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1

Advance View Proofs Thermodynamic Description of the Mg-Mn, Al-Mn and Mg-Al-Mn Systems  

E-Print Network [OSTI]

Advance View Proofs Thermodynamic Description of the Mg-Mn, Al-Mn and Mg-Al-Mn Systems Using-consistent thermodynamic model of the Mg-Mn, Al-Mn and Mg-Al-Mn systems has been developed. The major difference between work on the Al-Mn system that uses the same model for the liquid phase reveals that better agreement

Medraj, Mamoun

2

Modelling Al and Mn in the open ocean  

E-Print Network [OSTI]

Modelling Al and Mn in the open ocean Marco van Hulten*, Alessandro Tagliabue, Jean-Claude Dutay van Hulten: Modelling Al and Mn in the open ocean 1 #12;Outline Introduction Model of aluminium Constraining dust flux Model of manganese Conclusions Marco van Hulten: Modelling Al and Mn in the open ocean 2

Haak, Hein

3

Metastable phase boundaries of quasicrystalline phases. [Al-Mn; Al-Ru  

SciTech Connect (OSTI)

The melting curve (T/sub 0/) of the metastable icosahedral phase and the liquidus of the decagonal phase of Al-Mn have been obtained for 14 to 22 at. % Mn. Icosahedral Al-Mn has a congruent melting point of 910 +- 20/sup 0/C at 20 at. % Mn, and melts approx.30/sup 0/C lower than crystalline compounds with the same composition. Icosahedral Al/sub 82/Ru/sub 18/ was determined to melt at 1260 +- 30/sup 0/C. These results were obtained by forming single-phase icosahedral alloys with ion beam mixing, and by rapid heating to accurately known temperatures with electron beams.

Follstaedt, D.M.; Knapp, J.A.

1987-01-01T23:59:59.000Z

4

Electrodeposited Al-Mn Alloys with Microcrystalline, Nanocrystalline, Amorphous and Nano-quasicrystalline Structures  

E-Print Network [OSTI]

Al–Mn alloys with Mn content ranging from 0 to 15.8 at.% are prepared by electrodeposition from an ionic liquid at room temperature, and exhibit a remarkably broad range of structures. The alloys are characterized through ...

Ruan, Shiyun

5

Precipitation in cold-rolled Al–Sc–Zr and Al–Mn–Sc–Zr alloys prepared by powder metallurgy  

SciTech Connect (OSTI)

The effects of cold-rolling on thermal, mechanical and electrical properties, microstructure and recrystallization behaviour of the AlScZr and AlMnScZr alloys prepared by powder metallurgy were studied. The powder was produced by atomising in argon with 1% oxygen and then consolidated by hot extrusion at 350 °C. The electrical resistometry and microhardness together with differential scanning calorimetry measurements were compared with microstructure development observed by transmission and scanning electron microscopy, X-ray diffraction and electron backscatter diffraction. Fine (sub)grain structure developed and fine coherent Al{sub 3}Sc and/or Al{sub 3}(Sc,Zr) particles precipitated during extrusion at 350 °C in the alloys studied. Additional precipitation of the Al{sub 3}Sc and/or Al{sub 3}(Sc,Zr) particles and/or their coarsening was slightly facilitated by the previous cold rolling. The presence of Sc,Zr-containing particles has a significant antirecrystallization effect that prevents recrystallization at temperatures minimally up to 420 °C. The precipitation of the Al{sub 6}Mn- and/or Al{sub 6}(Mn,Fe) particles of a size ? 1.0 ?m at subgrain boundaries has also an essential antirecrystallization effect and totally suppresses recrystallization during 32 h long annealing at 550 °C. The texture development of the alloys seems to be affected by high solid solution strengthening by Mn. The precipitation of the Mn-containing alloy is highly enhanced by a cold rolling. The apparent activation energy of the Al{sub 3}Sc particles formation and/or coarsening and that of the Al{sub 6}Mn and/or Al{sub 6}(Mn,Fe) particle precipitation in the powder and in the compacted alloys were determined. The cold deformation has no effect on the apparent activation energy values of the Al{sub 3}Sc-phase and the Al{sub 6}Mn-phase precipitation. - Highlights: • The Mn, Sc and Zr additions to Al totally suppresses recrystallization at 550 °C. • The Sc,Zr-containing particle precipitation is slightly facilitated by cold rolling. • The Mn-containing particle precipitation is highly enhanced by cold rolling. • Cold rolling has no effect on activation energy of the Al{sub 3}Sc and Al{sub 6}Mn precipitation. • The texture development is affected by high solid solution strengthening by Mn.

Vlach, M., E-mail: martin.vlach@mff.cuni.cz [Charles University in Prague, Faculty of Mathematics and Physics, Ke Karlovu 3, CZ-121 16 Prague (Czech Republic); Stulikova, I.; Smola, B.; Kekule, T.; Kudrnova, H.; Danis, S. [Charles University in Prague, Faculty of Mathematics and Physics, Ke Karlovu 3, CZ-121 16 Prague (Czech Republic); Gemma, R. [King Abdullah University of Science and Technology (KAUST), Physical Sciences and Engineering Division, 23955-6900 Thuwal (Saudi Arabia); Ocenasek, V. [SVÚM a.s., Podnikatelská 565, CZ-190 11 Prague (Czech Republic); Malek, J. [Czech Technical University in Prague, Faculty of Mechanical Engineering, CZ-120 00 Prague (Czech Republic); Tanprayoon, D.; Neubert, V. [Institut für Materialprüfung und Werkstofftechnik, Freiberger Strasse 1, D-38678 Clausthal-Zellerfeld (Germany)

2013-12-15T23:59:59.000Z

6

Surface alloys of icosahedral AlMnSi with phason distortions  

SciTech Connect (OSTI)

The microstructures produced by electron-beam melting and by ion-beam mixing Al/Mn and Al/Mn/Si layers on Si substrates are examined. The treatments were found to incorporate Si from the substrate into the surface alloy. Several phases formed, depending on treatment, including ..cap alpha..- and ..beta..-AlMnSi, ..mu..-AlMn (epitaxial on Si(111), and amorphous and icosahedral AlMnSi. The observed microstructures relate the novel icosahedral phase to other phases and elucidate its formation kinetics. Diffraction patterns from large icosahedral grains (up to 5 ..mu..m) show distortions in the position and shape of weak (but not strong) reflections, as predicted for phason defects in a quasicrystalline lattice, one of the structures proposed for icosahedral phases.

Follstaedt, D.M.; Knapp, J.A.

1986-12-01T23:59:59.000Z

7

Surface structures of Al-Pd-Mn and Al-Cu-Fe icosahedral quasicrystals  

SciTech Connect (OSTI)

In this dissertation, the author reports on the surface structure of i-Al-Pd-Mn twofold, threefold, fivefold and i-Al-Cu-Fe fivefold surfaces. The LEED studies indicate the existence of two distinct stages in the regrowth of all four surfaces after Ar{sup +} sputtering. In the first stage, upon annealing at relatively low temperature: 500K--800K (depending on different surfaces), a cubic phase appears. The cubic LEED patterns transform irreversibly to unreconstructed quasicrystalline patterns upon annealing to higher temperatures, indicating that the cubic overlayers are metastable. Based upon the data for three chemically-identical, but symmetrically-inequivalent surfaces, a model is developed for the relation between the cubic overlayers and the quasicrystalline substrate. The model is based upon the related symmetries of cubic close-packed and icosahedral-packed materials. These results may be general among Al-rich, icosahedral materials. STM study of Al-Pd-Mn fivefold surface shows that terrace-step-kink structures start to form on the surface after annealing above 700K. Large, atomic ally-flat terraces were formed after annealing at 900K. Fine structures with fivefold icosahedral symmetry were found on those terraces. Data analysis and comparison of the STM images and structure model of icosahedral Al-Pd-Mn suggest that the fine structures in the STM images may be the pseudo Mackay (PMI) clusters which are the structure units of the structure model. Based upon his results, he can conclude that quasicrystalline structures are the stable structures of quasicrystal surfaces. In other words, quasicrystalline structures extend from the bulk to the surface. As a result of the effort reported in this dissertation, he believes that he has increased his understanding of the surface structure of icosahedral quasicrystals to a new level.

Shen, Z.

1999-02-12T23:59:59.000Z

8

Melting point measurements for quasicrystalline phases. [Al-Mn; icosahedral and decagonal phases  

SciTech Connect (OSTI)

Melting transitions of metastable quasicrystalline phases of Al-Mn have been observed using rapid electron-beam heating of fine-grained icosahedral surface layers. The congruent melting point for icosahedral Al/sub 80/Mn/sub 20/ was directly measured to be 910 +- 20/sup 0/C. Heating to higher temperatures shows another transition which is inferred to correspond to the liquidus of the decagonal phase at 965 +- 20/sup 0/C for 20 at. % Mn. The microstructure and formation kinetics of the decagonal phase are discussed, and its electron diffraction is described.

Knapp, J.A.; Follstaedt, D.M.

1986-01-01T23:59:59.000Z

9

Chobert MN et al LIVER PRECURSOR CELLS INCREASE HEPATIC FIBROSIS INDUCED BY CHRONIC  

E-Print Network [OSTI]

by chronic carbon tetrachloride (CCl4) administration for 6 weeks, in combination with chronic; CCl4, carbon tetrachloride; CK19, cytokeratin 19; CCR2, chemokine C-C motif receptor 2; EMTChobert MN et al LIVER PRECURSOR CELLS INCREASE HEPATIC FIBROSIS INDUCED BY CHRONIC CARBON

Boyer, Edmond

10

Characterization of Al-Mn particles in AZ91D investment castings  

SciTech Connect (OSTI)

Manganese is currently added to Mg-Al alloys in order to improve the corrosion behavior of cast components. A part of this manganese is dissolved in the magnesium matrix and the balance is found as fine Al(Mn,Fe) particles dispersed within castings. For AZ91D specimens prepared using the plaster mould investment casting process, these particles were observed in very large quantity at the surface of castings. These particles were characterized by scanning electron microscopy and electron probe microanalysis. It was found that they consist of Al{sub 8}Mn{sub 5} phase and that their morphology and size depend on local solidification conditions. Their presence at the surface of the castings is related to low solidification rates and reduced thermal gradients at the mould/metal interface.

Lun Sin, S. [Department of Mining, Metallurgical and Materials Engineering, Laval University, Quebec, Quebec, G1K 7P4 (Canada); Dube, D. [Department of Mining, Metallurgical and Materials Engineering, Laval University, Quebec, Quebec, G1K 7P4 (Canada)], E-mail: dominique.dube@gmn.ulaval.ca; Tremblay, R. [Department of Mining, Metallurgical and Materials Engineering, Laval University, Quebec, Quebec, G1K 7P4 (Canada)

2007-10-15T23:59:59.000Z

11

Determination of Mn valence states in mixed-valent manganates by XANES spectroscopy AlAin MAnceAu,1,  

E-Print Network [OSTI]

Cedex 9, France 2 Advanced Light Source, Lawrence Berkeley National Laboratory, One Cyclotron Road and phyllomanganates with no or little Mn3+ in the MnO2 layer exhibit intensi- ties, shapes, and relative energy catalysis, hazardous waste remediation, and rechargeable battery technology (Thackeray 1997; Toupin et al

12

Atomic moments in Mn2CoAl thin films analyzed by X-ray magnetic circular dichroism  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

Spin gapless semiconductors are known to be strongly affected by structural disorder when grown epitaxially as thin films. The magnetic properties of Mn2CoAl thin films grown on GaAs (001) substrates are investigated here as a function of annealing. This study investigates the atomic-specific magnetic moments of Mn and Co atoms measured through X-ray magnetic circular dichroism as a function of annealing and the consequent structural ordering. The results indicate that the structural distortion mainly affects the Mn atoms as seen by the reduction of the magnetic moment from its predicted value. (auth)

Jamer M.; Sterbinsky G.; Assaf, B.; Arena, D.; Heiman, D.

2014-12-07T23:59:59.000Z

13

Unoccupied electronic states of icosahedral Al-Pd-Mn quasicrystals: Evidence of image potential resonance and pseudogap  

SciTech Connect (OSTI)

We study the unoccupied region of the electronic structure of the fivefold symmetric surface of an icosahedral (i) Al-Pd-Mn quasicrystal. A feature that exhibits parabolic dispersion with an effective mass of (1.15ą0.1)me and tracks the change in the work function is assigned to an image potential resonance because our density functional calculation shows an absence of band gap in the respective energy region. We show that Sn grows pseudomorphically on i?Al?Pd?Mn as predicted by density functional theory calculations, and the energy of the image potential resonance tracks the change in the work function with Sn coverage. The image potential resonance appears much weaker in the spectrum from the related crystalline Al-Pd-Mn surface, demonstrating that its strength is related to the compatibility of the quasiperiodic wave functions in i?Al?Pd?Mn with the free-electron-like image potential states. Our investigation of the energy region immediately above EF provides unambiguous evidence for the presence of a pseudogap, in agreement with our density functional theory calculations.

Maniraj, M [UGC-DAE Confortium for Scientific Research; Rai, Abhishek [UGC-DAE Confortium for Scientific Research; Barman, S R [UGC-DAE Confortium for Scientific Research; Krajci, M [Slovak Academy of Sciences; Schlagel, Deborah L [Ames Laboratory; Lograsso, Thomas A [Ames Laboratory; Horn, K [Fritz-Haber-Institut der Max-Planck-Gesellschaft

2014-09-01T23:59:59.000Z

14

Evidence for triplet superconductivity in Josephson junctions with barriers of the ferromagnetic Heusler alloy Cu2MnAl  

E-Print Network [OSTI]

Evidence for triplet superconductivity in Josephson junctions with barriers of the ferromagnetic have studied Josephson junctions with barriers prepared from the Heusler compound Cu2MnAl. In the as metal. Measurements on lateral Josephson junctions with half metallic CrO2 Ref. 7 and the rare

Martinis, John M.

15

E-Print Network 3.0 - al fe mn Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

National Cheng Kung University Collection: Physics 4 Valence states of transition-metal ions in cubic perovskites SrMn1-xFexO3 H. J. Lee,a Summary: the Mn 3d resonance and...

16

Conditions for spin-gapless semiconducting behavior in Mn{sub 2}CoAl inverse Heusler compound  

SciTech Connect (OSTI)

Employing ab initio electronic structure calculations, we investigate the conditions for spin-gapless semiconducting (SGS) behavior in the inverse Mn{sub 2}CoAl Heusler compound. We show that tetragonalization of the lattice, which can occur during films growth, keeps the SGS character of the perfect cubic compound. On the contrary, atomic swaps even between sites with different local symmetry destroy the SGS character giving rise to a half-metallic state. Furthermore, the occurrence of Co-surplus leads also to half-metallicity. Thus, we propose that in order to achieve SGS behavior during the growth of Mn{sub 2}CoAl (and similar SGS Heusler compounds) thin films, one should minimize the occurrence of defects, while small deformations of the lattice, due to the lattice mismatch with the substrate, do not play a crucial role.

Galanakis, I., E-mail: galanakis@upatras.gr [Department of Materials Science, School of Natural Sciences, University of Patras, GR-26504 Patra (Greece); Özdo?an, K., E-mail: kozdogan@yildiz.edu.tr [Department of Physics, Yildiz Technical University, 34210 ?stanbul (Turkey); ?a??o?lu, E.; Blügel, S. [Peter Grünberg Institut and Institute for Advanced Simulation, Forschungszentrum Jülich and JARA, 52425 Jülich (Germany)

2014-03-07T23:59:59.000Z

17

Magneto-transport properties of oriented Mn{sub 2}CoAl films sputtered on thermally oxidized Si substrates  

SciTech Connect (OSTI)

Spin gapless semiconductors are interesting family of materials by embracing both magnetism and semiconducting due to their unique band structure. Its potential application in future spintronics requires realization in thin film form. In this Letter, we report fabrication and transport properties of spin gapless Mn{sub 2}CoAl films prepared on thermally oxidized Si substrates by magnetron sputtering deposition. The films deposited at 673?K are well oriented to (001) direction and display a uniform-crystalline surface. Magnetotransport measurements on the oriented films reveal a semiconducting-like resistivity, small anomalous Hall conductivity, and linear magnetoresistance representative of the transport signatures of spin gapless semiconductors. The magnetic properties of the films have also been investigated and compared to that of bulk Mn{sub 2}CoAl, showing small discrepancy induced by the composition deviation.

Xu, G. Z.; Du, Y.; Zhang, X. M.; Liu, E. K.; Wang, W. H., E-mail: wenhong.wang@iphy.ac.cn; Wu, G. H. [State Key Laboratory for Magnetism, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Zhang, H. G. [College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124 (China)

2014-06-16T23:59:59.000Z

18

20072200350/ 1966 1970 1974 1978 1982 1986 1990 1994 1998  

E-Print Network [OSTI]

Movements from North America to Asia 1,000TEU West Coast East Coast & Gulf Loading (1) #12; CO2LNG LNG LNG 12.5 25 1100(14) 1 16 #12; #12; (DME) #12; #12; #12; #12; (International) #12; #12; #12; LNG #12

Ishii, Hitoshi

19

Atomic moments in Mn2CoAl thin films analyzed by X-ray magnetic circular dichroism  

SciTech Connect (OSTI)

Spin gapless semiconductors are known to be strongly affected by structural disorder when grown epitaxially as thin films. The magnetic properties of Mn2CoAl thin films grown on GaAs (001) substrates are investigated here as a function of annealing. This study investigates the atomic-specific magnetic moments of Mn and Co atoms measured through X-ray magnetic circular dichroism as a function of annealing and the consequent structural ordering. The results indicate that the structural distortion mainly affects the Mn atoms as seen by the reduction of the magnetic moment from its predicted value. (auth)

Jamer M.; Sterbinsky G.; Assaf, B.; Arena, D.; Heiman, D.

2014-12-07T23:59:59.000Z

20

Improved Hydrogen Storage Performance of MgH2-LiAlH4 Composite by Addition of MnFe2O4  

E-Print Network [OSTI]

/L) densities are extremely eager for on-board hydrogen storage in fuel cell vehicles according to the U.S. DOE great potential as a catalyst to promote MgH2- LiAlH4 system hydrogen storage performances. MotivatedImproved Hydrogen Storage Performance of MgH2-LiAlH4 Composite by Addition of MnFe2O4 Qi Wan, Ping

Volinsky, Alex A.

Note: This page contains sample records for the topic "mn al 1970-1974" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Anti-site disorder and improved functionality of Mn{sub 2}NiX (X = Al, Ga, In, Sn) inverse Heusler alloys  

SciTech Connect (OSTI)

Recent first-principles calculations have predicted Mn{sub 2}NiX (X?=?Al, Ga, In, Sn) alloys to be magnetic shape memory alloys. Moreover, experiments on Mn{sub 2}NiGa and Mn{sub 2}NiSn suggest that the alloys deviate from the perfect inverse Heusler arrangement and that there is chemical disorder at the sublattices with tetrahedral symmetry. In this work, we investigate the effects of such chemical disorder on phase stabilities and magnetic properties using first-principles electronic structure methods. We find that except Mn{sub 2}NiAl, all other alloys show signatures of martensitic transformations in presence of anti-site disorder at the sublattices with tetrahedral symmetry. This improves the possibilities of realizing martensitic transformations at relatively low fields and the possibilities of obtaining significantly large inverse magneto-caloric effects, in comparison to perfect inverse Heusler arrangement of atoms. We analyze the origin of such improvements in functional properties by investigating electronic structures and magnetic exchange interactions.

Paul, Souvik; Kundu, Ashis; Ghosh, Subhradip, E-mail: subhra@iitg.ernet.in [Department of Physics, Indian Institute of Technology Guwahati, Guwahati, Assam 781039 (India); Sanyal, Biplab [Department of Physics and Astronomy, Uppsala University, Box 516, 75120 Uppsala (Sweden)

2014-10-07T23:59:59.000Z

22

Mn-doped Ga(As,P) and (Al,Ga)As ferromagnetic semiconductors: Electronic structure calculations  

E-Print Network [OSTI]

A remarkable progress towards functional ferromagnetic semiconductor materials for spintronics has been achieved in p-type (Ga,Mn)As. Robust hole-mediated ferromagnetism has, however, been observed also in other III-V hosts such as antimonides, Ga...

Masek, J.; Kudrnovsky, J.; Maca, F.; Sinova, Jairo; MacDonald, A. H.; Campion, R. P.; Gallagher, B. L.; Jungwirth, T.

2007-01-01T23:59:59.000Z

23

Scanning tuneeling microscopy studies of fivefold surfaces of icosahedral Al-Pd-Mn quasicrystals and of thin silver films on those surfaces  

SciTech Connect (OSTI)

The present work in this dissertation mainly focuses on the clean fivefold surfaces of i-Al-Pd-Mn quasicrystals as well as the nucleation and growth of Ag films on these surfaces. In addition, Ag film growth on NiAl(110) has been explored in the frame of this dissertation. First, we have investigated the equilibration of a fivefold surface of icosahedral Al-Pd-Mn quasicrystal at 900-915 K and 925-950 K, using Omicron variable temperature scanning tunneling microscope (STM). Annealing at low temperatures resulted in many voids on some terraces while the others were almost void-free. After annealing at 925-950K, void-rich terraces became much rarer. Our STM images suggest that through growth and coalescence of the voids, a different termination becomes exposed on host terraces. All of these observations in our study indicate that even after the quasicrystalline terrace-step structure appears, it evolves with time and temperature. More specifically, based on the STM observations, we conclude that during the annealing a wide range of energetically similar layers nucleate as surface terminations, however, with increasing temperature (and time) this distribution gets narrower via elimination of the metastable void-rich terraces. Next, we have examined the bulk structural models of icosahedral Al-Pd-Mn quasicrystal in terms of the densities, compositions and interplanar spacings for the fivefold planes that might represent physical surface terminations. In our analyses, we mainly have focused on four deterministic models which have no partial or mixed occupancy but we have made some comparisons with an undeterministic model. We have compared the models with each other and also with the available experimental data including STM, LEED-IV, XPD and LEIS. In all deterministic models, there are two different families of layers (a pair of planes), and the nondeterministic model contains similar group of planes. These two families differ in terms of the chemical decoration of their top planes. Hence, we name them as Pd+(with Pd) and Pd-(without Pd). Based on their planer structure and the step height, it can be said that these two families can be viable surface terminations. However, besides the Pd content, these two sets differ in terms of relative densities of their top planes as well as the gap separating the layer from the nearest atomic plane. The experimental data and other arguments lead to the conclusion that the Pd- family is favored over the Pd+. This has an important implication on the interpretation of local motifs seen in the high resolution STM images. In other words, the dark stars are not formed by cut-Bergmans rather they are formed by cut-Mackays.

Unal, Baris

2008-12-01T23:59:59.000Z

24

Intrinsic magnetic, structural and resistivity properties of ferromagnetic Mn{sub 0.5}Zn{sub 0.5}Al{sub x}Fe{sub 2?x}O{sub 4} nanoparticles  

SciTech Connect (OSTI)

Highlights: ? Al{sup 3+} ion substituted Mn–Zn ferrite nanoparticles. ? Single phase cubic spinel structure changes with Al{sup 3+} substitution. ? Magnetization and coercivity decreased with increasing Al{sup 3+}. ? Resistivity increased with Al{sup 3+} substitution. - Abstract: In this work the nano-structural, magnetic and resistivity properties of Al{sup 3+} substituted Mn–Zn ferrites powders were investigated. Mn{sub 0.5}Zn{sub 0.5}Al{sub x}Fe{sub 2?x}O{sub 4} powders, where x = 0.0, 0.1, 0.2, 0.3, 0.4 and 0.5 were obtained by the sol–gel auto-combustion method. X-ray diffraction data indicate that, after substitution, all the samples consisted of the main spinel phase in combination with a small amount of a foreign Al{sub 2}O{sub 3} phase. The addition of Al{sup 3+} resulted in a reduction of particle size and density of the prepared samples. Cation distribution in the present study was estimated by using X-ray diffraction data. The tetrahedral site radii initially increased with Al{sup 3+} content while the octahedral site radii decreased with the Al{sup 3+} substitution. FTIR spectra show two strong absorption bands at 529–548 cm{sup ?1} and 445–452 cm{sup ?1} which are the typical bands for the cubic spinel crystal structure. The magnetic properties were measured by employing a vibrating sample magnetometer. It was observed that the saturation magnetization, coercivity and anisotropy field decreased with the increase of Al{sup 3+} substitution. Introduction of Al{sup 3+} ions into the Mn–Zn ferrite increased the values of the resistivity, especially in the lower temperature range.

Haralkar, S.J. [Department of Physics, Kulswamini College, Tuljapur, Osmanabad, MS (India); Kadam, R.H. [Materials Research Laboratory, Srikrishna Mahavidyalaya Gunjoti, Omerga, Osmanabad 413613, MS (India); More, S.S. [Department of Physics, Yashwantrao Chavan Mahavidyalaya, Tuljapur, Osmanabad, MS (India); Shirsath, Sagar E., E-mail: shirsathsagar@hotmail.com [Spin Device Technology Center, Faculty of Engineering, Shinshu University, Nagano 380-8553 (Japan); Mane, M.L. [Department of Physics, S.G.R.G. Shinde Mahavidyalaya, Paranda 413502, MS (India); Patil, Swati [Materials Research Laboratory, Srikrishna Mahavidyalaya Gunjoti, Omerga, Osmanabad 413613, MS (India); Mane, D.R. [Dr. Babasaheb Ambedkar Marathwada University, Aurangabad 431004, MS (India)

2013-03-15T23:59:59.000Z

25

AL  

E-Print Network [OSTI]

AL. EMERGENCY PREPAREDNESS SYLLABUS ATTACHMENT. EMERGENCY NOTIFICATION PROCEDURES are based on a simple concept - if you hear a.

26

Dissolved trace metals (Ni, Zn, Co, Cd, Pb, Al, and Mn) around the Crozet Islands, Southern Ocean  

E-Print Network [OSTI]

of trace elements such as Zn, Co, and Cd may be influenced by complexing ligands [e.g., Zn: Bruland, 1989; Ellwood and van den Berg, 2000; Co: Ellwood and van den Berg, 2001; Saito et al., 2004; Cd: Bruland, 1992

Paris-Sud XI, Université de

27

Ferromagnetism and magneto-transport properties of Mn{sub 0.92}Ca{sub 0.08}As thin film grown on Al{sub 2}O{sub 3}(0001) substrate  

SciTech Connect (OSTI)

The epitaxial Mn{sub 0.92}Ca{sub 0.08}As thin film was grown on Al{sub 2}O{sub 3}(0001) substrate by molecular beam epitaxy. The Curie temperature (T{sub C}) around 340?K was enhanced with the addition of Ca, compared to that of bulk MnAs (T{sub C}???318?K). The maxima magnetoresistance, ?2.08% at 0.7?T, was observed near the critical magnetic transition temperature. Moreover, the giant magnetocaloric effect was found with the maximum magnetic entropy change, ?200?J/kgK, around 330?K at 5?T.

Dung, Dang Duc; Van Thiet, Duong [Department of Physics, University of Ulsan, Ulsan 680-749 (Korea, Republic of); Department of General Physics, School of Engineering Physics, Ha Noi University of Science and Technology, 1 Dai Co Viet road, Ha Noi (Viet Nam); Anh Tuan, Duong; Cho, Sunglae, E-mail: slcho@ulsan.ac.kr [Department of Physics, University of Ulsan, Ulsan 680-749 (Korea, Republic of); Feng, Wuwei [School of Materials Science and Engineering, China University of Geosciences, Beijing 100083 (China)

2014-05-07T23:59:59.000Z

28

Giant magnetocaloric effect of Mn{sub 0.92}Ba{sub 0.08}As thin film grown on Al{sub 2}O{sub 3}(0001) substrate  

SciTech Connect (OSTI)

The epitaxial Mn{sub 0.92}Ba{sub 0.08}As thin film was grown on Al{sub 2}O{sub 3}(0001) substrate by molecular beam epitaxy. The Curie temperature (T{sub C}) around 350 K was enhanced with the addition of Ba, compared to that of bulk MnAs (T{sub C} {approx} 318 K). We have observed the linear resistivity versus the square of temperature and high negative magnetoresistance near Curie temperature. Moreover, the giant magnetocaloric effect was found with maximum magnetic entropy change, 65 J/kgK, around room temperature at 5 T.

Dang Duc Dung [Department of Physics, University of Ulsan, Ulsan 690-749 (Korea, Republic of); Department of General Physics, School of Engineering, Ha Noi University of Science and Technology, 1 Dai Co Viet road, Ha Noi (Viet Nam); Duong Anh Tuan; Duong Van Thiet; Shin, Yooleemi; Cho, Sunglae [Department of Physics, University of Ulsan, Ulsan 690-749 (Korea, Republic of)

2012-04-01T23:59:59.000Z

29

Effect of MnO on the microstructures, phase stability and mechanical properties of ceria-partially-stabilized zirconia (Ce-TZP) and Ce-TZP-Al sub 2 O sub 3 composites  

SciTech Connect (OSTI)

Effect of increasing amounts of MnO additions on the microstructures, phase stability and mechanical properties of ZrO{sub 2}-12 m% CeO{sub 2} and ZrO{sub 2}-12 m% CeO{sub 2}-10 w% Al{sub 2}O{sub 3} were studied. MnO suppressed grain growth in ZrO{sub 2}-12 m% CeO{sub 2}, while enhancing the mechanical properties significantly (strength=557 MPa, fracture toughness=9.3 MPa.(m){sup 1/2} at 0.2 w% MnO). The enhanced mechanical properties were achieved despite an increased stability of the tetragonal phase as evidenced by a lower burst transformation temperature (M{sub b}) and a reduced volume fraction of the monoclinic phase on the fracture surface. In ZrO{sub 2}-12 m% CeO{sub 2}-10 w% Al{sub 2}O{sub 3}, the addition of MnO suppressed the grain size of ZrO{sub 2}, while promoting grain growth and changing the morphology of Al{sub 2}O{sub 3}. More significantly, the stability of the tetragonal ZrO{sub 2} phase decreased (high M{sub b} temperature) with a concurrent increase in fracture toughness (13.2 MPa.(m){sup 1/2} at 2 w% MnO) and transformation plasticity (1.2% in four-point bending). The widths of the transformation zones observed adjacent to the fracture surfaces showed a consistent inverse relation to the transformation yield stress as would be expected from the mechanics of stress-induced phase transformation at crack tips. The improvements in mechanical properties obtained in the base Ce-TZP and the Ce-TZP-Al{sub 2}O{sub 3} composite ceramics with the addition of MnO are critically examined in the context of transformation toughening and other possible mechanisms.

Wang, J.S.; Tsai, J.F.; Shetty, D.K.; Virkar, A.V. (Department of Materials Science and Engineering, University of Utah, Salt Lake City, UT (USA))

1990-09-01T23:59:59.000Z

30

Structure and Electrochemistry of LiNi1/3Co1/3-yMyMn1/3O2 (M=Ti, Al, Fe) Positive Electrode Materials  

SciTech Connect (OSTI)

A series of materials based on the LiNi1/3Co1/3-yMyMn1/3O2 (M = Ti,Al,Fe) system has been synthesized and examined structurally and electrochemically. It is found that the changes in electrochemical performance depend highly on the nature of the substituting atom and its effect on the crystal structure. Substitution with small amounts of Ti4+ (y = 1/12) leads to the formation of a high-capacity and high-rate positive electrode material. Iron substituted materials suffer from an increased antisite defect concentration and exhibit lower capacities and poor rate capabilities. Single-phase materials are found for LiNi1/3Co1/3-yAlyMn1/3O2 when y<_ 1/4 and all exhibit decreased capacities when cycled to 4.3 V. However, an increase in rate performance and cycle stability upon aluminum substitution is correlated with an improved lamellar structure.

Wilcox, James; Patoux, Sebastien; Doeff, Marca

2009-01-14T23:59:59.000Z

31

BiFeO{sub 3}/La{sub 0.7}Sr{sub 0.3}MnO{sub 3} heterostructures deposited on spark plasma sintered LaAlO{sub 3} substrates  

SciTech Connect (OSTI)

Multiferroic BiFeO{sub 3} (BFO)/La{sub 0.7}Sr{sub 0.3}MnO{sub 3} heterostructured thin films were grown by pulsed laser deposition on polished spark plasma sintered LaAlO{sub 3} (LAO) polycrystalline substrates. Both polycrystalline LAO substrates and BFO films were locally characterized using electron backscattering diffraction, which confirmed the high-quality local epitaxial growth on each substrate grain. Piezoforce microscopy was used to image and switch the piezo-domains, and the results are consistent with the relative orientation of the ferroelectric variants with the surface normal. This high-throughput synthesis process opens the routes towards wide survey of electronic properties as a function of crystalline orientation in complex oxide thin film synthesis.

Pravarthana, D.; Lacotte, M.; David, A.; Prellier, W., E-mail: wilfrid.prellier@ensicaen.fr [Laboratoire CRISMAT, CNRS UMR 6508, ENSICAEN, Normandie Université, 6 Bd Maréchal Juin, F-14050 Caen Cedex 4 (France); Trassin, M. [Department of Physics, University of California, Berkeley, California 94720 (United States); Department of Materials, ETH, Wolfgang-Pauli-Str. 10, 8093 Zurich (Switzerland); Haw Chu, Jiun [Department of Physics, University of California, Berkeley, California 94720 (United States); Ramesh, R. [Department of Physics, University of California, Berkeley, California 94720 (United States); Department of Materials Science and Engineering, University of California, Berkeley, California 94720 (United States); Materials Science Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Salvador, P. A. [Department of Materials Science and Engineering, Carnegie Mellon University, 5000 Forbes Ave., Pittsburgh, Pennsylvania 15213 (United States)

2014-02-24T23:59:59.000Z

32

Structural And Physical Characterization of Tetranuclear [Mn**II(3)Mn**IV] And [Mn**II(2)Mn**III(2)] Valence-Isomer Manganese Complexes  

SciTech Connect (OSTI)

Two tetranuclear Mn complexes with an average Mn oxidation state of +2.5 have been prepared. These valence isomers have been characterized by a combination of X-ray crystallography, X-ray absorption spectroscopy, and magnetic susceptibility. The Mn{sup II}{sub 3}Mn{sup IV} tetramer has the Mn ions arranged in a distorted tetrahedron, with an S = 6 ground spin state, dominated by ferromagnetic exchange among the manganese ions. The Mn{sup II}{sub 2}Mn{sup III}{sub 2} tetramer also has a distorted tetrahedral arrangement of Mn ions but shows magnetic behavior, suggesting that it is a single-molecule magnet. The X-ray absorption near-edge structure (XANES) spectra for the two complexes are similar, suggesting that, while Mn XANES has sufficient sensitivity to distinguish between trinuclear valence isomers (Alexiou et al. Inorg. Chem. 2003, 42, 2185), similar distinctions are difficult for tetranuclear complexes such as that found in the photosynthetic oxygen-evolving complex.

Zaleski, C.M.; Weng, T.-C.; Dendrinou-Samara, C.; Alexiou, M.; Kanakaraki, P.; Hsieh, W.-Y.; Kampf, J.; Penner-Hahn, J.E.; Pecoraro, V.L.; Kessissoglou, D.P.

2009-05-28T23:59:59.000Z

33

Distinct local electronic structure and magnetism for Mn in amorphous Si and Ge  

E-Print Network [OSTI]

Li, A. P. et al. Magnetism in Mn x Ge 1-x semiconductorsElectronic Structure and Magnetism for Mn in Amorphous Sistructure that determines magnetism. Figure 3 shows XAS data

Zeng, Li

2010-01-01T23:59:59.000Z

34

Single Nanorod Devices for Battery Diagnostics: A Case Study on LiMn2O4  

E-Print Network [OSTI]

correlate well with the better cycling performance of Al-doped LiMn2O4 in our Li-ion battery tests: LiAl0Single Nanorod Devices for Battery Diagnostics: A Case Study on LiMn2O4 Yuan Yang, Chong Xie nanostructure devices as a powerful new diagnostic tool for batteries with LiMn2O4 nanorod materials

Cui, Yi

35

The helium abundances in HgMn and normal stars  

E-Print Network [OSTI]

The parameter-free model of diffusion in the atmospheres of HgMn stars (Michaud 1986; Michaud et al 1979) predicts that helium should sink below the He II ionization zone in order that diffusion of other elements may take place, and that all HgMn stars should have deficits of helium in their photospheres, with a minimum deficit of 0.3 dex. In this study, the Smith & Dworetsky (1993) sample of HgMn stars and normal comparison stars is examined, and the helium abundances determined by spectrum synthesis using echelle spectra taken at Lick Observatory and the AAT. The prediction is confirmed; all HgMn stars are deficient in He by as much as 1.5 dex. Also, two HgMn stars, HR7361 and HR7664, show clear evidence of helium stratification.

M. M. Dworetsky

2004-07-26T23:59:59.000Z

36

Bulk modulus and specific heat of B-site doped (La{sub 0.3}Pr{sub 0.7}){sub 0.65}Ca{sub 0.35}Mn{sub 1?x}B{sub x}O{sub 3} (B=Fe, Cr, Ru, Al, Ga)  

SciTech Connect (OSTI)

Specific heat (C{sub p}) thermal expansion (?) and Bulk modulus (B{sub T}) of lightly doped Rare Earth manganites (La{sub 0.3}Pr{sub 0.7}){sub 0.65}Ca{sub 0.35}Mn{sub 1?x}B{sub x}O{sub 3} (B{sup 3+}?=?Fe{sup 3+},Cr{sup 3+},Ga{sup 3+},Al{sup 3+},Ru4+); (0.3Mn{sub 0.97}Fe{sub 0.03}O{sub 3} as a function of temperature (10K?T? 200K) is found to be in agreement with the published data. The trend of variation of Debye temperature with B-site cationic radius is predicted probably for the first time for the B-site doped rare earth manganites.

Srivastava, Archana, E-mail: archanasaran01@gmail.com [Department of Physics, Sri Sathya Sai College for Women, Bhopal-462024 (India); Thakur, Rasna; Gaur, N. K. [Department of Physics, Barkatullah University, Bhopal-462026 (India)

2014-04-24T23:59:59.000Z

37

E-Print Network 3.0 - alloy ni-mn-ga single Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mathematics 35 Lattice dynamics and phonon softening in Ni-Mn-Al Heusler alloys Xavier Moya, Llus Maosa,* and Antoni Planes Summary: as 10% have been re- ported in single...

38

High Mn austenitic stainless steel  

DOE Patents [OSTI]

An austenitic stainless steel alloy includes, in weight percent: >4 to 15 Mn; 8 to 15 Ni; 14 to 16 Cr; 2.4 to 3 Al; 0.4 to 1 total of at least one of Nb and Ta; 0.05 to 0.2 C; 0.01 to 0.02 B; no more than 0.3 of combined Ti+V; up to 3 Mo; up to 3 Co; up to 1W; up to 3 Cu; up to 1 Si; up to 0.05 P; up to 1 total of at least one of Y, La, Ce, Hf, and Zr; less than 0.05 N; and base Fe, wherein the weight percent Fe is greater than the weight percent Ni, and wherein the alloy forms an external continuous scale including alumina, nanometer scale sized particles distributed throughout the microstructure, the particles including at least one of NbC and TaC, and a stable essentially single phase FCC austenitic matrix microstructure that is essentially delta-ferrite-free and essentially BCC-phase-free.

Yamamoto, Yukinori (Oak Ridge, TN) [Oak Ridge, TN; Santella, Michael L (Knoxville, TN) [Knoxville, TN; Brady, Michael P (Oak Ridge, TN) [Oak Ridge, TN; Maziasz, Philip J (Oak Ridge, TN) [Oak Ridge, TN; Liu, Chain-tsuan (Knoxville, TN) [Knoxville, TN

2010-07-13T23:59:59.000Z

39

Framework-incorporated Mn and Co analcime zeolites: Synthesis and characterization  

SciTech Connect (OSTI)

The framework-substituted cobalt and manganese analcime zeolites were synthesized via a direct hydrothermal approach. The obtained samples were characterized by XRD powder, SEM-EDX, nitrogen physical adsorption, Raman microscopy, diffuse reflectance UV-Vis and IR spectroscopy which complementarily demonstrated the incorporation of cobalt and manganese into the zeolites framework. The results showed that substitution of Mn and Co could be placed in two synthesis gels with same compositions containing Al/Mn=5 and Al/Co=4 mol ratios, respectively. In addition, with replacing Al with Mn and synthesis of Mn-modified analcime, zeolite with higher surface area and pore volume could be achieved than the Co modified analcime. - Graphical abstract: The images and adsorption-desorption isotherms of N{sub 2} at 77 K for (a) Co (b) Mn modified analcime. Highlights: Black-Right-Pointing-Pointer Synthesis of Co and Mn modified analcime for the first time. Black-Right-Pointing-Pointer Framework-incorporation of Co and Mn using the same silicate gel composition. Black-Right-Pointing-Pointer Applying several techniques to provide proofs for the characterization.

Azizi, Seyed Naser, E-mail: azizi@umz.ac.ir [Analytical Division, Faculty of Chemistry, University of Mazandaran, P.O. Box 47416-95447, Babolsar (Iran, Islamic Republic of); Ehsani Tilami, Salma [Analytical Division, Faculty of Chemistry, University of Mazandaran, P.O. Box 47416-95447, Babolsar (Iran, Islamic Republic of)] [Analytical Division, Faculty of Chemistry, University of Mazandaran, P.O. Box 47416-95447, Babolsar (Iran, Islamic Republic of)

2013-02-15T23:59:59.000Z

40

E-Print Network 3.0 - al pb zn Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

et al., 1993; Dejonghe, 1998), resulting in elevated concentrations of Zn, Pb... by atomic absorption spectroscopy (AAS) for Zn, Pb, Mn, Fe, Ca, Mg, K and Al, and by...

Note: This page contains sample records for the topic "mn al 1970-1974" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Structural and Magnetic Properties of Co-Mn-Sb Thin films  

SciTech Connect (OSTI)

Thin Co-Mn-Sb films of different compositions were investigated and utilized as electrodes in alumina based magnetic tunnel junctions with CoFe counterelectrode. The preparation conditions were optimized with respect to magnetic and structural properties. The Co-Mn-Sb/Al-O interface was analyzed by x-ray absorption spectroscopy and magnetic circular dichroism with particular focus on the element-specific magnetic moments. Co-Mn-Sb crystallizes in different complex cubic structures depending on its composition. The magnetic moments of Co and Mn are ferromagnetically coupled in all cases. A tunnel magnetoresistance ratio of up to 24% at 13 K was found and indicates that Co-Mn-Sb is not a ferromagnetic half-metal. These results are compared to recent works on the structure and predictions of the electronic properties.

Meinert, M.; Schmalhorst, J.-M.; Ebke, D.; Liu, N. N.; Thomas, A.; Reiss, G.; Kanak, J.; Stobiecki, T.; Arenholz, E.

2009-12-17T23:59:59.000Z

42

Darlington AL O'Reillys AL  

E-Print Network [OSTI]

CanungraCk Darlington AL Darlington Coom era R O'Reillys AL Beechmont AL Binna Burra AL BackCk Tyungun AL Numinbah Valley AL NerangR Natural Bridge Numinbah AL Little Nerang Dam AL Albert R Bromfleet AL Benobble AL Wolffdene AL Luscombe AL Wongawallan AL Mt Tamborine Canungra Pimpama R Laheys Lookout

Greenslade, Diana

43

Plutonium Oxidation and Subsequent Reduction by Mn (IV) Minerals  

SciTech Connect (OSTI)

Plutonium sorbed to rock tuff was preferentially associated with manganese oxides. On tuff and synthetic pyrolusite (Mn{sup IV}O{sub 2}), Pu(IV) or Pu(V) was initially oxidized, but over time Pu(IV) became the predominant oxidation state of sorbed Pu. Reduction of Pu(V/VI), even on non-oxidizing surfaces, is proposed to result from a lower Gibbs free energy of the hydrolyzed Pu(IV) surface species versus that of the Pu(V) or Pu(VI) surface species. This work suggests that despite initial oxidation of sorbed Pu by oxidizing surfaces to more soluble forms, the less mobile form of Pu, Pu(IV), will dominate Pu solid phase speciation during long term geologic storage. The safe design of a radioactive waste or spent nuclear fuel geologic repository requires a risk assessment of radionuclides that may potentially be released into the surrounding environment. Geochemical knowledge of the radionuclide and the surrounding environment is required for predicting subsurface fate and transport. Although difficult even in simple systems, this task grows increasingly complicated for constituents, like Pu, that exhibit complex environmental chemistries. The environmental behavior of Pu can be influenced by complexation, precipitation, adsorption, colloid formation, and oxidation/reduction (redox) reactions (1-3). To predict the environmental mobility of Pu, the most important of these factors is Pu oxidation state. This is because Pu(IV) is generally 2 to 3 orders of magnitude less mobile than Pu(V) in most environments (4). Further complicating matters, Pu commonly exists simultaneously in several oxidation states (5, 6). Choppin (7) reported Pu may exist as Pu(IV), Pu(V), or Pu(VI) oxic natural groundwaters. It is generally accepted that plutonium associated with suspended particulate matter is predominantly Pu(IV) (8-10), whereas Pu in the aqueous phase is predominantly Pu(V) (2, 11-13). The influence of the character of Mn-containing minerals expected to be found in subsurface repository environments on Pu oxidation state distributions has been the subject of much recent research. Kenney-Kennicutt and Morse (14), Duff et al. (15), and Morgenstern and Choppin (16) observed oxidation of Pu facilitated by Mn(IV)-bearing minerals. Conversely, Shaughnessy et al. (17) used X-ray Absorption near-edge spectroscopy (XANES) to show reduction of Pu(VI) by hausmannite (Mn{sup II}Mn{sub 2}{sup III}O{sub 4}) and manganite ({gamma}-Mn{sup III}OOH) and Kersting et al., (18) observed reduction of Pu(VI) by pyrolusite (Mn{sup IV}O{sub 2}). In this paper, we attempt to reconcile the apparently conflicting datasets by showing that Mn-bearing minerals can indeed oxidize Pu, however, if the oxidized species remains on the solid phase, the oxidation step competes with the formation of Pu(IV) that becomes the predominant solid phase Pu species with time. The experimental approach we took was to conduct longer term (approximately two years later) oxidation state analyses on the Pu sorbed to Yucca Mountain tuff (initial analysis reported by Duff et al., (15)) and measure the time-dependant changes in the oxidation state distribution of Pu in the presence of the Mn mineral pyrolusite.

KAPLAN, DANIEL

2005-09-13T23:59:59.000Z

44

Structure and magnetic properties of rf thermally plasma synthesized Mn and MnZn ferrite nanoparticles  

E-Print Network [OSTI]

Structure and magnetic properties of rf thermally plasma synthesized Mn and Mn­Zn ferrite has previously been shown to be a viable route to producing nanocrystalline magnetite and Ni ferrite nanoparticles. In this work nanocrystalline powders of Mn and Mn­Zn ferrites have been synthesized using a 50 k

McHenry, Michael E.

45

Mn-Fe base and Mn-Cr-Fe base austenitic alloys  

DOE Patents [OSTI]

Manganese-iron base and manganese-chromium-iron base austenitic alloys designed to have resistance to neutron irradiation induced swelling and low activation have the following compositions (in weight percent): 20 to 40 Mn; up to about 15 Cr; about 0.4 to about 3.0 Si; an austenite stabilizing element selected from C and N, alone or in combination with each other, and in an amount effective to substantially stabilize the austenite phase, but less than about 0.7 C, and less than about 0.3 N; up to about 2.5 V; up to about 0.1 P; up to about 0.01 B; up to about 3.0 Al; up to about 0.5 Ni; up to about 2.0 W; up to about 1.0 Ti; up to about 1.0 Ta; and with the remainder of the alloy being essentially iron.

Brager, Howard R. (Richland, WA); Garner, Francis A. (Richland, WA)

1987-01-01T23:59:59.000Z

46

ALS Visitors  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

including Ethan Crumlin (at right) about current research in energy storage and battery efficiency. Berkeleyside Editor Lance Knoble toured the ALS and Berkeley Lab with...

47

Giant magnetothermal conductivity in the NiMnIn ferromagnetic shape memory alloys  

E-Print Network [OSTI]

­10 It is well known that colossal magne- toresistance CMR in the Mn-based perovskites is closely related, this transition can be shifted to lower temperature and even totally suppressed by a magnetic field. The magnetic: 10.1063/1.2753710 Very recently, Kainuma et al. discovered magnetic-field- induced shape recovery

Zexian, Cao

48

E-Print Network 3.0 - al-si alloy reinforced Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

novembre1993 Summary: number): Li, Al, Si, Ca, Mn,Cu, Zn, Sr, Y, Zr, Ag and Rare Earth (RE) elements. Some minor alloying... ,which normally are considered as typical for...

49

Effect of Mn doping on the structural, morphological, optical...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mn doping on the structural, morphological, optical and magnetic properties of indium tin oxide films. Effect of Mn doping on the structural, morphological, optical and magnetic...

50

ALS@20  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation InInformation InExplosion Monitoring:Home|PhysicsGasandArgonneALS in the News ALS

51

ALS Spectrum  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07)Operations DuringALS DoctoralALSSpectroscopyALS

52

IMPROVEMENT OF CdMnTe DETECTOR PERFORMANCE BY MnTe PURIFICATION  

SciTech Connect (OSTI)

Residual impurities in manganese (Mn) are a big obstacle to obtaining high-performance CdMnTe (CMT) X-ray and gamma-ray detectors. Generally, the zone-refining method is an effective way to improve the material's purity. In this work, we purified the MnTe compounds combining the zone-refining method with molten Te, which has a very high solubility for most impurities. We confirmed the improved purity of the material by glow-discharge mass spectrometry (GDMS). We also found that CMT crystals from a multiply-refined MnTe source, grown by the vertical Bridgman method, yielded better performing detectors.

Kim, K.H.; Bolotnikov, A.E.; Camarda, G.S.; Tappero, R.; Hossain, A.; Cui, Y.; Yang, G.; Gul, R.; and James, R.B.

2011-04-25T23:59:59.000Z

53

Mn/DOT County Road Safety Plans  

E-Print Network [OSTI]

Roads Program !! Minnesota Central Safety Funds !! Foster safety culture among county stakeholders 41 Mn/DOT County Road Safety Plans CTS Annual Research Conference April 27 & 28, 2010 Howard Preston & Objectives !! Project Overview !! Schedule, Participating Counties, Approach !! Safety Emphasis Areas

Minnesota, University of

54

arXiv:1002.0800v1[astro-ph.GA]3Feb2010 Mon. Not. R. Astron. Soc. 000, 000000 (0000) Printed 3 February 2010 (MN LATEX style file v2.2)  

E-Print Network [OSTI]

February 2010 (MN LATEX style file v2.2) High resolution X-ray spectroscopy and imaging of Mrk 573 Stefano Astronomico di Roma (INAF), Via Frascati 33, I-00040 Monte Porzio Catone, Italy 3 February 2010 ABSTRACT We et al. 2003; Bianchi et al. 2006). Since the NLR is also believed to be #12;2 Stefano Bianchi, et al

Evans, Dan

55

AL. I  

Office of Legacy Management (LM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou areDowntown Site -MiamiYVE r 'Xxy";^it ! (-AL.

56

ALS Visitors  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert SouthwestTechnologies |November 2011Astudies smartHistory: The FirstUsers' ExecutiveALS

57

ALS Visitors  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert SouthwestTechnologies |November 2011Astudies smartHistory: The FirstUsers'ALS Visitors

58

Industry @ ALS  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert Southwest Region service area.Portaldefault Sign In AboutIn theIndustry @ ALS

59

ALS Spectrum  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07)Operations DuringALS DoctoralALSSpectroscopy

60

ALS Spectrum  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07)Operations DuringALS

Note: This page contains sample records for the topic "mn al 1970-1974" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Energy absorption in Ni-Mn-Ga/ polymer composites  

E-Print Network [OSTI]

In recent years Ni-Mn-Ga has attracted considerable attention as a new kind of actuator material. Off-stoichiometric single crystals of Ni2MnGa can regularly exhibit 6% strain in tetragonal martensites and orthorhombic ...

Feuchtwanger, Jorge

2006-01-01T23:59:59.000Z

62

Theory of weak localization in ferromagnetic (Ga,Mn)As  

E-Print Network [OSTI]

We study quantum interference corrections to the conductivity in (Ga,Mn)As ferromagnetic semiconductors using a model with disordered valence-band holes coupled to localized Mn moments through a p-d kinetic-exchange interaction. We find that at Mn...

Garate, Ion; Sinova, Jairo; Jungwirth, T.; MacDonald, A. H.

2009-01-01T23:59:59.000Z

63

MN4602 Crouch 2004 REASSESSING WEAPON SYSTEM  

E-Print Network [OSTI]

MN4602 Crouch 2004 REASSESSING WEAPON SYSTEM OPERATIONAL TEST & EVALUATION METHODOLOGIES LTC Thom support assessing a weapon systems true cost and performance characteristics? S1: Can/should cost, operational effectiveness and suitability be assessed independent of one another? S2: Do current test

64

"MBUF Demo" "Mn Road Fee Test"  

E-Print Network [OSTI]

(40 mpg) Electric Vehicle (non-gas powered) State Tax * Federal Tax ** State Tax * Federal Tax"MBUF Demo" "Mn Road Fee Test" "IntelliDrive Connected Vehicles for Safety, Mobility and User Fee Overview Six Months In-Vehicle Data Collection Participant Recruited Equipment Deployed First Odometer

Minnesota, University of

65

Mn/DOT's Project Peer Review  

E-Print Network [OSTI]

and sustain this culture #12;Project Management #12;Recent National Work in Transportation Project ManagementMn/DOT's Project Management Peer Review Creating a Project Management Culture 2010 CTS Research a Peer Review? Why Project Management? ¡Improve project delivery performance ­ on time, on budget (an

Minnesota, University of

66

Helical antiferromagnetic ordering in Lu1-xScxMnSi  

SciTech Connect (OSTI)

Polycrystalline samples of Lu1?xScxMnSi (x=0, 0.25, 0.5) are studied using powder x-ray diffraction, heat capacity Cp, magnetization, magnetic susceptibility ?, and electrical resistivity ? measurements versus temperature T and magnetic field H. This system crystallizes in the primitive orthorhombic TiNiSi-type structure (space group Pnma) as previously reported. The ?(T) data indicate metallic behavior. The Cp(T), ?(T), and ?(T) measurements consistently indicate long-range antiferromagnetic (AF) transitions with AF ordering temperatures TN=246, 215, and 188 K for x=0, 0.25, and 0.5, respectively. A second transition is observed at somewhat lower T for each sample from the ?(T) and ?(T) measurements, which we speculate are due to spin reorientation transitions; these second transitions are completely suppressed in H=5.5 T. The Cp data below 10 K for each composition indicate an enhanced Sommerfeld electronic heat capacity coefficient for the series in the range ?=24–29 mJ/mol K2. The ?(T) measurements up to 1000 K were fitted by local-moment Curie-Weiss behaviors which indicate a low Mn spin S?1. The ? data below TN are analyzed using the Weiss molecular field theory for a planar noncollinear cycloidal AF structure with a composition-dependent pitch, following the previous neutron diffraction work of Venturini et al. [J. Alloys Compd. 256, 65 (1997)]. Within this model, the fits indicate a turn angle between Mn ordered moments along the cycloid axis of ?100? or ?145?, either of which indicate dominant AF interactions between the Mn spins in the Lu1?xScxMnSi series of compounds.

Goetsch, Ryan J [Ames Laboratory; Anand, V K [Ames Laboratory; Johnston, David C [Ames Laboratory

2014-08-01T23:59:59.000Z

67

Temperature dependent electronic structure of Pr{sub 0.67}Sr{sub 0.33}MnO{sub 3} film probed by X-ray absorption near edge structure  

SciTech Connect (OSTI)

The Mn K edge X-ray absorption near edge structures (XANES) of Pr{sub 0.67}Sr{sub 0.33}MnO{sub 3} film (100 nm) on (001) LaAlO{sub 3} substrate was measured at different temperatures to probe the MnO{sub 6} octahedron distortion and corresponding electronic structure. The absorption of high temperature paramagnetic-insulator phase differed from that of the low temperature ferromagnetic-metal phase. The temperature-dependent absorption intensity of Mn K edge XANES was correlated with the relaxation of distorted MnO{sub 6} octahedron, which changed the crystal field acting on the Mn site and the related electronic structure and properties. At low temperature, the splitting of Mn majority e{sub g} orbitals decreased and the density of states above the Fermi level increased in the relaxed MnO{sub 6} octahedron, as reflected by a wider separation between two sub-peaks in the pre-edge XANES spectra.

Zhang, Bangmin [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Department of Materials Science and Engineering, National University of Singapore, Singapore 117576 (Singapore); NUSNNI-Nanocore, National University of Singapore, Singapore 117411 (Singapore); Sun, Cheng-Jun, E-mail: cjsun@aps.anl.gov, E-mail: msecgm@nus.edu.sg; Heald, Steve M. [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Chen, Jing-Sheng; Moog Chow, Gan, E-mail: cjsun@aps.anl.gov, E-mail: msecgm@nus.edu.sg [Department of Materials Science and Engineering, National University of Singapore, Singapore 117576 (Singapore); Venkatesan, T. [NUSNNI-Nanocore, National University of Singapore, Singapore 117411 (Singapore); Department of Physics, National University of Singapore, Singapore 117542 (Singapore); Department of Electrical and Computer Engineering, National University of Singapore, Singapore 117576 (Singapore)

2014-05-07T23:59:59.000Z

68

,"International Falls, MN Natural Gas Pipeline Imports From Canada...  

U.S. Energy Information Administration (EIA) Indexed Site

International Falls, MN Natural Gas Pipeline Imports From Canada (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of...

69

,"Noyes, MN Natural Gas Pipeline Imports From Canada (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Imports From Canada (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Noyes, MN...

70

,"Warroad, MN Natural Gas Pipeline Imports From Canada (MMcf...  

U.S. Energy Information Administration (EIA) Indexed Site

Imports From Canada (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Warroad, MN...

71

Alignment of micro-crystals of Mn12-acetate and direct observation of single molecules thereof  

E-Print Network [OSTI]

This dissertation focuses on three separate studies. First, magnetization of the Mn12- acetate was studied by low temperature hysteresis loops and DC magnetization data on magnetically aligned Mn12-acetate micro-crystals. Secondly, Mn12-acetate thin...

Seo, Dongmin

2009-05-15T23:59:59.000Z

72

-and -Coordinated Al in AlC2 . A Combined  

E-Print Network [OSTI]

- and -Coordinated Al in AlC2 - and AlCSi- . A Combined Photoelectron Spectroscopy and ab Initio the structure and chemical bonding in AlC2 - and AlCSi-. AlC2 - was found to have a C2V structure whereas AlCSi- was found to be almost linear, thus establishing -coordination of Al in AlC2 - and -coordination in Al

Simons, Jack

73

Minnesota Guidestar www.dot.state.mn.us/guidestar  

E-Print Network [OSTI]

.dot.state.mn.us/guidestar What is ITS? ˇ Application of technology to improve the safety and efficiency of the transportation system. #12;Minnesota Guidestar www.dot.state.mn.us/guidestar What is ITS? ˇ Traffic Management ­ Signal Systems ­ Ramp Meters ˇ Emergency Response ­ Mobile Data Terminals ­ 911 Dispatch ­ RF Data Networks

Minnesota, University of

74

Thermal Stability of MnBi Magnetic Materials  

SciTech Connect (OSTI)

MnBi attracts great attention in recent years for its great potential as permanent magnet materials. It is unique because its coercivity increases with increasing temperature, which makes it a good hard phase for exchange coupling nanocomposite magnet. MnBi phase is difficult to obtain, partly because the reaction between Mn and Bi is peritectic, and partly because Mn is easy to react with oxygen. MnO formation is irreversible and causes degradation to the magnetic properties. In this paper, we report our effort on developing MnBi permanent magnet. High purity MnBi (>90%) can be routinely produced in large quantity. The obtained powder exhibit 74 emu/g saturation magnetization at room temperature with 9 T applied field. After alignment, the powder exhibits 11.6 MGOe, and the sintered bulk magnet exhibit 7.8 MGOe at room temperature. Thermal stability study shows that the MnBi is stable up to 473 K in air.

Cui, Jun; Choi, Jung-Pyung; Li, Guosheng; Polikarpov, Evgueni; Darsell, Jens T.; Overman, Nicole R.; Olszta, Matthew J.; Schreiber, Daniel K.; Bowden, Mark E.; Droubay, Timothy C.; Kramer, Matthew J.; Zarkevich, Nikolai; Wang, L. L.; Johnson, Duane D.; Marinescu, Melania; Takeuchi, Ichiro; Huang, Qingzhen; Wu, Hui; Reeve, Hayden; Vuong, Nguyen V.; Liu, J.Ping

2014-01-01T23:59:59.000Z

75

Thermal stability of MnBi magnetic materials  

SciTech Connect (OSTI)

MnBi has attracted much attention in recent years due to its potential as a rare-earth-free permanent magnet material. It is unique because its coercivity increases with increasing temperature, which makes it a good hard phase material for exchange coupling nanocomposite magnets. MnBi phase is difficult to obtain, partly because the reaction between Mn and Bi is peritectic, and partly because Mn reacts readily with oxygen. MnO formation is irreversible and harmful to magnet performance. In this paper, we report our efforts toward developing MnBi permanent magnets. To date, high purity MnBi (>90%) can be routinely produced in large quantities. The produced powder exhibits 74:6 emu g1 saturation magnetization at room temperature with 9 T applied field. After proper alignment, the maximum energy product (BH) max of the powder reached 11.9 MGOe, and that of the sintered bulk magnet reached 7.8 MGOe at room temperature. A comprehensive study of thermal stability shows that MnBi powder is stable up to 473 K in air.

Cui, Jinfang [Pacific Northwest National Laboratory; Choi, J. P. [Pacific Northwest National Laboratory; Li, G. [Pacific Northwest National Laboratory; Polikarpov, E. [Pacific Northwest National Laboratory; Darsell, J. [Pacific Northwest National Laboratory; Overman, N. [Pacific Northwest National Laboratory; Olszta, M. [Pacific Northwest National Laboratory; Schreiber, D. [Pacific Northwest National Laboratory; Bowden, M. [Environmental Molecular Sciences Laboratory; Droubay, T. [Pacific Northwest National Laboratory; Kramer, Matthew J. [Ames Laboratory; Zarkevich, Nikolay A. [Ames Laboratory; Wang, L L. [Ames Laboratory; Johnson, Duane D. [Ames Laboratory; Marinescu, M. [Electron Energy Corporation; Takeuchi, I. [University of Maryland; Huang, Q. Z. [National Institute of Standards and Technology; Wu, H. [University of Maryland; Reeve, H. [United Technologies Research Center; Vuong, N. V. [University of Texas; Liu, J P. [University of Texas

2014-01-27T23:59:59.000Z

76

Spectroscopy of Mn atoms isolated in solid {sup 4}He  

SciTech Connect (OSTI)

We present an experimental study of the laser-induced luminescence spectra of Mn atoms in solid helium matrices. We observe transitions of the valence electron and of inner-shell electrons. We find that the Mn-He interaction perturbs the inner-shell transitions to a lesser extent than the valence-electron transitions. The observed lineshapes of the inner-shell transitions of Mn are similar to those of an inner-shell transition in Ba studied earlier. At the same time, they are more strongly perturbed than the corresponding transitions in Au and Cu under the same conditions. We suggest a qualitative explanation of these observations based on the atomic bubble model. Our results also suggest that the inner-shell transitions of Mn in solid He are more strongly perturbed than the same lines of Mn isolated in solid Ar or Kr matrices.

Moroshkin, P., E-mail: petr.moroshkin@riken.jp; Lebedev, V.; Weis, A. [Department of Physics, University of Fribourg, Chemin du Musée 3, 1700 Fribourg (Switzerland)

2014-06-07T23:59:59.000Z

77

Magnetic Moment Enhancement for Mn7 Cluster on Graphene  

SciTech Connect (OSTI)

Mn7 cluster on graphene with different structural motifs and magnetic orders are investigated systematically by first-principles calculations. The calculations show that Mn7 on graphene prefers a two-layer motif and exhibits a ferrimagnetic coupling. The magnetic moment of the Mn7 cluster increases from 5.0 ?B at its free-standing state to about 6.0 ?B upon adsorption on graphene. Mn7 cluster also induces about 0.3 ?B of magnetic moment in the graphene layer, leading to an overall enhancement of 1.3 ?B magnetic moment for Mn7 on graphene. Detail electron transfer and bonding analysis have been carried out to investigate the origin of the magnetic enhancement.

Liu, Xiaojie [Ames Laboratory; Wang, Cai-Zhuang [Ames Laboratory; Lin, Hai-Qing [Beijing Computational Science Research Center; Ho, Kai-Ming [Ames Laboratory

2014-08-21T23:59:59.000Z

78

Formation of MnSb during the growth of MnSi layers in the presence of an Sb flux  

E-Print Network [OSTI]

, Kawasaki 210-0855, Japan Y. Yan National Renewable Energy Laboratory, Golden, Colorado 80401 S. J a magnetic transition at TC 29.1 K from a paramag- netic state to a helicoidal order.3 An itinerant metamagnetic transition in MnSi has been observed,4,5 and magnetic prop- erties of MnSi under high pressure

Pennycook, Steve

79

Chemical and structural investigation of the role of both Mn and Mn oxide in the formation of manganese silicate barrier layers on SiO{sub 2}  

SciTech Connect (OSTI)

In this study, Mn silicate (MnSiO{sub 3}) barrier layers were formed on thermally grown SiO{sub 2} using both metallic Mn and oxidized Mn films, in order to investigate the role of oxygen in determining the extent of the interaction between the deposited Mn and the SiO{sub 2} substrate. Using x-ray photoelectron spectroscopy, it has been shown that a metallic Mn film with an approximate thickness of 1 nm cannot be fully converted to Mn silicate following vacuum annealing to 500 deg. C. Transmission electron microscopy (TEM) analysis suggests the maximum MnSiO{sub 3} layer thickness obtainable using metallic Mn is {approx}1.7 nm. In contrast, a {approx}1 nm partially oxidized Mn film can be fully converted to Mn silicate following thermal annealing to 400 deg. C, forming a MnSiO{sub 3} layer with a measured thickness of 2.6 nm. TEM analysis also clearly shows that MnSiO{sub 3} growth results in a corresponding reduction in the SiO{sub 2} layer thickness. It has also been shown that a fully oxidized Mn oxide thin film can be converted to Mn silicate, in the absence of metallic Mn. Based on these results it is suggested that the presence of Mn oxide species at the Mn/SiO{sub 2} interface facilitates the conversion of SiO{sub 2} to MnSiO{sub 3}, in agreement with previously published studies.

Casey, P.; Bogan, J.; Hughes, G. [School of Physical Sciences, Dublin City University, Glasnevin, Dublin 9 (Ireland); Lozano, J. G.; Nellist, P. D. [Department of Materials, University of Oxford, Parks Road, Oxford OX1 3PH (United Kingdom)

2011-09-01T23:59:59.000Z

80

Unusual Structure and Magnetism in MnO Nanoclusters  

E-Print Network [OSTI]

We report an unusual evolution of structure and magnetism in stoichiometric MnO clusters based on an extensive and unbiased search through the potential energy surface within density functional theory. The smaller clusters, containing up to five MnO units, adopt two-dimensional structures; and regardless of the size of the cluster, magnetic coupling is found to be antiferromagnetic in contrast to previous theoretical findings. Predicted structure and magnetism are strikingly different from the magnetic core of Mn-based molecular magnets, whereas they were previously argued to be similar. Both of these features are explained through the inherent electronic structures of the clusters.

Ganguly, Shreemoyee; Sanyal, Biplab; Mookerjee, Abhijit; 10.1103/PhysRevB.83.020411

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mn al 1970-1974" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Parallel Polarization EPR Characterization of the Mn(III) Center of Oxidized Manganese Superoxide  

E-Print Network [OSTI]

Parallel Polarization EPR Characterization of the Mn(III) Center of Oxidized Manganese Superoxide polarization CW-EPR to investigate the paramagnetic Mn3+ ion of the MnSOD enzyme from Escherichia coli with a positive axial zero-field splitting value, D, are arranged as shown in Figure 1. An EPR signal from the Mn

Miller, Anne-Frances

82

Solid state phase equilibria and intermetallic compounds of the Al-Cr-Ho system  

SciTech Connect (OSTI)

The solid state phase equilibria of the Al-Cr-Ho ternary system at 500 Degree-Sign C were experimentally investigated. The phase relations at 500 Degree-Sign C are governed by 14 three-phase regions, 29 two-phase regions and 15 single-phase regions. The existences of 10 binary compounds and 2 ternary phases have been confirmed. Al{sub 11}Cr{sub 2}, Al{sub 11}Cr{sub 4} and Al{sub 17}Ho{sub 2} were not found at 500 Degree-Sign C. Crystal structures of Al{sub 9}Cr{sub 4} and Al{sub 8}Cr{sub 4}Ho were determined by the Rietveld X-ray powder data refinement. Al{sub 9}Cr{sub 4} was found to exhibit cubic structure with space group I4-bar 3m (no. 217) and lattice parameters a=0.9107(5) nm. Al{sub 8}Cr{sub 4}Ho crystallizes in ThMn{sub 12} structure type with space group I4/mmm (no. 139) and lattice parameters a=0.8909(4) nm, c=0.5120(5) nm. It is concluded that the obtained Al{sub 4}Cr phase in this work should be {mu}-Al{sub 4}Cr by comparing with XRD pattern of the hexagonal {mu}-Al{sub 4}Mn compound. - Graphical abstract: The solid state phase equilibria of the Al-Cr-Ho ternary system at 500 Degree-Sign C. Highlights: Black-Right-Pointing-Pointer Al-Cr-Ho system has been investigated. Black-Right-Pointing-Pointer Al{sub 9}Cr{sub 4} has cubic structure with space group I4-bar 3m. Black-Right-Pointing-Pointer Al{sub 8}Cr{sub 4}Ho crystallizes in ThMn{sub 12} type with space group I4/mmm. Black-Right-Pointing-Pointer Al{sub 4}Cr phase is {mu}-type at 500 Degree-Sign C.

Pang, Mingjun [Laboratory of Nonferrous Metal Materials and New Processing Technology, Ministry of Education, Guangxi University, Nanning, Guangxi 530004 (China) [Laboratory of Nonferrous Metal Materials and New Processing Technology, Ministry of Education, Guangxi University, Nanning, Guangxi 530004 (China); SAIC-GM-Wuling Automobile Co., Ltd., Liuzhou, Guangxi 545007 (China); Zhan, Yongzhong, E-mail: zyzmatres@yahoo.com.cn [Laboratory of Nonferrous Metal Materials and New Processing Technology, Ministry of Education, Guangxi University, Nanning, Guangxi 530004 (China)] [Laboratory of Nonferrous Metal Materials and New Processing Technology, Ministry of Education, Guangxi University, Nanning, Guangxi 530004 (China); Du, Yong [State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083 (China)] [State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083 (China)

2013-02-15T23:59:59.000Z

83

Howes et al. Reply  

E-Print Network [OSTI]

Howes et al. Reply to Comment on "Kinetic Simulations of Magnetized Turbulence in Astrophysical Plasmas" arXiv:0711.4355

G. G. Howes; S. C. Cowley; W. Dorland; G. W. Hammett; E. Quataert; A. A. Schekochihin; T. Tatsuno

2008-12-12T23:59:59.000Z

84

Transverse acoustic actuation of Ni-Mn-Ga single crystals  

E-Print Network [OSTI]

Two methods for the transverse acoustic actuation of {110}-cut Ni-Mn-Ga single crystals are discussed. In this actuation mode, crystals are used that have the {110}- type twinning planes parallel to the base of the crystal. ...

Simon, Jesse Matthew

2007-01-01T23:59:59.000Z

85

Ambi-site substitution of Mn in lanthanum germanate apatites  

SciTech Connect (OSTI)

A neutron diffraction study at 4 K of the Mn doped lanthanum germanate apatite-type oxide ion conductor of nominal starting composition 'La{sub 9.5}Mn{sub 0.5}(GeO{sub 4}){sub 6}O{sub 2.75}' is reported. The structure was refined in space group P6{sub 3}/m, although high thermal displacement parameters were observed for the oxide ion sites (particularly O3, and O4). Reduced thermal displacement parameters were obtained by splitting the O3 site, and allowing the O4 oxygen to move off site, which may indicate local regions of lower symmetry within the structure. In addition, the data suggested ambi-site substitution of Mn, with it being present on both the Ge site and the La site. Assuming no change in La:Mn:Ge ratio, a composition of La{sub 9.18}Mn{sub 0.28}(GeO{sub 4}){sub 5.8}(MnO{sub 4}){sub 0.2}O{sub 2} was determined. As such there are nominally no interstitial oxide ions, but rather cation vacancies on the La site. Therefore, the high conductivity for this sample is most likely related to the introduction of Frenkel-type defects at higher temperature, as previously proposed for other apatite-type systems containing vacancies on the La site.

Kendrick, E. [Chemical Sciences, University of Surrey, Guildford, Surrey GU2 7XH (United Kingdom); Knight, K.S. [ISIS Facility, Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Didcot OX11 0QX (United Kingdom); Slater, P.R., E-mail: p.r.slater@bham.ac.uk [School of Chemistry, University of Birmingham, Edgbaston, Birmingham B15 2TT (United Kingdom)

2009-08-05T23:59:59.000Z

86

Magnetoluminescence of CdTe/MnTe/CdMgTe heterostructures with ultrathin MnTe layers  

SciTech Connect (OSTI)

CdTe/MnTe/CdMgTe quantum-well structures with one or two monolayers of MnTe inserted at CdTe/CdMgTe interfaces were fabricated. The spectra of the excitonic luminescence from CdTe quantum wells and their variation with temperature indicate that introduction of ultrathin MnTe layers improves the interface quality. The effect of a magnetic field in the Faraday configuration on the spectral position of the exciton-emission peaks indicates that frustration of magnetic moments in one-monolayer MnTe insertions is weaker than in two-monolayer insertions. The effect of a magnetic field on the exciton localization can be explained in terms of the exciton wave-function shrinkage and obstruction of the photoexcited charge-carrier motion in the quantum well.

Agekyan, V. F., E-mail: vfag@rambler.ru [St. Petersburg State University, Fock Institute of Physics (Russian Federation); Holz, P. O. [Polish Academy of Sciences, Institute of Physics (Poland); Karczewski, G. [Linkoeping University (Sweden); Katz, V. N. [St. Petersburg State University, Fock Institute of Physics (Russian Federation); Moskalenko, E. S. [Russian Academy of Sciences, Ioffe Physical Technical Institute (Russian Federation); Serov, A. Yu.; Filosofov, N. G. [St. Petersburg State University, Fock Institute of Physics (Russian Federation)

2011-10-15T23:59:59.000Z

87

Diversity of Mn oxides produced by Mn(II)-oxidizing fungi. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed Newcatalyst phasesDataTranslocationDiurnal Cycle of Convection atDiversity of Mn

88

Application of Mn/DOT Utility Coordination Process to Local Agencies Based on national best practices, the Minnesota Department of Transportation (Mn/DOT) Utility  

E-Print Network [OSTI]

Application of Mn/DOT Utility Coordination Process to Local Agencies Based on national best practices, the Minnesota Department of Transportation (Mn/DOT) Utility Coordination Process incorporates Processes There are projects where the full process is not necessary. The Mn/DOT Utilities Manual provides

Minnesota, University of

89

Comparison of the EXAFS Spectra of Heteronuclear MnCa/Sr Model Complexes to the Oxygen-Evolving Mn(4)Ca Complex of Photosystem II  

SciTech Connect (OSTI)

Heterometallic Mn-Ca and Mn-Sr complexes have been prepared and employed as model complexes for Ca and Sr EXAFS spectral comparisons with the Oxygen-Evolving Complex (OEC) of Photosystem II (PS II); these have revealed similarities that support the presence of at least one O atom bridge between the Mn and Ca/Sr in the OEC.

Mishra, A.; Yano, J.; Pushkar, Y.; Abboud, K.A.; Yachandra, V.K.; Christou, G.

2009-06-03T23:59:59.000Z

90

Magnetic properties of transition metal doped AlN nanosheet: First-principle studies  

SciTech Connect (OSTI)

We carry out our first-principles calculations within density functional theory to study the 3d transition metal (TM) doped AlN nanosheets. The calculated results indicate that a stoichiometric AlN nanosheet is graphene-like structure and nonmagnetic. The TM impurities can induce magnetic moments, localized mainly on the 3d TM atoms and neighboring N atoms. Our calculated results of TM-doped nanosheet systems indicate a strong interaction between 3d orbit of TM atom and the 2p orbit of N atoms. In addition, the Mn- and Ni-doped AlN nanosheet with half-metal characters seems to be good candidates for spintronic applications. When substituting two Al atoms, the relative energies of the states between ferromagnetic and antiferromagnetic coupling are investigated sufficiently. The exchange coupling of Co- and Ni-doped AlN nanosheets exhibits a transformation with different distances of two TM atoms and that of Cr-, Mn-, and Fe-doped AlN nanosheets is not changed.

Shi, Changmin; Qin, Hongwei, E-mail: qin-hw@vip.163.com; Zhang, Yongjia; Hu, Jifan; Ju, Lin [School of Physics, State Key Laboratory for Crystal Materials, Shandong University, Jinan 250100 (China)

2014-02-07T23:59:59.000Z

91

Hydrothermal synthesis and catalytic properties of {alpha}- and {beta}-MnO{sub 2} nanorods  

SciTech Connect (OSTI)

One-dimensional {alpha}-MnO{sub 2} and {beta}-MnO{sub 2} single-crystalline nanostructures were prepared by hydrothermal process. The products were characterized in detail by multiform techniques: X-ray diffraction, scanning electron microscopy, and transmission electron microscopy. Experimental results indicate that the temperature plays important roles in determining produce {alpha}-MnO{sub 2} and {beta}-MnO{sub 2} nanorods. In addition, the as-prepared {alpha}-MnO{sub 2} and {beta}-MnO{sub 2} nanorods showed excellent catalytic performance in the Fenton-like reaction.

Cao, Guangsheng, E-mail: daqingcgs@163.com [Key Laboratory of Enhanced Oil and Gas Recovery of Ministry of Education, Daqing Petroleum Institute, Daqing 163318 (China)] [Key Laboratory of Enhanced Oil and Gas Recovery of Ministry of Education, Daqing Petroleum Institute, Daqing 163318 (China); Su, Ling; Zhang, Xiaojuan; Li, Hui [Key Laboratory of Enhanced Oil and Gas Recovery of Ministry of Education, Daqing Petroleum Institute, Daqing 163318 (China)] [Key Laboratory of Enhanced Oil and Gas Recovery of Ministry of Education, Daqing Petroleum Institute, Daqing 163318 (China)

2010-04-15T23:59:59.000Z

92

Spin dependent transport properties of Mn-Ga/MgO/Mn-Ga magnetic tunnel junctions with metal(Mg, Co, Cr) insertion layer  

SciTech Connect (OSTI)

We report a first principles theoretical investigation of spin polarized quantum transport in Mn{sub 2}Ga/MgO/Mn{sub 2}Ga and Mn{sub 3}Ga/MgO/Mn{sub 3}Ga magnetic tunneling junctions (MTJs) with the consideration of metal(Mg, Co, Cr) insertion layer effect. By changing the concentration of Mn, our calculation shows a considerable disparity in transport properties: A tunneling magnetoresistance (TMR) ratio of 852% was obtained for Mn{sub 2}Ga-based MTJs, however, only a 5% TMR ratio for Mn{sub 3}Ga-based MTJs. In addition, the influence of insertion layer has been considered in our calculation. We found the Co insertion layer can increase the TMR of Mn{sub 2}Ga-based MTJ to 904%; however, the Cr insertion layer can decrease the TMR by 668%; A negative TMR ratio can be obtained with Mg insertion layer. Our work gives a comprehensive understanding of the influence of different insertion layer in Mn-Ga based MTJs. It is proved that, due to the transmission can be modulated by the interfacial electronic structure of insertion, the magnetoresistance ratio of Mn{sub 2}Ga/MgO/Mn{sub 2}Ga MTJ can be improved by inserting Co layer.

Liang, S. H.; Tao, L. L.; Liu, D. P., E-mail: dpliu@iphy.ac.cn; Han, X. F., E-mail: xfhan@iphy.ac.cn [State Key Laboratory of Magnetism, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Lu, Y. [Institut Jean Lamour, UMR 7198, CNRS-Nancy Université, BP 239, 54506 Vandoeuvre (France)

2014-04-07T23:59:59.000Z

93

A comparative study of magnetic behaviors in TbNi{sub 2}, TbMn{sub 2} and TbNi{sub 2}Mn  

SciTech Connect (OSTI)

All TbNi{sub 2}, TbMn{sub 2}, and TbNi{sub 2}Mn compounds exhibit the cubic Laves phase with AB{sub 2}-type structure in spite of the fact that the ratio of the Tb to transition-metal components in TbNi{sub 2}Mn is 1:3. Rietveld refinement indicates that in TbNi{sub 2}Mn the Mn atoms are distributed on both the A (8a) and B (16d) sites. The values of the lattice constants were measured to be a?=?14.348?Ĺ (space group F-43?m), 7.618?Ĺ, and 7.158?Ĺ (space group Fd-3?m) for TbNi{sub 2}, TbMn{sub 2}, and TbNi{sub 2}Mn, respectively. The magnetic transition temperatures T{sub C} were found to be T{sub C}?=?38?K and T{sub C}?=?148?K for TbNi{sub 2} and TbNi{sub 2}Mn, respectively, while two magnetic phase transitions are detected for TbMn{sub 2} at T{sub 1}?=?20?K and T{sub 2}?=?49?K. Clear magnetic history effects in a low magnetic field are observed in TbMn{sub 2} and TbNi{sub 2}Mn. The magnetic entropy changes have been obtained.

Wang, J. L., E-mail: jianli@uow.edu.au [Institute for Superconductivity and Electronic Materials, University of Wollongong, Wollongong, NSW 2522 (Australia); Bragg Institute, ANSTO, Lucas Heights, NSW 2234 (Australia); Md Din, M. F.; Hong, F.; Cheng, Z. X.; Dou, S. X. [Institute for Superconductivity and Electronic Materials, University of Wollongong, Wollongong, NSW 2522 (Australia); Kennedy, S. J.; Studer, A. J. [Bragg Institute, ANSTO, Lucas Heights, NSW 2234 (Australia); Campbell, S. J. [School of Physical, Environmental and Mathematical Sciences, The University of New South Wales, Canberra, ACT 2600 (Australia); Wu, G. H. [Institute of Physics, Chinese Academy of Science, Beijing 100190 (China)

2014-05-07T23:59:59.000Z

94

ALS Evidence Confirms Combustion Theory  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ALS Evidence Confirms Combustion Theory ALS Evidence Confirms Combustion Theory Print Wednesday, 22 October 2014 11:43 Researchers recently uncovered the first step in the process...

95

ALS in the News  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation InInformation InExplosion Monitoring:Home|PhysicsGasandArgonneALS in the News ALS in the

96

ALS in the News  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation InInformation InExplosion Monitoring:Home|PhysicsGasandArgonneALS in the News ALS in

97

LiMnPO4 Nanoplate Grown via Solid-State Reaction in Molten Hydrocarbon...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

LiMnPO4 Nanoplate Grown via Solid-State Reaction in Molten Hydrocarbon for Li-ion Battery Cathode. LiMnPO4 Nanoplate Grown via Solid-State Reaction in Molten Hydrocarbon for Li-ion...

98

Mn12-acetate thin film patterns and their interaction with superconductors  

E-Print Network [OSTI]

Mn12-acetate single-molecule magnets (SMMs) are nano-scale magnets showing a strong magnetic anisotropy, slow relaxation and stepwise magnetic hysteresis curves. Possible applications of Mn12-acetate, e.g. for ultra high density magnetic information...

Kim, Kyongwan

2009-05-15T23:59:59.000Z

99

On deformation twinning in a 17.5%Mn-TWIP steel: A physically...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

On deformation twinning in a 17.5%Mn-TWIP steel: A physically-based phenomenological model. On deformation twinning in a 17.5%Mn-TWIP steel: A physically-based phenomenological...

100

Pulsed laser deposition of Mn doped CdSe quantum dots for improved solar cell performance  

SciTech Connect (OSTI)

In this work, we demonstrate (1) a facile method to prepare Mn doped CdSe quantum dots (QDs) on Zn{sub 2}SnO{sub 4} photoanodes by pulsed laser deposition and (2) improved device performance of quantum dot sensitized solar cells of the Mn doped QDs (CdSe:Mn) compared to the undoped QDs (CdSe). The band diagram of photoanode Zn{sub 2}SnO{sub 4} and sensitizer CdSe:Mn QD is proposed based on the incident-photon-to-electron conversion efficiency (IPCE) data. Mn-modified band structure leads to absorption at longer wavelengths than the undoped CdSe QDs, which is due to the exchange splitting of the CdSe:Mn conduction band by the Mn dopant. Three-fold increase in the IPCE efficiency has also been observed for the Mn doped samples.

Dai, Qilin; Wang, Wenyong, E-mail: wwang5@uwyo.edu, E-mail: jtang2@uwyo.edu; Tang, Jinke, E-mail: wwang5@uwyo.edu, E-mail: jtang2@uwyo.edu [Department of Physics and Astronomy, University of Wyoming, Laramie, Wyoming 82071 (United States); Sabio, Erwin M. [Department of Chemistry, University of Wyoming, Laramie, Wyoming 82071 (United States)

2014-05-05T23:59:59.000Z

Note: This page contains sample records for the topic "mn al 1970-1974" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Engineering the magnetic properties of the Mn13 cluster by doping  

E-Print Network [OSTI]

With a goal to produce a giant magnetic moment in a Mn13 cluster that will be useful for practical applications, we have considered the structure and magnetic properties of a pure Mn13 cluster and substitutionally doped ...

Datta, Soumendu

102

X-ray absorption study of the electronic structure of Mn-doped amorphous Si  

E-Print Network [OSTI]

X-ray absorption study of the electronic structure of Mn-?x ) is studied by X-ray absorption spectroscopy at the Mn Land featureless L 3,2 absorption peaks, corresponding to an

Zeng, Li

2008-01-01T23:59:59.000Z

103

Effect of Composition and Heat Treatment on MnBi Magnetic Materials...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Abstract: The metallic compound MnBi is a promising rare-earth-free permanent magnet material. Compare to other rare-earth-free candidates, MnBi stands out for its high...

104

Disentangling the Mn moments on different sublattices in the half-metallic ferrimagnet Mn3?xCoxGa  

SciTech Connect (OSTI)

Ferrimagnetic Mn{sub 3-x}Co{sub x}Ga compounds have been investigated by magnetic circular dichroism in x-ray absorption (XMCD). Compounds with x > 0.5 crystallize in the CuHg{sub 2}Ti structure. A tetragonal distortion of the cubic structure occurs for x {le} 0.5. For the cubic phase, magnetometry reveals a linearly increasing magnetization of 2x Bohr magnetons per formula unit obeying the generalized Slater-Pauling rule. XMCD confirms the ferrimagnetic character with Mn atoms occupying two different sublattices with antiparallel spin orientation and different degrees of spin localization and identifies the region 0.6 < x {le} 0.8 as most promising for a high spin polarization at the Fermi level. Individual Mn moments on inequivalent sites are compared to theoretical predictions.

Klaer, P.; Jenkins, C.A.; Alijani, V.; Winterlik, J.; Balke, B.; Felser, C.; Elmers, H.J.

2011-05-03T23:59:59.000Z

105

Brambilla, et al. Reply  

E-Print Network [OSTI]

Brambilla, et al. Reply: van Megen and Williams (vMW) question our recent claim that dense colloidal hard spheres enter at large volume fraction \\phi a dynamical regime not observed in earlier work and not described by the mode-coupling theory (MCT) of the glass transition.

Giovanni Brambilla; Djamel El Masri; Matteo Pierno; Ludovic Berthier; Luca Cipelletti; George Petekidis; Andrew B. Schofield

2010-08-27T23:59:59.000Z

106

Novel frustrated magnetic lattice based on triangular [Mn3(m3-F)] clusters with tetrazole ligands{  

E-Print Network [OSTI]

Novel frustrated magnetic lattice based on triangular [Mn3(m3-F)] clusters with tetrazole ligands701840a Unprecedented [MnII 3(m3-F)(m-N­N)3] triangular clusters with tetrazole ligands are linked by Mn the tetrazolate ligands, which possess additional N-donor sites for network formation. To our knowledge, [M3(m3-X

Gao, Song

107

On the role of Mn(IV) vacancies in the photoreductive dissolution of hexagonal birnessite  

SciTech Connect (OSTI)

Photoreductive dissolution of layer type Mn(IV) oxides (birnessite) under sunlight illumination to form soluble Mn(II) has been observed in both field and laboratory settings, leading to a consensus that this process is a key driver of the biogeochemical cycling of Mn in the euphotic zones of marine and freshwater ecosystems. However, the underlying mechanisms for the process remain unknown, although they have been linked to the semiconducting characteristics of hexagonal birnessite, the ubiquitous Mn(IV) oxide produced mainly by bacterial oxidation of soluble Mn(II). One of the universal properties of this biogenic mineral is the presence of Mn(IV) vacancies, long-identified as strong adsorption sites for metal cations. In this paper, the possible role of Mn vacancies in photoreductive dissolution is investigated theoretically using quantum mechanical calculations based on spin-polarized density functional theory (DFT). Our DFT study demonstrates unequivocally that Mn vacancies significantly reduce the band-gap energy for hexagonal birnessite relative to a hypothetical vacancy-free MnO{sub 2} and thus would increase the concentration of photo-induced electrons available for Mn(IV) reduction upon illumination of the mineral by sunlight. Calculations of the charge distribution in the presence of vacancies, although not fully conclusive, show a clear separation of photo-induced electrons and holes, implying a slow recombination of these charge-carriers that facilitates the two-electron reduction of Mn(IV) to Mn(II).

Kwon, K.D.; Refson, K.; Sposito, G.

2009-06-01T23:59:59.000Z

108

Smith et al Supporting Information  

E-Print Network [OSTI]

Smith et al 1 Supporting Information for Smith et al. 2006, PLoS Computational Biology 2:e161-hyperpallium apicale; HF-hippocampal formation, and M-mesopallium. #12;Smith et al 2 FigureS2,nolinkswerefoundbetweenelectrodesindifferentbirds,andnolinkswerefoundintothesoundstimulusvariable. CombinedAnalysisofAllBirds'ElectrodesPlusSound #12;Smith et al 3 Analysis of Data from Subsections

Jarvis, Erich D.

109

Cationic disorder and Mn{sup 3+}/Mn{sup 4+} charge ordering in the B? and B? sites of Ca{sub 3}Mn{sub 2}NbO{sub 9} perovskite: a comparison with Ca{sub 3}Mn{sub 2}WO{sub 9}  

SciTech Connect (OSTI)

We describe the preparation, crystal structure determination, magnetic and transport properties of two novel Mn-containing perovskites, with a different electronic configuration for Mn atoms located in B site. Ca{sub 3}Mn{sup 3+}{sub 2}WO{sub 9} and Ca{sub 3}Mn{sup 3+/4+}{sub 2}NbO{sub 9} were synthesized by standard ceramic procedures; the crystallographic structure was studied from X-ray powder diffraction (XRPD) and neutron powder diffraction (NPD). Both phases exhibit a monoclinic symmetry (S.G.: P2{sub 1}/n); Ca{sub 3}Mn{sub 2}WO{sub 9} presents a long-range ordering over the B sites, whereas Ca{sub 3}Mn{sub 2}NbO{sub 9} is strongly disordered. By “in-situ” NPD, the temperature evolution of the structure study presents an interesting evolution in the octahedral size (?Mn–O?) for Ca{sub 3}Mn{sub 2}NbO{sub 9}, driven by a charge ordering effect between Mn{sup 3+} and Mn{sup 4+} atoms, related to the anomaly observed in the transport measurements at T?160 K. Both materials present a magnetic order below T{sub C}=30 K and 40 K for W and Nb materials, respectively. The magneto-transport measurements display non-negligible magnetoresistance properties in the paramagnetic regime. - Graphical abstract: Comparison between the octahedron size and the magnetic behaviour for Ca{sub 3}Mn{sub 2}NbO{sub 9} in the temperature region where the charge and magnetic order occur. Display Omitted - Highlights: • Two novel Mn-containing double perovskites were obtained by solid-state reactions. • Both double perovskites are monoclinic (P2{sub 1}/n) determined by XRPD and NPD. • Ca{sub 3}Mn{sub 2}WO{sub 9} contains Mn{sup 3+} while Ca{sub 3}Mn{sub 2}NbO{sub 9} includes mixed-valence cations Mn{sup 3+}/Mn{sup 4+}. • Ca{sub 3}Mn{sub 2}NbO{sub 9} presents a charge-ordering effect between Mn{sup 3+} and Mn{sup 4+} evidenced by NPD. • The magnetic and transport studies evidenced the charge ordering in Ca{sub 3}Mn{sub 2}NbO{sub 9}.

López, C.A., E-mail: calopez@unsl.edu.ar [INTEQUI-Área de Química General e Inorgánica “Dr. G. F. Puelles”, Facultad de Química, Bioquímica y Farmacia, Universidad Nacional de San Luis, Chacabuco y Pedernera, 5700 San Luis (Argentina); Centro Atómico Bariloche, Comisión Nacional de Energía Atómica and Instituto Balseiro, Universidad Nacional de Cuyo, 8400S.C. de Bariloche, Río Negro (Argentina); Saleta, M.E. [Centro Atómico Bariloche, Comisión Nacional de Energía Atómica and Instituto Balseiro, Universidad Nacional de Cuyo, 8400S.C. de Bariloche, Río Negro (Argentina); Pedregosa, J.C. [INTEQUI-Área de Química General e Inorgánica “Dr. G. F. Puelles”, Facultad de Química, Bioquímica y Farmacia, Universidad Nacional de San Luis, Chacabuco y Pedernera, 5700 San Luis (Argentina); Sánchez, R.D. [Centro Atómico Bariloche, Comisión Nacional de Energía Atómica and Instituto Balseiro, Universidad Nacional de Cuyo, 8400S.C. de Bariloche, Río Negro (Argentina); Alonso, J.A. [Instituto de Ciencia de Materiales de Madrid, CSIC, Cantoblanco, E-28049 Madrid (Spain); and others

2014-02-15T23:59:59.000Z

110

Growing the renewable chemicals and advanced biofuels cluster in MN  

E-Print Network [OSTI]

Growing the renewable chemicals and advanced biofuels cluster in MN #12;Renewable Chemical Value% Reduction 60% Reduction 0% 10% 20% 30% 40% 50% 60% 70% 80% 90% 100% Gasoline Corn Ethanol Advanced Biofuel Cellulosic Biofuel Corn Ethanol 20% GHG Reduction Compared to gasoline: Advanced Biofuel 50% GHG Reduction e

Levinson, David M.

111

Electronic interactions between gold films and mn12-acetate  

E-Print Network [OSTI]

the presence of a surface layer of Mn12–acetate, have been performed using a dilution refrigerator. Quantitative fits to the data using the predictions of weak localization theory were performed using a least-squares fit method in order to determine...

Means, Joel Lewis

2009-05-15T23:59:59.000Z

112

Mn/DOT's Ombudsman Program Collaboration and Process  

E-Print Network [OSTI]

Mn/DOT's Ombudsman Program Collaboration and Process #12;Overview Ombudsman exists to rebuild trust on the environmental and municipal consent processes can be critical #12;A Large Organization #12;Tragedy;Ombudsman Does Not... ˇ! Advocate for one party or point of view ˇ! Own any formal process or policy

Minnesota, University of

113

0 1 2 3 4 5 Fig. S1. Core photograph combined with Ca, Mn, Fe counts and Mn/Fe ratio determined by XRF core  

E-Print Network [OSTI]

1. Core photograph combined with Ca, Mn, Fe counts and Mn/Fe ratio determined by XRF core scanning determined by XRF core scanning on core ZH10-19 from Lake Zurich recovered in 135 m water depth (2 m above counts and Mn/Fe ratio determined by XRF core scanning on core ZH10-21 from Lake Zurich recovered in 123

Gilli, Adrian

114

(Ca,Na)(Zn,Mn){sub 2}As{sub 2}: A new spin and charge doping decoupled diluted ferromagnetic semiconductor  

SciTech Connect (OSTI)

Here, we report the successful synthesis of a spin- and charge-decoupled diluted magnetic semiconductor (DMS) (Ca,Na)(Zn,Mn){sub 2}As{sub 2}, crystallizing into the hexagonal CaAl{sub 2}Si{sub 2} structure. The compound shows a ferromagnetic transition with a Curie temperature up to 33?K with 10% Na doping, which gives rise to carrier density of n{sub p}???10{sup 20?}cm{sup ?3}. The new DMS is a soft magnetic material with H{sub C}?Mn doping, ferromagnetic order is accompanied by an interaction between the local spin and mobile charge, giving rise to a minimum in resistivity at low temperatures and localizing the conduction electrons. The system provides an ideal platform for studying the interaction of the local spins and conduction electrons.

Zhao, K.; Chen, B. J.; Deng, Z.; Zhao, G. Q.; Zhu, J. L.; Liu, Q. Q.; Wang, X. C. [Beijing National Laboratory for Condensed Matter Physics and Institute of Physics, Chinese Academy of Sciences, Collaborative Innovation Center of Quantum Matter, Beijing (China); Han, W. [Beijing National Laboratory for Condensed Matter Physics and Institute of Physics, Chinese Academy of Sciences, Collaborative Innovation Center of Quantum Matter, Beijing (China); Department of Physics, Chengde Mingzu College, Chengde (China); Frandsen, B.; Liu, L.; Cheung, S.; Uemura, Y. J. [Department of Physics, Columbia University, New York, New York 10027 (United States); Ning, F. L. [Department of Physics, Zhejiang University, Hangzhou 310027 (China); Munsie, T. J. S.; Medina, T.; Luke, G. M. [Department of Physics and Astronomy, McMaster University, Hamilton, L8S 4M1 (Canada); Carlo, J. P. [Department of Physics, Villanova University, Villanova, Pennsylvania 19085 (United States); Munevar, J. [Centro Brasileiro de Pesquisas Fisicas, Rio de Janeiro (Brazil); Zhang, G. M. [Department of Physics, Tsinghua University, Beijing (China); Jin, C. Q., E-mail: JIN@iphy.ac.cn [Beijing National Laboratory for Condensed Matter Physics and Institute of Physics, Chinese Academy of Sciences, Collaborative Innovation Center of Quantum Matter, Beijing (China); Department of Physics, Columbia University, New York, New York 10027 (United States)

2014-10-28T23:59:59.000Z

115

Optimization of chemical compositions in low-carbon Al-killed enamel steel produced by ultra-fast continuous annealing  

SciTech Connect (OSTI)

The influence of Mn,S and B contents on microstructural characteristics, mechanical properties and hydrogen trapping ability of low-carbon Al-killed enamel steel was investigated. The materials were produced and processed in a laboratory and the ultra-fast continuous annealing processing was performed using a continuous annealing simulator. It was found that increasing Mn,S contents in steel can improve its hydrogen trapping ability which is attributed by refined ferrite grains, more dispersed cementite and added MnS inclusions. Nevertheless, it deteriorates mechanical properties of steel sheet. Addition of trace boron results in both good mechanical properties and significantly improved hydrogen trapping ability. The boron combined with nitrogen segregating at grain boundaries, cementite and MnS inclusions, provides higher amount of attractive hydrogen trapping sites and raises the activation energy for hydrogen desorption from them. - Highlights: • We study microstructures and properties in low-carbon Al-killed enamel steel. • Hydrogen diffusion coefficients are measured to reflect fish-scale resistance. • Manganese improves hydrogen trapping ability but decrease deep-drawing ability. • Boron improves both hydrogen trapping ability and deep-drawing ability. • Both excellent mechanical properties and fish-scale resistance can be matched.

Dong, Futao, E-mail: dongft@sina.com [The State Key Laboratory of Rolling and Automation, Northeastern University, Shenyang 110819 (China); Du, Linxiu; Liu, Xianghua [The State Key Laboratory of Rolling and Automation, Northeastern University, Shenyang 110819 (China); Xue, Fei [College of Electrical Engineering, Hebei United University, Tangshan 063000 (China)

2013-10-15T23:59:59.000Z

116

Bending properties of epoxy resin matrix composites filled with NiMnGa ferromagnetic shape memory alloy powders  

E-Print Network [OSTI]

Bending properties of epoxy resin matrix composites filled with Ni­Mn­Ga ferromagnetic shape memory­Mn­Ga Composite materials Mechanical properties Microstructure Two types of epoxy resin matrix composites filled­Mn­Ga epoxy resin composites were reported, yet the bending property of Ni­Mn­Ga-polymer smart composites has

Zheng, Yufeng

117

PHYSICAL REVIEW B 84, 205305 (2011) Spin-phonon coupling in single Mn-doped CdTe quantum dot  

E-Print Network [OSTI]

PHYSICAL REVIEW B 84, 205305 (2011) Spin-phonon coupling in single Mn-doped CdTe quantum dot C. L dynamics of a single Mn atom in a laser driven CdTe quantum dot is addressed theoretically. Recent of single Mn-doped CdTe dots, information about the quantum spin state of a single Mn atom is extracted from

Paris-Sud XI, UniversitĂŠ de

118

Effect of Composition and Heat Treatment on MnBi Magnetic Materials  

SciTech Connect (OSTI)

The metallic compound MnBi is a promising rare-earth-free permanent magnet material. Compare to other rare-earth-free candidates, MnBi stands out for its high intrinsic coercivity (Hci) and its large positive temperature coefficient. Several groups have demonstrated that the Hci of MnBi compound in thin film or in powder form can exceed 12 kOe and 26 kOe at 300 K and 523 K, respectively. Such steep increase in Hci with increasing temperature is unique to MnBi. Consequently, MnBi is a highly sought-after hard phase for exchange coupling nanocomposite magnets. The reaction between Mn and Bi is peritectic, so Mn tends to precipitate out of the MnBi liquid during the solidification process. As result, the composition of the Mn-Bi alloy with the largest amount of the desired LTP (low temperature phase) MnBi and highest saturation magnetization will be over-stoichiometric and rich in Mn. The amount of additional Mn required to compensate the Mn precipitation depends on solidification rate: the faster the quench speed, the less Mn precipitates. Here we report a systematic study of the effect of composition and heat treatments on the phase contents and magnetic properties of Mn-Bi alloys. In this study, Mn-Bi alloys with 14 compositions were prepared using conventional metallurgical methods such as arc melting and vacuum heat treatment, and the obtained alloys were analyzed for compositions, crystal structures, phase content, and magnetic properties. The results show that the composition with 55 at.% Mn exhibits the highest LTP MnBi content and the highest magnetization. The sample with this composition shows >90 wt.% LTP MnBi content. Its measured saturation magnetization is 68 emu/g with 2.3 T applied field at 300 K; its coercivity is 13 kOe and its energy product is 12 MGOe at 300 K. A bulk magnet fabricated using this powder exhibits an energy product of 8.2 MGOe.

Cui, Jun; Choi, Jung-Pyung; Polikarpov, Evgueni; Bowden, Mark E.; Xie, Wei; Li, Guosheng; Nie, Zimin; Zarkevich, Nikolai; Kramer, Matthew J.; Johnson, Duane D.

2014-08-17T23:59:59.000Z

119

ALS Communications Group  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation InInformation InExplosion Monitoring:Home|PhysicsGasandArgonne LeadershipBeamlines ALS

120

About the ALS  

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Note: This page contains sample records for the topic "mn al 1970-1974" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

2015 ALS Shutdown  

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122

ALS Activity Reports  

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123

ALS Beamlines Directory  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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124

ALS Beamlines Directory  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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125

ALS Communications Group  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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126

ALS in the News  

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127

ALS Beamlines Directory  

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128

ALS Beamlines Directory  

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129

ALS Chemistry Lab  

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130

ALS Chemistry Lab  

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131

Charge transport properties of CdMnTe radiation detectors  

SciTech Connect (OSTI)

Growth, fabrication and characterization of indium-doped cadmium manganese telluride (CdMnTe)radiation detectors have been described. Alpha-particle spectroscopy measurements and time resolved current transient measurements have yielded an average charge collection efficiency approaching 100 %. Spatially resolved charge collection efficiency maps have been produced for a range of detector bias voltages. Inhomogeneities in the charge transport of the CdMnTe crystals have been associated with chains of tellurium inclusions within the detector bulk. Further, it has been shown that the role of tellurium inclusions in degrading chargecollection is reduced with increasing values of bias voltage. The electron transit time was determined from time of flight measurements. From the dependence of drift velocity on applied electric field the electron mobility was found to be n = (718 55) cm2/Vs at room temperature.

Kim K.; Rafiel, R.; Boardman, M.; Reinhard, I.; Sarbutt, A.; Watt, G.; Watt, C.; Uxa, S.; Prokopovich, D.A.; Belas, E.; Bolotnikov, A.E.; James, R.B.

2012-04-11T23:59:59.000Z

132

High-Resolution Mn EXAFS of the Oxygen-Evolving Complex inPhotosystem II: Structural Implications for the Mn4Ca Cluster  

SciTech Connect (OSTI)

The biological generation of oxygen by the oxygen-evolving complex in photosystem II (PS II) is one of natures most important reactions. The recent X-ray crystal structures, while limited by resolutions of 3.2 to 3.5 A, have located the electron density associated with the Mn4Ca complex within the multi-protein PS II complex. Detailed structures critically depend on input from spectroscopic techniques such as EXAFS and EPR/ENDOR, as the XRD resolution does not allow for accurate determination of the position of Mn/Ca or the bridging and terminal ligand atoms. The number and distances of Mn-Mn/Ca/ligand interactions determined from EXAFS provide important constraints for the structure of the Mn cluster. Here we present data from a high-resolution EXAFS method using a novel multi-crystal monochromator that show three short Mn-Mn distances between 2.7 and 2.8 A and hence the presence of three di-mu-oxobridged units in the Mn4Ca cluster. This result imposes clear limitations on the proposed structures based on spectroscopic and diffraction data and provides input for refining such structures.

Yano, Junko; Pushkar, Yulia; Glatzel, Pieter; Lewis, Azul; Sauer,Kenneth; Messinger, Johannes; Bergmann, Uwe; Yachandra, Vittal

2005-09-06T23:59:59.000Z

133

Ferromagnetic Mn moments at SrRuO3/SrMnO3 interfaces Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439  

E-Print Network [OSTI]

Ferromagnetic Mn moments at SrRuO3/SrMnO3 interfaces Y. Choia Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439 Y. Z. Yoo, O. Chmaissem, A. Ullah, S. Kolesnik, and C. W University, DeKalb, Illinois 60115 D. Haskel Advanced Photon Source, Argonne National Laboratory, Argonne

Haskel, Daniel

134

Magnetic field-induced phase transformation and variant reorientation in Ni2MnGa and NiMnCoIn magnetic shape memory alloys  

E-Print Network [OSTI]

The purpose of this work is to reveal the governing mechanisms responsible for the magnetic field-induced i) martensite reorientation in Ni2MnGa single crystals, ii) stress-assisted phase transformation in Ni2MnGa single crystals and iii) phase...

Karaca, Haluk Ersin

2009-05-15T23:59:59.000Z

135

Negative ion photodetachment spectroscopy of the Al3O2 , Al3O3 , Al4Ox , Al5Ox (x = 35), Al6O5 , and Al7O5 clusters  

E-Print Network [OSTI]

Negative ion photodetachment spectroscopy of the Al3O2 , Al3O3 , Al4Ox , Al5Ox (x = 3­5), Al6O5 , and Al7O5 clusters Giovanni Meloni, Michael J. Ferguson and Daniel M. Neumark Department of Chemistry as an Advance Article on the web 9th September 2003 The Al3O2 , Al3O3 , Al4Ox , Al5Ox (x Ÿ 3­5), Al6O5 , and Al7

Neumark, Daniel M.

136

Effect of composition and heat treatment on MnBi magnetic materials  

SciTech Connect (OSTI)

The metallic compound MnBi is a promising rare-earth-free permanent magnet material, unique among all candidates for its high intrinsic coercivity (Hci) and its large positive temperature coefficient. The Hci of MnBi in thin-film or powder form can exceed 12 and 26 kOe at 300 and 523 K, respectively. Such a steep rise in Hci with increasing temperature is unique to MnBi. Consequently, MnBi is a highly sought-after hard phase for exchange coupling nanocomposite magnets. However, the reaction between Mn and Bi is peritectic, and hence Mn tends to precipitate out of the MnBi liquid during the solidification process. As result, when the alloy is prepared using conventional induction or arc-melting casting methods, additional Mn is required to compensate the precipitation of Mn. In addition to composition, post-casting annealing plays an important role in obtaining a high content of MnBi low-temperature phase (LTP) because the annealing encourages the Mn precipitates and the unreacted Bi to react, forming the desired LTP phase. Here we report a systematic study of the effect of composition and heat treatments on the phase content and magnetic properties of Mn–Bi alloys. In this study, 14 compositions were prepared using conventional metallurgical methods, and the compositions, crystal structures, phase content and magnetic properties of the resulting alloys were analyzed. The results show that the composition with 55 at.% Mn exhibits both the highest LTP content (93 wt.%) and magnetization (74 emu g?1 with 9 T applied field at 300 K).

Cui, Jun [Pacific Northwest National Laboratory; Choi, Jung-Pyung [Pacific Northwest National Laboratory; Polikarpov, Evgueni [Pacific Northwest National Laboratory; Bowden, Mark E [Pacific Northwest National Laboratory; Xie, Wei [Pacific Northwest National Laboratory; Li, Guosheng [Pacific Northwest National Laboratory; Nie, Zimin [Pacific Northwest National Laboratory; Zarkevich, Nikolai [Ames Laboratory; Kramer, Matthew J [Ames Laboratory; Johnson, Duane [Ames Laboratory

2014-10-01T23:59:59.000Z

137

DOPING AND BOND LENGTH CONTRIBUTIONS TO Mn K-EDGE SHIFT IN La1-xSrxMnO3 AND THEIR CORRELATION WITH ELECTRICAL TRANSPORT BEHAVIOUR.  

SciTech Connect (OSTI)

The experimental Mn K-edge x-ray absorption spectra of La{sub 1-x}Sr{sub x}MnO{sub 3}, x = 0 - 0.7 are compared with the band structure calculations using spin polarized density functional theory. It is explicitly shown that there is a correspondence between the inflection point on the absorption edge and the center of gravity of the unoccupied Mn 4p-band. This correspondence has been used to separate the doping and size contributions to edge shift due to variation in number of electrons in valence band and Mn-O bond lengths, respectively when Sr is doped into LaMnO{sub 3}. Such separation is helpful to find the localization behavior of charge carriers and to understand the observed transport properties and type of charge carrier participating in the conduction process in these compounds.

PANDEY,S.K.; KHALID,S.; BINDU, R.; KUMAR, A.; PIMPALE, A.V.

2006-12-04T23:59:59.000Z

138

The massive transformation in Ti-Al alloys: mechanistic observations  

SciTech Connect (OSTI)

The massive {alpha}{yields}{gamma}{sub m} transformation, as observed using analytical transmission electron microscopy, in Ti-49Al, Ti-48Al-2Nb-2Mn, Ti-55Al-25Ta and Ti-50Al-20Ta alloys is described. Conventional solution heating and quenching experiments have been combined with the more rapid quenching possible using electron beam melting in order to provide further insight into the early stages of the transformation of these alloys. It is shown that the {gamma} develops first at grain boundaries as lamellae in one of the grains and that these lamellae intersect and spread into the adjacent grain in a massive manner. Consequently, there is no orientation relationship between the massive gamma ({gamma}{sub m}) and the grain being consumed whereas there is the expected relation between the {gamma}{sub m} and the first grain which is inherited from the lamellae. It is further shown that the {gamma}{sub m} grows as an f.c.c. phase after initially growing with the L1{sub 0} structure. Furthermore, it is shown that the massive f.c.c. phase then orders to the L1{sub 0} structure producing APDB-like defects which are actually thin 90{degree} domains separating adjacent domains that have the same orientation yet are out of phase. The advancing {gamma}{sub m} interface tends to facet parallel either to one of its four {l_brace}111{r_brace} planes or to the basal plane in the grain being consumed by impinging on existing {gamma} lamellae. Thin microtwins and {alpha}{sub 2} platelets then form in the {gamma}{sub m} presumably due, respectively, to transformation stresses and supersaturation of the {gamma}{sub m} with titanium for alloys containing {approximately}48% Al; indeed, there is a local depletion in aluminium across the {alpha}{sub 2} platelets as determined using fine probe microanalysis.

Zhang, X.D.; Godfrey, S.; Weaver, M.; Strangwood, M.; Kaufman, M.J.; Loretto, M.H. [Univ. of Birmingham, Edgbaston (United Kingdom). IRC in Materials for High Performance Applications] [Univ. of Birmingham, Edgbaston (United Kingdom). IRC in Materials for High Performance Applications; Threadgill, P. [Univ. of Birmingham, Edgbaston (United Kingdom). IRC in Materials for High Performance Applications] [Univ. of Birmingham, Edgbaston (United Kingdom). IRC in Materials for High Performance Applications; [TWI, Cambridge (United Kingdom)

1996-09-01T23:59:59.000Z

139

GAMETOPHYTIC SELF-INCOMPATIBILITY (Newbigin et al., 1993; Matton et al., 1994; Dodds et al., 1997)  

E-Print Network [OSTI]

GAMETOPHYTIC SELF-INCOMPATIBILITY (Newbigin et al., 1993; Matton et al., 1994; Dodds et al., 1997, but expressed at high levels in the style. d. There are high levels of this gene product in self-incompatible species, whereas very low levels in self-compatible species. f. Generalized features: #12;Self-incompatibility

Bhattacharyya, Madan Kumar

140

Improving high-capacity Li1.2Ni0.15Mn0.55Co0.1O2-based lithium-ion cells by modifiying the positive electrode with alumina  

E-Print Network [OSTI]

and EVs), they must meet a range of stringent criteria: for instance, energy densities high enoughImproving high-capacity Li1.2Ni0.15Mn0.55Co0.1O2-based lithium-ion cells by modifiying the positive-ion Atomic layer deposition Al2O3 Coating Secondary ion mass spectrometry Layered oxide a b s t r a c

Spila, Timothy P.

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141

Environmental effect on room-temperature ductility of isothermally forged TiAl-base alloys  

SciTech Connect (OSTI)

Isothermally forged TiAl-base alloy (Al-rich, Mn-containing, and Cr-containing TiAl) were heat-treated in various conditions, and equiaxed grain structures consisting of [gamma] and [alpha][sub 2] or [beta] phases were obtained. The heat-treated alloys were tensile tested in vacuum and air at room temperature, and the environmental effect on tensile elongation was studied. The ductility of the alloys consisting of equiaxed [gamma] grains and a large amount of [alpha][sub 2] grains was not largely affecting by laboratory air, and a decrease in the amount of [alpha][sub 2] grains resulted in a large reduction of ductility in air. The [beta] phase in the Cr-containing alloy improved the ductility in vacuum, but it resulted in a large reduction of ductility in air.

Nakamura, Morihiko; Hashimoto, Kenki (National Research Inst. for Metals, Tokyo (Japan)); Itoh, Naoyuki (Nippon Steel Corp., Chiba (Japan)); Tsujimoto, Tokuzo (Ibaraki Univ. (Japan). Faculty of Engineering); Suzuki, Toshiyuki (Kougakuin Univ., Tokyo (Japan))

1994-02-01T23:59:59.000Z

142

Effect of a high electric field on the conductivity of MnGa{sub 2}S{sub 4}, MnIn{sub 2}S{sub 4}, and MnGaInS{sub 4} single crystals  

SciTech Connect (OSTI)

The results of studying the effect of a high electric field on the conductivity of MnGa{sub 2}S{sub 4}, MnIn{sub 2}S{sub 4}, and MnGaInS{sub 4} single crystals are reported. The activation energy is determined in high and low electric fields. It is established that the decrease in the activation energy with increasing the external voltage is associated with decreasing the depth of the potential well, in which the electron is located.

Niftiev, N. N. [Azerbaijan State Pedagogical University (Azerbaijan); Tagiev, O. B. [National Academy of Sciences of Azerbaijan, Institute of Physics (Azerbaijan)

2009-09-15T23:59:59.000Z

143

IV. -PHOTOMAGNETISM AND CONDUCT I W r PHOTOMAGNETIC EFFECT IN A Li-Mn FERRITE  

E-Print Network [OSTI]

IV. - PHOTOMAGNETISM AND CONDUCT I W r PHOTOMAGNETIC EFFECT IN A Li-Mn FERRITE P. BERNSTEIN and T'effet photomagnCtique dans le ferrite Fez,I oLi0.45Mn0.4504 au moyen de la variation de la perm investigated in a Fez.loLi0.45Mn0.4504ferrite by looking at the variations of the permeability under light

Paris-Sud XI, UniversitĂŠ de

144

Electronic Structure and Oxidation State Changes in the Mn (4) Ca Cluster of Photosystem II  

SciTech Connect (OSTI)

Oxygen-evolving complex (Mn{sub 4}Ca cluster) of Photosystem II cycles through five intermediate states (S{sub i}-states, i = 0-4) before a molecule of dioxygen is released. During the S-state transitions, electrons are extracted from the OEC, either from Mn or alternatively from a Mn ligand. The oxidation state of Mn is widely accepted as Mn{sub 4}(III{sub 2},IV{sub 2}) and Mn{sub 4}(III,IV{sub 3}) for S{sub 1} and S{sub 2} states, while it is still controversial for the S{sub 0} and S{sub 3} states. We used resonant inelastic X-ray scattering (RIXS) to study the electronic structure of Mn{sub 4}Ca complex in the OEC. The RIXS data yield two-dimensional plots that provide a significant advantage by obtaining both K-edge pre-edge and L-edge-like spectra (metal spin state) simultaneously. We have collected data from PSII samples in the each of the S-states and compared them with data from various inorganic Mn complexes. The spectral changes in the Mn 1s2p{sub 3/2} RIXS spectra between the S-states were compared to those of the oxides of Mn and coordination complexes. The results indicate strong covalency for the electronic configuration in the OEC, and we conclude that the electron is transferred from a strongly delocalized orbital, compared to those in Mn oxides or coordination complexes. The magnitude for the S{sub 0} to S{sub 1}, and S{sub 1} to S{sub 2} transitions is twice as large as that during the S{sub 2} to S{sub 3} transition, indicating that the electron for this transition is extracted from a highly delocalized orbital with little change in charge density at the Mn atoms.

Yano, J.; Pushkar, Y.; Messinger, J.; Bergmann, U.; Glatzel, P.; Yachandra, V.K.; /SLAC

2012-08-17T23:59:59.000Z

145

Structural Changes in the Mn(4)Ca Cluster And the Mechanism of Photosynthetic Water Splitting  

SciTech Connect (OSTI)

Photosynthetic water oxidation, where water is oxidized to dioxygen, is a fundamental chemical reaction that sustains the biosphere. This reaction is catalyzed by a Mn{sub 4}Ca complex in the photosystem II (PS II) oxygen-evolving complex (OEC): a multiprotein assembly embedded in the thylakoid membranes of green plants, cyanobacteria, and algae. The mechanism of photosynthetic water oxidation by the Mn{sub 4}Ca cluster in photosystem II is the subject of much debate, although lacking structural characterization of the catalytic intermediates. Biosynthetically exchanged Ca/Sr-PS II preparations and x-ray spectroscopy, including extended x-ray absorption fine structure (EXAFS), allowed us to monitor Mn-Mn and Ca(Sr)-Mn distances in the four intermediate S states, S{sub 0} through S{sub 3}, of the catalytic cycle that couples the one-electron photochemistry occurring at the PS II reaction center with the four-electron water-oxidation chemistry taking place at the Mn{sub 4}Ca(Sr) cluster. We have detected significant changes in the structure of the complex, especially in the Mn-Mn and Ca(Sr)-Mn distances, on the S{sub 2}-to-S{sub 3} and S{sub 3}-to-S{sub 0} transitions. These results implicate the involvement of at least one common bridging oxygen atom between the Mn-Mn and Mn-Ca(Sr) atoms in the O-O bond formation. Because PS II cannot advance beyond the S{sub 2} state in preparations that lack Ca(Sr), these results show that Ca(Sr) is one of the critical components in the mechanism of the enzyme. The results also show that Ca is not just a spectator atom involved in providing a structural framework, but is actively involved in the mechanism of water oxidation and represents a rare example of a catalytically active Ca cofactor.

Pushkar, Y.; Yano, J.; Sauer, K.; Boussac, A.; Yachandra, V.K.

2009-05-21T23:59:59.000Z

146

Structural Changes in the Mn4Ca Cluster and the Mechanism of Photosynthetic Water Splitting  

SciTech Connect (OSTI)

Photosynthetic water oxidation, where water is oxidized to dioxygen, is a fundamental chemical reaction that sustains the biosphere. This reaction is catalyzed by a Mn4Ca complex in the photosystem II (PS II) oxygen-evolving complex (OEC): a multiproteinassembly embedded in the thylakoid membranes of green plants, cyanobacteria, and algae. The mechanism of photosynthetic water oxidation by the Mn4Ca cluster in photosystem II is the subject of much debate, although lacking structural characterization of the catalytic intermediates. Biosynthetically exchanged Ca/Sr-PS II preparations and x-ray spectroscopy, including extended x-ray absorption fine structure (EXAFS), allowed us to monitor Mn-Mn and Ca(Sr)-Mn distances in the four intermediate S states, S0 through S3, of the catalytic cycle that couples the one-electron photochemistry occurring at the PS II reaction center with the four-electron water-oxidation chemistry taking place at the Mn4Ca(Sr) cluster. We have detected significant changes in the structure of the complex, especially in the Mn-Mn and Ca(Sr)-Mn distances, on the S2-to-S3 and S3-to-S0 transitions. These results implicate the involvement of at least one common bridging oxygen atom between the Mn-Mn and Mn-Ca(Sr) atoms in the O-O bond formation. Because PS II cannot advance beyond the S2 state in preparations that lack Ca(Sr), these results show that Ca(Sr) is one of the critical components in the mechanism of the enzyme. The results also show that Ca is not just a spectator atom involved in providing a structural framework, but is actively involved in the mechanism of water oxidation and represents a rare example of a catalytically active Ca cofactor.

Pushkar, Y.; Yano, J.; Sauer, K.; Boussac, A.; Yachandra, V.K.

2007-10-25T23:59:59.000Z

147

Preparation and electrochemical properties of lamellar MnO{sub 2} for supercapacitors  

SciTech Connect (OSTI)

Lamellar birnessite-type MnO{sub 2} materials were prepared by changing the pH of the initial reaction system via hydrothermal synthesis. The interlayer spacing of MnO{sub 2} with a layered structure increased gradually when the initial pH value varied from 12.43 to 2.81, while the MnO{sub 2}, composed of {alpha}-MnO{sub 2} and {gamma}-MnO{sub 2}, had a rod-like structure at pH 0.63. Electrochemical studies indicated that the specific capacitance of birnessite-type MnO{sub 2} was much higher than that of rod-like MnO{sub 2} at high discharge current densities due to the lamellar structure with fast intercalation/deintercalation of protons and high utilization of MnO{sub 2}. The initial specific capacitance of MnO{sub 2} prepared at pH 2.81 was 242.1 F g{sup -1} at 2 mA cm{sup -2} in 2 mol L{sup -1} (NH{sub 4}){sub 2}SO{sub 4} aqueous electrolyte. The capacitance increased by about 8.1% of initial capacitance after 200 cycles at a current density of 100 mA cm{sup -2}.

Yan, Jun; Wei, Tong [Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China)] [Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China); Cheng, Jie [Research Institute of Chemical Defense, Beijing 100083 (China)] [Research Institute of Chemical Defense, Beijing 100083 (China); Fan, Zhuangjun, E-mail: fanzhj666@163.com [Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China)] [Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China); Zhang, Milin [Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China)] [Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China)

2010-02-15T23:59:59.000Z

148

Distinct local electronic structure and magnetism for Mn in amorphous Si and Ge  

SciTech Connect (OSTI)

Transition metals such as Mn generally have large local moments in covalent semiconductors due to their partially filled d shells. However, Mn magnetization in group-IV semiconductors is more complicated than often recognized. Here we report a striking crossover from a quenched Mn moment (<0.1 {mu}{sub B}) in amorphous Si (a-Si) to a large distinct local Mn moment ({ge}3{mu}{sub B}) in amorphous Ge (a-Ge) over a wide range of Mn concentrations (0.005-0.20). Corresponding differences are observed in d-shell electronic structure and the sign of the Hall effect. Density-functional-theory calculations show distinct local structures, consistent with different atomic density measured for a-Si and a-Ge, respectively, and the Mn coordination number N{sub c} is found to be the key factor. Despite the amorphous structure, Mn in a-Si is in a relatively well-defined high coordination interstitial type site with broadened d bands, low moment, and electron (n-type) carriers, while Mn in a-Ge is in a low coordination substitutional type site with large local moment and holes (p-type) carriers. Moreover, the correlation between N{sub c} and the magnitude of the local moment is essentially independent of the matrix; the local Mn moments approach zero when N{sub c} > 7 for both a-Si and a-Ge.

Zeng, Li; Cao, J. X.; Helgren, E.; Karel, J.; Arenholz, E.; Ouyang, Lu; Smith, David J.; Wu, R. Q.; Hellman, F.

2010-06-01T23:59:59.000Z

149

Strain mediated coupling in magnetron sputtered multiferroic PZT/Ni-Mn-In/Si thin film heterostructure  

SciTech Connect (OSTI)

The strain mediated electrical and magnetic properties were investigated in PZT/Ni-Mn-In heterostructure deposited on Si (100) by dc/rf magnetron sputtering. X-ray diffraction pattern revealed that (220) orientation of Ni-Mn-In facilitate the (110) oriented tertragonal phase growth of PZT layer in PZT/Ni-Mn-In heterostructure. A distinctive peak in dielectric constant versus temperature plots around martensitic phase transformation temperature of Ni-Mn-In showed a strain mediated coupling between Ni-Mn-In and PZT layers. The ferroelectric measurement taken at different temperatures exhibits a well saturated and temperature dependent P-E loops with a highest value of P{sub sat}???55 ?C/cm{sup 2} obtained during martensite-austenite transition temperature region of Ni-Mn-In. The stress induced by Ni-Mn-In layer on upper PZT film due to structural transformation from martensite to austenite resulted in temperature modulated Tunability of PZT/Ni-Mn-In heterostructure. A tunability of 42% was achieved at 290?K (structural transition region of Ni-Mn-In) in these heterostructures. I-V measurements taken at different temperatures indicated that ohmic conduction was the main conduction mechanism over a large electric field range in these heterostructures. Magnetic measurement revealed that heterostructure was ferromagnetic at room temperature with a saturation magnetization of ?123?emu/cm{sup 3}. Such multiferroic heterostructures exhibits promising applications in various microelectromechanical systems.

Singh, Kirandeep; Kaur, Davinder, E-mail: dkaurfph@iitr.ernet.in [Functional Nanomaterials Research Lab, Department of Physics and Centre of Nanotechnology, Indian Institute of Technology Roorkee, Roorkee-247667, Uttarakhand (India); Singh, Sushil Kumar [Functional Materials Division, Solid State Physics Lab (SSPL), DRDO, Lucknow Road, Timarpur, Delhi 110054 (India)

2014-09-21T23:59:59.000Z

150

ALS Evidence Confirms Combustion Theory  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ALS Evidence Confirms Combustion Theory Print Researchers recently uncovered the first step in the process that transforms gas-phase molecules into solid particles like soot and...

151

MN Office of Energy Security | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth's Heat JumpIncMAKGalway Bay IEOWCCatcher.pngWavemill <MN Office of Energy

152

Thermal Stability of MnBi Magnetic Materials. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism in Layered NbS2 andThe1 MembersStability of MnBi Magnetic Materials.

153

Electronic Structure and Oxidation State Changes in the Mn4Ca Cluster of Photosystem II  

SciTech Connect (OSTI)

Oxygen-evolving complex (Mn4Ca cluster) of Photosystem II cycles through five intermediate states (Si-states, i =0-4) before a molecule of dioxygen is released. During the S-state transitions, electrons are extracted from the OEC, either from Mn or alternatively from a Mn ligand. The oxidation state of Mn is widely accepted as Mn4(III2,IV2) and Mn4(III,IV3) for S1 and S2 states, while it is still controversial for the S0 and S3 states. We used resonant inelastic X-ray scattering (RIXS) to study the electronic structure of Mn4Ca complex in the OEC. The RIXS data yield two-dimensional plots that provide a significant advantage by obtaining both K-edge pre-edge and L-edge-like spectra (metal spin state) simultaneously. We have collected data from PSII samples in the each of the S-states and compared them with data from various inorganic Mncomplexes. The spectral changes in the Mn 1s2p3/2 RIXS spectra between the S-states were compared to those of the oxides of Mn and coordination complexes. The results indicate strong covalency for the electronic configuration in the OEC, and we conclude that the electron is transferred from a strongly delocalized orbital, compared to those in Mn oxides or coordination complexes. The magnitude for the S0 to S1, and S1 to S2 transitions is twice as large as that during the S2 to S3 transition, indicating that the electron for this transition is extracted from a highly delocalized orbital with little change in charge density at the Mn atoms.

Yano, Junko; Pushkar, Yulia; Messinger, Johannes; Bergmann, Uwe; Glatzel, Pieter; Yachandra, Vittal K

2007-08-03T23:59:59.000Z

154

Protective effects of ebselen (Ebs) and para-aminosalicylic acid (PAS) against manganese (Mn)-induced neurotoxicity  

SciTech Connect (OSTI)

Chronic, excessive exposure to manganese (Mn) may induce neurotoxicity and cause an irreversible brain disease, referred to as manganism. Efficacious therapies for the treatment of Mn are lacking, mandating the development of new interventions. The purpose of the present study was to investigate the efficacy of ebselen (Ebs) and para-aminosalicylic acid (PAS) in attenuating the neurotoxic effects of Mn in an in vivo rat model. Exposure biomarkers, inflammatory and oxidative stress biomarkers, as well as behavioral parameters were evaluated. Co-treatment with Mn plus Ebs or Mn plus PAS caused a significant decrease in blood and brain Mn concentrations (compared to rats treated with Mn alone), concomitant with reduced brain E{sub 2} prostaglandin (PGE{sub 2}) and enhanced brain glutathione (GSH) levels, decreased serum prolactin (PRL) levels, and increased ambulation and rearing activities. Taken together, these results establish that both PAS and Ebs are efficacious in reducing Mn body burden, neuroinflammation, oxidative stress and locomotor activity impairments in a rat model of Mn-induced toxicity. -- Highlights: ? The manuscript is unique in its approach to the neurotoxicity of Mn. ? The manuscript incorporates molecular, cellular and functional (behavioral) analyses. ? Both PAS and Ebs are effective in restoring Mn behavioral function. ? Both PAS and Ebs are effective in reducing Mn-induced oxidative stress. ? Both PAS and Ebs led to a decrease in Mn-induced neuro-inflammation.

Marreilha dos Santos, A.P., E-mail: apsantos@ff.ul.pt [I-Med.UL, Department of Toxicology and Food Sciences, Faculty of Pharmacy, University of Lisbon, Lisbon (Portugal); Lucas, Rui L.; Andrade, Vanda; Mateus, M. Luísa [I-Med.UL, Department of Toxicology and Food Sciences, Faculty of Pharmacy, University of Lisbon, Lisbon (Portugal)] [I-Med.UL, Department of Toxicology and Food Sciences, Faculty of Pharmacy, University of Lisbon, Lisbon (Portugal); Milatovic, Dejan; Aschner, Michael [Department of Pediatrics, Vanderbilt University Medical Center, Nashville, TN 37232 (United States)] [Department of Pediatrics, Vanderbilt University Medical Center, Nashville, TN 37232 (United States); Batoreu, M. Camila [I-Med.UL, Department of Toxicology and Food Sciences, Faculty of Pharmacy, University of Lisbon, Lisbon (Portugal)] [I-Med.UL, Department of Toxicology and Food Sciences, Faculty of Pharmacy, University of Lisbon, Lisbon (Portugal)

2012-02-01T23:59:59.000Z

155

E-Print Network 3.0 - al-fe-mn-si obtidas por Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

o sistema Mx b. (d) Seja "x M b" a aproximacao da solucao obtida por MATLAB. Sejam y e z... as aproximacoes obtidas atraves das suas implementacoes da...

156

Synthesis of NiCoMnX (X = In, Al) Heusler-type Magnetic Shape Memory Alloy Thin Films  

E-Print Network [OSTI]

found applications in biomedical and aerospace industries, actuator applications are limited to relatively low frequencies compared to piezoelectric materials. The slow response of shape memory alloys is associated with heating or cooling the material...

Rios, Steven Eli

2014-08-13T23:59:59.000Z

157

Minnesota Innovation Partnerships (MN-IP) Try and Buy MN-IP Try and Buy --for companies interested in licensing existing U of M inventions  

E-Print Network [OSTI]

is executed BUY (LICENSE) ¡ Low, published royalty rate, with first $1 million of product sales royalty-free ¡ Royalty rates based on industry comparables ¡ Royalty rate discount for MN operating companies2 ¡ Royalty

Minnesota, University of

158

Exchange interaction mediated ferroelectricity in multiferroic MnTiO{sub 3} with anisotropic orbital hybridization and hole delocalization  

SciTech Connect (OSTI)

We present the orbital structure of MnTiO{sub 3} with polarization dependent x-ray absorption and resonant x-ray emission spectra accompanied with electronic structure calculations. The results clearly indicate a strongly anisotropic O 2p-Mn 3d orbital hybridization whereas the Mn 3d hole state shows a highly delocalized characteristic ascribed to the 3d-4p mixing. The extended Mn 4p orbital could enhance the exchange interaction between Mn (3d)-O (2p)-Mn (3d) leading to an asymmetric charge distribution in Mn-O bonds. The delocalized characteristic of Mn 3d holes is indispensable to the mechanism of spin-dependent-metal-ligand hybridization to explain magnetically induced ferroelectricity.

Chen, S. W.; Fu, S. W.; Lee, J. M.; Lee, J. F.; Pao, C. W.; Ishii, H.; Tsuei, K. D.; Hiraoka, N.; Lu, K. T.; Chen, J. M., E-mail: jeng@phys.nthu.edu.tw, E-mail: xiaolin@uow.edu.au, E-mail: jmchen@nsrrc.org.tw [National Synchrotron Radiation Research Center, Hsinchu 30076, Taiwan (China); Lin, P. A. [Department of Physics, National Tsing Hua University, Hsinchu 30013, Taiwan (China); Jeng, H. T., E-mail: jeng@phys.nthu.edu.tw, E-mail: xiaolin@uow.edu.au, E-mail: jmchen@nsrrc.org.tw [Department of Physics, National Tsing Hua University, Hsinchu 30013, Taiwan (China); Institute of Physics, Academia Sinica, Taipei 11529, Taiwan (China); Chen, D. P.; Dou, S. X.; Wang, X. L., E-mail: jeng@phys.nthu.edu.tw, E-mail: xiaolin@uow.edu.au, E-mail: jmchen@nsrrc.org.tw [Institute for Superconducting and Electronic Materials, Australian Institute of Innovative, Materials, University of Wollongong, North Wollongong, NSW 2500 (Australia)

2014-02-24T23:59:59.000Z

159

An Analysis of Mn-Zn Ferrite Microstructure by Impedance Spectroscopy, STEM and EDS Characterisations.  

E-Print Network [OSTI]

An Analysis of Mn-Zn Ferrite Microstructure by Impedance Spectroscopy, STEM and EDS.loyau@satie.ens-cachan.fr Abstract AC resistivity measurement results on Mn-Zn sintered ferrite were analyzed in the 0.1-500 MHz of the main limitations in frequency increase is the energy dissipations by losses in ferrites that produce

Boyer, Edmond

160

Short communication The composite rods of MnO and multi-walled carbon nanotubes as  

E-Print Network [OSTI]

Short communication The composite rods of MnO and multi-walled carbon nanotubes as anode materialsO as an anode material for lithium ion batteries are significantly improved. The MnO/MWNTs composite shows a Electronic Materials Research Laboratory, Key Laboratory of the Ministry of Education, Xi'an Jiaotong

Ceder, Gerbrand

Note: This page contains sample records for the topic "mn al 1970-1974" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Structural, Electrochemical, and Spectroscopic Investigation of Acetate Bridged Dinuclear Tetrakis-Schiff Base Macrocycles of Mn  

E-Print Network [OSTI]

resembling the oxygen-evolving complex (OEC) in photosystem II and dimanganese catalase enzymes, resulting+ and Zn2LAc+ , the two metal centers are bridged by an acetate ligand. [Mn2LAc](ClO4)¡(DMF)0.5, [Mn2LAc for substrate molecules bound to redox active metal centers.5-10 In 1970, Robson showed that dinuclear tetrakis

Dinolfo, Peter H.

162

Semimetallic antiferromagnetism in the half-Heusler compound CuMnSb Ruben Weht,2  

E-Print Network [OSTI]

CuMnSb, the first antiferromagnet AFM in the Mn-based class of Heuslers and half-Heuslers that contains several conventional and half metallic ferromagnets, shows a peculiar stability of its magnetic order in high magnetic fields. Density functional based studies reveal an unusual nature of its unstable

Pickett, Warren

163

NICKEL-FREE Fe-12Mn-0.2Ti ALLOY STEEL FOR CRYOGENIC APPLICATIONS  

E-Print Network [OSTI]

Parr, J. Gordon, J. Iron and Steel Inst. B, vol. 283,137 (Properties of Fe-12Mn-0.2Ti Steel at -196°C Yield Stress (FREE Fe-12Mn-O. 2Ti ALLOY STEEL FOR CRYOGENIC APPLICATIONS

Hwang, S.

2010-01-01T23:59:59.000Z

164

Tunable White-Light-Emitting Mn-Doped ZnSe Nanocrystals Vijay Kumar Sharma,  

E-Print Network [OSTI]

Tunable White-Light-Emitting Mn-Doped ZnSe Nanocrystals Vijay Kumar Sharma, Burak Guzelturk, Talha report white-light-emitting Mn-doped ZnSe nanocrystals (NCs) that are synthesized using modified orange emission (580 nm), allowed us to achieve excitation wavelength tailorable white-light generation

Demir, Hilmi Volkan

165

Photovoltaic effect in multiphase Bi-Mn-O thin J. P. Chakrabartty,1  

E-Print Network [OSTI]

Photovoltaic effect in multiphase Bi-Mn-O thin films J. P. Chakrabartty,1 R. Nechache,2,4 C and therefore the photovoltaic conversion efficiency. Specifically, a higher Bi/Mn ratio (towards unity separation. Š2013 Optical Society of America OCIS codes: (040.5350) Photovoltaic; (160.2260) Ferroelectrics

166

austenitnoj cr-mn stali: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

cr-mn stali First Page Previous Page 1 2 3 4 5 6 Next Page Last Page Topic Index 1 Cavitation erosion of laser processed Fe-Cr-Mn and Fe-Cr-Co alloys CiteSeer Summary: Received...

167

Magnetism of NiMn2O4-Fe3O4 spinel interfaces  

SciTech Connect (OSTI)

We investigate the magnetic properties of the isostructural spinel-spinel interface of NiMn{sub 2}O{sub 4}(NMO)-Fe{sub 3}O{sub 4}. Although the magnetic transition temperature of the NMO film is preserved, both bulk and interface sensitive measurements demonstrate that the interface exhibits strong interfacial magnetic coupling up to room temperature. While NMO thin films have a ferrimagnetic transition temperature of 60 K, both NiFe{sub 2}O{sub 4} and MnFe{sub 2}O{sub 4} are ferrimagnetic at room temperature. Our experimental results suggest that these magnetic properties arise from a thin interdiffused region of (Fe,Mn,Ni){sub 3}O{sub 4} at the interface, leading to Mn and Ni magnetic properties similar to those of MnFe{sub 2}O{sub 4} and NiFe{sub 2}O{sub 4}.

Arenholz, Elke; Nelson-Cheeseman, B. B.; Chopdekar, R. V.; Bettinger, J. S.; Arenholz, E.; Suzuki, Y.

2007-09-13T23:59:59.000Z

168

Neutron diffraction study of MnNiGa{sub 2}—Structural and magnetic behaviour  

SciTech Connect (OSTI)

MnNiGa{sub 2} crystallizes in the L21 (Heusler) structure and has a ferromagnetic ordering temperature T{sub C}???192?K. Rietveld refinement of the neutron diffraction patterns indicates that the Ga atoms occupy the equivalent 8c position, while Mn and Ni share the 4a (0, 0, 0) and 4b (0.5, 0.5, 0.5) sites with a mixed occupancy of Mn and Ni atoms. It is found that that ?83% of Mn and ?17% Ni are located at the 4a site while ?83% of Ni and ?17% Mn occupy the 4b site. There is no evidence of a magneto-volume effect around T{sub C}. In agreement with this finding, our detailed critical exponent analyses of isothermal magnetization curves and the related Arrott plots confirm that the magnetic phase transition at T{sub C} is second order.

Wang, J. L., E-mail: jianli@uow.edu.au [Institute for Superconductivity and Electronic Materials, University of Wollongong, Wollongong, NSW 2522 (Australia); Bragg Institute, ANSTO, Lucas Heights, NSW 2234 (Australia); School of Physical, Environmental and Mathematical Sciences, The University of New South Wales, Canberra, ACT 2600 (Australia); Ma, L.; Wu, G. H. [Institute of Physics, Chinese Academy of Science, Beijing 100190 (China); Hofmann, M. [FRM-II, Technische Universität München, 85747 Garching (Germany); Avdeev, M.; Kennedy, S. J. [Bragg Institute, ANSTO, Lucas Heights, NSW 2234 (Australia); Campbell, S. J. [School of Physical, Environmental and Mathematical Sciences, The University of New South Wales, Canberra, ACT 2600 (Australia); Md Din, M. F.; Dou, S. X. [Institute for Superconductivity and Electronic Materials, University of Wollongong, Wollongong, NSW 2522 (Australia); Hoelzel, M. [FRM-II, Technische Universität München, 85747 Garching (Germany); Fachbereich Materialwissenschaften, Technische Universität Darmstadt, 64287 Darmstadt (Germany)

2014-05-07T23:59:59.000Z

169

Allegato "B" DOMANDA DI PARTECIPAZIONE AL CONCORSO DI AMMISSIONE AL  

E-Print Network [OSTI]

IN ROBOTICA, NEUROSCIENZE, NANOTECNOLOGIE E SCOPERTA FARMACI IN COLLABORAZIONE CON LA FONDAZIONE IIT Si prega'ammissione al Corso di Dottorato di Ricerca in Robotica, Neuroscienze, Nanotecnologie e Scoperta Farmaci

Sandini, Giulio

170

Al Akhawayn University Al Akhawayn partner of TUM since 2002  

E-Print Network [OSTI]

Haddouti ˇ Dissertation at Chair for Databases (Prof. Bayer), Professor at Al Akhawayn, now working at BMW (TUM & AUI Alumni) ˇ BMW, Hachim.haddouti@bmw.de #12;Double Degree TUM - Georgia Tech Fakultät für

Cengarle, María Victoria

171

Al Akhawayn University Al Akhawayn partner of TUM since 2002  

E-Print Network [OSTI]

Haddouti ˇ Dissertation at Chair for Databases (Prof. Bayer), Professor at Al Akhawayn, now working at BMW) ˇ BMW, Hachim.haddouti@bmw.de #12;Double Degree TUM - Georgia Tech Fakultät für Informatik TUM School

Cengarle, María Victoria

172

Al Akhawayn University Al Akhawayn partner of TUM since 2002  

E-Print Network [OSTI]

Haddouti ˇ Dissertation at Chair for Databases (Prof. Bayer), Professor at Al Akhawayn, now working at BMW Alumni) ˇ BMW, Hachim.haddouti@bmw.de #12;Double Degree TUM - Georgia Tech Fakultät für Informatik TUM

Cengarle, María Victoria

173

Microstructure, microstructural stability and mechanical properties of sand-cast Mg–4Al–4RE alloy  

SciTech Connect (OSTI)

This paper presents a methodology for assessing the phase composition and the results of structural stability tests of the sand-cast Mg–4Al–4RE alloy after annealing it at 175 and 250 °C for 3000 h. The microstructure was analyzed with optical, scanning electron, and transmission electron microscopy. The phase composition was determined with X-ray diffraction. The structure of the Mg–4Al–4RE (AE44) alloy is composed of large grains of ?-Mg solid solution, needle-shaped precipitates of the Al{sub 11}RE{sub 3}phase, polyhedral precipitates of the Al{sub 2}RE phase and Al{sub 10}RE{sub 2}Mn{sub 7} phase. After annealing at 175 °C for 3000 h, no changes in the alloy structure are observed, whereas after annealing at 250 °C the precipitates of the Al{sub 11}RE{sub 3} phase are found to be in the initial stages of spheroidization. The coarse-grained structure and unfavorable morphology of the intermetallic phases in the sand-cast AE44 alloy, which are caused by low solidification rates, result in low creep resistance up to 200 °C and low mechanical properties at ambient temperature and at 175 °C. - Highlights: • Complement the knowledge about the microstructure of Mg-Al-RE alloys. • Clarify the mechanism of formation of Mg17Al12 phase above 180 °C. • Applying a chemical dissolution of the ?-Mg in order to phase identification. • Applying a statistical test to assess the spheroidization of precipitates. • Quantitative description of microstructure of Mg-Al-RE alloys.

Rzycho?, Tomasz, E-mail: tomasz.rzychon@polsl.pl [Silesian University of Technology, Faculty of Materials Science and Metallurgy, Krasi?skiego 8, 40 019 Katowice (Poland); Kie?bus, Andrzej [Silesian University of Technology, Faculty of Materials Science and Metallurgy, Krasi?skiego 8, 40 019 Katowice (Poland); Lity?ska-Dobrzy?ska, Lidia [Polish Academy of Sciences, Institute of Metallurgy and Materials Science, 25 Reymonta Street, 30-059 Kraków (Poland)

2013-09-15T23:59:59.000Z

174

Mn3O4-Graphene Hybrid as a High-Capacity Anode Material for Lithium Ion Hailiang Wang,,  

E-Print Network [OSTI]

Mn3O4-Graphene Hybrid as a High-Capacity Anode Material for Lithium Ion Batteries Hailiang Wang hybrid materials of Mn3O4 nanoparticles on reduced graphene oxide (RGO) sheets for lithium ion battery stability, owing to the intimate interactions between the graphene substrates and the Mn3O4 nanoparticles

Cui, Yi

175

Electronic structure of the molecule-based magnet MnN,,CN...22 from theory and experiment  

E-Print Network [OSTI]

, Louisiana 70118 Received 27 November 2001; published 24 July 2002 The electronic structure of the Mn-based determined recently by Kurmoo and Kepert.2,3 More recently, x-ray structure of the Mn-based material has beenElectronic structure of the molecule-based magnet MnN,,CN...22 from theory and experiment M. R

Liu, Amy Y.

176

(12) United States Patent Harvey et al.  

E-Print Network [OSTI]

(12) United States Patent Harvey et al. (54) ANALYZING RETURN ON INVESTMENT OF ADVERTISING US 2009/0259518 Al Oct. 15,2009 Int. Cl. G06F 17/30 (2006.01) G07G 1/00 (2006.01) U.S. Cl et al. 911980 Block et al. 511982 Eskin et al. 1111982 Barber et al. 711985 Block et al. 111996

Shamos, Michael I.

177

In Memory of Al Cameron  

E-Print Network [OSTI]

Al Cameron, who died recently (October 3, 2005) at 80, was one of the giants in astrophysics. His insights were profound and his interests were wide-ranging. Originally trained as a nuclear physicist, he made major contributions in a number of fields, including nuclear reactions in stars, nucleosynthesis, the abundances of the elements in the Solar System, and the origin of the Solar System and the Moon. In 1957, Cameron and, independently, Burbidge, Burbidge, Fowler and Hoyle, wrote seminal papers on nuclear astrophysics. Most of our current ideas concerning element formation in stars have followed from those two pioneering and historical works. Al also made many contributions in the field of Solar System physics. Particularly noteworthy in this regard was Cameron's work on the formation of the Moon. Al was also a good friend and mentor of young people. Al Cameron will be missed by many in the community both for his scientific contributions and for his friendship.

John J. Cowan; James W. Truran

2006-11-27T23:59:59.000Z

178

E-Print Network 3.0 - al suolo al Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

DEI CAMBIAMENTI Summary: tradizionali rimboschimenti vincoli al dissodamento aumento delle provvigioni e dei turni riduzione degli... Commissione al Consiglio e al...

179

Dirac cones in artificial structures of 3d transitional-metals doped Mg-Al spinels  

SciTech Connect (OSTI)

Motivated by recent theoretical predications for Dirac cone in two-dimensional (2D) triangular lattice [H. Ishizuka, Phys. Rev. Lett. 109, 237207 (2012)], first-principles studies are performed to predict Dirac cones in artificial structures of 3d transitional-metals (TM?=?Ti, V, Cr, Mn, Fe, Co, Ni, and Cu) doped Mg-Al spinels. In investigated artificial structures, TM dopants substitute specific positions of the B sub-lattice in Mg-Al spinel, and form a quasi-2D triangular lattice in the a-b plane. Calculated results illustrate the existence of the spin-polarized Dirac cones formed in d-wave bands at (around) the K-point in the momentum space. The study provides a promising route for engineering Dirac physics in condensed matters.

Lu, Yuan; Zuo, Xu, E-mail: xzuo@nankai.edu.cn [College of Electronic Information and Optical Engineering, Nankai University, Tianjin 300071 (China); Feng, Min [School of Physics, Nankai University, Tianjin 300071 (China); Shao, Bin [Department of Physics, Tsinghua University, Beijing 100084 (China)

2014-05-07T23:59:59.000Z

180

Magnetic phase diagram of magnetoelectric LiMnPO4  

SciTech Connect (OSTI)

The nature of the spin-flop (SF) transition in the magnetoelectric quasi-2D Heisenberg system LiMnPO4 is studied in fields applied along the a axis. A refinement of the magnetic structure using neutron diffraction data in the SF phase reveals that the spins reorient from being parallel to the a axis to be nearly along the c axis at magnetic fields between 4 and 4.7 T, depending on temperature. The low-field antiferromagnetic phase boundary is shown to join the spin-flop line tangentially at the so-called bicritical point, where there is a suppression of the ordering temperature. At the bicritical field, we observe an increased intensity of the Lorentz broadened elastic scattering at magnetic Bragg peaks above TN as compared to zero field and 10 T, without an increase in peak width. This suggests an increased density of fluctuations at the bicritical field as compared to zero field.

Toft-Petersen, Rasmus; Andersen, Niels H.; Li, Haifeng; Li, Jiying; Tian, Wei; Budko, Serguei L.; Jensen, Thomas B.S.; Niedermayer, Christof; Laver, Mark; Zaharko, Oksana; Lynn, Jeffrey W.; Vaknin, David

2012-06-14T23:59:59.000Z

Note: This page contains sample records for the topic "mn al 1970-1974" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Low-temperature magnetization of (Ga,Mn) As semiconductors  

E-Print Network [OSTI]

of the Zeeman Hamil- tonian gS#3;BBS?z+gj#3;BBj?z, and from Eq. #1;1#2;: m ? mMF #14; mQF = ? #3;B j S + j #1;gS ? gj#2; . #1;5#2; When j=1/2 and gS=gj =2 the quantum fluctuation correc- tion to the magnetization vanishes even though the mean- field...Low-temperature magnetization of (Ga,Mn)As semiconductors T. Jungwirth,1,2 J. Ma?ek,3 K. Y. Wang,2 K. W. Edmonds,2 M. Sawicki,4 M. Polini,5 Jairo Sinova,6 A. H. MacDonald,7 R. P. Campion,2,8 L. X. Zhao,2,8 N. R. S. Farley,2,8 T. K. Johal,8 G. van...

Jungwirth, T.; Masek, J.; Wang, KY; Edmonds, KW; Sawicki, M.; Polini, M.; Sinova, Jairo; MacDonald, AH; Campion, RP; Zhao, LX; Farley, NRS; Johal, TK; van der Laan, G.; Foxon, CT; Gallagher, BL.

2006-01-01T23:59:59.000Z

182

Ferromagnetism in Mn-Implanted Epitaxially Grown Ge on Si(100)  

SciTech Connect (OSTI)

We have studied ferromagnetism of Mn-implanted epitaxial Ge films on silicon. The Ge films were grown by ultrahigh vacuum chemical vapor deposition using a mixture of germane (GeH{sub 4}) and methylgermane (CH{sub 3}GeH{sub 3}) gases with a carbon concentration of less than 1 at. %, and observed surface rms roughness of 0.5 nm, as measured by atomic force microscopy. Manganese ions were implanted in epitaxial Ge films grown on Si (100) wafers to an effective concentration of 16, 12, 6, and 2 at. %. Superconducting quantum interference device measurements showed that only the three highest Mn concentration samples are ferromagnetic, while the fourth sample, with [Mn] = 2 at. %, is paramagnetic. X-ray absorption spectroscopy and x-ray magnetic circular dichroism measurements indicate that localized Mn moments are ferromagnetically coupled below the Curie temperature. Isothermal annealing of Mn-implanted Ge films with [Mn] = 16 at. % at 300 C for up to 1200 s decreases the magnetization but does not change the Curie temperature, suggesting that the amount of the magnetic phase slowly decreases with time at this anneal temperature. Furthermore, transmission electron microscopy and synchrotron grazing incidence x-ray diffraction experiments show that the Mn-implanted region is amorphous, and we believe that it is this phase that is responsible for the ferromagnetism. This is supported by our observation that high-temperature annealing leads to recrystallization and transformation of the material into a paramagnetic phase.

Guchhait, S.; Jamil, M.; Ohldag, H.; Mehta, A.; Arenholz, E.; Lian, G.; Li Fatou, A.; Ferrer, D. A.; Markert, J. T.; Colombo, L.; Banerjee, S. K.

2011-01-05T23:59:59.000Z

183

Ferrimagnetism and disorder of epitaxial Mn2-xCoxVAl Heusler compound thin films  

SciTech Connect (OSTI)

The quaternary full Heusler compound Mn{sub 2-x}Co{sub x}VAl with x = 1 is predicted to be a half-metallic antiferromagnet. Thin films of the quaternary compounds with x = 0-2 were prepared by dc and RF magnetron co-sputtering on heated MgO (0 0 1) substrates. The magnetic structure was examined by x-ray magnetic circular dichroism and the chemical disorder was characterized by x-ray diffraction. Ferrimagnetic coupling of V to Mn was observed for Mn{sub 2}VAl (x = 0). For x = 0.5, we also found ferrimagnetic order with V and Co antiparallel to Mn. The observed reduced magnetic moments are interpreted with the help of band structure calculations in the coherent potential approximation. Mn{sub 2}VAl is very sensitive to disorder involving Mn, because nearest-neighbour Mn atoms couple antiferromagnetically. Co{sub 2}VAl has B2 order and has reduced magnetization. In the cases with x {ge} 0.9 conventional ferromagnetism was observed, closely related to the atomic disorder in these compounds.

Meinert, Markus; Schmalhorst, Jan-Michael; Reiss, Gunter; Arenholz, Elke

2011-01-29T23:59:59.000Z

184

Large interface diffusion in endotaxial growth of MnP films on GaP substrates  

SciTech Connect (OSTI)

The metal organic vapor deposition of MnP films on GaP (100) substrates is shown to have a substantial endotaxial component. A study of the growth time evolution of the endotaxial depths of MnP grains reveals a diffusion-controlled growth with a relatively large diffusion coefficient of Mn in GaP. The value (2.2?ą?1.5)?×?10{sup ?15} (cm{sup 2}/s) obtained at 650?°C is at least two orders of magnitude larger than the reported Mn diffusion in bulk GaP. GaP surface mounds provide further indirect evidence that this large diffusion coefficient is concurrent with the out-diffusion of Ga atoms at the growing MnP/GaP interface. No trace of dislocations could be observed at or near this interface, which strongly suggests that Mn diffusion occurs through vacant sites generated by the difference between the crystallographic structures of MnP and GaP.

Nateghi, N., E-mail: seyyed-nima.nateghi@polymtl.ca; Ménard, D.; Masut, R. A. [Regroupement québécoise sur les matériaux de pointe (RQMP), Département de Génie Physique, Polytechnique Montréal, C.P. 6079, succ. Centre-ville, Montréal, Québec H3C 3A7 (Canada)

2014-10-07T23:59:59.000Z

185

Structural characterization of terrestrial microbial Mn oxides from Pinal Creek, AZ  

SciTech Connect (OSTI)

The microbial catalysis of Mn(II) oxidation is believed to be a dominant source of abundant sorption- and redox-active Mn oxides in marine, freshwater, and subsurface aquatic environments. In spite of their importance, environmental oxides of known biogenic origin have generally not been characterized in detail from a structural perspective. Hyporheic zone Mn oxide grain coatings at Pinal Creek, Arizona, a metals-contaminated stream, have been identified as being dominantly microbial in origin and are well studied from bulk chemistry and contaminant hydrology perspectives. This site thus presents an excellent opportunity to study the structures of terrestrial microbial Mn oxides in detail. XRD and EXAFS measurements performed in this study indicate that the hydrated Pinal Creek Mn oxide grain coatings are layer-type Mn oxides with dominantly hexagonal or pseudo-hexagonal layer symmetry. XRD and TEM measurements suggest the oxides to be nanoparticulate plates with average dimensions on the order of 11 nm thick x 35 nm diameter, but with individual particles exhibiting thickness as small as a single layer and sheets as wide as 500 nm. The hydrated oxides exhibit a 10-A basal-plane spacing and turbostratic disorder. EXAFS analyses suggest the oxides contain layer Mn(IV) site vacancy defects, and layer Mn(III) is inferred to be present, as deduced from Jahn-Teller distortion of the local structure. The physical geometry and structural details of the coatings suggest formation within microbial biofilms. The biogenic Mnoxides are stable with respect to transformation into thermodynamically more stable phases over a time scale of at least 5 months. The nanoparticulate layered structural motif, also observed in pure culture laboratory studies, appears to be characteristic of biogenic Mn oxides and may explain the common occurrence of this mineral habit in soils and sediments.

Bargar, John; Fuller, Christopher; Marcus, Matthew A.; Brearley, Adrian J.; Perez De la Rosa, M.; Webb, Samuel M.; Caldwell, Wendel A.

2008-03-19T23:59:59.000Z

186

DAFS study of site-specific local structure of Mn in manganese ferrite films.  

SciTech Connect (OSTI)

Manganese ferrite (MnFe{sub 2}O{sub 4}) is a well-known magnetic material widely used in electronics for many years. It is well established that its magnetic behavior is strongly influenced by local structural properties of Mn ions, which are distributed between crystallographically inequivalent tetrahedral and octahedral sites in the unit cell. In order to understand and be able to tune properties of these structures, it is necessary to have detailed site-specific structural information on the system. Here we report on the application of diffraction-anomalous fine structure (DAFS) spectroscopy to resolve site-specific Mn local structures in manganese ferrite films. The DAFS measurements were done at undulator beamline 4-ID-D of the Advanced Photon Source at Argonne National Laboratory. The DAFS spectra (Fig. 1) were measured at several Bragg reflections in the vicinity of the Mn absorption K-edge, having probed separately contributions from tetrahedrally and octahedrally coordinated Mn sites. The DAFS data analysis done with an iterative Kramers-Kroenig algorithm made it possible to solve separately the local structure around different inequivalent Mn sites in the unit cell. The reliability of the data treatment was checked carefully, and it was showed that the site-specific structural parameters obtained with DAFS allow us to describe fluorescence EXAFS spectrum measured independently. Fig. 2 shows individual site contributions to the imaginary part of the resonant scattering amplitude obtained from the treatment of the data of Fig. 1. The analysis of the refined site-specific absorption spectra was done using EXAFS methods based on theoretical standards. We provided direct evidence for the tetrahedral Mn-O bond distance being increased relative to the corresponding Fe-O distance in bulk manganese ferrites. The first coordination shell number was found to be reduced significantly for Mn atoms at these sites. This finding is consistent with the well-known tendency of Mn to be tetrahedrally coordinated in these compounds.

Kravtsov, E.; Haskel, D.; Cady, A.; Yang, A.; Vittoria, C.; Zuo, X.; Harris, V. G.; X-Ray Science Division; Inst. of Metal Physics; Northeastern Univ.; Nankai Univ.

2006-01-01T23:59:59.000Z

187

Course Syllabus: Chemistry 3AL Course Information  

E-Print Network [OSTI]

Course Syllabus: Chemistry 3AL Course Information Course Name Chemistry 3AL Course Instructor are online. Chemistry 3AL Syllabus https://elearning.berkeley.edu/AngelUploads/Content/2013SUC... 1 of 5 5

Alvarez-Cohen, Lisa

188

Quantum interference in exciton-Mn spin interactions in a CdTe semiconductor quantum dot  

E-Print Network [OSTI]

We show theoretically and experimentally the existence of a new quantum interference(QI) effect between the electron-hole interactions and the scattering by a single Mn impurity. Theoretical model, including electron-valence hole correlations, the short and long range exchange interaction of Mn ion with the heavy hole and with electron and anisotropy of the quantum dot, is compared with photoluminescence spectroscopy of CdTe dots with single magnetic ions. We show how design of the electronic levels of a quantum dot enable the design of an exciton, control of the quantum interference and hence engineering of light-Mn interaction.

Trojnar, A; Kadantsev, E; Hawrylak, P; Goryca, M; Kazimierczuk, T; Kossacki, P; Wojnar, P; Potemski, M

2011-01-01T23:59:59.000Z

189

Quantum interference in exciton-Mn spin interactions in a CdTe semiconductor quantum dot  

E-Print Network [OSTI]

We show theoretically and experimentally the existence of a new quantum interference(QI) effect between the electron-hole interactions and the scattering by a single Mn impurity. Theoretical model, including electron-valence hole correlations, the short and long range exchange interaction of Mn ion with the heavy hole and with electron and anisotropy of the quantum dot, is compared with photoluminescence spectroscopy of CdTe dots with single magnetic ions. We show how design of the electronic levels of a quantum dot enable the design of an exciton, control of the quantum interference and hence engineering of light-Mn interaction.

A. Trojnar; M. Korkusinski; E. Kadantsev; P. Hawrylak; M. Goryca; T. Kazimierczuk; P. Kossacki; P. Wojnar; M. Potemski

2011-05-04T23:59:59.000Z

190

ALS Ceramics Materials Research Advances Engine Performance  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ALS Ceramics Materials Research Advances Engine Performance ALS Ceramics Materials Research Advances Engine Performance Print Thursday, 27 September 2012 00:00 ritchie ceramics...

191

AlN/Fe/AlN nanostructures for magnetooptic magnetometry  

SciTech Connect (OSTI)

AlN/Fe/AlN/Cu nanostructures with ultrathin Fe grown by sputtering on Si substrates are evaluated as probes for magnetooptical (MO) mapping of weak currents. They are considered for a laser wavelength of ??=?410?nm (3.02?eV) and operate at oblique light incidence angles, ?{sup (0)}, to enable detection of both in-plane and out-of-plane magnetization. Their performance is evaluated in terms of MO reflected wave electric field amplitudes. The maximal MO amplitudes in AlN/Fe/AlN/Cu are achieved by a proper choice of layer thicknesses. The nanostructures were characterized by MO polar Kerr effect at ?{sup (0)}???5° and longitudinal Kerr effect spectra (?{sup (0)}?=?45°) at photon energies between 1 and 5?eV. The nominal profiles were refined using a model-based analysis of the spectra. Closed form analytical expressions are provided, which are useful in the search for maximal MO amplitudes.

Lišková-Jakubisová, E., E-mail: liskova@karlov.mff.cuni.cz; Viš?ovský, Š. [Faculty of Mathematics and Physics, Charles University in Prague, Ke Karlovu 5, 12116 Prague 2 (Czech Republic); Široký, P.; Hrabovský, D.; Pištora, J. [Nanotechnology Center, Technical University of Ostrava, 17. listopadu 15/2172, 70833 Ostrava Poruba (Czech Republic); Harward, I.; Celinski, Z. [Center for Magnetism and Magnetic Nanostructures, University of Colorado at Colorado Springs, 1420 Austin Bluffs Pkwy., Colorado Springs, Colorado 80918 (United States)

2014-05-07T23:59:59.000Z

192

A nuclear magnetic resonance probe of Fe-Al and Al20V2Eu intermetallics  

E-Print Network [OSTI]

Al-rich Fe-Al systems (FeAl2, Fe2 Al5 and Fe4Al13) and Al20V2Eu have complicated structures with quasicrystal-like features making these materials potentially of interest for magnetic behavior. However, there is not much work on these materials...

Chi, Ji

2009-05-15T23:59:59.000Z

193

AL2007-03.doc  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergy Cooperation |South Valley ResponsibleSubmissionofDepartmentNo. AL7.pdf6-04v2.pdfContractorAL

194

ALS Evidence Confirms Combustion Theory  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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195

ALS Scientific Advisory Committee Charter  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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196

ALS Scientific Advisory Committee Charter  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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197

ALS Scientific Advisory Committee Charter  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07)Operations DuringALS DoctoralALS

198

Al  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc Documentation RUCProductstwrmrAre theAdministratorCFM LEAPAgendaConditioning AirWhyon the way to

199

Magnetism of NiMn2O4-Fe3O4 spinel interfaces  

E-Print Network [OSTI]

Magnetism of NiMn 2 O 4 –Fe 3 O 4 spinel interfaces B. B.2. Element-specific magnetism of Fe 3 O 4 /NMO interface inin these structures, 6 the magnetism near the isostructural

Nelson-Cheeseman, B. B.

2007-01-01T23:59:59.000Z

200

Synthesis and characterization of MnPS{sub 3} for hydrogen sorption  

SciTech Connect (OSTI)

Single phase MnPS{sub 3} powder was prepared by solid state reaction between Mn, S and P carried out at 650 deg. C in evacuated silica tube. The structure, morphology and sorption characteristics of the prepared solid were investigated. The results revealed that the obtained MnPS{sub 3} compound was capable of adsorbing 3.5 wt% hydrogen at -193 deg. C and a pressure of 30 bar. Little amount of hydrogen (0.07 wt%) was adsorbed at room temperature. The hydrogen adsorption/desorption cycles at various temperatures did not result in irreversible chemical structural changes of the MnPS{sub 3} compound, but the microstructure after hydrogen cycling diminished and became finer. - Graphical abstract: Atomic building of MPS{sub 3}

Ismail, N., E-mail: nahlaismail24@yahoo.co [Physical Chemistry Department, National Research Center, Center of Excellence for Advanced Science, Renewable Energy Group, Cairo (Egypt); Temerk, Y.M. [Assiut University, Faculty of Science, Chemistry Department, Assuit (Egypt); El-Meligi, A.A. [Physical Chemistry Department, National Research Center, Center of Excellence for Advanced Science, Renewable Energy Group, Cairo (Egypt); Badr, M.A. [Mechanical Engineering Department, Cairo (Egypt); Madian, M. [Physical Chemistry Department, National Research Center, Center of Excellence for Advanced Science, Renewable Energy Group, Cairo (Egypt)

2010-05-15T23:59:59.000Z

Note: This page contains sample records for the topic "mn al 1970-1974" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Electrode Characteristics of Individual, MnO2 Coated Carbon Nanotubes  

E-Print Network [OSTI]

MnO2 Coated Carbon Nanotubes Brad L. Corso, Israel Perez,single- walled carbon nanotubes. Li ion cyclic voltammetrysingle-walled carbon nanotubes (SWNTs) that are grown in

Collins, Philip G

2011-01-01T23:59:59.000Z

202

Characterization of LiNi?.?Mn?.?O? Thin Film Cathode Prepared by Pulsed Laser Deposition  

E-Print Network [OSTI]

LiNi?.?Mn?.?O? thin films have been grown by pulsed laser deposition (PLD) on stainless steel (SS) substrates. The crystallinity and structure of thin films were investigated by X-ray diffraction (XRD). Microstructure and ...

Xia, Hui

203

Frequency Response of Acoustic-Assisted Ni–Mn–Ga Ferromagnetic- Shape-Memory-Alloy Actuator  

E-Print Network [OSTI]

A prototype of Ni–Mn–Ga based ferromagnetic-shape-memory-alloy (FSMA) actuator was designed and built; an acoustic-assist technique was applied to the actuator to enhance its performance. A piezoelectric stack actuator was ...

Techapiesancharoenkij, Ratchatee

204

Combining sedimentological, trace metal (Mn, Mo) and molecular evidence for reconstructing past water-column  

E-Print Network [OSTI]

Combining sedimentological, trace metal (Mn, Mo) and molecular evidence for reconstructing past online 22 June 2013 Abstract Here, we present sedimentological, trace metal, and molecular evidence underscores the value of combining sedimentological, geochemical, and microbiological approaches

Wehrli, Bernhard

205

DOI: 10.1002/ejic.200700164 Chlorido-Bridged MnII  

E-Print Network [OSTI]

geometry sharing an equatorial-to-axial edge with parallel equatorial planes. The hydrogen bonds be,[3] dicyanamide,[4] and car- boxylate.[5] Ferromagnetic exchange coupling among these MnII compounds

Gao, Song

206

Understanding and development of combined acoustic and magnetic actuation of Ni?MnGa single crystals  

E-Print Network [OSTI]

Ni-Mn-Ga based ferromagnetic shape memory alloys (FSMAs) have emerged as a promising new class of active materials capable of producing a large (several %) magnetic-field-induced strain (MFIS). FSMAs still have several ...

Techapiesancharoenkij, Ratchatee, 1979-

2007-01-01T23:59:59.000Z

207

Formation of nano-crystalline todorokite from biogenic Mn Xiong Han Feng a,1  

E-Print Network [OSTI]

Formation of nano-crystalline todorokite from biogenic Mn oxides Xiong Han Feng a,1 , Mengqiang Zhu oxides in the environment. Additionally this method may be a viable biosynthesis route for porous, nano

Sparks, Donald L.

208

Prospects for high temperature ferromagnetism in (Ga,Mn)As semiconductors  

E-Print Network [OSTI]

-quality metallic samples increases linearly with the number of uncompensated local moments on Mn-Ga acceptors, with no sign of saturation. Room temperature ferromagnetism is expected for a 10% concentration of these local moments. Our magnetotransport...

Jungwirth, T.; Wang, KY; Masek, J.; Edmonds, KW; Konig, J.; Sinova, Jairo; Polini, M.; Goncharuk, NA; MacDonald, AH; Sawicki, M.; Rushforth, AW; Campion, RP; Zhao, LX; Foxon, CT; Gallagher, BL.

2005-01-01T23:59:59.000Z

209

Irradiated Esophageal Cells are Protected from Radiation-Induced Recombination by MnSOD Gene Therapy  

E-Print Network [OSTI]

Radiation-induced DNA damage is a precursor to mutagenesis and cytotoxicity. During radiotherapy, exposure of healthy tissues can lead to severe side effects. We explored the potential of mitochondrial SOD (MnSOD) gene ...

Niu, Yunyun

210

Effect of MnAs/GaAs(001) film accommodations on the phase-transition temperature  

SciTech Connect (OSTI)

The phase-transition temperature of MnAs epitaxial films grown by molecular-beam epitaxy on GaAs(001) with different crystalline accommodations was studied by specular and grazing incidence x-ray diffraction. The transition temperature of MnAs films with tilted hexagonal c-axis orientations with respect to the GaAs substrate is higher than the most investigated nontilted films and reaches a value above room temperature, which is more suitable for device applications.

Iikawa, F.; Brasil, M.J.S.P.; Couto, O.D.D.; Adriano, C.; Giles, C.; Daeweritz, L. [Instituto de Fisica 'Gleb Wataghin', UNICAMP, Campinas-SP, C.P. 6165, 13083-970 (Brazil); Instituto de Fisica 'Gleb Wataghin', UNICAMP, Campinas-SP, C.P. 6165, 13083-970, Brazil and Laboratorio Nacional de Luz Sincrotron, CP-6192, 13084-971 Campinas-SP (Brazil); Paul-Drude-Institut fuer Festkoerperelektronik, Hausvogteiplatz 5-7, 10117 Berlin (Germany)

2004-09-20T23:59:59.000Z

211

DC electrodeposition of Mn–Co alloys on stainless steels for SOFC interconnect application  

SciTech Connect (OSTI)

High conductivity coatings that resist oxide scale growth and reduce chromium evaporation are needed to make stainless steel interconnect materials viable for long-term stable operation of solid oxide fuel cells (SOFC). Mn1.5Co1.5O4 spinel is one of the most promising coatings for interconnect application because of its high conductivity, good chromium retention capability, as well as good CTE match to ferritic stainless steels. Mn–Co electrodeposition followed by oxidization is potentially a low cost method for fabrication of (Mn,Co)3O4 spinel coatings. This work looks at the co-deposition of Mn–Co alloys for this application. As a guide to optimize the deposition process, characterizations of the cathodic reactions and reaction potentials are done using polarization curves. It was found that as cobalt concentration was varied that the alloy composition became richer in cobalt, indicating that the deposition is regular co-deposition process. It was also found that at 0.05M Co concentration in excess gluconate the Mn–Co alloys composition could be tuned by varying the current density. Coatings with Mn–Co around 1:1 could be obtained at a current density of 250 mA/cm2. However, the higher potential increased hydrogen production making the films more porous. Oxidation of the alloy coatings showed that much of the porosities could be eliminated during oxidation. It was found in a number of samples that fully dense coatings where obtained. The composition of the oxidized coating was found to become enriched in Mn, possibly due to the Mn fast diffusion from the substrate.

Wu, Junwei; Jiang, Yinglu; Johnson, Christopher; Liu, Xingbo

2008-03-01T23:59:59.000Z

212

(In,Mn)As quantum dots: Molecular-beam epitaxy and optical properties  

SciTech Connect (OSTI)

Self-assembled (In,Mn)As quantum dots are synthesized by molecular-beam epitaxy on GaAs (001) substrates. The experimental results obtained by transmission electron microscopy show that doping of the central part of the quantum dots with Mn does not bring about the formation of structural defects. The optical properties of the samples, including those in external magnetic fields, are studied.

Bouravleuv, A. D., E-mail: bour@mail.ioffe.ru; Nevedomskii, V. N. [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation)] [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation); Ubyivovk, E. V. [St. Petersburg State University (Russian Federation)] [St. Petersburg State University (Russian Federation); Sapega, V. F. [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation)] [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation); Khrebtov, A. I. [St. Petersburg Academic University, Nanotechnology Research and Education Centre (Russian Federation)] [St. Petersburg Academic University, Nanotechnology Research and Education Centre (Russian Federation); Samsonenko, Yu. B.; Cirlin, G. E.; Ustinov, V. M. [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation)] [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation)

2013-08-15T23:59:59.000Z

213

Transformer Abdullah Al-Otaibi  

E-Print Network [OSTI]

Transformer Abdullah Al-Otaibi ID#242374 Section#2 Abstract- this is a brief description for transformer and how it works. I. DEFINITION A transformer is a device that transfers electrical energy from of the transformer in 1831. The transformer is used by Faraday only to demonstrate the principle of electromagnetic

Masoudi, Husain M.

214

Magneto acoustical emission in nanocrystalline Mn–Zn ferrites  

SciTech Connect (OSTI)

Graphical abstract: Mn{sub 0.4}Zn{sub 0.6}Fe{sub 2}O{sub 4} powders were prepared by microwave hydrothermal method. The powders were characterized by X-ray diffraction, transmission electron microscope. The powders were sintered at different temperatures 400, 500, 600, 700, 800 and 900 °C/30 min using microwave sintering method. The grain size was estimated by scanning electron microscope. The room temperature dielectric and magnetic properties were studied in the frequency range (100 kHz–1.8 GHz). The magnetization properties were measured upto 1.5 T. The acoustic emission has been measured along the hysteresis loops from 80 K to Curie temperature. It is found that the magneto-acoustic emission (MAE) activity along hysteresis loop is proportional to the hysteresis losses during the same loop. This law has been verified on series of polycrystalline ferrites and found that the law is valid whatever the composition, the grain size and temperature. It is also found that the domain wall creation/or annihilation processes are the origin of the MAE. - Highlights: • The AE been measured along the hysteresis loops from 80 K to Curie temperature. • The MAE activity along hysteresis loop is proportional to P{sub h} during the same loop. • It is found that the domain wall creation/or annihilation processes are the origin of the MAE. - Abstract: Mn{sub 0.4}Zn{sub 0.6}Fe{sub 2}O{sub 4} powders were prepared by microwave hydrothermal method. The powders were characterized by X-ray diffraction, transmission electron microscope. The powders were sintered at different temperatures 400, 500, 600, 700, 800 and 900 °C/30 min using microwave sintering method. The grain size was estimated by scanning electron microscope. The room temperature dielectric and magnetic properties were studied in the frequency range (100 kHz–1.8 GHz). The magnetization properties were measured upto 1.5 T. The acoustic emission has been measured along the hysteresis loops from 80 K to Curie temperature. It is found that the magneto-acoustic emission (MAE) activity along hysteresis loop is proportional to the hysteresis losses during the same loop. This law has been verified on series of polycrystalline ferrites and found that the law is valid whatever the composition, the grain size and temperature. It is also found that the domain wall creation/or annihilation processes are the origin of the MAE.

Praveena, K., E-mail: praveenaou@gmail.com [Materials Research Centre, Indian Institute of Science, Bangalore 560012 (India); Department of Physics, Osmania University, Hyderabad 500007 (India); Murthty, S.R. [Department of Physics, Osmania University, Hyderabad 500007 (India)

2013-11-15T23:59:59.000Z

215

Hydrothermal synthesis of Mn vanadate nanosheets and visible-light photocatalytic performance for the degradation of methyl blue  

SciTech Connect (OSTI)

Graphical abstract: - Highlights: • Mn vanadate nanosheets have been synthesized by simple hydrothermal process. • The formation of Mn vanadate nanosheets can be controlled by growth conditions. • Mn vanadate nanosheets exhibit good photocatalytic activities for methyl blue. - Abstract: Mn vanadate nanosheets have been synthesized via a facile hydrothermal route using ammonium metavanadate and Mn acetate as the raw materials, polyvinyl pyrrolidone (PVP) as the surfactant. X-ray diffraction (XRD) shows that the Mn vanadate nanosheets are composed of monoclinic MnV{sub 2}O{sub 6} phase. Scanning electron microscopy (SEM) observation indicates that the nanosheets have the average thickness of about 50 nm, length of 2–10 ?m and width of 800 nm to 2 ?m. The growth process of the Mn vanadate nanosheets has also been discussed based on the analysis of the roles of the growth conditions on the formation of the Mn vanadate nanosheets. The nanosheets show good photocatalytic activities for the degradation of methylene blue (MB) under visible light irradiation. About 72.96% MB can be degraded after visible light irradiation for 1 h over 10 mg Mn vanadate nanosheets in 10 mL MB solution with the concentration of 10 mg L{sup ?1}.

Pei, L.Z., E-mail: lzpei@ahut.edu.cn; Xie, Y.K.; Pei, Y.Q.; Jiang, Y.X.; Yu, H.Y.; Cai, Z.Y.

2013-07-15T23:59:59.000Z

216

Magnetic properties and loss separation in iron-silicone-MnZn ferrite soft magnetic composites  

SciTech Connect (OSTI)

This paper investigates the magnetic and structural properties of iron-based soft magnetic composites coated with silicone-MnZn ferrite hybrid. The organic silicone resin was added to improve the flexibility of the insulated iron powder and causes better adhesion between particles to increase the mechanical properties. Scanning electron microscopy and distribution maps show that the iron particle surface is covered with a thin layer of silicone-MnZn ferrite. Silicone-MnZn ferrite coated samples have higher permeability when compared with the non-magnetic silicone resin coated compacts. The real part of permeability increases by 34.18% when compared with the silicone resin coated samples at 20 kHz. In this work, a formula for calculating the total loss component by loss separation method is presented and finally the different parts of total losses are calculated. The results show that the eddy current loss coefficient is close to each other for the silicone-MnZn ferrite, silicone resin and MnZn ferrite coated samples (0.0078MnZn ferrite coated sample (k{sub 2} =1.4058) in comparison with other samples.

Wu, Shen; Sun, Aizhi; Xu, Wenhuan; Zou, Chao; Yang, Jun; Dong, Juan [School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing (China)

2013-12-16T23:59:59.000Z

217

(12) United States Patent Reardan et al.  

E-Print Network [OSTI]

(12) United States Patent Reardan et al. (54) SENSITIVE DRUG DISTRIBUTION SYSTEM AND METHOD (75 2004/0117205 Al Jun. 17,2004 (51) Int. Cl. G06Q 10/00 (2006.01) (52) U.S. Cl/231 4,976,351 A 1211990 Mangini et al. 5,737,539 A * 411998 Edelson et al. ................. 705/3 5

Shamos, Michael I.

218

(12) United States Patent Likourezos et al.  

E-Print Network [OSTI]

(12) United States Patent Likourezos et al. (54) SYSTEM AND METHOD FOR AUTOMATICALLY EFFECTING Publication Data US 2002/0095376 Al Jul. 18, 2002 Related U.S. Application Data Continuation Altman et al. ................ 705/36 5,715,314 A 211998 Payne et al. 5,794,219 A 811998 Brown 5

Shamos, Michael I.

219

al tratamiento local: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and MEG data (Vigario et al., 1998; Tang et al., 2000a; Vigario et al., 1999, 2000; Wubbeler et al Pearlmutter, Barak 39 Independent Components of...

220

SCIENCE CAREER Al nanoclusters in coagulants and granulates: application  

E-Print Network [OSTI]

SCIENCE CAREER Al nanoclusters in coagulants and granulates: application in arsenic removal from suitable for arsenic removal. The aluminum nanocl- usters Al13 (AlO4Al12(OH)24H2O12 7? ) and Al30 (Al2O8Al coagulant or in Al granulate during water treatment. Keywords Arsenic Á Water treatment Á Al nanoclusters Á

Wehrli, Bernhard

Note: This page contains sample records for the topic "mn al 1970-1974" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Letter Report Documenting Progress of Second Generation ATF FeCrAl Alloy Fabrication  

SciTech Connect (OSTI)

Development of the 2nd generation ATF FeCrAl alloy has been initiated, and a candidate alloy was selected for trial tube fabrication through hot-extrusion and gun-drilling processes. Four alloys based on Fe-13Cr-4.5Al-0.15Y in weight percent were newly cast with minor alloying additions of Mo, Si, Nb, and C to promote solid-solution and second-phase precipitate strengthening. The alloy compositions were selected with guidance from computational thermodynamic tools. The lab-scale heats of ~ 600g were arc-melted and drop-cast, homogenized, hot-forged and -rolled, and then annealed producing plate shape samples. An alloy with Mo and Nb additions (C35MN) processed at 800°C exhibits very fine sub-grain structure with the sub-grain size of 1-3?m which exhibited more than 25% better yield and tensile strengths together with decent ductility compared to the other FeCrAl alloys at room temperature. It was found that the Nb addition was key to improving thermal stability of the fine sub-grain structure. Optimally, grains of less than 30 microns are desired, with grains up to and order of magnitude in desired produced through Nb addition. Scale-up effort of the C35MN alloy was made in collaboration with a commercial cast company who has a capability of vacuum induction melting. A 39lb columnar ingot with ~81mm diameter and ~305mm height (with hot-top) was commercially cast, homogenized, hot-extruded, and annealed providing 10mm-diameter bar-shape samples with the fine sub-grain structure. This commercial heat proved consistent with materials produced at ORNL at the lab-scale. Tubes and end caps were machined from the bar sample and provided to another work package for the ATF-1 irradiation campaign in the milestone M3FT-14OR0202251.

Yamamoto,, Y. [ORNL] [ORNL; Yang, Y. [ORNL] [ORNL; Field, K. G. [ORNL] [ORNL; Terrani, K. [ORNL] [ORNL; Pint, B. A. [ORNL] [ORNL; Snead, L. L. [ORNL] [ORNL

2014-06-10T23:59:59.000Z

222

Calcium EXAFS establishes the Mn-Ca cluster in the oxygen-evolving complex of Photosystem II  

SciTech Connect (OSTI)

The proximity of Ca to the Mn cluster of the photosynthetic water-oxidation complex is demonstrated by X-ray absorption spectroscopy. We have collected EXAFS data at the Ca K-edge using active PS II membrane samples that contain approximately 2 Ca per 4 Mn. These samples are much less perturbed than previously investigated Sr-substituted samples, which were prepared subsequent to Ca depletion. The new Ca EXAFS clearly shows backscattering from Mn at 3.4 angstroms, a distance that agrees with that surmised from previously recorded Mn EXAFS. This result is also consistent with earlier related experiments at the Sr K-edge, using samples that contained functional Sr, that show Mn is {approx}; 3.5 angstroms distant from Sr. The totality of the evidence clearly advances the notion that the catalytic center of oxygen evolution is a Mn-Ca heteronuclear cluster.

Cinco, Roehl M.; McFarlane Holman, Karen L.; Robblee, John H.; Yano, Junko; Pizarro, Shelly A.; Bellacchio, Emanuele; Sauer, Kenneth; Yachandra, Vittal K.

2002-08-02T23:59:59.000Z

223

Synthesis of Li{sub (x)}Na{sub (2-x)}Mn{sub 2}S{sub 3} and LiNaMnS{sub 2} through redox-induced ion exchange reactions  

SciTech Connect (OSTI)

Na{sub 2}Mn{sub 2}S{sub 3} was oxidatively deintercalated using iodine in acetonitrile to yield Na{sub 1.3}Mn{sub 2}S{sub 3}, with lattice constants nearly identical to that of the reactant. Lithium was then reductively intercalated into the oxidized product to yield Li{sub 0.7}Na{sub 1.3}Mn{sub 2}S{sub 3}. When heated, this metastable compound decomposed to form a new crystalline compound, LiNaMnS{sub 2}, along with MnS and residual Na{sub 2}Mn{sub 2}S{sub 3}. Single crystal X-ray diffraction structural analysis of LiNaMnS{sub 2} revealed that this compound crystallizes in P-3m1 with cell parameters a=4.0479(6) A, c=6.7759(14) A, V=96.15(3) A{sup 3} (Z=1, wR2=0.0367) in the NaLiCdS{sub 2} structure-type. - Graphical abstract: Structure of LiNaMnS{sub 2}. Li and Mn are statistically distributed in edge-shared tetrahedral environments linked into infinite planes. Sodium ions occupy interlayer sites.

Luthy, Joshua A.; Goodman, Phillip L. [Department of Chemistry and Biochemistry, Texas State University-San Marcos, 601 University Drive, San Marcos, TX 78666 (United States); Martin, Benjamin R. [Department of Chemistry and Biochemistry, Texas State University-San Marcos, 601 University Drive, San Marcos, TX 78666 (United States)], E-mail: bmartin@txstate.edu

2009-03-15T23:59:59.000Z

224

PVP-Assisted ZrO2 coating on LiMn2O4 spinel cathode nanoparticles prepared by MnO2 nanowire templates  

E-Print Network [OSTI]

solution. Upon annealing at 600 °C in air, an amorphous ZrO2 nanoscale coating layer was obtained [5­10]. Although Li-ion batteries are attractive power-storage devices that have high energy density metal oxide coatings have been reported, studies to improve both the rate capabilities of spinel LiMn2O4

Cho, Jaephil

225

Measurement of the transmission magnetic circular dichroism of Ga{sub 1?x}Mn{sub x}As epilayers using a built-in p-i-n photodiode  

SciTech Connect (OSTI)

By constructing a GaMnAs epilayer/semi-insulating In{sub 0.2}Ga{sub 0.8}As/(001) n{sup +}-GaAs substrate layer structure as a built-in p-i-n photodiode, we developed a scheme for on-chip measurements of transmission magnetic circular dichroism (T-MCD). Both the hysteresis loops in the magnetic field sweeps and the wavelength scans at saturated magnetic fields measured using the new T-MCD scheme, illustrated the same features as those previously measured on the freestanding GaMnAs thin films by conventional T-MCD. Because a large group of epitaxially grown magnetic film/semiconductor heterostructures, such as Fe, NiFe, CoFeAl, and MnGa films on semiconductor substrates, are becoming important new building blocks for semiconductor-based spin field-effect transistor, perpendicular magnetic tunnel junction (p-MTJ) and lateral MTJ devices, the new T-MCD scheme can be applied to tests of their magnetic properties by forming either p-i-n or Schottky photodiodes.

He, Z. X.; Zheng, H. Z., E-mail: hzzheng@red.semi.ac.cn; Wang, H. L.; Zhao, J. H. [State Key Laboratory of Superlattices and Microstructures, Institute of Semiconductors, Chinese Academy of Sciences, P. O. Box 912, Beijing 100083 (China)

2014-02-28T23:59:59.000Z

226

PROYECTO DE CAMBIOS AL DFL1 PRESENTADO AL CONGRESO EN 1999  

E-Print Network [OSTI]

PROYECTO DE CAMBIOS AL DFL1 PRESENTADO AL CONGRESO EN 1999 LEY GENERAL DE SERVICIOS ELECTRICOS hace, en materias de electricidad, gas y combustibles lĂ­quidos, al Ministerio del Interior o al Ministro del Interior, deberĂĄn entenderse referidas al Ministerio de EconomĂ­a, Fomento y ReconstrucciĂłn o

Rudnick, Hugh

227

X-ray Emission Spectroscopy to Study Ligand Valence Orbitals in Mn Coordination Complexes  

SciTech Connect (OSTI)

We discuss a spectroscopic method to determine the character of chemical bonding and for the identification of metal ligands in coordination and bioinorganic chemistry. It is based on the analysis of satellite lines in X-ray emission spectra that arise from transitions between valence orbitals and the metal ion 1s level (valence-to-core XES). The spectra, in connection with calculations based on density functional theory (DFT), provide information that is complementary to other spectroscopic techniques, in particular X-ray absorption (XANES and EXAFS). The spectral shape is sensitive to protonation of ligands and allows ligands, which differ only slightly in atomic number (e.g., C, N, O...), to be distinguished. A theoretical discussion of the main spectral features is presented in terms of molecular orbitals for a series of Mn model systems: [Mn(H2O)6]2+, [Mn(H2O)5OH]+, [Mn(H2O)5NH2]+, and [Mn(H2O)5NH3]2+. An application of the method, with comparison between theory and experiment, is presented for the solvated Mn2+ ion in water and three Mn coordination complexes, namely [LMn(acac)N3]BPh4, [LMn(B2O3Ph2)(ClO4)], and [LMn(acac)N]BPh4, where L represents 1,4,7-trimethyl-1,4,7-triazacyclononane, acac stands for the 2,4-pentanedionate anion, and B2O3Ph2 represents the 1,3-diphenyl-1,3-dibora-2-oxapropane-1,3-diolato dianion.

Smolentsev, Grigory; Soldatov, Alexander V; Messinger, Johannes; Merz, Kathrin; Weyhermuller, Thomas; Bergmann, Uwe; Pushkar, Yulia; Yano, Junko; Yachandra, Vittal K.; Glatzel, Pieter

2009-03-02T23:59:59.000Z

228

Supercapacitor behavior of ?-MnMoO{sub 4} nanorods on different electrolytes  

SciTech Connect (OSTI)

Graphical abstract: SEM image of ?-MnMoO{sub 4} nanorods on FTO substrate. Highlights: ? Synthesis of ?-MnMoO{sub 4} nanorods by spin coating method. ? First study on the effect of electrolyte on the pseudocapacitance behavior. ? ?-MnMoO{sub 4} nanorods exhibit maximum specific capacitance of 998 F/g. ? At higher scan rates p-TSA electrolyte exhibits superior capacitive behavior. -- Abstract: ?-MnMoO{sub 4} nanorods were prepared on conducting glass substrate via sol–gel spin coating method at the optimum doping level. The effect of electrolyte on the pseudocapacitance behavior of the ?-MnMoO{sub 4} nanorods was studied using para toluene sulfonic acid (p-TSA), sulfuric acid (H{sub 2}SO{sub 4}) and hydrochloric acid (HCl) as electrolytes. X-ray diffraction analysis reveals the formation of ?-MnMoO{sub 4} in monoclinic phase. FTIR spectra contain vibrational bands associated with Mo=O, M–O and Mo–O–Mo bonds. SEM image reveals the formation of nanorods. Supercapacitor behavior has been studied using cyclic voltammetry (CV) analysis. ?-MnMoO{sub 4} nanorods exhibit maximum specific capacitance of 998 F/g at a scan rate of 5 mV/s in H{sub 2}SO{sub 4} electrolyte while a specific capacitance of 784 F/g and 530 F/g have been obtained using p-TSA and HCl electrolytes, respectively. At higher scan rates p-TSA electrolyte exhibits superior capacitive behavior than H{sub 2}SO{sub 4}.

Purushothaman, K.K., E-mail: purushoth_gri@yahoo.co.in [Department of Physics, TRP Engineering College (SRM Group), Irungalur, Trichy, Tamilnadu (India); Cuba, M. [Department of Physics, Gandhigram Rural Institute – Deemed University, Gandhigram, Tamilnadu (India)] [Department of Physics, Gandhigram Rural Institute – Deemed University, Gandhigram, Tamilnadu (India); Muralidharan, G., E-mail: muralg@rediffmail.com [Department of Physics, Gandhigram Rural Institute – Deemed University, Gandhigram, Tamilnadu (India)

2012-11-15T23:59:59.000Z

229

The geochemical evolution of the Sonju Lake intrusion: assimilation and fractional crystallization in a layered mafic intrusion near Finland, Mn.  

E-Print Network [OSTI]

??The Sonju Lake Intrusion, located within the Beaver Bay Complex near Finland, MN, is the most completely differentiated intrusion related to the Midcontinent Rift System… (more)

Dayton, Ryan N.

2011-01-01T23:59:59.000Z

230

Enhanced ferromagnetic order in Sr{sub 4}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} featuring canted [MnO{sub 4}]{sub ?} spin chains of mixed-valent Mn(III)/Mn(IV). Aliovalent substitution of the Sr{sub 4?x}Ln{sub x}Mn{sup III}{sub 2+x}Mn{sup IV}{sub 1?x}O{sub 3}(GeO{sub 4}){sub 3} solid-solution  

SciTech Connect (OSTI)

Crystals of Sr{sub 4?x}Ln{sub x}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} (x=0; x?0.15 for Ln=La, Pr, Nd, Sm. Eu, Gd, Dy; x?0.3 for Ln=Gd) were isolated upon using high-temperature, solid-state methods in molten-salt media. These compounds are isostructural with the previously reported Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3} (Ln=La, Sm, Gd) series that contains the same [MnO{sub 4}]{sub ?} spin chains. The synthesis of the Sr{sub 4}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} (x=0) phase was carried out by a double aliovalent substitution with respect to the Sr{sup 2+} and Ge{sup 4+} ions that replace Na{sup +}/Ln{sup 3+} and As{sup 5+} in Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3}, respectively. The title series contains mixed-valent Mn(III)/Mn(IV) and shows a limited range of solid solution, both of which were not observed in the previously reported Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3} series. To form the Sr{sub 4?x}Ln{sub x}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} solid solution, one of the Sr{sup 2+} sites, i.e., the original Ln-site in Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3}, is partially substituted by Ln{sup 3+} in a statistical disorder of Sr{sub 1?x}/Ln{sub x}. Initial magnetic investigations of selected derivatives reveal higher ferromagnetic ordering temperatures than those reported for the Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3} series, presumably attributed to a lesser degree of canting as a result of introducing non-Jahn–Teller Mn{sup 4+} ions. Also intriguing is the observation of multiple anomalies at low temperatures which appear to be of electronic origins. - Graphical abstract: Sr{sub 4?x}Ln{sub x}Mn(III){sub 2+x}Mn(IV){sub 1?x}O{sub 3}(GeO{sub 4}){sub 3}. Display Omitted - Highlights: • Double aliovalent substitution: Sr{sub 4}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} with respect to Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3}. • Solid solution with respect to statistical disorder of Sr{sub 1?x}Ln{sub x} in one of the two Sr sites. • Mn{sup 3+}/Mn{sup 4+} magnetic ions are spatially arranged in a triangular kagomé fashion. • Enhanced ferromagnetic ordering attributed to doping non-Jahn–Teller Mn{sup 4+}.

West, J. Palmer; Sulejmanovic, Dino [Department of Chemistry, Clemson University, Clemson, SC 29634 (United States); Becht, Gregory [E. I. du Pont, Wilmington, DE 19880-0500 (United States); He, Jian; Hitchcock, Dale [Department of Physics and Astronomy, Clemson University, Clemson, SC 29634 (United States); Yan, Yonggao [Wuhan University of Technology, Wuhan 430070 (China); Hwu, Shiou-Jyh, E-mail: shwu@clemson.edu [Department of Chemistry, Clemson University, Clemson, SC 29634 (United States)

2013-10-15T23:59:59.000Z

231

High-Resolution Structure of the Photosynthetic Mn4Ca Catalyst from X-ray Spectroscopy  

SciTech Connect (OSTI)

The application of high-resolution X-ray spectroscopy methods to study the photosynthetic water oxidizing complex, which contains a unique hetero-nuclear catalytic Mn4Ca cluster, are described. Issues of X-ray damage especially at the metal sites in the Mn4Ca cluster are discussed. The structure of the Mn4Ca catalyst at high-resolution which has so far eluded attempts of determination by X-ray diffraction, EXAFS and other spectroscopic techniques has been addressed using polarized EXAFS techniques applied to oriented PS II membrane preparations and PS II single crystals. A review of how the resolution of traditional EXAFS techniques can be improved, using methods such as range-extended EXAFS is presented, and the changes that occur in the structure of the cluster as it advances through the catalytic cycle are described. X-ray absorption and emission techniques (XANES and K? emission) have been used earlier to determine the oxidation states of the Mn4Ca cluster, and in this report we review the use of X-ray resonant Raman spectroscopy to understand the electronic structure of the Mn4Ca cluster as it cycles through the intermediate S-states.

Yachandra, Vittal; Yano, Junko; Kern, Jan; Pushkar, Yulia; Sauer, Kenneth; Glatzel, Pieter; Bergmann, Uwe; Messinger, Johannes; Zouni, Athina; Yachandra, Vittal K.

2007-08-01T23:59:59.000Z

232

Oxidation State Changes of the Mn(4)Ca Cluster in Photosystem II  

SciTech Connect (OSTI)

A detailed electronic structure of the Mn{sub 4}Ca cluster is required before two key questions for understanding the mechanism of photosynthetic water oxidation can be addressed. They are whether all four oxidizing equivalents necessary to oxidize water to O{sub 2} accumulate on the four Mn ions of the oxygen-evolving complex, or do some ligand-centered oxidations take place before the formation and release of O{sub 2} during the S{sub 3} {yields} [S{sub 4}] {yields} S{sub 0} transition, and what are the oxidation state assignments for the Mn during S-state advancement. X-ray absorption and emission spectroscopy of Mn, including the newly introduced resonant inelastic X-ray scattering spectroscopy have been used to address these questions. The present state of understanding of the electronic structure and oxidation state changes of the Mn{sub 4}Ca cluster in all the S-states, particularly in the S{sub 2} to S{sub 3} transition, derived from these techniques is described in this review.

Yano, J.; Yachandra, V.K.

2009-06-04T23:59:59.000Z

233

Magnetoresistance in Mn ion-implanted GaAs:Zn nanowires  

SciTech Connect (OSTI)

We have investigated the magnetoresistance (MR) in a series of Zn doped (p-type) GaAs nanowires implanted with different Mn concentrations. The nanowires with the lowest Mn concentration (?0.0001%) exhibit a low resistance of a few k? at 300?K and a 4% positive MR at 1.6?K, which can be well described by invoking a spin-split subband model. In contrast, nanowires with the highest Mn concentration (4%) display a large resistance of several M? at 300?K and a large negative MR of 85% at 1.6?K. The large negative MR is interpreted in terms of spin-dependent hopping in a complex magnetic nanowire landscape of magnetic polarons, separated by intermediate regions of Mn impurity spins. Sweeping the magnetic field back and forth for the 4% sample reveals a hysteresis that indicates the presence of a weak ferromagnetic phase. We propose co-doping with Zn to be a promising way to reach the goal of realizing ferromagnetic Ga{sub 1?x}Mn{sub x}As nanowires for future nanospintronics.

Paschoal, W.; Kumar, Sandeep; Jain, V.; Pettersson, H., E-mail: hakan.pettersson@hh.se [Solid State Physics/The Nanometer Structure Consortium, Lund University, Box 118, SE-221 00 Lund (Sweden); Department of Mathematics, Physics and Electrical Engineering, Halmstad University, Box 823, SE-301 18, Halmstad (Sweden); Jacobsson, D.; Samuelson, L. [Solid State Physics/The Nanometer Structure Consortium, Lund University, Box 118, SE-221 00 Lund (Sweden); Johannes, A.; Ronning, C. [Institute for Solid State Physics, Friedrich-Schiller-University Jena, Max-Wien-Platz 1, D-07743 Jena (Germany); Canali, C. M.; Pertsova, A. [Department of Physics and Electrical Engineering, Linneaus University, SE-39233 Kalmar (Sweden); Dick, K. A. [Solid State Physics/The Nanometer Structure Consortium, Lund University, Box 118, SE-221 00 Lund (Sweden); Center for Analysis and Synthesis, Lund University, Box 124, S-221 00 Lund (Sweden)

2014-04-14T23:59:59.000Z

234

Carbon/lambda-MnO{sub 2} composites for supercapacitor electrodes  

SciTech Connect (OSTI)

In the present work a composite of carbon with lambda-MnO{sub 2} have been synthesized by a simple two-step route. In the first step, to obtain LiMn{sub 2}O{sub 4}/carbon material, mesoporous activated carbon was impregnated with the solution of precursor metal salts and heated subsequently. As-prepared materials were acid treated which resulted in the formation of lambda-MnO{sub 2}/carbon. Physical properties, structure and specific surface area of electrode materials were studied by TEM, X-ray diffraction and nitrogen sorption measurements. Voltammetry cycling, galvanostatic charge/discharge and impedance spectroscopy measurements performed in two- and three-electrode cells have been applied in order to measure electrochemical parameters. TEM images confirmed well dispersed lambda-MnO{sub 2} particles on the surface of carbon material. The carbon in the composite plays an important role as the surface area enhancing component and a support of pseudocapacitive material. Furthermore, the through-connected porosity serves as a continuous pathway for electrolyte transport. A synergetic effect of the porous carbon framework and of the redox properties of the lambda-MnO{sub 2} is at the origin of improvement of specific capacitance values which has been observed for composites after delithiation. - Comparison of capacitance characteristics for initial carbon and synthesised composites for CB in 1 mol L{sup -1} Na{sub 2}SO{sub 4} solution.

Malak-Polaczyk, A., E-mail: agnieszka-malak@wp.p [Institute of Chemistry and Technical Electrochemistry, Poznan University of Technology, Piotrowo 3, 60-695 Poznan (Poland); Institut de Sciences des Materiaux de Mulhouse, CNRS LRC 7228, 15 Rue Starcky, 68057 Mulhouse (France); Matei-Ghimbeu, C.; Vix-Guterl, C. [Institut de Sciences des Materiaux de Mulhouse, CNRS LRC 7228, 15 Rue Starcky, 68057 Mulhouse (France); Frackowiak, E. [Institute of Chemistry and Technical Electrochemistry, Poznan University of Technology, Piotrowo 3, 60-695 Poznan (Poland)

2010-04-15T23:59:59.000Z

235

Supra-Canonical 26Al/27Al and the Residence Time of CAIs in the  

E-Print Network [OSTI]

Supra-Canonical 26Al/27Al and the Residence Time of CAIs in the Solar Protoplanetary Disk Edward D initial 26Al/27Al ratio of 4.5 � 10­5 has been a fiducial marker for the beginning of the solar system that some CAIs had initial 26Al/27Al values at least 25% greater than canonical and that the canonical

Harrison, Mark

236

Scott Taylor, ALS Safety Manager  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administrationcontroller systemsBi (2) Sr (2)ScienceScientists In thePrincetonScott Taylor, ALS

237

AL2007-02.doc  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergy Cooperation |South Valley ResponsibleSubmissionofDepartmentNo. AL7.pdf6-04v2.pdfContractor

238

AL PRO | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of Inspector GeneralDepartmentAUDIT REPORT Americium/Curium Vitrification Project AtOpenLabsEspanaAL PRO Jump

239

ALS 20th Anniversary Celebration  

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AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07)Operations During the months3ALCC PastALPES20thALS

240

ALS Doctoral Fellowship in Residence  

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241

ALS Evidence Confirms Combustion Theory  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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242

ALS Evidence Confirms Combustion Theory  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07)Operations DuringALS Doctoral Fellowship inALSALSALS

243

Teatro al Sur y la escena Argentina  

E-Print Network [OSTI]

140 LATIN AMERICAN THEATRE REVIEW Teatro al Sur y la escena Argentina Acaba de aparecer un nuevo número de Teatro al Sur, Revista Latinoamericana. Su título de tapa - Teatro Argentino a varias voces - resume la intención de esta nueva entrega...

Editors

2000-04-01T23:59:59.000Z

244

ALS User Meeting Highlights Challenges, Accomplishments  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

advantage of those. ALS Director Roger Falcone was up next and he began with a sad acknowledgement of the passing of a veteran ALS user, Dennis Lindle. While the past year has been...

245

Unique light-induced degradation in yellow-emitting K{sub 2}SiF{sub 6}:Mn{sup 2+} phosphor  

SciTech Connect (OSTI)

Photo-induced luminescence intensity degradation in yellow-emitting K{sub 2}SiF{sub 6}:Mn{sup 2+} phosphor is studied using x-ray diffraction measurement, photoluminescence (PL) analysis, PL excitation (PLE) spectroscopy, PL decay analysis, and electron spin resonance (ESR) measurement. The yellow-emitting K{sub 2}SiF{sub 6}:Mn{sup 2+} phosphor exhibits remarkable degradation in the PL intensity under Xe lamp exposure. Coherent laser irradiation also induces degradation and its degree is in the order of He–Cd (??=?325?nm)?>?Ar{sup +} (488?nm)?>?He–Ne laser (632.8?nm). The degradation mechanism is proposed to be due to change in the valence state of manganese ions from Mn{sup 2+} to Mn{sup 3+} by the photooxidation (Mn{sup 2+} ? Mn{sup 3+}) or disproportionation reaction (2Mn{sup 2+} ? Mn{sup +} + Mn{sup 3+}). The ESR measurement confirms the decreased Mn{sup 2+} spin density in the sample exposed with Xe lamp. The PLE spectrum suggests that the excitation of Mn{sup 3+} ions occurs through energy transfer upon absorption of exciting radiation by the Mn{sup 2+} ions. Thermal annealing of the degraded samples at ?200?°C causes a blueshift in the PL emission band with an appearance of the Mn{sup 4+}-related sharp red emission lines.

Oyama, Takuya; Adachi, Sadao, E-mail: adachi@el.gunma-u.ac.jp [Division of Electronics and Informatics, Faculty of Science and Technology, Gunma University, Kiryu-shi, Gunma 376-8515 (Japan)

2014-10-07T23:59:59.000Z

246

(12) United States Patent Vertes et al.  

E-Print Network [OSTI]

(12) United States Patent Vertes et al. (54) THREE-DIMENSIONAL MOLECULAR IMAGING BY INFRARED LASER/0012831 Al Jan. 21, 2010 Related U.S. Application Data (63) Continuation-in-part of application No. 121176,656,690 B2 6,744,046 B2 6,991,903 B2 7,084,396 B2 12/2003 Crooke et al. 612004 Valaskovic et al. 112006 Fu

Vertes, Akos

247

(12) United States Patent Vertes et al.  

E-Print Network [OSTI]

(12) United States Patent Vertes et al. (54) LASER DESORPTION IONIZATION AND PEPTIDE SEQUENCING. (21) Appl. No.: 11/674,671 (22) Filed: Feb. 14,2007 (65) Prior Publication Data US 2009/0321626 Al Dec Suizdak et al. 6,589,485 B2 7/2003 Koster 6,794,196 B2 912004 Fonash et al. 6,846,681 B2 112005 Buriak et

Vertes, Akos

248

(12) United States Patent Reardan et al.  

E-Print Network [OSTI]

(12) United States Patent Reardan et al. (54) SENSITIVE DRUG DISTRIBUTION SYSTEM AND METHOD (75 US 2005/0090425 Al Apr. 28, 2005 Related U.S. Application Data Division of application No.1 0,847,764 A 711989 Halvorson 4,976,351 A 1211990 Mangini et al. 5,737,539 A 411998 Edelson et al. 5,845,255 A 1211998

Shamos, Michael I.

249

(12) United States Patent Fallon et al.  

E-Print Network [OSTI]

(12) United States Patent Fallon et al. (54) SYSTEM AND METHOD FOR DATA FEED ACCELERATION/131,631 (22) Filed: Jun. 2,2008 (65) Prior Publication Data US 200910287839 Al Nov. 19,2009 Related U References Cited U.S. PATENT DOCUMENTS 3,394,352 A 7/1968 Wernikoff et al. 3,490,690 A 111970 Apple et al. 4

Shamos, Michael I.

250

United States Patent [191 Jalali et al.  

E-Print Network [OSTI]

antennas: SPIE vol. 1703 (1992) 264-271. GA Magel et al.: "Phosphosilicate Glass waveguides for phased

Jalali. Bahram

251

Aluminium distribution in ZSM-5 revisited: The role of Al-Al interactions  

SciTech Connect (OSTI)

We present a theoretical study of the distribution of Al atoms in zeolite ZSM-5 with Si/Al=47, where we focus on the role of Al-Al interactions rather than on the energetics of Al/Si substitutions at individual sites. Using interatomic potential methods, we evaluate the energies of the full set of symmetrically independent configurations of Al siting in a Si{sub 94}Al{sub 2}O{sub 192} cell. The equilibrium Al distribution is determined by the interplay of two factors: the energetics of the Al/Si substitution at an individual site, which tends to populate particular T sites (e.g., the T14 site), and the Al-Al interaction, which at this Si/Al maximises Al-Al distances in general agreement with Dempsey's rule. However, it is found that the interaction energy changes approximately as the inverse of the square of the distance between the two Al atoms, rather than the inverse of the distance expected if this were merely charge repulsion. Moreover, we find that the anisotropic nature of the framework density plays an important role in determining the magnitude of the interactions, which are not simply dependent on Al-Al distances. - Graphical abstract: Role of Al-Al interactions in high silica ZSM-5 is shown to be anisotropic in nature and not dependent solely on Coulombic interactions. Highlights: Black-Right-Pointing-Pointer Si-Al distribution in ZSM-5 is revisited, stressing the role of the Al-Al interaction. Black-Right-Pointing-Pointer Coulomb interactions are not the key factors controlling the Al siting. Black-Right-Pointing-Pointer Anisotropy of the framework is identified as a source of departure from Dempsey's rule.

Ruiz-Salvador, A. Rabdel, E-mail: rabdel@imre.oc.uh.cu [Group of Materials Developed by Design, Division of Chemistry and Technology of Materials, Institute of Materials Science and Engineering (IMRE), University of Havana, Havana 10400 (Cuba); Grau-Crespo, Ricardo; Gray, Aileen E.; Lewis, Dewi W. [Department of Chemistry, University College London, 20 Gordon Street, London, WC1H OAJ (United Kingdom)] [Department of Chemistry, University College London, 20 Gordon Street, London, WC1H OAJ (United Kingdom)

2013-02-15T23:59:59.000Z

252

Effect of Al-Si-Al and Al-Si-Si-Al Pairs in the ZSM-5 Zeolite Framework on the 27 NMR Spectra. A Combined High-Resolution 27  

E-Print Network [OSTI]

Effect of Al-Si-Al and Al-Si-Si-Al Pairs in the ZSM-5 Zeolite Framework on the 27 Al NMR Spectra. A Combined High-Resolution 27 Al NMR and DFT/MM Study Jiri´ Dedecek, Stepan Sklenak,*, Chengbin Li, Blanka of the presence of Al-O-Si-O-Al and Al-O-Si-O-Si-O-Al sequences in the ZSM-5 zeolite framework on the local

Sklenak, Stepan

253

United States Patent [19] Miura et al.  

E-Print Network [OSTI]

of Pyrrole--3,4--diacetic Acid and Its Derivatives", Synthesis, pp. 262--265 (1989). Coderre et al., "Boron/1992 OTHER PUBLICATIONS Japan . Japan . WIPO . WIPO . Miura et al.,, "Synthesis, Tissue Uptake, and Toxicity Therapy for Cancer, Kobe, Japan (Oct. 31--Nov. 4, 1994). Miura et al., "Synthesis and Spectroscopic

Shelnutt, John A.

254

SMERDON ET AL.: AUXILIARY MATERIAL Auxiliary Material  

E-Print Network [OSTI]

run [Ammann et al., 2007; hereinafter CCSM] and the GKSS ECHO-g ERIK2 run [Gonzålez-Rouco et al., 2006; hereinafter ECHO-g]. The annual means of the modeled temperature fields are interpolated to 5° latitude;SMERDON ET AL.: AUXILIARY MATERIAL 2 ECHO-g simulations, respectively. The above conventions

Smerdon, Jason E.

255

AUTORIT ACCADEMICHE Situazione al 27 settembre 2012  

E-Print Network [OSTI]

AUTORITĂ? ACCADEMICHE Situazione al 27 settembre 2012 Presidenti dei Comitati di direzione delle FacoltĂ  e Scuole FacoltĂ  di Giurisprudenza Prof. Francesco Denozza dal 10.9.2012 al 30.9.2014 FacoltĂ  di Scienze politiche, economiche e sociali Prof.ssa Laura Ammannati dal 10.9.2012 al 30.9.2014 FacoltĂ  di

De Cindio, Fiorella

256

United States Patent [19] Church et al.  

E-Print Network [OSTI]

United States Patent [19] Church et al. [54] CHARACTERIZATION OF INDIVIDUAL POLYMER MOLECULES BASED al.. "ANeutral Amino Acid Change in Segment TIS4 Dramatically Alters the Gating Properties of the Volt- age-Dependent Sodium Channel". 1990, Proc. Natl. Acad. Sci. USA, 87:323-27. Bensirnon. A.. et al

Church, George M.

257

(12) United States Patent Likourezos et al.  

E-Print Network [OSTI]

(12) United States Patent Likourezos et al. (54) SYSTEM AND METHOD FOR EFFECTING A REAL: Nov. 14, 2001 (65) Prior Publication Data US 2002/0095377 Al Jul. 18, 2002 Related U.S. Application Cited U.S. PATENT DOCUMENTS 4,799,156 A 4,876,648 A 111989 Shavit et al. 1011989 Lloyd 102 102 111111

Shamos, Michael I.

258

Deutsch als Zweitsprache in der Lehrerausbildung  

E-Print Network [OSTI]

Deutsch als Zweitsprache in der Lehrerausbildung Bedarf ­ Umsetzung ­ Perspektiven Dokumentation. JÜrg Roche, Ludwig-Maximilians-Universität Mßnchen Deutsch als Zweitsprache in der Lehrerausbildung Deutsch als Fremdsprache, Ludwig- Maximilians-Universität Mßnchen Wie wird die Qualität der Da

Prediger, Susanne

259

(12) United States Patent Vertes et al.  

E-Print Network [OSTI]

(12) United States Patent Vertes et al. (54) NANOPHOTONIC PRODUCTION, MODULATION AND SWITCHING to any disclaimer, the term ofthis patent is extended or adjusted under 35 U.S.c. 154(b) by 194 days. (21) References Cited U.S. PATENT DOCUMENTS 200910236512 Al * 912009 Naya et al. .................... 250/281 2009

Vertes, Akos

260

Anomalously large spin susceptibility enhancement in n-doped CdMnTe quantum wells  

SciTech Connect (OSTI)

We report on time-resolved Kerr rotation (TRKR) experiments done on n-doped CdMnTe quantum wells (QWs), in the regime where strong coupling between the electron and the Mn spin-flip excitations shows up. It has been proposed previously to deduce the 2D electron gas spin susceptibility from the coupling energy between these spin excitations. Here we measure the coupling energy on a high mobility sample down to very low excitation density, and compare the results with spin-flip Raman scattering (SFRS) on the same sample. The electron spin polarizations measured by TRKR and SFRS are found in relatively good agreement. However the spin susceptibility measured by TRKR exceeds systematically the values predicted by many-body theory. This could be an indication that the two-oscillator model used to describe mixed electron-Mn spin excitations needs to be improved.

Ben Cheikh, Z. [Laboratoire Charles Coulomb, UMR 5221, Département Semi-conducteurs, Matériaux et Capteurs, Université Montpellier 2, France and Laboratoire de Physique des Matériaux: Structures et Propriétés, Faculté (Tunisia); Cronenberger, S.; Vladimirova, M.; Scalbert, D. [Laboratoire Charles Coulomb, UMR 5221, Departement Semi-conducteurs, Materiaux et Capteurs, Universite Montpellier 2 (France); Boujdaria, K. [Laboratoire de Physique des Matériaux: Structures et Propriétés, Faculté des Sciences de Bizerte, Université de Carthage, 7021 Zarzouna (Tunisia); Baboux, F.; Perez, F. [Institut des NanoSciences de Paris, CNRS/Université Paris 6, 4 place Jussieu, F-75005 Paris (France); Wojtowicz, T.; Karczewski, G. [Institute of Physics, Polish Academy of Sciences, 02-668 Warsaw (Poland)

2013-12-04T23:59:59.000Z

Note: This page contains sample records for the topic "mn al 1970-1974" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

In-situ spectro-microscopy on organic films: Mn-Phthalocyanine on Ag(100)  

SciTech Connect (OSTI)

Metal phthalocyanines are attracting significant attention, owing to their potential for applications in chemical sensors, solar cells and organic magnets. As the electronic properties of molecular films are determined by their crystallinity and molecular packing, the optimization of film quality is important for improving the performance of organic devices. Here, we present the results of in situ low-energy electron microscopy / photoemission electron microscopy (LEEM/PEEM) studies of incorporation-limited growth [1] of manganese-phthalocyanine (MnPc) on Ag(100) surfaces. MnPc thin films were grown on both, bulk Ag(100) surface and thin Ag(100)/Fe(100) films, where substrate spin-polarized electronic states can be modified through tuning the thickness of the Ag film [2]. We also discuss the electronic structure and magnetic ordering in MnPc thin films, investigated by angle- and spin-resolved photoemission spectroscopy.

Al-Mahboob A.; Vescovo, E.; Sadowski, J.T.

2013-08-18T23:59:59.000Z

262

The resistance to cavitation erosion of CrMnN stainless steels  

SciTech Connect (OSTI)

The resistance to cavitation erosion (CE) was measured using a magnetostrictive device and a rotating disk device for some CrMnN stainless steels (Chinese patent ZL 90 1 02197.0). The microstructural changes in the surface layer before and after CE were analyzed by use of Mossbauer spectra. Results show that the resistance to CE of duplex austenitic-martensitic CrMnN stainless steels is much better than that of ZG0Cr13Ni4-6Mo and ZG0Cr16Ni5Mo steel, which are in common use for hydraulic turbine runners. The metastable austenite and its changes in the process of CE are the key factors why the CrMnN stainless steels have excellent resistance to cavitation erosion.

Fu, W.T. [Yanshan Univ., Qinhuangdao (China). Dept. of Materials Engineering] [Yanshan Univ., Qinhuangdao (China). Dept. of Materials Engineering; [Harbin Inst. of Tech. (China); Jing, T.F.; Zheng, Y.Z. [Yanshan Univ., Qinhuangdao (China). Dept. of Materials Engineering] [Yanshan Univ., Qinhuangdao (China). Dept. of Materials Engineering; Yang, Y.B. [Yanshan Univ., Qinhuangdao (China). Dept. of Materials Engineering] [Yanshan Univ., Qinhuangdao (China). Dept. of Materials Engineering; [Bohai Aluminum Industries Co., Ltd., Qinhuangdao (China); Yao, M. [Harbin Inst. of Tech. (China)] [Harbin Inst. of Tech. (China)

1998-12-01T23:59:59.000Z

263

Ferromagnetism and the electronic band structure in (Ga,Mn)(Bi,As) epitaxial layers  

SciTech Connect (OSTI)

Impact of Bi incorporation into (Ga,Mn)As layers on their electronic- and band-structures as well as their magnetic and structural properties has been studied. Homogenous (Ga,Mn)(Bi,As) layers of high structural perfection have been grown by the low-temperature molecular-beam epitaxy technique. Post-growth annealing treatment of the layers results in an improvement of their structural and magnetic properties and an increase in the hole concentration in the layers. The modulation photoreflectance spectroscopy results are consistent with the valence-band model of hole-mediated ferromagnetism in the layers. This material combines the properties of (Ga,Mn)As and Ga(Bi,As) ternary compounds and offers the possibility of tuning its electrical and magnetic properties by controlling the alloy composition.

Yastrubchak, O., E-mail: yastrub@hektor.umcs.lublin.pl [Institute of Physics, Maria Curie-Sklodowska University in Lublin, Pl. M. Curie-Sk?odowskiej 1, 20-031 Lublin (Poland); Institute of Semiconductor Physics, National Academy of Sciences, 41 pr. Nauki, 03028 Kyiv (Ukraine); Sadowski, J. [MAX-IV Laboratory, Lund University, P.O. Box 118, SE-221 00 Lund (Sweden); Institute of Physics, Polish Academy of Sciences, Al. Lotnikow 32/46, 02-668 Warsaw (Poland); Gluba, L.; ?uk, J.; Kulik, M. [Institute of Physics, Maria Curie-Sklodowska University in Lublin, Pl. M. Curie-Sk?odowskiej 1, 20-031 Lublin (Poland); Domagala, J. Z.; Andrearczyk, T.; Wosinski, T. [Institute of Physics, Polish Academy of Sciences, Al. Lotnikow 32/46, 02-668 Warsaw (Poland); Rawski, M. [Analytical Laboratory, Maria Curie-Sklodowska University in Lublin, Pl. M. Curie-Sk?odowskiej 3, 20-031 Lublin (Poland)

2014-08-18T23:59:59.000Z

264

Shell Model for Atomistic Simulation of Lithium Diffusion in Mixed Mn/Ti Oxides  

SciTech Connect (OSTI)

Mixed Mn/Ti oxides present attractive physicochemical properties such as their ability to accommodate Li for application in Li-ion batteries. In this work, atomic parameters for Mn were developed to extend an existing shell model of the Li-Ti-O system and allow simulations of pure and lithiated Mn and mixed Mn/Ti oxide polymorphs. The shell model yielded good agreement with experimentally-derived structures (i.e. lattice parameters and inter-atomic distances) and represented an improvement over existing potential models. The shell model was employed in molecular dynamics (MD) simulations of Li diffusion in the 1×1 c direction channels of LixMn1 yTiyO2 with the rutile structure, where 0 ? x ? 0.25 and 0 ? y ? 1. In the infinite dilution limit, the arrangement of Mn and Ti ions in the lattice was found to have a significant effect on the activation energy for Li diffusion in the c channels due to the destabilization of half of the interstitial octahedral sites. Anomalous diffusion was demonstrated for Li concentrations as low as x = 0.125, with a single Li ion positioned in every other c channel. Further increase in Li concentration showed not only the substantial effect of Li-Li repulsive interactions on Li mobility but also their influence on the time dependence of Li diffusion. The results of the MD simulations can inform intrinsic structure-property relationships for the rational design of improved electrode materials for Li-ion batteries.

Kerisit, Sebastien N.; Chaka, Anne M.; Droubay, Timothy C.; Ilton, Eugene S.

2014-10-23T23:59:59.000Z

265

Colossal anisotropic resistivity and oriented magnetic domains in strained La{sub 0.325}Pr{sub 0.3}Ca{sub 0.375}MnO{sub 3} films  

SciTech Connect (OSTI)

Magnetic and resistive anisotropies have been studied for the La{sub 0.325}Pr{sub 0.3}Ca{sub 0.375}MnO{sub 3} films with different thicknesses grown on low symmetric (011)-oriented (LaAlO{sub 3}){sub 0.3}(SrAl{sub 0.5}Ta{sub 0.5}O{sub 3}){sub 0.7} substrates. In the magnetic and electronic phase separation region, a colossal anisotropic resistivity (AR) of ?10{sup 5}% and an anomalous large anisotropic magnetoresistance can be observed for 30 nm film. However, for 120 nm film, the maximum AR decreases significantly (?2?×?10{sup 3}%) due to strain relaxation. The colossal AR is strongly associated with the oriented formation of magnetic domains, and the features of the strain effects are believed to be useful for the design of artificial materials and devices.

Jiang, Tao; Yang, Shengwei; Liu, Yukuai; Zhao, Wenbo; Feng, Lei; Li, Xiaoguang, E-mail: lixg@ustc.edu.cn [Hefei National Laboratory for Physical Sciences at Microscale, Department of Physics, University of Science and Technology of China, Hefei 230026 (China); Zhou, Haibiao; Lu, Qingyou [Hefei National Laboratory for Physical Sciences at Microscale, Department of Physics, University of Science and Technology of China, Hefei 230026 (China); High Magnetic Field Laboratory, Chinese Academy of Sciences and University of Science and Technology of China, Hefei 230031 (China); Hou, Yubin [High Magnetic Field Laboratory, Chinese Academy of Sciences and University of Science and Technology of China, Hefei 230031 (China)

2014-05-19T23:59:59.000Z

266

Oxygen Atom Transfer and Oxidative Water Incorporation in Cuboidal Mn3MOn Complexes Based on Synthetic, Isotopic Labeling,  

E-Print Network [OSTI]

is performed by the oxygen-evolving center (OEC) of photo- system II (PSII).2 The OEC consists of a Mn4Ca, United States *S Supporting Information ABSTRACT: The oxygen-evolving complex (OEC) of photo- system IIOxygen Atom Transfer and Oxidative Water Incorporation in Cuboidal Mn3MOn Complexes Based

Goddard III, William A.

267

First-principles study of magnetism in spinel MnO2 Dane Morgan and Billie Wang  

E-Print Network [OSTI]

First-principles study of magnetism in spinel MnO2 Dane Morgan and Billie Wang Department to calculate the ground state, transition tem- perature, and thermodynamic properties of magnetic excitations in spinel MnO2 . The magnetic interactions are mapped onto a Heisenberg model whose exchange interactions

Ceder, Gerbrand

268

Zn Sorption Mechanisms onto Sheathed Leptothrix Discophora and the Impact of the Nanoparticulate Biogenic Mn Oxide Coating  

SciTech Connect (OSTI)

Zinc sorption on sheathed Leptothrix discophora bacterium, the isolated extracellular polymeric substances (EPS) sheath, and Mn oxide-coated bacteria was investigated with macroscopic and spectroscopic techniques. Complexation with L. discophora was dominated by the outer membrane phosphoryl groups of the phospholipid bilayer while sorption to isolated EPS was dominated by carboxyl groups. Precipitation of nanoparticulate Mn oxide coatings on the cell surface increased site capacity by over twenty times with significant increase in metal sorption. XAS analysis of Zn sorption in the coated system showed Mn oxide phase contributions of 18 to 43% through mononuclear inner-sphere complexes. The coordination environments in coprecipitation samples were identical to those of sorption samples, indicating that, even in coprecipitation, Zn is not incorporated into the Mn oxide structure. Rather, through enzymatic oxidation by L. discophora, Mn(II) is oxidized and precipitated onto the biofilm providing a large surface for metal sequestration. The nanoparticulate Mn oxide coating exhibited significant microporosity (75%) suggesting contributions from intraparticle diffusion. Transient studies conducted over 7 months revealed a 170% increase in Zn loading. However, the intraparticle diffusivity of 10{sup -19} cm{sup 2} s{sup -1} is two orders of magnitude smaller than that for abiotic Mn oxide which we attribute to morphological changes such as reduced pore sizes in the nanoparticulate oxide. Our results demonstrate that the cell-bound Mn oxide particles can sorb significant amounts of Zn over long periods of time representing an important surface for sequestration of metal contaminants.

Boonfueng, T.; Axe, L; Yee, N; Hahn, D; Ndiba, P

2009-01-01T23:59:59.000Z

269

MnO spin-wave dispersion curves from neutron powder diffraction  

SciTech Connect (OSTI)

We describe a model-independent approach for the extraction of spin-wave dispersion curves from powder neutron total scattering data. Our approach is based on a statistical analysis of real-space spin configurations to calculate spin-dynamical quantities. The RMCPROFILE implementation of the reverse Monte Carlo refinement process is used to generate a large ensemble of supercell spin configurations from MnO powder diffraction data collected at 100 K. Our analysis of these configurations gives spin-wave dispersion curves for MnO that agree well with those determined independently using neutron triple-axis spectroscopic techniques.

Goodwin, Andrew L.; Dove, Martin T. [Department of Earth Sciences, Cambridge University, Downing Street, Cambridge CB2 3EQ (United Kingdom); Tucker, Matthew G. [ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, Oxfordshire OX11 0QX (United Kingdom); Keen, David A. [ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, Oxfordshire OX11 0QX (United Kingdom); Department of Physics, Oxford University, Clarendon Laboratory, Parks Road, Oxford OX1 3PU (United Kingdom)

2007-02-15T23:59:59.000Z

270

A study of magnetic anisotropy energy in CuMn spin glass  

E-Print Network [OSTI]

A STUDY OF MAGNETIC ANISOTROPY ENERGY IN CuMn SPIN GLASS A Thesis by CHRISTINE ADELE ALLEN Submitted to the Graduate College of Texas ARM University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE August 1986... Major Subject: Physics A STUDY OF MAGNETIC ANISOTROPY ENERGY IN CuMn SPIN GLASS A Thesis by CHRISTINE ADELE ALLEN Approved as to style and content by: Thomas W. Adair, III (Chai man of Committee) Robert A. enefick (Member) Donald L. Parker...

Allen, Christine Adele

1986-01-01T23:59:59.000Z

271

Thickness dependent exchange bias in martensitic epitaxial Ni-Mn-Sn thin films  

SciTech Connect (OSTI)

A thickness dependent exchange bias in the low temperature martensitic state of epitaxial Ni-Mn-Sn thin films is found. The effect can be retained down to very small thicknesses. For a Ni{sub 50}Mn{sub 32}Sn{sub 18} thin film, which does not undergo a martensitic transformation, no exchange bias is observed. Our results suggest that a significant interplay between ferromagnetic and antiferromagnetic regions, which is the origin for exchange bias, is only present in the martensite. The finding is supported by ab initio calculations showing that the antiferromagnetic order is stabilized in the phase.

Behler, Anna [IFW Dresden, Institute for Complex Materials, P.O. Box 27 01 16, 01171 Dresden (Germany) [IFW Dresden, Institute for Complex Materials, P.O. Box 27 01 16, 01171 Dresden (Germany); Department of Physics, Institute for Solid State Physics, Dresden University of Technology, 01062 Dresden (Germany); Teichert, Niclas; Auge, Alexander; Hütten, Andreas [Department of Physics, Thin Films and Physics of Nanostructures, Bielefeld University, 33501 Bielefeld (Germany)] [Department of Physics, Thin Films and Physics of Nanostructures, Bielefeld University, 33501 Bielefeld (Germany); Dutta, Biswanath; Hickel, Tilmann [Max-Planck Institut für Eisenforschung, 40237 Düsseldorf (Germany)] [Max-Planck Institut für Eisenforschung, 40237 Düsseldorf (Germany); Waske, Anja [IFW Dresden, Institute for Complex Materials, P.O. Box 27 01 16, 01171 Dresden (Germany)] [IFW Dresden, Institute for Complex Materials, P.O. Box 27 01 16, 01171 Dresden (Germany); Eckert, Jürgen [IFW Dresden, Institute for Complex Materials, P.O. Box 27 01 16, 01171 Dresden (Germany) [IFW Dresden, Institute for Complex Materials, P.O. Box 27 01 16, 01171 Dresden (Germany); Institute of Materials Science, Dresden University of Technology, 01062 Dresden (Germany)

2013-12-15T23:59:59.000Z

272

Quantum Critical Transition Amplifies Magnetoelastic Coupling in Mn[N(CN)2]2  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

We report the discovery of a magnetic quantum critical transition in Mn[N(CN)2]2 that drives the system from a canted antiferromagnetic state to the fully polarized state with amplified magnetoelastic coupling as an intrinsic part of the process. The local lattice distortions, revealed through systematic phonon frequency shifts, suggest a combined MnN6 octahedra distortion+counterrotation mechanism that reduces antiferromagnetic interactions and acts to accommodate the field-induced state. These findings deepen our understanding of magnetoelastic coupling near a magnetic quantum critical point and away from the static limit.

Brinzari, T. V.; Chen, P.; Sun, Q.-C.; Liu, J.; Tung, L.-C.; Wang, Y.; Schlueter, J. A.; Singleton, J.; Manson, J. L.; Whangbo, M.-H.; Litvinchuk, A. P.; Musfeldt, J. L.

2013-06-01T23:59:59.000Z

273

UW Cosmogenic Isotopes Al-Be 1 EXTRACTION OF Al & Be FROM QUARTZ FOR ISOTOPIC ANALYSIS  

E-Print Network [OSTI]

UW Cosmogenic Isotopes Al-Be 1 EXTRACTION OF Al & Be FROM QUARTZ FOR ISOTOPIC ANALYSIS Summary This method is used to separate Al and Be for AMS analysis from pure quartz samples. After adding Be carrier, quartz is dissolved in HF. The solution is sub-sampled for determination of total Al content, then dried

Stone, John

274

ccsd00001116 Nucleation of Al 3 Zr and Al 3 Sc in aluminum alloys  

E-Print Network [OSTI]

ccsd­00001116 (version 1) : 4 Feb 2004 Nucleation of Al 3 Zr and Al 3 Sc in aluminum alloys: from 4, 2004) Zr and Sc precipitate in aluminum alloys to form the compounds Al3Zr and Al3Sc which

275

Growth of single-crystal {alpha}-MnO{sub 2} nanorods on multi-walled carbon nanotubes  

SciTech Connect (OSTI)

Single-crystal {alpha}-MnO{sub 2} nanorods were grown on multi-walled carbon nanotubes (MWNTs) in H{sub 2}SO{sub 4} aqueous solution. The morphology and microstructure of the composites were examined by transmission electron microscopy, high-resolution transmission electron microscopy (HRTEM), X-ray diffractometry and energy dispersive spectroscopy (EDS). The results show that {alpha}-MnO{sub 2} single-crystal nanorods with a mean diameter of 15 nm were densely grown on the surface of MWNTs. Those MWNTs/MnO{sub 2} composites were used as an electrode material for supercapacitors, and it was found that the supercapacitor performance using MWNTs/MnO{sub 2} composites was improved largely compared to that using pure MWNTs and {alpha}-MnO{sub 2} nanorod mechanically mixed with MWNTs.

Chen Yong [Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016 (China); Key Laboratory of Tropic Biological Resources, MOE, Hainan University, 58 Renmin Road, Haikou 570228 (China); Liu Chenguang; Liu Chang [Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016 (China); Lu Gaoqing [ARC Centre for Functional Nanomaterials, Australian Institute of Bioengineering and Nanotechnology, University of Queensland, QLD 4072 (Australia); Cheng Huiming [Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016 (China)], E-mail: cheng@imr.ac.cn

2007-11-06T23:59:59.000Z

276

Effect of Ti doping on high pressure behavior of BiMn{sub 2}O{sub 5}  

SciTech Connect (OSTI)

Our high pressure x-ray diffraction studies on BiMn{sub 1.5}Ti{sub 0.5}O{sub 5} show iso-structural phase transition above 12 GPa similar to the one observed in undoped BiMn{sub 2}O{sub 5}; however anisotropic compressional behavior is found to be more enhanced in the doped case. Unlike undoped system, an anomalous lattice expansion along c axis has been observed in BiMn{sub 1.5}Ti{sub 0.5}O{sub 5} above 12 GPa; whereas the b lattice parameter has been found to be more compressible as compared to BiMn{sub 2}O{sub 5}. As doping with Ti reduces the magnetic interactions among Mn ions, the observed changes are suggestive of having adverse magnetic implications in the observed iso-structural phase transition.

Pandey, K. K., E-mail: kkpandey@barc.gov.in; Poswal, H. K., E-mail: kkpandey@barc.gov.in; Sharma, Surinder M. [High Pressure and Synchrotron Radiation Physics Division, Bhabha Atomic Research Centre, Trombay, Mumbai 40008 (India); Kumar, Ravi [Centre for Materials Science and Engineering, National Institute of Technology, Hamirpur-177005 (India)

2014-04-24T23:59:59.000Z

277

Redox Exchange Induced MnO2 Nanoparticle Enrichment in Poly(3,4-ethylenedioxythiophene) Nanowires for Electrochemical Energy Storage  

SciTech Connect (OSTI)

MnO{sub 2} nanoparticle enriched poly(3,4-ethylenedioxythiophene) (PEDOT) nanowires are fabricated by simply soaking the PEDOT nanowires in potassium permanganate (KMnO{sub 4}) solution. The structures of these MnO{sub 2} nanoparticle enriched PEDOT nanowires are characterized by SEM and TEM, which show that the MnO{sub 2} nanoparticles have uniform sizes and are finely dispersed in the PEDOT matrix. The chemical constituents and bonding of these composite nanowires are characterized by energy-dispersive X-ray analysis, X-ray photoelectron spectroscopy, and infrared spectroscopy, which indicate that the formation and dispersion of these MnO{sub 2} nanoparticles into the nanoscale pores of the PEDOT nanowires are most likely triggered by the reduction of KMnO{sub 4} via the redox exchange of permanganate ions with the functional group on PEDOT. Varying the concentrations of KMnO{sub 4} and the reaction time controls the loading amount and size of the MnO{sub 2} nanoparticles. Cyclic voltammetry and galvanostatic charge?discharge are used to characterize the electrochemical properties of these MnO{sub 2} nanoparticle loaded PEDOT nanowires. Due to their extremely high exposed surface area with nanosizes, the pristine MnO{sub 2} nanoparticles in these MnO{sub 2} nanoparticle enriched PEDOT nanowires show very high specific capacitance (410 F/g) as the supercapacitor electrode materials as well as high Li+ storage capacity (300 mAh/g) as cathode materials of Li ion battery, which boost the energy storage capacity of PEDOT nanowires to 4 times without causing excessive volume expansion in the polymer. The highly conductive and porous PEDOT matrix facilitates fast charge/discharge of the MnO{sub 2} nanoparticles and prevents them from agglomerating. These synergic properties enable the MnO{sub 2} nanoparticle enriched PEDOT nanowires to be promising electrode materials for supercapacitors and lithium ion batteries.

Liu, R; Duay, Jonathon; Lee, Sang Bok

2010-01-01T23:59:59.000Z

278

Comparative Genomic Discovery of miRNAs Grad et al.  

E-Print Network [OSTI]

Comparative Genomic Discovery of miRNAs Grad et al. Computational and Experimental Identification throughout the adult life cycle (Feinbaum and Ambros, 1999; Lee et al., 1993; Reinhart et al., 2000 al., 1993; Wightman et al., 1993; Reinhart et al., 2000; Slack et al., 2000). Both lin-4 and let-7

Church, George M.

279

Local Agency Project Manager Checklist The steps below follow those outlined in the Mn/DOT Utility Manual. A PDF of the manual  

E-Print Network [OSTI]

Form Contact utility owners Utility Contact List available at http://www.dot.state.mn.us/utility/files/pdf/contacts/contact-utilityLocal Agency Project Manager Checklist The steps below follow those outlined in the Mn/DOT Utility Manual. A PDF of the manual and supporting documents are available at: http://www.dot.state.mn.us/utility

Minnesota, University of

280

Atomic and molecular adsorption on RhMn alloy surface: A first principles study  

E-Print Network [OSTI]

and hydrogen from reforming of natural gas and coal to hydro- carbon Fishcher-Tropsch synthesis and oxygenates- bon and partial oxidation of methane.15 The importance of Rh catalysts on catalytic reactions molecules in terms of the energetics and site preferences on Rh catalysts as well as the effects of Mn added

Li, Weixue

Note: This page contains sample records for the topic "mn al 1970-1974" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Crystallography of Interfaces and Grain Size Distributions in Sr-Doped LaMnO3  

E-Print Network [OSTI]

Crystallography of Interfaces and Grain Size Distributions in Sr-Doped LaMnO3 Qinyuan Liu,§ Sudip systems are similar. I. Introduction HIGH-TEMPERATURE solid oxide fuel cells (SOFCs) offer highly efficient, clean, direct conversion of chemical to electrical energy.1 SOFC performance is dictated

Rohrer, Gregory S.

282

Frustration and multiferroic behavior in Ca3CoMnO6  

SciTech Connect (OSTI)

Lu{sub 2}MnCoO{sub 6} and Ca{sub 3}MnCoO{sub 6} satisfy one of the primary goals of multiferroics research, namely ferromagnetic-like magnetization coupled to ferroelectric-like polarization. Thus the mechanism for magnetoelectric coupling in these materials deserves careful study. New data shows that the physics of these compound may be related to the classic 'ANNNI' model. Frustration between ferromagnetic nearest-neighbor and antiferromagnetic next-nearest-neighbor interactions between Ising spins creates an 'up up down down' magnetic structure in zero magnetic field, along c-axis chains that consist of alternating Co and Mn ions. In applied magnetic fields 'up up down,' 'up up up down' and other metastable variations can evolve, yielding hysteretic ferromagnetic-like magnetization. The key is that the phase slips between regions of 'up' and 'down' carries an electric polarization due to broken spatial inversion symmetry. Thus these phase slips can be manipulated with both electric and magnetic fields. The result is a profusion of magnetic and electric states that are closely-spaced in temperature, electric, and magnetic field. We present experimental studies of the magnetic, electric, and structural properties of these two compounds. We include very new data up to 100 Ton Ca{sub 3}CoMnO{sub 6} that resolves a key controversy of over the magnetic structure and the size of the moments.

Zapf, Vivien [Los Alamos National Laboratory

2012-06-01T23:59:59.000Z

283

Optical properties of metallic (III, Mn)V ferromagnetic semiconductors in the infrared to visible range  

E-Print Network [OSTI]

We report on a study of the ac conductivity and magneto-optical properties of metallic ferromagnetic (III, Mn)V semiconductors in the infrared to visible spectrum at zero temperature. Our analysis is based on the successful kinetic exchange model...

Hankiewicz, EM; Jungwirth, T.; Dietl, T.; Timm, C.; Sinova, Jairo.

2004-01-01T23:59:59.000Z

284

Microscopic mechanism of the noncrystalline anisotropic magnetoresistance in (Ga,Mn)As  

E-Print Network [OSTI]

Starting with a microscopic model based on the Kohn-Luttinger Hamiltonian and kinetic p-d exchange combined with Boltzmann formula for conductivity we identify the scattering from magnetic Mn combined with the strong spin-orbit interaction of the Ga...

Vyborny, Karel; Kucera, Jan; Sinova, Jairo; Rushforth, A. W.; Gallagher, B. L.; Jungwirth, T.

2009-01-01T23:59:59.000Z

285

Synthesis and Characterization of NiMnGa Ferromagnetic Shape Memory Alloy Thin Films  

E-Print Network [OSTI]

, it is very important to understand their behavior and examine their properties. This thesis is an effort to contribute to the literature of Ni-Mn-Ga thin films as ferromagnetic shape memory alloys. The focus of this project is to develop a recipe...

Jetta, Nishitha

2011-10-21T23:59:59.000Z

286

Aliovalent titanium substitution in layered mixed Li Ni-Mn-Co oxides for lithium battery applications  

SciTech Connect (OSTI)

Improved electrochemical characteristics are observed for Li[Ni1/3Co1/3-yMyMn1/3]O2 cathode materials when M=Ti and y<0.07, compared to the baseline material, with up to 15percent increased discharge capacity.

Kam, Kinson; Doeff, Marca M.

2010-12-01T23:59:59.000Z

287

Modified magnetic ground state in NiMn2O4 thin films  

SciTech Connect (OSTI)

We demonstrate the stabilization of a magnetic ground state in epitaxial NiMn2O4 (NMO) thin films not observed in their bulk counterpart. Bulk NMO exhibits a magnetic transition from a paramagnetic phase to a collinear ferrimagnetic moment configuration below 110 K and to a canted moment configuration below 70 K. By contrast, as-grown NMO films exhibit a single magnetic transition at 60 K and annealed films exhibit the magnetic behavior found in bulk. Cation inversion and epitaxial strain are ruled out as possible causes for the new magnetic ground state in the as-grown films. However, a decrease in the octahedral Mn{sup 4+}:Mn{sup 3+} concentration is observed and likely disrupts the double exchange that produces the magnetic state at intermediate temperatures. X-ray magnetic circular dichroism and bulk magnetometry indicate a canted ferrimagnetic state in all samples at low temperature. Together these results suggest that the collinear ferrimagnetic state observed in bulk NMO at intermediate temperatures is suppressed in the as grown NMO thin films due to a decrease in octahedral Mn{sup 4+} while the canted moment ferrimagnetic ordering is preserved below 60 K.

Nelson-Cheeseman, B. B.; Chopdekar, R. V.; Toney, M. F.; Arenholz, E.; Suzuki, Y.; Iwata, J.M.

2010-08-03T23:59:59.000Z

288

Reduced-activation austenitic stainless steels: The Fe--Mn--Cr--C system  

SciTech Connect (OSTI)

Nickel-free manganese-stabilized steels are being developed for fusion-reactor applications. As the first part of this effort, the austenite-stable region in the Fe--Mn--Cr--C system was determined. Results indicated that the Schaeffler diagram developed for Fe--Ni--Cr--C alloys cannot be used to predict the constituents expected for high-manganese steels. This is true because manganese is not as strong an austenite stabilizer relative to delta-ferrite formation as predicted by the diagram, but it is a stronger austenite stabilizer relative to martensite than predicted. Therefore, the austenite-stable region for Ne--Mn--Cr--C alloys occurs at lower chromium and hugher combinations of manganese and carbon than predicted by the Schaeffler diagram. Development of a manganese-stabilized stainless steel should be possible in the composition range of 20 to 25% Mn, 10 to 15% Cr, and 0.01 to 0.25%C. Tensile behavior of an Fe--20%Mn--12%Cr--0.25%C alloy was determined. The strength and ductility of this possible base composition was comparable to type 316 stainless steel in both the solution-annealed and cold-worked condition.

Klueh, R.L.; Maziasz, P.J.

1988-01-01T23:59:59.000Z

289

Electrodeposition of Mn-Co Alloys on Stainless Steels for SOFC Interconnect Application  

SciTech Connect (OSTI)

Chromium-containing ferritic stainless steels are the most popular materials for solid oxide fuel cell (SOFC) interconnect applications because of its oxidation resistance and easy fabrication process. However, excessive scale growth and chromium evaporation will degrade the cell performance. Highly conductive coatings that resist oxide scale growth and chromium evaporation may prevent both of these problems. Mn1.5Co1.5O4 spinel is one of the most promising coatings for interconnect application because of its high conducitivy, good chromium retention capability, as well as good CTE match. Electroplating of alloys or thin film multilayers followed by controlled oxidation to the desired spinel phase offers an additional deposition option. In the present study binary Mn/Co alloys was fabricated by electrodeposition, and polarization curves were used to characterize the cathodic reactions on substrate surface. By controlling the current density precisely, coatings with Mn/Co around 1:1 has been successfully deposited in Mn/Co =10 solutions, SEM and EDX was used to characterize the surface morphology and composition.

Wu, J. (West Virginia University); Jiang, Y. (West Virginia University); Johnson, C.; Gong, M. (West Virginia University); Liu, X. (West Virginia University)

2007-09-01T23:59:59.000Z

290

Electrical gating effects on the magnetic properties of (Ga,Mn)As diluted magnetic semiconductors  

E-Print Network [OSTI]

-effect transistor (FET) based on low-doped Ga0.975Mn0.025As was fabricated. It has an in-built n-GaAs back-gate, which, in addition to being a normal gate, enhances the gating effects, especially in the depletion of the epilayer, by decreasing the effective channel...

Owen, Man Hon Samuel

2010-11-16T23:59:59.000Z

291

A violet emission in ZnS:Mn,Eu: Luminescence and applications for radiation detection  

SciTech Connect (OSTI)

We prepared manganese and europium co-doped zinc sulfide (ZnS:Mn,Eu) phosphors and used them for radiation detection. In addition to the red fluorescence at 583?nm due to the d-d transition of Mn ions, an intense violet emission at 420?nm is newly observed in ZnS:Mn,Eu phosphors. The emission is related to Eu{sup 2+} doping but only appears at certain Eu{sup 2+} concentrations. It is found that the intensity of the 420?nm violet fluorescence is X-ray does-dependent, while the red fluorescence of 583?nm is not. The ratio of fluorescence intensities at 420?nm and 583?nm has been monitored as a function of X-ray doses that exposed upon the ZnS:Mn,Eu phosphors. Empirical formulas are provided to estimate the doses of applied X-ray irradiation. Finally, possible mechanisms of X-ray irradiation induced fluorescence quenching are discussed. The intense 420?nm emission not only provides a violet light for solid state lighting but also offers a very sensitive method for radiation detection.

Ma, Lun; Chen, Wei, E-mail: weichen@uta.edu [Department of Physics and the SAVANT Center, The University of Texas at Arlington, Arlington, Texas 76019-0059 (United States); Jiang, Ke [Center for Biofrontiers Institute, University of Colorado at Colorado Springs, 1420 Austin Bluffs Pkwy., Colorado Springs, Colorado 80918 (United States); Liu, Xiao-tang [Department of Physics and the SAVANT Center, The University of Texas at Arlington, Arlington, Texas 76019-0059 (United States); Department of Applied Chemistry, College of Science, South China Agricultural University, Guangzhou 510642 (China)

2014-03-14T23:59:59.000Z

292

Site preferences of indium impurity atoms in intermetallics having Al3Ti and Al3Zr crystal structures  

E-Print Network [OSTI]

Site preferences of indium impurity atoms in intermetallics having Al3Ti and Al3Zr crystal-04843 (Metals Program) and Praveen Sinha Fund for Physics Research. L12 DO22 DO23 Cu3Au Al3Ti Al3Zr #12;Outline ¡ Indium was doped in samples of Al3V and Al3Ti (Al3Ti structure) and Al3Zr (Al3Zr structure) by arc

Collins, Gary S.

293

ENVIRONMENT AL REVIEW for CATEGORICAL EXCLUSION DETERMINATION  

Broader source: Energy.gov (indexed) [DOE]

ENVIRONMENT AL REVIEW for CATEGORICAL EXCLUSION DETERMINATION Rocky Mountain Region, Western Area Power Administration Upper Molina-Lower Molina 115 kV Road Maintenance and...

294

Märchenfilme im Unterricht Deutsch als Fremdsprache.  

E-Print Network [OSTI]

??Diese Masterarbeit befasst sich mit dem Einsatz von Märchenfilmen im Unterricht Deutsch als Fremdsprache und versucht folgende Fragen zu beantworten: Welches Potential stellen Märchenfilme für… (more)

Serdinsky, Andrea

2014-01-01T23:59:59.000Z

295

High-field electroluminescence in semiconductor tunnel junctions with a Mn-doped GaAs layer  

SciTech Connect (OSTI)

We investigated high-field electroluminescence (EL) in semiconductor tunnel junctions with a Mn-doped GaAs layer (here, referred to as GaAs:Mn). Besides the band-gap emission of GaAs, the EL spectra show visible light emissions with two peaks at 1.94?eV and 2.19?eV, which are caused by d-d transitions of the Mn atoms excited by hot electrons. The threshold voltages for band-gap and visible light EL in the tunnel junctions with a GaAs:Mn electrode are 1.3?V higher than those of GaAs:Mn excited by hot holes in reserve biased p{sup +}-n junctions, which is consistent with the hot carrier transport in the band profiles of these structures. Our EL results at room temperature show that the electron temperature in GaAs:Mn can be as high as ?700?K for a low input electrical power density of 0.4?W/cm{sup 2}, while the lattice temperature of the GaAs:Mn layer can be kept at 340?K.

Hai, Pham Nam [Department of Electrical Engineering and Information Systems, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan); Department of Physical Electronics, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Tokyo 152-0033 (Japan); Yatsui, Takashi; Ohtsu, Motoichi; Tanaka, Masaaki [Department of Electrical Engineering and Information Systems, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan); Nanophotonics Research Center, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)

2014-09-21T23:59:59.000Z

296

A Single Layer of Mn in a GaAs Quantum Well: A Ferromagnet with Quantum Fluctuations  

SciTech Connect (OSTI)

Some of the highest transition temperatures achieved for Mn-doped GaAs have been in &-doped heterostructures with well-separated planes of Mn. But in the absense of magnetic anisotropy, the Mermin-Wagner theorem implies that a single plane of magnetic ions cannot be ferromagnetic. We show that the same mechanism that produces magnetic frustration and suppresses the transition can stabilize ferromagnetic order for a single layer of Mn in a GaAs quantum well. But this comes at the price of quantum fluctuations that suppress the ordered moment from that of a fully saturated ferromagnet.

Melko, Roger G [ORNL; Fishman, Randy Scott [ORNL; Reboredo, Fernando A [ORNL

2007-01-01T23:59:59.000Z

297

Quantitatively Probing the Al Distribution in Zeolites  

SciTech Connect (OSTI)

The degree of substitution of Si4+ by Al3+ in the oxygen-terminated tetrahedra (Al T-sites) of zeolites determines the concentration of ion-exchange and Brřnsted acid sites. As the location of the tetrahedra and the associated subtle variations in bond angles influence the acid strength, quantitative information about Al T-sites in the framework is critical to rationalize catalytic properties and to design new catalysts. A quantitative analysis is reported that uses a combination of extended X-ray absorption fine structure (EXAFS) analysis and 27Al MAS NMR spectroscopy supported by DFT-based molecular dynamics simulations. To discriminate individual Al atoms, sets of ab initio EXAFS spectra for various T-sites are generated from DFT-based molecular dynamics simulations allowing quantitative treatment of the EXAFS single- and multiple-photoelectron scattering processes out to 3-4 atom shells surrounding the Al absorption center. It is observed that identical zeolite types show dramatically different Al-distributions. A preference of Al for T-sites that are part of one or more 4-member rings in the framework over those T-sites that are part of only 5- and 6-member rings in the HBEA150 sample has been determined from a combination of these methods. This work was supported by the U. S. Department of Energy (DOE), Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences.

Vjunov, Aleksei; Fulton, John L.; Huthwelker, Thomas; Pin, Sonia; Mei, Donghai; Schenter, Gregory K.; Govind, Niranjan; Camaioni, Donald M.; Hu, Jian Z.; Lercher, Johannes A.

2014-06-11T23:59:59.000Z

298

A new step size rule in Yan et al.'s self-adaptive projection method  

E-Print Network [OSTI]

Jan 29, 2015 ... Abstract: In this paper, we propose a new step size rule to accelerate Yan et al.'s self-adaptive projection method. Under the new step size ...

Gao Bin

2015-01-29T23:59:59.000Z

299

Soziale Beziehungen und Unterrichtsklima im Deutsch als Fremdsprache–/Deutsch als Zweitsprache–Unterricht.  

E-Print Network [OSTI]

??In der vorliegenden Arbeit wird das Konzept „Klima“ in Bezug auf den Deutsch als Fremdsprache–/Deutsch als Zweitsprache–Unterricht untersucht. Es wird dargestellt, welchen Stellenwert ein positives… (more)

Tischler, Christina

2013-01-01T23:59:59.000Z

300

Penetration depth and absorption mechanisms of spin currents in Ir{sub 20}Mn{sub 80} and Fe{sub 50}Mn{sub 50} polycrystalline films by ferromagnetic resonance and spin pumping  

SciTech Connect (OSTI)

Spintronics relies on the spin dependent transport properties of ferromagnets (Fs). Although antiferromagnets (AFs) are used for their magnetic properties only, some fundamental F-spintronics phenomena like spin transfer torque, domain wall motion, and tunnel anisotropic magnetoresistance also occur with AFs, thus making AF-spintronics attractive. Here, room temperature critical depths and absorption mechanisms of spin currents in Ir{sub 20}Mn{sub 80} and Fe{sub 50}Mn{sub 50} are determined by F-resonance and spin pumping. In particular, we find room temperature critical depths originating from different absorption mechanisms: dephasing for Ir{sub 20}Mn{sub 80} and spin flipping for Fe{sub 50}Mn{sub 50}.

Merodio, P.; Ghosh, A.; Lemonias, C.; Gautier, E.; Ebels, U.; Chshiev, M.; Béa, H., E-mail: vincent.baltz@cea.fr, E-mail: helene.bea@cea.fr; Baltz, V., E-mail: vincent.baltz@cea.fr, E-mail: helene.bea@cea.fr [SPINTEC, UMR 8191 CNRS/INAC-CEA/UJF-Grenoble 1/Grenoble-INP, F-38054 Cedex (France); Bailey, W. E., E-mail: web54@columbia.edu [Mat. Sci. and Engn. Program, Department of Appl. Phys. and Appl. Math., Columbia University, New York, New York 10027 (United States)

2014-01-20T23:59:59.000Z

Note: This page contains sample records for the topic "mn al 1970-1974" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Modeling Precipitation and Sorption of Al, U and Co-contaminants during Titration of Acidic Sediments in Recirculation Flow-Through Experiments  

SciTech Connect (OSTI)

We conducted batch and recirculating column titration tests with contaminated acidic sediments with controlled CO2 in the headspace, and extended the geochemical model by Gu et al. (2003, GCA) to better understand and quantify the reactions governing trace metal fate in the subsurface. The sediment titration curve showed slow pH increase due to strong buffering by Al precipitation and CO2 uptake. Assuming precipitation of basaluminite at low saturation index (SI=-4), and decreasing cation exchange selectivity coefficient (kNa\\Al=0.3), the predictions are close to the observed pH and Al; and the model explains 1) the observed Ca, Mg, and Mn concentration decrease by cation exchange with sorbed Al, and 2) the decrease of U by surface complexation with Fe hydroxides at low pH, and precipitation as liebigite (Ca2UO2(CO3)3:10H2O) at pH>5.5. Without further adjustment geochemical parameters, the model describes reasonably well previous sediment and column titration tests without CO2 in the headspace, as well as the new large column test. The apparent inhibition of U and Ni decrease in the large column can be explained by formation of aqueous carbonate complexes and/or competition with carbonate for surface sites. These results indicated that ignoring labile solid phase Al would underestimate base requirement in titration of acidic aquifers.

Tang, Guoping [ORNL; Luo, Wensui [Institute of Urban Environment, Chinese Academy of Sciences; Brooks, Scott C [ORNL; Watson, David B [ORNL; Gu, Baohua [ORNL

2013-01-01T23:59:59.000Z

302

Boston University AccelerAted MedicAl And dentAl ProgrAMs  

E-Print Network [OSTI]

Boston University AccelerAted MedicAl And dentAl ProgrAMs teAcher evAlUAtion To the applicant: Applicants to any of the College of Arts & Sciences' accelerated medical or dental programs must submit three (last, first, middle initial) Date of birth Accelerated Program of application (please check one

Finzi, Adrien

303

Mn concentration dependent structural and optical properties of a-plane Zn{sub 0.99-x}Mn{sub x}Na{sub 0.01}O  

SciTech Connect (OSTI)

Non-polar a-plane (112{sup Ż}0) Zn{sub 0.99?x}Mn{sub x}Na{sub 0.01}O (x?=?0, 0.02, 0.03, 0.04, and 0.05) thin films have been prepared on r-plane (112{sup Ż}0) sapphire substrates by pulsed laser deposition (PLD). The influences of Mn content on the structural and optical properties of the films have been studied. It is indicated that moderate Mn doping facilitates the non-polar growth of ZnO, and all the doped films are single phase with a hexagonal wurtzite structure. The transmittance spectra suggested that all films are transparent in the visible region exhibiting a transmittance above 80%. Mn{sup 2+} doped Zn{sub 0.99}Na{sub 0.01}O shows an initial decrease of optical band gap (OBG) for small concentration of Mn, followed by a monotonic increase. The anomalous decrease in OBG for low concentrations of Mn is attributed to the strong exchange interaction present between the sp electrons of the host matrix and d electrons of Mn. Emission studies were also performed showing suppressed blue-shifted ultraviolet band and dominant violet-blue bands, which might originate from the zinc vacancy (V{sub Zn}) and zinc interstitial (Zn{sub i}) defects. The intensity of defect-related emission peaks is Mn doping-level-dependent as well and the results coincide well with that from the structural analyses.

Lu, B., E-mail: binlu@zju.edu.cn; Zhou, T. T.; Ma, M. J.; Ye, Y. H.; Ye, Z. Z.; Lu, J. G.; Pan, X. H. [State Key Laboratory of Silicon Materials, Cyrus Tang Center for Sensor Materials and Applications, Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027 (China)

2013-12-14T23:59:59.000Z

304

Reassessment of Al-Ce and Al-Nd Binary Systems Supported by Critical Experiments and First-Principles  

E-Print Network [OSTI]

Reassessment of Al-Ce and Al-Nd Binary Systems Supported by Critical Experiments and First The present study reinvestigates the Al-Ce and Al-Nd phase diagrams and reoptimizes their thermody- namics results and theoretical calculations show that Al2Nd (or Al2Ce) should be treated as a stoichiometric

Widom, Michael

305

Nmr Study of Thiocarbonyl Derivatives of Fe and Mn were made with solutions of the tungsten and molybdenum species  

E-Print Network [OSTI]

Nmr Study of Thiocarbonyl Derivatives of Fe and Mn were made with solutions of the tungsten.g.. the tungsten ion readily oxidizes in aqueous acid [A. Samotus and B. Kosowicz-Czajkowska, Rocz. Chem., 45, 1623

Bodner, George M.

306

Heat capacity of the site-diluted spin dimer system Ba?(Mn1-xVx)?O?  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

Heat-capacity and susceptibility measurements have been performed on the diluted spin dimer compound Ba?(Mn1-xVx)?O?. The parent compound Ba?Mn?O? is a spin dimer system based on pairs of antiferromagnetically coupled S=1, 3d˛ Mn?? ions such that the zero-field ground state is a product of singlets. Substitution of nonmagnetic S=0, 3d? V?? ions leads to an interacting network of unpaired Mn moments, the low-temperature properties of which are explored in the limit of small concentrations 0?x?0.05. The zero-field heat capacity of this diluted system reveals a progressive removal of magnetic entropy over an extended range of temperatures, with no evidence for a phase transition. The concentration dependence does not conform to expectations for a spin-glass state. Rather, the data suggest a low-temperature random singlet phase, reflecting the hierarchy of exchange energies found in this system.

Samulon, E. C.; Shapiro, M. C.; Fisher, I. R.

2011-08-01T23:59:59.000Z

307

Electronic Structure of a Paramagnetic {MNO}[superscript 6] Complex: MnNO 5,5-Tropocoronand  

E-Print Network [OSTI]

Using density functional theory (OLYP/STO-TZP) calculations, we have investigated the electronic structure of [Mn(5,5-tropocoronand)(NO)], a rare paramagnetic {MNO}6 complex. Experimental methods, including magnetic ...

Tangen, Espen

308

A new discontinuously reinforced aluminum MMC: Al+AlB{sub 2} flakes  

SciTech Connect (OSTI)

Development of a novel metal matrix composite based on the Al-B alloy system has been undertaken. Preparation of this discontinuously reinforced material is based on the precipitation of high aspect ratio AlB{sub 2} from an Al-B alloy. This paper describes a number of efforts forced on preparing high volume fractions (> 30 v%) of AlB{sub 2} in aluminum. New insights into the behavior of the Al-B alloys system allowed this effort to be successful.

HALL,AARON C.; ECONOMY,J.

2000-06-08T23:59:59.000Z

309

Prediction of O2 Dissociation Kinetics on LaMnO3-Based Cathode Materials for Solid Oxide Fuel Cells  

SciTech Connect (OSTI)

First-principles and statistical-theory calculations were applied to examine the interactions between oxygen molecules and the (100) surfaces of LaMnO3 and La0.5Sr0.5MnO2.75, one of the most-used cathode materials in solid oxide fuel cells (SOFCs). To predict the rate constants for the interactions between O2 and LaMnO3 or La0.5Sr0.5MnO2.75, potential energy profiles were constructed using the nudged elastic band (NEB) method. Predicted rate constants for the dissociation of adsorbed oxygen species on LaMnO3 (lm) and La0.5Sr0.5MnO2.75 (lsm) can be expressed as kdiss,lm ) 2.35 × 1012 exp(-0.50 eV/RT) s-1 and kdiss,lsm ) 2.15 × 1012 exp(-0.23 eV/RT) s-1, respectively, in the temperature range of 873-1273 K at 1 atm. Because the activation energy for oxygen dissociation on La0.5Sr0.5MnO2.75 (0.23 eV) is much smaller than that on LaMnO3 (0.50 eV), oxygen vacancies greatly enhance O2 dissociation kinetics. The kinetic and mechanistic studies for the interactions at the molecular level are imperative to gaining a fundamental understanding of oxygen reduction kinetics on cathode materials and to providing important insight into the rational design of more catalytically active cathode materials for SOFCs.

Choi, Yongman; Lynch, Matthew E.; Lin, M. C.; Liu, Meilin

2009-04-30T23:59:59.000Z

310

Magnetocaloric and magnetoresistive properties of La0.67Ca0.33-xSrxMnO3  

E-Print Network [OSTI]

Risø-PhD-5 Magnetocaloric and magnetoresistive properties of La0.67Ca0.33-xSrxMnO3 Anders Reves: Magnetocaloric and magnetoresistive properties of La0.67Ca0.33-xSrxMnO3 Department: Materials Research Department of magneto- caloric and magnetoresistive properties of a series of polycrystalline Ca- and Sr- doped

311

Coulomb interaction of acceptors in Cd{sub 1?x}Mn{sub x}Te/CdTe quantum dot  

SciTech Connect (OSTI)

The investigation on the effect of confining potential like isotropic harmonic oscillator type potential on the binding and the Coulomb interaction energy of the double acceptors in the presence of magnetic field in a Cd{sub 1?x}Mn{sub x}Te/CdTe Spherical Quantum Dot has been made for the Mn ion composition x=0.3 and compared with the results obtained from the square well type potential using variational procedure in the effective mass approximation.

Kalpana, P.; Nithiananthi, P., E-mail: kjkumar-gri@rediffmail.com; Jayakumar, K., E-mail: kjkumar-gri@rediffmail.com [Department of Physics, Gandhigram Rural University, Gandhigram-624302, TamilNadu (India); Reuben, A. Merwyn Jasper D. [Department of Physics, School of Engineering, Saveetha University, Thandalam, Chennai- 600104, TamilNadu (India)

2014-04-24T23:59:59.000Z

312

Preparation and Magnetic Properties of MnBi-based Hard/Soft Composite Magnets  

SciTech Connect (OSTI)

Bulk anisotropic composite magnets based on MnBi/Co(Fe) exhibiting the different morphology of the soft magnetic phase were prepared by powder metallurgy processing. First, single-phase MnBi bulk magnets were produced using a maximum energy product [(BH)m] of 6.3 MGOe at room temperature. The nanoscale soft phase with the different morphology was then added to form a composite magnet. It was observed that addition of magnetic soft-phase nanoparticles and nanoflakes causes a dramatic coercivity reduction. However, the addition of soft magnetic phase nanowires enhanced the composite magnetization without sacrificing the coercivity. Nevertheless, a kink was still observed on the demagnetization curves and the coercivity decreased when the soft-phase content was larger than 10 wt. %, which was caused by the agglomeration of the soft phase nanowires that also led to a decreased degree of texture.

Ma, Yilong; Liu, Xubo; Gandha, Kinjal; Vuong, Nguyen V.; Yang, Y. B.; Yang, Jinbo; Poudyal, Narayan; Cui, Jun; Liu, J.Ping

2014-05-07T23:59:59.000Z

313

Low temperature magnetic properties of magnesium substituted YbMnO{sub 3}  

SciTech Connect (OSTI)

Structural and magnetic properties of polycrystalline Yb{sub 1?x}Mg{sub x}MnO{sub 3} (x = 0, 0.05 and 0.10) hexagonal compounds prepared by solid state method, have been studied. The structural analyses of the samples were carried out by Rietveld analysis of neutron diffraction data. With increasing Mg content, we find that the lattice parameter a decreases and c increases whereas the overall Mn-O bond length decreases. Magnetization measured as a function of magnetic field at 2.5 K exhibits hysteresis, which is attributed to ferromagnetic like ordering of Yb{sup 3+} sublattice. Temperature dependence of ac magnetic susceptibility, ?{sub ac}(T), shows no signature of spin-glass behavior. ?”(T) exhibits a sudden increase at low temperatures which is due to ordering of Yb{sup 3+} sublattice.

Sattibabu, Bhumireddi, E-mail: bsb.satti@gmail.com; Bhatnagar, Anil K., E-mail: bsb.satti@gmail.com; Mohan, Dasari, E-mail: bsb.satti@gmail.com; Das, Dibakar, E-mail: bsb.satti@gmail.com; Sundararaman, Mahadevan, E-mail: bsb.satti@gmail.com [School of Engineering Sciences and Technology, University of Hyderabad, Hyderabad-500046 (India); Siruguri, Vasudeva; Rayaprol, Sudhindra [UGC-DAE Consortium for Scientific Research, Mumbai Centre, R-5 Shed, Bhabha Atomic Research Centre, Mumbai-400085 (India)

2014-04-24T23:59:59.000Z

314

Abundance analysis of SB2 binary stars with HgMn primaries  

E-Print Network [OSTI]

We present a short review of the abundances in the atmospheres of SB2 systems with Mercury-Manganese (HgMn) primaries. Up to now a careful study has been made for both components of 8 out of 17 known SB2 binaries with orbital periods shorter than 100 days and mass ratio ranging from 1.08 to 2.2. For all eight systems we observe a lower Mn abundance in the secondary's atmospheres than in the primary's. Significant difference in the abundances is also found for some peculiar elements such as Ga, Xe, Pt. All secondary stars with effective temperatures less than 10000 K show abundance characteristics typical of the metallic-line stars.

T. Ryabchikova

1998-05-06T23:59:59.000Z

315

Magneto-optical spectroscopy of ferromagnetic shape-memory Ni-Mn-Ga alloy  

SciTech Connect (OSTI)

Magneto-optical properties of single crystal of Ni{sub 50.1}Mn{sub 28.4}Ga{sub 21.5} magnetic shape memory alloy in martensite and austenite phase were systematically studied. Crystal orientation was approximately along (100) planes of parent cubic austenite. At room temperature, the sample was in modulated 10M martensite phase and transformed to cubic austenite at 323?K. Spectral dependence of polar magneto-optical Kerr effect was obtained by generalized magneto-optical ellipsometry with rotating analyzer in the photon energy range from 1.2 to 4?eV, and from room temperature to temperature above the Curie point. The Kerr rotation spectra exhibit prominent features typical for complexes containing Mn atoms. Significant spectral changes during transformation to austenite can be explained by different optical properties caused by changes in density of states near the Fermi energy.

Veis, M., E-mail: veis@karlov.mff.cuni.cz; Beran, L.; Zahradnik, M.; Antos, R. [Faculty of Mathematics and Physics, Charles University in Prague, Ke Karlovu 5, 12116 Prague (Czech Republic); Straka, L. [Aalto University School of Engineering, PL14200, FIN-00076 Aalto (Finland); Kopecek, J.; Fekete, L.; Heczko, O. [Institute of Physics, ASCR, Na Slovance 2, 182 21 Prague (Czech Republic)

2014-05-07T23:59:59.000Z

316

High capacitive performance of nanostructured Mn-Ni-Co oxide composites for supercapacitor  

SciTech Connect (OSTI)

Nanostructured Mn-Ni-Co oxide composites (MNCO) were prepared by thermal decomposition of the precursor obtained by chemical co-precipitation of Mn, Ni and Co salts. The chemical composition and morphology were characterized by X-ray diffraction (XRD), energy dispersive spectroscopy (EDS) and scanning electron microscopy (SEM). The electrochemical capacitance of MNCO electrode was examined by cyclic voltammetry, impedance and galvanostatic charge-discharge measurements. The results showed that MNCO electrode exhibited the good electrochemical characteristics. A maximum capacitance value of 1260 F g{sup -1} could be obtained within the potential range of -0.1 to 0.4 V versus saturated calomel electrode (SCE) in 6 mol L{sup -1} KOH electrolyte.

Luo Jianmin [Institute of Applied Chemistry, Xinjiang University, Urumqi 830046 (China); Gao Bo [College of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016 (China); Zhang Xiaogang [College of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016 (China)], E-mail: azhangxg@163.com

2008-05-06T23:59:59.000Z

317

Optical transitions in MnGa{sub 2}Se{sub 4}  

SciTech Connect (OSTI)

The dependence of the absorption coefficient on incident photon energy in a MnGa{sub 2}Se{sub 4} single crystal has been investigated in the temperature range 110-295 K. Using group-theory analysis of the electron state symmetry and comparison of the symmetry of the energy spectrum of MnGa{sub 2}Se{sub 4} and its isoelectronic analogs, a conclusion about the character of optical transitions has been drawn. It is shown that the features observed at 2.31 and 2.45 eV are related to the intracenter transitions {sup 6}A{sub 1}{sup 1} {yields} {sup 4}T{sub 2}({sup 4}G) and {sup 6}A{sub 1}{sup 2} {yields} {sup 4}T{sub 2}({sup 4}G). The {sup 6}A{sub 1} state is split by the crystal field.

Tagiev, B. G.; Kerimova, T. G., E-mail: ktaira@physics.ab.az; Tagiev, O. B.; Asadullayeva, S. G.; Mamedova, I. A. [National Academy of Sciences of Azerbaijan, Institute of Physics (Azerbaijan)

2012-06-15T23:59:59.000Z

318

Effect of heat treatment on microstructure and interface of SiC particle reinforced 2124 Al matrix composite  

SciTech Connect (OSTI)

The microstructure and interface between metal matrix and ceramic reinforcement of a composite play an important role in improving its properties. In the present investigation, the interface and intermetallic compound present in the samples were characterized to understand structural stability at an elevated temperature. Aluminum based 2124 alloy with 10 wt.% silicon carbide (SiC) particle reinforced composite was prepared through vortex method and the solid ingot was deformed by hot rolling for better particle distribution. Heat treatment of the composite was carried out at 575 °C with varying holding time from 1 to 48 h followed by water quenching. In this study, the microstructure and interface of the SiC particle reinforced Al based composites have been studied using optical microscopy, scanning electron microscopy (SEM) coupled with energy dispersive X-ray spectroscopy (EDS), electron probe micro-analyzer (EPMA) associated with wavelength dispersive spectroscopy (WDS) and transmission electron microscopy (TEM) to identify the precipitate and intermetallic phases that are formed during heat treatment. The SiC particles are uniformly distributed in the aluminum matrix. The microstructure analyses of Al–SiC composite after heat treatment reveal that a wide range of dispersed phases are formed at grain boundary and surrounding the SiC particles. The energy dispersive X-ray spectroscopy and wavelength dispersive spectroscopy analyses confirm that finely dispersed phases are CuAl{sub 2} and CuMgAl{sub 2} intermetallic and large spherical phases are Fe{sub 2}SiAl{sub 8} or Al{sub 15}(Fe,Mn){sub 3}Si. It is also observed that a continuous layer enriched with Cu and Mg of thickness 50–80 nm is formed at the interface in between Al and SiC particles. EDS analysis also confirms that Cu and Mg are segregated at the interface of the composite while no carbide is identified at the interface. - Highlights: • The composite was successfully heat treated at 575°C for 1-48 hrs. • A layer of 50-75 nm is formed at interface after heat treatment. • No Carbide formation and SiC dissolution is observed at this temperature. • MgAl{sub 2}O{sub 4}, CuMgAl{sub 2} phases are segregated at interface of Al-SiC composite. • Mg and Cu are also segregated at near to the grain boundary.

Mandal, Durbadal, E-mail: durbadal73@yahoo.co.in [MEF Division, CSIR-National Metallurgical Laboratory, Jamshedpur 831007 (India); Viswanathan, Srinath [Dept of Metallurgical and Materials Engineering, University of Alabama, Tuscaloosa, AL (United States)

2013-11-15T23:59:59.000Z

319

Ni{sub 3}Al aluminide alloys  

SciTech Connect (OSTI)

This paper provides a brief review of the recent progress in research and development of Ni{sub 3}Al and its alloys. Emphasis has been placed on understanding low ductility and brittle fracture of Ni{sub 3}Al alloys at ambient and elevated temperatures. Recent studies have resulted in identifying both intrinsic and extrinsic factors governing the fracture behavior of Ni{sub 3}Al alloys. Parallel efforts on alloy design using physical metallurgy principles have led to properties for structural use. Industrial interest in these alloys is high, and examples of industrial involvement in processing and utilization of these alloys are briefly mentioned.

Liu, C.T.

1993-10-01T23:59:59.000Z

320

Thermal diffusion in Ni/Al multilayer  

SciTech Connect (OSTI)

Two Ni/Al multilayers deposited by ion beam sputtering of nominal design [Ni(200A)/Al(100A)] Multiplication-Sign 5 and [Ni(50A)/Al(227A)] Multiplication-Sign 5 on Si substrates were annealed at 200 Degree-Sign C. As-deposited and annealed samples were characterized by x-ray diffraction (XRD) and x-ray reflectometry (XRR). The effort was to study the path of alloying in the above two multilayers of same elements but of opposite stoichiometric ratio. We find distinct differences in alloying of these samples.

Swain, M.; Bhattacharya, D.; Singh, S.; Basu, S. [Solid State Physics Division, Bhabha Atomic Research Center, Mumbai 400085 (India); Gupta, M. [UGC-DAE-Consortium for Scientific Research, University Campus, Khandwa Road, Indore 452017 (India)

2013-02-05T23:59:59.000Z

Note: This page contains sample records for the topic "mn al 1970-1974" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

ALS Reveals New State of Matter  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07)Operations DuringALS DoctoralALS Reveals NewALS

322

Thermoelectric study of crossroads material MnTe via sulfur doping  

SciTech Connect (OSTI)

Here, we report thermoelectric study of crossroads material MnTe via iso-electronic doping S on the Te-site. MnTe{sub 1-x}S{sub x} samples with nominal S content of x?=?0.00, 0.05, and 0.10 were prepared using a melt-quench method followed by pulverization and spark plasma sintering. The X-ray powder diffraction, scanning electron microscopy, and ZAF-corrected compositional analysis confirmed that S uniformly substitutes Te up to slightly over 2%. A higher content of S in the starting materials led to the formation of secondary phases. The thermoelectric properties of MnTe{sub 1-x}S{sub x} samples were characterized by means of Seebeck coefficient, electrical conductivity, and thermal conductivity measurements from 300?K to 773?K. Furthermore, Hall coefficient measurements and a single parabolic band model were used to help gain insights on the effects of S-doping on the scattering mechanism and the carrier effective mass. As expected, S doping not only introduced hole charge carriers but also created short-range defects that effectively scatter heat-carrying phonons at elevated temperatures. On the other hand, we found that S doping degraded the effective mass. As a result, the ZT of MnTe{sub 0.9}S{sub 0.1} was substantially enhanced over the pristine sample near 400?K, while the improvement of ZT became marginal at elevated temperatures. A ZT???0.65 at 773?K was obtained in all three samples.

Xie, Wenjie, E-mail: xie@imw.uni-stuttgart.de; Populoh, Sascha; Sagarna, Leyre; Trottmann, Matthias [Empa–Swiss Federal Laboratories for Materials Science and Technology, Solid State Chemistry and Catalysis, Uberlandstrasse 129, CH-8600 Dübendorf (Switzerland); Ga??zka, Krzysztof [Empa–Swiss Federal Laboratories for Materials Science and Technology, Solid State Chemistry and Catalysis, Uberlandstrasse 129, CH-8600 Dübendorf (Switzerland); Department of Chemistry and Biochemistry, University of Bern, Freiestrasse 3, CH-3012 Bern (Switzerland); Xiao, Xingxing [Institute for Materials Science, University of Stuttgart, DE-70569 Stuttgart (Germany); Liu, Yufei; He, Jian [Department of Physics and Astronomy, Clemson University, Clemson, South Carolina 29634-0978 (United States); Weidenkaff, Anke [Empa–Swiss Federal Laboratories for Materials Science and Technology, Solid State Chemistry and Catalysis, Uberlandstrasse 129, CH-8600 Dübendorf (Switzerland); Institute for Materials Science, University of Stuttgart, DE-70569 Stuttgart (Germany)

2014-03-14T23:59:59.000Z

323

Preparation and characterization of nanostructured NiO/MnO{sub 2} composite electrode for electrochemical supercapacitors  

SciTech Connect (OSTI)

Nanostructured nickel-manganese oxides composite was prepared by the sol-gel and the chemistry deposition combination new route. The surface morphology and structure of the composite were characterized by scanning electron microscope and X-ray diffraction. The as-synthesized NiO/MnO{sub 2} samples exhibit higher surface area of 130-190 m{sup 2} g{sup -1}. Cyclic voltammetry and galvanostatic charge/discharge measurements were applied to investigate the electrochemical performance of the composite electrodes with different ratios of NiO/MnO{sub 2}. When the mass ratio of MnO{sub 2} and NiO in composite material is 80:20, the specific capacitance value of NiO/MnO{sub 2} calculated from the cyclic voltammetry curves is 453 F g{sup -1}, for pure NiO and MnO{sub 2} are 209, 330 F g{sup -1} in 6 mol L{sup -1} KOH electrolyte and at scan rate of 10 mV s{sup -1}, respectively. The specific capacitance of NiO/MnO{sub 2} electrode is much larger than that of each pristine component. Moreover, the composite electrodes showed high power density and stable electrochemical properties.

Liu Enhui [College of Chemistry, Xiangtan University, Hunan 411105 (China)], E-mail: liuenhui99@sina.com.cn; Li Wen; Li Jian; Meng Xiangyun; Ding Rui; Tan Songting [College of Chemistry, Xiangtan University, Hunan 411105 (China)

2009-05-06T23:59:59.000Z

324

Construction of the Magnetic Phase Diagram of FeMn/Ni/Cu(001) Using Photoemission Electron Microscopy  

SciTech Connect (OSTI)

Single crystalline FeMn/Ni bilayer was epitaxially grown on Cu(001) substrate and investigated by photoemission electron microscopy (PEEM). The FeMn and Ni films were grown into two cross wedges to facilitate an independent control of the FeMn (0-20 ML) and Ni (0-20 ML) film thicknesses. The Ni magnetic phases were determined by Ni domain images as a function of the Ni thickness (d{sub Ni}) and the FeMn thickness (d{sub FeMn}). The result shows that as the Ni thickness increases, the Ni film undergoes a paramagnetic-to-ferromagnetic state transition at a critical thickness of d{sub FM} and an in-plane to out-of-plane spin reorientation transition at a thicker thickness d{sub SRT}. The phase diagram shows that both d{sub FM} and d{sub SRT} increase as the FeMn film establishes its antiferromagnetic order.

Wu, J.; Scholl, A.; Arenholz, E.; Hwang, C.; Qiu, Z. Q.

2011-01-04T23:59:59.000Z

325

Structural and Magnetic Properties of MCl2 (M = Fe, Mn, Co): Acetonitrile Solvates  

SciTech Connect (OSTI)

M{sup II}Cl{sub 2} (M = Mn, Fe, Co) as their acetonitrile solvates were isolated, and their structural, spectroscopic, and magnetic properties were studied. MCl{sub 2}(NCMe){sub 2} (M = Fe, Mn) form 1-D chains of octahedral M{sup II} ions with four bridging chlorides and two axial MeCN's. The presence of an axial distortion for MFe causes a significant magnetic anisotropy that increases significantly below 150 K; however, {chi}{sub av} [=({chi}{sub {parallel}} + 2{chi}{sub {perpendicular}})/3] almost coincides with the value obtained on a polycrystalline sample. MnCl{sub 2}(NCMe){sub 2} is a paramagnet with a weak antiferromagnetic coupling. Annealing FeCl{sub 2}(NCMe){sub 2} at 55 {sup o}C forms the monosolvate of FeCl{sub 2}(NCMe) composition in which two chains collapse into a double chain with formation of Fe-Cl bonding such that half of the {mu}-Cl's becomes {mu}{sub 3}-Cl's. This material orders magnetically below {Tc} = 4.3 K. For M = Co, paramagnetic tetrahedral [CoCl{sub 3}(NCMe)]{sup -} anions are isolated.

Pokhodnya,K.; Bonner, M.; DiPasquale, A.; Rheingold, A.; Her, J.; Stephens, P.; Park, J.; Kennon, B.; Arif, A.; Miller, J.

2007-01-01T23:59:59.000Z

326

Why MnIn{sub 2}O{sub 4} spinel is not a transparent conducting oxide?  

SciTech Connect (OSTI)

The title compound has been synthesized by a citrate technique. The crystal structure has been investigated at room temperature from high-resolution neutron powder diffraction (NPD) data. It crystallizes in a cubic spinel structure, space group Fd3-bar m, Z=8, with a=9.0008(1) A at 295 K. It exhibits a crystallographic formula (Mn{sub 0.924(2)}In{sub 0.076(2)}){sub 8a}(In{sub 1.804(2)}Mn{sub 0.196(2)}){sub 16d}O{sub 4}, where 8a and 16d stand for the tetrahedral and octahedral sites of the spinel structure, respectively, with a slight degree of inversion, {lambda}=0.08. MnIn{sub 2}O{sub 4} shows antiferromagnetic interactions below T{sub N} Almost-Equal-To 40 K, due to the statistical distribution of Mn ions over the two available sites. Unlike the related MgIn{sub 2}O{sub 4} and CdIn{sub 2}O{sub 4} spinels, well known as transparent conducting oxides, MnIn{sub 2}O{sub 4} is not transparent and shows a poor conductivity ({sigma}=0.38 S cm{sup -1} at 1123 K): the presence of Mn ions, able to adopt mixed valence states, localizes the charges that, otherwise, would be delocalized in the spinel conduction band. - Graphical Abstract: From NPD data the crystallographic formula (Mn{sub 0.924(2)}In{sub 0.076(2)}){sub 8a}(In{sub 1.804(2)}Mn{sub 0.196(2)}){sub 16d}O{sub 4}, shows a slight degree of inversion, {lambda}=0.08 and a certain In deficiency. The presence of Mn ions, able to adopt mixed oxidation states, localize the charges that, otherwise, would be delocalized in the spinel conduction band; the presence of localized Mn{sup 2+} and Mn{sup 3+} ions provides the characteristic brown color. Highlights: Black-Right-Pointing-Pointer Accurate structural determination from NPD data: inversion degree (8%), and In deficiency. Black-Right-Pointing-Pointer Bond-valence indicates Mn{sup 2+}-Mn{sup 3+} ions; edge-sharing octahedra contain 90% In{sup 3+}+10% Mn{sup 3+} cations. Black-Right-Pointing-Pointer Conductivity several orders of magnitude lower than those of MgIn{sub 2}O{sub 4} or CdIn{sub 2}O{sub 4}. Black-Right-Pointing-Pointer Variability of Mn oxidation states cancels any electron-doping effect, emptying conduction band of mobile charge carriers. Black-Right-Pointing-Pointer Curie-Weiss behavior confirming the determined charge distribution.

Martinez-Lope, M.J. [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco E-28049 Madrid (Spain); Retuerto, M. [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco E-28049 Madrid (Spain); Department of Chemistry, Rutgers State University of New Jersey, Piscataway, NJ 08854-8087 (United States); Calle, C. de la [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco E-28049 Madrid (Spain); Porcher, Florence [Laboratoire Leon Brillouin, CEA/Saclay, 91191 Gif Sur Ivette Cedex, France. (France); Alonso, J.A., E-mail: ja.alonso@icmm.csic.es [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco E-28049 Madrid (Spain)

2012-03-15T23:59:59.000Z

327

Summary Slides of ALS Industry Highlights  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Highlight ALSNews Volume 15 Caribou Biosciences Has Roots at ALS - 09.24.2014 Vol. 357 13 Lithium-Battery Dendrite Growth: A New View 8.3.2 04.30.2014 Vol. 352 12 IBM Probes...

328

Promising Magnesium Battery Research at ALS  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to the ALS. Beamline 6.3.1 scientists are studying magnesium battery performance and degradation with a unique new endstation that offers in situ electrochemical soft x-ray...

329

Western Baldwin County, AL Grid Interconnection Project  

SciTech Connect (OSTI)

The Objective of this Project was to provide an additional supply of electricity to the affected portions of Baldwin County, AL through the purchase, installation, and operation of certain substation equipment.

Thomas DeBell

2011-09-30T23:59:59.000Z

330

The Impact of Aluminum and Iron Substitution on the Structure and Electrochemistry of Li[Ni0.4Co0.2-yMyMn0.4]O2 Materials  

SciTech Connect (OSTI)

Li[Ni0.4Co0.2-yMyMn0.4]O2 (0<_y<_0.2) (M=Al) and Li[Ni0.4Co0.15Fe0.05Mn0.4]O2 compounds were prepared in order to investigate the effect of replacement of all or part of the cobalt on the structural and electrochemical properties. The impact of substitution on the structure has been examined by both x-ray and neutron diffraction experiments. The incorporation of aluminum has minimal effect on the anti-site defect concentration, but leads to structural changes that affect electrochemical performance. The most important effect is an opening of the lithium slab dimension upon substitution, which results in improved rate performance compared to the parent compound. In contrast, the lithium slab dimension is not affected by iron substitution and no rate enhancement effect is observed. The cycling stability of aluminum containing materials is superior to both the parent material and iron-substituted materials.

WIlcox, James D.; Rodriguez, Efrain E.; Doeff, Marca M.

2009-07-23T23:59:59.000Z

331

Adhesion, Atomic Structure, and Bonding at theAdhesion, Atomic Structure, and Bonding at the ----AlAl22OO33(0001)/Al(111) Interface:(0001)/Al(111) Interface  

E-Print Network [OSTI]

Adhesion, Atomic Structure, and Bonding at theAdhesion, Atomic Structure, and Bonding at the ----AlAl22OO33(0001)/Al(111) Interface:(0001)/Al(111) Interface: A First Principles StudyA First Principles--ceramic interfaces are ubiquitous in many industrial applications: ­ Microelectronics ­ Al and other metals

Adams, James B

332

Zn13(CrxAl1-x)27 (x = 0.34-0.37): a new intermetallic phase containing icosahedra as building units  

SciTech Connect (OSTI)

The title compounds Zn{sub 13}(Cr{sub x}Al{sub 1-x}){sub 27} (x = 0.34-0.37) were obtained by melting the pure elements at 923 K, and followed by a heat treatment at 723 K in a tantalum container. According to single crystal structural analysis, the title compounds crystallize in the rhombohedral system, adopting a new structure type (R-3m, a = 7.5971(8), c = 36.816(6), for crystal I). Single crystal X-ray structural analysis reveals a statistical mixing of Cr/Al in their crystallographic positions. Single crystal and powder X-ray diffraction as well as energy dispersive X-ray analyses suggested the title phase to have a narrow homogeneity range. The substructure of Zn{sub 13}(Cr{sub x}Al{sub 1-x}){sub 27} shows close resemblance with the Mn{sub 3}Al{sub 10} structure type. A bonding analysis, through crystal orbital Hamiltonian populations (COHPs), of 'Cr{sub 9}Al{sub 18}Zn{sub 13}' as a representative composition indicated that both homo- and heteronuclear interactions are important for the stability of this new phase.

Thimmaiah, Srinivasa; Han, Mi-Kyung; Miller, Gordon J.

2011-03-13T23:59:59.000Z

333

Magnetic ordering in the spinel compound LiMn2-xLixO4,,x=0,0.04... John Gaddy,1  

E-Print Network [OSTI]

.1063/1.3073660 The ground state properties of the known lithium-based cubic spinel compounds LiT2O4 range from BCS-range antiferromagnetic order. In contrast, whereas lithium-substituted Li Mn2-xLix O4 also undergoes a charge eightfold rings.6 The Mn4+ rings only interact with other rings via the intervening Mn3+ ions. When cooled

Montfrooij, Wouter

334

The effect of interface oxygen content on magnetoelectric effect of epitaxial La{sub 0.7}Sr{sub 0.3}MnO{sub 3}/BaTiO{sub 3} bilayer  

SciTech Connect (OSTI)

The epitaxial La{sub 0.7}Sr{sub 0.3}MnO{sub 3}/BaTiO{sub 3} (LSMO/BTO) bilayer films are grown on (001) oriented LaAlO{sub 3} substrate by pulsed laser deposition technique. The oxygen-rich interface is obtained through in-situ annealing process in oxygen, and the oxygen-deficient interface is obtained without the annealing process. The results show that the ferromagnetic properties of the LSMO film and the magnetoelectric effect (ME) of the bilayer films strongly correlate to the oxygen content at the interface of LSMO/BTO. The saturated magnetization and the ME voltage coefficient of the oxygen-rich bilayer film are higher than that of oxygen-deficient one. It suggests a more effective ME coupling at the LSMO/BTO interface, which are generated through not only the interface strain but also the spin polarized carriers.

Tingxian, Li, E-mail: wxlltx@126.com [College of Physics and Electrical Engineering, Anyang Normal University, Anyang 455002 (China); Kuoshe, Li [National Engineering Research Central for Rare Earth Materials, General Research Institute for Nonferrous Metals, The Grirem Advanced materials Co. Ltd., Beijing 100088 (China)

2014-01-28T23:59:59.000Z

335

Recovery of oscillatory magneto-resistance in phase separated La{sub 0.3}Pr{sub 0.4}Ca{sub 0.3}MnO{sub 3} epitaxial thin films  

SciTech Connect (OSTI)

In-plane angular dependent magneto-resistance has been studied in La{sub 0.3}Pr{sub 0.4}Ca{sub 0.3}MnO{sub 3} (LPCMO) manganite thin films deposited on the (100) oriented NdGaO{sub 3}, and (001) oriented SrTiO{sub 3} and LaAlO{sub 3} substrates. At temperatures where the electronic phase separation is the strongest, a metastable irreversible state exists in the films whose resistivity ? attains a large time dependent value. The ? decreases sharply with an increasing angle ? between the magnetic field and the current, and does not display an expected oscillatory cos{sup 2}?/sin{sup 2}? dependence for all films. The regular oscillations are recovered during repetitive sweeping of ? between 0° and 180°. We discuss possible factors that could produce these unusual changes in the resistivity.

Alagoz, H. S., E-mail: alagoz@ualberta.ca; Jeon, J.; Mahmud, S. T.; Saber, M. M.; Chow, K. H., E-mail: khchow@ualberta.ca; Jung, J., E-mail: jjung@ualberta.ca [Department of Physics, University of Alberta, Edmonton, Alberta T6G 2E1 (Canada); Prasad, B. [Department of Materials Science and Metallurgy, University of Cambridge, Cambridge CB2 3QZ (United Kingdom)] [Department of Materials Science and Metallurgy, University of Cambridge, Cambridge CB2 3QZ (United Kingdom); Egilmez, M. [Department of Physics, American University of Sharjah, Sharjah (United Arab Emirates)] [Department of Physics, American University of Sharjah, Sharjah (United Arab Emirates)

2013-12-02T23:59:59.000Z

336

6. M. Jeltsch et al., Science 276, 1423 (1997); S. J. Oh et al., Dev. Biol. 188, 96 (1997).  

E-Print Network [OSTI]

6. M. Jeltsch et al., Science 276, 1423 (1997); S. J. Oh et al., Dev. Biol. 188, 96 (1997). 7. V, 671 (1997). 16. A. Vecchi et al., Eur. J. Cell Biol. 63, 247 (1994). 17. The presence of VEGFR-3 m. 12, 473 (1998). 21. L. C. Wang et al., EMBO J. 16, 4374 (1997). 22. P. Carmeliet et al., Nature 383

Suarez, Andrew V.

337

A new step size rule in Yan et al.'s self-adaptive projection method  

E-Print Network [OSTI]

Jan 29, 2015 ... ... which can be viewed as a combination of Li and Yuan's manipulation idea of step size and descending direction presented by Yan et al. [14].

2015-01-29T23:59:59.000Z

338

THE THERMAL EXPANSION OF THE DIRECTIONALLY SOLIDIFIED Al-CuAl2 EUTECTIC  

E-Print Network [OSTI]

standard linear solid model, which works well for the Al-the aluminum solid solution is known to work hard- en as it

Baker, Dennis Frank

2011-01-01T23:59:59.000Z

339

Combustion Synthesis of Nanoparticulate LiMgxMn1-xPO4 (x=0, 0.1, 0.2) Carbon Composites  

E-Print Network [OSTI]

for Rechargeable Lithium Batteries. J. Electrochem. Soc.Materials for Lithium Batteries. J. Electrochem. Soc. 148,LiMnPO 4 for Lithium Ion Batteries. Electrochem. and Solid

Doeff, Marca M

2010-01-01T23:59:59.000Z

340

Combustion Synthesis of Nanoparticulate LiMgxMn1-xPO4 (x=0, 0.1, 0.2) Carbon Composites  

E-Print Network [OSTI]

for Rechargeable Lithium Batteries. J. Electrochem. Soc.4 V Cathode Materials for Lithium Batteries. J. Electrochem.LiMnPO 4 for Lithium Ion Batteries. Electrochem. and Solid

Doeff, Marca M

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mn al 1970-1974" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Transmission electron microscopy of RSP Fe/Cr/Mn/Mo/C alloy. [Fe-3 wt % Cr-2 wt % Mn-0. 5 wt % Mo, -0. 3 wt % C  

SciTech Connect (OSTI)

Rapid solidification processing (RSP) has been carried out on an Fe/Cr/Mn/Mo/C alloy using both electron-beam melting and piston-and-anvil techniques. Preliminary TEM results show RSP produces a refined duplex microstructure of ferrite and martensite, with a typical ferrite grain size of 0.50 - 3.0 microns. This RSP microstructure is significantly different from that observed in the conventionally austenitized and quenched alloys - a lath martensitic microstructure with thin films of retained interlath austenite. The morphological change produced by RSP is accompanied by an increase in hardness from 48R/sub c/ to 61R/sub c/ (approx. 480 to 720 VHN). It is intended to use electron-beam specimens to examine the potential beneficial effect of RSP upon sliding wear resistance and, by careful TEM studies, it will be possible to characterize the microstructure and its role in the hardness and wear behavior of the RSP alloy.

Rayment, J.J.; Thomas, G.

1982-03-01T23:59:59.000Z

342

al embarazo reporte: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of superelastic CuAlNi single crystal shape memory alloy during stress Sun, Qing-Ping 133 Josephson effect and tunneling spectroscopy in NbAl2O3AlMgB2 thin films junctions...

343

ALS Gives Chevron Scientists New Insights into Corrosion Resistance  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ALS Gives Chevron Scientists New Insights into Corrosion Resistance ALS Gives Chevron Scientists New Insights into Corrosion Resistance Print Thursday, 25 July 2013 13:44 In the...

344

New ALS Technique Guides IBM in Next-Generation Semiconductor...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

New ALS Technique Guides IBM in Next-Generation Semiconductor Development New ALS Technique Guides IBM in Next-Generation Semiconductor Development Print Wednesday, 21 January 2015...

345

modelado en geofisica aplicado al transporte de nitrato en aguas ...  

E-Print Network [OSTI]

En los últimos ańos, diversas investigaciones han conducido al estudio del comportamiento del nitrato y su potencial impacto ambiental (Mehran et al., 1984

346

al ni shape: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

NiAl NANOLAMINATES . Open Access Theses and Dissertations Summary: ??To characterize the self-propagating, high-temperature exothermic alloying reactions of NiAl nanoscaled...

347

al censo nacional: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

DOCUMENTS 4,450,407 51984 Kwon et al. ... 324304 4 Romalis, Mike 229 (12) United States Patent Bezos et al. Computer Technologies and Information...

348

al alloy matrix: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

dislocation structure of both Al matrix and precipitates Gubicza, Jen 3 Elevated temperature wear of an aluminum matrix composite Al6061-20 percent aluminum(2) oxygen(3)...

349

ALS Scientists Patent Technique To Dramatically Advance Grating...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ALS Scientists Patent Technique To Dramatically Advance Grating-Based Spectroscopy ALS Scientists Patent Technique To Dramatically Advance Grating-Based Spectroscopy Print Gratings...

350

The mechanical properties of FeAl  

SciTech Connect (OSTI)

Only in the last few years has progress been made in obtaining reproducible mechanical properties data for FeAl. Two sets of observations are the foundation of this progress. The first is that the large vacancy concentrations that exist in FeAl at high temperature are easily retained at low temperature and that these strongly affect the low-temperature mechanical properties. The second is that RT ductility is adversely affected by water vapor. Purpose of this paper is not to present a comprehensive overview of the mechanical properties of FeAl but rather to highlight our understanding of key phenomena and to show how an understanding of the factors which control the yield strength and fracture behavior has followed the discovery of the above two effects. 87 refs, 9 figs.

Baker, I. [Dartmouth Coll., Hanover, NH (United States); George, E.P. [Oak Ridge National Lab., TN (United States)

1996-12-31T23:59:59.000Z

351

Delocalization and hybridization enhance the magnetocaloric effect in Ni2Mn0.75Cu0.25Ga  

SciTech Connect (OSTI)

In view of the looming energy crisis facing our planet, attention increasingly focuses on materials potentially useful as a basis for energy saving technologies. The discovery of giant magnetocaloric (GMC) compounds - materials that exhibit especially large changes in temperature as the externally applied magnetic field is varied - is one such compound 1. These materials have potential for use in solid state cooling technology as a viable alternative to existing gas based refrigeration technologies that use choro-fluoro - and hydro-fluoro-carbon chemicals known to have a severe detrimental effect on human health and environment 2,3. Examples of GMC compounds include Gd5(SiGe)4 4, MnFeP1-xAsx 5 and Ni-Mn-Ga shape memory alloy based compounds 6-8. Here we explain how the properties of one of these compounds (Ni2MnGa) can be tuned as a function of temperature by adding dopants. By altering the free energy such that the structural and magnetic transitions coincide, a GMC compound that operates at just the right temperature for human requirements can be obtained 9. We show how Cu, substituted for Mn, pulls the magnetic transition downwards in temperature and also, counterintuitively, increases the delocalization of the Mn magnetism. At the same time, this reinforces the Ni-Ga chemical bond, raising the temperature of the martensite-austenite transition. At 25percent doping, the two transitions coincide at 317 K.

Roy, Sujoy; Blackburn, E.; Valvidares, S. M.; Fitzsimmons, M. R.; Vogel, Sven C.; Khan, M.; Dubenko, I.; Stadler, S.; Ali, N.; Sinha, S. K.; Kortright, J. B.

2008-11-26T23:59:59.000Z

352

Magnetovolume effect in Ho{sub 2}Fe{sub 17-x}Mn{sub x} compounds  

SciTech Connect (OSTI)

The structural and magnetic properties of seven compounds in the Ho{sub 2}Fe{sub 17-x}Mn{sub x} series (x = 0-5) have been investigated. The spontaneous magnetization M{sub s} at 10 K exhibits a minimum at x{approx_equal} 3.8 while the 3d-sublattice magnetization M{sub T} is found to decrease at {approx} -3.4 {mu}{sub B}/per Mn atom compared with the rate of {approx}-2.0 {mu}{sub B}/per Mn atom expected from a simple dilution model. All of the Ho{sub 2}Fe{sub 17-x}Mn{sub x} compounds exhibit anisotropic thermal expansion below their Curie temperatures leading to the presence of strong magnetovolume effects and Invar-type behavior below T{sub C}. An approximately zero volume thermal expansion has been detected between 10 K and 270 K for Ho{sub 2}Fe{sub 17}. The maximum magnetic entropy changes for Ho{sub 2}Fe{sub 17-x}Mn{sub x} with x = 0 and 2.0 are 3.2 J kg{sup -1} K{sup -1} around T{sub C} {approx} 336 K and 2.7 J kg{sup -1} K{sup -1} around T{sub C} {approx} 302 K, respectively, for magnetic field change of B = 0-5 T.

Wang, J. L. [Institute for Superconductivity and Electronic Materials, University of Wollongong (Australia); Bragg Institute, ANSTO, Menai, NSW 2234 (Australia); School of Physical, Environmental and Mathematical Sciences, University of New South Wales, Canberra, ACT 2600 (Australia); Studer, A. J.; Kennedy, S. J. [Bragg Institute, ANSTO, Menai, NSW 2234 (Australia); Zeng, R.; Dou, S. X. [Institute for Superconductivity and Electronic Materials, University of Wollongong (Australia); Campbell, S. J. [School of Physical, Environmental and Mathematical Sciences, University of New South Wales, Canberra, ACT 2600 (Australia)

2012-04-01T23:59:59.000Z

353

The beta-decay of 22Al  

E-Print Network [OSTI]

In an experiment performed at the LISE3 facility of GANIL, we studied the decay of 22Al produced by the fragmentation of a 36Ar primary beam. A beta-decay half-life of 91.1 +- 0.5 ms was measured. The beta-delayed one- and two-proton emission as well as beta-alpha and beta-delayed gamma decays were measured and allowed us to establish a partial decay scheme for this nucleus. New levels were determined in the daughter nucleus 22Mg. The comparison with model calculations strongly favours a spin-parity of 4+ for the ground state of 22Al.

N. L. Achouri; F. de Oliveira Santos; M. Lewitowicz; B. Blank; J. Aysto; G. Canchel; S. Czajkowski; P. Dendooven; A. Emsallem; J. Giovinazzo; N. Guillet; A. Jokinen; A. M. Laird; C. Longour; K. Perajarvi; N. Smirnova; M. Stanoiu; J. C. Thomas

2006-08-01T23:59:59.000Z

354

AL/FAL 99-01  

Office of Environmental Management (EM)

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355

ALS Operating Schedule on Google Calendar  

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356

ALS Reveals New State of Matter  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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357

ALS Reveals New State of Matter  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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358

Electronic circuits having NiAl and Ni.sub.3 Al substrates  

DOE Patents [OSTI]

An electronic circuit component having improved mechanical properties and thermal conductivity comprises NiAl and/or Ni.sub.3 Al, upon which an alumina layer is formed prior to applying the conductive elements. Additional layers of copper-aluminum alloy or copper further improve mechanical strength and thermal conductivity.

Deevi, Seetharama C. (Midlothian, VA); Sikka, Vinod K. (Oak Ridge, TN)

1999-01-01T23:59:59.000Z

359

Synthesis of nanostructured AlN by solid state reaction of Al and diaminomaleonitrile  

SciTech Connect (OSTI)

The solid state reaction of diaminomaleonitrile (DAMN) with aluminum via both mechanochemical and thermal treatment routes was studied by X-ray diffraction and Fourier transform infrared spectroscopy. During the milling process, the reaction starts with the deammoniation of the DAMN molecules, followed by the formation of nanostructured AlN powder as the main solid product after milling for 7 h. The reactivity of the mixed powder was also investigated during the conventional thermal treatment process using differential scanning calorimetry, derivative thermogravimetry and thermogravimetric analysis. The results reveal that DAMN starts to polymerize at 192 Degree-Sign C by the elimination of the amine groups. Furthermore, increasing the annealing temperature leads to the formation of a nitrogen-containing carbonaceous material with the structure similar to non-crystalline carbon. However, no evidence for the formation of AlN was observed in the annealed samples even at temperatures as high as the Al melting point. - Graphical abstract: AlN nanoparticles obtained after milling of Al and diaminomaleonitrile (DAMN) for 12 h. Highlights: Black-Right-Pointing-Pointer Solid state reaction of diaminomaleonitrile (DAMN) with Al was studied via mechanochemical and thermal treatment routs. Black-Right-Pointing-Pointer Nanocrystalline AlN was successfully synthesized by the mechanochemical process. Black-Right-Pointing-Pointer The C/N material was formed by polymerization of DAMN during the thermal treatment process. Black-Right-Pointing-Pointer No reaction between DAMN and Al was detected during the thermal treatment method.

Rounaghi, S.A., E-mail: s.a.rounaghi@gmail.com [Department of Materials Engineering, Ferdowsi University of Mashhad. P.O. Box no. 91775-1111, Mashhad (Iran, Islamic Republic of); IFW Dresden, Institut fuer Komplexe Materialien, Postfach 27 01 16, Dresden D-01171 (Germany); Eshghi, H., E-mail: heshghi@ferdowsi.um.ac.ir [Department of Chemistry, Ferdowsi University of Mashhad. P.O. Box no. 91775-1436, Mashhad (Iran, Islamic Republic of); Kiani Rashid, A.R.; Vahdati Khaki, J. [Department of Materials Engineering, Ferdowsi University of Mashhad. P.O. Box no. 91775-1111, Mashhad (Iran, Islamic Republic of)] [Department of Materials Engineering, Ferdowsi University of Mashhad. P.O. Box no. 91775-1111, Mashhad (Iran, Islamic Republic of); Samadi Khoshkhoo, M.; Scudino, S. [IFW Dresden, Institut fuer Komplexe Materialien, Postfach 27 01 16, Dresden D-01171 (Germany)] [IFW Dresden, Institut fuer Komplexe Materialien, Postfach 27 01 16, Dresden D-01171 (Germany); Eckert, J. [IFW Dresden, Institut fuer Komplexe Materialien, Postfach 27 01 16, Dresden D-01171 (Germany) [IFW Dresden, Institut fuer Komplexe Materialien, Postfach 27 01 16, Dresden D-01171 (Germany); TU Dresden, Institut fuer Werkstoffwissenschaft, Dresden D-01062 (Germany)

2013-02-15T23:59:59.000Z

360

I have never touched her: the body in Al-Ghazal Al-‘Udhri   

E-Print Network [OSTI]

Al-ghazal al-‘udhri emerged as a remarkable literary genre in Arabic literature during the Umayyad period (7th-8th centuries CE). The leaders of this genre are famous poet-lovers who were known for their dramatic love ...

Alharthi, Jokha Mohammed

2011-02-09T23:59:59.000Z

Note: This page contains sample records for the topic "mn al 1970-1974" from the National Library of EnergyBeta (NLEBeta).
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to obtain the most current and comprehensive results.


361

Phase transformation during mechano-synthesis of nanocrystalline/amorphous Fe–32Mn–6Si alloys  

SciTech Connect (OSTI)

Mechano-synthesis of Fe–32Mn–6Si alloy by mechanical alloying of the elemental powder mixtures was evaluated by running the ball milling process under an inert argon gas atmosphere. In order to characterize the as-milled powders, powder sampling was performed at predetermined intervals from 0.5 to 192 h. X-ray florescence analyzer, X-ray diffraction, scanning electron microscope, and high resolution transmission electron microscope were utilized to investigate the chemical composition, structural evolution, morphological changes, and microstructure of the as-milled powders, respectively. According to the results, the nanocrystalline Fe–Mn–Si alloys were completely synthesized after 48 h of milling. Moreover, the formation of a considerable amount of amorphous phase during the milling process was indicated by quantitative X-ray diffraction analysis as well as high resolution transmission electron microscopy image and its selected area diffraction pattern. It was found that the ?-to-? and subsequently the amorphous-to-crystalline (especially martensite) phase transformation occurred by milling development. - Graphical abstract: Mechano-synthesis of nanocrystalline/amorphous Fe–32Mn–6Si shape memory alloys in the powder form: amorphous phase formation, ?-to-? phase transformation, mechano-crystallization of the amorphous, and martensite phase formation during the process. Highlights: • During MA, the ?-to-? phase transformation and amorphization occurred. • Mechano-crystallization of the amorphous phase occurred at sufficient milling time. • The formation of high amount of ?-martensite was evidenced at high milling times. • The platelet, spherical, and then irregular particle shapes was extended by MA. • By MA, the particles size was increased, then reduced, and afterward re-increased.

Amini, Rasool, E-mail: ramini2002@gmail.com [Department of Materials Science and Engineering, Shiraz University of Technology, 71555-313 Shiraz (Iran, Islamic Republic of); Shamsipoor, Ali [Department of Materials Science and Engineering, Shiraz University of Technology, 71555-313 Shiraz (Iran, Islamic Republic of); Ghaffari, Mohammad [Department of Electrical and Electronics Engineering, UNAM-National Institute of Materials Science and Nanotechnology Bilkent University, Ankara 06800 (Turkey); Alizadeh, Morteza [Department of Materials Science and Engineering, Shiraz University of Technology, 71555-313 Shiraz (Iran, Islamic Republic of); Okyay, Ali Kemal [Department of Electrical and Electronics Engineering, UNAM-National Institute of Materials Science and Nanotechnology Bilkent University, Ankara 06800 (Turkey)

2013-10-15T23:59:59.000Z

362

Magnetic and electrical properties of layered magnets Tl(Cr,Mn,Co)Se{sub 2}  

SciTech Connect (OSTI)

Tl(Cr,Mn,Co)Se{sub 2} crystals were synthesized at T {approx} 1050 K. X-ray diffraction analysis showed that TlCrSe{sub 2}, TlMnSe{sub 2}, and TlCoSe{sub 2} compounds crystallize in the hexagonal crystal system with the lattice parameters: a = 3.6999 A, c = 22.6901 A, c/a {approx} 6.133, z = 3, {rho}{sub x} = 6.209 g/cm{sup 3}; a = 6.53 A, c = 23.96 A, c/a {approx} 3.669, z = 8, {rho}{sub x} = 6.71 g/cm{sup 3}; and a = 3.747 A, c = 22.772 A, c/a {approx} 6.077, z = 3, {rho}{sub x} = 7.577 g/cm{sup 3}, respectively. Magnetic and electrical studies in the temperature range from 80-400 K showed that TlCrSe{sub 2} is a semiconductor ferromagnet, TlMnSe{sub 2} is a semiconductor antiferromagnet, and TlCoSe{sub 2} is a ferrimagnet with a conductivity characteristic of metals. A rather large deviation in the experimental effective magnetic moment for TlCrSe{sub 2} (3.05 {mu}B) from the theoretical value (3.85 {mu}B) is attributed to two-dimensional magnetic ordering in the paramagnetic region of the noticeably layered ferromagnet TlCrSe{sub 2}. In TlCrSe{sub 2}, a correlation between magnetic and electrical properties was detected.

Veliyev, R. G.; Sadikhov, R. Z.; Kerimova, E. M., E-mail: ekerimova@physics.ab.az; Asadov, Yu. G.; Jabbarov, A. I. [National Academy of Sciences of Azerbaijan, Institute of Physics (Azerbaijan)

2009-02-15T23:59:59.000Z

363

Magnetoelastic Coupling and Symmetry Breaking in the Frustrated Antiferromagnet {alpha}-NaMnO{sub 2}  

SciTech Connect (OSTI)

The magnetic and crystal structures of the {alpha}-NaMnO{sub 2} have been determined by high-resolution neutron powder diffraction. The system maps out a frustrated triangular spin lattice with anisotropic interactions that displays two-dimensional spin correlations below 200 K. Magnetic frustration is lifted through magneto-elastic coupling, evidenced by strong anisotropic broadening of the diffraction profiles at high temperature and ultimately by a structural phase transition at 45 K. In this low-temperature regime a three-dimensional antiferromagnetic state is observed with a propagation vector k=((1/2),(1/2),0)

Giot, Maud [Institute of Electronic Structure and Laser, Foundation for Research and Technology - Hellas, Vassilika Vouton, 71110 Heraklion (Greece); ISIS, Science and Technology Facilities Council, Rutherford Appleton Laboratory, Chilton-Didcot, OX11 0QX, Oxfordshire (United Kingdom); Chapon, Laurent C.; Radaelli, Paolo G. [ISIS, Science and Technology Facilities Council, Rutherford Appleton Laboratory, Chilton-Didcot, OX11 0QX, Oxfordshire (United Kingdom); Androulakis, John; Lappas, Alexandros [Institute of Electronic Structure and Laser, Foundation for Research and Technology - Hellas, Vassilika Vouton, 71110 Heraklion (Greece); Green, Mark A. [NIST Center for Neutron Research, 100 Bureau Drive, Gaithersburg, Maryland 20899-8562 (United States); Department of Materials Science and Engineering, University of Maryland, College Park, Maryland 20742-2115 (United States)

2007-12-14T23:59:59.000Z

364

Vacancy dynamic in Ni-Mn-Ga ferromagnetic shape memory alloys  

SciTech Connect (OSTI)

Vacancies control any atomic ordering process and consequently most of the order-dependent properties of the martensitic transformation in ferromagnetic shape memory alloys. Positron annihilation spectroscopy demonstrates to be a powerful technique to study vacancies in NiMnGa alloys quenched from different temperatures and subjected to post-quench isothermal annealing treatments. Considering an effective vacancy type the temperature dependence of the vacancy concentration has been evaluated. Samples quenched from 1173?K show a vacancy concentration of 1100?ą?200?ppm. The vacancy migration and formation energies have been estimated to be 0.55?ą?0.05?eV and 0.90?ą?0.07?eV, respectively.

Merida, D., E-mail: david.merida@ehu.es [Fisika Aplikatua II Saila, Euskal Herriko Unibertsitatea UPV/EHU, p.k. 644, 48080 Bilbao (Spain); Elektrizitate eta Elektronika Saila, Euskal Herriko Unibertsitatea UPV/EHU, p.k. 644, 48080 Bilbao (Spain); García, J. A. [Fisika Aplikatua II Saila, Euskal Herriko Unibertsitatea UPV/EHU, p.k. 644, 48080 Bilbao (Spain); BC Materials (Basque Centre for Materials, Application and Nanostructures), 48040 Leioa (Spain); Sánchez-Alarcos, V.; Pérez-Landazábal, J. I.; Recarte, V. [Departamento de Física, Universidad Pública de Navarra, Campus de Arrosadia, 31006 Pamplona (Spain); Plazaola, F. [Elektrizitate eta Elektronika Saila, Euskal Herriko Unibertsitatea UPV/EHU, p.k. 644, 48080 Bilbao (Spain)

2014-06-09T23:59:59.000Z

365

Spin relaxation time dependence on optical pumping intensity in GaAs:Mn  

SciTech Connect (OSTI)

We analyze the dependence of electron spin relaxation time on optical pumping intensity in a partially compensated acceptor semiconductor GaAs:Mn using analytic solutions for the kinetic equations of the charge carrier concentrations. Our results are applied to previous experimental data of spin-relaxation time vs. excitation power for magnetic concentrations of approximately 10{sup 17}?cm{sup ?3}. The agreement of our analytic solutions with the experimental data supports the mechanism of the earlier-reported atypically long electron-spin relaxation time in the magnetic semiconductor.

Burobina, V. [Department of Physics and Astronomy, University of Utah, 115 South 1400 East, Salt Lake City, Utah 84112-0830 (United States); Binek, Ch. [Department of Physics and Astronomy, Nebraska Center for Materials and Nanoscience, Theodore Jorgensen Hall, 855 North 16th Street, University of Nebraska, P.O. Box 880299, Lincoln, Nebraska 68588-0299 (United States)

2014-04-28T23:59:59.000Z

366

Oxidation Characteristics of Fe-18Cr-18Mn-stainless alloys  

SciTech Connect (OSTI)

Air oxidation studies of Fe-18Cr-18Mn stainless steels were conducted at 525°C, 625°C, and 725°C. Alloys were evaluated with respect to changes in oxidation properties as a result of interstitial additions of nitrogen and carbon and of minor solute additions of silicon, molybdenum, and nickel. Interstitial concentrations possibly had a small, positive effect on oxidation resistance. Minor solute additions significantly improved oxidation resistance but could also reduce interstitial solubility resulting in formation of chromium carbides. Loss of solute chromium resulted in a slight reduction in oxidation protection. Oxidation lasting over 500 hours produced a manganese rich, duplex oxide structure: an outer sesquioxide and an inner spinel oxide.

James Rawers

2010-10-01T23:59:59.000Z

367

Ferromagnetic transition temperature enhancement in (Ga,Mn)As semiconductors by carbon codoping  

E-Print Network [OSTI]

-1829/2003/68~16!/161202~4!/$20.00 68 161202- t in ?Ga,Mn?As semiconductors codoping ,2,4 and A. H. MacDonald2 a? 10, 162 53 Praha 6, Czech Republic y Station C1600, Austin, Texas 78712-0264, USA 2, 182 21 Praha 8, Czech Republic y, College Station, Texas 77843-4242, USA d 13... Society1 RAPID COMMUNICATIONS JUNGWIRTH, MASE? K, SINOVA, AND MacDONALD PHYSICAL REVIEW B 68, 161202~R! ~2003! The above qualitative analysis of formation energies sug- gests that CAs codoping is favorable for achieving high Curie temperatures. Unlike...

Jungwirth, T.; Masek, J.; Sinova, Jairo; MacDonald, AH.

2003-01-01T23:59:59.000Z

368

Synthesis and Luminescence of ZnMgS:Mn2+ Nanoparticles. | EMSL  

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369

File:USDA-CE-Production-GIFmaps-MN.pdf | Open Energy Information  

Open Energy Info (EERE)

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370

Stabilization of ZnMnO3 Phase from Sol-gel Synthesized Nitrate Precursors .  

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371

Suppression of conductivity in Mn-Doped ZnO Thin Films. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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372

Neutron structural characterization, inversion degree and transport properties of NiMn{sub 2}O{sub 4} spinel prepared by the hydroxide route  

SciTech Connect (OSTI)

Graphical abstract: A pure specimen has been synthesized by the hydroxide route. This spinel, studied by NPD, shows an important inversion degree, ? = 0.80. A bond-valence study shows that the tetrahedral Mn ions are divalent whereas the octahedral Mn and Ni are slightly oxidized from the expected 3+ and 2+ values, respectively. The mixed valence Mn{sup 3+}/Mn{sup 4+} accounts for a hopping mechanism between adjacent octahedral sites, leading to a significant conductivity. Highlights: ? A low-temperature hydroxide route allowed preparing almost pure specimens of NiMn{sub 2}O{sub 4}. ? NPD essential to determine inversion degree; contrasting Ni and Mn for neutrons. ? Bond valence establishes valence state of octahedral and tetrahedral Ni and Mn ions. ? Thermal analysis, transport measurements complement characterization of this oxide. ? A structure–properties relationship is established. -- Abstract: The title compound has been synthesized by the hydroxide route. The crystal structure has been investigated at room temperature from high-resolution neutron powder diffraction (NPD) data. It crystallizes in a cubic spinel structure, space group Fd3{sup Ż}m, Z = 8, with a = 8.3940(2) ? at 295 K. The crystallographic formula is (Ni{sub 0.202(1)}Mn{sub 0.798(1)}){sub 8a}(Ni{sub 0.790(1)}Mn{sub 1.210(1)}){sub 16d}O{sub 4} where 8a and 16d stand for the tetrahedral and octahedral sites of the spinel structure, respectively. There is a significant inversion degree of the spinel structure, ? = 0.80. In fact, the variable parameter for the oxygen position, u = 0.2636(4), is far from that expected (u = 0.25) for normal spinels. From a bond-valence study, it seems that the valence distribution in NiMn{sub 2}O{sub 4} spinel is not as trivial as expected (Ni{sup 2+} and Mn{sup 3+}), but clearly the tetrahedral Mn ions are divalent whereas the octahedral Mn and Ni are slightly oxidized from the expected +3 and +2 values, respectively. The mixed valence observed at the octahedral sites provides the charge carriers that, by a hopping mechanism between Mn{sup 3+}/Mn{sup 4+} adjacent sites, leads to a significant conductivity, up to 0.85 S cm{sup ?1} at 800 °C in air.

Sagua, A.; Lescano, Gabriela M. [Departamento de Química, Laboratorio de Fisicoquímica Inorgánica, Universidad Nacional del Sur, INQUISUR, 8000 Bahía Blanca (Argentina)] [Departamento de Química, Laboratorio de Fisicoquímica Inorgánica, Universidad Nacional del Sur, INQUISUR, 8000 Bahía Blanca (Argentina); Alonso, J.A., E-mail: jaalonso@icmm.csic.es [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco, E-28049 Madrid (Spain); Martínez-Coronado, R. [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco, E-28049 Madrid (Spain)] [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco, E-28049 Madrid (Spain); Fernández-Díaz, M.T. [Institut Laue Langevin, BP 156X, Grenoble F-38042 (France)] [Institut Laue Langevin, BP 156X, Grenoble F-38042 (France); Morán, E. [Departamento de Química Inorgánica, Facultad de Ciencias Químicas, Universidad Complutense, 28040 Madrid (Spain)] [Departamento de Química Inorgánica, Facultad de Ciencias Químicas, Universidad Complutense, 28040 Madrid (Spain)

2012-06-15T23:59:59.000Z

373

LiMn{sub 2}O{sub 4} nanoparticles anchored on graphene nanosheets as high-performance cathode material for lithium-ion batteries  

SciTech Connect (OSTI)

Nanocrystalline LiMn{sub 2}O{sub 4}/graphene nanosheets nanocomposite has been successfully synthesized by a one-step hydrothermal method without post-heat treatment. In the nanocomposite, LiMn{sub 2}O{sub 4} nanoparticles of 10–30 nm in size are well crystallized and homogeneously anchored on the graphene nanosheets. The graphene nanosheets not only provide a highly conductive matrix for LiMn{sub 2}O{sub 4} nanoparticles but also effectively reduce the agglomeration of LiMn{sub 2}O{sub 4} nanoparticles. The nanocrystalline LiMn{sub 2}O{sub 4}/graphene nanosheets nanocomposite exhibited greatly improved electrochemical performance in terms of specific capacity, cycle performance, and rate capability compared with the bare LiMn{sub 2}O{sub 4} nanoparticles. The superior electrochemical performance of the nanocrystalline LiMn{sub 2}O{sub 4}/graphene nanosheets nanocomposite makes it promising as cathode material for high-performance lithium-ion batteries. - Graphical abstract: Nanocrystalline LiMn{sub 2}O{sub 4}/graphene nanosheets (GNS) nanocomposite exhibit superior cathode performance for lithium-ion batteries compared to the bare LiMn{sub 2}O{sub 4} nanoparticles. Display Omitted - Highlights: • LiMn{sub 2}O{sub 4}/graphene nanocomposite is synthesized by a one-step hydrothermal method. • LiMn{sub 2}O{sub 4} nanoparticles are uniformly anchored on the graphene nanosheets. • The nanocomposite exhibits excellent cathode performance for lithium-ion batteries.

Lin, Binghui; Yin, Qing; Hu, Hengrun; Lu, Fujia [School of Materials Science and Engineering, Nanjing University of Science and Technology, Xiaolingwei 200, Nanjing, Jiangsu 210094 (China); Xia, Hui, E-mail: xiahui@njust.edu.cn [School of Materials Science and Engineering, Nanjing University of Science and Technology, Xiaolingwei 200, Nanjing, Jiangsu 210094 (China); Herbert Gleiter Institute of Nanoscience, Nanjing University of Science and Technology, Nanjing 210094 (China)

2014-01-15T23:59:59.000Z

374

Solid-State 55Mn NMR Spectroscopy of bis(?-oxo)dimanganese(IV) [Mn2O2(salpn)2], a Model for the Oxygen Evolving Complex in Photosystem II  

SciTech Connect (OSTI)

Given the obvious global energy needs, it has become imperative to develop a catalytic process for converting water to molecular oxygen and protons. Many have sought to understand the details of photosynthesis and in particular the water splitting reaction to help in the development of the appropriate catalysis.1-3 While the scientific community has made great strides towards this goal, it has fallen short at the critical stage of the determination of the structure associated with the oxygen evolving complex (OEC) within photosystem II (PSII).4,5 Despite the existence of x-ray structures of PSII,6-8 the best data we have for the structure of the OEC comes from models derived from EPR and EXAFS measurements.9-14 This experimental situation has led to collaborations with theoreticians to enable the development of models for the structure of the OEC where the experimental observables (EXAFS and magnetic resonance parameters) serve as constraints to the theoretical calculations. Of particular interest to this study is the observation of the S1 state of the Kok cycle15 where the core of the OEC can be described as a tetranuclear manganese cluster composed of Mn4OxCa. The simplest model for the OEC can be thought of as two Mn-pairs and a Ca2+ where each Mn-pair is antiferromagnetically coupled to its partner. We utilize the term "pair" to describe the Mn atoms within the OEC with the same oxidation state, which for the S1 state is (Mn2(III, III) and Mn2(IV, IV)).16 It is unclear as to the degree of interaction between the pairs as well as the role of the Ca2+. At cryogenic temperatures the S1 state of the OEC is diamagnetic and in principle amenable to solid-state NMR experiments.

Ellis, Paul D.; Sears, Jesse A.; Yang, Ping; Dupuis, Michel; Boron, Ted; Pecoraro, Vince; Stich, Troy; Britt, R. David; Lipton, Andrew S.

2010-12-01T23:59:59.000Z

375

Partha P. Mitra's Publications (Erlich, Mitra et al. 2008; Saar and Mitra 2008; DeCoteau, Thorn et al. 2007; DeCoteau,  

E-Print Network [OSTI]

Partha P. Mitra's Publications (Erlich, Mitra et al. 2008; Saar and Mitra 2008; DeCoteau, Thorn et al. 2007; DeCoteau, Thorn et al. 2007; Lin, Bohland et al. 2007; Mitra 2007; Mitra and Bokil 2007; Valente, Golani et al. 2007; Valente, Wang et al. 2007; Andrews, Saar et al. 2006; Bokil, Purpura et al

376

Grain boundary compositon in NiAl  

SciTech Connect (OSTI)

The high temperature strength and oxidation resistance of many transition metal aluminides makes these intermetallic materials attractive for high temperature applications. However, these aluminides are generally brittle at low temperatures and this restricts their technological applications. However, these aluminides are generally brittle at low temperatures and this restricts their technological applications. It has been demonstrated that the addition of more than 200 ppm of boron to the L1{sub 2}-ordered Ni{sub 3}Al changes the fracture behavior from intergranular to transgranular and increases the ductility. The B2-ordered NiAl nickel aluminide is particularly attractive because of its low density and high melting temperature. This aluminide also fractures intergranularly at room temperature. However, no improvement in ductility is observed with similar boron additions even though the intergranular fracture is suppressed and there is a significant increase in the yield strength. In this paper, the results of an atom probe field ion microscopy investigation of the compositions of the grain boundaries in undoped and boron-doped NiAl are presented. The suitability of the atom probe field ion microscopy technique for the characterization of boundaries has clearly been demonstrated in many previous investigations including the characterization of boron segregation to grain boundaries and other planar features in Ni{sub 3}Al.

Miller, M.K.; Jayaram, R.; Camus, P.P. (Metals and Ceramics Div., Oak Ridge National Lab., Oak Ridge, TN (US))

1992-02-15T23:59:59.000Z

377

4, 29593004, 2007 D. Mietchen et al.  

E-Print Network [OSTI]

detectable amounts of residual water or organic molecules, the analysis of which has become an integral part than organic residues. 2960 #12;BGD 4, 2959­3004, 2007 Fossil MRI D. Mietchen et al. Title Page deposits have been ac- cumulated over geologic

Hammerton, James

378

Cherednik algebras, Macdonald polynomi als and combinatorics  

E-Print Network [OSTI]

Cherednik algebras, Macdonald polynomi­ als and combinatorics Mark Haiman # Abstract. In the first part of this article we review the general theory of Cherednik algebras and non­symmetric Macdonald). Primary 33D52, Secondary 05E10. Keywords. Macdonald polynomials, a#ne Hecke algebras, Cherednik algebras

Haiman, Mark D.

379

Der Gebudebereich als Motor fr die Energiewende  

E-Print Network [OSTI]

Verbrauch! #12;#12;Gebäude als Energiespeicher 1,09 TWh/K 1.090.000.000 kWh/K #12;Gebäude der Zukunft Energieerzeuger + Energiespeicher #12;Wärmebrßcken ­ Thermografie #12;#12;,,Die Szenarien belegen, die

380

Lieth et al -p.1 Progress Report  

E-Print Network [OSTI]

of its overall thermal status, therefore, any physical process that affects the thermal exchange between is solar radiation. Light sensors are used to measure the global solar radiation striking the greenhouse;Lieth et al - p.2 conductance which is of significance to greenhouse energetics includes heat fluxes

Lieth, J. Heinrich

Note: This page contains sample records for the topic "mn al 1970-1974" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Scott (e Amundsen) al Polo Sud,  

E-Print Network [OSTI]

pag. 2 Scott (e Amundsen) al Polo Sud, cento anni dopo di Nicoletta Brazzelli pag. 4 pag. 6 Entra in applicazione della legge 240/2010. Si conclude cosĂŹ l'iter preparatorio dello Statuto ed inizia la traduzione

De Cindio, Fiorella

382

Ternary Dy-Er-Al magnetic refrigerants  

DOE Patents [OSTI]

A ternary magnetic refrigerant material comprising (Dy{sub 1{minus}x}Er{sub x})Al{sub 2} for a magnetic refrigerator using the Joule-Brayton thermodynamic cycle spanning a temperature range from about 60K to about 10K, which can be adjusted by changing the Dy to Er ratio of the refrigerant. 29 figs.

Gschneidner, K.A. Jr.; Takeya, Hiroyuki

1995-07-25T23:59:59.000Z

383

Ternary Dy-Er-Al magnetic refrigerants  

DOE Patents [OSTI]

A ternary magnetic refrigerant material comprising (Dy.sub.1-x Er.sub.x)Al.sub.2 for a magnetic refrigerator using the Joule-Brayton thermodynamic cycle spanning a temperature range from about 60K to about 10K, which can be adjusted by changing the Dy to Er ratio of the refrigerant.

Gschneidner, Jr., Karl A. (Ames, IA); Takeya, Hiroyuki (Ibaraki, JP)

1995-07-25T23:59:59.000Z

384

(12) United States Patent Vertes et al.  

E-Print Network [OSTI]

(12) United States Patent Vertes et al. (54) LASERABLATION ELECTROSPRAY IONIZATION (LAESI) ( *) Notice: Subject to any disclaimer, the term ofthis patent is extended or adjusted under 35 U.S.C. 154(b) by 0 days. lbis patent is subject to a terminal dis- claimer. (21) Appl. No.: 131271,435 Oct. 12, 2011

Vertes, Akos

385

(12) United States Patent Geohegan et al.  

E-Print Network [OSTI]

(12) United States Patent Geohegan et al. US008540542B2 US 8,540,542 B2 Sep. 24, 2013 (10) Patent N0.: (45) Date of Patent: (54) TRANSPARENT CONDUCTIVE NANO-COMPOSITES (75) Inventors: David Bruce Research Foundation, Knoxville, TN (US) Notice: Subject to any disclaimer, the term ofthis patent

Geohegan, David B.

386

(12) United States Patent Vertes et al.  

E-Print Network [OSTI]

(12) United States Patent Vertes et al. (54) PROTEIN MICROSCOPE (75) Inventors: Akos Vertes, Reston patent is extended or adjusted under 35 U.S.c. 154(b) by 135 days. (21) Appl. No.: 111795,687 (22 1111111111111111111111111111111111111111111111111111111111111 16 US007735146B2 (10) Patent No.: (45) Date of Patent: US 7,735,146 B2 Jun. 8,2010 (56) References

Vertes, Akos

387

(12) United States Patent Grier et al.  

E-Print Network [OSTI]

(12) United States Patent Grier et al. US008791985B2 US 8,791,985 B2 Jul. 29, 2014 (10) Patent N0.: (45) Date of Patent: (54) (75) (73) (21) (22) (86) (87) (65) (60) (51) (52) TRACKING to any disclaimer, the term ofthis patent is extended or adjusted under 35 U.S.C. 154(b) by 744 days. 12

Grier, David

388

Fachprfungsordnung fr den Bachelor-Teilstudiengang Deutsch als Fremdsprache  

E-Print Network [OSTI]

Fachprßfungsordnung fßr den Bachelor-Teilstudiengang Deutsch als Fremdsprache an der Ernst Bachelor-Teilstudiengang Deutsch als Fremd- sprache als Satzung: Inhaltsverzeichnis § 1 Geltungsbereich § 2- Teilstudiengang Deutsch als Fremdsprache. Ergänzend gilt die Gemeinsa- me Prßfungsordnung fßr Bachelor- und Master

Greifswald, Ernst-Moritz-Arndt-Universität

389

High Nb, Ta, and Al creep- and oxidation-resistant austenitic stainless steel  

DOE Patents [OSTI]

An austenitic stainless steel HTUPS alloy includes, in weight percent: 15 to 30 Ni; 10 to 15 Cr; 2 to 5 Al; 0.6 to 5 total of at least one of Nb and Ta; no more than 0.3 of combined Ti+V; up to 3 Mo; up to 3 Co; up to 1 W; up to 0.5 Cu; up to 4 Mn; up to 1 Si; 0.05 to 0.15 C; up to 0.15 B; up to 0.05 P; up to 1 total of at least one of Y, La, Ce, Hf, and Zr; less than 0.05 N; and base Fe, wherein the weight percent Fe is greater than the weight percent Ni wherein said alloy forms an external continuous scale comprising alumina, nanometer scale sized particles distributed throughout the microstructure, said particles comprising at least one composition selected from the group consisting of NbC and TaC, and a stable essentially single phase fcc austenitic matrix microstructure, said austenitic matrix being essentially delta-ferrite-free and essentially BCC-phase-free.

Brady, Michael P (Oak Ridge, TN) [Oak Ridge, TN; Santella, Michael L (Knoxville, TN) [Knoxville, TN; Yamamoto, Yukinori (Oak Ridge, TN) [Oak Ridge, TN; Liu, Chain-tsuan (Oak Ridge, TN) [Oak Ridge, TN

2010-07-13T23:59:59.000Z

390

An analysis of the effects of Mn{sup 2+} on oxidative phosphorylation in liver, brain, and heart mitochondria using state 3 oxidation rate assays  

SciTech Connect (OSTI)

Manganese (Mn) toxicity is partially mediated by reduced ATP production. We have used oxidation rate assays-a measure of ATP production-under rapid phosphorylation conditions to explore sites of Mn{sup 2+} inhibition of ATP production in isolated liver, brain, and heart mitochondria. This approach has several advantages. First, the target tissue for Mn toxicity in the basal ganglia is energetically active and should be studied under rapid phosphorylation conditions. Second, Mn may inhibit metabolic steps which do not affect ATP production rate. This approach allows identification of inhibitions that decrease this rate. Third, mitochondria from different tissues contain different amounts of the components of the metabolic pathways potentially resulting in different patterns of ATP inhibition. Our results indicate that Mn{sup 2+} inhibits ATP production with very different patterns in liver, brain, and heart mitochondria. The primary Mn{sup 2+} inhibition site in liver and heart mitochondria, but not in brain mitochondria, is the F{sub 1}F{sub 0} ATP synthase. In mitochondria fueled by either succinate or glutamate + malate, ATP production is much more strongly inhibited in brain than in liver or heart mitochondria; moreover, Mn{sup 2+} inhibits two independent sites in brain mitochondria. The primary site of Mn-induced inhibition of ATP production in brain mitochondria when succinate is substrate is either fumarase or complex II, while the likely site of the primary inhibition when glutamate plus malate are the substrates is either the glutamate/aspartate exchanger or aspartate aminotransferase.

Gunter, Thomas E., E-mail: thomas_gunter@urmc.rochester.ed [Department of Biochemistry and Biophysics, University of Rochester School of Medicine and Dentistry, Rochester, NY 14642 (United States); Gerstner, Brent, E-mail: brent_gerstner@urmc.rochester.ed [Department of Biochemistry and Biophysics, University of Rochester School of Medicine and Dentistry, Rochester, NY 14642 (United States); Lester, Tobias, E-mail: Tlester200@gmail.co [Department of Biochemistry and Biophysics, University of Rochester School of Medicine and Dentistry, Rochester, NY 14642 (United States); Wojtovich, Andrew P., E-mail: andrew_wojtovich@urmc.rochester.ed [Department of Pharmacology and Physiology, University of Rochester School of Medicine and Dentistry, Rochester, NY 14642 (United States); Malecki, Jon, E-mail: jon_malecki@urmc.rochester.ed [Department of Biochemistry and Biophysics, University of Rochester School of Medicine and Dentistry, Rochester, NY 14642 (United States); Swarts, Steven G., E-mail: steven_swarts@urmc.rochester.ed [Department of Radiation Oncology, University of Rochester School of Medicine and Dentistry, Rochester, NY 14642 (United States); Brookes, Paul S., E-mail: paul_brookes@urmc.rochester.ed [Department of Pharmacology and Physiology, University of Rochester School of Medicine and Dentistry, Rochester, NY 14642 (United States); Department of Anesthesiology, University of Rochester School of Medicine and Dentistry, Rochester, NY 14642 (United States); Gavin, Claire E., E-mail: candegavin@aol.com; Gunter, Karlene K., E-mail: karlene_gunter@urmc.rochester.ed [Department of Biochemistry and Biophysics, University of Rochester School of Medicine and Dentistry, Rochester, NY 14642 (United States)

2010-11-15T23:59:59.000Z

391

JOURNAL DE PHYSIQUE Colloque Cl, supplkment au no 4, Tome 38, Auril 1977, page Cl-303 MULTILAYER SINTERING OF MnZn FERRITES  

E-Print Network [OSTI]

SINTERING OF MnZn FERRITES IN CONTROLLED ATMOSPHERE M. I. ALAM, N. R. NAlR and T. V. RAMAMURTI Central dans la litterature que I'empilement depots de ferrites les uns sur les autres durant le traitement production des couches multiples d'echantillons de ferrite de Mn-Zn. On a utilise jusqu'a 10 couches d

Boyer, Edmond

392

Atomic-Scale Spin-Polarized Scanning Tunneling Microscopy Applied To Mn3N2(010) Haiqiang Yang and Arthur R. Smith  

E-Print Network [OSTI]

source effusion cell for Mn and a rf plasma source for N [5,6]. All STM imaging is performed at 300 K-centered tetragonal (fct) rock-salt type struc- ture. The bulk magnetic moments of the Mn atoms are FM within (001

393

Free-Standing LiNi0.5Mn1.5O4/Carbon Nanofiber Network Film as Light-Weight and High-Power  

E-Print Network [OSTI]

Free-Standing LiNi0.5Mn1.5O4/Carbon Nanofiber Network Film as Light-Weight and High-Power Cathode Pure carbon nanofiber (CNF) network without LiNi0.5Mn1.5O4 was tested in the voltage window of 3.5-5 V

Zhou, Chongwu

394

A Facile and Template-Free Hydrothermal Synthesis of Mn3O4 Nanorods on Graphene Sheets for Supercapacitor Electrodes with  

E-Print Network [OSTI]

/Mn3O4 composites were prepared by a simple hydrothermal process from KMnO4 using ethylene glycolA Facile and Template-Free Hydrothermal Synthesis of Mn3O4 Nanorods on Graphene Sheets in Faradaic electron-transfer processes of a metal oxide or conducting poly- mer.3 It is also possible

395

Suppression of the thermal hysteresis in magnetocaloric MnAs thin film by highly charged ion bombardment  

SciTech Connect (OSTI)

We present the investigation on the modifications of structural and magnetic properties of MnAs thin film epitaxially grown on GaAs induced by slow highly charged ions bombardment under well-controlled conditions. The ion-induced defects facilitate the nucleation of one phase with respect to the other in the first-order magneto-structural MnAs transition, with a consequent suppression of thermal hysteresis without any significant perturbation on the other structural and magnetic properties. In particular, the irradiated film keeps the giant magnetocaloric effect at room temperature opening new perspective on magnetic refrigeration technology for everyday use.

Trassinelli, M., E-mail: martino.trassinelli@insp.jussieu.fr; Marangolo, M.; Eddrief, M.; Etgens, V. H.; Gafton, V.; Hidki, S.; Lacaze, E.; Lamour, E.; Prigent, C.; Rozet, J.-P.; Steydli, S.; Zheng, Y.; Vernhet, D. [CNRS, UMR 7588, Institut des NanoSciences de Paris (INSP), F-75005 Paris (France); Sorbonne Universités, UPMC Univ. Paris 06, UMR 7588, INSP, F-75005 Paris (France)

2014-02-24T23:59:59.000Z

396

Thermochemical generation of hydrogen and oxygen from water. [NaMnO/sub 2/ and TiO/sub 2/  

DOE Patents [OSTI]

A thermochemical cyclic process for the production of hydrogen exploits the reaction between sodium manganate (NaMnO/sub 2/) and titanium dioxide (TiO/sub 2/) to form sodium titanate (Na/sub 2/TiO/sub 3/), manganese (II) titanate (MnTiO/sub 3/) and oxygen. The titanate mixture is treated with sodium hydroxide, in the presence of steam, to form sodium titanate, sodium manganate (III), water and hydrogen. The sodium titanate-manganate (III) mixture is treated with water to form sodium manganate (III), titanium dioxide and sodium hydroxide. Sodium manganate (III) and titanium dioxide are recycled following dissolution of sodium hydroxide in water.

Robinson, P.R.; Bamberger, C.E.

1980-02-08T23:59:59.000Z

397

Enhancing structural transition by carrier and quantum confinement: Stabilization of cubic InN quantum dots by Mn incorporation  

SciTech Connect (OSTI)

We demonstrate in this work controllable synthesis of cubic InN nanocrystals through Mn doping. We show that the pristine nanocrystal has the wurtzite structure, but can be converted into the zinc-blende (ZB) structure when it is doped with Mn. Our first-principles calculations show that the phase transition is caused by the stronger p-d coupling between the host p valence state and the impurity d level in the ZB structure, which makes the hole generation in the ZB structure easier. Quantum confinement in the nanocrystals further enhanced this effect. This observation lays an important foundation for defects control of crystal phases.

Meng, Xiuqing; Wu, Fengmin [Zhejiang Normal University, Jinhua, Zhejiang Province 321004 (China)] [Zhejiang Normal University, Jinhua, Zhejiang Province 321004 (China); Chen, Zhanghui; Li, Shu-Shen [State Key Laboratory for Superlattices and Microstructures, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083 (China)] [State Key Laboratory for Superlattices and Microstructures, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083 (China); Chen, Zhuo [Department of Physics, Beijing Institute of Technology, Beijing 100081 (China)] [Department of Physics, Beijing Institute of Technology, Beijing 100081 (China); Li, Jingbo, E-mail: jbli@semi.ac.cn, E-mail: swei@nrel.gov [Zhejiang Normal University, Jinhua, Zhejiang Province 321004 (China) [Zhejiang Normal University, Jinhua, Zhejiang Province 321004 (China); State Key Laboratory for Superlattices and Microstructures, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083 (China); Wu, Junqiao [Department of Materials Science and Engineering, University of California, Berkeley, California 94720 (United States)] [Department of Materials Science and Engineering, University of California, Berkeley, California 94720 (United States); Wei, Su-Huai, E-mail: jbli@semi.ac.cn, E-mail: swei@nrel.gov [National Renewable Energy Laboratory, Golden, Colorado 80401 (United States)] [National Renewable Energy Laboratory, Golden, Colorado 80401 (United States)

2013-12-16T23:59:59.000Z

398

Quantum Critical Transition Amplifies Magnetoelastic Coupling in Mn[N(CN)2]2  

SciTech Connect (OSTI)

We report the discovery of a magnetic quantum critical transition in Mn[N(CN)2]2 that drives the system from a canted antiferromagnetic state to the fully polarized state with amplified magnetoelastic coupling as an intrinsic part of the process. The local lattice distortions, revealed through systematic phonon frequency shifts, suggest a combined MnN6 octahedra distortion+counterrotation mechanism that reduces antiferromagnetic interactions and acts to accommodate the field-induced state. These findings deepen our understanding of magnetoelastic coupling near a magnetic quantum critical point and away from the static limit.

Brinzari, T. V.; Chen, P.; Sun, Q.-C.; Liu, J.; Tung, L.-C.; Wang, Y.; Schlueter, J. A.; Singleton, J.; Manson, J. L.; Whangbo, M.-H.; Litvinchuk, A. P.; Musfeldt, J. L.

2013-06-01T23:59:59.000Z

399

Effects of Ti substitution on structural and magnetic properties of Zn–Mn ferrospinels  

SciTech Connect (OSTI)

Highlights: ? Novel system ZnMn{sub 1?x}Ti{sub x}FeO{sub 4} synthesized by sol–gel route. ? Nanocrystalline materials. ? Magnetic materials. - Abstract: Nanocrystalline ZnMn{sub 1?x}Ti{sub x}FeO{sub 4} (1.0 ? x ? 0) ferrites were prepared by sol–gel route. Formation of single phase cubic spinel structure for all the compositions was confirmed from their X-ray diffraction patterns. The lattice parameter shows an increasing trend with the increase in Ti content. These ferrite samples existed as crystalline nanoparticles of about 30–40 nm size as observed from transmission electron microscopy (TEM) technique. EDAX analysis indicated that the concentration of different elements in different compositions is in close agreement with the starting concentrations. Infrared spectra showed two main absorption bands in the range 400–800 cm{sup ?1} arising due to tetrahedral (A) and octahedral (B) stretching vibrations. The magnetic studies indicated that, the ferrimagnetic behavior increases with titanium substitution.

Patil, R.P., E-mail: raj_rbm_raj@yahoo.com [Department of Chemistry, Shivaji University, Kolhapur 416004 (India); Patil, N.M. [Department of Chemistry, Shivaji University, Kolhapur 416004 (India); Sasikala, R. [Chemistry Division, Bhabha Atomic Research Centre, Mumbai 400085 (India); Hankare, P.P., E-mail: p_hankarep@rediffmail.com [Department of Chemistry, Shivaji University, Kolhapur 416004 (India); Delekar, S.D. [Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University, Sub-campus Osmanabad, 413501 (India)

2013-05-15T23:59:59.000Z

400

EPR in Mn2+ doped betaine calcium chloride dihydrate single crystals J. L. Ribeiro (1), J. C. Fayet (2), J. Emery (2), M. Pdzeril (2), J. Albers (3), A. Klpperpieper (3),  

E-Print Network [OSTI]

devil's staircase. In this paper we report a study of Electronic Paramagnetic Resonance of Mn2 + doped

Paris-Sud XI, UniversitĂŠ de

Note: This page contains sample records for the topic "mn al 1970-1974" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Electrochemically induced deposition method to prepare {gamma}-MnO{sub 2}/multi-walled carbon nanotube composites as electrode material in supercapacitors  

SciTech Connect (OSTI)

The {gamma}-MnO{sub 2}/multi-walled carbon nanotube ({gamma}-MnO{sub 2}/MWNT) composite has been prepared by electrochemically induced deposition method. The morphology and crystal structure of the composite were investigated by X-ray diffraction and scanning electron microscopy, respectively. The capacitive properties of the {gamma}-MnO{sub 2}/MWNT composite have been investigated by cyclic voltammetry (CV). A specific capacitance (based on {gamma}-MnO{sub 2}) as high as 579 F g{sup -1} is obtained at a scan rate of 10 mV s{sup -1} in 0.1 M Na{sub 2}SO{sub 4} aqueous solution. Additionally, the {gamma}-MnO{sub 2}/MWNT composite electrode shows excellent long-term cycle stability (only 2.4% decrease of the specific capacitance is observed after 500 CV cycles)

Fan Zhen [State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082 (China); Chen Jinhua [State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082 (China)], E-mail: chenjinhua@hnu.cn; Zhang Bing; Sun Feng; Liu Bo; Kuang Yafei [State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082 (China)

2008-08-04T23:59:59.000Z

402

MATH 22AL Fall 2012 Dr. Dad-del  

E-Print Network [OSTI]

MATH 22AL Fall 2012 Dr. Dad-del Important Information about MAT22A and MAT22AL MATH 22AL is an on line computer lab for MATH 22AL. This course uses MATLAB to reinforce the concepts learned in MATH22A. All MAT 22A students are required to take 22AL, unless they have taken Eng 6 or have a good knowledge

Goldwyn, Eli

403

Characterization of Ultrathin Films of -Al2O3 and the Chemistry of 1,3-Butadiene on NiAl(001) and -Al2O3  

E-Print Network [OSTI]

Characterization of Ultrathin Films of -Al2O3 and the Chemistry of 1,3-Butadiene on NiAl(001) and -Al2O3 Michelle M. Ivey, Kathryn A. Layman, Armen Avoyan, Heather C. Allen, and John C. HemmingerVine, California 92697 ReceiVed: October 3, 2002; In Final Form: March 27, 2003 Ultrathin films of -Al2O3 grown

404

Short-period superlattices of AlN/Al0.08Ga0.92N grown on AlN substrates S. A. Nikishin,a)  

E-Print Network [OSTI]

American Institute of Physics. [DOI: 10.1063/1.1815056] Layers of AlGaN with high content of AlN suffer (LEDs) and solar blind pho- todetectors. Short period superlattices (SPSLs) of AlN/Al0.08Ga0.92N maxima. The analysis of the central peak of the RSM shows a high degree of lateral co- herence of 44 m

Holtz, Mark

405

SILICON SURFACE PASSIVATION BY ULTRATHIN Al2O3 FILMS AND Al2O3/SiNx STACKS  

E-Print Network [OSTI]

, Florian Werner, Dimitri Zielke, and Rolf Brendel Institute for Solar Energy Research Hamelin (ISFH), Am in a conveyor-belt furnace deteriorates the passivation quality, in particular for ultrathin Al2O3 films. For Al capping layer of PECVD-SiNx onto the Al2O3. Application of Al2O3 to the rear of PERC solar cells shows

406

Radiation-induced instability of MnS precipitates and its possible consequences on irradiation-induced stress corrosion cracking of austenitic stainless steels  

SciTech Connect (OSTI)

Irradiation-assisted stress corrosion cracking (IASCC) is a significant materials issue for the light water reactor (LWR) industry and may also pose a problem for fusion power reactors that will use water as coolant. A new metallurgical process is proposed that involves the radiation-induced release into solution of minor impurity elements not usually thought to participate in IASCC. MnS-type precipitates, which contain most of the sulfur in stainless steels, are thought to be unstable under irradiation. First, Mn transmutes strongly to Fe in thermalized neutron spectra. Second, cascade-induced disordering and the inverse Kirkendall effect operating at the incoherent interfaces of MnS precipitates are thought to act as a pump to export Mn from the precipitate into the alloy matrix. Both of these processes will most likely allow sulfur, which is known to exert a deleterious influence on intergranular cracking, to re-enter the matrix. To test this hypothesis, compositions of MnS-type precipitates contained in several unirradiated and irradiated heats of Type 304, 316, and 348 stainless steels (SSs) were analyzed by Auger electron spectroscopy. Evidence is presented that shows a progressive compositional modification of MnS precipitates as exposure to neutrons increases in boiling water reactors. As the fluence increases, the Mn level in MnS decreases, whereas the Fe level increases. The S level also decreases relative to the combined level of Mn and Fe. MnS precipitates were also found to be a reservoir of other deleterious impurities such as F and O which could be also released due to radiation-induced instability of the precipitates.

Chung, H.M.; Sanecki, J.E. [Argonne National Lab., IL (United States); Garner, F.A. [Pacific Northwest National Lab., Richland, WA (United States)

1996-12-01T23:59:59.000Z

407

The evolution of Al-Azhar Street, Al-Qahira, Egypt  

E-Print Network [OSTI]

The historic quarter of Cairo, al-Qahira, is going through a period intense transformation that is threatening the physical environment as well as the social and economic fabric of the city. The transformations taking place ...

Elkatsha, Markus Fawzy Fahmy

2000-01-01T23:59:59.000Z

408

Local stress-induced effects on AlGaAs/AlOx oxidation front shape  

SciTech Connect (OSTI)

The lateral oxidation of thick AlGaAs layers (>500?nm) is studied. An uncommon shape of the oxide tip is evidenced and attributed to the embedded stress distribution, inherent to the oxidation reaction. Experimental and numerical studies of the internal strain in oxidized Al{sub x}Ga{sub 1?x}As/GaAs structures were carried out by dark-field electron holography and finite element methods. A mapping of the strain distribution around the AlGaAs/oxide interface demonstrates the main role of internal stress on the shaping of the oxide front. These results demonstrate the high relevance of strain in oxide-confined III-V devices, in particular, with over-500-nm thick AlOx confinement layers.

Chouchane, F.; Almuneau, G., E-mail: almuneau@laas.fr; Arnoult, A.; Lacoste, G.; Fontaine, C. [CNRS, LAAS, 7 avenue du colonel Roche, F-31400 Toulouse (France); Univ de Toulouse, UPS, LAAS, F-31400 Toulouse (France); Cherkashin, N. [Univ de Toulouse, UPS, LAAS, F-31400 Toulouse (France); CNRS, CEMES, 29 Rue Jeanne Marvig, 31055 Toulouse Cedex 4 (France)

2014-07-28T23:59:59.000Z

409

Observable Proxies For 26 Al Enhancement  

SciTech Connect (OSTI)

We consider the cospatial production of elements in supernova explosions to find observationally detectable proxies for enhancement of {sup 26}Al in supernova ejecta and stellar systems. Using four progenitors we explore a range of 1D explosions at different energies and an asymmetric 3D explosion. We find that the most reliable indicator of the presence of {sup 26}Al in unmixed ejecta is a very low S/Si ratio ({approx} 0.05). Production of N in O/S/Si-rich regions is also indicative. The biologically important element P is produced at its highest abundance in the same regions. Proxies should be detectable in supernova ejecta with high spatial resolution multi wavelength observations, but the small absolute abundance of material injected into a proto-planetary disk makes detection unlikely in existing or forming stellar/planetary systems.

Fryer, Christopher L [Los Alamos National Laboratory; Young, Patrick A [Los Alamos National Laboratory; Ellinger, Carola I [ASU; Arnett, William D [UNIV ARIZONA

2008-01-01T23:59:59.000Z

410

Status of the AlCap experiment  

E-Print Network [OSTI]

The AlCap experiment is a joint project between the COMET and Mu2e collaborations. Both experiments intend to look for the lepton-flavour violating conversion $\\mu + A \\rightarrow e + A$, using tertiary muons from high-power pulsed proton beams. In these experiments the products of ordinary muon capture in the muon stopping target are an important concern, both in terms of hit rates in tracking detectors and radiation damage to equipment. The goal of the AlCap experiment is to provide precision measurements of the products of nuclear capture on Aluminium, which is the favoured target material for both COMET and Mu2e. The results will be used for optimising the design of both conversion experiments, and as input to their simulations. Data was taken in December 2013 and is currently being analysed.

Litchfield, R Phillip

2015-01-01T23:59:59.000Z

411

Status of the AlCap experiment  

E-Print Network [OSTI]

The AlCap experiment is a joint project between the COMET and Mu2e collaborations. Both experiments intend to look for the lepton-flavour violating conversion $\\mu + A \\rightarrow e + A$, using tertiary muons from high-power pulsed proton beams. In these experiments the products of ordinary muon capture in the muon stopping target are an important concern, both in terms of hit rates in tracking detectors and radiation damage to equipment. The goal of the AlCap experiment is to provide precision measurements of the products of nuclear capture on Aluminium, which is the favoured target material for both COMET and Mu2e. The results will be used for optimising the design of both conversion experiments, and as input to their simulations. Data was taken in December 2013 and is currently being analysed.

R. Phillip Litchfield

2015-01-20T23:59:59.000Z

412

United States Patent [19] Carlson et al.  

E-Print Network [OSTI]

United States Patent [19] Carlson et al. [11] Patent Number: 4,523,230 [45] Date of Patent: Jun. 11 ............. 358/160, 163; 166; 167, 358/905, 21 R, 36; 382/49, 54 [56] References Cited U.S. PATENT DOCUMENTS 4 signals. 24 Claims, 8 Drawing Figures #12;U.S. Patent Jun. 11, 1985 Sheet 1 of 4 4,523,230 #12;U.S. Patent

Adelson, Edward

413

United States Patent [19] Burt et al.  

E-Print Network [OSTI]

United States Patent [19] Burt et al. [11] Patent Number: 4 , 6 98, 84 3 [45] Date of Patent: Oct, 43, 49, 50, 54, 55 [56] References Cited U.S. PATENT DOCUMENTS 3,737,855 6/1973 Cutaia.S. Patent Oct. 6, 1987 Sheet 1 of 3 4,698,843 #12;U.S. Patent Oct. 6, 1987 Sheet 2 of 3 4,698,843 #12;U

Adelson, Edward

414

Competition between stripe and checkerboard magnetic instabilities in Mn-doped BaFe2As2  

SciTech Connect (OSTI)

The appearance of unconventional superconductivity often requires the suppression of an antiferromagnetic (AFM) ordered state by tuning the chemical composition. In BaFe2As2, the AFM ordered state is driven by Fermi surface nesting, resulting in stripe magnetic ordering with propagation vector Qstripe = (; 0) (in Fe square lattice notation). Co substitution acts as an electron donor that destabilizes the nesting condition,1 leading to suppression of the stripe AFM ordering2 and the appearance of superconductivity.3,4 Mn is nominally the hole-doping counterpart of Co which should also detune the Fermi surface nesting, but it is not a superconductor.5 Here we report that Mn doping does not act solely as a hole donor, but instead introduces strong spin uctuations at a wavevector (; ) that is unrelated to the Fermi surface topology of BaFe2As2. Spin uctuations at (; ) and (; 0) coexist, suggesting the Mn dopants act as local magnetic impurities that polarize neighbouring Fe/Mn spins, potentially disrupting superconductivity.

Pratt, Daniel [Ames Laboratory and Iowa State University; Kim, M. G. [Ames Laboratory and Iowa State University; Ran, S. [Ames Laboratory and Iowa State University; Thaler, A. [Ames Laboratory and Iowa State University; Granroth, Garrett E [ORNL; Marty, Karol J [ORNL; Tian, W. [University of Tennessee, Knoxville (UTK); Zarestky, J. L. [Ames Laboratory and Iowa State University; Lumsden, Mark D [ORNL; Budko, S L [Ames Laboratory and Iowa State University; Canfield, P. C. [Ames Laboratory; Goldman, A. I. [Ames Laboratory and Iowa State University; Mcqueeney, R J [Ames Laboratory and Iowa State University; Tucker, G. S. [Ames Laboratory and Iowa State University

2012-01-01T23:59:59.000Z

415

EXAFS and FT-IR Characterization of Mn and Li Promoted Titania-Supported Rh Catalysts for CO Hydrogenation  

SciTech Connect (OSTI)

The effect of Li and Mn promoters on the structure and selectivity of supported Rh catalysts for CO hydrogenation reaction was examined. Infrared spectroscopy and X-ray absorption were used to investigate the adsorption of reactants and local structure of Rh. These techniques were used in combination with reactivity, H{sub 2} chemisorption, and temperature programmed studies to correlate structural characteristics with activity and selectivity during CO hydrogenation of unpromoted Rh/TiO{sub 2} and three promoted Rh catalysts: Rh-Li/TiO{sub 2}, Rh-Mn/TiO{sub 2}, and Rh-Li-Mn/TiO{sub 2}. The presence of a promoter slightly decreases the Rh clusters size; however, no evidence for an electronic effect induced by the presence of Li and Mn was found. Higher turnover frequencies were found for the promoted catalysts, which also showed the lower dispersion. The Li promoter introduces a weakened CO adsorption site that appears to enhance the selectivity to C{sub 2+} oxygenates. The selectivity to C{sub 2+} oxygenates varies inversely with the reducibility of Rh metal, that is, the lower the Rh reducibility, the higher the selectivity.

V Schwartz; A Campos; A Egbebi; J Spivey; S Overbury

2011-12-31T23:59:59.000Z

416

Microstructure, mechanical property and corrosion behaviors of interpenetrating C/Mg-Zn-Mn composite fabricated by suction casting  

E-Print Network [OSTI]

bonding between Mg-Zn-Mn alloy and carbon scaffold was very well. The composite had an ultimate. Introduction Carbon, in all its forms, such as carbon nanotubes, carbon fabric, carbon-carbon composites, glassy carbon, pyrocarbons and diamond- like layers, is considered as a promising material for biomedical

Zheng, Yufeng

417

Enhanced Li+ ion transport in LiNi0.5Mn1.5O4 through Control...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Citation: Zheng J, J Xiao, X Yu, L Kovarik, M Gu, F Omenya, X Chen, XQ Yang, J Liu, GL Graff, MS Whittingham, and J Zhang.2012."Enhanced Li+ ion transport in LiNi0.5Mn1.5O4...

418

Bioaccumulation of essential metals (Co, Mn and Zn) in the king scallop Pecten maximus: seawater, food and sediment exposures  

E-Print Network [OSTI]

, food and sediment exposures Marc Metiana,b , Michel Warnaua* , Laetitia HĂŠdouina,b , Paco Bustamanteb-feeding mollusks living in soft sediments, the uptake and depuration kinetics of three elements (Co, Mn and Zn) were investigated in the king scallop Pecten maximus exposed via seawater, food, or sediment, using

Boyer, Edmond

419

pH Effects on the structure of biogenic Mn-oxides Mengqiang Zhu, mzhu@UDel.Edu1  

E-Print Network [OSTI]

metals. In this study, pH effects were investigated in CaCl2 and NaCl solutions at pH 6, 7 and 8 for 48. The structure of BioMnOx preformed at pH 8 in a CaCl2 solution was not modified by lower pHs of the CaCl2

Sparks, Donald L.

420

Transport properties of La1?xCaxMnO3 (Eur. Phys. J. B 26, 467?471...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Societ a Italiana di Fisica Springer-Verlag 2002 Transport properties of La 1-x Ca x MnO 3 (0.5 x < 1) H.-D. Zhou, R.-K. Zheng, G. Li, S.-J. Feng, F. Liu, X.-J. Fan,...

Note: This page contains sample records for the topic "mn al 1970-1974" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Physica B 322 (2002) 236247 The electronic properties of FeCo, Ni3Mn and Ni3Fe  

E-Print Network [OSTI]

1. Introduction The Fe- and Mn-based transition metal (TM) alloys possess a number of unusual with the local-density functional method. It is shown that the value of the magnetic moment is insensitive- stant and magnetization of Fe­Co alloys depend non-monotonically on Co concentration, and change

Kim, Jai Sam

422

Copyright 2010 IEEE. Reprinted from Proceedings of the 2010 IEEE Power & Energy Society General Meeting, Minneapolis, MN, USA.  

E-Print Network [OSTI]

General Meeting, Minneapolis, MN, USA. This material is posted here with permission of the IEEE and therefore is exposed to fluctuations in future electricity prices (day-ahead and real-time) and potential from participating in the wholesale electricity market. We propose a methodology to derive optimal day

Kemner, Ken

423

High-temperature stability, structure and thermoelectric properties of CaMn1xNbxO3 phases  

E-Print Network [OSTI]

technologies such as solid oxide fuel cells, thermoelectric (TE) modules and high-temperature superconductorsHigh-temperature stability, structure and thermoelectric properties of CaMn1Ă?xNbxO3 phases Laura diffraction and electron diffraction data. Thermogravi- metric heating/cooling studies showed a reversible

424

Unusual magnetic hysteresis and the weakened transition behavior induced by Sn substitution in Mn{sub 3}SbN  

SciTech Connect (OSTI)

Substitution of Sb with Sn was achieved in ferrimagnetic antiperovskite Mn{sub 3}SbN. The experimental results indicate that with an increase in Sn concentration, the magnetization continuously decreases and the crystal structure of Mn{sub 3}Sb{sub 1-x}Sn{sub x}N changes from tetragonal to cubic phase at around x of 0.8. In the doping series, step-like anomaly in the isothermal magnetization was found and this behavior was highlighted at x?=?0.4. The anomaly could be attributed to the magnetic frustration, resulting from competition between the multiple spin configurations in the antiperovskite lattice. Meantime, H{sub c} of 18 kOe was observed at x?=?0.3, which is probably the highest among those of manganese antiperovskite materials reported so far. With increasing Sn content, the abrupt change of resistivity and the sharp peak of heat capacity in Mn{sub 3}SbN were gradually weakened. The crystal structure refinements indicate the weakened change at the magnetic transition is close related to the change of c/a ratio variation from tetragonal to cubic with Sn content. The results derived from this study indicate that the behavior of Mn{sub 3}Sb{sub 1-x}Sn{sub x}N could potentially enhance its scientific and technical applications, such as spin torque transfer and hard magnets.

Sun, Ying, E-mail: sunying@buaa.edu.cn [Center for Condensed Matter and Materials Physics, Department of Physics, Beihang University, Beijing 100191 (China); International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science, Tsukuba, Ibaraki 305-0044 (Japan); Guo, Yanfeng; Li, Jun; Wang, Xia [Superconducting Properties Unit, National Institute for Materials Science, Tsukuba, Ibaraki 305-0044 (Japan); Tsujimoto, Yoshihiro [Materials Processing Unit, National Institute for Materials Science, Tsukuba, Ibaraki 305-0047 (Japan); Wang, Cong [Center for Condensed Matter and Materials Physics, Department of Physics, Beihang University, Beijing 100191 (China); Feng, Hai L.; Sathish, Clastin I.; Yamaura, Kazunari, E-mail: yamaura.kazunari@nims.go.jp [Superconducting Properties Unit, National Institute for Materials Science, Tsukuba, Ibaraki 305-0044 (Japan); Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan); Matsushita, Yoshitaka [Analysis Station, National Institute for Materials Science, Tsukuba, Ibaraki 305-0047 (Japan)

2014-01-28T23:59:59.000Z

425

Iron-based soft magnetic composites with MnZn ferrite nanoparticles coating obtained by solgel method  

E-Print Network [OSTI]

­gel method Shen Wu a , Aizhi Sun a,n , Wenhuan Xu a , Qian Zhang a , Fuqiang Zhai a , Philip Logan b , Alex A-ray spectroscopy and distribution maps show that the iron particle surface is covered with a thin layer of Mn compared with the epoxy resin coated samples at 10 kHz. The effects of heat treatment temperature

Volinsky, Alex A.

426

Mineralogical heterogeneities in the Earth's mantle: Constraints from Mn, Co, Ni and Zn partitioning during partial melting  

E-Print Network [OSTI]

Mineralogical heterogeneities in the Earth's mantle: Constraints from Mn, Co, Ni and Zn online 1 June 2011 Editor: L. Stixrude Keywords: transition metals mineralogical heterogeneities are sensitive to changes in mineralogy or major element composition, and thus, are promising to trace

Lee, Cin-Ty Aeolus

427

X-ray magnetic circular dichroism in (Ge,Mn) compounds: experiments and modeling Samuel Tardif,1, 2,  

E-Print Network [OSTI]

X-ray magnetic circular dichroism in (Ge,Mn) compounds: experiments and modeling Samuel Tardif,1, 2: July 29, 2013) X-ray absorption (XAS) and x-ray magnetic circular dichroism (XMCD) spectra at the L2),6 and x-ray spectroscopy (x-ray absorption spec- troscopy, XAS, and x-ray magnetic circular

428

Short-period superlattices of AlN/Al{sub 0.08}Ga{sub 0.92}N grown on AlN substrates  

SciTech Connect (OSTI)

High-quality short-period superlattices of AlN/Al{sub 0.08}Ga{sub 0.92}N have been grown by gas-source molecular-beam epitaxy with ammonia on Al face of AlN (0001) substrates. A significant reduction was achieved in the dislocation density, down to 3x10{sup 8} cm{sup -2}. Complete removal of residual Al{sub 2}O{sub 3} surface oxide is needed in order to obtain low dislocation density in homoepitaxy on AlN. We show that the presence of Al{sub 2}O{sub 3} islands with the surface coverage as low as 0.2% results in increased dislocation density.

Nikishin, S.A.; Borisov, B.A.; Chandolu, A.; Kuryatkov, V.V.; Temkin, H.; Holtz, M.; Mokhov, E.N.; Makarov, Yu.; Helava, H. [Department of Electrical and Computer Engineering and Nano Tech Center, Texas Tech University, Lubbock, Texas 79409-3102 (United States); Nano Tech Center/Department of Physics, Texas Tech University, Lubbock, Texas 79409 (United States); Fox Group Inc., 1154 Stealth Street, Livermore, California 94550 (United States)

2004-11-08T23:59:59.000Z

429

Where Water is Oxidized to Dioxygen: Structure of the Photosynthetic Mn4Ca Cluster from X-ray Spectroscopy  

SciTech Connect (OSTI)

Light-driven oxidation of water to dioxygen in plants, algae and cyanobacteria iscatalyzed within photosystem II (PS II) by a Mn4Ca cluster. Although the cluster has been studied by many different methods, the structure and the mechanism have remained elusive. X-ray absorption and emission spectroscopy and EXAFS studies have been particularly useful in probing the electronic and geometric structure, and the mechanism of the water oxidation reaction. Recent progress, reviewed here, includes polarized X-ray absorption spectroscopy measurements of PS II single crystals. Analysis of those results has constrained the Mn4Ca cluster geometry to a setof three similar high-resolution structures. The structure of the cluster from the present study is unlike either the 3.0 or 3.5 Angstrom-resolution X-ray structures or other previously proposed models. The differences between the models derived from X-rayspectroscopy and crystallography are predominantly because of damage to the Mn4Ca cluster by X-rays under the conditions used for structure determination by X-ray crystallography. X-ray spectroscopy studies are also used for studying the changes in the structure of the Mn4Ca catalytic center as it cycles through the five intermediate states known as the Si-states (i=0-4). The electronic structure of the Mn4Ca cluster has been studied more recently using resonant inelastic X-ray scattering spectroscopy (RIXS), in addition to the earlier X-ray absorption and emission spectroscopy methods. These studies are revealing that the assignment of formaloxidation states is overly simplistic. A more accurate description should consider the charge density on the Mn atoms that includes the covalency of the bonds and delocalization of the charge over the cluster. The geometric and electronic structure of the Mn4Ca cluster in the S-states derived from X-ray spectroscopy are leading to a detailed understanding of the mechanism of the O-O bond formation during the photosynthetic water splitting process.

Yano, Junko; Yano, Junko; Yachandra, Vittal K.

2007-10-24T23:59:59.000Z

430

Al-Ca and Al-Fe metal-metal composite strength, conductivity, and microstructure relationships  

SciTech Connect (OSTI)

Deformation processed metal-metal composites (DMMC’s) are composites formed by mechanical working (i.e., rolling, swaging, or wire drawing) of two-phase, ductile metal mixtures. Since both the matrix and reinforcing phase are ductile metals, the composites can be heavily deformed to reduce the thickness and spacing of the two phases. Recent studies have shown that heavily drawn DMMCs can achieve anomalously high strength and outstanding combinations of strength and conductivity. In this study, Al-Fe wire composite with 0.07, 0.1, and 0.2 volume fractions of Fe filaments and Al-Ca wire composite with 0.03, 0.06, and 0.09 volume fractions of Ca filaments were produced in situ, and their mechanical properties were measured as a function of deformation true strain. The Al-Fe composites displayed limited deformation of the Fe phase even at high true strains, resulting in little strengthening effect in those composites. Al-9vol%Ca wire was deformed to a deformation true strain of 13.76. The resulting Ca second-phase filaments were deformed to thicknesses on the order of one micrometer. The ultimate tensile strength increased exponentially with increasing deformation true strain, reaching a value of 197 MPa at a true strain of 13.76. This value is 2.5 times higher than the value predicted by the rule of mixtures. A quantitative relationship between UTS and deformation true strain was determined. X-ray diffraction data on transformation of Al + Ca microstructures to Al + various Al-Ca intermetallic compounds were obtained at the Advanced Photon Source at Argonne National Laboratory. Electrical conductivity was measured over a range of true strains and post-deformation heat treatment schedules.

Kim, Hyong June

2011-12-01T23:59:59.000Z

431

Commuter airlines at Boston Logan International Airport: 1973-1981  

E-Print Network [OSTI]

Introduction: The adequacy of air transportation in New England has been the subject of intermittent debate-over the last twenty years-, culminating in the Civil Aeronautics Board's 1970-1974 "New England Service Investigation" ...

Ausrotas, Raymond A.

1981-01-01T23:59:59.000Z

432

Thermodynamic and transport properties of single-crystal Yb{sub 14}MnSb{sub 11}  

SciTech Connect (OSTI)

Relatively large (up to 250 mg) single crystals of the intermetallic compound Yb{sub 14}MnSb{sub 11} have been prepared by a flux-growth technique. The results of thermodynamic and transport measurements of these samples are presented. The compound orders ferromagnetically at approximately T{sub C}=53{plus_minus}1K, with a magnetization consistent with the assignment Mn{sup 3+} (3d{sup 4}) and Yb{sup 2+} (4f{sup 14}). The Mn moments are local in nature, with the full effective and saturated moment of the Hund{close_quote}s rule spin-only ground state. The electrical resistivity has a metallic temperature dependence, with only a modest anisotropy. Room-temperature values of the resistivity are relatively high for an intermetallic compound: 1630{plus_minus}160 {mu}{Omega}cm and 1250{plus_minus}130 {mu}{Omega}cm for currents flowing approximately parallel and perpendicular to the {ital c} axis, respectively. There is a distinct loss of spin-disorder scattering in the resistivity at T{sub C}. From the heat capacity, a rough estimation of the magnetic entropy gives {Delta}S{sub M}{approx}12.1 J/mol K, the value in reasonable agreement with the expected {Delta}S{sub M}{approx}R ln 5 from the assignment of these moments. All of these data are consistent with a picture of Mn{sup 3+} local moments being coupled via conduction electrons. To this end, Yb{sub 14}MnSb{sub 11} appears to be analogous to local-moment rare-earth intermetallic compounds, and may point the way toward a class of 3d Kondo lattice compounds. {copyright} {ital 1999} {ital The American Physical Society}

Fisher, I.R.; Wiener, T.A.; Budko, S.L.; Canfield, P.C. [Ames Laboratory and Department of Physics and Astronomy, Iowa State University, Ames, Iowa 50011 (United States)] [Ames Laboratory and Department of Physics and Astronomy, Iowa State University, Ames, Iowa 50011 (United States); Chan, J.Y.; Kauzlarich, S.M. [Department of Chemistry, One Shields Avenue, University of California, Davis, California 95616 (United States)] [Department of Chemistry, One Shields Avenue, University of California, Davis, California 95616 (United States)

1999-06-01T23:59:59.000Z

433

Unraveling the voltage fade mechanism in layer Li-Mn-rich electrode: formation of the tetrahedral cations for spinel conversion  

SciTech Connect (OSTI)

Discovery of high-voltage layered lithium-and manganese-rich (LMR) composite oxide electrode has dramatically enhanced the energy density of current Li-ion energy storage systems. However, practical usage of these materials is currently not viable because of their inability to maintain a consistent voltage profile (voltage fading) during subsequent charge-discharge cycles. This report rationalizes the cause of this voltage fade by providing the evidence of layer to spinel-like (LSL) structural evolution pathways in the host Li1.2Mn0.55Ni0.15Co0.1O2 LMR composite oxide. By employing neutron powder diffraction, and temperature dependent magnetic susceptibility, we show that LSL structural rearrangement in LMR oxide occurs through a tetrahedral cation intermediate via: i) diffusion of lithium atoms from octahedral to tetrahedral sites of the lithium layer [(LiLioct LiLitet] which is followed by the dispersal of the lithium ions from the adjacent octahedral site of the metal layer to the tetrahedral sites of lithium layer [LiTM oct LiLitet]; and ii) migration of Mn from the octahedral sites of the transition metal layer to the permanent octahedral site of lithium layer via tetrahedral site of lithium layer [MnTMoct MnLitet MnLioct)]. The findings opens the door to the potential routes to mitigate this atomic restructuring in the high-voltage LMR composite oxide cathodes by manipulating the composition/structure for practical use in high-energy-density lithium-ion batteries.

Mohanty, Debasish [ORNL; Li, Jianlin [ORNL; Abraham, Daniel P [Argonne National Laboratory (ANL); Huq, Ashfia [ORNL; Payzant, E Andrew [ORNL; Wood III, David L [ORNL; Daniel, Claus [ORNL

2014-01-01T23:59:59.000Z

434

Facile synthesis of {alpha}-MnO{sub 2} one-dimensional (1D) nanostructure and energy storage ability studies  

SciTech Connect (OSTI)

The dense manganese oxide nanorods with an extremely narrow distribution are synthesized at a low temperature using first cathodic electrodeposition subsequently heat treatment. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) images show that the nanorods have bar shapes, and their average diameter is less than 50 nm. The Fourier transform infrared (FT-IR) study, the selected area electron diffraction (SAED) pattern in TEM images and the X-ray diffraction (XRD) result show that the nanorods are {alpha}-MnO{sub 2} single crystal. The results of N{sub 2} adsorption-desorption analysis indicate that the BET surface area of the {alpha}-MnO{sub 2} nanorods is 93 m{sup 2} g{sup -1}. By recording the potential-time curve during the electrodeposition process, it is revealed that water reduction reaction has a major role in the electrogeneration of base at the cathode surface under the applied electrochemical conditions. Finally, based on the H{sub 2} bubbling on the cathode surface, the mechanism of the formation and the growth of {alpha}-MnO{sub 2} nanorods are proposed and discussed. For the electrochemical supercapacitor application, electrochemically prepared {alpha}-MnO{sub 2} is found to be stable for a large number of cycles with high specific capacitance, 338 F g{sup -1} at a scan rate of 10 mV s{sup -1}. Finally, the charge-discharge mechanism is discussed. - Graphical abstract: Highlights: Black-Right-Pointing-Pointer New nanostructures of MnO{sub 2} is synthesized by simple method of cathodicelectrodeposition. Black-Right-Pointing-Pointer The product has unique one-dimensional morphology with average diameter size of 50 nm. Black-Right-Pointing-Pointer The experiment conditions (temperature, current density) has not been reported. Black-Right-Pointing-Pointer The one-nanostructures obtained without using of hard template or surfactant.

Yousefi, Taher, E-mail: anozadg@yahoo.com [Department of Chemistry, Tarbiat Moallem University, PO Box: 31979-37551, Tehran (Iran, Islamic Republic of); Materials Research School, NSTRI, PO Box: 14395-836, Tehran (Iran, Islamic Republic of); Golikand, Ahmad Nozad, E-mail: taher_yosefy@yahoo.com [Materials Research School, NSTRI, PO Box: 14395-836, Tehran (Iran, Islamic Republic of); Hossein Mashhadizadeh, Mohammad [Department of Chemistry, Tarbiat Moallem University, PO Box: 31979-37551, Tehran (Iran, Islamic Republic of); Aghazadeh, Mustafa [Department of Optic and Spectroscopy, Lasers and Optics Research School, NSTRI, PO Box: 11365-8486, Tehran (Iran, Islamic Republic of)

2012-06-15T23:59:59.000Z

435

Polarized X-Ray Absorption Spectroscopy of Single-Crystal Mn(V) Complexes Relevant to the Oxygen-Evolving Complex of Photosystem II  

SciTech Connect (OSTI)

High-valent Mn-oxo species have been suggested to have a catalytically important role in the water splitting reaction which occurs in the Photosystem II membrane protein. In this study, five- and six-coordinate mononuclear Mn(V) compounds were investigated by polarized X-ray absorption spectroscopy in order to understand the electronic structure and spectroscopic characteristics of high-valent Mn species. Single crystals of the Mn(V)-nitrido and Mn(V)-oxo compounds were aligned along selected molecular vectors with respect to the X-ray polarization vector using X-ray diffraction. The local electronic structure of the metal site was then studied by measuring the polarization dependence of X-ray absorption near-edge spectroscopy (XANES) pre-edge spectra (1s to 3d transition) and comparing with the results of density functional theory (DFT) calculations. The Mn(V)-nitrido compound, in which the manganese is coordinated in a tetragonally distorted octahedral environment, showed a single dominant pre-edge peak along the MnN axis that can be assigned to a strong 3dz2-4pz mixing mechanism. In the square pyramidal Mn(V)-oxo system, on the other hand, an additional peak was observed at 1 eV below the main pre-edge peak. This component was interpreted as a 1s to 3dxz,yz transition with 4px,y mixing, due to the displacement of the Mn atom out of the equatorial plane. The XANES results have been correlated to DFT calculations, and the spectra have been simulated using a TD (time-dependent)-DFT approach. The relevance of these results to understanding the mechanism of the photosynthetic water oxidation is discussed.

Yano, J.K.; Robblee, J.; Pushkar, Y.; Marcus, M.A.; Bendix, J.; Workman, J.M.; Collins, T.J.; Solomon, E.I.; George, S.D.; Yachandra, V.K.; /LBL, Berkeley /Copenhagen U. /Stanford U., Chem. Dept. /SLAC, SSRL

2007-10-16T23:59:59.000Z

436

Microsoft Word - AL2005-03.doc  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department ofT ib l L d F S i DOE Tribal Leader HOWARD8-04 (02/21/08) 1 AcquisitionAL

437

Microsoft Word - AL2006-10.doc  

Energy Savers [EERE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of Inspector General Office0-72.pdfGeorgeDoesn't32 Master EM ManagementWe2.docAL-2006-10 Acquisition Regulation

438

Category:Montgomery, AL | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of InspectorConcentrating SolarElectricEnergyCTBarreis aCallahanWind FarmAdd aMinutes JumpMissing RequiredAL

439

ALS Reveals New State of Matter  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert SouthwestTechnologies |November 2011Astudies smartHistory: The First 20ALS Reveals New

440

ALS Reveals New State of Matter  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert SouthwestTechnologies |November 2011Astudies smartHistory: The First 20ALS Reveals

Note: This page contains sample records for the topic "mn al 1970-1974" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Summary Slides of ALS Science Highlights  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security AdministrationcontrollerNanocrystalline Gallium OxideSumin Kim Sumin Kim Sumin KimSummary Slides of ALS

442

A=17Al (1993TI07)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04) (See93TI07)7AJ02) (See1982AJ01)86AJ04)Al

443

ALS Ceramics Materials Research Advances Engine Performance  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07)Operations During theALS CapabilitiesALSALSALSALSALS

444

ALS Ceramics Materials Research Advances Engine Performance  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07)Operations During theALS

445

ALS History: The First 20 Years  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07)Operations DuringALS Doctoral Fellowship

446

ALS Operating Schedule on Google Calendar  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07)Operations DuringALS Doctoral FellowshipALSALS

447

ALS Reveals New State of Matter  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07)Operations DuringALS Doctoral FellowshipALSALSALS

448

ALS Reveals New State of Matter  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07)Operations DuringALS Doctoral FellowshipALSALSALSALS

449

ALS Reveals New State of Matter  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07)Operations DuringALS Doctoral

450

al ruido industrial: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: .5% absolute 2 compared to conventional aluminum back surface field (Al-BSF) solar cells. The main effect SINGULAR In the recent years, aluminum oxide (AlOx) layers...

451

Data Transfer Considerations for ALS Scientists and Users  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Data Transfer Considerations for ALS Scientists and Users Print Introduction Working at the ALS generates huge amounts of data, and for many years this has caused users to have to...

452

Slow Orbit Feedback at the ALS Using Matlab  

E-Print Network [OSTI]

Ring Setup and Control Using MatlabŽ," LSAP Note #248, JuneFeedback at the ALS Using Matlab G_ Port mann Advanced LightFEEDBACK AT THE ALS USING MATLAB* G. Portmann Advanced Light

Portmann, G.

2011-01-01T23:59:59.000Z

453

al coated a2: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2 AlTiN layer effect on mechanical properties of Ti-doped diamond-like carbon composite coatings Engineering Websites Summary: AlTiN layer effect on mechanical properties...

454

al tratamiento nutricional: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

defects andEffects of point defects and impurities on kinetics in NaAlHimpurities on kinetics in NaAlH44 Energy Storage, Conversion and Utilization Websites Summary: Nsites...

455

Instability, intermixing and electronic structure at theepitaxialLaAl...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

intermixing and electronic structure at the epitaxialLaAlO3SrTiO3(001) heterojunction. Instability, intermixing and electronic structure at the epitaxialLaAlO3...

456

Plagiarism in Linguistic Editing Dr. Ismael Al-Qayam  

E-Print Network [OSTI]

Plagiarism in Linguistic Editing Abstract Dr. Ismael Al-Qayam Philadelphia University This paper Lughawiyya is plagiarized from a number of former linguists, especially Mohammed Al Adnani and Mohammed Dhari

457

Cisco Systems Funds "Whisker" Growth Research at the ALS  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Cisco Systems Funds "Whisker" Growth Research at the ALS Cisco Systems Funds "Whisker" Growth Research at the ALS Print Friday, 09 November 2012 10:06 Lead-free components have...

458

Magneto-transport in LaTi{sub 1?x}Mn{sub x}O{sub 3}/SrTiO{sub 3} oxide heterostructures  

SciTech Connect (OSTI)

We report the growth of ultrathin film of Mn doped LaTiO{sub 3} on TiO{sub 2} terminated SrTiO{sub 3} (001) substrate by pulsed laser deposition (PLD) and their electrical transport characteristics including magnetoresistance (MR). Though the replacement of Mn in LaTiO{sub 3} at the Ti site in dilute limit does not affect the metallic behaviour of films but variation in resistance is observed. Normalised resistance behaviour is explained on the basis of variation in charge carriers and increased interaction between Mn atoms in the system under investigation.

Kumar, Pramod, E-mail: pramodnpl2011@gmail.com; Dogra, Anjana, E-mail: pramodnpl2011@gmail.com; Budhani, R. C., E-mail: pramodnpl2011@gmail.com [Quantum Phenomena and Applications Division, National Physical Laboratory (CSIR), Dr. K.S. Krishnan Marg, New Delhi-110012 (India)

2014-04-24T23:59:59.000Z

459

LiMnPO4 Nanoplate Grown via Solid-State Reaction in Molten Hydrocarbon for Li-ion Battery Cathode  

SciTech Connect (OSTI)

Electrochemically active LiMnPO4 nanoplates have been synthesized via novel single step solid state reaction in molten hydrocarbon. The LiMnPO4 prepared show unique porous nanoplate shape ~50nm in thickness with highly preferred crystallographic orientation. The reversible cycling of carbon coated LiMnPO4 show flat potential at 4.1 V vs. Li with specific capacity reaching up to 168mAh/g and excellent cycling performance using only galvanostatic charging / discharging mode.

Choi, Daiwon; Wang, Donghai; Bae, In-Tae; Xiao, Jie; Nie, Zimin; Wang, Wei; Viswanathan, Vilayanur V.; Lee, Yun Jung; Zhang, Jiguang; Graff, Gordon L.; Yang, Zhenguo; Liu, Jun

2010-08-11T23:59:59.000Z

460

Electronic Structure of the Mn(4)Ca Cluster in the Oxygen-Evolving Complex of Photosystem Ii Studied By Resonant Inelastic X-Ray Scattering  

SciTech Connect (OSTI)

Oxygen-evolving complex (Mn{sub 4}Ca cluster) of Photosystem II cycles through five intermediate states (S{sub i}-states, i=0--4) before a molecule of dioxygen is released. During the S-state transitions, electrons are extracted from the OEC, either from Mn or alternatively from a Mn ligand. The oxidation state of Mn is widely accepted as Mn{sub 4}(III{sub 2},IV{sub 2}) and Mn{sub 4}(III,IV{sub 3}) for S{sub 1} and S{sub 2} states, while it is still controversial for the S{sub 0} and S{sub 3} states. We used resonant inelastic X-ray scattering (RIXS) to study the electronic structure of Mn{sub 4}Ca complex in the OEC. The RIXS data yield two-dimensional plots that provide a significant advantage by obtaining both K-edge pre-edge and L-edge-like spectra simultaneously. The second energy dimension separates the pre-edge (1s to 3d) transitions from the main K-edge (1s to 4p), and thus more precise analysis is possible. The 1s2p RIXS final state electron configuration along the energy transfer axis is identical to conventional L-edge absorption spectroscopy and the RIXS spectra are therefore sensitive to the metal spin state. We have collected data from PS II samples in the each of the S-states and compared them with data from various inorganic Mn complexes. The spectral changes in the Mn 1s2p{sub 3/2} RIXS spectra between the S-states are small compared to those of the oxides of Mn and coordination complexes. The results indicate strong covalency for the electronic configuration in the OEC, and we conclude that the electron is transferred from a strongly delocalized orbital, compared to those in Mn oxides or coordination complexes. The magnitude for the S{sub 0} to S{sub 1}, and S{sub 1} to S{sub 2} transitions is twice as large as that during the S{sub 2} to S{sub 3} transition, indicating that the electron for this transition is extracted from a highly delocalized orbital with little change in charge density at the Mn atoms. The RIXS spectra of S{sub 0} and S{sub 3} states also showed characteristic features which were not clear from the K-edge spectroscopy.

Yano, J.; Pushkar, Y.; Messinger, J.; Bergmann, U.; Glatzel, P.; Yachandra, V.K.

2009-06-04T23:59:59.000Z

Note: This page contains sample records for the topic "mn al 1970-1974" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Heteroepitaxial growth and surface structure of L1{sub 0}-MnGa(111) ultra-thin films on GaN(0001)  

SciTech Connect (OSTI)

L1{sub 0}-structured MnGa(111) ultra-thin films were heteroepitaxially grown on GaN(0001) under lightly Mn-rich conditions using molecular beam epitaxy. Room-temperature scanning tunneling microscopy (STM) investigations reveal smooth terraces and angular step edges, with the surface structure consisting primarily of a 2 × 2 reconstruction along with small patches of 1 × 2. Theoretical calculations were carried out using density functional theory, and the simulated STM images were calculated using the Tersoff-Hamman approximation, revealing that a stoichiometric 1 × 2 and a Mn-rich 2 × 2 surface structure give the best agreement with the observed experimental images.

Mandru, Andrada-Oana; Wang, Kangkang; Cooper, Kevin; Ingram, David C.; Smith, Arthur R. [Department of Physics and Astronomy, Nanoscale and Quantum Phenomena Institute, Ohio University, Athens, Ohio 45701 (United States)] [Department of Physics and Astronomy, Nanoscale and Quantum Phenomena Institute, Ohio University, Athens, Ohio 45701 (United States); Garcia Diaz, Reyes; Takeuchi, Noboru [Department of Physics and Astronomy, Nanoscale and Quantum Phenomena Institute, Ohio University, Athens, Ohio 45701 (United States) [Department of Physics and Astronomy, Nanoscale and Quantum Phenomena Institute, Ohio University, Athens, Ohio 45701 (United States); Centro de Nanociencias y Nanotecnologia, Universidad Nacional Autónoma de México, Apartado Postal 14, Ensenada Baja California, Codigo Postal 22800 (Mexico); Haider, Muhammad [Department of Physics and Astronomy, Nanoscale and Quantum Phenomena Institute, Ohio University, Athens, Ohio 45701 (United States) [Department of Physics and Astronomy, Nanoscale and Quantum Phenomena Institute, Ohio University, Athens, Ohio 45701 (United States); Department of Physics, King Fahd University of Petroleum and Minerals, Dhahran, 31261 (Saudi Arabia)

2013-10-14T23:59:59.000Z

462

Structure and Magnetic Ordering of a 2-D MnII(TCNE)I(OH2) (TCNE = tetracyanoethylene) Organic-based Magnet (Tc = 171 K)  

SciTech Connect (OSTI)

Mn{sup II}(TCNE)I(OH{sub 2}) was isolated from the reaction of tetracyanoethylene (TCNE) and MnI{sub 2}(THF){sub 3}, and has a 2-D structure possessing an unusual, asymmetric bonded {mu}{sub 4}-[TCNE]{sup {sm_bullet}-}. Direct antiferromagnetic coupling between the S = 5/2 Mn{sup II} and S = 1/2 [TCNE]{sup {sm_bullet}-} leads to magnetic ordering as a canted antiferromagnet at a T{sub c} of 171 K.

S Lapidus; A McConnell; P Stephens; J Miller

2011-12-31T23:59:59.000Z

463

Energy localization on the Al sublattice of Pt3Al with L12 order  

SciTech Connect (OSTI)

A three-dimensional molecular-dynamics model of with order was developed and found to support the excitation of discrete breathers (DBs) and energy localization on the Al sublattice. For an initial lattice temperature of 0 K, large-amplitude DBs polarized along [100] are found to be very weakly damped, retaining most of their initial energy for more than 2000 cycles, while DBs polarized along [111] damped out over ~30 cycles. Because the DBs and their dissipation channels are confined to the Al sublattice, long-lived nonequilibrium states with large energy differences between the Al and Pt sublattices occur. Since collisions during irradiation more efficiently generate lattice vibrations in light atoms than heavy atoms, such nonequilibrium states may occur and alter the relaxation processes occurring during radiation damage.

Medvedev, Nikolay N [Altay State Technical University, Russia] [Altay State Technical University, Russia; Starostenkov, Mikhail D [Altay State Technical University, Russia] [Altay State Technical University, Russia; Manley, Michael E [ORNL] [ORNL

2013-01-01T23:59:59.000Z

464

als medium von: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Information Technology) Prof. Dr. Andreas Rausch (Software Systems Engineering Zachmann, Gabriel 7 Bachelorarbeit Integration von PDF-Formularen als Multidisciplinary...

465

als homologem von: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Information Technology) Prof. Dr. Andreas Rausch (Software Systems Engineering Zachmann, Gabriel 7 Bachelorarbeit Integration von PDF-Formularen als Multidisciplinary...

466

als folge von: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Information Technology) Prof. Dr. Andreas Rausch (Software Systems Engineering Zachmann, Gabriel 12 Bachelorarbeit Integration von PDF-Formularen als Multidisciplinary...

467

E-Print Network 3.0 - als zuschnittselemente abschlussbericht...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

als Projekt. Eine... in Agrarintensivregionen (PartizipA). Abschlussbericht des deutsch- sterreichischen Verbundprojekts. Beitrge des... Landwirtschaft und Ernhrung:...

468

Metastable phase diagram for Ni-implanted Al and pulse surface melted Al(Ni)  

SciTech Connect (OSTI)

The microstructure of <110> Al implanted with Ni was examined before and after subsequent electron beam pulsed surface melting (65 ns, 1.7 J/cm/sup 2/). Both processes were done with the Al substrate at room temperature. Implantation at several energies (160 to 15 keV) into a given sample produced a nearly constant measured Ni concentration through a approx. 0.1 ..mu..m region below the surface (7). Such samples with concentrations from 8 to 25 at. % Ni were examined, along with a sample with a peak concentration of 32 at. % Ni.

Follstaedt, D.M.; Picraux, S.T.

1984-01-01T23:59:59.000Z

469

Constraining oceanic dust deposition using surface ocean dissolved Al  

E-Print Network [OSTI]

Constraining oceanic dust deposition using surface ocean dissolved Al Qin Han,1 J. Keith Moore,1; accepted 7 December 2007; published 12 April 2008. [1] We use measurements of ocean surface dissolved Al (DEAD) model to constrain dust deposition to the oceans. Our Al database contains all available

Zender, Charles

470

Ahmad Salim, Salam Zummo, and Samir Al-Presented by  

E-Print Network [OSTI]

Ahmad Salim, Salam Zummo, and Samir Al- Ghadhban Presented by: Department of Electrical Engineering direction and increases the SNR in that direction. 8 #12; [Wolniansky et al, 1998] proposed VBLAST, in which with one Tx and two Rx antennas. In [Tao et al, 2001] a combination of BLAST and STC was implemented which

Al-Ghadhban, Samir

471

Department of Business Administration Samir Aziz Alaiwy Al-Abbadi  

E-Print Network [OSTI]

Department of Business Administration Samir Aziz Alaiwy Al-Abbadi P.O. Box:1 Philadelphia. Samir Aziz Alaiwy Al-Abbadi Date of Birth : 1949 Academic Qualification ¡ B.Sc Business Administration - 1975 ­ Al- Mustansiryah University ­ Iraq ¡ M.B.A Business Administration (Production / Operations

472

Aluminum sulfate (alum; Al2 O) is used as a  

E-Print Network [OSTI]

477 Aluminum sulfate (alum; Al2 (SO4 )3 ¡14H2 O) is used as a chemical treatment of poultry litter litters showed that the P is present in inorganic (P sorbed on Al oxides, calcium phosphates) and organic increases. Overall, alum-amended litters exhibited higher proportions of Al-bound P species and phytic acid

Sparks, Donald L.

473

Graeber et al. 2014 1 Supporting Information (SI Appendix)  

E-Print Network [OSTI]

Graeber et al. 2014 1 Supporting Information (SI Appendix) Graeber et al. (2014) - www for the temperature- and gibberellin-dependent control of seed germination Kai Graeber, Ada Linkies, Tina Steinbrecher17 and WT #12;Graeber et al. 2014 2 Supplementary Methods Genome Size Analysis by Flow Cytometry

Chittka, Lars

474

Ordnung fr die Studienbegleitende Ausbildung Deutsch als Zweitsprache  

E-Print Network [OSTI]

Ordnung fßr die Studienbegleitende Ausbildung Deutsch als Zweitsprache an der Universität Literaturwissenschaften der Universität Regensburg bietet die studienbegleitende Ausbildung Deutsch als Zweitsprache (im Fachbereichs Deutschs als Zweitsprache zu einer Unterrichtstätigkeit in diesem Bereich zu befähigen. (3) 1 Die

Schubart, Christoph

475

Corrosion of Bare and Coated Al 5052-H3 and Al 6061-T6 in Seawater Work sponsored by  

E-Print Network [OSTI]

1 Corrosion of Bare and Coated Al 5052-H3 and Al 6061-T6 in Seawater Work sponsored by: US and Kentaro Kusada Hawaii Corrosion Laboratory Department of Mechanical Engineering College of Engineering

476

13. B. E. Baysal et al., Genomics 44, 214 (1997); P. Deloukas et al., Science 282, 744 (1998).  

E-Print Network [OSTI]

. Kelleher, M. Hoeckel, Strahlenther. Onkol. 174, Suppl. 4, 6 (1998). 30. T. G. Graeber et al., Nature 379

Ulanovsky, Nachum

477

Oxygen reduction at a stabilized zirconia interface with Y[sub 1-x]Ca[sub x]MnO[sub 3] or La[sub 1-x]Sr[sub x]MnO[sub 3] cathode materials  

SciTech Connect (OSTI)

Impedance spectroscopy, combined with an unbonded interface cell, has been used to assess oxygen reduction behavior at interfaces between an yttria-stabilized zirconia electrolyte and perovskite or platinum cathode materials. Intrinsic oxygen reduction specific activities of Y[sub 1-x]Ca[sub x]MnO[sub 3] (x = 0.5, 0.6 and 0.7) and La[sub 1-x]Sr[sub x]MnO[sub 3] (x = 0.1 and 0.3) were determined as a function of temperature and oxygen partial pressure, independent of the interface morphology. The overall cathodic interfacial polarization consists of two or more fundamental processes. In the temperature range of 900--1000C and in air, the operating conditions for a solid oxide fuel cell, charge transfer and oxygen dissociation processes were approximately equivalent relative to the overall oxygen reduction kinetics.

Youngblood, G.E.; Pederson, L.R.; Bates, J.L. (Pacific Northwest Lab., Richland, WA (United States)); Rupaal, A.S. (Western Washington Univ., Bellingham, WA (United States))

1993-05-01T23:59:59.000Z

478

Oxygen reduction at a stabilized zirconia interface with Y{sub 1-x}Ca{sub x}MnO{sub 3} or La{sub 1-x}Sr{sub x}MnO{sub 3} cathode materials  

SciTech Connect (OSTI)

Impedance spectroscopy, combined with an unbonded interface cell, has been used to assess oxygen reduction behavior at interfaces between an yttria-stabilized zirconia electrolyte and perovskite or platinum cathode materials. Intrinsic oxygen reduction specific activities of Y{sub 1-x}Ca{sub x}MnO{sub 3} (x = 0.5, 0.6 and 0.7) and La{sub 1-x}Sr{sub x}MnO{sub 3} (x = 0.1 and 0.3) were determined as a function of temperature and oxygen partial pressure, independent of the interface morphology. The overall cathodic interfacial polarization consists of two or more fundamental processes. In the temperature range of 900--1000C and in air, the operating conditions for a solid oxide fuel cell, charge transfer and oxygen dissociation processes were approximately equivalent relative to the overall oxygen reduction kinetics.

Youngblood, G.E.; Pederson, L.R.; Bates, J.L. [Pacific Northwest Lab., Richland, WA (United States); Rupaal, A.S. [Western Washington Univ., Bellingham, WA (United States)

1993-05-01T23:59:59.000Z

479

Magnetization anomaly of Nb3Al strands and instability of Nb3Al Rutherford cables  

SciTech Connect (OSTI)

Using a Cu stabilized Nb{sub 3}Al strand with Nb matrix, a 30 meter long Nb{sub 3}Al Rutherford cable was made by a collaboration of Fermilab and NIMS. Recently the strand and cable were tested. In both cases instability was observed at around 1.5 Tesla. The magnetization of this Nb{sub 3}Al strand was measured first using a balanced coil magnetometer at 4.2 K. Strands showed an anomalously large magnetization behavior around at 1.6 T, which is much higher than the usual B{sub c2} {approx} 0.5 Tesla (4.2 K) of Nb matrix. This result is compared with the magnetization data of short strand samples using a SQUID magnetometer, in which a flux-jump signal was observed at 0.5 Tesla, but not at higher field. As a possible explanation for this magnetization anomaly, the interfilament coupling through the thin Nb films in the strands is suggested. The instability problem observed in low field tests of the Nb{sub 3}Al Rutherford cables is attributed to this effect.

Yamada, Ryuji; /Fermilab; Kikuchi, Akihiro; /Tsukuba Magnet Lab; Wake, Masayoshi; /KEK, Tsukuba

2006-08-01T23:59:59.000Z

480

Room-temperature photomagnetism in the spinel ferrite (Mn,Zn,Fe)3O4 as seen via soft x-ray magnetic circular dichroism  

E-Print Network [OSTI]

photomagnetism in the spinel ferrite (Mn,Zn,Fe)3O4 as seendoped garnets 1 , doped spinel ferrites 2 , doped perovskiteIn the doped garnets and ferrites, the microscopic origin of

Bettinger, J.S.

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mn al 1970-1974" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Mon. Not. R. Astron. Soc. 000, 1?? (2002) Printed 3 November 2011 (MN LATEX style file v2.2) A generalised porosity formalism for isotropic and  

E-Print Network [OSTI]

the first X-ray line profiles computed directly from line-driven instability simulations using a 3-D patchMon. Not. R. Astron. Soc. 000, 1­?? (2002) Printed 3 November 2011 (MN LATEX style file v2

Cohen, David

482

Comparison of Small Polaron Migration and Phase Separation in Olivine LiMnPO? and LiFePO? using Hybrid Density Functional Theory  

E-Print Network [OSTI]

Using hybrid density functional theory based on the Heyd-Scuseria-Ernzerhof (HSE06) functional, we compared polaron migration and phase separation in olivine LiMnPO? to LiFePO?. The barriers for free hole and electron ...

Ong, Shyue Ping

483

Effect of ball milling and post-annealing on magnetic properties of Ni49.8Mn28.5Ga21.7 alloy powders  

E-Print Network [OSTI]

, The University of Western Australia, Crawley WA6009, Australia c Department of Advanced Materials mechanical energy absorption [8,9]. Ni­Mn­Ga powders have been prepared by various methods, including spark

Zheng, Yufeng

484

doi:10.1016/j.gca.2005.03.018 Natural speciation of Mn, Ni, and Zn at the micrometer scale in a clayey paddy soil using  

E-Print Network [OSTI]

, Berkeley, CA 94720, USA 6 Department of Agricultural Chemistry, National Taiwan University, Taipei, Taiwan-supporting clay film from the 2 m fraction of the soil. Manganese was concentrated in Fe-Mn soft mottles (44.4 g

485

Electroluminescence of InGaAs/GaAs quantum-size heterostructures with (III, Mn)V and Ni ferromagnetic injectors  

SciTech Connect (OSTI)

Electroluminescence characteristics of light-emitting diodes based on InGaAs/GaAs quantum well heterostructures with an injector layer made of ferromagnetic metal (Ni), semimetal compound (MnSb), or magnetic semiconductor (InMnAs) were comparatively studied. The general feature is electroluminescence quenching as the spacer layer thickness between a quantum well and a magnetic injector decreases. It was found that the temperature dependence of the electroluminescence in diodes with Ni and MnSb is caused by thermal ejection of carriers from the quantum well; in diodes with InMnAs, it is caused by the temperature dependence of the carrier concentration in magnetic semiconductor and thermal ejection of carriers from the quantum well in the high-temperature region.

Prokof'eva, M. M., E-mail: marinaprkfeva@rambler.ru [Lobachevsky State University (Russian Federation); Dorokhin, M. V.; Danilov, Yu. A.; Kudrin, A. V.; Vikhrova, O. V. [Lobachevsky State University of Nizhni Novgorod, Physicotechnical Research Institute (Russian Federation)

2010-11-15T23:59:59.000Z

486

X-ray and neutron scattering studies of the Rb?MnF? and Cu?â??őxMgxĚłGeO? in an external magnetic field  

E-Print Network [OSTI]

This thesis presents results of two scattering studies of low dimensional magnetic materials. The first is a neutron scattering study of Rb2MnF4, a nearly ideal two-dimensional square lattice Heisenberg antiferromagnet ...

Christianson, Rebecca J. (Rebecca Jean), 1973-

2001-01-01T23:59:59.000Z

487

Combustion Synthesis of Nanoparticulate LiMgxMn1-xPO4 (x=0, 0.1, 0.2) Carbon Composites  

E-Print Network [OSTI]

G. J. Exarhos: Glycine-nitrate Combustion Synthesis of Oxideby the Nitrate-Citrate Combustion Method. Mat. Res. Bull.Combustion Synthesis of Nanoparticulate LiMg x Mn 1-x PO 4 (

Doeff, Marca M

2010-01-01T23:59:59.000Z

488

Bicolor Mn-doped CuInS{sub 2}/ZnS core/shell nanocrystals for white light-emitting diode with high color rendering index  

SciTech Connect (OSTI)

We synthesized bicolor Mn-doped CuInS{sub 2} (CIS)/ZnS core/shell nanocrystals (NCs), in which Mn{sup 2+} ions and the CIS core were separated with a ZnS layer, and both Mn{sup 2+} ions and CIS cores could emit simultaneously. Transmission electron microscopy and powder X-ray diffraction measurements indicated the epitaxial growth of ZnS shell on the CuInS{sub 2} core, and electron paramagnetic resonance spectrum indicated that Mn{sup 2+} ions were on the lattice points of ZnS shell. By integrating these bicolor NCs with commercial InGaN-based blue-emitting diodes, tricolor white light-emitting diodes with color rendering index of 83 were obtained.

Huang, Bo; Dai, Qian; Zhang, Huichao; Liao, Chen; Cui, Yiping; Zhang, Jiayu, E-mail: jyzhang@seu.edu.cn [Advanced Photonic Center, Southeast University, Nanjing 210096 (China); Zhuo, Ningze; Jiang, Qingsong; Shi, Fenghua; Wang, Haibo [Research Institute of Electric Light Source Materials, Nanjing University of Technology, Nanjing 210015 (China)

2014-09-07T23:59:59.000Z

489

Formation of Nb/sub 3/Al in powder processed Nb-Al superconductors  

SciTech Connect (OSTI)

In high magnetic fields, the critical current density is strongly dependent on the upper critical field, which is determined primarily by the stoichiometry of the Nb/sub 3/Al. The critical temperature (T/sub c/), like the upper critical field, is considered to be a measure of the ''intrinsic'' quality of the superconductor, indicating the stoichiometry, order, and strain. If the A15 phase is stoichiometric and well ordered, a high T/sub c/ (and high H/sub C/sub 2//) is expected, regardless of the volume fraction of superconductor. On the other hand, if sigma phase is present with the A15, the resultant composition gradient across the sigma-A15 interface(s) requires that some of the A15 be off-stoichiometric, and therefore that the T/sub c/ (and H/sub C/sub