National Library of Energy BETA

Sample records for mix gradually shifts

  1. Integrated Water Gas Shift Membrane Reactors Utilizing Novel, Non Precious Metal Mixed Matrix Membrane

    SciTech Connect (OSTI)

    Ferraris, John

    2013-09-30

    Nanoparticles of zeolitic imidazolate frameworks and other related hybrid materials were prepared by modifying published synthesis procedures by introducing bases, changing stoichiometric ratios, or adjusting reaction conditions. These materials were stable at temperatures >300 C and were compatible with the polymer matrices used to prepare mixed- matrix membranes (MMMs). MMMs tested at 300 C exhibited a >30 fold increase in permeability, compared to those measured at 35 C, while maintaining H{sub 2}/CO{sub 2} selectivity. Measurements at high pressure (up to 30 atm) and high temperature (up to 300 C) resulted in an increase in gas flux across the membrane with retention of selectivity. No variations in permeability were observed at high pressures at either 35 or 300 C. CO{sub 2}-induced plasticization was not observed for Matrimid, VTEC, and PBI polymers or their MMMs at 30 atm and 300 C. Membrane surface modification by cross-linking with ethanol diamine resulted in an increase in H{sub 2}/CO{sub 2} selectivity at 35 C. Spectrometric analysis showed that the cross-linking was effective to temperatures <150 C. At higher temperatures, the cross-linked membranes exhibit a H{sub 2}/CO{sub 2} selectivity similar to the uncross-linked polymer. Performance of the polybenzimidazole (PBI) hollow fibers prepared at Santa Fe Science and Technology (SFST, Inc.) showed increased flux o to a flat PBI membrane. A water-gas shift reactor has been built and currently being optimized for testing under DOE conditions.

  2. Fact #647: November 1, 2010 Sales Shifting from Light Trucks to Cars

    Broader source: Energy.gov [DOE]

    From 2005 to 2009 light vehicle sales have gradually shifted toward cars over light trucks. The graph below shows this trend broken down by the major manufacturers. This trend is more evident among...

  3. Gradual Release of Strongly Bound Nitric Oxide from Fe2(NO)2(dobdc) |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Gradual Release of Strongly Bound Nitric Oxide from Fe2(NO)2(dobdc) Previous Next List Bloch, Eric D; Queen, Wendy L; Chavan, Sachin; Wheatley, Paul S.; Zadrozny, Joseph M.; Morris, Russell; Brown, Craig M; Lamberti, Carlo; Bordiga, Silvia; and Long, Jeffrey R, J. Am. Chem. Soc., 137, 3466-3469 (2015) DOI: 10.1021/ja5132243 gradual release Abstract: An iron(II)-based metal-organic framework featuring

  4. Shifting scintillator neutron detector

    DOE Patents [OSTI]

    Clonts, Lloyd G; Cooper, Ronald G; Crow, Jr., Morris Lowell; Hannah, Bruce W; Hodges, Jason P; Richards, John D; Riedel, Richard A

    2014-03-04

    Provided are sensors and methods for detecting thermal neutrons. Provided is an apparatus having a scintillator for absorbing a neutron, the scintillator having a back side for discharging a scintillation light of a first wavelength in response to the absorbed neutron, an array of wavelength-shifting fibers proximate to the back side of the scintillator for shifting the scintillation light of the first wavelength to light of a second wavelength, the wavelength-shifting fibers being disposed in a two-dimensional pattern and defining a plurality of scattering plane pixels where the wavelength-shifting fibers overlap, a plurality of photomultiplier tubes, in coded optical communication with the wavelength-shifting fibers, for converting the light of the second wavelength to an electronic signal, and a processor for processing the electronic signal to identify one of the plurality of scattering plane pixels as indicative of a position within the scintillator where the neutron was absorbed.

  5. Shift End | Y-12 National Security Complex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Shift End Shift End A shift ends and the race for home begins.

  6. Device and method for measuring fluid flow in a conduit having a gradual bend

    DOE Patents [OSTI]

    Ortiz, M.G.; Boucher, T.J.

    1998-11-10

    A system is described for measuring fluid flow in a conduit having a gradual bend or arc, and a straight section. The system includes pressure transducers, one or more disposed in the conduit on the outside of the arc, and one disposed in the conduit in a straight section thereof. The pressure transducers measure the pressure of fluid in the conduit at the locations of the pressure transducers and this information is used by a computational device to calculate fluid flow rate in the conduit. For multi-phase fluid, the density of the fluid is measured by another pair of pressure transducers, one of which is located in the conduit elevationally above the other. The computation device then uses the density measurement along with the fluid pressure measurements, to calculate fluid flow. 1 fig.

  7. Device and method for measuring fluid flow in a conduit having a gradual bend

    DOE Patents [OSTI]

    Ortiz, Marcos German (Idaho Falls, ID); Boucher, Timothy J (Helena, MT)

    1998-01-01

    A system for measuring fluid flow in a conduit having a gradual bend or arc, and a straight section. The system includes pressure transducers, one or more disposed in the conduit on the outside of the arc, and one disposed in the conduit in a straight section thereof. The pressure transducers measure the pressure of fluid in the conduit at the locations of the pressure transducers and this information is used by a computational device to calculate fluid flow rate in the conduit. For multi-phase fluid, the density of the fluid is measured by another pair of pressure transducers, one of which is located in the conduit elevationally above the other. The computation device then uses the density measurement along with the fluid pressure measurements, to calculate fluid flow.

  8. Phase shifting interferometer

    DOE Patents [OSTI]

    Sommargren, G.E.

    1999-08-03

    An interferometer is disclosed which has the capability of measuring optical elements and systems with an accuracy of {lambda}/1000 where {lambda} is the wavelength of visible light. Whereas current interferometers employ a reference surface, which inherently limits the accuracy of the measurement to about {lambda}/50, this interferometer uses an essentially perfect spherical reference wavefront generated by the fundamental process of diffraction. Whereas current interferometers illuminate the optic to be tested with an aberrated wavefront which also limits the accuracy of the measurement, this interferometer uses an essentially perfect spherical measurement wavefront generated by the fundamental process of diffraction. This interferometer is adjustable to give unity fringe visibility, which maximizes the signal-to-noise, and has the means to introduce a controlled prescribed relative phase shift between the reference wavefront and the wavefront from the optics under test, which permits analysis of the interference fringe pattern using standard phase extraction algorithms. 11 figs.

  9. Phase shifting diffraction interferometer

    DOE Patents [OSTI]

    Sommargren, Gary E. (Santa Cruz, CA)

    1996-01-01

    An interferometer which has the capability of measuring optical elements and systems with an accuracy of .lambda./1000 where .lambda. is the wavelength of visible light. Whereas current interferometers employ a reference surface, which inherently limits the accuracy of the measurement to about .lambda./50, this interferometer uses an essentially perfect spherical reference wavefront generated by the fundamental process of diffraction. This interferometer is adjustable to give unity fringe visibility, which maximizes the signal-to-noise, and has the means to introduce a controlled prescribed relative phase shift between the reference wavefront and the wavefront from the optics under test, which permits analysis of the interference fringe pattern using standard phase extraction algorithms.

  10. Phase shifting interferometer

    DOE Patents [OSTI]

    Sommargren, Gary E. (Santa Cruz, CA)

    1999-01-01

    An interferometer which has the capability of measuring optical elements and systems with an accuracy of .lambda./1000 where .lambda. is the wavelength of visible light. Whereas current interferometers employ a reference surface, which inherently limits the accuracy of the measurement to about .lambda./50, this interferometer uses an essentially perfect spherical reference wavefront generated by the fundamental process of diffraction. Whereas current interferometers illuminate the optic to be tested with an aberrated wavefront which also limits the accuracy of the measurement, this interferometer uses an essentially perfect spherical measurement wavefront generated by the fundamental process of diffraction. This interferometer is adjustable to give unity fringe visibility, which maximizes the signal-to-noise, and has the means to introduce a controlled prescribed relative phase shift between the reference wavefront and the wavefront from the optics under test, which permits analysis of the interference fringe pattern using standard phase extraction algorithms.

  11. Phase shifting diffraction interferometer

    DOE Patents [OSTI]

    Sommargren, G.E.

    1996-08-29

    An interferometer which has the capability of measuring optical elements and systems with an accuracy of {lambda}/1000 where {lambda} is the wavelength of visible light. Whereas current interferometers employ a reference surface, which inherently limits the accuracy of the measurement to about {lambda}/50, this interferometer uses an essentially perfect spherical reference wavefront generated by the fundamental process of diffraction. This interferometer is adjustable to give unity fringe visibility, which maximizes the signal-to-noise, and has the means to introduce a controlled prescribed relative phase shift between the reference wavefront and the wavefront from the optics under test, which permits analysis of the interference fringe pattern using standard phase extraction algorithms. 8 figs.

  12. Quantized beam shifts in graphene

    SciTech Connect (OSTI)

    de Melo Kort-Kamp, Wilton Junior; Sinitsyn, Nikolai; Dalvit, Diego Alejandro Roberto

    2015-10-08

    We predict the existence of quantized Imbert-Fedorov, Goos-Hanchen, and photonic spin Hall shifts for light beams impinging on a graphene-on-substrate system in an external magnetic field. In the quantum Hall regime the Imbert-Fedorov and photonic spin Hall shifts are quantized in integer multiples of the fine structure constant ?, while the Goos-Hanchen ones in multiples of ?2. We investigate the influence on these shifts of magnetic field, temperature, and material dispersion and dissipation. An experimental demonstration of quantized beam shifts could be achieved at terahertz frequencies for moderate values of the magnetic field.

  13. Concealed configuration mixing and shape coexistence in the platinum nuclei

    SciTech Connect (OSTI)

    Garcia-Ramos, J. E.; Hellemans, V.; Heyde, K.

    2012-10-20

    The role of configuration mixing in the Pt region is investigated. The nature of the ground state changes smoothly, being spherical around mass A{approx} 174 and A{approx} 192 and deformed around the mid-shell N= 104 region. Interacting Boson Model with configuration mixing calculations are presented for deformations and isotope shifts. The assumption of the existence of two configurations with very different deformation provides a simple framework to explain the observed isotope shifts systematics.

  14. Integrated reformer and shift reactor

    DOE Patents [OSTI]

    Bentley, Jeffrey M.; Clawson, Lawrence G.; Mitchell, William L.; Dorson, Matthew H.

    2006-06-27

    A hydrocarbon fuel reformer for producing diatomic hydrogen gas is disclosed. The reformer includes a first reaction vessel, a shift reactor vessel annularly disposed about the first reaction vessel, including a first shift reactor zone, and a first helical tube disposed within the first shift reactor zone having an inlet end communicating with a water supply source. The water supply source is preferably adapted to supply liquid-phase water to the first helical tube at flow conditions sufficient to ensure discharge of liquid-phase and steam-phase water from an outlet end of the first helical tube. The reformer may further include a first catalyst bed disposed in the first shift reactor zone, having a low-temperature shift catalyst in contact with the first helical tube. The catalyst bed includes a plurality of coil sections disposed in coaxial relation to other coil sections and to the central longitudinal axis of the reformer, each coil section extending between the first and second ends, and each coil section being in direct fluid communication with at least one other coil section.

  15. Scale dependence of entrainment-mixing mechanisms in cumulus clouds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lu, Chunsong; Liu, Yangang; Niu, Shengjie; Endo, Satoshi

    2014-12-17

    This work empirically examines the dependence of entrainment-mixing mechanisms on the averaging scale in cumulus clouds using in situ aircraft observations during the Routine Atmospheric Radiation Measurement Aerial Facility Clouds with Low Optical Water Depths Optical Radiative Observations (RACORO) field campaign. A new measure of homogeneous mixing degree is defined that can encompass all types of mixing mechanisms. Analysis of the dependence of the homogenous mixing degree on the averaging scale shows that, on average, the homogenous mixing degree decreases with increasing averaging scales, suggesting that apparent mixing mechanisms gradually approach from homogeneous mixing to extreme inhomogeneous mixing with increasingmore » scales. The scale dependence can be well quantified by an exponential function, providing first attempt at developing a scale-dependent parameterization for the entrainment-mixing mechanism. The influences of three factors on the scale dependence are further examined: droplet-free filament properties (size and fraction), microphysical properties (mean volume radius and liquid water content of cloud droplet size distributions adjacent to droplet-free filaments), and relative humidity of entrained dry air. It is found that the decreasing rate of homogeneous mixing degree with increasing averaging scales becomes larger with larger droplet-free filament size and fraction, larger mean volume radius and liquid water content, or higher relative humidity. The results underscore the necessity and possibility of considering averaging scale in representation of entrainment-mixing processes in atmospheric models.« less

  16. Scale dependence of entrainment-mixing mechanisms in cumulus clouds

    SciTech Connect (OSTI)

    Lu, Chunsong; Liu, Yangang; Niu, Shengjie; Endo, Satoshi

    2014-12-17

    This work empirically examines the dependence of entrainment-mixing mechanisms on the averaging scale in cumulus clouds using in situ aircraft observations during the Routine Atmospheric Radiation Measurement Aerial Facility Clouds with Low Optical Water Depths Optical Radiative Observations (RACORO) field campaign. A new measure of homogeneous mixing degree is defined that can encompass all types of mixing mechanisms. Analysis of the dependence of the homogenous mixing degree on the averaging scale shows that, on average, the homogenous mixing degree decreases with increasing averaging scales, suggesting that apparent mixing mechanisms gradually approach from homogeneous mixing to extreme inhomogeneous mixing with increasing scales. The scale dependence can be well quantified by an exponential function, providing first attempt at developing a scale-dependent parameterization for the entrainment-mixing mechanism. The influences of three factors on the scale dependence are further examined: droplet-free filament properties (size and fraction), microphysical properties (mean volume radius and liquid water content of cloud droplet size distributions adjacent to droplet-free filaments), and relative humidity of entrained dry air. It is found that the decreasing rate of homogeneous mixing degree with increasing averaging scales becomes larger with larger droplet-free filament size and fraction, larger mean volume radius and liquid water content, or higher relative humidity. The results underscore the necessity and possibility of considering averaging scale in representation of entrainment-mixing processes in atmospheric models.

  17. Gradual degradation of concrete fiber containers and preliminary Safety analysis for the Slovak near-surface repository

    SciTech Connect (OSTI)

    Duran, Juraj

    2007-07-01

    Available in abstract form only. Full text of publication follows: National Radioactive Waste Repository will be used for safe disposal of low and intermediate-level radioactive wastes in Mochovce, Slovak Republic. The Preliminary Safety Analysis Report (PSAR) has developed a conceptual model that strongly overestimated radiological exposures for the Normal Evolution Scenario (NES). Radioactive waste management required additional measures for safe disposal of radioactive waste to minimize the potential consequence to the workers and the public. Use of Fiber Reinforced Containers (FRC) is proposed to enhance the performance of the potential repository for safe disposal of radioactive waste and reduce the probability of exposure. This paper contains the description of models, methods, results from experimental measurements and input data, which were used for probabilistic calculations of the lifetime FRC. The Cumulative Distribution Function (CDF) for the FRC lifetime was used to modify the conceptual model for NES. The model assumed gradual degradation of the FRC and gradual intrusion of water to the repository volume. These assumptions are in contrary to the ones in the PSAR that assumed instantaneous degradation of the FRC and instantaneous fill-up of the repository volume. The model showed that the new assumptions resulted in less radiological consequences, which allows for final design modifications of the repository. (author)

  18. Sylgard Mixing Study

    SciTech Connect (OSTI)

    Bello, Mollie [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Welch, Cynthia F. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Goodwin, Lynne Alese [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Keller, Jennie [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2014-08-22

    Sylgard 184 and Sylgard 186 silicone elastomers form Dow Corning are used as potting agents across the Nuclear Weapons Complex. A standardized mixing procedure is required for filled versions of these products. The present study is a follow-up to a mixing study performed by MST-7 which established the best mixing procedure to use when adding filler to either 184 or 186 base resins. The most effective and consistent method of mixing resin and curing agent for three modified silicone elastomer recipes is outlined in this report. For each recipe, sample size, mixing type, and mixing time was varied over 10 separate runs. The results show that the THINKY Mixer gives reliable mixing over varying batch sizes and mixing times. Hand Mixing can give improved mixing, as indicated by reduced initial viscosity; however, this method is not consistent.

  19. Gradual crossover in molecular organization of stable liquid H{sub 2}O at moderately high pressure and temperature

    SciTech Connect (OSTI)

    Koga, Yoshikata; Westh, Peter; Yoshida, Koh; Inaba, Akira; Nakazawa, Yasuhiro

    2014-09-15

    Using the literature raw data of the speed of sound and the specific volume, the isothermal compressibility, ?{sub T}, a second derivative thermodynamic quantity of G, was evaluated for liquid H{sub 2}O in the pressure range up to 350 MPa and the temperature to 50 C. We then obtained its pressure derivative, d?{sub T}/dp, a third derivative numerically without using a fitting function to the ?{sub T} data. On taking yet another p-derivative at a fixed T graphically without resorting to any fitting function, the resulting d{sup 2}?{sub T}/dp{sup 2}, a fourth derivative, showed a weak but clear step anomaly, with the onset of the step named point X and its end point Y. In analogy with another third and fourth derivative pair in binary aqueous solutions of glycerol, d?{sub p}/dx{sub Gly} and d{sup 2}?{sub p}/dx{sub Gly}{sup 2}, at 0.1 MPa (?{sub p} is the thermal expansivity and x{sub Gly} the mole fraction of solute glycerol) in our recent publication [J. Solution Chem. 43, 663-674 (2014); DOI:10.1007/s10953-013-0122-7], we argue that there is a gradual crossover in the molecular organization of pure H{sub 2}O from a low to a high p-regions starting at point X and ending at Y at a fixed T. The crossover takes place gradually spanning for about 100 MPa at a fixed temperature. The extrapolated temperature to zero p seems to be about 70 80 C for points X and 90 110 C for Y. Furthermore, the mid-points of X and Y seem to extrapolate to the triple point of liquid, ice Ih and ice III. Recalling that the zero x{sub Gly} extrapolation of point X and Y for binary aqueous glycerol at 0.1 MPa gives about the same T values respectively, we suggest that at zero pressure the region below about 70 C the hydrogen bond network is bond-percolated, while above about 90 C there is no hydrogen bond network. Implication of these findings is discussed.

  20. Non-stoichiometric mixed-phase titania photocatalyst

    DOE Patents [OSTI]

    Chen, Le (Lakewood, CO); Gray, Kimberly A. (Evanston, IL); Graham, Michael E. (Evanston, IL)

    2012-06-19

    A mixed anatase-rutile phase, non-stoichiometric titania photocatalyst material is a highly reactive and is a UV and visible light responsive photocastalyst in the as-deposited condition (i.e. without the need for a subsequent thermal treatment). The mixed phase, non-stoichiometric titania thin film material is non-stoichiometric in terms of its oxygen content such that the thin film material shows a marked red-shift in photoresponse.

  1. Mixed oxide solid solutions

    DOE Patents [OSTI]

    Magno, Scott (Dublin, CA); Wang, Ruiping (Fremont, CA); Derouane, Eric (Liverpool, GB)

    2003-01-01

    The present invention is a mixed oxide solid solution containing a tetravalent and a pentavalent cation that can be used as a support for a metal combustion catalyst. The invention is furthermore a combustion catalyst containing the mixed oxide solid solution and a method of making the mixed oxide solid solution. The tetravalent cation is zirconium(+4), hafnium(+4) or thorium(+4). In one embodiment, the pentavalent cation is tantalum(+5), niobium(+5) or bismuth(+5). Mixed oxide solid solutions of the present invention exhibit enhanced thermal stability, maintaining relatively high surface areas at high temperatures in the presence of water vapor.

  2. Fuel Mix Disclosure

    Broader source: Energy.gov [DOE]

    In January 1999, the Colorado Public Utility Commission (PUC) adopted regulations requiring the state's utilities to disclose information regarding their fuel mix to retail customers. Utilities are...

  3. Process Intensification with Integrated Water-Gas-Shift Membrane...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    with Integrated Water-Gas-Shift Membrane Reactor Process Intensification with Integrated Water-Gas-Shift Membrane Reactor PDF icon water-gas-shift.pdf More Documents & Publications ...

  4. In-line phase shift tomosynthesis

    SciTech Connect (OSTI)

    Hammonds, Jeffrey C.; Price, Ronald R.; Pickens, David R.; Donnelly, Edwin F.

    2013-08-15

    Purpose: The purpose of this work is to (1) demonstrate laboratory measurements of phase shift images derived from in-line phase-contrast radiographs using the attenuation-partition based algorithm (APBA) of Yan et al.[Opt. Express 18(15), 1607416089 (2010)], (2) verify that the APBA reconstructed images obey the linearity principle, and (3) reconstruct tomosynthesis phase shift images from a collection of angularly sampled planar phase shift images.Methods: An unmodified, commercially available cabinet x-ray system (Faxitron LX-60) was used in this experiment. This system contains a tungsten anode x-ray tube with a nominal focal spot size of 10 ?m. The digital detector uses CsI/CMOS with a pixel size of 50 50 ?m. The phantoms used consisted of one acrylic plate, two polystyrene plates, and a habanero pepper. Tomosynthesis images were reconstructed from 51 images acquired over a 25 arc. All phase shift images were reconstructed using the APBA.Results: Image contrast derived from the planar phase shift image of an acrylic plate of uniform thickness exceeded the contrast of the traditional attenuation image by an approximate factor of two. Comparison of the planar phase shift images from a single, uniform thickness polystyrene plate with two polystyrene plates demonstrated an approximate linearity of the estimated phase shift with plate thickness (?1600 rad vs ?2970 rad). Tomographic phase shift images of the habanero pepper exhibited acceptable spatial resolution and contrast comparable to the corresponding attenuation image.Conclusions: This work demonstrated the feasibility of laboratory-based phase shift tomosynthesis and suggests that phase shift imaging could potentially provide a new imaging biomarker. Further investigation will be needed to determine if phase shift contrast will be able to provide new tissue contrast information or improved clinical performance.

  5. ADVANCED MIXING MODELS

    SciTech Connect (OSTI)

    Lee, S.; Dimenna, R.; Tamburello, D.

    2011-02-14

    The process of recovering and processing High Level Waste (HLW) the waste in storage tanks at the Savannah River Site (SRS) typically requires mixing the contents of the tank with one to four mixers (pumps) located within the tank. The typical criteria to establish a mixed condition in a tank are based on the number of pumps in operation and the time duration of operation. To ensure that a mixed condition is achieved, operating times are typically set conservatively long. This approach results in high operational costs because of the long mixing times and high maintenance and repair costs for the same reason. A significant reduction in both of these costs might be realized by reducing the required mixing time based on calculating a reliable indicator of mixing with a suitably validated computer code. The focus of the present work is to establish mixing criteria applicable to miscible fluids, with an ultimate goal of addressing waste processing in HLW tanks at SRS and quantifying the mixing time required to suspend sludge particles with the submersible jet pump. A single-phase computational fluid dynamics (CFD) approach was taken for the analysis of jet flow patterns with an emphasis on the velocity decay and the turbulent flow evolution for the farfield region from the pump. Literature results for a turbulent jet flow are reviewed, since the decay of the axial jet velocity and the evolution of the jet flow patterns are important phenomena affecting sludge suspension and mixing operations. The work described in this report suggests a basis for further development of the theory leading to the identified mixing indicators, with benchmark analyses demonstrating their consistency with widely accepted correlations. Although the indicators are somewhat generic in nature, they are applied to Savannah River Site (SRS) waste tanks to provide a better, physically based estimate of the required mixing time. Waste storage tanks at SRS contain settled sludge which varies in height from zero to 10 ft. The sludge has been characterized and modeled as micron-sized solids, typically 1 to 5 microns, at weight fractions as high as 20 to 30 wt%, specific gravities to 1.4, and viscosities up to 64 cp during motion. The sludge is suspended and mixed through the use of submersible slurry jet pumps. To suspend settled sludge, water is added to the tank as a slurry medium and stirred with the jet pump. Although there is considerable technical literature on mixing and solid suspension in agitated tanks, very little literature has been published on jet mixing in a large-scale tank. One of the main objectives in the waste processing is to provide feed of a uniform slurry composition at a certain weight percentage (e.g. typically {approx}13 wt% at SRS) over an extended period of time. In preparation of the sludge for slurrying, several important questions have been raised with regard to sludge suspension and mixing of the solid suspension in the bulk of the tank: (1) How much time is required to prepare a slurry with a uniform solid composition? (2) How long will it take to suspend and mix the sludge for uniform composition in any particular waste tank? (3) What are good mixing indicators to answer the questions concerning sludge mixing stated above in a general fashion applicable to any waste tank/slurry pump geometry and fluid/sludge combination?

  6. Mixing method and apparatus

    DOE Patents [OSTI]

    Green, Norman W. (Redwood City, CA)

    1982-06-15

    Method of mixing particulate materials comprising contacting a primary source and a secondary source thereof whereby resulting mixture ensues; preferably at least one of the two sources has enough motion to insure good mixing and the particulate materials may be heat treated if desired. Apparatus for such mixing comprising an inlet for a primary source, a reactor communicating therewith, a feeding means for supplying a secondary source to the reactor, and an inlet for the secondary source. Feeding means is preferably adapted to supply fluidized materials.

  7. Nearly discontinuous chaotic mixing

    SciTech Connect (OSTI)

    Sharp, David Howland [Los Alamos National Laboratory; Lim, Hyun K [STONYBROOK UNIV.; Yu, Yan [STONYBROOK UNIV.; Glimm, James G [STONYBROOK UNIV.

    2009-01-01

    A new scientific approach is presented for a broad class of chaotic problems involving a high degree of mixing over rapid time scales. Rayleigh-Taylor and Richtmyer-Meshkov unstable flows are typical of such problems. Microscopic mixing properties such as chemical reaction rates for turbulent mixtures can be obtained with feasible grid resolution. The essential dependence of (some) fluid mixing observables on transport phenomena is observed. This dependence includes numerical as well as physical transport and it includes laminar as well as turbulent transport. A new approach to the mathematical theory for the underlying equations is suggested.

  8. Fuel Mix Disclosure

    Broader source: Energy.gov [DOE]

    California's retail electricity suppliers must disclose to all customers the fuel mix used in the generation of electricity. Utilities must use a standard label created by the California Energy...

  9. QCD Sum Rules for Magnetically Induced Mixing between ηc and J/ψ

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cho, Sungtae; Hattori, Koichi; Lee, Su Houng; Morita, Kenji; Ozaki, Sho

    2014-10-20

    We investigate the properties of charmonia in strong magnetic fields by using QCD sum rules. We show how to implement the mixing effects between ηc and J/ψ on the basis of field-theoretical approaches, and then show that the sum rules are saturated by the mixing effects with phenomenologically determined parameters. Consequently, we find that the mixing effects are the dominant contribution to the mass shifts of the static charmonia in strong magnetic fields.

  10. ADVANCED MIXING MODELS

    SciTech Connect (OSTI)

    Lee, S; Richard Dimenna, R; David Tamburello, D

    2008-11-13

    The process of recovering the waste in storage tanks at the Savannah River Site (SRS) typically requires mixing the contents of the tank with one to four dual-nozzle jet mixers located within the tank. The typical criteria to establish a mixed condition in a tank are based on the number of pumps in operation and the time duration of operation. To ensure that a mixed condition is achieved, operating times are set conservatively long. This approach results in high operational costs because of the long mixing times and high maintenance and repair costs for the same reason. A significant reduction in both of these costs might be realized by reducing the required mixing time based on calculating a reliable indicator of mixing with a suitably validated computer code. The work described in this report establishes the basis for further development of the theory leading to the identified mixing indicators, the benchmark analyses demonstrating their consistency with widely accepted correlations, and the application of those indicators to SRS waste tanks to provide a better, physically based estimate of the required mixing time. Waste storage tanks at SRS contain settled sludge which varies in height from zero to 10 ft. The sludge has been characterized and modeled as micron-sized solids, typically 1 to 5 microns, at weight fractions as high as 20 to 30 wt%, specific gravities to 1.4, and viscosities up to 64 cp during motion. The sludge is suspended and mixed through the use of submersible slurry jet pumps. To suspend settled sludge, water is added to the tank as a slurry medium and stirred with the jet pump. Although there is considerable technical literature on mixing and solid suspension in agitated tanks, very little literature has been published on jet mixing in a large-scale tank. If shorter mixing times can be shown to support Defense Waste Processing Facility (DWPF) or other feed requirements, longer pump lifetimes can be achieved with associated operational cost and schedule savings. The focus of the present work is to establish mixing criteria associated with the waste processing at SRS and to quantify the mixing time required to suspend sludge particles with the submersible jet pump. Literature results for a turbulent jet flow are reviewed briefly, since the decay of the axial jet velocity and the evolution of the jet flow patterns are important phenomena affecting sludge suspension and mixing operations. One of the main objectives in the waste processing is to provide the DWPF a uniform slurry composition at a certain weight percentage (typically {approx}13 wt%) over an extended period of time. In preparation of the sludge for slurrying to DWPF, several important questions have been raised with regard to sludge suspension and mixing of the solid suspension in the bulk of the tank: (1) How much time is required to prepare a slurry with a uniform solid composition for DWPF? (2) How long will it take to suspend and mix the sludge for uniform composition in any particular waste tank? (3) What are good mixing indicators to answer the questions concerning sludge mixing stated above in a general fashion applicable to any waste tank/slurry pump geometry and fluid/sludge combination? Grenville and Tilton (1996) investigated the mixing process by giving a pulse of tracer (electrolyte) through the submersible jet nozzle and by monitoring the conductivity at three locations within the cylindrical tank. They proposed that the mixing process was controlled by the turbulent kinetic energy dissipation rate in the region far away from the jet entrance. They took the energy dissipation rates in the regions remote from the nozzle to be proportional to jet velocity and jet diameter at that location. The reduction in the jet velocity was taken to be proportional to the nozzle velocity and distance from the nozzle. Based on their analysis, a correlation was proposed. The proposed correlation was shown to be valid over a wide range of Reynolds numbers (50,000 to 300,000) with a relative standard deviation of {+-} 11.83%. An improved correlat

  11. GreenShift Corporation | Open Energy Information

    Open Energy Info (EERE)

    Corporation Jump to: navigation, search Name: GreenShift Corporation Address: 1 Penn Plaza, Suite 1612 Place: New York, New York Zip: 10119 Region: Northeast - NY NJ CT PA Area...

  12. Community D Mixed/Pine Hardwood D Bottomland Hardwood Mixed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    D Mixed/Pine Hardwood D Bottomland Hardwood _ Mixed Swamp Forest Soils 540 Soils Soil Series and Phase DCh .OrC .Sh .Ta o 540 1080 Meters N A sc Figure 7-2. Plant communities and soils associated with the Mixed Swamp Forest Set-Aside Area. 7-7 Set-Aside 7: Mixed Swamp Forest

  13. Mixed waste: Proceedings

    SciTech Connect (OSTI)

    Moghissi, A.A.; Blauvelt, R.K.; Benda, G.A.; Rothermich, N.E.

    1993-12-31

    This volume contains the peer-reviewed and edited versions of papers submitted for presentation a the Second International Mixed Waste Symposium. Following the tradition of the First International Mixed Waste Symposium, these proceedings were prepared in advance of the meeting for distribution to participants. The symposium was organized by the Mixed Waste Committee of the American Society of Mechanical Engineers. The topics discussed at the symposium include: stabilization technologies, alternative treatment technologies, regulatory issues, vitrification technologies, characterization of wastes, thermal technologies, laboratory and analytical issues, waste storage and disposal, organic treatment technologies, waste minimization, packaging and transportation, treatment of mercury contaminated wastes and bioprocessing, and environmental restoration. Individual abstracts are catalogued separately for the data base.

  14. Mixed crystal organic scintillators

    DOE Patents [OSTI]

    Zaitseva, Natalia P; Carman, M Leslie; Glenn, Andrew M; Hamel, Sebastien; Hatarik, Robert; Payne, Stephen A; Stoeffl, Wolfgang

    2014-09-16

    A mixed organic crystal according to one embodiment includes a single mixed crystal having two compounds with different bandgap energies, the organic crystal having a physical property of exhibiting a signal response signature for neutrons from a radioactive source, wherein the signal response signature does not include a significantly-delayed luminescence characteristic of neutrons interacting with the organic crystal relative to a luminescence characteristic of gamma rays interacting with the organic crystal. According to one embodiment, an organic crystal includes bibenzyl and stilbene or a stilbene derivative, the organic crystal having a physical property of exhibiting a signal response signature for neutrons from a radioactive source.

  15. MixDown

    Energy Science and Technology Software Center (OSTI)

    2010-01-01

    MixDown is a meta-build tool that orchestrates and manages the building of multiple 3rd party libraries. It can manage the downloading, uncompressing, unpacking, patching, configuration, build, and installation of 3rd party libraries using a variety of configuration and build tools. As a meta-build tool, it relies on 3rd party tools such as GNU Autotools, make, Cmake, scons, etc. to actually confugure and build libraries. MixDown includes an extensive database of settings to be used formore » general machines and specific leadership class computing resources.« less

  16. Photoswitchable Red Fluorescent Protein with a Large Stokes Shift...

    Office of Scientific and Technical Information (OSTI)

    Photoswitchable Red Fluorescent Protein with a Large Stokes Shift Citation Details In-Document Search Title: Photoswitchable Red Fluorescent Protein with a Large Stokes Shift ...

  17. Shape-Shifting Plastic (Other) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Other: Shape-Shifting Plastic Citation Details In-Document Search Title: Shape-Shifting ... Save Share this Record Citation Formats MLA APA Chicago Bibtex Export Metadata Endnote ...

  18. Majors' Shift to Natural Gas, The

    Reports and Publications (EIA)

    2001-01-01

    The Majors' Shift to Natural Gas investigates the factors that have guided the United States' major energy producers' growth in U.S. natural gas production relative to oil production. The analysis draws heavily on financial and operating data from the Energy Information Administration's Financial Reporting System (FRS)

  19. Magnetically coupled system for mixing

    DOE Patents [OSTI]

    Miller, III, Harlan; Meichel, George; Legere, Edward; Malkiel, Edwin; Woods, Robert Paul; Ashley, Oliver; Katz, Joseph; Ward, Jason; Petersen, Paul

    2014-04-01

    The invention provides a mixing system comprising a magnetically coupled drive system and a foil for cultivating algae, or cyanobacteria, in an open or enclosed vessel. The invention provides effective mixing, low energy usage, low capital expenditure, and ease of drive system component maintenance while maintaining the integrity of a sealed mixing vessel.

  20. Magnetically coupled system for mixing

    DOE Patents [OSTI]

    Miller, III, Harlan; Meichel, George; Legere, Edward; Malkiel, Edwin; Woods, Robert Paul; Ashley, Oliver; Katz, Joseph; Ward, Jason; Petersen, Paul

    2015-09-22

    The invention provides a mixing system comprising a magnetically coupled drive system and a foil for cultivating algae, or cyanobacteria, in an open or enclosed vessel. The invention provides effective mixing, low energy usage, low capital expenditure, and ease of drive system component maintenance while maintaining the integrity of a sealed mixing vessel.

  1. Device and method for measuring multi-phase fluid flow and density of fluid in a conduit having a gradual bend

    DOE Patents [OSTI]

    Ortiz, M.G.; Boucher, T.J.

    1998-10-27

    A system is described for measuring fluid flow in a conduit having a gradual bend or arc, and a straight section. The system includes pressure transducers, one or more disposed in the conduit on the outside of the arc, and one disposed in the conduit in a straight section thereof. The pressure transducers measure the pressure of fluid in the conduit at the locations of the pressure transducers and this information is used by a computational device to calculate fluid flow rate in the conduit. For multi-phase fluid, the density of the fluid is measured by another pair of pressure transducers, one of which is located in the conduit elevationally above the other. The computation device then uses the density measurement along with the fluid pressure measurements, to calculate fluid flow. 1 fig.

  2. Device and method for measuring multi-phase fluid flow and density of fluid in a conduit having a gradual bend

    DOE Patents [OSTI]

    Ortiz, Marcos German (Idaho Falls, ID); Boucher, Timothy J. (Helena, MT)

    1998-01-01

    A system for measuring fluid flow in a conduit having a gradual bend or arc, and a straight section. The system includes pressure transducers, one or more disposed in the conduit on the outside of the arc, and one disposed in the conduit in a straight section thereof. The pressure transducers measure the pressure of fluid in the conduit at the locations of the pressure transducers and this information is used by a computational device to calculate fluid flow rate in the conduit. For multi-phase fluid, the density of the fluid is measured by another pair of pressure transducers, one of which is located in the conduit elevationally above the other. The computation device then uses the density measurement along with the fluid pressure measurements, to calculate fluid flow.

  3. TH-C-BRD-12: Robust Intensity Modulated Proton Therapy Plan Can Eliminate Junction Shifts for Craniospinal Irradiation

    SciTech Connect (OSTI)

    Liao, L; Jiang, S; Li, Y; Wang, X; Li, H; Zhu, X; Sahoo, N; Gillin, M; Mahajan, A; Grosshans, D; Zhang, X; Lim, G

    2014-06-15

    Purpose: The passive scattering proton therapy (PSPT) technique is the commonly used radiotherapy technique for craniospinal irradiation (CSI). However, PSPT involves many numbers of junction shifts applied over the course of treatment to reduce the cold and hot regions caused by field mismatching. In this work, we introduced a robust planning approach to develop an optimal and clinical efficient techniques for CSI using intensity modulated proton therapy (IMPT) so that junction shifts can essentially be eliminated. Methods: The intra-fractional uncertainty, in which two overlapping fields shift in the opposite directions along the craniospinal axis, are incorporated into the robust optimization algorithm. Treatment plans with junction sizes 3,5,10,15,20,25 cm were designed and compared with the plan designed using the non-robust optimization. Robustness of the plans were evaluated based on dose profiles along the craniospinal axis for the plans applying 3 mm intra-fractional shift. The dose intra-fraction variations (DIV) at the junction are used to evaluate the robustness of the plans. Results: The DIVs are 7.9%, 6.3%, 5.0%, 3.8%, 2.8% and 2.2%, for the robustly optimized plans with junction sizes 3,5,10,15,20,25 cm. The DIV are 10% for the non-robustly optimized plans with junction size 25 cm. The dose profiles along the craniospinal axis exhibit gradual and tapered dose distribution. Using DIVs less than 5% as maximum acceptable intrafractional variation, the overlapping region can be reduced to 10 cm, leading to potential reduced number of the fields. The DIVs are less than 5% for 5 mm intra-fractional shifts with junction size 25 cm, leading to potential no-junction-shift for CSI using IMPT. Conclusion: This work is the first report of the robust optimization on CSI based on IMPT. We demonstrate that robust optimization can lead to much efficient carniospinal irradiation by eliminating the junction shifts.

  4. Stabilizing windings for tilting and shifting modes

    DOE Patents [OSTI]

    Jardin, Stephen C. (Princeton, NJ); Christensen, Uffe R. (Princeton, NJ)

    1984-01-01

    This invention relates to passive conducting loops for stabilizing a plasma ring against unstable tilting and/or shifting modes. To this end, for example, plasma ring in a spheromak is stabilized by a set of four figure-8 shaped loops having one pair on one side of the plasma and one pair on the other side with each pair comprising two loops whose axes are transverse to each other.

  5. Robertsons Ready Mix | Open Energy Information

    Open Energy Info (EERE)

    Ready Mix Jump to: navigation, search Name Robertsons Ready Mix Facility Robertsons Ready Mix Sector Wind energy Facility Type Community Wind Facility Status In Service Owner...

  6. Pendulum Shifts, Context, Error, and Personal Accountability

    SciTech Connect (OSTI)

    Harold Blackman; Oren Hester

    2011-09-01

    This paper describes a series of tools that were developed to achieve a balance in under-standing LOWs and the human component of events (including accountability) as the INL continues its shift to a learning culture where people report, are accountable and interested in making a positive difference - and want to report because information is handled correctly and the result benefits both the reporting individual and the organization. We present our model for understanding these interrelationships; the initiatives that were undertaken to improve overall performance.

  7. Resonance-shifting luminescent solar concentrators

    DOE Patents [OSTI]

    Giebink, Noel Christopher; Wiederrecht, Gary P; Wasielewski, Michael R

    2014-09-23

    An optical system and method to overcome luminescent solar concentrator inefficiencies by resonance-shifting, in which sharply directed emission from a bi-layer cavity into a glass substrate returns to interact with the cavity off-resonance at each subsequent reflection, significantly reducing reabsorption loss en route to the edges. In one embodiment, the system comprises a luminescent solar concentrator comprising a transparent substrate, a luminescent film having a variable thickness; and a low refractive index layer disposed between the transparent substrate and the luminescent film.

  8. Smoothing of mixed complementarity problems

    SciTech Connect (OSTI)

    Gabriel, S.A.; More, J.J.

    1995-09-01

    The authors introduce a smoothing approach to the mixed complementarity problem, and study the limiting behavior of a path defined by approximate minimizers of a nonlinear least squares problem. The main result guarantees that, under a mild regularity condition, limit points of the iterates are solutions to the mixed complementarity problem. The analysis is applicable to a wide variety of algorithms suitable for large-scale mixed complementarity problems.

  9. Fuel Mix and Emissions Disclosure

    Broader source: Energy.gov [DOE]

    Electricity suppliers and electricity companies must also provide a fuel mix report to customers twice annually, within the June and December billing cycles. Emissions information must be disclos...

  10. Mixed Oxide Fuel Fabrication Facility

    National Nuclear Security Administration (NNSA)

    0%2A en Mixed Oxide (MOX) Fuel Fabrication Facility http:nnsa.energy.govfieldofficessavannah-river-field-officemixed-oxide-mox-fuel-fabrication-facility

  11. Automated manual transmission shift sequence controller

    DOE Patents [OSTI]

    Lawrie, Robert E. (Whitmore Lake, MI); Reed, Richard G. (Royal Oak, MI); Rausen, David J. (Denver, CO)

    2000-02-01

    A powertrain system for a hybrid vehicle. The hybrid vehicle includes a heat engine, such as a diesel engine, and an electric machine, which operates as both, an electric motor and an alternator, to power the vehicle. The hybrid vehicle also includes a manual-style transmission configured to operate as an automatic transmission from the perspective of the driver. The engine and the electric machine drive an input shaft which in turn drives an output shaft of the transmission. In addition to driving the transmission, the electric machine regulates the speed of the input shaft in order to synchronize the input shaft during either an upshift or downshift of the transmission by either decreasing or increasing the speed of the input shaft. When decreasing the speed of the input shaft, the electric motor functions as an alternator to produce electrical energy which may be stored by a storage device. Operation of the transmission is controlled by a transmission controller which receives input signals and generates output signals to control shift and clutch motors to effect smooth launch, upshift shifts, and downshifts of the transmission, so that the transmission functions substantially as an automatic transmission from the perspective of the driver, while internally substantially functioning as a manual transmission.

  12. Mixing in polymeric microfluidic devices.

    SciTech Connect (OSTI)

    Schunk, Peter Randall; Sun, Amy Cha-Tien; Davis, Robert H. (University of Colorado at Boulder, Boulder, CO); Brotherton, Christopher M. (University of Colorado at Boulder, Boulder, CO)

    2006-04-01

    This SAND report describes progress made during a Sandia National Laboratories sponsored graduate fellowship. The fellowship was funded through an LDRD proposal. The goal of this project is development and characterization of mixing strategies for polymeric microfluidic devices. The mixing strategies under investigation include electroosmotic flow focusing, hydrodynamic focusing, physical constrictions and porous polymer monoliths. For electroosmotic flow focusing, simulations were performed to determine the effect of electroosmotic flow in a microchannel with heterogeneous surface potential. The heterogeneous surface potential caused recirculations to form within the microchannel. These recirculations could then be used to restrict two mixing streams and reduce the characteristic diffusion length. Maximum mixing occurred when the ratio of the mixing region surface potential to the average channel surface potential was made large in magnitude and negative in sign, and when the ratio of the characteristic convection time to the characteristic diffusion time was minimized. Based on these results, experiments were performed to evaluate the manipulation of surface potential using living-radical photopolymerization. The material chosen to manipulate typically exhibits a negative surface potential. Using living-radical surface grafting, a positive surface potential was produced using 2-(Dimethylamino)ethyl methacrylate and a neutral surface was produced using a poly(ethylene glycol) surface graft. Simulations investigating hydrodynamic focusing were also performed. For this technique, mixing is enhanced by using a tertiary fluid stream to constrict the two mixing streams and reduce the characteristic diffusion length. Maximum mixing occurred when the ratio of the tertiary flow stream flow-rate to the mixing streams flow-rate was maximized. Also, like the electroosmotic focusing mixer, mixing was also maximized when the ratio of the characteristic convection time to the characteristic diffusion time was minimized. Physical constrictions were investigated through simulations. The results show that the maximum mixing occurs when the height of the mixing region is minimized. Finally, experiments were performed to determine the effectiveness of using porous polymer monoliths to enhance mixing. The porous polymer monoliths were constructed using a monomer/salt paste. Two salt crystal size ranges were used; 75 to 106 microns and 53 to 180 microns. Mixing in the porous polymer monoliths fabricated with the 75 to 106 micron salt crystal size range was six times higher than a channel without a monolith. Mixing in the monolith fabricated with the 53 to 180 micron salt crystal size range was nine times higher.

  13. Hick Shifts Gears in NERSC's Storage Systems Group, Takes on...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hick Shifts Gears in NERSC's Storage Systems Group Hick Shifts Gears in NERSC's Storage Systems Group, Takes on New Role October 7, 2015 JasonHick2015 Jason Hick, who has been...

  14. Mixed Waste Working Group report

    SciTech Connect (OSTI)

    Not Available

    1993-11-09

    The treatment of mixed waste remains one of this country`s most vexing environmental problems. Mixed waste is the combination of radioactive waste and hazardous waste, as defined by the Resource Conservation and Recovery Act (RCRA). The Department of Energy (DOE), as the country`s largest mixed waste generator, responsible for 95 percent of the Nation`s mixed waste volume, is now required to address a strict set of milestones under the Federal Facility Compliance Act of 1992. DOE`s earlier failure to adequately address the storage and treatment issues associated with mixed waste has led to a significant backlog of temporarily stored waste, significant quantities of buried waste, limited permanent disposal options, and inadequate treatment solutions. Between May and November of 1993, the Mixed Waste Working Group brought together stakeholders from around the Nation. Scientists, citizens, entrepreneurs, and bureaucrats convened in a series of forums to chart a course for accelerated testing of innovative mixed waste technologies. For the first time, a wide range of stakeholders were asked to examine new technologies that, if given the chance to be tested and evaluated, offer the prospect for better, safer, cheaper, and faster solutions to the mixed waste problem. In a matter of months, the Working Group has managed to bridge a gap between science and perception, engineer and citizen, and has developed a shared program for testing new technologies.

  15. Phase-shifting point diffraction interferometer

    DOE Patents [OSTI]

    Medecki, H.

    1998-11-10

    Disclosed is a point diffraction interferometer for evaluating the quality of a test optic. In operation, the point diffraction interferometer includes a source of radiation, the test optic, a beam divider, a reference wave pinhole located at an image plane downstream from the test optic, and a detector for detecting an interference pattern produced between a reference wave emitted by the pinhole and a test wave emitted from the test optic. The beam divider produces separate reference and test beams which focus at different laterally separated positions on the image plane. The reference wave pinhole is placed at a region of high intensity (e.g., the focal point) for the reference beam. This allows reference wave to be produced at a relatively high intensity. Also, the beam divider may include elements for phase shifting one or both of the reference and test beams. 8 figs.

  16. Phase-shifting point diffraction interferometer

    DOE Patents [OSTI]

    Medecki, Hector

    1998-01-01

    Disclosed is a point diffraction interferometer for evaluating the quality of a test optic. In operation, the point diffraction interferometer includes a source of radiation, the test optic, a beam divider, a reference wave pinhole located at an image plane downstream from the test optic, and a detector for detecting an interference pattern produced between a reference wave emitted by the pinhole and a test wave emitted from the test optic. The beam divider produces separate reference and test beams which focus at different laterally separated positions on the image plane. The reference wave pinhole is placed at a region of high intensity (e.g., the focal point) for the reference beam. This allows reference wave to be produced at a relatively high intensity. Also, the beam divider may include elements for phase shifting one or both of the reference and test beams.

  17. Is the tribimaximal mixing accidental?

    SciTech Connect (OSTI)

    Abbas, Mohammed; Smirnov, A. Yu.

    2010-07-01

    The tribimaximal (TBM) mixing is not accidental if structures of the corresponding leptonic mass matrices follow immediately from certain (residual or broken) flavor symmetry. We develop a simple formalism which allows one to analyze effects of deviations of the lepton mixing from TBM on the structure of the neutrino mass matrix and on the underlying flavor symmetry. We show that possible deviations from the TBM mixing can lead to strong modifications of the mass matrix and strong violation of the TBM-mass relations. As a result, the mass matrix may have an 'anarchical' structure with random values of elements or it may have some symmetry that differs from the TBM symmetry. Interesting examples include matrices with texture zeros, matrices with certain 'flavor alignment' as well as hierarchical matrices with a two-component structure, where the dominant and subdominant contributions have different symmetries. This opens up new approaches to understanding the lepton mixing.

  18. Mixed-mu superconducting bearings

    DOE Patents [OSTI]

    Hull, J.R.; Mulcahy, T.M.

    1998-03-03

    A mixed-mu superconducting bearing is disclosed including a ferrite structure disposed for rotation adjacent a stationary superconductor material structure and a stationary permanent magnet structure. The ferrite structure is levitated by said stationary permanent magnet structure. 9 figs.

  19. Mixed-mu superconducting bearings

    DOE Patents [OSTI]

    Hull, John R. (Hinsdale, IL); Mulcahy, Thomas M. (Western Springs, IL)

    1998-01-01

    A mixed-mu superconducting bearing including a ferrite structure disposed for rotation adjacent a stationary superconductor material structure and a stationary permanent magnet structure. The ferrite structure is levitated by said stationary permanent magnet structure.

  20. Electrostatic shape-shifting ion optics

    DOE Patents [OSTI]

    Dahl, David A.; Scott, Jill R.; Appelhans, Anthony D.

    2006-05-02

    Electrostatic shape-shifting ion optics includes an outer electrode that defines an interior region between first and second opposed open ends. A first inner electrode is positioned within the interior region of the outer electrode at about the first open end. A second inner electrode is positioned within the interior region of the outer electrode at about the second open end. A first end cap electrode is positioned at about a first open end of the first inner electrode so that the first end cap electrode substantially encloses the first open end of the first inner electrode. A second end cap electrode is positioned at about a second open end of the second inner electrode so that the second end cap electrode substantially encloses the second open end of the second inner electrode. A voltage source operatively connected to each of the electrodes applies voltage functions to each of the electrodes to produce an electric field within an interior space enclosed by the electrodes.

  1. Scientists ignite aluminum water mix

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Scientists ignite aluminum water mix Scientists ignite aluminum water mix Don't worry, that beer can you're holding is not going to spontaneously burst into flames. June 30, 2014 Los Alamos National Laboratory chemist Bryce Tappan ignites a small quantity of aluminum nanoparticle water mixture. In open air, the compound burns like a Fourth of July sparkler. Los Alamos National Laboratory chemist Bryce Tappan ignites a small quantity of aluminum nanoparticle water mixture. In open air, the

  2. Overview of mixed waste issues

    SciTech Connect (OSTI)

    Piciulo, P.L.; Bowerman, B.S.; Kempf, C.R.; MacKenzie, D.R.; Siskind, B.

    1986-01-01

    Based on BNL's study it was concluded that there are LLWs which contain chemically hazardous components. Scintillation liquids may be considered an EPA listed hazardous waste and are, therefore, potential mixed wastes. Since November, 1985 no operating LLW disposal site will accept these wastes for disposal. Unless such wastes contain de minimis quantities of radionuclides, they cannot be disposed of at an EPA an EPA permitted site. Currently generators of LSC wastes can ship de minimis wastes to be burned at commercial facilities. Oil wastes will also eventually be an EPA listed waste and thus will have to be considered a potential radioactive mixed wasted unless NRC establishes de minimis levels of radionuclides below which oils can be managed as hazardous wastes. Regarding wastes containing lead metal there is some question as to the extent of the hazard posed by lead disposed in a LLW burial trench. Chromium-containing wastes would have to be tested to determine whether they are potential mixed wastes. There may be other wastes that are mixed wastes; the responsibility for determining this rests with the waste generator. It is believed that there are management options for handling potential mixed wastes but there is no regulatory guidance. BNL has identified and evaluated a variety of treatment options for the management of potential radioactive mixed wastes. The findings of that study showed that application of a management option with the purpose of addressing EPA concern can, at the same time, address stabilization and volume reduction concerns of NRC.

  3. Independent Oversight Review, Advanced Mixed Waste Treatment...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Mixed Waste Treatment Project - April 2013 Independent Oversight Review, Advanced Mixed Waste Treatment Project - April 2013 April 2013 Review of Radiation Protection...

  4. Process Intensification with Integrated Water-Gas-Shift Membrane Reactor |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy with Integrated Water-Gas-Shift Membrane Reactor Process Intensification with Integrated Water-Gas-Shift Membrane Reactor PDF icon water-gas-shift.pdf More Documents & Publications ITP Energy Intensive Processes: Energy-Intensive Processes Portfolio: Addressing Key Energy Challenges Across U.S. Industry Energy-Intensive Processes Portfolio: Addressing Key Energy Challenges Across U.S. Industry Gasification Systems 2013 Project Selections

  5. Etched-multilayer phase shifting masks for EUV lithography

    DOE Patents [OSTI]

    Chapman, Henry N.; Taylor, John S.

    2005-04-05

    A method is disclosed for the implementation of phase shifting masks for EUV lithography. The method involves directly etching material away from the multilayer coating of the mask, to cause a refractive phase shift in the mask. By etching into the multilayer (for example, by reactive ion etching), rather than depositing extra material on the top of the multilayer, there will be minimal absorption loss associated with the phase shift.

  6. Nonlinear frequency shift of electrostatic waves in general collisionl...

    Office of Scientific and Technical Information (OSTI)

    Nonlinear frequency shift of electrostatic waves in general collisionless plasma: Unifying theory of fluid and kinetic nonlinearities Citation Details In-Document Search This...

  7. On the Coulomb shifts of nuclear resonances at low energies

    SciTech Connect (OSTI)

    Takibayev, N.

    2005-05-06

    The relationship between the shift of a resonance and the interacion potential is obtained in the frame of coupling constant evolution method. Analysis of the Coulomb shifts of resonance energies and widths has been carried out for nuclear cluster systems at low energies. The nature of these shifts is investigated in the examples of p, {alpha} and p,6Li scatterings. For simplicity a model using separable potentials describing two-body nuclear scattering resonances. The results of the calculation are in accordance with experimental data. In the case of the two {alpha}-particles system the relationship shows that the Coulomb shift of {alpha}, {alpha}-resonance remains small.

  8. Nature of Coulomb Shifts of Nuclear Scattering Resonances

    SciTech Connect (OSTI)

    Takibayev, N.Zh.

    2005-07-01

    Relations determining the shift of energies and widths of scattering resonances are obtained within the method of evolution in the coupling constant. These relations generalize the well-known relations for the shift of levels in a discrete spectrum. The problem of determining the Coulomb shifts of low-energy resonances manifesting themselves in the cross section for the scattering of some light nuclei is solved. Examples that are of importance for nuclear astrophysics and examples of problems that are associated with the production of chemical elements are considered. The character of Coulomb shifts is studied within simple nuclear models. Respective numerical estimates are given, which agree satisfactorily with experimental data.

  9. PowerSHIFT Biofuels LLC | Open Energy Information

    Open Energy Info (EERE)

    Biofuels LLC Jump to: navigation, search Name: PowerSHIFT Biofuels LLC Place: Wyoming Product: Focused on biodiesel plants and power generation facilities in the US. References:...

  10. Optical transmission through double-layer, laterally shifted...

    Office of Scientific and Technical Information (OSTI)

    shifted metallic subwavelength hole arrays We measure the transmission of infra-red radiation through double-layer metal lms with periodic arrays of subwavelength holes....

  11. PowerSHIFT Energy Company Inc | Open Energy Information

    Open Energy Info (EERE)

    search Name: PowerSHIFT Energy Company Inc Place: Casper, Wyoming Zip: 82605 Sector: Biofuels Product: Wyoming-based biofuels producer. Coordinates: 42.850095, -106.327734...

  12. Nonideal Rayleigh-Taylor mixing

    SciTech Connect (OSTI)

    Sharp, David Howland [Los Alamos National Laboratory; Lin, Hyun K [STONY BROOK UNIV.; Iwerks, Justin G [Los Alamos National Laboratory; Gliman, James G [Los Alamos National Laboratory; [NON LANL

    2009-01-01

    Rayleigh-Taylor mixing is a classical hydrodynamic Instability, which occurs when a light fluid pushes against a heavy fluid. The two main sources of nonideal behavior in Rayleigh-Taylor (RT) mixing are regularizations (physical and numerical) which produce deviations from a pure Euler equation, scale Invariant formulation, and non Ideal (i.e. experimental) initial conditions. The Kolmogorov theory of turbulence predicts stirring at all length scales for the Euler fluid equations without regularization. We Interpret mathematical theories of existence and non-uniqueness in this context, and we provide numerical evidence for dependence of the RT mixing rate on nonideal regularizations, in other words indeterminacy when modeled by Euler equations. Operationally, indeterminacy shows up as non unique solutions for RT mixing, parametrized by Schmidt and Prandtl numbers, In the large Reynolds number (Euler equation) limit. Verification and validation evidence is presented for the large eddy simulation algorithm used here. Mesh convergence depends on breaking the nonuniqueness with explicit use of the laminar Schmidt and PrandtJ numbers and their turbulent counterparts, defined in terms of subgrid scale models. The dependence of the mixing rate on the Schmidt and Prandtl numbers and other physical parameters will be illustrated. We demonstrate numerically the influence of initial conditions on the mixing rate. Both the dominant short wavelength Initial conditions and long wavelength perturbations are observed to playa role. By examination of two classes of experiments, we observe the absence of a single universal explanation, with long and short wavelength initial conditions, and the various physical and numerical regularizations contributing In different proportions In these two different contexts.

  13. Mixed ternary heterojunction solar cell

    DOE Patents [OSTI]

    Chen, Wen S.; Stewart, John M.

    1992-08-25

    A thin film heterojunction solar cell and a method of making it has a p-type layer of mixed ternary I-III-VI.sub.2 semiconductor material in contact with an n-type layer of mixed binary II-VI semiconductor material. The p-type semiconductor material includes a low resistivity copper-rich region adjacent the back metal contact of the cell and a composition gradient providing a minority carrier mirror that improves the photovoltaic performance of the cell. The p-type semiconductor material preferably is CuInGaSe.sub.2 or CuIn(SSe).sub.2.

  14. Advances in compressible turbulent mixing

    SciTech Connect (OSTI)

    Dannevik, W.P.; Buckingham, A.C.; Leith, C.E.

    1992-01-01

    This volume includes some recent additions to original material prepared for the Princeton International Workshop on the Physics of Compressible Turbulent Mixing, held in 1988. Workshop participants were asked to emphasize the physics of the compressible mixing process rather than measurement techniques or computational methods. Actual experimental results and their meaning were given precedence over discussions of new diagnostic developments. Theoretical interpretations and understanding were stressed rather than the exposition of new analytical model developments or advances in numerical procedures. By design, compressibility influences on turbulent mixing were discussed--almost exclusively--from the perspective of supersonic flow field studies. The papers are arranged in three topical categories: Foundations, Vortical Domination, and Strongly Coupled Compressibility. The Foundations category is a collection of seminal studies that connect current study in compressible turbulent mixing with compressible, high-speed turbulent flow research that almost vanished about two decades ago. A number of contributions are included on flow instability initiation, evolution, and transition between the states of unstable flow onset through those descriptive of fully developed turbulence. The Vortical Domination category includes theoretical and experimental studies of coherent structures, vortex pairing, vortex-dynamics-influenced pressure focusing. In the Strongly Coupled Compressibility category the organizers included the high-speed turbulent flow investigations in which the interaction of shock waves could be considered an important source for production of new turbulence or for the enhancement of pre-existing turbulence. Individual papers are processed separately.

  15. Syngas Mixed Alcohol Cost Validation

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1, 2013 DOE Bioenergy Technologies Office: Project Peer Review Syngas Mixed Alcohol Cost Validation Abhijit Dutta, NREL This presentation does not contain any proprietary, confidential, or otherwise restricted information Goal Statement Enable research and development of cost-competitive biomass to liquid fuels by providing: - Techno-economic analysis (TEA) - Feedback to the research efforts Specific objective in 2012: Provide TEA and validate DOE BETO's goal to demonstrate technologies capable

  16. Mixed Alcohol Synthesis Catalyst Screening

    SciTech Connect (OSTI)

    Gerber, Mark A.; White, James F.; Stevens, Don J.

    2007-09-03

    National Renewable Energy Laboratory (NREL) and Pacific Northwest National Laboratory (PNNL) are conducting research to investigate the feasibility of producing mixed alcohols from biomass-derived synthesis gas (syngas). PNNL is tasked with obtaining commercially available or preparing promising mixed-alcohol catalysts and screening them in a laboratory-scale reactor system. Commercially available catalysts and the most promising experimental catalysts are provided to NREL for testing using a slipstream from a pilot-scale biomass gasifier. From the standpoint of producing C2+ alcohols as the major product, it appears that the rhodium catalyst is the best choice in terms of both selectivity and space-time yield (STY). However, unless the rhodium catalyst can be improved to provide minimally acceptable STYs for commercial operation, mixed alcohol synthesis will involve significant production of other liquid coproducts. The modified Fischer-Tropsch catalyst shows the most promise for providing both an acceptable selectivity to C2+ alcohols and total liquid STY. However, further optimization of the Fischer-Tropsch catalysts to improve selectivity to higher alcohols is highly desired. Selection of a preferred catalyst will likely entail a decision on the preferred coproduct slate. No other catalysts tested appear amenable to the significant improvements needed for acceptable STYs.

  17. Spin relaxation and linear-in-electric-field frequency shift...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Spin relaxation and linear-in-electric-field frequency shift in an ... It is found that the rectangular cell geometry admits of a general result for Tsub 1, ...

  18. Optical transmission through double-layer, laterally shifted metallic

    Office of Scientific and Technical Information (OSTI)

    subwavelength hole arrays (Journal Article) | SciTech Connect Journal Article: Optical transmission through double-layer, laterally shifted metallic subwavelength hole arrays Citation Details In-Document Search Title: Optical transmission through double-layer, laterally shifted metallic subwavelength hole arrays We measure the transmission of infra-red radiation through double-layer metal lms with periodic arrays of subwavelength holes. When the two metal lms are placed in su ciently close

  19. Photoswitchable Red Fluorescent Protein with a Large Stokes Shift (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect Photoswitchable Red Fluorescent Protein with a Large Stokes Shift Citation Details In-Document Search Title: Photoswitchable Red Fluorescent Protein with a Large Stokes Shift Authors: Piatkevich, Kiryl D. ; English, Brian P. ; Malashkevich, Vladimir N. ; Xiao, Hui ; Almo, Steven C. ; Singer, Robert H. ; Verkhusha, Vladislav V. [1] ; HHMI) [2] ; Helsinki) [2] + Show Author Affiliations (Einstein) ( Publication Date: 2014-11-19 OSTI Identifier: 1163388 Resource Type:

  20. Mixed Solvent Electrolyte Model | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mixed Solvent Electrolyte Model Mixed Solvent Electrolyte Model Software Tool to Predict Solubility of Solids and Other Thermophysical Properties With assistance from AMO, OLI Systems, Inc., developed the mixed-solvent electrolyte model, a comprehensive physical property package that can predict the properties of electrolyte systems ranging from dilute solutions to fused salts in water, nonaqueous, or mixed solvents. The model accurately predicts the solubility of solids in complex

  1. Thin film mixed potential sensors

    DOE Patents [OSTI]

    Garzon, Fernando H. (Santa Fe, NM); Brosha, Eric L. (Los Alamos, NM); Mukundan, Rangachary (Santa Fe, NM)

    2007-09-04

    A mixed potential sensor for oxidizable or reducible gases and a method of making. A substrate is provided and two electrodes are formed on a first surface of the substrate, each electrode being formed of a different catalytic material selected to produce a differential voltage between the electrodes from electrochemical reactions of the gases catalyzed by the electrode materials. An electrolytic layer of an electrolyte is formed over the electrodes to cover a first portion of the electrodes from direct exposure to the gases with a second portion of the electrodes uncovered for direct exposure to the gases.

  2. Mixing It Up | Department of Energy

    Office of Environmental Management (EM)

    Mixing It Up Mixing It Up June 30, 2015 - 12:00pm Addthis Mixing It Up PADUCAH, Ky. - A 150-foot-tall crane turns an eight-foot-diameter auger performing deep-soil mixing at the Paducah Gaseous Diffusion Plant's southwest groundwater plume. More than 260 borings are being made to a depth of about 60 feet to remove a source of trichloroethene groundwater contamination. Addthis Related Articles A 150-foot-tall crane turns an eight-foot-diameter auger performing deep-soil mixing at the Paducah

  3. Mixed waste characterization reference document

    SciTech Connect (OSTI)

    1997-09-01

    Waste characterization and monitoring are major activities in the management of waste from generation through storage and treatment to disposal. Adequate waste characterization is necessary to ensure safe storage, selection of appropriate and effective treatment, and adherence to disposal standards. For some wastes characterization objectives can be difficult and costly to achieve. The purpose of this document is to evaluate costs of characterizing one such waste type, mixed (hazardous and radioactive) waste. For the purpose of this document, waste characterization includes treatment system monitoring, where monitoring is a supplement or substitute for waste characterization. This document establishes a cost baseline for mixed waste characterization and treatment system monitoring requirements from which to evaluate alternatives. The cost baseline established as part of this work includes costs for a thermal treatment technology (i.e., a rotary kiln incinerator), a nonthermal treatment process (i.e., waste sorting, macronencapsulation, and catalytic wet oxidation), and no treatment (i.e., disposal of waste at the Waste Isolation Pilot Plant (WIPP)). The analysis of improvement over the baseline includes assessment of promising areas for technology development in front-end waste characterization, process equipment, off gas controls, and monitoring. Based on this assessment, an ideal characterization and monitoring configuration is described that minimizes costs and optimizes resources required for waste characterization.

  4. Mixing stops at the LHC

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Agrawal, Prateek; Frugiuele, Claudia

    2014-01-01

    We study the phenomenology of a light stop NLSP in the presence of large mixing with either the first or the second generation. R-symmetric models provide a prime setting for this scenario, but our discussion also applies to the MSSM when a significant amount of mixing can be accommodated. In our framework the dominant stop decay is through the flavor violating mode into a light jet and the LSP in an extended region of parameter space. There are currently no limits from ATLAS and CMS in this region. We emulate shape-based hadronic SUSY searches for this topology, and find thatmore » they have potential sensitivity. If the extension of these analyses to this region is robust, we find that these searches can set strong exclusion limits on light stops. If not, then the flavor violating decay mode is challenging and may represent a blind spot in stop searches even at 13 TeV. Thus, an experimental investigation of this scenario is well motivated.« less

  5. Expandable mixing section gravel and cobble eductor

    DOE Patents [OSTI]

    Miller, Arthur L. (Kenyon, MN); Krawza, Kenneth I. (Lakeville, MN)

    1997-01-01

    In a hydraulically powered pump for excavating and transporting slurries in hich it is immersed, the improvement of a gravel and cobble eductor including an expandable mixing section, comprising: a primary flow conduit that terminates in a nozzle that creates a water jet internal to a tubular mixing section of the pump when water pressure is applied from a primary supply flow; a tubular mixing section having a center line in alignment with the nozzle that creates a water jet; a mixing section/exit diffuser column that envelopes the flexible liner; and a secondary inlet conduit that forms an opening at a bas portion of the column and adjacent to the nozzle and water jet to receive water saturated gravel as a secondary flow that mixes with the primary flow inside of the mixing section to form a combined total flow that exits the mixing section and decelerates in the exit diffuser.

  6. Observation of the Goos-Haenchen Shift with Neutrons

    SciTech Connect (OSTI)

    Haan, Victor-O. de; Plomp, Jeroen; Rekveldt, Theo M.; Kraan, Wicher H.; Well, Ad A. van; Dalgliesh, Robert M.; Langridge, Sean

    2010-01-08

    The Goos-Haenchen effect is a spatial shift along an interface resulting from an interference effect that occurs for total internal reflection. This phenomenon was suggested by Sir Isaac Newton, but it was not until 1947 that the effect was experimentally observed by Goos and Haenchen. We provide the first direct, absolute, experimental determination of the Goos-Haenchen shift for a particle experiencing a potential well as required by quantum mechanics: namely, wave-particle duality. Here, the particle is a spin-polarized neutron reflecting from a film of magnetized material. We detect the effect through a subtle change in polarization of the neutron. Here, we demonstrate, through experiment and theory, that neutrons do exhibit the Goos-Haenchen effect and postulate that the associated time shift should also be observable.

  7. System for computer controlled shifting of an automatic transmission

    DOE Patents [OSTI]

    Patil, Prabhakar B.

    1989-01-01

    In an automotive vehicle having an automatic transmission that driveably connects a power source to the driving wheels, a method to control the application of hydraulic pressure to a clutch, whose engagement produces an upshift and whose disengagement produces a downshift, the speed of the power source, and the output torque of the transmission. The transmission output shaft torque and the power source speed are the controlled variables. The commanded power source torque and commanded hydraulic pressure supplied to the clutch are the control variables. A mathematical model is formulated that describes the kinematics and dynamics of the powertrain before, during and after a gear shift. The model represents the operating characteristics of each component and the structural arrangement of the components within the transmission being controlled. Next, a close loop feedback control is developed to determine the proper control law or compensation strategy to achieve an acceptably smooth gear ratio change, one in which the output torque disturbance is kept to a minimum and the duration of the shift is minimized. Then a computer algorithm simulating the shift dynamics employing the mathematical model is used to study the effects of changes in the values of the parameters established from a closed loop control of the clutch hydraulic and the power source torque on the shift quality. This computer simulation is used also to establish possible shift control strategies. The shift strategies determine from the prior step are reduced to an algorithm executed by a computer to control the operation of the power source and the transmission.

  8. Mixing in SRS Closure Business Unit Applications

    SciTech Connect (OSTI)

    POIRIER, MICHAELR.

    2004-06-23

    The following equipment is commonly used to mix fluids: mechanical agitators, jets (pumps), shrouded axial impeller mixers (Flygt mixers), spargers, pulsed jet mixers, boiling, static mixers, falling films, liquid sprays, and thermal convection. This discussion will focus on mechanical agitators, jets, shrouded axial impeller mixers, spargers, and pulsed jet mixers, as these devices are most likely to be employed in Savannah River Site (SRS) Closure Business applications. In addressing mixing problems in the SRS Tank Farm, one must distinguish between different mixing objectives. These objectives include sludge mixing (e.g., Extended Sludge Processing), sludge retrieval (e.g., sludge transfers between tanks), heel retrieval (e.g., Tanks 18F and 19F), chemical reactions (e.g., oxalic acid neutralization) and salt dissolution. For example, one should not apply sludge mixing guidelines to heel removal applications. Mixing effectiveness is a function of both the mixing device (e.g., slurry pump, agitator, air sparger) and the properties of the material to be mixed (e.g., yield stress, viscosity, density, and particle size). The objective of this document is to provide background mixing knowledge for the SRS Closure Business Unit personnel and to provide general recommendations for mixing in SRS applications.

  9. Extracting Scattering Phase-Shifts in Higher Partial-Waves from...

    Office of Scientific and Technical Information (OSTI)

    Extracting Scattering Phase-Shifts in Higher Partial-Waves from Lattice QCD Calculations Citation Details In-Document Search Title: Extracting Scattering Phase-Shifts in Higher...

  10. Quantifying uncertainty in stable isotope mixing models

    SciTech Connect (OSTI)

    Davis, Paul; Syme, James; Heikoop, Jeffrey; Fessenden-Rahn, Julianna; Perkins, George; Newman, Brent; Chrystal, Abbey E.; Hagerty, Shannon B.

    2015-05-19

    Mixing models are powerful tools for identifying biogeochemical sources and determining mixing fractions in a sample. However, identification of actual source contributors is often not simple, and source compositions typically vary or even overlap, significantly increasing model uncertainty in calculated mixing fractions. This study compares three probabilistic methods, SIAR [Parnell et al., 2010] a pure Monte Carlo technique (PMC), and Stable Isotope Reference Source (SIRS) mixing model, a new technique that estimates mixing in systems with more than three sources and/or uncertain source compositions. In this paper, we use nitrate stable isotope examples (?15N and ?18O) but all methods tested are applicable to other tracers. In Phase I of a three-phase blind test, we compared methods for a set of six-source nitrate problems. PMC was unable to find solutions for two of the target water samples. The Bayesian method, SIAR, experienced anchoring problems, and SIRS calculated mixing fractions that most closely approximated the known mixing fractions. For that reason, SIRS was the only approach used in the next phase of testing. In Phase II, the problem was broadened where any subset of the six sources could be a possible solution to the mixing problem. Results showed a high rate of Type I errors where solutions included sources that were not contributing to the sample. In Phase III some sources were eliminated based on assumed site knowledge and assumed nitrate concentrations, substantially reduced mixing fraction uncertainties and lowered the Type I error rate. These results demonstrate that valuable insights into stable isotope mixing problems result from probabilistic mixing model approaches like SIRS. The results also emphasize the importance of identifying a minimal set of potential sources and quantifying uncertainties in source isotopic composition as well as demonstrating the value of additional information in reducing the uncertainty in calculated mixing fractions.

  11. Quantifying uncertainty in stable isotope mixing models

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Davis, Paul; Syme, James; Heikoop, Jeffrey; Fessenden-Rahn, Julianna; Perkins, George; Newman, Brent; Chrystal, Abbey E.; Hagerty, Shannon B.

    2015-05-19

    Mixing models are powerful tools for identifying biogeochemical sources and determining mixing fractions in a sample. However, identification of actual source contributors is often not simple, and source compositions typically vary or even overlap, significantly increasing model uncertainty in calculated mixing fractions. This study compares three probabilistic methods, SIAR [Parnell et al., 2010] a pure Monte Carlo technique (PMC), and Stable Isotope Reference Source (SIRS) mixing model, a new technique that estimates mixing in systems with more than three sources and/or uncertain source compositions. In this paper, we use nitrate stable isotope examples (δ15N and δ18O) but all methods testedmore » are applicable to other tracers. In Phase I of a three-phase blind test, we compared methods for a set of six-source nitrate problems. PMC was unable to find solutions for two of the target water samples. The Bayesian method, SIAR, experienced anchoring problems, and SIRS calculated mixing fractions that most closely approximated the known mixing fractions. For that reason, SIRS was the only approach used in the next phase of testing. In Phase II, the problem was broadened where any subset of the six sources could be a possible solution to the mixing problem. Results showed a high rate of Type I errors where solutions included sources that were not contributing to the sample. In Phase III some sources were eliminated based on assumed site knowledge and assumed nitrate concentrations, substantially reduced mixing fraction uncertainties and lowered the Type I error rate. These results demonstrate that valuable insights into stable isotope mixing problems result from probabilistic mixing model approaches like SIRS. The results also emphasize the importance of identifying a minimal set of potential sources and quantifying uncertainties in source isotopic composition as well as demonstrating the value of additional information in reducing the uncertainty in calculated mixing fractions.« less

  12. Method and apparatus for executing a shift in a hybrid transmission

    DOE Patents [OSTI]

    Gupta, Pinaki; Kaminsky, Lawrence A; Demirovic, Besim

    2013-09-03

    A method for executing a transmission shift in a hybrid transmission including first and second electric machines includes executing a shift-through-neutral sequence from an initial transmission state to a target transmission state including executing an intermediate shift to neutral. Upon detecting a change in an output torque request while executing the shift-through-neutral sequence, possible recovery shift paths are identified. Available ones of the possible recovery shift paths are identified and a shift cost for each said available recovery shift path is evaluated. The available recovery shift path having a minimum shift cost is selected as a preferred recovery shift path and is executed to achieve a non-neutral transmission state.

  13. Fuel Mix Disclosure | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    customers. Such information must be provided on customers' bills or as a bill insert once annually. The fuel mix is also published in annual reports. Source http:...

  14. Microsecond Microfluidic Mixing for Investigation of Protein...

    Office of Scientific and Technical Information (OSTI)

    for Investigation of Protein Folding Kinetics Citation Details In-Document Search Title: Microsecond Microfluidic Mixing for Investigation of Protein Folding Kinetics We have ...

  15. TANK MIXING STUDY WITH FLOW RECIRCULATION

    SciTech Connect (OSTI)

    Lee, S.

    2014-06-25

    The primary objective of this work is to quantify the mixing time when two miscible fluids are mixed by one recirculation pump and to evaluate adequacy of 2.5 hours of pump recirculation to be considered well mixed in SRS tanks, JT-71/72. The work scope described here consists of two modeling analyses. They are the steady state flow pattern analysis during pump recirculation operation of the tank liquid and transient species transport calculations based on the initial steady state flow patterns. The modeling calculations for the mixing time are performed by using the 99% homogeneity criterion for the entire domain of the tank contents.

  16. Lanthanide doped strontium barium mixed halide scintillators

    DOE Patents [OSTI]

    Gundiah, Gautam; Bizarri, Gregory; Hanrahan, Stephen M; Bourret-Courchesne, Edith; Derenzo, Stephen E

    2013-07-16

    The present invention provides for a composition comprising an inorganic scintillator comprising a lanthanide-doped strontium barium mixed halide useful for detecting nuclear material.

  17. Inference of ICF implosion core mix using experimental data and theoretical mix modeling

    SciTech Connect (OSTI)

    Sherrill, Leslie Welser; Haynes, Donald A; Cooley, James H; Sherrill, Manolo E; Mancini, Roberto C; Tommasini, Riccardo; Golovkin, Igor E; Haan, Steven W

    2009-01-01

    The mixing between fuel and shell materials in Inertial Confinement Fusion (lCF) implosion cores is a current topic of interest. The goal of this work was to design direct-drive ICF experiments which have varying levels of mix, and subsequently to extract information on mixing directly from the experimental data using spectroscopic techniques. The experimental design was accomplished using hydrodynamic simulations in conjunction with Haan's saturation model, which was used to predict the mix levels of candidate experimental configurations. These theoretical predictions were then compared to the mixing information which was extracted from the experimental data, and it was found that Haan's mix model predicted trends in the width of the mix layer as a function of initial shell thickness. These results contribute to an assessment of the range of validity and predictive capability of the Haan saturation model, as well as increasing confidence in the methods used to extract mixing information from experimental data.

  18. In Situ Time-Resolved Characterization of Ni-MoO2 Catalysts for the Water-Gas Shift Reaction

    SciTech Connect (OSTI)

    Wen,W.; Calderon, J.; Brito, J.; Marinkovic, N.; Hanson, J.; Rodriquez, J.

    2008-01-01

    Active catalysts for the water-gas shift (WGS, CO + H2O ? H2 + CO2) reaction were synthesized from nickel molybdates ({beta}-NiMoO4 and nH2O{center_dot}NiMoO4) as precursors, and their structural transformations were monitored using in situ time-resolved X-ray diffraction and X-ray absorption near-edge spectroscopy. In general, the nickel molybdates were not stable and underwent partial reduction in the presence of CO or CO/H2O mixtures at high temperatures. The interaction of {beta}-NiMoO4 with the WGS reactants at 500 C led to the formation of a mixture of Ni (24 nm particle size) and MoO2 (10 nm particle size). These Ni-MoO2 systems displayed good catalytic activity at 350, 400, and 500 C. At 350 and 400 C, catalytic tests revealed that the Ni-MoO2 system was much more active than isolated Ni (some activity) or isolated MoO2 (negligible activity). Thus, cooperative interactions between the admetal and oxide support were probably responsible for the high WGS activity of Ni-MoO2. In a second synthetic approach, the NiMoO4 hydrate was reduced to a mixture of metallic Ni, NiO, and amorphous molybdenum oxide by direct reaction with H2 gas at 350 C. In the first pass of the water-gas shift reaction, MoO2 appeared gradually at 500 C with a concurrent increase of the catalytic activity. For these catalysts, the particle size of Ni (4 nm) was much smaller than that of the MoO2 (13 nm). These systems were found to be much more active WGS catalysts than Cu-MoO2, which in turn is superior to commercial low-temperature Cu-ZnO catalysts.

  19. Thin films of mixed metal compounds

    DOE Patents [OSTI]

    Mickelsen, Reid A. (Bellevue, WA); Chen, Wen S. (Seattle, WA)

    1985-01-01

    A compositionally uniform thin film of a mixed metal compound is formed by simultaneously evaporating a first metal compound and a second metal compound from independent sources. The mean free path between the vapor particles is reduced by a gas and the mixed vapors are deposited uniformly. The invention finds particular utility in forming thin film heterojunction solar cells.

  20. Neutrino mixing and oscillations in astrophysical environments

    SciTech Connect (OSTI)

    Balantekin, A. B. [Physics Department, University of Wisconsin, Madison WI 53706 (United States)

    2014-05-02

    A brief review of the current status of neutrino mixing and oscillations in astrophysical environments, with particular emphasis on the Sun and core-collapse supernovae, is given. Implications of the existence of sterile states which mix with the active neutrinos are discussed.

  1. Tower Water-Vapor Mixing Ratio

    SciTech Connect (OSTI)

    Guastad, Krista; Riihimaki, Laura; none,

    2013-04-01

    The purpose of the Tower Water-Vapor Mixing Ratio (TWRMR) value-added product (VAP) is to calculate water-vapor mixing ratio at the 25-meter and 60-meter levels of the meteorological tower at the Southern Great Plains (SGP) Central Facility.

  2. Collisional shifts in optical-lattice atom clocks

    SciTech Connect (OSTI)

    Band, Y. B. [Department of Chemistry, Ben-Gurion University of the Negev, Beer-Sheva 84105 (Israel); Atomic Physics Division, A267 Physics, National Institute of Standards and Technology, Gaithersburg, Maryland 20899 (United States); Ilse Katz Center for Nano-Science, Ben-Gurion University of the Negev, Beer-Sheva 84105 (Israel); Vardi, A. [Department of Chemistry, Ben-Gurion University of the Negev, Beer-Sheva 84105 (Israel)

    2006-09-15

    We theoretically study the effects of elastic collisions on the determination of frequency standards via Ramsey-fringe spectroscopy in optical-lattice atom clocks. Interparticle interactions of bosonic atoms in multiply occupied lattice sites can cause a linear frequency shift, as well as generate asymmetric Ramsey-fringe patterns and reduce fringe visibility due to interparticle entanglement. We propose a method of reducing these collisional effects in an optical lattice by introducing a phase difference of {pi} between the Ramsey driving fields in adjacent sites. This configuration suppresses site-to-site hopping due to interference of two tunneling pathways, without degrading fringe visibility. Consequently, the probability of double occupancy is reduced, leading to cancellation of collisional shifts.

  3. Phase-shifting point diffraction interferometer mask designs

    DOE Patents [OSTI]

    Goldberg, Kenneth Alan (Berkeley, CA)

    2001-01-01

    In a phase-shifting point diffraction interferometer, different image-plane mask designs can improve the operation of the interferometer. By keeping the test beam window of the mask small compared to the separation distance between the beams, the problem of energy from the reference beam leaking through the test beam window is reduced. By rotating the grating and mask 45.degree., only a single one-dimensional translation stage is required for phase-shifting. By keeping two reference pinholes in the same orientation about the test beam window, only a single grating orientation, and thus a single one-dimensional translation stage, is required. The use of a two-dimensional grating allows for a multiplicity of pinholes to be used about the pattern of diffracted orders of the grating at the mask. Orientation marks on the mask can be used to orient the device and indicate the position of the reference pinholes.

  4. Three dimensional imaging detector employing wavelength-shifting optical fibers

    DOE Patents [OSTI]

    Worstell, W.A.

    1997-02-04

    A novel detector element structure and method for its use is provided. In a preferred embodiment, one or more inorganic scintillating crystals are coupled through wavelength shifting optical fibers (WLSFs) to position sensitive photomultipliers (PS-PMTs). The superior detector configuration in accordance with this invention is designed for an array of applications in high spatial resolution gamma ray sensing with particular application to SPECT, PET and PVI imaging systems. The design provides better position resolution than prior art devices at a lower total cost. By employing wavelength shifting fibers (WLSFs), the sensor configuration of this invention can operate with a significant reduction in the number of photomultipliers and electronics channels, while potentially improving the resolution of the system by allowing three dimensional reconstruction of energy deposition positions. 11 figs.

  5. Spatial-heterodyne interferometry for transmission (SHIFT) measurements

    DOE Patents [OSTI]

    Bingham, Philip R.; Hanson, Gregory R.; Tobin, Ken W.

    2006-10-10

    Systems and methods are described for spatial-heterodyne interferometry for transmission (SHIFT) measurements. A method includes digitally recording a spatially-heterodyned hologram including spatial heterodyne fringes for Fourier analysis using a reference beam, and an object beam that is transmitted through an object that is at least partially translucent; Fourier analyzing the digitally recorded spatially-heterodyned hologram, by shifting an original origin of the digitally recorded spatially-heterodyned hologram to sit on top of a spatial-heterodyne carrier frequency defined by an angle between the reference beam and the object beam, to define an analyzed image; digitally filtering the analyzed image to cut off signals around the original origin to define a result; and performing an inverse Fourier transform on the result.

  6. Three dimensional imaging detector employing wavelength-shifting optical fibers

    DOE Patents [OSTI]

    Worstell, William A. (Framingham, MA)

    1997-01-01

    A novel detector element structure and method for its use is provided. In a preferred embodiment, one or more inorganic scintillating crystals are coupled through wavelength shifting optical fibers (WLSFs) to position sensitive photomultipliers (PS-PMTs). The superior detector configuration in accordance with this invention is designed for an array of applications in high spatial resolution gamma ray sensing with particular application to SPECT, PET and PVI imaging systems. The design provides better position resolution than prior art devices at a lower total cost. By employing wavelength shifting fibers (WLSFs), the sensor configuration of this invention can operate with a significant reduction in the number of photomultipliers and electronics channels, while potentially improving the resolution of the system by allowing three dimensional reconstruction of energy deposition positions.

  7. Thin films of mixed metal compounds

    DOE Patents [OSTI]

    Mickelsen, R.A.; Chen, W.S.

    1985-06-11

    Disclosed is a thin film heterojunction solar cell, said heterojunction comprising a p-type I-III-IV[sub 2] chalcopyrite substrate and an overlying layer of an n-type ternary mixed metal compound wherein said ternary mixed metal compound is applied to said substrate by introducing the vapor of a first metal compound to a vessel containing said substrate from a first vapor source while simultaneously introducing a vapor of a second metal compound from a second vapor source of said vessel, said first and second metals comprising the metal components of said mixed metal compound; independently controlling the vaporization rate of said first and second vapor sources; reducing the mean free path between vapor particles in said vessel, said gas being present in an amount sufficient to induce homogeneity of said vapor mixture; and depositing said mixed metal compound on said substrate in the form of a uniform composition polycrystalline mixed metal compound. 5 figs.

  8. Phase-shifting point diffraction interferometer grating designs

    DOE Patents [OSTI]

    Naulleau, Patrick (Oakland, CA); Goldberg, Kenneth Alan (Berkeley, CA); Tejnil, Edita (San Carlos, CA)

    2001-01-01

    In a phase-shifting point diffraction interferometer, by sending the zeroth-order diffraction to the reference pinhole of the mask and the first-order diffraction to the test beam window of the mask, the test and reference beam intensities can be balanced and the fringe contrast improved. Additionally, using a duty cycle of the diffraction grating other than 50%, the fringe contrast can also be improved.

  9. Hybrid powertrain system including smooth shifting automated transmission

    DOE Patents [OSTI]

    Beaty, Kevin D.; Nellums, Richard A.

    2006-10-24

    A powertrain system is provided that includes a prime mover and a change-gear transmission having an input, at least two gear ratios, and an output. The powertrain system also includes a power shunt configured to route power applied to the transmission by one of the input and the output to the other one of the input and the output. A transmission system and a method for facilitating shifting of a transmission system are also provided.

  10. Willis Lamb, Jr., the Hydrogen Atom, and the Lamb Shift

    Office of Scientific and Technical Information (OSTI)

    Willis E. Lamb, Jr., the Hydrogen Atom, and the Lamb Shift Resources with Additional Information Willis E. Lamb, Jr., was awarded the 2000 National Medal of Science for "his towering contributions to classical and quantum theories of laser radiation and quantum optics, and to the proper interpretation of non-relativistic quantum mechanics. ... The National Medal of Science, established by Congress in 1959 and administered for the President by the National Science Foundation, is the nation's

  11. Maximizing productivity & profitability through best cost shift schedules

    SciTech Connect (OSTI)

    Coleman, R.

    1996-12-31

    If you have the right equipment and employees at the right place, the fight time, and the right cost, you have the perfect business schedule. But, if you`re like most mines, you can probably improve your schedule, improvements that will reach all the way to the bottom line. And unlike adding employees, materials, or capital equipment, better scheduling is a cost-free way improve profitability. A good schedule can save millions. A bad schedule will cost money every year. A shift schedule is not a day off pattern or shift length. A shift schedule is a complete system deploying personnel and capital equipment. Most mining schedules are either copied from another operation, based on tradition or the result of a contract negotiation made far from the mine site. Unfortunately, most mine managers don`t give much thought to schedules until a crisis develops; at which point the tendency is to implement the first solution that comes along as quickly as possible. Costly mistakes are made.

  12. Hand held phase-shifting diffraction moire interferometer

    DOE Patents [OSTI]

    Deason, Vance A. (Idaho Falls, ID); Ward, Michael B. (Idaho Falls, ID)

    1994-01-01

    An interferometer in which a coherent beam of light is generated within a remote case and transmitted to a hand held unit tethered to said remote case, said hand held unit having optical elements for directing a pair of mutually coherent collimated laser beams at a diffraction grating. Data from the secondary or diffracted beams are then transmitted to a separate video and data acquisition system for recording and analysis for load induced deformation or for identification purposes. Means are also provided for shifting the phase of one incident beam relative to the other incident beam and being controlled from within said remote case.

  13. Hand held phase-shifting diffraction Moire interferometer

    DOE Patents [OSTI]

    Deason, V.A.; Ward, M.B.

    1994-09-20

    An interferometer is described in which a coherent beam of light is generated within a remote case and transmitted to a hand held unit tethered to said remote case, said hand held unit having optical elements for directing a pair of mutually coherent collimated laser beams at a diffraction grating. Data from the secondary or diffracted beams are then transmitted to a separate video and data acquisition system for recording and analysis for load induced deformation or for identification purposes. Means are also provided for shifting the phase of one incident beam relative to the other incident beam and being controlled from within said remote case. 4 figs.

  14. Phase-shifting point diffraction interferometer phase grating designs

    DOE Patents [OSTI]

    Naulleau, Patrick (Oakland, CA)

    2001-01-01

    Diffraction phase gratings are employed in phase-shifting point diffraction interferometers to improve the interferometric fringe contrast. The diffraction phase grating diffracts a zeroth-order diffraction of light at a first power level to the test-beam window of a mask that is positioned at the image plane and a first-order diffraction at a second power to the reference-beam pinhole. The diffraction phase grating is preferably selected to yield a desired ratio of the first power level to second power level.

  15. Micellar compositions in mixed surfactant solutions

    SciTech Connect (OSTI)

    Zhi-Jian Yu ); Guo-Xi Zhao )

    1993-03-15

    Micellization of aqueous mixtures of alkyltriethylammonium bromide and sodium alkylsulfate in the presence of excess sodium bromide has been studied by surface tension measurements. The molecular ratio of the cationic surfactant to the anionic surfactant in the mixed micelles is deduced by applying the Gibbs-Duhem equation to the measured critical micelle concentrations. Approximately equimolar amounts of the surfactant components in the mixed micelles over a wide range of aqueous mixing ratio are found in the systems of components similar in chain lengths. Large deviations of the surfactant molecular ratio deduced by the regular solution approach (Rubingh's model) when compared with that deduced by this approach are discovered, which suggests a limitation in applying the regular solution approach to mixed systems of cationic/anionic surfactants.

  16. Mixing lengths scaling in a gravity flow

    SciTech Connect (OSTI)

    Ecke, Robert E [Los Alamos National Laboratory; Rivera, Micheal [Los Alamos National Laboratory; Chen, Jun [Los Alamos National Laboratory; Ecke, Robert E [Los Alamos National Laboratory

    2009-01-01

    We present an experimental study of the mixing processes in a gravity current. The turbulent transport of momentum and buoyancy can be described in a very direct and compact form by a Prandtl mixing length model [1]: the turbulent vertical fluxes of momentum and buoyancy are found to scale quadraticatly with the vertical mean gradients of velocity and density. The scaling coefficient is the square of the mixing length, approximately constant over the mixing zone of the stratified shear layer. We show in this paper how, in different flow configurations, this length can be related to the shear length of the flow {radical}({var_epsilon}/{partial_derivative}{sub z}u{sup 3}).

  17. Ice in Arctic Mixed-phase Stratocumulus

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ice Nuclei Recycling in the Maintenance of Cloud Ice in Arctic Mixed-phase Stratocumulus For original submission and image(s), see ARM Research Highlights http:www.arm.gov...

  18. NMR chemical shifts in amino acids: Effects of environments, electric field, and amine group rotation

    SciTech Connect (OSTI)

    Yoon, Young-Gui; Pfrommer, Bernd G.; Louie, Steven G.; Canning, Andrew

    2002-03-03

    The authors present calculations of NMR chemical shifts in crystalline phases of some representative amino acids such as glycine, alanine, and alanyl-alanine. To get an insight on how different environments affect the chemical shifts, they study the transition from the crystalline phase to completely isolated molecules of glycine. In the crystalline limit, the shifts are dominated by intermolecular hydrogen-bonds. In the molecular limit, however, dipole electric field effects dominate the behavior of the chemical shifts. They show that it is necessary to average the chemical shifts in glycine over geometries. Tensor components are analyzed to get the angle dependent proton chemical shifts, which is a more refined characterization method.

  19. Mixed oxide nanoparticles and method of making

    DOE Patents [OSTI]

    Lauf, Robert J. (Oak Ridge, TN); Phelps, Tommy J. (Knoxville, TN); Zhang, Chuanlun (Columbia, MO); Roh, Yul (Oak Ridge, TN)

    2002-09-03

    Methods and apparatus for producing mixed oxide nanoparticulates are disclosed. Selected thermophilic bacteria cultured with suitable reducible metals in the presence of an electron donor may be cultured under conditions that reduce at least one metal to form a doped crystal or mixed oxide composition. The bacteria will form nanoparticles outside the cell, allowing easy recovery. Selection of metals depends on the redox potentials of the reducing agents added to the culture. Typically hydrogen or glucose are used as electron donors.

  20. Leptonic mixing, family symmetries, and neutrino phenomenology

    SciTech Connect (OSTI)

    Medeiros Varzielas, I. de [Departamento de Fisica and Centro de Fisica Teorica de Particulas, Instituto Superior Tecnico, Avenida Rovisco Pais, 1049-001 Lisboa (Portugal); Fakultaet fuer Physik, Technische Universitaet Dortmund D-44221 Dortmund (Germany); Gonzalez Felipe, R. [Departamento de Fisica and Centro de Fisica Teorica de Particulas, Instituto Superior Tecnico, Avenida Rovisco Pais, 1049-001 Lisboa (Portugal); Instituto Superior de Engenharia de Lisboa, Rua Conselheiro Emidio Navarro, 1959-007 Lisboa (Portugal); Serodio, H. [Departamento de Fisica and Centro de Fisica Teorica de Particulas, Instituto Superior Tecnico, Avenida Rovisco Pais, 1049-001 Lisboa (Portugal)

    2011-02-01

    Tribimaximal leptonic mixing is a mass-independent mixing scheme consistent with the present solar and atmospheric neutrino data. By conveniently decomposing the effective neutrino mass matrix associated to it, we derive generic predictions in terms of the parameters governing the neutrino masses. We extend this phenomenological analysis to other mass-independent mixing schemes which are related to the tribimaximal form by a unitary transformation. We classify models that produce tribimaximal leptonic mixing through the group structure of their family symmetries in order to point out that there is often a direct connection between the group structure and the phenomenological analysis. The type of seesaw mechanism responsible for neutrino masses plays a role here, as it restricts the choices of family representations and affects the viability of leptogenesis. We also present a recipe to generalize a given tribimaximal model to an associated model with a different mass-independent mixing scheme, which preserves the connection between the group structure and phenomenology as in the original model. This procedure is explicitly illustrated by constructing toy models with the transpose tribimaximal, bimaximal, golden ratio, and hexagonal leptonic mixing patterns.

  1. Implications of Upwells as Hydrodynamic Jets in a Pulse Jet Mixed System

    SciTech Connect (OSTI)

    Pease, Leonard F.; Bamberger, Judith A.; Minette, Michael J.

    2015-08-01

    This report evaluates the physics of the upwell flow in pulse jet mixed systems in the Hanford Tank Waste Treatment and Immobilization Plant (WTP). Although the initial downward flow and radial flow from pulse jet mixers (PJMs) has been analyzed in some detail, the upwells have received considerably less attention despite having significant implications for vessel mixing. Do the upwells behave like jets? How do the upwells scale? When will the central upwell breakthrough? What proportion of the vessel is blended by the upwells themselves? Indeed, how the physics of the central upwell is affected by multiple PJMs (e.g., six in the proposed mixing vessels), non-Newtonian rheology, and significant multicomponent solids loadings remain unexplored. The central upwell must satisfy several criteria to be considered a free jet. First, it must travel for several diameters in a nearly constant direction. Second, its velocity must decay with the inverse of elevation. Third, it should have an approximately Gaussian profile. Fourth, the influence of surface or body forces must be negligible. A combination of historical data in a 12.75 ft test vessel, newly analyzed data from the 8 ft test vessel, and conservation of momentum arguments derived specifically for PJM operating conditions demonstrate that the central upwell satisfies these criteria where vigorous breakthrough is achieved. An essential feature of scaling from one vessel to the next is the requirement that the underlying physics does not change adversely. One may have confidence in scaling if (1) correlations and formulas capture the relevant physics; (2) the underlying physics does not change from the conditions under which it was developed to the conditions of interest; (3) all factors relevant to scaling have been incorporated, including flow, material, and geometric considerations; and (4) the uncertainty in the relationships is sufficiently narrow to meet required specifications. Although the central upwell satisfies these criteria when vigorous breakthrough is achieved, not all available data follow the free jet profile for the central upwell, particularly at lower nozzle velocities. Alternative flow regimes are considered and new models for cloud height, “cavern height,” and the rate of jet penetration (jet celerity) are benchmarked against data to anchor scaling analyses. This analytical modeling effort to provide a technical basis for scaling PJM mixed vessels has significant implications for vessel mixing, because jet physics underlies “cavern” height, cloud height, and the volume of mixing considerations. A new four-parameter cloud height model compares favorably to experimental results. This model is predictive of breakthrough in 8 ft vessel tests with the two-part simulant. Analysis of the upwell in the presence of yield stresses finds evidence of expanding turbulent jets, confined turbulent jets, and confined laminar flows. For each, the critical elevation at which jet momentum depletes is predicted, which compare favorably to experimental cavern height data. Partially coupled momentum and energy balances suggest that these are limiting cases of a gradual transition from a turbulent expanding flow to a confined laminar flow. This analysis of the central upwell alone lays essential groundwork for complete analysis of mode three mixing (i.e., breakthrough with slow peripheral mixing). Consideration of jet celerity shows that the rate of jet penetration is a governing consideration in breakthrough to the surface. Estimates of the volume of mixing are presented. This analysis shows that flow along the vessel wall is sluggish such that the central upwell governs the volume of mixing. This analysis of the central upwell alone lays essential groundwork for complete analysis of mode three mixing and estimates of hydrogen release rates from first principles.

  2. Ab initio thermodynamic approach to identify mixed solid sorbents for CO2 capture technology

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Duan, Yuhua

    2015-10-15

    Because the current technologies for capturing CO2 are still too energy intensive, new materials must be developed that can capture CO2 reversibly with acceptable energy costs. At a given CO2 pressure, the turnover temperature (Tt) of the reaction of an individual solid that can capture CO2 is fixed. Such Tt may be outside the operating temperature range (ΔTo) for a practical capture technology. To adjust Tt to fit the practical ΔTo, in this study, three scenarios of mixing schemes are explored by combining thermodynamic database mining with first principles density functional theory and phonon lattice dynamics calculations. Our calculated resultsmore » demonstrate that by mixing different types of solids, it’s possible to shift Tt to the range of practical operating temperature conditions. According to the requirements imposed by the pre- and post- combustion technologies and based on our calculated thermodynamic properties for the CO2 capture reactions by the mixed solids of interest, we were able to identify the mixing ratios of two or more solids to form new sorbent materials for which lower capture energy costs are expected at the desired pressure and temperature conditions.« less

  3. Catalyst support of mixed cerium zirconium titanium oxide, including use and method of making

    DOE Patents [OSTI]

    Willigan, Rhonda R. (Manchester, CT); Vanderspurt, Thomas Henry (Glastonbury, CT); Tulyani, Sonia (Manchester, CT); Radhakrishnan, Rakesh (Vernon, CT); Opalka, Susanne Marie (Glastonbury, CT); Emerson, Sean C. (Broad Brook, CT)

    2011-01-18

    A durable catalyst support/catalyst is capable of extended water gas shift operation under conditions of high temperature, pressure, and sulfur levels. The support is a homogeneous, nanocrystalline, mixed metal oxide of at least three metals, the first being cerium, the second being Zr, and/or Hf, and the third importantly being Ti, the three metals comprising at least 80% of the metal constituents of the mixed metal oxide and the Ti being present in a range of 5% to 45% by metals-only atomic percent of the mixed metal oxide. The mixed metal oxide has an average crystallite size less than 6 nm and forms a skeletal structure with pores whose diameters are in the range of 4-9 nm and normally greater than the average crystallite size. The surface area of the skeletal structure per volume of the material of the structure is greater than about 240 m.sup.2/cm.sup.3. The method of making and use are also described.

  4. Liquidliquid mixing studies in annular centrifugal contactors comparing stationary mixing vane options

    SciTech Connect (OSTI)

    Wardle, Kent E.

    2015-09-11

    Comparative studies of multiphase operation of an annular centrifugal contactor show the impact of housing stationary mixing vane configuration. A number of experimental results for several different mixing vane options are reported for operation of a 12.5 cm engineering-scale contactor unit. Fewer straight vanes give greater mixing-zone hold-up compared to curved vanes. Quantitative comparison of droplet size distribution also showed a significant decrease in mean diameter for four straight vanes versus eight curved vanes. This set of measurements gives a compelling case for careful consideration of mixing vane geometry when evaluating hydraulic operation and extraction process efficiency of annular centrifugal contactors.

  5. DOE Publishes CALiPER Report on Chromaticity Shift Modes of LED...

    Office of Environmental Management (EM)

    CALiPER Report on Chromaticity Shift Modes of LED PAR38 Lamps DOE Publishes CALiPER Report on Chromaticity Shift Modes of LED PAR38 Lamps March 23, 2016 - 11:33am Addthis The U.S. ...

  6. Report 20.5: Chromaticity Shift Modes of LED PAR38 Lamps Operated...

    Energy Savers [EERE]

    5: Chromaticity Shift Modes of LED PAR38 Lamps Operated in Steady-State Conditions Report 20.5: Chromaticity Shift Modes of LED PAR38 Lamps Operated in Steady-State Conditions PDF ...

  7. CASL-U-2015-0170-000-a SHIFT: A New Monte Carlo Package Seth...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CASL-U-2015-0170-000-a 2 Shift: MC RT Code What makes Shift an HPC transport code? * Modern framework - Rapid development with C++11, Python, CMake, CTest, ... - Integration...

  8. Mixed-mode diesel HCCI with External Mixture Formation: Preliminary...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mixed-mode diesel HCCI with External Mixture Formation: Preliminary Results Mixed-mode diesel HCCI with External Mixture Formation: Preliminary Results 2003 DEER Conference...

  9. Search for Neutral D Meson Mixing using Semileptonic Decays ...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Search for Neutral D Meson Mixing using Semileptonic Decays Citation Details In-Document Search Title: Search for Neutral D Meson Mixing using Semileptonic Decays...

  10. Design Case Summary: Production of Mixed Alcohols from Municipal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Design Case Summary: Production of Mixed Alcohols from Municipal Solid Waste via Gasification Design Case Summary: Production of Mixed Alcohols from Municipal Solid Waste via ...

  11. Advanced Mixed Waste Treatment Project Achieves Impressive Safety...

    Office of Environmental Management (EM)

    Advanced Mixed Waste Treatment Project Achieves Impressive Safety and Production Marks Advanced Mixed Waste Treatment Project Achieves Impressive Safety and Production Marks June ...

  12. Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol Synthesis of Lignocellulosic Biomass Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol Synthesis ...

  13. Intercomparison of model simulations of mixed-phase clouds observed...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Intercomparison of model simulations of mixed-phase clouds observed during the ARM Mixed-Phase Arctic Cloud Experiment. I: Single layer cloud Citation Details ...

  14. Performance and mix measurements of indirect drive Cu doped Be...

    Office of Scientific and Technical Information (OSTI)

    Performance and mix measurements of indirect drive Cu doped Be implosions Citation Details In-Document Search Title: Performance and mix measurements of indirect drive Cu doped Be...

  15. Theoretical Synthesis of Mixed Materials for CO2 Capture Applications...

    Office of Scientific and Technical Information (OSTI)

    Theoretical Synthesis of Mixed Materials for CO2 Capture Applications Citation Details In-Document Search Title: Theoretical Synthesis of Mixed Materials for CO2 Capture...

  16. Fuel Effects on Mixing-Controlled Combustion Strategies for High...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mixing-Controlled Combustion Strategies for High-Efficiency Clean-Combustion Engines Fuel Effects on Mixing-Controlled Combustion Strategies for High-Efficiency Clean-Combustion ...

  17. DOE intends to extend the Advanced Mixed Waste Treatment Project...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DOE intends to extend the Advanced Mixed Waste Treatment Project contract for four months as competition for long-term contract continues. Scene from inside the Advanced Mixed...

  18. CARBON BED MERCURY EMISSIONS CONTROL FOR MIXED WASTE TREATMENT...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: CARBON BED MERCURY EMISSIONS CONTROL FOR MIXED WASTE TREATMENT Citation Details In-Document Search Title: CARBON BED MERCURY EMISSIONS CONTROL FOR MIXED WASTE ...

  19. Multipartite entangled states in particle mixing

    SciTech Connect (OSTI)

    Blasone, M.; Dell'Anno, F.; De Siena, S.; Di Mauro, M.; Illuminati, F.

    2008-05-01

    In the physics of flavor mixing, the flavor states are given by superpositions of mass eigenstates. By using the occupation number to define a multiqubit space, the flavor states can be interpreted as multipartite mode-entangled states. By exploiting a suitable global measure of entanglement, based on the entropies related to all possible bipartitions of the system, we analyze the correlation properties of such states in the instances of three- and four-flavor mixing. Depending on the mixing parameters, and, in particular, on the values taken by the free phases, responsible for the CP-violation, entanglement concentrates in certain bipartitions. We quantify in detail the amount and the distribution of entanglement in the physically relevant cases of flavor mixing in quark and neutrino systems. By using the wave packet description for localized particles, we use the global measure of entanglement, suitably adapted for the instance of multipartite mixed states, to analyze the decoherence, induced by the free evolution dynamics, on the quantum correlations of stationary neutrino beams. We define a decoherence length as the distance associated with the vanishing of the coherent interference effects among massive neutrino states. We investigate the role of the CP-violating phase in the decoherence process.

  20. Dielectric waveguide gas-filled stark shift modulator

    DOE Patents [OSTI]

    Hutchinson, Donald P.; Richards, Roger K.

    2003-07-22

    An optical modulator includes a dielectric waveguide for receiving an optical beam and coupling energy of the optical beam into the waveguide. At least one Stark material is provided in the waveguide. A bias circuit generates a bias signal to produce an electrical field across the Stark material to shift at least one of the Stark absorption frequencies towards the frequency of the optical beam. A circuit for producing a time varying electric field across the Stark material modulates the optical beam. At least a portion of the bias field can be generated by an alternating bias signal, such as a square wave. A method of modulating optical signals includes the steps of providing a dielectric waveguide for receiving an optical beam and coupling energy of the optical beam into the waveguide, the waveguide having at least one Stark material disposed therein, and varying an electric field imposed across the Stark material.

  1. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, I.O.

    1992-04-21

    A free flowing, conformable powder-like mix of silica particles and a phase change material (p.c.m.) is disclosed. The silica particles have a critical size of about 7 [times] 10[sup [minus]3] to about 7 [times] 10[sup [minus]2] microns and the pcm must be added to the silica in an amount of 80 wt. % or less pcm per combined weight of silica and pcm. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and in cementitious compositions of the type in which it is beneficial to use a pcm material. The silica-pcm mix can also be admixed with soil to provide a soil warming effect and placed about a tree, flower, or shrub. 9 figs.

  2. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, I.O.

    1993-10-19

    Free flowing, conformable powder-like mix of silica particles and a phase change material (pcm) is disclosed. The silica particles have a critical size of about 7[times]10[sup [minus]3] to about 7[times]10[sup [minus]2] microns and the pcm must be added to the silica in an amount of 80 wt. % or less pcm per combined weight of silica and pcm. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and in cementitious compositions of the type in which it is beneficial to use a pcm material. The silica-pcm mix can also be admixed with soil to provide a soil warming effect and placed about a tree, flower, or shrub. 10 figures.

  3. Mixing enhancement by use of swirling jets

    SciTech Connect (OSTI)

    Kraus, D.K.; Cutler, A.D.

    1993-01-01

    It has been proposed that the mixing of fuel with air in the combustor of scramjet engines might be enhanced by the addition of swirl to the fuel jet prior to injection. This study investigated the effects of swirl on the mixing of a 30 deg wall jet into a Mach 2 flow. Cases with swirl and without swirl were investigated, with both helium and air simulating the fuel. Rayleigh scattering was used to visualize the flow, and seeding the fuel with water allowed it to be traced through the main flow. The results show that the addition of swirl to the fuel jet causes the fuel to mix more rapidly with the main flow, that larger amounts of swirl increase this effect, and that helium spreads better into the main flow than air. 12 refs.

  4. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, Ival O. (Dayton, OH)

    1993-01-01

    Free flowing, conformable powder-like mix of silica particles and a phase change material (p.c.m.) is disclosed. The silica particles have a critical size of about 7.times.10.sup.-3 to about 7.times.10.sup.-2 microns and the pcm must be added to the silica in an amount of 80 wt. % or less pcm per combined weight of silica and pcm. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and in cementitious compositions of the type in which it is beneficial to use a pcm material. The silica-pcm mix can also be admixed with soil to provide a soil warming effect and placed about a tree, flower, or shrub.

  5. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, I.O.

    1994-02-01

    Free flowing, conformable powder-like mix of silica particles and a phase change material (PCM) is provided. The silica particles have a critical size of about 0.005 to about 0.025 microns and the PCM must be added to the silica in an amount of 75% or less PCM per combined weight of silica and PCM. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and in cementitious compositions of the type in which it is beneficial to use a PCM material. The silica-PCM mix can also be admixed with soil to provide a soil warming effect and placed about a tree, flower, or shrub. 2 figures.

  6. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, Ival O. (Dayton, OH)

    1994-01-01

    Free flowing, conformable powder-like mix of silica particles and a phase change material (PCM) is provided. The silica particles have a critical size of about 0.005 to about 0.025 microns and the PCM must be added to the silica in an amount of 75% or less PCM per combined weight of silica and PCM. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and in cementitious compositions of the type in which it is beneficial to use a PCM material. The silica-PCM mix can also be admixed with soil to provide a soil warming effect and placed about a tree, flower, or shrub.

  7. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, Ival O. (Dayton, OH)

    1992-01-01

    Free flowing, conformable powder-like mix of silica particles and a phase change material (p.c.m.) is disclosed. The silica particles have a critical size of about 7.times.10.sup.-3 to about 7.times.10.sup.-2 microns and the pcm must be added to the silica in an amount of 80 wt. % or less pcm per combined weight of silica and pcm. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and in cementitious compositions of the type in which it is beneficial to use a pcm material. The silica-pcm mix can also be admixed with soil to provide a soil warming effect and placed about a tree, flower, or shrub.

  8. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, I.O.

    1993-05-18

    Free flowing, conformable powder-like mix of silica particles and a phase change material (p.c.m.) is disclosed. The silica particles have a critical size of about 7[times]10[sup [minus]3] to about 7[times]10[sup [minus]2] microns and the p.c.m. must be added to the silica in an amount of 80 wt. % or less p.c.m. per combined weight of silica and p.c.m. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and in cementitious compositions of the type in which it is beneficial to use a p.c.m. material. The silica-p.c.m. mix can also be admixed with soil to provide a soil warming effect and placed about a tree, flower, or shrub.

  9. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, Ival O. (Dayton, OH)

    1993-01-01

    Free flowing, conformable powder-like mix of silica particles and a phase change material (p.c.m.) is disclosed. The silica particles have a critical size of about 7.times.10.sup.-3 to about 7.times.10.sup.-2 microns and the pcm must be added to the silica in an amount of 80 wt. % or less pcm per combined weight of silica and pcm. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garmets, quilts and blankets, and in cementitious compositions of the type in which it is beneficial to use a pcm material. The silica-pcm mix can also be admixed with soil to provide a soil warming effect and placed about a tree, flower, or shrub.

  10. Pulse Jet Mixing Tests With Noncohesive Solids

    SciTech Connect (OSTI)

    Meyer, Perry A.; Bamberger, Judith A.; Enderlin, Carl W.; Fort, James A.; Wells, Beric E.; Sundaram, S. K.; Scott, Paul A.; Minette, Michael J.; Smith, Gary L.; Burns, Carolyn A.; Greenwood, Margaret S.; Morgen, Gerald P.; Baer, Ellen BK; Snyder, Sandra F.; White, Michael K.; Piepel, Gregory F.; Amidan, Brett G.; Heredia-Langner, Alejandro

    2012-02-17

    This report summarizes results from pulse jet mixing (PJM) tests with noncohesive solids in Newtonian liquid. The tests were conducted during FY 2007 and 2008 to support the design of mixing systems for the Hanford Waste Treatment and Immobilization Plant (WTP). Tests were conducted at three geometric scales using noncohesive simulants, and the test data were used to develop models predicting two measures of mixing performance for full-scale WTP vessels. The models predict the cloud height (the height to which solids will be lifted by the PJM action) and the critical suspension velocity (the minimum velocity needed to ensure all solids are suspended off the floor, though not fully mixed). From the cloud height, the concentration of solids at the pump inlet can be estimated. The predicted critical suspension velocity for lifting all solids is not precisely the same as the mixing requirement for 'disturbing' a sufficient volume of solids, but the values will be similar and closely related. These predictive models were successfully benchmarked against larger scale tests and compared well with results from computational fluid dynamics simulations. The application of the models to assess mixing in WTP vessels is illustrated in examples for 13 distinct designs and selected operational conditions. The values selected for these examples are not final; thus, the estimates of performance should not be interpreted as final conclusions of design adequacy or inadequacy. However, this work does reveal that several vessels may require adjustments to design, operating features, or waste feed properties to ensure confidence in operation. The models described in this report will prove to be valuable engineering tools to evaluate options as designs are finalized for the WTP. Revision 1 refines data sets used for model development and summarizes models developed since the completion of Revision 0.

  11. Scoping Study of Airlift Circulation Technologies for Supplemental Mixing in Pulse Jet Mixed Vessels

    SciTech Connect (OSTI)

    Schonewill, Philip P.; Berglin, Eric J.; Boeringa, Gregory K.; Buchmiller, William C.; Burns, Carolyn A.; Minette, Michael J.

    2015-04-07

    At the request of the U.S. Department of Energy Office of River Protection, Pacific Northwest National Laboratory (PNNL) conducted a scoping study to investigate supplemental technologies for supplying vertical fluid motion and enhanced mixing in Waste Treatment and Immobilization Plant (WTP) vessels designed for high solids processing. The study assumed that the pulse jet mixers adequately mix and shear the bottom portion of a vessel. Given that, the primary function of a supplemental technology should be to provide mixing and shearing in the upper region of a vessel. The objective of the study was to recommend a mixing technology and configuration that could be implemented in the 8-ft test vessel located at Mid-Columbia Engineering (MCE). Several mixing technologies, primarily airlift circulator (ALC) systems, were evaluated in the study. This technical report contains a review of ALC technologies, a description of the PNNL testing and accompanying results, and recommended features of an ALC system for further study.

  12. Improvements in Mixing Time and Mixing Uniformity in Devices Designed for Studies of Protein Folding Kinetics

    SciTech Connect (OSTI)

    Yao, Shuhuai [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Bakajin, Olgica [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

    2007-08-01

    Using a microfluidic laminar flow mixer designed for studies of protein folding kinetics, we demonstrate a mixing time of 1 +/- 1 micros with sample consumption on the order of femtomoles. We recognize two limitations of previously proposed designs: (1) size and shape of the mixing region, which limits mixing uniformity and (2) the formation of Dean vortices at high flow rates, which limits the mixing time. We address these limitations by using a narrow shape-optimized nozzle and by reducing the bend of the side channel streamlines. The final design, which combines both of these features, achieves the best performance. We quantified the mixing performance of the different designs by numerical simulation of coupled Navier-Stokes and convection-diffusion equations and experiments using fluorescence resonance energy-transfer (FRET)-labeled DNA.

  13. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, Ival O. (Dayton, OH)

    1994-01-01

    A free flowing, conformable powder-like mix of silica particles and a phase change material (PCM) is provided. The silica particles have a critical size of about 0.005 to about 0.025 microns and the PCM must be added to the silica in an amount of 75% or less PCM per combined weight of silica and PCM. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and particularly in applications for heat protection for heat sensitive items, such as aircraft flight recorders, and for preventing brake fade in automobiles, buses, trucks and aircraft.

  14. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, I.O.

    1995-12-26

    A free flowing, conformable powder-like mix of silica particles and a phase change material (PCM) is provided. The silica particles have a critical size of about 0.005 to about 0.025 microns and the PCM must be added to the silica in an amount of 75% or less PCM per combined weight of silica and PCM. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and particularly in applications for heat protection for heat sensitive items, such as aircraft flight recorders, and for preventing brake fade in automobiles, buses, trucks and aircraft. 3 figs.

  15. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, I.O.

    1994-12-06

    A free flowing, conformable powder-like mix of silica particles and a phase change material (PCM) is provided. The silica particles have a critical size of about 0.005 to about 0.025 microns and the PCM must be added to the silica in an amount of 75% or less PCM per combined weight of silica and PCM. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and particularly in applications for heat protection for heat sensitive items, such as aircraft flight recorders, and for preventing brake fade in automobiles, buses, trucks and aircraft. 3 figures.

  16. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, Ival O. (Dayton, OH)

    1995-01-01

    A free flowing, conformable powder-like mix of silica particles and a phase change material (PCM) is provided. The silica particles have a critical size of about 0.005 to about 0.025 microns and the PCM must be added to the silica in an amount of 75% or less PCM per combined weight of silica and PCM. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and particularly in applications for heat protection for heat sensitive items, such as aircraft flight recorders, and for preventing brake fade in automobiles, buses, trucks and aircraft.

  17. Mixed waste paper to ethanol fuel

    SciTech Connect (OSTI)

    Not Available

    1991-01-01

    The objectives of this study were to evaluate the use of mixed waste paper for the production of ethanol fuels and to review the available conversion technologies, and assess developmental status, current and future cost of production and economics, and the market potential. This report is based on the results of literature reviews, telephone conversations, and interviews. Mixed waste paper samples from residential and commercial recycling programs and pulp mill sludge provided by Weyerhauser were analyzed to determine the potential ethanol yields. The markets for ethanol fuel and the economics of converting paper into ethanol were investigated.

  18. BENCH SCALE SALTSTONE PROCESS DEVELOPMENT MIXING STUDY

    SciTech Connect (OSTI)

    Cozzi, A.; Hansen, E.

    2011-08-03

    The Savannah River National Laboratory (SRNL) was requested to develop a bench scale test facility, using a mixer, transfer pump, and transfer line to determine the impact of conveying the grout through the transfer lines to the vault on grout properties. Bench scale testing focused on the effect the transfer line has on the rheological property of the grout as it was processed through the transfer line. Rheological and other physical properties of grout samples were obtained prior to and after pumping through a transfer line. The Bench Scale Mixing Rig (BSMR) consisted of two mixing tanks, grout feed tank, transfer pump and transfer hose. The mixing tanks were used to batch the grout which was then transferred into the grout feed tank. The contents of the feed tank were then pumped through the transfer line (hose) using a progressive cavity pump. The grout flow rate and pump discharge pressure were monitored. Four sampling stations were located along the length of the transfer line at the 5, 105 and 205 feet past the transfer pump and at 305 feet, the discharge of the hose. Scaling between the full scale piping at Saltstone to bench scale testing at SRNL was performed by maintaining the same shear rate and total shear at the wall of the transfer line. The results of scaling down resulted in a shorter transfer line, a lower average velocity, the same transfer time and similar pressure drops. The condition of flow in the bench scale transfer line is laminar. The flow in the full scale pipe is in the transition region, but is more laminar than turbulent. The resulting plug in laminar flow in the bench scale results in a region of no-mixing. Hence mixing, or shearing, at the bench scale should be less than that observed in the full scale, where this plug is non existent due to the turbulent flow. The bench scale tests should be considered to be conservative due to the highly laminar condition of flow that exists. Two BSMR runs were performed. In both cases, wall shearing was shown to reduce the rheological properties of the grout as it was processed through the transfer line. Samples taken at the static feed tank showed that gelling impacted the rheological properties of the grout before it was fed into the pump and transfer line. A comparison of the rheological properties of samples taken at the feed tank and transfer line discharge indicated shearing of the grout was occurring in the transfer line. Bench scale testing of different mixing methods with three different salt solutions showed that method of mixing influences the rheological properties of the grouts. The paddle blade mixing method of the salt solution used for the BMSR testing provided comparable rheological properties of the grout prepared in the BMSR after 14 minutes of processing, B3. The paddle blade mixing method can be used to represent BMSR results and mixing time can be adjusted to represent larger scale mixing.

  19. Hazardous and Radioactive Mixed Waste Program

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1989-02-22

    To establish Department of Energy (DOE) hazardous and radioactive mixed waste policies and requirements and to implement the requirements of the Resource Conservation and Recovery Act (RCRA) within the framework of the environmental programs established under DOE O 5400.1. This directive does not cancel any directives.

  20. Mixing liquid holding tanks for uniform concentration

    SciTech Connect (OSTI)

    Sprouse, K.M.

    1988-01-01

    Achieving uniform concentration within liquid holding tanks can often times be a difficult task for the nuclear chemical process industry. This is due to the fact that nuclear criticality concerns require these tanks to be designed with high internal aspect ratios such that the free movement of fluid is greatly inhibited. To determine the mixing times required to achieve uniform concentrations within these tanks, an experimental program was conducted utilizing pencil tanks, double-pencil tanks, and annular tanks of varying geometries filled with salt-water solutions (simulant for nitric acid actinide solutions). Mixing was accomplished by air sparging and/or pump recirculation. Detailed fluid mechanic mixing models were developed --from first principles--to analyze and interpret the test results. These nondimensional models show the functionality of the concentration inhomogeneity (defined as the relative standard deviation of the true concentration within the tank) in relationship to the characteristic mixing time--among other variables. The results can be readily used to scale tank geometries to sizes other than those studied here.

  1. Symmetrical parametrizations of the lepton mixing matrix

    SciTech Connect (OSTI)

    Rodejohann, W. [Max-Planck-Institut fuer Kernphysik, Postfach 103980, 69029 Heidelberg (Germany); Valle, J. W. F. [AHEP Group, Institut de Fisica Corpuscular--C.S.I.C./Universitat de Valencia, Edificio Institutos de Paterna, Apt 22085, E-46071 Valencia (Spain)

    2011-10-01

    Advantages of the original symmetrical form of the parametrization of the lepton mixing matrix are discussed. It provides a conceptually more transparent description of neutrino oscillations and lepton number violating processes like neutrinoless double beta decay, clarifying the significance of Dirac and Majorana phases. It is also ideal for parametrizing scenarios with light sterile neutrinos.

  2. Low-Frequency Sonic Mixing Technology | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Frequency Sonic Mixing Technology Low-Frequency Sonic Mixing Technology New Acoustic Mixing Technology Improves Productivity Using Low-Frequency, High-Intensity Sound Energy Typical mixing technology uses a drive mechanism-usually an electric, hydraulic, or pneumatic motor-to rotate a shaft with one or more impellers. While many other mixer designs are available, including static mixers that do not use motors, the motor-driven mixer is the most prevalent mixing method. Resodyn Corporation's

  3. Challenge in Urea Mixing Design | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Challenge in Urea Mixing Design Challenge in Urea Mixing Design This project reviews existing urea mixing technologies for automobile applications and discusses some critical issues in urea mixing design using bench test experience. PDF icon deer11_miao.pdf More Documents & Publications Urea Mixing Design -- Simulation and Test Investigation SCR Performance Optimization Through Advancements in Aftertreatment Packaging Aftertreatment Research Prioritization: A CLEERS Industrial Survey

  4. Pulse Jet Mixing Tests With Noncohesive Solids

    SciTech Connect (OSTI)

    Meyer, Perry A.; Bamberger, Judith A.; Enderlin, Carl W.; Fort, James A.; Wells, Beric E.; Sundaram, S. K.; Scott, Paul A.; Minette, Michael J.; Smith, Gary L.; Burns, Carolyn A.; Greenwood, Margaret S.; Morgen, Gerald P.; Baer, Ellen BK; Snyder, Sandra F.; White, Michael; Piepel, Gregory F.; Amidan, Brett G.; Heredia-Langner, Alejandro; Bailey, Sharon A.; Bower, John C.; Denslow, Kayte M.; Eakin, David E.; Elmore, Monte R.; Gauglitz, Phillip A.; Guzman, Anthony D.; Hatchell, Brian K.; Hopkins, Derek F.; Hurley, David E.; Johnson, Michael D.; Kirihara, Leslie J.; Lawler, Bruce D.; Loveland, Jesse S.; Mullen, O Dennis; Pekour, Mikhail S.; Peters, Timothy J.; Robinson, Peter J.; Russcher, Michael S.; Sande, Susan; Santoso, Christian; Shoemaker, Steven V.; Silva, Steve M.; Smith, Devin E.; Su, Yin-Fong; Toth, James J.; Wiberg, John D.; Yu, Xiao-Ying; Zuljevic, Nino

    2009-05-11

    This report summarizes results from pulse jet mixing (PJM) tests with noncohesive solids in Newtonian liquid conducted during FY 2007 and 2008 to support the design of mixing systems for the Hanford Waste Treatment and Immobilization Plant (WTP). Tests were conducted at three geometric scales using noncohesive simulants. The test data were used to independently develop mixing models that can be used to predict full-scale WTP vessel performance and to rate current WTP mixing system designs against two specific performance requirements. One requirement is to ensure that all solids have been disturbed during the mixing action, which is important to release gas from the solids. The second requirement is to maintain a suspended solids concentration below 20 weight percent at the pump inlet. The models predict the height to which solids will be lifted by the PJM action, and the minimum velocity needed to ensure all solids have been lifted from the floor. From the cloud height estimate we can calculate the concentration of solids at the pump inlet. The velocity needed to lift the solids is slightly more demanding than "disturbing" the solids, and is used as a surrogate for this metric. We applied the models to assess WTP mixing vessel performance with respect to the two performance requirements. Each mixing vessel was evaluated against these two criteria for two defined waste conditions. One of the wastes was defined by design limits and one was derived from Hanford waste characterization reports. The assessment predicts that three vessel types will satisfy the design criteria for all conditions evaluated. Seven vessel types will not satisfy the performance criteria used for any of the conditions evaluated. The remaining three vessel types provide varying assessments when the different particle characteristics are evaluated. The assessment predicts that three vessel types will satisfy the design criteria for all conditions evaluated. Seven vessel types will not satisfy the performance criteria used for any of the conditions evaluated. The remaining three vessel types provide varying assessments when the different particle characteristics are evaluated. The HLP-022 vessel was also evaluated using 12 m/s pulse jet velocity with 6-in. nozzles, and this design also did not satisfy the criteria for all of the conditions evaluated.

  5. Mixed waste focus area alternative technologies workshop

    SciTech Connect (OSTI)

    Borduin, L.C.; Palmer, B.A.; Pendergrass, J.A.

    1995-05-24

    This report documents the Mixed Waste Focus Area (MWFA)-sponsored Alternative Technology Workshop held in Salt Lake City, Utah, from January 24--27, 1995. The primary workshop goal was identifying potential applications for emerging technologies within the Options Analysis Team (OAT) ``wise`` configuration. Consistent with the scope of the OAT analysis, the review was limited to the Mixed Low-Level Waste (MLLW) fraction of DOE`s mixed waste inventory. The Los Alamos team prepared workshop materials (databases and compilations) to be used as bases for participant review and recommendations. These materials derived from the Mixed Waste Inventory Report (MWIR) data base (May 1994), the Draft Site Treatment Plan (DSTP) data base, and the OAT treatment facility configuration of December 7, 1994. In reviewing workshop results, the reader should note several caveats regarding data limitations. Link-up of the MWIR and DSTP data bases, while representing the most comprehensive array of mixed waste information available at the time of the workshop, requires additional data to completely characterize all waste streams. A number of changes in waste identification (new and redefined streams) occurred during the interval from compilation of the data base to compilation of the DSTP data base with the end result that precise identification of radiological and contaminant characteristics was not possible for these streams. To a degree, these shortcomings compromise the workshop results; however, the preponderance of waste data was linked adequately, and therefore, these analyses should provide useful insight into potential applications of alternative technologies to DOE MLLW treatment facilities.

  6. Understanding predicted shifts in diazotroph biogeography using resource competition theory

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dutkiewicz, S.; Ward, B. A.; Scott, J. R.; Follows, M. J.

    2014-05-19

    We examine the sensitivity of the biogeography of nitrogen fixers to a warming climate and increased aeolian iron deposition in the context of a global Earth System Model. We employ concepts from Resource Ratio Theory to provide a simplifying and transparent interpretation of the results. First we demonstrate that a set of clearly defined, easily diagnosed provinces are consistent with the theory. Using the framework we show that the regions most vulnerable to province shifts and changes in diazotroph biogeography are the Equatorial and South Pacific, and central Atlantic. Warmer and dustier climates favor diazotrophs due to an increase inmore » the ratio of supply rate of iron to fixed nitrogen. The analysis suggests that monitoring of real world province boundaries, indicated by transitions in surface nutrient concentrations, would provide a clear and easily interpreted indicator of ongoing global change. We suggest that the emergent provinces could be a standard diagnostic for global change models, allowing for rapid and transparent interpretation and comparison of model predictions and the underlying mechanisms.« less

  7. Understanding predicted shifts in diazotroph biogeography using resource competition theory

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dutkiewicz, S.; Ward, B. A.; Scott, J. R.; Follows, M. J.

    2014-10-08

    We examine the sensitivity of the biogeography of nitrogen fixers to a warming climate and increased aeolian iron deposition in the context of a global earth system model. We employ concepts from the resource-ratio theory to provide a simplifying and transparent interpretation of the results. First we demonstrate that a set of clearly defined, easily diagnosed provinces are consistent with the theory. Using this framework we show that the regions most vulnerable to province shifts and changes in diazotroph biogeography are the equatorial and South Pacific, and central Atlantic. Warmer and dustier climates favor diazotrophs due to an increase inmore » the ratio of supply rate of iron to fixed nitrogen. We suggest that the emergent provinces could be a standard diagnostic for global change models, allowing for rapid and transparent interpretation and comparison of model predictions and the underlying mechanisms. The analysis suggests that monitoring of real world province boundaries, indicated by transitions in surface nutrient concentrations, would provide a clear and easily interpreted indicator of ongoing global change.« less

  8. Susceptibility and Knight-shift anomalies in cuprate superconductors

    SciTech Connect (OSTI)

    Thoma, J.; Tewari, S.; Ruvalds, J.; Rieck, C.T.

    1995-06-01

    The unconventional temperature variation of the static susceptibility {chi}({ital T}) that has been discovered in various copper oxide superconductors is explained in terms of a model density of states that has a step shape at an energy threshold {ital E}{sub 0} along with a logarithmic Van Hove singularity at the same {ital E}{sub 0}. Calculations of {chi}({ital T}) and the Knight shift above the superconducting transition temperature {ital T}{sub {ital c}} yield good fits to the YBCO, BSCCO, and LSCO data by adjusting only the Fermi energy {mu} in correspondence to the oxygen or Sr content, respectively. When {mu} is right on or slightly below the Van Hove singularity, an upturn in {chi} occurs as the temperature {ital T} is lowered. By contrast, when {mu} is slightly above the threshold energy {ital E}{sub 0}, a downturn in {chi} is achieved as {ital T} is lowered. A correlation of these phenomena with experimental data provides insight into the proximity of the Van Hove singularity to {mu} in several cuprate superconductors. The YBCO and TBCO cuprates with the higher {ital T}{sub {ital c}} values exhibit a nearly constant susceptibility that suggests a Fermi energy well removed from the Van Hove singularity. The sensitivity of {ital T}{sub {ital c}} as well as the susceptibility to chemical changes may provide tests of electronic mechanisms of electron pairing as well as the BCS theory.

  9. Liquid–liquid mixing studies in annular centrifugal contactors comparing stationary mixing vane options

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wardle, Kent E.

    2015-09-11

    Comparative studies of multiphase operation of an annular centrifugal contactor show the impact of housing stationary mixing vane configuration. A number of experimental results for several different mixing vane options are reported for operation of a 12.5 cm engineering-scale contactor unit. Fewer straight vanes give greater mixing-zone hold-up compared to curved vanes. Quantitative comparison of droplet size distribution also showed a significant decrease in mean diameter for four straight vanes versus eight curved vanes. This set of measurements gives a compelling case for careful consideration of mixing vane geometry when evaluating hydraulic operation and extraction process efficiency of annular centrifugalmore » contactors.« less

  10. Resonances and spectral shift function for a magnetic Schroedinger operator

    SciTech Connect (OSTI)

    Khochman, Abdallah

    2009-04-15

    We consider the three-dimensional Schroedinger operator H{sub 0} with a constant magnetic field and subject to an electric potential v{sub 0} depending only on the variable along the magnetic field x{sub 3}. The operator H{sub 0} has infinitely many eigenvalues of infinite multiplicity embedded in its continuous spectrum. We perturb H{sub 0} by smooth scalar potentials V=O(<(x{sub 1},x{sub 2})>{sup -{delta}{sub perpendicular}}{sup -{delta}{sub ||}}), {delta}{sub perpendicular}>2, {delta}{sub ||}>1. We assume also that V and v{sub 0} have an analytic continuation, in the magnetic field direction, in a complex sector outside a compact set. We define the resonances of H=H{sub 0}+V as the eigenvalues of the nonself-adjoint operator obtained from H by analytic distortions of R{sub x{sub 3}}. We study their distribution near any fixed real eigenvalue of H{sub 0}, 2bq+{lambda} for q is an element of N. In a ring centered at 2bq+{lambda} with radii (r,2r), we establish an upper bound, as r tends to 0, of the number of resonances. This upper bound depends on the decay of V at infinity only in the directions (x{sub 1},x{sub 2}). Finally, we deduce a representation of the derivative of the spectral shift function for the operator pair (H{sub 0},H) in terms of resonances. This representation justifies the Breit-Wigner approximation and implies a local trace formula.

  11. Hybrid shearing and phase-shifting point diffraction interferometer

    DOE Patents [OSTI]

    Goldberg, Kenneth Alan; Naulleau, Patrick P.

    2003-06-03

    A new interferometry configuration combines the strengths of two existing interferometry methods, improving the quality and extending the dynamic range of both. On the same patterned mask, placed near the image-plane of an optical system under test, patterns for phase-shifting point diffraction interferometry and lateral shearing interferometry coexist. The former giving verifiable high accuracy for the measurement of nearly diffraction-limited optical systems. The latter enabling the measurement of optical systems with more than one wave of aberration in the system wavefront. The interferometry configuration is a hybrid shearing and point diffraction interferometer system for testing an optical element that is positioned along an optical path including: a source of electromagnetic energy in the optical path; a first beam splitter that is secured to a device that includes means for maneuvering the first beam splitter in a first position wherein the first beam splitter is in the optical path dividing light from the source into a reference beam and a test beam and in a second position wherein the first beam splitter is outside the optical path: a hybrid mask which includes a first section that defines a test window and at least one reference pinhole and a second section that defines a second beam splitter wherein the hybrid mask is secured to a device that includes means for maneuvering either the first section or the second section into the optical path positioned in an image plane that is created by the optical element, with the proviso that the first section of the hybrid mask is positioned in the optical path when first beam splitter is positioned in the optical path; and a detector positioned after the hybrid mask along the optical path.

  12. Scalar relativistic computations of nuclear magnetic shielding and g-shifts with the zeroth-order regular approximation and range-separated hybrid density functionals

    SciTech Connect (OSTI)

    Aquino, Fredy W.; Govind, Niranjan; Autschbach, Jochen

    2011-10-01

    Density functional theory (DFT) calculations of NMR chemical shifts and molecular g-tensors with Gaussian-type orbitals are implemented via second-order energy derivatives within the scalar relativistic zeroth order regular approximation (ZORA) framework. Nonhybrid functionals, standard (global) hybrids, and range-separated (Coulomb-attenuated, long-range corrected) hybrid functionals are tested. Origin invariance of the results is ensured by use of gauge-including atomic orbital (GIAO) basis functions. The new implementation in the NWChem quantum chemistry package is verified by calculations of nuclear shielding constants for the heavy atoms in HX (X=F, Cl, Br, I, At) and H2X (X = O, S, Se, Te, Po), and Te chemical shifts in a number of tellurium compounds. The basis set and functional dependence of g-shifts is investigated for 14 radicals with light and heavy atoms. The problem of accurately predicting F NMR shielding in UF6-nCln, n = 1 to 6, is revisited. The results are sensitive to approximations in the density functionals, indicating a delicate balance of DFT self-interaction vs. correlation. For the uranium halides, the results with the range-separated functionals are mixed.

  13. In Situ Time-Resolved Characterization of Novel Cu-MoO2 Catalysts During the Water-Gas Shift Reaction

    SciTech Connect (OSTI)

    Wen ,W.; Liu, J.; White, M.; Marinkovic, N.; Hanson, J.; Rodriguez, J.

    2007-01-01

    A novel and active Cu-MoO{sub 2} catalyst was synthesized by partial reduction of a precursor CuMoO{sub 4} mixed-metal oxide with CO or H{sub 2} at 200-250 C. The phase transformations of Cu-MoO{sub 2} during H{sub 2} reduction and the water-gas shift reaction could be followed by In situ time resolved XRD techniques. During the reduction process the diffraction pattern of the CuMoO{sub 4} collapsed and the copper metal lines were observed on an amorphous material background that was assigned to molybdenum oxides. During the first pass of water-gas shift (WGS) reaction, diffraction lines for Cu{sub 6}Mo{sub 5}O{sub 18} and MoO{sub 2} appeared around 350 C and Cu{sub 6}Mo{sub 5}O{sub 18} was further transformed to Cu/MoO{sub 2} at higher temperature. During subsequent passes, significant WGS catalytic activity was observed with relatively stable plateaus in product formation around 350, 400 and 500 C. The interfacial interactions between Cu clusters and MoO{sub 2} increased the water-gas shift catalytic activities at 350 and 400 C.

  14. Polymer flood mixing apparatus and method

    SciTech Connect (OSTI)

    Cox, B.M.; Stephenson, S.V.

    1984-02-28

    A method and an apparatus are described for controlling the viscosity of a mixture by controlling the volumetric flow of a fluid with respect to the volumetric flow of another fluid. The apparatus includes volumetric flow detectors for detecting the flow of the 2 fluids. An electronic controller responds to electric signals generated by the volumetric flow detectors in proportion to the respective detective volumetric flows. The output of the controller operates a flow drive element, such as a pump, so that the volumetric flow of one of the fluids is controlled. The volumetric flow of the controlled fluid and the volumetric flow of the other fluid are mixed by a suitable mixer to obtain the mix having the desired viscosity. 7 claims

  15. (Small) Resonant non-Gaussianities: Signatures of a Discrete Shift Symmetry

    Office of Scientific and Technical Information (OSTI)

    in the Effective Field Theory of Inflation (Journal Article) | SciTech Connect Journal Article: (Small) Resonant non-Gaussianities: Signatures of a Discrete Shift Symmetry in the Effective Field Theory of Inflation Citation Details In-Document Search Title: (Small) Resonant non-Gaussianities: Signatures of a Discrete Shift Symmetry in the Effective Field Theory of Inflation We apply the Effective Field Theory of Inflation to study the case where the continuous shift symmetry of the Goldstone

  16. (Small) resonant non-gaussianities: signatures of a discrete shift symmetry

    Office of Scientific and Technical Information (OSTI)

    in the effective field theory of inflation (Journal Article) | SciTech Connect (Small) resonant non-gaussianities: signatures of a discrete shift symmetry in the effective field theory of inflation Citation Details In-Document Search Title: (Small) resonant non-gaussianities: signatures of a discrete shift symmetry in the effective field theory of inflation We apply the Effective Field Theory of Inflation to study the case where the continuous shift symmetry of the Goldstone boson π is

  17. Decrease in carbonyl sulfide in the feed to Claus converters by shift catalysts

    SciTech Connect (OSTI)

    Gens, T.A. (BOC Group Technical Center, Murray Hill, NJ (United States))

    1994-07-01

    The principal reaction in the burner in a Claus plant is the combustion of part of the hydrogen sulfide to form sulfur dioxide, which can react with more hydrogen sulfide to form sulfur. Alumina or commercial shift catalysts were used downstream of a Claus burner to shift carbon monoxide to carbon dioxide before it could react to form carbonyl sulfide. The shift catalysts were effective in preventing formation of carbonyl sulfide, thereby decreasing sulfur losses.

  18. (Small) Resonant non-Gaussianities: Signatures of a Discrete Shift Symmetry

    Office of Scientific and Technical Information (OSTI)

    in the Effective Field Theory of Inflation (Journal Article) | SciTech Connect (Small) Resonant non-Gaussianities: Signatures of a Discrete Shift Symmetry in the Effective Field Theory of Inflation Citation Details In-Document Search Title: (Small) Resonant non-Gaussianities: Signatures of a Discrete Shift Symmetry in the Effective Field Theory of Inflation We apply the Effective Field Theory of Inflation to study the case where the continuous shift symmetry of the Goldstone boson {pi} is

  19. Federal-Tribal Partnership on Climate Change Action Rounds Corner, Shifts

    Office of Environmental Management (EM)

    Into High Gear at 2013 Tribal Nations Conference | Department of Energy Federal-Tribal Partnership on Climate Change Action Rounds Corner, Shifts Into High Gear at 2013 Tribal Nations Conference Federal-Tribal Partnership on Climate Change Action Rounds Corner, Shifts Into High Gear at 2013 Tribal Nations Conference November 19, 2013 - 5:12pm Addthis Federal-Tribal Partnership on Climate Change Action Rounds Corner, Shifts Into High Gear at 2013 Tribal Nations Conference David F. Conrad

  20. Mixing device for materials with large density differences

    DOE Patents [OSTI]

    Gregg, D.W.

    1994-08-16

    An auger-tube pump mixing device is disclosed for mixing materials with large density differences while maintaining low stirring RPM and low power consumption. The mixing device minimizes the formation of vortexes and minimizes the incorporation of small bubbles in the liquid during mixing. By avoiding the creation of a vortex the device provides efficient stirring of full containers without spillage over the edge. Also, the device solves the problem of effective mixing in vessels where the liquid height is large compared to the diameter. Because of the gentle stirring or mixing by the device, it has application for biomedical uses where cell damage is to be avoided. 2 figs.

  1. Mixing device for materials with large density differences

    DOE Patents [OSTI]

    Gregg, David W. (Moraga, CA)

    1994-01-01

    An auger-tube pump mixing device for mixing materials with large density differences while maintaining low stirring RPM and low power consumption. The mixing device minimizes the formation of vortexes and minimizes the incorporation of small bubbles in the liquid during mixing. By avoiding the creation of a vortex the device provides efficient stirring of full containers without spillage over the edge. Also, the device solves the problem of effective mixing in vessels where the liquid height is large compared to the diameter. Because of the gentle stirring or mixing by the device, it has application for biomedical uses where cell damage is to be avoided.

  2. Process for etching mixed metal oxides

    DOE Patents [OSTI]

    Ashby, C.I.H.; Ginley, D.S.

    1994-10-18

    An etching process is described using dicarboxylic and tricarboxylic acids as chelating etchants for mixed metal oxide films such as high temperature superconductors and ferroelectric materials. Undesirable differential etching rates between different metal oxides are avoided by selection of the proper acid or combination of acids. Feature sizes below one micron, excellent quality vertical edges, and film thicknesses in the 100 Angstrom range may be achieved by this method. 1 fig.

  3. Process for etching mixed metal oxides

    DOE Patents [OSTI]

    Ashby, Carol I. H. (Edgewood, NM); Ginley, David S. (Evergreen, CO)

    1994-01-01

    An etching process using dicarboxylic and tricarboxylic acids as chelating etchants for mixed metal oxide films such as high temperature superconductors and ferroelectric materials. Undesirable differential etching rates between different metal oxides are avoided by selection of the proper acid or combination of acids. Feature sizes below one micron, excellent quality vertical edges, and film thicknesses in the 100 Angstom range may be achieved by this method.

  4. MIxed Waste Integrated Program (MWIP): Technology summary

    SciTech Connect (OSTI)

    1994-02-01

    The mission of the Mixed Waste Integrated Program (MWIP) is to develop and demonstrate innovative and emerging technologies for the treatment and management of DOE`s mixed low-level wastes (MLLW) for use by its customers, the Office of Waste Operations (EM-30) and the Office of Environmental Restoration (EM-40). The primary goal of MWIP is to develop and demonstrate the treatment and disposal of actual mixed waste (MMLW and MTRU). The vitrification process and the plasma hearth process are scheduled for demonstration on actual radioactive waste in FY95 and FY96, respectively. This will be accomplished by sequential studies of lab-scale non-radioactive testing followed by bench-scale radioactive testing, followed by field-scale radioactive testing. Both processes create a highly durable final waste form that passes leachability requirements while destroying organics. Material handling technology, and off-gas requirements and capabilities for the plasma hearth process and the vitrification process will be established in parallel.

  5. Differential Light-Shift Cancellation in a Magnetic-Field-Insensitive Transition of {sup 87}Rb

    SciTech Connect (OSTI)

    Chicireanu, R.; Nelson, K. D.; Olmschenk, S.; Porto, J. V.; Lundblad, N.; Derevianko, A.

    2011-02-11

    The precise measurement of transition frequencies of trapped atomic samples is susceptible to inaccuracy arising from the inhomogeneous differential shift of the relevant energy levels in the presence of the trapping fields. We demonstrate near-complete cancellation of the differential ac Stark shift (''light shift'') of a two-photon magnetic-field-insensitive microwave hyperfine (clock) transition in {sup 87}Rb atoms trapped in an optical lattice. Up to 95(2)% of the differential light shift is cancelled while maintaining magnetic-field insensitivity. This technique should have applications in quantum information and frequency metrology.

  6. Guide to good practices for control of on-shift training

    SciTech Connect (OSTI)

    1998-12-01

    This Guide to Good Practices is written to enhance understanding of, and provide direction for, Control of On-Shift Training, Chapter 5 of Department of Energy (DOE) Order 5480.19, Conduct of Operations Requirements for DOE Facilities. The practices in this guide should be considered when planning or reviewing on-shift training programs. ``Control of On-Shift Training`` is an element of an effective Conduct of Operations program. The complexity and array of activities performed in DOE facilities dictate the necessary for a coordinated on-shift training program to meet the continuous demand for skilled, well-trained personnel to promote safe and efficient operations.

  7. Iron-ceria Aerogels Doped with Palladium as Water-gas Shift Catalysts for the Production of Hydrogen

    SciTech Connect (OSTI)

    Bali, S.; Huggins, F; Ernst, R; Pugmire, R; Huffman, G; Eyring, E

    2010-01-01

    Mixed 4.5% iron oxide-95.5% cerium oxide aerogels doped with 1% and 2% palladium (Pd) by weight have been synthesized, and their activities for the catalysis of water-gas shift (WGS) reaction have been determined. The aerogels were synthesized using propylene oxide as the proton scavenger for the initiation of hydrolysis and polycondensation of a homogeneous alcoholic solution of cerium(III) chloride heptahydrate and iron(III) chloride hexahydrate precursor. Palladium was doped onto some of these materials by gas-phase incorporation (GPI) using ({eta}{sup 3}-allyl)({eta}{sup 5}-cyclopentadienyl)palladium as the volatile Pd precursor. Water-gas shift catalytic activities were evaluated in a six-channel fixed-bed reactor at atmospheric pressure and reaction temperatures ranging from 150 to 350 C. Both 1% and 2% Pd-doped 4.5% iron oxide-95.5% cerium oxide aerogels showed WGS activities that increased significantly from 150 to 350 C. The activities of 1% Pd-doped 4.5% iron oxide-95.5% cerium oxide aerogels were also compared with that of the 1% Pd-doped ceria aerogel without iron. The WGS activity of 1% Pd on 4.5% iron oxide-95.5% cerium oxide aerogels is substantially higher (5 times) than the activity of 1% Pd-doped ceria aerogel without iron. The gas-phase incorporation results in a better Pd dispersion. Ceria aerogel provides a nonrigid structure wherein iron is not significantly incorporated inside the matrix, thereby resulting in better contact between the Fe and Pd and thus enhancing the WGS activity. Further, neither Fe nor Pd is reduced during the ceria-aerogel-catalyzed WGS reaction. This behavior contrasts with that noted for other Fe-based WGS catalysts, in which the original ferric oxide is typically reduced to a nonstoichiometric magnetite form.

  8. Charles Mix Electric Assn, Inc | Open Energy Information

    Open Energy Info (EERE)

    Charles Mix Electric Assn, Inc Jump to: navigation, search Name: Charles Mix Electric Assn, Inc Place: South Dakota Phone Number: 605-487-7321 Website: www.cme.coop Twitter:...

  9. Water and Gold: A Promising Mix for Future Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water and Gold: A Promising Mix for Future Batteries Water and Gold: A Promising Mix for Future Batteries Berkeley Lab Study Reveals Molecular Structure of Water at Gold Electrodes...

  10. Intercomparison of model simulations of mixed-phase clouds observed...

    Office of Scientific and Technical Information (OSTI)

    Radiation Measurement (ARM) program's Mixed-Phase Arctic Cloud Experiment. The observed cloud occurred in a well-mixed boundary layer with a cloud top temperature of -15 C. The ...

  11. Investigation of Mixed Oxide Catalysts for NO Oxidation | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Mixed Oxide Catalysts for NO Oxidation Investigation of Mixed Oxide Catalysts for NO Oxidation 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon ace078_muntean_2012_o.pdf More Documents & Publications Investigation of Mixed Oxide Catalysts for NO Oxidation Vehicle Technologies Office Merit Review 2014: Investigation of Mixed Oxide Catalysts for NO Oxidation Vehicle Technologies Office Merit Review

  12. Urea Mixing Design -- Simulation and Test Investigation | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Mixing Design -- Simulation and Test Investigation Urea Mixing Design -- Simulation and Test Investigation Effective urea mixing design should be based on the placement and nature of the selected injector, and new approaches for mixing may be found from the biotech and chemical engineering industries. PDF icon deer12_miao.pdf More Documents & Publications Optimization of a turbocharger for high EGR applications SCR Performance Optimization Through Advancements in Aftertreatment

  13. Independent Oversight Review, Advanced Mixed Waste Treatment Project- April 2013

    Broader source: Energy.gov [DOE]

    Review of Radiation Protection Program Implementation at the Advanced Mixed Waste Treatment Project of the Idaho Site

  14. Feature Extraction of PDV Challenge Data Set A with Digital Down Shift (DDS)

    SciTech Connect (OSTI)

    Tunnell, T. W.

    2012-10-18

    This slide-show is about data analysis in photonic Doppler velocimetry. The digital down shift subtracts a specified velocity (frequency) from all components in the Fourier frequency domain and generates both the down shifted in-phase and out-of-phase waveforms so that phase and displacement can be extracted through a continuous unfold of the arctangent.

  15. CO (Carbon Monoxide Mixing Ratio System) Handbook

    SciTech Connect (OSTI)

    Biraud, S

    2011-02-23

    The main function of the CO instrument is to provide continuous accurate measurements of carbon monoxide mixing ratio at the ARM SGP Central Facility (CF) 60-meter tower (36.607 °N, 97.489 °W, 314 meters above sea level). The essential feature of the control and data acquisition system is to record signals from a Thermo Electron 48C and periodically calibrate out zero and span drifts in the instrument using the combination of a CO scrubber and two concentrations of span gas (100 and 300 ppb CO in air). The system was deployed on May 25, 2005.

  16. Resonantly enhanced four-wave mixing

    DOE Patents [OSTI]

    Begley, Richard F. (Los Alamos, NM); Kurnit, Norman A. (Santa Fe, NM)

    1978-01-01

    A method and apparatus for achieving large susceptibilities and long interaction lengths in the generation of new wavelengths in the infrared spectral region. A process of resonantly enhanced four-wave mixing is employed, utilizing existing laser sources, such as the CO.sub.2 laser, to irradiate a gaseous media. The gaseous media, comprising NH.sub.3, CH.sub.3 F, D.sub.2, HCl, HF, CO, and H.sub.2 or some combination thereof, are of particular interest since they are capable of providing high repetition rate operation at high flux densities where crystal damage problems become a limitation.

  17. Increasing jet entrainment, mixing and spreading

    DOE Patents [OSTI]

    Farrington, R.B.

    1994-08-16

    A free jet of air is disturbed at a frequency that substantially matches natural turbulences in the free jet to increase the entrainment, mixing, and spreading of air by the free jet, for example in a room or other enclosure. The disturbances are created by pulsing the flow of air that creates the free jet at the desired frequency. Such pulsing of the flow of air can be accomplished by sequentially occluding and opening a duct that confines and directs the flow of air, such as by rotating a disk on an axis transverse to the flow of air in the duct. 11 figs.

  18. Increasing jet entrainment, mixing and spreading

    DOE Patents [OSTI]

    Farrington, Robert B. (Wheatridge, CO)

    1994-01-01

    A free jet of air is disturbed at a frequency that substantially matches natural turbulences in the free jet to increase the entrainment, mixing, and spreading of air by the free jet, for example in a room or other enclosure. The disturbances are created by pulsing the flow of air that creates the free jet at the desired frequency. Such pulsing of the flow of air can be accomplished by sequentially occluding and opening a duct that confines and directs the flow of air, such as by rotating a disk on an axis transverse to the flow of air in the duct.

  19. Theoretical Screening of Mixed Solid Sorbent for

    Office of Scientific and Technical Information (OSTI)

    xtended A b stra c t o f 2 0 1 4 AICliE S pring M eeting, New O rleans, LA, M ar.30-A pr.02, 20 1 4 Theoretical Screening of Mixed Solid Sorbent for Applications to C 0 2 Capture Technology Yuhua Duan' N ational E nergy T echnology Laboratory, United States D epartm ent o f Energy, Pittsburgh, Pennsylvania 15236, USA Abstract Since current technologies for capturing CO2 to fight global clim ate change are still too energy intensive, there is a critical need for developm ent o f new m aterials

  20. Mixed-Precision Spectral Deferred Correction: Preprint

    SciTech Connect (OSTI)

    Grout, Ray W. S.

    2015-09-02

    Convergence of spectral deferred correction (SDC), where low-order time integration methods are used to construct higher-order methods through iterative refinement, can be accelerated in terms of computational effort by using mixed-precision methods. Using ideas from multi-level SDC (in turn based on FAS multigrid ideas), some of the SDC correction sweeps can use function values computed in reduced precision without adversely impacting the accuracy of the final solution. This is particularly beneficial for the performance of combustion solvers such as S3D [6] which require double precision accuracy but are performance limited by the cost of data motion.

  1. Method and apparatus for reducing mixed waste

    DOE Patents [OSTI]

    Elliott, Michael L. (Kennewick, WA); Perez, Jr., Joseph M. (Richland, WA); Chapman, Chris C. (Richland, WA); Peters, Richard D. (Pasco, WA)

    1995-01-01

    The present invention is a method and apparatus for in-can waste reduction. The method is mixing waste with combustible material prior to placing the waste into a waste reduction vessel. The combustible portion is ignited, thereby reducing combustible material to ash and non-combustible material to a slag. Further combustion or heating may be used to sinter or melt the ash. The apparatus is a waste reduction vessel having receiving canister connection means on a first end, and a waste/combustible mixture inlet on a second end. An oxygen supply is provided to support combustion of the combustible mixture.

  2. Mixed Mode Fuel Injector And Injection System

    DOE Patents [OSTI]

    Stewart, Chris Lee; Tian, Ye; Wang, Lifeng; Shafer, Scott F.

    2005-12-27

    A fuel injector includes a homogenous charge nozzle outlet set and a conventional nozzle outlet set that are controlled respectively by first and second three way needle control valves. Each fuel injector includes first and second concentric needle valve members. One of the needle valve members moves to an open position for a homogenous charge injection event, while the other needle valve member moves to an open position for a conventional injection event. The fuel injector has the ability to operate in a homogenous charge mode with a homogenous charge spray pattern, a conventional mode with a conventional spray pattern or a mixed mode.

  3. Transient Mixed Convection Validation for NGNP

    SciTech Connect (OSTI)

    Smith, Barton; Schultz, Richard

    2015-10-19

    The results of this project are best described by the papers and dissertations that resulted from the work. They are included in their entirety in this document. They are: (1) Jeff Harris PhD dissertation (focused mainly on forced convection); (2) Blake Lance PhD dissertation (focused mainly on mixed and transient convection). This dissertation is in multi-paper format and includes the article currently submitted and one to be submitted shortly; and, (3) JFE paper on CFD Validation Benchmark for Forced Convection.

  4. Isotope shifts in francium isotopes Fr 206 - 213 and Fr 221

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Collister, R.; Gwinner, G.; Tandecki, M.; Behr, J. A.; Pearson, M. R.; Zhang, J.; Orozco, L. A.; Aubin, S.; Gomez, E.; FrPNC Collaboration

    2014-11-07

    We present the isotope shifts of the 7s1/2 to 7p1/2 transition for francium isotopes ²⁰⁶⁻²¹³Fr with reference to ²²¹Fr collected from two experimental periods. The shifts are measured on a sample of atoms prepared within a magneto-optical trap by a fast sweep of radio-frequency sidebands applied to a carrier laser. King plot analysis, which includes literature values for 7s1/2 to 7p3/2 isotope shifts, provides a field shift constant ratio of 1.0520(10) and a difference between the specific mass shift constants of 170(100) GHz amu between the D₁ and D₂ transitions, of sufficient precision to differentiate between ab initio calculations.

  5. Thermal Imaging Technique for Measuring Mixing of Fluids - Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    fluid flow. Current methods rely on different physical principles such as: pressure measurement, particle tracking using images, heat removal from a wire and Doppler shift...

  6. US pipelines report mixed results for 1993

    SciTech Connect (OSTI)

    True, W.R.

    1994-11-21

    US natural gas pipelines started 1994 in generally better conditions than a year earlier. These companies' operational and financial results for 1993 indicate modest but continuing improvement. Petroleum liquids pipelines, on the other hand, suffered reduced revenues and incomes last: increased deliveries and trunkline movement of liquid petroleum products failed fully to offset fewer barrels of crude oil moving through the companies' pipeline systems. Revenues, incomes, mileage operated, and other data are tracked in Oil and Gas Journal's exclusive Economics Report. Additionally, this report contains extensive data on actual costs of pipeline construction compared with what companies expected to spend at the time of projects' approvals. The paper also discusses the continuing shift of natural gas pipelines as merchants to role of transporter; what was spent; the US interstate network; pipeline mileage; deliveries; the top 10 companies; construction activities; cost trends; and cost components.

  7. Water-Gas-Shift Membrane Reactor for High-Pressure Hydrogen Production. A comprehensive project report (FY2010 - FY2012)

    SciTech Connect (OSTI)

    Klaehn, John; Peterson, Eric; Orme, Christopher; Bhandari, Dhaval; Miller, Scott; Ku, Anthony; Polishchuk, Kimberly; Narang, Kristi; Singh, Surinder; Wei, Wei; Shisler, Roger; Wickersham, Paul; McEvoy, Kevin; Alberts, William; Howson, Paul; Barton, Thomas; Sethi, Vijay

    2013-01-01

    Idaho National Laboratory (INL), GE Global Research (GEGR), and Western Research Institute (WRI) have successfully produced hydrogen-selective membranes for water-gas-shift (WGS) modules that enable high-pressure hydrogen product streams. Several high performance (HP) polymer membranes were investigated for their gas separation performance under simulated (mixed gas) and actual syngas conditions. To enable optimal module performance, membranes with high hydrogen (H2) selectivity, permeance, and stability under WGS conditions are required. The team determined that the VTEC PI 80-051 and VTEC PI 1388 (polyimide from Richard Blaine International, Inc.) are prime candidates for the H2 gas separations at operating temperatures (~200C). VTEC PI 80-051 was thoroughly analyzed for its H2 separations under syngas processing conditions using more-complex membrane configurations, such as tube modules and hollow fibers. These membrane formats have demonstrated that the selected VTEC membrane is capable of providing highly selective H2/CO2 separation (? = 7-9) and H2/CO separation (? = 40-80) in humidified syngas streams. In addition, the VTEC polymer membranes are resilient within the syngas environment (WRI coal gasification) at 200C for over 1000 hours. The information within this report conveys current developments of VTEC PI 80-051 as an effective H2 gas separations membrane for high-temperature syngas streams.

  8. Mixing in wicking structures and the use of enhanced mixing within wicks in microchannel devices

    DOE Patents [OSTI]

    Stenkamp, Victoria S [Richland, WA; TeGrotenhuis, Ward E [Kennewick, WA; Wegeng, Robert S [Richland, WA

    2011-04-19

    Advanced wicking structures and methods utilizing these structures are described. The use of advanced wicking structures can promote rapid mass transfer while maintaining high capillary pressure through the use of small pores. Particularly improved results in fluid contacting processes can be achieved by enhanced mixing within a wicking layer within a microchannel.

  9. Mixing in wicking structures and the use of enhanced mixing within wicks in microchannel devices

    DOE Patents [OSTI]

    Stenkamp, Victoria S. (Richland, WA); TeGrotenhuis, Ward E. (Kennewick, WA); Wegeng, Robert S. (Alexandria, VA)

    2009-06-02

    Advanced wicking structures and methods utilizing these structures are described. The use of advanced wicking structures can promote rapid mass transfer while maintaining high capillary pressure through the use of small pores. Particularly improved results in fluid contacting processes can be achieved by enhanced mixing within a wicking layer within a microchannel.

  10. Guide to good practices for the selection, training, and qualification of shift technical advisors

    SciTech Connect (OSTI)

    1993-02-01

    The DOE Guide to Good Practices For the Selection, Training, and Qualification of Shift Technical Advisors can be used by any DOE nuclear facility that has implemented the shift technical advisor (STA) position. DOE Order 5480.20A, Personnel Selection, Qualification and Training Requirements for DOE Nuclear Facilities, states that only Category A reactors must have a shift technical advisor. However, many DOE nuclear facilities have implemented the shift technical advisor position to provide independent on-shift technical advice and counsel to the shift operating personnel to help determine cause and mitigation of facility accidents. Those DOE nuclear facilities that have implemented or are going to implement the shift technical advisor position will find this guide useful. This guide addresses areas that may be covered by other training programs. In these cases, it is unnecessary (and undesirable) to duplicate these areas in the STA training program as long as the specific skills and knowledge essential for STAs are addressed. The guide is based on the premise that the trainee has not completed any facility-specific training other than general employee training.

  11. SU-E-T-575: Isocenter Shifts in Treatment Planning and Its Clinical Implications

    SciTech Connect (OSTI)

    Ahmed, Y; Damiani, S; Cao, Y; Jamshidi, A

    2014-06-01

    Purpose: To investigate causes of isocenter shifts in treatment planning and its clinical impact on patient treatment efficiency and safety. Methods/Materials: Treatment planning data of 340 patients under treatment over 8 weeks period were gathered to identify isocenter shifts according to site of the treatment, types of treatment plan or types of the machine used. Treatment plans included inversed and forward IMRT, as well as 3D plans. Treatment sites included pelvis, chest, abdomen, breasts, head and necks and extremities. Re-planning were performed without the isocenter shift for pelvis and chest plans, the dosimetric parameters such as PTV coverage, and dose sparing of OARs of these plans were analyzed and compared. Results/Discussions: Results showed that the isocenter shift was always necessary for some of sites such as breasts, two or more distinctive PTVs, or special cases such as large PTV treated with enhanced dynamic wedge. Many other cases, the re-planning results indicated 53% of the plans that the same quality of the plan can be achieved without the shift of the isocenter. Repositioning patients on a daily basis demanded unambiguous instructions for therapists for patient setups, and additional time to perform the shifts before treatment. Opportunities for error propagation exist during the communication and hand-over of such plans. Conclusion: Isocenter shifts demanded unambiguous instructions and times for therapists for daily patient setups, therefore it impacted both safety and efficiency of the patient treatment. Based on the analysis, the isocenter shifts were unavoidable for cases such as treatment of multiple sites, overcoming limitations of treatment machines, and/or sometime better dosimetry. However, we found many initially proposed shifts may have been eliminated either by careful planning or by improved CT simulation process such as detailed review of the images and localization of the PTV during simulation.

  12. Report 20.5: Chromaticity Shift Modes of LED PAR38 Lamps Operated in

    Energy Savers [EERE]

    Steady-State Conditions | Department of Energy 5: Chromaticity Shift Modes of LED PAR38 Lamps Operated in Steady-State Conditions Report 20.5: Chromaticity Shift Modes of LED PAR38 Lamps Operated in Steady-State Conditions PDF icon Report 20.5: Chromaticity Shift Modes of LED PAR38 Lamps Operated in Steady-State Conditions More Documents & Publications Report 20.4: Lumen and Chromaticity Maintenance of LED PAR38 Lamps Retail Lamps Study 3.2: Lumen and Chromaticity Maintenance of LED A

  13. Optimum focusing of Gaussian laser beams: Beam waist shift in spot size minimization

    SciTech Connect (OSTI)

    Li, Y.; Katz, J. )

    1994-04-01

    Optimum focusing of Gaussian laser beams is first discussed by Dickson, who described the change in beam radius under the effect of focusing system parameters. The purpose of this study is to present a formulation for calculating the waist shift under various optimum conditions. Because the variations of beam waist can be measured directly, the waist shift in a focused Gaussian beam is a more practical parameter than the movement of the intensity maximum that is the subject for investigators of the well-known focal shift problem.

  14. Deconvolution of mixed magnetism in multilayer graphene

    SciTech Connect (OSTI)

    Swain, Akshaya Kumar; Bahadur, Dhirendra

    2014-06-16

    Magnetic properties of graphite modified at the edges by KCl and exfoliated graphite in the form of twisted multilayered graphene (<4 layers) are analyzed to understand the evolution of magnetic behavior in the absence of any magnetic impurities. The mixed magnetism in multilayer graphene is deconvoluted using Low field-high field hysteresis loops at different temperatures. In addition to temperature and the applied magnetic field, the density of edge state spins and the interaction between them decides the nature of the magnetic state. By virtue of magnetometry and electron spin resonance studies, we demonstrate that ferromagnetism is intrinsic and is due to the interactions among various paramagnetic centers. The strength of these magnetic correlations can be controlled by modifying the structure.

  15. Extended model for Richtmyer-Meshkov mix

    SciTech Connect (OSTI)

    Mikaelian, K O

    2009-11-18

    We examine four Richtmyer-Meshkov (RM) experiments on shock-generated turbulent mix and find them to be in good agreement with our earlier simple model in which the growth rate h of the mixing layer following a shock or reshock is constant and given by 2{alpha}A{Delta}v, independent of initial conditions h{sub 0}. Here A is the Atwood number ({rho}{sub B}-{rho}{sub A})/({rho}{sub B} + {rho}{sub A}), {rho}{sub A,B} are the densities of the two fluids, {Delta}V is the jump in velocity induced by the shock or reshock, and {alpha} is the constant measured in Rayleigh-Taylor (RT) experiments: {alpha}{sup bubble} {approx} 0.05-0.07, {alpha}{sup spike} {approx} (1.8-2.5){alpha}{sup bubble} for A {approx} 0.7-1.0. In the extended model the growth rate beings to day after a time t*, when h = h*, slowing down from h = h{sub 0} + 2{alpha}A{Delta}vt to h {approx} t{sup {theta}} behavior, with {theta}{sup bubble} {approx} 0.25 and {theta}{sup spike} {approx} 0.36 for A {approx} 0.7. They ascribe this change-over to loss of memory of the direction of the shock or reshock, signaling transition from highly directional to isotropic turbulence. In the simplest extension of the model h*/h{sub 0} is independent of {Delta}v and depends only on A. They find that h*/h{sub 0} {approx} 2.5-3.5 for A {approx} 0.7-1.0.

  16. Ab Initio Calculation of Nuclear Magnetic Resonance Chemical Shift Anisotropy Tensors 1. Influence of Basis Set on the Calculation of 31P Chemical Shifts

    SciTech Connect (OSTI)

    Alam, T.M.

    1998-09-01

    The influence of changes in the contracted Gaussian basis set used for ab initio calculations of nuclear magnetic resonance (NMR) phosphorous chemical shift anisotropy (CSA) tensors was investigated. The isotropic chemical shitl and chemical shift anisotropy were found to converge with increasing complexity of the basis set at the Hartree-Fock @IF) level. The addition of d polarization function on the phosphorous nucIei was found to have a major impact of the calculated chemical shi~ but diminished with increasing number of polarization fimctions. At least 2 d polarization fimctions are required for accurate calculations of the isotropic phosphorous chemical shift. The introduction of density fictional theory (DFT) techniques through tie use of hybrid B3LYP methods for the calculation of the phosphorous chemical shift tensor resulted in a poorer estimation of the NMR values, even though DFT techniques result in improved energy and force constant calculations. The convergence of the W parametem with increasing basis set complexity was also observed for the DFT calculations, but produced results with consistent large deviations from experiment. The use of a HF 6-31 l++G(242p) basis set represents a good compromise between accuracy of the simulation and the complexity of the calculation for future ab initio calculations of 31P NMR parameters in larger complexes.

  17. Extracting Scattering Phase-Shifts in Higher Partial-Waves from...

    Office of Scientific and Technical Information (OSTI)

    Scattering Phase-Shifts in Higher Partial-Waves from Lattice QCD Calculations Authors: Luu, T ; Savage, M J Publication Date: 2011-01-18 OSTI Identifier: 1068270 Report...

  18. The WIPP RCRA Part B permit application for TRU mixed waste disposal

    SciTech Connect (OSTI)

    Johnson, J.E. [Westinghouse Electric Corp., Carlsbad, NM (United States). Waste Isolation Div.; Snider, C.A. [USDOE Carlsbad Area Office, NM (United States)

    1995-12-31

    In August 1993, the New Mexico Environment Department (NMED) issued a draft permit for the Waste Isolation Pilot Plant (WIPP) to begin experiments with transuranic (TRU) mixed waste. Subsequently, the Department of Energy (DOE) decided to cancel the on-site test program, opting instead for laboratory testing. The Secretary of the NMED withdrew the draft permit in 1994, ordering the State`s Hazardous and Radioactive Waste Bureau to work with the DOE on submittal of a revised permit application. Revision 5 of the WIPP`s Resource Conservation and Recovery Act (RCRA) Part B Permit Application was submitted to the NMED in May 1995, focusing on disposal of 175,600 m{sup 3} of TRU mixed waste over a 25 year span plus ten years for closure. A key portion of the application, the Waste Analysis Plan, shifted from requirements to characterize a relatively small volume of TRU mixed waste for on-site experiments, to describing a complete program that would apply to all DOE TRU waste generating facilities and meet the appropriate RCRA regulations. Waste characterization will be conducted on a waste stream basis, fitting into three broad categories: (1) homogeneous solids, (2) soil/gravel, and (3) debris wastes. Techniques used include radiography, visually examining waste from opened containers, radioassay, headspace gas sampling, physical sampling and analysis of homogeneous wastes, and review of documented acceptable knowledge. Acceptable knowledge of the original organics and metals used, and the operations that generated these waste streams is sufficient in most cases to determine if the waste has toxicity characteristics, hazardous constituents, polychlorinated biphenyls (PBCs), or RCRA regulated metals.

  19. MIXING STUDY FOR JT-71/72 TANKS

    SciTech Connect (OSTI)

    Lee, S.

    2013-11-26

    All modeling calculations for the mixing operations of miscible fluids contained in HBLine tanks, JT-71/72, were performed by taking a three-dimensional Computational Fluid Dynamics (CFD) approach. The CFD modeling results were benchmarked against the literature results and the previous SRNL test results to validate the model. Final performance calculations were performed by using the validated model to quantify the mixing time for the HB-Line tanks. The mixing study results for the JT-71/72 tanks show that, for the cases modeled, the mixing time required for blending of the tank contents is no more than 35 minutes, which is well below 2.5 hours of recirculation pump operation. Therefore, the results demonstrate the adequacy of 2.5 hours mixing time of the tank contents by one recirculation pump to get well mixed.

  20. Shift Register Clock Rate Effects on Coincidence Collection 50MHz versus 4MHz Comparison Tests

    SciTech Connect (OSTI)

    Newell, Matthew R.; Bourret, Steven C.; Swinhoe, Martyn Thomas

    2015-11-03

    The following report identifies and quantifies the timing differences between the older slower Shift Register Coincidence/Multiplicity modules and today’s modern higher speed devices. Modern high speed Shift Register Coincidence/Multiplicity instruments employ high speed internal clocks that run at frequencies more than ten times the older units, typically 50MHz. These higher speed clocks allow for a finer time resolution when recording input pulses.

  1. Method for the manufacture of phase shifting masks for EUV lithography

    DOE Patents [OSTI]

    Stearns, Daniel G.; Sweeney, Donald W.; Mirkarimi, Paul B.; Barty, Anton

    2006-04-04

    A method for fabricating an EUV phase shift mask is provided that includes a substrate upon which is deposited a thin film multilayer coating that has a complex-valued reflectance. An absorber layer or a buffer layer is attached onto the thin film multilayer, and the thickness of the thin film multilayer coating is altered to introduce a direct modulation in the complex-valued reflectance to produce phase shifting features.

  2. Quantized beam shifts in graphene (Journal Article) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Quantized beam shifts in graphene Citation Details In-Document Search This content will become publicly available on February 21, 2017 Title: Quantized beam shifts in graphene Authors: Kort-Kamp, W. J. M. ; Sinitsyn, N. A. ; Dalvit, D. A. R. Publication Date: 2016-02-22 OSTI Identifier: 1238697 Type: Publisher's Accepted Manuscript Journal Name: Physical Review B Additional Journal Information: Journal Volume: 93; Journal Issue: 8; Journal ID: ISSN 2469-9950 Publisher: American Physical Society

  3. Extracting Scattering Phase-Shifts in Higher Partial-Waves from Lattice QCD

    Office of Scientific and Technical Information (OSTI)

    Calculations (Journal Article) | SciTech Connect Extracting Scattering Phase-Shifts in Higher Partial-Waves from Lattice QCD Calculations Citation Details In-Document Search Title: Extracting Scattering Phase-Shifts in Higher Partial-Waves from Lattice QCD Calculations Authors: Luu, T ; Savage, M J Publication Date: 2011-01-18 OSTI Identifier: 1068270 Report Number(s): LLNL-JRNL-472171 DOE Contract Number: W-7405-ENG-48 Resource Type: Journal Article Resource Relation: Journal Name: Physical

  4. Hick Shifts Gears in NERSC's Storage Systems Group, Takes on New Role

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hick Shifts Gears in NERSC's Storage Systems Group Hick Shifts Gears in NERSC's Storage Systems Group, Takes on New Role October 7, 2015 JasonHick2015 Jason Hick, who has been group lead of the Storage Systems Group (SSG) at NERSC since first coming to the center in 2006, has decided to return to his roots as a senior storage engineer, applying his computer science background and management expertise to NERSC's next-generation data storage and data management challenges. Effective immediately,

  5. OPS 9.2 Shift Routines and Operating Practices 8/24/98 | Department of

    Energy Savers [EERE]

    Energy 2 Shift Routines and Operating Practices 8/24/98 OPS 9.2 Shift Routines and Operating Practices 8/24/98 The objective of this surveillance is to verify that standards for the professional conduct of operations personnel are established and followed so that operator performance meets the expectations of DOE and facility management. This surveillance provides a basis for evaluating watchstanding practices of operations personnel external to the control area in various plant locations.

  6. Method of chaotic mixing and improved stirred tank reactors

    DOE Patents [OSTI]

    Muzzio, F.J.; Lamberto, D.J.

    1999-07-13

    The invention provides a method and apparatus for efficiently achieving a homogeneous mixture of fluid components by introducing said components having a Reynolds number of between about [le]1 to about 500 into a vessel and continuously perturbing the mixing flow by altering the flow speed and mixing time until homogeneity is reached. This method prevents the components from aggregating into non-homogeneous segregated regions within said vessel during mixing and substantially reduces the time the admixed components reach homogeneity. 19 figs.

  7. Method of chaotic mixing and improved stirred tank reactors

    DOE Patents [OSTI]

    Muzzio, Fernando J. (Monroe, NJ); Lamberto, David J. (Edison, NJ)

    1999-01-01

    The invention provides a method and apparatus for efficiently achieving a homogeneous mixture of fluid components by introducing said components having a Reynolds number of between about .ltoreq.1 to about 500 into a vessel and continuously perturbing the mixing flow by altering the flow speed and mixing time until homogeniety is reached. This method prevents the components from aggregating into non-homogeneous segregated regions within said vessel during mixing and substantially reduces the time the admixed components reach homogeneity.

  8. Radiochemical Mix Diagnostic in the Presence of Burn

    SciTech Connect (OSTI)

    Hayes, Anna C.

    2014-01-28

    There is a general interest in radiochemical probes of hydrodamicalmix in burning regions of NIF capsule. Here we provide estimates for the production of 13N from mixing of 10B ablator burning hotspot of a capsule. By comparing the 13N signal with x-ray measurements of the ablator mix into the hotspot it should be possible to estimate the chunkiness of this mix.

  9. Pyrolysis and hydrolysis of mixed polymer waste comprising

    Office of Scientific and Technical Information (OSTI)

    polyethyleneterephthalate and polyethylene to sequentially recover (Patent) | SciTech Connect Pyrolysis and hydrolysis of mixed polymer waste comprising polyethyleneterephthalate and polyethylene to sequentially recover Citation Details In-Document Search Title: Pyrolysis and hydrolysis of mixed polymer waste comprising polyethyleneterephthalate and polyethylene to sequentially recover A process of using fast pyrolysis in a carrier gas to convert a plastic waste feedstream having a mixed

  10. Radiograph and passive data analysis using mixed variable optimization

    Office of Scientific and Technical Information (OSTI)

    (Patent) | SciTech Connect Patent: Radiograph and passive data analysis using mixed variable optimization Citation Details In-Document Search Title: Radiograph and passive data analysis using mixed variable optimization Disclosed herein are representative embodiments of methods, apparatus, and systems for performing radiography analysis. For example, certain embodiments perform radiographic analysis using mixed variable computation techniques. One exemplary system comprises a radiation

  11. Fully Developed Turbulent Mixing in an Annular Sector

    SciTech Connect (OSTI)

    Lim, Hyun-Kyung; Zhou, Yijie; de Almeida, Valmor F; Glimm, James G

    2014-01-01

    We review recent progress on the characterization of turbulent mixing fluid flow and relate these ideas to high-speed, two-phase Couette flow with application to mixing in a centrifugal contactor. The general ideas are more broadly applicable and have been applied to the study of Rayleigh-Taylor and Richtmyer-Meshkov fluid mixing, combustion in the engine of a scram jet and the analysis of inertial confinement pellet simulations.

  12. Idaho's Advanced Mixed Waste Treatment Project Details 2013

    Office of Environmental Management (EM)

    Accomplishments | Department of Energy Idaho's Advanced Mixed Waste Treatment Project Details 2013 Accomplishments Idaho's Advanced Mixed Waste Treatment Project Details 2013 Accomplishments December 24, 2013 - 12:00pm Addthis IDAHO FALLS, Idaho - EM and its contractor, Idaho Treatment Group (ITG), safely and compliantly met all of their production and shipping targets in the Advanced Mixed Waste Treatment Project (AMWTP) at the Idaho site in 2013. AMWTP's purpose is to safely process and

  13. Hydropower Still in the Mix | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydropower Still in the Mix Hydropower Still in the Mix April 27, 2015 - 9:39am Addthis Hydropower Still in the Mix Hoyt Battey Market Acceleration and Deployment Program Manager, Wind and Water Power Technologies Office Hydropower has provided clean, reliable power for more than a hundred years, and remains the largest source of renewable electricity in the United States. While hydropower dates back to the early 1900s, many people are unaware of hydropower's existing infrastructure since newer

  14. DOE Extends Advanced Mixed Waste Treatment Project Contract | Department of

    Office of Environmental Management (EM)

    Energy Advanced Mixed Waste Treatment Project Contract DOE Extends Advanced Mixed Waste Treatment Project Contract September 29, 2015 - 6:00pm Addthis Media Contact Danielle Miller, 208-526-5709 Idaho Falls, ID - The U.S. Department of Energy's Office of Environmental Management (EM) today announced it is extending its contract for the Advanced Mixed Waste Treatment Project at the Idaho Site for a period of 6 months. The contract period for the current contractor, Idaho Treatment Group

  15. Parameterizing the Mixing State of Complex Submicron Aerosols...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DA Knopf, MK Gilles, and RC Moffet. 2015. "Chemical imaging of ambient aerosol particles: Observational constraints on mixing state parameterization." Journal of Geophysical...

  16. Radon Measurements of Atmospheric Mixing (RAMIX) 2006-2014 Final...

    Office of Scientific and Technical Information (OSTI)

    Title: Radon Measurements of Atmospheric Mixing (RAMIX) 2006-2014 Final Campaign Summary ... estimates of regional land-atmosphere carbon exchange (i.e., estimates based on ...

  17. Fuel Mix and Emissions Disclosure | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    customers the fuel mix of its electricity production and the associated sulfur dioxide, nitrogen oxide, and carbon dioxide emissions emissions, expressed in pounds per 1000...

  18. Towards a Characterization of Arctic Mixed-Phase Clouds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    manual classification of cloud phase. Using collocated cloud radar and depolarization lidar observations, it is shown that mixed-phase conditions have a high correlation with a...

  19. ARM - Field Campaign - Radon Measurements of Atmospheric Mixing (RAMIX

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2008) govCampaignsRadon Measurements of Atmospheric Mixing (RAMIX 2008) ARM Data Discovery Browse Data Related Campaigns Radon Measurements of Atmospheric Mixing (RAMIX) 2006.11.01, Fischer, SGP Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Radon Measurements of Atmospheric Mixing (RAMIX 2008) 2008.04.01 - 2009.03.31 Lead Scientist : Marc Fischer For data sets, see below. Abstract At present, uncertainty in vertical mixing

  20. Fuel Mix and Emissions Disclosure | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    to disclose to residential and small commercial customers details regarding the fuel mix and emissions of electric generation. Such information is provided to customers four...

  1. Extended Formulations in Mixed-integer Convex Programming | Argonne...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    reformulations are shown to be effective extended formulations themselves because they encode separability structure. For mixed-integer conic-representable problems, we provide the...

  2. Charles Mix County, South Dakota: Energy Resources | Open Energy...

    Open Energy Info (EERE)

    Zone Subtype A. Places in Charles Mix County, South Dakota Castalia, South Dakota Dante, South Dakota Geddes, South Dakota Lake Andes, South Dakota Marty, South Dakota...

  3. A multifluid mix model with material strength effects

    SciTech Connect (OSTI)

    Chang, C. H. [Los Alamos National Laboratory; Scannapieco, A. J. [Los Alamos National Laboratory

    2012-04-23

    We present a new multifluid mix model. Its features include material strength effects and pressure and temperature nonequilibrium between mixing materials. It is applicable to both interpenetration and demixing of immiscible fluids and diffusion of miscible fluids. The presented model exhibits the appropriate smooth transition in mathematical form as the mixture evolves from multiphase to molecular mixing, extending its applicability to the intermediate stages in which both types of mixing are present. Virtual mass force and momentum exchange have been generalized for heterogeneous multimaterial mixtures. The compression work has been extended so that the resulting species energy equations are consistent with the pressure force and material strength.

  4. Fuel Mix and Emissions Disclosure | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    restructuring legislation, Illinois established provisions for the disclosure of fuel mix and emissions data. All electric utilities and alternative retail electric...

  5. Sandia Energy - Turbulent Mixed-Mode Combustion Studied in a...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Turbulent Mixed-Mode Combustion Studied in a New Piloted Burner Home Transportation Energy CRF Office of Science Capabilities News News & Events Research & Capabilities Fuel...

  6. ARM - Field Campaign - Radon Measurements of Atmospheric Mixing...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    data sets, see below. Abstract Uncertainty in vertical mixing between the surface layer, boundary layer, and free troposphere leads to significant uncertainty in determining...

  7. Department of Energy Idaho - Advanced Mixed Waste Treatment Project...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    > AMWTP Contract Idaho Treatment Group, LLC (ITG) Advanced Mixed Waste Treatment Project Contract Basic Contract Contract Modifications Last Updated: 10052015 Privacy Statement...

  8. Long-Term Stewardship of Mixed Wastes: Passive Reactive Barriers...

    Office of Scientific and Technical Information (OSTI)

    Long-Term Stewardship of Mixed Wastes: Passive Reactive Barriers for Simultaneous In Situ Remediation of Chlorinated Solvent, Heavy Metal, and Radionuclide Contaminants Citation...

  9. Thermochemical cycle of a mixed metal oxide for augmentation...

    Office of Scientific and Technical Information (OSTI)

    Thermochemical cycle of a mixed metal oxide for augmentation of thermal energy storage in solid particles. Citation Details In-Document Search Title: Thermochemical cycle of a ...

  10. LANL disassembles "pits," makes mixed-oxide fuel

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    LANL disassembles "pits," makes mixed-oxide fuel LANL has successfully disassembled nuclear weapons "pits" and converted them into more than 240 kilograms of plutonium oxide. ...

  11. Fuel Mix and Emissions Disclosure | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    utility restructuring legislation requires all electric companies and electricity suppliers to provide customers with details regarding the fuel mix and emissions of electric...

  12. The Neutral kaon mixing parameter B(K) from unquenched mixed-action lattice QCD

    SciTech Connect (OSTI)

    Christopher Aubin, Jack Laiho, Ruth S. Van de Water

    2010-01-01

    We calculate the neutral kaon mixing parameter B{sub K} in unquenched lattice QCD using asqtad-improved staggered sea quarks and domain-wall valence quarks. We use the '2+1' flavor gauge configurations generated by the MILC Collaboration, and simulate with multiple valence and sea quark masses at two lattice spacings of a {approx} 0.12 fm and a {approx} 0.09 fm. We match the lattice determination of B{sub K} to the continuum value using the nonperturbative method of Rome-Southampton, and extrapolate B{sub K} to the continuum and physical quark masses using mixed action chiral perturbation theory. The 'mixed-action' method enables us to control all sources of systematic uncertainty and therefore to precisely determine B{sub K}; we find a value of B{sub K}{sup {ovr MS},NDR} (2 GeV) = 0.527(6)(21), where the first error is statistical and the second is systematic.

  13. A novel fermentation strategy for removing the key inhibitor acetic acid and efficiently utilizing the mixed sugars from lignocellulosic hydrolysates

    SciTech Connect (OSTI)

    Mark A. Eiteman PHD; Elliot Altman Phd

    2009-02-11

    As part of preliminary research efforts, we have completed several experiments which demonstrate 'proof of concept.' These experiments addressed the following three questions: (1) Can a synthetic mixed sugar solution of glucose and xylose be efficiently consumed using the multi-organism approach? (2) Can this approach be used to accumulate a model product? (3) Can this approach be applied to the removal of an inhibitor, acetate, selectively from mixtures of xylose and glucose? To answer the question of whether this multi-organism approach can effectively consume synthetic mixed sugar solutions, we first tested substrate-selective uptake using two strains, one unable to consume glucose and one unable to consume xylose. The xylose-selective strain ALS998 has mutations in the three genes involved in glucose uptake, rendering it unable to consume glucose: ptsG codes for the Enzyme IICB{sup Glc} of the phosphotransferase system (PTS) for carbohydrate transport (Postma et al., 1993), manZ codes for the IID{sup Man} domain of the mannose PTS permease (Huber, 1996), glk codes for glucokinase (Curtis and Epstein 1975) We also constructed strain ALS1008 which has a knockout in the xylA gene encoding for xylose isomerase, rendering ALS1008 unable to consume xylose. Two batch experiments and one continuous bioprocess were completed. In the first experiment, each strain was grown separately in a defined medium of 8 g/L xylose and 15 g/L glucose which represented xylose and glucose concentrations that can be generated by actual biomass. In the second experiment, the two strains were grown together in batch in the same defined, mixed-sugar medium. In a third experiment, we grew the strains continuously in a 'chemostat', except that we shifted the concentrations of glucose and xylose periodically to observe how the system would respond. (For example, we shifted the glucose concentration suddenly from 15 g/L to 30 g/L in the feed).

  14. Safety analysis approaches or mixed transuranic waste.

    SciTech Connect (OSTI)

    Courtney, J. C.; Dwight, C. C.; Forrester, R. J.; Lehto, M. A.; Pan, Y. C.

    1999-02-10

    Argonne National Laboratory (ANL) has completed a survey of assumptions and techniques used for safety analyses at seven sites that handle or store mixed transuranic (TRU) waste operated by contractors for the US Department of Energy (DOE). While approaches to estimating on-site and off-site consequences of hypothetical accidents differ, there are commonalities in all of the safety studies. This paper identifies key parameters and methods used to estimate the radiological consequences associated with release of waste forms under abnormal conditions. Specific facilities are identified by letters with their safety studies listed in a bibliography rather than as specific references so that similarities and differences are emphasized in a nonjudgmental manner. References are provided for specific parameters used to project consequences associated with compromise of barriers and dispersion of potentially hazardous materials. For all of the accidents and sites, estimated dose commitments are well below guidelines even using highly conservative assumptions. Some of the studies quantified the airborne concentrations of toxic materials; this paper only addresses these analyses briefly, as an entire paper could be dedicated to this subject.

  15. Zeolite Membrane Reactor for Water Gas Shift Reaction for Hydrogen Production

    SciTech Connect (OSTI)

    Lin, Jerry Y.S.

    2013-01-29

    Gasification of biomass or heavy feedstock to produce hydrogen fuel gas using current technology is costly and energy-intensive. The technology includes water gas shift reaction in two or more reactor stages with inter-cooling to maximize conversion for a given catalyst volume. This project is focused on developing a membrane reactor for efficient conversion of water gas shift reaction to produce a hydrogen stream as a fuel and a carbon dioxide stream suitable for sequestration. The project was focused on synthesizing stable, hydrogen perm-selective MFI zeolite membranes for high temperature hydrogen separation; fabricating tubular MFI zeolite membrane reactor and stable water gas shift catalyst for membrane reactor applications, and identifying experimental conditions for water gas shift reaction in the zeolite membrane reactor that will produce a high purity hydrogen stream. The project has improved understanding of zeolite membrane synthesis, high temperature gas diffusion and separation mechanisms for zeolite membranes, synthesis and properties of sulfur resistant catalysts, fabrication and structure optimization of membrane supports, and fundamentals of coupling reaction with separation in zeolite membrane reactor for water gas shift reaction. Through the fundamental study, the research teams have developed MFI zeolite membranes with good perm-selectivity for hydrogen over carbon dioxide, carbon monoxide and water vapor, and high stability for operation in syngas mixture containing 500 part per million hydrogen sulfide at high temperatures around 500C. The research teams also developed a sulfur resistant catalyst for water gas shift reaction. Modeling and experimental studies on the zeolite membrane reactor for water gas shift reaction have demonstrated the effective use of the zeolite membrane reactor for production of high purity hydrogen stream.

  16. Apparatus for mixing char-ash into coal stream

    DOE Patents [OSTI]

    Blaskowski, Henry J. (Avon, CT)

    1982-03-16

    Apparatus for obtaining complete mixing of char with coal prior to the introduction of the mixture into the combustor (30) of a coal gasifier (10). The coal is carried in one air stream (22), and the char in another air stream (54), to a riffle plate arrangement (26), where the streams of solid are intimately mixed or blended.

  17. Ethanol production in fermentation of mixed sugars containing xylose

    DOE Patents [OSTI]

    Viitanen, Paul V.; Mc Cutchen, Carol M.; Li; Xu; Emptage, Mark; Caimi, Perry G.; Zhang, Min; Chou, Yat-Chen; Franden, Mary Ann

    2009-12-08

    Xylose-utilizing Z. mobilis strains were found to have improved ethanol production when grown in medium containing mixed sugars including xylose if sorbitol or mannitol was included in the medium. The effect was seen in concentrations of mixed sugars where no growth lag period occurs, as well as in higher sugars concentrations.

  18. Tunable infrared source employing Raman mixing

    DOE Patents [OSTI]

    Byer, Robert L. (Stanford, CA); Herbst, Richard L. (Menlo Park, CA)

    1980-01-01

    A tunable source of infrared radiation is obtained by irradiating an assemblage of Raman active gaseous atoms or molecules with a high intensity pumping beam of coherent radiation at a pump frequency .omega..sub.p to stimulate the generation of Stokes wave energy at a Stokes frequency .omega..sub.s and to stimulate the Raman resonant mode at the Raman mode frequency .omega..sub.R within the irradiated assemblage where the pump frequency .omega..sub.p minus the Stokes frequency .omega..sub.s is equal to the Raman mode frequency .omega..sub.R. The stimulated assemblage is irradiated with a tunable source of coherent radiation at a frequency .omega..sub.i to generate the output infrared radiation of the frequency .omega..sub.0 which is related to the Raman mode frequency .omega..sub.R and the input wave .omega..sub.i by the relation .omega..sub.0 =.omega..sub.i .+-..omega..sub.R. In one embodiment the interaction between the pump wave energy .omega..sub.p and the tunable input wave energy .omega..sub.i is collinear and the ratio of the phase velocity mismatch factor .DELTA.k to the electric field exponential gain coefficient T is within the range of 0.1 to 5. In another embodiment the pump wave energy .omega..sub.p and the tunable input wave energy .omega..sub.i have velocity vectors k.sub.p and k.sub.i which cross at an angle to each other to compensate for phase velocity mismatches in the medium. In another embodiment, the Stokes wave energy .omega..sub.s is generated by pump energy .omega..sub.p in a first Raman cell and .omega..sub.s, .omega..sub.i and .omega..sub.p are combined in a second Raman mixing cell to produce the output at .omega..sub.i.

  19. Age Dating of Mixed SNM--Preliminary Investigations

    SciTech Connect (OSTI)

    Yuan, D., Guss, P. P., Yfantis, E., Klingensmith, A., Emer, D.

    2011-12-01

    Recently we investigated the nuclear forensics problem of age determination for mixed special nuclear material (SNM). Through limited computational mixing experiments and interactive age analysis, it was observed that age dating results are generally affected by the mixing of samples with different assays or even by small radioactive material contamination. The mixing and contamination can be detected through interactive age analysis, a function provided by the Decay Interaction, Visualization and Analysis (DIVA) software developed by NSTec. It is observed that for mixed SNM with two components, the age estimators typically fall into two distinct clusters on the time axis. This suggests that averaging or other simple statistical methods may not always be suitable for age dating SNM mixtures. Instead, an interactive age analysis would be more suitable for age determination of material components of such SNM mixtures. This work was supported by the National Center for Nuclear Security (NCNS).

  20. Anomalously Large Polarization Effect Responsible for Excitonic Red Shifts in PbSe Quantum Dot Solids

    SciTech Connect (OSTI)

    A Wolcott; V Doyeux; C Nelson; R Gearba; K Lei; K Yager; A dolocan; K Williams; D Nguyen; X Zhu

    2011-12-31

    The formation of solid thin films from colloidal semiconductor quantum dots (QDs) is often accompanied by red shifts in excitonic transitions, but the mechanisms responsible for the red shifts are under debate. We quantitatively address this issue using optical absorption spectroscopy of two-dimensional (2D) and three-dimensional (3D) arrays of PbSe QDs with controlled inter-QD distance, which was determined by the length of alkanedithiol linking molecules. With decreasing inter-QD distance, the first and second exciton absorption peaks show increasing red shifts. Using thin films consisting of large and isolated QDs embedded in a matrix of small QDs, we determine that a dominant contribution to the observed red shift is due to changes in polarization of the dielectric environment surrounding each QD ({approx}88%), while electronic or transition dipole coupling plays a lesser role. However, the observed red shifts are more than 1 order of magnitude larger than theoretical predictions based on the dielectric polarization effect for spherical QDs. We attribute this anomalously large polarization effect to deviations of the exciton wave functions from eigenfunctions of the idealized spherical quantum well model.

  1. Implementation, capabilities, and benchmarking of Shift, a massively parallel Monte Carlo radiation transport code

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pandya, Tara M.; Johnson, Seth R.; Evans, Thomas M.; Davidson, Gregory G.; Hamilton, Steven P.; Godfrey, Andrew T.

    2015-12-21

    This paper discusses the implementation, capabilities, and validation of Shift, a massively parallel Monte Carlo radiation transport package developed and maintained at Oak Ridge National Laboratory. It has been developed to scale well from laptop to small computing clusters to advanced supercomputers. Special features of Shift include hybrid capabilities for variance reduction such as CADIS and FW-CADIS, and advanced parallel decomposition and tally methods optimized for scalability on supercomputing architectures. Shift has been validated and verified against various reactor physics benchmarks and compares well to other state-of-the-art Monte Carlo radiation transport codes such as MCNP5, CE KENO-VI, and OpenMC. Somemore » specific benchmarks used for verification and validation include the CASL VERA criticality test suite and several Westinghouse AP1000® problems. These benchmark and scaling studies show promising results.« less

  2. DOE handbook: Guide to good practices for the selection, training, and qualification of shift supervisors

    SciTech Connect (OSTI)

    1999-04-01

    This Department of Energy (DOE) handbook is approved for use by all DOE Components and their contractors. The Handbook incorporates editorial changes to DOE-STD-1061-93, ``Guide to Good Practices for the Selection, Training, and Qualification of shift Supervisors,`` and supersedes DOE-STD-1061-93. Technical content of this Handbook has not changed from the original technical standard. Changes are primarily editorial improvements, redesignation of the standard to a Handbook, and format changes to conform with current Technical Standards Program procedures. This guide, used in conjunction with a facility-specific job analysis, provides a framework for the selection, training, qualification, and professional development of reactor facility and non-reactor nuclear facility shift supervisors. Training and qualification programs based on this guide should provide assurance that shift supervisors perform their jobs safely and competently.

  3. Vortex precession frequency and its amplitude-dependent shift in cylindrical nanomagnets

    SciTech Connect (OSTI)

    Metlov, Konstantin L.

    2013-12-14

    Frequency of free magnetic vortex precession in circular soft ferromagnetic nano-cylinders (magnetic dots) of various sizes is an important parameter, used in design of spintronic devices (such as spin-torque microwave nano-oscillators) and characterization of magnetic nanostructures. Here, using a recently developed collective-variable approach to non-linear dynamics of magnetic textures in planar nano-magnets, this frequency and its amplitude-dependent shift are computed analytically and plotted for the full range of cylinder geometries. The frequency shift is positive in large planar dots, but becomes negative in smaller and more elongated ones. At certain dot dimensions, a zero frequency shift is realized, which can be important for enhancing frequency stability of magnetic nano-oscillators.

  4. Capabilities, Implementation, and Benchmarking of Shift, a Massively Parallel Monte Carlo Radiation Transport Code

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pandya, Tara M; Johnson, Seth R; Evans, Thomas M; Davidson, Gregory G; Hamilton, Steven P; Godfrey, Andrew T

    2016-01-01

    This work discusses the implementation, capabilities, and validation of Shift, a massively parallel Monte Carlo radiation transport package developed and maintained at Oak Ridge National Laboratory. It has been developed to scale well from laptop to small computing clusters to advanced supercomputers. Special features of Shift include hybrid capabilities for variance reduction such as CADIS and FW-CADIS, and advanced parallel decomposition and tally methods optimized for scalability on supercomputing architectures. Shift has been validated and verified against various reactor physics benchmarks and compares well to other state-of-the-art Monte Carlo radiation transport codes such as MCNP5, CE KENO-VI, and OpenMC. Somemorespecific benchmarks used for verification and validation include the CASL VERA criticality test suite and several Westinghouse AP1000 R problems. These benchmark and scaling studies show promising results.less

  5. A single-gradient junction technique to replace multiple-junction shifts for craniospinal irradiation treatment

    SciTech Connect (OSTI)

    Hadley, Austin; Ding, George X.

    2014-01-01

    Craniospinal irradiation (CSI) requires abutting fields at the cervical spine. Junction shifts are conventionally used to prevent setup errorinduced overdosage/underdosage from occurring at the same location. This study compared the dosimetric differences at the cranial-spinal junction between a single-gradient junction technique and conventional multiple-junction shifts and evaluated the effect of setup errors on the dose distributions between both techniques for a treatment course and single fraction. Conventionally, 2 lateral brain fields and a posterior spine field(s) are used for CSI with weekly 1-cm junction shifts. We retrospectively replanned 4 CSI patients using a single-gradient junction between the lateral brain fields and the posterior spine field. The fields were extended to allow a minimum 3-cm field overlap. The dose gradient at the junction was achieved using dose painting and intensity-modulated radiation therapy planning. The effect of positioning setup errors on the dose distributions for both techniques was simulated by applying shifts of 3 and 5 mm. The resulting cervical spine doses across the field junction for both techniques were calculated and compared. Dose profiles were obtained for both a single fraction and entire treatment course to include the effects of the conventional weekly junction shifts. Compared with the conventional technique, the gradient-dose technique resulted in higher dose uniformity and conformity to the target volumes, lower organ at risk (OAR) mean and maximum doses, and diminished hot spots from systematic positioning errors over the course of treatment. Single-fraction hot and cold spots were improved for the gradient-dose technique. The single-gradient junction technique provides improved conformity, dose uniformity, diminished hot spots, lower OAR mean and maximum dose, and one plan for the entire treatment course, which reduces the potential human error associated with conventional 4-shifted plans.

  6. Multi-pulse frequency shifted (MPFS) multiple access modulation for ultra wideband

    DOE Patents [OSTI]

    Nekoogar, Faranak; Dowla, Farid U.

    2012-01-24

    The multi-pulse frequency shifted technique uses mutually orthogonal short duration pulses o transmit and receive information in a UWB multiuser communication system. The multiuser system uses the same pulse shape with different frequencies for the reference and data for each user. Different users have a different pulse shape (mutually orthogonal to each other) and different transmit and reference frequencies. At the receiver, the reference pulse is frequency shifted to match the data pulse and a correlation scheme followed by a hard decision block detects the data.

  7. The Shifting Landscape of Ratepayer-Funded Energy Efficiency in the U.S. |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy The Shifting Landscape of Ratepayer-Funded Energy Efficiency in the U.S. The Shifting Landscape of Ratepayer-Funded Energy Efficiency in the U.S. Over the last two decades, utility ratepayer funding for energy efficiency programs has seen both booms and busts. Currently, roughly 35 states implement some set of ratepayer-funded electric and/or natural gas energy efficiency programs, with a total U.S. budget of $3.1 billion in 2008 (CEE 2008).1 The top 10 states account

  8. Spin relaxation and linear-in-electric-field frequency shift in an

    Office of Scientific and Technical Information (OSTI)

    arbitrary, time-independent magnetic field (Technical Report) | SciTech Connect Technical Report: Spin relaxation and linear-in-electric-field frequency shift in an arbitrary, time-independent magnetic field Citation Details In-Document Search Title: Spin relaxation and linear-in-electric-field frequency shift in an arbitrary, time-independent magnetic field A method is presented to calculate the spin relaxation times T{sub 1}, T{sub 2} due to a nonuniform magnetic field, and the

  9. Spin relaxation and linear-in-electric-field frequency shift in an

    Office of Scientific and Technical Information (OSTI)

    arbitrary, time-independent magnetic field (Technical Report) | SciTech Connect Technical Report: Spin relaxation and linear-in-electric-field frequency shift in an arbitrary, time-independent magnetic field Citation Details In-Document Search Title: Spin relaxation and linear-in-electric-field frequency shift in an arbitrary, time-independent magnetic field × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of

  10. Measurement of the nuclear polarization of hydrogen and deuterium molecules using a Lamb-shift polarimeter

    SciTech Connect (OSTI)

    Engels, Ralf Gorski, Robert; Grigoryev, Kiril; Mikirtychyants, Maxim; Rathmann, Frank; Seyfarth, Hellmut; Strher, Hans; Weiss, Philipp; Kochenda, Leonid; Kravtsov, Peter; Trofimov, Viktor; Tschernov, Nikolay; Vasilyev, Alexander; Vznuzdaev, Marat; Schieck, Hans Paetz gen.

    2014-10-15

    Lamb-shift polarimeters are used to measure the nuclear polarization of protons and deuterons at energies of a few keV. In combination with an ionizer, the polarization of hydrogen and deuterium atoms was determined after taking into account the loss of polarization during the ionization process. The present work shows that the nuclear polarization of hydrogen or deuterium molecules can be measured as well, by ionizing the molecules and injecting the H{sub 2}{sup +} (or D{sub 2}{sup +}) ions into the Lamb-shift polarimeter.

  11. Industrial mixing techniques for Hanford double-shell tanks

    SciTech Connect (OSTI)

    Daymo, E.A.

    1997-09-01

    Jet mixer pumps are currently the baseline technology for sludge mobilization and mixing in one-million gallon double-shell tanks at the Hanford and Savannah River Sites. Improvements to the baseline jet mixer pump technology are sought because jet mixer pumps have moving parts that may fail or require maintenance. Moreover, jet mixers are relatively expensive, they heat the waste, and, in some cases, may not mobilize enough of the sludge. This report documents a thorough literature search for commercially available applicable mixing technologies that could be used for double-shell tank sludge mobilization and mixing. Textbooks, research articles, conference proceedings, mixing experts, and the Thomas Register were consulted to identify applicable technologies. While there are many commercial methods that could be used to mobilize sludge or mix the contents of a one-million gallon tank, few will work given the geometrical constraints (e.g., the mixer must fit through a 1.07-m-diameter riser) or the tank waste properties (e.g., the sludge has such a high yield stress that it generally does not flow under its own weight). Pulsed fluid jets and submersible Flygt mixers have already been identified at Hanford and Savannah River Sites for double-shell tank mixing applications. While these mixing technologies may not be applicable for double-shell tanks that have a thick sludge layer at the bottom (since too many of these mixers would need to be installed to mobilize most of the sludge), they may have applications in tanks that do not have a settled solids layer. Retrieval projects at Hanford and other U.S. Department of Energy sites are currently evaluating the effectiveness of these mixing techniques for tank waste applications. The literature search did not reveal any previously unknown technologies that should be considered for sludge mobilization and mixing in one-million gallon double-shell tanks.

  12. Advanced Mixed Waste Treatment Project Achieves Impressive Safety and

    Office of Environmental Management (EM)

    Production Marks | Department of Energy Advanced Mixed Waste Treatment Project Achieves Impressive Safety and Production Marks Advanced Mixed Waste Treatment Project Achieves Impressive Safety and Production Marks June 26, 2013 - 12:00pm Addthis Only the 620 employees at EM’s Advanced Mixed Waste Treatment Project earned the right to this vanity plate after working more than 14 million hours without a lost-time injury and safely and compliantly shipping more than 50,000 cubic meters of

  13. Mixed species radioiodine air sampling readout and dose assessment system

    DOE Patents [OSTI]

    Distenfeld, Carl H. (Mattituck, NY); Klemish, Jr., Joseph R. (Bohemia, NY)

    1978-01-01

    This invention provides a simple, reliable, inexpensive and portable means and method for determining the thyroid dose rate of mixed airborne species of solid and gaseous radioiodine without requiring highly skilled personnel, such as health physicists or electronics technicians. To this end, this invention provides a means and method for sampling a gas from a source of a mixed species of solid and gaseous radioiodine for collection of the mixed species and readout and assessment of the emissions therefrom by cylindrically, concentrically and annularly molding the respective species around a cylindrical passage for receiving a conventional probe-type Geiger-Mueller radiation detector.

  14. ARM - Field Campaign - Characterization of Black Carbon Mixing State

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govCampaignsCharacterization of Black Carbon Mixing State ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Characterization of Black Carbon Mixing State 2012.11.01 - 2013.06.14 Lead Scientist : Arthur Sedlacek For data sets, see below. Abstract The objective of the proposed experiments was to characterize the mixing state of black carbon produced in biomass burning using the single particle soot photometer

  15. Impacts of Mixing on Acceptable Indoor Air Quality in Homes

    SciTech Connect (OSTI)

    Sherman, Max H.; Walker, Iain I.

    2010-01-01

    Ventilation reduces occupant exposure to indoor contaminants by diluting or removing them. In a multi-zone environment such as a house, every zone will have different dilution rates and contaminant source strengths. The total ventilation rate is the most important factor in determining occupant exposure to given contaminant sources, but the zone-specific distribution of exhaust and supply air and the mixing of ventilation air can play significant roles. Different types of ventilation systems will provide different amounts of mixing depending on several factors such as air leakage, air distribution system, and contaminant source and occupant locations. Most U.S. and Canadian homes have central heating, ventilation, and air conditioning systems, which tend to mix the air; thus, the indoor air in different zones tends to be well mixed for significant fractions of the year. This article reports recent results of investigations to determine the impact of air mixing on exposures of residential occupants to prototypical contaminants of concern. We summarize existing literature and extend past analyses to determine the parameters than affect air mixing as well as the impacts of mixing on occupant exposure, and to draw conclusions that are relevant for standards development and for practitioners designing and installing home ventilation systems. The primary conclusion is that mixing will not substantially affect the mean indoor air quality across a broad population of occupants, homes, and ventilation systems, but it can reduce the number of occupants who are exposed to extreme pollutant levels. If the policy objective is to minimize the number of people exposed above a given pollutant threshold, some amount of mixing will be of net benefit even though it does not benefit average exposure. If the policy is to minimize exposure on average, then mixing air in homes is detrimental and should not be encouraged. We also conclude that most homes in the US have adequate mixing already, but that new, high-performance homes may require additional mixing. Also our results suggest that some differentiation should be made in policies and standards for systems that provide continuous exhaust, thereby reducing relative dose for occupants overall.

  16. Centrifugal contactor with liquid mixing and flow control vanes and method of mixing liquids of different phases

    DOE Patents [OSTI]

    Jubin, Robert T. (Powell, TN); Randolph, John D. (Maryville, TN)

    1991-01-01

    The invention is directed to a centrifugal contactor for solvent extraction systems. The centrifugal contactor is provided with an annular vertically oriented mixing chamber between the rotor housing and the rotor for mixing process liquids such as the aqueous and organic phases of the solvent extraction process used for nuclear fuel reprocessing. A set of stationary helically disposed vanes carried by the housing is in the lower region of the mixing chamber at a location below the process-liquid inlets for the purpose of urging the liquids in an upward direction toward the inlets and enhancing the mixing of the liquids and mass transfer between the liquids. The upper region of the mixing vessel above the inlets for the process liquids is also provided with a set helically disposed vanes carried by the housing for urging the process liquids in a downward direction when the liquid flow rates through the inlets are relatively high and the liquids contact the vane set in the upper region. The use of these opposing vane sets in the mixing zone maintains the liquid in the mixing zone at suitable levels.

  17. Experimental and numerical investigations of the phase-shift effect in capacitively coupled discharges

    SciTech Connect (OSTI)

    Gao, Fei; Zhang, Yu-Ru; Zhao, Shu-Xia; Wang, You-Nian, E-mail: ynwang@dlut.edu.cn [Key Laboratory of Materials Modification by Laser, Ion, and Electron Beams (Ministry of Education), School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)

    2014-08-15

    The phase-shift effect has been investigated by a Langmuir probe and a fluid model in Ar capacitively coupled plasmas at 50 mTorr. In the discharge, two sources with the same frequency, i.e., 27.12?MHz, are applied on the top and bottom electrodes simultaneously, and the phase shift between them varies from 0 to ?. It is found that the electron density has an off-axis peak near the radial edge when the phase difference is equal to 0 due to the electrostatic edge effect, and the best radial uniformity is observed at a phase difference equal to ?. Furthermore, when the voltage increases, the best radial uniformity is obtained at lower phase shift values. Moreover, the electron energy probability function has a bi-temperature structure at all the selected phase differences at r?=?115?cm. The evolution of the plasma characteristics with the phase difference implies that the best radial uniformity can be obtained, by balancing the electrostatic edge effect and the phase shift effect.

  18. The I=2 ππ S-wave Scattering Phase Shift from Lattice QCD

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Beane, S. R.; Chang, E.; Detmold, W.; Lin, H. W.; Luu, T. C.; Orginos, K.; Parreno, A.; Savage, M. J.; Torok, A.; Walker-Loud, A.

    2012-02-16

    The π+π+ s-wave scattering phase-shift is determined below the inelastic threshold using Lattice QCD. Calculations were performed at a pion mass of mπ ≈ 390 MeV with an anisotropic nf = 2+1 clover fermion discretization in four lattice volumes, with spatial extent L ≈ 2.0, 2.5, 3.0 and 3.9 fm, and with a lattice spacing of bs ≈ 0.123 fm in the spatial direction and bt bs/3.5 in the time direction. The phase-shift is determined from the energy-eigenvalues of π+π+ systems with both zero and non-zero total momentum in the lattice volume using Luscher's method. Our calculations are precise enoughmore »to allow for a determination of the threshold scattering parameters, the scattering length a, the effective range r, and the shape-parameter P, in this channel and to examine the prediction of two-flavor chiral perturbation theory: mπ2 a r = 3+O(mπ2/Λχ2). Chiral perturbation theory is used, with the Lattice QCD results as input, to predict the scattering phase-shift (and threshold parameters) at the physical pion mass. Our results are consistent with determinations from the Roy equations and with the existing experimental phase shift data.« less

  19. Enhanced Oil Recovery Affects the Future Energy Mix | GE Global...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Enhanced Oil Recovery Affects the Future Energy Mix Click to email this to a friend (Opens in new window) Share on Facebook (Opens in new window) Click to share (Opens in new...

  20. Ab initio thermodynamic approach to identify mixed solid sorbents...

    Office of Scientific and Technical Information (OSTI)

    Such Tt may be outside the operating temperature range (To) for a practical capture technology. To adjust Tt to fit the practical To, in this study, three scenarios of mixing ...

  1. Mixing between high velocity clouds and the galactic halo

    SciTech Connect (OSTI)

    Gritton, Jeffrey A.; Shelton, Robin L.; Kwak, Kyujin E-mail: rls@physast.uga.edu

    2014-11-01

    In the Galactic halo, metal-bearing Galactic halo material mixes into high velocity clouds (HVCs) as they hydrodynamically interact. This interaction begins long before the clouds completely dissipate and long before they slow to the velocity of the Galactic material. In order to make quantitative estimates of the mixing efficiency and resulting metal enrichment of HVCs, we made detailed two- and three-dimensional simulations of cloud-interstellar medium interactions. Our simulations track the hydrodynamics and time-dependent ionization levels. They assume that the cloud originally has a warm temperature and extremely low metallicity while the surrounding medium has a high temperature, low density, and substantial metallicity, but our simulations can be generalized to other choices of initial metallicities. In our simulations, mixing between cloud and halo gas noticeably raises the metallicity of the high velocity material. We present plots of the mixing efficiency and metal enrichment as a function of time.

  2. Expandable mixing section gravel and cobble eductor (Patent)...

    Office of Scientific and Technical Information (OSTI)

    conduit that terminates in a nozzle that creates a water jet internal to a tubular mixing section of the pump when water pressure is applied from a primary supply flow; a ...

  3. ARM - Field Campaign - Mixed-Phase Arctic Cloud Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govCampaignsMixed-Phase Arctic Cloud Experiment Campaign Links Science Document M-PACE Website Final Summary Report ARM Data Discovery Browse Data Comments? We would love to hear...

  4. Search for Neutral D Meson Mixing using Semileptonic Decays ...

    Office of Scientific and Technical Information (OSTI)

    the DeltaM distribution and the time-dependence of mixed events directly from the data. Neural networks are used both to select events and to fully reconstruct the Dsup 0....

  5. DOE Chooses Contractor to Disposition Waste at the Advanced Mixed...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    IDAHO, 83403 DOE Chooses Contractor to Disposition Waste at the Advanced Mixed Waste Treatment Project (AMWTP) CH2M Hill Newport News Nuclear, LLC to continue cleanup and waste...

  6. Slurry Retrieval, Pipeline Transport & Plugging and Mixing Workshop

    Office of Environmental Management (EM)

    Gary L. Smith - Office of Waste Processing (EM-21) Slurry Retrieval, Pipeline Transport & Plugging and Mixing Workshop 1 Dr. Gary L. Smith - Office of Waste Processing (EM-21) Dr. ...

  7. Rocky Flats Environmental Technology Site Mixed Residue Consent...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    9-09-24-01 State Colorado Agreement Type Consent Order Legal Driver(s) RCRA Scope Summary Substitute this Consent Order for the MR Consent Order; establish requirements for mixed...

  8. Fuel Mix and Emissions Disclosure | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Customer Choice and Electric Reliability Act of 2000 (P.A. 141) requires electric suppliers to disclose to customers details related to the fuel mix and emissions, in pounds...

  9. Molten carbonate fuel cell cathode with mixed oxide coating

    DOE Patents [OSTI]

    Hilmi, Abdelkader; Yuh, Chao-Yi

    2013-05-07

    A molten carbonate fuel cell cathode having a cathode body and a coating of a mixed oxygen ion conductor materials. The mixed oxygen ion conductor materials are formed from ceria or doped ceria, such as gadolinium doped ceria or yttrium doped ceria. The coating is deposited on the cathode body using a sol-gel process, which utilizes as precursors organometallic compounds, organic and inorganic salts, hydroxides or alkoxides and which uses as the solvent water, organic solvent or a mixture of same.

  10. Simulating Arctic mixed-phase clouds: Sensitivity to environmental

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    conditions and cloud microphysics processes Simulating Arctic mixed-phase clouds: Sensitivity to environmental conditions and cloud microphysics processes Sednev, Igor Lawrence Berkeley National Laboratory Menon, Surabi Lawrence Berkeley National Laboratory McFarquhar, Greg University of Illinois Category: Field Campaigns The importance of Arctic mixed-phase clouds on radiation and the Arctic climate are evaluated using the NASA GISS single column model (SCM) and cloud microphysics and radar

  11. Microsecond Microfluidic Mixing for Investigation of Protein Folding

    Office of Scientific and Technical Information (OSTI)

    Kinetics (Conference) | SciTech Connect Conference: Microsecond Microfluidic Mixing for Investigation of Protein Folding Kinetics Citation Details In-Document Search Title: Microsecond Microfluidic Mixing for Investigation of Protein Folding Kinetics We have developed and characterized a mixer to study the reaction kinetics of protein folding on a microsecond timescale. The mixer uses hydrodynamic focusing of pressure-driven flow in a microfluidic channel to reduce diffusion times as first

  12. Evidence of ion mixing increasing the thermal boundary conductance across

    Office of Scientific and Technical Information (OSTI)

    aluminum/silicon interfaces. (Journal Article) | SciTech Connect Evidence of ion mixing increasing the thermal boundary conductance across aluminum/silicon interfaces. Citation Details In-Document Search Title: Evidence of ion mixing increasing the thermal boundary conductance across aluminum/silicon interfaces. Abstract not provided. Authors: Hattar, Khalid Mikhiel ; Beechem Iii, Thomas Edwin ; Ihlefeld, Jon F. ; Biedermann, Laura Butler ; Piekos, Edward Stanley ; Medlin, Douglas L. [1] ;

  13. Magnetohydrodynamics and deep mixing in evolved stars. I. Two- and

    Office of Scientific and Technical Information (OSTI)

    three-dimensional analytical models for the asymptotic giant branch (Journal Article) | SciTech Connect Magnetohydrodynamics and deep mixing in evolved stars. I. Two- and three-dimensional analytical models for the asymptotic giant branch Citation Details In-Document Search Title: Magnetohydrodynamics and deep mixing in evolved stars. I. Two- and three-dimensional analytical models for the asymptotic giant branch The advection of thermonuclear ashes by magnetized domains emerging near the H

  14. Non carbon mixed conducting materials for PEFC electrocatalysts and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    electrodes | Department of Energy Non carbon mixed conducting materials for PEFC electrocatalysts and electrodes Non carbon mixed conducting materials for PEFC electrocatalysts and electrodes These slides were presented at the 2010 New Fuel Cell Projects Meeting on September 28, 2010. PDF icon 11_iit_ramani.pdf More Documents & Publications DOE's Fuel Cell Catalyst R&D Activities Analysis of the Durability of PEM FC Membrane Electrode Assemblies in Automotive Applications Development

  15. Theoretical Synthesis of Mixed Materials for CO2 Capture Applications

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect Theoretical Synthesis of Mixed Materials for CO2 Capture Applications Citation Details In-Document Search Title: Theoretical Synthesis of Mixed Materials for CO2 Capture Applications These pages provide an example of the layout and style required for the preparation of four-page papers for the TechConnect World 2015 technical proceedings.Documents must be submitted in electronic (Adobe PDFfile) format. Please study the enclosed materials beforebeginning the

  16. Fuel Mix and Emissions Disclosure | Department of Energy

    Energy Savers [EERE]

    Fuel Mix and Emissions Disclosure Fuel Mix and Emissions Disclosure < Back Eligibility Investor-Owned Utility Municipal Utilities Cooperative Utilities Program Info Sector Name State Website http://www.powertochoose.org State Texas Program Type Generation Disclosure Summary Disclosure Requirements As part of Texas's 1999 electric utility restructuring legislation, the state's retail electric providers (REPs) are required to disclose certain information in the form of a standardized

  17. Mixed Analyte Performance Evaluation Program Flyer | Department of Energy

    Office of Environmental Management (EM)

    Mixed Analyte Performance Evaluation Program Flyer Mixed Analyte Performance Evaluation Program Flyer This flyer will explain the MAPEP program, its quality assurance oversight for environmental analytical services, and additional contact information about this program. MAPEP provides quality assurance oversight for environmental analytical services by performing semiannual proficiency testing and evaluation of laboratories managed by the U.S. Department of Energy (DOE), the U.S. Department of

  18. Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Synthesis of Lignocellulosic Biomass | Department of Energy Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol Synthesis of Lignocellulosic Biomass Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol Synthesis of Lignocellulosic Biomass This process design and technoeconomic evaluation addresses the conversion of biomass to ethanol via thermochemical pathways that are expected to be demonstrated at the pilot level by 2012. PDF icon Thermochemical Ethanol via

  19. Design Case Summary: Production of Mixed Alcohols from Municipal Solid

    Office of Environmental Management (EM)

    Waste via Gasification | Department of Energy Design Case Summary: Production of Mixed Alcohols from Municipal Solid Waste via Gasification Design Case Summary: Production of Mixed Alcohols from Municipal Solid Waste via Gasification The Bioenergy Technologies Office develops design cases to understand the current state of conversion technologies and to determine where improvements need to take place in the future. This design case establishes cost targets for converting MSW to ethanol and

  20. Reflection and transmission of light waves from the air-magnetoplasma interface: Spatial and angular Imbert-Fedorov shifts

    SciTech Connect (OSTI)

    Borhanian, Jafar

    2015-03-15

    We have investigated the reflection and transmission of an electromagnetic wave from the air-magnetoplasma interface. The reflection and transmission coefficients are obtained for an arbitrary polarized incident wave. The spatial and angular Imbert-Fedorov (IF) shifts are discussed. The numerical results are presented to study the dependence of the reflection and transmission coefficients and IF shifts on relevant parameters of the system. The plasma and wave parameters can be used to control the reflection coefficients and IF shifts.

  1. SLURRY PUMP MIXING EFFECTIVENESS IN TANK 50H

    SciTech Connect (OSTI)

    Lee, S; Richard Dimenna, R

    2008-04-15

    Computational Fluid Dynamics (CFD) models of Tank 50 with different numbers of pumps and operational modes, including pump rotation, have been developed to estimate flow patterns and the resultant sludge mixing. Major solid obstructions including the tank wall, the pump housing, the pump columns, and the 82-in central support column were included in the model. Transient analyses with a two-equation turbulence model were performed with FLUENT{trademark}, a commercial CFD code. All analyses were based on three-dimensional results. Recommended operational guidance was developed assuming that local fluid velocity and characteristic measures of local turbulence could be used as indicators of sludge suspension and spatial mixing. The calculation results show that three pumps, the maximum number of pumps studied, will give acceptable homogeneous mixing in about 6 minutes in terms of flow patterns and turbulent energy dissipation. These qualitative results are consistent with literature results. Sensitivity calculations have also been performed to assess the impact of different operating modes on sludge suspension and mixing. Two-pump operation provides a marginal level of sludge suspension and turbulent mixing, while one pump does not provide acceptable flow patterns and turbulent eddies for good mixing.

  2. Characterization of supersonic mixing in a nonreacting Mach 2 combustor

    SciTech Connect (OSTI)

    Hollo, S.D.; Mcdaniel, J.C.; Hartfield, R.J., JR. )

    1992-01-01

    Planar measurements of the injection mole fraction distribution and the velocity field within a nonreacting model SCRAMJET combustor have been made using laser-induced iodine fluorescence. The combustor geometry investigated in this work is staged transverse injection of air into a Mach 2 freestream. A complete three-dimensional survey of the injectant mole fraction distribution has been generated and a single planar velocity measurement has been completed. The measurements reveal the dramatic effect of streamwise vortices on the mixing of the injectant in the near field of the injectors, as well as the rapid mixing generated by staging two field injectors. Analysis of the downstream decay of the maximum injectant mole fraction in this and other nonreacting combustor geometries indicates that the relative rate of injectant mixing well downstream of the injectors is independent of combustor geometry, combustor Mach number, and injectant molecular weight. Mixing within this region of the combustor is dominated by turbulent diffusion within the injectant plume. The transition of the dominant mixing mechanism, from vortex-driven mixing in the near field to turbulent diffusion in the far field, was found to occur in the region between 10 and 20 jet diameters downstream of the injectors. 22 refs.

  3. HYDRAULICS AND MIXING EVALUATIONS FOR NT-21/41 TANKS

    SciTech Connect (OSTI)

    Lee, S.; Barnes, O.

    2014-11-17

    The hydraulic results demonstrate that pump head pressure of 20 psi recirculates about 5.6 liters/min flowrate through the existing 0.131-inch orifice when a valve connected to NT-41 is closed. In case of the valve open to NT-41, the solution flowrates to HB-Line tanks, NT-21 and NT-41, are found to be about 0.5 lpm and 5.2 lpm, respectively. The modeling calculations for the mixing operations of miscible fluids contained in the HB-Line tank NT-21 were performed by taking a three-dimensional Computational Fluid Dynamics (CFD) approach. The CFD modeling results were benchmarked against the literature results and the previous SRNL test results to validate the model. Final performance calculations were performed for the nominal case by using the validated model to quantify the mixing time for the HB-Line tank. The results demonstrate that when a pump recirculates a solution volume of 5.7 liters every minute out of the 72-liter tank contents containing two acid solutions of 2.7 M and 0 M concentrations (i.e., water), a minimum mixing time of 1.5 hours is adequate for the tank contents to get the tank contents adequately mixed. In addition, the sensitivity results for the tank contents of 8 M existing solution and 1.5 M incoming species show that the mixing time takes about 2 hours to get the solutions mixed.

  4. Environmental effects of interstate power trading on electricity consumption mixes

    SciTech Connect (OSTI)

    Joe Marriott; H. Scott Matthews

    2005-11-15

    Although many studies of electricity generation use national or state average generation mix assumptions, in reality a great deal of electricity is transferred between states with very different mixes of fossil and renewable fuels, and using the average numbers could result in incorrect conclusions in these studies. The authors create electricity consumption profiles for each state and for key industry sectors in the U.S. based on existing state generation profiles, net state power imports, industry presence by state, and an optimization model to estimate interstate electricity trading. Using these 'consumption mixes' can provide a more accurate assessment of electricity use in life-cycle analyses. It is concluded that the published generation mixes for states that import power are misleading, since the power consumed in-state has a different makeup than the power that was generated. And, while most industry sectors have consumption mixes similar to the U.S. average, some of the most critical sectors of the economy - such as resource extraction and material processing sectors - are very different. This result does validate the average mix assumption made in many environmental assessments, but it is important to accurately quantify the generation methods for electricity used when doing life-cycle analyses. 16 refs., 7 figs., 2 tabs.

  5. Mixed and Low-Level Treatment Facility Project

    SciTech Connect (OSTI)

    Not Available

    1992-04-01

    This appendix contains the mixed and low-level waste engineering design files (EDFS) documenting each low-level and mixed waste stream investigated during preengineering studies for Mixed and Low-Level Waste Treatment Facility Project. The EDFs provide background information on mixed and low-level waste generated at the Idaho National Engineering Laboratory. They identify, characterize, and provide treatment strategies for the waste streams. Mixed waste is waste containing both radioactive and hazardous components as defined by the Atomic Energy Act and the Resource Conservation and Recovery Act, respectively. Low-level waste is waste that contains radioactivity and is not classified as high-level waste, transuranic waste, spent nuclear fuel, or 11e(2) byproduct material as defined by DOE 5820.2A. Test specimens of fissionable material irradiated for research and development only, and not for the production of power or plutonium, may be classified as low-level waste, provided the concentration of transuranic is less than 100 nCi/g. This appendix is a tool that clarifies presentation format for the EDFS. The EDFs contain waste stream characterization data and potential treatment strategies that will facilitate system tradeoff studies and conceptual design development. A total of 43 mixed waste and 55 low-level waste EDFs are provided.

  6. OPS 9.5 Control of On-Shift Training 3/14/01 | Department of Energy

    Energy Savers [EERE]

    5 Control of On-Shift Training 3/14/01 OPS 9.5 Control of On-Shift Training 3/14/01 The objective of this surveillance is to verify that on-shift training is properly controlled and is conducted in accordance with facility instructions and procedures. This surveillance provides a basis for evaluating the effectiveness of the contractor's program for control of on-shift training and for establishing compliance with DOE requirements. Microsoft Office document icon OPS9-05.doc More Documents &

  7. Minimum information about a marker gene sequence (MIMARKS) and minimum information about any (x) sequence (MIxS) specifications.

    SciTech Connect (OSTI)

    Yilmaz, P.; Kottmann, R.; Field, D.; Knight, R.; Cole, J. R.; Amaral-Zettler, L.; Gilbert, J. A.

    2011-05-01

    Here we present a standard developed by the Genomic Standards Consortium (GSC) for reporting marker gene sequences - the minimum information about a marker gene sequence (MIMARKS). We also introduce a system for describing the environment from which a biological sample originates. The 'environmental packages' apply to any genome sequence of known origin and can be used in combination with MIMARKS and other GSC checklists. Finally, to establish a unified standard for describing sequence data and to provide a single point of entry for the scientific community to access and learn about GSC checklists, we present the minimum information about any (x) sequence (MIxS). Adoption of MIxS will enhance our ability to analyze natural genetic diversity documented by massive DNA sequencing efforts from myriad ecosystems in our ever-changing biosphere.

  8. METHODS FOR DETERMINING AGITATOR MIXING REQUIREMENTS FOR A MIXING & SAMPLING FACILITY TO FEED WTP (WASTE TREATMENT PLANT)

    SciTech Connect (OSTI)

    GRIFFIN PW

    2009-08-27

    The following report is a summary of work conducted to evaluate the ability of existing correlative techniques and alternative methods to accurately estimate impeller speed and power requirements for mechanical mixers proposed for use in a mixing and sampling facility (MSF). The proposed facility would accept high level waste sludges from Hanford double-shell tanks and feed uniformly mixed high level waste to the Waste Treatment Plant. Numerous methods are evaluated and discussed, and resulting recommendations provided.

  9. Structural and spectroscopic properties of high temperature prepared ZrO₂–TiO₂ mixed oxides

    SciTech Connect (OSTI)

    Gionco, Chiara; Battiato, Alfio; Vittone, Ettore; Paganini, Maria Cristina; Giamello, Elio

    2013-05-01

    ZrO₂-TiO₂ mixed oxides of various composition, with the molar fraction of TiO₂ ranging from 0.1% to 15%, have been prepared via sol-gel synthesis and then calcined at 1273 K to check both their thermal stability and physicochemical properties. These solids are usually employed in photocatalytic processes and as active phase supports in heterogeneous catalysis. As indicated by X-ray diffraction and Raman spectroscopy, solid solutions based on Ti ions diluted in the ZrO₂ matrix are formed in the whole range of Ti molar fraction examined. Materials with low Ti loading (0.1%–1%) are basically constituted by the monoclinic phase of ZrO₂ while the tetragonal phase becomes prevalent at 15% of TiO₂ molar fraction. The presence of Ti ions modify the electronic structure of the solid as revealed by investigation of the optical properties. The typical band gap transition of ZrO₂ undergoes, in fact, a red shift roughly proportional to the Ti loading which reach the remarkable value of 1.6 eV for the sample with 10% of molar Ti concentration. Comparing chemical analysis of the solids with XPS data it has been put into evidence that the titanium ions distribution into the solid is not uniform and the concentration of Ti⁴⁺ tend to be higher in subsurface layers than in the crystal bulk. The introduction of titanium ions in the structure increases the reducibility of the solid. Annealing under vacuum at various temperatures causes oxygen depletion with consequent reduction of the solid which shows up mainly in terms of formation of Ti³⁺ reduced centres which are characterized by a typical EPR signal. Ti³⁺ defects forms, as also forecast by theoretical modelling of the solid, as their energy is lower than that of other possible reduced defective centers. The reduced solids are able to transfer electrons to adsorbed oxygen molecules in mild condition resulting in the formation of surface superoxide anions (O₂⁻) which are stabilized on surface Zr⁴⁺ or, alternatively, on Ti⁴⁺ ions according to the sample composition. - Graphical abstract: The presence of Ti in ZrO₂ modifies UV–vis and electronic properties of mixed oxides. Highlights: • ZrO₂–TiO₂ mixed oxides have been prepared via sol–gel synthesis. • Solids with low Ti loading are constituted by the monoclinic phase of ZrO₂. • The presence of Ti ions modify the electronic structure of the solid. • The introduction of titanium ions increases the reducibility of the solid.

  10. Mixed and Low-Level Treatment Facility Project. Appendix B, Waste stream engineering files, Part 1, Mixed waste streams

    SciTech Connect (OSTI)

    Not Available

    1992-04-01

    This appendix contains the mixed and low-level waste engineering design files (EDFS) documenting each low-level and mixed waste stream investigated during preengineering studies for Mixed and Low-Level Waste Treatment Facility Project. The EDFs provide background information on mixed and low-level waste generated at the Idaho National Engineering Laboratory. They identify, characterize, and provide treatment strategies for the waste streams. Mixed waste is waste containing both radioactive and hazardous components as defined by the Atomic Energy Act and the Resource Conservation and Recovery Act, respectively. Low-level waste is waste that contains radioactivity and is not classified as high-level waste, transuranic waste, spent nuclear fuel, or 11e(2) byproduct material as defined by DOE 5820.2A. Test specimens of fissionable material irradiated for research and development only, and not for the production of power or plutonium, may be classified as low-level waste, provided the concentration of transuranic is less than 100 nCi/g. This appendix is a tool that clarifies presentation format for the EDFS. The EDFs contain waste stream characterization data and potential treatment strategies that will facilitate system tradeoff studies and conceptual design development. A total of 43 mixed waste and 55 low-level waste EDFs are provided.

  11. Non-Sooting, Low Flame Temperature Mixing-Controlled DI Diesel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sooting, Low Flame Temperature Mixing-Controlled DI Diesel Combustion Non-Sooting, Low Flame Temperature Mixing-Controlled DI Diesel Combustion 2003 DEER Conference Presentation: ...

  12. The Status of NRC Decommissioning Guidance on Intentional Soil Mixing

    SciTech Connect (OSTI)

    Watson, B.A.

    2007-07-01

    In 1997, the U.S. Nuclear Regulatory Commission (NRC) published the License Termination Rule (LTR) as Subpart E of 10 CFR Part 20, which established the license termination criteria for unrestricted use and the controls for restricted use. By 2003, the NRC staff's experience with the LTR revealed some important implementation issues impacting the decommissioning of sites, and these were addressed to the Commission (SECY-03-0069). In 2004, the staff provided the Commission with its analysis of a ninth issue, intentional soil mixing (SECY-04-0035). The Commission approved the staff's recommendations, with comments. In the draft revision of Supplement 1 to NUREG-1757, 'Consolidated Decommissioning Guidance', the staff endorsed the current practice of allowing intentional soil mixing to meet the waste acceptance criteria of offsite disposal facilities and the limited use of this practice to demonstrate compliance with the LTR criteria. The staff recommended including a provision that the staff would consider intentional mixing on a case-by-case basis, provided that the resulting contaminated area footprint is not increased and clean soil from outside the footprint is not mixed with contaminated soil to lower the concentrations. In addition, the staff would consider only those rare cases in which the mixing of clean soil is the only viable option for achieving the dose levels of the LTR. In 2005, the staff issued draft Supplement 1 to NUREG-1757 for public comment. The staff evaluated the public comments, including those from a number of States, and revised the guidance. The staff subsequently summarized the public comments on the draft guidance for the Commission (SECY-06-0143) in early 2006. This paper will discuss the public comments related to intentional mixing, the Commission's comments in its staff requirements memorandum, and the revision to the guidance in NUREG-1757 incorporating the current NRC decommissioning policy for intentional soil mixing. (authors)

  13. Proteinligand interactions investigated by thermal shift assays (TSA) and dual polarization interferometry (DPI)

    SciTech Connect (OSTI)

    Grftehauge, Morten K. Hajizadeh, Nelly R.; Swann, Marcus J.; Pohl, Ehmke

    2015-01-01

    The biophysical characterization of proteinligand interactions in solution using techniques such as thermal shift assay, or on surfaces using, for example, dual polarization interferometry, plays an increasingly important role in complementing crystal structure determinations. Over the last decades, a wide range of biophysical techniques investigating proteinligand interactions have become indispensable tools to complement high-resolution crystal structure determinations. Current approaches in solution range from high-throughput-capable methods such as thermal shift assays (TSA) to highly accurate techniques including microscale thermophoresis (MST) and isothermal titration calorimetry (ITC) that can provide a full thermodynamic description of binding events. Surface-based methods such as surface plasmon resonance (SPR) and dual polarization interferometry (DPI) allow real-time measurements and can provide kinetic parameters as well as binding constants. DPI provides additional spatial information about the binding event. Here, an account is presented of new developments and recent applications of TSA and DPI connected to crystallography.

  14. Shape Shifters: Demonstrating Tunable Phase Shifting | U.S. DOE Office of

    Office of Science (SC) Website

    Science (SC) Shape Shifters: Demonstrating Tunable Phase Shifting Basic Energy Sciences (BES) BES Home About Research Facilities Science Highlights Benefits of BES Funding Opportunities Basic Energy Sciences Advisory Committee (BESAC) Community Resources Contact Information Basic Energy Sciences U.S. Department of Energy SC-22/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-3081 F: (301) 903-6594 E: Email Us More Information » 10.01.15 Shape Shifters:

  15. The Shifting Landscape of Ratepayer-Funded Energy Efficiency in the U.S.

    Energy Savers [EERE]

    LBNL-2258E ERNEST ORLANDO LAWRENCE BERKELEY NATIONAL LABORATORY The Shifting Landscape of Ratepayer- Funded Energy Efficiency in the U.S. Galen Barbose, Charles Goldman, and Jeff Schlegel Environmental Energy Technologies Division October 2009 Expanded pre-print version of article published in The Electricity Journal plus Technical Appendix This work was supported by the Office of Electricity Delivery and Energy Reliability and by the Office of Energy Efficiency and Renewable Energy,

  16. Effects of vacuum exposure on stress and spectral shift of high reflective coatings

    SciTech Connect (OSTI)

    Stolz, C.J.; Taylor, J.R.; Eickelberg, W.K.; Lindh, J.D.

    1992-06-01

    The Atomic Vapor Laser Isotope Laser Separation (AVLIS) program operates the world`s largest average power dye laser; the dye laser beams are combined, formatted, and transported in vacuum. The optical system is aligned at atmosphere, while the system must meet requirements in vacuum. Therefore, coating performance must be characterized in both atmosphere and vacuum. Changes in stress and spectral shift in ambient and vacuum environments are reported for conventional and dense multilayer dielectric coatings.

  17. Effects of vacuum exposure on stress and spectral shift of high reflective coatings

    SciTech Connect (OSTI)

    Stolz, C.J.; Taylor, J.R.; Eickelberg, W.K.; Lindh, J.D.

    1992-06-01

    The Atomic Vapor Laser Isotope Laser Separation (AVLIS) program operates the world's largest average power dye laser; the dye laser beams are combined, formatted, and transported in vacuum. The optical system is aligned at atmosphere, while the system must meet requirements in vacuum. Therefore, coating performance must be characterized in both atmosphere and vacuum. Changes in stress and spectral shift in ambient and vacuum environments are reported for conventional and dense multilayer dielectric coatings.

  18. Large doppler shift in radar detection of ultra-high energy cosmic rays.

    SciTech Connect (OSTI)

    Underwood, D. G.; High Energy Physics

    2008-01-01

    Radar detection of cosmic ray air showers has been discussed for 60 years, but never clearly observed. The topic was reexamined by Gorham in 2001 and some serious simulations were done by Takai, who also initiated the Mariachi project utilizing commercial television transmissions as a signal source. The air showers from ultra-high energy cosmic rays are expected to generate a plasma with plasma frequency in the high VHF region. One factor limiting the received signal strength is the short ion recombination time in air at low altitude. However, a major factor which has not been the center of attention so far is the possible large Doppler shifts for non-specular reflection, and the soft transition between specular and diffuse for small objects and short time scales. We discuss recent work on receivers, and simulations of the Doppler shift. These simulations assume a very short ion recombination time in the lower atmosphere, and use an extremely simple mathematical model. A central feature of our simulations is large Doppler shift from non-moving material.

  19. On-shift training of plant personnel on environmental, safety and health regulations

    SciTech Connect (OSTI)

    Miller, D.

    1996-08-01

    As one of the standing committees under the American Petroleum Institute (API) General Committee of Refining, the Central Committee on Training and Development has several goals. These include improving plant operations and maintenance, reducing occupational injuries and illnesses, reducing the incidence of fires, maintaining effective environmental controls, and improving plant security. An additional responsibility is to develop cost and resource effective training materials. One of the activities the committee uses to achieve its goal is by sponsoring a series of biannual regional training conferences that attract participants from a variety of refineries and petrochemical plants. During the 1995 Spring Conferences, conference attendees were asked if on-shift training of plant personnel on environmental, safety and health was being utilized to assist compliance efforts and to achieve cost and resource effective training. In general, use of on-shift training is increasingly finding acceptance among the sites. One west coast refiner reported that their refinery had implemented a program of on-shift training for plant personnel on all environmental, safety and health regulations, and had achieved nearly one-hundred percent compliance through the first quarter of the effort.

  20. Proposal of a truncated atomic beam fountain for reduction of collisional frequency shift

    SciTech Connect (OSTI)

    Takamizawa, A.; Yanagimachi, S.; Ikegami, T. [National Metrology Institute of Japan (NMIJ), National Institute of Advanced Industrial Science and Technology, Tsukuba, Ibaraki 305-8563 (Japan); Shirakawa, Y. [Department of Physics, Faculty of Science and Technology, Tokyo University of Science, 2641 Yamazaki, Noda shi, Chiba 278-8510 (Japan)

    2010-07-15

    We propose an atomic fountain clock with a truncated cold atomic beam to achieve both a low collisional frequency shift and high frequency stability. In this clock, the launching velocity of a cold atomic beam can be swept to reduce the atomic density in the interrogation region for the Ramsey resonance and to increase the atomic density in the detection region. Before the top of the beam arrives at the interrogation region, the cold atomic beam is truncated by turning off the cooling laser beams to remove the unnecessary light shift. The atomic density in the interrogation region is theoretically evaluated to be 0.04 times that in an ordinary atomic fountain with optical molasses for the same number of detected atoms. The frequency stability limit due to quantum projection noise is calculated to reach 6.4x10{sup -14} in 1 s from the number of detected atoms while the fractional collisional shift is estimated to be {approx}{sup -}2x10{sup -16}.

  1. Characterization and correction of charge-induced pixel shifts in DECam

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gruen, D.; Bernstein, G. M.; Jarvis, M.; Rowe, B.; Vikram, V.; Plazas, A. A.; Seitz, S.

    2015-05-28

    Interaction of charges in CCDs with the already accumulated charge distribution causes both a flux dependence of the point-spread function (an increase of observed size with flux, also known as the brighter/fatter effect) and pixel-to-pixel correlations of the Poissonian noise in flat fields. We describe these effects in the Dark Energy Camera (DECam) with charge dependent shifts of effective pixel borders, i.e. the Antilogus et al. (2014) model, which we fit to measurements of flat-field Poissonian noise correlations. The latter fall off approximately as a power-law r-2.5 with pixel separation r, are isotropic except for an asymmetry in the directmore » neighbors along rows and columns, are stable in time, and are weakly dependent on wavelength. They show variations from chip to chip at the 20% level that correlate with the silicon resistivity. The charge shifts predicted by the model cause biased shape measurements, primarily due to their effect on bright stars, at levels exceeding weak lensing science requirements. We measure the flux dependence of star images and show that the effect can be mitigated by applying the reverse charge shifts at the pixel level during image processing. Differences in stellar size, however, remain significant due to residuals at larger distance from the centroid.« less

  2. SU-E-J-16: A Review of the Magnitude of Patient Imaging Shifts in Relation to Departmental Policy Changes

    SciTech Connect (OSTI)

    O'Connor, M; Sansourekidou, P

    2014-06-01

    Purpose: To evaluate how changes in imaging policy affect the magnitude of shifts applied to patients. Methods: In June 2012, the department's imaging policy was altered to require that any shifts derived from imaging throughout the course of treatment shall be considered systematic only after they were validated with two data points that are consistent in the same direction. Multiple additions and clarifications to the imaging policy were implemented throughout the course of the data collection, but they were mostly of administrative nature. Entered shifts were documented in MOSAIQ (Elekta AB) through the localization offset. The MOSAIQ database was queried to identify a possible trend. A total of 25,670 entries were analyzed, including four linear accelerators with a combination of MV planar, kV planar and kV three dimensional imaging. The monthly average of the magnitude of the vector was used. Plan relative offsets were excluded. During the evaluated period of time, one of the satellite facilities acquired and implemented Vision RT (AlignRT Inc). Results: After the new policy was implemented the shifts variance and standard deviation decreased. The decrease is linear with time elapsed. Vision RT implementation at one satellite facility reduced the number of overall shifts, specifically for breast patients. Conclusion: Changes in imaging policy have a significant effect on the magnitude of shifts applied to patients. Using two statistical points before applying a shift as persistent decreased the overall magnitude of the shifts applied to patients.

  3. The Role of Subtropical Irreversible PV Mixing in the Zonal Mean Circulation Response to Global Warming-like Thermal Forcing

    SciTech Connect (OSTI)

    Lu, Jian; Sun, Lantao; Wu, Yutian; Chen, Gang

    2014-03-15

    The atmospheric circulation response to the global warming-like tropical upper tropospheric heating is revisited using a dry atmospheric general circulation model (AGCM) in light of a new diagnostics based on the concept of finite-amplitude wave activity (FAWA) on equivalent latitude. For a given tropical heating profile, the linear Wentzel-Kramers-Brillouin (WKB) wave refraction analysis sometimes gives a very different and even opposite prediction of the eddy momentum flux response to that of the actual full model simulation, exposing the limitation of the traditional linear approach in understanding the full dynamics of the atmospheric response under global warming. The implementation of the FAWA diagnostics reveals that in response to the upper tropospheric heating, effective diffusivity, a measure of the mixing efficiency, increases and advances upward and poleward in the subtropics and the resultant enhancement and the poleward encroachment of eddy potential vorticity mixing leads to a poleward displaced potential vorticity (PV) gradient peak in the upper troposphere. The anomalous eddy PV flux, in balance with the PV dissipation, gives rise to a poleward shift in the eddy-driven jet and eddy-driven mean meridional circulation. Sensitivity experiments show that these irreversible dissipation processes in the upper troposphere are robust, regardless of the width of the tropical heating.

  4. Minimization of steam requirements and enhancement of water-gas shift reaction with warm gas temperature CO2 removal

    DOE Patents [OSTI]

    Siriwardane, Ranjani V; Fisher, II, James C

    2013-12-31

    The disclosure utilizes a hydroxide sorbent for humidification and CO.sub.2 removal from a gaseous stream comprised of CO and CO.sub.2 prior to entry into a water-gas-shift reactor, in order to decrease CO.sub.2 concentration and increase H.sub.2O concentration and shift the water-gas shift reaction toward the forward reaction products CO.sub.2 and H.sub.2. The hydroxide sorbent may be utilized for absorbtion of CO.sub.2 exiting the water-gas shift reactor, producing an enriched H.sub.2 stream. The disclosure further provides for regeneration of the hydroxide sorbent at temperature approximating water-gas shift conditions, and for utilizing H.sub.2O product liberated as a result of the CO.sub.2 absorption.

  5. Mixed ionic and electronic conducting ceramic membranes for hydrocarbon processing

    DOE Patents [OSTI]

    Van Calcar, Pamela (Superior, CO); Mackay, Richard (Lafayette, CO); Sammells, Anthony F. (Boulder, CO)

    2002-01-01

    The invention relates to mixed phase materials for the preparation of catalytic membranes which exhibit ionic and electronic conduction and which exhibit improved mechanical strength compared to single phase ionic and electronic conducting materials. The mixed phase materials are useful for forming gas impermeable membranes either as dense ceramic membranes or as dense thin films coated onto porous substrates. The membranes and materials of this invention are useful in catalytic membrane reactors in a variety of applications including synthesis gas production. One or more crystalline second phases are present in the mixed phase material at a level sufficient to enhance the mechanical strength of the mixture to provide membranes for practical application in CMRs.

  6. Engineering scale mixing system tests for MWTF title II design

    SciTech Connect (OSTI)

    Chang, S.C.

    1994-10-10

    Mixing tests for the Multifunction Waste Tank Facility (MWTF) were conducted in 1/25 and 1/10 scale test tanks with different slurry levels, solids concentrations, different jet mixers and with simulated in-tank structures. The same test procedure was used as in the Title I program, documented in WHC-SD-W236A-ER-005. The test results support the scaling correlation derived previously in the Title I program. The tests also concluded that a partially filled tank requires less mixing power, and horizontal and angled jets in combination (H/A mixer) are significantly more effective than the two horizontal jet mixers (H/H mixer) when used for mixing slurry with a high solids concentrations.

  7. Reclamation of potable water from mixed gas streams

    DOE Patents [OSTI]

    Judkins, Roddie R; Bischoff, Brian L; Debusk, Melanie Moses; Narula, Chaitanya

    2013-08-20

    An apparatus for separating a liquid from a mixed gas stream can include a wall, a mixed gas stream passageway, and a liquid collection assembly. The wall can include a first surface, a second surface, and a plurality of capillary condensation pores. The capillary condensation pores extend through the wall, and have a first opening on the first surface of the wall, and a second opening on the second surface of the wall. The pore size of the pores can be between about 2 nm to about 100 nm. The mixed gas stream passageway can be in fluid communication with the first opening. The liquid collection assembly can collect liquid from the plurality of pores.

  8. On the mixing time of geographical threshold graphs

    SciTech Connect (OSTI)

    Bradonjic, Milan

    2009-01-01

    In this paper, we study the mixing time of random graphs generated by the geographical threshold graph (GTG) model, a generalization of random geometric graphs (RGG). In a GTG, nodes are distributed in a Euclidean space, and edges are assigned according to a threshold function involving the distance between nodes as well as randomly chosen node weights. The motivation for analyzing this model is that many real networks (e.g., wireless networks, the Internet, etc.) need to be studied by using a 'richer' stochastic model (which in this case includes both a distance between nodes and weights on the nodes). We specifically study the mixing times of random walks on 2-dimensional GTGs near the connectivity threshold. We provide a set of criteria on the distribution of vertex weights that guarantees that the mixing time is {Theta}(n log n).

  9. Summary of BNL studies regarding commercial mixed waste

    SciTech Connect (OSTI)

    Bowerman, B.S.; Kempf, C.R.; MacKenzie, D.R.; Siskind, B.; Piciulo, P.L.

    1986-09-01

    Based on BNL's study it was concluded that there are low-level radioactive wastes (LLWs) which contain chemically hazardous components. Scintillation liquids may be considered an EPA listed hazardous waste and are, therefore, potential mixed wastes. Since November 1985, no operating LLW disposal site will accept these wastes for disposal. Unless such wastes contain de minimis quantities of radionuclides, they cannot be disposed of at an EPA permitted site. Currently generators of liquid scintillation wastes can ship de minimis wastes to be burned at commercial facilities. Oil wastes may also eventually be an EPA listed waste and thus will have to be considered a potential radioactive mixed waste unless NRC establishes de minimis levels of radionuclides below which oils can be managed as hazardous wastes. Regarding wastes containing lead metal there is some question as to the extent of the hazard posed by lead disposed in a LLW burial trench. Chromium-containing wastes would have to be tested to determine whether they are potential mixed wastes. There may be other wastes that are mixed wastes; the responsibility for determining this rests with the waste generator. While management options for handling potential mixed wastes are available, there is limited regulatory guidance for generators. BNL has identified and evaluated a variety of treatment options for the management of potential radioactive mixed wastes. The findings of that study showed that application of a management option with the purpose of addressing EPA concerns can, at the same time, address stabilization and volume reduction concerns of NRC. 6 refs., 1 tab.

  10. Kondo and mixed-valence regimes in multilevel quantum dots

    SciTech Connect (OSTI)

    Chudnovskiy, A. L.; Ulloa, S. E.

    2001-04-15

    We investigate the dependence of the ground state of a multilevel quantum dot on the coupling to an external fermionic system and on the interactions in the dot. As the coupling to the external system increases, the rearrangement of the effective energy levels in the dot signals the transition from the Kondo regime to a mixed-valence (MV) regime. The MV regime in a two-level dot is characterized by an intrinsic mixing of the levels in the dot, resulting in nonperturbative subtunneling and supertunneling phenomena that strongly influence the Kondo effect.

  11. Water and Gold: A Promising Mix for Future Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water and Gold: A Promising Mix for Future Batteries Water and Gold: A Promising Mix for Future Batteries Berkeley Lab Study Reveals Molecular Structure of Water at Gold Electrodes October 23, 2014 Contact: Rachel Berkowitz, 510-486-7254, rberkowitz@lbl.gov When a solid material is immersed in a liquid, the liquid immediately next to its surface differs from that of the bulk liquid at the molecular level. This interfacial layer is critical to our understanding of a diverse set of phenomena from

  12. Nanopatterns by phase separation of patterned mixed polymer monolayers

    DOE Patents [OSTI]

    Huber, Dale L; Frischknecht, Amalie

    2014-02-18

    Micron-size and sub-micron-size patterns on a substrate can direct the self-assembly of surface-bonded mixed polymer brushes to create nanoscale patterns in the phase-separated mixed polymer brush. The larger scale features, or patterns, can be defined by a variety of lithographic techniques, as well as other physical and chemical processes including but not limited to etching, grinding, and polishing. The polymer brushes preferably comprise vinyl polymers, such as polystyrene and poly(methyl methacrylate).

  13. Mixed anion materials and compounds for novel proton conducting membranes

    DOE Patents [OSTI]

    Poling, Steven Andrew; Nelson, Carly R.; Martin, Steve W.

    2006-09-05

    The present invention provides new amorphous or partially crystalline mixed anion chalcogenide compounds for use in proton exchange membranes which are able to operate over a wide variety of temperature ranges, including in the intermediate temperature range of about 100 .degree. C. to 300.degree. C., and new uses for crystalline mixed anion chalcogenide compounds in such proton exchange membranes. In one embodiment, the proton conductivity of the compounds is between about 10.sup.-8 S/cm and 10.sup.-1 S/cm within a temperature range of between about -60 and 300.degree. C. and a relative humidity of less than about 12%..

  14. Composite mixed oxide ionic and electronic conductors for hydrogen separation

    DOE Patents [OSTI]

    Gopalan, Srikanth (Westborough, MA); Pal, Uday B. (Dover, MA); Karthikeyan, Annamalai (Quincy, MA); Hengdong, Cui (Allston, MA)

    2009-09-15

    A mixed ionic and electronic conducting membrane includes a two-phase solid state ceramic composite, wherein the first phase comprises an oxygen ion conductor and the second phase comprises an n-type electronically conductive oxide, wherein the electronically conductive oxide is stable at an oxygen partial pressure as low as 10.sup.-20 atm and has an electronic conductivity of at least 1 S/cm. A hydrogen separation system and related methods using the mixed ionic and electronic conducting membrane are described.

  15. Critical experiments with mixed plutonium-uranium nitrate solutions having

    Office of Scientific and Technical Information (OSTI)

    Pu:(Pu + U) ratios greater than 0.5 (Technical Report) | SciTech Connect Critical experiments with mixed plutonium-uranium nitrate solutions having Pu:(Pu + U) ratios greater than 0.5 Citation Details In-Document Search Title: Critical experiments with mixed plutonium-uranium nitrate solutions having Pu:(Pu + U) ratios greater than 0.5 × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical

  16. Unexpected magnetism, Griffiths phase, and exchange bias in the mixed

    Office of Scientific and Technical Information (OSTI)

    lanthanide Pr0.6Er0.4Al2 (Journal Article) | SciTech Connect Journal Article: Unexpected magnetism, Griffiths phase, and exchange bias in the mixed lanthanide Pr0.6Er0.4Al2 Citation Details In-Document Search Title: Unexpected magnetism, Griffiths phase, and exchange bias in the mixed lanthanide Pr0.6Er0.4Al2 We report an unusual coexistence of ferromagnetism and ferrimagnetism, and metamagnetism in Pr0.6Er0.4Al2. In addition, this compound retains a clear Griffiths phase behavior even at 1

  17. Biodegradation and Biotransformation of Mixed Wastes Containing Metals and Chlorinated Xenobiotic Compounds By Microbial

    SciTech Connect (OSTI)

    Crqwford, D. L.; Kamashwaran, S. R.

    2001-07-01

    OAK 270 - Biodegradation and biotransformation of mixed Wastes Containing metals and chlorinated Xenobiotic compounds by microbial.

  18. Mixed Stream Test Rig Winter FY-2011 Report

    SciTech Connect (OSTI)

    Chalres Park; Tedd Lister; Kevin DeWall

    2011-04-01

    This report describes the data and analysis of the initial testing campaign of the Mixed Stream Test Rig (MISTER) at Idaho National Laboratory (INL). It describes the test specimen selection, physical configuration of the test equipment, operations methodology, and data and analysis of specimens exposed in two environments designed to represent those expected for high temperature steam electrolysis (HTSE).

  19. Mixing coefficients for subchannel analyses with supercritical water

    SciTech Connect (OSTI)

    Vogt, Bastian; Laurien, Eckart; Class, Andreas G.; Schulenberg, Thomas

    2007-07-01

    This paper is related to pressure drop and mixing correlations which are used in subchannel codes. The commercial CFD code STAR-CD has been applied for central subchannels of a supercritical water reactor fuel assembly design. First, pressure drop coefficients for cross flow have been evaluated for this geometry using steady state calculations. Different from established correlations for cross flow in rod bundles, the effects of strong axial flow in the bundle have been taken into account for the presented geometry, flow conditions and fluid properties. In the second part of the paper the unsteady RANS CFD-method is applied and assessed with respect to the prediction of flow pulsation phenomena and turbulent mixing. The results are compared with experimental correlations for the turbulent mixing coefficient and the flow pulsation frequency. It is found that the applied unsteady RANS method is able to predict the flow pulsation frequency but over-predicts the turbulent mixing by a factor of around 3.5. (authors)

  20. A mixed plug flow anaerobic digester for dairy manure

    SciTech Connect (OSTI)

    Cournoyer, M.S.; Delisle, U.; Ferland, D.; Chagnon, R.

    1985-01-01

    In 1982, a ''mixed plug-flow'' anaerobic digester has been built to produce biogas from the manure of 350 dairy cows and, subsequently, to produce electricity for on-farm use only. This paper describes the digester and presents the main results of one year of technical follow-up.

  1. Intercomparison of model simulations of mixed-phase clouds observed during

    Office of Scientific and Technical Information (OSTI)

    the ARM Mixed-Phase Arctic Cloud Experiment. I: Single layer cloud (Journal Article) | SciTech Connect Journal Article: Intercomparison of model simulations of mixed-phase clouds observed during the ARM Mixed-Phase Arctic Cloud Experiment. I: Single layer cloud Citation Details In-Document Search Title: Intercomparison of model simulations of mixed-phase clouds observed during the ARM Mixed-Phase Arctic Cloud Experiment. I: Single layer cloud Results are presented from an intercomparison of

  2. ACTIVE REGION MOSS: DOPPLER SHIFTS FROM HINODE/EXTREME-ULTRAVIOLET IMAGING SPECTROMETER OBSERVATIONS

    SciTech Connect (OSTI)

    Tripathi, Durgesh [Inter-University Centre for Astronomy and Astrophysics, Pune University Campus, Pune 411007 (India); Mason, Helen E. [Department of Applied Mathematics and Theoretical Physics, University of Cambridge, Wilberforce Road, Cambridge CB3 0WA (United Kingdom); Klimchuk, James A. [NASA Goddard Space Flight Center, Greenbelt, MD 20771 (United States)

    2012-07-01

    Studying the Doppler shifts and the temperature dependence of Doppler shifts in moss regions can help us understand the heating processes in the core of the active regions. In this paper, we have used an active region observation recorded by the Extreme-ultraviolet Imaging Spectrometer (EIS) on board Hinode on 2007 December 12 to measure the Doppler shifts in the moss regions. We have distinguished the moss regions from the rest of the active region by defining a low-density cutoff as derived by Tripathi et al. in 2010. We have carried out a very careful analysis of the EIS wavelength calibration based on the method described by Young et al. in 2012. For spectral lines having maximum sensitivity between log T = 5.85 and log T = 6.25 K, we find that the velocity distribution peaks at around 0 km s{sup -1} with an estimated error of 4-5 km s{sup -1}. The width of the distribution decreases with temperature. The mean of the distribution shows a blueshift which increases with increasing temperature and the distribution also shows asymmetries toward blueshift. Comparing these results with observables predicted from different coronal heating models, we find that these results are consistent with both steady and impulsive heating scenarios. However, the fact that there are a significant number of pixels showing velocity amplitudes that exceed the uncertainty of 5 km s{sup -1} is suggestive of impulsive heating. Clearly, further observational constraints are needed to distinguish between these two heating scenarios.

  3. Monolayer-induced band shifts at Si(100) and Si(111) surfaces

    SciTech Connect (OSTI)

    Mkinen, A. J. Kim, Chul-Soo; Kushto, G. P.

    2014-01-27

    We report our study of the interfacial electronic structure of Si(100) and Si(111) surfaces that have been chemically modified with various organic monolayers, including octadecene and two para-substituted benzene derivatives. X-ray photoelectron spectroscopy reveals an upward band shift, associated with the assembly of these organic monolayers on the Si substrates, that does not correlate with either the dipole moment or the electron withdrawing/donating character of the molecular moieties. This suggests that the nature and quality of the self-assembled monolayer and the intrinsic electronic structure of the semiconductor material define the interfacial electronic structure of the functionalized Si(100) and Si(111) surfaces.

  4. MEASUREMENTS OF ANISOTROPIC ION TEMPERATURES, NON-THERMAL VELOCITIES, AND DOPPLER SHIFTS IN A CORONAL HOLE

    SciTech Connect (OSTI)

    Hahn, M.; Savin, D. W.

    2013-02-15

    We present a new diagnostic allowing one to measure the anisotropy of ion temperatures and non-thermal velocities, as well as Doppler shifts with respect to the ambient magnetic field. This method provides new results, as well as an independent test for previous measurements obtained with other techniques. Our spectral data come from observations of a low-latitude, on-disk coronal hole. A potential field source surface model was used to calculate the angle between the magnetic field lines and the line of sight for each spatial bin of the observation. A fit was performed to determine the line widths and Doppler shifts parallel and perpendicular to the magnetic field. For each line width component we derived ion temperatures T {sub i,} and T {sub i, Parallel-To} and non-thermal velocities v {sub nt,} and v {sub nt, Parallel-To }. T {sub i,} was cooler than off-limb polar coronal hole measurements, suggesting increasing collisional cooling with decreasing height. T {sub i, Parallel-To} is consistent with a uniform temperature of (1.8 {+-} 0.2) Multiplication-Sign 10{sup 6} K for each ion. Since parallel ion heating is expected to be weak, this ion temperature should reflect the proton temperature. A comparison between our results and others implies a large proton temperature gradient around 1.02 R {sub Sun }. The non-thermal velocities are thought to be proportional to the amplitudes of various waves. Our results for v {sub nt,} agree with Alfven wave amplitudes inferred from off-limb polar coronal hole line width measurements. Our v {sub nt, Parallel-To} results are consistent with slow magnetosonic wave amplitudes inferred from Fourier analysis of time-varying intensity fluctuations. Doppler shift measurements yield outflows of Almost-Equal-To 5 km s{sup -1} for ions formed over a broad temperature range. This differs from other studies that found a strong Doppler shift dependence on formation temperature.

  5. In Situ alignment system for phase-shifting point-diffraction interferometry

    DOE Patents [OSTI]

    Goldberg, Kenneth Alan; Naulleau, Patrick P.

    2000-01-01

    A device and method to facilitate the gross alignment of patterned object- and image-plane masks in optical systems such as the phase-shifting point diffraction interferometer are provided. When an array of similar pinholes or discreet mask fields is used, confusion can occur over the alignment of the focused beams within the field. Adding to the mask pattern a circumscribed or inscribed set of symbols that are identifiable in situ facilitates the unambiguous gross alignment of the object- and/or image-plane masks. Alternatively, a system of markings can be encoded directly into the window shape to accomplish this same task.

  6. Null test fourier domain alignment technique for phase-shifting point diffraction interferometer

    DOE Patents [OSTI]

    Naulleau, Patrick; Goldberg, Kenneth Alan

    2000-01-01

    Alignment technique for calibrating a phase-shifting point diffraction interferometer involves three independent steps where the first two steps independently align the image points and pinholes in rotation and separation to a fixed reference coordinate system, e.g, CCD. Once the two sub-elements have been properly aligned to the reference in two parameters (separation and orientation), the third step is to align the two sub-element coordinate systems to each other in the two remaining parameters (x,y) using standard methods of locating the pinholes relative to some easy to find reference point.

  7. Dissipation in a rotating frame: Master equation, effective temperature, and Lamb shift

    SciTech Connect (OSTI)

    Verso, Alvise; Ankerhold, Joachim

    2010-02-15

    Motivated by recent realizations of microwave-driven nonlinear resonators in superconducting circuits, the impact of environmental degrees of freedom is analyzed as seen from a rotating frame. A system plus reservoir model is applied to consistently derive in the weak coupling limit the master equation for the reduced density in the moving frame and near the first bifurcation threshold. The concept of an effective temperature is introduced to analyze to what extent a detailed balance relation exists. Explicit expressions are also found for the Lamb-shift. Results for ohmic baths are in agreement with experimental findings, while for structured environments population inversion is predicted that may qualitatively explain recent observations.

  8. World pipeline construction patterns shifting away from big North American gas lines

    SciTech Connect (OSTI)

    Koen, A.D.; True, W.R.

    1992-02-10

    The pattern of world pipeline construction has begun to shift away from large diameter gas lines in North America. Total miles of gas pipelines planned this year and beyond have registered big increases in Europe and Asia- Pacific regions, more than offsetting decreased mileage of planned U.S. and Canadian gas projects. World products pipeline construction planned in 1992 and beyond shows the largest year to year gain, paced by projects in Latin America. Those are among highlights of this article. Many projects only under study or unlikely to be built are excluded from final mileage tallies.

  9. Application of Coherent Tune Shift Measurements to the Characterization of Electron Cloud Growth

    SciTech Connect (OSTI)

    Kreinick, D.L.; Crittenden, J.A.; Dugan, G.; Holtzapple, R.L.; Randazzo, M.; Furman, M.A.; Venturini, M.; Palmer, M.A.; Ramirez, G.

    2011-03-28

    Measurements of coherent tune shifts at the Cornell Electron Storage Ring Test Accelerator (CesrTA) have been made for electron and positron beams under a wide variety of beam energies, bunch charge, and bunch train configurations. Comparing the observed tunes with the predictions of several electron cloud simulation programs allows the evaluation of important parameters in these models. These simulations will be used to predict the behavior of the electron cloud in damping rings for future linear colliders. We outline recent improvements to the analysis techniques that should improve the fidelity of the modeling.

  10. CASL-U-2015-0170-000 SHIFT: A Massively Parallel Monte Carlo

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SHIFT: A Massively Parallel Monte Carlo Radiation Transport Package Tara M. Pandya, Seth R. Johnson, Gregory G. Davidson, Thomas M. Evans, and Steven P. Hamilton Oak Ridge National Laboratory April 19, 2015 CASL-U-2015-0170-000 ANS MC2015 - Joint International Conference on Mathematics and Computation (M&C), Supercomputing in Nuclear Applications (SNA) and the Monte Carlo (MC) Method * Nashville, Tennessee * April 19-23, 2015, on CD-ROM, American Nuclear Society, LaGrange Park, IL (2015)

  11. Reduction of reabsorption effects in scintillators by employing solutes with large Stokes shifts

    DOE Patents [OSTI]

    Harrah, Larry A. (Albuquerque, NM); Renschler, Clifford L. (Albuquerque, NM)

    1986-01-01

    In a radiation or high energy particle responsive system useful as a scintillator, and comprising, a first component which interacts with said radiation or high energy particle to emit photons in a certain first wavelength range; and at least one additional solute component which absorbs the photons in said first wavelength range and thereupon emits photons in another wavelength range higher than said first range; an improvement is provided wherein at least one of said components absorbs substantially no photons in said wavelength range in which it emits photons, due to a large Stokes shift caused by an excited state intramolecular rearrangement.

  12. Reduction of reabsorption effects in scintillators by employing solutes with large Stokes shifts

    DOE Patents [OSTI]

    Harrah, L.A.; Renschler, C.L.

    1984-08-01

    A radiation or high energy particle responsive system useful as a scintillator comprises, a first component which interacts with radiation or high energy particles to emit photons in a certain first wavelength range, and at least one additional solute component which absorbs the photons in said first wavelength range and thereupon emits photons in another wavelength range higher than said first range. An improvement is provided wherein at least one of said components absorbs substantially no photons in the wavelength range in which it emits photons, due to a large Stokes shift caused by an excited state intramolecular rearrangement.

  13. Scaled Tests and Modeling of Effluent Stack Sampling Location Mixing

    SciTech Connect (OSTI)

    Recknagle, Kurtis P.; Yokuda, Satoru T.; Ballinger, Marcel Y.; Barnett, J. M.

    2009-02-01

    The Pacific Northwest National Laboratory researchers used a computational fluid dynamics (CFD) computer code to evaluate the mixing at a sampling system location of a research and development facility. The facility requires continuous sampling for radioactive air emissions. Researchers sought to determine whether the location would meet the criteria for uniform air velocity and contaminant concentration as prescribed in the American National Standard Institute (ANSI) standard, Sampling and Monitoring Releases of Airborne Radioactive Substances from the Stacks and Ducts of Nuclear Facilities. Standard ANSI/HPS N13.1-1999 requires that the sampling location be well-mixed and stipulates specific tests (e.g., velocity, gas, and aerosol uniformity and cyclonic flow angle) to verify the extent of mixing.. The exhaust system for the Radiochemical Processing Laboratory was modeled with a CFD code to better understand the flow and contaminant mixing and to predict mixing test results. The CFD results were compared to actual measurements made at a scale-model stack and to the limited data set for the full-scale facility stack. Results indicated that the CFD code provides reasonably conservative predictions for velocity, gas, and aerosol uniformity. Cyclonic flow predicted by the code is less than that measured by the required methods. In expanding from small to full scale, the CFD predictions for full-scale measurements show similar trends as in the scale model and no unusual effects. This work indicates that a CFD code can be a cost-effective aid in design or retrofit of a facilitys stack sampling location that will be required to meet Standard ANSI/HPS N13.1-1999.

  14. Plasmon-enhanced reverse water gas shift reaction over oxide supported Au catalysts

    SciTech Connect (OSTI)

    Upadhye, AA; Ro, I; Zeng, X; Kim, HJ; Tejedor, I; Anderson, MA; Dumesic, JA; Huber, GW

    2015-01-01

    We show that localized surface plasmon resonance (LSPR) can enhance the catalytic activities of different oxide-supported Au catalysts for the reverse water gas shift (RWGS) reaction. Oxide-supported Au catalysts showed 30 to 1300% higher activity for RWGS under visible light compared to dark conditions. Au/TiO2 catalyst prepared by the deposition-precipitation (DP) method with 3.5 nm average Au particle size showed the highest activity for the RWGS reaction. Visible light is converted into chemical energy for this reaction with up to a 5% overall efficiency. A shift in the apparent activation energy (from 47 kJ mol(-1) in dark to 35 kJ mol(-1) in light) and apparent reaction order with respect to CO2 (from 0.5 in dark to 1.0 in light) occurs due to the LSPR. Our kinetic results indicate that the LSPR increases the rate of either the hydroxyl hydrogenation or carboxyl decomposition more than any other steps in the reaction network.

  15. The motional Stark effect diagnostic for ITER using a line-shift approach

    SciTech Connect (OSTI)

    Foley, E. L.; Levinton, F. M.; Yuh, H. Y.; Zakharov, L. E.

    2008-10-15

    The United States has been tasked with the development and implementation of a motional Stark effect (MSE) system on ITER. In the harsh ITER environment, MSE is particularly susceptible to degradation, as it depends on polarimetry, and the polarization reflection properties of surfaces are highly sensitive to thin film effects due to plasma deposition and erosion of a first mirror. Here we present the results of a comprehensive study considering a new MSE-based approach to internal plasma magnetic field measurements for ITER. The proposed method uses the line shifts in the MSE spectrum (MSE-LS) to provide a radial profile of the magnetic field magnitude. To determine the utility of MSE-LS for equilibrium reconstruction, studies were performed using the ESC-ERV code system. A near-term opportunity to test the use of MSE-LS for equilibrium reconstruction is being pursued in the implementation of MSE with laser-induced fluorescence on NSTX. Though the field values and beam energies are very different from ITER, the use of a laser allows precision spectroscopy with a similar ratio of linewidth to line spacing on NSTX as would be achievable with a passive system on ITER. Simulation results for ITER and NSTX are presented, and the relative merits of the traditional line polarization approach and the new line-shift approach are discussed.

  16. Slurry phase Fischer-Tropsch synthesis: Cobalt plus a water-gas shift catalyst

    SciTech Connect (OSTI)

    Yates, I.C.; Satterfield, C.N.

    1988-01-01

    A cobalt Fischer-Tropsch catalyst (CO/MgO/silica) was reduced and slurried in combination with reduced Cu/ZnO/Al[sub 2]0[sub 3] water-gas-shift catalyst. Combined catalyst system was run at fixed process conditions for more than 400 hours. The system showed stable selectivity. The Cu/ZnO/Al[sub 2]0[sub 3] water-gas-shift catalyst remained reasonably active in the presence of the cobalt catalyst. Hydrocarbon selectivity of the cobalt and Cu/ZnO/Al[sub 2]0[sub 3] catalyst system compared favorably to selectivity of iron-based catalysts. Methane selectivity was slightly higher for the cobalt-based system, but C[sub 5][sup +] selectivity was essentially the same. The hydrocarbon product distribution appeared to exhibit a double-a behavior. a[sub 1] was near 0.80 which is higher than that of iron catalysts, while a[sub 2] was calculated to be 0.86 which is somewhat lower than would be typical for an iron-based catalyst.

  17. Interactive tools designed to study mix in inertial confinement fusion implosions

    SciTech Connect (OSTI)

    Welser-sherrill, Leslie; Cooley, James H; Wilson, Doug C

    2008-01-01

    Graphical user interface tools have been built in IDL to study mix in inertial confinement fusion (ICF) implosion cores. FLAME (Fall-Line Analysis Mix Evaluator), a code which investigates yield degradation due to mix , was designed to post-process 1D hydrodynamic simulation output by implementing a variety of mix models. Three of these mix models are based on the physics of the fall-line. In addition, mixing data from other sources can be incorporated into the yield degradation analysis. Two independent tools called HAME (Haan Analysis Mix Evaluator) and YAME (Youngs Analysis Mix Evaluator) were developed to calculate the spatial extent of the mix region according to the Haan saturation model and Youngs' phenomenological model, respectively. FLAME facilitates a direct comparison to experimental data. The FLAME, HAME, and YAME interfaces are user-friendly, flexible, and platform-independent.

  18. 125Te NMR chemical-shift trends in PbTeGeTe and PbTeSnTe alloys

    SciTech Connect (OSTI)

    Njegic, Bosiljka; Levin, Evgenii M.; Schmidt-Rohr, Klaus

    2013-10-08

    Complex tellurides, such as doped PbTe, GeTe, and their alloys, are among the best thermoelectric materials. Knowledge of the change in 125Te NMR chemical shift due to bonding to dopant or solute atoms is useful for determination of phase composition, peak assignment, and analysis of local bonding. We have measured the 125Te NMR chemical shifts in PbTe-based alloys, Pb1?xGexTe and Pb1?xSnxTe, which have a rocksalt-like structure, and analyzed their trends. For low x, several peaks are resolved in the 22-kHz MAS 125Te NMR spectra. A simple linear trend in chemical shifts with the number of Pb neighbors is observed. No evidence of a proposed ferroelectric displacement of Ge atoms in a cubic PbTe matrix is detected at low Ge concentrations. The observed chemical shift trends are compared with the results of DFT calculations, which confirm the linear dependence on the composition of the first-neighbor shell. The data enable determination of the composition of various phases in multiphase telluride materials. They also provide estimates of the 125Te chemical shifts of GeTe and SnTe (+970 and +400150 ppm, respectively, from PbTe), which are otherwise difficult to access due to Knight shifts of many hundreds of ppm in neat GeTe and SnTe.

  19. Radiolysis Model Formulation for Integration with the Mixed Potential Model

    SciTech Connect (OSTI)

    Buck, Edgar C.; Wittman, Richard S.

    2014-07-10

    The U.S. Department of Energy Office of Nuclear Energy (DOE-NE), Office of Fuel Cycle Technology has established the Used Fuel Disposition Campaign (UFDC) to conduct the research and development activities related to storage, transportation, and disposal of used nuclear fuel (UNF) and high-level radioactive waste. Within the UFDC, the components for a general system model of the degradation and subsequent transport of UNF is being developed to analyze the performance of disposal options [Sassani et al., 2012]. Two model components of the near-field part of the problem are the ANL Mixed Potential Model and the PNNL Radiolysis Model. This report is in response to the desire to integrate the two models as outlined in [Buck, E.C, J.L. Jerden, W.L. Ebert, R.S. Wittman, (2013) Coupling the Mixed Potential and Radiolysis Models for Used Fuel Degradation, FCRD-UFD-2013-000290, M3FT-PN0806058

  20. Pre-mixing apparatus for a turbine engine

    DOE Patents [OSTI]

    Lacy, Benjamin Paul (Greer, SC); Varatharajan, Balachandar (Cincinnati, OH); Ziminsky, Willy Steve (Simpsonville, SC); Kraemer, Gilbert Otto (Greer, SC); Yilmaz, Ertan (Albany, NY); Melton, Patrick Benedict (Horse Shoe, NC); Zuo, Baifang (Simpsonville, SC); Stevenson, Christian Xavier (Inman, SC); Felling, David Kenton (Greenville, SC); Uhm, Jong Ho (Simpsonville, SC)

    2012-04-03

    A pre-mixing apparatus for a turbine engine includes a main body having an inlet portion, an outlet portion and an exterior wall that collectively establish at least one fluid delivery plenum, and a plurality of fluid delivery tubes extending through at least a portion of the at least one fluid delivery plenum. Each of the plurality of fluid delivery tubes includes at least one fluid delivery opening fluidly connected to the at least one fluid delivery plenum. With this arrangement, a first fluid is selectively delivered to the at least one fluid delivery plenum, passed through the at least one fluid delivery opening and mixed with a second fluid flowing through the plurality of fluid delivery tubes prior to being combusted in a combustion chamber of a turbine engine.

  1. Development of characterization protocol for mixed liquid radioactive waste classification

    SciTech Connect (OSTI)

    Zakaria, Norasalwa; Wafa, Syed Asraf; Wo, Yii Mei; Mahat, Sarimah

    2015-04-29

    Mixed liquid organic waste generated from health-care and research activities containing tritium, carbon-14, and other radionuclides posed specific challenges in its management. Often, these wastes become legacy waste in many nuclear facilities and being considered as problematic waste. One of the most important recommendations made by IAEA is to perform multistage processes aiming at declassification of the waste. At this moment, approximately 3000 bottles of mixed liquid waste, with estimated volume of 6000 litres are currently stored at the National Radioactive Waste Management Centre, Malaysia and some have been stored for more than 25 years. The aim of this study is to develop a characterization protocol towards reclassification of these wastes. The characterization protocol entails waste identification, waste screening and segregation, and analytical radionuclides profiling using various analytical procedures including gross alpha/ gross beta, gamma spectrometry, and LSC method. The results obtained from the characterization protocol are used to establish criteria for speedy classification of the waste.

  2. Mixed and low-level waste treatment facility project

    SciTech Connect (OSTI)

    Not Available

    1992-04-01

    The technology information provided in this report is only the first step toward the identification and selection of process systems that may be recommended for a proposed mixed and low-level waste treatment facility. More specific information on each technology will be required to conduct the system and equipment tradeoff studies that will follow these preengineering studies. For example, capacity, maintainability, reliability, cost, applicability to specific waste streams, and technology availability must be further defined. This report does not currently contain all needed information; however, all major technologies considered to be potentially applicable to the treatment of mixed and low-level waste are identified and described herein. Future reports will seek to improve the depth of information on technologies.

  3. Requirements for shipment of DOE radioactive mixed waste

    SciTech Connect (OSTI)

    Gablin, K.; No, Hyo; Herman, J.

    1993-08-01

    There are several sources of radioactive mixed waste (RMW) at Argonne National Laboratory which, in the past, were collected at waste tanks and/or sludge tanks. They were eventually pumped out by special pumps and processed in an evaporator located in the waste operations area in Building No. 306. Some of this radioactive mixed waste represents pure elementary mercury. These cleaning tanks must be manually cleaned up because the RMW material was too dense to pump with the equipment in use. The four tanks being discussed in this report are located in Building No. 306. They are the Acid Waste Tank, IMOX/FLOC Tanks, Evaporation Feed Tanks, and Waste Storage Tanks. All of these tanks are characterized and handled separately. This paper discusses the process and the requirements for characterization and the associated paperwork for Argonne Waste to be shipped to Westinghouse Hanford Company for storage.

  4. Polymer solidification of mixed wastes at the Rocky Flats Plant

    SciTech Connect (OSTI)

    Faucette, A.M.; Logsdon, B.W.; Lucerna, J.J.; Yudnich, R.J.

    1994-02-01

    The Rocky Flats Plant is pursuing polymer solidification as a viable treatment option for several mixed waste streams that are subject to land disposal restrictions within the Resource Conservation and Recovery Act provisions. Tests completed to date using both surrogate and actual wastes indicate that polyethylene microencapsulation is a viable treatment option for several mixed wastes at the Rocky Flats Plant, including nitrate salts, sludges, and secondary wastes such as ash. Treatability studies conducted on actual salt waste demonstrated that the process is capable of producing waste forms that comply with all applicable regulatory criteria, including the Toxicity Characteristic Leaching Procedure. Tests have also been conducted to evaluate the feasibility of macroencapsulating certain debris wastes in polymers. Several methods and plastics have been tested for macroencapsulation, including post-consumer recycle and regrind polyethylene.

  5. Internal wave energy radiated from a turbulent mixed layer

    SciTech Connect (OSTI)

    Munroe, James R.; Sutherland, Bruce R.

    2014-09-15

    We examine mixed-layer deepening and the generation of internal waves in stratified fluid resulting from turbulence that develops in response to an applied surface stress. In laboratory experiments the stress is applied over the breadth of a finite-length tank by a moving roughened conveyor belt. The turbulence in the shear layer is characterized using particle image velocimetry to measure the kinetic energy density. The internal waves are measured using synthetic schlieren to determine their amplitudes, frequencies, and energy density. We also perform fully nonlinear numerical simulations restricted to two dimensions but in a horizontally periodic domain. These clearly demonstrate that internal waves are generated by transient eddies at the integral length scale of turbulence and which translate with the background shear along the base of the mixed layer. In both experiments and simulations we find that the energy density of the generated waves is 1%3% of the turbulent kinetic energy density of the turbulent layer.

  6. Laminated microchannel devices, mixing units and method of making same

    DOE Patents [OSTI]

    Bennett, Wendy D [Kennewick, WA; Hammerstrom, Donald J [West Richland, WA; Martin, Peter M [Kennewick, WA; Matson, Dean W [Kennewick, WA

    2002-10-17

    A laminated microchannel device is described in which there is a unit operation process layer that has longitudinal channel. The longitudinal channel is cut completely through the layer in which the unit process operation resides. Both the device structure and method of making the device provide significant advantages in terms of simplicity and efficiency. A static mixing unit that can be incorporated in the laminated microchannel device is also described.

  7. Energy Efficient Crawlspace Foundation Retrofit: Mixed Humid Climate

    SciTech Connect (OSTI)

    Del Bianco, M.; Wiehagen, J.

    2013-01-01

    Residential quality management systems have most often been designed for new home construction. To address quality in existing homes in the form of Scopes of Work (SOW), the NAHB Research Center began with a new construction scope of work and applied it to an existing home project. This document is intended to outline the steps of translating a new home construction SOW to SOW for retrofit and addressed crawlspace foundations in a mixed-humid climate.

  8. Mixed series in ultraspherical polynomials and their approximation properties

    SciTech Connect (OSTI)

    Sharapudinov, I I

    2003-04-30

    New (mixed) series in ultraspherical polynomials P{sub n}{sup {alpha}}{sup ,{alpha}}(x) are introduced. The basic difference between a mixed series in the polynomials P{sub n}{sup {alpha}}{sup ,{alpha}}(x) and a Fourier series in the same polynomials is as follows: a mixed series contains terms of the form (2{sup r}f{sub r,k}{sup {alpha}})/(k+2{alpha}){sup [r]}) P{sub k+r}{sup {alpha}}{sup -r,{alpha}}{sup -r}(x), where 1{<=}r is an integer and f{sub r,k}{sup {alpha}} is the kth Fourier coefficient of the derivative f{sup (r)}(x) with respect to the ultraspherical polynomials P{sub k}{sup {alpha}}{sup ,{alpha}}(x). It is shown that the partial sums Y{sub n+2r}{sup {alpha}}(f,x) of a mixed series in the polynomial P{sub k}{sup {alpha}}{sup ,{alpha}}(x) contrast favourably with Fourier sums S{sub n}{sup {alpha}}(f,x) in the same polynomials as regards their approximation properties in classes of differentiable and analytic functions, and also in classes of functions of variable smoothness. In particular, the Y{sub n+2r}{sup {alpha}}(f,x) can be used for the simultaneous approximation of a function f(x) and its derivatives of orders up to (r- 1), whereas the S{sub n}{sup {alpha}}(f,x) are not suitable for this purpose.

  9. Community Loblolly Pine Longleaf Pine D Mixed Pine/Hardwood

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    D Mixed Pine/Hardwood D Bottomland Hardwood _ Water _ Bottomland Hardwood/Pine IIIIiI Scrub/Shrub E2:I SRS Bays i&. Roads NUtility ROW EEl Hydric Soils 230 o 230 Vegetation Meters Soils Soil Series and Phase D BaB _w .Wm Figure 10-2. Plant communities and soils associated with the Risher Pond Set-Aside Area. 10-9 Set-Aside 10: Risher Pond

  10. Nonaqueous purification of mixed nitrate heat transfer media

    DOE Patents [OSTI]

    Fiorucci, Louis C.; Morgan, Michael J.

    1983-12-20

    A nonaqueous, in-line method for removing carbonate and hydroxide contamination from a molten mixed sodium nitrate/potassium nitrate heat transfer salt. The method comprises dissolving a stoichiometric quantity of anhydrous Ca(NO.sub.3).sub.2 in the melt whereby an insoluble CaCO.sub.3 and Ca(OH).sub.2 precipitate is formed. The precipitate can be removed by settling, filtration or floatation techniques.

  11. Mixed Sugar Fermentative Strain of Zymomonas mobilis - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Biomass and Biofuels Biomass and Biofuels Find More Like This Return to Search Mixed Sugar Fermentative Strain of Zymomonas mobilis Improved Strain of Zymomonas mobilis enables the production of ethanol from not only hexose (six-carbon) sugars, but from pentose (five-carbon) sugars National Renewable Energy Laboratory Contact NREL About This Technology Technology Marketing SummaryEthanol is the clean, renewable, domestic form of gasoline the U.S. needs to decrease its dependence on

  12. Mixed-Phase Cloud Retrievals Using Doppler Radar Spectra

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mixed-Phase Cloud Retrievals Using Doppler Radar Spectra M. D. Shupe, S. Y. Matrosov, and T. L. Schneider National Oceanic and Atmospheric Administration Environmental Technology Laboratory Boulder, Colorado P. Kollias Rosentiel School of Marine Atmospheric Sciences University of Miami Miami, Florida Introduction The radar Doppler spectrum contains a wealth of information on cloud microphysical properties. Typically, radar-based cloud retrievals use only the zeroth or first moments of the

  13. More Efficient Ethanol Production from Mixed Sugars Using Spathaspora Yeast

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    - Energy Innovation Portal More Efficient Ethanol Production from Mixed Sugars Using Spathaspora Yeast Great Lakes Bioenergy Research Center Contact GLBRC About This Technology Technology Marketing SummaryEthanol obtained from the fermentation of grains and sugars is being blended with gasoline to bolster dwindling petroleum supplies. The alcohol increases combustion efficiency and octane value, and can be fermented from renewable corn cobs, stalks, cane and grasses. Still, it is essential

  14. Phenomenological relations for neutrino masses and mixing parameters

    SciTech Connect (OSTI)

    Khruschov, V. V.

    2013-11-15

    Phenomenological relations for masses, angles, and CP phases in the neutrino mixing matrix are proposed with allowance for available experimental data. For the case of CP violation in the lepton sector, an analysis of the possible structure of the neutrino mass matrix and a calculation of the neutrino mass features and the Dirac CP phase for the bimodal-neutrino model are performed. The values obtained in this way can be used to interpret and predict the results of various neutrino experiments.

  15. SCALED EXPERIMENTS EVALUATING PULSE JET MIXING OF SLURRIES

    SciTech Connect (OSTI)

    Bamberger, Judith A.; Meyer, Perry A.; Enderlin, Carl W.; Fort, James A.; Wells, Beric E.; Minette, Michael J.; Burns, Carolyn A.; Baer, Ellen BK; Eakin, David E.; Elmore, Monte R.; Snyder, Sandra F.

    2009-11-13

    Pulse jet mixing (PJM) tests with noncohesive solids in Newtonian liquid were conducted at three geometric scales to support the design of mixing systems for the Hanford Waste Treatment and Immobilization Plant. The test data will be used to develop mixing models. The models predict the cloud height (the height to which solids will be lifted by the PJM action) and the critical suspension velocity (the minimum velocity needed to ensure all solids have been lifted from the floor. From the cloud height estimate, the concentration of solids near the vessel floor and the minimum velocity predicted to lift solids can be calculated. The test objective was to observe the influence of vertically downward-directed jets on noncohesive solids in a series of scaled tanks with several bottom shapes. The test tanks and bottom shapes included small-and large-scale tanks with elliptical bottoms, a mid-scale tank with a spherical bottom, and a large-scale tank with an F&D bottom. During testing, the downward-directed jets were operated in either a steady flow condition or a pulsed (periodic) flow condition. The mobilization of the solids resulting from the jets was evaluated based on: the motion/agitation of the particulate on the tank floor and the elevation the solids reach within the tank; the height the solids material reaches in the tank is referred to as the cloud height (HC).

  16. Mixed and Low-Level Waste Treatment Facility project

    SciTech Connect (OSTI)

    Not Available

    1992-04-01

    Mixed and low-level wastes generated at the Idaho National Engineering Laboratory (INEL) are required to be managed according to applicable State and Federal regulations, and Department of Energy Orders that provide for the protection of human health and the environment. The Mixed and Low-Level Waste Treatment Facility Project was chartered in 1991, by the Department of Energy to provide treatment capability for these mixed and low-level waste streams. The first project task consisted of conducting engineering studies to identify the waste streams, their potential treatment strategies, and the requirements that would be imposed on the waste streams and the facilities used to process them. This report, Appendix A, Environmental Regulatory Planning Documentation, identifies the regulatory requirements that would be imposed on the operation or construction of a facility designed to process the INEL's waste streams. These requirements are contained in five reports that discuss the following topics: (1) an environmental compliance plan and schedule, (2) National Environmental Policy Act requirements, (3) preliminary siting requirements, (4) regulatory justification for the project, and (5) health and safety criteria.

  17. Preliminary Scaling Estimate for Select Small Scale Mixing Demonstration Tests

    SciTech Connect (OSTI)

    Wells, Beric E.; Fort, James A.; Gauglitz, Phillip A.; Rector, David R.; Schonewill, Philip P.

    2013-09-12

    The Hanford Site double-shell tank (DST) system provides the staging location for waste that will be transferred to the Hanford Tank Waste Treatment and Immobilization Plant (WTP). Specific WTP acceptance criteria for waste feed delivery describe the physical and chemical characteristics of the waste that must be met before the waste is transferred from the DSTs to the WTP. One of the more challenging requirements relates to the sampling and characterization of the undissolved solids (UDS) in a waste feed DST because the waste contains solid particles that settle and their concentration and relative proportion can change during the transfer of the waste in individual batches. A key uncertainty in the waste feed delivery system is the potential variation in UDS transferred in individual batches in comparison to an initial sample used for evaluating the acceptance criteria. To address this uncertainty, a number of small-scale mixing tests have been conducted as part of Washington River Protection Solutions Small Scale Mixing Demonstration (SSMD) project to determine the performance of the DST mixing and sampling systems.

  18. Steam Reforming of Low-Level Mixed Waste

    SciTech Connect (OSTI)

    1998-01-01

    Under DOE Contract No. DE-AR21-95MC32091, Steam Reforming of Low-Level Mixed Waste, ThermoChem has successfully designed, fabricated and operated a nominal 90 pound per hour Process Development Unit (PDU) on various low-level mixed waste surrogates. The design construction, and testing of the PDU as well as performance and economic projections for a 500- lb/hr demonstration and commercial system are described. The overall system offers an environmentally safe, non-incinerating, cost-effective, and publicly acceptable method of processing LLMW. The steam-reforming technology was ranked the No. 1 non-incineration technology for destruction of hazardous organic wastes in a study commissioned by the Mixed Waste Focus Area published April 1997.1 The ThermoChem steam-reforming system has been developed over the last 13 years culminating in this successful test campaign on LLMW surrogates. Six surrogates were successfidly tested including a 750-hour test on material simulating a PCB- and Uranium- contaminated solid waste found at the Portsmouth Gaseous Diffusion Plant. The test results indicated essentially total (>99.9999oA) destruction of RCRA and TSCA hazardous halogenated organics, significant levels of volume reduction (> 400 to 1), and retention of radlonuclides in the volume-reduced solids. Cost studies have shown the steam-reforming system to be very cost competitive with more conventional and other emerging technologies.

  19. Mixed Waste Management Options: 1995 Update. National Low-Level Waste Management Program

    SciTech Connect (OSTI)

    Kirner, N.; Kelly, J.; Faison, G.; Johnson, D.

    1995-05-01

    In the original mixed Waste Management Options (DOE/LLW-134) issued in December 1991, the question was posed, ``Can mixed waste be managed out of existence?`` That study found that most, but not all, of the Nation`s mixed waste can theoretically be managed out of existence. Four years later, the Nation is still faced with a lack of disposal options for commercially generated mixed waste. However, since publication of the original Mixed Waste Management Options report in 1991, limited disposal capacity and new technologies to treat mixed waste have become available. A more detailed estimate of the Nation`s mixed waste also became available when the US Environmental Protection Agency (EPA) and the US Nuclear Regulatory Commission (NRC) published their comprehensive assessment, titled National Profile on Commercially Generated Low-Level Radioactive Mixed Waste (National Profile). These advancements in our knowledge about mixed waste inventories and generation, coupled with greater treatment and disposal options, lead to a more applied question posed for this updated report: ``Which mixed waste has no treatment option?`` Beyond estimating the volume of mixed waste requiring jointly regulated disposal, this report also provides a general background on the Atomic Energy Act (AEA) and the Resource Conservation and Recovery Act (RCRA). It also presents a methodical approach for generators to use when deciding how to manage their mixed waste. The volume of mixed waste that may require land disposal in a jointly regulated facility each year was estimated through the application of this methodology.

  20. Low temperature, sulfur tolerant homogeneous catalysts for the water-gas shift reaction

    SciTech Connect (OSTI)

    Laine, R.M.

    1986-01-20

    The purpose of this report is to update and reorganize our recent review on homogeneous catalysis of the water-gas shift reaction (WGSR) based on recent literature publications and patents. This updated version will serve as a means of selecting 10 candidate catalyst systems for use in developing effective, sulfur-tolerant, low temperature WGSR catalysts. This report discusses the variations possible in the basic chemistry associated with WGSR catalytic cycles, including basic, acidic, and neutral conditions. Then individual mechanism for specific WGSR catalyst systems are discussed. Finally, on the basis of the literature reports, a list is presented of candidate catalysts and basic systems we have chosen for study in Task 3.

  1. Phase-shifting point diffraction interferometer focus-aid enhanced mask

    DOE Patents [OSTI]

    Naulleau, Patrick (5239 Miles Ave., Apt. A, Oakland, CA 94618)

    2000-01-01

    A phase-shifting point diffraction interferometer system (PS/PDI) employing a PS/PDI mask that includes a PDI focus aid is provided. The PDI focus aid mask includes a large or secondary reference pinhole that is slightly displaced from the true or primary reference pinhole. The secondary pinhole provides a larger capture tolerance for interferometrically performing fine focus. With the focus-aid enhanced mask, conventional methods such as the knife-edge test can be used to perform an initial (or rough) focus and the secondary (large) pinhole is used to perform interferometric fine focus. Once the system is well focused, high accuracy interferometry can be performed using the primary (small) pinhole.

  2. Surface plasmon polariton assisted red shift in excitonic emission of semiconductor microflowers

    SciTech Connect (OSTI)

    Parameswaran, Chithra; Warrier, Anita R. Bingi, Jayachandra Vijayan, C.

    2014-10-15

    We report on the study of metal nanoparticle-semiconductor hybrid system composed of ?-indium sulfide (?-In{sub 2}S{sub 3}) and gold (Au) nanoparticles. ?-In{sub 2}S{sub 3} micron sized flower like structures (?1 ?m) and Au nanoparticles (?10 nm) were synthesized by chemical route. These Au nanoparticles have surface plasmon resonance at ? 520 nm. We study the influence of Au surface plasmon polaritons on the radiative properties of the ?-In{sub 2}S{sub 3} microflowers. As a result of the coupling between the surface plasmon polaritons and the excitons there is a red shift ? 50 nm in emission spectrum of hybrid ?-In{sub 2}S{sub 3}-Au system. Such hybrid systems provide scope for a control on the optical properties of semiconductor microstructures, thus rendering them suitable for specific device applications in optoelectronics and photovoltaics.

  3. Shifting of infrared radiation using rotational raman resonances in diatomic molecular gases

    DOE Patents [OSTI]

    Kurnit, Norman A. (Santa Fe, NM)

    1980-01-01

    A device for shifting the frequency of infrared radiation from a CO.sub.2 laser by stimulated Raman scattering in either H.sub.2 or D.sub.2. The device of the preferred embodiment comprises an H.sub.2 Raman laser having dichroic mirrors which are reflective for 16 .mu.m radiation and transmittive for 10 .mu.m, disposed at opposite ends of an interaction cell. The interaction cell contains a diatomic molecular gas, e.g., H.sub.2, D.sub.2, T.sub.2, HD, HT, DT and a capillary waveguide disposed within the cell. A liquid nitrogen jacket is provided around the capillary waveguide for the purpose of cooling. In another embodiment the input CO.sub.2 radiation is circularly polarized using a Fresnel rhomb .lambda./4 plate and applied to an interaction cell of much longer length for single pass operation.

  4. Electric rate that shifts hourly may foretell spot-market kWh

    SciTech Connect (OSTI)

    Springer, N.

    1985-11-25

    Four California industrial plants have cut their electricity bills up to 16% by shifting from the traditional time-of-use rates to an experimental real-time program (RTP) that varies prices hourly. The users receive a price schedule reflecting changing generating costs one day in advance to encourage them to increase power consumption during the cheapest time periods. Savings during the pilot program range between $11,000 and $32,000 per customer. The hourly cost breakdown encourages consumption during the night and early morning. The signalling system could be expanded to cogenerators and independent small power producers. If an electricity spot market develops, forecasters think a place on the stock exchanges for future-delivery contracts could develop in the future.

  5. Method and apparatus for executing an asynchronous clutch-to-clutch shift in a hybrid transmission

    DOE Patents [OSTI]

    Demirovic, Besim; Gupta, Pinaki; Kaminsky, Lawrence A.; Naqvi, Ali K.; Heap, Anthony H.; Sah, Jy-Jen F.

    2014-08-12

    A hybrid transmission includes first and second electric machines. A method for operating the hybrid transmission in response to a command to execute a shift from an initial continuously variable mode to a target continuously variable mode includes increasing torque of an oncoming clutch associated with operating in the target continuously variable mode and correspondingly decreasing a torque of an off-going clutch associated with operating in the initial continuously variable mode. Upon deactivation of the off-going clutch, torque outputs of the first and second electric machines and the torque of the oncoming clutch are controlled to synchronize the oncoming clutch. Upon synchronization of the oncoming clutch, the torque for the oncoming clutch is increased and the transmission is operated in the target continuously variable mode.

  6. Commercial Submersible Mixing Pump For SRS Tank Waste Removal - 15223

    SciTech Connect (OSTI)

    Hubbard, Mike; Herbert, James E.; Scheele, Patrick W.

    2015-01-12

    The Savannah River Site Tank Farms have 45 active underground waste tanks used to store and process nuclear waste materials. There are 4 different tank types, ranging in capacity from 2839 m3 to 4921 m3 (750,000 to 1,300,000 gallons). Eighteen of the tanks are older style and do not meet all current federal standards for secondary containment. The older style tanks are the initial focus of waste removal efforts for tank closure and are referred to as closure tanks. Of the original 51 underground waste tanks, six of the original 24 older style tanks have completed waste removal and are filled with grout. The insoluble waste fraction that resides within most waste tanks at SRS requires vigorous agitation to suspend the solids within the waste liquid in order to transfer this material for eventual processing into glass filled canisters at the Defense Waste Processing Facility (DWPF). SRS suspends the solid waste by use of recirculating mixing pumps. Older style tanks generally have limited riser openings which will not support larger mixing pumps, since the riser access is typically 58.4 cm (23 inches) in diameter. Agitation for these tanks has been provided by four long shafted standard slurry pumps (SLP) powered by an above tank 112KW (150 HP) electric motor. The pump shaft is lubricated and cooled in a pressurized water column that is sealed from the surrounding waste in the tank. Closure of four waste tanks has been accomplished utilizing long shafted pump technology combined with heel removal using multiple technologies. Newer style waste tanks at SRS have larger riser openings, allowing the processing of waste solids to be accomplished with four large diameter SLPs equipped with 224KW (300 HP) motors. These tanks are used to process the waste from closure tanks for DWPF. In addition to the SLPs, a 224KW (300 HP) submersible mixer pump (SMP) has also been developed and deployed within older style tanks. The SMPs are product cooled and product lubricated canned motor pumps designed to fit within available risers and have significant agitation capabilities to suspend waste solids. Waste removal and closure of two tanks has been accomplished with agitation provided by 3 SMPs installed within the tanks. In 2012, a team was assembled to investigate alternative solids removal technologies to support waste removal for closing tanks. The goal of the team was to find a more cost effective approach that could be used to replace the current mixing pump technology. This team was unable to identify an alternative technology outside of mixing pumps to support waste agitation and removal from SRS waste tanks. However, the team did identify a potentially lower cost mixing pump compared to the baseline SLPs and SMPs. Rather than using the traditional procurement using an engineering specification, the team proposed to seek commercially available submersible mixer pumps (CSMP) as alternatives to SLPs and SMPs. SLPs and SMPs have a high procurement cost and the actual cost of moving pumps between tanks has shown to be significantly higher than the original estimates that justified the reuse of SMPs and SLPs. The team recommended procurement of “off-the-shelf” industry pumps which may be available for significant savings, but at an increased risk of failure and reduced operating life in the waste tank. The goal of the CSMP program is to obtain mixing pumps that could mix from bulk waste removal through tank closure and then be abandoned in place as part of tank closure. This paper will present the development, progress and relative advantages of the CSMP.

  7. Charm Mixing, CP Violation and Rare D**0 Decays at BaBar (Conference...

    Office of Scientific and Technical Information (OSTI)

    Charm Mixing, CP Violation and Rare D**0 Decays at BaBar Citation Details In-Document Search Title: Charm Mixing, CP Violation and Rare D**0 Decays at BaBar Dsup 0-bar Dsup 0...

  8. Results on Charm Mixing and CP Violation from the B Factories...

    Office of Scientific and Technical Information (OSTI)

    Results on Charm Mixing and CP Violation from the B Factories Citation Details In-Document Search Title: Results on Charm Mixing and CP Violation from the B Factories Authors:...

  9. Gasification Characteristics of Coal/Biomass Mixed Fuels

    SciTech Connect (OSTI)

    Mitchell, Reginald

    2013-09-30

    A research project was undertaken that had the overall objective of developing the models needed to accurately predict conversion rates of coal/biomass mixtures to synthesis gas under conditions relevant to a commercially-available coal gasification system configured to co- produce electric power as well as chemicals and liquid fuels. In our efforts to accomplish this goal, experiments were performed in an entrained flow reactor in order to produce coal and biomass chars at high heating rates and temperatures, typical of the heating rates and temperatures fuel particles experience in real systems. Mixed chars derived from coal/biomass mixtures containing up to 50% biomass and the chars of the pure coal and biomass components were subjected to a matrix of reactivity tests in a pressurized thermogravimetric analyzer (TGA) in order to obtain data on mass loss rates as functions of gas temperature, pressure and composition as well as to obtain information on the variations in mass specific surface area during char conversion under kinetically-limited conditions. The experimental data were used as targets when determining the unknown parameters in the chemical reactivity and specific surface area models developed. These parameters included rate coefficients for the reactions in the reaction mechanism, enthalpies of formation and absolute entropies of adsorbed species formed on the carbonaceous surfaces, and pore structure coefficients in the model used to describe how the mass specific surface area of the char varies with conversion. So that the reactivity models can be used at high temperatures when mass transport processes impact char conversion rates, Thiele modulus – effectiveness factor relations were also derived for the reaction mechanisms developed. In addition, the reactivity model and a mode of conversion model were combined in a char-particle gasification model that includes the effects of chemical reaction and diffusion of reactive gases through particle pores and energy exchange between the particle and its environment. This char-particle gasification model is capable of predicting the average mass loss rates, sizes, apparent densities, specific surface areas, and temperatures of the char particles produced when co-firing coal and biomass to the type environments established in entrained flow gasifiers operating at high temperatures and elevated pressures. A key result of this work is the finding that the reactivities of the mixed chars were not always in between the reactivities of the pure component chars at comparable gasification conditions. Mixed char reactivity to CO{sub 2} was lower than the reactivities of both the pure Wyodak coal and pure corn stover chars to CO{sub 2}. In contrast, mixed char reactivity to H{sub 2}O was higher than the reactivities of both the pure Wyodak coal and pure corn stover chars to H{sub 2}O. This was found to be in part, a consequence of the reduced mass specific surface areas of the coal char particles formed during devolatilization when the coal and biomass particles are co-fired. The biomass particles devolatilize prior to the coal particles, impacting the temperature and the composition of the environment in which the coal particles devolatilize. This situation results in coal char particles within the mixed char that differ in specific surface area and reactivity from the coal char particles produced in the absence of the devolatilizing biomass particles. Due to presence of this “affected” coal char, it was not possible to develop a mixed char reactivity model that uses linear mixing rules to determine the reactivity of a mixed char from only the reactivities of the pure mixture components. However, it was possible to predict both mixed char specific surface area and reactivity for a wide range of fuel mixture rat os provided the specific surface area and reactivity of the affected coal char particles are known. Using the kinetic parameters determined for the Wyodak coal and corn stover chars, the model was found to adequately predict the observed conversion times and off-gas compositions in gasification conditions established in a variety of commercial gasifiers. The model has the potential to provide insight on certain implications of co-firing coal and biomass in gasification and combustion application when kinetic parameters for the mixed chars are employed.

  10. Alertness, performance and off-duty sleep on 8-hour and 12-hour night shifts in a simulated continuous operations control room setting

    SciTech Connect (OSTI)

    Baker, T.L.

    1995-04-01

    A growing number of nuclear power plants in the United States have adopted routine 12-hr shift schedules. Because of the potential impact that extended work shifts could have on safe and efficient power plant operation, the U.S. Nuclear Regulatory Commission funded research on 8-hr and 12-hr shifts at the Human Alertness Research Center (HARC) in Boston, Massachusetts. This report describes the research undertaken: a study of simulated 8-hr and 12-hr work shifts that compares alertness, speed, and accuracy at responding to simulator alarms, and relative cognitive performance, self-rated mood and vigor, and sleep-wake patterns of 8-hr versus 12-hr shift workers.

  11. Phenomenology of maximal and near-maximal lepton mixing (Journal Article) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Phenomenology of maximal and near-maximal lepton mixing Citation Details In-Document Search Title: Phenomenology of maximal and near-maximal lepton mixing The possible existence of maximal or near-maximal lepton mixing constitutes an intriguing challenge for fundamental theories of flavor. We study the phenomenological consequences of maximal and near-maximal mixing of the electron neutrino with other (x=tau and/or muon) neutrinos. We describe the deviations from maximal

  12. Photoelectron imaging and theoretical study on the structure and chemical binding of the mixed-ligand M(I) complexes, [HMSH]{sup ?} (M = Cu, Ag, and Au)

    SciTech Connect (OSTI)

    Qin, Zhengbo; Liu, Zhiling; Cong, Ran; Xie, Hua; Tang, Zichao, E-mail: zctang@dicp.ac.cn, E-mail: fanhj@dicp.ac.cn; Fan, Hongjun, E-mail: zctang@dicp.ac.cn, E-mail: fanhj@dicp.ac.cn [State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China)] [State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China)

    2014-03-21

    We have reported a combined photoelectron imaging and theoretical study on gaseous mixed-ligand M(I) complexes of [HMSH]{sup ?} (M = Cu, Ag, and Au). With the aid of Franck-Condon simulations, vibrationally resolved photoelectron spectra yield accurate electron affinities of 3.269(6), 3.669(10), and 3.591(6) eV for [HCuSH], [HAgSH], and [HAuSH], respectively. And low-frequency modes are observed: 368(12) cm{sup ?1} for [HCuSH], 286(12) cm{sup ?1} for [HAgSH], and 327(12) cm{sup ?1} for [HAuSH], respectively. Extensive theoretical calculations are performed to aid in the spectral assignments and the calculated values agree well with the experimental observations. Although the S and H atoms have little discrepancy in electronegativity (2.20 for H and 2.54 for S), distinct bonding properties are demonstrated between HM and MS bond. It is revealed that there exists significant ionic bonding between MS in [HMSH]{sup ?} (M = Cu, Ag, and Au), while a gradual transition from ionic behavior between HCu in [HCuSH]{sup ?} to quite strong covalent bonding between HAu in [HAuSH]{sup ?}, supported by a variety of chemical bonding analyses.

  13. VAC*TRAX - Thermal desorption for mixed wastes

    SciTech Connect (OSTI)

    McElwee, M.J.; Palmer, C.R.

    1995-12-01

    The patented VAC*TRAX process was designed in response to the need to remove organic constituents from mixed waste, waste that contains both a hazardous (RCRA or TSCA regulated) component and a radioactive component. Separation of the mixed waste into its hazardous and radioactive components allows for ultimate disposal of the material at existing, permitted facilities. The VAC*TRAX technology consists of a jacketed vacuum dryer followed by a condensing train. Solids are placed in the dryer and indirectly heated to temperatures as high as 260{degrees}C, while a strong vacuum (down to 50 mm Hg absolute pressure) is applied to the system and the dryer is purged with a nitrogen carrier gas. The organic contaminants in the solids are thermally desorbed, swept up in the carrier gas and into the condensing train where they are cooled and recovered. The dryer is fitted with a filtration system that keeps the radioactive constituents from migrating to the condensate. As such, the waste is separated into hazardous liquid and radioactive solid components, allowing for disposal of these streams at a permitted incinerator or a radioactive materials landfill, respectively. The VAC*TRAX system is designed to be highly mobile, while minimizing the operational costs with a simple, robust process. These factors allow for treatment of small waste streams at a reasonable cost. This paper describes the VAC*TRAX thermal desorption process, as well as results from the pilot testing program. Also, the design and application of the full-scale treatment system is presented. Materials tested to date include spiked soil and debris, power plant trash and sludge contaminated with solvents, PCB contaminated soil, solvent-contaminated uranium mill-tailings, and solvent and PCB-contaminated sludge and trash. Over 70 test runs have been performed using the pilot VAC*TRAX system, with more than 80% of the tests using mixed waste as the feed material.

  14. Subgrid models for mass and thermal diffusion in turbulent mixing

    SciTech Connect (OSTI)

    Sharp, David H; Lim, Hyunkyung; Li, Xiao - Lin; Gilmm, James G

    2008-01-01

    We are concerned with the chaotic flow fields of turbulent mixing. Chaotic flow is found in an extreme form in multiply shocked Richtmyer-Meshkov unstable flows. The goal of a converged simulation for this problem is twofold: to obtain converged solutions for macro solution features, such as the trajectories of the principal shock waves, mixing zone edges, and mean densities and velocities within each phase, and also for such micro solution features as the joint probability distributions of the temperature and species concentration. We introduce parameterized subgrid models of mass and thermal diffusion, to define large eddy simulations (LES) that replicate the micro features observed in the direct numerical simulation (DNS). The Schmidt numbers and Prandtl numbers are chosen to represent typical liquid, gas and plasma parameter values. Our main result is to explore the variation of the Schmidt, Prandtl and Reynolds numbers by three orders of magnitude, and the mesh by a factor of 8 per linear dimension (up to 3200 cells per dimension), to allow exploration of both DNS and LES regimes and verification of the simulations for both macro and micro observables. We find mesh convergence for key properties describing the molecular level of mixing, including chemical reaction rates between the distinct fluid species. We find results nearly independent of Reynolds number for Re 300, 6000, 600K . Methodologically, the results are also new. In common with the shock capturing community, we allow and maintain sharp solution gradients, and we enhance these gradients through use of front tracking. In common with the turbulence modeling community, we include subgrid scale models with no adjustable parameters for LES. To the authors' knowledge, these two methodologies have not been previously combined. In contrast to both of these methodologies, our use of Front Tracking, with DNS or LES resolution of the momentum equation at or near the Kolmogorov scale, but without resolving the Batchelor scale, allows a feasible approach to the modeling of high Schmidt number flows.

  15. Water Vapor Turbulence Profiles in Stationary Continental Convective Mixed Layers

    SciTech Connect (OSTI)

    Turner, D. D.; Wulfmeyer, Volker; Berg, Larry K.; Schween, Jan

    2014-10-08

    The U.S. Department of Energy Atmospheric Radiation Measurement (ARM) program’s Raman lidar at the ARM Southern Great Plains (SGP) site in north-central Oklahoma has collected water vapor mixing ratio (q) profile data more than 90% of the time since October 2004. Three hundred (300) cases were identified where the convective boundary layer was quasi-stationary and well-mixed for a 2-hour period, and q mean, variance, third order moment, and skewness profiles were derived from the 10-s, 75-m resolution data. These cases span the entire calendar year, and demonstrate that the q variance profiles at the mixed layer (ML) top changes seasonally, but is more related to the gradient of q across the interfacial layer. The q variance at the top of the ML shows only weak correlations (r < 0.3) with sensible heat flux, Deardorff convective velocity scale, and turbulence kinetic energy measured at the surface. The median q skewness profile is most negative at 0.85 zi, zero at approximately zi, and positive above zi, where zi is the depth of the convective ML. The spread in the q skewness profiles is smallest between 0.95 zi and zi. The q skewness at altitudes between 0.6 zi and 1.2 zi is correlated with the magnitude of the q variance at zi, with increasingly negative values of skewness observed lower down in the ML as the variance at zi increases, suggesting that in cases with larger variance at zi there is deeper penetration of the warm, dry free tropospheric air into the ML.

  16. Syngas Conversion to Hydrocarbon Fuels through Mixed Alcohol Intermediates

    SciTech Connect (OSTI)

    Dagle, Robert A.; Lebarbier, Vanessa M.; Albrecht, Karl O.; Li, Jinjing; Taylor, Charles E.; Bao, Xinhe; Wang, Yong

    2013-05-13

    Synthesis gas (syngas) can be used to synthesize a variety of fuels and chemicals. Domestic transportation and military operational interests have driven continued focus on domestic syngas-based fuels production. Liquid transportation fuels may be made from syngas via four basic processes: 1) higher alcohols, 2) Fischer-Tropsch (FT), 3) methanol-to-gasoline (MTG), and 4) methanol-to-olefins (MTO) and olefins-to-gasoline/distillate (MOGD). Compared to FT and higher alcohols, MTG and MTO-MOGD have received less attention in recent years. Due to the high capital cost of these synthetic fuel plants, the production cost of the finished fuel cannot compete with petroleum-derived fuel. Pacific Northwest National Laboratory has recently evaluated one way to potentially reduce capital cost and overall production cost for MTG by combining the methanol and MTG syntheses in a single reactor. The concept consists of mixing the conventional MTG catalyst (i.e. HZSM-5) with an alcohol synthesis catalyst. It was found that a methanol synthesis catalyst, stable at high temperature (i.e. Pd/ZnO/Al2O3) [1], when mixed with ZSM-5, was active for syngas conversion. Relatively high syngas conversion can be achieved as the equilibrium-driven conversion limitations for methanol and dimethyl ether are removed as they are intermediates to the final hydrocarbon product. However, selectivity control was difficult to achieve as formation of undesirable durene and light hydrocarbons was problematic [2]. The objective of the present study was thus to evaluate other potential composite catalyst systems and optimize the reactions conditions for the conversion of syngas to hydrocarbon fuels, through the use of mixed alcohol intermediates. Mixed alcohols are of interest as they have recently been reported to produce higher yields of gasoline compared to methanol [3]. 1. Lebarbier, V.M., Dagle, R.A., Kovarik, L., Lizarazo-Adarme, J.A., King, D.L., Palo, D.R., Catalyst Science & Technology, 2012, 2, 2116-2127. 2. Zhu, Y., Jones, S.B., Biddy, M.J., Dagle, R.A., Palo, D.P., Bioresource Technology, 2012, 117, 341-351. 3. Gujar, A.C., Guda, V.K., Nolan, M., Yan W., Toghiani, H., White, M.G., Applied Catalysis A: General, 2009, 363, 115-121.

  17. Microsecond Microfluidic Mixing for Investigation of Protein Folding Kinetics

    SciTech Connect (OSTI)

    Hertzog, D E; Santiago, J G; Bakajin, O

    2005-02-10

    We have developed and characterized a mixer to study the reaction kinetics of protein folding on a microsecond timescale. The mixer uses hydrodynamic focusing of pressure-driven flow in a microfluidic channel to reduce diffusion times as first demonstrated by Knight et al.[1]. Features of the mixer include 1 {micro}s mixing times, sample consumptions of order 1 nl/s, loading sample volumes on the order of microliters, and the ability to manufacture in fused silica for compatibility with most spectroscopic methods.

  18. Design and synthesis of mixed oxides nanoparticles for biofuel applications

    SciTech Connect (OSTI)

    Chen, Senniang

    2010-05-15

    The work in this dissertation presents the synthesis of two mixed metal oxides for biofuel applications and NMR characterization of silica materials. In the chapter 2, high catalytic efficiency of calcium silicate is synthesized for transesterfication of soybean oil to biodisels. Chapter 3 describes the synthesis of a new Rh based catalyst on mesoporous manganese oxides. The new catalyst is found to have higher activity and selectivity towards ethanol. Chapter 4 demonstrates the applications of solid-state Si NMR in the silica materials.

  19. Mixed mode control method and engine using same

    DOE Patents [OSTI]

    Kesse, Mary L. (Peoria, IL); Duffy, Kevin P. (Metamora, IL)

    2007-04-10

    A method of mixed mode operation of an internal combustion engine includes the steps of controlling a homogeneous charge combustion event timing in a given engine cycle, and controlling a conventional charge injection event to be at least a predetermined time after the homogeneous charge combustion event. An internal combustion engine is provided, including an electronic controller having a computer readable medium with a combustion timing control algorithm recorded thereon, the control algorithm including means for controlling a homogeneous charge combustion event timing and means for controlling a conventional injection event timing to be at least a predetermined time from the homogeneous charge combustion event.

  20. A Physically Based Correlation of Irradiation-Induced Transition Temperature Shifts for RPV Steels

    SciTech Connect (OSTI)

    Eason, Ernest D.; Odette, George Robert; Nanstad, Randy K; Yamamoto, Takuya

    2007-11-01

    The reactor pressure vessels (RPVs) of commercial nuclear power plants are subject to embrittlement due to exposure to high-energy neutrons from the core, which causes changes in material toughness properties that increase with radiation exposure and are affected by many variables. Irradiation embrittlement of RPV beltline materials is currently evaluated using Regulatory Guide 1.99 Revision 2 (RG1.99/2), which presents methods for estimating the shift in Charpy transition temperature at 30 ft-lb (TTS) and the drop in Charpy upper shelf energy (?USE). The purpose of the work reported here is to improve on the TTS correlation model in RG1.99/2 using the broader database now available and current understanding of embrittlement mechanisms. The USE database and models have not been updated since the publication of NUREG/CR-6551 and, therefore, are not discussed in this report. The revised embrittlement shift model is calibrated and validated on a substantially larger, better-balanced database compared to prior models, including over five times the amount of data used to develop RG1.99/2. It also contains about 27% more data than the most recent update to the surveillance shift database, in 2000. The key areas expanded in the current database relative to the database available in 2000 are low-flux, low-copper, and long-time, high-fluence exposures, all areas that were previously relatively sparse. All old and new surveillance data were reviewed for completeness, duplicates, and discrepancies in cooperation with the American Society for Testing and Materials (ASTM) Subcommittee E10.02 on Radiation Effects in Structural Materials. In the present modeling effort, a 10% random sample of data was reserved from the fitting process, and most aspects of the model were validated with that sample as well as other data not used in calibration. The model is a hybrid, incorporating both physically motivated features and empirical calibration to the U.S. power reactor surveillance data. It contains two terms, corresponding to the best-understood radiation damage features, matrix damage and copper-rich precipitates, although the empirical calibration will ensure that all other damage processes that are occurring are also reflected in those terms. Effects of material chemical composition, product form, and radiation exposure are incorporated, such that all effects are supported by findings of statistical significance, physical understanding, or comparison with independent data from controlled experiments, such as the Irradiation Variable (IVAR) Program. In most variable effects, the model is supported by two or three of these different forms of evidence. The key variable trends, such as the neutron fluence dependence and copper-nickel dependence in the new TTS model, are much improved over RG1.99/2 and are well supported by independent data and the current understanding of embrittlement mechanisms. The new model includes the variables copper, nickel, and fluence that are in RG1.99/2, but also includes effects of irradiation temperature, neutron flux, phosphorus, and manganese. The calibrated model is a good fit, with no significant residual error trends in any of the variables used in the model or several additional variables and variable interactions that were investigated. The report includes a chapter summarizing the current understanding of embrittlement mechanisms and one comparing the IVAR database with the TTS model predictions. Generally good agreement is found in that quantitative comparison, providing independent confirmation of the predictive capability of the TTS model. The key new insight in the TTS modeling effort, that flux effects are evident in both low (or no) copper and higher copper materials, is supported by the IVAR data. The slightly simplified version of the TTS model presented in Section 7.3 of this report is recommended for applications.

  1. Ionization energy shift of characteristic K x-ray lines from high-Z materials for plasma diagnostics

    SciTech Connect (OSTI)

    S?abkowska, K.; Szyma?ska, E.; Polasik, M.; Pereira, N. R.; Rzadkiewicz, J.; Seely, J. F.; Weber, B. V.; Schumer, J. W.

    2014-03-15

    The energy of the characteristic x-rays emitted by high atomic number atoms in a plasma that contains energetic electrons depends on the atom's ionization. For tungsten, the ionization energy shift of the L-lines has recently been used to diagnose the plasma's ionization; the change in energy of a K-line has been measured for iridium and observed for ytterbium. Here, we present detailed computations of the ionization energy shift to K-lines of these and an additional element, dysprosium; for these atoms, some K-lines nearly coincide in energy with K-edges of slightly lower Z atoms so that a change in transmission behind a K-edge filter betrays a change in energy. The ionization energy shift of such high-energy K-lines may enable a unique diagnostic when the plasma is inside an otherwise opaque enclosure such as hohlraums used on the National Ignition Facility.

  2. Guides and Case Studies for Mixed-Humid Climates | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mixed-Humid Climates Guides and Case Studies for Mixed-Humid Climates Map of the Mixed-Humid Climate which reaches from the coast of Maryland through North Carolina and sprawls to cover most of Kansas and Oklahoma. The Department of Energy (DOE) has developed a series of best practices and case studies to help builders improve whole-house energy performance in buildings found in mixed-humid climates. Best Practice Guides 40% Whole-House Energy Savings in the Mixed-Humid Climates - Volume 16

  3. Polarization-Driven Stark Shifts in Quantum Dot Luminescence from Single CdSe/oligo-PPV Nanoparticles

    SciTech Connect (OSTI)

    Early, K. T.; Sudeep, P. K.; Emrick, Todd; Barnes, M. D.

    2010-05-12

    We demonstrate polarization-induced spectral shifts and associated linearly polarized absorption and emission in single CdSe/oligo-(phenylene vinylene) (CdSe/OPV) nanoparticles. A mechanism for these observations is presented in which charge separation from photoexcited ligands results in a significant Stark distortion of the quantum dot electron/hole wavefunctions. This distortion results in an induced linear polarization and an associated red shift in band-edge photoluminescence. These studies suggest the use of single quantum dots as local charge mobility probes.

  4. Systems engineering identification and control of mixed waste technology development

    SciTech Connect (OSTI)

    Beitel, G.A.

    1997-08-01

    The Department of Energy (DOE) established the Mixed Waste Characterization, Treatment, and Disposal Focus Area (MWFA) to develop technologies required to meet the Department`s commitments for treatment of mixed low-level and transuranic wastes. Waste treatment includes all necessary steps from generation through disposal. Systems engineering was employed to reduce programmatic risk, that is, risk of failure to meet technical commitments within cost and schedule. Customer needs (technology deficiencies) are identified from Site Treatment Plans, Consent Orders, ten year plans, Site Technical Coordinating Groups, Stakeholders, and Site Visits. The Technical Baseline, a prioritized list of technology deficiencies, forms the basis for determining which technology development activities will be supported by the MWFA. Technology Development Requirements Documents are prepared for each technology selected for development. After technologies have been successfully developed and demonstrated, they are documented in a Technology Performance Report. The Technology Performance Reports are available to any of the customers or potential users of the technology, thus closing the loop between problem identification and product development. This systematic approach to technology development and its effectiveness after 3 years is discussed in this paper.

  5. Mixed Waste Focus Area: Department of Energy complex needs report

    SciTech Connect (OSTI)

    Roach, J.A.

    1995-11-16

    The Assistant Secretary for the Office of Environmental Management (EM) at the US Department of Energy (DOE) initiated a new approach in August of 1993 to environmental research and technology development. A key feature of this new approach included establishment of the Mixed Waste Characterization, Treatment, and Disposal Focus Area (MWFA). The mission of the MWFA is to identify, develop, and implement needed technologies such that the major environmental management problems related to meeting DOE`s commitments for treatment of mixed wastes under the Federal Facility Compliance Act (FFCA), and in accordance with the Land Disposal Restrictions (LDR) of the Resource Conservation and Recovery Act (RCRA), can be addressed, while cost-effectively expending the funding resources. To define the deficiencies or needs of the EM customers, the MWFA analyzed Proposed Site Treatment Plans (PSTPs), as well as other applicable documents, and conducted site visits throughout the summer of 1995. Representatives from the Office of Waste Management (EM-30), the Office of Environmental Restoration (EM-40), and the Office of Facility Transition and Management (EM-60) at each site visited were requested to consult with the Focus Area to collaboratively define their technology needs. This report documents the needs, deficiencies, technology gaps, and opportunities for expedited treatment activities that were identified during the site visit process. The defined deficiencies and needs are categorized by waste type, namely Wastewaters, Combustible Organics, Sludges/Soils, Debris/Solids, and Unique Wastes, and will be prioritized based on the relative affect the deficiency has on the DOE Complex.

  6. Water in protoplanetary disks: Deuteration and turbulent mixing

    SciTech Connect (OSTI)

    Furuya, Kenji; Aikawa, Yuri; Nomura, Hideko; Hersant, Franck; Wakelam, Valentine

    2013-12-10

    We investigate water and deuterated water chemistry in turbulent protoplanetary disks. Chemical rate equations are solved with the diffusion term, mimicking turbulent mixing in a vertical direction. Water near the midplane is transported to the disk atmosphere by turbulence and is destroyed by photoreactions to produce atomic oxygen, while the atomic oxygen is transported to the midplane and reforms water and/or other molecules. We find that this cycle significantly decreases column densities of water ice at r ? 30 AU, where dust temperatures are too high to reform water ice effectively. The radial extent of such region depends on the desorption energy of atomic hydrogen. Our model indicates that water ice could be deficient even outside the sublimation radius. Outside this radius, the cycle decreases the deuterium-to-hydrogen (D/H) ratio of water ice from ?2 10{sup 2}, which is set by the collapsing core model, to 10{sup 4}-10{sup 2} in 10{sup 6} yr, without significantly decreasing the water ice column density. The resultant D/H ratios depend on the strength of mixing and the radial distance from the central star. Our finding suggests that the D/H ratio of cometary water (?10{sup 4}) could be established (i.e., cometary water could be formed) in the solar nebula, even if the D/H ratio of water ice delivered to the disk was very high (?10{sup 2}).

  7. Mixing of Isotactic and Syndiotactic Polypropylenes in the Melt

    SciTech Connect (OSTI)

    CLANCY,THOMAS C.; PUTZ,MATHIAS; WEINHOLD,JEFFREY D.; CURRO,JOHN G.; MATTICE,WAYNE L.

    2000-07-14

    The miscibility of polypropylene (PP) melts in which the chains differ only in stereochemical composition has been investigated by two different procedures. One approach used detailed local information from a Monte Carlo simulation of a single chain, and the other approach takes this information from a rotational isomeric state model devised decades ago, for another purpose. The first approach uses PRISM theory to deduce the intermolecular packing in the polymer blend, while the second approach uses a Monte Carlo simulation of a coarse-grained representation of independent chains, expressed on a high-coordination lattice. Both approaches find a positive energy change upon mixing isotactic PP (iPP) and syndiotactic polypropylene (sPP) chains in the melt. This conclusion is qualitatively consistent with observations published recently by Muelhaupt and coworkers. The size of the energy chain on mixing is smaller in the MC/PRISM approach than in the RIS/MC simulation, with the smaller energy change being in better agreement with the experiment. The RIS/MC simulation finds no demixing for iPP and atactic polypropylene (aPP) in the melt, consistent with several experimental observations in the literature. The demixing of the iPP/sPP blend may arise from attractive interactions in the sPP melt that are disrupted when the sPP chains are diluted with aPP or iPP chains.

  8. Steam reforming of low-level mixed waste. Final report

    SciTech Connect (OSTI)

    1998-06-01

    ThermoChem has successfully designed, fabricated and operated a nominal 90 pound per hour Process Development Unit (PDU) on various low-level mixed waste surrogates. The design, construction, and testing of the PDU as well as performance and economic projections for a 300-lb/hr demonstration and commercial system are described. The overall system offers an environmentally safe, non-incinerating, cost-effective, and publicly acceptable method of processing LLMW. The steam-reforming technology was ranked the No. 1 non-incineration technology for destruction of hazardous organic wastes in a study commissioned by the Mixed Waste Focus Area and published in April 1997. The ThermoChem steam-reforming system has been developed over the last 13 years culminating in this successful test campaign on LLMW surrogates. Six surrogates were successfully tested including a 750-hour test on material simulating a PCB- and Uranium-contaminated solid waste found at the Portsmouth Gaseous Diffusion Plant. The test results indicated essentially total (> 99.9999%) destruction of RCRA and TSCA hazardous halogenated organics, significant levels of volume reduction (> 400 to 1), and retention of radionuclides in the volume-reduced solids. Economic evaluations have shown the steam-reforming system to be very cost competitive with more conventional and other emerging technologies.

  9. Shifts in oxidation states of cerium oxide nanoparticles detected inside intact hydrated cells and organelles

    SciTech Connect (OSTI)

    Szymanski, Craig J.; Munusamy, Prabhakaran; Mihai, Cosmin; Xie, Yumei; Hu, Dehong; Gilles, Marry K.; Tyliszczak, T.; Thevuthasan, Suntharampillai; Baer, Donald R.; Orr, Galya

    2015-09-01

    Cerium oxide nanoparticles (CNPs) have been shown to induce diverse biological effects, ranging from toxic to beneficial. The beneficial effects have been attributed to the potential antioxidant activity of CNPs via certain redox reactions, depending on their oxidation state or Ce3+/Ce4+ ratio. However, this ratio is strongly dependent on the environment and age of the nanoparticles and it is unclear whether and how the complex intracellular environment impacts this ratio and the possible redox reactions of CNPs. To identify any changes in the oxidation state of CNPs in the intracellular environment and better understand their intracellular reactions, we directly quantified the oxidation states of CNPs outside and inside intact hydrated cells and organelles using correlated scanning transmission x-ray and super resolution fluorescence microscopies. By analyzing hundreds of small CNP aggregates, we detected a shift to a higher Ce3+/Ce4+ ratio in CNPs inside versus outside the cells, indicating a net reduction of CNPs in the intracellular environment. We further found a similar ratio in the cytoplasm and in the lysosomes, indicating that the net reduction occurs earlier in the internalization pathway. Together with oxidative stress and toxicity measurements, our observations identify a net reduction of CNPs in the intracellular environment, which is consistent with their involvement in potentially beneficial oxidation reactions, but also point to interactions that can negatively impact the health of cells.

  10. One-Dimensional Ceria as Catalyst for the Low-Temperature Water-Gas Shift Reaction

    SciTech Connect (OSTI)

    Han, W.; Wen, W; Hanson, J; Teng, X; Marinkovic, N; Rodriguez, J

    2009-01-01

    Synchrotron-based in situ time-resolved X-ray diffraction and X-ray absorption spectroscopy were used to study pure ceria and Pd-loaded ceria nanotubes and nanorods (1D-ceria) as catalysts for the water-gas shift (WGS) reaction. While bulk ceria is very poor as WGS catalysts, pure 1D-ceria displayed catalytic activity at a temperature as low as 300 C. The reduction of the pure 1D-ceria in pure hydrogen started at 150 C, which is a much lower temperature than those previously reported for the reduction of 3D ceria nanoparticles. This low reduction temperature reflects the novel morphology of the oxide systems and may be responsible for the low-temperature WGS catalytic activity seen for the 1D-ceria. Pd-loaded 1D ceria displayed significant WGS activity starting at 200 C. During pretreatment in H{sub 2}, the ceria lattice parameter increased significantly around 60 C, which indicates that Pd-oxygen interactions may facilitate the reduction of Pd-loaded 1D-ceria. Pd and ceria both participate in the formation of the active sites for the catalytic reactions. The low-temperature hydrogen pretreatment results in higher WGS activity for Pd-loaded 1D-ceria.

  11. PROPERTIES IMPORTANT TO MIXING FOR WTP LARGE SCALE INTEGRATED TESTING

    SciTech Connect (OSTI)

    Koopman, D.; Martino, C.; Poirier, M.

    2012-04-26

    Large Scale Integrated Testing (LSIT) is being planned by Bechtel National, Inc. to address uncertainties in the full scale mixing performance of the Hanford Waste Treatment and Immobilization Plant (WTP). Testing will use simulated waste rather than actual Hanford waste. Therefore, the use of suitable simulants is critical to achieving the goals of the test program. External review boards have raised questions regarding the overall representativeness of simulants used in previous mixing tests. Accordingly, WTP requested the Savannah River National Laboratory (SRNL) to assist with development of simulants for use in LSIT. Among the first tasks assigned to SRNL was to develop a list of waste properties that matter to pulse-jet mixer (PJM) mixing of WTP tanks. This report satisfies Commitment 5.2.3.1 of the Department of Energy Implementation Plan for Defense Nuclear Facilities Safety Board Recommendation 2010-2: physical properties important to mixing and scaling. In support of waste simulant development, the following two objectives are the focus of this report: (1) Assess physical and chemical properties important to the testing and development of mixing scaling relationships; (2) Identify the governing properties and associated ranges for LSIT to achieve the Newtonian and non-Newtonian test objectives. This includes the properties to support testing of sampling and heel management systems. The test objectives for LSIT relate to transfer and pump out of solid particles, prototypic integrated operations, sparger operation, PJM controllability, vessel level/density measurement accuracy, sampling, heel management, PJM restart, design and safety margin, Computational Fluid Dynamics (CFD) Verification and Validation (V and V) and comparison, performance testing and scaling, and high temperature operation. The slurry properties that are most important to Performance Testing and Scaling depend on the test objective and rheological classification of the slurry (i.e., Newtonian or non-Newtonian). The most important properties for testing with Newtonian slurries are the Archimedes number distribution and the particle concentration. For some test objectives, the shear strength is important. In the testing to collect data for CFD V and V and CFD comparison, the liquid density and liquid viscosity are important. In the high temperature testing, the liquid density and liquid viscosity are important. The Archimedes number distribution combines effects of particle size distribution, solid-liquid density difference, and kinematic viscosity. The most important properties for testing with non-Newtonian slurries are the slurry yield stress, the slurry consistency, and the shear strength. The solid-liquid density difference and the particle size are also important. It is also important to match multiple properties within the same simulant to achieve behavior representative of the waste. Other properties such as particle shape, concentration, surface charge, and size distribution breadth, as well as slurry cohesiveness and adhesiveness, liquid pH and ionic strength also influence the simulant properties either directly or through other physical properties such as yield stress.

  12. Materials used in new generation vehicles: supplies, shifts, and supporting infrastructure

    SciTech Connect (OSTI)

    Das, S.; Curlee, T.R.; Schexnayder, S.M.

    1997-08-01

    The Partnership for a New Generation of Vehicles (PNGV) program intends to develop new designs for automobiles that will reduce fuel consumption by two thirds but otherwise have price, comfort, safety, and other measures of performance similar to the typical automobile now on the market. PNGV vehicle designs are expected to substitute lightweight materials, such as aluminum, magnesium, carbon-reinforced polymer composites, glass-reinforced polymer composites, and ultra- light steel, for heavier materials such as steel and iron in automobile components. The target mass of a PNGV vehicle is 1,960 pounds, as compared to the average current vehicle that weights 3,240 pounds. Other changes could include the use of different ferrous alloys, engineering changes, or incorporation of advanced ceramic components. Widespread adoption of these vehicle designs would affect materials markets and require concurrent development and adoption of supporting technologies to supply the materials and to use and maintain them in automobiles. This report identifies what would be required to bring about these changes and developments in materials substitution; identifies reasons that might make these substitutions difficult to accomplish within the overall objectives and timetable of the PNGV program; and identifies any issues arising from the substitution that could prompt consideration of policies to deal with them. The analysis in this paper uses scenarios that assume the production of new generation vehicles will begin in 2007 and that their market share will increase gradually over the following 25 years. The scenarios on which the analysis is based assume a maximum substitution of each potential replacement material considered. This maximum substitution of individual materials (i.e., the amount of replacement material by weight that would be added to the baseline vehicle`s composition) is as follows: ULSAB (high strength steel), 298 lbs.; glass-reinforced composites, 653 lbs.; carbon-reinforced composites, 379 lbs.; aluminum, 926 lbs.; and magnesium, 216 lbs. The substitutions (and the steel and iron they replace) are multiplied by the number of new generation vehicles produced on an annual basis out to 2030 to determine the total quantity of material used in new generation vehicles and the quantity of steel that would be displaced. We identified six stages in the life cycle of materials--mining or extraction of resources; smelting or other processing to produce the material from the resource; producing components from the material; assembling the components into vehicles, using, maintaining, and repairing vehicles; and disposing of the vehicle, including any recycling of materials for automotive or other use--and identified what might be required to supply and use the substitute materials at different life cycle stages. The variables considered are the mineral or material supply, the capital and equipment (including necessary capacity, technical changes, cost, and location), labor and employment, energy, material complements, and environmental emissions and impacts. The analysis shows that raw materials to produce each of the replacement materials are sufficiently available, and adequate mining or extraction capacity exists for each. However, challenges are possible at the material production stage for three of the four materials. For aluminum and magnesium the difficulties are associated with requirements for significant new production capacity, necessary for aluminum because new production equipment will be needed to produce the material in a cost-effective manner and for magnesium because current production capacity is inadequate. The required capacity investment for magnesium to meet demand in 2030 is $13.1 billion. Both materials also would sharply increase energy requirements, and both industries would likely develop mostly--if not entirely--outside the United States. To produce the carbon-based fiber to meet PNGV demand in 2015, an entire new industry must be developed--a $4.6 billion investment. Significant environmental concerns

  13. Simulation Analysis for HB-Line Dissolver Mixing

    SciTech Connect (OSTI)

    Lee, S

    2006-03-22

    In support of the HB-Line Engineering agitator mixing project, flow pattern calculations have been made for a 90{sup o} apart and helical pitch agitator submerged in a flat tank containing dissolver baskets. The work is intended to determine maximum agitator speed to keep the dissolver baskets from contacting the agitator for the nominal tank liquid level. The analysis model was based on one dissolver basket located on the bottom surface of the flat tank for a conservative estimate. The modeling results will help determine acceptable agitator speeds and tank liquid levels to ensure that the dissolver basket is kept from contacting the agitator blade during HB-Line dissolver tank operations. The numerical modeling and calculations have been performed using a computational fluid dynamics approach. Three-dimensional steady-state momentum and continuity equations were used as the basic equations to estimate fluid motion driven by an agitator with four 90{sup o} pitched blades or three flat blades. Hydraulic conditions were fully turbulent (Reynolds number about 1 x 10{sup 5}). A standard two-equation turbulence model ({kappa},{var_epsilon}), was used to capture turbulent eddy motion. The commercial finite volume code, Fluent [5], was used to create a prototypic geometry file with a non-orthogonal mesh. Hybrid meshing was used to fill the computational region between the round-edged tank bottom and agitator regions. The nominal calculations and a series of sensitivity runs were made to investigate the impact of flow patterns on the lifting behavior of the dissolver basket. At high rotational speeds and low tank levels, local turbulent flow reaches the critical condition for the dissolver basket to be picked up from the tank floor and to touch the agitator blades during the tank mixing operations. This is not desirable in terms of mixing performance. The modeling results demonstrate that the flow patterns driven by the agitators considered here are not strong enough to lift up the dissolver basket for the agitator speeds up to 2500 rpm. The results also show that local velocity magnitudes for the three-blade flat plate agitator are at maximum three times smaller than the helical fourblade one. Table 5 and Table 6 summarize the results.

  14. Measurement of Ultracold Neutrons Produced by Using Doppler-shifted Bragg Reflection at a Pulsed-neutron Source

    DOE R&D Accomplishments [OSTI]

    Brun, T. O.; Carpenter, J. M.; Krohn, V. E.; Ringo, G. R.; Cronin, J. W.; Dombeck, T. W.; Lynn, J. W.; Werner, S. A.

    1979-01-01

    Ultracold neutrons (UCN) have been produced at the Argonne pulsed-neutron source by the Doppler shift of 400-m/s neutrons Bragg reflected from a moving crystal. The peak density of UCN produced at the crystal exceeds 0.1 n/cm{sup 3}.

  15. Ice Thermal Storage Systems for LWR Supplemental Cooling and Peak Power Shifting

    SciTech Connect (OSTI)

    Haihua Zhao; Hongbin Zhang; Phil Sharpe; Blaise Hamanaka; Wei Yan; WoonSeong Jeong

    2010-06-01

    Availability of enough cooling water has been one of the major issues for the nuclear power plant site selection. Cooling water issues have frequently disrupted the normal operation at some nuclear power plants during heat waves and long draught. The issues become more severe due to the new round of nuclear power expansion and global warming. During hot summer days, cooling water leaving a power plant may become too hot to threaten aquatic life so that environmental regulations may force the plant to reduce power output or even temporarily to be shutdown. For new nuclear power plants to be built at areas without enough cooling water, dry cooling can be used to remove waste heat directly into the atmosphere. However, dry cooling will result in much lower thermal efficiency when the weather is hot. One potential solution for the above mentioned issues is to use ice thermal storage systems (ITS) that reduce cooling water requirements and boost the plant’s thermal efficiency in hot hours. ITS uses cheap off-peak electricity to make ice and uses those ice for supplemental cooling during peak demand time. ITS is suitable for supplemental cooling storage due to its very high energy storage density. ITS also provides a way to shift large amount of electricity from off peak time to peak time. Some gas turbine plants already use ITS to increase thermal efficiency during peak hours in summer. ITSs have also been widely used for building cooling to save energy cost. Among three cooling methods for LWR applications: once-through, wet cooling tower, and dry cooling tower, once-through cooling plants near a large water body like an ocean or a large lake and wet cooling plants can maintain the designed turbine backpressure (or condensation temperature) during 99% of the time; therefore, adding ITS to those plants will not generate large benefits. For once-through cooling plants near a limited water body like a river or a small lake, adding ITS can bring significant economic benefits and avoid forced derating and shutdown during extremely hot weather. For the new plants using dry cooling towers, adding the ice thermal storage systems can effectively reduce the efficiency loss and water consumption during hot weather so that new LWRs could be considered in regions without enough cooling water. \\ This paper presents the feasibility study of using ice thermal storage systems for LWR supplemental cooling and peak power shifting. LWR cooling issues and ITS application status will be reviewed. Two ITS application case studies will be presented and compared with alternative options: one for once-through cooling without enough cooling for short time, and the other with dry cooling. Because capital cost, especially the ice storage structure/building cost, is the major cost for ITS, two different cost estimation models are developed: one based on scaling method, and the other based on a preliminary design using Building Information Modeling (BIM), an emerging technology in Architecture/Engineering/Construction, which enables design options, performance analysis and cost estimating in the early design stage.

  16. Pilot Scale Water Gas Shift - Membrane Device for Hydrogen from Coal

    SciTech Connect (OSTI)

    Barton, Tom

    2013-06-30

    The objectives of the project were to build pilot scale hydrogen separation systems for use in a gasification product stream. This device would demonstrate fabrication and manufacturing techniques for producing commercially ready facilities. The design was a 2 lb/day hydrogen device which included composite hydrogen separation membranes, a water gas shift monolith catalyst, and stainless steel structural components. Synkera Technologies was to prepare hydrogen separation membranes with metallic rims, and to adjust the alloy composition in their membranes to a palladium-gold composition which is sulfur resistant. Chart was to confirm their brazing technology for bonding the metallic rims of the composite membranes to their structural components and design and build the 2 lbs/day device incorporating membranes and catalysts. WRI prepared the catalysts and completed the testing of the membranes and devices on coal derived syngas. The reactor incorporated eighteen 2'' by 7'' composite palladium alloy membranes. These membranes were assembled with three stacks of three paired membranes. Initial vacuum testing and visual inspection indicated that some membranes were cracked, either in transportation or in testing. During replacement of the failed membranes, while pulling a vacuum on the back side of the membranes, folds were formed in the flexible composite membranes. In some instances these folds led to cracks, primarily at the interface between the alumina and the aluminum rim. The design of the 2 lb/day device was compromised by the lack of any membrane isolation. A leak in any membrane failed the entire device. A large number of tests were undertaken to bring the full 2 lb per day hydrogen capacity on line, but no single test lasted more than 48 hours. Subsequent tests to replace the mechanical seals with brazing have been promising, but the technology remains promising but not proven.

  17. Voltage sensing systems and methods for passive compensation of temperature related intrinsic phase shift

    DOE Patents [OSTI]

    Davidson, James R. (Idaho Falls, ID); Lassahn, Gordon D. (Idaho Falls, ID)

    2001-01-01

    A small sized electro-optic voltage sensor capable of accurate measurement of high levels of voltages without contact with a conductor or voltage source is provided. When placed in the presence of an electric field, the sensor receives an input beam of electromagnetic radiation into the sensor. A polarization beam displacer serves as a filter to separate the input beam into two beams with orthogonal linear polarizations. The beam displacer is oriented in such a way as to rotate the linearly polarized beams such that they enter a Pockels crystal at a preferred angle of 45 degrees. The beam displacer is therefore capable of causing a linearly polarized beam to impinge a crystal at a desired angle independent of temperature. The Pockels electro-optic effect induces a differential phase shift on the major and minor axes of the input beam as it travels through the Pockels crystal, which causes the input beam to be elliptically polarized. A reflecting prism redirects the beam back through the crystal and the beam displacer. On the return path, the polarization beam displacer separates the elliptically polarized beam into two output beams of orthogonal linear polarization representing the major and minor axes. In crystals that introduce a phase differential attributable to temperature, a compensating crystal is provided to cancel the effect of temperature on the phase differential of the input beam. The system may include a detector for converting the output beams into electrical signals, and a signal processor for determining the voltage based on an analysis of the output beams. The output beams are amplitude modulated by the frequency of the electric field and the amplitude of the output beams is proportional to the magnitude of the electric field, which is related to the voltage being measured.

  18. Sealed, nozzle-mix burners for silica deposition

    DOE Patents [OSTI]

    Adler, Meryle D. M.; Brown, John T.; Misra, Mahendra K.

    2003-07-08

    Burners (40) for producing fused silica boules are provided. The burners employ a tube-in-tube (301-306) design with flats (56, 50) on some of the tubes (305, 301) being used to limit the cross-sectional area of certain passages (206, 202) within the burner and/or to atomize a silicon-containing, liquid source material, such as OMCTS. To avoid the possibility of flashback, the burner has separate passages for fuel (205) and oxygen (204, 206), i.e., the burner employs nozzle mixing, rather than premixing, of the fuel and oxygen. The burners are installed in burner holes (26) formed in the crown (20) of a furnace and form a seal with those holes so that ambient air cannot be entrained into the furnace through the holes. An external air cooled jacket (60) can be used to hold the temperature of the burner below a prescribed upper limit, e.g., 400.degree. C.

  19. All-solid electrodes with mixed conductor matrix

    DOE Patents [OSTI]

    Huggins, Robert A. (Stanford, CA); Boukamp, Bernard A. (Achterste Kamp, NL)

    1984-01-01

    Alkali metal based electrochemical cells offer a great deal of promise for applications in many areas such as electric vehicles and load leveling purposes in stationary power plants. Lithium is an attractive candidate as the electroactive species in such cells since lithium is very electropositive, abundant and light weight. One type of lithium-based cell utilizes a molten salt electrolyte and normally is operated at elevated temperatures. The subject invention provides an electrochemical cell in one embodiment of which lithium is the electroactive species. The cell comprises an electrolyte, a positive electrode, and a negative electrode, either or both of which is an all-solid, composite microstructural electrode containing both a reactant phase and a mixed ionic-electronic conducting phase. The cells of the subject invention exhibit improved kinetic features, current and power densities. Repeated charging and discharging of these cells can be accomplished without appreciable loss of capacity.

  20. Distribution and Room Air Mixing Risks to Retrofitted Homes

    SciTech Connect (OSTI)

    Burdick, A.

    2014-12-01

    ?Energy efficiency upgrades reduce heating and cooling loads on a house. With enough load reduction and if the HVAC system warrants replacement, the HVAC system is often upgraded with a more efficient, lower capacity system that meets the loads of the upgraded house. For a single-story house with ceiling supply air diffusers, ducts are often removed and upgraded. For houses with ducts that are embedded in walls, the cost of demolition precludes the replacement of ducts. The challenge with the use of existing ducts is that the reduced airflow creates a decreased throw at the supply registers, and the supply air and room air do not mix well, leading to potential thermal comfort complaints. This project investigates this retrofit scenario. The issues and solutions discussed here are relevant to all climate zones, with emphasis on climates that require cooling.

  1. Studies of the effects of curvature on dilution jet mixing

    SciTech Connect (OSTI)

    Holdeman, J.D.; Srinivasan, Ram: Reynolds, R.S.; White, C.D. Allied-Signal Aerospace Co., Phoenix, AZ )

    1992-02-01

    An analytical program was conducted using both three-dimensional numerical and empirical models to investigate the effects of transition liner curvature on the mixing of jets injected into a confined crossflow. The numerical code is of the TEACH type with hybrid numerics; it uses the power-law and SIMPLER algorithms, an orthogonal curvilinear coordinate system, and an algebraic Reynolds stress turbulence model. From the results of the numerical calculations, an existing empirical model for the temperature field downstream of single and multiple rows of jets injected into a straight rectangular duct was extended to model the effects of curvature. Temperature distributions, calculated with both the numerical and empirical models, are presented to show the effects of radius of curvature and inner and outer wall injection for single and opposed rows of cool dilution jets injected into a hot mainstream flow. 27 refs.

  2. Radiograph and passive data analysis using mixed variable optimization

    DOE Patents [OSTI]

    Temple, Brian A.; Armstrong, Jerawan C.; Buescher, Kevin L.; Favorite, Jeffrey A.

    2015-06-02

    Disclosed herein are representative embodiments of methods, apparatus, and systems for performing radiography analysis. For example, certain embodiments perform radiographic analysis using mixed variable computation techniques. One exemplary system comprises a radiation source, a two-dimensional detector for detecting radiation transmitted through a object between the radiation source and detector, and a computer. In this embodiment, the computer is configured to input the radiographic image data from the two-dimensional detector and to determine one or more materials that form the object by using an iterative analysis technique that selects the one or more materials from hierarchically arranged solution spaces of discrete material possibilities and selects the layer interfaces from the optimization of the continuous interface data.

  3. Mixed mode fuel injector with individually moveable needle valve members

    DOE Patents [OSTI]

    Stewart, Chris; Chockley, Scott A.; Ibrahim, Daniel R.; Lawrence, Keith; Tomaseki, Jay; Azam, Junru H.; Tian, Steven Ye; Shafer, Scott F.

    2004-08-03

    A fuel injector includes a homogenous charge nozzle outlet set and a conventional nozzle outlet set controlled respectively, by first and second needle valve members. One of the needle valve members moves to an open position while the other needle valve member remains stationary for a homogeneous charge injection event. The former needle valve member stays stationary while the other needle valve member moves to an open position for a conventional injection event. One of the needle valve members is at least partially positioned in the other needle valve member. Thus, the injector can perform homogeneous charge injection events, conventional injection events, or even a mixed mode having both types of injection events in a single engine cycle.

  4. Unitarity and the Three Flavour Neutrino Mixing Matrix

    SciTech Connect (OSTI)

    Parke, Stephen; Ross-Lonergan, Mark

    2015-08-20

    Unitarity is a fundamental property of any theory required to ensure we work in a theoretically consistent framework. In comparison with the quark sector, experimental tests of unitarity for the 3x3 neutrino mixing matrix are considerably weaker. It must be remembered that the vast majority of our information on the neutrino mixing angles originates from v-e and vμ disappearance experiments, with the assumption of unitarity being invoked to constrain the remaining elements. New physics can invalidate this assumption for the 3x3 subset and thus modify our precision measurements. We also perform a reanalysis to see how global knowledge is altered when one refits oscillation results without assuming unitarity, and present 3σ ranges for allowed UPMNS elements consistent with all observed phenomena. We calculate the bounds on the closure of the six neutrino unitarity triangles, with the closure of the v-e and vμ triangle being constrained to be ≤0.03, while the remaining triangles are significantly less constrained to be ≤ 0.1 - 0.2. Similarly for the row and column normalization, we find their deviation from unity is constrained to be ≤ 0.2 - 0.4, for four out of six such normalizations, while for the vμ and ve row normalization the deviations are constrained to be ≤0.07, all at the 3σCL. Additionally, we emphasize that there is significant room for new low energy physics, especially in the vτ sector which very few current experiments constrain directly.

  5. High Catalytic Activity of Au/CeOx/TiO2(110) Controlled by the Nature of the Mixed Metal Oxide at the Nanometer Level

    SciTech Connect (OSTI)

    Park, J.; Graciani, J; Evans, J; Stacchiola, D; Ma, S; Liu, P; Nambu, A; Sanz, J; Hrbek, J; et. al.

    2009-01-01

    Mixed-metal oxides play a very important role in many areas of chemistry, physics, materials science, and geochemistry. Recently, there has been a strong interest in understanding phenomena associated with the deposition of oxide nanoparticles on the surface of a second (host) oxide. Here, scanning tunneling microscopy, photoemission, and density-functional calculations are used to study the behavior of ceria nanoparticles deposited on a TiO2(110) surface. The titania substrate imposes nontypical coordination modes on the ceria nanoparticles. In the CeOx/TiO2(110) systems, the Ce cations adopt an structural geometry and an oxidation state (+3) that are quite different from those seen in bulk ceria or for ceria nanoparticles deposited on metal substrates. The increase in the stability of the Ce3+ oxidation state leads to an enhancement in the chemical and catalytic activity of the ceria nanoparticles. The codeposition of ceria and gold nanoparticles on a TiO2(110) substrate generates catalysts with an extremely high activity for the production of hydrogen through the water-gas shift reaction (H2O + CO ? H2 + CO2) or for the oxidation of carbon monoxide (2CO + O2 ? 2CO2). The enhanced stability of the Ce3+ state is an example of structural promotion in catalysis described here on the atomic level. The exploration of mixed-metal oxides at the nanometer level may open avenues for optimizing catalysts through stabilization of unconventional surface structures with special chemical activity.

  6. Accurate evaluations of the field shift and lowest-order QED correction for the ground 1{sup 1}S?states of some light two-electron ions

    SciTech Connect (OSTI)

    Frolov, Alexei M.; Wardlaw, David M.

    2014-09-14

    Mass-dependent and field shift components of the isotopic shift are determined to high accuracy for the ground 1{sup 1}S?states of some light two-electron Li{sup +}, Be{sup 2+}, B{sup 3+}, and C{sup 4+} ions. To determine the field components of these isotopic shifts we apply the Racah-Rosental-Breit formula. We also determine the lowest order QED corrections to the isotopic shifts for each of these two-electron ions.

  7. Optimizing the mix of strategies for control of vehicular emissions

    SciTech Connect (OSTI)

    Lejano, R.P.; Ayala, P.M.; Gonzales, E.A.

    1997-01-01

    A number of strategies for the control of vehicular emissions are being considered by the Philippine government to address Metropolitan Manila`s air quality problem. An analytical tool is needed for optimizing criteria pollutant reductions given the budgetary constraints. The simplest approach is to take costs and pollutant removals to be linear with each strategy`s scale of activity, and this is readily solved as a linear programming problem. Another approach is to use a dynamic system of weights which shift with progressive improvements in pollutant emissions. The two approaches yield somewhat different results, suggesting the sensitivity of the solution to the assumed weights. The study also illustrates the importance of a sound methodology for evaluating priorities given to different air quality goals. One such methodology may involve a polling of expert panels and the public to gain insight into the relative importance given to competing emissions reduction goals. An informal polling of resource agency staff was conducted and discussed in this paper. The authors take the position that proper planning involves tracing intermediate steps to the final outcome and not just focusing on the latter. 17 refs., 1 fig., 8 tabs.

  8. Radiative Influences on Glaciation Time-Scales of Mixed-Phase Clouds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Radiative Influences on Glaciation Time-Scales of Mixed-Phase Clouds Harrington, Jerry The Pennsylvania State University Category: Modeling Mixed-phase stratus clouds are dominant in the Arctic during much of the year. These clouds typically have liquid tops that precipitate ice. Time scales for the complete glaciation of such clouds (the Bergeron process) are typically computed using the classical mass growth equations for crystals and liquid drops. However, mixed phase arctic stratus have

  9. A Mixed Mode HCCI/DI Engine Based on a Novel Heavy Fuel Atomizer |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy A Mixed Mode HCCI/DI Engine Based on a Novel Heavy Fuel Atomizer A Mixed Mode HCCI/DI Engine Based on a Novel Heavy Fuel Atomizer 2002 DEER Conference Presentation: The Ohio State University PDF icon 2002_deer_rizzoni.pdf More Documents & Publications Mixed-mode diesel HCCI with External Mixture Formation: Preliminary Results Diesel HCCI with External Mixture Preparation A Micro-Variable Circular Orifice (MVCO) Fuel Injector for Zoned Low Temperature Combustion

  10. Radon Measurements of Atmospheric Mixing (RAMIX) 2006-2014 Final Campaign

    Office of Scientific and Technical Information (OSTI)

    Summary (Program Document) | SciTech Connect Radon Measurements of Atmospheric Mixing (RAMIX) 2006-2014 Final Campaign Summary Citation Details In-Document Search Title: Radon Measurements of Atmospheric Mixing (RAMIX) 2006-2014 Final Campaign Summary Uncertainty in vertical mixing between the surface layer, boundary layer, and free troposphere leads to large uncertainty in "top-down" estimates of regional land-atmosphere carbon exchange (i.e., estimates based on measurements of

  11. Radon Measurements of Atmospheric Mixing (RAMIX) 2006-2014 Final Campaign

    Office of Scientific and Technical Information (OSTI)

    Summary (Program Document) | SciTech Connect Radon Measurements of Atmospheric Mixing (RAMIX) 2006-2014 Final Campaign Summary Citation Details In-Document Search Title: Radon Measurements of Atmospheric Mixing (RAMIX) 2006-2014 Final Campaign Summary Uncertainty in vertical mixing between the surface layer, boundary layer, and free troposphere leads to large uncertainty in "top-down" estimates of regional land-atmosphere carbon exchange (i.e., estimates based on measurements of

  12. Mixed-mode diesel HCCI with External Mixture Formation: Preliminary Results

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Mixed-mode diesel HCCI with External Mixture Formation: Preliminary Results Mixed-mode diesel HCCI with External Mixture Formation: Preliminary Results 2003 DEER Conference Presentation: The Ohio State University PDF icon 2003_deer_rizzoni.pdf More Documents & Publications Diesel HCCI with External Mixture Preparation Gasoline-like fuel effects on advanced combustion regimes A Mixed Mode HCCI/DI Engine Based on a Novel Heavy Fuel Atomizer

  13. F-AREA PUMP TANK 1 MIXING ANALYSIS

    SciTech Connect (OSTI)

    Tamburello, D; Richard Dimenna, R; Si Lee, S

    2008-11-05

    The F-area pump tanks are used to transfer supernate, sludge, and other materials. In any transfer, the solution must stay well mixed without allowing particulate matter to settle out of the liquid and, thus, accumulate in the bottom of the pump tank. Recently, the pulse jet mixing in F-area Pump Tank 1 (FPT1) has been decommissioned. An analysis of the liquid transfer through FPT1 has been performed using computational fluid dynamics (CFD) methods to assess whether or not the velocities throughout the tank will remain high enough to keep all particulate suspended using only transfer and recirculation pumps. The following paragraph is an abbreviated synopsis of the transfer procedure for FPT1 [1, 2]. Prior to a transfer, FPT1 begins to be filled with inhibited water through the inlet transfer line (TI). When the tank liquid level reaches 52.5 inches above the absolute tank bottom, the recirculation pump (RI and RO) is activated. At a tank liquid level of 72.5 inches above the absolute tank bottom, the outlet transfer line (TO) is activated to reduce the liquid level in FPT1 and transfer inhibited water to H-area Pump Tank 7 (HPT7). The liquid level is reduced down to 39.5 inches, with an allowable range from 37.5 to 41.5 inches above the absolute tank bottom. HPT7 goes through a similar procedure as FPT1 until both have tank liquid levels of approximately 39.5 inches above the absolute tank bottom. The transfer of inhibited water continues until a steady-state has been reached in both pump tanks. At this point, the supernate/sludge transfer begins with a minimum flow rate of 70 gpm and an average flow rate of 150 gpm. After the transfer is complete, the pump tanks (both FPT1 and HPT7) are pumped down to between 20.5 and 22.5 inches (above absolute bottom) and then flushed with 25,000 gallons of inhibited water to remove any possible sludge heal. After the flushing, the pump tanks are emptied. Note that the tank liquid level is measured using diptubes. Figure 2.1 provides a simplified sketch (not to scale) of FPT1 during the steady-state transfer condition, which consists of two inlet flows that impact the liquid surface as plunging jets and two outlet flows drawn from near the bottom of the tank. During the transfer, the supernate level is held at 39.5 inches above the absolute bottom of the tank [1, 2]. In addition, the FPT1 can contain up to 16.7 wt.% sludge particles within the supernate for a given transfer [2]. Test results from Tank 40 sludge Batch 3 [3] provide a typical range of particulate diameters between 0.1 and 25 {micro}m, with approximately 20 vol.% of the sludge distribution consisting of particles less than 1 {micro}m in diameter. The purpose of this analysis is to estimate FPT1 flow field during the steady-state transfer conditions to ensure that the tank remains mixed and that the velocities throughout the tank are sufficient to keep all sludge particulate suspended.

  14. The effect of mix on capsule yields as a function of shell thickness and gas fill

    SciTech Connect (OSTI)

    Bradley, P. A.

    2014-06-15

    An investigation of direct drive capsules with different shell thicknesses and gas fills was conducted to examine the amount of shock induced (Richtmyer-Meshkov) mix versus Rayleigh-Taylor mix from deceleration of the implosion. The RAGE (Eulerian) code with a turbulent mix model was used to model these capsules for neutron yields along with time-dependent mix amounts. The amount of Richtmyer-Meshkov induced mix from the shock breaking out of the shell is about 0.1??g (0.15??m of shell material), while the Rayleigh-Taylor mix is of order 1??g and determines the mixed simulation yield. The simulations were able to calculate a yield over mix (YOM) ratio (experiment/mix simulation) between 0.5 and 1.0 for capsules with shell thicknesses ranging from 7.5 to 20??m and with gas fills between 3.8 and 20?atm of D{sub 2} or DT. The simulated burn averaged T{sub ion} values typically lie with 0.5?keV of the data, which is within the measurement error. For capsules with shell thicknesses >25??m, the YOM values drop to 0.10??0.05, suggesting that some unmodeled effect needs to be accounted for in the thickest capsules.

  15. Fuel injection and mixing systems having piezoelectric elements and methods of using the same

    DOE Patents [OSTI]

    Mao, Chien-Pei; Short, John; Klemm, Jim; Abbott, Royce; Overman, Nick; Pack, Spencer; Winebrenner, Audra

    2011-12-13

    A fuel injection and mixing system is provided that is suitable for use with various types of fuel reformers. Preferably, the system includes a piezoelectric injector for delivering atomized fuel, a gas swirler, such as a steam swirler and/or an air swirler, a mixing chamber and a flow mixing device. The system utilizes ultrasonic vibrations to achieve fuel atomization. The fuel injection and mixing system can be used with a variety of fuel reformers and fuel cells, such as SOFC fuel cells.

  16. FINAL REPORT: An Investigation of the Microphysical, Radiative, and Dynamical Properties of Mixed-Phase Clouds

    SciTech Connect (OSTI)

    Shupe, Matthew D

    2007-10-01

    This final report summarizes the major accomplishments and products resulting from a three-year grant funded by the DOE, Office of Science, Atmospheric Radiation Measurement Program titled: An Investigation of the Microphysical, Radiative, and Dynamical Properties of Mixed-Phase Clouds. Accomplishments are listed under the following subcategories: Mixed-phase cloud retrieval method development; Mixed-phase cloud characterization; ARM mixed-phase cloud retrieval review; and New ARM MICROBASE product. In addition, lists are provided of service to the Atmospheric Radiation Measurement Program, data products provided to the broader research community, and publications resulting from this grant.

  17. Intercomparison of model simulations of mixed-phase clouds observed during

    Office of Scientific and Technical Information (OSTI)

    the ARM Mixed-Phase Arctic Cloud Experiment. Part I: Single layer cloud (Journal Article) | SciTech Connect Part I: Single layer cloud Citation Details In-Document Search Title: Intercomparison of model simulations of mixed-phase clouds observed during the ARM Mixed-Phase Arctic Cloud Experiment. Part I: Single layer cloud Results are presented from an intercomparison of single-column and cloud-resolving model simulations of a cold-air outbreak mixed-phase stratocumulus cloud observed during

  18. Voluntary Protection Program Onsite Review, Advanced Mixed Waste Treatment Project- May 2009

    Broader source: Energy.gov [DOE]

    Evaluation to determine whether Advanced Mixed Waste Treatment Project is continuing to perform at a level deserving DOE-VPP Star recognition.

  19. Mixed valency and site-preference chemistry for cerium and its...

    Office of Scientific and Technical Information (OSTI)

    from two competing oxidation states-itinerant Ce4+ and localized Ce3+. Under applied stress, anomalous transitions are observed but not well understood. Here we treat mixed...

  20. Progress on Acidic Zirconia Mixed Oxides for Efficient NH3-SCR Catalysis |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Acidic Zirconia Mixed Oxides for Efficient NH3-SCR Catalysis Progress on Acidic Zirconia Mixed Oxides for Efficient NH3-SCR Catalysis Details progress on non-zeolitic zirconia-based mixed oxides as promising new SCR catalyst materials and results of engine bench testing of full-size SCR prototype confirms Details progress on non-zeolitic zirconia-based mixed oxides as promising new SCR catalyst materials and results of engine bench testing of full-size SCR prototype

  1. Computational Modeling of Mixed Solids for CO2 CaptureSorbents...

    Office of Scientific and Technical Information (OSTI)

    In this presentation, we apply our screening methodology to mixing solid systems to adjust ... Resource Relation: Conference: 2015 AIChE Spring Meeting Research Org: National Energy ...

  2. Guides and Case Studies for Hot-Dry and Mixed-Dry Climates | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Dry and Mixed-Dry Climates Guides and Case Studies for Hot-Dry and Mixed-Dry Climates Map of the Hot-Dry and Mixed-Dry Zone of the United States. The zone contains the eastern side of California and follows the US border to cover the western half of Texas. The Department of Energy (DOE) has developed a series of best practices and case studies to help builders improve whole-house energy performance in buildings found in hot-dry and mixed-dry climates. Best Practice Guides 40%

  3. Radon Measurements of Atmospheric Mixing (RAMIX) 2006–2014 Final Campaign Summary

    SciTech Connect (OSTI)

    Fischer, ML; Biraud, SC; Hirsch, A

    2015-05-01

    Uncertainty in vertical mixing between the surface layer, boundary layer, and free troposphere leads to large uncertainty in “top-down” estimates of regional land-atmosphere carbon exchange (i.e., estimates based on measurements of atmospheric CO2 mixing ratios). The radioisotope radon-222 (222Rn) is a valuable tracer for measuring atmospheric mixing because it is emitted from the land surface and has a short enough half-life (3.8 days) to allow characterization of mixing processes based on vertical profile measurements.

  4. Radon Measurements of Atmospheric Mixing (RAMIX) 2006–2014 Final Campaign Summary

    SciTech Connect (OSTI)

    Fischer, ML; Biraud, SC

    2015-05-01

    Uncertainty in vertical mixing between the surface layer, boundary layer, and free troposphere leads to large uncertainty in “top-down” estimates of regional land-atmosphere carbon exchange (i.e., estimates based on measurements of atmospheric CO2 mixing ratios. Radon-222 (222Rn) is a valuable tracer for measuring atmospheric mixing because it is emitted from the land surface and has a short enough half-life (3.8 days) to allow characterization of mixing processes based on vertical profile measurements.

  5. Performance Analysis for Mixing Pumps in Tank 18

    SciTech Connect (OSTI)

    Lee, S.Y.

    2002-04-16

    In support of sludge suspension and mixing operations in Tank 18, flow evolution models were developed and performance calculations completed for the advanced design mixer pump (ADMP) and the modified ADMP (MADMP). The MADMP was being considered as a replacement for the ADMP in Tank 18. The models and calculations were based on prototypic tank geometry and expected normal operating conditions as defined by Waste Removal Closure (WRC) Engineering. Computational fluid dynamics models of both the TNX full tank experimental facility and Tank 18 were developed using the FLUENT(tm) code. TNX test data were used to benchmark the models and assess the efficiency of sludge suspension and removal operations in the 85 ft tank. The models employed a three-dimensional approach, a two-equation turbulence model, and a stepped-rotation approximation to estimate pump rotation effects. A two-dimensional approach was also used as a scoping analysis to examine multi-dimensional effects of fluid motion on the flow circulation patterns in the tank. The results were verified by both TNX test data and literature data. Local velocity was used as a measure of slurrying and mixing capability. The results showed that normal operations in Tank 18 with the existing ADMP mixer and a 70 inch liquid level provide adequate sludge removal in most regions of the tank. The exception is the region within about 2 ft of the wall, assuming the minimum velocity required to suspend waste sludge is 2.27 ft/sec. Further results showed that the time to reach a steady-state flow pattern was affected by both pump rotation and pump location. Sensitivity studies showed that a higher tank level and the smaller nozzle size would result in better performance in suspending and removing the sludge. The results also showed that the MADMP mixer has the best sludge removal capacity. Computational results for two different fluids, water and a typical slurry, showed that the maximum clearing distance was not sensiti ve to the slurry fluid properties.

  6. Communication: Towards the binding energy and vibrational red shift of the simplest organic hydrogen bond: Harmonic constraints for methanol dimer

    SciTech Connect (OSTI)

    Heger, Matthias; Suhm, Martin A.; Mata, Ricardo A.

    2014-09-14

    The discrepancy between experimental and harmonically predicted shifts of the OH stretching fundamental of methanol upon hydrogen bonding to a second methanol unit is too large to be blamed mostly on diagonal and off-diagonal anharmonicity corrections. It is shown that a decisive contribution comes from post-MP2 electron correlation effects, which appear not to be captured by any of the popular density functionals. We also identify that the major deficiency is in the description of the donor OH bond. Together with estimates for the electronic and harmonically zero-point corrected dimer binding energies, this work provides essential constraints for a quantitative description of this simple hydrogen bond. The spectroscopic dissociation energy is predicted to be larger than 18 kJ/mol and the harmonic OH-stretching fundamental shifts by about ?121 cm{sup ?1} upon dimerization, somewhat more than in the anharmonic experiment (?111 cm{sup ?1})

  7. Reply to comment on 'Tunable three-dimensional intensity distribution by a pure phase-shifting apodizer'

    SciTech Connect (OSTI)

    Gao Xiumin

    2007-01-10

    I thank Canales et al. very much for their attention to the effect of the phase apodizer, especially for their comment on my paper [Appl. Opt. 44, 4870(2005)]. I reinvestigated the three-dimensional intensity distribution by a pure phase-shifting apodizer, and the main results on focal shift, focal split, and three intensity distributions are correct.However, the changing principle of the Strehl ratio is wrong, as Canales et al. show in their comment. Here, I show the cause leading to the erroneous result and give the correct dependence of the Strehl ratio on the inner radius and relative waist width. I am very sorry for the incorrect results in the paper.

  8. ANALYSIS OF TURBULENT MIXING JETS IN LARGE SCALE TANK

    SciTech Connect (OSTI)

    Lee, S; Richard Dimenna, R; Robert Leishear, R; David Stefanko, D

    2007-03-28

    Flow evolution models were developed to evaluate the performance of the new advanced design mixer pump for sludge mixing and removal operations with high-velocity liquid jets in one of the large-scale Savannah River Site waste tanks, Tank 18. This paper describes the computational model, the flow measurements used to provide validation data in the region far from the jet nozzle, the extension of the computational results to real tank conditions through the use of existing sludge suspension data, and finally, the sludge removal results from actual Tank 18 operations. A computational fluid dynamics approach was used to simulate the sludge removal operations. The models employed a three-dimensional representation of the tank with a two-equation turbulence model. Both the computational approach and the models were validated with onsite test data reported here and literature data. The model was then extended to actual conditions in Tank 18 through a velocity criterion to predict the ability of the new pump design to suspend settled sludge. A qualitative comparison with sludge removal operations in Tank 18 showed a reasonably good comparison with final results subject to significant uncertainties in actual sludge properties.

  9. Molten salt processing of mixed wastes with offgas condensation

    SciTech Connect (OSTI)

    Cooper, J.F.; Brummond, W.; Celeste, J.; Farmer, J.; Hoenig, C.; Krikorian, O.H.; Upadhye, R. ); Gay, R.L.; Stewart, A.; Yosim, S. . Energy Systems Group)

    1991-05-13

    We are developing an advanced process for treatment of mixed wastes in molten salt media at temperatures of 700--1000{degrees}C. Waste destruction has been demonstrated in a single stage oxidation process, with destruction efficiencies above 99.9999% for many waste categories. The molten salt provides a heat transfer medium, prevents thermal surges, and functions as an in situ scrubber to transform the acid-gas forming components of the waste into neutral salts and immobilizes potentially fugitive materials by a combination of particle wetting, encapsulation and chemical dissolution and solvation. Because the offgas is collected and assayed before release, and wastes containing toxic and radioactive materials are treated while immobilized in a condensed phase, the process avoids the problems sometimes associated with incineration processes. We are studying a potentially improved modification of this process, which treats oxidizable wastes in two stages: pyrolysis followed by catalyzed molten salt oxidation of the pyrolysis gases at ca. 700{degrees}C. 15 refs., 5 figs., 1 tab.

  10. Chemical tailoring of steam to remediate underground mixed waste contaminents

    DOE Patents [OSTI]

    Aines, Roger D. (Livermore, CA); Udell, Kent S. (Berkeley, CA); Bruton, Carol J. (Livermore, CA); Carrigan, Charles R. (Tracy, CA)

    1999-01-01

    A method to simultaneously remediate mixed-waste underground contamination, such as organic liquids, metals, and radionuclides involves chemical tailoring of steam for underground injection. Gases or chemicals are injected into a high pressure steam flow being injected via one or more injection wells to contaminated soil located beyond a depth where excavation is possible. The injection of the steam with gases or chemicals mobilizes contaminants, such as metals and organics, as the steam pushes the waste through the ground toward an extraction well having subatmospheric pressure (vacuum). The steam and mobilized contaminants are drawn in a substantially horizontal direction to the extraction well and withdrawn to a treatment point above ground. The heat and boiling action of the front of the steam flow enhance the mobilizing effects of the chemical or gas additives. The method may also be utilized for immobilization of metals by using an additive in the steam which causes precipitation of the metals into clusters large enough to limit their future migration, while removing any organic contaminants.

  11. Tribimaximal neutrino mixing and neutrinoless double beta decay

    SciTech Connect (OSTI)

    Hirsch, M.; Morisi, S.; Valle, J. W. F. [AHEP Group, Institut de Fisica Corpuscular-- C.S.I.C./Universitat de Valencia, Edificio Institutos de Paterna, Apt 22085, E-46071 Valencia (Spain)

    2008-11-01

    We present a tribimaximal lepton mixing scheme where the neutrinoless double beta decay rate has a lower bound which correlates with the ratio {alpha}{identical_to}{delta}m{sub sol}{sup 2}/{delta}m{sub atm}{sup 2} well determined by current data, as well as with the unknown Majorana CP phase {phi}{sub 12} characterizing the solar neutrino subsystem. For the special value {phi}{sub 12}=({pi}/2) (opposite CP-sign neutrinos) the {beta}{beta}{sub 0{nu}} rate vanishes at tree level when {delta}m{sub sol}{sup 2}/{delta}m{sub atm}{sup 2}=3/80, only allowed at 3{sigma}. For all other cases the rate is nonzero, and lies within current and projected experimental sensitivities close to {phi}{sub 12}=0. We suggest two model realizations of this scheme in terms of A{sub 4}xZ{sub 2} and A{sub 4}xZ{sub 4} flavor symmetries.

  12. Investigation of Mixed Oxide Catalysts for NO Oxidation

    SciTech Connect (OSTI)

    Szanyi, Janos; Karim, Ayman M.; Pederson, Larry R.; Kwak, Ja Hun; Mei, Donghai; Tran, Diana N.; Herling, Darrell R.; Muntean, George G.; Peden, Charles HF; Howden, Ken; Qi, Gongshin; Li, Wei

    2014-12-09

    The oxidation of engine-generated NO to NO2 is an important step in the reduction of NOx in lean engine exhaust because NO2 is required for the performance of the LNT technology [2], and it enhances the activities of ammonia selective catalytic reduction (SCR) catalysts [1]. In particular, for SCR catalysts an NO:NO2 ratio of 1:1 is most effective for NOx reduction, whereas for LNT catalysts, NO must be oxidized to NO2 before adsorption on the storage components. However, NO2 typically constitutes less than 10% of NOx in lean exhaust, so catalytic oxidation of NO is essential. Platinum has been found to be especially active for NO oxidation, and is widely used in DOC and LNT catalysts. However, because of the high cost and poor thermal durability of Pt-based catalysts, there is substantial interest in the development of alternatives. The objective of this project, in collaboration with partner General Motors, is to develop mixed metal oxide catalysts for NO oxidation, enabling lower precious metal usage in emission control systems. [1] M. Koebel, G. Madia, and M. Elsener, Catalysis Today 73, 239 (2002). [2] C. H. Kim, G. S. Qi, K. Dahlberg, and W. Li, Science 327, 1624 (2010).

  13. Processing of solid mixed waste containing radioactive and hazardous materials

    DOE Patents [OSTI]

    Gotovchikov, Vitaly T. (Moscow, RU); Ivanov, Alexander V. (Moscow, RU); Filippov, Eugene A. (Moscow, RU)

    1998-05-12

    Apparatus for the continuous heating and melting of a solid mixed waste bearing radioactive and hazardous materials to form separate metallic, slag and gaseous phases for producing compact forms of the waste material to facilitate disposal includes a copper split water-cooled (cold) crucible as a reaction vessel for receiving the waste material. The waste material is heated by means of the combination of a plasma torch directed into the open upper portion of the cold crucible and an electromagnetic flux produced by induction coils disposed about the crucible which is transparent to electromagnetic fields. A metallic phase of the waste material is formed in a lower portion of the crucible and is removed in the form of a compact ingot suitable for recycling and further processing. A glass-like, non-metallic slag phase containing radioactive elements is also formed in the crucible and flows out of the open upper portion of the crucible into a slag ingot mold for disposal. The decomposition products of the organic and toxic materials are incinerated and converted to environmentally safe gases in the melter.

  14. Processing of solid mixed waste containing radioactive and hazardous materials

    DOE Patents [OSTI]

    Gotovchikov, V.T.; Ivanov, A.V.; Filippov, E.A.

    1998-05-12

    Apparatus for the continuous heating and melting of a solid mixed waste bearing radioactive and hazardous materials to form separate metallic, slag and gaseous phases for producing compact forms of the waste material to facilitate disposal includes a copper split water-cooled (cold) crucible as a reaction vessel for receiving the waste material. The waste material is heated by means of the combination of a plasma torch directed into the open upper portion of the cold crucible and an electromagnetic flux produced by induction coils disposed about the crucible which is transparent to electromagnetic fields. A metallic phase of the waste material is formed in a lower portion of the crucible and is removed in the form of a compact ingot suitable for recycling and further processing. A glass-like, non-metallic slag phase containing radioactive elements is also formed in the crucible and flows out of the open upper portion of the crucible into a slag ingot mold for disposal. The decomposition products of the organic and toxic materials are incinerated and converted to environmentally safe gases in the melter. 6 figs.

  15. Vitrification development plan for US Department of Energy mixed wastes

    SciTech Connect (OSTI)

    Peters, R.; Lucerna, J.; Plodinec, M.J.

    1993-10-01

    This document is a general plan for conducting vitrification development for application to mixed wastes owned by the US Department of Energy. The emphasis is a description and discussion of the data needs to proceed through various stages of development. These stages are (1) screening at a waste site to determine which streams should be vitrified, (2) waste characterization and analysis, (3) waste form development and treatability studies, (4) process engineering development, (5) flowsheet and technical specifications for treatment processes, and (6) integrated pilot-scale demonstration. Appendices provide sample test plans for various stages of the vitrification development process. This plan is directed at thermal treatments which produce waste glass. However, the study is still applicable to the broader realm of thermal treatment since it deals with issues such as off-gas characterization and waste characterization that are not necessarily specific to vitrification. The purpose is to provide those exploring or considering vitrification with information concerning the kinds of data that are needed, the way the data are obtained, and the way the data are used. This will provide guidance to those who need to prioritize data needs to fit schedules and budgets. Knowledge of data needs also permits managers and planners to estimate resource requirements for vitrification development.

  16. Effect of YSZ sintering temperature on mixed potential sensor performance

    SciTech Connect (OSTI)

    Sekhar, Praveen K; Brosha, Eric L; Rangachary, Mukundan; Garzon, Fernando H; Nelson, Mark A; Toracco, Dennis

    2009-01-01

    In this article, the influence of Yttria-Stabilized Zirconia (YSZ) sintering temperature on a Pt/YSZ/La{sub 0.8}Sr{sub 0.2}CrO{sub 3} mixed potential sensor performance is reported. The sintering temperature of YSZ was varied from 1000 to 1200 C. Mercury porosity measurements were performed to estimate the porosity and tortuosity of the YSZ sample as a function of sintering temperature. Further, the surface area of YSZ was computed by the BET method. After YSZ characterization, the unbiased and biased sensor response was recorded. The 1000 C sintered YSZ sample was taken as the reference for comparison purposes. Experimental results indicated a 30% reduction in porosity for the 1200 C sintered YSZ sample, accounting for a 14-fold increase in the sensor response rise time. In addition, for the same sample, a 13-fold increase in sensitivity was observed upon exposure to propylene (100 ppm), associated with a 76% reduction in surface area. The slow response time of the sensor with YSZ sintered at higher temperatures has been attributed to higher tortuosity (delay in gas permeation to the three phase interface). Whereas, reduced heterogeneous catalysis induced by lower surface area accounts for the rise in sensitivity levels. The optimum YSZ sintering temperature was found to lie between 1100 and 1150 C.

  17. Mixed ionic-electronic conductor-based radiation detectors and methods of fabrication

    DOE Patents [OSTI]

    Conway, Adam; Beck, Patrick R; Graff, Robert T; Nelson, Art; Nikolic, Rebecca J; Payne, Stephen A; Voss, Lars; Kim, Hadong

    2015-04-07

    A method of fabricating a mixed ionic-electronic conductor (e.g. TlBr)-based radiation detector having halide-treated surfaces and associated methods of fabrication, which controls polarization of the mixed ionic-electronic MIEC material to improve stability and operational lifetime.

  18. An experimental investigation of thermal mixing and combustion in supersonic flows

    SciTech Connect (OSTI)

    Srikrishnan, A.R.; Kurian, J.; Sriramulu, V.

    1996-12-01

    A radially lobed nozzle (petal nozzle) is being increasingly recognized as a potential candidate for promoting mixing in compressible flows. An experimental investigation has been conducted to study its effectiveness in improving thermal mixing and combustion in supersonic flow. A hot gas jet issuing supersonically from a lobed nozzle mixes with a cold supersonic jet in a circular mixing tube. The two jets issue coaxially. A detailed survey of the flow field inside the mixing duct reveals that nearly complete thermal mixing (as exemplified by the nearly uniform temperature distribution) could be achieved in a short distance when a lobed nozzle is employed. The results also indicate the presence of large-scale vortices in the flow field downstream of the lobed nozzle. Having thus created a field in which mixing is good, supersonic combustion was then attempted. Kerosene was introduced into the hot stream issuing from the lobed nozzle and it burned mainly in the mixing tube, which served as a supersonic combustor. Resulting temperature and pressure rises were measured and the supersonic combustion efficiency was found to be of the order of 60%. The performance of a conventional conical nozzle was found to be much inferior to that of the petal nozzle under identical conditions.

  19. Dry low NOx combustion system with pre-mixed direct-injection secondary fuel nozzle

    DOE Patents [OSTI]

    Zuo, Baifang; Johnson, Thomas; Ziminsky, Willy; Khan, Abdul

    2013-12-17

    A combustion system includes a first combustion chamber and a second combustion chamber. The second combustion chamber is positioned downstream of the first combustion chamber. The combustion system also includes a pre-mixed, direct-injection secondary fuel nozzle. The pre-mixed, direct-injection secondary fuel nozzle extends through the first combustion chamber into the second combustion chamber.

  20. An Innovative Injection and Mixing System for Diesel Fuel Reforming

    SciTech Connect (OSTI)

    Spencer Pack

    2007-12-31

    This project focused on fuel stream preparation improvements prior to injection into a solid oxide fuel cell reformer. Each milestone and the results from each milestone are discussed in detail in this report. The first two milestones were the creation of a coking formation test rig and various testing performed on this rig. Initial tests indicated that three anti-carbon coatings showed improvement over an uncoated (bare metal) baseline. However, in follow-up 70 hour tests of the down selected coatings, Scanning Electron Microscope (SEM) analysis revealed that no carbon was generated on the test specimens. These follow-up tests were intended to enable a down selection to a single best anti-carbon coating. Without the formation of carbon it was impossible to draw conclusions as to which anti-carbon coating showed the best performance. The final 70 hour tests did show that AMCX AMC26 demonstrated the lowest discoloration of the metal out of the three down selected anti-carbon coatings. This discoloration did not relate to carbon but could be a useful result when carbon growth rate is not the only concern. Unplanned variations in the series of tests must be considered and may have altered the results. Reliable conclusions could only be drawn from consistent, repeatable testing beyond the allotted time and funding for this project. Milestones 3 and 4 focused on the creation of a preheating pressure atomizer and mixing chamber. A design of experiment test helped identify a configuration of the preheating injector, Build 1, which showed a very uniform fuel spray flow field. This injector was improved upon by the creation of a Build 2 injector. Build 2 of the preheating injector demonstrated promising SMD results with only 22psi fuel pressure and 0.7 in H2O of Air. It was apparent from testing and CFD that this Build 2 has flow field recirculation zones. These recirculation zones may suggest that this Build 2 atomizer and mixer would require steam injection to reduce the auto ignition potential. It is also important to note that to achieve uniform mixing within a short distance, some recirculation is necessary. Milestone 5 generated CFD and FEA results that could be used to optimize the preheating injector. CFD results confirmed the recirculation zones seen in test data and confirmed that the flow field would not change when attached to a reformer. The FEA predicted fuel wetted wall temperatures which led to several suggested improvements that could possibly improve nozzle efficiency. Milestone 6 (originally an optional task) took a different approach than the preheating pressure atomizer. It focused on creation and optimization of a piezoelectric injector which could perform at extremely low fuel pressures. The piezoelectric atomizer showed acceptable SMD results with fuel pressure less than 1.0 psig and air pressure less than 1.0 in H2O. These SMD values were enhanced when a few components were changed, and it is expected would improve further still at elevated air temperatures. It was demonstrated that the piezoelectric injector could accomplish the desired task. The addition of phase tracking and a burst mode to the frequency controller increased the usability of the piezoelectric injector. This injector is ready to move on to the next phase of development. Engine Components has met the required program milestones of this project. Some of the Milestones were adjusted to allow Milestone 6 to be completed in parallel with the other Milestones. Because of this, Task 3.10 and 3.13 were made optional instead of Milestone 6. Engine Components was extremely grateful for the support that was provided by NETL in support of this work.

  1. Hybrid multiscale simulation of a mixing-controlled reaction

    SciTech Connect (OSTI)

    Scheibe, Timothy D.; Schuchardt, Karen L.; Agarwal, Khushbu; Chase, Jared M.; Yang, Xiaofan; Palmer, Bruce J.; Tartakovsky, Alexandre M.; Elsethagen, Todd O.; Redden, George D.

    2015-09-01

    Continuum-scale models have been used to study subsurface flow, transport, and reactions for many years but lack the capability to resolve fine-grained processes. Recently, pore-scale models, which operate at scales of individual soil grains, have been developed to more accurately model and study pore-scale phenomena, such as mineral precipitation and dissolution reactions, microbially-mediated surface reactions, and other complex processes. However, these highly-resolved models are prohibitively expensive for modeling domains of sizes relevant to practical problems. To broaden the utility of pore-scale models for larger domains, we developed a hybrid multiscale model that initially simulates the full domain at the continuum scale and applies a pore-scale model only to areas of high reactivity. Since the location and number of pore-scale model regions in the model varies as the reactions proceed, an adaptive script defines the number and location of pore regions within each continuum iteration and initializes pore-scale simulations from macroscale information. Another script communicates information from the pore-scale simulation results back to the continuum scale. These components provide loose coupling between the pore- and continuum-scale codes into a single hybrid multiscale model implemented within the SWIFT workflow environment. In this paper, we consider an irreversible homogenous bimolecular reaction (two solutes reacting to form a third solute) in a 2D test problem. This paper is focused on the approach used for multiscale coupling between pore- and continuum-scale models, application to a realistic test problem, and implications of the results for predictive simulation of mixing-controlled reactions in porous media. Our results and analysis demonstrate that loose coupling provides a feasible, efficient and scalable approach for multiscale subsurface simulations.

  2. Boosted di-boson from a mixed heavy stop

    SciTech Connect (OSTI)

    Ghosh, Diptimoy

    2013-12-01

    The lighter mass eigenstate ($\\widetilde{t}_1$) of the two top squarks, the scalar superpartners of the top quark, is extremely difficult to discover if it is almost degenerate with the lightest neutralino ($\\widetilde{\\chi}_1^0$), the lightest and stable supersymmetric particle in the R-parity conserving supersymmetry. The current experimental bound on $\\widetilde{t}_1$ mass in this scenario stands only around 200 GeV. For such a light $\\widetilde{t}_1$, the heavier top squark ($\\widetilde{t}_2$) can also be around the TeV scale. Moreover, the high value of the higgs ($h$) mass prefers the left and right handed top squarks to be highly mixed allowing the possibility of a considerable branching ratio for $\\widetilde{t}_2 \\to \\widetilde{t}_1 h$ and $\\widetilde{t}_2 \\to \\widetilde{t}_1 Z$. In this paper, we explore the above possibility together with the pair production of $\\widetilde{t}_2$ $\\widetilde{t}_2^*$ giving rise to the spectacular di-boson + missing transverse energy final state. For an approximately 1 TeV $\\widetilde{t}_2$ and a few hundred GeV $\\widetilde{t}_1$ the final state particles can be moderately boosted which encourages us to propose a novel search strategy employing the jet substructure technique to tag the boosted $h$ and $Z$. The reconstruction of the $h$ and $Z$ momenta also allows us to construct the stransverse mass $M_{T2}$ providing an additional efficient handle to fight the backgrounds. We show that a 4--5$\\sigma$ signal can be observed at the 14 TeV LHC for $\\sim$ 1 TeV $\\widetilde{t}_2$ with 100 fb$^{-1}$ integrated luminosity.

  3. Neutral B meson mixing in unquenched lattice QCD

    SciTech Connect (OSTI)

    Gamiz, Elvira; Davies, Christine T. H.; Lepage, G. Peter; Shigemitsu, Junko; Wingate, Matthew

    2009-07-01

    We study B{sub d} and B{sub s} mixing in unquenched lattice QCD employing the MILC Collaboration gauge configurations that include u, d, and s sea quarks based on the improved staggered quark (AsqTad) action and a highly improved gluon action. We implement the valence light quarks also with the AsqTad action and use the nonrelativistic NRQCD action for the valence b quark. We calculate hadronic matrix elements necessary for extracting Cabibbo-Kobayashi-Maskawa matrix elements from experimental measurements of mass differences {delta}M{sub d} and {delta}M{sub s}. We find {xi}{identical_to}f{sub B{sub s}}{radical}(B-circumflex{sub B{sub s}})/f{sub B{sub d}}{radical}(B-circumflex{sub B{sub d}})=1.258(33), f{sub B{sub d}}{radical}(B-circumflex{sub B{sub d}})=216(15) MeV, and f{sub B{sub s}}{radical}(B-circumflex{sub B{sub s}})=266(18) MeV. We also update previous results for decay constants and obtain f{sub B{sub d}}=190(13) MeV, f{sub B{sub s}}=231(15) MeV, and f{sub B{sub s}}/f{sub B{sub d}}=1.226(26). The new lattice results lead to updated values for the ratio of Cabibbo-Kobayashi-Maskawa matrix elements |V{sub td}|/|V{sub ts}| and for the standard model prediction for Br(B{sub s}{yields}{mu}{sup +}{mu}{sup -}) with reduced errors. We determine |V{sub td}|/|V{sub ts}|=0.214(1)(5) and Br(B{sub s}{yields}{mu}{sup +}{mu}{sup -})=3.19(19)x10{sup -9}.

  4. Effects of gas injection condition on mixing efficiency in the ladle refining process

    SciTech Connect (OSTI)

    Pan, S.M.; Chiang, J.D.; Hwang, W.S.

    1997-02-01

    The aim of this research was to investigate the effects of injection condition on the mixing efficiency of the gas injection treatment of the ladle refining process in steelmaking. A water modeling approach was employed. A NaCl solution was injected into the vessel and the electric conductivity value of the water solution was measured to represent the concentration of the additive. The results of this investigation reveal that up to a certain level, mixing efficiency is improved as the gas flow rate increases. Off-center injection is better than centerline injection. However, the injection lance should not be too close to the wall. Also, mixing efficiency is improved when the submerged depth of the immersion lance increases. The immersion hood has a optimal size as far as mixing efficiency is concerned. A larger or smaller hood would reduce its efficiency. The submerged depth of the immersion hood should be kept to a minimum to improve mixing efficiency.

  5. Enhanced air/fuel mixing for automotive Stirling engine turbulator-type combustors

    SciTech Connect (OSTI)

    Riecke, G.T.; Stotts, R.E.

    1992-02-25

    This patent describes a combustor for use in a Stirling engine and the like. It comprises: a combustor chamber; a fuel inlet couple to the chamber to inject fuel therein; a turbulator means disposed in the chambers downstream of the fuel inlet means for injecting combustion air into the chamber, the turbulator means being so positioned to cause a mixing of the combustion air and fuel injected in the chamber; diverter means for dividing the combustion air and creating a primary mixing zone downstream fa the primary mixing zone; and wherein the primary mixing zone comprises a fuel rich zone where combustion initiates and the secondary mixing zone has sufficient combustion air to complete combustion of the fuel.

  6. NdBaFe{sub 2}O{sub 5+w} and steric effect of Nd on valence mixing and ordering of Fe

    SciTech Connect (OSTI)

    Linden, J.; Karen, P.

    2010-11-15

    NdBaFe{sub 2}O{sub 5} above and below Verwey transition is studied by synchrotron X-ray powder diffraction and Moessbauer spectroscopy and compared with GdBaFe{sub 2}O{sub 5} that adopts a higher-symmetry charge-ordered structure typical of the Sm-Ho variants of the title phase. Differences are investigated by Moessbauer spectroscopy accounting for iron valence states at their local magnetic and ionic environments. In the charge-ordered state, the orientation of the electric-field gradient (EFG) versus the internal magnetic field (B) agrees with experiment only when contribution from charges of the ordered d{sub xz} orbitals of Fe{sup 2+} is included, proving thus the orbital ordering. The EFG magnitude indicates that only some 60% of the orbital order occurring in the Sm-Ho variants is achieved in NdBaFe{sub 2}O{sub 5}. The consequent diminishing of the orbit contribution (of opposite sign) to the field B at the Fe{sup 2+} nucleus explains why B is larger than for the Sm-Ho variants. The decreased orbital ordering in NdBaFe{sub 2}O{sub 5} causes a corresponding decrease in charge ordering, which is achieved by decreasing both the amount of the charge-ordered iron states in the sample and their fractional valence separation as seen by the Moessbauer isomer shift. The charge ordering in NdBaFe{sub 2}O{sub 5+w} is more easily suppressed by the oxygen nonstoichiometry (w) than in the Sm-Ho variants. Also the valence mixing into Fe{sup 2.5+} is destabilized by the large size of Nd. The orientation of the EFG around this valence-mixed iron can only be accounted for when the valence-mixing electron is included in the electrostatic ligand field. This proves that the valence mixing occurs between the two iron atoms facing each other across the structural plane of the rare-earth atoms. -- Graphical Abstract: Moessbauer spectrum detects ordering of d{sub xz} orbitals of Fe{sup II}O{sub 5} via the electric-field gradient (EFG) of the orbital, which makes the main component of the total EFG parallel with the magnetic moment B. Display Omitted

  7. The Role of Cohesive Particle Interactions on Solids Uniformity and Mobilization During Jet Mixing: Testing Recommendations

    SciTech Connect (OSTI)

    Gauglitz, Phillip A.; Wells, Beric E.; Bamberger, Judith A.; Fort, James A.; Chun, Jaehun; Jenks, Jeromy WJ

    2010-04-01

    Radioactive waste that is currently stored in large underground tanks at the Hanford Site will be staged in selected double-shell tanks (DSTs) and then transferred to the Waste Treatment and Immobilization Plant (WTP). Before being transferred, the waste will be mixed, sampled, and characterized to determine if the waste composition and meets the waste feed specifications. Washington River Protection Solutions is conducting a Tank Mixing and Sampling Demonstration Program to determine the mixing effectiveness of the current baseline mixing system that uses two jet mixer pumps and the adequacy of the planned sampling method. The overall purpose of the demonstration program is to mitigate the technical risk associated with the mixing and sampling systems meeting the feed certification requirements for transferring waste to the WTP.The purpose of this report is to analyze existing data and evaluate whether scaled mixing tests with cohesive simulants are needed to meet the overall objectives of the small-scale mixing demonstration program. This evaluation will focus on estimating the role of cohesive particle interactions on various physical phenomena that occur in parts of the mixing process. A specific focus of the evaluation will be on the uniformity of suspended solids in the mixed region. Based on the evaluation presented in this report and the absence of definitive studies, the recommendation is to conduct scaled mixing tests with cohesive particles and augment the initial testing with non-cohesive particles. In addition, planning for the quantitative tests would benefit from having test results from some scoping experiments that would provide results on the general behavior when cohesive inter-particle forces are important.

  8. Evaluation of plastic materials for range shifting, range compensation, and solid-phantom dosimetry in carbon-ion radiotherapy

    SciTech Connect (OSTI)

    Kanematsu, Nobuyuki; Koba, Yusuke; Ogata, Risa

    2013-04-15

    Purpose: Beam range control is the essence of radiotherapy with heavy charged particles. In conventional broad-beam delivery, fine range adjustment is achieved by insertion of range shifting and compensating materials. In dosimetry, solid phantoms are often used for convenience. These materials should ideally be equivalent to water. In this study, the authors evaluated dosimetric water equivalence of four common plastics, high-density polyethylene (HDPE), polymethyl methacrylate (PMMA), polyethylene terephthalate (PET), and polyoxymethylene (POM). Methods: Using the Bethe formula for energy loss, the Gottschalk formula for multiple scattering, and the Sihver formula for nuclear interactions, the authors calculated the effective densities of the plastics for these interactions. The authors experimentally measured variation of the Bragg peak of carbon-ion beams by insertion of HDPE, PMMA, and POM, which were compared with analytical model calculations. Results: The theoretical calculation resulted in slightly reduced multiple scattering and severely increased nuclear interactions for HDPE, compared to water and the other plastics. The increase in attenuation of carbon ions for 20-cm range shift was experimentally measured to be 8.9% for HDPE, 2.5% for PMMA, and 0.0% for POM while PET was theoretically estimated to be in between PMMA and POM. The agreement between the measurements and the calculations was about 1% or better. Conclusions: For carbon-ion beams, POM was dosimetrically indistinguishable from water and the best of the plastics examined in this study. The poorest was HDPE, which would reduce the Bragg peak by 0.45% per cm range shift, although with marginal superiority for reduced multiple scattering. Between the two clear plastics, PET would be superior to PMMA in dosimetric water equivalence.

  9. NEPA REVIEW LASO-10-002 CATEGORICAL EXCLUSION PAJARITO ROAD RIGHT-OF-WAY SHIFT AT TA-50 AND TA-55

    National Nuclear Security Administration (NNSA)

    REVIEW LASO-10-002 CATEGORICAL EXCLUSION PAJARITO ROAD RIGHT-OF-WAY SHIFT AT TA-50 AND TA-55 1. DESCRIPTION OF PROPOSED ACTION: LANL proposes to shift a segment of Pajarito Road slightly to the south along the edge of Two-Mile Canyon in the vicinity of TA-55. The existing centerline would be moved between 36 feet and 56 feet depending on final designs. This shift would address the need to integrate security requirements related to the Chemistry and Metallurgy Building Replacement Project (CMRR)

  10. Parametric Gasification of Oak and Pine Feedstocks Using the TCPDU and Slipstream Water-Gas Shift Catalysis

    SciTech Connect (OSTI)

    Hrdlicka, J.; Feik, C.; Carpenter, D.; Pomeroy, M.

    2008-12-01

    With oak and pine feedstocks, the Gasification of Biomass to Hydrogen project maximizes hydrogen production using the Full Stream Reformer during water-gas shift fixed-bed reactor testing. Results indicate that higher steam-to-biomass ratio and higher thermal cracker temperature yield higher hydrogen concentration. NREL's techno-economic models and analyses indicate hydrogen production from biomass may be viable at an estimated cost of $1.77/kg (current) and $1.47/kg (advanced in 2015). To verify these estimates, NREL used the Thermochemical Process Development Unit (TCPDU), an integrated system of unit operations that investigates biomass thermochemical conversion to gaseous and liquid fuels and chemicals.

  11. DOE-STD-1041-93 CN-1; Guide to Good Practices for Shift Routines and Operating Practices

    Office of Environmental Management (EM)

    1-93 June 1998 Change Notice No. 1 December 1998 DOE STANDARD GUIDE TO GOOD PRACTICES FOR SHIFT ROUTINES AND OPERATING PRACTICES U.S. Department of Energy AREA MISC Washington, D.C. 20585 DISTRIBUTION STATEMENT A:Approved for public release; distribution unlimited. This document has been reproduced from the best available copy. Available to DOE and DOE contractors from ES&H Technical Information Services, U.S. Department of Energy, (800) 473-4375, fax: (301) 903-9823. Available to the public

  12. Spatial Heterogeneity and Imperfect Mixing in Chemical Reactions: Visualization of Density-Driven Pattern Formation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sobel, Sabrina G.; Hastings, Harold M.; Testa, Matthew

    2009-01-01

    Imore » mperfect mixing is a concern in industrial processes, everyday processes (mixing paint, bread machines), and in understanding salt water-fresh water mixing in ecosystems. The effects of imperfect mixing become evident in the unstirred ferroin-catalyzed Belousov-Zhabotinsky reaction, the prototype for chemical pattern formation. Over time, waves of oxidation (high ferriin concentration, blue) propagate into a background of low ferriin concentration (red); their structure reflects in part the history of mixing in the reaction vessel. However, it may be difficult to separate mixing effects from reaction effects. We describe a simpler model system for visualizing density-driven pattern formation in an essentially unmixed chemical system: the reaction of pale yellow Fe 3 + with colorless SCN − to form the blood-red Fe ( SCN ) 2 + complex ion in aqueous solution. Careful addition of one drop of Fe ( NO 3 ) 3 to KSCN yields striped patterns after several minutes. The patterns appear reminiscent of Rayleigh-Taylor instabilities and convection rolls, arguing that pattern formation is caused by density-driven mixing.« less

  13. Wave-mixing with high-order harmonics in extreme ultraviolet region

    SciTech Connect (OSTI)

    Dao, Lap Van; Dinh, Khuong Ba; Le, Hoang Vu; Gaffney, Naylyn; Hannaford, Peter

    2015-01-12

    We report studies of the wave-mixing process in the extreme ultraviolet region with two near-infrared driving and controlling pulses with incommensurate frequencies (at 1400 nm and 800 nm). A non-collinear scheme for the two beams is used in order to spatially separate and to characterise the properties of the high-order wave-mixing field. We show that the extreme ultraviolet frequency mixing can be treated by perturbative, very high-order nonlinear optics; the modification of the wave-packet of the free electron needs to be considered in this process.

  14. DEMONSTRATION OF MIXING AND TRANSFERRING SETTLING COHESIVE SLURRY SIMULANTS IN THE AY-102 TANK

    SciTech Connect (OSTI)

    Adamson, D.; Gauglitz, P.

    2012-01-03

    In support of Hanford's feed delivery of high level waste (HLW) to the Waste Treatment and Immobilization Plant (WTP), pilot-scale testing and demonstrations with simulants containing cohesive particles were performed as a joint collaboration between Savannah River National Laboratory (SRNL) and the Pacific Northwest National Laboratory (PNNL) staff. The objective of the demonstrations was to determine the impact that cohesive particle interactions in the simulants, and the resulting non-Newtonian rheology, have on tank mixing and batch transfer of large and dense seed particles. The work addressed the impacts cohesive simulants have on mixing and batch transfer performance in a pilot-scale system. Kaolin slurries with a range of wt% concentrations to vary the Bingham yield stress were used in all the non-Newtonian simulants. To study the effects of just increasing the liquid viscosity (no yield stress) on mixing and batch transfers, a glycerol/water mixture was used. Stainless steel 100 micron particles were used as seed particles due to their density and their contrasting color to the kaolin and glycerol. In support of Hanford's waste certification and delivery of tank waste to the Waste Treatment and Immobilization Plant (WTP), Savannah River National Laboratory (SRNL) was tasked by Washington River Protection Solutions (WRPS) to evaluate the effectiveness of mixing and transferring tank waste in a Double Shell Tank (DST) to the WTP Receipt Tank. The work addresses the impacts cohesive simulants have on mixing and batch transfer performance. This work is follow-on to the previous tasks 'Demonstration of Mixer Jet Pump Rotational Sensitivity on Mixing and Transfers of the AY-102 Tank' and 'Demonstration of Simulated Waste Transfers from Tank AY-102 to the Hanford Waste Treatment Facility'. The cohesive simulants were investigated and selected jointly by SRNL and PNNL and a white paper was written on this evaluation. The testing and demonstrations of cohesive simulants was a joint effort performed as collaboration between SRNL and PNNL staff. The objective of the demonstrations was to determine the impact that cohesive particle interactions in the simulants have on tank mixing using the 1/22nd scale mixing system and batch transfer of seed particles. Seed particles are particles of contracting color added to mixing tank for visual inspection and an indicator of how well the contents of the tank are mixing. Also the seed particles serve as a measuring stick for how well the contents of the tank are transferred from the mixing tank during batch transfers. This testing is intended to provide supporting evidence to the assumption that Hanford Small Scale Mixing Demonstration (SSMD) testing in water is conservative.

  15. Measurements of continuous mix evolution in a high energy density shear flow

    SciTech Connect (OSTI)

    Loomis, E. Doss, F.; Flippo, K.; Fincke, J.

    2014-04-15

    We report on the novel integration of streaked radiography into a counter-flowing High Energy Density (HED) shear environment that continually measures a growing mix layer of Al separating two low-density CH foams. Measurements of the mix width allow us to validate compressible turbulence models and with streaked imaging, make this possible with a minimal number of experiments on large laser facilities. In this paper, we describe how the HED counter-flowing shear layer is created and diagnosed with streaked radiography. We then compare the streaked data to previous two-dimensional, single frame radiography and radiation hydrodynamic simulations of the experiment with inline compressible turbulent mix models.

  16. Phase-mixing of electrostatic modes in a cold magnetized electron-positron plasma

    SciTech Connect (OSTI)

    Maity, Chandan; Chakrabarti, Nikhil

    2013-08-15

    In a fluid description, we study space-time evolution of electrostatic oscillations in a cold magnetized electron-positron plasma. Nonlinear results up to third order, obtained by employing a simple perturbation technique, indicate phase-mixing and thus breaking of excited oscillations, and provide an expression for the phase-mixing time. It is shown that an increase in the strength of ambient magnetic field results in an increase in the phase-mixing time. The results of our investigation will be of relevance to astrophysical environments as well as laboratory experiments.

  17. Complex catalytic behaviors of CuTiOx mixed-oxide during CO oxidation

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Complex catalytic behaviors of CuTiOx mixed-oxide during CO oxidation Citation Details In-Document Search This content will become publicly available on September 21, 2016 Title: Complex catalytic behaviors of CuTiOx mixed-oxide during CO oxidation Mixed metal oxides have attracted considerable attention in heterogeneous catalysis due to the unique stability, reactivity, and selectivity. Here, the activity and stability of the CuTiOx monolayer film

  18. COMPUTATIONAL FLUID DYNAMICS MODELING OF SCALED HANFORD DOUBLE SHELL TANK MIXING - CFD MODELING SENSITIVITY STUDY RESULTS

    SciTech Connect (OSTI)

    JACKSON VL

    2011-08-31

    The primary purpose of the tank mixing and sampling demonstration program is to mitigate the technical risks associated with the ability of the Hanford tank farm delivery and celtification systems to measure and deliver a uniformly mixed high-level waste (HLW) feed to the Waste Treatment and Immobilization Plant (WTP) Uniform feed to the WTP is a requirement of 24590-WTP-ICD-MG-01-019, ICD-19 - Interface Control Document for Waste Feed, although the exact definition of uniform is evolving in this context. Computational Fluid Dynamics (CFD) modeling has been used to assist in evaluating scaleup issues, study operational parameters, and predict mixing performance at full-scale.

  19. Impact of aerosol on mixed-phase stratocumulus during MPACE in a mesoscale

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    model with two-moment microphysics Impact of aerosol on mixed-phase stratocumulus during MPACE in a mesoscale model with two-moment microphysics Morrison, Hugh MMM/ASP National Center for Atmospheric Research Pinto, James University of Colorado Curry, Judith Georgia Institute of Technology Category: Modeling The Penn State/NCAR mesoscale model MM5 is coupled to a new microphysics scheme to examine the impact of aerosol on mixed-phase stratocumulus during the Mixed-Phase Arctic Stratus

  20. Relating B_S Mixing and B_S to mu+mu- with New Physics (Journal...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Relating BS Mixing and BS to mu+mu- with New Physics Citation Details In-Document Search Title: Relating BS Mixing and BS to mu+mu- with New Physics We perform...

  1. Relating B_S Mixing and B_S to mu+mu- with New Physics (Journal...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Relating BS Mixing and BS to mu+mu- with New Physics Citation Details In-Document Search Title: Relating BS Mixing and BS to mu+mu- with New Physics You are...

  2. Exciton diamagnetic shifts and valley Zeeman effects in monolayer WS2 and MoS2 to 65 Tesla

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stier, Andreas V.; McCreary, Kathleen M.; Jonker, Berend T.; Kono, Junichiro; Crooker, Scott A.

    2016-02-09

    In bulk and quantum-confined semiconductors, magneto-optical studies have historically played an essential role in determining the fundamental parameters of excitons (size, binding energy, spin, dimensionality and so on). Here we report low-temperature polarized reflection spectroscopy of atomically thin WS2 and MoS2 in high magnetic fields to 65 T. Both the A and B excitons exhibit similar Zeeman splittings of approximately –230 μeV T–1 (g-factor ≃–4), thereby quantifying the valley Zeeman effect in monolayer transition-metal disulphides. Crucially, these large fields also allow observation of the small quadratic diamagnetic shifts of both A and B excitons in monolayer WS2, from which radiimore » of ~1.53 and ~1.16 nm are calculated. Further, when analysed within a model of non-local dielectric screening, these diamagnetic shifts also constrain estimates of the A and B exciton binding energies (410 and 470 meV, respectively, using a reduced A exciton mass of 0.16 times the free electron mass). Lastly, these results highlight the utility of high magnetic fields for understanding new two-dimensional materials.« less

  3. Ultralow-threshold laser and blue shift cooperative luminescence in a Yb{sup 3+} doped silica microsphere

    SciTech Connect (OSTI)

    Huang, Yantang Huang, Yu; Zhang, Peijin; Guo, Changlei; Department of Electronic Engineering, Institute of Optoelectronic Technology, Xiamen University, Xiamen, 361005

    2014-02-15

    An experimental investigation on ultralow threshold laser and blue shift cooperative luminescence (CL) in a Yb{sup 3+} doped silica microsphere (YDSM) with continuous-wave 976 nm laser diode pumping is reported. The experimental results show that the YDSM emits laser oscillation with ultralow threshold of 2.62 ?W, and the laser spectrum is modulated by the microsphere morphology characteristics. In addition, blue emission of YDSM is also observed with the increase of pump power, which is supposed to be generated by CL of excited Yb ion-pairs with the absorption of 976 nm photons and Si-O vibration phonons, and the process is explained with an energy level diagram. This property of the blue shift CL with phonons absorption in the Yb{sup 3+}doped microcavity makes it attractive for the application of laser cooling based on anti-Stokes fluorescence emission, if the Yb{sup 3+}doped microcavity made from with low phonon energy host materials.

  4. Extracting Short Rise-Time Velocity Profiles with Digital Down-Shift Analysis of Optically Up-Converted PDV Data

    SciTech Connect (OSTI)

    Abel Diaz, Nathan Riley, Cenobio Gallegos, Matthew Teel, Michael Berninger, Thomas W. Tunnell

    2010-09-08

    This work describes the digital down-shift (DDS) technique, a new method of extracting short rise-time velocity profiles in the analysis of optically up-converted PDV data. The DDS technique manipulates the PDV data by subtracting a constant velocity (i.e., the DDS velocity ?DDS) from the velocity profile. DDS exploits the simple fact that the optically up-converted data ride on top of a base velocity (?0, the apparent velocity at no motion) with a rapid rise to a high velocity (?f) of a few km/s or more. Consequently, the frequency content of the signal must describe a velocity profile that increases from ?0 to ?0 + ?f. The DDS technique produces velocity reversals in the processed data before shock breakout when ?0 < ?DDS < ?0 + ?f. The DDS analysis process strategically selects specific DDS velocities (velocity at which the user down shifts the data) that produce anomalous reversals (maxima and/or minima), which are predictable and easy to identify in the mid-range of the data. Additional analysis determines when these maxima and minima occur. By successive application of the DDS technique and iterative analysis, velocity profiles are extracted as time as a function of velocity rather than as a function of time as it would be in a conventional velocity profile. Presented results include a description of DDS, velocity profiles extracted from laser-driven shock data with rise times of 200 ps or less, and a comparison with other techniques.

  5. Transition metal carbides, nitrides and borides, and their oxygen containing analogs useful as water gas shift catalysts

    DOE Patents [OSTI]

    Thompson, Levi T.; Patt, Jeremy; Moon, Dong Ju; Phillips, Cory

    2003-09-23

    Mono- and bimetallic transition metal carbides, nitrides and borides, and their oxygen containing analogs (e.g. oxycarbides) for use as water gas shift catalysts are described. In a preferred embodiment, the catalysts have the general formula of M1.sub.A M2.sub.B Z.sub.C O.sub.D, wherein M1 is selected from the group consisting of Mo, W, and combinations thereof; M2 is selected from the group consisting of Fe, Ni, Cu, Co, and combinations thereof; Z is selected from the group consisting of carbon, nitrogen, boron, and combinations thereof; A is an integer; B is 0 or an integer greater than 0; C is an integer; O is oxygen; and D is 0 or an integer greater than 0. The catalysts exhibit good reactivity, stability, and sulfur tolerance, as compared to conventional water shift gas catalysts. These catalysts hold promise for use in conjunction with proton exchange membrane fuel cell powered systems.

  6. Mixing of partial waves near B*B̄* threshold in e⁺e⁻ annihilation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Xin; Voloshin, M. B.

    2013-05-31

    We consider the production of B*B̄* meson pairs in e⁺e⁻ annihilation near the threshold. The rescattering due to pion exchange between the mesons results in a mixing between three partial wave amplitudes: two P-wave amplitudes with the total spin of the meson pair S=0 and S=2 and an F-wave amplitude. The mixing due to pion exchange with a low momentum transfer is calculable up to c.m. energy E≈15–20 MeV above the threshold. We find that the P–F mixing is numerically quite small in this energy range, while the mixing of the two P-wave amplitudes is rapidly changing with energy andmore » can reach of order one at such low energies.« less

  7. Vehicle Technologies Office Merit Review 2015: Mixed Polyanion (MP) Glasses as Cathode Materials

    Broader source: Energy.gov [DOE]

    Presentation given by Oak Ridge National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about mixed polyanion...

  8. EA-1135: Offsite Thermal Treatment of Low-level Mixed Waste, Richland, Washington

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts of the proposal to treat contact-handled low-level mixed waste, containing polychlorinated biphenyls and other organics, to meet existing regulatory...

  9. EA-1189: Non-thermal Treatment of Hanford Site Low-level Mixed Waste, Richland, Washington

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts for the proposal to demonstrate the feasibility of commercial treatment of contact-handled low-level mixed waste to meet existing Federal and State...

  10. EA-1292: On-site Treatment of Low Level Mixed Waste, Golden, Colorado

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts for the proposal to evaluate the proposed treatment of low level mixed waste at the U.S. Department of Energy's Rocky Flats Environmental Technology Site.

  11. EA-0820: Construction of Mixed Waste Storage RCRA Facilities, Buildings 7668 and 7669, Oak Ridge, Tennessee

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts of a proposal to construct and operate two mixed (both radioactive and hazardous) waste storage facilities (Buildings 7668 and 7669) in accordance with...

  12. Coalescent 4 wave frequency mixing in a plasma, applied to plasma diagnosis

    SciTech Connect (OSTI)

    Quande, Z.

    1982-09-01

    It is demonstrated that it is possible to use continuous infrared lasers of relatively low power as the source for frequency mixing in a continuous wave diagnosis of a plasma.

  13. Phase-mixing of Langmuir oscillations in cold electron-positron-ion plasmas

    SciTech Connect (OSTI)

    Maity, Chandan

    2014-07-15

    Space-time evolution of Langmuir oscillations in a cold homogeneous electron-positron-ion plasma has been analyzed by employing a straightforward perturbation expansion method, showing phase-mixing and, thus, wave-breaking of excited oscillations at arbitrary amplitudes. Within an assumption of infinitely massive ions, an approximate phase-mixing time is found to scale as ?{sub pe}t{sub mix}?[(6/?{sup 2})((2??){sup 5/2}/(1??))]{sup 1/3}, where ? and ? (= n{sub 0i}/n{sub 0e}) are the amplitude of perturbation and the ratio of equilibrium ion density to equilibrium electron density, respectively, and ?{sub pe}??(4?n{sub 0e}e{sup 2}/m) is the electron plasma frequency. The results presented on phase-mixing of Langmuir modes in multispecies plasmas are expected to be relevant to laboratory and astrophysical environments.

  14. Mixed axion/gravitino dark matter from SUSY models with heavy...

    Office of Scientific and Technical Information (OSTI)

    Title: Mixed axiongravitino dark matter from SUSY models with heavy axinos Authors: Bae, Kyu Jung ; Baer, Howard ; Chun, Eung Jin ; Shin, Chang Sub Publication Date: 2015-04-14 ...

  15. Mixing in thermally stratified nonlinear spin-up with uniform boundary fluxes

    SciTech Connect (OSTI)

    Baghdasarian, Meline; Pacheco-Vega, Arturo; Pacheco, J. Rafael; Verzicco, Roberto

    2014-09-15

    Studies of stratified spin-up experiments in enclosed cylinders have reported the presence of small pockets of well-mixed fluids but quantitative measurements of the mixedness of the fluid has been lacking. Previous numerical simulations have not addressed these measurements. Here we present numerical simulations that explain how the combined effect of spin-up and thermal boundary conditions enhances or hinders mixing of a fluid in a cylinder. The energy of the system is characterized by splitting the potential energy into diabatic and adiabatic components, and measurements of efficiency of mixing are based on both, the ratio of dissipation of available potential energy to forcing and variance of temperature. The numerical simulations of the NavierStokes equations for the problem with different sets of thermal boundary conditions at the horizontal walls helped shed some light on the physical mechanisms of mixing, for which a clear explanation was absent.

  16. Computational and experimental studies of hydrodynamic instabilities and turbulent mixing (Review of NVIIEF efforts)

    SciTech Connect (OSTI)

    Andronov, V.A.; Zhidov, I.G.; Meskov, E.E.; Nevmerzhitskii, N.V.; Nikiforov, V.V.; Razin, A.N.; Rogatchev, V.G.; Tolshmyakov, A.I.; Yanilkin, Yu.V.

    1995-02-01

    This report describes an extensive program of investigations conducted at Arzamas-16 in Russia over the past several decades. The focus of the work is on material interface instability and the mixing of two materials. Part 1 of the report discusses analytical and computational studies of hydrodynamic instabilities and turbulent mixing. The EGAK codes are described and results are illustrated for several types of unstable flow. Semiempirical turbulence transport equations are derived for the mixing of two materials, and their capabilities are illustrated for several examples. Part 2 discusses the experimental studies that have been performed to investigate instabilities and turbulent mixing. Shock-tube and jelly techniques are described in considerable detail. Results are presented for many circumstances and configurations.

  17. Technical area status report for low-level mixed waste final waste forms. Volume 2, Appendices

    SciTech Connect (OSTI)

    Mayberry, J.L.; Huebner, T.L.; Ross, W.; Nakaoka, R.; Schumacher, R.; Cunnane, J.; Singh, D.; Darnell, R.; Greenhalgh, W.

    1993-08-01

    This report presents information on low-level mixed waste forms.The descriptions of the low-level mixed waste (LLMW) streams that are considered by the Mixed Waste Integrated Program (MWIP) are given in Appendix A. This information was taken from descriptions generated by the Mixed Waste Treatment Program (MWTP). Appendix B provides a list of characteristic properties initially considered by the Final Waste Form (FWF) Working Group (WG). A description of facilities available to test the various FWFs discussed in Volume I of DOE/MWIP-3 are given in Appendix C. Appendix D provides a summary of numerous articles that were reviewed on testing of FWFS. Information that was collected by the tests on the characteristic properties considered in this report are documented in Appendix D. The articles reviewed are not a comprehensive list, but are provided to give an indication of the data that are available.

  18. Gas adsorption and gas mixture separations using mixed-ligand MOF material

    DOE Patents [OSTI]

    Hupp, Joseph T. (Northfield, IL); Mulfort, Karen L. (Chicago, IL); Snurr, Randall Q. (Evanston, IL); Bae, Youn-Sang (Evanston, IL)

    2011-01-04

    A method of separating a mixture of carbon dioxiode and hydrocarbon gas using a mixed-ligand, metal-organic framework (MOF) material having metal ions coordinated to carboxylate ligands and pyridyl ligands.

  19. Mixed Waste Management Facility Preliminary Safety Analysis Report. Chapters 1 to 20

    SciTech Connect (OSTI)

    Not Available

    1994-09-01

    This document provides information on waste management practices, occupational safety, and a site characterization of the Lawrence Livermore National Laboratory. A facility description, safety engineering analysis, mixed waste processing techniques, and auxiliary support systems are included.

  20. Hanford Site annual dangerous waste report: Volume 4, Waste Management Facility report, Radioactive mixed waste

    SciTech Connect (OSTI)

    1994-12-31

    This report contains information on radioactive mixed wastes at the Hanford Site. Information consists of shipment date, physical state, chemical nature, waste description, handling method and containment vessel, waste number, waste designation and amount of waste.