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Note: This page contains sample records for the topic "mineral gadolinite ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

EMSL - minerals  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

minerals en Reorientation of the ‘free OH’ group in the top-most layer of airwater interface of sodium fluoride aqueous http:www.emsl.pnl.govemslwebpublications...

2

* Phys 222 may be substituted for Chem 178/178L ** CE 460 may be substituted for CE 333 or CE 334  

E-Print Network [OSTI]

(Structural Analysis I) 3 CE 372 (Engr Hydro & Hydraulics) 3 CE 360 (Geotechnical Engineering) 3 CE 382 (Engr Hydro & Hydraulics) 3 CE 355 (Transportation Engr) 3 CE 382 (Design of Concretes) 3 CE 326 Design) 3 Numerical Analysis Elective 3 CE 485 (CE Design I) 2 Micro 201 (General Microbiology) 3 Engr

Lin, Zhiqun

3

2011 Minerals Yearbook U.S. Department of the Interior  

E-Print Network [OSTI]

); Oil-dri Corp. of america (fuller's earth); Texas Industries, Inc. (common clay and shale); Thiele2011 Minerals Yearbook U.S. Department of the Interior U.S. Geological Survey CLAY AND SHALE [ADVANCE RELEASE] May 2013 #12;Clay and Shale--2011 [adVanCe ReleaSe] 18.1 Clay and Shale By Robert l

4

Update: Proposed CE Curriculum & Program  

E-Print Network [OSTI]

Update: Proposed CE Curriculum & Program Bruce Jacob, End of Summer 2008 #12;What's all this, then, students, graduates · Held constituents' meeting over winter · Group vote this curriculum Barua has agreed to develop and teach the course ENEE 3xx (Digital systems) -- new course Bruce Jacob

Jacob, Bruce

5

College of Engineering CE Civil Engineering  

E-Print Network [OSTI]

College of Engineering CE Civil Engineering KEY: # = new course * = course changed = course.Lecture,twohours;laboratory,fourhoursperweek.Prereqorcoreq:MA113orconsentofinstructor. CE 120 INTRODUCTION TO CIVIL ENGINEERING. (1) An introduction to the civil engineering profession and the use of computer hardware and software in CE systems analysis and design

MacAdam, Keith

6

CE Geothermal | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin: EnergyBoston Areais3: Crystalline Rock - Basement JumpGeneral: CDOT Name: CE

7

International Refrigeration: Order (2012-CE-1510) | Department...  

Broader source: Energy.gov (indexed) [DOE]

Refrigeration: Order (2012-CE-1510) July 20, 2012 DOE ordered International Refrigeration Products to pay an 8,000 civil penalty after finding International Refrigeration had...

8

Table 1. Connection of Criterion 8 CE Outcomes to CE Courses (required, design elective, advanced elective)  

E-Print Network [OSTI]

treatment Biological wastewater treatment (d) Proficiency in Water Resources Engineering CE 3305 CE 3354 CE systems Design of advance water treatment systems Design of biological wastewater treatment systems (g ENVE 4391 ENVE 4399 Water, wastewater, air, solid waste Physical and chemical treatment Advanced water

Gelfond, Michael

9

Thermoelectric Couple Demonstration of (In, Ce)-based Skutterudite...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Couple Demonstration of (In, Ce)-based Skutterudite Materials for Automotive Energy Recovery Thermoelectric Couple Demonstration of (In, Ce)-based Skutterudite Materials for...

10

Lumiram Electric: Order (2010-CE-1014) | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Lumiram Electric: Order (2010-CE-1014) Lumiram Electric: Order (2010-CE-1014) November 23, 2010 DOE issued an Order and entered into a Compromise Agreement with Lumiram Electric...

11

MINERAL COUNTY COMMISSIONERS  

Broader source: Energy.gov (indexed) [DOE]

S.W. Washington, DC 20585 Dear Sirs: Attached are the comments for modification of the Price-Anderson Act Notice of Inquiry(NOI) provided to the Board of Mineral County...

12

ADVISER ROOM # EMAIL ADDRESS Adams 221 COBH (eda@ce.montana.edu)  

E-Print Network [OSTI]

, Michael L. Adams Senior CE Betcher, Jacob M. Lewandowski Freshman CE Bigelow, Adam J. (F 11) Larsson Sophomore CE Deen, Michael Perkins Junior CE Devoe, Colleen L. (1st deg Arch) Larsson Sophomore CE #12;DeWitt

Dyer, Bill

13

Engineering and Mineral Resources  

E-Print Network [OSTI]

News ????????????????? ® College of Engineering and Mineral Resources Winter 2008 table of contents. . . . . . . . . . . . . . . . . . . . 7 wvCROSSROADS DepartmentofCivilandEnvironmentalEngineering Civil engineering exchange program and environmental engineering with a focus in transportation will have the opportunity to study abroad as part

Mohaghegh, Shahab

14

Mineral Rights and Proceeds (Nebraska)  

Broader source: Energy.gov [DOE]

This section contains provisions which determine when mineral rights are presumed to be abandoned by property owners.

15

Comparison of CeBr3 with LaBr3:Ce, LaCl3:Ce, and NaI:Tl Detectors  

SciTech Connect (OSTI)

Energy resolution and detection efficiency were compared between two sizes of cerium bromide (CeBr3) scintillators, three sizes of lanthanum bromide (LaBr3:Ce) scintillators, three sizes of sodium iodide (NaI:Tl) scintillators, and a lanthanum chloride (LaCl3:Ce) scintillator. Comparisons are made of key parameters such as energy resolution, detection efficiency, linearity, and self-activity of CeBr3, LaBr3:Ce, LaCl3:Ce, and NaI:Tl scintillator detectors. The scintillator detectors are tested by comparing the peak separation and identification in the energy range up to 3.0 MeV using 133Ba, 152Eu, and naturally occurring radioactive materials [1]. The study has shown that CeBr3 scintillator detectors provided by Saint-Gobain offer better resolution than NaI:Tl scintillator detectors. CeBr3 detectors could resolve some closely spaced peaks from 133Ba and 152Eu, which NaI:Tl could not. LaBr3:Ce has slightly better resolution, and a slightly higher efficiency than CeBr3. In this work, “self-activity” of each of these four detector types was measured by operating the detectors themselves. A comparison of the intrinsic activity for all of the detectors in this study is demonstrated. For CeBr3, the self-activity present may be reduced, or even eliminated in the future, through improved processes for growing the material. It will be discussed if, and under what conditions, CeBr3 may be better than LaBr3:Ce and LaCl3:Ce for detection of certain special nuclear material ?-rays [2]. An overall advantage of CeBr3 detectors over lanthanum halide and NaI:Tl detectors will be discussed.

,

2010-09-01T23:59:59.000Z

16

CIVIL ENGINEERING PREREQUISITE SUMMARY Note: BSCE candidate means that you have been admitted to upper division. CE enrolled means you are listed  

E-Print Network [OSTI]

3316 Transportation Engineering BSCE cand. CE 3426 Soil Mechanics CE 2425, CE 2017, BSCE cand. CE 4096 & Engineering Drawing CE 2017 CE 3016 Surveying Math 1297 CE 3025 Environmental Engineering Chem 1151 or 1153 and 1154, CE 3221, BSCE cand. CE 3026 Project Management None CE 3027 Infrastructure Materials CE 2017

Levinson, David M.

17

American Power: Order (2010-CE-0911) | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Power: Order (2010-CE-0911) American Power: Order (2010-CE-0911) October 5, 2010 DOE issued an Order and entered into a Compromise Agreement with American Power Solutions, Inc....

18

rtino is prof of Cyber Ce  

E-Print Network [OSTI]

Program Technolo Worksho Bertino is Compute systems Compute to secure rtino is prof of Cyber Ce internatio Database Indexing Intelligen Services the Very on the e Security& on Web, Program VLDB, A Data Eng distributed fessor of Co enter and R nce and Se mputer Scien EC laborator maden) in S ers Universi arch

Holland, Jeffrey

19

CeBiTec Symposium Molecular Biotechnology  

E-Print Network [OSTI]

F), Bielefeld University April 3 ­ 4, 2014 PROGRAMME Thursday, April 3rd, 2014 11:00 Registration / Snacks 12:00 Opening remarks Volker F. Wendisch, Bielefeld University, Germany Welcome addresses Martin Egelhaaf (Vice.N. (University of Paderborn) Introduction to the CeBiTec Thomas Noll, Bielefeld University, Germany Session I

Moeller, Ralf

20

CE 473/573 Groundwater Course information  

E-Print Network [OSTI]

. Groundwater modeling 4.1. Introduction to finite-difference models 4.2. Models of groundwater flow 4.3. ModelsCE 473/573 Groundwater Fall 2011 Course information Instructor: Prof. Chris Rehmann rehmann of water and contaminants in groundwater systems to solve problems of groundwater resource evaluation

Rehmann, Chris

Note: This page contains sample records for the topic "mineral gadolinite ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

CE 473/573 Groundwater Course information  

E-Print Network [OSTI]

-reactive and reactive contaminants 4. Groundwater modeling 4.1. Introduction to finite-difference models 4.2. Models of groundwater flow 4.3. Models of contaminant transport 4.4. Available models #12;Recommended textbooks FetterCE 473/573 Groundwater Fall 2009 Course information Instructor: Prof. Chris Rehmann rehmann

Rehmann, Chris

22

SPRING 2013 CEE COURSES: v7 rev: 11/08/12 TRANSPORTATION PLANNING as CE 4410 & CE 6410  

E-Print Network [OSTI]

options for urban transport. After a student registers for CE 4410 or CE WATER MARKETS with Brian Richter and Professor Culver as CE 6500 The utility. This project course will enable us to identify what works best, and how to avoid

Acton, Scott

23

Anchoring Sites for Initial Au Nucleation on CeO2{111}: O Vacancy versus Ce Vacancy Changjun Zhang,  

E-Print Network [OSTI]

Anchoring Sites for Initial Au Nucleation on CeO2{111}: O Vacancy versus Ce Vacancy Changjun Zhang is a matter of debate. Both oxygen and cerium vacancies have been suggested as the anchoring sites initio thermodynamics approaches to investigate the formation of various vacancies at a CeO2{111} surface

Alavi, Ali

24

Investigation of Mineral Transformations in Wet Supercritical...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mineral Transformations in Wet Supercritical CO2 by Electron Microscopy. Investigation of Mineral Transformations in Wet Supercritical CO2 by Electron Microscopy. Abstract: The...

25

Universal ripper miner  

DOE Patents [OSTI]

A universal ripper miner used to cut, collect and transfer material from an underground mine working face includes a cutter head that is vertically movable in an arcuate cutting cycle by means of drive members, such as hydraulically actuated pistons. The cutter head may support a circular cutter bit having a circular cutting edge that may be indexed to incrementally expose a fresh cutting edge. An automatic indexing system is disclosed wherein indexing occurs by means of a worm gear and indexing lever mechanism. The invention also contemplates a bi-directional bit holder enabling cutting to occur in both the upstroke and the downstroke cutting cycle. Another feature of the invention discloses multiple bits arranged in an in-line, radially staggered pattern, or a side-by-side pattern to increase the mining capacity in each cutting cycle. An on-board resharpening system is also disclosed for resharpening the cutting edge at the end of cutting stroke position. The aforementioned improvement features may be used either singly, or in any proposed combination with each other.

Morrell, Roger J. (Bloomington, MN); Larson, David A. (Minneapolis, MN)

1991-01-01T23:59:59.000Z

26

CeCap LLP | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of InspectorConcentrating SolarElectricEnergyCTBarreis aCallahanWindSyracuse, NY JumpKS"Cayucos,CeCap LLP

27

CIVIL ENGINEERING Prerequisite Summary Note: BSCE candidate means that you have been admitted to upper division. CE enrolled means you are listed with  

E-Print Network [OSTI]

, Math 3280 (conc), BSCE cand. CE 3316 Transportation Engineering BSCE cand. CE 3426 Soil Mechanics CE & Engineering Drawing CE 2017, BSCE cand. CE 3016 Surveying Math 1297, BSCE cand. CE 3025 Environmental Engineering Chem 1151 or 1153 and 1154, CE 3221, BSCE cand. CE 3026 Project Management BSCE cand. CE 3027

Levinson, David M.

28

Universitt Bielefeld Centrum fr Biotechnologie -CeBiTec  

E-Print Network [OSTI]

for the development of algal biotechnology Center for Interdisciplinary Research (ZiF), Bielefeld University, Germany September 21 ­ 24, 2014 The Center for Biotechnology (CeBiTec) of Bielefeld University cordially invites you include The 2014 International CeBiTec Research Conference aims to give a complete overview

Moeller, Ralf

29

A List of Kansas Minerals  

E-Print Network [OSTI]

that mineral occurs. I t i s a i found associated with A n g l e s i t e t I t i s reported from Cherokee county. C e l e s t i t e (720). Orthorhombic, composition strontium sulphate Sr S0*j. This mineral has been found q u i t e s p a r i n g l y i n...Master Th e s i s Geology Grov e r , C h a r l e s H. 1895 L i s t of Kansas m i n e r a l s * A l i s t of Kansas Minerals with "brief notes on the^cr^stjalogr&phio (form, chemical composition, and the p r i n c i p a l l o c a l i t i e s f...

Grover, Charles H.

1895-01-01T23:59:59.000Z

30

Minerals handbook 1984/1985  

SciTech Connect (OSTI)

This handbook consists of statistical tables giving a profile of almost 50 strategic minerals. A compendium of statistics on reserves, production, and trade, the book provides a view of international supply and demand. Information is complied here which is otherwise available only through scattered sources. The 1984/1985 edition has been updated and expanded. Reserves have been recalculated on the new basis instituted by the United States. Seven new minerals have been added: arsenic, berrylium, bismuth, boron, gallium, rare earths, and tellurium. Growth rates of consumption have been extended and the section on end use of patterns for each mineral now shows the percentage for Europe and Japan as well as the U.S.

Crowson, P.

1985-01-01T23:59:59.000Z

31

Synthesis and structure of nanocrystalline mixed Ce–Yb silicates  

SciTech Connect (OSTI)

Graphical abstract: - Highlights: • New method of synthesis of nanocrystalline mixed lanthanide silicates is proposed. • Formation of A-type (Ce{sub 1?y}Yb{sub y}){sub 2}Si{sub 2}O{sub 7} in well dispersed Ce{sub 1?x}Yb{sub x}O{sub 2?(x/2)}–SiO{sub 2} system. • Formation of Yb{sub y}Ce{sub 9.33?y}(SiO{sub 4}){sub 6}O{sub 2} in agglomerated Ce{sub 1?x}Yb{sub x}O{sub 2?(x/2)}–SiO{sub 2} system. - Abstract: This work presents results of studies on synthesis and structure of mixed, nanocrystalline Ce–Yb silicates. Using TEM, XRD and FTIR we showed that heat treatment of nanocrystalline Ce{sub 1?x}Yb{sub x}O{sub 2?(x/2)} (x = 0.3, 0.5) mixed oxide supported on amorphous silica in reducing atmosphere, results in formation of Ce–Yb mixed silicates. Dispersion of the oxide on the silica surface and thus a local lanthanide/Si atomic ratio determines the stoichiometry of the silicate. Oxide crystallites uniformly dispersed on the silica surface transformed into A-(Ce{sub 1?y}Yb{sub y}){sub 2}Si{sub 2}O{sub 7} disilicate, while the agglomerated nanoparticles converted into Yb{sub y}Ce{sub 9.33?y}(SiO{sub 4}){sub 6}O{sub 2} oxyapatite silicate as an intermediate phase.

Ma?ecka, Ma?gorzata A., E-mail: M.Malecka@int.pan.wroc.pl; K?pi?ski, Leszek

2013-07-15T23:59:59.000Z

32

Mineral County Secondary Data Analysis  

E-Print Network [OSTI]

prevalence (Heart Attack) 4.0% 4.1% 6.0% All Sites Cancer 466.5 455.5 543.2 1 Community Health Data, MT2 1. Cancer 2. Heart Disease 3. Unintentional Injuries**, CLRD*, Cerebrovascular Disease 1. Cancer 2. Heart Disease 3.CLRD* 1. Heart Disease 2. Cancer 3. CLRD* #12; Mineral County

Maxwell, Bruce D.

33

2006 Minerals Yearbook RARE EARTHS  

E-Print Network [OSTI]

parts per million (ppm), to thulium and lutetium, the least abundant rare-earth elements at about 0 and malleable, similar in density to titanium. The elemental forms of rare earths are iron gray to silvery2006 Minerals Yearbook RARE EARTHS U.S. Department of the Interior U.S. Geological Survey May 2008

34

Institute for Mineral and Energy  

E-Print Network [OSTI]

. The University of Adelaide is unique within Australia for its strong research and teaching groups in geology fields of research are: · Earth Sciences ­ geology; geochemistry; geo-sequestration; geophysics to 10 per cent per annum while other minerals such as uranium and rare earth elements will become

35

LOW TEMPERATURE GEOTHERMAL MINERAL RECOVERY PROGRAM 02/11/2014...  

Energy Savers [EERE]

LOW TEMPERATURE GEOTHERMAL MINERAL RECOVERY PROGRAM 02112014 LOW TEMPERATURE GEOTHERMAL MINERAL RECOVERY PROGRAM 02112014 mineral-webinar.pdf More Documents & Publications LOW...

36

Ferromagnetism in chemically synthesized CeO2 nanoparticles by...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

by Ni doping. Ferromagnetism in chemically synthesized CeO2 nanoparticles by Ni doping. Abstract: This work reports the discovery of room-temperature ferromagnetism in 5 - 9 nm...

37

Mineral Supplementation of Beef Cows in Texas  

E-Print Network [OSTI]

Nutrient balance is the key to any effective nutrition program, especially where trace minerals are concerned. Many factors cannot be optimized when mineral intake is not properly balanced. Recommendations are given for the producer....

Herd, Dennis B.

1997-06-04T23:59:59.000Z

38

Mineral Transformation and Biomass Accumulation Associated With  

E-Print Network [OSTI]

Mineral Transformation and Biomass Accumulation Associated With Uranium Bioremediation at Rifle transformation and biomass accumulation, both of which can alter the flow field and potentially bioremediation to understand the biogeochemical processes and to quantify the biomass and mineral transformation/ accumulation

Hubbard, Susan

39

Remote Sensing of Soils, Minerals, and Geomorphology  

E-Print Network [OSTI]

,Remote Sensing of Soils, Minerals, and GeomorphologyMinerals, and Geomorphology · Soil is unconsolidated material). ·· SoilSoil is unconsolidated material at the surface of the Earth thatis unconsolidated material

40

Ca2+-Doped CeBr3 Scintillating Materials  

SciTech Connect (OSTI)

Despite the outstanding scintillation performance characteristics of cerium tribromide (CeBr3) and cerium-activated lanthanum tribromide, their commercial availability and application are limited due to the difficulties of growing large, crack-free single crystals from these fragile materials. This investigation employed aliovalent doping to increase crystal strength while maintaining the optical properties of the crystal. One divalent dopant (Ca2+) was used as a dopant to strengthen CeBr3 without negatively impacting scintillation performance. Ingots containing nominal concentrations of 1.9% of the Ca2+ dopant were grown. Preliminary scintillation measurements are presented for this aliovalently doped scintillator. Ca2+-doped CeBr3 exhibited little or no change in the peak fluorescence emission for 371 nm optical excitation for CeBr3. The structural, electronic, and optical properties of CeBr3 crystals were studied using the density functional theory within the generalized gradient approximation. The calculated lattice parameters are in good agreement with the experimental data. The energy band structures and density of states were obtained. The optical properties of CeBr3, including the dielectric function, were calculated.

Guss, Paul [NSTec; Foster, Michael E. [SNL; Wong, Bryan M. [SNL; Doty, F. Patrick [SNL; Shah, Kanai [RMD; Squillante, Michael R. [RMD; Shirwadkar, Urmila [RMD; Hawrami, Rastgo [RMD; Tower, Josh [RMD; Yuan, Ding [NSTec

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mineral gadolinite ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Effects of CeO2 Support Facets on VOx/CeO2 Catalysts in Oxidative...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

The higher activity for VOxCeO2(110) might be related to the more abundant oxygen vacancies present on the (110) facets, evidenced from Raman spectroscopic measurements....

42

Mineral Resource Information System for Field Lab in the Osage Mineral Reservation Estate  

SciTech Connect (OSTI)

The Osage Mineral Reservation Estate is located in Osage County, Oklahoma. Minerals on the Estate are owned by members of the Osage Tribe who are shareholders in the Estate. The Estate is administered by the Osage Agency, Branch of Minerals, operated by the U.S. Bureau of Indian Affairs (BIA). Oil, natural gas, casinghead gas, and other minerals (sand, gravel, limestone, and dolomite) are exploited by lessors. Operators may obtain from the Branch of Minerals and the Osage Mineral Estate Tribal Council leases to explore and exploit oil, gas, oil and gas, and other minerals on the Estate. Operators pay a royalty on all minerals exploited and sold from the Estate. A mineral Resource Information system was developed for this project to evaluate the remaining hydrocarbon resources located on the Estate. Databases on Microsoft Excel spreadsheets of operators, leases, and production were designed for use in conjunction with an evaluation spreadsheet for estimating the remaining hydrocarbons on the Estate.

Carroll, H.B.; Johnson, William I.

1999-04-27T23:59:59.000Z

43

Homoleptic Ce(III) and Ce(IV) Nitroxide Complexes: Significant Stabilization of the 4+ Oxidation State  

SciTech Connect (OSTI)

Electrochemical experiments performed on the complex Ce-IV[2-((BuNO)-Bu-t)py](4), where [2-((BuNO)-Bu-t)py](-) = N-tert-butyl-N-2-pyridylnitroxide, indicate a 2.51 V stabilization of the 4+ oxidation state of Ce compared to [(Bu4N)-Bu-n](2)[Ce(NO3)(6)] in acetonitrile and a 2.95 V stabilization compared to the standard potential for the ion under aqueous conditions. Density functional theory calculations suggest that this preference for the higher oxidation state is a result of the tetrakis(nitroxide) ligand framework at the Ce cation, which allows for effective electron donation into, and partial covalent overlap with, vacant 4f orbitals with delta symmetry. The results speak to the behavior of CeO2 and related solid solutions in oxygen uptake and transport applications, in particular an inherent local character of bonding that stabilizes the 4+ oxidation state. The results indicate a cerium(IV) complex that has been stabilized to an unprecedented degree through tuning of its ligand-field environment.

Bogart, Justin A.; Lewis, Andrew J.; Medling, Scott A.; Piro, Nicholas A.; Carroll, Patrick J.; Booth, Corwin H.; Schelter, Eric J.

2014-06-25T23:59:59.000Z

44

Mineral Test Hole Regulatory Act (Tennessee)  

Broader source: Energy.gov [DOE]

The Mineral Hole Regulatory Act is applicable to any person (individual, corporation, company, association, joint venture, partnership, receiver, trustee, guardian, executor, administrator,...

45

Minerals and Mining Program (South Dakota)  

Broader source: Energy.gov [DOE]

The Minerals and Mining Program has the authority to oversee mining activities in the state and issue regulations pertaining to the permitting and environmental impact mitigation of, and...

46

Luminescence Enhancement of CdTe Nanostructures in LaF3:Ce/CdTe...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Enhancement of CdTe Nanostructures in LaF3:CeCdTe Nanocomposites. Luminescence Enhancement of CdTe Nanostructures in LaF3:CeCdTe Nanocomposites. Abstract: Radiation detection...

47

The suburban villa (munya) and court culture in Umayyad Cordoba (756-976 CE)  

E-Print Network [OSTI]

As the capital of the Umayyad dynasty (r. 756 CE-1031 CE), the city of Cordoba developed into one of the most renowned urban centers of the western Mediterranean. The Great Mosque of Cordoba is the outstanding testament ...

Anderson, Glaire D

2005-01-01T23:59:59.000Z

48

CE 467 / 567 HIGHWAY SAFETY AND OPERATIONS Fall 2006 Course Syllabus  

E-Print Network [OSTI]

1 CE 467 / 567 HIGHWAY SAFETY AND OPERATIONS Fall 2006 Course Syllabus Catalog This course of class) #12;2 CE 467 / 567 HIGHWAY SAFETY AND OPERATIONS Fall 2006 Course Syllabus Course Outline: What

Hickman, Mark

49

E-Print Network 3.0 - allanita-ce vinculadas al Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

allanita-ce vinculadas al Search Powered by Explorit Topic List Advanced Search Sample search results for: allanita-ce vinculadas al Page: << < 1 2 3 4 5 > >> 1 Elena Garrigs Mic,...

50

CE FLNG, LLC - FE DKT. NO. 12-123-LNG - ORDER 3193 | Department...  

Broader source: Energy.gov (indexed) [DOE]

CE FLNG, LLC - FE DKT. NO. 12-123-LNG - ORDER 3193 CE FLNG, LLC - FE DKT. NO. 12-123-LNG - ORDER 3193 No reports submitted for this docket. More Documents & Publications...

51

Proactive Design of n-Type (In, Ce) Filled Skutterudites Enabling...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Design of n-Type (In, Ce) Filled Skutterudites Enabling High-Temperature Waste Heat Recovery Proactive Design of n-Type (In, Ce) Filled Skutterudites Enabling High-Temperature...

52

Magnetic structures and interplay between rare-earth Ce and Fe magnetism in single-crystal CeFeAsO  

SciTech Connect (OSTI)

Neutron and synchrotron resonant x-ray magnetic scattering (RXMS) complemented by heat capacity and resistivity measurements reveal the evolution of the magnetic structures of Fe and Ce sublattices in a CeFeAsO single crystal. The RXMS of magnetic reflections at the Ce LII edge shows a magnetic transition that is specific to the Ce antiferromagnetic long-range ordering at TCe? 4 K with short-range Ce ordering above TCe, whereas neutron diffraction measurements of a few magnetic reflections indicate a transition at T?? 12 K with an unusual order parameter. Detailed order-parameter measurements on several magnetic reflections by neutrons show a weak anomaly at 4 K that we associate with the Ce ordering. The successive transitions at TCe and T? can also be clearly identified by two anomalies in heat capacity and resistivity measurements. The higher transition temperature at T?? 12 K is mainly ascribed to Fe spin reorientation transition, below which Fe spins rotate uniformly and gradually in the ab plane. The Fe spin reorientation transition and short-range Ce ordering above TCe reflect the strong Fe-Ce couplings prior to long-range ordering of the Ce. The evolution of the intricate magnetic structures in CeFeAsO going through T? and TCe is proposed.

Zhang, Qiang [Ames Laboratory; Tian, Wei [Ames Laboratory; Li, Haifeng [Ames Laboratory; Kim, Jong-Woo [Argonne Naitonal Laboratory; Yan, Jiaqiang [Ames Laboratory; McCallum, Robert William [Ames Laboratory; Lograsso, Thomas A. [Ames Laboratory; Zarestky, Jerel L. [Ames Laboratory; Budko, Sergey L. [Ames Laboratory; McQueeney, Robert J. [Ames Laboratory; Vaknin, David [Ames Laboratory

2013-11-27T23:59:59.000Z

53

ue Ce ec o o es o a Energy Efficiency &  

E-Print Network [OSTI]

phenomena improving MEA and stack performance · Optimize fuel cells and systems for early marketue Ce ec o o es o a Energy Efficiency & Renewable Energy Fuel Cell Bus Workshop Overview and Purppose Dimitrios Papageorgopoulos Fuel Cell Technologgies Proggram DOE and DOT Joint Fuel Cell Bus

54

University of Saskatchewan College of Arts & sCienCe  

E-Print Network [OSTI]

University of Saskatchewan College of Arts & sCienCe Annual report 2009/2010 #12;Contents The Dean thought....The strong work ethic of the youth of Saskatchewan, who are then exposed to high- minded Simard, BA'69, LLB'70 Minister of Health, Government of Saskatchewan (1991­1995) #12;The dean's message I

Patterson, William P.

55

2014 Course Description Solid Waste Engineering -CE 477  

E-Print Network [OSTI]

2014 Course Description Solid Waste Engineering - CE 477 Engineering Principles of Solid Waste on course web site http://people.engr.ncsu.edu/barlaz/ Solid Waste Technology & Management by Christensen et al (eBook available through NCSU libraries) Solid waste management must be addressed by virtually

Barlaz, Morton A.

56

CE 469 / 569 TRAVEL DEMAND MODELING Spring 2006 Course Syllabus  

E-Print Network [OSTI]

of travel demand data, and should apply these methods to estimating and to forecasting travel demand these to practical modeling scenarios. The student should also use existing computer tools to forecast travel demand1 CE 469 / 569 TRAVEL DEMAND MODELING Spring 2006 Course Syllabus Catalog Detailed investigation

Hickman, Mark

57

Seven-quasiparticle bands in {sup 139}Ce  

SciTech Connect (OSTI)

The high spin states in the {sup 139}Ce nucleus have been studied by in-beam {gamma}-spectroscopic techniques using the reaction {sup 130}Te({sup 12}C,3n){sup 139}Ce at E{sub beam}=65 MeV. A gamma detector array, consisting of five Compton-suppressed Clover detectors was used for coincidence measurements. 15 new levels have been proposed and 28 new {gamma} transitions have been assigned to {sup 139}Ce on the basis of {gamma}{gamma} coincidence data. The level scheme of {sup 139}Ce has been extended above the known 70 ns (19/2){sup -} isomer up to {approx}6.1 MeV in excitation energy and (35/2)({Dirac_h}/2{pi}) in spin. The spin-parity assignments for most of the newly proposed levels have been made using the deduced Directional Correlation from Oriented states of nuclei (DCO ratio) and the Polarization Directional Correlation from Oriented states (PDCO ratio) for the de-exciting transitions. The observed level structure has been compared with a large basis shell model calculation and also with the predictions from cranked Nilsson-Strutinsky (CNS) calculations. A general consistency has been observed between these two different theoretical approaches.

Chanda, Somen; Bhattacharjee, Tumpa; Bhattacharyya, Sarmishtha; Mukherjee, Anjali; Basu, Swapan Kumar; Ragnarsson, I.; Bhowmik, R. K.; Muralithar, S.; Singh, R. P.; Ghugre, S. S.; Pramanik, U. Datta [Variable Energy Cyclotron Centre, Kolkata 700064 (India); Division of Mathematical Physics, Lund Institute of Technology, Lund University, P. O. Box 118, S-22100 Lund (Sweden); Inter University Accelerator Centre, New Delhi 110067 (India); University Grants Commission and Department of Atomic Energy Consortium for Scientific Research, Kolkata 700098 (India); Saha Institute of Nuclear Physics, Kolkata 700064 (India)

2009-05-15T23:59:59.000Z

58

CE 4990 -Construction Scheduling Week 1: Steel Frame Project  

E-Print Network [OSTI]

CE 4990 - Construction Scheduling Week 1: Steel Frame Project Fall 2011 January 13, 2012 Introduction You are a construction manager for a project to build a steel frame for an office building1 of 964 pre-fabricated structural steel members will be used in the construction. The standard bay size

Mukherjee, Amlan

59

Thermodynamic and Structural Features of Aqueous Ce(III)  

SciTech Connect (OSTI)

With a single f-electron, Ce(III) is the simplest test case for benchmarking the thermodynamic and structural properties of hydrated Ln(III) against varying density functionals and reaction field models, in addition to determining the importance of multiconfigurational character in their wave functions. Here, the electronic structure of Ce(H2O)x(H2O)y3+ (x = 8, 9; y = 0, 12-14) has been examined using DFT and CASSCF calculations. The latter confirmed that the wave function of octa- and nona-aqua Ce(III) is well-described by a single configuration. Benchmarking was performed for density functionals, reaction field cavity types, and solvation reactions against the experimental free energy of hydration, ?Ghyd(Ce3+). The UA0, UAKS, Pauling, and UFF polarized continuum model cavities displayed different performance, depending on whether one or two hydration shells were examined, and as a function of the size of the metal basis set. These results were essentially independent of the density functional employed. Using these benchmarks, the free energy for water exchange between CN = 8 and CN = 9, for which no experimental data are available, was estimated to be approximately -4 kcal/mol.

Adriana Dinescu; Aurora E. Clark

2008-10-01T23:59:59.000Z

60

Thermodynamic and Structural Features of Aqueous Ce(III)  

SciTech Connect (OSTI)

With a single f-electron, Ce(III) is the simplest test case for benchmarking the thermodynamic and structural properties of hydrated Ln(III) against varying density functionals and reaction field models, in addition to determining the importance of multiconfigurational character in their wave functions. Here, the electronic structure of Ce(H?O)x(H?O)y 3+ (x =8, 9; y= 0, 12-14) has been examined using DFT and CASSCF calculations. The latter confirmed that the wave function of octa- and nona-aqua Ce(III) is well-described by a single configuration. Benchmarking was performed for density functionals, reaction field cavity types, and solvation reactions against the experimental free energy of hydration, ?Ghyd(Ce3+). The UA0, UAKS, Pauling, and UFF polarized continuum model cavities displayed different performance, depending on whether one or two hydration shells were examined, and as a function of the size of the metal basis set. These results were essentially independent of the density functional employed. Using these benchmarks, the free energy for water exchange between CN = 8 and CN = 9, for which no experimental data are available, was estimated to be approximately -4 kcal/mol.

Dinescu, Adriana; Clark, Aurora E.

2008-10-10T23:59:59.000Z

Note: This page contains sample records for the topic "mineral gadolinite ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

The mission of the USGS National Minerals Information Center (formerly  

E-Print Network [OSTI]

, and in the development of strate- gies to maintain a competitive position in the global economy. The Center's mineralsThe mission of the USGS National Minerals Information Center (formerly the Minerals Information of and demand for minerals and mineral materials essential to the U.S. economy and national security. Examples

Torgersen, Christian

62

CO Oxidation mechanism on CeO2-supported Au nanoclusters  

SciTech Connect (OSTI)

To reveal the richer chemistry of CO oxidation by CeO2 supported Au Nanoclusters(NCs)/Nanoparticles, we design Au13 and Au12 supported on a flat and a stepped-CeO2 model (Au/CeO2) and study various kinds of CO oxidation mechanisms at the Au-CeO2 interface and the Au NC as well.

Kim H. Y.; Henkelman, G.

2013-09-08T23:59:59.000Z

63

In this Issue International CeBiTec Research Conference on Algal Biotechnology  

E-Print Network [OSTI]

Biotechnology From September 21 to 24, 2014, the CeBiTec organized the 4th International CeBiTec Research production. In this respect, the 4th International CeBiTec Research Conference 2014 aimed to give a completeBiTec ­ Quarterly www.cebitec.uni-bielefeld.de #12;2 | 4 CeBiTec ­ Quarterly | Autumn 2014 International

Moeller, Ralf

64

Neutron scattering of CeNi at the SNS-ORNL: A preliminary report  

SciTech Connect (OSTI)

This is a preliminary report of a neutron scattering experiment used to investigate 4f electron behavior in Ce.

Mirmelstein, A. [Russian Federal Nuclear Center VNIITF, Snezhinsk, Russia; Podlesnyak, Andrey A [ORNL; Kolesnikov, Alexander I [ORNL; Saporov, B. [Oak Ridge National Laboratory (ORNL); Sefat, A.S. [Oak Ridge National Laboratory (ORNL); Tobin, J. G. [Lawrence Livermore National Laboratory (LLNL)

2014-01-01T23:59:59.000Z

65

Energy and Mineral Development in Indian Country  

Broader source: Energy.gov [DOE]

The Rocky Mountain Mineral Law Foundation is hosting the Special Institute on Energy and Mineral Development in Indian Country. This two-day conference will cover laws, policies, and practices regarding natural resources development in Indian Country and how they've evolved in the recent years.

66

Chapter 15 Mineral Resources and the Environment  

E-Print Network [OSTI]

Materials produced from natural gas or crude oil, such as plastics Fertilizers for agriculture, phosphate tons per year. Gold and silver have annual consumption rates of 10,000 tons or less. Worldwide consumption of minerals #12; The fundamental problem associated with the availability of mineral resources

Pan, Feifei

67

New Mexico Bureau Mines and Mineral  

E-Print Network [OSTI]

Number22 - 1999 New Mexico Bureau of Mines and Mineral Resources a division of Nei~, Mexico Tech forsandblasting five times! ThisIssue Earth Briefs-Better age estimates on some New Mexico volcanic rocks Have You) NewMexico's Most Wanted Minera Is (pageT) Magnification of microscopic miner- als and glass (page 8

Dunbar, Nelia W.

68

DAO O ce Note 1998-05 Version 1 Dated 12/06/1999 O ce Note Series on  

E-Print Network [OSTI]

Assimilation Siegfried Schubert, Editor Documentation of the Physical-Space Statistical Analysis System (PSAS and sources, as well as the use of the multivariate formulation. An on-line version of this document can be obtained from the DAO. Robert M. Atlas, Acting Head Data Assimilation O ce Goddard Space Flight Center

69

Minerals yearbook: Mineral industries of Europe and central Eurasia. Volume 3. 1992 international review  

SciTech Connect (OSTI)

Volume III, Minerals Yearbook -- International Review contains the latest available mineral data on more than 175 foreign countries and discusses the importance of minerals to the economies of these nations. Since the 1989 International Review, the volume has been presented as six reports. The report presents the Mineral Industries of Europe and Central Eurasia. The report incorporates location maps, industry structure tables, and an outlook section previously incorporated in the authors' Minerals Perspectives Series quinquennial regional books, which are being discontinued. This section of the Minerals Yearbook reviews the minerals industries of 45 countries: the 12 nations of the European Community (EC); 6 of the 7 nations of the European Free Trade Association (EFTA); Malta; the 11 Eastern European economies in transition (Albania, Bosnia and Hercegovina, Bulgaria, Croatia, Czechoslovakia, Hungary, Macedonia, Poland, Romania, Serbia and Montenegro, and Slovenia); and the countries of Central Eurasia (Armenia, Azerbaijan, Belarus, Estonia, Georgia, Kazakhstan, Kyrgystan, Latvia, Lithuania, Moldova, Russia, Tajikistan, Turkmenistan, Ukraine, and Uzbekistan).

Not Available

1992-01-01T23:59:59.000Z

70

alters bone mineral: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

for Mineral and Energy Physics Websites Summary: Institute for Mineral and Energy Resources Answering Global Resource and Energy Challenges 12;Answering Global Resource and...

71

absorptiometric bone mineral: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

for Mineral and Energy Physics Websites Summary: Institute for Mineral and Energy Resources Answering Global Resource and Energy Challenges 12;Answering Global Resource and...

72

african mineral dust: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Laurent 19 Does the size distribution of mineral dust aerosols depend on the wind speed at emission? CERN Preprints Summary: The size distribution of mineral dust aerosols...

73

artery calcium mineral: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

between diatom aggregates, minerals, particulate organic carbon, and dissolved organic October 2008. 1 Correlations of particulate organic carbon (POC) and mineral fluxes into...

74

Determining Individual Mineral Contributions To U(VI) Adsorption...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Individual Mineral Contributions To U(VI) Adsorption In A Contaminated Aquifer Sediment: A Fluorescence Spectroscopy Determining Individual Mineral Contributions To U(VI)...

75

Synthesis of supported carbon nanotubes in mineralized silica...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

supported carbon nanotubes in mineralized silica-wood composites. Synthesis of supported carbon nanotubes in mineralized silica-wood composites. Abstract: Multiwall carbon...

76

Mineral Recovery Creates Revenue Stream for Geothermal Energy...  

Energy Savers [EERE]

Mineral Recovery Creates Revenue Stream for Geothermal Energy Development Mineral Recovery Creates Revenue Stream for Geothermal Energy Development January 21, 2014 - 12:00am...

77

V-215: NetworkMiner Directory Traversal and Insecure Library...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

5: NetworkMiner Directory Traversal and Insecure Library Loading Vulnerabilities V-215: NetworkMiner Directory Traversal and Insecure Library Loading Vulnerabilities August 9, 2013...

78

Biotic and abiotic pathways of phosphorus cycling in minerals...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and abiotic pathways of phosphorus cycling in minerals and sediments: insights from oxygen isotopes in phosphate. Biotic and abiotic pathways of phosphorus cycling in minerals...

79

Relations Of Ammonium Minerals At Several Hydrothermal Systems...  

Open Energy Info (EERE)

Minerals At Several Hydrothermal Systems In The Western Us Abstract Ammonium bound to silicate and sulfate minerals has recently been located at several major hydrothermal systems...

80

ITP Mining: Mining Industry of the Future Mineral Processing...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

of the Future Mineral Processing Technology Roadmap ITP Mining: Mining Industry of the Future Mineral Processing Technology Roadmap mptroadmap.pdf More Documents & Publications ITP...

Note: This page contains sample records for the topic "mineral gadolinite ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

www.ce.udel.edu/speakers ENVIRONMENTAL ENGINEERING  

E-Print Network [OSTI]

strategies" Dr. Angelia Seyfferth Assistant Professor Department of Plant and soil science UNIversITy Of DelAWAre MAR 08 "Tradeoffs in Water Quality Management: risk, economics and equity" Dr. Michael Kavanaugh-831-2442 "sustainable stormwater research" Dr. Robert G. Traver Director vIllANOvA CeNTer fOr The ADvANCeMeNT Of sUsTAINAbIlITy

Kirby, James T.

82

Mineral Leases by Political Subdivisions (Texas)  

Broader source: Energy.gov [DOE]

This legislation authorizes local political subdivisions to lease lands they own for the development of mineral interests, including coal and lignite. A public hearing process is required prior to...

83

Minerals on School and Public Lands  

Broader source: Energy.gov [DOE]

The Commissioner of School and Public Lands is authorized to lease the mineral interests of such lands for development. Section 5-7 of the SD Codified Laws describes provisions for the leasing of...

84

Oil, Gas, and Metallic Minerals (Iowa)  

Broader source: Energy.gov [DOE]

Operators of oil, gas, and metallic mineral exploration and production operations are required to obtain a drilling permit from the Iowa Department of Natural Resources and file specific forms with...

85

Sustainable growth and valuation of mineral reserves  

E-Print Network [OSTI]

The annual change in the value of an in-ground mineral is equal to the increase or decrease of inventories ("reserves"), multiplied by the market value of a reserve unit. The limited shrinking resource base does not exist. ...

Adelman, Morris Albert

1994-01-01T23:59:59.000Z

86

Approved Module Information for CE1102, 2014/5 Module Title/Name: Organic Chemistry for Engineers Module Code: CE1102  

E-Print Network [OSTI]

Approved Module Information for CE1102, 2014/5 Module Title/Name: Organic Chemistry for Engineers Module Code: CE1102 School: Engineering and Applied Science Module Type: Standard Module New Module chemistry. Part 2: Introduction to Laboratory Skills To enable the student to develop good practical skills

Neirotti, Juan Pablo

87

Mineral royalties : a preview of the development of Mineral Royalty legislation in South Africa.  

E-Print Network [OSTI]

?? A dynamic shift in the ownership, management and development of the countrys mineral heritage took place after the inauguration of the new political dispensation… (more)

Van der Zwan, Pieter

2010-01-01T23:59:59.000Z

88

Strongly correlated electron behavior : superconductivity and non-Fermi liquid behavior in Ce?-xRxColn?  

E-Print Network [OSTI]

T ( ) c T ( c ab La Ce Pr Nd PmSm Eu Gd Tb Dy Ho Er Tm YbSm x Ce La Tb La Ce Pr Nd PmSm Eu Gd Tb Dy Ho Er Tm Yb (b)g -1) J(J+1) Ce (a) La Ce Pr Nd PmSm Eu Gd Tb Dy Ho Er Tm Yb

Gonzales, Eileen

2009-01-01T23:59:59.000Z

89

2012 Minerals Yearbook U.S. Department of the Interior  

E-Print Network [OSTI]

spodumene. Australia was, by far, the leading producer of lithium mineral concentrates, but Brazil, China

90

One Weird Trick to Stop Selfish Miners: Fresh Bitcoins, A Solution for the Honest Miner.  

E-Print Network [OSTI]

One Weird Trick to Stop Selfish Miners: Fresh Bitcoins, A Solution for the Honest Miner. Ethan Heilman Boston University heilman@bu.edu Abstract--A recent result in Bitcoin is the selfish mining incentive-compatible and harmful to Bitcoin. In this paper we introduce a new defense against selfish mining

91

Sustainable Water Management in the Minerals Industry 1 SUSTAINABLE WATER MANAGEMENT IN THE MINERALS  

E-Print Network [OSTI]

Sustainable Water Management in the Minerals Industry 1 SUSTAINABLE WATER MANAGEMENT IN THE MINERALS INDUSTRY Bill Whiten1, Mark McGuinness2, Sayed Hoseini3 The problem of managing a storage dam interest. It arises in the provision of water for Queensland coal mines, where additional water

McGuinness, Mark

92

Whirlpool: Order (2014-CE-21010) | Department of Energy  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergyENERGYWomen Owned SmallOf TheViolations | Department of Energyis EIA? Andof4-CE-21010)

93

LG: Proposed Penalty (2015-CE-14022) | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensionalthe10 DOEWashington, DCKickoffLDV5-CE-14022) LG: Proposed Penalty

94

Sunpentown: Order (2012-CE-1505) | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |Energy Usage »of Energy Strain Rate4 RecoveryJulyEvaluationOffi ce U.S. DepartmentOrder

95

Ethanol Steam Reforming on Co/CeO2: The Effect of ZnO Promoter  

SciTech Connect (OSTI)

A series of ZnO promoted Co/CeO2 catalysts were synthesized and characterized using XRD, TEM, H2-TPR, CO chemisorption, O2-TPO, IR-Py, and CO2-TPD. The effects of ZnO on the catalytic performances of Co/CeO2 were studied in ethanol steam reforming. It was found that the addition of ZnO facilitated the oxidation of Co0 via enhanced oxygen mobility of the CeO2 support which decreased the activity of Co/CeO2 in C–C bond cleavage of ethanol. 3 wt% ZnO promoted Co/CeO2 exhibited minimum CO and CH4 selectivity and maximum CO2 selectivity. This resulted from the combined effects of the following factors with increasing ZnO loading: (1) enhanced oxygen mobility of CeO2 facilitated the oxidation of CHx and CO to form CO2; (2) increased ZnO coverage on CeO2 surface reduced the interaction between CHx/CO and Co/CeO2; and (3) suppressed CO adsorption on Co0 reduced CO oxidation rate to form CO2. In addition, the addition of ZnO also modified the surface acidity and basicity of CeO2, which consequently affected the C2–C4 product distributions.

Davidson, Stephen; Sun, Junming; Wang, Yong

2013-12-02T23:59:59.000Z

96

CeBr3 as a High-Resolution Gamma-Ray Detector  

SciTech Connect (OSTI)

Lanthanum halide (LaBr3:Ce) scintillators have been well-documented as high-resolution gamma-ray detectors that are operated at room temperature. These scintillators have better resolution (<3% at 662 keV) relative to sodium iodide (NaI(Tl)) scintillators (7% at 662 keV), but the naturally occurring radioactive isotope 138La causes self-activity in the crystal that occludes portions of the gamma-ray spectrum. This selfactivity limits the use of LaBr3:Ce in high-sensitivity applications. Cerium, the dopant in the LaBr3:Ce matrix possesses useful scintillation properties, and its selfactivity is on the order of 3750 times less than La; however, Ce has not been fully characterized as the chief component in a scintillation detector. This work investigated Ce as the key scintillation matrix component in a scintillation detector with the hypothesis that CeBr3 promises energy resolution comparable or superior to LaBr3:Ce. The researchers involved with this work believe that CeBr3 may be the answer to obtaining high-temperature, high-resolution spectra with greater sensitivity than LaBr3:Ce.

Michael Reed, Paul Guss, Christopher Contreras

2008-11-13T23:59:59.000Z

97

Capillary electrophoresis-fluorescence line narrowing system (CE-FLNS) for on-line structural characterization  

DOE Patents [OSTI]

Capillary electrophoresis (CE) is interfaced with low temperature fluorescence line-narrowing (FLN) spectroscopy for on-line structural characterization of separated molecular analytes. 21 figs.

Jankowiak, R.J.; Small, G.J.; Shields, P.A.

1999-04-27T23:59:59.000Z

98

The Complex Core Level Spectra of CeO2: An Analysis in Terms of Atomic and Charge Transfer Effects  

SciTech Connect (OSTI)

We present a rigorous parameter-free theoretical treatment of the Ce 4s and 5s photoelectron spectra of CeO2. In the currently accepted model the satellite structure in the photoelectron spectra is explained in terms of a mixed valence (Ce 4f0 O 2p6, Ce 4f1 O 2p5, and Ce 4f2 O 2p4) con?guration. We show that charge transfer (CT) into Ce 5d as well as con?gurations involving intra-atomic movement of charge must be considered in addition and compute their contributions to the spectra.

Bagus, Paul S.; Nelin, Constance J.; Ilton, Eugene S.; Baron, Martin; Abbott, Heather; Primorac, Elena; Kuhlenbeck, Helmut; Shaikhutdinov, Shamil; Freund, Hans-Joachim

2010-03-05T23:59:59.000Z

99

Interaction of carbon monoxide with oxygen in the adsorbed layer on Pd, Ce, Pd-Ce catalysts supported on /gamma/-Al/sub 2/O/sub 3/  

SciTech Connect (OSTI)

The adsorption of CO and the interaction of CO/sub ads/ with O/sub 2/ on Pd, Ce, and Pd-Ce//gamma/-Al/sub 2/O/sub 3/ (0.5 wt. % Pd, 2.0 wt. % Ce) has been studied using the methods of IR spectroscopy and differential scanning calorimetry. The identity of the adsorbed CO complexes, the temperature ranges over which they desorb, and their reactivity with O/sub 2/ have been established. The interaction of bridging and carbonate - carboxylate CO complexes and carbon (disproportionation and dissociation products) with O/sub 2/ on Pd and Pd-Ce catalysts is preceded by the coadsorption of oxygen and the evolution of heat. During the oxidation of CO, autooscillation, heat evolution, and the concentration of oxygen in the flow are observed.

Savel'eva, G.A.; Sass, A.S.; Speranskaya, G.V.; Tenchev, K.K.; Petrov, L.A.; Vozdvizhenskii, V.F.; Galeev, T.K.; Popova, N.M.

1989-01-01T23:59:59.000Z

100

CO Oxidation at the Interface of Au Nanoclusters and the Stepped-CeO2(111) Surface  

SciTech Connect (OSTI)

To reveal the richer chemistry of CO oxidation by CeO2 supported Au Nanoclusters NCs)/Nanoparticles, we design a Au12 supported on a stepped-CeO2 model (Au/CeO2-step) and study various kinds of CO oxidation mechanisms at the interface of the Au/CeO2-step: oxygen spillover from the CeO2 to the Au NCs;2 CO oxidation by the O2 bound to the Au-Ce3+ interface;3 and CO oxidation by the Mars-van Krevelen (M-vK) mechanism.4 DFT+U calculations show that lattice oxygen at the CeO2 step edge oxidizes CO bound to Au NCs by the M-vK mechanism. CO2 desorption determines the rate of CO oxidation and the vacancy formation energy (Evac) is a reactivity descriptor for CO oxidation. The maximum Evac that insures spontaneous CO2 production is higher for the Au/CeO2-step than the Au/CeO2-surface suggesting that the CeO2-step is a better supporting material than the CeO2-surface for CO oxidation by the Au/CeO2. Our results also suggest that for CO oxidation by Au NCs supported on nano- or meso-structured CeO2, which is the case of industrial catalysts, the M-vK mechanism accounts for a large portion of the total activity.

Kim H. Y.; Henkelman, G.

2013-01-14T23:59:59.000Z

Note: This page contains sample records for the topic "mineral gadolinite ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Earth Minerals Did you read chapter 29  

E-Print Network [OSTI]

1 Chapter 29 Earth Minerals Did you read chapter 29 before coming to class? A. Yes B. No Lets play that begins in Hawaii Other "Hot Spots" around the world The interior structure of Earth has been determined outer core #12;2 What is different on earth (as opposed to other planets)? Continents Why does

Hart, Gus

102

Institute for Mineral and Energy Resources  

E-Print Network [OSTI]

and sustainable use and development of the world's mineral and energy resources for the benefit of society; · Advance the science and technology needed to lower the cost and enhance cleaner energy generation, storage and energy systems; bioenergy generation, conversion and storage; control of sound and vibration; physical

103

Clay mineral reactions in clastic diagenesis  

SciTech Connect (OSTI)

Studies of clastic sediments have documented the formation and transformation of clay mineral assemblages during burial diagensis. The transformation of smectite to illite in shale by its reaction with the decomposition products of detrital K-feldspar and mica results in the production of new pore water at depth. The overall reaction mobilizes all the major chemical components in the shale, most of which are consumed in the formation of the diagenetic assemblage illite/smectite + chlorite + quartz. However, part of all the components is undoubtedly transported from the shale to sandstone units and is involved in cementation, replacement, and diagenetic clay mineral formation in these reservoir rocks. In contrast to burial diagenetic reactions in shale, where the sequence is monotonic and reasonably predictable, diagenetic reactions in sandstone are frequently variable. This variability is probably attributable to the fact that sandstones are open systems in which the reactions that proceed are controlled in part by the influx of new pore water, the chemistry of which is determined by an outside source. The useful understanding role of clay minerals in hydrocarbon exploration will follow from a determination of the system shale/sandstone/organic material. We need to tie in the nature and timing of shale mineral reactions and their control on the fluid and mass transfer from shale to sandstone.

Hower, J.

1983-03-01T23:59:59.000Z

104

2005 Minerals Yearbook CLAY AND SHALE  

E-Print Network [OSTI]

2005 Minerals Yearbook CLAY AND SHALE U.S. Department of the Interior U.S. Geological Survey February 2007 #12;CLAY AND SHALE--2005 18.1 CLAY AND SHALE By Robert L. Virta Domestic survey data at $1.68 billion in 2004 (table 1). Common clay and shale accounted for 59% of the tonnage, and kaolin

105

USED MINERAL-BASED CRANKCASE OIL  

E-Print Network [OSTI]

based crankcase oil vary depending on the brand and type of oil, whether gasoline or diesel fuel was used, the mechanical condition of the engine that the oil came from, and the amount of use between oil changes. Used oil is not naturally found in the environment. What happens to used mineral-based crankcase oil when it enters the environment? q Used mineral-based crankcase oil enters the air through the exhaust system during engine use. q It may enter water or soil when disposed of improperly. q The hydrocarbon components of the oil generally stick to the soil surface. q Some hydrocarbons evaporate into the air very quickly, and others evaporate more slowly. q Hydrocarbon components of the oil that enter surface water bind to small particles in the water and eventually settle to the bottom. q Hydrocarbons from used mineral-based crankcase oil may build up in shellfish or other organisms. q Some metals in used mineral-based crankcase oil dissolve in water and move through the s

Used Mineral-Based Crankcase

106

Iron oxyhydroxide mineralization on microbial extracellular polysaccharides  

SciTech Connect (OSTI)

Iron biominerals can form in neutral pH microaerophilic environments where microbes both catalyze iron oxidation and create polymers that localize mineral precipitation. In order to classify the microbial polymers that influence FeOOH mineralogy, we studied the organic and mineral components of biominerals using scanning transmission X-ray microscopy (STXM), micro X-ray fluorescence ({mu}XRF) microscopy, and high-resolution transmission electron microscopy (HRTEM). We focused on iron microbial mat samples from a creek and abandoned mine; these samples are dominated by iron oxyhydroxide-coated structures with sheath, stalk, and filament morphologies. In addition, we characterized the mineralized products of an iron-oxidizing, stalk-forming bacterial culture isolated from the mine. In both natural and cultured samples, microbial polymers were found to be acidic polysaccharides with carboxyl functional groups, strongly spatially correlated with iron oxyhydroxide distribution patterns. Organic fibrils collect FeOOH and control its recrystallization, in some cases resulting in oriented crystals with high aspect ratios. The impact of polymers is particularly pronounced as the materials age. Synthesis experiments designed to mimic the biomineralization processes show that the polysaccharide carboxyl groups bind dissolved iron strongly but release it as mineralization proceeds. Our results suggest that carboxyl groups of acidic polysaccharides are produced by different microorganisms to create a wide range of iron oxyhydroxide biomineral structures. The intimate and potentially long-term association controls the crystal growth, phase, and reactivity of iron oxyhydroxide nanoparticles in natural systems.

Chan, Clara S.; Fakra, Sirine C.; Edwards, David C.; Emerson, David; Banfield, Jillian F.

2010-06-22T23:59:59.000Z

107

Atomistic Study of Doped BaCeO3: Dopant Site-Selectivity and Cation Nonstoichiometry  

E-Print Network [OSTI]

of Technology, Pasadena, California 91125, and Materials Chemistry Group, Chemistry DiVision, Uni, the trivalent dopants are assumed to occupy the Ce4+ -site, which introduces oxygen vacancies partitioning over both Ba and Ce sites. Such partitioning reduces the concentration of oxygen vacancies, which

Haile, Sossina M.

108

E-Print Network 3.0 - affecting born mineral Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

mineral mines may affect air quality. As with water pollution, mines can contribute to air pollution... Chapter 15 Mineral Resources and the Environment 12;Minerals found in a...

109

aluminosilicate clay minerals: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

used mineral-based crankcase oil may build up in shellfish or other organisms. q Some metals in used mineral-based crankcase oil dissolve in water and move through the s Used...

110

anaerobic toluene mineralization: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and found in nature as the mineral tincal. Boric acid, also known as orthoboric acid boric acid. The most common minerals of commercial importance in the United States were...

111

accompanying mineral crystal: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Foreign investment: Coal 45 1 Oil 4.7 6 Industrial minerals: Cement 42 1 Fluorspar 55 1 Rare earths 85 1 Metals: Aluminum 312 Mineral-filled polypropylene: Improvement of scratch...

112

articular cartilage mineralization: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Foreign investment: Coal 45 1 Oil 4.7 6 Industrial minerals: Cement 42 1 Fluorspar 55 1 Rare earths 85 1 Metals: Aluminum 304 Mineral-filled polypropylene: Improvement of scratch...

113

amaro mineral sand: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Foreign investment: Coal 45 1 Oil 4.7 6 Industrial minerals: Cement 42 1 Fluorspar 55 1 Rare earths 85 1 Metals: Aluminum 452 Mineral-filled polypropylene: Improvement of scratch...

114

aporte del mineral: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Foreign investment: Coal 45 1 Oil 4.7 6 Industrial minerals: Cement 42 1 Fluorspar 55 1 Rare earths 85 1 Metals: Aluminum 118 Mineral-filled polypropylene: Improvement of scratch...

115

agua por mineral: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Foreign investment: Coal 45 1 Oil 4.7 6 Industrial minerals: Cement 42 1 Fluorspar 55 1 Rare earths 85 1 Metals: Aluminum 171 Mineral-filled polypropylene: Improvement of scratch...

116

Ternary ceramic alloys of Zr-Ce-Hf oxides  

DOE Patents [OSTI]

A ternary ceramic alloy is described which produces toughening of zirconia and zirconia composites through the stress transformation from tetragonal phase to monoclinic phase. This alloy, having the general formula Ce[sub x]Hf[sub y]Zr[sub 1[minus]x[minus]y]O[sub 2], is produced through the addition of appropriate amounts of ceria and hafnia to the zirconia. Typically, improved toughness is achieved with about 5 to about 15 mol % ceria and up to about 40 mol % hafnia. The preparation of alloys of these compositions are given together with data as to the densities, tetragonal phase content, hardness and fracture toughness. The alloys are useful in preparing zirconia bodies as well as reinforcing ceramic composites. 1 fig.

Becher, P.F.; Funkenbusch, E.F.

1990-11-20T23:59:59.000Z

117

Ternary ceramic alloys of ZR-CE-HF oxides  

DOE Patents [OSTI]

A ternary ceramic alloy which produces toughening of zirconia and zirconia composites through the stress transformation from tetragonal phase to monoclinic phase. This alloy, having the general formula Ce.sub.x Hf.sub.y Zn.sub.1-x-y O.sub.2, is produced through the addition of appropriate amounts of ceria and hafnia to the zirconia. Typically, improved toughness is achieved with about 5 to about 15 mol % ceria and up to about 40 mol % hafnia. The preparation of alloys of these compositions are given together with data as to the densities, tetragonal phase content, hardness and fracture toughness. The alloys are useful in preparing zirconia bodies as well as reinforcing ceramic composites.

Becher, Paul F. (Oak Ridge, TN); Funkenbusch, Eric F. (White Bear Lake, MN)

1990-01-01T23:59:59.000Z

118

Professor Jan Cilliers, Rio Tinto Professor of Mineral Processing  

E-Print Network [OSTI]

;38 Flowing froth - video #12;39 Smelter and Converter Separating the metal from the mineral #12;40 Casting

119

Molecular Characterization of Bacterial Respiration on Minerals  

SciTech Connect (OSTI)

The overall aim of this project was to contribute to our fundamental understanding of proteins and biological processes under extreme environmental conditions. We sought to define the biochemical and physiological mechanisms that underlie biodegradative and other cellular processes in normal, extreme, and engineered environments. Toward that end, we sought to understand the substrate oxidation pathways, the electron transport mechanisms, and the modes of energy conservation employed during respiration by bacteria on soluble iron and insoluble sulfide minerals. In accordance with these general aims, the specific aims were two-fold: To identify, separate, and characterize the extracellular biomolecules necessary for aerobic respiration on iron under strongly acidic conditions; and to elucidate the molecular principles whereby these bacteria recognize and adhere to their insoluble mineral substrates under harsh environmental conditions. The results of these studies were described in a total of nineteen manuscripts. Highlights include the following: 1. The complete genome of Acidithiobacillus ferrooxidans ATCC 23270 (type strain) was sequenced in collaboration with the DOE Joint Genome Institute; 2. Genomic and mass spectrometry-based proteomic methods were used to evaluate gene expression and in situ microbial activity in a low-complexity natural acid mine drainage microbial biofilm community. This was the first effort to successfully analyze a natural community using these techniques; 3. Detailed functional and structural studies were conducted on rusticyanin, an acid-stable electron transfer protein purified from cell-free extracts of At. ferrooxidans. The three-dimensional structure of reduced rusticyanin was determined from a combination of homonuclear proton and heteronuclear 15N- and 13C-edited NMR spectra. Concomitantly, the three-dimensional structure of oxidized rusticyanin was determined by X-ray crystallography to a resolution of 1.9 A by multiwavelength anomalous dispersion (MAD) phasing; 4. An acid-stable red cytochrome with a novel absorbance peak at 579 nm was purified from cell-free extracts of L. ferriphilum. Functional studies demonstrated that this cytochrome was an important component of the aerobic iron respiratory chain in this organism; 5. The specific adhesion of At. ferrooxidans to pyrite is mediated by an extracellular protein that was identified as aporusticyanin. The adhesion of At. ferrooxidans to minerals was characterized by high affinity binding that exhibited a high specificity for pyrite over other sulfide minerals. The principal biopolymer involved in this high-affinity adhesion to pyrite was isolated by mineral affinity chromatography and identified as aporusticyanin. The adhesion of purified aporusticyanin to minerals was observed to adhere to different mineral with a pattern of reactivity identical to that observed with the intact bacterium. Further, preincubation of pyrite with excess exogenous aporusticyanin served to inhibit the adherence of intact cells to the surface of the mineral, indicating that the protein and the cells adhered to the pyrite in a mutually exclusive manner. Taken together, these observations support a model where aporusticyanin located on the surface of the bacterial cell acts as a mineral-specific receptor for the initial adherence of At. ferrooxidans to solid pyrite; 6. The specific adhesion of L. ferriphilum to pyrite was mediated by a different acid-stable extracellular protein than aporusticyanin; and 7. A prototype integrating cavity absorption meter (ICAM) was assembled to determine whether this novel spectrophotometer could be used to study cellular respiration in situ.

Blake, Robert C.

2013-04-26T23:59:59.000Z

120

COLLECTIONS POLICY MANUAL Earth and Mineral Sciences Museum  

E-Print Network [OSTI]

COLLECTIONS POLICY MANUAL Earth and Mineral Sciences Museum College of Earth and Mineral Sciences Manual for the Earth and Mineral Sciences Museum has been developed to standardize procedures and provide guidelines for handling collections. The policies outlined here were established by the EMS Museum Director

Maroncelli, Mark

Note: This page contains sample records for the topic "mineral gadolinite ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Carbon Sequestration via Mineral Carbonation: Overview and Assessment  

E-Print Network [OSTI]

1 Carbon Sequestration via Mineral Carbonation: Overview and Assessment 14 March 2002 Howard Herzog overview and assessment of carbon sequestration by mineral carbonation (referred to as "mineral sequestration R&D. The first is that carbonates have a lower energy state than CO2. Therefore, at least

122

1synQPSK Univ. Paderborn, Germany; CeLight Israel; Photline, France; IPAG, Germany Univ. Paderborn, Germany  

E-Print Network [OSTI]

1synQPSK Univ. Paderborn, Germany; CeLight Israel; Photline, France; IPAG, Germany synQPSK Univ. Paderborn, Germany CeLight Israel Photline, France IPAG, Germany Contract 004631 in FP6 IST-2002 Phase Shift Keying Transmission #12;2synQPSK Univ. Paderborn, Germany; CeLight Israel; Photline, France

Noé, Reinhold

123

Synthesis and magnetic properties of the double layer perovskite CeBaFe2O5+w  

E-Print Network [OSTI]

Synthesis and magnetic properties of the double layer perovskite CeBaFe2O5+w R. L. de Almeida,1 O The synthesis, crystallographic structure, and magnetic properties of polycrystalline single-phase samples of CeBaFe results on the successful prepara- tion and characterization of polycrystalline CeBaFe2O5+w samples. Ideal

de Lima, Oscar Ferreira

124

Reassessment of Al-Ce and Al-Nd Binary Systems Supported by Critical Experiments and First-Principles  

E-Print Network [OSTI]

Reassessment of Al-Ce and Al-Nd Binary Systems Supported by Critical Experiments and First The present study reinvestigates the Al-Ce and Al-Nd phase diagrams and reoptimizes their thermody- namics results and theoretical calculations show that Al2Nd (or Al2Ce) should be treated as a stoichiometric

Widom, Michael

125

Mineral balances, including in drinking water, estimated for Merced County dairy herds  

E-Print Network [OSTI]

of daily mineral intake, drinking-water mineral contributionND Total daily intake, including minerals in drinking water.mineral contents in drinking water and daily drinking-water

Castillo, Alejandro R Dr.; Santos, Jose Eduardo P.; Tabone, Tom J.

2007-01-01T23:59:59.000Z

126

Studies on Cu/CeO{sub 2}: A new NO reduction catalyst  

SciTech Connect (OSTI)

Fine particle and large surface area Cu/CeO{sub 2} catalysts of crystallite sizes in the range of 100--200 {angstrom} synthesized by the solution combustion method have been investigated for NO reduction. Five percent Cu/CeO{sub 2} catalyst shows nearly 100% conversion of NO by NH{sub 3} below 300 C, whereas pure ceria and Zr, Y, and Ca doped ceria show 85--95% NO conversion above 600 C. Similarly NO reduction by CO has been observed over 5% Cu/CeO{sub 2} with nearly 100% conversion below 300 C. Hydrocarbon (n-butane) oxidation by NO to CO{sub 2}, N{sub 2}, and H{sub 2}O has also been demonstrated over this catalyst below 350 C making Cu/CeO{sub 2} a new NO reduction catalyst in the low temperature window of 150--350 C. Kinetics of NO reduction over 5% Cu/CeO{sub 2} have also been investigated. The rate constants are in the range of 1.4 {times} 10{sup 4} to 2.3 {times} 10{sup 4} cm{sup 3}/g s between 170 and 300 C. Cu/CeO{sub 2} catalysts are characterized by X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, and electron paramagnetic resonance spectroscopy where Cu{sup 2+} ions are shown to be dispersed on the CeO{sub 2} surface.

Bera, P.; Aruna, S.T.; Patil, K.C.; Hegde, M.S. [Indian Inst. of Science, Bangalore (India)] [Indian Inst. of Science, Bangalore (India)

1999-08-15T23:59:59.000Z

127

Studies on Ca2+-Doped CeBr3 Scintillating Materials  

SciTech Connect (OSTI)

Despite the outstanding scintillation performance characteristics of cerium tribromide (CeBr3) and cerium-activated lanthanum tribromide (LaBr3:Ce), their commercial availability and application is limited due to the difficulties of growing large, crack-free single crystals from these fragile materials. The objective of this investigation was to employ aliovalent doping to increase crystal strength while maintaining the optical properties of the crystal. One divalent dopant (Ca2+) was investigated as a dopant to strengthen CeBr3 without negatively impacting scintillation performance. Ingots containing nominal concentrations of 1.9% of the Ca2+ dopant were grown. Preliminary scintillation measurements are presented for this aliovalently doped scintillator. Ca2+-doped CeBr3 exhibited little or no change in the peak fluorescence emission for 371 nm optical excitation for CeBr3. The structural, electronic, and optical properties of CeBr3 crystals were investigated using the density functional theory within generalized gradient approximation. The calculated lattice parameters are in good agreement with the experimental data. The energy band structures and density of states were obtained. The optical properties of CeBr3, including the dielectric function, were calculated.

Guss, P. [NSTec; Foster, M. E. [SNL; Wong, B. M. [SNL; Doty, F. P. [SNL; Shah, K. [RMD; Squillante, M. [RMD; Glodo, J. [RMD; Yuan, D. [NSTec

2013-07-03T23:59:59.000Z

128

Studies on Ca2+-Doped CeBr3 Scintillating Materials  

SciTech Connect (OSTI)

Despite the outstanding scintillation performance characteristics of cerium tribromide (CeBr3) and cerium-activated lanthanum tribromide (LaBr3:Ce), their commercial availability and application is limited due to the difficulties of growing large, crack-free single crystals from these fragile materials. The objective of this investigation was to employ aliovalent doping to increase crystal strength while maintaining the optical properties of the crystal. One divalent dopant (Ca2+) was investigated as a dopant to strengthen CeBr3 without negatively impacting scintillation performance. Ingots containing nominal concentrations of 1.9% of the Ca2+ dopant were grown. Preliminary scintillation measurements are presented for this aliovalently doped scintillator. Ca2+-doped CeBr3 exhibited little or no change in the peak fluorescence emission for 371 nm optical excitation for CeBr3. The structural, electronic, and optical properties of CeBr3 crystals were investigated using the density functional theory within generalized gradient approximation. The calculated lattice parameters are in good agreement with the experimental data. The energy band structures and density of states were obtained. The optical properties of CeBr3, including the dielectric function, were calculated.

Guss, P. [NSTec; Foster, M. E. [SNL; Wong, B. M. [SNL; Doty, F. P. [SNL; Shah, K. [RMD; Squillante, M. R. [RMD; Shirwadkar, U. [RMD; Hawrami, R. [RMD; Tower, J. [RMD; Yuan, D. [NSTec

2013-09-01T23:59:59.000Z

129

E-Print Network 3.0 - activated mineral carbon Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Heat Engineering Laboratory Summary: FACULTY OF TECHNOLOGY Heat Engineering Laboratory Carbon dioxide sequestration by mineral... - Carbon dioxide sequestration by mineral...

130

Carbon dioxide sequestration by aqueous mineral carbonation of magnesium silicate minerals  

SciTech Connect (OSTI)

The dramatic increase in atmospheric carbon dioxide since the Industrial Revolution has caused concerns about global warming. Fossil-fuel-fired power plants contribute approximately one third of the total human-caused emissions of carbon dioxide. Increased efficiency of these power plants will have a large impact on carbon dioxide emissions, but additional measures will be needed to slow or stop the projected increase in the concentration of atmospheric carbon dioxide. By accelerating the naturally occurring carbonation of magnesium silicate minerals it is possible to sequester carbon dioxide in the geologically stable mineral magnesite (MgCO3). The carbonation of two classes of magnesium silicate minerals, olivine (Mg2SiO4) and serpentine (Mg3Si2O5(OH)4), was investigated in an aqueous process. The slow natural geologic process that converts both of these minerals to magnesite can be accelerated by increasing the surface area, increasing the activity of carbon dioxide in the solution, introducing imperfections into the crystal lattice by high-energy attrition grinding, and in the case of serpentine, by thermally activating the mineral by removing the chemically bound water. The effect of temperature is complex because it affects both the solubility of carbon dioxide and the rate of mineral dissolution in opposing fashions. Thus an optimum temperature for carbonation of olivine is approximately 185 degrees C and 155 degrees C for serpentine. This paper will elucidate the interaction of these variables and use kinetic studies to propose a process for the sequestration of the carbon dioxide.

Gerdemann, Stephen J.; Dahlin, David C.; O'Connor, William K.; Penner, Larry R.

2003-01-01T23:59:59.000Z

131

Mineral revenues: the 1983 report on receipts from Federal and Indian leases with summary data from 1920 to 1983  

SciTech Connect (OSTI)

Tables and figures abound for: mineral revenue management in 1983; offshore federal mineral revenues; onshore federal mineral revenues; Indian mineral revenues; distribution of federal and Indian mineral revenues; plus appended lease management data. (PSB)

Not Available

1984-01-01T23:59:59.000Z

132

CE 363 -TRANSPORTATION ENGINEERING AND PAVEMENT DESIGN Fall 2009 Course Syllabus  

E-Print Network [OSTI]

1 CE 363 - TRANSPORTATION ENGINEERING AND PAVEMENT DESIGN Fall 2009 Course Syllabus Catalog (4) CDT Course Syllabus D2L: The primary source for homework, solutions, design project activities, and other

Hickman, Mark

133

Pressure tuning of competing magnetic interactions in intermetallic CeFe2  

SciTech Connect (OSTI)

We use high-pressure magnetic x-ray diffraction and numerical simulation to determine the low-temperature magnetic phase diagram of stoichiometric CeFe2. Near 1.5 GPa we find a transition from ferromagnetism to antiferromagnetism, accompanied by a rhombohedral distortion of the cubic Laves crystal lattice. By comparing pressure and chemical substitution we find that the phase transition is controlled by a shift of magnetic frustration from the Ce-Ce to the Fe-Fe sublattice. Notably the dominant Ce-Fe magnetic interaction, which sets the temperature scale for the onset of long-range order, remains satisfied throughout the phase diagram but does not determine the magnetic ground state. Our results illustrate the complexity of a system with multiple competing magnetic energy scales and lead to a general model for magnetism in cubic Laves phase intermetallic compounds.

Wang, Jiyang; Feng, Yejun; Jaramillo, R.; van Wezel, Jasper; Canfield, Paul C.; Rosenbaum, T.F.

2012-07-20T23:59:59.000Z

135

Ion-Beam-Induced Chemical Mixing at a Nanocrystalline CeO2&ndash...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

microscopy imaging and analysis suggest that this band of contrast is a cerium silicate phase with an approximate Ce:Si:O composition ratio of 1:1:3 in an amorphous nature....

136

Data:B084b37a-3e1c-482d-8041-d7ce3e7aa0ce | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onb5-dcc1fcffd1f2 No revision has38865d08 No revision has been approved for this page.af74fa257cc No54a9102ce3e7aa0ce No

137

Data:Ce82df4d-c557-42d2-a1f3-ce3b159222ae | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onb5-dcc1fcffd1f2bb71-d4159a938742e80b26cc4 Nodbb-44ce-80f8-79eb97a58f0a No revisionde0244033 No revisiona1f3-ce3b159222ae

138

Electronic structure and f-orbital occupancy in Yb-substituted CeCoIn5  

SciTech Connect (OSTI)

The local structure and 4f orbital occupancy have been investigated in Ce{sub 1?x}Yb{sub x}CoIn{sub 5} via Yb L{sub III}-edge extended x-ray absorption fine structure (EXAFS), Ce and Yb L{sub III}-edge x-ray absorption near-edge structure (XANES), and angle-resolved photoemission spectroscopy (ARPES) measurements. Yb(III) (4f{sup 13}) is the hole analog of Ce(III) (4f{sup 1}). Yb is found to be strongly intermediate-valent in Ce{sub 1?x}Yb{sub x}CoIn{sub 5} throughout the entire doping range, including pure YbCoIn{sub 5}, with an f-hole occupancy for Yb of n{sub f} ? 0.3 (i.e. Yb{sup 2.3+}), independent of Yb concentration and independent of temperature down to T = 20 K. In contrast, the f-electron orbital occupancy for Ce remains close to 1 for all Yb concentrations, suggesting that there is no mutual influence on n{sub f} between neighboring Ce and Yb sites. Likewise, ARPES measurements at 12 K have found that the electronic structure along {Gamma} ? X is not sensitive to the Yb substitution, suggesting that the Kondo hybridization of Ce f electrons with the conduction band is not affected by the presence of Yb impurities in the lattice. The emerging picture is that in Ce{sub 1?x}Yb{sub x}CoIn{sub 5} there are two networks, interlaced but independent, that couple to the conduction band: one network of Ce ions in the heavy-fermion limit, one network of Yb ions in the strongly intermediate-valent limit. The robustness of the local and electronic structure to doping suggests the absence of charge transfer between the Ce and Yb ions, and may explain the relative robustness of superconductivity for this Ce-site substitution as compared to the In-site substitution.

Booth, C. H.; Durakiewicz, T.; Capan, C.; Hurt, D.; Bianchi, A. D.; Joyce, J.J.; Fisk, Z.

2011-05-03T23:59:59.000Z

139

582014-15 Suggested Course Plan CompuTeR sCIenCe  

E-Print Network [OSTI]

Algebra & Diff. Equations EE 364: Intro to Probability & Statistics or mATh 407: Probability Theory sCIenCe582014-15 Suggested Course Plan CompuTeR sCIenCe FIRST YEAR FALL: 16 units SPRING: 16 units SECOND104L,170 4 BASIC SCIENCE I 4 TECH. ELECTIVE I 4 TECH. ELECTIVE II 4 EE 364 MATH225or245 or MATH 407

Zhou, Chongwu

140

Nevada Division of Minerals | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth's HeatMexico: EnergyMithunCenter Jump to:2 Jump to:Minerals Name: Nevada

Note: This page contains sample records for the topic "mineral gadolinite ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

CeO2 and CuOx Interactions and the Controlled Assembly of CeO2(111) and CeO2(100) Nanoparticles on an Oxidized Cu(111)Substrate  

SciTech Connect (OSTI)

The catalytic performance of ceria-based heterogeneous catalysts in many chemical transformations (water-gas shift reaction, CO oxidation, alcohol synthesis from CO/CO{sub 2} hydrogenation, etc.) is affected by the surface structure of the ceria. To control the performance of ceria-containing inverse catalysts, we devised a method to grow ceria nanoparticles (NPs) exposing exclusively either (111) or (100) surfaces and characterized their surface structures by scanning tunneling microscopy. When cerium is vapor-deposited on Cu(111) in a background of molecular O{sub 2}, only CeO{sub 2}(111) NPs grow. However, if the surface of Cu(111) is preoxidized with O{sub 2} or NO{sub 2} to form a rectangular copper oxide phase, probably Cu{sub 4}O{sub 3}(001), CeO{sub 2}(100) NPs grow on the oxide template instead. These experimental findings are interpreted using results of density functional calculations. The (100) surface of bulk ceria reconstructs to preserve charge neutrality. This is not necessary for CeO{sub 2}(100) NPs grown on Cu{sub 4}O{sub 3}(001), where the topmost oxygen layer of Cu{sub 4}O{sub 3} is shared with the interfacial layer of cerium. After the CeO{sub 2}(100)/CuO{sub x}/Cu(111) surfaces were exposed to CO, the copper oxide was reduced but the shape of the CeO{sub 2}(100) NPs remained intact. This opens the door for diverse applications in catalysis.

Rodriguez J. A.; Yang F.; Choi Y.M.; Agnoli S.; Liu P.; Stacchiola D.; Hrbek J.

2011-11-24T23:59:59.000Z

142

Selective flotation of phosphate minerals with hydroxamate collectors  

DOE Patents [OSTI]

A method is disclosed for separating phosphate minerals from a mineral mixture, particularly from high-dolomite containing phosphate ores. The method involves conditioning the mineral mixture by contacting in an aqueous in environment with a collector in an amount sufficient for promoting flotation of phosphate minerals. The collector is a hydroxamate compound of the formula; ##STR1## wherein R is generally hydrophobic and chosen such that the collector has solubility or dispersion properties it can be distributed in the mineral mixture, typically an alkyl, aryl, or alkylaryl group having 6 to 18 carbon atoms. M is a cation, typically hydrogen, an alkali metal or an alkaline earth metal. Preferably, the collector also comprises an alcohol of the formula, R'--OH wherein R' is generally hydrophobic and chosen such that the collector has solubility or dispersion properties so that it can be distributed in the mineral mixture, typically an alkyl, aryl, or alkylaryl group having 6 to 18 carbon atoms.

Miller, Jan D. (Salt Lake City, UT); Wang, Xuming (Salt Lake City, UT); Li, Minhua (Salt Lake City, UT)

2002-01-01T23:59:59.000Z

143

New Geophysical Technique for Mineral Exploration and Mineral Discrimination Based on Electromagnetic Methods  

SciTech Connect (OSTI)

The research during the first two years of the project was focused on developing the foundations of a new geophysical technique for mineral exploration and mineral discrimination, based on electromagnetic (EM) methods. The developed new technique is based on examining the spectral induced polarization effects in electromagnetic data using effective-medium theory and advanced methods of 3-D modeling and inversion. The analysis of IP phenomena is usually based on models with frequency dependent complex conductivity distribution. In this project, we have developed a rigorous physical/mathematical model of heterogeneous conductive media based on the effective-medium approach. The new generalized effective-medium theory of IP effect (GEMTIP) provides a unified mathematical method to study heterogeneity, multi-phase structure, and polarizability of rocks. The geoelectrical parameters of a new composite conductivity model are determined by the intrinsic petrophysical and geometrical characteristics of composite media: mineralization and/or fluid content of rocks, matrix composition, porosity, anisotropy, and polarizability of formations. The new GEMTIP model of multi-phase conductive media provides a quantitative tool for evaluation of the type of mineralization, and the volume content of different minerals using electromagnetic data. We have developed a 3-D EM-IP modeling algorithm using the integral equation (IE) method. Our IE forward modeling software is based on the contraction IE method, which improves the convergence rate of the iterative solvers. This code can handle various types of sources and receivers to compute the effect of a complex resistivity model. We have demonstrated that the generalized effective-medium theory of induced polarization (GEMTIP) in combination with the IE forward modeling method can be used for rock-scale forward modeling from grain-scale parameters. The numerical modeling study clearly demonstrates how the various complex resistivity models manifest differently in the observed EM data. These modeling studies lay a background for future development of the IP inversion method, directed at determining the electrical conductivity and the intrinsic chargeability distributions, as well as the other parameters of the relaxation model simultaneously. The new technology introduced in this project can be used for the discrimination between uneconomic mineral deposits and the location of zones of economic mineralization and geothermal resources.

Michael S. Zhdanov

2009-03-09T23:59:59.000Z

144

SkyMine Carbon Mineralization Pilot Project  

SciTech Connect (OSTI)

This Topical Report addresses accomplishments achieved during Phase 2b of the SkyMine® Carbon Mineralization Pilot Project. The primary objectives of this project are to design, construct, and operate a system to capture CO2 from a slipstream of flue gas from a commercial coal-fired cement kiln, convert that CO2 to products having commercial value (i.e., beneficial use), show the economic viability of the CO2 capture and conversion process, and thereby advance the technology to the point of readiness for commercial scale demonstration and deployment. The overall process is carbon negative, resulting in mineralization of CO2 that would otherwise be released into the atmosphere. The project will also substantiate market opportunities for the technology by sales of chemicals into existing markets, and identify opportunities to improve technology performance and reduce costs at the commercial scale. The project is being conducted in two phases. The primary objectives of Phase 1 were to evaluate proven SkyMine® process chemistry for commercial pilot-scale operation and complete the preliminary design for the pilot plant to be built and operated in Phase 2, complete a NEPA evaluation, and develop a comprehensive carbon life cycle analysis. The objective of Phase 2b was to build the pilot plant to be operated and tested in Phase 2c.

Christenson, Norm; Walters, Jerel

2014-12-31T23:59:59.000Z

145

Mineral dissolution kinetics at the pore scale  

SciTech Connect (OSTI)

Mineral dissolution rates in the field have been reported to be orders of magnitude slower than those measured in the laboratory, an unresolved discrepancy that severely limits our ability to develop scientifically defensible predictive or even interpretive models for many geochemical processes in the earth and environmental sciences. One suggestion links this discrepancy to the role of physical and chemical heterogeneities typically found in subsurface soils and aquifers in producing scale-dependent rates where concentration gradients develop. In this paper, we examine the possibility that scale-dependent mineral dissolution rates can develop even at the single pore and fracture scale, the smallest and most fundamental building block of porous media. To do so, we develop two models to analyze mineral dissolution kinetics at the single pore scale: (1) a Poiseuille Flow model that applies laboratory-measured dissolution kinetics at the pore or fracture wall and couples this to a rigorous treatment of both advective and diffusive transport, and (2) a Well-Mixed Reactor model that assumes complete mixing within the pore, while maintaining the same reactive surface area, average flow rate, and geometry as the Poiseuille Flow model. For a fracture, a 1D Plug Flow Reactor model is considered in addition to quantify the effects of longitudinal versus transverse mixing. The comparison of averaged dissolution rates under various conditions of flow, pore size, and fracture length from the three models is used as a means to quantify the extent to which concentration gradients at the single pore and fracture scale can develop and render rates scale-dependent. Three important minerals that dissolve at widely different rates, calcite, plagioclase, and iron hydroxide, are considered. The modeling indicates that rate discrepancies arise primarily where concentration gradients develop due to comparable rates of reaction and advective transport, and incomplete mixing via molecular diffusion. The magnitude of the reaction rate is important, since it is found that scaling effects (and thus rate discrepancies) are negligible at the single pore and fracture scale for plagioclase and iron hydroxide because of the slow rate at which they dissolve. In the case of calcite, where dissolution rates are rapid, scaling effects can develop at high flow rates from 0.1 cm/s to 1000 cm/s and for fracture lengths less than 1 cm. At more normal flow rates, however, mixing via molecular diffusion is effective in homogenizing the concentration field, thus eliminating any discrepancies between the Poiseuille Flow and the Well-Mixed Reactor model. This suggests that a scale dependence to mineral dissolution rates is unlikely at the single pore or fracture scale under normal geological/hydrologic conditions, implying that the discrepancy between laboratory and field rates must be attributed to other factors.

Li, L.; Steefel, C.I.; Yang, L.

2007-05-24T23:59:59.000Z

146

Australasian Code for Reporting of Exploration Results, Mineral...  

Open Energy Info (EERE)

The Joint Ore Reserves Committee of The Australasian Institute of Mining and Metallurgy, Australian Institute of Geoscientists, and Minerals Council of Australia, 2012...

147

Coop: 02-2011 COLLEGE OF ENGINEERING AND MINERAL RESOURCES  

E-Print Network [OSTI]

Coop: 02-2011 COLLEGE OF ENGINEERING AND MINERAL RESOURCES COOPERATIVE EDUCATION PROGRAM STUDENT. DEPENDABILITY Reliable, prompt, trustworthy; meets obligations and follow directions. CREATIVITY Proposes ideas

Mohaghegh, Shahab

148

Reclamation of Land Used for Mineral Mining (Virginia)  

Broader source: Energy.gov [DOE]

This legislation aims to provide for the rehabilitation and conservation of land affected by the mining of minerals through proper planning, proper use of appropriate methods of mining,...

149

Potential of Mineral Uptake Efficiency by Some Apple Rootstocks  

E-Print Network [OSTI]

1999. Drought tolerance of apple rootstocks: Production andwater relations of five apple rootstocks. Acta Horticultureon Mineral Composition of Apple Leaves. J. Am. Soc. Hort.

Amiri, Mohammad E; Fallahi, Esmail

2009-01-01T23:59:59.000Z

150

arable mineral soils: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

year (tyr) of magnesium ferrosilicon, and 8,500 tyr of ferrosilicon (Globe Specialty Metals, inc 320 Placement of Mineral Trioxide Aggregate Using Two Different Techniques....

151

Mineral Association Changes the Secondary Structure and Dynamics...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Dynamics of Murine Amelogenin. Mineral Association Changes the Secondary Structure and Dynamics of Murine Amelogenin. Abstract: Biomineralization proteins, present during the...

152

Epithermal Gold Mineralization and a Geothermal Resource at Blue...  

Open Energy Info (EERE)

Epithermal Gold Mineralization and a Geothermal Resource at Blue Mountain, Humboldt County, Nevada Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal...

153

Oxygen And Carbon Isotope Ratios Of Hydrothermal Minerals From...  

Open Energy Info (EERE)

boiling or by isotopic exchange at low waterrock ratios in new fractures. The mineralogy and apparent 18O enrichments of hydrothermal fracture-filling minerals are...

154

New Geophysical Technique for Mineral Exploration and Mineral Discrimination Based on Electromagnetic Methods  

SciTech Connect (OSTI)

The research during the first year of the project was focused on developing the foundations of a new geophysical technique for mineral exploration and mineral discrimination, based on electromagnetic (EM) methods. The proposed new technique is based on examining the spectral induced polarization effects in electromagnetic data using modern distributed acquisition systems and advanced methods of 3-D inversion. The analysis of IP phenomena is usually based on models with frequency dependent complex conductivity distribution. One of the most popular is the Cole-Cole relaxation model. In this progress report we have constructed and analyzed a different physical and mathematical model of the IP effect based on the effective-medium theory. We have developed a rigorous mathematical model of multi-phase conductive media, which can provide a quantitative tool for evaluation of the type of mineralization, using the conductivity relaxation model parameters. The parameters of the new conductivity relaxation model can be used for discrimination of the different types of rock formations, which is an important goal in mineral exploration. The solution of this problem requires development of an effective numerical method for EM forward modeling in 3-D inhomogeneous media. During the first year of the project we have developed a prototype 3-D IP modeling algorithm using the integral equation (IP) method. Our IE forward modeling code INTEM3DIP is based on the contraction IE method, which improves the convergence rate of the iterative solvers. This code can handle various types of sources and receivers to compute the effect of a complex resistivity model. We have tested the working version of the INTEM3DIP code for computer simulation of the IP data for several models including a southwest US porphyry model and a Kambalda-style nickel sulfide deposit. The numerical modeling study clearly demonstrates how the various complex resistivity models manifest differently in the observed EM data. These modeling studies lay a background for future development of the IP inversion method, directed at determining the electrical conductivity and the intrinsic chargeability distributions, as well as the other parameters of the relaxation model simultaneously. The new technology envisioned in this proposal, will be used for the discrimination of different rocks, and in this way will provide an ability to distinguish between uneconomic mineral deposits and the location of zones of economic mineralization and geothermal resources.

Michael S. Zhdanov

2005-03-09T23:59:59.000Z

155

Enhanced oxygen storage capacity of Ce{sub 0.88}Mn{sub 0.12}O{sub y} compared to CeO{sub 2}: An experimental and theoretical investigation  

SciTech Connect (OSTI)

Graphical abstract: Display Omitted Highlights: ? Ce{sub 0.88}Mn{sub 0.12}O{sub y} and CeO{sub 2} hollow nanospheres were successfully prepared via a supercritical antisolvent process. ? Compared with the pure CeO{sub 2}, the Ce{sub 0.88}Mn{sub 0.12}O{sub y} has nearly the same surface area but more oxygen vacancies. ? DFT calculations shows that the surface oxygen of the CeO{sub 2} gets activated after doping Mn. -- Abstract: Ce{sub 0.88}Mn{sub 0.12}O{sub y} and CeO{sub 2} nanoparticles have been successfully prepared via a supercritical antisolvent process. High-resolution transmission electron microscopy displays the hollow and spherical structures of these nanoparticles. X-ray diffraction analysis demonstrates the formation of Ce{sub 0.88}Mn{sub 0.12}O{sub y} solid solution. N{sub 2} adsorption reveals that the Ce{sub 0.88}Mn{sub 0.12}O{sub y} has nearly the same surface area with the CeO{sub 2}. It is shown that the Ce{sub 0.88}Mn{sub 0.12}O{sub y} has higher oxygen storage capacity (OSC) than the CeO{sub 2}. To understand the mechanism of the improved OSC of the Mn doped CeO{sub 2}, Raman spectroscopy, X-ray photoelectron spectra and density functional theoretical (DFT) calculations have been performed. It is found that the Ce{sub 0.88}Mn{sub 0.12}O{sub y} presents more oxygen vacancies, indicating the easier of oxygen mobility from bulk to surface. DFT calculations reveal that structural and electronic modifications are caused by the incorporation of Mn in the CeO{sub 2}, resulting in activated oxygen species. The oxygen vacancy formation energy is lowered by the Mn doping. These changes are responsible for the enhanced OSC of the Ce{sub 0.88}Mn{sub 0.12}O{sub y}.

Zhang, Minhua; Jiang, Dongyu [Key Laboratory for Green Chemical Technology of Ministry of Education, R and D Center for Petrochemical Technology, Tianjin University, Tianjin 300072 (China)] [Key Laboratory for Green Chemical Technology of Ministry of Education, R and D Center for Petrochemical Technology, Tianjin University, Tianjin 300072 (China); Jiang, Haoxi, E-mail: hxjiang@tju.edu.cn [Key Laboratory for Green Chemical Technology of Ministry of Education, R and D Center for Petrochemical Technology, Tianjin University, Tianjin 300072 (China)] [Key Laboratory for Green Chemical Technology of Ministry of Education, R and D Center for Petrochemical Technology, Tianjin University, Tianjin 300072 (China)

2012-12-15T23:59:59.000Z

156

Respiratory disease in Utah coal miners  

SciTech Connect (OSTI)

Two hundred forty-two Utah underground coal miners volunteered to participate in a respiratory disease study. They were an older group (mean, 56 years of age) and had spent a mean of 29 years in the coal-mining industry. The prevalence of chronic bronchitis was 57%, and that of coal worker's pneumoconiosis, 25%; only one worker had progressive massive fibrosis. Significant impairment of pulmonary function was found among those with a history of cigarette smoking. Chronic bronchitis or coal worker's penumoconiosis among nonsmokers did not impair pulmonary function. There was a significant association among the nonsmokers between increasing exposure to coal dust and coal worker's pneumoconiosis, but not for changes in pulmonary function. Coal mine dust had a significant influence in causing the symptom complex of chronic cough and sputum production, and coal worker's pneumoconiosis.

Rom, W.N.; Kanner, R.E.; Renzetti, A.D. Jr.; Shigeoka, J.W.; Barkman, H.W.; Nichols, M.; Turner, W.A.; Coleman, M.; Wright, W.E.

1981-04-01T23:59:59.000Z

157

Respiratory disease in Utah coal miners  

SciTech Connect (OSTI)

Two hundred forty-two Utah underground coal miners volunteered to participate in a respiratory disease study. They were an older group (mean, 56 years of age) and had spent a mean of 29 years in the coal-mining industry. The prevalence of chronic bronchitis was 57%, and that of coal worker's pneumoconiosis, 25%; only one worker had progressive massive fibrosis. Significant impairment of pulmonary function was found among those with a history of cigarette smoking. Chronic bronchitis or coal worker's pneumoconiosis among nonsmokers did not impair pulmonary function. There was a significant association among the nonsmokers between increasing exposure to coal dust and coal worker's pneumoconiosis, but not for changes in pulmonary function. Coal mine dust had a significant influence in causing the symptom complex of chronic cough and sputum production, and coal worker's pneumoconiosis.

Rom, W.N.; Kanner, R.E.; Renzetti, A.D. Jr.; Shigeoka, J.W.; Barkman, H.W.; Nichols, M.; Turner, W.A.; Coleman, M.; Wright, W.E.

1981-04-01T23:59:59.000Z

158

ORIGINAL PAPER Comparison of manure compost and mineral fertilizer  

E-Print Network [OSTI]

ORIGINAL PAPER Comparison of manure compost and mineral fertilizer for hybrid poplar plantation and methods Composted sheep manure (10 and 20 kg/tree) at planting was compared to N and P mineral Contrary to what we expected, compost treatments neither increased root development nor tree water status

Paris-Sud XI, Université de

159

2011 Minerals Yearbook U.S. Department of the Interior  

E-Print Network [OSTI]

Resources Ltd.). DuPont produced zircon from its heavy-mineral sands operation near Starke, FL. Iluka2011 Minerals Yearbook U.S. Department of the Interior U.S. Geological Survey ZIRCONIUM AND HAFNIUM. In 2011, although the global economy continued to struggle, consumption of zirconium ores and concentrates

160

2009 Minerals Yearbook U.S. Department of the Interior  

E-Print Network [OSTI]

of australian company iluka resources Ltd.). duPont produced zircon from its heavy-mineral sands operation near2009 Minerals Yearbook U.S. Department of the Interior U.S. Geological Survey ZIRCONIUM AND HAFNIUM. in 2009, global economic conditions continued to depress zircon consumption. in response to decreased

Note: This page contains sample records for the topic "mineral gadolinite ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

2010 Minerals Yearbook U.S. Department of the Interior  

E-Print Network [OSTI]

subsidiary of Australian company Iluka Resources Ltd.). DuPont produced zircon from its heavy-mineral sands2010 Minerals Yearbook U.S. Department of the Interior U.S. Geological Survey ZIRCONIUM AND HAFNIUM. In 2010, the global economy began to recover, and consumption of zirconium ores and concentrates increased

162

Trans Boundary Transport of Pollutants by Atmospheric Mineral  

E-Print Network [OSTI]

Trans Boundary Transport of Pollutants by Atmospheric Mineral Dust Y I G A L E R E L , * , U R I D, and solid constituents in the atmosphere (3-11). Uptake of pollutants by mineral dust has been shown Jerusalem, Israel The transport of anthropogenic pollution by desert dust in the Eastern Mediterranean

Einat, Aharonov

163

Calcite Mineral Scaling Potentials of High-Temperature Geothermal Wells  

E-Print Network [OSTI]

#12;i Calcite Mineral Scaling Potentials of High-Temperature Geothermal Wells Alvin I. Remoroza-Temperature Geothermal Wells Alvin I. Remoroza 60 ECTS thesis submitted in partial fulfillment of a Magister Scientiarum #12;iv Calcite Mineral Scaling Potentials of High-Temperature Geothermal Wells 60 ECTS thesis

Karlsson, Brynjar

164

Proactive Design of n-Type (In, Ce) Filled Skutterudites Enabling High-Temperature Waste Heat Recovery  

Broader source: Energy.gov [DOE]

Thermoelectric and structural properties of n-type (In, Ce) filled skutterudites including power factors and ZT as a function of temperature are presented

165

Extension of lattice strain theory to mineral/mineral rare-earth element partitioning: An approach for assessing disequilibrium  

E-Print Network [OSTI]

Extension of lattice strain theory to mineral/mineral rare-earth element partitioning: An approach/melt parti- tion coefficients for rare-earth elements (REEs) in olivine and orthopyroxene to better 2006; accepted in revised form 20 September 2006 Abstract Olivine/melt and orthopyroxene/melt rare-earth

Lee, Cin-Ty Aeolus

166

Mechanism of Methane Chemical Looping Combustion with Hematite Promoted with CeO2  

SciTech Connect (OSTI)

Chemical looping combustion (CLC) is a promising technology for fossil fuel combustion that produces sequestration-ready CO{sub 2} stream, reducing the energy penalty of CO{sub 2} separation from flue gases. An effective oxygen carrier for CLC will readily react with the fuel gas and will be reoxidized upon contact with oxygen. This study investigated the development of a CeO{sub 2}-promoted Fe{sub 2}O{sub 3}?hematite oxygen carrier suitable for the methane CLC process. Composition of CeO{sub 2} is between 5 and 25 wt % and is lower than what is generally used for supports in Fe{sub 2}O{sub 3} carrier preparations. The incorporation of CeO{sub 2} to the natural ore hematite strongly modifies the reduction behavior in comparison to that of CeO{sub 2} and hematite alone. Temperature-programmed reaction studies revealed that the addition of even 5 wt % CeO{sub 2} enhances the reaction capacity of the Fe{sub 2}O{sub 3} oxygen carrier by promoting the decomposition and partial oxidation of methane. Fixed-bed reactor data showed that the 5 wt % cerium oxides with 95 wt % iron oxide produce 2 times as much carbon dioxide in comparison to the sum of carbon dioxide produced when the oxides were tested separately. This effect is likely due to the reaction of CeO{sub 2} with methane forming intermediates, which are reactive for extracting oxygen from Fe{sub 2}O{sub 3} at a considerably faster rate than the rate of the direct reaction of Fe{sub 2}O{sub 3} with methane. These studies reveal that 5 wt % CeO{sub 2}/Fe{sub 2}O{sub 3} gives stable conversions over 15 reduction/oxidation cycles. Lab-scale reactor studies (pulsed mode) suggest the methane reacts initially with CeO{sub 2} lattice oxygen to form partial oxidation products (CO + H{sub 2}), which continue to react with oxygen from neighboring Fe{sub 2}O{sub 3}, leading to its complete oxidation to form CO{sub 2}. The reduced cerium oxide promotes the methane decomposition reaction to form C + H{sub 2}, which continue to react with Fe{sub 2}O{sub 3}/Fe{sub 3}O{sub 4} to form CO/CO{sub 2} and H{sub 2}O. This mechanism is supported by the characterization studies, which also suggest that the formation of carbonaceous intermediates may affect the reaction rate and selectivity of the oxygen carrier.

Miller, Duane D.; Siriwardane, Ranjani

2013-08-01T23:59:59.000Z

167

DFT+U Study of CeO2 and Its Native Defects  

E-Print Network [OSTI]

in solid state fuel cells2, as a catalyst3-6, as a high-dielectric constant gate oxide7, and in resistance random access memories (ReRAM)8. Many properties of CeO2 are determined by its intrinsic defects9-23 and the unusual behavior of the semi-core Ce 4f... averaging scheme46 for spin- orbital coupling effect. The RRKJ method is chosen as optimization of pseudopotentials47. The PBE functional was chosen for PBE+U calculations with a kinetic cutoff energy of 750eV, which expands the valence electrons states...

Huang, Bolong; Gillen, Roland; Robertson, John

2014-10-14T23:59:59.000Z

168

Assessment of industrial minerals and rocks in the controlled area  

SciTech Connect (OSTI)

Yucca Mountain in Nye County, Nevada, is a potential site for a permanent repository for high-level nuclear waste in Miocene ash flow tuff. The Yucca Mountain controlled area occupies approximately 98 km{sup 2} that includes the potential repository site. The Yucca Mountain controlled area is located within the southwestern Nevada volcanic field, a large area of Miocene volcanism that includes at least four major calderas or cauldrons. It is sited on a remnant of a Neogene volcanic plateau that was centered around the Timber Mountain caldera complex. The Yucca Mountain region contains many occurrences of valuable or potentially valuable industrial minerals, including deposits with past or current production of construction aggregate, borate minerals, clay, building stone, fluorspar, silicate, and zeolites. The existence of these deposits in the region and the occurrence of certain mineral materials at Yucca Mountain, indicate that the controlled area may have potential for industrial mineral and rock deposits. Consideration of the industrial mineral potential within the Yucca Mountain controlled area is mainly based on petrographic and lithologic studies of samples from drill holes in Yucca Mountain. Clay minerals, zeolites, fluorite, and barite, as minerals that are produced economically in Nevada, have been identified in samples from drill holes in Yucca Mountain.

Castor, S.B. [Nevada Bureau of Mines and Geology, Reno, NV (United States); Lock, D.E. [Mackay School of Mines, Reno, NV (United States)

1996-08-01T23:59:59.000Z

169

Comparative Study on Redox Properties of Nanosized CeO2 and CuO/Ce2 Under CO/O2  

SciTech Connect (OSTI)

Nanosized CeO{sub 2} and CuO/CeO{sub 2} samples, active for CO-PROX or related processes were comparatively examined by O{sub 2} probe electron paramagnetic resonance and in situ Raman and X-ray diffraction techniques. Their behavior toward CO reduction, as well as the oxygen-handling properties of the CO-reduced samples, was explored. An appreciable reduction of the ceria bulk was detected on treatment under CO at 473 K. On the basis of the analysis of the evolution of different oxygen-derived species (superoxide, peroxide, O-) on low-temperature (77-300 K) oxygen chemisorption on the CO-reduced samples, a general picture of the redox properties of the samples is presented. Results demonstrate that the presence of copper promotes completion of the redox cycle under CO/O{sub 2} by favoring both ceria reduction and oxidation. This can be relevant to explaining the remarkable oxidation activity and synergetic effects observed for catalysts combining CuO and CeO{sub 2}.

Martinez-Arias,A.; Gamarra, D.; Fernandez-Garcia, M.; Wang, X.; Hanson, J.; Rodriguez, J.

2006-01-01T23:59:59.000Z

170

E-Print Network 3.0 - austrian mineral water Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

mines may affect air quality. As with water pollution, mines can contribute to air pollution... Chapter 15 Mineral Resources and the Environment 12;Minerals ... Source: Pan,...

171

E-Print Network 3.0 - african gold miners Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

in Peridotite: Alleghany... ultramafic wall rocks associated with Mother Lode-type hydrothermal gold-quartz vein mineralization... , gold, and associated minerals, and...

172

E-Print Network 3.0 - avoiding mineral pretreatment Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

their high mineral, especially nitrogen... , content, which is very useful in down-stream processing, since the utilisation of mineral nutrients Source: Ris National Laboratory...

173

E-Print Network 3.0 - areal bone mineral Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

(DXA)-derived areal bone mineral density (BMD) and reductions in vertebral fracture incidence... than the bone volume fraction (mineralized bone volumebulk volume).12...

174

E-Print Network 3.0 - affecting bone mineral Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of remodeling on the mineralization of bone... of therapies that reduce the risk of fracture, increase bone mineral density or change the biochemical markers... mass and...

175

E-Print Network 3.0 - activity bone mineral Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of remodeling on the mineralization of bone... of therapies that reduce the risk of fracture, increase bone mineral density or change the biochemical markers... mass and...

176

E-Print Network 3.0 - actinide pyrochlore minerals Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

minerals, Na- bearing carbonates, and Zr-bearing oxides... INTRODUCTION Titanite is one of the most common and paragenetically supple titanium minerals in the...

177

SkyMine Carbon Mineralization Pilot Project  

SciTech Connect (OSTI)

This Topical Report addresses accomplishments achieved during Phase 1 of the SkyMine{reg_sign} Carbon Mineralization Pilot Project. The primary objectives of this project are to design, construct, and operate a system to capture CO{sub 2} from a slipstream of flue gas from a commercial coal-fired cement kiln, convert that CO{sub 2} to products having commercial value (i.e., beneficial use), show the economic viability of the CO{sub 2} capture and conversion process, and thereby advance the technology to a point of readiness for commercial scale demonstration and proliferation. The project will also substantiate market opportunities for the technology by sales of chemicals into existing markets, and identify opportunities to improve technology performance and reduce costs at commercial scale. The primary objectives of Phase 1 of the project were to elaborate proven SkyMine{reg_sign} process chemistry to commercial pilot-scale operation and complete the preliminary design ('Reference Plant Design') for the pilot plant to be built and operated in Phase 2. Additionally, during Phase 1, information necessary to inform a DOE determination regarding NEPA requirements for the project was developed, and a comprehensive carbon lifecycle analysis was completed. These items were included in the formal application for funding under Phase 2. All Phase 1 objectives were successfully met on schedule and within budget.

Joe Jones; Clive Barton; Mark Clayton; Al Yablonsky; David Legere

2010-09-30T23:59:59.000Z

178

Integrating Steel Production with Mineral Carbon Sequestration  

SciTech Connect (OSTI)

The objectives of the project were (i) to develop a combination iron oxide production and carbon sequestration plant that will use serpentine ores as the source of iron and the extraction tailings as the storage element for CO2 disposal, (ii) the identification of locations within the US where this process may be implemented and (iii) to create a standardized process to characterize the serpentine deposits in terms of carbon disposal capacity and iron and steel production capacity. The first objective was not accomplished. The research failed to identify a technique to accelerate direct aqueous mineral carbonation, the limiting step in the integration of steel production and carbon sequestration. Objective (ii) was accomplished. It was found that the sequestration potential of the ultramafic resource surfaces in the US and Puerto Rico is approximately 4,647 Gt of CO2 or over 500 years of current US production of CO2. Lastly, a computer model was developed to investigate the impact of various system parameters (recoveries and efficiencies and capacities of different system components) and serpentinite quality as well as incorporation of CO2 from sources outside the steel industry.

Klaus Lackner; Paul Doby; Tuncel Yegulalp; Samuel Krevor; Christopher Graves

2008-05-01T23:59:59.000Z

179

Observation of Strong Resonant Behavior in the Inverse Photoelectron Spectroscopy of Ce Oxide  

SciTech Connect (OSTI)

X-ray Emission Spectroscopy (XES) and Resonant Inverse Photoelectron Spectroscopy (RIPES) have been used to investigate the photon emission associated with the Ce3d5/2 and Ce3d3/2 thresholds. Strong resonant behavior has been observed in the RIPES of Ce Oxide near the 5/2 and 3/2 edges. Inverse Photoelectron Spectroscopy (IPES) and its high energy variant, Bremstrahlung Isochromat Spectroscopy (BIS), are powerful techniques that permit a direct interrogation of the low-lying unoccupied electronic structure of a variety of materials. Despite being handicapped by counting rates that are approximately four orders of magnitude less that the corresponding electron spectroscopies (Photoelectron Spectroscopy, PES, and X-ray Photoelectron Spectroscopy, XPS) both IPES and BIS have a long history of important contributions. Over time, an additional variant of this technique has appeared, where the kinetic energy (KE) of the incoming electron and photon energy (hv) of the emitted electron are roughly the same magnitude as the binding energy of a core level of the material in question. Under these circumstances and in analogy to Resonant Photoelectron Spectroscopy, a cross section resonance can occur, giving rise to Resonant Inverse Photoelectron Spectroscopy or RIPES. Here, we report the observation of RIPES in an f electron system, specifically the at the 3d{sub 5/2} and 3d{sub 3/2} thresholds of Ce Oxide. The resonant behavior of the Ce4f structure at the 3d thresholds has been addressed before, including studies of the utilization of the technique as a probe of electron correlation in a variety of Ce compounds. Interestingly, the first RIPES work on rare earths dates back to 1974, although under conditions which left the state of the surface and near surface regions undefined. Although they did not use the more modern terminology of 'RIPES,' it is clear that RIPES was actually first performed in 1974 by Liefeld, Burr and Chamberlain on both La and Ce based materials. In these experiments, the La and Ce metallic samples were attached to the anode of an x-ray tube and the x-ray emission characteristics were measured using a two crystal monochromator. The pressure in the x-ray tube was quoted as being below 2 x 10{sup -8} Torr. They did indeed observed resonant behavior at the M{alpha} (3d{sub 5/2}) and M{beta} (3d{sub 3/2}) thresholds. In fact, our results here will confirm the measurements made upon the Ce based sample used in by Liefeld et al. However, the state of the Ce sample surface and near surface regions are quite undefined in the study in Ref 9. For example, the authors suggest that they are probing Ce metal, since they cannot see any evidence of an OK{alpha} (1s) XES line. However, they do report the observation of FK{alpha} (1s) line, possibly due to the utilization of cerium fluoride in the sample preparation. Later, they tried to address these issues in a new ultrahigh vacuum system. Based upon our results, it is clear that their original sample surface was oxidized, using the word here in its more general context as in having lost electrons to the oxidizing agent, although whether the structure is an oxide or fluoride remains unclear. In any case, the primacy of Liefeld and coworkers in these measurements should be noted. Cerium and cerium oxide have been studied with a variety of spectroscopic techniques under UHV conditions. This includes Bremstrahlung Isochromat Spectroscopy or BIS, Photoelectron Spectroscopy, X-ray Absorption Spectroscopy, Electron Energy Loss Spectroscopy and Resonant XES, to name just a few. We will compare our results to those of other spectroscopies.

Tobin, J G; Yu, S W; Chung, B W; Waddill, G D; Damian, E; Duda, L; Nordgren, J

2009-12-15T23:59:59.000Z

180

Mineral Deformation at Earth's Core-Mantle Boundary  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment SurfacesResource Program PreliminaryA3,0 Alabama - Natural GasMineralMineralMineral

Note: This page contains sample records for the topic "mineral gadolinite ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Overseas Affairs and Planning Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University  

E-Print Network [OSTI]

Contact: Overseas Affairs and Planning Institute for Integrated Cell-Material Sciences (i Cell-Material Sciences, iCeMS for short, I welcome you to the Seventh iCeMS International Symposium to develop them through evolution. They are also very important to design and create various novel "smart

Takada, Shoji

182

Laser Surface Modification of a Crystalline Al-Co-Ce Alloy for Enhanced Corrosion  

E-Print Network [OSTI]

#12;Laser Surface Modification of a Crystalline Al-Co-Ce Alloy for Enhanced Corrosion Resistance hardness, structure manipula- tion, and improvements in corrosion resistance of metallic materials.[1 surface modify steel and aluminum alloys for improved corrosion resistance.[3,4] The enhanced corrosion

Fitz-Gerald, James M.

183

Logiciel de Gestion de Version Qu'est-ce qu'un Version Control System (VCS) ?  

E-Print Network [OSTI]

Logiciel de Gestion de Version Git Qu'est-ce qu'un Version Control System (VCS) ? Appelé également Logiciel de Gestion de Révision (RCS), un VCS est un outil qui permet de : · de suivre l'évolution d revenir en arrière en cas de problème ; · de retenir qui a effectué chaque modification de chaque fichier

Tichit, Laurent

184

CeSOS Highlights and AMOS Visions 27-29th May 2013 Aurlien Babarit  

E-Print Network [OSTI]

2013 Criteria for comparison > The true criterion is cost of kWh. > kWh (power production) can absorption · Income side of COE · The higher the power absorption per unit, the less the installation cost a limit to the allowed cost for viability #12;A. Babarit CeSOS Highlights and AMOS Visions ­ 27-29th May

Nørvåg, Kjetil

185

COMMENT LES NANOTUBES DE CARBONE INTERAGISSENT AVEC LES MACROPHAGES : CE QUE NOUS DIT LA MICROFLUORESCENCE X  

E-Print Network [OSTI]

COMMENT LES NANOTUBES DE CARBONE INTERAGISSENT AVEC LES MACROPHAGES : CE QUE NOUS DIT LA. Boczkowski (INSERM). Réf. : Nano Lett. 8 (9), 2659-2663 (2008). Les nanotubes de carbone présentent des utilisée jusqu'alors pour étudier des nanotubes de carbone. Nous avons choisi d'étudier différentes sortes

Paris-Sud 11, Université de

186

In situ corrosion analysis of Al-Zn-In-Mg-Ti-Ce sacrificial anode alloy  

SciTech Connect (OSTI)

The corrosion behaviour of Al-5Zn-0.02In-1Mg-0.05Ti-0.5Ce (wt.%) alloy has been investigated by immersion test, scanning electron microscopy, energy dispersive X-ray detector, electrochemical impedance spectroscopy and electrochemical noise. The results show that there exist different corrosion types of the alloy in 3.5% NaCl solution with the immersion time. At the initial stage of immersion, pitting due to the precipitates predominates the corrosion with a typical inductive loop at low frequencies in electrochemical impedance spectroscopy. The major precipitates of the alloy are MgZn{sub 2} and Al{sub 2}CeZn{sub 2} particles. The corrosion potentials of the bulk MgZn{sub 2} and Al{sub 2}CeZn{sub 2} alloys are negative with respect to that of {alpha}-Al, so the MgZn{sub 2} and Al{sub 2}CeZn{sub 2} precipitates can act as activation centre and cause the pitting. In the late corrosion, a relative uniform corrosion predominates the corrosion process controlled by the dissolution/precipitation of the In ions and characterized by a capacitive loop at medium-high frequencies in electrochemical impedance spectroscopy. The potential noise of the pitting shows larger amplitude fluctuation and lower frequency, but the potential noise of the uniform corrosion occurs with smaller amplitude fluctuation and higher frequency.

Ma Jingling, E-mail: majingling.student@sina.com; Wen Jiuba; Zhai Wenxia; Li Quanan

2012-03-15T23:59:59.000Z

187

The CompuTer SCienCe program The bachelor of science degree in computer science  

E-Print Network [OSTI]

The CompuTer SCienCe program The bachelor of science degree in computer science offered by the Watson School is accredited by the Computing Accreditation Commission of ABET Inc. (mailing address: 111 in the fundamentals of computer science, elements of practical application and an appreciation for liberal learning

Suzuki, Masatsugu

188

Energy Based Methods in Wind Turbine Control CeSOS Highlights and AMOS Visions  

E-Print Network [OSTI]

Energy Based Methods in Wind Turbine Control CeSOS Highlights and AMOS Visions Morten D. Pedersen 1 / 26 #12;This talk 1 Background 2 Understanding the Wind Turbine 3 Nonlinear Turbine Modeling 4;Background The Problem Previously stable wind turbine systems began exhibiting resonant behavior when put

Nørvåg, Kjetil

189

CE990 Graduate Seminar Presentations The presentation materials shown in this file were prepared by graduate  

E-Print Network [OSTI]

cord · 10% fabric 4 #12;Thermal ConductivityThermal Conductivity · Low thermal conductivity of 0.242W conventional aggregatesconventional aggregates 5 #12;Thermal ConductivityThermal Conductivity ··Shredded tireCE990 Graduate Seminar Presentations DISCLAIMER The presentation materials shown in this file were

Saskatchewan, University of

190

Author's personal copy Prepration and photoluminescence properties of Ce doped lutetium silicate  

E-Print Network [OSTI]

Author's personal copy Prepration and photoluminescence properties of Ce doped lutetium silicate silicate Cerium Solegel Photoluminescence Lu2SiO5 a b s t r a c t Cerium doped lutetium silicate powders%). The synthesized lutetium silicate powders were investigated by X-ray diffraction (XRD), TG-DTA, SEM

Cao, Guozhong

191

A Review Of Water Contents Of Nominally Anhydrous Natural Minerals...  

Open Energy Info (EERE)

Water Contents Of Nominally Anhydrous Natural Minerals In The Mantles Of Earth, Mars And The Moon Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal...

192

An Overview of Hydrothermal Alteration and Vein Mineralization...  

Open Energy Info (EERE)

Vein Mineralization in Continental Scientific Drilling Program Core Hole VC-2B, Valles Caldera, New Mexico Jump to: navigation, search OpenEI Reference LibraryAdd to library...

193

Hyperspectral mineral mapping in support of geothermal exploration...  

Open Energy Info (EERE)

mineral mapping in support of geothermal exploration- Examples from Long Valley Caldera, CA and Dixie Valley, NV, USA Jump to: navigation, search OpenEI Reference LibraryAdd to...

194

Select Minerals and Potable Use of Reclaimed Wastewaters  

E-Print Network [OSTI]

The long-observed relationships of an influence of drinking water mineral content on heart-circulatory deaths are developed to indicate that sodium -- when present in sufficiently high concentrations -- may be detrimental to human health...

Wolf, H.

195

Hyperspectral Mineral Mapping For Geothermal Exploration On The...  

Open Energy Info (EERE)

and X-ray diffraction analyses of samples collected in the field. We are in the process of producing and validating mineral maps that will be used to narrow the scope of...

196

U.S. Geological Survey China's Growing Appetite for Minerals  

E-Print Network [OSTI]

: Coal 45 1 Oil 4.7 6 Industrial minerals: Cement 42 1 Fluorspar 55 1 Rare earths 85 1 Metals: Aluminum Republic of Korea Thailand Other Asian Crisis 1997 #12;Production Flow for Cement #12;Country-Level Ou

197

Unusual Physical and Chemical Properties of Cu in Ce1-xCuxO2 Oxides  

SciTech Connect (OSTI)

The structural and electronic properties of Ce{sub 1-x}Cu{sub x}O{sub 2} nano systems prepared by a reverse microemulsion method were characterized with synchrotron-based X-ray diffraction, X-ray absorption spectroscopy, Raman spectroscopy, and density functional calculations. The Cu atoms embedded in ceria had an oxidation state higher than those of the cations in Cu{sub 2}O or CuO. The lattice of the Ce{sub 1-x}Cu{sub x}O{sub 2} systems still adopted a fluorite-type structure, but it was highly distorted with multiple cation-oxygen distances with respect to the single cation-oxygen bond distance seen in pure ceria. The doping of CeO{sub 2} with copper introduced a large strain into the oxide lattice and favored the formation of O vacancies, leading to a Ce{sub 1-x}Cu{sub x}O{sub 2-y} stoichiometry for our materials. Cu approached the planar geometry characteristic of Cu(II) oxides, but with a strongly perturbed local order. The chemical activities of the Ce{sub 1-x}Cu{sub x}O{sub 2} nanoparticles were tested using the reactions with H2 and O2 as probes. During the reduction in hydrogen, an induction time was observed and became shorter after raising the reaction temperature. The fraction of copper that could be reduced in the Ce{sub 1-x}Cu{sub x}O{sub 2} oxides also depended strongly on the reaction temperature. A comparison with data for the reduction of pure copper oxides indicated that the copper embedded in ceria was much more difficult to reduce. The reduction of the Ce{sub 1-x}Cu{sub x}O{sub 2} nanoparticles was rather reversible, without the generation of a significant amount of CuO or Cu{sub 2}O phases during reoxidation. This reversible process demonstrates the unusual structural and chemical properties of the Cu-doped ceria materials.

Wang,X.; Rodriguez, J.; Hanson, J.; Gamarra, D.; Martinez-Arias, A.; Fernandez-Garcia, M.

2005-01-01T23:59:59.000Z

198

Inducing Mineral Precipitation in Groundwater by Addition of Phosphate  

SciTech Connect (OSTI)

Induced precipitation of phosphate minerals to scavenge trace metals and radionuclides from groundwater is a potential remediation approach for contaminated aquifers. Phosphate minerals can sequester trace elements by primary mineral formation, solid solution formation and/or adsorption, and they are poorly soluble under many environmental conditions, making them attractive for long-term sustainable remediation. The success of such engineered schemes will depend on the particular mineral phases generated, their rates of formation, and their long term stability. The purpose of this study was to examine the precipitation of calcium phosphate minerals under conditions representative of a natural groundwater. Because microorganisms are present in groundwater, and because some proposed schemes for induced phosphate mineral precipitation rely on the stimulation of native groundwater populations, we also tested the effect of bacterial cells (initial densities of 105 and 107 ml-1) within the precipitation medium. We also tested the effect of a trace mixture of propionic, isovaleric, formic and butyric acids (total concentration 0.035 mM). The experiments showed that the general progression of mineral precipitation was similar under all of the conditions, with initial formation of amorphous calcium carbonate, and transformation to poorly crystalline hydroxyapatite (HAP) by the end of the week-long experiments. The presence of the bacterial cells appeared to delay precipitation, although by the end of 7 days the overall extent of precipitation was similar for all of the treatments. The stoichiometry of the final precipitates as well as results of Rietveld refinement of x-ray diffraction data indicated that the treatments including organic acids and bacterial cells resulted in increased distortion of the HAP crystal lattice, with the higher concentration of cells resulting in the greatest distortion. Uptake of Sr into the phosphate minerals was decreased in the treatments with cells and organic acids, compared to the control. The results of the experiments enable a greater understanding of the challenges associated with phosphate-based remediation schemes for contaminated environments.

Karen E. Wright; Yoshiko Fujita; Thomas Hartmann; Mark Conrad

2011-10-01T23:59:59.000Z

199

Phase relations and crystal structures in the system Ce-Ni-Zn at 800 Degree-Sign C  

SciTech Connect (OSTI)

Phase relations have been established for the system Ce-Ni-Zn in the isothermal section at 800 Degree-Sign C using electron microprobe analysis and X-ray powder diffraction. Phase equilibria at 800 Degree-Sign C are characterized by a large region for the liquid phase covering most of the Ce-rich part of the diagram, whereas a Zn-rich liquid is confined to a small region near the Zn-corner of the Gibbs triangle. Whereas solubility of Ce in the binary Ni-Zn phases is negligible, mutual solubilities of Ni and Zn at a constant Ce content are large at 800 Degree-Sign C for most Ce-Zn and Ce-Ni compounds. The solid solution Ce(Ni{sub 1-x}Zn{sub x}){sub 5} with the CaCu{sub 5}-type is continuous throughout the entire section and for the full temperature region from 400 to 800 Degree-Sign C. Substitution of Zn by Ni is found to stabilize the structure of CeZn{sub 11} to higher temperatures. At 800 Degree-Sign C Ce(Ni{sub x}Zn{sub 1-x}){sub 11} (0.03{<=}x{<=}0.22) appears as a ternary solution phase. Similarly, a rather extended solution forms for Ce{sub 2}(Ni{sub x}Zn{sub 1-x}){sub 17} (0{<=}x{<=}0.53). Detailed data on atom site occupation and atom parameters were derived from X-ray structure analyses for single crystals of Ce{sub 2+y}(Ni{sub x}Zn{sub 1-x}){sub 17}, y=0.02, x=0.49 (a=0.87541(3), c=1.25410(4) nm; Th{sub 2}Zn{sub 17} type with space group R3{sup Macron }m,R{sub F{sup 2}}=0.018) and Ce(Ni{sub 0.18}Zn{sub 0.82}){sub 11} (a=1.04302(2), c=0.67624(3)nm, BaCd{sub 11} type with space group I4{sub 1}/amd, R{sub F{sup 2}}=0.049). - Graphical abstract: Ce-Ni-Zn isothermal section at 800 Degree-Sign C. Highlights: Black-Right-Pointing-Pointer Phase relations were determined for the system Ce-Ni-Zn in the section at 800 Degree-Sign C. Black-Right-Pointing-Pointer A continuous solid solution Ce(Ni{sub 1-x}Zn{sub x}){sub 5}, 0{<=}x{<=}1, forms between 400 and 800 Degree-Sign C. Black-Right-Pointing-Pointer Zn/Ni substitution stabilizes the ternary phase Ce(Zn{sub 1-x}Ni{sub x}){sub 11}, 0.03{<=}x{<=}0.22, 800 Degree-Sign C. Black-Right-Pointing-Pointer An extended solution forms for Ce{sub 2}(Ni{sub x}Zn{sub 1-x}){sub 17} (0{<=}x{<=}0.53). Black-Right-Pointing-Pointer Crystal data are given: Ce{sub 2+y}(Ni{sub x}Zn{sub 1-x}){sub 17} (Th{sub 2}Zn{sub 17}), Ce(Ni{sub 0.18}Zn{sub 0.82}){sub 11} (BaCd{sub 11}).

Malik, Z.; Grytsiv, A. [Institute of Physical Chemistry, University of Vienna, Waehringerstrasse 42, A-1090 Vienna (Austria)] [Institute of Physical Chemistry, University of Vienna, Waehringerstrasse 42, A-1090 Vienna (Austria); Rogl, P., E-mail: peter.franz.rogl@univie.ac.at [Institute of Physical Chemistry, University of Vienna, Waehringerstrasse 42, A-1090 Vienna (Austria); Giester, G. [Institute of Mineralogy and Crystallography, University of Vienna, Althanstrasse 14, A-1090 Vienna (Austria)] [Institute of Mineralogy and Crystallography, University of Vienna, Althanstrasse 14, A-1090 Vienna (Austria)

2012-10-15T23:59:59.000Z

200

A NOVEL APPROACH TO MINERAL CARBONATION: ENHANCING CARBONATION WHILE AVOIDING MINERAL PRETREATMENT PROCESS COST  

SciTech Connect (OSTI)

Known fossil fuel reserves, especially coal, can support global energy demands for centuries to come, if the environmental problems associated with CO{sub 2} emissions can be overcome. Unlike other CO{sub 2} sequestration candidate technologies that propose long-term storage, mineral sequestration provides permanent disposal by forming geologically stable mineral carbonates. Carbonation of the widely occurring mineral olivine (e.g., forsterite, Mg{sub 2}SiO{sub 4}) is a large-scale sequestration process candidate for regional implementation, which converts CO{sub 2} into the environmentally benign mineral magnesite (MgCO{sub 3}). The primary goal is cost-competitive process development. As the process is exothermic, it inherently offers low-cost potential. Enhancing carbonation reactivity is key to economic viability. Recent studies at the U.S. DOE Albany Research Center have established that aqueous-solution carbonation using supercritical CO{sub 2} is a promising process; even without olivine activation, 30-50% carbonation has been achieved in an hour. Mechanical activation (e.g., attrition) has accelerated the carbonation process to an industrial timescale (i.e., near completion in less than an hour), at reduced pressure and temperature. However, the activation cost is too high to be economical and lower cost pretreatment options are needed. Herein, we report our first year progress in exploring a novel approach that offers the potential to substantially enhance carbonation reactivity while bypassing pretreatment activation. We have discovered that robust silica-rich passivating layers form on the olivine surface during carbonation. As carbonation proceeds, these passivating layers thicken, fracture and eventually exfoliate, exposing fresh olivine surfaces during rapidly-stirred/circulating carbonation. We are exploring the mechanisms that govern carbonation reactivity and the impact that (1) modeling/controlling the slurry fluid-flow conditions, (2) varying the aqueous ion species/size and concentration (e.g., Li{sup +}, Na{sup +}, K{sup +}, Rb{sup +}, Cl{sup -}, HCO{sub 3}{sup -}), and (3) incorporating select sonication offer to enhance exfoliation and carbonation. Thus far, we have succeeded in nearly doubling the extent of carbonation observed compared with the optimum procedure previously developed by the Albany Research Center. Aqueous carbonation reactivity was found to be a strong function of the ionic species present and their aqueous activities, as well as the slurry fluid flow conditions incorporated. Synergistic control of these parameters offers the potential for further improvements in carbonation reactivity. A new sonication exfoliation system incorporating a novel sealing system was developed to carry out the sonication studies. Our initial studies that incorporate controlled sonication have not yet lead to a significant improvement in the extent of carbonation observed. Year 2 studies will emphasize those approaches that offer the greatest potential to cost effectively enhance carbonation, as well as combined approaches that may further enhance carbonation. Mechanistic investigations indicate incongruent dissolution results in the observed silica-rich passivating layer formation. Observations of magnesite nanocrystals within the passivating layers that form indicate the layers can exhibit significant permeability to the key reactants present (e.g., Mg{sup 2+}, H{sup +}, H{sub 2}O, CO{sub 2}, and HCO{sub 3} -). Atomistic modeling supports the observation of robust passivating layers that retain significant permeability to the key reaction species involved. Studies in Year 2 will emphasize the impact that controlled aqueous speciation and activity and slurry-flow dynamics have on the mechanisms that control carbonation reactivity and the potential they offer to substantially reduce olivine mineral sequestration process cost.

Michael J. McKelvy; Andrew V.G. Chizmeshya; Kyle Squires; Ray W. Carpenter; Hamadallah Bearat

2005-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "mineral gadolinite ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Size Effect on Nuclear Gamma-Ray Energy Spectra Acquired by Different Sized CeBr3, LaBr3:Ce, and NaI:Tl Gamma-Ray Detectors  

SciTech Connect (OSTI)

Gamma-ray energy spectra were acquired for different sizes of cerium tribromide (CeBr3), cerium-doped lanthanum tribromide (LaBr3:Ce), and thallium-doped sodium iodide (NaI:Tl) detectors. A comparison was conducted of the energy resolution and detection efficiency of these scintillator detectors for different sizes of detectors. The results of this study are consistent with the observation that for each size detector, LaBr3:Ce offers better resolution than either a CeBr3 or NaI:Tl detector of the same size. In addition, CeBr3 and LaBr3:Ce detectors could resolve some closely spaced peaks in the spectra of several radioisotopes that NaI:Tl could not. As the detector size increased, all three detector materials exhibited higher efficiency, albeit with slightly reduced resolution. Significantly, the very low intrinsic activity of CeBr3 is also demonstrated in this study, which, when combined with energy resolution characteristics for a range of detector sizes, could lead to an improved ability to detect special nuclear materials compared to the other detectors.

Guss, Paul [NSTec; Reed, Michael [NSTec; Yuan, Ding [NSTec; Beller, Denis [UNLV; Cutler, Matthew [UNLV; Contreras, Chris [UNLV; Mukhopadhyay, Sanjoy [NSTec; Wilde, Scott UNLV

2014-03-01T23:59:59.000Z

202

Sustainable Development Indicators 353 In the Mineral Industries, Milos 2003, Greece  

E-Print Network [OSTI]

Sustainable Development Indicators 353 In the Mineral Industries, Milos 2003, Greece Sustainable technologies in the sustainable development of mineral resources. 1. INTRODUCTION The design of surface mineral operations must balance mine planning with the principles of sustainable development of mineral resources

203

Data:678ce1a9-73c5-4299-aa54-b70f702c53ce | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office695810186 No revision has been approvedea02758d3 No revision has1574de6f No revisionb70f702c53ce No revision has

204

Data:Ce155644-3dbb-44ce-80f8-79eb97a58f0a | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onb5-dcc1fcffd1f2bb71-d4159a938742e80b26cc4 Nodbb-44ce-80f8-79eb97a58f0a No revision has been approved for this page. It

205

A Novel Approach to Mineral Carbonation: Enhancing Carbonation While Avoiding Mineral Pretreatment Process Cost  

SciTech Connect (OSTI)

Known fossil fuel reserves, especially coal, can support global energy demands for centuries to come, if the environmental problems associated with CO{sub 2} emissions can be overcome. Unlike other CO{sub 2} sequestration candidate technologies that propose long-term storage, mineral sequestration provides permanent disposal by forming geologically stable mineral carbonates. Carbonation of the widely occurring mineral olivine (e.g., forsterite, Mg{sub 2}SiO{sub 4}) is a large-scale sequestration process candidate for regional implementation, which converts CO{sub 2} into the environmentally benign mineral magnesite (MgCO{sub 3}). The primary goal is cost-competitive process development. As the process is exothermic, it inherently offers low-cost potential. Enhancing carbonation reactivity is key to economic viability. Recent studies at the U.S. DOE Albany Research Center have established that aqueous-solution carbonation using supercritical CO{sub 2} is a promising process; even without olivine activation, 30-50% carbonation has been achieved in an hour. Mechanical activation (e.g., attrition) has accelerated the carbonation process to an industrial timescale (i.e., near completion in less than an hour), at reduced pressure and temperature. However, the activation cost is too high to be economical and lower cost pretreatment options are needed. We have discovered that robust silica-rich passivating layers form on the olivine surface during carbonation. As carbonation proceeds, these passivating layers thicken, fracture and eventually exfoliate, exposing fresh olivine surfaces during rapidly-stirred/circulating carbonation. We are exploring the mechanisms that govern carbonation reactivity and the impact that (1) modeling/controlling the slurry fluid-flow conditions, (2) varying the aqueous ion species/size and concentration (e.g., Li+, Na+, K+, Rb+, Cl-, HCO{sub 3}{sup -}), and (3) incorporating select sonication offer to enhance exfoliation and carbonation. Thus far, we have succeeded in nearly doubling the extent of carbonation observed compared with the optimum procedure previously developed by the Albany Research Center. Aqueous carbonation reactivity was found to be a strong function of the ionic species present and their aqueous activities, as well as the slurry fluid flow conditions incorporated. High concentration sodium, potassium, and sodium/potassium bicarbonate aqueous solutions have been found to be the most effective solutions for enhancing aqueous olivine carbonation to date. Slurry-flow modeling using Fluent indicates that the slurry-flow dynamics are a strong function of particle size and mass, suggesting that controlling these parameters may offer substantial potential to enhance carbonation. During the first project year we developed a new sonication exfoliation apparatus with a novel sealing system to carry out the sonication studies. We also initiated investigations to explore the potential that sonication may offer to enhance carbonation reactivity. During the second project year, we extended our investigations of the effects of sonication on the extent of carbonation as a function of the following parameters: particle size distribution, the mass of solid reactant, volume fraction of aqueous solution present, sonication power, time, temperature, and CO{sub 2} pressure. To date, none of the conditions investigated have significantly enhanced carbonation. Mechanistic investigations of the stirred ({approx}1,500 rpm) aqueous olivine carbonation process indicate the carbonation process involves both incongruent magnesium dissolution and silica precipitation, which results in robust silica-rich passivating layer formation. Secondary ion mass spectrometry observation of H within the passivating layer that forms during static carbonation suggests 2H{sup +}/Mg{sup 2+} ion exchange is associated with incongruent dissolution. Apparently, H{sub 2}O forms at or near the olivine/passivating-layer interface during the process and diffuses out through the passivating layers during the carbonation reaction. This is

Andrew V. G. Chizmeshya; Michael J. McKelvy; Kyle Squires; Ray W. Carpenter; Hamdallah Bearat

2007-06-21T23:59:59.000Z

206

A Novel Approach To Mineral Carbonation: Enhancing Carbonation While Avoiding Mineral Pretreatment Process Cost  

SciTech Connect (OSTI)

Known fossil fuel reserves, especially coal, can support global energy demands for centuries to come, if the environmental problems associated with CO{sub 2} emissions can be overcome. Unlike other CO{sub 2} sequestration candidate technologies that propose long-term storage, mineral sequestration provides permanent disposal by forming geologically stable mineral carbonates. Carbonation of the widely occurring mineral olivine (e.g., forsterite, Mg{sub 2}SiO{sub 4}) is a large-scale sequestration process candidate for regional implementation, which converts CO{sub 2} into the environmentally benign mineral magnesite (MgCO{sub 3}). The primary goal is cost-competitive process development. As the process is exothermic, it inherently offers low-cost potential. Enhancing carbonation reactivity is key to economic viability. Recent studies at the U.S. DOE Albany Research Center have established that aqueous-solution carbonation using supercritical CO{sub 2} is a promising process; even without olivine activation, 30-50% carbonation has been achieved in an hour. Mechanical activation (e.g., attrition) has accelerated the carbonation process to an industrial timescale (i.e., near completion in less than an hour), at reduced pressure and temperature. However, the activation cost is too high to be economical and lower cost pretreatment options are needed. Herein, we report our second year progress in exploring a novel approach that offers the potential to substantially enhance carbonation reactivity while bypassing pretreatment activation. As our second year progress is intimately related to our earlier work, the report is presented in that context to provide better overall understanding of the progress made. We have discovered that robust silica-rich passivating layers form on the olivine surface during carbonation. As carbonation proceeds, these passivating layers thicken, fracture and eventually exfoliate, exposing fresh olivine surfaces during rapidly-stirred/circulating carbonation. We are exploring the mechanisms that govern carbonation reactivity and the impact that (i) modeling/controlling the slurry fluid-flow conditions, (ii) varying the aqueous ion species/size and concentration (e.g., Li{sup +}, Na{sup +}, K{sup +}, Rb{sup +}, Cl{sup -}, HCO{sub 3}{sup -}), and (iii) incorporating select sonication offer to enhance exfoliation and carbonation. We have succeeded in nearly doubling the extent of carbonation observed compared with the optimum procedure previously developed by the Albany Research Center. Aqueous carbonation reactivity was found to be a strong function of the ionic species present and their aqueous activities, as well as the slurry fluid flow conditions incorporated. High concentration sodium, potassium, and sodium/potassium bicarbonate aqueous solutions have been found to be the most effective solutions for enhancing aqueous olivine carbonation to date. Slurry-flow modeling using Fluent indicates that the slurry-flow dynamics are a strong function of particle size and mass, suggesting that controlling these parameters may offer substantial potential to enhance carbonation. Synergistic control of the slurry-flow and aqueous chemistry parameters offers further potential to improve carbonation reactivity, which is being investigated during the no-cost extension period. During the first project year we developed a new sonication exfoliation system with a novel sealing system to carry out the sonication studies. We also initiated(Abstract truncated).

Michael J. McKelvy; Andrew V. G. Chizmeshya; Kyle Squires; Ray W. Carpenter; Hamdallah Bearat

2006-06-21T23:59:59.000Z

207

Minerals leached into drinking water from rubber stoppers  

SciTech Connect (OSTI)

Drinking water and its delivery system are potential sources of variation in animal research. Concern arose that rubber stoppers used to cork water bottles might be a source of some nutritionally required minerals which could leach into drinking water. Six types of stoppers, each having different compositions, were cleaned with stainless-steel sipper tubes inserted into them and attached to polypropylene bottles filled with either deionized water (pH 4.5) or acidified-deionized water (pH 2.5). After six days of contact, water levels of copper, magnesium, iron, manganese, zinc, chromium, and selenium were determined by atomic absorption spectroscopy. Additionally, three of the stopper types were analyzed for mineral content. Minerals were present in both stoppers and drinking water. Acidified-deionized water generally leached minerals from the stoppers than did deionized water. The black stopper which is commonly used in animal facilities contained and leached measurable levels of some minerals, but it still can be recommended for typical animal husbandry uses, although other types of stoppers would be more suitable for specific nutritional and toxicologic studies.

Kennedy, B.W.; Beal, T.S. (Carbohydrate Nutrition Laboratory, Beltsville Human Nutrition Research Center, MD (United States))

1991-06-01T23:59:59.000Z

208

Methane Combustion over Pd/ZrO2/SiC, Pd/CeO2/SiC, Pd/Zr0.5Ce0.5O2/SiC Catalysts  

E-Print Network [OSTI]

1 Methane Combustion over Pd/ZrO2/SiC, Pd/CeO2/SiC, Pd/Zr0.5Ce0.5O2/SiC Catalysts Xiaoning Guo a Laboratory of Coal Conversion, Institute of Coal Chemistry, Taiyuan 030001, PR China b GREMI UMR6606 CNRS0.5O2 solid solution) modified Pd/SiC catalysts for methane combustion are studied. XRD and XPS

Paris-Sud XI, Université de

209

Scintillation properties of some Ce[sup 3+] and Pr[sup 3+] doped inorganic crystals  

SciTech Connect (OSTI)

The scintillations properties of Ce[sup 3+] and Pr[sup 3+] doped complex fluoride crystals of composition CsGd[sub 2]F[sub 7] and K[sub 2]YF[sub 5] and of Pr[sup 3+] doped Y[sub 3]Al[sub 5]O[sub 12] single crystals were studied by means of x-ray and gamma ray excitation. The Ce[sub 3+] and Pr[sub 3+] doped fluoride crystals show 5d-4f luminescences at wavelengths near 340 nm and 240 nm, respectively. 5d-4f luminescence of Pr[sup 3+] doped Y[sub 3]Al[sub 5]O[sub 12] is observed between 300 and 400 nm. The authors present the absolute light yield in photons/MeV together with results from scintillation decay time experiments.

Dorenbos, P.; Visser, R.; Eijk, C.W.E. van (Delft Univ. of Technology (Netherlands). Dept. of Applied Physics); Khaidukov, N.M. (N.S. Kurnakov Inst. of General and Inorganic Chemistry, Moscow (Russian Federation)); Korzhik, M.V. (Inst. of Nuclear Problems, Minsk (Russian Federation))

1993-08-01T23:59:59.000Z

210

Magnetization switching of rare earth orthochromite CeCrO{sub 3}  

SciTech Connect (OSTI)

We report the synthesis of single phase rare earth orthochromite CeCrO{sub 3} and its magnetic properties. A canted antiferromagnetic transition with thermal hysteresis at T?=?260?K is observed, and a magnetic compensation (zero magnetization) near 133?K is attributed to the antiparallel coupling between Ce{sup 3+} and Cr{sup 3+} moments. At low temperature, field induced magnetization reversal starting from 43?K for H?=?1.2 kOe reveals the spin flip driven by Zeeman energy between the net moments and the applied field. These findings may find potential uses in magnetic switching devices such as nonvolatile magnetic memory which facilitates two distinct states of magnetization.

Cao, Yiming; Cao, Shixun, E-mail: sxcao@shu.edu.cn; Ren, Wei; Feng, Zhenjie; Yuan, Shujuan; Kang, Baojuan; Zhang, Jincang [Department of Physics, Shanghai University, Shanghai 200444 (China); Lu, Bo [Laboratory for Microstructures, Shanghai University, Shanghai 200444 (China)

2014-06-09T23:59:59.000Z

211

Josephson effect in CeCoIn{sub 5} microbridges as seen via quantum interferometry  

SciTech Connect (OSTI)

A superconducting quantum interference device (SQUID) was prepared on a micron-sized single crystal using a selected growth domain of a thin film of CeCoIn{sub 5} grown by molecular beam epitaxy. SQUID voltage oscillations of good quality were obtained as well as interference effects stemming from the individual Josephson microbridges. The transport characteristics in the superconducting state exhibited several peculiarities which we ascribe to the periodic motion of vortices in the microbridges. The temperature dependence of the Josephson critical current shows good correspondence to the Ambegaokar-Baratoff relation, expected for the ideal Josephson junction. The results indicate a promising pathway to identify the type of order parameter in CeCoIn{sub 5} by means of phase-sensitive measurements on microbridges.

Foyevtsov, Oleksandr; Porrati, Fabrizio; Huth, Michael [Physikalisches Institut, Goethe University, Frankfurt am Main, 60438 (Germany)

2011-07-15T23:59:59.000Z

212

Investigation into Nanostructured Lanthanum Halides and CeBr{sub 3} for Nuclear Radiation Detection  

SciTech Connect (OSTI)

This slide-show presents work on radiation detection with nanostructured lanthanum halides and CeBr{sub 3}. The goal is to extend the gamma energy response on both low and high-energy regimes by demonstrating the ability to detect low-energy x-rays and relatively high-energy activation prompt gamma rays simultaneously using the nano-structured lanthanum bromide, lanthanum fluoride, cerium bromide, or other nanocrystal material. Homogeneous and nano structure cases are compared.

Guss, P., Guise, R., Mukhopadhyay, S., Yuan, D.

2011-06-22T23:59:59.000Z

213

Synthesis of Transient Climate Evolution of the last 21-kyr (SynTraCE-21)  

SciTech Connect (OSTI)

Climate evolution in the last 21,000 years provides critical observations for testing state-of-the-art climate models on the simulation of climate evolution and abrupt climate changes. Proxy evidences and new modeling activities have led to rapid advances in our understanding of climate change for this past time period. This funding helps to support the first international SynTraCE-21k workshop at Mount Hood, Oregon from 10-13 October, 2010.

Zhengyu Liu

2011-05-06T23:59:59.000Z

214

Luminescence Enhancement of CdTe Nanostructures in LaF3:Ce/CdTe Nanocomposites  

SciTech Connect (OSTI)

Radiation detection demands new scintillators with high quantum efficiency, high energy resolution and short luminescence lifetimes. Nanocomposites consisting of quantum dots and Ce3+ doped nanophosphors may be able to meet these requirements. Here we report the luminescence of LaF3:Ce/CdTe nanocomposites which were synthesized by a wet chemistry method. In LaF3:Ce/CdTe nanocomposites the CdTe quantum dots are converted into nanowires, while in LaF3/CdTe nanocomposites no such conversion is observed. The CdTe luminescence in LaF3:Ce/CdTe nanocomposites is enhanced about 5 times, while in LaF3/CdTe nanocomposites no enhancement was observed. Energy transfer, light-re-absorption and surface passivation are likely the reasons for the luminescence enhancement.

Yao, Mingzhen; Zhang, Xing; Ma, Lun; Chen, Wei; Joly, Alan G.; Huang, Jinsong; Wang, Qingwu

2010-11-15T23:59:59.000Z

215

A dipole polarizable potential for reduced and doped CeO[subscript 2] obtained from first principles  

E-Print Network [OSTI]

In this paper we present the parameterization of a new interionic potential for stoichiometric, reduced and doped CeO[subscript 2]. We use a dipole polarizable potential (DIPPIM: the dipole polarizable ion model) and ...

Burbano, Mario

216

Impact of the CE mark approval on exit opportunities and validation for early stage medical device companies  

E-Print Network [OSTI]

The aim of this thesis was to look at the impact of acquiring the CE marking approval on the outcome of early stage medical device companies, specifically its impact on strategic acquisition opportunities and on valuation. ...

Kothari, Ashish (Ashish Shrikant)

2011-01-01T23:59:59.000Z

217

Lung cancer epidemiology in New Mexico uranium miners  

SciTech Connect (OSTI)

This investigation assesses the health effects of radon progeny exposure in New Mexico uranium miners. Cumulative exposures sustained by most New Mexico miners are well below those received earlier in the Colorado Plateau. This project utilizes the research opportunity offered by New Mexico miners to address unresolved issues related to radon progeny exposure: (1) the lung cancer risk of lower levels of exposure, (2) interaction between radon progeny exposure and cigarette smoking in the causation of lung cancer, (3) the relationship between lung cancer histologic type and radon progeny exposure, and (4) possible effects of radon progeny exposure other than lung cancer. A cohort study of 3800 men with at least one year of underground uranium mining experience in New Mexico is in progress. Results are discussed.

Samet, J.M.

1991-11-01T23:59:59.000Z

218

Adsorption and Reaction of C1-C3 Alcohols over CeOx(111) Thin Films  

SciTech Connect (OSTI)

This study reports the interaction of methanol, ethanol, 1-propanol, and 2-propanol with well-ordered CeO{sub 2}(111) thin film surfaces. All of the alcohols adsorb at low temperature by forming alkoxy and hydroxyl species on the surface. On fully oxidized CeO{sub 2}(111), recombination occurs between some of the alkoxys and hydroxyls, resulting in alcohol desorption near 220 K. At the same temperature, some of the surface hydroxyls disproportionate to produce water and the loss of lattice O. The remaining alkoxys react above 550 K. The primary alcohols favor dehydrogenation products (aldehydes). There is a net loss of O from the system, resulting in a reduction of the ceria. The secondary alcohol, 2-propanol, undergoes primarily dehydration, producing propene with no net change in the cerium oxidation state. Reduced CeO{sub x}(111) competes with the gaseous products for available O. Little or no water is produced. The reaction selectivity for the C{sub 2} and C{sub 3} alcohols shifts toward favoring dehydration products. The loss of O from the alcohols leads to oxidation of the reduced ceria. Compared with the oxidized surface, the alkene desorption shifts to lower temperature, whereas the aldehyde desorption shifts to higher temperature. This indicates that, on the reduced surface, it is easier to break the C-O bond but more difficult to break the O-substrate bond.

D Mullins; S Senanayake; T Chen

2011-12-31T23:59:59.000Z

219

Iowa State Mining and Mineral Resources Research Institute  

SciTech Connect (OSTI)

This final report describes the activities of the Iowa State Mining and Mineral Resources Research Institute (ISMMRRI) at Iowa State University for the period July 1, 1989, to June 30, 1990. Activities include research in mining- and mineral-related areas, education and training of scientists and engineers in these fields, administration of the Institute, and cooperative interactions with industry, government agencies, and other research centers. During this period, ISMMRRI has supported research efforts to: (1) Investigate methods of leaching zinc from sphalerite-containing ores. (2) Study the geochemistry and geology of an Archean gold deposit and of a gold-telluride deposit. (3) Enchance how-quality aggregates for use in construction. (4) Pre-clean coal by triboelectric charging in a fluidized-bed. (5) Characterize the crystal/grain alignment during processing of yttrium-barium-copper-perovskite (1-2-3) superconductors. (5) Study the fluid inclusion properties of a fluorite district. (6) Study the impacts of surface mining on community planning. (7) Assess the hydrophobicity of coal and pyrite for beneficiation. (8) Investigate the use of photoacoustic absorption spectroscopy for monitoring unburnt carbon in the exhaust gas from coal-fired boilers. The education and training program continued within the interdepartmental graduate minor in mineral resources includes courses in such areas as mining methods, mineral processing, industrial minerals, extractive metallurgy, coal science and technology, and reclamation of mined land. In addition, ISMMRRI hosted the 3rd International Conference on Processing and Utilization of High-Sulfur Coals in Ames, Iowa. The Institute continues to interact with industry in order to foster increased cooperation between academia and the mining and mineral community.

Not Available

1990-08-01T23:59:59.000Z

220

Mineral Deformation at Earth's Core-Mantle Boundary  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment SurfacesResource Program PreliminaryA3,0 Alabama - Natural GasMineralMineral

Note: This page contains sample records for the topic "mineral gadolinite ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Morphological and Structural Changes During the Reduction and Reoxidation of CuO/CeO(2) and Ce(1-x)Cu(x)O(2) Nanocatalysts: In-situ Studies with Environmental TEM, XRD and XAS  

SciTech Connect (OSTI)

We have studied the structural, morphological, and electronic properties of CuO/CeO{sub 2} and Ce{sub 1-x}Cu{sub x}O{sub 2} nanocatalysts during reduction/oxidation cycles using H{sub 2} and O{sub 2} as chemical probes. Time-resolved in situ characterization was performed by X-ray diffraction (XRD) and X-ray absorption spectroscopy (XAS) as well as aberration-corrected environmental transmission electron microscopy (ETEM). We have found that both types of nanocatalysts reduce to a Cu/CeO{sub 2} biphase system with significant oxygen vacancies in CeO{sub 2}. Important variations are seen in the Cu particle size and metal dispersion depending on the initial state of the copper oxide-ceria systems. During subsequent in situ oxygen annealing, the Cu precipitated from the CuO/CeO{sub 2} system reoxidized to form CuO through a Cu{sub 2}O intermediate phase as expected. However, the Cu precipitated from the Ce{sub 0.8}Cu{sub 0.2}O{sub 2} solid solution behaved rather differently under oxidizing conditions, and neither oxidized to form CuO nor fully returned to a bulk Ce{sub 0.8}Cu{sub 0.2}O{sub 2} phase in solid solution. We found that {approx} 50% of the Cu returned to a Ce{sub 1-x}Cu{sub x}O{sub 2} solid solution, while the remainder was observed by in situ ETEM to form an amorphous copper oxide phase with a Cu oxidation state similar to Ce{sub 1-x}Cu{sub x}O{sub 2}, but with a local bonding environment similar to CuO. The behavior of the reduced Ce{sub 0.8}Cu{sub 0.2}O{sub 2} reflects strong interactions between Cu and the ceria matrix and illustrates the advantages of working with solid solutions of mixed oxides.

Rodriguez, J.A.; Ciston, J.; Si, R.; Hanson, J.C.; Martínez-Arias, A.; Fernandez-García, M.; Zhu, Y.

2011-07-21T23:59:59.000Z

222

Morphological and Structural Changes during the Reduction and Reoxidation of CuO/CeO2 and Ce1-xCuxO2 Nanocatalysts: In Situ Studies with Environmental TEM XRD and XAS  

SciTech Connect (OSTI)

We have studied the structural, morphological, and electronic properties of CuO/CeO{sub 2} and Ce{sub 1-x}Cu{sub x}O{sub 2} nanocatalysts during reduction/oxidation cycles using H2 and O2 as chemical probes. Time-resolved in situ characterization was performed by X-ray diffraction (XRD) and X-ray absorption spectroscopy (XAS) as well as aberration-corrected environmental transmission electron microscopy (ETEM). We have found that both types of nanocatalysts reduce to a Cu/CeO{sub 2} biphase system with significant oxygen vacancies in CeO{sub 2}. Important variations are seen in the Cu particle size and metal dispersion depending on the initial state of the copper oxide-ceria systems. During subsequent in situ oxygen annealing, the Cu precipitated from the CuO/CeO{sub 2} system reoxidized to form CuO through a Cu2O intermediate phase as expected. However, the Cu precipitated from the Ce{sub 0.8}Cu{sub 0.2}O{sub 2} solid solution behaved rather differently under oxidizing conditions, and neither oxidized to form CuO nor fully returned to a bulk Ce{sub 0.8}Cu{sub 0.2}O{sub 2} phase in solid solution. We found that 50% of the Cu returned to a Ce{sub 1-x}Cu{sub x}O{sub 2} solid solution, while the remainder was observed by in situ ETEM to form an amorphous copper oxide phase with a Cu oxidation state similar to Ce{sub 1-x}Cu{sub x}O{sub 2}, but with a local bonding environment similar to CuO. The behavior of the reduced Ce{sub 0.8}Cu{sub 0.2}O{sub 2} reflects strong interactions between Cu and the ceria matrix and illustrates the advantages of working with solid solutions of mixed oxides.

J Ciston; R Si; J Rodriquez; J Hanson; A Martinez-Arias; M Fernandez-Garcia; Y Zhu

2011-12-31T23:59:59.000Z

223

High thermoelectric performance of In, Yb, Ce multiple filled CoSb{sub 3} based skutterudite compounds  

SciTech Connect (OSTI)

Filling voids with rare earth atoms is an effective way to lowering thermal conductivity which necessarily enhances thermoelectric properties of skutterudite compounds. Yb atom is one of the most effective species among the rare earth atoms for filling the voids in the skutterudite structure due to a large atomic mass, radius and it is intermediate valence state. In this work, we aim to find the best filling partners for Yb using different combinations of Ce and In as well as to optimize actual filling fraction in order to achieve high values of ZT. The traditional method of synthesis relying on melting-annealing and followed by spark plasma sintering was used to prepare all samples. The thermoelectric properties of four samples of Yb{sub 0.2}In{sub 0.2}Co{sub 4}Sb{sub 12}, Yb{sub 0.2}Ce{sub 0.15}Co{sub 4}Sb{sub 12}, Yb{sub 0.2}Ce{sub 0.15}In{sub 0.2}Co{sub 4}Sb{sub 12}, and Yb{sub 0.3}Ce{sub 0.15}In{sub 0.2}Co{sub 4}Sb{sub 12} (nominal) were examined based on the Seebeck coefficient, electrical conductivity, thermal conductivity, and Hall coefficient. Hall coefficient and Seebeck coefficient signs confirm that all samples are n-type skutterudite compounds. Carrier density increases with the increasing Yb+Ce content. A high power factor value of 57.7 {mu}W/K{sup 2}/cm for Yb{sub 0.2}Ce{sub 0.15}Co{sub 4}Sb{sub 12} and a lower thermal conductivity value of 2.82 W/m/K for Yb{sub 0.2}Ce{sub 0.15}In{sub 0.2}Co{sub 4}Sb{sub 12} indicate that small quantities of Ce with In may be a good partner to Yb to reduce the thermal conductivity further and thus enhance the thermoelectric performance of skutterudites. The highest ZT value of 1.43 was achieved for Yb{sub 0.2}Ce{sub 0.15}In{sub 0.2}Co{sub 4}Sb{sub 12} triple-filled skutterudite at 800 K. - Graphical abstract: Thermoelectric figure of merit of Yb{sub x}In{sub y}Ce{sub z}Co{sub 4}Sb{sub 12} (0{<=}x,y,z{<=}0.18 actual) compounds versus temperature. Highlights: Black-Right-Pointing-Pointer TE properties of Yb,In,Ce multiple-filled Yb{sub x}In{sub y}Ce{sub z}Co{sub 4}Sb{sub 12} skutterudites were investigated. Black-Right-Pointing-Pointer Thermal conductivity is strongly suppressed by multiple filling of Yb, Ce and In. Black-Right-Pointing-Pointer Small amounts of Ce and In with Yb are beneficial for the enhancement of TE performance. Black-Right-Pointing-Pointer The highest ZT=1.43 was achieved with Yb{sub 0.07}In{sub 0.094}Ce{sub 0.065}Co{sub 4}Sb{sub 11.92} at 800 K.

Ballikaya, Sedat [Department of Physics, University of Istanbul, 34134 Vezneciler, Istanbul (Turkey) [Department of Physics, University of Istanbul, 34134 Vezneciler, Istanbul (Turkey); Department of Physics, University of Michigan, Ann Arbor, MI, 48109 (United States); Uzar, Neslihan; Yildirim, Saffettin [Department of Physics, University of Istanbul, 34134 Vezneciler, Istanbul (Turkey)] [Department of Physics, University of Istanbul, 34134 Vezneciler, Istanbul (Turkey); Salvador, James R. [Chemical Sci. and Mater. Systems Laboratory, General Motors Global R and D Center, Warren, MI 48090 (United States)] [Chemical Sci. and Mater. Systems Laboratory, General Motors Global R and D Center, Warren, MI 48090 (United States); Uher, Ctirad, E-mail: cuher@umich.edu [Department of Physics, University of Michigan, Ann Arbor, MI, 48109 (United States)] [Department of Physics, University of Michigan, Ann Arbor, MI, 48109 (United States)

2012-09-15T23:59:59.000Z

224

A literature review of actinide-carbonate mineral interactions  

SciTech Connect (OSTI)

Chemical retardation of actinides in groundwater systems is a potentially important mechanism for assessing the performance of the Waste Isolation Pilot Plant (WIPP), a facility intended to demonstrate safe disposal of transuranic waste. Rigorous estimation of chemical retardation during transport through the Culebra Dolomite, a water-bearing unit overlying the WIPP, requires a mechanistic understanding of chemical reactions between dissolved elements and mineral surfaces. This report represents a first step toward this goal by examining the literature for pertinent experimental studies of actinide-carbonate interactions. A summary of existing models is given, along with the types of experiments on which these models are based. Articles pertaining to research into actinide interactions with carbonate minerals are summarized. Select articles involving trace element-carbonate mineral interactions are also reviewed and may serve as templates for future research. A bibliography of related articles is included. Americium(III), and its nonradioactive analog neodymium(III), partition strongly from aqueous solutions into carbonate minerals. Recent thermodynamic, kinetic, and surface studies show that Nd is preferentially removed from solution, forming a Nd-Ca carbonate solid solution. Neptunium(V) is rapidly removed from solution by carbonates. Plutonium incorporation into carbonates is complicated by multiple oxidation states. Little research has been done on the radium(H) and thorium(IV) carbonate systems. Removal of uranyl ion from solution by calcite is limited to monolayer surface coverage.

Stout, D.L. [Missouri Univ., Columbia, MO (United States). Dept. of Geological Sciences; Carroll, S.A. [Lawrence Livermore National Lab., CA (United States)

1993-10-01T23:59:59.000Z

225

Contrib Mineral Petrol (2991) 109:10-18 Contributions to  

E-Print Network [OSTI]

mineral (PGM) nuggets of eluvial (residual) origin, associated with the Freetown Layered Gabbro Complex Os. The Pt- Fe alloy nuggets, on the other hand, were formed later in a residual melt which depositional environments. Introduction The origin of platinum nuggets is controversial. Pro- posed models

226

Mineral mesopore effects on nitrogenous organic matter Andrew R. Zimmermana,  

E-Print Network [OSTI]

as sequestration of pollutants in soils and sediments (Luthy et al., 1997), turnover of natural soil organic carbon that organic matter (OM) may be protected from enzymatic degradation by sequestration within mineral mesopores observations. These results provide a potential mechanism for the selective sequestration and preservation

Chorover, Jon

227

2011 Minerals Yearbook U.S. Department of the Interior  

E-Print Network [OSTI]

of chromium chemicals and stainless steel. in 2011, oregon resources Corp. (orC) [a subsidiary of i Coos County, or, paleo-beach placer (heavy-mineral sand) deposits. in doing so, orC became the sole producer of foundry-grade chromite ore in the united States. orC chromite ore shipments were 5

228

2007 Minerals Yearbook U.S. Department of the Interior  

E-Print Network [OSTI]

parts per million (ppm), to thulium and lutetium, the least abundant rare-earth elements (REE) at about2007 Minerals Yearbook U.S. Department of the Interior U.S. Geological Survey RARE EARTHS May 2010 #12;RARE EARTHS--2007 60.1 RARE EARTHS By James B. Hedrick Domestic survey data and tables were

229

Prospects for Rare Earth Elements From Marine Minerals  

E-Print Network [OSTI]

Prospects for Rare Earth Elements From Marine Minerals Rare earth elements (REEs) compose in the earth's crust. However, because of their geochemical proper es, rare earth elements are typically. Briefing Paper 02/12 Jim Hein | May 2012 www.isa.org.jm Table 1: Rare Earth Elements This paper

230

2010 Minerals Yearbook U.S. Department of the Interior  

E-Print Network [OSTI]

million (ppm), to thulium and lutetium, the least abundant rare-earth elements (REE), at about 0.5 ppm, and thallium. Rare earths can be classified as either light rare-earth elements (LREE) or heavy rare-earth2010 Minerals Yearbook U.S. Department of the Interior U.S. Geological Survey RARE EARTHS [ADVANCE

231

2009 Minerals Yearbook U.S. Department of the Interior  

E-Print Network [OSTI]

parts per million (ppm), to thulium and lutetium, the least abundant rare-earth elements (REE), at about be classified as either light rare-earth elements (LREE) or heavy rare-earth elements (HREE). This division2009 Minerals Yearbook U.S. Department of the Interior U.S. Geological Survey RARE EARTHS [ADVANCE

232

2011 Minerals Yearbook U.S. Department of the Interior  

E-Print Network [OSTI]

not necessarily reflect trends in consumption. the rare earths are a moderately abundant group of 17 elements light rare-earth elements (LRee) or heavy rare-earth elements (hRee). the LRee include the lanthanide2011 Minerals Yearbook U.S. Department of the Interior U.S. Geological Survey RARE EARTHS [ADVANCE

233

REE MINERALS IN CATALO II, GOIAS, BRASIL Essaid BILAL1  

E-Print Network [OSTI]

, these minerals interact with the fluid surface and lose some of their REE and Ba. The exchange reactions between (cerrado). The most comprehensive study concerned drill-hole C3B1, located at about 175m north of the pipe). The drill first intersected several tens of meters of reddish-yellow clay soil,

Boyer, Edmond

234

2005 Minerals Yearbook U.S. Department of the Interior  

E-Print Network [OSTI]

Sector Initiatives: Opportunities Now), a presidential public-private partnership established in 2003 produced by surface and underground mining and from brine. U.S. consumption of minerals and compounds and installing energy efficient burners in the driers has rewarded SVM by increased efficiency and energy savings

235

KING FAHD UNIVERSITY OF PETROLEUM & MINERALS Dhahran, Saudi Arabia  

E-Print Network [OSTI]

Rocks By Dr. Sidqi A. Abu-Khamsin Professor, Department of Petroleum Engineering © Copyright by Dr;1. INTRODUCTION 1.1: The nature of petroleum All chemical compounds found in nature are classified as eitherKING FAHD UNIVERSITY OF PETROLEUM & MINERALS Dhahran, Saudi Arabia Basic Properties of Reservoir

Abu-Khamsin, Sidqi

236

The semismooth Newton method for multicomponent reactive transport with minerals  

E-Print Network [OSTI]

is that problems containing CCs (so-called complementarity problems, CPs) are well known in the field of optimization theory. In this field, it is a well known strategy to solve CPs with the semismooth Newton method essential. The article is structured as follows. In Sec. 2.1 we introduce the mineral precipitation

Kraeutle, Serge

237

Electrical Properties of Mineral Surfaces for Increasing Water Sorption  

E-Print Network [OSTI]

in the presence of O2.2,4,5 In addition to controlling Mn concentrations, the nanostructures sequester heavy-metal and the associated toxic metals can be remobilized. N the electrical properties of mineral surfaces and thereby affect reactions with charged species such as metal

238

Preliminary conceptual model for mineral evolution in Yucca Mountain  

SciTech Connect (OSTI)

A model is presented for mineral alteration in Yucca Mountain, Nevada, that suggests that the mineral transformations observed there are primarily controlled by the activity of aqueous silica. The rate of these reactions is related to the rate of evolution of the metastable silica polymorphs opal-CT and cristobalite assuming that a{sub SiO{sub 2(aq)}} is fixed at the equilibrium solubility of the most soluble silica polymorph present. The rate equations accurately predict the present depths of disappearance of opal-CT and cristobalite. The rate equations have also been used to predict the extent of future mineral alteration that may result from emplacement of a high-level nuclear waste repository in Yucca Mountain. Relatively small changes in mineralogy are predicted, but these predictions are based on the assumption that emplacement of a repository would not increase the pH of water in Yucca Mountain nor increase its carbonate content. Such changes may significantly increase mineral alteration. Some of the reactions currently occurring in Yucca Mountain consume H{sup +} and CO{sub 3}{sup 2{minus}}. Combining reaction rate models for these reactions with water chemistry data may make it possible to estimate water flux through the basal vitrophyre of the Topopah Spring Member and to help confirm the direction and rate of flow of groundwater in Yucca Mountain.

Duffy, C.J.

1993-12-01T23:59:59.000Z

239

Mineral formation during simulated leaks of Hanford waste tanks  

E-Print Network [OSTI]

Mineral formation during simulated leaks of Hanford waste tanks Youjun Deng a , James B. Harsh a handling by M. Gascoyne Abstract Highly-alkaline waste solutions have leaked from underground tanks mimicking tank leak conditions at the US DOE Hanford Site. In batch experiments, Si-rich solutions

Flury, Markus

240

2006 Minerals Yearbook ClaY and Shale  

E-Print Network [OSTI]

2006 Minerals Yearbook ClaY and Shale U.S. Department of the Interior U.S. Geological Survey January 2008 #12;Clay and Shale--2006 18.1 The amount of clay sold or used by domestic producers in 2006 in 2005 (table 1). Common clay and shale accounted for 59% of the tonnage, and kaolin accounted for 55

Note: This page contains sample records for the topic "mineral gadolinite ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Cost Assessment of CO2 Sequestration by Mineral Carbonation  

E-Print Network [OSTI]

Cost Assessment of CO2 Sequestration by Mineral Carbonation Frank E. Yeboah Tuncel M. Yegulalp Harmohindar Singh Research Associate Professor Professor Center for Energy Research... them carbon dioxide (CO 2 ). This paper assesses the cost of sequestering CO 2 produced by a ZEC power plant using solid sequestration process. INTRODUCTION CO 2 is produced when electrical energy is generated using conventional fossil...

Yeboah, F. E.; Yegulalp, T. M.; Singh, H.

2006-01-01T23:59:59.000Z

242

2008 Minerals Yearbook U.S. Department of the Interior  

E-Print Network [OSTI]

statistics and world tungsten concentrate production for 2008 and the previous 4 years are listed in table 1 for lead in bullets, shot, and other products. Tungsten chemicals are used to make catalysts, corrosion2008 Minerals Yearbook U.S. Department of the Interior U.S. Geological Survey TUNGSTEN October 2010

243

2007 Minerals Yearbook U.S. Department of the Interior  

E-Print Network [OSTI]

statistics and world tungsten concentrate production for 2007 and the previous 4 years are listed in table 12007 Minerals Yearbook U.S. Department of the Interior U.S. Geological Survey TUNGSTEN May 2010 #12;TUNGSTEN--2007 79.1 TUNGSTEN By Kim B. Shedd Domestic survey data and tables were prepared by Danielle L

244

2005 Minerals Yearbook U.S. Department of the Interior  

E-Print Network [OSTI]

2005 Minerals Yearbook TungsTen U.S. Department of the Interior U.S. Geological Survey #12;TungsTen--2005 79.1 TungsTen ByKimB.shedd Domestic survey data and tables were prepared by Amy C. Tolcin, statistical assistant, and the world production table was prepared by Glenn J. Wallace, international data

245

2006 Minerals Yearbook U.S. Department of the Interior  

E-Print Network [OSTI]

, international data coordinator. No U.S. tungsten mine production was reported in 2006. U.S. supply of tungsten Service (FWS) granted final approval to four new tungsten shot products for hunting waterfowl and coots--iron-tungsten2006 Minerals Yearbook TUNGSTEN U.S. Department of the Interior U.S. Geological Survey April 2008

246

2010 Minerals Yearbook U.S. Department of the Interior  

E-Print Network [OSTI]

with that of 2009. Salient U.S. tungsten statistics and world tungsten concentrate production for 20102010 Minerals Yearbook U.S. Department of the Interior U.S. Geological Survey TUNGSTEN [ADVANCE RELEASE] February 2012 #12;TUNGSTEN--2010 [ADVANCE RELEASE] 79.1 TUNGSTEN By Kim B. Shedd Domestic survey

247

2011 Minerals Yearbook U.S. Department of the Interior  

E-Print Network [OSTI]

consumption increased significantly in 2011, as compared with that of 2010. World tungsten mine production. salient u.s. tungsten statistics and world tungsten concentrate production for 2007­11 are listed in table2011 Minerals Yearbook U.S. Department of the Interior U.S. Geological Survey TUNGSTEN [ADVANCE

248

MIN E 408: Mining Enterprise Economics Mineral Resource/Reserve  

E-Print Network [OSTI]

quality assurance and quality control (QA/QC) programs. Geological / Grade continuity · geometrical of any mining project. The quality of resource classification is a key parameter for accurate economic to attract investors. Mineral resource classification standards were created in order to define rules

Boisvert, Jeff

249

2011 Minerals Yearbook U.S. Department of the Interior  

E-Print Network [OSTI]

, electrowon, and secondary production. The United States fell to eighth ranked in copper smelter production2011 Minerals Yearbook U.S. Department of the Interior U.S. Geological Survey COPPER [ADVANCE RELEASE] July 2013 #12;Copper--2011 [ADVANCe reLeASe] 20.1 Copper By Daniel L. edelstein Domestic survey

250

Heavy mineral distribution in stream sediment of Tapah area, Perak, Malaysia  

SciTech Connect (OSTI)

This paper aims to provide the overview of occurrence, distribution and origin of the heavy minerals in the study area. A total of 45 selected stream sediment heavy mineral concentrate samples were panned using standard dulangs, dried and separated from other light minerals using bromoform. The heavy minerals were separated into different fractions at different amperes using Frantz Isodynamic magnetic separator. Mineral identification was done using binocular microscope augmented by X-ray diffraction analyses. Mineral abundance data were analysed graphically using triangular diagrams to show their origin. Dominant minerals present in the heavy mineral samples collected are ilmenite, cassiterite, tourmaline, zircon, topaz, and magnetite. The less common minerals, present in trace amounts are hematite, xenotime, allanite, monazite, rutile, anatase, leucoxene, chromite, garnet and olivine. Examination of the heavy mineral assemblage shows that they originated from granite batholiths of the Main Range, Changkat Rembian as well as from the metasedimentary rock in the area. The gold flakes present are found together with cassiterite and topaz indicating that gold originates from the mineralized veins contact-metamorphosed metasedimentary rocks. Almost all samples collected contain cassiterite grains in various amounts. From the mineral assemblage, the source of cassiterite originates from the mineralized quartz veins that cut granitic rocks of Main Range, Changkat Rembian as well as the metasedimentary rock in the area. Greisenized veins containing quartz, mica and tourmaline with the presence of wolframite and arsenopyrite also contribute to the presence of cassiterite in this study area.

Sibon, Mahat Hj [Jabatan Mineral dan Geosains Malaysia, 40000 Shah Alam, Selangor, Malaysia and Program Geologi, Pusat Pengajian Sains Sekitaran dan Sumber Alam, Fakulti Sains dan Teknologi, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia); Jamil, Habibah; Umor, Mohd Rozi [Program Geologi, Pusat Pengajian Sains Sekitaran dan Sumber Alam, Fakulti Sains dan Teknologi, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia); Hassan, Wan Fuad Wan [Jabatan Geologi, Fakulti Sains Universiti Malaya, 50603 Kuala Lumpur (Malaysia)

2013-11-27T23:59:59.000Z

251

Societal demand for increasing mineral resources continue to affect societythrough aspects as varied as  

E-Print Network [OSTI]

Societal demand for increasing mineral resources continue to affect societythrough aspects in investment. The discovery of new mineral resources requires increasing risk, increasing costs, and to provide trained individuals to industry. Vancouver has long been a global leader in exploration

Handy, Todd C.

252

Journal of Crystal Growth 280 (2005) 587593 Optimization of the mineral content in polymeric gels  

E-Print Network [OSTI]

Journal of Crystal Growth 280 (2005) 587­593 Optimization of the mineral content in polymeric gels.67. Phosphate ions were incorporated during the polymerization of the gel and mineralization was initiated

Azad, Abdul-Majeed

253

STRUCTURAL CONTROL AND ANISOTROPY OF MINERALIZATION THE CHUQUICAMATA PORPHYRY COPPER DEPOSIT,  

E-Print Network [OSTI]

STRUCTURAL CONTROL AND ANISOTROPY OF MINERALIZATION WITHIN THE CHUQUICAMATA PORPHYRY COPPER DEPOSIT CONTROL AND ANISOTROPY OF MINERALIZATION WITHIN THE CHUQUICAMATA PORPHYRY COPPER DEPOSIT, NORTHERN CHILE the Chuquicamata Porphyry Copper Deposit, northern Chile DEPARTMENT OR SCHOOL: Department of Earth Sciences DEGREE

Beaumont, Christopher

254

Pyridine sorption to mineral surfaces: a fourier transform infrared spectroscopy study  

E-Print Network [OSTI]

for the sorption of pyridine to the various mineral surfaces. Results indicated that hydrogen bonding and bonding to Lewis acid sites are responsible for the sorption of gaseous phase pyridine which sorbed to all mineral surfaces. FTIR spectra provided evidence...

Graham, Robert Edward

1999-01-01T23:59:59.000Z

255

Exploring Frontiers in Kinetics and Mechanisms of Geochemical Processes at the Mineral/Water Interface  

E-Print Network [OSTI]

Exploring Frontiers in Kinetics and Mechanisms of Geochemical Processes at the Mineral in the Earth's Critical Zone is the kinetics. The timescales for geochemical processes range from milliseconds geochemical processes including surface complexation, mineral transformations, and oxidation

Sparks, Donald L.

256

RIETVELD REFINEMENT OF REAL STRUCTURE PARAMETERS OF DISORDERED CLAY MINERALS IN  

E-Print Network [OSTI]

-conventional hydrocarbons in Germany) Germany's potential for shale oil and shale gas NIKO seal gas-rich shale shale: sedimentary rock which contains quartz, carbonates and clay minerals #12;clay minerals in shales quartz

Magee, Joseph W.

257

Rend Lake College celebrates the opening of a new coal miner training facility  

SciTech Connect (OSTI)

The Coal Miner Training Center at Rend Lake College recently hosted the Illinois Mining Institute's annual conference and a regional mine rescue competition. The article gives an outline of the coal miner training and refresher course offered. 3 photos.

Buchsbaum, L.

2009-09-15T23:59:59.000Z

258

Rationalization of the Hubbard U parameter in CeO{sub x} from first principles: Unveiling the role of local structure in screening  

SciTech Connect (OSTI)

The density functional theory (DFT)+U method has been widely employed in theoretical studies on various ceria systems to correct the delocalization bias in local and semi-local DFT functionals with moderate computational cost. We present a systematic and quantitative study, aiming to gain better understanding of the dependence of Hubbard U on the local atomic arrangement. To rationalize the Hubbard U of Ce 4f, we employed the first principles linear response method to compute Hubbard U for Ce in ceria clusters, bulks, and surfaces. We found that the Hubbard U varies in a wide range from 4.3 eV to 6.7 eV, and exhibits a strong correlation with the Ce coordination number and Ce–O bond lengths, rather than the Ce 4f valence state. The variation of the Hubbard U can be explained by the changes in the strength of local screening due to O ? Ce intersite transitions.

Lu, Deyu, E-mail: dlu@bnl.gov, E-mail: pingliu3@bnl.gov; Liu, Ping, E-mail: dlu@bnl.gov, E-mail: pingliu3@bnl.gov [Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, New York 11973 (United States)] [Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, New York 11973 (United States)

2014-02-28T23:59:59.000Z

259

Reportonoperations2009 stAteMent of CoMpliAnCe  

E-Print Network [OSTI]

between Curtin, the University of Western Australia and the state government. this centre will lead Curtin's position as a leader in collaborative research and education in the minerals, energy Australia's bid for the $3 billion square Kilometre Array · allocation of $20.5 million from the education

260

Hunchback Shelter: A Fremont Lithic Production Site in the Mineral Mountains of Eastern Utah  

E-Print Network [OSTI]

Mineral Mountains or Black Rock sources (Talbot et al. 2000:Canyon, and Black Rock obsidian source areas. occupations

Greubel, Rand A.; Andrews, Bradford W.

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mineral gadolinite ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Report TKK-ENY-9 Mineral carbonation for long-term storage of CO2  

E-Print Network [OSTI]

://www.entek.chalmers.se/~anly/symp/symp2001.html) "CO2 sequestration by magnesium silicate mineral carbonation in Finland" Ron Zevenhoven of magnesium oxide-based mineral carbonation for CO2 sequestration" Ron Zevenhoven, Jens Kohlmann. underReport TKK-ENY-9 Mineral carbonation for long-term storage of CO2 from flue gases Jens Kohlmann 1

Zevenhoven, Ron

262

West Virginia University Benjamin M. Statler College of Engineering and Mineral Resources  

E-Print Network [OSTI]

West Virginia University Benjamin M. Statler College of Engineering and Mineral Resources Out.cemr.wvu.edu/freshman. #12;West Virginia University Benjamin M. Statler College of Engineering and Mineral Resources Study College of Engineering and Mineral Resources (CEMR) and the Freshman Engineering Program (FEP

Mohaghegh, Shahab

263

Mineral replacement rate of olivine by chrysotile and brucite under high alkaline conditions  

E-Print Network [OSTI]

Mineral replacement rate of olivine by chrysotile and brucite under high alkaline conditions Romain Available online 8 March 2012 Keywords: A1. Mineral replacement rate A1. Serpentinization A1. TG analyses B1. Alkaline medium B2. Chrysotile nanotubes a b s t r a c t Olivine mineral replacement by serpentine is one

Montes-Hernandez, German

264

Mineral sequestration of CO2 by aqueous carbonation of1 coal combustion fly-ash2  

E-Print Network [OSTI]

1 Mineral sequestration of CO2 by aqueous carbonation of1 coal combustion fly-ash2 3 G. Montes that could possibly4 contribute to reducing carbon dioxide emissions is the in-situ mineral sequestration (long term5 geological storage) or the ex-situ mineral sequestration (controlled industrial reactors

Paris-Sud XI, Université de

265

DOI-BLM-ID-110-2009-3825-CE | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin:EnergyWisconsin:2003)CrowleyEnergyMasse) JumpConsultation-2009-3825-CE Jump to:

266

XRD, lead equivalent and UV-VIS properties study of Ce and Pr lead silicate glasses  

SciTech Connect (OSTI)

In this work, Cerium (Ce) and Praseodymium (Pr) containing lead silicate glasses were produced with 2 different molar ratios low (0.2 wt%) and high (0.4wt%). These types of glasses can satisfy the characteristics required for radiation shielding glasses and minimize the lead composition in glass. The radiation shielding properties of the synthesized glasses is explained in the form of lead equivalent study. The XRD diffraction and UV-VIS analysis were performed to observe the structural changes of the synthesis glasses at 1.5 Gy gamma radiation exposures.

Alias, Nor Hayati, E-mail: norhayati@nuclearmalaysia.gov.my; Abdullah, Wan Shafie Wan, E-mail: norhayati@nuclearmalaysia.gov.my; Isa, Norriza Mohd, E-mail: norhayati@nuclearmalaysia.gov.my; Isa, Muhammad Jamal Md, E-mail: norhayati@nuclearmalaysia.gov.my; Zali, Nurazila Mat; Abdullah, Nuhaslinda Ee [Malaysian Nuclear Agency, 43000, Bangi, Kajang, Selangor (Malaysia); Muhammad, Azali [Malaysian Society for Non-Destructive Testing (Malaysia)

2014-02-12T23:59:59.000Z

267

Data:46440396-c64b-4541-ad0a-43775ce1671b | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of48d9ff47edf3a87dcc95b No revisione66e17fc7f7 No revisione18fe97c No revision has been approved for775ce1671b

268

Probing the Reaction Intermediates for the Water-Gas Shift over Inverse CeOx/Au(111) Catalysts  

SciTech Connect (OSTI)

The water-gas shift (WGS) is an important reaction for the production of molecular H{sub 2} from CO and H{sub 2}O. An inverse CeO{sub x}/Au(1 1 1) catalyst exhibits a very good WGS activity, better than that of copper surfaces or Cu nanoparticles dispersed on a ZnO(0 0 0 {bar 1}) substrate which model current WGS industrial catalysts. In this work we report on intermediates likely to arise during the CO + H{sub 2}O reaction over CeO{sub x}/Au(1 1 1) using soft X-ray photoemission (sXPS) and near-edge X-ray absorption fine structure (NEXAFS). Several potential intermediates including formates (HCOO), carbonates (CO{sub 3}) and carboxylates (HOCO) are considered. Adsorption of HCOOH and CO{sub 2} is used to create both HCOO and CO{sub 3} on the CeO{sub x}/Au(1 1 1) surface, respectively. HCOO appears to have greater stability with desorption temperatures up to 600 K while CO{sub 3} only survives on the surface up to 300 K. On the CeO{sub x}/Au(1 1 1) catalysts, the presence of Ce{sup 3+} leads to the dissociation of H{sub 2}O to give OH groups. We demonstrate experimentally that the OH species are stable on the surface up to 600 K and interact with CO to yield weakly bound intermediates. When there is an abundance of Ce{sup 4+}, the OH concentration is diminished and the likely intermediates are carbonates. As the surface defects are increased and the Ce{sup 3+}/Ce{sup 4+} ratio grows, the OH concentration also grows and both carbonate and formate species are observed on the surface after dosing CO to H{sub 2}O/CeO{sub x}/Au(1 1 1). The addition of ceria nanoparticles to Au(1 1 1) is essential to generate an active WGS catalyst and to increase the production and stability of key reaction intermediates (OH, HCOO and CO{sub 3}).

Rodriguez, J.A.; Senanayake, S.D.; Stacchiola, D.; Evans, J.; Estrella, M.; Barrio-Pliego, L.; Pérez, M.; Hrbek, J.

2010-05-04T23:59:59.000Z

269

Probing the Reaction Intermediates for the Water–gas Shift over Inverse CeOx / Au(1 1 1) Catalysts  

SciTech Connect (OSTI)

The water-gas shift (WGS) is an important reaction for the production of molecular H{sub 2} from CO and H{sub 2}O. An inverse CeO{sub x}/Au(1 1 1) catalyst exhibits a very good WGS activity, better than that of copper surfaces or Cu nanoparticles dispersed on a ZnO(0 0 0 {bar 1}) substrate which model current WGS industrial catalysts. In this work we report on intermediates likely to arise during the CO + H{sub 2}O reaction over CeO{sub x}/Au(1 1 1) using soft X-ray photoemission (sXPS) and near-edge X-ray absorption fine structure (NEXAFS). Several potential intermediates including formates (HCOO), carbonates (CO{sub 3}) and carboxylates (HOCO) are considered. Adsorption of HCOOH and CO{sub 2} is used to create both HCOO and CO{sub 3} on the CeO{sub x}/Au(1 1 1) surface, respectively. HCOO appears to have greater stability with desorption temperatures up to 600 K while CO{sub 3} only survives on the surface up to 300 K. On the CeO{sub x}/Au(1 1 1) catalysts, the presence of Ce{sup 3+} leads to the dissociation of H{sub 2}O to give OH groups. We demonstrate experimentally that the OH species are stable on the surface up to 600 K and interact with CO to yield weakly bound intermediates. When there is an abundance of Ce{sup 4+}, the OH concentration is diminished and the likely intermediates are carbonates. As the surface defects are increased and the Ce{sup 3+}/Ce{sup 4+} ratio grows, the OH concentration also grows and both carbonate and formate species are observed on the surface after dosing CO to H{sub 2}O/CeO{sub x}/Au(1 1 1). The addition of ceria nanoparticles to Au(1 1 1) is essential to generate an active WGS catalyst and to increase the production and stability of key reaction intermediates (OH, HCOO and CO{sub 3}).

Senanayake, S.; Stacchiola, D; Evans, J; Estrella, M; Barrio, L; Perez, M; Hrbek, J; Rodriguez, J

2010-01-01T23:59:59.000Z

270

X-ray luminescence of CdTe quantum dots in LaF{sub 3}:Ce/CdTe nanocomposites  

SciTech Connect (OSTI)

CdTe quantum dots have intense photoluminescence but exhibit almost no x-ray luminescence. However, intense x-ray luminescence from CdTe quantum dots is observed in LaF{sub 3}:Ce/CdTe nanocomposites. This enhancement in the x-ray luminescence of CdTe quantum dots is attributed to the energy transfer from LaF{sub 3}:Ce to CdTe quantum dots in the nanocomposites. The combination of LaF{sub 3}:Ce nanoparticles and CdTe quantum dots makes LaF{sub 3}:Ce/CdTe nanocomposites promising scintillators for radiation detection.

Hossu, Marius; Liu Zhongxin; Yao Mingzhen; Ma Lun; Chen Wei

2012-01-02T23:59:59.000Z

271

Grant Title: RESEARCH GRANTS FOR PREVENTING VIOLENCE AND VIOLENCE-RELATED INJURY Funding Opportunity Number: RFA-CE-14-006. CFDA Number(s): 93.136.  

E-Print Network [OSTI]

Opportunity Number: RFA-CE-14-006. CFDA Number(s): 93.136. Agency/Department: Centers for Disease Control

Farritor, Shane

272

Nickel deficiency in RENi2-xP2 (RE=La, Ce, Pr). Combined crystallographic and physical property studies  

SciTech Connect (OSTI)

Large single crystals from RENi{sub 2-x}P{sub 2} (RE = La, Ce, Pr) were synthesized from the pure elements using Sn as a metal flux, and their structures were established by X-ray crystallography. The title compounds were confirmed to crystallize in the body-centered tetragonal ThCr{sub 2}Si{sub 2} structure type (space group I4/mmm (No. 139); Pearson's symbol tI10), but with a significant stoichiometry breadth with respect to the transition metal. Systematic synthetic work, coupled with accurate structure refinements indicated strong correlation between the degree of Ni-deficiency and the reaction conditions. For four different PrNi{sub 2-x}P{sub 2} (x {le} 0.5) samples, temperature dependent dc magnetization measurements indicated typical local moment 4f-magnetism and a stable Pr{sup 3+} ground state. Field-dependent heat capacity data confirmed a ferromagnetic order at low temperature, and the variations of T{sub c} with the concentration of Ni defects are discussed. LaNi{sub 2-x}P{sub 2}, as expected was found to be Pauli-like paramagnetic in the studied temperature regime, while the Ce-analog CeNi{sub 2-x}P{sub 2} (x = 0.28(1)) showed the characteristics of a mixed valent Ce{sup 3+}/Ce{sup 4+} system with a possible Kondo temperature on the order of 230 K.

Bauer, Eric D [Los Alamos National Laboratory; Ronning, Filip [Los Alamos National Laboratory; Thompson, Joe D [Los Alamos National Laboratory; Sarrao, John L [Los Alamos National Laboratory; Bobev, S [U. OF DE; Xia, S [U. OF DE

2008-01-01T23:59:59.000Z

273

Spatially resolved mineral deposition on patterned self-assembled monolayers  

SciTech Connect (OSTI)

Electron and ion beam lithographic techniques were used to pattern self-assembled monolayers with organic functional groups. Nucleation and growth of minerals from aqueous solution were confined to the patterned regions. A vinyl-terminated self-assembled monolayer (SAM) was selectively deposited in ion and electron beam etched regions of a methyl-terminated SAM. Sulfonation of the vinyl groups produced a surface patterned in either hydrophobic methyl groups or hydrophilic sulfonate groups. Subsequent growth of FeOOH films was confined to the sulfonated regions. Condensation images were used to image each step in the lithographic scheme. Resolution of the SAM patterning step was 1-3 [mu]m, while resolution of the mineral deposition step was 10-15 [mu]m. 15 refs., 3 figs.

Rieke, P.C.; Tarasevich, B.J.; Wood, L.L.; Engelhard, M.H.; Baer, D.R.; Fryxell, G.E. (Pacific Northwest Lab., Richland, WA (United States)); John, C.M. (Charles Evans Associates, Redwood City, CA (United States)); Laken, D.A.; Jaehnig, M.C. (FEI Corp., Beaverton, OR (United States))

1994-03-01T23:59:59.000Z

274

Intercalation of Trichloroethene by Sediment-Associated Clay Minerals  

SciTech Connect (OSTI)

The objective of this research was to examine the potential for intercalation of trichloroethene (TCE) by clay minerals associated with aquifer sediments. Sediment samples were collected from a field site inTucson, AZ. Two widely used Montmorillonite specimen clays were employed as controls. X-ray diffraction, conducted with a controlled-environment chamber, was used to characterize smectite interlayer dspacing for three treatments (bulk air-dry sample, sample mixed with synthetic groundwater, sample mixed with TCE-saturated synthetic groundwater). The results show that the d-spacing measured for the samples treated with TCE-saturated synthetic groundwater are larger (*26%) than those of the untreated samples for all field samples as well as the specimen clays. These results indicate that TCE was intercalated by the clay minerals, which may have contributed to the extensive elution tailing observed in prior miscible-displacement experiments conducted with this sediment.

Matthieu, Donald E.; Brusseau, Mark; Johnson, G. R.; Artiola, J. L.; Bowden, Mark E.; Curry, J. E.

2013-01-01T23:59:59.000Z

275

Scanning probe microscopy: Sulfate minerals in scales and cements  

SciTech Connect (OSTI)

The principles of scanning probe microscopy (SPM) are illustrated with examples from oilfield mineralogy, particularly emphasizing sulfate minerals involved in scale formation and cement hydration chemistry. The topography of the (010) cleavage surface of gypsum observed by atomic force microscopy shows atomically flat terraces separated by shallow steps often only one unit cell high. SPM allows direct observation of processes on mineral surfaces while they are in contact with solutions. The dissolution etching and crystal growth of gypsum and barite are discussed and rates of step migration estimated. The orientation of steps is related to the crystallographic axes. The action of phosphonate crystal growth inhibitor on gypsum and of a chelating scale solvent on barite are also shown. The multiphase microstructure of an oilwell cement clinker is described in relation to its hydration chemistry in contact with water and its reaction with sulfate ions.

Hall, C. [Schlumberger Cambridge Research (United Kingdom)

1995-11-01T23:59:59.000Z

276

2008 Minerals Yearbook U.S. Department of the Interior  

E-Print Network [OSTI]

million (ppm), to thulium and lutetium, the least abundant rare-earth elements (Ree) at about 0.5 ppm2008 Minerals Yearbook U.S. Department of the Interior U.S. Geological Survey RARE EARTHS October 2010 #12;RaRe eaRths--2008 60.1 RaRe eaRths By Daniel J. Cordier and James B. hedrick Domestic survey

277

Effects of mineral fillers in slurry seal mixtures  

E-Print Network [OSTI]

rather than a desi~. The current practice among engineers and contractors is to prepare a mixture in ac- cordance with these specifications using local materials. In many cases a mineral filler, usually portland cement, is added to "improve... applied to portland cement concrete pavements to improve the skid resistance and riding qualities of tbe surface. A slurry seal cost does not increase or improve the strength of the pavement structure . The City of Las Vagas, New Mexico, used slurry...

Harper, William Joe

1964-01-01T23:59:59.000Z

278

Hydrodesulfurization and hydrodenitrogenation catalysts obtained from coal mineral matter  

DOE Patents [OSTI]

A hydrotreating catalyst is prepared from coal mineral matter obtained by low temperature ashing coals of relatively low bassanite content by the steps of: (a) depositing on the low temperature ash 0.25-3 grams of an iron or nickel salt in water per gram of ash and drying a resulting slurry; (b) crushing and sizing a resulting solid; and (c) heating the thus-sized solid powder in hydrogen.

Liu, Kindtoken H. D. (Newark, DE); Hamrin, Jr., Charles E. (Lexington, KY)

1982-01-01T23:59:59.000Z

279

Implementation of the SAM-CE Monte Carlo benchmark analysis capability for validating nuclear data and reactor design codes  

SciTech Connect (OSTI)

The National Nuclear Data Center is continuing its program to improve the nuclear data base used as input for commercial reactor analysis and design. In the most recent phase of this project the Monte Carlo program SAM-CE, developed by the Mathematical Applications Group, Inc. (MAGI), was made operational at BNL. This program was implemented on the BNL-CDC-7600 Computer, and also on the PDP-10 in-house computer. The NNDC made operational and developed techniques for processing ENDF/B-V cross sections for SAM-CE. A limited ENDF/B-V based library was produced. Use of the SAM-CE program in thermal reactor problems was validated using detailed comparisons of results with other Monte Carlo codes such as RECAP, RCP01 and VIM as well as with experimental data.

Beer, M.; Rose, P.

1981-04-01T23:59:59.000Z

280

On the local electronic and atomic structure of Ce{sub 1?x}Pr{sub x}O{sub 2??} epitaxial films on Si  

SciTech Connect (OSTI)

The local electronic and atomic structure of (111)-oriented, single crystalline mixed Ce{sub 1?x}Pr{sub x}O{sub 2??} (x?=?0, 0.1 and 0.6) epitaxial thin films on silicon substrates have been investigated in view of engineering redox properties of complex oxide films. Non-destructive X-ray absorption near edge structure reveals that Pr shows only +3 valence and Ce shows only nominal +4 valence in mixed oxides. Extended x-ray absorption fine structure (EXAFS) studies were performed at K edges of Ce and Pr using a specially designed monochromator system for high energy measurements. They demonstrate that the fluorite lattice of ceria (CeO{sub 2}) is almost not perturbed for x?=?0.1 sample, while higher Pr concentration (x?=?0.6) not only generates a higher disorder level (thus more disordered oxygen) but also causes a significant reduction of Ce–O interatomic distances. The valence states of the cations were also examined by techniques operating in highly reducing environments: scanning transmission electron microscopy-electron energy loss spectroscopy and X-ray photoemission spectroscopy; in these reducing environments, evidence for the presence of Ce{sup 3+} was clearly found for the higher Pr concentration. Thus, the introduction of Pr{sup 3+} into CeO{sub 2} strongly enhances the oxygen exchange properties of CeO{sub 2}. This improved oxygen mobility properties of CeO{sub 2} are attributed to the lattice disorder induced by Pr mixing in the CeO{sub 2} fluorite lattice, as demonstrated by EXAFS measurements. Thus, a comprehensive picture of the modifications of the atomic and electronic structure of Ce{sub 1?x}Pr{sub x}O{sub 2??} epitaxial films and their relation is obtained.

Niu, Gang, E-mail: gang@ihp-microelectronics.com; Schubert, Markus Andreas; Zoellner, Marvin Hartwig [IHP, Im Technologiepark 25, 15236 Frankfurt (Oder) (Germany); D'Acapito, Francesco [Consiglio Nazionale delle Ricerche, Istituto Officina dei Materiali, Operative Group in Grenoble, c/o European Synchrotron Radiation Facility, B.P. 220, 38043 Grenoble (France); Schroeder, Thomas [IHP, Im Technologiepark 25, 15236 Frankfurt (Oder) (Germany); BTU Cottbus-Senftenberg, Konrad-Zuse-Str. 1, 03046 Cottbus (Germany); Boscherini, Federico [Consiglio Nazionale delle Ricerche, Istituto Officina dei Materiali, Operative Group in Grenoble, c/o European Synchrotron Radiation Facility, B.P. 220, 38043 Grenoble (France); Department of Physics and Astronomy, University of Bologna, via le C. Berti Pichat 6/2, 40127 Bologna (Italy)

2014-09-28T23:59:59.000Z

Note: This page contains sample records for the topic "mineral gadolinite ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Electrical anisotropy of mineralized and non mineralized rocks T.J. Katsube, M.E. Best*, and Jones, A.G., Geological Survey of Canada  

E-Print Network [OSTI]

PP 10.2 Electrical anisotropy of mineralized and non mineralized rocks T.J. Katsube, M.E. Best*, and Jones, A.G., Geological Survey of Canada Summary Significant electrical resistivity anisotropy, up to 1 to understand the electrical mechanisms involved in such anisotropic processes in order to provide information

Jones, Alan G.

282

456 IEEE TRANSACTIONS ON ROBOTICS, VOL. 24, NO. 2, APRIL 2008 the PA10-6CE utilizing the geometric and flexibility calibration method  

E-Print Network [OSTI]

456 IEEE TRANSACTIONS ON ROBOTICS, VOL. 24, NO. 2, APRIL 2008 the PA10-6CE utilizing the geometric for demanding dynamic ap- plications with the PA10-6CE robot arm. ACKNOWLEDGMENT The authors thank N. Mauntler in robot joints with harmonic drives and torque sensors," Int. J. Robot. Res., vol. 16, no. 2, pp. 214­ 239

283

The University of Florida Dean of Students O ce creates a culture of care for students, their families, faculty and sta by providing exemplary  

E-Print Network [OSTI]

The University of Florida Dean of Students O ce creates a culture of care for students. Develop an inclusive physical environment for Veteran services and resources. Focus energy towards 2012. Complete and implement recommendations from the O ce of Audit & Compliance Review internal audit

Roy, Subrata

284

The effect of Au and Ni doping on the heavy fermion state of the Kondo lattice antiferromagnet CePtZn  

SciTech Connect (OSTI)

We have probed the effect of doping CePtZn with Au and Ni and also investigated in detail the magnetic behavior of the iso-structural CeAuZn. A magnetic ground state is observed in both CePt{sub 0.9}Au{sub 0.1}Zn and CePt{sub 0.9}Ni{sub 0.1}Zn with T{sub N}?=?2.1 and 1.1?K and the coefficient of the linear term of electronic heat capacity ??=?0.34 and 0.9?J/mol K{sup 2}, respectively. The corresponding values for CePtZn are 1.7?K and 0.6?J/mol K{sup 2}. The altered values of T{sub N} and ? show that the electronic correlations in CePtZn are affected by doping with Au and Ni. CeAuZn orders magnetically near 1.7?K and its electrical resistivity shows a normal metallic behavior. Together with a ? of 0.022?J/mol K{sup 2} the data indicate a weak 4f-conduction electron hybridization in CeAuZn characteristic of normal trivalent cerium based systems.

Dhar, S. K., E-mail: sudesh@tifr.res.in [DCMPMS, T.I.F.R., Homi Bhabha Road, Colaba, Mumbai 400005 (India); Aoki, Y.; Suemitsu, B.; Miyazaki, R. [Department of Physics, Tokyo Metropolitan University, Minami-Ohsawa 1-1, Hachioji-Shi, Tokyo (Japan); Provino, A.; Manfrinetti, P. [Departimento Physica Chemicale, Universita di Genova, Via Dodecaneso, 16146 Genova (Italy)

2014-05-07T23:59:59.000Z

285

\\\\Ce_equine3\\public\\Cheryl\\WebDocuments\\OnLine\\CCYouthNomForm.doc NEW HAMPSHIRE 4-H CURRICULUM COMMITTEE  

E-Print Network [OSTI]

\\\\Ce_equine3\\public\\Cheryl\\WebDocuments\\OnLine\\CCYouthNomForm.doc NEW HAMPSHIRE 4-H CURRICULUM, including this year? #12;\\\\Ce_equine3\\public\\Cheryl\\WebDocuments\\OnLine\\CCYouthNomForm.doc 2. List and structure of 4-H (service, training, background, etc.) 4. What special attributes does this youth have

New Hampshire, University of

286

Momentum transfer driven textural changes of CeO{sub 2} thin films  

SciTech Connect (OSTI)

The influence of the target erosion depth on the film texture was investigated during DC reactive magnetron sputter deposition of CeO{sub 2} thin films. Three fluxes towards the substrate surface (the relative negative oxygen ion flux, the material flux, and the energy flux) were measured and related to the ongoing erosion of a cerium target. As the deposition rate increased for more eroded targets, both the energy flux and the negative ion flux decreased. Cerium oxide thin films that were deposited at different target erosion states, exhibited a change in preferential crystalline orientation from [200] to [111]. This textural change cannot be explained in terms of the energy per arriving atom concept. Instead, it is shown that the momentum of the high energetic negative ions is an essential condition to clarify the witnessed trends.

Van Steenberge, S., E-mail: sigelinde.vansteenberge@ugent.be; Leroy, W. P.; Depla, D. [Department of Solid State Sciences, Ghent University, Krijgslaan 281/S1, 9000 Ghent (Belgium); Hubin, A. [Department of Materials and Chemistry, Vrije Universiteit Brussel, Pleinlaan 2, 1050 Brussels (Belgium)

2014-09-15T23:59:59.000Z

287

Preparation, crystallography, magnetic and magnetothermal properties of Ce5SiGe4-x alloys  

SciTech Connect (OSTI)

An investigation of the crystal structure and the phase relationships in the Ce{sub 5}Si{sub 4-x}Ge{sub x} system has been carried out. The crystal structures of the single phase intermetallics were characterized using X-ray powder diffraction and subsequent refinement employing the Rietveld analysis technique was performed. The intermetallic system was found to crystallize in three distinct crystal structures. The Ce{sub 5}Si{sub 4}-based solid solution extends from x = 0 to x = 2.15 and it was found to crystallize in the well-known Zr{sub 5}Si{sub 4}-type tetragonal structure. The germanium rich alloys, where 3.1 {le} x {le} 4, crystallized in the Sm{sub 5}Ge{sub 4}-type orthorhombic structure. The crystal structure of the intermediate phase, when 2.35 {le} x {le} 2.8, was found out to be of the Gd{sub 5}Si{sub 2}Ge{sub 2}-type monoclinic structure. Microhardness tests were conducted on the samples in order to probe the trend in mechanical properties in this alloy system as a function of Ge concentration. The magnetic, thermal and magnetocaloric properties of the Ce{sub 5}Si{sub 4-x}Ge{sub x} alloy system have been investigated for x = 0, 1.0, 1.8, 2.5, 2.8, 3.5, 3.8 and 4.0. The phases with x = 0, 1.0 and 1.8 crystallize in the tetragonal Zr{sub 5}Si{sub 4} structure and those with x = 2.5, 2.8 form in the Gd{sub 5}Si{sub 2}Ge{sub 2}-type monoclinic structure. The alloys with x = 3.5, 3.8 and 4.0 crystallize in the Sm{sub 5}Ge{sub 4}-type orthorhombic structure. The Curie temperature of the tetragonal phases increases with increasing Ge content. The ordering temperatures of the monoclinic and orthorhombic phases remain nearly unaffected by the composition, with the Curie temperatures of the latter slightly higher than those of the former. All the alloys display evidence of antiferromagnetic interactions in the ground state. The orthorhombic and the monoclinic alloys behave as ferromagnets whereas the Si-rich tetragonal phase acts more like an antiferromagnet at high fields (1 T and higher). The maximum isothermal magnetic entropy change occurs at {approx}11 K in the monoclinic and orthorhombic phases with the highest value being 14.7 J/kg.K for Ce{sub 5}Ge{sub 4} for a field change of 10 T which is considered moderate.

Vijayaraghavan, Rangarajan

2005-05-01T23:59:59.000Z

288

Vortex Lattice Studies in CeCoIn? with H?c  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

We present small angle neutron scattering studies of the vortex lattice (VL) in CeCoIn? with magnetic fields applied parallel (H) to the antinodal [100] and nodal [110] directions. For H II 100], a single VL orientation is observed, while a 90° reorientation transition is found for H II [110]. For both field orientations and VL configurations we find a distorted hexagonal VL with an anisotropy, ?=2.0±0.05. The VL form factor shows strong Pauli paramagnetic effects similar to what have previously been reported for H II [001]. At high fields, above which the upper critical field (Hc2) becomes a first-order transition, an increased disordering of the VL is observed.

Das, P.; White, J. S.; Holmes, A. T.; Gerber, S.; Forgan, E. M.; Bianchi, A. D.; Kenzelmann, M.; Zolliker, M.; Gavilano, J. L.; Bauer, E. D.; Sarrao, J. L.; Petrovic, C.; Eskildsen, M. R.

2012-02-01T23:59:59.000Z

289

Theoretical studies of Ir5Th and Ir5Ce nanoscale precipitates in Ir  

SciTech Connect (OSTI)

Experimentally, it is known that very small amounts of thorium and/or cerium added to iridium metal form a precipitate, Ir5Th / Ir5Ce, which improves the high temperature mechanical properties of the resulting alloys. We demonstrate that there are low-energy configurations for nano-scale precipitates of these phases in Ir, and that these coherent arrangements may assist in producing improved mechanical properties. One precipitate/matrix orientation gives a particularly low interfacial energy, and a low lattice misfit. Nanolayer precipitates with this orientation are found to be likely to form, with little driving force to coarsen. The predicted morphology of the precipitates and their orientation with the matrix phase provide a potential experiment that could be used to test these predictions.

Morris, James R [ORNL] [ORNL; Averill, Frank [ORNL] [ORNL; Cooper, Valentino R [ORNL] [ORNL

2014-01-01T23:59:59.000Z

290

Complex magnetic ordering in CeFe1.76 studied by neutron diffraction  

SciTech Connect (OSTI)

Neutron diffraction measurements on a single crystal of CeGe1.76 reveal a complex series of magnetic transitions at low temperature. At TN?7 K, there is a transition from a paramagnetic state at higher temperature to an incommensurate magnetic structure characterized by a magnetic propagation vector (0 0 ?) with ??14 and the magnetic moment along the a axis of the orthorhombic unit cell. Below TLI?5 K, the magnetic structure locks in to a commensurate structure with ?=14 and the magnetic moment remains along the a axis. Below T??4 K, we find additional half-integer and integer indexed magnetic Bragg peaks consistent with a second commensurately ordered antiferromagnetic state.

Jayasekara, Wageesha T [Ames Laboratory; Tian, W [Oak Ridge National Laboratory; Hodovanets, Halyna [Ames Laboratory; Canfield, Paul C [Ames Laboratory; Bud'ko, Serguei L [Ames Laboratory; Kreyssig, Andreas [Ames Laboratory; Goldman, Alan I [Ames Laboratory

2014-10-01T23:59:59.000Z

291

MINERAL PROCESSING BY SHORT CIRCUITS IN PROTOPLANETARY DISKS  

SciTech Connect (OSTI)

Meteoritic chondrules were formed in the early solar system by brief heating of silicate dust to melting temperatures. Some highly refractory grains (Type B calcium-aluminum-rich inclusions, CAIs) also show signs of transient heating. A similar process may occur in other protoplanetary disks, as evidenced by observations of spectra characteristic of crystalline silicates. One possible environment for this process is the turbulent magnetohydrodynamic flow thought to drive accretion in these disks. Such flows generally form thin current sheets, which are sites of magnetic reconnection, and dissipate the magnetic fields amplified by a disk dynamo. We suggest that it is possible to heat precursor grains for chondrules and other high-temperature minerals in current sheets that have been concentrated by our recently described short-circuit instability. We extend our work on this process by including the effects of radiative cooling, taking into account the temperature dependence of the opacity; and by examining current sheet geometry in three-dimensional, global models of magnetorotational instability. We find that temperatures above 1600 K can be reached for favorable parameters that match the ideal global models. This mechanism could provide an efficient means of tapping the gravitational potential energy of the protoplanetary disk to heat grains strongly enough to form high-temperature minerals. The volume-filling nature of turbulent magnetic reconnection is compatible with constraints from chondrule-matrix complementarity, chondrule-chondrule complementarity, the occurrence of igneous rims, and compound chondrules. The same short-circuit mechanism may perform other high-temperature mineral processing in protoplanetary disks such as the production of crystalline silicates and CAIs.

McNally, Colin P. [Niels Bohr International Academy, Niels Bohr Institute, DK-2100 Copenhagen (Denmark); Hubbard, Alexander; Mac Low, Mordecai-Mark [Department of Astrophysics, American Museum of Natural History, New York, NY 10024-5192 (United States); Ebel, Denton S. [Department of Earth and Planetary Sciences, American Museum of Natural History, New York, NY 10024-5192 (United States); D'Alessio, Paola, E-mail: cmcnally@nbi.dk, E-mail: ahubbard@amnh.org, E-mail: mordecai@amnh.org, E-mail: debel@amnh.org, E-mail: p.dalessio@crya.unam.mx [Centro de Radioastronomia y Astrofisica, Universidad Nacional Autonoma de Mexico, 58089 Morelia, MICH (Mexico)

2013-04-10T23:59:59.000Z

292

UCL SChooL of Life and MediCaL SCienCeS Creating knowledge, achieving impact  

E-Print Network [OSTI]

UCL SChooL of Life and MediCaL SCienCeS Creating knowledge, achieving impact Population Health 4 #12;PREFACE UCL's School of Life and Medical Sciences encompasses arguably the greatest concentration Assessment Exercise was outstanding, and for most key measures the School comfortably tops UK league tables

Saunders, Mark

293

Pour citer ce document : CHELKOFF, Grgoire. For an ecological approach to architecture : perception and design. First International Workshop  

E-Print Network [OSTI]

Pour citer ce document : CHELKOFF, Grégoire. For an ecological approach to architecture : perception and design. First International Workshop : Architectural and urban Ambient Environment, Nantes, 6-7-8 Février 2002. Nantes: CERMA, Ecole D'architecture de Nantes, 2002, 11p. For an ecological approach

Paris-Sud XI, Université de

294

CO Oxidation at the Au-Cu Interface of Bimetallic Nanoclusters Supported on CeO2(111)  

E-Print Network [OSTI]

of tunable interfaces, metal and oxide,9,12,15-18 metal and carbide,19 and oxide and oxide,2 of the structure of CeO2(111)-supported Au- based bimetallic nanoclusters (NCs) show that a strong support-metal Materials, and Catalysis The critical role of the interface between a supporting oxide and supported metal

Henkelman, Graeme

295

Synthesis and properties of Sr2CeO4 blue emission powder phosphor for field emission displays  

E-Print Network [OSTI]

for publication 19 January 1999 A blue emission powder phosphor Sr2CeO4 for field emission displays was preparedV. The emission peak of this phosphor is at 470 nm and Commission International de l'Eclairage coordinates are x 0

Wang, Zhong L.

296

Potassium Fixation and Supply by Soils with Mixed Clay Minerals.  

E-Print Network [OSTI]

B-1090 December 1969 1 potassium Fixation and Supply By Soils With Misd Clay Minerals I KUS A&M UNIVERSITY Tcrv Agricultural Experiment Station r i 0. Kunkel, Acting Director, College Station, Texas Summary to the plants while Cameron clay... supplied onl!. Studies were made on three agriculturally important me/me of exchangeable K. The capacity of all a soils of South Texas and Northern Mexico to determine soils to fix K increased with increasing remo\\dl i their potassium (K)-supplying power...

Hipp, Billy W.

1969-01-01T23:59:59.000Z

297

NOVEL IN-SITU METAL AND MINERAL EXTRACTION TECHNOLOGY  

SciTech Connect (OSTI)

This white paper summarizes the state of art of in-situ leaching of metals and minerals, and describes a new technology concept employing improved fragmentation of ores underground in order to prepare the ore for more efficient in-situ leaching, combined with technology to continuously improve solution flow patterns through the ore during the leaching process. The process parameters and economic benefits of combining the new concept with chemical and biological leaching are described. A summary is provided of the next steps required to demonstrate the technology with the goal of enabling more widespread use of in-situ leaching.

Glenn O'Gorman; Hans von Michaelis; Gregory J. Olson

2004-09-22T23:59:59.000Z

298

The morphological and chemical characteristics of respirable mineral wool fibers  

E-Print Network [OSTI]

in these are rockwool, slagwool and fibrous glass, any one of wh1ch may be processed from a molten state into a fluffy, lightweight mass of fine, intermingled mineral fibers composed of complex sil1cates. Each of these f1bers may have quite different physical... the United States, I In the early product1on of man-made slag fibers a stream of high pressure steam was aimed at molten slag flowing from a blast furnace, The wool produced was used ma1nly in the makinq of mortar as its value as an insulat1on material...

Butler, Donnie Ray

1976-01-01T23:59:59.000Z

299

Mineral Deformation at Earth's Core-Mantle Boundary  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment SurfacesResource Program PreliminaryA3,0 Alabama - Natural GasMineral Deformation at

300

Mineral Deformation at Earth's Core-Mantle Boundary  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment SurfacesResource Program PreliminaryA3,0 Alabama - Natural GasMineral Deformation

Note: This page contains sample records for the topic "mineral gadolinite ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
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301

Mineral Deformation at Earth's Core-Mantle Boundary  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment SurfacesResource Program PreliminaryA3,0 Alabama - Natural GasMineral

302

Mineral Deformation at Earth's Core-Mantle Boundary  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recovery challenge fundProject8 -3EutecticMinding the Gap Makes for MoreMineral

303

Mineral Deformation at Earth's Core-Mantle Boundary  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recovery challenge fundProject8 -3EutecticMinding the Gap Makes forMineral

304

Charge transfer and formation of reduced Ce{sup 3+} upon adsorption of metal atoms at the ceria (110) surface  

SciTech Connect (OSTI)

The modification of cerium dioxide with nanoscale metal clusters is intensely researched for catalysis applications, with gold, silver, and copper having been particularly well studied. The interaction of the metal cluster with ceria is driven principally by a localised interaction between a small number of metal atoms (as small as one) and the surface and understanding the fundamentals of the interaction of metal atoms with ceria surfaces is therefore of great interest. Much attention has been focused on the interaction of metals with the (111) surface of ceria, since this is the most stable surface and can be grown as films, which are probed experimentally. However, nanostructures exposing other surfaces such as (110) show high activity for reactions including CO oxidation and require further study; these nanostructures could be modified by deposition of metal atoms or small clusters, but there is no information to date on the atomic level details of metal-ceria interactions involving the (110) surface. This paper presents the results of density functional theory (DFT) corrected for on-site Coulomb interactions (DFT+U) calculations of the adsorption of a number of different metal atoms at an extended ceria (110) surface; the metals are Au, Ag, Cu, Al, Ga, In, La, Ce, V, Cr, and Fe. Upon adsorption all metals are oxidised, transferring electron(s) to the surface, resulting in localised surface distortions. The precise details depend on the identity of the metal atom. Au, Ag, Cu each transfer one electron to the surface, reducing one Ce ion to Ce{sup 3+}, while of the trivalent metals, Al and La are fully oxidised, but Ga and In are only partially oxidised. Ce and the transition metals are also partially oxidised, with the number of reduced Ce ions possible in this surface no more than three per adsorbed metal atom. The predicted oxidation states of the adsorbed metal atoms should be testable in experiments on ceria nanostructures modified with metal atoms.

Nolan, Michael [Tyndall National Institute, University College Cork, Lee Maltings, Prospect Row, Cork (Ireland)

2012-04-07T23:59:59.000Z

305

Synthesis, Structures, and Magnetic Properties of Rare-Earth Cobalt Arsenides, RCo2As2 (R = La, Ce, Pr, Nd)  

SciTech Connect (OSTI)

Four rare-earth cobalt arsenides, RCo2As2 (R = La, Ce, Pr, Nd), were obtained by reactions of constituent elements in molten Bi. The use of Bi flux also allowed the growth of representative single crystals. All compounds are isostructural and belong to the ThCr2Si2 structure type (space group I4/mmm). The formation of Co vacancies is observed in all structures, while the structures of La- and Ce-containing compounds also show incorporation of minor Bi defects next to the R crystallographic site. Correspondingly, the general formula of these materials can be written as R1 xBixCo2 As2, with x/ = 0.03/0.1, 0.05/0.15, 0/0.2, and 0/0.3 for R = La, Ce, Pr, and Nd, respectively. All compounds exhibit high-temperature ferromagnetic ordering of Co magnetic moments in the range of 150-200 K. Electronic band structure calculations revealed a high peak in the density of states at the Fermi level, thus supporting the itinerant nature of magnetism in the Co sublattice. The magnetic ordering in the lanthanide sublattice takes place at lower temperatures, with the R moments aligning antiparallel to the Co moments to give a ferrimagnetic ground state. The measurements on oriented single crystals demonstrated significant magnetic anisotropy in the ferrimagnetic state, with the preferred moment alignment along the c axis of the tetragonal lattice. Neutron powder diffraction failed to reveal the structure of magnetically ordered states, but confirmed the presence of Co vacancies. X-ray absorption near-edge structure spectroscopy on Ce1.95Bi0.05Co1.85As2 showed the average oxidation state of Ce to be +3.06. Solid state NMR spectroscopy revealed a substantially reduced hyperfine field on the Co atoms in the vicinity of Bi defects.

Thompson, Corey [Florida State University, Tallahassee] [Florida State University, Tallahassee; Tan, Xiaoyan [Florida State University, Tallahassee] [Florida State University, Tallahassee; Kovnir, Kirill [Florida State University, Tallahassee] [Florida State University, Tallahassee; Garlea, Vasile O [ORNL] [ORNL; Shatruk, Michael [Florida State University, Tallahassee] [Florida State University, Tallahassee

2014-01-01T23:59:59.000Z

306

Quantitative determination of mineral composition by powder x-ray diffraction  

DOE Patents [OSTI]

An external standard intensity ratio method is used for quantitatively determining mineralogic compositions of samples by x-ray diffraction. The method uses ratios of x-ray intensity peaks from a single run. Constants are previously determined for each mineral which is to be quantitatively measured. Ratios of the highest intensity peak of each mineral to be quantified in the sample and the highest intensity peak of a reference mineral contained in the sample are used to calculate sample composition.

Pawloski, G.A.

1984-08-10T23:59:59.000Z

307

Dust suppression results using mineral oil applications on corn and milo  

E-Print Network [OSTI]

distribution (MCPSD) analysis, to determine the amount and particle size of the dust captured on the grain surface. Statistical analyses were performed on the effects due to dust concentration, mineral oil application and mineral oil*dust interaction. Each... TO CORN BENEFITS OF ADDING MINERAL OIL TO MILO 96 . 97 23 TREATMENT DESCRIPTION OP CORN SAMPLES USED FOR TESTING. 104 TREATMENT DESCRIPTION OF MILO SAMPLES USED FOR TESTING, . . . . . . . . . . . . . . PARTICLE SIZE DISTRIBUTION STATISTICS...

Wardlaw, Herman Douglas

1987-01-01T23:59:59.000Z

308

DOI Bureau of Indian Affairs Mineral Development Grants to Help with Development of Tribal Energy  

Broader source: Energy.gov [DOE]

The U.S. Department of the Interior, through the Bureau of Indian Affairs, Office of Indian Energy and Economic Development (IEED) is offering grants to federally-recognized Tribes and tribal energy resource development organizations for projects that help the development of a tribal energy and mineral resource inventory, a tribal energy and mineral resource on Indian land, or for the development of a report necessary to the development of energy and mineral resources on Indian lands.

309

Regulation of biological tissue mineralization through post-nucleation shielding  

E-Print Network [OSTI]

In vertebrates, insufficient availability of calcium and phosphate ions in extracellular fluids leads to loss of bone density and neuronal hyper-excitability. To counteract this problem, calcium ions are present at high concentrations throughout body fluids -- at concentrations exceeding the saturation point. This condition leads to the opposite situation where unwanted mineral sedimentation may occur. Remarkably, ectopic or out-of-place sedimentation into soft tissues is rare, in spite of the thermodynamic driving factors. This fortunate fact is due to the presence of auto-regulatory proteins that are found in abundance in bodily fluids. Yet, many important inflammatory disorders such as atherosclerosis and osteoarthritis are associated with this undesired calcification. Hence, it is important to gain an understanding of the regulatory process and the conditions under which it can go awry. In this Letter, we use ideas from mean-field classical nucleation theory to study the regulation of sedimentation of calcium phosphate salts in biological tissues through the mechanism of post-nuclear shielding of nascent mineral particles by binding proteins. A critical concentration of regulatory protein is identified as a function of the physical parameters that describe the system.

Joshua C. Chang; Robert M. Miura

2015-01-29T23:59:59.000Z

310

Society for Geology Applied to Ore Deposits GENEVA MINERALS: Industry and Academia  

E-Print Network [OSTI]

Society for Geology Applied to Ore Deposits GENEVA MINERALS: Industry and Academia Creating links Tripodi, Vanga Resources, Geneva · A student view of economic geology. Honza Catchpole, President

Halazonetis, Thanos

311

E-Print Network 3.0 - azoto mineral durante Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Futures Discussion Paper: Sustainability+Mineral... Future commodity outlooks New technology assessment Regions in transition Vision 2040: Mining, ... Source: University of...

312

E-Print Network 3.0 - adhesionvia template-driven mineralization...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Futures Discussion Paper: Sustainability+Mineral... Future commodity outlooks New technology assessment Regions in transition Vision 2040: Mining, ... Source: University of...

313

E-Print Network 3.0 - alkali mineral complex Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Geological Sciences, University of Manitoba Collection: Geosciences 44 Definitions CaX(s) + 90 Summary: Adsorption - surface complexation via a strong bond to a mineral...

314

Dept of Mathematical Sciences King Fahd University of Petroleum and Minerals  

E-Print Network [OSTI]

Seminar Dept of Mathematical Sciences King Fahd University of Petroleum and Minerals Presenter Dr, Smart Classroom # 203 Abstract The term regionalized variable is used to designate any variable

Omar, Mohammad H.

315

E-Print Network 3.0 - atrazine mineralization capacity Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Biotechnology 51 Improving Life through Science and Technology. Summary: ;12;12;Carbon Mineralization Gas tight 1-L glass containers Ten mL 1 M KOH Humidity...

316

Three Packets of Minerals of the Periodic Table of Chemical Elements and Chemical Compounds  

E-Print Network [OSTI]

The concepts of alpha- and beta-packets of the periodic table of chemical elements and chemical compounds are defined. The first of the 47 minerals alpha-packets is composed. In it all minerals are arranged in increasing Iav index of proportionality of atomic weights of composing chemical elements, the same way as chemical elements are located in increasing atomic weights in the Periodic table. The packet includes 93 known minerals and two compounds - N2O5 and CO2 - being actually minerals. Beta-packet of oxides and hydroxides minerals includes 88 known minerals and five chemical compounds - N2O5, CO2, CO, SO3 and SO2. Two minerals of the packet have not been determined yet. Besides, beta-packet of minerals with sulfur, selenium or arsenic is composed, with one mineral not defined yet. The results of the calculations can be used for further development of the Periodic Table of Chemical Elements and Chemical Compounds and their properties investigation.

Labushev, Mikhail M

2013-01-01T23:59:59.000Z

317

Three Packets of Minerals of the Periodic Table of Chemical Elements and Chemical Compounds  

E-Print Network [OSTI]

The concepts of alpha- and beta-packets of the periodic table of chemical elements and chemical compounds are defined. The first of the 47 minerals alpha-packets is composed. In it all minerals are arranged in increasing Iav index of proportionality of atomic weights of composing chemical elements, the same way as chemical elements are located in increasing atomic weights in the Periodic table. The packet includes 93 known minerals and two compounds - N2O5 and CO2 - being actually minerals. Beta-packet of oxides and hydroxides minerals includes 88 known minerals and five chemical compounds - N2O5, CO2, CO, SO3 and SO2. Two minerals of the packet have not been determined yet. Besides, beta-packet of minerals with sulfur, selenium or arsenic is composed, with one mineral not defined yet. The results of the calculations can be used for further development of the Periodic Table of Chemical Elements and Chemical Compounds and their properties investigation.

Mikhail M. Labushev

2013-03-20T23:59:59.000Z

318

1983 annual report on Alaska's mineral resources. Geological Survey Circular 908  

SciTech Connect (OSTI)

This report describes activity during 1982 in Alaska relating to oil and gas, uranium, coal and peat, geothermal resources, and non-fuel, critical and strategic minerals. (ACR)

Not Available

1983-01-01T23:59:59.000Z

319

E-Print Network 3.0 - atomic minerals exploration Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: , and adsorption of toxic atoms (such as arsenic) and molecules (such as dioxins) onto mineral surfaces 6... to simultaneously explore a wide range of contaminants...

320

Composition and method for self-assembly and mineralization of peptide-amphiphiles  

DOE Patents [OSTI]

The present invention is directed to a composition useful for making homogeneously mineralized self assembled peptide-amphiphile nanofibers and nanofiber gels. The composition is generally a solution comprised of a positively or negatively charged peptide-amphiphile and a like signed ion from the mineral. Mixing this solution with a second solution containing a dissolved counter-ion of the mineral and/or a second oppositely charged peptide amphiphile, results in the rapid self assembly of the peptide-amphiphiles into a nanofiber gel and templated mineralization of the ions. Templated mineralization of the initially dissolved mineral cations and anions in the mixture occurs with preferential orientation of the mineral crystals along the fiber surfaces within the nanofiber gel. One advantage of the present invention is that it results in homogenous growth of the mineral throughout the nanofiber gel. Another advantage of the present invention is that the nanofiber gel formation and mineralization reactions occur in a single mixing step and under substantially neutral or physiological pH conditions. These homogeneous nanostructured composite materials are useful for medical applications especially the regeneration of damaged bone in mammals. This invention is directed to the synthesis of peptide-amphiphiles with more than one amphiphilic moment and to supramolecular compositions comprised of such multi-dimensional peptide-amphiphiles. Supramolecular compositions can be formed by self assembly of multi-dimensional peptide-amphiphiles by mixing them with a solution comprising a monovalent cation.

Stupp, Samuel I. (Chicago, IL); Beniash, Elia (Newton, MA); Hartgerink, Jeffrey D. (Pearland, TX)

2012-02-28T23:59:59.000Z

Note: This page contains sample records for the topic "mineral gadolinite ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Rock, Mineral, Coal, Oil, and Gas Resources on State Lands (Montana)  

Broader source: Energy.gov [DOE]

This chapter authorizes and regulates prospecting permits and mining leases for the exploration and development of rock, mineral, oil, coal, and gas resources on state lands.

322

E-Print Network 3.0 - aqueous mineral carbonation Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

7 Relative stability and significance of dawsonite and aluminum minerals in geologic carbon sequestration Summary: Relative stability and significance of dawsonite and...

323

Reactivity of iron-bearing minerals and CO2 sequestration: A...  

Office of Scientific and Technical Information (OSTI)

Reactivity of iron-bearing minerals and CO2 sequestration: A multi-disciplinary experimental approach Re-direct Destination: The reactivity of sandstones was studied under...

324

E-Print Network 3.0 - apatite structured minerals Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

calcic garnet and clinopyroxene, REE primarily occupy the structural position... and titanite i.e. minerals that preferentially incorporate ... Source: Arrhenius, Gustaf -...

325

Effect of MnO on the microstructures, phase stability and mechanical properties of ceria-partially-stabilized zirconia (Ce-TZP) and Ce-TZP-Al sub 2 O sub 3 composites  

SciTech Connect (OSTI)

Effect of increasing amounts of MnO additions on the microstructures, phase stability and mechanical properties of ZrO{sub 2}-12 m% CeO{sub 2} and ZrO{sub 2}-12 m% CeO{sub 2}-10 w% Al{sub 2}O{sub 3} were studied. MnO suppressed grain growth in ZrO{sub 2}-12 m% CeO{sub 2}, while enhancing the mechanical properties significantly (strength=557 MPa, fracture toughness=9.3 MPa.(m){sup 1/2} at 0.2 w% MnO). The enhanced mechanical properties were achieved despite an increased stability of the tetragonal phase as evidenced by a lower burst transformation temperature (M{sub b}) and a reduced volume fraction of the monoclinic phase on the fracture surface. In ZrO{sub 2}-12 m% CeO{sub 2}-10 w% Al{sub 2}O{sub 3}, the addition of MnO suppressed the grain size of ZrO{sub 2}, while promoting grain growth and changing the morphology of Al{sub 2}O{sub 3}. More significantly, the stability of the tetragonal ZrO{sub 2} phase decreased (high M{sub b} temperature) with a concurrent increase in fracture toughness (13.2 MPa.(m){sup 1/2} at 2 w% MnO) and transformation plasticity (1.2% in four-point bending). The widths of the transformation zones observed adjacent to the fracture surfaces showed a consistent inverse relation to the transformation yield stress as would be expected from the mechanics of stress-induced phase transformation at crack tips. The improvements in mechanical properties obtained in the base Ce-TZP and the Ce-TZP-Al{sub 2}O{sub 3} composite ceramics with the addition of MnO are critically examined in the context of transformation toughening and other possible mechanisms.

Wang, J.S.; Tsai, J.F.; Shetty, D.K.; Virkar, A.V. (Department of Materials Science and Engineering, University of Utah, Salt Lake City, UT (USA))

1990-09-01T23:59:59.000Z

326

Plutonium Oxidation and Subsequent Reduction by Mn (IV) Minerals  

SciTech Connect (OSTI)

Plutonium sorbed to rock tuff was preferentially associated with manganese oxides. On tuff and synthetic pyrolusite (Mn{sup IV}O{sub 2}), Pu(IV) or Pu(V) was initially oxidized, but over time Pu(IV) became the predominant oxidation state of sorbed Pu. Reduction of Pu(V/VI), even on non-oxidizing surfaces, is proposed to result from a lower Gibbs free energy of the hydrolyzed Pu(IV) surface species versus that of the Pu(V) or Pu(VI) surface species. This work suggests that despite initial oxidation of sorbed Pu by oxidizing surfaces to more soluble forms, the less mobile form of Pu, Pu(IV), will dominate Pu solid phase speciation during long term geologic storage. The safe design of a radioactive waste or spent nuclear fuel geologic repository requires a risk assessment of radionuclides that may potentially be released into the surrounding environment. Geochemical knowledge of the radionuclide and the surrounding environment is required for predicting subsurface fate and transport. Although difficult even in simple systems, this task grows increasingly complicated for constituents, like Pu, that exhibit complex environmental chemistries. The environmental behavior of Pu can be influenced by complexation, precipitation, adsorption, colloid formation, and oxidation/reduction (redox) reactions (1-3). To predict the environmental mobility of Pu, the most important of these factors is Pu oxidation state. This is because Pu(IV) is generally 2 to 3 orders of magnitude less mobile than Pu(V) in most environments (4). Further complicating matters, Pu commonly exists simultaneously in several oxidation states (5, 6). Choppin (7) reported Pu may exist as Pu(IV), Pu(V), or Pu(VI) oxic natural groundwaters. It is generally accepted that plutonium associated with suspended particulate matter is predominantly Pu(IV) (8-10), whereas Pu in the aqueous phase is predominantly Pu(V) (2, 11-13). The influence of the character of Mn-containing minerals expected to be found in subsurface repository environments on Pu oxidation state distributions has been the subject of much recent research. Kenney-Kennicutt and Morse (14), Duff et al. (15), and Morgenstern and Choppin (16) observed oxidation of Pu facilitated by Mn(IV)-bearing minerals. Conversely, Shaughnessy et al. (17) used X-ray Absorption near-edge spectroscopy (XANES) to show reduction of Pu(VI) by hausmannite (Mn{sup II}Mn{sub 2}{sup III}O{sub 4}) and manganite ({gamma}-Mn{sup III}OOH) and Kersting et al., (18) observed reduction of Pu(VI) by pyrolusite (Mn{sup IV}O{sub 2}). In this paper, we attempt to reconcile the apparently conflicting datasets by showing that Mn-bearing minerals can indeed oxidize Pu, however, if the oxidized species remains on the solid phase, the oxidation step competes with the formation of Pu(IV) that becomes the predominant solid phase Pu species with time. The experimental approach we took was to conduct longer term (approximately two years later) oxidation state analyses on the Pu sorbed to Yucca Mountain tuff (initial analysis reported by Duff et al., (15)) and measure the time-dependant changes in the oxidation state distribution of Pu in the presence of the Mn mineral pyrolusite.

KAPLAN, DANIEL

2005-09-13T23:59:59.000Z

327

Utilization of coal-associated minerals. Final report  

SciTech Connect (OSTI)

Under contract number DE-AS21-77ET10533 with the US-DOE several methods of utilizing coal associated by-products were examined for potential commercial use. Such use could transform a costly waste disposal situation into new materials for further use and could provide incentive for the adoption of new coal utilization processes. Several utilization processes appear to have merit and are recommended for further study. Each process is discussed separately in the text of this report. Common coal cleaning processes were also examined to determine the effect of such processes on the composition of by-products. Data obtained in this portion of the research effort are reported in the Appendix. Information of this type is required before utilization processes can be considered. A knowledge of the mineral composition of these materials is also required before even simple disposal methods can be considered.

Slonaker, J. F.; Akers, D. J.; Alderman, J. K.

1980-01-01T23:59:59.000Z

328

Uranium mineralization in fluorine-enriched volcanic rocks  

SciTech Connect (OSTI)

Several uranium and other lithophile element deposits are located within or adjacent to small middle to late Cenozoic, fluorine-rich rhyolitic dome complexes. Examples studied include Spor Mountain, Utah (Be-U-F), the Honeycomb Hills, Utah (Be-U), the Wah Wah Mountains, Utah (U-F), and the Black Range-Sierra Cuchillo, New Mexico (Sn-Be-W-F). The formation of these and similar deposits begins with the emplacement of a rhyolitic magma, enriched in lithophile metals and complexing fluorine, that rises to a shallow crustal level, where its roof zone may become further enriched in volatiles and the ore elements. During initial explosive volcanic activity, aprons of lithicrich tuffs are erupted around the vents. These early pyroclastic deposits commonly host the mineralization, due to their initial enrichment in the lithophile elements, their permeability, and the reactivity of their foreign lithic inclusions (particularly carbonate rocks). The pyroclastics are capped and preserved by thick topaz rhyolite domes and flows that can serve as a source of heat and of additional quantities of ore elements. Devitrification, vapor-phase crystallization, or fumarolic alteration may free the ore elements from the glassy matrix and place them in a form readily leached by percolating meteoric waters. Heat from the rhyolitic sheets drives such waters through the system, generally into and up the vents and out through the early tuffs. Secondary alteration zones (K-feldspar, sericite, silica, clays, fluorite, carbonate, and zeolites) and economic mineral concentrations may form in response to this low temperature (less than 200 C) circulation. After cooling, meteoric water continues to migrate through the system, modifying the distribution and concentration of the ore elements (especially uranium).

Burt, D.M.; Sheridan, M.F.; Bikun, J.; Christiansen, E.; Correa, B.; Murphy, B.; Self, S.

1980-09-01T23:59:59.000Z

329

Societal demand for increasing mineral resources Canada has made significant contributions  

E-Print Network [OSTI]

Societal demand for increasing mineral resources Canada has made significant contributions. The discovery of new mineral resources requires increasing risk, increasing costs, and increasingly effective Vancouver has long been a global leader continue to affect society through aspects as varied as high metal

Michelson, David G.

330

Global Mineral Resource Assessment Potash--A Global Overview of Evaporite-Related Potash  

E-Print Network [OSTI]

Global Mineral Resource Assessment Potash--A Global Overview of Evaporite-Related Potash Resources intentionally left blank. #12;Global Mineral Resource Assessment Michael L. Zientek, Jane M. Hammarstrom, and Kathleen M. Johnson, editors Potash--A Global Overview of Evaporite-Related Potash Resources, Including

Fleskes, Joe

331

Soil Tillage Influences on Soil Mineral Nitrogen and Nitrate Leaching in  

E-Print Network [OSTI]

Soil Tillage Influences on Soil Mineral Nitrogen and Nitrate Leaching in Swedish Arable Soils Åsa Myrbeck Faculty of Natural Resources and Agricultural Sciences Department of Soil and Environment Uppsala field experiment, Paper III. (photo: J. Arvidsson) #12;Soil Tillage Influences on Soil Mineral Nitrogen

332

Borehole Miner - Extendible Nozzle Development for Radioactive Waste Dislodging and Retrieval from Underground Storage Tanks  

SciTech Connect (OSTI)

This report summarizes development of borehole-miner extendible-nozzle water-jetting technology for dislodging and retrieving salt cake, sludge} and supernate to remediate underground storage tanks full of radioactive waste. The extendible-nozzle development was based on commercial borehole-miner technology.

CW Enderlin; DG Alberts; JA Bamberger; M White

1998-09-25T23:59:59.000Z

333

Clay and non-clay minerals in the pharmaceutical industry Part I. Excipients and medical applications  

E-Print Network [OSTI]

Clay and non-clay minerals in the pharmaceutical industry Part I. Excipients and medical in the pharmaceutical industry as lubricants, desiccants, disintegrants, diluents, binders, pigments and opaci ers form 17 July 2009 Accepted 22 July 2009 Available online 29 July 2009 Keywords: Minerals Pharmaceutical

Ahmad, Sajjad

334

Review Article Clay and non-clay minerals in the pharmaceutical and cosmetic industries  

E-Print Network [OSTI]

Review Article Clay and non-clay minerals in the pharmaceutical and cosmetic industries Part II Pharmaceutical industry Cosmetic industry Active ingredients Physical and physico-chemical properties A wide range and variety of minerals are used in the pharmaceutical industry as active ingredients

Ahmad, Sajjad

335

U.S. GEOLOGICAL SURVEY--MINERALS INFORMATION 1 By Joyce A. Ober  

E-Print Network [OSTI]

sell lithium as mineral concentrate, brine, compound, data for lithium from a voluntary survey of U of the material to determine if sales of the mercury-contaminated material presented a risk to environmental its brine deposit in Silver Peak, NV (Cyprus Amax Minerals Co., 1997). In addition to its Nevada

336

Copyright: King Fahd University of Petroleum & Minerals; http://www.kfupm.edu.sa  

E-Print Network [OSTI]

© Copyright: King Fahd University of Petroleum & Minerals; http://www.kfupm.edu.sa On Optimal SYSTEMS AND APPLICATIONS, VOLS 1 AND 2; pp: 819-824; Vol: ## King Fahd University of Petroleum & Minerals http://www.kfupm.edu.sa Summary In today's online connected world, almost all corporate networks use

El-Alfy, El-Sayed

337

Spatially-Correlated Mass Spectrometric Analysis of Microbe-Mineral Interactions  

SciTech Connect (OSTI)

A new methodology for examining the interactions of microbes with heterogeneous minerals is presented. Imaging laser-desorption Fourier transform mass spectrometry was used to examine the colonization patterns of Burkholderia vietnamiensis (Burkholderia cepacia) G4 on a heterogeneous basalt sample. Depth-profile imaging found that the bacterium preferentially colonized the plagioclase mineral phases within the basalt.

Jill R. Scott; Beizhan Yan; Daphne L. Stoner

2006-11-01T23:59:59.000Z

338

Fibrous-clay mineral formation and soil evolution in Aridisols of northeastern Patagonia, Argentina  

E-Print Network [OSTI]

Fibrous-clay mineral formation and soil evolution in Aridisols of northeastern Patagonia, Argentina Patagónico, CONICET, Avd. Brown s/n, 9120, Puerto Madryn, Chubut, Argentina b Departamento de Edafología, EPS horizons; Chubut province of Argentina 1. Introduction Palygorskite and sepiolite are clay minerals

Ahmad, Sajjad

339

Electrical conductivity of minerals and rocks Shun-ichiro Karato1  

E-Print Network [OSTI]

1 Electrical conductivity of minerals and rocks Shun-ichiro Karato1 and Duojun Wang1,2 1 : Yale-Blackwell #12;2 SUMMARY Electrical conductivity of most minerals is sensitive to hydrogen (water) content, temperature, major element chemistry and oxygen fugacity. The influence of these parameters on electrical

340

Minerals to Dairy Cows with Focus on Calcium and Magnesium Balance  

E-Print Network [OSTI]

Minerals to Dairy Cows with Focus on Calcium and Magnesium Balance Cecilia Kronqvist Faculty;Minerals to Dairy Cows with Focus on Calcium and Magnesium Balance Abstract Both clinical and subclinical deficiency of calcium and magnesium may cause problems in dairy cows. Clinical hypocalcaemia most commonly

Note: This page contains sample records for the topic "mineral gadolinite ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

ATOMIC-LEVEL IMAGING OF CO2 DISPOSAL AS A CARBONATE MINERAL: OPTIMIZING REACTION PROCESS DESIGN  

SciTech Connect (OSTI)

Fossil fuels, especially coal, can support the energy demands of the world for centuries to come, if the environmental problems associated with CO{sub 2} emissions can be overcome. Permanent and safe methods for CO{sub 2} capture and disposal/storage need to be developed. Mineralization of stationary-source CO{sub 2} emissions as carbonates can provide such safe capture and long-term sequestration. Mg-rich lamellar-hydroxide based minerals (e.g., brucite and serpentine) offer a class of widely available, low-cost materials, with intriguing mineral carbonation potential. Carbonation of such materials inherently involves dehydroxylation, which can disrupt the material down to the atomic level. As such, controlled dehydroxylation before and/or during carbonation may provide an important parameter for enhancing carbonation reaction processes. Mg(OH){sub 2} was chosen as the model material for investigating lamellar hydroxide mineral dehydroxylation/carbonation mechanisms due to (i) its structural and chemical simplicity, (ii) interest in Mg(OH){sub 2} gas-solid carbonation as a potentially cost-effective CO{sub 2} mineral sequestration process component, and (iii) its structural and chemical similarity to other lamellar-hydroxide-based minerals (e.g., serpentine-based minerals) whose carbonation reaction processes are being explored due to their low-cost CO{sub 2} sequestration potential. Fundamental understanding of the mechanisms that govern dehydroxylation/carbonation processes is essential for cost optimization of any lamellar-hydroxide-based mineral carbonation sequestration process.

M.J. McKelvy; R. Sharma; A.V.G. Chizmeshya; H. Bearat; R.W. Carpenter

2000-08-01T23:59:59.000Z

342

Structure and Dynamics of Monolayer Growth at Mineral-Water Interfaces  

E-Print Network [OSTI]

Structure and Dynamics of Monolayer Growth at Mineral-Water Interfaces Geri Richmond Department insights into structure and dynamics of these interfaces. The driving forces behind adsorption at mineral an important role. In this presentation I will describe our recent studies measuring the structure and dynamics

Richmond, Geraldine L.

343

An epidemiological study of salt miners in diesel and nondiesel mines  

SciTech Connect (OSTI)

A cross-sectional study of 5 NaCl mines and 259 miners addressed the following questions: 1) Is there an association of increased respiratory symptoms, radiographic findings, and reduced pulmonary function with exposure to nitrogen dioxide (NO2) and/or respirable particulate (RP) among these miners. 2) Is there increased morbidity of these miners compared to other working populations. Personal samples of NO2 and respirable particulate for jobs in each mine were used to estimate cumulative exposure. NO2 is used as a surrogate measure of diesel exposure. Cough was associated with age and smoking, dyspnea with age; neither symptom was associated with exposure (years worked, estimated cumulative NO2 or RP exposure). Phlegm was associated with age, smoking, and exposure. Reduced pulmonary function (FVC, FEV1, peak, flow, FEF50, FEF75) showed no association with exposure. There was one case of small rounded and one case of small irregular opacities; pneumoconiosis was not analyzed further. Compared to underground coal miners, above ground coal miners, potash miners, and nonmining workers, the study population after adjustment for age and smoking generally showed no increased prevalence of cough, phlegm, dyspnea, or obstruction (FEV1/FVC less than 0.7). Obstruction in younger salt miners and phlegm in older salt miners was elevated compared to nonmining workers. Mean predicted pulmonary function was reduced 2-4% for FEV1 and FVC, 7-13% for FEF50, and 18-22% for FEF75 below all comparison populations.

Gamble, J.; Jones, W.; Hudak, J.

1983-01-01T23:59:59.000Z

344

Mineral replacement rate of olivine by chrysotile and brucite under high1 alkaline conditions2  

E-Print Network [OSTI]

1 Mineral replacement rate of olivine by chrysotile and brucite under high1 alkaline conditions2 3.1016/j.jcrysgro.2012.02.040 #12;2 Abstract16 Olivine mineral replacement by serpentine is one major replaced by18 chrysotile and brucite under high alkaline conditions. In our study, olivine replacement19

Paris-Sud XI, Université de

345

Mineral paragenesis and textures associated with sandstone-hosted roll-front uranium deposits, NW China  

E-Print Network [OSTI]

, People's Republic of China c Northwest Institute of Uranium Geology, China National Nuclear CorporationMineral paragenesis and textures associated with sandstone-hosted roll-front uranium deposits, NW, Wuyiyi and Shihongtan sandstone-hosted roll-front uranium deposits, northwest China. The mineralization

Fayek, Mostafa

346

Nitrogen mineralization potentials of revegetated mixed lignite overburden in the Texas Gulf Coast  

E-Print Network [OSTI]

and Chemical Characteristics Analysis of Data. CHAPTER IV: RESULTS AND DISCUSSION. Physical Properties of Spoil and Native Soil. Nitrogen Mineralization Potentials and Rate Constants Nitrogen Pool Nitrification and Denitrification Most Probable Numbers.... Chemical Properties of Native Soil and Spoil Before and After Amendment. Chemical and Physical Properties of Sewage Sludge . Laboratory Incubation Study . Determination of Nitrogen Mineralized . Determining Populations of Nitrifying Bacteria, Physcial...

Hornby, William Joseph

1984-01-01T23:59:59.000Z

347

emissions: mineral carbonation and Finnish pulp and paper industry (CO2  

E-Print Network [OSTI]

CO2 emissions: mineral carbonation and Finnish pulp and paper industry (CO2 Nordic Plus) and Use carbonation processes. One aspect was to verify the possible use of mineral carbon- ation for the separation, utilisation and long-term storage of carbon dioxide (CO2) in the pulp and paper industry. The Geological

Zevenhoven, Ron

348

A benchmark for investigating the radial dependence of C/E for control rod worths in large decoupled cores  

SciTech Connect (OSTI)

The first physics measurements of a heterogeneous core on the critical assembly ZPPR-7 at ANL showed that the C/E ratios with ENDF/B data for the worths of the control rods in the outer bank were several percent higher than those at the inner bank positions. This radial variation in the C/E for the rod worths was further confirmed in the analysis of the large conventional core ZPPR-10, and again in the analysis of the large heterogeneous core series ZPPR-13. In the design of a power reactor, the number of control rods, and their disposition, are determined by calculations. Misprediction of the worth of the control rods can lead to serious economic penalties by restricting the operation of the core. Retrofitting a core to accommodate more worth will be costly and is likely to lead to a non-optimized core. This document provides a discussion of these calculations. 7 refs., 7 figs., 12 tabs.

Salvatores, M. (CEA Centre d'Etudes Nucleaires de Cadarache, 13 - Saint-Paul-lez-Durance (France)); Orechwa, Y. (Argonne National Lab., IL (USA)); Collins, P.J. (Argonne National Lab., Idaho Falls, ID (USA))

1990-01-01T23:59:59.000Z

349

Q-dependence of the spin fluctuations in the intermediate valence compound CePd3  

SciTech Connect (OSTI)

We report inelastic neutron scattering experiments on a single crystal of the intermediate valence compound CePd3. At 300 K the magnetic scattering is quasielastic, with half-width G = 23 meV, and is independent of momentum transfer Q. At low temperature, the Q-averaged magnetic spectrum is inelastic, exhibiting a broad peak centered near E-max = 55 meV. These results, together with the temperature dependence of the susceptibility, 4f occupation number, and specific heat, can be fit by the Kondo/Anderson impurity model. The low temperature scattering near Emax, however, shows significant variations with Q, reflecting the coherence of the 4f lattice. The intensity is maximal at (1/2, 1/2, 0), intermediate at (1/2, 0, 0) and (0, 0, 0), and weak at (1/2, 1/2, 1/2). We discuss this Q-dependence in terms of current ideas about coherence in heavy fermion systems.

Fanelli, V. R.; Lawrence, J. M.; Goremychkin, E. A.; Osborn, R.; Bauer, E. D.; McClellan, K. J.; Thompson, J. D.; Booth, C. H.; Christianson, A. D.; Riseborough, P. S.

2014-06-25T23:59:59.000Z

350

Observation of inner-shell-excited configurations in triply ionized cerium Ce{sup 3+}  

SciTech Connect (OSTI)

We report wavelength measurements and energy levels for the three-times ionized cerium atom Ce{sup 3+}. The spectrum is that of a simple one-electron atom overlaid with a more complex three-electron spectrum originating from the excitation of an electron in the inner closed shell to the valence shell. The data provide energy levels for the inner-shell-excited configurations 5p{sup 5}4f5d and 5p{sup 5}4f6s and solve a long-standing puzzle regarding the fine structure of the 5p{sup 6}6d configuration, which is known to be anomalously large and inverted. The data show that this anomalous fine structure is the result of interaction between 5p{sup 6}6d and the inner-shell-excited configuration 5p{sup 5}4f5d. The results are supported by Hartree-Fock calculations and least-squares fits of the energy parameters to the observed levels. From our observed 5p{sup 6}6g configuration, we determine the ionization energy as 297670{+-}70 cm{sup -1} (36.906{+-}0.009 eV)

Reader, Joseph; Wyart, Jean-Francois [National Institute of Standards and Technology, Gaithersburg, Maryland 20899 (United States); Laboratoire Aime Cotton, CNRS, Universite Paris-Sud, Batiment 505, 91405 Orsay Cedex (France)

2009-10-15T23:59:59.000Z

351

Ion-Beam-Induced Chemical Mixing at a Nanocrystalline CeO2–Si Interface  

SciTech Connect (OSTI)

Thin films of nanocrystalline ceria deposited onto a silicon substrate have been irradiated with 3 MeV Au+ ions to a total dose of 34 displacements per atom to examine the film/substrate interfacial response upon displacement damage. Under irradiation, a band of contrast is observed to form that grows under further irradiation. Scanning and high-resolution transmission electron microscopy imaging and analysis suggest that this band of contrast is a cerium silicate phase with an approximate Ce:Si:O composition ratio of 1:1:3 in an amorphous nature. The slightly nonstoichiometric composition arises due to the loss of mobile oxygen within the cerium silicate phase under the current irradiation condition. This nonequilibrium phase is formed as a direct result of ion-beam-induced chemical mixing caused by ballistic collisions between the incoming ion and the lattice atoms. This may hold promise in ion beam engineering of cerium silicates for microelectronic applications e.g., the fabrication of blue LEDs.

Edmondson, P. D.; Young, Niel P.; Parish, Chad M.; Moll, Sandra J.; Namavar, Fereydoon; Weber, William J.; Zhang, Yanwen

2013-02-28T23:59:59.000Z

352

Ion-Beam-Induced Chemical Mixing at a Nanocrystalline CeO2 Si Interface  

SciTech Connect (OSTI)

Thin films of nanocrystalline ceria deposited onto a silicon substrate have been irradiated with 3 MeV Au+ ions to a total dose of 34 displacements per atom to examine the film/substrate interfacial response upon displacement damage. Under irradiation, a band of contrast is observed to form that grows under further irradiation. Scanning and high-resolution transmission electron microscopy imaging and analysis suggest that this band of contrast is a cerium silicate phase with an approximate Ce:Si:O composition ratio of 1:1:3 in an amorphous nature. The slightly nonstoichiometric composition arises due to the loss of mobile oxygen within the cerium silicate phase under the current irradiation condition. This nonequilibrium phase is formed as a direct result of ion-beam-induced chemical mixing caused by ballistic collisions between the incoming ion and the lattice atoms. This may hold promise in ion beam engineering of cerium silicates for microelectronic applications e.g., the fabrication of blue LEDs.

Edmondson, Dr. Philip [University of Oxford; Young, Neil P. [Department of Materials, University of Oxford, Parks Rd, Oxford, OX1 3PH, UK; Parish, Chad M [ORNL; Moll, Sandra [CEA, Saclay, France; Namavar, Fereydoon [University of Nebraska Medical Center; Weber, William J [ORNL; Zhang, Yanwen [ORNL

2013-01-01T23:59:59.000Z

353

Structure Sensitivity of the Low-temperature Water-gas Shift Reaction on Cu–CeO2 catalysts  

SciTech Connect (OSTI)

We have investigated the structure sensitivity of the water-gas shift (WGS) reaction on Cu-CeO{sub 2} catalysts prepared at the nanoscale by different techniques. On the surface of ceria, different CuO{sub x} structures exist. We show here that only the strongly bound Cu-[O{sub x}]-Ce species, probably associated with the surface oxygen vacancies of ceria, are active for catalyzing the low-temperature WGS reaction. Weakly bound CuO{sub x} clusters and CuO nanoparticles are spectator species in the reaction. Isolated Cu{sup 2+} ions doping the ceria surface are not active themselves, but they are important in that they create oxygen vacancies and can be used as a reservoir of copper to replenish surface Cu removed by leaching or sintering. Accordingly, synthesis techniques such as coprecipitation that allow for extensive solubility of Cu in ceria should be preferred over impregnation, deposition-precipitation, ion exchange or another two-step method whereby the copper precursor is added to already made ceria nanocrystals. For the synthesis of different structures, we have used two methods: a homogeneous coprecipitation (CP), involving hexamethylenetetramine as the precipitating agent and the pH buffer; and a deposition-precipitation (DP) technique. In the latter case, the ceria supports were first synthesized at the nanoscale with different shapes (rods, cubes) to investigate any potential shape effect on the reaction. Cu-CeO{sub 2} catalysts with different copper contents up to ca. 20 at.% were prepared. An indirect shape effect of CeO{sub 2}, manifested by the propensity to form oxygen vacancies and strongly bind copper in the active form, was established; i.e. the water-gas shift reaction is not structure-sensitive. The apparent activation energy of the reaction on all samples was similar, 50 {+-} 10 kJ/mol, in a product-free (2% CO-10% H{sub 2}O) gas mixture.

Si, R.; Zhang, L.; Raitano, J.; Yi, N.; Chan, S.-W.; Flytzani-Stephanopoulos, M.

2012-01-17T23:59:59.000Z

354

Characterization of Ce SUP 3+-tributyl phosphate coordination complexes produced by fused droplet electrospray ionization with a target capillary  

SciTech Connect (OSTI)

Coordination complexes containing Ce(III) and tri-n-butyl phosphate (TBP) in the 1+, 2+ and 3+ charge states were generated using desorption electrospray ionization (DESI) mass spectrometry, in which the analyte solutions were supplied via a target capillary orthogonally situated with respect to the electrospray. Comparison with direct electrospray (ESI) showed that the same coordination complexes were produced in each experiment, and could be described by the general formula [Ce(NO3)m=0-2(TBP)n](3-m)+. This result indicates that DESI has utility for measuring metal speciation for metal ligand solutions where the gas-phase complexes generated by ESI have been correlated with solution speciation. Such an application would be useful for analyses where it is desirable to limit the total amount of metal being handled, or that have solvent systems that are not readily amenable to ESI. Both the direct ESI and DESI mass spectra showed similar trends with respect to the TBP:Ce ratio, viz. high values tend to favor formation of a larger fraction of the 1+ species, and the 2+ and 3+ species become relatively more important as the ratio is decreased. Within individual charge state ion envelopes, lower TBP:Ce ratios produce coordination complexes with fewer ligands, a trend also seen using both approaches. These trends again point toward strong similarity between the direct ESI and DESI analyses of the metal-ligand solutions. The DESI experiments were less sensitive for measuring the coordination complexes compared to the direct ESI experiments, by a factor of 10 - 100 depending on whether minimum detectable concentration or absolute ion abundances were considered. Nevertheless, mid-picomolar quantities of coordination complexes were measured using the target capillary, indicating that sensitivity would be sufficient for measuring species in many industrial separations processes.

Gary S. Groenewold; Jean-Jacques Gaumet

2011-12-01T23:59:59.000Z

355

Analysis of stream sediment reconnaissance data for mineral resources from the Montrose NTMS Quadrangle, Colorado  

SciTech Connect (OSTI)

Multivariate statistical analysis to support the National Uranium Resource Evaluation and to evaluate strategic and other commercially important mineral resources was carried out on Hydrogeochemical and Stream Sediment Reconnaissance data from the Montrose quadrangle, Colorado. The analysis suggests that: (1) the southern Colorado Mineral Belt is an area favorable for uranium mineral occurrences; (2) carnotite-type occurrences are likely in the nose of the Gunnison Uplift; (3) uranium mineral occurrences may be present along the western and northern margins of the West Elk crater; (4) a base-metal mineralized area is associated with the Uncompahgre Uplift; and (5) uranium and base metals are associated in some areas, and both are often controlled by faults trending west-northwest and north.

Beyth, M.; Broxton, D.; McInteer, C.; Averett, W.R.; Stablein, N.K.

1980-06-01T23:59:59.000Z

356

Anomalous Chemical Expansion Behavior of Pr[subscript 0.2]Ce[subscript 0.8]O[subscript 2-?] Thin Films Grown by Pulsed Laser Deposition  

E-Print Network [OSTI]

The chemomechanical and electrical properties of (Pr,Ce)O[subscript 2-?] thin films were studied between 30 and 875°C in air by in situ X-ray diffraction and complex impedance spectroscopy measurements. Reduction/oxidation ...

Kuru, Y.

357

Adsorption and Reaction of C(1)-C(3) Alcohols over CeO(x)(111) Thin Films  

SciTech Connect (OSTI)

This study reports the interaction of methanol, ethanol, 1-propanol, and 2-propanol with well-ordered CeO{sub 2}(111) thin film surfaces. All of the alcohols adsorb at low temperature by forming alkoxy and hydroxyl species on the surface. On fully oxidized CeO{sub 2}(111), recombination occurs between some of the alkoxys and hydroxyls, resulting in alcohol desorption near 220 K. At the same temperature, some of the surface hydroxyls disproportionate to produce water and the loss of lattice O. The remaining alkoxys react above 550 K. The primary alcohols favor dehydrogenation products (aldehydes). There is a net loss of O from the system, resulting in a reduction of the ceria. The secondary alcohol, 2-propanol, undergoes primarily dehydration, producing propene with no net change in the cerium oxidation state. Reduced CeO{sub X}(111) competes with the gaseous products for available O. Little or no water is produced. The reaction selectivity for the C{sub 2} and C{sub 3} alcohols shifts toward favoring dehydration products. The loss of O from the alcohols leads to oxidation of the reduced ceria. Compared with the oxidized surface, the alkene desorption shifts to lower temperature, whereas the aldehyde desorption shifts to higher temperature. This indicates that, on the reduced surface, it is easier to break the C-O bond but more difficult to break the O-substrate bond.

Mullins, David R [ORNL; Senanayake, Sanjaya D [ORNL; Chen, Tsung-Liang [ORNL

2010-01-01T23:59:59.000Z

358

Thermodynamic stabilities of U(VI) minerals: Estimated and observed relationships  

SciTech Connect (OSTI)

Gibbs free energies of formation ({Delta}G{degree}{sub f}) for several structurally related U(VI) minerals are estimated by summing the Gibbs energy contributions from component oxides. The estimated {Delta}G{degree}{sub f} values are used to construct activity-activity (stability) diagrams, and the predicted stability fields are compared with observed mineral occurrences and reaction pathways. With some exceptions, natural occurrences agree well with the mineral stability fields estimated for the systems SiO{sub 2}-CaO-UO{sub 3}-H{sub 2}O and CO{sub 2}-CaO-UO{sub 3}H{sub 2}O, providing confidence in the estimated thermodynamic values. Activity-activity diagrams are sensitive to small differences in {Delta}G{degree}{sub f} values, and mineral compositions must be known accurately, including structurally bound H{sub 2}O. The estimated {Delta}G{degree}{sub f} values are not considered reliable for a few minerals for two major reasons: (1) the structures of the minerals in question are not closely similar to those used to estimate the {Delta}G{sub f}* values of the component oxides, and/or (2) the minerals in question are exceptionally fine grained, leading to large surface energies that increase the effective mineral solubilities. The thermodynamic stabilities of uranium(VI) minerals are of interest for understanding the role of these minerals in controlling uranium concentrations in oxidizing groundwaters associated with uranium ore bodies, uranium mining and mill tailings and geological repositories for nuclear waste.

Finch, R.J. [Univ. of Manitoba, Winnipeg, Manitoba (Canada)

1996-12-31T23:59:59.000Z

359

Characterization of CeO2-Supported Cu-Pd Bimetallic Catalyst for the Oxygen-Assisted Water-Gas Shift Reaction  

SciTech Connect (OSTI)

This study was focused to investigate the roles of Cu and Pd in CuPd/CeO2 bimetallic catalysts containing 20-30 wt% Cu and 0.5-1 wt% Pd used in the oxygen-assisted water-gas shift (OWGS) reaction employing a combined bulk and surface characterization techniques such as XRD, TPR, CO chemisorption, and in-situ XPS. The catalytic activity for CO conversion and the stability of catalyst during on-stream operation increased by the addition of Cu to Pd/CeO2 or Pd to Cu/CeO2 monometallic catalysts, especially when the OWGS reaction was performed under low temperatures, below 200oC. The bimetallic catalyst after leaching with nitric acid retained about 60% of its original activity. The TPR of monometallic Cu/CeO2 showed reduction of CuO supported on CeO2 in two distinct regions, around 150 and 250oC. The high temperature peak disappeared and reduction occurred in a single step around 150oC upon Pd addition. The Pd dispersion decreased from 38.5% for Pd/CeO2 to below 1% for CuPd/CeO2 bimetallic catalyst. In-situ XPS studies showed a shift in Cu 2p peaks toward lower binding energy (BE) with concommitant shift in the Pd 3d peaks toward higher BE. Addition of Pd decreased the surface Cu concentration while the concentration of Pd remained unaltered. All these observations indicated the formation of Cu-Pd surface alloy. The valence band XP spectra collected below 10 eV corroborated the core level XP spectra and indicated that Cu is mainly involved in the catalytic reaction. The improved catalytic activity and stability of CuPd/CeO2 bimetallic catalyst was attributed to the alloy formation.

Fox, Elise; Velu, Subramani; Engelhard, Mark H.; Chin, Ya-Huei; Miller, Jeffrey T.; Kropf, Jeremy; Song, Chunshan

2008-12-10T23:59:59.000Z

360

Structural characterization of the CeO{sub 2}/Gd{sub 2}O{sub 3} mixed system by synchrotron X-ray diffraction  

SciTech Connect (OSTI)

The structural determination of the CeO{sub 2}/Gd{sub 2}O{sub 3} mixed system is a non-trivial problem because of the close resemblance between the ionic sizes of Ce{sup 4+} and Gd{sup 3+} and between the crystal structures of CeO{sub 2} and Gd{sub 2}O{sub 3}. (Ce{sub 1-x}Gd{sub x})O{sub 2-x/2} powder samples with x ranging between 0 and 1 have been synthesized by coprecipitation of mixed oxalates and subsequent thermal decomposition in air at 1200 Degree-Sign C followed by slow cooling. Synchrotron powder X-ray diffraction data were collected and refined by the Rietveld method. Lattice parameters do not follow Vegard's law and no peak splitting has been observed for any composition, meaning that no biphasic regions exist over the whole compositional range. The same hybrid structural model - a proper mixture of the structures of the two pure oxides - was used for the refinements, allowing to account for the data observed. - graphical abstract: Substituting Ce{sup 4+} by Gd{sup 3+}, a gradual transition from the F structure (typical of CeO{sub 2}) to the C structure (typical of Gd{sub 2}O{sub 3}) takes place. The lattice parameters do not follow Vegard's law. Highlights: Black-Right-Pointing-Pointer A structural study of Ce-Gd mixed oxides has been performed. Black-Right-Pointing-Pointer In (Ce{sub 1-x}Gd{sub x})O{sub 2-x/2} a solid solution forms for 0{<=}x{<=}0.3. Black-Right-Pointing-Pointer For x>0.3 a gradual transition from the C to the F structure is observed. Black-Right-Pointing-Pointer Lattice parameters do not follow Vegard's law.

Artini, Cristina, E-mail: c.artini@ge.ieni.cnr.it [Dipartimento di Chimica e Chimica Industriale, Universita degli Studi di Genova, Via Dodecaneso 31, 16146 Genova (Italy); Costa, Giorgio A., E-mail: costa@chimica.unige.it [Dipartimento di Chimica e Chimica Industriale, Universita degli Studi di Genova, Via Dodecaneso 31, 16146 Genova (Italy); CNR-SPIN Genova, Corso Perrone 24, 16152 Genova (Italy); Pani, Marcella, E-mail: marcella@chimica.unige.it [Dipartimento di Chimica e Chimica Industriale, Universita degli Studi di Genova, Via Dodecaneso 31, 16146 Genova (Italy); Lausi, Andrea, E-mail: andrea.lausi@elettra.trieste.it [Sincrotrone Trieste S.C.p.A., ss 14, km 163, 5, 34149 Basovizza, Trieste (Italy); Plaisier, Jasper, E-mail: jasper.plaisier@elettra.trieste.it [Sincrotrone Trieste S.C.p.A., ss 14, km 163, 5, 34149 Basovizza, Trieste (Italy)

2012-06-15T23:59:59.000Z

Note: This page contains sample records for the topic "mineral gadolinite ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Cloud condensation nucleus activity comparison of dry- and wet-generated mineral dust aerosol : the significance of soluble material  

E-Print Network [OSTI]

This study examines the interaction of clay mineral particles and water vapor to determine the conditions required for cloud droplet formation. Droplet formation conditions are investigated for two common clay minerals, ...

Garimella, Sarvesh

2014-01-01T23:59:59.000Z

362

Cloud condensation nucleus activity comparison of dry- and wet-generated mineral dust aerosol: the significance of soluble material  

E-Print Network [OSTI]

This study examines the interaction of clay mineral particles and water vapor for determining the conditions required for cloud droplet formation. Droplet formation conditions are investigated for two common clay minerals, ...

Garimella, Sarvesh

363

Crystalline Electric Field as a Probe for Long-Range Antiferromagnetic Order and Superconducting State of CeFeAsO1-xFx  

SciTech Connect (OSTI)

We use inelastic neutron scattering to study the crystalline electric field (CEF) excitations of Ce{sup 3+} in CeFeAsO{sub 1-x}F{sub x} (x=0, 0.16). For nonsuperconducting CeFeAsO, the Ce CEF levels have three magnetic doublets in the paramagnetic state, but these doublets split into six singlets when the Fe ions order antiferromagnetically. For superconducting CeFeAsO{sub 0.84}F{sub 0.16} (T{sub c} = 41 K), where the static antiferromagnetic order is suppressed, the Ce CEF levels have three magnetic doublets at {h_bar}{sub {omega}} = 0, 18.7, 58.4 meV at all temperatures. Careful measurements of the intrinsic linewidth {Lambda} and the peak position of the 18.7 meV mode reveal a clear anomaly at T{sub c}, consistent with a strong enhancement of local magnetic susceptibility {chi}{double_prime}({h_bar}{sub {omega}}) below T{sub c}. These results suggest that CEF excitations in the rare-earth oxypnictides can be used as a probe of spin dynamics in the nearby FeAs planes.

Chi, Songxue [University of Tennessee, Knoxville (UTK); Adroja, D. T. [ISIS Facility, Rutherford Appleton Laboratory; GUIDI, T. [ISIS Facility, Rutherford Appleton Laboratory; Bewley, Robert I. [ISIS Facility, Rutherford Appleton Laboratory; Li, Shiliang [University of Tennessee, Knoxville (UTK); Zhao, Jun [ORNL; Lynn, J. W. [National Institute of Standards and Technology (NIST); Brown, C. M. [National Institute of Standards and Technology (NIST); Qiu, Y. [National Institute of Standards and Technology (NIST); Chen, G. F, [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics; Luo, J. L. [Chinese Academy of Sciences; Wang, N. L. [Chinese Academy of Sciences; Dai, Pengcheng [ORNL

2008-01-01T23:59:59.000Z

364

Communication : 9th CANMET [Canada Centre for Mineral and Energy Technology] /ACI [American Concrete Institute] (International Conference on Superplasticizers and other Chemical Admixtures in  

E-Print Network [OSTI]

Communication : 9th CANMET [Canada Centre for Mineral and Energy Technology] /ACI [American for Mineral and Energy Technology] /ACI [American Concrete Institute] (International Conference (Canada Centre for Mineral and Energy Technology) /ACI (American Concrete Institute) (International

Boyer, Edmond

365

DEVELOPMENT OF DEWATERING AIDS FOR MINERALS AND COAL FINES  

SciTech Connect (OSTI)

MCT has developed a suite of novel dewatering chemicals (or aids) that are designed to cause a decrease in the capillary pressures of the water trapped in a filter cake by (1) decreasing the surface tension of water, (2) increasing the contact angles of the particles to be dewatered, and (3) causing the particles to coagulate, all at the same time. The decrease in capillary pressure in turn causes an increase in the rate filtration, an increase in throughput, and a decrease in pressure drop requirement for filtration. The reagents are used frequently as blends of different chemicals in order to bring about the changes in all of the process variables noted above. The minerals and coal samples tested in the present work included copper sulfide, lead sulfide, zinc sulfide, kaolin clay, talc, and silica. The laboratory-scale test work included studies of reagent types, drying cycle times, cake thickness, slurry temperature, conditioning intensity and time, solid content, and reagent dosages. To better understand the mechanisms involved, fundamental studies were also conducted. These included the measurements of the contact angles of the particles to be dewatered (which are the measures of particle hydrophobicity) and the surface tensions of the filtrates produced from dewatering tests. The results of the laboratory-scale filtration experiments showed that the use of the novel dewatering aids can reduce the moistures of the filter cake by 30 to 50% over what can be achieved using no dewatering aids. In many cases, such high levels of moisture reductions are sufficient to obviate the needs for thermal drying, which is costly and energy intensive. Furthermore, the use of the novel dewatering aids cause a substantial increase in the kinetics of dewatering, which in turn results in increased throughput. As a result of these technological advantages, the novel dewatering aids have been licensed to Nalco, which is one of the largest mining chemicals companies of the world. At least one mineral company is currently using the technology in full-scale plant operation, which has resulted in the shutdown of a thermal dryer.

Roe-Hoam Yoon; Ramazan Asmatulu; Ismail Yildirim; William Jansen; Jinmig Zhang; Brad Atkinson; Jeff Havens

2004-07-01T23:59:59.000Z

366

Degradation of dome cutting minerals in Hanford waste  

SciTech Connect (OSTI)

At the Hanford Tank Farms, recent changes in retrieval technology require cutting new risers in several single-shell tanks. The Hanford Tank Farm Operator is using water jet technology with abrasive silicate minerals such as garnet or olivine to cut through the concrete and rebar dome. The abrasiveness of these minerals, which become part of the high-level waste stream, may enhance the erosion of waste processing equipment. However, garnet and olivine are not thermodynamically stable in Hanford waste, slowly degrading over time. How likely these materials are to dissolve completely in the waste before the waste is processed in the Waste Treatment and Immobilization Plant can be evaluated using theoretical analysis for olivine and collected direct experimental evidence for garnet. Based on an extensive literature study, a large number of primary silicates decompose into sodalite and cancrinite when exposed to Hanford waste. Given sufficient time, the sodalite also degrades into cancrinite. Even though cancrinite has not been directly added to any Hanford tanks during process times, it is the most common silicate observed in current Hanford waste. By analogy, olivine and garnet are expected to ultimately also decompose into cancrinite. Garnet used in a concrete cutting demonstration was immersed in a simulated supernate representing the estimated composition of the liquid retrieving waste from Hanford tank 241-C-107 at both ambient and elevated temperatures. This simulant was amended with extra NaOH to determine if adding caustic would help enhance the degradation rate of garnet. The results showed that the garnet degradation rate was highest at the highest NaOH concentration and temperature. At the end of 12 weeks, however, the garnet grains were mostly intact, even when immersed in 2 molar NaOH at 80 deg C. Cancrinite was identified as the degradation product on the surface of the garnet grains. In the case of olivine, the rate of degradation in the high-pH regimes of a waste tank is expected to depend on two main parameters: carbonate is expected to slow olivine degradation rates, whereas hydroxide is expected to enhance olivine dissolution rates. Which of these two competing dissolution drivers will have a larger impact on the dissolution rate in the specific environment of a waste tank is currently not identifiable. In general, cancrinite is much smaller and less hard than either olivine or garnet, so would be expected to be less erosive to processing equipment. Complete degradation of either garnet or olivine prior to being processed at the Waste Treatment and Immobilization Plant cannot be confirmed, however.

Reynolds, Jacob G.; Huber, Heinz J.; Cooke, Gary A.

2013-01-11T23:59:59.000Z

367

Degradation of Dome Cutting Minerals in Hanford Waste - 13100  

SciTech Connect (OSTI)

At the Hanford Tank Farms, recent changes in retrieval technology require cutting new risers in several single-shell tanks. The Hanford Tank Farm Operator is using water jet technology with abrasive silicate minerals such as garnet or olivine to cut through the concrete and rebar dome. The abrasiveness of these minerals, which become part of the high-level waste stream, may enhance the erosion of waste processing equipment. However, garnet and olivine are not thermodynamically stable in Hanford waste, slowly degrading over time. How likely these materials are to dissolve completely in the waste before the waste is processed in the Waste Treatment and Immobilization Plant can be evaluated using theoretical analysis for olivine and collected direct experimental evidence for garnet. Based on an extensive literature study, a large number of primary silicates decompose into sodalite and cancrinite when exposed to Hanford waste. Given sufficient time, the sodalite also degrades into cancrinite. Even though cancrinite has not been directly added to any Hanford tanks during process times, it is the most common silicate observed in current Hanford waste. By analogy, olivine and garnet are expected to ultimately also decompose into cancrinite. Garnet used in a concrete cutting demonstration was immersed in a simulated supernate representing the estimated composition of the liquid retrieving waste from Hanford tank 241-C-107 at both ambient and elevated temperatures. This simulant was amended with extra NaOH to determine if adding caustic would help enhance the degradation rate of garnet. The results showed that the garnet degradation rate was highest at the highest NaOH concentration and temperature. At the end of 12 weeks, however, the garnet grains were mostly intact, even when immersed in 2 molar NaOH at 80 deg. C. Cancrinite was identified as the degradation product on the surface of the garnet grains. In the case of olivine, the rate of degradation in the high-pH regimes of a waste tank is expected to depend on two main parameters: carbonate is expected to slow olivine degradation rates, whereas hydroxide is expected to enhance olivine dissolution rates. Which of these two competing dissolution drivers will have a larger impact on the dissolution rate in the specific environment of a waste tank is currently not identifiable. In general, cancrinite is much smaller and less hard than either olivine or garnet, so would be expected to be less erosive to processing equipment. Complete degradation of either garnet or olivine prior to being processed at the Waste Treatment and Immobilization Plant cannot be confirmed, however. (authors)

Reynolds, Jacob G.; Cooke, Gary A.; Huber, Heinz J. [Washington River Protection Solutions, LLC, P.O. Box 850, Richland, WA 99352 (United States)] [Washington River Protection Solutions, LLC, P.O. Box 850, Richland, WA 99352 (United States)

2013-07-01T23:59:59.000Z

368

TITANIUM MINERAL CONCENTRATES1 (Data in thousand metric tons of contained TiO2 unless otherwise noted)  

E-Print Network [OSTI]

and pigment industries. Global production of titanium mineral concentrates was expected to increase during half of 2015. In Western Australia, the heavy-mineral resource, data for at the Keysbrook project were172 TITANIUM MINERAL CONCENTRATES1 (Data in thousand metric tons of contained TiO2 unless otherwise

369

PUBLISHED BY THE AMERICAN ARACHNOLOGICAL SOCIETY A new approach to examining scorpion peg sensilla: the mineral oil flood technique  

E-Print Network [OSTI]

an improved method of chemical stimulus delivery called the mineral oil flood technique, which uses non: the mineral oil flood technique Elizabeth D. Knowlton and Douglas D. Gaffin: Department of Zoology, University peg sensilla: the mineral oil flood technique Elizabeth D. Knowlton and Douglas D. Gaffin: Department

Gaffin, Doug

370

Relations between Au / Sn-W mineralizations and late hercynian granite: Preliminary results from the Schistose Domain of Galicia-  

E-Print Network [OSTI]

Relations between Au / Sn-W mineralizations and late hercynian granite: Preliminary results from, mesothermal mineralization, late hercynian granites, hydrothermalism, Galicia, Spain ABSTRACT : Au and W-Sn mineralization of the Schistose Domain of Galicia-Trás-os-Montes are spatially related to late hercynian granites

Boyer, Edmond

371

O and Pb isotopic analyses of uranium minerals by ion microprobe and UPb ages from the Cigar Lake deposit  

E-Print Network [OSTI]

O and Pb isotopic analyses of uranium minerals by ion microprobe and U­Pb ages from the Cigar Lake intergrown uranium minerals and oxygen isotopic analyes of uraninite from the unconformity-type Cigar Lake uranium deposit. Secondary uranium minerals intergrown with uraninite, such as coffinite, USiO4ÁnH2O

Fayek, Mostafa

372

SESAME 96170, a solid-liquid equation of state for CeO2  

SciTech Connect (OSTI)

I describe an equation of state (EOS) for the low-pressure solid phase and liquid phase of cerium (IV) oxide, CeO{sub 2}. The models and parameters used to calculate the EOS are presented in detail, and I compare with data for the full-density crystal. Hugoniot data are available only for high-porosity powders, and I discuss difficulties in comparing with such data. I have constructed SESAME 96170, an EOS for cerium (IV) oxide that includes the ambient solid and liquid phases. The EOS extends over the full standard SESAME range, but should not be used at low temperatures and high densities because of the lack of a high-pressure solid phase. I have described the models used to compute the three terms of the EOS (cold curve, nuclear, and thermal electronic), and I have given the parameters used in the models. They were determined by comparison with experimental data at P = 1 atm, including the constant-pressure specific heat, coefficient of thermal expansion, and melting and boiling points. The EOS compares well with data in its intended range of validity, but the presence of high-frequency optical modes in its phonon spectrum limits the agreement of our models with thermal data. The next step is to construct a multiphase EOS that includes the low- and high-pressure solid phases and the liquid. The DAC data from Duclos will most strongly constrain the parameters of the high-pressure solid. A remaining issue is the comparison of the crystal-density EOS with experimental Hugoniot data, which are taken at much lower initial data because the samples are porous powders. A satisfactory means of modeling porosity, allowing comparison of theory and experiment, has not yet been produced.

Chisolm, Eric D. [Los Alamos National Laboratory] [Los Alamos National Laboratory

2014-05-02T23:59:59.000Z

373

Interaction of Ce{sub 1?x}Er{sub x}O{sub 2?y} nanoparticles with SiO{sub 2}-effect of temperature and atmosphere  

SciTech Connect (OSTI)

Morphology, microstructure and phase evolution of homogeneous, nanocrystalline Ce{sub 1?x}Er{sub x}O{sub 2?x/2} mixed oxide (x=0.3 and 0.5), prepared by microemulsion method, supported on amorphous SiO{sub 2} was studied in oxidizing and reducing atmosphere by XRD, TEM, SEM-EDS and N{sub 2} adsorption. The system is structurally and chemically stable in the oxidizing atmosphere up to 1000 °C, exhibiting only a small increase of the mean crystallite size of the oxide to ?4 nm. At 1100 °C formation of Er silicate with unusual structure isomorphic with y-Y{sub 2}Si{sub 2}O{sub 7} (yttrialite), stabilized by Ce{sup 4+} ions was observed. In the reducing atmosphere the Ce{sub 1?x}Er{sub x}O{sub 2?x/2} reacted with SiO{sub 2} already at 900 °C, due to high affinity of the reduced Ce{sup 3+} to form a silicate phase. At higher temperature the silicate crystallized into the tetragonal, low temperature A-(Ce{sub 1?x}Er{sub x}){sub 2}Si{sub 2}O{sub 7} polymorph. Such systems, containing nanocrystalline silicate particles with Er{sup 3+} ions placed in well defined sites embedded in silica matrix, may be interesting as highly efficient active components of optical waveguides amplifiers integrated with Si microelectronics. The nanocrystalline Ce–Er–O/SiO{sub 2} system prepared by the impregnation of the silica with the aqueous solution of nitrates appeared to be chemically inhomogeneous and less stable in both oxidising and reducing atmosphere. - Graphical abstract: Structure evolution of Ce{sub 0.5}Er{sub 0.5}O{sub 1.75} in air and in H{sub 2}. Display Omitted - Highlights: • Homogeneous 3 nm Ce{sub 1?x}Er{sub x}O{sub 2?y} particles were prepared and uniformly dispersed on SiO{sub 2}. • Er diffusion to SiO{sub 2} determines the stability of the mixed oxide in air to ?1000 °C. • Spreading of Ce{sub 1?x}Er{sub x}O{sub 2?y} onto SiO{sub 2} occurs in hydrogen at 900 °C. • Nanocrystalline A-(Ce,Er){sub 2}Si{sub 2}O{sub 7} silicate forms in H{sub 2} at 1100 °C.

Kepinski, L., E-mail: L.Kepinski@int.pan.wroc.pl; Krajczyk, L.; Mista, W.

2014-01-15T23:59:59.000Z

374

Electrical properties of dispersions of graphene in mineral oil  

SciTech Connect (OSTI)

Dispersions of graphene in mineral oil have been prepared and electrical conductivity and permittivity have been measured. The direct current (DC) conductivity of the dispersions depends on the surface characteristics of the graphene platelets and followed a percolation model with a percolation threshold ranging from 0.05 to 0.1?wt. %. The difference in DC conductivities can be attributed to different states of aggregation of the graphene platelets and to the inter-particle electron transfer, which is affected by the surface radicals. The frequency-dependent conductivity (?(?)) and permittivity (?(?)) were also measured. The conductivity of dispersions with particle contents much greater than the percolation threshold remains constant and equal to the DC conductivity at low frequencies ? with and followed a power-law ?(?)???{sup s} dependence at very high frequencies with s?0.9. For dispersions with graphene concentration near the percolation threshold, a third regime was displayed at intermediate frequencies indicative of interfacial polarization consistent with Maxwell-Wagner effect typically observed in mixtures of two (or more) phases with very distinct electrical and dielectric properties.

Monteiro, O. R., E-mail: othon.monteiro@bakerhughes.com [Baker Hughes, 14990 Yorktown Plaza Dr., Houston, Texas 77040 (United States)

2014-02-03T23:59:59.000Z

375

Utilization of coal associated minerals. Quarterly report No. 11, April 1-June 30, 1980  

SciTech Connect (OSTI)

The purpose of this research program is to examine the effects of coal mineral materials on coal waste by-product utilization and to investigate new and improved methods for the utilization of waste by-products from cleaning, combustion and conversion processing of coal. The intermediate objectives include: (1) the examination of the effects of cleaning, gasification and combustion on coal mineral materials; and (2) the changes which occur in the coal wastes as a result of both form and distribution of mineral materials in feed coals in conjunction with the coal treatment effects resulting from coal cleaning or either gasification or combustion.

Slonaker, J. F.; Akers, D. J.; Alderman, J. K.

1980-08-29T23:59:59.000Z

376

Micro-Analysis of Actinide Minerals for Nuclear Forensics and Treaty Verification  

SciTech Connect (OSTI)

Micro-Raman spectroscopy has been demonstrated to be a viable tool for nondestructive determination of the crystal phase of relevant minerals. Collecting spectra on particles down to 5 microns in size was completed. Some minerals studied were weak scatterers and were better studied with the other techniques. A decent graphical software package should easily be able to compare collected spectra to a spectral library as well as subtract out matrix vibration peaks. Due to the success and unequivocal determination of the most common mineral false positive (zircon), it is clear that Raman has a future for complementary, rapid determination of unknown particulate samples containing actinides.

M. Morey, M. Manard, R. Russo, G. Havrilla

2012-03-22T23:59:59.000Z

377

Geophysical characterization of mineral and energy resources at Yucca Mountain and vicinity, Nevada  

SciTech Connect (OSTI)

This report was prepared for the Yucca Mountain Project (Department of Energy) as part of the study of the mineral and energy resource potential of the site (Activity 8.3.1.9.2.1.5) under the Human Interference part of the program. Most of the 1991 geophysical scoping activities in the Mineral Resources Study were involved with the acquisition and evaluation of existing data. This report presents an overview of how geophysical data (existing and planned) will aid in the evaluation of the potential for mineral and energy resource potential at Yucca Mountain and vicinity.

Langenheim, V.E.; Oliver, H.W. [Geological Survey, Menlo Park, CA (United States); Hoover, D.B. [Geological Survey, Denver, CO (United States)

1991-12-31T23:59:59.000Z

378

Data:Ce7ce2d1-1aee-4b6e-b53c-61f5d633ed15 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onb5-dcc1fcffd1f2bb71-d4159a938742e80b26cc4 Nodbb-44ce-80f8-79eb97a58f0a No revisionde0244033 No revision has

379

Soil Nitrogen Mineralization Potential for Improved Fertilizer Recommendations and Decreased Nitrate Contamination of Groundwater  

E-Print Network [OSTI]

In order to prevent overfertilization, which could lead to groundwater contamination, rapid and accurate soil testing procedures are needed to evaluate agricultural surface soils for their potential to mineralize C and N. Our objectives were...

Franzluebbers, Alan; Haney, Richard; Hons, Frank

380

Application Of Fluid Inclusion And Rock-Gas Analysis In Mineral...  

Open Energy Info (EERE)

mineral surfaces by heating. The most abundant of these gases, besides H2O, are usually CO2, CH4, CO and N2. We have used a gas chromatograph to analyze these gases in fluid...

Note: This page contains sample records for the topic "mineral gadolinite ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Department of Energy and Mineral Engineering Spring 2013 Solar Innovations -HVAC and Waste Stream Analysis  

E-Print Network [OSTI]

PENNSTATE Department of Energy and Mineral Engineering Spring 2013 Solar Innovations - HVAC and Waste Stream Analysis Overview There are two problems that were voiced by Solar Innovations, HVAC system

Demirel, Melik C.

382

Resource Management Services: Mineral Resources, Parts 550-559 (New York)  

Broader source: Energy.gov [DOE]

This section establishes a Bureau of Mineral Resources within the Department of Environmental Conservation, which has the authority to regulate the exploration and mining for oil and gas resources...

383

E-Print Network 3.0 - actinide-bearing mineral waste Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Medicine 82 I N F O R M A T I O N N O T E Use of Sewage Summary: too. USE OF SEWAGE SLUDGE AND COMPOST ON MINERAL AND BROWNFIELD LAND* Application of organic wastes... or...

384

Leaching of antimony from polyethylene terephthalate (PET) bottles into mineral water  

E-Print Network [OSTI]

Leaching of antimony from polyethylene terephthalate (PET) bottles into mineral water Szilvia April 2009 Available online 21 May 2009 Keywords: Antimony Water Leaching Polyethylene terephthalate SODIS The Sb leaching from polyethylene terephthalate (PET) package material into 10 different brands

Short, Daniel

385

Dept of Mathematics and Statistics King Fahd University of Petroleum and Minerals  

E-Print Network [OSTI]

Seminar Dept of Mathematics and Statistics King Fahd University of Petroleum and Minerals Presenter relation can be used to calculate variance of a few more observations. Some other characteristics

Omar, Mohammad H.

386

Dept of Mathematics and Statistics King Fahd University of Petroleum and Minerals  

E-Print Network [OSTI]

Seminar Dept of Mathematics and Statistics King Fahd University of Petroleum and Minerals Presenter observations are of the same sign. They will be used to find bounds for some well-known sample statistics: z

Omar, Mohammad H.

387

Dept of Mathematics and Statistics King Fahd University of Petroleum and Minerals  

E-Print Network [OSTI]

Seminar Dept of Mathematics and Statistics King Fahd University of Petroleum and Minerals Presenter outcome in sampling without replacement is shown to have a combinatorial form. Then it is used

Omar, Mohammad H.

388

Race/ethnic differences in bone mineral densities in older men  

E-Print Network [OSTI]

the Baltimore men’s osteoporosis study. J Bone Miner Res 13.center genetic study of osteoporosis. Osteoporos Int 17:125–Leung Jockey Club Centre for Osteoporosis Care and Control,

2010-01-01T23:59:59.000Z

389

Mineral Sequestration of Carbon Dixoide in a Sandstone-Shale System  

E-Print Network [OSTI]

Clays and Clay Minerals, 39(4), 355-361. Hower, J. ,Eslinger, E.V. , Hower, M.E. , Perry, E.A. , 1976. Mechanismanalyses such as those by Hower et al. (1976), for the

Xu, Tianfu; Apps, John A.; Pruess, Karsten

2004-01-01T23:59:59.000Z

390

Oil, Gas, and Minerals, Exploration and Production, Lease of Public Land (Iowa)  

Broader source: Energy.gov [DOE]

The state, counties and cities and other political subdivisions may lease publicly owned lands for the purpose of oil or gas or metallic minerals exploration and production.  Any such leases shall...

391

E-Print Network 3.0 - au ag-polymetallic mineralization Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Reno Collection: Geosciences Page: << < 1 2 3 4 5 > >> Page: << < 1 2 3 4 5 > >> 81 geology and Ranger 1 open-pit uranium mine in Australia Summary: ;Uranium minerals: The...

392

E-Print Network 3.0 - accessory mineral growth Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

0003-004X001112157305.00 1573 Summary: diopside (Di), potassium feldspar (Kfs), titanite (Ttn), and a variety of accessory minerals as well... contained Bad and a variety of...

393

E-Print Network 3.0 - accessory minerals zirconolite Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2004 0003-004X041112175205.00 1752 Summary: , Manitoba R3T 2N2, Canada ABSTRACT Titanite is a common accessory mineral in silicocarbonatite from the... acidic pH, and...

394

Vascular flora and vegetation of granite outcrops in the Central Mineral Region of Texas  

E-Print Network [OSTI]

of Texas Location of the Central Mineral Region, indicating areas underlain by Precambrian granitic tock 13 Location of 20 granite outcrops in the Central Mineral Region of Texas 20 Climate diagrams for Mason, Llano, Burnet, and Gillespie Counties...& Texas 23 Climate diagrams for Mason, Llano, Burnet, and Gillespie Counties, Texas 25 Distribution of 2 granite outcrop endemics in the area of study and in the state of Texas 60 Distribution of Pilularia americana 63 Distribution of 2 granite...

Walters, Terrence Wesley

1980-01-01T23:59:59.000Z

395

High gradient magnetic separation of iron oxide minerals from soil clays  

E-Print Network [OSTI]

HIGH GRADIENT MAGNETIC SEPARATION OF IRON OXIDE MINERALS FROM SOIL CLAYS A Thesis by DARRELL GENE SCHULZE Submitted to the Graduate College of Texas AIM University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE... December 1977 Major Subject: Soil Science HIGH GRADIENT MAGNETIC SEPARATION OF IRON OXIDE MINERALS FROM SOIL CLAYS A Thesis DARRELL GENE SCHULZE Approved as to style and content by: (Chairman of C ittee) epartm t) j (Member) (Membe December 1977...

Schulze, Darrell Gene

1977-01-01T23:59:59.000Z

396

Enhancement of Growth Performance and Bone Mineralization in Market Broilers through Dietary Enzymes  

E-Print Network [OSTI]

. In Experiment 1, a 35-day grow out trial was conducted to investigate the effect of three commercially available phytase enzymes on growth performance and bone mineralization in phosphorus deficient corn/soy based diets. Increasing the level of available... phosphorus (aP) in the control diets resulted in improved bird performance and bone ash data. The presence of dietary phytase in phosphorus deficient diets resulted in improvements in growth parameters and bone mineralization. Regression analysis...

Coppedge, Jacob Ryan

2012-02-14T23:59:59.000Z

397

Magnesium and pyridoxine intake and mineral content of selected tissues and physical development in rats  

E-Print Network [OSTI]

MAGNESIUM AND PYRIDOXINE INTAKE MINERAL CONTENT OF SELECTED TISSUES PHYSICAL DEVELOPMENT IN RATS A Thesis by SU S AN ELA I NE EDGAR Submitted to the Graduate College of Texas A8rM University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE August 1986 Major Subject: Nutrition MAGNESIUM AND PYRIDOXINE INTAKE MINERAL CONTENT OF SELECTED TISSUES PHYS ICAL DEVELOPMENT IN RATS A Thesis by SUSAN ELAINE EDGAR Approved as to style and content by: 'KAREN...

Edgar, Susan Elaine

2012-06-07T23:59:59.000Z

398

FLUIDIZED BED STEAM REFORMED MINERAL WASTE FORMS: CHARACTERIZATION AND DURABILITY TESTING  

SciTech Connect (OSTI)

Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of high sodium low activity wastes (LAW) such as those existing at the Hanford site, at the Idaho National Laboratory (INL), and the Savannah River Site (SRS). The addition of clay, charcoal, and a catalyst as co-reactants with the waste denitrates the aqueous wastes and forms a granular mineral waste form that can subsequently be made into a monolith for disposal if necessary. The waste form produced is a multiphase mineral assemblage of Na-Al-Si (NAS) feldspathoid minerals with cage and ring structures and iron bearing spinel minerals. The mineralization occurs at moderate temperatures between 650-750 C in the presence of superheated steam. The cage and ring structured feldspathoid minerals atomically bond radionuclides like Tc-99 and Cs-137 and anions such as SO{sub 4}, I, F, and Cl. The spinel minerals stabilize Resource Conservation and Recovery Act (RCRA) hazardous species such as Cr and Ni. Granular mineral waste forms were made from (1) a basic Hanford Envelope A low activity waste (LAW) simulant and (2) an acidic INL simulant commonly referred to as sodium bearing waste (SBW) in pilot scale facilities at the Science Applications International Corporation (SAIC) Science and Technology Applications Research (STAR) facility in Idaho Falls, ID. The FBSR waste forms were characterized and the durability tested via ASTM C1285 (Product Consistency Test), the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP), and the Single Pass Flow Through (SPFT) test. The results of the SPFT testing and the activation energies for dissolution are discussed in this study.

Jantzen, C; Troy Lorier, T; John Pareizs, J; James Marra, J

2006-12-06T23:59:59.000Z

399

FLUIDIZED BED STEAM REFORMED MINERAL WASTE FORMS: CHARACTERIZATION AND DURABILITY TESTING  

SciTech Connect (OSTI)

Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of high sodium low activity wastes (LAW) such as those existing at the Hanford site, at the Idaho National Laboratory (INL), and the Savannah River Site (SRS). The addition of clay, charcoal, and a catalyst as co-reactants with the waste denitrates the aqueous wastes and forms a granular mineral waste form that can subsequently be made into a monolith for disposal if necessary. The waste form produced is a multiphase mineral assemblage of Na-Al-Si (NAS) feldspathoid minerals with cage and ring structures and iron bearing spinel minerals. The mineralization occurs at moderate temperatures between 650-750 C in the presence of superheated steam. The cage and ring structured feldspathoid minerals atomically bond radionuclides like Tc-99 and Cs-137 and anions such as SO4, I, F, and Cl. The spinel minerals stabilize Resource Conservation and Recovery Act (RCRA) hazardous species such as Cr and Ni. Granular mineral waste forms were made from (1) a basic Hanford Envelope A low-activity waste (LAW) simulant and (2) an acidic INL simulant commonly referred to as sodium bearing waste (SBW) in pilot scale facilities at the Science Applications International Corporation (SAIC) Science and Technology Applications Research (STAR) facility in Idaho Falls, ID. The FBSR waste forms were characterized and the durability tested via ASTM C1285 (Product Consistency Test), the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP), and the Single Pass Flow Through (SPFT) test. The results of the SPFT testing and the activation energies for dissolution are discussed in this study.

Jantzen, C; Troy Lorier, T; John Pareizs, J; James Marra, J

2007-03-31T23:59:59.000Z

400

Clay minerals of recent marine sediments to the west of the Mississippi Delta  

E-Print Network [OSTI]

CLAY MINERALS OF RECENT MARINE SEDIMENTS 10 THE WEST OP THE MISSISSIPPI DKLTA A Dissertation By RAYMOND ERANCIS McALLI9TER> Jr. Submitted to the Graduate School of the Agricultural and Mechanical College of Texas in partial fulfillment... of the requirements for the degree of DOCTOR OF PHILOSOPHY IN OCEANOGRAPHY May* 1958 Major Subject: Geological Oceanography CLAY MINERALS OF RECENT MARINE SEDIMENTS TO THE WEST OF THE MISSISSIPPI DELTA A Dissertation RAYMOND FRANCIS McALLISTER, Jr. Approved...

McAllister, Raymond Francis

1958-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mineral gadolinite ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

ATOMIC-LEVEL IMAGING OF CO2 DISPOSAL AS A CARBONATE MINERAL: OPTIMIZING REACTION PROCESS DESIGN  

SciTech Connect (OSTI)

Fossil fuels, especially coal, can support the energy demands of the world for centuries to come, if the environmental problems associated with CO{sub 2} emissions can be overcome. Permanent and safe methods for CO{sub 2} capture and disposal/storage need to be developed. Mineralization of stationary-source CO{sub 2} emissions as carbonates can provide such safe capture and long-term sequestration. Mg-rich lamellar-hydroxide based minerals (e.g., brucite and serpentine) offer a class of widely available, low-cost materials, with intriguing mineral carbonation potential. Carbonation of such materials inherently involves dehydroxylation, which can disrupt the material down to the atomic level. As such, controlled dehydroxylation, before and/or during carbonation, may provide an important parameter for enhancing carbonation reaction processes. Mg(OH){sub 2} was chosen as the model material for investigating lamellar hydroxide mineral dehydroxylation/carbonation mechanisms due to (1) its structural and chemical simplicity, (2) interest in Mg(OH){sub 2} gas-solid carbonation as a potentially cost-effective CO{sub 2} mineral sequestration process component, and (3) its structural and chemical similarity to other lamellar-hydroxide-based minerals (e.g., serpentine-based minerals) whose carbonation reaction processes are being explored due to their low-cost CO{sub 2} sequestration potential. Fundamental understanding of the mechanisms that govern dehydroxylation/carbonation processes is essential for minimizing the cost of any lamellar-hydroxide-based mineral carbonation sequestration process. This final report covers the overall progress of this grant.

M.J. McKelvy; R. Sharma; A.V.G. Chizmeshya; H. Bearat; R.W. Carpenter

2002-11-01T23:59:59.000Z

402

ATOMIC-LEVEL IMAGING OF CO2 DISPOSAL AS A CARBONATE MINERAL: OPTIMIZING REACTION PROCESS DESIGN  

SciTech Connect (OSTI)

Fossil fuels, especially coal, can support the energy demands of the world for centuries to come, if the environmental problems associated with CO{sub 2} emissions can be overcome. Permanent and safe methods for CO{sub 2} capture and disposal/storage need to be developed. Mineralization of stationary-source CO{sub 2} emissions as carbonates can provide such safe capture and long-term sequestration. Mg-rich lamellar-hydroxide based minerals (e.g., brucite and serpentine) offer a class of widely available, low-cost materials, with intriguing mineral carbonation potential. Carbonation of such materials inherently involves dehydroxylation, which can disrupt the material down to the atomic level. As such, controlled dehydroxylation, before and/or during carbonation, may provide an important parameter for enhancing carbonation reaction processes. Mg(OH){sub 2} was chosen as the model material for investigating lamellar hydroxide mineral dehydroxylation/carbonation mechanisms due to (i) its structural and chemical simplicity, (ii) interest in Mg(OH){sub 2} gas-solid carbonation as a potentially cost-effective CO{sub 2} mineral sequestration process component, and (iii) its structural and chemical similarity to other lamellar-hydroxide-based minerals (e.g., serpentine-based minerals) whose carbonation reaction processes are being explored due to their low-cost CO{sub 2} sequestration potential. Fundamental understanding of the mechanisms that govern dehydroxylation/carbonation processes is essential for minimizing the cost of any lamellar-hydroxide-based mineral carbonation sequestration process. This report covers the third year progress of this grant, as well as providing an integrated overview of the progress in years 1-3, as we have been granted a one-year no-cost extension to wrap up a few studies and publications to optimize project impact.

M.J. McKelvy; R. Sharma; A.V.G. Chizmeshya; H. Bearat; R.W. Carpenter

2001-10-01T23:59:59.000Z

403

Absorption and retention of different chemical forms of trace minerals by mature horses  

E-Print Network [OSTI]

Micro-minerals are gaining greater importance in ration balancing so as to enhance the growth and development of a wide range of tissue types in horses (Jackson, 1998; Ott and Johnson, 2001). Several different chemical formulations of trace mineral... in the oxidative phosphorylation process in mitochondria (Jackson, 1998). Zinc appears in numerous physiologic roles in the body. In concert with copper, zinc has been tied to bone formation and epithelial integrity, including hoof growth (Ott and Johnson, 2001...

Wagner, Elizabeth Lynn

2003-01-01T23:59:59.000Z

404

Application of the Modified Methylene Blue Test to Detect Clay Minerals in Coarse Aggregate Fines  

E-Print Network [OSTI]

APPLICATION OF THE MODIFIED METHYLENE BLUE TEST TO DETECT CLAY MINERALS IN COARSE AGGREGATE FINES A Thesis by BRANDON THOMAS PITRE Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment...: Civil Engineering Copyright 2012 Brandon Thomas Pitre ii ABSTRACT The purpose of this study was to implement a new, rapid field method to effectively and accurately detect harmful clay minerals in aggregate fines by using the modified...

Pitre, Brandon

2012-12-04T23:59:59.000Z

405

Transport properties of partially-filled Ce{sub y}Co{sub 4}Sb{sub 12}  

SciTech Connect (OSTI)

The authors have investigated the magnetic and transport properties of Ce{sub y}Co{sub 4}Sb{sub 12} filled skutterudites with the filling fraction y {le} 0.1. These compounds are n-type materials that develop a magnetic moment upon the presence of trivalent cerium. Cerium has a strong influence on all transport properties and even in small amounts it drastically reduces the lattice thermal conductivity. The resulting figures of merit are comparable to the values established previously for the p-type filled skutterudites.

Uher, C.; Chen, B.; Hu, S.; Morelli, D.T.; Meisner, G.P.

1997-07-01T23:59:59.000Z

406

Data:69ce9c3e-1066-4306-b704-dccfa06245b9 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office695810186 No revision has been approvedea02758d3 Nob05268d8cd No revisionf1fe86ce5f9ae-1b5eba546306 No

407

Data:5289eb16-08ae-4779-aef7-e948945f84ce | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of48d9ff47edf3a87dcc95b Nobfef8fa58cf74865627f783 Noaad3-ec22188355fa No341c9c4152dd958 No6d1644d544e948945f84ce

408

Data:9d9aa544-afad-4985-ba5a-1093160c0ce4 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office695810186 Nod2db5b31cb44 No revision has beenfcf13f143bb No revision has been44632c851160c0ce4 No revision has

409

Data:Ce257723-a06c-4647-a520-102fafcf2c22 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onb5-dcc1fcffd1f2bb71-d4159a938742e80b26cc4 Nodbb-44ce-80f8-79eb97a58f0a No revision has been approved

410

Data:Ce453e06-3085-4555-bb8f-0a6eefe99579 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onb5-dcc1fcffd1f2bb71-d4159a938742e80b26cc4 Nodbb-44ce-80f8-79eb97a58f0a No revision hasf-0a6eefe99579 No revision has

411

Data:Ce7bcd1a-3552-4059-96b7-c45de0244033 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onb5-dcc1fcffd1f2bb71-d4159a938742e80b26cc4 Nodbb-44ce-80f8-79eb97a58f0a No revisionde0244033 No revision has been

412

Data:Ce81fdcf-0181-4f95-8509-ee44606aaf57 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onb5-dcc1fcffd1f2bb71-d4159a938742e80b26cc4 Nodbb-44ce-80f8-79eb97a58f0a No revisionde0244033 No revision

413

Data:Ce930280-ac1e-449d-8c43-c4daf70201be | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onb5-dcc1fcffd1f2bb71-d4159a938742e80b26cc4 Nodbb-44ce-80f8-79eb97a58f0a No revisionde0244033 Nodaf70201be No revision has

414

Synchrotron based mass spectrometry to investigate the molecular properties of mineral-organic associations  

SciTech Connect (OSTI)

Soil organic matter (OM) is important because its decay drives life processes in the biosphere. Analysis of organic compounds in geological systems is difficult because of their intimate association with mineral surfaces. To date there is no procedure capable of quantitatively separating organic from mineral phases without creating artifacts or mass loss. Therefore, analytical techniques that can (a) generate information about both organic and mineral phases simultaneously and (b) allow the examination of predetermined high-interest regions of the sample as opposed to conventional bulk analytical techniques are valuable. Laser Desorption Synchrotron Postionization (synchrotron-LDPI) mass spectrometry is introduced as a novel analytical tool to characterize the molecular properties of organic compounds in mineral-organic samples from terrestrial systems, and it is demonstrated that when combined with Secondary Ion Mass Spectrometry (SIMS), can provide complementary information on mineral composition. Mass spectrometry along a decomposition gradient in density fractions, verifies the consistency of our results with bulk analytical techniques. We further demonstrate that by changing laser and photoionization energies, variations in molecular stability of organic compounds associated with mineral surfaces can be determined. The combination of synchrotron-LDPI and SIMS shows that the energetic conditions involved in desorption and ionization of organic matter may be a greater determinant of mass spectral signatures than the inherent molecular structure of the organic compounds investigated. The latter has implications for molecular models of natural organic matter that are based on mass spectrometric information.

Liu, Suet Yi; Kleber, Markus; Takahashi, Lynelle K.; Nico, Peter; Keiluweit, Marco; Ahmed, Musahid

2013-04-01T23:59:59.000Z

415

Mineral Sequestration of Carbon Dixoide in a Sandstone-Shale System  

SciTech Connect (OSTI)

A conceptual model of CO2 injection in bedded sandstone-shale sequences has been developed using hydrogeologic properties and mineral compositions commonly encountered in Gulf Coast sediments. Numerical simulations were performed with the reactive fluid flow and geochemical transport code TOUGHREACT to analyze mass transfer between sandstone and shale layers and CO2 immobilization through carbonate precipitation. Results indicate that most CO2 sequestration occurs in the sandstone. The major CO2 trapping minerals are dawsonite and ankerite. The CO2 mineral-trapping capacity after 100,000 years reaches about 90 kg per cubic meter of the medium. The CO2 trapping capacity depends on primary mineral composition. Precipitation of siderite and ankerite requires Fe+2 supplied mainly by chlorite and some by hematite dissolution and reduction. Precipitation of dawsonite requires Na+ provided by oligoclase dissolution. The initial abundance of chlorite and oligoclase therefore affects the CO2 mineral trapping capacity. The sequestration time required depends on the kinetic rate of mineral dissolution and precipitation. Dawsonite reaction kinetics is not well understood, and sensitivity regarding the precipitation rate was examined. The addition of CO2 as secondary carbonates results in decreased porosity. The leaching of chemical constituents from the interior of the shale causes slightly increased porosity. The limited information currently available for the mineralogy of natural high-pressure CO2 gas reservoirs is also generally consistent with our simulation. The ''numerical experiments'' give a detailed understanding of the dynamic evolution of a sandstone-shale geochemical system.

Xu, Tianfu; Apps, John A.; Pruess, Karsten

2004-07-09T23:59:59.000Z

416

Lab 1 Mineral Utility Lab notes The physical world is made up of a vast number of different minerals. Later on in  

E-Print Network [OSTI]

Lake City, Utah which removes 225,000 metric tons of rock a day, 20% of which is ore. Quarries: Sand quarries. Rocks like granite and marble are used as decorative rocks on the outside of buildings, or even of removing a mineral from its ore. Quarried rocks may simply need crushing, grinding, and sizing before use

Li, X. Rong

417

Nanopattering in CeOx/Cu(111): A New Type of Surface Reconstruction and Enhancement of Catalytic Activity  

SciTech Connect (OSTI)

Our results indicate that small amounts of an oxide deposited on a stable metal surface can trigger a massive surface reconstruction under reaction conditions. In low-energy electron microscopy (LEEM) experiments, no reconstruction of Cu(111) is observed after chemisorbing oxygen or after reducing O/Cu(111) in a CO atmosphere. On the other hand, LEEM images taken in situ during the reduction of CeO{sub 2}/CuO{sub 1-x}/Cu(111) show a complex nonuniform transformation of the surface morphology. Ceria particles act as nucleation sites for the growth of copper microterraces once CuO{sub 1-x} is reduced. Can this reconstructed surface be used to enhance the catalytic activity of inverse oxide/metal catalysts? Indeed, CeO{sub x} on reconstructed Cu(111) is an extremely active catalyst for the water-gas shift process (CO + H{sub 2}O {yields} H{sub 2} + CO{sub 2}), with the Cu microterraces providing very efficient sites for the dissociation of water and subsequent reaction with CO.

Rodriguez J. A.; Senanayake, S.D.; Sadowski, J.; Evans, J.; Kundu, S.; Agnoli, S.; Yang, F.; Stacchiola, D.; Flege, J.I.; Hrbek, J.

2012-04-05T23:59:59.000Z

418

CE IGCC repowering project: Clean Coal II Project. Annual report, 1 January, 1992--31 December, 1992  

SciTech Connect (OSTI)

CE is participating in a $270 million coal gasification combined cycle repowering project that will provide a nominal 60 MW of electricity to City, Water, light and Power (CWL and P) in Springfield, Illinois. The IGCC system will consist of CE`s air-blown entrained flow two-stage gasifier; an advanced hot gas cleanup system; a combustion turbine adapted to use low-Btu gas: and all necessary coal handling equipment. The project is currently in the second budget period of five. The major activities during this budgeted period are: Establishment of an approved for design (AFD) engineering package; development of a detailed cost estimate; resolution of project business issues; CWL and P renewal and replacement activities; and application for environmental air permits. The Project Management Plan was updated. The conceptual design of the plant was completed and a cost and schedule baseline for the project was established previously in Budget Period One. This information was used to establish AFD Process Flow Diagrams, Piping and Instrument Diagrams, Equipment Data Sheets, material take offs, site modification plans and other information necessary to develop a plus or minus 20% cost estimate. Environmental permitting activities are continuing. At the end of 1992 the major activities remaining for Budget Period two is to finish the cost estimate and complete the Continuation Request Documents.

Not Available

1993-12-01T23:59:59.000Z

419

Rapid Microwave Preparation of Highly Efficient Ce[superscript 3+]-Substituted Garnet Phosphors for Solid State White Lighting  

SciTech Connect (OSTI)

Ce{sup 3+}-substituted aluminum garnet compounds of yttrium (Y{sub 3}Al{sub 5}O{sub 12}) and lutetium (Lu{sub 3}Al{sub 5}O{sub 12}) - both important compounds in the generation of (In,Ga)N-based solid state white lighting - have been prepared using a simple microwave heating technique involving the use of a microwave susceptor to provide the initial heat source. Carbon used as the susceptor additionally creates a reducing atmosphere around the sample that helps stabilize the desired luminescent compound. High quality, phase-pure materials are prepared within a fraction of the time and using a fraction of the energy required in a conventional ceramic preparation; the microwave technique allows for a reduction of about 95% in preparation time, making it possible to obtain phase pure, Ce{sup 3+}-substituted garnet compounds in under 20 min of reaction time. It is estimated that the overall reduction in energy compared with ceramic routes as practiced in the lab is close to 99%. Conventionally prepared material is compared with material prepared using microwave heating in terms of structure, morphology, and optical properties, including quantum yield and thermal quenching of luminescence. Finally, the microwave-prepared compounds have been incorporated into light-emitting diode 'caps' to test their performance characteristics in a real device, in terms of their photon efficiency and color coordinates.

Birkel, Alexander; Denault, Kristin A.; George, Nathan C.; Doll, Courtney E.; Héry, Bathylle; Mikhailovsky, Alexander A.; Birkel, Christina S.; Hong, Byung-Chul; Seshadri, Ram (UCSB); (Mitsubishi)

2012-04-30T23:59:59.000Z

420

Preparation and luminescence characterization of GGAG:Ce{sup 3+},B{sup 3+} for a white light-emitting diode  

SciTech Connect (OSTI)

We prepared Gd{sub 3}Ga{sub 2}Al{sub 3}O{sub 12} (GGAG) co-doped with trivalent cerium and boron ions and investigated its luminescence properties as a function of the B{sup 3+} concentration. The luminescence intensity was enhanced markedly by adding B{sup 3+} as a co-dopant. The non-boron-doped GGAG:Ce{sup 3+} converted less than 10% of the absorbed blue light into luminescence. As the B{sup 3+} concentration increased, Q increased and reached a maximum of Q = 21% at 1.5 moles in GGAG:Ce{sup 3+}. White light closer to daylight with good color-rendering index properties was generated with the proper combination of yellow emission from GGAG:Ce{sup 3+},B{sup 3+} and blue emission from a GaN chip.

Kang, Jun-Gill [Department of Chemistry, Chungnam National University, Daejeon 305-764 (Korea, Republic of)], E-mail: jgkang@cnu.ac.kr; Kim, Myung-Kyo [Alti-Electronics Co., Ltd., 90-1 Bongmyung-Ri, Namsa-Myun, Youngin, Gyeonggi-Do 449-882 (Korea, Republic of); Kim, Kwang-Bok [Kumho Electric, Inc., 64-1, Bongmyung-Ri, Namsa-Myun, Youngin, Gyeonggi-Do 449-883 (Korea, Republic of)

2008-08-04T23:59:59.000Z

Note: This page contains sample records for the topic "mineral gadolinite ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

ENHANCING THE ATOMIC-LEVEL UNDERSTANDING OF CO2 MINERAL SEQUESTRATION MECHANISMS VIA ADVANCED COMPUTATIONAL MODELING  

SciTech Connect (OSTI)

Fossil fuels currently provide 85% of the world's energy needs, with the majority coming from coal, due to its low cost, wide availability, and high energy content. The extensive use of coal-fired power assumes that the resulting CO2 emissions can be vented to the atmosphere. However, exponentially increasing atmospheric CO2 levels have brought this assumption under critical review. Over the last decade, this discussion has evolved from whether exponentially increasing anthropogenic CO2 emissions will adversely affect the global environment, to the timing and magnitude of their impact. A variety of sequestration technologies are being explored to mitigate CO2 emissions. These technologies must be both environmentally benign and economically viable. Mineral carbonation is an attractive candidate technology as it disposes of CO2 as geologically stable, environmentally benign mineral carbonates, clearly satisfying the first criteria. The primary challenge for mineral carbonation is cost-competitive process development. CO2 mineral sequestration--the conversion of stationary-source CO2 emissions into mineral carbonates (e.g., magnesium and calcium carbonate, MgCO3 and CaCO3)--has recently emerged as one of the most promising sequestration options, providing permanent CO2 disposal, rather than storage. In this approach a magnesium-bearing feedstock mineral (typically serpentine or olivine; available in vast quantities globally) is specially processed and allowed to react with CO2 under controlled conditions. This produces a mineral carbonate which (1) is environmentally benign, (2) already exists in nature in quantities far exceeding those that could result from carbonating the world's known fossil fuel reserves, and (3) is stable on a geological time scale. Minimizing the process cost via optimization of the reaction rate and degree of completion is the remaining challenge. As members of the DOE/NETL managed National Mineral Sequestration Working Group we have already significantly improved our understanding of mineral carbonation. Group members at the Albany Research Center have recently shown that carbonation of olivine and serpentine, which naturally occurs over geological time (i.e., 100,000s of years), can be accelerated to near completion in hours. Further process refinement will require a synergetic science/engineering approach that emphasizes simultaneous investigation of both thermodynamic processes and the detailed microscopic, atomic-level mechanisms that govern carbonation kinetics. Our previously funded Phase I Innovative Concepts project demonstrated the value of advanced quantum-mechanical modeling as a complementary tool in bridging important gaps in our understanding of the atomic/molecular structure and reaction mechanisms that govern CO2 mineral sequestration reaction processes for the model Mg-rich lamellar hydroxide feedstock material Mg(OH)2. In the present simulation project, improved techniques and more efficient computational schemes have allowed us to expand and augment these capabilities and explore more complex Mg-rich, lamellar hydroxide-based feedstock materials, including the serpentine-based minerals. These feedstock materials are being actively investigated due to their wide availability, and low-cost CO2 mineral sequestration potential. Cutting-edge first principles quantum chemical, computational solid-state and materials simulation methodology studies proposed herein, have been strategically integrated with our new DOE supported (ASU-Argonne National Laboratory) project to investigate the mechanisms that govern mineral feedstock heat-treatment and aqueous/fluid-phase serpentine mineral carbonation in situ. This unified, synergetic theoretical and experimental approach has provided a deeper understanding of the key reaction mechanisms than either individual approach can alone. We used ab initio techniques to significantly advance our understanding of atomic-level processes at the solid/solution interface by elucidating the origin of vibrational, electronic, x-ray and electron energy loss sp

A.V.G. Chizmeshya; M.J. McKelvy; G.H. Wolf; R.W. Carpenter; D.A. Gormley; J.R. Diefenbacher; R. Marzke

2006-03-01T23:59:59.000Z

422

Single x-ray transmission system for bone mineral density determination  

SciTech Connect (OSTI)

Bones are the support of the body. They are composed of many inorganic compounds and other organic materials that all together can be used to determine the mineral density of the bones. The bone mineral density is a measure index that is widely used as an indicator of the health of the bone. A typical manner to evaluate the quality of the bone is a densitometry study; a dual x-ray absorptiometry system based study that has been widely used to assess the mineral density of some animals' bones. However, despite the success stories of utilizing these systems in many different applications, it is a very expensive method that requires frequent calibration processes to work properly. Moreover, its usage in small species applications (e.g., rodents) has not been quite demonstrated yet. Following this argument, it is suggested that there is a need for an instrument that would perform such a task in a more reliable and economical manner. Therefore, in this paper we explore the possibility to develop a new, affordable, and reliable single x-ray absorptiometry system. The method consists of utilizing a single x-ray source, an x-ray image sensor, and a computer platform that all together, as a whole, will allow us to calculate the mineral density of the bone. Utilizing an x-ray transmission theory modified through a version of the Lambert-Beer law equation, a law that expresses the relationship among the energy absorbed, the thickness, and the absorption coefficient of the sample at the x-rays wavelength to calculate the mineral density of the bone can be advantageous. Having determined the parameter equation that defines the ratio of the pixels in radiographies and the bone mineral density [measured in mass per unit of area (g/cm{sup 2})], we demonstrated the utility of our novel methodology by calculating the mineral density of Wistar rats' femur bones.

Jimenez-Mendoza, Daniel; Vargas-Vazquez, Damian [Division de Investigacion y Posgrado, Facultad de Ingenieria, Universidad Autonoma de Queretaro, Cerro de las Campanas s/n., C.P. 76010, Queretaro, Qro. (Mexico); Espinosa-Arbelaez, Diego G. [Posgrado en Ciencia e Ingenieria en Materiales, Instituto de Investigaciones en Materiales, Universidad Nacional Autonoma de Mexico, Av. Universidad 3000, C.P. 04510, Coyoacan, Mexico D.F. (Mexico); Departamento de Nanotecnologia, Centro de Fisica Aplicada y Tecnologia Avanzada, Universidad Nacional Autonoma de Mexico, Campus Juriquilla, Boulevard Juriquilla 3001, C.P. 76230, A.P. 1-1010, Juriquilla, Qro. (Mexico); Giraldo-Betancur, Astrid L. [Centro de Investigacion y de Estudios Avanzados del Instituto Politecnico Nacional, Libramiento Norponiente 2000, C.P. 76230, Fracc. Real de Juriquilla, Qro. (Mexico); Hernandez-Urbiola, Margarita I. [Posgrado en Investigaciones Biomedicas, Universidad Nacional Autonoma de Mexico, Campus Juriquilla, Boulevard Juriquilla 3001, C.P. 76230, A.P. 1-1010, Juriquilla, Qro. (Mexico); Departamento de Nanotecnologia, Centro de Fisica Aplicada y Tecnologia Avanzada, Universidad Nacional Autonoma de Mexico, Campus Juriquilla, Boulevard Juriquilla 3001, C.P. 76230, A.P. 1-1010, Juriquilla, Qro. (Mexico); Rodriguez-Garcia, Mario E. [Departamento de Nanotecnologia, Centro de Fisica Aplicada y Tecnologia Avanzada, Universidad Nacional Autonoma de Mexico, Campus Juriquilla, Boulevard Juriquilla 3001, C.P. 76230, A.P. 1-1010, Juriquilla, Qro. (Mexico)

2011-12-15T23:59:59.000Z

423

Oxide-ion conductivity in Cu {sub x}Ce{sub 1-x}O{sub 2-{delta}} (0 {<=} x {<=} 0.10)  

SciTech Connect (OSTI)

Up to 10 at.% of copper readily substitutes for cerium in ceria. It is found that at oxygen partial pressures between 0.21 atm and 10{sup -5} atm, Cu {sub x}Ce{sub 1-x}O{sub 2-{delta}} (0 {<=} x {<=} 0.10) solid solution behave as an oxide-ion electrolyte. Interestingly, Cu{sub 0.10}Ce{sub 0.90}O{sub 2-{delta}} exhibits the oxide-ion conductivity of ca. 10{sup -4} {omega}{sup -1} cm{sup -1} at 600 deg. C at an oxygen partial pressure of 10{sup -5} atm.

Gayen, Arup [Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore 560012 (India); Priolkar, K.R. [Department of Physics, Goa University, Taleigao Plateau, Goa 403206 (India); Shukla, A.K. [Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore 560012 (India); Ravishankar, N. [Materials Research Centre, Indian Institute of Science, Bangalore 560012 (India); Hegde, M.S. [Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore 560012 (India)]. E-mail: mshegde@sscu.iisc.ernet.in

2005-03-08T23:59:59.000Z

424

Lu.sub.1-xI.sub.3:Ce.sub.x-a scintillator for gamma-ray spectroscopy and time-of-flight pet  

DOE Patents [OSTI]

The present invention includes very fast scintillator materials including lutetium iodide doped with Cerium (Lu.sub.1-xI.sub.3:Ce.sub.x; LuI.sub.3:Ce). The LuI.sub.3 scintillator material has surprisingly good characteristics including high light output, high gamma-ray stopping efficiency, fast response, low cost, good proportionality, and minimal afterglow that the material is useful for gamma-ray spectroscopy, medical imaging, nuclear and high energy physics research, diffraction, non-destructive testing, nuclear treaty verification and safeguards, and geological exploration.

Shah, Kanai S. (Newton, MA)

2008-02-12T23:59:59.000Z

425

In Vitro Enzymatic Reduction Kinetics of Mineral Oxides by Membrane Fractions from Shewanella oneidensis MR-1  

SciTech Connect (OSTI)

This study documents the first example of in vitro solid-phase mineral oxide reduction by enzyme-containing membrane fractions. Previous in vitro studies have only reported the reduction of aqueous ions. Total membrane (TM) fractions from iron-grown cultures of Shewanella oneidensis MR-1 were isolated and shown to catalyze the reduction of goethite, hematite, birnessite, and ramsdellite/pyrolusite using formate. In contrast, nicotinamide adenine dinucleotide (NADH) and succinate cannot function as electron donors. The significant implications of observations related to this cell-free system are: (i) both iron and manganese mineral oxides are reduced by the TM fraction, but aqueous U(VI) is not; (ii) TM fractions from anaerobically grown, but not aerobically grown, cells can reduce the mineral oxides; (iii) electron shuttles and iron chelators are not needed for this in vitro reduction, documenting conclusively that reduction can occur by direct contact with the mineral oxide; (iv) electron shuttles and EDTA stimulate the in vitro Fe(III) reduction, documenting that exogenous molecules can enhance rates of enzymatic mineral reduction; and (v) multiple membrane components are involved in solid-phase oxide reduction. The membrane fractions, consisting of liposomes of cytoplasmic and outer membrane segments, contain at least 100 proteins including the enzyme that oxidizes formate, formate dehydrogenase. Mineral oxide reduction was inhibited by the addition of detergent Triton X-100, which solubilizes membranes and their associated proteins, consistent with the involvement of multiple electron carriers that are disrupted by detergent addition. In contrast, formate dehydrogenase activity was not inhibited by Triton X-100. The addition of anthraquinone-2,6-disulfonate (AQDS) and menaquinone-4 was unable to restore activity; however, menadione (MD) restored 33% of the activity. The addition of AQDS and MD to reactions without added detergent increased the rate of goethite reduction. The Michaelis-Menten K{sub m} values of 71 {+-} 22 m{sup 2}/L for hematite and 50 {+-} 16 m{sup 2}/L for goethite were calculated as a function of surface area of the two insoluble minerals. V{sub max} was determined to be 123 {+-} 14 and 156 {+-} 13 nmol Fe(II)/min/mg of TM protein for hematite and goethite, respectively. These values are consistent with in vivo rates of reduction reported in the literature. These observations are consistent with our conclusion that the enzymatic reduction of mineral oxides is an effective probe that will allow elucidation of molecular chemistry of the membrane-mineral interface where electron transfer occurs.

Ruebush,S.; Icopini, G.; Brantley, S.; Tien, M.

2006-01-01T23:59:59.000Z

426

Mineral transformation and biomass accumulation associated with uranium bioremediation at Rifle, Colorado  

SciTech Connect (OSTI)

Injection of organic carbon into the subsurface as an electron donor for bioremediation of redox-sensitive contaminants like uranium often leads to mineral transformation and biomass accumulation, both of which can alter the flow field and potentially bioremediation efficacy. This work combines reactive transport modeling with a column experiment and field measurements to understand the biogeochemical processes and to quantify the biomass and mineral transformation/accumulation during a bioremediation experiment at a uranium contaminated site near Rifle, Colorado. We use the reactive transport model CrunchFlow to explicitly simulate microbial community dynamics of iron and sulfate reducers, and their impacts on reaction rates. The column experiment shows clear evidence of mineral precipitation, primarily in the form of calcite and iron monosulfide. At the field scale, reactive transport simulations suggest that the biogeochemical reactions occur mostly close to the injection wells where acetate concentrations are highest, with mineral precipitate and biomass accumulation reaching as high as 1.5% of the pore space. This work shows that reactive transport modeling coupled with field data can be an effective tool for quantitative estimation of mineral transformation and biomass accumulation, thus improving the design of bioremediation strategies.

Li, L.; Steefel, C.I.; Williams, K.H.; Wilkins, M.J.; Hubbard, S.S.

2009-04-20T23:59:59.000Z

427

Mineral Dissolution and Secondary Precipitation on Quartz Sand in Simulated Hanford Tank Solutions Affecting Subsurface Porosity  

SciTech Connect (OSTI)

Highly alkaline nuclear waste solutions have been released from underground nuclear waste storage tanks and pipelines into the vadose zone at the U.S. Department of Energy’s Hanford Site in Washington, causing mineral dissolution and re-precipitation upon contact with subsurface sediments. High pH caustic NaNO3 solutions with and without dissolved Al were reacted with quartz sand through flow-through columns stepwise at 45, 51, and 89°C to simulate possible reactions between leaked nuclear waste solution and primary subsurface mineral. Upon reaction, Si was released from the dissolution of quartz sand, and nitrate-cancrinite [Na8Si6Al6O24(NO3)2] precipitated on the quartz surface as a secondary mineral phase. Both steady-state dissolution and precipitation kinetics were quantified, and quartz dissolution apparent activation energy was determined. Mineral alteration through dissolution and precipitation processes results in pore volume and structure changes in the subsurface porous media. In this study, the column porosity increased up to 40.3% in the pure dissolution column when no dissolved Al was present in the leachate, whereas up to a 26.5% porosity decrease was found in columns where both dissolution and precipitation were observed because of the presence of Al in the input solution. The porosity change was also confirmed by calculation using the dissolution and precipitation rates and mineral volume changes.

Wang, Guohui; Um, Wooyong

2012-11-23T23:59:59.000Z

428

DXRD (Dynamic X-Ray Diffraction) studies of oil shale mineral reactions  

SciTech Connect (OSTI)

With the advent of second generation, above-ground oil shale processes, retorted shale is likely to be combusted at temperatures between 1000{degree}K and 1200{degree}K. At these temperatures the mineral matrix of the shale will undergo a variety of chemical reactions including carbonate decomposition, sulfation and recombination reactions to form silicates. This complex set of reactions can be very important to the optimum design of a retorted shale combustor. For example the net heat of combustion is very dependent on these reactions since the carbonate mineral decomposition reactions are highly endothermic and some of the silication reactions only mildly endothermic. In addition, the combusted shale (ash) will have to be disposed and revegetated and the environmental consequences of this process will be highly dependent on the mineral composition of the ash. The degree to which the mineral reactions influence these considerations will depend on the time-temperature history to which the shale is exposed. Thus it is important to have a knowledge of the kinetics of these reactions. Previous attempts to study these kinetics have been made at Lawrence Livermore Laboratories and in our own laboratory. However, these studies all employed TGA techniques and, since there is usually more than one reaction occurring simultaneously, there is no way to distinguish between competing reactions. What is described here is the application of a new technique - Dynamic X-Ray Diffraction (DXRD), which has been successfully applied to studies of oil shale mineral reactions under typical retorted shale combustion conditions.

Helling, K.A.; Thomson, W.J.

1987-04-01T23:59:59.000Z

429

Lung cancer in uranium miners: A tissue resource and pilot study. Final performance report  

SciTech Connect (OSTI)

This project incorporates two related research projects directed toward understanding respiratory carcinogenesis in radon-exposed former uranium miners. The first project involved a continuation of the tissue resource of lung cancer cases from former underground uranium miners and comparison cases from non-miners. The second project was a pilot study for a proposed longitudinal study of respiratory carcinogenesis in former uranium miners. The objectives including facilitating the investigation of molecular changes in radon exposed lung cancer cases, developing methods for prospectively studying clinical, cytologic, cytogenetic, and molecular changes in the multi-event process of respiratory carcinogenesis, and assessing the feasibility of recruiting former uranium miners into a longitudinal study that collected multiple biological specimens. A pilot study was conducted to determine whether blood collection, induced sputum, bronchial brushing, washings, and mucosal biopsies from participants at two of the hospitals could be included efficiently. A questionnaire was developed for the extended study and all protocols for specimen collection and tissue handling were completed. Resource utilization is in progress at ITRI and the methods have been developed to study molecular and cellular changes in exfoliated cells contained in sputum as well as susceptibility factors.

Samet, J.; Gilliland, F.D.

1998-08-13T23:59:59.000Z

430

Effect of the bioemulsifier emulsan on naphthalene mineralization from coal tar in aqueous systems  

SciTech Connect (OSTI)

Coal tar in aerobic aqueous systems was treated with purified emulsan, the anionic heteropolysaccharide bioemulsifier produced by Acinetobacter calcoaceticus RAG-1; with inocula of various concentrations of stationary phase RAG-1 cells; or with cell-free broth from stationary phase RAG-1 cultures. Naphthalene mineralization by a mixed PAH-degrading population was measured by recovering {sup 14}CO{sub 2} evolved during biotransformation of the [{sup 14}C]naphthalene-labeled coal tar. There was no evidence of naphthalene mineralization by RAG- 1 cells alone. The addition of emulsan, RAG-1 inocula, or cell-free broth to systems containing the PAH-degrading population did not significantly affect naphthalene mineralization in any of the systems tested. Coal tar in these experiments was present either as a free dense nonaqueous phase liquid (DNAPL), or as DNAPL imbibed into microporous silica particles. Emulsification of the tar was not observed in either case. The presence or absence of microporous silica did not affect the extent or rate of naphthalene mineralization, nor did the concentration of RAG-1 inocula or the amount of broth added. The addition of cell-free broth, emulsan, or RAG-1 cells late in the experiments did not yield significantly different results compared to initial addition of these substances. Thus, emulsan and related fractions from RAG-1 cultures were ineffective in altering naphthalene mineralization in this study.

Skubal, K.L.; Luthy, R.G.

1994-09-01T23:59:59.000Z

431

Quantitative mineralogical composition of complex mineral wastes - Contribution of the Rietveld method  

SciTech Connect (OSTI)

The objective of the work presented in this paper is the quantitative determination of the mineral composition of two complex mineral wastes: a sewage sludge ash (SSA) and a municipal solid waste incineration fly ash (MSWIFA). The mineral compositions were determined by two different methods: the first based on calculation using the qualitative mineralogical composition of the waste combined with physicochemical analyses; the second the Rietveld method, which uses only X-ray diffraction patterns. The results obtained are coherent, showing that it is possible to quantify the mineral compositions of complex mineral waste with such methods. The apparent simplicity of the Rietveld method (due principally to the availability of software packages implementing the method) facilitates its use. However, care should be taken since the crystal structure analysis based on powder diffraction data needs experience and a thorough understanding of crystallography. So the use of another, complementary, method such as the first one used in this study, may sometimes be needed to confirm the results.

Mahieux, P.-Y. [Universite de Toulouse, UPS, INSA, LMDC (Laboratoire Materiaux et Durabilite des Constructions), 135, Avenue de Rangueil, F-31 077 Toulouse Cedex 4 (France); Aubert, J.-E., E-mail: aubert@insa-toulouse.f [Universite de Toulouse, UPS, INSA, LMDC (Laboratoire Materiaux et Durabilite des Constructions), 135, Avenue de Rangueil, F-31 077 Toulouse Cedex 4 (France); Cyr, M.; Coutand, M.; Husson, B. [Universite de Toulouse, UPS, INSA, LMDC (Laboratoire Materiaux et Durabilite des Constructions), 135, Avenue de Rangueil, F-31 077 Toulouse Cedex 4 (France)

2010-03-15T23:59:59.000Z

432

Process for removal of mineral particulates from coal-derived liquids  

DOE Patents [OSTI]

Suspended mineral solids are separated from a coal-derived liquid containing the solids by a process comprising the steps of: (a) contacting said coal-derived liquid containing solids with a molten additive having a melting point of 100.degree.-500.degree. C. in an amount of up to 50 wt. % with respect to said coal-derived liquid containing solids, said solids present in an amount effective to increase the particle size of said mineral solids and comprising material or mixtures of material selected from the group of alkali metal hydroxides and inorganic salts having antimony, tin, lithium, sodium, potassium, magnesium, calcium, beryllium, aluminum, zinc, molybdenum, cobalt, nickel, ruthenium, rhodium or iron cations and chloride, iodide, bromide, sulfate, phosphate, borate, carbonate, sulfite, or silicate anions; and (b) maintaining said coal-derived liquid in contact with said molten additive for sufficient time to permit said mineral matter to agglomerate, thereby increasing the mean particle size of said mineral solids; and (c) recovering a coal-derived liquid product having reduced mineral solids content. The process can be carried out with less than 5 wt. % additive and in the absence of hydrogen pressure.

McDowell, William J. (Knoxville, TN)

1980-01-01T23:59:59.000Z

433

Computing in SCienCe & engineering This arTicle has been peer-reviewed. 13 R e p r o d u c i b l e R e s e a r c h  

E-Print Network [OSTI]

Computing in SCienCe & engineering This arTicle has been peer-reviewed. 13 R e p r o d u c i b l e as well as some efforts and approaches to overcome them. #12;14 Computing in SCienCe & engineering in 2011; a panel discussion at the International Biometric Society meeting in 2011 featured re- producibility

LeVeque, Randy

434

Hydrogen activation, diffusion, and clustering on CeO{sub 2}(111): A DFT+U study  

SciTech Connect (OSTI)

We present a comprehensive density functional theory+U study of the mechanisms underlying the dissociation of molecular hydrogen, and diffusion and clustering of the resulting atomic species on the CeO{sub 2}(111) surface. Contrary to a widely held view based solely on a previous theoretical prediction, our results show conclusively that H{sub 2} dissociation is an activated process with a large energy barrier ?1.0 eV that is not significantly affected by coverage or the presence of surface oxygen vacancies. The reaction proceeds through a local energy minimum – where the molecule is located close to one of the surface oxygen atoms and the H–H bond has been substantially weaken by the interaction with the substrate –, and a transition state where one H atom is attached to a surface O atom and the other H atom sits on-top of a Ce{sup 4+} ion. In addition, we have explored how several factors, including H coverage, the location of Ce{sup 3+} ions as well as the U value, may affect the chemisorption energy and the relative stability of isolated OH groups versus pair and trimer structures. The trimer stability at low H coverages and the larger upward relaxation of the surface O atoms within the OH groups are consistent with the assignment of the frequent experimental observation by non-contact atomic force and scanning tunneling microscopies of bright protrusions on three neighboring surface O atoms to a triple OH group. The diffusion path of isolated H atoms on the surface goes through the adsorption on-top of an oxygen in the third atomic layer with a large energy barrier of ?1.8 eV. Overall, the large energy barriers for both, molecular dissociation and atomic diffusion, are consistent with the high activity and selectivity found recently in the partial hydrogenation of acetylene catalyzed by ceria at high H{sub 2}/C{sub 2}H{sub 2} ratios.

Fernández-Torre, Delia [Departamento de Física Teórica de la Materia Condensada, Universidad Autónoma de Madrid, E-28049 Madrid (Spain); Instituto de Estructura de la Materia, CSIC, C/ Serrano 121, E-28006 Madrid (Spain); Carrasco, Javier [CIC Energigune, Albert Einstein 48, 01510 Miñano, Álava (Spain); Instituto de Catálisis y Petroleoquímica, CSIC, C/ Marie Curie 2, E-28049 Madrid (Spain); Ganduglia-Pirovano, M. Verónica [Instituto de Catálisis y Petroleoquímica, CSIC, C/ Marie Curie 2, E-28049 Madrid (Spain); Pérez, Rubén, E-mail: ruben.perez@uam.es [Departamento de Física Teórica de la Materia Condensada, Universidad Autónoma de Madrid, E-28049 Madrid (Spain); Condensed Matter Physics Center (IFIMAC), Universidad Autónoma de Madrid, E-28049 Madrid (Spain)

2014-07-07T23:59:59.000Z

435

Development and evaluation of a thermodynamic dataset for phases of interest in CO2 mineral sequestration in basaltic rocks  

E-Print Network [OSTI]

evaluation of a thermodynamic dataset for phases of interestKeywords: Thermodynamic dataset CO2–water– basaltABSTRACT A thermodynamic dataset describing 36 mineral

Aradottir, E.S.P.

2013-01-01T23:59:59.000Z

436

CLAY MINERALS OF THE FRONT RANGE: A FIELD GUIDE TO THE GEOLOGY, HISTORY, AND CLAY MINERALOGY OF THE CHIEFTAIN MINE,  

E-Print Network [OSTI]

.................................................... 71 Appendix I: Clay Minerals Society field trip mileage log ............... 76 #12;FIGURES 1. Line ......................................... 21 7. Robinson Brick Company history ................................... 22 8. Diffractogram showing

437

Interaction between humans and the physical world is com-plex. Topics such as water management, mineral depletion,  

E-Print Network [OSTI]

with a bachelor's degree are found in government agencies, the energy industry, private consulting, construction, mineral depletion, air pollution, soil contamination, invasive species, defor- estation and loss

Saldin, Dilano

438

Automated simulation of areal bone mineral density assessment in the distal radius from high-resolution peripheral quantitative computed tomography  

E-Print Network [OSTI]

Bone mineral density . DXA . HR-pQCT . Osteoporosis .Simulation Introduction Osteoporosis is a conditionclinical assessment of osteoporosis status were identified

Burghardt, A. J.; Kazakia, G. J.; Link, T. M.; Majumdar, S.

2009-01-01T23:59:59.000Z

439

Electronic and thermoelectric properties of Ce{sub 3}Te{sub 4} and La{sub 3}Te{sub 4} computed with density functional theory with on-site Coulomb interaction correction  

SciTech Connect (OSTI)

The electronic properties and Seebeck coefficients of Ce{sub 3}Te{sub 4} and La{sub 3}Te{sub 4} are computed using Density Functional Theory with on-site Coulomb interaction correction. We found that the Seebeck coefficients of Ce{sub 3}Te{sub 4} and La{sub 3}Te{sub 4} are almost equal at temperatures larger than the Curie temperature of Ce{sub 3}Te{sub 4}, and in good agreement with the measurements reported by May et al. [Phys. Rev. B 86, 035135 (2012)]. At temperatures below the Curie temperature, the Seebeck coefficient of Ce{sub 3}Te{sub 4} increases due to the ferromagnetic ordering, which leads the f-electron of Ce to contribute to the Seebeck coefficient in the relevant range of electron concentration.

Vo, Trinh; Allmen, Paul von; Huang, Chen-Kuo; Ma, James; Bux, Sabah; Fleurial, Jean-Pierre [Jet Propulsion Laboratory, California Institute of Technology, Pasadena, California 91109 (United States)

2014-10-07T23:59:59.000Z

440

Injury experience in nonmetallic mineral mining (except stone and coal), 1989  

SciTech Connect (OSTI)

This Mine Safety and Health Administration (MSHA) informational report reviews in detail the occupational injury and illness experience of nonmetallic mineral mining (except stone and coal) in the United States for 1989. Data reported by operators of mining establishments concerning work injuries are summarized by work location, accident classification, part of body injured, nature of injury, occupation, and principal type of mineral. Related information on employment, worktime, and operating activity also is presented. Data reported by independent contractors performing certain work at mining locations are depicted separately in this report. For ease of comparison with other metal and nonmetallic mineral mining industries and with coal mining, summary reference tabulations are included at the end of both the operator and the contractor sections of this report. 3 figs., 46 tabs.

Not Available

1990-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mineral gadolinite ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Association of trace elements with mineral species in the New Albany oil shale  

SciTech Connect (OSTI)

X-Ray diffraction (XRD), electron microprobe (EMP), scanning electron microscopy (SEM) and neutron activation analysis (NAA) were used to identify mineral species in the New Albany shale and kerogen isolates. Elemental abundances were determined by NAA and distributions of Ni, V, As, and other elements with-in mineral grains were determined by EMP-XRF. Vanadium in the New Albany shale was found to be associated primarily with clay minerals (illite, montmorrillonite). In the New Albany kerogen, Ni and V were shown to be predominantly associated with the organic matrix. Pyrite (and/or marcasite) was shown to occur in two forms, a euhedral variety and as framboidal clusters. The Ni content of the framboidal variety was found to be higher than that of the euhedral pyrite.

Fitzgerald, S.L.; Day, J.W.; Mercer, G.E.; Filby, R.H. (Washington State Univ., Pullman (USA))

1989-03-01T23:59:59.000Z

442

Study of catalytic effects of mineral matter level on coal reactivity  

SciTech Connect (OSTI)

Coal liquefaction experiments using a 400-lb/day bubble-column reactor tested the catalytic effects of added mineral matter level on coal conversion, desulfurization, and distillate yields in continuous operation under recycle conditions, with specific emphasis on the use of a disposable pyrite catalyst indigenous to the feed coal. Western Kentucky No. 11 run-of-mine (ROM) and washed coals were used as feedstocks to determine the effects of levels of mineral matter, specifically iron compounds. Liquefaction reactivity as characterized by total distillate yield was lower for washed coal, which contained less mineral matter. Liquefaction reactivity was regained when pyrite concentrate was added as a disposable catalyst to the washed coal feed in sufficient quantity to match the feed iron concentration of the run-of-mine coal liquefaction test run.

Mazzocco, Nestor J.; Klunder, Edgar B.; Krastman, Donald

1981-03-01T23:59:59.000Z

443

Lung cancer epidemiology in New Mexico uranium miners. Progress report, March 1, 1991--November 30, 1991  

SciTech Connect (OSTI)

This investigation assesses the health effects of radon progeny exposure in New Mexico uranium miners. Cumulative exposures sustained by most New Mexico miners are well below those received earlier in the Colorado Plateau. This project utilizes the research opportunity offered by New Mexico miners to address unresolved issues related to radon progeny exposure: (1) the lung cancer risk of lower levels of exposure, (2) interaction between radon progeny exposure and cigarette smoking in the causation of lung cancer, (3) the relationship between lung cancer histologic type and radon progeny exposure, and (4) possible effects of radon progeny exposure other than lung cancer. A cohort study of 3800 men with at least one year of underground uranium mining experience in New Mexico is in progress. Results are discussed.

Samet, J.M.

1991-11-01T23:59:59.000Z

444

Adsorbate effects on a mixed-valence compound: Carbon monoxide chemisorption on CeIr/sub 2/  

SciTech Connect (OSTI)

We have studied the effects of stoichiometry change and CO chemisorption on the surface electronic structure of the mixed-valence compound CeIr/sub 2/. We show that the surface iridium to cerium ratio can be varied by changing sample temperature while sputtering. Carbon monoxide is found to adsorb 80% molecularly on the surface and cause a mild surface oxidation which induces a shift of electron density into available cerium f orbitals. Peaks due to the 4sigma, 1..pi.., and 5sigma CO molecular orbitals appear at different binding energies than those due to molecular CO on the pure iridium surface. This binding-energy shift as well as the high percentage of molecular CO on the surface (CO adsorption on pure cerium is completely dissociative) points toward a surface which has lost much of the elemental character of its two constituents upon compound formation.

Lindquist, J.M.; Hemminger, J.C.; Lawrence, J.

1987-10-15T23:59:59.000Z

445

Adsorbate effects on a mixed-valence compound: carbon monoxide chemisorption on CeIr/sub 2/  

SciTech Connect (OSTI)

The authors studied the effects of stoichiometry change and CO chemisorption on the surface electronic structure of the mixed-valence compound CeIr/sub 2/. It is shown that the surface iridium to cerium ratio can be varied by changing sample temperature while sputtering. Carbon monoxide is found to adsorb 80% molecularly on the surface and cause a mild surface oxidation which induces a shift of electron density into available cerium f orbitals. Peaks due to the 4 sigma, 1 pi, and 5 sigma CO molecular orbitals appear at different binding energies than those due to molecular CO on the pure iridium surface. This binding-energy shift as well as the high percentage of molecular CO on the surface (CO adsorption on pure cerium is completely dissociative) points toward a surface which has lost much of the elemental character of its two constituents upon compound formation.

Lindquist, J.M.; Hemminger, J.C.

1987-10-15T23:59:59.000Z

446

Effect of CeO{sub 2} buffer layer on the microstructure and magnetic properties of yttrium iron garnet film on Si substrate  

SciTech Connect (OSTI)

Yttrium iron garnet films were grown by radio frequency magnetron sputtering on Si(111) substrate with and without CeO{sub 2} buffer layer, and influence of CeO{sub 2} buffer on the microstructure and magnetic behaviors of the films were investigated. As compared with the film without buffer, a larger saturation magnetizaton (M{sub s}), lower coercive force (H{sub c}), and higher remnant magnetization (M{sub r}) were obtained due to the introduction of CeO{sub 2} layer. The higher M{sub s} results from the denser structure and the smaller content of Fe{sup 2+} ions. The lower H{sub c} and higher M{sub r} can be explained by the small surface roughness and crystal grains size. The film on CeO{sub 2} buffer layer possess fine microstructure and its surface roughness is smaller than the unbuffered films, which provides an increased exchange between the crystal grains and an enhanced spontaneous magnetization effect, leading to the higher remnant magnetization.

Yang Qinghui; Zhang Huaiwu; Wen Qiye; Liu Yingli [State Key Laboratory of Electronic Films and Integrated Devices, University of Electronic Science and Technology of China, Chengdu, 610054 (China); Xiao, John Q. [Department of Physics and Astronomy, University of Delaware, Newark, Delaware, 19716 (United States)

2009-04-01T23:59:59.000Z

447

UV absorption properties of ceria-modified compositions within the fluorite-type solid solution CeO{sub 2}-Y{sub 6}WO{sub 12}  

SciTech Connect (OSTI)

A new fluorite-type solid solution domain has been evidenced in the system (1-x) CeO{sub 2}-x/7 Y{sub 6}WO{sub 12}{open_square}{sub 2} using the amorphous citrate route. All the studied phases (0{<=}x{<=}1) crystallize in a cubic-type symmetry. Diffuse reflectance spectra reveal a strong optical absorption between 380 and 400 nm. All substituted compositions spectral selectivities are estimated suitable for application as inorganic UV absorbers. The non linear variation observed in the optical gap values between Y{sub 6}WO{sub 12} and CeO{sub 2} is attributed to the presence of the cerium 4f-block band. Additionally, Time Resolved Microwave Conductivity (TRMC) experiment and phenol photodegradation analyses carried out on the Ce{sub 0.81}Y{sub 0.16}W{sub 0.03}O{sub 1.95}{open_square}{sub 0.05} (x=0.19) composition do not indicate any photocalatytic activity for this material. - Graphical abstract: Diffuse reflectance spectra of the Ce-Y-W-O samples calcined at 1000 deg. C.

Chevire, Francois [UMR CNRS 6226 'Sciences Chimiques de Rennes', equipe 'Verres et Ceramiques', Universite de Rennes 1, 35042 Rennes cedex (France); Munoz, Francisco [UMR CNRS 6226 'Sciences Chimiques de Rennes', equipe 'Verres et Ceramiques', Universite de Rennes 1, 35042 Rennes cedex (France); Baker, Charles F. [UMR CNRS 6226 'Sciences Chimiques de Rennes', equipe 'Verres et Ceramiques', Universite de Rennes 1, 35042 Rennes cedex (France); Tessier, Franck [UMR CNRS 6226 'Sciences Chimiques de Rennes', equipe 'Verres et Ceramiques', Universite de Rennes 1, 35042 Rennes cedex (France)]. E-mail: Franck.Tessier@univ-rennes1.fr; Larcher, Olivier [UMR CNRS 6226 'Sciences Chimiques de Rennes', equipe 'Verres et Ceramiques', Universite de Rennes 1, 35042 Rennes cedex (France); Boujday, Souhir [Laboratoire d'Ingenierie des Materiaux et des Hautes Pressions, CNRS UPR 1311, Universite Paris 13, 99 Avenue J. B. Clement, 93430 Villetaneuse (France); Colbeau-Justin, Christophe [Laboratoire d'Ingenierie des Materiaux et des Hautes Pressions, CNRS UPR 1311, Universite Paris 13, 99 Avenue J. B. Clement, 93430 Villetaneuse (France); Marchand, Roger [UMR CNRS 6226 'Sciences Chimiques de Rennes', equipe 'Verres et Ceramiques', Universite de Rennes 1, 35042 Rennes cedex (France)

2006-10-15T23:59:59.000Z

448

TP HTML -CSS -PHP -POSTGRESQL Le but de ce TP est de complter les fichiers fournis pour raliser une micro application interactive qui  

E-Print Network [OSTI]

TP HTML - CSS - PHP - POSTGRESQL Le but de ce TP est de compléter les fichiers fournis pour afficher (fichiers .html ou .php). · Enregistrez dans votre home l'archive contenant les fichiers du TP à partir de http://perso.limsi.fr/annlor/enseignement/ensiie/pw/tpPHP.tar · Extrayez de l'archive le

Ligozat, Anne-Laure

449

The Institute for Integrated Cell-Material Sciences (iCeMS) was founded in 2007 as part of a government program called the World Premier International  

E-Print Network [OSTI]

, Sports, Science and Technology (MEXT) of Japan. The fund provides a total of 6 million dollars per year science. iCeMS is one of nine WPI centers throughout Japan and boasts eighteen world-renowned principal investigators, who are leading experts in cell biology, chemistry, and physics. Notably, Kyoto University Center

Takada, Shoji

450

Electronic Structure of CeFeAsO1-xFx (x=0, 0.11/x=0.12) compounds  

SciTech Connect (OSTI)

We report an extensive study on the intrinsic bulk electronic structure of the high-temperature superconductor CeFeAsO{sub 0.89}F{sub 0.11} and its parent compound CeFeAsO by soft and hard x-ray photoemission, x-ray absorption and soft-x-ray emission spectroscopies. The complementary surface/bulk probing depth, and the elemental and chemical sensitivity of these techniques allows resolving the intrinsic electronic structure of each element and correlating it with the local structure, which has been probed by extended-x-ray absorption fine structure spectroscopy. The measurements indicate a predominant 4f{sup 1} (i.e. Ce{sup 3+}) initial state configuration for Cerium and an effective valence-band-to-4f charge-transfer screening of the core hole. The spectra also reveal the presence of a small Ce f{sup 0} initial state configuration, which we assign to the occurrence of an intermediate valence state. The data reveal a reasonably good agreement with the partial density of states as obtained in standard density functional calculations over a large energy range. Implications for the electronic structure of these materials are discussed.

Bondino, F.; Magnano, E.; Booth, C. H.; Offi, F.; Panaccione, G.; Malvestuto, M.; Paolicelli, G.; Simonelli, L.; Parmigiani, F.; McGuire, M. A.; Sefat, A. S.; Sales, B. C.; Jin, R.; Vilmercati, P.; Mandrus, D.; Singh, D. J.; Mannella, N.

2011-01-25T23:59:59.000Z

451

Un atlas smantique pour le cerveau Un des buts principaux de ce projet est le dveloppement d'un outil qui permettra  

E-Print Network [OSTI]

Un atlas sémantique pour le cerveau Un des buts principaux de ce projet est le développement d construire des représentations sémantiques à partir de large corpus de textes (les Atlas sémantiques (AS

Institut des Sciences Cognitives, CNRS

452

VI INTERNATIONAL TELECOMMUNICATIONS SYMPOSIUM (ITS2006), SEPTEMBER 3-6, 2006, FORTALEZA-CE, BRAZIL 1 Fringe Benefits of the H.264/AVC  

E-Print Network [OSTI]

of the Motion Picture Experts Groups (MPEG) from the International Standards Organization (ISO) and of the VideoVI INTERNATIONAL TELECOMMUNICATIONS SYMPOSIUM (ITS2006), SEPTEMBER 3-6, 2006, FORTALEZA-CE, BRAZIL, and Tiago A. Fonseca Abstract-- H.264/AVC is the newest, state-of-the-art, video compression standard

de Queiroz, Ricardo L.

453

Effect of CeO{sub 2} addition on the properties of FeAl based alloy produced by mechanical alloying technique  

SciTech Connect (OSTI)

Iron aluminides based on FeAl is notable for their low materials cost, ease of fabrication and good corrosion, suffixation and oxidation resistance. However, the application based on these unique properties still require the development of Fe-Al based alloy since it shows some drawbacks such as a lack of high temperature strength and low ductility. To improve the mechanical properties of FeAl based alloy, ceria (CeO{sub 2}) will be added to this compound. FeAl based alloy produced by the mechanical alloying (MA) technique. The developed specimens then assessed with respect to oxidation behaviour in high temperature, scale microstructure and hardness. The surface morphologies of the alloy evaluated and observed using scanning electron microscopy (SEM) with an energy dispersive X-ray spectroscopy (EDX). The phase structures of oxide scale formed on them were identified by X-ray diffraction (XRD). The results found that the FeAl intermetallic compound containing CeO{sub 2} 0.5 wt.% is less pores and CeO{sub 2} 1.0 wt.% is more homogen in powder and solid form, higher hardness and increase in their resistance to oxidation behaviour in high temperature compared with another percentage of CeO{sub 2}.

Khaerudini, Deni S.; Muljadi,; Sardjono, P.; Tetuko, Anggito P.; Sebayang, P.; Ginting, M. [Research Center for Physics, Indonesian Institute of Sciences (LIPI) Gd. 440, Kawasan Puspiptek Serpong Tangerang 15314 Banten (Indonesia)] [Research Center for Physics, Indonesian Institute of Sciences (LIPI) Gd. 440, Kawasan Puspiptek Serpong Tangerang 15314 Banten (Indonesia)

2013-09-03T23:59:59.000Z

454

IFT1227, Architecture des ordinateurs 1: Ce devoir vous permet de manipuler les robots equipes de la -chip PIC18F4550 presentes en demo.  

E-Print Network [OSTI]

IFT1227, Architecture des ordinateurs 1: Devoir 3 Ce devoir vous permet de manipuler les robots robot soit attir´e ou suive une lumi`ere relativement forte (une lampe de poche ou autre mise devant lui). 1 Comportement basique Votre programme devra fournir le comportement suivant : ­ Quand le robot

Boyer, Michel

455

plan de polarisation de 18', en sens contraire du courant qui anime l'lecuro-aimant. On peut comparer ce rsultat avec l'effet produit  

E-Print Network [OSTI]

celle que produit directement l'acier, ce qui donne pour l'effet de la lame 50' au lieu de 48', nombre un champ magnétique et du phénomène de Peltier. L'expérience de M. Hall est répétée au moyen d

Paris-Sud XI, Université de

456

CE IGCC Repowering Project: Use of the Lockheed Kinetic Extruder for coal feeding; Topical report, June 1993  

SciTech Connect (OSTI)

ABB CE is evaluating alternate methods of coal feed across a pressure barrier for its pressurized coal gasification process. The Lockheed Kinetic Extruder has shown to be one of the most promising such developments. In essence, the Kinetic Extruder consists of a rotor in a pressure vessel. Coal enters the rotor and is forced outward to the surrounding pressure vessel by centrifugal force. The force on the coal passing across the rotor serves as a pressure barrier. Should this technology be successfully developed and tested, it could reduce the cost of IGCC technology by replacing the large lockhoppers conventionally used with a much smaller system. This will significantly decrease the size of the gasifier island. Kinetic Extruder technology needs testing over an extended period of time to develop and prove the long term reliability and performance needed in a commercial application. Major issues to be investigated in this program are component design for high temperatures, turn-down, scale-up factors, and cost. Such a test would only be economically feasible if it could be conducted on an existing plant. This would defray the cost of power and feedstock. Such an installation was planned for the CE IGCC Repowering Project in Springfield, Illinois. Due to budgetary constraints, however, this provision was dropped from the present plant design. It is believed that, with minor design changes, a small scale test version of the Kinetic Extruder could be installed parallel to an existing lockhopper system without prior space allocation. Kinetic Extruder technology represents significant potential cost savings to the IGCC process. For this reason, a test program similar to that specified for the Springfield project would be a worthwhile endeavor.

NONE

1994-02-01T23:59:59.000Z

457

Studies Concerning the Accumulation of Minerals and Heavy Metals in Fruiting Bodies of Wild Mushrooms  

SciTech Connect (OSTI)

The minerals and heavy metals play an important role in the metabolic processes, during the growth and development of mushrooms, when they are available in appreciable concentration. In this work the concentrations of Cr, Mn, Fe, Ni, Cu, Zn, Se, Cd and Pb were analyzed using the Flame Atomic Absorption spectrometry (FAAS) together with Energy Dispersive X-ray Fluorescence spectrometry (EDXRF) in 3 wild mushrooms species and their growing substrate, collected from various forestry fields in Dambovita County, Romania. The analyzed mushrooms were: Amanita phalloides, Amanita rubescens and Armillariella mellea. The accumulation coefficients were calculated to assess the mobility of minerals and heavy metals from substrate to mushrooms [1].

Stihi, Claudia; Radulescu, Cristiana [Valahia University of Targoviste, Faculty of Sciences and Arts, Sciences Department, Unirii street, 130082, Targoviste (Romania); Gheboianu, Anca; Bancuta, Iulian [Valahia University of Targoviste, Multidisciplinary Research Institute for Sciences and Technologies, Unirii street, 130082, Targoviste (Romania); Popescu, Ion V. [Valahia University of Targoviste, Faculty of Sciences and Arts, Sciences Department, Unirii street, 130082, Targoviste (Romania); Valahia University of Targoviste, Multidisciplinary Research Institute for Sciences and Technologies, Unirii street, 130082, Targoviste (Romania); Academy of Romanian Scientist, Bucharest (Romania); Busuioc, Gabriela [Valahia University of Targoviste, Faculty of Environmental Engineering and Biotechnologies, Environmental Engineering Department, Unirii street, 130082, Targoviste (Romania)

2011-10-03T23:59:59.000Z

458

http://www.cemr.wvu.edu/freshman UPDATED 12/15/2010 COLLEGE OF ENGINEERING AND MINERAL RESOURCES FRESHMAN ENGINEERING  

E-Print Network [OSTI]

http://www.cemr.wvu.edu/freshman UPDATED 12/15/2010 COLLEGE OF ENGINEERING AND MINERAL RESOURCES ­ FRESHMAN ENGINEERING STUDY LAB POLICY SPRING 2011 The College of Engineering and Mineral Resources (CEMR in college. Student feedback indicates that students want more help in Math, Chemistry, Physics

Mohaghegh, Shahab

459

Shedding light on carbon-mineral complexation in the soil environment: impacts on C sequestration and cycling  

E-Print Network [OSTI]

42 Shedding light on carbon-mineral complexation in the soil environment: impacts on C sequestration and cycling Sparks, D.L. & C. Chen Department of Plant and Soil Sciences and Delaware@udel.edu) Abstract Organic matter (OM)-mineral complexation plays a critical role in soil carbon (C) stabilization

Sparks, Donald L.

460

MINERALIZATION OF RADIOACTIVE WASTES BY FLUIDIZED BED STEAM REFORMING (FBSR): COMPARISONS TO VITREOUS WASTE FORMS, AND PERTINENT DURABILITY TESTING  

SciTech Connect (OSTI)

The Savannah River National Laboratory (SRNL) was requested to generate a document for the Washington State Department of Ecology and the U.S. Environmental Protection Agency that would cover the following topics: (1) A description of the mineral structures produced by Fluidized Bed Steam Reforming (FBSR) of Hanford type Low Activity Waste (LAW including LAWR which is LAW melter recycle waste) waste, especially the cage structured minerals and how they are formed. (2) How the cage structured minerals contain some contaminants, while others become part of the mineral structure (Note that all contaminants become part of the mineral structure and this will be described in the subsequent sections of this report). (3) Possible contaminant release mechanisms from the mineral structures. (4) Appropriate analyses to evaluate these release mechanisms. (5) Why the appropriate analyses are comparable to the existing Hanford glass dataset. In order to discuss the mineral structures and how they bond contaminants a brief description of the structures of both mineral (ceramic) and vitreous waste forms will be given to show their similarities. By demonstrating the similarities of mineral and vitreous waste forms on atomic level, the contaminant release mechanisms of the crystalline (mineral) and amorphous (glass) waste forms can be compared. This will then logically lead to the discussion of why many of the analyses used to evaluate vitreous waste forms and glass-ceramics (also known as glass composite materials) are appropriate for determining the release mechanisms of LAW/LAWR mineral waste forms and how the durability data on LAW/LAWR mineral waste forms relate to the durability data for LAW/LAWR glasses. The text will discuss the LAW mineral waste form made by FBSR. The nanoscale mechanism by which the minerals form will be also be described in the text. The appropriate analyses to evaluate contaminant release mechanisms will be discussed, as will the FBSR test results to date and how they compare to testing performed on LAW glasses. Other details about vitreous waste form durability and impacts of REDuction/OXidation (REDOX) on durability are given in Appendix A. Details about the FBSR process, various pilot scale demonstrations, and applications are given in Appendix B. Details describing all the different leach tests that need to be used jointly to determine the leaching mechanisms of a waste form are given in Appendix C. Cautions regarding the way in which the waste form surface area is measured and in the choice of leachant buffers (if used) are given in Appendix D.

Jantzen, C

2008-12-26T23:59:59.000Z

Note: This page contains sample records for the topic "mineral gadolinite ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

The role of reaction affinity and secondary minerals in regulating chemical weathering rates at the Santa Cruz Soil Chronosequence, California  

SciTech Connect (OSTI)

In order to explore the reasons for the apparent discrepancy between laboratory and field weathering rates and to determine the extent to which weathering rates are controlled by the approach to thermodynamic equilibrium, secondary mineral precipitation and flow rates, a multicomponent reactive transport model (CrunchFlow) was used to interpret soil profile development and mineral precipitation and dissolution rates at the 226 ka marine terrace chronosequence near Santa Cruz, CA. Aqueous compositions, fluid chemistry, transport, and mineral abundances are well characterized (White et al., 2008, GCA) and were used to constrain the reaction rates for the weathering and precipitating minerals in the reactive transport modeling. When primary mineral weathering rates are calculated with either of two experimentally determined rate constants, the nonlinear, parallel rate law formulation of Hellmann and Tisser and [2006] or the aluminum inhibition model proposed by Oelkers et al. [1994], modeling results are consistent with field-scale observations when independently constrained clay precipitation rates are accounted for. Experimental and field rates, therefore, can be reconciled at the Santa Cruz site. Observed maximum clay abundances in the argillic horizons occur at the depth and time where the reaction fronts of the primary minerals overlap. The modeling indicates that the argillic horizon at Santa Cruz can be explained almost entirely by weathering of primary minerals and in situ clay precipitation accompanied by undersaturation of kaolinite at the top of the profile. The rate constant for kaolinite precipitation was also determined based on model simulations of mineral abundances and dissolved Al, SiO{sub 2}(aq) and pH in pore waters. Changes in the rate of kaolinite precipitation or the flow rate do not affect the gradient of the primary mineral weathering profiles, but instead control the rate of propagation of the primary mineral weathering fronts and thus total mass removed from the weathering profile. Our analysis suggests that secondary clay precipitation is as important as aqueous transport in governing the amount of dissolution that occurs within a profile because clay minerals exert a strong control over the reaction affinity of the dissolving primary minerals. The modeling also indicates that the weathering advance rate and the total mass of mineral dissolved is controlled by the thermodynamic saturation of the primary dissolving phases plagioclase and K-feldspar, as is evident from the difference in propagation rates of the reaction fronts for the two minerals despite their very similar kinetic rate laws.

Maher, K.; Steefel, C. I.; White, A.F.; Stonestrom, D.A.

2009-02-25T23:59:59.000Z

462

Measure Guideline: Three High Performance Mineral Fiber Insulation Board Retrofit Solutions  

SciTech Connect (OSTI)

This Measure Guideline describes a high performance enclosure retrofit package that uses mineral fiber insulation board. The Measure Guideline describes retrofit assembly and details for wood frame roof and walls and for cast concrete foundations. This Measure Guideline is intended to serve contractors and designers seeking guidance for non-foam exterior insulation retrofit.

Neuhauser, K.

2015-01-01T23:59:59.000Z

463

Inhibition Effect of Secondary Phosphate Mineral Precipitation on Uranium Release from Contaminated Sediments  

SciTech Connect (OSTI)

The inhibitory effect of phosphate mineral precipitation on uranium release was evaluated using a U(VI)-contaminated sediment collected from the US Department of Energy (DOE) Hanford site. The sediment contained U(VI) that was associated with diffusion-limited intragrain regions within its mm-size granitic lithic fragments. The sediment was first treated to promote phosphate mineral precipitation in batch suspensions spiked with 1 and 50 mM aqueous phosphate, and calcium in a stoichiometric ratio of mineral hydroxyapatite. The phosphate-treated sediment was then leached to solubilize contaminant U(VI) in a column system using a synthetic groundwater that contained chemical components representative of Hanford groundwater. Phosphate treatment significantly decreased the extent of U(VI) release from the sediment. Within the experimental duration of about 200 pore volumes, the effluent U(VI) concentrations were consistently lower by over one and two orders of magnitude after the sediment was treated with 1 and 50 mM of phosphate, respectively. Measurements of solid phase U(VI) using various spectroscopes and chemical extraction of the sediment collectively indicated that the inhibition of U(VI) release from the sediment was caused by: 1) U(VI) adsorption to the secondary phosphate precipitates and 2) the transformation of initially present U(VI) mineral phases to less soluble forms.

Shi, Zhenqing; Liu, Chongxuan; Zachara, John M.; Wang, Zheming; Deng, Baolin

2009-11-01T23:59:59.000Z

464

USE OF CdTe DETECTORS IN BONE MINERAL MEASUREMENTS J. VOGEL, J. ULLMAN  

E-Print Network [OSTI]

375 USE OF CdTe DETECTORS IN BONE MINERAL MEASUREMENTS J. VOGEL, J. ULLMAN Nuclear Medicine. Cet ensemble emploie des détecteurs CdTe mesurant la transmission d'un faisceau collimaté de rayons X periods of prolonged bedrest or weightlessness. The unit employs CdTe detectors to mea- sure

Paris-Sud XI, Université de

465

4.4 Nanoscale: Mineral Weathering Boundary RI Dorn, Arizona State University, Tempe, AZ, USA  

E-Print Network [OSTI]

of more intense dissolution are seen as pits on the scale of micrometers. Heavy metal scavenging Iron and manganese oxides and hydroxides scavenge heavy metals such as zinc, copper, and lead. High in mineral weathering, silt production, rock coating behavior, geochemical pollution, thermal weathering from

Dorn, Ron

466

The need of mineral resources driven by the energy transition for the next 40 years  

E-Print Network [OSTI]

increase in the share of solar and wind energy Evolution of hydro, solar and wind energy production world production PV from PH 2002 PH 2002 PH 2002 PH 2002 #12;Should we worry ? Materials requirementsThe need of mineral resources driven by the energy transition for the next 40 years Olivier Vidal

Canet, Léonie

467

In Brief . ... resident scholar in the Center for Energy and Mineral Resources, will  

E-Print Network [OSTI]

In Brief . ... resident scholar in the Center for Energy and Mineral Resources, will administer production of hatchery seed and the culture of marketable oysters. They also hope to increase productivity director of Texas A&M Univer- sity's Center for Marine Resources, the University reports. Hann, who

468

Department of Energy and Mineral Engineering Spring 2013 Solar Innovations, Inc. Energy Management Program  

E-Print Network [OSTI]

Management Program Overview A team of six energy engineering students was assigned the task of developing an energy management program in order to reduce the client's energy use. The team had 14 weeks (1 semesterPENNSTATE Department of Energy and Mineral Engineering Spring 2013 Solar Innovations, Inc. Energy

Demirel, Melik C.

469

Effect of a liquid multi-vitamin-mineral supplement on anaerobic exercise performance  

E-Print Network [OSTI]

The purpose of this study was to determine if supplementation with a liquid multi-vitamin/mineral would improve anaerobic exercise performance. Fourteen resistance-trained men performed a 30-second cycle sprint and one set of squat exercise on 2...

Fry, Andrew C.; Bloomer, Richard J.; Falvo, Michael J.; Moore, Chris A.; Schilling, Brian K.; Weiss, Lawrence W.

2006-01-01T23:59:59.000Z

470

GFDI COLLOQUIUM "Use of Mineral vs. Polymer Drilling Fluids in Deep  

E-Print Network [OSTI]

GFDI COLLOQUIUM Title "Use of Mineral vs. Polymer Drilling Fluids in Deep Foundation Construction. Refreshments will be served at 1:30M ABSTRACT: In deep foundation design, drilled shafts (also referred to as bored piles or drilled caissons) are preferred because of their large load capacities and greater

Ronquist, Fredrik

471

John G. Hinchey Ke iko H. Hattori Magmatic mineralization and hydrothermal enrichment of the High Grade  

E-Print Network [OSTI]

ARTICLE John G. Hinchey � Ke´ iko H. Hattori Magmatic mineralization and hydrothermal enrichment; millerite + siegenite ± chalcopyrite ± pyrite co-existing with hornblende + plagioclase ± quartz ± carbonate, and pyrite ± chalcopyrite with chlorite + actinolite ± albite ± quartz ± carbonate. The ore is high in Pd

472

Helping effort increases with relatedness in bell miners, but `unrelated' helpers of both  

E-Print Network [OSTI]

Helping effort increases with relatedness in bell miners, but `unrelated' helpers of both sexes-breeding individuals help raise the young of relatives. However, the evolution of helping by non-relatives requires extremely clear evidence for the expected effect of genetic relatedness on individual helping effort per

Richner, Heinz

473

Research Profile Particles are everywhere: from the earth and its mineral min-  

E-Print Network [OSTI]

Research Profile Particles are everywhere: from the earth and its mineral min- ing to the air we aiming for new catalysts, sensors, nanocomposites,fuel cells,batteries,phosphors,CO2 sorbents, dental, orthopedic and even nutritional applications. Competences / Infrastructure Mixed ceramic/metal nanoparticle

Sandoghdar, Vahid

474

King Fahd University of Petroleum & Minerals College of Compute Sciences and Engineering  

E-Print Network [OSTI]

King Fahd University of Petroleum & Minerals College of Compute Sciences and Engineering and evaluation, specification, design, and evolution of software. In addition, vital issues in software that integrate ethical, social, legal, and economic concerns 4. Demonstrate the ability to work as an individual

El-Alfy, El-Sayed

475

1. Department, Course Number, Title ORE 678, Marine Mineral Resources Engineering  

E-Print Network [OSTI]

Nodules and Marine Mining · Deep Sea Mining Technology · Minerals Processing · Offshore Oil and Gas · Oil · Formation Processes of Polymetallic Sulfides (PMS) on the Ocean Floor: Geology of the Smoker and PMS · Chemistry of Hydrothermal Vents and Polymetallic Sulfides · PMS Deposits: From Smoker to an Ore Body · Case

Frandsen, Jannette B.

476

Permeability changes due to mineral diagenesis in fractured crust: implications for hydrothermal circulation at  

E-Print Network [OSTI]

The hydrothermal processes at ridge crests have been extensively studied during the last two decades. NeverthelessPermeability changes due to mineral diagenesis in fractured crust: implications for hydrothermal, the reasons why hydrothermal fields are only occasionally found along some ridge segments remain a matter

Manga, Michael

477

Coke gasification: the influence and behavior of inherent catalytic mineral matter  

SciTech Connect (OSTI)

Gasification of coke contributes to its degradation in the blast furnace. In this study, the effect of gasification on the inherent catalytic minerals in cokes and their reciprocal influence on gasification are investigated. The catalytic mineral phases identified in the cokes used in this study were metallic iron, iron sulfides, and iron oxides. Metallic iron and pyrrhotite were rapidly oxidized during gasification to iron oxide. The catalysts had a strong influence on the apparent rates at the initial stages of reaction. As gasification proceeds, their effect on the reaction rate diminishes as a result of reducing the surface contact between catalyst and carbon matrix because of carbon consumption around the catalyst particles; with extended burnout the reactivity of the coke becomes increasingly dependent on surface area. The reaction rate in the initial stages was also influenced by the particle size of the catalytic minerals; for a given catalytic iron level, the cokes whose catalytic minerals were more finely dispersed had a higher apparent reaction rate than cokes containing larger catalytic particles. Iron, sodium, and potassium in the amorphous phase did not appear to affect the reaction rate. 40 refs., 16 figs., 6 tabs.

Mihaela Grigore; Richard Sakurovs; David French; Veena Sahajwalla [Commonwealth Scientific and Industrial Research Organisation (CSIRO), Bangor, NSW (Australia)

2009-04-15T23:59:59.000Z

478

DIVISION S-10--WETLAND SOILS Carbon Accumulation and Storage in Mineral Subsoil beneath Peat  

E-Print Network [OSTI]

DIVISION S-10--WETLAND SOILS Carbon Accumulation and Storage in Mineral Subsoil beneath Peat Tim R subsoil (Turunen and Moore, 2003). TheyWe showed that sandy subsoils beneath peat near Ramsey Lake conditions beneath the peat. soils beneath the forest, those beneath the peat contained similar In this paper

Moore, Tim

479

Mineral bone composition and some elements of calcium metabolism in magnesium-deficient growing rats  

E-Print Network [OSTI]

Mineral bone composition and some elements of calcium metabolism in magnesium-deficient growing-Chomponelle, Theix, 63110 Beaumont, France. Summary. (1) Magnesium deficiency was induced in Sprague-Dawley male rats of deprivation. (3) The leg bones were fragmented as shown in figure 1. Their magnesium content had decreased

Paris-Sud XI, Université de

480

150 Years of Boom and Bust: What Drives Mineral Commodity Prices?  

E-Print Network [OSTI]

and production levels of copper, lead, tin, zinc, and crude oil from 1840 to 2010. Price fluctuations that price surges caused by rapid industrialization are a recurrent phenomenon throughout history. Mineral that supply shocks account for the broad behavior of the price of crude oil. In contrast, Kilian (2008b, 2009

Nesterov, Yurii

Note: This page contains sample records for the topic "mineral gadolinite ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

PASI 2011: Process Modeling and Optimization for Energy and Sustainability Mineral Process Design for  

E-Print Network [OSTI]

PASI 2011 PASI 2011: Process Modeling and Optimization for Energy and Sustainability Mineral, high population growth and urbanization, both key metals consumption and GDP are expected to grow the environmental impact, both in per tonne of product and on total amount of emissions and reduction. #12

Grossmann, Ignacio E.

482

Solidification of Aluminum Alloys Edited by TMS (The Minerals, Metals & Materials Society), 2004  

E-Print Network [OSTI]

Solidification of Aluminum Alloys Edited by TMS (The Minerals, Metals & Materials Society), 2004 Modeling the Effects of Mold Topography on Aluminum Cast Surfaces Lijian Tan1 , Nicholas Zabaras1 1 14853, USA Keywords: Aluminum Solidification; Mold topography; Cast Surfaces Abstract The air

Zabaras, Nicholas J.

483

Role of microbial iron reduction in the dissolution of iron hydroxysulfate minerals - article no. G01012  

SciTech Connect (OSTI)

Reduction of structural sulfate in the iron-hydroxysulfate mineral jarosite by sulfate-reducing bacteria has previously been demonstrated. The primary objective of this work was to evaluate the potential for anaerobic dissolution of the iron-hydroxysulfate minerals jarosite and schwertmannite at neutral pH by iron-reducing bacteria. Mineral dissolution was tested using a long-term cultivar, Geobacter metallireducens strain GS-15, and a fresh isolate Geobacter sp. strain ENN1, previously undescribed. ENN1 was isolated from the discharge site of Shadle Mine, in the southern anthracite coalfield of Pennsylvania, where schwertmannite was the predominant iron-hydroxysulfate mineral. When jarosite from Elizabeth Mine (Vermont) was provided as the sole terminal electron acceptor, resting cells of both G. metallireducens and ENN1 were able to reduce structural Fe(III), releasing Fe{sup +2}, SO{sub 4}{sup -2}, and K{sup +} ions. A lithified jarosite sample from Utah was more resistant to microbial attack, but slow release of Fe{sup +2} was observed. Neither bacterium released Fe{sup +2} from poorly crystalline synthetic schwertmannite. Our results indicate that exposure of jarosite to iron-reducing conditions at neutral pH is likely to promote the mobility of hazardous constituents and should therefore be considered in evaluating waste disposal and/or reclamation options involving jarosite-bearing materials.

Jones, E.J.P.; Nadeau, T.L.; Voytek, M.A.; Landa, E.R. [US Geological Survey, Reston, VA (United States)

2006-03-28T23:59:59.000Z

484

Effects of sulfuric acid and nitrogen deposition on mineral nutrition of Picea abies (L.) Karst.  

E-Print Network [OSTI]

ecosystems, saplings have been sprayed with artificial acid rain, structured soil samples have been extractedEffects of sulfuric acid and nitrogen deposition on mineral nutrition of Picea abies (L.) Karst. B sites in the Fichtel- gebirge, and low fogwater pH (Trautner, 1989) of 2.2 indicate a high acid stress

Paris-Sud XI, Université de

485

Porphyry Copper and Other Intrusion-Related Mineralization in Mexico MARK D. BARTON  

E-Print Network [OSTI]

Porphyry Copper and Other Intrusion-Related Mineralization in Mexico MARK D. BARTON JOHN-MARK G Inc., Tucson, Arizona ABSTRACT Intrusion-related copper-bearing ore deposits in Mexico span a wide. These deposits include world-class copper porphyry and skarn deposits as well as a continuum of similar skarn

Barton, Mark D.

486

Ke iko H. Hattori Jerey D. Keith Contribution of mac melt to porphyry copper mineralization  

E-Print Network [OSTI]

mineralization: evidence from Mount Pinatubo, Philippines, and Bingham Canyon, Utah, USA Received: 15 April 2001 Canyon, Utah, site of the largest copper and gold deposit in North America at 38 Ma. The Bingham Canyon and selenium (Hattori 1993, 1996). We suggest that a sim- ilar process took place at 38 Ma at Bingham Canyon

487

Mineral and Rock Physics [MR] MR21B MCW:Level 1 Tuesday 0800h  

E-Print Network [OSTI]

Mineral and Rock Physics [MR] MR21B MCW:Level 1 Tuesday 0800h Structural Refinement Studies Kunz, Advanced Light Source MR21B-0018 The Crystal Structure of Diopside at Pressure to 10 Gpa tetrahedra and M1 octahedra to try and understand the observed changes in pyroxenes with changing P, T, and x

Downs, Robert T.

488

Grid computing and molecular simulations: the vision of the eMinerals project  

E-Print Network [OSTI]

1 Grid computing and molecular simulations: the vision of the eMinerals project Martin T Dove1, London WC1E 7HX Abstract This paper discusses a number of aspects of using grid computing methods for a useful grid infrastructure are discussed, including the integration of compute and data grids, automatic

Cambridge, University of

489

KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS Information and Computer Science Department  

E-Print Network [OSTI]

KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS Information and Computer Science Department ICS431 an error, you must report that the command can not be found and the child process should exit(). #12 sure you print its status and then wait again for current foreground command. Part 2: In this Part, you

Razak, Saquib

490

KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS Information and Computer Science Department  

E-Print Network [OSTI]

KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS Information and Computer Science Department ICS431 is not possible mathematically 6 / 0 For operations like this, your program should report the following the exit status from the "wait" call and check if the program terminated due to an exception. #12;

Razak, Saquib

491

KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS Information and Computer Science Department  

E-Print Network [OSTI]

KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS Information and Computer Science Department ICS 431 ends when its termination is reported to its parent process; at that time, all of the process resources--for example, its exit status code. A newly forked child process continues to execute the same program as its

Razak, Saquib

492

KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS Information and Computer Science Department  

E-Print Network [OSTI]

KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS Information and Computer Science Department ICS431: You must add "job status" to the shell. This means you have to recognize the command "ps to be executed. If the execvp/execvl returns an error, you must report that the command can not be found

Razak, Saquib

493

Department of Earth and Mineral Engineering Spring 2011 Oxidative Coupling of Methane Reactor  

E-Print Network [OSTI]

PENNSTATE Department of Earth and Mineral Engineering Spring 2011 Oxidative Coupling of Methane of an experimental reactor designed to couple methane to ethane and dehydrogenate ethane to ethylene. The reactor and build the reactor and perform methane conversion testing to provide proof of concept for the OCM

Demirel, Melik C.

494

Estimated number of women likely to benefit from bone mineral density measurement in France  

E-Print Network [OSTI]

; Menopause Introduction The prevalence of osteoporosis is rising, most notably in postmenopausal women years of age with risk factors for osteoporosis likely to lead to bone mineral density measurement, an investigation reimbursed by the French national health insurance system in patients at risk for osteoporosis

Paris-Sud XI, Université de

495

The chemistry of minerals obtained from the combustion of Jordanian oil shale  

E-Print Network [OSTI]

The chemistry of minerals obtained from the combustion of Jordanian oil shale Awni Y. Al was performed on the spent oil shale (oil shale ash) obtained from the combustion of Jordanian oil shale process, minimal fragmentation was encountered since Jordanian oil shale contains large proportions of ash

Shawabkeh, Reyad A.

496

Effects of internal mineral structures on the magnetic remanence of silicate-hosted titanomagnetite inclusions  

E-Print Network [OSTI]

Effects of internal mineral structures on the magnetic remanence of silicate-hosted titanomagnetite epitaxially by exsolution from their host silicate. Close examination of clinopyroxene- hosted inclusions of silicate-hosted titanomagnetite inclusions: An electron holography study, J. Geophys. Res., 111, B12S15

Dunin-Borkowski, Rafal E.

497

Impact of Particle Generation Method on the Apparent Hygroscopicity of Insoluble Mineral Particles  

SciTech Connect (OSTI)

Atmospheric mineral dust particles represent a major component of tropospheric aerosol mass and provide a reactive surface for heterogeneous reactions with trace atmospheric gases (Dentener et al. 1996).Heterogeneous processes alter the chemical balance of the atmosphere and also modify the physicochemical properties of mineral dust particles (Bauer et al. 2004). Organic and inorganic vapors can react with or partition to dust particles and alter their chemical composition (Al-Hosney et al. 2005; Laskin et al. 2005a, 2005b; Liu et al. 2008; Sullivan et al. 2007, 2009a; Sullivan and Prather 2007; Usher et al. 2003). Calcite (CaCO3) is one of the most reactive components of mineral dust, readily reacting with acidic gases. The fraction of CaCO3 in total dust mineralogy displays large variations between desert regions and other regions of the world as well as between individual mineral particles (Claquin et al. 1999; Jeong 2008; Laskin et al. 2005b; Sullivan et al. 2007). Through reactions with acidic gases CaCO3 can be converted to soluble hygroscopic products including CaCl2 and Ca(NO3)2, and sparingly soluble, non-hygroscopic products including CaSO4 and CaC2O4 (Krueger et al. 2004; Liu et al. 2008; Sullivan et al. 2009a, 2009b).

Sullivan, Ryan; Moore, Meagan J.; Petters, Markus D.; Kreidenweis, Sonia M.; Qafoku, Odeta; Laskin, Alexander; Roberts, Greg C.; Prather, Kimberly A.

2010-07-28T23:59:59.000Z

498

Basin evolution, diagenesis and uranium mineralization in the PaleoproterozicThelon Basin,  

E-Print Network [OSTI]

Basin evolution, diagenesis and uranium mineralization in the PaleoproterozicThelon Basin, Nunavut,Canada Eric E. Hiatt,n Sarah E. Palmer,w1 T. Kurt Kyserw and Terrence K. O'Connorz n Geology Department, University of Wisconsin Oshkosh, Oshkosh,Wisconsin, USA wDepartment of Geological Sciences and Engineering

Hiatt, Eric E.

499

Precambrian Research 148 (2006) 125144 The uranium mineralization potential of the Paleoproterozoic  

E-Print Network [OSTI]

Precambrian Research 148 (2006) 125­144 The uranium mineralization potential. Hanlya,, T. Kurtis Kysera, Eric E. Hiattb, Jim Marlattc, Sandra Fosterc a Department of Geological Sciences and Geological Engineering, Queen's University, Kingston, Ont., Canada K7L 3N6 b Geology

Hiatt, Eric E.

500

NEW MEXICO SCHOOL OF MINES STATE BUREAU OF MINES AND MINERAL RESOURCES  

E-Print Network [OSTI]

NEW MEXICO SCHOOL OF MINES STATE BUREAU OF MINES AND MINERAL RESOURCES BULLETIN 13 FRONTISPIECE PIT AT HARDING MINE (To left of dump) DUMP AT HARDING MINE (To right of pit) #12;NEW MEXICO SCHOOL OF MINES STATE and Economic Features of the Pegmatites of Taos and Rio Arriba Counties, New Mexico By EVAN JUST SOCORRO, N. M

Lee, Cin-Ty Aeolus