDS systems. AdditionalSupportby: FormoreInformationortoregistergoto:http://www.emc

  13. RobeRt & LauRie bean taishoff inciting a MoRe incLusive

    E-Print Network [OSTI]

    McConnell, Terry

    RobeRt & LauRie bean taishoff inciting a MoRe incLusive coLLege caMpus syRacuse univeRsity scho. Thanks to her expertise--and the generosity of Robert Taishoff '86 and Laurie Bean Taishoff '84--the

  14. Incremental Development for Automotive Software in AutoMoDe Andreas Bauer1

    E-Print Network [OSTI]

    Braun, Peter

    Incremental Development for Automotive Software in AutoMoDe Andreas Bauer1 Jan Romberg1 Bernhard Validas AG 3 ETAS GmbH 4 PMSF IT Consulting 5 Robert Bosch GmbH Abstract Automotive software development. To facilitate the design and evolution of heterogeneous automotive software, suitable views for each level

  15. Interaction Layer Characteristics in U-xMo Dispersion/Monolithic Fuels

    SciTech Connect (OSTI)

    D. L. Porter

    2010-11-01T23:59:59.000Z

    Published data concerning the interaction layer (IL) formed between U-xMo fuel alloy and aluminum (Al)-based matrix or cladding materials was reviewed, including the effects of silicon (Si) content in the matrix/cladding, molybdenum (Mo) content in the fuel, pre irradiation thermal treatments, irradiation, and test temperature. The review revealed that tests conducted in the laboratory produce results different from those conducted in an irradiation environment. However, the laboratory testing relates well to thermal treatments performed prior to irradiation and helps in understanding the effects that these pre irradiation treatments have on in reactor performance. A pre-formed, Si-enriched IL seems to be important in delaying the onset of rapid growth of fission gas bubbles at low irradaiiation temperatures. Several other conclusions can be drawn: 1. An IL with phases akin to UAl3 is desired for optimum fuel performance, but at low temperatures, and especially in an irradiation atmosphere, the desired (Al+Si)/(U+Mo) ratio of three is difficult to produce. When the fuel operating temperature is low, it is important to create a pre-irradiation IL, enriched in Si. This pre-formed IL is relatively stable, performs well in terms of swelling resistance, and prevents rapid IL growth during irradiation. 2. At higher operating temperatures (>150–170°C), IL formation in reactor may not be so dependent on pre-irradiation IL formation, especially at high burnup; a pre-fabricated IL seems to be less stable at high burnup and high operating temperature. Moreover, the (Al+SI)/(U+Mo) ratio of three occurs more often at higher temperature. For these two reasons, it is important at high operating temperature to also have a matrix with significant Si content to create an IL in reactor with the right characteristics. 3. Out-of-reactor testing seems to indicate that Si in the matrix material is required in some concentration (2%, 5%, ?) to provide for a thin, Si-enriched IL formed before irradiation of a fuel plate. It ensures that the IL contains beneficial phases, or prevents formation of some known to promote poor fuel performance. Significant progress has been made in determining the desired characteristics of the IL. 4. The use of a fuel with stable gamma phase appears to allow more predictable performance regarding both a beneficial pre-irradiation layer, and the fuel performance (low swelling) to high burnup. Destabilization of the gamma phase may create problems with IL breakaway growth. 5. A theory whereby prevention of the U6Mo4Al43 complex phase in interaction layers formed during fabrication may be a key to good irradiation performance. Si additions to the matrix allow for solubility of Mo in the desirable (U,Mo)(Al,Si)3 or perhaps (U,Mo)(Al,Si)4 phase, helping to prevent formation of the complex phase. Keeping alloy Mo content as low as possible may also help so long as decomposition does not occur in fabrication, forcing Mo into the interaction layer. This theory may explain a number of apparent anomalies observed in testing results. 6. More work is needed in order to prescribe the conditions to best produce a beneficial IL. Another necessity is a better understanding of any correlation between beneficial characteristics of the pre-fabricated IL and the irradiation conditions to which it will be subjected.

  16. First-principles study of the interfacial adhesion between SiO2 and MoSi2 D. E. Jiang1 and Emily A. Carter2

    E-Print Network [OSTI]

    Carter, Emily A.

    the energy efficiency and per- formance of gas turbine engines requires structural materials able to operate on MoSi2, a potential high-temperature coating material for metals. This silica scale protects MoSi2 the potential of MoSi2 as a high-temperature structural material and coating. DOI: 10.1103/PhysRevB.72

  17. The carburization of transition metal molybdates (MxMoO?, M= Cu, Ni or Co) and the generation of highly active metal/carbide catalysts for CO? hydrogenation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rodriguez, Jose A.; Xu, Wenqian; Ramirez, Pedro J.; Stachiola, Dario; Brito, Joaquin L.

    2015-05-06T23:59:59.000Z

    A new approach has been tested for the preparation of metal/Mo?C catalysts using mixed-metal oxide molybdates as precursors. Synchrotron-based in situ time-resolved X-ray diffraction was used to study the reduction and carburization processes of Cu?(MoO?)?(OH)?, a-NiMoO? and CoMoO?•nH?O by thermal treatment under mixtures of hydrogen and methane. In all cases, the final product was ?-Mo?C and a metal phase (Cu, Ni, or Co), but the transition sequence varied with the different metals, and it could be related to the reduction potential of the Cu²?, Ni²? and Co²? cations inside each molybdate. The synthesized Cu/Mo?C, Ni/Mo?C and Co/Mo?C catalysts were highlymore »active for the hydrogenation of CO?. The metal/Mo?C systems exhibited large variations in the selectivity towards methanol, methane and CnH?n?? (n > 2) hydrocarbons depending on the nature of the supported metal and its ability to cleave C-O bonds. Cu/Mo?C displayed a high selectivity for CO and methanol production. Ni/Mo?C and Co/Mo?C were the most active catalysts for the activation and full decomposition of CO?, showing high selectivity for the production of methane (Ni case) and CnH?n?? (n > 2) hydrocarbons (Co case).« less

  18. METALS AND MATERIALS International, Vol. 13, No. 6 (2007), pp. 463~468 Comparative Study on Mechanical Properties of MoSiN Multilayer Films

    E-Print Network [OSTI]

    Boo, Jin-Hyo

    2007-01-01T23:59:59.000Z

    -grown MoSiN thin films, argon and nitrogen plasmas ignited by RF and pulse DC under vacuum conditions were) and Ti-covered Si(100) substrates, as well as silicon nitride substrates. Titanium and its alloy have of a MoSi2 source in the presence of nitrogen plasma and MoSiN films have shown good thermal stability

  19. The carburization of transition metal molybdates (MxMoO?, M= Cu, Ni or Co) and the generation of highly active metal/carbide catalysts for CO? hydrogenation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rodriguez, Jose A. [Brookhaven National Lab. (BNL), Upton, NY (United States); Xu, Wenqian [Brookhaven National Lab. (BNL), Upton, NY (United States); Ramirez, Pedro J. [Brookhaven National Lab. (BNL), Upton, NY (United States); Univ. Central De Venezuela, Caracas (Venesuela); Stachiola, Dario [Brookhaven National Lab. (BNL), Upton, NY (United States); Brito, Joaquin L. [Inst. Venezolano de Investigaciones Cientificas, Caracas (Venezuela)

    2015-05-06T23:59:59.000Z

    A new approach has been tested for the preparation of metal/Mo?C catalysts using mixed-metal oxide molybdates as precursors. Synchrotron-based in situ time-resolved X-ray diffraction was used to study the reduction and carburization processes of Cu?(MoO?)?(OH)?, a-NiMoO? and CoMoO?•nH?O by thermal treatment under mixtures of hydrogen and methane. In all cases, the final product was ?-Mo?C and a metal phase (Cu, Ni, or Co), but the transition sequence varied with the different metals, and it could be related to the reduction potential of the Cu²?, Ni²? and Co²? cations inside each molybdate. The synthesized Cu/Mo?C, Ni/Mo?C and Co/Mo?C catalysts were highly active for the hydrogenation of CO?. The metal/Mo?C systems exhibited large variations in the selectivity towards methanol, methane and CnH?n?? (n > 2) hydrocarbons depending on the nature of the supported metal and its ability to cleave C-O bonds. Cu/Mo?C displayed a high selectivity for CO and methanol production. Ni/Mo?C and Co/Mo?C were the most active catalysts for the activation and full decomposition of CO?, showing high selectivity for the production of methane (Ni case) and CnH?n?? (n > 2) hydrocarbons (Co case).

  20. Processing, Microstructure and Creep Behavior of Mo-Si-B-Based Intermetallic Alloys for Very High Temperature Structural Applications

    SciTech Connect (OSTI)

    Vijay Vasudevan

    2008-03-31T23:59:59.000Z

    This research project is concerned with developing a fundamental understanding of the effects of processing and microstructure on the creep behavior of refractory intermetallic alloys based on the Mo-Si-B system. In the first part of this project, the compression creep behavior of a Mo-8.9Si-7.71B (in at.%) alloy, at 1100 and 1200 C was studied, whereas in the second part of the project, the constant strain rate compression behavior at 1200, 1300 and 1400 C of a nominally Mo-20Si-10B (in at.%) alloy, processed such as to yield five different {alpha}-Mo volume fractions ranging from 5 to 46%, was studied. In order to determine the deformation and damage mechanisms and rationalize the creep/high temperature deformation data and parameters, the microstructure of both undeformed and deformed samples was characterized in detail using x-ray diffraction, scanning electron microscopy (SEM) with back scattered electron imaging (BSE) and energy dispersive x-ray spectroscopy (EDS), electron back scattered diffraction (EBSD)/orientation electron microscopy in the SEM and transmission electron microscopy (TEM). The microstructure of both alloys was three-phase, being composed of {alpha}-Mo, Mo{sub 3}Si and T2-Mo{sub 5}SiB{sub 2} phases. The values of stress exponents and activation energies, and their dependence on microstructure were determined. The data suggested the operation of both dislocation as well as diffusional mechanisms, depending on alloy, test temperature, stress level and microstructure. Microstructural observations of post-crept/deformed samples indicated the presence of many voids in the {alpha}-Mo grains and few cracks in the intermetallic particles and along their interfaces with the {alpha}-Mo matrix. TEM observations revealed the presence of recrystallized {alpha}-Mo grains and sub-grain boundaries composed of dislocation arrays within the grains (in Mo-8.9Si-7.71B) or fine sub-grains with a high density of b = 1/2<111> dislocations (in Mo-20Si-10B), which are consistent with the values of the respective stress exponents and activation energies that were obtained and provide confirmatory evidence for the operation of diffusional (former alloy) or dislocation (latter alloy) creep mechanisms. In contrast, the intermetallic phases contained very few dislocations, but many cracks. The relative contributions of the {alpha}-Mo and the intermetallic particles to the overall deformation process, including their individual and collective dependence on temperature and strain rate are discussed in light of the present results and those from previous reports.

  1. Modeling of Interaction Layer Growth Between U-Mo Particles and an Al Matrix

    SciTech Connect (OSTI)

    Yeon Soo Kim; G. L. Hofman; Ho Jin Ryu; Jong Man Park; A. B. Robinson; D. M. Wachs

    2013-12-01T23:59:59.000Z

    Interaction layer growth between U-Mo alloy fuel particles and Al in a dispersion fuel is a concern due to the volume expansion and other unfavorable irradiation behavior of the interaction product. To reduce interaction layer (IL) growth, a small amount of Si is added to the Al. As a result, IL growth is affected by the Si content in the Al matrix. In order to predict IL growth during fabrication and irradiation, empirical models were developed. For IL growth prediction during fabrication and any follow-on heating process before irradiation, out-of-pile heating test data were used to develop kinetic correlations. Two out-of-pile correlations, one for the pure Al matrix and the other for the Al matrix with Si addition, respectively, were developed, which are Arrhenius equations that include temperature and time. For IL growth predictions during irradiation, the out-of-pile correlations were modified to include a fission-rate term to consider fission enhanced diffusion, and multiplication factors to incorporate the Si addition effect and the effect of the Mo content. The in-pile correlation is applicable for a pure Al matrix and an Al matrix with the Si content up to 8 wt%, for fuel temperatures up to 200 degrees C, and for Mo content in the range of 6 – 10wt%. In order to cover these ranges, in-pile data were included in modeling from various tests, such as the US RERTR-4, -5, -6, -7 and -9 tests and Korea’s KOMO-4 test, that were designed to systematically examine the effects of the fission rate, temperature, Si content in Al matrix, and Mo content in U-Mo particles. A model converting the IL thickness to the IL volume fraction in the meat was also developed.

  2. Novel Processing of mo-si-b Intermetallics for improved efficiency of power systems

    SciTech Connect (OSTI)

    M.J. Kramer; O. Degirmen; A.J. Thom; M. Akinc

    2004-09-30T23:59:59.000Z

    Multiphase composite alloys based on the Mo-Si-B system are candidate materials for ultra-high temperature applications. In non load-bearing applications such as thermal barrier coatings or heat exchangers in fossil fuel burners, these materials may be ideally suited. Alloys based on the Mo{sub 5}Si{sub 3}B{sub x} phase (Tl phase) possess excellent oxidation resistance to at least 1600 C in synthetic air atmospheres. However, the ability of Tl-based alloys to resist aggressive combustion environments has not yet been determined. The present work seeks to investigate the resistance of these Mo-Si-B alloys to simulated combustion atmospheres. Material was pre-alloyed by combustion synthesis, and samples for testing were prepared by classic powder metallurgical processing techniques. Precursor material synthesized by self-heating-synthesis was sintered to densities exceeding 98% in an argon atmosphere at 1800 C. The approximate phase assemblage of the material was 57% Tl, 29% MoB, 14% MoSi{sub 2} (wt%). The alloy was oxidized from 1000-1100 C in flowing air containing water vapor at 18 Torr. At 1000 C the material achieved a steady state mass loss, and at 1100 C the material undergoes a steady state mass gain. The oxidation rate of these alloys in this temperature regime was accelerated by the presence of water vapor compared to oxidation in dry air. The results of microstructural analysis of the tested alloys will be discussed. Techniques and preliminary results for fabricating near-net-shaped parts will also be presented.

  3. Investigation of the $^{37}Ar(n,p)$ $^{37}Cl$ and $^{37}Ar(n,\\alpha)$ $^{34}S$ reactions as a function of the neutron energy

    E-Print Network [OSTI]

    Wagemans, C; Wagemans, J; Bieber, R; Loiselet, M; Gaelens, M; Denecke, B; Geltenbort, P; Kolen, F; Wagemans, Cyriel; Goeminne, Gert; Wagemans, Jan; Bieber, Ronald; Loiselet, Marc; Gaelens, Michel; Denecke, Bruno; Geltenbort, Peter; Kolen, Filip

    1999-01-01T23:59:59.000Z

    The energy dependent 37Ar(n,p)37Cl and 37Ar(n,alpha)34S reaction cross sections were determined for the first time in an experimental effort involving three large facilities: the cyclotron of the UCL (Louvain-la-Neuve, Belgium) where implanted 37Ar samples were produced; the high flux reactor of the ILL (Grenoble, France) where thermal (n,p), (n,alpha_0) and (n,alpha_1) cross sections of (37+/-4)b, (1070+/-80)b and (290+/-50)mb respectively could be determined, and the GELINA neutron time-of-flight facility of the IRMM (Geel, Belgium) where strong resonances were observed in the keV region.

  4. Investigation of the 37Ar(n,p)37Cl and 37Ar(n,alpha)34S reactions as a function of the neutron energy

    E-Print Network [OSTI]

    Cyriel Wagemans; Gert Goeminne; Jan Wagemans; Ronald Bieber; Marc Loiselet; Michel Gaelens; Bruno Denecke; Peter Geltenbort; Filip Kolen

    1999-02-09T23:59:59.000Z

    The energy dependent 37Ar(n,p)37Cl and 37Ar(n,alpha)34S reaction cross sections were determined for the first time in an experimental effort involving three large facilities: the cyclotron of the UCL (Louvain-la-Neuve, Belgium) where implanted 37Ar samples were produced; the high flux reactor of the ILL (Grenoble, France) where thermal (n,p), (n,alpha_0) and (n,alpha_1) cross sections of (37+/-4)b, (1070+/-80)b and (290+/-50)mb respectively could be determined, and the GELINA neutron time-of-flight facility of the IRMM (Geel, Belgium) where strong resonances were observed in the keV region.

  5. MoS{sub 2}@ZnO nano-heterojunctions with enhanced photocatalysis and field emission properties

    SciTech Connect (OSTI)

    Tan, Ying-Hua; Yu, Ke, E-mail: yk5188@263.net; Li, Jin-Zhu; Fu, Hao; Zhu, Zi-Qiang [Key Laboratory of Polar Materials and Devices (Ministry of Education of China), Department of Electronic Engineering, East China Normal University, Shanghai 200241 (China)

    2014-08-14T23:59:59.000Z

    The molybdenum disulfide (MoS{sub 2})@ZnO nano-heterojunctions were successfully fabricated through a facile three-step synthetic process: prefabrication of the ZnO nanoparticles, the synthesis of MoS{sub 2} nanoflowers, and the fabrication of MoS{sub 2}@ZnO heterojunctions, in which ZnO nanoparticles were uniformly self-assembled on the MoS{sub 2} nanoflowers by utilizing polyethyleneimine as a binding agent. The photocatalytic activities of the composite samples were evaluated by monitoring the photodegradation of methylene blue (MB). Compared with pure MoS{sub 2} nanoflowers, the composites show higher adsorption capability in dark and better photocatalytic efficiency due to the increased specific surface area and improved electron-hole pair separation. After irradiation for 100?min, the remaining MB in solution is about 7.3%. Moreover, the MoS{sub 2}@ZnO heterojunctions possess enhanced field emission properties with lower turn-on field of 3.08?V ?m{sup ?1}and lower threshold field of 6.9?V ?m{sup ?1} relative to pure MoS{sub 2} with turn-on field of 3.65?V ?m{sup ?1} and threshold field of 9.03?V ?m{sup ?1}.

  6. Chemical interaction of B{sub 4}C, B, and C with Mo/Si layered structures

    SciTech Connect (OSTI)

    Rooij-Lohmann, V. I. T. A. de; Veldhuizen, L. W.; Zoethout, E.; Yakshin, A. E.; Kruijs, R. W. E. van de [FOM Institute for Plasma Physics Rijnhuizen, P.O. Box 1207, 3430 BE Nieuwegein (Netherlands); Thijsse, B. J. [Department of Materials Science and Engineering, Delft University of Technology, Mekelweg 2, 2628 CD Delft (Netherlands); Gorgoi, M.; Schaefers, F. [Helmholtz-Zentrum Berlin fuer Materialien und Energie GmbH, BESSY II, Albert-Einstein Strasse 15, 12489 Berlin (Germany); Bijkerk, F. [FOM Institute for Plasma Physics Rijnhuizen, P.O. Box 1207, 3430 BE Nieuwegein (Netherlands); MESA Institute for Nanotechnology, University of Twente, P.O. Box 217, 7500 AE Enschede (Netherlands)

    2010-11-15T23:59:59.000Z

    To enhance the thermal stability, B{sub 4}C diffusion barrier layers are often added to Mo/Si multilayer structures for extreme ultraviolet optics. Knowledge about the chemical interaction between B{sub 4}C and Mo or Si, however is largely lacking. Therefore, the chemical processes during annealing up to 600 deg. C of a Mo/B{sub 4}C/Si layered structure have been investigated in situ with hard x-ray photoelectron spectroscopy and ex situ with depth profiling x-ray photoelectron spectroscopy. Mo/B/Si and Mo/C/Si structures have also been analyzed as reference systems. The chemical processes in these systems have been identified, with two stages being distinguished. In the first stage, B and C diffuse and react predominantly with Mo. MoSi{sub x} forms in the second stage. If the diffusion barrier consists of C or B{sub 4}C, a compound forms that is stable up to the maximum probed temperature and annealing time. We suggest that the diffusion barrier function of B{sub 4}C interlayers as reported in literature can be caused by the stability of the formed compound, rather than by the stability of B{sub 4}C itself.

  7. K-Ar Dates Of Hydrothermal Clays From Core Hole Vc-2B, Valles...

    Open Energy Info (EERE)

    Ar Dates Of Hydrothermal Clays From Core Hole Vc-2B, Valles Caldera, New Mexico And Their Relation To Alteration In A Large Hydrothermal System Jump to: navigation, search OpenEI...

  8. An Application of Augmented Reality (AR) in the Teaching of an Arc Welding Robot

    E-Print Network [OSTI]

    Chong, J. W. S.

    Augmented Reality (AR) is an emerging technology that utilizes computer vision methods to overlay virtual objects onto the real world scene so as to make them appear to co-exist with the real objects. Its main objective ...

  9. Apprentice Researchers The Apprentice Researchers (AR) program was awarded supplemental funding by NSF's EHR

    E-Print Network [OSTI]

    Bigelow, Stephen

    Apprentice Researchers The Apprentice Researchers (AR) program was awarded supplemental funding apprentices acquire scientific knowledge and lab skills while experiencing what real research in hopes to their peers, family, and mentors. Totals -Summers 1991 to 2008 Total #Apprentices % Apprentices All

  10. The science case for 37Ar as a monitor for underground nuclear explosions

    SciTech Connect (OSTI)

    Haas, Derek A.; Orrell, John L.; Bowyer, Ted W.; McIntyre, Justin I.; Miley, Harry S.; Aalseth, Craig E.; Hayes, James C.

    2010-06-04T23:59:59.000Z

    A new calculation of the production of 37Ar from nuclear explosion neutron interactions on 40Ca in a suite of common sub-surface materials (rock, etc) is presented. Even in mineral structures that are relatively low in Ca, the resulting 37Ar signature is large enough for detection in cases of venting or gaseous diffusion driven by barometric pumping. Field and laboratory detection strategies and projected sensitivities are presented.

  11. Le magn)sme ar)ficiel pour les gaz d'atomes froids Jean Dalibard

    E-Print Network [OSTI]

    Dalibard, Jean

    Le magné)sme ar)ficiel pour les gaz d'atomes froids Jean Dalibard Année 2013-14 Chaire Atomes et rayonnement Magné8sme ar8ficiel et interac8ons : condensats en rota8on #12;Magné8sme dans une assemblée de par8cule en interac8on

  12. Ionization satellites of the ArHe dimer

    SciTech Connect (OSTI)

    Miteva, Tsveta; Klaiman, Shachar; Gokhberg, Kirill [Theoretische Chemie, Physikalisch-Chemisches Institut, Universität Heidelberg, Im Neuenheimer Feld 229, D-69120 Heidelberg (Germany); Gromov, Evgeniy V., E-mail: Evgeniy.Gromov@pci.uni-heidelberg.de [Theoretische Chemie, Physikalisch-Chemisches Institut, Universität Heidelberg, Im Neuenheimer Feld 229, D-69120 Heidelberg (Germany); Laboratory of Quantum Chemistry, Computer Center, Irkutsk State University, K. Marks 1, 664003 Irkutsk (Russian Federation)

    2014-05-28T23:59:59.000Z

    Ionization satellites are key ingredients in the control of post ionization processes such as molecular dissociation and interatomic Coulombic decay. Here, using the high-level ab initio method of multi-reference configuration interaction up to triple excitations, we study the potential energy curves (PECs) of the ionization satellites of the ArHe dimer. With this model system, we demonstrate that the simple model used in alkaline earth metal and rare gas complexes to describe the satellites as a Rydberg electron moving on top of a dicationic core does not fully hold for the rare gas clusters. The more complex valence structure in the rare gas atom leads to the mixing of different electronic configurations of the dimer. This prevents one from assigning a single dicationic parent state to some of the ionization satellites. We further analyze the structure of the different PECs, demonstrating how the density of the Rydberg electron is reflected in the structure of the PEC wherever the simple model is applicable.

  13. Epitaxial growth of few-layer MoS2(0001) on FeS2{100}

    E-Print Network [OSTI]

    Liu, T.; Temprano, I.; King, D. A.; Driver, S. M.; Jenkins, S. J.

    2014-11-13T23:59:59.000Z

    ) or self-assembled monolayers have already shown promise in delivering high quality graphene.8 Few-layer MoS2 is most commonly obtained by top-down methods such as lithium intercalation, micro mechanical exfoliation, or liquid-phase exfoliation.2 Attempts... trilayers may be terminated by complete S layers, leading to S–Fe–S–S–Mo–S layering; in this scenario, the epitaxy is driven simply by van der Waals interactions between the layers. In principle, sourcing the S atoms in the MoS2 layer from the bulk FeS2...

  14. Photoresponse properties of large-area MoS{sub 2} atomic layer synthesized by vapor phase deposition

    SciTech Connect (OSTI)

    Luo, Siwei; Qi, Xiang, E-mail: xqi@xtu.edu.cn, E-mail: jxzhong@xtu.edu.cn; Ren, Long; Hao, Guolin; Fan, Yinping; Liu, Yundan; Han, Weijia; Zang, Chen; Li, Jun; Zhong, Jianxin, E-mail: xqi@xtu.edu.cn, E-mail: jxzhong@xtu.edu.cn [Hunan Key Laboratory for Micro-Nano Energy Materials and Devices, People's Republic of China Laboratory for Quantum Engineering and Micro-Nano Energy Technology, and Faculty of Materials and Optoelectronic Physics, Xiangtan University, Hunan 411105 (China)

    2014-10-28T23:59:59.000Z

    Photoresponse properties of a large area MoS{sub 2} atomic layer synthesized by vapor phase deposition method without any catalyst are studied. Scanning electron microscopy, atomic force microscopy, Raman spectrum, and photoluminescence spectrum characterizations confirm that the two-dimensional microstructures of MoS{sub 2} atomic layer are of high quality. Photoelectrical results indicate that the as-prepared MoS{sub 2} devices have an excellent sensitivity and a good reproducibility as a photodetector, which is proposed to be ascribed to the potential-assisted charge separation mechanism.

  15. Hanford Site's Data Packages in the Administrative Record (AR) and Public Information Repository (PIR)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    In 1989, the Department of Energy joined with the Washington State Department of Ecology and the U.S. Environmental Protection Agency in signing the Hanford Federal Facility Agreement and Consent Order more commonly known as the Tri-Party Agreement (TPA). The TPA outlines legally enforceable milestones for Hanford cleanup over the next several decades. The AR is the body of documents and information that is considered or relied upon to arrive at a final decision for remedial action or hazardous waste management. An AR is established for each operable unit (OU); treatment, storage, or disposal unit (TSD); or Expedited Response Action (ERA) group and will contain all documents having information considered in arriving at a Record of Decision or permit. Documents become part of the AR after they have been designated as an AR by the TPA or after EPA, DOE, or other official parties have identified a document or set of documents for inclusion. Furthermore, AR documents are to be kept in a Public Information Repository (PIR).Thousands of data packages that support the AR documents are available to the public in the Hanford PIR.

  16. Structure of Co-Mo/UPSILON-Al/sub 7/O/sub 3/ catalysts and relationship to HDS and hydrogenation activity. [Hydrodesulfurization (HDS)

    SciTech Connect (OSTI)

    Bennet, B.A. (Imperial Coll., London, England); Chadwick, D.; Jawahery, A.R.; Breysse, M.; Vrinat, M.

    1982-09-01T23:59:59.000Z

    From Mossbauer spectroscopy studies of catalysts of typical industrial compositions and activity measurements it was shown that catalysts containing the ''Co-Mo-S'' phase have relatively higher hydrodesulfurization (HDS) activities. It was also found that the use of Co in the first impregnation step favored the formation of Co/sub 9/S/sub 8/ (in addition to Co in alumina), while the reverse impregnation order produced mainly the ''Co-Mo-S'' phase. Avoiding Co/sub 3/O/sub 4/ formation in the oxide precursor was important for the formation of the ''Co-Mo-S'' phase and this was achieved by the impregnation of Mo before Co. There was also evidence that when Co was used in the second impregnation step, there was significant Mo, Co interaction. This interaction my produce a CoMo surface phase which is disordered and well dispersed and sulfides to the ''Co-Mo-S'' phase. (JMT)

  17. AMoRE: Collaboration for searches for the neutrinoless double-beta decay of the isotope of {sup 100}Mo with the aid of {sup 40}Ca{sup 100}MoO{sub 4} as a cryogenic scintillation detector

    SciTech Connect (OSTI)

    Khanbekov, N. D., E-mail: xanbekov@gmail.com [Institute of Theoretical and Experimental Physics (Russian Federation)

    2013-09-15T23:59:59.000Z

    The AMoRE (Advanced Mo based Rare process Experiment) Collaboration is planning to employ {sup 40}Ca{sup 100}MoO{sub 4} single crystals as a cryogenic Scintillation detector for studying the neutrinoless double-beta decay of the isotope {sup 100}Mo. A simultaneous readout of phonon and scintillation signals is performed in order to suppress the intrinsic background. The planned sensitivity of the experiment that would employ 100 kg of {sup 40}Ca{sup 100}MoO{sub 4} over five years of data accumulation would be T{sub 1/2}{sup 0{nu}} = 3 Multiplication-Sign 10{sup 26} yr, which corresponds to values of the effective Majorana neutrino mass in the range of Left-Pointing-Angle-Bracket m{sub {nu}} Right-Pointing-Angle-Bracket {approx} 0.02-0.06 eV.

  18. Brittle Fracture in a 50Mo-50Re alloy in static tensile testing

    SciTech Connect (OSTI)

    Xu, Jianhui [University of Kentucky, Lexington; Kenik, Edward A [ORNL; Zhai, Tongguang [University of Kentucky, Lexington

    2008-01-01T23:59:59.000Z

    Tensile tests were conducted on 50Mo-50Re alloys, in fully-recrystallized and recovery heat-treated conditions respectively, at a very low strain rate of 10-6 s-1 and room temperature in air. It was found that both these alloys exhibited predominantly cleavage fracture with significant intergranular secondary cracking, compared to the predominantly ductile fracture found in the alloys at a higher strain rate. Cracks were often initiated at grain boundary triple junctions at the low strain rate. Electron back scatter diffraction (EBSD) measurements revealed significantly high misorientation gradients at grain boundaries, especially in the vicinity of some grain boundary triple junctions in the deformed alloys. Transmission electron microscopic (TEM) results verified the existence of significant misorientation taking place at grain boundaries in these alloys. Stress-assisted dynamic embrittlement, possibly due to trace interstitials, was the possible cause for the occurrence of brittle fracture in the 50Mo-50Re alloys at the low strain rate.

  19. Spectroscopy of Double-Beta and Inverse-Beta Decays from 100Mo for Neutrinos

    E-Print Network [OSTI]

    H. Ejiri; J. Engel; R. Hazama; P. Krastev; N. Kudomi; R. G. H. Robertson

    2000-05-15T23:59:59.000Z

    Spectroscopic studies of two beta-rays from 100Mo are shown to be of potential interest for investigating both the Majorana neutrino mass by neutrinoless double beta-decay and low energy solar neutrino's by inverse beta-decay. With a multi-ton 100Mo detector, coincidence studies of correlated beta-beta from neutrinoless double beta-decay, together with the large Q value, permit identification of the neutrino-mass term with a sensitivity of ~ 0.03 eV. Correlation studies of the inverse beta and the successive beta-decay of 100Tc, together with the large capture rates for low energy solar neutrino's, make it possible to detect in realtime individual low energy solar neutrino in the same detector.

  20. Air damping of atomically thin MoS{sub 2} nanomechanical resonators

    SciTech Connect (OSTI)

    Lee, Jaesung; Wang, Zenghui; Feng, Philip X.-L., E-mail: philip.feng@case.edu [Department of Electrical Engineering and Computer Science, Case School of Engineering, Case Western Reserve University, 10900 Euclid Avenue, Cleveland, Ohio 44106 (United States); He, Keliang; Shan, Jie [Department of Physics, College of Arts and Sciences, Case Western Reserve University, 10900 Euclid Avenue, Cleveland, Ohio 44106 (United States)

    2014-07-14T23:59:59.000Z

    We report on experimental measurement of air damping effects in high frequency nanomembrane resonators made of atomically thin molybdenum disulfide (MoS{sub 2}) drumhead structures. Circular MoS{sub 2} nanomembranes with thickness of monolayer, few-layer, and multi-layer up to ?70?nm (?100 layers) exhibit intriguing pressure dependence of resonance characteristics. In completely covered drumheads, where there is no immediate equilibrium between the drum cavity and environment, resonance frequencies and quality (Q) factors strongly depend on environmental pressure due to bulging of the nanomembranes. In incompletely covered drumheads, strong frequency shifts due to compressing-cavity stiffening occur above ?200?Torr. The pressure-dependent Q factors are limited by free molecule flow (FMF) damping, and all the mono-, bi-, and tri-layer devices exhibit lower FMF damping than thicker, conventional devices do.

  1. Improved performance of U-Mo dispersion fuel by Si addition in Al matrix.

    SciTech Connect (OSTI)

    Kim, Y S; Hofman, G L [Nuclear Engineering Division

    2011-06-01T23:59:59.000Z

    The purpose of this report is to collect in one publication and fit together work fragments presented in many conferences in the multi-year time span starting 2002 to the present dealing with the problem of large pore formation in U-Mo/Al dispersion fuel plates first observed in 2002. Hence, this report summarizes the excerpts from papers and reports on how we interpreted the relevant results from out-of-pile and in-pile tests and how this problem was dealt with. This report also provides a refined view to explain in detail and in a quantitative manner the underlying mechanism of the role of silicon in improving the irradiation performance of U-Mo/Al.

  2. Oxidation Behavior and Chlorination Treatment to Improve Oxidation Resistance of Nb-Mo-Si-B Alloys

    SciTech Connect (OSTI)

    Vikas Behrani

    2004-12-19T23:59:59.000Z

    This thesis is written in an alternate format. The thesis is composed of a general introduction, two original manuscripts, and a general conclusion. References cited within each chapter are given at the end of each chapter. The general introduction starts with the driving force behind this research, and gives an overview of previous work on boron doped molybdenum silicides, Nb/Nb{sub 5}Si{sub 3} composites, boron modified niobium silicides and molybdenum niobium silicides. Chapter 2 focuses on the oxidation behavior of Nb-Mo-Si-B alloys. Chapter 3 contains studies on a novel chlorination technique to improve the oxidation resistance of Nb-Mo-Si-B alloys. Chapter 4 summarizes the important results in this study.

  3. Fission induced swelling and creep of U–Mo alloy fuel

    SciTech Connect (OSTI)

    Yeon Soo Kim; G. L. Hofman; J. S. Cheon; A. B. Robinson; D. M. Wachs

    2013-06-01T23:59:59.000Z

    Tapering of U–Mo alloy fuel at the end of plates is attributed to lateral mass transfer by fission induced creep, by which fuel mass is relocated away from the fuel end region where fission product induced fuel swelling is in fact the highest. This mechanism permits U–Mo fuel to achieve high burnup by effectively relieving stresses at the fuel end region, where peak stresses are otherwise expected because peak fission product induced fuel swelling occurs there. ABAQUS FEA was employed to examine whether the observed phenomenon can be simulated using physical–mechanical data available in the literature. The simulation results obtained for several plates with different fuel fabrication and loading scheme showed that the measured data were able to be simulated with a reasonable creep rate coefficient. The obtained creep rate constant lies between values for pure uranium and MOX, and is greater than all other ceramic uranium fuels.

  4. Induced codeposition. 1: An experimental investigation of Ni-Mo alloys

    SciTech Connect (OSTI)

    Podlaha, E.J.; Landolt, D. [Ecole Polytechnique Federale de Lausanne (Switzerland)

    1996-03-01T23:59:59.000Z

    The electrodeposition of nickel-molybdenum alloys was studied on rotating cylinder electrodes. The current density, electrode rotation rate, electrolyte temperature, and species concentrations were shown to influence alloy composition. The mass-transport limiting species were identified for different operating conditions and electrolyte compositions in order to study the rate-limiting steps of induced codeposition. If the concentration of nickel in the electrolyte was much larger than that of molybdate the molybdenum content in the alloy increased with rotation rate. On the other hand, if the concentration of molybdate in the electrolyte was larger than that of nickel the alloy composition was found to be independent of rotation rate. These results were applied to the deposition of compositionally modulated Ni-Mo alloys exhibiting larger periodic variations in Mo concentration than hitherto reported.

  5. Phase transitions in K-doped MoO{sub 2}

    SciTech Connect (OSTI)

    Alves, L. M. S., E-mail: leandro-fisico@hotmail.com; Lima, B. S. de; Santos, C. A. M. dos [Departamento de Engenharia de Materiais, Escola de Engenharia de Lorena-USP, Lorena, São Paulo 12602-810 (Brazil); Rebello, A.; Masunaga, S. H.; Neumeier, J. J. [Department of Physics, Montana State University, P.O. Box 173840, Bozeman, Montana 59717-3840 (United States); Leão, J. B. [NIST Center for Neutron Research, National Institute of Standards and Technology, 100 Bureau Dr. MS 6102, Gaithersburg, Maryland 20899-6102 (United States)

    2014-05-28T23:59:59.000Z

    K{sub 0.05}MoO{sub 2} has been studied by x-ray and neutron diffractometry, electrical resistivity, magnetization, heat capacity, and thermal expansion measurements. The compound displays two phase transitions, a first-order phase transition near room temperature and a second-order transition near 54?K. Below the transition at 54?K, a weak magnetic anomaly is observed and the electrical resistivity is well described by a power-law temperature dependence with exponent near 0.5. The phase transitions in the K-doped MoO{sub 2} compound have been discussed for the first time using neutron diffraction, high resolution thermal expansion, and heat capacity measurements as a function of temperature.

  6. arXiv:0802.3463v1[nucl-th]23Feb2008 Nuclear astrophysics from direct reactions

    E-Print Network [OSTI]

    Bertulani, Carlos A. - Department of Physics and Astronomy, Texas A&M University

    , and energy production in stars. A. Nuclear reaction rates Low energy nuclear astrophysics requires the knowl Be(p, ) 8 B plays a major role for the production of high energy neutrinos from the -decay of 8 B Department of Physics, Texas A&M University, Commerce, TX 75429, USA Accurate nuclear reaction rates

  7. LEXICAL DECISION IN A PHONOLOGICALLY SHALLOW ORTHOGRAPHY* G Lukatela+, Do Popadic+, P. Ognjenovic+, and Mo To Turvey++

    E-Print Network [OSTI]

    +, and Mo To Turvey++ Abstracto The Serbo-Croatian language is written in two alphabets, Roman and Cyrillic shallow writing systems of Serbo-Croatian, lex ical decision proceeds with reference to the phonology

  8. Performance of ZnMoO4 crystal as cryogenic scintillating bolometer to search for double beta decay of molybdenum

    E-Print Network [OSTI]

    L. Gironi; C. Arnaboldi; J. W. Beeman; O. Cremonesi; F. A. Danevich; V. Ya. Degoda; L. I. Ivleva; L. L. Nagornaya; M. Pavan; G. Pessina; S. Pirro; V. I. Tretyak; I. A. Tupitsyna

    2010-10-01T23:59:59.000Z

    Zinc molybdate (ZnMoO4) single crystals were grown for the first time by the Czochralski method and their luminescence was measured under X ray excitation in the temperature range 85-400 K. Properties of ZnMoO4 crystal as cryogenic low temperature scintillator were checked for the first time. Radioactive contamination of the ZnMoO4 crystal was estimated as <0.3 mBq/kg (228-Th) and 8 mBq/kg (226-Ra). Thanks to the simultaneous measurement of the scintillation light and the phonon signal, the alpha particles can be discriminated from the gamma/beta interactions, making this compound extremely promising for the search of neutrinoless Double Beta Decay of 100-Mo. We also report on the ability to discriminate the alpha-induced background without the light measurement, thanks to a different shape of the thermal signal that characterizes gamma/beta and alpha particle interactions.

  9. High yield production of inorganic graphene-like materials (MoS?, WS?, BN) through liquid exfoliation testing key parameters

    E-Print Network [OSTI]

    Pu, Fei, S.B. Massachusetts Institute of Technology

    2012-01-01T23:59:59.000Z

    Inorganic graphene-like materials such as molybdenum disulfide (MoS?), tungsten sulfide (WS?), and boron nitride (BN) are known to have electronic properties. When exfoliated into layers and casted onto carbon nanofilms, ...

  10. Two photon absorption and its saturation of WS2 and MoS2 monolayer and few-layer films

    E-Print Network [OSTI]

    Zhang, Saifeng; McEvoy, Niall; O'Brien, Maria; Winters, Sinéad; Berner, Nina C; Yim, Chanyoung; Zhang, Xiaoyan; Chen, Zhanghai; Zhang, Long; Duesberg, Georg S; Wang, Jun

    2015-01-01T23:59:59.000Z

    The optical nonlinearity of WS2, MoS2 monolayer and few-layer films was investigated using the Z-scan technique with femtosecond pulses from the visible to the near infrared. The dependence of nonlinear absorption of the WS2 and MoS2 films on layer number and excitation wavelength was studied systematically. WS2 with 1~3 layers exhibits a giant two-photon absorption (TPA) coefficient. Saturation of TPA for WS2 with 1~3 layers and MoS2 with 25~27 layers was observed. The giant nonlinearity of WS2 and MoS2 is attributed to two dimensional confinement, a giant exciton effect and the band edge resonance of TPA.

  11. US WSC TX Site Consumption

    U.S. Energy Information Administration (EIA) Indexed Site

    an average of 77 million Btu per year, about 14% less than the U.S. average. * Average electricity consumption per Texas home is 26% higher than the national average, but...

  12. College TX 71843-25000

    E-Print Network [OSTI]

    D. A., Polymer 19(1978) 1008. L—8 JOURNAL DE PHYSIQUE * LET'I'RFS No l. 1976. [14] HUANG, Y. Y., FRIEDMAN, E. A., ANDREWS, R. D. and HART_ i,.

  13. ~txF74.ptx

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33Frequently20,000 Russian Nuclearand Characterization ofC u r r e n t IENERGY'S CONTRACTS WITH +

  14. ~tx22C0.ptx

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual Siteof Energy 2,AUDIT REPORT Americium/Curium Vitrification Project At-234-4433 Neal R.

  15. Quantitative Prediction of Surface Segregation in Bimetallic Pt-MAlloy Nanoparticles (M=Ni, Re, Mo)

    SciTech Connect (OSTI)

    Wang, Guofeng; Van Hove, Michel A.; Ross, Phil N.; Baskes,Michael I.

    2005-06-20T23:59:59.000Z

    This review addresses the issue of surface segregation inbimetallic alloy nanoparticles, which are relevant to heterogeneouscatalysis, in particular for electro-catalysts of fuel cells. We describeand discuss a theoretical approach to predicting surface segregation insuch nanoparticles by using the Modified Embedded Atom Method and MonteCarlo simulations. In this manner it is possible to systematicallyexplore the behavior of such nanoparticles as a function of componentmetals, composition, and particle size, among other variables. We choseto compare Pt75Ni25, Pt75Re25, and Pt80Mo20 alloys as example systems forthis discussion, due to the importance of Pt in catalytic processes andits high-cost. It is assumed that the equilibrium nanoparticles of thesealloys have a cubo-octahedral shape, the face-centered cubic lattice, andsizes ranging from 2.5 nm to 5.0 nm. By investigating the segregation ofPt atoms to the surfaces of the nanoparticles, we draw the followingconclusions from our simulations at T= 600 K. (1) Pt75Ni25 nanoparticlesform a surface-sandwich structure in which the Pt atoms are stronglyenriched in the outermost and third layers while the Ni atoms areenriched in the second layer. In particular, a nearly pure Pt outermostsurface layer can be achieved in those nanoparticles. (2) EquilibriumPt75Re25 nanoparticles adopt a core-shell structure: a nearly pure Ptshell surrounding a more uniform Pt-Re core. (3) In Pt80Mo20nanoparticles, the facets are fully occupied by Pt atoms, the Mo atomsonly appear at the edges and vertices, and the Pt and Mo atoms arrangethemselves in an alternating sequence along the edges and vertices. Oursimulations quantitatively agree with previous experimental andtheoretical results for the extended surfaces of Pt-Ni, Pt-Re, and Pt-Moalloys. We further discuss the reasons for the different types of surfacesegregation found in the different alloys, and some of theirimplications.

  16. Co-Rolled U10Mo/Zirconium-Barrier-Layer Monolithic Fuel Foil Fabrication Process

    SciTech Connect (OSTI)

    G. A. Moore; M. C. Marshall

    2010-01-01T23:59:59.000Z

    Integral to the current UMo fuel foil processing scheme being developed at Idaho National Laboratory (INL) is the incorporation of a zirconium barrier layer for the purpose of controlling UMo-Al interdiffusion at the fuel-meat/cladding interface. A hot “co-rolling” process is employed to establish a ~25-µm-thick zirconium barrier layer on each face of the ~0.3-mm-thick U10Mo fuel foil.

  17. An internship with San Tomas hunting camp Freeport-McMoRan, Inc. 

    E-Print Network [OSTI]

    Huggins, J. Grant

    1986-01-01T23:59:59.000Z

    An Internship with San Tomas Hunting Camp Freeport~NoRan, Inc. : A PRCFESSIQRAL PAPER by J. Grant Huggine Submitted to the College of Agriculture of Texas AN University in Rmrtial fulfillment of the requirements for the degree of NASTER GF... AGRICULTURE December 1986 Najor Subject: Wildlife Science Department of Wildife and Fisheries Sciences An Internship with San Tomas Hunting Camp Fr eeport-McMoRan, Inc. by J. Grant Huggins Approved as to style and content by: Wallace G. Klussmann...

  18. Continuing investigations for technology assessment of /sup 99/Mo production from LEU (low enriched Uranium) targets

    SciTech Connect (OSTI)

    Vandergrift, G.F.; Kwok, J.D.; Marshall, S.L.; Vissers, D.R.; Matos, J.E.

    1987-01-01T23:59:59.000Z

    Currently much of the world's supply of /sup 99m/Tc for medical purposes is produced from /sup 99/Mo derived from the fissioning of high enriched uranium (HEU). The need for /sup 99m/Tc is continuing to grow, especially in developing countries, where needs and national priorities call for internal production of /sup 99/Mo. This paper presents the results of our continuing studies on the effects of substituting low enriched Uranium (LEU) for HEU in targets for the production of fission product /sup 99/Mo. Improvements in the electrodeposition of thin films of uranium metal are reported. These improvements continue to increase the appeal for the substitution of LEU metal for HEU oxide films in cylindrical targets. The process is effective for targets fabricated from stainless steel or hastaloy. A cost estimate for setting up the necessary equipment to electrodeposit uranium metal on cylindrical targets is reported. Further investigations on the effect of LEU substitution on processing of these targets are also reported. Substitution of uranium silicides for the uranium-aluminum alloy or uranium aluminide dispersed fuel used in other current target designs will allow the substitution of LEU for HEU in these targets with equivalent /sup 99/Mo-yield per target and no change in target geometries. However, this substitution will require modifications in current processing steps due to (1) the insolubility of uranium silicides in alkaline solutions and (2) the presence of significant quantities of silicate in solution. Results to date suggest that both concerns can be handled and that substitution of LEU for HEU can be achieved.

  19. AutoMoDe - Model-Based Development of Automotive Software

    E-Print Network [OSTI]

    Ziegenbein, Dirk; Freund, Ulrich; Bauer, Andreas; Romberg, Jan; Schatz, Bernhard

    2011-01-01T23:59:59.000Z

    This paper describes first results from the AutoMoDe (Automotive Model-Based Development) project. The overall goal of the project is to develop an integrated methodology for model-based development of automotive control software, based on problem-specific design notations with an explicit formal foundation. Based on the existing AutoFOCUS framework, a tool prototype is being developed in order to illustrate and validate the key elements of our approach.

  20. Mo-Al{sub 2}O{sub 3} cermet research and development

    SciTech Connect (OSTI)

    Glass, S.J.; Monroe, S.L.; Stephens, J.J.; Moore, R.H. [and others

    1997-08-01T23:59:59.000Z

    This report describes the results to date of a program that was initiated to predict and measure residual stresses in Mo-Al{sub 2}O{sub 3} cermet-containing components and to develop new materials and processes that would lead to the reduction or elimination of the thermal mismatch stresses. The period of performance includes work performed CY95-97. Excessive thermal mismatch stresses had produced cracking in some cermet-containing neutron tube components. This cracking could lead to a loss of hermeticity or decreased tube reliability. Stress predictions were conducted using finite element models of the various components, along with the thermal coefficient of expansion (CTE), Young`s modulus, and strength properties. A significant portion of the program focused on the property measurements for the existing cermet materials, processing conditions, and the measurement technique. The effects of differences in the properties on the predicted residual stresses were calculated for existing designs. Several potential approaches were evaluated for reducing the residual stresses and cracking in cermet-containing parts including reducing the Mo content of the cermet, substituting a ternary alloy with a better CTE match with alumina, and substituting Nb for Mo. Processing modifications were also investigated for minimizing warpage that occurs during sintering due to differential sintering. These modifications include changing the pressing of the 94ND2 alumina and changing to a 96% alumina powder from AlSiMag.

  1. Effect of heat treatment on the mechanical properties of modified 9Cr-1Mo steel

    SciTech Connect (OSTI)

    Sultan F. Alsagabi; Triratna Shrestha; Indrajit Charit; Gabriel P. Potirniche; Michael V. Glazoff

    2014-09-01T23:59:59.000Z

    The modified 9Cr-1Mo steel (Grade 91) is a material of choice in fossil-fuel-fired power plants with increased efficiency, service life, and reduction in emission of greenhouse gases. It is also considered a prospective material for the Next Generation Nuclear Power Plant for application in reactor pressure vessels at temperatures up to 650°C. In this paper, heat treatment of the modified 9Cr-1Mo steel was studied by normalizing and tempering the steel at various temperatures and times, with the ultimate goal of improving its creep resistance and optimizing material hardness. The microstructural evolution of the heat treated steels was correlated with the differential scanning calorimetric results. Optical microscopy, scanning and transmission electron microscopy in conjunction with microhardness profiles and calorimetric plots were used to understand the evolution of microstructure including precipitate structures in modified 9Cr-1Mo steel and relate it to the mechanical behavior of the steel. Thermo- CalcTM calculations were used to support experimental work and provide guidance in terms of the precipitate stability and microstructural evolution. Furthermore, the carbon isopleth and temperature dependencies of the volume fraction of different precipitates were constructed. The predicted and experimentally observed results were found to be in good agreement.

  2. Evolution of collectivity along the N=Z line: The {sup 84}Mo nucleus

    SciTech Connect (OSTI)

    Bucurescu, D.; Ur, C.A.; Marginean, N.; Ionescu-Bujor, M.; Iordachescu, A.; Petrache, C.M. [Horia Hulubei National Institute of Physics and Nuclear Engineering, Bucharest (Romania)] [Horia Hulubei National Institute of Physics and Nuclear Engineering, Bucharest (Romania); Ur, C.A; Bazzacco, D.; Lunardi, S.; Petrache, C.M.; Brandolini, F.; Falconi, G.; Lenzi, S.M.; Venturelli, R. [Dipartimento di Fisica dellUniversita and INFN, Sezione di Padova, Padova (Italy)] [Dipartimento di Fisica dellUniversita and INFN, Sezione di Padova, Padova (Italy); Napoli, D.R.; de Angelis, G.; Gadea, A.; Foltescu, D.; Farnea, E.; Podolyak, Zs.; De Poli, M. [INFN, Laboratori Nazionali di Legnaro, Legnaro (Italy)] [INFN, Laboratori Nazionali di Legnaro, Legnaro (Italy); Rao, M.N. [Universidade de Sao Paolo, Sao Paolo, Brasil (Brazil)] [Universidade de Sao Paolo, Sao Paolo, Brasil (Brazil)

    1997-11-01T23:59:59.000Z

    The reaction {sup 58}Ni({sup 28}Si,2n{gamma}) at 90 MeV incident energy has been used to populate the N=Z nucleus {sup 84}Mo. The GASP array was used together with the ISIS Silicon ball, which allowed a subtraction of the charged particle channels in the {gamma}-{gamma} coincidences. The only known transition 2{sub 1}{sup +}{r_arrow}0{sub 1}{sup +} of 443.8 keV in {sup 84}Mo has been found in coincidence with a {gamma} ray of 673.5{plus_minus}0.4 keV which was assigned as the second (4{sub 1}{sup +}{r_arrow}2{sub 1}{sup +}) yrast transition. The behavior of the resulting yrast line indicates that {sup 84}Mo is a transitional nucleus. The correlation between the excitation energies of the 2{sub 1}{sup +} and 4{sub 1}{sup +} levels of the N=Z nuclei reveals a systematic deviation from the average behavior defined by all collective even-even nuclei. {copyright} {ital 1997} {ital The American Physical Society}

  3. Superconducting and structural properties of {delta}-MoC{sub 0.681} cubic molybdenum carbide phase

    SciTech Connect (OSTI)

    Sathish, C.I. [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan) [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan); Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Guo, Yanfeng, E-mail: GUO.Yanfeng@nims.go.jp [Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)] [Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Wang, Xia [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan) [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan); Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Tsujimoto, Yoshihiro [International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)] [International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Li, Jun [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan) [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan); Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Zhang, Shoubao [International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)] [International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Matsushita, Yoshitaka [Synchrotron X-ray Station at SPring-8, National Institute for Materials Science, 1-1-1 Kouto, Sayo-cho, Hyogo 679-5148 (Japan)] [Synchrotron X-ray Station at SPring-8, National Institute for Materials Science, 1-1-1 Kouto, Sayo-cho, Hyogo 679-5148 (Japan); Shi, Youguo; Tian, Huanfang; Yang, Huaixin; Li, Jianqi [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China)] [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Yamaura, Kazunari, E-mail: YAMAURA.Kazunari@nims.go.jp [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan) [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan); Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)

    2012-12-15T23:59:59.000Z

    The superconducting and lattice properties of {delta}-MoC{sub 0.681} were studied by electromagnetic measurements, synchrotron X-ray diffraction, neutron diffraction, and electron diffraction. The superconducting properties (T{sub c}=12 K) of {delta}-MoC{sub 0.681} were well characterized by a weak coupling model. The carbon vacancies present in the host cubic structure were found to be robust, although the material was synthesized from stoichiometric carbon and Mo powder under a high-pressure of 6 GPa. A thermodynamically-stable structure with ordered vacancies did not account for the robust features of {delta}-MoC{sub 0.681} since the vacancies are unlikely to be ordered in long range in the host structure. A model based on inherent phonon instability theoretically predicted for a stoichiometric MoC phase might be responsible for the robust features of {delta}-MoC{sub 0.681}. - Graphical Abstract: The cubic molybdenum carbide shows an excellent superconductivity with robust carbon vacancies. Inherent phonon instability theoretically predicted for a stoichiometric MoC phase might be responsible for the vacancies rather than a thermodynamically-stable structure with vacancies ordering. Highlights: Black-Right-Pointing-Pointer The 12 K superconductivity is well characterized by a weakly coupling model. Black-Right-Pointing-Pointer Carbon vacancies are robust and disordered in the cubic host structure. Black-Right-Pointing-Pointer Inherent phonon instability might be responsible for the robust carbon vacancies in {delta}-MoC{sub 0.681}.

  4. Low-frequency 1/f noise in MoS{sub 2} transistors: Relative contributions of the channel and contacts

    SciTech Connect (OSTI)

    Renteria, J.; Jiang, C. [Nano-Device Laboratory, Department of Electrical Engineering, Bourns College of Engineering, University of California – Riverside, Riverside, California 92521 (United States); Samnakay, R. [Materials Science and Engineering Program, Bourns College of Engineering, University of California – Riverside, Riverside, California 92521 (United States); Rumyantsev, S. L. [Department of Electrical, Computer, and Systems Engineering, Center for Integrated Electronics, Rensselaer Polytechnic Institute, Troy, New York 12180 (United States); Ioffe Physical-Technical Institute, St. Petersburg 194021 (Russian Federation); Goli, P.; Balandin, A. A., E-mail: balandin@ee.ucr.edu [Nano-Device Laboratory, Department of Electrical Engineering, Bourns College of Engineering, University of California – Riverside, Riverside, California 92521 (United States); Materials Science and Engineering Program, Bourns College of Engineering, University of California – Riverside, Riverside, California 92521 (United States); Shur, M. S. [Department of Electrical, Computer, and Systems Engineering, Center for Integrated Electronics, Rensselaer Polytechnic Institute, Troy, New York 12180 (United States)

    2014-04-14T23:59:59.000Z

    We report on the results of the low-frequency (1/f, where f is frequency) noise measurements in MoS{sub 2} field-effect transistors revealing the relative contributions of the MoS{sub 2} channel and Ti/Au contacts to the overall noise level. The investigation of the 1/f noise was performed for both as fabricated and aged transistors. It was established that the McWhorter model of the carrier number fluctuations describes well the 1/f noise in MoS{sub 2} transistors, in contrast to what is observed in graphene devices. The trap densities extracted from the 1/f noise data for MoS{sub 2} transistors, are 2?×?10{sup 19}?eV{sup ?1}cm{sup ?3} and 2.5?×?10{sup 20}?eV{sup ?1}cm{sup ?3} for the as fabricated and aged devices, respectively. It was found that the increase in the noise level of the aged MoS{sub 2} transistors is due to the channel rather than the contact degradation. The obtained results are important for the proposed electronic applications of MoS{sub 2} and other van der Waals materials.

  5. Traces on ion yields and electron spectra of Ar inner-shell hollow states with Free-Electron Lasers

    E-Print Network [OSTI]

    Wallis, A O G; Emmanouilidou, A

    2015-01-01T23:59:59.000Z

    We explore the formation by Free-Electron-Laser radiation of Ar hollow states with two or three inner-shell holes. We find that even charged Ar ion states can be more populated than odd charged Ar ion states. This depends on the pulse intensity and the number of energetically accessible inner- shell holes. Fully accounting for fine structure, we demonstrate that one electron spectra bare the imprints of Ar hollow states with two inner-shell holes. Moreover, we show how the Auger spectra of these hollow states can be extracted from two-electron coincidence spectra.

  6. A practical grinding-assisted dry synthesis of nanocrystalline NiMoO{sub 4} polymorphs for oxidative dehydrogenation of propane

    SciTech Connect (OSTI)

    Chen Miao, E-mail: chenmiao@sinochem.com [Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433 (China); Zhejiang Chemical Industry Research Institute, Hangzhou 310023 (China); Wu Jialing; Liu Yongmei [Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433 (China); Cao Yong, E-mail: yongcao@fudan.edu.cn [Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433 (China); Guo Li [Zhejiang Chemical Industry Research Institute, Hangzhou 310023 (China); He Heyong; Fan Kangnian [Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433 (China)

    2011-12-15T23:59:59.000Z

    A practical two-stage reactive grinding-assisted pathway waste-free and cost-effective for the synthesis of NiMoO{sub 4} has been successfully developed. It was demonstrated that proper design in synthetic strategy for grinding plays a crucial role in determining the ultimate polymorph of NiMoO{sub 4}. Specifically, direct grinding (DG) of MoO{sub 3} and NiO rendered {alpha}-NiMoO{sub 4} after annealing, whereas sequential grinding (SG) of the two independently pre-ground oxides followed by annealing generated {beta}-NiMoO{sub 4} solid solution. Characterizations in terms of Raman and X-ray diffraction suggest the creation of {beta}-NiMoO{sub 4} precursor in the latter alternative is the key aspect for the formation of {beta}-NiMoO{sub 4}. The DG-derived {alpha}-NiMoO{sub 4} tested by oxidative dehydrogenation of propane exhibited superior activity in contrast to its analog synthesized via conventional coprecipitation. It is suggested that the favorable chemical composition facilely obtained via grinding in contrast to that by coprecipitation was essential for achieving a more selective production of propylene. - Graphical Abstract: Grinding-assisted synthesis of NiMoO{sub 4} offers higher and more reproducible activities in contrast to coprecipitation for oxidative dehydrogenation of propane, and both {alpha}- and {beta}-NiMoO{sub 4} can be synthesized. Highlights: Black-Right-Pointing-Pointer NiMoO{sub 4} was prepared through grinding-assisted pathway. Black-Right-Pointing-Pointer Direct/sequential grinding rendered {alpha}-, {beta}-NiMoO{sub 4}, respectively. Black-Right-Pointing-Pointer Grinding-derived {alpha}-NiMoO{sub 4} showed high and reproducible activity for oxidative dehydrogenation of propane.

  7. Calibration of an ultra-low-background proportional counter for measuring {sup 37}Ar

    SciTech Connect (OSTI)

    Seifert, A.; Aalseth, C. E.; Bonicalzi, R. M.; Bowyer, T. W.; Day, A. R.; Fuller, E. S.; Haas, D. A.; Hayes, J. C.; Hoppe, E. W.; Humble, P. H.; Keillor, M. E.; LaFerriere, B. D.; Mace, E. K.; McIntyre, J. I.; Merriman, J. H.; Miley, H. S.; Myers, A. W.; Orrell, J. L.; Overman, C. T.; Panisko, M. E. [Pacific Northwest National Laboratory, 902 Battelle Boulevard, Richland, Washington, 99352 (United States)] [Pacific Northwest National Laboratory, 902 Battelle Boulevard, Richland, Washington, 99352 (United States); and others

    2013-08-08T23:59:59.000Z

    An ultra-low-background proportional counter design has been developed at Pacific Northwest National Laboratory (PNNL) using clean materials, primarily electro-chemically-purified copper. This detector, along with an ultra-low-background counting system (ULBCS), was developed to complement a new shallow underground laboratory (30 meters water-equivalent) at PNNL. The ULBCS design includes passive neutron and gamma shielding, along with an active cosmic-veto system. This system provides a capability for making ultra-sensitive measurements to support applications like age-dating soil hydrocarbons with {sup 14}C/{sup 3}H, age-dating of groundwater with {sup 39}Ar, and soil-gas assay for {sup 37}Ar to support On-Site Inspection (OSI). On-Site Inspection is a key component of the verification regime for the Comprehensive Nuclear-Test-Ban Treaty (CTBT). Measurements of radionuclides created by an underground nuclear explosion are valuable signatures of a Treaty violation. For OSI, the 35-day half-life of {sup 37}Ar, produced from neutron interactions with calcium in soil, provides both high specific activity and sufficient time for inspection before decay limits sensitivity. This work describes the calibration techniques and analysis methods developed to enable quantitative measurements of {sup 37}Ar samples over a broad range of proportional counter operating pressures. These efforts, along with parallel work in progress on gas chemistry separation, are expected to provide a significant new capability for {sup 37}Ar soil gas background studies.

  8. Transmission electron microscopy of RSP Fe/Cr/Mn/Mo/C alloy. [Fe-3 wt % Cr-2 wt % Mn-0. 5 wt % Mo, -0. 3 wt % C

    SciTech Connect (OSTI)

    Rayment, J.J.; Thomas, G.

    1982-03-01T23:59:59.000Z

    Rapid solidification processing (RSP) has been carried out on an Fe/Cr/Mn/Mo/C alloy using both electron-beam melting and piston-and-anvil techniques. Preliminary TEM results show RSP produces a refined duplex microstructure of ferrite and martensite, with a typical ferrite grain size of 0.50 - 3.0 microns. This RSP microstructure is significantly different from that observed in the conventionally austenitized and quenched alloys - a lath martensitic microstructure with thin films of retained interlath austenite. The morphological change produced by RSP is accompanied by an increase in hardness from 48R/sub c/ to 61R/sub c/ (approx. 480 to 720 VHN). It is intended to use electron-beam specimens to examine the potential beneficial effect of RSP upon sliding wear resistance and, by careful TEM studies, it will be possible to characterize the microstructure and its role in the hardness and wear behavior of the RSP alloy.

  9. Effects of Potassium Doping on CO Hydrogenation Over MoS2 Catalysts: A First-Principles Investigation

    SciTech Connect (OSTI)

    Andersen, Amity; Kathmann, Shawn M.; Lilga, Michael A.; Albrecht, Karl O.; Hallen, Richard T.; Mei, Donghai

    2014-07-01T23:59:59.000Z

    Periodic density functional theory calculations were performed to explore the effects of doping potassium (K) on the reactivity of CO hydrogenation to mixed higher alcohols over MoS2 catalysts. We found that the doped K species over the model MoS2(100) catalyst surface acts as a unique site for CO adsorption where either the K-C or the K-O bonding is allowed. The charge transfer from the K 4s electron to the conduction band of the MoS2(100) surface slightly enhances CO adsorption at the edge Mo sites. Due to the large electropositive nature, the presence of the surface K species, however, will hinder the dissociative adsorption of hydrogen. As a result, the doping K species drive CO hydrogenation selectivity toward the C2+ alcohols instead of hydrocarbons by increasing CO and decreasing hydrogen coverages on the MoS2 catalysts. To further elucidate the effect of doping K on the shifting of the selectivity toward CO hydrogenation, we calculated several key reaction steps leading to the H2CCO precursor formation, i.e., CO hydrogenation, the C-O bond scission and the C-C coupling (CH2+CO). The C-C coupling step is favorable for both the Mo and S edges. However, the undoped S edge has an overall more thermodynamically favorable reaction profile up to C-O scission compared with the Mo edge. This work was funded by a CRADA project (No. PNNL/297) with Range Fuels. The research was performed using EMSL, a national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory. The work involving the results analysis and mansucript writing was supported by the US Department of Energy, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences.

  10. Linking Education R&D Institutes and IndustryLinking Education, R&D Institutes and Industry l ifi E b l AR)(examples are more specific to Egypt , but many apply to AR)

    E-Print Network [OSTI]

    Abdou, Mohamed

    and Industry l ifi E b l AR)(examples are more specific to Egypt , but many apply to AR) Mohamed A. Abdou goals. The overall assessment indicates that: Egypt's current S&T system has failed to substantially impactEgypt s current S&T system has failed to substantially impact socio-economic development which

  11. Service Description Unit Rate in $ Invoice Description Database Administration (1 to 600 MB) MB/Month 0.550 DATABASE 1-600 MB/MO

    E-Print Network [OSTI]

    Service Description Unit Rate in $ Invoice Description Database Administration (1 to 600 MB) MB/Month 0.550 DATABASE 1-600 MB/MO Database Administration (601 to 950 MB) MB/Month 0.290 DATABASE 601-950 MB/MO Database Administration (951 to 3,000 MB) MB/Month 0.200 DATABASE 951-3,000 MB/MO Database

  12. Service Description Unit Rate in $ Invoice Description Database Administration (1 to 600 MB) MB/Month 0.500 DATABASE 1-600 MB/MO

    E-Print Network [OSTI]

    Service Description Unit Rate in $ Invoice Description Database Administration (1 to 600 MB) MB/Month 0.500 DATABASE 1-600 MB/MO Database Administration (601 to 950 MB) MB/Month 0.265 DATABASE 601-950 MB/MO Database Administration (951 to 3,000 MB) MB/Month 0.175 DATABASE 951-3,000 MB/MO Database

  13. Ion mass spectrometry investigations of the discharge during reactive high power pulsed and direct current magnetron sputtering of carbon in Ar and Ar/N{sub 2}

    SciTech Connect (OSTI)

    Schmidt, S.; Greczynski, G.; Jensen, J.; Hultman, L. [Thin Film Physics Div., Department of Physics (IFM), Linkoeping University, SE-581 83 (Sweden); Czigany, Zs. [Institute of Technical Physics and Materials Science, Research Centre for Natural Sciences, Hungarian Academy of Sciences, Konkoly Thege Miklos ut 29-33. H-1121 Budapest (Hungary)

    2012-07-01T23:59:59.000Z

    Ion mass spectrometry was used to investigate discharges formed during high power impulse magnetron sputtering (HiPIMS) and direct current magnetron sputtering (DCMS) of a graphite target in Ar and Ar/N{sub 2} ambient. Ion energy distribution functions (IEDFs) were recorded in time-averaged and time-resolved mode for Ar{sup +}, C{sup +}, N{sub 2}{sup +}, N{sup +}, and C{sub x}N{sub y}{sup +} ions. An increase of N{sub 2} in the sputter gas (keeping the deposition pressure, pulse width, pulse frequency, and pulse energy constant) results for the HiPIMS discharge in a significant increase in C{sup +}, N{sup +}, and CN{sup +} ion energies. Ar{sup +}, N{sub 2}{sup +}, and C{sub 2}N{sup +} ion energies, in turn, did not considerably vary with the changes in working gas composition. The HiPIMS process showed higher ion energies and fluxes, particularly for C{sup +} ions, compared to DCMS. The time evolution of the plasma species was analyzed for HiPIMS and revealed the sequential arrival of working gas ions, ions ejected from the target, and later during the pulse-on time molecular ions, in particular CN{sup +} and C{sub 2}N{sup +}. The formation of fullerene-like structured CN{sub x} thin films for both modes of magnetron sputtering is explained by ion mass-spectrometry results and demonstrated by transmission electron microscopy as well as diffraction.

  14. Electron-Transfer from H-2 and Ar to Stored Multiply Charged Argon Ions Produced by Synchrotron Radiation 

    E-Print Network [OSTI]

    Kravis, S. D.; Church, David A.; Johnson, B. M.; Meron, M.; Jones, K. W.; Levin, J. C.; Sellin, I. A.; Azuma, Y.; Berrahmansour, N.; Berry, H. G.; Druetta, M.

    1992-01-01T23:59:59.000Z

    -shell photoionization of Ar atoms, using broadband synchrotron x-ray radiation. K-electron removal resulted in vacancy cascading, yielding a distribution of argon-ion charge states peaked near Ar4+. The stored ion gas had an initial temperature near 480 K. The basic...

  15. Polymorphisms of the acid sensing histidine kinase gene arsS in Helicobacter pylori populations from anatomically distinct gastric sites

    E-Print Network [OSTI]

    Forsyth, Mark

    Polymorphisms of the acid sensing histidine kinase gene arsS in Helicobacter pylori populations 2012 Available online 30 August 2012 Keywords: Helicobacter pylori arsS Polymorphism Homopolymeric as environmental or host conditions change. Unusual among Helicobacter pylori phase variable or contingency genes

  16. Electron-Transfer from H-2 and Ar to Stored Multiply Charged Argon Ions Produced by Synchrotron Radiation

    E-Print Network [OSTI]

    Kravis, S. D.; Church, David A.; Johnson, B. M.; Meron, M.; Jones, K. W.; Levin, J. C.; Sellin, I. A.; Azuma, Y.; Berrahmansour, N.; Berry, H. G.; Druetta, M.

    1992-01-01T23:59:59.000Z

    -shell photoionization of Ar atoms, using broadband synchrotron x-ray radiation. K-electron removal resulted in vacancy cascading, yielding a distribution of argon-ion charge states peaked near Ar4+. The stored ion gas had an initial temperature near 480 K. The basic...

  17. Epitaxial TiN,,001... Grown and Analyzed In situ by XPS and UPS. II. Analysis of Ar

    E-Print Network [OSTI]

    Gall, Daniel

    Epitaxial TiN,,001... Grown and Analyzed In situ by XPS and UPS. II. Analysis of Ar¿ Sputter Etched and UPS were used to study epitaxial TiN 001 layers grown in situ which were Ar sputter etched. The films Host Material: epitaxial TiN(001) thin film sputter etched Instrument: Physical Electronics, Inc. 5400

  18. Excitation functions for the reactions of Ar^+ with CH4, CD4, and CH2D2

    E-Print Network [OSTI]

    Wyatt, J. R.; Strattan, L. W.; Chivalak, S.; Hierl, Peter M.

    1975-01-01T23:59:59.000Z

    Integral reaction cross sections as a function of initial translational energy (0.4–30 eV c.m.) are reported for isotopic variants of the exoergic ion?molecule reaction Ar++CH4 ? ArH++CH3. The excitation functions, which maximize at about 5 e...

  19. Ar dating of Apollo 12 regolith: Implications for the age of Copernicus and the source of nonmare materials

    E-Print Network [OSTI]

    40 Ar/39 Ar dating of Apollo 12 regolith: Implications for the age of Copernicus and the source; accepted in revised form 20 September 2006 Abstract Twenty-one 2­4 mm rock samples from the Apollo 12 and source of nonmare materials at the Apollo 12 site. Among the samples analyzed are: 2 felsites, 11 KREEP

  20. Martensitic transformation behaviors of rapidly solidified Ti–Ni–Mo powders

    SciTech Connect (OSTI)

    Kim, Yeon-wook, E-mail: ywk@kmu.ac.kr [Department of Advanced Materials, Keimyung University, 1000 Shindang-dong, Dalseo-gu, Daegu 704-701 (Korea, Republic of)] [Department of Advanced Materials, Keimyung University, 1000 Shindang-dong, Dalseo-gu, Daegu 704-701 (Korea, Republic of)

    2012-10-15T23:59:59.000Z

    For the fabrication of bulk near-net-shape shape memory alloys and porous metallic biomaterials, consolidation of Ti–Ni–Mo alloy powders is more useful than that of elemental powders of Ti, Ni and Mo. Ti{sub 50}Ni{sub 49.9}Mo{sub 0.1} shape memory alloy powders were prepared by gas atomization, and transformation temperatures and microstructures of those powders were investigated as a function of powder size. XRD analysis showed that the B2–R–B19 martensitic transformation occurred in powders smaller than 150 ?m. According to DSC analysis of the as-atomized powders, the B2–R transformation temperature (T{sub R}) of the 25–50 ?m powders was 18.4 °C. The T{sub R} decreased with increasing powder size, however, the difference in T{sub R} between 25–50 ?m powders and 100–150 ?m powders is only 1 °C. Evaluation of powder microstructures was based on SEM examination of the surface and the polished and etched powder cross sections and the typical images of the rapidly solidified powders showed cellular morphology. Porous cylindrical foams of 10 mm diameter and 1.5 mm length were fabricated by spark plasma sintering (SPS) at 800 °C and 5 MPa. Finally these porous TiNi alloy samples are heat-treated for 1 h at 850 °C, and then quenched in ice water. The bulk samples have 23% porosity and 4.6 g/cm{sup 3} density and their T{sub R} is 17.8 °C.

  1. Using Qualified Energy Conservation Bonds (QECBs) to Fund a Residential Energy Efficiency Loan Program: Case Study on Saint Louis County, MO

    E-Print Network [OSTI]

    Zimring, Mark

    2012-01-01T23:59:59.000Z

    2011 Using Qualified Energy Conservation Bonds (QECBs) toCounty, MO Qualified Energy Conservation Bonds (QECBs) arerange of qualified energy conservation projects. QECBs offer

  2. COMBATING THE PURPLE BOTANICAL PLAGUE: EVALUATION OF COLLETOTRICHUM GLOEOSPORIOIDES F. SP. MICONIAE FOR BIOLOGICAL CONTROL OF MICONIA CALVESCENS IN MO’OREA, FRENCH POLYNESIA

    E-Print Network [OSTI]

    Chen, Irene Y

    2009-01-01T23:59:59.000Z

    gloeosporioides, elevation, endophyte community, Mo’orea,occur upon contact: the endophyte fungus outcompeted theelevation gradient having 25 endophyte competition plates.

  3. Beta-decay properties of Zr and Mo neutron-rich isotopes

    E-Print Network [OSTI]

    P. Sarriguren; J. Pereira

    2010-06-08T23:59:59.000Z

    Gamow-Teller strength distributions, beta-decay half-lives, and beta-delayed neutron emission are investigated in neutron-rich Zr and Mo isotopes within a deformed quasiparticle random-phase approximation. The approach is based on a self-consistent Skyrme Hartree-Fock mean field with pairing correlations and residual separable particle-hole and particle-particle forces. Comparison with recent measurements of half-lives stresses the important role that nuclear deformation plays in the description of beta-decay properties in this mass region.

  4. Electronic structure of CdMoO{sub 4} using Compton scattering technique

    SciTech Connect (OSTI)

    Sharma, Khushboo, E-mail: khushboo.phy@gmail.com; Ahuja, B. L. [Department of Physics, University College of Science, M.L. Sukhadia University, Udaipur-313001 (India); Sahariya, Jagrati [Department of Physics, Manipal University, Jaipur-303007 (India)

    2014-04-24T23:59:59.000Z

    The first ever Compton profile of polycrystalline CdMoO{sub 4} has been measured using {sup 137}Cs spectrometer. The results are compared with theoretical Compton profiles deduced from free atom and linear combination of atomic orbitals (LCAO) methods. We have also computed the energy bands using density functional theory (DFT) within LCAO. The computed bands confirm the semiconducting behaviour of this compound. It is seen that the DFT theoretical profile (with local density approximation) gives a better agreement with the experimental Compton data than free atom Compton profile.

  5. FULL SIZE U-10MO MONOLITHIC FUEL FOIL AND FUEL PLATE FABRICATION-TECHNOLOGY DEVELOPMENT

    SciTech Connect (OSTI)

    G. A. Moore; J-F Jue; B. H. Rabin; M. J. Nilles

    2010-03-01T23:59:59.000Z

    Full-size U10Mo foils are being developed for use in high density LEU monolithic fuel plates. The application of a zirconium barrier layer too the foil is applied using a hot co-rolling process. Aluminum clad fuel plates are fabricated using Hot Isostatic Pressing (HIP) or a Friction Bonding (FB) process. An overview is provided of ongoing technology development activities, including: the co-rolling process, foil shearing/slitting and polishing, cladding bonding processes, plate forming, plate-assembly swaging, and fuel plate characterization. Characterization techniques being employed include, Ultrasonic Testing (UT), radiography, and microscopy.

  6. DOE - Office of Legacy Management -- St Louis Downtown Site - MO 02

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA group currentBradleyTableSelling Corp -K LeDowntown Site - MO 02 FUSRAP

  7. DOE - Office of Legacy Management -- St Louis University - MO 0-02

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA group currentBradleyTableSelling Corp -K LeDowntown Site - MO 02 FUSRAPSt Louis

  8. DOE - Office of Legacy Management -- United Nuclear Corp - MO 0-03

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA group currentBradleyTableSelling Corp -K LeDowntownUnited Nuclear Corp - MO 0-03

  9. Reply to the revised Comment [PRL 102, 139601; arXiv:0810.4791] on ''Dynamic Scaling of Non-Euclidean Interfaces''

    E-Print Network [OSTI]

    Carlos Escudero

    2009-06-05T23:59:59.000Z

    This is the Reply to the revised Comment [Phys. Rev. Lett. 102, 139601; arXiv:0810.4791] by Joachim Krug on our paper: C. Escudero, Phys. Rev. Lett. 100, 116101 (2008); arXiv:0804.1898.

  10. Single-crystal structure of vanadium-doped La{sub 2}Mo{sub 2}O{sub 9}

    SciTech Connect (OSTI)

    Alekseeva, O. A., E-mail: olalex@ns.crys.ras.ru; Antipin, A. M. [Russian Academy of Sciences, Shubnikov Institute of Crystallography (Russian Federation)] [Russian Academy of Sciences, Shubnikov Institute of Crystallography (Russian Federation); Gagor, A.; Pietraszko, A. [Polish Academy of Sciences, Trzebiatowski Institute of Low Temperature and Structure Research (Poland)] [Polish Academy of Sciences, Trzebiatowski Institute of Low Temperature and Structure Research (Poland); Novikova, N. E.; Sorokina, N. I. [Russian Academy of Sciences, Shubnikov Institute of Crystallography (Russian Federation)] [Russian Academy of Sciences, Shubnikov Institute of Crystallography (Russian Federation); Kharitonova, E. P.; Voronkova, V. I. [Moscow State University (Russian Federation)] [Moscow State University (Russian Federation)

    2013-11-15T23:59:59.000Z

    A high-precision X-ray diffraction study of single crystals of two compositions-La{sub 2}Mo{sub 1.78}V{sub 0.22}O{sub 8.89} and La{sub 2}Mo{sub 1.64}V{sub 0.36}O{sub 8.82}-was performed. In the vanadium-doped compounds, as in the structure of the metastable {beta}{sub ms} phase of pure La{sub 2}Mo{sub 2}O{sub 9}, the La and Mo atoms and one of the three oxygen atoms are displaced from the threefold axis, on which they are located in the high-temperature {beta} phase. The structure contains two partially occupied oxygen sites. It was shown that molybdenum atoms are partially replaced by vanadium atoms, which are not involved in the disordering, are located on the threefold axis, and are shifted toward one of the oxygen atoms. This is consistent with the temperature-induced changes in the structure of La{sub 2}Mo{sub 2}O{sub 9} and the changes in the properties of these crystals caused by the introduction of vanadium atoms into the structure.

  11. MO: ZL

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA group currentBradleyTableSelling7111AWell:F E ,"^ I ThisS11220Grand

  12. 916 IEEE TRANSACTIONS ON AUDIO, SPEECH, AND LANGUAGE PROCESSING, VOL. 19, NO. 4, MAY 2011 AR-GARCH in Presence of Noise: Parameter

    E-Print Network [OSTI]

    Cohen, Israel

    916 IEEE TRANSACTIONS ON AUDIO, SPEECH, AND LANGUAGE PROCESSING, VOL. 19, NO. 4, MAY 2011 AR-GARCH (VAD) based on the autoregressive-generalized autore- gressive conditional heteroscedasticity (AR-GARCH) model. The speech signal is modeled as an AR-GARCH process in the time domain, and the likelihood ratio

  13. IEEE TRANS. AUDIO, SPEECH AND LANGUAGE PROCESSING, VOL. XX, NO. Y, MONTH 2010 1 AR-GARCH in Presence of Noise: Parameter

    E-Print Network [OSTI]

    Cohen, Israel

    IEEE TRANS. AUDIO, SPEECH AND LANGUAGE PROCESSING, VOL. XX, NO. Y, MONTH 2010 1 AR-GARCH (VAD) based on the autoregressive-generalized autore- gressive conditional heteroscedasticity (AR-GARCH) model. The speech signal is modeled as an AR-GARCH process in the time domain, and the likelihood ratio

  14. arXiv:hep-ph/0306282v127Jun2003 Neutrino Physics: an Update

    E-Print Network [OSTI]

    Washington at Seattle, University of - Department of Physics, Electroweak Interaction Research Group

    arXiv:hep-ph/0306282v127Jun2003 Neutrino Physics: an Update Wick C. Haxtona and Barry R. Holsteina recent didactic survey of neutrino physics, including new results from the Sudbury Neutrino Observatory;1 Introduction Several years ago, we authored a paper in this journal entitled "Neutrino Physics," hereafter

  15. arXiv:astro-ph/0305066v16May2003 High Energy Photons, Neutrinos and

    E-Print Network [OSTI]

    Zhang, Bing

    arXiv:astro-ph/0305066v16May2003 High Energy Photons, Neutrinos and Gravitational Waves from Gamma-Ray. of Physics Pennsylvania State University University Park, PA 16802, USA 1 Introduction A new era in Gamma-ray Burst (GRB) research opened in 1991 with the launch of the Compton Gamma-Ray Observatory (CGRO), whose

  16. arXiv:astro-ph/0009259v219Sep2000 How the Sun Shines

    E-Print Network [OSTI]

    Walter, Frederick M.

    arXiv:astro-ph/0009259v219Sep2000 How the Sun Shines John N. Bahcall What makes the sun shine? How does the sun produce the vast amount of energy necessary to support life on earth? These questions 1833 Treatise on Astronomy: The sun's rays are the ultimate source of almost every motion which takes

  17. arXiv:cond-mat/9707333v131Jul1997 Fingering Instability in Combustion

    E-Print Network [OSTI]

    Moses, Elisha

    arXiv:cond-mat/9707333v131Jul1997 Fingering Instability in Combustion O. Zik(1) , Z. Olami(2) and E quantitatively verify a model based on diffusion limited transport. Harnessing combustion is a basic element conflagrations is often determined by fundamental issues regarding the stability of combustion fronts. Although

  18. arXiv:astro-ph/0509571v119Sep2005 Gamma-Ray Burst Early Afterglows

    E-Print Network [OSTI]

    Zhang, Bing

    arXiv:astro-ph/0509571v119Sep2005 Gamma-Ray Burst Early Afterglows Bing Zhang Department of Physics's Swift Gamma-Ray Burst Explorer open a new era for the multi-wavelength study of the very early afterglow phase of gamma-ray bursts (GRBs). GRB early afterglow information is essential to explore the unknown

  19. MinErAl prEpArAtion EnginEEring

    E-Print Network [OSTI]

    Hartman, Chris

    MinErAl prEpArAtion EnginEEring College of Engineering and Mines Department of Mining ­ 36 credits The mineral preparation engineering program offers specialization in the processes used to concentrate target minerals and remove undesir- able material from mined ore. Interdisciplinary study

  20. Sudden Lifetime Drop Phenomena and their Effective Cures in PF-ring and PF-AR

    SciTech Connect (OSTI)

    Tanimoto, Yasunori; Honda, Tohru; Uchiyama, Takashi; Nogami, Takashi [Accelerator Laboratory, High Energy Accelerator Research Organization (KEK), 1-1 Oho, Tsukuba, Ibaraki 305-0801 (Japan)

    2010-06-23T23:59:59.000Z

    In PF-ring and PF-AR, sudden drops in the electron beam lifetime, which are attributed to dust trapping, were frequently observed after extensive renewals of the storage rings. The reduced-lifetime state sometimes lasts for a few hours, and the mitigation of this problem was strongly demanded for stable user operations. Since a major source of dust particles was thought to be a distributed ion pump (DIP), we attempted switching the DIPs off during user operations in both the rings. As a result, occurrence of the lifetime drops was almost completely suppressed during single-bunch mode in PF-ring, while the occurrence frequency was reduced by only 38% in PF-AR. We found that the lifetime drops were sometimes accompanied by a transient increase in the vacuum pressure at some discharge-prone devices. Based on the hypothesis that the harmful dust could be generated by an electric discharge in vacuum, we attempted the conditioning of these devices in PF-AR by storing 25% higher current than usual. By combination of the DIP-OFF operation and the high-current conditioning, the occurrence frequency of the lifetime drops in PF-AR was reduced by no less than 67%.

  1. Topographie de surfaces Si(111) aprs bombardement d'ions Ar+ et recuit thermique

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1161 Topographie de surfaces Si(111) après bombardement d'ions Ar+ et recuit thermique J. Fauré, A du recuit nécessaire, ainsi que sur la topographie de la surface obtenue, a été mise en évidence. La de retrouver la topographie de la surface initiale : même disposition et même densité des marches

  2. 6035 Hg(Ar) Lamp in 6058 Fiber Optic Accessory. Pencil Style Calibration Lamps

    E-Print Network [OSTI]

    Woodall, Jerry M.

    to that of the Hg(Ar) Lamp, which is the characteristic mercury line spectrum. Forced air-cooling (i.e. from of the handle for connection to the power supply. Table 1 Usable Wavelengths of Spectral Calibration Lamps (in.2 1079.8 1084.5 1114.3 Power Supplies; AC versus DC We offer different power supplies for different needs

  3. Spectroscopy, polarization and nonadiabatic dynamics of electronically excited Ba(Ar)n clusters: Theory and experiment

    E-Print Network [OSTI]

    Krylov, Anna I.

    Spectroscopy, polarization and nonadiabatic dynamics of electronically excited Ba(Ar)n clusters, France Received 13 September 1995; accepted 17 November 1995 Molecular Dynamics simulations using, a comprehensive picture of the excited state dynamics is given. It is found that upon excitation, energy

  4. arXiv:physics/000908727Sep2000 MEASURING AND CONTROLLING ENERGY SPREAD IN CEBAF

    E-Print Network [OSTI]

    arXiv:physics/000908727Sep2000 MEASURING AND CONTROLLING ENERGY SPREAD IN CEBAF G. A. Krafft, J spread from a CEBAF-type machine to be relatively small; the measured energy spread from CEBAF at 4 Ge, the various subsystems contributing to the energy spread of a CEBAF-type accel- erator are reviewed, as well

  5. Culture of Atlantic Salmon, Sa/roo sa/ar, in Puget Sound

    E-Print Network [OSTI]

    Culture of Atlantic Salmon, Sa/roo sa/ar, in Puget Sound JAMES L. MIGHELL Introduction Depletion streams. A pilot study conducted in Puget Sound, Wash., showed that Atlan- tic salmon brood stock could a feasibility study and pilot test in the Pacific Northwest (Puget Sound, Wash.) to rear Atlantic salmon from

  6. arXiv:astro-ph/0301495v124Jan2003 GAIA Spectroscopy, Science and Technology

    E-Print Network [OSTI]

    Gomboc, Andreja

    arXiv:astro-ph/0301495v124Jan2003 GAIA Spectroscopy, Science and Technology ASP Conference Series. and therefore the benefits of a large and highly accurate database on stellar rotation, obtained by GAIA and the effectivness of tidal energy dissipation. · Rotational velocity as an indicator of angular momentum of solar

  7. arXiv:hepex/0505096 Measurement of the Higgs Boson Mass

    E-Print Network [OSTI]

    ################ arXiv:hep­ex/0505096 v1 30 May 2005 Measurement of the Higgs Boson Mass for the measurement of the Higgs boson mass. An integrated luminosity of 500 fb 1 is assumed. For Higgs boson masses of 120, 150 and 180 GeV the uncertainty on the Higgs boson mass measurement is estimated to be 40, 65

  8. http://arXiv.org/physics/0507088 Teaching About Nature's Nuclear Reactors

    E-Print Network [OSTI]

    Learned, John

    http://arXiv.org/physics/0507088 Teaching About Nature's Nuclear Reactors J. Marvin Herndon reactors existed in uranium deposits on Earth long before Enrico Fermi built the first man-made nuclear reactors. The subject of planetocentric nuclear fission reactors can be a jumping off point for stimulating

  9. arXiv:hepph/0406301 NUHEP-TH/04-05

    E-Print Network [OSTI]

    arXiv:hep­ph/0406301 v1 27 Jun 2004 NUHEP-TH/04-05 Probing New Physics by Comparing Solar and Kam Road, Evanston, IL 60208, USA Carlos Pe~na-Garay School of Natural Sciences, Institute for Advanced Study, Einstein Drive, Princeton, NJ 08540, USA We explore whether KamLAND and solar data may end up

  10. arXiv draft On the mechanisms of precipitation of graphene on nickel thin

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    arXiv draft On the mechanisms of precipitation of graphene on nickel thin films L. Baraton1 (a) , Z. In the case of nickel, where carbon has a significant solubility, such a growth process includes at least two, we dissolve calibrated amounts of carbon in nickel films, using carbon ion implantation

  11. The titanium tris-anilide cation [Ti(N[[superscript t]Bu]Ar)[subscript 3

    E-Print Network [OSTI]

    Spinney, Heather A.

    This work explores the reduction of 4,4?-bipyridine using two equivalents of the titanium(III) complex Ti(N[[superscript t]Bu]Ar)[subscript 3] resulting in formation of a black, crystalline complex, (4,4?-bipy){Ti(N[[superscript ...

  12. The Navigation and Control technology inside the AR.Drone micro UAV

    E-Print Network [OSTI]

    is that it is a stabilized aerial platform, remotely controlled through a user-friendly graphical interface runningThe Navigation and Control technology inside the AR.Drone micro UAV Pierre-Jean Bristeau François, FRANCE Abstract: This paper exposes the Navigation and Control technology embedded in a recently com

  13. arXiv:astro-ph/0703364v227Aug2007 Electromagnetic dark energy

    E-Print Network [OSTI]

    Wright, Francis

    arXiv:astro-ph/0703364v227Aug2007 Electromagnetic dark energy Christian Beck School of MathematicalGill University, Montreal, Quebec, Canada (Dated: August 28, 2007) We introduce a new model for dark energy equations, or more generally with the existence of dark energy. The dark energy density consistent

  14. arXiv:astro-ph/0512327v27Mar2006 Laboratory tests on dark energy

    E-Print Network [OSTI]

    Beck, Christian

    arXiv:astro-ph/0512327v27Mar2006 Laboratory tests on dark energy Christian Beck School of the currently observed dark energy in the universe is completely unclear, and many different theoretical models co-exist. Nevertheless, if dark energy is produced by vac- uum fluctuations then there is a chance

  15. arXiv:gr-qc/0012068v119Dec2000 International Journal of Modern Physics D,

    E-Print Network [OSTI]

    Jantzen, Robert T.

    arXiv:gr-qc/0012068v119Dec2000 International Journal of Modern Physics D, c World Scientific of applications to black hole physics, culminating in the "membrane paradigm" for treating the black hole horizon2 and physics around black holes. Their approach to the integral version of Maxwell's equations is based

  16. arXiv:hepph/0610045v2 2006 ENERGY CONSERVATION and POMERON LOOPS

    E-Print Network [OSTI]

    Lunds Universitet,

    arXiv:hep­ph/0610045v2 31 Oct 2006 ENERGY CONSERVATION and POMERON LOOPS in HIGH ENERGY EVOLUTION@thep.lu.se We present a formalism which modi#12;es the Mueller Dipole Model such that it incorporates energy at the XLVI Cracow School of Theoretical Physics, May 27 - June 5 2006, Zakopane, Poland. (1) #12; 2 Emil

  17. arXiv:hep-ex/0408121v124Aug2004 Letter of Intent

    E-Print Network [OSTI]

    McDonald, Kirk

    of Silesia, Katowice, Poland A. Godley, S.R. Mishra, C. Rosenfeld, K. Wu University of South Carolina Institute for Nuclear Studies, Warsaw, Poland W. Dominik Warsaw University, Warsaw, Poland P.J. Doe, J Identification and Energy Resolution of The Liquid Ar- gon Detector

  18. Vibrational predissociation spectroscopy and theory of Ar-tagged, protonated Imidazole (Im) Im13H+

    E-Print Network [OSTI]

    Auerbach, Scott M.

    measurements carried out directly in the condensed phase [10]. Recent advances [11] in gas-phase ion chemistry s t r a c t We report vibrational predissociation spectra and theoretical analysis of the Ar- cies at the heart of the proton-transport process. In fact, a 2009 theoretical analysis of proton

  19. /sup 238/PuO/sub 2//Mo-50 wt% Re compatibility at 800 and 1000/sup 0/C

    SciTech Connect (OSTI)

    Schaeffer, D.R.; Teaney, P.E.

    1980-07-18T23:59:59.000Z

    The compatibility of Mo-50 wt % Re with /sup 238/PuO/sub 2/ was investigated after heat treatments of up to 720 days at 800/sup 0/C and 180 days at 1000/sup 0/C. At 800/sup 0/C, a 1-..mu..m thick, continuous layer of molybdenum oxide resulted. At 1000/sup 0/C, the oxide reaction product contained some plutonium and did not appear continuous. At 1000/sup 0/C, a layer of intermetallic formed at the Mo-Re edge, beneath the oxide layer, creating a barrier between the Mo-50 wt % Re and the /sup 238/PuO/sub 2/. The intermetallic layer was promoted by the iron impurity in the /sup 238/PuO/sub 2/.

  20. LASER TRIGGERED GAS SWITCHES UTILIZING BEAM TRANSPORT THROUGH 1 MO-cm DEIONIZED WATER.

    SciTech Connect (OSTI)

    Woodworth, Joseph Ray; Lehr, Jane [Sandia National Laboratories, Albuquerque, NM; Blickem, James R.; Wallace, Zachariah R.; Anaya, Victor Jr; Corley, John P; Lott, John; Hodge, Keith; Zameroski, Nathan D. [Sandia National Laboratories, Albuquerque, NM

    2005-11-01T23:59:59.000Z

    We report on the successful attempts to trigger high voltage pressurized gas switches by utilizing beam transport through 1 MO-cm deionized water. The wavelength of the laser radiation was 532 nm. We have investigated Nd: YAG laser triggering of a 6 MV, SF6 insulated gas switch for a range of laser and switch parameters. Laser wavelength of 532 nm with nominal pulse lengths of 10 ns full width half maximum (FWHM) were used to trigger the switch. The laser beam was transported through 67 cm-long cell of 1 MO-cm deionized water constructed with anti reflection UV grade fused silica windows. The laser beam was then focused to form a breakdown arc in the gas between switch electrodes. Less than 10 ns jitter in the operation of the switch was obtained for laser pulse energies of between 80-110 mJ. Breakdown arcs more than 35 mm-long were produced by using a 70 cm focusing optic.

  1. Shape controlled synthesis of CaMoO{sub 4} thin films and their photoluminescence property

    SciTech Connect (OSTI)

    Marques, Ana Paula de Azevedo [Laboratorio Interdisciplinar de Eletroquimica e Ceramica, Departamento de Quimica, Centro Multidisciplinar de Desenvolvimento de Materiais Ceramicos, Universidade Federal de Sao Carlos, C. Postal 676, 13565-905 Sao Carlos, SP (Brazil)], E-mail: apamarques@liec.ufscar.br; Longo, Valeria M. [Laboratorio Interdisciplinar de Eletroquimica e Ceramica, Departamento de Quimica, Centro Multidisciplinar de Desenvolvimento de Materiais Ceramicos, Universidade Federal de Sao Carlos, C. Postal 676, 13565-905 Sao Carlos, SP (Brazil); Melo, Dulce M.A. de [Laboratorio de Analise Termica e Materiais, Departamento de Quimica, Universidade Federal do Rio Grande do Norte, 59072-970 Natal, RN (Brazil); Pizani, Paulo S. [Laboratorio de Semicondutores, Departamento de Fisica, Universidade Federal de Sao Carlos, C. Postal 676, 13565-905 Sao Carlos, SP (Brazil); Leite, Edson R. [Laboratorio Interdisciplinar de Eletroquimica e Ceramica, Departamento de Quimica, Centro Multidisciplinar de Desenvolvimento de Materiais Ceramicos, Universidade Federal de Sao Carlos, C. Postal 676, 13565-905 Sao Carlos, SP (Brazil); Varela, Jose Arana [CMDMC, LIEC, Instituto de Quimica, Universidade Estadual Paulista, 14801-907 Araraquara, SP (Brazil); Longo, Elson [Laboratorio Interdisciplinar de Eletroquimica e Ceramica, Departamento de Quimica, Centro Multidisciplinar de Desenvolvimento de Materiais Ceramicos, Universidade Federal de Sao Carlos, C. Postal 676, 13565-905 Sao Carlos, SP (Brazil); CMDMC, LIEC, Instituto de Quimica, Universidade Estadual Paulista, 14801-907 Araraquara, SP (Brazil)

    2008-05-15T23:59:59.000Z

    CaMoO{sub 4} (CMO) disordered and ordered thin films were prepared by the complex polymerization method (CPM). The films were annealed at different temperatures and time in a conventional resistive furnace (RF) and in a microwave (MW) oven. The microstructure and surface morphology of the structure were monitored by atomic force microscopy (AFM) and high-resolution scanning electron microscopy (HRSEM). Order and disorder were characterized by X-ray diffraction (XRD) and optical reflectance. A strong photoluminescence (PL) emission was observed in the disordered thin films and was attributed to complex cluster vacancies. The experimental results were compared with density functional and Hartree-Fock calculations. - Graphical abstract: CaMoO{sub 4} thin films were prepared by the complex polymerization method (CPM). The films were annealed at different temperatures and time in a conventional resistive furnace and in a microwave oven. A strong photoluminescence emission was observed in the disordered thin films and was attributed to complex cluster vacancies. The experimental results were confirmed by high level first principle calculations.

  2. On the bonding nature of electron states for the Fe-Mo double perovskite

    SciTech Connect (OSTI)

    Carvajal, E.; Cruz-Irisson, M. [ESIME-Culhuacán, Instituto Politécnico Nacional, Av. Santa Ana 1000, C.P. 04430, México, D.F. (Mexico); Oviedo-Roa, R. [Programa de Investigación en Ingeniería Molecular, Instituto Mexicano del Petróleo, Eje Central Lázaro Cárdenas Norte 152, C.P. 07730, México, D.F. (Mexico); Navarro, O. [Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, A.P. 70-360, 04510, México, D.F. (Mexico)

    2014-05-15T23:59:59.000Z

    The electronic transport as well as the effect of an external magnetic field has been investigated on manganese-based materials, spinels and perovskites. Potential applications of double perovskites go from magnetic sensors to electrodes in solid-oxide fuel cells; besides the practical interests, it is known that small changes in composition modify radically the physical properties of double perovskites. We have studied the Sr{sub 2}FeMoO{sub 6} double perovskite compound (SFMO) using first-principles density functional theory. The calculations were done within the generalized gradient approximation (GGA) scheme with the Perdew-Burke-Ernzerhof (PBE) functional. We have made a detailed analysis of each electronic state and the charge density maps around the Fermi level. For the electronic properties of SFMO it was used a primitive cell, for which we found the characteristic half-metallic behavior density of states composed by e{sub g} and t{sub 2g} electrons from Fe and Mo atoms. Those peaks were tagged as bonding or antibonding around the Fermi level at both, valence and conduction bands.

  3. MoO3 as combined hole injection layer and tapered spacer in combinatorial multicolor microcavity organic light emitting diodes

    SciTech Connect (OSTI)

    Liu, R.; Xu, Chun; Biswas, Rana; Shinar, Joseph; Shinar, Ruth

    2011-09-01T23:59:59.000Z

    Multicolor microcavity ({mu}C) organic light-emitting diode (OLED) arrays were fabricated simply by controlling the hole injection and spacer MoO{sub 3} layer thickness. The normal emission was tunable from {approx}490 to 640 nm and can be further expanded. A compact, integrated spectrometer with two-dimensional combinatorial arrays of {mu}C OLEDs was realized. The MoO{sub 3} yields more efficient and stable devices, revealing a new breakdown mechanism. The pixel current density reaches {approx}4 A/cm{sup 2} and a maximal normal brightness {approx}140 000 Cd/m{sup 2}, which improves photoluminescence-based sensing and absorption measurements.

  4. Thermoelectric properties of M{sub 2}Mo{sub 6}Se{sub 6} (M =Tl,In)

    SciTech Connect (OSTI)

    Verebelyi, D.T.; Payne, J.E.; Tessema, G.X.; Mengistu, E.

    1997-07-01T23:59:59.000Z

    The authors have measured the thermal conductivity of Tl{sub 2}Mo{sub 6}Se{sub 6}, a quasi-one dimensional conductor which belongs to the family of M{sub 2}Mo{sub 6}X{sub 6} linear chain compounds. Using these results and the measurements of the Seebeck coefficient and the electrical conductivity the authors estimate the dimensionless figure of merit to be of the order of 0.08. This result suggest that this compound and other related compounds are good potential TE.

  5. Semiconductor electrodes; XLV: photoelectrochemistry of n- and p-Type MoTe/sub 2/ in aqueous solutions

    SciTech Connect (OSTI)

    Abruna, H.D.; Bard, A.J.; Hope, G.A.

    1982-10-01T23:59:59.000Z

    MoTe/sub 2/ (n- and p-type) electrodes have been characterized in terms of the energetic location of the valence and conduction bands, their voltammetric behavior, and their potential utility in photoelectrochemical cells. They show behavior that is qualitatively similar to the other layered semiconductors in terms of the sensitivity of their properties to growth conditions and surface imperfections. PEC cells based on n-MoTe/sub 2/ with I/sup -//I/sub 2/ as a redox couple were constructed. These reached monochromatic light (He/Ne laser) to electrical conversion efficiencies of over 8%.

  6. Y{sub 2}MoSe{sub 3}O{sub 12} and Y{sub 2}MoTe{sub 3}O{sub 12}: Solid-state synthesis, structure determination, and characterization of two new quaternary mixed metal oxides containing asymmetric coordination environment

    SciTech Connect (OSTI)

    Bang, Seong-eun; Pan, Zhi; Kim, Yeong Hun; Lee, Dong Woo; Ok, Kang Min, E-mail: kmok@cau.ac.kr

    2013-12-15T23:59:59.000Z

    Two new quaternary yttrium molybdenum selenium/tellurium oxides, Y{sub 2}MoSe{sub 3}O{sub 12} and Y{sub 2}MoTe{sub 3}O{sub 12} have been prepared by standard solid-state reactions using Y{sub 2}O{sub 3}, MoO{sub 3}, and SeO{sub 2} (or TeO{sub 2}) as reagents. Single-crystal X-ray diffraction was used to determine the crystal structures of the reported materials. Although both of the materials contain second-order Jahn–Teller (SOJT) distortive cations and are stoichiometrically similar, they reveal different structural features: while Y{sub 2}MoSe{sub 3}O{sub 12} shows a three-dimensional framework consisting of YO{sub 8}, MoO{sub 6}, and SeO{sub 3} groups, Y{sub 2}MoTe{sub 3}O{sub 12} exhibits a layered structure composed of YO{sub 8}, MoO{sub 4}, TeO{sub 3}, and TeO{sub 4} polyhedra. With the Mo{sup 6+} cations in Y{sub 2}MoSe{sub 3}O{sub 12}, a C{sub 3}-type intraoctahedral distortion toward a face is observed, in which the direction of the out-of-center distortion for Mo{sup 6+} is away from the oxide ligand linked to a Se{sup 4+} cation. The Se{sup 4+} and Te{sup 4+} cations in both materials are in asymmetric coordination environment attributed to the lone pairs. Elemental analyses, infrared spectroscopy, thermal analyses, intraoctahedral distortions, and dipole moment calculations for the compounds are also presented. - Graphical abstract: Y{sub 2}MoSe{sub 3}O{sub 12} reveals a three-dimensional framework consisting of YO{sub 8}, MoO{sub 6}, and SeO{sub 3} polyhedra, whereas Y{sub 2}MoTe{sub 3}O{sub 12} exhibits a layered structure composed of YO{sub 8}, MoO{sub 4}, TeO{sub 3}, and TeO{sub 4} groups. - Highlights: • Two new selenite and tellurite (Y{sub 2}MoQ{sub 3}O{sub 12}; Q=Se and Te) are synthesized. • Y{sub 2}MoQ{sub 3}O{sub 12} contain second-order Jahn–Teller distortive cations in asymmetric environments. • The intra-octahedral distortion of the Mo{sup 6+} is influenced by the Se{sup 4+}.

  7. Guidelines and Procedures for Motion Picture/Video/Film or Photography of and on the campus of the University of Missouri, Columbia MO.

    E-Print Network [OSTI]

    Taylor, Jerry

    of the University of Missouri, Columbia MO. The University of Missouri-Columbia, which houses the state of Missouri University of Missouri 311 Jesse Hall Columbia MO 65211-1240 Fax: 573.884.5446 The completed application producers, directors and their crew wish to use University property to produce films, television shows

  8. Controlled, Defect-Guided, Metal-Nanoparticle Incorporation onto MoS2 via Chemical and Microwave Routes: Electrical, Thermal, and

    E-Print Network [OSTI]

    Berry, Vikas

    show that MoS2 can be applied effectively in sensing,6,7 energy harvesting,8 and photoelectronicControlled, Defect-Guided, Metal-Nanoparticle Incorporation onto MoS2 via Chemical and Microwave via both diffusion limited aggregation and instantaneous reaction arresting (using microwaves

  9. Preparation and structural study from neutron diffraction data of Pr{sub 5}Mo{sub 3}O{sub 16}

    SciTech Connect (OSTI)

    Martinez-Lope, M.J. [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco, E-28049 Madrid, Spain. (Spain); Alonso, J.A., E-mail: ja.alonso@icmm.csic.e [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco, E-28049 Madrid, Spain. (Spain); Sheptyakov, D.; Pomjakushin, V. [Laboratory for Neutron Scattering, Paul Scherrer Institut, CH-5232 Villigen PSI (Switzerland)

    2010-12-15T23:59:59.000Z

    The title compound has been prepared as polycrystalline powder by thermal treatments of mixtures of Pr{sub 6}O{sub 11} and MoO{sub 2} in air. In the literature, an oxide with a composition Pr{sub 2}MoO{sub 6} has been formerly described to present interesting catalytic properties, but its true stoichiometry and crystal structure are reported here for the first time. It is cubic, isostructural with CdTm{sub 4}Mo{sub 3}O{sub 16} (space group Pn-3n, Z=8), with a=11.0897(1) A. The structure contains MoO{sub 4} tetrahedral units, with Mo-O distances of 1.788(2) A, fully long-range ordered with PrO{sub 8} polyhedra; in fact it can be considered as a superstructure of fluorite (M{sub 8}O{sub 16}), containing 32 MO{sub 2} fluorite formulae per unit cell, with a lattice parameter related to that of cubic fluorite (a{sub f}=5.5 A) as a{approx}2a{sub f}. A bond valence study indicates that Mo exhibits a mixed oxidation state between 5+ and 6+ (perhaps accounting for the excellent catalytic properties). One kind of Pr atoms is trivalent whereas the second presents a mixed Pr{sup 3+}-Pr{sup 4+} oxidation state. The similarity of the XRD pattern with that published for Ce{sub 2}MoO{sub 6} suggests that this compound also belongs to the same structural type, with an actual stoichiometry Ce{sub 5}Mo{sub 3}O{sub 16}. -- Graphical Abstract: Formerly formulated as Pr{sub 2}MoO{sub 6}, the title compound is a cubic superstructure of fluorite (a=11.0897(1) A, space group Pn-3n) due to the long-range ordering of PrO{sub 8} scalenohedra and MoO{sub 4} tetrahedral units, showing noticeable shifts of the oxygen positions in order to provide a tetrahedral coordination for Mo ions. A mixed valence Mo{sup 5+}-Mo{sup 6+} is identified, which could account for the excellent catalytic properties of this material. Display Omitted

  10. Determination of thermal and cementation histories from [sup 40]Ar/[sup 39]Ar and ion microprobe stable isotope analyses: A San Joaquin Basin example

    SciTech Connect (OSTI)

    Mahon, K.I.; Harrison, T.M.; Grove, M.; Lovera, O.M. (UCLA, Los Angeles, CA (United States))

    1996-01-01T23:59:59.000Z

    Knowledge of the temperature and cementation histories of sedimentary basins is key to appraisal of their liquid hydrocarbon potential. Understanding the thermal history permits assessment of whether source rocks have experienced conditions appropriate for petroleum formation. The mobility of hydrocarbons and their storage capacity in sandstone reservoirs are directly related to porosity changes during diagenesis. Recent advances in [sup 40]Ar/[sup 39]Ar dating (stripping of Cl-correlated Ar[sub xs] Multi-Diffusion Domain model) and development of ion micro-probe techniques for precise ([+-]0.6[per thousand]) [mu]m-scale oxygen isotopic analysis provide a basis to quantitatively determine thermal and cementation histories. Arkosic sandstones of the Stevens turbidities, San Joaquin basin, are cemented by carbonates with minor amounts of clay and quartz. Detrital K-spars from depths of 4.12 (A4) and 6.61 km (Al) in the Stevens zone at Elk Hills yield thermal histories via the MDD model. These results indicate a broadly linear temperature rise of 9[+-]3[degrees]C/Ma over the past 10 Ma and predict current peak temperatures that are within error ([+-]25[degrees]C) of the measured values of 200[degrees] (Al) and 150[degrees]C (A4). Previous bulk isotopic analyses of cements from Stevens sands at North Coles Levee indicate that diagenetic pore fluids were modified by the introduction of hydrocarbons and CO[sub 2] from maturing source horizons. In situ O isotopic analyses of 10 [mu]m spots in these cements confirms this heterogeneity. A model cementation history can then be calculated by linking the oxygen isotopic composition of the cements (and temperature-dependent fractionation factor) with the thermal history independently established from thermochronometry.

  11. Determination of thermal and cementation histories from {sup 40}Ar/{sup 39}Ar and ion microprobe stable isotope analyses: A San Joaquin Basin example

    SciTech Connect (OSTI)

    Mahon, K.I.; Harrison, T.M.; Grove, M.; Lovera, O.M. [UCLA, Los Angeles, CA (United States)

    1996-12-31T23:59:59.000Z

    Knowledge of the temperature and cementation histories of sedimentary basins is key to appraisal of their liquid hydrocarbon potential. Understanding the thermal history permits assessment of whether source rocks have experienced conditions appropriate for petroleum formation. The mobility of hydrocarbons and their storage capacity in sandstone reservoirs are directly related to porosity changes during diagenesis. Recent advances in {sup 40}Ar/{sup 39}Ar dating (stripping of Cl-correlated Ar{sub xs} Multi-Diffusion Domain model) and development of ion micro-probe techniques for precise ({+-}0.6{per_thousand}) {mu}m-scale oxygen isotopic analysis provide a basis to quantitatively determine thermal and cementation histories. Arkosic sandstones of the Stevens turbidities, San Joaquin basin, are cemented by carbonates with minor amounts of clay and quartz. Detrital K-spars from depths of 4.12 (A4) and 6.61 km (Al) in the Stevens zone at Elk Hills yield thermal histories via the MDD model. These results indicate a broadly linear temperature rise of 9{+-}3{degrees}C/Ma over the past 10 Ma and predict current peak temperatures that are within error ({+-}25{degrees}C) of the measured values of 200{degrees} (Al) and 150{degrees}C (A4). Previous bulk isotopic analyses of cements from Stevens sands at North Coles Levee indicate that diagenetic pore fluids were modified by the introduction of hydrocarbons and CO{sub 2} from maturing source horizons. In situ O isotopic analyses of 10 {mu}m spots in these cements confirms this heterogeneity. A model cementation history can then be calculated by linking the oxygen isotopic composition of the cements (and temperature-dependent fractionation factor) with the thermal history independently established from thermochronometry.

  12. Wideband saturable absorption in few-layer molybdenum diselenide (MoSe2) for Q-switching Yb-, Er- and Tm-doped fiber lasers

    E-Print Network [OSTI]

    Woodward, R I; Runcorn, T H; Hu, G; Torrisi, F; Kelleher, E J R; Hasan, T

    2015-01-01T23:59:59.000Z

    We fabricate a free-standing molybdenum diselenide (MoSe2) saturable absorber by embedding liquid-phase exfoliated few-layer MoSe2 flakes into a polymer film. The MoSe2-polymer composite is used to Q-switch fiber lasers based on ytterbium (Yb), erbium (Er) and thulium (Tm) gain fiber, producing trains of microsecond-duration pulses with kilohertz repetition rates at 1060 nm, 1566 nm and 1924 nm, respectively. Such operating wavelengths correspond to sub-bandgap saturable absorption in MoSe2, which is explained in the context of edge-states, building upon studies of other semiconducting transition metal dichalcogenide (TMD)-based saturable absorbers. Our work adds few-layer MoSe2 to the growing catalog of TMDs with remarkable optical properties, which offer new opportunities for photonic devices.

  13. Toward epitaxially grown two-dimensional crystal hetero-structures: Single and double MoS{sub 2}/graphene hetero-structures by chemical vapor depositions

    SciTech Connect (OSTI)

    Lin, Meng-Yu [Graduate Institute of Electronics Engineering, National Taiwan University, Taipei, Taiwan (China); Research Center for Applied Sciences, Academia Sinica, Nankang, Taipei, Taiwan (China); Chang, Chung-En [Department of Photonics, National Chiao-Tung University, Hsinchu, Taiwan (China); Wang, Cheng-Hung [Institute of Display, National Chiao-Tung University, Hsinchu, Taiwan (China); Su, Chen-Fung; Chen, Chi [Research Center for Applied Sciences, Academia Sinica, Nankang, Taipei, Taiwan (China); Lee, Si-Chen [Graduate Institute of Electronics Engineering, National Taiwan University, Taipei, Taiwan (China); Lin, Shih-Yen, E-mail: shihyen@gate.sinica.edu.tw [Graduate Institute of Electronics Engineering, National Taiwan University, Taipei, Taiwan (China); Research Center for Applied Sciences, Academia Sinica, Nankang, Taipei, Taiwan (China); Department of Photonics, National Chiao-Tung University, Hsinchu, Taiwan (China)

    2014-08-18T23:59:59.000Z

    Uniform large-size MoS{sub 2}/graphene hetero-structures fabricated directly on sapphire substrates are demonstrated with layer-number controllability by chemical vapor deposition (CVD). The cross-sectional high-resolution transmission electron microscopy (HRTEM) images provide the direct evidences of layer numbers of MoS{sub 2}/graphene hetero-structures. Photo-excited electron induced Fermi level shift of the graphene channel are observed on the single MoS{sub 2}/graphene hetero-structure transistors. Furthermore, double hetero-structures of graphene/MoS{sub 2}/graphene are achieved by CVD fabrication of graphene layers on top of the MoS{sub 2}, as confirmed by the cross-sectional HRTEM. These results have paved the possibility of epitaxially grown multi-hetero-structures for practical applications.

  14. Photoionization studies of C2H5I and C6H6 perturbed by Ar and SF6

    E-Print Network [OSTI]

    Findley, Gary L.

    1 Photoionization studies of C2H5I and C6H6 perturbed by Ar and SF6 C. M. Evans a,b , J. D. Scott a photoionization spectra of C2H5I and C6H6 doped into Ar and SF6, and photoabsorption spectra of C2H5I doped into Ar. The observation of subthreshold photoionization in C2H5I/SF6 and C6H6/SF6 is discussed in terms

  15. Dinitrogen fixation chemistry of a molybdenum trisanilide system

    E-Print Network [OSTI]

    Curley, John Joseph

    2009-01-01T23:59:59.000Z

    Dinitrogen cleavage by Mo(N[t-Bu]Ar)3 (Ar = 3,5-C6H3Me2) proceeds through the intermediate ([mu]-N2)[Mo(N[t-Bu]Ar)3]2 before forming N=Mo(N[t-Bu]Ar)3 as the product. Both the intermediate bridging N2 complex and the nitride ...

  16. Discuss the role of StAR protein in steroid hormone synthesis This essay will determine the exact role of StAR, its structure, regulation, and problems associated with

    E-Print Network [OSTI]

    Nottingham, University of

    synthesises glucocorticoids and mineralocorticoids which regulate metabolism and water balance, and also smallDa and 37-kDa. The essentiality of StAR was demonstrated by studying patients with congenital lipoid adrenal

  17. Volume 177, number 2 CHEMICAL PHYSICS LETTERS 15 February 1991 Cu titration of tilted CO on a MO( 110) surface

    E-Print Network [OSTI]

    Goodman, Wayne

    to the surface normal. Upon subsequent deposition of = 0.9 ML Cu at 95 Kfollowed by heating, infrared, in a weakening of the C-O bond [ l-41. The tilted CO can either dissociate into atomic C and 0 upon heating to z) surface. In this Letter, we present the results of studies on tilted CO on MO( 110) using infrared

  18. Trade Liberalization in South East Europe: Review of conformity of 23 FTAs with the MoU

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Trade Liberalization in South East Europe: Review of conformity of 23 FTAs with the MoU Patrick A1 of South East Europe (SEE) agreed to conclude bilateral Free Trade Agreements (FTAs) in order to develop their mutual trade and promote economic integration in the region. This approach implied

  19. Concept Feasibility Report for Using Co-Extrusion to Bond Metals to Complex Shapes of U-10Mo

    SciTech Connect (OSTI)

    Lavender, Curt A.; Paxton, Dean M.; Smith, Mark T.; Soulami, Ayoub; Joshi, Vineet V.; Burkes, Douglas

    2013-12-30T23:59:59.000Z

    In support of the Convert Program of the U.S. Department of Energy’s National Nuclear Security Administration (DOE/NNSA) Global Threat Reduction Initiative (GTRI), Pacific Northwest National Laboratory (PNNL) has been investigating manufacturing processes for the uranium-10% molybdenum (U-10Mo) alloy plate fuel for the U.S. high-performance research reactors (USHPRR). This report documents the results of PNNL’s efforts to develop the extrusion process for this concept. The approach to the development of a co-extruded complex-shaped fuel has been described and an extrusion of DU-10Mo was made. The initial findings suggest that given the extrusion forces required for processing U-10Mo, the co-extrusion process can meet the production demands of the USHPRR fuel and may be a viable production method. The development activity is in the early stages and has just begun to identify technical challenges to address details such as dimensional tolerances and shape control. New extrusion dies and roll groove profiles have been developed and will be assessed by extrusion and rolling of U-10Mo during the next fiscal year. Progress on the development and demonstration of the co-extrusion process for flat and shaped fuel is reported in this document

  20. Prediction of U-Mo dispersion nuclear fuels with Al-Si alloy using artificial neural network

    SciTech Connect (OSTI)

    Susmikanti, Mike, E-mail: mike@batan.go.id [Center for Development of Nuclear Informatics, National Nuclear Energy Agency, PUSPIPTEK, Tangerang (Indonesia); Sulistyo, Jos, E-mail: soj@batan.go.id [Center for Nuclear Facilities Engineering, National Nuclear Energy Agency, PUSPIPTEK, Tangerang (Indonesia)

    2014-09-30T23:59:59.000Z

    Dispersion nuclear fuels, consisting of U-Mo particles dispersed in an Al-Si matrix, are being developed as fuel for research reactors. The equilibrium relationship for a mixture component can be expressed in the phase diagram. It is important to analyze whether a mixture component is in equilibrium phase or another phase. The purpose of this research it is needed to built the model of the phase diagram, so the mixture component is in the stable or melting condition. Artificial neural network (ANN) is a modeling tool for processes involving multivariable non-linear relationships. The objective of the present work is to develop code based on artificial neural network models of system equilibrium relationship of U-Mo in Al-Si matrix. This model can be used for prediction of type of resulting mixture, and whether the point is on the equilibrium phase or in another phase region. The equilibrium model data for prediction and modeling generated from experimentally data. The artificial neural network with resilient backpropagation method was chosen to predict the dispersion of nuclear fuels U-Mo in Al-Si matrix. This developed code was built with some function in MATLAB. For simulations using ANN, the Levenberg-Marquardt method was also used for optimization. The artificial neural network is able to predict the equilibrium phase or in the phase region. The develop code based on artificial neural network models was built, for analyze equilibrium relationship of U-Mo in Al-Si matrix.

  1. The photocatalysis of Bi{sub 2}MoO{sub 6} under the irradiation of blue LED

    SciTech Connect (OSTI)

    Sun, Yuanyuan; Wang, Wenzhong, E-mail: wzwang@mail.sic.ac.cn; Zhang, Ling; Sun, Songmei

    2013-10-15T23:59:59.000Z

    Graphical abstract: - Highlights: • ·OH trap and hole sink were involved to investigate the active radicals. • Holes play a more important role in the degradation of RhB. • The ·OH were related to the decomposition of phenol. • The ·O{sub 2}-played a leading role in the photodegradation of phenol. • Blue LED is competitive and promising alternative for the future application. - Abstract: Bi{sub 2}MoO{sub 6} has been reported as a promising photocatalyst in wastewater treatment. The active radicals generated over the Bi{sub 2}MoO{sub 6} during the photocatalytic process were thought to be hydroxyl radical (·OH) but have not been proved. Herein, Bi{sub 2}MoO{sub 6} with nanoplate like morphology was synthesized and its photocatalytic performances in the degradation of rhodamine B (RhB) and phenol as colored and colorless model pollutants respectively were evaluated under the irradiation of blue light emitting diode (LED). The tert-butyl alcohol (TBA) as a ·OH trap and ethylene diamine tetraacetic acid (EDTA) as a hole sink were involved to investigate the main active groups that are generated on Bi{sub 2}MoO{sub 6} and function during the photodegradation of RhB and phenol. In addition, it is a competitive and promising alternative plan to use blue LED as light source for the future practical application in environmental remediation.

  2. Characterization of Gas Metal Arc Welding welds obtained with new high Cr-Mo ferritic stainless steel filler wires

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Characterization of Gas Metal Arc Welding welds obtained with new high Cr-Mo ferritic stainless Several compositions of metal cored filler wire were manufactured to define the best welding conditions for homogeneous welding, by Gas Metal Arc Welding (GMAW) process, of a modified AISI 444 ferritic stainless steel

  3. Highly Reversible Li-Ion Intercalating MoP2 Nanoparticle Cluster Anode for Lithium Rechargeable Batteries

    E-Print Network [OSTI]

    Cho, Jaephil

    Highly Reversible Li-Ion Intercalating MoP2 Nanoparticle Cluster Anode for Lithium Rechargeable nanoparticle clusters have quite reversible lithium-ion insertion and extraction, showing the first discharge lithium reactions, i MPn LixMPn simple Li-ion interca- lation and ii MPn M LixM + LixP alloying followed

  4. Development and validation of capabilities to measure thermal properties of layered monolithic U-Mo alloy plate-type fuel

    SciTech Connect (OSTI)

    Burkes, Douglas; Casella, Andrew M.; Buck, Edgar C.; Casella, Amanda J.; Edwards, Matthew K.; MacFarlan, Paul J.; Pool, Karl N.; Smith, Frances N.; Steen, Franciska H.

    2014-07-19T23:59:59.000Z

    The uranium-molybdenum (U-Mo) alloy in a monolithic form has been proposed as one fuel design capable of converting some of the world’s highest power research reactors from the use of high enriched uranium (HEU) to low enriched uranium (LEU). One aspect of the fuel development and qualification process is to demonstrate appropriate understanding of thermal conductivity behavior of the fuel system as a function of temperature and expected irradiation conditions. The purpose of this paper is to verify and validate the functionality of equipment methods installed in hot cells for eventual measurements on irradiated uranium-molybdenum (U-Mo) monolithic fuel specimens, procedures to operate the equipment, and models to extract the desired thermal properties. The results presented here demonstrate the adequacy of the equipment, procedures and models that have been developed for this purpose based on measurements conducted on surrogate depleted uranium-molybdenum (DU-Mo) alloy samples containing a zirconium diffusion barrier and clad in aluminum alloy 6061 (AA6061). The results are in excellent agreement with thermal property data reported in the literature for similar U-Mo alloys as a function of temperature.

  5. Synergistic effects of MoDTC and ZDTP on frictional behaviour of tribofilms at the nanometer scale

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    conditions in automotive engines, lubricating oils contain several additives, among which there are detergent ways resulting either in synergies or in adverse effects affecting the oil performance regarding anti1 Synergistic effects of MoDTC and ZDTP on frictional behaviour of tribofilms at the nanometer

  6. Effect of Mo substitution by W on impact property of heat affected zone in duplex stainless steels

    SciTech Connect (OSTI)

    Huh, M.J.; Kim, S.B.; Paik, K.W.; Kim, Y.G. [Korea Advanced Inst. of Science and Technology, Taejon (Korea, Republic of). Dept. of Materials Science and Engineering] [Korea Advanced Inst. of Science and Technology, Taejon (Korea, Republic of). Dept. of Materials Science and Engineering

    1997-04-01T23:59:59.000Z

    The duplex stainless steels are characterized by two phase structures composed of a mixture of austenite and ferrite phases. They offer high toughness, good weldability, satisfactory corrosion protection, excellent stress corrosion cracking resistance and high strength. Because of these characteristics, these steels have been widely used in various applications such as oil, gas, and chemical industries. Duplex stainless steels generally have suffered embrittlement when exposed at elevated temperature, i.e. above 300 C. To avoid this embrittlement, conventional duplex stainless steels are subject to solution treatment followed by water quenching in the final stage of production or fabrication, which limits the size of products. Kim et al. have recently reported that embrittlement can be greatly reduced by the partial or full replacement of Mo by W in 22Cr-base duplex stainless steels. For the processing of duplex stainless steel, fusion welding is a major fabrication method for corrosion resistant applications. Therefore the welding behavior of these materials has to be fully defined. The purpose of this study is to investigate the effect of Mo substitution by W on the impact property of simulated heat affected zones in 22Cr duplex stainless steels. Structural transformation associated with Mo substitution by W in HAZ has been also investigated on W-containing alloys and conventional 3% Mo duplex stainless steel.

  7. Effect of Composition on the Formation of Sigma during Single-Pass Welding of Mo-Bearing Stainless Steels

    E-Print Network [OSTI]

    DuPont, John N.

    by extending the solidification temperature range. Conversely, duplex and ferritic stainless steels, the advent of super-duplex stainless steels[8,12,17] with increased addi-bearing stainless steel compositions ranging from 0 to 10 wt pct Mo and over a broad range of Ni and Cr contents

  8. Synthesis of MoS? nano-petal forest supported on carbon nanotubes for enhanced field emission performance

    SciTech Connect (OSTI)

    Murawala, Aditya P.; Loh, Tamie A. J.; Chua, Daniel H. C., E-mail: msechcd@nus.edu.sg [Department of Materials Science and Engineering, National University of Singapore, Singapore 117576 (Singapore)

    2014-09-21T23:59:59.000Z

    We report the fabrication of a three-dimensional forest of highly crystalline two-dimensional (2D) molybdenum disulfide (MoS?) nano-petals encapsulating vertically aligned carbon nanotubes (CNT) in a core-shell configuration. Growth was conducted via magnetron sputtering at room temperature and it was found that the nano-petal morphology was formed only when a critical threshold in sputter deposition time was reached. Below this threshold, an amorphous tubular structure composed of mainly molybdenum oxides dominates instead. The presence of the MoS? nano-petals was shown to impart photoluminescence to the CNTs, in addition to significantly enhancing their electron emission properties, where the turn-on field was lowered from 2.50 V?m?¹ for pristine CNTs to 0.80 V?m?¹ for MoS?-CNT heterostructures fabricated at 30 min sputter deposition time. Photoluminescence was detected at wavelengths of approximately 684 nm and 615 nm, with the band at 684 nm gradually blue-shifting as sputter time was increased. These results demonstrate that it is possible to synthesize 2D MoS? layers without the need for chemical routes and high growth temperatures.

  9. tinyMoBot: A Platform for Mobile Sensor Networks Torsten Stremlau, Christoph Weyer, and Volker Turau

    E-Print Network [OSTI]

    Turau, Volker

    tinyMoBot: A Platform for Mobile Sensor Networks Torsten Stremlau, Christoph Weyer, and Volker or the whole network consist of mobile sen- sor nodes. Currently, no common platform is available. This paper are able to communicate with static nodes. Since a general mobile sensor network platform is not available

  10. Photodisintegration studies on p-nuclei: The case of Mo and Sm isotopes

    E-Print Network [OSTI]

    C. Nair; A. R. Junghans; M. Erhard; D. Bemmerer; R. Beyer; P. Crespo; E. Grosse; M. Fauth; K. Kosev; G. Rusev; K. D. Schilling; R. Schwengner; A. Wagner

    2007-10-26T23:59:59.000Z

    In explosive stellar environments like supernovae, the temperatures are high enough for the production of heavy neutron-deficient nuclei, the socalled p-nuclei. Up to now, the knowledge of the reaction rates of p-nuclei is based on theoretical parameterizations using statistical model calculations. At the bremsstrahlung facility of the superconducting electron accelerator ELBE of FZ Dresden-Rossendorf, we aim to measure the photodisintegration rates of heavy nuclei experimentally. Photoactivation measurements on the astrophysically relevant p-nuclei 92Mo and 144Sm have been performed with bremsstrahlung end-point energies from 10.0 to 16.5 MeV. First experiments on the short-lived decays following the reaction 144Sm(gamma,n) are carried out using a pneumatic delivery system for rapid transport of activated samples. The activation yields are compared with calculations using cross sections from recent Hauser-Feshbach models.

  11. Thermodynamic modeling and experimental validation of the Fe-Al-Ni-Cr-Mo alloy system

    SciTech Connect (OSTI)

    Teng, Zhenke [ORNL; Zhang, F [CompuTherm LLC, Madison, WI; Miller, Michael K [ORNL; Liu, Chain T [Hong Kong Polytechnic University; Huang, Shenyan [ORNL; Chou, Y.T. [Multi-Phase Services Inc., Knoxville; Tien, R [Multi-Phase Services Inc., Knoxville; Chang, Y A [ORNL; Liaw, Peter K [University of Tennessee, Knoxville (UTK)

    2012-01-01T23:59:59.000Z

    NiAl-type precipitate-strengthened ferritic steels have been known as potential materials for the steam turbine applications. In this study, thermodynamic descriptions of the B2-NiAl type nano-scaled precipitates and body-centered-cubic (BCC) Fe matrix phase for four alloys based on the Fe-Al-Ni-Cr-Mo system were developed as a function of the alloy composition at the aging temperature. The calculated phase structure, composition, and volume fraction were validated by the experimental investigations using synchrotron X-ray diffraction and atom probe tomography. With the ability to accurately predict the key microstructural features related to the mechanical properties in a given alloy system, the established thermodynamic model in the current study may significantly accelerate the alloy design process of the NiAl-strengthened ferritic steels.

  12. Intense femtosecond photoexcitation of bulk and monolayer MoS{sub 2}

    SciTech Connect (OSTI)

    Paradisanos, I.; Fotakis, C. [Institute of Electronic Structure and Laser (IESL), Foundation for Research and Technology-Hellas (FORTH), Heraklion 71003 (Greece); Physics Department, University of Crete, Heraklion 71003 (Greece); Kymakis, E. [Center of Materials Technology and Photonics and Electrical Engineering Department, Technological Educational Institute (TEI) of Crete, Heraklion 71003 (Greece); Kioseoglou, G. [Materials Science and Technology Department, University of Crete, Heraklion 71003 (Greece); Stratakis, E., E-mail: stratak@iesl.forth.gr [Institute of Electronic Structure and Laser (IESL), Foundation for Research and Technology-Hellas (FORTH), Heraklion 71003 (Greece); Materials Science and Technology Department, University of Crete, Heraklion 71003 (Greece)

    2014-07-28T23:59:59.000Z

    The effect of femtosecond laser irradiation on bulk and single-layer MoS{sub 2} on silicon oxide is studied. Optical, field emission scanning electron microscopy and Raman microscopy were used to quantify the damage. The intensity of A{sub 1g} and E{sub 2g}{sup 1} vibrational modes was recorded as a function of the number of irradiation pulses. The observed behavior was attributed to laser-induced bond breaking and subsequent atoms removal due to electronic excitations. The single-pulse optical damage threshold was determined for the monolayer and bulk under 800?nm and 1030?nm pulsed laser irradiation, and the role of two-photon versus one photon absorption effects is discussed.

  13. Indirect-direct band gap transition through electric tuning in bilayer MoS{sub 2}

    SciTech Connect (OSTI)

    Zhang, Z. Y.; Si, M. S., E-mail: sims@lzu.edu.cn; Wang, Y. H.; Gao, X. P. [Key laboratory for Magnetism and Magnetic Materials of the Ministry of Education, School of Physical Science and Technology, Lanzhou University, Lanzhou 730 000 (China)] [Key laboratory for Magnetism and Magnetic Materials of the Ministry of Education, School of Physical Science and Technology, Lanzhou University, Lanzhou 730 000 (China); Sung, Dongchul; Hong, Suklyun [Graphene Research Institute, Sejong University, Seoul 143 747 (Korea, Republic of)] [Graphene Research Institute, Sejong University, Seoul 143 747 (Korea, Republic of); He, Junjie [Department of Physics, Xiangtan University, Hunan 411 105 (China)] [Department of Physics, Xiangtan University, Hunan 411 105 (China)

    2014-05-07T23:59:59.000Z

    We investigate the electronic properties of bilayer MoS{sub 2} exposed to an external electric field by using first-principles calculations. It is found that a larger interlayer distance, referring to that by standard density functional theory (DFT) with respect to that by DFT with empirical dispersion corrections, makes indirect-direct band gap transition possible by electric control. We show that external electric field effectively manipulates the valence band contrast between the K- and ?-valleys by forming built-in electric dipole fields, which realizes an indirect-direct transition before a semiconductor-metal transition happens. Our results provide a novel efficient access to tune the electronic properties of two-dimensional layered materials.

  14. Irradiation effects on base metal and welds of 9Cr-1Mo (EM10) martensitic steel

    SciTech Connect (OSTI)

    Alamo, A.; Seran, J.L.; Rabouille, O.; Brachet, J.C.; Maillard, A.; Touron, H.; Royer, J. [CEA Saclay, Gif-sur-Yvette (France)

    1996-12-31T23:59:59.000Z

    9Cr martensitic steels are being developed for core components (wrapper tubes) of fast breeder reactors as well as for fusion reactor structures. Here, the effects of fast neutron irradiation on the mechanical behavior of base metal and welds of 9Cr-1Mo (EM10) martensitic steel have been studied. Two types of weldments have been produced by TIG and electron beam techniques. Half of samples have been post-weld heat treated to produce a stress-relieved structure. The irradiation has been conducted in the Phenix reactor to doses of 63--65 dpa in the temperature range 450--459 C. The characterization of the welds, before and after irradiation, includes metallographic observations, hardness measurements, tensile and Charpy tests. It is shown that the mechanical properties of the welds after irradiation are in general similar to the characteristics obtained on the base metal, which is little affected by neutron irradiation.

  15. Microstructural Characterization of Irradiated U-7Mo/Al-5Si Dispersion to High Fission Density

    SciTech Connect (OSTI)

    J. Gan; B. D. Miller; D. D. Keiser, Jr.; A. B. Robinson; J. W. Madden; P. G. Medvedev; D. M. Wachs

    2014-11-01T23:59:59.000Z

    The fuel development program for research and test reactors calls for improved knowledge on the effect of microstructure on fuel performance in reactors. This work summarizes the recent TEM microstructural characterization of an irradiated U-7Mo/Al-5Si dispersion fuel plate (R3R050) irradiated in the Advanced Test Reactor (ATR) at Idaho National Laboratory to 5.2×1021 fissions/cm3. While a large fraction of the fuel grains is decorated with large bubbles, there is no evidence showing interlinking of these large bubbles at the specified fission density. The attachment of solid fission product precipitates to the bubbles is likely the result of fission product diffusion into these bubbles. The process of fission gas bubble superlattice collapse appears through bubble coalescence. The results are compared with the previous TEM work of the dispersion fuels irradiated to lower fission density from the same fuel plate.

  16. Small-scale Specimen Testing of Monolithic U-Mo Fuel Foils

    SciTech Connect (OSTI)

    Ramprashad Prabhakaran; Douglas E. Burkes; James I. Cole; Indrajit Charit; Daniel M. Wachs

    2008-10-01T23:59:59.000Z

    The objective of this investigation is to develop a shear punch testing (SPT) procedure and standardize it to evaluate the mechanical properties of irradiated fuels in a hot-cell so that the tensile behavior can be predicted using small volumes of material and at greatly reduced irradiation costs. This is highly important in the development of low-enriched uranium fuels for nuclear research and test reactors. The load-displacement data obtained using SPT can be interpreted in terms of and correlated with uniaxial mechanical properties. In order to establish a correlation between SPT and tensile data, sub-size tensile and microhardness testing were performed on U-Mo alloys. In addition, efforts are ongoing to understand the effect of test parameters (such as specimen thickness, surface finish, punch-die clearance, crosshead velocity and carbon content) on the measured mechanical properties, in order to rationalize the technique, prior to employing it on a material of unknown strength.

  17. Heat treated 9 Cr-1 Mo steel material for high temperature application

    DOE Patents [OSTI]

    Jablonski, Paul D.; Alman, David; Dogan, Omer; Holcomb, Gordon; Cowen, Christopher

    2012-08-21T23:59:59.000Z

    The invention relates to a composition and heat treatment for a high-temperature, titanium alloyed, 9 Cr-1 Mo steel exhibiting improved creep strength and oxidation resistance at service temperatures up to 650.degree. C. The novel combination of composition and heat treatment produces a heat treated material containing both large primary titanium carbides and small secondary titanium carbides. The primary titanium carbides contribute to creep strength while the secondary titanium carbides act to maintain a higher level of chromium in the finished steel for increased oxidation resistance, and strengthen the steel by impeding the movement of dislocations through the crystal structure. The heat treated material provides improved performance at comparable cost to commonly used high-temperature steels such as ASTM P91 and ASTM P92, and requires heat treatment consisting solely of austenization, rapid cooling, tempering, and final cooling, avoiding the need for any hot-working in the austenite temperature range.

  18. Waste Processing To Support {sup 99}Mo Production at Sandia National Laboratories

    SciTech Connect (OSTI)

    Longley, Susan; Carson, Susan; McDonald, Marion

    1997-06-01T23:59:59.000Z

    As part of the Isotope Production Program at Sandia National Laboratories New Mexico (SNL/NM), procedures are being finalized for the production of {sup 99}Mo from the irradiation of {sup 235}U-coated stainless steel targets at the Technical Area (TA) V reactor and hot cell facilities. Methods have been identified and tested for the management of the non-product (waste) material as the final step in the production process. These methods were developed utilizing the waste material from a series of cold and hot tests, beginning with depleted uranium powder and culminating with a test involving an irradiated {sup 235}U target with an initial fission product inventory of approximately 18,000 Ci at the end of the irradiation cycle.

  19. Induced codeposition. 2: A mathematical model describing the electrodeposition of Ni-Mo alloys

    SciTech Connect (OSTI)

    Podlaha, E.J.; Landolt, D. [Ecole Polytechnique Federale de Lausanne (Switzerland)

    1996-03-01T23:59:59.000Z

    A steady-state mathematical model was developed to predict the behavior of the induced codeposition of Ni-Mo alloys in the kinetic and mass-transport controlled regions on rotating cylinder electrodes. The kinetic regions were characterized by a simple Tafel expression. A Nernst boundary layer representation described the mass transfer of ions through a diffusion layer. The governing features of the induced codeposition mechanism included soluble nickel acting as a catalyst to the molybdenum deposition and the generation of an absorbed intermediate species on the electrode surface. The resulting alloy composition was simulated for two electrolytes over a wide range of current densities and electrode rotation rates. The model predictions agreed with the observed trends in the experimental data.

  20. Development of an energy-use estimation methodology for the revised Navy Manual MO-303

    SciTech Connect (OSTI)

    Richman, E.E.; Keller, J.M.; Wood, A.G.; Dittmer, A.L.

    1995-01-01T23:59:59.000Z

    The U.S. Navy commissioned Pacific Northwest Laboratory (PNL) to revise and/or update the Navy Utilities Targets Manual, NAVFAC MO-303 (U.S. Navy 1972b). The purpose of the project was to produce a current, applicable, and easy-to-use version of the manual for use by energy and facility engineers and staff at all Navy Public Works Centers (PWCs), Public Works Departments (PWDs), Engineering Field Divisions (EFDs), and other related organizations. The revision of the MO-303 manual involved developing a methodology for estimating energy consumption in buildings and ships. This methodology can account for, and equitably allocate, energy consumption within Navy installations. The analyses used to develop this methodology included developing end-use intensities (EUIs) from a vast collection of Navy base metering and billing data. A statistical analysis of the metering data, weather data, and building energy-use characteristics was used to develop appropriate EUI values for use at all Navy bases. A complete Navy base energy reconciliation process was also created for use in allocating all known energy consumption. Initial attempts to use total Navy base consumption values did not produce usable results. A parallel effort using individual building consumption data provided an estimating method that incorporated weather effects. This method produced a set of building EUI values and weather adjustments for use in estimating building energy use. A method of reconciling total site energy consumption was developed based on a {open_quotes}zero-sum{close_quotes} principle. This method provides a way to account for all energy use and apportion part or all of it to buildings and other energy uses when actual consumption is not known. The entire text of the manual was also revised to present a more easily read understood and usable document.

  1. NUMERICAL SIMULATION FOR MECHANICAL BEHAVIOR OF U10MO MONOLITHIC MINIPLATES FOR RESEARCH AND TEST REACTORS

    SciTech Connect (OSTI)

    Hakan Ozaltun & Herman Shen

    2011-11-01T23:59:59.000Z

    This article presents assessment of the mechanical behavior of U-10wt% Mo (U10Mo) alloy based monolithic fuel plates subject to irradiation. Monolithic, plate-type fuel is a new fuel form being developed for research and test reactors to achieve higher uranium densities within the reactor core to allow the use of low-enriched uranium fuel in high-performance reactors. Identification of the stress/strain characteristics is important for understanding the in-reactor performance of these plate-type fuels. For this work, three distinct cases were considered: (1) fabrication induced residual stresses (2) thermal cycling of fabricated plates; and finally (3) transient mechanical behavior under actual operating conditions. Because the temperatures approach the melting temperature of the cladding during the fabrication and thermal cycling, high temperature material properties were incorporated to improve the accuracy. Once residual stress fields due to fabrication process were identified, solution was used as initial state for the subsequent simulations. For thermal cycling simulation, elasto-plastic material model with thermal creep was constructed and residual stresses caused by the fabrication process were included. For in-service simulation, coupled fluid-thermal-structural interaction was considered. First, temperature field on the plates was calculated and this field was used to compute the thermal stresses. For time dependent mechanical behavior, thermal creep of cladding, volumetric swelling and fission induced creep of the fuel foil were considered. The analysis showed that the stresses evolve very rapidly in the reactor. While swelling of the foil increases the stress of the foil, irradiation induced creep causes stress relaxation.

  2. Experimental and Theoretical EPR Study of Jahn?Teller-Active [HIPTN[subscript 3]N]MoL Complexes (L = N[subscript 2], CO, NH[subscript 3])

    E-Print Network [OSTI]

    McNaughton, Rebecca L.

    The trigonally symmetric Mo(III) coordination compounds [HIPTN[subscript 3]N]MoL (L = N[subscript 2], CO, NH[subscript 3]; [HIPTN3N]Mo = [(3,5-(2,4,6-i-Pr[subscript 3]C[subscript 6]H[subscript 2])[subscript 2]C[subscript ...

  3. Inductively coupled plasma etching of Si{sub 1-x}Ge{sub x} in CF{sub 4}/Ar and Cl{sub 2}/Ar discharges

    SciTech Connect (OSTI)

    Wu, S.-L.; Lee, C.-H.; Chang, S.-J.; Lin, Y.-M. [Department of Electronics Engineering, Cheng Shiu University, 840 Chengcing Road, Niaosong, Kaohsiung 833, Taiwan (China); Institute of Microelectronics, Department of Electrical Engineering, National Cheng Kung University, 1 Ta Hseuh Road, Tainan 701, Taiwan (China); Institute of Microelectronics, Department of Electrical Engineering, National Cheng Kung University, 1 Ta Hseuh Road, Tainan 701, Taiwan (China)

    2006-05-15T23:59:59.000Z

    In this article, we report the experimental realization of SiGe/Si materials using CF{sub 4}/Ar and Cl{sub 2}/Ar mixed-gas inductively coupled plasma (ICP) etching process. The effects of process parameters such as gas combination and gas species on etch rates and selectivities were investigated. It was found that samples in CF{sub 4} gas result in a faster etching rate than those obtained in Cl{sub 2} gas, which are responsible for a lower boiling point for Si-based fluoride. The lower boiling point provides more chemically active Si and SiGe materials. Moreover, the selectivity of 1.5 between Si{sub 0.3}Ge{sub 0.7}/Si by ICP technology was found and higher than that obtained previously by reactive ion etching reported in the literature. Based on these etch characteristics, the application of the ICP process to the device fabrication of SiGe doped-channel field-effect transistors was conducted. The devices using ICP mesa have excellent pinch-off characteristics with relatively low leakage current, small output conduction in the saturated region, and low knee voltage.

  4. arXiv:physics/0401035v19Jan2004 A Didactic Approach to Linear Waves in the Ocean

    E-Print Network [OSTI]

    Beron-Vera, Francisco Javier

    arXiv:physics/0401035v19Jan2004 A Didactic Approach to Linear Waves in the Ocean F. J. Beron conceptual. Accordingly, the equations of motion are simplified as much as possible for didactic purposes

  5. A 33 yr CONSTANCY OF THE X-RAY CORONAE OF AR Lac AND ECLIPSE DIAGNOSIS OF SCALE HEIGHT

    E-Print Network [OSTI]

    Drake, Jeremy J.

    Extensive X-ray and EUV photometric observations of the eclipsing RS CVn system AR Lac were obtained over the years 1997-2013 with the Chandra X-Ray Observatory Extreme-Ultraviolet Explorer (EUVE). During primary eclipse, ...

  6. arXiv:submit/0193005[math.AP]7Feb2011 Fast reconstruction algorithms for the thermoacoustic

    E-Print Network [OSTI]

    Kunyansky, Leonid

    arXiv:submit/0193005[math.AP]7Feb2011 Fast reconstruction algorithms for the thermoacoustic Thermoacoustic tomography (TAT) and the closely related photoacoustic modality (PAT) are both based

  7. arXiv:0912.2022v1[math.AP]10Dec2009 Mathematics of Photoacoustic and Thermoacoustic

    E-Print Network [OSTI]

    Kunyansky, Leonid

    arXiv:0912.2022v1[math.AP]10Dec2009 Mathematics of Photoacoustic and Thermoacoustic Tomography P that surveys the mathematical models, problems, and algorithms of the Thermoacoustic (TAT) and Photoacoustic

  8. arXiv:1102.1413v1[math.AP]7Feb2011 Fast reconstruction algorithms for the thermoacoustic

    E-Print Network [OSTI]

    Kunyansky, Leonid

    arXiv:1102.1413v1[math.AP]7Feb2011 Fast reconstruction algorithms for the thermoacoustic tomography Thermoacoustic tomography (TAT) and the closely related photoacoustic modality (PAT) are both based

  9. arXiv:cond-mat/0503226v19Mar2005 Two Superconducting Phases in the d = 3 Hubbard Model

    E-Print Network [OSTI]

    Gozuacik, Devrim

    arXiv:cond-mat/0503226v19Mar2005 Two Superconducting Phases in the d = 3 Hubbard Model: Phase. The strong-coupling phase, on the other hand, has characteristics of BEC-type superconductivity, including

  10. K/AR dating of clinoptilolite, mordenite, and associated clays from Yucca Mountains, Nevada

    SciTech Connect (OSTI)

    WoldeGabriel, G.

    1993-07-01T23:59:59.000Z

    Zeolites are abundant in the geologic record in both continental and marine environments. The purpose of the present study is to evaluate the utility of K-bearing zeolites for dating by the K/Ar method to determine the time of zeolite diagenesis at Yucca Mountain, Nevada (Fig. 1). At Yucca Mountain, K-rich clinoptilolite and possibly mordenite are the only potentially K/Ar dateable secondary minerals present in the zeolite-rich tuffs except for some illite/smectites ({ge}10% illite layers) associated with these minerals. Direct dating of K-rich clinoptilolite, the most abundant zeolite in the altered tuffs, is important to delineate zeolite chronology as part of the site characterization of Yucca Mountain.

  11. M5Si3(M=Ti, Nb, Mo) Based Transition-Metal Silicides for High Temperature Applications

    SciTech Connect (OSTI)

    Zhihong Tang

    2007-12-01T23:59:59.000Z

    Transition metal silicides are being considered for future engine turbine components at temperatures up to 1600 C. Although significant improvement in high temperature strength, room temperature fracture toughness has been realized in the past decade, further improvement in oxidation resistance is needed. Oxidation mechanism of Ti{sub 5}Si{sub 3}-based alloys was investigated. Oxidation behavior of Ti{sub 5}Si{sub 3}-based alloy strongly depends on the atmosphere. Presence of Nitrogen alters the oxidation behavior of Ti{sub 5}Si{sub 3} by nucleation and growth of nitride subscale. Ti{sub 5}Si{sub 3.2} and Ti{sub 5}Si{sub 3}C{sub 0.5} alloys exhibited an excellent oxidation resistance in nitrogen bearing atmosphere due to limited dissolution of nitrogen and increased Si/Ti activity ratio. MoSi{sub 2} coating developed by pack cementation to protect Mo-based Mo-Si-B composites was found to be effective up to 1500 C. Shifting coating composition to T1+T2+Mo{sub 3}Si region showed the possibility to extend the coating lifetime above 1500 C by more than ten times via formation of slow growing Mo{sub 3}Si or T2 interlayer without sacrificing the oxidation resistance of the coating. The phase equilibria in the Nb-rich portion of Nb-B system has been evaluated experimentally using metallographic analysis and differential thermal analyzer (DTA). It was shown that Nb{sub ss} (solid solution) and NbB are the only two primary phases in the 0-40 at.% B composition range, and the eutectic reaction L {leftrightarrow} Nb{sub SS} + NbB was determined to occur at 2104 {+-} 5 C by DTA.

  12. arXiv:astroph/0105270 IUCAA22/2001, KSUPT01/3 May 2001

    E-Print Network [OSTI]

    Souradeep, Tarun

    arXiv:astro­ph/0105270 16 May 2001 IUCAA­22/2001, KSUPT­01/3 May 2001 Window Function for Non cosmological parameters. See, e.g., Subrah­ manyan et al. (2000), Romeo et al. (2001), Dawson et al. (2000), and Padin et al. (2001) for recent CMB anisotropy observations, and, e.g., Ratra et al. (1997), G'orski et

  13. Investigation of plasma-dust structures in He-Ar gas mixture

    SciTech Connect (OSTI)

    Maiorov, S. A. [A.M. Prokhorov General Physics Institute of Russian Academy of Sciences, Moscow (Russian Federation); Ramazanov, T. S.; Dzhumagulova, K. N.; Jumabekov, A. N.; Dosbolayev, M. K. [Al Farabi Kazakh National University, IETP, Tole bi 96a, Almaty, 050012 (Kazakhstan)

    2008-09-15T23:59:59.000Z

    The paper reports on the first experiments with plasma-dust formations in dc gas discharge plasma for a He-Ar mixture. It is shown that the choice of light and heavy gases for the mixture suppresses ion heating in electric field under the conventional conditions of experiments and results in a supersonic jet with high Mach numbers. Distribution functions for drifting ions in the gas mixture are calculated for various mixture concentrations, electric field strengths, and gas pressures.

  14. arXiv:1311.5455v1 NLO QCD Corrections to Electroweak Higgs Boson

    E-Print Network [OSTI]

    Lunds Universitet,

    arXiv:1311.5455v1 [hep­ph] 21 Nov 2013 NLO QCD Corrections to Electroweak Higgs Boson Plus Three.sjodahl@thep.lu.se The implementation of the full next­to­leading order (NLO) QCD corrections to electroweak Higgs boson plus three jet Model (SM) Higgs boson [3, 4, 5, 6]. Further, reports from the ATLAS and CMS Collaborations indicate

  15. Le magn)sme ar)ficiel pour les gaz d'atomes froids

    E-Print Network [OSTI]

    Dalibard, Jean

    Le magné)sme ar)ficiel pour les gaz d'atomes froids Jean Dalibard Année 2013-14 Chaire Atomes et rayonnement #12;Thème général du cours : le magné?sme = q v B = 0 perdu d'avance ? pas forcément... On peut émuler ce magné?sme par

  16. Electron shakeoff following the $\\Beta$+ decay of trapped 35Ar+ ions

    E-Print Network [OSTI]

    Couratin, C; Fabre, B; Pons, B; Fléchard, X; Liénard, E; Ban, G; Breitenfeldt, M; Delahaye, P; Durand, D; Méry, A; Naviliat-Cuncic, O; Porobic, T; Quéméner, G; Rodriguez, D; Severijns, N; Thomas, J C; Van Gorp, S

    2013-01-01T23:59:59.000Z

    The electron shakeoff of $^{35}$Cl atoms resulting from the $\\beta$$^+$ decay of $^{35}$Ar$^+$ ions has been investigated using a Paul trap coupled to a recoil-ion spectrometer. The charge-state distribution of the recoiling daughter nuclei is compared to theoretical calculations accounting for shakeoff and Auger processes. The calculations are in excellent agreement with the experimental results and enable to identify the ionization reaction routes leading to the formation of all charge states.

  17. Quasiparticle and Optical Excitations in Solid Ne and Ar: GW and BSE Approximations

    SciTech Connect (OSTI)

    Patterson, Charles H.; Galamic-Mulaomerovic, S. [School of Physics, Trinity College Dublin, Dublin 2 (Ireland)

    2007-12-26T23:59:59.000Z

    The GW approximation and the Bethe-Salpeter equation (BSE) have been used to calculate quasiparticle and optical excitations in solid Ne and Ar. Absolute positions of quasiparticle and quasihole energies are found to be in very good agreement with experimental values. Binding energies of Frenkel excitons for these systems calculated using the BSE are also in good agreement with experiment. Splitting of excitons into longitudinal and transverse modes is calculated and found to be approximately twice the experimentally measured value.

  18. Vibrational relaxation in I2 ,,Ar...n ,,n1,2,6,9... and I2

    E-Print Network [OSTI]

    Neumark, Daniel M.

    with excitation energy. The observed dynamics for I2 (CO2) and several of the I2 (Ar)n clusters directly probe is complemented by molecular dynamics simulations by Parson and co-workers2,13­18 and others.19­22 The two solvent in I2 (Ar)20 also a full solvent shell occurs on a time scale of 130 ps.7 Molecular dynamics

  19. A novel perfluorinated AR (antireflective) and protective coating for KDP (potassium dihydrogen phosphate) and other optical materials

    SciTech Connect (OSTI)

    Thomas, I.M.; Campbell, J.H.

    1990-12-17T23:59:59.000Z

    A new commercially available perfluorinated organic polymer has been used to prepare a combined quarterwave AR and protective coating for KDP and other optical materials. Coatings are applied from solution at room temperature by spin or dip, they are fully dense and have a refractive index of 1.29. The laser damage threshold at 1064 nm and 355 nm is the highest that we have ever measured for an AR coating material. 5 refs., 8 figs., 3 tabs.

  20. Development of cryogenic low background detector based on enriched zinc molybdate crystal scintillators to search for neutrinoless double beta decay of $^{100}$Mo

    E-Print Network [OSTI]

    Chernyak, Dmitry

    2015-01-01T23:59:59.000Z

    ZnMoO$_4$ scintillators with a mass of $\\sim$ 0.3 kg, as well as Zn$^{100}$MoO$_4$ crystals enriched in the isotope $^{100}$Mo were produced for the first time by using the low-thermal-gradient Czochralski technique. The optical and luminescent properties of the produced crystals were studied to estimate the progress in crystal growth quality. The low-temperature tests with a 313 g ZnMoO$_4$ and two enriched Zn$^{100}$MoO$_4$ crystals were performed aboveground in the Centre de Sciences Nucl\\'eaires et de Sciences de la Mati\\`ere. The low background measurements with a three ZnMoO$_4$ and two enriched detectors installed in the EDELWEISS set-up at the Laboratoire Souterrain de Modane were carried out. To optimize the light collection in ZnMoO$_4$ scintillating bolometers, we have simulated the collection of scintillation photons in a detector module for different geometries by Monte Carlo method using the GEANT4 package. Response to the 2$\

  1. Method for generating a crystalline .sup.99 MoO.sub.3 product and the isolation .sup.99m Tc compositions therefrom

    DOE Patents [OSTI]

    Bennett, Ralph G. (Idaho Falls, ID); Christian, Jerry D. (Idaho Falls, ID); Kirkham, Robert J. (Blackfoot, ID); Tranter, Troy J. (Idaho Falls, ID)

    1998-01-01T23:59:59.000Z

    An improved method for producing .sup.99m Tc compositions. .sup.100 Mo metal is irradiated with photons in a particle (electron) accelerator to produce .sup.99 Mo metal which is dissolved in a solvent. A solvated .sup.99 Mo product is then dried to generate a supply of .sup.99 MoO.sub.3 crystals. The crystals are thereafter heated at a temperature which will sublimate the crystals and form a gaseous mixture containing vaporized .sup.99m TcO.sub.3 and vaporized .sup.99m TcO.sub.2 but will not cause the production of vaporized .sup.99 MoO.sub.3. The mixture is then combined with an oxidizing gas to generate a gaseous stream containing vaporized .sup.99m Tc.sub.2 O.sub.7. Next, the gaseous stream is cooled to a temperature sufficient to convert the vaporized .sup.99m Tc.sub.2 O.sub.7 into a condensed .sup.99m Tc-containing product. The product has high purity levels resulting from the use of reduced temperature conditions and ultrafine crystalline .sup.99 MoO.sub.3 starting materials with segregated .sup.99m Tc compositions therein which avoid the production of vaporized .sup.99 MoO.sub.3 contaminants.

  2. Method for generating a crystalline {sup 99}MoO{sub 3} product and the isolation {sup 99m}Tc compositions therefrom

    DOE Patents [OSTI]

    Bennett, R.G.; Christian, J.D.; Kirkham, R.J.; Tranter, T.J.

    1998-09-01T23:59:59.000Z

    An improved method is described for producing {sup 99m}Tc compositions. {sup 100}Mo metal is irradiated with photons in a particle (electron) accelerator to produce {sup 99}Mo metal which is dissolved in a solvent. A solvated {sup 99}Mo product is then dried to generate a supply of {sup 99}MoO{sub 3} crystals. The crystals are thereafter heated at a temperature which will sublimate the crystals and form a gaseous mixture containing vaporized {sup 99m}TcO{sub 3} and vaporized {sup 99m}TcO{sub 2} but will not cause the production of vaporized {sup 99}MoO{sub 3}. The mixture is then combined with an oxidizing gas to generate a gaseous stream containing vaporized {sup 99m}Tc{sub 2}O{sub 7}. Next, the gaseous stream is cooled to a temperature sufficient to convert the vaporized {sup 99m}Tc{sub 2}O{sub 7} into a condensed {sup 99m}Tc-containing product. The product has high purity levels resulting from the use of reduced temperature conditions and ultrafine crystalline {sup 99}MoO{sub 3} starting materials with segregated {sup 99m}Tc compositions therein which avoid the production of vaporized {sup 99}MoO{sub 3} contaminants. 1 fig.

  3. Synthesis, crystal structure, and structural conversion of Ni molybdate hydrate NiMoO{sub 4}.nH{sub 2}O

    SciTech Connect (OSTI)

    Eda, Kazuo, E-mail: eda@kobe-u.ac.j [Department of Chemistry, Graduate School of Science, Kobe University, Nada-ku, Kobe 657-8501 (Japan); Kato, Yasuyuki; Ohshiro, Yu; Sugitani, Takamitu [Department of Chemistry, Graduate School of Science, Kobe University, Nada-ku, Kobe 657-8501 (Japan); Whittingham, M. Stanley [Institute for Materials Research, State University of New York at Binghamton, Binghamton, NY 13902-6000 (United States)

    2010-06-15T23:59:59.000Z

    The synthesis and crystal structure of NiMoO{sub 4}.nH{sub 2}O were investigated. The hydrate crystallized in the triclinic system with space group P-1, Z=4 with unit cell parameters of a=6.7791(2) A, b=6.8900(2) A, c=9.2486(2) A, {alpha}=76.681(2){sup o}, {beta}=83.960(2){sup o}, {gamma}=74.218(2){sup o}. Its ideal chemical composition was NiMoO{sub 4}.3/4H{sub 2}O rather than NiMoO{sub 4}.1H{sub 2}O. Under hydrothermal conditions the hydrate turned directly into {alpha}-NiMoO{sub 4} above 483 K, giving nanorods thinner than the crystallites of the mother hydrate. On the other hand, it turned into Anderson type of polyoxomolybdate via a solid-solution process in a molybdate solution at room temperature. - Graphical abstract: NiMoO{sub 4}.nH{sub 2}O crystallized in the triclinic system with space group P-1, and its ideal chemical composition was NiMoO{sub 4}.3/4H{sub 2}O rather than NiMoO{sub 4}.1H{sub 2}O.

  4. Results of U-xMo (x=7, 10, 12 wt.%) Alloy versus Al-6061 Cladding Diffusion Couple Experiments Performed at 500, 550 and 600 Degrees C

    SciTech Connect (OSTI)

    Emmanuel Perez; Dennis D. Keiser, Jr.; Yongho Sohn

    2013-04-01T23:59:59.000Z

    The Reduced Enrichment for Research and Test Reactors (RERTR) program has been developing low enrichment fuel systems encased in Al 6061 for use in research and test reactors. U–Mo alloys in contact with Al and Al alloys can undergo diffusional interactions that can result in the development of interdiffusion zones with complex fine-grained microstructures composed of multiple phases. A monolithic fuel currently being developed by the RERTR program has local regions where the U–Mo fuel plate is in contact with the Al 6061 cladding and, as a result, the program finds information about interdiffusion zone development at high temperatures of interest. In this study, the microstructural development of diffusion couples consisting of U-7wt.%Mo, U-10wt.%Mo, and U-12wt.%Mo vs. Al 6061 (or 6061 aluminum) cladding, annealed at 500, 550, 600 degrees C for 1, 5, 20, 24, or 132 hours, was analyzed by backscatter electron microscopy and x-ray energy dispersive spectroscopy on a scanning electron microscope. Concentration profiles were determined by standardized wavelength dispersive spectroscopy and standardless x-ray energy dispersive spectroscopy. The results of this work shows that the presence of surface layers at the U–Mo/Al 6061 interface can dramatically impact the overall interdiffusion behavior in terms of rate of interaction and uniformity of the developed interdiffusion zones. It further reveals that relatively uniform interaction layers with higher Si concentrations can develop in U–Mo/Al 6061 couples annealed at shorter times and that longer times at temperature result in the development of more non-uniform interaction layers with more areas that are enriched in Al. At longer annealing times and relatively high temperatures, U–Mo/Al 6061 couples can exhibit more interaction compared to U–Mo/pure Al couples. The minor alloying constituents in Al 6061 cladding can result in the development of many complex phases in the interaction layer of U–Mo/Al–6061 cladding couples, and some phases in the interdiffusion zones of U–Mo/Al–6061 cladding couples are likely similar to those observed for U–Mo/pure Al couples.

  5. Cobalt-doped Bi{sub 26}Mo{sub 10}O{sub 69}: Crystal structure and conductivity

    SciTech Connect (OSTI)

    Mikhailovskaya, Z.A., E-mail: zozoikina@mail.ru [Ural Federal University, Lenin Ave. 51, 620000 Ekaterinburg (Russian Federation); Buyanova, E.S. [Ural Federal University, Lenin Ave. 51, 620000 Ekaterinburg (Russian Federation); Petrova, S.A. [Institute of Metallurgy, Ural Branch of the Russian Academy of Sciences, 101 Amundsen Str., 620016 Ekaterinburg (Russian Federation); Morozova, M.V.; Zhukovskiy, V.M. [Ural Federal University, Lenin Ave. 51, 620000 Ekaterinburg (Russian Federation); Zakharov, R.G. [Institute of Metallurgy, Ural Branch of the Russian Academy of Sciences, 101 Amundsen Str., 620016 Ekaterinburg (Russian Federation); Tarakina, N.V. [Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, 91 Pervomayskaya Str., 620990 Ekaterinburg (Russian Federation); Experimentelle Physik III, Physikalisches Institut and Wilhelm Conrad Röntgen—Research Centre for Complex Material Systems, Universität Würzburg, Am Hubland, D-97074 Würzburg (Germany); Berger, I.F. [Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, 91 Pervomayskaya Str., 620990 Ekaterinburg (Russian Federation)

    2013-08-15T23:59:59.000Z

    A series of cobalt-doped bismuth molybdates were synthesized and investigated using X-ray powder diffraction, transmission electron microscopy and impedance spectroscopy. The ranges of solid solution were determined. Two new compounds, Bi{sub 1?x}Co{sub x}[Bi{sub 12}O{sub 14}]Mo{sub 5}O{sub 34.5±?} (x=0.2) and Bi[Bi{sub 12}O{sub 14}]Mo{sub 5?y}Co{sub y}O{sub 34.5±?} (y=0.2), which crystallise in monoclinic unit cells have been examined in detail by diffraction methods. Impedance spectroscopy measurements show that the studied materials are good ionic conductors with conductivity values about 5×10{sup ?3} S×cm{sup ?1} at 973 K and 1.7×10{sup ?4} S×cm{sup ?1} at 623 K, which are similar to conductivity values of yttrium substituted zirconia and (YSZ) gadolinium doped ceria (CGO). - Graphical abstract: Measured and calculated diffraction spectra for Bi{sub 12.8}Co{sub 0.2}Mo{sub 5}O{sub 34±?} and projection of the Bi{sub 12.8}Co{sub 0.2}Mo{sub 5}O{sub 34±?} crystal structure onto the ac plane. Highlights: • The limit of the Bi{sub 1?x}Co{sub x}[Bi{sub 12}O{sub 14}]Mo{sub 5}O{sub 34.5±?} homogeneity range is equal to x=0.2. • The limit of the Bi[Bi{sub 12}O{sub 14}]Mo{sub 5?y}Co{sub y}O{sub 34.5±?} homogeneity range is equal to y=0.2. • Solid solutions have monoclinic symmetry. No phase transition is observed. • The conductivity at 700° for y=0.2 solid solutions is equal to ?lg ?, S×cm{sup ?1}=2.23. • The conductivity at 350° for y=0.2 solid solutions is equal to ?lg ?, S×cm{sup ?1}=3.74.

  6. High-efficiency superconducting nanowire single-photon detectors fabricated from MoSi thin-films

    E-Print Network [OSTI]

    Verma, V B; Bussières, F; Horansky, R D; Dyer, S D; Lita, A E; Vayshenker, I; Marsili, F; Shaw, M D; Zbinden, H; Mirin, R P; Nam, S W

    2015-01-01T23:59:59.000Z

    We demonstrate high-efficiency superconducting nanowire single-photon detectors (SNSPDs) fabricated from MoSi thin-films. We measure a maximum system detection efficiency (SDE) of 87 +- 0.5 % at 1542 nm at a temperature of 0.7 K, with a jitter of 76 ps, maximum count rate approaching 10 MHz, and polarization dependence as low as 3.4 +- 0.7 % The SDE curves show saturation of the internal efficiency similar to WSi-based SNSPDs at temperatures as high as 2.3 K. We show that at similar cryogenic temperatures, MoSi SNSPDs achieve efficiencies comparable to WSi-based SNSPDs with nearly a factor of two reduction in jitter.

  7. Calculation of Design Parameters for an Equilibrium LEU Core in the NBSR using a U7Mo Dispersion Fuel

    SciTech Connect (OSTI)

    Hanson A. L.; Diamond D.

    2014-06-30T23:59:59.000Z

    A plan is being developed for the conversion of the NIST research reactor (NBSR) from high-enriched uranium (HEU) fuel to low-enriched uranium (LEU) fuel. The LEU fuel may be a monolithic foil (LEUm) of U10Mo (10% molybdenum by weight in an alloy with uranium) or a dispersion of U7Mo in aluminum (LEUd). A previous report provided neutronic calculations for the LEUm fuel and this report presents the neutronics parameters for the LEUd fuel. The neutronics parameters for the LEUd fuel are compared to those previously obtained for the present HEU fuel and the proposed LEUm fuel. The results show no significant differences between the LEUm and the LEUd other than the LEUd fuel requires slightly less uranium than the LEUm fuel due to less molybdenum being present. The calculations include kinetics parameters, reactivity coefficients, reactivity worths of control elements and abnormal configurations, and power distributions under normal operation and with misloaded fuel elements.

  8. Continuous ultra-thin MoS{sub 2} films grown by low-temperature physical vapor deposition

    SciTech Connect (OSTI)

    Muratore, C. [Department of Chemical and Materials Engineering, University of Dayton, Dayton, Ohio 45469 (United States); Materials and Manufacturing Directorate, Air Force Research Laboratory, Wright-Patterson AFB, Ohio 45433 (United States); Hu, J. J.; Bultman, J. E.; Jespersen, M. L. [Materials and Manufacturing Directorate, Air Force Research Laboratory, Wright-Patterson AFB, Ohio 45433 (United States); University of Dayton Research Institute, Dayton, Ohio 45469 (United States); Wang, B.; Haque, M. A. [Department of Mechanical and Nuclear Engineering, Pennsylvania State University, College Park, Pennsylvania 16802 (United States); Shamberger, P. J.; McConney, M. E.; Naguy, R. D.; Voevodin, A. A. [Materials and Manufacturing Directorate, Air Force Research Laboratory, Wright-Patterson AFB, Ohio 45433 (United States)

    2014-06-30T23:59:59.000Z

    Uniform growth of pristine two dimensional (2D) materials over large areas at lower temperatures without sacrifice of their unique physical properties is a critical pre-requisite for seamless integration of next-generation van der Waals heterostructures into functional devices. This Letter describes a vapor phase growth technique for precisely controlled synthesis of continuous, uniform molecular layers of MoS{sub 2} on silicon dioxide and highly oriented pyrolitic graphite substrates of over several square centimeters at 350?°C. Synthesis of few-layer MoS{sub 2} in this ultra-high vacuum physical vapor deposition process yields materials with key optical and electronic properties identical to exfoliated layers. The films are composed of nano-scale domains with strong chemical binding between domain boundaries, allowing lift-off from the substrate and electronic transport measurements from contacts with separation on the order of centimeters.

  9. Feasibility study Part I - Thermal hydraulic analysis of LEU target for {sup 99}Mo production in Tajoura reactor

    SciTech Connect (OSTI)

    Bsebsu, F.M.; Abotweirat, F. [Reactor Department, Renewable Energies and Water Desalination Research Cente, P.O. Box 30878 Tajoura, Tripoli (Libyan Arab Jamahiriya)], E-mail: Bsebso@yahoo.com, E-mail: abutweirat@yahoo.com; Elwaer, S. [Radiochemistry Department, Renewable Energies and Water Desalination Research Cente, P.O. Box 30878 Tajoura, Tripoli (Libyan Arab Jamahiriya)], E-mail: samiwer@yahoo.com

    2008-07-15T23:59:59.000Z

    The Renewable Energies and Water Desalination Research Center (REWDRC), Libya, will implement the technology for {sup 99}Mo isotope production using LEU foil target, to obtain new revenue streams for the Tajoura nuclear research reactor and desiring to serve the Libyan hospitals by providing the medical radioisotopes. Design information is presented for LEU target with irradiation device and irradiation Beryllium (Be) unit in the Tajoura reactor core. Calculated results for the reactor core with LEU target at different level of power are presented for steady state and several reactivity induced accident situations. This paper will present the steady state thermal hydraulic design and transient analysis of Tajoura reactor was loaded with LEU foil target for {sup 99}Mo production. The results of these calculations show that the reactor with LEU target during the several cases of transient are in safe and no problems will occur. (author)

  10. Fano resonance and spectrally modified photoluminescence enhancement in monolayer MoS2 integrated with plasmonic nanoantenna array

    E-Print Network [OSTI]

    Lee, Bumsu; Han, Gang Hee; Ee, Ho-Seok; Naylor, Carl H; Liu, Wenjing; Johnson, A T Charlie; Agarwal, Ritesh

    2015-01-01T23:59:59.000Z

    The manipulation of light-matter interactions in two-dimensional atomically thin crystals is critical for obtaining new optoelectronic functionalities in these strongly confined materials. Here, by integrating chemically grown monolayers of MoS2 with a silver-bowtie nanoantenna array supporting narrow surface-lattice plasmonic resonances, a unique two-dimensional optical system has been achieved. The enhanced exciton-plasmon coupling enables profound changes in the emission and excitation processes leading to spectrally tunable, large photoluminescence enhancement as well as surface-enhanced Raman scattering at room temperature. Furthermore, at low temperatures, due to the decreased damping of MoS2 excitons interacting with the plasmonic resonances of the bowtie array, stronger exciton-plasmon coupling is achieved resulting in a Fano lineshape in the reflection spectrum. The Fano lineshape, which is due to the interference between the pathways involving the excitation of the exciton and plasmon, can be tuned ...

  11. Excitons in a mirror: Formation of “optical bilayers” using MoS{sub 2} monolayers on gold substrates

    SciTech Connect (OSTI)

    Mertens, Jan; Baumberg, Jeremy J., E-mail: jjb12@cam.ac.uk [Nanophotonics Centre, Cavendish Laboratory, University of Cambridge, Cambridge CB3 0HE (United Kingdom); Shi, Yumeng; Yang, Hui Ying, E-mail: yanghuiying@sutd.edu.sg [Pillar of Engineering Product Development, Singapore University of Technology and Design, Singapore 138682 (Singapore); Molina-Sánchez, Alejandro; Wirtz, Ludger [Physics and Materials Science Research Unit, University of Luxembourg, L-1511 Luxembourg (Luxembourg)

    2014-05-12T23:59:59.000Z

    We report coupling of excitons in monolayers of molybdenum disulphide to their mirror image in an underlying gold substrate. Excitons at the direct band gap are little affected by the substrate whereas strongly bound C-excitons associated with a van-Hove singularity change drastically. On quartz substrates only one C-exciton is visible (in the blue) but on gold substrates a strong red-shifted extra resonance in the green is seen. Exciton coupling to its image leads to formation of a “mirror biexciton” with enhanced binding energy. Estimates of this energy shift in an emitter-gold system match experiments well. The absorption spectrum of MoS{sub 2} on gold thus resembles a bilayer of MoS{sub 2} which has been created by optical coupling. Additional top-mirrors produce an “optical bulk.”.

  12. High temperature oxidation and NaCl-induced accelerated corrosion of hot-dip aluminized 9Cr-1Mo and 310 stainless steel 

    E-Print Network [OSTI]

    Tsaur, Charng-Cheng

    2005-02-17T23:59:59.000Z

    The behaviors of high temperature corrosion on hot-dip aluminized on 9Cr-1Mo and 310 stainless steels when catalyzed by NaCl and cyclic heating environment were studied experimentally. The corrosion behavior and morphological ...

  13. The Influence of Casting Conditions on the Microstructure of As-Cast U-10Mo Alloys: Characterization of the Casting Process Baseline

    SciTech Connect (OSTI)

    Nyberg, Eric A.; Joshi, Vineet V.; Lavender, Curt A.; Paxton, Dean M.; Burkes, Douglas

    2013-12-13T23:59:59.000Z

    Sections of eight plate castings of uranium alloyed with 10 wt% molybdenum (U-10Mo) were sent from Y-12 to the Pacific Northwest National Laboratory (PNNL) for microstructural characterization. This report summarizes the results from this study.

  14. SEM Characterization of the High Burn-up Microstructure of U-7Mo Alloy

    SciTech Connect (OSTI)

    Dennis D. Keiser, Jr.; Jan-Fong Jue; Jian Gan; Brandon Miller; Adam Robinson; Pavel Medvedev; James Madden; Dan Wachs; M. Teague

    2014-04-01T23:59:59.000Z

    During irradiation, the microstructure of U-7Mo evolves until at a fission density near 5x1021 f/cm3 a high-burnup microstructure exists that is very different than what was observed at lower fission densities. This microstructure is dominated by randomly distributed, relatively large, homogeneous fission gas bubbles. The bubble superlattice has collapsed in many microstructural regions, and the fuel grain sizes, in many areas, become sub-micron in diameter with both amorphous fuel and crystalline fuel present. Solid fission product precipitates can be found inside the fission gas bubbles. To generate more information about the characteristics of the high-fission density microstructure, three samples irradiated in the RERTR-7 experiment have been characterized using a scanning electron microscope equipped with a focused ion beam. The FIB was used to generate samples for SEM imaging and to perform 3D reconstruction of the microstructure, which can be used to look for evidence of possible fission gas bubble interlinkage.

  15. Search for neutrinoless double-beta decay of Mo 100 with the NEMO-3 detector

    SciTech Connect (OSTI)

    John D. Baker; A. J. Caffrey

    2014-06-01T23:59:59.000Z

    We report the results of a search for the neutrinoless double-ß decay (0?ßß ) of Mo 100 , using the NEMO-3 detector to reconstruct the full topology of the final state events. With an exposure of 34.7??kg·y , no evidence for the 0?ßß signal has been found, yielding a limit for the light Majorana neutrino mass mechanism of T 1/2 (0?ßß)>1.1×10 24 years (90% C.L.) once both statistical and systematic uncertainties are taken into account. Depending on the nuclear matrix elements this corresponds to an upper limit on the Majorana effective neutrino mass of ?m ? ?<0.3–0.9??eV (90% C.L.). Constraints on other lepton number violating mechanisms of 0?ßß decays are also given. Searching for high-energy double electron events in all suitable sources of the detector, no event in the energy region [3.2–10] MeV is observed for an exposure of 47??kg·y .

  16. Reply to [arXiv:1105.5653]: "Comment on 'Quasinormal modes in Schwarzschild-de Sitter spacetime: A simple derivation of the level spacing of the frequencies'"

    E-Print Network [OSTI]

    T. Roy Choudhury; T. Padmanabhan

    2011-05-31T23:59:59.000Z

    We explain why the analysis in our paper [Phys. Rev. D 69, 064033 (2004), arXiv:gr-qc/0311064 ] is relevant and correct.

  17. Nonlinear Raman Shift Induced by Exciton-to-Trion Transformation in Suspended Trilayer MoS2

    E-Print Network [OSTI]

    Taghinejad, Hossein; Tarasov, Alexey; Tsai, Meng-Yen; Hosseinnia, Amir H; Campbell, Philip M; Eftekhar, Ali A; Vogel, Eric M; Adibi, Ali

    2015-01-01T23:59:59.000Z

    Layered two-dimensional (2D) semiconductors such as molybdenum disulfide (MoS2) have recently attracted remarkable attention because of their unique physical properties. Here, we use photoluminescence (PL) and Raman spectroscopy to study the formation of the so- called trions in a synthesized freestanding trilayer MoS2. A trion is a charged quasi-particle formed by adding one electron or hole to a neutral exciton (a bound electron-hole pair). We demonstrate accurate control over the transformation of excitons to trions by tuning the power of the optical pump (laser). Increasing the power of the excitation laser beyond a certain threshold (~ 4 mW) allows modulation of trion-to-exciton PL intensity ratio as well as the spectral linewidth of both trions and excitons. Via a systematic and complementary Raman analysis we disclose a strong coupling between laser induced exciton-to-trion transformation and the characteristic phononic vibrations of MoS2. The onset of such an optical transformation corresponds to the ...

  18. Investigation of (110)Mo, (110)W monocrystals and Nb polycrystal implanted by oxygen ions and used as TEC electrodes

    SciTech Connect (OSTI)

    Tsakadze, L.M.

    1995-12-31T23:59:59.000Z

    In an effort to improve efficiency of a thermionic energy converter (TEC), converting thermal power into electric power, there were investigated collectors made of (110)Mo and (110)W monocrystals, and Nb polycrystal, all being implanted by oxygen ions with fluence of 1*10{sup 18} cm{sup {minus}2}. For emitters there were used (110)Mo and (110)W monocrystals, and Nb polycrystal implanted by oxygen ions, respectively. The performance of TEC with implanted electrode material is compared with this of TEC having electrodes of non-implanted materials. It is demonstrated that for emitter temperature range of 1,473 to 1,873 K employment of (110)Mo and (110)W monocrystals, implanted by oxygen ions, for TEC collector allows to increase the specific output power of a converter approximately by a factor of 1.6, and employment of implanted Nb for electrodes -- to increase this value approximately by a factor of 3, as compared with non-implanted electrode materials. The upgraded performance of TEC with implanted electrode materials is caused by the increase of minimum values of the collector working function by {approximately}0.15--0.2 eV as compared with non-implanted collectors, as well as by improvement of emitter emissive and adsorption properties due to oxygen supply from collectors at operating temperatures.

  19. Reconfigurable p-n junction diodes and the photovoltaic effect in exfoliated MoS{sub 2} films

    SciTech Connect (OSTI)

    Sutar, Surajit; Agnihotri, Pratik; Comfort, Everett; Ung Lee, Ji, E-mail: jlee1@albany.edu [The College of Nanoscale Science and Engineering (CNSE), SUNY at Albany, Albany, New York 12203 (United States); Taniguchi, T.; Watanabe, K. [National Institute of Materials Science, 1-2-1 Sengen, Tsukuba-city, Ibaraki 305-0047 (Japan)

    2014-03-24T23:59:59.000Z

    Realizing basic semiconductor devices such as p-n junctions are necessary for developing thin-film and optoelectronic technologies in emerging planar materials such as MoS{sub 2}. In this work, electrostatic doping by buried gates is used to study the electronic and optoelectronic properties of p-n junctions in exfoliated MoS{sub 2} flakes. Creating a controllable doping gradient across the device leads to the observation of the photovoltaic effect in monolayer and bilayer MoS{sub 2} flakes. For thicker flakes, strong ambipolar conduction enables realization of fully reconfigurable p-n junction diodes with rectifying current-voltage characteristics, and diode ideality factors as low as 1.6. The spectral response of the photovoltaic effect shows signatures of the predicted band gap transitions. For the first excitonic transition, a shift of >4{sub kB}T is observed between monolayer and bulk devices, indicating a thickness-dependence of the excitonic coulomb interaction.

  20. Electronic structure of the 4d transition metal carbides: Dispersed fluorescence spectroscopy of MoC, RuC, and PdC

    E-Print Network [OSTI]

    Morse, Michael D.

    C, RuC, and PdC Ryan S. DaBell,a) Raymond G. Meyer,b) and Michael D. Morsec) Department of Chemistry fluorescence studies of the diatomic molecules MoC, RuC, and PdC are reported. New states identified in Mo are observed by dispersed fluorescence in PdC. The ground state is found to be ... 2 4 12 2 , 1