Sample records for mn class ii

  1. Structural And Physical Characterization of Tetranuclear [Mn**II(3)Mn**IV] And [Mn**II(2)Mn**III(2)] Valence-Isomer Manganese Complexes

    SciTech Connect (OSTI)

    Zaleski, C.M.; Weng, T.-C.; Dendrinou-Samara, C.; Alexiou, M.; Kanakaraki, P.; Hsieh, W.-Y.; Kampf, J.; Penner-Hahn, J.E.; Pecoraro, V.L.; Kessissoglou, D.P.

    2009-05-28T23:59:59.000Z

    Two tetranuclear Mn complexes with an average Mn oxidation state of +2.5 have been prepared. These valence isomers have been characterized by a combination of X-ray crystallography, X-ray absorption spectroscopy, and magnetic susceptibility. The Mn{sup II}{sub 3}Mn{sup IV} tetramer has the Mn ions arranged in a distorted tetrahedron, with an S = 6 ground spin state, dominated by ferromagnetic exchange among the manganese ions. The Mn{sup II}{sub 2}Mn{sup III}{sub 2} tetramer also has a distorted tetrahedral arrangement of Mn ions but shows magnetic behavior, suggesting that it is a single-molecule magnet. The X-ray absorption near-edge structure (XANES) spectra for the two complexes are similar, suggesting that, while Mn XANES has sufficient sensitivity to distinguish between trinuclear valence isomers (Alexiou et al. Inorg. Chem. 2003, 42, 2185), similar distinctions are difficult for tetranuclear complexes such as that found in the photosynthetic oxygen-evolving complex.

  2. Class II virus membrane fusion proteins

    SciTech Connect (OSTI)

    Kielian, Margaret [Department of Cell Biology, Albert Einstein College of Medicine, 1300 Morris Park Ave., Bronx, NY 10461 (United States)]. E-mail: kielian@aecom.yu.edu

    2006-01-05T23:59:59.000Z

    Enveloped animal viruses fuse their membrane with a host cell membrane, thus delivering the virus genetic material into the cytoplasm and initiating infection. This critical membrane fusion reaction is mediated by a virus transmembrane protein known as the fusion protein, which inserts its hydrophobic fusion peptide into the cell membrane and refolds to drive the fusion reaction. This review describes recent advances in our understanding of the structure and function of the class II fusion proteins of the alphaviruses and flaviviruses. Inhibition of the fusion protein refolding reaction confirms its importance in fusion and suggests new antiviral strategies for these medically important viruses.

  3. Comparison of the EXAFS Spectra of Heteronuclear MnCa/Sr Model Complexes to the Oxygen-Evolving Mn(4)Ca Complex of Photosystem II

    SciTech Connect (OSTI)

    Mishra, A.; Yano, J.; Pushkar, Y.; Abboud, K.A.; Yachandra, V.K.; Christou, G.

    2009-06-03T23:59:59.000Z

    Heterometallic Mn-Ca and Mn-Sr complexes have been prepared and employed as model complexes for Ca and Sr EXAFS spectral comparisons with the Oxygen-Evolving Complex (OEC) of Photosystem II (PS II); these have revealed similarities that support the presence of at least one O atom bridge between the Mn and Ca/Sr in the OEC.

  4. Total synthesis of Class II and Class III Galbulimima Alkaloids

    E-Print Network [OSTI]

    Tjandra, Meiliana

    2010-01-01T23:59:59.000Z

    I. Total Synthesis of All Class III Galbulimima Alkaloids We describe the total synthesis of (+)- and (-)-galbulimima alkaloid 13, (-)-himgaline anad (-)-himbadine. The absolute stereochemistry of natural (-)-galbulimima ...

  5. DOI: 10.1002/ejic.200700164 Chlorido-Bridged MnII

    E-Print Network [OSTI]

    Gao, Song

    geometry sharing an equatorial-to-axial edge with parallel equatorial planes. The hydrogen bonds be,[3] dicyanamide,[4] and car- boxylate.[5] Ferromagnetic exchange coupling among these MnII compounds

  6. Electronic Structure and Oxidation State Changes in the Mn (4) Ca Cluster of Photosystem II

    SciTech Connect (OSTI)

    Yano, J.; Pushkar, Y.; Messinger, J.; Bergmann, U.; Glatzel, P.; Yachandra, V.K.; /SLAC

    2012-08-17T23:59:59.000Z

    Oxygen-evolving complex (Mn{sub 4}Ca cluster) of Photosystem II cycles through five intermediate states (S{sub i}-states, i = 0-4) before a molecule of dioxygen is released. During the S-state transitions, electrons are extracted from the OEC, either from Mn or alternatively from a Mn ligand. The oxidation state of Mn is widely accepted as Mn{sub 4}(III{sub 2},IV{sub 2}) and Mn{sub 4}(III,IV{sub 3}) for S{sub 1} and S{sub 2} states, while it is still controversial for the S{sub 0} and S{sub 3} states. We used resonant inelastic X-ray scattering (RIXS) to study the electronic structure of Mn{sub 4}Ca complex in the OEC. The RIXS data yield two-dimensional plots that provide a significant advantage by obtaining both K-edge pre-edge and L-edge-like spectra (metal spin state) simultaneously. We have collected data from PSII samples in the each of the S-states and compared them with data from various inorganic Mn complexes. The spectral changes in the Mn 1s2p{sub 3/2} RIXS spectra between the S-states were compared to those of the oxides of Mn and coordination complexes. The results indicate strong covalency for the electronic configuration in the OEC, and we conclude that the electron is transferred from a strongly delocalized orbital, compared to those in Mn oxides or coordination complexes. The magnitude for the S{sub 0} to S{sub 1}, and S{sub 1} to S{sub 2} transitions is twice as large as that during the S{sub 2} to S{sub 3} transition, indicating that the electron for this transition is extracted from a highly delocalized orbital with little change in charge density at the Mn atoms.

  7. Electronic Structure and Oxidation State Changes in the Mn4Ca Cluster of Photosystem II

    SciTech Connect (OSTI)

    Yano, Junko; Pushkar, Yulia; Messinger, Johannes; Bergmann, Uwe; Glatzel, Pieter; Yachandra, Vittal K

    2007-08-03T23:59:59.000Z

    Oxygen-evolving complex (Mn4Ca cluster) of Photosystem II cycles through five intermediate states (Si-states, i =0-4) before a molecule of dioxygen is released. During the S-state transitions, electrons are extracted from the OEC, either from Mn or alternatively from a Mn ligand. The oxidation state of Mn is widely accepted as Mn4(III2,IV2) and Mn4(III,IV3) for S1 and S2 states, while it is still controversial for the S0 and S3 states. We used resonant inelastic X-ray scattering (RIXS) to study the electronic structure of Mn4Ca complex in the OEC. The RIXS data yield two-dimensional plots that provide a significant advantage by obtaining both K-edge pre-edge and L-edge-like spectra (metal spin state) simultaneously. We have collected data from PSII samples in the each of the S-states and compared them with data from various inorganic Mncomplexes. The spectral changes in the Mn 1s2p3/2 RIXS spectra between the S-states were compared to those of the oxides of Mn and coordination complexes. The results indicate strong covalency for the electronic configuration in the OEC, and we conclude that the electron is transferred from a strongly delocalized orbital, compared to those in Mn oxides or coordination complexes. The magnitude for the S0 to S1, and S1 to S2 transitions is twice as large as that during the S2 to S3 transition, indicating that the electron for this transition is extracted from a highly delocalized orbital with little change in charge density at the Mn atoms.

  8. High-Resolution Mn EXAFS of the Oxygen-Evolving Complex inPhotosystem II: Structural Implications for the Mn4Ca Cluster

    SciTech Connect (OSTI)

    Yano, Junko; Pushkar, Yulia; Glatzel, Pieter; Lewis, Azul; Sauer,Kenneth; Messinger, Johannes; Bergmann, Uwe; Yachandra, Vittal

    2005-09-06T23:59:59.000Z

    The biological generation of oxygen by the oxygen-evolving complex in photosystem II (PS II) is one of natures most important reactions. The recent X-ray crystal structures, while limited by resolutions of 3.2 to 3.5 A, have located the electron density associated with the Mn4Ca complex within the multi-protein PS II complex. Detailed structures critically depend on input from spectroscopic techniques such as EXAFS and EPR/ENDOR, as the XRD resolution does not allow for accurate determination of the position of Mn/Ca or the bridging and terminal ligand atoms. The number and distances of Mn-Mn/Ca/ligand interactions determined from EXAFS provide important constraints for the structure of the Mn cluster. Here we present data from a high-resolution EXAFS method using a novel multi-crystal monochromator that show three short Mn-Mn distances between 2.7 and 2.8 A and hence the presence of three di-mu-oxobridged units in the Mn4Ca cluster. This result imposes clear limitations on the proposed structures based on spectroscopic and diffraction data and provides input for refining such structures.

  9. Cathepsin S regulates class II MHC processing in human CD4+ HLA-DR+ T cells

    E-Print Network [OSTI]

    Ploegh, Hidde

    Although it has long been known that human CD4+ T cells can express functional class II MHC molecules, the role of lysosomal proteases in the T cell class II MHC processing and presentation pathway is unknown. Using CD4+ ...

  10. Diversity of Mn oxides produced by Mn(II)-oxidizing fungi. | EMSL

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  11. Calcium EXAFS establishes the Mn-Ca cluster in the oxygen-evolving complex of Photosystem II

    SciTech Connect (OSTI)

    Cinco, Roehl M.; McFarlane Holman, Karen L.; Robblee, John H.; Yano, Junko; Pizarro, Shelly A.; Bellacchio, Emanuele; Sauer, Kenneth; Yachandra, Vittal K.

    2002-08-02T23:59:59.000Z

    The proximity of Ca to the Mn cluster of the photosynthetic water-oxidation complex is demonstrated by X-ray absorption spectroscopy. We have collected EXAFS data at the Ca K-edge using active PS II membrane samples that contain approximately 2 Ca per 4 Mn. These samples are much less perturbed than previously investigated Sr-substituted samples, which were prepared subsequent to Ca depletion. The new Ca EXAFS clearly shows backscattering from Mn at 3.4 angstroms, a distance that agrees with that surmised from previously recorded Mn EXAFS. This result is also consistent with earlier related experiments at the Sr K-edge, using samples that contained functional Sr, that show Mn is {approx}; 3.5 angstroms distant from Sr. The totality of the evidence clearly advances the notion that the catalytic center of oxygen evolution is a Mn-Ca heteronuclear cluster.

  12. Performance assessment for the class L-II disposal facility

    SciTech Connect (OSTI)

    NONE

    1997-03-01T23:59:59.000Z

    This draft radiological performance assessment (PA) for the proposed Class L-II Disposal Facility (CIIDF) on the Oak Ridge Reservation (ORR) has been prepared to demonstrate compliance with the requirements of the US Department of Energy Order 5820.2A. This PA considers the disposal of low-level radioactive wastes (LLW) over the operating life of the facility and the long-term performance of the facility in providing protection to public health and the environment. The performance objectives contained in the order require that the facility be managed to accomplish the following: (1) Protect public health and safety in accordance with standards specified in environmental health orders and other DOE orders. (2) Ensure that external exposure to the waste and concentrations of radioactive material that may be released into surface water, groundwater, soil, plants, and animals results in an effective dose equivalent (EDE) that does not exceed 25 mrem/year to a member of the public. Releases to the atmosphere shall meet the requirements of 40 CFR Pt. 61. Reasonable effort should be made to maintain releases of radioactivity in effluents to the general environment as low as reasonably achievable. (1) Ensure that the committed EDEs received by individual who inadvertently may intrude into the facility after the loss of active institutional control (100 years) will not exceed 100 mrem/year for continuous exposure of 500 mrem for a single acute exposure. (4) Protect groundwater resources, consistent with federal, state, and local requirements.

  13. E-Print Network 3.0 - association class ii Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Waterloo Collection: Computer Technologies and Information Sciences 55 SOLAR PHYSICS (SOLA) Dear Author(s), Summary: . Out of 59 type IIs, 26 events are associated with C-class...

  14. Structure and Magnetic Ordering of a 2-D MnII(TCNE)I(OH2) (TCNE = tetracyanoethylene) Organic-based Magnet (Tc = 171 K)

    SciTech Connect (OSTI)

    S Lapidus; A McConnell; P Stephens; J Miller

    2011-12-31T23:59:59.000Z

    Mn{sup II}(TCNE)I(OH{sub 2}) was isolated from the reaction of tetracyanoethylene (TCNE) and MnI{sub 2}(THF){sub 3}, and has a 2-D structure possessing an unusual, asymmetric bonded {mu}{sub 4}-[TCNE]{sup {sm_bullet}-}. Direct antiferromagnetic coupling between the S = 5/2 Mn{sup II} and S = 1/2 [TCNE]{sup {sm_bullet}-} leads to magnetic ordering as a canted antiferromagnet at a T{sub c} of 171 K.

  15. Efeitos do Jasper Jumper e do aparelho de protração mandibular no tratamento da má oclusão de classe II.

    E-Print Network [OSTI]

    Rafael Pinelli Henriques

    2008-01-01T23:59:59.000Z

    ??O objetivo deste estudo foi comparar os efeitos do tratamento da má oclusão de Classe II por meio do Aparelho de Protração Mandibular (APM) e… (more)

  16. Contributions of the S100A9 C-Terminal Tail to High-Affinity Mn(II) Chelation by the Host-Defense Protein Human Calprotectin

    E-Print Network [OSTI]

    Nolan, Elizabeth M.

    Human calprotectin (CP) is an antimicrobial protein that coordinates Mn(II) with high affinity in a Ca(II)-dependent manner at an unusual histidine-rich site (site 2) formed at the S100A8/S100A9 dimer interface. We present ...

  17. Oxidation State Changes of the Mn(4)Ca Cluster in Photosystem II

    SciTech Connect (OSTI)

    Yano, J.; Yachandra, V.K.

    2009-06-04T23:59:59.000Z

    A detailed electronic structure of the Mn{sub 4}Ca cluster is required before two key questions for understanding the mechanism of photosynthetic water oxidation can be addressed. They are whether all four oxidizing equivalents necessary to oxidize water to O{sub 2} accumulate on the four Mn ions of the oxygen-evolving complex, or do some ligand-centered oxidations take place before the formation and release of O{sub 2} during the S{sub 3} {yields} [S{sub 4}] {yields} S{sub 0} transition, and what are the oxidation state assignments for the Mn during S-state advancement. X-ray absorption and emission spectroscopy of Mn, including the newly introduced resonant inelastic X-ray scattering spectroscopy have been used to address these questions. The present state of understanding of the electronic structure and oxidation state changes of the Mn{sub 4}Ca cluster in all the S-states, particularly in the S{sub 2} to S{sub 3} transition, derived from these techniques is described in this review.

  18. Electronic Structure of the Mn(4)Ca Cluster in the Oxygen-Evolving Complex of Photosystem Ii Studied By Resonant Inelastic X-Ray Scattering

    SciTech Connect (OSTI)

    Yano, J.; Pushkar, Y.; Messinger, J.; Bergmann, U.; Glatzel, P.; Yachandra, V.K.

    2009-06-04T23:59:59.000Z

    Oxygen-evolving complex (Mn{sub 4}Ca cluster) of Photosystem II cycles through five intermediate states (S{sub i}-states, i=0--4) before a molecule of dioxygen is released. During the S-state transitions, electrons are extracted from the OEC, either from Mn or alternatively from a Mn ligand. The oxidation state of Mn is widely accepted as Mn{sub 4}(III{sub 2},IV{sub 2}) and Mn{sub 4}(III,IV{sub 3}) for S{sub 1} and S{sub 2} states, while it is still controversial for the S{sub 0} and S{sub 3} states. We used resonant inelastic X-ray scattering (RIXS) to study the electronic structure of Mn{sub 4}Ca complex in the OEC. The RIXS data yield two-dimensional plots that provide a significant advantage by obtaining both K-edge pre-edge and L-edge-like spectra simultaneously. The second energy dimension separates the pre-edge (1s to 3d) transitions from the main K-edge (1s to 4p), and thus more precise analysis is possible. The 1s2p RIXS final state electron configuration along the energy transfer axis is identical to conventional L-edge absorption spectroscopy and the RIXS spectra are therefore sensitive to the metal spin state. We have collected data from PS II samples in the each of the S-states and compared them with data from various inorganic Mn complexes. The spectral changes in the Mn 1s2p{sub 3/2} RIXS spectra between the S-states are small compared to those of the oxides of Mn and coordination complexes. The results indicate strong covalency for the electronic configuration in the OEC, and we conclude that the electron is transferred from a strongly delocalized orbital, compared to those in Mn oxides or coordination complexes. The magnitude for the S{sub 0} to S{sub 1}, and S{sub 1} to S{sub 2} transitions is twice as large as that during the S{sub 2} to S{sub 3} transition, indicating that the electron for this transition is extracted from a highly delocalized orbital with little change in charge density at the Mn atoms. The RIXS spectra of S{sub 0} and S{sub 3} states also showed characteristic features which were not clear from the K-edge spectroscopy.

  19. Polarized X-Ray Absorption Spectroscopy of Single-Crystal Mn(V) Complexes Relevant to the Oxygen-Evolving Complex of Photosystem II

    SciTech Connect (OSTI)

    Yano, J.K.; Robblee, J.; Pushkar, Y.; Marcus, M.A.; Bendix, J.; Workman, J.M.; Collins, T.J.; Solomon, E.I.; George, S.D.; Yachandra, V.K.; /LBL, Berkeley /Copenhagen U. /Stanford U., Chem. Dept. /SLAC, SSRL

    2007-10-16T23:59:59.000Z

    High-valent Mn-oxo species have been suggested to have a catalytically important role in the water splitting reaction which occurs in the Photosystem II membrane protein. In this study, five- and six-coordinate mononuclear Mn(V) compounds were investigated by polarized X-ray absorption spectroscopy in order to understand the electronic structure and spectroscopic characteristics of high-valent Mn species. Single crystals of the Mn(V)-nitrido and Mn(V)-oxo compounds were aligned along selected molecular vectors with respect to the X-ray polarization vector using X-ray diffraction. The local electronic structure of the metal site was then studied by measuring the polarization dependence of X-ray absorption near-edge spectroscopy (XANES) pre-edge spectra (1s to 3d transition) and comparing with the results of density functional theory (DFT) calculations. The Mn(V)-nitrido compound, in which the manganese is coordinated in a tetragonally distorted octahedral environment, showed a single dominant pre-edge peak along the MnN axis that can be assigned to a strong 3dz2-4pz mixing mechanism. In the square pyramidal Mn(V)-oxo system, on the other hand, an additional peak was observed at 1 eV below the main pre-edge peak. This component was interpreted as a 1s to 3dxz,yz transition with 4px,y mixing, due to the displacement of the Mn atom out of the equatorial plane. The XANES results have been correlated to DFT calculations, and the spectra have been simulated using a TD (time-dependent)-DFT approach. The relevance of these results to understanding the mechanism of the photosynthetic water oxidation is discussed.

  20. Solid-State 55Mn NMR Spectroscopy of bis(?-oxo)dimanganese(IV) [Mn2O2(salpn)2], a Model for the Oxygen Evolving Complex in Photosystem II

    SciTech Connect (OSTI)

    Ellis, Paul D.; Sears, Jesse A.; Yang, Ping; Dupuis, Michel; Boron, Ted; Pecoraro, Vince; Stich, Troy; Britt, R. David; Lipton, Andrew S.

    2010-12-01T23:59:59.000Z

    Given the obvious global energy needs, it has become imperative to develop a catalytic process for converting water to molecular oxygen and protons. Many have sought to understand the details of photosynthesis and in particular the water splitting reaction to help in the development of the appropriate catalysis.1-3 While the scientific community has made great strides towards this goal, it has fallen short at the critical stage of the determination of the structure associated with the oxygen evolving complex (OEC) within photosystem II (PSII).4,5 Despite the existence of x-ray structures of PSII,6-8 the best data we have for the structure of the OEC comes from models derived from EPR and EXAFS measurements.9-14 This experimental situation has led to collaborations with theoreticians to enable the development of models for the structure of the OEC where the experimental observables (EXAFS and magnetic resonance parameters) serve as constraints to the theoretical calculations. Of particular interest to this study is the observation of the S1 state of the Kok cycle15 where the core of the OEC can be described as a tetranuclear manganese cluster composed of Mn4OxCa. The simplest model for the OEC can be thought of as two Mn-pairs and a Ca2+ where each Mn-pair is antiferromagnetically coupled to its partner. We utilize the term "pair" to describe the Mn atoms within the OEC with the same oxidation state, which for the S1 state is (Mn2(III, III) and Mn2(IV, IV)).16 It is unclear as to the degree of interaction between the pairs as well as the role of the Ca2+. At cryogenic temperatures the S1 state of the OEC is diamagnetic and in principle amenable to solid-state NMR experiments.

  1. MnII (TCNE)3/2(I3)1/2 - A 3-D Network-structured Organic-based Magnet and Comparison to a 2-D Analog

    SciTech Connect (OSTI)

    Stone, K.; Stephens, P; McConnell, A; Shurdha, E; Pokhodnya, K; Miller, J

    2010-01-01T23:59:59.000Z

    Mn{sup II}(TCNE){sub 3/2}(I{sub 3}){sub 1/2} and Mn{sup II}(TCNE)[C{sub 4}(CN){sub 8}]{sub 1/2} [tetracyanoethylene (TCNE)] are organic-based magnets with 3D and 2D extended network structures with vastly different magnetic behavior. They have similar ferrimagnetic coupled layers of Mn{sup II}(TCNE){sup {lg_bullet}-} with different interlayer couplings, which lead, respectively, to net ferrimagnetic (T{sub c} = 171 K) and antiferromagnetic (T{sub c} = 68 K) order.

  2. Estudo comparativo dos efeitos do tratamento da má oclusão de Classe II, 1ª divisão com os aparelhos Jasper Jumper e Bionator, associados ao aparelho fixo.

    E-Print Network [OSTI]

    Leniana Santos Neves

    2007-01-01T23:59:59.000Z

    ??O objetivo deste estudo foi comparar os efeitos do tratamento da má oclusão de Classe II, 1ª divisão por meio dos aparelhos Jasper Jumper e… (more)

  3. Structural Basis for Activation of Class Ib Ribonucleotide Reductase

    SciTech Connect (OSTI)

    Boal, Amie K.; Cotruvo, Jr., Joseph A.; Stubbe, JoAnne; Rosenzweig, Amy C. (MIT); (NWU)

    2010-12-03T23:59:59.000Z

    The class Ib ribonucleotide reductase of Escherichia coli can initiate reduction of nucleotides to deoxynucleotides with either a Mn{sub 2}{sup III}-tyrosyl radical (Y{sm_bullet}) or a Fe{sub 2}{sup III}-Y{sm_bullet} cofactor in the NrdF subunit. Whereas Fe{sub 2}{sup III}-Y{sm_bullet} can self-assemble from Fe{sub 2}{sup II}-NrdF and O{sub 2}, activation of Mn{sub 2}{sup II}-NrdF requires a reduced flavoprotein, NrdI, proposed to form the oxidant for cofactor assembly by reduction of O{sub 2}. The crystal structures reported here of E. coli Mn{sub 2}{sup II}-NrdF and Fe{sub 2}{sup II}-NrdF reveal different coordination environments, suggesting distinct initial binding sites for the oxidants during cofactor activation. In the structures of Mn{sub 2}{sup II}-NrdF in complex with reduced and oxidized NrdI, a continuous channel connects the NrdI flavin cofactor to the NrdF Mn{sub 2}{sup II} active site. Crystallographic detection of a putative peroxide in this channel supports the proposed mechanism of Mn{sub 2}{sup III}-Y{sm_bullet} cofactor assembly.

  4. anti-class ii antibodies: Topics by E-print Network

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    16 at 4:00 p.m. (Climate Change and comprehensive) Exams I and II are planned as two Dibble, Theodore 308 by popular demand: Addiction II Computer Technologies and Information...

  5. Participation of Glutamate-354 of the CP43 Polypeptide in the Ligation of Mn and the Binding of Substrate Water in Photosystem II

    SciTech Connect (OSTI)

    Service, Rachel; Yano, Junko; McConnell, Iain; Hwang, Hong Jin; Niks, Dimitri; Hille, Russ; Wydrzynski, Tom; Burnap, Robert; Hillier, Warwick; Debus, Richard

    2010-09-30T23:59:59.000Z

    In the current X-ray crystallographic structural models of photosystem II, Glu354 of the CP43 polypeptide is the only amino acid ligand of the oxygen-evolving Mn4Ca cluster that is not provided by the D1 polypeptide. To further explore the influence of this structurally unique residue on the properties of the Mn4Ca cluster, the CP43-E354Q mutant of the cyanobacterium Synechocystis sp. PCC 6803 was characterized with a variety of biophysical and spectroscopic methods, including polarography, EPR, X-ray Absorption, FTIR, and mass spectrometry. The kinetics of oxygen release in the mutant were essentially unchanged from those in wild-type. In addition, the oxygen flash-yields exhibited normal period-four oscillations having normal S state parameters, although the yields were lower, correlating with the mutant?s lower steady-state rate (approx. 20percent compared to wild-type). Experiments conducted with H218O showed that the fast and slow phases of substrate water exchange in CP43-E354Q thylakoid membranes were accelerated 8.5- and 1.8-fold, respectively, in the S3 state compared to wild-type. Purified oxygen-evolving CP43-E354Q PSII core complexes exhibited a slightly altered S1 state Mn-EXAFS spectrum, a slightly altered S2 state multiline EPR signal, a substantially altered S2-minus-S1 FTIR difference spectrum, and an unusually long lifetime for the S2 state (> 10 hours) in a substantial fraction of reaction centers. In contrast, the S2 state Mn-EXAFS spectrum was nearly indistinguishable from that of wild-type. The S2-minus-S1 FTIR difference spectrum showed alterations throughout the amide and carboxylate stretching regions. Global labeling with 15N and specific labeling with L-[1-13C]alanine revealed that the mutation perturbs both amide II and carboxylate stretching modes and shifts the symmetric carboxylate stretching modes of the ?-COO? group of D1-Ala344 (the C-terminus of the D1 polypeptide) to higher frequencies by 3 ? 4 cm-1 in both the S1 and S2 states. The EPR and FTIR data implied that 76 -82 percent of CP43-E354Q PSII centers can achieve the S2 state and that most of these can achieve the S3 state, but no evidence for advancement beyond the S3 state was observed in the FTIR data, at least not in a majority of PSII centers. Although the X-ray absorption and EPR data showed that the CP43-E354Q mutation only subtly perturbs the structure and spin state of the Mn4Ca cluster in the S2 state, the FTIR and H218O exchange data show that the mutation strongly influences other properties of the Mn4Ca cluster, altering the response of numerous carboxylate and amide groups to the increased positive charge that develops on the cluster during the S1 to S2 transition and weakening the binding of both substrate water molecules (or water derived ligands), especially the one that exchanges rapidly in the S3 state. The FTIR data provide evidence that CP43-Glu354 coordinates to the Mn4Ca cluster in the S1 state as a bridging ligand between two metal ions, but provide no compelling evidence that this residue changes its coordination mode during the S1 to S2 transition. The H218O exchange data provide evidence that CP43-Glu354 interacts with the Mn ion that ligates the substrate water molecule (or water-derived ligand) that is in rapid exchange in the S3 state.

  6. Monodisperse porous polymer particles containing macrocyclic ether as a new class of sorbent for SR(II) separation

    SciTech Connect (OSTI)

    Leng, Yuxiao; Bai, Feifei [Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084 (China); Faculty of Chemical Science and Engineering, China University of Petroleum, Beijing 100084 (China); Ye, Gang; Wei, Jichao; Wang, Jianchen; Chen, Jing [Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084 (China)

    2013-07-01T23:59:59.000Z

    Strontium{sup 90} is one of the typical fission products that may be found in high level liquid waste (HLLW). Separation of Sr{sup 90} prior to the vitrification is beneficial to the final treatment of solid radioactive waste. In this study, a new class of sorbent for Sr(II) was developed by loading the macrocyclic ether DtBuCH18C6 into the monodisperse porous polymer particles (MPPPs). The MPPPs are well-known as a promising chromatographic material due to the uniform particle size, porous morphology, good compatibility with organic extractants, and rigid matrix. The structure and micro-morphology of the sorbent particles were characterized. The adsorption behavior towards Sr(II) in HNO{sub 3} media was investigated by both batch and column experiments. High adsorption efficiency and selective separation of Sr(II) was obtained. The sorbent particles can be recycled for at least several times before obvious lose of the adsorption ability. This kind of sorbent possesses the potential to be used for strontium separation in radioactive liquid waste.

  7. Improved Oil Recovery from Upper Jurassic Smackover Carbonates through the Application of Advanced Technologies at Womack Hill Oil Field, Choctaw and Clarke Counties, Eastern Gulf Coastal Plain, Class II

    SciTech Connect (OSTI)

    Mancini, Ernest, A.; Crate, David; Blasingame, Thomas; Major, R.P.; Brown, Lewis; Stafford, Wayne

    2002-11-02T23:59:59.000Z

    The principal objectives of the project were: increasing the productivity and profitability of the Womack Hill Field Unit, thereby extending the economic life of this Class II Reservoir and transferring effectively and in a timely manner the knowledge gained and technology developed from this project to producers who are operating other domestic fields with Class II Reservoirs.

  8. II

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  9. II

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou$0.C. 20545*. . : '* FEB1f\lMUC4cb90,fioml7aa AMY yII

  10. Novel frustrated magnetic lattice based on triangular [Mn3(m3-F)] clusters with tetrazole ligands{

    E-Print Network [OSTI]

    Gao, Song

    Novel frustrated magnetic lattice based on triangular [Mn3(m3-F)] clusters with tetrazole ligands701840a Unprecedented [MnII 3(m3-F)(m-N­N)3] triangular clusters with tetrazole ligands are linked by Mn the tetrazolate ligands, which possess additional N-donor sites for network formation. To our knowledge, [M3(m3-X

  11. On the role of Mn(IV) vacancies in the photoreductive dissolution of hexagonal birnessite

    SciTech Connect (OSTI)

    Kwon, K.D.; Refson, K.; Sposito, G.

    2009-06-01T23:59:59.000Z

    Photoreductive dissolution of layer type Mn(IV) oxides (birnessite) under sunlight illumination to form soluble Mn(II) has been observed in both field and laboratory settings, leading to a consensus that this process is a key driver of the biogeochemical cycling of Mn in the euphotic zones of marine and freshwater ecosystems. However, the underlying mechanisms for the process remain unknown, although they have been linked to the semiconducting characteristics of hexagonal birnessite, the ubiquitous Mn(IV) oxide produced mainly by bacterial oxidation of soluble Mn(II). One of the universal properties of this biogenic mineral is the presence of Mn(IV) vacancies, long-identified as strong adsorption sites for metal cations. In this paper, the possible role of Mn vacancies in photoreductive dissolution is investigated theoretically using quantum mechanical calculations based on spin-polarized density functional theory (DFT). Our DFT study demonstrates unequivocally that Mn vacancies significantly reduce the band-gap energy for hexagonal birnessite relative to a hypothetical vacancy-free MnO{sub 2} and thus would increase the concentration of photo-induced electrons available for Mn(IV) reduction upon illumination of the mineral by sunlight. Calculations of the charge distribution in the presence of vacancies, although not fully conclusive, show a clear separation of photo-induced electrons and holes, implying a slow recombination of these charge-carriers that facilitates the two-electron reduction of Mn(IV) to Mn(II).

  12. Class Pricing

    E-Print Network [OSTI]

    Wernerfelt, Birger

    2008-01-15T23:59:59.000Z

    A contract with K-class pricing divides a large set of goods or services into K classes and assigns a single price to any element of a class. Class pricing can be efficient when several different versions may be traded and ...

  13. Structural Changes in the Mn(4)Ca Cluster And the Mechanism of Photosynthetic Water Splitting

    SciTech Connect (OSTI)

    Pushkar, Y.; Yano, J.; Sauer, K.; Boussac, A.; Yachandra, V.K.

    2009-05-21T23:59:59.000Z

    Photosynthetic water oxidation, where water is oxidized to dioxygen, is a fundamental chemical reaction that sustains the biosphere. This reaction is catalyzed by a Mn{sub 4}Ca complex in the photosystem II (PS II) oxygen-evolving complex (OEC): a multiprotein assembly embedded in the thylakoid membranes of green plants, cyanobacteria, and algae. The mechanism of photosynthetic water oxidation by the Mn{sub 4}Ca cluster in photosystem II is the subject of much debate, although lacking structural characterization of the catalytic intermediates. Biosynthetically exchanged Ca/Sr-PS II preparations and x-ray spectroscopy, including extended x-ray absorption fine structure (EXAFS), allowed us to monitor Mn-Mn and Ca(Sr)-Mn distances in the four intermediate S states, S{sub 0} through S{sub 3}, of the catalytic cycle that couples the one-electron photochemistry occurring at the PS II reaction center with the four-electron water-oxidation chemistry taking place at the Mn{sub 4}Ca(Sr) cluster. We have detected significant changes in the structure of the complex, especially in the Mn-Mn and Ca(Sr)-Mn distances, on the S{sub 2}-to-S{sub 3} and S{sub 3}-to-S{sub 0} transitions. These results implicate the involvement of at least one common bridging oxygen atom between the Mn-Mn and Mn-Ca(Sr) atoms in the O-O bond formation. Because PS II cannot advance beyond the S{sub 2} state in preparations that lack Ca(Sr), these results show that Ca(Sr) is one of the critical components in the mechanism of the enzyme. The results also show that Ca is not just a spectator atom involved in providing a structural framework, but is actively involved in the mechanism of water oxidation and represents a rare example of a catalytically active Ca cofactor.

  14. Structural Changes in the Mn4Ca Cluster and the Mechanism of Photosynthetic Water Splitting

    SciTech Connect (OSTI)

    Pushkar, Y.; Yano, J.; Sauer, K.; Boussac, A.; Yachandra, V.K.

    2007-10-25T23:59:59.000Z

    Photosynthetic water oxidation, where water is oxidized to dioxygen, is a fundamental chemical reaction that sustains the biosphere. This reaction is catalyzed by a Mn4Ca complex in the photosystem II (PS II) oxygen-evolving complex (OEC): a multiproteinassembly embedded in the thylakoid membranes of green plants, cyanobacteria, and algae. The mechanism of photosynthetic water oxidation by the Mn4Ca cluster in photosystem II is the subject of much debate, although lacking structural characterization of the catalytic intermediates. Biosynthetically exchanged Ca/Sr-PS II preparations and x-ray spectroscopy, including extended x-ray absorption fine structure (EXAFS), allowed us to monitor Mn-Mn and Ca(Sr)-Mn distances in the four intermediate S states, S0 through S3, of the catalytic cycle that couples the one-electron photochemistry occurring at the PS II reaction center with the four-electron water-oxidation chemistry taking place at the Mn4Ca(Sr) cluster. We have detected significant changes in the structure of the complex, especially in the Mn-Mn and Ca(Sr)-Mn distances, on the S2-to-S3 and S3-to-S0 transitions. These results implicate the involvement of at least one common bridging oxygen atom between the Mn-Mn and Mn-Ca(Sr) atoms in the O-O bond formation. Because PS II cannot advance beyond the S2 state in preparations that lack Ca(Sr), these results show that Ca(Sr) is one of the critical components in the mechanism of the enzyme. The results also show that Ca is not just a spectator atom involved in providing a structural framework, but is actively involved in the mechanism of water oxidation and represents a rare example of a catalytically active Ca cofactor.

  15. The helium abundances in HgMn and normal stars

    E-Print Network [OSTI]

    M. M. Dworetsky

    2004-07-26T23:59:59.000Z

    The parameter-free model of diffusion in the atmospheres of HgMn stars (Michaud 1986; Michaud et al 1979) predicts that helium should sink below the He II ionization zone in order that diffusion of other elements may take place, and that all HgMn stars should have deficits of helium in their photospheres, with a minimum deficit of 0.3 dex. In this study, the Smith & Dworetsky (1993) sample of HgMn stars and normal comparison stars is examined, and the helium abundances determined by spectrum synthesis using echelle spectra taken at Lick Observatory and the AAT. The prediction is confirmed; all HgMn stars are deficient in He by as much as 1.5 dex. Also, two HgMn stars, HR7361 and HR7664, show clear evidence of helium stratification.

  16. Magnetic field-induced phase transformation and variant reorientation in Ni2MnGa and NiMnCoIn magnetic shape memory alloys

    E-Print Network [OSTI]

    Karaca, Haluk Ersin

    2009-05-15T23:59:59.000Z

    The purpose of this work is to reveal the governing mechanisms responsible for the magnetic field-induced i) martensite reorientation in Ni2MnGa single crystals, ii) stress-assisted phase transformation in Ni2MnGa single crystals and iii) phase...

  17. Semimetallic antiferromagnetism in the half-Heusler compound CuMnSb Ruben Weht,2

    E-Print Network [OSTI]

    Pickett, Warren

    CuMnSb, the first antiferromagnet AFM in the Mn-based class of Heuslers and half-Heuslers that contains several conventional and half metallic ferromagnets, shows a peculiar stability of its magnetic order in high magnetic fields. Density functional based studies reveal an unusual nature of its unstable

  18. Understanding and development of combined acoustic and magnetic actuation of Ni?MnGa single crystals

    E-Print Network [OSTI]

    Techapiesancharoenkij, Ratchatee, 1979-

    2007-01-01T23:59:59.000Z

    Ni-Mn-Ga based ferromagnetic shape memory alloys (FSMAs) have emerged as a promising new class of active materials capable of producing a large (several %) magnetic-field-induced strain (MFIS). FSMAs still have several ...

  19. Structural, Electrochemical, and Spectroscopic Investigation of Acetate Bridged Dinuclear Tetrakis-Schiff Base Macrocycles of Mn

    E-Print Network [OSTI]

    Dinolfo, Peter H.

    resembling the oxygen-evolving complex (OEC) in photosystem II and dimanganese catalase enzymes, resulting+ and Zn2LAc+ , the two metal centers are bridged by an acetate ligand. [Mn2LAc](ClO4)·(DMF)0.5, [Mn2LAc for substrate molecules bound to redox active metal centers.5-10 In 1970, Robson showed that dinuclear tetrakis

  20. Polarized Range-Extended X-Ray Absorption Spectroscopy of Oriented Photosystem Ii Membranes in the S (1) State

    SciTech Connect (OSTI)

    Pushkar, Y.; Yano, J.; Glatzel, P.; Messinger, J.; Lewis, A.; Sauer, K.; Bergmann, U.; Yachandra, V.K.

    2009-06-05T23:59:59.000Z

    Detailed information about the orientation of particular Mn-Mn and Mn-Ca vectors in the oxygen evolving complex (OEC) of the Photosystem II in the S{sub 1} state provide a critical starting point for the analysis of the structural changes in the OEC along the catalytic S{sub i}-state cycle. The method of polarized range-extended EXAFS is an important technical development, that allows: (i) resolution of the 2.7 {angstrom} and 2.8 {angstrom} Mn-Mn interactions; (ii) resolution of 3.2 {angstrom} Mn-Mn and 3.4 {angstrom} Mn-Ca; (iii) determination of 2.7 {angstrom}, 2.8 {angstrom}, 3.2 {angstrom} Mn-Mn and 3.4 {angstrom} Mn-Ca vectors orientation relative to the membrane normal.

  1. Advance View Proofs Thermodynamic Description of the Mg-Mn, Al-Mn and Mg-Al-Mn Systems

    E-Print Network [OSTI]

    Medraj, Mamoun

    Advance View Proofs Thermodynamic Description of the Mg-Mn, Al-Mn and Mg-Al-Mn Systems Using-consistent thermodynamic model of the Mg-Mn, Al-Mn and Mg-Al-Mn systems has been developed. The major difference between work on the Al-Mn system that uses the same model for the liquid phase reveals that better agreement

  2. First results from the CALYPSO IRAM-PdBI survey. II. Resolving the hot corino in the Class 0 protostar NGC 1333-IRAS2A

    E-Print Network [OSTI]

    Maury, A J; André, Ph; Maret, S; Gueth, F; Codella, C; Cabrit, S; Testi, L; Bontemps, S

    2014-01-01T23:59:59.000Z

    We investigate the origin of complex organic molecules (COMs) in the gas phase around the low-mass Class~0 protostar NGC1333-IRAS2A, to determine if the COM emission lines trace an embedded disk, shocks from the protostellar jet, or the warm inner parts of the protostellar envelope. In the framework of the CALYPSO (Continuum And Lines in Young ProtoStellar Objects) IRAM Plateau de Bure survey, we obtained large bandwidth spectra at sub-arcsecond resolution towards NGC 1333-IRAS2A. We identify the emission lines towards the central protostar and perform Gaussian fits to constrain the size of the emitting region for each of these lines, tracing various physical conditions and scales. The emission of numerous COMs such as methanol, ethylene glycol, and methyl formate is spatially resolved by our observations. This allows us to measure, for the first time, the size of the COM emission inside the protostellar envelope, finding that it originates from a region of radius 40-100 AU, centered on the NGC 1333-IRAS2A pr...

  3. Finding $\\eta$ Car Analogs in Nearby Galaxies Using Spitzer: II. Identification of An Emerging Class of Extragalactic Self-Obscured Stars

    E-Print Network [OSTI]

    Khan, Rubab; Stanek, K Z; Gerke, Jill

    2014-01-01T23:59:59.000Z

    Understanding the late-stage evolution of the most massive stars such as $\\eta$ Carinae is challenging because no true analogs of $\\eta$ Car have been clearly identified in the Milky Way or other galaxies. In Khan et. al. (2013), we utilized Spitzer IRAC images of $7$ nearby ($\\lesssim4$ Mpc) galaxies to search for such analogs, and found $34$ candidates with flat or red mid-IR spectral energy distributions. Here, in Paper II, we present our characterization of these candidates using multi-wavelength data from the optical through the far-IR. Our search detected no true analogs of $\\eta$ Car, which implies an eruption rate that is a fraction $0.01\\lesssim F \\lesssim 0.19$ of the ccSN rate. This is roughly consistent with each $M_{ZAMS} \\gtrsim 70M_\\odot$ star undergoing $1$ or $2$ outbursts in its lifetime. However, we do identify a significant population of $18$ lower luminosity $\\left(\\log(L/L_\\odot)\\simeq5.5-6.0\\right)$ dusty stars. Stars enter this phase at a rate that is fraction $0.09 \\lesssim F \\lesssim...

  4. Oxygen Atom Transfer and Oxidative Water Incorporation in Cuboidal Mn3MOn Complexes Based on Synthetic, Isotopic Labeling,

    E-Print Network [OSTI]

    Goddard III, William A.

    is performed by the oxygen-evolving center (OEC) of photo- system II (PSII).2 The OEC consists of a Mn4Ca, United States *S Supporting Information ABSTRACT: The oxygen-evolving complex (OEC) of photo- system IIOxygen Atom Transfer and Oxidative Water Incorporation in Cuboidal Mn3MOn Complexes Based

  5. Classes and End of Term Examinations in Case of Typhoon, Disruption of Transportation, etc.

    E-Print Network [OSTI]

    Banbara, Mutsunori

    is lifted, the normal class schedule resumes from the first class in the morning. (ii) If, by 10:00 a.m., the transportation service is rehabilitated or the weather warning is lifted, the normal class schedule resumes from is rehabilitated or the weather warning is lifted, the normal class schedule resumes from the sixth class

  6. Spectroscopic Study of (two-dimensional) Molecule-based Magnets: [MII(TCNE)(NCMe)2][SbF6] (M = Fe Mn Ni)

    SciTech Connect (OSTI)

    C Olson; C Heth; S Lapidus; P Stephens; G Halder; K Pokhodnya

    2011-12-31T23:59:59.000Z

    The M-[TCNE] (M = 3d metal; TCNE = tetracyanoethylene) system is one of the most interesting classes of molecule-based magnets, exhibiting a plethora of compositions and structures (inorganic polymer chains, 2D layers, 3D networks, and amorphous solids) with a wide range of magnetic ordering temperatures (up to 400 K). A systematic study of vibrational (both infrared and, for the first time, Raman) properties of the family of new TCNE-based magnets of M{sup II}(TCNE) (NCMe){sub 2}[SbF{sub 6}] [M = Mn, Fe, Ni] composition is discussed in conjunction with their magnetic behavior and newly resolved crystal structures. The vibrational properties of the isolated TCNE{sup {sm_bullet}-} anion in the paramagnetic Bu{sub 4}N [TCNE{sup {sm_bullet}-}] salt and recently characterized 2D layered magnet Fe{sup II}(TCNE)(NCMe){sub 2}[FeCl{sub 4}] are also reported for comparison. Additionally, a linear correlation between {nu}{sub c=c} (a{sub g}) frequency of the TCNE ligand and its formal charge Z (the spin density on the {pi}* orbital), Z = [1571 - {nu}{sub C=C} (ag)]/154.5 [e], is presented. It is shown that monitoring Z by Raman spectroscopy is of great use in providing information that allows understanding the peculiarity of the superexchange interaction in M-[TCNE] magnets and establishing the structure-magnetic properties correlations in this class of magnetic material.

  7. Structure and magnetic properties of rf thermally plasma synthesized Mn and MnZn ferrite nanoparticles

    E-Print Network [OSTI]

    McHenry, Michael E.

    Structure and magnetic properties of rf thermally plasma synthesized Mn and Mn­Zn ferrite has previously been shown to be a viable route to producing nanocrystalline magnetite and Ni ferrite nanoparticles. In this work nanocrystalline powders of Mn and Mn­Zn ferrites have been synthesized using a 50 k

  8. Class Syllabus (information)

    E-Print Network [OSTI]

    Bailey, Charlotte M

    2014-12-19T23:59:59.000Z

    in class, but it is still your responsibility to learn these topics. Class lesson notes are ... on their personal computers. (Information continued on the next page.) ...

  9. Structural characterization of terrestrial microbial Mn oxides from Pinal Creek, AZ

    SciTech Connect (OSTI)

    Bargar, John; Fuller, Christopher; Marcus, Matthew A.; Brearley, Adrian J.; Perez De la Rosa, M.; Webb, Samuel M.; Caldwell, Wendel A.

    2008-03-19T23:59:59.000Z

    The microbial catalysis of Mn(II) oxidation is believed to be a dominant source of abundant sorption- and redox-active Mn oxides in marine, freshwater, and subsurface aquatic environments. In spite of their importance, environmental oxides of known biogenic origin have generally not been characterized in detail from a structural perspective. Hyporheic zone Mn oxide grain coatings at Pinal Creek, Arizona, a metals-contaminated stream, have been identified as being dominantly microbial in origin and are well studied from bulk chemistry and contaminant hydrology perspectives. This site thus presents an excellent opportunity to study the structures of terrestrial microbial Mn oxides in detail. XRD and EXAFS measurements performed in this study indicate that the hydrated Pinal Creek Mn oxide grain coatings are layer-type Mn oxides with dominantly hexagonal or pseudo-hexagonal layer symmetry. XRD and TEM measurements suggest the oxides to be nanoparticulate plates with average dimensions on the order of 11 nm thick x 35 nm diameter, but with individual particles exhibiting thickness as small as a single layer and sheets as wide as 500 nm. The hydrated oxides exhibit a 10-A basal-plane spacing and turbostratic disorder. EXAFS analyses suggest the oxides contain layer Mn(IV) site vacancy defects, and layer Mn(III) is inferred to be present, as deduced from Jahn-Teller distortion of the local structure. The physical geometry and structural details of the coatings suggest formation within microbial biofilms. The biogenic Mnoxides are stable with respect to transformation into thermodynamically more stable phases over a time scale of at least 5 months. The nanoparticulate layered structural motif, also observed in pure culture laboratory studies, appears to be characteristic of biogenic Mn oxides and may explain the common occurrence of this mineral habit in soils and sediments.

  10. Zn Sorption Mechanisms onto Sheathed Leptothrix Discophora and the Impact of the Nanoparticulate Biogenic Mn Oxide Coating

    SciTech Connect (OSTI)

    Boonfueng, T.; Axe, L; Yee, N; Hahn, D; Ndiba, P

    2009-01-01T23:59:59.000Z

    Zinc sorption on sheathed Leptothrix discophora bacterium, the isolated extracellular polymeric substances (EPS) sheath, and Mn oxide-coated bacteria was investigated with macroscopic and spectroscopic techniques. Complexation with L. discophora was dominated by the outer membrane phosphoryl groups of the phospholipid bilayer while sorption to isolated EPS was dominated by carboxyl groups. Precipitation of nanoparticulate Mn oxide coatings on the cell surface increased site capacity by over twenty times with significant increase in metal sorption. XAS analysis of Zn sorption in the coated system showed Mn oxide phase contributions of 18 to 43% through mononuclear inner-sphere complexes. The coordination environments in coprecipitation samples were identical to those of sorption samples, indicating that, even in coprecipitation, Zn is not incorporated into the Mn oxide structure. Rather, through enzymatic oxidation by L. discophora, Mn(II) is oxidized and precipitated onto the biofilm providing a large surface for metal sequestration. The nanoparticulate Mn oxide coating exhibited significant microporosity (75%) suggesting contributions from intraparticle diffusion. Transient studies conducted over 7 months revealed a 170% increase in Zn loading. However, the intraparticle diffusivity of 10{sup -19} cm{sup 2} s{sup -1} is two orders of magnitude smaller than that for abiotic Mn oxide which we attribute to morphological changes such as reduced pore sizes in the nanoparticulate oxide. Our results demonstrate that the cell-bound Mn oxide particles can sorb significant amounts of Zn over long periods of time representing an important surface for sequestration of metal contaminants.

  11. High-Resolution Structure of the Photosynthetic Mn4Ca Catalyst from X-ray Spectroscopy

    SciTech Connect (OSTI)

    Yachandra, Vittal; Yano, Junko; Kern, Jan; Pushkar, Yulia; Sauer, Kenneth; Glatzel, Pieter; Bergmann, Uwe; Messinger, Johannes; Zouni, Athina; Yachandra, Vittal K.

    2007-08-01T23:59:59.000Z

    The application of high-resolution X-ray spectroscopy methods to study the photosynthetic water oxidizing complex, which contains a unique hetero-nuclear catalytic Mn4Ca cluster, are described. Issues of X-ray damage especially at the metal sites in the Mn4Ca cluster are discussed. The structure of the Mn4Ca catalyst at high-resolution which has so far eluded attempts of determination by X-ray diffraction, EXAFS and other spectroscopic techniques has been addressed using polarized EXAFS techniques applied to oriented PS II membrane preparations and PS II single crystals. A review of how the resolution of traditional EXAFS techniques can be improved, using methods such as range-extended EXAFS is presented, and the changes that occur in the structure of the cluster as it advances through the catalytic cycle are described. X-ray absorption and emission techniques (XANES and K? emission) have been used earlier to determine the oxidation states of the Mn4Ca cluster, and in this report we review the use of X-ray resonant Raman spectroscopy to understand the electronic structure of the Mn4Ca cluster as it cycles through the intermediate S-states.

  12. Plutonium Oxidation and Subsequent Reduction by Mn (IV) Minerals

    SciTech Connect (OSTI)

    KAPLAN, DANIEL

    2005-09-13T23:59:59.000Z

    Plutonium sorbed to rock tuff was preferentially associated with manganese oxides. On tuff and synthetic pyrolusite (Mn{sup IV}O{sub 2}), Pu(IV) or Pu(V) was initially oxidized, but over time Pu(IV) became the predominant oxidation state of sorbed Pu. Reduction of Pu(V/VI), even on non-oxidizing surfaces, is proposed to result from a lower Gibbs free energy of the hydrolyzed Pu(IV) surface species versus that of the Pu(V) or Pu(VI) surface species. This work suggests that despite initial oxidation of sorbed Pu by oxidizing surfaces to more soluble forms, the less mobile form of Pu, Pu(IV), will dominate Pu solid phase speciation during long term geologic storage. The safe design of a radioactive waste or spent nuclear fuel geologic repository requires a risk assessment of radionuclides that may potentially be released into the surrounding environment. Geochemical knowledge of the radionuclide and the surrounding environment is required for predicting subsurface fate and transport. Although difficult even in simple systems, this task grows increasingly complicated for constituents, like Pu, that exhibit complex environmental chemistries. The environmental behavior of Pu can be influenced by complexation, precipitation, adsorption, colloid formation, and oxidation/reduction (redox) reactions (1-3). To predict the environmental mobility of Pu, the most important of these factors is Pu oxidation state. This is because Pu(IV) is generally 2 to 3 orders of magnitude less mobile than Pu(V) in most environments (4). Further complicating matters, Pu commonly exists simultaneously in several oxidation states (5, 6). Choppin (7) reported Pu may exist as Pu(IV), Pu(V), or Pu(VI) oxic natural groundwaters. It is generally accepted that plutonium associated with suspended particulate matter is predominantly Pu(IV) (8-10), whereas Pu in the aqueous phase is predominantly Pu(V) (2, 11-13). The influence of the character of Mn-containing minerals expected to be found in subsurface repository environments on Pu oxidation state distributions has been the subject of much recent research. Kenney-Kennicutt and Morse (14), Duff et al. (15), and Morgenstern and Choppin (16) observed oxidation of Pu facilitated by Mn(IV)-bearing minerals. Conversely, Shaughnessy et al. (17) used X-ray Absorption near-edge spectroscopy (XANES) to show reduction of Pu(VI) by hausmannite (Mn{sup II}Mn{sub 2}{sup III}O{sub 4}) and manganite ({gamma}-Mn{sup III}OOH) and Kersting et al., (18) observed reduction of Pu(VI) by pyrolusite (Mn{sup IV}O{sub 2}). In this paper, we attempt to reconcile the apparently conflicting datasets by showing that Mn-bearing minerals can indeed oxidize Pu, however, if the oxidized species remains on the solid phase, the oxidation step competes with the formation of Pu(IV) that becomes the predominant solid phase Pu species with time. The experimental approach we took was to conduct longer term (approximately two years later) oxidation state analyses on the Pu sorbed to Yucca Mountain tuff (initial analysis reported by Duff et al., (15)) and measure the time-dependant changes in the oxidation state distribution of Pu in the presence of the Mn mineral pyrolusite.

  13. Quantification of corrosion resistance of a new-class of criticality control materials: thermal-spray coatings of high-boron iron-based amorphous metals - Fe49.7Cr17.7Mn1.9Mo7.4W1.6B15.2C3.8Si2.4

    SciTech Connect (OSTI)

    Farmer, J C; Choi, J S; Shaw, C K; Rebak, R; Day, S D; Lian, T; Hailey, P; Payer, J H; Branagan, D J; Aprigliano, L F

    2007-03-28T23:59:59.000Z

    An iron-based amorphous metal, Fe{sub 49.7}Cr{sub 17.7}Mn{sub 1.9}Mo{sub 7.4}W{sub 1.6}B{sub 15.2}C{sub 3.8}Si{sub 2.4} (SAM2X5), with very good corrosion resistance was developed. This material was produced as a melt-spun ribbon, as well as gas atomized powder and a thermal-spray coating. Chromium (Cr), molybdenum (Mo) and tungsten (W) provided corrosion resistance, and boron (B) enabled glass formation. The high boron content of this particular amorphous metal made it an effective neutron absorber, and suitable for criticality control applications. Earlier studies have shown that ingots and melt-spun ribbons of these materials have good passive film stability in these environments. Thermal spray coatings of these materials have now been produced, and have undergone a variety of corrosion testing, including both atmospheric and long-term immersion testing. The modes and rates of corrosion have been determined in the various environments, and are reported here.

  14. Effect of Mn doping on the structural, morphological, optical...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mn doping on the structural, morphological, optical and magnetic properties of indium tin oxide films. Effect of Mn doping on the structural, morphological, optical and magnetic...

  15. Low Wind Speed Turbine Project Phase II: The Application of Medium-Voltage Electrical Apparatus to the Class of Variable Speed Multi-Megawatt Low Wind Speed Turbines; 15 June 2004--30 April 2005

    SciTech Connect (OSTI)

    Erdman, W.; Behnke, M.

    2005-11-01T23:59:59.000Z

    Kilowatt ratings of modern wind turbines have progressed rapidly from 50 kW to 1,800 kW over the past 25 years, with 3.0- to 7.5-MW turbines expected in the next 5 years. The premise of this study is simple: The rapid growth of wind turbine power ratings and the corresponding growth in turbine electrical generation systems and associated controls are quickly making low-voltage (LV) electrical design approaches cost-ineffective. This report provides design detail and compares the cost of energy (COE) between commercial LV-class wind power machines and emerging medium-voltage (MV)-class multi-megawatt wind technology. The key finding is that a 2.5% reduction in the COE can be achieved by moving from LV to MV systems. This is a conservative estimate, with a 3% to 3.5% reduction believed to be attainable once purchase orders to support a 250-turbine/year production level are placed. This evaluation considers capital costs as well as installation, maintenance, and training requirements for wind turbine maintenance personnel. Subsystems investigated include the generator, pendant cables, variable-speed converter, and padmount transformer with switchgear. Both current-source and voltage-source converter/inverter MV topologies are compared against their low-voltage, voltage-source counterparts at the 3.0-, 5.0-, and 7.5-MW levels.

  16. CLASS DESCRIPTIONS CYCLING SERIES

    E-Print Network [OSTI]

    Pittendrigh, Barry

    will utilize concepts from the 50-minute cycling class while going the distance to optimal health. Whether you're an avid cyclist, triathlete, or desire a longer class for a greater challenge, join us for this 75-minute AN URBANATHLETE Are you registered to compete in an adventure race like the Men's Health Urbanathlon, Warrior Dash

  17. An analysis of the effects of Mn{sup 2+} on oxidative phosphorylation in liver, brain, and heart mitochondria using state 3 oxidation rate assays

    SciTech Connect (OSTI)

    Gunter, Thomas E., E-mail: thomas_gunter@urmc.rochester.ed [Department of Biochemistry and Biophysics, University of Rochester School of Medicine and Dentistry, Rochester, NY 14642 (United States); Gerstner, Brent, E-mail: brent_gerstner@urmc.rochester.ed [Department of Biochemistry and Biophysics, University of Rochester School of Medicine and Dentistry, Rochester, NY 14642 (United States); Lester, Tobias, E-mail: Tlester200@gmail.co [Department of Biochemistry and Biophysics, University of Rochester School of Medicine and Dentistry, Rochester, NY 14642 (United States); Wojtovich, Andrew P., E-mail: andrew_wojtovich@urmc.rochester.ed [Department of Pharmacology and Physiology, University of Rochester School of Medicine and Dentistry, Rochester, NY 14642 (United States); Malecki, Jon, E-mail: jon_malecki@urmc.rochester.ed [Department of Biochemistry and Biophysics, University of Rochester School of Medicine and Dentistry, Rochester, NY 14642 (United States); Swarts, Steven G., E-mail: steven_swarts@urmc.rochester.ed [Department of Radiation Oncology, University of Rochester School of Medicine and Dentistry, Rochester, NY 14642 (United States); Brookes, Paul S., E-mail: paul_brookes@urmc.rochester.ed [Department of Pharmacology and Physiology, University of Rochester School of Medicine and Dentistry, Rochester, NY 14642 (United States); Department of Anesthesiology, University of Rochester School of Medicine and Dentistry, Rochester, NY 14642 (United States); Gavin, Claire E., E-mail: candegavin@aol.com; Gunter, Karlene K., E-mail: karlene_gunter@urmc.rochester.ed [Department of Biochemistry and Biophysics, University of Rochester School of Medicine and Dentistry, Rochester, NY 14642 (United States)

    2010-11-15T23:59:59.000Z

    Manganese (Mn) toxicity is partially mediated by reduced ATP production. We have used oxidation rate assays-a measure of ATP production-under rapid phosphorylation conditions to explore sites of Mn{sup 2+} inhibition of ATP production in isolated liver, brain, and heart mitochondria. This approach has several advantages. First, the target tissue for Mn toxicity in the basal ganglia is energetically active and should be studied under rapid phosphorylation conditions. Second, Mn may inhibit metabolic steps which do not affect ATP production rate. This approach allows identification of inhibitions that decrease this rate. Third, mitochondria from different tissues contain different amounts of the components of the metabolic pathways potentially resulting in different patterns of ATP inhibition. Our results indicate that Mn{sup 2+} inhibits ATP production with very different patterns in liver, brain, and heart mitochondria. The primary Mn{sup 2+} inhibition site in liver and heart mitochondria, but not in brain mitochondria, is the F{sub 1}F{sub 0} ATP synthase. In mitochondria fueled by either succinate or glutamate + malate, ATP production is much more strongly inhibited in brain than in liver or heart mitochondria; moreover, Mn{sup 2+} inhibits two independent sites in brain mitochondria. The primary site of Mn-induced inhibition of ATP production in brain mitochondria when succinate is substrate is either fumarase or complex II, while the likely site of the primary inhibition when glutamate plus malate are the substrates is either the glutamate/aspartate exchanger or aspartate aminotransferase.

  18. IMPROVEMENT OF CdMnTe DETECTOR PERFORMANCE BY MnTe PURIFICATION

    SciTech Connect (OSTI)

    Kim, K.H.; Bolotnikov, A.E.; Camarda, G.S.; Tappero, R.; Hossain, A.; Cui, Y.; Yang, G.; Gul, R.; and James, R.B.

    2011-04-25T23:59:59.000Z

    Residual impurities in manganese (Mn) are a big obstacle to obtaining high-performance CdMnTe (CMT) X-ray and gamma-ray detectors. Generally, the zone-refining method is an effective way to improve the material's purity. In this work, we purified the MnTe compounds combining the zone-refining method with molten Te, which has a very high solubility for most impurities. We confirmed the improved purity of the material by glow-discharge mass spectrometry (GDMS). We also found that CMT crystals from a multiply-refined MnTe source, grown by the vertical Bridgman method, yielded better performing detectors.

  19. Mn/DOT County Road Safety Plans

    E-Print Network [OSTI]

    Minnesota, University of

    Roads Program !! Minnesota Central Safety Funds !! Foster safety culture among county stakeholders 41 Mn/DOT County Road Safety Plans CTS Annual Research Conference April 27 & 28, 2010 Howard Preston & Objectives !! Project Overview !! Schedule, Participating Counties, Approach !! Safety Emphasis Areas

  20. Plain Language Training Class

    Broader source: Energy.gov [DOE]

    Registration link: Click Here to RegisterThe link will bring you to the Plain Writing Powerpedia page, where you can register for the class that works for you. Alternatively, please contact Michael...

  1. Plain Language Training Class

    Broader source: Energy.gov [DOE]

    Registration link: Click Here to RegisterThe link will bring you to the Plain Writing Powerpedia page, where you can register for the class that works for you. Alternatively, please contact Michael...

  2. High Mn austenitic stainless steel

    DOE Patents [OSTI]

    Yamamoto, Yukinori (Oak Ridge, TN) [Oak Ridge, TN; Santella, Michael L (Knoxville, TN) [Knoxville, TN; Brady, Michael P (Oak Ridge, TN) [Oak Ridge, TN; Maziasz, Philip J (Oak Ridge, TN) [Oak Ridge, TN; Liu, Chain-tsuan (Knoxville, TN) [Knoxville, TN

    2010-07-13T23:59:59.000Z

    An austenitic stainless steel alloy includes, in weight percent: >4 to 15 Mn; 8 to 15 Ni; 14 to 16 Cr; 2.4 to 3 Al; 0.4 to 1 total of at least one of Nb and Ta; 0.05 to 0.2 C; 0.01 to 0.02 B; no more than 0.3 of combined Ti+V; up to 3 Mo; up to 3 Co; up to 1W; up to 3 Cu; up to 1 Si; up to 0.05 P; up to 1 total of at least one of Y, La, Ce, Hf, and Zr; less than 0.05 N; and base Fe, wherein the weight percent Fe is greater than the weight percent Ni, and wherein the alloy forms an external continuous scale including alumina, nanometer scale sized particles distributed throughout the microstructure, the particles including at least one of NbC and TaC, and a stable essentially single phase FCC austenitic matrix microstructure that is essentially delta-ferrite-free and essentially BCC-phase-free.

  3. Thermochemical generation of hydrogen and oxygen from water. [NaMnO/sub 2/ and TiO/sub 2/

    DOE Patents [OSTI]

    Robinson, P.R.; Bamberger, C.E.

    1980-02-08T23:59:59.000Z

    A thermochemical cyclic process for the production of hydrogen exploits the reaction between sodium manganate (NaMnO/sub 2/) and titanium dioxide (TiO/sub 2/) to form sodium titanate (Na/sub 2/TiO/sub 3/), manganese (II) titanate (MnTiO/sub 3/) and oxygen. The titanate mixture is treated with sodium hydroxide, in the presence of steam, to form sodium titanate, sodium manganate (III), water and hydrogen. The sodium titanate-manganate (III) mixture is treated with water to form sodium manganate (III), titanium dioxide and sodium hydroxide. Sodium manganate (III) and titanium dioxide are recycled following dissolution of sodium hydroxide in water.

  4. Structural and Magnetic Properties of MCl2 (M = Fe, Mn, Co): Acetonitrile Solvates

    SciTech Connect (OSTI)

    Pokhodnya,K.; Bonner, M.; DiPasquale, A.; Rheingold, A.; Her, J.; Stephens, P.; Park, J.; Kennon, B.; Arif, A.; Miller, J.

    2007-01-01T23:59:59.000Z

    M{sup II}Cl{sub 2} (M = Mn, Fe, Co) as their acetonitrile solvates were isolated, and their structural, spectroscopic, and magnetic properties were studied. MCl{sub 2}(NCMe){sub 2} (M = Fe, Mn) form 1-D chains of octahedral M{sup II} ions with four bridging chlorides and two axial MeCN's. The presence of an axial distortion for MFe causes a significant magnetic anisotropy that increases significantly below 150 K; however, {chi}{sub av} [=({chi}{sub {parallel}} + 2{chi}{sub {perpendicular}})/3] almost coincides with the value obtained on a polycrystalline sample. MnCl{sub 2}(NCMe){sub 2} is a paramagnet with a weak antiferromagnetic coupling. Annealing FeCl{sub 2}(NCMe){sub 2} at 55 {sup o}C forms the monosolvate of FeCl{sub 2}(NCMe) composition in which two chains collapse into a double chain with formation of Fe-Cl bonding such that half of the {mu}-Cl's becomes {mu}{sub 3}-Cl's. This material orders magnetically below {Tc} = 4.3 K. For M = Co, paramagnetic tetrahedral [CoCl{sub 3}(NCMe)]{sup -} anions are isolated.

  5. Class Notes FOUNDATION SYSTEMS

    E-Print Network [OSTI]

    Jacobs, Laurence J.

    CEE 6443 Class Notes FOUNDATION SYSTEMS Applied Geotechnical Analysis and Evaluation by Paul W: 404-894-6226; Fax-2281 January 2004 #12;CEE 6443 FOUNDATION SYSTEMS Paul W. Mayne, PhD, P.E. Professor) ! Shallow Foundations ` Spread Footings ` Structural Mats/Rafts ` Deformations (deflections, displacements

  6. Class not > 1% relative

    E-Print Network [OSTI]

    Weston, Ken

    into the Gulf of Mexico (GOM). Knowledge of the composition of this crude oil is instrumental in determining its DWH Crude Neutrals & Bases Organic Acids DWH Crude Neutrals & Bases Organic Acids 20 40 60 800 20 40 Class not > 1% relative abundance Carbon Number DWH Crude Neutrals & Bases Organic Acids DWH Crude

  7. Energy absorption in Ni-Mn-Ga/ polymer composites

    E-Print Network [OSTI]

    Feuchtwanger, Jorge

    2006-01-01T23:59:59.000Z

    In recent years Ni-Mn-Ga has attracted considerable attention as a new kind of actuator material. Off-stoichiometric single crystals of Ni2MnGa can regularly exhibit 6% strain in tetragonal martensites and orthorhombic ...

  8. Theory of weak localization in ferromagnetic (Ga,Mn)As

    E-Print Network [OSTI]

    Garate, Ion; Sinova, Jairo; Jungwirth, T.; MacDonald, A. H.

    2009-01-01T23:59:59.000Z

    We study quantum interference corrections to the conductivity in (Ga,Mn)As ferromagnetic semiconductors using a model with disordered valence-band holes coupled to localized Mn moments through a p-d kinetic-exchange interaction. We find that at Mn...

  9. Modelling Al and Mn in the open ocean

    E-Print Network [OSTI]

    Haak, Hein

    Modelling Al and Mn in the open ocean Marco van Hulten*, Alessandro Tagliabue, Jean-Claude Dutay van Hulten: Modelling Al and Mn in the open ocean 1 #12;Outline Introduction Model of aluminium Constraining dust flux Model of manganese Conclusions Marco van Hulten: Modelling Al and Mn in the open ocean 2

  10. MN4602 Crouch 2004 REASSESSING WEAPON SYSTEM

    E-Print Network [OSTI]

    MN4602 Crouch 2004 REASSESSING WEAPON SYSTEM OPERATIONAL TEST & EVALUATION METHODOLOGIES LTC Thom support assessing a weapon systems true cost and performance characteristics? S1: Can/should cost, operational effectiveness and suitability be assessed independent of one another? S2: Do current test

  11. "MBUF Demo" "Mn Road Fee Test"

    E-Print Network [OSTI]

    Minnesota, University of

    (40 mpg) Electric Vehicle (non-gas powered) State Tax * Federal Tax ** State Tax * Federal Tax"MBUF Demo" "Mn Road Fee Test" "IntelliDrive Connected Vehicles for Safety, Mobility and User Fee Overview Six Months In-Vehicle Data Collection Participant Recruited Equipment Deployed First Odometer

  12. Mn/DOT's Project Peer Review

    E-Print Network [OSTI]

    Minnesota, University of

    and sustain this culture #12;Project Management #12;Recent National Work in Transportation Project ManagementMn/DOT's Project Management Peer Review Creating a Project Management Culture 2010 CTS Research a Peer Review? Why Project Management? ·Improve project delivery performance ­ on time, on budget (an

  13. Photosystem II

    ScienceCinema (OSTI)

    James Barber

    2010-09-01T23:59:59.000Z

    James Barber, Ernst Chain Professor of Biochemistry at Imperial College, London, gives a BSA Distinguished Lecture titled, "The Structure and Function of Photosystem II: The Water-Splitting Enzyme of Photosynthesis."

  14. New classes of Wavelets

    SciTech Connect (OSTI)

    Manchanda, P. [Department of Mathematics, Guru Nanak Dev University, Amritsar (India); Meenakshi [Dev Samaj College for Women, Ferozepur (India)

    2009-07-02T23:59:59.000Z

    Recently Manchanda, Meenakshi and Siddiqi have studied Haar-Vilenkin wavelet and a special type of non-uniform multiresolution analysis. Haar-Vilenkin wavelet is a generalization of Haar wavelet. Motivated by the paper of Gabardo and Nashed we have introduced a class of multiresolution analysis extending the concept of classical multiresolution analysis. We present here a resume of these results. We hope that applications of these concepts to some significant real world problems could be found.

  15. Periodic Trends within a Series of Five-Coordinate Thiolate-Ligated [MII(SMe2N4(tren))]+ (M ) Mn, Fe, Co, Ni, Cu, Zn) Complexes, Including a

    E-Print Network [OSTI]

    Kovacs, Julie

    Periodic Trends within a Series of Five-Coordinate Thiolate-Ligated [MII(SMe2N4(tren))]+ (M ) Mn-ligated complexes [MII (tren)N4SMe2 ]+ (M ) Mn, Fe, Co, Ni, Cu, Zn; tren ) tris(2-aminoethyl)amine) are reported. All of the gem-dimethyl derivatized complexes are monomeric and, with the exception of [NiII (SMe2 N4

  16. Characterization of BoLA class II genes

    E-Print Network [OSTI]

    Sherwood, Sidney James

    1989-01-01T23:59:59.000Z

    ) along with identif ication of BoLA linked markers such as 210H (21 steroid hydroxylase) wi 1 I help in the def init ion of the linkage group. LITERATURE REVIEk) It was in 1936 that Peter Sorer f irst def ined the major histocompatability complex... ? 2 complex. This linkage was confirmed by McDevitt (1965 a 8 b) by typing eleven intra- H ? 2 recombinants as well as segregants of a four point cross involving mouse chromosome 17 loci T (brachyury), tf ( thin-furred) & H-2K and H ? 2D. this led...

  17. Summary of NREL's Recent Class 8 Tractor Trailer Platooning Testing (Presentation)

    SciTech Connect (OSTI)

    Lammert, M.; Kelly, K.; Walkowicz, K.

    2014-08-01T23:59:59.000Z

    This presentation summarizes NREL's recent class 8 tractor trailer platooning testing, including analysis of SAE J1321 Type II fuel consumption testing, fuel consumption improvement, fuel economy and platooning position accuracy.

  18. Experiment Hazard Class 4.4 -Class 4 Lasers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    system as only a class 1 or class 2 equivalent, then the requirement for training and eye exams is waived for "User Mode" only operation. Any other mode of operation of the...

  19. Where Water is Oxidized to Dioxygen: Structure of the Photosynthetic Mn4Ca Cluster from X-ray Spectroscopy

    SciTech Connect (OSTI)

    Yano, Junko; Yano, Junko; Yachandra, Vittal K.

    2007-10-24T23:59:59.000Z

    Light-driven oxidation of water to dioxygen in plants, algae and cyanobacteria iscatalyzed within photosystem II (PS II) by a Mn4Ca cluster. Although the cluster has been studied by many different methods, the structure and the mechanism have remained elusive. X-ray absorption and emission spectroscopy and EXAFS studies have been particularly useful in probing the electronic and geometric structure, and the mechanism of the water oxidation reaction. Recent progress, reviewed here, includes polarized X-ray absorption spectroscopy measurements of PS II single crystals. Analysis of those results has constrained the Mn4Ca cluster geometry to a setof three similar high-resolution structures. The structure of the cluster from the present study is unlike either the 3.0 or 3.5 Angstrom-resolution X-ray structures or other previously proposed models. The differences between the models derived from X-rayspectroscopy and crystallography are predominantly because of damage to the Mn4Ca cluster by X-rays under the conditions used for structure determination by X-ray crystallography. X-ray spectroscopy studies are also used for studying the changes in the structure of the Mn4Ca catalytic center as it cycles through the five intermediate states known as the Si-states (i=0-4). The electronic structure of the Mn4Ca cluster has been studied more recently using resonant inelastic X-ray scattering spectroscopy (RIXS), in addition to the earlier X-ray absorption and emission spectroscopy methods. These studies are revealing that the assignment of formaloxidation states is overly simplistic. A more accurate description should consider the charge density on the Mn atoms that includes the covalency of the bonds and delocalization of the charge over the cluster. The geometric and electronic structure of the Mn4Ca cluster in the S-states derived from X-ray spectroscopy are leading to a detailed understanding of the mechanism of the O-O bond formation during the photosynthetic water splitting process.

  20. Experiment Hazard Class 4.2 - Class 2 Lasers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Controls - Secure work area to prevent unexpected exposure to class 2 laser devices such as alignment tools. Procedural Controls - No formal (written) procedure is...

  1. ,"International Falls, MN Natural Gas Pipeline Imports From Canada...

    U.S. Energy Information Administration (EIA) Indexed Site

    International Falls, MN Natural Gas Pipeline Imports From Canada (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of...

  2. ,"Noyes, MN Natural Gas Pipeline Imports From Canada (MMcf)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Imports From Canada (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Noyes, MN...

  3. ,"Warroad, MN Natural Gas Pipeline Imports From Canada (MMcf...

    U.S. Energy Information Administration (EIA) Indexed Site

    Imports From Canada (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Warroad, MN...

  4. Alignment of micro-crystals of Mn12-acetate and direct observation of single molecules thereof

    E-Print Network [OSTI]

    Seo, Dongmin

    2009-05-15T23:59:59.000Z

    This dissertation focuses on three separate studies. First, magnetization of the Mn12- acetate was studied by low temperature hysteresis loops and DC magnetization data on magnetically aligned Mn12-acetate micro-crystals. Secondly, Mn12-acetate thin...

  5. Depressurization-induced gas production from Class 1 and Class 2 hydrate deposits

    E-Print Network [OSTI]

    Moridis, George J.; Kowalsky, Michael

    2006-01-01T23:59:59.000Z

    hydrate (Class 1W) or gas and hydrate (Class 1G). In Class 1Class 1G (involving gas and hydrate in the HBL). In Class 2JNOC/GSC Mallik 2L-38 Gas Hydrate Research Well, Mackenzie

  6. On the structure of a class of operators

    E-Print Network [OSTI]

    Hamid, Sami

    2005-08-29T23:59:59.000Z

    to thank my family for their love, patience and understand- ing. vi TABLE OF CONTENTS CHAPTER Page I INTRODUCTION AND PRELIMINARIES : : : : : : : : : : : 1 II SOME RESULTS ABOUT THE DUAL ALGEBRAS AGT : : : : 7 III A NEW STRUCTURE THEOREM ABOUT (BCP... : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : 56 VITA : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : 60 1 CHAPTER I INTRODUCTION AND PRELIMINARIES In this dissertation we will study certain classes of operators on a separable, complex, in?nite dimensional Hilbert...

  7. Minnesota Guidestar www.dot.state.mn.us/guidestar

    E-Print Network [OSTI]

    Minnesota, University of

    .dot.state.mn.us/guidestar What is ITS? · Application of technology to improve the safety and efficiency of the transportation system. #12;Minnesota Guidestar www.dot.state.mn.us/guidestar What is ITS? · Traffic Management ­ Signal Systems ­ Ramp Meters · Emergency Response ­ Mobile Data Terminals ­ 911 Dispatch ­ RF Data Networks

  8. Thermal Stability of MnBi Magnetic Materials

    SciTech Connect (OSTI)

    Cui, Jun; Choi, Jung-Pyung; Li, Guosheng; Polikarpov, Evgueni; Darsell, Jens T.; Overman, Nicole R.; Olszta, Matthew J.; Schreiber, Daniel K.; Bowden, Mark E.; Droubay, Timothy C.; Kramer, Matthew J.; Zarkevich, Nikolai; Wang, L. L.; Johnson, Duane D.; Marinescu, Melania; Takeuchi, Ichiro; Huang, Qingzhen; Wu, Hui; Reeve, Hayden; Vuong, Nguyen V.; Liu, J.Ping

    2014-01-01T23:59:59.000Z

    MnBi attracts great attention in recent years for its great potential as permanent magnet materials. It is unique because its coercivity increases with increasing temperature, which makes it a good hard phase for exchange coupling nanocomposite magnet. MnBi phase is difficult to obtain, partly because the reaction between Mn and Bi is peritectic, and partly because Mn is easy to react with oxygen. MnO formation is irreversible and causes degradation to the magnetic properties. In this paper, we report our effort on developing MnBi permanent magnet. High purity MnBi (>90%) can be routinely produced in large quantity. The obtained powder exhibit 74 emu/g saturation magnetization at room temperature with 9 T applied field. After alignment, the powder exhibits 11.6 MGOe, and the sintered bulk magnet exhibit 7.8 MGOe at room temperature. Thermal stability study shows that the MnBi is stable up to 473 K in air.

  9. Thermal stability of MnBi magnetic materials

    SciTech Connect (OSTI)

    Cui, Jinfang [Pacific Northwest National Laboratory; Choi, J. P. [Pacific Northwest National Laboratory; Li, G. [Pacific Northwest National Laboratory; Polikarpov, E. [Pacific Northwest National Laboratory; Darsell, J. [Pacific Northwest National Laboratory; Overman, N. [Pacific Northwest National Laboratory; Olszta, M. [Pacific Northwest National Laboratory; Schreiber, D. [Pacific Northwest National Laboratory; Bowden, M. [Environmental Molecular Sciences Laboratory; Droubay, T. [Pacific Northwest National Laboratory; Kramer, Matthew J. [Ames Laboratory; Zarkevich, Nikolay A. [Ames Laboratory; Wang, L L. [Ames Laboratory; Johnson, Duane D. [Ames Laboratory; Marinescu, M. [Electron Energy Corporation; Takeuchi, I. [University of Maryland; Huang, Q. Z. [National Institute of Standards and Technology; Wu, H. [University of Maryland; Reeve, H. [United Technologies Research Center; Vuong, N. V. [University of Texas; Liu, J P. [University of Texas

    2014-01-27T23:59:59.000Z

    MnBi has attracted much attention in recent years due to its potential as a rare-earth-free permanent magnet material. It is unique because its coercivity increases with increasing temperature, which makes it a good hard phase material for exchange coupling nanocomposite magnets. MnBi phase is difficult to obtain, partly because the reaction between Mn and Bi is peritectic, and partly because Mn reacts readily with oxygen. MnO formation is irreversible and harmful to magnet performance. In this paper, we report our efforts toward developing MnBi permanent magnets. To date, high purity MnBi (>90%) can be routinely produced in large quantities. The produced powder exhibits 74:6 emu g1 saturation magnetization at room temperature with 9 T applied field. After proper alignment, the maximum energy product (BH) max of the powder reached 11.9 MGOe, and that of the sintered bulk magnet reached 7.8 MGOe at room temperature. A comprehensive study of thermal stability shows that MnBi powder is stable up to 473 K in air.

  10. Thermodynamic and transport properties of single-crystal Yb{sub 14}MnSb{sub 11}

    SciTech Connect (OSTI)

    Fisher, I.R.; Wiener, T.A.; Budko, S.L.; Canfield, P.C. [Ames Laboratory and Department of Physics and Astronomy, Iowa State University, Ames, Iowa 50011 (United States)] [Ames Laboratory and Department of Physics and Astronomy, Iowa State University, Ames, Iowa 50011 (United States); Chan, J.Y.; Kauzlarich, S.M. [Department of Chemistry, One Shields Avenue, University of California, Davis, California 95616 (United States)] [Department of Chemistry, One Shields Avenue, University of California, Davis, California 95616 (United States)

    1999-06-01T23:59:59.000Z

    Relatively large (up to 250 mg) single crystals of the intermetallic compound Yb{sub 14}MnSb{sub 11} have been prepared by a flux-growth technique. The results of thermodynamic and transport measurements of these samples are presented. The compound orders ferromagnetically at approximately T{sub C}=53{plus_minus}1K, with a magnetization consistent with the assignment Mn{sup 3+} (3d{sup 4}) and Yb{sup 2+} (4f{sup 14}). The Mn moments are local in nature, with the full effective and saturated moment of the Hund{close_quote}s rule spin-only ground state. The electrical resistivity has a metallic temperature dependence, with only a modest anisotropy. Room-temperature values of the resistivity are relatively high for an intermetallic compound: 1630{plus_minus}160 {mu}{Omega}cm and 1250{plus_minus}130 {mu}{Omega}cm for currents flowing approximately parallel and perpendicular to the {ital c} axis, respectively. There is a distinct loss of spin-disorder scattering in the resistivity at T{sub C}. From the heat capacity, a rough estimation of the magnetic entropy gives {Delta}S{sub M}{approx}12.1 J/mol K, the value in reasonable agreement with the expected {Delta}S{sub M}{approx}R ln 5 from the assignment of these moments. All of these data are consistent with a picture of Mn{sup 3+} local moments being coupled via conduction electrons. To this end, Yb{sub 14}MnSb{sub 11} appears to be analogous to local-moment rare-earth intermetallic compounds, and may point the way toward a class of 3d Kondo lattice compounds. {copyright} {ital 1999} {ital The American Physical Society}

  11. Spectroscopy of Mn atoms isolated in solid {sup 4}He

    SciTech Connect (OSTI)

    Moroshkin, P., E-mail: petr.moroshkin@riken.jp; Lebedev, V.; Weis, A. [Department of Physics, University of Fribourg, Chemin du Musée 3, 1700 Fribourg (Switzerland)

    2014-06-07T23:59:59.000Z

    We present an experimental study of the laser-induced luminescence spectra of Mn atoms in solid helium matrices. We observe transitions of the valence electron and of inner-shell electrons. We find that the Mn-He interaction perturbs the inner-shell transitions to a lesser extent than the valence-electron transitions. The observed lineshapes of the inner-shell transitions of Mn are similar to those of an inner-shell transition in Ba studied earlier. At the same time, they are more strongly perturbed than the corresponding transitions in Au and Cu under the same conditions. We suggest a qualitative explanation of these observations based on the atomic bubble model. Our results also suggest that the inner-shell transitions of Mn in solid He are more strongly perturbed than the same lines of Mn isolated in solid Ar or Kr matrices.

  12. Magnetic Moment Enhancement for Mn7 Cluster on Graphene

    SciTech Connect (OSTI)

    Liu, Xiaojie [Ames Laboratory; Wang, Cai-Zhuang [Ames Laboratory; Lin, Hai-Qing [Beijing Computational Science Research Center; Ho, Kai-Ming [Ames Laboratory

    2014-08-21T23:59:59.000Z

    Mn7 cluster on graphene with different structural motifs and magnetic orders are investigated systematically by first-principles calculations. The calculations show that Mn7 on graphene prefers a two-layer motif and exhibits a ferrimagnetic coupling. The magnetic moment of the Mn7 cluster increases from 5.0 ?B at its free-standing state to about 6.0 ?B upon adsorption on graphene. Mn7 cluster also induces about 0.3 ?B of magnetic moment in the graphene layer, leading to an overall enhancement of 1.3 ?B magnetic moment for Mn7 on graphene. Detail electron transfer and bonding analysis have been carried out to investigate the origin of the magnetic enhancement.

  13. Unraveling the voltage fade mechanism in layer Li-Mn-rich electrode: formation of the tetrahedral cations for spinel conversion

    SciTech Connect (OSTI)

    Mohanty, Debasish [ORNL; Li, Jianlin [ORNL; Abraham, Daniel P [Argonne National Laboratory (ANL); Huq, Ashfia [ORNL; Payzant, E Andrew [ORNL; Wood III, David L [ORNL; Daniel, Claus [ORNL

    2014-01-01T23:59:59.000Z

    Discovery of high-voltage layered lithium-and manganese-rich (LMR) composite oxide electrode has dramatically enhanced the energy density of current Li-ion energy storage systems. However, practical usage of these materials is currently not viable because of their inability to maintain a consistent voltage profile (voltage fading) during subsequent charge-discharge cycles. This report rationalizes the cause of this voltage fade by providing the evidence of layer to spinel-like (LSL) structural evolution pathways in the host Li1.2Mn0.55Ni0.15Co0.1O2 LMR composite oxide. By employing neutron powder diffraction, and temperature dependent magnetic susceptibility, we show that LSL structural rearrangement in LMR oxide occurs through a tetrahedral cation intermediate via: i) diffusion of lithium atoms from octahedral to tetrahedral sites of the lithium layer [(LiLioct LiLitet] which is followed by the dispersal of the lithium ions from the adjacent octahedral site of the metal layer to the tetrahedral sites of lithium layer [LiTM oct LiLitet]; and ii) migration of Mn from the octahedral sites of the transition metal layer to the permanent octahedral site of lithium layer via tetrahedral site of lithium layer [MnTMoct MnLitet MnLioct)]. The findings opens the door to the potential routes to mitigate this atomic restructuring in the high-voltage LMR composite oxide cathodes by manipulating the composition/structure for practical use in high-energy-density lithium-ion batteries.

  14. Engi 8717 -9601, In Class Assignment, 9 March 2010 A) human waste and agricultural run-off

    E-Print Network [OSTI]

    Coles, Cynthia

    Engi 8717 - 9601, In Class Assignment, 9 March 2010 A) human waste and agricultural run-off B) reduced fertilizer use (or no fertilizer use), ii) wetlands need to be reintroduced into the catchments

  15. Formation of MnSb during the growth of MnSi layers in the presence of an Sb flux

    E-Print Network [OSTI]

    Pennycook, Steve

    , Kawasaki 210-0855, Japan Y. Yan National Renewable Energy Laboratory, Golden, Colorado 80401 S. J a magnetic transition at TC 29.1 K from a paramag- netic state to a helicoidal order.3 An itinerant metamagnetic transition in MnSi has been observed,4,5 and magnetic prop- erties of MnSi under high pressure

  16. Chemical and structural investigation of the role of both Mn and Mn oxide in the formation of manganese silicate barrier layers on SiO{sub 2}

    SciTech Connect (OSTI)

    Casey, P.; Bogan, J.; Hughes, G. [School of Physical Sciences, Dublin City University, Glasnevin, Dublin 9 (Ireland); Lozano, J. G.; Nellist, P. D. [Department of Materials, University of Oxford, Parks Road, Oxford OX1 3PH (United Kingdom)

    2011-09-01T23:59:59.000Z

    In this study, Mn silicate (MnSiO{sub 3}) barrier layers were formed on thermally grown SiO{sub 2} using both metallic Mn and oxidized Mn films, in order to investigate the role of oxygen in determining the extent of the interaction between the deposited Mn and the SiO{sub 2} substrate. Using x-ray photoelectron spectroscopy, it has been shown that a metallic Mn film with an approximate thickness of 1 nm cannot be fully converted to Mn silicate following vacuum annealing to 500 deg. C. Transmission electron microscopy (TEM) analysis suggests the maximum MnSiO{sub 3} layer thickness obtainable using metallic Mn is {approx}1.7 nm. In contrast, a {approx}1 nm partially oxidized Mn film can be fully converted to Mn silicate following thermal annealing to 400 deg. C, forming a MnSiO{sub 3} layer with a measured thickness of 2.6 nm. TEM analysis also clearly shows that MnSiO{sub 3} growth results in a corresponding reduction in the SiO{sub 2} layer thickness. It has also been shown that a fully oxidized Mn oxide thin film can be converted to Mn silicate, in the absence of metallic Mn. Based on these results it is suggested that the presence of Mn oxide species at the Mn/SiO{sub 2} interface facilitates the conversion of SiO{sub 2} to MnSiO{sub 3}, in agreement with previously published studies.

  17. FALL 2014 SPANISH PLACEMENT TEST Who needs it: All students wishing to take a Spanish class at VT for the first time must take the Spanish

    E-Print Network [OSTI]

    Buehrer, R. Michael

    FALL 2014 SPANISH PLACEMENT TEST Who needs it: All students wishing to take a Spanish class at VT for the first time must take the Spanish Placement Test to determine what class they need and to be force-added into that class. Students who have taken less than Spanish II in high school do not take the placement test

  18. Class 1 Permit Modification Notification

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Waste Bureau New Mexico Environment Department 2905 Rodeo Park Drive East, Bu il ding 1 Santa Fe, New Mexico 87505-6303 JUL 0 5 2011 Subject: Notification of a Class 1 Permit...

  19. Plain Language Training Class 01

    Broader source: Energy.gov [DOE]

    Registration link:  CHRIS https://mis.doe.gov/ess/index.cfm   002357/0017 and https://powerpedia.energy.gov/wiki/Plain_Writing_Training_Class_October_...Course Type: Classroom   Course Location:...

  20. Query Optimization Techniques Class Hierarchies

    E-Print Network [OSTI]

    Mannheim, Universität

    Query Optimization Techniques Exploiting Class Hierarchies Sophie Cluet 1 Guido Moerkotte 2 1 INRIA Since the introduction of object base management systems (OBMS), many query optimization techniques tailored for object query languages have been proposed. They adapt known optimization techniques

  1. Cyanide clusters of ReII with 3d metal ions and their magnetic properties: incorporating anisotropic ions into metal-cyanide clusters with high spin magnetic ground states

    E-Print Network [OSTI]

    Schelter, Eric John

    2005-08-29T23:59:59.000Z

    B. Synthesis of Re-triphos Compounds????????.. 33 1. II(triphos)(CH3CN)3][BF4]2 (1)??????. 33 2. [(triphos)ReII(? -Cl)3ReII(triphos)]Cl (2)................. 34 3. (triphos)ReI(? -Cl)3ReII(triphos) (3.... Experimental Section????...................................................... 74 A. Starting Materials??........................................................ 74 B. Synthesis of Molecular Cubes of Re4Mn4, Re4Fe4, Re 4Co4...

  2. Unusual Structure and Magnetism in MnO Nanoclusters

    E-Print Network [OSTI]

    Ganguly, Shreemoyee; Sanyal, Biplab; Mookerjee, Abhijit; 10.1103/PhysRevB.83.020411

    2011-01-01T23:59:59.000Z

    We report an unusual evolution of structure and magnetism in stoichiometric MnO clusters based on an extensive and unbiased search through the potential energy surface within density functional theory. The smaller clusters, containing up to five MnO units, adopt two-dimensional structures; and regardless of the size of the cluster, magnetic coupling is found to be antiferromagnetic in contrast to previous theoretical findings. Predicted structure and magnetism are strikingly different from the magnetic core of Mn-based molecular magnets, whereas they were previously argued to be similar. Both of these features are explained through the inherent electronic structures of the clusters.

  3. Parallel Polarization EPR Characterization of the Mn(III) Center of Oxidized Manganese Superoxide

    E-Print Network [OSTI]

    Miller, Anne-Frances

    Parallel Polarization EPR Characterization of the Mn(III) Center of Oxidized Manganese Superoxide polarization CW-EPR to investigate the paramagnetic Mn3+ ion of the MnSOD enzyme from Escherichia coli with a positive axial zero-field splitting value, D, are arranged as shown in Figure 1. An EPR signal from the Mn

  4. Artificial Photosynthesis II -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    II - Artificial Photosynthesis II - Joint Center for Artificial Photosynthesis (JCAP) Simulations NathanLewis.png Schematic of a photoelectrochemical cell being designed to harness...

  5. Introduction Real datasets with known classes

    E-Print Network [OSTI]

    Hennig, Christian

    Introduction Real datasets with known classes Simulated datasets Real datasets without known 8, 2011 Christian Hennig Some thoughts on cluster benchmarking #12;Introduction Real datasets with known classes Simulated datasets Real datasets without known classes Benchmarking should not be ranking

  6. Transverse acoustic actuation of Ni-Mn-Ga single crystals

    E-Print Network [OSTI]

    Simon, Jesse Matthew

    2007-01-01T23:59:59.000Z

    Two methods for the transverse acoustic actuation of {110}-cut Ni-Mn-Ga single crystals are discussed. In this actuation mode, crystals are used that have the {110}- type twinning planes parallel to the base of the crystal. ...

  7. New possible resonance for population II Cepheids

    SciTech Connect (OSTI)

    Cox, A.N.; Kidman, R.B.

    1984-01-01T23:59:59.000Z

    Light and velocity curves of some radial mode variable stars seem to indicate a resonance where the second overtone has a period exactly half that of the fundamental mode. The two classes of stars that show this resonance by bumps in their light curves are the classical Cepheids and the population II BL Her variables. We here propose that there is another resonance for the population II W Vir variables where the ratio of the first overtone to the fundamental periods is 0.5.

  8. Crossovers between superconducting symmetry classes

    E-Print Network [OSTI]

    V. A. Koziy; M. A. Skvortsov

    2011-06-20T23:59:59.000Z

    We study the average density of states in a small metallic grain coupled to two superconductors with the phase difference $\\pi$, in a magnetic field. The spectrum of the low-energy excitations in the grain is described by the random matrix theory whose symmetry depends on the magnetic field strength and coupling to the superconductors. In the limiting cases, a pure superconducting symmetry class is realized. For intermediate magnetic fields or couplings to the superconductors, the system experiences a crossover between different symmetry classes. With the help of the supersymmetric sigma-model we derive the exact expressions for the average density of states in the crossovers between the symmetry classes A-C and CI-C.

  9. Ambi-site substitution of Mn in lanthanum germanate apatites

    SciTech Connect (OSTI)

    Kendrick, E. [Chemical Sciences, University of Surrey, Guildford, Surrey GU2 7XH (United Kingdom); Knight, K.S. [ISIS Facility, Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Didcot OX11 0QX (United Kingdom); Slater, P.R., E-mail: p.r.slater@bham.ac.uk [School of Chemistry, University of Birmingham, Edgbaston, Birmingham B15 2TT (United Kingdom)

    2009-08-05T23:59:59.000Z

    A neutron diffraction study at 4 K of the Mn doped lanthanum germanate apatite-type oxide ion conductor of nominal starting composition 'La{sub 9.5}Mn{sub 0.5}(GeO{sub 4}){sub 6}O{sub 2.75}' is reported. The structure was refined in space group P6{sub 3}/m, although high thermal displacement parameters were observed for the oxide ion sites (particularly O3, and O4). Reduced thermal displacement parameters were obtained by splitting the O3 site, and allowing the O4 oxygen to move off site, which may indicate local regions of lower symmetry within the structure. In addition, the data suggested ambi-site substitution of Mn, with it being present on both the Ge site and the La site. Assuming no change in La:Mn:Ge ratio, a composition of La{sub 9.18}Mn{sub 0.28}(GeO{sub 4}){sub 5.8}(MnO{sub 4}){sub 0.2}O{sub 2} was determined. As such there are nominally no interstitial oxide ions, but rather cation vacancies on the La site. Therefore, the high conductivity for this sample is most likely related to the introduction of Frenkel-type defects at higher temperature, as previously proposed for other apatite-type systems containing vacancies on the La site.

  10. Magnetoluminescence of CdTe/MnTe/CdMgTe heterostructures with ultrathin MnTe layers

    SciTech Connect (OSTI)

    Agekyan, V. F., E-mail: vfag@rambler.ru [St. Petersburg State University, Fock Institute of Physics (Russian Federation); Holz, P. O. [Polish Academy of Sciences, Institute of Physics (Poland); Karczewski, G. [Linkoeping University (Sweden); Katz, V. N. [St. Petersburg State University, Fock Institute of Physics (Russian Federation); Moskalenko, E. S. [Russian Academy of Sciences, Ioffe Physical Technical Institute (Russian Federation); Serov, A. Yu.; Filosofov, N. G. [St. Petersburg State University, Fock Institute of Physics (Russian Federation)

    2011-10-15T23:59:59.000Z

    CdTe/MnTe/CdMgTe quantum-well structures with one or two monolayers of MnTe inserted at CdTe/CdMgTe interfaces were fabricated. The spectra of the excitonic luminescence from CdTe quantum wells and their variation with temperature indicate that introduction of ultrathin MnTe layers improves the interface quality. The effect of a magnetic field in the Faraday configuration on the spectral position of the exciton-emission peaks indicates that frustration of magnetic moments in one-monolayer MnTe insertions is weaker than in two-monolayer insertions. The effect of a magnetic field on the exciton localization can be explained in terms of the exciton wave-function shrinkage and obstruction of the photoexcited charge-carrier motion in the quantum well.

  11. Application of Mn/DOT Utility Coordination Process to Local Agencies Based on national best practices, the Minnesota Department of Transportation (Mn/DOT) Utility

    E-Print Network [OSTI]

    Minnesota, University of

    Application of Mn/DOT Utility Coordination Process to Local Agencies Based on national best practices, the Minnesota Department of Transportation (Mn/DOT) Utility Coordination Process incorporates Processes There are projects where the full process is not necessary. The Mn/DOT Utilities Manual provides

  12. Universality class of holographic superconductors

    E-Print Network [OSTI]

    Kengo Maeda; Makoto Natsuume; Takashi Okamura

    2010-05-14T23:59:59.000Z

    We study "holographic superconductors" in various spacetime dimensions. We compute most of the static critical exponents in the linear perturbations and show that they take the standard mean-field values. We also consider the dynamic universality class for these models and show that they belong to model A with dynamic critical exponent z=2.

  13. Fixation of atmospheric CO[sub 2] by a series of hydroxo complexes of divalent metal ions and the implication for the catalytic role of metal ion in carbonic anhydrase. Synthesis, characterization, and molecular structure of [LM(OH)][sub n] (n = 1 or 2) and LM([mu]-CO[sub 3])ML (M(II) = Mn, Fe, Co, Ni, Cu, Zn; L = HB(3,5-iPr[sub 2]pz)[sub 3])

    SciTech Connect (OSTI)

    Kitajima, Nobumasa; Hikichi, Shiro; Tanaka, Masako; Moro-oka, Yoshihiko (Tokyo Inst. of Technology, Yokohama (Japan))

    1993-06-30T23:59:59.000Z

    By using the hindered tris(pyrazoly)borate ligand HB(3,5-iPr[sub 2]pz)[sub 3], (hydrotris(3,5-diisopropyl-1-pyrazolyl)-borate), a series of hydroxo complexes of first-row divalent metal ions (Mn (1), Fe (2), Co (3), Ni (4), Cu (5), Zn (6)) was synthesized. X-ray crystallography was applied to 1-5, establishing that all these hydroxo complexes have a dinuclear structure solely bridged with a bis(hydroxo) unit. The structure of 6 was characterized by spectroscopy, which indicates that 6 is monomeric. All these hydroxo complexes were found to react with CO[sub 2], even atmospheric CO[sub 2], to afford [mu]-carbonato dinuclear complexes of Mn (7), Fe (8), Co (9), Ni (10), Cu (11), and Zn (12). The molecular structures of the complexes 8-12 were determined. A variety of coordination modes of the carbonate group was seen. In 10 and 11, the carbonate group is bound to both metal centers bidentately in a symmetric fashion, while in 8 and 9, the carbonate coordination modes are described as an unsymmetric bidentate. The carbonate group in 12 is coordinated to one zinc ion bidentately, but it is bound to the other zinc ion unidentately. From IR data, the coordination mode of the carbonate group in 7 was suggested to be similar to those found in 8 and 9. Thus, the order of the coordination distortions of the carbonate groups in this series of [mu]-carbonato dinuclear complexes is determined. 40 refs., 8 figs., 4 tabs.

  14. METR 3223: Physical Meteorology II: Cloud Physics, Atmospheric Electricity and Optics

    E-Print Network [OSTI]

    Droegemeier, Kelvin K.

    METR 3223: Physical Meteorology II: Cloud Physics, Atmospheric Electricity and Optics CLASS: Monday as atmospheric electricity and optics. Specific topics that will be covered are as follows: Cloud physics: Review Observation studies Atmospheric electricity: Electrostatics Electromagnetic wave Thunderstorm charging

  15. Hydrothermal synthesis and catalytic properties of {alpha}- and {beta}-MnO{sub 2} nanorods

    SciTech Connect (OSTI)

    Cao, Guangsheng, E-mail: daqingcgs@163.com [Key Laboratory of Enhanced Oil and Gas Recovery of Ministry of Education, Daqing Petroleum Institute, Daqing 163318 (China)] [Key Laboratory of Enhanced Oil and Gas Recovery of Ministry of Education, Daqing Petroleum Institute, Daqing 163318 (China); Su, Ling; Zhang, Xiaojuan; Li, Hui [Key Laboratory of Enhanced Oil and Gas Recovery of Ministry of Education, Daqing Petroleum Institute, Daqing 163318 (China)] [Key Laboratory of Enhanced Oil and Gas Recovery of Ministry of Education, Daqing Petroleum Institute, Daqing 163318 (China)

    2010-04-15T23:59:59.000Z

    One-dimensional {alpha}-MnO{sub 2} and {beta}-MnO{sub 2} single-crystalline nanostructures were prepared by hydrothermal process. The products were characterized in detail by multiform techniques: X-ray diffraction, scanning electron microscopy, and transmission electron microscopy. Experimental results indicate that the temperature plays important roles in determining produce {alpha}-MnO{sub 2} and {beta}-MnO{sub 2} nanorods. In addition, the as-prepared {alpha}-MnO{sub 2} and {beta}-MnO{sub 2} nanorods showed excellent catalytic performance in the Fenton-like reaction.

  16. Spin dependent transport properties of Mn-Ga/MgO/Mn-Ga magnetic tunnel junctions with metal(Mg, Co, Cr) insertion layer

    SciTech Connect (OSTI)

    Liang, S. H.; Tao, L. L.; Liu, D. P., E-mail: dpliu@iphy.ac.cn; Han, X. F., E-mail: xfhan@iphy.ac.cn [State Key Laboratory of Magnetism, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Lu, Y. [Institut Jean Lamour, UMR 7198, CNRS-Nancy Université, BP 239, 54506 Vandoeuvre (France)

    2014-04-07T23:59:59.000Z

    We report a first principles theoretical investigation of spin polarized quantum transport in Mn{sub 2}Ga/MgO/Mn{sub 2}Ga and Mn{sub 3}Ga/MgO/Mn{sub 3}Ga magnetic tunneling junctions (MTJs) with the consideration of metal(Mg, Co, Cr) insertion layer effect. By changing the concentration of Mn, our calculation shows a considerable disparity in transport properties: A tunneling magnetoresistance (TMR) ratio of 852% was obtained for Mn{sub 2}Ga-based MTJs, however, only a 5% TMR ratio for Mn{sub 3}Ga-based MTJs. In addition, the influence of insertion layer has been considered in our calculation. We found the Co insertion layer can increase the TMR of Mn{sub 2}Ga-based MTJ to 904%; however, the Cr insertion layer can decrease the TMR by 668%; A negative TMR ratio can be obtained with Mg insertion layer. Our work gives a comprehensive understanding of the influence of different insertion layer in Mn-Ga based MTJs. It is proved that, due to the transmission can be modulated by the interfacial electronic structure of insertion, the magnetoresistance ratio of Mn{sub 2}Ga/MgO/Mn{sub 2}Ga MTJ can be improved by inserting Co layer.

  17. A comparative study of magnetic behaviors in TbNi{sub 2}, TbMn{sub 2} and TbNi{sub 2}Mn

    SciTech Connect (OSTI)

    Wang, J. L., E-mail: jianli@uow.edu.au [Institute for Superconductivity and Electronic Materials, University of Wollongong, Wollongong, NSW 2522 (Australia); Bragg Institute, ANSTO, Lucas Heights, NSW 2234 (Australia); Md Din, M. F.; Hong, F.; Cheng, Z. X.; Dou, S. X. [Institute for Superconductivity and Electronic Materials, University of Wollongong, Wollongong, NSW 2522 (Australia); Kennedy, S. J.; Studer, A. J. [Bragg Institute, ANSTO, Lucas Heights, NSW 2234 (Australia); Campbell, S. J. [School of Physical, Environmental and Mathematical Sciences, The University of New South Wales, Canberra, ACT 2600 (Australia); Wu, G. H. [Institute of Physics, Chinese Academy of Science, Beijing 100190 (China)

    2014-05-07T23:59:59.000Z

    All TbNi{sub 2}, TbMn{sub 2}, and TbNi{sub 2}Mn compounds exhibit the cubic Laves phase with AB{sub 2}-type structure in spite of the fact that the ratio of the Tb to transition-metal components in TbNi{sub 2}Mn is 1:3. Rietveld refinement indicates that in TbNi{sub 2}Mn the Mn atoms are distributed on both the A (8a) and B (16d) sites. The values of the lattice constants were measured to be a?=?14.348?Å (space group F-43?m), 7.618?Å, and 7.158?Å (space group Fd-3?m) for TbNi{sub 2}, TbMn{sub 2}, and TbNi{sub 2}Mn, respectively. The magnetic transition temperatures T{sub C} were found to be T{sub C}?=?38?K and T{sub C}?=?148?K for TbNi{sub 2} and TbNi{sub 2}Mn, respectively, while two magnetic phase transitions are detected for TbMn{sub 2} at T{sub 1}?=?20?K and T{sub 2}?=?49?K. Clear magnetic history effects in a low magnetic field are observed in TbMn{sub 2} and TbNi{sub 2}Mn. The magnetic entropy changes have been obtained.

  18. Ultrafast Photooxidation of Mn(II)-Terpyridine Complexes Covalently Attached to TiO2 Nanoparticles

    E-Print Network [OSTI]

    -energy conversion by dye-sensitized solar cells,1,2 photocatalysis,3-6 and molecular electronics.7,8 Most previous-cost, high-efficiency solar cell based on Ru-dye sensitization of colloidal TiO2 films.1 Presently, the most studies have been focused on TiO2 nanoparticles sensitized with Ru dyes,9,10 although IET in other

  19. EA-1809: White Earth Nation Wind Energy Project II, Becker and Mahnomen Counties, MN

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts of a proposal to provide Congressionally Directed funds to the White Earth Nation to purchase and install up to four small mid-sized wind turbines at two sites near the towns of Waubun and Naytahwaush on the White Earth Reservation in Mahnomen County in western Minnesota .

  20. Mn(II) Oxidation by an Ascomycete Fungus is Linked to Superoxide Production

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment SurfacesResource Program PreliminaryA3,0StatementsMixing Up a Batch ofSpectral

  1. Mn-Fe base and Mn-Cr-Fe base austenitic alloys

    DOE Patents [OSTI]

    Brager, Howard R. (Richland, WA); Garner, Francis A. (Richland, WA)

    1987-01-01T23:59:59.000Z

    Manganese-iron base and manganese-chromium-iron base austenitic alloys designed to have resistance to neutron irradiation induced swelling and low activation have the following compositions (in weight percent): 20 to 40 Mn; up to about 15 Cr; about 0.4 to about 3.0 Si; an austenite stabilizing element selected from C and N, alone or in combination with each other, and in an amount effective to substantially stabilize the austenite phase, but less than about 0.7 C, and less than about 0.3 N; up to about 2.5 V; up to about 0.1 P; up to about 0.01 B; up to about 3.0 Al; up to about 0.5 Ni; up to about 2.0 W; up to about 1.0 Ti; up to about 1.0 Ta; and with the remainder of the alloy being essentially iron.

  2. LiMnPO4 Nanoplate Grown via Solid-State Reaction in Molten Hydrocarbon...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    LiMnPO4 Nanoplate Grown via Solid-State Reaction in Molten Hydrocarbon for Li-ion Battery Cathode. LiMnPO4 Nanoplate Grown via Solid-State Reaction in Molten Hydrocarbon for Li-ion...

  3. Electrodeposited Al-Mn Alloys with Microcrystalline, Nanocrystalline, Amorphous and Nano-quasicrystalline Structures

    E-Print Network [OSTI]

    Ruan, Shiyun

    Al–Mn alloys with Mn content ranging from 0 to 15.8 at.% are prepared by electrodeposition from an ionic liquid at room temperature, and exhibit a remarkably broad range of structures. The alloys are characterized through ...

  4. Distinct local electronic structure and magnetism for Mn in amorphous Si and Ge

    E-Print Network [OSTI]

    Zeng, Li

    2010-01-01T23:59:59.000Z

    Li, A. P. et al. Magnetism in Mn x Ge 1-x semiconductorsElectronic Structure and Magnetism for Mn in Amorphous Sistructure that determines magnetism. Figure 3 shows XAS data

  5. Mn12-acetate thin film patterns and their interaction with superconductors

    E-Print Network [OSTI]

    Kim, Kyongwan

    2009-05-15T23:59:59.000Z

    Mn12-acetate single-molecule magnets (SMMs) are nano-scale magnets showing a strong magnetic anisotropy, slow relaxation and stepwise magnetic hysteresis curves. Possible applications of Mn12-acetate, e.g. for ultra high density magnetic information...

  6. On deformation twinning in a 17.5%Mn-TWIP steel: A physically...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    On deformation twinning in a 17.5%Mn-TWIP steel: A physically-based phenomenological model. On deformation twinning in a 17.5%Mn-TWIP steel: A physically-based phenomenological...

  7. Pulsed laser deposition of Mn doped CdSe quantum dots for improved solar cell performance

    SciTech Connect (OSTI)

    Dai, Qilin; Wang, Wenyong, E-mail: wwang5@uwyo.edu, E-mail: jtang2@uwyo.edu; Tang, Jinke, E-mail: wwang5@uwyo.edu, E-mail: jtang2@uwyo.edu [Department of Physics and Astronomy, University of Wyoming, Laramie, Wyoming 82071 (United States); Sabio, Erwin M. [Department of Chemistry, University of Wyoming, Laramie, Wyoming 82071 (United States)

    2014-05-05T23:59:59.000Z

    In this work, we demonstrate (1) a facile method to prepare Mn doped CdSe quantum dots (QDs) on Zn{sub 2}SnO{sub 4} photoanodes by pulsed laser deposition and (2) improved device performance of quantum dot sensitized solar cells of the Mn doped QDs (CdSe:Mn) compared to the undoped QDs (CdSe). The band diagram of photoanode Zn{sub 2}SnO{sub 4} and sensitizer CdSe:Mn QD is proposed based on the incident-photon-to-electron conversion efficiency (IPCE) data. Mn-modified band structure leads to absorption at longer wavelengths than the undoped CdSe QDs, which is due to the exchange splitting of the CdSe:Mn conduction band by the Mn dopant. Three-fold increase in the IPCE efficiency has also been observed for the Mn doped samples.

  8. Engineering the magnetic properties of the Mn13 cluster by doping

    E-Print Network [OSTI]

    Datta, Soumendu

    With a goal to produce a giant magnetic moment in a Mn13 cluster that will be useful for practical applications, we have considered the structure and magnetic properties of a pure Mn13 cluster and substitutionally doped ...

  9. X-ray absorption study of the electronic structure of Mn-doped amorphous Si

    E-Print Network [OSTI]

    Zeng, Li

    2008-01-01T23:59:59.000Z

    X-ray absorption study of the electronic structure of Mn-?x ) is studied by X-ray absorption spectroscopy at the Mn Land featureless L 3,2 absorption peaks, corresponding to an

  10. E-Print Network 3.0 - al fe mn Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    National Cheng Kung University Collection: Physics 4 Valence states of transition-metal ions in cubic perovskites SrMn1-xFexO3 H. J. Lee,a Summary: the Mn 3d resonance and...

  11. Effect of Composition and Heat Treatment on MnBi Magnetic Materials...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Abstract: The metallic compound MnBi is a promising rare-earth-free permanent magnet material. Compare to other rare-earth-free candidates, MnBi stands out for its high...

  12. Differences in serum concentrations of organochlorine compounds by occupational social class in pancreatic cancer

    SciTech Connect (OSTI)

    Porta, Miquel [Institut Municipal d'Investigacio Medica, Barcelona (Spain); Facultat de Medicina, Universitat Autonoma de Barcelona (Spain); CIBER en Epidemiologia y Salud Publica (CIBERESP) (Spain)], E-mail: mporta@imim.es; Bosch de Basea, Magda [Institut Municipal d'Investigacio Medica, Barcelona (Spain); CIBER en Epidemiologia y Salud Publica CIBERESP (Spain); Universitat Pompeu Fabra, Barcelona (Spain); Benavides, Fernando G. [CIBER en Epidemiologia y Salud Publica (CIBERESP) (Spain); Universitat Pompeu Fabra, Barcelona (Spain); Lopez, Tomas [Institut Municipal d'Investigacio Medica, Barcelona (Spain); CIBER en Epidemiologia y Salud Publica (CIBERESP) (Spain); Fernandez, Esteve [Universitat Pompeu Fabra, Barcelona (Spain); Institut Catala d'Oncologia, L'Hospitalet de Llobregat, Barcelona (Spain); Marco, Esther [Department of Environmental Chemistry, Institute of Chemical and Environmental Research (IIQAB-CSIC), Barcelona (Spain); Alguacil, Juan [CIBER en Epidemiologia y Salud Publica (CIBERESP) (Spain); Universidad de Huelva (Spain); Grimalt, Joan O. [CIBER en Epidemiologia y Salud Publica (CIBERESP) (Spain); Department of Environmental Chemistry, Institute of Chemical and Environmental Research (IIQAB-CSIC), Barcelona (Spain); Puigdomenech, Elisa [Institut Municipal d'Investigacio Medica, Barcelona (Spain); Facultat de Medicina, Universitat Autonoma de Barcelona (Spain); CIBER en Epidemiologia y Salud Publica (CIBERESP) (Spain)

    2008-11-15T23:59:59.000Z

    Background: The relationships between social factors and body concentrations of environmental chemical agents are unknown in many human populations. Some chemical compounds may play an etiopathogenic role in pancreatic cancer. Objective: To analyze the relationships between occupational social class and serum concentrations of seven selected organochlorine compounds (OCs) in exocrine pancreatic cancer: dichlorodiphenyltrichloroethane (p,p'-DDT), dichlorodiphenyldichloroethene (p,p'-DDE), 3 polychlorinated biphenyls (PCBs), hexachlorobenzene, and {beta}-hexachlorocyclohexane. Methods: Incident cases of exocrine pancreatic cancer were prospectively identified, and interviewed face-to-face during hospital admission (n=135). Serum concentrations of OCs were analyzed by high-resolution gas chromatography with electron-capture detection. Social class was classified according to occupation. Results: Multivariate-adjusted concentrations of all seven compounds were higher in occupational social classes IV-V (the less affluent) than in classes I-II; they were higher as well in class III than in classes I-II for four compounds. Concentrations of six OCs were higher in manual workers than in non-manual workers (p<0.05 for PCBs). Social class explained statistically between 3.7% and 5.7% of the variability in concentrations of PCBs, and 2% or less variability in the other OCs. Conclusions: Concentrations of most OCs were higher in the less affluent occupational social classes. In pancreatic cancer the putative causal role of these persistent organic pollutants may not be independent of social class. There is a need to integrate evidence on the contribution of different social processes and environmental chemical exposures to the etiology of pancreatic and other cancers.

  13. Disentangling the Mn moments on different sublattices in the half-metallic ferrimagnet Mn3?xCoxGa

    SciTech Connect (OSTI)

    Klaer, P.; Jenkins, C.A.; Alijani, V.; Winterlik, J.; Balke, B.; Felser, C.; Elmers, H.J.

    2011-05-03T23:59:59.000Z

    Ferrimagnetic Mn{sub 3-x}Co{sub x}Ga compounds have been investigated by magnetic circular dichroism in x-ray absorption (XMCD). Compounds with x > 0.5 crystallize in the CuHg{sub 2}Ti structure. A tetragonal distortion of the cubic structure occurs for x {le} 0.5. For the cubic phase, magnetometry reveals a linearly increasing magnetization of 2x Bohr magnetons per formula unit obeying the generalized Slater-Pauling rule. XMCD confirms the ferrimagnetic character with Mn atoms occupying two different sublattices with antiparallel spin orientation and different degrees of spin localization and identifies the region 0.6 < x {le} 0.8 as most promising for a high spin polarization at the Fermi level. Individual Mn moments on inequivalent sites are compared to theoretical predictions.

  14. By Christopher Parker Class year? Hometown?

    E-Print Network [OSTI]

    By Christopher Parker Class year? Hometown? - I'm class of 2010, Chemical Engineering major the opening for a tournament assistant. I'm al- ways in Keith or Jessica's office being the treasurer

  15. Cationic disorder and Mn{sup 3+}/Mn{sup 4+} charge ordering in the B? and B? sites of Ca{sub 3}Mn{sub 2}NbO{sub 9} perovskite: a comparison with Ca{sub 3}Mn{sub 2}WO{sub 9}

    SciTech Connect (OSTI)

    López, C.A., E-mail: calopez@unsl.edu.ar [INTEQUI-Área de Química General e Inorgánica “Dr. G. F. Puelles”, Facultad de Química, Bioquímica y Farmacia, Universidad Nacional de San Luis, Chacabuco y Pedernera, 5700 San Luis (Argentina); Centro Atómico Bariloche, Comisión Nacional de Energía Atómica and Instituto Balseiro, Universidad Nacional de Cuyo, 8400S.C. de Bariloche, Río Negro (Argentina); Saleta, M.E. [Centro Atómico Bariloche, Comisión Nacional de Energía Atómica and Instituto Balseiro, Universidad Nacional de Cuyo, 8400S.C. de Bariloche, Río Negro (Argentina); Pedregosa, J.C. [INTEQUI-Área de Química General e Inorgánica “Dr. G. F. Puelles”, Facultad de Química, Bioquímica y Farmacia, Universidad Nacional de San Luis, Chacabuco y Pedernera, 5700 San Luis (Argentina); Sánchez, R.D. [Centro Atómico Bariloche, Comisión Nacional de Energía Atómica and Instituto Balseiro, Universidad Nacional de Cuyo, 8400S.C. de Bariloche, Río Negro (Argentina); Alonso, J.A. [Instituto de Ciencia de Materiales de Madrid, CSIC, Cantoblanco, E-28049 Madrid (Spain); and others

    2014-02-15T23:59:59.000Z

    We describe the preparation, crystal structure determination, magnetic and transport properties of two novel Mn-containing perovskites, with a different electronic configuration for Mn atoms located in B site. Ca{sub 3}Mn{sup 3+}{sub 2}WO{sub 9} and Ca{sub 3}Mn{sup 3+/4+}{sub 2}NbO{sub 9} were synthesized by standard ceramic procedures; the crystallographic structure was studied from X-ray powder diffraction (XRPD) and neutron powder diffraction (NPD). Both phases exhibit a monoclinic symmetry (S.G.: P2{sub 1}/n); Ca{sub 3}Mn{sub 2}WO{sub 9} presents a long-range ordering over the B sites, whereas Ca{sub 3}Mn{sub 2}NbO{sub 9} is strongly disordered. By “in-situ” NPD, the temperature evolution of the structure study presents an interesting evolution in the octahedral size (?Mn–O?) for Ca{sub 3}Mn{sub 2}NbO{sub 9}, driven by a charge ordering effect between Mn{sup 3+} and Mn{sup 4+} atoms, related to the anomaly observed in the transport measurements at T?160 K. Both materials present a magnetic order below T{sub C}=30 K and 40 K for W and Nb materials, respectively. The magneto-transport measurements display non-negligible magnetoresistance properties in the paramagnetic regime. - Graphical abstract: Comparison between the octahedron size and the magnetic behaviour for Ca{sub 3}Mn{sub 2}NbO{sub 9} in the temperature region where the charge and magnetic order occur. Display Omitted - Highlights: • Two novel Mn-containing double perovskites were obtained by solid-state reactions. • Both double perovskites are monoclinic (P2{sub 1}/n) determined by XRPD and NPD. • Ca{sub 3}Mn{sub 2}WO{sub 9} contains Mn{sup 3+} while Ca{sub 3}Mn{sub 2}NbO{sub 9} includes mixed-valence cations Mn{sup 3+}/Mn{sup 4+}. • Ca{sub 3}Mn{sub 2}NbO{sub 9} presents a charge-ordering effect between Mn{sup 3+} and Mn{sup 4+} evidenced by NPD. • The magnetic and transport studies evidenced the charge ordering in Ca{sub 3}Mn{sub 2}NbO{sub 9}.

  16. Growing the renewable chemicals and advanced biofuels cluster in MN

    E-Print Network [OSTI]

    Levinson, David M.

    Growing the renewable chemicals and advanced biofuels cluster in MN #12;Renewable Chemical Value% Reduction 60% Reduction 0% 10% 20% 30% 40% 50% 60% 70% 80% 90% 100% Gasoline Corn Ethanol Advanced Biofuel Cellulosic Biofuel Corn Ethanol 20% GHG Reduction Compared to gasoline: Advanced Biofuel 50% GHG Reduction e

  17. Electronic interactions between gold films and mn12-acetate

    E-Print Network [OSTI]

    Means, Joel Lewis

    2009-05-15T23:59:59.000Z

    the presence of a surface layer of Mn12–acetate, have been performed using a dilution refrigerator. Quantitative fits to the data using the predictions of weak localization theory were performed using a least-squares fit method in order to determine...

  18. Mn/DOT's Ombudsman Program Collaboration and Process

    E-Print Network [OSTI]

    Minnesota, University of

    Mn/DOT's Ombudsman Program Collaboration and Process #12;Overview Ombudsman exists to rebuild trust on the environmental and municipal consent processes can be critical #12;A Large Organization #12;Tragedy;Ombudsman Does Not... ·! Advocate for one party or point of view ·! Own any formal process or policy

  19. 0 1 2 3 4 5 Fig. S1. Core photograph combined with Ca, Mn, Fe counts and Mn/Fe ratio determined by XRF core

    E-Print Network [OSTI]

    Gilli, Adrian

    1. Core photograph combined with Ca, Mn, Fe counts and Mn/Fe ratio determined by XRF core scanning determined by XRF core scanning on core ZH10-19 from Lake Zurich recovered in 135 m water depth (2 m above counts and Mn/Fe ratio determined by XRF core scanning on core ZH10-21 from Lake Zurich recovered in 123

  20. XANES, EXAFS and Kbeta spectroscopic studies of the oxygen-evolving complex in Photosystem II

    SciTech Connect (OSTI)

    Robblee, John H.

    2000-12-01T23:59:59.000Z

    A key question for the understanding of photosynthetic water oxidation is whether the four oxidizing equivalents necessary to oxidize water to dioxygen are accumulated on the four Mn ions of the oxygen evolving complex (OEC), or whether some ligand-centered oxidations take place before the formation and release of dioxygen during the S{sub 3} {r_arrow} [S{sub 4}] {r_arrow} S{sub 0} transition. Progress in instrumentation and flash sample preparation allowed us to apply Mn K{beta} X-ray emission spectroscopy (Kb XES) to this problem for the first time. The K{beta} XES results, in combination with Mn X-ray absorption near-edge structure (XANES) and electron paramagnetic resonance (EPR) data obtained from the same set of samples, show that the S{sub 2} {r_arrow} S{sub 3} transition, in contrast to the S{sub 0} {r_arrow} S{sub 1} and S{sub 1} {r_arrow} S{sub 2} transitions, does not involve a Mn-centered oxidation. This is rationalized by manganese {mu}-oxo bridge radical formation during the S{sub 2} {r_arrow} S{sub 3} transition. Using extended X-ray absorption fine structure (EXAFS) spectroscopy, the local environment of the Mn atoms in the S{sub 0} state has been structurally characterized. These results show that the Mn-Mn distance in one of the di-{mu}-oxo-bridged Mn-Mn moieties increases from 2.7 {angstrom} in the S{sub 1} state to 2.85 {angstrom} in the S{sub 0} state. Furthermore, evidence is presented that shows three di-{mu}-oxo binuclear Mn{sub 2} clusters may be present in the OEC, which is contrary to the widely held theory that two such clusters are present in the OEC. The EPR properties of the S{sub 0} state have been investigated and a characteristic ''multiline'' signal in the S{sub 0} state has been discovered in the presence of methanol. This provides the first direct confirmation that the native S{sub 0} state is paramagnetic. In addition, this signal was simulated using parameters derived from three possible oxidation states of Mn in the S{sub 0} state. The dichroic nature of X-rays from synchrotron radiation and single-crystal Mn complexes have been exploited to selectively probe Mn-ligand bonds using XANES and EXAFS spectroscopy. The results from single-crystal Mn complexes show that dramatic dichroism exists in these complexes, and are suggestive of a promising future for single-crystal studies of PS II.

  1. Bending properties of epoxy resin matrix composites filled with NiMnGa ferromagnetic shape memory alloy powders

    E-Print Network [OSTI]

    Zheng, Yufeng

    Bending properties of epoxy resin matrix composites filled with Ni­Mn­Ga ferromagnetic shape memory­Mn­Ga Composite materials Mechanical properties Microstructure Two types of epoxy resin matrix composites filled­Mn­Ga epoxy resin composites were reported, yet the bending property of Ni­Mn­Ga-polymer smart composites has

  2. PHYSICAL REVIEW B 84, 205305 (2011) Spin-phonon coupling in single Mn-doped CdTe quantum dot

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    PHYSICAL REVIEW B 84, 205305 (2011) Spin-phonon coupling in single Mn-doped CdTe quantum dot C. L dynamics of a single Mn atom in a laser driven CdTe quantum dot is addressed theoretically. Recent of single Mn-doped CdTe dots, information about the quantum spin state of a single Mn atom is extracted from

  3. ACRA-II

    Energy Science and Technology Software Center (OSTI)

    003089IBMPC00 ACRA-II: Kernel Integration Code System for Estimation of Radiation Doses Caused by a Hypothetical Reactor Accident   

  4. Effect of Composition and Heat Treatment on MnBi Magnetic Materials

    SciTech Connect (OSTI)

    Cui, Jun; Choi, Jung-Pyung; Polikarpov, Evgueni; Bowden, Mark E.; Xie, Wei; Li, Guosheng; Nie, Zimin; Zarkevich, Nikolai; Kramer, Matthew J.; Johnson, Duane D.

    2014-08-17T23:59:59.000Z

    The metallic compound MnBi is a promising rare-earth-free permanent magnet material. Compare to other rare-earth-free candidates, MnBi stands out for its high intrinsic coercivity (Hci) and its large positive temperature coefficient. Several groups have demonstrated that the Hci of MnBi compound in thin film or in powder form can exceed 12 kOe and 26 kOe at 300 K and 523 K, respectively. Such steep increase in Hci with increasing temperature is unique to MnBi. Consequently, MnBi is a highly sought-after hard phase for exchange coupling nanocomposite magnets. The reaction between Mn and Bi is peritectic, so Mn tends to precipitate out of the MnBi liquid during the solidification process. As result, the composition of the Mn-Bi alloy with the largest amount of the desired LTP (low temperature phase) MnBi and highest saturation magnetization will be over-stoichiometric and rich in Mn. The amount of additional Mn required to compensate the Mn precipitation depends on solidification rate: the faster the quench speed, the less Mn precipitates. Here we report a systematic study of the effect of composition and heat treatments on the phase contents and magnetic properties of Mn-Bi alloys. In this study, Mn-Bi alloys with 14 compositions were prepared using conventional metallurgical methods such as arc melting and vacuum heat treatment, and the obtained alloys were analyzed for compositions, crystal structures, phase content, and magnetic properties. The results show that the composition with 55 at.% Mn exhibits the highest LTP MnBi content and the highest magnetization. The sample with this composition shows >90 wt.% LTP MnBi content. Its measured saturation magnetization is 68 emu/g with 2.3 T applied field at 300 K; its coercivity is 13 kOe and its energy product is 12 MGOe at 300 K. A bulk magnet fabricated using this powder exhibits an energy product of 8.2 MGOe.

  5. Oil and gas: Oilfield class actions

    SciTech Connect (OSTI)

    McArthur, J.B.

    1997-06-01T23:59:59.000Z

    The use of class actions is getting alot of attention in the oilfield. Plaintiffs have filed class actions challenging two of the most rooted industry practices, oil posted prices and deregulated natural gas affiliate deduction and charges. The classes will include tens or hundreds of thousands of plaintiffs and may transform two of the industry`s most settled practices. The emotions surrounding the class action risk obscuring the fact that it is an old and oft-used tool in oilfield litigation. The class action {open_quotes}provides a means by which, where a large group of persons are interested in a matter, one or more may sue or be sued as representatives of the class without needing to join every member of the class.{close_quotes} The procedure avoids waste by combining scattered disputes, even if some injured might sue individually, and it enables plaintiffs who could not afford to sue to be represented anyway. The lawyers draw their fees from any recovery. Almost all oilpatch class actions are brought to resolve a {open_quotes}common question{close_quotes} under Federal Rules of Civil Procedure 23(b)(3) or state counterparts. The rule`s {open_quotes}opt-out{close_quotes} provisions give class actions a tremendous boost because members stay in unless they take steps to get out. This article discusses present and future class actions.

  6. CSC6870 Computer Graphics II CSC6870 Computer Graphics II

    E-Print Network [OSTI]

    Hua, Jing

    CSC6870 Computer Graphics II Surfaces CSC6870 Computer Graphics II Surfaces · Plane · Quadratic. CSC6870 Computer Graphics II Plane and Intersection CSC6870 Computer Graphics II Plane Equations · General plane equation ax+by+cz+d=0 · Normal of the plane n=[a, b, c] CSC6870 Computer Graphics II

  7. Combined Final Report for Colony II Project

    SciTech Connect (OSTI)

    Kale, Laxmikant [University of Illinois] [University of Illinois; Jones, Terry [Oak Ridge National Laboratory] [Oak Ridge National Laboratory; Moreira, Jose [IBM Corp.] [IBM Corp.

    2013-10-23T23:59:59.000Z

    (This report was originally submmited by the lead PI (Terry Jones, ORNL) on October 22, 2013 to the program manager, Lucy Nowell. It is being submitted from University of Illinois in accordance with instructions). HPC Colony II seeks to provide portable performance for leadership class machines. Our strategy is based on adaptive system software that aims to make the intelligent decisions necessary to allow domain scientists to safely focus on their task at hand and allow the system software stack to adapt their application to the underlying architecture. This report describes the research undertaken towards these objectives and the results obtained over the performance period of the project.

  8. Class B0631+519: Last of the Class Lenses

    SciTech Connect (OSTI)

    York, Tom; Jackson, N.; Browne, I.W.A.; Koopmans, L.V.E.; McKean, J.P.; Norbury, M.A.; Biggs, A.D.; Blandford, R.D.; de Bruyn, A.G.; Fassnacht, C.D.; Myers, S.T.; Pearson, T.J.; Phillips, P.M.; Readhead, A.C.S.; Rusin, D.; Wilkinson, P.N.; /Jodrell Bank /Kapteyn Astron. Inst., Groningen /UC, Davis /JIVE, Dwingeloo /KIPAC, Menlo Park /NFRA,

    2005-05-31T23:59:59.000Z

    We report the discovery of the new gravitational lens system CLASS B0631+519. Imaging with the VLA, MERLIN and the VLBA reveals a doubly-imaged flat-spectrum radio core, a doubly-imaged steep-spectrum radio lobe and possible quadruply-imaged emission from a second lobe. The maximum separation between the lensed images is 1.16 arcsec. High resolution mapping with the VLBA at 5 GHz resolves the most magnified image of the radio core into a number of sub-components spread across approximately 20 mas. No emission from the lensing galaxy or an odd image is detected down to 0.31 mJy (5{sigma}) at 8.4 GHz. Optical and near-infrared imaging with the ACS and NICMOS cameras on the HST show that there are two galaxies along the line of sight to the lensed source, as previously discovered by optical spectroscopy. We find that the foreground galaxy at z=0.0896 is a small irregular, and that the other, at z=0.6196 is a massive elliptical which appears to contribute the majority of the lensing effect. The host galaxy of the lensed source is detected in the HST near-infrared imaging as a set of arcs, which form a nearly complete Einstein ring. Mass modeling using non-parametric techniques can reproduce the near-infrared observations and indicates that the small irregular galaxy has a (localized) effect on the flux density distribution in the Einstein ring at the 5-10% level.

  9. Charge transport properties of CdMnTe radiation detectors

    SciTech Connect (OSTI)

    Kim K.; Rafiel, R.; Boardman, M.; Reinhard, I.; Sarbutt, A.; Watt, G.; Watt, C.; Uxa, S.; Prokopovich, D.A.; Belas, E.; Bolotnikov, A.E.; James, R.B.

    2012-04-11T23:59:59.000Z

    Growth, fabrication and characterization of indium-doped cadmium manganese telluride (CdMnTe)radiation detectors have been described. Alpha-particle spectroscopy measurements and time resolved current transient measurements have yielded an average charge collection efficiency approaching 100 %. Spatially resolved charge collection efficiency maps have been produced for a range of detector bias voltages. Inhomogeneities in the charge transport of the CdMnTe crystals have been associated with chains of tellurium inclusions within the detector bulk. Further, it has been shown that the role of tellurium inclusions in degrading chargecollection is reduced with increasing values of bias voltage. The electron transit time was determined from time of flight measurements. From the dependence of drift velocity on applied electric field the electron mobility was found to be n = (718 55) cm2/Vs at room temperature.

  10. Schedule of Classes Bulletin Indiana University -IUPUI

    E-Print Network [OSTI]

    Zhou, Yaoqi

    ) 7231 03:35 P-05:35 P R OC Turner J 30 30 0 ABOVE CLASS MEETS ON THE BLOOMINGTON CAMPUS. 7232 PERM ARR

  11. Experiment Hazard Class 3 - High Temperatures

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Operation * APS Base Low Temperatures * Cryogenic Systems High Temperatures * Electric Furnace * Optical Furnace * Other High Temperature Lasers * Laser, Class 2 * Laser,...

  12. Ferromagnetic Mn moments at SrRuO3/SrMnO3 interfaces Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439

    E-Print Network [OSTI]

    Haskel, Daniel

    Ferromagnetic Mn moments at SrRuO3/SrMnO3 interfaces Y. Choia Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439 Y. Z. Yoo, O. Chmaissem, A. Ullah, S. Kolesnik, and C. W University, DeKalb, Illinois 60115 D. Haskel Advanced Photon Source, Argonne National Laboratory, Argonne

  13. Effect of composition and heat treatment on MnBi magnetic materials

    SciTech Connect (OSTI)

    Cui, Jun [Pacific Northwest National Laboratory; Choi, Jung-Pyung [Pacific Northwest National Laboratory; Polikarpov, Evgueni [Pacific Northwest National Laboratory; Bowden, Mark E [Pacific Northwest National Laboratory; Xie, Wei [Pacific Northwest National Laboratory; Li, Guosheng [Pacific Northwest National Laboratory; Nie, Zimin [Pacific Northwest National Laboratory; Zarkevich, Nikolai [Ames Laboratory; Kramer, Matthew J [Ames Laboratory; Johnson, Duane [Ames Laboratory

    2014-10-01T23:59:59.000Z

    The metallic compound MnBi is a promising rare-earth-free permanent magnet material, unique among all candidates for its high intrinsic coercivity (Hci) and its large positive temperature coefficient. The Hci of MnBi in thin-film or powder form can exceed 12 and 26 kOe at 300 and 523 K, respectively. Such a steep rise in Hci with increasing temperature is unique to MnBi. Consequently, MnBi is a highly sought-after hard phase for exchange coupling nanocomposite magnets. However, the reaction between Mn and Bi is peritectic, and hence Mn tends to precipitate out of the MnBi liquid during the solidification process. As result, when the alloy is prepared using conventional induction or arc-melting casting methods, additional Mn is required to compensate the precipitation of Mn. In addition to composition, post-casting annealing plays an important role in obtaining a high content of MnBi low-temperature phase (LTP) because the annealing encourages the Mn precipitates and the unreacted Bi to react, forming the desired LTP phase. Here we report a systematic study of the effect of composition and heat treatments on the phase content and magnetic properties of Mn–Bi alloys. In this study, 14 compositions were prepared using conventional metallurgical methods, and the compositions, crystal structures, phase content and magnetic properties of the resulting alloys were analyzed. The results show that the composition with 55 at.% Mn exhibits both the highest LTP content (93 wt.%) and magnetization (74 emu g?1 with 9 T applied field at 300 K).

  14. DOPING AND BOND LENGTH CONTRIBUTIONS TO Mn K-EDGE SHIFT IN La1-xSrxMnO3 AND THEIR CORRELATION WITH ELECTRICAL TRANSPORT BEHAVIOUR.

    SciTech Connect (OSTI)

    PANDEY,S.K.; KHALID,S.; BINDU, R.; KUMAR, A.; PIMPALE, A.V.

    2006-12-04T23:59:59.000Z

    The experimental Mn K-edge x-ray absorption spectra of La{sub 1-x}Sr{sub x}MnO{sub 3}, x = 0 - 0.7 are compared with the band structure calculations using spin polarized density functional theory. It is explicitly shown that there is a correspondence between the inflection point on the absorption edge and the center of gravity of the unoccupied Mn 4p-band. This correspondence has been used to separate the doping and size contributions to edge shift due to variation in number of electrons in valence band and Mn-O bond lengths, respectively when Sr is doped into LaMnO{sub 3}. Such separation is helpful to find the localization behavior of charge carriers and to understand the observed transport properties and type of charge carrier participating in the conduction process in these compounds.

  15. Abstract Presented at Synchrotron Environmental Science II (SES-II)

    E-Print Network [OSTI]

    Brookhaven National Laboratory

    Abstract Presented at Synchrotron Environmental Science II (SES-II) Argonne National Laboratory - 6 such as dioxins and furans, polychlorinated biphenyls (PCBs), and polynuclear aromatic hydrocarbons (PAHs). *Work

  16. Identification of the Dinuclear and Tetranuclear Air-Oxidized Products Derived from Labile Phenolate-Bridged Dimanganese(II) Pyridyl-Chelate Compounds

    SciTech Connect (OSTI)

    Larsen,F.; Boisen, A.; Berry, K.; Moubaraki, B.; Murray, K.; McKee, V.; Scarrow, R.; McKenzie, C.

    2006-01-01T23:59:59.000Z

    Dioxygen-sensitive dinuclear manganese complexes of the phenoxo-hinged dinucleating ligand 2,6-bis{l_brace}[N,N{prime}-bis(2-picolyl)amino]methyl{r_brace}-4-tert-butylphenolato (bpbp{sup -}) containing exogenous labile THF, water and perchlorato ligands are described. The manganese(II) complexes [Mn{sub 2}(bpbp)(ClO{sub 4}){sub 2}(THF)]{sup +} (1) and [Mn{sub 2}(bpbp)(ClO{sub 4})(H{sub 2}O){sub 2}]{sup 2+} (2) have been isolated as the salts 1{center_dot}ClO{sub 4}{center_dot}THF{center_dot}3H{sub 2}O, 1{center_dot}B(C{sub 6}H{sub 5}){sub 4}{center_dot}4THF and 2{center_dot}(ClO{sub 4})2{center_dot}H{sub 2}O. Complexes 1 and 2 are spontaneously oxidised in air in solution and the solid state. The reaction products of the air oxidation in THF, water and methanol solutions are labile dinuclear Mn{sup II}-Mn{sup III}, Mn{sup III}{sub 2} and Mn{sup III}-Mn{sup IV} complexes containing water- and methanol-derived exogenous ligands. In addition, a Mn{sub 4} complex has been isolated. Magnetic susceptibility data confirm the Mn{sup II}-Mn{sup III} oxidation state assignment with an S = 2/S = 5/2 model with weak antiferromagnetic coupling (J = -3.7 cm{sup -1}) in [Mn{sub 2}(bpbp)(CH{sub 3}O){sub 2}(H{sub 2}O){sub 2}](ClO{sub 4}){sub 2} [3{center_dot}(ClO{sub 4}){sub 2}]. A tetranuclear complex, [Mn{sub 4}(O){sub 4-n}(OH){sub n}(bpbp){sub 2}](ClO{sub 4}){sub 4} [n = 1 or 2; 7{center_dot}(ClO{sub 4}){sub 4}], recovered from THF shows a Mn{sub 4}O{sub 6} adamantane-type core with the O bridges furnished by the two phenolato groups and four hydroxide/oxide bridges. We have arrived at two feasible formulations for the core metal oxidation states and oxo-bridge protonation states, namely [Mn{sup III}{sub 4}(O){sub 2}(OH){sub 2}(bpbp){sub 2}]{sup 4+} and [Mn{sup III}{sub 3}Mn{sup IV}(O){sub 3}(OH)(bpbp){sub 2}]{sup 4+}, for 7, on the basis of a bond valence sum analysis of the crystal structure, elemental analysis and XANES. Thus, complex 7 is at least two oxidation state levels lower than known complexes with the Mn{sub 4}O{sub 6} adamantane core structure. The magnetism of 7 was fitted well to an MnIII4 three-J model. Complex cations related to 3 by homology, and to 7 by hydration/solvation, have been identified by ESI mass spectrometry. The [Mn{sub 2}(bpbp)(OH){sub 2}(H{sub 2}O){sub 2}]{sup 2+} ion (4) present in aqueous solutions on dissolution of 1{center_dot}ClO4{center_dot}THF{center_dot}3H2O in air or by simple dissolution of 3 in water-containing solvent is isoelectronic to 3. In the presence of significant amounts of water the Mn{sup II}-Mn{sup III} complexes 3 and 4 are susceptible to further metal oxidation and concomitant aquo ligand deprotonation to give ions assignable to [Mn{sup III/IV}{sub 2}(bpbp)O(OCH{sub 3}){sub 2}(H{sub 2}O)]{sup 2+} (5) and [Mn{sup III}{sub 2}(bpbp)(OH){sub 3}(H{sub 2}O)]{sup 2+} (6). ESI mass spectra of water or methanol solutions of 1, 2, 3 and 7 show predominantly an ion assignable to the oxide [Mn{sub 2}(bpbp)(O)]{sup 2+} (8). Cation 8 is most likely not present in solution. Using mild source conditions and MS-MS techniques, the gas-phase fragmentation pathways to generate 8 have been mapped.

  17. FTIR spectra and normal-mode analysis of a tetranuclear Manganese adamantane-like complex in two electrochemically prepared oxidation states: Relevance to the oxygen-evolving complex of Photosystem II

    SciTech Connect (OSTI)

    Visser, Hendrik; Dube, Christopher E.; Armstrong, William H.; Sauer, Kenneth; Yachandra, Vittal K.

    2002-03-19T23:59:59.000Z

    The IR spectra and normal-mode analysis of the adamantane-like compound [Mn4O6(bpea)4]n+ in two oxidation states, MnIV4 and MnIIIMnIV3, that are relevant to the oxygen-evolving complex of photosystem II are presented. Mn-O vibrational modes are identified with isotopic exchange, 16O->18O, of the mono-(mu)-oxo bridging atoms in the complex. IR spectra of the MnIIIMnIV3 species are obtained by electrochemical reduction of the MnIV4 species using a spectroelectrochemical cell, based on attenuated total reflection [Visser et al. Anal Chem 2001, 73, 4374-4378]. A novel method of subtraction is used to reduce background contributions from solvent and ligand modes, and the difference and double-difference spectra are used in identifying Mn-O bridging modes that are sensitive to oxidation state change. Two strong IR bands are observed for the MnIV4 species at 745 and 707 cm-1 and a weaker band at 510 cm-1. Upon reduction, the MnIIIMnIV3 species exhibits two strong IR bands at 745 and 680 cm-1, and several weaker bands are observed in the 510 - 425 cm-1 range. A normal mode analysis is performed to assign all the relevant bridging modes in the oxidized MnIV4 and reduced MnIIIMnIV3 species. The calculated force constants for the MnIV4 species are = 3.15 mdynAngstrom, = 0.55 mdyn/Angstrom, and = 0.20 mdyn/Angstrom. The force constants for the MnIIIMnIV3 species are = 3.10 mdyn/Angstrom, = 2.45 mdyn/Angstrom, = 0.40, and = 0.15 mdyn/Angstrom. This study provides insights for the identification of Mn-O modes in the IR spectra of the photosynthetic oxygen-evolving complex during its catalytic cycle.

  18. Experiment Hazard Class 4.3b - Class 3b Lasers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    system as only a class 1 or class 2 equivalent, then the requirement for training and eye exams is waived for "User Mode" only operation. Any other mode of operation of the...

  19. Videotraining: A comparison between "virtual class"

    E-Print Network [OSTI]

    Boyer, Edmond

    is to evaluate a new type of communication technology, the videoconferencing as a tool for remote training. The usage of two tools of videotraining is observed: the usage of individual computer in "virtual class" and a usage of a "remote class". In the first part, a review of the literature will enable us to present

  20. Algorithms in grid classes Ruth Hoffmann

    E-Print Network [OSTI]

    St Andrews, University of

    signs c1, . . . , cs and row signs, r1, . . . , rt and let = {(k, ) : Mk, = 0}. The map : GridAlgorithms in grid classes Ruth Hoffmann University of St Andrews, School of Computer Science Permutation Patterns 2013 Universit´e Paris Diderot 2nd July 2013 Ruth Hoffmann Algorithms in grid classes 1

  1. Testing Type Class Laws Johan Jeuring

    E-Print Network [OSTI]

    Utrecht, Universiteit

    ]. Instances of Monad should satisfy the following laws: return a>>=k k a m >>=return m m >>=(x k x>>=h) (m>>=k)>>=hTesting Type Class Laws Johan Jeuring Patrik Jansson Cl´audio Amaral Technical Report UU-CS-2012.089 3508 TB Utrecht The Netherlands #12;Testing Type Class Laws Johan Jeuring Utrecht University and Open

  2. Synthesis, crystal structure and properties of [(dien){sub 2}Mn]Ge{sub 2}S{sub 4} with mixed-valent Ge centers

    SciTech Connect (OSTI)

    Yue, Cheng-Yang; Yuan, Zhuang-Dong; Zhang, Lu-Ge; Wang, Ya-Bai; Liu, Guo-Dong; Gong, Liao-Kuo [Key Laboratory of Inorganic Chemistry in Universities of Shandong, Department of Chemistry and Chemical Engineering, Jining University, Qufu, Shandong 273155 (China); Lei, Xiao-Wu, E-mail: xwlei_jnu@163.com [Key Laboratory of Inorganic Chemistry in Universities of Shandong, Department of Chemistry and Chemical Engineering, Jining University, Qufu, Shandong 273155 (China); State Key Laboratory of Crystal Materials, Institute of Crystal Materials, Shandong University, Jinan, Shandong 250100 (China)

    2013-10-15T23:59:59.000Z

    One new manganese thiogermanate, [(dien){sub 2}Mn]Ge{sub 2}S{sub 4} (dien=diethylenetriamine), was prepared under mild solvothermal conditions and structurally and spectroscopically characterized. The title compound crystallizes in the orthorhombic system, chiral space group P2{sub 1}2{sub 1}2{sub 1} (no. 19) with a=9.113(4) Å, b=12.475(5) Å, c=17.077(7) Å, V=1941.5(15) Å{sup 3} and Z=4. Its structure features a three-dimensional (3D) network composed of a one-dimensional (1D) [Ge{sub 2}S{sub 4}]{sup 2?} anionic chain and a [(dien){sub 2}Mn]{sup 2+} complex interconnected via various hydrogen bonds. The most interesting structural feature of the compound is the presence of two different oxidation states of germanium centers in the 1D [Ge{sub 2}S{sub 4}]{sup 2?} chain, which is also supported by the result of X-ray photoelectron spectroscopy measurement. The optical property of the title compound has also been studied by UV–vis spectra. - Graphical abstract: One new thiogermanate, [(dien){sub 2}Mn]Ge{sub 2}S{sub 4}, contains a one-dimensional [Ge{sub 2}S{sub 4}]{sup 2?} anionic chain with two different oxidation states of germanium centers. Display Omitted - Highlights: • One new manganese thiogermanate [(dien){sub 2}Mn]Ge{sub 2}S{sub 4} was prepared. • The compound features 1D [Ge{sub 2}S{sub 4}]{sup 2?} chain composed of [Ge{sup II}S{sub 4}] and [Ge{sup IV}S{sub 4}] tetrahedra. • The first example of inorganic–organic hybrid thiogermanates with mixed valent Ge centers.

  3. Effect of a high electric field on the conductivity of MnGa{sub 2}S{sub 4}, MnIn{sub 2}S{sub 4}, and MnGaInS{sub 4} single crystals

    SciTech Connect (OSTI)

    Niftiev, N. N. [Azerbaijan State Pedagogical University (Azerbaijan); Tagiev, O. B. [National Academy of Sciences of Azerbaijan, Institute of Physics (Azerbaijan)

    2009-09-15T23:59:59.000Z

    The results of studying the effect of a high electric field on the conductivity of MnGa{sub 2}S{sub 4}, MnIn{sub 2}S{sub 4}, and MnGaInS{sub 4} single crystals are reported. The activation energy is determined in high and low electric fields. It is established that the decrease in the activation energy with increasing the external voltage is associated with decreasing the depth of the potential well, in which the electron is located.

  4. MATLAB tensor classes for fast algorithm prototyping.

    SciTech Connect (OSTI)

    Bader, Brett William; Kolda, Tamara Gibson (Sandia National Laboratories, Livermore, CA)

    2004-10-01T23:59:59.000Z

    Tensors (also known as mutidimensional arrays or N-way arrays) are used in a variety of applications ranging from chemometrics to psychometrics. We describe four MATLAB classes for tensor manipulations that can be used for fast algorithm prototyping. The tensor class extends the functionality of MATLAB's multidimensional arrays by supporting additional operations such as tensor multiplication. The tensor as matrix class supports the 'matricization' of a tensor, i.e., the conversion of a tensor to a matrix (and vice versa), a commonly used operation in many algorithms. Two additional classes represent tensors stored in decomposed formats: cp tensor and tucker tensor. We descibe all of these classes and then demonstrate their use by showing how to implement several tensor algorithms that have appeared in the literature.

  5. Biological Mn(II) oxidation in freshwater and marine systems : new perspectives on reactants, mechanisms and microbial catalysts of Mn cycling in the environment

    E-Print Network [OSTI]

    Clement, Brian Gregory

    2006-01-01T23:59:59.000Z

    and Oceanography 16, 107-112. Bruland K. W. (1983) Traceand Oceanography 16, 107-112. Bruland K. W. (1983) TraceLanding W. M. and Bruland K. W. (1987) The contrasting

  6. IV. -PHOTOMAGNETISM AND CONDUCT I W r PHOTOMAGNETIC EFFECT IN A Li-Mn FERRITE

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    IV. - PHOTOMAGNETISM AND CONDUCT I W r PHOTOMAGNETIC EFFECT IN A Li-Mn FERRITE P. BERNSTEIN and T'effet photomagnCtique dans le ferrite Fez,I oLi0.45Mn0.4504 au moyen de la variation de la perm investigated in a Fez.loLi0.45Mn0.4504ferrite by looking at the variations of the permeability under light

  7. Single Nanorod Devices for Battery Diagnostics: A Case Study on LiMn2O4

    E-Print Network [OSTI]

    Cui, Yi

    correlate well with the better cycling performance of Al-doped LiMn2O4 in our Li-ion battery tests: LiAl0Single Nanorod Devices for Battery Diagnostics: A Case Study on LiMn2O4 Yuan Yang, Chong Xie nanostructure devices as a powerful new diagnostic tool for batteries with LiMn2O4 nanorod materials

  8. Jan Hendrik Bruinier II Anna von Pippich Fabrizio Andreatta -Milan, Italy II Massimo Bertolini -Essen, Germany II Siegfried Bcherer -

    E-Print Network [OSTI]

    Haller-Dintelmann, Robert

    Massimo Bertolini - Essen, Germany II Siegfried Böcherer - Mannheim, Germany II Thanasis Bouganis - Durham II Jay Jorgenson - New York, USA II Winfried Kohnen - Heidelberg, Germany II Jürg Kramer - Berlin, Germany II Siddarth Sankaran - Bonn, Germany II Maryna Viazovska - Bonn, Germany II Tonghai Yang - Madison

  9. Preparation and electrochemical properties of lamellar MnO{sub 2} for supercapacitors

    SciTech Connect (OSTI)

    Yan, Jun; Wei, Tong [Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China)] [Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China); Cheng, Jie [Research Institute of Chemical Defense, Beijing 100083 (China)] [Research Institute of Chemical Defense, Beijing 100083 (China); Fan, Zhuangjun, E-mail: fanzhj666@163.com [Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China)] [Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China); Zhang, Milin [Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China)] [Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China)

    2010-02-15T23:59:59.000Z

    Lamellar birnessite-type MnO{sub 2} materials were prepared by changing the pH of the initial reaction system via hydrothermal synthesis. The interlayer spacing of MnO{sub 2} with a layered structure increased gradually when the initial pH value varied from 12.43 to 2.81, while the MnO{sub 2}, composed of {alpha}-MnO{sub 2} and {gamma}-MnO{sub 2}, had a rod-like structure at pH 0.63. Electrochemical studies indicated that the specific capacitance of birnessite-type MnO{sub 2} was much higher than that of rod-like MnO{sub 2} at high discharge current densities due to the lamellar structure with fast intercalation/deintercalation of protons and high utilization of MnO{sub 2}. The initial specific capacitance of MnO{sub 2} prepared at pH 2.81 was 242.1 F g{sup -1} at 2 mA cm{sup -2} in 2 mol L{sup -1} (NH{sub 4}){sub 2}SO{sub 4} aqueous electrolyte. The capacitance increased by about 8.1% of initial capacitance after 200 cycles at a current density of 100 mA cm{sup -2}.

  10. Metastable phase boundaries of quasicrystalline phases. [Al-Mn; Al-Ru

    SciTech Connect (OSTI)

    Follstaedt, D.M.; Knapp, J.A.

    1987-01-01T23:59:59.000Z

    The melting curve (T/sub 0/) of the metastable icosahedral phase and the liquidus of the decagonal phase of Al-Mn have been obtained for 14 to 22 at. % Mn. Icosahedral Al-Mn has a congruent melting point of 910 +- 20/sup 0/C at 20 at. % Mn, and melts approx.30/sup 0/C lower than crystalline compounds with the same composition. Icosahedral Al/sub 82/Ru/sub 18/ was determined to melt at 1260 +- 30/sup 0/C. These results were obtained by forming single-phase icosahedral alloys with ion beam mixing, and by rapid heating to accurately known temperatures with electron beams.

  11. Distinct local electronic structure and magnetism for Mn in amorphous Si and Ge

    SciTech Connect (OSTI)

    Zeng, Li; Cao, J. X.; Helgren, E.; Karel, J.; Arenholz, E.; Ouyang, Lu; Smith, David J.; Wu, R. Q.; Hellman, F.

    2010-06-01T23:59:59.000Z

    Transition metals such as Mn generally have large local moments in covalent semiconductors due to their partially filled d shells. However, Mn magnetization in group-IV semiconductors is more complicated than often recognized. Here we report a striking crossover from a quenched Mn moment (<0.1 {mu}{sub B}) in amorphous Si (a-Si) to a large distinct local Mn moment ({ge}3{mu}{sub B}) in amorphous Ge (a-Ge) over a wide range of Mn concentrations (0.005-0.20). Corresponding differences are observed in d-shell electronic structure and the sign of the Hall effect. Density-functional-theory calculations show distinct local structures, consistent with different atomic density measured for a-Si and a-Ge, respectively, and the Mn coordination number N{sub c} is found to be the key factor. Despite the amorphous structure, Mn in a-Si is in a relatively well-defined high coordination interstitial type site with broadened d bands, low moment, and electron (n-type) carriers, while Mn in a-Ge is in a low coordination substitutional type site with large local moment and holes (p-type) carriers. Moreover, the correlation between N{sub c} and the magnitude of the local moment is essentially independent of the matrix; the local Mn moments approach zero when N{sub c} > 7 for both a-Si and a-Ge.

  12. Strain mediated coupling in magnetron sputtered multiferroic PZT/Ni-Mn-In/Si thin film heterostructure

    SciTech Connect (OSTI)

    Singh, Kirandeep; Kaur, Davinder, E-mail: dkaurfph@iitr.ernet.in [Functional Nanomaterials Research Lab, Department of Physics and Centre of Nanotechnology, Indian Institute of Technology Roorkee, Roorkee-247667, Uttarakhand (India); Singh, Sushil Kumar [Functional Materials Division, Solid State Physics Lab (SSPL), DRDO, Lucknow Road, Timarpur, Delhi 110054 (India)

    2014-09-21T23:59:59.000Z

    The strain mediated electrical and magnetic properties were investigated in PZT/Ni-Mn-In heterostructure deposited on Si (100) by dc/rf magnetron sputtering. X-ray diffraction pattern revealed that (220) orientation of Ni-Mn-In facilitate the (110) oriented tertragonal phase growth of PZT layer in PZT/Ni-Mn-In heterostructure. A distinctive peak in dielectric constant versus temperature plots around martensitic phase transformation temperature of Ni-Mn-In showed a strain mediated coupling between Ni-Mn-In and PZT layers. The ferroelectric measurement taken at different temperatures exhibits a well saturated and temperature dependent P-E loops with a highest value of P{sub sat}???55 ?C/cm{sup 2} obtained during martensite-austenite transition temperature region of Ni-Mn-In. The stress induced by Ni-Mn-In layer on upper PZT film due to structural transformation from martensite to austenite resulted in temperature modulated Tunability of PZT/Ni-Mn-In heterostructure. A tunability of 42% was achieved at 290?K (structural transition region of Ni-Mn-In) in these heterostructures. I-V measurements taken at different temperatures indicated that ohmic conduction was the main conduction mechanism over a large electric field range in these heterostructures. Magnetic measurement revealed that heterostructure was ferromagnetic at room temperature with a saturation magnetization of ?123?emu/cm{sup 3}. Such multiferroic heterostructures exhibits promising applications in various microelectromechanical systems.

  13. PARS II Training Workbook (Course 103) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PARS II Training Workbook (Course 103) PARS II Training Workbook (Course 103) PARS II More Documents & Publications PARS II TRAINING PARS II TRAINING PARS II 104 Contractor Monthly...

  14. Surface Complexation of Pb(II) on Amorphous Iron Oxide and Manganese Oxide: Spectroscopic and Time Studies

    SciTech Connect (OSTI)

    Xu,Y.; Boonfueng, T.; Axe, L.; Maeng, S.; Tyson, T.

    2006-01-01T23:59:59.000Z

    Hydrous Fe and Mn oxides (HFO and HMO) are important sinks for heavy metals and Pb(II) is one of the more prevalent metal contaminants in the environment. In this work, Pb(II) sorption to HFO (Fe{sub 2}O{sub 3}{center_dot}nH{sub 2}O, n=1-3) and HMO (MnO{sub 2}) surfaces has been studied with EXAFS: mononuclear bidentate surface complexes were observed on FeO{sub 6} (MnO{sub 6}) octahedra with Pb{single_bond}O distance of 2.25-2.35 Angstroms and Pb{single_bond}Fe(Mn) distances of 3.29-3.36 (3.65-3.76) Angstroms. These surface complexes were invariant of pH 5 and 6, ionic strength 2.8x10{sup -3} to 1.5x10{sup -2}, loading 2.03x10{sup -4} to 9.1 x 10{sup -3} mol Pb/g, and reaction time up to 21 months. EXAFS data at the Fe K-edge revealed that freshly precipitated HFO exhibits short-range order; the sorbed Pb(II) ions do not substitute for Fe but may inhibit crystallization of HFO. Pb(II) sorbed to HFO through a rapid initial uptake ({approx}77%) followed by a slow intraparticle diffusion step ({approx}23%) resulting in a surface diffusivity of 2.5x10{sup -15} cm{sup 2}/s. Results from this study suggest that mechanistic investigations provide a solid basis for successful adsorption modeling and that inclusion of intraparticle surface diffusion may lead to improved geochemical transport depiction.

  15. Class 3 Tracking and Monitoring System Report

    SciTech Connect (OSTI)

    Safely, Eugene; Salamy, S. Phillip

    1999-11-29T23:59:59.000Z

    The objective of Class 3 tracking system are to assist DOE in tracking and performance and progress of these projects and to capture the technical and financial information collected during the projects' monitoring phase. The captured information was used by DOE project managers and BDM-Oklahoma staff for project monitoring and evaluation, and technology transfer activities. The proposed tracking system used the Class Evaluation Executive Report (CLEVER), a relation database for storing and disseminating class project data; GeoGraphix, a geological and technical analysis and mapping software system; the Tertiary Oil Recovery Information System (TORIS) database; and MS-Project, a project management software system.

  16. MN Office of Energy Security | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth's Heat JumpIncMAKGalway Bay IEOWCCatcher.pngWavemill <MN Office of Energy

  17. Thermal Stability of MnBi Magnetic Materials. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism in Layered NbS2 andThe1 MembersStability of MnBi Magnetic Materials.

  18. Protective effects of ebselen (Ebs) and para-aminosalicylic acid (PAS) against manganese (Mn)-induced neurotoxicity

    SciTech Connect (OSTI)

    Marreilha dos Santos, A.P., E-mail: apsantos@ff.ul.pt [I-Med.UL, Department of Toxicology and Food Sciences, Faculty of Pharmacy, University of Lisbon, Lisbon (Portugal); Lucas, Rui L.; Andrade, Vanda; Mateus, M. Luísa [I-Med.UL, Department of Toxicology and Food Sciences, Faculty of Pharmacy, University of Lisbon, Lisbon (Portugal)] [I-Med.UL, Department of Toxicology and Food Sciences, Faculty of Pharmacy, University of Lisbon, Lisbon (Portugal); Milatovic, Dejan; Aschner, Michael [Department of Pediatrics, Vanderbilt University Medical Center, Nashville, TN 37232 (United States)] [Department of Pediatrics, Vanderbilt University Medical Center, Nashville, TN 37232 (United States); Batoreu, M. Camila [I-Med.UL, Department of Toxicology and Food Sciences, Faculty of Pharmacy, University of Lisbon, Lisbon (Portugal)] [I-Med.UL, Department of Toxicology and Food Sciences, Faculty of Pharmacy, University of Lisbon, Lisbon (Portugal)

    2012-02-01T23:59:59.000Z

    Chronic, excessive exposure to manganese (Mn) may induce neurotoxicity and cause an irreversible brain disease, referred to as manganism. Efficacious therapies for the treatment of Mn are lacking, mandating the development of new interventions. The purpose of the present study was to investigate the efficacy of ebselen (Ebs) and para-aminosalicylic acid (PAS) in attenuating the neurotoxic effects of Mn in an in vivo rat model. Exposure biomarkers, inflammatory and oxidative stress biomarkers, as well as behavioral parameters were evaluated. Co-treatment with Mn plus Ebs or Mn plus PAS caused a significant decrease in blood and brain Mn concentrations (compared to rats treated with Mn alone), concomitant with reduced brain E{sub 2} prostaglandin (PGE{sub 2}) and enhanced brain glutathione (GSH) levels, decreased serum prolactin (PRL) levels, and increased ambulation and rearing activities. Taken together, these results establish that both PAS and Ebs are efficacious in reducing Mn body burden, neuroinflammation, oxidative stress and locomotor activity impairments in a rat model of Mn-induced toxicity. -- Highlights: ? The manuscript is unique in its approach to the neurotoxicity of Mn. ? The manuscript incorporates molecular, cellular and functional (behavioral) analyses. ? Both PAS and Ebs are effective in restoring Mn behavioral function. ? Both PAS and Ebs are effective in reducing Mn-induced oxidative stress. ? Both PAS and Ebs led to a decrease in Mn-induced neuro-inflammation.

  19. A new class of photoresponsive surfactants

    E-Print Network [OSTI]

    Shang, Tiangang, 1969-

    2005-01-01T23:59:59.000Z

    In this thesis, a new class of nonionic, photoresponsive surfactants consisting of a polar di(ethylene oxide) head group attached to an alkyl spacer of between two and eight methylene groups, coupled through an ether linkage ...

  20. World Class Boilers and Steam Distribution System

    E-Print Network [OSTI]

    Portell, V. P.

    WORLD CLASS BOILERS AND STEAM DISTRIBUTION SYSTEM Vernon P. Portell, Ph.D. Manager Armstrong Service, Inc. ABSTRACT categorizing, measuring, and comparing subjects which are of interest to us is the way we identify the "World class" is a... of information can also be obtained through an independent firm that provides third-party assessment of steam systems. One of these third parties, Armstrong Energy Certification, Inc., has used data gleaned from decades of industrial experience...

  1. Computer Graphics II CSC6870 Computer Graphics II CSC6870 Computer Graphics II

    E-Print Network [OSTI]

    Hua, Jing

    1 Computer Graphics II CSC6870 Computer Graphics II CSC6870 Computer Graphics II Course Information://www.cs.wayne.edu/~jinghua/6870/csc6870.htm) CSC6870 Computer Graphics II Textbooks · REQUIRED TEXTBOOK: Interactive Computer Graphics: A Top-Down Approach with Shader-Based OpenGL (6th Edition) Edward Angel, Dave Shreiner ISBN-10

  2. Minnesota Innovation Partnerships (MN-IP) Try and Buy MN-IP Try and Buy --for companies interested in licensing existing U of M inventions

    E-Print Network [OSTI]

    Minnesota, University of

    is executed BUY (LICENSE) · Low, published royalty rate, with first $1 million of product sales royalty-free · Royalty rates based on industry comparables · Royalty rate discount for MN operating companies2 · Royalty

  3. Exchange interaction mediated ferroelectricity in multiferroic MnTiO{sub 3} with anisotropic orbital hybridization and hole delocalization

    SciTech Connect (OSTI)

    Chen, S. W.; Fu, S. W.; Lee, J. M.; Lee, J. F.; Pao, C. W.; Ishii, H.; Tsuei, K. D.; Hiraoka, N.; Lu, K. T.; Chen, J. M., E-mail: jeng@phys.nthu.edu.tw, E-mail: xiaolin@uow.edu.au, E-mail: jmchen@nsrrc.org.tw [National Synchrotron Radiation Research Center, Hsinchu 30076, Taiwan (China); Lin, P. A. [Department of Physics, National Tsing Hua University, Hsinchu 30013, Taiwan (China); Jeng, H. T., E-mail: jeng@phys.nthu.edu.tw, E-mail: xiaolin@uow.edu.au, E-mail: jmchen@nsrrc.org.tw [Department of Physics, National Tsing Hua University, Hsinchu 30013, Taiwan (China); Institute of Physics, Academia Sinica, Taipei 11529, Taiwan (China); Chen, D. P.; Dou, S. X.; Wang, X. L., E-mail: jeng@phys.nthu.edu.tw, E-mail: xiaolin@uow.edu.au, E-mail: jmchen@nsrrc.org.tw [Institute for Superconducting and Electronic Materials, Australian Institute of Innovative, Materials, University of Wollongong, North Wollongong, NSW 2500 (Australia)

    2014-02-24T23:59:59.000Z

    We present the orbital structure of MnTiO{sub 3} with polarization dependent x-ray absorption and resonant x-ray emission spectra accompanied with electronic structure calculations. The results clearly indicate a strongly anisotropic O 2p-Mn 3d orbital hybridization whereas the Mn 3d hole state shows a highly delocalized characteristic ascribed to the 3d-4p mixing. The extended Mn 4p orbital could enhance the exchange interaction between Mn (3d)-O (2p)-Mn (3d) leading to an asymmetric charge distribution in Mn-O bonds. The delocalized characteristic of Mn 3d holes is indispensable to the mechanism of spin-dependent-metal-ligand hybridization to explain magnetically induced ferroelectricity.

  4. An Analysis of Mn-Zn Ferrite Microstructure by Impedance Spectroscopy, STEM and EDS Characterisations.

    E-Print Network [OSTI]

    Boyer, Edmond

    An Analysis of Mn-Zn Ferrite Microstructure by Impedance Spectroscopy, STEM and EDS.loyau@satie.ens-cachan.fr Abstract AC resistivity measurement results on Mn-Zn sintered ferrite were analyzed in the 0.1-500 MHz of the main limitations in frequency increase is the energy dissipations by losses in ferrites that produce

  5. Short communication The composite rods of MnO and multi-walled carbon nanotubes as

    E-Print Network [OSTI]

    Ceder, Gerbrand

    Short communication The composite rods of MnO and multi-walled carbon nanotubes as anode materialsO as an anode material for lithium ion batteries are significantly improved. The MnO/MWNTs composite shows a Electronic Materials Research Laboratory, Key Laboratory of the Ministry of Education, Xi'an Jiaotong

  6. NICKEL-FREE Fe-12Mn-0.2Ti ALLOY STEEL FOR CRYOGENIC APPLICATIONS

    E-Print Network [OSTI]

    Hwang, S.

    2010-01-01T23:59:59.000Z

    Parr, J. Gordon, J. Iron and Steel Inst. B, vol. 283,137 (Properties of Fe-12Mn-0.2Ti Steel at -196°C Yield Stress (FREE Fe-12Mn-O. 2Ti ALLOY STEEL FOR CRYOGENIC APPLICATIONS

  7. Tunable White-Light-Emitting Mn-Doped ZnSe Nanocrystals Vijay Kumar Sharma,

    E-Print Network [OSTI]

    Demir, Hilmi Volkan

    Tunable White-Light-Emitting Mn-Doped ZnSe Nanocrystals Vijay Kumar Sharma, Burak Guzelturk, Talha report white-light-emitting Mn-doped ZnSe nanocrystals (NCs) that are synthesized using modified orange emission (580 nm), allowed us to achieve excitation wavelength tailorable white-light generation

  8. Photovoltaic effect in multiphase Bi-Mn-O thin J. P. Chakrabartty,1

    E-Print Network [OSTI]

    Photovoltaic effect in multiphase Bi-Mn-O thin films J. P. Chakrabartty,1 R. Nechache,2,4 C and therefore the photovoltaic conversion efficiency. Specifically, a higher Bi/Mn ratio (towards unity separation. ©2013 Optical Society of America OCIS codes: (040.5350) Photovoltaic; (160.2260) Ferroelectrics

  9. austenitnoj cr-mn stali: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    cr-mn stali First Page Previous Page 1 2 3 4 5 6 Next Page Last Page Topic Index 1 Cavitation erosion of laser processed Fe-Cr-Mn and Fe-Cr-Co alloys CiteSeer Summary: Received...

  10. Class of 2007 Career Status Survey

    E-Print Network [OSTI]

    Bogaerts, Steven

    ..................................................24-26 II. Salary Statistics (Full-Time Employment Only): Starting Salaries...........................................................4 Summary Statistics..................................................................................5 Employment and Post-Baccalaureate Program Status by Major at Wittenberg......6 Employment and Post

  11. Class of 2009 Career Status Survey

    E-Print Network [OSTI]

    Bogaerts, Steven

    ..................................................22-24 II. Salary Statistics (Full-Time Employment Only): Starting Salaries...........................................................4 Summary Statistics..................................................................................5 Employment and Post-Baccalaureate Program Status by Major at Wittenberg......6 Employment and Post

  12. Class of 2010 Career Status Survey

    E-Print Network [OSTI]

    Bogaerts, Steven

    ..................................................23-25 II. Salary Statistics (Full-Time Employment Only): Starting Salaries...........................................................4 Summary Statistics..................................................................................5 Employment and Post-Baccalaureate Program Status by Major at Wittenberg......6 Employment and Post

  13. Class of 2008 Career Status Survey

    E-Print Network [OSTI]

    Bogaerts, Steven

    ..................................................22-24 II. Salary Statistics (Full-Time Employment Only): Starting Salaries...........................................................4 Summary Statistics..................................................................................5 Employment and Post-Baccalaureate Program Status by Major at Wittenberg......6 Employment and Post

  14. Surface alloys of icosahedral AlMnSi with phason distortions

    SciTech Connect (OSTI)

    Follstaedt, D.M.; Knapp, J.A.

    1986-12-01T23:59:59.000Z

    The microstructures produced by electron-beam melting and by ion-beam mixing Al/Mn and Al/Mn/Si layers on Si substrates are examined. The treatments were found to incorporate Si from the substrate into the surface alloy. Several phases formed, depending on treatment, including ..cap alpha..- and ..beta..-AlMnSi, ..mu..-AlMn (epitaxial on Si(111), and amorphous and icosahedral AlMnSi. The observed microstructures relate the novel icosahedral phase to other phases and elucidate its formation kinetics. Diffraction patterns from large icosahedral grains (up to 5 ..mu..m) show distortions in the position and shape of weak (but not strong) reflections, as predicted for phason defects in a quasicrystalline lattice, one of the structures proposed for icosahedral phases.

  15. Structural and Magnetic Properties of Co-Mn-Sb Thin films

    SciTech Connect (OSTI)

    Meinert, M.; Schmalhorst, J.-M.; Ebke, D.; Liu, N. N.; Thomas, A.; Reiss, G.; Kanak, J.; Stobiecki, T.; Arenholz, E.

    2009-12-17T23:59:59.000Z

    Thin Co-Mn-Sb films of different compositions were investigated and utilized as electrodes in alumina based magnetic tunnel junctions with CoFe counterelectrode. The preparation conditions were optimized with respect to magnetic and structural properties. The Co-Mn-Sb/Al-O interface was analyzed by x-ray absorption spectroscopy and magnetic circular dichroism with particular focus on the element-specific magnetic moments. Co-Mn-Sb crystallizes in different complex cubic structures depending on its composition. The magnetic moments of Co and Mn are ferromagnetically coupled in all cases. A tunnel magnetoresistance ratio of up to 24% at 13 K was found and indicates that Co-Mn-Sb is not a ferromagnetic half-metal. These results are compared to recent works on the structure and predictions of the electronic properties.

  16. Magnetism of NiMn2O4-Fe3O4 spinel interfaces

    SciTech Connect (OSTI)

    Arenholz, Elke; Nelson-Cheeseman, B. B.; Chopdekar, R. V.; Bettinger, J. S.; Arenholz, E.; Suzuki, Y.

    2007-09-13T23:59:59.000Z

    We investigate the magnetic properties of the isostructural spinel-spinel interface of NiMn{sub 2}O{sub 4}(NMO)-Fe{sub 3}O{sub 4}. Although the magnetic transition temperature of the NMO film is preserved, both bulk and interface sensitive measurements demonstrate that the interface exhibits strong interfacial magnetic coupling up to room temperature. While NMO thin films have a ferrimagnetic transition temperature of 60 K, both NiFe{sub 2}O{sub 4} and MnFe{sub 2}O{sub 4} are ferrimagnetic at room temperature. Our experimental results suggest that these magnetic properties arise from a thin interdiffused region of (Fe,Mn,Ni){sub 3}O{sub 4} at the interface, leading to Mn and Ni magnetic properties similar to those of MnFe{sub 2}O{sub 4} and NiFe{sub 2}O{sub 4}.

  17. Neutron diffraction study of MnNiGa{sub 2}—Structural and magnetic behaviour

    SciTech Connect (OSTI)

    Wang, J. L., E-mail: jianli@uow.edu.au [Institute for Superconductivity and Electronic Materials, University of Wollongong, Wollongong, NSW 2522 (Australia); Bragg Institute, ANSTO, Lucas Heights, NSW 2234 (Australia); School of Physical, Environmental and Mathematical Sciences, The University of New South Wales, Canberra, ACT 2600 (Australia); Ma, L.; Wu, G. H. [Institute of Physics, Chinese Academy of Science, Beijing 100190 (China); Hofmann, M. [FRM-II, Technische Universität München, 85747 Garching (Germany); Avdeev, M.; Kennedy, S. J. [Bragg Institute, ANSTO, Lucas Heights, NSW 2234 (Australia); Campbell, S. J. [School of Physical, Environmental and Mathematical Sciences, The University of New South Wales, Canberra, ACT 2600 (Australia); Md Din, M. F.; Dou, S. X. [Institute for Superconductivity and Electronic Materials, University of Wollongong, Wollongong, NSW 2522 (Australia); Hoelzel, M. [FRM-II, Technische Universität München, 85747 Garching (Germany); Fachbereich Materialwissenschaften, Technische Universität Darmstadt, 64287 Darmstadt (Germany)

    2014-05-07T23:59:59.000Z

    MnNiGa{sub 2} crystallizes in the L21 (Heusler) structure and has a ferromagnetic ordering temperature T{sub C}???192?K. Rietveld refinement of the neutron diffraction patterns indicates that the Ga atoms occupy the equivalent 8c position, while Mn and Ni share the 4a (0, 0, 0) and 4b (0.5, 0.5, 0.5) sites with a mixed occupancy of Mn and Ni atoms. It is found that that ?83% of Mn and ?17% Ni are located at the 4a site while ?83% of Ni and ?17% Mn occupy the 4b site. There is no evidence of a magneto-volume effect around T{sub C}. In agreement with this finding, our detailed critical exponent analyses of isothermal magnetization curves and the related Arrott plots confirm that the magnetic phase transition at T{sub C} is second order.

  18. Smaller Classes and Student Achievement: Three Papers Exploring the Class Size Effect

    E-Print Network [OSTI]

    Collins, Courtney

    2011-08-08T23:59:59.000Z

    -K class who reminded me that education is nothing if it does not sparkle. And most important, I want to thank God?who is mighty even when I am not, and who understood everything, econometrics and all, before the world began. Thank you... Page III.7 Conclusions and Future Work ............................................................ 72 IV DOES SORTING STUDENTS IMPROVE SCORES? AN ANALYSIS OF CLASS SIZE AND CLASS COMPOSITION...

  19. ClassWaiver-PUA.pdf | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    ClassWaiver-PUA.pdf More Documents & Publications ClassWaiverNPUA-2.pdf EXHIBIT A: CRADA, WFO, PUA and NPUA Comparison Table, with suggested changes Class Patent Waiver...

  20. Class_Waiver_NPUA-2.pdf | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    lassWaiverNPUA-2.pdf ClassWaiverNPUA-2.pdf More Documents & Publications EXHIBIT A: CRADA, WFO, PUA and NPUA Comparison Table, with suggested changes ClassWaiver-PUA.pdf Class...

  1. Shifting Interest Regimes of the Working Classes in Latin America

    E-Print Network [OSTI]

    Berins Collier, Ruth; Handlin, Samuel P.

    2005-01-01T23:59:59.000Z

    Handlin IIR Working Paper Shifting Interest Regimes of the2000), “Working-Class Power, Capitalist-Class Interest, andShifting Interest Regimes of the Working Classes in Latin

  2. Mn3O4-Graphene Hybrid as a High-Capacity Anode Material for Lithium Ion Hailiang Wang,,

    E-Print Network [OSTI]

    Cui, Yi

    Mn3O4-Graphene Hybrid as a High-Capacity Anode Material for Lithium Ion Batteries Hailiang Wang hybrid materials of Mn3O4 nanoparticles on reduced graphene oxide (RGO) sheets for lithium ion battery stability, owing to the intimate interactions between the graphene substrates and the Mn3O4 nanoparticles

  3. Electronic structure of the molecule-based magnet MnN,,CN...22 from theory and experiment

    E-Print Network [OSTI]

    Liu, Amy Y.

    , Louisiana 70118 Received 27 November 2001; published 24 July 2002 The electronic structure of the Mn-based determined recently by Kurmoo and Kepert.2,3 More recently, x-ray structure of the Mn-based material has beenElectronic structure of the molecule-based magnet MnN,,CN...22 from theory and experiment M. R

  4. Smog Check II Evaluation Part II: Overview of Vehicle

    E-Print Network [OSTI]

    Denver, University of

    Smog Check II Evaluation Part II: Overview of Vehicle Emissions . . . . . . . . . . . . Prepared in Later Sections ____________________ 1 3. Older Vehicles Have Higher Emissions on Average _____________ 3 4. The Vehicle Fleet Is Dominated by Newer Vehicles______________ 8 5. More Recent Vehicle Models

  5. Vehicle Technologies Office Merit Review 2014: Class 8 Truck...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Class 8 Truck Freight Efficiency Improvement Project Vehicle Technologies Office Merit Review 2014: Class 8 Truck Freight Efficiency Improvement Project Presentation given by...

  6. FAKULTT II MATHEMATIK UND

    E-Print Network [OSTI]

    Nabben, Reinhard

    OF A NETWORK CREATION GAME WITH EXPONENTIAL PAYOFF by NADINE BAUMANN SEBASTIAN STILLER No. 2007/19 #12;The Price of Anarchy of a Network Creation Game with Exponential Payoff Nadine Baumann Sebastian Stiller May/5-3. Technische Universität Berlin, Fakultät II, Stra�e des 17. Juni 136, 10623 Berlin, Germany. Email: stiller

  7. Atmospheric Dynamics II Instructor

    E-Print Network [OSTI]

    AT602 Atmospheric Dynamics II 2 credits Instructor: David W. J. Thompson davet: An Introduction to Dynamic Meteorology, 5th Edition, Academic Press (recommended) · Marshall, J., and Plumb, R. A., 2008: Atmosphere, Ocean, and Climate Dynamics: An Introductory Text, Academic Press. · Vallis, G. K

  8. Polymorphism of the MHC class II Eb gene determines the protection against collagen-induced arthritis

    SciTech Connect (OSTI)

    Gonzalez-Gay, M.A.; Zanelli, E.; Krco, C.J. [Mayo Clinic and Mayo Graduate School of Medicine, Rochester, MN (United States)] [and others

    1995-05-01T23:59:59.000Z

    Collagen-induced arthritis (CIA) is an animal model of auto immune polyarthritis, sharing similarities with rheumatoid arthritis (RA). Paradoxally, susceptibility to mouse CIA is controlled by the H2A loci (DQ homologous) while RA is linked to HLA.DR genes (H2E homologous). We recently showed that the E{beta}{sup d} molecule prevents CIA development in susceptible H2{sup q} mice. We addressed the question of whether H2Eb polymorphism will influence CIA incidence as HLA.DRB1 polymorphism does in RA. In F{sub 1} mice, only H2Eb{sup d} and H2Eb{sup s} molecules showed protection. Using recombinant B10.RDD (Eb{sup d/b}) mice, we found that CIA protection was mediated by the first domain of the E{beta}{sup d} molecule. Using peptides covering the third hypervariable region of the E{beta} chain, we found a perfect correlation between presentation of E{beta} peptides by the H2A{sup q} molecule and protection on CIA. Therefore, the mechanism by which H2Eb protects against CIA seems to rely on the affinity of E{beta} peptides for the H2A{sup q} molecule. 35 refs., 2 figs., 3 tabs.

  9. Voraussetzungen: Control Systems I & II, System Modeling, Engine Class (IC Engines and Propulsion Systems,

    E-Print Network [OSTI]

    Lygeros, John

    ein neues Motorkonzept Positionsregelung eines Verbrennungsmotors (Simulation) Beschreibung: Für ein

  10. Voraussetzungen: Control Systems I & II, System Modeling, Engine Class (IC Engines and Propulsion Systems,

    E-Print Network [OSTI]

    Lygeros, John

    , voserc@ethz.ch Regelung für ein neues Motorkonzept Positionsregelung eines Verbrennungsmotors (Simulation

  11. Prediction of the binding affinities of peptides to class II MHC using a ...

    E-Print Network [OSTI]

    andrew

    2010-01-18T23:59:59.000Z

    We introduce a new model for predicting binding affinities of peptides to ... peptide residues so that the total binding energy is a sum of the binding energies of.

  12. Annihilators for the class group of a cyclic field of prime power degree II

    E-Print Network [OSTI]

    Kuèera, Radan

    and Radan Kucera Abstract We prove, for a field K which is cyclic of odd prime power degree over]. To explain the significance of our main result (for more details and for references, see [GK2]) we use a bit

  13. ES2A7 -Fluid Mechanics Example Classes Model Answers to Example Questions (Set II)

    E-Print Network [OSTI]

    Thomas, Peter J.

    of msvp = 2 -1 . Calculate the mean model wind tunnel speed if the model is made to 1/10 scale. Assume in a wind tunnel. The airspeed range to be investigated is at the docking end of its range, a maximum -=-=-= --- Question 4: Sliding Board #12;A board with an area slides down an inclined ramp as is schematically

  14. ES2A7 -Fluid Mechanics Example Classes Example Questions (Set II)

    E-Print Network [OSTI]

    Thomas, Peter J.

    end of its range, a maximum of msvp = 2 -1 . Calculate the mean model wind tunnel speed if the model = 20 m needs to be studied in a wind tunnel. The airspeed range to be investigated is at the docking an inclined ramp as is schematically illustrated in Figure 3. The ramp is inclined at an angle . The weight

  15. Electric Motors and Generators for Use in Hazardous Locations, Class II, Groups E, F and G 

    E-Print Network [OSTI]

    Anonymous

    This Standard represents the judgment of Undenvriters' Laboratories, Inc., as to the basic requirements for the construction and performance of the products to be Listed under this category. These requirements are based ...

  16. E-Print Network 3.0 - aberrant class ii Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the diffraction limit... , but there are situations in which having slightly aberrated optics can provide some relative visual benefits. This fact led Source: Artal, Pablo -...

  17. Characterization of a major histocompatibility class II A gene (Clha-DAA) with an embedded microsatellite

    E-Print Network [OSTI]

    Ruzzante, Daniel E.

    ¨teborg University, Tja¨rno¨ Marine Biological Laboratory, S-45296, Stro¨mstad, Sweden and #Department of Biology

  18. Characterization of the dual start motif of a class II holin gene

    E-Print Network [OSTI]

    Barenboim, Maxim

    2012-06-07T23:59:59.000Z

    and Siminovitch, 197 la; Campbell and Rolfe, 1975; Young, 1992). Lysis can be prematurely triggered as early as 20 minutes after induction. However, the rate of lysis, as judged by the lysis profile, depends on the concentration of the S protein in the inner...

  19. Improved Oil Recovery in Mississippian Carbonate Reservoirs of Kansas - Near-Term, Class II

    SciTech Connect (OSTI)

    Carr, Timothy R.; Green, Don W.; Willhite, G. Paul

    2001-10-30T23:59:59.000Z

    The focus of this project was development and demonstration of cost-effective reservoir description and management technologies to extend the economic life of mature reservoirs in Kansas and the mid-continent.

  20. Directed Evolution of Soluble Single-chain Human Class II MHC Molecules

    E-Print Network [OSTI]

    Zhao, Huimin

    diabetes, transplant rejection and certain infectious diseases such as malaria.2,3 A detailed understanding

  1. Prerequisites: Control Systems I+II, Engine Class (IC Engines and Propulsion Systems, Introduction to

    E-Print Network [OSTI]

    Daraio, Chiara

    to Modeling and Control of Internal Combustion Engine Systems,...), Model Predictive Control, Matlab Iterative Learning Control for Internal Combustion Engines Modeling and Control Description: In classical. The objective of this work is to apply learning algorithms to highly dynamic internal combustion engines

  2. Prerequisites: Control Systems I+II, System Modeling, Engine Class (Introduction to Modeling and Control of

    E-Print Network [OSTI]

    Daraio, Chiara

    and Control of Internal Combustion Engine Systems, IC Engines, ...), Optimization Course, Matlab The gas-diesel engine is a natural gas engine, where the combustion is initiated by a small quantity on the investigation of the combustion process of the gas-diesel engine. A highly flexible engine test-bench with COC

  3. Prerequisites: Control Systems I+II, Engine Class (IC Engines and Propulsion Systems, Introduction to

    E-Print Network [OSTI]

    Daraio, Chiara

    to Modeling and Control of Internal Combustion Engine Systems,...), Matlab/Simulink experience Contact for a Novel Engine Concept Position Control for an Internal Combustion Engine (Simulation) Description an internal combustion engine piston follow a reference position trajectory with sufficient accuracy

  4. Prevalence of class 1 and class 2 integrons in poultry processing and a natural water ecosystem

    E-Print Network [OSTI]

    Roe, Matthew Todd

    2002-01-01T23:59:59.000Z

    Class-4 nrft Integron (VCR Regions) vin4 nrf2 nr13 torttA nrfd nrfS nrf6 nr17 FIG. 2. Representations of the three classes of integron gene sequences found in nature. attl-integration site; P evariable region promoter; open circle-59 base element...

  5. Soit la classe TestDate suivante public class TestDate{

    E-Print Network [OSTI]

    Belaïd, Abdel

    Marque(){ return marque; } } La classe suivante nous permet de construire une voiture de type BMW avec des pneus Bridgestone public class TestVoiture{ public static void main(String argv[]){ Voiture BMW= new Voiture("BMW","Bridgestone"); System.out.println("la marque de la voiture est : " + BMW.getMarque()); for (int i=0; i

  6. Magnetic phase diagram of magnetoelectric LiMnPO4

    SciTech Connect (OSTI)

    Toft-Petersen, Rasmus; Andersen, Niels H.; Li, Haifeng; Li, Jiying; Tian, Wei; Budko, Serguei L.; Jensen, Thomas B.S.; Niedermayer, Christof; Laver, Mark; Zaharko, Oksana; Lynn, Jeffrey W.; Vaknin, David

    2012-06-14T23:59:59.000Z

    The nature of the spin-flop (SF) transition in the magnetoelectric quasi-2D Heisenberg system LiMnPO4 is studied in fields applied along the a axis. A refinement of the magnetic structure using neutron diffraction data in the SF phase reveals that the spins reorient from being parallel to the a axis to be nearly along the c axis at magnetic fields between 4 and 4.7 T, depending on temperature. The low-field antiferromagnetic phase boundary is shown to join the spin-flop line tangentially at the so-called bicritical point, where there is a suppression of the ordering temperature. At the bicritical field, we observe an increased intensity of the Lorentz broadened elastic scattering at magnetic Bragg peaks above TN as compared to zero field and 10 T, without an increase in peak width. This suggests an increased density of fluctuations at the bicritical field as compared to zero field.

  7. Low-temperature magnetization of (Ga,Mn) As semiconductors

    E-Print Network [OSTI]

    Jungwirth, T.; Masek, J.; Wang, KY; Edmonds, KW; Sawicki, M.; Polini, M.; Sinova, Jairo; MacDonald, AH; Campion, RP; Zhao, LX; Farley, NRS; Johal, TK; van der Laan, G.; Foxon, CT; Gallagher, BL.

    2006-01-01T23:59:59.000Z

    of the Zeeman Hamil- tonian gS#3;BBS?z+gj#3;BBj?z, and from Eq. #1;1#2;: m ? mMF #14; mQF = ? #3;B j S + j #1;gS ? gj#2; . #1;5#2; When j=1/2 and gS=gj =2 the quantum fluctuation correc- tion to the magnetization vanishes even though the mean- field...Low-temperature magnetization of (Ga,Mn)As semiconductors T. Jungwirth,1,2 J. Ma?ek,3 K. Y. Wang,2 K. W. Edmonds,2 M. Sawicki,4 M. Polini,5 Jairo Sinova,6 A. H. MacDonald,7 R. P. Campion,2,8 L. X. Zhao,2,8 N. R. S. Farley,2,8 T. K. Johal,8 G. van...

  8. Ferromagnetism in Mn-Implanted Epitaxially Grown Ge on Si(100)

    SciTech Connect (OSTI)

    Guchhait, S.; Jamil, M.; Ohldag, H.; Mehta, A.; Arenholz, E.; Lian, G.; Li Fatou, A.; Ferrer, D. A.; Markert, J. T.; Colombo, L.; Banerjee, S. K.

    2011-01-05T23:59:59.000Z

    We have studied ferromagnetism of Mn-implanted epitaxial Ge films on silicon. The Ge films were grown by ultrahigh vacuum chemical vapor deposition using a mixture of germane (GeH{sub 4}) and methylgermane (CH{sub 3}GeH{sub 3}) gases with a carbon concentration of less than 1 at. %, and observed surface rms roughness of 0.5 nm, as measured by atomic force microscopy. Manganese ions were implanted in epitaxial Ge films grown on Si (100) wafers to an effective concentration of 16, 12, 6, and 2 at. %. Superconducting quantum interference device measurements showed that only the three highest Mn concentration samples are ferromagnetic, while the fourth sample, with [Mn] = 2 at. %, is paramagnetic. X-ray absorption spectroscopy and x-ray magnetic circular dichroism measurements indicate that localized Mn moments are ferromagnetically coupled below the Curie temperature. Isothermal annealing of Mn-implanted Ge films with [Mn] = 16 at. % at 300 C for up to 1200 s decreases the magnetization but does not change the Curie temperature, suggesting that the amount of the magnetic phase slowly decreases with time at this anneal temperature. Furthermore, transmission electron microscopy and synchrotron grazing incidence x-ray diffraction experiments show that the Mn-implanted region is amorphous, and we believe that it is this phase that is responsible for the ferromagnetism. This is supported by our observation that high-temperature annealing leads to recrystallization and transformation of the material into a paramagnetic phase.

  9. Ferrimagnetism and disorder of epitaxial Mn2-xCoxVAl Heusler compound thin films

    SciTech Connect (OSTI)

    Meinert, Markus; Schmalhorst, Jan-Michael; Reiss, Gunter; Arenholz, Elke

    2011-01-29T23:59:59.000Z

    The quaternary full Heusler compound Mn{sub 2-x}Co{sub x}VAl with x = 1 is predicted to be a half-metallic antiferromagnet. Thin films of the quaternary compounds with x = 0-2 were prepared by dc and RF magnetron co-sputtering on heated MgO (0 0 1) substrates. The magnetic structure was examined by x-ray magnetic circular dichroism and the chemical disorder was characterized by x-ray diffraction. Ferrimagnetic coupling of V to Mn was observed for Mn{sub 2}VAl (x = 0). For x = 0.5, we also found ferrimagnetic order with V and Co antiparallel to Mn. The observed reduced magnetic moments are interpreted with the help of band structure calculations in the coherent potential approximation. Mn{sub 2}VAl is very sensitive to disorder involving Mn, because nearest-neighbour Mn atoms couple antiferromagnetically. Co{sub 2}VAl has B2 order and has reduced magnetization. In the cases with x {ge} 0.9 conventional ferromagnetism was observed, closely related to the atomic disorder in these compounds.

  10. Framework-incorporated Mn and Co analcime zeolites: Synthesis and characterization

    SciTech Connect (OSTI)

    Azizi, Seyed Naser, E-mail: azizi@umz.ac.ir [Analytical Division, Faculty of Chemistry, University of Mazandaran, P.O. Box 47416-95447, Babolsar (Iran, Islamic Republic of); Ehsani Tilami, Salma [Analytical Division, Faculty of Chemistry, University of Mazandaran, P.O. Box 47416-95447, Babolsar (Iran, Islamic Republic of)] [Analytical Division, Faculty of Chemistry, University of Mazandaran, P.O. Box 47416-95447, Babolsar (Iran, Islamic Republic of)

    2013-02-15T23:59:59.000Z

    The framework-substituted cobalt and manganese analcime zeolites were synthesized via a direct hydrothermal approach. The obtained samples were characterized by XRD powder, SEM-EDX, nitrogen physical adsorption, Raman microscopy, diffuse reflectance UV-Vis and IR spectroscopy which complementarily demonstrated the incorporation of cobalt and manganese into the zeolites framework. The results showed that substitution of Mn and Co could be placed in two synthesis gels with same compositions containing Al/Mn=5 and Al/Co=4 mol ratios, respectively. In addition, with replacing Al with Mn and synthesis of Mn-modified analcime, zeolite with higher surface area and pore volume could be achieved than the Co modified analcime. - Graphical abstract: The images and adsorption-desorption isotherms of N{sub 2} at 77 K for (a) Co (b) Mn modified analcime. Highlights: Black-Right-Pointing-Pointer Synthesis of Co and Mn modified analcime for the first time. Black-Right-Pointing-Pointer Framework-incorporation of Co and Mn using the same silicate gel composition. Black-Right-Pointing-Pointer Applying several techniques to provide proofs for the characterization.

  11. Large interface diffusion in endotaxial growth of MnP films on GaP substrates

    SciTech Connect (OSTI)

    Nateghi, N., E-mail: seyyed-nima.nateghi@polymtl.ca; Ménard, D.; Masut, R. A. [Regroupement québécoise sur les matériaux de pointe (RQMP), Département de Génie Physique, Polytechnique Montréal, C.P. 6079, succ. Centre-ville, Montréal, Québec H3C 3A7 (Canada)

    2014-10-07T23:59:59.000Z

    The metal organic vapor deposition of MnP films on GaP (100) substrates is shown to have a substantial endotaxial component. A study of the growth time evolution of the endotaxial depths of MnP grains reveals a diffusion-controlled growth with a relatively large diffusion coefficient of Mn in GaP. The value (2.2?±?1.5)?×?10{sup ?15} (cm{sup 2}/s) obtained at 650?°C is at least two orders of magnitude larger than the reported Mn diffusion in bulk GaP. GaP surface mounds provide further indirect evidence that this large diffusion coefficient is concurrent with the out-diffusion of Ga atoms at the growing MnP/GaP interface. No trace of dislocations could be observed at or near this interface, which strongly suggests that Mn diffusion occurs through vacant sites generated by the difference between the crystallographic structures of MnP and GaP.

  12. Fluorescence of [Fe II] in H II regions

    E-Print Network [OSTI]

    M. Rodriguez

    1999-06-17T23:59:59.000Z

    A study of [Fe II] lines at various positions within the H II regions M42 and M43 is presented. The relative intensities of selected optical [Fe II] lines are shown to be correlated with the intensity of the apparent nebular continuous spectrum. Since the continuum of H II regions is known to be mostly stellar radiation scattered by dust intermixed with the emitting gas, these correlations provide direct evidence for the existence of fluorescent excitation in the formation process of the [Fe II] lines, irrespective of the prevailing physical state.

  13. DAFS study of site-specific local structure of Mn in manganese ferrite films.

    SciTech Connect (OSTI)

    Kravtsov, E.; Haskel, D.; Cady, A.; Yang, A.; Vittoria, C.; Zuo, X.; Harris, V. G.; X-Ray Science Division; Inst. of Metal Physics; Northeastern Univ.; Nankai Univ.

    2006-01-01T23:59:59.000Z

    Manganese ferrite (MnFe{sub 2}O{sub 4}) is a well-known magnetic material widely used in electronics for many years. It is well established that its magnetic behavior is strongly influenced by local structural properties of Mn ions, which are distributed between crystallographically inequivalent tetrahedral and octahedral sites in the unit cell. In order to understand and be able to tune properties of these structures, it is necessary to have detailed site-specific structural information on the system. Here we report on the application of diffraction-anomalous fine structure (DAFS) spectroscopy to resolve site-specific Mn local structures in manganese ferrite films. The DAFS measurements were done at undulator beamline 4-ID-D of the Advanced Photon Source at Argonne National Laboratory. The DAFS spectra (Fig. 1) were measured at several Bragg reflections in the vicinity of the Mn absorption K-edge, having probed separately contributions from tetrahedrally and octahedrally coordinated Mn sites. The DAFS data analysis done with an iterative Kramers-Kroenig algorithm made it possible to solve separately the local structure around different inequivalent Mn sites in the unit cell. The reliability of the data treatment was checked carefully, and it was showed that the site-specific structural parameters obtained with DAFS allow us to describe fluorescence EXAFS spectrum measured independently. Fig. 2 shows individual site contributions to the imaginary part of the resonant scattering amplitude obtained from the treatment of the data of Fig. 1. The analysis of the refined site-specific absorption spectra was done using EXAFS methods based on theoretical standards. We provided direct evidence for the tetrahedral Mn-O bond distance being increased relative to the corresponding Fe-O distance in bulk manganese ferrites. The first coordination shell number was found to be reduced significantly for Mn atoms at these sites. This finding is consistent with the well-known tendency of Mn to be tetrahedrally coordinated in these compounds.

  14. Quantum interference in exciton-Mn spin interactions in a CdTe semiconductor quantum dot

    E-Print Network [OSTI]

    Trojnar, A; Kadantsev, E; Hawrylak, P; Goryca, M; Kazimierczuk, T; Kossacki, P; Wojnar, P; Potemski, M

    2011-01-01T23:59:59.000Z

    We show theoretically and experimentally the existence of a new quantum interference(QI) effect between the electron-hole interactions and the scattering by a single Mn impurity. Theoretical model, including electron-valence hole correlations, the short and long range exchange interaction of Mn ion with the heavy hole and with electron and anisotropy of the quantum dot, is compared with photoluminescence spectroscopy of CdTe dots with single magnetic ions. We show how design of the electronic levels of a quantum dot enable the design of an exciton, control of the quantum interference and hence engineering of light-Mn interaction.

  15. Quantum interference in exciton-Mn spin interactions in a CdTe semiconductor quantum dot

    E-Print Network [OSTI]

    A. Trojnar; M. Korkusinski; E. Kadantsev; P. Hawrylak; M. Goryca; T. Kazimierczuk; P. Kossacki; P. Wojnar; M. Potemski

    2011-05-04T23:59:59.000Z

    We show theoretically and experimentally the existence of a new quantum interference(QI) effect between the electron-hole interactions and the scattering by a single Mn impurity. Theoretical model, including electron-valence hole correlations, the short and long range exchange interaction of Mn ion with the heavy hole and with electron and anisotropy of the quantum dot, is compared with photoluminescence spectroscopy of CdTe dots with single magnetic ions. We show how design of the electronic levels of a quantum dot enable the design of an exciton, control of the quantum interference and hence engineering of light-Mn interaction.

  16. Melting point measurements for quasicrystalline phases. [Al-Mn; icosahedral and decagonal phases

    SciTech Connect (OSTI)

    Knapp, J.A.; Follstaedt, D.M.

    1986-01-01T23:59:59.000Z

    Melting transitions of metastable quasicrystalline phases of Al-Mn have been observed using rapid electron-beam heating of fine-grained icosahedral surface layers. The congruent melting point for icosahedral Al/sub 80/Mn/sub 20/ was directly measured to be 910 +- 20/sup 0/C. Heating to higher temperatures shows another transition which is inferred to correspond to the liquidus of the decagonal phase at 965 +- 20/sup 0/C for 20 at. % Mn. The microstructure and formation kinetics of the decagonal phase are discussed, and its electron diffraction is described.

  17. Collaborative Approach World-Class Facilities

    E-Print Network [OSTI]

    Chen, Tsuhan

    .5 million from the Department of Energy, along with additional funds from New York State, for an EnergyWCMC Collaborative Approach World-Class Facilities Research at Cornell /A Statistical Excerpt York 08 Funding Cornell's Research 09 Expending Research Dollars 10 Funding Graduate Education 12

  18. Class of Jost-like functions

    SciTech Connect (OSTI)

    Adhikari, S.K.; Tomio, L.

    1987-06-01T23:59:59.000Z

    A class of functions having the same analytic properties as the Jost function is introduced. In momentum space these functions can be calculated through solutions of some auxiliary integral equations. The present approach is applicable for both local and nonlocal potentials and suggests an unified calculational scheme for bound states and scattering problems.

  19. Building Class Sensitive Models for Tracking Applications

    E-Print Network [OSTI]

    Magee, Derek

    ) and on Eigenface images [11]. The two spaces produced by delta analysis may be used in conjunction to describe. The objective of creating these spaces is to improve the efficiency of eigenspace search algo­ rithms. The inter­class optimised space may also be used to improve classi­ fication and a quantitative evaluation of this against

  20. College of Engineering WORLD-CLASS ENGINEERING

    E-Print Network [OSTI]

    Maroncelli, Mark

    College of Engineering WORLD-CLASS ENGINEERING in Learning, Discovery and Engagement 2014-2019 STRATEGY #12;College of Engineering PREAMBLE The College of Engineering at Penn State is a leading academy, research enterprise and service to the global engineering community. Innovation is a hallmark of Penn State

  1. APPLIED GEOPHYSICS FIELD CLASS GEOLOGY 437

    E-Print Network [OSTI]

    Nickrent, Daniel L.

    APPLIED GEOPHYSICS FIELD CLASS GEOLOGY 437 SPRING 2014 OF NATURAL RESOURCES INCLUDING OIL, COAL, MINERALS AND GROUNDWATER. OTHER APPLICATIONS OF GEOPHYSICS MAY, IF AVAILABLE, WE WILL VISIT AN OIL DRILLING RIG IN OPERATION. DATES FOR FIELD TRIPS WILL DEPEND ON THE WEATHER

  2. Quarterly Class Schedule Lee County Extension

    E-Print Network [OSTI]

    Hill, Jeffrey E.

    INDUSTRY BEST MANAGEMENT PRACTICES Stephen Brown, Tom Becker, Joy Hazell This is a required class VOLUNTEER TRAINING Tom Becker The mission of the Lee County Master Gardner program is to train and inspire 533-7512 or email tbecker@leegov.com FLORIDA YARDS AND NEIGHBORHOODS Tom Becker Learn the 9 principles

  3. CHEMICAL THERMODYNAMICS AND KINETICS Class Meetings

    E-Print Network [OSTI]

    Sherrill, David

    CHEM 6471 CHEMICAL THERMODYNAMICS AND KINETICS Class Meetings 9:35 ­ 10:55 am, Tuesday and Thursday of October 22-26 Textbooks Molecular Thermodynamics by D.A McQuarrie and J.D. Simon, University Science Books the laws of classical thermodynamics and some of their chemical applications. It also covers basic

  4. Workplace Violence Prevention Employee Awareness Class

    Broader source: Energy.gov [DOE]

    The Office of Health, Safety, and Security has been working to organize a Workplace Violence Prevention Program that includes dealing with the Active Shooter scenario. After the Navy Yard event, HSS has been trying to accelerate the roll out. Next week we start two-a-days for the Employee Awareness class, which is the first step in the program development and roll out.

  5. EHSO TRAINING CLASSES Fire Safety Program Training

    E-Print Network [OSTI]

    EHSO TRAINING CLASSES Fire Safety Program Training 1. Fire Safety (60 minutes) Instruction includes an actual fire eperience. 2. Fire Extinguisher Training (30 minutes) A practical demonstration on actual burnable liquid fires. This practical extinguisher training is a critical portion of the fire

  6. Ribosomal Database Project II

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The Ribosomal Database Project (RDP) provides ribosome related data and services to the scientific community, including online data analysis and aligned and annotated Bacterial small-subunit 16S rRNA sequences. As of March 2008, RDP Release 10 is available and currently (August 2009) contains 1,074,075 aligned 16S rRNA sequences. Data that can be downloaded include zipped GenBank and FASTA alignment files, a histogram (in Excel) of the number of RDP sequences spanning each base position, data in the Functional Gene Pipeline Repository, and various user submitted data. The RDP-II website also provides numerous analysis tools.[From the RDP-II home page at http://rdp.cme.msu.edu/index.jsp

  7. PARS II TRAINING | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    TRAINING PARS II TRAINING BASICS TRAINING WORKBOOK PARS II TRAINING More Documents & Publications PARS II PARS II Training Workbook (Course 103) PARSIIUserGuideV1.0Draft.pdf...

  8. NEWLY IDENTIFIED EXTENDED GREEN OBJECTS (EGOs) FROM THE SPITZER GLIMPSE II SURVEY. II. MOLECULAR CLOUD ENVIRONMENTS

    SciTech Connect (OSTI)

    Chen Xi; Gan Conggui; Shen Zhiqiang [Key Laboratory for Research in Galaxies and Cosmology, Shanghai Astronomical Observatory, Chinese Academy of Sciences, Shanghai 200030 (China); Ellingsen, Simon P.; Titmarsh, Anita [School of Mathematics and Physics, University of Tasmania, Hobart, Tasmania (Australia); He Jinhua, E-mail: chenxi@shao.ac.cn [Key Laboratory for the Structure and Evolution of Celestial Objects, Yunnan Astronomical Observatory/National Astronomical Observatory, Chinese Academy of Sciences, P.O. Box 110, Kunming 650011, Yunnan Province (China)

    2013-06-01T23:59:59.000Z

    We have undertaken a survey of molecular lines in the 3 mm band toward 57 young stellar objects using the Australia Telescope National Facility Mopra 22 m radio telescope. The target sources were young stellar objects with active outflows (extended green objects (EGOs)) newly identified from the GLIMPSE II survey. We observe a high detection rate (50%) of broad line wing emission in the HNC and CS thermal lines, which combined with the high detection rate of class I methanol masers toward these sources (reported in Paper I) further demonstrates that the GLIMPSE II EGOs are associated with outflows. The physical and kinematic characteristics derived from the 3 mm molecular lines for these newly identified EGOs are consistent with these sources being massive young stellar objects with ongoing outflow activity and rapid accretion. These findings support our previous investigations of the mid-infrared properties of these sources and their association with other star formation tracers (e.g., infrared dark clouds, methanol masers and millimeter dust sources) presented in Paper I. The high detection rate (64%) of the hot core tracer CH{sub 3}CN reveals that the majority of these new EGOs have evolved to the hot molecular core stage. Comparison of the observed molecular column densities with predictions from hot core chemistry models reveals that the newly identified EGOs from the GLIMPSE II survey are members of the youngest hot core population, with an evolutionary time scale of the order of 10{sup 3} yr.

  9. SRC-II process

    SciTech Connect (OSTI)

    Schmid, B.K.; Jackson, D.M.

    1980-01-01T23:59:59.000Z

    Extensive laboratory and pilot plant experimental work on the Solvent Refined Coal Process has led to the development of an improved version of the process known as SRC-II. This work has shown considerable promise and plans are being made to demonstrate the SRC-II process using commercial size equipment in a 6000 T/D plant to be located near Morgantown, West Virginia. On the basis of recent economic studies, the products (both liquid and gas) from a future large-scale commercial plant are expected to have an overall selling price of $4.00 to 5.00 per million Btu (first quarter 1980 basis). The major product of the primary process is distillate fuel oil of less than 0.3% sulfur for use largely as a non-polluting fuel for generating electrical power and steam, especially in the east where utilities and industry are presently using petroleum products. For the longer term, the major growth opportunity for SRC-II fuel oil in the generation of electric power will probably be through advanced combustion turbine units with heat recovery boilers (combined cycle units). The light liquid fractions (naphtha and middle distillate) produced by the SRC-II process can be upgraded to a high octane unleaded gasoline to supplement petroleum-derived supplies. Significant quantities of pipeline gas are also produced at a cost which should be competitive with SNG from direct coal gasification. Light hydrocarbons (ethane, propane) from the process may be effectively converted to ethylene in conventional cracking plants to offset ethylene demand from petroleum-derived naphtha and gas oil, both of which could otherwise be used for other refinery products. In addition, certain fraction of the fuel oil might also be used in medium speed diesel engines and automotive gas turbines.

  10. A Testing Strategy for Abstract Classes [Draft] Peter J. Clarke

    E-Print Network [OSTI]

    Power, James

    approach to testing abstract classes is to instantiate a concrete descendant class and test the features on concrete classes in these applications if changes are made to the abstract classes. Testing OO software via one of its concrete descendants and test the derived instance [2]. However, it is not clear

  11. METR 3223: Physical Meteorology II: Cloud Physics, Atmospheric Electricity and Optics

    E-Print Network [OSTI]

    Droegemeier, Kelvin K.

    METR 3223: Physical Meteorology II: Cloud Physics, Atmospheric Electricity and Optics CLASS: Monday of the physical states and processes of clouds and precipitation as well as atmospheric electricity and optics and results Radar observation and estimation Atmospheric electricity: Electrostatics Electromagnetic wave

  12. Magnetic measurements and neutron diffraction study of the layered hybrid compounds Mn(C{sub 8}H{sub 4}O{sub 4})(H{sub 2}O){sub 2} and Mn{sub 2}(OH){sub 2}(C{sub 8}H{sub 4}O{sub 4})

    SciTech Connect (OSTI)

    Sibille, Romain, E-mail: romain.sibille@ijl.nancy-universite.fr [Institut Jean Lamour, UMR 7198-Nancy Universite, BP 70239, 54506 Vandoeuvre-les-Nancy Cedex (France); Mesbah, Adel; Mazet, Thomas; Malaman, Bernard [Institut Jean Lamour, UMR 7198-Nancy Universite, BP 70239, 54506 Vandoeuvre-les-Nancy Cedex (France); Capelli, Silvia [Institut Laue Langevin, 6 rue Jules Horowitz, 38042 Grenoble Cedex 9 (France); Francois, Michel [Institut Jean Lamour, UMR 7198-Nancy Universite, BP 70239, 54506 Vandoeuvre-les-Nancy Cedex (France)

    2012-02-15T23:59:59.000Z

    Mn(C{sub 8}H{sub 4}O{sub 4})(H{sub 2}O){sub 2} and Mn{sub 2}(OH){sub 2}(C{sub 8}H{sub 4}O{sub 4}) layered organic-inorganic compounds based on manganese(II) and terephthalate molecules (C{sub 8}H{sub 4}O{sub 4}{sup 2-}) have been studied by DC and AC magnetic measurements and powder neutron diffraction. The dihydrated compound behaves as a 3D antiferromagnet below 6.5 K. The temperature dependence of its {chi}T product is typical of a 2D Heisenberg system and allows determining the in-plane exchange constant J Almost-Equal-To -7.4 K through the carboxylate bridges. The magnetic structure confirms the in-plane nearest neighbor antiferromagnetic interactions and the 3D ordering. The hydroxide based compound also orders as a 3D antiferromagnet with a higher Neel temperature (38.5 K). Its magnetic structure is described from two antiferromagnetically coupled ferromagnetic sublattices, in relation with the two independent metallic sites. The isothermal magnetization data at 2 K are consistent with the antiferromagnetic ground-state of these compounds. However, in both cases, a slope change points to field-induced modification of the magnetic structure. - Graphical abstract: The macroscopic magnetic properties and magnetic structures of two metal-organic frameworks based on manganese (II) and terephthalate molecules are presented. Highlights: Black-Right-Pointing-Pointer Magnetic study of Mn(C{sub 8}H{sub 4}O{sub 4})(H{sub 2}O){sub 2} and Mn{sub 2}(OH){sub 2}(C{sub 8}H{sub 4}O{sub 4}). Black-Right-Pointing-Pointer Two compounds with common features (interlayer linker/distance, S=5/2 spin). Black-Right-Pointing-Pointer Magnetic measurements quantitatively analyzed to deduce exchange constants. Black-Right-Pointing-Pointer Magnetic structures determined from neutron powder diffraction experiments.

  13. Magnetism of NiMn2O4-Fe3O4 spinel interfaces

    E-Print Network [OSTI]

    Nelson-Cheeseman, B. B.

    2007-01-01T23:59:59.000Z

    Magnetism of NiMn 2 O 4 –Fe 3 O 4 spinel interfaces B. B.2. Element-specific magnetism of Fe 3 O 4 /NMO interface inin these structures, 6 the magnetism near the isostructural

  14. Synthesis and characterization of MnPS{sub 3} for hydrogen sorption

    SciTech Connect (OSTI)

    Ismail, N., E-mail: nahlaismail24@yahoo.co [Physical Chemistry Department, National Research Center, Center of Excellence for Advanced Science, Renewable Energy Group, Cairo (Egypt); Temerk, Y.M. [Assiut University, Faculty of Science, Chemistry Department, Assuit (Egypt); El-Meligi, A.A. [Physical Chemistry Department, National Research Center, Center of Excellence for Advanced Science, Renewable Energy Group, Cairo (Egypt); Badr, M.A. [Mechanical Engineering Department, Cairo (Egypt); Madian, M. [Physical Chemistry Department, National Research Center, Center of Excellence for Advanced Science, Renewable Energy Group, Cairo (Egypt)

    2010-05-15T23:59:59.000Z

    Single phase MnPS{sub 3} powder was prepared by solid state reaction between Mn, S and P carried out at 650 deg. C in evacuated silica tube. The structure, morphology and sorption characteristics of the prepared solid were investigated. The results revealed that the obtained MnPS{sub 3} compound was capable of adsorbing 3.5 wt% hydrogen at -193 deg. C and a pressure of 30 bar. Little amount of hydrogen (0.07 wt%) was adsorbed at room temperature. The hydrogen adsorption/desorption cycles at various temperatures did not result in irreversible chemical structural changes of the MnPS{sub 3} compound, but the microstructure after hydrogen cycling diminished and became finer. - Graphical abstract: Atomic building of MPS{sub 3}

  15. Electrode Characteristics of Individual, MnO2 Coated Carbon Nanotubes

    E-Print Network [OSTI]

    Collins, Philip G

    2011-01-01T23:59:59.000Z

    MnO2 Coated Carbon Nanotubes Brad L. Corso, Israel Perez,single- walled carbon nanotubes. Li ion cyclic voltammetrysingle-walled carbon nanotubes (SWNTs) that are grown in

  16. Characterization of LiNi?.?Mn?.?O? Thin Film Cathode Prepared by Pulsed Laser Deposition

    E-Print Network [OSTI]

    Xia, Hui

    LiNi?.?Mn?.?O? thin films have been grown by pulsed laser deposition (PLD) on stainless steel (SS) substrates. The crystallinity and structure of thin films were investigated by X-ray diffraction (XRD). Microstructure and ...

  17. Frequency Response of Acoustic-Assisted Ni–Mn–Ga Ferromagnetic- Shape-Memory-Alloy Actuator

    E-Print Network [OSTI]

    Techapiesancharoenkij, Ratchatee

    A prototype of Ni–Mn–Ga based ferromagnetic-shape-memory-alloy (FSMA) actuator was designed and built; an acoustic-assist technique was applied to the actuator to enhance its performance. A piezoelectric stack actuator was ...

  18. Combining sedimentological, trace metal (Mn, Mo) and molecular evidence for reconstructing past water-column

    E-Print Network [OSTI]

    Wehrli, Bernhard

    Combining sedimentological, trace metal (Mn, Mo) and molecular evidence for reconstructing past online 22 June 2013 Abstract Here, we present sedimentological, trace metal, and molecular evidence underscores the value of combining sedimentological, geochemical, and microbiological approaches

  19. Formation of nano-crystalline todorokite from biogenic Mn Xiong Han Feng a,1

    E-Print Network [OSTI]

    Sparks, Donald L.

    Formation of nano-crystalline todorokite from biogenic Mn oxides Xiong Han Feng a,1 , Mengqiang Zhu oxides in the environment. Additionally this method may be a viable biosynthesis route for porous, nano

  20. Prospects for high temperature ferromagnetism in (Ga,Mn)As semiconductors

    E-Print Network [OSTI]

    Jungwirth, T.; Wang, KY; Masek, J.; Edmonds, KW; Konig, J.; Sinova, Jairo; Polini, M.; Goncharuk, NA; MacDonald, AH; Sawicki, M.; Rushforth, AW; Campion, RP; Zhao, LX; Foxon, CT; Gallagher, BL.

    2005-01-01T23:59:59.000Z

    -quality metallic samples increases linearly with the number of uncompensated local moments on Mn-Ga acceptors, with no sign of saturation. Room temperature ferromagnetism is expected for a 10% concentration of these local moments. Our magnetotransport...

  1. Irradiated Esophageal Cells are Protected from Radiation-Induced Recombination by MnSOD Gene Therapy

    E-Print Network [OSTI]

    Niu, Yunyun

    Radiation-induced DNA damage is a precursor to mutagenesis and cytotoxicity. During radiotherapy, exposure of healthy tissues can lead to severe side effects. We explored the potential of mitochondrial SOD (MnSOD) gene ...

  2. E-Print Network 3.0 - alloy ni-mn-ga single Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mathematics 35 Lattice dynamics and phonon softening in Ni-Mn-Al Heusler alloys Xavier Moya, Llus Maosa,* and Antoni Planes Summary: as 10% have been re- ported in single...

  3. Effect of MnAs/GaAs(001) film accommodations on the phase-transition temperature

    SciTech Connect (OSTI)

    Iikawa, F.; Brasil, M.J.S.P.; Couto, O.D.D.; Adriano, C.; Giles, C.; Daeweritz, L. [Instituto de Fisica 'Gleb Wataghin', UNICAMP, Campinas-SP, C.P. 6165, 13083-970 (Brazil); Instituto de Fisica 'Gleb Wataghin', UNICAMP, Campinas-SP, C.P. 6165, 13083-970, Brazil and Laboratorio Nacional de Luz Sincrotron, CP-6192, 13084-971 Campinas-SP (Brazil); Paul-Drude-Institut fuer Festkoerperelektronik, Hausvogteiplatz 5-7, 10117 Berlin (Germany)

    2004-09-20T23:59:59.000Z

    The phase-transition temperature of MnAs epitaxial films grown by molecular-beam epitaxy on GaAs(001) with different crystalline accommodations was studied by specular and grazing incidence x-ray diffraction. The transition temperature of MnAs films with tilted hexagonal c-axis orientations with respect to the GaAs substrate is higher than the most investigated nontilted films and reaches a value above room temperature, which is more suitable for device applications.

  4. DC electrodeposition of Mn–Co alloys on stainless steels for SOFC interconnect application

    SciTech Connect (OSTI)

    Wu, Junwei; Jiang, Yinglu; Johnson, Christopher; Liu, Xingbo

    2008-03-01T23:59:59.000Z

    High conductivity coatings that resist oxide scale growth and reduce chromium evaporation are needed to make stainless steel interconnect materials viable for long-term stable operation of solid oxide fuel cells (SOFC). Mn1.5Co1.5O4 spinel is one of the most promising coatings for interconnect application because of its high conductivity, good chromium retention capability, as well as good CTE match to ferritic stainless steels. Mn–Co electrodeposition followed by oxidization is potentially a low cost method for fabrication of (Mn,Co)3O4 spinel coatings. This work looks at the co-deposition of Mn–Co alloys for this application. As a guide to optimize the deposition process, characterizations of the cathodic reactions and reaction potentials are done using polarization curves. It was found that as cobalt concentration was varied that the alloy composition became richer in cobalt, indicating that the deposition is regular co-deposition process. It was also found that at 0.05M Co concentration in excess gluconate the Mn–Co alloys composition could be tuned by varying the current density. Coatings with Mn–Co around 1:1 could be obtained at a current density of 250 mA/cm2. However, the higher potential increased hydrogen production making the films more porous. Oxidation of the alloy coatings showed that much of the porosities could be eliminated during oxidation. It was found in a number of samples that fully dense coatings where obtained. The composition of the oxidized coating was found to become enriched in Mn, possibly due to the Mn fast diffusion from the substrate.

  5. (In,Mn)As quantum dots: Molecular-beam epitaxy and optical properties

    SciTech Connect (OSTI)

    Bouravleuv, A. D., E-mail: bour@mail.ioffe.ru; Nevedomskii, V. N. [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation)] [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation); Ubyivovk, E. V. [St. Petersburg State University (Russian Federation)] [St. Petersburg State University (Russian Federation); Sapega, V. F. [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation)] [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation); Khrebtov, A. I. [St. Petersburg Academic University, Nanotechnology Research and Education Centre (Russian Federation)] [St. Petersburg Academic University, Nanotechnology Research and Education Centre (Russian Federation); Samsonenko, Yu. B.; Cirlin, G. E.; Ustinov, V. M. [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation)] [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation)

    2013-08-15T23:59:59.000Z

    Self-assembled (In,Mn)As quantum dots are synthesized by molecular-beam epitaxy on GaAs (001) substrates. The experimental results obtained by transmission electron microscopy show that doping of the central part of the quantum dots with Mn does not bring about the formation of structural defects. The optical properties of the samples, including those in external magnetic fields, are studied.

  6. Magneto acoustical emission in nanocrystalline Mn–Zn ferrites

    SciTech Connect (OSTI)

    Praveena, K., E-mail: praveenaou@gmail.com [Materials Research Centre, Indian Institute of Science, Bangalore 560012 (India); Department of Physics, Osmania University, Hyderabad 500007 (India); Murthty, S.R. [Department of Physics, Osmania University, Hyderabad 500007 (India)

    2013-11-15T23:59:59.000Z

    Graphical abstract: Mn{sub 0.4}Zn{sub 0.6}Fe{sub 2}O{sub 4} powders were prepared by microwave hydrothermal method. The powders were characterized by X-ray diffraction, transmission electron microscope. The powders were sintered at different temperatures 400, 500, 600, 700, 800 and 900 °C/30 min using microwave sintering method. The grain size was estimated by scanning electron microscope. The room temperature dielectric and magnetic properties were studied in the frequency range (100 kHz–1.8 GHz). The magnetization properties were measured upto 1.5 T. The acoustic emission has been measured along the hysteresis loops from 80 K to Curie temperature. It is found that the magneto-acoustic emission (MAE) activity along hysteresis loop is proportional to the hysteresis losses during the same loop. This law has been verified on series of polycrystalline ferrites and found that the law is valid whatever the composition, the grain size and temperature. It is also found that the domain wall creation/or annihilation processes are the origin of the MAE. - Highlights: • The AE been measured along the hysteresis loops from 80 K to Curie temperature. • The MAE activity along hysteresis loop is proportional to P{sub h} during the same loop. • It is found that the domain wall creation/or annihilation processes are the origin of the MAE. - Abstract: Mn{sub 0.4}Zn{sub 0.6}Fe{sub 2}O{sub 4} powders were prepared by microwave hydrothermal method. The powders were characterized by X-ray diffraction, transmission electron microscope. The powders were sintered at different temperatures 400, 500, 600, 700, 800 and 900 °C/30 min using microwave sintering method. The grain size was estimated by scanning electron microscope. The room temperature dielectric and magnetic properties were studied in the frequency range (100 kHz–1.8 GHz). The magnetization properties were measured upto 1.5 T. The acoustic emission has been measured along the hysteresis loops from 80 K to Curie temperature. It is found that the magneto-acoustic emission (MAE) activity along hysteresis loop is proportional to the hysteresis losses during the same loop. This law has been verified on series of polycrystalline ferrites and found that the law is valid whatever the composition, the grain size and temperature. It is also found that the domain wall creation/or annihilation processes are the origin of the MAE.

  7. THE USE OF MICROSTRUCTURE CONTROL TO TOUGHEN FERRITIC STEELS FOR CRYOGENIC USE. II. Fe-Mn STEELS

    E-Print Network [OSTI]

    Hwang, S.K.

    2010-01-01T23:59:59.000Z

    steels in current use at LNG temperatures and below containtemperature to below LNG temperature. The resulting alloysis suitable for use to below LNG temperature in the grain-

  8. Hydrothermal synthesis of Mn vanadate nanosheets and visible-light photocatalytic performance for the degradation of methyl blue

    SciTech Connect (OSTI)

    Pei, L.Z., E-mail: lzpei@ahut.edu.cn; Xie, Y.K.; Pei, Y.Q.; Jiang, Y.X.; Yu, H.Y.; Cai, Z.Y.

    2013-07-15T23:59:59.000Z

    Graphical abstract: - Highlights: • Mn vanadate nanosheets have been synthesized by simple hydrothermal process. • The formation of Mn vanadate nanosheets can be controlled by growth conditions. • Mn vanadate nanosheets exhibit good photocatalytic activities for methyl blue. - Abstract: Mn vanadate nanosheets have been synthesized via a facile hydrothermal route using ammonium metavanadate and Mn acetate as the raw materials, polyvinyl pyrrolidone (PVP) as the surfactant. X-ray diffraction (XRD) shows that the Mn vanadate nanosheets are composed of monoclinic MnV{sub 2}O{sub 6} phase. Scanning electron microscopy (SEM) observation indicates that the nanosheets have the average thickness of about 50 nm, length of 2–10 ?m and width of 800 nm to 2 ?m. The growth process of the Mn vanadate nanosheets has also been discussed based on the analysis of the roles of the growth conditions on the formation of the Mn vanadate nanosheets. The nanosheets show good photocatalytic activities for the degradation of methylene blue (MB) under visible light irradiation. About 72.96% MB can be degraded after visible light irradiation for 1 h over 10 mg Mn vanadate nanosheets in 10 mL MB solution with the concentration of 10 mg L{sup ?1}.

  9. Magnetic properties and loss separation in iron-silicone-MnZn ferrite soft magnetic composites

    SciTech Connect (OSTI)

    Wu, Shen; Sun, Aizhi; Xu, Wenhuan; Zou, Chao; Yang, Jun; Dong, Juan [School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing (China)

    2013-12-16T23:59:59.000Z

    This paper investigates the magnetic and structural properties of iron-based soft magnetic composites coated with silicone-MnZn ferrite hybrid. The organic silicone resin was added to improve the flexibility of the insulated iron powder and causes better adhesion between particles to increase the mechanical properties. Scanning electron microscopy and distribution maps show that the iron particle surface is covered with a thin layer of silicone-MnZn ferrite. Silicone-MnZn ferrite coated samples have higher permeability when compared with the non-magnetic silicone resin coated compacts. The real part of permeability increases by 34.18% when compared with the silicone resin coated samples at 20 kHz. In this work, a formula for calculating the total loss component by loss separation method is presented and finally the different parts of total losses are calculated. The results show that the eddy current loss coefficient is close to each other for the silicone-MnZn ferrite, silicone resin and MnZn ferrite coated samples (0.0078MnZn ferrite coated sample (k{sub 2} =1.4058) in comparison with other samples.

  10. ARM - RHUBC II Instruments

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc Documentation RUC :ProductsSCM Forcing Data DerivedInstruments Related Links RHUBC-II Home RHUBC

  11. PART II - CONTRACT CLAUSES

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 - September 2006 The 2002OpticsPeriodical: Volume 5, Issue 32012) |GContract115I,I

  12. Evaluation of the computerized procedures Manual II (COPMA II)

    SciTech Connect (OSTI)

    Converse, S.A. [North Carolina State Univ., Raleigh, NC (United States)

    1995-11-01T23:59:59.000Z

    The purpose of this study was to evaluate the effects of a computerized procedure system, the Computerized Procedure Manual II (COPMA-II), on the performance and mental workload of licensed reactor operators. To evaluate COPMA-II, eight teams of two operators were trained to operate a scaled pressurized water reactor facility (SPWRF) with traditional paper procedures and with COPMA-II. Following training, each team operated the SPWRF under normal operating conditions with both paper procedures and COPMA-II. The teams then performed one of two accident scenarios with paper procedures, but performed the remaining accident scenario with COPMA-II. Performance measures and subjective estimates of mental workload were recorded for each performance trial. The most important finding of the study was that the operators committed only half as many errors during the accident scenarios with COPMA-II as they committed with paper procedures. However, time to initiate a procedure was fastest for paper procedures for accident scenario trials. For performance under normal operating conditions, there was no difference in time to initiate or to complete a procedure, or in the number of errors committed with paper procedures and with COPMA-II. There were no consistent differences in the mental workload ratings operators recorded for trials with paper procedures and COPMA-II.

  13. PROGRAMA FISICA II. INTRODUCCI O

    E-Print Network [OSTI]

    Batiste, Oriol

    PROGRAMA F´ISICA II. INTRODUCCI ´O I ELECTRICITAT I.1 Camp electrost`atic I.2 Potencial i energia I.4 `Optica #12;BIBLIOGRAFIA B`asica 1. Tipler, P.A. F´isica. Vol. II, ed. Revert´e, 1992. 2. Purcell Blum, R. F´isica: Electricidad, Mag- netismo y Luz. Vol. II, ed. Revert´e, 1986. Complement`aria 1

  14. Supernovae. Part II: The aftermath

    E-Print Network [OSTI]

    Trimble, V

    1983-01-01T23:59:59.000Z

    R. Viswanathan, 1980, As- Supernovae. Part II ExperimentalSmith, 1982, Astrophys. Supernovae. Chevalier, R. A. , andC. B. , 1974, Ed. , Supernovae and Supernova Rem- nants,

  15. Synthesis of Li{sub (x)}Na{sub (2-x)}Mn{sub 2}S{sub 3} and LiNaMnS{sub 2} through redox-induced ion exchange reactions

    SciTech Connect (OSTI)

    Luthy, Joshua A.; Goodman, Phillip L. [Department of Chemistry and Biochemistry, Texas State University-San Marcos, 601 University Drive, San Marcos, TX 78666 (United States); Martin, Benjamin R. [Department of Chemistry and Biochemistry, Texas State University-San Marcos, 601 University Drive, San Marcos, TX 78666 (United States)], E-mail: bmartin@txstate.edu

    2009-03-15T23:59:59.000Z

    Na{sub 2}Mn{sub 2}S{sub 3} was oxidatively deintercalated using iodine in acetonitrile to yield Na{sub 1.3}Mn{sub 2}S{sub 3}, with lattice constants nearly identical to that of the reactant. Lithium was then reductively intercalated into the oxidized product to yield Li{sub 0.7}Na{sub 1.3}Mn{sub 2}S{sub 3}. When heated, this metastable compound decomposed to form a new crystalline compound, LiNaMnS{sub 2}, along with MnS and residual Na{sub 2}Mn{sub 2}S{sub 3}. Single crystal X-ray diffraction structural analysis of LiNaMnS{sub 2} revealed that this compound crystallizes in P-3m1 with cell parameters a=4.0479(6) A, c=6.7759(14) A, V=96.15(3) A{sup 3} (Z=1, wR2=0.0367) in the NaLiCdS{sub 2} structure-type. - Graphical abstract: Structure of LiNaMnS{sub 2}. Li and Mn are statistically distributed in edge-shared tetrahedral environments linked into infinite planes. Sodium ions occupy interlayer sites.

  16. PVP-Assisted ZrO2 coating on LiMn2O4 spinel cathode nanoparticles prepared by MnO2 nanowire templates

    E-Print Network [OSTI]

    Cho, Jaephil

    solution. Upon annealing at 600 °C in air, an amorphous ZrO2 nanoscale coating layer was obtained [5­10]. Although Li-ion batteries are attractive power-storage devices that have high energy density metal oxide coatings have been reported, studies to improve both the rate capabilities of spinel LiMn2O4

  17. X-ray Emission Spectroscopy to Study Ligand Valence Orbitals in Mn Coordination Complexes

    SciTech Connect (OSTI)

    Smolentsev, Grigory; Soldatov, Alexander V; Messinger, Johannes; Merz, Kathrin; Weyhermuller, Thomas; Bergmann, Uwe; Pushkar, Yulia; Yano, Junko; Yachandra, Vittal K.; Glatzel, Pieter

    2009-03-02T23:59:59.000Z

    We discuss a spectroscopic method to determine the character of chemical bonding and for the identification of metal ligands in coordination and bioinorganic chemistry. It is based on the analysis of satellite lines in X-ray emission spectra that arise from transitions between valence orbitals and the metal ion 1s level (valence-to-core XES). The spectra, in connection with calculations based on density functional theory (DFT), provide information that is complementary to other spectroscopic techniques, in particular X-ray absorption (XANES and EXAFS). The spectral shape is sensitive to protonation of ligands and allows ligands, which differ only slightly in atomic number (e.g., C, N, O...), to be distinguished. A theoretical discussion of the main spectral features is presented in terms of molecular orbitals for a series of Mn model systems: [Mn(H2O)6]2+, [Mn(H2O)5OH]+, [Mn(H2O)5NH2]+, and [Mn(H2O)5NH3]2+. An application of the method, with comparison between theory and experiment, is presented for the solvated Mn2+ ion in water and three Mn coordination complexes, namely [LMn(acac)N3]BPh4, [LMn(B2O3Ph2)(ClO4)], and [LMn(acac)N]BPh4, where L represents 1,4,7-trimethyl-1,4,7-triazacyclononane, acac stands for the 2,4-pentanedionate anion, and B2O3Ph2 represents the 1,3-diphenyl-1,3-dibora-2-oxapropane-1,3-diolato dianion.

  18. Supercapacitor behavior of ?-MnMoO{sub 4} nanorods on different electrolytes

    SciTech Connect (OSTI)

    Purushothaman, K.K., E-mail: purushoth_gri@yahoo.co.in [Department of Physics, TRP Engineering College (SRM Group), Irungalur, Trichy, Tamilnadu (India); Cuba, M. [Department of Physics, Gandhigram Rural Institute – Deemed University, Gandhigram, Tamilnadu (India)] [Department of Physics, Gandhigram Rural Institute – Deemed University, Gandhigram, Tamilnadu (India); Muralidharan, G., E-mail: muralg@rediffmail.com [Department of Physics, Gandhigram Rural Institute – Deemed University, Gandhigram, Tamilnadu (India)

    2012-11-15T23:59:59.000Z

    Graphical abstract: SEM image of ?-MnMoO{sub 4} nanorods on FTO substrate. Highlights: ? Synthesis of ?-MnMoO{sub 4} nanorods by spin coating method. ? First study on the effect of electrolyte on the pseudocapacitance behavior. ? ?-MnMoO{sub 4} nanorods exhibit maximum specific capacitance of 998 F/g. ? At higher scan rates p-TSA electrolyte exhibits superior capacitive behavior. -- Abstract: ?-MnMoO{sub 4} nanorods were prepared on conducting glass substrate via sol–gel spin coating method at the optimum doping level. The effect of electrolyte on the pseudocapacitance behavior of the ?-MnMoO{sub 4} nanorods was studied using para toluene sulfonic acid (p-TSA), sulfuric acid (H{sub 2}SO{sub 4}) and hydrochloric acid (HCl) as electrolytes. X-ray diffraction analysis reveals the formation of ?-MnMoO{sub 4} in monoclinic phase. FTIR spectra contain vibrational bands associated with Mo=O, M–O and Mo–O–Mo bonds. SEM image reveals the formation of nanorods. Supercapacitor behavior has been studied using cyclic voltammetry (CV) analysis. ?-MnMoO{sub 4} nanorods exhibit maximum specific capacitance of 998 F/g at a scan rate of 5 mV/s in H{sub 2}SO{sub 4} electrolyte while a specific capacitance of 784 F/g and 530 F/g have been obtained using p-TSA and HCl electrolytes, respectively. At higher scan rates p-TSA electrolyte exhibits superior capacitive behavior than H{sub 2}SO{sub 4}.

  19. Class Host: Johnson County Sheriff's Office Criminalistics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series to User Group and Userof aChristina MartosLibrary ServicesClass Host:

  20. The geochemical evolution of the Sonju Lake intrusion: assimilation and fractional crystallization in a layered mafic intrusion near Finland, Mn.

    E-Print Network [OSTI]

    Dayton, Ryan N.

    2011-01-01T23:59:59.000Z

    ??The Sonju Lake Intrusion, located within the Beaver Bay Complex near Finland, MN, is the most completely differentiated intrusion related to the Midcontinent Rift System… (more)

  1. Phase II Final Report

    SciTech Connect (OSTI)

    Schuknecht, Nate [Project Manager; White, David [Principle Investigator; Hoste, Graeme [Research Engineer

    2014-09-11T23:59:59.000Z

    The SkyTrough DSP will advance the state-of-the-art in parabolic troughs for utility applications, with a larger aperture, higher operating temperature, and lower cost. The goal of this project was to develop a parabolic trough collector that enables solar electricity generation in the 2020 marketplace for a 216MWe nameplate baseload power plant. This plant requires an LCOE of 9¢/kWhe, given a capacity factor of 75%, a fossil fuel limit of 15%, a fossil fuel cost of $6.75/MMBtu, $25.00/kWht thermal storage cost, and a domestic installation corresponding to Daggett, CA. The result of our optimization was a trough design of larger aperture and operating temperature than has been fielded in large, utility scale parabolic trough applications: 7.6m width x 150m SCA length (1,118m2 aperture), with four 90mm diameter × 4.7m receivers per mirror module and an operating temperature of 500°C. The results from physical modeling in the System Advisory Model indicate that, for a capacity factor of 75%: The LCOE will be 8.87¢/kWhe. SkyFuel examined the design of almost every parabolic trough component from a perspective of load and performance at aperture areas from 500 to 2,900m2. Aperture-dependent design was combined with fixed quotations for similar parts from the commercialized SkyTrough product, and established an installed cost of $130/m2 in 2020. This project was conducted in two phases. Phase I was a preliminary design, culminating in an optimum trough size and further improvement of an advanced polymeric reflective material. This phase was completed in October of 2011. Phase II has been the detailed engineering design and component testing, which culminated in the fabrication and testing of a single mirror module. Phase II is complete, and this document presents a summary of the comprehensive work.

  2. CSC6870 Computer Graphics II Bezier Curves

    E-Print Network [OSTI]

    Hua, Jing

    CSC6870 Computer Graphics II Bezier Curves CSC6870 Computer Graphics II Bezier Curve CSC6870 Computer Graphics II Cubic Bezier Curves · Curve: · Control points · Basis functions: = = 3 0 3 )()( i ii uBpuc ip CSC6870 Computer Graphics II Bezier Curves (degree n) · Curve: · Control points · Basis functions

  3. CSC6870 Computer Graphics II Geometric Modeling

    E-Print Network [OSTI]

    Hua, Jing

    CSC6870 Computer Graphics II Geometric Modeling CSC6870 Computer Graphics II Overview 3D Shape, subdivision surfaces, implicit surfaces, particles. · Solids CSC6870 Computer Graphics II Basic Shapes CSC6870 Computer Graphics II Fundamental Shapes CSC6870 Computer Graphics II Fundamental Shapes CSC6870 Computer

  4. A Type II Radio Burst without a Coronal Mass Ejection

    E-Print Network [OSTI]

    Su, W; Ding, M D; Chen, P F; Sun, J Q

    2015-01-01T23:59:59.000Z

    Type II radio bursts are thought to be a signature of coronal shocks. In this paper, we analyze a short-lived type II burst that started at 07:40 UT on 2011 February 28. By carefully checking white-light images, we find that the type II radio burst is not accompanied by a coronal mass ejection, only with a C2.4 class flare and narrow jet. However, in the extreme-ultraviolet (EUV) images provided by the Atmospheric Imaging Assembly (AIA) on board the Solar Dynamics Observatory (SDO), we find a wave-like structure that propagated at a speed of $\\sim$ 600 km s$^{-1}$ during the burst. The relationship between the type II radio burst and the wave-like structure is in particular explored. For this purpose, we first derive the density distribution under the wave by the differential emission measure (DEM) method, which is used to restrict the empirical density model. We then use the restricted density model to invert the speed of the shock that produces the observed frequency drift rate in the dynamic spectrum. The ...

  5. National Synchrotron Light Source II

    ScienceCinema (OSTI)

    Steve Dierker

    2010-01-08T23:59:59.000Z

    The National Synchrotron Light Source II (NSLS-II) at the U.S. Department of Energy's Brookhaven National Laboratory is a proposed new state-of-the-art medium energy storage ring designed to deliver world-leading brightness and flux with top-off operation

  6. Enhanced ferromagnetic order in Sr{sub 4}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} featuring canted [MnO{sub 4}]{sub ?} spin chains of mixed-valent Mn(III)/Mn(IV). Aliovalent substitution of the Sr{sub 4?x}Ln{sub x}Mn{sup III}{sub 2+x}Mn{sup IV}{sub 1?x}O{sub 3}(GeO{sub 4}){sub 3} solid-solution

    SciTech Connect (OSTI)

    West, J. Palmer; Sulejmanovic, Dino [Department of Chemistry, Clemson University, Clemson, SC 29634 (United States); Becht, Gregory [E. I. du Pont, Wilmington, DE 19880-0500 (United States); He, Jian; Hitchcock, Dale [Department of Physics and Astronomy, Clemson University, Clemson, SC 29634 (United States); Yan, Yonggao [Wuhan University of Technology, Wuhan 430070 (China); Hwu, Shiou-Jyh, E-mail: shwu@clemson.edu [Department of Chemistry, Clemson University, Clemson, SC 29634 (United States)

    2013-10-15T23:59:59.000Z

    Crystals of Sr{sub 4?x}Ln{sub x}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} (x=0; x?0.15 for Ln=La, Pr, Nd, Sm. Eu, Gd, Dy; x?0.3 for Ln=Gd) were isolated upon using high-temperature, solid-state methods in molten-salt media. These compounds are isostructural with the previously reported Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3} (Ln=La, Sm, Gd) series that contains the same [MnO{sub 4}]{sub ?} spin chains. The synthesis of the Sr{sub 4}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} (x=0) phase was carried out by a double aliovalent substitution with respect to the Sr{sup 2+} and Ge{sup 4+} ions that replace Na{sup +}/Ln{sup 3+} and As{sup 5+} in Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3}, respectively. The title series contains mixed-valent Mn(III)/Mn(IV) and shows a limited range of solid solution, both of which were not observed in the previously reported Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3} series. To form the Sr{sub 4?x}Ln{sub x}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} solid solution, one of the Sr{sup 2+} sites, i.e., the original Ln-site in Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3}, is partially substituted by Ln{sup 3+} in a statistical disorder of Sr{sub 1?x}/Ln{sub x}. Initial magnetic investigations of selected derivatives reveal higher ferromagnetic ordering temperatures than those reported for the Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3} series, presumably attributed to a lesser degree of canting as a result of introducing non-Jahn–Teller Mn{sup 4+} ions. Also intriguing is the observation of multiple anomalies at low temperatures which appear to be of electronic origins. - Graphical abstract: Sr{sub 4?x}Ln{sub x}Mn(III){sub 2+x}Mn(IV){sub 1?x}O{sub 3}(GeO{sub 4}){sub 3}. Display Omitted - Highlights: • Double aliovalent substitution: Sr{sub 4}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} with respect to Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3}. • Solid solution with respect to statistical disorder of Sr{sub 1?x}Ln{sub x} in one of the two Sr sites. • Mn{sup 3+}/Mn{sup 4+} magnetic ions are spatially arranged in a triangular kagomé fashion. • Enhanced ferromagnetic ordering attributed to doping non-Jahn–Teller Mn{sup 4+}.

  7. EIS-0259: Disposal of Decommissioned, Defueled Cruiser, Ohio Class and Los Angeles Class Naval Reactor Plants, Hanford Site, Richland (adopted from Navy)

    Broader source: Energy.gov [DOE]

    This EIS analyzes the alternate ways for disposing of decommissioned, defieled reactor compliments from U.S. Navy nuclear-powered cruisers, (Bainbridge, Truxtun, Long Beach, California Class and Virginia Class) and Los Angeles Class, and Ohio Class submarines.

  8. Analytic Functions in Smirnov Classes Ep Real Boundary Values

    E-Print Network [OSTI]

    Khavinson, Dmitry

    Analytic Functions in Smirnov Classes Ep with Real Boundary Values L. De Castro and D. Khavinson. [1] Ch. 10.) Definition 1. An analytic function f(z) in G is said to belong to the class Ep (G) for p known that for p 1 functions in Ep -classes can be represented as Cauchy integrals of their boundary

  9. for classes Go to http://www.usf.edu

    E-Print Network [OSTI]

    Meyers, Steven D.

    taken care of your holds, you can begin your class schedule search. #12;Select appropriate term Use this if searching for an online class Choose your campus Start by selecting the appropriate term and campus from when searching for a class. Choose a subject (Ex: ENC) Enter a course # (Ex: 1102) #12;The "Status

  10. Class 18: Wed. Apr. 3: Toxic Substances Control Act and Cost/Benefit Analysis Class Project on TSCA

    E-Print Network [OSTI]

    Iglesia, Enrique

    1 Class 18: Wed. Apr. 3: Toxic Substances Control Act and Cost/Benefit Analysis Class Project on TSCA This project element will examine how technologies you are studying. Each project team will focus on the microorganisms

  11. Magnetoresistance in Mn ion-implanted GaAs:Zn nanowires

    SciTech Connect (OSTI)

    Paschoal, W.; Kumar, Sandeep; Jain, V.; Pettersson, H., E-mail: hakan.pettersson@hh.se [Solid State Physics/The Nanometer Structure Consortium, Lund University, Box 118, SE-221 00 Lund (Sweden); Department of Mathematics, Physics and Electrical Engineering, Halmstad University, Box 823, SE-301 18, Halmstad (Sweden); Jacobsson, D.; Samuelson, L. [Solid State Physics/The Nanometer Structure Consortium, Lund University, Box 118, SE-221 00 Lund (Sweden); Johannes, A.; Ronning, C. [Institute for Solid State Physics, Friedrich-Schiller-University Jena, Max-Wien-Platz 1, D-07743 Jena (Germany); Canali, C. M.; Pertsova, A. [Department of Physics and Electrical Engineering, Linneaus University, SE-39233 Kalmar (Sweden); Dick, K. A. [Solid State Physics/The Nanometer Structure Consortium, Lund University, Box 118, SE-221 00 Lund (Sweden); Center for Analysis and Synthesis, Lund University, Box 124, S-221 00 Lund (Sweden)

    2014-04-14T23:59:59.000Z

    We have investigated the magnetoresistance (MR) in a series of Zn doped (p-type) GaAs nanowires implanted with different Mn concentrations. The nanowires with the lowest Mn concentration (?0.0001%) exhibit a low resistance of a few k? at 300?K and a 4% positive MR at 1.6?K, which can be well described by invoking a spin-split subband model. In contrast, nanowires with the highest Mn concentration (4%) display a large resistance of several M? at 300?K and a large negative MR of 85% at 1.6?K. The large negative MR is interpreted in terms of spin-dependent hopping in a complex magnetic nanowire landscape of magnetic polarons, separated by intermediate regions of Mn impurity spins. Sweeping the magnetic field back and forth for the 4% sample reveals a hysteresis that indicates the presence of a weak ferromagnetic phase. We propose co-doping with Zn to be a promising way to reach the goal of realizing ferromagnetic Ga{sub 1?x}Mn{sub x}As nanowires for future nanospintronics.

  12. Carbon/lambda-MnO{sub 2} composites for supercapacitor electrodes

    SciTech Connect (OSTI)

    Malak-Polaczyk, A., E-mail: agnieszka-malak@wp.p [Institute of Chemistry and Technical Electrochemistry, Poznan University of Technology, Piotrowo 3, 60-695 Poznan (Poland); Institut de Sciences des Materiaux de Mulhouse, CNRS LRC 7228, 15 Rue Starcky, 68057 Mulhouse (France); Matei-Ghimbeu, C.; Vix-Guterl, C. [Institut de Sciences des Materiaux de Mulhouse, CNRS LRC 7228, 15 Rue Starcky, 68057 Mulhouse (France); Frackowiak, E. [Institute of Chemistry and Technical Electrochemistry, Poznan University of Technology, Piotrowo 3, 60-695 Poznan (Poland)

    2010-04-15T23:59:59.000Z

    In the present work a composite of carbon with lambda-MnO{sub 2} have been synthesized by a simple two-step route. In the first step, to obtain LiMn{sub 2}O{sub 4}/carbon material, mesoporous activated carbon was impregnated with the solution of precursor metal salts and heated subsequently. As-prepared materials were acid treated which resulted in the formation of lambda-MnO{sub 2}/carbon. Physical properties, structure and specific surface area of electrode materials were studied by TEM, X-ray diffraction and nitrogen sorption measurements. Voltammetry cycling, galvanostatic charge/discharge and impedance spectroscopy measurements performed in two- and three-electrode cells have been applied in order to measure electrochemical parameters. TEM images confirmed well dispersed lambda-MnO{sub 2} particles on the surface of carbon material. The carbon in the composite plays an important role as the surface area enhancing component and a support of pseudocapacitive material. Furthermore, the through-connected porosity serves as a continuous pathway for electrolyte transport. A synergetic effect of the porous carbon framework and of the redox properties of the lambda-MnO{sub 2} is at the origin of improvement of specific capacitance values which has been observed for composites after delithiation. - Comparison of capacitance characteristics for initial carbon and synthesised composites for CB in 1 mol L{sup -1} Na{sub 2}SO{sub 4} solution.

  13. PARS II KNOWN ISSUES AND SUGGESTED WORKAROUNDS

    Energy Savers [EERE]

    screen, the following workaround is suggested: Close all browser windows (PARS II and web applications). Reopen a browser and proceed with the PARS II log-in. PARS II does...

  14. Unique light-induced degradation in yellow-emitting K{sub 2}SiF{sub 6}:Mn{sup 2+} phosphor

    SciTech Connect (OSTI)

    Oyama, Takuya; Adachi, Sadao, E-mail: adachi@el.gunma-u.ac.jp [Division of Electronics and Informatics, Faculty of Science and Technology, Gunma University, Kiryu-shi, Gunma 376-8515 (Japan)

    2014-10-07T23:59:59.000Z

    Photo-induced luminescence intensity degradation in yellow-emitting K{sub 2}SiF{sub 6}:Mn{sup 2+} phosphor is studied using x-ray diffraction measurement, photoluminescence (PL) analysis, PL excitation (PLE) spectroscopy, PL decay analysis, and electron spin resonance (ESR) measurement. The yellow-emitting K{sub 2}SiF{sub 6}:Mn{sup 2+} phosphor exhibits remarkable degradation in the PL intensity under Xe lamp exposure. Coherent laser irradiation also induces degradation and its degree is in the order of He–Cd (??=?325?nm)?>?Ar{sup +} (488?nm)?>?He–Ne laser (632.8?nm). The degradation mechanism is proposed to be due to change in the valence state of manganese ions from Mn{sup 2+} to Mn{sup 3+} by the photooxidation (Mn{sup 2+} ? Mn{sup 3+}) or disproportionation reaction (2Mn{sup 2+} ? Mn{sup +} + Mn{sup 3+}). The ESR measurement confirms the decreased Mn{sup 2+} spin density in the sample exposed with Xe lamp. The PLE spectrum suggests that the excitation of Mn{sup 3+} ions occurs through energy transfer upon absorption of exciting radiation by the Mn{sup 2+} ions. Thermal annealing of the degraded samples at ?200?°C causes a blueshift in the PL emission band with an appearance of the Mn{sup 4+}-related sharp red emission lines.

  15. Upconversion luminescence of Eu3+ and Mn2+ in ZnS:Mn2+, Eu3+ codoped

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism inS-4500II Field Emission SEM with EDAX (For3Webinar

  16. Anomalously large spin susceptibility enhancement in n-doped CdMnTe quantum wells

    SciTech Connect (OSTI)

    Ben Cheikh, Z. [Laboratoire Charles Coulomb, UMR 5221, Département Semi-conducteurs, Matériaux et Capteurs, Université Montpellier 2, France and Laboratoire de Physique des Matériaux: Structures et Propriétés, Faculté (Tunisia); Cronenberger, S.; Vladimirova, M.; Scalbert, D. [Laboratoire Charles Coulomb, UMR 5221, Departement Semi-conducteurs, Materiaux et Capteurs, Universite Montpellier 2 (France); Boujdaria, K. [Laboratoire de Physique des Matériaux: Structures et Propriétés, Faculté des Sciences de Bizerte, Université de Carthage, 7021 Zarzouna (Tunisia); Baboux, F.; Perez, F. [Institut des NanoSciences de Paris, CNRS/Université Paris 6, 4 place Jussieu, F-75005 Paris (France); Wojtowicz, T.; Karczewski, G. [Institute of Physics, Polish Academy of Sciences, 02-668 Warsaw (Poland)

    2013-12-04T23:59:59.000Z

    We report on time-resolved Kerr rotation (TRKR) experiments done on n-doped CdMnTe quantum wells (QWs), in the regime where strong coupling between the electron and the Mn spin-flip excitations shows up. It has been proposed previously to deduce the 2D electron gas spin susceptibility from the coupling energy between these spin excitations. Here we measure the coupling energy on a high mobility sample down to very low excitation density, and compare the results with spin-flip Raman scattering (SFRS) on the same sample. The electron spin polarizations measured by TRKR and SFRS are found in relatively good agreement. However the spin susceptibility measured by TRKR exceeds systematically the values predicted by many-body theory. This could be an indication that the two-oscillator model used to describe mixed electron-Mn spin excitations needs to be improved.

  17. In-situ spectro-microscopy on organic films: Mn-Phthalocyanine on Ag(100)

    SciTech Connect (OSTI)

    Al-Mahboob A.; Vescovo, E.; Sadowski, J.T.

    2013-08-18T23:59:59.000Z

    Metal phthalocyanines are attracting significant attention, owing to their potential for applications in chemical sensors, solar cells and organic magnets. As the electronic properties of molecular films are determined by their crystallinity and molecular packing, the optimization of film quality is important for improving the performance of organic devices. Here, we present the results of in situ low-energy electron microscopy / photoemission electron microscopy (LEEM/PEEM) studies of incorporation-limited growth [1] of manganese-phthalocyanine (MnPc) on Ag(100) surfaces. MnPc thin films were grown on both, bulk Ag(100) surface and thin Ag(100)/Fe(100) films, where substrate spin-polarized electronic states can be modified through tuning the thickness of the Ag film [2]. We also discuss the electronic structure and magnetic ordering in MnPc thin films, investigated by angle- and spin-resolved photoemission spectroscopy.

  18. The resistance to cavitation erosion of CrMnN stainless steels

    SciTech Connect (OSTI)

    Fu, W.T. [Yanshan Univ., Qinhuangdao (China). Dept. of Materials Engineering] [Yanshan Univ., Qinhuangdao (China). Dept. of Materials Engineering; [Harbin Inst. of Tech. (China); Jing, T.F.; Zheng, Y.Z. [Yanshan Univ., Qinhuangdao (China). Dept. of Materials Engineering] [Yanshan Univ., Qinhuangdao (China). Dept. of Materials Engineering; Yang, Y.B. [Yanshan Univ., Qinhuangdao (China). Dept. of Materials Engineering] [Yanshan Univ., Qinhuangdao (China). Dept. of Materials Engineering; [Bohai Aluminum Industries Co., Ltd., Qinhuangdao (China); Yao, M. [Harbin Inst. of Tech. (China)] [Harbin Inst. of Tech. (China)

    1998-12-01T23:59:59.000Z

    The resistance to cavitation erosion (CE) was measured using a magnetostrictive device and a rotating disk device for some CrMnN stainless steels (Chinese patent ZL 90 1 02197.0). The microstructural changes in the surface layer before and after CE were analyzed by use of Mossbauer spectra. Results show that the resistance to CE of duplex austenitic-martensitic CrMnN stainless steels is much better than that of ZG0Cr13Ni4-6Mo and ZG0Cr16Ni5Mo steel, which are in common use for hydraulic turbine runners. The metastable austenite and its changes in the process of CE are the key factors why the CrMnN stainless steels have excellent resistance to cavitation erosion.

  19. Ferromagnetism and the electronic band structure in (Ga,Mn)(Bi,As) epitaxial layers

    SciTech Connect (OSTI)

    Yastrubchak, O., E-mail: yastrub@hektor.umcs.lublin.pl [Institute of Physics, Maria Curie-Sklodowska University in Lublin, Pl. M. Curie-Sk?odowskiej 1, 20-031 Lublin (Poland); Institute of Semiconductor Physics, National Academy of Sciences, 41 pr. Nauki, 03028 Kyiv (Ukraine); Sadowski, J. [MAX-IV Laboratory, Lund University, P.O. Box 118, SE-221 00 Lund (Sweden); Institute of Physics, Polish Academy of Sciences, Al. Lotnikow 32/46, 02-668 Warsaw (Poland); Gluba, L.; ?uk, J.; Kulik, M. [Institute of Physics, Maria Curie-Sklodowska University in Lublin, Pl. M. Curie-Sk?odowskiej 1, 20-031 Lublin (Poland); Domagala, J. Z.; Andrearczyk, T.; Wosinski, T. [Institute of Physics, Polish Academy of Sciences, Al. Lotnikow 32/46, 02-668 Warsaw (Poland); Rawski, M. [Analytical Laboratory, Maria Curie-Sklodowska University in Lublin, Pl. M. Curie-Sk?odowskiej 3, 20-031 Lublin (Poland)

    2014-08-18T23:59:59.000Z

    Impact of Bi incorporation into (Ga,Mn)As layers on their electronic- and band-structures as well as their magnetic and structural properties has been studied. Homogenous (Ga,Mn)(Bi,As) layers of high structural perfection have been grown by the low-temperature molecular-beam epitaxy technique. Post-growth annealing treatment of the layers results in an improvement of their structural and magnetic properties and an increase in the hole concentration in the layers. The modulation photoreflectance spectroscopy results are consistent with the valence-band model of hole-mediated ferromagnetism in the layers. This material combines the properties of (Ga,Mn)As and Ga(Bi,As) ternary compounds and offers the possibility of tuning its electrical and magnetic properties by controlling the alloy composition.

  20. Webinar: Systems Performance Advancement II Funding Opportunity...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Webinar: Systems Performance Advancement II Funding Opportunity Announcement Webinar: Systems Performance Advancement II Funding Opportunity Announcement January 22, 2015 2:00PM to...

  1. Shell Model for Atomistic Simulation of Lithium Diffusion in Mixed Mn/Ti Oxides

    SciTech Connect (OSTI)

    Kerisit, Sebastien N.; Chaka, Anne M.; Droubay, Timothy C.; Ilton, Eugene S.

    2014-10-23T23:59:59.000Z

    Mixed Mn/Ti oxides present attractive physicochemical properties such as their ability to accommodate Li for application in Li-ion batteries. In this work, atomic parameters for Mn were developed to extend an existing shell model of the Li-Ti-O system and allow simulations of pure and lithiated Mn and mixed Mn/Ti oxide polymorphs. The shell model yielded good agreement with experimentally-derived structures (i.e. lattice parameters and inter-atomic distances) and represented an improvement over existing potential models. The shell model was employed in molecular dynamics (MD) simulations of Li diffusion in the 1×1 c direction channels of LixMn1 yTiyO2 with the rutile structure, where 0 ? x ? 0.25 and 0 ? y ? 1. In the infinite dilution limit, the arrangement of Mn and Ti ions in the lattice was found to have a significant effect on the activation energy for Li diffusion in the c channels due to the destabilization of half of the interstitial octahedral sites. Anomalous diffusion was demonstrated for Li concentrations as low as x = 0.125, with a single Li ion positioned in every other c channel. Further increase in Li concentration showed not only the substantial effect of Li-Li repulsive interactions on Li mobility but also their influence on the time dependence of Li diffusion. The results of the MD simulations can inform intrinsic structure-property relationships for the rational design of improved electrode materials for Li-ion batteries.

  2. First-principles study of magnetism in spinel MnO2 Dane Morgan and Billie Wang

    E-Print Network [OSTI]

    Ceder, Gerbrand

    First-principles study of magnetism in spinel MnO2 Dane Morgan and Billie Wang Department to calculate the ground state, transition tem- perature, and thermodynamic properties of magnetic excitations in spinel MnO2 . The magnetic interactions are mapped onto a Heisenberg model whose exchange interactions

  3. Determination of Mn valence states in mixed-valent manganates by XANES spectroscopy AlAin MAnceAu,1,

    E-Print Network [OSTI]

    Cedex 9, France 2 Advanced Light Source, Lawrence Berkeley National Laboratory, One Cyclotron Road and phyllomanganates with no or little Mn3+ in the MnO2 layer exhibit intensi- ties, shapes, and relative energy catalysis, hazardous waste remediation, and rechargeable battery technology (Thackeray 1997; Toupin et al

  4. MnO spin-wave dispersion curves from neutron powder diffraction

    SciTech Connect (OSTI)

    Goodwin, Andrew L.; Dove, Martin T. [Department of Earth Sciences, Cambridge University, Downing Street, Cambridge CB2 3EQ (United Kingdom); Tucker, Matthew G. [ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, Oxfordshire OX11 0QX (United Kingdom); Keen, David A. [ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, Oxfordshire OX11 0QX (United Kingdom); Department of Physics, Oxford University, Clarendon Laboratory, Parks Road, Oxford OX1 3PU (United Kingdom)

    2007-02-15T23:59:59.000Z

    We describe a model-independent approach for the extraction of spin-wave dispersion curves from powder neutron total scattering data. Our approach is based on a statistical analysis of real-space spin configurations to calculate spin-dynamical quantities. The RMCPROFILE implementation of the reverse Monte Carlo refinement process is used to generate a large ensemble of supercell spin configurations from MnO powder diffraction data collected at 100 K. Our analysis of these configurations gives spin-wave dispersion curves for MnO that agree well with those determined independently using neutron triple-axis spectroscopic techniques.

  5. A study of magnetic anisotropy energy in CuMn spin glass

    E-Print Network [OSTI]

    Allen, Christine Adele

    1986-01-01T23:59:59.000Z

    A STUDY OF MAGNETIC ANISOTROPY ENERGY IN CuMn SPIN GLASS A Thesis by CHRISTINE ADELE ALLEN Submitted to the Graduate College of Texas ARM University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE August 1986... Major Subject: Physics A STUDY OF MAGNETIC ANISOTROPY ENERGY IN CuMn SPIN GLASS A Thesis by CHRISTINE ADELE ALLEN Approved as to style and content by: Thomas W. Adair, III (Chai man of Committee) Robert A. enefick (Member) Donald L. Parker...

  6. Thickness dependent exchange bias in martensitic epitaxial Ni-Mn-Sn thin films

    SciTech Connect (OSTI)

    Behler, Anna [IFW Dresden, Institute for Complex Materials, P.O. Box 27 01 16, 01171 Dresden (Germany) [IFW Dresden, Institute for Complex Materials, P.O. Box 27 01 16, 01171 Dresden (Germany); Department of Physics, Institute for Solid State Physics, Dresden University of Technology, 01062 Dresden (Germany); Teichert, Niclas; Auge, Alexander; Hütten, Andreas [Department of Physics, Thin Films and Physics of Nanostructures, Bielefeld University, 33501 Bielefeld (Germany)] [Department of Physics, Thin Films and Physics of Nanostructures, Bielefeld University, 33501 Bielefeld (Germany); Dutta, Biswanath; Hickel, Tilmann [Max-Planck Institut für Eisenforschung, 40237 Düsseldorf (Germany)] [Max-Planck Institut für Eisenforschung, 40237 Düsseldorf (Germany); Waske, Anja [IFW Dresden, Institute for Complex Materials, P.O. Box 27 01 16, 01171 Dresden (Germany)] [IFW Dresden, Institute for Complex Materials, P.O. Box 27 01 16, 01171 Dresden (Germany); Eckert, Jürgen [IFW Dresden, Institute for Complex Materials, P.O. Box 27 01 16, 01171 Dresden (Germany) [IFW Dresden, Institute for Complex Materials, P.O. Box 27 01 16, 01171 Dresden (Germany); Institute of Materials Science, Dresden University of Technology, 01062 Dresden (Germany)

    2013-12-15T23:59:59.000Z

    A thickness dependent exchange bias in the low temperature martensitic state of epitaxial Ni-Mn-Sn thin films is found. The effect can be retained down to very small thicknesses. For a Ni{sub 50}Mn{sub 32}Sn{sub 18} thin film, which does not undergo a martensitic transformation, no exchange bias is observed. Our results suggest that a significant interplay between ferromagnetic and antiferromagnetic regions, which is the origin for exchange bias, is only present in the martensite. The finding is supported by ab initio calculations showing that the antiferromagnetic order is stabilized in the phase.

  7. Quantum Critical Transition Amplifies Magnetoelastic Coupling in Mn[N(CN)2]2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Brinzari, T. V.; Chen, P.; Sun, Q.-C.; Liu, J.; Tung, L.-C.; Wang, Y.; Schlueter, J. A.; Singleton, J.; Manson, J. L.; Whangbo, M.-H.; Litvinchuk, A. P.; Musfeldt, J. L.

    2013-06-01T23:59:59.000Z

    We report the discovery of a magnetic quantum critical transition in Mn[N(CN)2]2 that drives the system from a canted antiferromagnetic state to the fully polarized state with amplified magnetoelastic coupling as an intrinsic part of the process. The local lattice distortions, revealed through systematic phonon frequency shifts, suggest a combined MnN6 octahedra distortion+counterrotation mechanism that reduces antiferromagnetic interactions and acts to accommodate the field-induced state. These findings deepen our understanding of magnetoelastic coupling near a magnetic quantum critical point and away from the static limit.

  8. North Wind 4-kW wind-system development. Phase II. Fabrication and test

    SciTech Connect (OSTI)

    Lynch, J.; Coleman, C.; Mayer, D.J.

    1983-01-01T23:59:59.000Z

    This report presents the results of Phase II (testing and fabrication) of a program funded by the US Department of Energy to design, fabricate, and test a cost-effective wind system in the 3 to 6 kW class. During Phase II, using the design developed during Phase I, a prototype 4 kW machine was fabricated and tested in Waitsfield, Vermont. Several problems were encountered and subsequently analyzed. Design modifications, including the use of a larger alternator, are described. Test performed by North Wind and by Rockwell International (which monitored the program) demonstrated the predicted performance characteristics and the validity of the North Wind design.

  9. Options Study - Phase II

    SciTech Connect (OSTI)

    R. Wigeland; T. Taiwo; M. Todosow; W. Halsey; J. Gehin

    2010-09-01T23:59:59.000Z

    The Options Study has been conducted for the purpose of evaluating the potential of alternative integrated nuclear fuel cycle options to favorably address the issues associated with a continuing or expanding use of nuclear power in the United States. The study produced information that can be used to inform decisions identifying potential directions for research and development on such fuel cycle options. An integrated nuclear fuel cycle option is defined in this study as including all aspects of the entire nuclear fuel cycle, from obtaining natural resources for fuel to the ultimate disposal of used nuclear fuel (UNF) or radioactive wastes. Issues such as nuclear waste management, especially the increasing inventory of used nuclear fuel, the current uncertainty about used fuel disposal, and the risk of nuclear weapons proliferation have contributed to the reluctance to expand the use of nuclear power, even though it is recognized that nuclear power is a safe and reliable method of producing electricity. In this Options Study, current, evolutionary, and revolutionary nuclear energy options were all considered, including the use of uranium and thorium, and both once-through and recycle approaches. Available information has been collected and reviewed in order to evaluate the ability of an option to clearly address the challenges associated with the current implementation and potential expansion of commercial nuclear power in the United States. This Options Study is a comprehensive consideration and review of fuel cycle and technology options, including those for disposal, and is not constrained by any limitations that may be imposed by economics, technical maturity, past policy, or speculated future conditions. This Phase II report is intended to be used in conjunction with the Phase I report, and much information in that report is not repeated here, although some information has been updated to reflect recent developments. The focus in this Options Study was to identify any nuclear fuel cycle technology or option that may result in a significant beneficial impact to the issues as compared to the current U.S. approach of once-through use of nuclear fuel in LWRs or similar reactors followed by direct disposal of UNF. This approach was taken because incremental differences may be difficult to clearly identify and justify due to the large uncertainties that can be associated with the specific causes of the issues. Phase II of this Options Study continued the review of nuclear fuel cycle options that was initiated and documented during Phase I, concentrating on reviewing and summarizing the potential of integrated nuclear fuel cycles. However, based on the reviews of previous studies and available data, it was not always possible to clearly determine sufficiently large differences between the various fuel cycle and technology options for some of the issues or evaluation measures, for example, in cases where only incremental differences with respect to the issues might be achieved regardless of the fuel cycle option or technologies being considered, or where differences were insufficient to clearly rise above the uncertainties.

  10. Growth of single-crystal {alpha}-MnO{sub 2} nanorods on multi-walled carbon nanotubes

    SciTech Connect (OSTI)

    Chen Yong [Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016 (China); Key Laboratory of Tropic Biological Resources, MOE, Hainan University, 58 Renmin Road, Haikou 570228 (China); Liu Chenguang; Liu Chang [Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016 (China); Lu Gaoqing [ARC Centre for Functional Nanomaterials, Australian Institute of Bioengineering and Nanotechnology, University of Queensland, QLD 4072 (Australia); Cheng Huiming [Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016 (China)], E-mail: cheng@imr.ac.cn

    2007-11-06T23:59:59.000Z

    Single-crystal {alpha}-MnO{sub 2} nanorods were grown on multi-walled carbon nanotubes (MWNTs) in H{sub 2}SO{sub 4} aqueous solution. The morphology and microstructure of the composites were examined by transmission electron microscopy, high-resolution transmission electron microscopy (HRTEM), X-ray diffractometry and energy dispersive spectroscopy (EDS). The results show that {alpha}-MnO{sub 2} single-crystal nanorods with a mean diameter of 15 nm were densely grown on the surface of MWNTs. Those MWNTs/MnO{sub 2} composites were used as an electrode material for supercapacitors, and it was found that the supercapacitor performance using MWNTs/MnO{sub 2} composites was improved largely compared to that using pure MWNTs and {alpha}-MnO{sub 2} nanorod mechanically mixed with MWNTs.

  11. Effect of Ti doping on high pressure behavior of BiMn{sub 2}O{sub 5}

    SciTech Connect (OSTI)

    Pandey, K. K., E-mail: kkpandey@barc.gov.in; Poswal, H. K., E-mail: kkpandey@barc.gov.in; Sharma, Surinder M. [High Pressure and Synchrotron Radiation Physics Division, Bhabha Atomic Research Centre, Trombay, Mumbai 40008 (India); Kumar, Ravi [Centre for Materials Science and Engineering, National Institute of Technology, Hamirpur-177005 (India)

    2014-04-24T23:59:59.000Z

    Our high pressure x-ray diffraction studies on BiMn{sub 1.5}Ti{sub 0.5}O{sub 5} show iso-structural phase transition above 12 GPa similar to the one observed in undoped BiMn{sub 2}O{sub 5}; however anisotropic compressional behavior is found to be more enhanced in the doped case. Unlike undoped system, an anomalous lattice expansion along c axis has been observed in BiMn{sub 1.5}Ti{sub 0.5}O{sub 5} above 12 GPa; whereas the b lattice parameter has been found to be more compressible as compared to BiMn{sub 2}O{sub 5}. As doping with Ti reduces the magnetic interactions among Mn ions, the observed changes are suggestive of having adverse magnetic implications in the observed iso-structural phase transition.

  12. Super KEKB / Belle II Project

    E-Print Network [OSTI]

    B. Golob

    2010-06-22T23:59:59.000Z

    We present the status of the KEKB collider and the Belle detector upgrade, along with several examples of physics measurements to be performed with Belle II at Super KEKB.

  13. Environmental Chemistry II (Atmospheric Chemistry)

    E-Print Network [OSTI]

    Dibble, Theodore

    Seinfeld, J. H. and Pandis, S. N. Atmospheric Chemistry and Physics: From Air Pollution to Climate ChangeSYLLABUS FOR Environmental Chemistry II (Atmospheric Chemistry) FCH 511 Fall 2013 Theodore S

  14. The Kinematic Composition of MgII Absorbers

    E-Print Network [OSTI]

    Jane C. Charlton; Christopher W. Churchill

    1997-12-17T23:59:59.000Z

    The study of galaxy evolution using quasar absorption lines requires an understanding of what components of galaxies and their surroundings are contributing to the absorption in various transitions. This paper considers the kinematic composition of the class of 0.4 < z < 1.0 MgII absorbers, particularly addressing the question of what fraction of this absorption is produced in halos and what fraction arises from galaxy disks. We design models with various fractional contributions from radial infall of halo material and from a rotating thick disk component. We generate synthetic spectra from lines of sight through model galaxies and compare the resulting ensembles of MgII profiles with the 0.4 < z < 1.0 sample observed with HIRES/Keck. We apply a battery of statistical tests and find that pure disk and pure halo models can be ruled out, but that various models with rotating disk and infall/halo contributions can produce an ensemble that is nearly consistent with the data. A discrepancy in all models that we considered requires the existence of a kinematic component intermediate between halo and thick disk. The variety of MgII profiles can be explained by the gas in disks and halos of galaxies not very much different than galaxies in the local Universe. In any one case there is considerable ambiguity in diagnosing the kinematic composition of an absorber from the low ionization high resolution spectra alone. Future data will allow galaxy morphologies, impact parameters, and orientations, FeII/MgII of clouds, and the distribution of high ionization gas to be incorporated into the kinematic analysis. Combining all these data will permit a more accurate diagnosis of the physical conditions along the line of sight through the absorbing galaxy.

  15. Redox Exchange Induced MnO2 Nanoparticle Enrichment in Poly(3,4-ethylenedioxythiophene) Nanowires for Electrochemical Energy Storage

    SciTech Connect (OSTI)

    Liu, R; Duay, Jonathon; Lee, Sang Bok

    2010-01-01T23:59:59.000Z

    MnO{sub 2} nanoparticle enriched poly(3,4-ethylenedioxythiophene) (PEDOT) nanowires are fabricated by simply soaking the PEDOT nanowires in potassium permanganate (KMnO{sub 4}) solution. The structures of these MnO{sub 2} nanoparticle enriched PEDOT nanowires are characterized by SEM and TEM, which show that the MnO{sub 2} nanoparticles have uniform sizes and are finely dispersed in the PEDOT matrix. The chemical constituents and bonding of these composite nanowires are characterized by energy-dispersive X-ray analysis, X-ray photoelectron spectroscopy, and infrared spectroscopy, which indicate that the formation and dispersion of these MnO{sub 2} nanoparticles into the nanoscale pores of the PEDOT nanowires are most likely triggered by the reduction of KMnO{sub 4} via the redox exchange of permanganate ions with the functional group on PEDOT. Varying the concentrations of KMnO{sub 4} and the reaction time controls the loading amount and size of the MnO{sub 2} nanoparticles. Cyclic voltammetry and galvanostatic charge?discharge are used to characterize the electrochemical properties of these MnO{sub 2} nanoparticle loaded PEDOT nanowires. Due to their extremely high exposed surface area with nanosizes, the pristine MnO{sub 2} nanoparticles in these MnO{sub 2} nanoparticle enriched PEDOT nanowires show very high specific capacitance (410 F/g) as the supercapacitor electrode materials as well as high Li+ storage capacity (300 mAh/g) as cathode materials of Li ion battery, which boost the energy storage capacity of PEDOT nanowires to 4 times without causing excessive volume expansion in the polymer. The highly conductive and porous PEDOT matrix facilitates fast charge/discharge of the MnO{sub 2} nanoparticles and prevents them from agglomerating. These synergic properties enable the MnO{sub 2} nanoparticle enriched PEDOT nanowires to be promising electrode materials for supercapacitors and lithium ion batteries.

  16. Local Agency Project Manager Checklist The steps below follow those outlined in the Mn/DOT Utility Manual. A PDF of the manual

    E-Print Network [OSTI]

    Minnesota, University of

    Form Contact utility owners Utility Contact List available at http://www.dot.state.mn.us/utility/files/pdf/contacts/contact-utilityLocal Agency Project Manager Checklist The steps below follow those outlined in the Mn/DOT Utility Manual. A PDF of the manual and supporting documents are available at: http://www.dot.state.mn.us/utility

  17. Diesel Fueled SOFC for Class 7/Class 8 On-Highway Truck Auxiliary Power

    SciTech Connect (OSTI)

    Vesely, Charles John-Paul [Cummins Power Generation; Fuchs, Benjamin S. [Cummins Power Generation; Booten, Chuck W. [Protonex Technology, LLC

    2010-03-31T23:59:59.000Z

    The following report documents the progress of the Cummins Power Generation (CPG) Diesel Fueled SOFC for Class 7/Class 8 On-Highway Truck Auxiliary Power (SOFC APU) development and final testing under the U.S. Department of Energy (DOE) Energy Efficiency and Renewable Energy (EERE) contract DE-FC36-04GO14318. This report overviews and summarizes CPG and partner development leading to successful demonstration of the SOFC APU objectives and significant progress towards SOFC commercialization. Significant SOFC APU Milestones: Demonstrated: Operation meeting SOFC APU requirements on commercial Ultra Low Sulfur Diesel (ULSD) fuel. SOFC systems operating on dry CPOX reformate. Successful start-up and shut-down of SOFC APU system without inert gas purge. Developed: Low cost balance of plant concepts and compatible systems designs. Identified low cost, high volume components for balance of plant systems. Demonstrated efficient SOFC output power conditioning. Demonstrated SOFC control strategies and tuning methods.

  18. Neural network definitions of highly predictable protein secondary structure classes

    SciTech Connect (OSTI)

    Lapedes, A. [Los Alamos National Lab., NM (United States)]|[Santa Fe Inst., NM (United States); Steeg, E. [Toronto Univ., ON (Canada). Dept. of Computer Science; Farber, R. [Los Alamos National Lab., NM (United States)

    1994-02-01T23:59:59.000Z

    We use two co-evolving neural networks to determine new classes of protein secondary structure which are significantly more predictable from local amino sequence than the conventional secondary structure classification. Accurate prediction of the conventional secondary structure classes: alpha helix, beta strand, and coil, from primary sequence has long been an important problem in computational molecular biology. Neural networks have been a popular method to attempt to predict these conventional secondary structure classes. Accuracy has been disappointingly low. The algorithm presented here uses neural networks to similtaneously examine both sequence and structure data, and to evolve new classes of secondary structure that can be predicted from sequence with significantly higher accuracy than the conventional classes. These new classes have both similarities to, and differences with the conventional alpha helix, beta strand and coil.

  19. PHYSLIB: A C++ tensor class library

    SciTech Connect (OSTI)

    Budge, K.G.

    1991-10-09T23:59:59.000Z

    C++ is the first object-oriented programming language which produces sufficiently efficient code for consideration in computation-intensive physics and engineering applications. In addition, the increasing availability of massively parallel architectures requires novel programming techniques which may prove to be relatively easy to implement in C++. For these reasons, Division 1541 at Sandia National Laboratories is devoting considerable resources to the development of C++ libraries. This document describes the first of these libraries to be released, PHYSLIB, which defines classes representing Cartesian vectors and (second-order) tensors. This library consists of the header file physlib.h, the inline code file physlib.inl, and the source file physlib.C. The library is applicable to both three-dimensional and two-dimensional problems; the user selects the 2-D version of the library by defining the symbol TWO D in the header file physlib.h and recompiling physlib.C and his own code. Alternately, system managers may wish to provide duplicate header and object modules of each dimensionality. This code was produced under the auspices of Sandia National Laboratories, a federally-funded research center administered for the United States Department of Energy on a non-profit basis by AT T. This code is available to US citizens, and institutions under research, government use and/or commercial license agreements.

  20. Atomic and molecular adsorption on RhMn alloy surface: A first principles study

    E-Print Network [OSTI]

    Li, Weixue

    and hydrogen from reforming of natural gas and coal to hydro- carbon Fishcher-Tropsch synthesis and oxygenates- bon and partial oxidation of methane.15 The importance of Rh catalysts on catalytic reactions molecules in terms of the energetics and site preferences on Rh catalysts as well as the effects of Mn added

  1. Crystallography of Interfaces and Grain Size Distributions in Sr-Doped LaMnO3

    E-Print Network [OSTI]

    Rohrer, Gregory S.

    Crystallography of Interfaces and Grain Size Distributions in Sr-Doped LaMnO3 Qinyuan Liu,§ Sudip systems are similar. I. Introduction HIGH-TEMPERATURE solid oxide fuel cells (SOFCs) offer highly efficient, clean, direct conversion of chemical to electrical energy.1 SOFC performance is dictated

  2. Frustration and multiferroic behavior in Ca3CoMnO6

    SciTech Connect (OSTI)

    Zapf, Vivien [Los Alamos National Laboratory

    2012-06-01T23:59:59.000Z

    Lu{sub 2}MnCoO{sub 6} and Ca{sub 3}MnCoO{sub 6} satisfy one of the primary goals of multiferroics research, namely ferromagnetic-like magnetization coupled to ferroelectric-like polarization. Thus the mechanism for magnetoelectric coupling in these materials deserves careful study. New data shows that the physics of these compound may be related to the classic 'ANNNI' model. Frustration between ferromagnetic nearest-neighbor and antiferromagnetic next-nearest-neighbor interactions between Ising spins creates an 'up up down down' magnetic structure in zero magnetic field, along c-axis chains that consist of alternating Co and Mn ions. In applied magnetic fields 'up up down,' 'up up up down' and other metastable variations can evolve, yielding hysteretic ferromagnetic-like magnetization. The key is that the phase slips between regions of 'up' and 'down' carries an electric polarization due to broken spatial inversion symmetry. Thus these phase slips can be manipulated with both electric and magnetic fields. The result is a profusion of magnetic and electric states that are closely-spaced in temperature, electric, and magnetic field. We present experimental studies of the magnetic, electric, and structural properties of these two compounds. We include very new data up to 100 Ton Ca{sub 3}CoMnO{sub 6} that resolves a key controversy of over the magnetic structure and the size of the moments.

  3. Optical properties of metallic (III, Mn)V ferromagnetic semiconductors in the infrared to visible range

    E-Print Network [OSTI]

    Hankiewicz, EM; Jungwirth, T.; Dietl, T.; Timm, C.; Sinova, Jairo.

    2004-01-01T23:59:59.000Z

    We report on a study of the ac conductivity and magneto-optical properties of metallic ferromagnetic (III, Mn)V semiconductors in the infrared to visible spectrum at zero temperature. Our analysis is based on the successful kinetic exchange model...

  4. Microscopic mechanism of the noncrystalline anisotropic magnetoresistance in (Ga,Mn)As

    E-Print Network [OSTI]

    Vyborny, Karel; Kucera, Jan; Sinova, Jairo; Rushforth, A. W.; Gallagher, B. L.; Jungwirth, T.

    2009-01-01T23:59:59.000Z

    Starting with a microscopic model based on the Kohn-Luttinger Hamiltonian and kinetic p-d exchange combined with Boltzmann formula for conductivity we identify the scattering from magnetic Mn combined with the strong spin-orbit interaction of the Ga...

  5. Synthesis and Characterization of NiMnGa Ferromagnetic Shape Memory Alloy Thin Films

    E-Print Network [OSTI]

    Jetta, Nishitha

    2011-10-21T23:59:59.000Z

    , it is very important to understand their behavior and examine their properties. This thesis is an effort to contribute to the literature of Ni-Mn-Ga thin films as ferromagnetic shape memory alloys. The focus of this project is to develop a recipe...

  6. Aliovalent titanium substitution in layered mixed Li Ni-Mn-Co oxides for lithium battery applications

    SciTech Connect (OSTI)

    Kam, Kinson; Doeff, Marca M.

    2010-12-01T23:59:59.000Z

    Improved electrochemical characteristics are observed for Li[Ni1/3Co1/3-yMyMn1/3]O2 cathode materials when M=Ti and y<0.07, compared to the baseline material, with up to 15percent increased discharge capacity.

  7. Giant magnetothermal conductivity in the NiMnIn ferromagnetic shape memory alloys

    E-Print Network [OSTI]

    Zexian, Cao

    ­10 It is well known that colossal magne- toresistance CMR in the Mn-based perovskites is closely related, this transition can be shifted to lower temperature and even totally suppressed by a magnetic field. The magnetic: 10.1063/1.2753710 Very recently, Kainuma et al. discovered magnetic-field- induced shape recovery

  8. Modified magnetic ground state in NiMn2O4 thin films

    SciTech Connect (OSTI)

    Nelson-Cheeseman, B. B.; Chopdekar, R. V.; Toney, M. F.; Arenholz, E.; Suzuki, Y.; Iwata, J.M.

    2010-08-03T23:59:59.000Z

    We demonstrate the stabilization of a magnetic ground state in epitaxial NiMn2O4 (NMO) thin films not observed in their bulk counterpart. Bulk NMO exhibits a magnetic transition from a paramagnetic phase to a collinear ferrimagnetic moment configuration below 110 K and to a canted moment configuration below 70 K. By contrast, as-grown NMO films exhibit a single magnetic transition at 60 K and annealed films exhibit the magnetic behavior found in bulk. Cation inversion and epitaxial strain are ruled out as possible causes for the new magnetic ground state in the as-grown films. However, a decrease in the octahedral Mn{sup 4+}:Mn{sup 3+} concentration is observed and likely disrupts the double exchange that produces the magnetic state at intermediate temperatures. X-ray magnetic circular dichroism and bulk magnetometry indicate a canted ferrimagnetic state in all samples at low temperature. Together these results suggest that the collinear ferrimagnetic state observed in bulk NMO at intermediate temperatures is suppressed in the as grown NMO thin films due to a decrease in octahedral Mn{sup 4+} while the canted moment ferrimagnetic ordering is preserved below 60 K.

  9. Reduced-activation austenitic stainless steels: The Fe--Mn--Cr--C system

    SciTech Connect (OSTI)

    Klueh, R.L.; Maziasz, P.J.

    1988-01-01T23:59:59.000Z

    Nickel-free manganese-stabilized steels are being developed for fusion-reactor applications. As the first part of this effort, the austenite-stable region in the Fe--Mn--Cr--C system was determined. Results indicated that the Schaeffler diagram developed for Fe--Ni--Cr--C alloys cannot be used to predict the constituents expected for high-manganese steels. This is true because manganese is not as strong an austenite stabilizer relative to delta-ferrite formation as predicted by the diagram, but it is a stronger austenite stabilizer relative to martensite than predicted. Therefore, the austenite-stable region for Ne--Mn--Cr--C alloys occurs at lower chromium and hugher combinations of manganese and carbon than predicted by the Schaeffler diagram. Development of a manganese-stabilized stainless steel should be possible in the composition range of 20 to 25% Mn, 10 to 15% Cr, and 0.01 to 0.25%C. Tensile behavior of an Fe--20%Mn--12%Cr--0.25%C alloy was determined. The strength and ductility of this possible base composition was comparable to type 316 stainless steel in both the solution-annealed and cold-worked condition.

  10. Electrodeposition of Mn-Co Alloys on Stainless Steels for SOFC Interconnect Application

    SciTech Connect (OSTI)

    Wu, J. (West Virginia University); Jiang, Y. (West Virginia University); Johnson, C.; Gong, M. (West Virginia University); Liu, X. (West Virginia University)

    2007-09-01T23:59:59.000Z

    Chromium-containing ferritic stainless steels are the most popular materials for solid oxide fuel cell (SOFC) interconnect applications because of its oxidation resistance and easy fabrication process. However, excessive scale growth and chromium evaporation will degrade the cell performance. Highly conductive coatings that resist oxide scale growth and chromium evaporation may prevent both of these problems. Mn1.5Co1.5O4 spinel is one of the most promising coatings for interconnect application because of its high conducitivy, good chromium retention capability, as well as good CTE match. Electroplating of alloys or thin film multilayers followed by controlled oxidation to the desired spinel phase offers an additional deposition option. In the present study binary Mn/Co alloys was fabricated by electrodeposition, and polarization curves were used to characterize the cathodic reactions on substrate surface. By controlling the current density precisely, coatings with Mn/Co around 1:1 has been successfully deposited in Mn/Co =10 solutions, SEM and EDX was used to characterize the surface morphology and composition.

  11. Electrical gating effects on the magnetic properties of (Ga,Mn)As diluted magnetic semiconductors

    E-Print Network [OSTI]

    Owen, Man Hon Samuel

    2010-11-16T23:59:59.000Z

    -effect transistor (FET) based on low-doped Ga0.975Mn0.025As was fabricated. It has an in-built n-GaAs back-gate, which, in addition to being a normal gate, enhances the gating effects, especially in the depletion of the epilayer, by decreasing the effective channel...

  12. Chobert MN et al LIVER PRECURSOR CELLS INCREASE HEPATIC FIBROSIS INDUCED BY CHRONIC

    E-Print Network [OSTI]

    Boyer, Edmond

    by chronic carbon tetrachloride (CCl4) administration for 6 weeks, in combination with chronic; CCl4, carbon tetrachloride; CK19, cytokeratin 19; CCR2, chemokine C-C motif receptor 2; EMTChobert MN et al LIVER PRECURSOR CELLS INCREASE HEPATIC FIBROSIS INDUCED BY CHRONIC CARBON

  13. A violet emission in ZnS:Mn,Eu: Luminescence and applications for radiation detection

    SciTech Connect (OSTI)

    Ma, Lun; Chen, Wei, E-mail: weichen@uta.edu [Department of Physics and the SAVANT Center, The University of Texas at Arlington, Arlington, Texas 76019-0059 (United States); Jiang, Ke [Center for Biofrontiers Institute, University of Colorado at Colorado Springs, 1420 Austin Bluffs Pkwy., Colorado Springs, Colorado 80918 (United States); Liu, Xiao-tang [Department of Physics and the SAVANT Center, The University of Texas at Arlington, Arlington, Texas 76019-0059 (United States); Department of Applied Chemistry, College of Science, South China Agricultural University, Guangzhou 510642 (China)

    2014-03-14T23:59:59.000Z

    We prepared manganese and europium co-doped zinc sulfide (ZnS:Mn,Eu) phosphors and used them for radiation detection. In addition to the red fluorescence at 583?nm due to the d-d transition of Mn ions, an intense violet emission at 420?nm is newly observed in ZnS:Mn,Eu phosphors. The emission is related to Eu{sup 2+} doping but only appears at certain Eu{sup 2+} concentrations. It is found that the intensity of the 420?nm violet fluorescence is X-ray does-dependent, while the red fluorescence of 583?nm is not. The ratio of fluorescence intensities at 420?nm and 583?nm has been monitored as a function of X-ray doses that exposed upon the ZnS:Mn,Eu phosphors. Empirical formulas are provided to estimate the doses of applied X-ray irradiation. Finally, possible mechanisms of X-ray irradiation induced fluorescence quenching are discussed. The intense 420?nm emission not only provides a violet light for solid state lighting but also offers a very sensitive method for radiation detection.

  14. Dynamic Conditional Correlation - A Simple Class of Multivariate GARCH Models

    E-Print Network [OSTI]

    Engle, Robert F

    2000-01-01T23:59:59.000Z

    Multivariate Simultaneous GARCH," Econometric Theory 11,and Joseph Mezrich, (1996) "GARCH for Groups," Risk August,SIMPLE CLASS OF MULTIVARIATE GARCH MODELS BY ROBERT F. ENGLE

  15. A parallel between two classes of pricing problems in transportation ...

    E-Print Network [OSTI]

    G raldine Heilporn

    2009-01-05T23:59:59.000Z

    Jan 5, 2009 ... A parallel between two classes of pricing problems in transportation and economics. G raldine Heilporn (Geraldine.Heilporn ***at*** hec.ca)

  16. A New Class of Switched Reluctance Motors without Permanent Magnets...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A New Class of Switched Reluctance Motors without Permanent Magnets A Segmented Drive Inverter Topology with a Small DC Bus Capacitor A Segmented Drive Inverter Topology with a...

  17. Class Patent Waiver W(C)2011-009

    Broader source: Energy.gov [DOE]

    This is a request by WFO Class Waiver for a DOE waiver of domestic and foreign patent rights under agreement N/A.

  18. PE06 -Beginning & Intermediate Core Training Class Syllabus

    E-Print Network [OSTI]

    PE06 - Beginning & Intermediate Core Training Class Syllabus Instructor: Sandra Marbut Office attendance requirements as outlined on this syllabus 3. Pass midterm examination 4. Submit their final

  19. acute toxic class method: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and is obtained in two steps. First a scalar problem is solved Henrion, Didier 34 Analysis of the factorization method for a general class of boundary conditions Physics...

  20. Defect classes - an overdue paradigm for CMOS IC testing

    SciTech Connect (OSTI)

    Hawkins, C.F. [Univ. of New Mexico, Albuquerque, NM (United States); Soden, J.M.; Righter, A.W. [Sandia National Labs., Albuquerque, NM (United States); Ferguson, F.J. [Univ. of California, Santa Cruz, CA (United States)

    1994-09-01T23:59:59.000Z

    The IC test industry has struggled for more than 30 years to establish a test approach that would guarantee a low defect level to the customer. We propose a comprehensive strategy for testing CMOS ICs that uses defect classes based on measured defect electrical properties. Defect classes differ from traditional fault models. Our defect class approach requires that the test strategy match the defect electrical properties, while fault models require that IC defects match the fault definition. We use data from Sandia Labs failure analysis and test facilities and from public literature. We describe test pattern requirements for each defect class and propose a test paradigm.

  1. University ofWashington DIRECTORY*OF CLASSES,u

    E-Print Network [OSTI]

    Kaminsky, Werner

    University ofWashington DIRECTORY*OF CLASSES,u 8060- PUBLISHED IN BACK-TO-SCHOOL SERIES 1995 ©1995 Phone Directory.~........:....................................................................3 Address

  2. Accelerated Schemes For A Class of Variational Inequalities

    E-Print Network [OSTI]

    Yuyuan Chen

    2014-03-17T23:59:59.000Z

    Mar 17, 2014 ... Abstract: We propose a novel method, namely the accelerated mirror-prox (AMP) method, for computing the weak solutions of a class of ...

  3. Class Patent Waiver W(C)2012-006

    Broader source: Energy.gov [DOE]

    This is a request by LBNL DESIGN FORWARD PROJECT for a DOE Class patent waiver of domestic and foreign patent rights under agreement N/A.

  4. Guidelines for Writing Papers in Music History and Literature Classes

    E-Print Network [OSTI]

    Saldin, Dilano

    Guidelines for Writing Papers in Music History and Literature Classes which these Guidelines are based) Quick Guide: http;3 · Use "measure" instea

  5. STATEMENT OF CONSIDERATIONS CLASS WANER OF THE GOVERNMENT'S

    Broader source: Energy.gov (indexed) [DOE]

    to designated user facilities under the auspices of the Department's Energy Research program. This new Class Waiver expands the former by making available the utilization ofthe...

  6. Helical antiferromagnetic ordering in Lu1-xScxMnSi

    SciTech Connect (OSTI)

    Goetsch, Ryan J [Ames Laboratory; Anand, V K [Ames Laboratory; Johnston, David C [Ames Laboratory

    2014-08-01T23:59:59.000Z

    Polycrystalline samples of Lu1?xScxMnSi (x=0, 0.25, 0.5) are studied using powder x-ray diffraction, heat capacity Cp, magnetization, magnetic susceptibility ?, and electrical resistivity ? measurements versus temperature T and magnetic field H. This system crystallizes in the primitive orthorhombic TiNiSi-type structure (space group Pnma) as previously reported. The ?(T) data indicate metallic behavior. The Cp(T), ?(T), and ?(T) measurements consistently indicate long-range antiferromagnetic (AF) transitions with AF ordering temperatures TN=246, 215, and 188 K for x=0, 0.25, and 0.5, respectively. A second transition is observed at somewhat lower T for each sample from the ?(T) and ?(T) measurements, which we speculate are due to spin reorientation transitions; these second transitions are completely suppressed in H=5.5 T. The Cp data below 10 K for each composition indicate an enhanced Sommerfeld electronic heat capacity coefficient for the series in the range ?=24–29 mJ/mol K2. The ?(T) measurements up to 1000 K were fitted by local-moment Curie-Weiss behaviors which indicate a low Mn spin S?1. The ? data below TN are analyzed using the Weiss molecular field theory for a planar noncollinear cycloidal AF structure with a composition-dependent pitch, following the previous neutron diffraction work of Venturini et al. [J. Alloys Compd. 256, 65 (1997)]. Within this model, the fits indicate a turn angle between Mn ordered moments along the cycloid axis of ?100? or ?145?, either of which indicate dominant AF interactions between the Mn spins in the Lu1?xScxMnSi series of compounds.

  7. High-field electroluminescence in semiconductor tunnel junctions with a Mn-doped GaAs layer

    SciTech Connect (OSTI)

    Hai, Pham Nam [Department of Electrical Engineering and Information Systems, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan); Department of Physical Electronics, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Tokyo 152-0033 (Japan); Yatsui, Takashi; Ohtsu, Motoichi; Tanaka, Masaaki [Department of Electrical Engineering and Information Systems, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan); Nanophotonics Research Center, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)

    2014-09-21T23:59:59.000Z

    We investigated high-field electroluminescence (EL) in semiconductor tunnel junctions with a Mn-doped GaAs layer (here, referred to as GaAs:Mn). Besides the band-gap emission of GaAs, the EL spectra show visible light emissions with two peaks at 1.94?eV and 2.19?eV, which are caused by d-d transitions of the Mn atoms excited by hot electrons. The threshold voltages for band-gap and visible light EL in the tunnel junctions with a GaAs:Mn electrode are 1.3?V higher than those of GaAs:Mn excited by hot holes in reserve biased p{sup +}-n junctions, which is consistent with the hot carrier transport in the band profiles of these structures. Our EL results at room temperature show that the electron temperature in GaAs:Mn can be as high as ?700?K for a low input electrical power density of 0.4?W/cm{sup 2}, while the lattice temperature of the GaAs:Mn layer can be kept at 340?K.

  8. Stewart Morrow Field - DOE Class 1

    SciTech Connect (OSTI)

    Burchardt, P.; Reynolds, R.R.; Watney, L.

    1995-12-31T23:59:59.000Z

    Two demonstration cost-share projects are being conducted in Kansas under the U.S. Department of Energy (DOE) Class 1 Oil Program for fluvial dominated deltaic reservoirs. These projects are one of fourteen awards granted by DOE nationwide for projects in this reservoir classification. The projects are conducted in a cooperative manner, involving University of Kansas scientists, engineers, and geologists and independent oil operators. The Stewart Field project is located in Finney County, Kansas. This project involves a Morrow reservoir located in the southwestern part of the State. Morrow reservoirs of western Kansas are still actively being explored and constitute an important resource in Kansas. Cumulative oil production from the Marrow in Kansas is over 174,308,000 bbls. Much of the production from the Morrow is still in the primary stage and has not reached the mature declining stage. The objective of this project is to address waterflood problems in Morrow sandstone reservoirs in southwestern Kansas. The general topics addressed are (1) reservoir management and primary drive performance evaluation, and (2) the demonstration of a recovery process involving off-the-shelf technology which can be used to enhance waterflood recovery and increase reserves. Future plans consist of the design, construction and operation of a waterflood installation incorporated fieldwide utilizing state-of-the art, off-the-shelf technologies in an attempt to optimize secondary oil recovery. Production and reservoir data will be analyzed using reservoir characterization techniques and by updating the existing reservoir simulation. The analysis of results will be utilized to optimize the waterflood plan and flooding techniques to maximize the secondary oil recovery.

  9. THE MAGNETIC FIELD MORPHOLOGY OF THE CLASS 0 PROTOSTAR L1157-mm

    SciTech Connect (OSTI)

    Stephens, Ian W.; Looney, Leslie W.; Kwon, Woojin; Crutcher, Richard M. [Department of Astronomy, University of Illinois, 1002 West Green Street, Urbana, IL 61801 (United States); Hull, Charles L. H.; Plambeck, Richard L. [Astronomy Department and Radio Astronomy Laboratory, 601 Campbell Hall, University of California, Berkeley, CA 94720 (United States); Chapman, Nicholas; Novak, Giles; Matthews, Tristan [Center for Interdisciplinary Exploration and Research in Astrophysics (CIERA) and Department of Physics and Astronomy, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208 (United States); Davidson, Jacqueline [School of Physics, University of Western Australia, 35 Stirling Hwy, Crawley, WA 6009 (Australia); Vaillancourt, John E. [SOFIA Science Center, Universities Space Research Association, NASA Ames Research Center, MS 232-11, Moffett Field, CA 94035-0001 (United States); Shinnaga, Hiroko, E-mail: stephen6@illinois.edu [Subaru Telescope, National Astronomical Observatory of Japan, 650 North A'ohoku Place, Hilo, HI 96720 (United States)

    2013-05-20T23:59:59.000Z

    We present the first detection of polarization around the Class 0 low-mass protostar L1157-mm at two different wavelengths. We show polarimetric maps at large scales (10'' resolution at 350 {mu}m) from the SHARC-II Polarimeter and at smaller scales (1.''2-4.''5 at 1.3 mm) from the Combined Array for Research in Millimeter-wave Astronomy (CARMA). The observations are consistent with each other and show inferred magnetic field lines aligned with the outflow. The CARMA observations suggest a full hourglass magnetic field morphology centered about the core; this is only the second well-defined hourglass detected around a low-mass protostar to date. We apply two different methods to CARMA polarimetric observations to estimate the plane-of-sky magnetic field magnitude, finding values of 1.4 and 3.4 mG.

  10. LCLS-II New Instruments Workshops Report

    SciTech Connect (OSTI)

    Baradaran, Samira; Bergmann, Uwe; Durr, Herrmann; Gaffney, Kelley; Goldstein, Julia; Guehr, Markus; Hastings, Jerome; Heimann, Philip; Lee, Richard; Seibert, Marvin; Stohr, Joachim; /SLAC; ,

    2012-08-08T23:59:59.000Z

    The LCLS-II New Instruments workshops chaired by Phil Heimann and Jerry Hastings were held on March 19-22, 2012 at the SLAC National Accelerator Laboratory. The goal of the workshops was to identify the most exciting science and corresponding parameters which will help define the LCLS-II instrumentation. This report gives a synopsis of the proposed investigations and an account of the workshop. Scientists from around the world have provided short descriptions of the scientific opportunities they envision at LCLS-II. The workshops focused on four broadly defined science areas: biology, materials sciences, chemistry and atomic, molecular and optical physics (AMO). Below we summarize the identified science opportunities in the four areas. The frontiers of structural biology lie in solving the structures of large macromolecular biological systems. Most large protein assemblies are inherently difficult to crystallize due to their numerous degrees of freedom. Serial femtosecond protein nanocrystallography, using the 'diffraction-before-destruction' approach to outrun radiation damage has been very successfully pioneered at LCLS and diffraction patterns were obtained from some of the smallest protein crystals ever. The combination of femtosecond x-ray pulses of high intensity and nanosized protein crystals avoids the radiation damage encountered by conventional x-ray crystallography with focused beams and opens the door for atomic structure determinations of the previously largely inaccessible class of membrane proteins that are notoriously difficult to crystallize. The obtained structures will allow the identification of key protein functions and help in understanding the origin and control of diseases. Three dimensional coherent x-ray imaging at somewhat lower resolution may be used for larger objects such as viruses. The chemistry research areas of primary focus are the predictive understanding of catalytic mechanisms, with particular emphasis on photo- and heterogeneous catalysis. Of particular interest is the efficient conversion of light to electrical or chemical energy, which requires understanding the non-adiabatic dynamics of electronic excited states. Ultrafast x-ray scattering presents an excellent opportunity to investigate structural dynamics of molecular systems with atomic resolution, and x-ray scattering and spectroscopy present an excellent opportunity to investigating the dynamics of the electronic charge distribution. Harnessing solar energy to generate fuels, either indirectly with photovoltaics and electrochemical catalysis or directly with photocatalysts, presents a critical technological challenge that will require the use of forefront scientific tools such as ultrafast x-rays. At the center of this technical challenge is the rational design of efficient and cost effective catalysts. Important materials science opportunities relate to information technology applications, in particular the transport and storage of information on increasingly smaller length- and faster time-scales. Of interest are the understanding of the intrinsic size limits associated with the storage of information bits and the speed limits of information or bit processing. Key questions revolve about how electronic charges and spins of materials can be manipulated by electric and magnetic fields. This requires the exploration of speed limits subject to the fundamental conservation laws of energy and linear and angular momentum and the different coupling of polar electric and axial magnetic fields to charge and spin. Of interest are novel composite materials, including molecular systems combining multi electric and magnetic functionality. Ultrafast x-rays offer the required probing speed, can probe either the charge or spin properties through polarization control and through scattering and spectroscopy cover the entire energy-time-momentum-distance phase space. In the field of atomic and molecular science, LCLS II promises to elucidate the fundamental interactions among electrons and between electrons and nuclei, and to explore the fron

  11. 2013 Team UniSA-Australia World class thinking.

    E-Print Network [OSTI]

    Li, Jiuyong "John"

    2013 Team UniSA-Australia guide World class thinking. World class talent. #12;Intoduction A message from Patrick Jonker, Team UniSA-Australia Ambassador Rider Profiles > Bernard Sulzberger > Adam Phelan and contacts 3 4 5 6 7 8 9 10 11 12 Team UniSA-Australia contents #12;3 Team UniSA-Australia A modern, vibrant

  12. The Dangerous Allure of the Issue Class Action

    E-Print Network [OSTI]

    Hines, Laura J.

    2004-01-01T23:59:59.000Z

    In the complex and chaotic world of mass torts, a class action that aggregates the claims of aggrieved individuals against a common defendant would seem not only a prudent solution, but possibly even a necessary one. The class device holds out...

  13. Free Minor Closed Classes and the Kuratowski theorem. Dainis ZEPS

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Free Minor Closed Classes and the Kuratowski theorem. Dainis ZEPS Abstract Free-minor closed classes [2] and free-planar graphs [3] are considered. Versions of Kuratowski-like theorem for free example is free-planar graphs [3]. A planar graph is called free-planar, if after adding an arbitrary edge

  14. A Class-Object Model for Program Transformations

    E-Print Network [OSTI]

    Chiba, Shigeru

    class-object model makes power- ful transformations not only of the compiler experts but alsoA Class-Object Model for Program Transformations Doctoral Program in Engineering University. The technology that enables the reuse of larger software components have become available with the emergence

  15. FUNCTIONAL DECOMPOSITION OF A CLASS OF WILD POLYNOMIALS

    E-Print Network [OSTI]

    Coulter, Robert

    FUNCTIONAL DECOMPOSITION OF A CLASS OF WILD POLYNOMIALS ROBERT S. COULTER, GEORGE HAVAS AND MARIE for the functional de- composition of wild polynomials over a finite field. However partial solutions exist factoring methods in skew-polynomial rings. This algorithm is extended to a related class of wild

  16. Nonproliferation Graduate Fellowship Program, Annual Report, Class of 2012

    SciTech Connect (OSTI)

    McMakin, Andrea H.

    2013-09-23T23:59:59.000Z

    This 32-pp annual report/brochure describes the accomplishments of the Class of 2012 of the Nonproliferation Graduate Fellowship Program (the last class of this program), which PNNL administers for the National Nuclear Security Administration. The time period covers Sept 2011 through June 2013.

  17. Atomic moments in Mn2CoAl thin films analyzed by X-ray magnetic circular dichroism

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jamer M.; Sterbinsky G.; Assaf, B.; Arena, D.; Heiman, D.

    2014-12-07T23:59:59.000Z

    Spin gapless semiconductors are known to be strongly affected by structural disorder when grown epitaxially as thin films. The magnetic properties of Mn2CoAl thin films grown on GaAs (001) substrates are investigated here as a function of annealing. This study investigates the atomic-specific magnetic moments of Mn and Co atoms measured through X-ray magnetic circular dichroism as a function of annealing and the consequent structural ordering. The results indicate that the structural distortion mainly affects the Mn atoms as seen by the reduction of the magnetic moment from its predicted value. (auth)

  18. Precipitation in cold-rolled Al–Sc–Zr and Al–Mn–Sc–Zr alloys prepared by powder metallurgy

    SciTech Connect (OSTI)

    Vlach, M., E-mail: martin.vlach@mff.cuni.cz [Charles University in Prague, Faculty of Mathematics and Physics, Ke Karlovu 3, CZ-121 16 Prague (Czech Republic); Stulikova, I.; Smola, B.; Kekule, T.; Kudrnova, H.; Danis, S. [Charles University in Prague, Faculty of Mathematics and Physics, Ke Karlovu 3, CZ-121 16 Prague (Czech Republic); Gemma, R. [King Abdullah University of Science and Technology (KAUST), Physical Sciences and Engineering Division, 23955-6900 Thuwal (Saudi Arabia); Ocenasek, V. [SVÚM a.s., Podnikatelská 565, CZ-190 11 Prague (Czech Republic); Malek, J. [Czech Technical University in Prague, Faculty of Mechanical Engineering, CZ-120 00 Prague (Czech Republic); Tanprayoon, D.; Neubert, V. [Institut für Materialprüfung und Werkstofftechnik, Freiberger Strasse 1, D-38678 Clausthal-Zellerfeld (Germany)

    2013-12-15T23:59:59.000Z

    The effects of cold-rolling on thermal, mechanical and electrical properties, microstructure and recrystallization behaviour of the AlScZr and AlMnScZr alloys prepared by powder metallurgy were studied. The powder was produced by atomising in argon with 1% oxygen and then consolidated by hot extrusion at 350 °C. The electrical resistometry and microhardness together with differential scanning calorimetry measurements were compared with microstructure development observed by transmission and scanning electron microscopy, X-ray diffraction and electron backscatter diffraction. Fine (sub)grain structure developed and fine coherent Al{sub 3}Sc and/or Al{sub 3}(Sc,Zr) particles precipitated during extrusion at 350 °C in the alloys studied. Additional precipitation of the Al{sub 3}Sc and/or Al{sub 3}(Sc,Zr) particles and/or their coarsening was slightly facilitated by the previous cold rolling. The presence of Sc,Zr-containing particles has a significant antirecrystallization effect that prevents recrystallization at temperatures minimally up to 420 °C. The precipitation of the Al{sub 6}Mn- and/or Al{sub 6}(Mn,Fe) particles of a size ? 1.0 ?m at subgrain boundaries has also an essential antirecrystallization effect and totally suppresses recrystallization during 32 h long annealing at 550 °C. The texture development of the alloys seems to be affected by high solid solution strengthening by Mn. The precipitation of the Mn-containing alloy is highly enhanced by a cold rolling. The apparent activation energy of the Al{sub 3}Sc particles formation and/or coarsening and that of the Al{sub 6}Mn and/or Al{sub 6}(Mn,Fe) particle precipitation in the powder and in the compacted alloys were determined. The cold deformation has no effect on the apparent activation energy values of the Al{sub 3}Sc-phase and the Al{sub 6}Mn-phase precipitation. - Highlights: • The Mn, Sc and Zr additions to Al totally suppresses recrystallization at 550 °C. • The Sc,Zr-containing particle precipitation is slightly facilitated by cold rolling. • The Mn-containing particle precipitation is highly enhanced by cold rolling. • Cold rolling has no effect on activation energy of the Al{sub 3}Sc and Al{sub 6}Mn precipitation. • The texture development is affected by high solid solution strengthening by Mn.

  19. A Single Layer of Mn in a GaAs Quantum Well: A Ferromagnet with Quantum Fluctuations

    SciTech Connect (OSTI)

    Melko, Roger G [ORNL; Fishman, Randy Scott [ORNL; Reboredo, Fernando A [ORNL

    2007-01-01T23:59:59.000Z

    Some of the highest transition temperatures achieved for Mn-doped GaAs have been in &-doped heterostructures with well-separated planes of Mn. But in the absense of magnetic anisotropy, the Mermin-Wagner theorem implies that a single plane of magnetic ions cannot be ferromagnetic. We show that the same mechanism that produces magnetic frustration and suppresses the transition can stabilize ferromagnetic order for a single layer of Mn in a GaAs quantum well. But this comes at the price of quantum fluctuations that suppress the ordered moment from that of a fully saturated ferromagnet.

  20. Penetration depth and absorption mechanisms of spin currents in Ir{sub 20}Mn{sub 80} and Fe{sub 50}Mn{sub 50} polycrystalline films by ferromagnetic resonance and spin pumping

    SciTech Connect (OSTI)

    Merodio, P.; Ghosh, A.; Lemonias, C.; Gautier, E.; Ebels, U.; Chshiev, M.; Béa, H., E-mail: vincent.baltz@cea.fr, E-mail: helene.bea@cea.fr; Baltz, V., E-mail: vincent.baltz@cea.fr, E-mail: helene.bea@cea.fr [SPINTEC, UMR 8191 CNRS/INAC-CEA/UJF-Grenoble 1/Grenoble-INP, F-38054 Cedex (France); Bailey, W. E., E-mail: web54@columbia.edu [Mat. Sci. and Engn. Program, Department of Appl. Phys. and Appl. Math., Columbia University, New York, New York 10027 (United States)

    2014-01-20T23:59:59.000Z

    Spintronics relies on the spin dependent transport properties of ferromagnets (Fs). Although antiferromagnets (AFs) are used for their magnetic properties only, some fundamental F-spintronics phenomena like spin transfer torque, domain wall motion, and tunnel anisotropic magnetoresistance also occur with AFs, thus making AF-spintronics attractive. Here, room temperature critical depths and absorption mechanisms of spin currents in Ir{sub 20}Mn{sub 80} and Fe{sub 50}Mn{sub 50} are determined by F-resonance and spin pumping. In particular, we find room temperature critical depths originating from different absorption mechanisms: dephasing for Ir{sub 20}Mn{sub 80} and spin flipping for Fe{sub 50}Mn{sub 50}.

  1. Mn concentration dependent structural and optical properties of a-plane Zn{sub 0.99-x}Mn{sub x}Na{sub 0.01}O

    SciTech Connect (OSTI)

    Lu, B., E-mail: binlu@zju.edu.cn; Zhou, T. T.; Ma, M. J.; Ye, Y. H.; Ye, Z. Z.; Lu, J. G.; Pan, X. H. [State Key Laboratory of Silicon Materials, Cyrus Tang Center for Sensor Materials and Applications, Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027 (China)

    2013-12-14T23:59:59.000Z

    Non-polar a-plane (112{sup ¯}0) Zn{sub 0.99?x}Mn{sub x}Na{sub 0.01}O (x?=?0, 0.02, 0.03, 0.04, and 0.05) thin films have been prepared on r-plane (112{sup ¯}0) sapphire substrates by pulsed laser deposition (PLD). The influences of Mn content on the structural and optical properties of the films have been studied. It is indicated that moderate Mn doping facilitates the non-polar growth of ZnO, and all the doped films are single phase with a hexagonal wurtzite structure. The transmittance spectra suggested that all films are transparent in the visible region exhibiting a transmittance above 80%. Mn{sup 2+} doped Zn{sub 0.99}Na{sub 0.01}O shows an initial decrease of optical band gap (OBG) for small concentration of Mn, followed by a monotonic increase. The anomalous decrease in OBG for low concentrations of Mn is attributed to the strong exchange interaction present between the sp electrons of the host matrix and d electrons of Mn. Emission studies were also performed showing suppressed blue-shifted ultraviolet band and dominant violet-blue bands, which might originate from the zinc vacancy (V{sub Zn}) and zinc interstitial (Zn{sub i}) defects. The intensity of defect-related emission peaks is Mn doping-level-dependent as well and the results coincide well with that from the structural analyses.

  2. The Sun -II Alexei Gilchrist

    E-Print Network [OSTI]

    Wardle, Mark

    The Sun - II Alexei Gilchrist #12;Some resources · http://www.nineplanets.org/sol.html · "The Universe: Secrets of the Sun" video ­ Search on youtube (references are to clips here http in these slides Secrets of the Sun #12;Why does the sun shine? Long and fascinating history involving - geology

  3. Robotics II June 10, 2014

    E-Print Network [OSTI]

    De Luca, Alessandro

    Robotics II June 10, 2014 Exercise 1 Consider a planar 3R robot with unitary link lengths as in Fig. 1. Taking into account the robot redundancy, a velocity control scheme is active so as to track desired end-effector position trajectories while trying to locally maximize the minimum Cartesian distance

  4. Evidence That the [beta] Subunit of Chlamydia trachomatis Ribonucleotide Reductase Is Active with the Manganese Ion of Its Manganese(IV)/Iron(III) Cofactor in Site 1

    SciTech Connect (OSTI)

    Dassama, Laura M.K.; Boal, Amie K.; Krebs, Carsten; Rosenzweig, Amy C.; Bollinger, Jr., J. Martin (NWU); (Penn)

    2014-10-02T23:59:59.000Z

    The reaction of a class I ribonucleotide reductase (RNR) begins when a cofactor in the {beta} subunit oxidizes a cysteine residue {approx}35 {angstrom} away in the {alpha} subunit, generating a thiyl radical. In the class Ic enzyme from Chlamydia trachomatis (Ct), the cysteine oxidant is the Mn{sup IV} ion of a Mn{sup IV}/Fe{sup III} cluster, which assembles in a reaction between O{sub 2} and the Mn{sup II}/Fe{sup II} complex of {beta}. The heterodinuclear nature of the cofactor raises the question of which site, 1 or 2, contains the Mn{sup IV} ion. Because site 1 is closer to the conserved location of the cysteine-oxidizing tyrosyl radical of class Ia and Ib RNRs, we suggested that the Mn{sup IV} ion most likely resides in this site (i.e., {sup 1}Mn{sup IV}/{sup 2}Fe{sup III}), but a subsequent computational study favored its occupation of site 2 ({sup 1}Fe{sup III}/{sup 2}Mn{sup IV}). In this work, we have sought to resolve the location of the Mn{sup IV} ion in Ct RNR-{beta} by correlating X-ray crystallographic anomalous scattering intensities with catalytic activity for samples of the protein reconstituted in vitro by two different procedures. In samples containing primarily Mn{sup IV}/Fe{sup III} clusters, Mn preferentially occupies site 1, but some anomalous scattering from site 2 is observed, implying that both {sup 1}Mn{sup II}/{sup 2}Fe{sup II} and {sup 1}Fe{sup II}/{sup 2}Mn{sup II} complexes are competent to react with O{sub 2} to produce the corresponding oxidized states. However, with diminished Mn{sup II} loading in the reconstitution, there is no evidence for Mn occupancy of site 2, and the greater activity of these 'low-Mn' samples on a per-Mn basis implies that the {sup 1}Mn{sup IV}/{sup 2}Fe{sup III}-{beta} is at least the more active of the two oxidized forms and may be the only active form.

  5. Nmr Study of Thiocarbonyl Derivatives of Fe and Mn were made with solutions of the tungsten and molybdenum species

    E-Print Network [OSTI]

    Bodner, George M.

    Nmr Study of Thiocarbonyl Derivatives of Fe and Mn were made with solutions of the tungsten.g.. the tungsten ion readily oxidizes in aqueous acid [A. Samotus and B. Kosowicz-Czajkowska, Rocz. Chem., 45, 1623

  6. Heat capacity of the site-diluted spin dimer system Ba?(Mn1-xVx)?O?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Samulon, E. C.; Shapiro, M. C.; Fisher, I. R.

    2011-08-01T23:59:59.000Z

    Heat-capacity and susceptibility measurements have been performed on the diluted spin dimer compound Ba?(Mn1-xVx)?O?. The parent compound Ba?Mn?O? is a spin dimer system based on pairs of antiferromagnetically coupled S=1, 3d² Mn?? ions such that the zero-field ground state is a product of singlets. Substitution of nonmagnetic S=0, 3d? V?? ions leads to an interacting network of unpaired Mn moments, the low-temperature properties of which are explored in the limit of small concentrations 0?x?0.05. The zero-field heat capacity of this diluted system reveals a progressive removal of magnetic entropy over an extended range of temperatures, with no evidence for a phase transition. The concentration dependence does not conform to expectations for a spin-glass state. Rather, the data suggest a low-temperature random singlet phase, reflecting the hierarchy of exchange energies found in this system.

  7. Electronic Structure of a Paramagnetic {MNO}[superscript 6] Complex: MnNO 5,5-Tropocoronand

    E-Print Network [OSTI]

    Tangen, Espen

    Using density functional theory (OLYP/STO-TZP) calculations, we have investigated the electronic structure of [Mn(5,5-tropocoronand)(NO)], a rare paramagnetic {MNO}6 complex. Experimental methods, including magnetic ...

  8. PARS II Process Document - Project Phasing | Department of Energy

    Energy Savers [EERE]

    PARS II Process Document - Project Phasing.pdf More Documents & Publications Proposed Data Elements for PARS II Web Application Slide 1 PARS II Standard Operating Procedure (SOP)...

  9. Proposed Data Elements for PARS II Web Application | Department...

    Broader source: Energy.gov (indexed) [DOE]

    Proposed Data Elements for PARS II Web Application Proposed Data Elements for PARS II Web Application Proposed Data Elements for PARS II Web Application More Documents &...

  10. PARS II - Integrated Project Team Meeting | Department of Energy

    Energy Savers [EERE]

    Meeting PARS II - Integrated Project Team Meeting More Documents & Publications PARS II 104 Contractor Monthly Upload Proposed Data Elements for PARS II Web Application Slide 1...

  11. Prediction of O2 Dissociation Kinetics on LaMnO3-Based Cathode Materials for Solid Oxide Fuel Cells

    SciTech Connect (OSTI)

    Choi, Yongman; Lynch, Matthew E.; Lin, M. C.; Liu, Meilin

    2009-04-30T23:59:59.000Z

    First-principles and statistical-theory calculations were applied to examine the interactions between oxygen molecules and the (100) surfaces of LaMnO3 and La0.5Sr0.5MnO2.75, one of the most-used cathode materials in solid oxide fuel cells (SOFCs). To predict the rate constants for the interactions between O2 and LaMnO3 or La0.5Sr0.5MnO2.75, potential energy profiles were constructed using the nudged elastic band (NEB) method. Predicted rate constants for the dissociation of adsorbed oxygen species on LaMnO3 (lm) and La0.5Sr0.5MnO2.75 (lsm) can be expressed as kdiss,lm ) 2.35 × 1012 exp(-0.50 eV/RT) s-1 and kdiss,lsm ) 2.15 × 1012 exp(-0.23 eV/RT) s-1, respectively, in the temperature range of 873-1273 K at 1 atm. Because the activation energy for oxygen dissociation on La0.5Sr0.5MnO2.75 (0.23 eV) is much smaller than that on LaMnO3 (0.50 eV), oxygen vacancies greatly enhance O2 dissociation kinetics. The kinetic and mechanistic studies for the interactions at the molecular level are imperative to gaining a fundamental understanding of oxygen reduction kinetics on cathode materials and to providing important insight into the rational design of more catalytically active cathode materials for SOFCs.

  12. Magnetocaloric and magnetoresistive properties of La0.67Ca0.33-xSrxMnO3

    E-Print Network [OSTI]

    Risø-PhD-5 Magnetocaloric and magnetoresistive properties of La0.67Ca0.33-xSrxMnO3 Anders Reves: Magnetocaloric and magnetoresistive properties of La0.67Ca0.33-xSrxMnO3 Department: Materials Research Department of magneto- caloric and magnetoresistive properties of a series of polycrystalline Ca- and Sr- doped

  13. Coulomb interaction of acceptors in Cd{sub 1?x}Mn{sub x}Te/CdTe quantum dot

    SciTech Connect (OSTI)

    Kalpana, P.; Nithiananthi, P., E-mail: kjkumar-gri@rediffmail.com; Jayakumar, K., E-mail: kjkumar-gri@rediffmail.com [Department of Physics, Gandhigram Rural University, Gandhigram-624302, TamilNadu (India); Reuben, A. Merwyn Jasper D. [Department of Physics, School of Engineering, Saveetha University, Thandalam, Chennai- 600104, TamilNadu (India)

    2014-04-24T23:59:59.000Z

    The investigation on the effect of confining potential like isotropic harmonic oscillator type potential on the binding and the Coulomb interaction energy of the double acceptors in the presence of magnetic field in a Cd{sub 1?x}Mn{sub x}Te/CdTe Spherical Quantum Dot has been made for the Mn ion composition x=0.3 and compared with the results obtained from the square well type potential using variational procedure in the effective mass approximation.

  14. Predominant Occupation of the Class I MHC Molecule H-2Kwm7 with a Single Self-peptide Suggests a Mechanism for its Diabetes-protective Effect

    SciTech Connect (OSTI)

    Brims, D.; Qian, J; Jarchum, I; Mikesh, L; Palmieri, E; Ramagopal, U; Malashkevich, V; Chaparro, R; Lund, T; et. al.

    2010-01-01T23:59:59.000Z

    Type 1 diabetes (T1D) is an autoimmune disease characterized by T cell-mediated destruction of insulin-producing pancreatic {beta} cells. In both humans and the non-obese diabetic (NOD) mouse model of T1D, class II MHC alleles are the primary determinant of disease susceptibility. However, class I MHC genes also influence risk. These findings are consistent with the requirement for both CD{sup 4+} and CD{sup 8+} T cells in the pathogenesis of T1D. Although a large body of work has permitted the identification of multiple mechanisms to explain the diabetes-protective effect of particular class II MHC alleles, studies examining the protective influence of class I alleles are lacking. Here, we explored this question by performing biochemical and structural analyses of the murine class I MHC molecule H-2K{sup wm7}, which exerts a diabetes-protective effect in NOD mice. We have found that H-2K{sup wm7} molecules are predominantly occupied by the single self-peptide VNDIFERI, derived from the ubiquitous protein histone H2B. This unexpected finding suggests that the inability of H-2K{sup wm7} to support T1D development could be due, at least in part, to the failure of peptides from critical {beta}-cell antigens to adequately compete for binding and be presented to T cells. Predominant presentation of a single peptide would also be expected to influence T-cell selection, potentially leading to a reduced ability to select a diabetogenic CD{sup 8+} T-cell repertoire. The report that one of the predominant peptides bound by T1D-protective HLA-A*31 is histone derived suggests the potential translation of our findings to human diabetes-protective class I MHC molecules.

  15. Characterization of Al-Mn particles in AZ91D investment castings

    SciTech Connect (OSTI)

    Lun Sin, S. [Department of Mining, Metallurgical and Materials Engineering, Laval University, Quebec, Quebec, G1K 7P4 (Canada); Dube, D. [Department of Mining, Metallurgical and Materials Engineering, Laval University, Quebec, Quebec, G1K 7P4 (Canada)], E-mail: dominique.dube@gmn.ulaval.ca; Tremblay, R. [Department of Mining, Metallurgical and Materials Engineering, Laval University, Quebec, Quebec, G1K 7P4 (Canada)

    2007-10-15T23:59:59.000Z

    Manganese is currently added to Mg-Al alloys in order to improve the corrosion behavior of cast components. A part of this manganese is dissolved in the magnesium matrix and the balance is found as fine Al(Mn,Fe) particles dispersed within castings. For AZ91D specimens prepared using the plaster mould investment casting process, these particles were observed in very large quantity at the surface of castings. These particles were characterized by scanning electron microscopy and electron probe microanalysis. It was found that they consist of Al{sub 8}Mn{sub 5} phase and that their morphology and size depend on local solidification conditions. Their presence at the surface of the castings is related to low solidification rates and reduced thermal gradients at the mould/metal interface.

  16. Preparation and Magnetic Properties of MnBi-based Hard/Soft Composite Magnets

    SciTech Connect (OSTI)

    Ma, Yilong; Liu, Xubo; Gandha, Kinjal; Vuong, Nguyen V.; Yang, Y. B.; Yang, Jinbo; Poudyal, Narayan; Cui, Jun; Liu, J.Ping

    2014-05-07T23:59:59.000Z

    Bulk anisotropic composite magnets based on MnBi/Co(Fe) exhibiting the different morphology of the soft magnetic phase were prepared by powder metallurgy processing. First, single-phase MnBi bulk magnets were produced using a maximum energy product [(BH)m] of 6.3 MGOe at room temperature. The nanoscale soft phase with the different morphology was then added to form a composite magnet. It was observed that addition of magnetic soft-phase nanoparticles and nanoflakes causes a dramatic coercivity reduction. However, the addition of soft magnetic phase nanowires enhanced the composite magnetization without sacrificing the coercivity. Nevertheless, a kink was still observed on the demagnetization curves and the coercivity decreased when the soft-phase content was larger than 10 wt. %, which was caused by the agglomeration of the soft phase nanowires that also led to a decreased degree of texture.

  17. Low temperature magnetic properties of magnesium substituted YbMnO{sub 3}

    SciTech Connect (OSTI)

    Sattibabu, Bhumireddi, E-mail: bsb.satti@gmail.com; Bhatnagar, Anil K., E-mail: bsb.satti@gmail.com; Mohan, Dasari, E-mail: bsb.satti@gmail.com; Das, Dibakar, E-mail: bsb.satti@gmail.com; Sundararaman, Mahadevan, E-mail: bsb.satti@gmail.com [School of Engineering Sciences and Technology, University of Hyderabad, Hyderabad-500046 (India); Siruguri, Vasudeva; Rayaprol, Sudhindra [UGC-DAE Consortium for Scientific Research, Mumbai Centre, R-5 Shed, Bhabha Atomic Research Centre, Mumbai-400085 (India)

    2014-04-24T23:59:59.000Z

    Structural and magnetic properties of polycrystalline Yb{sub 1?x}Mg{sub x}MnO{sub 3} (x = 0, 0.05 and 0.10) hexagonal compounds prepared by solid state method, have been studied. The structural analyses of the samples were carried out by Rietveld analysis of neutron diffraction data. With increasing Mg content, we find that the lattice parameter a decreases and c increases whereas the overall Mn-O bond length decreases. Magnetization measured as a function of magnetic field at 2.5 K exhibits hysteresis, which is attributed to ferromagnetic like ordering of Yb{sup 3+} sublattice. Temperature dependence of ac magnetic susceptibility, ?{sub ac}(T), shows no signature of spin-glass behavior. ?”(T) exhibits a sudden increase at low temperatures which is due to ordering of Yb{sup 3+} sublattice.

  18. Abundance analysis of SB2 binary stars with HgMn primaries

    E-Print Network [OSTI]

    T. Ryabchikova

    1998-05-06T23:59:59.000Z

    We present a short review of the abundances in the atmospheres of SB2 systems with Mercury-Manganese (HgMn) primaries. Up to now a careful study has been made for both components of 8 out of 17 known SB2 binaries with orbital periods shorter than 100 days and mass ratio ranging from 1.08 to 2.2. For all eight systems we observe a lower Mn abundance in the secondary's atmospheres than in the primary's. Significant difference in the abundances is also found for some peculiar elements such as Ga, Xe, Pt. All secondary stars with effective temperatures less than 10000 K show abundance characteristics typical of the metallic-line stars.

  19. Magneto-optical spectroscopy of ferromagnetic shape-memory Ni-Mn-Ga alloy

    SciTech Connect (OSTI)

    Veis, M., E-mail: veis@karlov.mff.cuni.cz; Beran, L.; Zahradnik, M.; Antos, R. [Faculty of Mathematics and Physics, Charles University in Prague, Ke Karlovu 5, 12116 Prague (Czech Republic); Straka, L. [Aalto University School of Engineering, PL14200, FIN-00076 Aalto (Finland); Kopecek, J.; Fekete, L.; Heczko, O. [Institute of Physics, ASCR, Na Slovance 2, 182 21 Prague (Czech Republic)

    2014-05-07T23:59:59.000Z

    Magneto-optical properties of single crystal of Ni{sub 50.1}Mn{sub 28.4}Ga{sub 21.5} magnetic shape memory alloy in martensite and austenite phase were systematically studied. Crystal orientation was approximately along (100) planes of parent cubic austenite. At room temperature, the sample was in modulated 10M martensite phase and transformed to cubic austenite at 323?K. Spectral dependence of polar magneto-optical Kerr effect was obtained by generalized magneto-optical ellipsometry with rotating analyzer in the photon energy range from 1.2 to 4?eV, and from room temperature to temperature above the Curie point. The Kerr rotation spectra exhibit prominent features typical for complexes containing Mn atoms. Significant spectral changes during transformation to austenite can be explained by different optical properties caused by changes in density of states near the Fermi energy.

  20. High capacitive performance of nanostructured Mn-Ni-Co oxide composites for supercapacitor

    SciTech Connect (OSTI)

    Luo Jianmin [Institute of Applied Chemistry, Xinjiang University, Urumqi 830046 (China); Gao Bo [College of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016 (China); Zhang Xiaogang [College of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016 (China)], E-mail: azhangxg@163.com

    2008-05-06T23:59:59.000Z

    Nanostructured Mn-Ni-Co oxide composites (MNCO) were prepared by thermal decomposition of the precursor obtained by chemical co-precipitation of Mn, Ni and Co salts. The chemical composition and morphology were characterized by X-ray diffraction (XRD), energy dispersive spectroscopy (EDS) and scanning electron microscopy (SEM). The electrochemical capacitance of MNCO electrode was examined by cyclic voltammetry, impedance and galvanostatic charge-discharge measurements. The results showed that MNCO electrode exhibited the good electrochemical characteristics. A maximum capacitance value of 1260 F g{sup -1} could be obtained within the potential range of -0.1 to 0.4 V versus saturated calomel electrode (SCE) in 6 mol L{sup -1} KOH electrolyte.

  1. Optical transitions in MnGa{sub 2}Se{sub 4}

    SciTech Connect (OSTI)

    Tagiev, B. G.; Kerimova, T. G., E-mail: ktaira@physics.ab.az; Tagiev, O. B.; Asadullayeva, S. G.; Mamedova, I. A. [National Academy of Sciences of Azerbaijan, Institute of Physics (Azerbaijan)

    2012-06-15T23:59:59.000Z

    The dependence of the absorption coefficient on incident photon energy in a MnGa{sub 2}Se{sub 4} single crystal has been investigated in the temperature range 110-295 K. Using group-theory analysis of the electron state symmetry and comparison of the symmetry of the energy spectrum of MnGa{sub 2}Se{sub 4} and its isoelectronic analogs, a conclusion about the character of optical transitions has been drawn. It is shown that the features observed at 2.31 and 2.45 eV are related to the intracenter transitions {sup 6}A{sub 1}{sup 1} {yields} {sup 4}T{sub 2}({sup 4}G) and {sup 6}A{sub 1}{sup 2} {yields} {sup 4}T{sub 2}({sup 4}G). The {sup 6}A{sub 1} state is split by the crystal field.

  2. Part II: Project Summaries Project Summaries

    E-Print Network [OSTI]

    Perkins, Richard A.

    Part II: Project Summaries Part II Project Summaries #12 generally cannot be achieved for reasonable computational cost. Applications that require modeling, and in nondestructive testing. The objective of this project is to advance the state of the art in electromagnetic

  3. PARS II Training Schedule | Department of Energy

    Office of Environmental Management (EM)

    will certify that user to receive a PARS II user account. PARSIITrainingSchedule03-06-2014.pdf More Documents & Publications Slide 1 Slide 1 PARS II Course Registration Form...

  4. Swift Progress on NSLS-II Booster

    ScienceCinema (OSTI)

    None

    2013-07-17T23:59:59.000Z

    Get an inside look around the booster ring at the National Synchrotron Light Source II. The booster is part of the injector complex for NSLS-II, now under construction at Brookhaven Lab.

  5. Thermoelectric study of crossroads material MnTe via sulfur doping

    SciTech Connect (OSTI)

    Xie, Wenjie, E-mail: xie@imw.uni-stuttgart.de; Populoh, Sascha; Sagarna, Leyre; Trottmann, Matthias [Empa–Swiss Federal Laboratories for Materials Science and Technology, Solid State Chemistry and Catalysis, Uberlandstrasse 129, CH-8600 Dübendorf (Switzerland); Ga??zka, Krzysztof [Empa–Swiss Federal Laboratories for Materials Science and Technology, Solid State Chemistry and Catalysis, Uberlandstrasse 129, CH-8600 Dübendorf (Switzerland); Department of Chemistry and Biochemistry, University of Bern, Freiestrasse 3, CH-3012 Bern (Switzerland); Xiao, Xingxing [Institute for Materials Science, University of Stuttgart, DE-70569 Stuttgart (Germany); Liu, Yufei; He, Jian [Department of Physics and Astronomy, Clemson University, Clemson, South Carolina 29634-0978 (United States); Weidenkaff, Anke [Empa–Swiss Federal Laboratories for Materials Science and Technology, Solid State Chemistry and Catalysis, Uberlandstrasse 129, CH-8600 Dübendorf (Switzerland); Institute for Materials Science, University of Stuttgart, DE-70569 Stuttgart (Germany)

    2014-03-14T23:59:59.000Z

    Here, we report thermoelectric study of crossroads material MnTe via iso-electronic doping S on the Te-site. MnTe{sub 1-x}S{sub x} samples with nominal S content of x?=?0.00, 0.05, and 0.10 were prepared using a melt-quench method followed by pulverization and spark plasma sintering. The X-ray powder diffraction, scanning electron microscopy, and ZAF-corrected compositional analysis confirmed that S uniformly substitutes Te up to slightly over 2%. A higher content of S in the starting materials led to the formation of secondary phases. The thermoelectric properties of MnTe{sub 1-x}S{sub x} samples were characterized by means of Seebeck coefficient, electrical conductivity, and thermal conductivity measurements from 300?K to 773?K. Furthermore, Hall coefficient measurements and a single parabolic band model were used to help gain insights on the effects of S-doping on the scattering mechanism and the carrier effective mass. As expected, S doping not only introduced hole charge carriers but also created short-range defects that effectively scatter heat-carrying phonons at elevated temperatures. On the other hand, we found that S doping degraded the effective mass. As a result, the ZT of MnTe{sub 0.9}S{sub 0.1} was substantially enhanced over the pristine sample near 400?K, while the improvement of ZT became marginal at elevated temperatures. A ZT???0.65 at 773?K was obtained in all three samples.

  6. Preparation and characterization of nanostructured NiO/MnO{sub 2} composite electrode for electrochemical supercapacitors

    SciTech Connect (OSTI)

    Liu Enhui [College of Chemistry, Xiangtan University, Hunan 411105 (China)], E-mail: liuenhui99@sina.com.cn; Li Wen; Li Jian; Meng Xiangyun; Ding Rui; Tan Songting [College of Chemistry, Xiangtan University, Hunan 411105 (China)

    2009-05-06T23:59:59.000Z

    Nanostructured nickel-manganese oxides composite was prepared by the sol-gel and the chemistry deposition combination new route. The surface morphology and structure of the composite were characterized by scanning electron microscope and X-ray diffraction. The as-synthesized NiO/MnO{sub 2} samples exhibit higher surface area of 130-190 m{sup 2} g{sup -1}. Cyclic voltammetry and galvanostatic charge/discharge measurements were applied to investigate the electrochemical performance of the composite electrodes with different ratios of NiO/MnO{sub 2}. When the mass ratio of MnO{sub 2} and NiO in composite material is 80:20, the specific capacitance value of NiO/MnO{sub 2} calculated from the cyclic voltammetry curves is 453 F g{sup -1}, for pure NiO and MnO{sub 2} are 209, 330 F g{sup -1} in 6 mol L{sup -1} KOH electrolyte and at scan rate of 10 mV s{sup -1}, respectively. The specific capacitance of NiO/MnO{sub 2} electrode is much larger than that of each pristine component. Moreover, the composite electrodes showed high power density and stable electrochemical properties.

  7. Construction of the Magnetic Phase Diagram of FeMn/Ni/Cu(001) Using Photoemission Electron Microscopy

    SciTech Connect (OSTI)

    Wu, J.; Scholl, A.; Arenholz, E.; Hwang, C.; Qiu, Z. Q.

    2011-01-04T23:59:59.000Z

    Single crystalline FeMn/Ni bilayer was epitaxially grown on Cu(001) substrate and investigated by photoemission electron microscopy (PEEM). The FeMn and Ni films were grown into two cross wedges to facilitate an independent control of the FeMn (0-20 ML) and Ni (0-20 ML) film thicknesses. The Ni magnetic phases were determined by Ni domain images as a function of the Ni thickness (d{sub Ni}) and the FeMn thickness (d{sub FeMn}). The result shows that as the Ni thickness increases, the Ni film undergoes a paramagnetic-to-ferromagnetic state transition at a critical thickness of d{sub FM} and an in-plane to out-of-plane spin reorientation transition at a thicker thickness d{sub SRT}. The phase diagram shows that both d{sub FM} and d{sub SRT} increase as the FeMn film establishes its antiferromagnetic order.

  8. Cross Section Evaluation Group shielding benchmark compilation. Volume II

    SciTech Connect (OSTI)

    Rose, P.F.; Roussin, R.W.

    1983-12-01T23:59:59.000Z

    At the time of the release of ENDF/B-IV in 1974, the Shielding Subcommittee had identified a series of 12 shielding data testing benchmarks (the SDT series). Most were used in the ENDF/B-IV data testing effort. A new concept and series was begun in the interim, the so-called Shielding Benchmark (SB) series. An effort was made to upgrade the SDT series as far as possible and to add new SB benchmarks. In order to be designated in the SB class, both an experiment and analysis must have been performed. The current recommended benchmark for Shielding Data Testing are listed. Until recently, the philosophy has been to include only citations to published references for shielding benchmarks. It is now our intention to provide adequate information in this volume for proper analysis of any new benchmarks added to the collection. These compilations appear in Section II, with the SB5 Fusion Reactor Shielding Benchmark as the first entry.

  9. Sloan Digital Sky Survey II (SDSS-II) Supernova Data

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The Sloan Digital Sky Survey (SDSS) is a series of three interlocking imaging and spectroscopic surveys, carried out over an eight-year period with a dedicated 2.5m telescope located at Apache Point Observatory in Southern New Mexico. The SDSS Supernova Survey was one of those three components of SDSS and SDSS-II, a 3-year extension of the original SDSS that operated from July 2005 to July 2008. The Supernova Survey was a time-domain survey, involving repeat imaging of the same region of sky every other night, weather permitting. The primary scientific motivation was to detect and measure light curves for several hundred supernovae through repeat scans of the SDSS Southern equatorial stripe 82 (about 2.5? wide by ~120? long). Over the course of three 3-month campaigns SDSS-II SN discovered and measured multi-band lightcurves for ~500 spectroscopically confirmed Type Ia supernovae in the redshift range z=0.05-0.4. In addition, the project harvested a few hundred light curves for SNe Ia and discovered about 80 spectroscopically confirmed core-collapse supernovae (supernova types Ib/c and II).

  10. Ti (II) Mediated Reactions in Organic Chemistry

    E-Print Network [OSTI]

    Johnson, Jeff S.

    ' #12;Generation of Ti(II) from Ti(IV) · Bercaw accessed and characterized the first Ti'X -X Generation of Ti(II) via Reductive Alkylation · Ti(IV) converted to Ti(II) via reductive/Acetylene Functionalizations · Reductive Couplings #12;Advantages of Titanium · Titanium (IV) reagents are cheap and readily

  11. I I I I II I I I II I I I II I I I II I I I II I I I II I I I II I I I II I I I II I I I IIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIII

    E-Print Network [OSTI]

    Laboratory during 1996. The department is undertaking research within Simulation and Optimisation of Energy I II I I I II I I I II I I I I I CONTENTS 4 Introduction 6 Simulation and Optimisation of Energy Related to Power Production 16 Energy and Environment in Developing Countries 16 UNEP Support Activities

  12. Why MnIn{sub 2}O{sub 4} spinel is not a transparent conducting oxide?

    SciTech Connect (OSTI)

    Martinez-Lope, M.J. [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco E-28049 Madrid (Spain); Retuerto, M. [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco E-28049 Madrid (Spain); Department of Chemistry, Rutgers State University of New Jersey, Piscataway, NJ 08854-8087 (United States); Calle, C. de la [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco E-28049 Madrid (Spain); Porcher, Florence [Laboratoire Leon Brillouin, CEA/Saclay, 91191 Gif Sur Ivette Cedex, France. (France); Alonso, J.A., E-mail: ja.alonso@icmm.csic.es [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco E-28049 Madrid (Spain)

    2012-03-15T23:59:59.000Z

    The title compound has been synthesized by a citrate technique. The crystal structure has been investigated at room temperature from high-resolution neutron powder diffraction (NPD) data. It crystallizes in a cubic spinel structure, space group Fd3-bar m, Z=8, with a=9.0008(1) A at 295 K. It exhibits a crystallographic formula (Mn{sub 0.924(2)}In{sub 0.076(2)}){sub 8a}(In{sub 1.804(2)}Mn{sub 0.196(2)}){sub 16d}O{sub 4}, where 8a and 16d stand for the tetrahedral and octahedral sites of the spinel structure, respectively, with a slight degree of inversion, {lambda}=0.08. MnIn{sub 2}O{sub 4} shows antiferromagnetic interactions below T{sub N} Almost-Equal-To 40 K, due to the statistical distribution of Mn ions over the two available sites. Unlike the related MgIn{sub 2}O{sub 4} and CdIn{sub 2}O{sub 4} spinels, well known as transparent conducting oxides, MnIn{sub 2}O{sub 4} is not transparent and shows a poor conductivity ({sigma}=0.38 S cm{sup -1} at 1123 K): the presence of Mn ions, able to adopt mixed valence states, localizes the charges that, otherwise, would be delocalized in the spinel conduction band. - Graphical Abstract: From NPD data the crystallographic formula (Mn{sub 0.924(2)}In{sub 0.076(2)}){sub 8a}(In{sub 1.804(2)}Mn{sub 0.196(2)}){sub 16d}O{sub 4}, shows a slight degree of inversion, {lambda}=0.08 and a certain In deficiency. The presence of Mn ions, able to adopt mixed oxidation states, localize the charges that, otherwise, would be delocalized in the spinel conduction band; the presence of localized Mn{sup 2+} and Mn{sup 3+} ions provides the characteristic brown color. Highlights: Black-Right-Pointing-Pointer Accurate structural determination from NPD data: inversion degree (8%), and In deficiency. Black-Right-Pointing-Pointer Bond-valence indicates Mn{sup 2+}-Mn{sup 3+} ions; edge-sharing octahedra contain 90% In{sup 3+}+10% Mn{sup 3+} cations. Black-Right-Pointing-Pointer Conductivity several orders of magnitude lower than those of MgIn{sub 2}O{sub 4} or CdIn{sub 2}O{sub 4}. Black-Right-Pointing-Pointer Variability of Mn oxidation states cancels any electron-doping effect, emptying conduction band of mobile charge carriers. Black-Right-Pointing-Pointer Curie-Weiss behavior confirming the determined charge distribution.

  13. Codings of separable compact subsets of the first Baire class

    E-Print Network [OSTI]

    Dodos, Pandelis

    2008-01-01T23:59:59.000Z

    Let $X$ be a Polish space and $K$ a separable compact subset of the first Baire class on $X$. For every sequence $\\bs$ dense in $\\kk$, the descriptive set-theoretic properties of the set \\[ \\lbf=\\{L\\in[\

  14. TH.D. STUDENT PROFILES 2006 Entering Class

    E-Print Network [OSTI]

    Reif, John H.

    TH.D. STUDENT PROFILES 2006 Entering Class Jeff Conklin-Miller Primary Concentration: Theology ecclesiology, drawing on insights of John Howard Yoder, Rowan Williams, and the Wesleyan tradition. Tommy

  15. A Single-Product Inventory Model for Multiple Demand Classes

    E-Print Network [OSTI]

    Arslan, Hasan

    2005-05-27T23:59:59.000Z

    We consider a single-product inventory system that serves multiple demand classes, which differ in their shortage costs or service level requirements. We assume a critical-level control policy, and show the equivalence ...

  16. Applied Health Sciences May 6, 2010 Class of 2010

    E-Print Network [OSTI]

    Illinois at Chicago, University of

    Applied Health Sciences May 6, 2010 Class of 2010 PRESIDING . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Charlotte A. Tate PRESENTATION OF DEGREE CANDIDATES (see list on page 12) Biomedical and Health Information in · Biomedical Visualization · Health Informatics · Health Information Management Disability and Human

  17. Computing the Grothendieck constant of some graph classes

    E-Print Network [OSTI]

    Monique Laurent

    2011-06-10T23:59:59.000Z

    Jun 10, 2011 ... However this is not the case for the clique-web inequalities, a wide class of valid inequalities for the cut polytope, whose integrality ratio is ...

  18. STATEMENT OF CONSIDERATIONS Advance Test Reactor Class Waiver

    Broader source: Energy.gov (indexed) [DOE]

    Advance Test Reactor Class Waiver W(C)-2008-004 The Advanced Test Reactor (A TR) is a pressurized water test reactor at the Idaho National Laboratory (INL) that operates at low...

  19. Challenging the Issue Class Action End-Run

    E-Print Network [OSTI]

    Hines, Laura J.

    2003-01-01T23:59:59.000Z

    An ever-increasing number of courts and commentators have advocated a simple solution to the seemingly insuperable problem of troublesome individual issues that often thwart certification of a Rule 23(b)(3) class action on predominance grounds...

  20. Obstacles to Determining Punitive Damages in Class Actions

    E-Print Network [OSTI]

    Hines, Laura J.

    2001-01-01T23:59:59.000Z

    Courts and commentators have often embraced the class action device as an ideal means of assessing punitive damages fairly in mass tort cases. In this Article, Professor Hines sounds a cautionary note by identifying a number of procedural...

  1. Class Patent Waiver W(C)2012-002

    Broader source: Energy.gov [DOE]

    This is a request by DEMONSTRATION FACILITY PROGRAM (MDF) for a DOE Class patent waiver of domestic and foreign patent rights under agreement DE-AC05-OR22725.

  2. Teaching Design for Environment in Product Design Classes

    E-Print Network [OSTI]

    Baeriswyl, Michael C.

    The paper presents an approach to teaching design for environment (DFE) in the context of a product design and development course. The teaching method has been applied in our classes for graduate engineering, business, and ...

  3. STATEMENT OF CONSIDERATIONS CLASS WAIVER OF THE GOVERNMENT'S...

    Broader source: Energy.gov (indexed) [DOE]

    MADE IN THE COURSE OF OR UNDER CONTRACT DE-AC04-76DP00613 WITH THE DEPARTMENT OF ENERGY (DOE) FOR THE MANAGEMENT AND OPERATION OF THE KANSAS CITY PLANT AND INCLUDING A CLASS...

  4. STATEMENT OF CONSIDERATIONS CLASS WAIVER OF THE GOVERNMENT'S...

    Broader source: Energy.gov (indexed) [DOE]

    INC. MADE IN THE COURSE OF OR UNDER CONTRACT DE-AC04-92AL73000 WITH THE DEPARTMENT OF ENERGY (DOE) FOR THE MANAGEMENT AND OPERATION OF THE PINELLAS PLANT AND INCLUDING A CLASS...

  5. STATEMENT OF CONSIDERATIONS CLASS WAIVER OF THE GOVERNMENT'S...

    Broader source: Energy.gov (indexed) [DOE]

    INC., MADE IN THE COURSE OF OR UNDER CONTRACT DE-AC04-91AL65030 WITH THE DEPARTMENT OF ENERGY (DOE) FOR THE MANAGEMENT AND OPERATION OF THE PANTEX PLANT AND INCLUDING A CLASS...

  6. Exciting youth about science and engineering : the Stirling Engine class

    E-Print Network [OSTI]

    Barragán, Patrick R

    2008-01-01T23:59:59.000Z

    The problem of a lack of science and engineering opportunities for youth has been identified. While other programs and attempted solutions exist, a novel approach involving creating self-contained project classes, called ...

  7. Class Patent Waiver W(C)2012-004

    Broader source: Energy.gov [DOE]

    This is a request by BIOENERGY SCIENCE CENTER (BESC) for a DOE Class patent waiver of domestic and foreign patent rights under agreement DE-AC05-00OR22725.

  8. Multi-Class Classification with Maximum Margin Multiple Kernel

    E-Print Network [OSTI]

    Tomkins, Andrew

    (named OBSCURE and UFO-MKL, respectively) are used to optimize primal versions of equivalent problems), the OBSCURE and UFO-MKL algorithms are compared against MCMKL #12;Multi-Class Classification with Maximum

  9. Class Patent Waiver W(C)2012-007

    Broader source: Energy.gov [DOE]

    This is a request by SOLID-STATE LIGHTING ROUND 4 for a DOE Class patent waiver of domestic and foreign patent rights under agreement DE-FOA-0000792.

  10. STATEMENT OF CONSIDERATIONS CLASS WAIVER OF THE GOVERNMENT'S

    Broader source: Energy.gov (indexed) [DOE]

    to Designated Non-Proprietary User facilities at all DOE facilities funded by any DOE program. Therefore, the 1983 Non-Proprietary User Class Waiver is superseded by this new...

  11. The heuristic solutions to a class of circle covering problems

    E-Print Network [OSTI]

    Ge, Nenghong Norman

    1989-01-01T23:59:59.000Z

    THE HEURISTIC SOLUTIONS TO A CLASS OF CIRCLE COVERING PROBLEMS A Thesis by NENGHONG NORMAN GE Submitted to the Office of Graduate Studies of Texas AIirM University in partial fulfillment of the requirements for the degree of MASTER... OF SCIENCE May 1989 Major Subject: Electrical Engineering THE HEURITIC SOLUTIONS TO A CLASS OF CIRCLE COVERING PROBLEMS A Th'esis by NENGHONE NORMAN GE Approved as to style and content by: Mi Lu (Chair. of Commirce& Norman Grisw ld (Member) Karan...

  12. Molten Air -- A new, highest energy class of rechargeable batteries

    E-Print Network [OSTI]

    Licht, Stuart

    2013-01-01T23:59:59.000Z

    This study introduces the principles of a new class of batteries, rechargeable molten air batteries, and several battery chemistry examples are demonstrated. The new battery class uses a molten electrolyte, are quasi reversible, and have amongst the highest intrinsic battery electric energy storage capacities. Three examples of the new batteries are demonstrated. These are the iron, carbon and VB2 molten air batteries with respective intrinsic volumetric energy capacities of 10,000, 19,000 and 27,000 Wh per liter.

  13. Luz II | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to:46 - 429Lacey,(MonasterLowell Point, Alaska:Luz II Jump to: navigation, search Name:

  14. Topaz II preliminary safety assessment

    SciTech Connect (OSTI)

    Marshall, A.C. (Sandia National Laboratories, Albuquerque, New Mexico 87185 (United States)); Standley, V. (Air Force Phillips Laboratory, Albuquerque, New Mexico 87110 (United States)); Voss, S.S. (Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)); Haskin, E. (Department of Chemical and Nuclear Engineering Department, Institute for Nuclear Power Studies, University of New Mexico, Albuquerque, New Mexico 87110 (United States))

    1993-01-10T23:59:59.000Z

    The Strategic Defense Initiative Organization (SDIO) decided to investigate the possibility of launching a Russian Topaz II space nuclear power system. A preliminary safety assessment was conducted to determine whether or not a space mission could be conducted safely and within budget constraints. As part of this assessment, a safety policy and safety functional requirements were developed to guide both the safety assessment and future Topaz II activities. A review of the Russian flight safety program was conducted and documented. Our preliminary safety assessment included a top level event tree, neutronic analysis of normal and accident configurations, an evaluation of temperature coefficients of reactivity, a reentry and disposal analysis, and analysis of postulated launch abort impact accidents, and an analysis of postulated propellant fire and explosion accidents. Based on the assessment, it appears that it will be possible to safely launch the Topaz II system in the U.S. with some possible system modifications. The principal system modifications will probably include design changes to preclude water flooded criticality and to assure intact reentry.

  15. PEP-II Operations Report

    SciTech Connect (OSTI)

    Zisman, Michael S.

    2000-11-01T23:59:59.000Z

    PEP-II is a two-ring asymmetric B factory operating at the Upsilon(4S) resonance. It was constructed by a SLAC-LBNL-LLNL collaboration. The collider comprises two rings, a High-Energy Ring (HER) storing 9 GeV electrons, and a Low-Energy Ring (LER) storing 3.1 GeV positrons. Commissioning of the HER began in mid-1997 and commissioning of the LER began in mid-1998. First evidence for collisions was obtained on July 23, 1998. The BaBar detector was installed in early 1999, and commissioning with the detector commenced in May 1999. By September 1999, PEP-II had reached a peak luminosity of 1.35 x 10{sup 33} cm{sup {minus}2} s{sup {minus}1}. In the present run, which began in October 1999, the peak luminosity has reached 3.1 x 10{sup 33} cm{sup {minus}2} s{sup {minus}1} and the integrated luminosity delivered is 25 fb{sup {minus}1}. At present, PEP-II is the world's highest luminosity collider. In this paper we describe the startup experience and summarize the operational experience during fiscal year 2000 (from October 1999 through September 2000). Plan s for luminosity upgrades are briefly described.

  16. Two Zebrafish Alcohol Dehydrogenases Share Common Ancestry with Mammalian Class I, II, IV, and V Alcohol Dehydrogenase

    E-Print Network [OSTI]

    Tullos, Desiree

    Department, Woods Hole Oceanographic Institution, Woods Hole, Massachusetts 02543 Ethanol is teratogenic there is an association between ethanol metab- olism and ethanol-mediated developmental toxicity. Here we report that ADH8A metabolizes ethanol, with a Vmax of 13.4 nmol/min/mg protein, whereas ADH8B does not metabolize

  17. An Integrated Study of the Grayburg/San Andres Reservoir, Foster and South Cowden Fields, Ector County, Texas, Class II

    SciTech Connect (OSTI)

    Trentham, Robert C.; Weinbrandt, Richard; Robinson, William C.; Widner, Kevin

    2001-05-03T23:59:59.000Z

    The objectives of the project were to: (1) Thoroughly understand the 60-year history of the field. (2) Develop a reservoir description using geology and 3D seismic. (3) Isolate the upper Grayburg in wells producing from multiple intervals to stop cross flow. (4) Re-align and optimize the upper Grayburg waterflood. (5) Determine well condition, identify re-frac candidates, evaluate the effectiveness of well work and obtain bottom hole pressure data for simulation utilizing pressure transient testing field wide. (6) Quantitatively integrate all the data to guide the field operations, including identification of new well locations utilizing reservoir simulation.

  18. Zinc(II)-Coordinated Oligotyrosine: A New Class of Cell Penetrating James R. Johnson, Hua Jiang, and Bradley D. Smith*

    E-Print Network [OSTI]

    Smith, Bradley D.

    Jiang, and Bradley D. Smith* Department of Chemistry and Biochemistry, University of Notre Dame, Notre

  19. Global Energetics of Solar Flares: II. Thermal Energies

    E-Print Network [OSTI]

    Aschwanden, M J; Ryan, D; Caspi, A; McTiernan, J M; Warren, H P

    2015-01-01T23:59:59.000Z

    We present the second part of a project on the global energetics of solar flares and CMEs that includes about 400 M- and X-class flares observed with AIA/SDO during the first 3.5 years of its mission. In this Paper II we compute the differential emission measure (DEM) distribution functions and associated multi-thermal energies, using a spatially-synthesized Gaussian DEM forward-fitting method. The multi-thermal DEM function yields a significantly higher (by an average factor of $\\approx 14$), but more comprehensive (multi-)thermal energy than an isothermal energy estimate from the same AIA data. We find a statistical energy ratio of $E_{th}/E_{diss} \\approx 2\\%-40\\%$ between the multi-thermal energy $E_{th}$ and the magnetically dissipated energy $E_{diss}$, which is an order of magnitude higher than the estimates of Emslie et al.~2012. For the analyzed set of M and X-class flares we find the following physical parameter ranges: $L=10^{8.2}-10^{9.7}$ cm for the length scale of the flare areas, $T_p=10^{5.7}-...

  20. A NEW CLASS OF GAMMA-RAY BURSTS FROM STELLAR DISRUPTIONS BY INTERMEDIATE-MASS BLACK HOLES

    SciTech Connect (OSTI)

    Gao, H.; Lu, Y.; Zhang, S. N. [National Astronomical Observatories, Chinese Academy of Sciences, Beijing 100012 (China)

    2010-07-01T23:59:59.000Z

    It has been argued that the long gamma-ray burst (GRB) of GRB 060614 without an associated supernova (SN) has challenged the current classification and fuel model for long GRBs, and thus a tidal disruption model has been proposed to account for such an event. Since it is difficult to detect SNe for long GRBs at high redshift, the absence of an SN association cannot be regarded as the solid criterion for a new classification of long GRBs similar to GRB 060614, called GRB 060614-type bursts. Fortunately, we now know that there is an obvious periodic substructure observed in the prompt light curve of GRB 060614. We thus use such periodic substructure as a potential criterion to categorize some long GRBs into a new class of bursts, which might have been fueled by an intermediate-mass black hole (IMBH) gulping a star, rather than a massive star collapsing to form a black hole. Therefore, the second criterion to recognize for this new class of bursts is whether they fit the tidal disruption model. From a total of 328 Swift GRBs with accurately measured durations and without SN association, we find 25 GRBs satisfying the criteria for GRB 060614-type bursts: seven of them are with known redshifts and 18 with unknown redshifts. These new bursts are {approx}6% of the total Swift GRBs, which are clustered into two subclasses: Type I and Type II with considerably different viscous parameters of accretion disks formed by tidally disrupting their different progenitor stars. We suggest that the two different kinds of progenitors are solar-type stars and white dwarfs: the progenitors for four Type I bursts with viscous parameter of around 0.1 are solar-type stars, and the progenitors for 21 Type II bursts with viscous parameter of around 0.3 are white dwarfs. The potential applications of this new class of GRBs as cosmic standard candles are discussed briefly.

  1. Magnetic ordering in the spinel compound LiMn2-xLixO4,,x=0,0.04... John Gaddy,1

    E-Print Network [OSTI]

    Montfrooij, Wouter

    .1063/1.3073660 The ground state properties of the known lithium-based cubic spinel compounds LiT2O4 range from BCS-range antiferromagnetic order. In contrast, whereas lithium-substituted Li Mn2-xLix O4 also undergoes a charge eightfold rings.6 The Mn4+ rings only interact with other rings via the intervening Mn3+ ions. When cooled

  2. Ii.

    Office of Scientific and Technical Information (OSTI)

    sponsorship of the Materials Division of ASME in conjunction with the Mechanical Metallurgy Committee of AIME. Personne l Connecte d with Contract 1. Professor ial Staff: J....

  3. II

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofofOxford SiteToledo SiteTonawanda North - t ' v I tfi -- ..~

  4. II

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecember 2005 (Thousand9,0, 1997Environment >7,992000 Short-TermSeptember» ;, a

  5. II*

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecember 2005 (Thousand9,0, 1997Environment >7,992000 Short-TermSeptember» ;,

  6. II

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou$0.C. 20545*. . : '* FEB1f\lMUC4cb90,fioml7aa AMY y

  7. II

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou$0.C. 20545*. . : '* FEB1f\lMUC4cb90,fioml7aa AMY y

  8. Combustion Synthesis of Nanoparticulate LiMgxMn1-xPO4 (x=0, 0.1, 0.2) Carbon Composites

    E-Print Network [OSTI]

    Doeff, Marca M

    2010-01-01T23:59:59.000Z

    for Rechargeable Lithium Batteries. J. Electrochem. Soc.Materials for Lithium Batteries. J. Electrochem. Soc. 148,LiMnPO 4 for Lithium Ion Batteries. Electrochem. and Solid

  9. Combustion Synthesis of Nanoparticulate LiMgxMn1-xPO4 (x=0, 0.1, 0.2) Carbon Composites

    E-Print Network [OSTI]

    Doeff, Marca M

    2010-01-01T23:59:59.000Z

    for Rechargeable Lithium Batteries. J. Electrochem. Soc.4 V Cathode Materials for Lithium Batteries. J. Electrochem.LiMnPO 4 for Lithium Ion Batteries. Electrochem. and Solid

  10. Transmission electron microscopy of RSP Fe/Cr/Mn/Mo/C alloy. [Fe-3 wt % Cr-2 wt % Mn-0. 5 wt % Mo, -0. 3 wt % C

    SciTech Connect (OSTI)

    Rayment, J.J.; Thomas, G.

    1982-03-01T23:59:59.000Z

    Rapid solidification processing (RSP) has been carried out on an Fe/Cr/Mn/Mo/C alloy using both electron-beam melting and piston-and-anvil techniques. Preliminary TEM results show RSP produces a refined duplex microstructure of ferrite and martensite, with a typical ferrite grain size of 0.50 - 3.0 microns. This RSP microstructure is significantly different from that observed in the conventionally austenitized and quenched alloys - a lath martensitic microstructure with thin films of retained interlath austenite. The morphological change produced by RSP is accompanied by an increase in hardness from 48R/sub c/ to 61R/sub c/ (approx. 480 to 720 VHN). It is intended to use electron-beam specimens to examine the potential beneficial effect of RSP upon sliding wear resistance and, by careful TEM studies, it will be possible to characterize the microstructure and its role in the hardness and wear behavior of the RSP alloy.

  11. Conformal nets II: conformal blocks

    E-Print Network [OSTI]

    Arthur Bartels; Christopher L. Douglas; André Henriques

    2014-09-30T23:59:59.000Z

    Conformal nets provide a mathematical formalism for conformal field theory. Associated to a conformal net with finite index, we give a construction of the `bundle of conformal blocks', a representation of the mapping class groupoid of closed topological surfaces into the category of finite-dimensional projective Hilbert spaces. We also construct infinite-dimensional spaces of conformal blocks for topological surfaces with smooth boundary. We prove that the conformal blocks satisfy a factorization formula for gluing surfaces along circles, and an analogous formula for gluing surfaces along intervals. We use this interval factorization property to give a new proof of the modularity of the category of representations of a conformal net.

  12. A DUSTY Mg II ABSORBER ASSOCIATED WITH THE QUASAR SDSS J003545.13+011441.2

    SciTech Connect (OSTI)

    Jiang, P.; Lu, H. L.; Zhou, H. Y. [Key Laboratory for Research in Galaxies and Cosmology, University of Science and Technology of China, Chinese Academy of Sciences, Hefei, Anhui, 230026 (China); Ge, J. [Astronomy Department, University of Florida, 211 Bryant Space Science Center, P. O. Box 112055, Gainesville, FL 32611 (United States); Prochaska, J. X. [University of California Observatories-Lick Observatory, University of California, Santa Cruz, CA 95064 (United States); Kulkarni, V. P., E-mail: jpaty@mail.ustc.edu.c [Department of Physics and Astronomy, University of South Carolina, Columbia, SC 29208 (United States)

    2010-09-01T23:59:59.000Z

    We report on a dusty Mg II absorber associated with the quasar SDSS J003545.13+011441.2 (hereafter J0035+0114) at z = 1.5501, the strongest of the three Mg II absorbers along the sight line of the quasar. The two low-redshift intervening absorbers are at z = 0.7436 and 0.5436. Based on the photometric and spectroscopic data of the Sloan Digital Sky Survey (SDSS), we infer that the rest-frame color excess E(B - V) due to the associated dust is more than 0.07 by assuming a Small Magellanic Cloud (SMC) type extinction curve. Our follow-up moderate resolution spectroscopic observation with the ESI spectrometer at the 10 m Keck telescope enables us to reliably identify most of the important metal elements, such as Zn, Fe, Mn, Mg, Al, Si, Cr, and Ni, in the associated system. We measure the column density of each species and detect significant dust depletion. In addition, we develop a simulation technique to gauge the significance of a 2175 A dust absorption bump in the SDSS quasar spectra. By using this technique, we analyze the SDSS spectrum of J0035+0114 for the presence of an associated 2175 A extinction feature and report a tentative detection at a {approx}2{sigma} significant level.

  13. Neutronics analysis for HYLIFE-II

    SciTech Connect (OSTI)

    Tobin, M.T.

    1990-12-20T23:59:59.000Z

    A preliminary neutronics analysis of the HYLIFE-2 reactor concept gives a tritium breeding ratio of 1.17 and a system energy multiplication factor of 1.14. Modified SS-316 (in which Mn is substituted for Ni) is superior to Hastelloy X and Hastelloy N as a firstwall material considering He generation, dpa-limited lifetime, and shallow-burial index. Since Flibe is corrosive to Mn metals, however, a favorable first-wall material is yet to be decided on. Flibe impurities considered (e.g., inherent impurities and those arising from wall erosion or secondary-coolant leakage) do not increase the hazard to the public over that of pure Flibe. The main issues for HYLIFE-2 are the high shallow-burial index (106) and the requirement to contain some 99.7% of the {sup 18}F inventory to prevent its release to the public 18 refs., 3 figs., 9 tabs.

  14. WC_2000_003_CLASS_WAIVER_FOR_BWXT_UNDER_A_MANAGEMENT_AND_OPE...

    Broader source: Energy.gov (indexed) [DOE]

    NDERAMANAGEMENTANDOPE.pdf More Documents & Publications ClassWaiverWC-2000-003.pdf WC2000004CLASSWAIVERMadeinthePerformanceofCRADAby.pdf ClassWaiverWC-2000-004...

  15. Policy Flash 2013-64 Acquisition Letter 10 and Class Deviation...

    Office of Environmental Management (EM)

    64 Acquisition Letter 10 and Class Deviation for Nondisplacement of Qualified Workers Policy Flash 2013-64 Acquisition Letter 10 and Class Deviation for Nondisplacement of...

  16. Policy Flash 2013-64 Acquisition Letter 10 and Class Deviation...

    Energy Savers [EERE]

    4 Acquisition Letter 10 and Class Deviation for Nondisplacement of Qualified Workers Policy Flash 2013-64 Acquisition Letter 10 and Class Deviation for Nondisplacement of Qualified...

  17. Belle II Technical Design Report

    E-Print Network [OSTI]

    Abe, T; Adamczyk, K; Ahn, S; Aihara, H; Akai, K; Aloi, M; Andricek, L; Aoki, K; Arai, Y; Arefiev, A; Arinstein, K; Arita, Y; Asner, D M; Aulchenko, V; Aushev, T; Aziz, T; Bakich, A M; Balagura, V; Ban, Y; Barberio, E; Barvich, T; Belous, K; Bergauer, T; Bhardwaj, V; Bhuyan, B; Blyth, S; Bondar, A; Bonvicini, G; Bozek, A; Bracko, M; Brodzicka, J; Brovchenko, O; Browder, T E; Cao, G; Chang, M -C; Chang, P; Chao, Y; Chekelian, V; Chen, A; Chen, K -F; Chen, P; Cheon, B G; Chiang, C -C; Chistov, R; Cho, K; Choi, S -K; Chung, K; Comerma, A; Cooney, M; Cowley, D E; Critchlow, T; Dalseno, J; Danilov, M; Dieguez, A; Dierlamm, A; Dillon, M; Dingfelder, J; Dolenec, R; Dolezal, Z; Drasal, Z; Drutskoy, A; Dungel, W; Dutta, D; Eidelman, S; Enomoto, A; Epifanov, D; Esen, S; Fast, J E; Feindt, M; Garcia, M Fernandez; Fifield, T; Fischer, P; Flanagan, J; Fourletov, S; Fourletova, J; Freixas, L; Frey, A; Friedl, M; Fruehwirth, R; Fujii, H; Fujikawa, M; Fukuma, Y; Funakoshi, Y; Furukawa, K; Fuster, J; Gabyshev, N; Cueto, A Gaspar de Valenzuela; Garmash, A; Garrido, L; Geisler, Ch; Gfall, I; Goh, Y M; Golob, B; Gorton, I; Grzymkowski, R; Guo, H; Ha, H; Haba, J; Hara, K; Hara, T; Haruyama, T; Hayasaka, K; Hayashi, K; Hayashii, H; Heck, M; Heindl, S; Heller, C; Hemperek, T; Higuchi, T; Horii, Y; Hou, W -S; Hsiung, Y B; Huang, C -H; Hwang, S; Hyun, H J; Igarashi, Y; Iglesias, C; Iida, Y; Iijima, T; Imamura, M; Inami, K; Irmler, C; Ishizuka, M; Itagaki, K; Itoh, R; Iwabuchi, M; Iwai, G; Iwai, M; Iwasaki, M; Iwasaki, M; Iwasaki, Y; Iwashita, T; Iwata, S; Jang, H; Ji, X; Jinno, T; Jones, M; Julius, T; Kageyama, T; Kah, D H; Kakuno, H; Kamitani, T; Kanazawa, K; Kapusta, P; Kataoka, S U; Katayama, N; Kawai, M; Kawai, Y; Kawasaki, T; Kennedy, J; Kichimi, H; Kikuchi, M; Kiesling, C; Kim, B K; Kim, G N; Kim, H J; Kim, H O; Kim, J -B; Kim, J H; Kim, M J; Kim, S K; Kim, K T; Kim, T Y; Kinoshita, K; Kishi, K; Kisielewski, B; van Dam, K Kleese; Knopf, J; Ko, B R; Koch, M; Kodys, P; Koffmane, C; Koga, Y; Kohriki, T; Koike, S; Koiso, H; Kondo, Y; Korpar, S; Kouzes, R T; Kreidl, Ch; Kreps, M; Krizan, P; Krokovny, P; Krueger, H; Kruth, A; Kuhn, W; Kuhr, T; Kumar, R; Kumita, T; Kupper, S; Kuzmin, A; Kvasnicka, P; Kwon, Y -J; Lacasta, C; Lange, J S; Lee, I -S; Lee, M J; Lee, M W; Lee, S -H; Lemarenko, M; Li, J; Li, W D; Li, Y; Libby, J; Limosani, A; Liu, C; Liu, H; Liu, Y; Liu, Z; Liventsev, D; Virto, A Lopez; Makida, Y; Mao, Z P; Marinas, C; Masuzawa, M; Matvienko, D; Mitaroff, W; Miyabayashi, K; Miyata, H; Miyazaki, Y; Miyoshi, T; Mizuk, R; Mohanty, G B; Mohapatra, D; Moll, A; Mori, T; Morita, A; Morita, Y; Moser, H -G; Martin, D Moya; Mueller, T; Muenchow, D; Murakami, J; Myung, S S; Nagamine, T; Nakamura, I; Nakamura, T T; Nakano, E; Nakano, H; Nakao, M; Nakazawa, H; Nam, S -H; Natkaniec, Z; Nedelkovska, E; Negishi, K; Neubauer, S; Ng, C; Ninkovic, J; Nishida, S; Nishimura, K; Novikov, E; Nozaki, T; Ogawa, S; Ohmi, K; Ohnishi, Y; Ohshima, T; Ohuchi, N; Oide, K; Olsen, S L; Ono, M; Ono, Y; Onuki, Y; Ostrowicz, W; Ozaki, H; Pakhlov, P; Pakhlova, G; Palka, H; Park, H; Park, H K; Peak, L S; Peng, T; Peric, I; Pernicka, M; Pestotnik, R; Petric, M; Piilonen, L E; Poluektov, A; Prim, M; Prothmann, K; Regimbal, K; Reisert, B; Richter, R H; Riera-Babures, J; Ritter, A; Ritter, A; Ritter, M; Roehrken, M; Rorie, J; Rosen, M; Rozanska, M; Ruckman, L; Rummel, S; Rusinov, V; Russell, R M; Ryu, S; Sahoo, H; Sakai, K; Sakai, Y; Santelj, L; Sasaki, T; Sato, N; Sato, Y; Scheirich, J; Schieck, J; Schwanda, C; Schwartz, A J; Schwenker, B; Seljak, A; Senyo, K; Seon, O -S; Sevior, M E; Shapkin, M; Shebalin, V; Shen, C P; Shibuya, H; Shiizuka, S; Shiu, J -G; Shwartz, B; Simon, F; Simonis, H J; Singh, J B; Sinha, R; Sitarz, M; Smerkol, P; Sokolov, A; Solovieva, E; Stanic, S; Staric, M; Stypula, J; Suetsugu, Y; Sugihara, S; Sugimura, T; Sumisawa, K; Sumiyoshi, T; Suzuki, K; Suzuki, S Y; Takagaki, H; Takasaki, F; Takeichi, H; Takubo, Y; Tanaka, M; Tanaka, S; Taniguchi, N; Tarkovsky, E; Tatishvili, G; Tawada, M; Taylor, G N; Teramoto, Y; Tikhomirov, I; Trabelsi, K; Tsuboyama, T; Tsunada, K; Tu, Y -C; Uchida, T; Uehara, S; Ueno, K; Uglov, T; Unno, Y; Uno, S; Urquijo, P; Ushiroda, Y; Usov, Y; Vahsen, S; Valentan, M; Vanhoefer, P; Varner, G; Varvell, K E; Vazquez, P; Vila, I; Vilella, E; Vinokurova, A; Visniakov, J; Vos, M; Wang, C H; Wang, J; Wang, M -Z; Wang, P; Wassatch, A; Watanabe, M; Watase, Y; Weiler, T; Wermes, N; Wescott, R E; White, E; Wicht, J; Widhalm, L; Williams, K M; Won, E; Xu, H; Yabsley, B D; Yamamoto, H; Yamaoka, H; Yamaoka, Y; Yamauchi, M; Yin, Y; Yoon, H; Yu, J; Yuan, C Z; Yusa, Y; Zander, D; Zdybal, M; Zhang, Z P; Zhao, J; Zhao, L; Zhao, Z; Zhilich, V; Zhou, P; Zhulanov, V; Zivko, T; Zupanc, A; Zyukova, O

    2010-01-01T23:59:59.000Z

    The Belle detector at the KEKB electron-positron collider has collected almost 1 billion Y(4S) events in its decade of operation. Super-KEKB, an upgrade of KEKB is under construction, to increase the luminosity by two orders of magnitude during a three-year shutdown, with an ultimate goal of 8E35 /cm^2 /s luminosity. To exploit the increased luminosity, an upgrade of the Belle detector has been proposed. A new international collaboration Belle-II, is being formed. The Technical Design Report presents physics motivation, basic methods of the accelerator upgrade, as well as key improvements of the detector.

  18. SECTION II: HEAVY ION REACTIONS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 -the Mid-Infrared0 ResourceAwards SAGE Awards ,# , on behalfCURRICULUMTemperatureII:

  19. ARM - RHUBC II Science Objectives

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  20. Penascal II | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth'sOklahoma/GeothermalOrange County isParadise, Nevada:PavilionSunPeetzPenascal II

  1. Aegir II | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of InspectorConcentrating SolarElectric Coop,SaveWhiskeyEnergyAd-VentaAddison is aAdenaAdrianItalyAegir II

  2. SPIDERS Phase II Technical Report

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department ofT ib l LPROJECTS IN7 Roadmap forDKT.AwardsSPEER's Building EnergyPhase II

  3. Delocalization and hybridization enhance the magnetocaloric effect in Ni2Mn0.75Cu0.25Ga

    SciTech Connect (OSTI)

    Roy, Sujoy; Blackburn, E.; Valvidares, S. M.; Fitzsimmons, M. R.; Vogel, Sven C.; Khan, M.; Dubenko, I.; Stadler, S.; Ali, N.; Sinha, S. K.; Kortright, J. B.

    2008-11-26T23:59:59.000Z

    In view of the looming energy crisis facing our planet, attention increasingly focuses on materials potentially useful as a basis for energy saving technologies. The discovery of giant magnetocaloric (GMC) compounds - materials that exhibit especially large changes in temperature as the externally applied magnetic field is varied - is one such compound 1. These materials have potential for use in solid state cooling technology as a viable alternative to existing gas based refrigeration technologies that use choro-fluoro - and hydro-fluoro-carbon chemicals known to have a severe detrimental effect on human health and environment 2,3. Examples of GMC compounds include Gd5(SiGe)4 4, MnFeP1-xAsx 5 and Ni-Mn-Ga shape memory alloy based compounds 6-8. Here we explain how the properties of one of these compounds (Ni2MnGa) can be tuned as a function of temperature by adding dopants. By altering the free energy such that the structural and magnetic transitions coincide, a GMC compound that operates at just the right temperature for human requirements can be obtained 9. We show how Cu, substituted for Mn, pulls the magnetic transition downwards in temperature and also, counterintuitively, increases the delocalization of the Mn magnetism. At the same time, this reinforces the Ni-Ga chemical bond, raising the temperature of the martensite-austenite transition. At 25percent doping, the two transitions coincide at 317 K.

  4. Magnetovolume effect in Ho{sub 2}Fe{sub 17-x}Mn{sub x} compounds

    SciTech Connect (OSTI)

    Wang, J. L. [Institute for Superconductivity and Electronic Materials, University of Wollongong (Australia); Bragg Institute, ANSTO, Menai, NSW 2234 (Australia); School of Physical, Environmental and Mathematical Sciences, University of New South Wales, Canberra, ACT 2600 (Australia); Studer, A. J.; Kennedy, S. J. [Bragg Institute, ANSTO, Menai, NSW 2234 (Australia); Zeng, R.; Dou, S. X. [Institute for Superconductivity and Electronic Materials, University of Wollongong (Australia); Campbell, S. J. [School of Physical, Environmental and Mathematical Sciences, University of New South Wales, Canberra, ACT 2600 (Australia)

    2012-04-01T23:59:59.000Z

    The structural and magnetic properties of seven compounds in the Ho{sub 2}Fe{sub 17-x}Mn{sub x} series (x = 0-5) have been investigated. The spontaneous magnetization M{sub s} at 10 K exhibits a minimum at x{approx_equal} 3.8 while the 3d-sublattice magnetization M{sub T} is found to decrease at {approx} -3.4 {mu}{sub B}/per Mn atom compared with the rate of {approx}-2.0 {mu}{sub B}/per Mn atom expected from a simple dilution model. All of the Ho{sub 2}Fe{sub 17-x}Mn{sub x} compounds exhibit anisotropic thermal expansion below their Curie temperatures leading to the presence of strong magnetovolume effects and Invar-type behavior below T{sub C}. An approximately zero volume thermal expansion has been detected between 10 K and 270 K for Ho{sub 2}Fe{sub 17}. The maximum magnetic entropy changes for Ho{sub 2}Fe{sub 17-x}Mn{sub x} with x = 0 and 2.0 are 3.2 J kg{sup -1} K{sup -1} around T{sub C} {approx} 336 K and 2.7 J kg{sup -1} K{sup -1} around T{sub C} {approx} 302 K, respectively, for magnetic field change of B = 0-5 T.

  5. Mittwoch, 28.05.2014 Zeit H17, NW II H18, NW II H20, NW II

    E-Print Network [OSTI]

    Ullmann, G. Matthias

    Beliefs and Fracking Gebäude Audimax 09:40 (Gebäudewechsel Audimax -> NW II) 10:00 "Hydrogeologie von

  6. Surface structures of Al-Pd-Mn and Al-Cu-Fe icosahedral quasicrystals

    SciTech Connect (OSTI)

    Shen, Z.

    1999-02-12T23:59:59.000Z

    In this dissertation, the author reports on the surface structure of i-Al-Pd-Mn twofold, threefold, fivefold and i-Al-Cu-Fe fivefold surfaces. The LEED studies indicate the existence of two distinct stages in the regrowth of all four surfaces after Ar{sup +} sputtering. In the first stage, upon annealing at relatively low temperature: 500K--800K (depending on different surfaces), a cubic phase appears. The cubic LEED patterns transform irreversibly to unreconstructed quasicrystalline patterns upon annealing to higher temperatures, indicating that the cubic overlayers are metastable. Based upon the data for three chemically-identical, but symmetrically-inequivalent surfaces, a model is developed for the relation between the cubic overlayers and the quasicrystalline substrate. The model is based upon the related symmetries of cubic close-packed and icosahedral-packed materials. These results may be general among Al-rich, icosahedral materials. STM study of Al-Pd-Mn fivefold surface shows that terrace-step-kink structures start to form on the surface after annealing above 700K. Large, atomic ally-flat terraces were formed after annealing at 900K. Fine structures with fivefold icosahedral symmetry were found on those terraces. Data analysis and comparison of the STM images and structure model of icosahedral Al-Pd-Mn suggest that the fine structures in the STM images may be the pseudo Mackay (PMI) clusters which are the structure units of the structure model. Based upon his results, he can conclude that quasicrystalline structures are the stable structures of quasicrystal surfaces. In other words, quasicrystalline structures extend from the bulk to the surface. As a result of the effort reported in this dissertation, he believes that he has increased his understanding of the surface structure of icosahedral quasicrystals to a new level.

  7. Phase transformation during mechano-synthesis of nanocrystalline/amorphous Fe–32Mn–6Si alloys

    SciTech Connect (OSTI)

    Amini, Rasool, E-mail: ramini2002@gmail.com [Department of Materials Science and Engineering, Shiraz University of Technology, 71555-313 Shiraz (Iran, Islamic Republic of); Shamsipoor, Ali [Department of Materials Science and Engineering, Shiraz University of Technology, 71555-313 Shiraz (Iran, Islamic Republic of); Ghaffari, Mohammad [Department of Electrical and Electronics Engineering, UNAM-National Institute of Materials Science and Nanotechnology Bilkent University, Ankara 06800 (Turkey); Alizadeh, Morteza [Department of Materials Science and Engineering, Shiraz University of Technology, 71555-313 Shiraz (Iran, Islamic Republic of); Okyay, Ali Kemal [Department of Electrical and Electronics Engineering, UNAM-National Institute of Materials Science and Nanotechnology Bilkent University, Ankara 06800 (Turkey)

    2013-10-15T23:59:59.000Z

    Mechano-synthesis of Fe–32Mn–6Si alloy by mechanical alloying of the elemental powder mixtures was evaluated by running the ball milling process under an inert argon gas atmosphere. In order to characterize the as-milled powders, powder sampling was performed at predetermined intervals from 0.5 to 192 h. X-ray florescence analyzer, X-ray diffraction, scanning electron microscope, and high resolution transmission electron microscope were utilized to investigate the chemical composition, structural evolution, morphological changes, and microstructure of the as-milled powders, respectively. According to the results, the nanocrystalline Fe–Mn–Si alloys were completely synthesized after 48 h of milling. Moreover, the formation of a considerable amount of amorphous phase during the milling process was indicated by quantitative X-ray diffraction analysis as well as high resolution transmission electron microscopy image and its selected area diffraction pattern. It was found that the ?-to-? and subsequently the amorphous-to-crystalline (especially martensite) phase transformation occurred by milling development. - Graphical abstract: Mechano-synthesis of nanocrystalline/amorphous Fe–32Mn–6Si shape memory alloys in the powder form: amorphous phase formation, ?-to-? phase transformation, mechano-crystallization of the amorphous, and martensite phase formation during the process. Highlights: • During MA, the ?-to-? phase transformation and amorphization occurred. • Mechano-crystallization of the amorphous phase occurred at sufficient milling time. • The formation of high amount of ?-martensite was evidenced at high milling times. • The platelet, spherical, and then irregular particle shapes was extended by MA. • By MA, the particles size was increased, then reduced, and afterward re-increased.

  8. Magnetic and electrical properties of layered magnets Tl(Cr,Mn,Co)Se{sub 2}

    SciTech Connect (OSTI)

    Veliyev, R. G.; Sadikhov, R. Z.; Kerimova, E. M., E-mail: ekerimova@physics.ab.az; Asadov, Yu. G.; Jabbarov, A. I. [National Academy of Sciences of Azerbaijan, Institute of Physics (Azerbaijan)

    2009-02-15T23:59:59.000Z

    Tl(Cr,Mn,Co)Se{sub 2} crystals were synthesized at T {approx} 1050 K. X-ray diffraction analysis showed that TlCrSe{sub 2}, TlMnSe{sub 2}, and TlCoSe{sub 2} compounds crystallize in the hexagonal crystal system with the lattice parameters: a = 3.6999 A, c = 22.6901 A, c/a {approx} 6.133, z = 3, {rho}{sub x} = 6.209 g/cm{sup 3}; a = 6.53 A, c = 23.96 A, c/a {approx} 3.669, z = 8, {rho}{sub x} = 6.71 g/cm{sup 3}; and a = 3.747 A, c = 22.772 A, c/a {approx} 6.077, z = 3, {rho}{sub x} = 7.577 g/cm{sup 3}, respectively. Magnetic and electrical studies in the temperature range from 80-400 K showed that TlCrSe{sub 2} is a semiconductor ferromagnet, TlMnSe{sub 2} is a semiconductor antiferromagnet, and TlCoSe{sub 2} is a ferrimagnet with a conductivity characteristic of metals. A rather large deviation in the experimental effective magnetic moment for TlCrSe{sub 2} (3.05 {mu}B) from the theoretical value (3.85 {mu}B) is attributed to two-dimensional magnetic ordering in the paramagnetic region of the noticeably layered ferromagnet TlCrSe{sub 2}. In TlCrSe{sub 2}, a correlation between magnetic and electrical properties was detected.

  9. Quadrature formulae for classes of functions of low smoothness

    SciTech Connect (OSTI)

    Nursultanov, E D [Kazakhstan Branch of Lomonosov Moscow State University, Astana (Kazakhstan); Tleukhanova, N T [Eurasian National University named after L.N.Gumilev, Astana (Kazakhstan)

    2003-10-31T23:59:59.000Z

    For Sobolev and Korobov spaces of functions of several variables a quadrature formula with explicitly defined coefficients and nodes is constructed. This formula is precise for trigonometric polynomials with harmonics from the corresponding step hyperbolic cross. The error of the quadrature formula in the classes W{sup {alpha}}{sub p}[0,1]{sup n}, E{sup {alpha}}[0,1]{sup n} is o((ln M){sup {beta}}/M{sup {alpha}}), where M is the number of nodes and {beta} is a parameter depending on the class. The problem of the approximate calculation of multiple integrals for functions in W{sup {alpha}}{sub p}[0,1]{sup n} is considered in the case when this class does not lie in the space of continuous functions, that is, for {alpha}{<=}1/p.

  10. The tractability of CSP classes defined by forbidden patterns

    E-Print Network [OSTI]

    Cooper, David A Cohen Martin C; Salamon, András Z

    2011-01-01T23:59:59.000Z

    The constraint satisfaction problem (CSP) is a general problem central to computer science and artificial intelligence. Although the CSP is NP-hard in general, considerable effort has been spent on identifying tractable subclasses. The main two approaches consider structural properties (restrictions on the hypergraph of constraint scopes) and relational properties (restrictions on the language of constraint relations). Recently, some authors have considered hybrid properties that restrict the constraint hypergraph and the relations simultaneously. Our key contribution is the novel concept of a CSP pattern and classes of problems defined by forbidden patterns (which can be viewed as forbidding generic subproblems). We describe the theoretical framework which can be used to reason about classes of problems defined by forbidden patterns. We show that this framework generalises relational properties and allows us to capture known hybrid tractable classes. Although we are not close to obtaining a dichotomy concern...

  11. Magnetoelastic Coupling and Symmetry Breaking in the Frustrated Antiferromagnet {alpha}-NaMnO{sub 2}

    SciTech Connect (OSTI)

    Giot, Maud [Institute of Electronic Structure and Laser, Foundation for Research and Technology - Hellas, Vassilika Vouton, 71110 Heraklion (Greece); ISIS, Science and Technology Facilities Council, Rutherford Appleton Laboratory, Chilton-Didcot, OX11 0QX, Oxfordshire (United Kingdom); Chapon, Laurent C.; Radaelli, Paolo G. [ISIS, Science and Technology Facilities Council, Rutherford Appleton Laboratory, Chilton-Didcot, OX11 0QX, Oxfordshire (United Kingdom); Androulakis, John; Lappas, Alexandros [Institute of Electronic Structure and Laser, Foundation for Research and Technology - Hellas, Vassilika Vouton, 71110 Heraklion (Greece); Green, Mark A. [NIST Center for Neutron Research, 100 Bureau Drive, Gaithersburg, Maryland 20899-8562 (United States); Department of Materials Science and Engineering, University of Maryland, College Park, Maryland 20742-2115 (United States)

    2007-12-14T23:59:59.000Z

    The magnetic and crystal structures of the {alpha}-NaMnO{sub 2} have been determined by high-resolution neutron powder diffraction. The system maps out a frustrated triangular spin lattice with anisotropic interactions that displays two-dimensional spin correlations below 200 K. Magnetic frustration is lifted through magneto-elastic coupling, evidenced by strong anisotropic broadening of the diffraction profiles at high temperature and ultimately by a structural phase transition at 45 K. In this low-temperature regime a three-dimensional antiferromagnetic state is observed with a propagation vector k=((1/2),(1/2),0)

  12. Vacancy dynamic in Ni-Mn-Ga ferromagnetic shape memory alloys

    SciTech Connect (OSTI)

    Merida, D., E-mail: david.merida@ehu.es [Fisika Aplikatua II Saila, Euskal Herriko Unibertsitatea UPV/EHU, p.k. 644, 48080 Bilbao (Spain); Elektrizitate eta Elektronika Saila, Euskal Herriko Unibertsitatea UPV/EHU, p.k. 644, 48080 Bilbao (Spain); García, J. A. [Fisika Aplikatua II Saila, Euskal Herriko Unibertsitatea UPV/EHU, p.k. 644, 48080 Bilbao (Spain); BC Materials (Basque Centre for Materials, Application and Nanostructures), 48040 Leioa (Spain); Sánchez-Alarcos, V.; Pérez-Landazábal, J. I.; Recarte, V. [Departamento de Física, Universidad Pública de Navarra, Campus de Arrosadia, 31006 Pamplona (Spain); Plazaola, F. [Elektrizitate eta Elektronika Saila, Euskal Herriko Unibertsitatea UPV/EHU, p.k. 644, 48080 Bilbao (Spain)

    2014-06-09T23:59:59.000Z

    Vacancies control any atomic ordering process and consequently most of the order-dependent properties of the martensitic transformation in ferromagnetic shape memory alloys. Positron annihilation spectroscopy demonstrates to be a powerful technique to study vacancies in NiMnGa alloys quenched from different temperatures and subjected to post-quench isothermal annealing treatments. Considering an effective vacancy type the temperature dependence of the vacancy concentration has been evaluated. Samples quenched from 1173?K show a vacancy concentration of 1100?±?200?ppm. The vacancy migration and formation energies have been estimated to be 0.55?±?0.05?eV and 0.90?±?0.07?eV, respectively.

  13. Spin relaxation time dependence on optical pumping intensity in GaAs:Mn

    SciTech Connect (OSTI)

    Burobina, V. [Department of Physics and Astronomy, University of Utah, 115 South 1400 East, Salt Lake City, Utah 84112-0830 (United States); Binek, Ch. [Department of Physics and Astronomy, Nebraska Center for Materials and Nanoscience, Theodore Jorgensen Hall, 855 North 16th Street, University of Nebraska, P.O. Box 880299, Lincoln, Nebraska 68588-0299 (United States)

    2014-04-28T23:59:59.000Z

    We analyze the dependence of electron spin relaxation time on optical pumping intensity in a partially compensated acceptor semiconductor GaAs:Mn using analytic solutions for the kinetic equations of the charge carrier concentrations. Our results are applied to previous experimental data of spin-relaxation time vs. excitation power for magnetic concentrations of approximately 10{sup 17}?cm{sup ?3}. The agreement of our analytic solutions with the experimental data supports the mechanism of the earlier-reported atypically long electron-spin relaxation time in the magnetic semiconductor.

  14. Oxidation Characteristics of Fe-18Cr-18Mn-stainless alloys

    SciTech Connect (OSTI)

    James Rawers

    2010-10-01T23:59:59.000Z

    Air oxidation studies of Fe-18Cr-18Mn stainless steels were conducted at 525°C, 625°C, and 725°C. Alloys were evaluated with respect to changes in oxidation properties as a result of interstitial additions of nitrogen and carbon and of minor solute additions of silicon, molybdenum, and nickel. Interstitial concentrations possibly had a small, positive effect on oxidation resistance. Minor solute additions significantly improved oxidation resistance but could also reduce interstitial solubility resulting in formation of chromium carbides. Loss of solute chromium resulted in a slight reduction in oxidation protection. Oxidation lasting over 500 hours produced a manganese rich, duplex oxide structure: an outer sesquioxide and an inner spinel oxide.

  15. Ferromagnetic transition temperature enhancement in (Ga,Mn)As semiconductors by carbon codoping

    E-Print Network [OSTI]

    Jungwirth, T.; Masek, J.; Sinova, Jairo; MacDonald, AH.

    2003-01-01T23:59:59.000Z

    -1829/2003/68~16!/161202~4!/$20.00 68 161202- t in ?Ga,Mn?As semiconductors codoping ,2,4 and A. H. MacDonald2 a? 10, 162 53 Praha 6, Czech Republic y Station C1600, Austin, Texas 78712-0264, USA 2, 182 21 Praha 8, Czech Republic y, College Station, Texas 77843-4242, USA d 13... Society1 RAPID COMMUNICATIONS JUNGWIRTH, MASE? K, SINOVA, AND MacDONALD PHYSICAL REVIEW B 68, 161202~R! ~2003! The above qualitative analysis of formation energies sug- gests that CAs codoping is favorable for achieving high Curie temperatures. Unlike...

  16. Synthesis and Luminescence of ZnMgS:Mn2+ Nanoparticles. | EMSL

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  17. File:USDA-CE-Production-GIFmaps-MN.pdf | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublicIDAPowerPlantSitingConstruction.pdfNotify98.pdf Jump to: navigation,storage planIL.pdf JumpMN.pdf Jump to:

  18. Stabilization of ZnMnO3 Phase from Sol-gel Synthesized Nitrate Precursors .

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administrationcontroller systemsBiSiteNeutron Scattering4 By I.| EMSL ZnMnO3 Phase from Sol-gel

  19. Suppression of conductivity in Mn-Doped ZnO Thin Films. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security AdministrationcontrollerNanocrystalline GalliumSuppression of conductivity in Mn-Doped ZnO Thin Films.

  20. Neutron structural characterization, inversion degree and transport properties of NiMn{sub 2}O{sub 4} spinel prepared by the hydroxide route

    SciTech Connect (OSTI)

    Sagua, A.; Lescano, Gabriela M. [Departamento de Química, Laboratorio de Fisicoquímica Inorgánica, Universidad Nacional del Sur, INQUISUR, 8000 Bahía Blanca (Argentina)] [Departamento de Química, Laboratorio de Fisicoquímica Inorgánica, Universidad Nacional del Sur, INQUISUR, 8000 Bahía Blanca (Argentina); Alonso, J.A., E-mail: jaalonso@icmm.csic.es [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco, E-28049 Madrid (Spain); Martínez-Coronado, R. [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco, E-28049 Madrid (Spain)] [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco, E-28049 Madrid (Spain); Fernández-Díaz, M.T. [Institut Laue Langevin, BP 156X, Grenoble F-38042 (France)] [Institut Laue Langevin, BP 156X, Grenoble F-38042 (France); Morán, E. [Departamento de Química Inorgánica, Facultad de Ciencias Químicas, Universidad Complutense, 28040 Madrid (Spain)] [Departamento de Química Inorgánica, Facultad de Ciencias Químicas, Universidad Complutense, 28040 Madrid (Spain)

    2012-06-15T23:59:59.000Z

    Graphical abstract: A pure specimen has been synthesized by the hydroxide route. This spinel, studied by NPD, shows an important inversion degree, ? = 0.80. A bond-valence study shows that the tetrahedral Mn ions are divalent whereas the octahedral Mn and Ni are slightly oxidized from the expected 3+ and 2+ values, respectively. The mixed valence Mn{sup 3+}/Mn{sup 4+} accounts for a hopping mechanism between adjacent octahedral sites, leading to a significant conductivity. Highlights: ? A low-temperature hydroxide route allowed preparing almost pure specimens of NiMn{sub 2}O{sub 4}. ? NPD essential to determine inversion degree; contrasting Ni and Mn for neutrons. ? Bond valence establishes valence state of octahedral and tetrahedral Ni and Mn ions. ? Thermal analysis, transport measurements complement characterization of this oxide. ? A structure–properties relationship is established. -- Abstract: The title compound has been synthesized by the hydroxide route. The crystal structure has been investigated at room temperature from high-resolution neutron powder diffraction (NPD) data. It crystallizes in a cubic spinel structure, space group Fd3{sup ¯}m, Z = 8, with a = 8.3940(2) ? at 295 K. The crystallographic formula is (Ni{sub 0.202(1)}Mn{sub 0.798(1)}){sub 8a}(Ni{sub 0.790(1)}Mn{sub 1.210(1)}){sub 16d}O{sub 4} where 8a and 16d stand for the tetrahedral and octahedral sites of the spinel structure, respectively. There is a significant inversion degree of the spinel structure, ? = 0.80. In fact, the variable parameter for the oxygen position, u = 0.2636(4), is far from that expected (u = 0.25) for normal spinels. From a bond-valence study, it seems that the valence distribution in NiMn{sub 2}O{sub 4} spinel is not as trivial as expected (Ni{sup 2+} and Mn{sup 3+}), but clearly the tetrahedral Mn ions are divalent whereas the octahedral Mn and Ni are slightly oxidized from the expected +3 and +2 values, respectively. The mixed valence observed at the octahedral sites provides the charge carriers that, by a hopping mechanism between Mn{sup 3+}/Mn{sup 4+} adjacent sites, leads to a significant conductivity, up to 0.85 S cm{sup ?1} at 800 °C in air.

  1. LiMn{sub 2}O{sub 4} nanoparticles anchored on graphene nanosheets as high-performance cathode material for lithium-ion batteries

    SciTech Connect (OSTI)

    Lin, Binghui; Yin, Qing; Hu, Hengrun; Lu, Fujia [School of Materials Science and Engineering, Nanjing University of Science and Technology, Xiaolingwei 200, Nanjing, Jiangsu 210094 (China); Xia, Hui, E-mail: xiahui@njust.edu.cn [School of Materials Science and Engineering, Nanjing University of Science and Technology, Xiaolingwei 200, Nanjing, Jiangsu 210094 (China); Herbert Gleiter Institute of Nanoscience, Nanjing University of Science and Technology, Nanjing 210094 (China)

    2014-01-15T23:59:59.000Z

    Nanocrystalline LiMn{sub 2}O{sub 4}/graphene nanosheets nanocomposite has been successfully synthesized by a one-step hydrothermal method without post-heat treatment. In the nanocomposite, LiMn{sub 2}O{sub 4} nanoparticles of 10–30 nm in size are well crystallized and homogeneously anchored on the graphene nanosheets. The graphene nanosheets not only provide a highly conductive matrix for LiMn{sub 2}O{sub 4} nanoparticles but also effectively reduce the agglomeration of LiMn{sub 2}O{sub 4} nanoparticles. The nanocrystalline LiMn{sub 2}O{sub 4}/graphene nanosheets nanocomposite exhibited greatly improved electrochemical performance in terms of specific capacity, cycle performance, and rate capability compared with the bare LiMn{sub 2}O{sub 4} nanoparticles. The superior electrochemical performance of the nanocrystalline LiMn{sub 2}O{sub 4}/graphene nanosheets nanocomposite makes it promising as cathode material for high-performance lithium-ion batteries. - Graphical abstract: Nanocrystalline LiMn{sub 2}O{sub 4}/graphene nanosheets (GNS) nanocomposite exhibit superior cathode performance for lithium-ion batteries compared to the bare LiMn{sub 2}O{sub 4} nanoparticles. Display Omitted - Highlights: • LiMn{sub 2}O{sub 4}/graphene nanocomposite is synthesized by a one-step hydrothermal method. • LiMn{sub 2}O{sub 4} nanoparticles are uniformly anchored on the graphene nanosheets. • The nanocomposite exhibits excellent cathode performance for lithium-ion batteries.

  2. Topaz II preliminary safety assessment

    SciTech Connect (OSTI)

    Marshall, A.C. (Sandia National Labs., Albuquerque, NM (United States)); Standley, V. (Air Force Phillips Laboratory, Albuquerque, NM (United States)); Voss, S.S. (Los Alamos National Lab., NM (United States)); Haskin, E. (New Mexico Univ., Albuquerque, NM (United States). Dept. of Chemical and Nuclear Engineering)

    1992-01-01T23:59:59.000Z

    The Strategic Defense Initiative Organization (SDIO) decided to investigate the possibility of launching a Russian Topaz 11 space nuclear power system. A preliminary safety assessment was conducted to determine whether or not a space mission could be conducted safely and within budget constraints. As part of this assessment, a safety policy and safety functional requirements were developed to guide both the safely assessment and future Topaz II activities. A review of the Russian flight safety program was conducted and documented. Our preliminary safety assessment included a top level event tree, neutronic analysis of normal and accident configurations, an evaluation of temperature coefficients of reactivity, a reentry and disposal analysis, and analysis of postulated launch abort impact accidents, and an analysis of postulated propellant fire and explosion accidents. Based on the assessment, it appears that it will be possible to safely launch the Topaz II system in the US with some possible system modifications. The principal system modifications will probably include design changes to preclude water flooded criticality and to assure intact reentry.

  3. The imaginary quadratic fields of class number two

    E-Print Network [OSTI]

    Merritt, Michael Henry

    2012-06-07T23:59:59.000Z

    number 1 or 2 is still an unsolved problem~ However? if h denotes the class num'her of the imaginary quadratic field R(~+m) (m ~0)? Heilbronn [5j has shown that = ~? Hence the number of imaginary quadratic fields with given class num'her h is 1'inite... by the induction hypothesis& 'Y and E can each be expressed as a product of prime integers Thus 4 is expressible as a product of prime integers? In general, unique factoriaatiou into primes does not exist in R(~ For exampIe, in R(?/-5) we have 6 = 2? 3? (1 + ~5...

  4. Black Holes and Universality Classes of Critical Points

    SciTech Connect (OSTI)

    Kovtun, Pavel; Ritz, Adam [Department of Physics and Astronomy, University of Victoria, Victoria, British Columbia, V8P 5C2 (Canada)

    2008-05-02T23:59:59.000Z

    We argue that there exists an infinite class of conformal field theories in diverse dimensions having a universal ratio of the central charge c to the normalized entropy density c-tilde. The universality class includes all conformal theories which possess a classical gravity dual according to the AdS/CFT correspondence. From the practical point of view, the universality of c/c-tilde provides an explicit test which can be applied to determine whether a given critical point may admit a dual description in terms of classical gravity.

  5. Second order hydrodynamics for a special class of gravity duals

    SciTech Connect (OSTI)

    Springer, T. [School of Physics and Astronomy, University of Minnesota, Minneapolis, Minnesota 55455 (United States)

    2009-04-15T23:59:59.000Z

    The sound mode hydrodynamic dispersion relation is computed up to order q{sup 3} for a class of gravitational duals which includes both Schwarzschild AdS and Dp-brane metrics. The implications for second order transport coefficients are examined within the context of Israel-Stewart theory. These sound mode results are compared with previously known results for the shear mode. This comparison allows one to determine the third order hydrodynamic contributions to the shear mode for the class of metrics considered here.

  6. ROYAUME DU MAROC Universit Hassan II -Casablanca

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ROYAUME DU MAROC Université Hassan II - Casablanca Faculté des Science Ben M'sik Casablanca UFR'Sik, Université Hassan II, Casablanca, Maroc Président BENNAMARA Ahmed Professeur à la Faculté des Sciences Ben M'Sik, Université Hassan II, Casablanca, Maroc Rapporteur TALBI Mohammed Professeur à la Faculté des Sciences Ben M

  7. Mass Spectrometer: Single Particle (SPLAT II) | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    nano- and micro-scales. SPLAT II's applications include but are not limited to climate, air pollution, human health, bioterrorism, and emerging nanotechnologies. Portability is a...

  8. Microsoft Word - Vol II.docx

    Office of Legacy Management (LM)

    Volume II Institutional Controls Plan January 2014 U.S. Department of Energy Revision 7 Final This page intentionally left blank Emergency Contact Legacy Management 24-hour...

  9. Site Environmental Report for 2008, Volume II

    E-Print Network [OSTI]

    Lackner, Regina

    2009-01-01T23:59:59.000Z

    Volume I: Collection Stack Air Ambient Air Rainwater Creekscollection activities Volume II section Stormwater Ambient Air; RainwaterRainwater Radiological Activity Analyte Gross alpha Location* ENV-44 Collection

  10. Giant Protease TPP II's Structure, Mechanism Uncovered

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    proteins (a protease), is implicated in numerous cellular processes including the degradation of the endogenous satiety agent cholecystokinin-8, making TPP II a target in the...

  11. Concrete Pour in NSLS-II Ring

    ScienceCinema (OSTI)

    Bruno Semon

    2013-07-22T23:59:59.000Z

    The mezzanine floor of the ring building tunnel for NSLS-II was completed when the last concrete was placed in February 2011.

  12. Septiembre 2002 Calculo Numerico II (4o

    E-Print Network [OSTI]

    Quirós, Fernando

    Septiembre 2002 C´alculo Num´erico II (4o de Matem´aticas) 1er semestre 1. Responder razonadamente

  13. Site Environmental Report for 2008, Volume II

    E-Print Network [OSTI]

    Lackner, Regina

    2009-01-01T23:59:59.000Z

    Air; Soil Creeks; Rainwater; Stormwater; Sewer Sewer AmbientAir Ambient Air Rainwater Creeks Stormwater Sewer FixedII section Stormwater Ambient Air; Rainwater Ambient Air

  14. Southwest MN IPM STUFF All the pestilence that's fit to print

    E-Print Network [OSTI]

    Amin, S. Massoud

    and no precipitation the week of July 2-8. The crop responded with rapid growth and development. Flowering of wheat winter and wet spring - if crop production was fair. Based on the age class of these larvae, it still

  15. The synthesis and characterization of zinc(II) and copper(II) diphosphonatoalkanes

    E-Print Network [OSTI]

    Arnold, Deirdre I.

    2000-01-01T23:59:59.000Z

    THE SYNTHESIS AND CHARACTERIZATION OF ZINC(II) AND COPPER(II) DIPHOSPHONATOALKANES A Thesis by DEIRDRE I. ARNOLD Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree... of MASTER OF SCIENCE August 2000 Major Subject: Chemistry THE SYNTHESIS AND CHARACTERIZATION OF ZINC(II) AND COPPER(II) DIPHOSPHONATOALKANES A Thesis by DEIRDRE I. ARNOLD Submitted to Texas ARM University in partial fulfillment of the requirements...

  16. JOURNAL DE PHYSIQUE Colloque Cl, supplkment au no 4, Tome 38, Auril 1977, page Cl-303 MULTILAYER SINTERING OF MnZn FERRITES

    E-Print Network [OSTI]

    Boyer, Edmond

    SINTERING OF MnZn FERRITES IN CONTROLLED ATMOSPHERE M. I. ALAM, N. R. NAlR and T. V. RAMAMURTI Central dans la litterature que I'empilement depots de ferrites les uns sur les autres durant le traitement production des couches multiples d'echantillons de ferrite de Mn-Zn. On a utilise jusqu'a 10 couches d

  17. Atomic-Scale Spin-Polarized Scanning Tunneling Microscopy Applied To Mn3N2(010) Haiqiang Yang and Arthur R. Smith

    E-Print Network [OSTI]

    source effusion cell for Mn and a rf plasma source for N [5,6]. All STM imaging is performed at 300 K-centered tetragonal (fct) rock-salt type struc- ture. The bulk magnetic moments of the Mn atoms are FM within (001

  18. Free-Standing LiNi0.5Mn1.5O4/Carbon Nanofiber Network Film as Light-Weight and High-Power

    E-Print Network [OSTI]

    Zhou, Chongwu

    Free-Standing LiNi0.5Mn1.5O4/Carbon Nanofiber Network Film as Light-Weight and High-Power Cathode Pure carbon nanofiber (CNF) network without LiNi0.5Mn1.5O4 was tested in the voltage window of 3.5-5 V

  19. A Facile and Template-Free Hydrothermal Synthesis of Mn3O4 Nanorods on Graphene Sheets for Supercapacitor Electrodes with

    E-Print Network [OSTI]

    /Mn3O4 composites were prepared by a simple hydrothermal process from KMnO4 using ethylene glycolA Facile and Template-Free Hydrothermal Synthesis of Mn3O4 Nanorods on Graphene Sheets in Faradaic electron-transfer processes of a metal oxide or conducting poly- mer.3 It is also possible

  20. Suppression of the thermal hysteresis in magnetocaloric MnAs thin film by highly charged ion bombardment

    SciTech Connect (OSTI)

    Trassinelli, M., E-mail: martino.trassinelli@insp.jussieu.fr; Marangolo, M.; Eddrief, M.; Etgens, V. H.; Gafton, V.; Hidki, S.; Lacaze, E.; Lamour, E.; Prigent, C.; Rozet, J.-P.; Steydli, S.; Zheng, Y.; Vernhet, D. [CNRS, UMR 7588, Institut des NanoSciences de Paris (INSP), F-75005 Paris (France); Sorbonne Universités, UPMC Univ. Paris 06, UMR 7588, INSP, F-75005 Paris (France)

    2014-02-24T23:59:59.000Z

    We present the investigation on the modifications of structural and magnetic properties of MnAs thin film epitaxially grown on GaAs induced by slow highly charged ions bombardment under well-controlled conditions. The ion-induced defects facilitate the nucleation of one phase with respect to the other in the first-order magneto-structural MnAs transition, with a consequent suppression of thermal hysteresis without any significant perturbation on the other structural and magnetic properties. In particular, the irradiated film keeps the giant magnetocaloric effect at room temperature opening new perspective on magnetic refrigeration technology for everyday use.

  1. Enhancing structural transition by carrier and quantum confinement: Stabilization of cubic InN quantum dots by Mn incorporation

    SciTech Connect (OSTI)

    Meng, Xiuqing; Wu, Fengmin [Zhejiang Normal University, Jinhua, Zhejiang Province 321004 (China)] [Zhejiang Normal University, Jinhua, Zhejiang Province 321004 (China); Chen, Zhanghui; Li, Shu-Shen [State Key Laboratory for Superlattices and Microstructures, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083 (China)] [State Key Laboratory for Superlattices and Microstructures, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083 (China); Chen, Zhuo [Department of Physics, Beijing Institute of Technology, Beijing 100081 (China)] [Department of Physics, Beijing Institute of Technology, Beijing 100081 (China); Li, Jingbo, E-mail: jbli@semi.ac.cn, E-mail: swei@nrel.gov [Zhejiang Normal University, Jinhua, Zhejiang Province 321004 (China) [Zhejiang Normal University, Jinhua, Zhejiang Province 321004 (China); State Key Laboratory for Superlattices and Microstructures, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083 (China); Wu, Junqiao [Department of Materials Science and Engineering, University of California, Berkeley, California 94720 (United States)] [Department of Materials Science and Engineering, University of California, Berkeley, California 94720 (United States); Wei, Su-Huai, E-mail: jbli@semi.ac.cn, E-mail: swei@nrel.gov [National Renewable Energy Laboratory, Golden, Colorado 80401 (United States)] [National Renewable Energy Laboratory, Golden, Colorado 80401 (United States)

    2013-12-16T23:59:59.000Z

    We demonstrate in this work controllable synthesis of cubic InN nanocrystals through Mn doping. We show that the pristine nanocrystal has the wurtzite structure, but can be converted into the zinc-blende (ZB) structure when it is doped with Mn. Our first-principles calculations show that the phase transition is caused by the stronger p-d coupling between the host p valence state and the impurity d level in the ZB structure, which makes the hole generation in the ZB structure easier. Quantum confinement in the nanocrystals further enhanced this effect. This observation lays an important foundation for defects control of crystal phases.

  2. Quantum Critical Transition Amplifies Magnetoelastic Coupling in Mn[N(CN)2]2

    SciTech Connect (OSTI)

    Brinzari, T. V.; Chen, P.; Sun, Q.-C.; Liu, J.; Tung, L.-C.; Wang, Y.; Schlueter, J. A.; Singleton, J.; Manson, J. L.; Whangbo, M.-H.; Litvinchuk, A. P.; Musfeldt, J. L.

    2013-06-01T23:59:59.000Z

    We report the discovery of a magnetic quantum critical transition in Mn[N(CN)2]2 that drives the system from a canted antiferromagnetic state to the fully polarized state with amplified magnetoelastic coupling as an intrinsic part of the process. The local lattice distortions, revealed through systematic phonon frequency shifts, suggest a combined MnN6 octahedra distortion+counterrotation mechanism that reduces antiferromagnetic interactions and acts to accommodate the field-induced state. These findings deepen our understanding of magnetoelastic coupling near a magnetic quantum critical point and away from the static limit.

  3. AN EXTENDED CLASS OF NONLINEAR CONJUGATE GRADIENT METHODS \\Lambda

    E-Print Network [OSTI]

    Yuan, Ya-xiang

    AN EXTENDED CLASS OF NONLINEAR CONJUGATE GRADIENT METHODS \\Lambda Y. H. Dai and Y. Yuan State Key 100080, P. R. China. Email: dyh,yyx@lsec.cc.ac.cn Abstract Conjugate gradient methods are very important be analyzed uniformly, conjugate gradient methods are often analyzed individually. Recently, Dai and Yuan

  4. Green function diagonal for a class of heat equations

    E-Print Network [OSTI]

    Grzegorz Kwiatkowski; Sergey Leble

    2011-12-15T23:59:59.000Z

    A construction of the heat kernel diagonal is considered as element of generalized Zeta function, that, being meromorfic function, its gradient at the origin defines determinant of a differential operator in a technique for regularizing quadratic path integral. Some classes of explicit expression in the case of finite-gap potential coefficient of the heat equation are constructed.

  5. MATLAB tensor classes for fast algorithm prototyping : source code.

    SciTech Connect (OSTI)

    Bader, Brett William; Kolda, Tamara Gibson (Sandia National Laboratories, Livermore, CA)

    2004-10-01T23:59:59.000Z

    We present the source code for three MATLAB classes for manipulating tensors in order to allow fast algorithm prototyping. A tensor is a multidimensional or Nway array. This is a supplementary report; details on using this code are provided separately in SAND-XXXX.

  6. Energy and Momentum of a Class of Rotating Gravitational Waves

    E-Print Network [OSTI]

    M. Sharif

    2001-02-09T23:59:59.000Z

    We calculate energy and momentum for a class of cylindrical rotating gravitational waves using Einstein and Papapetrou's prescriptions. It is shown that the results obtained are reduced to the special case of the cylindrical gravitational waves already available in the literature.

  7. Linear Codes, Target Function Classes, and Network Computing Capacity

    E-Print Network [OSTI]

    Franceschetti, Massimo

    Linear Codes, Target Function Classes, and Network Computing Capacity Rathinakumar Appuswamy Submitted: May 6, 2011 Abstract We study the use of linear codes for network computing in single in network coding are applicable to network computing as well. Network computing problems arise in various

  8. DISCLAIMER & INSTRUCTIONS to Class A/B Operators

    E-Print Network [OSTI]

    Navara, Kristen

    : ­ Farm, residential, heating oil, septic, Flow-through process, hazardous wastes, stormwater, wastewater Class C Operators be trained in: ­ Location and function of emergency stop for pumps (slides 25 on duty during dispensing, (think of a typical gas station) ­ Farm or residential tank (

  9. On a Class of Renewal Processes in a Random Environment

    E-Print Network [OSTI]

    Patriksson, Michael

    On a Class of Renewal Processes in a Random Environment David Svensson April 12, 1998 #12; 1 #12 continuous lifelength distribution. A random environment is modelled by a positive recurrent birth and death, governed by the environment process and based on an underlying set of deterministic failure rate functions

  10. Franchising, Arbitration, and the Future of the Class Action

    E-Print Network [OSTI]

    Drahozal, Christopher R.; Wittrock, Quentin R.

    2009-01-01T23:59:59.000Z

    In this article, we consider whether arbitration clauses are likely to result in the extinction of the class action. In our view, the answer is no. We reach that conclusion for two main reasons. First, at least some parties that draft standard form...

  11. Focused Crawling of the Deep Web Using Service Class Descriptions

    SciTech Connect (OSTI)

    Rocco, D; Liu, L; Critchlow, T

    2004-06-21T23:59:59.000Z

    Dynamic Web data sources--sometimes known collectively as the Deep Web--increase the utility of the Web by providing intuitive access to data repositories anywhere that Web access is available. Deep Web services provide access to real-time information, like entertainment event listings, or present a Web interface to large databases or other data repositories. Recent studies suggest that the size and growth rate of the dynamic Web greatly exceed that of the static Web, yet dynamic content is often ignored by existing search engine indexers owing to the technical challenges that arise when attempting to search the Deep Web. To address these challenges, we present DynaBot, a service-centric crawler for discovering and clustering Deep Web sources offering dynamic content. DynaBot has three unique characteristics. First, DynaBot utilizes a service class model of the Web implemented through the construction of service class descriptions (SCDs). Second, DynaBot employs a modular, self-tuning system architecture for focused crawling of the DeepWeb using service class descriptions. Third, DynaBot incorporates methods and algorithms for efficient probing of the Deep Web and for discovering and clustering Deep Web sources and services through SCD-based service matching analysis. Our experimental results demonstrate the effectiveness of the service class discovery, probing, and matching algorithms and suggest techniques for efficiently managing service discovery in the face of the immense scale of the Deep Web.

  12. Scott Domain Representability of a Class of Generalized Ordered Spaces

    E-Print Network [OSTI]

    Lutzer, David J.

    -space constructed on a locally compact LOTS, is Scott-domain representable, i.e., is homeomorphic to the space-domain representable (i.e., being homeomorphic to the subspace of maximal elements of a Scott-domain with the ScottScott Domain Representability of a Class of Generalized Ordered Spaces Kevin W. Duke and David

  13. Class-based Bandwidth Management in Heterogeneous Wireless Networks

    E-Print Network [OSTI]

    Sreenan, Cormac J.

    function of band- width, packet loss, delay, and energy information using integer linear programming}@cs.ucc.ie 2 Electronics and Electrical Communications Dept., Cairo University, Egypt azahran, utility-based optimisation of network selection and resource allocation for clients of different classes

  14. Counting Complexity Classes over the Reals I: The Additive Case

    E-Print Network [OSTI]

    Bürgisser, Peter

    2 1 Faculty of Computer Science, Electrical Engineering, and Mathematics Paderborn University, D with the goal of providing numerical computations (as performed e.g., in numerical analysis or computational counting classes in the model of addi- tive BSS-machines [15]. The computation nodes of these machines

  15. A CLASS OF ESSENTIAL REPRESENTATIONS OF PRODUCT SYSTEMS

    E-Print Network [OSTI]

    Argerami, Martin

    A CLASS OF ESSENTIAL REPRESENTATIONS OF PRODUCT SYSTEMS REMUS FLORICEL Abstract. We construct a family of essential representations of an arbitrary product system by generalizing some techniques intro of the product system on unital vectors. In the sequel, this classification shows explicitly that any E0

  16. Final Report Encouraging Sustainable Practices in the Freshmen Class

    E-Print Network [OSTI]

    Aalberts, Daniel P.

    . Though the entire student body needs to participate in sustainable living in order to have the greatestGeos 206 Final Report May 2009 Encouraging Sustainable Practices in the Freshmen Class with proenvironmental habits, but those who may not be used to sustainable practices need not expect radical life

  17. A WWW-based in-class response system

    E-Print Network [OSTI]

    Gonzalez Barron, Raul

    1997-01-01T23:59:59.000Z

    ], and were developed at the University of Hawaii Office of Technology Transfer and Economic Development in cooperation with Maui Community College. This program also has the capability to be used in an in-class setting since it 22 grades the results...

  18. IMPROVING ELECTRIC FRAUD DETECTION USING CLASS IMBALANCE STRATEGIES

    E-Print Network [OSTI]

    that automatically detects suspicious behavior analyzing customers historical consumption curve. Thus, UTE's expertsIMPROVING ELECTRIC FRAUD DETECTION USING CLASS IMBALANCE STRATEGIES Mat´ias Di Martino, Federico, jmolinelli}@gmail.com Keywords: Electricity theft, Support vector machine, Optimum path forest, Unbalance

  19. Effects of Ti substitution on structural and magnetic properties of Zn–Mn ferrospinels

    SciTech Connect (OSTI)

    Patil, R.P., E-mail: raj_rbm_raj@yahoo.com [Department of Chemistry, Shivaji University, Kolhapur 416004 (India); Patil, N.M. [Department of Chemistry, Shivaji University, Kolhapur 416004 (India); Sasikala, R. [Chemistry Division, Bhabha Atomic Research Centre, Mumbai 400085 (India); Hankare, P.P., E-mail: p_hankarep@rediffmail.com [Department of Chemistry, Shivaji University, Kolhapur 416004 (India); Delekar, S.D. [Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University, Sub-campus Osmanabad, 413501 (India)

    2013-05-15T23:59:59.000Z

    Highlights: ? Novel system ZnMn{sub 1?x}Ti{sub x}FeO{sub 4} synthesized by sol–gel route. ? Nanocrystalline materials. ? Magnetic materials. - Abstract: Nanocrystalline ZnMn{sub 1?x}Ti{sub x}FeO{sub 4} (1.0 ? x ? 0) ferrites were prepared by sol–gel route. Formation of single phase cubic spinel structure for all the compositions was confirmed from their X-ray diffraction patterns. The lattice parameter shows an increasing trend with the increase in Ti content. These ferrite samples existed as crystalline nanoparticles of about 30–40 nm size as observed from transmission electron microscopy (TEM) technique. EDAX analysis indicated that the concentration of different elements in different compositions is in close agreement with the starting concentrations. Infrared spectra showed two main absorption bands in the range 400–800 cm{sup ?1} arising due to tetrahedral (A) and octahedral (B) stretching vibrations. The magnetic studies indicated that, the ferrimagnetic behavior increases with titanium substitution.

  20. ASYMPTOTIC STUDY OF SUBCRITICAL GRAPH CLASSES MICHAEL DRMOTA, ERIC FUSY, MIHYUN KANG, VERONIKA KRAUS

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ASYMPTOTIC STUDY OF SUBCRITICAL GRAPH CLASSES MICHAEL DRMOTA, ´ERIC FUSY, MIHYUN KANG, VERONIKA from the so-called "subcritical" graph classes, which include the classes of cacti graphs, outerplanar graphs chosen from subcritical classes. We show that the number gn/n! (resp. gn) of labelled (resp