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Note: This page contains sample records for the topic "mn nh nj" from the National Library of EnergyBeta (NLEBeta).
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1

NJ.?3  

Office of Legacy Management (LM)

r-2 r-2 . . . * c J/y. a5 NJ.?3 ti I "( -r par 7 This docam& consists of 3tiHpages, ~$0. .F of 2' topics, Series A WY/~ F/yS. 5 2 --s.d %6/e /. Prospectus On Uranium Center Operation Speciri! Rcreview FInsI Dctei mmaiion February 1, 1951 # A. L. Baker President THE KELLEX CORPORATION 233 BROADWAY NEW YORK 7, N.Y. "CAUTION" This document contains information affecting the National Defense of the Ulliterl :JI.F~*?s. ~. _________-.-.. ___-.-~~ -- . CONTENTS " ' -' P F. Brown INTRODUCTION ............................................ Page 5 PROPOSED PROGRAM ...................................... 7 Contract Scope ....................................... 7 Corporate Mechanism ................................. 8 Contract Terms ...................................... 9

2

Growth kinetics and micromorphology of NH{sub 4}Cl:Mn{sup 2+} crystals formed in the NH{sub 4}Cl-MnCl{sub 2}-H{sub 2}O-CONH{sub 3} system  

Science Conference Proceedings (OSTI)

The growth kinetics and elementary growth processes on the surface of NH{sub 4}Cl:Mn{sup 2+} heterogeneous crystals formed in the NH{sub 4}Cl-MnCl{sub 2}-H{sub 2}O-CONH{sub 3} system are experimentally studied. It is found that a change in the composition of complexes in an NH{sub 4}Cl crystal from Mn(NH{sub 4}){sub 2}Cl{sub 4} {center_dot} 2H{sub 2}O to MnCl{sub 2} {center_dot} 2CONH{sub 3} leads to the occurrence of a local maximum in the kinetic curve and a change in the shape of dislocation growth centers from flat to conical. The growth kinetics of {l_brace}100{r_brace} faces of heterogeneous NH{sub 4}Cl:Mn{sup 2+} crystals is described within the Bliznakov model using the Fowler-Guggenheim adsorption isotherm, which takes into account the lateral interaction of adsorbed particles.

Pyankova, L. A., E-mail: lyuba_pyan@mail.ru; Punin, Yu. O.; Bocharov, S. N.; Shtukenberg, A. G. [Petersburg State University (Russian Federation)

2012-03-15T23:59:59.000Z

3

DOE - Office of Legacy Management -- Middlesex North NJ Site - NJ 05  

Office of Legacy Management (LM)

Middlesex North NJ Site - NJ 05 Middlesex North NJ Site - NJ 05 FUSRAP Considered Sites Middlesex North, NJ Alternate Name(s): Middlesex Landfill Middlesex Municipal Landfill NJ.05-2 NJ.05-4 Location: Mountain Avenue to Bound Brook, Middlesex, New Jersey NJ.05-2 Historical Operations: Served as a disposal site for low-level radioactive pitchblende ore generated from activites at the Middlesex Sampling Plant. NJ.05-2 NJ.05-3 Eligibility Determination: Eligible NJ.05-1 Radiological Survey(s): Assessment Surveys NJ.05-3 NJ.05-4 Site Status: Certification Basis and Federal Register Notice. USACE determination for additional remediation is pending. NJ.05-5 NJ.05-6 Long-term Care Requirements: Long-Term Surveillance and Maintenance Requirements for Remediated FUSRAP Sites S07566_FUSRAP

4

Grow NJ (New Jersey) | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Grow NJ (New Jersey) Grow NJ (New Jersey) Eligibility Commercial Savings For Alternative Fuel Vehicles Hydrogen & Fuel Cells Buying & Making Electricity Water Home Weatherization...

5

DOE - Office of Legacy Management -- New Brunswick NJ Site - NJ 14  

Office of Legacy Management (LM)

Brunswick NJ Site - NJ 14 Brunswick NJ Site - NJ 14 FUSRAP Considered Sites New Brunswick, NJ Alternate Name(s): New Brunswick Laboratory NJ.14-1 Location: 986 Jersey Avenue, New Brunswick, New Jersey NJ.14-2 Historical Operations: Performed radiochemical analyses on uranium, thorium, beryllium, and zirconium metals and compounds for MED, AEC, ERDA, and DOE to support nuclear power and weapons programs. NJ.14-3 NJ.14-5 Eligibility Determination: Eligible NJ.14-1 Radiological Survey(s): Assessment Surveys, Verification Surveys NJ.14-2 NJ.14-4 NJ.14-6 Site Status: Certification Basis, Federal Register Notice Included NJ.14-5 Long-term Care Requirements: Long-Term Surveillance and Maintenance Requirements for Remediated FUSRAP Sites S07566_FUSRAP Also see New Brunswick, New Jersey, Site

6

DOE - Office of Legacy Management -- Maywood Site - NJ 10  

Office of Legacy Management (LM)

Maywood Site - NJ 10 Maywood Site - NJ 10 FUSRAP Considered Sites Maywood, NJ Alternate Name(s): Maywood Chemical Works Maywood Chemical Company Maywood Interim Storage Site (MISS) Stepan Chemical Company NJ.10-2 NJ.10-3 NJ.10-7 NJ.10-11 Location: 100 West Hunter Avenue, Maywood/Rochelle Park, New Jersey NJ.10-4 Historical Operations: Processed monazite sands for extraction of rare earth compounds and mantle-grade thorium nitrates. NJ.10-2 NJ.10-3 NJ.10-4 NJ.10-5 Eligibility Determination: Eligible NJ.10-1 NJ.10-10 Radiological Survey(s): Assessment Surveys NJ.10-6 NJ.10-7 NJ.10-8 Site Status: Cleanup in progress by U.S. Army Corps of Engineers. NJ.10-9 NJ.10-13 USACE FUSRAP Long-term Care Requirements: To be determined upon completion. Also see FUSRAP Maywood Superfund Site

7

DOE - Office of Legacy Management -- Jersey City NJ Site - NJ 07  

NLE Websites -- All DOE Office Websites (Extended Search)

Jersey City NJ Site - NJ 07 Jersey City NJ Site - NJ 07 FUSRAP Considered Sites Jersey City, NJ Alternate Name(s): Kellex Laboratory Jersey City Laboratory Kellex/Pierpont Vitro Corporation of America Delco-Levco Pierpont Property M.W. Kellogg Site NJ.07-1 NJ.07-2 NJ.07-6 Location: New Jersey Route 440 and Kellogg Street, Jersey City, New Jersey NJ.07-5 Historical Operations: Conducted research and development for MED and AEC on gaseous diffusion process for uranium enrichment using uranium hexaflouride and solvent extraction process for uranium recovery from ores. Also conducted solvent extraction of uranium and other byproducts from waste. Processes resulted in contamination of uranium, radium, and thorium. NJ.07-3 NJ.07-5 Eligibility Determination: Radiological Survey(s): Assessment Survey, Verification Survey NJ.07-4

8

Palmco Power NJ, LLC | Open Energy Information  

Open Energy Info (EERE)

Palmco Power NJ, LLC Jump to: navigation, search Name Palmco Power NJ, LLC Place New York Utility Id 56501 Utility Location Yes Ownership R Operates Generating Plant Yes References...

9

SolarWorks NJ | Open Energy Information  

Open Energy Info (EERE)

Jersey Sector Renewable Energy, Solar Product SolarWorks NJ, LLC, a provider of turnkey solar electricity installations and renewable energy solutions. References SolarWorks...

10

DOE - Office of Legacy Management -- Princeton University - NJ 08  

NLE Websites -- All DOE Office Websites (Extended Search)

Princeton University - NJ 08 Princeton University - NJ 08 FUSRAP Considered Sites Site: PRINCETON UNIVERSITY (NJ.08) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: Princeton , New Jersey NJ.08-1 Evaluation Year: 1985 NJ.08-2 Site Operations: During 1940's, performed experiments on uranium isotope separation and experiments for the development of diffusion barrier material for the gaseous diffusion enrichment process. NJ.08-2 Site Disposition: Eliminated - Radiation levels below criteria NJ.08-1 NJ.08-2 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled: Uranium NJ.08-2 NJ.08-3 Radiological Survey(s): Yes NJ.08-1 NJ.08-4 Site Status: Eliminated from consideration under FUSRAP Also see Documents Related to PRINCETON UNIVERSITY

11

Tracking the Sun IV: An Historical Summary of the Installed Cost of Photovoltaics in the United States from 1998 to 2010  

E-Print Network (OSTI)

Energy Grant Program MN MSEO Solar Electric Rebate Program NH NHPUC Renewable Energy Rebate Program NJ

Darghouth, Naim

2012-01-01T23:59:59.000Z

12

Northeast - NY NJ CT PA Area | Open Energy Information  

Open Energy Info (EERE)

Northeast - NY NJ CT PA Area Northeast - NY NJ CT PA Area (Redirected from New York Area - NY NJ CT PA) Jump to: navigation, search Contents 1 Clean Energy Clusters in the Northeast - NY NJ CT PA Area 1.1 Products and Services in the Northeast - NY NJ CT PA Area 1.2 Research and Development Institutions in the Northeast - NY NJ CT PA Area 1.3 Networking Organizations in the Northeast - NY NJ CT PA Area 1.4 Investors and Financial Organizations in the Northeast - NY NJ CT PA Area 1.5 Policy Organizations in the Northeast - NY NJ CT PA Area Clean Energy Clusters in the Northeast - NY NJ CT PA Area Products and Services in the Northeast - NY NJ CT PA Area Loading map... {"format":"googlemaps3","type":"ROADMAP","types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"limit":500,"offset":0,"link":"all","sort":[""],"order":[],"headers":"show","mainlabel":"","intro":"","outro":"","searchlabel":"\u2026

13

Valero Refining Company - NJ | Open Energy Information  

Open Energy Info (EERE)

Valero Refining Company - NJ Valero Refining Company - NJ Jump to: navigation, search Name Valero Refining Company - NJ Place New Jersey Utility Id 56325 Utility Location Yes Ownership R Operates Generating Plant Yes Activity Retail Marketing Yes References EIA Form EIA-861 Final Data File for 2010 - File1_a[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Utility Rate Schedules Grid-background.png No rate schedules available. Average Rates Industrial: $0.0652/kWh References ↑ "EIA Form EIA-861 Final Data File for 2010 - File1_a" Retrieved from "http://en.openei.org/w/index.php?title=Valero_Refining_Company_-_NJ&oldid=411921" Categories: EIA Utility Companies and Aliases

14

Northeast - NY NJ CT PA Area | Open Energy Information  

Open Energy Info (EERE)

Northeast - NY NJ CT PA Area Northeast - NY NJ CT PA Area Jump to: navigation, search Contents 1 Clean Energy Clusters in the Northeast - NY NJ CT PA Area 1.1 Products and Services in the Northeast - NY NJ CT PA Area 1.2 Research and Development Institutions in the Northeast - NY NJ CT PA Area 1.3 Networking Organizations in the Northeast - NY NJ CT PA Area 1.4 Investors and Financial Organizations in the Northeast - NY NJ CT PA Area 1.5 Policy Organizations in the Northeast - NY NJ CT PA Area Clean Energy Clusters in the Northeast - NY NJ CT PA Area Products and Services in the Northeast - NY NJ CT PA Area Loading map... {"format":"googlemaps3","type":"ROADMAP","types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"limit":500,"offset":0,"link":"all","sort":[""],"order":[],"headers":"show","mainlabel":"","intro":"","outro":"","searchlabel":"\u2026

15

DOE - Office of Legacy Management -- Bloomfield Tool Co - NJ 21  

Office of Legacy Management (LM)

Bloomfield Tool Co - NJ 21 Bloomfield Tool Co - NJ 21 FUSRAP Considered Sites Site: Bloomfield Tool Co. (NJ.21 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: Bloomfield , New Jersey NJ.21-1 Evaluation Year: 1987 NJ.21-2 Site Operations: During a small-scale experiment, uranium slugs were machined. NJ.21-3 Site Disposition: Eliminated - Potential for contamination considered remote due to limited scope and duration of the operations NJ.21-4 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled: Uranium NJ.21-2 NJ.21-3 Radiological Survey(s): None Indicated Site Status: Eliminated from consideration under FUSRAP Also see Documents Related to Bloomfield Tool Co. NJ.21-1 - AEC Memorandum; Reichard to Files; Visit to Bloomfield

16

DOE - Office of Legacy Management -- Heyden Chemical Corp - NJ 19  

Office of Legacy Management (LM)

Heyden Chemical Corp - NJ 19 Heyden Chemical Corp - NJ 19 FUSRAP Considered Sites Site: Heyden Chemical Corp. (NJ.19 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: American Cyanamid NJ.19-2 Location: Princeton , New Jersey NJ.19-1 Evaluation Year: 1987 NJ.19-1 Site Operations: Commercial chemical operation. AEC was interested in their process for keeping thorium oxide in suspension. No indication of AEC contractual relationship with Heyden. NJ.19-1 NJ.19-3 Site Disposition: Eliminated - No indication of AEC operations conducted on the site NJ.19-1 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled: Thorium Oxide NJ.19-2 Radiological Survey(s): None Indicated Site Status: Eliminated from consideration under FUSRAP

17

DOE - Office of Legacy Management -- Navy Ammunition Depot - NJ 15  

Office of Legacy Management (LM)

Navy Ammunition Depot - NJ 15 Navy Ammunition Depot - NJ 15 FUSRAP Considered Sites Site: NAVY AMMUNITION DEPOT (NJ.15) Eliminated from further consideration under FUSRAP - Referred to DOD Designated Name: Not Designated Alternate Name: None Location: Earle, New Jersey NJ.15-1 Evaluation Year: 1987 NJ.15-2 Site Operations: Storage facility and disposal unit for drummed radioactive waste that was dumped at sea. NJ.15-1 Site Disposition: Eliminated - Referred to DOD NJ.15-2 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled: Radioactive Waste Materials NJ.15-2 Radiological Survey(s): None Indicated Site Status: Eliminated from further consideration under FUSRAP - Referred to DOD NJ.15-2 Also see Documents Related to NAVY AMMUNITION DEPOT NJ.15-1 - AEC Memorandum; Piccot to the Files; Subject: Visit to

18

DOE - Office of Legacy Management -- Wayne Site - NJ 16  

Office of Legacy Management (LM)

Wayne Site - NJ 16 Wayne Site - NJ 16 FUSRAP Considered Sites Wayne, NJ Alternate Name(s): Wayne Interim Storage Site (WISS) W.R. Grace and Company W.R. Grace Site Rare Earths, Inc. Davison Chemical Division NJ.16-1 NJ.16-2 NJ.16-3 Location: 868 Black Oak Road, Wayne, New Jersey NJ.16-5 Historical Operations: Produced crude thorium hydroxide and rare earth elements from monazite sands. Site was also used for interim storage of contaminated material removed from vicinity properties under FUSRAP. NJ.16-5 Eligibility Determination: Eligible NJ.16-1 NJ.16-11 Radiological Survey(s): Assessment Surveys NJ.16-3 NJ.16-6 NJ.16-7 NJ.16-8 NJ.16-9 Site Status: USACE cleanup complete, not yet delisted from the National Priorities List. USACE Website EPA Website Long-term Care Requirements: Long-Term Surveillance and Maintenance Requirements for Remediated FUSRAP Sites S07566_FUSRAP

19

Category:Atlantic City, NJ | Open Energy Information  

Open Energy Info (EERE)

NJ NJ Jump to: navigation, search Go Back to PV Economics By Location Media in category "Atlantic City, NJ" The following 16 files are in this category, out of 16 total. SVFullServiceRestaurant Atlantic City NJ Public Service Elec & Gas Co.png SVFullServiceRestauran... 63 KB SVMidriseApartment Atlantic City NJ Public Service Elec & Gas Co.png SVMidriseApartment Atl... 62 KB SVQuickServiceRestaurant Atlantic City NJ Public Service Elec & Gas Co.png SVQuickServiceRestaura... 64 KB SVSecondarySchool Atlantic City NJ Public Service Elec & Gas Co.png SVSecondarySchool Atla... 62 KB SVStandAloneRetail Atlantic City NJ Public Service Elec & Gas Co.png SVStandAloneRetail Atl... 63 KB SVHospital Atlantic City NJ Public Service Elec & Gas Co.png

20

DOE - Office of Legacy Management -- Bowen Lab - NJ 33  

NLE Websites -- All DOE Office Websites (Extended Search)

Bowen Lab - NJ 33 Bowen Lab - NJ 33 FUSRAP Considered Sites Site: Bowen Lab (NJ.33) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: Bowen Engineering, Inc. NJ.33-1 Location: North Branch , New Jersey NJ.33-1 Evaluation Year: Circa 1990 NJ.33-2 Site Operations: Test runs of spray calcining of boiled down pitchblende raffinates was conducted on May 15 and 16, 1951. Equipment used was decontaminated on May 17. NJ.33-1 Site Disposition: Eliminated - Potential for contamination considered remote due to the limited quantities of material used and the duration of the tests, and subsequent cleanup of the site following the tests. NJ.33-2 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled: Uranium NJ.33-1

Note: This page contains sample records for the topic "mn nh nj" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

NJ WY AK AL CA AR CO CT DE FL GA HI ID KS IL IN IA IA KY LA  

Gasoline and Diesel Fuel Update (EIA)

0.00-1.99 0.00-1.99 2.00-2.99 3.00-3.99 4.00-4.99 5.00-5.99 6.00-6.99 7.00+ NJ WY AK AL CA AR CO CT DE FL GA HI ID KS IL IN IA IA KY LA ME MI MA MD MN MS MT MO NE ND OH NV NM NY NH NC OK OR PA RI SC SD TN TX UT VT WA WV WI AZ VA DC 0.00-1.99 2.00-2.99 3.00-3.99 4.00-4.99 5.00-5.99 6.00-6.99 7.00+ 18. Average Price of Natural Gas Delivered to U.S. Onsystem Industrial Consumers, 1996 (Dollars per Thousand Cubic Feet) Figure 19. Average Price of Natural Gas Delivered to U.S. Electric Utilities, 1996 (Dollars per Thousand Cubic Feet) Figure Sources: Federal Energy Regulatory Commission (FERC), Form FERC-423, "Monthly Report of Cost and Quality of Fuels for Electric Plants," and Energy Information Administration (EIA), Form EIA-176, "Annual Report of Natural and Supplemental Gas Supply and Disposition." Note: In 1996, consumption of natural gas for agricultural use

22

DOE - Office of Legacy Management -- Bakelite Corp - NJ 35  

Office of Legacy Management (LM)

Bakelite Corp - NJ 35 Bakelite Corp - NJ 35 FUSRAP Considered Sites Site: Bakelite Corp (NJ 35) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: Bound Brook , New Jersey NJ.35-1 Evaluation Year: 1986 NJ.35-1 Site Operations: Processed nickel metal and various chemicals in support of the K-25 plant. No indication that radioactive materials were handled. NJ.35-1 Site Disposition: Eliminated - No indication that radioactive material was used at the site NJ.35-1 Radioactive Materials Handled: No Primary Radioactive Materials Handled: None Radiological Survey(s): None Indicated Site Status: Eliminated from consideration under FUSRAP Also see Documents Related to Bakelite Corp NJ.35-1 - DOE Checklist/Memorandum; D.Levine to the File; Subject:

23

DOE - Office of Legacy Management -- Fairmont Chemical Co - NJ 25  

Office of Legacy Management (LM)

Fairmont Chemical Co - NJ 25 Fairmont Chemical Co - NJ 25 FUSRAP Considered Sites Site: Fairmont Chemical Co. (NJ.25 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: Newark , New Jersey NJ.25-1 Evaluation Year: 1987 NJ.25-1 Site Operations: Company was a commercial chemical company identified as a rare earths processor (hafnium). NJ.25-1 Site Disposition: Eliminated - Potential for contamination remote NJ.25-1 Radioactive Materials Handled: None Indicated Primary Radioactive Materials Handled: None Indicated Radiological Survey(s): None Indicated Site Status: Eliminated from consideration under FUSRAP Also see Documents Related to Fairmont Chemical Co. NJ.25-1 - DOE Memorandum/Checklist; Wallo to File; Fairmont Chemical

24

DOE - Office of Legacy Management -- Tube Reducing Co - NJ 11  

Office of Legacy Management (LM)

experiments involving the sizing and reduction of rolled Uranium rod by the "Rockrite Process" for National Lead Company of Ohio. NJ.11-1 NJ.11-4 Site Disposition: Eliminated -...

25

Palmco Power NJ, LLC (New Jersey) | Open Energy Information  

Open Energy Info (EERE)

NJ, LLC (New Jersey) Jump to: navigation, search Name Palmco Power NJ, LLC Place New Jersey Utility Id 56501 References EIA Form EIA-861 Final Data File for 2010 - File220101...

26

NJ WY AK AL CA AR CO CT DE FL GA HI ID KS IL IN IA IA KY LA  

Gasoline and Diesel Fuel Update (EIA)

176, "Annual Report of Natural and Supplemental Gas Supply and Disposition." NJ WY AK AL CA AR CO CT DE FL GA HI ID KS IL IN IA IA KY LA ME MI MA MD MN MS MT MO NE ND OH NV NM NY...

27

DOE - Office of Legacy Management -- E I Du Pont - NJ 06  

Office of Legacy Management (LM)

- NJ 06 - NJ 06 FUSRAP Considered Sites E.I. Dupont, NJ Alternate Name(s): E.I. Du Pont De Nemours and Company E.I. Du Pont Company Dupont Chambers Works Plant NJ.06-1 NJ.06-5 Location: Pennsville and Carney Townships, Southeast bank of the Delaware River, Deepwater, New Jersey NJ.06-5 Historical Operations: Development of a process for converting uranium oxide to uranium tetraflouride, production of uranium tetraflouride, research into conversion of uranium oxide to uranium metal, and production of uranium metal. NJ.06-3 NJ.06-5 Eligibility Determination: Eligible NJ.06-1 Radiological Survey(s): Assessment Surveys NJ.06-3 NJ.06-5 NJ.06-7 NJ.06-8 Site Status: Cleanup in progress by U.S. Army Corps of Engineers. NJ.06-2 NJ.06-6 USACE Website Long-term Care Requirements: To be determined upon completion.

28

DOE - Office of Legacy Management -- Aluminum Co of America - NJ 24  

Office of Legacy Management (LM)

NJ 24 NJ 24 FUSRAP Considered Sites Site: Aluminum Co of America (NJ.24 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: ALCOA (Garwood Plant) NJ.24-1 Location: Garwood , New Jersey NJ.24-1 Evaluation Year: Circa 1987 NJ.24-5 Site Operations: Constructed and altered die-casting dies and conducted die casting operation on uranium slugs. NJ.24-1 NJ.24-3 NJ.24-4 Site Disposition: Eliminated - Potential for residual contamination considered remote due to limited scope of activities performed at the site NJ.24-2 NJ.24-5 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled: Uranium metal NJ.24-1 NJ.24-3 NJ.24-4 Radiological Survey(s): None Indicated Site Status: Eliminated from consideration under FUSRAP

29

DOE - Office of Legacy Management -- J T Baker Chemical Co - NJ 0-02  

Office of Legacy Management (LM)

J T Baker Chemical Co - NJ 0-02 J T Baker Chemical Co - NJ 0-02 FUSRAP Considered Sites Site: J.T. BAKER CHEMICAL CO. ( NJ.0-02 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: Subsidiary of Vick Chemical Company NJ.0-02-1 Location: 600 North Broad Street , Phillipsburg , New Jersey NJ.0-02-2 Evaluation Year: 1987 NJ.0-02-3 Site Operations: Commercial operation - licensed to process and distribute refined source material. NJ.0-02-2 NJ.0-02-3 NJ.0-02-4 NJ.0-02-5 Site Disposition: Eliminated - No basis for inclusion in FUSRAP NJ.0-02-3 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled: Uranium NJ.0-02-5 NJ.0-02-6 Radiological Survey(s): None Indicated Site Status: Eliminated from consideration under FUSRAP

30

DOE - Office of Legacy Management -- Vitro Corp of America - NJ 02  

Office of Legacy Management (LM)

NJ 02 NJ 02 FUSRAP Considered Sites Site: Vitro Corp. of America (NJ.02) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: Vitro Laboratories NJ.02-1 Location: West Orange , New Jersey NJ.02-2 Evaluation Year: 1985 NJ.02-3 Site Operations: Performed work that involved conversion of low enrichment uranium dioxide to uranium carbon spheres and for the separation of fission products. NJ.02-3 NJ.02-4 Site Disposition: Eliminated - Radiation levels below criteria NJ.02-2 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled: Uranium Compounds NJ.02-2 NJ.02-4 Radiological Survey(s): Yes NJ.02-2 Site Status: Eliminated from consideration under FUSRAP Also see Documents Related to Vitro Corp. of America

31

DOE - Office of Legacy Management -- Metals Disintegrating Co Inc - NJ 0-03  

Office of Legacy Management (LM)

Disintegrating Co Inc - NJ Disintegrating Co Inc - NJ 0-03 FUSRAP Considered Sites Site: METALS DISINTEGRATING CO., INC. (NJ.0-03 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: 271 Grove Avenue , Verona or Elizabeth , New Jersey NJ.0-03-1 NJ.0-03-2 NJ.0-03-3 Evaluation Year: 1987 NJ.0-03-3 Site Operations: Provided nickel to Linde. NJ.0-03-3 NJ.0-03-4 Site Disposition: Eliminated - No radioactive materials were handled at this site. NJ.0-03-3 Radioactive Materials Handled: None Indicated Primary Radioactive Materials Handled: None Indicated Radiological Survey(s): None Indicated Site Status: Eliminated from consideration under FUSRAP Also see Documents Related to METALS DISINTEGRATING CO., INC. NJ.0-03-1 - Letter; Goman to Metals Disintegrating Company, Inc.

32

DOE - Office of Legacy Management -- Baker and Williams Co - NJ 13  

NLE Websites -- All DOE Office Websites (Extended Search)

Baker and Williams Co - NJ 13 Baker and Williams Co - NJ 13 FUSRAP Considered Sites Site: Baker and Williams Co (NJ 13) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: Baker and Company, Inc. Engelhard Industries, Baker Platinum Division NJ.13-8 NJ.13-1 Location: 113 Astor Street , Newark , New Jersey NJ.13-1 NJ.13-8 Evaluation Year: 1990 NJ.13-2 NJ.13-7 Site Operations: From 1943 through the mid-1950s, the facility processed spent catalyst (contaminated platinum) to recovery the platinum for the AEC. From the Mid-1950s to the early-1960s the facility conducted research and development on metal fabrication processes including rolling, drawing uranium metal metals continued recovery operations (uranium from scrap under AEC source material license). NJ.13-3

33

DOE - Office of Legacy Management -- United Lead Co - NJ 29  

NLE Websites -- All DOE Office Websites (Extended Search)

Lead Co - NJ 29 Lead Co - NJ 29 FUSRAP Considered Sites Site: United Lead Co. (NJ.29 ) Designated Name: Alternate Name: Location: Evaluation Year: Site Operations: Site Disposition: Radioactive Materials Handled: Primary Radioactive Materials Handled: Radiological Survey(s): Site Status: This site is one of a group of 77 FUSRAP considered sites for which few, if any records are available in their respective site files to provide an historical account of past operations and their relationship, if any, with MED/AEC operations. Reviews of contact lists, accountable station lists, health and safety records and other documentation of the period do not provide sufficient information to warrant further search of historical records for information on these sites. These site files remain "open" to

34

DOE - Office of Legacy Management -- New York Shipbuilding Corp - NJ 34  

Office of Legacy Management (LM)

Shipbuilding Corp - NJ 34 Shipbuilding Corp - NJ 34 FUSRAP Considered Sites Site: NEW YORK SHIPBUILDING CORP. (NJ.34) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: South Yard, New York Shipbuilding facility on the Delaware River , Camden , New Jersey NJ.34-1 Evaluation Year: Circa 1990 NJ.34-2 Site Operations: NYX Project (1951 - 1954) - fabricated and assembled equipment (reactors) for the AEC Savannah River Plant under subcontract to AEC Prime. Later built the N.S. Savannah, the world's first nuclear-powered cargo-passenger ship -- a joint project of the AEC and the Maritime Administration authorized by the Congress in 1956. NJ.34-1 NJ.34-3 Site Disposition: Eliminated - Potential for contamination related to work for Savannah River Plant considered remote due to the limited quantity of radioactive material involved and duration of the activity NJ.34-2

35

NJ Regional Middle School Science Bowl | Princeton Plasma Physics Lab  

NLE Websites -- All DOE Office Websites (Extended Search)

February 22, 2013, 8:00am February 22, 2013, 8:00am Science Education Lab-wide Event NJ Regional Middle School Science Bowl Teams of students are invited to participate in the Department of Energy's National Science Bowl Competition. Each year PPPL hosts the New Jersey Regional Science Bowl which decides which teams from the local area can continue onto the national competition in Washington, D.C. The Science Bowl is a double elimination contest with oral question and answer rounds in the fields of chemistry, biology, physics, astronomy and mathematics plus general and earth sciences. Questions are given in a toss-up with a bonus format. For more information, visit our Science Bowl website! Contact Information Website: NJ Regional Middle School Science Bowl Coordinator(s): Deedee Ortiz

36

New Jersey Solar Power LLC NJ Solar Power | Open Energy Information  

Open Energy Info (EERE)

Solar Power LLC NJ Solar Power Solar Power LLC NJ Solar Power Jump to: navigation, search Name New Jersey Solar Power LLC (NJ Solar Power) Place New Jersey Sector Solar Product A photovoltaic engineering firm which offers and installs a complete line of solar electric products for residential, commercial, and institutional customers. References New Jersey Solar Power LLC (NJ Solar Power)[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. New Jersey Solar Power LLC (NJ Solar Power) is a company located in New Jersey . References ↑ "New Jersey Solar Power LLC (NJ Solar Power)" Retrieved from "http://en.openei.org/w/index.php?title=New_Jersey_Solar_Power_LLC_NJ_Solar_Power&oldid=349171

37

Help in N.J. for Those Struggling with Energy Costs | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Help in N.J. for Those Struggling with Energy Costs Help in N.J. for Those Struggling with Energy Costs Help in N.J. for Those Struggling with Energy Costs April 2, 2010 - 2:27pm Addthis Joshua DeLung In Newark, N.J., times are still tough for some residents. Among the rows of worn brick architecture, though, there are signs of hope, thanks to a local community action agency's weatherization assistance program and an extra boost in funding from the Recovery Act. The stories of homes in need of retrofitting in Newark are like those in many cities across America. Sammie Rutledge worked as a carpenter since he was a teenager but stopped working in 2004 when he was diagnosed with cancer. Faced without a paycheck from a full-time job and with high energy bills, as much as $600 each month, Sammie was distraught. Then, a friend

38

Help in N.J. for Those Struggling with Energy Costs | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

in N.J. for Those Struggling with Energy Costs in N.J. for Those Struggling with Energy Costs Help in N.J. for Those Struggling with Energy Costs April 2, 2010 - 2:27pm Addthis Joshua DeLung In Newark, N.J., times are still tough for some residents. Among the rows of worn brick architecture, though, there are signs of hope, thanks to a local community action agency's weatherization assistance program and an extra boost in funding from the Recovery Act. The stories of homes in need of retrofitting in Newark are like those in many cities across America. Sammie Rutledge worked as a carpenter since he was a teenager but stopped working in 2004 when he was diagnosed with cancer. Faced without a paycheck from a full-time job and with high energy bills, as much as $600 each month, Sammie was distraught. Then, a friend

39

January 21, 2014 @ 5:00 PM (EST): 2014 NJ Regional Science Bowl...  

NLE Websites -- All DOE Office Websites (Extended Search)

Tuesday, January 21, 2014 - 05:00 January 21, 2014 @ 5:00 PM (EST): 2014 NJ Regional Science Bowl registration closes Registration for the 2014 New Jersey Regional Science Bowl...

40

Category:Concord, NH | Open Energy Information  

Open Energy Info (EERE)

Go Back to PV Economics By Location Go Back to PV Economics By Location Media in category "Concord, NH" The following 16 files are in this category, out of 16 total. SVFullServiceRestaurant Concord NH Public Service Co of NH.png SVFullServiceRestauran... 74 KB SVHospital Concord NH Public Service Co of NH.png SVHospital Concord NH ... 75 KB SVLargeHotel Concord NH Public Service Co of NH.png SVLargeHotel Concord N... 74 KB SVLargeOffice Concord NH Public Service Co of NH.png SVLargeOffice Concord ... 76 KB SVMediumOffice Concord NH Public Service Co of NH.png SVMediumOffice Concord... 74 KB SVMidriseApartment Concord NH Public Service Co of NH.png SVMidriseApartment Con... 71 KB SVOutPatient Concord NH Public Service Co of NH.png SVOutPatient Concord N... 72 KB SVPrimarySchool Concord NH Public Service Co of NH.png

Note: This page contains sample records for the topic "mn nh nj" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

U.S. DEPARTMENT OF ENERGY EERE PROJECT MANAGEMENT CENTER NJ1PA DETERMINATION  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

NJ1PA DETERMINATION NJ1PA DETERMINATION RECIPIENT:Abengoa Solar Inc. Page 1 of2 STATE: CO PROJECT TITLE: Reducing the Cost of Thermal Energy Storage for Parabolic Trough Power Plants Funding Opportunity Announcement Numbu Procurement Instrument Number NEPA Control Numbu ell) Number DE·PS36-08G098032 G018156 GFQ.G018156-003 G018156 Based on my review oflhe information concerning the proposed action, as NEPA Compliance Officer (authorized under DOE Order 451.1A),1 have made the following determination: ex, EA, EIS APPENDIX AND NUMBER: Description: A9 Information gathering (including, but nollimiled to, literature surveys. inventories. audits), data analysis (indudm9 computer modeling). document preparation (such as conceptual design or feasibility studies, analytical energy supply

42

**NO SCIENCE ON SATURDAY TODAY** NJ Regional High School Science Bowl |  

NLE Websites -- All DOE Office Websites (Extended Search)

February 23, 2013, 8:00am February 23, 2013, 8:00am Science Education Lab-wide Event **NO SCIENCE ON SATURDAY TODAY** NJ Regional High School Science Bowl Teams of students are invited to participate in the Department of Energy's National Science Bowl Competition. Each year PPPL hosts the New Jersey Regional Science Bowl which decides which teams from the local area can continue onto the national competition in Washington, D.C. The Science Bowl is a double elimination contest with oral question and answer rounds in the fields of chemistry, biology, physics, astronomy and mathematics plus general and earth sciences. Questions are given in a toss-up with a bonus format. For more information, visit our Science Bowl website! Contact Information Website: NJ Regional High School Science Bowl

43

NH NH NH NH  

NLE Websites -- All DOE Office Websites (Extended Search)

- Grand Station Foyer Continental Breakfast - Grand Station iii PoSt-CoMbuStion MeMbrane-baS Moderator - Jos Figueroa, U.S. Department of Energy, National Energy Techno tueSday,...

44

Updated 6/10 Volunteer NH!  

E-Print Network (OSTI)

Plant a garden 5 Hitchcock Hall Durham, NH 03824 Marianne Fortescue, Coordinator 603-862-2197 marianne.fortescue

Pohl, Karsten

45

NJ,O-04 MEMOHANDUtl TO: FILE FRon: SITE NAME: CITY:  

Office of Legacy Management (LM)

I I &-?I, I . . . ,- . . -' * 3 8OC NJ,O-04 MEMOHANDUtl TO: FILE FRon: SITE NAME: CITY: _____ -&-&~--------STATE: . . ------ .- OWNER(S) -------- P=st:~__------_-____--------- Current: ~~~~~~~-~----~-~~-~--~-~~~ Owner contacted q yes I-J no; if yes, date contacted TYPE OF OPERATION ~_--_---_-~~----- 0 Research & Develapment q Facility Type 0 Production scale testing 0 Pilot Scale g Bench Scale Process ? a Theoretical Studies? $0 Sample & Analysis E Production 0. Disposal/Storage q Manufacturing 0 University 0 Research Organization 0 Government Cpansored Faci 1 i ty 0 Other ~~~-~~~-~-_~~--~--~-- TYPE OF CONTRACT ~-_-----~-~----- A Prime q Subcontractk- 0 Purchase Order 0 Other information (i.e., cost + fixed fee, unit price,

46

Synthesis and Characterization of MnO2-Based Mixed Oxides as Supercapacitors  

E-Print Network (OSTI)

Synthesis and Characterization of MnO2-Based Mixed Oxides as Supercapacitors Hansung Kim. Available electronically January 28, 2003. The development of a high-power-density supercapacitor made to develop supercapacitors based on non-noble oxides.13 Hydrous manganese oxide (a-MnO2 · nH2O

Popov, Branko N.

47

US. DEPARTMENT OF ENERGY EERE PROJECT MANAGEMENT CENTER NJ1PA DETERMINATION  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

OF ENERGY OF ENERGY EERE PROJECT MANAGEMENT CENTER NJ1PA DETERMINATION Page 1 of2 RECIPIENT:ELECTRATHERM, Inc. STATE: NV PROJECT TITLE: ·Small Scale Electrical Power Generation from Heat Co-Produced in Geothermal Fluids: MiningOperation" Funding Opportunity Announcement Number PNK:urement Instrument Number N£PA Control Number em Number OE+FOAOOOO336 DE-EEOOO4435 GF0-0004435-002 G04435 Based on my review of the information c:oncerning tbe proposed action, 85 NEPA Compliance Officer (authorized under DOE Order 451.IA),1 have made the following determination: ex, EA, EIS APPENDIX AND NUMBER: Description: A9 Info rm ation gathering, analysis, and d issemination Information gathering (including , but not limited to, literature surveys, inventories, site visits, and

48

H. B. Fry, Staff Assistant NJ-, i.4 SUBJECT: DISCUSSION CCSJCERMZIQ THE M  

Office of Legacy Management (LM)

' ' : H. B. Fry, Staff Assistant NJ-, i.4 SUBJECT: DISCUSSION CCSJCERMZIQ THE M E W BRUNSWICK UBORAIORY; MONDAY, EOVEKBER 1, '1948 REFER TO SYb5BOLt SA:HBF tu 14-7 2 Those presentr M r. Rodden, Dr. Donovan, Hr. K&lay, Dr. Chadwell, Messrs. Fry, Bslmore and Hill, The purpose of the meeting was to disouss the program and working relationships of the New York Offioe and the laboratory at New Brunswick. There is attached an agenda for the meeting. There was no disagreement on the functiona of the laboratory described by Mr. Belmore as followat 1. To assist the Produotion Division in oontrolling wality of uranium, thori=, beryllium, zirconium metals and oompounds, (or any material assigned to NYOO). (a) By analyzing various raw materials, intermediater and

49

DECONTAMINATION OF DREDGED MATERIAL FROM PORT OF NY/NJ DECONTAMINATION OF DREDGED MATERIAL FROM THE PORT OF  

E-Print Network (OSTI)

of Liters Transported (Source: New Jersey Petroleum Council) Rank Port Liters 1 New York Harbor, NY/NJ 106 Jersey ranks first in the United States in volume of petroleum products handled each year. In addition to the discharge of significant amounts of petroleum hydrocarbons into the waters of the New York/New Jersey region

Brookhaven National Laboratory

50

DOE - Office of Legacy Management -- R Brew Co - NH 01  

NLE Websites -- All DOE Office Websites (Extended Search)

R Brew Co - NH 01 R Brew Co - NH 01 FUSRAP Considered Sites Site: R. BREW CO. (NH.01 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: Concord , New Hampshire NH.01-1 Evaluation Year: 1994 NH.01-2 Site Operations: Conducted vacuum furnace tests using uranium and copper billets. NH.01-1 NH.01-3 Site Disposition: Eliminated - Potential for contamination remote NH.01-2 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled: Uranium NH.01-1 NH.01-3 Radiological Survey(s): Yes - radiological monitoring during operations NH.01-3 Site Status: Eliminated from consideration under FUSRAP Also see Documents Related to R. BREW CO. NH.01-1 - Memorandum/Checklist; Landis to File; Subject: R. Brew

51

Effective red compensation of Sr2SiO4: Dy3+ phosphor by codoping Mn2+ ions and its energy transfer  

Science Conference Proceedings (OSTI)

Mn2+ ions codoped Sr2SiO4 : Dy3+ phosphors were prepared by the solid-state reaction method using NH4Cl as the flux. Their phase compositions, photoluminescence properties, and the energy transfer ...

Le Zhang, Zhou Lu, Pengde Han, Lixi Wang, Qitu Zhang

2012-01-01T23:59:59.000Z

52

NH House Committee_April27 2005  

NLE Websites -- All DOE Office Websites (Extended Search)

Mercury Control Mercury Control Technology R&D Program for Coal-Fired Boilers Working Session of the New Hampshire House Science, Technology, & Energy Committee April 26, 2005 Concord, New Hampshire Thomas J. Feeley, III thomas.feeley@netl.doe.gov National Energy Technology Laboratory NH House Committee_April 2005 Mercury Control Technology Field Testing Program Performance/Cost Objectives * Have technologies ready for commercial demonstration by 2007 for all coals * Reduce "uncontrolled" Hg emissions by 50-70% * Reduce cost by 25-50% compared to baseline cost estimates Baseline Costs: $50,000 - $70,000 / lb Hg Removed 2000 Year Cost NH House Committee_April 2005 Stages of Mercury Control Technology Development DOE RD&D Model Lab/Bench/Pilot-Scale Testing Field Testing

53

u.s. DI!PARThIENT OF ENERGY EERE PROJECT MANAGEMENT CENTER NJ!PA DETEJU,llNATION  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

MANAGEMENT CENTER MANAGEMENT CENTER NJ!PA DETEJU,llNATION RECIPIENT :Ocean Renewable Power Company, LlC Page I of2 STATE: AK PROJECf TITLE: Acoustic Monitoring of Beluga Whale Interactions withCook Inlet Tidal Energy Project Funding Opportunity Announcement Number Procurement Instrument Number NEPA Control Number em Number DE-FOA-OOOOO69 DE-EE0002657 GFO-O002657-002 G02657 Based on my review oftbe information concerning the proposed action, as NEPA Compliance Officer (authorized under DOE Order 451.1A), I have made the following determination: ex, EA, EIS APPENDIX AND NUMBER: Description: B3.3 Research related to Field and laboratory research, inventory, and information collection activities that are directly conservation of fish, wildlife, related to the conservation of fish and wildlife resources or to the protection of cultural

54

2nd Int. Symp. on Lithium Applications for Fusion Devices, April 27-29, 2011, Princeton, NJ Program for the 2nd International Symposium  

E-Print Network (OSTI)

2nd Int. Symp. on Lithium Applications for Fusion Devices, April 27-29, 2011, Princeton, NJ Program for the 2nd International Symposium on Lithium Applications for Fusion Devices April 27-29, 2011:40 Welcome, S. Prager, Director, PPPL 8:45 Announcement: Local organizer Session I-A. Lithium in Magnetic

Princeton Plasma Physics Laboratory

55

Molecular Biology of the Brain, edited by S.J. Higgins. Princeton, NJ: Princeton University Press, 1999. 196 pp. $32.50.  

E-Print Network (OSTI)

Molecular Biology of the Brain, edited by S.J. Higgins. Princeton, NJ: Princeton University Press level is one of the great- est and most important questions facing science. The Molecular Biology of the Brain reviews the state of current knowledge about the molecular foundations of brain function and gives

Schoenemann, P. Thomas

56

,"Pittsburg, NH Natural Gas Pipeline Imports From Canada (MMcf...  

U.S. Energy Information Administration (EIA) Indexed Site

Of Series","Frequency","Latest Data for" ,"Data 1","Pittsburg, NH Natural Gas Pipeline Imports From Canada (MMcf)",1,"Annual",2012 ,"Release Date:","172014" ,"Next...

57

NH Clean Power Act (New Hampshire) | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

NH Clean Power Act (New Hampshire) NH Clean Power Act (New Hampshire) NH Clean Power Act (New Hampshire) < Back Eligibility Agricultural Commercial Industrial Investor-Owned Utility Municipal/Public Utility Utility Savings Category Alternative Fuel Vehicles Hydrogen & Fuel Cells Buying & Making Electricity Water Home Weatherization Solar Wind Program Info State New Hampshire Program Type Environmental Regulations Provider NH Department of Environmental Services The Act calls for annual reductions of multiple pollutants, including SO2, Nox, CO2, and mercury. The Act calls for an 87% reduction in SO2 emissions and a 70% reduction in Nox emissions from 1999 levels. CO2 emissions are to be reduced to 1990 levels by the end of 2006. Act is implemented under NH Rules Env-A 2900. This act applies specifically to three existing fossil

58

Public Service Co of NH | Open Energy Information  

Open Energy Info (EERE)

NH NH (Redirected from PSNH) Jump to: navigation, search Name Public Service Co of NH Place New Hampshire Service Territory New Hampshire Website www.psnh.com Green Button Landing Page www.psnh.com/SaveEnergyMo Green Button Reference Page www.psnh.com/SaveEnergyMo Green Button Implemented Yes Utility Id 15472 Utility Location Yes Ownership I NERC Location NPCC NERC NPCC Yes ISO NE Yes Operates Generating Plant Yes Activity Generation Yes Activity Transmission Yes Activity Buying Transmission Yes Activity Distribution Yes Activity Wholesale Marketing Yes Activity Retail Marketing Yes Alt Fuel Vehicle Yes Alt Fuel Vehicle2 Yes References EIA Form EIA-861 Final Data File for 2010 - File1_a[1] Energy Information Administration Form 826[2] LinkedIn Connections

59

Microwave-assisted fast vapor-phase transport synthesis of MnAPO-5 molecular sieves  

Science Conference Proceedings (OSTI)

MnAPO-5 was prepared by a microwave-assisted vapor-phase transport method at 180 deg. C in short times. The products were characterized by X-ray diffraction, scanning electron microscopy, Fourier transform infrared spectra, UV-vis spectroscopic measurement, NH{sub 3}-temperature-programmed desorption and esterification reaction. It was found that dry gels prepared with aluminum isopropoxide, phosphoric acid and manganese acetate could be transferred to MnAPO-5 in the vapors of triethylamine and water by the microwave-assisted vapor-phase transport method at 180 deg. C for less than 30 min. The crystallization time was greatly reduced by the microwave heating compared with the conventional heating. The resulting MnAPO-5 exhibited much smaller particle sizes, higher surface areas and slightly higher catalytic activity in the esterification of acetic acid and butyl alcohol than those prepared by the conventional vapor-phase transport method and hydrothermal synthesis.

Shao Hui [State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009 (China); Department of Chemical Engineering, Jiangsu Polytechnic University, Changzhou 213016 (China); Yao Jianfeng; Ke Xuebin [State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009 (China); Zhang Lixiong [State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009 (China)], E-mail: lixiongzhang@yahoo.com; Xu Nanping [State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009 (China)

2009-04-02T23:59:59.000Z

60

C:\\ANNUAL\\VENTCHAP.V8\\NGA.VP  

Gasoline and Diesel Fuel Update (EIA)

4 NJ WY AK AL CA AR CO CT DE FL GA HI ID KS IL IN IA IA KY LA ME MI MA MD MN MS MT MO NE ND OH NV NM NY NH NC OK OR PA RI SC SD TN TX UT VT WA WV WI AZ VA DC 0.00-1.99 2.00-2.99...

Note: This page contains sample records for the topic "mn nh nj" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

C:\\ANNUAL\\VENTCHAP.V8\\NGAla1109.vp  

Gasoline and Diesel Fuel Update (EIA)

0 NJ WY AK AL CA AR CO CT DE FL GA HI ID KS IL IN IA IA KY LA ME MI MA MD MN MS MT MO NE ND OH NV NM NY NH NC OK OR PA RI SC SD TN TX UT VT WA WV WI AZ VA DC Sources: Energy...

62

NGA98fin5.vp  

Annual Energy Outlook 2012 (EIA)

NJ WY AK AL CA AR CO CT DE FL GA HI ID KS IL IN IA IA KY LA ME MI MA MD MN MS MT MO NE ND OH NV NM NY NH NC OK OR PA RI SC SD TN TX UT VT WA WV WI AZ VA DC 0.00-1.99 2.00-2.99...

63

U.S. Energy Information Administration | Annual Energy Outlook...  

Annual Energy Outlook 2012 (EIA)

3 Regional maps Figure F6. Coal supply regions WA ID OR CA NV UT TX OK AR MO LA MS AL GA FL TN SC NC KY VA WV WY CO SD ND MI MN WI IL IN OH MD PA NJ DE CT MA NH VT NY ME RI MT NE...

64

Public Service Co of NH | Open Energy Information  

Open Energy Info (EERE)

Name Public Service Co of NH Name Public Service Co of NH Place New Hampshire Service Territory New Hampshire Website www.psnh.com Green Button Landing Page www.psnh.com/SaveEnergyMo Green Button Reference Page www.psnh.com/SaveEnergyMo Green Button Implemented Yes Utility Id 15472 Utility Location Yes Ownership I NERC Location NPCC NERC NPCC Yes ISO NE Yes Operates Generating Plant Yes Activity Generation Yes Activity Transmission Yes Activity Buying Transmission Yes Activity Distribution Yes Activity Wholesale Marketing Yes Activity Retail Marketing Yes Alt Fuel Vehicle Yes Alt Fuel Vehicle2 Yes References EIA Form EIA-861 Final Data File for 2010 - File1_a[1] Energy Information Administration Form 826[2] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now!

65

RECIPIENT:Princeton Power Systems STATE: NJ PROJECT Marine High-Voltage Power Conditioning and Transmission System with Integrated Energy Storage  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Princeton Power Systems Princeton Power Systems STATE: NJ PROJECT Marine High-Voltage Power Conditioning and Transmission System with Integrated Energy Storage TITLE: Funding Opportunity Announcement Number Procurement Instrument Number NEPA Control Number cm Number DE-FOA-0000293 DE-EE0003640 GFO-000364~001 GOO Based on my review of the information concerning the proposed action, as NEPA Compliance Officer (authorized under DOE Order 451.1A), I have made the foUowing determination: CX, EA, EIS APPENDIX AND NUMBER: Description: A9 Information gathering (including, but not limited to, ~terature surveys, inventories, audits), data analysis (including computer modeling), document preparation (such as conceptual design or feasibility studies, analytical energy supply

66

Mn deposition on Ni{sub 2}MnGa(100)  

Science Conference Proceedings (OSTI)

We report the study of Mn adlayers on a Mn deficient Ni{sub 2}MnGa(100) surface by using low energy electron diffraction (LEED). The spot profile analysis indicates that after 0.2 monolayer (ML) deposition, the LEED spots become very sharp. This pattern indicates the removal of Mn vacancies formed on the surface due to Mn deficiency. But with further growth of Mn layers on this surface, the LEED spots become broad.

Nayak, J.; Rai, Abhishek; D'Souza, S. W.; Maniraj, M.; Barman, S. R. [UGC-DAE Consortium for Scientific Research, Khandwa Road, Indore, 452001, M.P. (India)

2012-06-05T23:59:59.000Z

67

Category:Minneapolis, MN | Open Energy Information  

Open Energy Info (EERE)

MN MN Jump to: navigation, search Go Back to PV Economics By Location Media in category "Minneapolis, MN" The following 16 files are in this category, out of 16 total. SVFullServiceRestaurant Minneapolis MN Northern States Power Co (Minnesota) Excel Energy.png SVFullServiceRestauran... 89 KB SVHospital Minneapolis MN Northern States Power Co (Minnesota) Excel Energy.png SVHospital Minneapolis... 85 KB SVLargeHotel Minneapolis MN Northern States Power Co (Minnesota) Excel Energy.png SVLargeHotel Minneapol... 85 KB SVLargeOffice Minneapolis MN Northern States Power Co (Minnesota) Excel Energy.png SVLargeOffice Minneapo... 82 KB SVMediumOffice Minneapolis MN Northern States Power Co (Minnesota) Excel Energy.png SVMediumOffice Minneap... 83 KB SVMidriseApartment Minneapolis MN Northern States Power Co (Minnesota) Excel Energy.png

68

Characterization of the selective reduction of NO by NH/sub 3/  

Science Conference Proceedings (OSTI)

The selective reduction of NO by NH/sub 3/ addition has been studied in a lean-burning oil-fired laboratory combustion tunnel as a function of equivalence ratio, NH/sub 3/ injection temperature, concentration of NH/sub 3/ added, and the source of NO. Ammonia breakthrough was found to depend strongly on the NH/sub 3/ addition temperature. The total concentration of nitrogen containing species other N/sub 2/, NO, and NH/sub 3/ was measured with a variety of techniques and was found to be less than 5 ppM over the range of conditions studied.

Lucas, D.; Brown, N.J.

1981-04-01T23:59:59.000Z

69

Page 1 of 7 2013 NH 4-H HORSE QUIZ BOWL  

E-Print Network (OSTI)

at http://extension.unh.edu/4H/NH4-HHorseProject.htm or by sending an Excel document to Rhiannon.Beauregard

New Hampshire, University of

70

Export.gov - NJ Staff  

NLE Websites -- All DOE Office Websites (Extended Search)

Aerospace Agribusiness ArchitectureConstruction AutomotiveTransportation Education Energy Environmental Technology Franchising HotelRestaurant Information & Communication...

71

Microsoft Word - Mn.doc  

NLE Websites -- All DOE Office Websites (Extended Search)

5 5 Structural Determination of Marine Bacteriogenic Manganese Oxides John R. Bargar, Samuel M. Webb (Stanford Synchrotron Radiation Laboratory), and Bradley M. Tebo (Oregon Health and Science University) Bacterial oxidation of Mn(II) impacts the global geochemical cycling of carbon, nitrogen, sulfur, nutrients, and contaminants in the environment. Manganese is abundant in the biosphere (~10 14 Kg of suspended and dissolved manganese in the oceans) and is second only to iron in relative terrestrial abun- dance of transition metals. Manganese is an important nutrient in the marine water column and is fundamentally required for photosynthesis. The acquisition of manganese by organisms and the biogeochemistry of manganese in the oceans is therefore an

72

DOE - Office of Legacy Management -- Elk River Reactor - MN 01  

Office of Legacy Management (LM)

Elk River Reactor - MN 01 FUSRAP Considered Sites Site: Elk River Reactor (MN.01 ) Eliminated from consideration under FUSRAP - Reactor was dismantled and decommissioned by 1974...

73

CHARACTERIZATION STUDIES OF THE SELECTIVE REDUCTION OF NO by NH3  

E-Print Network (OSTI)

and Maloney, K.L. , "NOx Reduction with Ammonia: Laboratoryand Hashizawa, K. , "Reduction of NOx in Combustion ExhaustSelective Noncatalytic Reduction of NOx with NH3," EPRI NOx

Brown, N.J.

2013-01-01T23:59:59.000Z

74

IMPROVEMENT OF CdMnTe DETECTOR PERFORMANCE BY MnTe PURIFICATION  

Science Conference Proceedings (OSTI)

Residual impurities in manganese (Mn) are a big obstacle to obtaining high-performance CdMnTe (CMT) X-ray and gamma-ray detectors. Generally, the zone-refining method is an effective way to improve the material's purity. In this work, we purified the MnTe compounds combining the zone-refining method with molten Te, which has a very high solubility for most impurities. We confirmed the improved purity of the material by glow-discharge mass spectrometry (GDMS). We also found that CMT crystals from a multiply-refined MnTe source, grown by the vertical Bridgman method, yielded better performing detectors.

Kim, K.H.; Bolotnikov, A.E.; Camarda, G.S.; Tappero, R.; Hossain, A.; Cui, Y.; Yang, G.; Gul, R.; and James, R.B.

2011-04-25T23:59:59.000Z

75

Solid Solution Phases in Olivine-Type LiMnPO4/MnP4System  

NLE Websites -- All DOE Office Websites (Extended Search)

Solid Solution Phases in Olivine-Type LiMnPO4MnP4System Title Solid Solution Phases in Olivine-Type LiMnPO4MnP4System Publication Type Journal Article Year of Publication 2009...

76

MN Office of Energy Security | Open Energy Information  

Open Energy Info (EERE)

MN Office of Energy Security MN Office of Energy Security Jump to: navigation, search Name MN Office of Energy Security Place St. Paul, MN Website http://www.mnofficeofenergysec References MN Office of Energy Security[1] Information About Partnership with NREL Partnership with NREL Yes Partnership Type Test & Evaluation Partner Partnering Center within NREL Electricity Resources & Building Systems Integration LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! MN Office of Energy Security is a company located in St. Paul, MN. References ↑ "MN Office of Energy Security" Retrieved from "http://en.openei.org/w/index.php?title=MN_Office_of_Energy_Security&oldid=379158" Categories: Clean Energy Organizations Companies Organizations

77

Microsoft Word - figure_8.doc  

Gasoline and Diesel Fuel Update (EIA)

T I D O R W Y ND SD C A N V U T CO NE KS A Z NM OK TX MN WI MI IA I L IN OH MO AR M S AL GA T N KY FL SC NC WV MD DE VA PA NJ NY CT RI MA VT NH ME LA HI A K J a p a n Mexico M e x...

78

Thermal Durability of Cu-CHA NH3-SCR Catalysts for Diesel NOx Reduction  

SciTech Connect

Multiple catalytic functions (NOx conversion, NO and NH3 oxidation, NH3 storage) of a commercial Cu-zeolite urea/NH3-SCR catalyst were assessed in a laboratory fixed-bed flow reactor system after differing degrees of hydrothermal aging. Catalysts were characterized by using x-ray diffraction (XRD), 27Al solid state nuclear magnetic resonance (NMR) and transmission electron microscopy (TEM) / energy dispersive X-ray (EDX) spectroscopy to develop an understanding of the degradation mechanisms during catalyst aging. The catalytic reaction measurements of laboratory-aged catalysts were performed, which allows us to obtain a universal curve for predicting the degree of catalyst performance deterioration as a function of time at each aging temperature. Results show that as the aging temperature becomes higher, the zeolite structure collapses in a shorter period of time after an induction period. The decrease in SCR performance was explained by zeolite structure destruction and/or Cu agglomeration, as detected by XRD/27Al NMR and by TEM/EDX, respectively. Destruction of the zeolite structure and agglomeration of the active phase also results in a decrease in the NO/NH3 oxidation activity and the NH3 storage capacity of the catalyst. Selected laboratory aging conditions (16 h at 800oC) compare well with a 135,000 mile vehicle-aged catalyst for both performance and characterization criteria.

Schmieg, Steven J.; Oh, Se H.; Kim, Chang H.; Brown, David B.; Lee, Jong H.; Peden, Charles HF; Kim, Do Heui

2012-04-30T23:59:59.000Z

79

Composition-structure-property-performance relationship inMn-substituted LiMn2O4  

DOE Green Energy (OSTI)

The spinel LiMn{sub 2}O{sub 4} has been extensively studied as a positive electrode active material in lithium rechargeable batteries. Partial substitution of Mn by another metal has also been the subject of recent study in an effort to improve the cycling performance. In general, the literature has shown that Mn substitution results in improved cycling stability at the expense of capacity (1,2). Resistance to the formation of tetragonal phase upon lithiation of the starting spinel (via a higher nominal Mn oxidation state in the substituted spinel) has been suggested as a mechanism for the improved performance. The degree of substitution is an important factor to optimize in order to minimize capacity loss and costs. The spectroscopic investigations on LiMn{sub 2}O{sub 4} described in the previous paper (LixMn2O4) confirmed that the cooperative Jahn-Teller effect (CJTE) from the [Mn{sup 3+}O{sub 6}] octahedra is the mechanism for the cubic to tetragonal phase transformation. The driving force for the CJTE is based upon the electronic structure, therefore changes in electronic structure should lead to changes in the phase behavior. The fact that the LiMn{sub 1.5}Ni{sub 0.5}O{sub 4} does not form tetragonal phase upon discharging (FUJI3, MUCK?), unlike the 100% Mn{sup 4+} spinel Li{sub 4}Mn{sub 5}O{sub 12} (THAC5), led to the hypothesis that an increased degree of covalency as a source for the behavior. An increased covalence would remove the driving force for the transformation, the increased electronic stability achieved in tetragonally-distorted [Mn{sup 3+}O{sub 6}] octahedra, due to a change in electron density and widening of the Mn 3d bands. The STH field is dependent upon the amount of unpaired spin density transferred between the magnetic (transition-metal) and diamagnetic ions through an intermittent oxygen ion, attributable to overlap and electron transfer effects. Therefore, the magnitude of the STH coupling constant reflects the degree of covalency (GESC, HUAN). In the case of LiMn{sub 2-y}Me{sub y}O{sub 4}, the STH coupling constant characterizes the amount of unpaired spin density transferred to the Li{sup +} from the Mn, Co, or Ni. Similarly, the La/Lb ratio of the Mn L-XES is sensitive to the amount of electron density at the Mn site as a higher ratio indicates that the Mn 3d{sub 5/2} level is more populated (GRUS1). An investigation into the effects of Mn-substitution on the electronic structure along with the ramifications to the phase behavior upon changing lithium content was carried out. To accomplish this, a set of LiMn{sub 2-y}Me{sub y}O{sub 4} with Me = Li, Co, or Ni over a range of y were synthesized, characterized, and subjected to changes in lithium content by various techniques.

Horne, Craig R.; Richardson, Thomas J.; Gee, B.; Tucker, Mike; Grush, Melissa M.; Bergmann, Uwe; Striebel, Kathryn A.; Cramer, StephenP.; Reimer, Jeffrey A.; Cairns, Elton J.

2001-03-09T23:59:59.000Z

80

Photolysis of solid NH{sub 3} and NH{sub 3}-H{sub 2}O mixtures at 193 nm  

SciTech Connect

We have studied UV photolysis of solid ammonia and ammonia-dihydrate samples at 40 K, using infrared spectroscopy, mass spectrometry, and microgravimetry. We have shown that in the pure NH{sub 3} sample, the main species ejected are NH{sub 3}, H{sub 2}, and N{sub 2}, where the hydrogen and nitrogen increase with laser fluence. This increase in N{sub 2} ejection with laser fluence explains the increase in mass loss rate detected by a microbalance. In contrast, for the ammonia-water mixture, we see very weak signals of H{sub 2} and N{sub 2} in the mass spectrometer, consistent with the very small mass loss during the experiment and with a <5% decrease in the NH{sub 3} infrared absorption bands spectroscopy after a fluence of {approx}3 x 10{sup 19} photons/cm{sup 2}. The results imply that ammonia-ice mixtures in the outer solar system are relatively stable under solar irradiation.

Loeffler, M. J. [Astrochemistry Laboratory, NASA Goddard Space Flight Center, Code 691, Greenbelt, Maryland 20771 (United States); Laboratory for Atomic and Surface Physics, Engineering Physics, University of Virginia, Charlottesville, Virginia 22904 (United States); Baragiola, R. A. [Laboratory for Atomic and Surface Physics, Engineering Physics, University of Virginia, Charlottesville, Virginia 22904 (United States)

2010-12-07T23:59:59.000Z

Note: This page contains sample records for the topic "mn nh nj" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Grants to Help N.H. Towns Conserve Energy | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Grants to Help N.H. Towns Conserve Energy Grants to Help N.H. Towns Conserve Energy Grants to Help N.H. Towns Conserve Energy March 19, 2010 - 4:17pm Addthis New Hampshire has a plan to lower expenses and create jobs, all while conserving energy. In all, the state has received $17.3 million in Energy Efficiency and Conservation Block Grant (EECBG) funding. Of that, $9.6 million has been sent to the New Hampshire Office of Energy and Planning (NHOEP) to launch several energy saving projects. NHOEP established a subgrant program to award $6.6 million of the EECBG grant funding to local municipalities and counties. New Hampshire municipalities and counties submitted over 270 applications, totaling over $21 million in grant requests. "Substantial energy efficiency improvements will be made throughout the

82

Grants to Help N.H. Towns Conserve Energy | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Grants to Help N.H. Towns Conserve Energy Grants to Help N.H. Towns Conserve Energy Grants to Help N.H. Towns Conserve Energy March 19, 2010 - 4:17pm Addthis New Hampshire has a plan to lower expenses and create jobs, all while conserving energy. In all, the state has received $17.3 million in Energy Efficiency and Conservation Block Grant (EECBG) funding. Of that, $9.6 million has been sent to the New Hampshire Office of Energy and Planning (NHOEP) to launch several energy saving projects. NHOEP established a subgrant program to award $6.6 million of the EECBG grant funding to local municipalities and counties. New Hampshire municipalities and counties submitted over 270 applications, totaling over $21 million in grant requests. "Substantial energy efficiency improvements will be made throughout the

83

Category:International Falls, MN | Open Energy Information  

Open Energy Info (EERE)

MN MN Jump to: navigation, search Go Back to PV Economics By Location Media in category "International Falls, MN" The following 16 files are in this category, out of 16 total. SVFullServiceRestaurant International Falls MN Northern States Power Co (Minnesota) Excel Energy.png SVFullServiceRestauran... 88 KB SVHospital International Falls MN Northern States Power Co (Minnesota) Excel Energy.png SVHospital Internation... 84 KB SVLargeHotel International Falls MN Northern States Power Co (Minnesota) Excel Energy.png SVLargeHotel Internati... 85 KB SVLargeOffice International Falls MN Northern States Power Co (Minnesota) Excel Energy.png SVLargeOffice Internat... 83 KB SVMediumOffice International Falls MN Northern States Power Co (Minnesota) Excel Energy.png

84

Magnetoelastic Coupling in NiMnGa Ferromagnetic Shape ...  

Science Conference Proceedings (OSTI)

... Magnetoelastic Coupling in NiMnGa Ferromagnetic Shape Memory Alloys. Peng Zhao (Dept. of Materials Science and ...

85

First Principles Calculation for Magnetic Properties of Mn Alloys  

Science Conference Proceedings (OSTI)

The results indicate that the ? of MnAl and MnAlGe are extremely small because of ... Alloy Design and Powder Processing of Mn-Al Based Materials for Rare Earth ... Device Arrays Using Self-limiting Low-energy Glow-discharge Processing.

86

Synthesis and Characterization of Th2N2(NH) Isomorphous to Th2N3  

SciTech Connect

Using a new, low-temperature, fluoride-based process, thorium nitride imide of the chemical formula Th{sub 2}N{sub 2}(NH) was synthesized from thorium dioxide via an ammonium thorium fluoride intermediate. The resulting product phase was characterized by powder X-ray diffraction (XRD) analysis and was found to be crystallographically similar to Th{sub 2}N{sub 3}. Its unit cell was hexagonal with a space group of P3m{bar 1} and lattice parameters of a = b = 3.886(1) and c = 6.185(2) {angstrom}. The presence of -NH in the nitride phase was verified by Fourier transform infrared spectroscopy (FTIR). Total energy calculations performed using all-electron scalar relativistic density functional theory (DFT) showed that the hydrogen atom in the Th{sub 2}N{sub 2}(NH) prefers to bond with nitrogen atoms occupying 1a Wyckoff positions of the unit cell. Lattice fringe disruptions observed in nanoparticle areas of the nitride species by high-resolution transmission electron microscopic (HRTEM) images also displayed some evidence for the presence of -NH group. As ThO{sub 2} was identified as an impurity, possible reaction mechanisms involving its formation are discussed.

Silva, G W Chinthaka M [ORNL; Yeamans, Charles B. [University of California, Berkeley; Hunn, John D [ORNL; Sattelberger, Alfred P [Argonne National Laboratory (ANL); Czerwinski, Ken R. [University of Nevada, Las Vegas; Weck, Dr. Phil F [University of Nevada, Las Vegas

2012-01-01T23:59:59.000Z

87

Page 1 of 16 2013 NH 4-H Horse Quiz Bowl  

E-Print Network (OSTI)

: 9:00 AM to 5:00 PM Location: Belmont Middle School, 38 School Street, Belmont NH 03220 Deadline Quiz Bowl is an event where youth demonstrate their knowledge of equine science in a contest similar to high school quiz bowls. Teams of four race to hit their buzzers and answer equine-related questions

New Hampshire, University of

88

Electrochemical Performances of LiMnPO4 Synthesized from Non-Stoichiometric Li/Mn Ratio  

Science Conference Proceedings (OSTI)

In this paper we report the influences of the initial lithium content on the structural, electrochemical and magnetic properties of nonstoichiometric LixMnPO4 (0.5?x?1.2) nano-particles. It has been revealed Mn2P2O7 is the main impurity when Li1.0. The different functions of Mn2P2O7 and Li3PO4 impurities in the non-stoichiometric compounds have been investigated systematically. At a slow rate of C/50 the reversible capacity of both Li0.5MnPO4 and Li0.8MnPO4 increases with cycling indicating a gradual activation of more sites to accommodate a reversible diffusion of Li+ ions which may be related to the interaction between Mn2P2O7 and LiMnPO4 nanoparticles. Among all the different compositions, Li1.1MnPO4 exhibits the most stable cycling ability probably due to the existence of a trace amount of Li3PO4 impurity which functions as a solid state electrolyte on the surface. The magnetic properties and X-ray absorption spectroscopy (XAS) of MnPO4?H2O precursor, pure and carbon coated LiMnPO4 and all the other non-stoichiometric LixMnPO4 are also investigated to identify the key steps to prepare a high performance LiMnPO4.

Xiao, Jie; Chernova, Natalya; Upreti, Shailesh; Chen, Xilin; Li, Zheng; Deng, Zhiqun; Choi, Daiwon; Xu, Wu; Nie, Zimin; Graff, Gordon L.; Liu, Jun; Whittingham, M. S.; Zhang, Jiguang

2011-09-12T23:59:59.000Z

89

Page 1 of 16 2014 NH 4-H Horse Quiz Bowl  

E-Print Network (OSTI)

their knowledge of equine science in a contest similar to high school quiz bowls. Teams of four race to hitPage 1 of 16 2014 NH 4-H Horse Quiz Bowl Date: Saturday January 25, 2014 Time: 9:00 AM to 5:00 PM the day of the contest. The New Hampshire 4-H Quiz Bowl is an event where youth demonstrate

New Hampshire, University of

90

Low-temperature magnetization of (Ga,Mn) As semiconductors  

E-Print Network (OSTI)

We report on a comprehensive study of the ferromagnetic moment per Mn atom in (Ga,Mn)As ferromagnetic semiconductors. Theoretical discussion is based on microscopic calculations and on an effective model of Mn local moments antiferromagnetically coupled to valence band hole spins. The validity of the effective model over the range of doping studied is assessed by comparing with microscopic tight-binding/coherent-potential approximation calculations. Using the virtual crystal k center dot p model for hole states, we evaluate the zero-temperature mean-field contributions to the magnetization from the hole kinetic and exchange energies, and magnetization suppression due to quantum fluctuations of Mn moment orientations around their mean-field ground state values. Experimental low-temperature ferromagnetic moments per Mn are obtained by superconducting quantum interference device and x-ray magnetic circular dichroism measurements in a series of (Ga,Mn)As semiconductors with nominal Mn doping ranging from similar to 2 to 8%. Hall measurements in as-grown and annealed samples are used to estimate the number of uncompensated substitutional Mn moments. Based on our comparison between experiment and theory we conclude that all these Mn moments in high quality (Ga,Mn)As materials have nearly parallel ground state alignment.

Jungwirth, T.; Masek, J.; Wang, KY; Edmonds, KW; Sawicki, M.; Polini, M.; Sinova, Jairo; MacDonald, AH; Campion, RP; Zhao, LX; Farley, NRS; Johal, TK; van der Laan, G.; Foxon, CT; Gallagher, BL.

2006-01-01T23:59:59.000Z

91

Theoretical Investigations on the Formation and Dehydrogenation Reaction Pathways of H(NH2BH2)nH (n=1-4) Oligomers: Importance of Dihydrogen Interactions (DHI)  

DOE Green Energy (OSTI)

The H(NH2BH2)nH oligomers are possible products from dehydrogenation of ammonia borane (NH3BH3) and ammonium borohydride (NH4BH4), which belong to a class of boron-nitrogen-hydrogen (BNHx) compounds that are promising materials for chemical hydrogen storage. Understanding the kinetics and reaction pathways of formation of these oligomers and their further dehydrogenation is essential for developing BNHx-based hydrogen storage materials. We have performed computational modeling using density functional theory (DFT), ab initio wavefunction theory, and Car-Parrinello molecular dynamics (CPMD) simulations on the energetics and formation pathways for the H(NH2BH2)nH (n=1-4) oligomers, polyaminoborane (PAB), from NH3BH3 monomers and the subsequent dehydrogenation steps to form polyiminoborane (PIB). Through transition state searches and evaluation of the intrinsic reaction coordinates, we have investigated the B-N bond cleavage, the reactions of NH3BH3 molecule with intermediates, dihydrogen release through intra- and intermolecular hydrogen transfer, dehydrocoupling/cyclization of the oligomers, and the dimerization of NH3BH3 molecules. We discovered the formation mechanism of H(NH2BH2)n+1H oligomers through reactions of the H(NH2BH2)nH oligomers first with BH3 followed by reactions with NH3 and the release of H2, where the BH3 and NH3 intermediates are formed through dissociation of NH3BH3. We also found that the dimerization of the NH3BH3 molecules to form c-(NH2BH2)2 is slightly exothermic, with an unexpected transition state that leads to the simultaneous release of two H2 molecules. The dehydrogenations of the oligomers are also exothermic, typically by less than 10 kcal/(mol of H2), with the largest exothermicity for n=3. The transition state search shows that the one-step direct dehydrocoupling cyclization of the oligomers is not a favored pathway because of high activation barriers. The dihydrogen bonding, in which protic (HN) hydrogens interact with hydridic (HB) hydrogens, plays a vital role in stabilizing different structures of the reactants, transition states, and products. The dihydrogen interaction (DHI) within the -BH2(?2-H2) moiety accounts for both the formation mechanisms of the oligomers and for the dehydrogenation of ammonia borane. Support was provided from the U.S. Department of Energy, Office of Basic Energy Sciences, Chemical Sciences Division and from the U.S. Department of Energy, Energy Efficiency and Renewable Energy, Chemical Hydrogen Storage Center of Excellence. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.

Li, Jun; Kathmann, Shawn M.; Hu, Han-Shi; Schenter, Gregory K.; Autrey, Thomas; Gutowski, Maciej S.

2010-09-06T23:59:59.000Z

92

A WATER MASER AND NH{sub 3} SURVEY OF GLIMPSE EXTENDED GREEN OBJECTS  

SciTech Connect

We present the results of a Nobeyama 45 m H{sub 2}O maser and NH{sub 3} survey of all 94 northern GLIMPSE extended green objects (EGOs), a sample of massive young stellar objects (MYSOs) identified based on their extended 4.5 {mu}m emission. We observed the NH{sub 3}(1,1), (2,2), and (3,3) inversion lines, and detected emission toward 97%, 63%, and 46% of our sample, respectively (median rms {approx} 50 mK). The H{sub 2}O maser detection rate is 68% (median rms {approx} 0.11 Jy). The derived H{sub 2}O maser and clump-scale gas properties are consistent with the identification of EGOs as young MYSOs. To explore the degree of variation among EGOs, we analyze subsamples defined based on mid-infrared (MIR) properties or maser associations. H{sub 2}O masers and warm dense gas, as indicated by emission in the higher-excitation NH{sub 3} transitions, are most frequently detected toward EGOs also associated with both Class I and II CH{sub 3}OH masers. Ninety-five percent (81%) of such EGOs are detected in H{sub 2}O (NH{sub 3}(3,3)), compared to only 33% (7%) of EGOs without either CH{sub 3}OH maser type. As populations, EGOs associated with Class I and/or II CH{sub 3}OH masers have significantly higher NH{sub 3} line widths, column densities, and kinetic temperatures than EGOs undetected in CH{sub 3}OH maser surveys. However, we find no evidence for statistically significant differences in H{sub 2}O maser properties (such as maser luminosity) among any EGO subsamples. Combining our data with the 1.1 mm continuum Bolocam Galactic Plane Survey, we find no correlation between isotropic H{sub 2}O maser luminosity and clump number density. H{sub 2}O maser luminosity is weakly correlated with clump (gas) temperature and clump mass.

Cyganowski, C. J. [Harvard-Smithsonian Center for Astrophysics, Cambridge, MA 02138 (United States)] [Harvard-Smithsonian Center for Astrophysics, Cambridge, MA 02138 (United States); Koda, J.; Towers, S.; Meyer, J. Donovan [Department of Physics and Astronomy, Stony Brook University, Stony Brook, NY 11794 (United States)] [Department of Physics and Astronomy, Stony Brook University, Stony Brook, NY 11794 (United States); Rosolowsky, E. [Department of Physics and Astronomy, University of British Columbia, Okanagan, Kelowna BC V1V 1V7 (Canada)] [Department of Physics and Astronomy, University of British Columbia, Okanagan, Kelowna BC V1V 1V7 (Canada); Egusa, F. [Institute of Space and Astronautical Science, Japan Aerospace Exploration Agency, Chuo-ku, Sagamihara, Kanagawa 252-5210 (Japan)] [Institute of Space and Astronautical Science, Japan Aerospace Exploration Agency, Chuo-ku, Sagamihara, Kanagawa 252-5210 (Japan); Momose, R. [Department of Astronomy, University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan)] [Department of Astronomy, University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan); Robitaille, T. P., E-mail: ccyganowski@cfa.harvard.edu [Max Planck Institute for Astronomy, Heidelberg (Germany)

2013-02-10T23:59:59.000Z

93

[(CH3)4N][(C5H5NH)0.8((CH3)3NH)0.2]U2Si9O23F4 (USH-8): An Organically Templated Open-Framework Uranium Silicate  

E-Print Network (OSTI)

-Framework Uranium Silicate Xiqu Wang, Jin Huang, and Allan J. Jacobson* Department of Chemistry, Uni pyramids we obtained also a number of open-framework uranium silicates.18,19 These new compounds were-framework uranium fluorosilicate [(CH3)4N][(C5H5NH)0.8((CH3)3NH)0.2]U2Si9O23F4 (USH- 8) that has been synthesized

Wang, Xiqu

94

Microstructural Characterization of Fe-Mn-C Ternary Alloy under ...  

Science Conference Proceedings (OSTI)

Mercury Oxidation and Capture over SCR Catalysts in Simulated Coal Combustion Flue Gas Microstructural Characterization of Fe-Mn-C Ternary Alloy under...

95

Electrochemical Performance of LiFeMnPO4  

Science Conference Proceedings (OSTI)

Symposium, Energy Storage: Materials, Systems, and Applications. Presentation Title, Electrochemical Performance of LiFeMnPO4: A Comparison of Synthesis...

96

Microstructure and Coercivity of Nitrided Mn-Sn Based Alloy  

Science Conference Proceedings (OSTI)

Alloy Design and Powder Processing of Mn-Al Based Materials for Rare Earth ... Enhancement of the Refrigerant Capacity in Partially Crystallized Gd-Fe-Al-B...

97

,"Warroad, MN Natural Gas Pipeline Exports to Canada (Million...  

U.S. Energy Information Administration (EIA) Indexed Site

Of Series","Frequency","Latest Data for" ,"Data 1","Warroad, MN Natural Gas Pipeline Exports to Canada (Million Cubic Feet)",1,"Annual",2003 ,"Release Date:","172014"...

98

,"Warroad, MN Natural Gas Pipeline Imports From Canada (MMcf...  

U.S. Energy Information Administration (EIA) Indexed Site

Of Series","Frequency","Latest Data for" ,"Data 1","Warroad, MN Natural Gas Pipeline Imports From Canada (MMcf)",1,"Annual",2012 ,"Release Date:","172014" ,"Next...

99

,"International Falls, MN Natural Gas Pipeline Imports From Canada...  

U.S. Energy Information Administration (EIA) Indexed Site

International Falls, MN Natural Gas Pipeline Imports From Canada (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of...

100

,"Noyes, MN Natural Gas Pipeline Imports From Canada (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Of Series","Frequency","Latest Data for" ,"Data 1","Noyes, MN Natural Gas Pipeline Imports From Canada (MMcf)",1,"Annual",2012 ,"Release Date:","172014" ,"Next...

Note: This page contains sample records for the topic "mn nh nj" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Characterization of Mn-Co Electrodeposition for SOFC Interconnect ...  

Science Conference Proceedings (OSTI)

Presentation Title, Characterization of Mn-Co Electrodeposition for SOFC Interconnect Applications by QCM. Author(s), Junwei Wu, Ayyakkannu Manivannan,...

102

Electrodeposited Mn-Co Alloy Coating For SOFC Interconnects  

Science Conference Proceedings (OSTI)

Presentation Title, Electrodeposited Mn-Co Alloy Coating For SOFC Interconnects. Author(s), Heather McCrabb, Tim Hall, Junwei Wu, Hui Zhang, Xingbo Liu,...

103

Ammonia as a hydrogen energy-storage medium. [LH/sub 2/, MeOH, and NH/sub 3/  

DOE Green Energy (OSTI)

Liquid Hydrogen (LH/sub 2/), Methanol (MeOH), and Ammonia (NH/sub 3/) are compared as hydrogen energy-storage media on the basis of reforming the MeOH to produce H/sub 2/ and dissociating (cracking) the NH/sub 3/ to release H/sub 2/. The factors important in this storage concept are briefly discussed. Results of the comparison show that, in terms of energy input for media manufacture from natural gas, hydrogen energy content of the medium, and energy cost ($/10/sup 6/ Btu), NH/sub 3/ has a wide advantage and comes the closest to matching gasoline. The tasks required in developing a safe and practicial hydrogen energy-storage system based on the storage and cracking of NH/sub 3/ are listed. Results of the technical and economic evaluation of this concept will provide the basis for continued development.

Strickland, G

1980-08-01T23:59:59.000Z

104

Ni(II) Sorption on Biogenic Mn-Oxides with Varying Mn  

E-Print Network (OSTI)

Lightsource (SSRL), Menlo Park, CA. EXAFS spectra from Ni(II) organic standards were collected in transmission-3 at SSRL. This method is described in detail in Zhu et al. (6). Results Sorption Isotherms and Dissolved Mn,anationaluserfacilityoperatedbyStanfordUniversity on behalf of the U.S. Department of Energy, Office of Basic Energy Sciences. The SSRL Structural Molecular

Sparks, Donald L.

105

High-Resolution Structure of the Photosynthetic Mn4Ca Catalyst from X-ray Spectroscopy  

E-Print Network (OSTI)

the Photosynthetic Mn 4 Ca Catalyst from X-ray Spectroscopystructure of the Mn 4 Ca catalyst at high-resolution whichthe structure of Mn 4 Ca catalyst as it cycles through the

Yano, Junko

2008-01-01T23:59:59.000Z

106

Metallicity of InN and GaN surfaces exposed to NH{sub 3}.  

Science Conference Proceedings (OSTI)

A systematic study of energies and structures of InN and GaN (0001) surfaces exposed to NH{sub 3} and its decomposition products was performed with first-principles methods. A phenomenological model including electron counting contributions is developed based on calculated DFT energies and is used to identify low-energy structures. These predictions are checked with additional DFT calculations. The equilibrium phase diagrams are found to contain structures that violate the electron counting rule. Densities of states for these structures indicate n-type conductivity, consistent with available experimental results.

Walkosz, W.; Zapol, P.; Stephenson, G. B. (Materials Science Division)

2012-01-01T23:59:59.000Z

107

MN471018, Work Planning and Control Manual  

NLE Websites -- All DOE Office Websites (Extended Search)

18, Work Planning and Control Manual 18, Work Planning and Control Manual Sponsor: Michael W. Hazen, 4000 Issue Date: January 3, 2007 Revision Date: June 1, 2009 This document is no longer a CPR. This document implements the requirements of Corporate procedure ESH100.1.WPC.1, Plan and Control Work. IMPORTANT NOTICE: A printed copy of this document may not be the document currently in effect. The official version is the online version located on the Sandia Restricted Network (SRN) MN471018 - WORK PLANNING AND CONTROL MANUAL Subject Matter Expert: Brad Elkin; CA Counterpart: Aden Jackson MN471018 Revision Date: June 1, 2009; Replaces Document: October 28, 2008 Implementation Notice: The requirements outlined in this document must be incorporated into approved comprehensive organizational procedures on or before June 30, 2009. New work planned and conducted after June 30, 2009 shall be performed in accordance with this document. Ongoing work, conducted under an existing, current, and approved PHS and TWD (if required), is authorized until the expiration of the applicable PHS, TWD, or June 30, 2010.

108

Quasielastic neutron scattering of -NH3 and -BH3 rotational dynamics in orthorhombic ammonia borane  

Science Conference Proceedings (OSTI)

Neutrons scattering techniques are ideally suited to directly probe H in materials due to the large incoherent scattering cross-section of hydrogen atom, and have been invaluable in providing direct insight into the local fluctuations and large amplitude motions in AB. Dihydrogen bonding may have a significant affect on materials to be used to store hydrogen for fuel-cell powered applications. We have noticed a trend of low temperature release of H2 in materials composed of hydridic and protonic hydrogen. This phenomenon has caught our attention and motivated our interest to gain more insight into dihydrogen bonding interactions in AB. We present results from a thorough Quasielastic Neutron Scattering (QENS) investigation of diffusive hydrogen motion in NH311BH3 and ND311BH3 to obtain (1) a direct measure of the rotational energy barriers the protonated species and (2) a confirmation of the 3-site jump model for rotational motion. The amplitude of the energy barrier of rotation of BH3 and NH3 determined by QENS are compared to those determined for BD3 and ND3 determined by 2H NMR studies.

Hess, Nancy J.; Hartman, Michael R.; Brown, Craig; Mamontov, Eugene; Karkamkar, Abhijeet J.; Heldebrant, David J.; Daemen, Luke L.; Autrey, Thomas

2008-06-27T23:59:59.000Z

109

Herschel / HIFI observations of CO, H2O and NH3 in Mon R2  

E-Print Network (OSTI)

Context. Mon R2 is the only ultracompact HII region (UCHII) where the associated photon-dominated region (PDR) can be resolved with Herschel. Due to its brightness and proximity, it is the best source to investigate the chemistry and physics of highly UV-irradiated PDRs. Aims. Our goal is to estimate the abundance of H2O and NH3 in this region and investigate their origin. Methods. We present new observations obtained with HIFI and the IRAM-30m telescope. Using a large velocity gradient approach, we model the line intensities and derive an average abundance of H2O and NH3 across the region. Finally, we model the line profiles with a non-local radiative transfer model and compare these results with the abundance predicted by the Meudon PDR code. Results. The variations of the line profiles and intensities indicate complex geometrical and kinematical patterns. The H2O lines present a strong absorption at the ambient velocity and emission in high velocity wings towards the HII region. The spatial distribution of...

Pilleri, P; Cernicharo, J; Ossenkopf, V; Bern, O; Gerin, M; Pety, J; Goicoechea, J R; Rizzo, J R; Montillaud, J; Gonzlez-Garca, M; Joblin, C; Bourlot, J Le; Petit, F Le; Kramer, C

2012-01-01T23:59:59.000Z

110

Microsoft Word - FUSRAP Wayne NJ.rtf  

Office of Legacy Management (LM)

Wayne Interim Storage Site (WISS) Wayne, New Jersey FACT SHEET January 2004 DESCRIPTION: The Wayne site is located in a highly developed area of northern New Jersey, approximately 20 miles north-northwest of Newark, New Jersey. The site was formerly owned and operated by Rare Earths, Inc. and W.R. Grace & Co. Contamination at the property resulted from rare earths and thorium processing activities conducted at the facility during the period of 1948 to 1971. The property is now owned by the U.S. government and is designated as the Wayne Interim Storage Site (WISS). The site is located at the intersection of Black Oak Ridge Road and Pompton Plains Cross Road in Wayne Township, Passaic County, New Jersey. The WISS consists of approximately 6.5 acres of fenced property, roughly

111

Microsoft Word - FUSRAP Maywood NJ.rtf  

Office of Legacy Management (LM)

Maywood, New Jersey Maywood, New Jersey FACT SHEET January 2004 DESCRIPTION: The Maywood site is located in a highly developed area of northeastern New Jersey, in the boroughs of Maywood and Lodi and the township of Rochelle Park. It is located approximately 13 miles northeast of Newark, New Jersey. Contamination at the properties resulted from rare earths and thorium processing activities conducted at the Maywood Chemical Works (MCW) from the early 1900 through 1959. MCW stopped extracting thorium in 1959. The property was subsequently sold to the Stepan Company (Stepan), a pharmaceutical manufacturer, in 1959. The Maywood site is composed of the Maywood Interim Storage Site (MISS) and various nearby properties, including the Stepan property and numerous residential, commercial, and

112

US MidAtl NJ Site Consumption  

U.S. Energy Information Administration (EIA) Indexed Site

in New Jersey homes is for space heating. Air conditioning accounts for a larger share of household consumption than other Northeast states, but still only accounts for 3% of the...

113

The January Thaw at New Brunswick, NJ  

Science Conference Proceedings (OSTI)

An investigation of the January thaw phenomenon, a period of unseasonable warmth, was conducted using daily maximum temperatures recorded at New Brunswick, New Jersey, from 18581981. Student's t-tests, comparing long-term means of daily maximum ...

John R. Lanzante; Robert P. Harnack

1982-07-01T23:59:59.000Z

114

Microsoft Word - FUSRAP Middlesex NJ.doc  

Office of Legacy Management (LM)

were traces of radioactive materials that had been carried offsite over the years by wind and rain to yards of neighboring homes. Also, records later revealed that in 1948, some...

115

US MidAtl NJ Site Consumption  

Annual Energy Outlook 2012 (EIA)

than the average U.S. household. * New Jersey homes are 20% larger than the average U.S. home. CONSUMPTION BY END USE Nearly half the energy consumed in New Jersey homes is for...

116

Electronic structure and magnetism in BaMn2As2 and BaMn2Sb2  

Science Conference Proceedings (OSTI)

We study the properties of ThCr{sub 2}Si{sub 2} structure BaMn{sub 2}As{sub 2} and BaMn{sub 2}Sb{sub 2} using density functional calculations of the electronic and magnetic properties as well as experimental measurements on single crystal samples of BaMn{sub 2}As{sub 2}. These materials are local moment magnets with moderate band gap antiferromagnetic semiconducting ground states. The electronic structures show substantial Mn-pnictogen hybridization, which stabilizes an intermediate spin configuration for the nominally d{sup 5} Mn. The results are discussed in the context of possible thermoelectric applications and the relationship with the corresponding iron/cobalt/nickel compounds Ba(Fe,Co,Ni){sub 2}As{sub 2}.

An, Jiming [ORNL; Safa-Sefat, Athena [ORNL; Singh, David J [ORNL; Du, Mao-Hua [ORNL

2009-01-01T23:59:59.000Z

117

Study of intergranular embrittlement in Fe-12Mn alloys  

Science Conference Proceedings (OSTI)

A high resolution scanning Auger microscopic study has been performed on the intergranular fracture surfaces of Fe-12Mn steels in the as-austenitized condition. Fracture mode below the ductile-brittle transition temperature was intergranular whenever the alloy was quenched from the austenite field. The intergranular fracture surface failed to reveal any consistent segregation of P, S, As, O, or N. The occasional appearance of S or O on the fracture surface was found to be due to a low density precipitation of MnS and MnO/sub 2/ along the prior austenite boundaries. An AES study with Ar/sup +/ ion-sputtering showed no evidence of manganese enrichment along the prior austenite boundaries, but a slight segregation of carbon which does not appear to be implicated in the tendency toward intergranular fracture. Addition of 0.002% B with a 1000/sup 0/C/1h/WQ treatment yielded a high Charpy impact energy at liquid nitrogen temperature, preventing the intergranular fracture. High resolution AES studies showed that 3 at. % B on the prior austenite grain boundaries is most effective in increasing the grain boundary cohesive strength in an Fe-12Mn alloy. Trace additions of Mg, Zr, or V had negligible effects on the intergranular embrittlement. A 450/sup 0/C temper of the boron-modified alloys was found to cause tempered martensite embrittlement, leading to intergranular fracture. The embrittling treatment of the Fe-12Mn alloys with and without boron additions raised the ductile-brittle transition by 150/sup 0/C. This tempered martensite embrittlement was found to be due to the Mn enrichment of the fracture surface to 32 at. % Mn in the boron-modified alloy and 38 at. % Mn in the unmodified alloy. The Mn-enriched region along the prior austenite grain boundaries upon further tempering is believed to cause nucleation of austenite and to change the chemistry of the intergranular fracture surfaces. 61 figures.

Lee, H.J.

1982-06-01T23:59:59.000Z

118

The Role of Manganese Dioxide (MnO2) Deposition in Microbiologically Influenced Corrosion  

Science Conference Proceedings (OSTI)

This report documents the role of manganese dioxide (MnO2) in microbiologically influenced corrosion.

2004-12-20T23:59:59.000Z

119

DOE - Office of Legacy Management -- Twin Cities Ammunition - MN 0-01  

NLE Websites -- All DOE Office Websites (Extended Search)

Twin Cities Ammunition - MN 0-01 Twin Cities Ammunition - MN 0-01 FUSRAP Considered Sites Site: TWIN CITIES AMMUNITION (MN.0-01) Eliminated from further consideration under FUSRAP - Referred to DOD Designated Name: Not Designated Alternate Name: None Location: New Brighton , Minnesota MN.0-01-1 Evaluation Year: 1987 MN.0-01-2 Site Operations: Site was formerly licensed under 10CFR 70 by the NRC. MN.0-01-1 MN.0-01-2 Site Disposition: Eliminated - No Authority - Referred to DOD MN.0-01-1 Radioactive Materials Handled: None Indicated Primary Radioactive Materials Handled: None Radiological Survey(s): None Indicated Site Status: Eliminated from further consideration under FUSRAP - Referred to DOD MN.0-01-2 Also see Documents Related to TWIN CITIES AMMUNITION MN.0-01-1 - DOE Letter; Mott to Spence; Listings of Military

120

Effects of Mn Doping on the Dielectric Properties of Nnanostructured ...  

Science Conference Proceedings (OSTI)

In order to further improve the insulation resistance, manganese (Mn) was introduced (0.005 at%-1.0 at%) into the TiO2 system by a powder coating process...

Note: This page contains sample records for the topic "mn nh nj" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

International Falls, MN Natural Gas Pipeline Imports From Canada...  

U.S. Energy Information Administration (EIA) Indexed Site

per Thousand Cubic Feet) International Falls, MN Natural Gas Pipeline Imports From Canada (Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

122

International Falls, MN Natural Gas Pipeline Imports From Canada...  

U.S. Energy Information Administration (EIA) Indexed Site

Million Cubic Feet) International Falls, MN Natural Gas Pipeline Imports From Canada (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

123

Diluted magnetic semiconductor effects in Mn-implanted silicon carbide  

Science Conference Proceedings (OSTI)

Light transmission and Faraday rotation spectra measured at the temperature of 2 K were compared for silicon carbide single crystals of 4H polytype (4H-SiC), implanted with 3.8 x 10{sup 16} cm{sup -2} of Mn ions at the beam energy of 190 keV, and a control 4H-SiC single crystal sample, which was not implanted. Mn ion implantation led to the creation of a Mn-doped surface layer with the average Mn concentration of 10{sup 21} cm{sup -3} and a thickness of approximately 0.2 {mu}m. Transmission of light through the implanted crystal changed only slightly in comparison with the control sample, which however, corresponded to a relatively strong attenuation in the implanted layer. This was interpreted as a result of scattering, which emerges in the surface layer due to optical nonuniformities, created by the high energy ion irradiation. The presence of a thin Mn-ion-containing surface layer led, despite its small thickness, to noticeable changes in the sample Faraday rotation spectra. The estimated values of the Verdet constant for this layer were about three orders of magnitude larger and of opposite sign compared to the Verdet constant values of the undoped sample. Magnetic field dependencies of the Faraday rotation contribution from the implanted layer were found to be saturating functions, which points to a proportionality of the Faraday rotation to the magnetization of the paramagnetic Mn ion subsystem. Based on these findings we conclude that the Mn-implanted SiC layer exhibits magneto-optical properties typical of a diluted magnetic semiconductor. At the same time, no ferromagnetic ordering was observed in the studied (Si, Mn)C sample.

Komarov, A. V.; Ryabchenko, S. M. [Institute of Physics of the National Academy of Sciences of Ukraine, 46 Nauki Ave., Kiev 03028 (Ukraine); Los, A. V. [ISS Ltd., Semiconductors and Circuits Lab, 15 Bozhenko Street, Kiev 03680 (Ukraine); Freescale Semiconductor Ukraine LLC., 15 Bozhenko Street, Kiev 03680 (Ukraine); Romanenko, S. M. [ISS Ltd., Semiconductors and Circuits Lab, 15 Bozhenko Street, Kiev 03680 (Ukraine)

2011-04-15T23:59:59.000Z

124

Verification of Allowable Stresses In ASME Section III Subsection NH For Grade 91 Steel & Alloy 800H  

Science Conference Proceedings (OSTI)

The database for the creep-rupture of 9Cr-1Mo-V (Grade 91) steel was collected and reviewed to determine if it met the needs for recommending time-dependent strength values, S{sub t}, for coverage in ASME Section III Subsection NH (ASME III-NH) to 650 C (1200 F) and 600,000 hours. The accumulated database included over 300 tests for 1% total strain, nearly 400 tests for tertiary creep, and nearly 1700 tests to rupture. Procedures for analyzing creep and rupture data for ASME III-NH were reviewed and compared to the procedures used to develop the current allowable stress values for Gr 91 for ASME II-D. The criteria in ASME III-NH for estimating S{sub t} included the average strength for 1% total strain for times to 600,000 hours, 80% of the minimum strength for tertiary creep for times to 600,000 hours, and 67% of the minimum rupture strength values for times to 600,000 hours. Time-temperature-stress parametric formulations were selected to correlate the data and make predictions of the long-time strength. It was found that the stress corresponding to 1% total strain and the initiation of tertiary creep were not the controlling criteria over the temperature-time range of concern. It was found that small adjustments to the current values in III-NH could be introduced but that the existing values were conservative and could be retained. The existing database was found to be adequate to extend the coverage to 600,000 hours for temperatures below 650 C (1200 F).

R. W. Swindeman; M. J. Swindeman; B. W. Roberts; B. E. Thurgood; D. L. Marriott

2007-11-30T23:59:59.000Z

125

Effect of sulfated CaO on NO reduction by NH{sub 3} in the presence of excess oxygen  

Science Conference Proceedings (OSTI)

The effect of sulfated CaO on NO reduction by NH{sub 3} in the presence of excess oxygen was investigated to evaluate the potential of simultaneous SO{sub 2} and NO removal at the temperature range of 700-850{sup o}C. The physical and chemical properties of the CaO sulfation products were analyzed to investigate the NO reduction mechanism. Experimental results showed that sulfated CaO had a catalytic effect on NO reduction by NH{sub 3} in the presence of excess O{sub 2} after the sulfation reaction entered the transition control stage. With the increase of CaO sulfation extent in this stage, the activity for NO reduction first increased and then decreased, and the selectivity of NH{sub 3} for NO reduction to N{sub 2} increased. The byproduct (NO{sub 2} and N{sub 2}O) formation during NO reduction experiments was negligible. X-ray photoelectron spectroscopy (XPS) analysis showed that neither CaSO{sub 3} nor CaS was detected, indicating that the catalytic activity of NO reduction by NH{sub 3} in the presence of excess O{sub 2} over sulfated CaO was originated from the CaSO{sub 4} product. These results revealed that simultaneous SO{sub 2} and NOx control by injecting NH{sub 3} into the dry flue gas desulfurization process for NO reduction might be achieved. 38 refs., 6 figs., 1 tab.

Tianjin Li; Yuqun Zhuo; Yufeng Zhao; Changhe Chen; Xuchang Xu [Tsinghua University, Beijing (China). Key Laboratory for Thermal Science and Power Engineering of Ministry of Education

2009-04-15T23:59:59.000Z

126

Plasma-sprayed semiconductor electrodes: Photoelectrochemical characterization and NH sub 3 photoproduction by substoichiometric tungsten oxides  

Science Conference Proceedings (OSTI)

Two substoichiometric tungsten oxide coatings have been obtained by plasma spray of WO{sub 3} powder on Ti substrates. The films are 40 {plus minus} 20 {mu}m thick and are yellow (WO{sub 2.99}) or dark blue (WO{sub 2.97}). WO{sub 2.99} coatings show a highly textured surface with a specific area 27.9 times the geometrical one. X-ray diffraction pattern reveals that their structure is a mixture of monoclinic and triclinic phases. The yellow films have been characterized photoelectrochemically in regenerative cells by using O{sub 2}/H{sub 2}O redox at pH 2.0. Under anodic polarization of 1.5 V (SCE) their quantum yield is between 10% and 20% in the wavelength range comprised between 270 and 430 nm with an indirect bandgap of 2.55 eV and a flatband potential of {minus}0.1 V. WO{sub 2.99} films have been tested for NH{sub 3} photoproduction.

Ladouceur, M.; Dodelet, J.P. (INRS-Energie, Varennes, Quebec (Canada)); Tourillon, G. (Universite Paris-Sud, Orsay (France)); Parent, L.; Dallaire, S. (IGM, Boucherville, Quebec (Canada))

1990-05-31T23:59:59.000Z

127

NGA_99fin.vp  

Gasoline and Diesel Fuel Update (EIA)

DAKOTA NEBRASKA KANSAS ARIZONA NEW MEXICO OKLAHOMA ARKANSAS MISSOURI IOWA MINNESOTA WISCONSIN MICH PA MD DELAWARE CONNECTICUT RHODE ISLAND MASS NH NJ ILL INDIANA OHIO VIRGINIA WV...

128

Studies on a novel secondary battery: MH/MnO{sub 2} rechargeable battery. 2: Characteristics of the MnO{sub 2} cathode  

SciTech Connect

The characteristics of the MnO{sub 2} cathode of a MH/MnO{sub 2} battery have been studied by cyclic voltammetry, x-ray diffraction, and potentiostatic techniques. It was found that the addition of Ni(OH){sub 2} to the MnO{sub 2} can prevent overcharge of the MnO{sub 2} and decrease the imbalance of the charge/discharge states of the positive and negative electrodes, raise the working voltage of the MH/MnO{sub 2} cell, and prevent the formation of Mn{sub 3}O{sub 4}, thereby improving the rechargeability of the MnO{sub 2} electrode. The discharge mechanism is also discussed.

Xia, X.; Guo, Z. [Xinjiang Univ., Urumqi, Xinjiang (China). Dept. of Chemistry

1997-08-01T23:59:59.000Z

129

Molecular beam epitaxy growth of exchange-biased PtMn/NiFe bilayers with a spontaneously ordered PtMn layer  

Science Conference Proceedings (OSTI)

We report the direct epitaxial growth of equiatomic ordered antiferromagnetic PtMn layers by molecular beam epitaxy. Such layers are used in giant magnetoresistance spin valve sensors as the antiferromagnetic pinning layer. Structural characterization and phase identification confirmed the spontaneous formation of the chemically ordered face-centered-tetragonal (L1{sub 0}) phase of PtMn with about 87.4% ordering. Based on the antiferromagnetic PtMn layer, we prepared exchange-biased PtMn/NiFe bilayers with various PtMn thicknesses. The exchange anisotropy field of the bilayer with NiFe grown on PtMn stabilizes at about 50 Oe beyond a PtMn thickness of 15 nm. Although the exchange anisotropy field is small compared to that of the polycrystalline system, the antiferromagnetic domain structure is stable over repetitive external magnetic field cycling and no training effect is observed.

Choi, Y. S.; Petford-Long, A. K.; Ward, R. C. C.; Fan, R.; Goff, J. P.; Hase, T. P. A. [Department of Materials, University of Oxford, Parks Road, Oxford OX1 3PH (United Kingdom); Clarendon Laboratory, University of Oxford, Parks Road, Oxford OX1 3PU (United Kingdom); Department of Physics, University of Liverpool, Liverpool L69 7ZE (United Kingdom); Department of Physics, University of Durham, Durham DH1 3LE (United Kingdom)

2006-04-15T23:59:59.000Z

130

MN471004, Electrical Safety Manual Sponsor: Michael W. Hazen, 4000  

NLE Websites -- All DOE Office Websites (Extended Search)

MN471004, Electrical Safety Manual MN471004, Electrical Safety Manual Sponsor: Michael W. Hazen, 4000 Revision Date: June 9, 2011 Replaces Document Dated: September 4, 2007 This document is no longer a CPR. This document implements the requirements of Corporate Procedure ESH100.2.ELC.1, Manage Electrical Hazards. IMPORTANT NOTICE: A printed copy of this document may not be the document currently in effect. The official version is the online version located on the Sandia Restricted Network (SRN). Subject Matter Experts: Marc Williams and David Paoletta MN471004, Issue S Revision Date: June 9, 2011; Replaces Document Dated: April 29, 2008 Review Date: August 29, 2007 Administrative Changes: February 5, 2008, June 28, 2010, July 28, 2010, May 26, 2011, June 9, 2011, November 28, 2011, February 1, 2012

131

Capacitive deionization of NH{sub 4}CIO{sub 4} solutions with carbon aerogel electrodes. Revision 1  

Science Conference Proceedings (OSTI)

A process for capacitive deionization of water with a stack of carbon aerogel electrodes was developed. Unlike ion exchange, one of the more conventional deionization processes, no chemicals are required for regeneration of the system; electricity is used instead. An aqueous solution of NH{sub 4}ClO{sub 4} is pumped through the electrochemical cell. After polarization, NH{sub 4}{sup +} and ClO{sub 4}{sup -} ions are removed from the water by the imposed electric field and trapped in the extensive cathodic and anodic double layers. Thsi process produces one stream of purified water and a second stream of concentrate. Effects of cell voltage, salt concentration, and cycling on electrosorption capacity were studied and results reported.

Farmer, J.C.; Fix, D.V.; Mack, G.V.; Pekala, R.W.; Poco, J.F.

1996-01-01T23:59:59.000Z

132

A reaction mechanism for titanium nitride CVD from TiCl{sub 4} and NH{sub 3}  

Science Conference Proceedings (OSTI)

A gas-phase and surface reaction mechanism for the CVD of TiN from TiCl{sub 4} and NH{sub 3} is proposed. The only gas-phase process is complex formation, which can compete with deposition. The surface mechanism postulates the stepwise elimination of Cl and H atoms from TiCl{sub 4} and NH{sub 3}, respectively, to form solid TiN and gaseous HCl. The mechanism also accounts for the change in oxidation state of Ti by allowing for liberation of N{sub 2}. Provided that the surface composition is at steady state, the stoichiometry of the overall reaction is reproduced exactly. In addition, the global kinetic law predicted by the mechanism is successfully fit to new deposition data from a rotating disk reactor and is shown to be consistent with literature results.

Larson, R.S.; Allendorf, M.D.

1995-12-01T23:59:59.000Z

133

Rechargeable Zn-MnO sub 2 alkaline batteries  

SciTech Connect

In this paper progress in the development of rechargeable alkaline zinc-manganese dioxide cells is described. The advantages and limitations of the system are evaluated. Laboratory tests run on commercial primary alkaline cells as well as model simulations of a bipolar MnO{sub 2} electrode show that the rechargeable alkaline battery may be able to compete with lead-acid, nickel-cadmium, and secondary lithium cells for low- to moderate-rate applications. However, because of this poor performance at high rates and low temperatures, the alkaline MnO{sub 2} battery is not suitable for present automotive starting applications.

Wruck, W.J.; Reichman, B.; Bullock, K.R.; Kao, W.H. (Corporate Applied Research, Johnson Controls, Inc., Milwaukee, WI (US))

1991-12-01T23:59:59.000Z

134

Magnetic properties of a metal-organic antiferromagnet Mn,,hfipbb...py,,H2O...0.5  

E-Print Network (OSTI)

crystallographically independent Mn atoms Mn1 and Mn2 exist in this structure, and an alternate connection ­MnMnMn are discovered. Here we report the synthesis, structure, and magnetic properties of a metal-organic coordination 0.195, 0.5 mmol , py 2 ml , and H2O 5 ml was sealed in a Teflon-lined acid digestion bomb and heated

Li, Jing

135

Disentangling the Mn moments on different sublattices in the half-metallic ferrimagnet Mn3?xCoxGa  

SciTech Connect

Ferrimagnetic Mn{sub 3-x}Co{sub x}Ga compounds have been investigated by magnetic circular dichroism in x-ray absorption (XMCD). Compounds with x > 0.5 crystallize in the CuHg{sub 2}Ti structure. A tetragonal distortion of the cubic structure occurs for x {le} 0.5. For the cubic phase, magnetometry reveals a linearly increasing magnetization of 2x Bohr magnetons per formula unit obeying the generalized Slater-Pauling rule. XMCD confirms the ferrimagnetic character with Mn atoms occupying two different sublattices with antiparallel spin orientation and different degrees of spin localization and identifies the region 0.6 < x {le} 0.8 as most promising for a high spin polarization at the Fermi level. Individual Mn moments on inequivalent sites are compared to theoretical predictions.

Klaer, P.; Jenkins, C.A.; Alijani, V.; Winterlik, J.; Balke, B.; Felser, C.; Elmers, H.J.

2011-05-03T23:59:59.000Z

136

Thermal Instability of Olivine-type LiMnPO4 Cathodes  

NLE Websites -- All DOE Office Websites (Extended Search)

Thermal Instability of Olivine-type LiMnPO4 Cathodes Title Thermal Instability of Olivine-type LiMnPO4 Cathodes Publication Type Journal Article Year of Publication 2010 Authors...

137

Electrodeposited Al-Mn Alloys with Microcrystalline, Nanocrystalline, Amorphous and Nano-quasicrystalline Structures  

E-Print Network (OSTI)

AlMn alloys with Mn content ranging from 0 to 15.8 at.% are prepared by electrodeposition from an ionic liquid at room temperature, and exhibit a remarkably broad range of structures. The alloys are characterized through ...

Ruan, Shiyun

138

Assessment of the Diffusive Gradients in Thin-films (DGT) technique to assess the plant availability of Mn in soils.  

E-Print Network (OSTI)

predicts copper availability to plants. EnvironmentalAttempts to assess Mn availability have been impeded due towill influence the Mn availability. Often flooding of soils

Mundus, Simon; Husted, Sren; Lombi, Enzo

2009-01-01T23:59:59.000Z

139

Control of magnetic properties of MnBi and MnBiCu thin films by Kr{sup +} ion irradiation  

SciTech Connect

Mn{sub 52}Bi{sub 48} (15 nm) and Mn{sub 54}Bi{sub 24}Cu{sub 21} (15 nm) thin films were prepared by the magnetron sputtering and vacuum annealing at 350 deg. C, and the variations of their structures and magnetic properties with 30 keV Kr{sup +} ion irradiation were studied. The MnBi and MnBiCu films exhibited saturation magnetizations M{sub s} of 180 emu/cc and 210 emu/cc, the coercivities H{sub c} of 10 kOe and 3.4 kOe, respectively. The M{sub s} and H{sub c} of the MnBi abruptly vanished by the irradiation of ion dose at 3 x 10{sup 14} ions/cm{sup 2}, while those of the MnBiCu film gradually decreased with increasing the ion dose and became zero at 5 x 10{sup 13} ions/cm{sup 2}. The different trend on the ion irradiation between MnBi and MnBiCu films is understood by the surface structure of the film, i.e., the MnBi has convex islands on its surface, which protect the underneath NiAs-type MnBi from the irradiation, while the MnBiCu has rather flat surface, and its crystal structure was uniformly modified by the irradiation. From the surface flatness and the uniformity of the MnBiCu film, as well as the low annealing temperature of 350 deg. C, it was concluded that the MnBiCu film is one of the attractive materials for high-density ion irradiation bit patterned media.

Xu Qianqian; Kanbara, Ryutarou; Kato, Takeshi; Iwata, Satoshi [Department of Quantum Engineering, Nagoya University Furo-cho, Chikusa-ku, Nagoya, 464-8603 (Japan); Tsunashima, Shigeru [Department of Research, Nagoya Industrial Science Research Institute, 1-13 Yotsuya-dori, Chikusa-ku, Nagoya 460-0819 (Japan)

2012-04-01T23:59:59.000Z

140

Intramolecular ET in Ru-Modified MnCyt c  

NLE Websites -- All DOE Office Websites (Extended Search)

Tetraammine(L)ruthenium(III)-Modified Tetraammine(L)ruthenium(III)-Modified Manganocytochromes c Ji Sun and James F. Wishart Inorg. Chem. 37, 1124-1126 (1998) [Find paper at ACS Publications] or use ACS Articles on Request Abstract: Manganese-substituted horse heart cytochrome c was prepared by replacing the iron in the heme group according to established methods. The resulting manganicytochrome c was subsequently modified at histidine-33 with three ruthenium complexes trans-(NH3)4(L)Ru-His33, where L = NH3, pyridine or isonicotinamide. Proof of correct derivatization was obtained by atomic absorption analysis of manganese and ruthenium, differential pulse voltammetry and electrospray mass spectroscopy. Manganese(II)-to-ruthenium(III) intramolecular electron transfer rates were measured as a function of temperature by pulse radiolysis, using oxidation

Note: This page contains sample records for the topic "mn nh nj" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Thermoelectric figure of merit of LSCoO-Mn perovskites  

Science Conference Proceedings (OSTI)

Oxide ceramics with nominal composition of La"0"."8Sr"0"."2Co"1"-"xMn"xO"3(0= Keywords: 72.20.Pa, 84.60.Bk, 84.60.Rb, 85.80.Fi, LSCoO compounds, Thermoelectric figure of merit, Thermoelectric materials

J. E. Rodrguez; D. Cadavid; L. C. Moreno

2008-11-01T23:59:59.000Z

142

Clarification of enhanced ferromagnetism in Be-codoped InMnP fabricated using Mn/InP:Be bilayers grown by molecular beam epitaxy  

Science Conference Proceedings (OSTI)

The p-type InMnP:Be epilayers were prepared by the sequential growth of Mn/InP:Be bilayers using molecular-beam-epitaxy and the subsequent in-situ annealing at 200-300 deg. C. In triple-axis x-ray diffraction patterns, the samples revealed a shoulder peak indicative of intrinsic InMnP. The ferromagnetic transition in InMnP:Be was observed to occur at the elevated temperature of {approx}140 K, and the ferromagnetic spin-domains clearly appeared in magnetic force microscopy images. The improved ferromagnetic properties are attributed to the increased p-d hybridation due to high p-type conductivity of InMnP:Be (p {approx} 10{sup 20 }cm{sup -3}). The results suggest that enhanced ferromagnetism can be effectively obtained from Be-codoped InMnP.

Shon, Yoon; Lee, Sejoon; Taek Yoon, Im; Jeon, H. C.; Lee, D. J.; Kang, T. W. [Quantum-functional Semiconductor Research Center, Dongguk University-Seoul, Seoul 100-715 (Korea, Republic of); Song, J. D. [Center for Spintronics Research, Korea Institute of Science and Technology, Seoul 136-791 (Korea, Republic of); Yoon, Chong S. [Department of Materials Science and Engineering, Hanyang University, Seoul 133-791 (Korea, Republic of); Kim, D. Y. [Department of Semiconductor Science, Dongguk University-Seoul, Seoul 100-715 (Korea, Republic of); Park, C. S. [School of Electrical Engineering, Korea University, Anam-dong, Seongbuk-gu, Seoul 136-713 (Korea, Republic of)

2011-11-07T23:59:59.000Z

143

The Mn effect on magnetic structure of FeMn-B amorphous metals , D.M.C. Nicholson2  

E-Print Network (OSTI)

usually less than 1mm in thickness, because fast cooling rate is (~ 106 °K/sec) required for retaining] for a historical summary on the discovery of bulk amorphous metals.) They have been proposed for a range in transformers and electrical motors. Lately, high Mn content, Fe-based bulk amorphous metals have been

Widom, Michael

144

UNH Cooperative Extension is an equal opportunity educator and employer, UNH, U.S. Dept. of Agriculture and NH counties cooperating.  

E-Print Network (OSTI)

-up of what you did to Rhiannon Beauregard, 4-H State Program Coordinator. Signature of Applicant Date: Rhiannon Beauregard, 4-H State Program Coordinator Moiles House, 180 Main Street, Durham, NH 03824 Rhiannon.beauregard

New Hampshire, University of

145

Precios de Gasolina  

NLE Websites -- All DOE Office Websites (Extended Search)

Precios de Gasolina para Ciudades en EEUU Pulse en el mapa para ver los precios de la gasolina en diferentes ciudades de su estado. AK VT ME NH NH MA MA RI CT CT DC NJ DE DE NY WV...

146

Plutonium Oxidation and Subsequent Reduction by Mn (IV) Minerals  

Science Conference Proceedings (OSTI)

Plutonium sorbed to rock tuff was preferentially associated with manganese oxides. On tuff and synthetic pyrolusite (Mn{sup IV}O{sub 2}), Pu(IV) or Pu(V) was initially oxidized, but over time Pu(IV) became the predominant oxidation state of sorbed Pu. Reduction of Pu(V/VI), even on non-oxidizing surfaces, is proposed to result from a lower Gibbs free energy of the hydrolyzed Pu(IV) surface species versus that of the Pu(V) or Pu(VI) surface species. This work suggests that despite initial oxidation of sorbed Pu by oxidizing surfaces to more soluble forms, the less mobile form of Pu, Pu(IV), will dominate Pu solid phase speciation during long term geologic storage. The safe design of a radioactive waste or spent nuclear fuel geologic repository requires a risk assessment of radionuclides that may potentially be released into the surrounding environment. Geochemical knowledge of the radionuclide and the surrounding environment is required for predicting subsurface fate and transport. Although difficult even in simple systems, this task grows increasingly complicated for constituents, like Pu, that exhibit complex environmental chemistries. The environmental behavior of Pu can be influenced by complexation, precipitation, adsorption, colloid formation, and oxidation/reduction (redox) reactions (1-3). To predict the environmental mobility of Pu, the most important of these factors is Pu oxidation state. This is because Pu(IV) is generally 2 to 3 orders of magnitude less mobile than Pu(V) in most environments (4). Further complicating matters, Pu commonly exists simultaneously in several oxidation states (5, 6). Choppin (7) reported Pu may exist as Pu(IV), Pu(V), or Pu(VI) oxic natural groundwaters. It is generally accepted that plutonium associated with suspended particulate matter is predominantly Pu(IV) (8-10), whereas Pu in the aqueous phase is predominantly Pu(V) (2, 11-13). The influence of the character of Mn-containing minerals expected to be found in subsurface repository environments on Pu oxidation state distributions has been the subject of much recent research. Kenney-Kennicutt and Morse (14), Duff et al. (15), and Morgenstern and Choppin (16) observed oxidation of Pu facilitated by Mn(IV)-bearing minerals. Conversely, Shaughnessy et al. (17) used X-ray Absorption near-edge spectroscopy (XANES) to show reduction of Pu(VI) by hausmannite (Mn{sup II}Mn{sub 2}{sup III}O{sub 4}) and manganite ({gamma}-Mn{sup III}OOH) and Kersting et al., (18) observed reduction of Pu(VI) by pyrolusite (Mn{sup IV}O{sub 2}). In this paper, we attempt to reconcile the apparently conflicting datasets by showing that Mn-bearing minerals can indeed oxidize Pu, however, if the oxidized species remains on the solid phase, the oxidation step competes with the formation of Pu(IV) that becomes the predominant solid phase Pu species with time. The experimental approach we took was to conduct longer term (approximately two years later) oxidation state analyses on the Pu sorbed to Yucca Mountain tuff (initial analysis reported by Duff et al., (15)) and measure the time-dependant changes in the oxidation state distribution of Pu in the presence of the Mn mineral pyrolusite.

KAPLAN, DANIEL

2005-09-13T23:59:59.000Z

147

Electrodeposited Mn-Co Alloy Coating For SOFC Interconnects  

NLE Websites -- All DOE Office Websites (Extended Search)

Electrodeposited Electrodeposited Mn-Co Alloy Coating For SOFC Interconnects H. McCrabb * , T. Hall * , J. Wu # , H. Zhang # , X. Liu # , E.J. Taylor * * Faraday Technology Inc., 315 Huls Dr., Clayton, OH 45315, USA # West Virginia University, Dept. of Mechanical and Aerospace Eng.ESB, Morgantown, WV, 26506, USA Overall Objective Overall Objective Principal Investigator: Heather McCrabb, Company Name: Faraday Technology, Inc., Address: 315 Huls Drive, Clayton, OH 45315, Phone: 937-836-7749, E-mail: heathermccrabb@faradaytechnology.com, Company website: faradaytechnology.com Previous Work at WVU Results Develop an inexpensive manufacturing process for depositing (Mn,Co) 3 O 4 spinel coatings onto SOFC interconnects. Introduction The decrease in the SOFC operating temperatures from 1000°C to between 650 and 850°C has enabled the use of chromia-forming ferritic stainless steels as interconnects

148

Charge transport properties of CdMnTe radiation detectors  

Science Conference Proceedings (OSTI)

Growth, fabrication and characterization of indium-doped cadmium manganese telluride (CdMnTe)radiation detectors have been described. Alpha-particle spectroscopy measurements and time resolved current transient measurements have yielded an average charge collection efficiency approaching 100 %. Spatially resolved charge collection efficiency maps have been produced for a range of detector bias voltages. Inhomogeneities in the charge transport of the CdMnTe crystals have been associated with chains of tellurium inclusions within the detector bulk. Further, it has been shown that the role of tellurium inclusions in degrading chargecollection is reduced with increasing values of bias voltage. The electron transit time was determined from time of flight measurements. From the dependence of drift velocity on applied electric field the electron mobility was found to be n = (718 55) cm2/Vs at room temperature.

Kim K.; Rafiel, R.; Boardman, M.; Reinhard, I.; Sarbutt, A.; Watt, G.; Watt, C.; Uxa, S.; Prokopovich, D.A.; Belas, E.; Bolotnikov, A.E.; James, R.B.

2012-04-11T23:59:59.000Z

149

High-Resolution Mn EXAFS of the Oxygen-Evolving Complex inPhotosystem II: Structural Implications for the Mn4Ca Cluster  

DOE Green Energy (OSTI)

The biological generation of oxygen by the oxygen-evolving complex in photosystem II (PS II) is one of natures most important reactions. The recent X-ray crystal structures, while limited by resolutions of 3.2 to 3.5 A, have located the electron density associated with the Mn4Ca complex within the multi-protein PS II complex. Detailed structures critically depend on input from spectroscopic techniques such as EXAFS and EPR/ENDOR, as the XRD resolution does not allow for accurate determination of the position of Mn/Ca or the bridging and terminal ligand atoms. The number and distances of Mn-Mn/Ca/ligand interactions determined from EXAFS provide important constraints for the structure of the Mn cluster. Here we present data from a high-resolution EXAFS method using a novel multi-crystal monochromator that show three short Mn-Mn distances between 2.7 and 2.8 A and hence the presence of three di-mu-oxobridged units in the Mn4Ca cluster. This result imposes clear limitations on the proposed structures based on spectroscopic and diffraction data and provides input for refining such structures.

Yano, Junko; Pushkar, Yulia; Glatzel, Pieter; Lewis, Azul; Sauer,Kenneth; Messinger, Johannes; Bergmann, Uwe; Yachandra, Vittal

2005-09-06T23:59:59.000Z

150

DENSE GAS TRACERS IN PERSEUS: RELATING THE N{sub 2}H{sup +}, NH{sub 3}, AND DUST CONTINUUM PROPERTIES OF PRE- AND PROTOSTELLAR CORES  

SciTech Connect

We investigate 35 prestellar cores and 36 protostellar cores in the Perseus molecular cloud. We find a very tight correlation between the physical parameters describing the N{sub 2}H{sup +} and NH{sub 3} gas. Both the velocity centroids and the line widths of N{sub 2}H{sup +} and NH{sub 3} correlate much better than either species correlates with CO, as expected if the nitrogen-bearing species are probing primarily the dense core gas where the CO has been depleted. We also find a tight correlation in the inferred abundance ratio between N{sub 2}H{sup +} and para-NH{sub 3} across all cores, with N(p-NH{sub 3})/N(N{sub 2}H{sup +}) = 22 +- 10. We find a mild correlation between NH{sub 3} (and N{sub 2}H{sup +}) column density and the (sub)millimeter dust continuum derived H{sub 2} column density for prestellar cores, N(p-NH{sub 3})/N(H{sub 2}) {approx}10{sup -8}, but do not find a fixed ratio for protostellar cores. The observations suggest that in the Perseus molecular cloud the formation and destruction mechanisms for the two nitrogen-bearing species are similar, regardless of the physical conditions in the dense core gas. While the equivalence of N{sub 2}H{sup +} and NH{sub 3} as powerful tracers of dense gas is validated, the lack of correspondence between these species and the (sub)millimeter dust continuum observations for protostellar cores is disconcerting and presently unexplained.

Johnstone, Doug; Kirk, Helen [National Research Council Canada, Herzberg Institute of Astrophysics, 5071 West Saanich Road, Victoria, BC V9E 2E7 (Canada); Rosolowsky, Erik [University of British Columbia Okanagan, Kelowna, BC V1V 1V7 (Canada); Tafalla, Mario, E-mail: doug.johnstone@nrc-cnrc.gc.c [Observatorio Astronomico Nacional (IGN), Alfonso XII 3, E-28014 Madrid (Spain)

2010-03-10T23:59:59.000Z

151

Structural and magnetic properties of MnAs nanoclusters formed by Mn ion implantation in GaAs  

SciTech Connect

Ferromagnetic (FM) nanostructures embedded in semiconductors are of fundamental interest since their physical properties could be used in new devices such as memories, sensors or spintronics. In this work, we present results obtained on the synthesis and characterization of nanosized MnAs ferromagnets buried in GaAs. These nanocrystals are formed either by single Mn implantation or Mn + As co-implantation at room temperature into GaAs wafers at 141 and 180 keV respectively. Two doses, 1 x 10{sup 16} and 2 x 10{sup 16} ions {center_dot} cm{sup -2} for each impurity, are tested. Pieces of the wafers are then annealed by RTA or classical furnace annealing at various temperatures under N{sub 2} atmosphere for increasing times. HRTEM and diffraction analysis show that under such conditions MnAs precipitates form with a regular hexagonal structure, the 3m orientation-relationship of precipitates with respect to the matrix offers the most energetically stable configuration. Size distributions are systematically extracted from statistical analysis of ''2 beam'' TEM images. The precipitate mean diameters of nanocrystals populations range from 9 to 13 nm depending on the annealing conditions. Magnetization measurements by SQUID magnetometry on the same samples reveal a progressive transition from a superparamagnetic behavior at room temperature to an FM one at 2K, reflecting a distribution of blocking temperature, due to distribution of size and to dipolar interactions. Curie temperatures in the range of 360K were measured.

Serres, A.; Benassayag, G.; Respaud, M.; Armand, C.; Pesant, J.C.; Mari, A.; Liliental-Weber, Z.; Claverie, A.

2002-08-01T23:59:59.000Z

152

NGA_99fin.vp  

Gasoline and Diesel Fuel Update (EIA)

9 9 NJ WY AK AL CA AR CO CT DE FL GA HI ID KS IL IN IA IA KY LA ME MI MA MD MN MS MT MO NE ND OH NV NM NY NH NC OK OR PA RI SC SD TN TX UT VT WA WV WI AZ VA DC 0.00-1.99 2.00-2.99 3.00-3.99 4.00-4.99 5.00-5.99 6.00-6.99 7.00+ NJ WY AK AL CA AR CO CT DE FL GA HI ID KS IL IN IA IA KY LA ME MI MA MD MN MS MT MO NE ND OH NV NM NY NH NC OK OR PA RI SC SD TN TX UT VT WA WV WI AZ VA DC 0.00-1.99 2.00-2.99 3.00-3.99 4.00-4.99 5.00-5.99 6.00-6.99 7.00+ 18. Average Price of Natural Gas Delivered to U.S. Onsystem Industrial Consumers, 1999 (Dollars per Thousand Cubic Feet) Figure 19. Average Price of Natural Gas Delivered to U.S. Electric Utilities, 1999 (Dollars per Thousand Cubic Feet) Figure Sources: Federal Energy Regulatory Commission (FERC), Form FERC-423, "Monthly Report of Cost and Quality of Fuels for Electric Plants," and Energy Information Administration (EIA), Form EIA-176, "Annual Report of Natural and Supplemental

153

C:\ANNUAL\VENTCHAP.V8\NGAla1109.vp  

Gasoline and Diesel Fuel Update (EIA)

Energy Energy Information Administration / Natural Gas Annual 2000 NJ WY AK AL CA AR CO CT DE FL GA HI ID KS IL IN IA IA KY LA ME MI MA MD MN MS MT MO NE ND OH NV NM NY NH NC OK OR PA RI SC SD TN TX UT VT WA WV WI AZ VA DC Source: Energy Information Administration (EIA), Form EIA-176, "Annual Report of Natural and Supplemental Gas Supply and Disposition." NJ WY AK AL CA AR CO CT DE FL GA HI ID KS IL IN IA IA KY LA ME MI MA MD MN MS MT MO NE ND OH NV NM NY NH NC OK OR PA RI SC SD TN TX UT VT WA WV WI AZ VA DC Note: Commercial prices include natural gas delivered for use as vehicle fuel. Source: Energy Information Administration (EIA), Form EIA-176, "Annual Report of Natural and Supplemental Gas Supply and Disposition." 0.00-1.99 2.00-3.99 4.00-5.99 6.00-7.99 8.00-9.99 10.00-11.99 12.00+ 0.00-1.99 2.00-3.99 4.00-5.99 6.00-7.99 8.00-9.99 10.00-11.99 12.00+ 17. Average Price of Natural Gas Delivered to U.S. Residential

154

NGA98fin5.vp  

Gasoline and Diesel Fuel Update (EIA)

8 8 NJ WY AK AL CA AR CO CT DE FL GA HI ID KS IL IN IA IA KY LA ME MI MA MD MN MS MT MO NE ND OH NV NM NY NH NC OK OR PA RI SC SD TN TX UT VT WA WV WI AZ VA DC 0.00-1.99 2.00-2.99 3.00-3.99 4.00-4.99 5.00-5.99 6.00-6.99 7.00+ NJ WY AK AL CA AR CO CT DE FL GA HI ID KS IL IN IA IA KY LA ME MI MA MD MN MS MT MO NE ND OH NV NM NY NH NC OK OR PA RI SC SD TN TX UT VT WA WV WI AZ VA DC 0.00-1.99 2.00-2.99 3.00-3.99 4.00-4.99 5.00-5.99 6.00-6.99 7.00+ 18. Average Price of Natural Gas Delivered to U.S. Onsystem Industrial Consumers, 1998 (Dollars per Thousand Cubic Feet) Figure 19. Average Price of Natural Gas Delivered to U.S. Electric Utilities, 1998 (Dollars per Thousand Cubic Feet) Figure Sources: Federal Energy Regulatory Commission (FERC), Form FERC-423, "Monthly Report of Cost and Quality of Fuels for Electric Plants," and Energy Information Administration (EIA), Form EIA-176, "Annual Report of Natural and Supplemental

155

C:\ANNUAL\VENTCHAP.V8\NGAla1109.vp  

Gasoline and Diesel Fuel Update (EIA)

2000 2000 NJ WY AK AL CA AR CO CT DE FL GA HI ID KS IL IN IA IA KY LA ME MI MA MD MN MS MT MO NE ND OH NV NM NY NH NC OK OR PA RI SC SD TN TX UT VT WA WV WI AZ VA DC 0.00-1.99 2.00-3.99 4.00-5.99 6.00-7.99 8.00-9.99 10.00-11.99 12.00+ NJ WY AK AL CA AR CO CT DE FL GA HI ID KS IL IN IA IA KY LA ME MI MA MD MN MS MT MO NE ND OH NV NM NY NH NC OK OR PA RI SC SD TN TX UT VT WA WV WI AZ VA DC 0.00-1.99 2.00-3.99 4.00-5.99 6.00-7.99 8.00-99.99 10.00-11.99 12.00+ 19. Average Price of Natural Gas Delivered to U.S. Onsystem Industrial Consumers, 2000 (Dollars per Thousand Cubic Feet) Figure 20. Average Price of Natural Gas Delivered to U.S. Electric Utilities, 2000 (Dollars per Thousand Cubic Feet) Figure Sources: Federal Energy Regulatory Commission (FERC), Form FERC-423, "Monthly Report of Cost and Quality of Fuels for Electric Plants," and Energy Information Administration (EIA), Form EIA-176, "Annual Report of Natural

156

C:\Annual\VENTCHAP.V8\NGA02.vp  

Gasoline and Diesel Fuel Update (EIA)

2002 2002 0.00-1.99 2.00-3.99 4.00-5.99 6.00-7.99 8.00-9.99 10.00-11.99 12.00+ WA ID MT OR CA NV UT AZ NM CO WY ND SD MN WI NE IA KS MO TX IL IN OH MI OK AR TN W VA KY MD PA WI NY VT NH MA CT ME RI NJ DE DC NC SC GA AL MS LA FL HI AK Source: Energy Information Administration (EIA), Form EIA-176, "Annual Report of Natural and Supplemental Gas Supply and Disposition," and Form EIA 910, "Monthly Natural Gas Marketer Survey." 17. Average Price of Natural Gas Delivered to U.S. Commercial Consumers, 2002 (Dollars per Thousand Cubic Feet) Figure 0.00-1.99 2.00-3.99 4.00-5.99 6.00-7.99 8.00-9.99 10.00-11.99 12.00+ WA ID MT OR CA NV UT AZ NM CO WY ND SD MN WI NE IA KS MO TX IL IN OH MI OK AR TN W VA KY MD PA WI NY VT NH MA CT ME RI NJ DE DC NC SC GA AL MS LA FL HI AK 16. Average Price of Natural Gas Delivered to U.S. Residential Consumers, 2002 (Dollars per Thousand Cubic Feet) Figure Source: Energy Information Administration

157

Microsoft Word - Figure_18_19.doc  

Gasoline and Diesel Fuel Update (EIA)

9 9 0.00-2.49 2.50-4.49 4.50-6.49 6.50-8.49 8.50-10.49 10.50+ WA ID MT OR CA NV UT AZ NM CO WY ND SD MN WI NE IA KS MO TX IL IN OH MI OK AR TN WV VA KY PA WI NY VT NH MA CT ME RI NJ DE DC NC SC GA AL MS LA FL HI AK MD 0.00-2.49 2.50-4.49 4.50-6.49 6.50-8.49 8.50-10.49 10.50+ WA ID MT OR CA NV UT AZ NM CO WY ND SD MN WI NE IA KS MO TX IL IN OH MI OK AR TN WV VA KY MD PA WI NY VT NH MA CT ME RI NJ DE DC NC SC GA AL MS LA FL HI AK Figure 18. Average Price of Natural Gas Delivered to U.S. Onsystem Industrial Consumers, 2004 (Dollars per Thousand Cubic Feet) Figure 19. Average Price of Natural Gas Delivered to U.S. Electric Power Consumers, 2004 (Dollars per Thousand Cubic Feet) Source: Energy Information Administration (EIA), Form EIA-176, "Annual Report of Natural and Supplemental Gas Supply and Disposition." Note: States where the electric power price has been withheld (see Table 23) are included in the $0.00-$2.49 price category.

158

Microsoft Word - NGAMaster_State_TablesNov12.doc  

Gasoline and Diesel Fuel Update (EIA)

49 49 0.00-1.99 2.00-3.99 4.00-5.99 6.00-7.99 8.00-9.99 10.00-11.99 12.00+ WA ID MT OR CA NV UT AZ NM CO WY ND SD MN WI NE IA KS MO TX IL IN OH MI OK AR TN WV VA KY PA WI NY VT NH MA CT ME RI NJ DE DC NC SC GA AL MS LA FL HI AK MD 0.00-1.99 2.00-3.99 4.00-5.99 6.00-7.99 8.00-9.99 10.00-11.99 12.00+ WA ID MT OR CA NV UT AZ NM CO WY ND SD MN WI NE IA KS MO TX IL IN OH MI OK AR TN WV VA KY MD PA WI NY VT NH MA CT ME RI NJ DE DC NC SC GA AL MS LA FL HI AK Figure 18. Average Price of Natural Gas Delivered to U.S. Onsystem Industrial Consumers, 2003 (Dollars per Thousand Cubic Feet) Figure 19. Average Price of Natural Gas Delivered to U.S. Electric Power Consumers, 2003 (Dollars per Thousand Cubic Feet) Source: Energy Information Administration (EIA), Form EIA-176, "Annual Report of Natural and Supplemental Gas Supply and Disposition." Note: States where the electric power price has been withheld (see Table 23) are included in the $0.00-$1.99 price category.

159

C:\Annual\VENTCHAP.V8\NGA02.vp  

Gasoline and Diesel Fuel Update (EIA)

2 2 0.00-1.99 2.00-3.99 4.00-5.99 6.00-7.99 8.00-9.99 10.00-11.99 12.00+ WA ID MT OR CA NV UT AZ NM CO WY ND SD MN WI NE IA KS MO TX IL IN OH MI OK AR TN W VA KY MD PA WI NY VT NH MA CT ME RI NJ DE DC NC SC GA AL MS LA FL HI AK 18. Average Price of Natural Gas Delivered to U.S. Onsystem Industrial Consumers, 2002 (Dollars per Thousand Cubic Feet) Figure Source: Energy Information Administration (EIA), Form EIA-176, "Annual Report of Natural and Supplemental Gas Supply and Disposition." 0.00-1.99 2.00-3.99 4.00-5.99 6.00-7.99 8.00-9.99 10.00-11.99 12.00+ WA ID MT OR CA NV UT AZ NM CO WY ND SD MN WI NE IA KS MO TX IL IN OH MI OK AR TN W VA KY MD PA WI NY VT NH MA CT ME RI NJ DE DC NC SC GA AL MS LA FL HI AK 19. Average Price of Natural Gas Delivered to U.S. Electric Utilities, 2002 (Dollars per Thousand Cubic Feet) Figure Sources: Federal Energy Regulatory Commission (FERC), Form FERC-423, "Monthly Report of Cost

160

NGA_99fin.vp  

Gasoline and Diesel Fuel Update (EIA)

9 9 NJ WY AK AL CA AR CO CT DE FL GA HI ID KS IL IN IA IA KY LA ME MI MA MD MN MS MT MO NE ND OH NV NM NY NH NC OK OR PA RI SC SD TN TX UT VT WA WV WI AZ VA DC Source: Energy Information Administration (EIA), Form EIA-176, "Annual Report of Natural and Supplemental Gas Supply and Disposition." NJ WY AK AL CA AR CO CT DE FL GA HI ID KS IL IN IA IA KY LA ME MI MA MD MN MS MT MO NE ND OH NV NM NY NH NC OK OR PA RI SC SD TN TX UT VT WA WV WI AZ VA DC Note: Commercial prices include natural gas delivered for use as vehicle fuel. Source: Energy Information Administration (EIA), Form EIA-176, "Annual Report of Natural and Supplemental Gas Supply and Disposition." 0.00-1.99 2.00-2.99 3.00-3.99 4.00-4.99 5.00-5.99 6.00-6.99 7.00+ 0.00-1.99 2.00-2.99 3.00-3.99 4.00-4.99 5.00-5.99 6.00-6.99 7.00+ 16. Average Price of Natural Gas Delivered to U.S. Residential Consumers, 1999 (Dollars per Thousand Cubic Feet) Figure

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161

C:\ANNUAL\VENTCHAP.V8\NGA.VP  

Gasoline and Diesel Fuel Update (EIA)

8 8 NJ WY AK AL CA AR CO CT DE FL GA HI ID KS IL IN IA IA KY LA ME MI MA MD MN MS MT MO NE ND OH NV NM NY NH NC OK OR PA RI SC SD TN TX UT VT WA WV WI AZ VA DC Source: Energy Information Administration (EIA), Form EIA-176, "Annual Report of Natural and Supplemental Gas Supply and Disposition." NJ WY AK AL CA AR CO CT DE FL GA HI ID KS IL IN IA IA KY LA ME MI MA MD MN MS MT MO NE ND OH NV NM NY NH NC OK OR PA RI SC SD TN TX UT VT WA WV WI AZ VA DC Note: Commercial prices include natural gas delivered for use as vehicle fuel. Source: Energy Information Administration (EIA), Form EIA-176, "Annual Report of Natural and Supplemental Gas Supply and Disposition." 0.00-1.99 2.00-2.99 3.00-3.99 4.00-4.99 5.00-5.99 6.00-6.99 7.00+ 0.00-1.99 2.00-2.99 3.00-3.99 4.00-4.99 5.00-5.99 6.00-6.99 7.00+ 16. Average Price of Natural Gas Delivered to U.S. Residential Consumers, 1997 (Dollars per Thousand Cubic Feet) Figure

162

C:\ANNUAL\VENTCHAP.V8\NewNGA02.vp  

Gasoline and Diesel Fuel Update (EIA)

2001 2001 0.00-1.99 2.00-3.99 4.00-5.99 6.00-7.99 8.00-9.99 10.00-11.99 12.00+ WA ID MT OR CA NV UT AZ NM CO WY ND SD MN WI NE IA KS MO TX IL IN OH MI OK AR TN W VA KY MD PA WI NY VT NH MA CT ME RI NJ DE DC NC SC GA AL MS LA FL HI AK Source: Energy Information Administration (EIA), Form EIA-176, "Annual Report of Natural and Supplemental Gas Supply and Disposition." 28. Average Price of Natural Gas Delivered to U.S. Onsystem Residential Consumers, 2001 (Dollars per Thousand Cubic Feet) Figure 0.00-1.99 2.00-3.99 4.00-5.99 6.00-7.99 8.00-9.99 10.00-11.99 12.00+ WA ID MT OR CA NV UT AZ NM CO WY ND SD MN WI NE IA KS MO TX IL IN OH MI OK AR TN W VA KY MD PA WI NY VT NH MA CT ME RI NJ DE DC NC SC GA AL MS LA FL HI AK Note: Commercial prices include natural gas delivered for use as vehicle fuel. Source: Energy Information Administration (EIA), Form EIA-176, "Annual Report of Natural and Supplemental Gas Supply and Disposition."

163

NGA98fin5.vp  

Gasoline and Diesel Fuel Update (EIA)

1998 1998 NJ WY AK AL CA AR CO CT DE FL GA HI ID KS IL IN IA IA KY LA ME MI MA MD MN MS MT MO NE ND OH NV NM NY NH NC OK OR PA RI SC SD TN TX UT VT WA WV WI AZ VA DC Source: Energy Information Administration (EIA), Form EIA-176, "Annual Report of Natural and Supplemental Gas Supply and Disposition." NJ WY AK AL CA AR CO CT DE FL GA HI ID KS IL IN IA IA KY LA ME MI MA MD MN MS MT MO NE ND OH NV NM NY NH NC OK OR PA RI SC SD TN TX UT VT WA WV WI AZ VA DC Note: Commercial prices include natural gas delivered for use as vehicle fuel. Source: Energy Information Administration (EIA), Form EIA-176, "Annual Report of Natural and Supplemental Gas Supply and Disposition." 0.00-1.99 2.00-2.99 3.00-3.99 4.00-4.99 5.00-5.99 6.00-6.99 7.00+ 0.00-1.99 2.00-2.99 3.00-3.99 4.00-4.99 5.00-5.99 6.00-6.99 7.00+ 16. Average Price of Natural Gas Delivered to U.S. Residential Consumers, 1998 (Dollars per Thousand Cubic Feet) Figure

164

C:\ANNUAL\VENTCHAP.V8\NewNGA02.vp  

Gasoline and Diesel Fuel Update (EIA)

2001 2001 0.00-1.99 2.00-3.99 4.00-5.99 6.00-7.99 8.00-9.99 10.00-11.99 12.00+ WA ID MT OR CA NV UT AZ NM CO WY ND SD MN WI NE IA KS MO TX IL IN OH MI OK AR TN W VA KY MD PA WI NY VT NH MA CT ME RI NJ DE DC NC SC GA AL MS LA FL HI AK Source: Energy Information Administration (EIA), Form EIA-176, "Annual Report of Natural and Supplemental Gas Supply and Disposition." 30. Average Price of Natural Gas Delivered to U.S. Onsystem Industrial Consumers, 2001 (Dollars per Thousand Cubic Feet) Figure 0.00-1.99 2.00-3.99 4.00-5.99 6.00-7.99 8.00-9.99 10.00-11.99 12.00+ WA ID MT OR CA NV UT AZ NM CO WY ND SD MN WI NE IA KS MO TX IL IN OH MI OK AR TN W VA KY MD PA WI NY VT NH MA CT ME RI NJ DE DC NC SC GA AL MS LA FL HI AK 31. Average Price of Natural Gas Delivered to U.S. Electric Utilities, 2001 (Dollars per Thousand Cubic Feet) Figure Sources: Federal Energy Regulatory Commission (FERC), Form FERC-423, "Monthly Report of

165

Effect of a high electric field on the conductivity of MnGa{sub 2}S{sub 4}, MnIn{sub 2}S{sub 4}, and MnGaInS{sub 4} single crystals  

Science Conference Proceedings (OSTI)

The results of studying the effect of a high electric field on the conductivity of MnGa{sub 2}S{sub 4}, MnIn{sub 2}S{sub 4}, and MnGaInS{sub 4} single crystals are reported. The activation energy is determined in high and low electric fields. It is established that the decrease in the activation energy with increasing the external voltage is associated with decreasing the depth of the potential well, in which the electron is located.

Niftiev, N. N. [Azerbaijan State Pedagogical University (Azerbaijan); Tagiev, O. B. [National Academy of Sciences of Azerbaijan, Institute of Physics (Azerbaijan)

2009-09-15T23:59:59.000Z

166

Ga{sub 1-x}Mn{sub x}N epitaxial films with high magnetization  

Science Conference Proceedings (OSTI)

We report on the fabrication of pseudomorphic wurtzite Ga{sub 1-x}Mn{sub x}N grown on GaN with Mn concentrations up to 10% using molecular beam epitaxy. According to Rutherford backscattering, the Mn ions are mainly at the Ga-substitutional positions, and they are homogeneously distributed according to depth-resolved Auger-electron spectroscopy and secondary-ion mass-spectroscopy measurements. A random Mn distribution is indicated by transmission electron microscopy, and no Mn-rich clusters are present for optimized growth conditions. A linear increase of the c-lattice parameter with increasing Mn concentration is found using x-ray diffraction. The ferromagnetic behavior is confirmed by superconducting quantum-interference measurements showing saturation magnetizations of up to 150 emu/cm{sup 3}.

Kunert, G.; Kruse, C.; Figge, S.; Hommel, D. [Semiconductor Epitaxy, Institute of Solid State Physics, University of Bremen, D-28359 Bremen (Germany); Dobkowska, S.; Jakiela, R.; Stefanowicz, W.; Sawicki, M. [Institute of Physics, Polish Academy of Science, PL-02-668 Warszawa (Poland); Li, Tian; Bonanni, A. [Institute for Semiconductor and Solid State Physics, Johannes Kepler University Linz, A 4040 Linz (Austria); Reuther, H.; Grenzer, J.; Borany, J. von [Helmholtz-Zentrum Dresden-Rossendorf, Institute of Ion Beam Physics and Materials Research, Bautzner Landstrasse 400, 01328 Dresden (Germany); Dietl, T. [Institute of Physics, Polish Academy of Science, PL-02-668 Warszawa (Poland); Institute of Theoretical Physics, Faculty of Physics, University of Warsaw, PL-00-681 Warszawa (Poland)

2012-07-09T23:59:59.000Z

167

Time resolved magneto-optical studies of ferromagnetic InMnSb films  

SciTech Connect

We report time resolved magneto-optical measurements in InMnSb ferromagnetic films with 2% and 2.8% Mn contents grown by low temperature molecular beam epitaxy. In order to probe a possible interaction between the spins of photoexcited carriers and the Mn ions, we measured spin dynamics before and after aligning the Mn ions by applying an external magnetic field at temperatures above and below the samples' Curie temperatures. We observed no significant temperature or magnetic field dependence in the relaxation times and attribute the observed dynamics entirely to the relaxation of photoexcited electrons in the conduction band where the s-d coupling with the localized Mn ions is significantly weaker compared to the p-d exchange coupling. We observed several differences in the optical response of our InMnSb samples which could have been influenced mainly by the samples' growth conditions.

Frazier, M.; Kini, R. N.; Nontapot, K.; Khodaparast, G. A. [Department of Physics, Virginia Tech, Blacksburg, Virginia 24061 (United States); Wojtowicz, T. [Institute of Physics, Polish Academy of Sciences 02-668 Warsaw (Poland); Liu, X.; Furdyna, J. K. [Department of Physics, University of Notre Dame, Notre Dame, Indiana 46556 (United States)

2008-02-11T23:59:59.000Z

168

Investigation of structure, magnetic, and transport properties of Mn-doped SiC films  

SciTech Connect

Mn-doped SiC films were fabricated by radio frequency magnetron sputtering technique. The structure, composition, and magnetic and transport properties of the films were investigated. The results show the films have the 3C-SiC crystal structure and the doped Mn atoms in the form of Mn{sup 2+} ions substitute for C sites in SiC lattice. All the films are ferromagnetic at 300 K, and the ferromagnetism in films arises from the doped Mn atoms and some extended defects. In addition, the saturation magnetization increases with the Mn-doped concentration increasing. The Mn doping does not change the semiconductor characteristics of the SiC films.

Sun Xianke [School of Material Science and Engineering, Tianjin University, Tianjin 300172 (China); Tianjin Key Laboratory for Photoelectric Materials and Devices, Tianjin University of Technology, Tianjin 300384 (China); Guo Ruisong [School of Material Science and Engineering, Tianjin University, Tianjin 300172 (China); An Yukai [Tianjin Key Laboratory for Photoelectric Materials and Devices, Tianjin University of Technology, Tianjin 300384 (China); School of Material Science and Engineering, Tianjin University of Technology, Tianjin 300384 (China); Liu Jiwen [School of Material Science and Engineering, Tianjin University, Tianjin 300172 (China); Tianjin Key Laboratory for Photoelectric Materials and Devices, Tianjin University of Technology, Tianjin 300384 (China); School of Material Science and Engineering, Tianjin University of Technology, Tianjin 300384 (China)

2013-07-15T23:59:59.000Z

169

Electronic Structure and Oxidation State Changes in the Mn (4) Ca Cluster of Photosystem II  

Science Conference Proceedings (OSTI)

Oxygen-evolving complex (Mn{sub 4}Ca cluster) of Photosystem II cycles through five intermediate states (S{sub i}-states, i = 0-4) before a molecule of dioxygen is released. During the S-state transitions, electrons are extracted from the OEC, either from Mn or alternatively from a Mn ligand. The oxidation state of Mn is widely accepted as Mn{sub 4}(III{sub 2},IV{sub 2}) and Mn{sub 4}(III,IV{sub 3}) for S{sub 1} and S{sub 2} states, while it is still controversial for the S{sub 0} and S{sub 3} states. We used resonant inelastic X-ray scattering (RIXS) to study the electronic structure of Mn{sub 4}Ca complex in the OEC. The RIXS data yield two-dimensional plots that provide a significant advantage by obtaining both K-edge pre-edge and L-edge-like spectra (metal spin state) simultaneously. We have collected data from PSII samples in the each of the S-states and compared them with data from various inorganic Mn complexes. The spectral changes in the Mn 1s2p{sub 3/2} RIXS spectra between the S-states were compared to those of the oxides of Mn and coordination complexes. The results indicate strong covalency for the electronic configuration in the OEC, and we conclude that the electron is transferred from a strongly delocalized orbital, compared to those in Mn oxides or coordination complexes. The magnitude for the S{sub 0} to S{sub 1}, and S{sub 1} to S{sub 2} transitions is twice as large as that during the S{sub 2} to S{sub 3} transition, indicating that the electron for this transition is extracted from a highly delocalized orbital with little change in charge density at the Mn atoms.

Yano, J.; Pushkar, Y.; Messinger, J.; Bergmann, U.; Glatzel, P.; Yachandra, V.K.; /SLAC

2012-08-17T23:59:59.000Z

170

Distinct local electronic structure and magnetism for Mn in amorphous Si and Ge  

SciTech Connect

Transition metals such as Mn generally have large local moments in covalent semiconductors due to their partially filled d shells. However, Mn magnetization in group-IV semiconductors is more complicated than often recognized. Here we report a striking crossover from a quenched Mn moment (<0.1 {mu}{sub B}) in amorphous Si (a-Si) to a large distinct local Mn moment ({ge}3{mu}{sub B}) in amorphous Ge (a-Ge) over a wide range of Mn concentrations (0.005-0.20). Corresponding differences are observed in d-shell electronic structure and the sign of the Hall effect. Density-functional-theory calculations show distinct local structures, consistent with different atomic density measured for a-Si and a-Ge, respectively, and the Mn coordination number N{sub c} is found to be the key factor. Despite the amorphous structure, Mn in a-Si is in a relatively well-defined high coordination interstitial type site with broadened d bands, low moment, and electron (n-type) carriers, while Mn in a-Ge is in a low coordination substitutional type site with large local moment and holes (p-type) carriers. Moreover, the correlation between N{sub c} and the magnitude of the local moment is essentially independent of the matrix; the local Mn moments approach zero when N{sub c} > 7 for both a-Si and a-Ge.

Zeng, Li; Cao, J. X.; Helgren, E.; Karel, J.; Arenholz, E.; Ouyang, Lu; Smith, David J.; Wu, R. Q.; Hellman, F.

2010-06-01T23:59:59.000Z

171

Investigation of Structural Stability of Monolayer MnO 2 Sheet under ...  

Science Conference Proceedings (OSTI)

Presentation Title, Investigation of Structural Stability of Monolayer MnO2 Sheet under Electron Beam Irradiation. Author(s), Yong Wang, Chenghua Sun, Jin Zou ...

172

Ion-exchanged MnO2 nanoparticles as cathodes of lithium ion ...  

Science Conference Proceedings (OSTI)

Presentation Title, Ion-exchanged MnO2 nanoparticles as cathodes of lithium ion batteries at elevated temperatures. Author(s), Dawei Liu, Jasper Wright, Wei...

173

F-8: Modeling of Mn-Ni-Si-Cu Precipitation in Reactor Pressure ...  

Science Conference Proceedings (OSTI)

Presentation Title, F-8: Modeling of Mn-Ni-Si-Cu Precipitation in Reactor .... Steels 316 and Comparison with the Rate Theory Model of a Multicomponent System.

174

Ageing and Toughness of a Mn-Ni-Mo PWR Steel  

Science Conference Proceedings (OSTI)

Abstract Scope, Mn-Ni-Mo steels are widely used in the fabrication of pressurisers, steam generators and pressure vessels of pressurised water reactors (PWR).

175

Optimization of Na 0.44 MnO 2 Cathode Material - Programmaster.org  

Science Conference Proceedings (OSTI)

Symposium, Energy Storage: Materials, Systems, and Applications. Presentation Title, Optimization of Na0.44MnO2 Cathode Material for Use in Aqueous...

176

Low-energy structure of 61Mn populated following $\\beta$ decay of 61Cr  

E-Print Network (OSTI)

$\\beta$ decay of the $^{61}$Cr$_{37}$ ground state has been studied. A new half-life of 233 +/- 11 ms has been deduced, and seven delayed $\\gamma$ rays have been assigned to the daughter, $^{61}$Mn$_{36}$. The low-energy level structure of $^{61}$Mn$_{36}$ is similar to that of the less neutron-rich $^{57,59}$Mn nuclei. The odd-A $_{25}$Mn isotopes follow the systematic trend in the yrast states of the even-even, Z + 1 $_{26}$Fe isotopes, and not that of the Z - 1 $_{24}$Cr isotopes, where a possible onset of collectivity has been suggested to occur already at N = 36.

Crawford, H L; Berryman, J S; Broda, R; Fornal, B; Hoffman, C R; Hoteling, N; Janssens, R V F; Lenzi, S M; Pereira, J; Stoker, J B; Tabor, S L; Walters, W B; Wang, X; Zhu, S

2009-01-01T23:59:59.000Z

177

Low-energy structure of 61Mn populated following $?$ decay of 61Cr  

E-Print Network (OSTI)

$\\beta$ decay of the $^{61}$Cr$_{37}$ ground state has been studied. A new half-life of 233 +/- 11 ms has been deduced, and seven delayed $\\gamma$ rays have been assigned to the daughter, $^{61}$Mn$_{36}$. The low-energy level structure of $^{61}$Mn$_{36}$ is similar to that of the less neutron-rich $^{57,59}$Mn nuclei. The odd-A $_{25}$Mn isotopes follow the systematic trend in the yrast states of the even-even, Z + 1 $_{26}$Fe isotopes, and not that of the Z - 1 $_{24}$Cr isotopes, where a possible onset of collectivity has been suggested to occur already at N = 36.

H. L. Crawford; P. F. Mantica; J. S. Berryman; R. Broda; B. Fornal; C. R. Hoffman; N. Hoteling; R. V. F. Janssens; S. M. Lenzi; J. Pereira; J. B. Stoker; S. L. Tabor; W. B. Walters; X. Wang; S. Zhu

2009-04-29T23:59:59.000Z

178

NOIlVUlSININdV NOIlVWdOdNI AOd3N3 ACTO3NH  

Gasoline and Diesel Fuel Update (EIA)

NOIlVUlSININdV NOIlVWdOdNI AOd3N3 NOIlVUlSININdV NOIlVWdOdNI AOd3N3 ACTO3NH 0661 This publication may be purchased from the Superintendent of Documents, U.S. Government Printing Office. Purchasing in formation for this or other Energy Information Administration (EIA) publications may be obtained from the Government Printing Office or ElA's National Energy Information Center. Questions on energy statistics should be directed to the Center by mail, telephone, or telecommunications device for the hearing impaired. Addresses, telephone numbers, and hours are as follows: National Energy Information Center Energy Information Administration Forrestal Building, Room 1F-048 Washington, DC 20585 (202) 586-8800 Telecommunications Device for the Hearing Impaired Only: (202) 586-1181 8 a.m. - 5 p.m., eastern time, M-F

179

A model of the gas-phase chemistry of boron nitride CVC from BCl{sub 3} and NH{sub 3}  

Science Conference Proceedings (OSTI)

The kinetics of gas-phase reactions occurring during the CVD of boron nitride (BN) from BCl{sub 3} and NH{sub 3} are investigated using an elementary reaction mechanism whose rate constants were obtained from theoretical predictions and literature sources. Plug-flow calculations using this mechanism predict that unimolecular decomposition of BCl{sub 3} is not significant under typical CVD conditions, but that some NH{sub 3} decomposition may occur, especially for deposition occurring at atmospheric pressure. Reaction of BCl{sub 3} with NH{sub 3} is rapid under CVD conditions and yields species containing both boron and nitrogen. One of these compounds, Cl{sub 2}BNH{sub 2}, is predicted to be a key gas-phase precursor to BN.

Allendorf, M.D.; Melius, C.F.; Osterheld, T.H.

1995-12-01T23:59:59.000Z

180

FLUORESCENCE EXCITATION MODELS OF AMMONIA AND AMIDOGEN RADICAL (NH{sub 2}) IN COMETS: APPLICATION TO COMET C/2004 Q2 (MACHHOLZ)  

SciTech Connect

Ammonia is a major reservoir of nitrogen atoms in cometary materials. However, detections of ammonia in comets are rare, with several achieved at radio wavelengths. A few more detections were obtained through near-infrared observations (around the 3 {mu}m wavelength region), but moderate relative velocity shifts are required to separate emission lines of cometary ammonia from telluric absorption lines in the 3 {mu}m wavelength region. On the other hand, the amidogen radical (NH{sub 2}-a photodissociation product of ammonia in the coma) also shows rovibrational emission lines in the 3 {mu}m wavelength region. Thus, gas production rates for ammonia can be determined from the rovibrational emission lines of ammonia (directly) and amidogen radical (indirectly) simultaneously in the near-infrared. In this article, we present new fluorescence excitation models for cometary ammonia and amidogen radical in the near-infrared, and we apply these models to the near-infrared high-dispersion spectra of comet C/2004 Q2 (Machholz) to determine the mixing ratio of ammonia to water in the comet. Based on direct detection of NH{sub 3} lines, the mixing ratio of NH{sub 3}/H{sub 2}O is 0.46% {+-} 0.03% in C/2004 Q2 (Machholz), in agreement with other results. The mixing ratio of ammonia determined from the NH{sub 2} observations (0.31%-0.79%) is consistent but has relatively larger error, owing to uncertainty in the photodissociation rates of ammonia. At the present level of accuracy, we confirm that NH{sub 3} could be the sole parent of NH{sub 2} in this comet.

Kawakita, Hideyo [Department of Physics, Faculty of Science, Kyoto Sangyo University, Motoyama, Kamigamo, Kita-ku, Kyoto 603-8555 (Japan); Mumma, Michael J., E-mail: kawakthd@cc.kyoto-su.ac.jp [Solar System Exploration Division, Mailstop 690.3, NASA Godard Space Flight Center, Greenbelt, MD 20771 (United States)

2011-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "mn nh nj" from the National Library of EnergyBeta (NLEBeta).
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181

Giant tunneling magnetoresistance in Co{sub 2}MnSi/Al-O/Co{sub 2}MnSi magnetic tunnel junctions  

SciTech Connect

Magnetic tunnel junctions (MTJs) with a stacking structure of Co{sub 2}MnSi/Al-O/Co{sub 2}MnSi were fabricated using magnetron sputtering system. Fabricated MTJ exhibited an extremely large tunneling magnetoresistance (TMR) ratio of 570% at low temperature, which is the highest TMR ratio reported to date for an amorphous Al-O tunneling barrier. The observed dependence of tunneling conductance on bias voltage clearly reveals the half-metallic energy gap of Co{sub 2}MnSi. The origins of large temperature dependence of TMR ratio were discussed on the basis of the present results.

Sakuraba, Y.; Hattori, M.; Oogane, M.; Ando, Y.; Kato, H.; Sakuma, A.; Miyazaki, T.; Kubota, H. [Department of Applied Physics, Graduate School of Engineering, Tohoku University, Aoba-yama 6-6-05, Aramaki, Aoba-ku, Sendai 980-8579 (Japan); Nanoelectronics Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Umezono, Tsukuba 305-8568 (Japan)

2006-05-08T23:59:59.000Z

182

Large energy absorption in Ni-Mn-Ga/polymer composites  

SciTech Connect

Ferromagnetic shape memory alloys can respond to a magnetic field or applied stress by the motion of twin boundaries and hence they show large hysteresis or energy loss. Ni-Mn-Ga particles made by spark erosion have been dispersed and oriented in a polymer matrix to form pseudo 3:1 composites which are studied under applied stress. Loss ratios have been determined from the stress-strain data. The loss ratios of the composites range from 63% to 67% compared to only about 17% for the pure, unfilled polymer samples.

Feuchtwanger, Jorge; Richard, Marc L.; Tang, Yun J.; Berkowitz, Ami E.; O'Handley, Robert C.; Allen, Samuel M. [Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); University of California, San Diego, La Joya, California 92093 (United States); Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States)

2005-05-15T23:59:59.000Z

183

Short-term recovery of NH4-15N applied to a temperate forest inceptisol and ultisol in east Tennessee USA  

Science Conference Proceedings (OSTI)

The short-term fate and retention of ammonium (NH4)-{sup 15}nitrogen (N) applied to two types of forest soils in east Tennessee was investigated. Four ridgetop forests, predominantly oak (Quercus spp.), were studied. Five applications of NH{sub 4}-{sup 15}N tracer were made to the forest floor at 2- to 4-week intervals over a 14-week period in 2004. Nitrogen-15 recovery in the forest floor, fine roots (100 weeks) indicated the forest floor is an effective filter for atmospheric N inputs.

Garten Jr, Charles T [ORNL; Brice, Deanne Jane [ORNL; Todd Jr, Donald E [ORNL

2007-11-01T23:59:59.000Z

184

Specific DNA cleavage mediated by [SalenMn(III)][sup +  

Science Conference Proceedings (OSTI)

The combination of [SalenMn(III)][sup +] and a terminal oxidant affords efficient and specific cleavage of right-handed double-helical DNA in regions rich in A:T base pairs. Metal complexes of the tetradentate chelating ligands Salen (Salen = N,N[prime]-ethylenebis(salicylideneaminato)) have been part of the inorganic chemistry literature for several decades. The cationic manganese(III) complex [SalenMn(III)][sup +] (1) is an efficient catalyst for the epoxidation of olefins with terminal oxidants such as iodosylbenzene. 1 also catalyzes oxidative C-H bond activation. The flat, crescent shape of 1, its aromatic and cationic nature, and its ability to catalyze hydrocarbon oxidation are features shared in whole or in part by metal complexes which bind to DNA and cleave it via oxidative processes. These similarities prompted the authors to evaluate the DNA-cleaving properties of 1, and they now report that 1 mediates specific cleavage of right-handed double-helical DNA in a reaction requiring a terminal oxidant. 20 refs., 3 figs., 1 tab.

Gravert, D.J.; Griffin, J.H. (Stanford Univ., CA (United States))

1993-02-12T23:59:59.000Z

185

Category:Utility Rate Impacts on PV Economics By Location | Open Energy  

Open Energy Info (EERE)

Utility Rate Impacts on PV Economics By Location Utility Rate Impacts on PV Economics By Location Jump to: navigation, search Impact of Utility Rates on PV Economics Montgomery, AL Little Rock, AR Flagstaff, AZ Phoenix, AZ Tucson, AZ Arcata, CA LA, CA San Francisco, CA Boulder, CO Eagle County, CO Pueblo, CO Bridgeport, CT Wilmington, DE Miami, FL Tampa, FL Atlanta, GA Savannah, GA Des Moines, IA Mason, IA Boise, ID Chicago, IL Springfield, IL Indianapolis, IN Goodland, KS Wichita, KS Lexington, KY New Orleans, LA Shreveport, LA Boston, MA Baltimore, MD Caribou, ME Portland, ME Detroit, MI Houghton-Lake, MI Traverse City, MI International Falls, MN Minneapolis, MN Kansas City, MO Jackson, MS Billings, MT Greensboro, NC Wilmington, NC Bismarck, ND Minot, ND Omaha, NE Concord, NH Atlantic City, NJ Albuquerque, NM Las Vegas, NV Reno, NV New York, NY

186

Element-specific study of the temperature dependent magnetization of Co-Mn-Sb thin films  

SciTech Connect

Magnetron sputtered thin Co-Mn-Sb films were investigated with respect to their element-specific magnetic properties. Stoichiometric Co{sub 1}Mn{sub 1}Sb{sub 1} crystallized in the C1{sub b} structure has been predicted to be half-metallic and is therefore of interest for spintronics applications. It should show a characteristic antiferromagnetic coupling of the Mn and Co magnetic moments and a transition temperature T{sub C} of about 480K. Although the observed transition temperature of our 20nm thick Co{sub 32.4}Mn{sub 33.7}Sb{sub 33.8}, Co{sub 37.7}Mn{sub 34.1}Sb{sub 28.2} and Co{sub 43.2}Mn{sub 32.6}Sb{sub 24.2} films is in quite good agreement with the expected value, we found a ferromagnetic coupling of the Mn and Co magnetic moments which indicates that the films do not crystallize in the C1{sub b} structure and are probably not fully spin-polarized. The ratio of the Co and Mn moments does not change up to the transition temperature and the temperature dependence of the magnetic moments can be well described by the mean field theory.

Schmalhorst, J.; Ebke, D.; Meinert, M.; Thomas, A.; Reiss, G.; Arenholz, E.

2008-09-30T23:59:59.000Z

187

Cation Effects on the Layer Structure of Biogenic Mn-Oxides  

E-Print Network (OSTI)

Radiation Lightsource (SSRL). Wet sample slurries were placed in an aluminum sample cell with Lexan windows-bs (Samuel Webb, SSRL). Two Mn-oxide references, triclinic birnessite (TcBir) and -MnO2 were synthesized and Environmental and Quality (ISEQ) Graduate Fellowship. M.Z. also thanks Dr. Samuel Webb at SSRL for his help

Sparks, Donald L.

188

[Characterization of lignin and Mn peroxidases from Phanerochaete chrysosporium]. Progress report  

DOE Green Energy (OSTI)

Lignin peroxidases were investigated with respect to enzyme kinetics and NMR spectroscopy of the heme domain. MN peroxidases were studied with respect to the role of oxalate in enzyme activity, the NMR spectroscopy of the heme domain. Gene expression of both lignin and MN peroxidases were examined as well as expression of site-directed mutants aimed at scale up production of these enzymes.

Not Available

1992-12-31T23:59:59.000Z

189

Dietary resveratrol administration increases MnSOD expression and activity in mouse brain  

E-Print Network (OSTI)

SOD protein level (140%) and activity (75%). The increase in MnSOD was not due to a substantial proliferationDietary resveratrol administration increases MnSOD expression and activity in mouse brain Ellen L oxidative stress. In vitro studies have shown an increase in antioxidant enzyme activities following

Stuart, Jeffrey A.

190

Electric-Field Modulation of Curie Temperature in (Ga, Mn)As Field-Effect Transistor Structures with Varying Channel Thickness and Mn Compositions  

SciTech Connect

We have investigated the change of T{sub C} of ferromagnetic semiconductor (Ga, Mn)As by changing hole concentration p. The field effect transistor structure was utilized to change p. The relation T{sub C}propor top{sup 0.2} is obtained for three samples, despite the difference of their Mn composition and thickness, indicating that the relation holds over 2 decades of p.

Nishitani, Y.; Endo, M. [Laboratory for Nanoelectronics and Spintronics, Research Institute of Electrical Communication, Tohoku University, Katahira 2-1-1, Aoba-ku, Sendai 980-8577 (Japan); Chiba, D. [Semiconductor Spintronics Project, Exploratory Research for Advanced Technology, Japan Science and Technology Agency, Sanban-cho 5, Chiyoda-ku, Tokyo 102-0075 (Japan); Laboratory for Nanoelectronics and Spintronics, Research Institute of Electrical Communication, Tohoku University, Katahira 2-1-1, Aoba-ku, Sendai 980-8577 (Japan); Matsukura, F.; Ohno, H. [Laboratory for Nanoelectronics and Spintronics, Research Institute of Electrical Communication, Tohoku University, Katahira 2-1-1, Aoba-ku, Sendai 980-8577 (Japan); Semiconductor Spintronics Project, Exploratory Research for Advanced Technology, Japan Science and Technology Agency, Sanban-cho 5, Chiyoda-ku, Tokyo 102-0075 (Japan)

2010-01-04T23:59:59.000Z

191

Estudo das propriedades termomecnicas da liga cu 78,3% - al 9,8% mn 11,9%.  

E-Print Network (OSTI)

??The alloys Cu 78,3% - Al 9,8% - Mn 11,9 and 77.5% Cu - Al 9.8% - Mn 11,9% -% Nb 0.5 - 0.3% Ni (more)

Rafael Evaristo Calute

2012-01-01T23:59:59.000Z

192

Scanning tunneling microscopy reveals LiMnAs is a room temperature anti-ferromagnetic semiconductor  

SciTech Connect

We performed scanning tunneling microscopy and spectroscopy on a LiMnAs(001) thin film epitaxially grown on an InAs(001) substrate by molecular beam epitaxy. While the in situ cleavage exposed only the InAs(110) non-polar planes, the cleavage continued into the LiMnAs thin layer across several facets. We combined both topography and current mappings to confirm that the facets correspond to LiMnAs. By spectroscopy we show that LiMnAs has a band gap. The band gap evidenced in this study, combined with the known Neel temperature well above room temperature, confirms that LiMnAs is a promising candidate for exploring the concepts of high temperature semiconductor spintronics based on antiferromagnets.

Wijnheijmer, A. P.; Koenraad, P. M. [COBRA Inter-University Research Institute, Department of Applied Physics, Eindhoven University of Technology, P. O. Box 513, NL-5600 MB Eindhoven (Netherlands); Marti, X. [Faculty of Mathematics and Physics, Charles University in Prague, Ke Karlovu 3, 121 16 Prague 2 (Czech Republic); Institute of Physics ASCR, v.v.i., Cukrovarnicka 10, 162 53 Prague 6 (Czech Republic); Holy, V. [Faculty of Mathematics and Physics, Charles University in Prague, Ke Karlovu 3, 121 16 Prague 2 (Czech Republic); Cukr, M.; Novak, V. [Institute of Physics ASCR, v.v.i., Cukrovarnicka 10, 162 53 Prague 6 (Czech Republic); Jungwirth, T. [Institute of Physics ASCR, v.v.i., Cukrovarnicka 10, 162 53 Prague 6 (Czech Republic); School of Physics and Astronomy, University of Nottingham, Nottingham NG7 2RD (United Kingdom)

2012-03-12T23:59:59.000Z

193

Improvement of Thermal Stability of Li-Ion Batteries by Polymer Coating of LiMn2O4  

E-Print Network (OSTI)

lithium-ion battery by arresting the Mn + dissolution, thereby increasing the battery stability. Key Words: Lithium Battery, Cathode,

Stroeve, Pieter; Vidu, Ruxandra

2004-01-01T23:59:59.000Z

194

Manganese trends in a sample of thin and thick disk stars. The origin of Mn  

E-Print Network (OSTI)

CONTEXT: Manganese is an iron-peak element and although the nucleosynthesis path that leads to its formation is fairly well understood, it remains unclear which objects, SN II and/or SN Ia, that contribute the majority of Mn to the interstellar medium. It also remains unclear to which extent the supernovae Mn yields depend on the metallicity of the progenitor star or not. AIMS: By using a well studied and well defined sample of 95 dwarf stars we aim at further constraining the formation site(s) of Mn. METHODS: We derive Mn abundances through spectral synthesis of four Mn I lines at 539.4, 549.2, 601.3, and 601.6 nm. Stellar parameters and data for oxygen are taken from Bensby et al. (2003, 2004, 2005). RESULTS: When comparing our Mn abundances with O abundances for the same stars we find that the abundance trends in the stars with kinematics of the thick disk can be explained by metallicity dependent yields from SN II. We go on and combine our data for dwarf stars in the disks with data for dwarf and giant stars in the metal-poor thick disk and halo from the literature. We find that dwarf and giant stars show the same trends, which indicates that neither non-LTE nor evolutionary effects are a major concern for Mn. Furthermore, the [Mn/O] vs [O/H] trend in the halo is flat. CONCLUSIONS: We conclude that the simplest interpretation of our data is that Mn is most likely produced in SN II and that the Mn yields for such SNae must be metallicity dependent. Contribution from SN Ia in the metal-rich thin disk can not, however, be excluded.

S. Feltzing; M. Fohlman; T. Bensby

2007-03-19T23:59:59.000Z

195

Low temperature hydrothermally synthesized nanocrystalline orthorhombic LiMnO2 cathode material for lithium-ion cells  

Science Conference Proceedings (OSTI)

Nanocrystalline orthorhombic LiMnO2 particles with an average particle size of about 35 nm in diameter were successfully synthesized by a hydrothermal process at 160-180 C from trimanganese tetroxide (Mn3O4) prepared ... Keywords: hydrothermal process, lithium ion battery, nanocrystalline, orthorhombic LiMnO2, solvothermal process

Mengqiang Wu; Ai Chen; Rongqing Xu; Yue Li

2003-05-01T23:59:59.000Z

196

A rational self-sacrificing template route to LiMn2O4nanotubes and nanowires  

Science Conference Proceedings (OSTI)

Single-crystalline LiMn2O4 nanotubes and nanowires have been synthesized via a low-temperature molten salt synthesis method, using the prepared ?-MnO2 nanotubes and ?-MnO2 nanowires as the precursors ...

Baojun Yang; Xinsong Yuan; Duoli Chai

2011-01-01T23:59:59.000Z

197

Recrystallization behavior of a supersaturated Al Mn alloy  

SciTech Connect

The effect of concurrent precipitation on recrystallization behavior during the isothermal annealing of a supersaturated and deformed Al-Mn alloy was investigated. It is found that concurrent precipitation strongly affects the recrystallization behavior of this alloy. At low temperatures, concurrent precipitation retards recrystallization and results in large flat grains. The size of recrystallized grains decreases significantly with increasing temperature. The kinetics of recrystallization was determined by measurements of hardness. The JMAK exponent decreases from 3.0 to 0.8 as the annealing temperature increases from 371 C to 427 C. The activation energy for recrystallization of the alloy is about 456 kJ/mol. Concurrent precipitation enhances the activation energy for recrystallization of aluminum alloys.

Radhakrishnan, Balasubramaniam [ORNL; Liu, W C [Yanshan University

2010-01-01T23:59:59.000Z

198

Metalloantibiotic Mn(II)-bacitracin complex mimicking manganese superoxide dismutase  

SciTech Connect

Superoxide dismutase (SOD) activities of various metallobacitracin complexes were evaluated using the riboflavin-methionine-nitro blue tetrazolium assay. The radical scavenging activity of various metallobacitracin complexes was shown to be higher than those of the negative controls, e.g., free transition metal ions and metal-free bacitracin. The SOD activity of the complex was found to be in the order of Mn(II) > Cu(II) > Co(II) > Ni(II). Furthermore, the effect of bacitracin and their complexation to metals on various microorganisms was assessed by antibiotic susceptibility testing. Moreover, molecular modeling and quantum chemical calculation of the metallobacitracin complex was performed to evaluate the correlation of electrostatic charge of transition metal ions on the SOD activity.

Piacham, Theeraphon [Department of Clinical Microbiology, Faculty of Medical Technology, Mahidol University, Bangkok 10700 (Thailand); Pure and Applied Biochemistry, Chemical Center, Lund University, P.O. Box 124, 22100 Lund (Sweden); Isarankura-Na-Ayudhya, Chartchalerm [Department of Clinical Microbiology, Faculty of Medical Technology, Mahidol University, Bangkok 10700 (Thailand); Nantasenamat, Chanin [Department of Clinical Microbiology, Faculty of Medical Technology, Mahidol University, Bangkok 10700 (Thailand); Yainoy, Sakda [Department of Clinical Microbiology, Faculty of Medical Technology, Mahidol University, Bangkok 10700 (Thailand); Ye Lei [Pure and Applied Biochemistry, Chemical Center, Lund University, P.O. Box 124, 22100 Lund (Sweden); Buelow, Leif [Pure and Applied Biochemistry, Chemical Center, Lund University, P.O. Box 124, 22100 Lund (Sweden); Prachayasittikul, Virapong [Department of Clinical Microbiology, Faculty of Medical Technology, Mahidol University, Bangkok 10700 (Thailand)]. E-mail: mtvpr@mucc.mahidol.ac.th

2006-03-24T23:59:59.000Z

199

Interfacial studies of a thin-film Li2Mn4O9 electrode  

NLE Websites -- All DOE Office Websites (Extended Search)

Interfacial studies of a thin-film Li2Mn4O9 electrode Interfacial studies of a thin-film Li2Mn4O9 electrode Title Interfacial studies of a thin-film Li2Mn4O9 electrode Publication Type Journal Article Year of Publication 1999 Authors Kostecki, Robert, Fanping Kong, Yoshiaki Matsuo, and Frank R. McLarnon Journal Electrochimica Acta Volume 45 Pagination 225-233 Keywords interfacial films, manganese oxide electrode Abstract A thin-film spinel Li2Mn4O9 electrode was prepared by spin coating onto a Pt substrate. Spectroscopic ellipsometry, X-ray diffraction and current-sensing atomic force microscopy (CSAFM) were used to characterize interfacial processes and film formation at this electrode in the presence of 1.0 M LiPF6, EC:DMC (1:1 by volume) electrolyte. Prolonged exposure of the film to the electrolyte at ambient temperature resulted in spontaneous decomposition of the spinel to λ-MnO2 without disruption of the original structure. The surface of the resulting λ-MnO2 film exhibited no significant change in morphology, however a thin passive electrode surface layer was detected by the CSAFM probe. This electrode surface layer exhibited insulating properties and most likely contained Li2O, a by-product of Li2Mn4O9 decomposition.

200

Ferromagnetism in Mn-Implanted Epitaxially Grown Ge on Si(100)  

SciTech Connect

We have studied ferromagnetism of Mn-implanted epitaxial Ge films on silicon. The Ge films were grown by ultrahigh vacuum chemical vapor deposition using a mixture of germane (GeH{sub 4}) and methylgermane (CH{sub 3}GeH{sub 3}) gases with a carbon concentration of less than 1 at. %, and observed surface rms roughness of 0.5 nm, as measured by atomic force microscopy. Manganese ions were implanted in epitaxial Ge films grown on Si (100) wafers to an effective concentration of 16, 12, 6, and 2 at. %. Superconducting quantum interference device measurements showed that only the three highest Mn concentration samples are ferromagnetic, while the fourth sample, with [Mn] = 2 at. %, is paramagnetic. X-ray absorption spectroscopy and x-ray magnetic circular dichroism measurements indicate that localized Mn moments are ferromagnetically coupled below the Curie temperature. Isothermal annealing of Mn-implanted Ge films with [Mn] = 16 at. % at 300 C for up to 1200 s decreases the magnetization but does not change the Curie temperature, suggesting that the amount of the magnetic phase slowly decreases with time at this anneal temperature. Furthermore, transmission electron microscopy and synchrotron grazing incidence x-ray diffraction experiments show that the Mn-implanted region is amorphous, and we believe that it is this phase that is responsible for the ferromagnetism. This is supported by our observation that high-temperature annealing leads to recrystallization and transformation of the material into a paramagnetic phase.

Guchhait, S.; Jamil, M.; Ohldag, H.; Mehta, A.; Arenholz, E.; Lian, G.; Li Fatou, A.; Ferrer, D. A.; Markert, J. T.; Colombo, L.; Banerjee, S. K.

2011-01-05T23:59:59.000Z

Note: This page contains sample records for the topic "mn nh nj" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Energy Transfer Dynamics and Dopant Luminescence in Mn-Doped CdS/ZnS Core/Shell Nanocrystals  

E-Print Network (OSTI)

Mn-doped II-VI semiconductor nanocrystals exhibit bright dopant photoluminescence that has potential usefulness for light emitting devices, temperature sensing, and biological imaging. The bright luminescence comes from the 4T1?6A1 transition of the Mn2+ d electrons after the exciton-dopant energy transfer, which reroutes the exciton relaxation through trapping processes. The driving force of the energy transfer is the strong exchange coupling between the exciton and Mn2+ due to the confinement of exciton in the nanocrystal. The exciton-Mn spatial overlap affecting the exchange coupling strength is an important parameter that varies the energy transfer rate and the quantum yield of Mn luminescence. In this dissertation, this correlation is studied in radial doping location-controlled Mn-doped CdS/ZnS nanocrystals. Energy transfer rate was found decreasing when increasing the doping radius in the nanocrystals at the same core size and shell thickness and when increasing the size of the nanocrystals at a fixed doping radius. In addition to the exciton-Mn energy transfer discussed above, two consecutive exciton-Mn energy transfers can also occur if multiple excitons are generated before the relaxation of Mn (lifetime ~10^-4 - 10^-2 s). The consecutive exciton-Mn energy transfer can further excite the Mn2+ d electrons high in conduction band and results in the quenching of Mn luminescence. The highly excited electrons show higher photocatalytic efficiency than the electrons in undoped nanocrystals. Finally, the effect of local lattice strain on the local vibrational frequency and local thermal expansion was observed via the temperature-dependent Mn luminescence spectral linewidth and peak position in Mn-doped CdS/ZnS nanocrystals. The local lattice strain on the Mn2+ ions is varied using the large core/shell lattice mismatch (~7%) that creates a gradient of lattice strain at various radial locations. When doping the Mn2+ closer to the core/shell interface, the stronger lattice strain softens the vibrational frequency coupled to the 4T1?6A1 transition of Mn2+ (Mn luminescence) by ~50%. In addition, the lattice strain also increases the anharmonicity, resulting in larger local thermal expansion observed from the nearly an order larger thermal shift of the Mn luminescence compared to the Mn-doped ZnS nanocrystals without the core/shell lattice mismatch.

Chen, Hsiang-Yun

2012-12-01T23:59:59.000Z

202

Ni spin switching induced by magnetic frustration in FeMn/Ni/Cu(001)  

SciTech Connect

Epitaxially grown FeMn/Ni/Cu(001) films are investigated by Photoemission Electron Microscopy and Magneto-Optic Kerr Effect. We find that as the FeMn overlayer changes from paramagnetic to antiferromagnetic state, it could switch the ferromagnetic Ni spin direction from out-of-plane to in-plane direction of the film. This phenomenon reveals a new mechanism of creating magnetic anisotropy and is attributed to the out-of-plane spin frustration at the FeMn-Ni interface.

Wu, J.; Choi, J.; Scholl, A.; Doran, A.; Arenholz, E.; Hwang, Chanyong; Qiu, Z. Q.

2009-03-08T23:59:59.000Z

203

Quantum Anomalous Hall Effect in Hg_1-yMn_yTe Quantum Wells  

SciTech Connect

The quantum Hall effect is usually observed when the two-dimensional electron gas is subjected to an external magnetic field, so that their quantum states form Landau levels. In this work we predict that a new phenomenon, the quantum anomalous Hall effect, can be realized in Hg{sub 1-y}Mn{sub y}Te quantum wells, without the external magnetic field and the associated Landau levels. This effect arises purely from the spin polarization of the Mn atoms, and the quantized Hall conductance is predicted for a range of quantum well thickness and the concentration of the Mn atoms. This effect enables dissipationless charge current in spintronics devices.

Liu, Chao-Xing; /Tsinghua U., Beijing /Stanford U., Phys. Dept.; Qi, Xiao-Liang; /Stanford U., Phys. Dept.; Dai, Xi; Fang, Zhong; /Beijing, Inst. Phys.; Zhang, Shou-Cheng; /Stanford U., Phys. Dept.

2010-03-19T23:59:59.000Z

204

Demonstration of molecular beam epitaxy and a semiconducting band structure for I-Mn-V compounds  

SciTech Connect

Our ab initio theory calculations predict a semiconducting band structure of I-Mn-V compounds. We demonstrate on LiMnAs that high-quality materials with group-I alkali metals in the crystal structure can be grown by molecular beam epitaxy. Optical measurements on the LiMnAs epilayers are consistent with the theoretical electronic structure. Our calculations also reproduce earlier reports of high antiferromagnetic ordering temperature and predict large, spin-orbit-coupling-induced magnetic anisotropy effects. We propose a strategy for employing antiferromagnetic semiconductors in high-temperature semiconductor spintronics.

Jungwirth, T. [Institute of Physics ASCR, v.v.i., Cukrovarnicka 10, 162 53 Praha 6 (Czech Republic); School of Physics and Astronomy, University of Nottingham, Nottingham NG7 2RD (United Kingdom); Novak, V.; Cukr, M.; Zemek, J. [Institute of Physics ASCR, v.v.i., Cukrovarnicka 10, 162 53 Praha 6 (Czech Republic); Marti, X.; Horodyska, P.; Nemec, P.; Holy, V. [Faculty of Mathematics and Physics, Charles University in Prague, Ke Karlovu 3, 121 16 Prague 2 (Czech Republic); Maca, F.; Shick, A. B.; Masek, J.; Kuzel, P. [Institute of Physics ASCR, v.v.i., Na Slovance 2, 182 21 Praha 8 (Czech Republic); Nemec, I. [Faculty of Science, Charles University in Prague, Hlavova 2030, 128 40 Prague 2 (Czech Republic); Gallagher, B. L.; Campion, R. P.; Foxon, C. T. [School of Physics and Astronomy, University of Nottingham, Nottingham NG7 2RD (United Kingdom); Wunderlich, J. [Institute of Physics ASCR, v.v.i., Cukrovarnicka 10, 162 53 Praha 6 (Czech Republic); Hitachi Cambridge Laboratory, Cambridge CB3 0HE (United Kingdom)

2011-01-15T23:59:59.000Z

205

Anomalous Stoichiometry Layered Structure and Magnetic Ordering of the Prussian Blue Analog [NEt4]2MnII3(CN)8  

Science Conference Proceedings (OSTI)

Atypical of Prussian blue structured materials, Mn{sup II} and [NEt{sub 4}]CN react to form [NEt{sub 4}]{sub 2}Mn{sub 3}(CN){sub 8} possessing layers of octahedral [Mn{sup II}(CN){sub 6}]{sup 4-} bonded to two high-spin tetrahedral Mn{sup II} sites.

J Her; P Stephens; C Kareis; J Moore; J Miller

2011-12-31T23:59:59.000Z

206

To cities, with nothing : prisoner resettlement in Newark, NJ  

E-Print Network (OSTI)

This thesis considers how cities can improve employment outcomes of recently released, formerly incarcerated people. The Newark Prisoner Reentry Initiative (NPRI) is a unique case where the city directly managed six ...

Feeney, Kevin Joseph

2011-01-01T23:59:59.000Z

207

DOE - Office of Legacy Management -- Maywood Site - NJ 10  

Office of Legacy Management (LM)

Site Fairfield Site Falls City Site Fernald Preserve Gasbuggy Site General Atomics Geothermal Gnome-Coach Site Grand Junction Sites Granite City Site Green River Site Gunnison...

208

RECIPIENT:Princeton Power Systems STATE: NJ PROJECT Marine High...  

NLE Websites -- All DOE Office Websites (Extended Search)

This is a fully licensed facility with established safety and chemical handling protocols . All activities meet OSHA standards and the site is monitored and audited by OSHA,...

209

DOE's NJ HIGH SCHOOL SCIENCE BOWL | Princeton Plasma Physics...  

NLE Websites -- All DOE Office Websites (Extended Search)

Join Our Mailing List A Collaborative National Center for Fusion & Plasma Research Search form Search Search Home About Overview Learn More Visiting PPPL History...

210

Characterization of LiNi?.?Mn?.?O? Thin Film Cathode Prepared by Pulsed Laser Deposition  

E-Print Network (OSTI)

LiNi?.?Mn?.?O? thin films have been grown by pulsed laser deposition (PLD) on stainless steel (SS) substrates. The crystallinity and structure of thin films were investigated by X-ray diffraction (XRD). Microstructure and ...

Xia, Hui

211

D11: Thermodynamic and Electrochemical Properties of the Mg-Mn ...  

Science Conference Proceedings (OSTI)

B7: Synthesis and Electrical Properties of K2NiF4-Type (Ca2-xLnx)MnO4 (Ln=Nd and Sm) B8: Monitoring Oxygen Diffusion in Gd-Doped Ceria by Null...

212

100- The Effect of Mn and Pr Co-Doping on Electrical Properties of ...  

Science Conference Proceedings (OSTI)

144- The Role of Mn Content on Microstructure and Phases of High Alloyed White Cast Irons 145- The Synergy of XRD and XRF in a Shale and Slate Analysis.

213

Southwest MN IPM STUFF All the pestilence that's fit to print  

E-Print Network (OSTI)

and soybeans during hot dry weather. Twospotted spider mites are favored by high temperatures and drought Southwest Research and Outreach Center 23669 130th Street Lamberton, MN 56152 Phone: 507.752.5066 Cell: 507

Amin, S. Massoud

214

Southwest MN IPM STUFF All the pestilence that's fit to print  

E-Print Network (OSTI)

started to show up. This could be a bad year for this disease. Cool wet spring and hot, dry late seasons Research and Outreach Center 23669 130th Street Lamberton, MN 56152 Phone: 507.752.5066 Cell: 507

Amin, S. Massoud

215

Formation of nano-crystalline todorokite from biogenic Mn Xiong Han Feng a,1  

E-Print Network (OSTI)

Formation of nano-crystalline todorokite from biogenic Mn oxides Xiong Han Feng a,1 , Mengqiang Zhu oxides in the environment. Additionally this method may be a viable biosynthesis route for porous, nano

Sparks, Donald L.

216

Mn solid solutions in self-assembled Ge/Si (001) quantum dot heterostructures  

SciTech Connect

Heteroepitaxial Ge{sub 0.98}Mn{sub 0.02} quantum dots (QDs) on Si (001) were grown by molecular beam epitaxy. The standard Ge wetting layer-hut-dome-superdome sequence was observed, with no indicators of second phase formation in the surface morphology. We show that Mn forms a dilute solid solution in the Ge quantum dot layer, and a significant fraction of the Mn partitions into a sparse array of buried, Mn-enriched silicide precipitates directly underneath a fraction of the Ge superdomes. The magnetic response from the ultra-thin film indicates the absence of robust room temperature ferromagnetism, perhaps due to anomalous intermixing of Si into the Ge quantum dots.

Kassim, J.; Nolph, C.; Reinke, P.; Floro, J. [Department of Materials Science and Engineering, University of Virginia, Charlottesville, Virginia 22904 (United States); Jamet, M. [Institut Nanosciences et Cryogenie/SP2M, CEA-UJF, F-38054 Grenoble (France)

2012-12-10T23:59:59.000Z

217

Synthesis, characterization, and microwave-absorbing properties of polypyrrole/MnFe2O4 nanocomposite  

Science Conference Proceedings (OSTI)

Conductive polypyrrole (PPy)-manganese ferrite (MnFe2O4) nanocomposites with core-shell structure were synthesized by in situ polymerization in the presence of dodecyl benzene sulfonic acid (DBSA) as the surfactant and dopant and ...

Seyed Hossein Hosseini; Ahmad Asadnia

2012-01-01T23:59:59.000Z

218

Aliovalent titanium substitution in layered mixed Li Ni-Mn-Co oxides for lithium battery applications  

Science Conference Proceedings (OSTI)

Improved electrochemical characteristics are observed for Li[Ni1/3Co1/3-yMyMn1/3]O2 cathode materials when M=Ti and ycapacity.

Kam, Kinson; Doeff, Marca M.

2010-12-01T23:59:59.000Z

219

Electrophysical properties of semimagnetic solid solutions Hg 1?x Mn x Te  

Science Conference Proceedings (OSTI)

A comprehensive study of the electrophysical properties of the semimagnetic ternary solid solution Hg 1?x Mn x Te an alternative material to Hg 1?x Cd x Te is reported. The charge-carrier scattering

I. M. Nesmelova; V. N. Ryzhkov; M. I. Ibragimova; V. Yu. PetukhovKazan Physicotechnical Institute, Kazan Research Center of the Russian Academy of Sciences, Kazan?420029, Russia

2004-01-01T23:59:59.000Z

220

Spin current switching and spin-filtering effects in Mn-doped boron nitride nanoribbons  

Science Conference Proceedings (OSTI)

The spin transport properties are investigated by means of the first principle approach for boron nitride nanoribbons with one or two substitutional Mn impurities, connected to graphene electrodes. The spin current polarization is evaluated using the ...

G. A. Nemnes

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mn nh nj" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Mn Monolayer Modified Rh for Syngas-to-Ethanol Conversion: A First-Principles Study  

SciTech Connect

Rh is unique in its ability to convert syngas to ethanol with the help of promoters. We performed systematic first-principles computations to examine the catalytic performance of pure and Mn modified Rh(100) surfaces for ethanol formation from syngas. CO dissociation on the surface as well as CO insertion between the chemisorbed CH{sub 3} and the surface are the two key steps. The CO dissociation barrier on the Mn monolayer modified Rh(100) surface is remarkably lowered by {approx}1.5 eV compared to that on Rh(100). Moreover, the reaction barrier of CO insertion into the chemisorbed CH{sub 3} group on the Mn monolayer modified Rh(100) surface is 0.34 eV lower than that of methane formation. Thus the present work provides new mechanistic insight into the role of Mn promoters in improving Rh's selectivity to convert syngas to ethanol.

Li, Fengyu [University of Puerto Rico; Jiang, Deen [ORNL; Zeng, X.C. [University of Nebraska, Lincoln; Chen, Zhongfang [University of Puerto Rico

2012-01-01T23:59:59.000Z

222

Building of a Novel Mn12 Single Molecule Magnet by Assembly of Anisotropic  

NLE Websites -- All DOE Office Websites (Extended Search)

Building of a Novel Mn12 Single Building of a Novel Mn12 Single Molecule Magnet by Assembly of Anisotropic Triangles Building of a Novel Mn12 Single Molecule Magnet by Assembly of Anisotropic Triangles Print Wednesday, 06 July 2011 12:58 Assembly of triangular {MnIII3(O)(salox)3}+ fragments mediated by azido ligands, results in the dodecanuclear [Mn12O4(salox)12(N3)4(MeOH)4(H2O)2] complex with S = 8 ground state and SMM response. After the discovery of the Single-Molecule-Magnet (SMM) behaviour of [Mn6(O)2(salox)6(R-COO)2] (salox = salicylaldoxime, R = Me, Ph) complexes in 2004,1 the chemistry of this family of [Mn6] clusters has been studied in depth: the systematic change of the carboxylato ligands, the study of substitutedR-saloxH2 related ligands,2 the effect of variation of the oxidation state,3 the response under pressure4 or the one-dimensional assembly of [Mn6] units into chains of clusters5 with Single-Chain-Magnet behaviour in some cases,5c,d turn this system into one of the best known in the SMM field. One of the main goals of this work, developed by Brechin et al. has been to modulate the value of the ground spin level, reaching the maximum possible spin S = 12 by means of the adequate choice of methyl or ethyl substituted salicylaldoximes and the understanding of the structural features that control the coupling inside the triangles. Article Link (PDF)

223

DOE/EIA-0131(96) Distribution Category/UC-960 Natural Gas  

Gasoline and Diesel Fuel Update (EIA)

ID ID OR WY ND SD CA NV UT CO NE KS AZ NM OK TX MN WI MI IA IL IN OH MO AR MS AL GA TN KY FL SC NC WV MD DE VA PA NJ NY CT RI MA VT NH ME LA HI AK Japan Mexico Mexico Algeria Canada Canada Canada Canada Canada Canada Canada Algeria Canada United Arab Emirates Interstate Movements of Natural Gas in the United States, 1996 (Volumes Reported in Million Cubic Feet) Supplemental Data From Volume To From Volume To (T) AL KY (T) MA ME (T) AL LA MA NH (T) AL MO (T) MA NJ (T) AL SC MD DC CT RI RI MA DE MD VA DC MA CT (T) Trucked Source: Energy Information Administration (EIA), Form EIA-176, "Annual Report of Natural and Supplemental Gas Supply and Disposition." E I A NERGY NFORMATION DMINISTRATION 906,407 355,260 243,866 220 384,311 576,420 823,799 842,114 27,271 126,012 133 602,841 266 579,598 16,837 268,138 48,442 182,511 219,242 86,897 643,401 619,703 8,157 937,806 292,711 869,951 12,316 590,493 118,256

224

NEUTRON DIFFRACTION STUDY OF A NON-STOICHIOMETRIC Ni-Mn-Ga MSM ALLOY  

SciTech Connect

The structure and chemical order of a Heusler alloy of non-stoichiometric composition Ni-Mn-Ga were studied using constant-wavelength (1.538 ) neutron diffraction at 363K and the diffraction pattern was refined using the FullProf software. At this temperature the structure is austenite (cubic) with Fm-3m space group and lattice constant of a = 5.83913(4) [ ]. The chemical order is of critical importance in these alloys, as Mn becomes antiferromagnetic when the atoms are closer than the radius of the 3d shell. In the studied alloy the refinement of the site occupancy showed that the 4b (Ga site) contained as much as 22% Mn; that significantly alters the distances between the Mn atoms in the crystal and, as a result, also the exchange energy between some of the Mn atoms. Based on the refinement, the composition was determined to be Ni1.91Mn1.29Ga0.8

Ari-Gur, Pnina [Western Michigan University; Garlea, Vasile O [ORNL

2013-01-01T23:59:59.000Z

225

Effects of laser irradiation on the self-assembly of MnAs nanoparticles in a GaAs matrix  

SciTech Connect

We investigate the effects of laser irradiation on the self-assembly of MnAs nanoparticles during solid-phase decomposition in a GaAs matrix. It is found that laser irradiation suppresses the growth of MnAs nanoparticles from small to large size, and that the median diameter D{sub 1} in the size distribution of small MnAs nanoparticles depends on the incident photon energy E following D{sub 1} {approx} E{sup -1/5}. We explain this behavior by the desorption of Mn atoms on the MnAs nanoparticle surface due to resonant optical absorption, in which incident photons excite intersubband electronic transitions between the quantized energy levels in the MnAs nanoparticles.

Hai, Pham Nam; Nomura, Wataru [Department of Electrical Engineering and Information Systems, University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan); Yatsui, Takashi; Ohtsu, Motoichi; Tanaka, Masaaki [Department of Electrical Engineering and Information Systems, University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan); Nanophotonics Research Center, University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)

2012-11-05T23:59:59.000Z

226

Magnetic field-induced phase transformation and variant reorientation in Ni2MnGa and NiMnCoIn magnetic shape memory alloys  

E-Print Network (OSTI)

The purpose of this work is to reveal the governing mechanisms responsible for the magnetic field-induced i) martensite reorientation in Ni2MnGa single crystals, ii) stress-assisted phase transformation in Ni2MnGa single crystals and iii) phase transformation in NiMnCoIn alloys. The ultimate goal of utilizing these mechanisms is to increase the actuation stress levels in magnetic shape memory alloys (MSMAs). Extensive experimental work on magneto-thermo-mechanical (MTM) characterization of these materials enabled us to i) better understand the ways to increase the actuation stress and strain and decrease the required magnetic field for actuation in MSMAs, ii) determine the effects of main MTM parameters on reversible magnetic field induced phase transformation, such as magnetocrystalline anisotropy energy (MAE), Zeeman energy (ZE), stress hysteresis, thermal hysteresis, critical stress for the stress induced phase transformation and crystal orientation, iii) find out the feasibility of employing polycrystal MSMAs, and iv) formulate a thermodynamical framework to capture the energetics of magnetic field-induced phase transformations in MSMAs. Magnetic shape memory properties of Ni2MnGa single crystals were characterized by monitoring magnetic field-induced strain (MFIS) as a function of compressive stress and stress-induced strain as a function of magnetic field. It is revealed that the selection of the operating temperature with respect to martensite start and Curie temperatures is critical in optimizing actuator performance. The actuation stress of 5 MPa and work output of 157 kJm?3 are obtained by the field-induced variant reorientation in NiMnGa alloys. Reversible and one-way stress-assisted field-induced phase transformations are observed in Ni2MnGa single crystals under low field magnitudes (transformation and shape memory characteristics of NiMnCoIn single crystals are also studied. Reversible field-induced phase transformation is observed only under high magnetic fields (>4T). Necessary magnetic and mechanical conditions, and materials design and selection guidelines are proposed to search for field-induced phase transformation in other ferromagnetic materials that undergo thermoelastic martensitic phase transformation.

Karaca, Haluk Ersin

2007-08-01T23:59:59.000Z

227

Properties of Ga{sub 1-x}Mn{sub x}As with high x (>0.1)  

SciTech Connect

We have investigated the magnetic and the crystalline properties of a set of Ga{sub 1-x}Mn{sub x}As layers with high nominal Mn compositions (x=0.101-0.198). Magnetization measurements and combined channeling Rutherford backscattering (c-RBS) and particle induced x-ray emission (c-PIXE) measurements have been performed to determine the effective Mn composition x{sub eff} and the fraction of Mn atoms at various lattice sites. Here, x{sub eff} determined from magnetization measurements, which increases with increasing x, is consistent with the results determined from c-RBS-PIXE measurements.

Chiba, D. [Semiconductor Spintronics Project, Exploratory Research for Advanced Technology, Japan Science and Technology Agency, Sendai 980-0023 (Japan); Laboratory for Nanoelectronics and Spintronics, Research Institute of Electrical Communication, Tohoku University, Katahira 2-1-1, Aoba-ku, Sendai 980-8577 (Japan); Yu, K. M.; Walukiewicz, W. [Electronic Materials Program, Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94549 (United States); Nishitani, Y. [Laboratory for Nanoelectronics and Spintronics, Research Institute of Electrical Communication, Tohoku University, Katahira 2-1-1, Aoba-ku, Sendai 980-8577 (Japan); Matsukura, F.; Ohno, H. [Laboratory for Nanoelectronics and Spintronics, Research Institute of Electrical Communication, Tohoku University, Katahira 2-1-1, Aoba-ku, Sendai 980-8577 (Japan); Semiconductor Spintronics Project, Exploratory Research for Advanced Technology, Japan Science and Technology Agency, Sendai 980-0023 (Japan)

2008-04-01T23:59:59.000Z

228

Mn-Stabilized Zirconia: From Imitation Diamonds to a New Potential High-T{sub C} Ferromagnetic Spintronics Material  

SciTech Connect

From the basis of ab initio electronic structure calculations which include the effects of thermally excited magnetic fluctuations, we predict Mn-stabilized cubic zirconia to be ferromagnetic above 500 K. We find this material, which is well known both as an imitation diamond and as a catalyst, to be half-metallic with the majority and minority spin Mn impurity states lying in zirconia's wide gap. The Mn concentration can exceed 40%. The high-T{sub C} ferromagnetism is robust to oxygen vacancy defects and to how the Mn impurities are distributed on the Zr fcc sublattice. We propose this ceramic as a promising future spintronics material.

Ostanin, S. [Max-Planck-Institut fuer Mikrostrukturphysik, Weinberg 2, D-06120 Halle (Saale) (Germany); Department of Physics, University of Warwick, Coventry CV4 7AL (United Kingdom); Ernst, A.; Sandratskii, L. M.; Bruno, P. [Max-Planck-Institut fuer Mikrostrukturphysik, Weinberg 2, D-06120 Halle (Saale) (Germany); Daene, M.; Hergert, W.; Mertig, I. [Martin-Luther-Universitaet Halle-Wittenberg, Fachbereich Physik, D-06099 Halle (Germany); Hughes, I. D.; Staunton, J. B. [Department of Physics, University of Warwick, Coventry CV4 7AL (United Kingdom); Kudrnovsky, J. [Max-Planck-Institut fuer Mikrostrukturphysik, Weinberg 2, D-06120 Halle (Saale) (Germany); Institute of Physics, Academy of Sciences of the Czech Republic, Na Slovance 2, CZ-18221 Prague 8 (Czech Republic)

2007-01-05T23:59:59.000Z

229

Flexible Zn2SnO4/MnO2 Core/Shell Nanocable-Carbon Microfiber ...  

Science Conference Proceedings (OSTI)

Presentation Title, Flexible Zn2SnO4/MnO2 Core/Shell Nanocable-Carbon Microfiber Hybrid Composites for High-Performance Supercapacitor Electrodes.

230

Magnetic order near 270 K in mineral and synthetic Mn 2 FeSbO 6 ilmenite  

Science Conference Proceedings (OSTI)

The structural and magnetic properties of Mn 2 FeSbO 6 single-crystalline mineral and ceramic samples synthesized under thermobaric treatment have been investigated

R. Mathieu; S. A. Ivanov; G. V. Bazuev; M. Hudl; P. Lazor; I. V. Solovyev; P. Nordblad

2011-01-01T23:59:59.000Z

231

Regulatory Safety Issues in the Structural Design Criteria of ASME Section III Subsection NH and for Very High Temperatures for VHTR & GEN IV  

Science Conference Proceedings (OSTI)

The objective of this task is to identify issues relevant to ASME Section III, Subsection NH [1], and related Code Cases that must be resolved for licensing purposes for VHTGRs (Very High Temperature Gas Reactor concepts such as those of PBMR, Areva, and GA); and to identify the material models, design criteria, and analysis methods that need to be added to the ASME Code to cover the unresolved safety issues. Subsection NH was originally developed to provide structural design criteria and limits for elevated-temperature design of Liquid Metal Fast Breeder Reactor (LMFBR) systems and some gas-cooled systems. The U.S. Nuclear Regulatory Commission (NRC) and its Advisory Committee for Reactor Safeguards (ACRS) reviewed the design limits and procedures in the process of reviewing the Clinch River Breeder Reactor (CRBR) for a construction permit in the late 1970s and early 1980s, and identified issues that needed resolution. In the years since then, the NRC and various contractors have evaluated the applicability of the ASME Code and Code Cases to high-temperature reactor designs such as the VHTGRs, and identified issues that need to be resolved to provide a regulatory basis for licensing. This Report describes: (1) NRC and ACRS safety concerns raised during the licensing process of CRBR , (2) how some of these issues are addressed by the current Subsection NH of the ASME Code; and (3) the material models, design criteria, and analysis methods that need to be added to the ASME Code and Code Cases to cover unresolved regulatory issues for very high temperature service.

William J. ODonnell; Donald S. Griffin

2007-05-07T23:59:59.000Z

232

Novel Solar Energy Conversion Materials by Design of Mn(II) Oxides  

Science Conference Proceedings (OSTI)

Solar energy conversion materials need to fulfill simultaneously a number of requirements in regard of their band-structure, optical properties, carrier transport, and doping. Despite their desirable chemical properties, e.g., for photo-electrocatalysis, transition-metal oxides usually do not have desirable semiconducting properties. Instead, oxides with open cation d-shells are typically Mott or charge-transfer insulators with notoriously poor transport properties, resulting from large effective electron/hole masses or from carrier self-trapping. Based on the notion that the electronic structure features (p-d interaction) supporting the p-type conductivity in d10 oxides like Cu2O and CuAlO2 occurs in a similar fashion also in the d5 (high-spin) oxides, we recently studied theoretically the band-structure and transport properties of the prototypical binary d5 oxides MnO and Fe2O3 [PRB 85, 201202(R)]. We found that MnO tends to self-trap holes by forming Mn+III, whereas Fe2O3 self-traps electrons by forming Fe+II. However, the self-trapping of holes is suppressed by when Mn is tetrahedrally coordinated, which suggests specific routes to design novel solar conversion materials by considering ternary Mn(II) oxides or oxide alloys. We are presenting theory, synthesis, and initial characterization for these novel energy materials.

Lany, S.; Peng, H.; Ndione, P.; Zakutayev, A.; Ginley, D. S.

2013-01-01T23:59:59.000Z

233

High-Resolution Structure of the Photosynthetic Mn4Ca Catalyst from X-ray Spectroscopy  

Science Conference Proceedings (OSTI)

The application of high-resolution X-ray spectroscopy methods to study the photosynthetic water oxidizing complex, which contains a unique hetero-nuclear catalytic Mn4Ca cluster, are described. Issues of X-ray damage especially at the metal sites in the Mn4Ca cluster are discussed. The structure of the Mn4Ca catalyst at high-resolution which has so far eluded attempts of determination by X-ray diffraction, EXAFS and other spectroscopic techniques has been addressed using polarized EXAFS techniques applied to oriented PS II membrane preparations and PS II single crystals. A review of how the resolution of traditional EXAFS techniques can be improved, using methods such as range-extended EXAFS is presented, and the changes that occur in the structure of the cluster as it advances through the catalytic cycle are described. X-ray absorption and emission techniques (XANES and K? emission) have been used earlier to determine the oxidation states of the Mn4Ca cluster, and in this report we review the use of X-ray resonant Raman spectroscopy to understand the electronic structure of the Mn4Ca cluster as it cycles through the intermediate S-states.

Yachandra, Vittal; Yano, Junko; Kern, Jan; Pushkar, Yulia; Sauer, Kenneth; Glatzel, Pieter; Bergmann, Uwe; Messinger, Johannes; Zouni, Athina; Yachandra, Vittal K.

2007-08-01T23:59:59.000Z

234

Carbon/lambda-MnO{sub 2} composites for supercapacitor electrodes  

Science Conference Proceedings (OSTI)

In the present work a composite of carbon with lambda-MnO{sub 2} have been synthesized by a simple two-step route. In the first step, to obtain LiMn{sub 2}O{sub 4}/carbon material, mesoporous activated carbon was impregnated with the solution of precursor metal salts and heated subsequently. As-prepared materials were acid treated which resulted in the formation of lambda-MnO{sub 2}/carbon. Physical properties, structure and specific surface area of electrode materials were studied by TEM, X-ray diffraction and nitrogen sorption measurements. Voltammetry cycling, galvanostatic charge/discharge and impedance spectroscopy measurements performed in two- and three-electrode cells have been applied in order to measure electrochemical parameters. TEM images confirmed well dispersed lambda-MnO{sub 2} particles on the surface of carbon material. The carbon in the composite plays an important role as the surface area enhancing component and a support of pseudocapacitive material. Furthermore, the through-connected porosity serves as a continuous pathway for electrolyte transport. A synergetic effect of the porous carbon framework and of the redox properties of the lambda-MnO{sub 2} is at the origin of improvement of specific capacitance values which has been observed for composites after delithiation. - Comparison of capacitance characteristics for initial carbon and synthesised composites for CB in 1 mol L{sup -1} Na{sub 2}SO{sub 4} solution.

Malak-Polaczyk, A., E-mail: agnieszka-malak@wp.p [Institute of Chemistry and Technical Electrochemistry, Poznan University of Technology, Piotrowo 3, 60-695 Poznan (Poland); Institut de Sciences des Materiaux de Mulhouse, CNRS LRC 7228, 15 Rue Starcky, 68057 Mulhouse (France); Matei-Ghimbeu, C.; Vix-Guterl, C. [Institut de Sciences des Materiaux de Mulhouse, CNRS LRC 7228, 15 Rue Starcky, 68057 Mulhouse (France); Frackowiak, E. [Institute of Chemistry and Technical Electrochemistry, Poznan University of Technology, Piotrowo 3, 60-695 Poznan (Poland)

2010-04-15T23:59:59.000Z

235

Investigation of Modified Ni-Cr-Mn Base Alloys for SOFC Interconnect Applications  

Science Conference Proceedings (OSTI)

Two Ni-Cr-W-Mn base alloys based on Haynes 230 were developed and evaluated against criteria relevant to SOFC interconnect applications, which included oxidation behavior under SOFC operating conditions, scale electrical conductivity, and thermal expansion. It was found that, similar to the ferritic stainless steel Crofer22 APU, additions of Mn led to the formation of a unique scale that was comprised of a M3O4 (M=Mn, Cr, Ni, ) spinel-rich top layer and Cr2O3-rich sub-layer. The modified alloys demonstrated reasonable oxidation resistance under SOFC operating conditions, though the Mn additions increased the scale growth rate and thus sacrificed to some extent the oxidation resistance of the base alloy (Haynes 230). The formation of a spinel-rich top layer improved the scale conductivity, especially during the early stages of oxidation, but the higher scale growth rate resulted in a higher rate of increase in the area-specific electrical resistance. Due to their FCC crystal structure, the Ni-Cr-W-Mn base alloys demonstrated a CTE that was higher than that of anode-supported cells and candidate ferritic stainless steels such as Crofer22 APU.

Yang, Z Gary; Singh, Prabhakar; Stevenson, Jeffry W.; Xia, Gordon

2006-09-01T23:59:59.000Z

236

Effects of gaseous NH{sub 3} and SO{sub 2} on the concentration profiles of PCDD/F in flyash under post-combustion zone conditions  

Science Conference Proceedings (OSTI)

Highlights: Black-Right-Pointing-Pointer Influence of NH{sub 3} and SO{sub 2} on 2378-PCDD/F in flyash and flue gases was investigated. Black-Right-Pointing-Pointer NH{sub 3} decreased the concentration of PCDD and PCDF by 34-75% in the flyash. Black-Right-Pointing-Pointer NH{sub 3} decreased the concentration of PCDD and PCDF by 21-40% from the flue gases. Black-Right-Pointing-Pointer SO{sub 2} led to 99% PCDD and 93% PCDF reductions in the flyash. Black-Right-Pointing-Pointer SO{sub 2} led to 89% PCDD and 76% PCDF reductions in the flue gases. - Abstract: The influence of gaseous ammonia and sulphur dioxide on the formation of 2378-substituted PCDD/F on a reference flyash from a municipal waste incinerator has been investigated using a laboratory scale fixed-bed reactor. The reference flyash samples (BCR-490) was reacted under a simulated flue gas stream at temperatures of 225 and 375 Degree-Sign C for 96 h. The experiments were carried out in two series: first with simulated flue gas alone, and then with injection of NH{sub 3} or SO{sub 2} gas into the flue gas just before the reactor inlet. It was found that the injection of gaseous ammonia into the flue gas could decrease the concentration of both PCDD and PCDF by 34-75% from the solid phase and by 21-40% from the gas phase. Converting the results to I-TEQ values, it could reduce the total I-TEQ values of PCDD and PCDF in the sum of the flyash and exhaust flue gas by 42-75% and 24-57% respectively. The application of SO{sub 2} led to 99% and 93% reductions in the PCDD and PCDF average congener concentrations, respectively in the solid phase. In the gas phase, the total reductions were 89% and 76% for PCDD and PCDF, respectively. Moreover, addition of SO{sub 2} reduced the total I-TEQ value of PCDD and PCDF in the flyash and exhaust flue gas together by 60-86% and 72-82% respectively. Sulphur dioxide was more effective than ammonia in suppressing PCDD/F formation in flyash under the conditions investigated.

Hajizadeh, Yaghoub; Onwudili, Jude A. [Energy Research Institute, University of Leeds, Leeds LS2 9JT (United Kingdom); Williams, Paul T., E-mail: p.t.williams@leeds.ac.uk [Energy Research Institute, University of Leeds, Leeds LS2 9JT (United Kingdom)

2012-07-15T23:59:59.000Z

237

Decomposition of NH3BH3 at sub-ambient pressures: A combined thermogravimetry-differential thermal analysis-mass spectrometry study  

DOE Green Energy (OSTI)

We report a systematic study of the isothermal decomposition of ammonia borane, NH3BH3, at 363 K as a function of argon pressure ranging between 50 and 1040 mbar using thermogravimetry and differential thermal analysis coupled with mass analysis of the volatile species. During thermal aging at 363 K, evolution of hydrogen, aminoborane and borazine is monitored, with the relative mass loss strongly depending on the pressure in the reaction chamber. Furthermore, the induction period required for hydrogen release at 363 K decreases with decreasing pressure.

Palumbo, Oriele; Paolone, Annalisa; Rispoli, Pasquale; Cantelli, Rosario; Autrey, Thomas

2010-03-15T23:59:59.000Z

238

Xcel Energy - Solar*Rewards Program and MN Made PV Rebate Program |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Xcel Energy - Solar*Rewards Program and MN Made PV Rebate Program Xcel Energy - Solar*Rewards Program and MN Made PV Rebate Program Xcel Energy - Solar*Rewards Program and MN Made PV Rebate Program < Back Eligibility Commercial Local Government Nonprofit Residential Savings Category Solar Buying & Making Electricity Maximum Rebate $90,000 (as determined by the incentive level and maximum system size) Program Info Start Date 03/01/2010 State Minnesota Program Type Utility Rebate Program Rebate Amount REC Rebate Program 2010-2012:$2.25/W DC REC Rebate Program 2013:$1.50/W DC Minnesota Made Bonus 2010-2012:Up to an additional $2.75/W DC (paired with REC Rebate) Provider Xcel Energy '''''Note: All 2012 funding for the Solar*Rewards program and Minnesota Made Bonus has been reserved as of July 11, 2012. On October 1, 2012, the

239

Magnetism, chemical spots, and stratification in the HgMn star phi Phoenicis  

E-Print Network (OSTI)

Mercury-manganese (HgMn) stars have been considered as non-magnetic and non-variable chemically peculiar (CP) stars for a long time. However, recent discoveries of the variability in spectral line profiles suggested an inhomogeneous surface distribution of chemical elements in some HgMn stars. From the studies of other CP stars it is known that magnetic field plays a key role in the formation of surface spots. All attempts to find magnetic fields in HgMn stars yielded negative results. In this study, we investigate a possible presence of the magnetic field in phi Phe (HD 11753) and reconstruct surface distribution of chemical elements that show variability in spectral lines. We also test a hypothesis that magnetic field is concentrated in chemical spots and look into the possibility that some chemical elements are stratified with depth in the stellar atmosphere.

Makaganiuk, V; Piskunov, N; Jeffers, S V; Johns-Krull, C M; Keller, C U; Rodenhuis, M; Snik, F; Stempels, H C; Valenti, J A

2011-01-01T23:59:59.000Z

240

In-situ spectro-microscopy on organic films: Mn-Phthalocyanine on Ag(100)  

SciTech Connect

Metal phthalocyanines are attracting significant attention, owing to their potential for applications in chemical sensors, solar cells and organic magnets. As the electronic properties of molecular films are determined by their crystallinity and molecular packing, the optimization of film quality is important for improving the performance of organic devices. Here, we present the results of in situ low-energy electron microscopy / photoemission electron microscopy (LEEM/PEEM) studies of incorporation-limited growth [1] of manganese-phthalocyanine (MnPc) on Ag(100) surfaces. MnPc thin films were grown on both, bulk Ag(100) surface and thin Ag(100)/Fe(100) films, where substrate spin-polarized electronic states can be modified through tuning the thickness of the Ag film [2]. We also discuss the electronic structure and magnetic ordering in MnPc thin films, investigated by angle- and spin-resolved photoemission spectroscopy.

Al-Mahboob A.; Vescovo, E.; Sadowski, J.T.

2013-08-18T23:59:59.000Z

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241

Growth and Magnetic Properties of Mn-doped Germanium near the Kinetic Solubility Limit  

Science Conference Proceedings (OSTI)

Growth of high-quality dilute magnetic semiconductor (DMS) material is often compromised by the low solubility of magnetic dopants, leading to formation of precipitates. Here, we explore the feasibility of growing precipitate-free Mn-doped Ge at doping levels near the kinetic solubility limit. Ge:Mn DMS films were grown at low temperature so as to minimize precipitate formation. Meanwhile, epitaxial quality was maintained by employing a very low growth rate. The magnetic properties of these lightly doped films exhibit both interesting contrasts and similarities with those of heavily-doped DMS reported in the literature, indicating that the substitutional Mn contents are very similar. Films grown at 95 degree C are free of intermetallic precipitates, offering useful opportunities for studying the fundamentals of carrier mediated exchange and metal insulator transitions without complications arising from precipitate formation.

Ozer, Mustafa M [University of Tennessee, Knoxville (UTK); Thompson, James R [ORNL; Weitering, Harm H [ORNL

2012-01-01T23:59:59.000Z

242

Figure 23. Average price of natural gas delivered to U.S. commercial...  

Annual Energy Outlook 2012 (EIA)

Natural and Supplemental Gas Supply and Disposition," and Form EIA-910, "Monthly Natural Gas Marketer Survey." IN OH TN WV VA KY MD PA NY VT NH MA CT ME RI DE DC NC SC GA FL NJ AL...

243

Microsoft Word - figure_22.doc  

Gasoline and Diesel Fuel Update (EIA)

Natural and Supplemental Gas Supply and Disposition," and Form EIA-910, "Monthly Natural Gas Marketer Survey." IN OH TN WV VA KY MD PA NY VT NH MA CT ME RI DE DC NC SC GA FL NJ AL...

244

Quantum wells on 3C-SiC/NH-SiC heterojunctions. Calculation of spontaneous polarization and electric field strength in experiments  

SciTech Connect

The results of experiments with quantum wells on 3C-SiC/4H-SiC and 3C-SiC/6H-SiC heterojunctions obtained by various methods are reconsidered. Spontaneous polarizations, field strengths, and energies of local levels in quantum wells on 3C-SiC/NH-SiC heterojunctions were calculated within a unified model. The values obtained are in agreement with the results of all considered experiments. Heterojunction types are determined. Approximations for valence band offsets on heterojunctions between silicon carbide polytypes and the expression for calculating local levels in quantum wells on the 3C-SiC/NH-SiC heterojunction are presented. The spontaneous polarizations and field strengths induced by spontaneous polarization on 3C-SiC/4H-SiC and 3C-SiC/6H-SiC heterojunctions were calculated as 0.71 and 0.47 C/m{sup 2} and 0.825 and 0.55 MV/cm, respectively.

Sbruev, I. S.; Sbruev, S. B., E-mail: science@yandex.ru [Moscow Aviation Institute (Russian Federation)

2010-10-15T23:59:59.000Z

245

HfO2 Gate Dielectric on (NH4)2S Passivated (100) GaAs Grown by Atomic Layer Deposition  

Science Conference Proceedings (OSTI)

The interface between hafnium oxide grown by atomic layer deposition and (100) GaAs treated with HCl cleaning and (NH{sub 4}){sub 2}S passivation has been characterized. Synchrotron radiation photoemission core level spectra indicated successful removal of the native oxides and formation of passivating sulfides on the GaAs surface. Layer-by-layer removal of the hafnia film revealed a small amount of As{sub 2}O{sub 3} formed at the interface during the dielectric deposition. Traces of arsenic and sulfur out-diffusion into the hafnia film were observed after a 450 C post-deposition anneal, and may be the origins for the electrically active defects. Transmission electron microscopy cross section images showed thicker HfO{sub 2} films for a given precursor exposure on S-treated GaAs versus the non-treated sample. In addition, the valence-band and the conduction-band offsets at the HfO{sub 2}/GaAs interface were deduced to be 3.18 eV and a range of 0.87-0.97 eV, respectively. It appears that HCl+(NH{sub 4})2{sub S} treatments provide a superior chemical passivation for GaAs and initial surface for ALD deposition.

Chen, P.T.; /Stanford U., Materials Sci. Dept.; Sun, Y.; /SLAC, SSRL; Kim, E.; McIntyre, P.C.; /Stanford U., Materials Sci. Dept.; Tsai, W.; Garner, M.; /Intel, Santa Clara; Pianetta, P.; /SLAC, SSRL; Nishi, Y.; /Stanford U., Elect. Eng. Dept.; Chui, C.O.; /UCLA

2007-09-28T23:59:59.000Z

246

AFFECTS OF MECHANICAL MILLING AND METAL OXIDE ADDITIVES ON SORPTION KINETICS OF 1:1 LiNH2/MgH2 MIXTURE  

DOE Green Energy (OSTI)

The destabilized complex hydride system composed of LiNH{sub 2}:MgH{sub 2} (1:1 molar ratio) is one of the leading candidates of hydrogen storage with a reversible hydrogen storage capacity of 8.1 wt%. A low sorption enthalpy of {approx}32 kJ/mole H{sub 2} was first predicted by Alapati et al. utilizing first principle density function theory (DFT) calculations and has been subsequently confirmed empirically by Lu et al. through differential thermal analysis (DTA). This enthalpy suggests that favorable sorption kinetics should be obtainable at temperatures in the range of 160 C to 200 C. Preliminary experiments reported in the literature indicate that sorption kinetics are substantially lower than expected in this temperature range despite favorable thermodynamics. Systematic isothermal and isobaric sorption experiments were performed using a Sievert's apparatus to form a baseline data set by which to compare kinetic results over the pressure and temperature range anticipated for use of this material as a hydrogen storage media. Various material preparation methods and compositional modifications were performed in attempts to increase the kinetics while lowering the sorption temperatures. This paper outlines the results of these systematic tests and describes a number of beneficial additions which influence kinetics as well as NH{sub 3} formation.

Erdy, C.; Anton, D.; Gray, J.

2010-12-08T23:59:59.000Z

247

Neutron and X-ray diffraction studies on the high temperature phase of Mn{sub 3}(VO{sub 4}){sub 2}, the new isostructural compound NaMn{sub 4}(VO{sub 4}){sub 3} and their mixed crystals Na{sub x}Mn{sub 4.5-x/2}(VO{sub 4}){sub 3} (0{<=}x{<=}1)  

SciTech Connect

This paper presents a detailed structure analysis (combined Rietveld analysis of X-ray and neutron powder diffraction data as well as quantum mechanical calculations) of the high temperature phase of Mn{sub 3}(VO{sub 4}){sub 2} (space group I4 Macron 2d). Special attention is directed to the analysis of the local coordination around Mn{sup 2+} ions or vacancies within a stella quadrangula configuration of anions. Furthermore, the new compound NaMn{sub 4}(VO{sub 4}){sub 3} is described as well as a range of mixed crystals between NaMn{sub 4}(VO{sub 4}){sub 3} and Mn{sub 3}(VO{sub 4}){sub 2} (described by the formula Na{sub x}Mn{sub 4.5-x/2}(VO{sub 4}){sub 3}, 0{<=}x{<=}1) which were synthesized by a solid state route. All compounds were shown to be isostructural to the high temperature phase Mn{sub 3}(VO{sub 4}){sub 2}. - Graphical abstract: The crystal structure of the new compound NaMn{sub 4}(VO{sub 4}){sub 3}. Highlights: Black-Right-Pointing-Pointer We present neutron and X-ray diffraction studies on high temperature-Mn{sub 3}(VO{sub 4}){sub 2}. Black-Right-Pointing-Pointer Structural details of partly filled stellae quadrangulae positions are discussed. Black-Right-Pointing-Pointer Refined structural parameters and theoretical calculations are compared. Black-Right-Pointing-Pointer We investigate the mixed crystal system Mn{sub 3}(VO{sub 4}){sub 2}-NaMn{sub 4}(VO{sub 4}){sub 3}.

Clemens, Oliver [Universitaet des Saarlandes, Institut fuer Anorganische und Analytische Chemie und Radiochemie, Am Markt, Zeile 5, 66125 Saarbruecken (Germany)] [Universitaet des Saarlandes, Institut fuer Anorganische und Analytische Chemie und Radiochemie, Am Markt, Zeile 5, 66125 Saarbruecken (Germany); Haberkorn, Robert [Universitaet des Saarlandes, Anorganische Festkoerperchemie, Am Markt, Zeile 3, 66125 Saarbruecken (Germany)] [Universitaet des Saarlandes, Anorganische Festkoerperchemie, Am Markt, Zeile 3, 66125 Saarbruecken (Germany); Springborg, Michael [Universitaet des Saarlandes, Physikalische und Theoretische Chemie, Campus B2 2, 66123 Saarbruecken (Germany)] [Universitaet des Saarlandes, Physikalische und Theoretische Chemie, Campus B2 2, 66123 Saarbruecken (Germany); Beck, Horst Philipp, E-mail: hp.beck@mx.uni-saarland.de [Universitaet des Saarlandes, Institut fuer Anorganische und Analytische Chemie und Radiochemie, Am Markt, Zeile 5, 66125 Saarbruecken (Germany)

2012-10-15T23:59:59.000Z

248

Stoichiometric growth of high Curie temperature heavily alloyed GaMnAs  

SciTech Connect

Heavily alloyed, 100 nm Ga{sub 1-x}Mn{sub x}As (x>0.1) films are obtained via low-temperature molecular beam epitaxy by utilizing a combinatorial technique which allows systematic control of excess arsenic during growth. Reproducible electronic, magnetic, and structural properties are optimized in a narrow range of stoichiometric growth conditions. In contrast to a prediction of the Zener model of hole-mediated ferromagnetism, the Curie temperature of the stoichiometric material is independent of x (for x>0.1), while substitutional Mn content is proportional to x within a large window of growth conditions.

Mack, S.; Myers, R. C.; Heron, J. T.; Gossard, A. C.; Awschalom, D. D. [Center for Spintronics and Quantum Computation, University of California, Santa Barbara, California 93106 (United States)

2008-05-12T23:59:59.000Z

249

Ultrafast Enhancement of Ferromagnetism via Photoexcited Holes inGaMnAs  

SciTech Connect

We report on the observation of ultrafast photo-enhanced ferromagnetism in GaMnAs. It is manifested as a transient magnetization increase on a 100-ps time scale, after an initial sub-ps demagnetization. The dynamic magnetization enhancement exhibits a maximum below the Curie temperature {Tc} and dominates the demagnetization component when approaching {Tc}. We attribute the observed ultrafast collective ordering to the p-d exchange interaction between photoexcited holes and Mn spins, leading to a correlation-induced peak around 20K and a transient increase in {Tc}.

Wang, J.; Cotoros, I.; Dani, K.M.; Liu, X.; Furdyna, J.K.; Chemla, D.S.

2007-02-17T23:59:59.000Z

250

Relaxation of photoinduced spins and carriers in ferromagnetic InMnSb films  

SciTech Connect

The authors report time resolved measurements and control of photoinduced spin and carrier relaxations in InMnSb ferromagnetic films with 2% Mn content (grown by low-temperature molecular beam epitaxy) using femtosecond laser pulses, and compare them to analogous measurements on InBeSb and InSb films. In this work, magneto-optical Kerr effect and standard pump-probe techniques provided a direct measure of the photoexcited spin and carrier lifetimes, respectively. They observe decrease in relaxations times in the high laser fluence regime and an absence of temperature dependence of the relaxation times.

Nontapot, K.; Kini, R. N.; Gifford, A.; Merritt, T. R.; Khodaparast, G. A.; Wojtowicz, T.; Liu, X.; Furdyna, J. K. [Department of Physics, Virginia Tech, Blacksburg, Virginia 24061 (United States); Institute of Physics, Polish Academy of Sciences, 02-668 Warsaw (Poland); Department of Physics, University of Notre Dame, Notre Dame, Indiana 46556 (United States)

2007-04-02T23:59:59.000Z

251

Fabrication of (Mn,Co)3O4 Surface Coatings onto Alloy Substrates  

DOE Green Energy (OSTI)

Ferritic stainless steels are promising candidates for IT-SOFC interconnect applications due to their low cost and resistance to oxidation at SOFC operating temperatures. However, several challenges remain, including long term electrical conductivity and surface stability under interconnect exposure conditions and chromia scale evaporation. One means of extending interconnect lifetime and improving performance is to apply a protective coating, such as (Mn,Co)3O4 spinel, to the cathode side of the interconnect. These coatings have proven effective in reducing scale growth kinetics and Cr volatility. This report describes several procedures developed at PNNL for fabricating (Mn,Co)3O4 spinel coatings onto ferritic stainless steels.

Yang, Zhenguo; Xia, Guanguang; Li, Xiaohong S.; Singh, Prabhakar; Stevenson, Jeffry W.

2007-04-30T23:59:59.000Z

252

Multisegmented Au-MnO2/Carbon Nanotube Hybrid Coaxial Arrays for High-Power Supercapacitor Applications  

E-Print Network (OSTI)

Multisegmented Au-MnO2/Carbon Nanotube Hybrid Coaxial Arrays for High-Power SupercapacitorVised Manuscript ReceiVed: NoVember 4, 2009 The present work reports on synthesis and supercapacitor applications hybrid coaxial arrays are efficient electrodes for supercapacitor applications. Au-segmented MnO2/CNT

Ajayan, Pulickel M.

253

Growth of single-crystal {alpha}-MnO{sub 2} nanorods on multi-walled carbon nanotubes  

Science Conference Proceedings (OSTI)

Single-crystal {alpha}-MnO{sub 2} nanorods were grown on multi-walled carbon nanotubes (MWNTs) in H{sub 2}SO{sub 4} aqueous solution. The morphology and microstructure of the composites were examined by transmission electron microscopy, high-resolution transmission electron microscopy (HRTEM), X-ray diffractometry and energy dispersive spectroscopy (EDS). The results show that {alpha}-MnO{sub 2} single-crystal nanorods with a mean diameter of 15 nm were densely grown on the surface of MWNTs. Those MWNTs/MnO{sub 2} composites were used as an electrode material for supercapacitors, and it was found that the supercapacitor performance using MWNTs/MnO{sub 2} composites was improved largely compared to that using pure MWNTs and {alpha}-MnO{sub 2} nanorod mechanically mixed with MWNTs.

Chen Yong [Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016 (China); Key Laboratory of Tropic Biological Resources, MOE, Hainan University, 58 Renmin Road, Haikou 570228 (China); Liu Chenguang; Liu Chang [Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016 (China); Lu Gaoqing [ARC Centre for Functional Nanomaterials, Australian Institute of Bioengineering and Nanotechnology, University of Queensland, QLD 4072 (Australia); Cheng Huiming [Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016 (China)], E-mail: cheng@imr.ac.cn

2007-11-06T23:59:59.000Z

254

Wind Program: Stakeholder Engagement and Outreach  

Wind Powering America (EERE)

Outreach Outreach Printable Version Bookmark and Share The Stakeholder Engagement and Outreach initiative of the U.S. Department of Energy's Wind Program is designed to educate, engage, and enable critical stakeholders to make informed decisions about how wind energy contributes to the U.S. electricity supply. Highlights Resources Wind Resource Maps State Activities What activities are happening in my state? AK AL AR AZ CA CO CT DC DE FL GA HI IA ID IL IN KS KY LA MA MD ME MI MN MO MS MT NC ND NE NH NJ NM NV NY OH OK OR PA RI SC SD TN TX UT VA VT WA WI WV WY Installed wind capacity maps. Features A image of a house with a residential-scale small wind turbine. Small Wind for Homeowners, Farmers, and Businesses Stakeholder Engagement & Outreach Projects

255

Annual Energy Outlook 2012  

Gasoline and Diesel Fuel Update (EIA)

2 2 Source: U.S. Energy Information Administration, Office of Energy Analysis. U.S. Energy Information Administration / Annual Energy Outlook 2010 213 Appendix F Regional Maps Figure F1. United States Census Divisions Pacific East South Central South Atlantic Middle Atlantic New England West South Central West North Central East North Central Mountain AK WA MT WY ID NV UT CO AZ NM TX OK IA KS MO IL IN KY TN MS AL FL GA SC NC WV PA NJ MD DE NY CT VT ME RI MA NH VA WI MI OH NE SD MN ND AR LA OR CA HI Middle Atlantic New England East North Central West North Central Pacific West South Central East South Central South Atlantic Mountain Source: U.S. Energy Information Administration, Office of Integrated Analysis and Forecasting. Appendix F Regional Maps Figure F1. United States Census Divisions U.S. Energy Information Administration | Annual Energy Outlook 2012

256

Assumptions to the Annual Energy Outlook 2007 Report  

Gasoline and Diesel Fuel Update (EIA)

clothes drying, ceiling fans, coffee makers, spas, home security clothes drying, ceiling fans, coffee makers, spas, home security systems, microwave ovens, set-top boxes, home audio equipment, rechargeable electronics, and VCR/DVDs. In addition to the major equipment-driven end-uses, the average energy consumption per household is projected for other electric and nonelectric appliances. The module's output includes number Energy Information Administration/Assumptions to the Annual Energy Outlook 2007 19 Pacific East South Central South Atlantic Middle Atlantic New England West South Central West North Central East North Central Mountain AK WA MT WY ID NV UT CO AZ NM TX OK IA KS MO IL IN KY TN MS AL FL GA SC NC WV PA NJ MD DE NY CT VT ME RI MA NH VA WI MI OH NE SD MN ND AR LA OR CA HI Middle Atlantic New England East North Central West North Central Pacific West South Central East South Central

257

Microsoft Word - figure_13.doc  

Gasoline and Diesel Fuel Update (EIA)

Egypt Figure 13. Net Interstate Movements, Imports, and Exports of Natural Gas in the United States, 2007 (Million Cubic Feet) Nigeria Algeria 37,483 WA M T I D OR W Y ND SD C A N V UT CO NE KS AZ NM OK TX MN WI MI IA I L IN OH MO AR MS AL GA TN KY FL SC NC WV MD DE VA PA NJ NY CT RI MA VT NH ME LA HI AK Mexico C a n a d a C a n a d a Canada Canada Canada Canada Canada Algeria Canada Canada i i N g e r a Gulf of Mexico Gulf o f M e x i c o Gulf of Mexico Canada Gulf of Mexico Sources: Energy Information Administration (EIA), Form EIA-176, "Annual Report of Natural and Supplemental Gas Supply and Disposition," and the Office of Fossil Energy, Natural Gas Imports and Exports.

258

U.S. Energy Information Administration | Annual Energy Outlook 2011  

Gasoline and Diesel Fuel Update (EIA)

1 1 Regional maps Figure F6. Coal supply regions Figure F6. Coal Supply Regions WA ID OR CA NV UT TX OK AR MO LA MS AL GA FL TN SC NC KY VA WV WY CO SD ND MI MN WI IL IN OH MD PA NJ DE CT MA NH VT NY ME RI MT NE IA KS MI AZ NM 500 0 SCALE IN MILES APPALACHIA Northern Appalachia Central Appalachia Southern Appalachia INTERIOR NORTHERN GREAT PLAINS Eastern Interior Western Interior Gulf Lignite Dakota Lignite Western Montana Wyoming, Northern Powder River Basin Wyoming, Southern Powder River Basin Western Wyoming OTHER WEST Rocky Mountain Southwest Northwest KY AK 1000 0 SCALE IN MILES Source: U.S. Energy Information Administration, Office

259

Major DOE Biofuels Project Locations  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Biofuels Biofuels Project Locations Pacific Ethanol (Boardman, OR) BlueFire Ethanol (Corona, CA) POET (Emmetsburg, IA) Lignol Innovations (Commerce City, CO) ICM (St. Joseph, MO) Abengoa (Hugoton, KS) DOE Joint Bioenergy Institute (Berkeley, CA) DOE Great Lakes Bioenergy Research Center (Madison, WI) DOE Bioenergy Science Center (Oak Ridge, TN) NewPage (Wisconsin Rapids, WI) Range Fuels (Soperton, GA) DSM Innovation Center (Parsippany, NJ) Novozymes (Davis, CA) Genencor (Palo Alto, CA) Verenium Corp (San Diego, CA) Dupont (Wilmington, DE) Mascoma (Lebanon, NH) Cargill Inc (Minneapolis, MN) Regional Partnerships South Dakota State University, Brookings, SD Cornell University, Ithaca, NY University of Tennessee, Knoxville, TN Oklahoma State University, Stillwater, OK Oregon State University, Corvallis, OR

260

High-throughput and in situ EDXRD investigation on the formation of two new metal aminoethylphosphonates - Ca(O{sub 3}PC{sub 2}H{sub 4}NH{sub 2}) and Ca(OH)(O{sub 3}PC{sub 2}H{sub 4}NH{sub 3}){center_dot}2H{sub 2}O  

SciTech Connect

The system Ca{sup 2+}/2-aminoethylphosphonic acid/H{sub 2}O/NaOH was systematically investigated using high-throughput methods. The experiments led to one new compound Ca(O{sub 3}PC{sub 2} H{sub 4}NH{sub 2}) (1) and the crystal structure was determined using in house X-ray powder diffraction data (monoclinic, P2{sub 1}/c, a=9.7753(3), b=6.4931(2), c=8.4473(2) A, {beta}=106.46(2) Degree-Sign , V=514.20(2) A{sup 3}, Z=4). The formation of 1 was investigated by in situ energy dispersive X-ray diffraction measurements (EDXRD) at beamline F3 at HASYLAB (light source DORIS III), DESY, Hamburg. An intermediate, Ca(OH)(O{sub 3}PC{sub 2}H{sub 4}NH{sub 3}){center_dot}2H{sub 2}O (2), was observed and could be isolated from the reaction mixture at ambient temperatures by quenching the reaction. The crystal structure of 2 was determined from XRPD data using synchrotron radiation (monoclinic, P2{sub 1}/m, a=11.2193(7), b=7.1488(3), c=5.0635(2) A, {beta}=100.13(4) Degree-Sign , V=399.78(3) A{sup 3}, Z=2). - Graphical abstarct: The detailed in situ energy dispersive X-ray diffraction (EDXRD) investigation on the formation of the new inorganic-organic hybrid compound Ca(O{sub 3}PC{sub 2}H{sub 4}NH{sub 2}) leads to the discovery of a new crystalline intermediate phase. Both crystal structures were elucidated using X-ray powder diffraction data. Highlights: Black-Right-Pointing-Pointer High-throughput investigation led to new metal aminoethylphosphonate Ca(O{sub 3}PC{sub 2}H{sub 4}NH{sub 2}). Black-Right-Pointing-Pointer The formation of Ca(O{sub 3}PC{sub 2}H{sub 4}NH{sub 2}) was followed by in situ EDXRD measurements. Black-Right-Pointing-Pointer The crystalline intermediate Ca(O{sub 3}PC{sub 2}H{sub 4}NH{sub 3})(OH){center_dot}2H{sub 2}O was discovered. Black-Right-Pointing-Pointer Isolation of Ca(O{sub 3}PC{sub 2}H{sub 4}NH{sub 3})(OH){center_dot}2H{sub 2}O was accomplished by quenching experiments. Black-Right-Pointing-Pointer The structures were determined using X-ray powder diffraction data.

Schmidt, Corinna; Feyand, Mark [Institut fuer Anorganische Chemie, Christian-Albrechts-Universitaet, Max-Eyth Strasse 2, D 24118 Kiel (Germany); Rothkirch, Andre [HASYLAB, DESY Hamburg, Notkestrasse 85, 22607 Hamburg (Germany); Stock, Norbert, E-mail: stock@ac.uni-kiel.de [Institut fuer Anorganische Chemie, Christian-Albrechts-Universitaet, Max-Eyth Strasse 2, D 24118 Kiel (Germany)

2012-04-15T23:59:59.000Z

Note: This page contains sample records for the topic "mn nh nj" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Effect of solution hardening on the shape memory effect of Fe-Mn based alloys  

SciTech Connect

Fe-high Mn-Si alloys, which undergo {gamma} (fcc) to {var_epsilon} (hcp) martensitic transformation, exhibit a pronounced shape memory effect. The origin of shape memory effect of these alloys is the reversion of stress-induced {var_epsilon} martensite. A shape change must hence be accomplish3ed by stress-induced martensitic transformation without permanent slip in austenite ({gamma}) in order to obtain a good shape memory effect. It is clear that the intrusion of permanent slip can be suppressed by increasing the strength of austenite and by decreasing the applied stress required for a shape change due to stress-induced martensitic transformation. It has been reported that the addition of the interstitial elements of C and N as well as the substitutional elements of Mo and V increases the 0.2% proof stress of austenite in Fe-high Mn alloys. However, there have been few studies on the effect of these alloying elements on the shape memory effect of Fe-high Mn based alloys. In the present study, it was aimed to improve the shape memory effect of Fe-high Mn based alloys by the strengthening of austenite through solution hardening due to C and Mo.

Tsuzaki, K.; Natsume, Y.; Maki, T. [Kyoto Univ. (Japan). Dept. of Materials Science and Engineering; Tomota, Y. [Ibaraki Univ., Hitachi (Japan)

1995-10-01T23:59:59.000Z

262

Magnetic characterizations of sol-gel-produced mn-doped ZnO  

Science Conference Proceedings (OSTI)

Nanoparticles of ZnO doped with 6 at.% Mn were produced by a sol-gel method. X-ray diffraction confirms the hexagonal structure as that of the parent compound ZnO, and high-resolution electron transmission microscopy reveals a single-crystallite lattice. ...

R. Asmatulu; H. Haynes; M. Shinde; Y. H. Lin; Y. Y. Chen; J. C. Ho

2010-01-01T23:59:59.000Z

263

Cycling performance of nanocrystalline LiMn2O4 thin films via electrophoresis  

Science Conference Proceedings (OSTI)

The present study demonstrates a novel approach by which titanium foils coated with LiMn2O4 nanocrystals can be processed into a high-surface-area electrode for rechargeable batteries. A detailed study has been performed to elucidate ...

S. Parvathy; R. Ranjusha; K. Sujith; K. R. V. Subramanian; N. Sivakumar; Shantikumar V. Nair; Avinash Balakrishnan

2012-01-01T23:59:59.000Z

264

ON THE COMPETITION BETWEEN FERROMAGNETIC AND ANTIFERROMAGNETIC STATES IN Sr2MnMoO6  

E-Print Network (OSTI)

It is argued that the magnetic behavior of Sr2MnMoO6 is determined by the existence of two total energy minima corresponding to the metallic ferromagnetic and insulating antiferromagnetic states, which may be nearly degenerate depending on the magnitude of the breathing distortion. PACS: 71.20.Be; 71.70.Gm; 72.25.Ba; 75.30.Et

I. V. Solovyev

2002-01-01T23:59:59.000Z

265

Electrodeposition of Mn-Co Alloys on Stainless Steels for SOFC Interconnect Application  

Science Conference Proceedings (OSTI)

Chromium-containing ferritic stainless steels are the most popular materials for solid oxide fuel cell (SOFC) interconnect applications because of its oxidation resistance and easy fabrication process. However, excessive scale growth and chromium evaporation will degrade the cell performance. Highly conductive coatings that resist oxide scale growth and chromium evaporation may prevent both of these problems. Mn1.5Co1.5O4 spinel is one of the most promising coatings for interconnect application because of its high conducitivy, good chromium retention capability, as well as good CTE match. Electroplating of alloys or thin film multilayers followed by controlled oxidation to the desired spinel phase offers an additional deposition option. In the present study binary Mn/Co alloys was fabricated by electrodeposition, and polarization curves were used to characterize the cathodic reactions on substrate surface. By controlling the current density precisely, coatings with Mn/Co around 1:1 has been successfully deposited in Mn/Co =10 solutions, SEM and EDX was used to characterize the surface morphology and composition.

Wu, J. (West Virginia University); Jiang, Y. (West Virginia University); Johnson, C.; Gong, M. (West Virginia University); Liu, X. (West Virginia University)

2007-09-01T23:59:59.000Z

266

Modulation on Ni{sub 2}MnGa(001) surface  

SciTech Connect

We report periodic modulation on (001) surface of Ni2MnGa ferromagnetic shape memory alloy. For the stoichiometric surface, analysis of the low energy electron diffraction (LEED) spot profiles shows that the modulation is incommensurate. The modulation appears at 200 K, concomitant with the first order structural transition to the martensitic phase.

D'Souza, S. W.; Rai, Abhishek; Nayak, J.; Maniraj, M.; Dhaka, R. S.; Barman, S. R.; Schlagel, D. L.; Lograsso, T. A. [UGC-DAE Consortium for Scientific Research, Khandwa Road, Indore, 452001, Madhya Pradesh (India); Ames Laboratory U. S. DOE, Iowa State University, Ames, Iowa 50011-3020 (United States)

2011-07-15T23:59:59.000Z

267

Southwest MN IPM STUFF All the pestilence that's fit to print  

E-Print Network (OSTI)

in heavily infested fields in the near future. Hatch will continue for some time,. After a hot, humid day and Outreach Center 23669 130th Street Lamberton, MN 56152 Phone: 507.752.5066 Cell: 507.276.1184 Fax: 507

Amin, S. Massoud

268

Southwest MN IPM STUFF All the pestilence that's fit to print  

E-Print Network (OSTI)

of fields (hot spots) or field edges. Alate aphids depositing nymphs can rapidly increase the percentage for larva in square foot areas on the ground. During hot weather armyworms may hide under litter. In small 130th Street Lamberton, MN 56152 Phone: 507.752.5066 Cell: 507.276.1184 Fax: 507.752.5097 E

Amin, S. Massoud

269

Southwest MN IPM STUFF All the pestilence that's fit to print  

E-Print Network (OSTI)

indeed treated and the infestation was not a localized hot spot, this may signal the beginning of the end 23669 130th Street Lamberton, MN 56152 Phone: 507.752.5066 Cell: 507.276.1184 Fax: 507.752.5097 E

Amin, S. Massoud

270

Frustration and multiferroic behavior in Ca3CoMnO6  

Science Conference Proceedings (OSTI)

Lu{sub 2}MnCoO{sub 6} and Ca{sub 3}MnCoO{sub 6} satisfy one of the primary goals of multiferroics research, namely ferromagnetic-like magnetization coupled to ferroelectric-like polarization. Thus the mechanism for magnetoelectric coupling in these materials deserves careful study. New data shows that the physics of these compound may be related to the classic 'ANNNI' model. Frustration between ferromagnetic nearest-neighbor and antiferromagnetic next-nearest-neighbor interactions between Ising spins creates an 'up up down down' magnetic structure in zero magnetic field, along c-axis chains that consist of alternating Co and Mn ions. In applied magnetic fields 'up up down,' 'up up up down' and other metastable variations can evolve, yielding hysteretic ferromagnetic-like magnetization. The key is that the phase slips between regions of 'up' and 'down' carries an electric polarization due to broken spatial inversion symmetry. Thus these phase slips can be manipulated with both electric and magnetic fields. The result is a profusion of magnetic and electric states that are closely-spaced in temperature, electric, and magnetic field. We present experimental studies of the magnetic, electric, and structural properties of these two compounds. We include very new data up to 100 Ton Ca{sub 3}CoMnO{sub 6} that resolves a key controversy of over the magnetic structure and the size of the moments.

Zapf, Vivien [Los Alamos National Laboratory

2012-06-01T23:59:59.000Z

271

Hydrogen Storage in a Microporous Metal-Organic Framework with Exposed Mn2+ Coordination Sites  

E-Print Network (OSTI)

Hydrogen Storage in a Microporous Metal-Organic Framework with Exposed Mn2+ Coordination Sites and 90 bar, which at 60 g H2/L provides a storage density 85% of that of liquid hydrogen. The material-358. (2) EERE: Hydrogen, Fuel Cells, & Infrastructure Technologies Program Homepage, www.eere.energy

272

Aliovalent titanium substitution in layered mixed Li Ni-Mn-Co oxides for lithium battery applications  

SciTech Connect

Improved electrochemical characteristics are observed for Li[Ni1/3Co1/3-yMyMn1/3]O2 cathode materials when M=Ti and y<0.07, compared to the baseline material, with up to 15percent increased discharge capacity.

Kam, Kinson; Doeff, Marca M.

2010-12-01T23:59:59.000Z

273

U.S. Energy Information Administration | Annual Energy Outlook 2013  

Gasoline and Diesel Fuel Update (EIA)

2 2 Regional maps Figure F7. Coal demand regions Figure F7. Coal Demand Regions CT,MA,ME,NH,RI,VT OH 1. NE 3. S1 4. S2 5. GF 6. OH 7. EN AL,MS MN,ND,SD IA,NE,MO,KS TX,LA,OK,AR MT,WY,ID CO,UT,NV AZ,NM 9. AM 11. C2 12. WS 13. MT 14. CU 15. ZN WV,MD,DC,DE 2. YP Region Content Region Code NY,PA,NJ VA,NC,SC GA,FL IN,IL,MI,WI Region Content Region Code 14. CU 13. MT 16. PC 15. ZN 12. WS 11. C2 9. AM 5. GF 8. KT 4. S2 7. EN 6. OH 2. YP 1. NE 3. S1 10. C1 KY,TN 8. KT 16. PC AK,HI,WA,OR,CA 10. C1 CT,MA,ME,NH,RI,VT OH 1. NE 3. S1 4. S2 5. GF 6. OH 7. EN AL,MS MN,ND,SD IA,NE,MO,KS TX,LA,OK,AR MT,WY,ID CO,UT,NV AZ,NM 9. AM 11. C2 12. WS 13. MT 14. CU 15. ZN WV,MD,DC,DE 2. YP Region Content Region Code NY,PA,NJ VA,NC,SC GA,FL IN,IL,MI,WI Region Content Region Code 14. CU 13. MT

274

U.S. Energy Information Administration | Annual Energy Outlook 2011  

Gasoline and Diesel Fuel Update (EIA)

4 4 Regional maps Figure F7. Coal demand regions Figure F7. Coal Demand Regions CT,MA,ME,NH,RI,VT OH 1. NE 3. S1 4. S2 5. GF 6. OH 7. EN AL,MS MN,ND,SD IA,NE,MO,KS TX,LA,OK,AR MT,WY,ID CO,UT,NV AZ,NM 9. AM 11. C2 12. WS 13. MT 14. CU 15. ZN WV,MD,DC,DE 2. YP Region Content Region Code NY,PA,NJ VA,NC,SC GA,FL IN,IL,MI,WI Region Content Region Code 14. CU 13. MT 16. PC 15. ZN 12. WS 11. C2 9. AM 5. GF 8. KT 4. S2 7. EN 6. OH 2. YP 1. NE 3. S1 10. C1 KY,TN 8. KT 16. PC AK,HI,WA,OR,CA 10. C1 CT,MA,ME,NH,RI,VT OH 1. NE 3. S1 4. S2 5. GF 6. OH 7. EN AL,MS MN,ND,SD IA,NE,MO,KS TX,LA,OK,AR MT,WY,ID CO,UT,NV AZ,NM 9. AM 11. C2 12. WS 13. MT 14. CU 15. ZN WV,MD,DC,DE 2. YP Region Content Region Code NY,PA,NJ VA,NC,SC GA,FL IN,IL,MI,WI Region Content Region Code 14. CU 13. MT

275

High external quantum efficiency and fill-factor InGaN/GaN heterojunction solar cells grown by NH{sub 3}-based molecular beam epitaxy  

SciTech Connect

High external quantum efficiency (EQE) p-i-n heterojunction solar cells grown by NH{sub 3}-based molecular beam epitaxy are presented. EQE values including optical losses are greater than 50% with fill-factors over 72% when illuminated with a 1 sun AM0 spectrum. Optical absorption measurements in conjunction with EQE measurements indicate an internal quantum efficiency greater than 90% for the InGaN absorbing layer. By adjusting the thickness of the top p-type GaN window contact layer, it is shown that the short-wavelength (<365 nm) quantum efficiency is limited by the minority carrier diffusion length in highly Mg-doped p-GaN.

Lang, J. R.; Hurni, C. A.; Cruz, S. C.; Matioli, E.; Speck, J. S. [Department of Materials, University of California, Santa Barbara, California 93106 (United States); Neufeld, C. J.; Mishra, U. K. [Department of Electrical and Computer Engineering, University of California, Santa Barbara, California 93106 (United States)

2011-03-28T23:59:59.000Z

276

QM/MM Lineshape Simulation of the Hydrogen-bonded Uracil NH Stretching Vibration of the Adenine:Uracil Base Pair in CDCl$_3$  

E-Print Network (OSTI)

A hybrid Car-Parrinello QM/MM molecular dynamics simulation has been carried out for the Watson-Crick base pair of 9-ethyl-8-phenyladenine and 1-cyclohexyluracil in deuterochloroform solution at room temperature. The resulting trajectory is analyzed putting emphasis on the N-H$...$N Hydrogen bond geometry. Using an empirical correlation between the $\\NN$-distance and the fundamental NH-stretching frequency, the time-dependence of this energy gap along the trajectory is obtained. From the gap-correlation function we determine the infrared absorption spectrum using lineshape theory in combination with a multimode oscillator model. The obtained average transition frequency and the width of the spectrum is in reasonable agreement with recent experimental data.

Yan, Yun-an; Khn, Oliver

2008-01-01T23:59:59.000Z

277

Local atomic and electronic structure in LaMnO{sub 3} across the orbital ordering transition  

SciTech Connect

The local atomic disorder and electronic structure in the environment of manganese atoms in LaMnO{sub 3} has been studied by x-ray absorption spectroscopy over a temperature range (300-870 K) covering the orbital ordering transition ({approx}710 K). The Mn-O distance splitting into short and long bonds (1.95 and 2.15 A) is kept across the transition temperature, so that the MnO{sub 6} octahedra remain locally Jahn-Teller distorted. Discontinuities in the Mn local structure are identified in the extended x-ray fine structure spectra at this temperature, associated with a reduction of the disorder in the superexchange angle and to the removal of the anisotropy in the radial disorder within the coordination shell. Subtle changes in the electronic local structure also take place at the Mn site at the transition temperature. The near-edge spectra show a small drop of the Mn 4p hole count and a small enhancement in the pre-edge structures at the transition temperature. These features are associated with an increase of the covalence of the Mn-O bonds. Our results shed light on the local electronic and structural phenomena in a model of order-disorder transition, where the cooperative distortion is overcome by the thermal disorder.

Souza, Raquel A.; Souza-Neto, Narcizo M.; Ramos, Aline Y.; Tolentino, Helio C.N.; Granado, Eduardo [Laboratorio Nacional de Luz Sincrotron (LNLS), P.O. Box 6192, 13084-971, Campinas, Sao Paulo, Brazil and (Brazil); Instituto de Fisica Gleb Wataghin, IFGW-UNICAMP, Campinas, SP (Brazil); Laboratorio Nacional de Luz Sincrotron (LNLS), P.O. Box 6192, 13084-971, Campinas, Sao Paulo, Brazil and (Brazil); Departamento de Fisica dos Materiais e Mecanica, DFMT-IF-USP, Sao Paulo, SP (Brazil); Laboratorio Nacional de Luz Sincrotron (LNLS), P.O. Box 6192, 13084-971, Campinas, Sao Paulo, Brazil and (Brazil); Laboratoire de Mineralogie-Cristallographie de Paris, LMCP-UMR 7590-CNRS, Paris (France); Laboratorio Nacional de Luz Sincrotron (LNLS), P.O. Box 6192, 13084-971, Campinas, Sao Paulo (Brazil); Laboratorio Nacional de Luz Sincrotron (LNLS), P.O. Box 6192, 13084-971, Campinas, Sao Paulo, Brazil and (Brazil); Instituto de Fisica Gleb Wataghin, IFGW-UNICAMP, Campinas, SP (Brazil)

2004-12-01T23:59:59.000Z

278

In situ synchrotron x-ray studies of LiMn{sub 2}O{sub 4} cathodes  

DOE Green Energy (OSTI)

LiCoO{sub 2} cathodes are now used in most commercial lithium ion batteries. LiMn{sub 2}O{sub 4} is an attractive low cost alternative. However, it is difficult to make reproducibly. At Brookhaven National Laboratory two in situ synchrotron x-ray techniques, that are available at the National Synchrotron Light Source (NSLS), have been used to investigate LiMn{sub 2}O{sub 4}. The techniques are x-ray absorption and high resolution x-ray diffraction. With x-ray absorption it is possible to follow the changes in the Mn oxidation state and the changes in the Mn-O and Mn-Mn bond lengths on cycling. Also it is possible to detect amorphous phases. The high energy x-rays at the diffraction Beam Lines at the NSLS (up to 24 KeV) permit in situ x-ray diffraction, in the transmission mode, in thin lithium and lithium ion cells. The evolution of the structural chances that occur on cycling can be followed. These in situ measurements were done on Li/LiMn{sub 2}O{sub 4} cells with a liquid electrolyte (1 M LiPF{sub 6} in a 1:1:3 PC:EC:DMC solvent).

McBreen, J.; Mukerjee, S.; Yang, X.Q. [and others

1997-05-01T23:59:59.000Z

279

Electrochemical and structural characterization of titanium-substituted manganese oxides based on Na0.44MnO2  

DOE Green Energy (OSTI)

A series of titanium-substituted manganese oxides, Li{sub x}Ti{sub y}Mn{sub 1-y}O{sub 2} (y = 0.11, 0.22, 0.33, 0.44, and 0.55) with the Na{sub 0.44}MnO{sub 2} structure were prepared from Na{sub x}Ti{sub y}Mn{sub 1-y}O{sub 2} (x {approx} 0.44) precursors. The electrochemical characteristics of these compounds, which retain the unique double-tunnel structure during ion exchange, were examined in lithium/polymer electrolyte cells operating at 85 C. All of the substituted cathode materials intercalated lithium reversibly, with Li{sub x}Ti{sub 0.22}Mn{sub 0.78}O{sub 2} exhibiting the highest capacity in polymer cells, about 10-20% greater than that of unsubstituted Li{sub x}MnO{sub 2} made from Na{sub 0.44}MnO{sub 2}. In common with Li{sub x}MnO{sub 2}, the Ti-substituted materials exhibited good capacity retention over one hundred or more cycles, with some compositions exhibiting a fade rate of less than 0.03% per cycle.

Doeff, Marca M.; Richardson, Thomas J.; Hwang, Kwang-Taek

2004-03-01T23:59:59.000Z

280

Selective Catalytic Reduction (SCR) of nitric oxide with ammonia using Cu-ZSM-5 and Va-based honeycomb monolith catalysts: effect of H2 pretreatment, NH3-to-NO ratio, O2, and space velocity  

E-Print Network (OSTI)

In this work, the steady-state performance of zeolite-based (Cu-ZSM-5) and vanadium-based honeycomb monolith catalysts was investigated in the selective catalytic reduction process (SCR) for NO removal using NH3. The aim was to delineate the effect of various parameters including pretreatment of the catalyst sample with H2, NH3-to-NO ratio, inlet oxygen concentration, and space velocity. The concentrations of the species (e.g. NO, NH3, and others) were determined using a Fourier Transform Infrared (FTIR) spectrometer. The temperature was varied from ambient (25 C) to 500 C. The investigation showed that all of the above parameters (except pre-treatment with H2) significantly affected the peak NO reduction, the temperature at which peak NO reduction occurred, and residual ammonia left at higher temperatures (also known as 'NH3 slip'). Depending upon the particular values of the parameters, a peak NO reduction of around 90% was obtained for both the catalysts. However, an accompanied generation of N2O and NO2 species was observed as well, being much higher for the vanadium-based catalyst than for the Cu-ZSM-5 catalyst. For both catalysts, the peak NO reduction decreased with an increase in space velocity, and did not change significantly with an increase in oxygen concentration. The temperatures at which peak NO reduction and complete NH3 removal occurred increased with an increase in space velocity but decreased with an increase in oxygen concentration. The presence of more ammonia at the inlet (i.e. higher NH3-to-NO ratio) improved the peak NO reduction but simultaneously resulted in an increase in residual ammonia. Pretreatment of the catalyst sample with H2 (performed only for the Cu-ZSM-5 catalyst) did not produce any perceivable difference in any of the results for the conditions of these experiments.

Gupta, Saurabh

2003-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "mn nh nj" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Magnetic order near 270 K in mineral and synthetic Mn{sub 2}FeSbO{sub 6} ilmenite  

SciTech Connect

The structural and magnetic properties of Mn{sub 2}FeSbO{sub 6} single-crystalline mineral and ceramic samples synthesized under thermobaric treatment have been investigated, and compared to theoretical predictions based on first-principles electronic structure calculations. This ilmenite system displays a sharp magnetic transition just below the room temperature related to a ferrimagnetic ordering of the Mn{sup 2+} and Fe{sup 3+} cations, which makes Mn{sub 2}FeSbO{sub 6} a promising candidate for designing functional magnetic materials.

Mathieu, R.; Hudl, M.; Nordblad, P. [Department of Engineering Sciences, Uppsala University, Box 534, SE-75121 Uppsala (Sweden); Ivanov, S. A. [Department of Engineering Sciences, Uppsala University, Box 534, SE-75121 Uppsala (Sweden); Department of Inorganic Materials, Karpov' Institute of Physical Chemistry, Vorontsovo pole, 10 105064, Moscow K-64 (Russian Federation); Bazuev, G. V. [Institute of Solid-State Chemistry, Ural Branch of the Russian Academy of Science, 620999, Ekaterinburg GSP-145 (Russian Federation); Lazor, P. [Department of Earth Sciences, Uppsala University, Villavaegen 16, SE-75236 Uppsala (Sweden); Solovyev, I. V. [National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan)

2011-05-16T23:59:59.000Z

282

In situ X-ray absorption fine structure studies of a manganese dioxide electrode in a rechargeable MnO{sub 2}/Zn alkaline battery environment  

DOE Green Energy (OSTI)

Electronic and structural aspects of a MnO{sub 2} electrode in a rechargeable MnO{sub 2}/Zn battery environment have been investigated by in situ Mn K-edge X-ray absorption fine structure (XAFS). The relative amplitudes of the three major Fourier transform shells of the EXAFS (extended XAFS) function of the rechargeable MnO{sub 2} electrode in the undischarged state were found to be similar to those found for ramsdellite, a MnO{sub 2} polymorph with substantial corner-sharing linkages among the basic MnO{sub 6} octahedral units. The analyses of the background-subtracted pre-edge peaks and absorption edge regions for the nominally 1-e{sup {minus}} discharged electrode were consistent with Mn{sup 3+} as being the predominant constituent species, rather than a mixture of Mn{sup 4+} and Mn{sup 2+} sites. Furthermore, careful inspection of both the XANES (X-ray absorption near edge structure) and EXAFS indicated that the full recharge of MnO, which had been previously discharged either by a 1- or 2-equivalent corner-sharing linkages compared to the original undischarged MnO{sub 2}.

Mo, Y.; Hu, Y.; Bae, I.T.; Miller, B.; Scherson, D.A. [Case Western Reserve Univ., Cleveland, OH (United States). Dept. of Chemistry; Antonio, M.R. [Argonne National Lab., IL (United States). Chemistry Div.

1996-12-31T23:59:59.000Z

283

X-ray spectroscopic study of the charge state and local orderingof room-temperature ferromagnetic Mn oped ZnO  

Science Conference Proceedings (OSTI)

The charge state and local ordering of Mn doped into a pulsed laser deposited single-phase thin film of ZnO are investigated by using X-ray absorption spectroscopy at the O K-, Mn K- and L-edges, and X-ray emission spectroscopy at the O K- and Mn L-edge. This film is found to be ferromagnetic at room temperature. EXAFS measurement shows that Mn{sup 2+} replaces Zn site in tetrahedral symmetry, and there is no evidence for either metallic Mn or MnO in the film. Upon Mn doping, the top of O 2p valence band extends into the bandgap indicating additional charge carries being created.

Guo, J.-H.; Gupta, Amita; Sharma, Parmanand; Rao, K.V.; Marcus,M.A.; Dong, C.L.; Guillen, J.M.O.; Butorin, S.M.; Mattesini, M.; Glans,P.A.; Smith, K.E.; Chang, C.L.; Ahuja, R.

2007-08-07T23:59:59.000Z

284

The preparation of carbon nanotube/MnO2 composite fiber and its application to flexible micro-supercapacitor  

Science Conference Proceedings (OSTI)

In recent years, flexible electronic devices pursued for potential applications. The design and the fabrication of a novel flexible nanoarchitecture by coating electrical conductive MWCNT fiber with ultrathin films of MnO2 to achieve high ...

Li Li, Chen Chen, Jing Xie, Zehuai Shao, Fuxin Yang

2013-01-01T23:59:59.000Z

285

Synthesis and Electrochemical Properties of Monoclinic LiMnBO[subscript 3] as a Li Intercalation Material  

E-Print Network (OSTI)

We investigated the structural stability and electrochemical properties of LiMnBO3 in the hexagonal and monoclinic form with ab initio computations and, for the first time, report electrochemical data on monoclinic ...

Kim, Jae Chul

286

Synthesis and Electrochemical Properties of Monoclinic LiMnBO[subscript 3] as a Li Intercalation Material  

E-Print Network (OSTI)

We investigated the structural stability and electrochemical properties of LiMnBO[subscript 3] in the hexagonal and monoclinic form with ab initio computations and, for the first time, report electrochemical data on ...

Kim, Jae Chul

287

Thermal Stabilities of Delithiated Olivine MPO[subscript 4] (M=Fe,Mn) Cathodes investigated using First Principles Calculations  

E-Print Network (OSTI)

We present an analysis of the thermal reduction of delithiated LiMnPO[subscript 4] and LiFePO[subscript 4] based on the quarternary phase diagrams as calculated from first principles. Our results confirm the recent ...

Ong, Shyue Ping

288

Preparation of Mn{sub 2}SnO{sub 4} nanoparticles as the anode material for lithium secondary battery  

Science Conference Proceedings (OSTI)

The ultrafine Mn{sub 2}SnO{sub 4} nanoparticles with diameters of 5-10 nm have been prepared by thermal decomposition of precursor MnSn(OH){sub 6}. The MnSn(OH){sub 6} nanoparticles precursor was synthesized by a hydrothermal microemulsion method. X-ray diffraction, transmission electron microscopy, high-resolution transmission electron microscopy and electron diffraction have been employed to characterize the crystal structures and morphologies of the as-prepared samples. High-resolution transmission electron microscopy observations revealed that the as-synthesized nanoparticles were single crystals. The thermal characterization was studied by differential thermal analysis and thermogravimetry analysis measurements. Electrochemical test showed that the Mn{sub 2}SnO{sub 4} nanoparticles exhibited a high initial charge-discharge capacity of 1320 mAh/g.

Lei Shuijin [School of Materials Science and Engineering, Nanchang University, No. 999, Xuefu Avenue Honggutan New District, Nanchang, Jiangxi 330031 (China)], E-mail: shjlei@ncu.edu.cn; Tang Kaibin [Nanomaterial and Nanochemistry, Hefei National Laboratory for Physical Sciences at Micro-scale, University of Science and Technology of China, Hefei, Anhui 230026 (China)], E-mail: kbtang@ustc.edu.cn; Chen Chunhua; Jin Yi [Department of Materials Science and Engineering, University of Science and Technology of China, Hefei, Anhui 230026 (China); Zhou Lang [School of Materials Science and Engineering, Nanchang University, No. 999, Xuefu Avenue Honggutan New District, Nanchang, Jiangxi 330031 (China)

2009-02-04T23:59:59.000Z

289

Electrode properties of Mn2O3 nanospheres synthesized by combined sonochemical/solvothermal method for use in electrochemical capacitors  

Science Conference Proceedings (OSTI)

We report here an efficient single step combined sonochemical and solvothermal synthesis process to obtain bulk quantities of nanospherical particles of cubic Mn2O3 and characterized its pseudocapacitive characteristics in relevance ...

Teressa Nathan; Michael Cloke; S. R. S. Prabaharan

2008-01-01T23:59:59.000Z

290

Electrochemical and structural characterization of titanium-substituted manganese oxides based on Na0.44MnO2  

E-Print Network (OSTI)

by heating them in a molten salt- mixture of 68-mol% LiNOtakes place during the molten salt exchange. Because the850 C. c) prepared by molten salt exchange of Na x Ti y Mn

Doeff, Marca M.; Richardson, Thomas J.; Hwang, Kwang-Taek

2004-01-01T23:59:59.000Z

291

Synthesis and Electrochemical Characterization of M2Mn3O8 (M=Ca, Cu) Compounds and Derivatives  

E-Print Network (OSTI)

surprising, because the molten salt environment at elevatedthe product of the molten salt reaction can be considered tothat is formed during the molten salt reaction with Ca 2 Mn

Park, Yong Joon; Doeff, Marca M.

2005-01-01T23:59:59.000Z

292

DEPARTMENT OF ENERGY EERE PROJECT MN-IAGEMENT CENTER NEPA DETERMINATION  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

MN-IAGEMENT CENTER MN-IAGEMENT CENTER NEPA DETERMINATION Page 1 of4 RECIPIENT:A1aska Energy Authority STATE: AK PROJECT TITLE: Alaska Wind Energy PrOject Funding Opportunity Announcement Number PnK:urcmcntlnstrumcnl Numbcr NEPA Control Number CID Number DE-FG-36-05GOO85038 DE-FG-36-05GOO85038 GFO-G085038-002 G085038 Bastd on my review orthe information concuning the proposed adion, as NEPA Compliance Officer (authorized under DOE Order 45 1.IA), I have made the following determination: ex, EA. [IS APPENDIX AND NUMBER: Description: 61 .19 Microwave, Siting, construction, modification. operation, and removal of microwave, radio communication, and meteorological , meteorological towers and assOCIated facilities, prOVided that the towers and associated facilitJes would

293

Optical transitions in MnGa{sub 2}Se{sub 4}  

Science Conference Proceedings (OSTI)

The dependence of the absorption coefficient on incident photon energy in a MnGa{sub 2}Se{sub 4} single crystal has been investigated in the temperature range 110-295 K. Using group-theory analysis of the electron state symmetry and comparison of the symmetry of the energy spectrum of MnGa{sub 2}Se{sub 4} and its isoelectronic analogs, a conclusion about the character of optical transitions has been drawn. It is shown that the features observed at 2.31 and 2.45 eV are related to the intracenter transitions {sup 6}A{sub 1}{sup 1} {yields} {sup 4}T{sub 2}({sup 4}G) and {sup 6}A{sub 1}{sup 2} {yields} {sup 4}T{sub 2}({sup 4}G). The {sup 6}A{sub 1} state is split by the crystal field.

Tagiev, B. G.; Kerimova, T. G., E-mail: ktaira@physics.ab.az; Tagiev, O. B.; Asadullayeva, S. G.; Mamedova, I. A. [National Academy of Sciences of Azerbaijan, Institute of Physics (Azerbaijan)

2012-06-15T23:59:59.000Z

294

RECIPIENT:Minnesota Department of Commerce, Office of Energy Security SEP ARRA STATE: MN  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Minnesota Department of Commerce, Office of Energy Security SEP ARRA STATE: MN Minnesota Department of Commerce, Office of Energy Security SEP ARRA STATE: MN PROJECT TITLE: SEP - Residential Ground Source Heat Pump Installation - Schmitz, Mary C. Funding Opportunity Announcement Number DE FOA 0000052 Procurement Instrument Number EE0000164 NEPA Control Number cm Number GFO-0000164-018 0 Based on my review of the information concerning the proposed action, as NEPA Compliance Officer (authorized under DOE Order 451.1A), I have made the following determination: CX, EA, EIS APPENDIX AND NUMBER: Description: 85.1 Actions to conserve energy, demonstrate potential energy conservation, and promote energy-efficiency that do not increase the indoor concentrations of potentially harmful substances. These actions may involve financial and technical

295

File:USDA-CE-Production-GIFmaps-MN.pdf | Open Energy Information  

Open Energy Info (EERE)

MN.pdf MN.pdf Jump to: navigation, search File File history File usage Minnesota Ethanol Plant Locations Size of this preview: 776 × 600 pixels. Full resolution ‎(1,650 × 1,275 pixels, file size: 311 KB, MIME type: application/pdf) Description Minnesota Ethanol Plant Locations Sources United States Department of Agriculture Related Technologies Biomass, Biofuels, Ethanol Creation Date 2010-01-19 Extent State Countries United States UN Region Northern America States Minnesota External links http://www.nass.usda.gov/Charts_and_Maps/Ethanol_Plants/ File history Click on a date/time to view the file as it appeared at that time. Date/Time Thumbnail Dimensions User Comment current 16:16, 27 December 2010 Thumbnail for version as of 16:16, 27 December 2010 1,650 × 1,275 (311 KB) MapBot (Talk | contribs) Automated bot upload

296

Charge Melting & Polaron Collapse in LA1.2SR1.8MN207  

NLE Websites -- All DOE Office Websites (Extended Search)

Charge Melting & Polaron Collapse in LA1.2SR1.8MN207 Charge Melting & Polaron Collapse in LA1.2SR1.8MN207 Recent studies carried out on the Synchrotron Radiation Instrumentation Collaborative Access Team's beamline I-ID-C at the Advanced Photon Source provide new insights into charge melting and polaron collapse. X-ray and neutron scattering measurements directly demonstrate the existence of polarons in the paramagnetic phase of optimally doped colossal magnetoresistive oxides. The polarons exhibit short-range correlations that grow with decreasing temperature, but disappear abruptly at the ferromagnetic transition because of the sudden charge delocalization. The "melting" of the charge ordering as we cool through TC occurs with the collapse of the quasistatic polaron scattering, and provides important new

297

High capacitive performance of nanostructured Mn-Ni-Co oxide composites for supercapacitor  

SciTech Connect

Nanostructured Mn-Ni-Co oxide composites (MNCO) were prepared by thermal decomposition of the precursor obtained by chemical co-precipitation of Mn, Ni and Co salts. The chemical composition and morphology were characterized by X-ray diffraction (XRD), energy dispersive spectroscopy (EDS) and scanning electron microscopy (SEM). The electrochemical capacitance of MNCO electrode was examined by cyclic voltammetry, impedance and galvanostatic charge-discharge measurements. The results showed that MNCO electrode exhibited the good electrochemical characteristics. A maximum capacitance value of 1260 F g{sup -1} could be obtained within the potential range of -0.1 to 0.4 V versus saturated calomel electrode (SCE) in 6 mol L{sup -1} KOH electrolyte.

Luo Jianmin [Institute of Applied Chemistry, Xinjiang University, Urumqi 830046 (China); Gao Bo [College of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016 (China); Zhang Xiaogang [College of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016 (China)], E-mail: azhangxg@163.com

2008-05-06T23:59:59.000Z

298

Structural and magnetic properties of MBE grown GeMnN2 thin films  

Science Conference Proceedings (OSTI)

Epitaxial GeMnN{sub 2} thin films are synthesized by plasma-assisted molecular beam epitaxy. Transmission electron microscopy and x-ray diffraction measurements confirm that it is the orthorhombic variant, consistent with the predictions of first-principles calculations. The magnetic properties of the films are related to defects, with samples grown under Ge-rich conditions exhibiting a net magnetic moment above room temperature. These results are explained by first-principles calculations, indicating that the preferential substitution of one magnetic sublattice of GeMnN{sub 2} by impurities and/or intrinsic defects such as Ge antisites produces a net magnetic moment in an antiferromagnetic background, and also introduces spin-polarized carriers near the Fermi level.

Liu, Y [University of Wisconsin, Milwaukee; Lazarov, V. K. [University of Wisconsin, Milwaukee; Cheung, S.H. [University of Wisconsin, Milwaukee; Keavney, D.J. [Argonne National Laboratory (ANL); Gai, Zheng [ORNL; Gajdardziska-Josifovska, M [University of Wisconsin, Milwaukee; Weinert, M [University of Wisconsin, Milwaukee; Li, Lian [University of Wisconsin, Milwaukee

2012-01-01T23:59:59.000Z

299

Irradiation-controlled giant magnetoresistance of PtMn-based spin valve  

Science Conference Proceedings (OSTI)

He{sup +}-ion irradiation resulted in the direct ordering of PtMn without postannealing. Samples were irradiated with 2 MeV He{sup +} ions and a beam current of 1.08 {mu}A/cm{sup 2} such that the corresponding surface temperature was 190 deg. C. The exchange bias direction was set in situ during irradiation in a field of 900 Oe. A high giant magnetoresistance (GMR) ratio of 11% was obtained in PtMn-based spin valves after He{sup +} irradiation. The GMR is completely eliminated after it is irradiated with oxygen ions at 42 keV. Combining He{sup +} with oxygen-ion irradiation can provide magnetic patterning for GMR sensors.

Huang, S.-H.; Lai, C.-H.; Chiang, C. C.; Yang, C.-H. [Department of Materials Science and Engineering, National Tsing Huang University, 101, Section 2, Kuang Fu Road, Hsinchu, Taiwan 30013 (China)

2006-04-15T23:59:59.000Z

300

FTIR and Raman Study of LixTiyMn1-y2(y=0,0.11) Cathodes in  

NLE Websites -- All DOE Office Websites (Extended Search)

FTIR and Raman Study of LixTiyMn1-y2(y=0,0.11) Cathodes in FTIR and Raman Study of LixTiyMn1-y2(y=0,0.11) Cathodes in Pyrrolidinium-based Ionic Liquid Electrolyte Systems Title FTIR and Raman Study of LixTiyMn1-y2(y=0,0.11) Cathodes in Pyrrolidinium-based Ionic Liquid Electrolyte Systems Publication Type Journal Article Year of Publication 2009 Authors Hardwick, Laurence J., Juliette A. Saint, Ivan T. Lucas, Marca M. Doeff, and Robert Kostecki Journal J. Electrochemical Society Volume 156 Issue 2 Pagination A120-A127 Keywords electrochemical electrodes, Fourier transform spectra, infrared spectra, lithium compounds, manganese compounds, Raman spectra, titanium compounds Abstract This work demonstrates the protective effect of partial titanium substitution in LixTi0.11Mn0.89O2 against surface decomposition in room-temperature ionic liquid (RTILs) cells. Raman microscopy and reflectance Fourier transform IR (FTIR) spectroscopy were used to analyze electrodes recovered from cycled Li/LixTiyMn1-yO2 (y=0,0.11) cells containing the 0.5mol/kg LiTFSI in P13FSI RTIL electrolyte. [TFSI=bis(trifluoromethanesulfonyl)imide .] Raman and FTIR spectra of cycled LixMnO2 cathodes showed many distinct bands that can be attributed to both the electrolyte and electrode decomposition products. The thickness of the amorphous porous layer on the LixMnO2 cathode increased during cycling. The surface degradation of LixMnO2 and precipitation of electrolyte decomposition products contributed to the film growth. Improved cycling behavior was observed in cells containing LixTi0.11Mn0.89O2 , yet Raman spectroscopy also showed possible surface degradation. The FTIR spectra of cycled LixMnO2 and LixTi0.11Mn0.89O2 cathodes displayed bands characteristic for LiSO3CF3 and Li2NSO2CF3 , which originate from the reaction of the TFSI anion with traces of water present in the cell.

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301

LiFe(x)Mn(1-x)PO(4): A Cathode for Lithium-ion Batteries  

DOE Green Energy (OSTI)

The high redox potential of LiMnPO{sub 4}, {approx}4.0 vs. (Li{sup +}/Li), and its high theoretical capacity of 170 mAh g{sup -1} makes it a promising candidate to replace LiCoO{sub 2} as the cathode in Li-ion batteries. However, it has attracted little attention because of its severe kinetic problems during cycling. Introducing iron into crystalline LiMnPO{sub 4} generates a solid solution of LiFe{sub x}Mn{sub 1-x}PO{sub 4} and increases kinetics; hence, there is much interest in determining the Fe-to-Mn ratio that will optimize electrochemical performance. To this end, we synthesized a series of nanoporous LiFe{sub x}Mn{sub 1-x}PO{sub 4} compounds (with x = 0, 0.05, 0.1, 0.15, and 0.2), using an inexpensive solid-state reaction. The electrodes were characterized using X-ray diffraction and energy-dispersive spectroscopy to examine their crystal structure and elemental distribution. Scanning-, tunneling-, and transmission-electron microscopy (viz., SEM, STEM, and TEM) were employed to characterize the micromorphology of these materials; the carbon content was analyzed by thermogravimetric analyses (TGAs). We demonstrate that the electrochemical performance of LiFe{sub x}Mn{sub 1-x}PO{sub 4} rises continuously with increasing iron content. In situ synchrotron studies during cycling revealed a reversible structural change when lithium is inserted and extracted from the crystal structure. Further, introducing 20% iron (e.g., LiFe{sub 0.2}Mn{sub 0.8}PO{sub 4}) resulted in a promising capacity (138 mAh g{sup -1} at C/10), comparable to that previously reported for nano-LiMnPO{sub 4}.

J Hong; F Wang; X Wang; J Graetz

2011-12-31T23:59:59.000Z

302

Modeling, synthesis and characterization of LiMn{sub 2}O{sub 4} spinels  

DOE Green Energy (OSTI)

The authors report on an integrated program to understand the fundamentals of LiMn{sub 2}O{sub 4} performance as a cathode for lithium ion rechargeable batteries. Specifically, this program is designed to address the effects of doping on the crystal chemistry, lattice constants, and electrochemical performance. The work is being expanded to include studies on LiCoO{sub 2} and LiNiO{sub 2}.

Doughty, D.H.; Ingersoll, D.; Cygan, R.T.; Westrich, H.R.; Rodriguez, M.A.; Boyle, T.J.; Voigt, J.A. [Sandia National Labs., Albuquerque, NM (United States); Johnson, B.J. [3M Co., St. Paul, MN (United States). Specialty Chemicals Div.

1997-11-01T23:59:59.000Z

303

Annealing effect on the giant magnetoresistance of La-Ca-Mn-O thin films  

SciTech Connect

Thin films of perovskite-like (La,Ca)MnO{sub {delta}} with (001) orientation were grown epitaxially on (100) MgO substrates by a simple facing-target sputtering technique. The as-deposited films already possess a significant low field giant magnetoresistance. Further post-annealing experiments on these samples indicate that the high electrical resistivity is not a prerequisite of the giant magnetoresistance effect.

Zeng, X.T.; Wong, H.K. [Chinese Univ. of Hong Kong, Chatin (Hong Kong). Physics Dept.

1995-11-01T23:59:59.000Z

304

Elastic Properties of the Zintl Ferromagnet Yb14MnSb11  

SciTech Connect

We report measurements of the elastic moduli as a function of temperature (5-300) K and magnetic field (0-2 T) for the Zintl ferromagnet Yb{sub 14}MnSb{sub 11}, which is believed to be a rare example of an underscreened Kondo lattice. The elastic moduli measured below the Curie temperature in this complex ferromagnet exhibit unusual lattice stiffening that is independent of the magnetic field and can be adequately modeled using the Landau theory.

Bhattacharya, Sriparna [University of Tennessee, Knoxville (UTK); Marinescu, D. C. [Clemson University; Morris, James R [ORNL; Sergienko, Ivan A [ORNL; Sales, Brian C [ORNL; Mandrus, D. [University of Tennessee, Knoxville (UTK) & Oak Ridge National Laboratory (ORNL); Keppens, V. [University of Tennessee, Knoxville (UTK)

2012-01-01T23:59:59.000Z

305

Inhomogeneous distribution of mercury on the surfaces of rapidly rotating HgMn stars  

E-Print Network (OSTI)

Starspots are usually associated with the action of magnetic fields at the stellar surfaces. However, recently an inhomogeneous chemical distribution of mercury was found for the mercury-manganese (HgMn) star alpha And -- a well-established member of a non-magnetic subclass of the chemically peculiar stars of the upper main sequence. In this study we present first results of the high-resolution survey of the HgII 3984 resonance line in the spectra of rapidly rotating HgMn stars with atmospheric parameters similar to those of alpha And. We use spectrum synthesis modelling and take advantage of the Doppler resolution of the stellar surfaces to probe horizontal structure of mercury distribution. Clear signatures of spots are found in the HgII 3984 line profiles of HR 1185 and HR 8723. Two observations of the latter star separated by two days give evidence for the line profile variability. We conclude that inhomogeneous distribution of Hg is a common phenomenon for the rapidly rotating HgMn stars in the 13000--13800 K effective temperature range independently of the stellar evolutionary stage. These results establish existence of a new class of spectrum variable spotted B-type stars. It is suggested that the observed Hg inhomogeneities arise from dynamical instabilities in the chemical diffusion processes and are unrelated to magnetic phenomena.

O. Kochukhov; N. Piskunov; M. Sachkov; D. Kudryavtsev

2005-05-06T23:59:59.000Z

306

Thin-film Li-LiMn{sub 2}O{sub 4} batteries  

DOE Green Energy (OSTI)

Thin-film rechargeable Li-LiMn{sub 2}O{sub 4} batteries have been fabricated and characterized. Following deposition by electron beam evaporation of LiMn{sub 2}O{sub 4}, the amorphous as-deposited cathode films 1 cm{sup 2} in area by 0.3 to 4 {mu}m thick were annealed at 700{degree}C to 800{degree}C in oxygen in order to form the crystalline spinel phase. The capacity of the cells between 4.5 V to 3.8 V depended on the annealing conditions and ranged from 50 {mu}Ah/mg to 120 {mu}Ah/mg. When cycled over this range, the batteries exhibited excellent secondary performance with capacity losses as low as 0.001% per cycle. On charging to 5.3 V, a plateau with a median voltage of 5.1 V was observed. The total charge extracted between 3.8 V to 5.3 V corresponded to about 1Li/Mn{sub 2}O{sub 4}.

Bates, J.B.; Lubben, D.; Dudney, N.J.

1994-11-01T23:59:59.000Z

307

Redox Active Layer-by-Layer Structures containing MnO2 Nanoparticles  

Science Conference Proceedings (OSTI)

Nanoscale materials provide unique properties that will enable new technologies and enhance older ones. One area of intense activity in which nanoscale materials are being used is in the development of new functional materials for battery applications. This effort promises superior materials with properties that circumvent many of the problems associated with traditional battery materials. Previously we have worked on several approaches for using nanoscale materials for application as cathode materials in rechargeable Li batteries. Our recent work has focused on synthesizing MnO2 nanoparticles and using these in layer-by-layer (LbL) structures to probe the redox properties of the nanoparticles. We show that the aqueous colloidal nanoparticles produced by butanol reduction of tetramethylammonium permanganate can be trapped in thin films using a layer-by-layer deposition approach, and that these films are both redox active and exhibit kinetically facile electrochemical responses. We show cyclic voltammetry of MnO2 colloidal nanoparticles entrapped in a LbL thin film at an ITO electrode surface using poly(diallyldimethylammonium chloride) (PDDA). CV experiments demonstrate that Li+ insertion accompanies Mn(IV) reduction in LiClO4 supporting electrolytes, and that reduction is hindered in supporting electrolytes containing only tetrabutylammonium cations. We also show that electron propagation through multilayer films is facile, suggesting that electrons percolate through the films via electron exchange between nanoparticles.

Bazito, Fernanda; O'Brien, Robert; Buttry, Daniel A.

2005-02-01T23:59:59.000Z

308

Development of (Mn,Co)3O4 Protection Layers for Ferritic Stainless Steel Interconnects  

DOE Green Energy (OSTI)

A spinel-based surface protection layer has been developed for alloy SOFC current collectors and bi-polar gas separators. The (Mn,Co)3O4 spinel with a nominal composition of Mn1.5Co1.5O4 demonstrates an excellent electrical conductivity and thermal expansion match to ferritic stainless steel interconnects. A slurry-coating technique provides a viable approach for fabricating protective layers of the spinel onto the steel interconnects. Thermally grown protection layers of Mn1.5Co1.5O4 have been found not only to significantly decrease the contact resistance between a LSF cathode and stainless steel interconnect, but also inhibits the sub-scale growth on the stainless steel. The combination of the inhibited sub-scale growth, good thermal expansion matching between the spinel and the stainless steel, and the closed-pore structure contribute to the excellent structural and thermomechanical stability of these spinel protection layers, which was verified by a long-term thermal-cycling test. The spinel protection layers can also act effectively to prevent outward diffusion of chromium from the interconnect alloy, preventing subsequent chromium migration into the cathode and contact materials. PNNL is currently engaged in studies intended to optimize the composition, microstructure, and fabrication procedure for the spinel protection layers.

Yang, Zhenguo; Simner, Steven P.; Singh, Prabhakar; Xia, Guanguang; Stevenson, Jeffry W.

2005-07-05T23:59:59.000Z

309

Investigation of the Charge Collection Efficiency of CdMnTe Radiation Detectors  

SciTech Connect

This paper presents the growth, fabrication and characterization of indium-doped cadmium manganese telluride (CdMnTe) crystals grown by the vertical Bridgman technique. The 10 x 10 x 1.9 mm{sup 3} samples have been fabricated, and the charge collection properties of the CdMnTe detectors have been measured. Alpha-particle spectroscopy measurements have yielded an average charge collection efficiency approaching 100%. Ion beam induced charge (IBIC) measurements have been performed by raster scanning focused 5.5 MeV {sup 4}He beams onto the detectors. Spatially resolved charge collection efficiency maps have been produced for a range of detector bias voltages. Inhomogeneities in the charge transport of the CdMnTe crystals have been associated with chains of Te inclusions within the detector bulk, and the reduction in charge collection efficiency in their locality has been quantified. It has been shown that the role of Te inclusions in degrading charge collection is reduced with increasing values of bias voltage. IBIC measurements for a range of low biases have highlighted the evolution of the charge collection uniformity across the detectors.

Bolotnikov A.; Rafiei, R.; Boardman, D.; Sarbutt, A.; Prokopovich, A.; Kim, K.; Reinhard, M.I.; James, R.B.

2012-06-01T23:59:59.000Z

310

Carriers-mediated ferromagnetic enhancement in Al-doped ZnMnO dilute magnetic semiconductors  

SciTech Connect

Nano-crystalline Zn{sub 0.95-x}Mn{sub 0.05}Al{sub x}O (x = 0, 0.05, 0.10) dilute magnetic semiconductors (DMS) were synthesized by sol-gel derived auto-combustion. X-ray diffraction (XRD) analysis shows that the samples have pure wurtzite structure typical of ZnO without the formation of secondary phases or impurity. Crystallite sizes were approximated by Scherrer formula while surface morphology and grain sizes were measured by field emission scanning electron microscopy. Incorporation of Mn and Al into the ZnO structure was confirmed by energy-dispersive X-ray analysis. Temperature dependent electrical resistivity measurements showed a decreasing trend with the doping of Al in ZnMnO, which is attributable to the enhancement of free carriers. Vibrating sample magnetometer studies confirmed the presence of ferromagnetic behavior at room temperature. The results indicate that Al doping results in significant variation in the concentration of free carriers and correspondingly the carrier-mediated magnetization and room temperature ferromagnetic behavior, showing promise for practical applications. We attribute the enhanced saturation magnetization and electrical conductivity to the exchange interaction mediated by free electrons.

Saleem, Murtaza [Centre of Excellence in Solid State Physics, University of the Punjab, Lahore-54590 (Pakistan); Siddiqi, Saadat A. [Centre of Excellence in Solid State Physics, University of the Punjab, Lahore-54590 (Pakistan); Interdisciplinary Research Centre in Biomedical Materials (IRCBM), COMSATS Institute of Information Technology, Defence Road, Off Raiwind Road, Lahore (Pakistan); Atiq, Shahid, E-mail: shahidatiqpasrur@yahoo.com [Centre of Excellence in Solid State Physics, University of the Punjab, Lahore-54590 (Pakistan); Anwar, M. Sabieh; Hussain, Irshad [School of Science and Engineering (SSE), Lahore University of Management Sciences (LUMS), Opposite Sector U, D.H.A. Lahore Cantt-54792 (Pakistan); Alam, Shahzad [Pakistan Council for Scientific and Industrial Research (PCSIR) Laboratories Complex, Lahore (Pakistan)

2011-11-15T23:59:59.000Z

311

Mn-doped Ga(As,P) and (Al,Ga)As ferromagnetic semiconductors: Electronic structure calculations  

E-Print Network (OSTI)

A remarkable progress towards functional ferromagnetic semiconductor materials for spintronics has been achieved in p-type (Ga,Mn)As. Robust hole-mediated ferromagnetism has, however, been observed also in other III-V hosts such as antimonides, GaP, or (Al,Ga)As, which opens a wide area of possibilities for optimizing the host composition towards higher ferromagnetic Curie temperatures. Here we explore theoretically hole-mediated ferromagnetism and Mn incorporation in Ga(As,P) and (Al,Ga)As ternary hosts. While alloying (Ga,Mn)As with Al has only a small effect on the Curie temperature we predict a sizable enhancement of Curie temperatures in the smaller lattice constant Ga(As,P) hosts. Mn-doped Ga(As,P) is also favorable, as compared to (Al,Ga)As, with respect to the formation of carrier and moment compensating interstitial Mn impurities. In (Ga,Mn) (As,P) we find a marked decrease of the partial concentration of these detrimental impurities with increasing P content.

Masek, J.; Kudrnovsky, J.; Maca, F.; Sinova, Jairo; MacDonald, A. H.; Campion, R. P.; Gallagher, B. L.; Jungwirth, T.

2007-01-01T23:59:59.000Z

312

Fischer Tropsch synthesis : influence of Mn on the carburization rates and activities of Fe-based catalysts by TPR-EXAFS/XANES and catalyst testing.  

Science Conference Proceedings (OSTI)

Fe-based catalysts containing different amounts of Mn were tested for Fischer-Tropsch synthesis using a stirred tank reactor at 270 C, 1.21 MPa, and H{sub 2}:CO = 0.7. Catalyst activation by carburization with 10% CO/He was followed by Temperature Programmed Reduction/X-ray Absorption Spectroscopy (TPR-EXAFS/XANES) from room temperature to 300 C. {gamma}-Fe{sub 2}O{sub 3} was converted into iron carbides, whereas MnO{sub x} was reduced to oxygen deficient MnO. Mn hindered Fe carburization, such that the carburized catalyst displayed higher Fe{sub 3}O{sub 4} content than the catalyst without Mn. EXAFS fitting indicates that the carburized catalyst contained a mixture of Hgg carbide, Fe{sub 3}O{sub 4}, and Mn oxides. Increasing Mn content led to higher CH{sub 4} and light product selectivities, and lower light olefin selectivities. Higher and stable conversions were obtained with a catalyst containing an almost equimolar Fe/Mn ratio relative to the catalyst without Mn. Selectivity trends are attributed to the higher WGS rates observed on the FeMn catalysts, consistent with the structural differences observed.

Ribeiro, M. C.; Jacobs, G.; Pendyala, R.; Davis, B. H.; Cronauer, D. C.; Kropf, A. J.; Marshall, C. L. (Chemical Sciences and Engineering Division); (Univ. of Kentucky)

2011-03-24T23:59:59.000Z

313

Ab initio calculations and synthesis of the off-stoichiometric half-Heusler phase Ni{sub 1-x}Mn{sub 1+x}Sb  

SciTech Connect

We perform a combined theoretical and experimental study of the phase stability and magnetism of the off-stoichiometric Ni{sub 1-x}Mn{sub 1+x}Sb in the half-Heusler crystal phase. Our work is motivated by the need for strategies to engineer the magnetism of potentially half-metallic materials, such as NiMnSb, for improved performance at elevated temperatures. By means of ab initio calculations we investigate Ni{sub 1-x}Mn{sub 1+x}Sb over the whole composition range 0{<=}x{<=}1 of Ni replacing Mn and show that at relevant temperatures, the half-Heusler phase should be thermodynamically stable up to at least x=0.20 with respect to the competing C38 structure of Mn{sub 2}Sb. Furthermore we find that half-Heusler Ni{sub 1-x}Mn{sub 1+x}Sb retains half-metallic band structure over the whole concentration range and that the magnetic moments of substitutional Mn{sub Ni} atoms display magnetic exchange interactions an order of magnitude larger than the Ni-Mn interaction in NiMnSb. We also demonstrate experimentally that the alloys indeed can be created by synthesizing off-stoichiometric Ni{sub 1-x}Mn{sub 1+x}Sb films on MgO substrates by means of magnetron sputtering.

Ekholm, M.; Larsson, P.; Alling, B.; Helmersson, U.; Abrikosov, I. A. [Department of Physics, Chemistry and Biology (IFM), Linkoeping University, SE-58183 Linkoeping (Sweden)

2010-11-15T23:59:59.000Z

314

Why MnIn{sub 2}O{sub 4} spinel is not a transparent conducting oxide?  

SciTech Connect

The title compound has been synthesized by a citrate technique. The crystal structure has been investigated at room temperature from high-resolution neutron powder diffraction (NPD) data. It crystallizes in a cubic spinel structure, space group Fd3-bar m, Z=8, with a=9.0008(1) A at 295 K. It exhibits a crystallographic formula (Mn{sub 0.924(2)}In{sub 0.076(2)}){sub 8a}(In{sub 1.804(2)}Mn{sub 0.196(2)}){sub 16d}O{sub 4}, where 8a and 16d stand for the tetrahedral and octahedral sites of the spinel structure, respectively, with a slight degree of inversion, {lambda}=0.08. MnIn{sub 2}O{sub 4} shows antiferromagnetic interactions below T{sub N} Almost-Equal-To 40 K, due to the statistical distribution of Mn ions over the two available sites. Unlike the related MgIn{sub 2}O{sub 4} and CdIn{sub 2}O{sub 4} spinels, well known as transparent conducting oxides, MnIn{sub 2}O{sub 4} is not transparent and shows a poor conductivity ({sigma}=0.38 S cm{sup -1} at 1123 K): the presence of Mn ions, able to adopt mixed valence states, localizes the charges that, otherwise, would be delocalized in the spinel conduction band. - Graphical Abstract: From NPD data the crystallographic formula (Mn{sub 0.924(2)}In{sub 0.076(2)}){sub 8a}(In{sub 1.804(2)}Mn{sub 0.196(2)}){sub 16d}O{sub 4}, shows a slight degree of inversion, {lambda}=0.08 and a certain In deficiency. The presence of Mn ions, able to adopt mixed oxidation states, localize the charges that, otherwise, would be delocalized in the spinel conduction band; the presence of localized Mn{sup 2+} and Mn{sup 3+} ions provides the characteristic brown color. Highlights: Black-Right-Pointing-Pointer Accurate structural determination from NPD data: inversion degree (8%), and In deficiency. Black-Right-Pointing-Pointer Bond-valence indicates Mn{sup 2+}-Mn{sup 3+} ions; edge-sharing octahedra contain 90% In{sup 3+}+10% Mn{sup 3+} cations. Black-Right-Pointing-Pointer Conductivity several orders of magnitude lower than those of MgIn{sub 2}O{sub 4} or CdIn{sub 2}O{sub 4}. Black-Right-Pointing-Pointer Variability of Mn oxidation states cancels any electron-doping effect, emptying conduction band of mobile charge carriers. Black-Right-Pointing-Pointer Curie-Weiss behavior confirming the determined charge distribution.

Martinez-Lope, M.J. [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco E-28049 Madrid (Spain); Retuerto, M. [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco E-28049 Madrid (Spain); Department of Chemistry, Rutgers State University of New Jersey, Piscataway, NJ 08854-8087 (United States); Calle, C. de la [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco E-28049 Madrid (Spain); Porcher, Florence [Laboratoire Leon Brillouin, CEA/Saclay, 91191 Gif Sur Ivette Cedex, France. (France); Alonso, J.A., E-mail: ja.alonso@icmm.csic.es [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco E-28049 Madrid (Spain)

2012-03-15T23:59:59.000Z

315

LOW-TEMPERATURE ION TRAP STUDIES OF N{sup +}({sup 3} P{sub ja} ) + H{sub 2}(j) {yields} NH{sup +} + H  

SciTech Connect

Using a low-temperature 22-pole ion trap apparatus, detailed measurements for the title reaction have been performed between 10 K and 100 K in order to get some state specific information about this fundamental hydrogen abstraction process. The relative population of the two lowest H{sub 2} rotational states, j = 0 and 1, has been varied systematically. NH{sup +} formation is nearly thermo-neutral; however, to date, the energetics are not known with the accuracy required for low-temperature astrochemistry. Additional complications arise from the fact that, so far, there is no reliable theoretical or experimental information on how the reactivity of the N{sup +} ion depends on its fine-structure (FS) state {sup 3} P{sub ja} . Since in the present trapping experiment, thermalization of the initially hot FS population competes with hydrogen abstraction, the evaluation of the decay of N{sup +} ions over long storage times and at various He and H{sub 2} gas densities provides information on these processes. First assuming strict adiabatic behavior, a set of state specific rate coefficients is derived from the measured thermal rate coefficients. In addition, by recording the disappearance of the N{sup +} ions over several orders of magnitude, information on nonadiabatic transitions is extracted including FS-changing collisions.

Zymak, I.; Hejduk, M.; Mulin, D.; Plasil, R.; Glosik, J.; Gerlich, D. [Faculty of Mathematics and Physics, Charles University, Prague (Czech Republic)

2013-05-01T23:59:59.000Z

316

Imaging ion-molecule reactions: Charge transfer and C-N bond formation in the C{sup +}+ NH{sub 3} system  

Science Conference Proceedings (OSTI)

The velocity mapping ion imaging method is applied to the ion-molecule reactions occurring between C{sup +} and NH{sub 3}. The velocity space images are collected over the relative collision energy range from 1.5 to 3.3 eV, allowing both product kinetic energy distributions and angular distributions to be obtained from the data. The charge transfer process appears to be direct, dominated by long-range electron transfer that results in minimal deflection of the products. The product kinetic energy distributions are consistent with a process dominated by energy resonance. The kinetic energy distributions for C-N bond formation appear to scale with the total available energy, providing strong evidence that energy in the [CNH{sub 3}]{sup +} precursor to products is distributed statistically. The angular distributions for C-N bond formation show pronounced forward-backward symmetry, as expected for a complex that resembles a prolate symmetric top decaying along its symmetry axis.

Pei, Linsen; Farrar, James M. [Department of Chemistry, University of Rochester, Rochester, New York 14627 (United States)

2012-05-28T23:59:59.000Z

317

Detailed modeling and laser-induced fluorescence imaging of nitric oxide in a NH(i)-seeded non-premixed methane/air flame  

Science Conference Proceedings (OSTI)

In this paper we study the formation of NO in laminar, nitrogen diluted methane diffusion flames that are seeded with ammonia in the fuel stream. We have performed numerical simulations with detailed chemistry as well as laser-induced fluorescence imaging measurements for a range of ammonia injection rates. For comparison with the experimental data, synthetic LIF images are calculated based on the numerical data accounting for temperature and fluorescence quenching effects. We demonstrate good agreement between measurements and computations. The LIF corrections inferred from the simulation are then used to calculate absolute NO mole fractions from the measured signal.The NO formation in both doped and undoped flames occurs in the flame sheet. In the undoped flame, four different mechanisms including thermal and prompt NO appear to contribute to NO formation. As the NH3 seeding level increases, fuel-NO becomes the dominant mechanism and N2 shifts from being a net reactant to being a net product. Nitric oxide in the undoped flame as well as in the core region of the doped flames are underpredicted by the model; we attribute this mainly to inaccuracies in the NO recycling chemistry on the fuel-rich side of the flame sheet.

Bell, John B.; Day, Marcus S.; Grcar, Joseph F.; Bessler, Wolfgang G.; Schulz, Christof; Glarborg, Peter; Jensen, Anker D.

2001-12-14T23:59:59.000Z

318

Make Checks Payable to the 4-H Foundation of New Hampshire. For more information contact Rhiannon Beauregard at Rhiannon.Beauergard@unh.edu or (603) 862-2188. All of this information can be found at the NH 4-H State Horse Show Website  

E-Print Network (OSTI)

Beauregard at Rhiannon.Beauergard@unh.edu or (603) 862-2188. All of this information can be found at the NH 4 Foundation of New Hampshire. For more information contact Rhiannon Beauregard at Rhiannon Exposition. Please notify Rhiannon Beauregard, NH 4-H Animal and Agricultural Science Education Coordinator

New Hampshire, University of

319

In situ XRD Studies of Li-ion Cells with Mixed LiMn2O4 and LiCo1/3Ni1/3Mn1/3O2 Composite Cathode  

Science Conference Proceedings (OSTI)

The structural changes of the composite cathode made by mixing spinel LiMn2O4 and layered LiNi1/3Co1/3Mn1/3O2 in 1:1 wt% in both Li-half and Li-ion cells during charge/discharge are studied by in situ XRD. During the first charge up to {approx}5.2 V vs. Li/Li+, the in situ XRD spectra for the composite cathode in the Li-half cell track the structural changes of each component. At the early stage of charge, the lithium extraction takes place in the LiNi1/3Co1/3Mn1/3O2 component only. When the cell voltage reaches at {approx}4.0 V vs. Li/Li+, lithium extraction from the spinel LiMn2O4 component starts and becomes the major contributor for the cell capacity due to the higher rate capability of LiMn2O4. When the voltage passed 4.3 V, the major structural changes are from the LiNi1/3Co1/3Mn1/3O2 component, while the LiMn2O4 component is almost unchanged. In the Li-ion cell using a MCMB anode and a composite cathode cycled between 2.5 V and 4.2 V, the structural changes are dominated by the spinel LiMn2O4 component, with much less changes in the layered LiNi1/3Co1/3Mn1/3O2 component, comparing with the Li-half cell results. These results give us valuable information about the structural changes relating to the contributions of each individual component to the cell capacity at certain charge/discharge state, which are helpful in designing and optimizing the composite cathode using spinel- and layered-type materials for Li-ion battery research.

Nam, K.; Yoon, W; Shin, H; Chung, K; Choi, S; Yang, X

2009-01-01T23:59:59.000Z

320

NH_50m_Wind  

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UnitedStatesWindHighResolutionNewHampshireWindHighResolution.zip> Description: Abstract: Annual average wind resource potential for the state of New...

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321

Probing The Electrode/Electrolyte Interface in The Lithium Excess Layered Oxide Li1.2Ni0.2Mn0.6O2  

Science Conference Proceedings (OSTI)

A detailed surface investigation of the lithium-excess nickel manganese layered oxide Li1.2Ni0.2Mn0.6O2 structure was carried out using x-ray photoelectron spectroscopy (XPS), total electron yield and transmission x-ray absorption spectroscopy (XAS), and electron energy loss spectroscopy (EELS) during the first two electrochemical cycles. All spectroscopy techniques consistently showed the presence of Mn4+ in the pristine material and a surprising reduction of Mn at the voltage plateau during the first charge. The Mn reduction is accompanied by the oxygen loss revealed by EELS. Upon the first discharge, the Mn at the surface never fully returns back to Mn4+. The electrode/electrolyte interface of this compound consists of the reduced Mn at the crystalline defect-spinel inner layer and an oxidized Mn species simultaneously with the presence of a superoxide species in amorphous outer layer. This proposed model signifies that oxygen vacancy formation and lithium removal result in electrolyte decomposition and superoxide formation, leading to Mn activation/dissolution and surface layer-spinel phase transformation. The results also indicate that the role of oxygen is complex and significant in contributing to the extra capacity of this class of high energy density cathode materials.

Carroll, Kyler J [University of California, San Diego; Qian, Danna [University of California, San Diego; Fell, Chris [University of Florida, Gainesville; Calvin, Scott [Sarah Lawrence College; Veith, Gabriel M [ORNL; Chi, Miaofang [ORNL; Dudney, Nancy J [ORNL; Meng, Ying Shirley [University of California, San Diego

2013-01-01T23:59:59.000Z

322

Novel synthesis process and structure refinements of Li{sub 4}Mn{sub 5}O{sub 12} for rechargeable lithium batteries  

DOE Green Energy (OSTI)

Well crystallized Li4Mn5O12 was prepared from LiOAc-Mn(NO3)2 under flowing oxygen. Rietveld refinement with XRD and neutron powder diffraction indicated that Li4Mn5O12 has cubic spinel structure in which the Li ions occupy both the tetrahedral sites 8a and part of the octahedral sites 16d but not the 16c sites, while all the Mn ions occupy the 16d sites of the space group Fd{bar 3}m. The lattice parameter was found to be sensitive to synthesis temperature owing to variation in Mn valence. Sample prepared at 500 C showed better electrode performance: a rechargeable capacity of 135 mAh/g for the cell Li/Li4Mn5O12 at cell voltages 2.5-3.6 V. It is found that Mn oxidation state in Li4Mn5O12 has a strong effect on electrode performance of Li/Li4Mn5O12 cell.

Takada, Toshimi; Hayakawa, Hiroshi; Akiba, Etsuo [National Inst. of Materials and Chemical Research, Tsukuba, Ibaraki (Japan); Izumi, Fujio [National Inst. for Research in Inorganic Materials, Tsukuba (Japan); Chakoumakos, B.C. [Oak Ridge National Lab., TN (United States)

1996-12-31T23:59:59.000Z

323

In situ and ex situ spectroelectrochemical and X-ray absorption studies on rechargeable, chemically-modified and other MnO{sub 2} materials  

DOE Green Energy (OSTI)

A combined series of in situ and ex situ UV spectroelectrochemical and X-ray absorption studies have been made on MnO{sub 2}, chemically-modified by small amounts of Bi(III), and comparatively on other MnO{sub 2} materials such as a blank (Bi-free) and {gamma}-MnO{sub 2}. These procedures are applied in order to follow the oxidation-states of Bi and of Mn during the course of discharge and recharge of MnO{sub 2} as a battery cathode material, and the extents of rechargeability that can be achieved with such materials. Presence of Bi appears to provide a preferred ``heterogeneous`` discharge/recharge pathway involving a soluble Mn(III) intermediate, over the alternative ``electron-proton`` hopping, solid-state mechanism. From XAS results, it is concluded that presence of Bi, although not affecting the O-coordination, does influence the Mn-Mn coordination, determining the way the MnO{sub 2} coordination octahedra are connected.

Conway, B.E.; Qu, D.; McBreen, J. [Ottawa Univ., ON (Canada). Dept. of Chemistry]|[Brookhaven National Lab., Upton, NY (United States)

1992-12-31T23:59:59.000Z

324

Effect of Mn Substitution for Multiferroic BiFeO3 Probed by High-Resolution Soft-X-Ray Spectroscopy  

E-Print Network (OSTI)

sensor devices. low electrical resistivity, which affectstemperature. The low electrical resistivity of BF thin filmsFurthermore, the electrical resistivity also increases by Mn

Hattori, T.

2008-01-01T23:59:59.000Z

325

Gas Prices  

NLE Websites -- All DOE Office Websites (Extended Search)

Prices Gasoline Prices for U.S. Cities Click on the map to view gas prices for cities in your state. AK VT ME NH NH MA MA RI CT CT DC NJ DE DE NY WV VA NC SC FL GA AL MS TN KY IN...

326

Magnetic and electrical properties of layered magnets Tl(Cr,Mn,Co)Se{sub 2}  

Science Conference Proceedings (OSTI)

Tl(Cr,Mn,Co)Se{sub 2} crystals were synthesized at T {approx} 1050 K. X-ray diffraction analysis showed that TlCrSe{sub 2}, TlMnSe{sub 2}, and TlCoSe{sub 2} compounds crystallize in the hexagonal crystal system with the lattice parameters: a = 3.6999 A, c = 22.6901 A, c/a {approx} 6.133, z = 3, {rho}{sub x} = 6.209 g/cm{sup 3}; a = 6.53 A, c = 23.96 A, c/a {approx} 3.669, z = 8, {rho}{sub x} = 6.71 g/cm{sup 3}; and a = 3.747 A, c = 22.772 A, c/a {approx} 6.077, z = 3, {rho}{sub x} = 7.577 g/cm{sup 3}, respectively. Magnetic and electrical studies in the temperature range from 80-400 K showed that TlCrSe{sub 2} is a semiconductor ferromagnet, TlMnSe{sub 2} is a semiconductor antiferromagnet, and TlCoSe{sub 2} is a ferrimagnet with a conductivity characteristic of metals. A rather large deviation in the experimental effective magnetic moment for TlCrSe{sub 2} (3.05 {mu}B) from the theoretical value (3.85 {mu}B) is attributed to two-dimensional magnetic ordering in the paramagnetic region of the noticeably layered ferromagnet TlCrSe{sub 2}. In TlCrSe{sub 2}, a correlation between magnetic and electrical properties was detected.

Veliyev, R. G.; Sadikhov, R. Z.; Kerimova, E. M., E-mail: ekerimova@physics.ab.az; Asadov, Yu. G.; Jabbarov, A. I. [National Academy of Sciences of Azerbaijan, Institute of Physics (Azerbaijan)

2009-02-15T23:59:59.000Z

327

Pressure and field tuning the magnetostructural phases of Mn3O4: Raman scattering and x-ray diffraction studies  

Science Conference Proceedings (OSTI)

We present temperature-, magnetic-field-, and pressure-dependent Raman scattering studies of single crystal Mn{sub 3}O{sub 4}, combined with temperature- and field-dependent x-ray diffraction studies, revealing the novel magnetostructural phases in Mn{sub 3}O{sub 4}. Our temperature-dependent studies showed that the commensurate magnetic transition at T{sub 2} = 33K in the binary spinel Mn{sub 3}O{sub 4} is associated with a structural transition from tetragonal to orthorhombic structures. Field-dependent studies showed that the onset and nature of this structural transition can be controlled with an applied magnetic field, and revealed evidence for a field-tuned quantum phase transition to a tetragonal spin-disordered phase for H {parallel} [1{bar 1}0]. Pressure-dependent Raman measurements showed that the magnetic easy axis direction in Mn{sub 3}O{sub 4} can be controlled - and the ferrimagnetic transition temperature increased - with applied pressure. Finally, combined pressure- and magnetic-field-tuned Raman measurements revealed a rich magnetostructural phase diagram - including a pressure- and field-induced magnetically frustrated tetragonal phase in the PH phase diagram - that can be generated in Mn{sub 3}O{sub 4} with applied pressure and magnetic field.

Kim, M.; Nelson, C.; Chen, X.M.; Wang, X.; Budakian, R.; Abbamonte, P. & Cooper, S.L.

2011-11-18T23:59:59.000Z

328

Spinel LiMn(2)O(4)/Reduced Graphene Oxide Hybrid for High Rate Lithium Ion Batteries  

DOE Green Energy (OSTI)

A well-crystallized and nano-sized spinel LiMn{sub 2}O{sub 4}/reduced graphene oxide hybrid cathode material for high rate lithium-ion batteries has been successfully synthesized via a microwave-assisted hydrothermal method at 200 C for 30 min without any post heat-treatment. The nano-sized LiMn{sub 2}O{sub 4} particles were evenly dispersed on the reduced graphene oxide template without agglomeration, which allows the inherent high active surface area of individual LiMn{sub 2}O{sub 4} nanoparticles in the hybrid. These unique structural and morphological properties of LiMn{sub 2}O{sub 4} on the highly conductive reduced graphene oxide sheets in the hybrid enable achieving the high specific capacity, an excellent high rate capability and stable cycling performance. An analysis of the cyclic voltammogram data revealed that a large surface charge storage contribution of the LiMn{sub 2}O{sub 4}/reduced graphene oxide hybrid plays an important role in achieving faster charge/discharge.

Bak, S.M.; Nam, K.; Lee, C.-W.; Kim, K.-H.; Jung, H.-C.; Yang, X-Q.; Kim, K.-B.

2011-10-04T23:59:59.000Z

329

Investigation of thermal, mechanical and magnetic behaviors of the Cu-11%Al alloy with Ag and Mn additions  

SciTech Connect

The investigation of thermal, mechanical and magnetic behaviors of the Cu-11%Al, Cu-11%Al-3%Ag, Cu-11%Al-10%Mn and Cu-11%Al-10%Mn-3%Ag alloys was made using microhardness measurements, differential scanning calorimetry, X-ray diffractometry, scanning electron microscopy, energy dispersion X-ray spectroscopy and magnetic moment change with applied field measurement. The results indicated that the Mn addition changes the phase stability range, the microhardness values and makes undetectable the eutectoid reaction in annealed Cu-11%Al and Cu-11%Al-3%Ag alloys while the presence of Ag does not modify the phase transformation sequence neither microhardness values of the annealed Cu-11%Al and Cu-11%Al-10%Mn alloys, but it increases the magnetic moment of this latter at about 2.7 times and decreases the rates of eutectoid and peritectoid reactions of the former. - Highlights: Black-Right-Pointing-Pointer The microstructure of Cu-Al alloy is modified in the Ag presence. Black-Right-Pointing-Pointer ({alpha} + {gamma}) phase is stabilized down to room temperature when Ag is added to Cu-Al alloy. Black-Right-Pointing-Pointer Ag-rich phase modifies the magnetic characteristics of Cu-Al-Mn alloy.

Silva, R.A.G., E-mail: galdino.ricardo@gmail.com [Departamento de Ciencias Exatas e da Terra-UNIFESP, Diadema-SP (Brazil)] [Departamento de Ciencias Exatas e da Terra-UNIFESP, Diadema-SP (Brazil); Paganotti, A.; Gama, S. [Departamento de Ciencias Exatas e da Terra-UNIFESP, Diadema-SP (Brazil)] [Departamento de Ciencias Exatas e da Terra-UNIFESP, Diadema-SP (Brazil); Adorno, A.T.; Carvalho, T.M.; Santos, C.M.A. [Instituto de Quimica - UNESP, Araraquara-SP (Brazil)] [Instituto de Quimica - UNESP, Araraquara-SP (Brazil)

2013-01-15T23:59:59.000Z

330

Synthesis and Electrochemical Characterization of M2Mn3O8 (M=Ca,Cu) Compounds and Derivatives  

DOE Green Energy (OSTI)

M{sub 2}Mn{sub 3}O{sub 8} (M=Ca{sup 2+}, Cu{sup 2+}) compounds were synthesized and characterized in lithium cells. The M{sup 2+} cations, which reside in the van der Waal's gaps between adjacent sheets of Mn{sub 3}O{sub 8}{sup 4-}, may be replaced chemically (by ion-exchange) or electrochemically with Li. More than 7 Li{sup +}/Cu{sub 2}Mn{sub 3}O{sub 8} may be inserted electrochemically, with concomitant reduction of Cu{sup 2+} to Cu metal, but less Li can be inserted into Ca{sub 2}Mn{sub 3}O{sub 8}. In the case of Cu{sup 2+}, this process is partially reversible when the cell is charged above 3.5 V vs. Li, but intercalation of Cu{sup +} rather than Cu{sup 2+} and Li{sup +}/Cu{sup +} exchange occurs during the subsequent discharge. If the cell potential is kept below 3.4 V, the Li in excess of 4Li{sup +}/Cu{sub 2}Mn{sub 3}O{sub 8} can be cycled reversibly. The unusual mobility of +2 cations in a layered structure has important implications both for the design of cathodes for Li batteries and for new systems that could be based on M{sup 2+} intercalation compounds.

Park, Yong Joon; Doeff, Marca M.

2005-08-25T23:59:59.000Z

331

Neutron scattering study of MnSi proving no exchange hole  

SciTech Connect

Neutron scattering experiments have been performed in MnSi below T/sub c/ with the double-axis powder scattering technique using unpolarized neutrons, and also with the polarization analysis technique. The magnetic scattering intensity has not shown any anomaly around q = 0.5 A/sup -1/, in contrast to the previous results of Ziebeck et al. who found a large intensity peak at this momentum transfer. Thus the hypothesis of Ziebeck et al. of observing an Exchange Hole is excluded.

Uemura, Y.J.; Majkrzak, C.F.; Shirane, G.; Ishikawa, Y.

1983-01-01T23:59:59.000Z

332

Tiling theory applied to the surface structure of icosahedral AlPdMn quasicrystals  

E-Print Network (OSTI)

Surfaces in i-Al68Pd23Mn9 as observed with STM and LEED experiments show atomic terraces in a Fibonacci spacing. We analyze them in a bulk tiling model due to Elser which incorporates many experimental data. The model has dodecahedral Bergman clusters within an icosahedral tiling T^*(2F) and is projected from the 6D face-centered hypercubic lattice. We derive the occurrence and Fibonacci spacing of atomic planes perpendicular to any 5fold axis, compute the variation of planar atomic densities, and determine the (auto-) correlation functions. Upon interpreting the planes as terraces at the surface we find quantitative agreement with the STM experiments.

Peter Kramer; Zorka Papadopolos; Harald Teuscher

1999-03-04T23:59:59.000Z

333

Enhancement of spin-asymmetry by L2{sub 1}-ordering in Co{sub 2}MnSi/Cr/Co{sub 2}MnSi current-perpendicular-to-plane magnetoresistance devices  

SciTech Connect

Co{sub 2}MnSi/Cr/Co{sub 2}MnSi (001)-fully epitaxial current-perpendicular-to-plane giant magnetoresistance (CPP-GMR) devices were fabricated via an UHV magnetron sputtering system. The relationship between the degree of chemical ordering in Co{sub 2}MnSi (CMS) and the CPP-GMR characteristics was investigated systematically against the annealing temperature of the devices. X-ray diffraction profiles and reflection high-energy electron diffraction images indicated that annealing improved L2{sub 1}-ordering. The MR ratio also increased upon annealing and the maximum MR ratio of 5.2% and {delta}RA of 6.5 m{omega} {mu}m{sup 2} were achieved by annealing at 400 deg. C. These results indicate that promoting the degree of L2{sub 1}-ordering in CMS enhances the bulk and/or interface spin-asymmetry coefficients.

Sakuraba, Y.; Iwase, T.; Saito, K.; Mitani, S.; Takanashi, K. [Institute for Materials Research, Tohoku University, Katahira 2-1-1, Aoba-ku, Sendai 980-8577 (Japan)

2009-01-05T23:59:59.000Z

334

MN Workshop  

Science Conference Proceedings (OSTI)

Page 1. NIST Special Publication 1093 Mass Notification Messages: Workshop Proceedings Erica D. Kuligowski Richard ...

2009-03-24T23:59:59.000Z

335

Low Dose Radiation Research Program: Regulation of NF-kB and MnSOD in Low  

NLE Websites -- All DOE Office Websites (Extended Search)

NF-kB and MnSOD in Low Dose Radiation-Induced Adaptive NF-kB and MnSOD in Low Dose Radiation-Induced Adaptive Responses in Mouse and Human Skin Cells Jian Jian Li School of Health Sciences, Purdue University West Lafayette, Indiana Why this Project? To determine if low dose ionizing radiation-induced adaptive responses in skin cells are mediated by activation of signaling networks. Project Goals To evaluate the signaling networks involving transcription factor NF-kB and the mitochondrial antioxidant protein MnSOD. To determine if NF-kB is activated by low dose radiation in vivo. To determine if NF-kB activation is critical in the pathways that produce adaptive responses. Experimental Approach Cells transfected with NF-kB luciferase responder genes will be used to define a dose-response relationship for activation of the NF-kB gene. NF-kB

336

Microstructure and Magnetic Properties of PrMnO{sub 3} Bulk and Thin Film  

Science Conference Proceedings (OSTI)

Perovskite PrMnO{sub 3}(PMO) had been prepared in bulk by solid state reaction and thin films on corning glass, fused silica and MgO (100) glass substrate by pulsed laser deposition technique. SEM micrographs show that grains with size 2{approx}3 {mu}m is observed in bulk PMO while thin films PMO show strongly connected grain structure with particle size that not larger than 100 nm. X-ray diffraction analysis shows that all samples are in single phase with orthorhombic crystal structure. Bulk PMO sample had lattice strain of 0.134% which is the lowest value among others. However, larger lattice strain was observed in thin film samples due to lattice mismatch between film-substrate and caused the MnO{sub 6} to deform. All samples shown paramagnetic or antiferromagnetic behavior, enhancement in magnetization value occurred for all PMO grew as film. We believe that larger lattice strain favor the grain growth of PMO towards more order phase. In summary, formation of structure and microstructure of thin film PMO depends on type of substrate used and it affect the magnetic property.

Lim, K. P.; Halim, S. A.; Chen, S. K.; Ng, S. W.; Wong, J. K.; Gan, H. M. Albert [Department of Physics, Faculty of Science, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor (Malaysia); Woon, H. S. [College of Engineering, Universiti Tenaga Nasional, Jalan IKRAM-UNITEN, 43000 Kajang, Selangor (Malaysia)

2011-03-30T23:59:59.000Z

337

Room temperature ferromagnetism in Mn, Ni and Co ions doped Cu{sub 2}O nanorods  

SciTech Connect

Here we report the synthesis and characterization of Cu{sub 2}O nanorods doped with Mn, Ni and Co transition metal ions and the study of their magnetic properties. Synthesis of the nanorods was carried out by the modified polyol method. Powder X-ray diffraction patterns clearly showed them to be polycrystalline single phase material. They exhibited ferromagnetic behavior at room temperature, however no such behavior was observed for the reference undoped sample, which indicated that unintentionally introduced magnetic impurities were not responsible for the observed phenomenon. Ferromagnetic behavior was found to be dependent on the dopant concentration and increased consistently with its increment in the material. The total magnetic moments contribution was calculated for the dopant concentration and was found to be insignificant to account for the observed ferromagnetism, therefore it was suggested that ferromagnetism could have conjured up from the induced magnetic moment in the defects created as cation vacancies in the material. The presence of the defects was supported by the room temperature photoluminescence study which showed that intensity of the peaks was dependent on the dopant concentration and increased consistently with it. There was strong correlation between the magnitude of the photoluminescence peak and the observed ferromagnetic property in the doped samples. -- Graphical Abstract: Room temperature ferromagnetism was observed in the Cu{sub 2}O nanorods doped with Mn, Ni and Co ions. The origin seems to be the defects of cation vacancies created by the dopant ions. Display Omitted

Ahmed, Asar [Department of Chemistry, SL-214, Southern Lab, Indian Institute of Technology Kanpur, Kanpur, Uttar Pradesh (India); Gajbhiye, Namdeo S., E-mail: nsg@iitk.ac.i [Department of Chemistry, SL-214, Southern Lab, Indian Institute of Technology Kanpur, Kanpur, Uttar Pradesh (India)

2010-12-15T23:59:59.000Z

338

Exact Enumeration of the Phase Space of an Ising Model of Ni2MnGa  

Science Conference Proceedings (OSTI)

Exact evaluations of partition functions are generally prohibitively expensive due to exponential growth of phase space with the number of degrees of freedom. For an Ising model with sites the number of possible states is requiring the use of better scaling methods such as importance sampling Monte-Carlo calculations for all but the smallest systems. Yet the ability to obtain exact solutions for as large as possible systems can provide important benchmark results and opportunities for unobscured insight into the underlying physicsofthesystem.HerewepresentanIsingmodelforthemagneticsublatticesoftheimportantmagneto-caloricmaterialNi MnGa and use an exact enumeration algorithm to calculate the number of states for each energy and sublattice magne- tizations and . This allows the efficient calculation of the partition function and derived thermodynamic quantities such as specific heat and susceptibility. Utilizing the jaguarpf system at Oak Ridge we are able to calculate for systems of up to48sites,whichprovidesimportantinsightintothemechanismforthelargemagnet-caloriceffectinNi MnGaaswellasanimportant benchmark for Monte-Carlo (esp. Wang-Landau method).

Eisenbach, Markus [ORNL; Brown, Greg [ORNL; Rusanu, Aurelian [ORNL; Odbadrakh, Khorgolkhuu [ORNL; Nicholson, Don M [ORNL; McCarthy, Carrie V. [University of Georgia, Athens, GA

2013-01-01T23:59:59.000Z

339

Magnetic phase diagram of disordered Ni-Mn near the multicritical point  

Science Conference Proceedings (OSTI)

From detailed magnetization data taken under various field-cooling conditions, the magnetic phase diagram of temperature versus composition is determined for disordered Ni-Mn of Mn concentration (x) near 25 at. %. With increasing x, the ferromagnetic Curie-point (T/sub c/) line descends and meets the ascending line for the spin-glass reentrance temperature (T/sub f//sub g/) at a multicritical point (MCP) located at x = 23.9, T = 102 K, from which the spin-glass freezing-temperature (T/sub g/) line emerges and reaches a maximum at higher x. The reentrant spin-glass (SG) ordering is accompanied by a net ferromagnetic (FM) moment, thus describing a mixed ferro-spin-glass (FSG) state, which is separated from the normal SG state by a boundary line that extends essentially vertically down in temperature from the MCP. Moreover, it is shown that the SG ordering of the FSG state probably persists into the FM regime above T/sub f//sub g/, where T/sub f//sub g/ (like T/sub g/) remains defined operationally by the appearance of irreversible and time-dependent magnetic effects.

Abdul-Razzaq, W.; Kouvel, J.S.

1987-02-01T23:59:59.000Z

340

Defect Levels of Indium-doped CdMnTe Crystals  

Science Conference Proceedings (OSTI)

Using photoluminescence (PL) and current deep-level transient spectroscopy (I-DLTS), we investigated the electronic defects of indium-doped detector-grade CdMnTe:In (CMT:In) crystals grown by the vertical Bridgman method. We similarly analyzed CdZnTe:In (CZT:In) and undoped CdMnTe (CMT) crystals grown under the amount of same level of excess Te and/or indium doping level to detail the fundamental properties of the electronic defect structure more readily. Extended defects, existing in all the samples, were revealed by synchrotron white beam x-ray diffraction topography and scanning electron microscopy. The electronic structure of CMT is very similar to that of CZT, with shallow traps, A-centers, Cd vacancies, deep levels, and Te antisites. The 1.1-eV deep level, revealed by PL in earlier studies of CZT and CdTe, were attributed to dislocation-induced defects. In our I-DLTS measurements, the 1.1-eV traps showed different activation energies with applied bias voltage and an exponential dependence on the trap-filling time, which are typical characteristics of dislocation-induced defects. We propose a new defect-trap model for indium-doped CMT crystals.

K Kim; A Bolotinikov; G Camarda; R Gul; A Hossain; G Yang; Y Cui; R James

2011-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "mn nh nj" from the National Library of EnergyBeta (NLEBeta).
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We encourage you to perform a real-time search of NLEBeta
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341

Tb0.5Bi0.5MnO3: New material. A DFT study  

Science Conference Proceedings (OSTI)

In the present work we have determined the band structure and the densities of states (DOS) of Tb0.5Bi0.5MnO3 in cubic phase using the density functional theory (DFT). The determination of the lattice constant was ... Keywords: 61.50.-f, 62.20.-x, 71.15.Nc, 71.20.-b, 71.55.Ht, 75.20.En, Band structure, DFT, Density of states, Magnetic properties, Mechanical and structural properties, Tb1-xBixMnO3

Miguel Grizalez; M. Jairo Arbey Rodrguez; Jess Heiras; P. Prieto

2008-03-01T23:59:59.000Z

342

Identification of Mn site in Pb(Zr,Ti)O{sub 3} by synchrotron x-ray absorption near-edge structure: Theory and experiment  

SciTech Connect

Synchrotron x-ray absorption near-edge structure (XANES) experiments are performed on Mn-doped PbZr{sub 1-x}Ti{sub x}O{sub 3} samples (PZT) and compared with first-principles XANES simulations. The features of the measured Mn K-edge XANES are consistent with the first-principles XANES of Mn on the Ti/Zr site and inconsistent with Mn on other sites. The clear agreement between measured and first-principles theoretical XANES spectra reported here is by far the strongest evidence of Mn substituting for Ti/Zr in PZT. This work illustrates that a first-principles supercell framework, which is popularly used to study impurities in crystals, can be used in conjunction with XANES measurement in order to identify an impurity structure with a high degree of confidence. This approach may thus be broadly applicable to study impurities in other crystals.

Limpijumnong, Sukit; Rujirawat, Saroj; Boonchun, Adisak; Smith, M. F.; Cherdhirunkorn, B. [National Synchrotron Research Center, Nakhon Ratchasima 30000, Thailand and School of Physics, Suranaree University of Technology, Nakhon Ratchasima 30000 (Thailand); National Synchrotron Research Center, Nakhon Ratchasima 30000 (Thailand); Department of Physics, Thammasat University, Patum Thani 12121 (Thailand)

2007-03-05T23:59:59.000Z

343

Radiation-induced instability of MnS precipitates and its possible consequences on irradiation-induced stress corrosion cracking of austenitic stainless steels  

SciTech Connect

Irradiation-assisted stress corrosion cracking (IASCC) is a significant materials issue for the light water reactor (LWR) industry and may also pose a problem for fusion power reactors that will use water as coolant. A new metallurgical process is proposed that involves the radiation-induced release into solution of minor impurity elements not usually thought to participate in IASCC. MnS-type precipitates, which contain most of the sulfur in stainless steels, are thought to be unstable under irradiation. First, Mn transmutes strongly to Fe in thermalized neutron spectra. Second, cascade-induced disordering and the inverse Kirkendall effect operating at the incoherent interfaces of MnS precipitates are thought to act as a pump to export Mn from the precipitate into the alloy matrix. Both of these processes will most likely allow sulfur, which is known to exert a deleterious influence on intergranular cracking, to re-enter the matrix. To test this hypothesis, compositions of MnS-type precipitates contained in several unirradiated and irradiated heats of Type 304, 316, and 348 stainless steels (SSs) were analyzed by Auger electron spectroscopy. Evidence is presented that shows a progressive compositional modification of MnS precipitates as exposure to neutrons increases in boiling water reactors. As the fluence increases, the Mn level in MnS decreases, whereas the Fe level increases. The S level also decreases relative to the combined level of Mn and Fe. MnS precipitates were also found to be a reservoir of other deleterious impurities such as F and O which could be also released due to radiation-induced instability of the precipitates.

Chung, H.M.; Sanecki, J.E. [Argonne National Lab., IL (United States); Garner, F.A. [Pacific Northwest National Lab., Richland, WA (United States)

1996-12-01T23:59:59.000Z

344

EXAFS and FT-IR Characterization of Mn and Li Promoted Titania-Supported Rh Catalysts for CO Hydrogenation  

DOE Green Energy (OSTI)

The effect of Li and Mn promoters on the structure and selectivity of supported Rh catalysts for CO hydrogenation reaction was examined. Infrared spectroscopy and X-ray absorption were used to investigate the adsorption of reactants and local structure of Rh. These techniques were used in combination with reactivity, H{sub 2} chemisorption, and temperature programmed studies to correlate structural characteristics with activity and selectivity during CO hydrogenation of unpromoted Rh/TiO{sub 2} and three promoted Rh catalysts: Rh-Li/TiO{sub 2}, Rh-Mn/TiO{sub 2}, and Rh-Li-Mn/TiO{sub 2}. The presence of a promoter slightly decreases the Rh clusters size; however, no evidence for an electronic effect induced by the presence of Li and Mn was found. Higher turnover frequencies were found for the promoted catalysts, which also showed the lower dispersion. The Li promoter introduces a weakened CO adsorption site that appears to enhance the selectivity to C{sub 2+} oxygenates. The selectivity to C{sub 2+} oxygenates varies inversely with the reducibility of Rh metal, that is, the lower the Rh reducibility, the higher the selectivity.

V Schwartz; A Campos; A Egbebi; J Spivey; S Overbury

2011-12-31T23:59:59.000Z

345

Observations on the oxidation of Mn-modified Ni-base Haynes 230 alloy under SOFC exposure conditions  

Science Conference Proceedings (OSTI)

The commercial Ni-base Haynes 230 alloy (Ni-Cr-Mo-W-Mn) was modified with two increased levels of Mn (1 and 2 wt per cent) and evaluated for its oxidation resistance under simulated SOFC interconnect exposure conditions. Oxidation rate, oxide morphology, oxide conductivity and thermal expansion were measured and compared with commercial Haynes 230. It was observed that additions of higher levels of Mn to the bulk alloy facilitated the formation of a bi-layered oxide scale that was comprised of an outer M3O4 (M=Mn, Cr, Ni) spinel-rich layer at the oxide gas interface over a Cr2O3-rich sub-layer at the metal oxide interface. The modified alloys showed higher oxidation rates and the formation of thicker oxide scales compared to the base alloy. The formation of a spinel-rich top layer improved the scale conductivity, especially during the early stages of the oxidation, but the higher scale growth rate resulted in an increase in the area-specific electrical resistance over time. Due to their face-centered cubic crystal structure, both commercial and modified alloys demonstrated a coefficient of thermal expansion that was higher than that of typical anode-supported and electrolyte-supported SOFCs.

Yang, Z Gary; Xia, Gordon; Stevenson, Jeffry W.; Singh, Prabhakar

2005-07-01T23:59:59.000Z

346

Magnetic properties of MnSb inclusions formed in GaSb matrix directly during molecular beam epitaxial growth  

Science Conference Proceedings (OSTI)

Despite of intensive search for the proper semiconductor base materials for spintronic devices working at room temperature no appropriate material based on ferromagnetic semiconductors has been found so far. We demonstrate that the phase segregated system with MnSb hexagonal inclusions inside the GaSb matrix, formed directly during the molecular beam epitaxial growth reveals the ferromagnetic properties at room temperature and is a good candidate for exploitation in spintronics. Furthermore, the MnSb inclusions with only one crystalline structure were identified in this GaMn:MnSb granular material. The SQUID magnetometry confirmed that this material exhibits ferromagnetic like behavior starting from helium up to room temperature. Moreover, the magnetic anisotropy was found which was present also at room temperature, and it was proved that by choosing a proper substrate it is possible to control the direction of easy axis of inclusions' magnetization moment between in-plane and out-of-plane; the latter is important in view of potential applications in spintronic devices.

Lawniczak-Jablonska, Krystyna; Wolska, Anna; Klepka, Marcin T.; Kret, Slawomir; Kurowska, Boguslawa; Kowalski, Bogdan J. [Institute of Physics PAS, al. Lotnikow 32/46, 02-668 Warsaw (Poland); Gosk, Jacek [Institute of Experimental Physics, University of Warsaw, Hoza 69, 00-681 Warsaw (Poland); Faculty of Physics, Warsaw University of Technology, Koszykowa 75, 00-662 Warsaw (Poland); Twardowski, Andrzej; Wasik, Dariusz; Kwiatkowski, Adam [Institute of Experimental Physics, University of Warsaw, Hoza 69, 00-681 Warsaw (Poland); Sadowski, Janusz [Institute of Physics PAS, al. Lotnikow 32/46, 02-668 Warsaw (Poland); MAX-Lab, Lund University, SE-221 00 Lund (Sweden)

2011-04-01T23:59:59.000Z

347

Pyrovanadolysis: a Pyrophosphorolysis-like Reaction Mediated by Pyrovanadate MN2plus and DNA Polymerase of Bacteriophage T7  

Science Conference Proceedings (OSTI)

DNA polymerases catalyze the 3'-5'-pyrophosphorolysis of a DNA primer annealed to a DNA template in the presence of pyrophosphate (PP{sub i}). In this reversal of the polymerization reaction, deoxynucleotides in DNA are converted to deoxynucleoside 5'-triphosphates. Based on the charge, size, and geometry of the oxygen connecting the two phosphorus atoms of PP{sub i}, a variety of compounds was examined for their ability to carry out a reaction similar to pyrophosphorolysis. We describe a manganese-mediated pyrophosphorolysis-like activity using pyrovanadate (VV) catalyzed by the DNA polymerase of bacteriophage T7. We designate this reaction pyrovanadolysis. X-ray absorption spectroscopy reveals a shorter Mn-V distance of the polymerase-VV complex than the Mn-P distance of the polymerase-PP{sub i} complex. This structural arrangement at the active site accounts for the enzymatic activation by Mn-VV. We propose that the Mn{sup 2+}, larger than Mg{sup 2+}, fits the polymerase active site to mediate binding of VV into the active site of the polymerase. Our results may be the first documentation that vanadium can substitute for phosphorus in biological processes.

B Akabayov; A Kulczyk; S Akabayov; C Thiele; L McLaughlin; B Beauchamp; C Richardson

2011-12-31T23:59:59.000Z

348

ASHRAE 2000 Annual Meeting, June 24-28, 2000, Minneapolis, MN, and published in ASHRAE Transactions, 106(2) 2000.  

E-Print Network (OSTI)

LBNL-44422 Mo-420 ASHRAE 2000 Annual Meeting, June 24-28, 2000, Minneapolis, MN, and published in ASHRAE Transactions, 106(2) 2000. This work was supported by the Assistant Secretary for Energy-factors of predominantly planar, vertical windows has been made by both ASHRAE and NFRC, and as increasing consensus has

349

Competition between stripe and checkerboard magnetic instabilities in Mn-doped BaFe2As2  

Science Conference Proceedings (OSTI)

The appearance of unconventional superconductivity often requires the suppression of an antiferromagnetic (AFM) ordered state by tuning the chemical composition. In BaFe2As2, the AFM ordered state is driven by Fermi surface nesting, resulting in stripe magnetic ordering with propagation vector Qstripe = (; 0) (in Fe square lattice notation). Co substitution acts as an electron donor that destabilizes the nesting condition,1 leading to suppression of the stripe AFM ordering2 and the appearance of superconductivity.3,4 Mn is nominally the hole-doping counterpart of Co which should also detune the Fermi surface nesting, but it is not a superconductor.5 Here we report that Mn doping does not act solely as a hole donor, but instead introduces strong spin uctuations at a wavevector (; ) that is unrelated to the Fermi surface topology of BaFe2As2. Spin uctuations at (; ) and (; 0) coexist, suggesting the Mn dopants act as local magnetic impurities that polarize neighbouring Fe/Mn spins, potentially disrupting superconductivity.

Pratt, Daniel [Ames Laboratory and Iowa State University; Kim, M. G. [Ames Laboratory and Iowa State University; Ran, S. [Ames Laboratory and Iowa State University; Thaler, A. [Ames Laboratory and Iowa State University; Granroth, Garrett E [ORNL; Marty, Karol J [ORNL; Tian, W. [University of Tennessee, Knoxville (UTK); Zarestky, J. L. [Ames Laboratory and Iowa State University; Lumsden, Mark D [ORNL; Budko, S L [Ames Laboratory and Iowa State University; Canfield, P. C. [Ames Laboratory; Goldman, A. I. [Ames Laboratory and Iowa State University; Mcqueeney, R J [Ames Laboratory and Iowa State University; Tucker, G. S. [Ames Laboratory and Iowa State University

2012-01-01T23:59:59.000Z

350

Structural controlled magnetic anisotropy in Heusler L1{sub 0}-MnGa epitaxial thin films  

Science Conference Proceedings (OSTI)

Ferromagnetic L1{sub 0}-MnGa thin films have been epitaxially grown on GaN, sapphire, and MgO substrates using molecular beam epitaxy. Using diffraction techniques, the epitaxial relationships are determined. It is found that the crystalline orientation of the films differ due to the influence of the substrate. By comparing the magnetic anisotropy to the structural properties, a clear correlation could be established indicating that the in-plane and out-of-plane anisotropy is directly determined by the crystal orientation of the film and could be controlled via selection of the substrates. This result could be helpful in tailoring magnetic anisotropy in thin films for spintronic applications.

Wang Kangkang; Lu Erdong; Smith, Arthur R. [Department of Physics and Astronomy, Nanoscale and Quantum Phenomena Institute, Ohio University, Athens, Ohio 45701 (United States); Knepper, Jacob W.; Yang Fengyuan [Department of Physics, Ohio State University, 191 Woodruff Ave., Columbus, Ohio 43210 (United States)

2011-04-18T23:59:59.000Z

351

Synthesis and oxygen content dependent properties of hexagonal DyMnO{sub 3 + sub delta}.  

Science Conference Proceedings (OSTI)

Oxygen deficient polycrystalline samples of hexagonal P6{sub 3}cm (space group No.185) DyMnO{sub 3+{delta}} ({delta} stoichiometric in oxygen content ({delta} = 0). Chemical expansion of the crystal lattice corresponding to these large changes of oxygen was found to be 3.48 x 10{sup -2} mol{sup -1}. Thermal expansion of stoichiometric phases were determined to be 11.6 x 10{sup -6} and 2.1 x 10{sup -6} K{sup -1} for the P6{sub 3}cm and Hex{sub 2} phases, respectively. Our measurements also indicate that the oxygen non-stoichiometry of hexagonal RMnO{sub 3+{delta}} materials may have important influence on their multiferroic properties.

Remsen, S.; Dabrowski, B.; Chmaissem, O.; Mais, J.; Szewczyk, A. (Materials Science Division); (Northern Illinois Univ.); (Polish Acad. Sci.)

2011-07-01T23:59:59.000Z

352

Synthesis and oxygen content dependent properties of hexagonal DyMnO[subscript 3+delta  

SciTech Connect

Oxygen deficient polycrystalline samples of hexagonal P6{sub 3}cm (space group No.185) DyMnO{sub 3+{delta}} ({delta} < 0) were synthesized in Ar by intentional decomposition of its perovskite phase obtained in air. The relative stability of these phases is in accord with our previous studies of the temperature and oxygen vacancy dependent tolerance factor. Thermogravimetric measurements have shown that hexagonal samples of DyMnO{sub 3+{delta}} (0 {le} {delta} {le} 0.4) exhibit unusually large excess oxygen content, which readily incorporates on heating near 300 C in various partial-pressures of oxygen atmospheres. Neutron and synchrotron diffraction data show the presence of two new structural phases at {delta} {approx} 0.25 (Hex{sub 2}) and {delta} {approx} 0.40 (Hex{sub 3}). Rietveld refinements of the Hex{sub 2} phase strongly suggest it is well modeled by the R3 space group (No.146). These phases were observed to transform back to P6{sub 3}cm above {approx} 350 C when material becomes stoichiometric in oxygen content ({delta} = 0). Chemical expansion of the crystal lattice corresponding to these large changes of oxygen was found to be 3.48 x 10{sup -2} mol{sup -1}. Thermal expansion of stoichiometric phases were determined to be 11.6 x 10{sup -6} and 2.1 x 10{sup -6} K{sup -1} for the P6{sub 3}cm and Hex{sub 2} phases, respectively. Our measurements also indicate that the oxygen non-stoichiometry of hexagonal RMnO{sub 3+{delta}} materials may have important influence on their multiferroic properties.

Remsen, S.; Dabrowski, B.; Chmaissem, O.; Mais, J.; Szewczyk, A. (NIU); (Polish)

2011-10-28T23:59:59.000Z

353

Facile synthesis of {alpha}-MnO{sub 2} one-dimensional (1D) nanostructure and energy storage ability studies  

SciTech Connect

The dense manganese oxide nanorods with an extremely narrow distribution are synthesized at a low temperature using first cathodic electrodeposition subsequently heat treatment. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) images show that the nanorods have bar shapes, and their average diameter is less than 50 nm. The Fourier transform infrared (FT-IR) study, the selected area electron diffraction (SAED) pattern in TEM images and the X-ray diffraction (XRD) result show that the nanorods are {alpha}-MnO{sub 2} single crystal. The results of N{sub 2} adsorption-desorption analysis indicate that the BET surface area of the {alpha}-MnO{sub 2} nanorods is 93 m{sup 2} g{sup -1}. By recording the potential-time curve during the electrodeposition process, it is revealed that water reduction reaction has a major role in the electrogeneration of base at the cathode surface under the applied electrochemical conditions. Finally, based on the H{sub 2} bubbling on the cathode surface, the mechanism of the formation and the growth of {alpha}-MnO{sub 2} nanorods are proposed and discussed. For the electrochemical supercapacitor application, electrochemically prepared {alpha}-MnO{sub 2} is found to be stable for a large number of cycles with high specific capacitance, 338 F g{sup -1} at a scan rate of 10 mV s{sup -1}. Finally, the charge-discharge mechanism is discussed. - Graphical abstract: Highlights: Black-Right-Pointing-Pointer New nanostructures of MnO{sub 2} is synthesized by simple method of cathodicelectrodeposition. Black-Right-Pointing-Pointer The product has unique one-dimensional morphology with average diameter size of 50 nm. Black-Right-Pointing-Pointer The experiment conditions (temperature, current density) has not been reported. Black-Right-Pointing-Pointer The one-nanostructures obtained without using of hard template or surfactant.

Yousefi, Taher, E-mail: anozadg@yahoo.com [Department of Chemistry, Tarbiat Moallem University, PO Box: 31979-37551, Tehran (Iran, Islamic Republic of); Materials Research School, NSTRI, PO Box: 14395-836, Tehran (Iran, Islamic Republic of); Golikand, Ahmad Nozad, E-mail: taher_yosefy@yahoo.com [Materials Research School, NSTRI, PO Box: 14395-836, Tehran (Iran, Islamic Republic of); Hossein Mashhadizadeh, Mohammad [Department of Chemistry, Tarbiat Moallem University, PO Box: 31979-37551, Tehran (Iran, Islamic Republic of); Aghazadeh, Mustafa [Department of Optic and Spectroscopy, Lasers and Optics Research School, NSTRI, PO Box: 11365-8486, Tehran (Iran, Islamic Republic of)

2012-06-15T23:59:59.000Z

354

The role of the (111) texture on the exchange bias and interlayer coupling effects observed in sputtered NiFe/IrMn/Co trilayers  

Science Conference Proceedings (OSTI)

Magnetic properties of sputtered NiFe/IrMn/Co trilayers grown on different seed layers (Cu or Ta) deposited on Si (100) substrates were investigated by magnetometry and ferromagnetic resonance measurements. Exchange bias effect and magnetic spring behavior have been studied by changing the IrMn thickness. As shown by X-ray diffraction, Ta and Cu seed layers provoke different degrees of (111) fcc-texture that directly affect the exchange bias and indirectly modify the exchange spring coupling behavior. Increasing the IrMn thickness, it was observed that the coupling angle between the Co and NiFe ferromagnetic layers increases for the Cu seed system, but it reduces for the Ta case. The results were explained considering (i) different anisotropies of the Co and IrMn layers induced by the different degree of the (111) texture and (ii) the distinct exchange bias set at the NiFe/IrMn and IrMn/Co interfaces in both systems. The NiFe and Co interlayer coupling angle is strongly correlated with both exchange bias and exchange magnetic spring phenomena. It was also shown that the highest exchange bias field occurs when an unstressed L1{sub 2} IrMn structure is stabilized.

Castro, I. L.; Nascimento, V. P.; Passamani, E. C.; Takeuchi, A. Y.; Larica, C. [Universidade Federal do Espirito Santo, Vitoria, ES 29075-910 (Brazil)] [Universidade Federal do Espirito Santo, Vitoria, ES 29075-910 (Brazil); Tafur, M. [Universidade Federal de Itajuba, Campus Itabira, Itabira, MG 37500-903 (Brazil)] [Universidade Federal de Itajuba, Campus Itabira, Itabira, MG 37500-903 (Brazil); Pelegrini, F. [Universidade Federal de Goias, Goiania, GO 74001-970 (Brazil)] [Universidade Federal de Goias, Goiania, GO 74001-970 (Brazil)

2013-05-28T23:59:59.000Z

355

NGA_99fin.vp  

Gasoline and Diesel Fuel Update (EIA)

WA WA MT ID OR WY ND SD CA NV UT CO NE KS AZ NM OK TX MN WI MI IA IL IN OH MO AR MS AL GA TN KY FL SC NC WV MD DE VA PA NJ NY CT RI MA VT NH ME LA HI AK Japan Mexico Mexico Algeria Canada Canada Canada Canada Canada Canada Canada Algeria Canada United Arab Emirates Australia Australia Trinidad Qatar Malaysia Canada Mexico Interstate Movements of Natural Gas in the United States, 1999 (Volumes Reported in Million Cubic Feet) Supplemental Data From Volume To From Volume To (T) AL TX MA NH CT RI MD DC DE MD RI MA MA CT VA DC (T) Trucked Source: Energy Information Administration (EIA), Form EIA-176, "Annual Report of Natural and Supplemental Gas Supply and Disposition." E I A NERGY NFORMATION DMINISTRATION 837,902 415,636 225,138 232 308,214 805,614 803,034 800,345 685 147 628,589 9,786 790,088 17,369 278,302 40,727 214,076 275,629 51,935 843,280 826,638 9,988 998,603 553,440 896,187 11,817 629,551 98,423

356

Strong room-temperature ferromagnetism of high-quality lightly Mn-doped ZnO grown by molecular beam epitaxy  

Science Conference Proceedings (OSTI)

Strong room-temperature ferromagnetism is demonstrated in single crystalline Mn-doped ZnO grown by molecular beam epitaxy. With a low Mn concentration of 2 Multiplication-Sign 10{sup 19} cm{sup -3}, Mn-doped ZnO films exhibited room-temperature ferromagnetism with a coercivity field larger than 200 Oe, a large saturation moment of 6 {mu}{sub B}/ion, and a large residue moment that is {approx}70% of the saturation magnetization. Isolated ions with long range carrier mediated spin-spin coupling may be responsible for the intrinsic ferromagnetism.

Zuo Zheng; Zhou Huimei; Olmedo, Mario J.; Kong Jieying; Liu Jianlin [Quantum Structures Laboratory, Department of Electrical Engineering, University of California - Riverside, Riverside, California 92521 (United States); Beyermann, Ward P. [Department of Physics and Astronomy, University of California - Riverside, Riverside, California 92521 (United States); Zheng Jianguo [Laboratory for Electron and X-ray Instrumentation, California Institute for Telecommunications and Information Technology, University of California - Irvine, Irvine, California 92697 (United States); Xin Yan [NHMFL, Florida State University, 1800 E. Paul Dirac Dr., Tallahassee, Florida 32310-3706 (United States)

2012-09-01T23:59:59.000Z

357

Detailed Relationship Between Local Structure Polarons and Magnetization for La1-xCaxMnO3 (0.21 lt x lt 0.45)  

SciTech Connect

We present detailed local structure measurements (using the extended x-ray absorption fine structure technique) for the colossal magnetoresistive material La{sub 1-x}Ca{sub x}MnO{sub 3} (0.21 < x < 0.45) as a function of temperature and magnetic field. The local distortions of the Mn-O bonds are parameterized using {sigma}, the width of the Mn-O pair-distribution function (PDF). After subtracting thermal phonon contributions, we show that the contributions to {sigma}{sup 2} from polaron and Jahn-Teller (JT) distortions, {sigma}{sub JT/polaron}{sup 2}, are a universal function of the magnetization, independent of how the magnetization is achieved via changes in temperature or magnetic field. However this universal behavior is only observed for B fields {ge} 2 T, likely as a result of domain canting in low B fields. The resulting curve is well described by two straight lines with significantly different slopes. These regimes represent two distinctly differ distortions of the oxygen octahedra about the Mn. For low magnetizations up to {approx}65% of the theoretical maximum magnetization, M{sub T}, the slope is low and the distortion removed as the sample becomes magnetized is small - we argue this arises from polarons which have a low distortion around two (or possibly three) Mn sites. At high magnetizations large distortions per Mn site are removed as these sites become magnetized. The data are also analyzed in terms of a two Mn-O peak distribution using experimental standards for Mn-O. The results agree well with recent neutron PDF results but not with some earlier results. We discuss the limitations of assuming a two peak distribution in view of the two distortions needed to describe the Mn-O distortions as a function of T and B for B {ge} 2 T. It is likely that there is a distribution of longer bonds. Finally we show that with increasing B field, the Mn-Mn peak also has a small B-field-induced change - a measure at the unit cell level of magnetostriction but find that there is no observable B-field-induced change in the Mn-La/Ca pair distribution for fields up to {approx}10 T.

F Bridges; L Downward; J Neumeier; T Tyson

2011-12-31T23:59:59.000Z

358

LiMnPO4 Nanoplate Grown via Solid-State Reaction in Molten Hydrocarbon for Li-ion Battery Cathode  

DOE Green Energy (OSTI)

Electrochemically active LiMnPO4 nanoplates have been synthesized via novel single step solid state reaction in molten hydrocarbon. The LiMnPO4 prepared show unique porous nanoplate shape ~50nm in thickness with highly preferred crystallographic orientation. The reversible cycling of carbon coated LiMnPO4 show flat potential at 4.1 V vs. Li with specific capacity reaching up to 168mAh/g and excellent cycling performance using only galvanostatic charging / discharging mode.

Choi, Daiwon; Wang, Donghai; Bae, In-Tae; Xiao, Jie; Nie, Zimin; Wang, Wei; Viswanathan, Vilayanur V.; Lee, Yun Jung; Zhang, Jiguang; Graff, Gordon L.; Yang, Zhenguo; Liu, Jun

2010-08-11T23:59:59.000Z

359

Ferromagnetism in Ga1-xMnxP: evidence for inter-Mn exchangemediated bylocalized holes within a detached impurity band  

SciTech Connect

We report an energy gap for hole photoexcitation in ferromagnetic Ga{sub 1-x}Mn{sub x}P that is tunable by Mn concentration (x {le} 0.06) and by compensation with Te donors. For x{approx}0.06, electrical transport is dominated by excitation across this gap above the Curie temperature (T{sub c}) of 60 K and by thermally-activated hopping below T{sub c}. Magnetization measurements reveal a moment of 3.9 {+-} 0.4 {micro}{sub B} per substitutional Mn while the large anomalous Hall signal unambiguously demonstrates that the ferromagnetism is carrier-mediated. In aggregate these data indicate that ferromagnetic exchange is mediated by holes localized in a Mn-derived band that is detached from the valence band.

Scarpulla, M.A.; Cardozo, B.L.; Farshchi, R.; Hlaing Oo, W.M.; McCluskey, M.D.; Yu, K.M.; Dubon, O.D.

2005-01-11T23:59:59.000Z

360

Comparison of Small Polaron Migration and Phase Separation in Olivine LiMnPO? and LiFePO? using Hybrid Density Functional Theory  

E-Print Network (OSTI)

Using hybrid density functional theory based on the Heyd-Scuseria-Ernzerhof (HSE06) functional, we compared polaron migration and phase separation in olivine LiMnPO? to LiFePO?. The barriers for free hole and electron ...

Ong, Shyue Ping

Note: This page contains sample records for the topic "mn nh nj" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Combustion Synthesis of Nanoparticulate LiMgxMn1-xPO4 (x=0, 0.1, 0.2) Carbon Composites  

E-Print Network (OSTI)

G. J. Exarhos: Glycine-nitrate Combustion Synthesis of Oxideby the Nitrate-Citrate Combustion Method. Mat. Res. Bull.Combustion Synthesis of Nanoparticulate LiMg x Mn 1-x PO 4 (

Doeff, Marca M

2010-01-01T23:59:59.000Z

362

Stability of Jahn-Teller distortion in LaMnO{sub 3} under pressure: An x-ray absorption study  

SciTech Connect

The local environment of manganese atoms in LaMnO{sub 3} under pressure up to 15.3 GPa has been studied by x-ray absorption spectroscopy. For pressures below 8 GPa, no change is detected within the MnO{sub 6} octahedra. Above this pressure a continuous reduction of the long Mn-O distance takes place, however, the octahedral distortion persists over the whole pressure range. At 15.3 GPa the average Jahn-Teller splitting of the distances is reduced by about one-third, indicating that a total removal of the local Jahn-Teller distortion would occur only for pressures around 30 GPa, where metallization is reported to take place. A hysteresis in the long distance reduction is observed down to ambient pressure, suggesting the coexistence of MnO{sub 6} distorted and undistorted units.

Ramos, Aline Y.; Tolentino, Helio C. N.; Souza-Neto, Narcizo M.; Itie, Jean-Paul; Morales, Liliana; Caneiro, Alberto [Institut Neel, UPR 2940-CNRS, 25 av. des Martyrs, Boite Postale 166, 38042 Grenoble, France and Laboratorio Nacional de Luz Sincrotron-LNLS, P.O. Box 6192, 13084-971, Campinas, Sao Paulo (Brazil); Laboratorio Nacional de Luz Sincrotron-LNLS, P.O. Box 6192, 13084-971, Campinas, Sao Paulo, Brazil and Departamento de Fisica dos Materiais e Mecanica, DFMT-IF-USP, Sao Paulo, SP (Brazil); Synchrotron SOLEIL, L'Orme des Merisiers, Saint-Aubin, Boite Postale 48, 91192 Gif-sur-Yvette Cedex (France); Centro Atomico Bariloche and Instituto Balseiro, Comision Nacional de Energia Atomica and Universidad Nacional de Cuyo, 8400 S.C. de Bariloche (Argentina)

2007-02-01T23:59:59.000Z

363

Observation of Orbital Ordering and Jahn-Teller Distortions Supporting the Wigner-crystal Model in Highly Dopes Bi{1-x}Ca{x}MnO{3}  

SciTech Connect

We report on the experimental characterization of orbital ordering and the associated lattice distortions in highly doped Bi{sub 1-x}Ca{sub x}MnO{sub 3}. Resonant x-ray diffraction was used at the Mn L-edge for the direct observation of the ordered localized states, and at the Mn K-edge for the sensitivity to the distortions of the manganese-oxygen octahedra. The orbital ordering on Mn atoms was directly observed at x=0.69; the analysis and the numerical simulations of the K-edge spectra allow us to characterize the pattern of the distorted octahedra at x = 4/5. These observations support the Wigner-crystal-type model at both dopings; the bi-stripe model is ruled out at x = 0.69.

Grenier,S.; Kiryukhin, V.; Cheong, S.; Kim, B.; Hill, J.; Thomas, K.; Tonnerre, J.; Joly, Y.; Staub, U.; Scagnoli, V.

2007-01-01T23:59:59.000Z

364

Searching for a link between the presence of chemical spots on the surface of HgMn stars and their weak magnetic fields  

E-Print Network (OSTI)

We present the results of mapping the HgMn star AR Aur using the Doppler Imaging technique for several elements and discuss the obtained distributions in the framework of a magnetic field topology.

Savanov, I S; Gonzlez, J F; Schller, M

2009-01-01T23:59:59.000Z

365

Properties of molecular beam epitaxy grown Eu{sub x}(transition metal){sub y} films (transition metals: Mn, Cr)  

Science Conference Proceedings (OSTI)

The electronic and crystallographic structures, as well as the magnetic properties, of Eu{sub x}(transition metal){sub y} (transition metals: Mn, Cr) thin films grown by molecular beam epitaxy were studied. Relative changes of the Eu/Mn and Eu/Cr ratios derived from the XPS lines, as well as x-ray reflectivity, indicate mixing of the Eu/Mn and Eu/Cr layers. Valency transitions from Eu{sup 2+} to Eu{sup 3+} were observed in both systems for most studied stoichiometries. A transition to a magnetically ordered phase was observed at 15 K, 40 K, and 62 K for selected films in the Eu-Mn system, and at 50 K for the film with a Eu/Cr ratio of 0.5.

Balin, K. [A. Chelkowski Institute of Physics, University of Silesia, Katowice, 40-007 (Poland); Center for Magnetism and Magnetic Nanostructures, University of Colorado at Colorado Springs, Colorado Springs, Colorado 80918 (United States); Nowak, A. [A. Chelkowski Institute of Physics, University of Silesia, Katowice, 40-007 (Poland); Laboratoire de Physique de l'Etat Condense, University du Maine, Le Mans Cedex, 72085 (France); Gibaud, A. [Laboratoire de Physique de l'Etat Condense, University du Maine, Le Mans Cedex, 72085 (France); Szade, J. [A. Chelkowski Institute of Physics, University of Silesia, Katowice, 40-007 (Poland); Celinski, Z. [Center for Magnetism and Magnetic Nanostructures, University of Colorado at Colorado Springs, Colorado Springs, Colorado 80918 (United States)

2011-04-01T23:59:59.000Z

366

Excitons in single and double GaAs/AlGaAs/ZnSe/Zn(Cd)MnSe heterovalent quantum wells  

Science Conference Proceedings (OSTI)

Exciton photoluminescence spectra, photoluminescence excitation spectra, and magnetophotoluminescence spectra of single (GaAs/AlGaAs/ZnMnSe) and double (GaAs/AlGaAs/ZnSe/ZnCdMnSe) heterovalent quantum wells formed by molecular beam epitaxy are studied. It is shown that the exciton absorption spectrum of such quantum wells mainly reproduces the resonant exciton spectrum expected for usual quantum wells with similar parameters, while the radiative exciton recombination have substantial distinctions, in particular the additional localization mechanism determined by defects generated by heterovalent interface exists. The nature of these localization centers is not currently clarified; their presence leads to broadening of photoluminescence lines and to an increase in the Stokes shift between the peaks of luminescence and absorption, as well as determining the variation in the magnetic g factor of bound exciton complexes.

Toropov, A. A., E-mail: toropov@beam.ioffe.ru; Kaibyshev, V. Kh.; Terent'ev, Ya. V.; Ivanov, S. V.; Kop'ev, P. S. [Russian Academy of Sciences, Ioffe Physical Technical Institute (Russian Federation)

2011-02-15T23:59:59.000Z

367

Semiconducting Transition-Metal Oxides Based on D5 Cations: Theory for MnO and Fe2O3  

SciTech Connect

Transition-metal oxides with partially filled d shells are typically Mott or charge-transfer insulators with notoriously poor transport properties due to large effective electron/hole masses or due to carrier self-trapping. Employing band-structure calculations and ab initio small-polaron theory for MnO and Fe{sub 2}O{sub 3}, we explore the potential of d{sup 5} oxides for achieving desirable semiconducting properties, e.g., in solar energy applications. The quantification of self-trapping energies and the trends with the coordination symmetry suggest strategies to overcome the main bottlenecks, i.e., the tendency for self-trapping of holes due to Mn(II) and of electrons due to Fe(III).

Peng, H.; Lany, S.

2012-05-15T23:59:59.000Z

368

Phase Transition of ZnxMn1-xS Dilute Magnetic Semiconductor Nanoparticles under Ultra-high Pressure  

Science Conference Proceedings (OSTI)

The high-pressure behavior of different doping content of ZnS nanocrystals has been investigated using angle-dispersive synchrotron X-ray powder diffraction up to 45.1 GPa. A phase transformation from the zinc-blende(ZB) to the rock-salt (RS) structure is observed at pressures of about 17.7 and 18.3 GPa at room temperature, corresponding to the Mn{sup 2+} ion mole percent content solutions 0.85% and 1.26%, respectively. The obtained results indicate that the Mn{sup 2+} doping could obviously enhance the phase transition pressure of ZnS nanocrystal. The elevation of phase transition pressure could origin from the higher surface energy induced by ion doping.

Z Zong; Y Ma; T Hu; Q Cui; M Zhang; G Zou

2011-12-31T23:59:59.000Z

369

Crystal and magnetic structures and physical properties of a new pyroxene NaMnGe2O6 synthesized under high pressure  

Science Conference Proceedings (OSTI)

A new pyroxene NaMnGe2O6 has been synthesized at 3 GPa and 800 C, and fully characterized by x-ray single-crystal diffraction and neutron powder diffraction, measurements of magnetization and specific heat. Like other majority sodium pyroxenes, NaMnGe2O6 crystallizes into a monoclinic C2/c structure with unit-cell parameters a = 9.859(2) , b = 8.7507(18) , c = 5.5724(11) , and =105.64(3) at room temperature. The crystal structure is featured by quasi-one-dimensional chains of skew edge-sharing MnO6 octahedra running along the crystallographic c axis; these chains are connected by non-magnetic GeO4 tetrahedra, so as to lead to a low-dimensional magnetism. The highly distorted MnO6 octahedron consisting of three Mn-O bond lengths, i.e. 1.918 , 1.991 , and 2.198 , is consistent with the Jahn-Teller effect at Mn3+ in a cubic crystal field. A long-range cooperative Jahn-Teller distortion is formed by ordering longest Mn-O bonds between two neighboring octahedra along the chain direction. No orbital order-disorder transition has been found up to 750 K as checked by magnetic susceptibility. Like other alkali-metal pyroxenes with S > , NaMnGe2O6 (S = 2) was found to undergo a long-range antiferromagnetic ordering at TN = 7 K at low magnetic field due to the exchange interactions along and between chains. Due to the peculiar structural features and the corresponding magnetic coupling, the weak AF spin ordering gives way to a ferromagnetic-like state at a sufficiently high magnetic field. Specific-heat measurements demonstrated that a large portion of the magnetic entropy, i.e. > 60 %, has been removed above TN as a result of strong spin correlations within the quasi-one-dimensional Mn3+-spin chains. Neutron powder diffraction study suggests a commensurate magnetic structure defined by k = [0 0 0.5] with Mn moments aligned along the c axis. The present study on NaMnGe2O6 completed the evolution of magnetic properties as a function of the d-orbital occupancy from d1 to d5 in the magnetic pyroxenes.

Yan, Jiaqiang [ORNL; Tian, Wei [ORNL; May, Andrew F [ORNL; Cheng, J G [University of Texas, Austin; Zhou, J.-S. [University of Texas, Austin; Garlea, Vasile O [ORNL; Neuefeind, Joerg C [ORNL; Steinfink, Hugo [University of Texas, Austin; Lynch, V [University of Texas, Austin

2013-01-01T23:59:59.000Z

370

Characterization of precipitation behaviors in a non-stoichiometric Cu-24.5at.%Al-19.4at.%Mn alloy  

SciTech Connect

Scanning and transmission electron microscopy examinations of Cu-24.5at.% Al-19.4at.%Mn (similar to Cu{sub 2.2}Mn{sub 0.8}Al) alloy were performed after aging at temperatures ranging from 350 deg. C to 700 deg. C for various durations. It was observed that only {gamma}-brass type and L-J phases were formed after aging at or below 400 deg. C. On the other hand, the {beta}-Mn phase was formed after aging at temperatures ranging from 500 deg. C to 650 deg. C. It is noteworthy that the precipitation behaviors of the {gamma}-brass type and {beta}-Mn phases are different at different aging temperatures. This remarkable result differs from those reported in previous studies on the Cu{sub 3-X}Mn{sub X}Al alloys with X {<=} 1. - Research Highlights: {yields}Precipitation behaviors in a Cu{sub 2.2}Mn{sub 0.8}Al alloy shows different results from those reported in previous studies on the Cu-A-lMn alloys. {yields}The {gamma}-brass type precipitate occurs at temperatures ranging from 350 deg. C to 500 deg. C revealing different precipitation characteristics. {yields}The {beta}-Mn phase formed after aging at 500 deg. C to 650 deg. C shows different precipitation behaviors as well. {yields}L-J phase having an orthorhombic structure could be always observed in the as-quenched and aged conditions.

Jeng, S.C., E-mail: sccheng@tsint.edu.tw

2011-02-15T23:59:59.000Z

371

Solvothermal synthesis of Zn{sub 2}GeO{sub 4}:Mn{sup 2+} nanophosphor in water/diethylene glycol system  

SciTech Connect

The influence of aging of the suspension containing the amorphous precusors on structural, compositional and photoluminescent properties is studied to understand the mechanism on the formation of Zn{sub 2}GeO{sub 4}:Mn{sup 2+} nanoparticles during the solvothermal reaction in the water/diethylene glycol mixed solvent. Aging at 200 Degree-Sign C for 20 min forms the crystalline Zn{sub 2}GeO{sub 4} nanorods and then they grow up to {approx} 50 nm in mean length after aging for 240 min. Their interplanar spacing of (410) increases with increasing the aging time. The photoluminescence intensity corresponding to the d-d transition of Mn{sup 2+} increases with increasing the aging time up to 120 min, and then decreases after aging for 240 min. The photoluminescence lifetime decreases with increasing the aging time, indicating the locally concentrated Mn{sup 2+} ions. These results reveal that Mn{sup 2+} ions gradually replace Zn{sup 2+} ions near surface through repeating dissolusion and precipitation processes during prolonged aging after the complete crystallization of Zn{sub 2}GeO{sub 4}. - Graphical abstract: TEM images of Zn{sub 2}GeO{sub 4}:Mn{sup 2+} nanoparticles aged at 200 Degree-Sign C for different aging times in the mixed solvent of water and diethylene glycol. Highlights: Black-Right-Pointing-Pointer Mechanism on formation of Zn{sub 2}GeO{sub 4}:Mn{sup 2+} nanophosphor under solvothermal condition. Black-Right-Pointing-Pointer Zn{sub 2}GeO{sub 4} nanorods crystallize via amorphous precursors. Black-Right-Pointing-Pointer Gradual substitution of Mn{sup 2+} during prolonged aging. Black-Right-Pointing-Pointer Such an inhomogeneous Mn{sup 2+} doping process results in concentration quenching.

Takeshita, Satoru; Honda, Joji [Department of Applied Chemistry, Faculty of Science and Technology, Keio University, 3-14-1 Hiyoshi, Kohoku-ku, Yokohama 223-8522 (Japan); Isobe, Tetsuhiko, E-mail: isobe@applc.keio.ac.jp [Department of Applied Chemistry, Faculty of Science and Technology, Keio University, 3-14-1 Hiyoshi, Kohoku-ku, Yokohama 223-8522 (Japan); Sawayama, Tomohiro; Niikura, Seiji [SINLOIHI Company, Limited, 2-19-12 Dai, Kamakura 247-8550 (Japan)

2012-05-15T23:59:59.000Z

372

Structural, morphological, and magnetic characterization of In{sub 1-x}Mn{sub x}As quantum dots grown by molecular beam epitaxy  

SciTech Connect

In this paper, we present a method to order low temperature (LT) self-assembled ferromagnetic In{sub 1-x}Mn{sub x}As quantum dots (QDs) grown by molecular beam epitaxy (MBE). The ordered In{sub 1-x}Mn{sub x}As QDs were grown on top of a non-magnetic In{sub 0.4}Ga{sub 0.6}As/GaAs(100) QDs multi-layered structure. The modulation of the chemical potential, due to the stacking, provides a nucleation center for the LT In{sub 1-x}Mn{sub x}As QDs. For particular conditions, such as surface morphology and growth conditions, the In{sub 1-x}Mn{sub x}As QDs align along lines like chains. This work also reports the characterization of QDs grown on plain GaAs(100) substrates, as well as of the ordered structures, as function of Mn content and growth temperature. The substitutional Mn incorporation in the InAs lattice and the conditions for obtaining coherent and incoherent structures are discussed from comparison between Raman spectroscopy and x-ray analysis. Ferromagnetic behavior was observed for all structures at 2 K. We found that the magnetic moment axis changes from [110] in In{sub 1-x}Mn{sub x}As over GaAs to [1-10] for the ordered In{sub 1-x}Mn{sub x}As grown over GaAs template.

Ferri, F. A.; Marega, E. Jr. [Instituto de Fisica de Sao Carlos, Universidade de Sao Paulo, Sao Carlos 13560-970, SP (Brazil); Coelho, L. N. [Instituto de Fisica, Universidade de Brasilia, Brasilia 70919-970, DF (Brazil); Kunets, V. P.; Salamo, G. J. [Department of Physics, University of Arkansas, Fayetteville, Arkansas 72701 (United States)

2012-08-01T23:59:59.000Z

373

Electron cyclotron emission reconstruction image and m/n=3/2 mode in HT-7 tokamak  

SciTech Connect

Electron cyclotron emission reconstruction image has been used for flux surface reconstruction. The reconstruction image is based on plasma rigid rotation which is obtained from Mirnov diagnostic. From the reconstructed two-dimensional flux surface, the classical m/n=3/2 mode is visualized, which is of similar spatial structure as neoclassical 3/2 mode observed in some other tokamaks [B. Esposito et al., Phys. Rev. Lett. 100, 045006 (2008)].

Li Erzhong; Hu Liqun; Ling Bili; Liu Yong; Ti Ang; Chen Kaiyun; Shen Biao; Gao Xiang [Institute of Plasma Physics, Chinese Academy of Sciences, Hefei 230031 (China)

2010-07-15T23:59:59.000Z

374

Synthesis of Mn{sub 2}O{sub 3} homogeneous core/hollow-shell structures with excellent adsorption performance  

Science Conference Proceedings (OSTI)

Large-scale Mn{sub 2}O{sub 3} homogeneous core/hollow-shell structures with cube-shaped and dumbbell-shaped morphologies have been synthesized trough a facile and low-cost method. The microscopy analyses indicate that the core-shell microcubes have an average edge length of 2.5 {mu}m with a shell thickness of about 150 nm, and the core-shell microdumbbells were formed with a length of about 3 {mu}m and shell thickness of about 160 nm. The possible formation mechanism was discussed on the basis of transmission electron microscopy observations. The novel homogeneous core/hollow-shell structures were found to exhibit excellent performance in wastewater treatment. - Graphical abstract: A simple method is described for fabrication of Mn{sub 2}O{sub 3} homogeneous core/hollow-shell structures and the as-prepared materials showed a good ability to remove an organic pollutant in waste water. Highlights: Black-Right-Pointing-Pointer The Mn{sub 2}O{sub 3} homogeneous core/hollow-shell structures were successfully prepared. Black-Right-Pointing-Pointer A simple and high yield method was employed to fabricate such novel structure. Black-Right-Pointing-Pointer The products showed a good ability to remove an organic pollutant in waste water.

Cao Jie, E-mail: candj@mail.ustc.edu.cn [Anhui Provincial Key Lab of Photonics Devices and Materials, Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031 (China); Hefei National Laboratory for Physical Science at Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026 (China); Mao Qinghe [Anhui Provincial Key Lab of Photonics Devices and Materials, Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031 (China); Qian Yitai [Hefei National Laboratory for Physical Science at Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026 (China)

2012-07-15T23:59:59.000Z

375

Isothermal calorimetry investigation of Li{sub 1+x}Mn{sub 2-y}Al{sub z}O{sub 4} spinel.  

DOE Green Energy (OSTI)

The heat generation of LiMn{sub 2}O{sub 4}, Li{sub 1.156}Mn{sub 1.844}O{sub 4}, and Li{sub 1.06}Mn{sub 1.89}Al{sub 0.05}O{sub 4} spinel cathode materials in a half-cell system was investigated by isothermal micro-calorimetry (IMC). The heat variations of the Li/LiMn{sub 2}O{sub 4} cell during charging were attributed to the LiMn{sub 2}O{sub 4} phase transition and order/disorder changes. This heat variation was largely suppressed when the stoichiometric spinel was doped with excess lithium or lithium and aluminum. The calculated entropy change (dE/dT) from the IMC confirmed that the order/disorder change of LiMn{sub 2}O{sub 4}, which occurs in the middle of the charge, was largely suppressed with lithium or lithium and aluminum doping. The dE/dT values obtained did not agree between the charge and the discharge at room temperature (25 C), which was attributed to cell self-discharge. This discrepancy was not observed at low temperature (10 C). Differential scanning calorimeter (DSC) results showed that the fully charged spinel with lithium doping has better thermal stability.

Lu, W.; Belharouak, I.; Park, S. H.; Sun, Y. K; Amine, K.; Chemical Engineering; Hanyang Univ.

2007-05-25T23:59:59.000Z

376

Epitaxial growth on silicon and characterization of MnF{sub 2} and ZnF{sub 2} layers with metastable orthorhombic structure  

SciTech Connect

The growth of MnF{sub 2} and ZnF{sub 2} layers on Si(001) and Si(111) substrates was studied by molecular-beam epitaxy. Calcium fluoride buffer layers with (001) (110), and (111) orientations were used to prevent chemical interaction of MnF{sub 2} and ZnF{sub 2} molecules with the Si substrate. The analysis of x-ray and reflection high-energy electron-diffraction (RHEED) patterns showed that MnF{sub 2} layers grow on all of these planes in the orthorhombic {alpha}-PbO{sub 2}-type crystal phase observed earlier only at high pressures and temperatures. Atomic force microscopy revealed a strong dependence of the surface morphology on the buffer orientation and growth temperature. The best-ordered MnF{sub 2} growth occurred at 500 deg. C on a CaF{sub 2} (110) buffer layer. The diffraction analysis enabled us to find the epitaxial relations at the MnF{sub 2}/CaF{sub 2} interface. A careful analysis of the RHEED patterns of the films grown on CaF{sub 2}(001) showed a similarity in the structure and growth modes between MnF{sub 2} and ZnF{sub 2} layers, with ZnF{sub 2} tending to form multiphase layers. These findings are in agreement with the x-ray diffraction measurements.

Kaveev, A.K.; Anisimov, O.V.; Banshchikov, A.G.; Kartenko, N.F.; Ulin, V.P.; Sokolov, N.S. [Ioffe Physico-Technical Institute Russian Academy of Sciences, St. Petersburg 194021 (Russian Federation)

2005-07-01T23:59:59.000Z

377

Electrode Materials with the Na0.44MnO2 Structure: Effect ofTitanium Substitution on Physical and Electrochemical Properties  

Science Conference Proceedings (OSTI)

The physical and electrochemical properties of LixMnO2 and LixTi0.11Mn0.89O2 synthesized from precursors made by glycine-nitrate combustion (GNC) and solid-state synthesis methods (SS) are examined in this paper. The highest specific capacities in lithium cells are obtained for SS-LixMnO2 electrodes at low current densities, but GNC-LixTi0.11Mn0.89O2 electrodes show the best high rate performance. These results can be explained by changes in the voltage characteristics and differences in the particle morphologies induced by the Ti-substitution and synthesis method. Ti-substitution also results in a decrease in the electronic conductivity, but greatly improves the thermal properties and imparts dissolution resistance to the electrode. For these reasons, it is preferable to use LixTi0.11MnO0.89O2 in lithium battery configurations rather than LixMnO2. Suggestions for improving the electrochemical performance of the Ti-substituted variant are given based on the results described herein.

Doeff, Marca M; Saint, Juliette A.; Doeff, Marca M; Wilcox, James D.

2008-03-10T23:59:59.000Z

378

Factors Affecting the Hydrogen Embrittlement Resistance of Ni-Cr-Mn-Nb Welds  

DOE Green Energy (OSTI)

Nickel based alloys are often welded with argon/hydrogen shielding gas mixtures to minimize oxidation and improve weld quality. However, shielding gas mixtures with {ge} 1% hydrogen additions can result in hydrogen concentrations greater than 5 wt. ppm in the weld metal and reduce ductility via hydrogen embrittlement. For the conditions investigated, the degree of hydrogen embrittlement is highly variable between 5 and 14 wt. ppm. investigation of hydrogen embrittlement of EN82H GTAW welds via tensile testing, light microscopy, transmission electron microscopy, orientation imaging microscopy, and thermal desorption spectroscopy shows that this variability is due to the inhomogeneous microstructure of the welds, the presence of recrystallized grains, and complex residual plastic strains. Specifically, research indicates that high residual strains and hydrogen trapping lower the ductility of Ni-Cr-Mn-Nb weld metal when dissolved hydrogen concentrations are greater than 5 wt. ppm. The inhomogeneous microstructure contains columnar dendritic, cellular dendritic, and recrystallized grains. The decreased tensile ductility observed in embrittled samples is recovered by post weld heat treatments that decrease the bulk hydrogen concentration below 5 wt. ppm.

G.A. Young; C.K. Battige; N. Liwis; M.A. Penik; J. Kikel; A.J. Silvia; C.K. McDonald

2001-03-18T23:59:59.000Z

379

Hydrogen storage in a combined M.sub.xAlH.sub.6/M'.sub.y(NH.sub.2).sub.z system and methods of making and using the same  

SciTech Connect

As a promising clean fuel for vehicles, hydrogen can be used for propulsion, either directly or in fuel cells. Hydrogen storage compositions having high storage capacity, good dehydrogenation kinetics, and hydrogen release and uptake reactions which are reversible are disclosed and described. Generally a hydrogen storage composition of a metal aluminum hexahydride and a metal amide can be used. A combined system (Li.sub.3AIH.sub.6/3LiNH.sub.2) with a very high inherent hydrogen capacity (7.3 wt %) can be carried out at moderate temperatures, and with approximately 95% of that inherent hydrogen storage capacity (7.0%) is reversible over repeated cycling of release and uptake.

Lu, Jun (Salt Lake City, UT); Fang, Zhigang Zak (Salt Lake City, UT); Sohn, Hong Yong (Salt Lake City, UT)

2012-04-03T23:59:59.000Z

380

Hydrogen storage in a combined M.sub.xAlH.sub.6/M'.sub.y(NH.sub.2).sub.z system and methods of making and using the same  

DOE Patents (OSTI)

As a promising clean fuel for vehicles, hydrogen can be used for propulsion, either directly or in fuel cells. Hydrogen storage compositions having high storage capacity, good dehydrogenation kinetics, and hydrogen release and uptake reactions which are reversible are disclosed and described. Generally a hydrogen storage composition of a metal aluminum hexahydride and a metal amide can be used. A combined system (Li.sub.3AIH.sub.6/3LiNH.sub.2) with a very high inherent hydrogen capacity (7.3 wt %) can be carried out at moderate temperatures, and with approximately 95% of that inherent hydrogen storage capacity (7.0%) is reversible over repeated cycling of release and uptake.

Lu, Jun (Salt Lake City, UT); Fang, Zhigang Zak (Salt Lake City, UT); Sohn, Hong Yong (Salt Lake City, UT)

2012-04-03T23:59:59.000Z

Note: This page contains sample records for the topic "mn nh nj" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Mechanochemical transformation of mixtures of Ca(OH){sub 2} and (NH{sub 4}){sub 2}HPO{sub 4} or P{sub 2}O{sub 5}  

Science Conference Proceedings (OSTI)

A detailed comparative study of the mechanochemical transformation of two mixtures: Ca(OH){sub 2}-(NH{sub 4}){sub 2}HPO{sub 4} and Ca(OH){sub 2}-P{sub 2}O{sub 5}, milled in a mortar dry grinder for different periods of time was carried out. The phase transformations obtained at each milling stage were studied by X-ray diffraction, infrared spectroscopy, transmission electron microscopy, differential scanning calorimetry and thermogravimetric analysis. The transformations taking place during the first periods of milling are very different for both mixtures. However, prolonged milling, over nearly the same period, causes amorphization of both mixtures. DSC analysis of the milled powders showed the temperature of crystallization of hydroxyapatite and tricalcium phosphate ({beta}-TCP). Calcinations of all the different milled powders at 800 deg. C for 2 h, results in the formation of hydroxyapatite and {beta}-TCP.

Gonzalez, G. [Laboratorio de Materiales, Centro Tecnologico, Instituto Venezolano de Investigaciones Cientificas. Aptdo. 21827 Caracas 1020-A (Venezuela)]. E-mail: gemagonz@ivic.ve; Sagarzazu, A. [Laboratorio de Materiales, Centro Tecnologico, Instituto Venezolano de Investigaciones Cientificas. Aptdo. 21827 Caracas 1020-A (Venezuela); Villalba, R. [Laboratorio de Materiales, Centro Tecnologico, Instituto Venezolano de Investigaciones Cientificas. Aptdo. 21827 Caracas 1020-A (Venezuela)

2006-10-12T23:59:59.000Z

382

SiO{sub 2} nanospheres with tailorable interiors by directly controlling Zn{sup 2+} and NH{sub 3}.H{sub 2}O species in an emulsion process  

Science Conference Proceedings (OSTI)

SiO{sub 2} nanospheres with tailorable interiors were synthesized by a facile one-spot microemulsion process using TEOS as silica source, wherein cyclohexane including triton X-100 and n-octanol as oil phase and Zn{sup 2+} or NH{sub 3}.H{sub 2}O aqueous solution as dispersive phase, respectively. The products were characterized by Scanning Electron Microscopy, Transmission Electron Microscopy and X-ray Powder Diffraction. It was suggested that the as-synthesized silica nanospheres possessed grape-stone-like porous or single hollow interior, and also found that the ammonia dosage and aging time played key roles in controlling the size and structure of silica nanospheres. Furthermore, the comparative results confirmed that in-situ zinc species [ZnO/Zn(OH){sub 2}] acted as the temporary templates to construct grape-stone-like interior, and a simultaneously competing etching process occurred owing to the soluble Zn(NH{sub 3}){sub 4}{sup 2+} complex formation while the additional excessive ammonia was introduced. With the aging time being extended, the in-situ nanocrystals tended to grow into bigger ones by Ostwald Ripening, producing single hollow interior. - Graphical Abstract: Formation process of SiO{sub 2} nanospheres with porous and single hollow interior. Highlights: > ZnO/Zn(OH){sub 2} nanocrystals as the temporary templates shape the interior structures of SiO{sub 2} nanospheres. > Fabrication of porous and single hollow interiors needs no additional processes such as roasting or dissolving. > Tailorable interiors can be easily obtained through adjusting the aging time of temporary templates.

Liao Yuchao [State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190 (China); Graduate University of Chinese Academy of Sciences, Beijing 100049 (China); Wu Xiaofeng [State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190 (China); Wang Zhen [State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190 (China); Graduate University of Chinese Academy of Sciences, Beijing 100049 (China); Chen Yunfa, E-mail: yfchen@home.ipe.ac.cn [State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190 (China)

2011-07-15T23:59:59.000Z

383

Enhanced Li+ ion transport in LiNi0.5Mn1.5O4 through Control of Site Disorder  

SciTech Connect

High voltage spinel LiNi0.5Mn1.5O4 is a very promising cathode material for lithium ion batteries that can be used to power hybrid electrical vehicles (HEVs). In an effort to maximize the performances of high voltage spinel, it is found that the presence of an appropriate amount of oxygen deficiency and/or Mn3+ is critical to accelerate the transport of Li+ ions within the crystalline structure. Through careful control of the cooling rates after high temperature calcination, LiNi0.5Mn1.5O4 spinels with different disordered phase and/or Mn3+ contents have been synthesized. It is revealed that during slow cooling process (<3oC/min), oxygen deficiency is reduced by the oxygen intake, thus residual Mn3+ amount is also decreased in spinels due to charge neutrality. The relative ratio of ordered/disordered phases in high voltage spinels are systematically investigated and finally correlated with Li+ transport phenomena in the lattice through electrochemical evaluation and in-situ XRD technique. LiNi0.5Mn1.5O4 with an appropriate amount of disordered phase or Mn3+ ions offers high rate capability (96 mAh g-1 at 10 C) and excellent cycling performance with 94.8% capacity retention after 300 cycles. The fundamental findings in this work can be widely used to guide the synthesis of other mixed oxides or spinels as high performance electrode materials for lithium ion batteries.

Zheng, Jianming; Xiao, Jie; Yu, Xiqian; Kovarik, Libor; Gu, Meng; Omenya, Fredrick; Chen, Xilin; Yang, Xiao-Qing; Liu, Jun; Graff, Gordon L.; Whittingham, M. S.; Zhang, Jiguang

2012-10-31T23:59:59.000Z

384

u.s. DEPARTIllENT OF I!NJ1RG EERE PROJECT MANAGEMENT CENTER  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

or industrial practices, and smallscale conservation and renewable energy research and development and pilot projects. The actions could involve building renovations or...

385

Superfund Record of Decision (EPA Region 2): Grand Street Mercury Site, Hoboken, NJ, September 30, 1997  

SciTech Connect

This Record of Decision presents the selected remedial action for the Grand Street Mercury Site. The major components of the selected remedy include: permanent relocation of the former residents of the Site; continuation of temporary relocation of the former residents until permanent relocation has been implemented; historic preservation mitigation measures for the buildings at the Site, as appropriate; gross mercury decontamination of the buildings at the Site including recovery of available mercury, whenever possible; identification and abatement of asbestos in the buildings at the Site; removal and recovery of reusable fixtures, appliances, and recyclable scrap metal and other building components; demolition of the two buildings at the Site using measures to minimize releases of mercury into the environment; removal and off-site disposal of all demolition debris at EPA-approved facilities; sampling of soils at the Site; excavation and off-site disposal of contaminated soils at EPA-approved facilities; sampling of soils at off-site adjacent locations; sampling of groundwater at the Site; and assessment of off-site soil and groundwater data to evaluate the need for future remedial action.

1998-01-01T23:59:59.000Z

386

Department of Civil and Environmental Engineering 623 Bowser Rd. Piscataway NJ 08854-8014  

E-Print Network (OSTI)

medical Home Project 150,462 08-104 Allouche, Erez Applications of Inorganic Polymer Concrete (Geopolymer Prostate Cancer Detection System ULM 2,000 Erez Allouche Applications of Inorganic Polymer Concrete (Geopolymer') in Transportation Structures Located in Harsh Environments LTRC 30,000 Kody Varah- ramyan

387

Department of Civil and Environmental Engineering 623 Bowser Rd. Piscataway NJ 08854-8014  

E-Print Network (OSTI)

in Concrete · Corrosion/Fire-Resistant Structural Concretes · Geopolymer Structural Concrete DR. CHRISTINA · Infrastructure Deterioration · Cathodic Protection · Concrete #12;45 DR. TSUNG-CHOW "JOE" SU Professor Eng Concrete Presuel-Moreno, Francisco, Ph.D. .....44 Concurrency Shankar, Ravi, Ph

388

DOE - Office of Legacy Management -- U S Radium Corp - NJ 09  

Office of Legacy Management (LM)

Corp Historical documents may contain links which are no longer valid or to outside sources. LM can not attest to the accuracy of information provided by these links. Please see...

389

NJ,O-04 MEMOHANDUtl TO: FILE FRon: SITE NAME: CITY:  

Office of Legacy Management (LM)

if yes, date contacted TYPE OF OPERATION ----------- 0 Research & Develapment q Facility Type 0 Production scale testing 0 Pilot Scale g Bench Scale Process ? a Theoretical...

390

N.J. DEP recognizes PPPL as state's top environmental steward...  

NLE Websites -- All DOE Office Websites (Extended Search)

use and carbon emissions, convert our vehicles to more environmentally friendly fuels, compost our waste, and in general, implement a broad-based sustainability program, Dr. Cohen...

391

Aurivillius phases of PbBi{sub 4}Ti{sub 4}O{sub 15} doped with Mn{sup 3+} synthesized by molten salt technique: Structure, dielectric, and magnetic properties  

Science Conference Proceedings (OSTI)

Doping of manganese (Mn{sup 3+}/Mn{sup 4+}) into the Aurivillius phase Pb{sub 1-x}Bi{sub 4+x}Ti{sub 4-x}Mn{sub x}O{sub 15} was carried out using the molten salt technique for various Mn concentrations (x=0, 0.2, 0.4, 0.6, 0.8, and 1). Single phase samples could be obtained in the composition range with x up to 0.6 as confirmed by X-ray and neutron diffraction analysis. Dielectric measurements show a peak at 801, 803, 813 and 850 K for samples with x=0, 0.2, 0.4, and 0.6, respectively, related to the ferroelectric transition temperature (T{sub c}). The main contribution of the in-plane polarization for x{=}0.4 the polarization originates from the dipole moment in the Ti(2)O{sub 6} layer. Mn doping in the Pb{sub 1-x}Bi{sub 4+x}Ti{sub 4-x}Mn{sub x}O{sub 15} does not show any long range magnetic ordering. -- Graphical abstract: The dipole moment of TiO{sub 6} dependence of x in Pb{sub 1-x}Bi{sub 4+x}Ti{sub 4-x}Mn{sub x}O{sub 15} (0{0.2. {yields} Ferromagnetic interactions show the contribution of mixed valence of Mn{sup 3+}/Mn{sup 4+}.

Zulhadjri; Prijamboedi, B. [Inorganic and Physical Chemistry Group, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Jl. Ganesha No. 10, Bandung (Indonesia); Nugroho, A.A. [Magnetic and Photonic Physics Research-Group, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Jl. Ganesha No. 10, Bandung (Indonesia); Mufti, N. [Physics Department, Universitas Negeri Malang, Jl. Surabaya 6, Malang 65145 (Indonesia); Fajar, A. [Centre for Technology of Nuclear Industry Materials - BATAN Puspiptek Serpong, Tangerang (Indonesia); Palstra, T.T.M. [Solid State Materials Laboratory, Zernike Institute for Advanced Materials, Rijksuniversiteit Groningen, Nijenborgh 4, 9747AG Groningen (Netherlands); Ismunandar, E-mail: ismu@chem.itb.ac.i [Inorganic and Physical Chemistry Group, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Jl. Ganesha No. 10, Bandung (Indonesia)

2011-05-15T23:59:59.000Z

392

Electrochemical Kinetics and Performance of Layered Composite Cathode Material Li[Li0.2Ni0.2Mn0.6]O2  

SciTech Connect

Lithium-rich, manganese-rich (LMR) layered composite cathode material Li[Li0.2Ni0.2Mn0.6]O2 has been successfully prepared by a co-precipitation method and its structure is confirmed by XRD characterization. The material delivers a high discharge capacity of 281 mAh g-1, when charged and discharged at a low current density of 10 mA g-1. However, significant increase of cell polarization and decrease of discharge capacity are observed at voltages below 3.5 V with increasing current densities. Galvanostatic intermittent titration technique (GITT) analysis demonstrates that lithium ion intercalation/de-intercalation reactions in this material are kinetically controlled by Li2MnO3 and its activated MnO2 component. The relationship between the electrochemical kinetics and rate performance as well as cycling stability has been systematically investigated. High discharge capacity of 149 mAh g-1 can be achieved at 10 C charge rate and C/10 discharge rate. The result demonstrates that the Li2MnO3 based material could withstand high charge rate (except initial activation process), which is very promising for practical applications. A lower discharge current density is preferred to overcome the kinetic barrier of lithium ion intercalation into MnO2 component, in order to achieve higher discharge capacity even at high charge rates.

Zheng, Jianming; Shi, Wei; Gu, Meng; Xiao, Jie; Zuo, Pengjian; Wang, Chong M.; Zhang, Jiguang

2013-10-10T23:59:59.000Z

393

Pr{sub 0.67}Ba{sub 0.33}MnO{sub 3} in Bulk and Thin Film Ceramic  

Science Conference Proceedings (OSTI)

Bulk polycrystalline of Pr{sub 0.67}Ba{sub 0.33}MnO{sub 3}(PBMO) ceramic prepared via solid-state reaction and converted into thin films on corning glass, fused silica and MgO (100) by pulsed laser deposition (PLD) technique. As compared to bulk PBMO, the unit cell in thin film PBMO experienced positive misfit due to lattice strain induced by substrate used resulting MnO{sub 6} to deform (change in Mn-O-Mn bond angle and Mn-O bond length). Bulk PBMO had large grains ({approx}1.5{mu}m) as compared to thin film which are nano-sized (<100 nm). Two metal-insulator transition temperatures, T{sub P}(156 K and 190 K) were observed in bulk due to core-shell effect as proposed by Zhang et al.. In summary, variation of electrical behaviour was observed between bulk and thin film samples which believed to be due to the difference of ordering in core (body) and grain surface.

Wong, J. K.; Lim, K. P.; Halim, S. A.; Chen, S. K.; Ng, S. W.; Gan, H. M. Albert [Department of Physics, Faculty of Science, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor (Malaysia)

2011-03-30T23:59:59.000Z

394

Preparation and physical properties of the solid solutions Cu{sub 1+x}Mn{sub 1-x}O{sub 2} (0=  

SciTech Connect

Solid solutions of formula Cu{sub 1+x}Mn{sub 1-x}O{sub 2} (0=Mn{sup 3+} ions and revealed that the predominant interactions are antiferromagnetic. Their strength decreases with x, which can be ascribed to a dilution effect, and long-range 3D magnetic ordering observed for CuMnO{sub 2}, disappears for x> 0.05. The crednerite solid solutions are p-type semiconductors. Modeling the thermoelectric power behavior suggests that charge carriers are Cu{sup 2+} holes diffusing in Cu layers for small x values and Mn{sup 4+} holes diffusing in Mn layers for x>0.05. For larger x values a saturation effect limits the charge carrier concentration.

Trari, M. [Laboratoire de Stockage et de Valorisation des Energies Renouvelables, USTHB BP 32, El-Alia Algiers 16111 Algeria (Algeria); Toepfer, J. [Fachhochschule Jena, FB SciTec Carl-Zeiss-Promenade 2, 07745 Jena (Germany); Dordor, P. [Institut de la Matiere Condensee de Bordeaux, ICMCB-CNRS, 87, avenue du Dr. Schweitzer, 33608 Pessac, Cedex (France); Grenier, J.C. [Institut de la Matiere Condensee de Bordeaux, ICMCB-CNRS, 87, avenue du Dr. Schweitzer, 33608 Pessac, Cedex (France); Pouchard, M. [Institut de la Matiere Condensee de Bordeaux, ICMCB-CNRS, 87, avenue du Dr. Schweitzer, 33608 Pessac, Cedex (France); Doumerc, J.P. [Institut de la Matiere Condensee de Bordeaux, ICMCB-CNRS, 87, avenue du Dr. Schweitzer, 33608 Pessac, Cedex (France)]. E-mail: doumerc@icmcb-bordeaux.cnrs.fr

2005-09-15T23:59:59.000Z

395

LaMnO3 thin films grown by using pulsed laser deposition and their simple recovery to a stoichiometric phase by annealing  

Science Conference Proceedings (OSTI)

We systematically investigated various physical properties of epitaxial LaMnO{sub 3} thin films fabricated on SrTiO{sub 3} substrate by using pulsed laser deposition. In particular, we observed drastic changes in their properties when the as-grown films were annealed in a reduced-oxygen atmosphere. Whereas the as-grown LaMnO{sub 3} film showed ferromagnetic and semiconducting properties with a small optical band gap, the LaMnO{sub 3} films annealed at temperature higher than 700 C showed antiferromagnetic and insulating properties with an enlarged band gap. The optical features also changed drastically, in that the optical transition peak shifted to a higher energy with additional fine structures. Such changes were made in a direction such that the LaMnO{sub 3} films were more stoichiometric, indicating that the stoichiometric phase could be recovered by simple annealing of the pulsed-laser-deposited films. Finally, possibilities of the polar catastrophe scenario at the interface between LaMnO{sub 3} and SrTiO{sub 3} are briefly discussed.

Choi, W. S. [Seoul National University; Jeong, D. W. [Seoul National University; Jang, S. Y. [Seoul National University; Marton, Zsolt [ORNL; Seo, Sung Seok A [ORNL; Lee, Ho Nyung [ORNL; Lee, Y. S. [Soongsil University, Korea

2011-01-01T23:59:59.000Z

396

Growth and structure of epitaxial Pb{sub 1-x}Mn{sub x}Se(Ga) films  

Science Conference Proceedings (OSTI)

The growth and structure of Pb{sub 1-x}Mn{sub x}Se (Ga) (N{sub Ga} = 0.8 at %) films with thicknesses of 0.3-0.5 {mu}m, grown on single-crystal PbSe{sub 1-x}S{sub x} (100) substrates by molecular-beam epitaxy, have been studied. It is established that films grow in a face-centered cubic lattice with the (100) orientation, reproducing the substrate orientation. The optimal conditions for obtaining photosensitive epitaxial films with perfect crystal structure are determined (W{sub 1/2} = 70-80'').

Nuriyev, I. R., E-mail: mhagiyev@yahoo.com; Gadzhiyev, M. B.; Sadigov, R. M. [National Academy of Sciences of Azerbaijan, Institute of Physics (Azerbaijan)

2009-03-15T23:59:59.000Z

397

Detector Performance of Ammonium-Sulfide-Passivated CdZnTe and CdMnTe Materials  

Science Conference Proceedings (OSTI)

Dark currents, including those in the surface and bulk, are the leading source of electronic noise in X-ray and gamma detectors, and are responsible for degrading a detector's energy resolution. The detector material itself determines the bulk leakage current; however, the surface leakage current is controllable by depositing appropriate passivation layers. In previous research, we demonstrated the effectiveness of surface passivation in CZT (CdZnTe) and CMT (CdMnTe) materials using ammonium sulfide and ammonium fluoride. In this research, we measured the effect of such passivation on the surface states of these materials, and on the performances of detectors made from them.

Kim, K.H.; Bolotnikov, A.E.; Camarda, G.S.; Marchini, L.; Yang, G.; Hossain, A.; Cui, Y.; Xu, L.; and James, R.B.

2010-08-01T23:59:59.000Z

398

Oxygen reduction at a YSZ interface with cathode materials La{sub 1-x}(Ca or Sr){sub x}MnO{sub 3} or Y{sub 1-x}CaMnO{sub 3}  

Science Conference Proceedings (OSTI)

Impedance spectroscopy combined with an unbonded interface cell (UIC) design, was used to assess oxygen reduction at an yttria-stabilized zirconia electrolyte interface with several substituted yttrium and lanthanum manganite cathode compositions. By analyzing impedance spectra taken using the UIC, effective length of reaction zone at the solid-gas triple phase boundary can be estimated and used to normalize the oxygen reduction reaction rate for each cell, thus effectively removing effect of interface morphology. Intrinsic reaction rates (specific oxygen activities) were determined from spectra as function of temperature and oxygen partial pressure for cathodes La{sub 1-x}(Ca or Sr){sub x}MnO{sub 3} and Y{sub 1-x}Ca{sub x}MnO{sub 3} (LCM, LSM and YCM, respectively) and for Pt. Specific activities in the temperature and P(O{sub 2}) ranges of an operating solid oxide fuel cell (SOFC) cathode, 1173--1273K and 10{sup 5}-10{sup 3} Pa, were highest for LCM intermediate for YCM and lowest for LSM. For LCM and YCM, compositions with x=0.5 gave highest specific activities. Specific activities for all of the tested manganite compositions exceeded the platinum specific activities by at least an order of magnitude. Shapes of impedance spectra for all the manganite systems were similar. Examination of spectra shapes revealed that the overall cathodic polarization process was rather complex and made up of at least two or more fundamental steps.

Youngblood, G.E.; Windisch, C.F. Jr.; Bates, J.L.

1993-09-01T23:59:59.000Z

399

Charge transport and magnetization profile at the interface between the correlated metal CaRuO{sub3} and the antiferromagnetic insulator CaMnO{sub3}.;  

Science Conference Proceedings (OSTI)

A combination of spectroscopic probes was used to develop a detailed experimental description of the transport and magnetic properties of superlattices composed of the paramagnetic metal CaRuO{sub 3} and the antiferromagnetic insulator CaMnO{sub 3}. The charge-carrier density and Ru valence state in the superlattices are not significantly different from those of bulk CaRuO{sub 3}. The small charge transfer across the interface implied by these observations confirms predictions derived from density-functional calculations. However, a ferromagnetic polarization due to canted Mn spins penetrates 3-4 unit cells into CaMnO{sub 3}, far exceeding the corresponding predictions. The discrepancy may indicate the formation of magnetic polarons at the interface.

Freeland, J. W.; Chakhalian, J.; Boris, A. V.; Tonnerre, J-M.; Kavich, JJ.; Yordanov, P.; Grenier,S.; Zschack, P.; Karapetrova, E.; Popovich, P.; Lee, H. N.; Keimer, B. (X-Ray Science Division); ( PSC-USR); (Univ. of Arkansas); (Max Planck Inst. for Solid State Research); (Loughborough Univ.); (CNRS and Univ. Joseph Fourier); (Univ. of Illinois); (ORNL)

2010-01-01T23:59:59.000Z

400

Alanine-assisted low-temperature combustion synthesis of nanocrystalline LiMn{sub 2}O{sub 4} for lithium-ion batteries  

SciTech Connect

Nanocrystalline LiMn{sub 2}O{sub 4} powders have been synthesized by combustion process in a single step using a novel fuel, L-alanine. Thermogravimetric analysis and differential thermal analysis of the gel indicate a sharp combustion at a temperature as low as 149 deg. C. Quantitative phase analysis of X-ray diffraction data shows about 97% of phase purity in the as-synthesized powder, which on further calcination at 700 deg. C becomes single phase LiMn{sub 2}O{sub 4}. High Brunauer, Emmett, and Teller surface area values obtained for ash (53 m{sup 2}/g) and calcined powder (23 m{sup 2}/g) indicate the ultrafine nature of the powder. Average crystallite size is found to be {approx}60-70 nm from X-ray diffraction analysis and transmission electron microscopy. Fourier transformed infra-red spectrum shows two strong bands at 615 and 511 cm{sup -1} originating from asymmetrical stretching of MnO{sub 6} octahedra. A nominal composition of Li{sub 0.88} Mn{sub 2}O{sub 4} is calculated from the inductive coupled plasma analysis. From UV-vis spectroscopy, an optical band gap of 1.43 eV is estimated which is assigned to a transition between t{sub 2g} and e{sub g} bands of Mn 3d. Electrochemical charge-discharge profiles show typical LiMn{sub 2}O{sub 4} behavior with a specific capacity of 76 mAh/g.

Raja, M.W. [Fuel Cell and Battery Section, Electroceramics Division, Central Glass and Ceramic Research Institute, Kolkata 700 032 (India); Mahanty, S. [Fuel Cell and Battery Section, Electroceramics Division, Central Glass and Ceramic Research Institute, Kolkata 700 032 (India); Ghosh, Paromita [Fuel Cell and Battery Section, Electroceramics Division, Central Glass and Ceramic Research Institute, Kolkata 700 032 (India); Basu, R.N. [Fuel Cell and Battery Section, Electroceramics Division, Central Glass and Ceramic Research Institute, Kolkata 700 032 (India)]. E-mail: rnbasu@cgcri.res.in; Maiti, H.S. [Fuel Cell and Battery Section, Electroceramics Division, Central Glass and Ceramic Research Institute, Kolkata 700 032 (India)

2007-08-07T23:59:59.000Z

Note: This page contains sample records for the topic "mn nh nj" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
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401

LaL2SrL8Mn207BelowTc : Exchange StricthR ECEI VED  

NLE Websites -- All DOE Office Websites (Extended Search)

088-00-105 088-00-105 58916-00-105 9714E3 co C--q 03/64 - 1 Sign Reversal of the MN-0 bond Compressibility r in LaL2SrL8Mn207BelowTc : Exchange StricthR ECEI VED in the Ferromagnetic State JUL Q 7 1997 O S T I D. N. Argyriout§ J. F. Mitchell, J. B. Goodenough * , 0. Chmaissemt S. Short, and J. D. Jorgensen t Science and Technology Center for Superconductivity and Materials Science Division Argonne National Laboratory Argonne, IL 60439 * Center for Materials Science and Engineering, ECT 9.102 University of Texas at Austin Austin, TX 78712-1063 the submitted manuscript has been created by the University of Chicago as Operator of Argonne National ( Argonne") under Contract No. W-31-109-ENG-38 with the U. S. Department of Energy. The U.S. Government retains for itself, and others acting on its behalf, a paid-up, non

402

Neutron contribution to CaF2:Mn thermoluminescent dosimeter response in mixed (n/y) field environments.  

SciTech Connect

Thermoluminescent dosimeters (TLDs), particularly CaF{sub 2}:Mn, are often used as photon dosimeters in mixed (n/{gamma}) field environments. In these mixed field environments, it is desirable to separate the photon response of a dosimeter from the neutron response. For passive dosimeters that measure an integral response, such as TLDs, the separation of the two components must be performed by postexperiment analysis because the TLD reading system cannot distinguish between photon- and neutron-produced response. Using a model of an aluminum-equilibrated TLD-400 (CaF{sub 2}:Mn) chip, a systematic effort has been made to analytically determine the various components that contribute to the neutron response of a TLD reading. The calculations were performed for five measured reactor neutron spectra and one theoretical thermal neutron spectrum. The five measured reactor spectra all have experimental values for aluminum-equilibrated TLD-400 chips. Calculations were used to determine the percentage of the total TLD response produced by neutron interactions in the TLD and aluminum equilibrator. These calculations will aid the Sandia National Laboratories-Radiation Metrology Laboratory (SNL-RML) in the interpretation of the uncertainty for TLD dosimetry measurements in the mixed field environments produced by SNL reactor facilities.

DePriest, Kendall Russell; Griffin, Patrick Joseph

2003-07-01T23:59:59.000Z

403

Effect of Pt and H{sub 2} on n-butane isomerization over Fe and Mn promoted sulfated zirconia  

Science Conference Proceedings (OSTI)

The activity of a 0.4 wt% Pt-containing Fe and Mn promoted sulfated zirconia (PtSFMZ) catalyst in n-butane isomerization at 35{degrees}C was compared to that of a Pt-free catalyst (SFMZ). The maximum rate of n-butane conversion observed in helium over PtSFMZ was found to be 2.5 times higher than that over the SFMZ catalyst under the same conditions. It is believed that n-butane isomerization proceeds via a bimolecular mechanism in which the formation of hydrogen-deficient intermediates (carbenium ions and butenes), is necessary and the presence of transition metals such as Pt, Fe, and Mn on sulfated zirconia facilitates the formation/accumulation of these intermediates and increases their stability on the catalyst surface. The presence of H{sub 2} had a strong negative effect on n-butane conversion over PtSFMZ, but had no effect over SFMZ. The negative effect of H{sub 2} on PtSFMZ catalyst in n-butane isomerization reaction was attributed to the decreased concentration of butenes in the presence of hydrogen atoms which are formed by the dissociation of H{sub 2} on Pt. The ability of calcined Pt-containing catalysts to activate hydrogen at 35{degrees}C was demonstrated. Reduced SFMZ with or without Pt was not active at 35{degrees}C regardless of the nature of the carrier gas. 42 refs., 5 figs.

Song, Xuemin; Reddy, K.R.; Sayari, A. [Universite Laval, Quebec (Canada)] [Universite Laval, Quebec (Canada)

1996-06-01T23:59:59.000Z

404

Magnetic properties of the chemically delithiated Li{sub x}Mn{sub 2}O{sub 4} with 0.07{<=}x{<=}1  

Science Conference Proceedings (OSTI)

Magnetism for the Li{sub x}Mn{sub 2}O{sub 4} samples with 0.07{<=}x{<=}1, which are prepared by a chemical reaction in HNO{sub 3} solution, is investigated by direct current susceptibility ({chi}) and muon-spin rotation/relaxation ({mu}SR) measurements. The effective magnetic moment ({mu}{sub eff}) of Mn ions decreases monotonically with decreasing x, indicating that Mn{sup 3+} ions with S=2 (t{sub 2g}{sup 3}e{sub g}{sup 1}) are oxidized to Mn{sup 4+} ions with S=3/2 (t{sub 2g}{sup 3}) with decreasing x. On the other hand, as x decreases from 1 to 0.6, the Curie-Weiss temperature ({Theta}{sub p}) increases monotonically from {approx}-260 to -100 K, and then levels off to -100 K with further decreasing x. This indicates that the antiferromagnetic interaction is dominant in the whole x range. For the x=0.48 sample, the temperature dependence of {chi} in field-cooling mode clearly deviates from that in zero-field-cooling mode below {approx}63 K (=T{sub m}). Furthermore, the hysteresis loop is observed in the magnetization vs. field curve at 5 K. Since the zero-field {mu}SR spectrum is well fitted by a strongly damped oscillation function, the Mn moments for the x=0.48 sample are in a highly disordered fashion down to the lowest temperature measured. -- Graphical abstract: Magnetic phase diagram of the chemically delithiated spinel Li{sub x}Mn{sub 2}O{sub 4} determined by magnetic susceptibility ({chi}) and muon spin rotation/relaxation ({mu}SR) measurements. Display Omitted Highlights: {yields} Magnetic properties of the chemically delithiated Li{sub x}Mn{sub 2}O{sub 4} samples are investigated. {yields} The antiferromagnetic interaction is dominant in the whole x range. {yields} All the Li{sub x}Mn{sub 2}O{sub 4} samples show a magnetic transition below T{sub m}. {yields} The remanent magnetization vs. x curve exhibits a maximum at x=0.48. {yields} The x=0.48 sample is in a highly disordered magnetic state even at 1.8 K.

Mukai, Kazuhiko, E-mail: e1089@mosk.tytlabs.co.j [Toyota Central Research and Development Laboratories, Inc., 41-1 Yokomichi, Nagakute, Aichi 480-1192 (Japan); Sugiyama, Jun; Kamazawa, Kazuya; Ikedo, Yutaka [Toyota Central Research and Development Laboratories, Inc., 41-1 Yokomichi, Nagakute, Aichi 480-1192 (Japan); Andreica, Daniel [Laboratory for Muon-Spin Spectroscopy, Paul Scherrer Institut, PSI Villigen CH-5232 (Switzerland); Faculty of Physics, Babes-Bolyai University, 400084 Cluj-Napoca (Romania); Amato, Alex [Laboratory for Muon-Spin Spectroscopy, Paul Scherrer Institut, PSI Villigen CH-5232 (Switzerland)

2011-05-15T23:59:59.000Z

405

Exchange bias of spin valve structure with a top-pinned Co{sub 40}Fe{sub 40}B{sub 20}/IrMn  

SciTech Connect

We have investigated the exchange bias of a directly top-pinned Co{sub 40}Fe{sub 40}B{sub 20}/IrMn structure. An exchange bias was realized on the as-deposited samples, in which Co{sub 40}Fe{sub 40}B{sub 20} exhibits a fully amorphous structure. A current-in-plane giant magnetoresistance effect was demonstrated on simple Ru/CoFeB/Cu/CoFeB/IrMn/Ru stacks prior to and after annealing. The amorphous CoFeB layer partially crystallized from the interface with a Cu spacer layer after annealed at 280 deg. C.

You, C. Y.; Furubayashi, T.; Takahashi, Y. K. [National Institute for Materials Science, 1-2-1 Sengen, Tsukuba 305-0047 (Japan); Goripati, H. S. [Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba 305-8571 Japan (Japan); Hono, K. [National Institute for Materials Science, 1-2-1 Sengen, Tsukuba 305-0047 (Japan); Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba 305-8571 (Japan)

2008-07-07T23:59:59.000Z

406

First-principles calculation of the effect of atomic disorder on the electronic structure of the half-metallic ferromagnet NiMnSb  

Science Conference Proceedings (OSTI)

The electronic structure of the half-metallic ferromagnet NiMnSb with three different types of atomic disorder is calculated using the layer Korringa-Kohn-Rostoker method in conjunction with the coherent potential approximation. Results indicate the presence of minority-spin states at the Fermi energy for degrees of disorder as low as a few percent. The resulting spin polarization below 100{percent} is discussed in the light of experimental difficulties confirming the half-metallic property of NiMnSb thin films directly. {copyright} {ital 1999} {ital The American Physical Society}

Orgassa, D.; Fujiwara, H. [Center for Materials for Information Technolgy (MINT), The University of Alabama, Tuscaloosa, Alabama 35487-0209 (United States); Schulthess, T.C.; Butler, W.H. [Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831-6114 (United States)

1999-11-01T23:59:59.000Z

407

The Influence of Surface Chemistry on the Rate Capability of LiNi[subscript 0.5]Mn[subscript 0.5]O[subscript 2] for Lithium Rechargeable Batteries  

E-Print Network (OSTI)

Subsequent annealing at Formula enhances the rate capability of LiNi[subscript 0.5]Mn[subscript 0.5]O[subscript 2], delivering 180 mAh/g at 55[degrees]C and 8C rate compared to 50 mAh/g of LiNi[subscript 0.5]Mn[subscript ...

Yabuuchi, Naoaki

408

Synthesis, characterization and electrochemmistry of lithium battery electrodes : xLi{sub 2}MnO{sub 3}{center_dot}(1-x)LiMn{sub 0.333}Ni{sub 0.333}Co{sub 0.333}O{sub2} (0{le}x{le}0.7).  

Science Conference Proceedings (OSTI)

Lithium- and manganese-rich layered electrode materials, represented by the general formula xLi{sub 2}MnO{sub 3} {center_dot} (1-x)LiMO{sub 2} in which M is Mn, Ni, and Co, are of interest for both high-power and high-capacity lithium ion cells. In this paper, the synthesis, structural and electrochemical characterization of xLi{sub 2}MnO{sub 3} {center_dot} (1-x)LiMn{sub 0.333}Ni{sub 0.333}Co{sub 0.333}O{sub 2} electrodes over a wide compositional range (0 {le} x {le} 0.7) is explored. Changes that occur to the compositional, structural, and electrochemical properties of the electrodes as a function of x and the importance of using a relatively high manganese content and a high charging potential (>4.4 V) to generate high capacity (>200 mAh/g) electrodes are highlighted. Particular attention is given to the electrode composition 0.3Li{sub 2}MnO{sub 3} {center_dot} 0.7LiMn{sub 0.333}Ni{sub 0.333}Co{sub 0.333}O{sub 2} (x = 0.3) which, if completely delithiated during charge, yields Mn{sub 0.533}Ni{sub 0.233}Co{sub 0.233}O{sub 2}, in which the manganese ions are tetravalent and, when fully discharged, LiMn{sub 0.533}Ni{sub 0.233}Co{sub 0.233}O{sub 2}, in which the average manganese oxidation state (3.44) is marginally below that expected for a potentially damaging Jahn-Teller distortion (3.5). Acid treatment of 0.3Li{sub 2}MnO{sub 3} {center_dot} 0.7LiMn{sub 0.333}Ni{sub 0.333}Co{sub 0.333}O{sub 2} composite electrode structures with 0.1 M HNO{sub 3} chemically activates the Li{sub 2}MnO{sub 3} component and essentially eliminates the first cycle capacity loss but damages electrochemical behavior, consistent with earlier reports for Li{sub 2}MnO{sub 3}-stabilized electrodes. Differences between electrochemical and chemical activation of the Li{sub 2}MnO{sub 3} component are discussed. Electrochemical charge/discharge profiles and cyclic voltammogram data suggest that small spinel-like regions, generated in cycled manganese-rich electrodes, serve to stabilize the electrodes, particularly at low lithium loadings (high potentials). The study emphasizes that, for high values of x, a relatively small LiMO{sub 2} concentration stabilizes a layered Li{sub 2}MnO{sub 3} electrode to reversible lithium insertion and extraction when charged to a high potential.

Johnson, C. S.; Li, N.; Lefief, C.; Vaughey, J. T.; Thackeray, M. M.; Chemical Sciences and Engineering Division

2008-01-01T23:59:59.000Z

409

Demonstration Assessment of Light-Emitting Diode (LED) Roadway Lighting at the I-35W Bridge, Minneapolis, MN  

SciTech Connect

This report describes the process and results of a demonstration of solid-state lighting (SSL) technology conducted in 2009 at the recently reconstructed I-35W bridge in Minneapolis, MN. The project was supported under the U.S. Department of Energy (DOE) Solid-State Lighting GATEWAY Technology Demonstration Program. Other participants in the demonstration project included the Minnesota Department of Transportation (Mn/DOT), Federal Highways Administration (FHWA), and BetaLED (a division of Ruud Lighting). Pacific Northwest National Laboratory (PNNL) conducted the measurements and analysis of the results. DOE has implemented a three-year evaluation of the LED luminaires in this installation in order to develop new longitudinal field data on LED performance in a challenging, real-world environment. This document provides information through the initial phase of the I-35W bridge project, up to and including the opening of the bridge to the public and the initial feedback received on the LED lighting installation from bridge users. Initial findings of the evaluation are favorable, with minimum energy savings level of 13% for the LED installation relative to the simulated base case using 250W high-pressure sodium (HPS) fixtures. The LEDs had an average illuminance level of 0.91 foot candles compared to 1.29 fc for the HPS lamps. The LED luminaires cost $38,000 more than HPS lamps, yielding a lengthy payback period, however the bridge contractor had offered to include the LED luminaires as part of the construction package at no additional cost. One potentially significant benefit of the LEDs in this installation is avoiding rolling lane closures on the heavily-traveled interstate bridge for the purpose of relamping the HPS fixtures. Rolling lane closures involve multiple crew members and various maintenance and safety vehicles, diversion of traffic, as well as related administrative tasks (e.g., approvals, scheduling, etc.). Mn/DOT records show an average cost of relamping fixtures along interstate roadways of between $130-150 per pole. The previous bridge saw a lamp mortality rate of approximately 50% every two years, though the new bridge was designed to minimize many of the vibration issues. A voluntary Web-based feedback survey of nearly 500 self-described bridge users showed strong preference for the LED lighting - positive comments outnumbered negative ones by about five-to-one.

Kinzey, Bruce R.; Myer, Michael

2009-08-31T23:59:59.000Z

410

www.eia.gov  

U.S. Energy Information Administration (EIA)

MO MT NE NV NH NJ NM NY NC ND OH OK OR PA RI SC SD TN TX UT VT VA WA WV WI WY U.S. Number of states in which marketer is licensed ... Service Tech & Research Corp

411

Microsoft Word - NGAMaster_State_TablesNov12.doc  

Gasoline and Diesel Fuel Update (EIA)

WI NE IA KS MO TX IL IN OH MI OK AR TN WV VA KY MD PA WI NY VT NH MA CT ME RI NJ DC NC SC GA AL MS LA FL HI AK DE 0 2 4 6 8 10 1980 1982 1984 1986 1988 1990 1992 1994 1996 1998...

412

C:\\ANNUAL\\VENTCHAP.V8\\NewNGA02.vp  

Gasoline and Diesel Fuel Update (EIA)

NE IA KS MO TX IL IN OH MI OK AR TN W VA KY MD PA WI NY VT NH MA CT ME RI NJ DE DC NC SC GA AL MS LA FL HI AK 15. Marketed Production of Natural Gas in the United States, 2001...

413

Influence of defect formation as a result of incorporation of a Mn {delta} layer on the photosensitiviy spectrum of InGaAs/GaAs quantum wells  

Science Conference Proceedings (OSTI)

The influence of defect formation upon the deposition of a Mn {delta} layer and a GaAs coating layer (with the use of laser evaporation) on the photosensitivity spectra of heterostructures with InGaAs/GaAs quantum wells located in the near-surface region has been studied.

Gorshkov, A. P., E-mail: gorskovap@phys.unn.ru; Karpovich, I. A.; Pavlova, E. D.; Kalenteva, I. L. [Lobachevsky State University of Nizhny Novgorod (Russian Federation)

2012-02-15T23:59:59.000Z

414

In-situ x-ray characterization of LiMn{sub 2}O{sub 4}: A comparison of structural and electrochemical behavior  

DOE Green Energy (OSTI)

Li{sub x}Mn{sub 2}O{sub 4} materials are of considerable interest in battery research and development. The crystal structure of this material can significantly affect electrochemical performance. The ability to monitor changes of crystal structure during use, that is during electrochemical cycling, would prove useful to verify and control such structural changes. The authors report in-situ XRD measurements of LiMn{sub 2}O{sub 4} cathodes with the use of an electrochemical cell designed for in-situ X-ray analysis. Cells prepared using this cell design allow investigation of the changes in the LiMn{sub 2}O{sub 4} structure during charge and discharge. They describe the variation in lattice parameters along the voltage plateaus and consider the structural changes in terms of the electrochemical results on each cell. Kinetic effects of LiMn{sub 2}O{sub 4} phase changes are also addressed. Applications of the in-situ cell to other compounds such as LiCoO{sub 2} cathodes and carbon anodes are presented as well.

Rodriguez, M.A.; Ingersoll, D.; Doughty, D.H.

1998-02-01T23:59:59.000Z

415

Study of the Mn-binding sites in photosystem II using antibodies raised against lumenal regions of the D1 and D2 reaction center proteins  

DOE Green Energy (OSTI)

The experiments discussed in this thesis focus on identifying the protein segments or specific amino acids which provide ligands to the Mn cluster of photosystem II (PS II). This Mn cluster plays a central role in the oxygen-evolving complex (OEC) of PS II. The Mn cluster is thought to be bound by lumenal regions of the PS II reaction center proteins known as D1 and D2. First, several peptides were synthesized which correspond to specific lumenal segments of the D1 and D2 proteins. Next, polyclonal antibodies were successfully elicited using three of these peptides. The peptides recognized by these antibodies correspond to protein segments of the spinach reaction center proteins: Ile-321 to Ala-344 of D1 (D1-a), Asp-319 to Arg-334 of D1 (D1-b), and Val-300 to Asn-319 of D2 (D2-a). These antibodies were then used in assays which were developed to structurally or functionally probe the potential Mn-binding regions of the D1 and D2 proteins.

Dalmasso, E.A.

1992-04-01T23:59:59.000Z

416

Structural and magnetic characterization of BiFe{sub x}Mn{sub 2-x}O{sub 5} oxides (x=0.5, 1.0)  

SciTech Connect

The title compounds have been synthesized by a citrate technique followed by thermal treatments in air (BiFe{sub 0.5}Mn{sub 1.5}O{sub 5}) or under high oxygen pressure conditions (BiFeMnO{sub 5}), and characterized by X-ray diffraction (XRD), neutron powder diffraction (NPD) and magnetization measurements. The crystal structures have been refined from NPD data in the space group Pbam at 295 K. These phases are isostructural with RMn{sub 2}O{sub 5} oxides (R=rare earths) and contain infinite chains of Mn{sup 4+}O{sub 6} octahedra sharing edges, linked together by (Fe,Mn){sup 3+}O{sub 5} pyramids and BiO{sub 8} units. These units are strongly distorted with respect to those observed in other RFeMnO{sub 5} compounds, due to the presence of the electronic lone pair on Bi{sup 3+}. It is noteworthy the certain level of antisite disorder exhibited in both samples, where the octahedral positions are partially occupied by Fe cations, and vice versa. BiFe{sub x}Mn{sub 2-x}O{sub 5} (x=0.5, 1.0) are short-range magnetically ordered below 20 K for x=0.5 and at 40 K for x=1.0. The main magnetic interactions seem to be antiferromagnetic (AFM); however, the presence of a small hysteresis in the magnetization cycles indicates the presence of some weak ferromagnetic (FM) interactions. - Graphical Abstract: BiFe{sub x}Mn{sub 2-x}O{sub 5} (x=0.5, 1.0) samples are isostructural with BiMn{sub 2}O{sub 5}, belonging to the Pbam space group. The crystal structure contains infinite chains of edge-sharing Mn{sup 4+}O{sub 6} octahedra, interconnected by dimer units of Fe{sup 3+}O{sub 5} square pyramids. These units are strongly distorted due to the presence of the electronic lone pair on Bi{sup 3+}. They are magnetically ordered at low temperatures. The main magnetic interactions seem to be antiferromagnetic with the presence of some weak ferromagnetic response. Highlights: > Two new compounds of formula BiFe{sub x}Mn{sub 2-x}O{sub 5} (x=0.5, 1.0) have been obtained. > Their crystallographic structure is isotypical with that of RMn{sub 2}O{sub 5} materials. > The presence of the electronic lone pair on Bi{sup 3+} severely distorts the crystal structure. > There is no establishment of a long-range ferrimagnetic structure.

Retuerto, M., E-mail: retuerto@rci.rutgers.edu [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco, E-28049 Madrid (Spain); Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, 610 Taylor Road Piscataway, NJ 08854-808 (United States); Martinez-Lope, M.J. [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco, E-28049 Madrid (Spain); Krezhov, K. [Institute for Nuclear Research and Nuclear Energy, Bulgarian Academy of Sciences, 72 Tsarigradsko Chaussee Boulevard, Sofia 1784 (Bulgaria); Fernandez-Diaz, M.T. [Institut Laue-Langevin, BP156X, Grenoble F-38042 (France); Alonso, J.A. [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco, E-28049 Madrid (Spain)

2011-09-15T23:59:59.000Z

417

Growth and structure of photosensitive Pb{sub 1-x}Mn{sub x}Te(Ga) epitaxial films  

Science Conference Proceedings (OSTI)

The growth and structure of (1-1.5)-{mu}m-thick Pb{sub 1-x}Mn{sub x}Te(Ga)(x = 0.06) films with 0.4-0.9 at % of gallium, grown on BaF{sub 2}(111) and Pb{sub 1-x}Sn{sub x}Te (x = 0.2) (100) substrates by molecular beam epitaxy, have been investigated. It is established that the films are crystallized into an fcc structure, and their growth planes are (111) and (100), according to the substrate orientation. The optimal conditions for obtaining high-resistivity photosensitive p-and n-type films with a perfect crystal structure (W{sub 1/2} = 80''-100'') have been determined.

Nuriev, I. R.; Sadygov, R. M.; Nazarov, A. M., E-mail: afinnazarov@yahoo.com [Azerbaijan National Academy of Sciences, Institute of Physics (Azerbaijan)

2008-05-15T23:59:59.000Z

418

Reexamining the Beta Decay of 53,54Ni, 52,53Co, 51Fe, and 50Mn  

Science Conference Proceedings (OSTI)

he decay of 53,54Ni, 52,53Co, 51Fe, and 50Mn was investigated via the fragmentation of a 58Ni primary beam with an energy of 68.6 MeV/u. The proton- coincidences of 53Ni -delayed proton emission were observed. Based on the analysis of the proton- coincidence events, it was inferred that the previous assignment of the excitation energy for the isobaric analog state in 53Co may be problematic. The half-lives of these nuclei were obtained, in which the uncertainty of 52Co half-life was reduced by a factor of 3. The half-lives were evaluated and used as inputs of nucleosynthesis calculations of the rapid proton-capture process in an x-ray burst.

Su, J. [Neutron Scattering Laboratory, China Institute of Atomic Energy, Beijing, China; Liu, W. P. [China Institute of Atomic Energy Collaboration; Collaboration, [China Institute of Atomic Energy Collaboration; Wang, J. S. [Inst. Modern Phys., Chinese Academy of Sciences-Lanzhou; Collaboration, [Inst. Modern Phys., Chinese Academy of Sciences-Lanzhou; Li, X. Q. [Peking University-Beijing; He, C. [Peking University-Beijing; Smith, Michael Scott [ORNL

2013-01-01T23:59:59.000Z

419

NH Acid Rain Control Act (New Hampshire)  

Energy.gov (U.S. Department of Energy (DOE))

The Act is implemented under New Hampshire's acid deposition control program established under the Rules to Control Air Pollution in Chapter Env-A 400. The goal of the Act is to reduce emissions...

420

Export.gov - NH Our Services  

NLE Websites -- All DOE Office Websites (Extended Search)

Identify potential partners. Market your firm directly to local companies. Partner Search Identify potential partners and get detailed company reports. Determine the...

Note: This page contains sample records for the topic "mn nh nj" from the National Library of EnergyBeta (NLEBeta).
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421

Pittsburg, NH Natural Gas Exports to Canada  

Annual Energy Outlook 2012 (EIA)

56,879 39,438 26,767 18,297 19,826 47,451 1998-2012 Pipeline Prices 7.52 9.72 5.04 5.48 5.45 4.08 1998...

422

Pittsburg, NH Natural Gas Exports to Canada  

Gasoline and Diesel Fuel Update (EIA)

7 2008 2009 2010 2011 2012 View History Pipeline Volumes 0 64 0 0 336 199 2007-2012 Pipeline Prices -- 7.61 -- -- 7.54 2.62 2007-2012...

423

Buildings Energy Data Book: 3.9 Educational Facilities  

Buildings Energy Data Book (EERE)

6 6 2010 Regional New Construction and Renovations Expenditures for Public K-12 Schools ($Million) Region New Schools Additions Renovation Total Region 1 (CT, MA, ME, NH, RI, VT) Region 2 (NJ, NY, PA) Region 3 (DE, MD, VA, WV) Region 4 (KY, NC, SC, TN) Region 5 (AL, FL, GA, MS) Region 6 (IN, MI, OH) Region 7 (IL, MN, WI) Region 8 (IA, KS, MO, NE) Region 9 (AR, LA, OK, TX) Region 10 (CO, MT, ND, NM, SD, UT, WY) Region 11 (AZ, CA, HI, NV) Region 12 (AK, ID, OR, WA) Total Source(s): School Planning & Management, 16th Annual School Construction Report, Feb. 2011 p. CR3 8,669.5 3,074.1 2,796.8 14,540.4 1,605.4 407.3 275.2 2,287.9 258.2 181.8 158.1 598.1 1,653.9 479.6 387.8 2,521.2 548.2 130.9 93.3 772.4 309.3 206.1 135.3 650.7 217.6 231.4 187.8 636.8 1,338.0 327.6 175.9 1,841.4 359.6 286.3 278.9 924.8

424

regionalmaps  

Gasoline and Diesel Fuel Update (EIA)

LNG Imports LNG Imports Pacifi c (9) Moun tain (8) CA (12) AZ/N M (11) W. North Centr al (4) W. South Centr al (7) E. South Centr al (6) E. North Centr al (3) S. Atlan tic (5) FL (10) Mid. Atlan tic (2) New Engl. (1) W. Cana da E. Cana da MacK enzie Alask a Cana da Offsh ore and LNG Mexic o Baha mas Primary Flows Secondary Flows Pipeline Border Crossing Figure 6. Coal Supply Regions Source: Energy Information Administration. Office of Integrated Analysis and Forecasting WA ID OR CA NV UT TX OK AR MO LA MS AL GA FL TN SC NC KY VA WV WY CO SD ND MI MN WI IL IN OH MD PA NJ DE CT MA NH VT NY ME RI MT NE IA KS MI AZ NM 500 0 SCALE IN MILES APPALACHIA Northern Appalachia Central Appalachia Southern Appalachia INTERIOR NORTHERN GREAT PLAINS Eastern Interior Western Interior Gulf Lignite Dakota Lignite Western Montana Wyoming, Northern Powder River Basin Wyoming, Southern Powder River Basin Western Wyoming

425

Microsoft Word - NGAMaster_State_TablesNov12.doc  

Gasoline and Diesel Fuel Update (EIA)

WA WA MT ID OR WY ND SD CA NV UT CO NE KS AZ NM OK TX MN WI MI IA IL IN OH MO AR MS AL GA TN KY FL SC NC WV MD DE VA PA NJ NY CT RI MA VT NH ME LA HI AK Japan Mexico Mexico Algeria Canada Canada Canada Canada Canada Canada Canada Algeria Mexico Trinidad Canada Canada Nigeria Oman Qatar Trinidad Gulf of Mexico Gulf of Mexico Gulf of Mexico Canada Trinidad Trinidad Gulf of Mexico Malaysia 13,623 Figure 8. Interstate Movements of Natural Gas in the United States, 2003 (Million Cubic Feet) Source: Energy Information Administration (EIA), Form EIA-176, "Annual Report of Natural and Supplemental Gas Supply and Disposition." Energy Information Administration / Natural Gas Annual 2003 Supplemental Data From Volume To From Volume To CT RI RI MA MA CT VA DC MD DC 366,224 655,731 666,614 633,960 144,284 43,869 536,776 63,133 36,848

426

C:\ANNUAL\VENTCHAP.V8\NewNGA02.vp  

Gasoline and Diesel Fuel Update (EIA)

6 6 0.00-1.99 2.00-3.99 4.00-5.99 6.00-7.99 8.00-9.99 10.00-11.99 12.00+ WA ID MT OR CA NV UT AZ NM CO WY ND SD MN WI NE IA KS MO TX IL IN OH MI OK AR TN W VA KY MD PA WI NY VT NH MA CT ME RI NJ DE DC NC SC GA AL MS LA FL HI AK 27. Average City Gate Price of Natural Gas in the United States, 2001 (Dollars per Thousand Cubic Feet) Figure Sources: Energy Information Administration (EIA), Form EIA-857, "Monthly Report of Natural Gas Purchases and Deliveries to Consumers." 0 2 4 6 8 10 1980 1982 1984 1986 1988 1990 1992 1994 1996 1998 2000 Dollars per Thousand Cubic Feet 0 40 80 120 160 200 240 280 320 Dollars per Thousand Cubic Meters Constant Dollars Nominal Dollars Sources: Nominal dollars: Energy Information Administration (EIA), Form EIA-176, "Annual Report of Natural and Supplemental Gas Supply and Disposition." Constant dollars: Prices were converted to 2001 dollars using the chain-type

427

Residential Demand Module  

Gasoline and Diesel Fuel Update (EIA)

and clothes drying. In addition to the major equipment-driven and clothes drying. In addition to the major equipment-driven end-uses, the average energy consumption per household is projected for other electric and nonelectric Energy Information Administration/Assumptions to the Annual Energy Outlook 2006 19 Pacific East South Central South Atlantic Middle Atlantic New England West South Central West North Central East North Central Mountain AK WA MT WY ID NV UT CO AZ NM TX OK IA KS MO IL IN KY TN MS AL FL GA SC NC WV PA NJ MD DE NY CT VT ME RI MA NH VA WI MI OH NE SD MN ND AR LA OR CA HI Middle Atlantic New England East North Central West North Central Pacific West South Central East South Central South Atlantic Mountain Figure 5. United States Census Divisions Source:Energy Information Administration,Office of Integrated Analysis and Forecasting. Report #:DOE/EIA-0554(2006) Release date: March 2006

428

Microsoft Word - figure_13.doc  

Gasoline and Diesel Fuel Update (EIA)

Egypt Figure 13. Net Interstate Movements, Imports, and Exports of Natural Gas in the United States, 2008 (Million Cubic Feet) Norway Trinidad/ Tobago Interstate Movements Not Shown on Map From Volume To From Volume To CT RI RI MA MA CT VA DC MD DC 45,772 WA M T I D OR W Y ND SD C A N V UT CO NE KS AZ NM OK TX MN WI MI IA I L IN OH MO AR MS AL GA TN KY FL SC NC WV MD DE VA PA NJ NY CT RI MA VT NH ME LA HI AK Mexico C a n a d a C a n a d a Canada Canada Canada Canada Canada Canada Canada i i N g e r a Gulf of Mexico Gulf o f M e x i c o Gulf of Mexico Canada Gulf of Mexico Sources: Energy Information Administration (EIA), Form EIA-176, "Annual Report of Natural and Supplemental Gas Supply and Disposition," the Office of Fossil Energy, Natural Gas Imports and Exports, and EIA estimates.

429

Microsoft Word - figure_13.doc  

Gasoline and Diesel Fuel Update (EIA)

,833 ,833 35 Egypt Figure 13. Net Interstate Movements, Imports, and Exports of Natural Gas in the United States, 2009 (Million Cubic Feet) Norway Trinidad/ Tobago Trinidad/ Tobago Egypt Interstate Movements Not Shown on Map From Volume To From Volume To CT RI RI MA MA CT VA DC MD DC 111,144 WA M T I D OR W Y ND SD C A N V UT CO NE KS AZ NM OK TX MN WI MI IA I L IN OH MO AR MS AL GA TN KY FL SC NC WV MD DE VA PA NJ NY CT RI MA VT NH ME LA HI AK Mexico C a n a d a C a n a d a Canada Canada Canada Canada Canada Canada Canada i i N g e r a Gulf of Mexico Gulf o f M e x i c o Gulf of Mexico Canada Gulf of Mexico Sources: Energy Information Administration (EIA), Form EIA-176, "Annual Report of Natural and Supplemental Gas Supply and Disposition," the Office of Fossil Energy, Natural Gas Imports and Exports, and EIA estimates

430

AEOSup ltr to Dear Customer  

Gasoline and Diesel Fuel Update (EIA)

WA WA OR CA ID NV UT AZ NM CO WY MT ND SD NE KS OK TX MN IA MO AR LA WI IL KY IN OH WV TN MS AL GA SC NC VA PA NY VT ME NH MA RI CT NJ DE MD D.C. FL MI Electricity Supply Regions 1 ECAR 2 ERCOT 3 MAAC 4 MAIN 5 MAPP 6 NY 7 NE 8 FL 9 STV 10 SPP 11 NWP 12 RA 13 CNV 13 11 12 2 10 5 9 8 1 6 7 3 AK 15 14 H I 14 AK 15 H I Figure 2. Electricity Market Module (EMM) Regions 1. ECAR = East Central Area Reliability Coordination Agreement 2. ERCOT = Electric Reliability Council of Texas 3. MACC = Mid-Atlantic Area Council 4. MAIN = Mid-America Interconnected Network 5. MAPP = Mid-Continent Area Power Pool 6. NY = Northeast Power Coordinating Council/ New York 7. NE = Northeast Power Coordinating Council/ New England 8. FL = Southeastern Electric Reliability Council/ Florida 9. STV = Southeastern Electric Reliability Council /excluding Florida 10. SPP

431

regionalmaps  

Gasoline and Diesel Fuel Update (EIA)

Specific LNG Terminals Specific LNG Terminals Generic LNG Terminals Pacifi c (9) Moun tain (8) CA (12) AZ/N M (11) W. North Centr al (4) W. South Centr al (7) E. South Centr al (6) E. North Centr al (3) S. Atlan tic (5) FL (10) Mid. Atlan tic (2) New Engl. (1) W. Cana da E. Cana da MacK enzie Alask a Cana da Offsh ore and LNG Mexic o Baha mas Primary Flows Secondary Flows Pipeline Border Crossing Specific LNG Terminals Generic LNG Terminals Figure 6. Coal Supply Regions Source: Energy Information Administration. Office of Integrated Analysis and Forecasting WA ID OR CA NV UT TX OK AR MO LA MS AL GA FL TN SC NC KY VA WV WY CO SD ND MI MN WI IL IN OH MD PA NJ DE CT MA NH VT NY ME RI MT NE IA KS MI AZ NM 500 0 SCALE IN MILES APPALACHIA Northern Appalachia Central Appalachia Southern Appalachia INTERIOR NORTHERN GREAT PLAINS Eastern Interior Western Interior Gulf Lignite Dakota Lignite Western Montana

432

Microsoft Word - figure_13.doc  

Gasoline and Diesel Fuel Update (EIA)

6 6 (Million Cubic Feet) Supplemental Data From Volume To From Volume To CT RI RI MA MA CT VA DC MD DC 42,411 WA M T I D OR W Y ND SD C A N V UT CO NE KS AZ NM OK TX MN WI MI IA I L IN OH MO AR MS AL GA TN KY FL SC NC WV MD DE VA PA NJ NY CT RI MA VT NH ME LA HI AK Mexico C a n a d a C a n a d a Canada Canada Canada Canada Canada Algeria Canada Canada i i N g e r a Gulf of Mexico Gulf o f M e x i c o Gulf of Mexico Canada Gulf of Mexico Sources: Energy Information Administration (EIA), Form EIA-176, "Annual Report of Natural and Supplemental Gas Supply and Disposition," and the Office of Fossil Energy, Natural Gas Imports and Exports. Energy Information Administration / Natural Gas Annual 2006 253,214 690,780 634,185 658,523 134,764 63,063 526,726 121,049 34,531 492,655 101,101 23,154 40,113 1,496,283 68,601

433

U.S. Energy Information Administration | Annual Energy Outlook 2013  

Gasoline and Diesel Fuel Update (EIA)

Annual Energy Outlook 2013 Annual Energy Outlook 2013 Source: U.S. Energy Information Administration, Office of Energy Analysis. U.S. Energy Information Administration / Annual Energy Outlook 2010 213 Appendix F Regional Maps Figure F1. United States Census Divisions Pacific East South Central South Atlantic Middle Atlantic New England West South Central West North Central East North Central Mountain AK WA MT WY ID NV UT CO AZ NM TX OK IA KS MO IL IN KY TN MS AL FL GA SC NC WV PA NJ MD DE NY CT VT ME RI MA NH VA WI MI OH NE SD MN ND AR LA OR CA HI Middle Atlantic New England East North Central West North Central Pacific West South Central East South Central South Atlantic Mountain Source: U.S. Energy Information Administration, Office of Integrated Analysis and Forecasting. Appendix F Regional Maps Figure F1. United States Census Divisions U.S. Energy Information Administration | Annual Energy Outlook 2013

434

NGA_99fin.vp  

Gasoline and Diesel Fuel Update (EIA)

Energy Energy Information Administration / Natural Gas Annual 1999 NJ WY AK AL CA AR CO CT DE FL GA HI ID KS IL IN IA IA KY LA ME MI MA MD MN MS MT MO NE ND OH NV NM NY NH NC OK OR PA RI SC SD TN TX UT VT WA WV WI AZ VA DC Sources: Energy Information Administration (EIA), Form EIA-895, "Monthly Quantity and Value of Natural Gas Report," and the United States Minerals Management Service. None 1-15,000 15,001-100,000 100,001-200,000 200,001-500,000 500,001 and over 4. Marketed Production of Natural Gas in the United States, 1999 (Million Cubic Feet) Figure 5. Marketed Production of Natural Gas in Selected States, 1995-1999 Figure T e x a s L o u i s i a n a O k l a h o m a N e w M e x i c o W y o m i n g C o l o r a d o K a n s a s A l a b a m a A l a s k a C a l i f o r n i a A l l O t h e r S t a t e s 0 1 2 3 4 5 6 7 Trillion Cubic Feet Billion Cubic Meters 95 96 97 98 99 Sources: Energy Information Administration (EIA), Form EIA-895, "Monthly Quantity and Value

435

Microsoft Word - figure_14.doc  

Gasoline and Diesel Fuel Update (EIA)

Egypt Figure 14. Net Interstate Movements, Imports, and Exports of Natural Gas in the United States, 2010 (Million Cubic Feet) Norway India Trinidad/ Tobago Egypt Yemen Japan Interstate Movements Not Shown on Map From Volume To From Volume To CT RI RI MA MA CT VA DC MD DC 53,122 WA M T I D OR W Y ND SD C A N V UT CO NE KS AZ NM OK TX MN WI MI IA I L IN OH MO AR MS AL GA TN KY FL SC NC WV MD DE VA PA NJ NY CT RI MA VT NH ME LA HI AK Mexico C a n a d a C a n a d a Canada Canada Canada Canada Canada Canada Canada Gulf of Mexico Canada Sources: Energy Information Administration (EIA), Form EIA-176, "Annual Report of Natural and Supplemental Gas Supply and Disposition," the Office of Fossil Energy, Natural Gas Imports and Exports, and EIA estimates based on historical data. Energy Information

436

Microsoft Word - Figure_14_15.doc  

Gasoline and Diesel Fuel Update (EIA)

5 5 0.00-2.49 2.50-4.49 4.50-6.49 6.50-8.49 8.50-10.49 10.50+ WA ID MT OR CA NV UT AZ NM CO WY ND SD MN WI NE IA KS MO TX IL IN OH MI OK AR TN WV VA KY MD PA WI NY VT NH MA CT ME RI NJ DC NC SC GA AL MS LA FL HI AK DE 0 2 4 6 8 10 1980 1982 1984 1986 1988 1990 1992 1994 1996 1998 2000 2002 2004 Dollars per Thousand Cubic Feet 0 40 80 120 160 200 240 280 320 360 Dollars per Thousand Cubic Meters Constant Dollars Nominal Dollars Figure 14. Average Price of Natural Gas Delivered to Residential Consumers, 1980-2004 Figure 15. Average City Gate Price of Natural Gas in the United States, 2004 (Dollars per Thousand Cubic Feet) Sources: Nominal dollars: Energy Information Administration (EIA), Form EIA-176, "Annual Report of Natural and Supplemental Gas Supply and Disposition," and Form EIA-910, "Monthly Natural Gas Marketer Survey." Constant dollars: Prices were converted to 2004 dollars using the chain-type price indexes for Gross Domestic Product

437

Slide 1  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Inventory map reflects the non-federally owned SNF and HLW covered by the Nuclear Waste Policy Act Inventory map reflects the non-federally owned SNF and HLW covered by the Nuclear Waste Policy Act 2 Metric Tons Heavy Metal (MTHM) 3 Based on actual data through 2002 , as provided in the RW-859, and projected discharges for 2003-2010 which are rounded to two significant digits. Reflects trans-shipments as of end-2002. End of Year 2010 SNF & HLW Inventories 1 Approximately 64,000 MTHM 2 of Spent Nuclear Fuel (SNF) 3 & 275 High-Level Radioactive Waste (HLW) Canisters CT 1,900 TX 2,000 MD 1,200 VT 610 RI MT WY NE 790 SD ND OK KS 600 TX 2,000 LA 1,200 AR 1,200 IA 480 MN 1,100 WI 1,300 KY TN 1,500 MS 780 AL 3,000 GA 2,400 FL 2,900 NC 3,400 VA 2,400 WV OH 1,100 PA 5,800 ME 540 NJ 2,400 DE MI 2,500 MA 650 NH 480 IN SC 3,900 CO MO 670 IL 8,400 NY 3,300 CA 2,800 AZ 1,900 NM OR 360 NV UT WA 600 ID < 1 Commercial HLW 275 Canisters (~640 MTHM)

438

Table 25  

Gasoline and Diesel Fuel Update (EIA)

89 89 Table 25 Created on: 1/3/2014 3:10:33 PM Table 25. Natural gas home customer-weighted heating degree days, New England Middle Atlantic East North Central West North Central South Atlantic Month/Year/Type of data CT, ME, MA, NH, RI, VT NJ, NY, PA IL, IN, MI, OH, WI IA, KS, MN, MO, ND, NE, SD DE, FL, GA, MD, DC, NC, SC, VA, WV November Normal 702 665 758 841 442 2012 751 738 772 748 527 2013 756 730 823 868 511 % Diff (normal to 2013) 7.7 9.8 8.6 3.2 15.6 % Diff (2012 to 2013) 0.7 -1.1 6.6 16.0 -3.0 November to November Normal 702 665 758 841 442 2012 751 738 772 748 527 2013 756 730 823 868 511 % Diff (normal to 2013) 7.7 9.8 8.6 3.2 15.6 % Diff (2012 to 2013) 0.7 -1.1 6.6 16.0 -3.0

439

Green Power Network: Can I Buy Green Power in My State?  

NLE Websites -- All DOE Office Websites (Extended Search)

Can I Buy Green Power in my State? Community Renewable Energy Development Consumer Protection Large Purchasers of Green Power Can I Buy Green Power in My State? Click on your state below to find out which organizations offer green power in your state. The results will include utility green pricing programs, retail green power products offered in competitive electricity markets, and renewable energy certificate (REC) products sold separate from electricity. For additional information about these distinct products, see our Overview of Green Power Markets. Map of the United States. AK AL AR AZ CA CO CT DC DE FL GA HI IA ID IL IN KS KY LA MA MD ME MI MN MO MS MT NC ND NE NH NJ NM NV NY OH OK OR PA RI SC SD TN TX UT VA VT WA WI WV WY Alabama Alaska Arizona Arkansas California Colorado Connecticut Connecticut Delaware Delaware Florida Georgia Hawaii Idaho Illinois Indiana Iowa Kansas Kentucky Louisiana Maine Maryland Maryland Massachusetts Massachusetts Michigan Minnesota Mississippi Missouri Montana Nebraska Nevada New Hampshire New Hampshire New Jersey New Jersey New Mexico New York North Carolina North Dakota Ohio Oklahoma Oregon Pennsylvania Rhode Island Rhode Island South Carolina South Dakota Tennessee Texas Utah Vermont Vermont Virginia Washington West Virginia Wisconsin Wyoming Washington, DC

440

NGA_99fin.vp  

Gasoline and Diesel Fuel Update (EIA)

Supply Supply 17 Energy Information Administration / Natural Gas Annual 1999 NJ WY AK AL CA AR CO CT DE FL GA HI ID KS IL IN IA IA KY LA ME MI MA MD MN MS MT MO NE ND OH NV NM NY NH NC OK OR PA RI SC SD TN TX UT VT WA WV WI AZ VA DC Sources: Energy Information Administration (EIA), Form EIA-895, "Monthly Quantity and Value of Natural Gas Report," and the United States Minerals Management Service. None 1-15,000 15,001-100,000 100,001-200,000 200,001-500,000 500,001 and over 4. Marketed Production of Natural Gas in the United States, 1999 (Million Cubic Feet) Figure 5. Marketed Production of Natural Gas in Selected States, 1995-1999 Figure T e x a s L o u i s i a n a O k l a h o m a N e w M e x i c o W y o m i n g C o l o r a d o K a n s a s A l a b a m a A l a s k a C a l i f o r n i a A l l O t h e r S t a t e s 0 1 2 3 4 5 6 7 Trillion Cubic Feet Billion Cubic Meters 95 96 97 98 99 Sources: Energy Information Administration (EIA), Form EIA-895, "Monthly Quantity

Note: This page contains sample records for the topic "mn nh nj" from the National Library of EnergyBeta (NLEBeta).
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441

Microsoft Word - figure_13.doc  

Gasoline and Diesel Fuel Update (EIA)

5 5 (Million Cubic Feet) 24,891 2,895 Nigeria WA M T I D OR W Y ND SD C A N V UT CO NE KS AZ NM OK TX MN WI MI IA I L IN OH MO AR MS AL GA TN KY FL SC NC WV MD DE VA PA NJ NY CT RI MA VT NH ME LA HI AK Mexico Algeria C a n a d a C a n a d a Canada Canada Canada Canada Canada Algeria Canada Canada N i g e r i a O m a n Qatar Gulf of Mexico Gulf o f M e x i c o Gulf of Mexico Canada Gulf of Mexico Malaysia 2,986 Sources: Energy Information Administration (EIA), Form EIA-176, "Annual Report of Natural and Supplemental Gas Supply and Disposition," and the Office of Fossil Energy, Natural Gas Imports and Exports. Energy Information Administration / Natural Gas Annual 2005 Supplemental Data From Volume To From Volume To CT RI RI MA MA CT VA DC MD DC 335,380 634,982 664,318 612,297 125,202 33,223 531,868 103,624

442

Influence of the structure on electric and magnetic properties of La{sub 0.8}Na{sub 0.2}Mn{sub 1-x}Co{sub x}O{sub 3} perovskites  

SciTech Connect

The influence of the cobalt substitution for manganese ions in the mixed valence perovskites La{sub 0.8}Na{sub 0.2}Mn{sub 1-x}Co{sub x}O{sub 3} (0=Mn{sup 3+}->Mn{sup 4+} leading to the formation of stable couples Mn{sup 4+}-Co{sup 2+}. Therefore the double-exchange interactions Mn{sup 3+}-O{sup 2-}-Mn{sup 4+} partly vanish and they are replaced by positive superexchange interactions Mn{sup 4+}-O{sup 2-}-Co{sup 2+}, but of a semiconducting character.

Pollert, E. [Institute of Physics, ASCR, CZ-162 53 Prague 6 (Czech Republic)]. E-mail: pollert@fzu.cz; Hejtmanek, J. [Institute of Physics, ASCR, CZ-162 53 Prague 6 (Czech Republic); Jirak, Z. [Institute of Physics, ASCR, CZ-162 53 Prague 6 (Czech Republic); Knizek, K. [Institute of Physics, ASCR, CZ-162 53 Prague 6 (Czech Republic); Marysko, M. [Institute of Physics, ASCR, CZ-162 53 Prague 6 (Czech Republic); Doumerc, J.P. [Institut de Chimie de la Matiere Condensee de Bordeaux, CNRS, 33608 Pessac (France); Grenier, J.C. [Institut de Chimie de la Matiere Condensee de Bordeaux, CNRS, 33608 Pessac (France); Etourneau, J. [Institut de Chimie de la Matiere Condensee de Bordeaux, CNRS, 33608 Pessac (France)

2004-12-01T23:59:59.000Z

443

DOE - Office of Legacy Management -- Standard Oil Development...  

Office of Legacy Management (LM)

Standard Oil Development Co of NJ - NJ 18 FUSRAP Considered Sites Site: STANDARD OIL DEVELOPMENT CO. OF NJ (NJ.18) Eliminated from consideration under FUSRAP Designated Name: Not...

444

Direct evidence of the fermi-energy-dependent formation of Mn interstitials in modulation doped Ga1-yAlyAs/Ga1-xMnxAs/Ga1-yAlyAs heterostructures  

SciTech Connect

Using ion channeling techniques, we investigate the lattice locations of Mn in Ga{sub 1-x}Mn{sub x}As quantum wells between Be-doped Ga{sub 1-y}Al{sub y}As barriers. The earlier results showed that the Curie temperature T{sub C} depends on the growth sequence of the epitaxial layers. A lower T{sub C} was found in heterostructures in which the Ga{sub 1-x}Mn{sub x}As layer is grown after the modulation-doped barrier. Here we provide direct evidence that this reduction in T{sub C} is directly correlated with an increased formation of magnetically inactive Mn interstitials. The formation of interstitials is induced by a shift of the Fermi energy as a result of the transfer of holes from the barrier to the quantum well during the growth.

Yu, K.M.; Walukiewicz, W.; Wojtowicz, T.; Lim, W.L.; Liu, X.; Dobrowolska, M.; Furdyna, J.K.

2004-01-30T23:59:59.000Z

445

Participation of Glutamate-354 of the CP43 Polypeptide in the Ligation of Mn and the Binding of Substrate Water in Photosystem II  

Science Conference Proceedings (OSTI)

In the current X-ray crystallographic structural models of photosystem II, Glu354 of the CP43 polypeptide is the only amino acid ligand of the oxygen-evolving Mn4Ca cluster that is not provided by the D1 polypeptide. To further explore the influence of this structurally unique residue on the properties of the Mn4Ca cluster, the CP43-E354Q mutant of the cyanobacterium Synechocystis sp. PCC 6803 was characterized with a variety of biophysical and spectroscopic methods, including polarography, EPR, X-ray Absorption, FTIR, and mass spectrometry. The kinetics of oxygen release in the mutant were essentially unchanged from those in wild-type. In addition, the oxygen flash-yields exhibited normal period-four oscillations having normal S state parameters, although the yields were lower, correlating with the mutant?s lower steady-state rate (approx. 20percent compared to wild-type). Experiments conducted with H218O showed that the fast and slow phases of substrate water exchange in CP43-E354Q thylakoid membranes were accelerated 8.5- and 1.8-fold, respectively, in the S3 state compared to wild-type. Purified oxygen-evolving CP43-E354Q PSII core complexes exhibited a slightly altered S1 state Mn-EXAFS spectrum, a slightly altered S2 state multiline EPR signal, a substantially altered S2-minus-S1 FTIR difference spectrum, and an unusually long lifetime for the S2 state (> 10 hours) in a substantial fraction of reaction centers. In contrast, the S2 state Mn-EXAFS spectrum was nearly indistinguishable from that of wild-type. The S2-minus-S1 FTIR difference spectrum showed alterations throughout the amide and carboxylate stretching regions. Global labeling with 15N and specific labeling with L-[1-13C]alanine revealed that the mutation perturbs both amide II and carboxylate stretching modes and shifts the symmetric carboxylate stretching modes of the ?-COO? group of D1-Ala344 (the C-terminus of the D1 polypeptide) to higher frequencies by 3 ? 4 cm-1 in both the S1 and S2 states. The EPR and FTIR data implied that 76 -82 percent of CP43-E354Q PSII centers can achieve the S2 state and that most of these can achieve the S3 state, but no evidence for advancement beyond the S3 state was observed in the FTIR data, at least not in a majority of PSII centers. Although the X-ray absorption and EPR data showed that the CP43-E354Q mutation only subtly perturbs the structure and spin state of the Mn4Ca cluster in the S2 state, the FTIR and H218O exchange data show that the mutation strongly influences other properties of the Mn4Ca cluster, altering the response of numerous carboxylate and amide groups to the increased positive charge that develops on the cluster during the S1 to S2 transition and weakening the binding of both substrate water molecules (or water derived ligands), especially the one that exchanges rapidly in the S3 state. The FTIR data provide evidence that CP43-Glu354 coordinates to the Mn4Ca cluster in the S1 state as a bridging ligand between two metal ions, but provide no compelling evidence that this residue changes its coordination mode during the S1 to S2 transition. The H218O exchange data provide evidence that CP43-Glu354 interacts with the Mn ion that ligates the substrate water molecule (or water-derived ligand) that is in rapid exchange in the S3 state.

Service, Rachel; Yano, Junko; McConnell, Iain; Hwang, Hong Jin; Niks, Dimitri; Hille, Russ; Wydrzynski, Tom; Burnap, Robert; Hillier, Warwick; Debus, Richard

2010-09-30T23:59:59.000Z

446

Direct Observation of sp-d Exchange Interactions in Colloidal Mn2+- and Co2+-Doped CdSe Quantum Dots  

SciTech Connect

The defining attribute of a diluted magnetic semiconductor (DMS) is the existence of dopant-carrier magnetic exchange interactions. In this letter, we report the first direct observation of such exchange interactions in colloidal doped CdSe nanocrystals. Doped CdSe quantum dots were synthesized by thermal decomposition of (Me4N)2[Cd4(SePh)10] in the presence of TMCl2 (TM2+ ) Mn2+ or Co2+) in hexadecylamine and were characterized by several analytical and spectroscopic techniques. Using magnetic circular dichroism spectroscopy, successful doping and the existence of giant excitonic Zeeman splittings in both Mn2+- and Co2+-doped wurtzite CdSe quantum dots are demonstrated unambiguously.

Archer, Paul I.; Santangelo, Steven A.; Gamelin, Daniel R.

2007-03-23T23:59:59.000Z

447

MN Center for Renewable Energy: Cellulosic Ethanol, Optimization of Bio-fuels in Internal Combustion Engines, & Course Development for Technicians in These Areas  

DOE Green Energy (OSTI)

This final report for Grant #DE-FG02-06ER64241, MN Center for Renewable Energy, will address the shared institutional work done by Minnesota State University, Mankato and Minnesota West Community and Technical College during the time period of July 1, 2006 to December 30, 2008. There was a no-cost extension request approved for the purpose of finalizing some of the work. The grant objectives broadly stated were to 1) develop educational curriculum to train technicians in wind and ethanol renewable energy, 2) determine the value of cattails as a biomass crop for p