National Library of Energy BETA

Sample records for mixed waste storage

  1. Settlement Agreement on TRU Mixed Waste Storage at Nevada Test...

    Office of Environmental Management (EM)

    Settlement Agreement for Transuranic (TRU) Mixed Waste Storage Issues at the Nevada Test Site (NTS) State Nevada Agreement Type Settlement Agreement Legal Driver(s) RCRA Scope ...

  2. EA-0820: Construction of Mixed Waste Storage RCRA Facilities, Buildings 7668 and 7669, Oak Ridge, Tennessee

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts of a proposal to construct and operate two mixed (both radioactive and hazardous) waste storage facilities (Buildings 7668 and 7669) in accordance with...

  3. Supplemental design requirements document enhanced radioactive and mixed waste storage Phase V Project W-112

    SciTech Connect (OSTI)

    Ocampo, V.P.; Boothe, G.F.; Greager, T.M.; Johnson, K.D.; Kooiker, S.L.; Martin, J.D.

    1994-11-01

    This document provides additional and supplemental information to WHC-SD-W112-FDC-001, Project W-112 for radioactive and mixed waste storage. It provides additional requirements for the design and summarizes Westinghouse Hanford Company key design guidance and establishes the technical baseline agreements to be used for definitive design of the Project W-112 facilities.

  4. EA-0981: Solid Waste Retrieval Complex, Enhanced Radioactive and Mixed Waste Storage Facility, Infrastructure Upgrades, and Central Waste Support Complex, Hanford Site, Richland, Washington

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts of the proposal to retrieve transuranic waste (TRU), provide storage capacity for retrieved and newly generated TRU, Greater-than-Category 3, and mixed...

  5. Mixed waste: Proceedings

    SciTech Connect (OSTI)

    Moghissi, A.A.; Blauvelt, R.K.; Benda, G.A.; Rothermich, N.E.

    1993-12-31

    This volume contains the peer-reviewed and edited versions of papers submitted for presentation a the Second International Mixed Waste Symposium. Following the tradition of the First International Mixed Waste Symposium, these proceedings were prepared in advance of the meeting for distribution to participants. The symposium was organized by the Mixed Waste Committee of the American Society of Mechanical Engineers. The topics discussed at the symposium include: stabilization technologies, alternative treatment technologies, regulatory issues, vitrification technologies, characterization of wastes, thermal technologies, laboratory and analytical issues, waste storage and disposal, organic treatment technologies, waste minimization, packaging and transportation, treatment of mercury contaminated wastes and bioprocessing, and environmental restoration. Individual abstracts are catalogued separately for the data base.

  6. SAVANNAH RIVER SITE INCIPIENT SLUDGE MIXING IN RADIOACTIVE LIQUID WASTE STORAGE TANKS DURING SALT SOLUTION BLENDING

    SciTech Connect (OSTI)

    Leishear, R.; Poirier, M.; Lee, S.; Steeper, T.; Fowley, M.; Parkinson, K.

    2011-01-12

    This paper is the second in a series of four publications to document ongoing pilot scale testing and computational fluid dynamics (CFD) modeling of mixing processes in 85 foot diameter, 1.3 million gallon, radioactive liquid waste, storage tanks at Savannah River Site (SRS). Homogeneous blending of salt solutions is required in waste tanks. Settled solids (i.e., sludge) are required to remain undisturbed on the bottom of waste tanks during blending. Suspension of sludge during blending may potentially release radiolytically generated hydrogen trapped in the sludge, which is a safety concern. The first paper (Leishear, et. al. [1]) presented pilot scale blending experiments of miscible fluids to provide initial design requirements for a full scale blending pump. Scaling techniques for an 8 foot diameter pilot scale tank were also justified in that work. This second paper describes the overall reasons to perform tests, and documents pilot scale experiments performed to investigate disturbance of sludge, using non-radioactive sludge simulants. A third paper will document pilot scale CFD modeling for comparison to experimental pilot scale test results for both blending tests and sludge disturbance tests. That paper will also describe full scale CFD results. The final paper will document additional blending test results for stratified layers in salt solutions, scale up techniques, final full scale pump design recommendations, and operational recommendations. Specifically, this paper documents a series of pilot scale tests, where sludge simulant disturbance due to a blending pump or transfer pump are investigated. A principle design requirement for a blending pump is UoD, where Uo is the pump discharge nozzle velocity, and D is the nozzle diameter. Pilot scale test results showed that sludge was undisturbed below UoD = 0.47 ft{sup 2}/s, and that below UoD = 0.58 ft{sup 2}/s minimal sludge disturbance was observed. If sludge is minimally disturbed, hydrogen will not be

  7. Mixed Waste Working Group report

    SciTech Connect (OSTI)

    Not Available

    1993-11-09

    The treatment of mixed waste remains one of this country`s most vexing environmental problems. Mixed waste is the combination of radioactive waste and hazardous waste, as defined by the Resource Conservation and Recovery Act (RCRA). The Department of Energy (DOE), as the country`s largest mixed waste generator, responsible for 95 percent of the Nation`s mixed waste volume, is now required to address a strict set of milestones under the Federal Facility Compliance Act of 1992. DOE`s earlier failure to adequately address the storage and treatment issues associated with mixed waste has led to a significant backlog of temporarily stored waste, significant quantities of buried waste, limited permanent disposal options, and inadequate treatment solutions. Between May and November of 1993, the Mixed Waste Working Group brought together stakeholders from around the Nation. Scientists, citizens, entrepreneurs, and bureaucrats convened in a series of forums to chart a course for accelerated testing of innovative mixed waste technologies. For the first time, a wide range of stakeholders were asked to examine new technologies that, if given the chance to be tested and evaluated, offer the prospect for better, safer, cheaper, and faster solutions to the mixed waste problem. In a matter of months, the Working Group has managed to bridge a gap between science and perception, engineer and citizen, and has developed a shared program for testing new technologies.

  8. Mixed waste characterization reference document

    SciTech Connect (OSTI)

    1997-09-01

    Waste characterization and monitoring are major activities in the management of waste from generation through storage and treatment to disposal. Adequate waste characterization is necessary to ensure safe storage, selection of appropriate and effective treatment, and adherence to disposal standards. For some wastes characterization objectives can be difficult and costly to achieve. The purpose of this document is to evaluate costs of characterizing one such waste type, mixed (hazardous and radioactive) waste. For the purpose of this document, waste characterization includes treatment system monitoring, where monitoring is a supplement or substitute for waste characterization. This document establishes a cost baseline for mixed waste characterization and treatment system monitoring requirements from which to evaluate alternatives. The cost baseline established as part of this work includes costs for a thermal treatment technology (i.e., a rotary kiln incinerator), a nonthermal treatment process (i.e., waste sorting, macronencapsulation, and catalytic wet oxidation), and no treatment (i.e., disposal of waste at the Waste Isolation Pilot Plant (WIPP)). The analysis of improvement over the baseline includes assessment of promising areas for technology development in front-end waste characterization, process equipment, off gas controls, and monitoring. Based on this assessment, an ideal characterization and monitoring configuration is described that minimizes costs and optimizes resources required for waste characterization.

  9. Mixed waste characterization, treatment & disposal focus area

    SciTech Connect (OSTI)

    1996-08-01

    The mission of the Mixed Waste Characterization, Treatment, and Disposal Focus Area (referred to as the Mixed Waste Focus Area or MWFA) is to provide treatment systems capable of treating DOE`s mixed waste in partnership with users, and with continual participation of stakeholders, tribal governments, and regulators. The MWFA deals with the problem of eliminating mixed waste from current and future storage in the DOE complex. Mixed waste is waste that contains both hazardous chemical components, subject to the requirements of the Resource Conservation and Recovery Act (RCRA), and radioactive components, subject to the requirements of the Atomic Energy Act. The radioactive components include transuranic (TRU) and low-level waste (LLW). TRU waste primarily comes from the reprocessing of spent fuel and the use of plutonium in the fabrication of nuclear weapons. LLW includes radioactive waste other than uranium mill tailings, TRU, and high-level waste, including spent fuel.

  10. Radioactive waste storage issues

    SciTech Connect (OSTI)

    Kunz, D.E.

    1994-08-15

    In the United States we generate greater than 500 million tons of toxic waste per year which pose a threat to human health and the environment. Some of the most toxic of these wastes are those that are radioactively contaminated. This thesis explores the need for permanent disposal facilities to isolate radioactive waste materials that are being stored temporarily, and therefore potentially unsafely, at generating facilities. Because of current controversies involving the interstate transfer of toxic waste, more states are restricting the flow of wastes into - their borders with the resultant outcome of requiring the management (storage and disposal) of wastes generated solely within a state`s boundary to remain there. The purpose of this project is to study nuclear waste storage issues and public perceptions of this important matter. Temporary storage at generating facilities is a cause for safety concerns and underscores, the need for the opening of permanent disposal sites. Political controversies and public concern are forcing states to look within their own borders to find solutions to this difficult problem. Permanent disposal or retrievable storage for radioactive waste may become a necessity in the near future in Colorado. Suitable areas that could support - a nuclear storage/disposal site need to be explored to make certain the health, safety and environment of our citizens now, and that of future generations, will be protected.

  11. Supplemental design requirements document enhanced radioactive and mixed waste storage: Phase 5, Project W-113

    SciTech Connect (OSTI)

    Ocampo, V.P.

    1994-11-01

    This Supplemental Design Requirements Document (SDRD) is used to communicate Project W-113 specific plant design information from Westinghouse Hanford Company (WHC) to the United States Department of Energy (DOE) and the cognizant Architect Engineer (A/E). The SDRD is prepared after the completion of the project Conceptual Design report (CDR) and prior to the initiation of definitive design. Information in the SDRD serves two purposes: to convey design requirements that are too detailed for inclusion in the Functional Design Criteria (FDC) report and to serve as a means of change control for design commitments in the Title I and Title II design. The Solid Waste Retrieval Project (W-113) SDRD has been restructured from the equipment based outline used in previous SDRDs to a functional systems outline. This was done to facilitate identification of deficiencies in the information provided in the initial draft SDRD and aid design confirmation. The format and content of this SDRD adhere as closely as practicable to the requirements of WHC-CM-6-1, Standard Engineering Practices for Functional Design Criteria.

  12. Review of private sector and Department of Energy treatment, storage, and disposal capabilities for low-level and mixed low-level waste

    SciTech Connect (OSTI)

    Willson, R.A.; Ball, L.W.; Mousseau, J.D.; Piper, R.B.

    1996-03-01

    Private sector capacity for treatment, storage, and disposal (TSD) of various categories of radioactive waste has been researched and reviewed for the Idaho National Engineering Laboratory (INEL) by Lockheed Idaho Technologies Company, the primary contractor for the INEL. The purpose of this document is to provide assistance to the INEL and other US Department of Energy (DOE) sites in determining if private sector capabilities exist for those waste streams that currently cannot be handled either on site or within the DOE complex. The survey of private sector vendors was limited to vendors currently capable of, or expected within the next five years to be able to perform one or more of the following services: low-level waste (LLW) volume reduction, storage, or disposal; mixed LLW treatment, storage, or disposal; alpha-contaminated mixed LLW treatment; LLW decontamination for recycling, reclamation, or reuse; laundering of radioactively-contaminated laundry and/or respirators; mixed LLW treatability studies; mixed LLW treatment technology development. Section 2.0 of this report will identify the approach used to modify vendor information from previous revisions of this report. It will also illustrate the methodology used to identify any additional companies. Section 3.0 will identify, by service, specific vendor capabilities and capacities. Because this document will be used to identify private sector vendors that may be able to handle DOE LLW and mixed LLW streams, it was decided that current DOE capabilities should also be identified. This would encourage cooperation between DOE sites and the various states and, in some instances, may result in a more cost-effective alternative to privatization. The DOE complex has approximately 35 sites that generate the majority of both LLW and mixed LLW. Section 4.0 will identify these sites by Operations Office, and their associated LLW and mixed LLW TSD units.

  13. Mixed Waste Focus Area program management plan

    SciTech Connect (OSTI)

    Beitel, G.A.

    1996-10-01

    This plan describes the program management principles and functions to be implemented in the Mixed Waste Focus Area (MWFA). The mission of the MWFA is to provide acceptable technologies that enable implementation of mixed waste treatment systems developed in partnership with end-users, stakeholders, tribal governments and regulators. The MWFA will develop, demonstrate and deliver implementable technologies for treatment of mixed waste within the DOE Complex. Treatment refers to all post waste-generation activities including sampling and analysis, characterization, storage, processing, packaging, transportation and disposal.

  14. Thermal performance of a buried nuclear waste storage container storing a hybrid mix of PWR and BWR spent fuel rods

    SciTech Connect (OSTI)

    Johnson, G.L.

    1988-09-01

    Lawrence Livermore National Laboratory will design, model, and test nuclear waste packages for use at the Nevada Nuclear Waste Storage Repository at Yucca Mountain, Nevada. One such package would store lightly packed spent fuel rods from both pressurized and boiling water reactors. The storage container provides the primary containment of the nuclear waste and the spent fuel rod cladding provides secondary containment. A series of transient conduction and radiation heat transfer analyses was run to determine for the first 1000 yr of storage if the temperature of the tuff at the borehole wall ever falls below 97{degree}C and whether the cladding of the stored spent fuel ever exceeds 350{degree}C. Limiting the borehole to temperatures of 97{degree}C or greater helps minimize corrosion by assuring that no condensed water collects on the container. The 350{degree}C cladding limit minimizes the possibility of creep-related failure in the spent fuel rod cladding. For a series of packages stored in a 8 x 30 m borehole grid where each package contains 10-yr-old spent fuel rods generating 4.74 kW or more, the borehole wall stays above 97{degree}C for the full 1000-yr analysis period.

  15. Idaho Waste Vitrification Facilities Project Vitrified Waste Interim Storage Facility

    SciTech Connect (OSTI)

    Bonnema, Bruce Edward

    2001-09-01

    This feasibility study report presents a draft design of the Vitrified Waste Interim Storage Facility (VWISF), which is one of three subprojects of the Idaho Waste Vitrification Facilities (IWVF) project. The primary goal of the IWVF project is to design and construct a treatment process system that will vitrify the sodium-bearing waste (SBW) to a final waste form. The project will consist of three subprojects that include the Waste Collection Tanks Facility, the Waste Vitrification Facility (WVF), and the VWISF. The Waste Collection Tanks Facility will provide for waste collection, feed mixing, and surge storage for SBW and newly generated liquid waste from ongoing operations at the Idaho Nuclear Technology and Engineering Center. The WVF will contain the vitrification process that will mix the waste with glass-forming chemicals or frit and turn the waste into glass. The VWISF will provide a shielded storage facility for the glass until the waste can be disposed at either the Waste Isolation Pilot Plant as mixed transuranic waste or at the future national geological repository as high-level waste glass, pending the outcome of a Waste Incidental to Reprocessing determination, which is currently in progress. A secondary goal is to provide a facility that can be easily modified later to accommodate storage of the vitrified high-level waste calcine. The objective of this study was to determine the feasibility of the VWISF, which would be constructed in compliance with applicable federal, state, and local laws. This project supports the Department of Energy’s Environmental Management missions of safely storing and treating radioactive wastes as well as meeting Federal Facility Compliance commitments made to the State of Idaho.

  16. Overview of mixed waste issues

    SciTech Connect (OSTI)

    Piciulo, P.L.; Bowerman, B.S.; Kempf, C.R.; MacKenzie, D.R.; Siskind, B.

    1986-01-01

    Based on BNL's study it was concluded that there are LLWs which contain chemically hazardous components. Scintillation liquids may be considered an EPA listed hazardous waste and are, therefore, potential mixed wastes. Since November, 1985 no operating LLW disposal site will accept these wastes for disposal. Unless such wastes contain de minimis quantities of radionuclides, they cannot be disposed of at an EPA an EPA permitted site. Currently generators of LSC wastes can ship de minimis wastes to be burned at commercial facilities. Oil wastes will also eventually be an EPA listed waste and thus will have to be considered a potential radioactive mixed wasted unless NRC establishes de minimis levels of radionuclides below which oils can be managed as hazardous wastes. Regarding wastes containing lead metal there is some question as to the extent of the hazard posed by lead disposed in a LLW burial trench. Chromium-containing wastes would have to be tested to determine whether they are potential mixed wastes. There may be other wastes that are mixed wastes; the responsibility for determining this rests with the waste generator. It is believed that there are management options for handling potential mixed wastes but there is no regulatory guidance. BNL has identified and evaluated a variety of treatment options for the management of potential radioactive mixed wastes. The findings of that study showed that application of a management option with the purpose of addressing EPA concern can, at the same time, address stabilization and volume reduction concerns of NRC.

  17. DOE regulatory reform initiative vitrified mixed waste

    SciTech Connect (OSTI)

    Carroll, S.J.; Holtzscheiter, E.W.; Flaherty, J.E.

    1997-12-31

    The US Department of Energy (DOE) is charged with responsibly managing the largest volume of mixed waste in the United States. This responsibility includes managing waste in compliance with all applicable Federal and State laws and regulations, and in a cost-effective, environmentally responsible manner. Managing certain treated mixed wastes in Resource Conservation and Recovery Act (RCRA) permitted storage and disposal units (specifically those mixed wastes that pose low risks from the hazardous component) is unlikely to provide additional protection to human health and the environment beyond that afforded by managing these wastes in storage and disposal units subject to requirements for radiological control. In October, 1995, the DOE submitted a regulatory reform proposal to the Environmental Protection Agency (EPA) relating to vitrified mixed waste forms. The technical proposal supports a regulatory strategy that would allow vitrified mixed waste forms treated through a permit or other environmental compliance mechanism to be granted an exemption from RCRA hazardous waste regulation, after treatment, based upon the inherent destruction and immobilization capabilities of vitrification technology. The vitrified waste form will meet, or exceed the performance criteria of the Environmental Assessment (EA) glass that has been accepted as an international standard for immobilizing radioactive waste components and the LDR treatment standards for inorganics and metals for controlling hazardous constituents. The proposal further provides that vitrified mixed waste would be responsibly managed under the Atomic Energy Act (AEA) while reducing overall costs. Full regulatory authority by the EPA or a State would be maintained until an acceptable vitrified mixed waste form, protective of human health and the environment, is produced.

  18. Independent Oversight Review, Advanced Mixed Waste Treatment...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Mixed Waste Treatment Project - April 2013 Independent Oversight Review, Advanced Mixed Waste Treatment Project - April 2013 April 2013 Review of Radiation Protection...

  19. The Hazardous Waste/Mixed Waste Disposal Facility

    SciTech Connect (OSTI)

    Bailey, L.L.

    1991-01-01

    The Hazardous Waste/Mixed Waste Disposal Facility (HW/MWDF) will provide permanent Resource Conservation and Recovery Act (RCRA) permitted storage, treatment, and disposal for hazardous and mixed waste generated at the Department of Energy's (DOE) Savannah River Site (SRS) that cannot be disposed of in existing or planned SRS facilities. Final design is complete for Phase I of the project, the Disposal Vaults. The Vaults will provide RCRA permitted, above-grade disposal capacity for treated hazardous and mixed waste generated at the SRS. The RCRA Part B Permit application was submitted upon approval of the Permit application, the first Disposal Vault is scheduled to be operational in mid 1994. The technical baseline has been established for Phase II, the Treatment Building, and preliminary design work has been performed. The Treatment Building will provide RCRA permitted treatment processes to handle a variety of hazardous and mixed waste generated at SRS in preparation for disposal. The processes will treat wastes for disposal in accordance with the Environmental Protection Agency's (EPA's) Land Disposal Restrictions (LDR). A RCRA Part B Permit application has not yet been submitted to SCDHEC for this phase of the project. The Treatment Building is currently scheduled to be operational in late 1996.

  20. The Hazardous Waste/Mixed Waste Disposal Facility

    SciTech Connect (OSTI)

    Bailey, L.L.

    1991-12-31

    The Hazardous Waste/Mixed Waste Disposal Facility (HW/MWDF) will provide permanent Resource Conservation and Recovery Act (RCRA) permitted storage, treatment, and disposal for hazardous and mixed waste generated at the Department of Energy`s (DOE) Savannah River Site (SRS) that cannot be disposed of in existing or planned SRS facilities. Final design is complete for Phase I of the project, the Disposal Vaults. The Vaults will provide RCRA permitted, above-grade disposal capacity for treated hazardous and mixed waste generated at the SRS. The RCRA Part B Permit application was submitted upon approval of the Permit application, the first Disposal Vault is scheduled to be operational in mid 1994. The technical baseline has been established for Phase II, the Treatment Building, and preliminary design work has been performed. The Treatment Building will provide RCRA permitted treatment processes to handle a variety of hazardous and mixed waste generated at SRS in preparation for disposal. The processes will treat wastes for disposal in accordance with the Environmental Protection Agency`s (EPA`s) Land Disposal Restrictions (LDR). A RCRA Part B Permit application has not yet been submitted to SCDHEC for this phase of the project. The Treatment Building is currently scheduled to be operational in late 1996.

  1. National Institutes of Health: Mixed waste stream analysis

    SciTech Connect (OSTI)

    Kirner, N.P.; Faison, G.P.; Johnson, D.R.

    1994-08-01

    The Low-Level Radioactive Waste Policy Amendments Act of 1985 requires that the US Department of Energy (DOE) provide technical assistance to host States, compact regions, and unaffiliated States to fulfill their responsibilities under the Act. The National Low-Level Waste Management Program (NLLWMP) operated for DOE by EG&G Idaho, Inc. provides technical assistance in the development of new commercial low-level radioactive waste disposal capacity. The NLLWMP has been requested by the Appalachian Compact to help the biomedical community become better acquainted with its mixed waste streams, to help minimize the mixed waste streams generated by the biomedical community, and to provide applicable treatment technologies to those particular mixed waste streams. Mixed waste is waste that satisfies the definition of low-level radioactive waste (LLW) in the Low-Level Radioactive Waste Policy Act of 1980 (LLRWPA) and contains hazardous waste that either (a) is listed as a hazardous waste in Subpart D of 40 CFR 261, or (b) causes the LLW to exhibit any of the hazardous waste characteristics identified in 40 CFR 261. The purpose of this report is to clearly define and characterize the mixed waste streams generated by the biomedical community so that an identification can be made of the waste streams that can and cannot be minimized and treated by current options. An understanding of the processes and complexities of generation of mixed waste in the biomedical community may encourage more treatment and storage options to become available.

  2. Method for storage of solid waste

    DOE Patents [OSTI]

    Mecham, William J.

    1976-01-01

    Metal canisters for long-term storage of calcined highlevel radioactive wastes can be made self-sealing against a breach in the canister wall by the addition of powdered cement to the canister with the calcine before it is sealed for storage. Any breach in the canister wall will permit entry of water which will mix with the cement and harden to form a concrete patch, thus sealing the opening in the wall of the canister and preventing the release of radioactive material to the cooling water or atmosphere.

  3. Technical Safety Requirements for the Waste Storage Facilities May 2014

    SciTech Connect (OSTI)

    Laycak, D. T.

    2014-04-16

    This document contains the Technical Safety Requirements (TSR) for the Radioactive and Hazardous Waste Management (RHWM) WASTE STORAGE FACILITIES, which include Area 625 (A625) and the Building 693 (B693) Yard Area of the Decontamination and Waste Treatment Facility (DWTF) at LLNL. The TSRs constitute requirements for safe operation of the WASTE STORAGE FACILITIES. These TSRs are derived from the Documented Safety Analyses for the Waste Storage Facilities (DSA) (LLNL 2011). The analysis presented therein concluded that the WASTE STORAGE FACILITIES are low-chemical hazard, Hazard Category 2 non-reactor nuclear facilities. The TSRs consist primarily of inventory limits and controls to preserve the underlying assumptions in the hazard and accident analyses. Further, appropriate commitments to safety programs are presented in the administrative controls sections of the TSRs. The WASTE STORAGE FACILITIES are used by RHWM to handle and store hazardous waste, TRANSURANIC (TRU) WASTE, LOW-LEVEL WASTE (LLW), mixed waste, California combined waste, nonhazardous industrial waste, and conditionally accepted waste generated at LLNL as well as small amounts of waste from other DOE facilities, as described in the DSA. In addition, several minor treatments (e.g., size reduction and decontamination) are carried out in these facilities.

  4. Documented Safety Analysis for the Waste Storage Facilities

    SciTech Connect (OSTI)

    Laycak, D

    2008-06-16

    This documented safety analysis (DSA) for the Waste Storage Facilities was developed in accordance with 10 CFR 830, Subpart B, 'Safety Basis Requirements', and utilizes the methodology outlined in DOE-STD-3009-94, Change Notice 3. The Waste Storage Facilities consist of Area 625 (A625) and the Decontamination and Waste Treatment Facility (DWTF) Storage Area portion of the DWTF complex. These two areas are combined into a single DSA, as their functions as storage for radioactive and hazardous waste are essentially identical. The B695 Segment of DWTF is addressed under a separate DSA. This DSA provides a description of the Waste Storage Facilities and the operations conducted therein; identification of hazards; analyses of the hazards, including inventories, bounding releases, consequences, and conclusions; and programmatic elements that describe the current capacity for safe operations. The mission of the Waste Storage Facilities is to safely handle, store, and treat hazardous waste, transuranic (TRU) waste, low-level waste (LLW), mixed waste, combined waste, nonhazardous industrial waste, and conditionally accepted waste generated at LLNL (as well as small amounts from other DOE facilities).

  5. Documented Safety Analysis for the Waste Storage Facilities March 2010

    SciTech Connect (OSTI)

    Laycak, D T

    2010-03-05

    This Documented Safety Analysis (DSA) for the Waste Storage Facilities was developed in accordance with 10 CFR 830, Subpart B, 'Safety Basis Requirements,' and utilizes the methodology outlined in DOE-STD-3009-94, Change Notice 3. The Waste Storage Facilities consist of Area 625 (A625) and the Decontamination and Waste Treatment Facility (DWTF) Storage Area portion of the DWTF complex. These two areas are combined into a single DSA, as their functions as storage for radioactive and hazardous waste are essentially identical. The B695 Segment of DWTF is addressed under a separate DSA. This DSA provides a description of the Waste Storage Facilities and the operations conducted therein; identification of hazards; analyses of the hazards, including inventories, bounding releases, consequences, and conclusions; and programmatic elements that describe the current capacity for safe operations. The mission of the Waste Storage Facilities is to safely handle, store, and treat hazardous waste, transuranic (TRU) waste, low-level waste (LLW), mixed waste, combined waste, nonhazardous industrial waste, and conditionally accepted waste generated at LLNL (as well as small amounts from other DOE facilities).

  6. Requirements for shipment of DOE radioactive mixed waste

    SciTech Connect (OSTI)

    Gablin, K.; No, Hyo; Herman, J.

    1993-08-01

    There are several sources of radioactive mixed waste (RMW) at Argonne National Laboratory which, in the past, were collected at waste tanks and/or sludge tanks. They were eventually pumped out by special pumps and processed in an evaporator located in the waste operations area in Building No. 306. Some of this radioactive mixed waste represents pure elementary mercury. These cleaning tanks must be manually cleaned up because the RMW material was too dense to pump with the equipment in use. The four tanks being discussed in this report are located in Building No. 306. They are the Acid Waste Tank, IMOX/FLOC Tanks, Evaporation Feed Tanks, and Waste Storage Tanks. All of these tanks are characterized and handled separately. This paper discusses the process and the requirements for characterization and the associated paperwork for Argonne Waste to be shipped to Westinghouse Hanford Company for storage.

  7. Method of preparing nuclear wastes for tansportation and interim storage

    DOE Patents [OSTI]

    Bandyopadhyay, Gautam (Naperville, IL); Galvin, Thomas M. (Darien, IL)

    1984-01-01

    Nuclear waste is formed into a substantially water-insoluble solid for temporary storage and transportation by mixing the calcined waste with at least 10 weight percent powdered anhydrous sodium silicate to form a mixture and subjecting the mixture to a high humidity environment for a period of time sufficient to form cementitious bonds by chemical reaction. The method is suitable for preparing an interim waste form from dried high level radioactive wastes.

  8. Decision analysis of Hanford underground storage tank waste retrieval systems

    SciTech Connect (OSTI)

    Merkhofer, M.W.; Bitz, D.A.; Berry, D.L.; Jardine, L.J.

    1994-05-01

    A decision analysis approach has been proposed for planning the retrieval of hazardous, radioactive, and mixed wastes from underground storage tanks. This paper describes the proposed approach and illustrates its application to the single-shell storage tanks (SSTs) at Hanford, Washington.

  9. Nuclear waste storage container with metal matrix

    DOE Patents [OSTI]

    Sump, Kenneth R.

    1978-01-01

    The invention relates to a storage container for high-level waste having a metal matrix for the high-level waste, thereby providing greater impact strength for the waste container and increasing heat transfer properties.

  10. Method of encapsulating solid radioactive waste material for storage

    DOE Patents [OSTI]

    Bunnell, Lee Roy; Bates, J. Lambert

    1976-01-01

    High-level radioactive wastes are encapsulated in vitreous carbon for long-term storage by mixing the wastes as finely divided solids with a suitable resin, formed into an appropriate shape and cured. The cured resin is carbonized by heating under a vacuum to form vitreous carbon. The vitreous carbon shapes may be further protected for storage by encasement in a canister containing a low melting temperature matrix material such as aluminum to increase impact resistance and improve heat dissipation.

  11. Information related to low-level mixed waste inventory, characteristics, generation, and facility assessment for treatment, storage, and disposal alternatives considered in the U.S. Department of Energy Waste Management Programmatic Environmental Impact Statement

    SciTech Connect (OSTI)

    Wilkins, B.D.; Dolak, D.A.; Wang, Y.Y.; Meshkov, N.K.

    1996-12-01

    This report was prepared to support the analysis of risks and costs associated with the proposed treatment of low-level mixed waste (LLMW) under management of the US Department of Energy (DOE). The various waste management alternatives for treatment of LLMW have been defined in the DOE`s Office of Waste Management Programmatic Environmental Impact Statement. This technical memorandum estimates the waste material throughput expected at each proposed LLMW treatment facility and analyzes potential radiological and chemical releases at each DOE site resulting from treatment of these wastes. Models have been developed to generate site-dependent radiological profiles and waste-stream-dependent chemical profiles for these wastes. Current site-dependent inventories and estimates for future generation of LLMW have been obtained from DOE`s 1994 Mixed Waste Inventory Report (MWIR-2). Using treatment procedures developed by the Mixed Waste Treatment Project, the MWIR-2 database was analyzed to provide waste throughput and emission estimates for each of the different waste types assessed in this report. Uncertainties in the estimates at each site are discussed for waste material throughputs and radiological and chemical releases.

  12. Hanford Site annual dangerous waste report: Volume 4, Waste Management Facility report, Radioactive mixed waste

    SciTech Connect (OSTI)

    1994-12-31

    This report contains information on radioactive mixed wastes at the Hanford Site. Information consists of shipment date, physical state, chemical nature, waste description, handling method and containment vessel, waste number, waste designation and amount of waste.

  13. Hanford Site annual dangerous waste report: Volume 2, Generator dangerous waste report, radioactive mixed waste

    SciTech Connect (OSTI)

    1994-12-31

    This report contains information on radioactive mixed wastes at the Hanford Site. Information consists of shipment date, physical state, chemical nature, waste description, waste number, waste designation, weight, and waste designation.

  14. Microbial Transformation of TRU and Mixed Waste: Actinide Speciation and Waste Volume

    SciTech Connect (OSTI)

    Halada, Gary P

    2008-04-10

    In order to understand the susceptibility of transuranic and mixed waste to microbial degradation (as well as any mechanism which depends upon either complexation and/or redox of metal ions), it is essential to understand the association of metal ions with organic ligands present in mixed wastes. These ligands have been found in our previous EMSP study to limit electron transfer reactions and strongly affect transport and the eventual fate of radionuclides in the environment. As transuranic waste (and especially mixed waste) will be retained in burial sites and in legacy containment for (potentially) many years while awaiting treatment and removal (or remaining in place under stewardship agreements at government subsurface waste sites), it is also essential to understand the aging of mixed wastes and its implications for remediation and fate of radionuclides. Mixed waste containing actinides and organic materials are especially complex and require extensive study. The EMSP program described in this report is part of a joint program with the Environmental Sciences Department at Brookhaven National Laboratory. The Stony Brook University portion of this award has focused on the association of uranium (U(VI)) and transuranic analogs (Ce(III) and Eu(III)) with cellulosic materials and related compounds, with development of implications for microbial transformation of mixed wastes. The elucidation of the chemical nature of mixed waste is essential for the formulation of remediation and encapsulation technologies, for understanding the fate of contaminant exposed to the environment, and for development of meaningful models for contaminant storage and recovery.

  15. Environmental assessment, finding of no significant impact, and response to comments. Radioactive waste storage

    SciTech Connect (OSTI)

    1996-04-01

    The Department of Energy`s (DOE) Rocky Flats Environmental Technology Site (the Site), formerly known as the Rocky Flats Plant, has generated radioactive, hazardous, and mixed waste (waste with both radioactive and hazardous constituents) since it began operations in 1952. Such wastes were the byproducts of the Site`s original mission to produce nuclear weapons components. Since 1989, when weapons component production ceased, waste has been generated as a result of the Site`s new mission of environmental restoration and deactivation, decontamination and decommissioning (D&D) of buildings. It is anticipated that the existing onsite waste storage capacity, which meets the criteria for low-level waste (LL), low-level mixed waste (LLM), transuranic (TRU) waste, and TRU mixed waste (TRUM) would be completely filled in early 1997. At that time, either waste generating activities must cease, waste must be shipped offsite, or new waste storage capacity must be developed.

  16. Transportable Vitrification System Demonstration on Mixed Waste

    SciTech Connect (OSTI)

    Zamecnik, J.R.; Whitehouse, J.C.; Wilson, C.N.; Van Ryn, F.R.

    1998-01-01

    This paper describes preliminary results from the first demonstration of the Transportable Vitrification System (TVS) on actual mixed waste. The TVS is a fully integrated, transportable system for the treatment of mixed and low-level radioactive wastes. The demonstration was conducted at Oak Ridge`s East Tennessee Technology Park (ETTP), formerly known as the K-25 site. The purpose of the demonstration was to show that mixed wastes could be vitrified safely on a `field` scale using joule-heated melter technology and obtain information on system performance, waste form durability, air emissions, and costs.

  17. Site Visit Report, Hanford Waste Encapsulation Storage Facility...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Site Visit Report, Hanford Waste Encapsulation Storage Facility - January 2011 Site Visit Report, Hanford Waste Encapsulation Storage Facility - January 2011 January 2011 Hanford ...

  18. Method and apparatus for reducing mixed waste

    DOE Patents [OSTI]

    Elliott, Michael L.; Perez, Jr., Joseph M.; Chapman, Chris C.; Peters, Richard D.

    1995-01-01

    The present invention is a method and apparatus for in-can waste reduction. The method is mixing waste with combustible material prior to placing the waste into a waste reduction vessel. The combustible portion is ignited, thereby reducing combustible material to ash and non-combustible material to a slag. Further combustion or heating may be used to sinter or melt the ash. The apparatus is a waste reduction vessel having receiving canister connection means on a first end, and a waste/combustible mixture inlet on a second end. An oxygen supply is provided to support combustion of the combustible mixture.

  19. Advanced Mixed Waste Treatment Project Achieves Impressive Safety...

    Office of Environmental Management (EM)

    Advanced Mixed Waste Treatment Project Achieves Impressive Safety and Production Marks Advanced Mixed Waste Treatment Project Achieves Impressive Safety and Production Marks June ...

  20. CARBON BED MERCURY EMISSIONS CONTROL FOR MIXED WASTE TREATMENT...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: CARBON BED MERCURY EMISSIONS CONTROL FOR MIXED WASTE TREATMENT Citation Details In-Document Search Title: CARBON BED MERCURY EMISSIONS CONTROL FOR MIXED WASTE ...

  1. An Effective Waste Management Process for Segregation and Disposal of Legacy Mixed Waste at Sandia National Laboratories/New Mexico

    SciTech Connect (OSTI)

    Hallman, Anne K.; Meyer, Dann; Rellergert, Carla A.; Schriner, Joseph A.

    1998-06-01

    Sandia National Laboratories/New Mexico (SNL/NM) is a research and development facility that generates many highly diverse, low-volume mixed waste streams. Under the Federal Facility Compliance Act, SNL/NM must treat its mixed waste in storage to meet the Land Disposal Restrictions treatment standards. Since 1989, approximately 70 cubic meters (2500 cubic feet) of heterogeneous, poorly characterized and inventoried mixed waste was placed in storage that could not be treated as specified in the SNL/NM Site Treatment Plan. A process was created to sort the legacy waste into sixteen well- defined, properly characterized, and precisely inventoried mixed waste streams (Treatability Groups) and two low-level waste streams ready for treatment or disposal. From June 1995 through September 1996, the entire volume of this stored mixed waste was sorted and inventoried through this process. This process was planned to meet the technical requirements of the sorting operation and to identify and address the hazards this operation presented. The operations were routinely adapted to safely and efficiently handle a variety of waste matrices, hazards, and radiological conditions. This flexibility was accomplished through administrative and physical controls integrated into the sorting operations. Many Department of Energy facilities are currently facing the prospect of sorting, characterizing, and treating a large inventory of mixed waste. The process described in this paper is a proven method for preparing a diverse, heterogeneous mixed waste volume into segregated, characterized, inventoried, and documented waste streams ready for treatment or disposal.

  2. Aluminum phosphate ceramics for waste storage

    DOE Patents [OSTI]

    Wagh, Arun; Maloney, Martin D

    2014-06-03

    The present disclosure describes solid waste forms and methods of processing waste. In one particular implementation, the invention provides a method of processing waste that may be particularly suitable for processing hazardous waste. In this method, a waste component is combined with an aluminum oxide and an acidic phosphate component in a slurry. A molar ratio of aluminum to phosphorus in the slurry is greater than one. Water in the slurry may be evaporated while mixing the slurry at a temperature of about 140-200.degree. C. The mixed slurry may be allowed to cure into a solid waste form. This solid waste form includes an anhydrous aluminum phosphate with at least a residual portion of the waste component bound therein.

  3. Waste Management Facilities cost information for mixed low-level waste. Revision 1

    SciTech Connect (OSTI)

    Shropshire, D.; Sherick, M.; Biadgi, C.

    1995-06-01

    This report contains preconceptual designs and planning level life-cycle cost estimates for managing mixed low-level waste. The report`s information on treatment, storage, and disposal modules can be integrated to develop total life-cycle costs for various waste management options. A procedure to guide the US Department of Energy and its contractor personnel in the use of cost estimation data is also summarized in this report.

  4. Interim report: Waste management facilities cost information for mixed low-level waste

    SciTech Connect (OSTI)

    Feizollahi, F.; Shropshire, D.

    1994-03-01

    This report contains preconceptual designs and planning level life-cycle cost estimates for treating alpha and nonalpha mixed low-level radioactive waste. This report contains information on twenty-seven treatment, storage, and disposal modules that can be integrated to develop total life cycle costs for various waste management options. A procedure to guide the US Department of Energy and its contractor personnel in the use of estimating data is also summarized in this report.

  5. EM Cleanup Crew Nears Finish at Idaho Transuranic Waste Storage Facility

    Broader source: Energy.gov [DOE]

    IDAHO FALLS, Idaho – Working deliberately under demanding conditions, workers have entered the final storage “cell” to remove drums and boxes of waste from the Transuranic Storage Area–Retrieval Enclosure (TSA-RE) at the Department’s Advanced Mixed Waste Treatment Project (AMWTP) in Idaho.

  6. Impact of TRU waste storage on a stand-alone MRS facility

    SciTech Connect (OSTI)

    Griffin, R.E.; Ganley, J.T.

    1983-11-01

    A study was made of the impact of transuranic (TRU) waste storage on the conceptual design of a stand-alone Monitored Retrievable Storage (MRS) facility. The amount of TRU waste requiring storage is related to the startup dates of the reprocessing plant and the final repository. Current technology is available to store TRU waste from lightwater reactor (LWR) fuel reprocessing and mixed oxide (MOX) fuel refabrication safely and economically. Unit capital costs for TRU waste storage are in the range 7 to 10 $/kg of heavy metal. 7 references, 13 figures, 16 tables.

  7. Hybrid systems process mixed wastes

    SciTech Connect (OSTI)

    Chertow, M.R.

    1989-10-01

    Some technologies, developed recently in Europe, combine several processes to separate and reuse materials from solid waste. These plants have in common, generally, that they are reasonably small, have a composting component for the organic portion, and often have a refuse-derived fuel component for combustible waste. Many European communities also have very effective drop-off center programs for recyclables such as bottles and cans. By maintaining the integrity of several different fractions of the waste, there is a less to landfill and less to burn. The importance of these hybrid systems is that they introduce in one plant an approach that encompasses the key concept of today's solid waste planning; recover as much as possible and landfill as little as possible. The plants also introduce various risks, particularly of finding secure markets. There are a number of companies offering various combinations of materials recovery, composting, and waste combustion. Four examples are included: multiple materials recovery and refuse-derived fuel production in Eden Prairie, Minnesota; multiple materials recovery, composting and refuse-derived fuel production in Perugia, Italy; composting, refuse-derived fuel, and gasification in Tolmezzo, Italy; and a front-end system on a mass burning waste-to-energy plant in Neuchatel, Switzerland.

  8. Bioprocessing of a stored mixed liquid waste

    SciTech Connect (OSTI)

    Wolfram, J.H.; Rogers, R.D.; Finney, R.

    1995-12-31

    This paper describes the development and results of a demonstration for a continuous bioprocess for mixed waste treatment. A key element of the process is an unique microbial strain which tolerates high levels of aromatic solvents and surfactants. This microorganism is the biocatalysis of the continuous flow system designed for the processing of stored liquid scintillation wastes. During the past year a process demonstration has been conducted on commercial formulation of liquid scintillation cocktails (LSC). Based on data obtained from this demonstration, the Ohio EPA granted the Mound Applied Technologies Lab a treatability permit allowing the limited processing of actual mixed waste. Since August 1994, the system has been successfully processing stored, {open_quotes}hot{close_quotes} LSC waste. The initial LSC waste fed into the system contained 11% pseudocumene and detectable quantities of plutonium. Another treated waste stream contained pseudocumene and tritium. Data from this initial work shows that the hazardous organic solvent, and pseudocumene have been removed due to processing, leaving the aqueous low level radioactive waste. Results to date have shown that living cells are not affected by the dissolved plutonium and that 95% of the plutonium was sorbed to the biomass. This paper discusses the bioprocess, rates of processing, effluent, and the implications of bioprocessing for mixed waste management.

  9. Mixed Low-Level Radioactive Waste (MLLW) Primer

    SciTech Connect (OSTI)

    W. E. Schwinkendorf

    1999-04-01

    This document presents a general overview of mixed low-level waste, including the regulatory definitions and drivers, the manner in which the various kinds of mixed waste are regulated, and a discussion of the waste treatment options.

  10. Mixed waste focus area alternative technologies workshop

    SciTech Connect (OSTI)

    Borduin, L.C.; Palmer, B.A.; Pendergrass, J.A.

    1995-05-24

    This report documents the Mixed Waste Focus Area (MWFA)-sponsored Alternative Technology Workshop held in Salt Lake City, Utah, from January 24--27, 1995. The primary workshop goal was identifying potential applications for emerging technologies within the Options Analysis Team (OAT) ``wise`` configuration. Consistent with the scope of the OAT analysis, the review was limited to the Mixed Low-Level Waste (MLLW) fraction of DOE`s mixed waste inventory. The Los Alamos team prepared workshop materials (databases and compilations) to be used as bases for participant review and recommendations. These materials derived from the Mixed Waste Inventory Report (MWIR) data base (May 1994), the Draft Site Treatment Plan (DSTP) data base, and the OAT treatment facility configuration of December 7, 1994. In reviewing workshop results, the reader should note several caveats regarding data limitations. Link-up of the MWIR and DSTP data bases, while representing the most comprehensive array of mixed waste information available at the time of the workshop, requires additional data to completely characterize all waste streams. A number of changes in waste identification (new and redefined streams) occurred during the interval from compilation of the data base to compilation of the DSTP data base with the end result that precise identification of radiological and contaminant characteristics was not possible for these streams. To a degree, these shortcomings compromise the workshop results; however, the preponderance of waste data was linked adequately, and therefore, these analyses should provide useful insight into potential applications of alternative technologies to DOE MLLW treatment facilities.

  11. 1998 report on Hanford Site land disposal restrictions for mixed waste

    SciTech Connect (OSTI)

    Black, D.G.

    1998-04-10

    This report was submitted to meet the requirements of Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement) Milestone M-26-01H. This milestone requires the preparation of an annual report that covers characterization, treatment, storage, minimization, and other aspects of managing land-disposal-restricted mixed waste at the Hanford Facility. The US Department of Energy, its predecessors, and contractors on the Hanford Facility were involved in the production and purification of nuclear defense materials from the early 1940s to the late 1980s. These production activities have generated large quantities of liquid and solid mixed waste. This waste is regulated under authority of both the Resource Conservation and Recovery Act of l976 and the Atomic Energy Act of 1954. This report covers only mixed waste. The Washington State Department of Ecology, US Environmental Protection Agency, and US Department of Energy have entered into the Tri-Party Agreement to bring the Hanford Facility operations into compliance with dangerous waste regulations. The Tri-Party Agreement required development of the original land disposal restrictions (LDR) plan and its annual updates to comply with LDR requirements for mixed waste. This report is the eighth update of the plan first issued in 1990. The Tri-Party Agreement requires and the baseline plan and annual update reports provide the following information: (1) Waste Characterization Information -- Provides information about characterizing each LDR mixed waste stream. The sampling and analysis methods and protocols, past characterization results, and, where available, a schedule for providing the characterization information are discussed. (2) Storage Data -- Identifies and describes the mixed waste on the Hanford Facility. Storage data include the Resource Conservation and Recovery Act of 1976 dangerous waste codes, generator process knowledge needed to identify the waste and to make LDR determinations, quantities

  12. Mixed waste paper to ethanol fuel

    SciTech Connect (OSTI)

    Not Available

    1991-01-01

    The objectives of this study were to evaluate the use of mixed waste paper for the production of ethanol fuels and to review the available conversion technologies, and assess developmental status, current and future cost of production and economics, and the market potential. This report is based on the results of literature reviews, telephone conversations, and interviews. Mixed waste paper samples from residential and commercial recycling programs and pulp mill sludge provided by Weyerhauser were analyzed to determine the potential ethanol yields. The markets for ethanol fuel and the economics of converting paper into ethanol were investigated.

  13. MIxed Waste Integrated Program (MWIP): Technology summary

    SciTech Connect (OSTI)

    1994-02-01

    The mission of the Mixed Waste Integrated Program (MWIP) is to develop and demonstrate innovative and emerging technologies for the treatment and management of DOE`s mixed low-level wastes (MLLW) for use by its customers, the Office of Waste Operations (EM-30) and the Office of Environmental Restoration (EM-40). The primary goal of MWIP is to develop and demonstrate the treatment and disposal of actual mixed waste (MMLW and MTRU). The vitrification process and the plasma hearth process are scheduled for demonstration on actual radioactive waste in FY95 and FY96, respectively. This will be accomplished by sequential studies of lab-scale non-radioactive testing followed by bench-scale radioactive testing, followed by field-scale radioactive testing. Both processes create a highly durable final waste form that passes leachability requirements while destroying organics. Material handling technology, and off-gas requirements and capabilities for the plasma hearth process and the vitrification process will be established in parallel.

  14. Hazardous and Radioactive Mixed Waste

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1982-12-31

    To establish hazardous waste management procedures for facilities operated under authority of the Atomic Energy Act of 1954, as amended (AEA). The procedures will follow. to the extent practicable, regulations issued by the Environmental Protection Agency (EPA) pursuant to the Resource Conservation and Recovery Act of 1976 (RCRA). Although Department of Energy (DOE) operations conducted under authority other than the AEA are subject to EPA or State regulations conforming with RCRA, facilities administered under the authority of the AEA are not bound by such requirements.

  15. Hazardous and Radioactive Mixed Waste Program

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1989-02-22

    To establish Department of Energy (DOE) hazardous and radioactive mixed waste policies and requirements and to implement the requirements of the Resource Conservation and Recovery Act (RCRA) within the framework of the environmental programs established under DOE O 5400.1. This directive does not cancel any directives.

  16. Site Visit Report, Hanford Waste Encapsulation Storage Facility - January

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2011 | Department of Energy Hanford Waste Encapsulation Storage Facility - January 2011 Site Visit Report, Hanford Waste Encapsulation Storage Facility - January 2011 January 2011 Hanford Waste Encapsulation Storage Facility Documented Safety Analysis results of a review conducted by the Department of Energy's Office of Health, Safety and Security (HSS) of the documented safety analysis for the Waste Encapsulation Storage Facility at DOE's Hanford Site. The review was performed from July

  17. Canister storage building evaluation of nuclear safety for solidified high-level waste transfer and storage

    SciTech Connect (OSTI)

    Kidder, R.J., Westinghouse Hanford

    1996-09-17

    This document is issued to evaluate the safety impacts to the Canister Storage Building from transfer and storage of solidified high-level waste.

  18. Method for acid oxidation of radioactive, hazardous, and mixed organic waste materials

    DOE Patents [OSTI]

    Pierce, Robert A.; Smith, James R.; Ramsey, William G.; Cicero-Herman, Connie A.; Bickford, Dennis F.

    1999-01-01

    The present invention is directed to a process for reducing the volume of low level radioactive and mixed waste to enable the waste to be more economically stored in a suitable repository, and for placing the waste into a form suitable for permanent disposal. The invention involves a process for preparing radioactive, hazardous, or mixed waste for storage by contacting the waste starting material containing at least one organic carbon-containing compound and at least one radioactive or hazardous waste component with nitric acid and phosphoric acid simultaneously at a contacting temperature in the range of about 140.degree. C. to about 210 .degree. C. for a period of time sufficient to oxidize at least a portion of the organic carbon-containing compound to gaseous products, thereby producing a residual concentrated waste product containing substantially all of said radioactive or inorganic hazardous waste component; and immobilizing the residual concentrated waste product in a solid phosphate-based ceramic or glass form.

  19. Processing of Oak Ridge Mixed Waste Labpacks

    SciTech Connect (OSTI)

    Estes, C. H.; Franco, P.; Bisaria, A.

    2002-02-26

    The Oak Ridge Site Treatment Plan (STP) issued under a Tennessee Commissioner's Order includes a compliance milestone related to treatment of mixed waste labpacks on the Oak Ridge sites. The treatment plan was written and approved in Fiscal Year 1997. The plan involved approximately 1,100 labpacks and 7,400 on-the-shelf labpackable items stored at three Department of Energy (DOE) sites on the Oak Ridge Reservation (ORR). The labpacks and labpack items consist of liquids and solids with various chemical constituents and radiological concerns. The waste must be processed for shipment to a commercial hazardous waste treatment facility or treatment utilizing a Broad Spectrum mixed waste treatment contract. This paper will describe the labpack treatment plan that was developed as required by the Site Treatment Plan and the operations implemented to process the labpack waste. The paper will discuss the labpack inventory in the treatment plan, treatment and disposal options, processing strategies, project risk assessment, and current project status.

  20. Independent Oversight Review, Advanced Mixed Waste Treatment Project- April 2013

    Office of Energy Efficiency and Renewable Energy (EERE)

    Review of Radiation Protection Program Implementation at the Advanced Mixed Waste Treatment Project of the Idaho Site

  1. Treatment of M-area mixed wastes at the Savannah River Site

    SciTech Connect (OSTI)

    Not Available

    1994-06-01

    The Department of Energy has prepared this environmental assessment, DOE/EA-0918, to assess the potential environmental impacts of the treatment of mixed wastes currently stored in the M-Area at the Savannah River Site, near Aiken, South Carolina. DOE is proposing to treat and stabilize approximately 700,000 gallons of mixed waste currently stored in the Interim Treatment/Storage Facility (IT/SF) and Mixed Waste Storage Shed (MWSS). This waste material is proposed to be stabilized using a vitrification process and temporarily stored until final disposal is available by the year 2005. This document has been prepared to assess the potential environmental impacts attributable to the treatment and stabilization of M-area mixed wastes, the closure of the interim storage area, and storage of the vitrified waste until disposal in onsite RCRA vaults. Based on the analyses in the environmental assessment, the Department of Energy has determined that the proposed action is not a major Federal action significantly affecting the quality of the human environment within the meaning of the National Environmental Policy Act (NEPA) of 1969. Therefore, the preparation of an environmental impact statement is not required, and the Department of Energy is issuing this finding of no significant impact.

  2. Mixed Waste Management Options: 1995 Update. National Low-Level Waste Management Program

    SciTech Connect (OSTI)

    Kirner, N.; Kelly, J.; Faison, G.; Johnson, D.

    1995-05-01

    In the original mixed Waste Management Options (DOE/LLW-134) issued in December 1991, the question was posed, ``Can mixed waste be managed out of existence?`` That study found that most, but not all, of the Nation`s mixed waste can theoretically be managed out of existence. Four years later, the Nation is still faced with a lack of disposal options for commercially generated mixed waste. However, since publication of the original Mixed Waste Management Options report in 1991, limited disposal capacity and new technologies to treat mixed waste have become available. A more detailed estimate of the Nation`s mixed waste also became available when the US Environmental Protection Agency (EPA) and the US Nuclear Regulatory Commission (NRC) published their comprehensive assessment, titled National Profile on Commercially Generated Low-Level Radioactive Mixed Waste (National Profile). These advancements in our knowledge about mixed waste inventories and generation, coupled with greater treatment and disposal options, lead to a more applied question posed for this updated report: ``Which mixed waste has no treatment option?`` Beyond estimating the volume of mixed waste requiring jointly regulated disposal, this report also provides a general background on the Atomic Energy Act (AEA) and the Resource Conservation and Recovery Act (RCRA). It also presents a methodical approach for generators to use when deciding how to manage their mixed waste. The volume of mixed waste that may require land disposal in a jointly regulated facility each year was estimated through the application of this methodology.

  3. DOE acceptance of commercial mixed waste -- Studies are under way

    SciTech Connect (OSTI)

    Plummer, T.L.; Owens, C.M.

    1993-03-01

    The topic of the Department of Energy acceptance of commercial mixed waste at DOE facilities has been proposed by host States and compact regions that are developing low-level radioactive waste disposal facilities. States support the idea of DOE accepting commercial mixed waste because (a) very little commercial mixed waste is generated compared to generation by DOE facilities (Department of Energy--26,300 cubic meters annually vs. commercial--3400 cubic meters annually); (b) estimated costs for commercial disposal are estimated to be $15,000 to $40,000 per cubic foot; (c) once treatment capability becomes available, 70% of the current levels of commercial mixed waste will be eliminated, (d) some State laws prohibit the development of mixed waste disposal facilities in their States; (e) DOE is developing a nationwide strategy that will include treatment and disposal capacity for its own mixed waste and the incremental burden on the DOE facilities would be minuscule, and (6) no States are developing mixed waste disposal facilities. DOE senior management has repeatedly expressed willingness to consider investigating the feasibility of DOE accepting commercial mixed waste. In January 1991, Leo Duffy of the Department of energy met with members of the Low-Level Radioactive Waste Forum, which led to an agreement to explore such an arrangement. He stated that this seems like a cost-effective way to solve commercial mixed waste management problems.

  4. Environmental assessment for the construction and operation of waste storage facilities at the Paducah Gaseous Diffusion Plant, Paducah, Kentucky

    SciTech Connect (OSTI)

    1994-06-01

    DOE is proposing to construct and operate 3 waste storage facilities (one 42,000 ft{sup 2} waste storage facility for RCRA waste, one 42,000 ft{sup 2} waste storage facility for toxic waste (TSCA), and one 200,000 ft{sup 2} mixed (hazardous/radioactive) waste storage facility) at Paducah. This environmental assessment compares impacts of this proposed action with those of continuing present practices aof of using alternative locations. It is found that the construction, operation, and ultimate closure of the proposed waste storage facilities would not significantly affect the quality of the human environment within the meaning of NEPA; therefore an environmental impact statement is not required.

  5. Mixed and Low-Level Treatment Facility Project. Appendix B, Waste stream engineering files, Part 1, Mixed waste streams

    SciTech Connect (OSTI)

    Not Available

    1992-04-01

    This appendix contains the mixed and low-level waste engineering design files (EDFS) documenting each low-level and mixed waste stream investigated during preengineering studies for Mixed and Low-Level Waste Treatment Facility Project. The EDFs provide background information on mixed and low-level waste generated at the Idaho National Engineering Laboratory. They identify, characterize, and provide treatment strategies for the waste streams. Mixed waste is waste containing both radioactive and hazardous components as defined by the Atomic Energy Act and the Resource Conservation and Recovery Act, respectively. Low-level waste is waste that contains radioactivity and is not classified as high-level waste, transuranic waste, spent nuclear fuel, or 11e(2) byproduct material as defined by DOE 5820.2A. Test specimens of fissionable material irradiated for research and development only, and not for the production of power or plutonium, may be classified as low-level waste, provided the concentration of transuranic is less than 100 nCi/g. This appendix is a tool that clarifies presentation format for the EDFS. The EDFs contain waste stream characterization data and potential treatment strategies that will facilitate system tradeoff studies and conceptual design development. A total of 43 mixed waste and 55 low-level waste EDFs are provided.

  6. Savannah River Site - Mixed Waste Management Facility Northwest Plume |

    Office of Environmental Management (EM)

    Department of Energy Mixed Waste Management Facility Northwest Plume Savannah River Site - Mixed Waste Management Facility Northwest Plume January 1, 2013 - 12:00pm Addthis US Department of Energy Groundwater Database Groundwater Master Report InstallationName, State: Savannah River Site, SC Responsible DOE Office: Savannah River Site Plume Name: Mixed Waste Management Facility Northwest Plume Remediation Contractor: Savannah River Nuclear Solutions, LLC PBS Number: 30 Report Last Updated:

  7. DOE Extends Advanced Mixed Waste Treatment Project Contract | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Advanced Mixed Waste Treatment Project Contract DOE Extends Advanced Mixed Waste Treatment Project Contract September 29, 2015 - 6:00pm Addthis Media Contact Danielle Miller, 208-526-5709 Idaho Falls, ID - The U.S. Department of Energy's Office of Environmental Management (EM) today announced it is extending its contract for the Advanced Mixed Waste Treatment Project at the Idaho Site for a period of 6 months. The contract period for the current contractor, Idaho Treatment Group

  8. Summary of BNL studies regarding commercial mixed waste

    SciTech Connect (OSTI)

    Bowerman, B.S.; Kempf, C.R.; MacKenzie, D.R.; Siskind, B.; Piciulo, P.L.

    1986-09-01

    Based on BNL's study it was concluded that there are low-level radioactive wastes (LLWs) which contain chemically hazardous components. Scintillation liquids may be considered an EPA listed hazardous waste and are, therefore, potential mixed wastes. Since November 1985, no operating LLW disposal site will accept these wastes for disposal. Unless such wastes contain de minimis quantities of radionuclides, they cannot be disposed of at an EPA permitted site. Currently generators of liquid scintillation wastes can ship de minimis wastes to be burned at commercial facilities. Oil wastes may also eventually be an EPA listed waste and thus will have to be considered a potential radioactive mixed waste unless NRC establishes de minimis levels of radionuclides below which oils can be managed as hazardous wastes. Regarding wastes containing lead metal there is some question as to the extent of the hazard posed by lead disposed in a LLW burial trench. Chromium-containing wastes would have to be tested to determine whether they are potential mixed wastes. There may be other wastes that are mixed wastes; the responsibility for determining this rests with the waste generator. While management options for handling potential mixed wastes are available, there is limited regulatory guidance for generators. BNL has identified and evaluated a variety of treatment options for the management of potential radioactive mixed wastes. The findings of that study showed that application of a management option with the purpose of addressing EPA concerns can, at the same time, address stabilization and volume reduction concerns of NRC. 6 refs., 1 tab.

  9. Development of characterization protocol for mixed liquid radioactive waste classification

    SciTech Connect (OSTI)

    Zakaria, Norasalwa; Wafa, Syed Asraf; Wo, Yii Mei; Mahat, Sarimah

    2015-04-29

    Mixed liquid organic waste generated from health-care and research activities containing tritium, carbon-14, and other radionuclides posed specific challenges in its management. Often, these wastes become legacy waste in many nuclear facilities and being considered as ‘problematic’ waste. One of the most important recommendations made by IAEA is to perform multistage processes aiming at declassification of the waste. At this moment, approximately 3000 bottles of mixed liquid waste, with estimated volume of 6000 litres are currently stored at the National Radioactive Waste Management Centre, Malaysia and some have been stored for more than 25 years. The aim of this study is to develop a characterization protocol towards reclassification of these wastes. The characterization protocol entails waste identification, waste screening and segregation, and analytical radionuclides profiling using various analytical procedures including gross alpha/ gross beta, gamma spectrometry, and LSC method. The results obtained from the characterization protocol are used to establish criteria for speedy classification of the waste.

  10. Department of Energy Idaho - Advanced Mixed Waste Treatment Project...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    > AMWTP Contract Idaho Treatment Group, LLC (ITG) Advanced Mixed Waste Treatment Project Contract Basic Contract Contract Modifications Last Updated: 10052015 Privacy Statement...

  11. Surrogate formulations for thermal treatment of low-level mixed waste, Part II: Selected mixed waste treatment project waste streams

    SciTech Connect (OSTI)

    Bostick, W.D.; Hoffmann, D.P.; Chiang, J.M.; Hermes, W.H.; Gibson, L.V. Jr.; Richmond, A.A.; Mayberry, J.; Frazier, G.

    1994-01-01

    This report summarizes the formulation of surrogate waste packages, representing the major bulk constituent compositions for 12 waste stream classifications selected by the US DOE Mixed Waste Treatment Program. These waste groupings include: neutral aqueous wastes; aqueous halogenated organic liquids; ash; high organic content sludges; adsorbed aqueous and organic liquids; cement sludges, ashes, and solids; chloride; sulfate, and nitrate salts; organic matrix solids; heterogeneous debris; bulk combustibles; lab packs; and lead shapes. Insofar as possible, formulation of surrogate waste packages are referenced to authentic wastes in inventory within the DOE; however, the surrogate waste packages are intended to represent generic treatability group compositions. The intent is to specify a nonradiological synthetic mixture, with a minimal number of readily available components, that can be used to represent the significant challenges anticipated for treatment of the specified waste class. Performance testing and evaluation with use of a consistent series of surrogate wastes will provide a means for the initial assessment (and intercomparability) of candidate treatment technology applicability and performance. Originally the surrogate wastes were intended for use with emerging thermal treatment systems, but use may be extended to select nonthermal systems as well.

  12. 1999 Report on Hanford Site land disposal restriction for mixed waste

    SciTech Connect (OSTI)

    BLACK, D.G.

    1999-03-25

    This report was submitted to meet the requirements of Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement) Milestone M-26-011. This milestone requires the preparation of an annual report that covers characterization, treatment, storage, minimization, and other aspects of managing land-disposal-restricted mixed waste at the Hanford Facility.

  13. Safety analysis approaches or mixed transuranic waste.

    SciTech Connect (OSTI)

    Courtney, J. C.; Dwight, C. C.; Forrester, R. J.; Lehto, M. A.; Pan, Y. C.

    1999-02-10

    Argonne National Laboratory (ANL) has completed a survey of assumptions and techniques used for safety analyses at seven sites that handle or store mixed transuranic (TRU) waste operated by contractors for the US Department of Energy (DOE). While approaches to estimating on-site and off-site consequences of hypothetical accidents differ, there are commonalities in all of the safety studies. This paper identifies key parameters and methods used to estimate the radiological consequences associated with release of waste forms under abnormal conditions. Specific facilities are identified by letters with their safety studies listed in a bibliography rather than as specific references so that similarities and differences are emphasized in a nonjudgmental manner. References are provided for specific parameters used to project consequences associated with compromise of barriers and dispersion of potentially hazardous materials. For all of the accidents and sites, estimated dose commitments are well below guidelines even using highly conservative assumptions. Some of the studies quantified the airborne concentrations of toxic materials; this paper only addresses these analyses briefly, as an entire paper could be dedicated to this subject.

  14. Safety analysis report for the Waste Storage Facility. Revision 2

    SciTech Connect (OSTI)

    Bengston, S.J.

    1994-05-01

    This safety analysis report outlines the safety concerns associated with the Waste Storage Facility located in the Radioactive Waste Management Complex at the Idaho National Engineering Laboratory. The three main objectives of the report are: define and document a safety basis for the Waste Storage Facility activities; demonstrate how the activities will be carried out to adequately protect the workers, public, and environment; and provide a basis for review and acceptance of the identified risk that the managers, operators, and owners will assume.

  15. Nonradioactive Air Emissions Notice of Construction (NOC) Application for the Central Waste Complex (CSC) for Storage of Vented Waste Containers

    SciTech Connect (OSTI)

    KAMBERG, L.D.

    2000-04-01

    This Notice of Construction (NOC) application is submitted for the storage and management of waste containers at the Central Waste Complex (CWC) stationary source. The CWC stationary source consists of multiple sources of diffuse and fugitive emissions, as described herein. This NOC is submitted in accordance with the requirements of Washington Administrative Code (WAC) 173-400-110 (criteria pollutants) and 173-460-040 (toxic air pollutants), and pursuant to guidance provided by the Washington State Department of Ecology (Ecology). Transuranic (TRU) mixed waste containers at CWC are vented to preclude the build up of hydrogen produced as a result of radionuclide decay, not as safety pressure releases. The following activities are conducted within the CWC stationary source: Storage and inspection; Transfer and staging; Packaging; Treatment; and Sampling. This NOC application is intended to cover all existing storage structures within the current CWC treatment, storage, and/or disposal (TSD) boundary, as well as any storage structures, including waste storage pads and staging areas, that might be constructed in the future within the existing CWC boundary.

  16. Mixed waste focus area technical baseline report. Volume 2

    SciTech Connect (OSTI)

    1997-04-01

    As part of its overall program, the MWFA uses a national mixed waste data set to develop approaches for treating mixed waste that cannot be treated using existing capabilities at DOE or commercial facilities. The current data set was originally compiled under the auspices of the 1995 Mixed Waste Inventory Report. The data set has been updated over the past two years based on Site Treatment Plan revisions and clarifications provided by individual sites. The current data set is maintained by the MWFA staff and is known as MWFA97. In 1996, the MWFA developed waste groupings, process flow diagrams, and treatment train diagrams to systematically model the treatment of all mixed waste in the DOE complex. The purpose of the modeling process was to identify treatment gaps and corresponding technology development needs for the DOE complex. Each diagram provides the general steps needed to treat a specific type of waste. The NWFA categorized each MWFA97 waste stream by waste group, treatment train, and process flow. Appendices B through F provide the complete listing of waste streams by waste group, treatment train, and process flow. The MWFA97 waste strewn information provided in the appendices is defined in Table A-1.

  17. NNWSI [Nevada Nuclear Waste Storage Investigation] strategy for repository licensing

    SciTech Connect (OSTI)

    Plodinec, M.J.

    1987-01-16

    The Nevada Nuclear Waste Storage Investigation (NNWSI) has developed a strategy to license a nuclear waste repository in tuff. This strategy, which is currently circulating in draft form within the Department of Energy`s Office of Civilian Radioactive Waste Management, has important implications for DWPF waste form qualification activities, design of the DWPF process, and DWPF operations. In this report, the strategy and its implications for the DWPF are presented. 2 refs.

  18. MWIR-1995 DOE national mixed and TRU waste database users guide

    SciTech Connect (OSTI)

    1995-11-01

    The Department of Energy (DOE) National 1995 Mixed Waste Inventory Report (MWIR-1995) Database Users Guide provides information on computer system requirements and describes installation, operation, and navigation through the database. The MWIR-1995 database contains a detailed, nationwide compilation of information on DOE mixed waste streams and treatment systems. In addition, the 1995 version includes data on non- mixed, transuranic (TRU) waste streams. These were added to the data set as a result of coordination of the 1995 update with the National Transuranic Program Office`s (NTPO`s) data needs to support the Waste Isolation Pilot Plant (WIPP) TRU Waste Baseline Inventory Report (WTWBIR). However, the information on the TRU waste streams is limited to that associated with the core mixed waste data requirements. The additional, non-core data on TRU streams collected specifically to support the WTWBIR is not included in the MWIR-1995 database. With respect to both the mixed and TRU waste stream data, the data set addresses {open_quotes}stored{close_quotes} streams. In this instance, {open_quotes}stored{close_quotes} streams are defined as (a) streams currently in storage at both EM-30 and EM-40 sites and (b) streams that have yet to be generated but are anticipated within the next five years from sources other than environmental restoration and decontamination and decommissioning (ER/D&D) activities. Information on future ER/D&D streams is maintained in the EM-40 core database. The MWIR-1995 database also contains limited information for both waste streams and treatment systems that have been removed or deleted since the 1994 MWIR. Data on these is maintained only through Section 2, Waste Stream Identification/Tracking/Source, to document the reason for removal from the data set.

  19. Preliminary plan for treating mixed waste

    SciTech Connect (OSTI)

    Vandegrift, G.F.; Conner, C.; Hutter, J.C.; Leonard, R.A.; Nunez, L.; Sedlet, J.; Wygmans, D.G.

    1993-06-01

    A preliminary waste treatment plan was developed for disposing of radioactive inorganic liquid wastes that contain hazardous metals and/or hazardous acid concentrations at Argonne National Laboratory. This plan, which involves neutralization and sulfide precipitation followed by filtration, reduces the concentration of hazardous metals and the acidity so that the filtrate liquid is simply a low-level radioactive waste that can be fed to a low-level waste evaporator.

  20. DOE SEEKS CONTRACTOR TO DISPOSITION WASTE AT THE ADVANCED MIXED WASTE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TREATMENT PROJECT (AMWTP) SEEKS CONTRACTOR TO DISPOSITION WASTE AT THE ADVANCED MIXED WASTE TREATMENT PROJECT (AMWTP) Inside the AMWTP facility The AMWTP facility Idaho Falls - The U.S. Department of Energy, Idaho Operations Office, in coordination with the Office of Environmental Management today released a Final �Request for Proposal� to obtain a contractor to perform waste processing at the Advanced Mixed Waste Treatment Project at the Department�s Idaho Site near Idaho Falls,

  1. Polymer solidification of mixed wastes at the Rocky Flats Plant

    SciTech Connect (OSTI)

    Faucette, A.M.; Logsdon, B.W.; Lucerna, J.J.; Yudnich, R.J.

    1994-02-01

    The Rocky Flats Plant is pursuing polymer solidification as a viable treatment option for several mixed waste streams that are subject to land disposal restrictions within the Resource Conservation and Recovery Act provisions. Tests completed to date using both surrogate and actual wastes indicate that polyethylene microencapsulation is a viable treatment option for several mixed wastes at the Rocky Flats Plant, including nitrate salts, sludges, and secondary wastes such as ash. Treatability studies conducted on actual salt waste demonstrated that the process is capable of producing waste forms that comply with all applicable regulatory criteria, including the Toxicity Characteristic Leaching Procedure. Tests have also been conducted to evaluate the feasibility of macroencapsulating certain debris wastes in polymers. Several methods and plastics have been tested for macroencapsulation, including post-consumer recycle and regrind polyethylene.

  2. Regulatory Approaches for Solid Radioactive Waste Storage in Russia

    SciTech Connect (OSTI)

    Griffith, A.; Testov, S.; Diaschev, A.; Nazarian, A.; Ustyuzhanin, A.

    2003-02-26

    The Russian Navy under the Arctic Military Environmental Cooperation (AMEC) Program has designated the Polyarninsky Shipyard as the regional recipient for solid radioactive waste (SRW) pretreatment and storage facilities. Waste storage technologies include containers and lightweight modular storage buildings. The prime focus of this paper is solid radioactive waste storage options based on the AMEC mission and Russian regulatory standards. The storage capability at the Polyarninsky Shipyard in support of Mobile Pretreatment Facility (MPF) operations under the AMEC Program will allow the Russian Navy to accumulate/stage the SRW after treatment at the MPF. It is anticipated that the MPF will operate for 20 years. This paper presents the results of a regulatory analysis performed to support an AMEC program decision on the type of facility to be used for storage of SRW. The objectives the study were to: analyze whether a modular storage building (MSB), referred in the standards as a lightweight building, would comply with the Russian SRW storage building standard, OST 95 10517-95; analyze the Russian SRW storage pad standard OST 95 10516-95; and compare the two standards, OST 95 10517-95 for storage buildings and OST 95 10516-95 for storage pads.

  3. 1997 Hanford site report on land disposal restrictions for mixed waste

    SciTech Connect (OSTI)

    Black, D.G.

    1997-04-07

    The baseline land disposal restrictions (LDR) plan was prepared in 1990 in accordance with the Hanford Federal Facility Agreement and Consent Order (commonly referred to as the Tn-Party Agreement) Milestone M-26-00 (Ecology et al, 1989). The text of this milestone is below. ''LDR requirements include limitations on storage of specified hazardous wastes (including mixed wastes). In accordance with approved plans and schedules, the U.S. Department of Energy (DOE) shall develop and implement technologies necessary to achieve full compliance with LDR requirements for mixed wastes at the Hanford Site. LDR plans and schedules shall be developed with consideration of other action plan milestones and will not become effective until approved by the U.S. Environmental Protection Agency (EPA) (or Washington State Department of Ecology [Ecology]) upon authorization to administer LDRs pursuant to Section 3006 of the Resource Conservation and Recovery Act of 1976 (RCRA). Disposal of LDR wastes at any time is prohibited except in accordance with applicable LDR requirements for nonradioactive wastes at all times. The plan will include, but not be limited to, the following: Waste characterization plan; Storage report; Treatment report; Treatment plan; Waste minimization plan; A schedule depicting the events necessary to achieve full compliance with LDR requirements; and A process for establishing interim milestones.

  4. Risk assessment of CST-7 proposed waste treatment and storage facilities Volume I: Limited-scope probabilistic risk assessment (PRA) of proposed CST-7 waste treatment & storage facilities. Volume II: Preliminary hazards analysis of proposed CST-7 waste storage & treatment facilities

    SciTech Connect (OSTI)

    Sasser, K.

    1994-06-01

    In FY 1993, the Los Alamos National Laboratory Waste Management Group [CST-7 (formerly EM-7)] requested the Probabilistic Risk and Hazards Analysis Group [TSA-11 (formerly N-6)] to conduct a study of the hazards associated with several CST-7 facilities. Among these facilities are the Hazardous Waste Treatment Facility (HWTF), the HWTF Drum Storage Building (DSB), and the Mixed Waste Receiving and Storage Facility (MWRSF), which are proposed for construction beginning in 1996. These facilities are needed to upgrade the Laboratory`s storage capability for hazardous and mixed wastes and to provide treatment capabilities for wastes in cases where offsite treatment is not available or desirable. These facilities will assist Los Alamos in complying with federal and state requlations.

  5. Status Update: Extended Storage and Transportation Waste Confidence...

    Office of Environmental Management (EM)

    Status Update: Extended Storage and Transportation Waste Confidence Presentation made by David W. Pstrak for the NTSF annual meeting held from May 14-16, 2013 in Buffalo, NY. ...

  6. ORS 466 - Storage, Treatment, and Disposal of Hazardous Waste...

    Open Energy Info (EERE)

    ORS 466 - Storage, Treatment, and Disposal of Hazardous Waste and Materials Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: ORS...

  7. Update on intrusive characterization of mixed contact-handled transuranic waste at Argonne-West

    SciTech Connect (OSTI)

    Dwight, C.C.; Jensen, B.A.; Bryngelson, C.D.; Duncan, D.S.

    1997-02-03

    Argonne National Laboratory and Lockheed Martin Idaho Technologies Company have jointly participated in the Department of Energy`s (DOE) Waste Isolation Pilot Plant (WIPP) Transuranic Waste Characterization Program since 1990. Intrusive examinations have been conducted in the Waste Characterization Area, located at Argonne-West in Idaho Falls, Idaho, on over 200 drums of mixed contact-handled transuranic waste. This is double the number of drums characterized since the last update at the 1995 Waste Management Conference. These examinations have provided waste characterization information that supports performance assessment of WIPP and that supports Lockheed`s compliance with the Resource Conservation and Recovery Act. Operating philosophies and corresponding regulatory permits have been broadened to provide greater flexibility and capability for waste characterization, such as the provision for minor treatments like absorption, neutralization, stabilization, and amalgamation. This paper provides an update on Argonne`s intrusive characterization permits, procedures, results, and lessons learned. Other DOE sites that must deal with mixed contact-handled transuranic waste have initiated detailed planning for characterization of their own waste. The information presented herein could aid these other storage and generator sites in further development of their characterization efforts.

  8. Identification of radioactive mixed wastes in commercial low-level wastes

    SciTech Connect (OSTI)

    Bowerman, B.S.; Kempf, C.R.; MacKenzie, D.R.; Siskind, B.; Piciulo, P.L.

    1986-01-01

    A literature review and survey were conducted on behalf of the US NRC Division of Waste Management to determine whether any commercial low-level radioactive wastes (LLW) could be considered hazardous as defined by EPA under 40 CFR Part 261. The purpose of the study was to identify broad categories of LLW which may require special management as radioactive mixed waste, and to help address uncertainties regarding the regulation of such wastes. Of 239 questionnaires sent out to reactor and non-reactor LLW generators, there were 91 responses representing 29% by volume of all low-level wastes disposed of at commercial disposal sites in 1984. The analysis of the survey results indicated that the following waste types generic to commercial LLW may be potential radioactive mixed wastes: Wastes containing oil, disposed of by reactors and industrial facilities, and representing 4.2% of the total LLW volume reported in the survey. Wastes containing organic liquids, disposed of by all types of generators, and representing 2.3% by volume of all wastes reported. Wastes containing lead metal, i.e., discarded shielding and lead containers, representing <0.1% by volume of all wastes reported. Wastes containing chromium, i.e., process wastes from nuclear power plants which use chromates as corrosion inhibitors; these represent 0.6% of the total volume reported in the survey. Certain wastes, specific to particular generators, were identified as potential mixed wastes as well.

  9. A perspective of hazardous waste and mixed waste treatment technology at the Savannah River Site

    SciTech Connect (OSTI)

    England, J.L.; Venkatesh, S.; Bailey, L.L.; Langton, C.A.; Hay, M.S.; Stevens, C.B.; Carroll, S.J.

    1991-12-31

    Treatment technologies for the preparation and treatment of heavy metal mixed wastes, contaminated soils, and mixed mercury wastes are being considered at the Savannah River Site (SRS), a DOE nuclear material processing facility operated by Westinghouse Savannah River Company (WSRC). The proposed treatment technologies to be included at the Hazardous Waste/Mixed Waste Treatment Building at SRS are based on the regulatory requirements, projected waste volumes, existing technology, cost effectiveness, and project schedule. Waste sorting and size reduction are the initial step in the treatment process. After sorting/size reduction the wastes would go to the next applicable treatment module. For solid heavy metal mixed wastes the proposed treatment is macroencapsulation using a thermoplastic polymer. This process reduces the leachability of hazardous constituents from the waste and allows easy verification of the coating integrity. Stabilization and solidification in a cement matrix will treat a wide variety of wastes (i.e. soils, decontamination water). Some pretreatments may be required (i.e. Ph adjustment) before stabilization. Other pretreatments such as soil washing can reduce the amount of waste to be stabilized. Radioactive contaminated mercury waste at the SRS comes in numerous forms (i.e. process equipment, soils, and lab waste) with the required treatment of high mercury wastes being roasting/retorting and recovery. Any unrecyclable radioactive contaminated elemental mercury would be amalgamated, utilizing a batch system, before disposal.

  10. A perspective of hazardous waste and mixed waste treatment technology at the Savannah River Site

    SciTech Connect (OSTI)

    England, J.L.; Venkatesh, S.; Bailey, L.L.; Langton, C.A.; Hay, M.S.; Stevens, C.B.; Carroll, S.J.

    1991-01-01

    Treatment technologies for the preparation and treatment of heavy metal mixed wastes, contaminated soils, and mixed mercury wastes are being considered at the Savannah River Site (SRS), a DOE nuclear material processing facility operated by Westinghouse Savannah River Company (WSRC). The proposed treatment technologies to be included at the Hazardous Waste/Mixed Waste Treatment Building at SRS are based on the regulatory requirements, projected waste volumes, existing technology, cost effectiveness, and project schedule. Waste sorting and size reduction are the initial step in the treatment process. After sorting/size reduction the wastes would go to the next applicable treatment module. For solid heavy metal mixed wastes the proposed treatment is macroencapsulation using a thermoplastic polymer. This process reduces the leachability of hazardous constituents from the waste and allows easy verification of the coating integrity. Stabilization and solidification in a cement matrix will treat a wide variety of wastes (i.e. soils, decontamination water). Some pretreatments may be required (i.e. Ph adjustment) before stabilization. Other pretreatments such as soil washing can reduce the amount of waste to be stabilized. Radioactive contaminated mercury waste at the SRS comes in numerous forms (i.e. process equipment, soils, and lab waste) with the required treatment of high mercury wastes being roasting/retorting and recovery. Any unrecyclable radioactive contaminated elemental mercury would be amalgamated, utilizing a batch system, before disposal.

  11. Presidential Rapid Commercialization Initiative for mixed waste solvent extraction

    SciTech Connect (OSTI)

    Honigford, L.; Dilday, D.; Cook, D.; Sattler, J.

    1997-03-01

    Recently, the Fernald Environmental Management Project (FEMP) has made some major steps in mixed waste treatment which have taken it closer to meeting final remediation goals. However, one major hurdle remains for the FEMP mixed waste treatment program, and that hurdle is tri-mixed waste. Tri-mixed is a term coined to describe low-level waste containing RCRA hazardous constituents along with polychlorinated biphenyls (PCB). The prescribed method for disposal of PCBs is incineration. In mixed waste treatment plans developed by the FEMP with public input, the FEMP committed to pursue non-thermal treatment methods and avoid the use of incineration. Through the SITE Program, the FEMP identified a non-thermal treatment technology which uses solvents to extract PCBs. The technology belongs to a small company called Terra-Kleen Response Group, Inc. A question arose as to how can this new and innovative technology be implemented by a small company at a Department of Energy (DOE) facility. The answer came in the form of the Rapid Commercialization Initiative (RCI) and the Mixed Waste Focus Area (MWFA). RCI is a program sponsored by the Department of commerce (DOC), DOE, Department of Defense (DOD), US EPA and various state agencies to aid companies to market new and innovative technologies.

  12. Identification of radioactive mixed wastes in commercial low-level wastes

    SciTech Connect (OSTI)

    Bowerman, B.S.; Kempf, C.R.; MacKenzie, D.R.; Siskind, B.; Piciulo, P.L.

    1985-01-01

    A literature review and survey were conducted on behalf of the US NRC Division of Waste Management to determine whether any commercial low-level radioactive wastes (LLW) could be considered hazardous as defined by EPA under 40 CFR Part 261. The purpose of the study was to identify broad categories of LLW which may require special management as radioactive mixed waste, and to help address uncertainties regarding the regulation of such wastes. Of 239 questionnaires sent out to reactor and non-reactor LLW generators, there were 91 responses representing 29% by volume of all low-level wastes disposed of at commercial disposal sites in 1984. The analysis of the survey results indicated that three waste streams generic to commercial LLW may be potential radioactive mixed wastes. These are as follows: (1) wastes containing organic liquids, disposed of by all types of generators and representing approx. =2.3% by volume of all wastes reported; (2) wastes containing lead metal, i.e., discarded shielding and lead containers, representing <0.1% by volume of all wastes reported; and (3) wastes containing chromium, i.e., process wastes from nuclear power plants which use chromates as corrosion inhibitors; these represent 0.6% of the total volume reported in the survey. Certain wastes, specific to particular generators, were identified as potential mixed wastes as well. 4 refs., 5 tabs.

  13. On-site waste storage assuring the success of on-site, low-level nuclear waste storage

    SciTech Connect (OSTI)

    Preston, E.L.

    1986-09-21

    Waste management has reached paramount importance in recent years. The successful management of radioactive waste is a key ingredient in the successful operation of any nuclear facility. This paper discusses the options available for on-site storage of low-level radioactive waste and those options that have been selected by the Department of Energy facilities operated by Martin Marietta Energy Systems, Inc. in Oak Ridge, Tennessee. The focus of the paper is on quality assurance (QA) features of waste management activities such as accountability and retrievability of waste materials and waste packages, retrievability of data, waste containment, safety and environmental monitoring. Technical performance and careful documentation of that performance are goals which can be achieved only through the cooperation of numerous individuals from waste generating and waste managing organizations, engineering, QA, and environmental management.

  14. Transportable vitrification system demonstration on mixed waste. Revision 1

    SciTech Connect (OSTI)

    Zamecnik, J.R.; Whitehouse, J.C.; Wilson, C.N.; Van Ryn, F.R.

    1998-04-22

    The Transportable Vitrification System (TVS) is a large scale, fully integrated, vitrification system for the treatment of low-level and mixed wastes in the form of sludges, soils, incinerator ash, and many other waste streams. It was demonstrated on surrogate waste at Clemson University and at the Oak Ridge Reservation (ORR) prior to treating actual mixed waste. Treatment of a combination of dried B and C Pond sludge and CNF sludge was successfully demonstrated at ORR in 1997. The demonstration produced 7,616 kg of glass from 7,328 kg of mixed wastes with a 60% reduction in volume. Glass formulations for the wastes treated were developed using a combination of laboratory crucible studies with the actual wastes and small melter studies at Clemson with both surrogate and actual wastes. Initial characterization of the B and C Pond sludge had not shown the presence of carbon or fluoride, which required a modified glass formulation be developed to maintain proper glass redox and viscosity. The CNF sludge challenges the glass formulations due to high levels of phosphate and iron. The demonstration was delayed several times by permitting problems, a glass leak, and electrical problems. The demonstration showed that the two wastes could be successfully vitrified, although the design glass production rate was not achieved. The glass produced met the Universal Treatment Standards and the emissions from the TVS were well within the allowable permit limits.

  15. Biodegradation and Biotransformation of Mixed Wastes Containing Metals and Chlorinated Xenobiotic Compounds By Microbial

    SciTech Connect (OSTI)

    Crqwford, D. L.; Kamashwaran, S. R.

    2001-07-01

    OAK 270 - Biodegradation and biotransformation of mixed Wastes Containing metals and chlorinated Xenobiotic compounds by microbial.

  16. Thermal and chemical remediation of mixed waste

    DOE Patents [OSTI]

    Nelson, P.A.; Swift, W.M.

    1994-08-09

    A process and system for treating organic waste materials without venting gaseous emissions to the atmosphere. A fluidized bed including lime particles is operated at a temperature of at least 500 C by blowing gas having 20%/70% oxygen upwardly through the bed particles at a rate sufficient to fluidize same. A toxic organic waste material is fed into the fluidized bed where the organic waste material reacts with the lime forming CaCO[sub 3]. The off gases are filtered and cooled to condense water which is separated. A portion of the calcium carbonate formed during operation of the fluidized bed is replaced with lime particles. The off gases from the fluidized bed after drying are recirculated until the toxic organic waste material in the bed is destroyed. 3 figs.

  17. Thermal and chemical remediation of mixed waste

    DOE Patents [OSTI]

    Nelson, Paul A.; Swift, William M.

    1994-01-01

    A process and system for treating organic waste materials without venting gaseous emissions to the atmosphere. A fluidized bed including lime particles is operated at a temperature of at least 500.degree. C. by blowing gas having 20%/70% oxygen upwardly through the bed particles at a rate sufficient to fluidize same. A toxic organic waste material is fed into the fluidized bed where the organic waste material reacts with the lime forming CaCO.sub.3. The off gases are filtered and cooled to condense water which is separated. A portion of the calcium carbonate formed during operation of the fluidized bed is replaced with lime particles. The off gases from the fluidized bed after drying are recirculated until the toxic organic waste material in the bed is destroyed.

  18. Stabilization Using Phosphate Bonded Ceramics. Salt Containing Mixed Waste Treatment. Mixed Waste Focus Area. OST Reference #117

    SciTech Connect (OSTI)

    None, None

    1999-09-01

    Throughout the Department of Energy (DOE) complex there are large inventories of homogeneous mixed waste solids, such as wastewater treatment residues, fly ashes, and sludges that contain relatively high concentrations (greater than 15% by weight) of salts. The inherent solubility of salts (e.g., nitrates, chlorides, and sulfates) makes traditional treatment of these waste streams difficult, expensive, and challenging. One alternative is low-temperature stabilization by chemically bonded phosphate ceramics (CBPCs). The process involves reacting magnesium oxide with monopotassium phosphate with the salt waste to produce a dense monolith. The ceramic makes a strong environmental barrier, and the metals are converted to insoluble, low-leaching phosphate salts. The process has been tested on a variety of surrogates and actual mixed waste streams, including soils, wastewater, flyashes, and crushed debris. It has also been demonstrated at scales ranging from 5 to 55 gallons. In some applications, the CBPC technology provides higher waste loadings and a more durable salt waste form than the baseline method of cementitious grouting. Waste form test specimens were subjected to a variety of performance tests. Results of waste form performance testing concluded that CBPC forms made with salt wastes meet or exceed both RCRA and recommended Nuclear Regulatory Commission (NRC) low-level waste (LLW) disposal criteria. Application of a polymer coating to the CBPC may decrease the leaching of salt anions, but continued waste form evaluations are needed to fully assess the deteriorating effects of this leaching, if any, over time.

  19. Commercial Submersible Mixing Pump For SRS Tank Waste Removal - 15223

    SciTech Connect (OSTI)

    Hubbard, Mike; Herbert, James E.; Scheele, Patrick W.

    2015-01-12

    The Savannah River Site Tank Farms have 45 active underground waste tanks used to store and process nuclear waste materials. There are 4 different tank types, ranging in capacity from 2839 m3 to 4921 m3 (750,000 to 1,300,000 gallons). Eighteen of the tanks are older style and do not meet all current federal standards for secondary containment. The older style tanks are the initial focus of waste removal efforts for tank closure and are referred to as closure tanks. Of the original 51 underground waste tanks, six of the original 24 older style tanks have completed waste removal and are filled with grout. The insoluble waste fraction that resides within most waste tanks at SRS requires vigorous agitation to suspend the solids within the waste liquid in order to transfer this material for eventual processing into glass filled canisters at the Defense Waste Processing Facility (DWPF). SRS suspends the solid waste by use of recirculating mixing pumps. Older style tanks generally have limited riser openings which will not support larger mixing pumps, since the riser access is typically 58.4 cm (23 inches) in diameter. Agitation for these tanks has been provided by four long shafted standard slurry pumps (SLP) powered by an above tank 112KW (150 HP) electric motor. The pump shaft is lubricated and cooled in a pressurized water column that is sealed from the surrounding waste in the tank. Closure of four waste tanks has been accomplished utilizing long shafted pump technology combined with heel removal using multiple technologies. Newer style waste tanks at SRS have larger riser openings, allowing the processing of waste solids to be accomplished with four large diameter SLPs equipped with 224KW (300 HP) motors. These tanks are used to process the waste from closure tanks for DWPF. In addition to the SLPs, a 224KW (300 HP) submersible mixer pump (SMP) has also been developed and deployed within older style tanks. The SMPs are product cooled and

  20. Hanford Site waste treatment/storage/disposal integration

    SciTech Connect (OSTI)

    MCDONALD, K.M.

    1999-02-24

    In 1998 Waste Management Federal Services of Hanford, Inc. began the integration of all low-level waste, mixed waste, and TRU waste-generating activities across the Hanford site. With seven contractors, dozens of generating units, and hundreds of waste streams, integration was necessary to provide acute waste forecasting and planning for future treatment activities. This integration effort provides disposition maps that account for waste from generation, through processing, treatment and final waste disposal. The integration effort covers generating facilities from the present through the life-cycle, including transition and deactivation. The effort is patterned after the very successful DOE Complex EM Integration effort. Although still in the preliminary stages, the comprehensive onsite integration effort has already reaped benefits. These include identifying significant waste streams that had not been forecast, identifying opportunities for consolidating activities and services to accelerate schedule or save money; and identifying waste streams which currently have no path forward in the planning baseline. Consolidation/integration of planned activities may also provide opportunities for pollution prevention and/or avoidance of secondary waste generation. A workshop was held to review the waste disposition maps, and to identify opportunities with potential cost or schedule savings. Another workshop may be held to follow up on some of the long-term integration opportunities. A change to the Hanford waste forecast data call would help to align the Solid Waste Forecast with the new disposition maps.

  1. Treatability study of absorbent polymer waste form for mixed waste treatment

    SciTech Connect (OSTI)

    Herrmann, S. D.; Lehto, M. A.; Stewart, N. A.; Croft, A. D.; Kern, P. W.

    2000-02-10

    A treatability study was performed to develop and characterize an absorbent polymer waste form for application to low level (LLW) and mixed low level (MLLW) aqueous wastes at Argonne National Laboratory-West (ANL-W). In this study absorbent polymers proved effective at immobilizing aqueous liquid wastes in order to meet Land Disposal Restrictions for subsurface waste disposal. Treatment of aqueous waste with absorbent polymers provides an alternative to liquid waste solidification via high-shear mixing with clays and cements. Significant advantages of absorbent polymer use over clays and cements include ease of operations and waste volume minimization. Absorbent polymers do not require high-shear mixing as do clays and cements. Granulated absorbent polymer is poured into aqueous solutions and forms a gel which passes the paint filter test as a non-liquid. Pouring versus mixing of a solidification agent not only eliminates the need for a mixing station, but also lessens exposure to personnel and the potential for spread of contamination from treatment of radioactive wastes. Waste minimization is achieved as significantly less mass addition and volume increase is required of and results from absorbent polymer use than that of clays and cements. Operational ease and waste minimization translate into overall cost savings for LLW and MLLW treatment.

  2. Savannah River Site mixed waste Proposed Site Treatment Plan (PSTP). Volumes 1 and 2 and reference document: Revision 2

    SciTech Connect (OSTI)

    Helmich, E.; Noller, D.K.; Wierzbicki, K.S.; Bailey, L.L.

    1995-07-13

    The DOE is required by the Resource Conservation and Recovery Act to prepare site treatment plans describing the development of treatment capacities and technologies for treating mixed waste. This proposed plan contains Savannah River Site`s preferred options and schedules for constructing new facilities, and otherwise obtaining treatment for mixed wastes. The proposed plan consists of 2 volumes. Volume 1, Compliance Plan, identifies the capacity to be developed and the schedules as required. Volume 2, Background, provides a detailed discussion of the preferred options with technical basis, plus a description of the specific waste streams. Chapters are: Introduction; Methodology; Mixed low level waste streams; Mixed transuranic waste; High level waste; Future generation of mixed waste streams; Storage; Process for evaluation of disposal issues in support of the site treatment plans discussions; Treatment facilities and treatment technologies; Offsite waste streams for which SRS treatment is the Preferred Option (Naval reactor wastes); Summary information; and Acronyms and glossary. This revision does not contain the complete revised report, but only those pages that have been revised.

  3. Permitting plan for the high-level waste interim storage

    SciTech Connect (OSTI)

    Deffenbaugh, M.L.

    1997-04-23

    This document addresses the environmental permitting requirements for the transportation and interim storage of solidified high-level waste (HLW) produced during Phase 1 of the Hanford Site privatization effort. Solidified HLW consists of canisters containing vitrified HLW (glass) and containers that hold cesium separated during low-level waste pretreatment. The glass canisters and cesium containers will be transported to the Canister Storage Building (CSB) in a U.S. Department of Energy (DOE)-provided transportation cask via diesel-powered tractor trailer. Tri-Party Agreement (TPA) Milestone M-90 establishes a new major milestone, and associated interim milestones and target dates, governing acquisition and/or modification of facilities necessary for: (1) interim storage of Tank Waste Remediation Systems (TWRS) immobilized HLW (IHLW) and other canistered high-level waste forms; and (2) interim storage and disposal of TWRS immobilized low-activity tank waste (ILAW). An environmental requirements checklist and narrative was developed to identify the permitting path forward for the HLW interim storage (HLWIS) project (See Appendix B). This permitting plan will follow the permitting logic developed in that checklist.

  4. Automated system for handling tritiated mixed waste

    SciTech Connect (OSTI)

    Dennison, D.K.; Merrill, R.D.; Reitz, T.C.

    1995-03-01

    Lawrence Livermore National Laboratory (LLNL) is developing a semi system for handling, characterizing, processing, sorting, and repackaging hazardous wastes containing tritium. The system combines an IBM-developed gantry robot with a special glove box enclosure designed to protect operators and minimize the potential release of tritium to the atmosphere. All hazardous waste handling and processing will be performed remotely, using the robot in a teleoperational mode for one-of-a-kind functions and in an autonomous mode for repetitive operations. Initially, this system will be used in conjunction with a portable gas system designed to capture any gaseous-phase tritium released into the glove box. This paper presents the objectives of this development program, provides background related to LLNL`s robotics and waste handling program, describes the major system components, outlines system operation, and discusses current status and plans.

  5. Thermal and chemical remediation of mixed wastes

    DOE Patents [OSTI]

    Nelson, Paul A. (Wheaton, IL); Swift, William M. (Downers Grove, IL)

    1997-01-01

    A process for treating organic waste materials without venting gaseous emissions to the atmosphere which includes oxidizing the organic waste materials at an elevated temperature not less than about 500.degree. C. with a gas having an oxygen content in the range of from about 20% to about 70% to produce an oxidation product containing CO.sub.2 gas. The gas is then filtered to remove particulates, and then contacted with an aqueous absorbent solution of alkali metal carbonates or alkanolamines to absorb a portion of the CO.sub.2 gas from the particulate-free oxidation product. The CO.sub.2 absorbent is thereafter separated for further processing. A process and system are also disclosed in which the waste materials are contacted with a reactive medium such as lime and product treatment as described.

  6. Thermal and chemical remediation of mixed wastes

    DOE Patents [OSTI]

    Nelson, P.A.; Swift, W.M.

    1997-12-16

    A process is described for treating organic waste materials without venting gaseous emissions to the atmosphere which includes oxidizing the organic waste materials at an elevated temperature not less than about 500 C with a gas having an oxygen content in the range of from about 20% to about 70% to produce an oxidation product containing CO{sub 2} gas. The gas is then filtered to remove particulates, and then contacted with an aqueous absorbent solution of alkali metal carbonates or alkanolamines to absorb a portion of the CO{sub 2} gas from the particulate-free oxidation product. The CO{sub 2} absorbent is thereafter separated for further processing. A process and system are also disclosed in which the waste materials are contacted with a reactive medium such as lime and product treatment as described. 8 figs.

  7. Technical area status report for low-level mixed waste final waste forms. Volume 2, Appendices

    SciTech Connect (OSTI)

    Mayberry, J.L.; Huebner, T.L.; Ross, W.; Nakaoka, R.; Schumacher, R.; Cunnane, J.; Singh, D.; Darnell, R.; Greenhalgh, W.

    1993-08-01

    This report presents information on low-level mixed waste forms.The descriptions of the low-level mixed waste (LLMW) streams that are considered by the Mixed Waste Integrated Program (MWIP) are given in Appendix A. This information was taken from descriptions generated by the Mixed Waste Treatment Program (MWTP). Appendix B provides a list of characteristic properties initially considered by the Final Waste Form (FWF) Working Group (WG). A description of facilities available to test the various FWFs discussed in Volume I of DOE/MWIP-3 are given in Appendix C. Appendix D provides a summary of numerous articles that were reviewed on testing of FWFS. Information that was collected by the tests on the characteristic properties considered in this report are documented in Appendix D. The articles reviewed are not a comprehensive list, but are provided to give an indication of the data that are available.

  8. Waste Encapsulation and Storage Facility - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    300 Area 324 Building 325 Building 400 AreaFast Flux Test Facility 618-10 and 618-11 Burial Grounds 700 Area B Plant B Reactor C Reactor Canister Storage Building and Interim ...

  9. 324 Building Compliance Project: Selection and evaluation of alternatives for the removal of solid remote-handled mixed wastes from the 324 Building

    SciTech Connect (OSTI)

    Ross, W.A.; Bierschbach, M.C.; Dukelow, J.S. Jr.

    1995-06-01

    Six alternatives for the interim storage of remote-handled mixed wastes from the 324 Building on the Hanford Site have been identified and evaluated. The alternatives focus on the interim storage facility and include use of existing facilities in the 200 Area, the construction of new facilities, and the vitrification of the wastes within the 324 Building to remove the majority of the wastes from under RCRA regulations. The six alternatives are summarized in Table S.1, which identifies the primary facilities to be utilized, the anticipated schedule for removal of the wastes, the costs of the transfer from 324 Building to the interim storage facility (including any capital costs), and an initial risk comparison of the alternatives. A recently negotiated Tri-Party Agreement (TPA) change requires the last of the mixed wastes to be removed by May 1999. The ability to use an existing facility reduces the costs since it eliminates the need for new capital construction. The basic regulatory approvals for the storage of mixed wastes are in place for the PUREX facility, but the Form HI permit will need some minor modifications since the 324 Building wastes have some additional characteristic waste codes and the current permit limits storage of wastes to those from the facility itself. Regulatory reviews have indicated that it will be best to use the tunnels to store the wastes. The PUREX alternatives will only provide storage for about 65% of the wastes. This results from the current schedule of the B-Cell Clean Out Project, which projects that dispersible debris will continue to be collected in small quantities until the year 2000. The remaining fraction of the wastes will then be stored in another facility. Central Waste Complex (CWC) is currently proposed for that residual waste storage; however, other options may also be available.

  10. Classification methodology for tritiated waste requiring interim storage

    SciTech Connect (OSTI)

    Cana, D.; Dall'ava, D.

    2015-03-15

    Fusion machines like the ITER experimental research facility will use tritium as fuel. Therefore, most of the solid radioactive waste will result not only from activation by 14 MeV neutrons, but also from contamination by tritium. As a consequence, optimizing the treatment process for waste containing tritium (tritiated waste) is a major challenge. This paper summarizes the studies conducted in France within the framework of the French national plan for the management of radioactive materials and waste. The paper recommends a reference program for managing this waste based on its sorting, treatment and packaging by the producer. It also recommends setting up a 50-year temporary storage facility to allow for tritium decay and designing future disposal facilities using tritiated radwaste characteristics as input data. This paper first describes this waste program and then details an optimized classification methodology which takes into account tritium decay over a 50-year storage period. The paper also describes a specific application for purely tritiated waste and discusses the set-up expected to be implemented for ITER decommissioning waste (current assumption). Comparison between this optimized approach and other viable detritiation techniques will be drawn. (authors)

  11. United States National Waste Terminal Storage argillaceous rock studies

    SciTech Connect (OSTI)

    Brunton, G.D.

    1981-01-01

    The past and present argillaceous rock studies for the US National Waste Terminal Storage Program consist of: (1) evaluation of the geological characteristics of several widespread argillaceous formations in the United States; (2) laboratory studies of the physical and chemical properties of selected argillaceous rock samples; and (3) two full-scale in situ surface heater experiments that simulate the emplacement of heat-generating radioactive waste in argillaceous rock.

  12. Mixed and Low-Level Waste Treatment Facility Project

    SciTech Connect (OSTI)

    Not Available

    1992-04-01

    Mixed and low-level wastes generated at the Idaho National Engineering Laboratory (INEL) are required to be managed according to applicable State and Federal regulations, and Department of Energy Orders that provide for the protection of human health and the environment. The Mixed and Low-Level Waste Treatment Facility Project was chartered in 1991, by the Department of Energy to provide treatment capability for these mixed and low-level waste streams. The first project task consisted of conducting engineering studies to identify the waste streams, their potential treatment strategies, and the requirements that would be imposed on the waste streams and the facilities used to process them. This report documents those studies so the project can continue with an evaluation of programmatic options, system tradeoff studies, and the conceptual design phase of the project. This report, appendix B, comprises the engineering design files for this project study. The engineering design files document each waste steam, its characteristics, and identified treatment strategies.

  13. Mixed and Low-Level Waste Treatment Facility project

    SciTech Connect (OSTI)

    Not Available

    1992-04-01

    Mixed and low-level wastes generated at the Idaho National Engineering Laboratory (INEL) are required to be managed according to applicable State and Federal regulations, and Department of Energy Orders that provide for the protection of human health and the environment. The Mixed and Low-Level Waste Treatment Facility Project was chartered in 1991, by the Department of Energy to provide treatment capability for these mixed and low-level waste streams. The first project task consisted of conducting engineering studies to identify the waste streams, their potential treatment strategies, and the requirements that would be imposed on the waste streams and the facilities used to process them. This report, Appendix A, Environmental Regulatory Planning Documentation, identifies the regulatory requirements that would be imposed on the operation or construction of a facility designed to process the INEL's waste streams. These requirements are contained in five reports that discuss the following topics: (1) an environmental compliance plan and schedule, (2) National Environmental Policy Act requirements, (3) preliminary siting requirements, (4) regulatory justification for the project, and (5) health and safety criteria.

  14. U.S. Department of Energy Awards Contracts for Waste Storage...

    Energy Savers [EERE]

    Contracts for Waste Storage Canisters for Yucca Mountain U.S. Department of Energy Awards Contracts for Waste ... of the Transportation, Aging, and Disposal (TAD) canister system. ...

  15. A Canadian Solution for Management of Mixed Liquid Waste - 13384

    SciTech Connect (OSTI)

    Suryanarayan, Sriram; Husain, Aamir

    2013-07-01

    Mixed liquid wastes (MLW) from Canadian nuclear facilities consist of solvents, PCB (Poly Chlorinated Biphenyls) and non-PCB contaminated oils and aqueous wastes. Historically, MLW drums were shipped to a licensed US facility for destruction via incineration. This option is relatively expensive considering the significant logistics and destruction costs involved. In addition, commercial waste destruction facilities in US cannot accept PCB wastes from non-US jurisdictions. Because of this, Kinectrics has recently developed a novel and flexible process for disposing both PCB as well as non-PCB contaminated MLW within Canada. This avoids the need for cross-border shipments which significantly reduces the complexity and cost for waste disposal. This paper presents an overview of the various approaches and activities undertaken to date by Kinectrics for successfully processing and disposing the MLW drums. A summary of the results, challenges and how they were overcome are also presented. (authors)

  16. RCRA Part A and Part B Permit Application for Waste Management Activities at the Nevada Test Site: Proposed Mixed Waste Disposal Unit (MWSU)

    SciTech Connect (OSTI)

    NSTec Environmental Management

    2010-07-19

    The proposed Mixed Waste Storage Unit (MWSU) will be located within the Area 5 Radioactive Waste Management Complex (RWMC). Existing facilities at the RWMC will be used to store low-level mixed waste (LLMW). Storage is required to accommodate offsite-generated LLMW shipped to the Nevada Test Site (NTS) for disposal in the new Mixed Waste Disposal Unit (MWDU) currently in the design/build stage. LLMW generated at the NTS (onsite) is currently stored on the Transuranic (TRU) Pad (TP) in Area 5 under a Mutual Consent Agreement (MCA) with the Nevada Division of Environmental Protection, Bureau of Federal Facilities (NDEP/BFF). When the proposed MWSU is permitted, the U.S. Department of Energy (DOE) will ask that NDEP revoke the MCA and onsite-generated LLMW will fall under the MWSU permit terms and conditions. The unit will also store polychlorinated biphenyl (PCB) waste and friable and non-friable asbestos waste that meets the acceptance criteria in the Waste Analysis Plan (Exhibit 2) for disposal in the MWDU. In addition to Resource Conservation and Recovery Act (RCRA) requirements, the proposed MWSU will also be subject to Department of Energy (DOE) orders and other applicable state and federal regulations. Table 1 provides the metric conversion factors used in this application. Table 2 provides a list of existing permits. Table 3 lists operational RCRA units at the NTS and their respective regulatory status.

  17. LESSONS LEARNED FROM PREVIOUS WASTE STORAGE TANK VAPOR CONTROL ATTEMPTS ON SINGLE SHELL TANK (SST) & DOUBLE SHELL TANK (DST) FARMS

    SciTech Connect (OSTI)

    BAKER, D.M.

    2004-08-03

    This report forms the basis for a feasibility study and conceptual design to control vapor emissions from waste storage tanks at the Hanford Site. The Carbtrol, Vapor Mixing, and High Efficiency Gas Absorber (HEGA) vapor controls were evaluated to determine the lessons learned from previous failed vapor control attempts. This document illustrates the resulting findings based on that evaluation.

  18. Comparison of Waste Feed Delivery Small Scale Mixing Demonstration Simulant to Hanford Waste

    SciTech Connect (OSTI)

    Wells, Beric E.; Gauglitz, Phillip A.; Rector, David R.

    2011-09-01

    The Hanford double-shell tank (DST) system provides the staging location for waste that will be transferred to the Hanford Tank Waste Treatment and Immobilization Plant (WTP). Specific WTP acceptance criteria for waste feed delivery describe the physical and chemical characteristics of the waste that must be met before the waste is transferred from the DSTs to the WTP. One of the more challenging requirements relates to the sampling and characterization of the undissolved solids (UDS) in a waste feed DST because the waste contains solid particles that settle and their concentration and relative proportion can change during the transfer of the waste in individual batches. A key uncertainty in the waste feed delivery system is the potential variation in UDS transferred in individual batches in comparison to an initial sample used for evaluating the acceptance criteria. To address this uncertainty, a number of small-scale mixing tests have been conducted as part of Washington River Protection Solutions' Small Scale Mixing Demonstration (SSMD) project to determine the performance of the DST mixing and sampling systems. A series of these tests have used a five-part simulant composed of particles of different size and density and designed to be equal or more challenging than AY-102 waste. This five-part simulant, however, has not been compared with the broad range of Hanford waste, and thus there is an additional uncertainty that this simulant may not be as challenging as the most difficult Hanford waste. The purpose of this study is to quantify how the current five-part simulant compares to all of the Hanford sludge waste, and to suggest alternate simulants that could be tested to reduce the uncertainty in applying the current testing results to potentially more challenging wastes.

  19. Comparison of Waste Feed Delivery Small Scale Mixing Demonstration Simulant to Hanford Waste

    SciTech Connect (OSTI)

    Wells, Beric E.; Gauglitz, Phillip A.; Rector, David R.

    2012-07-10

    The Hanford double-shell tank (DST) system provides the staging location for waste that will be transferred to the Hanford Tank Waste Treatment and Immobilization Plant (WTP). Specific WTP acceptance criteria for waste feed delivery describe the physical and chemical characteristics of the waste that must be met before the waste is transferred from the DSTs to the WTP. One of the more challenging requirements relates to the sampling and characterization of the undissolved solids (UDS) in a waste feed DST because the waste contains solid particles that settle and their concentration and relative proportion can change during the transfer of the waste in individual batches. A key uncertainty in the waste feed delivery system is the potential variation in UDS transferred in individual batches in comparison to an initial sample used for evaluating the acceptance criteria. To address this uncertainty, a number of small-scale mixing tests have been conducted as part of Washington River Protection Solutions' Small Scale Mixing Demonstration (SSMD) project to determine the performance of the DST mixing and sampling systems. A series of these tests have used a five-part simulant composed of particles of different size and density and designed to be equal or more challenging than AY-102 waste. This five-part simulant, however, has not been compared with the broad range of Hanford waste, and thus there is an additional uncertainty that this simulant may not be as challenging as the most difficult Hanford waste. The purpose of this study is to quantify how the current five-part simulant compares to all of the Hanford sludge waste, and to suggest alternate simulants that could be tested to reduce the uncertainty in applying the current testing results to potentially more challenging wastes.

  20. Steam Reforming of Low-Level Mixed Waste

    SciTech Connect (OSTI)

    1998-01-01

    Under DOE Contract No. DE-AR21-95MC32091, Steam Reforming of Low-Level Mixed Waste, ThermoChem has successfully designed, fabricated and operated a nominal 90 pound per hour Process Development Unit (PDU) on various low-level mixed waste surrogates. The design construction, and testing of the PDU as well as performance and economic projections for a 500- lb/hr demonstration and commercial system are described. The overall system offers an environmentally safe, non-incinerating, cost-effective, and publicly acceptable method of processing LLMW. The steam-reforming technology was ranked the No. 1 non-incineration technology for destruction of hazardous organic wastes in a study commissioned by the Mixed Waste Focus Area published April 1997.1 The ThermoChem steam-reforming system has been developed over the last 13 years culminating in this successful test campaign on LLMW surrogates. Six surrogates were successfidly tested including a 750-hour test on material simulating a PCB- and Uranium- contaminated solid waste found at the Portsmouth Gaseous Diffusion Plant. The test results indicated essentially total (>99.9999oA) destruction of RCRA and TSCA hazardous halogenated organics, significant levels of volume reduction (> 400 to 1), and retention of radlonuclides in the volume-reduced solids. Cost studies have shown the steam-reforming system to be very cost competitive with more conventional and other emerging technologies.

  1. Mixed Waste Integrated Program Quality Assurance requirements plan

    SciTech Connect (OSTI)

    Not Available

    1994-04-15

    Mixed Waste Integrated Program (MWIP) is sponsored by the US Department of Energy (DOE), Office of Technology Development, Waste Management Division. The strategic objectives of MWIP are defined in the Mixed Waste Integrated Program Strategic Plan, and expanded upon in the MWIP Program Management Plan. This MWIP Quality Assurance Requirement Plan (QARP) applies to mixed waste treatment technologies involving both hazardous and radioactive constituents. As a DOE organization, MWIP is required to develop, implement, and maintain a written Quality Assurance Program in accordance with DOE Order 4700.1 Project Management System, DOE Order 5700.6C, Quality Assurance, DOE Order 5820.2A Radioactive Waste Management, ASME NQA-1 Quality Assurance Program Requirements for Nuclear Facilities and ANSI/ASQC E4-19xx Specifications and Guidelines for Quality Systems for Environmental Data Collection and Environmental Technology Programs. The purpose of the MWIP QA program is to establish controls which address the requirements in 5700.6C, with the intent to minimize risks and potential environmental impacts; and to maximize environmental protection, health, safety, reliability, and performance in all program activities. QA program controls are established to assure that each participating organization conducts its activities in a manner consistent with risks posed by those activities.

  2. Waste Encapsulation and Storage Facility (WESF) Hazards Assessment

    SciTech Connect (OSTI)

    COVEY, L.I.

    2000-11-28

    This report documents the hazards assessment for the Waste Encapsulation and Storage Facility (WESF) located on the U.S. Department of Energy (DOE) Hanford Site. This hazards assessment was conducted to provide the emergency planning technical basis for WESF. DOE Orders require an emergency planning hazards assessment for each facility that has the potential to reach or exceed the lowest level emergency classification.

  3. 2013-08 "Waste Isolation Pilot Plant Storage for LANL"

    Broader source: Energy.gov [DOE]

    Approved July 31, 2013 The intent of this recommendation is that DOE/EM and WIPP set their priorities for the remaining storage facilities at WIPP to ensure that there will be enough capacity to hold all TRU waste remaining at LANL and that the current disposal schedules can be met.

  4. An Adaptive, Consent-Based Path to Nuclear Waste Storage and...

    Office of Environmental Management (EM)

    An Adaptive, Consent-Based Path to Nuclear Waste Storage and Disposal Solutions An Adaptive, Consent-Based Path to Nuclear Waste Storage and Disposal Solutions February 12, 2014 - ...

  5. Mixed and low-level waste treatment facility project

    SciTech Connect (OSTI)

    Not Available

    1992-04-01

    The technology information provided in this report is only the first step toward the identification and selection of process systems that may be recommended for a proposed mixed and low-level waste treatment facility. More specific information on each technology will be required to conduct the system and equipment tradeoff studies that will follow these preengineering studies. For example, capacity, maintainability, reliability, cost, applicability to specific waste streams, and technology availability must be further defined. This report does not currently contain all needed information; however, all major technologies considered to be potentially applicable to the treatment of mixed and low-level waste are identified and described herein. Future reports will seek to improve the depth of information on technologies.

  6. Design and Fabrication of a Transportable Vitrification System for Mixed Waste Processing

    SciTech Connect (OSTI)

    Whitehouse, J.C.; Jantzen, C.M.; Van Ryn, F.R.; Davis, D.H.

    1995-04-06

    The stabilization and disposal of mixed wastes, which contain both hazardous and radioactive materials, is a significant waste management challenge to the DOE complex.

  7. Review of private sector treatment, storage, and disposal capacity for radioactive waste. Revision 1

    SciTech Connect (OSTI)

    Smith, M.; Harris, J.G.; Moore-Mayne, S.; Mayes, R.; Naretto, C.

    1995-04-14

    This report is an update of a report that summarized the current and near-term commercial and disposal of radioactive and mixed waste. This report was capacity for the treatment, storage, dating and written for the Idaho National Engineering Laboratory (INEL) with the objective of updating and expanding the report entitled ``Review of Private Sector Treatment, Storage, and Disposal Capacity for Radioactive Waste``, (INEL-95/0020, January 1995). The capacity to process radioactively-contaminated protective clothing and/or respirators was added to the list of private sector capabilities to be assessed. Of the 20 companies surveyed in the previous report, 14 responded to the request for additional information, five did not respond, and one asked to be deleted from the survey. One additional company was identified as being capable of performing LLMW treatability studies and six were identified as providers of laundering services for radioactively-contaminated protective clothing and/or respirators.

  8. Glassy slags as novel waste forms for remediating mixed wastes with high metal contents

    SciTech Connect (OSTI)

    Feng, X.; Wronkiewicz, D.J.; Bates, J.K.; Brown, N.R.; Buck, E.C.; Gong, M.; Ebert, W.L.

    1994-03-01

    Argonne National Laboratory (ANL) is developing a glassy slag final waste form for the remediation of low-level radioactive and mixed wastes with high metal contents. This waste form is composed of various crystalline and metal oxide phases embedded in a silicate glass phase. This work indicates that glassy slag shows promise as final waste form because (1) it has similar or better chemical durability than high-level nuclear waste (HLW) glasses, (2) it can incorporate large amounts of metal wastes, (3) it can incorporate waste streams having low contents of flux components (boron and alkalis), (4) it has less stringent processing requirements (e.g., viscosity and electric conductivity) than glass waste forms, (5) its production can require little or no purchased additives, which can result in greater reduction in waste volume and overall treatment costs. By using glassy slag waste forms, minimum additive waste stabilization approach can be applied to a much wider range of waste streams than those amenable only to glass waste forms.

  9. Development of a Transportable Vitrification System for Mixed Waste

    SciTech Connect (OSTI)

    Whitehouse, J.C.; Jantzen, C.M.; Bickford, D.F.; Kielpinski, A.L.; Helton, B.D.; Van Ryn, F.

    1995-01-13

    The US DOE through the Mixed Waste Integrated Program, has identified a need to move mixed waste vitrification technology from the laboratory to the field as rapidly as possible. A great deal of work over the last few years has shown the feasibility of immobilizing selected hazardous waste streams in a vitrified product. Lab-scale work has been extended to pilot-scale tests, usually with surrogates of the actual waste. DOE felt that the technology was mature enough to allow demonstration in the field, on actual wastes, with units that would be prototypic of full sized waste treatment equipment. To this end, DOE`s Office of Technology Development sponsored the Westinghouse Savannah River Company (WSRC) to specify, procure, test, and operate a field scale demonstration using mobile equipment. Oak Ridge Reservation was chosen as the initial location for the field demonstration and Martin Marietta Reservation was chosen as the initial location for the field demonstration and Martin Marietta Energy Systems (MMES) tasked with all permitting, site preparation, and field support activities. During September 1993, WSRC used a ``Vendor Forum`` to solicit preliminary proposals for the Transportable Vitrification System (TVS). A number of quality proposals were received and evaluated. A vendor was selected and detailed negotiations were completed in August 1994, at which time a contract was signed for the TVS. In parallel, WSRC opened a dialogue with MMES to explore candidate waste streams at the Oak Ridge Reservation for the first TVS vitrification campaign. After some preliminary work, a group of waste water sludges were selected. The first of these to be demonstrated with the TVS will be the West End Treatment Facility (WETF) sludge. This paper describes the development of the specification for the TVS, the design and construction activities to date, and ongoing efforts for permitting and site support. The schedule for field application is also discussed.

  10. US Department of Energy interim mixed waste inventory report: Waste streams, treatment capacities and technologies: Volume 3, Site specific---Illinois through New York

    SciTech Connect (OSTI)

    Not Available

    1993-04-01

    The Department of Energy (DOE) has prepared this report to provide an inventory of its mixed wastes and treatment capacities and technologies in response to Section 105(a) of the Federal Facility Compliance act (FFCAct) of 1992 (Pub. L. No. 102-386). As required by the FFCAct-1992, this report provides site-specific information on DOE`s mixed waste streams and a general review of available and planned treatment facilities for mixed wastes for the following sites: Argonne National Laboratory-East; Site A/plot M in Palos Forest Preserve, Illinois; Ames Laboratory; Paducah Gaseous Diffusion Plant; Portsmouth Naval Shipyard; Kansas City Plant; University of Missouri; Weldon Springs Site, St. Charles, Missouri; Nevada Test Site; Middlesex Sampling Plant, Middlesex, New Jersey; Princeton Plasma Physics Laboratory; LANL; Sandia national laboratory; Brookhaven National Laboratory; Colonie Interim Storage Site, Colonie, New York; Knolls Atomic Power Laboratory; Knolls Atomic Power Laboratory-Kesselring Site; and West Valley Demonstration Project.

  11. VAC*TRAX - Thermal desorption for mixed wastes

    SciTech Connect (OSTI)

    McElwee, M.J.; Palmer, C.R.

    1995-12-01

    The patented VAC*TRAX process was designed in response to the need to remove organic constituents from mixed waste, waste that contains both a hazardous (RCRA or TSCA regulated) component and a radioactive component. Separation of the mixed waste into its hazardous and radioactive components allows for ultimate disposal of the material at existing, permitted facilities. The VAC*TRAX technology consists of a jacketed vacuum dryer followed by a condensing train. Solids are placed in the dryer and indirectly heated to temperatures as high as 260{degrees}C, while a strong vacuum (down to 50 mm Hg absolute pressure) is applied to the system and the dryer is purged with a nitrogen carrier gas. The organic contaminants in the solids are thermally desorbed, swept up in the carrier gas and into the condensing train where they are cooled and recovered. The dryer is fitted with a filtration system that keeps the radioactive constituents from migrating to the condensate. As such, the waste is separated into hazardous liquid and radioactive solid components, allowing for disposal of these streams at a permitted incinerator or a radioactive materials landfill, respectively. The VAC*TRAX system is designed to be highly mobile, while minimizing the operational costs with a simple, robust process. These factors allow for treatment of small waste streams at a reasonable cost. This paper describes the VAC*TRAX thermal desorption process, as well as results from the pilot testing program. Also, the design and application of the full-scale treatment system is presented. Materials tested to date include spiked soil and debris, power plant trash and sludge contaminated with solvents, PCB contaminated soil, solvent-contaminated uranium mill-tailings, and solvent and PCB-contaminated sludge and trash. Over 70 test runs have been performed using the pilot VAC*TRAX system, with more than 80% of the tests using mixed waste as the feed material.

  12. VAC*TRAX - thermal desorption for mixed wastes

    SciTech Connect (OSTI)

    McElwee, M.J.; Palmer, C.R.

    1995-10-01

    The patented VAC*TRAX process was designed in response to the need to remove organic constituents from mixed waste, waste that contains both a hazardous (RCRA or TSCA regulated) component and a radioactive component. Separation of the mixed waste into its hazardous and radioactive components allows for ultimate disposal of the material at existing, permitted facilities. The VAC*TRAX technology consists of a jacketed vacuum dryer followed by a condensing train. Solids are placed in the dryer and indirectly heated to temperatures as high as 2600{degrees}C, while a strong vacuum (down to 50 mm Hg absolute pressure) is applied to the system and the dryer is purged with a nitrogen carrier gas. The organic contaminants in the solids are thermally desorbed, swept up in the carrier gas and into the condensing train where they are cooled and recovered. The dryer is fitted with a filtration system that keeps the radioactive constituents from migrating to the condensate. As such, the waste is separated into hazardous liquid and radioactive solid components, allowing for disposal of these streams at a permitted incinerator or a radioactive materials landfill, respectively. The VAC*TRAX system is designed to be highly mobile, while minimizing the operational costs with a simple, robust process. These factors allow for treatment of small waste streams at a reasonable cost.

  13. Mixed Waste Focus Area: Department of Energy complex needs report

    SciTech Connect (OSTI)

    Roach, J.A.

    1995-11-16

    The Assistant Secretary for the Office of Environmental Management (EM) at the US Department of Energy (DOE) initiated a new approach in August of 1993 to environmental research and technology development. A key feature of this new approach included establishment of the Mixed Waste Characterization, Treatment, and Disposal Focus Area (MWFA). The mission of the MWFA is to identify, develop, and implement needed technologies such that the major environmental management problems related to meeting DOE`s commitments for treatment of mixed wastes under the Federal Facility Compliance Act (FFCA), and in accordance with the Land Disposal Restrictions (LDR) of the Resource Conservation and Recovery Act (RCRA), can be addressed, while cost-effectively expending the funding resources. To define the deficiencies or needs of the EM customers, the MWFA analyzed Proposed Site Treatment Plans (PSTPs), as well as other applicable documents, and conducted site visits throughout the summer of 1995. Representatives from the Office of Waste Management (EM-30), the Office of Environmental Restoration (EM-40), and the Office of Facility Transition and Management (EM-60) at each site visited were requested to consult with the Focus Area to collaboratively define their technology needs. This report documents the needs, deficiencies, technology gaps, and opportunities for expedited treatment activities that were identified during the site visit process. The defined deficiencies and needs are categorized by waste type, namely Wastewaters, Combustible Organics, Sludges/Soils, Debris/Solids, and Unique Wastes, and will be prioritized based on the relative affect the deficiency has on the DOE Complex.

  14. METHODOLOGY AND CALCULATIONS FOR THE ASSIGNMENT OF WASTE GROUPS FOR THE LARGE UNDERGROUND WASTE STORAGE TANKS AT THE HANFORD SITE

    SciTech Connect (OSTI)

    WEBER RA

    2009-01-16

    The Hanford Site contains 177 large underground radioactive waste storage tanks (28 double-shell tanks and 149 single-shell tanks). These tanks are categorized into one of three waste groups (A, B, and C) based on their waste and tank characteristics. These waste group assignments reflect a tank's propensity to retain a significant volume of flammable gases and the potential of the waste to release retained gas by a buoyant displacement gas release event. Assignments of waste groups to the 177 double-shell tanks and single-shell tanks, as reported in this document, are based on a Monte Carlo analysis of three criteria. The first criterion is the headspace flammable gas concentration following release of retained gas. This criterion determines whether the tank contains sufficient retained gas such that the well-mixed headspace flammable gas concentration would reach 100% of the lower flammability limit if the entire tank's retained gas were released. If the volume of retained gas is not sufficient to reach 100% of the lower flammability limit, then flammable conditions cannot be reached and the tank is classified as a waste group C tank independent of the method the gas is released. The second criterion is the energy ratio and considers whether there is sufficient supernatant on top of the saturated solids such that gas-bearing solids have the potential energy required to break up the material and release gas. Tanks that are not waste group C tanks and that have an energy ratio < 3.0 do not have sufficient potential energy to break up material and release gas and are assigned to waste group B. These tanks are considered to represent a potential induced flammable gas release hazard, but no spontaneous buoyant displacement flammable gas release hazard. Tanks that are not waste group C tanks and have an energy ratio {ge} 3.0, but that pass the third criterion (buoyancy ratio < 1.0, see below) are also assigned to waste group B. Even though the designation as a waste

  15. METHODOLOGY AND CALCULATIONS FOR THE ASSIGNMENT OF WASTE GROUPS FOR THE LARGE UNDERGROUND WASTE STORAGE TANKS AT THE HANFORD SITE

    SciTech Connect (OSTI)

    FOWLER KD

    2007-12-27

    This document categorizes each of the large waste storage tanks into one of several categories based on each tank's waste characteristics. These waste group assignments reflect a tank's propensity to retain a significant volume of flammable gases and the potential of the waste to release retained gas by a buoyant displacement event. Revision 7 is the annual update of the calculations of the flammable gas Waste Groups for DSTs and SSTs. The Hanford Site contains 177 large underground radioactive waste storage tanks (28 double-shell tanks and 149 single-shell tanks). These tanks are categorized into one of three waste groups (A, B, and C) based on their waste and tank characteristics. These waste group assignments reflect a tank's propensity to retain a significant volume of flammable gases and the potential of the waste to release retained gas by a buoyant displacement gas release event. Assignments of waste groups to the 177 double-shell tanks and single-shell tanks, as reported in this document, are based on a Monte Carlo analysis of three criteria. The first criterion is the headspace flammable gas concentration following release of retained gas. This criterion determines whether the tank contains sufficient retained gas such that the well-mixed headspace flammable gas concentration would reach 100% of the lower flammability limit if the entire tank's retained gas were released. If the volume of retained gas is not sufficient to reach 100% of the lower flammability limit, then flammable conditions cannot be reached and the tank is classified as a waste group C tank independent of the method the gas is released. The second criterion is the energy ratio and considers whether there is sufficient supernatant on top of the saturated solids such that gas-bearing solids have the potential energy required to break up the material and release gas. Tanks that are not waste group C tanks and that have an energy ratio < 3.0 do not have sufficient potential energy to break up

  16. Foreign programs for the storage of spent nuclear power plant fuels, high-level waste canisters and transuranic wastes

    SciTech Connect (OSTI)

    Harmon, K.M.; Johnson, A.B. Jr.

    1984-04-01

    The various national programs for developing and applying technology for the interim storage of spent fuel, high-level radioactive waste, and TRU wastes are summarized. Primary emphasis of the report is on dry storage techniques for uranium dioxide fuels, but data are also provided concerning pool storage.

  17. Macroencapsulation of mixed waste debris at the Hanford Nuclear Reservation -- Final project report by AST Environmental Services, LLC

    SciTech Connect (OSTI)

    Baker, T.L.

    1998-02-25

    This report summarizes the results of a full-scale demonstration of a high density polyethylene (HDPE) package, manufactured by Arrow Construction, Inc. of Montgomery, Alabama. The HDPE package, called ARROW-PAK, was designed and patented by Arrow as both a method to macroencapsulation of radioactively contaminated lead and as an improved form of waste package for treatment and interim and final storage and/or disposal of drums of mixed waste. Mixed waste is waste that is radioactive, and meets the criteria established by the United States Environmental Protection Agency (US EPA) for a hazardous material. Results from previous testing conducted for the Department of Energy (DOE) at the Idaho National Engineering Laboratory in 1994 found that the ARROW-PAK fabrication process produces an HDPE package that passes all helium leak tests and drop tests, and is fabricated with materials impervious to the types of environmental factors encountered during the lifetime of the ARROW-PAK, estimated to be from 100 to 300 years. Arrow Construction, Inc. has successfully completed full-scale demonstration of its ARROW-PAK mixed waste macroencapsulation treatment unit at the DOE Hanford Site. This testing was conducted in accordance with Radiological Work Permit No. T-860, applicable project plans and procedures, and in close consultation with Waste Management Federal Services of Hanford, Inc.`s project management, health and safety, and quality assurance representatives. The ARROW-PAK field demonstration successfully treated 880 drums of mixed waste debris feedstock which were compacted and placed in 149 70-gallon overpack drums prior to macroencapsulation in accordance with the US EPA Alternate Debris Treatment Standards, 40 CFR 268.45. Based on all of the results, the ARROW-PAK process provides an effective treatment, storage and/or disposal option that compares favorably with current mixed waste management practices.

  18. Scaled Testing to Evaluate Pulse Jet Mixer Performance in Waste Treatment Plant Mixing Vessels

    SciTech Connect (OSTI)

    Fort, James A.; Meyer, Perry A.; Bamberger, Judith A.; Enderlin, Carl W.; Scott, Paul A.; Minette, Michael J.; Gauglitz, Phillip A.

    2010-03-07

    The Waste Treatment and Immobilization Plant (WTP) at Hanford is being designed and built to pre-treat and vitrify the waste in Hanford’s 177 underground waste storage tanks. Numerous process vessels will hold waste at various stages in the WTP. These vessels have pulse jet mixer (PJM) systems. A test program was developed to evaluate the adequacy of mixing system designs in the solids-containing vessels in the WTP. The program focused mainly on non-cohesive solids behavior. Specifically, the program addressed the effectiveness of the mixing systems to suspend settled solids off the vessel bottom, and distribute the solids vertically. Experiments were conducted at three scales using various particulate simulants. A range of solids loadings and operational parameters were evaluated, including jet velocity, pulse volume, and duty cycle. In place of actual PJMs, the tests used direct injection from tubes with suction at the top of the tank fluid. This gave better control over the discharge duration and duty cycle and simplified the facility requirements. The mixing system configurations represented in testing varied from 4 to 12 PJMs with various jet nozzle sizes. In this way the results collected could be applied to the broad range of WTP vessels with varying geometrical configurations and planned operating conditions. Data for “just-suspended velocity”, solids cloud height, and solids concentration vertical profile were collected, analyzed, and correlated. The correlations were successfully benchmarked against previous large-scale test results, then applied to the WTP vessels using reasonable assumptions of anticipated waste properties to evaluate adequacy of the existing mixing system designs.

  19. Molten salt processing of mixed wastes with offgas condensation

    SciTech Connect (OSTI)

    Cooper, J.F.; Brummond, W.; Celeste, J.; Farmer, J.; Hoenig, C.; Krikorian, O.H.; Upadhye, R. ); Gay, R.L.; Stewart, A.; Yosim, S. . Energy Systems Group)

    1991-05-13

    We are developing an advanced process for treatment of mixed wastes in molten salt media at temperatures of 700--1000{degrees}C. Waste destruction has been demonstrated in a single stage oxidation process, with destruction efficiencies above 99.9999% for many waste categories. The molten salt provides a heat transfer medium, prevents thermal surges, and functions as an in situ scrubber to transform the acid-gas forming components of the waste into neutral salts and immobilizes potentially fugitive materials by a combination of particle wetting, encapsulation and chemical dissolution and solvation. Because the offgas is collected and assayed before release, and wastes containing toxic and radioactive materials are treated while immobilized in a condensed phase, the process avoids the problems sometimes associated with incineration processes. We are studying a potentially improved modification of this process, which treats oxidizable wastes in two stages: pyrolysis followed by catalyzed molten salt oxidation of the pyrolysis gases at ca. 700{degrees}C. 15 refs., 5 figs., 1 tab.

  20. Vitrification development plan for US Department of Energy mixed wastes

    SciTech Connect (OSTI)

    Peters, R.; Lucerna, J.; Plodinec, M.J.

    1993-10-01

    This document is a general plan for conducting vitrification development for application to mixed wastes owned by the US Department of Energy. The emphasis is a description and discussion of the data needs to proceed through various stages of development. These stages are (1) screening at a waste site to determine which streams should be vitrified, (2) waste characterization and analysis, (3) waste form development and treatability studies, (4) process engineering development, (5) flowsheet and technical specifications for treatment processes, and (6) integrated pilot-scale demonstration. Appendices provide sample test plans for various stages of the vitrification development process. This plan is directed at thermal treatments which produce waste glass. However, the study is still applicable to the broader realm of thermal treatment since it deals with issues such as off-gas characterization and waste characterization that are not necessarily specific to vitrification. The purpose is to provide those exploring or considering vitrification with information concerning the kinds of data that are needed, the way the data are obtained, and the way the data are used. This will provide guidance to those who need to prioritize data needs to fit schedules and budgets. Knowledge of data needs also permits managers and planners to estimate resource requirements for vitrification development.

  1. Pipe overpack container for trasuranic waste storage and shipment

    DOE Patents [OSTI]

    Geinitz, Richard R.; Thorp, Donald T.; Rivera, Michael A.

    1999-01-01

    A Pipe Overpack Container for transuranic waste storage and shipment. The system consists of a vented pipe component which is positioned in a vented, insulated 55 gallon steel drum. Both the vented pipe component and the insulated drum are capable of being secured to prevent the contents from leaving the vessel. The vented pipe component is constructed of 1/4 inch stainless steel to provide radiation shielding. Thus, allowing shipment having high Americium-241 content. Several Pipe Overpack Containers are then positioned in a type B, Nuclear Regulatory Commission (NRC) approved, container. In the current embodiment, a TRUPACT-II container was employed and a maximum of fourteen Pipe Overpack Containers were placed in the TRUPACT-II. The combination received NRC approval for the shipment and storage of transuranic waste.

  2. Effect of viscosity on seismic response of waste storage tanks

    SciTech Connect (OSTI)

    Tang, Yu; Uras, R.A.; Chang, Yao-Wen

    1992-06-01

    The dynamic response of liquid-storage tanks subjected to harmonic excitations and earthquake ground motions has been studied. A rigid tank of negligible mass, rigidly supported at the base having a diameter of 50 ft. and fluid height of 20.4 ft. was used in the computer analysis. The liquid is assumed to have a density of 1.5 g/ml. Viscosity values, {mu} = 60, 200, 100, and 10,000 cP, were used in the numerical analyses to study the effects of viscosity on sloshing wave height, impulsive and convective pressure on the tank wall, base shear and base moments. Harmonic excitations as well as earthquake ground motions were used as input motions. The harmonic excitations used in the analyses covers a wide range of frequencies, including both the resonant and non-resonant frequencies. Two earthquake motions were used. One matches the Newmark-Hall median response spectrum and is anchored at 0.24 g for a rock site with a damping of 2% and a time duration of 10 s. The other is the 1978 Tabas earthquake which had a peak ZPA of 0.81 g and a time duration of 29 s. A small tank, about 1/15 the size of the typical waste storage tank, was used in the harmonic excitation study to investigate the effect of viscosity on the response of liquid-storage tanks and how the viscosity effect is affected by the size of the storage tank. The results of this study show that for the typical waste storage tank subjected to earthquake motions, the effect of viscosity on sloshing wave height and impulsive and convective pressures is very small and can be neglected. For viscosity effect to become noticeable in the response of the typical waste storage tank, the waste viscosity must be greater than 10,000 cP. This value is far greater than the estimated viscosity value of the high level wastes, which may range from 60 to 200 cP for some tanks.

  3. Electromagnetic mixed waste processing system for asbestos decontamination

    SciTech Connect (OSTI)

    Kasevich, R.S.; Vaux, W.G.; Nocito, T.

    1995-10-01

    DOE sites contain a broad spectrum of asbestos materials (cloth, pipe lagging, sprayed insulation and other substances) which are contaminated with a combination of hazardous and radioactive wastes due to its use during the development of the U.S. nuclear weapons complex. These wastes consist of cutting oils, lubricants, solvents, PCB`s, heavy metals and radioactive contaminants. The radioactive contaminants are the activation, decay and fission products of DOE operations. The asbestos must be converted by removing and separating the hazardous and radioactive materials to prevent the formation of mixed wastes and to allow for both sanitary disposal and effective decontamination. Currently, no technology exists that can meet these sanitary and other objectives.

  4. Steam reforming of low-level mixed waste. Final report

    SciTech Connect (OSTI)

    1998-06-01

    ThermoChem has successfully designed, fabricated and operated a nominal 90 pound per hour Process Development Unit (PDU) on various low-level mixed waste surrogates. The design, construction, and testing of the PDU as well as performance and economic projections for a 300-lb/hr demonstration and commercial system are described. The overall system offers an environmentally safe, non-incinerating, cost-effective, and publicly acceptable method of processing LLMW. The steam-reforming technology was ranked the No. 1 non-incineration technology for destruction of hazardous organic wastes in a study commissioned by the Mixed Waste Focus Area and published in April 1997. The ThermoChem steam-reforming system has been developed over the last 13 years culminating in this successful test campaign on LLMW surrogates. Six surrogates were successfully tested including a 750-hour test on material simulating a PCB- and Uranium-contaminated solid waste found at the Portsmouth Gaseous Diffusion Plant. The test results indicated essentially total (> 99.9999%) destruction of RCRA and TSCA hazardous halogenated organics, significant levels of volume reduction (> 400 to 1), and retention of radionuclides in the volume-reduced solids. Economic evaluations have shown the steam-reforming system to be very cost competitive with more conventional and other emerging technologies.

  5. Environmental assessment for the Radioactive and Mixed Waste Management Facility: Sandia National Laboratories/New Mexico

    SciTech Connect (OSTI)

    Not Available

    1993-06-01

    The Department of Energy (DOE) has prepared an environmental assessment (EA) (DOE/EA-0466) under the National Environmental Policy Act (NEPA) of 1969 for the proposed completion of construction and subsequent operation of a central Radioactive and Mixed Waste Management Facility (RMWMF), in the southeastern portion of Technical Area III at Sandia National Laboratory, Albuquerque (SNLA). The RMWMF is designed to receive, store, characterize, conduct limited bench-scale treatment of, repackage, and certify low-level waste (LLW) and mixed waste (MW) (as necessary) for shipment to an offsite disposal or treatment facility. The RMWMF was partially constructed in 1989. Due to changing regulatory requirements, planned facility upgrades would be undertaken as part of the proposed action. These upgrades would include paving of road surfaces and work areas, installation of pumping equipment and lines for surface impoundment, and design and construction of air locks and truck decontamination and water treatment systems. The proposed action also includes an adjacent corrosive and reactive metals storage area, and associated roads and paving. LLW and MW generated at SNLA would be transported from the technical areas to the RMWMF in containers approved by the Department of Transportation. The RMWMF would not handle nonradioactive hazardous waste. Based on the analysis in the EA, the proposed completion of construction and operation of the RMWMF does not constitute a major Federal action significantly affecting the quality of the human environment within the meaning of NEPA. Therefore, preparation of an environmental impact statement for the proposed action is not required.

  6. C-tank transfers: Transuranic sludge removal from the C-1, C-2, and W-23 waste storage tanks at Oak Ridge National Laboratory, Oak Ridge, Tennessee

    SciTech Connect (OSTI)

    Dahl, T.L.; Lay, A.C.; Taylor, S.A.; Moore, J.W.

    1999-05-01

    Two fluidic pulse jet mixing systems were used to successfully mobilize remote-handled transuranic sludge for retrieval from three 50,000-gal horizontal waste storage tanks at Oak Ridge National Laboratory (ORNL). The results of this operation indicate that the pulse jet system should be considered for mixing and bulk retrieval of sludges in other vertical and horizontal waste tanks at ORNL and at other U.S. Department of Energy sites.

  7. Development of a computer code to predict a ventilation requirement for an underground radioactive waste storage tank

    SciTech Connect (OSTI)

    Lee, Y.J.; Dalpiaz, E.L.

    1997-08-01

    Computer code, WTVFE (Waste Tank Ventilation Flow Evaluation), has been developed to evaluate the ventilation requirement for an underground storage tank for radioactive waste. Heat generated by the radioactive waste and mixing pumps in the tank is removed mainly through the ventilation system. The heat removal process by the ventilation system includes the evaporation of water from the waste and the heat transfer by natural convection from the waste surface. Also, a portion of the heat will be removed through the soil and the air circulating through the gap between the primary and secondary tanks. The heat loss caused by evaporation is modeled based on recent evaporation test results by the Westinghouse Hanford Company using a simulated small scale waste tank. Other heat transfer phenomena are evaluated based on well established conduction and convection heat transfer relationships. 10 refs., 3 tabs.

  8. Radioactive and mixed waste - risk as a basis for waste classification. Symposium proceedings No. 2

    SciTech Connect (OSTI)

    1995-06-21

    The management of risks from radioactive and chemical materials has been a major environmental concern in the United states for the past two or three decades. Risk management of these materials encompasses the remediation of past disposal practices as well as development of appropriate strategies and controls for current and future operations. This symposium is concerned primarily with low-level radioactive wastes and mixed wastes. Individual reports were processed separately for the Department of Energy databases.

  9. Environmental assessment for the treatment of Class A low-level radioactive waste and mixed low-level waste generated by the West Valley Demonstration Project

    SciTech Connect (OSTI)

    1995-11-01

    The U.S. Department of Energy (DOE) is currently evaluating low-level radioactive waste management alternatives at the West Valley Demonstration Project (WVDP) located on the Western New York Nuclear Service Center (WNYNSC) near West Valley, New York. The WVDP`s mission is to vitrify high-level radioactive waste resulting from commercial fuel reprocessing operations that took place at the WNYNSC from 1966 to 1972. During the process of high-level waste vitrification, low-level radioactive waste (LLW) and mixed low-level waste (MILLW) will result and must be properly managed. It is estimated that the WVDP`s LLW storage facilities will be filled to capacity in 1996. In order to provide sufficient safe storage of LLW until disposal options become available and partially fulfill requirements under the Federal Facilities Compliance Act (FFCA), the DOE is proposing to use U.S. Nuclear Regulatory Commission-licensed and permitted commercial facilities in Oak Ridge, Tennessee; Clive, Utah; and Houston, Texas to treat (volume-reduce) a limited amount of Class A LLW and MLLW generated from the WVDP. Alternatives for ultimate disposal of the West Valley LLW are currently being evaluated in an environmental impact statement. This proposed action is for a limited quantity of waste, over a limited period of time, and for treatment only; this proposal does not include disposal. The proposed action consists of sorting, repacking, and loading waste at the WVDP; transporting the waste for commercial treatment; and returning the residual waste to the WVDP for interim storage. For the purposes of this assessment, environmental impacts were quantified for a five-year operating period (1996 - 2001). Alternatives to the proposed action include no action, construction of additional on-site storage facilities, construction of a treatment facility at the WVDP comparable to commercial treatment, and off-site disposal at a commercial or DOE facility.

  10. Processing of solid mixed waste containing radioactive and hazardous materials

    DOE Patents [OSTI]

    Gotovchikov, Vitaly T.; Ivanov, Alexander V.; Filippov, Eugene A.

    1998-05-12

    Apparatus for the continuous heating and melting of a solid mixed waste bearing radioactive and hazardous materials to form separate metallic, slag and gaseous phases for producing compact forms of the waste material to facilitate disposal includes a copper split water-cooled (cold) crucible as a reaction vessel for receiving the waste material. The waste material is heated by means of the combination of a plasma torch directed into the open upper portion of the cold crucible and an electromagnetic flux produced by induction coils disposed about the crucible which is transparent to electromagnetic fields. A metallic phase of the waste material is formed in a lower portion of the crucible and is removed in the form of a compact ingot suitable for recycling and further processing. A glass-like, non-metallic slag phase containing radioactive elements is also formed in the crucible and flows out of the open upper portion of the crucible into a slag ingot mold for disposal. The decomposition products of the organic and toxic materials are incinerated and converted to environmentally safe gases in the melter.

  11. Processing of solid mixed waste containing radioactive and hazardous materials

    DOE Patents [OSTI]

    Gotovchikov, V.T.; Ivanov, A.V.; Filippov, E.A.

    1998-05-12

    Apparatus for the continuous heating and melting of a solid mixed waste bearing radioactive and hazardous materials to form separate metallic, slag and gaseous phases for producing compact forms of the waste material to facilitate disposal includes a copper split water-cooled (cold) crucible as a reaction vessel for receiving the waste material. The waste material is heated by means of the combination of a plasma torch directed into the open upper portion of the cold crucible and an electromagnetic flux produced by induction coils disposed about the crucible which is transparent to electromagnetic fields. A metallic phase of the waste material is formed in a lower portion of the crucible and is removed in the form of a compact ingot suitable for recycling and further processing. A glass-like, non-metallic slag phase containing radioactive elements is also formed in the crucible and flows out of the open upper portion of the crucible into a slag ingot mold for disposal. The decomposition products of the organic and toxic materials are incinerated and converted to environmentally safe gases in the melter. 6 figs.

  12. Management of radioactive mixed wastes in commercial low-level wastes

    SciTech Connect (OSTI)

    Kempf, C.R.; MacKenzie, D.R.; Piciulo, P.L.; Bowerman, B.S.; Siskind, B.

    1986-01-01

    Potential mixed wastes in commercial low-level wastes have been identified and management options applicable to these wastes have been evaluated. Both the identification and management evaluation have necessarily been based on review of NRC and EPA regulations and recommendations. The underlying intent of both agencies is protection of man and/or environment, but differences may occur in the means by which intent is achieved. Apparent discrepancies, data gaps and unresolved issues that have surfaced during the course of this work are discussed.

  13. Radiological, physical, and chemical characterization of additional alpha contaminated and mixed low-level waste for treatment at the advanced mixed waste treatment project

    SciTech Connect (OSTI)

    Hutchinson, D.P.

    1995-07-01

    This document provides physical, chemical, and radiological descriptive information for a portion of mixed waste that is potentially available for private sector treatment. The format and contents are designed to provide treatment vendors with preliminary information on the characteristics and properties for additional candidate portions of the Idaho National Engineering Laboratory (INEL) and offsite mixed wastes not covered in the two previous characterization reports for the INEL-stored low-level alpha-contaminated and transuranic wastes. This report defines the waste, provides background information, briefly reviews the requirements of the Federal Facility Compliance Act (P.L. 102-386), and relates the Site Treatment Plans developed under the Federal Facility Compliance Act to the waste streams described herein. Each waste is summarized in a Waste Profile Sheet with text, charts, and tables of waste descriptive information for a particular waste stream. A discussion of the availability and uncertainty of data for these waste streams precedes the characterization descriptions.

  14. Analysis of accident sequences and source terms at treatment and storage facilities for waste generated by US Department of Energy waste management operations

    SciTech Connect (OSTI)

    Mueller, C.; Nabelssi, B.; Roglans-Ribas, J.; Folga, S.; Policastro, A.; Freeman, W.; Jackson, R.; Mishima, J.; Turner, S.

    1996-12-01

    This report documents the methodology, computational framework, and results of facility accident analyses performed for the US Department of Energy (DOE) Waste Management Programmatic Environmental Impact Statement (WM PEIS). The accident sequences potentially important to human health risk are specified, their frequencies assessed, and the resultant radiological and chemical source terms evaluated. A personal-computer-based computational framework and database have been developed that provide these results as input to the WM PEIS for the calculation of human health risk impacts. The WM PEIS addresses management of five waste streams in the DOE complex: low-level waste (LLW), hazardous waste (HW), high-level waste (HLW), low-level mixed waste (LLMW), and transuranic waste (TRUW). Currently projected waste generation rates, storage inventories, and treatment process throughputs have been calculated for each of the waste streams. This report summarizes the accident analyses and aggregates the key results for each of the waste streams. Source terms are estimated, and results are presented for each of the major DOE sites and facilities by WM PEIS alternative for each waste stream. Key assumptions in the development of the source terms are identified. The appendices identify the potential atmospheric release of each toxic chemical or radionuclide for each accident scenario studied. They also discuss specific accident analysis data and guidance used or consulted in this report.

  15. SCFA lead lab technical assistance at Oak Ridge Y-12 nationalsecurity complex: Evaluation of treatment and characterizationalternatives of mixed waste soil and debris at disposal area remedialaction DARA solids storage facility (SSF)

    SciTech Connect (OSTI)

    Hazen, Terry

    2002-08-26

    On July 17-18, 2002, a technical assistance team from the U.S. Department of Energy (DOE) Subsurface Contaminants Focus Area (SCFA) met with the Bechtel Jacobs Company Disposal Area Remedial Action (DARA) environmental project leader to review treatment and characterization options for the baseline for the DARA Solids Storage Facility (SSF). The technical assistance request sought suggestions from SCFA's team of technical experts with experience and expertise in soil treatment and characterization to identify and evaluate (1) alternative treatment technologies for DARA soils and debris, and (2) options for analysis of organic constituents in soil with matrix interference. Based on the recommendations, the site may also require assistance in identifying and evaluating appropriate commercial vendors.

  16. METHODS FOR DETERMINING AGITATOR MIXING REQUIREMENTS FOR A MIXING & SAMPLING FACILITY TO FEED WTP (WASTE TREATMENT PLANT)

    SciTech Connect (OSTI)

    GRIFFIN PW

    2009-08-27

    The following report is a summary of work conducted to evaluate the ability of existing correlative techniques and alternative methods to accurately estimate impeller speed and power requirements for mechanical mixers proposed for use in a mixing and sampling facility (MSF). The proposed facility would accept high level waste sludges from Hanford double-shell tanks and feed uniformly mixed high level waste to the Waste Treatment Plant. Numerous methods are evaluated and discussed, and resulting recommendations provided.

  17. Mixed-layered bismuth--oxygen--iodine materials for capture and waste disposal of radioactive iodine

    DOE Patents [OSTI]

    Krumhansl, James L; Nenoff, Tina M

    2015-01-06

    Materials and methods of synthesizing mixed-layered bismuth oxy-iodine materials, which can be synthesized in the presence of aqueous radioactive iodine species found in caustic solutions (e.g. NaOH or KOH). This technology provides a one-step process for both iodine sequestration and storage from nuclear fuel cycles. It results in materials that will be durable for repository conditions much like those found in Waste Isolation Pilot Plant (WIPP) and estimated for Yucca Mountain (YMP). By controlled reactant concentrations, optimized compositions of these mixed-layered bismuth oxy-iodine inorganic materials are produced that have both a high iodine weight percentage and a low solubility in groundwater environments.

  18. Mixed-layered bismuth-oxygen-iodine materials for capture and waste disposal of radioactive iodine

    DOE Patents [OSTI]

    Krumhansl, James L; Nenoff, Tina M

    2013-02-26

    Materials and methods of synthesizing mixed-layered bismuth oxy-iodine materials, which can be synthesized in the presence of aqueous radioactive iodine species found in caustic solutions (e.g. NaOH or KOH). This technology provides a one-step process for both iodine sequestration and storage from nuclear fuel cycles. It results in materials that will be durable for repository conditions much like those found in Waste Isolation Pilot Plant (WIPP) and estimated for Yucca Mountain (YMP). By controlled reactant concentrations, optimized compositions of these mixed-layered bismuth oxy-iodine inorganic materials are produced that have both a high iodine weight percentage and a low solubility in groundwater environments.

  19. Systems engineering identification and control of mixed waste technology development

    SciTech Connect (OSTI)

    Beitel, G.A.

    1997-08-01

    The Department of Energy (DOE) established the Mixed Waste Characterization, Treatment, and Disposal Focus Area (MWFA) to develop technologies required to meet the Department`s commitments for treatment of mixed low-level and transuranic wastes. Waste treatment includes all necessary steps from generation through disposal. Systems engineering was employed to reduce programmatic risk, that is, risk of failure to meet technical commitments within cost and schedule. Customer needs (technology deficiencies) are identified from Site Treatment Plans, Consent Orders, ten year plans, Site Technical Coordinating Groups, Stakeholders, and Site Visits. The Technical Baseline, a prioritized list of technology deficiencies, forms the basis for determining which technology development activities will be supported by the MWFA. Technology Development Requirements Documents are prepared for each technology selected for development. After technologies have been successfully developed and demonstrated, they are documented in a Technology Performance Report. The Technology Performance Reports are available to any of the customers or potential users of the technology, thus closing the loop between problem identification and product development. This systematic approach to technology development and its effectiveness after 3 years is discussed in this paper.

  20. Mixed and low-level waste treatment facility project. Volume 3, Waste treatment technologies (Draft)

    SciTech Connect (OSTI)

    Not Available

    1992-04-01

    The technology information provided in this report is only the first step toward the identification and selection of process systems that may be recommended for a proposed mixed and low-level waste treatment facility. More specific information on each technology will be required to conduct the system and equipment tradeoff studies that will follow these preengineering studies. For example, capacity, maintainability, reliability, cost, applicability to specific waste streams, and technology availability must be further defined. This report does not currently contain all needed information; however, all major technologies considered to be potentially applicable to the treatment of mixed and low-level waste are identified and described herein. Future reports will seek to improve the depth of information on technologies.

  1. Comparison of Waste Feed Delivery Small Scale Mixing Demonstration Simulant to Hanford Waste

    SciTech Connect (OSTI)

    Wells, Beric E.; Gauglitz, Phillip A.; Rector, David R.

    2011-08-15

    'The Hanford double-shell tank (DST) system provides the staging location for waste feed delivery to the Hanford Tank Waste Treatment and Immobilization Plant (WTP). Hall (2008) includes WTP acceptance criteria that describe physical and chemical characteristics of the waste that must be certified as acceptable before the waste is transferred from the DSTs to the WTP. One of the more challenging requirements relates to the sampling and characterization of the undissolved solids (UDS) in a waste feed DST. The objectives of Washington River Protection Solutions' (WRPS) Small Scale Mixing Demonstration (SSMD) project are to understand and demonstrate the DST sampling and batch transfer performance at multiple scales using slurry simulants comprised of UDS particles and liquid (Townson 2009). The SSMD project utilizes geometrically scaled DST feed tanks to generate mixing, sampling, and transfer test data. In Phase 2 of the testing, RPP-49740, the 5-part simulant defined in RPP-48358 was used as the waste slurry simulant. The Phase 2 test data are being used to estimate the expected performance of the prototypic systems in the full-scale DSTs. As such, understanding of the how the small-scale systems as well as the simulant relate to the full-scale DSTs and actual waste is required. The focus of this report is comparison of the size and density of the 5-part SSMD simulant to that of the Hanford waste. This is accomplished by computing metrics for particle mobilization, suspension, settling, transfer line intake, and pipeline transfer from the characterization of the 5-part SSMD simulant and characterizations of the Hanford waste. In addition, the effects of the suspending fluid characteristics on the test results are considered, and a computational fluid dynamics tool useful to quantify uncertainties from simulant selections is discussed.'

  2. Excess Weapons Plutonium Disposition: Plutonium Packaging, Storage and Transportation and Waste Treatment, Storage and Disposal Activities

    SciTech Connect (OSTI)

    Jardine, L J; Borisov, G B

    2004-07-21

    A fifth annual Excess Weapons Plutonium Disposition meeting organized by Lawrence Livermore National Laboratory (LLNL) was held February 16-18, 2004, at the State Education Center (SEC), 4 Aerodromnya Drive, St. Petersburg, Russia. The meeting discussed Excess Weapons Plutonium Disposition topics for which LLNL has the US Technical Lead Organization responsibilities. The technical areas discussed included Radioactive Waste Treatment, Storage, and Disposal, Plutonium Oxide and Plutonium Metal Packaging, Storage and Transportation and Spent Fuel Packaging, Storage and Transportation. The meeting was conducted with a conference format using technical presentations of papers with simultaneous translation into English and Russian. There were 46 Russian attendees from 14 different Russian organizations and six non-Russian attendees, four from the US and two from France. Forty technical presentations were made. The meeting agenda is given in Appendix B and the attendance list is in Appendix C.

  3. Fire protection guide for solid waste metal drum storage

    SciTech Connect (OSTI)

    Bucci, H.M.

    1996-09-16

    This guide provides a method to assess potential fire development in drum storage facilities. The mechanism of fire propagation/spread through stored drum arrays is a complex process. It involves flame heat transfer, transient conduction,convection, and radiation between drums (stored in an array configuration). There are several phenomena which may occur when drums are exposed to fire. The most dramatic is violent lid failure which results in total lid removal. When a drum loses its lid due to fire exposure, some or all of the contents may be ejected from the drum, and both the ejected combustible material and the combustible contents remaining within the container will burn. The scope of this guide is limited to storage arrays of steel drums containing combustible (primarily Class A) and noncombustible contents. Class B combustibles may be included in small amounts as free liquid within the solid waste contents.Storage arrays, which are anticipated in this guide, include single or multi-tier palletized (steel or wood pallets) drums,high rack storage of drums, and stacked arrays of drums where plywood sheets are used between tiers. The purpose of this guide is to describe a simple methodology that estimates the consequences of a fire in drum storage arrays. The extent of fire development and the resulting heat release rates can be estimated. Release fractions applicable to this type of storage are not addressed, and the transport of contaminants away from the source is not addressed. However, such assessments require the amount of combustible material consumed and the surface area of this burning material. The methods included in this guide do provide this information.

  4. Transportable Vitrification System: Operational experience gained during vitrification of simulated mixed waste

    SciTech Connect (OSTI)

    Whitehouse, J.C.; Burket, P.R.; Crowley, D.A.; Hansen, E.K.; Jantzen, C.M.; Smith, M.E.; Singer, R.P.; Young, S.R.; Zamecnik, J.R.; Overcamp, T.J.; Pence, I.W. Jr.

    1996-11-21

    The Transportable Vitrification System (TVS) is a large-scale, fully-integrated, transportable, vitrification system for the treatment of low-level nuclear and mixed wastes in the form of sludges, soils, incinerator ash, and similar waste streams. The TVS was built to demonstrate the vitrification of actual mixed waste at U. S. Department of Energy (DOE) sites. Currently, Westinghouse Savannah River Company (WSRC) is working with Lockheed Martin Energy Systems (LMES) to apply field scale vitrification to actual mixed waste at Oak Ridge Reservation`s (ORR) K-25 Site. Prior to the application of the TVS to actual mixed waste it was tested on simulated K-25 B and C Pond waste at Clemson University. This paper describes the results of that testing and preparations for the demonstration on actual mixed waste.

  5. Project management plan for low-level mixed wastes and greater-than category 3 waste per Tri-Party Agreement M-91-10

    SciTech Connect (OSTI)

    BOUNINI, L.

    1999-06-17

    The objective of this project management plan is to define the tasks and deliverables that will support the treatment, storage, and disposal of remote-handled and large container contact-handled low-level mixed waste, and the storage of Greater-Than-Category 3 waste. The plan is submitted to fulfill the requirements of the Hanford Federal Facility Agreement and Consent Order Milestone M-91-10. The plan was developed in four steps: (1) the volumes of the applicable waste streams and the physical, dangerous, and radioactive characteristics were established using existing databases and forecasts; (2) required treatment was identified for each waste stream based on land disposal restriction treatment standards and waste characterization data; (3) alternatives for providing the required treatment were evaluated and the preferred options were selected; and (4) an acquisition plan was developed to establish the techuical, schedule, and cost baselines for providing the required treatment capabilities. The major waste streams are summarized in the table below, along with the required treatment for disposal.

  6. Project management plan for low-level mixed waste and greater-than-category 3 waste per tri-party agreement M-91-10

    SciTech Connect (OSTI)

    BOUNINI, L.

    1999-05-20

    The objective of this project management plan is to define the tasks and deliverables that will support the treatment, storage, and disposal of remote-handled and large container contact-handled low-level mixed waste, and the storage of Greater-thaw category 3 waste. The plan is submitted to fulfill the requirements of the Hanford Federal Facility Agreement and Consent Order Milestone M-91-10, The plan was developed in four steps: (1) the volumes of the applicable waste streams and the physical, dangerous, and radioactive characteristics were established using existing databases and forecasts; (2) required treatment was identified for each waste stream based on land disposal restriction treatment standards and waste characterization data; (3) alternatives for providing the required treatment were evaluated and the preferred options were selected; (4) an acquisition plan was developed to establish the technical, schedule, and cost baselines for providing the required treatment capabilities. The major waste streams are tabulated, along with the required treatment for disposal.

  7. Mixed Waste Management Facility Preliminary Safety Analysis Report. Chapters 1 to 20

    SciTech Connect (OSTI)

    Not Available

    1994-09-01

    This document provides information on waste management practices, occupational safety, and a site characterization of the Lawrence Livermore National Laboratory. A facility description, safety engineering analysis, mixed waste processing techniques, and auxiliary support systems are included.

  8. Identifying suitable "piercement" salt domes for nuclear waste storage sites

    SciTech Connect (OSTI)

    Kehle, R.

    1980-08-01

    Piercement salt domes of the northern interior salt basins of the Gulf of Mexico are being considered as permanent storage sites for both nuclear and chemically toxic wastes. The suitable domes are stable and inactive, having reached their final evolutionary configuration at least 30 million years ago. They are buried to depths far below the level to which erosion will penetrate during the prescribed storage period and are not subject to possible future reactivation. The salt cores of these domes are themselves impermeable, permitting neither the entry nor exit of ground water or other unwanted materials. In part, a stable dome may be recognized by its present geometric configuration, but conclusive proof depends on establishing its evolutionary state. The evolutionary state of a dome is obtained by reconstructing the growth history of the dome as revealed by the configuration of sedimentary strata in a large area (commonly 3,000 square miles or more) surrounding the dome. A high quality, multifold CDP reflection seismic profile across a candidate dome will provide much of the necessary information when integrated with available subsurface control. Additional seismic profiles may be required to confirm an apparent configuration of the surrounding strata and an interpreted evolutionary history. High frequency seismic data collected in the near vicinity of a dome are also needed as a supplement to the CDP data to permit accurate depiction of the configuration of shallow strata. Such data must be tied to shallow drill hole control to confirm the geologic age at which dome growth ceased. If it is determined that a dome reached a terminal configuration many millions of years ago, such a dome is incapable of reactivation and thus constitutes a stable storage site for nuclear wastes.

  9. Zero-Release Mixed Waste Process Facility Design and Testing

    SciTech Connect (OSTI)

    Richard D. Boardman; John A. Deldebbio; Robert J. Kirkham; Martin K. Clemens; Robert Geosits; Ping Wan

    2004-02-01

    A zero-release offgas cleaning system for mixed-waste thermal treatment processes has been evaluated through experimental scoping tests and process modeling. The principles can possibly be adapted to a fluidized-bed calcination or stream reforming process, a waste melter, a rotarykiln process, and possibly other waste treatment thermal processes. The basic concept of a zero-release offgas cleaning system is to recycle the bulk of the offgas stream to the thermal treatment process. A slip stream is taken off the offgas recycle to separate and purge benign constituents that may build up in the gas, such as water vapor, argon, nitrogen, and CO2. Contaminants are separated from the slip stream and returned to the thermal unit for eventual destruction or incorporation into the waste immobilization media. In the current study, a standard packed-bed scrubber, followed by gas separation membranes, is proposed for removal of contaminants from the offgas recycle slipstream. The scrub solution is continuously regenerated by cooling and precipitating sulfate, nitrate, and other salts that reach a solubility limit in the scrub solution. Mercury is also separated by the scrubber. A miscible chemical oxidizing agent was shown to effectively oxidize mercury and also NO, thus increasing their removal efficiency. The current study indicates that the proposed process is a viable option for reducing offgas emissions. Consideration of the proposed closed-system offgas cleaning loop is warranted when emissions limits are stringent, or when a reduction in the total gas emissions volume is desired. Although the current closed-loop appears to be technically feasible, economical considerations must be also be evaluated on a case-by-case basis.

  10. Voluntary Protection Program Onsite Review, Advanced Mixed Waste Treatment Project- May 2009

    Broader source: Energy.gov [DOE]

    Evaluation to determine whether Advanced Mixed Waste Treatment Project is continuing to perform at a level deserving DOE-VPP Star recognition.

  11. Chemical tailoring of steam to remediate underground mixed waste contaminents

    DOE Patents [OSTI]

    Aines, Roger D.; Udell, Kent S.; Bruton, Carol J.; Carrigan, Charles R.

    1999-01-01

    A method to simultaneously remediate mixed-waste underground contamination, such as organic liquids, metals, and radionuclides involves chemical tailoring of steam for underground injection. Gases or chemicals are injected into a high pressure steam flow being injected via one or more injection wells to contaminated soil located beyond a depth where excavation is possible. The injection of the steam with gases or chemicals mobilizes contaminants, such as metals and organics, as the steam pushes the waste through the ground toward an extraction well having subatmospheric pressure (vacuum). The steam and mobilized contaminants are drawn in a substantially horizontal direction to the extraction well and withdrawn to a treatment point above ground. The heat and boiling action of the front of the steam flow enhance the mobilizing effects of the chemical or gas additives. The method may also be utilized for immobilization of metals by using an additive in the steam which causes precipitation of the metals into clusters large enough to limit their future migration, while removing any organic contaminants.

  12. OPERATIONAL CHALLENGES IN MIXING AND TRANSFER OF HIGH YIELD STRESS SLUDGE WASTE

    SciTech Connect (OSTI)

    Caldwell, T.; Bhatt, P.

    2009-12-07

    The ability to mobilize and transport non-Newtonian waste is essential to advance the closure of highly radioactive storage tanks. Recent waste removal operations from Tank 12H at the Savannah River Site (SRS) encountered sludge mixtures with a yield stress too high to pump. The waste removal equipment for Tank 12H was designed to mobilize and transport a diluted slurry mixture through an underground 550m long (1800 ft) 0.075m diameter (3 inch) pipeline. The transfer pump was positioned in a well casing submerged in the sludge slurry. The design allowed for mobilized sludge to enter the pump suction while keeping out larger tank debris. Data from a similar tank with known rheological properties were used to size the equipment. However, after installation and startup, field data from Tank 12H confirmed the yield stress of the slurry to exceed 40 Pa, whereas the system is designed for 10 Pa. A revision to the removal strategy was required, which involved metered dilution, blending, and mixing to ensure effective and safe transfer performance. The strategy resulted in the removal of over 255,000 kgs of insoluble solids with four discrete transfer evolutions for a total transfer volume of 2400 m{sup 3} (634,000 gallons) of sludge slurry.

  13. Potential problem areas: extended storage of low-level radioactive waste

    SciTech Connect (OSTI)

    Siskind, B.

    1985-01-01

    If a state or regional compact does not have adequate disposal capacity for low-level radioactive waste (LLRW), then extended storage of certain LLRW may be necessary. The Nuclear Regulatory Commission (NRC) has contracted with Brookhaven National Laboratory to address the technical issues of extended storage. The dual objectives of this study are (1) to provide practical technical assessments for NRC to consider in evaluating specific proposals for extended storage and (2) to help ensure adequate consideration by NRC, Agreement States, and licensees of potential problems that may arise from existing or proposed extended storage practices. Storage alternatives are considered in order to characterize the likely storage environments for these wastes. In particular, the range of storage alternatives considered and being implemented by the nuclear power plant utilities is described. The properties of the waste forms and waste containers are discussed. An overview is given of the performance of the waste package and its contents during storage (e.g., radiolytic gas generation, corrosion) and of the effects of extended storage on the performance of the waste package after storage (e.g., radiation-induced embrittlement of polyethylene, the weakening of steel containers by corrosion). Additional information and actions required to address these concerns, including possible mitigative measures, are discussed. 26 refs., 1 tab.

  14. Task 1.6 - mixed waste. Topical report, April 1, 1994--September 30, 1995

    SciTech Connect (OSTI)

    1998-12-31

    For fifty years, the United States was involved in a nuclear arms race of immense proportions. During the majority of this period, the push was always to design new weapons, produce more weapons, and increase the size of the arsenal, maintaining an advantage over the opposition in order to protect U.S. interests. Now that the {open_quotes}Cold War{close_quotes} is over, we are faced with the imposing tasks of dismantling, cleaning up, and remediating the wide variety of problems created by this arms race. An overview of the current status of the total remediation effort within the DOE is presented in the DOE publication {open_quotes}ENVIRONMENTAL MANAGEMENT 1995{close_quotes} (EM 1995). Not all radioactive waste is the same though; therefore, a system was devised to categorize the different types of radioactive waste. These categories are as follows: spent fuel; high-level waste; transuranic waste; low-level waste; mixed waste; and uranium-mill tailings. Mixed waste is defined to be material contaminated with any of these categories of radioactive material plus an organic or heavy metal component. However, for this discussion, {open_quotes}mixed waste{close_quote} will pertain only to low-level mixed waste which consists of low-level radioactive waste mixed with organic solvents and or heavy metals. The area of {open_quotes}mixed-waste characterization, treatment, and disposal{close_quotes} is listed on page 6 of the EM 1995 publication as one of five focus areas for technological development, and while no more important than the others, it has become an area of critical concern for DOE. Lacking adequate technologies for treatment and disposal, the DOE stockpiled large quantities of mixed waste during the 1970s and 1980s. Legislative changes and the need for regulatory compliance have now made it expedient to develop methods of achieving final disposition for this stockpiled mixed waste.

  15. Extended storage of low-level radioactive waste: potential problem areas

    SciTech Connect (OSTI)

    Siskind, B.; Dougherty, D.R.; MacKenzie, D.R.

    1985-01-01

    If a state or state compact does not have adequate disposal capacity for low-level radioactive waste (LLRW) by 1986 as required by the Low-Level Waste Policy Act, then extended storage of certain LLRW may be necessary. The issue of extended storage of LLRW is addressed in order to determine for the Nuclear Regulatory Commission the areas of concern and the actions recommended to resolve these concerns. The focus is on the properties and behavior of the waste form and waste container. Storage alternatives are considered in order to characterize the likely storage environments for these wastes. The areas of concern about extended storage of LLRW are grouped into two categories: 1. Behavior of the waste form and/or container during storage, e.g., radiolytic gas generation, radiation-enhanced degradation of polymeric materials, and corrosion. 2. Effects of extended storage on the properties of the waste form and/or container that are important after storage (e.g., radiation-induced oxidative embrittlement of high-density polyethylene and the weakening of steel containers resulting from corrosion by the waste). The additional information and actions required to address these concerns are discussed and, in particular, it is concluded that further information is needed on the rates of corrosion of container material by Class A wastes and on the apparent dose-rate dependence of radiolytic processes in Class B and C waste packages. Modifications to the guidance for solidified wastes and high-integrity containers in NRC's Technical Position on Waste Form are recommended. 27 references.

  16. Nondestructive Waste Assay Using Gamma-Ray Active & Passive Computed Tomography. Mixed Waste Focus Area. OST Reference Number 2123

    SciTech Connect (OSTI)

    None, None

    1999-09-01

    This project was supported by the Mixed Waste Focus Area (MWFA) and the Federal Environmental Technology Center (FETC) to develop an improved nondestructive assay (NDA) capability that uses gamma-ray computed tomography and gamma-energy spectral analysis techniques to perform waste assay measurements. It was the intent of the Gamma-Ray Active & Passive Computed Tomography (A&PCT) development and demonstration project to enhance the overall utility of waste assay through the implementation of techniques that can accommodate known measurement complications, e.g., waste matrix and radioactive material distribution heterogeneities. This technology can measure the radionuclide content in all types of waste regardless of their classification as low level (LLW), transuranic (TRU) or mixed (MLLW or MTRU). The nondestructive waste assay capability needed to support Department of Energy (DOE) mixed waste characterization needs is necessarily a function of the waste form configurations in inventory. These waste form configurations exhibit a number of variables impacting assay system response that must be accounted for to ensure valid measurement data. Such variables include: matrix density, matrix elemental composition, matrix density distribution, radioactive material radionuclidic/isotopic composition, radioactive material physical/chemical form, and physical distribution in the waste matrix. Existing nondestructive assay technologies have identified capability limits with respect to these variables. Certain combinations of these variables result in waste configurations within the capability of one or more of the existing systems. Other combinations that are prevalent in the inventory are outside of the capability of such systems.

  17. Evaluation of prospective hazardous waste treatment technologies for use in processing low-level mixed wastes at Rocky Flats

    SciTech Connect (OSTI)

    McGlochlin, S.C.; Harder, R.V.; Jensen, R.T.; Pettis, S.A.; Roggenthen, D.K.

    1990-09-18

    Several technologies for destroying or decontaminating hazardous wastes were evaluated (during early 1988) as potential processes for treating low-level mixed wastes destined for destruction in the Fluidized Bed Incinerator. The processes that showed promise were retained for further consideration and placed into one (or more) of three categories based on projected availability: short, intermediate, and long-term. Three potential short-term options were identified for managing low-level mixed wastes generated or stored at the Rocky Flats Plant (operated by Rockwell International in 1988). These options are: (1) Continue storing at Rocky Flats, (2) Ship to Nevada Test Site for landfill disposal, or (3) Ship to the Idaho National Engineering Laboratory for incineration in the Waste Experimental Reduction Facility. The third option is preferable because the wastes will be destroyed. Idaho National Engineering Laboratory has received interim status for processing solid and liquid low-level mixed wastes. However, low-level mixed wastes will continue to be stored at Rocky Flats until the Department of Energy approval is received to ship to the Nevada Test Site or Idaho National Engineering Laboratory. Potential intermediate and long-term processes were identified; however, these processes should be combined into complete waste treatment systems'' that may serve as alternatives to the Fluidized Bed Incinerator. Waste treatment systems will be the subject of later work. 59 refs., 2 figs.

  18. Test procedures for polyester immobilized salt-containing surrogate mixed wastes

    SciTech Connect (OSTI)

    Biyani, R.K.; Hendrickson, D.W.

    1997-07-18

    These test procedures are written to meet the procedural needs of the Test Plan for immobilization of salt containing surrogate mixed waste using polymer resins, HNF-SD-RE-TP-026 and to ensure adequacy of conduct and collection of samples and data. This testing will demonstrate the use of four different polyester vinyl ester resins in the solidification of surrogate liquid and dry wastes, similar to some mixed wastes generated by DOE operations.

  19. Project report for the commercial disposal of mixed low-level waste debris

    SciTech Connect (OSTI)

    Andrews, G.; Balls, V.; Shea, T.; Thiesen, T.

    1994-05-01

    This report summarizes the basis for the commercial disposal of Idaho National Engineering Laboratory (INEL) mixed low-level waste (MLLW) debris and the associated activities. Mixed waste is radioactive waste plus hazardous waste as defined by the Resource Conservation and Recovery Act (RCRA). The critical factors for this project were DOE 5820.2A exemption, contracting mechanism, NEPA documentation, sampling and analysis, time limitation and transportation of waste. This report also will provide a guide or a starting place for future use of Envirocare of Utah or other private sector disposal/treatment facilities, and the lessons learned during this project.

  20. Composition and process for the encapsulation and stabilization of radioactive, hazardous and mixed wastes

    DOE Patents [OSTI]

    Kalb, P.D.; Colombo, P.

    1998-03-24

    The present invention provides a composition and process for disposal of radioactive, hazardous and mixed wastes. The present invention preferably includes a process for multibarrier encapsulation of radioactive, hazardous and mixed wastes by combining substantially simultaneously dry waste powder, a non-biodegradable thermoplastic polymer and an anhydrous additive in an extruder to form a homogeneous molten matrix. The molten matrix may be directed in a ``clean`` polyethylene liner, allowed to cool, thus forming a monolithic waste form which provides a multibarrier to the dispersion of wastes into the environment. 2 figs.

  1. Composition and process for the encapsulation and stabilization of radioactive hazardous and mixed wastes

    DOE Patents [OSTI]

    Kalb, P.D.; Colombo, P.

    1997-07-15

    The present invention provides a composition and process for disposal of radioactive, hazardous and mixed wastes. The present invention preferably includes a process for multibarrier encapsulation of radioactive, hazardous and mixed wastes by combining substantially simultaneously dry waste powder, a non-biodegradable thermoplastic polymer and an anhydrous additive in an extruder to form a homogeneous molten matrix. The molten matrix may be directed in a ``clean`` polyethylene liner, allowed to cool, thus forming a monolithic waste form which provides a multibarrier to the dispersion of wastes into the environment. 2 figs.

  2. Composition and process for the encapsulation and stabilization of radioactive, hazardous and mixed wastes

    DOE Patents [OSTI]

    Kalb, P.D.; Colombo, P.

    1999-07-20

    The present invention provides a composition and process for disposal of radioactive, hazardous and mixed wastes. The present invention preferably includes a process for multibarrier encapsulation of radioactive, hazardous and mixed wastes by combining substantially simultaneously dry waste powder, a non-biodegradable thermoplastic polymer and an anhydrous additive in an extruder to form a homogeneous molten matrix. The molten matrix may be directed in a clean'' polyethylene liner, allowed to cool, thus forming a monolithic waste form which provides a multibarrier to the dispersion of wastes into the environment. 2 figs.

  3. Composition and process for the encapsulation and stabilization of radioactive hazardous and mixed wastes

    DOE Patents [OSTI]

    Kalb, Paul D.; Colombo, Peter

    1997-01-01

    The present invention provides a composition and process for disposal of radioactive, hazardous and mixed wastes. The present invention preferably includes a process for multibarrier encapsulation of radioactive, hazardous and mixed wastes by combining substantially simultaneously dry waste powder, a non-biodegradable thermoplastic polymer and an anhydrous additive in an extruder to form a homogenous molten matrix. The molten matrix may be directed in a "clean" polyethylene liner, allowed to cool, thus forming a monolithic waste form which provides a multibarrier to the dispersion of wastes into the environment.

  4. Composition and process for the encapsulation and stabilization of radioactive, hazardous and mixed wastes

    DOE Patents [OSTI]

    Kalb, Paul D.; Colombo, Peter

    1998-03-24

    The present invention provides a composition and process for disposal of radioactive, hazardous and mixed wastes. The present invention preferably includes a process for multibarrier encapsulation of radioactive, hazardous and mixed wastes by combining substantially simultaneously dry waste powder, a non-biodegradable thermoplastic polymer and an anhydrous additive in an extruder to form a homogenous molten matrix. The molten matrix may be directed in a "clean" polyethylene liner, allowed to cool, thus forming a monolithic waste form which provides a multibarrier to the dispersion of wastes into the environment.

  5. Composition and process for the encapsulation and stabilization of radioactive, hazardous and mixed wastes

    DOE Patents [OSTI]

    Kalb, Paul D.; Colombo, Peter

    1999-07-20

    The present invention provides a composition and process for disposal of radioactive, hazardous and mixed wastes. The present invention preferably includes a process for multibarrier encapsulation of radioactive, hazardous and mixed wastes by combining substantially simultaneously dry waste powder, a non-biodegradable thermoplastic polymer and an anhydrous additive in an extruder to form a homogenous molten matrix. The molten matrix may be directed in a "clean" polyethylene liner, allowed to cool, thus forming a monolithic waste form which provides a multibarrier to the dispersion of wastes into the environment.

  6. Method for stabilizing low-level mixed wastes at room temperature

    DOE Patents [OSTI]

    Wagh, A.S.; Singh, D.

    1997-07-08

    A method to stabilize solid and liquid waste at room temperature is provided comprising combining solid waste with a starter oxide to obtain a powder, contacting the powder with an acid solution to create a slurry, said acid solution containing the liquid waste, shaping the now-mixed slurry into a predetermined form, and allowing the now-formed slurry to set. The invention also provides for a method to encapsulate and stabilize waste containing cesium comprising combining the waste with Zr(OH){sub 4} to create a solid-phase mixture, mixing phosphoric acid with the solid-phase mixture to create a slurry, subjecting the slurry to pressure; and allowing the now pressurized slurry to set. Lastly, the invention provides for a method to stabilize liquid waste, comprising supplying a powder containing magnesium, sodium and phosphate in predetermined proportions, mixing said powder with the liquid waste, such as tritium, and allowing the resulting slurry to set. 4 figs.

  7. Method for stabilizing low-level mixed wastes at room temperature

    DOE Patents [OSTI]

    Wagh, Arun S. (Joliet, IL); Singh, Dileep (Westmont, IL)

    1997-01-01

    A method to stabilize solid and liquid waste at room temperature is provided comprising combining solid waste with a starter oxide to obtain a powder, contacting the powder with an acid solution to create a slurry, said acid solution containing the liquid waste, shaping the now-mixed slurry into a predetermined form, and allowing the now-formed slurry to set. The invention also provides for a method to encapsulate and stabilize waste containing cesium comprising combining the waste with Zr(OH).sub.4 to create a solid-phase mixture, mixing phosphoric acid with the solid-phase mixture to create a slurry, subjecting the slurry to pressure; and allowing the now pressurized slurry to set. Lastly, the invention provides for a method to stabilize liquid waste, comprising supplying a powder containing magnesium, sodium and phosphate in predetermined proportions, mixing said powder with the liquid waste, such as tritium, and allowing the resulting slurry to set.

  8. Chemical compatibility screening results of plastic packaging to mixed waste simulants

    SciTech Connect (OSTI)

    Nigrey, P.J.; Dickens, T.G.

    1995-12-01

    We have developed a chemical compatibility program for evaluating transportation packaging components for transporting mixed waste forms. We have performed the first phase of this experimental program to determine the effects of simulant mixed wastes on packaging materials. This effort involved the screening of 10 plastic materials in four liquid mixed waste simulants. The testing protocol involved exposing the respective materials to {approximately}3 kGy of gamma radiation followed by 14 day exposures to the waste simulants of 60 C. The seal materials or rubbers were tested using VTR (vapor transport rate) measurements while the liner materials were tested using specific gravity as a metric. For these tests, a screening criteria of {approximately}1 g/m{sup 2}/hr for VTR and a specific gravity change of 10% was used. It was concluded that while all seal materials passed exposure to the aqueous simulant mixed waste, EPDM and SBR had the lowest VTRs. In the chlorinated hydrocarbon simulant mixed waste, only VITON passed the screening tests. In both the simulant scintillation fluid mixed waste and the ketone mixture simulant mixed waste, none of the seal materials met the screening criteria. It is anticipated that those materials with the lowest VTRs will be evaluated in the comprehensive phase of the program. For specific gravity testing of liner materials the data showed that while all materials with the exception of polypropylene passed the screening criteria, Kel-F, HDPE, and XLPE were found to offer the greatest resistance to the combination of radiation and chemicals.

  9. Calcine Waste Storage at the Idaho Nuclear Technology and Engineering Center

    SciTech Connect (OSTI)

    M. D. Staiger

    1999-06-01

    A potential option in the program for long-term management of high-level wastes at the Idaho Nuclear Technology and Engineering Center (INTEC), at the Idaho National Engineering and Environmental Laboratory, calls for retrieving calcine waste and converting it to a more stable and less dispersible form. An inventory of calcine produced during the period December 1963 to May 1999 has been prepared based on calciner run, solids storage facilities operating, and miscellaneous operational information, which gives the range of chemical compositions of calcine waste stored at INTEC. Information researched includes calciner startup data, waste solution analyses and volumes calcined, calciner operating schedules, solids storage bin capacities, calcine storage bin distributor systems, and solids storage bin design and temperature monitoring records. Unique information on calcine solids storage facilities design of potential interest to remote retrieval operators is given.

  10. Test plan for immobilization of salt-containing surrogate mixed wastes using polyester resins

    SciTech Connect (OSTI)

    Biyani, R.K.; Douglas, J.C.; Hendrickson, D.W.

    1997-07-07

    Past operations at many Department of Energy (DOE) sites have resulted in the generation of several waste streams with high salt content. These wastes contain listed and characteristic hazardous constituents and are radioactive. The salts contained in the wastes are primarily chloride, sulfate, nitrate, metal oxides, and hydroxides. DOE has placed these types of wastes under the purview of the Mixed Waste Focus Area (MWFA). The MWFA has been tasked with developing and facilitating the implementation of technologies to treat these wastes in support of customer needs and requirements. The MWFA has developed a Technology Development Requirements Document (TDRD), which specifies performance requirements for technology owners and developers to use as a framework in developing effective waste treatment solutions. This project will demonstrate the use of polyester resins in encapsulating and solidifying DOE`s mixed wastes containing salts, as an alternative to conventional and other emerging immobilization technologies.

  11. Mixed waste focus area integrated technical baseline report. Phase I, Volume 2: Revision 0

    SciTech Connect (OSTI)

    1996-01-16

    This document (Volume 2) contains the Appendices A through J for the Mixed Waste Focus Area Integrated Technical Baseline Report Phase I for the Idaho National Engineering Laboratory. Included are: Waste Type Managers` Resumes, detailed information on wastewater, combustible organics, debris, unique waste, and inorganic homogeneous solids and soils, and waste data information. A detailed list of technology deficiencies and site needs identification is also provided.

  12. Characterization of the solid low level mixed waste inventory for the solid waste thermal treatment activity - III

    SciTech Connect (OSTI)

    Place, B.G., Westinghouse Hanford

    1996-09-24

    The existing thermally treatable, radioactive mixed waste inventory is characterized to support implementation of the commercial, 1214 thermal treatment contract. The existing thermally treatable waste inventory has been identified using a decision matrix developed by Josephson et al. (1996). Similar to earlier waste characterization reports (Place 1993 and 1994), hazardous materials, radionuclides, physical properties, and waste container data are statistically analyzed. In addition, the waste inventory data is analyzed to correlate waste constituent data that are important to the implementation of the commercial thermal treatment contract for obtaining permits and for process design. The specific waste parameters, which were analyzed, include the following: ``dose equivalent`` curie content, polychlorinated biphenyl (PCB) content, identification of containers with PA-related mobile radionuclides (14C, 12 79Se, 99Tc, and U isotopes), tritium content, debris and non-debris content, container free liquid content, fissile isotope content, identification of dangerous waste codes, asbestos containers, high mercury containers, beryllium dust containers, lead containers, overall waste quantities, analysis of container types, and an estimate of the waste compositional split based on the thermal treatment contractor`s proposed process. A qualitative description of the thermally treatable mixed waste inventory is also provided.

  13. A preliminary evaluation of alternatives for disposal of INEL low-level waste and low-level mixed waste

    SciTech Connect (OSTI)

    Smith, T.H.; Roesener, W.S.; Jorgenson-Waters, M.J.

    1993-07-01

    The Mixed and Low-Level Waste Disposal Facility (MLLWDF) project was established in 1992 by the US Department of Energy Idaho Operations Office to provide enhanced disposal capabilities for Idaho National Engineering Laboratory (INEL) low-level mixed waste and low-level waste. This Preliminary Evaluation of Alternatives for Disposal of INEL Low-Level Waste and Low-Level Mixed Waste identifies and evaluates-on a preliminary, overview basis-the alternatives for disposal of that waste. Five disposal alternatives, ranging from of no-action`` to constructing and operating the MLLWDF, are identified and evaluated. Several subalternatives are formulated within the MLLWDF alternative. The subalternatives involve various disposal technologies as well as various scenarios related to the waste volumes and waste forms to be received for disposal. The evaluations include qualitative comparisons of the projected isolation performance for each alternative, and facility, health and safety, environmental, institutional, schedule, and rough order-of-magnitude life-cycle cost comparisons. The performance of each alternative is evaluated against lists of ``musts`` and ``wants.`` Also included is a discussion of other key considerations for decisionmaking. The analysis of results indicated further study is necessary to obtain the best estimate of long-term future waste volume and characteristics from the INEL Environmental Restoration activities and the expanded INEL Decontamination and Decommissioning Program.

  14. AN NDA Technique for the Disposition of Mixed Low Level Waste at the Advanced Mixed Waste Treatment Project

    SciTech Connect (OSTI)

    M.J. Clapham; J.V. Seamans; R.E. Arbon

    2006-05-16

    The AMWTP is aggressively characterizing and shipping transuranic (TRU) waste to meet the DOE-IDs goal of 6000m3 of TRU waste to the Waste Isolation Pilot Plant (WIPP). The AMWTP shipping schedule requires streamlined waste movements and efficient waste characterization. Achieving this goal is complicated by the presence of waste that cannot be shipped to WIPP. A large amount of this waste is non-shippable due to the fact that no measurable TRU activity is identified during non-destructive assay (NDA).

  15. Composite analysis for solid waste storage area 6

    SciTech Connect (OSTI)

    Lee, D.W.

    1997-09-01

    The composite analysis (CA) provides an estimate of the potential cumulative impacts to a hypothetical future member of the public from the Solid Waste Storage Area 6 (SWSA 6) disposal operations and all of the other sources of radioactive material in the ground on the ORR that may interact with contamination originating in SWSA 6.The projected annual dose to hypothetical future member of the public from all contributing sources is compared to the primary dose limit of 100 mrem per year and a dose constraint of 30 mrem per year. Consistent with the CA guidance, dose estimates for the first 1000 years after disposal are emphasized for comparison with the primary dose limit and dose constraint.The current land use plan for the ORR is being revised, and may include a reduction in the land currently controlled by DOE on the ORR. The possibility of changes in the land use boundary is considered in the CA as part of the sensitivity and uncertainty analysis of the results, the interpretation of results, and the conclusions.

  16. Progress and Status of the Ignalina Nuclear Power Plant's New Solid Waste Management and Storage Facilities

    SciTech Connect (OSTI)

    Rausch, J.; Henderson, R.W.; Penkov, V.

    2008-07-01

    A considerable amount of dry radioactive waste from former NPP operation has accumulated up to date and is presently stored at the Ignalina NPP site, Lithuania. Current storage capacities are nearly exhausted and more waste is to come from future decommissioning of the two RMBKtype reactors. Additionally, the existing storage facilities does not comply to the state-of-the-art technology for handling and storage of radioactive waste. In 2005, INPP faced this situation of a need for waste processing and subsequent interim storage of these wastes by contracting NUKEM with the design, construction, installation and commissioning of new waste management and storage facilities. The subject of this paper is to describe the scope and the status of the new solid waste management and storage facilities at the Ignalina Nuclear Power Plant. In summary: The turnkey contract for the design, supply and commission of the SWMSF was awarded in December 2005. The realisation of the project was initially planned within 48 month. The basic design was finished in August 2007 and the Technical Design Documentation and Preliminary Safety Analyses Report was provided to Authorities in October 2007. The construction license is expected in July 2008. The procurement phase was started in August 2007, start of onsite activities is expected in November 2007. The start of operation of the SWMSF is scheduled for end of 2009. (authors)

  17. DOE names Bechtel BWXT Idaho and the Advanced Mixed Waste Treatment Project

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    as a VPP Star Site names Bechtel BWXT Idaho and the Advanced Mixed Waste Treatment Project as a VPP Star Site Rick Provencher of DOE-ID, Jeff Mousseau of BBWI and co-safety chairs Tracy Anderson and Josh Wallace raise the VPP flag indicating the Advanced Mixed Waste Treatment Project is a Star site. View larger image here. The U.S. Department of Energy today announced it has recognized Bechtel BWXT Idaho at the Advanced Mixed Waste Treatment Project as a Star site in its Voluntary Protection

  18. Idaho's Advanced Mixed Waste Treatment Project Details 2013Accomplish...

    Office of Environmental Management (EM)

    (MLLW). The defense-related TRU waste is sent to the Waste Isolation Pilot Plant in New Mexico, and the MLLW is sent to other federal and commercial disposal sites. AMWTP is the...

  19. Environmental Assessment Idaho National Engineering Laboratory, low-level and mixed waste processing

    SciTech Connect (OSTI)

    Not Available

    1994-06-01

    The Department of Energy (DOE) has prepared an environmental assessment (EA), DOE/EA-0843, for the Idaho National Engineering Laboratory (INEL) low-level and mixed waste processing. The original proposed action, as reviewed in this EA, was (1) to incinerate INEL`s mixed low-level waste (MLLW) at the Waste Experimental Reduction Facility (WERF); (2) reduce the volume of INEL generated low-level waste (LLW) through sizing, compaction, and stabilization at the WERF; and (3) to ship INEL LLW to a commercial incinerator for supplemental LLW volume reduction.

  20. The effects of size reduction techniques on TCLP analysis of solidified mixed waste

    SciTech Connect (OSTI)

    Thiel, R.D.; McLaurin, A.W.; Kochen, R.L.

    1993-07-01

    The Rocky Flats Plant (RFP) generates and stores mixed wastes that are subject to regulation under the Resource Conservation and Recovery Act (RCRA) Land Disposal Restrictions (LDR). Low level mixed wastes at RFP are destined for disposal at the Nevada Test Site (NTS), and thus must meet stringent NTS Waste Acceptance Criteria (WAC), including free liquids, dispersible solids, and Toxicity Characteristic Leaching Procedure (TCLP) requirements. TCLP requires size reduction of the waste form to less than 0.95 centimeters. This can be accomplished by cutting, crushing, or grinding. These classic size reduction methods have the effect of exposing more surface area of the waste. Stabilization technologies under investigation at RFP include polymer encapsulation by co-extruding the waste with low density polyethylene and microwave melting. The objective of this study is to evaluate the effects of different size reduction methods on TCLP results for polyethylene-encapsulated and microwave melted surrogate waste.

  1. Proposed research and development plan for mixed low-level waste forms

    SciTech Connect (OSTI)

    O`Holleran, T.O.; Feng, X.; Kalb, P.

    1996-12-01

    The objective of this report is to recommend a waste form program plan that addresses waste form issues for mixed low-level waste (MLLW). The report compares the suitability of proposed waste forms for immobilizing MLLW in preparation for permanent near-surface disposal and relates them to their impact on the U.S. Department of Energy`s mixed waste mission. Waste forms are classified into four categories: high-temperature waste forms, hydraulic cements, encapsulants, and specialty waste forms. Waste forms are evaluated concerning their ability to immobilize MLLW under certain test conditions established by regulatory agencies and research institutions. The tests focused mainly on leach rate and compressive strength. Results indicate that all of the waste forms considered can be tailored to give satisfactory performance immobilizing large fractions of the Department`s MLLW inventory. Final waste form selection will ultimately be determined by the interaction of other, often nontechnical factors, such as economics and politics. As a result of this report, three top-level programmatic needs have been identified: (1) a basic set of requirements for waste package performance and disposal; (2) standardized tests for determining waste form performance and suitability for disposal; and (3) engineering experience operating production-scale treatment and disposal systems for MLLW.

  2. Immobilized low-activity waste interim storage facility, Project W-465 conceptual design report

    SciTech Connect (OSTI)

    Pickett, W.W.

    1998-03-02

    This report outlines the design and total estimated cost to modify the four unused grout vaults for the remote handling and interim storage of immobilized low-activity waste (ILAW).

  3. DQO Summary Report for 105-N/109-N Interim Safe Storage Project Waste Characterization

    SciTech Connect (OSTI)

    T. A. Lee

    2005-09-15

    The DQO summary report provides the results of the DQO process completed for waste characterization activities for the 105-N/109-N Reactor Interim Safe Storage Project including decommission, deactivate, decontaminate, and demolish activities for six associated buildings.

  4. National profile on commercially generated low-level radioactive mixed waste

    SciTech Connect (OSTI)

    Klein, J.A.; Mrochek, J.E.; Jolley, R.L.; Osborne-Lee, I.W.; Francis, A.A.; Wright, T.

    1992-12-01

    This report details the findings and conclusions drawn from a survey undertaken as part of a joint US Nuclear Regulatory Commission and US Environmental Protection Agency-sponsored project entitled ``National Profile on Commercially Generated Low-Level Radioactive Mixed Waste.`` The overall objective of the work was to compile a national profile on the volumes, characteristics, and treatability of commercially generated low-level mixed waste for 1990 by five major facility categories-academic, industrial, medical, and NRC-/Agreement State-licensed goverment facilities and nuclear utilities. Included in this report are descriptions of the methodology used to collect and collate the data, the procedures used to estimate the mixed waste generation rate for commercial facilities in the United States in 1990, and the identification of available treatment technologies to meet applicable EPA treatment standards (40 CFR Part 268) and, if possible, to render the hazardous component of specific mixed waste streams nonhazardous. The report also contains information on existing and potential commercial waste treatment facilities that may provide treatment for specific waste streams identified in the national survey. The report does not include any aspect of the Department of Energy`s (DOES) management of mixed waste and generally does not address wastes from remedial action activities.

  5. Final Environmental Impact Statement Safe Interim Storage Of Hanford Tank Wastes

    Office of Environmental Management (EM)

    Summary-1995.html[6/27/2011 12:58:00 PM] FINAL ENVIRONMENTAL IMPACT STATEMENT SAFE INTERIM STORAGE OF HANFORD TANK WASTES SUMMARY The Safe Interim Storage of Hanford Tank Wastes Environmental Impact Statement has been prepared according to requirements of the National Environmental Policy Act and the Washington State Environmental Policy Act. In accordance with these Acts, a Draft Environmental Impact Statement was issued on August 5, 1994, (DOE 1994) and it was revised in response to public,

  6. Calcine Waste Storage at the Idaho Nuclear Technology and Engineering Center

    SciTech Connect (OSTI)

    Staiger, Merle Daniel; M. C. Swenson

    2005-01-01

    This report documents an inventory of calcined waste produced at the Idaho Nuclear Technology and Engineering Center during the period from December 1963 to May 2000. The report was prepared based on calciner runs, operation of the calcined solids storage facilities, and miscellaneous operational information that establishes the range of chemical compositions of calcined waste stored at Idaho Nuclear Technology and Engineering Center. The report will be used to support obtaining permits for the calcined solids storage facilities, possible treatment of the calcined waste at the Idaho National Engineering and Environmental Laboratory, and to ship the waste to an off-site facility including a geologic repository. The information in this report was compiled from calciner operating data, waste solution analyses and volumes calcined, calciner operating schedules, calcine temperature monitoring records, and facility design of the calcined solids storage facilities. A compact disk copy of this report is provided to facilitate future data manipulations and analysis.

  7. Supplemental analysis of accident sequences and source terms for waste treatment and storage operations and related facilities for the US Department of Energy waste management programmatic environmental impact statement

    SciTech Connect (OSTI)

    Folga, S.; Mueller, C.; Nabelssi, B.; Kohout, E.; Mishima, J.

    1996-12-01

    This report presents supplemental information for the document Analysis of Accident Sequences and Source Terms at Waste Treatment, Storage, and Disposal Facilities for Waste Generated by US Department of Energy Waste Management Operations. Additional technical support information is supplied concerning treatment of transuranic waste by incineration and considering the Alternative Organic Treatment option for low-level mixed waste. The latest respirable airborne release fraction values published by the US Department of Energy for use in accident analysis have been used and are included as Appendix D, where respirable airborne release fraction is defined as the fraction of material exposed to accident stresses that could become airborne as a result of the accident. A set of dominant waste treatment processes and accident scenarios was selected for a screening-process analysis. A subset of results (release source terms) from this analysis is presented.

  8. EA-1189: Non-thermal Treatment of Hanford Site Low-level Mixed Waste, Richland, Washington

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts for the proposal to demonstrate the feasibility of commercial treatment of contact-handled low-level mixed waste to meet existing Federal and State...

  9. EA-1292: On-site Treatment of Low Level Mixed Waste, Golden, Colorado

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts for the proposal to evaluate the proposed treatment of low level mixed waste at the U.S. Department of Energy's Rocky Flats Environmental Technology Site.

  10. EA-1135: Offsite Thermal Treatment of Low-level Mixed Waste, Richland, Washington

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts of the proposal to treat contact-handled low-level mixed waste, containing polychlorinated biphenyls and other organics, to meet existing regulatory...

  11. Idaho’s Advanced Mixed Waste Treatment Project Details 2013 Accomplishments

    Broader source: Energy.gov [DOE]

    IDAHO FALLS, Idaho – EM and its contractor, Idaho Treatment Group (ITG), safely and compliantly met all of their production and shipping targets in the Advanced Mixed Waste Treatment Project (AMWTP) at the Idaho site in 2013.

  12. Key regulatory drivers affecting shipments of mixed transuranic waste from Los Alamos National Laboratory to the Waste Isolation Pilot Plant

    SciTech Connect (OSTI)

    Schumann, P.B.; Bacigalupa, G.A.; Kosiewicz, S.T.; Sinkule, B.J.

    1997-02-01

    A number of key regulatory drivers affect the nature, scope, and timing of Los Alamos National Laboratory`s (LANL`s) plans for mixed transuranic (MTRU) waste shipments to the Waste Isolation Pilot Plant (WIPP), which are planned to commence as soon as possible following WIPP`s currently anticipated November, 1997 opening date. This paper provides an overview of some of the key drivers at LANL, particularly emphasizing those associated with the hazardous waste component of LANL`s MTRU waste (MTRU, like any mixed waste, contains both a radioactive and a hazardous waste component). The key drivers discussed here derive from the federal Resource Conservation and Recovery Act (RCRA) and its amendments, including the Federal Facility Compliance Act (FFCAU), and from the New Mexico Hazardous Waste Act (NMHWA). These statutory provisions are enforced through three major mechanisms: facility RCRA permits; the New Mexico Hazardous Waste Management Regulations, set forth in the New Mexico Administrative Code, Title 20, Chapter 4, Part 1: and compliance orders issued to enforce these requirements. General requirements in all three categories will apply to MTRU waste management and characterization activities at both WIPP and LANL. In addition, LANL is subject to facility-specific requirements in its RCRA hazardous waste facility permit, permit conditions as currently proposed in RCRA Part B permit applications presently being reviewed by the New Mexico Environment Department (NNED), and facility-specific compliance orders related to MTRU waste management. Likewise, permitting and compliance-related requirements specific to WIPP indirectly affect LANL`s characterization, packaging, record-keeping, and transportation requirements for MTRU waste. LANL must comply with this evolving set of regulatory requirements to begin shipments of MTRU waste to WIPP in a timely fashion.

  13. Evaluation of potential mixed wastes containing lead, chromium, or used oil

    SciTech Connect (OSTI)

    Siskind, B.; MacKenzie, D.R.; Bowerman, B.S.; Kempf, C.R.; Piciulo, P.L.

    1987-01-01

    This paper presents the results of follow-on studies conducted by Brookhaven National Laboratory (BNL) for the Nuclear Regulatory Commission (NRC) on certain kinds of low-level waste (LLW) which could also be classified as hazardous waste subject to regulation by the Environmental Protection Agency (EPA). Such LLW is termed ''mixed waste.'' Additional data have been collected and evaluated on two categories of potential mixed waste, namely LLW containing metallic lead and LLW containing chromium. Additionally, LLW with organic liquids, especially liquid scintillation wastes, are reviewed. In light of a proposed EPA rule to list used oil as hazardous waste, the potential mixed waste hazard of used oil contaminated with radionuclides is discussed. It is concluded that the EPA test for determining whether a solid waste exhibits the hazardous characteristic of extraction procedure toxicity does not adequately simulate the burial environment at LLW disposal sites, and in particular, does not adequately assess the potential for dissolution and transport of buried metallic lead. Also, although chromates are, in general, not a normal or routine constitutent in commercial LLW (with the possible exception of chemical decontamination wastes), light water reactors which do use chromates might find it beneficial to consider alternative corrosion inhibitors. In addition, it is noted that if used oil is listed by the EPA as hazardous waste, LLW oil may be managed by a scheme including one or more of the following processes: incineration, immobilization, sorption, aqueous extraction and glass furnace processing.

  14. Public participation in a DOE national program: The mixed waste focus area`s approach

    SciTech Connect (OSTI)

    1997-05-01

    The authors describe the Mixed Waste Focus Area`s approach to involving interested Tribal and public members in the mixed waste technology development process. Evidence is provided to support the thesis that the Focus Area`s systems engineering process, which provides visible and documented requirements and decision criteria, facilitates effective Tribal and public participation. Also described is a status of Tribal and public involvement at three levels of Focus Area activities.

  15. LOW-LEVEL RADIOACTIVE & MIXED WASTE SHIPMENTS TO THE NEVADA NATIONAL SECURITY SITE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NV NY NY NV OH TN TN TN, WA, CA TN TN TN TX y ct 2 Plant Perma-Fix LOW-LEVEL RADIOACTIVE & MIXED WASTE SHIPMENTS TO THE NEVADA NATIONAL SECURITY SITE FIRST QUARTER REPORT, FY 2011 (OCTOBER, NOVEMBER, DECEMBER 2010) Livermore National Laboratory ergy Alliance onal Laboratory Mixed Waste Treatment Project gonne National Laboratory ational Laboratory Gaseous Diffusion Plant Proving Ground terra, LLC en National Laboratory y Environmental Services ecurity Technologies, Inc. h Gaseous Diffusion

  16. Mixed waste treatment using the ChemChar thermolytic detoxification technique

    SciTech Connect (OSTI)

    Kuchynka, D.

    1995-10-01

    The diversity of mixed waste matrices contained at Department of Energy sites that require treatment preclude a single, universal treatment technology capable of handling sludges, solids, heterogeneous debris, aqueous and organic liquids and soils. This report describes the ChemChar thermolytic detoxification process. The process is a thermal, chemically reductive technology that converts the organic portion of mixed wastes to a synthesis gas, while simultaneously absorbing volatile inorganics on a carbon-based char.

  17. Conceptual design report for immobilized high-level waste interim storage facility (Phase 1)

    SciTech Connect (OSTI)

    Burgard, K.C.

    1998-06-02

    The Hanford Site Canister Storage Building (CSB Bldg. 212H) will be utilized to interim store Phase 1 HLW products. Project W-464, Immobilized High-Level Waste Interim Storage, will procure an onsite transportation system and retrofit the CSB to accommodate the Phase 1 HLW products. The Conceptual Design Report establishes the Project W-464 technical and cost basis.

  18. Integrated chemical/biological treatment of paint stripper mixed waste: Metals toxicity and separation

    SciTech Connect (OSTI)

    Vanderberg-Twary, L.; Grumbine, R.K.; Foreman, T.; Hanners, J.L.; Brainard, J.R.; Sauer, N.N.; Unkefer, P.J.

    1995-05-01

    The DOE complex has generated vast quantities of complex heterogeneous mixed wastes. Paint stripper waste (PSW) is a complex waste that arose from decontamination and decommissioning activities. It contains paint stripper, cheesecloth, cellulose-based paints with Pb and Cr, and suspect Pu. Los Alamos National Laboratory has 150--200 barrels of PSW and other national laboratories such as Rocky Flats Plant have many more barrels of heterogeneous waste. Few technologies exist that can treat this complex waste. Our approach to solving this problem is the integration of two established technologies: biodegradation and metals chelation.

  19. Mixing Processes in High-Level Waste Tanks (Technical Report...

    Office of Scientific and Technical Information (OSTI)

    with transport in free and wall jets modeled using standard integral techniques. ... of fuel and oxygen concentrations in DOE high-level waste tanks following loss of ...

  20. Long-Term Stewardship of Mixed Wastes: Passive Reactive Barriers...

    Office of Scientific and Technical Information (OSTI)

    of microbial transformation of chromium, uranium, iron minerals, and trinitrotoluene (TNT) ... SOILS; TNT; TRANSFORMATIONS; URANIUM; WASTES Word Cloud More Like This Full ...

  1. Hazardous Waste/Mixed Waste Treatment Building Safety Information Document (SID)

    SciTech Connect (OSTI)

    Fatell, L.B.; Woolsey, G.B.

    1993-04-15

    This Safety Information Document (SID) provides a description and analysis of operations for the Hazardous Waste/Mixed Waste Disposal Facility Treatment Building (the Treatment Building). The Treatment Building has been classified as a moderate hazard facility, and the level of analysis performed and the methodology used are based on that classification. Preliminary design of the Treatment Building has identified the need for two separate buildings for waste treatment processes. The term Treatment Building applies to all these facilities. The evaluation of safety for the Treatment Building is accomplished in part by the identification of hazards associated with the facility and the analysis of the facility`s response to postulated events involving those hazards. The events are analyzed in terms of the facility features that minimize the causes of such events, the quantitative determination of the consequences, and the ability of the facility to cope with each event should it occur. The SID presents the methodology, assumptions, and results of the systematic evaluation of hazards associated with operation of the Treatment Building. The SID also addresses the spectrum of postulated credible events, involving those hazards, that could occur. Facility features important to safety are identified and discussed in the SID. The SID identifies hazards and reports the analysis of the spectrum of credible postulated events that can result in the following consequences: Personnel exposure to radiation; Radioactive material release to the environment; Personnel exposure to hazardous chemicals; Hazardous chemical release to the environment; Events leading to an onsite/offsite fatality; and Significant damage to government property. The SID addresses the consequences to the onsite and offsite populations resulting from postulated credible events and the safety features in place to control and mitigate the consequences.

  2. Calcined Waste Storage at the Idaho Nuclear Technology and Engineering Center

    SciTech Connect (OSTI)

    M. D. Staiger M. C. Swenson

    2007-06-01

    This report provides a quantitative inventory and composition (chemical and radioactivity) of calcined waste stored at the Idaho Nuclear Technology and Engineering Center. From December 1963 through May 2000, liquid radioactive wastes generated by spent nuclear fuel reprocessing were converted into a solid, granular form called calcine. This report also contains a description of the calcine storage bins.

  3. Overview of Nevada Test Site Radioactive and Mixed Waste Disposal Operations

    SciTech Connect (OSTI)

    J.T. Carilli; S.K. Krenzien; R.G. Geisinger; S.J. Gordon; B. Quinn

    2009-03-01

    The U.S. Department of Energy (DOE), National Nuclear Security Administration Nevada Site Office Environmental Management Program is responsible for carrying out the disposal of on-site and off-site generated low-level radioactive waste (LLW) and low-level radioactive mixed waste (MW) at the Nevada Test Site (NTS). Core elements of this mission are ensuring safe and cost-effective disposal while protecting workers, the public, and the environment. This paper focuses on the impacts of new policies, processes, and opportunities at the NTS related to LLW and MW. Covered topics include: the first year of direct funding for NTS waste disposal operations; zero tolerance policy for non-compliant packages; the suspension of mixed waste disposal; waste acceptance changes; DOE Consolidated Audit Program (DOECAP) auditing; the 92-Acre Area closure plan; new eligibility requirements for generators; and operational successes with unusual waste streams.

  4. B Plant complex hazardous, mixed and low level waste certification plan

    SciTech Connect (OSTI)

    Beam, T.G.

    1994-11-01

    This plan describes the administrative steps and handling methodology for certification of hazardous waste, mixed waste, and low level waste generated at B Plant Complex. The plan also provides the applicable elements of waste reduction and pollution prevention, including up front minimization and end product reduction of volume and/or toxicity. The plan is written to satisfy requirements for Hanford Site waste generators to have a waste certification program in place at their facility. This plan, as described, applies only to waste which is generated at, or is the responsibility of, B Plant Complex. The scope of this plan is derived from the requirements found in WHC-EP-0063, Hanford Site Solid Waste Acceptance Criteria.

  5. Commercial treatability study capabilities for application to the US Department of Energy`s anticipated mixed waste streams

    SciTech Connect (OSTI)

    1996-07-01

    The U.S. Department of Energy (DOE) has established the Mixed Waste Focus Area (MWFA), which represents a national effort to develop and coordinate treatment solutions for mixed waste among all DOE facilities. The hazardous waste component of mixed waste is regulated under the Resource Conservation and Recovery Act (RCRA), while the radioactive component is regulated under the Atomic Energy Act, as implemented by the DOE, making mixed waste one of the most complex types of waste for the DOE to manage. The MWFA has the mission to support technologies that meet the needs of the DOE`s waste management efforts to characterize, treat, and dispose of mixed waste being generated and stored throughout the DOE complex. The technologies to be supported must meet all regulatory requirements, provide cost and risk improvements over available technologies, and be acceptable to the public. The most notable features of the DOE`s mixed-waste streams are the wide diversity of waste matrices, volumes, radioactivity levels, and RCRA-regulated hazardous contaminants. Table 1-1 is constructed from data from the proposed site treatment plans developed by each DOE site and submitted to DOE Headquarters. The table shows the number of mixed-waste streams and their corresponding volumes. This table illustrates that the DOE has a relatively small number of large-volume mixed-waste streams and a large number of small-volume mixed-waste streams. There are 1,033 mixed-waste streams with volumes less than 1 cubic meter; 1,112 mixed-waste streams with volumes between 1 and 1,000 cubic meters; and only 61 mixed-waste streams with volumes exceeding 1,000 cubic meters.

  6. The WIPP RCRA Part B permit application for TRU mixed waste disposal

    SciTech Connect (OSTI)

    Johnson, J.E. [Westinghouse Electric Corp., Carlsbad, NM (United States). Waste Isolation Div.; Snider, C.A. [USDOE Carlsbad Area Office, NM (United States)

    1995-12-31

    In August 1993, the New Mexico Environment Department (NMED) issued a draft permit for the Waste Isolation Pilot Plant (WIPP) to begin experiments with transuranic (TRU) mixed waste. Subsequently, the Department of Energy (DOE) decided to cancel the on-site test program, opting instead for laboratory testing. The Secretary of the NMED withdrew the draft permit in 1994, ordering the State`s Hazardous and Radioactive Waste Bureau to work with the DOE on submittal of a revised permit application. Revision 5 of the WIPP`s Resource Conservation and Recovery Act (RCRA) Part B Permit Application was submitted to the NMED in May 1995, focusing on disposal of 175,600 m{sup 3} of TRU mixed waste over a 25 year span plus ten years for closure. A key portion of the application, the Waste Analysis Plan, shifted from requirements to characterize a relatively small volume of TRU mixed waste for on-site experiments, to describing a complete program that would apply to all DOE TRU waste generating facilities and meet the appropriate RCRA regulations. Waste characterization will be conducted on a waste stream basis, fitting into three broad categories: (1) homogeneous solids, (2) soil/gravel, and (3) debris wastes. Techniques used include radiography, visually examining waste from opened containers, radioassay, headspace gas sampling, physical sampling and analysis of homogeneous wastes, and review of documented acceptable knowledge. Acceptable knowledge of the original organics and metals used, and the operations that generated these waste streams is sufficient in most cases to determine if the waste has toxicity characteristics, hazardous constituents, polychlorinated biphenyls (PBCs), or RCRA regulated metals.

  7. DOE Chooses Idaho Treatment Group, LLC to Disposition Waste at the Advanced Mixed Waste Treatment Project: Contract will continue cleanup and waste operations at the Idaho Site

    Office of Energy Efficiency and Renewable Energy (EERE)

    Idaho Falls – In order to further meet the U.S. Department of Energy’s commitments to the citizens of the state of Idaho, the DOE today announced that it has selected Idaho Treatment Group, LLC (ITG) to perform waste processing at the Advanced Mixed Waste Treatment Project (AMWTP) at DOE’s Idaho Site near Idaho Falls.

  8. Analysis of accident sequences and source terms at waste treatment and storage facilities for waste generated by U.S. Department of Energy Waste Management Operations, Volume 1: Sections 1-9

    SciTech Connect (OSTI)

    Mueller, C.; Nabelssi, B.; Roglans-Ribas, J.

    1995-04-01

    This report documents the methodology, computational framework, and results of facility accident analyses performed for the U.S. Department of Energy (DOE) Waste Management Programmatic Environmental Impact Statement (WM PEIS). The accident sequences potentially important to human health risk are specified, their frequencies are assessed, and the resultant radiological and chemical source terms are evaluated. A personal computer-based computational framework and database have been developed that provide these results as input to the WM PEIS for calculation of human health risk impacts. The methodology is in compliance with the most recent guidance from DOE. It considers the spectrum of accident sequences that could occur in activities covered by the WM PEIS and uses a graded approach emphasizing the risk-dominant scenarios to facilitate discrimination among the various WM PEIS alternatives. Although it allows reasonable estimates of the risk impacts associated with each alternative, the main goal of the accident analysis methodology is to allow reliable estimates of the relative risks among the alternatives. The WM PEIS addresses management of five waste streams in the DOE complex: low-level waste (LLW), hazardous waste (HW), high-level waste (HLW), low-level mixed waste (LLMW), and transuranic waste (TRUW). Currently projected waste generation rates, storage inventories, and treatment process throughputs have been calculated for each of the waste streams. This report summarizes the accident analyses and aggregates the key results for each of the waste streams. Source terms are estimated and results are presented for each of the major DOE sites and facilities by WM PEIS alternative for each waste stream. The appendices identify the potential atmospheric release of each toxic chemical or radionuclide for each accident scenario studied. They also provide discussion of specific accident analysis data and guidance used or consulted in this report.

  9. Alternative disposal options for alpha-mixed low-level waste

    SciTech Connect (OSTI)

    Loomis, G.G.; Sherick, M.J.

    1995-12-31

    This paper presents several disposal options for the Department of Energy alpha-mixed low-level waste. The mixed nature of the waste favors thermally treating the waste to either an iron-enriched basalt or glass waste form, at which point a multitude of reasonable disposal options, including in-state disposal, are a possibility. Most notably, these waste forms will meet the land-ban restrictions. However, the thermal treatment of this waste involves considerable waste handling and complicated/expensive offgas, systems with secondary waste management problems. In the United States, public perception of off gas systems in the radioactive incinerator area is unfavorable. The alternatives presented here are nonthermal in nature and involve homogenizing the waste with cryogenic techniques followed by complete encapsulation with a variety of chemical/grouting agents into retrievable waste forms. Once encapsulated, the waste forms are suitable for transport out of the state or for actual in-state disposal. This paper investigates variances that would have to be obtained and contrasts the alternative encapsulation idea with the thermal treatment option.

  10. Alternative disposal options for alpha-mixed low-level waste

    SciTech Connect (OSTI)

    Loomis, G.G.; Sherick, M.J.

    1995-12-01

    This paper presents several disposal options for the Department of Energy alpha-mixed low-level waste. The mixed nature of the waste favors thermally treating the waste to either an iron-enriched basalt or glass waste form, at which point a multitude of reasonable disposal options, including in-state disposal, are a possibility. Most notably, these waste forms will meet the land-ban restrictions. However, the thermal treatment of this waste involves considerable waste handling and complicated/expensive offgas systems with secondary waste management problems. In the United States, public perception of offgas systems in the radioactive incinerator area is unfavorable. The alternatives presented here are nonthermal in nature and involve homogenizing the waste with cryogenic techniques followed by complete encapsulation with a variety of chemical/grouting agents into retrievable waste forms. Once encapsulated, the waste forms are suitable for transport out of the state or for actual in-state disposal. This paper investigates variances that would have to be obtained and contrasts the alternative encapsulation idea with the thermal treatment option.

  11. EIS-0212: Safe Interim Storage of Hanford Tank Wastes, Hanford Site, Richland, WA

    Office of Energy Efficiency and Renewable Energy (EERE)

    This environmental impact statement asseses Department of Energy and Washington State Department of Ecology maintanence of safe storage of high-level radioactive wastes currently stored in the older single-shell tanks, the Watchlist Tank 101-SY, and future waste volumes associated with tank farm and other Hanford facility operations, including a need to provide a modern safe, reliable, and regulatory-compliant replacement cross-site transfer capability. The purpose of this action is to prevent uncontrolled releases to the environment by maintaining safe storage of high-level tank wastes.

  12. Decommissioning and Dismantling of Liquid Waste Storage and Liquid Waste Treatment Facility from Paldiski Nuclear Site, Estonia

    SciTech Connect (OSTI)

    Varvas, M.; Putnik, H.; Johnsson, B.

    2006-07-01

    The Paldiski Nuclear Facility in Estonia, with two nuclear reactors was owned by the Soviet Navy and was used for training the navy personnel to operate submarine nuclear reactors. After collapse of Soviet Union the Facility was shut down and handed over to the Estonian government in 1995. In co-operation with the Paldiski International Expert Reference Group (PIERG) decommission strategy was worked out and started to implement. Conditioning of solid and liquid operational waste and dismantling of contaminated installations and buildings were among the key issues of the Strategy. Most of the liquid waste volume, remained at the Facility, was processed in the frames of an Estonian-Finnish co-operation project using a mobile wastewater purification unit NURES (IVO International OY) and water was discharged prior to the site take-over. In 1999-2002 ca 120 m{sup 3} of semi-liquid tank sediments (a mixture of ion exchange resins, sand filters, evaporator and flocculation slurry), remained after treatment of liquid waste were solidified in steel containers and stored into interim storage. The project was carried out under the Swedish - Estonian co-operation program on radiation protection and nuclear safety. Contaminated installations in buildings, used for treatment and storage of liquid waste (Liquid Waste Treatment Facility and Liquid Waste Storage) were then dismantled and the buildings demolished in 2001-2004. (authors)

  13. Hazardous Waste Treatment, Storage and Disposal Facilities (TSDF...

    Open Energy Info (EERE)

    Treatment, Storage and Disposal Facilities (TSDF) Guidance Jump to: navigation, search OpenEI Reference LibraryAdd to library PermittingRegulatory Guidance - GuideHandbook:...

  14. METHODOLOGY & CALCULATIONS FOR THE ASSIGNMENT OF WASTE GROUPS FOR THE LARGE UNDERGROUND WASTE STORAGE TANKS AT THE HANFORD SITE

    SciTech Connect (OSTI)

    BARKER, S.A.

    2006-07-27

    Waste stored within tank farm double-shell tanks (DST) and single-shell tanks (SST) generates flammable gas (principally hydrogen) to varying degrees depending on the type, amount, geometry, and condition of the waste. The waste generates hydrogen through the radiolysis of water and organic compounds, thermolytic decomposition of organic compounds, and corrosion of a tank's carbon steel walls. Radiolysis and thermolytic decomposition also generates ammonia. Nonflammable gases, which act as dilutents (such as nitrous oxide), are also produced. Additional flammable gases (e.g., methane) are generated by chemical reactions between various degradation products of organic chemicals present in the tanks. Volatile and semi-volatile organic chemicals in tanks also produce organic vapors. The generated gases in tank waste are either released continuously to the tank headspace or are retained in the waste matrix. Retained gas may be released in a spontaneous or induced gas release event (GRE) that can significantly increase the flammable gas concentration in the tank headspace as described in RPP-7771. The document categorizes each of the large waste storage tanks into one of several categories based on each tank's waste characteristics. These waste group assignments reflect a tank's propensity to retain a significant volume of flammable gases and the potential of the waste to release retained gas by a buoyant displacement event. Revision 5 is the annual update of the methodology and calculations of the flammable gas Waste Groups for DSTs and SSTs.

  15. METHODOLOGY & CALCULATIONS FOR THE ASSIGNMENT OF WASTE FOR THE LARGE UNDERGROUND WASTE STORAGE TANKS AT THE HANFORD SITE

    SciTech Connect (OSTI)

    TU, T.A.

    2007-01-04

    Waste stored within tank farm double-shell tanks (DST) and single-shell tanks (SST) generates flammable gas (principally hydrogen) to varying degrees depending on the type, amount, geometry, and condition of the waste. The waste generates hydrogen through the radiolysis of water and organic compounds, thermolytic decomposition of organic compounds, and corrosion of a tank's carbon steel walls. Radiolysis and thermolytic decomposition also generates ammonia. Nonflammable gases, which act as dilutents (such as nitrous oxide), are also produced. Additional flammable gases (e.g., methane) are generated by chemical reactions between various degradation products of organic chemicals present in the tanks. Volatile and semi-volatile organic chemicals in tanks also produce organic vapors. The generated gases in tank waste are either released continuously to the tank headspace or are retained in the waste matrix. Retained gas may be released in a spontaneous or induced gas release event (GRE) that can significantly increase the flammable gas concentration in the tank headspace as described in RPP-7771, Flammable Gas Safety Isme Resolution. Appendices A through I provide supporting information. The document categorizes each of the large waste storage tanks into one of several categories based on each tank's waste and characteristics. These waste group assignments reflect a tank's propensity to retain a significant volume of flammable gases and the potential of the waste to release retained gas by a buoyant displacement event. Revision 6 is the annual update of the flammable gas Waste Groups for DSTs and SSTs.

  16. The Treatment of Mixed Waste with GeoMelt In-Container Vitrification

    SciTech Connect (OSTI)

    Finucane, K.G.; Campbell, B.E.

    2006-07-01

    AMEC's GeoMelt{sup R} In-Container Vitrification (ICV){sup TM} has been used to treat diverse types of mixed low-level radioactive waste. ICV is effective in the treatment of mixed wastes containing polychlorinated biphenyls (PCBs) and other semi-volatile organic compounds, volatile organic compounds (VOCs) and heavy metals. The GeoMelt vitrification process destroys organic compounds and immobilizes metals and radionuclides in an extremely durable glass waste form. The process is flexible allowing for treatment of aqueous, oily, and solid mixed waste, including contaminated soil. In 2004, ICV was used to treat mixed radioactive waste sludge containing PCBs generated from a commercial cleanup project regulated by the Toxic Substances Control Act (TSCA), and to treat contaminated soil from Rocky Flats Environmental Technology Site. The Rocky Flats soil contained cadmium, PCBs, and depleted uranium. In 2005, AMEC completed a treatability demonstration of the ICV technology on Mock High Explosive from Sandia National Laboratories. This paper summarizes results from these mixed waste treatment projects. (authors)

  17. Fire hazards analysis of transuranic waste storage and assay facility

    SciTech Connect (OSTI)

    Busching, K.R., Westinghouse Hanford

    1996-07-31

    This document analyzes the fire hazards associated with operations at the Central Waste Complex. It provides the analysis and recommendations necessary to ensure compliance with applicable fire codes.

  18. Pump Jet Mixing and Pipeline Transfer Assessment for High-Activity Radioactive Wastes in Hanford Tank 241-AZ-102

    SciTech Connect (OSTI)

    Onishi, Yasuo; Recknagle, Kurtis P.; Wells, Beric E.

    2000-08-09

    This report evaluates how two 300-hp mixer pumps would mix solid and liquid radioactive wastes stored in Hanford double-shell Tank 241-AZ-102. It also assesses and confirms the adequacy of a 3-inch pipeline to transfer the resulting mixed waste slurry to the AP Tank Farm and ultimately to a planned waste treatment/vitrification plant on the Hanford Site.

  19. System Specification for Immobilized High-Level Waste Interim Storage

    SciTech Connect (OSTI)

    CALMUS, R.B.

    2000-12-27

    This specification establishes the system-level functional, performance, design, interface, and test requirements for Phase 1 of the IHLW Interim Storage System, located at the Hanford Site in Washington State. The IHLW canisters will be produced at the Hanford Site by a Selected DOE contractor. Subsequent to storage the canisters will be shipped to a federal geologic repository.

  20. A STUDY OF CORROSION AND STRESS CORROSION CRACKING OF CARBON STEEL NUCLEAR WASTE STORAGE TANKS

    SciTech Connect (OSTI)

    BOOMER, K.D.

    2007-08-21

    The Hanford reservation Tank Farms in Washington State has 177 underground storage tanks that contain approximately 50 million gallons of liquid legacy radioactive waste from cold war plutonium production. These tanks will continue to store waste until it is treated and disposed. These nuclear wastes were converted to highly alkaline pH wastes to protect the carbon steel storage tanks from corrosion. However, the carbon steel is still susceptible to localized corrosion and stress corrosion cracking. The waste chemistry varies from tank to tank, and contains various combinations of hydroxide, nitrate, nitrite, chloride, carbonate, aluminate and other species. The effect of each of these species and any synergistic effects on localized corrosion and stress corrosion cracking of carbon steel have been investigated with electrochemical polarization, slow strain rate, and crack growth rate testing. The effect of solution chemistry, pH, temperature and applied potential are all considered and their role in the corrosion behavior will be discussed.

  1. Radioactive waste shipments to Hanford retrievable storage from Babcock and Wilcox, Leechburg, Pennsylvania

    SciTech Connect (OSTI)

    Duncan, D.R.

    1994-02-14

    This report characterizes, as far as possible, the solid radioactive wastes generated by Babcock and Wilcox`s Park Township Plutonium Facility near Leechburg, Pennsylvania that were sent to retrievable storage at the Hanford Site. Solid waste as defined in this document is any containerized or self-contained material that has been declared waste. The objective is a description of characteristics of solid wastes that are or will be managed by the Restoration and Upgrades Program; gaseous or liquid effluents are discussed only at a summary level This characterization is of particular interest in the planning of transuranic (TRU) waste retrieval operations, including the Waste Receiving and Processing (WRAP) Facility, because Babcock and Wilcox generated greater than 2.5 percent of the total volume of TRU waste currently stored at the Hanford Site.

  2. Radioactive waste shipments to Hanford Retrievable Storage from the General Electric Vallecitos Nuclear Center, Pleasanton, California

    SciTech Connect (OSTI)

    Vejvoda, E.J.; Pottmeyer, J.A.; DeLorenzo, D.S.; Weyns-Rollosson, M.I.; Duncan, D.R.

    1993-10-01

    During the next two decades the transuranic (TRU) wastes now stored in the burial trenches and storage facilities at the Hanford Site are to be retrieved, processed at the Waste Receiving and Processing Facility, and shipped to the Waste Isolation Pilot Plant near Carlsbad, New Mexico for final disposal. Approximately 3.8% of the TRU waste to be retrieved for shipment to WIPP was generated at the General Electric (GE) Vallecitos Nuclear Center (VNC) in Pleasanton, California and shipped to the Hanford Site for storage. The purpose of this report is to characterize these radioactive solid wastes using process knowledge, existing records, and oral history interviews. The waste was generated almost exclusively from the activities, of the Plutonium Fuels Development Laboratory and the Plutonium Analytical Laboratory. Section 2.0 provides further details of the VNC physical plant, facility operations, facility history, and current status. The solid radioactive wastes were associated with two US Atomic Energy Commission/US Department of Energy reactor programs -- the Fast Ceramic Reactor (FCR) program, and the Fast Flux Test Reactor (FFTR) program. These programs involved the fabrication and testing of fuel assemblies that utilized plutonium in an oxide form. The types and estimated quantities of waste resulting from these programs are discussed in detail in Section 3.0. A detailed discussion of the packaging and handling procedures used for the VNC radioactive wastes shipped to the Hanford Site is provided in Section 4.0. Section 5.0 provides an in-depth look at this waste including the following: weight and volume of the waste, container types and numbers, physical description of the waste, radiological components, hazardous constituents, and current storage/disposal locations.

  3. Disposal of low-level and low-level mixed waste: audit report

    SciTech Connect (OSTI)

    1998-09-03

    The Department of Energy (Department) is faced with the legacy of thousands of contaminated areas and buildings and large volumes of `backlog` waste requiring disposal. Waste management and environmental restoration activities have become central to the Department`s mission. One of the Department`s priorities is to clean up former nuclear weapons sites and find more effective and timely methods for disposing of nuclear waste. This audit focused on determining if the Department was disposing of low-level and low-level mixed waste in the most cost-effective manner.

  4. Hanford facility dangerous waste permit application, 616 Nonradioactive dangerous waste storage facility

    SciTech Connect (OSTI)

    Price, S.M.

    1997-04-30

    This chapter provides information on the physical, chemical, and biological characteristics of the waste stored at the 616 NRDWSF. A waste analysis plan is included that describes the methodology used for determining waste types.

  5. Integrated Treatment and Storage Solutions for Solid Radioactive Waste at the Russian Shipyard Near Polyarny

    SciTech Connect (OSTI)

    Griffith, A.; Engoy, T.; Endregard, M.; Busmundrud, O.; Schwab, P.; Nazarian, A.; Krumrine, P.; Backe, S.; Gorin, S.; Evans, B.

    2002-02-27

    Russian Navy Yard No. 10 (Shkval), near the city of Murmansk, has been designated as the recipient for Solid Radioactive Waste (SRW) pretreatment and storage facilities under the Arctic Military Environmental Cooperation (AMEC) Program. This shipyard serves the Northern Fleet by servicing, repairing, and dismantling naval vessels. Specifically, seven nuclear submarines of the first and second generation and Victor class are laid up at this shipyard, awaiting defueling and dismantlement. One first generation nuclear submarine has already been dismantled there, but recently progress on dismantlement has slowed because all the available storage space is full. SRW has been placed in metal storage containers, which have been moved outside of the actual storage site, which increases the environmental risks. AMEC is a cooperative effort between the Russian Federation, Kingdom of Norway and the United States. AMEC Projects 1.3 and 1.4 specifically address waste treatment and storage issues. Various waste treatment options have been assessed, technologies selected, and now integrated facilities are being designed and constructed to address these problems. Treatment technologies that are being designed and constructed include a mobile pretreatment facility comprising waste assay, segregation, size reduction, compaction and repackaging operations. Waste storage technologies include metal and concrete containers, and lightweight modular storage buildings. This paper focuses on the problems and challenges that are and will be faced at the Polyarninsky Shipyard. Specifically, discussion of the waste quantities, types, and conditions and various site considerations versus the various technologies that are to be employed will be provided. A systems approach at the site is being proposed by the Russian partners, therefore integration with other ongoing and planned operations at the site will also be discussed.

  6. Mixed Waste Treatment Cost Analysis for a Range of GeoMelt Vitrification Process Configurations

    SciTech Connect (OSTI)

    Thompson, L. E.

    2002-02-27

    GeoMelt is a batch vitrification process used for contaminated site remediation and waste treatment. GeoMelt can be applied in several different configurations ranging from deep subsurface in situ treatment to aboveground batch plants. The process has been successfully used to treat a wide range of contaminated wastes and debris including: mixed low-level radioactive wastes; mixed transuranic wastes; polychlorinated biphenyls; pesticides; dioxins; and a range of heavy metals. Hypothetical cost estimates for the treatment of mixed low-level radioactive waste were prepared for the GeoMelt subsurface planar and in-container vitrification methods. The subsurface planar method involves in situ treatment and the in-container vitrification method involves treatment in an aboveground batch plant. The projected costs for the subsurface planar method range from $355-$461 per ton. These costs equate to 18-20 cents per pound. The projected cost for the in-container method is $1585 per ton. This cost equates to 80 cents per pound. These treatment costs are ten or more times lower than the treatment costs for alternative mixed waste treatment technologies according to a 1996 study by the US Department of Energy.

  7. Waste streams that preferentially corrode 55-gallon steel storage drums

    SciTech Connect (OSTI)

    Zirker, L.R.; Beitel, G.A.; Reece, C.M.

    1995-06-01

    When 55-gal steel drum waste containers fail in service, i.e., leak, corrode or breach, the standard fix has been to overpack the drum. When a drum fails and is overpacked into an 83-gal overpack drum, there are several negative consequences. Identifying waste streams that preferentially corrode steel drums is essential to the pollution prevention philosophy that ``an ounce of prevention is worth a pound of cure.`` It is essential that facilities perform pollution prevention measures at the front end of processes to reduce pollution on the back end. If these waste streams can be identified before they are packaged, the initial drum packaging system could be fortified or increased to eliminate future drum failures, breaches, clean-ups, and the plethora of other consequences. Therefore, a survey was conducted throughout the US Department of Energy complex for information concerning waste streams that have demonstrated preferential corrosion of 55-gal steel drums. From 21 site contacts, 21 waste streams were so identified. The major components of these waste streams include acids, salts, and solvent liquids, sludges, and still bottoms. The solvent-based waste streams typically had the shortest time to failure, 0.5 to 2 years. This report provides the results of this survey and research.

  8. Secure Long Term Storage of Waste Products at the Karlsruhe Research Center

    SciTech Connect (OSTI)

    Graf, A.; Merx, H.; Valencia, L.

    2002-02-27

    Due to the political situation in Germany there will presumably be no final disposal for radioactive waste in the next 30 years. This means, that the operators of nuclear facilities have to ensure a secure long term intermediate storage for radioactive waste products. The Karlsruhe Research Center operated and cooperated with different nuclear research facilities and laboratories with hot cells, which are now dismantled. During operation and decommissioning of the nuclear facilities radioactive waste was produced. The Central Decontamination Department (HDB) of the Research Center Karlsruhe has been conditioning radioactive waste into waste products for final disposal. Until the opening of a final disposal the resulting waste products will have to be stored at the HDB. To ensure secure long term storage, quality preserving measures will have to be taken. For example, the corrosion-preventing coating of the containers has to be kept intact. In case of damage the container has to be repaired or should be replaced. Another long term protection measure is the casting of drums in concrete inside the containers. This provides an additional barrier layer in case of drum corrosion. At HDB 46,500 m{sup 3} of radioactive waste products are in intermediate storage. The main project of the next few years will be the realization of the quality measures. In this paper the different methods are described in detail.

  9. A preliminary evaluation of alternatives for treatment of INEL Low-Level Waste and low-level mixed waste

    SciTech Connect (OSTI)

    Smith, T.H.; Roesener, W.S.; Jorgensen-Waters, M.J.; Edinborough, C.R.

    1992-06-01

    The Mixed and Low-Level Waste Treatment Facility (MLLWTF) project was established in 1991 by the US Department of Energy Idaho Field Office to provide treatment capabilities for Idaho National Engineering Laboratory (INEL) low-level mixed waste and low-level waste. This report identifies and evaluates the alternatives for treating that waste. Twelve treatment alternatives, ranging from ``no-action`` to constructing and operating the MLLWTF, are identified and evaluated. Evaluations include facility performance, environmental, safety, institutional, schedule, and rough order-of-magnitude cost comparisons. The performance of each alternative is evaluated against lists of ``musts`` and ``wants.`` Also included is a discussion of other key considerations for decision making. Analysis of results indicated further study is necessary to obtain the best estimate of future waste volumes and characteristics from the expanded INEL Decontamination and Decommissioning Program. It is also recommended that conceptual design begin as scheduled on the MLLWTF, maximum treatment alternative while re-evaluating the waste volume projections.

  10. Moving Forward to Address Nuclear Waste Storage and Disposal

    Broader source: Energy.gov [DOE]

    Today, Secretary Moniz announced that the Energy Department is moving forward with planning for a separate repository for high-level radioactive waste resulting from atomic energy defense activities.

  11. Stabilization of liquid low-level and mixed wastes: a treatability study

    SciTech Connect (OSTI)

    Carson, S.; Cheng, Yu-Cheng; Yellowhorse, L.; Peterson, P.

    1996-02-01

    A treatability study has been conducted on liquid low-level and mixed wastes using the stabilization agents Aquaset, Aquaset II, Aquaset II-H, Petroset, Petroset-H, and Petroset and Petroset II. A total of 40 different waste types with activities ranging from 10{sup {minus}14} to 10{sup {minus}4} curies/ml have been stabilized. Reported data for each waste include its chemical and radiological composition and the optimum composition or range of compositions (weight of agent/volume of waste) for each stabilization agent used. All wastes were successfully stabilized with one or more of the stabilization agents and all final waste forms passed the Paint Filter Liquids Test (EPA Method 9095).

  12. Statement of position of the United States Department of Energy in the matter of proposed rulemaking on the storage and disposal of nuclear waste (waste confidence rulemaking)

    SciTech Connect (OSTI)

    1980-04-15

    Purpose of this proceeding is to assess generically the degree of assurance that the radioactive waste can be safely disposed of, to determine when such disposal or off-site storage will be available, and to determine whether wastes can be safely stored on-site past license expiration until off-site disposal/storage is available. (DLC)

  13. A strategy for resolving high-priority Hanford Site radioactive waste storage tank safety issues

    SciTech Connect (OSTI)

    Babad, H.; DeFigh-Price, C.; Fulton, J.C.

    1993-02-01

    High-activity radioactive waste has been stored in large underground storage tanks at the US Department of Energy`s (DOE) Hanford Site in Eastern Washington State since 1944. Since then, more than 227,000 m{sup 3} (60 Mgal) of waste have been accumulated in 177 tanks. These caustic wastes consist of many different chemicals. The waste forms include liquids, slurries, salt cakes, and sludges. A number of safety issues have been raised about these wastes, and resolution of these issues is a top priority of DOE. A Waste Tank Safety Program has been established to resolve these high-priority safety issues. This paper will deal with three of these issues. The issues described are the release of flammable vapors from single- and double-shell tanks, the existence of organic chemicals, and/or ferrocyanide ion-containing fuel-rich mixtures of nitrate and nitrite salts in single-shell tanks.

  14. Task 1.6 -- Mixed waste treatment. Semi-annual report, January 1--June 30, 1995

    SciTech Connect (OSTI)

    Rindt, J.R.

    1997-08-01

    Mixed-waste sites make up the majority of contaminated sites, yet remediation techniques used at such sites often target only the most prevalent contaminant. A better understanding of site situation (i.e., most common types of contamination), current remediation techniques, and combinations of techniques would provide insight into areas in which further research should be performed. The first half of this task program year consisted of a survey of common types of mixed-wastes sites and a detailed literature search of the remediation techniques and combinations of techniques that were currently available. From this information, an assessment of each of the techniques was made and combined into various ways appropriate to mixed-waste protocol. This activity provided insight into areas in which further research should be performed.

  15. Status of inventory, recycling, and storage of hazardous waste in Kazakstan

    SciTech Connect (OSTI)

    Yermekbayeva, L.

    1996-12-31

    Conditions associated with toxic and radioactive waste in the Republic of Kazakstan are discussed. At present, more than 19 billion tons of various wastes, including toxic, radioactive, and other hazardous waste, have accumulated in the country, and about 1 billion tons of waste are generated each year. Ecological legislation for toxic waste storage is being examined. However, the definition and classification of waste inventories are not finalized. Furthermore, the country does not have sites for salvaging, rendering harmless, or disposing of these wastes. Kazakstan also has problems with radioactive waste that are complicated by the activity at the Semipalatinsk nuclear testing site. Here, nuclear explosions occurred because of economic and other reasons. In ecologically challenged regions, high levels of pollutants from chemical, toxic, industrial, and radioactive wastes and pesticides cause many diseases. These complex problems may be resolved by establishing a Governmental body to manage industrial and consumer waste, including toxic and radioactive waste, and also by developing legal and other regulations. 3 tabs.

  16. Performance assessment for continuing and future operations at solid waste storage area 6

    SciTech Connect (OSTI)

    1997-09-01

    This revised performance assessment (PA) for the continued disposal operations at Solid Waste Storage Area (SWSA) 6 on the Oak Ridge Reservation (ORR) has been prepared to demonstrate compliance with the performance objectives for low-level radioactive waste (LLW) disposal contained in the US Department of Energy (DOE) Order 5820.2A. This revised PA considers disposal operations conducted from September 26, 1988, through the projects lifetime of the disposal facility.

  17. Treatment of EBR-I NaK mixed waste at Argonne National Laboratory and subsequent land disposal at the Idaho National Engineering and Environmental Laboratory.

    SciTech Connect (OSTI)

    Herrmann, S. D.; Buzzell, J. A.; Holzemer, M. J.

    1998-02-03

    Sodium/potassium (NaK) liquid metal coolant, contaminated with fission products from the core meltdown of Experimental Breeder Reactor I (EBR-I) and classified as a mixed waste, has been deactivated and converted to a contact-handled, low-level waste at Argonne's Sodium Component Maintenance Shop and land disposed at the Radioactive Waste Management Complex. Treatment of the EBR-I NaK involved converting the sodium and potassium to its respective hydroxide via reaction with air and water, followed by conversion to its respective carbonate via reaction with carbon dioxide. The resultant aqueous carbonate solution was solidified in 55-gallon drums. Challenges in the NaK treatment involved processing a mixed waste which was incompletely characterized and difficult to handle. The NaK was highly radioactive, i.e. up to 4.5 R/hr on contact with the mixed waste drums. In addition, the potential existed for plutonium and toxic characteristic metals to be present in the NaK, resultant from the location of the partial core meltdown of EBR-I in 1955. Moreover, the NaK was susceptible to degradation after more than 40 years of storage in unmonitored conditions. Such degradation raised the possibility of energetic exothermic reactions between the liquid NaK and its crust, which could have consisted of potassium superoxide as well as hydrated sodium/potassium hydroxides.

  18. Phosphate glasses for radioactive, hazardous and mixed waste immobilization

    DOE Patents [OSTI]

    Cao, H.; Adams, J.W.; Kalb, P.D.

    1998-11-24

    Lead-free phosphate glass compositions are provided which can be used to immobilize low level and/or high level radioactive wastes in monolithic waste forms. The glass composition may also be used without waste contained therein. Lead-free phosphate glass compositions prepared at about 900 C include mixtures from about 1--6 mole % iron (III) oxide, from about 1--6 mole % aluminum oxide, from about 15--20 mole % sodium oxide or potassium oxide, and from about 30--60 mole % phosphate. The invention also provides phosphate, lead-free glass ceramic glass compositions which are prepared from about 400 C to about 450 C and which includes from about 3--6 mole % sodium oxide, from about 20--50 mole % tin oxide, from about 30--70 mole % phosphate, from about 3--6 mole % aluminum oxide, from about 3--8 mole % silicon oxide, from about 0.5--2 mole % iron (III) oxide and from about 3--6 mole % potassium oxide. Method of making lead-free phosphate glasses are also provided. 8 figs.

  19. Phosphate glasses for radioactive, hazardous and mixed waste immobilization

    DOE Patents [OSTI]

    Cao, Hui; Adams, Jay W.; Kalb, Paul D.

    1998-11-24

    Lead-free phosphate glass compositions are provided which can be used to immobilize low level and/or high level radioactive wastes in monolithic waste forms. The glass composition may also be used without waste contained therein. Lead-free phosphate glass compositions prepared at about 900.degree. C. include mixtures from about 1 mole % to about 6 mole % iron (III) oxide, from about 1 mole % to about 6 mole % aluminum oxide, from about 15 mole % to about 20 mole % sodium oxide or potassium oxide, and from about 30 mole % to about 60 mole % phosphate. The invention also provides phosphate, lead-free glass ceramic glass compositions which are prepared from about 400.degree. C. to about 450.degree. C. and which includes from about 3 mole % to about 6 mole % sodium oxide, from about 20 mole % to about 50 mole % tin oxide, from about 30 mole % to about 70 mole % phosphate, from about 3 mole % to about 6 mole % aluminum oxide, from about 3 mole % to about 8 mole % silicon oxide, from about 0.5 mole % to about 2 mole % iron (III) oxide and from about 3 mole % to about 6 mole % potassium oxide. Method of making lead-free phosphate glasses are also provided.

  20. Phosphate glasses for radioactive, hazardous and mixed waste immobilization

    DOE Patents [OSTI]

    Cao, H.; Adams, J.W.; Kalb, P.D.

    1999-03-09

    Lead-free phosphate glass compositions are provided which can be used to immobilize low level and/or high level radioactive wastes in monolithic waste forms. The glass composition may also be used without waste contained therein. Lead-free phosphate glass compositions prepared at about 900 C include mixtures from about 1 mole % to about 6 mole % iron (III) oxide, from about 1 mole % to about 6 mole % aluminum oxide, from about 15 mole % to about 20 mole % sodium oxide or potassium oxide, and from about 30 mole % to about 60 mole % phosphate. The invention also provides phosphate, lead-free glass ceramic glass compositions which are prepared from about 400 C to about 450 C and which includes from about 3 mole % to about 6 mole % sodium oxide, from about 20 mole % to about 50 mole % tin oxide, from about 30 mole % to about 70 mole % phosphate, from about 3 mole % to about 6 mole % aluminum oxide, from about 3 mole % to about 8 mole % silicon oxide, from about 0.5 mole % to about 2 mole % iron (III) oxide and from about 3 mole % to about 6 mole % potassium oxide. Method of making lead-free phosphate glasses are also provided. 8 figs.

  1. Phosphate glasses for radioactive, hazardous and mixed waste immobilization

    DOE Patents [OSTI]

    Cao, Hui; Adams, Jay W.; Kalb, Paul D.

    1999-03-09

    Lead-free phosphate glass compositions are provided which can be used to immobilize low level and/or high level radioactive wastes in monolithic waste forms. The glass composition may also be used without waste contained therein. Lead-free phosphate glass compositions prepared at about 900.degree. C. include mixtures from about 1 mole % to about 6 mole %.iron (III) oxide, from about 1 mole % to about 6 mole % aluminum oxide, from about 15 mole % to about 20 mole % sodium oxide or potassium oxide, and from about 30 mole % to about 60 mole % phosphate. The invention also provides phosphate, lead-free glass ceramic glass compositions which are prepared from about 400.degree. C. to about 450.degree. C. and which includes from about 3 mole % to about 6 mole % sodium oxide, from about 20 mole % to about 50 mole % tin oxide, from about 30 mole % to about 70 mole % phosphate, from about 3 mole % to about 6 mole % aluminum oxide, from about 3 mole % to about 8 mole % silicon oxide, from about 0.5 mole % to about 2 mole % iron (III) oxide and from about 3 mole % to about 6 mole % potassium oxide. Method of making lead-free phosphate glasses are also provided.

  2. Cementation and solidification of miscellaneous mixed wastes at the Rocky Flats Environmental Technology Site

    SciTech Connect (OSTI)

    Phillips, J.A.; Semones, G.B.

    1995-02-01

    The Rocky Flats Environmental Technology Site produces a variety of wastes which are amenable to micro-encapsulation in cement Portland cement is an inexpensive and readily available material for this application. The Waste Projects (WP) group at Rocky Flats evaluated cementation to determine its effectiveness in encapsulating several wastes. These included waste analytical laboratory solutions, incinerator ash, hydroxide precipitation sludge, and an acidic solution from the Delphi process (a chemical oxidation technology being evaluated as an alternative to incineration). WP prepared surrogate wastes and conducted designed experiments to optimize the cement formulation for the waste streams. These experiments used a Taguchi or factorial experimental design, interactions between the variables were also considered in the testing. Surrogate waste samples were spiked with various levels of each of six Resource Conservation and Recovery Act (RCRA) listed metals (Cd, Cr, Ba, Pb, Ni, and Ag), cemented using the optimized formulation, and analyzed for leach resistance using the Toxicity Characteristic Leaching Procedure (TCLP). The metal spike levels chosen were based on characterization data, and also based on an estimate of the highest levels of contaminants suspected in the waste. This paper includes laboratory test results for each waste studied. These include qualitative observations as well as quantitative data from TCLP analyses and environmental cycling studies. The results from these experiments show that cement stabilization of the different wastes can produce final waste forms which meet the current RCRA Land Disposal Restriction (LDR) requirements. Formulations that resulted in LDR compliant waste forms are provided. The volume increases associated with cementation are also lower than anticipated. Future work will include verification studies with actual mixed radioactive waste as well as additional formulation development studies on other waste streams.

  3. Process for the encapsulation and stabilization of radioactive, hazardous and mixed wastes

    DOE Patents [OSTI]

    Colombo, Peter; Kalb, Paul D.; Heiser, III, John H.

    1997-11-14

    The present invention provides a method for encapsulating and stabilizing radioactive, hazardous and mixed wastes in a modified sulfur cement composition. The waste may be incinerator fly ash or bottom ash including radioactive contaminants, toxic metal salts and other wastes commonly found in refuse. The process may use glass fibers mixed into the composition to improve the tensile strength and a low concentration of anhydrous sodium sulfide to reduce toxic metal solubility. The present invention preferably includes a method for encapsulating radioactive, hazardous and mixed wastes by combining substantially anhydrous wastes, molten modified sulfur cement, preferably glass fibers, as well as anhydrous sodium sulfide or calcium hydroxide or sodium hydroxide in a heated double-planetary orbital mixer. The modified sulfur cement is preheated to about 135.degree..+-.5.degree. C., then the remaining substantially dry components are added and mixed to homogeneity. The homogeneous molten mixture is poured or extruded into a suitable mold. The mold is allowed to cool, while the mixture hardens, thereby immobilizing and encapsulating the contaminants present in the ash.

  4. Mixed waste paper to ethanol fuel. A technology, market, and economic assessment for Washington

    SciTech Connect (OSTI)

    Not Available

    1991-01-01

    The objectives of this study were to evaluate the use of mixed waste paper for the production of ethanol fuels and to review the available conversion technologies, and assess developmental status, current and future cost of production and economics, and the market potential. This report is based on the results of literature reviews, telephone conversations, and interviews. Mixed waste paper samples from residential and commercial recycling programs and pulp mill sludge provided by Weyerhauser were analyzed to determine the potential ethanol yields. The markets for ethanol fuel and the economics of converting paper into ethanol were investigated.

  5. Operating cost guidelines for benchmarking DOE thermal treatment systems for low-level mixed waste

    SciTech Connect (OSTI)

    Salmon, R.; Loghry, S.L.; Hermes, W.H.

    1994-11-01

    This report presents guidelines for estimating operating costs for use in benchmarking US Department of Energy (DOE) low-level mixed waste thermal treatment systems. The guidelines are based on operating cost experience at the DOE Toxic Substances Control Act (TSCA) mixed waste incinerator at the K-25 Site at Oak Ridge. In presenting these guidelines, it should be made clear at the outset that it is not the intention of this report to present operating cost estimates for new technologies, but only guidelines for estimating such costs.

  6. Mixed and Low-Level Waste Treatment Facility Project. Appendix B, Waste stream engineering files: Part 2, Low-level waste streams

    SciTech Connect (OSTI)

    Not Available

    1992-04-01

    Mixed and low-level wastes generated at the Idaho National Engineering Laboratory (INEL) are required to be managed according to applicable State and Federal regulations, and Department of Energy Orders that provide for the protection of human health and the environment. The Mixed and Low-Level Waste Treatment Facility Project was chartered in 1991, by the Department of Energy to provide treatment capability for these mixed and low-level waste streams. The first project task consisted of conducting engineering studies to identify the waste streams, their potential treatment strategies, and the requirements that would be imposed on the waste streams and the facilities used to process them. This report documents those studies so the project can continue with an evaluation of programmatic options, system tradeoff studies, and the conceptual design phase of the project. This report, appendix B, comprises the engineering design files for this project study. The engineering design files document each waste steam, its characteristics, and identified treatment strategies.

  7. Evapotranspiration Cover for the 92-Acre Area Retired Mixed Waste Pits:Interim CQA Report

    SciTech Connect (OSTI)

    The Delphi Groupe, Inc., and J. A. Cesare and Associates, Inc.

    2011-06-20

    This Interim Construction Quality Assurance (CQA) Report is for the 92-Acre Evapotranspiration Cover, Area 5 Waste Management Division (WMD) Retired Mixed Waste Pits, Nevada National Security Site, Nevada for the period of January 20, 2011 to May 12, 2011. This Interim Construction Quality Assurance (CQA) Report is for the 92-Acre Evapotranspiration Cover, Area 5 Waste Management Division (WMD) Retired Mixed Waste Pits, Nevada National Security Site, Nevada for the period of January 20, 2011 to May 12, 2011. Construction was approved by the Nevada Division of Environmental Protection (NDEP) under the Approval of Corrective Action Decision Document/Corrective Action Plan (CADD/CAP) for Corrective Action Unit (CAU) 111: Area 5 WMD Retired Mixed Waste Pits, Nevada National Security Site, Nevada, on January 6, 2011, pursuant to Subpart XII.8a of the Federal Facility Agreement and Consent Order. The project is located in Area 5 of the Radioactive Waste Management Complex (RWMC) at the Nevada National Security Site (NNSS), formerly known as the Nevada Test Site, located in southern Nevada, approximately 65 miles northwest of Las Vegas, Nevada, in Nye County. The project site, in Area 5, is located in a topographically closed basin approximately 14 additional miles north of Mercury Nevada, in the north-central part of Frenchman Flat. The Area 5 RWMS uses engineered shallow-land burial cells to dispose of packaged waste. The 92-Acre Area encompasses the southern portion of the Area 5 RWMS, which has been designated for the first final closure operations. This area contains 13 Greater Confinement Disposal (GCD) boreholes, 16 narrow trenches, and 9 broader pits. With the exception of two active pits (P03 and P06), all trenches and pits in the 92-Acre Area had operational covers approximately 2.4 meters thick, at a minimum, in most areas when this project began. The units within the 92-Acre Area are grouped into the following six informal categories based on physical location

  8. Solidification of radioactive waste resins using cement mixed with organic material

    SciTech Connect (OSTI)

    Laili, Zalina; Yasir, Muhamad Samudi; Wahab, Mohd Abdul

    2015-04-29

    Solidification of radioactive waste resins using cement mixed with organic material i.e. biochar is described in this paper. Different percentage of biochar (0%, 5%, 8%, 11%, 14% and 18%) was investigated in this study. The characteristics such as compressive strength and leaching behavior were examined in order to evaluate the performance of solidified radioactive waste resins. The results showed that the amount of biochar affect the compressive strength of the solidified resins. Based on the data obtained for the leaching experiments performed, only one formulation showed the leached of Cs-134 from the solidified radioactive waste resins.

  9. System and method for the capture and storage of waste

    SciTech Connect (OSTI)

    Nenoff, Tina M.; Sava Gallis, Dorina Florentina; Chapman, Karena; Chupas, Peter

    2015-10-20

    The present disclosure is directed to systems and methods that absorb waste into a metal-organic framework (MOF), and applying pressure to the MOF material's framework to crystallize or make amorphous the MOF material thereby changing the MOF's pore structure and sorption characteristics without collapsing the MOF framework.

  10. Hanford/Rocky Flats collaboration on development of supercritical carbon dioxide extraction to treat mixed waste

    SciTech Connect (OSTI)

    Hendrickson, D.W.; Biyani, R.K.; Brown, C.M.; Teter, W.L.

    1995-11-01

    Proposals for demonstration work under the Department of Energy`s Mixed Waste Focus Area, during the 1996 through 1997 fiscal years included two applications of supercritical carbon dioxide to mixed waste pretreatment. These proposals included task RF15MW58 of Rocky Flats and task RL46MW59 of Hanford. Analysis of compatibilities in wastes and work scopes yielded an expectation of substantial collaboration between sites whereby Hanford waste streams may undergo demonstration testing at Rocky Flats, thereby eliminating the need for test facilities at Hanford. This form of collaboration is premised the continued deployment at Rocky Flats and the capability for Hanford samples to be treated at Rocky Flats. The recent creation of a thermal treatment contract for a facility near Hanford may alleviate the need to conduct organic extraction upon Rocky Flats wastes by providing a cost effective thermal treatment alternative, however, some waste streams at Hanford will continue to require organic extraction. Final site waste stream treatment locations are not within the scope of this document.

  11. Cryograb: A Novel Approach to the Retrieval of Waste from Underground Storage Tanks - 13501

    SciTech Connect (OSTI)

    O'Brien, Luke; Baker, Stephen; Bowen, Bob; Mallick, Pramod; Smith, Gary; King, Bill; Judd, Laurie

    2013-07-01

    The UK's National Nuclear Laboratory (NNL) is investigating the use of cryogenic technology for the recovery of nuclear waste. Cryograb, freezing the waste on a 'cryo-head' and then retrieves it as a single mass which can then be treated or stabilized as necessary. The technology has a number of benefits over other retrieval approaches in that it minimizes sludge disturbance thereby reducing effluent arising and it can be used to de-water, and thereby reduce the volume of waste. The technology has been successfully deployed for a variety of nuclear and non-nuclear waste recovery operations. The application of Cryograb for the recovery of waste from US underground storage tanks is being explored through a US DOE International Technology Transfer and Demonstration programme. A sample deployment being considered involves the recovery of residual mounds of sludge material from waste storage tanks at Savannah River. Operational constraints and success criteria were agreed prior to the completion of a process down selection exercise which specified the preferred configuration of the cryo-head and supporting plant. Subsequent process modeling identified retrieval rates and temperature gradients through the waste and tank infrastructure. The work, which has been delivered in partnership with US DOE, SRNL, NuVision Engineering and Frigeo AB has demonstrated the technical feasibility of the approach (to TRL 2) and has resulted in the allocation of additional funding from DOE to take the programme to bench and cold pilot-scale trials. (authors)

  12. Case Study in Corporate Memory Recovery: Hanford Tank Farms Miscellaneous Underground Waste Storage Tanks - 15344

    SciTech Connect (OSTI)

    Washenfelder, D. J.; Johnson, J. M.; Turknett, J. C.; Barnes, T. J.; Duncan, K. G.

    2015-01-07

    In addition to managing the 177 underground waste storage tanks containing 212,000 m3 (56 million gal) of radioactive waste at the U. S. Department of Energy’s Hanford Site 200 Area Tank Farms, Washington River Protection Solutions LLC is responsible for managing numerous small catch tanks and special surveillance facilities. These are collectively known as “MUSTs” - Miscellaneous Underground Storage Tanks. The MUSTs typically collected drainage and flushes during waste transfer system piping changes; special surveillance facilities supported Tank Farm processes including post-World War II uranium recovery and later fission product recovery from tank wastes. Most were removed from service following deactivation of the single-shell tank system in 1980 and stabilized by pumping the remaining liquids from them. The MUSTs were isolated by blanking connecting transfer lines and adding weatherproofing to prevent rainwater entry. Over the next 30 years MUST operating records were dispersed into large electronic databases or transferred to the National Archives Regional Center in Seattle, Washington. During 2014 an effort to reacquire the historical bases for the MUSTs’ published waste volumes was undertaken. Corporate Memory Recovery from a variety of record sources allowed waste volumes to be initially determined for 21 MUSTs, and waste volumes to be adjusted for 37 others. Precursors and symptoms of Corporate Memory Loss were identified in the context of MUST records recovery.

  13. Method for immobilizing mixed waste chloride salts containing radionuclides and other hazardous wastes

    DOE Patents [OSTI]

    Lewis, Michele A.; Johnson, Terry R.

    1993-01-01

    The invention is a method for the encapsulation of soluble radioactive waste chloride salts containing radionuclides such as strontium, cesium and hazardous wastes such as barium so that they may be permanently stored without future threat to the environment. The process consists of contacting the salts containing the radionuclides and hazardous wastes with certain zeolites which have been found to ion exchange with the radionuclides and to occlude the chloride salts so that the resulting product is leach resistant.

  14. Method for immobilizing mixed waste chloride salts containing radionuclides and other hazardous wastes

    DOE Patents [OSTI]

    Lewis, Michele A.; Johnson, Terry R.

    1993-09-07

    The invention is a method for the encapsulation of soluble radioactive waste chloride salts containing radionuclides such as strontium, cesium and hazardous wastes such as barium so that they may be permanently stored without future threat to the environment. The process consists of contacting the salts containing the radionuclides and hazardous wastes with certain zeolites which have been found to ion exchange with the radionuclides and to occlude the chloride salts so that the resulting product is leach resistant.

  15. Estimating heel retrieval costs for underground storage tank waste at Hanford. Draft

    SciTech Connect (OSTI)

    DeMuth, S.

    1996-08-26

    Approximately 100 million gallons ({approx}400,000 m{sup 3}) of existing U.S. Department of Energy (DOE) owned radioactive waste stored in underground tanks can not be disposed of as low-level waste (LLW). The current plan for disposal of UST waste which can not be disposed of as LLW is immobilization as glass and permanent storage in an underground repository. Disposal of LLW generally can be done sub-surface at the point of origin. Consequently, LLW is significantly less expensive to dispose of than that requiring an underground repository. Due to the lower cost for LLW disposal, it is advantageous to separate the 100 million gallons of waste into a small volume of high-level waste (HLW) and a large volume of LLW.

  16. Performance assessment for continuing and future operations at solid waste storage area 6. Appendices

    SciTech Connect (OSTI)

    1997-09-01

    This appendix provides the radionuclide inventory data used for the Solid Waste Storage Area (SWSA) 6 Performance Assessment (PA). The uncertainties in the radionuclide inventory data are also provided, along with the descriptions of the methods used to estimate the uncertainties.

  17. Spent fuel storage and waste management fuel cycle optimization using CAFCA

    SciTech Connect (OSTI)

    Brinton, S.; Kazimi, M.

    2013-07-01

    Spent fuel storage modeling is at the intersection of nuclear fuel cycle system dynamics and waste management policy. A model that captures the economic parameters affecting used nuclear fuel storage location options, which complements fuel cycle economic assessment has been created using CAFCA (Code for Advanced Fuel Cycles Assessment) of MIT. Research has also expanded to the study on dependency of used nuclear fuel storage economics, environmental impact, and proliferation risk. Three options of local, regional, and national storage were studied. The preliminary product of this research is the creation of a system dynamics tool known as the Waste Management Module which provides an easy to use interface for education on fuel cycle waste management economic impacts. Storage options costs can be compared to literature values with simple variation available for sensitivity study. Additionally, a first of a kind optimization scheme for the nuclear fuel cycle analysis is proposed and the applications of such an optimization are discussed. The main tradeoff for fuel cycle optimization was found to be between economics and most of the other identified metrics. (authors)

  18. Preparation of delisting petition for SRS (Savannah River Site) raw materials waste sludge---Mixed F006 waste

    SciTech Connect (OSTI)

    Langton, C.A.

    1989-01-01

    Waste sludge from the raw materials manufacturing facility at the Savannah River Site contains both hazardous and low-level radioactive components. This waste, which contains electroplating sludge and depleted uranium, is classified as a mixed waste. The objective of the delisting petition is to demonstrate that this waste can be treated/solidified in a cement-based material and disposed of in concrete vaults so that drinking water standards will not be exceeded. Sampling and analytical data which support this petition will be presented. Results show that when the data are applied to the EPA Vertical and Horizontal Spread Model, health-based standards for all hazardous waste constituents will not be exceeded during worst case operating and environmental conditions. Disposal of stabilized sludge in concrete vaults will also meet the requirements of DOE Order 5820.2A and the March 9, 1988 DOE Record of Decision which outline criteria for low-level radioactive waste disposal at the Savannah River Site. 9 refs., 2 figs., 3 tabs.

  19. Advanced Mixed Waste Treatment Project Achieves Impressive Safety and Production Marks

    Broader source: Energy.gov [DOE]

    IDAHO FALLS, Idaho – 14M50K is the new, genuinely unique vanity plate that only the 620 employees at EM’s Advanced Mixed Waste Treatment Project (AMWTP) at the Idaho site have earned the right to put on their vehicles.

  20. Systems Engineering Plan and project record Configuration Management Plan for the Mixed Waste Disposal Initiative

    SciTech Connect (OSTI)

    Bryan, W.E.; Oakley, L.B.

    1993-04-01

    This document summarizes the systems engineering assessment that was performed for the Mixed Waste Disposal Initiative (MWDI) Project to determine what types of documentation are required for the success of the project. The report also identifies the documents that will make up the MWDI Project Record and describes the Configuration Management Plan describes the responsibilities and process for making changes to project documentation.

  1. Environmental Assessment Offsite Thermal Treatment of Low-Level Mixed Waste

    SciTech Connect (OSTI)

    N /A

    1999-05-06

    The U.S. Department of Energy (DOE), Richland Operations Office (RL) needs to demonstrate the economics and feasibility of offsite commercial treatment of contact-handled low-level mixed waste (LLMW), containing polychlorinated biphenyls (PCBS) and other organics, to meet existing regulatory standards for eventual disposal.

  2. Compliance matrix for the mixed waste disposal facilities, trenches 31 and 34, burial ground 218-W-5. Revision 2

    SciTech Connect (OSTI)

    Johnson, K.D.

    1995-05-03

    This document provides a listing of applicable regulatory requirements to the Mixed Waste Disposal trenches. After the listing of regulations to be followed is a listing of documents that show how the regulations are being implemented and followed for the Mixed Waste trenches.

  3. Structural and seismic analyses of waste facility reinforced concrete storage vaults

    SciTech Connect (OSTI)

    Wang, C.Y.

    1995-07-01

    Facility 317 of Argonne National Laboratory consists of several reinforced concrete waste storage vaults designed and constructed in the late 1940`s through the early 1960`s. In this paper, structural analyses of these concrete vaults subjected to various natural hazards are described, emphasizing the northwest shallow vault. The natural phenomenon hazards considered include both earthquakes and tornados. Because these vaults are deeply embedded in the soil, the SASSI (System Analysis of Soil-Structure Interaction) code was utilized for the seismic calculations. The ultimate strength method was used to analyze the reinforced concrete structures. In all studies, moment and shear strengths at critical locations of the storage vaults were evaluated. Results of the structural analyses show that almost all the waste storage vaults meet the code requirements according to ACI 349--85. These vaults also satisfy the performance goal such that confinement of hazardous materials is maintained and functioning of the facility is not interrupted.

  4. Processing results of 1,800 gallons of mercury and radioactively contaminated mixed waste rinse solution

    SciTech Connect (OSTI)

    Thiesen, B.P.

    1993-01-01

    The mercury-contaminated rinse solution (INEL waste ID{number_sign} 123; File 8 waste) was successfully treated at the Idaho National Engineering Laboratory (INEL). This waste was generated during the decontamination of the Heat Transfer Reactor Experiment 3 (HTRE-3) reactor shield tank. Approximately 1,800 gal of waste was generated and was placed into 33 drums. Each drum contained precipitated sludge material ranging from 1--10 in. in depth, with the average depth of about 2.5 in. The pH of each drum varied from 3--11. The bulk liquid waste had a mercury level of 7.0 mg/l, which exceeded the Resource Conservation and Recovery Act (RCRA) limit of 0.2 mg/l. The average liquid bulk radioactivity was about 2.1 pCi/ml, while the average sludge contamination was about 13,800 pci/g. Treatment of the waste required separation of the liquid from the sludge, filtration, pH adjustment, and ion exchange. Because of difficulties in processing, three trials were required to reduce the mercury levels to below the RCRA limit. In the first trial, insufficient filtration of the waste allowed solid particulate produced during pH adjustment to enter into the ion exchange columns and ultimately the waste storage tank. In the second trial, the waste was filtered down to 0.1 {mu} to remove all solid mercury compounds. However, before filtration could take place, a solid mercury complex dissolved and mercury levels exceeded the RCRA limit after filtration. In the third trial, the waste was filtered through 0.3-A filters and then passed through the S-920 resin to remove the dissolved mercury. The resulting solution had mercury levels at 0.0186 mg/l and radioactivity of 0.282 pCi/ml. This solution was disposed of at the TAN warm waste pond, TAN782, TSF-10.

  5. High-level waste canister storage final design, installation, and testing. Topical report

    SciTech Connect (OSTI)

    Connors, B.J.; Meigs, R.A.; Pezzimenti, D.M.; Vlad, P.M.

    1998-04-01

    This report is a description of the West Valley Demonstration Project`s radioactive waste storage facility, the Chemical Process Cell (CPC). This facility is currently being used to temporarily store vitrified waste in stainless steel canisters. These canisters are stacked two-high in a seismically designed rack system within the cell. Approximately 300 canisters will be produced during the Project`s vitrification campaign which began in June 1996. Following the completion of waste vitrification and solidification, these canisters will be transferred via rail or truck to a federal repository (when available) for permanent storage. All operations in the CPC are conducted remotely using various handling systems and equipment. Areas adjacent to or surrounding the cell provide capabilities for viewing, ventilation, and equipment/component access.

  6. Closure of hazardous and mixed radioactive waste management units at DOE facilities. [Contains glossary

    SciTech Connect (OSTI)

    Not Available

    1990-06-01

    This is document addresses the Federal regulations governing the closure of hazardous and mixed waste units subject to Resource Conservation and Recovery Act (RCRA) requirements. It provides a brief overview of the RCRA permitting program and the extensive RCRA facility design and operating standards. It provides detailed guidance on the procedural requirements for closure and post-closure care of hazardous and mixed waste management units, including guidance on the preparation of closure and post-closure plans that must be submitted with facility permit applications. This document also provides guidance on technical activities that must be conducted both during and after closure of each of the following hazardous waste management units regulated under RCRA.

  7. Management of hazardous waste containers and container storage areas under the Resource Conservation and Recovery Act

    SciTech Connect (OSTI)

    Not Available

    1993-08-01

    DOE`s Office of Environmental Guidance, RCRA/CERCLA Division, has prepared this guidance document to assist waste management personnel in complying with the numerous and complex regulatory requirements associated with RCRA hazardous waste and radioactive mixed waste containers and container management areas. This document is designed using a systematic graphic approach that features detailed, step-by-step guidance and extensive references to additional relevant guidance materials. Diagrams, flowcharts, reference, and overview graphics accompany the narrative descriptions to illustrate and highlight the topics being discussed. Step-by-step narrative is accompanied by flowchart graphics in an easy-to-follow, ``roadmap`` format.

  8. Mixed-waste treatment -- What about the residuals? A comparative analysis of MSO and incineration

    SciTech Connect (OSTI)

    1993-06-01

    This report examines the issues concerning final waste forms, or residuals, that result from the treatment of mixed waste in molten salt oxidation (MSO) and incinerator systems. MSO is a technology with the potential to treat a certain segment of the waste streams at US Department of Energy (DOE) sites. MSO was compared with incineration because incineration is the best demonstrated available technology (BDAT) for the same waste streams. The Grand Junction Projects Office (GJPO) and Oak Ridge National Laboratory (ORNL) prepared this report for the DOE Office of Environmental Restoration (OER). The goals of this study are to objectively evaluate the anticipated residuals from MSO and incineration, examine regulatory issues for these final waste forms, and determine secondary treatment options. This report, developed to address concerns that MSO residuals present unique disposal difficulties, is part of a larger effort to successfully implement MSO as a treatment technology for mixed and hazardous waste. A Peer Review Panel reviewed the MSO technology in November 1991, and the implementation effort is ongoing under the guidance of the MSO Task Force.

  9. Conceptual Design Report: Nevada Test Site Mixed Waste Disposal Facility Project

    SciTech Connect (OSTI)

    NSTec Environmental Management

    2009-01-31

    Environmental cleanup of contaminated nuclear weapons manufacturing and test sites generates radioactive waste that must be disposed. Site cleanup activities throughout the U.S. Department of Energy (DOE) complex are projected to continue through 2050. Some of this waste is mixed waste (MW), containing both hazardous and radioactive components. In addition, there is a need for MW disposal from other mission activities. The Waste Management Programmatic Environmental Impact Statement Record of Decision designates the Nevada Test Site (NTS) as a regional MW disposal site. The NTS has a facility that is permitted to dispose of onsite- and offsite-generated MW until November 30, 2010. There is not a DOE waste management facility that is currently permitted to dispose of offsite-generated MW after 2010, jeopardizing the DOE environmental cleanup mission and other MW-generating mission-related activities. A mission needs document (CD-0) has been prepared for a newly permitted MW disposal facility at the NTS that would provide the needed capability to support DOE's environmental cleanup mission and other MW-generating mission-related activities. This report presents a conceptual engineering design for a MW facility that is fully compliant with Resource Conservation and Recovery Act (RCRA) and DOE O 435.1, 'Radioactive Waste Management'. The facility, which will be located within the Area 5 Radioactive Waste Management Site (RWMS) at the NTS, will provide an approximately 20,000-cubic yard waste disposal capacity. The facility will be licensed by the Nevada Division of Environmental Protection (NDEP).

  10. Technical considerations and problems associated with long-term storage of low-level waste

    SciTech Connect (OSTI)

    Siskind, B.

    1991-12-31

    If a state or regional compact does not have adequate disposal capacity for low-level radioactive waste (LLRW), then extended storage of certain LLRW may be necessary. The Nuclear Regulatory Commission (NRC) contracted with Brookhaven National Laboratory (BNL) several years ago (1984--86) to address the technical issues of extended storage. The dual objectives of this study were (1) to provide practical technical assessments for NRC to consider in evaluating specific proposals for extended storage and (2) to help ensure adequate consideration by NRC, Agreement States, and licensees of potential problems that may arise from existing or proposed extended storage practices. In this summary of that study, the circumstances under which extended storage of LLRW would most likely result in problems during or after the extended storage period are considered and possible mitigative measures to minimize these problems are discussed. These potential problem areas include: (1) the degradation of carbon steel and polyethylene containers during storage and the subsequent need for repackaging (resulting in increased occupational exposure), (2) the generation of hazardous gases during storage, and (3) biodegradative processes in LLRW.

  11. Technical considerations and problems associated with long-term storage of low-level waste

    SciTech Connect (OSTI)

    Siskind, B.

    1991-01-01

    If a state or regional compact does not have adequate disposal capacity for low-level radioactive waste (LLRW), then extended storage of certain LLRW may be necessary. The Nuclear Regulatory Commission (NRC) contracted with Brookhaven National Laboratory (BNL) several years ago (1984--86) to address the technical issues of extended storage. The dual objectives of this study were (1) to provide practical technical assessments for NRC to consider in evaluating specific proposals for extended storage and (2) to help ensure adequate consideration by NRC, Agreement States, and licensees of potential problems that may arise from existing or proposed extended storage practices. In this summary of that study, the circumstances under which extended storage of LLRW would most likely result in problems during or after the extended storage period are considered and possible mitigative measures to minimize these problems are discussed. These potential problem areas include: (1) the degradation of carbon steel and polyethylene containers during storage and the subsequent need for repackaging (resulting in increased occupational exposure), (2) the generation of hazardous gases during storage, and (3) biodegradative processes in LLRW.

  12. Analysis of embedded waste storage tanks subjected to seismic loading

    SciTech Connect (OSTI)

    Zaslawsky, M.; Sammaddar, S.; Kennedy, W.N.

    1991-01-01

    At the Savannah River Site, High Activity Wastes are stored in carbon steel tanks that are within reinforced concrete vaults. These soil-embedded tank/vault structures are approximately 80 ft. in diameter and 40 ft. deep. The tanks were studied to determine the essentials of governing variables, to reduce the problem to the least number of governing cases to optimize analysis effort without introducing excessive conservatism. The problem reduced to a limited number of cases of soil-structure interaction and fluid (tank contents) -- structure interaction problems. It was theorized that substantially reduced input would be realized from soil structure interaction (SSI) but that it was also possible that tank-to-tank proximity would result in (re)amplification of the input. To determine the governing seismic input motion, the three dimensional SSI code, SASSI, was used. Significant among the issues relative to waste tanks is to the determination of fluid response and tank behavior as a function of tank contents viscosity. Tank seismic analyses and studies have been based on low viscosity fluids (water) and the behavior is quite well understood. Typical wastes (salts, sludge), which are highly viscous, have not been the subject of studies to understand the effect of viscosity on seismic response. The computer code DYNA3D was used to study how viscosity alters tank wall pressure distribution and tank base shear and overturning moments. A parallel hand calculation was performed using standard procedures. Conclusions based on the study provide insight into the quantification of the reduction of seismic inputs for soil structure interaction for a soft'' soil site.

  13. Analysis of embedded waste storage tanks subjected to seismic loading

    SciTech Connect (OSTI)

    Zaslawsky, M.; Sammaddar, S.; Kennedy, W.N.

    1991-12-31

    At the Savannah River Site, High Activity Wastes are stored in carbon steel tanks that are within reinforced concrete vaults. These soil-embedded tank/vault structures are approximately 80 ft. in diameter and 40 ft. deep. The tanks were studied to determine the essentials of governing variables, to reduce the problem to the least number of governing cases to optimize analysis effort without introducing excessive conservatism. The problem reduced to a limited number of cases of soil-structure interaction and fluid (tank contents) -- structure interaction problems. It was theorized that substantially reduced input would be realized from soil structure interaction (SSI) but that it was also possible that tank-to-tank proximity would result in (re)amplification of the input. To determine the governing seismic input motion, the three dimensional SSI code, SASSI, was used. Significant among the issues relative to waste tanks is to the determination of fluid response and tank behavior as a function of tank contents viscosity. Tank seismic analyses and studies have been based on low viscosity fluids (water) and the behavior is quite well understood. Typical wastes (salts, sludge), which are highly viscous, have not been the subject of studies to understand the effect of viscosity on seismic response. The computer code DYNA3D was used to study how viscosity alters tank wall pressure distribution and tank base shear and overturning moments. A parallel hand calculation was performed using standard procedures. Conclusions based on the study provide insight into the quantification of the reduction of seismic inputs for soil structure interaction for a ``soft`` soil site.

  14. Calcined Waste Storage at the Idaho Nuclear Technology and Engineering Center

    SciTech Connect (OSTI)

    Staiger, M. Daniel, Swenson, Michael C.

    2011-09-01

    This comprehensive report provides definitive volume, mass, and composition (chemical and radioactivity) of calcined waste stored at the Idaho Nuclear Technology and Engineering Center. Calcine composition data are required for regulatory compliance (such as permitting and waste disposal), future treatment of the caline, and shipping the calcine to an off-Site-facility (such as a geologic repository). This report also contains a description of the calcine storage bins. The Calcined Solids Storage Facilities (CSSFs) were designed by different architectural engineering firms and built at different times. Each CSSF has a unique design, reflecting varying design criteria and lessons learned from historical CSSF operation. The varying CSSF design will affect future calcine retrieval processes and equipment. Revision 4 of this report presents refinements and enhancements of calculations concerning the composition, volume, mass, chemical content, and radioactivity of calcined waste produced and stored within the CSSFs. The historical calcine samples are insufficient in number and scope of analysis to fully characterize the entire inventory of calcine in the CSSFs. Sample data exist for all the liquid wastes that were calcined. This report provides calcine composition data based on liquid waste sample analyses, volume of liquid waste calcined, calciner operating data, and CSSF operating data using several large Microsoft Excel (Microsoft 2003) databases and spreadsheets that are collectively called the Historical Processing Model. The calcine composition determined by this method compares favorably with historical calcine sample data.

  15. Expedited demonstration of molten salt mixed waste treatment technology. Final report

    SciTech Connect (OSTI)

    1995-02-02

    This final report discusses the molten salt mixed waste project in terms of the various subtasks established. Subtask 1: Carbon monoxide emissions; Establish a salt recycle schedule and/or a strategy for off-gas control for MWMF that keeps carbon monoxide emission below 100 ppm on an hourly averaged basis. Subtask 2: Salt melt viscosity; Experiments are conducted to determine salt viscosity as a function of ash composition, ash concentration, temperature, and time. Subtask 3: Determine that the amount of sodium carbonate entrained in the off-gas is minimal, and that any deposited salt can easily be removed form the piping using a soot blower or other means. Subtask 4: The provision of at least one final waste form that meets the waste acceptance criteria of a landfill that will take the waste. This report discusses the progress made in each of these areas.

  16. Mixed waste focus area Department of Energy technology development needs identification and prioritization

    SciTech Connect (OSTI)

    Roach, J.A.

    1995-11-01

    The Assistant Secretary for the Office of Environmental Management (EM) at the US DOE initiated a new approach in August, 1993 to environmental research and technology development. The key features of this new approach included establishment of five focus areas and three crosscutting technology programs, which overlap the boundaries of the focus areas. The five focus areas include the Contaminant Plumes Containment and Remediation; Mixed Waste Characterization, Treatment, and Disposal; High-Level Waste Tank Remediation, Landfill Stabilization, and Decontamination and Decommissioning Focus Areas. The three crosscutting technologies programs include Characterization, Monitoring, and Sensor Technology; Efficient Separations and Processing; and Robotics. The DOE created the Mixed Waste Characterization, Treatment, and Disposal Focus Area (MWFA) to develop and facilitate implementation of technologies required to meet its commitments for treatment of mixed wastes. To accomplish this goal, the technology deficiencies must be identified and categorized, the deficiencies and needs must be prioritized, and a technical baseline must be established that integrates the requirements associated with these needs into the planned and ongoing environmental research and technology development activities supported by the MWFA. These steps are described.

  17. Surrogate formulations for thermal treatment of low-level mixed waste. Part 1: Radiological surrogates

    SciTech Connect (OSTI)

    Stockdale, J.A.D.; Bostick, W.D.; Hoffmann, D.P.; Lee, H.T.

    1994-01-01

    The evaluation and comparison of proposed thermal treatment systems for mixed wastes can be expedited by tests in which the radioactive components of the wastes are replaced by surrogate materials chosen to mimic, as far as is possible, the chemical and physical properties of the radioactive materials of concern. In this work, sponsored by the Mixed Waste Integrated Project of the US Department of Energy, the authors have examined reported experience with such surrogates and suggest a simplified standard list of materials for use in tests of thermal treatment systems. The chief radioactive nuclides of concern in the treatment of mixed wastes are {sup 239}Pu, {sup 238}U, {sup 235}U, {sup 137}Cs, {sup 103}Ru, {sup 99}Tc, and {sup 90}Sr. These nuclides are largely by-products of uranium enrichment, reactor fuel reprocessing, and weapons program activities. Cs, Ru, and Sr all have stable isotopes that can be used as perfect surrogates for the radioactive forms. Technetium exists only in radioactive form, as do plutonium and uranium. If one wishes to preclude radioactive contamination of the thermal treatment system under trial burn, surrogate elements must be chosen for these three. For technetium, the authors suggest the use of natural ruthenium, and for both plutonium and uranium, they recommend cerium. The seven radionuclides listed can therefore be simulated by a surrogate package containing stable isotopes of ruthenium, strontium, cesium, and cerium.

  18. A literature review of mixed waste components: Sensitivities and effects upon solidification/stabilization in cement-based matrices

    SciTech Connect (OSTI)

    Mattus, C.H.; Gilliam, T.M.

    1994-03-01

    The US DOE Oak Ridge Field Office has signed a Federal Facility Compliance Agreement (FFCA) regarding Oak Ridge Reservation (ORR) mixed wastes subject to the land disposal restriction (LDR) provisions of the Resource conservation and Recovery Act. The LDR FFCA establishes an aggressive schedule for conducting treatability studies and developing treatment methods for those ORR mixed (radioactive and hazardous) wastes listed in Appendix B to the Agreement. A development, demonstration, testing, and evaluation program has been initiated to provide those efforts necessary to identify treatment methods for all of the wastes that meet Appendix B criteria. The program has assembled project teams to address treatment development needs in a variety of areas, including that of final waste forms (i.e., stabilization/solidification processes). A literature research has been performed, with the objective of determining waste characterization needs to support cement-based waste-form development. The goal was to determine which waste species are problematic in terms of consistent production of an acceptable cement-based waste form and at what concentrations these species become intolerable. The report discusses the following: hydration mechanisms of Portland cement; mechanisms of retardation and acceleration of cement set-factors affecting the durability of waste forms; regulatory limits as they apply to mixed wastes; review of inorganic species that interfere with the development of cement-based waste forms; review of radioactive species that can be immobilized in cement-based waste forms; and review of organic species that may interfere with various waste-form properties.

  19. The Challenges of Creating a Real-Time Data Management System for TRU-Mixed Waste at the Advanced Mixed Waste Treatment Plant

    SciTech Connect (OSTI)

    Paff, S. W; Doody, S.

    2003-02-25

    This paper discusses the challenges associated with creating a data management system for waste tracking at the Advanced Mixed Waste Treatment Plant (AMWTP) at the Idaho National Engineering Lab (INEEL). The waste tracking system combines data from plant automation systems and decision points. The primary purpose of the system is to provide information to enable the plant operators and engineers to assess the risks associated with each container and determine the best method of treating it. It is also used to track the transuranic (TRU) waste containers as they move throughout the various processes at the plant. And finally, the goal of the system is to support paperless shipments of the waste to the Waste Isolation Pilot Plant (WIPP). This paper describes the approach, methodologies, the underlying design of the database, and the challenges of creating the Data Management System (DMS) prior to completion of design and construction of a major plant. The system was built utilizing an Oracle database platform, and Oracle Forms 6i in client-server mode. The underlying data architecture is container-centric, with separate tables and objects for each type of analysis used to characterize the waste, including real-time radiography (RTR), non-destructive assay (NDA), head-space gas sampling and analysis (HSGS), visual examination (VE) and coring. The use of separate tables facilitated the construction of automatic interfaces with the analysis instruments that enabled direct data capture. Movements are tracked using a location system describing each waste container's current location and a history table tracking the container's movement history. The movement system is designed to interface both with radio-frequency bar-code devices and the plant's integrated control system (ICS). Collections of containers or information, such as batches, were created across the various types of analyses, which enabled a single, cohesive approach to be developed for verification and

  20. A Short History of Hanford Waste Generation, Storage, and Release

    SciTech Connect (OSTI)

    Gephart, Roy E.

    2003-10-01

    Nine nuclear reactors and four reprocessing plants at Hanford produced nearly two-thirds of the plutonium used in the United States for government purposes . These site operations also created large volumes of radioactive and chemical waste. Some contaminants were released into the environment, exposing people who lived downwind and downstream. Other contaminants were stored. The last reactor was shut down in 1987, and the last reprocessing plant closed in 1990. Most of the human-made radioactivity and about half of the chemicals remaining onsite are kept in underground tanks and surface facilities. The rest exists in the soil, groundwater, and burial grounds. Hanford contains about 40% of all the radioactivity that exists across the nuclear weapons complex. Today, environmental restoration activities are under way.

  1. US Department of Energy interim mixed waste inventory report: Waste streams, treatment capacities and technologies: Volume 4, Site specific---Ohio through South Carolina

    SciTech Connect (OSTI)

    Not Available

    1993-04-01

    The Department of Energy (DOE) has prepared this report to provide an inventory of its mixed wastes and treatment capacities and technologies in response to Section 105(a) of the Federal Facility Compliance Act (FFCAct) of 1992 (Pub. L. No. 102-386). As required by the FFCAct-1992, this report provides site-specific information on DOE`s mixed waste streams and a general review of available and planned treatment facilities for mixed wastes at the following five Ohio facilities: Battelle Columbus Laboratories; Fernald Environmental Management Project; Mound Plant; Portsmouth Gaseous Diffusion Plant; and RMI, Titanium Company.

  2. CHARACTERIZATION THROUGH DATA QUALITY OBJECTIVES AND CERTIFICATION OF REMOTE-HANDLED TRANSURANIC WASTE GENERATOR/STORAGE SITES FOR SHIPMENT TO THE WIPP

    SciTech Connect (OSTI)

    Spangler, L.R.; Most, Wm.A.; Kehrman, R.F.; Gist, C.S.

    2003-02-27

    The Waste Isolation Pilot Plant (WIPP) is operating to receive and dispose of contact-handled (CH) transuranic (TRU) waste. The Department of Energy (DOE) Carlsbad Field Office (CBFO) is seeking approval from the Environmental Protection Agency (EPA) and the New Mexico Environment Department (NMED) of the remote-handled (RH) TRU characterization plan to allow disposal of RH TRU waste in the WIPP repository. In addition, the DOE-CBFO has received approval from the Nuclear Regulatory Commission (NRC) to use two shipping casks for transporting RH TRU waste. Each regulatory agency (i.e., EPA, NMED, and NRC) has different requirements that will have to be met through the use of information collected by characterizing the RH TRU waste. Therefore, the DOE-CBFO has developed a proposed characterization program for obtaining the RH TRU waste information necessary to demonstrate that the waste meets the applicable regulatory requirements. This process involved the development of a comprehensive set of Data Quality Objectives (DQOs) comprising the various regulatory requirements. The DOE-CBFO has identified seven DQOs for use in the RH TRU waste characterization program. These DQOs are defense waste determination, TRU waste determination, RH TRU determination, activity determination, RCRA physical and chemical properties, prohibited item determination, and EPA physical and chemical properties. The selection of the DQOs were based on technical, legal and regulatory drivers that assure the health and safety of the workers, the public, to protect the environment, and to comply with the requirements of the regulatory agencies. The DOE-CBFO also has the responsibility for the certification of generator/storage sites to ship RH TRU mixed waste to the WIPP for disposal. Currently, thirteen sites across the DOE complex are generators of RH TRU waste or store the waste at their location for other generators. Generator/storage site certification involves review and approval of site

  3. Criticality Safety Envelope for Receipt, Handling, and Storage of Transuranic Waste

    SciTech Connect (OSTI)

    Vincent, A.M.

    1998-12-04

    Current criticality safety limits for Solid Waste Management Facility (SWMF) Transuranic (TRU) Waste Storage Pads are based on analysis of systems where mass is the only independent parameter and all other parameters are assumed at their most reactive values (Ref. 1). These limits result in administrative controls (i.e., limit stacking of containers, coordination of drums for culvert storage based on individual drum fissile inventories, and mass limits for accumulation of polyethylene boxes in culverts) which can only be met by redundant SWMF administrative controls. These analyses did not credit the nature of the waste generator process that would provide bounding limits on the other parameters (i.e. less than optimal moderation and configurations within packages (containers)). They also did not indicate the margin of safety associated with operating to these mass limits. However, by crediting the waste generator processes (and maintaining such process assumptions via controls in the criteria for waste acceptance) sufficient margin of safety can be demonstrated to justify continued SWMF TRU pad operation with fewer administrative controls than specified in the Double Contingency analysis (DCA) (Ref. 1).

  4. Safe interim storage of Hanford tank wastes, draft environmental impact statement, Hanford Site, Richland, Washington

    SciTech Connect (OSTI)

    Not Available

    1994-07-01

    This Draft EIS is prepared pursuant to the National Environmental Policy Act (NEPA) and the Washington State Environmental Policy Act (SEPA). DOE and Ecology have identified the need to resolve near-term tank safety issues associated with Watchlist tanks as identified pursuant to Public Law (P.L.) 101-510, Section 3137, ``Safety Measures for Waste Tanks at Hanford Nuclear Reservation,`` of the National Defense Authorization Act for Fiscal Year 1991, while continuing to provide safe storage for other Hanford wastes. This would be an interim action pending other actions that could be taken to convert waste to a more stable form based on decisions resulting from the Tank Waste Remediation System (TWRS) EIS. The purpose for this action is to resolve safety issues concerning the generation of unacceptable levels of hydrogen in two Watchlist tanks, 101-SY and 103-SY. Retrieving waste in dilute form from Tanks 101-SY and 103-SY, hydrogen-generating Watchlist double shell tanks (DSTs) in the 200 West Area, and storage in new tanks is the preferred alternative for resolution of the hydrogen safety issues.

  5. Mixed and low-level waste treatment project: Appendix C, Health and safety criteria for the mixed and low-level waste treatment facility at the Idaho National Engineering Laboratory. Part 1, Waste streams and treatment technologies

    SciTech Connect (OSTI)

    Neupauer, R.M.; Thurmond, S.M.

    1992-09-01

    This report describes health and safety concerns associated with the Mixed and Low-level Waste Treatment Facility at the Idaho National Engineering Laboratory. Various hazards are described such as fire, electrical, explosions, reactivity, temperature, and radiation hazards, as well as the potential for accidental spills, exposure to toxic materials, and other general safety concerns.

  6. Steam reforming as a method to treat Hanford underground storage tank (UST) wastes

    SciTech Connect (OSTI)

    Miller, J.E.; Kuehne, P.B.

    1995-07-01

    This report summarizes a Sandia program that included partnerships with Lawrence Livermore National Laboratory and Synthetica Technologies, Inc. to design and test a steam reforming system for treating Hanford underground storage tank (UST) wastes. The benefits of steam reforming the wastes include the resolution of tank safety issues and improved radionuclide separations. Steam reforming destroys organic materials by first gasifying, then reacting them with high temperature steam. Tests indicate that up to 99% of the organics could be removed from the UST wastes by steam exposure. In addition, it was shown that nitrates in the wastes could be destroyed by steam exposure if they were first distributed as a thin layer on a surface. High purity alumina and nickel alloys were shown to be good candidates for materials to be used in the severe environment associated with steam reforming the highly alkaline, high nitrate content wastes. Work was performed on designing, building, and demonstrating components of a 0.5 gallon per minute (gpm) system suitable for radioactive waste treatment. Scale-up of the unit to 20 gpm was also considered and is feasible. Finally, process demonstrations conducted on non-radioactive waste surrogates were carried out, including a successful demonstration of the technology at the 0.1 gpm scale.

  7. Closure plan for Solid Waste Storage Area 6: Volume 1, Closure plan

    SciTech Connect (OSTI)

    Not Available

    1988-09-01

    This Closure Plan for Solid Waste Storage Area 6 (SWSA 6) a disposal area for low-level radioactive wastes and hazardous materials, of the US Department of Energy (DOE) Oak Ridge National Laboratory (ORNL) describes how portions of SWSA 6 will be closed under Resource Conservation and Recovery Act (RCRA) Interim Status per 40 CFR 265 Subpart G (TN Rule 1200-1-11-.05(7)). An overview is provided of activities necessary for final closure and corrective measures for all of SWSA 6. Results of surface waters and groundwater sampling are provided.

  8. ESTIMATING HIGH LEVEL WASTE MIXING PERFORMANCE IN HANFORD DOUBLE SHELL TANKS

    SciTech Connect (OSTI)

    THIEN MG; GREER DA; TOWNSON P

    2011-01-13

    The ability to effectively mix, sample, certify, and deliver consistent batches of high level waste (HLW) feed from the Hanford double shell tanks (DSTs) to the Waste Treatment and Immobilization Plant (WTP) presents a significant mission risk with potential to impact mission length and the quantity of HLW glass produced. The Department of Energy's (DOE's) Tank Operations Contractor (TOC), Washington River Protection Solutions (WRPS) is currently demonstrating mixing, sampling, and batch transfer performance in two different sizes of small-scale DSTs. The results of these demonstrations will be used to estimate full-scale DST mixing performance and provide the key input to a programmatic decision on the need to build a dedicated feed certification facility. This paper discusses the results from initial mixing demonstration activities and presents data evaluation techniques that allow insight into the performance relationships of the two small tanks. The next steps, sampling and batch transfers, of the small scale demonstration activities are introduced. A discussion of the integration of results from the mixing, sampling, and batch transfer tests to allow estimating full-scale DST performance is presented.

  9. Technical area status report for low-level mixed waste final waste forms. Volume 1

    SciTech Connect (OSTI)

    Mayberry, J.L.; DeWitt, L.M.; Darnell, R.

    1993-08-01

    The Final Waste Forms (FWF) Technical Area Status Report (TASR) Working Group, the Vitrification Working Group (WG), and the Performance Standards Working Group were established as subgroups to the FWF Technical Support Group (TSG). The FWF TASR WG is comprised of technical representatives from most of the major DOE sites, the Nuclear Regulatory Commission (NRC), the EPA Office of Solid Waste, and the EPA`s Risk Reduction Engineering Laboratory (RREL). The primary activity of the FWF TASR Working Group was to investigate and report on the current status of FWFs for LLNM in this TASR. The FWF TASR Working Group determined the current status of the development of various waste forms described above by reviewing selected articles and technical reports, summarizing data, and establishing an initial set of FWF characteristics to be used in evaluating candidate FWFS; these characteristics are summarized in Section 2. After an initial review of available information, the FWF TASR Working Group chose to study the following groups of final waste forms: hydraulic cement, sulfur polymer cement, glass, ceramic, and organic binders. The organic binders included polyethylene, bitumen, vinyl ester styrene, epoxy, and urea formaldehyde. Section 3 provides a description of each final waste form. Based on the literature review, the gaps and deficiencies in information were summarized, and conclusions and recommendations were established. The information and data presented in this TASR are intended to assist the FWF Production and Assessment TSG in evaluating the Technical Task Plans (TTPs) submitted to DOE EM-50, and thus provide DOE with the necessary information for their FWF decision-making process. This FWF TASR will also assist the DOE and the MWIP in establishing the most acceptable final waste forms for the various LLMW streams stored at DOE facilities.

  10. Design of a mixing system for simulated high-level nuclear waste melter feed slurries

    SciTech Connect (OSTI)

    Peterson, M.E.; McCarthy, D.; Muhlstein, K.D.

    1986-03-01

    The Nuclear Waste Treatment Program development program consists of coordinated nonradioactive and radioactive testing combined with numerical modeling of the process to provide a complete basis for design and operation of a vitrification facility. The radioactive demonstration tests of equipment and processes are conducted before incorporation in radioactive pilot-scale melter systems for final demonstration. The mixing system evaluation described in this report was conducted as part of the nonradioactive testing. The format of this report follows the sequence in which the design of a large-scale mixing system is determined. The initial program activity was concerned with gaining an understanding of the theoretical foundation of non-Newtonian mixing systems. Section 3 of this report describes the classical rheological models that are used to describe non-Newtonian mixing systems. Since the results obtained here are only valid for the slurries utilized, Section 4, Preparation of Simulated Hanford and West Valley Slurries, describes how the slurries were prepared. The laboratory-scale viscometric and physical property information is summarized in Section 5, Laboratory Rheological Evaluations. The bench-scale mixing evaluations conducted to define the effects of the independent variables described above on the degree of mixing achieved with each slurry are described in Section 6. Bench-scale results are scaled-up to establish engineering design requirements for the full-scale mixing system in Section 7. 24 refs., 37 figs., 44 tabs.

  11. Plan for glass waste form testing for NNWSI [Nevada Nuclear Waste Storage Investigations

    SciTech Connect (OSTI)

    Aines, R.D.

    1987-09-01

    The purpose of glass waste form testing is to determine the rate of release of radionuclides from breached glass waste containers. This information will be used to qualify glass waste forms with respect to the release requirements. It will be the basis of the source term from glass waste for repository performance assessment modeling. This information will also serve as part of the source term in the calculation of cumulative releases after 100,000 years in the site evaluation process. It will also serve as part of the source term input for calculation of cumulative releases to the accessible environment for 10,000 years after disposal, to determine compliance with EPA regulations. This investigation will provide data to resolve information needs. Information about the waste forms which is provided by the producer will be accumulated and evaluated; the waste form will be tested, properties determined, and mechanisms of degradation determined; and models providing long-term evaluation of release rates designed and tested. 23 refs.

  12. Safety evaluation for packaging (onsite) concrete-lined waste packaging

    SciTech Connect (OSTI)

    Romano, T.

    1997-09-25

    The Pacific Northwest National Laboratory developed a package to ship Type A, non-transuranic, fissile excepted quantities of liquid or solid radioactive material and radioactive mixed waste to the Central Waste Complex for storage on the Hanford Site.

  13. Waste encapsulation storage facility (WESF) standards/requirements identification document (S/RIDS)

    SciTech Connect (OSTI)

    Maddox, B.S., Westinghouse Hanford

    1996-07-29

    This Standards/Requirements Identification Document (S/RID) sets forth the Environmental Safety and Health (ES{ampersand}H) standards/requirements for the Waste Encapsulation Storage Facility (WESF). This S/RID is applicable to the appropriate life cycle phases of design, construction, operation, and preparation for decommissioning. These standards/requirements are adequate to ensure the protection of the health and safety of workers, the public, and the environment.

  14. Waste Encapsulation and Storage Facility (WESF) Quality Assurance Program Plan (QAPP)

    SciTech Connect (OSTI)

    ROBINSON, P.A.

    2000-04-17

    This Quality Assurance Plan describes how the Waste Encapsulation and Storage Facility (WESF) implements the quality assurance (QA) requirements of the Quality Assurance Program Description (QAPD) (HNF-Mp-599) for Project Hanford activities and products. This QAPP also describes the organizational structure necessary to successfully implement the program. The QAPP provides a road map of applicable Project Hanford Management System Procedures, and facility specific procedures, that may be utilized by WESF to implement the requirements of the QAPD.

  15. Integrated demonstration of molten salt oxidation with salt recycle for mixed waste treatment

    SciTech Connect (OSTI)

    Hsu, P.C.

    1997-11-01

    Molten Salt Oxidation (MSO) is a thermal, nonflame process that has the inherent capability of completely destroying organic constituents of mixed wastes, hazardous wastes, and energetic materials while retaining inorganic and radioactive constituents in the salt. For this reason, MSO is considered a promising alternative to incineration for the treatment of a variety of organic wastes. Lawrence Livermore National Laboratory (LLNL) has prepared a facility and constructed an integrated pilot-scale MSO treatment system in which tests and demonstrations are performed under carefully controlled (experimental) conditions. The system consists of a MSO processor with dedicated off-gas treatment, a salt recycle system, feed preparation equipment, and equipment for preparing ceramic final waste forms. This integrated system was designed and engineered based on laboratory experience with a smaller engineering-scale reactor unit and extensive laboratory development on salt recycle and final forms preparation. In this paper we present design and engineering details of the system and discuss its capabilities as well as preliminary process demonstration data. A primary purpose of these demonstrations is identification of the most suitable waste streams and waste types for MSO treatment.

  16. Final closure cover for a Hanford radioactive mixed waste disposal facility

    SciTech Connect (OSTI)

    Johnson, K.D.

    1996-02-06

    This study provides a preliminary design for a RCRA mixed waste landfill final closure cover. The cover design was developed by a senior class design team from Seattle University. The design incorporates a layered design of indigenous soils and geosynthetics in a layered system to meet final closure cover requirements for a landfill as imposed by the Washington Administrative Code WAC-173-303 implementation of the Resource Conservation and Recovery Act.

  17. EIS-0063: Waste Management Operations, Double-Shell Tanks for Defense High-Level Radioactive Waste Storage, Hanford Site, Richland, Washington

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy developed this statement to evaluate the existing tank design and consider additional specific design and safety feature alternatives for the thirteen tanks being constructed for storage of defense high-level radioactive liquid waste at the Hanford Site in Richland, Washington. This statement supplements ERDA-1538, "Final Environmental Statement on Waste Management Operation."

  18. Choosing solidification or vitrification for low-level radioactive and mixed waste treatment

    SciTech Connect (OSTI)

    Gimpel, R.F.

    1992-02-14

    Solidification (making concrete) and vitrification (making glass) are frequently the treatment methods recommended for treating inorganic or radioactive wastes. Solidification is generally perceived as the most economical treatment method. Whereas, vitrification is considered (by many) as the most effective of all treatment methods. Unfortunately, vitrification has acquired the stigma that it is too expensive to receive further consideration as an alternative to solidification in high volume treatment applications. Ironically, economic studies, as presented in this paper, show that vitrification may be more competitive in some high volume applications. Ex-situ solidification and vitrification are the competing methods for treating in excess of 450 000m{sup 3} of low-level radioactive and mixed waste at the Fernald Environmental Management Project (FEMP or simply, Fernald) located near Cincinnati, Ohio. This paper summarizes how Fernald is choosing between solidification and vitrification as the primary waste treatment method.

  19. Treatability studies with low-temperature thermal desorption on low-level mixed-waste solids

    SciTech Connect (OSTI)

    Bloom, R.; Stelmach, J.

    1995-12-31

    Under a program sponsored by the U.S. Department of Energy Albuquerque 0perations Office (DOE-AL), the DOE Grand Junction Projects Office, (GJPO) conducted treatability studies with a low-temperature, vacuum-assisted thermal desorption unit on low-level mixed-waste solids generated at Los Alamos National Laboratory, Kansas City Plant, Sandia National Laboratories/New Mexico and GJPO. The process extracts the volatile compounds from the matrix and condenses them into a treatable nonmixed waste liquid stream yielding a treated matrix that may be managed as a radioactive waste. The feed streams consisted of soils, sludge, and organic debris with various amount of moisture and organic compounds. The treatability test results indicate that Land Disposal Restriction standards for Resource Conservation and Recovery Act-listed compounds were met. These results are being used to design 3 mobile treatment unit for use at DOE-AL sites.

  20. Guidelines for generators to meet HWHF acceptance requirements for hazardous, radioactive, and mixed wastes at Berkeley Lab. Revision 3

    SciTech Connect (OSTI)

    Albert, R.

    1996-06-01

    This document provides performance standards that one, as a generator of hazardous chemical, radioactive, or mixed wastes at the Berkeley Lab, must meet to manage their waste to protect Berkeley Lab staff and the environment, comply with waste regulations and ensure the continued safe operation of the workplace, have the waste transferred to the correct Waste Handling Facility, and enable the Environment, Health and Safety (EH and S) Division to properly pick up, manage, and ultimately send the waste off site for recycling, treatment, or disposal. If one uses and generates any of these wastes, one must establish a Satellite Accumulation Area and follow the guidelines in the appropriate section of this document. Topics include minimization of wastes, characterization of the wastes, containers, segregation, labeling, empty containers, and spill cleanup and reporting.

  1. Analysis of long-term impacts of TRU waste remaining at generator/storage sites for No Action Alternative 2

    SciTech Connect (OSTI)

    Buck, J.W.; Bagaasen, L.M.; Bergeron, M.P.; Streile, G.P.

    1997-09-01

    This report is a supplement to the Waste Isolation Pilot Plant Disposal-Phase Final Supplemental Environmental Impact Statement (SEIS-II). Described herein are the underlying information, data, and assumptions used to estimate the long-term human-health impacts from exposure to radionuclides and hazardous chemicals in transuranic (TRU) waste remaining at major generator/storage sites after loss of institutional control under No Action Alternative 2. Under No Action Alternative 2, TRU wastes would not be emplaced at the Waste Isolation Pilot Plant (WIPP) but would remain at generator/storage sites in surface or near-surface storage. Waste generated at smaller sites would be consolidated at the major generator/storage sites. Current TRU waste management practices would continue, but newly generated waste would be treated to meet the WIPP waste acceptance criteria. For this alternative, institutional control was assumed to be lost 100 years after the end of the waste generation period, with exposure to radionuclides and hazardous chemicals in the TRU waste possible from direct intrusion and release to the surrounding environment. The potential human-health impacts from exposure to radionuclides and hazardous chemicals in TRU waste were analyzed for two different types of scenarios. Both analyses estimated site-specific, human-health impacts at seven major generator/storage sites: the Hanford Site (Hanford), Idaho National Engineering and Environmental Laboratory (INEEL), Lawrence Livermore National Laboratory (LLNL), Los Alamos National Laboratory (LANL), Oak Ridge National Laboratory (ORNL), Rocky Flats Environmental Technology Site (RFETS), and Savannah River Site (SRS). The analysis focused on these seven sites because 99 % of the estimated TRU waste volume and inventory would remain there under the assumptions of No Action Alternative 2.

  2. Identification of mixing effects in stratified chilled-water storage tanks by analysis of time series temperature data

    SciTech Connect (OSTI)

    Caldwell, J.S.; Bahnfleth, W.P.

    1998-12-31

    Several one-dimensional models of mixing in stratified chilled-water thermal energy storage tanks have been proposed. In the simplest models, mixing is assumed to be uniform throughout the tank. Other models permit spatial variation of mixing intensity. Published models were developed by adjusting model parameters to achieve qualitative agreement with measured profiles. The literature does not describe quantitative criteria for evaluating the performance of mixing models. This paper describes a method that can be used to determine the relative spatial distribution of mixing effects directly from experimental data. It also illustrates a method for quantitative comparison of experimental and modeled temperature profiles. The mixing calculation procedure may be applied to instantaneous spatial temperature data if temperature sensor spacing is sufficiently small. When sensors are widely spaced, time series data taken at individual sensors provide better accuracy. A criterion for maximum sensor spacing is proposed. The application of these procedures to time series charge-cycle operating data from a full-scale chilled-water thermal storage system serving a large medical center is described. Results of this analysis indicate that mixing is localized near the inlet diffuser and that one-dimensional flow with streamwise conduction predominates in most of the tank.

  3. Groundwater quality assessment report for Solid Waste Storage Area 6 at Oak Ridge National Laboratory, Oak Ridge, Tennessee -- 1997

    SciTech Connect (OSTI)

    1998-02-01

    Solid Waste Storage Area (SWSA) 6, located at the US Department of Energy (DOE) Oak Ridge National Laboratory (ORNL) facility, is a shallow land burial site for low-level radioactive waste (LLW) and other waste types. Wastes were disposed of in unlined trenches and auger holes from 1969 until May 1986, when it was determined that Resource Conservation and Recovery Act (RCRA) regulated wastes were being disposed of there. DOE closed SWSA 6 until changes in operating procedures prevented the disposal of RCRA wastes at SWSA 6. The site, which reopened for waste disposal activities in July 1986, is the only currently operating disposal area for low-level radioactive waste at ORNL. In addition to SWSA 6, it was determined that hazardous wastes were treated at the Explosives Detonation Trench (EDT). Explosives and shock-sensitive chemicals such as picric acid, phosphorus, and ammonium nitrate were detonated; debris from the explosions was backfilled into the trench.

  4. Design requirements document for Project W-465, immobilized low-activity waste interim storage

    SciTech Connect (OSTI)

    Burbank, D.A.

    1998-05-19

    The scope of this Design Requirements Document (DRD) is to identify the functions and associated requirements that must be performed to accept, transport, handle, and store immobilized low-activity waste (ILAW) produced by the privatized Tank Waste Remediation System (TWRS) treatment contractors. The functional and performance requirements in this document provide the basis for the conceptual design of the TWRS ILAW Interim Storage facility project and provides traceability from the program level requirements to the project design activity. Technical and programmatic risk associated with the TWRS planning basis are discussed in the Tank Waste Remediation System Decisions and Risk Assessment (Johnson 1994). The design requirements provided in this document will be augmented by additional detailed design data documented by the project.

  5. TWRS retrieval and storage mission, immobilized low-activity waste disposal plan

    SciTech Connect (OSTI)

    Shade, J.W.

    1998-01-07

    The TWRS mission is to store, treat, and immobilize highly radioactive Hanford waste (current and future tank waste and the encapsulated cesium and strontium) in a safe, environmentally sound, and cost-effective manner (TWRS JMN Justification for mission need). The mission includes retrieval, pretreatment, immobilization, interim storage and disposal, and tank closure. As part of this mission, DOE has established the TWRS Office to manage all Hanford Site tank waste activities. The TWRS program has identified the need to store, treat, immobilize, and dispose of the highly radioactive Hanford Site tank waste and encapsulated cesium and strontium materials in an environmentally sound, safe, and cost-effective manner. To support environmental remediation and restoration at the Hanford Site a two-phase approach to using private contractors to treat and immobilize the low-activity and high-level waste currently stored in underground tanks is planned. The request for proposals (RFP) for the first phase of waste treatment and immobilization was issued in February 1996 (Wagoner 1996) and initial contracts for two private contractor teams led by British Nuclear Fuels Ltd. and Lockheed-Martin Advanced Environmental Services were signed in September 1996. Phase 1 is a proof-of-concept and commercial demonstration effort to demonstrate the technical and business feasibility of using private facilities to treat Hanford Site waste, maintain radiological, nuclear, process, and occupational safety; and maintain environmental protection and compliance while reducing lifecycle costs and waste treatment times. Phase 1 production of ILAW is planned to begin in June 2002 and could treat up to about 13 percent of the waste. Phase 1 production is expected to be completed in 2007 for minimum order quantities or 2011 for maximum order quantities. Phase 2 is a full-scale production effort that will begin after Phase 1 and treat and immobilize most of the waste. Phase 2 production is

  6. WASTE ISOLATION PILOT PLANT (WIPP): THE NATIONS' SOLUTION TO NUCLEAR WASTE STORAGE AND DISPOSAL ISSUES

    SciTech Connect (OSTI)

    Lopez, Tammy Ann

    2014-07-17

    In the southeastern portion of my home state of New Mexico lies the Chihuahauan desert, where a transuranic (TRU), underground disposal site known as the Waste Isolation Pilot Plant (WIPP) occupies 16 square miles. Full operation status began in March 1999, the year I graduated from Los Alamos High School, in Los Alamos, NM, the birthplace of the atomic bomb and one of the nation’s main TRU waste generator sites. During the time of its development and until recently, I did not have a full grasp on the role Los Alamos was playing in regards to WIPP. WIPP is used to store and dispose of TRU waste that has been generated since the 1940s because of nuclear weapons research and testing operations that have occurred in Los Alamos, NM and at other sites throughout the United States (U.S.). TRU waste consists of items that are contaminated with artificial, man-made radioactive elements that have atomic numbers greater than uranium, or are trans-uranic, on the periodic table of elements and it has longevity characteristics that may be hazardous to human health and the environment. Therefore, WIPP has underground rooms that have been carved out of 2,000 square foot thick salt formations approximately 2,150 feet underground so that the TRU waste can be isolated and disposed of. WIPP has operated safely and successfully until this year, when two unrelated events occurred in February 2014. With these events, the safety precautions and measures that have been operating at WIPP for the last 15 years are being revised and improved to ensure that other such events do not occur again.

  7. Immobilized High Level Waste (HLW) Interim Storage Alternative Generation and analysis and Decision Report 2nd Generation Implementing Architecture

    SciTech Connect (OSTI)

    CALMUS, R.B.

    2000-09-14

    Two alternative approaches were previously identified to provide second-generation interim storage of Immobilized High-Level Waste (IHLW). One approach was retrofit modification of the Fuel and Materials Examination Facility (FMEF) to accommodate IHLW. The results of the evaluation of the FMEF as the second-generation IHLW interim storage facility and subsequent decision process are provided in this document.

  8. Advanced Mixed Waste Treatment Project melter system preliminary design technical review meeting

    SciTech Connect (OSTI)

    Eddy, T.L.; Raivo, B.D.; Soelberg, N.R.; Wiersholm, O.

    1995-02-01

    The Idaho National Engineering Laboratory Advanced Mixed Waste Treatment Project sponsored a plasma are melter technical design review meeting to evaluate high-temperature melter system configurations for processing heterogeneous alpha-contaminated low-level radioactive waste (ALLW). Thermal processing experts representing Department of Energy contractors, the Environmental Protection Agency, and private sector companies participated in the review. The participants discussed issues and evaluated alternative configurations for three areas of the melter system design: plasma torch melters and graphite arc melters, offgas treatment options, and overall system configuration considerations. The Technical Advisory Committee for the review concluded that graphite arc melters are preferred over plasma torch melters for processing ALLW. Initiating involvement of stakeholders was considered essential at this stage of the design. For the offgas treatment system, the advisory committee raised the question whether to a use wet-dry or a dry-wet system. The committee recommended that the waste stream characterization, feed preparation, and the control system are essential design tasks for the high-temperature melter treatment system. The participants strongly recommended that a complete melter treatment system be assembled to conduct tests with nonradioactive surrogate waste material. A nonradioactive test bed would allow for inexpensive design and operational changes prior to assembling a system for radioactive waste treatment operations.

  9. Apparatus for the processing of solid mixed waste containing radioactive and hazardous materials

    DOE Patents [OSTI]

    Gotovchikov, Vitaly T.; Ivanov, Alexander V.; Filippov, Eugene A.

    1999-03-16

    Apparatus for the continuous heating and melting of a solid mixed waste bearing radioactive and hazardous materials to form separate metallic, slag and gaseous phases for producing compact forms of the waste material to facilitate disposal includes a copper split water-cooled (cold) crucible as a reaction vessel for receiving the waste material. The waste material is heated by means of the combination oaf plasma torch directed into the open upper portion of the cold crucible and an electromagnetic flux produced by induction coils disposed about the crucible which is transparent to electromagnetic fields. A metallic phase of the waste material is formed in a lower portion of the crucible and is removed in the form of a compact ingot suitable for recycling and further processing. A glass-like, non-metallic slag phase containing radioactive elements is also formed in the crucible and flows out of the open upper portion of the crucible into a slag ingot mold for disposal. The decomposition products of the organic and toxic materials are incinerated and converted to environmentally safe gases in the melter.

  10. Apparatus for the processing of solid mixed waste containing radioactive and hazardous materials

    DOE Patents [OSTI]

    Gotovchikov, V.T.; Ivanov, A.V.; Filippov, E.A.

    1999-03-16

    Apparatus for the continuous heating and melting of a solid mixed waste bearing radioactive and hazardous materials to form separate metallic, slag and gaseous phases for producing compact forms of the waste material to facilitate disposal includes a copper split water-cooled (cold) crucible as a reaction vessel for receiving the waste material. The waste material is heated by means of the combination of a plasma torch directed into the open upper portion of the cold crucible and an electromagnetic flux produced by induction coils disposed about the crucible which is transparent to electromagnetic fields. A metallic phase of the waste material is formed in a lower portion of the crucible and is removed in the form of a compact ingot suitable for recycling and further processing. A glass-like, non-metallic slag phase containing radioactive elements is also formed in the crucible and flows out of the open upper portion of the crucible into a slag ingot mold for disposal. The decomposition products of the organic and toxic materials are incinerated and converted to environmentally safe gases in the melter. 6 figs.

  11. Vitrification of M-Area Mixed (Hazardous and Radioactive) F006 Wastes: I. Sludge and Supernate Characterization

    SciTech Connect (OSTI)

    Jantzen, C.M.

    2001-10-05

    Technologies are being developed by the US Department of Energy's (DOE) Nuclear Facility sites to convert low-level and mixed (hazardous and radioactive) wastes to a solid stabilized waste form for permanent disposal. One of the alternative technologies is vitrification into a borosilicate glass waste form. The Environmental Protection Agency (EPA) has declared vitrification the Best Demonstrated Available Technology (BDAT) for high-level radioactive mixed waste and produced a Handbook of Vitrification Technologies for Treatment of Hazardous and Radioactive Waste. The DOE Office of Technology Development (OTD) has taken the position that mixed waste needs to be stabilized to the highest level reasonably possible to ensure that the resulting waste forms will meet both current and future regulatory specifications. Stabilization of low level and hazardous wastes in glass are in accord with the 1988 Savannah River Technology Center (SRTC), then the Savannah River Laboratory (SRL), Professional Planning Committee (PPC) recommendation that high nitrate containing (low-level) wastes be incorporated into a low temperature glass (via a sol-gel technology). The investigation into this new technology was considered timely because of the potential for large waste volume reduction compared to solidification into cement.

  12. Geological site characterization for the proposed Mixed Waste Disposal Facility, Los Alamos National Laboratory

    SciTech Connect (OSTI)

    Reneau, S.L.; Raymond, R. Jr.

    1995-12-01

    This report presents the results of geological site characterization studies conducted from 1992 to 1994 on Pajarito Mesa for a proposed Los Alamos National Laboratory Mixed Waste Disposal Facility (MWDF). The MWDF is being designed to receive mixed waste (waste containing both hazardous and radioactive components) generated during Environmental Restoration Project cleanup activities at Los Alamos. As of 1995, there is no Resource Conservation and Recovery Act (RCRA) permitted disposal site for mixed waste at the Laboratory, and construction of the MWDF would provide an alternative to transport of this material to an off-site location. A 2.5 km long part of Pajarito Mesa was originally considered for the MWDF, extending from an elevation of about 2150 to 2225 m (7060 to 7300 ft) in Technical Areas (TAs) 15, 36, and 67 in the central part of the Laboratory, and planning was later concentrated on the western area in TA-67. The mesa top lies about 60 to 75 m (200 to 250 ft) above the floor of Pajarito Canyon on the north, and about 30 m (100 ft) above the floor of Threemile Canyon on the south. The main aquifer used as a water supply for the Laboratory and for Los Alamos County lies at an estimated depth of about 335 m (1100 ft) below the mesa. The chapters of this report focus on surface and near-surface geological studies that provide a basic framework for siting of the MWDF and for conducting future performance assessments, including fulfillment of specific regulatory requirements. This work includes detailed studies of the stratigraphy, mineralogy, and chemistry of the bedrock at Pajarito Mesa by Broxton and others, studies of the geological structure and of mesa-top soils and surficial deposits by Reneau and others, geologic mapping and studies of fracture characteristics by Vaniman and Chipera, and studies of potential landsliding and rockfall along the mesa-edge by Reneau.

  13. Greater-than-Class C low-level radioactive waste characterization. Appendix E-2: Mixed GTCC LLW assessment

    SciTech Connect (OSTI)

    Kirner, N.P. [Ebasco Environmental, Idaho Falls, ID (United States)

    1994-09-01

    Mixed greater-than-Class C low-level radioactive waste (mixed GTCC LLW) is waste that combines two characteristics: it is radioactive, and it is hazardous. This report uses information compiled from Greater-Than-Class C Low-Level Radioactive Waste Characterization: Estimated Volumes, Radionuclide Activities, and Other Characteristics (DOE/LLW 1 14, Revision 1), and applies it to the question of how much and what types of mixed GTCC LLW are generated and are likely to require disposal in facilities jointly regulated by the DOE and the NRC. The report describes how to classify a RCRA hazardous waste, and then applies that classification process to the 41 GTCC LLW waste types identified in the DOE/LLW-114 (Revision 1). Of the 41 GTCC LLW categories identified, only six were identified in this study as potentially requiring regulation as hazardous waste under RCRA. These wastes can be combined into the following three groups: fuel-in decontamination resins, organic liquids, and process waste consisting of lead scrap/shielding from a sealed source manufacturer. For the base case, no mixed GTCC LLW is expected from nuclear utilities or sealed source licensees, whereas only 177 ml of mixed GTCC LLW are expected to be produced by other generators through the year 2035. This relatively small volume represents approximately 40% of the base case estimate for GTCC wastes from other generators. For these other generators, volume estimates for mixed GTCC LLW ranged from less than 1 m{sup 3} to 187 m{sup 3}, depending on assumptions and treatments applied to the wastes.

  14. EIS-0109: Long-Term Management of the Existing Radioactive Wastes and Residues at the Niagara Falls Storage Site

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy developed this statement to evaluate the environmental impacts of several alternatives for management and control of the radioactive wastes and residues at the Niagara Falls Storage Site, including a no action alternative, an alternative to manage wastes on site, and two off-site management alternatives.

  15. High level waste storage tank farms/242-A evaporator Standards/Requirements Identification Document (S/RID), Volume 6

    SciTech Connect (OSTI)

    Not Available

    1994-04-01

    The High-Level Waste Storage Tank Farms/242-A Evaporator Standards/Requirements Identification Document (S/RID) is contained in multiple volumes. This document (Volume 6) outlines the standards and requirements for the sections on: Environmental Restoration and Waste Management, Research and Development and Experimental Activities, and Nuclear Safety.

  16. US Department of Energy Storage of Spent Fuel and High Level Waste

    SciTech Connect (OSTI)

    Sandra M Birk

    2010-10-01

    ABSTRACT This paper provides an overview of the Department of Energy's (DOE) spent nuclear fuel (SNF) and high level waste (HLW) storage management. Like commercial reactor fuel, DOE's SNF and HLW were destined for the Yucca Mountain repository. In March 2010, the DOE filed a motion with the Nuclear Regulatory Commission (NRC) to withdraw the license application for the repository at Yucca Mountain. A new repository is now decades away. The default for the commercial and DOE research reactor fuel and HLW is on-site storage for the foreseeable future. Though the motion to withdraw the license application and delay opening of a repository signals extended storage, DOE's immediate plans for management of its SNF and HLW remain the same as before Yucca Mountain was designated as the repository, though it has expanded its research and development efforts to ensure safe extended storage. This paper outlines some of the proposed research that DOE is conducting and will use to enhance its storage systems and facilities.

  17. Evaluation of tubular reactor designs for supercritical water oxidation of U.S. Department of Energy mixed waste

    SciTech Connect (OSTI)

    Barnes, C.M.

    1994-12-01

    Supercritical water oxidation (SCWO) is an emerging technology for industrial waste treatment and is being developed for treatment of the US Department of Energy (DOE) mixed hazardous and radioactive wastes. In the SCWO process, wastes containing organic material are oxidized in the presence of water at conditions of temperature and pressure above the critical point of water, 374 C and 22.1 MPa. DOE mixed wastes consist of a broad spectrum of liquids, sludges, and solids containing a wide variety of organic components plus inorganic components including radionuclides. This report is a review and evaluation of tubular reactor designs for supercritical water oxidation of US Department of Energy mixed waste. Tubular reactors are evaluated against requirements for treatment of US Department of Energy mixed waste. Requirements that play major roles in the evaluation include achieving acceptable corrosion, deposition, and heat removal rates. A general evaluation is made of tubular reactors and specific reactors are discussed. Based on the evaluations, recommendations are made regarding continued development of supercritical water oxidation reactors for US Department of Energy mixed waste.

  18. The Changing Adventures of Mixed Low-Level Waste Disposal at the Nevada Test Site

    SciTech Connect (OSTI)

    DOE /Navarro/NSTec

    2007-02-01

    After a 15-year hiatus, the United States Department of Energy (DOE) National Nuclear Security Administration Nevada Site Office (NNSA/NSO) began accepting DOE off-site generated mixed low-level radioactive waste (MLLW) for disposal at the Nevada Test Site (NTS) in December 2005. This action was predicated on the acceptance by the Nevada Division of Environmental Protection (NDEP) of a waste analysis plan (WAP). The NNSA/NSO agreed to limit mixed waste disposal to 20,000 cubic meters (approximately 706,000 cubic feet) and close the facility by December 2010 or sooner, if the volume limit is reached. The WAP and implementing procedures were developed based on Hanford’s system of verification to the extent possible so the two regional disposal sites could have similar processes. Since the NNSA/NSO does not have a breaching facility to allow the opening of boxes at the site, verification of the waste occurs by visual inspection at the generator/treatment facility or by Real-Time-Radiography (RTR) at the NTS. This system allows the NTS to effectively, efficiently, and compliantly accept MLLW for disposal. The WAP, NTS Waste Acceptance Criteria, and procedures have been revised based on learning experiences. These changes include: RTR expectations; visual inspection techniques; tamper-indicating device selection; void space requirements; and chemical screening concerns. The NNSA/NSO, NDEP, and the generators have been working together throughout the debugging of the verification processes. Additionally, the NNSA/NSO will continue to refine the MLLW acceptance processes and strive for continual improvement of the program.

  19. Nevada Nuclear-Waste-Storage Investigations. Quarterly report, April-June 1982

    SciTech Connect (OSTI)

    1982-09-01

    The Nevada Nuclear Waste Storage Investigations (NNWSI) are studying the Nevada Test Site (NTS) area to establish whether it would qualify as a licensable location for a commercial nuclear waste repository; determining whether specific underground rock masses in the NTS area are technically acceptable for permanently disposing of highly radioactive solid wastes; and developing and demonstrating the capability to safely handle and store commercial spent reactor fuel and high-level waste. Progress reports for the following eight tasks are presented: systems; waste package; site; repository; regulatory and institutional; test facilities; land acquisition; and program management. Some of the highlights are: A code library was established to provide a central location for documentation of repository performance assessment codes. A two-dimensional finite element code, SAGUARO, was developed for modeling saturated/unsaturated groundwater flow. The results of an initial experiment to determine canister penetration rates due to corrosion indicate the expected strong effect of toxic environmental conditions on the corrosion rate of carbon steel in tuff-conditioned water. Wells USW-H3 and USW-H4 at Yucca Mountain have been sampled for groundwater analysis. A summary characterizing and relating the mineralogy and petrology of Yucca Mountain tuffs was compiled from the findings of studies of core samples from five drill holes.

  20. Risk perception on management of nuclear high-level and transuranic waste storage

    SciTech Connect (OSTI)

    Dees, L.A.

    1994-08-15

    The Department of Energy`s program for disposing of nuclear High-Level Waste (HLW) and transuranic (TRU) waste has been impeded by overwhelming political opposition fueled by public perceptions of actual risk. Analysis of these perceptions shows them to be deeply rooted in images of fear and dread that have been present since the discovery of radioactivity. The development and use of nuclear weapons linked these images to reality and the mishandling of radioactive waste from the nations military weapons facilities has contributed toward creating a state of distrust that cannot be erased quickly or easily. In addition, the analysis indicates that even the highly educated technical community is not well informed on the latest technology involved with nuclear HLW and TRU waste disposal. It is not surprising then, that the general public feels uncomfortable with DOE`s management plans for with nuclear HLW and TRU waste disposal. Postponing the permanent geologic repository and use of Monitored Retrievable Storage (MRS) would provide the time necessary for difficult social and political issues to be resolved. It would also allow time for the public to become better educated if DOE chooses to become proactive.

  1. Ocean disposal option for bulk wastes containing naturally occurring radionuclides: an assessment case history. [From Niagara Falls storage site

    SciTech Connect (OSTI)

    Stull, E.A.; Merry-Libby, P.

    1985-01-01

    There are 180,000 m/sup 3/ of slightly contaminated radioactive wastes (36 pCi/g radium-226) currently stored at the US Department of Energy's Niagara Falls Storage Site (NFSS), near Lewiston, New York. These wastes resulted from the cleanup of soils that were contaminated above the guidelines for unrestricted use of property. An alternative to long-term management of these wastes on land is dispersal in the ocean. A scenario for ocean disposal is present

  2. EIS-0062: Double-Shell Tanks for Defense High Level Waste Storage, Savannah River Site, Aiken, SC

    Broader source: Energy.gov [DOE]

    This EIS analyzes the impacts of the various design alternatives for the construction of fourteen 1.3 million gallon high-activity radioactive waste tanks. The EIS further evaluates the effects of these alternative designs on tank durability, on the ease of waste retrieval from such tanks, and the choice of technology and timing for long-term storage or disposal of the wastes.

  3. Iron-phosphate ceramics for solidification of mixed low-level waste

    DOE Patents [OSTI]

    Aloy, Albert S.; Kovarskaya, Elena N.; Koltsova, Tatiana I.; Macheret, Yevgeny; Medvedev, Pavel G.; Todd, Terry

    2000-01-01

    A method of immobilizing mixed low-level waste is provided which uses low cost materials and has a relatively long hardening period. The method includes: forming a mixture of iron oxide powders having ratios, in mass %, of FeO:Fe.sub.2 O.sub.3 :Fe.sub.3 O.sub.4 equal to 25-40:40-10:35-50, or weighing a definite amount of magnetite powder. Metallurgical cinder can also be used as the source of iron oxides. A solution of the orthophosphoric acid, or a solution of the orthophosphoric acid and ferric oxide, is formed and a powder phase of low-level waste and the mixture of iron oxide powders or cinder (or magnetite powder) is also formed. The acid solution is mixed with the powder phase to form a slurry with the ratio of components (mass %) of waste:iron oxide powders or magnetite:acid solution=30-60:15-10:55-30. The slurry is blended to form a homogeneous mixture which is cured at room temperature to form the final product.

  4. Framework for DOE mixed low-level waste disposal: Site fact sheets

    SciTech Connect (OSTI)

    Gruebel, M.M.; Waters, R.D.; Hospelhorn, M.B.; Chu, M.S.Y.

    1994-11-01

    The Department of Energy (DOE) is required to prepare and submit Site Treatment Plans (STPS) pursuant to the Federal Facility Compliance Act (FFCAct). Although the FFCAct does not require that disposal be addressed in the STPS, the DOE and the States recognize that treatment of mixed low-level waste will result in residues that will require disposal in either low-level waste or mixed low-level waste disposal facilities. As a result, the DOE is working with the States to define and develop a process for evaluating disposal-site suitability in concert with the FFCAct and development of the STPS. Forty-nine potential disposal sites were screened; preliminary screening criteria reduced the number of sites for consideration to twenty-six. The DOE then prepared fact sheets for the remaining sites. These fact sheets provided additional site-specific information for understanding the strengths and weaknesses of the twenty-six sites as potential disposal sites. The information also provided the basis for discussion among affected States and the DOE in recommending sites for more detailed evaluation.

  5. INNOVATIVE TECHNIQUES AND TECHNOLOGY APPLICATION IN MANAGEMENT OF REMOTE HANDLED AND LARGE SIZED MIXED WASTE FORMS

    SciTech Connect (OSTI)

    BLACKFORD LT

    2008-02-04

    of RCRA storage regulations, reduce costs for waste management by nearly 50 percent, and create a viable method for final treatment and disposal of these waste forms that does not impact retrieval project schedules. This paper is intended to provide information to the nuclear and environmental clean-up industry with the experience of CH2M HILL and ORP in managing these highly difficult waste streams, as well as providing an opportunity for sharing lessons learned, including technical methods and processes that may be applied at other DOE sites.

  6. Report of the committee to review the use of J-13 well water in Nevada Nuclear Waste Storage Investigations

    SciTech Connect (OSTI)

    Harrar, J.E.; Carley, J.F.; Isherwood, W.F.; Raber, E.

    1990-01-01

    The Waste Management Project Office of the Department of Energy conducted a special audit of the activities of the Nevada Nuclear Waste Storage Investigation Project at Livermore. It was noted that there never has been a comprehensive, well-documented examination of the basis for the use of J-13 water in the nuclear waste storage investigations. In each of the sections of This Report, an issue relating to the use of J-13 water has been addressed. 58 refs., 19 figs., 8 tabs.

  7. Equipment design guidance document for flammable gas waste storage tank new equipment

    SciTech Connect (OSTI)

    Smet, D.B.

    1996-04-11

    This document is intended to be used as guidance for design engineers who are involved in design of new equipment slated for use in Flammable Gas Waste Storage Tanks. The purpose of this document is to provide design guidance for all new equipment intended for application into those Hanford storage tanks in which flammable gas controls are required to be addressed as part of the equipment design. These design criteria are to be used as guidance. The design of each specific piece of new equipment shall be required, as a minimum to be reviewed by qualified Unreviewed Safety Question evaluators as an integral part of the final design approval. Further Safety Assessment may be also needed. This guidance is intended to be used in conjunction with the Operating Specifications Documents (OSDs) established for defining work controls in the waste storage tanks. The criteria set forth should be reviewed for applicability if the equipment will be required to operate in locations containing unacceptable concentrations of flammable gas.

  8. The residuals analysis project: Evaluating disposal options for treated mixed low-level waste

    SciTech Connect (OSTI)

    Waters, R.D.; Gruebel, M.M.; Case, J.T.; Letourneau, M.J.

    1997-03-01

    For almost four years, the U.S. Department of Energy (DOE) through its Federal Facility Compliance Act Disposal Workgroup has been working with state regulators and governors` offices to develop an acceptable configuration for disposal of its mixed low-level waste (MLLW). These interactions have resulted in screening the universe of potential disposal sites from 49 to 15 and conducting ``performance evaluations`` for those fifteen sites to estimate their technical capabilities for disposal of MLLW. In the residuals analysis project, we estimated the volume of DOE`s MLLW that will require disposal after treatment and the concentrations of radionuclides in the treated waste. We then compared the radionuclide concentrations with the disposal limits determined in the performance evaluation project for each of the fifteen sites. The results are a scoping-level estimate of the required volumetric capacity for MLLW disposal and the identification of waste streams that may pose problems for disposal based on current treatment plans. The analysis provides technical information for continued discussions between the DOE and affected States about disposal of MLLW and systematic input to waste treatment developers on disposal issues.

  9. Simulant Development for Hanford Double-Shell Tank Mixing and Waste Feed Delivery Testing

    SciTech Connect (OSTI)

    Gauglitz, Phillip A.; Tran, Diana N.; Buchmiller, William C.

    2012-09-24

    The U.S. Department of Energy Office of River Projection manages the River Protection Project, which has the mission to retrieve and treat the Hanford tank waste for disposal and close the tank farms (Certa et al. 2011). Washington River Protection Solutions, LLC (WRPS) is responsible for a primary objective of this mission which is to retrieve and transfer tank waste to the Hanford Waste Treatment and Immobilization Plant (WTP). A mixing and sampling program with four separate demonstrations is currently being conducted to support this objective and also to support activities in a plan for addressing safety concerns identified by the Defense Nuclear Facilities Safety Board related to the ability of the WTP to mix, sample, and transfer fast settling particles. Previous studies have documented the objectives, criteria, and selection of non-radioactive simulants for these four demonstrations. The identified simulants include Newtonian suspending liquids with densities and viscosities that span the range expected in waste feed tanks. The identified simulants also include non-Newtonian slurries with Bingham yield stress values that span a range that is expected to bound the Bingham yield stress in the feed delivery tanks. The previous studies identified candidate materials for the Newtonian and non-Newtonian suspending fluids, but did not provide specific recipes for obtaining the target properties and information was not available to evaluate the compatibility of the fluids and particles or the potential for salt precipitation at lower temperatures. The purpose of this study is to prepare small batches of simulants in advance of the demonstrations to determine specific simulant recipes, to evaluate the compatibility of the liquids and particles, and to determine if the simulants are stable for the potential range of test temperatures. The objective of the testing, which is focused primarily on the Newtonian and non-Newtonian fluids, is to determine the composition of

  10. Potential applications of artificial intelligence in computer-based management systems for mixed waste incinerator facility operation

    SciTech Connect (OSTI)

    Rivera, A.L.; Singh, S.P.N.; Ferrada, J.J.

    1991-01-01

    The Department of Energy/Oak Ridge Field Office (DOE/OR) operates a mixed waste incinerator facility at the Oak Ridge K-25 Site, designed for the thermal treatment of incinerable liquid, sludge, and solid waste regulated under the Toxic Substances Control Act (TSCA) and the Resource Conversion and Recovery Act (RCRA). Operation of the TSCA Incinerator is highly constrained as a result of the regulatory, institutional, technical, and resource availability requirements. This presents an opportunity for applying computer technology as a technical resource for mixed waste incinerator operation to facilitate promoting and sustaining a continuous performance improvement process while demonstrating compliance. This paper describes mixed waste incinerator facility performance-oriented tasks that could be assisted by Artificial Intelligence (AI) and the requirements for AI tools that would implement these algorithms in a computer-based system. 4 figs., 1 tab.

  11. Readiness assessment plan for the Radioactive Mixed Waste Land Disposal Facility (Trench 31)

    SciTech Connect (OSTI)

    Irons, L.G.

    1994-11-22

    This document provides the Readiness Assessment Plan (RAP) for the Project W-025 (Radioactive Mixed Waste Land Disposal Facility) Readiness Assessment (RA). The RAP documents prerequisites to be met by the operating organization prior to the RA. The RAP is to be implemented by the RA Team identified in the RAP. The RA Team is to verify the facility`s compliance with criteria identified in the RAP. The criteria are based upon the {open_quotes}Core Requirements{close_quotes} listed in DOE Order 5480.31, {open_quotes}Startup and Restart of Nuclear Facilities{close_quotes}.

  12. Compliance matrix for the mixed waste disposal facilities, Trenches 31 & 34, burial ground 218-W-5

    SciTech Connect (OSTI)

    Carlyle, D.W.

    1994-10-31

    The purpose of the Trench 31 & 34 Mixed Waste Disposal Facility Compliance Matrix is to provide objective evidence of implementation of all regulatory and procedural-institutional requirements for the disposal facilities. This matrix provides a listing of the individual regulatory and procedural-institutional requirements that were addressed. Subject matter experts reviewed pertinent documents that had direct or indirect impact on the facility. Those found to be applicable were so noted and listed in Appendix A. Subject matter experts then extracted individual requirements from the documents deemed applicable and listed them in the matrix tables. The results of this effort are documented in Appendix B.

  13. Novel procurement concepts utilized to award contract for vitrification of an F006 mixed waste sludge

    SciTech Connect (OSTI)

    Pickett, J.B.; Musall, J.C.; Hayes, A.F.; Campbell, E.E.

    1994-06-01

    A number of novel concepts were utilized in a procurement bid process to award a contract for the stabilization of a mixed wastewater treatment plating line sludge from the Reactor Materials department (M-Area) at the Savannah River site (SRS). The contract award was based on a combination of technical and cost considerations. The technical aspects included an evaluation of the technical validity of the proposed process(es) (i.e., would the process work?), the physical resources of the proposer and the expertise of the personnel proposed to work on the program, and prior experience of the firm wit treatment and stabilization of mixed (radioactive and hazardous) wastes. This paper will concentrate on the cost and the bid award considerations, rather than the technical aspects.

  14. Performance assessment for continuing and future operations at Solid Waste Storage Area 6

    SciTech Connect (OSTI)

    Not Available

    1994-02-01

    This radiological performance assessment for the continued disposal operations at Solid Waste Storage Area 6 (SWSA 6) on the Oak Ridge Reservation (ORR) has been prepared to demonstrate compliance with the requirements of the US DOE. The analysis of SWSA 6 required the use of assumptions to supplement the available site data when the available data were incomplete for the purpose of analysis. Results indicate that SWSA 6 does not presently meet the performance objectives of DOE Order 5820.2A. Changes in operations and continued work on the performance assessment are expected to demonstrate compliance with the performance objectives for continuing operations at the Interim Waste Management Facility (IWMF). All other disposal operations in SWSA 6 are to be discontinued as of January 1, 1994. The disposal units at which disposal operations are discontinued will be subject to CERCLA remediation, which will result in acceptable protection of the public health and safety.

  15. Peer review of the Nevada Nuclear Waste Storage Investigations, August 24-28, 1981

    SciTech Connect (OSTI)

    1984-02-01

    On August 24-28, 1981, a peer review of three major areas of the Nevada Nuclear Waste Storage Investigations was conducted at the Riviera Hotel in Las Vegas, Nevada. The three investigative areas were: (1) geology/hydrology, (2) geotechnical/geoengineering, and (3) environmental studies. A separate review panel was established for each of the investigative areas which was composed of experts representing appropriate fields of expertise. A total of twenty nationally known or prominent state and local experts served on the three review panels.

  16. ADMINISTRATIVE AND ENGINEERING CONTROLS FOR THE OPERATION OF VENTILATION SYSTEMS FOR UNDERGROUND RADIOACTIVE WASTE STORAGE TANKS

    SciTech Connect (OSTI)

    Wiersma, B.; Hansen, A.

    2013-11-13

    Liquid radioactive wastes from the Savannah River Site are stored in large underground carbon steel tanks. The majority of the waste is confined in double shell tanks, which have a primary shell, where the waste is stored, and a secondary shell, which creates an annular region between the two shells, that provides secondary containment and leak detection capabilities should leakage from the primary shell occur. Each of the DST is equipped with a purge ventilation system for the interior of the primary shell and annulus ventilation system for the secondary containment. Administrative flammability controls require continuous ventilation to remove hydrogen gas and other vapors from the waste tanks while preventing the release of radionuclides to the atmosphere. Should a leak from the primary to the annulus occur, the annulus ventilation would also serve this purpose. The functionality of the annulus ventilation is necessary to preserve the structural integrity of the primary shell and the secondary. An administrative corrosion control program is in place to ensure integrity of the tank. Given the critical functions of the purge and annulus ventilation systems, engineering controls are also necessary to ensure that the systems remain robust. The system consists of components that are constructed of metal (e.g., steel, stainless steel, aluminum, copper, etc.) and/or polymeric (polypropylene, polyethylene, silicone, polyurethane, etc.) materials. The performance of these materials in anticipated service environments (e.g., normal waste storage, waste removal, etc.) was evaluated. The most aggressive vapor space environment occurs during chemical cleaning of the residual heels by utilizing oxalic acid. The presence of NO{sub x} and mercury in the vapors generated from the process could potentially accelerate the degradation of aluminum, carbon steel, and copper. Once identified, the most susceptible materials were either replaced and/or plans for discontinuing operations

  17. Radioactive waste shipments to Hanford retrievable storage from Westinghouse Advanced Reactors and Nuclear Fuels Divisions, Cheswick, Pennsylvania

    SciTech Connect (OSTI)

    Duncan, D.; Pottmeyer, J.A.; Weyns, M.I.; Dicenso, K.D.; DeLorenzo, D.S.

    1994-04-01

    During the next two decades the transuranic (TRU) waste now stored in the burial trenches and storage facilities at the Hanford Sits in southeastern Washington State is to be retrieved, processed at the Waste Receiving and Processing Facility, and shipped to the Waste Isolation Pilot Plant (WIPP), near Carlsbad, New Mexico for final disposal. Approximately 5.7 percent of the TRU waste to be retrieved for shipment to WIPP was generated by the decontamination and decommissioning (D&D) of the Westinghouse Advanced Reactors Division (WARD) and the Westinghouse Nuclear Fuels Division (WNFD) in Cheswick, Pennsylvania and shipped to the Hanford Sits for storage. This report characterizes these radioactive solid wastes using process knowledge, existing records, and oral history interviews.

  18. Environmental Assessment and Finding of No Significant Impact: On-Site Treatment of Low Level Mixed Waste

    SciTech Connect (OSTI)

    N /A

    1999-03-22

    The Department of Energy (DOE) has prepared an environmental assessment (EA) (DOE/EA-1292) to evaluate the proposed treatment of low level mixed waste (LLMW) at the Rocky Flats Environmental Technology Site (Site). The purpose of the action is to treat LLMW in order to meet the Land Disposal Restrictions specified by the Resource Conservation and Recovery Act and the waste acceptance criteria of the planned disposal site(s). Approximately 17,000 cubic meters (m{sup 3}) of LLMW are currently stored at the Site. Another 65,000 m{sup 3}of LLMW are likely to be generated by Site closure activities (a total of 82,000 m{sup 3} of LLMW). About 35,000 m{sup 3} can be directly disposed of off-site without treatment, and most of the remaining 47,000 m{sup 3} of LLMW can be treated at off-site treatment, storage, and disposal facilities. However, some LLMW will require treatment on-site, either because it does not meet shipping requirements or because off-site treatment is not available for these particular types of LLMW. Currently, this LLMW is stored at the Site pending the development and implementation of effective treatment processes. The Site needs to treat this LLMW on-site prior to shipment to off-site disposal facilities, in order to meet the DOE long-term objective of clean up and closure of the Site. All on-site treatment of LLMW would comply with applicable Federal and State laws designed to protect public health and safety and to enhance protection of the environment. The EA describes and analyzes the environmental effects of the proposed action (using ten mobile treatment processes to treat waste on-site), and the alternatives of treating waste onsite (using two fixed treatment processes), and of taking no action. The EA was the subject of a public comment period from February 3 to 24, 1999. No written or other comments regarding the EA were received.

  19. Twelfth annual US DOE low-level waste management conference

    SciTech Connect (OSTI)

    Not Available

    1990-01-01

    The papers in this document comprise the proceedings of the Department of Energy's Twelfth Annual Low-Level Radioactive Waste Management Conference, which was held in Chicago, Illinois, on August 28 and 29, 1990. General subjects addressed during the conference included: mixed waste, low-level radioactive waste tracking and transportation, public involvement, performance assessment, waste stabilization, financial assurance, waste minimization, licensing and environmental documentation, below-regulatory-concern waste, low-level radioactive waste temporary storage, current challenges, and challenges beyond 1990.

  20. Environmental monitoring plan for the Niagara Falls Storage Site and the Interim Waste Containment Facility

    SciTech Connect (OSTI)

    Not Available

    1986-04-01

    As part of the US Department of Energy's (DOE) Surplus Facility Management Program (SFMP), the Niagara Falls Storage Site (NFSS) is undergoing remedial action. Vicinity properties adjacent to and near the site are being cleaned up as part of DOE's Formerly Utilized Sites Remedial Action Program (FUSRAP). These programs are a DOE effort to clean up low-level radioactive waste resulting from the early days of the nation's atomic energy program. Radioactively contaminated waste from these remedial action activities are being stored at the NFSS in an interim waste containment facility (IWCF). When the remedial actions and IWCF are completed in 1986, activities at the site will be limited to waste management. The monitoring program was prepared in accordance with DOE Order 5484.1 and is designed to determine the contribution of radioactivity from the site to the environs and to demonstrate compliance with applicable criteria. Major elements of this program will also supplement other monitoring requirements including the performance monitoring system for the IWCF and the closure/post-closure plan. Emphasis will be directed toward the sampling and analysis of groundwater, surface water, air and sediment for parameters which are known to be present in the material stored at the site. The monitoring program will employ a phased approach whereby the first 5 years of data will be evaluated, and the program will be reviewed and modified as necessary. 17 refs., 10 figs., 3 tabs.

  1. Nevada nuclear waste storage investigations. Quarterly report, October-December 1981

    SciTech Connect (OSTI)

    1982-03-01

    The Nevada Nuclear Waste Storage Investigations (NNWSI) are investigating and determining whether specific underground rock masses are suitable for permanently disposing of highly radioactive wastes, studying and determining whether the Nevada Test Site (NTS) would qualify as a suitable repository site, and developing and demonstrating the capability to safely handle and store commercial spent reactor fuel and high-level waste. This document is a compilation of the technical progress of the principal project participants of the NNWSI in meeting the objectives described in the draft FY 1982 NNWSI Project Plan and revised planning documentation during the first quarter of FY 1982. The NNWSI Project Work Breakdown Structure (WBS) for FY 1982 is comprised of eight tasks which form the main sections of this document. They are: systems; waste package; site; repository; regulatory and institutional; test facilities; land acquisition; and program management. Scenarios for the release of radionuclide from a repository in alternate rock types occuring in the southwest NTS area were ranked by probabilities. Analysis of data from 60 wells in and around NTS are nearing completion. A computerized data recording and earthquake detection system that is more efficient was made operational. A series of 55 evaluations of repository locations in the screening area was performed. A review has been completed covering the likelihood of creep failure in a tuff repository. (DMC)

  2. Assessment of degradation concerns for spent fuel, high-level wastes, and transuranic wastes in monitored retrievalbe storage

    SciTech Connect (OSTI)

    Guenther, R.J.; Gilbert, E.R.; Slate, S.C.; Partain, W.L.; Divine, J.R.; Kreid, D.K.

    1984-01-01

    It has been concluded that there are no significant degradation mechanisms that could prevent the design, construction, and safe operation of monitored retrievable storage (MRS) facilities. However, there are some long-term degradation mechanisms that could affect the ability to maintain or readily retrieve spent fuel (SF), high-level wastes (HLW), and transuranic wastes (TRUW) several decades after emplacement. Although catastrophic failures are not anticipated, long-term degradation mechanisms have been identified that could, under certain conditions, cause failure of the SF cladding and/or failure of TRUW storage containers. Stress rupture limits for Zircaloy-clad SF in MRS range from 300 to 440/sup 0/C, based on limited data. Additional tests on irradiated Zircaloy (3- to 5-year duration) are needed to narrow this uncertainty. Cladding defect sizes could increase in air as a result of fuel density decreases due to oxidation. Oxidation tests (3- to 5-year duration) on SF are also needed to verify oxidation rates in air and to determine temperatures below which monitoring of an inert cover gas would not be required. Few, if any, changes in the physical state of HLW glass or canisters or their performance would occur under projected MRS conditions. The major uncertainty for HLW is in the heat transfer through cracked glass and glass devitrification above 500/sup 0/C. Additional study of TRUW is required. Some fraction of present TRUW containers would probably fail within the first 100 years of MRS, and some TRUW would be highly degraded upon retrieval, even in unfailed containers. One possible solution is the design of a 100-year container. 93 references, 28 figures, 17 tables.

  3. Comparison of alternative treatment systems for DOE mixed low-level waste

    SciTech Connect (OSTI)

    Schwinkendorf, W.E.

    1997-03-01

    From 1993 to 1996, the Department of Energy, Environmental Management, Office of Science and Technology (OST), has sponsored a series of systems analyses to guide its future research and development (R&D) programs for the treatment of mixed low-level waste (MLLW) stored in the DOE complex. The two original studies were of 20 mature and innovative thermal systems. As a result of a technical review of these thermal system studies, a similar study of five innovative nonthermal systems was conducted in which unit operations are limited to temperatures less than 350{degrees}C to minimize volatilization of heavy metals and radionuclides, and de novo production of dioxins and furans in the offgas. Public involvement in the INTS study was established through a working group of 20 tribal and stakeholder representatives to provide input to the INTS studies and identify principles against which the systems should be designed and evaluated. Pre-conceptual designs were developed for all systems to treat the same waste input (2927 lbs/hr) in a single centralized facility operating 4032 hours per year for 20 years. This inventory consisted of a wide range of combustible and non-combustible materials such as paper, plastics, metals, concrete, soils, sludges, liquids, etc., contaminated with trace quantities of radioactive materials and RCRA regulated wastes. From this inventory, an average waste profile was developed for simulated treatment using ASPEN PLUS{copyright} for mass balance calculations. Seven representative thermal systems were selected for comparison with the five nonthermal systems. This report presents the comparisons against the TSWG principles, of total life cycle cost (TLCC), and of other system performance indicators such as energy requirements, reagent requirements, land use, final waste volume, aqueous and gaseous effluents, etc.

  4. The effects of different mixing intensities during anaerobic digestion of the organic fraction of municipal solid waste

    SciTech Connect (OSTI)

    Lindmark, Johan Eriksson, Per; Thorin, Eva

    2014-08-15

    Highlights: • Effects of mixing on the anaerobic digestion of municipal solid waste. • Digestion of fresh substrate and post-digestion at three mixing intensities were evaluated. • Mixing performed at 150 RPM, 25 RPM and minimally intermittently. • Increased biogas production rates and yields at lower mixing intensities. - Abstract: Mixing inside an anaerobic digester is often continuous and is not actively controlled. The selected mixing regime can however affect both gas production and the energy efficiency of the biogas plant. This study aims to evaluate these effects and compare three different mixing regimes, 150 RPM and 25 RPM continuous mixing and minimally intermittent mixing for both digestion of fresh substrate and post-digestion of the organic fraction of municipal solid waste. The results show that a lower mixing intensity leads to a higher biogas production rate and higher total biogas production in both cases. 25 RPM continuous mixing and minimally intermittent mixing resulted in similar biogas production after process stabilization, while 150 RPM continuous mixing resulted in lower production throughout the experiment. The lower gas production at 150 RPM could not be explained by the inhibition of volatile fatty acids. Cumulative biogas production until day 31 was 295 ± 2.9, 317 ± 1.9 and 304 ± 2.8 N ml/g VS added during digestion of fresh feed and 113 ± 1.3, 134 ± 1.1 and 130 ± 2.3 N ml/g VS added during post digestion for the 150 RPM, 25 RPM and minimally mixed intensities respectively. As well as increasing gas production, optimal mixing can improve the energy efficiency of the anaerobic digestion process.

  5. Storage

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing ... Heavy Duty Fuels DISI Combustion HCCISCCI Fundamentals Spray Combustion Modeling ...

  6. Vitrification of surrogate mixed wastes in a graphite electrode arc melter

    SciTech Connect (OSTI)

    Soelberg, N.R.; Chambers, A.G.; Ball, L.

    1995-11-01

    Demonstration tests for vitrifying mixed wastes and contaminated soils have been conducted using a small (800 kVA), industrial-scale, three-phase AC, graphite electrode furnace located at the Albany Research Center of the United States Bureau of Mines (USBM). The feed mixtures were non-radioactive surrogates of various types of mixed (radioactive and hazardous), transuranic-contaminated wastes stored and buried at the Idaho National Engineering Laboratory (INEL). The feed mixtures were processed with added soil from the INEL. Objectives being evaluated include (1) equipment capability to achieve desired process conditions and vitrification products for different feed compositions, (2) slag and metals tapping capability, (3) partitioning of transuranic elements and toxic metals among the furnace products, (4) slag, fume, and metal products characteristics, and (5) performance of the feed, furnace and air pollution control systems. The tests were successfully completed in mid-April 1995. A very comprehensive process monitoring, sampling and analysis program was included in the test program. Sample analysis, data reduction, and results evaluation are currently underway. Initial results indicate that the furnace readily processed around 20,000 lb of widely ranging feed mixtures at feedrates of up to 1,100 lb/hr. Continuous feeding and slag tapping was achieved. Molten metal was also tapped twice during the test program. Offgas emissions were efficiently controlled as expected by a modified air pollution control system.

  7. Evapotranspiration Cover for the 92-Acre Area Retired Mixed Waste Pits, Area 5 Waste Management Division, Nevada National Security Site, Final CQA Report

    SciTech Connect (OSTI)

    NSTec Environmental Management; The Delphi Groupe, Inc.; J. A. Cesare and Associates, Inc.

    2012-01-31

    The report is the Final Construction Quality Assurance (CQA) Report for the 92-Acrew Evapotranspiration Cover, Area 5 Waste Management Division Retired Mixed Waste Pits, Nevada National Security Site, Nevada, for the period of January 20, 2011, to January 31, 2012 The Area 5 RWMS uses engineered shallow-land burial cells to dispose of packaged waste. The 92-Acre Area encompasses the southern portion of the Area 5 RWMS, which has been designated for the first final closure operations. This area contains 13 Greater Confinement Disposal (GCD) boreholes, 16 narrow trenches, and 9 broader pits. With the exception of two active pits (P03 and P06), all trenches and pits in the 92-Acre Area had operational covers approximately 2.4 meters thick, at a minimum, in most areas when this project began. The units within the 92-Acre Area are grouped into the following six informal categories based on physical location, waste types and regulatory requirements: (1) Pit 3 Mixed Waste Disposal Unit (MWDU); (2) Corrective Action Unit (CAU) 111; (3) CAU 207; (4) Low-level waste disposal units; (5) Asbestiform low-level waste disposal units; and (6) One transuranic (TRU) waste trench.

  8. NEVADA TEST SITE WASTE ACCEPTANCE CRITERIA

    SciTech Connect (OSTI)

    U.S. DEPARTMENT OF ENERGY, NATIONAL NUCLEAR SECURITY ADMINISTRATION, NEVADA SITE OFFICE

    2005-07-01

    This document establishes the U. S. Department of Energy, National Nuclear Security Administration Nevada Site Office (NNSA/NSO) waste acceptance criteria (WAC). The WAC provides the requirements, terms, and conditions under which the Nevada Test Site will accept low-level radioactive and mixed waste for disposal. Mixed waste generated within the State of Nevada by NNSA/NSO activities is accepted for disposal. It includes requirements for the generator waste certification program, characterization, traceability, waste form, packaging, and transfer. The criteria apply to radioactive waste received at the Nevada Test Site Area 3 and Area 5 Radioactive Waste Management Site for storage or disposal.

  9. Waste Encapsulation and Storage Facility (WESF) Basis for Interim Operation (BIO)

    SciTech Connect (OSTI)

    COVEY, L.I.

    2000-11-28

    The Waste Encapsulation and Storage Facility (WESF) is located in the 200 East Area adjacent to B Plant on the Hanford Site north of Richland, Washington. The current WESF mission is to receive and store the cesium and strontium capsules that were manufactured at WESF in a safe manner and in compliance with all applicable rules and regulations. The scope of WESF operations is currently limited to receipt, inspection, decontamination, storage, and surveillance of capsules in addition to facility maintenance activities. The capsules are expected to be stored at WESF until the year 2017, at which time they will have been transferred for ultimate disposition. The WESF facility was designed and constructed to process, encapsulate, and store the extracted long-lived radionuclides, {sup 90}Sr and {sup 137}Cs, from wastes generated during the chemical processing of defense fuel on the Hanford Site thus ensuring isolation of hazardous radioisotopes from the environment. The construction of WESF started in 1971 and was completed in 1973. Some of the {sup 137}Cs capsules were leased by private irradiators or transferred to other programs. All leased capsules have been returned to WESF. Capsules transferred to other programs will not be returned except for the seven powder and pellet Type W overpacks already stored at WESF.

  10. Quantities and characteristics of the contact-handled low-level mixed waste streams for the DOE complex

    SciTech Connect (OSTI)

    Huebner, T.L.; Wilson, J.M.; Ruhter, A.H.; Bonney, S.J.

    1994-08-01

    This report supports the Integrated Thermal Treatment System (ITTS) Study initiated by the Department of Energy (DOE) Office of Technology Development (EM-50), which is a system engineering assessment of a variety of mixed waste treatment process. The DOE generates and stores large quantities of mixed wastes that are contaminated with both chemically hazardous and radioactive species. The treatment of these mixed wastes requires meeting the standards established by the Environmental Protection Agency for the specific hazardous contaminants regulated under the Resource Conservation and Recovery Act while also providing adequate control of the radionuclides. The thrust of the study is to develop preconceptual designs and life-cycle cost estimates for integrated thermal treatment systems ranging from conventional incinerators, such as rotary kiln and controlled air systems, to more innovative but not yet established technologies, such as molten salt and molten metal waste destruction systems. Prior to this engineering activity, the physical and chemical characteristics of the DOE low-level mixed waste streams to be treated must be defined or estimated. This report describes efforts to estimate the DOE waste stream characteristics.

  11. Design considerations for the cross jet air mixing in the municipal solid waste incinerators

    SciTech Connect (OSTI)

    Ryu, C.K.; Choi, S.

    1995-12-31

    In the mass-burning municipal solid waste incinerators, overfire air injection plays a key role in the improvement of mixing and reaction between oxygen and incomplete combustion products and/or pollutants. However, design parameters of overfire air nozzles are not well understood and sometimes confusing. In this paper, major design parameters of the cross jet air nozzles are discussed along with flow simulation results for the simplified furnace geometry. The overall performance of the jet air mixing and the effects of design parameters are quantitatively evaluated. The flow simulation results are interpreted in terms of the penetration depth of the jet into the main flow, the size of the recirculation zone and the ratio of the unmixed portion of the gas flow. The momentum flux ratio(J) of the jet to the cross flow strongly affects the penetration depth of the jet and the mixing of two flow streams. As the inter-nozzle distance (S in non-dimensional form) decreases, the penetration depth decreases but the size of recirculation zone increases and the resultant mixing deteriorates. The degree of mixing of the jet with the cross gas stream is evaluated in terms of the mass-averaged probability distribution of the relative concentration. Fresh air disperses more efficiently into the gas stream as J and S increase. The momentum flux ratio and the inter-nozzle distance are considered as important design parameters, and optimum values of these variables can be chosen for the given furnace conditions. This numerical evaluation also provides the basis of the similarity consideration for the cold flow model tests and the validity of the 2-dimensional idealization.

  12. Superconducting Open-Gradient Magnetic Separation for the Pretreatment of Radioactive or Mixed Waste Vitrification Feeds

    SciTech Connect (OSTI)

    Nunez', L.; Kaminsky', M.D.,; Crawford, C.; Ritter, J.A.

    1999-12-31

    An open-gradient magnetic separation (OGMS) process is being considered to separate deleterious elements from radioactive and mixed waste streams prior to vitrification or stabilization. By physically segregating solid wastes and slurries based on the magnetic properties of the solid constituents, this potentially low-cost process may serve the U.S. Department of Energy (DOE) by reducing the large quantities of glass produced from defense-related high-level waste (HLW). Furthermore, the separation of deleterious elements from low-level waste (LLW) also can reduce the total quantity of waste produced in LLW immobilization activities. Many HLW 'and LLW waste' streams at both Hanford and the Savannah River Site (SRS) include constituents deleterious to the durability of borosilicate glass and the melter many of the constituents also possess paramagnetism. For example, Fe, Cr, Ni, and other transition metals may limit the waste loading and affect the durability of the glass by forming spine1 phases at the high operating temperature used in vitrification. Some magnetic spine1 phases observed in glass formation are magnetite (Fe,O,), chromite (FeCrO,), and others [(Fe, Ni, Mg, Zn, Mn)(Al, Fe, Ti, Cr)O,] as described elsewhere [Bates-1994, Wronkiewicz-1994] Stable spine1 phases can cause segregation between the glass and the crystalline phases. As a consequence of the difference in density, the spine1 phases tend to accumulate at the bottom of the glass melter, which decreases the conductivity and melter lifetime [Sproull-1993]. Crystallization also can affect glass durability [Jantzen-1985, Turcotte- 1979, Buechele-1990] by changing the chemical composition of the matrix glass surrounding the crystals or causing stress at the glass/crystal interface. These are some of the effects that can increase leaching [Jantzen-1985]. A SRS glass that was partially crystallized to contain 10% vol. crystals composed of spinels, nepheline, and acmite phases showed minimal changes in

  13. Successful Opening and Disposal to-Date of Mixed CERCLA Waste at the ORR-EMWMF

    SciTech Connect (OSTI)

    Corpstein, P.; Hopper, P.; McNutt, R.

    2003-02-25

    On May 28, 2002, the Environmental Management Waste Management Facility (EMWMF) opened for operations on the Department of Energy's Oak Ridge Reservation (ORR). The EMWMF is the centerpiece in the DOE's strategy for ORR environmental cleanup. The 8+ year planned project is an on-site engineered landfill, which is accepting for disposal radioactive, hazardous, toxic and mixed wastes generated by remedial action subcontractors. The opening of the EMWMF on May 28, 2002 marked the culmination of a long development process that began in mid-1980. In late 1999 the Record of Decision was signed and a full year of design for the initial 400, 000-yd3 disposal cell began. In early 2000 Duratek Federal Services, Inc. (Federal Services) began construction. Since then, Federal Services and Bechtel Jacobs Company, LLC (BJC) have worked cooperatively to complete a required DOE readiness evaluation, develop all the Safety Authorization Basis Documentation (ASA's, SER, and UCD's) and prepare procedures and work controlling documents required to safely accept waste. This paper explains the intricacies and economics of designing and constructing the facility.

  14. Development of a treatability variance guidance document for US DOE mixed-waste streams

    SciTech Connect (OSTI)

    Scheuer, N.; Spikula, R. ); Harms, T. . Environmental Guidance Div.); Triplett, M.B. )

    1990-03-01

    In response to the US Department of Energy's (DOE's) anticipated need for variances from the Resource Conservation and Recovery Act (RCRA) Land Disposal Restrictions (LDRs), a treatability variance guidance document was prepared. The guidance manual is for use by DOE facilities and operations offices. The manual was prepared as a part of an ongoing effort by DOE-EH to provide guidance for the operations offices and facilities to comply with the RCRA (LDRs). A treatability variance is an alternative treatment standard granted by EPA for a restricted waste. Such a variance is not an exemption from the requirements of the LDRs, but rather is an alternative treatment standard that must be met before land disposal. The manual, Guidance For Obtaining Variance From the Treatment Standards of the RCRA Land Disposal Restrictions (1), leads the reader through the process of evaluating whether a variance from the treatment standard is a viable approach and through the data-gathering and data-evaluation processes required to develop a petition requesting a variance. The DOE review and coordination process is also described and model language for use in petitions for DOE radioactive mixed waste (RMW) is provided. The guidance manual focuses on RMW streams, however the manual also is applicable to nonmixed, hazardous waste streams. 4 refs.

  15. Conceptual Evaluation for the Installation of Treatment Capability for Mixed Low Level Waste at the Nevada National Security Site

    SciTech Connect (OSTI)

    NSTec Environmental Management

    2010-11-24

    National Security Technologies, LLC, initiated an evaluation of treatment technologies that they would manage and operate as part of the mixed low-level waste (MLLW) disposal facilities at the Nevada National Security Site (NNSS). The NNSS Disposal Facility has been receiving radioactive waste from the U.S. Department of Energy (DOE) complex since the 1960s, and since 2005 the NNSS Disposal Facility has been receiving radioactive and MLLW for disposal only. In accordance with the Resource Conservation and Recovery Act (RCRA), all mixed waste must meet land disposal restrictions (LDRs) prior to disposal. Compliance with LDRs is attained through treatment of the waste to mitigate the characteristics of the listed waste hazard. Presently, most generators utilize commercial capacity for waste treatment prior to shipment to the NNSS Disposal Facility. The objectives of this evaluation are to provide a conceptual study of waste treatment needs (i.e., demand), identify potential waste treatment technologies to meet demand, and analyze implementation considerations for initiating MLLW treatment capacity at the NNSS Disposal Facility. A review of DOE complex waste generation forecast data indicates that current and future Departmental demand for mixed waste treatment capacity will remain steady and strong. Analysis and screening of over 30 treatment technologies narrowed the field of treatment technologies to four: • Macroencapsulation • Stabilization/microencapsulation • Sort and segregation • Bench-scale mercury amalgamation The analysis of treatment technologies also considered existing permits, current the NNSS Disposal Facility infrastructure such as utilities and procedures, and past experiences such as green-light and red-light lessons learned. A schedule duration estimate has been developed for permitting, design, and construction of onsite treatment capability at the NNSS Disposal Facility. Treatment capability can be ready in 20 months.

  16. The National Nuclear Laboratory's Approach to Processing Mixed Wastes and Residues - 13080

    SciTech Connect (OSTI)

    Greenwood, Howard; Docrat, Tahera; Allinson, Sarah J.; Coppersthwaite, Duncan P.; Sultan, Ruqayyah; May, Sarah

    2013-07-01

    The National Nuclear Laboratory (NNL) treats a wide variety of materials produced as by-products of the nuclear fuel cycle, mostly from uranium purification and fuel manufacture but also including materials from uranium enrichment and from the decommissioning of obsolete plants. In the context of this paper, treatment is defined as recovery of uranium or other activity from residues, the recycle of uranium to the fuel cycle or preparation for long term storage and the final disposal or discharge to the environment of the remainder of the material. NNL's systematic but flexible approach to residue assessment and treatment is described in this paper. The approach typically comprises up to five main phases. The benefits of a systematic approach to waste and residue assessments and processing are described in this paper with examples used to illustrate each phase of work. Benefits include early identification of processing routes or processing issues and the avoidance of investment in inappropriate and costly plant or processes. (authors)

  17. Novel room-temperature-setting phosphate ceramics for stabilizing combustion products and low-level mixed wastes

    SciTech Connect (OSTI)

    Wagh, A.S.; Singh, D.

    1994-12-31

    Argonne National Laboratory, with support from the Office of Technology in the US Department of Energy (DOE), has developed a new process employing novel, chemically bonded ceramic materials to stabilize secondary waste streams. Such waste streams result from the thermal processes used to stabilize low-level, mixed wastes. The process will help the electric power industry treat its combustion and low-level mixed wastes. The ceramic materials are strong, dense, leach-resistant, and inexpensive to fabricate. The room-temperature-setting process allows stabilization of volatile components containing lead, mercury, cadmium, chromium, and nickel. The process also provides effective stabilization of fossil fuel combustion products. It is most suitable for treating fly and bottom ashes.

  18. Preliminary siting criteria for the proposed mixed and low-level waste treatment facility at the Idaho National Engineering Laboratory

    SciTech Connect (OSTI)

    Jorgenson-Waters, M.

    1992-09-01

    The Mixed and Low-Level Waste Treatment Facility project was established in 1991 by the US Department of Energy Idaho Field Office. This facility will provide treatment capabilities for Idaho National Engineering Laboratory (INEL) low-level mixed waste and low-level waste. This report identifies the siting requirements imposed on facilities that treat and store these waste types by Federal and State regulatory agencies and the US Department of Energy. Site selection criteria based on cost, environmental, health and safety, archeological, geological and service, and support requirements are presented. These criteria will be used to recommend alternative sites for the new facility. The National Environmental Policy Act process will then be invoked to evaluate the alternatives and the alternative sites and make a final site determination.

  19. The composition, heating value and renewable share of the energy content of mixed municipal solid waste in Finland

    SciTech Connect (OSTI)

    Horttanainen, M. Teirasvuo, N.; Kapustina, V.; Hupponen, M.; Luoranen, M.

    2013-12-15

    Highlights: • New experimental data of mixed MSW properties in a Finnish case region. • The share of renewable energy of mixed MSW. • The results were compared with earlier international studies. • The average share of renewable energy was 30% and the average LHVar 19 MJ/kg. • Well operating source separation decreases the renewable energy content of MSW. - Abstract: For the estimation of greenhouse gas emissions from waste incineration it is essential to know the share of the renewable energy content of the combusted waste. The composition and heating value information is generally available, but the renewable energy share or heating values of different fractions of waste have rarely been determined. In this study, data from Finnish studies concerning the composition and energy content of mixed MSW were collected, new experimental data on the compositions, heating values and renewable share of energy were presented and the results were compared to the estimations concluded from earlier international studies. In the town of Lappeenranta in south-eastern Finland, the share of renewable energy ranged between 25% and 34% in the energy content tests implemented for two sample trucks. The heating values of the waste and fractions of plastic waste were high in the samples compared to the earlier studies in Finland. These high values were caused by good source separation and led to a low share of renewable energy content in the waste. The results showed that in mixed municipal solid waste the renewable share of the energy content can be significantly lower than the general assumptions (50–60%) when the source separation of organic waste, paper and cardboard is carried out successfully. The number of samples was however small for making extensive conclusions on the results concerning the heating values and renewable share of energy and additional research is needed for this purpose.

  20. Study of the VOC emissions from a municipal solid waste storage pilot-scale cell: Comparison with biogases from municipal waste landfill site

    SciTech Connect (OSTI)

    Chiriac, R.; De Araujos Morais, J.; Carre, J.; Bayard, R.; Chovelon, J.M.; Gourdon, R.

    2011-11-15

    Highlights: > Follow-up of the emission of VOCs in a municipal waste pilot-scale cell during the acidogenesis and acetogenesis phases. > Study from the very start of waste storage leading to a better understanding of the decomposition/degradation of waste. > Comparison of the results obtained on the pilot-scale cell with those from 3 biogases coming from the same landfill site. > A methodology of characterization for the progression of the stabilization/maturation of waste is finally proposed. - Abstract: The emission of volatile organic compounds (VOCs) from municipal solid waste stored in a pilot-scale cell containing 6.4 tonnes of waste (storage facility which is left open during the first period (40 days) and then closed with recirculation of leachates during a second period (100 days)) was followed by dynamic sampling on activated carbon and analysed by GC-MS after solvent extraction. This was done in order to know the VOC emissions before the installation of a methanogenesis process for the entire waste mass. The results, expressed in reference to toluene, were exploited during the whole study on all the analyzable VOCs: alcohols, ketones and esters, alkanes, benzenic and cyclic compounds, chlorinated compounds, terpene, and organic sulphides. The results of this study on the pilot-scale cell are then compared with those concerning three biogases from a municipal waste landfill: biogas (1) coming from waste cells being filled or recently closed, biogas (2) from all the waste storage cells on site, and biogas (3) which is a residual gas from old storage cells without aspiration of the gas. The analysis of the results obtained revealed: (i) a high emission of VOCs, principally alcohols, ketones and esters during the acidogenesis; (ii) a decrease in the alkane content and an increase in the terpene content were observed in the VOCs emitted during the production of methane; (iii) the production of heavier alkanes and an increase in the average number of carbon

  1. Application to ship nonmixed transuranic waste to the Nevada Test Site for interim storage. Waste Cerification Program

    SciTech Connect (OSTI)

    Not Available

    1993-12-01

    This report documents various regulations on radioactive waste processing and discusses how the Waste Isolation Pilot Plant will comply with and meet these requirements. Specific procedures are discussed concerning transuranic, metal scrap, salt block, solid, and glove box wastes.

  2. Engineering evaluation of alternatives for the disposition of Niagara Falls Storage Site, its residues and wastes

    SciTech Connect (OSTI)

    Not Available

    1984-01-01

    The final disposition scenarios selected by DOE for assessment in this document are consistent with those stated in the Notice of Intent to prepare an Environmental Impact Statement (EIS) for the Niagara Falls Storage Site (NFSS) (DOE, 1983d) and the modifications to the alternatives resulting from the public scoping process. The scenarios are: take no action beyond interim remedial measures other than maintenance and surveillance of the NFSS; retain and manage the NFSS as a long-term waste management facility for the wastes and residues on the site; decontaminate, certify, and release the NFSS for other use, with long-term management of the wastes and residues at other DOE sites; and partially decontaminate the NFSS by removal and transport off site of only the more radioactive residues, and upgrade containment of the remaining wastes and residues on site. The objective of this document is to present to DOE the conceptual engineering, occupational radiation exposure, construction schedule, maintenance and surveillance requirements, and cost information relevant to design and implementation of each of the four scenarios. The specific alternatives within each scenario used as the basis for discussion in this document were evaluated on the bases of engineering considerations, technical feasibility, and regulatory requirements. Selected alternatives determined to be acceptable for each of the four final disposition scenarios for the NFSS were approved by DOE to be assessed and costed in this document. These alternatives are also the subject of the EIS for the NFSS currently being prepared by Argonne National Laboratory (ANL). 40 figures, 38 tables.

  3. Mixed and Low-Level Waste Treatment Facility project. Appendix A, Environmental and regulatory planning and documentation: Draft

    SciTech Connect (OSTI)

    Not Available

    1992-04-01

    Mixed and low-level wastes generated at the Idaho National Engineering Laboratory (INEL) are required to be managed according to applicable State and Federal regulations, and Department of Energy Orders that provide for the protection of human health and the environment. The Mixed and Low-Level Waste Treatment Facility Project was chartered in 1991, by the Department of Energy to provide treatment capability for these mixed and low-level waste streams. The first project task consisted of conducting engineering studies to identify the waste streams, their potential treatment strategies, and the requirements that would be imposed on the waste streams and the facilities used to process them. This report, Appendix A, Environmental & Regulatory Planning & Documentation, identifies the regulatory requirements that would be imposed on the operation or construction of a facility designed to process the INEL`s waste streams. These requirements are contained in five reports that discuss the following topics: (1) an environmental compliance plan and schedule, (2) National Environmental Policy Act requirements, (3) preliminary siting requirements, (4) regulatory justification for the project, and (5) health and safety criteria.

  4. Update Direct-Strike Lightning Environment for Stockpile-to-Target Sequence: Supplement LLNL Subcontract #B568621 Lightning Protection at the Yucca Mountain Waste Storage Facility

    SciTech Connect (OSTI)

    Uman, M A

    2008-10-09

    The University of Florida has surveyed all relevant publications reporting lightning damage to metals, metals which could be used as components of storage containers for nuclear waste materials. We show that even the most severe lightning could not penetrate the stainless steel thicknesses proposed for nuclear waste storage casks.

  5. Development of a trial burn plan for a mixed waste fluidized bed incinerator

    SciTech Connect (OSTI)

    Kabot, F.J.; Ziegler, D.L.

    1988-01-01

    One of the more important elements of the incinerator permitting process under RCRA is the development of the Trial Burn Plan. This document describes the incinerator and defines the incinerator's process envelope within which the trial burns will be conducted. The data obtained during the trial burns will be the basis for the incinerator's operating permit. This paper describes the development of the Trial Burn Plan for a unique fluidized bed incinerator to be used for the incineration of hazardous and mixed wastes at the Department of Energy's Rocky Flats Plant. It describes a review process of the Trial Burn Plan involving a public comment period that actually preceded the trial burns. 2 refs., 1 fig.

  6. Probabilistic performance-assessment modeling of the mixed waste landfill at Sandia National Laboratories.

    SciTech Connect (OSTI)

    Peace, Gerald L.; Goering, Timothy James; Miller, Mark Laverne; Ho, Clifford Kuofei

    2007-01-01

    A probabilistic performance assessment has been conducted to evaluate the fate and transport of radionuclides (americium-241, cesium-137, cobalt-60, plutonium-238, plutonium-239, radium-226, radon-222, strontium-90, thorium-232, tritium, uranium-238), heavy metals (lead and cadmium), and volatile organic compounds (VOCs) at the Mixed Waste Landfill (MWL). Probabilistic analyses were performed to quantify uncertainties inherent in the system and models for a 1,000-year period, and sensitivity analyses were performed to identify parameters and processes that were most important to the simulated performance metrics. Comparisons between simulated results and measured values at the MWL were made to gain confidence in the models and perform calibrations when data were available. In addition, long-term monitoring requirements and triggers were recommended based on the results of the quantified uncertainty and sensitivity analyses.

  7. Disposal of low-level and mixed low-level radioactive waste during 1990

    SciTech Connect (OSTI)

    Not Available

    1993-08-01

    Isotopic inventories and other data are presented for low-level radioactive waste (LLW) and mixed LLW disposed (and occasionally stored) during calendar year 1990 at commercial disposal facilities and Department of Energy (DOE) sites. Detailed isotopic information is presented for the three commercial disposal facilities located near Barnwell, SC, Richland, WA, and Beatty, NV. Less information is presented for the Envirocare disposal facility located near Clive, UT, and for LLW stored during 1990 at the West Valley site. DOE disposal information is included for the Savannah River Site (including the saltstone facility), Nevada Test Site, Los Alamos National Laboratory, Idaho National Engineering Laboratory, Hanford Site, Y-12 Site, and Oak Ridge National Laboratory. Summary information is presented about stored DOE LLW. Suggestions are made about improving LLW disposal data.

  8. Mixed waste management facility groundwater monitoring report. Fourth quarter 1995 and 1995 summary

    SciTech Connect (OSTI)

    1996-03-01

    During fourth quarter 1995, seven constituents exceeded final Primary Drinking Water Standards (PDWS) in groundwater samples from downgradient monitoring wells at the Mixed Waste Management Facility. No constituents exceeded final PDWS in samples from the upgradient monitoring wells. As in previous quarters, tritium and trichloroethylene were the most widespread elevated constituents. Chloroethene, gross alpha, lead, mercury, and tetrachloroethylene also exceeded final PDWS in one or more wells. Elevated constituents were found in numerous Aquifer Zone IIB{sub 2} (Water Table) and Aquifer Zone IIB{sub 1} (Barnwell/McBean) wells and in three Aquifer Unit IIA (Congaree) wells. The groundwater flow directions and rates in the three hydrostratigraphic units were similar to those of previous quarters.

  9. Testing cleanable/reuseable HEPA prefilters for mixed waste incinerator air pollution control systems

    SciTech Connect (OSTI)

    Burns, D.B.; Wong, A.; Walker, B.W.; Paul, J.D.

    1997-08-01

    The Consolidated Incineration Facility (CIF) at the US DOE Savannah River Site is undergoing preoperational testing. The CIF is designed to treat solid and liquid RCRA hazardous and mixed wastes from site operations and clean-up activities. The technologies selected for use in the air pollution control system (APCS) were based on reviews of existing incinerators, air pollution control experience, and recommendations from consultants. This approach resulted in a facility design using experience from other operating hazardous/radioactive incinerators. In order to study the CIF APCS prior to operation, a 1/10 scale pilot facility, the Offgas Components Test Facility (OCTF), was constructed and has been in operation since late 1994. Its mission is to demonstrate the design integrity of the CIF APCS and optimize equipment/instrument performance of the full scale production facility. Operation of the pilot facility has provided long-term performance data of integrated systems and critical facility components. This has reduced facility startup problems and helped ensure compliance with facility performance requirements. Technical support programs assist in assuring all stakeholders the CIF can properly treat combustible hazardous, mixed, and low-level radioactive wastes. High Efficiency Particulate Air (HEPA) filters are used to remove hazardous and radioactive particulates from the exhaust gas strewn before being released into the atmosphere. The HEPA filter change-out frequency has been a potential issue and was the first technical issue to be studied at the OCTF. Tests were conducted to evaluate the performance of HEPA filters under different operating conditions. These tests included evaluating the impact on HEPA life of scrubber operating parameters and the type of HEPA prefilter used. This pilot-scale testing demonstrated satisfactory HEPA filter life when using cleanable metal prefilters and high flows of steam and water in the offgas scrubber. 8 figs., 2 tabs.

  10. Guidelines for development of structural integrity programs for DOE high-level waste storage tanks

    SciTech Connect (OSTI)

    Bandyopadhyay, K.; Bush, S.; Kassir, M.; Mather, B.; Shewmon, P.; Streicher, M.; Thompson, B.; Rooyen, D. van; Weeks, J.

    1997-01-01

    Guidelines are provided for developing programs to promote the structural integrity of high-level waste storage tanks and transfer lines at the facilities of the Department of Energy. Elements of the program plan include a leak-detection system, definition of appropriate loads, collection of data for possible material and geometric changes, assessment of the tank structure, and non-destructive examination. Possible aging degradation mechanisms are explored for both steel and concrete components of the tanks, and evaluated to screen out nonsignificant aging mechanisms and to indicate methods of controlling the significant aging mechanisms. Specific guidelines for assessing structural adequacy will be provided in companion documents. Site-specific structural integrity programs can be developed drawing on the relevant portions of the material in this document.

  11. Fractured rock modeling in the National Waste Terminal Storage Program: a review of requirements and status

    SciTech Connect (OSTI)

    St. John, C.; Krug, A.; Key, S.; Monsees, J.

    1983-05-01

    Generalized computer codes capable of forming the basis for numerical models of fractured rock masses are being used within the NWTS program. Little additional development of these codes is considered justifiable, except in the area of representation of discrete fractures. On the other hand, model preparation requires definition of medium-specific constitutive descriptions and site characteristics and is therefore legitimately conducted by each of the media-oriented projects within the National Waste Terminal Storage program. However, it is essential that a uniform approach to the role of numerical modeling be adopted, including agreement upon the contribution of modeling to the design and licensing process and the need for, and means of, model qualification for particular purposes. This report discusses the role of numerical modeling, reviews the capabilities of several computer codes that are being used to support design or performance assessment, and proposes a framework for future numerical modeling activities within the NWTS program.

  12. Radioactive Solid Waste Storage and Disposal at Oak Ridge National Laboratory, Description and Safety Analysis

    SciTech Connect (OSTI)

    Bates, L.D.

    2001-01-30

    Oak Ridge National Laboratory (ORNL) is a principle Department of Energy (DOE) Research Institution operated by the Union Carbide Corporation - Nuclear Division (UCC-ND) under direction of the DOE Oak Ridge Operations Office (DOE-ORO). The Laboratory was established in east Tennessee, near what is now the city of Oak Ridge, in the mid 1940s as a part of the World War II effort to develop a nuclear weapon. Since its inception, disposal of radioactively contaminated materials, both solid and liquid, has been an integral part of Laboratory operations. The purpose of this document is to provide a detailed description of the ORNL Solid Waste Storage Areas, to describe the practice and procedure of their operation, and to address the health and safety impacts and concerns of that operation.

  13. Mixed and low-level waste treatment project: Appendix C, Health and safety criteria for the mixed and low-level waste treatment facility at the Idaho National Engineering Laboratory

    SciTech Connect (OSTI)

    Neupauer, R.M.; Thurmond, S.M.

    1992-09-01

    This report describes health and safety concerns associated with the Mixed and Low-level Waste Treatment Facility at the Idaho National Engineering Laboratory. Various hazards are described such as fire, electrical, explosions, reactivity, temperature, and radiation hazards, as well as the potential for accidental spills, exposure to toxic materials, and other general safety concerns.

  14. Analysis of the suitability of DOE facilities for treatment of commercial low-level radioactive mixed waste

    SciTech Connect (OSTI)

    1996-02-01

    This report evaluates the capabilities of the United States Department of Energy`s (DOE`s) existing and proposed facilities to treat 52 commercially generated low-level radioactive mixed (LLMW) waste streams that were previously identified as being difficult-to-treat using commercial treatment capabilities. The evaluation was performed by comparing the waste matrix and hazardous waste codes for the commercial LLMW streams with the waste acceptance criteria of the treatment facilities, as identified in the following DOE databases: Mixed Waste Inventory Report, Site Treatment Plan, and Waste Stream and Technology Data System. DOE facility personnel also reviewed the list of 52 commercially generated LLMW streams and provided their opinion on whether the wastes were technically acceptable at their facilities, setting aside possible administrative barriers. The evaluation tentatively concludes that the DOE is likely to have at least one treatment facility (either existing or planned) that is technically compatible for most of these difficult-to-treat commercially generated LLMW streams. This conclusion is tempered, however, by the limited amount of data available on the commercially generated LLMW streams, by the preliminary stage of planning for some of the proposed DOE treatment facilities, and by the need to comply with environmental statutes such as the Clean Air Act.

  15. Pyrolysis and hydrolysis of mixed polymer waste comprising polyethyleneterephthalate and polyethylene to sequentially recover

    DOE Patents [OSTI]

    Evans, Robert J.; Chum, Helena L.

    1998-01-01

    A process of using fast pyrolysis in a carrier gas to convert a plastic waste feedstream having a mixed polymeric composition in a manner such that pyrolysis of a given polymer to its high value monomeric constituent occurs prior to pyrolysis of other plastic components therein comprising: selecting a first temperature program range to cause pyrolysis of said given polymer to its high value monomeric constituent prior to a temperature range that causes pyrolysis of other plastic components; selecting a catalyst and support for treating said feed streams with said catalyst to effect acid or base catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent in said temperature program range; differentially heating said feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of the high value monomeric constituent prior to pyrolysis of other plastic components; separating the high value monomeric constituents; selecting a second higher temperature range to cause pyrolysis of a different high value monomeric constituent of said plastic waste and differentially heating the feedstream at the higher temperature program range to cause pyrolysis of the different high value monomeric constituent; and separating the different high value monomeric constituent.

  16. Functional Stability Of A Mixed Microbial Consortia Producing PHA From Waste Carbon Sources

    SciTech Connect (OSTI)

    David N. Thompson; Erik R. Coats; William A. Smith; Frank J. Loge; Michael P. Wolcott

    2006-04-01

    Polyhydroxyalkanoates (PHAs), naturally-occurring biological polyesters that are microbially synthesized from a myriad of carbon sources, can be utilized as biodegradable substitutes for petroleum-derived thermoplastics. However, current PHA commercialization schemes are limited by high feedstock costs, the requirement for aseptic reactors, and high separation and purification costs. Bacteria indigenous to municipal waste streams can accumulate large quantities of PHA under environmentally controlled conditions; hence, a potentially more environmentally-effective method of production would utilize these consortia to produce PHAs from inexpensive waste carbon sources. In this study, PHA production was accomplished in sequencing batch bioreactors utilizing mixed microbial consortia from municipal activated sludge as inoculum, in cultures grown on real wastewaters. PHA production averaged 85%, 53%, and 10% of the cell dry weight from methanol-enriched pulp-and-paper mill foul condensate, fermented municipal primary solids, and biodiesel wastewater, respectively. The PHA-producing microbial consortia were examined to explore the microbial community changes that occurred during reactor operations, employing denaturing gradient gel electrophoresis (DGGE) of 16S-rDNA from PCR-amplified DNA extracts. Distinctly different communities were observed both between and within wastewaters following enrichment. More importantly, stable functions were maintained despite the differing and contrasting microbial populations.

  17. Investigation of Flammable Gas Releases from High Level Waste Tanks during Periodic Mixing

    SciTech Connect (OSTI)

    Swingle, R.F.

    1999-01-07

    The Savannah River Site processes high-level radioactive waste through precipitation by the addition of sodium tetraphenylborate in a large (approximately 1.3 million gallon) High Level Waste Tank. Radiolysis of water produces a significant amount of hydrogen gas in this slurry. During quiescent periods the tetraphenylborate slurry retains large amounts of hydrogen as dissolved gas and small bubbles. When mixing pumps start, large amounts of hydrogen release due to agitation of the slurry. Flammability concerns necessitate an understanding of the hydrogen retention mechanism in the slurry and a model of how the hydrogen releases from the slurry during pump operation. Hydrogen concentration data collected from the slurry tank confirmed this behavior in the full-scale system. These measurements also provide mass transfer results for the hydrogen release during operation. The authors compared these data to an existing literature model for mass transfer in small, agitated reactors and developed factors to scale this existing model to the 1.3 million gallon tanks in use at the Savannah River Site. The information provides guidance for facility operations.

  18. MERCURY REMOVAL FROM DOE SOLID MIXED WASTE USING THE GEMEP(sm) TECHNOLOGY

    SciTech Connect (OSTI)

    1999-03-01

    Under the sponsorship of the Federal Energy Technology Center (FETC), Metcalf and Eddy (M and E), in association with General Electric Corporate Research and Development Center (GE-CRD), Colorado Minerals Research Institute (CMRI), and Oak Ridge National Laboratory (ORNL), conducted laboratory-scale and bench-scale tests of the General Electric Mercury Extraction Process technology on two mercury-contaminated mixed solid wastes from U. S. Department of Energy sites: sediment from the East Fork of Poplar Creek, Oak Ridge (samples supplied by Oak Ridge National Laboratory), and drummed soils from Idaho National Environmental and Engineering Laboratory (INEEL). Fluorescent lamps provided by GE-CRD were also studied. The GEMEP technology, invented and patented by the General Electric Company, uses an extraction solution composed of aqueous potassium iodide plus iodine to remove mercury from soils and other wastes. The extraction solution is regenerated by chemical oxidation and reused, after the solubilized mercury is removed from solution by reducing it to the metallic state. The results of the laboratory- and bench-scale testing conducted for this project included: (1) GEMEP extraction tests to optimize extraction conditions and determine the extent of co-extraction of radionuclides; (2) pre-screening (pre-segregation) tests to determine if initial separation steps could be used effectively to reduce the volume of material needing GEMEP extraction; and (3) demonstration of the complete extraction, mercury recovery, and iodine recovery and regeneration process (known as locked-cycle testing).

  19. Treatment of DOE and commercial mixed waste by the private sector

    SciTech Connect (OSTI)

    Garrison, T.W.; Apel, M.L.; Owens, C.M.

    1993-03-01

    This paper presents a conceptual approach for private sector treatment of mixed low-level radioactive waste generated by the US Department of Energy and commercial industries. This approach focuses on MLLW treatment technologies and capacities available through the private sector in the near term. Wastestream characterization data for 108 MLLW streams at the Idaho National Engineering Laboratory (INEL) were collected and combined with similar data for MLLWs generated through commercial practices. These data were then provided to private treatment facilities and vendors to determine if, and to what extent, they could successfully treat these wastes. Data obtained from this project have provided an initial assessment of private sector capability and capacity to treat a variety of MLLW streams. This information will help formulate plans for future treatment of these and similar wastestreams at DOE facilities. This paper presents details of the MLLW data-gathering efforts used in this research, private sector assessment methods employed, and results of this assessment. Advantages of private sector treatment, as well as barriers to its present use, are also addressed.

  20. Two stage, low temperature, catalyzed fluidized bed incineration with in situ neutralization for radioactive mixed wastes

    SciTech Connect (OSTI)

    Wade, J.F.; Williams, P.M.

    1995-05-17

    A two stage, low temperature, catalyzed fluidized bed incineration process is proving successful at incinerating hazardous wastes containing nuclear material. The process operates at 550{degrees}C and 650{degrees}C in its two stages. Acid gas neutralization takes place in situ using sodium carbonate as a sorbent in the first stage bed. The feed material to the incinerator is hazardous waste-as defined by the Resource Conservation and Recovery Act-mixed with radioactive materials. The radioactive materials are plutonium, uranium, and americium that are byproducts of nuclear weapons production. Despite its low temperature operation, this system successfully destroyed poly-chlorinated biphenyls at a 99.99992% destruction and removal efficiency. Radionuclides and volatile heavy metals leave the fluidized beds and enter the air pollution control system in minimal amounts. Recently collected modeling and experimental data show the process minimizes dioxin and furan production. The report also discusses air pollution, ash solidification, and other data collected from pilot- and demonstration-scale testing. The testing took place at Rocky Flats Environmental Technology Site, a US Department of Energy facility, in the 1970s, 1980s, and 1990s.

  1. Guideline for benchmarking thermal treatment systems for low-level mixed waste

    SciTech Connect (OSTI)

    Hoffman, D.P.; Gibson, L.V. Jr.; Hermes, W.H.; Bastian, R.E.; Davis, W.T.

    1994-01-01

    A process for benchmarking low-level mixed waste (LLMW) treatment technologies has been developed. When used in conjunction with the identification and preparation of surrogate waste mixtures, and with defined quality assurance and quality control procedures, the benchmarking process will effectively streamline the selection of treatment technologies being considered by the US Department of Energy (DOE) for LLMW cleanup and management. Following the quantitative template provided in the benchmarking process will greatly increase the technical information available for the decision-making process. The additional technical information will remove a large part of the uncertainty in the selection of treatment technologies. It is anticipated that the use of the benchmarking process will minimize technology development costs and overall treatment costs. In addition, the benchmarking process will enhance development of the most promising LLMW treatment processes and aid in transferring the technology to the private sector. To instill inherent quality, the benchmarking process is based on defined criteria and a structured evaluation format, which are independent of any specific conventional treatment or emerging process technology. Five categories of benchmarking criteria have been developed for the evaluation: operation/design; personnel health and safety; economics; product quality; and environmental quality. This benchmarking document gives specific guidance on what information should be included and how it should be presented. A standard format for reporting is included in Appendix A and B of this document. Special considerations for LLMW are presented and included in each of the benchmarking categories.

  2. IDAHO SITE TO PROVIDE WASTE TREATMENT FOR OTHER DOE SITES

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    March 7, 2008 IDAHO SITE TO PROVIDE WASTE TREATMENT FOR OTHER DOE SITES Plan won't impact DOE commitment to removing all stored waste from Idaho Site Idaho's Advanced Mixed Waste Treatment Facility offers state of the art waste characterization, treatment and packaging capabilities. Click on image to enlarge The U.S. Department of Energy (DOE) is amending the Record of Decision for the Waste Management Program: Treatment and Storage of Transuranic Waste, originally issued in 1998. The amendment

  3. The mixed waste management facility. Project baseline revision 1.2

    SciTech Connect (OSTI)

    Streit, R.D.; Throop, A.L.

    1995-04-01

    Revision 1.2 to the Project Baseline (PB) for the Mixed Waste Management Facility (MWMF) is in response to DOE directives and verbal guidance to (1) Collocate the Decontamination and Waste Treatment Facility (DWTF) and MWMF into a single complex, integrate certain and overlapping functions as a cost-saving measure; (2) Meet certain fiscal year (FY) new-BA funding objectives ($15.3M in FY95) with lower and roughly balanced funding for out years; (3) Reduce Total Project Cost (TPC) for the MWMF Project; (4) Include costs for all appropriate permitting activities in the project TPC. This baseline revision also incorporates revisions in the technical baseline design for Molten Salt Oxidation (MSO) and Mediated Electrochemical Oxidation (MEO). Changes in the WBS dictionary that are necessary as a result of this rebaseline, as well as minor title changes, at WBS Level 3 or above (DOE control level) are approved as a separate document. For completeness, the WBS dictionary that reflects these changes is contained in Appendix B. The PB, with revisions as described in this document, were also the basis for the FY97 Validation Process, presented to DOE and their reviewers on March 21-22, 1995. Appendix C lists information related to prior revisions to the PB. Several key changes relate to the integration of functions and sharing of facilities between the portion of the DWTF that will house the MWMF and those portions that are used by the Hazardous Waste Management (HWM) Division at LLNL. This collocation has been directed by DOE as a cost-saving measure and has been implemented in a manner that maintains separate operational elements from a safety and permitting viewpoint. Appendix D provides background information on the decision and implications of collocating the two facilities.

  4. The Performance of Underground Radioactive Waste Storage Tanks at the Savannah River Site: A 60-Year Historical Perspective

    SciTech Connect (OSTI)

    Wiersma, Bruce J.

    2014-02-08

    The Savannah River Site produced weapons-grade materials for nearly 35 years between 1953 and 1988. The legacy of this production is nearly 37 million gallons of radioactive waste. Since the 1950s, the liquid waste has been stored in large, underground carbon steel waste tanks. During the past 20 years, the site has begun to process the waste so that it may be stored in vitrified and grout forms, which are more suitable for long-term storage. Over the history of the site, some tanks have experienced leakage of the waste to the secondary containment. This article is a review of the instances of leakage and corrosion degradation that the tanks and associated equipment have experienced since the first tanks were built. Furthermore, the activities that the site has taken to mitigate the degradation and manage the service life of the tank for its anticipated lifetime are reviewed.

  5. The Performance of Underground Radioactive Waste Storage Tanks at the Savannah River Site: A 60-Year Historical Perspective

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wiersma, Bruce J.

    2014-02-08

    The Savannah River Site produced weapons-grade materials for nearly 35 years between 1953 and 1988. The legacy of this production is nearly 37 million gallons of radioactive waste. Since the 1950s, the liquid waste has been stored in large, underground carbon steel waste tanks. During the past 20 years, the site has begun to process the waste so that it may be stored in vitrified and grout forms, which are more suitable for long-term storage. Over the history of the site, some tanks have experienced leakage of the waste to the secondary containment. This article is a review of themore » instances of leakage and corrosion degradation that the tanks and associated equipment have experienced since the first tanks were built. Furthermore, the activities that the site has taken to mitigate the degradation and manage the service life of the tank for its anticipated lifetime are reviewed.« less

  6. High-level waste storage tank farms/242-A evaporator Standards/Requirements Identification Document (S/RID), Volume 4

    SciTech Connect (OSTI)

    Not Available

    1994-04-01

    The High-Level Waste Storage Tank Farms/242-A Evaporator Standards/Requirements Identification Document (S/RID) is contained in multiple volumes. This document (Volume 4) presents the standards and requirements for the following sections: Radiation Protection and Operations.

  7. High-level waste storage tank farms/242-A evaporator Standards/Requirements Identification Document (S/RID), Volume 5

    SciTech Connect (OSTI)

    Not Available

    1994-04-01

    The High-Level Waste Storage Tank Farms/242-A Evaporator Standards/Requirements Identification Document (S/RID) is contained in multiple volumes. This document (Volume 5) outlines the standards and requirements for the Fire Protection and Packaging and Transportation sections.

  8. Submergible barge retrievable storage and permanent disposal system for radioactive waste

    DOE Patents [OSTI]

    Goldsberry, Fred L.; Cawley, William E.

    1981-01-01

    A submergible barge and process for submerging and storing radioactive waste material along a seabed. A submergible barge receives individual packages of radwaste within segregated cells. The cells are formed integrally within the barge, preferably surrounded by reinforced concrete. The cells are individually sealed by a concrete decking and by concrete hatch covers. Seawater may be vented into the cells for cooling, through an integral vent arrangement. The vent ducts may be attached to pumps when the barge is bouyant. The ducts are also arranged to promote passive ventilation of the cells when the barge is submerged. Packages of the radwaste are loaded into individual cells within the barge. The cells are then sealed and the barge is towed to the designated disposal-storage site. There, the individual cells are flooded and the barge will begin descent controlled by a powered submarine control device to the seabed storage site. The submerged barge will rest on the seabed permanently or until recovered by a submarine control device.

  9. Geochemical information for sites contaminated with low-level radioactive wastes: I. Niagara Falls Storage Site

    SciTech Connect (OSTI)

    Seeley, F.G.; Kelmers, A.D.

    1984-11-01

    The Niagara Falls Storage Site (NFSS) became radioactively contaminated as a result of wastes that were being stored from operations carried out to recover uranium from pitchblende ore in the 1940s and 1950s. The US Department of Energy (DOE) is considering various remedial action options for the NFSS. This report describes the results of geochemical investigations performed to help provide a quantitative evaluation of the effects of various options. NFSS soil and groundwater samples were characterized; and uranium and radium sorption ratios, as well as apparent concentration limit values, were measured in site soil/groundwater systems by employing batch contact methodology. The results suggest that any uranium which is in solution in the groundwater at the NFSS may be poorly retarded due to the low uranium sorption ratio values and high solubility measured. Further, appreciable concentrations of uranium in groundwater could be attained from soluble wastes. Release of uranium via groundwater migration could be a significant release pathway. Solubilized radium would be expected to be effectively retarded by soil at the NFSS as a result of the very high radium sorption ratios observed. The addition of iron oxyhydroxide to NFSS soils resulted in much higher uranium sorption ratios. Additional field testing of this potential remedial action additive could be desirable. 10 references.

  10. TWRS retrieval and disposal mission, immobilized high-level waste storage plan

    SciTech Connect (OSTI)

    Calmus, R.B.

    1998-01-07

    This project plan has a two fold purpose. First, it provides a plan specific to the Hanford Tank Waste Remediation System (TWRS) Immobilized High-Level Waste (EMW) Storage Subproject for the Washington State Department of Ecology (Ecology) that meets the requirements of Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement) milestone M-90-01 (Ecology et al. 1996) and is consistent with the project plan content guidelines found in Section 11.5 of the Tri-Party Agreement action plan. Second, it provides an upper tier document that can be used as the basis for future subproject line item construction management plans. The planning elements for the construction management plans are derived from applicable U.S. Department of Energy (DOE) planning guidance documents (DOE Orders 4700.1 (DOE 1992a) and 430.1 (DOE 1995)). The format and content of this project plan are designed to accommodate the plan`s dual purpose. A cross-check matrix is provided in Appendix A to explain where in the plan project planning elements required by Section 11.5 of the Tri-Party Agreement are addressed.

  11. May 16, 2016 Webinar- Predicting the Service Life of Geomembranes in Low-Level and Mixed-Waste Disposal Facilities

    Office of Energy Efficiency and Renewable Energy (EERE)

    Performance & RIsk Assessment (P&RA) Community of Practice (CoP) Webinar - May 16, 2016 - Predicting the Service Life of Geomembranes in Low-Level and Mixed-Waste Disposal Facilities: Findings from a Long-Term Study. Presented by Dr. Craig Benson (Dean of School of Engineering and Applied Science, and Janet Scott Hamilton and John Downman Hamilton Professor, Univ. of Virginia).

  12. Waste treatment process for removal of contaminants from aqueous, mixed-waste solutions using sequential chemical treatment and crossflow microfiltration, followed by dewatering

    DOE Patents [OSTI]

    Vijayan, S.; Wong, C.F.; Buckley, L.P.

    1994-11-22

    In processes of this invention aqueous waste solutions containing a variety of mixed waste contaminants are treated to remove the contaminants by a sequential addition of chemicals and adsorption/ion exchange powdered materials to remove the contaminants including lead, cadmium, uranium, cesium-137, strontium-85/90, trichloroethylene and benzene, and impurities including iron and calcium. Staged conditioning of the waste solution produces a polydisperse system of size enlarged complexes of the contaminants in three distinct configurations: water-soluble metal complexes, insoluble metal precipitation complexes, and contaminant-bearing particles of ion exchange and adsorbent materials. The volume of the waste is reduced by separation of the polydisperse system by cross-flow microfiltration, followed by low-temperature evaporation and/or filter pressing. The water produced as filtrate is discharged if it meets a specified target water quality, or else the filtrate is recycled until the target is achieved. 1 fig.

  13. Waste treatment process for removal of contaminants from aqueous, mixed-waste solutions using sequential chemical treatment and crossflow microfiltration, followed by dewatering

    DOE Patents [OSTI]

    Vijayan, Sivaraman; Wong, Chi F.; Buckley, Leo P.

    1994-01-01

    In processes of this invention aqueous waste solutions containing a variety of mixed waste contaminants are treated to remove the contaminants by a sequential addition of chemicals and adsorption/ion exchange powdered materials to remove the contaminants including lead, cadmium, uranium, cesium-137, strontium-85/90, trichloroethylene and benzene, and impurities including iron and calcium. Staged conditioning of the waste solution produces a polydisperse system of size enlarged complexes of the contaminants in three distinct configurations: water-soluble metal complexes, insoluble metal precipitation complexes, and contaminant-bearing particles of ion exchange and adsorbent materials. The volume of the waste is reduced by separation of the polydisperse system by cross-flow microfiltration, followed by low-temperature evaporation and/or filter pressing. The water produced as filtrate is discharged if it meets a specified target water quality, or else the filtrate is recycled until the target is achieved.

  14. Melton Valley liquid low-level radioactive waste storage tanks evaluation

    SciTech Connect (OSTI)

    1995-06-01

    The Melton Valley Liquid Low-Level Radioactive Waste Storage Tanks (MVSTs) store the evaporator concentrates from the Liquid Low-Level Radioactive Waste (LLLW) System at the Oak Ridge National Laboratory (ORNL). The eight stainless steel tanks contain approximately 375,000 gallons of liquid and sludge waste. These are some of the newer, better-designed tanks in the LLLW System. They have been evaluated and found by the US Environmental Protection Agency (EPA) and the Tennessee Department of Environment and Conservation to comply with all Federal Facility Agreement requirements for double containment. The operations and maintenance aspects of the tanks were also reviewed by the Defense Nuclear Facilities Safety Board (DNFSB) in September 1994. This document also contains an assessment of the risk to the public and ORNL workers from a leak in one of the MVSTs. Two primary scenarios were investigated: (1) exposure of the public to radiation from drinking Clinch River water contaminated by leaked LLLW, and (2) exposure of on-site workers to radiation by inhaling air contaminated by leaked LLLW. The estimated frequency of a leak from one of the MVSTs is about 8 {times} 10{sup {minus}4} events per year, or about once in 1200 years (with a 95% confidence level). If a leak were to occur, the dose to a worker from inhalation would be about 2.3 {times} 10{sup {minus}1} mrem (with a 95% confidence level). The dose to a member of the public through the drinking water pathway is estimated to be about 7 {times} 10{sup {minus}1} mrem (with a 95% confidence level). By comparison with EPA Safe Drinking Water regulations, the allowable lifetime radiation dose is about 300 mrem. Thus, a postulated LLLW leak from the MVSTs would not add appreciably to an individual`s lifetime radiation dose.

  15. Scoping evaluation of the technical capabilities of DOE sites for disposal of hazardous metals in mixed low-level waste

    SciTech Connect (OSTI)

    Gruebel, M.M.; Waters, R.D.; Langkopf, B.S.

    1997-05-01

    A team of analysts designed and conducted a scoping evaluation to estimate the technical capabilities of fifteen Department of Energy sites for disposal of the hazardous metals in mixed low-level waste (i.e., waste that contains both low-level radioactive materials and hazardous constituents). Eight hazardous metals were evaluated: arsenic, barium, cadmium, chromium, lead, mercury, selenium, and silver. The analysis considered transport only through the groundwater pathway. The results are reported as site-specific estimates of maximum concentrations of each hazardous metal in treated mixed low-level waste that do not exceed the performance measures established for the analysis. Also reported are site-specific estimates of travel times of each hazardous metal to the point of compliance.

  16. Mediated electrochemical oxidation treatment for Rocky Flats combustible low-level mixed waste. Final report, FY 1993 and 1994

    SciTech Connect (OSTI)

    Chiba, Z.; Lewis, P.R.; Murguia, L.C.

    1994-09-01

    Mediated Electrochemical Oxidation (MEO) is an aqueous process which destroys hazardous organics by oxidizing a mediator at the anode of an electrochemical cell; the mediator in turn oxidizes the organics within the bulk of the electrolyte. With this process organics can be nearly completely destroyed, that is, the carbon and hydrogen present in the hydrocarbon are almost entirely mineralized to carbon dioxide and water. The MEO process is also capable of dissolving radioactive materials, including difficult-to-dissolve compounds such as plutonium oxide. Hence, this process can treat mixed wastes, by destroying the hazardous organic components of the waste, and dissolving the radioactive components. The radioactive material can be recovered if desired, or disposed of as non-mixed radioactive waste. The process is inherently safe, since the hazardous and radioactive materials are completely contained in the aqueous phase, and the system operates at low temperatures (below 80{degree}C) and at ambient pressures.

  17. Microsoft Word - Transmittal of the Certification Audit Report for the Advanced Mixed Waste Treatment Program, Audit A-08-19.do

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    535:UFC 2300.00 Department of Energy Carlsbad Field Office P. O. Box 3090 Carlsbad, New Mexico 88221 November 25, 2008 Mr. Steve Zappe, Project Leader Hazardous Waste Bureau New Mexico Environment Department 2905 Rodeo Park Drive East, Building 1 Santa Fe, New Mexico 87505-6303 Subject: Transmittal of the Certification Audit Report for the Advanced Mixed Waste Treatment Program, Audit A-08-19 Dear Mr. Zappe: Enclosed is the Advanced Mixed Waste Treatment Program (AMWTP) Audit Report for the

  18. Groundwater quality assessment report for Solid Waste Storage Area 6 at Oak Ridge National Laboratory, Oak Ridge, Tennessee

    SciTech Connect (OSTI)

    1998-12-31

    Solid Waste Storage Area (SWSA) 6, located at the US Department of Energy (DOE) Oak Ridge National Laboratory (ORNL) facility, is a shallow land burial site for low-level radioactive waste (LLW) and other waste types. Wastes were disposed of in unlined trenches and auger holes from 1969 until May 1986, when it was determined that Resource Conservation and Recovery Act (RCRA) regulated wastes were being disposed of there. DOE closed SWSA 6 until changes in operating procedures prevented the disposal of RCRA wastes at SWSA 6. The site, which reopened for waste disposal activities in July 1986, is the only currently operated disposal area for low-level radioactive waste at ORNL. This report provides the results of the 1998 RCRA groundwater assessment monitoring. The monitoring was performed in accordance with the proposed routine monitoring plan recommended in the 1996 EMP. Section 2 provides pertinent background on SWSA 6. Section 3 presents the 1998 monitoring results and discusses the results in terms of any significant changes from previous monitoring efforts. Section 4 provides recommendations for changes in monitoring based on the 1998 results. References are provided in Section 5. Appendix A provides the 1998 RCRA Sampling Data and Appendix B provides a summary of 1998 Quality Assurance results.

  19. Application of EPA regulations to low-level radioactive waste

    SciTech Connect (OSTI)

    Bowerman, B.S.; Piciulo, P.L.

    1985-01-01

    The survey reported here was conducted with the intent of identifying categories of low-level radioactive wastes which would be classified under EPA regulations 40 CFR Part 261 as hazardous due to the chemical properties of the waste. Three waste types are identified under these criteria as potential radioactive mixed wastes: wastes containing organic liquids; wastes containing lead metal; and wastes containing chromium. The survey also indicated that certain wastes, specific to particular generators, may also be radioactive mixed wastes. Ultimately, the responsibility for determining whether a facility's wastes are mixed wastes rest with the generator. However, the uncertainties as to which regulations are applicable, and the fact that no legal definition of mixed wastes exists, make such a determination difficult. In addition to identifying mixed wastes, appropriate methods for the management of mixed wastes must be defined. In an ongoing study, BNL is evaluating options for the management of mixed wastes. These options will include segregation, substitution, and treatments to reduce or eliminate chemical hazards associated with the wastes listed above. The impacts of the EPA regulations governing hazardous wastes on radioactive mixed waste cannot be assessed in detail until the applicability of these regulations is agreed upon. This issue is still being discussed by EPA and NRC and should be resolved in the near future. Areas of waste management which may affect generators of mixed wastes include: monitoring/tracking of wastes before shipment; chemical testing of wastes; permits for treatment of storage of wastes; and additional packaging requirements. 3 refs., 1 fig., 2 tabs.

  20. REGIONAL BINNING FOR CONTINUED STORAGE OF SPENT NUCLEAR FUEL AND HIGH-LEVEL WASTES

    SciTech Connect (OSTI)

    W. Lee Poe, Jr

    1998-10-01

    In the Continued Storage Analysis Report (CSAR) (Reference 1), DOE decided to analyze the environmental consequences of continuing to store the commercial spent nuclear fuel (SNF) at 72 commercial nuclear power sites and DOE-owned spent nuclear fuel and high-level waste at five Department of Energy sites by region rather than by individual site. This analysis assumes that three commercial facilities pairs--Salem and Hope Creek, Fitzpatrick and Nine-Mile Point, and Dresden and Moms--share common storage due to their proximity to each other. The five regions selected for this analysis are shown on Figure 1. Regions 1, 2, and 3 are the same as those used by the Nuclear Regulatory Commission in their regulatory oversight of commercial power reactors. NRC Region 4 was subdivided into two regions to more appropriately define the two different climates that exist in NRC Region 4. A single hypothetical site in each region was assumed to store all the SNF and HLW in that region. Such a site does not exist and has no geographic location but is a mathematical construct for analytical purposes. To ensure that the calculated results for the regional analyses reflect appropriate inventory, facility and material degradation, and radionuclide transport, the waste inventories, engineered barriers, and environmental conditions for the hypothetical sites were developed from data for each of the existing sites within the given region. Weighting criteria to account for the amount and types of SNF and HLW at each site were used in the development of the environmental data for the regional site, such that the results of the analyses for the hypothetical site were representative of the sum of the results of each actual site if they had been modeled independently. This report defines the actual site data used in development of this hypothetical site, shows how the individual site data was weighted to develop the regional site, and provides the weighted data used in the CSAR analysis. It is

  1. Solidification Tests Conducted on Transuranic Mixed Oil Waste (TRUM) at the Rocky Flats Environmental Technology Site (RFETS)

    SciTech Connect (OSTI)

    Brunkow, W. G.; Campbell, D.; Geimer, R.; Gilbreath, C.; Rivera, M.

    2002-02-25

    Rocky Flats Environmental Technology Site (RFETS) near Golden, Colorado is the first major nuclear weapons site within the DOE complex that has been declared a full closure site. RFETS has been given the challenge of closing the site by 2006. Key to meeting this challenge is the removal of all waste from the site followed by site restoration. Crucial to meeting this challenge is Kaiser-Hill's (RFETS Operating Contractor) ability to dispose of significant quantities of ''orphan'' wastes. Orphan wastes are those with no current disposition for treatment or disposal. Once such waste stream, generically referred to as Transuranic oils, poses a significant threat to meeting the closure schedule. Historically, this waste stream, which consist of a variety of oil contaminated with a range of organic solvents were treated by simply mixing with Environstone. This treatment method rendered a solidified waste form, but unfortunately not a TRUPACT-II transportable waste. So for the last ten years, RFETS has been accumulating these TRU oils while searching for a non-controversial treatment option.

  2. Draft Title 40 CFR 191 compliance certification application for the Waste Isolation Pilot Plant. Volume 3: Appendix BIR Volume 1

    SciTech Connect (OSTI)

    1995-03-31

    The Waste Isolation Pilot Plant (WIPP) Transuranic Waste Baseline Inventory Report (WTWBIR) establishes a methodology for grouping wastes of similar physical and chemical properties, from across the US Department of Energy (DOE) transuranic (TRU) waste system, into a series of ``waste profiles`` that can be used as the basis for waste form discussions with regulatory agencies. The majority of this document reports TRU waste inventories of DOE defense sites. An appendix is included which provides estimates of commercial TRU waste from the West Valley Demonstration Project. The WIPP baseline inventory is estimated using waste streams identified by the DOE TRU waste generator/storage sites, supplemented by information from the Mixed Waste Inventory Report (MWIR) and the 1994 Integrated Data Base (IDB). The sites provided and/or authorized all information in the Waste Stream Profiles except the EPA (hazardous waste) codes for the mixed inventories. These codes were taken from the MWIR (if a WTWBIR mixed waste stream was not in MWIR, the sites were consulted). The IDB was used to generate the WIPP radionuclide inventory. Each waste stream is defined in a waste stream profile and has been assigned a waste matrix code (WMC) by the DOE TRU waste generator/storage site. Waste stream profiles with WMCs that have similar physical and chemical properties can be combined into a waste matrix code group (WMCG), which is then documented in a site-specific waste profile for each TRU waste generator/storage site that contains waste streams in that particular WMCG.

  3. Settlement Agreement on TRU Mixed Waste Storage at Nevada Test Site

    Office of Environmental Management (EM)

    Department of Energy Services » Electricity Advisory Committee » Archived Meetings 2008-2015 » EAC 2014 Meetings » September 24 & 25, 2014 Meeting of the Electricity Advisory Committee September 24 & 25, 2014 Meeting of the Electricity Advisory Committee September 24 & 25, 2014 Meeting of the Electricity Advisory Committee Date: Wednesday, September 24, 2014 12:00 p.m. - 5:30 p.m. EDT Date: Thursday, September 25, 2014 8:00 a.m. - 4:00 p.m. EDT Location: National Rural

  4. HWMA/RCRA Closure Plan for the CPP-648 Radioactive Solid and Liquid Waste Storage Tank System (VES-SFE-106)

    SciTech Connect (OSTI)

    S. K. Evans

    2006-08-15

    This Hazardous Waste Management Act/Resource Conservation and Recovery Act closure plan for the Radioactive Solid and Liquid Waste Storage Tank System located in the adjacent to the Sludge Tank Control House (CPP-648), Idaho Nuclear Technology and Engineering Center, Idaho National Laboratory, was developed to meet the interim status closure requirements for a tank system. The system to be closed includes a tank and associated ancillary equipment that were determined to have managed hazardous waste. The CPP-648 Radioactive Solid and Liquid Waste Storage Tank System will be "cleaned closed" in accordance with the requirements of the Hazardous Waste Management Act/Resource Conservation and Recovery Act as implemented by the Idaho Administrative Procedures Act and 40 Code of Federal Regulations 265. This closure plan presents the closure performance standards and methods of acheiving those standards for the CPP-648 Radioactive Solid and Liquid Waste Storage Tank System.

  5. A One System Integrated Approach to Simulant Selection for Hanford High Level Waste Mixing and Sampling Tests

    SciTech Connect (OSTI)

    Thien, Mike G.; Barnes, Steve M.

    2013-01-17

    The Hanford Tank Operations Contractor (TOC) and the Hanford Waste Treatment and Immobilization Plant (WTP) contractor are both engaged in demonstrating mixing, sampling, and transfer system capabilities using simulated Hanford High-Level Waste (HLW) formulations. This represents one of the largest remaining technical issues with the high-level waste treatment mission at Hanford. Previous testing has focused on very specific TOC or WTP test objectives and consequently the simulants were narrowly focused on those test needs. A key attribute in the Defense Nuclear Facilities Safety Board (DNFSB) Recommendation 2010-2 is to ensure testing is performed with a simulant that represents the broad spectrum of Hanford waste. The One System Integrated Project Team is a new joint TOC and WTP organization intended to ensure technical integration of specific TOC and WTP systems and testing. A new approach to simulant definition has been mutually developed that will meet both TOC and WTP test objectives for the delivery and receipt of HLW. The process used to identify critical simulant characteristics, incorporate lessons learned from previous testing, and identify specific simulant targets that ensure TOC and WTP testing addresses the broad spectrum of Hanford waste characteristics that are important to mixing, sampling, and transfer performance are described.

  6. ADVANCED MIXING MODELS

    SciTech Connect (OSTI)

    Lee, S.; Dimenna, R.; Tamburello, D.

    2011-02-14

    The process of recovering and processing High Level Waste (HLW) the waste in storage tanks at the Savannah River Site (SRS) typically requires mixing the contents of the tank with one to four mixers (pumps) located within the tank. The typical criteria to establish a mixed condition in a tank are based on the number of pumps in operation and the time duration of operation. To ensure that a mixed condition is achieved, operating times are typically set conservatively long. This approach results in high operational costs because of the long mixing times and high maintenance and repair costs for the same reason. A significant reduction in both of these costs might be realized by reducing the required mixing time based on calculating a reliable indicator of mixing with a suitably validated computer code. The focus of the present work is to establish mixing criteria applicable to miscible fluids, with an ultimate goal of addressing waste processing in HLW tanks at SRS and quantifying the mixing time required to suspend sludge particles with the submersible jet pump. A single-phase computational fluid dynamics (CFD) approach was taken for the analysis of jet flow patterns with an emphasis on the velocity decay and the turbulent flow evolution for the farfield region from the pump. Literature results for a turbulent jet flow are reviewed, since the decay of the axial jet velocity and the evolution of the jet flow patterns are important phenomena affecting sludge suspension and mixing operations. The work described in this report suggests a basis for further development of the theory leading to the identified mixing indicators, with benchmark analyses demonstrating their consistency with widely accepted correlations. Although the indicators are somewhat generic in nature, they are applied to Savannah River Site (SRS) waste tanks to provide a better, physically based estimate of the required mixing time. Waste storage tanks at SRS contain settled sludge which varies in

  7. DOE`s planning process for mixed low-level waste disposal

    SciTech Connect (OSTI)

    Case, J.T.; Letourneau, M.J.; Chu, M.S.Y.

    1995-03-01

    A disposal planning process was established by the Department of Energy (DOE) Mixed Low-Level Waste (MLLW) Disposal Workgroup. The process, jointly developed with the States, includes three steps: site-screening, site-evaluation, and configuration study. As a result of the screening process, 28 sites have been eliminated from further consideration for MLLW disposal and 4 sites have been assigned a lower priority for evaluation. Currently 16 sites are being evaluated by the DOE for their potential strengths and weaknesses as MLLW disposal sites. The results of the evaluation will provide a general idea of the technical capability of the 16 disposal sites; the results can also be used to identify which treated MLLW streams can be disposed on-site and which should be disposed of off-site. The information will then serve as the basis for a disposal configuration study, which includes analysis of both technical as well as non-technical issues, that will lead to the ultimate decision on MLLW disposal site locations.

  8. Closure plan for Solid Waste Storage Area 6: Volume 1, Closure plan. Remedial investigation/feasibility study

    SciTech Connect (OSTI)

    Not Available

    1988-09-01

    This Closure Plan for Solid Waste Storage Area 6 (SWSA 6) a disposal area for low-level radioactive wastes and hazardous materials, of the US Department of Energy (DOE) Oak Ridge National Laboratory (ORNL) describes how portions of SWSA 6 will be closed under Resource Conservation and Recovery Act (RCRA) Interim Status per 40 CFR 265 Subpart G [TN Rule 1200-1-11-.05(7)]. An overview is provided of activities necessary for final closure and corrective measures for all of SWSA 6. Results of surface waters and groundwater sampling are provided.

  9. CHARACTERIZING DOE HANFORD SITE WASTE ENCAPSULATION STORAGE FACILITY CELLS USING RADBALL

    SciTech Connect (OSTI)

    Farfan, E.; Coleman, R.

    2011-03-31

    RadBall{trademark} is a novel technology that can locate and quantify unknown radioactive hazards within contaminated areas, hot cells, and gloveboxes. The device consists of a colander-like outer tungsten collimator that houses a radiation-sensitive polymer semi-sphere. The collimator has a number of small holes with tungsten inserts; as a result, specific areas of the polymer are exposed to radiation becoming increasingly more opaque in proportion to the absorbed dose. The polymer semi-sphere is imaged in an optical computed tomography scanner that produces a high resolution 3D map of optical attenuation coefficients. A subsequent analysis of the optical attenuation data using a reverse ray tracing or backprojection technique provides information on the spatial distribution of gamma-ray sources in a given area forming a 3D characterization of the area of interest. RadBall{trademark} was originally designed for dry deployments and several tests, completed at Savannah River National Laboratory and Oak Ridge National Laboratory, substantiate its modeled capabilities. This study involves the investigation of the RadBall{trademark} technology during four submerged deployments in two water filled cells at the DOE Hanford Site's Waste Encapsulation Storage Facility.

  10. Geochemistry research planning for the underground storage of high-level nuclear waste

    SciTech Connect (OSTI)

    Apps, J.A.

    1983-09-01

    This report is a preliminary attempt to plan a comprehensive program of geochemistry research aimed at resolving problems connected with the underground storage of high-level nuclear waste. The problems and research needs were identified in a companion report to this one. The research needs were taken as a point of departure and developed into a series of proposed projects with estimated manpowers and durations. The scope of the proposed research is based on consideration of an underground repository as a multiple barrier system. However, the program logic and organization reflect conventional strategies for resolving technological problems. The projects were scheduled and the duration of the program, critical path projects and distribution of manpower determined for both full and minimal programs. The proposed research was then compared with ongoing research within DOE, NRC and elsewhere to identify omissions in current research. Various options were considered for altering the scope of the program, and hence its cost and effectiveness. Finally, recommendations were made for dealing with omissions and uncertainties arising from program implementation. 11 references, 6 figures, 4 tables.

  11. Remote-controlled NDA (nondestructive assay) systems for feed and product storage at an automated MOX (mixed oxide) facility

    SciTech Connect (OSTI)

    Menlove, H.O.; Augustson, R.H.; Ohtani, T.; Seya, M.; Takahashi, S.; Abedin-Zadeh, R.; Hassan, B.; Napoli, S.

    1989-01-01

    Nondestructive assay (NDA) systems have been developed for use in an automated mixed oxide (MOX) fabrication facility. Unique features have been developed for the NDA systems to accommodate robotic sample handling and remote operation. In addition, the systems have been designed to obtain International Atomic Energy Agency inspection data without the need for an inspector at the facility at the time of the measurements. The equipment is being designed to operate continuously in an unattended mode with data storage for periods of up to one month. The two systems described in this paper include a canister counter for the assay of MOX powder at the input to the facility and a capsule counter for the assay of complete liquid-metal fast breeder reactor fuel assemblies at the output of the plant. The design, performance characteristics, and authentication of the two systems will be described. The data related to reliability, precision, and stability will be presented. 5 refs., 10 figs., 4 tabs.

  12. Low-Level & Mixed Low-Level Radioactive Waste Shipments to NNSS, FY2010 2nd QTR

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NM NY NY NV OH TN TN TN, WA, CA TN TN TN TX Total Shipments by Route Lawrence Livermore National Laboratory Batelle Energy Alliance Idaho National Laboratory Advanced Mixed Waste Treatment Project Energx Argonne National Laboratory Argonne National Laboratory Paducah Gaseous Diffusion Plant Aberdeen Proving Ground Sandia National Laboratories Brookhaven National Laboratory West Valley Environmental Services National Security Technologies, Inc. Portsmouth Gaseous Diffusion Plant Duratek/Energy

  13. Targeted Health Assessment for Wastes Contained at the Niagara Falls Storage Site to Guide Planning for Remedial Action Alternatives - 13428

    SciTech Connect (OSTI)

    Busse, John; Keil, Karen; Staten, Jane; Miller, Neil; Barker, Michelle; MacDonell, Margaret; Peterson, John; Chang, Young-Soo; Durham, Lisa

    2013-07-01

    The U.S. Army Corps of Engineers (USACE) is evaluating potential remedial alternatives at the 191-acre Niagara Falls Storage Site (NFSS) in Lewiston, New York, under the Formerly Utilized Sites Remedial Action Program (FUSRAP). The Manhattan Engineer District (MED) and Atomic Energy Commission (AEC) brought radioactive wastes to the site during the 1940's and 1950's, and the U.S. Department of Energy (US DOE) consolidated these wastes into a 10-acre interim waste containment structure (IWCS) in the southwest portion of the site during the 1980's. The USACE is evaluating remedial alternatives for radioactive waste contained within the IWCS at the NFSS under the Feasibility Study phase of the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) process. A preliminary evaluation of the IWCS has been conducted to assess potential airborne releases associated with uncovered wastes, particularly during waste excavation, as well as direct exposures to uncovered wastes. Key technical issues for this assessment include: (1) limitations in waste characterization data; (2) representative receptors and exposure routes; (3) estimates of contaminant emissions at an early stage of the evaluation process; (4) consideration of candidate meteorological data and air dispersion modeling approaches; and (5) estimates of health effects from potential exposures to both radionuclides and chemicals that account for recent updates of exposure and toxicity factors. Results of this preliminary health risk assessment indicate if the wastes were uncovered and someone stayed at the IWCS for a number of days to weeks, substantial doses and serious health effects could be incurred. Current controls prevent such exposures, and the controls that would be applied to protect onsite workers during remedial action at the IWCS would also effectively protect the public nearby. This evaluation provides framing context for the upcoming development and detailed evaluation of

  14. Evaluation of the three-phase, electric arc melting furnace for treatment of simulated, thermally oxidized radioactive and mixed wastes. Part 1: Design criteria and description of integrated waste treatment facility

    SciTech Connect (OSTI)

    Oden, L.L.; O`Connor, W.K.; Turner, P.C.; Hartman, A.D.

    1995-06-01

    The US Bureau of Mines and the Department of Energy (DOE), through its contractor EG and G Idaho Inc., are collaborating on a multiyear research project to evaluate the applicability of three-phase, electric-arc furnace melting technology to vitrify materials simulating low-level radioactive and mixed wastes buried or stored at the Idaho National Engineering Laboratory and other DOE sites. The melter is sealed, 1-t (1.1-st), three-phase, 800-kV {center_dot} A electric arc melting furnace with 10.2-cm- (4-in-) diameter graphite electrodes, water-cooled roof and sidewalls, and four water-cooled feed tubes. A water-cooled copper fixture provides for continuous tapping of slag. An instrumented air pollution control system (APCS) with access ports for analysis and a feeder based on screw conveyors and a bucket elevator are dedicated to the facility. Test data are provided by an arc furnace analyzer and by sensors indicating feed rate; slag temperature; and temperature, pressure, and velocity in the APCS. These data are received by a data logger, digitized, and transmitted to a personal computer for storage and display. This unique waste treatment facility is available for public and private use on a cost-sharing basis.

  15. Implementation of seismic design and evaluation guidelines for the Department of Energy high-level waste storage tanks and appurtenances

    SciTech Connect (OSTI)

    Conrads, T.J.

    1993-06-01

    In the fall of 1992, a draft of the Seismic Design and Evaluation Guidelines for the Department of Energy (DOE) High-level Waste Storage Tanks and Appurtenances was issued. The guidelines were prepared by the Tanks Seismic Experts Panel (TSEP) and this task was sponsored by DOE, Environmental Management. The TSEP is comprised of a number of consultants known for their knowledge of seismic ground motion and expertise in the analysis of structures, systems and components subjected to seismic loads. The development of these guidelines was managed by staff from Brookhaven National Laboratory, Engineering Research and Applications Division, Department of Nuclear Energy. This paper describes the process used to incorporate the Seismic Design and Evaluation Guidelines for the DOE High-Level Waste Storage Tanks and Appurtenances into the design criteria for the Multi-Function Waste Tank Project at the Hanford Site. This project will design and construct six new high-level waste tanks in the 200 Areas at the Hanford Site. This paper also discusses the vehicles used to ensure compliance to these guidelines throughout Title 1 and Title 2 design phases of the project as well as the strategy used to ensure consistent and cost-effective application of the guidelines by the structural analysts. The paper includes lessons learned and provides recommendations for other tank design projects which might employ the TSEP guidelines.

  16. Status and use of the Rocky Flats Environmental Technology Site Pipe Overpack Container for TRU waste storage and shipments

    SciTech Connect (OSTI)

    Thorp, D.T.; Geinitz, R.R.; Rivera, M.A.

    1998-03-03

    The Pipe Overpack Container was designed to optimize shipments of high plutonium content transuranic waste from Rocky Flats Environmental Technology Site (RFETS) to Waste Isolation Pilot Plant (WIPP). The container was approved for use in the TRUPACT-II shipping container by the Nuclear Regulatory Commission in February 1997. The container optimizes shipments to WIPP by increasing the TRUPACT-II criticality limit from 325 fissile grams equivalent (FGE) to 2,800 FGE and provides additional shielding for handling wastes with high americium-241 (Am-241) content. The container was subsequently evaluated and approved for storage of highly dispersible TRU wastes and residues at RFETS. Thermal evaluation of the container shows that the container will mitigate the impact of a worst case thermal event from reactive or potentially pyrophoric materials. These materials contain hazards postulated by the Defense Nuclear Facilities Safety Board for interim storage. Packaging these reactive or potentially pyrophoric residues in the container without stabilizing the materials is under consideration at RFETS. The design, testing, and evaluations used in the approvals, and the current status of the container usage, will be discussed.

  17. Superconducting open-gradient magnetic separation for the pretreatment of radioactive or mixed waste vitrification feeds. 1997 annual progress report

    SciTech Connect (OSTI)

    Doctor, R.; Nunez, L.; Cicero-Herman, C.A.; Ritter, J.A.; Landsberger, S.

    1997-01-01

    'Vitrification has been selected as a final waste form technology in the US for long-term storage of high-level radioactive wastes (HLW). However, a foreseeable problem during vitrification in some waste feed streams lies in the presence of elements (e.g., transition metals) in the HLW that may cause instabilities in the final glass product. The formation of spinel compounds, such as Fe{sub 3}O{sub 4} and FeCrO{sub 4}, results in glass phase separation and reduces vitrifier lifetime, and durability of the final waste form. A superconducting open gradient magnetic separation (OGMS) system maybe suitable for the removal of the deleterious transition elements (e.g. Fe, Co, and Ni) and other elements (lanthanides) from vitrification feed streams due to their ferromagnetic or paramagnetic nature. The OGMS systems are designed to deflect and collect paramagnetic minerals as they interact with a magnetic field gradient. This system has the potential to reduce the volume of HLW for vitrification and ensure a stable product. In order to design efficient OGMS and High gradient magnetic separation (HGMS) processes, a fundamental understanding of the physical and chemical properties of the waste feed streams is required. Using HLW simulant and radioactive fly ash and sludge samples from the Savannah River Technology Center, Rocky Flats site, and the Hanford reservation, several techniques were used to characterize and predict the separation capability for a superconducting OGMS system.'

  18. Report on the performance monitoring system for the interim waste containment at the Niagara Falls Storage Site, Lewiston, New York

    SciTech Connect (OSTI)

    Not Available

    1985-10-01

    The Niagara Falls Storage Site (NFSS) is an interim storage site for low-level radioactive waste, established by the US Department of Energy (DOE) at Lewiston, New York. The waste containment structure for encapsulating low-level radioactive waste at the NFSS has been designed to minimize infiltration of rainfall, prevent pollution of groundwater, preclude formation of leachate, and prevent radon emanation. Accurately determining the performance of the main engineered elements of the containment structure will be important in establishing confidence in the ability of the structure to retain the wastes. For this purpose, a waste containment performance monitoring system has been developed to verify that these elements are functioning as intended. The key objective of the performance monitoring system is the early detection of trends that could be indicative of weaknesses developing in the containment structure so that corrective action can be taken before the integrity of the structure is compromised. Consequently, subsurface as well as surface monitoring techniques will be used. After evaluating several types of subsurface instrumentation, it was determined that vibrating wire pressure transducers, in combination with surface monitoring techniques, would satisfactorily monitor the parameters of concern, such as water accumulation inside the containment facility, waste settlement, and shrinkage of the clay cover. Surface monitoring will consist of topographic surveys based on predetermined gridlines, walkover surveys, and aerial photography to detect vegetative stress or other changes not evident at ground level. This report details the objectives of the performance monitoring system, identifies the elements of the containment design whose performance will be monitored, describes the monitoring system recommended, and outlines the costs associated with the monitoring system. 5 refs., 4 figs., 3 tabs.

  19. Report on interim storage of spent nuclear fuel. Midwestern high-level radioactive waste transportation project

    SciTech Connect (OSTI)

    Not Available

    1993-04-01

    The report on interim storage of spent nuclear fuel discusses the technical, regulatory, and economic aspects of spent-fuel storage at nuclear reactors. The report is intended to provide legislators state officials and citizens in the Midwest with information on spent-fuel inventories, current and projected additional storage requirements, licensing, storage technologies, and actions taken by various utilities in the Midwest to augment their capacity to store spent nuclear fuel on site.

  20. Acceptable Knowledge Summary Report for Mixed TRU Waste Streams: SR-W026-221F-HET-A through D

    SciTech Connect (OSTI)

    Lunsford, G.F.

    2001-10-02

    This document, along with referenced supporting documents provides a defensible and auditable record of acceptable knowledge for the heterogeneous debris mixed transuranic waste streams generated in the FB-Line after January 25, 1990 and before March 20, 1997.

  1. Geochemical information for sites contaminated with low-level radioactive wastes. III. Weldon Spring Storage Site

    SciTech Connect (OSTI)

    Seeley, F.G.; Kelmers, A.D.

    1985-02-01

    The Weldon Spring Storage Site (WSSS), which includes both the chemical site and the quarry, became radioactively contaminated as the result of wastes that were being stored from operations to recover uranium from pitchblende ores in the 1940s and 1950s. The US Department of Energy (DOE) is considering various remedial action options for the WSSS. This report describes the results of geochemical investigations carried out at Oak Ridge National Laboratory (ORNL) to support these activities and to help quantify various remedial action options. Soil and groundwater samples were characterized, and uranium and radium sorption ratios were measured in site soil/groundwater systems by batch contact methodology. Soil samples from various locations around the raffinate pits were found to contain major amounts of silica, along with illite as the primary clay constituent. Particle sizes of the five soil samples were variable (50% distribution point ranging from 12 to 81 ..mu..m); the surface areas varied from 13 to 62 m/sup 2//g. Elemental analysis of the samples showed them to be typical of sandy clay and silty clay soils. Groundwater samples included solution from Pit 3 and well water from Well D. Anion analyses showed significant concentrations of sulfate and nitrate (>350 and >7000 mg/L, respectively) in the solution from Pit 3. These anions were also present in the well water, but in lower concentrations. Uranium sorption ratios for four of the soil samples contacted with the solution from Pit 3 were moderate to high (approx. 300 to approx. 1000 mL/g). The fifth sample had a ratio of only 12 mL/g. Radium sorption ratios for the five samples were moderate to high (approx. 600 to approx. 1000 mL/g). These values indicate that soil at the WSSS may show favorable retardation of uranium and radium in the groundwater. 13 references, 13 figures, 10 tables.

  2. SOLID RADIOACTIVE WASTE STORAGE TECHNOLOGIES: PERFORMANCE OF A POLYMER SEALANT COATING IN AN ARCTIC MARINE ENVIRONMENT

    SciTech Connect (OSTI)

    COWGILL,M.G.; MOSKOWITZ,P.D.; CHERNAENKO,L.M.; NAZARIAN,A.; GRIFFITH,A.; DIASHEV,A.; ENGOY,T.

    2000-06-14

    This first project, under the auspices of the Arctic Military Environmental Cooperation (AMEC) forum, Project 1.4-1 Solid Radioactive Waste Storage Technologies, successfully demonstrated the feasibility of using a polymer-based coating to seal concrete and steel surfaces from permanent radioactive contamination in an Arctic marine environment. A mobile, self-sufficient spraying device, was developed to specifications provided by the Russian Ministry of Defence Northern Navy and was deployed at the RTP Atomflot site, Murmansk, Russia. Demonstration coatings of Polibrid 705 were applied to concrete surfaces exposed to conditions ranging from indoor pedestrian usage to heavy vehicle passage and container handling in a loading bay. A large steel container was also coated with the polymer, filled with solid radwaste, sealed, and left out of doors and exposed to the full 12 month Arctic weather cycle. The field tests were accompanied by a series of laboratory qualification tests carried out at the research laboratory of ICC Nuclide in St. Petersburg. During the 12-month field tests, the sealant coating showed little sign of degradation except for a few chips and gouge marks on the loading bay surface that were readily repaired. Contamination resulting from radwaste handling was easily removed and the surface was not degraded by contact with the decontamination agents. In the laboratory testing, Polibrid 705 met all the Russian qualification requirements with the exception of flammability. In this last instance, it was decided to restrict application of the coating to land-based facilities. The Russian technical experts from the Ministry of Defence quickly familiarized themselves with the equipment and were able to identify several areas of potential improvement as deployment of the equipment progressed. The prime among these was the desirability of extending the range of the equipment through enlarged gasoline tanks (to permit extended operational times) and longer

  3. The First Recovery Act Funded Waste Shipment depart from the...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The First Recovery Act Funded Waste Shipment departs from the Advanced Mixed Waste Treatment Facility A shipment of mixed low-level waste left DOEs Advanced Mixed Waste ...

  4. EIS-0290: Idaho National Engineering and Environmental Laboratory Advanced Mixed Waste Treatment Project (AMWTP)

    Broader source: Energy.gov [DOE]

    The AMWTP Final EIS assesses the potential environmental impacts associated with alternatives related to the construction and operation of a proposed waste treatment facility at the Idaho National...

  5. Verification survey report of the south waste tank farm training/test tower and hazardous waste storage lockers at the West Valley demonstration project, West Valley, New York

    SciTech Connect (OSTI)

    Weaver, Phyllis C.

    2012-08-29

    A team from ORAU's Independent Environmental Assessment and Verification Program performed verification survey activities on the South Test Tower and four Hazardous Waste Storage Lockers. Scan data collected by ORAU determined that both the alpha and alpha-plus-beta activity was representative of radiological background conditions. The count rate distribution showed no outliers that would be indicative of alpha or alpha-plus-beta count rates in excess of background. It is the opinion of ORAU that independent verification data collected support the site?s conclusions that the South Tower and Lockers sufficiently meet the site criteria for release to recycle and reuse.

  6. Portable Analyzer Based on Microfluidics/Nanoengineered Electrochemical Sensors for in Situ Characterization of Mixed Wastes

    SciTech Connect (OSTI)

    Wang, Joseph

    2006-06-01

    Portable Analyzer Based on Microfluidic/Nanoengineered Electrochemical Sensors for in Situ Characterization of Mixed Wastes PI: Dr. Joseph Wang (In Collaboration with the PNNL PI Dr. Y. Lin). Objective of Research: This research effort aims at developing a portable analytical system for fast, sensitive, and inexpensive, on-site monitoring of toxic transition metals and radionuclides in contaminated DOE Sites. The portable devices will be based on Microscale Total Analytical systems ( -TAS) or 'Lab-on-a-chip' in combination with electrochemical (stripping-voltammetric) sensors. The resulting microfluidics/electrochemical sensor system would allow testing for toxic metals to be performed more rapidly, inexpensively, and reliably in a field setting. Progress Summary/Accomplishments: This report summarizes the ASU activity over the second year of the project. In accordance to our original objectives our studies have focused on various fundamental and practical aspects of sensing and microchip devices for monitoring metal contaminants. As described in this section, we have made a substantial progress, and introduced effective routes for improving the on-site detection of toxic metals and for interfacing microchips with the real world. This activity has already resulted in 7 research papers (published or in press in major international journals). The electrochemical sensors being developed rely on the highly sensitive adsorptive stripping voltammetry (AdSV) technique to detect metal ions of interest to the DOE, particularly uranium and chromium. Traditionally, AdSV measurements of U and Cr require the use of mercury electrodes which are not suitable attractive for field deployment. Our initial goal was thus to replace these toxic mercury electrodes with 'environmentally-friendly' sensor materials. In particular, we demonstrated recently that bismuth-film electrodes offer high-quality measurements of heavy metals that compare favorably with that of mercury electrodes

  7. Nevada Test Site Waste Acceptance Criteria

    SciTech Connect (OSTI)

    U. S. Department of Energy, National Nuclear Security Administration Nevada Site Office

    2005-10-01

    This document establishes the U.S. Department of Energy (DOE), National Nuclear Security Administration Nevada Site Office (NNSA/NSO) waste acceptance criteria (WAC). The WAC provides the requirements, terms, and conditions under which the Nevada Test Site (NTS) will accept low-level radioactive (LLW) and mixed waste (MW) for disposal. It includes requirements for the generator waste certification program, characterization, traceability, waste form, packaging, and transfer. The criteria apply to radioactive waste received at the NTS Area 3 and Area 5 Radioactive Waste Management Complex (RWMC) for storage or disposal.

  8. DOE Identifies its Preferred Alternative for Certain Hanford Tank Wastes

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy (DOE) is announcing its preferred alternative for wastes contained in underground radioactive waste storage tanks evaluated in the Final Tank Closure and Waste Management Environmental Impact Statement for the Hanford Site, Richland, Washington (Final TC & WM EIS, DOE/EIS-0391, December 2012). With regard to those wastes that, in the future, may be properly and legally classified as mixed transuranic waste (mixed TRU waste). DOE's preferred alternative is to retrieve, treat, package, and characterize and certify the wastes for disposal at the Waste Isolation Pilot Plant (WIPP) in Carlsbad, New Mexico, a geologic repository for the disposal of mixed TRU waste generated by atomic energy defense activities.

  9. Portable Analyzer Based on Microfluidics/Nanoengineered Electrochemical Sensors for In-situ Characterization of Mixed Wastes

    SciTech Connect (OSTI)

    Yuehe Lin; Glen E. Fryxell; Wassana Yantasee; Guodong Liu; Zheming Wang

    2006-06-01

    Required characterizations of the DOE's transuranic (TRU) and mixed wastes (MW) before disposing and treatment of the wastes are currently costly and have lengthy turnaround. Research toward developing faster and more sensitive characterization and analysis tools to reduce costs and accelerate throughputs is therefore desirable. This project is aimed at the development of electrochemical sensors, specific to toxic transition metals, uranium, and technetium, that can be integrated into the portable sensor systems. This system development will include fabrication and performance evaluation of electrodes as well as understanding of electrochemically active sites on the electrodes specifically designed for toxic metals, uranium and technetium detection. Subsequently, these advanced measurement units will be incorporated into a microfluidic prototype specifically designed and fabricated for field-deployable characterizations of such species.

  10. EIS-0200: Waste Management Programmatic Environmental Impact Statement for Managing Treatment, Storage, and Disposal of Radioactive and Hazardous Waste

    Broader source: Energy.gov [DOE]

    This Programmatic EIS evaluates the potential environmental and cost impacts of strategic management alternatives for managing five types of radioactive and hazardous wastes that have resulted and will continue to result from nuclear defense and research activities at a variety of sites around the United States.

  11. Statement of work for conceptual design of solidified high-level waste interim storage system project (phase I)

    SciTech Connect (OSTI)

    Calmus, R.B., Westinghouse Hanford

    1996-12-17

    The U.S. Department of Energy (DOE) has embarked upon a course to acquire Hanford Site tank waste treatment and immobilization services using privatized facilities. This plan contains a two phased approach. Phase I is a ``proof-of-principle/commercial demonstration- scale`` effort and Phase II is a full-scale production effort. In accordance with the planned approach, interim storage (IS) and disposal of various products from privatized facilities are to be DOE furnished. The path forward adopted for Phase I solidification HLW IS entails use of Vaults 2 and 3 in the Spent Nuclear Fuel Canister Storage Building, to be located in the Hanford Site 200 East Area. This Statement of Work describes the work scope to be performed by the Architect-Engineer to prepare a conceptual design for the solidified HLW IS System.

  12. Underground storage tank integrated demonstration: Evaluation of pretreatment options for Hanford tank wastes

    SciTech Connect (OSTI)

    Lumetta, G.J.; Wagner, M.J.; Colton, N.G.; Jones, E.O.

    1993-06-01

    Separation science plays a central role inn the pretreatment and disposal of nuclear wastes. The potential benefits of applying chemical separations in the pretreatment of the radioactive wastes stored at the various US Department of Energy sites cover both economic and environmental incentives. This is especially true at the Hanford Site, where the huge volume (>60 Mgal) of radioactive wastes stored in underground tanks could be partitioned into a very small volume of high-level waste (HLW) and a relatively large volume of low-level waste (LLW). The cost associated with vitrifying and disposing of just the HLW fraction in a geologic repository would be much less than those associated with vitrifying and disposing of all the wastes directly. Futhermore, the quality of the LLW form (e.g., grout) would be improved due to the lower inventory of radionuclides present in the LLW stream. In this report, we present the results of an evaluation of the pretreatment options for sludge taken from two different single-shell tanks at the Hanford Site-Tanks 241-B-110 and 241-U-110 (referred to as B-110 and U-110, respectively). The pretreatment options examined for these wastes included (1) leaching of transuranic (TRU) elements from the sludge, and (2) dissolution of the sludge followed by extraction of TRUs and {sup 90}Sr. In addition, the TRU leaching approach was examined for a third tank waste type, neutralized cladding removal waste.

  13. Design report for the interim waste containment facility at the Niagara Falls Storage Site. [Surplus Facilities Management Program

    SciTech Connect (OSTI)

    Not Available

    1986-05-01

    Low-level radioactive residues from pitchblende processing and thorium- and radium-contaminated sand, soil, and building rubble are presently stored at the Niagara Falls Storage Site (NFSS) in Lewiston, New York. These residues and wastes derive from past NFSS operations and from similar operations at other sites in the United States conducted during the 1940s by the Manhattan Engineer District (MED) and subsequently by the Atomic Energy Commission (AEC). The US Department of Energy (DOE), successor to MED/AEC, is conducting remedial action at the NFSS under two programs: on-site work under the Surplus Facilities Managemnt Program and off-site cleanup of vicinity properties under the Formerly Utilized Sites Remedial Action Program. On-site remedial action consists of consolidating the residues and wastes within a designated waste containment area and constructing a waste containment facility to prevent contaminant migration. The service life of the system is 25 to 50 years. Near-term remedial action construction activities will not jeopardize or preclude implementation of any other remedial action alternative at a later date. Should DOE decide to extend the service life of the system, the waste containment area would be upgraded to provide a minimum service life of 200 years. This report describes the design for the containment system. Pertinent information on site geology and hydrology and on regional seismicity and meteorology is also provided. Engineering calculations and validated computer modeling studies based on site-specific and conservative parameters confirm the adequacy of the design for its intended purposes of waste containment and environmental protection.

  14. Solid Waste Assurance Program Implementation Plan

    SciTech Connect (OSTI)

    Irons, L.G.

    1995-06-19

    On June 6, 1995, a waiver to Hanford Site Solid Waste Acceptance Criteria, was approved by the US Department of Energy Richland Operations Office (RL) to replace the low-level, mixed, and transuranic (TRU) generator assessment programs with the Solid Waste Assurance Program (SWAP). This is associated with a waiver that was approved on March 16, 1995 to replace the Storage/Disposal Approval Record (SDAR) requirements with the Waste Specification System (WSS). This implementation plan and the SWAP applies to Solid Waste Disposal (SWD) functions, facilities, and personnel who perform waste acceptance, verification, receipt, and management functions of dangerous, radioactive, and mixed waste from on- and off-site generators who ship to or within the Hanford Site for treatment, storage, and/or disposal (TSD) at SWD TSD facilities.

  15. Turning the Corner on Hanford Tank Waste Cleanup-From Safe Storage to Closure

    SciTech Connect (OSTI)

    Boston, H. L.; Cruz, E. J.; Coleman, S. J.

    2002-02-25

    The U.S. Department of Energy (DOE), Office of River Protection (ORP) is leading the River Protection Project (RPP) which is responsible for the disposition of 204,000 cubic meters (54 million gallons) of high-level radioactive waste that have accumulated in large underground tanks at the Hanford Site since 1944. ORP continues to make good progress on improving the capability to treat Hanford tank waste. Design of the waste vitrification facilities is proceeding well and construction will begin within the next year. Progress is also being made in reducing risk to the worker and the environment from the waste currently stored in the tank farms. Removal of liquids from single-shell tanks (SSTs) is on schedule and we will begin removing solids (salt cake) from a tank (241-U-107) in 2002. There is a sound technical foundation for the waste vitrification facilities. These initial facilities will be capable of treating (vitrifying) the bulk of Hanford tank waste and are the corners tone of the clean-up strategy. ORP recognizes that as the near-term work is performed, it is vital that there be an equally strong and defensible plan for completing the mission. ORP is proceeding on a three-pronged approach for moving the mission forward. First, ORP will continue to work aggressively to complete the waste vitrification facilities. ORP intends to provide the most capable and robust facilities to maximize the amount of waste treated by these initial facilities by 2028 (regulatory commitment for completion of waste treatment). Second, and in parallel with completing the waste vitrification facilities, ORP is beginning to consider how best to match the hazard of the waste to the disposal strategy. The final piece of our strategy is to continue to move forward with actions to reduce risk in the tank farms and complete cleanup.

  16. EA-0843: Idaho National Engineering Laboratory Low-Level and Mixed Waste Processing, Idaho Falls, Idaho

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts of a proposal to (1) reduce the volume of the U.S. Department of Energy's Idaho National Engineering Laboratory's (INEL) generated low-level waste (LLW)...

  17. Probabilistic performance-assessment modeling of the mixed waste landfill at Sandia National Laboratories.

    SciTech Connect (OSTI)

    Peace, Gerald L.; Goering, Timothy James; Miller, Mark Laverne; Ho, Clifford Kuofei

    2005-11-01

    A probabilistic performance assessment has been conducted to evaluate the fate and transport of radionuclides (americium-241, cesium-137, cobalt-60, plutonium-238, plutonium-239, radium-226, radon-222, strontium-90, thorium-232, tritium, uranium-238), heavy metals (lead and cadmium), and volatile organic compounds (VOCs) at the Mixed Waste Landfill (MWL). Probabilistic analyses were performed to quantify uncertainties inherent in the system and models for a 1,000-year period, and sensitivity analyses were performed to identify parameters and processes that were most important to the simulated performance metrics. Comparisons between simulated results and measured values at the MWL were made to gain confidence in the models and perform calibrations when data were available. In addition, long-term monitoring requirements and triggers were recommended based on the results of the quantified uncertainty and sensitivity analyses. At least one-hundred realizations were simulated for each scenario defined in the performance assessment. Conservative values and assumptions were used to define values and distributions of uncertain input parameters when site data were not available. Results showed that exposure to tritium via the air pathway exceeded the regulatory metric of 10 mrem/year in about 2% of the simulated realizations when the receptor was located at the MWL (continuously exposed to the air directly above the MWL). Simulations showed that peak radon gas fluxes exceeded the design standard of 20 pCi/m{sup 2}/s in about 3% of the realizations if up to 1% of the containers of sealed radium-226 sources were assumed to completely degrade in the future. If up to 100% of the containers of radium-226 sources were assumed to completely degrade, 30% of the realizations yielded radon surface fluxes that exceeded the design standard. For the groundwater pathway, simulations showed that none of the radionuclides or heavy metals (lead and cadmium) reached the groundwater during

  18. Analysis of accident sequences and source terms at waste treatment and storage facilities for waste generated by U.S. Department of Energy Waste Management Operations, Volume 3: Appendixes C-H

    SciTech Connect (OSTI)

    Mueller, C.; Nabelssi, B.; Roglans-Ribas, J.

    1995-04-01

    This report contains the Appendices for the Analysis of Accident Sequences and Source Terms at Waste Treatment and Storage Facilities for Waste Generated by the U.S. Department of Energy Waste Management Operations. The main report documents the methodology, computational framework, and results of facility accident analyses performed as a part of the U.S. Department of Energy (DOE) Waste Management Programmatic Environmental Impact Statement (WM PEIS). The accident sequences potentially important to human health risk are specified, their frequencies are assessed, and the resultant radiological and chemical source terms are evaluated. A personal computer-based computational framework and database have been developed that provide these results as input to the WM PEIS for calculation of human health risk impacts. This report summarizes the accident analyses and aggregates the key results for each of the waste streams. Source terms are estimated and results are presented for each of the major DOE sites and facilities by WM PEIS alternative for each waste stream. The appendices identify the potential atmospheric release of each toxic chemical or radionuclide for each accident scenario studied. They also provide discussion of specific accident analysis data and guidance used or consulted in this report.

  19. RCRA Part A Permit Application for Waste Management Activities at the Nevada Test Site, Part B Permit Application Hazardous Waste Storage Unit, Nevada Test Site, and Part B Permit Application - Explosives Ordnance Disposal Unit (EODU)

    SciTech Connect (OSTI)

    NSTec Environmental Programs

    2010-06-17

    The Area 5 Hazardous Waste Storage Unit (HWSU) was established to support testing, research, and remediation activities at the Nevada Test Site (NTS), a large-quantity generator of hazardous waste. The HWSU, located adjacent to the Area 5 Radioactive Waste Management Site (RWMS), is a prefabricated, rigid steel-framed, roofed shelter used to store hazardous nonradioactive waste generated on the NTS. No offsite generated wastes are managed at the HWSU. Waste managed at the HWSU includes the following categories: Flammables/Combustibles; Acid Corrosives; Alkali Corrosives; Oxidizers/Reactives; Toxics/Poisons; and Other Regulated Materials (ORMs). A list of the regulated waste codes accepted for storage at the HWSU is provided in Section B.2. Hazardous wastes stored at the HWSU are stored in U.S. Department of Transportation (DOT) compliant containers, compatible with the stored waste. Waste transfer (between containers) is not allowed at the HWSU and containers remain closed at all times. Containers are stored on secondary containment pallets and the unit is inspected monthly. Table 1 provides the metric conversion factors used in this application. Table 2 provides a list of existing permits. Table 3 lists operational Resource Conservation and Recovery Act (RCRA) units at the NTS and their respective regulatory status.

  20. Turning the Corner on Hanford Tank Waste Cleanup from Safe Storage to Closure

    SciTech Connect (OSTI)

    CRUZ, E.J.; BOSTON, H.L.

    2002-02-04

    The U.S. Department of Energy (DOE), Office of River Protection (ORP) is leading the River Protection Project (RPP) which is responsible for the disposition of 204,000 cubic meters (54 million gallons) of high-level radioactive waste that have accumulated in large underground tanks at the Hanford Site since 1944. ORP continues to make good progress on improving the capability to treat Hanford tank waste. Design of the waste vitrification facilities is proceeding well and construction will begin within the next year. Progress is also being made in reducing risk to the worker and the environment from the waste currently stored in the tank farms. Removal of liquids from single-shell tanks (SSTs) is on schedule and we will begin removing solids (salt cake) from a tank (241-U-107) in 2002. There is a sound technical foundation for the waste vitrification facilities. These initial facilities will be capable of treating (vitrifying) the bulk of Hanford tank waste and are the cornerstone of the clean-up strategy. ORP recognizes that as the near-term work is performed, it is vital that there be an equally strong and defensible plan for completing the mission. ORP is proceeding on a three-pronged approach for moving the mission forward. First, ORP will continue to work aggressively to complete the waste vitrification facilities. ORP intends to provide the most capable and robust facilities to maximize the amount of waste treated by these Initial facilities by 2028 (regulatory commitment for completion of waste treatment). Second, and in parallel with completing the waste vitrification facilities, ORP is beginning to consider how best to match the hazard of the waste to the disposal strategy. The final piece of our strategy is to continue to move forward with actions to reduce risk in the tank farms and complete cleanup. The goal of these efforts is to keep the RPP on a success path for completing cleanup of Hanford tank waste. While all parties are aggressively moving

  1. Grand Junction projects office mixed-waste treatment program, VAC*TRAX mobile treatment unit process hazards analysis

    SciTech Connect (OSTI)

    Bloom, R.R.

    1996-04-01

    The objective of this report is to demonstrate that a thorough assessment of the risks associated with the operation of the Rust Geotech patented VAC*TRAX mobile treatment unit (MTU) has been performed and documented. The MTU was developed to treat mixed wastes at the US Department of Energy (DOE) Albuquerque Operations Office sites. The MTU uses an indirectly heated, batch vacuum dryer to thermally desorb organic compounds from mixed wastes. This process hazards analysis evaluated 102 potential hazards. The three significant hazards identified involved the inclusion of oxygen in a process that also included an ignition source and fuel. Changes to the design of the MTU were made concurrent with the hazard identification and analysis; all hazards with initial risk rankings of 1 or 2 were reduced to acceptable risk rankings of 3 or 4. The overall risk to any population group from operation of the MTU was determined to be very low; the MTU is classified as a Radiological Facility with low hazards.

  2. Environmental permits and approvals plan for high-level waste interim storage, Project W-464

    SciTech Connect (OSTI)

    Deffenbaugh, M.L.

    1998-05-28

    This report discusses the Permitting Plan regarding NEPA, SEPA, RCRA, and other regulatory standards and alternatives, for planning the environmental permitting of the Canister Storage Building, Project W-464.

  3. Portable Analyzer Based on Microfluidics/Nanoengineered Electrochemical Sensors for In-situ Characterization of Mixed Wastes

    SciTech Connect (OSTI)

    Lin, Yuehe; Wang, Joseph

    2004-06-01

    Required characterizations of the DOE's transuranic (TRU) and mixed wastes (MW) before disposing and treatment of the wastes are currently costly and have lengthy turnaround. Research toward developing faster and more sensitive characterization and analysis tools to reduce costs and accelerate throughputs is therefore desirable. This project is aimed at the development of electrochemical sensors, specific to toxic transition metals, uranium, and technetium, that can be integrated into the portable sensor systems. This system development will include fabrication and performance evaluation of electrodes as well as understanding of electrochemically active sites on the electrodes specifically designed for toxic metals, uranium and technetium detection. Subsequently, these advanced measurement units will be incorporated into a microfluidic prototype specifically designed and fabricated for field-deployable characterizations of such species. The electrochemical sensors being invest igated are based on a new class of nanoengineered sorbents, Self-Assembled Monolayer on Mesoporous Supports (SAMMS). SAMMS are highly efficient sorbents due to their interfacial chemistry that can be fine-tuned to selectively sequester a specific target species. Adsorptive stripping voltammetry (AdSV) will be performed on two classes of electrodes: the SAMMS modified carbon paste electrodes, and the SAMMS thin film immobilized on microelectrode arrays. Interfacial chemistry and electrochemistry of metal species on the surfaces of SAMMS-based electrodes will be studied. This fundamental knowledge is required for predicting how the sensors will perform in the real wastes which consist of many interferences/ligands and a spectrum of pH levels. The best electrode for each specific waste constituent will be integrated onto the portable microfluidic platform. Efforts will also be focused on testing the portable microfluidics/electrochemical sensor systems with the selected MW and T RU waste samples

  4. EA-1146: Radioactive Waste Storage at Rocky Flats Environmental Technology Site, Golden, Colorado

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts of the proposal to convert buildings at the U.S. Department of Energy Rocky Flats Environmental Technology Site from their former uses to interim waste...

  5. An Adaptive, Consent-Based Path to Nuclear Waste Storage and...

    Broader source: Energy.gov (indexed) [DOE]

    for the final disposition of used fuel and nuclear waste must be based not only on sound science but also on achieving public acceptance at the local, and state and tribal levels....

  6. Master Safety Analysis Report (SAR) approach for solid waste treatment, storage, and disposal facilities

    SciTech Connect (OSTI)

    Bonner, A.L.; Estrellado, J.P. Jr.

    1993-06-01

    In 1989, the Hanford Site took on a new mission of waste remediation and environmental cleanup. The Hanford Site vision is to become the leader in environmental cleanup technology while bringing the site back to its environmental pristine condition. This technology drive to launch the Hanford site as the flagship of environmental restoration has been divided into several mission areas. This paper focuses on the solid waste management (SWM) mission.

  7. Mixed Waste Management Facility (MWMF) Old Burial Ground (OBG) source control technology and inventory study

    SciTech Connect (OSTI)

    Flach, G.P.; Rehder, T.E.; Kanzleiter, J.P.

    1996-10-02

    This report has been developed to support information needs for wastes buried in the Burial Ground Complex. Information discussed is presented in a total of four individual attachments. The general focus of this report is to collect information on estimated source inventories, leaching studies, source control technologies, and to provide information on modeling parameters and associated data deficiencies.

  8. Description of a Multipurpose Processing and Storage Complex for the Hanford Site`s radioactive material

    SciTech Connect (OSTI)

    Nyman, D.H.; Wolfe, B.A.; Hoertkorn, T.R.

    1993-05-01

    The mission of the US Department of Energy`s (DOE) Hanford Site has changed from defense nuclear materials production to that of waste management/disposal and environmental restoration. ne Multipurpose Processing and Storage Complex (MPSC) is being designed to process discarded waste tank internal hardware contaminated with mixed wastes, failed melters from the vitrification plant, and other Hanford Site high-level solid waste. The MPSC also will provide interim storage of other radioactive materials (irradiated fuel, canisters of vitrified high-level waste [HLW], special nuclear material [SNM], and other designated radioactive materials).

  9. Transuranic waste inventory, characteristics, generation, and facility assessment for treatment, storage, and disposal alternatives considered in the U.S. Department of Energy Waste Management Programmatic Environmental Impact Statement

    SciTech Connect (OSTI)

    Hong, K.; Kotek, T.; Folga, S.; Koebnick, B.; Wang, Y.; Kaicher, C.

    1996-12-01

    Transuranic waste (TRUW) loads and potential contaminant releases at and en route to treatment, storage, and disposal sites in the US Department of Energy (DOE) complex are important considerations in DOE`s Waste Management Programmatic Environmental Impact Statement (WM PEIS). Waste loads are determined in part by the level of treatment the waste has undergone and the complex-wide configuration of origination, treatment, storage, and disposal sites selected for TRUW management. Other elements that impact waste loads are treatment volumes, waste characteristics, and the unit operation parameters of the treatment technologies. Treatment levels and site configurations have been combined into six TRUW management alternatives for study in the WM PEIS. This supplemental report to the WM PEIS gives the projected waste loads and contaminant release profiles for DOE treatment sites under each of the six TRUW management alternatives. It gives TRUW characteristics and inventories for current DOE generation and storage sites, describes the treatment technologies for three proposed levels of TRUW treatment, and presents the representative unit operation parameters of the treatment technologies. The data presented are primary inputs to developing the costs, health risks, and socioeconomic and environmental impacts of treating, packaging, and shipping TRUW for disposal.

  10. Hazard Evaluation for Storage of Spent Nuclear Fuel (SNF) Sludge at the Solid Waste Treatment Facility

    SciTech Connect (OSTI)

    SCHULTZ, M.V.

    2000-08-22

    As part of the Spent Nuclear Fuel (SNF) storage basin clean-up project, sludge that has accumulated in the K Basins due to corrosion of damaged irradiated N Reactor will be loaded into containers and placed in interim storage. The Hanford Site Treatment Complex (T Plant) has been identified as the location where the sludge will be stored until final disposition of the material occurs. Long term storage of sludge from the K Basin fuel storage facilities requires identification and analysis of potential accidents involving sludge storage in T Plant. This report is prepared as the initial step in the safety assurance process described in DOE Order 5480.23, Nuclear Safety Analysis Reports and HNF-PRO-704, Hazards and Accident Analysis Process. This report documents the evaluation of potential hazards and off-normal events associated with sludge storage activities. This information will be used in subsequent safety analyses, design, and operations procedure development to ensure safe storage. The hazards evaluation for the storage of SNF sludge in T-Plant used the Hazards and Operability Analysis (HazOp) method. The hazard evaluation identified 42 potential hazardous conditions. No hazardous conditions involving hazardous/toxic chemical concerns were identified. Of the 42 items identified in the HazOp study, eight were determined to have potential for onsite worker consequences. No items with potential offsite consequences were identified in the HazOp study. Hazardous conditions with potential onsite worker or offsite consequences are candidates for quantitative consequence analysis. The hazardous conditions with potential onsite worker consequences were grouped into two event categories, Container failure due to overpressure - internal to T Plant, and Spill of multiple containers. The two event categories will be developed into accident scenarios that will be quantitatively analyzed to determine release consequences. A third category, Container failure due to

  11. Analysis of the technical capabilities of DOE sites for disposal of residuals from the treatment of mixed low-level waste

    SciTech Connect (OSTI)

    Waters, R.D.; Gruebel, M.M.; Langkopf, B.S.; Kuehne, P.B.

    1997-04-01

    The US Department of Energy (DOE) has stored or expects to generate over the next five years more than 130,000 m{sup 3} of mixed low-level waste (MLLW). Before disposal, MLLW is usually treated to comply with the land disposal restrictions of the Resource Conservation and Recovery Act. Depending on the type of treatment, the original volume of MLLW and the radionuclide concentrations in the waste streams may change. These changes must be taken into account in determining the necessary disposal capacity at a site. Treatment may remove the characteristic in some waste that caused it to be classified as mixed. Treatment of some waste may, by reduction of the mass, increase the concentrations of some transuranic radionuclides sufficiently so that it becomes transuranic waste. In this report, the DOE MLLW streams were analyzed to determine after-treatment volumes and radionuclide concentrations. The waste streams were reclassified as residual MLLW or low-level or transuranic waste resulting from treatment. The volume analysis indicated that about 89,000 m{sup 3} of waste will require disposal as residual MLLW. Fifteen DOE sites were then evaluated to determine their capabilities for hosting disposal facilities for some or all of the residual MLLW. Waste streams associated with about 90% of the total residual MLLW volume are likely to present no significant issues for disposal and require little additional analysis. Future studies should focus on the remaining waste streams that are potentially problematic by examining site-specific waste acceptance criteria, alternative treatment processes, alternative waste forms for disposal, and pending changes in regulatory requirements.

  12. High Performance Zero-Bleed CLSM/Grout Mixes for High-Level Waste Tank Closures Strategic Research and Development - FY99 Report

    SciTech Connect (OSTI)

    Langton, C.A.

    2000-08-11

    The overall objective of this program, SRD-99-08, was to design and test suitable materials, which can be used to close high-level waste tanks at SRS. Fill materials can be designed to perform several functions including chemical stabilization and/or physical encapsulation of incidental waste so that the potential for transport of contaminants into the environment is reduced. Also they are needed to physically stabilize the void volume in the tanks to prevent/minimize future subsidence and inadvertent intrusion. The intent of this work was to develop a zero-bleed soil CLSM (ZBS-CLSM) and a zero-bleed concrete mix (ZBC) which meet the unique placement and stabilization/encapsulation requirements for high-level waste tank closures. These mixes in addition to the zero-bleed CLSM mixes formulated for closure of Tanks 17-F and 20-F provide design engineers with a suite of options for specifying materials for future tank closures.

  13. Preliminary data from an instantaneous profile test conducted near the Mixed Waste Landfill, Technical Area 3, Sandia National Laboratories/New Mexico

    SciTech Connect (OSTI)

    Bayliss, S.C.; Goering, T.J.; McVey, M.D.; Strong, W.R.; Peace, J.L.

    1996-04-01

    This paper presents data from an instantaneous profile test conducted near the Sandia National Laboratories/New Mexico Mixed Waste Landfill in Technical Area 3. The test was performed from December 1993 through 1995 as part of the environmental Restoration Project`s Phase 2 RCRA Facility Investigation of the Mixed Waste Landfill. The purpose of the test was to measure the unsaturated hydraulic properties of soils near the Mixed Waste Landfill. The instantaneous profile test and instrumentation are described, and the pressure and moisture content data from the test are presented. These data may be useful for understanding the unsaturated hydraulic properties of soils in Technical Area 3 and for model validation, verification, and calibration.

  14. Design Case Summary. Production of Mixed Alcohols from Municipal Solid Waste via Gasification

    SciTech Connect (OSTI)

    Valkenburg, C.; Zhu, Y.; Walton, C. W.; Thompson, B. L.; Gerber, M. A.; Jones, S. B.; Stevens, D. J.

    2010-03-01

    The Biomass Program develops design cases to understand the current state of conversion technologies and to determine where improvements need to take place in the future. This design case establishes cost targets for converting MSW to ethanol and other mixed alcohols via gasification.

  15. Innovative cross-flow membrane system for volume reduction of mixed waste

    SciTech Connect (OSTI)

    Greene, W.

    1997-10-01

    In this task, SpinTek Membrane Systems, Inc., and the Institute of Gas Technology are completing engineering development leading to a full-scale demonstration of the SpinTek ST-II High Shear Rotary Membrane Filtration System (ST-II) under a Program Research and Development Agreement (PRDA) with the Federal Energy Technology Center-Morgantown. The SpinTek ST-II technology will be scaled-up, and a two-stage ST-II system will be designed, constructed, and operated on both surrogate and actual feed at the Los Alamos National Laboratory (LANL) Liquid Radioactive Waste Treatment Facility (LRWTF). Results from these studies on both surrogate and actual wastewater streams will also be used by LANL personnel to produce a model for determining the applicability and economics of the SpinTek ST-II system to other DOE waste and process streams. The ST-II is a unique, compact cross-flow membrane system having several advantages in performance and cost compared to currently available systems. Staff at LANL have performed pilot-scale testing with the SpinTek technology to evaluate its feasibility for enhanced radionuclide removal from wastewater at its 5- to 8-million-gallon-per-year LRWTF. Recent data have shown the system`s capabilities to remove radionuclides from the waste stream at concentration factors greater than 2000:1, and performance has exceeded both conventional and all other advanced technologies examined.

  16. In-situ radiation measurements of the C1 and C2 waste storage tank vault

    SciTech Connect (OSTI)

    Yong, L.K.; Womble, P.C.; Weems, L.D.

    1996-09-01

    In August of 1996, the Applied Radiation Measurements Department (ARMD) of the Waste Management and Remedial Action Division (WMRAD) at Oak Ridge National Laboratory (ORNL) was tasked with characterizing the radiation fields in the C{sub 1} and C{sub 2} Liquid Low Level Waste (LLLW) tank vault located at ORNL. These in-situ measurements were made to provide data for evaluating the potential radiological conditions for personnel working in or around the vault during future planned activities. This report describes the locations where measurements were made, the types of radiation detection instruments used, the methods employed, the problems encountered and resolved, and discusses the results obtained.

  17. Corrosion Control Measures For Liquid Radioactive Waste Storage Tanks At The Savannah River Site

    SciTech Connect (OSTI)

    Wiersma, B. J.; Subramanian, K. H.

    2012-11-27

    The Savannah River Site has stored radioactive wastes in large, underground, carbon steel tanks for approximately 60 years. An assessment of potential degradation mechanisms determined that the tanks may be vulnerable to nitrate- induced pitting corrosion and stress corrosion cracking. Controls on the solution chemistry and temperature of the wastes are in place to mitigate these mechanisms. These controls are based upon a series of experiments performed using simulated solutions on materials used for construction of the tanks. The technical bases and evolution of these controls is presented in this paper.

  18. Method for extracting metals from aqueous waste streams for long term storage

    DOE Patents [OSTI]

    Chaiko, David J.

    1995-01-01

    A liquid--liquid extraction method for removing metals and hydrous metal colloids from waste streams is provided wherein said waste streams are contacted with a solvent system containing a water-in-oil microemulsion wherein the inverted micelles contain the extracted metal. A silicon alkoxide, either alone or in combination with other metal alkoxide compounds is added to the water-in-oil microemulsion, thereby allowing encapsulation of the extracted metal within a silicon oxide network. Lastly, the now-encapsulated metal is precipitated from the water-in-oil microemulsion phase to yield aggregates of metal-silicate particles having average individual particle sizes of approximately 40 nanometers.

  19. Method for extracting metals from aqueous waste streams for long term storage

    DOE Patents [OSTI]

    Chaiko, D.J.

    1995-03-07

    A liquid-liquid extraction method for removing metals and hydrous metal colloids from waste streams is provided wherein said waste streams are contacted with a solvent system containing a water-in-oil microemulsion wherein the inverted micelles contain the extracted metal. A silicon alkoxide, either alone or in combination with other metal alkoxide compounds is added to the water-in-oil microemulsion, thereby allowing encapsulation of the extracted metal within a silicon oxide network. Lastly, the now-encapsulated metal is precipitated from the water-in-oil microemulsion phase to yield aggregates of metal-silicate particles having average individual particle sizes of approximately 40 nanometers. 2 figs.

  20. Method for extracting metals from aqueous waste streams for long term storage

    DOE Patents [OSTI]

    Chaiko, D.J.

    1993-01-01

    A liquid-liquid extraction method for removing metals and hydrous metal colloids from waste streams is provided wherein said waste streams are contacted with a solvent system containing a water-in-oil microemulsion wherein the inverted micelles contain the extracted metal. A silicon alkoxide, either alone or in combination with other metal alkoxide compounds is added to the water-in-oil microemulsion, thereby allowing encapsulation of the extracted metal within a silicon oxide network. Lastly, the now-encapsulated metal is precipitated from the water-in-oil microemulsion phase to yield aggregates of metal-silicate particles having average. individual particle sizes of approximately 40 manometers.

  1. Idaho Nuclear Technology and Engineering Center Newly Generated Liquid Waste Demonstration Project Feasibility Study

    SciTech Connect (OSTI)

    Herbst, A.K.

    2000-02-01

    A research, development, and demonstration project for the grouting of newly generated liquid waste (NGLW) at the Idaho Nuclear Technology and Engineering Center is considered feasible. NGLW is expected from process equipment waste, decontamination waste, analytical laboratory waste, fuel storage basin waste water, and high-level liquid waste evaporator condensate. The potential grouted waste would be classed as mixed low-level waste, stabilized and immobilized to meet RCRA LDR disposal in a grouting process in the CPP-604 facility, and then transported to the state.

  2. Phase 5 storage (Project W-112) Central Waste Complex operational readiness review, final report

    SciTech Connect (OSTI)

    Wight, R.H.

    1997-05-30

    This document is the final report for the RFSH conducted, Contractor Operational Readiness Review (ORR) for the Central Waste Complex (CWC) Project W-112 and Interim Safety Basis implementation. As appendices, all findings, observations, lines of inquiry and the implementation plan are included.

  3. Compliance matrix for the Mixed Waste Disposal Facilities, Trenches 31 and 34, burial ground 218-W-5. Revision 1

    SciTech Connect (OSTI)

    Carlyle, D.W.

    1994-12-30

    The purpose of the Trench 31 and 34 Mixed Waste Disposal Facility Compliance Matrix is to provide objective evidence of implementation of all regulatory and procedural--institutional requirements for the disposal facilities. This matrix provides a listing of the individual regulatory and procedural--institutional requirements that were addressed. Subject matter experts reviewed pertinent documents that had direct or indirect impact on the facility. Those found to be applicable were so noted and listed in Appendix A. Subject matter experts then extracted individual requirements from the documents deemed applicable and listed them in the matrix tables. The results of this effort are documented in Appendix B. The implementing compliance documentation for WHC-CM manuals is not included in Appendix B because these are, by definition, implementing documents.

  4. GAS-GENERATION EXPERIMENTS FOR LONG-TERM STORAGE OF TRU WASTES AT WIPP

    SciTech Connect (OSTI)

    Felicione, F.S.; Carney, K.P.; Dwight, C.C.; Cummings, D.G.; Foulkrod, L.E.

    2003-02-27

    An experimental investigation was conducted for gas generation in contact-handled transuranic (CH-TRU) wastes subjected for several years to conditions similar to those expected to occur at the Waste Isolation Pilot Plant (WIPP) should the repository eventually become inundated with brine. Various types of actual CH-TRU wastes were placed into 12 corrosion-resistant vessels. The vessels were loosely filled with the wastes, which were submerged in synthetic brine having the same chemical composition as that in the WIPP vicinity. The vessels were also inoculated with microbes found in the Salado Formation at WIPP. The vessels were sealed, purged, and the approximately 750-ml headspace was pressurized with nitrogen gas to approximately 146 atmospheres to create anoxic conditions at the lithostatic pressure expected in the repository were it inundated. The temperature was maintained at the expected 30 C. The test program objective was to measure the quantities and species of gases generate d by metal corrosion, radiolysis, and microbial activity. These data will assist in the specification of the rates at which gases are produced under inundated repository conditions for use in the WIPP Performance Assessment computer models. These experiments were very carefully designed, constructed, instrumented, and performed. Approximately 6-1/2 years of continuous, undisturbed testing were accumulated. Several of the vessels showed significantly elevated levels of generated gases, virtually all of which was hydrogen. One vessel measured over 4.2% hydrogen, by volume. Two other vessels generated well over 1% hydrogen, and another was at nearly 1%. Only small quantities of other gases, principally carbon dioxide, were detected. Gas generation was found to depend strongly on the waste composition. The maximum hydrogen generation occurred in tests containing carbon steel. Average corrosion penetration rates in carbon-steel of up to 2.3 microns per year were deduced. Conversion of

  5. High-level waste storage tank farms/242-A evaporator standards/requirements identification document (S/RID), Vol. 7

    SciTech Connect (OSTI)

    Not Available

    1994-04-01

    This Requirements Identification Document (RID) describes an Occupational Health and Safety Program as defined through the Relevant DOE Orders, regulations, industry codes/standards, industry guidance documents and, as appropriate, good industry practice. The definition of an Occupational Health and Safety Program as specified by this document is intended to address Defense Nuclear Facilities Safety Board Recommendations 90-2 and 91-1, which call for the strengthening of DOE complex activities through the identification and application of relevant standards which supplement or exceed requirements mandated by DOE Orders. This RID applies to the activities, personnel, structures, systems, components, and programs involved in maintaining the facility and executing the mission of the High-Level Waste Storage Tank Farms.

  6. Final Report: Fiscal Year 1997 demonstration of omnivorous non-thermal mixed waste treatment: Direct chemical oxidation of organic solids and liquids using peroxydisulfate

    SciTech Connect (OSTI)

    Cooper, J.F.

    1998-01-01

    Direct Chemical Oxidation (DCO) is a non-thermal, ambient pressure, aqueous-based technology for the oxidative destruction of the organic components of hazardous or mixed waste streams. The process has been developed for applications in waste treatment, chemical demilitarization and decontamination at LLNL since 1992. The process uses solutions of the peroxydisulfate ion (typically sodium or ammonium salts) to completely mineralize the organics to carbon dioxide and water. The expended oxidant may be electrolytically regenerated to minimize secondary waste. The paper briefly describes: free radical and secondary oxidant formation; electrochemical regeneration; offgas stream; and throughput.

  7. Refinement of Modeling Techniques for the Structural Evaluation of Hanford Single-Shell Nuclear Waste Storage Tanks

    SciTech Connect (OSTI)

    Karri, Naveen K.; Rinker, Michael W.; Johnson, Kenneth I.; Bapanapalli, Satish K.

    2012-11-10

    ABSTRACT Several tanks at the Hanford Site (in Washington State, USA) belong to the first generation of underground nuclear waste storage tanks known as single shell tanks (SSTs). These tanks were constructed between 1943 and 1964 and are well beyond their design life. This article discusses the structural analysis approach and modeling challenges encountered during the ongoing analysis of record (AOR) for evaluating the structural integrity of the SSTs. There are several geometrical and material nonlinearities and uncertainties to be dealt with while performing the modern finite element analysis of these tanks. The analysis takes into account the temperature history of the tanks and allowable mechanical operating loads of these tanks for proper estimation of creep strains and thermal degradation of material properties. The loads prescribed in the AOR models also include anticipated loads that these tanks may see during waste retrieval and closure. Due to uncertainty in a number of inputs to the models, sensitivity studies were conducted to address questions related to the boundary conditions to realistically or conservatively represent the influence of surrounding tanks in a tank farm, the influence of backfill excavation slope, the extent of backfill and the total extent of undisturbed soil surrounding the backfill. Because of the limited availability of data on the thermal and operating history for many of the individual tanks, some of the data was assumed or interpolated. However, the models developed for the analysis of record represent the bounding scenarios and include the loading conditions that the tanks were subjected to or anticipated. The modeling refinement techniques followed in the AOR resulted in conservative estimates for force and moment demands at various sections in the concrete tanks. This article discusses the modeling aspects related to Type-II and Type-III SSTs. The modeling techniques, methodology and evaluation criteria developed for

  8. Comparative assessment of status and opportunities for carbon Dioxide Capture and storage and Radioactive Waste Disposal In North America

    SciTech Connect (OSTI)

    Oldenburg, C.; Birkholzer, J.T.

    2011-07-22

    Aside from the target storage regions being underground, geologic carbon sequestration (GCS) and radioactive waste disposal (RWD) share little in common in North America. The large volume of carbon dioxide (CO{sub 2}) needed to be sequestered along with its relatively benign health effects present a sharp contrast to the limited volumes and hazardous nature of high-level radioactive waste (RW). There is well-documented capacity in North America for 100 years or more of sequestration of CO{sub 2} from coal-fired power plants. Aside from economics, the challenges of GCS include lack of fully established legal and regulatory framework for ownership of injected CO{sub 2}, the need for an expanded pipeline infrastructure, and public acceptance of the technology. As for RW, the USA had proposed the unsaturated tuffs of Yucca Mountain, Nevada, as the region's first high-level RWD site before removing it from consideration in early 2009. The Canadian RW program is currently evolving with options that range from geologic disposal to both decentralized and centralized permanent storage in surface facilities. Both the USA and Canada have established legal and regulatory frameworks for RWD. The most challenging technical issue for RWD is the need to predict repository performance on extremely long time scales (10{sup 4}-10{sup 6} years). While attitudes toward nuclear power are rapidly changing as fossil-fuel costs soar and changes in climate occur, public perception remains the most serious challenge to opening RW repositories. Because of the many significant differences between RWD and GCS, there is little that can be shared between them from regulatory, legal, transportation, or economic perspectives. As for public perception, there is currently an opportunity to engage the public on the benefits and risks of both GCS and RWD as they learn more about the urgent energy-climate crisis created by greenhouse gas emissions from current fossil-fuel combustion practices.

  9. Refinement of Modeling Techniques for the Structural Evaluation of Hanford Single-Shell Nuclear Waste Storage Tanks

    SciTech Connect (OSTI)

    Karri, Naveen K.; Rinker, Michael W.; Johnson, Kenneth I.; Bapanapalli, Satish K.

    2012-03-01

    Abstract: A total of 149 tanks out of 177 at the Hanford Site (in Washington State, USA) belong to the first generation of underground nuclear waste storage tanks known as single shell tanks (SSTs). These tanks were constructed between 1943 and 1964 and are well beyond their design life. All the SSTs had been removed from active service by November 1980 and have been later interim stabilized by removing the pumpable liquids. The remaining waste in the tanks is in the form of salt cake and sludge awaiting r permanent disposal.. The evaluation of the structural integrity of these tanks is of utmost importance not only for the continued safe storage of the waste until waste retrieval and closure, but also to assure safe retrieval and closure operations. This article discusses the structural analysis approach, modeling challenges and issues encountered during the ongoing analysis of record (AOR) for evaluating the structural integrity of the SSTs. There are several geometrical and material nonlinearities and uncertainties to be dealt with while performing the modern finite element analysis of these tanks. Several studies were conducted to refine the models in order to minimize modeling artifacts introduced by soil arching, boundary effects, concrete cracking, and concrete-soil interface behavior. The analysis takes into account the temperature history of the tanks and allowable mechanical operating loads of these tanks for proper estimation of creep strains and thermal degradation of material properties. The loads imposed in the AOR models also include anticipated loads that these tanks may see during waste retrieval and closure. Due to uncertainty in a number of inputs to the models, sensitivity studies were conducted to address questions related to the boundary conditions to realistically or conservatively represent the influence of surrounding tanks in a tank farm, the influence of backfill excavation slope, the extent of backfill and the total extent of undisturbed

  10. Pyrolysis and hydrolysis of mixed polymer waste comprising polyethylene-terephthalate and polyethylene to sequentially recover [monomers

    DOE Patents [OSTI]

    Evans, R.J.; Chum, H.L.

    1998-10-13

    A process is described for using fast pyrolysis in a carrier gas to convert a plastic waste feed stream having a mixed polymeric composition in a manner such that pyrolysis of a given polymer to its high value monomeric constituent occurs prior to pyrolysis of other plastic components therein comprising: selecting a first temperature program range to cause pyrolysis of said given polymer to its high value monomeric constituent prior to a temperature range that causes pyrolysis of other plastic components; selecting a catalyst and support for treating said feed streams with said catalyst to effect acid or base catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent in said temperature program range; differentially heating said feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of the high value monomeric constituent prior to pyrolysis of other plastic components; separating the high value monomeric constituents; selecting a second higher temperature range to cause pyrolysis of a different high value monomeric constituent of said plastic waste and differentially heating the feed stream at the higher temperature program range to cause pyrolysis of the different high value monomeric constituent; and separating the different high value monomeric constituent. 83 figs.

  11. A decision methodology for the evaluation of mixed low-level radioactive waste management options for DOE sites

    SciTech Connect (OSTI)

    Bassi, J.; Abashian, M.S.; Chakraborti, S.; Devarakonda, M.; Djordjevic, S.M.

    1993-03-01

    Currently, many DOE sites are developing site-specific solutions to manage their mixed low-level wastes. These site-specific MLLW programs often result in duplication of efforts between the different sites, and consequently, inefficient use of DOE system resources. A nationally integrated program for MLLW eliminates unnecessary duplication of effort, but requires a comprehensive analysis of waste management options to ensure that all site issues are addressed. A methodology for comprehensive analysis of the complete DOE MLLW system is being developed by DOE-HQ to establish an integrated and standardized solution for managing MLLW. To be effective, the comprehensive systems analysis must consider all aspects of MLLW management from cradle-to-grave (i.e. from MLLW generation to disposal). The results of the analysis will include recommendations for alternative management options for the complete DOE MLLW system based on various components such as effectiveness, cost, health and safety risks, and the probability of regulatory acceptance for an option. Because of the diverse nature of these various components and the associated difficulties in comparing between them, a decision methodology is being developed that will integrate the above components into a single evaluation scheme for performing relative comparisons between different MLLW management options. The remainder of this paper provides an overview of the roles and responsibilities of the various participants of the DOE MLLW Program, and discusses in detail the components involved in the development of the decision methodology for a comprehensive systems analysis.

  12. High-level waste storage tank farms/242-A evaporator Standards/Requirements Identification Document (S/RID), Volume 7. Revision 1

    SciTech Connect (OSTI)

    Burt, D.L.

    1994-04-01

    The High-Level Waste Storage Tank Farms/242-A Evaporator Standards/Requirements Identification Document (S/RID) is contained in multiple volumes. This document (Volume 7) presents the standards and requirements for the following sections: Occupational Safety and Health, and Environmental Protection.

  13. Operations and Maintenance Concept Plan for the Immobilized High Level Waste (IHLW) Interim Storage Facility

    SciTech Connect (OSTI)

    JANIN, L.F.

    2000-08-30

    This O&M Concept looks at the future operations and maintenance of the IHLW/CSB interim storage facility. It defines the overall strategy, objectives, and functional requirements for the portion of the building to be utilized by Project W-464. The concept supports the tasks of safety basis planning, risk mitigation, alternative analysis, decision making, etc. and will be updated as required to support the evolving design.

  14. Time and motion study for alternative mixed low-level waste treatment systems

    SciTech Connect (OSTI)

    Biagi, C.; Vetromile, J.; Teheranian, B.

    1997-02-01

    The time and motion study was developed to look at time-related aspects of the technologies and systems studied in the Integrated Thermal Treatment Systems (ITTS) and Integrated Nonthermal Treatment Systems (INTS) studies. The INTS and ITTS studies combined technologies into systems and subsystems for evaluation. The system approach provides DOE a method of measuring advantages and disadvantages of the many technologies currently being researched. For example, technologies which are more likely to create secondary waste or require extensive pretreatment handling may be less desirable than technologies which require less support from other processes. The time and motion study was designed to address the time element in the INTS and ITTS systems studies. Previous studies have focused on material balance, cost, technical effectiveness, regulatory issues, community acceptance, and operability. This study looks at system dynamics by estimating the treatment time required for a unit of waste, from receipt to certification for shipping. Labor estimates are also developed, based on the time required to do each task for each process. This focus on time highlights critical path processes and potential bottlenecks in the INTS and ITTS systems.

  15. Functional Stability of a Mixed Microbial Consortium Producing PHA From Waste Carbon Sources

    SciTech Connect (OSTI)

    David N. Thompson; Erik R. Coats; William A. Smith; Frank J. Loge; Michael P. Wolcott

    2006-04-01

    Polyhydroxyalkanoates (PHAs) represent an environmentally-effective alternative to synthetic thermoplastics; however, current production practices are not sustainable. In this study, PHA production was accomplished in sequencing batch bioreactors utilizing real wastewaters and mixed microbial consortia from municipal activated sludge as inoculum. Polymer production reached 85%, 53%, and 10% of the cell dry weight from methanol-enriched pulp-and-paper mill foul condensate, fermented municipal primary solids, and biodiesel wastewater, respectively. Employing denaturing gradient gel electrophoresis of 16S-rDNA from PCR-amplified DNA extracts, distinctly different communities were observed between and within wastewaters following enrichment. Most importantly, functional stability was maintained despite differing and contrasting microbial populations.

  16. Seismic design and evaluation guidelines for the Department of Energy High-Level Waste Storage Tanks and Appurtenances

    SciTech Connect (OSTI)

    Bandyopadhyay, K.; Cornell, A.; Costantino, C.; Kennedy, R.; Miller, C.; Veletsos, A.

    1995-10-01

    This document provides seismic design and evaluation guidelines for underground high-level waste storage tanks. The guidelines reflect the knowledge acquired in the last two decades in defining seismic ground motion and calculating hydrodynamic loads, dynamic soil pressures and other loads for underground tank structures, piping and equipment. The application of the guidelines is illustrated with examples. The guidelines are developed for a specific design of underground storage tanks, namely double-shell structures. However, the methodology discussed is applicable for other types of tank structures as well. The application of these and of suitably adjusted versions of these concepts to other structural types will be addressed in a future version of this document. The original version of this document was published in January 1993. Since then, additional studies have been performed in several areas and the results are included in this revision. Comments received from the users are also addressed. Fundamental concepts supporting the basic seismic criteria contained in the original version have since then been incorporated and published in DOE-STD-1020-94 and its technical basis documents. This information has been deleted in the current revision.

  17. Evaluation of methods to measure surface level in waste storage tanks

    SciTech Connect (OSTI)

    Peters, T.J.; Park, W.R.; Cuta, F.M.

    1993-06-01

    This report describes the results of a program conducted at the Pacific Northwest Laboratory (PNL) and Westinghouse Hanford Company (WHC) to identify alternative methods to measure the surface level in the waste tanks. This program examined commercially available devices for measuring the distance to a target. Test were performed with five devices to determine their applicability to measure the surface level in the waste tanks. The devices were the Enraf-Nonius{sup {trademark}} 872 Radar Gauge, the Enraf-Nonius{sup {trademark}} 854 Advanced Technology Gauge, the Stanley Tool Laser Measuring Device, the Robertshaw Inven-Tel{sup {reg_sign}} Precision Level Gauge, and the Micro Switch 942 Acoustic Sensor. In addition, discussions were held with several manufacturer representatives regarding other potential devices.

  18. Imaging through obscurations for sluicing operations in the waste storage tanks

    SciTech Connect (OSTI)

    Peters, T.J.; McMakin, D.L.; Sheen, D.M.; Chieda, M.A.

    1994-08-01

    Waste remediators have identified that surveillance of waste remediation operations and periodic inspections of stored waste are required under very demanding and difficult viewing environments. In many cases, obscurants such as dust or water vapor are generated as part of the remediation activity. Methods are required for viewing or imaging beyond the normal visual spectrum. Work space images guide the movement of remediation equipment, creating a need for rapidly updated, near real-time imaging capability. In addition, there is a need for three-dimensional topographical data to determine the contours of the wastes, to plan retrieval campaigns, and to provide a three-dimensional map of a robot`s work space as basis for collision avoidance. Three basic imaging techniques were evaluated: optical, acoustic and radar. The optical imaging methods that were examined used cameras which operated in the visible region and near-infrared region and infrared cameras which operated in the 3--5 micron and 8--12 micron wavelength regions. Various passive and active lighting schemes were tested, as well as the use of filters to eliminate reflection in the visible region. Image enhancement software was used to extend the range where visual techniques could be used. In addition, the operation of a laser range finder, which operated at 0.835 microns, was tested when fog/water droplets were suspended in the air. The acoustic technique involved using commercial acoustic sensors, operating at approximately 50 kHz and 215 kHz, to determine the attenuation of the acoustic beam in a high-humidity environment. The radar imaging methods involved performing millimeter wave (94 GHz) attenuation measurement sin the various simulated sluicing environments and performing preliminary experimental imaging studies using a W-Band (75--110 GHz) linearly scanned transceiver in a laboratory environment. The results of the tests are discussed.

  19. NEVADA TEST SITE WASTE ACCEPTANCE CRITERIA, JUNE 2006

    SciTech Connect (OSTI)

    U.S. DEPARTMENT OF ENERGY, NATIONAL NUCLEAR SECURITY ADMINISTRATION NEVADA SITE OFFICE

    2006-06-01

    This document establishes the U.S. Department of Energy (DOE), National Nuclear Security Administration Nevada Site Office (NNSA/NSO) waste acceptance criteria (WAC). The WAC provides the requirements, terms, and conditions under which the Nevada Test Site (NTS) will accept low-level radioactive (LLW) and mixed waste (MW) for disposal. It includes requirements for the generator waste certification program, characterization, traceability, waste form, packaging, and transfer. The criteria apply to radioactive waste received at the NTS Area 3 and Area 5 Radioactive Waste Management Complex (RWMC) for storage or disposal.

  20. Radioactive waste storage in mined caverns in crystalline rock: results of field investigations at Stripa, Sweden

    SciTech Connect (OSTI)

    Witherspoon, P.A.

    1980-10-01

    It is generally agreed that the most practicable method of isolating nuclear wastes from the biosphere is by deep burial in suitable geologic formations. Such burial achieves a high degree of physical isolation but raises questions concerning the rate at which some of these wastes may return to the biosphere through transport by groundwater. Any suitable repository site will be disturbed first by excavation and second by the thermal pulse caused by the radioactive decay of the wastes. To assess the effectiveness of geologic isolation it is necessary to develop the capability of predicting the response of a rock mass to such a thermal pulse. Ultimately, this requires field measurements below the surface in media representative of those likely to be encountered at an actual repository. Access to a granitic rock mass adjacent to a defunct iron ore mine at Stripa, Sweden, at a depth of about 350 m below surface has provided a unique opportunity to conduct a comprehensive suite of hydrological and thermo-mechanical experiments under such conditions. The results of these field tests have shown the importance of geologic structure and the functional dependence of the thermo-mechanical properties on temperature in developing a valid predictive model. The results have also demonstrated the vital importance of carrying out large-scale investigations in a field test facility.