National Library of Energy BETA

Sample records for mineral gadolinite ce

  1. Clay Minerals

    SciTech Connect (OSTI)

    Mueller, Karl T.; Sanders, Rebecca L.; Washton, Nancy M.

    2014-03-14

    Clay minerals are important components of the environment and are involved or implicated in processes such as the uptake of pollutants and the release of nutrients and as potential platforms for a number of chemical reactions. Owing to their small particle sizes (typically, on the order of microns or smaller) and mixing with a variety of other minerals and soil components, advanced characterization methods are needed to study their structures, dynamics, and reactivities. In this article, we describe the use of solid-state NMR methods to characterize the structures and chemistries of clay minerals. Early one-pulse magic-angle spinning (MAS) NMR studies of 27Al and 29Si have now been enhanced and extended with new studies utilizing advanced methodologies (such as Multiple Quantum MAS) as well as studies of less-sensitive nuclei. In additional work, the issue of reactivity of clay minerals has been addressed, including studies of reactive surface area in the environment. Utilizations of NMR-sensitive nuclides within the clay minerals themselves, and in molecules that react with speci?c sites on the clay mineral surfaces, have aided in understanding the reactivity of these complex aluminosilicate systems.

  2. Fall even years Spring odd years CE G7100 Water & Wastewater Quality CE G0800 GIS in WREE

    E-Print Network [OSTI]

    Wolberg, George

    Drinking Water Treatment CE H0800 Applied Hydraulics CE 58300/H8300 Air Pollution and Control CE 56600/H7600 Biological Wastewater Treatment CE 58400/H8400 Solid Waste Management CE 48200 WaterFall even years Spring odd years CE G7100 Water & Wastewater Quality CE G0800 GIS in WREE CE G8100

  3. Table 1. Connection of Criterion 8 CE Outcomes to CE Courses (required, design elective, advanced elective)

    E-Print Network [OSTI]

    Chen, Xinzhong

    ENVE 4391 ENVE 4399 Water, wastewater, air, solid waste Physical and chemical treatment Advanced water Experiments, Interpret Data CE 2101 CE 3103 CE 3105 CE 3121 CE 3171 Construction materials behaviors Material codes and construction practices Design codes and construction practices Regulations, interaction

  4. Earth's Mineral Evolution

    E-Print Network [OSTI]

    Downs, Robert T.

    Earth's Mineral Evolution :: Astrobiology Magazine - earth science - evol...rth science evolution Extreme Life Mars Life Outer Planets Earth's Mineral Evolution Summary (Nov 14, 2008): New research. Display Options: Earth's Mineral Evolution Based on a CIW news release Mineral Kingdom Has Co

  5. College of Engineering CE Civil Engineering

    E-Print Network [OSTI]

    MacAdam, Keith

    College of Engineering CE Civil Engineering KEY: # = new course * = course changed = course.Lecture,twohours;laboratory,fourhoursperweek.Prereqorcoreq:MA113orconsentofinstructor. CE 120 INTRODUCTION TO CIVIL ENGINEERING. (1) An introduction to the civil engineering profession and the use of computer hardware and software in CE systems analysis and design

  6. MINERAL FACILITIES MAPPING PROJECT

    E-Print Network [OSTI]

    Gilbes, Fernando

    Questionnaires. Update the data that pertaining to MIT's contacts worldwide. #12;BOJNOURD CEMENT PLANT Location a database using the Structural Table of Mineral Industry, which includes the location of main mineral The mineral facilities database included: Type of facility: Mine (open pit, underground) Plant ( refineries

  7. MINERAL COMMODITY SUMMARIES 2002

    E-Print Network [OSTI]

    Torgersen, Christian

    Kyanite Lead Lime Lithium Magnesium Manganese Mercury Mica Molybdenum Nickel Nitrogen Peat Perlite . . . . . . . . . . . . . . . . . . . . . . . . . . . . 192 Appendix C--A Resource/Reserve Classification for Minerals

  8. Thermoelectric Couple Demonstration of (In, Ce)-based Skutterudite...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Couple Demonstration of (In, Ce)-based Skutterudite Materials for Automotive Energy Recovery Thermoelectric Couple Demonstration of (In, Ce)-based Skutterudite Materials for...

  9. Vitamin and mineral requirements

    E-Print Network [OSTI]

    Laughlin, Robert B.

    Vitamin and mineral requirements in human nutrition Second edition Please go to the Table/WHO Expert Consultation on Human Vitamin and Mineral Requirements (1998 : Bangkok, Thailand). Vitamin, 21­30 September 1998. 1.Vitamins -- standards 2.Micronutrients -- standards 3.Trace elements

  10. Cost objective PLM and CE

    E-Print Network [OSTI]

    Nicolas Perry; Alain Bernard

    2010-11-26

    Concurrent engineering taking into account product life-cycle factors seems to be one of the industrial challenges of the next years. Cost estimation and management are two main strategic tasks that imply the possibility of managing costs at the earliest stages of product development. This is why it is indispensable to let people from economics and from industrial engineering collaborates in order to find the best solution for enterprise progress for economical factors mastering. The objective of this paper is to present who we try to adapt costing methods in a PLM and CE point of view to the new industrial context and configuration in order to give pertinent decision aid for product and process choices. A very important factor is related to cost management problems when developing new products. A case study is introduced that presents how product development actors have referenced elements to product life-cycle costs and impacts, how they have an idea bout economical indicators when taking decisions during the progression of the project of product development.

  11. Palmetto Clean Energy (PaCE) Program

    Broader source: Energy.gov [DOE]

    PaCE funding comes from the customers of participating utilities who voluntarily choose to support the program through an additional charge on their monthly utility bills. Of the $4, $3.50 goes t...

  12. MINERAL COMMODITY SUMMARIES 2003

    E-Print Network [OSTI]

    Torgersen, Christian

    Kyanite Lead Lime Lithium Magnesium Manganese Mercury Mica Molybdenum Nickel Nitrogen Peat Perlite Magnesium Manganese Mercury Mica Molybdenum Nickel Nitrogen Peat Perlite Phosphate Rock Platinum Potash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 194 Appendix C--A Resource/Reserve Classification for Minerals

  13. Search for pressure-induced superconductivity in CeFeAsO and CeFePO iron pnictides

    SciTech Connect (OSTI)

    Zocco, D. A. [University of California, San Diego; Baumbach, R. E. [University of California, San Diego; Hamlin, J. J. [University of California, San Diego; Janoschek, M. [University of California, San Diego; Lum, I. K. [University of California, San Diego; McGuire, Michael A [ORNL; Safa-Sefat, Athena [ORNL; Sales, Brian C [ORNL; Jin, Rongying [ORNL; Mandrus, David [ORNL; Jeffries, J. R. [Lawrence Livermore National Laboratory (LLNL); Weir, S. T. [Lawrence Livermore National Laboratory (LLNL); Vohra, Y. K. [University of Alabama, Birmingham; Maple, M. B. [University of California, San Diego

    2011-01-01

    The CeFeAsO and CeFePO iron pnictide compounds were studied via electrical transport measurements under high pressure. In CeFeAsO polycrystals, the magnetic phases involving the Fe and Ce ions coexist for hydrostatically applied pressures up to 15 GPa, and with no signs of pressure-induced superconductivity up to 50 GPa for the less hydrostatic pressure techniques. For the CeFePO single crystals, pressure further stabilizes the Kondo screening of the Ce 4f-electron magnetic moments.

  14. MINERAL COMMODITY SUMMARIES 2014

    E-Print Network [OSTI]

    Torgersen, Christian

    Talc Bauxite Graphite Peat Tantalum Beryllium Gypsum Perlite Tellurium Bismuth Hafnium Phosphate Rock resources, natural hazards, and the environment-- visit http://www.usgs.gov or call 1­888­ASK--Reserves and Resources.....................191 Appendix D--Country Specialists Directory...............195 Mineral

  15. MINERAL COMMODITY SUMMARIES 2012

    E-Print Network [OSTI]

    Fleskes, Joe

    Nitrogen Sulfur Bauxite Graphite Peat Talc Beryllium Gypsum Perlite Tantalum Bismuth Hafnium Phosphate Rock and living resources, natural hazards, and the environment-- visit http://www.usgs.gov or call 1­888­ASK--Reserves and Resources.....................193 Appendix D--Country Specialists Directory...............197 Mineral

  16. Engineering and Mineral Resources

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    News ????????????????? ® College of Engineering and Mineral Resources Winter 2008 table of contents. . . . . . . . . . . . . . . . . . . . 7 wvCROSSROADS DepartmentofCivilandEnvironmentalEngineering Civil engineering exchange program and environmental engineering with a focus in transportation will have the opportunity to study abroad as part

  17. RON MINER MEMORIAL BIOENGINEERING SCHOLARSHIP The Ron Miner Memorial Scholarship honors the memory of J. Ronald Miner, an

    E-Print Network [OSTI]

    Tullos, Desiree

    RON MINER MEMORIAL BIOENGINEERING SCHOLARSHIP The Ron Miner Memorial Scholarship honors the memory & Ecological Engineering. DONOR Ron Miner Memorial Bioengineering Scholarship Fund ELIGIBILITY REQUIREMENTS

  18. CE 576 Environmental Flows Spring 2012

    E-Print Network [OSTI]

    Rehmann, Chris

    .1. Conservation of mass 1.2. Conservation of momentum 2. Channel flows 2.1. Laminar flow 2.1.1. Flow in a tubeCE 576 Environmental Flows Spring 2012 Course information Instructor: Prof. Chris Rehmann rehmann in environmental fluid mechanics Prerequisites: Elementary fluid mechanics, calculus, differential equations

  19. CE 473/573 Groundwater Learning objectives

    E-Print Network [OSTI]

    Rehmann, Chris

    CE 473/573 Groundwater Fall 2009 Learning objectives While the goals of the class are quite general for various soil types and explain how sorting affects porosity. Explain how results from a groundwater model. Sketch and explain profiles of piezometric head. 7. Define groundwater divide and compute its properties

  20. CE 473/573 Groundwater Learning objectives

    E-Print Network [OSTI]

    Rehmann, Chris

    CE 473/573 Groundwater Fall 2011 Learning objectives While the goals of the class are quite general. Identify contemporary issues involving groundwater; explain how solutions that use knowledge of groundwater of piezometric head. Define groundwater divide and compute its properties. Explain how to determine whether

  1. CE 473/573 Groundwater Course information

    E-Print Network [OSTI]

    Rehmann, Chris

    CE 473/573 Groundwater Fall 2011 Course information Instructor: Prof. Chris Rehmann rehmann of water and contaminants in groundwater systems to solve problems of groundwater resource evaluation and groundwater contamination, to develop thinking skills, to communicate effectively and function on teams

  2. CE 473/573 Groundwater Course information

    E-Print Network [OSTI]

    Rehmann, Chris

    CE 473/573 Groundwater Fall 2009 Course information Instructor: Prof. Chris Rehmann rehmann of water and contaminants in groundwater systems to solve problems of groundwater resource evaluation and groundwater contamination, to develop thinking skills, to communicate effectively and function on teams

  3. Biomimetic Mineralization: Mesoporous Biological mineral synthesis, in contrast to conven-

    E-Print Network [OSTI]

    Biomimetic Mineralization: Mesoporous Structures Biological mineral synthesis, in contrast of mineral crystals. Mesophases are materials which have domain length scales of the order of a few as a molecular blueprint for the site- directed formation of the inorganic phase, by providing an interface

  4. CIVIL ENGINEERING CURRICULUM EFFECTIVE FALL 2015 CE 1105 ......................................................... 1 CE 1252 ........................................................ 2

    E-Print Network [OSTI]

    Huang, Haiying

    6/9/2015 CIVIL ENGINEERING CURRICULUM EFFECTIVE FALL 2015 FIRST YEAR CE 1105 ......................................................... 4 MATH 3319 ........................................................ 3 17 17 See "Civil Engineering school foreign language. REQUIRED COURSE TITLES COMMUNICATIONS CIVIL ENGINEERING (ABET Proficiency test

  5. A. G. Walton October 1999 Civil Engineering CE201 Mathematics

    E-Print Network [OSTI]

    Walton, Andrew G

    Civil Engineering CE201 Mathematics Lecturers: Andy Walton, David Denison, Roy Jacobs Timetable. Advanced Engineering Mathematics, E. Kreyszig.

  6. Dr. T.P. Clement CE 3010 class notes

    E-Print Network [OSTI]

    Clement, Prabhakar

    8/15/2011 1 Dr. T.P. Clement CE 3010 class notes Learning Objectives · Motivation · Basic approach value of the definite integral 2 b a dxxf )( Dr. T.P. Clement CE 3010 class notes Analytical (or exact a dxxf )( Dr. T.P. Clement CE 3010 class notes Trapezoidal Rule F(x) #12;8/15/2011 2 Dr. T.P. Clement CE

  7. Spin reorientation and Ce-Mn coupling in antiferromagnetic oxypnictide CeMnAsO

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Qiang; Tian, Wei; Peterson, Spencer G.; Dennis, Kevin W.; Vaknin, David

    2015-02-18

    Structure and magnetic properties of high-quality polycrystlline CeMnAsO, a parent compound of the “1111”-type oxypnictides, have been investigated using neutron powder diffraction and magnetization measurements. We find that CeMnAsO undergoes a C-type antiferromagnetic order with Mn2+(S = 5/2) moments pointing along the c axis below a relatively high Néel temperature of TN = 347(1) K. Below TSR = 35 K, two simultaneous transitions occur where the Mn moments reorient from the c axis to the ab plane preserving the C-type magnetic order, and Ce moments undergo long-range AFM ordering with antiparallel moments pointing in the ab plane. Another transition tomore »a noncollinear magnetic structure occurs below 7 K. The ordered moments of Mn and Ce at 2 K are 3.32(4) ?B and 0.81(4)?B, respectively. We find that CeMnAsO primarily falls into the category of a local-moment antiferromagnetic insulator in which the nearest-neighbor interaction (J1) is dominant with J2 1/2 in the context of J1 – J2 – Jc model. The spin reorientation transition driven by the coupling between Ce and the transition metal seems to be common to Mn, Fe, and Cr ions, but not to Co and Ni ions in the isostructural oxypnictides. As a result, a schematic illustration of magnetic structures in Mn and Ce sublattices in CeMnAsO is presented.« less

  8. GIS IN WATER RESOURCES CE 413/513, 3 credits

    E-Print Network [OSTI]

    Wright, Dawn Jeannine

    GIS IN WATER RESOURCES CE 413/513, 3 credits Prerequisites: Senior or graduate in Engineering or one previous GIS course CE 413 Instructor: Tracy Arras CE 513 Instructor: Wayne Huber Office: Owen 238 Learning Objectives · Demonstrate the basic concepts and operation of GIS for water resources Data models

  9. Minerals and mine drainage

    SciTech Connect (OSTI)

    Liang, H.C.; Thomson, B.M. [Tetra Technical Inc, Denver, CO (United States)

    2009-09-15

    A review of literature published in 2008 and early 2009 on research related to the production of acid mine drainage and/or in the dissolution of minerals as a result of mining, with special emphasis on the effects of these phenomena on the water quality in the surrounding environment, is presented. This review is divided into six sections: 1) Site Characterization and Assessment, 2) Protection, Prevention, and Restoration, 3) Toxicity Assessment, 4) Environmental Fate and Transport, 5) Biological Characterization, and 6) Treatment Technologies. Because there is much overlap in research areas associated with minerals and mine drainage, many papers presented in this review can be classified into more than one category, and the six sections should not be regarded as being mutually-exclusive, nor should they be thought of as being all-inclusive.

  10. Role of Ce4+ in the scintillation mechanism of codoped Gd3Ga3Al2O12:Ce

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wu, Yuntao; Meng, Fang; Li, Qi; Koschan, Merry; Melcher, Charles L.

    2014-10-17

    To control the time-response performance of widely used cerium-activated scintillators in cutting-edge medical-imaging devices, such as time-of-flight positron-emission tomography, a comprehensive understanding of the role of Ce valence states, especially stable Ce4+, in the scintillation mechanism is essential. However, despite some progress made recently, an understanding of the physical processes involving Ce4+ is still lacking. The aim of this work is to clarify the role of Ce4+ in scintillators by studying Ca2+ codoped Gd3Ga3Al2O12?Ce?(GGAG?Ce). By using a combination of optical absorption spectra and x-ray absorption near-edge spectroscopies, the correlation between Ca2+codoping content and the Ce4+ fraction is seen. The energy-levelmore »diagrams of Ce3+ and Ce4+ in the Gd3Ga3Al2O12 host are established by using theoretical and experimental methods, which indicate a higher position of the 5d1 state of Ce4+ in the forbidden gap in comparison to that of Ce3+. Underlying reasons for the decay-time acceleration resulting from Ca2+ codoping are revealed, and the physical processes of the Ce4+-emission model are proposed and further demonstrated by temperature-dependent radioluminescence spectra under x-ray excitation.« less

  11. Iron oxyhydroxide mineralization on microbial extracellular polysaccha...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Iron oxyhydroxide mineralization on microbial extracellular polysaccharides Citation Details In-Document Search Title: Iron oxyhydroxide mineralization on...

  12. Mineral industries of Australia, Canada, and Oceania (including a discussion of Antarctica's mineral resources). Mineral perspective

    SciTech Connect (OSTI)

    Kimbell, C.L.; Lyday, T.Q.; Newman, H.H.

    1985-12-01

    The Bureau of Mines report gives the mineral industry highlights of two of the world's major mineral producing countries, Australia and Canada, and seven Pacific island nations or territories--Fiji, New Caledonia, New Zealand, Papua New Guinea, Republic of Nauru, Solomon Islands, and Vanuatu. The mineral resources of Antarctica are also discussed. Because of the size of the Australian and Canadian mineral industries, summary reviews are presented for each of the States, Provinces, or Territories. The most current information available from all nations is given on major minerals or mineral-commodity production, share of world production, and reserves. Reported also are significant mining companies, locations and capacities of their main facilities, and their share of domestic production. Other information is provided on mineral-related trade with the United States, government mineral policy, energy production-consumption and trade, the mining industry labor force, and prospects for the mineral industry. Maps show the locations of selected mineral deposits, oilfields and gasfields, mines, and processing facilities including iron and steel plants, nonferrous smelters and refineries, and cement plants, as well as infrastructure pertinent to the mineral industry.

  13. Minerals Yearbook: Minerals in the world economy. 1988 International review

    SciTech Connect (OSTI)

    Kimbell, C.L.; Zajac, W.L.

    1988-01-01

    In overview, 1988 appeared to be the best year for the world's mineral industry since 1980, although the all-important petroleum component suffered severely from low prices. With this notable exception, the traditional statistical measures of mineral industry performance, namely production, trade, and consumption, reflected growth in most elements of the world mineral industry from crude material extraction through the gamut of downstream processing. Moreover, the growth was reasonably well distributed geographically, with many countries sharing in the substantial upturn in activity. The report discusses production, trade, consumption, investment, transportation, prices, and statistical summary of world production and trade of major mineral commodities.

  14. CeCap LLP | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoopButte County,Camilla,Thermal Gradient Holes Jump to:MiddleCayucos, California:CeCap

  15. Linac Coherent Light SourCe

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on DeliciousMathematicsEnergyInterested Parties - WAPA PublicLED ADOPTIONtoLighting SystemLinac Coherent Light SourCe

  16. Universal ripper miner

    DOE Patents [OSTI]

    Morrell, Roger J. (Bloomington, MN); Larson, David A. (Minneapolis, MN)

    1991-01-01

    A universal ripper miner used to cut, collect and transfer material from an underground mine working face includes a cutter head that is vertically movable in an arcuate cutting cycle by means of drive members, such as hydraulically actuated pistons. The cutter head may support a circular cutter bit having a circular cutting edge that may be indexed to incrementally expose a fresh cutting edge. An automatic indexing system is disclosed wherein indexing occurs by means of a worm gear and indexing lever mechanism. The invention also contemplates a bi-directional bit holder enabling cutting to occur in both the upstroke and the downstroke cutting cycle. Another feature of the invention discloses multiple bits arranged in an in-line, radially staggered pattern, or a side-by-side pattern to increase the mining capacity in each cutting cycle. An on-board resharpening system is also disclosed for resharpening the cutting edge at the end of cutting stroke position. The aforementioned improvement features may be used either singly, or in any proposed combination with each other.

  17. Mineral dissolution kinetics at the pore scale

    E-Print Network [OSTI]

    Li, L.; Steefel, C.I.; Yang, L.

    2008-01-01

    Weathering Rates of Silicate Minerals , Vol. 31 (ed. A. F.as a result of secondary mineral precipitation and approachWeathering Rates of Silicate Minerals , Vol. 31, pp. 565-

  18. Informations et rservations : ce.pv-holidays.com

    E-Print Network [OSTI]

    Arleo, Angelo

    Informations et réservations : ce.pv-holidays.com * Offre valable pour tout séjour de 7 nuits détails sur ce.pv-holidays.com. Offre valable sur l'hébergement seul (hors frais de dossier, prestations cumulable avec votre remise partenaire, toute offre promotionnelle ou réductions. PV-CPDistribution, Société

  19. Dr. T.P. Clement CE 3010 class notes

    E-Print Network [OSTI]

    Clement, Prabhakar

    1 Dr. T.P. Clement CE 3010 class notes Quotes · Genius is 1 percent inspiration and 99 percent in little things. Excellence is not an exception, it is a prevailing attitude Colin Powell 1 Dr. T.P · Combining conditions · Loops · Examples 2 Dr. T.P. Clement CE 3010 class notes Program to Find Real Roots

  20. Approved Module Information for CE2110, 2014/5 Module Title/Name: Process Laboratory Module Code: CE2110

    E-Print Network [OSTI]

    Neirotti, Juan Pablo

    Approved Module Information for CE2110, 2014/5 Module Title/Name: Process Laboratory Module Code: CE2110 School: Engineering and Applied Science Module Type: Standard Module New Module? No Module Credits: 10 Module Management Information Module Leader Name John Brammer Email Address brammejg

  1. Approved Module Information for CE4018, 2014/5 Module Title/Name: Advanced Particle Processing Module Code: CE4018

    E-Print Network [OSTI]

    Neirotti, Juan Pablo

    Approved Module Information for CE4018, 2014/5 Module Title/Name: Advanced Particle Processing Module Code: CE4018 School: Engineering and Applied Science Module Type: Standard Module New Module? No Module Credits: 10 Module Management Information Module Leader Name Mark Leaper Email Address m

  2. Approved Module Information for CE3013, 2014/5 Module Title/Name: Particle Processing Module Code: CE3013

    E-Print Network [OSTI]

    Neirotti, Juan Pablo

    Approved Module Information for CE3013, 2014/5 Module Title/Name: Particle Processing Module Code: CE3013 School: Engineering and Applied Science Module Type: Standard Module New Module? No Module Credits: 10 Module Management Information Module Leader Name Mark Leaper Email Address m

  3. Approved Module Information for CE3102, 2014/5 Module Title/Name: Reaction Engineering Module Code: CE3102

    E-Print Network [OSTI]

    Neirotti, Juan Pablo

    Approved Module Information for CE3102, 2014/5 Module Title/Name: Reaction Engineering Module Code: CE3102 School: Engineering and Applied Science Module Type: Standard Module New Module? No Module Credits: 10 Module Management Information Module Leader Name Feroz Kabir Email Address kabirf

  4. Approved Module Information for CE3112, 2014/5 Module Title/Name: Nanomaterials Module Code: CE3112

    E-Print Network [OSTI]

    Neirotti, Juan Pablo

    Approved Module Information for CE3112, 2014/5 Module Title/Name: Nanomaterials Module Code: CE3112 School: Engineering and Applied Science Module Type: Standard Module New Module? No Module Credits: 10 Module Management Information Module Leader Name Qingchun Yuan Email Address q.yuan@aston.ac.uk Telephone

  5. Approved Module Information for CE1002, 2014/5 Module Title/Name: Design and Build Module Code: CE1002

    E-Print Network [OSTI]

    Neirotti, Juan Pablo

    Approved Module Information for CE1002, 2014/5 Module Title/Name: Design and Build Module Code: CE1002 School: Engineering and Applied Science Module Type: Standard Module New Module? No Module Credits: 10 Module Management Information Module Leader Name Paul Andrew Tack Email Address tackpa

  6. Minerals in the world economy. Minerals yearbook Volume 3. 1991 international review

    SciTech Connect (OSTI)

    Kimbell, C.L.

    1991-12-31

    This edition of the Minerals Yearbook - International Review records the performance of the worldwide minerals industry during 1991 and provides background information to assist in interpreting that performance. Volume III, International Review, contains the latest available mineral data on more than 150 foreign countries and discusses the importance of minerals to the economies of these nations. The 1991 review is presented as five area reports and one world overview: Mineral Industries of Africa, Mineral Industries of Asia and the Pacific, Mineral Industries of Latin America and Canada, Mineral Industries of Europe and the U.S.S.R., Mineral Industries of the Middle East, and Minerals in the World Economy.

  7. Proactive Design of n-Type (In, Ce) Filled Skutterudites Enabling...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    n-Type (In, Ce) Filled Skutterudites Enabling High-Temperature Waste Heat Recovery Thermoelectric and structural properties of n-type (In, Ce) filled skutterudites including power...

  8. Iron oxyhydroxide mineralization on microbial extracellular polysaccharides

    E-Print Network [OSTI]

    Iron oxyhydroxide mineralization on microbial extracellular polysaccharides Clara S. Chan a oxidation and create polymers that localize mineral precipitation. In order to classify the microbial polymers that influence FeOOH miner- alogy, we studied the organic and mineral components of biominerals

  9. Ca2+-Doped CeBr3 Scintillating Materials

    SciTech Connect (OSTI)

    Guss, Paul; Foster, Michael E.; Wong, Bryan M.; Doty, F. Patrick; Shah, Kanai; Squillante, Michael R.; Shirwadkar, Urmila; Hawrami, Rastgo; Tower, Josh; Yuan, Ding

    2014-01-21

    Despite the outstanding scintillation performance characteristics of cerium tribromide (CeBr3) and cerium-activated lanthanum tribromide, their commercial availability and application are limited due to the difficulties of growing large, crack-free single crystals from these fragile materials. This investigation employed aliovalent doping to increase crystal strength while maintaining the optical properties of the crystal. One divalent dopant (Ca2+) was used as a dopant to strengthen CeBr3 without negatively impacting scintillation performance. Ingots containing nominal concentrations of 1.9% of the Ca2+ dopant were grown. Preliminary scintillation measurements are presented for this aliovalently doped scintillator. Ca2+-doped CeBr3 exhibited little or no change in the peak fluorescence emission for 371 nm optical excitation for CeBr3. The structural, electronic, and optical properties of CeBr3 crystals were studied using the density functional theory within the generalized gradient approximation. The calculated lattice parameters are in good agreement with the experimental data. The energy band structures and density of states were obtained. The optical properties of CeBr3, including the dielectric function, were calculated.

  10. Effects of CeO2 Support Facets on VOx/CeO2 Catalysts in Oxidative Dehydrogenation of Methanol

    SciTech Connect (OSTI)

    Li, Yan; Wei, Zhehao; Gao, Feng; Kovarik, Libor; Peden, Charles HF; Wang, Yong

    2014-05-13

    CeO2 supports with dominating facets, i.e., low index (100), (110) and (111) facets, are prepared. The facet effects on the structure and catalytic performance of supported vanadium oxide catalysts are investigated using oxidative dehydrogenation of methanol as a model reaction. In the presence of mixed facets, Infrared and Raman characterizations demonstrate that surface vanadia species preferentially deposit on CeO2 (100) facets, presumably because of its higher surface energy. At the same surface vanadium densities, VOx species on (100) facets show better dispersion, followed by (110) and (111) facets. The VOx species on CeO2 nanorods with (110) and (100) facets display higher activity and lower apparent activation energies compared to that on CeO2 nanopolyhedras with dominating (111) facets and CeO2 nanocubes with dominating (100) facets. The higher activity for VOx/CeO2(110) might be related to the more abundant oxygen vacancies present on the (110) facets, evidenced from Raman spectroscopic measurements.

  11. Mineral Supplementation of Beef Cows in Texas 

    E-Print Network [OSTI]

    Herd, Dennis B.

    1997-06-04

    Nutrient balance is the key to any effective nutrition program, especially where trace minerals are concerned. Many factors cannot be optimized when mineral intake is not properly balanced. Recommendations are given for the producer....

  12. Mineral Selection for Multicomponent Equilibrium Geothermometry

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Plamer, C. D.; Ohly, S. R.; Smith, R. W.; Neupane, G.; McLing, T.; Mattson, E.

    2015-04-01

    Muliticomponent geothermometry requires knowledge of the mineral phases in the reservoir with which the geothermal fluids may be equilibrated.

  13. Institute for Mineral and Energy Resources

    E-Print Network [OSTI]

    Institute for Mineral and Energy Resources #12;IMER VISION IMER's vision is to enable the efficient and sustainable use and development of the world's mineral and energy resources for the benefit of society, discovery and extraction of mineral and energy resources, including petroleum and geothermal resources

  14. Mineral minimization in nature's alternative teeth

    E-Print Network [OSTI]

    Zok, Frank

    REVIEW Mineral minimization in nature's alternative teeth Christopher C. Broomell1, , Rashda K, University of California, Santa Barbara, CA 93106, USA Contrary to conventional wisdom, mineralization, with little to no help from mineralization. Based on biochemical analyses, three of these mouthparts, the jaws

  15. Review of 1989 international mineral industry activities

    SciTech Connect (OSTI)

    Kimbell, C.L. (US Bureau of Mines, Washington, DC (US))

    1990-07-01

    This article reviews global mineral industry activities for 1989. Production of coal, natural gas, and petroleum, as well as non-fuel minerals, is detailed regionally and for individual countries. The problems of changes in technology, economic and political systems are discussed where they have affected mineral production.

  16. Mineral bridges in nacre revisited

    E-Print Network [OSTI]

    Antonio G. Checa; Julyan H. E. Cartwright; Marc-Georg Willinger

    2012-07-20

    We confirm with high-resolution techniques the existence of mineral bridges between superposed nacre tablets. In the towered nacre of both gastropods and the cephalopod Nautilus there are large bridges aligned along the tower axes, corresponding to gaps (150-200 nm) in the interlamellar membranes. Gaps are produced by the interaction of the nascent tablets with a surface membrane that covers the nacre compartment. In the terraced nacre of bivalves bridges associated with elongated gaps in the interlamellar membrane (> 100 nm) have mainly been found at or close to the edges of superposed parental tablets. To explain this placement, we hypothesize that the interlamellar membrane breaks due to differences in osmotic pressure across it when the interlamellar space below becomes reduced at an advanced stage of calcification. In no cases are the minor connections between superimposed tablets (mineral bridges, found to be such.

  17. A List of Kansas Minerals

    E-Print Network [OSTI]

    Grover, Charles H.

    1895-01-01

    Master Th e s i s Geology Grov e r , C h a r l e s H. 1895 L i s t of Kansas m i n e r a l s * A l i s t of Kansas Minerals with "brief notes on the^cr^stjalogr&phio (form, chemical composition, and the p r i n c i p a l l o c a l i t i e s f...£om which £hey have been reported* ^S/V-y The f o l l o w i n g l i s t , i t i s believed, embraces a l l the minerals of the state that have been so f a r discovered and reported. Two s i m i l a r i i s t s have been heretofore published i n...

  18. D:\\352\\2014\\MineralHandbooks.LST.wpd EPSc 352: Handbooks for Mineral Identification

    E-Print Network [OSTI]

    D:\\352\\2014\\MineralHandbooks.LST.wpd EPSc 352: Handbooks for Mineral Identification Best books preceded by **. Arem, Joel. 1991. Rocks and Minerals. Phoenix: Geoscience Press, Inc. ISBN #0-945005-06-7 Bishop, A.C.; Wolley, A.R.; and Hamilton, W.R. 1999. Cambridge Guide to Minerals, Rocks, and Fossils

  19. Homoleptic Ce(III) and Ce(IV) Nitroxide Complexes: Significant Stabilization of the 4+ Oxidation State

    SciTech Connect (OSTI)

    Bogart, Justin A.; Lewis, Andrew J.; Medling, Scott A.; Piro, Nicholas A.; Carroll, Patrick J.; Booth, Corwin H.; Schelter, Eric J.

    2014-06-25

    Electrochemical experiments performed on the complex Ce-IV[2-((BuNO)-Bu-t)py](4), where [2-((BuNO)-Bu-t)py](-) = N-tert-butyl-N-2-pyridylnitroxide, indicate a 2.51 V stabilization of the 4+ oxidation state of Ce compared to [(Bu4N)-Bu-n](2)[Ce(NO3)(6)] in acetonitrile and a 2.95 V stabilization compared to the standard potential for the ion under aqueous conditions. Density functional theory calculations suggest that this preference for the higher oxidation state is a result of the tetrakis(nitroxide) ligand framework at the Ce cation, which allows for effective electron donation into, and partial covalent overlap with, vacant 4f orbitals with delta symmetry. The results speak to the behavior of CeO2 and related solid solutions in oxygen uptake and transport applications, in particular an inherent local character of bonding that stabilizes the 4+ oxidation state. The results indicate a cerium(IV) complex that has been stabilized to an unprecedented degree through tuning of its ligand-field environment.

  20. Mineralization of Carbon Dioxide: Literature Review

    SciTech Connect (OSTI)

    Romanov, V; Soong, Y; Carney, C; Rush, G; Nielsen, B; O'Connor, W

    2015-01-01

    CCS research has been focused on CO2 storage in geologic formations, with many potential risks. An alternative to conventional geologic storage is carbon mineralization, where CO2 is reacted with metal cations to form carbonate minerals. Mineralization methods can be broadly divided into two categories: in situ and ex situ. In situ mineralization, or mineral trapping, is a component of underground geologic sequestration, in which a portion of the injected CO2 reacts with alkaline rock present in the target formation to form solid carbonate species. In ex situ mineralization, the carbonation reaction occurs above ground, within a separate reactor or industrial process. This literature review is meant to provide an update on the current status of research on CO2 mineralization. 2

  1. Mineral Scavenger Hunt 1. CONTRIBUTOR'S NAME: Johnny MacLean

    E-Print Network [OSTI]

    Brewer, Carol

    Mineral Scavenger Hunt 1. CONTRIBUTOR'S NAME: Johnny MacLean 2. NAME OF INQUIRY: Mineral Scavenger from minerals? What are some objects in the classroom that come from minerals? What minerals did these objects come from? b. Ecological Theme(s): Minerals are the building blocks of rocks. Rocks

  2. The San Francisco Consortium CT Host, CE Home

    E-Print Network [OSTI]

    Ovchinnikov, Sergei

    The San Francisco Consortium CT Host, CE Home me l r Student: Complete Sections 1 through 5. Print Campus Campus California College of Podiatric Medicine City College of San Francisco Cogswell College Golden Gate University Tuition Required Hastings College of the Law San Francisco State University

  3. CE 4990 -Construction Scheduling Integrating Cost and Schedule

    E-Print Network [OSTI]

    Mukherjee, Amlan

    CE 4990 - Construction Scheduling Integrating Cost and Schedule March 16, 2012 Definitions The goal) = BCWP/BCWS · Cost Variance (CV) = BCWP - ACWP · Cost Performance Index (CPI) = BCWP/ACWP · EAC = ACWP is to develop integrated metrics for measuring cost and schedule performance. This note provides guidelines

  4. Improved performance of QCD code on ALiCE

    E-Print Network [OSTI]

    Sroczynski, Z

    2003-01-01

    We present results for the performance of QCD code on ALiCE, the Alpha-Linux Cluster Engine at Wuppertal. We describe the techniques employed to optimise the code, including the metaprogramming of assembler kernels, the effects of data layout and an investigation into the overheads incurred by the communication.

  5. EnTRAnCE AWARDS AGBIO Renewable Entrance

    E-Print Network [OSTI]

    Peak, Derek

    EnTRAnCE AWARDS AGBIO Renewable Entrance Scholarships Benjamin Dietrich, Moosomin Logan Pizzey Megan Hodges, Dalmeny COnTInUInG STUDEnT AWARDS AGBIO Renewable Entrance Scholarships, Second Year Tracy Smith, Radisson AGBIO Renewable Entrance Scholarships, Third Year Melanie Hawrysh, Borden Kathryn Stolle

  6. Progressive Multiple Biosequence Alignments on the ALiCE Grid

    E-Print Network [OSTI]

    Teo, Yong-Meng

    to high-end computational capabilities [10]. The pioneer grid efforts spun off as experimental attemptsProgressive Multiple Biosequence Alignments on the ALiCE Grid Yong-Meng TEO1,2 , Yew-Kwong NG1 problem that has semi-regular computational pattern. Grid-enabled PMSA is implemented using our Java

  7. In this Issue CeBiTec Symposium: Molecular Biotechnology

    E-Print Network [OSTI]

    Moeller, Ralf

    of tools and techniques for transcriptome sequencing 3rd CeBiTec Students Academy Synthetic Biology and Bielefeld presented insights into cutting edge developments of Molecular Biotechnology. This regional focus compounds to biological halogenation, enzyme coatings and chemical protein labelling. One session

  8. Mineral Resource Information System for Field Lab in the Osage Mineral Reservation Estate

    SciTech Connect (OSTI)

    Carroll, H.B.; Johnson, William I.

    1999-04-27

    The Osage Mineral Reservation Estate is located in Osage County, Oklahoma. Minerals on the Estate are owned by members of the Osage Tribe who are shareholders in the Estate. The Estate is administered by the Osage Agency, Branch of Minerals, operated by the U.S. Bureau of Indian Affairs (BIA). Oil, natural gas, casinghead gas, and other minerals (sand, gravel, limestone, and dolomite) are exploited by lessors. Operators may obtain from the Branch of Minerals and the Osage Mineral Estate Tribal Council leases to explore and exploit oil, gas, oil and gas, and other minerals on the Estate. Operators pay a royalty on all minerals exploited and sold from the Estate. A mineral Resource Information system was developed for this project to evaluate the remaining hydrocarbon resources located on the Estate. Databases on Microsoft Excel spreadsheets of operators, leases, and production were designed for use in conjunction with an evaluation spreadsheet for estimating the remaining hydrocarbons on the Estate.

  9. The suburban villa (munya) and court culture in Umayyad Cordoba (756-976 CE)

    E-Print Network [OSTI]

    Anderson, Glaire D

    2005-01-01

    As the capital of the Umayyad dynasty (r. 756 CE-1031 CE), the city of Cordoba developed into one of the most renowned urban centers of the western Mediterranean. The Great Mosque of Cordoba is the outstanding testament ...

  10. Strata control in mineral engineering

    SciTech Connect (OSTI)

    Bieniawski, Z.T.

    1986-01-01

    This book covers the state-of-the-art of strata control practice both in the United States and abroad with respect to strata reinforcement by rock bolting, long wall mining technology and innovations in energy development, such as mining for oil and tunneling for storage of high-level nuclear waste in deep underground repositories. It features coverage of design concepts in rock engineering and rockbolt systems, stability of rock pillars, rockbursts, shaft design and construction and a detailed consideration of mineral and energy needs in the United States.

  11. Neutron scattering of CeNi at the SNS-ORNL: A preliminary report

    SciTech Connect (OSTI)

    Mirmelstein, A. [Russian Federal Nuclear Center VNIITF, Snezhinsk, Russia; Podlesnyak, Andrey A [ORNL; Kolesnikov, Alexander I [ORNL; Saporov, B. [Oak Ridge National Laboratory (ORNL); Sefat, A.S. [Oak Ridge National Laboratory (ORNL); Tobin, J. G. [Lawrence Livermore National Laboratory (LLNL)

    2014-01-01

    This is a preliminary report of a neutron scattering experiment used to investigate 4f electron behavior in Ce.

  12. CO Oxidation at the Interface between Doped CeO2 and Supported Au Nanoclusters

    E-Print Network [OSTI]

    Henkelman, Graeme

    nanoclusters (NCs) supported on either CeO2 or doped (X-Ce)O2 (X = Au, Pt, Pd, Ti, Ru, Zr) show that dopingCO Oxidation at the Interface between Doped CeO2 and Supported Au Nanoclusters Hyun You Kim, we study the e ect of doping on CO oxidation catalyzed by CeO2-supported Au13 NCs and, especially, CO

  13. Module Information for CE3104, 2015/6 -APPROVED Module Title/Name: Process & Pollution Control Module Code: CE3104

    E-Print Network [OSTI]

    Rebollo-Neira, Laura

    - characteristics, variation with source, treatment principles, discharge to sewers and watercourses - Air PollutionModule Information for CE3104, 2015/6 - APPROVED Module Title/Name: Process & Pollution Control on piping and instrumentation diagrams (P&ID). Indicative Module Content: Pollution Prevention and Control

  14. Comparative studies of low-temperature watergas shift reaction over Pt=CeO2, Au=CeO2,

    E-Print Network [OSTI]

    Gulari, Erdogan

    , has shown that ceria affects in a number of catalytic reactions. Cerium oxide or Ceria (CeO2) may attention re- cently because of their catalytic activity in low temperature CO oxidation, catalytic; accepted 13 March 2003 Abstract We studied catalytic low-temperature water­gas shift (WGS) reaction over

  15. Approved Module Information for CE4503, 2014/5 Module Title/Name: Advanced Process Design Module Code: CE4503

    E-Print Network [OSTI]

    Neirotti, Juan Pablo

    Code: CE4503 School: Engineering and Applied Science Module Type: Standard Module New Module? No Module available: BEng/MEng Chemical Engineering. Available to Exchange Students? Not Specified Module Dependancies. The Design Problem is intended to test the students ability to apply the principles of Chemical Engineering

  16. Approved Module Information for CE2105, 2014/5 Module Title/Name: Process Simulation Module Code: CE2105

    E-Print Network [OSTI]

    Neirotti, Juan Pablo

    : CE2105 School: Engineering and Applied Science Module Type: Standard Module New Module? No Module processes with solids * Coal drying * Coal combustion Module Delivery Methods of Delivery & Learning Hours weighting (including approaches to formative assessment as well as summative): Assessment Type Category

  17. Approved Module Information for CE3104, 2014/5 Module Title/Name: Process & Pollution Control Module Code: CE3104

    E-Print Network [OSTI]

    Neirotti, Juan Pablo

    , treatment principles, discharge to sewers and watercourses * Air Pollution - effects of pollutants, typesApproved Module Information for CE3104, 2014/5 Module Title/Name: Process & Pollution Control - Understand how a chemical process is controlled safely and efficiently Pollution Control #12;* The impact

  18. Short communication Chemically abrupt interface between Ce oxide and Fe films

    E-Print Network [OSTI]

    Kim, Sehun

    of an Fe film followed by deposition of Ce metal. Once a Ce oxide layer is formed on top of Fe, it acts.90.+f; 74.25.jb; 79.60 Ài; 79.60.Dp Keywords: MTJ; Ce oxide layer; XPS Magnetic tunneling junctions (MTJ of the oxide layer, resulting in decreased tunneling magneto- resistance and fluctuations in the local

  19. Interface Induced Carbonate Mineralization: A Fundamental Geochemical...

    Office of Scientific and Technical Information (OSTI)

    Geochemical Process Relevant to Carbon Sequestration We have approached the long-standing geochemical question why anhydrous high-Mg carbonate minerals (i.e., magnesite and...

  20. Interface Induced Carbonate Mineralization: A Fundamental Geochemical

    Office of Scientific and Technical Information (OSTI)

    Interface Induced Carbonate Mineralization: A Fundamental Geochemical Process Relevant to Carbon Sequestration Teng, H. Henry PI, The George Washington University PI, The George...

  1. system, the origin of silicate minerals around stars, and mixing in circumstellar disks. The mineral

    E-Print Network [OSTI]

    system, the origin of silicate minerals around stars, and mixing in circumstellar disks. The mineral grains and components that we have seen in the comet are analogous to glacial erratics in the center of the solar nebula, and many of the larger particles are rocks composed of several minerals

  2. CliniCal anesthesia ConferenCe 2015

    E-Print Network [OSTI]

    Thompson, Michael

    Can-am CliniCal anesthesia ConferenCe 2015 T H I r T Y - T H I r D a n n u a l Conference 2015 Please FaX, Mail or e-Mail: CMe aDMinistRatOR Continuing Health Sciences education mcmaster conferences: yes no www.twitter.com/mcmaster_chse http://ca.linkedin.com/pub/mcmaster-continuing- health

  3. PQL: Order (2013-CE-27001) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy Bills andOrder 422.1, CONDUCT P - . . - - 4PORTSFUTUREOrder (2013-CE-27001)

  4. LG: Order (2015-CE-14022) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURING OFFICE INDUSTRIALU.S. DepartmentJeanKeyLANLLG: Order (2015-CE-14022) LG: Order

  5. Haier: Order (2011-CE-2104) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12,ExecutiveFinancing Programs |ReferencePowerHaier: Order (2011-CE-2104) Haier:

  6. New Mexico Bureau Mines and Mineral

    E-Print Network [OSTI]

    Dunbar, Nelia W.

    Number22 - 1999 New Mexico Bureau of Mines and Mineral Resources a division of Nei~, Mexico Tech forsandblasting five times! ThisIssue Earth Briefs-Better age estimates on some New Mexico volcanic rocks Have You) NewMexico's Most Wanted Minera Is (pageT) Magnification of microscopic miner- als and glass (page 8

  7. Spectroscopic Identification of Carbonate Minerals in the

    E-Print Network [OSTI]

    Bandfield, Joshua L.

    local climatic conditions in the martian past suitable for sustaining life. Carbonate minerals have­10). Researchers used the Viking labeled re- lease experiment to limit the concentration of carbonates presentSpectroscopic Identification of Carbonate Minerals in the Martian Dust Joshua L. Bandfield

  8. Approved Module Information for CE1102, 2014/5 Module Title/Name: Organic Chemistry for Engineers Module Code: CE1102

    E-Print Network [OSTI]

    Neirotti, Juan Pablo

    Approved Module Information for CE1102, 2014/5 Module Title/Name: Organic Chemistry for Engineers Module Code: CE1102 School: Engineering and Applied Science Module Type: Standard Module New Module chemistry. Part 2: Introduction to Laboratory Skills To enable the student to develop good practical skills

  9. Approved Module Information for CE4014, 2014/5 Module Title/Name: Advanced Reaction Engineering II Module Code: CE4014

    E-Print Network [OSTI]

    Neirotti, Juan Pablo

    Approved Module Information for CE4014, 2014/5 Module Title/Name: Advanced Reaction Engineering II Module Code: CE4014 School: Engineering and Applied Science Module Type: Standard Module New Module? No Module Credits: 10 Module Management Information Module Leader Name Feroz Kabir Email Address kabirf

  10. Lab 2: Mineral Lab notes. Minerals are inorganic, solid, naturally occurring substances that have a characteristic chemical compositions,

    E-Print Network [OSTI]

    Li, X. Rong

    Lab 2: Mineral Lab notes. Minerals are inorganic, solid, naturally occurring substances that have composition is the chemical elements that make up any given mineral. For instance, the mineral quartz is silicon dioxide SiO2; the mineral galena is an ore of lead, and its chemical formula is PbS, a lead

  11. Mineral Deposit Research Unit The University of British Columbia

    E-Print Network [OSTI]

    Michelson, David G.

    1 Mineral Deposit Research Unit The University of British Columbia Earth Sciences Building metallogenic constraints on mineralization in poorly understood or exposed portions of Yukon and Alaska. The mineral deposit studies, models, and metallogenic frameworks developed in this project

  12. The impact of mineral fertilizers on the carbon footprint of crop production

    E-Print Network [OSTI]

    Brentrup, Frank

    2009-01-01

    hence yield. The use of mineral fertilizer as a source ofsustainable agriculture. Mineral fertilizers are applied toresidues are decomposed to minerals Soil Figure 1: Mineral

  13. Mineral Selection for Multicomponent Equilibrium Geothermometry

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Plamer, C. D.; Ohly, S. R.; Smith, R. W.; Neupane, G.; McLing, T.; Mattson, E.

    2015-04-01

    Multicomponent geothermometry requires knowledge of the mineral phases in the reservoir with which the geothermal fluids may be equilibrated. These minerals phases are most often alteration products rather than primary minerals. We have reviewed the literature on geothermal systems representing most major geologic environments typically associated with geothermal activity and identified potential alteration products in various environments. We have included this information in RTEst, a code we have developed to estimate reservoir conditions (temperature, CO2 fugacity) from the geochemistry of near-surface geothermal waters. The information has been included in RTEst through the addition of filters that decrease the potential numbermore »of minerals from all possibilities based on the basis species to those that are more relevant to the particular conditions in which the user is interested. The three groups of filters include host rock type (tholeiitic, calc-alkaline, silicic, siliciclastic, carbonate), water type (acidic, neutral), and the temperature range over which the alteration minerals were formed (low, medium, high). The user-chosen mineral assemblage is checked to make sure that it does not violate the Gibbs phase rule. The user can select one of three mineral saturation weighting schemes that decrease the chance the optimization from being skewed by reaction stoichiometry or analytical uncertainty.« less

  14. Process for the physical segregation of minerals

    DOE Patents [OSTI]

    Yingling, Jon C.; Ganguli, Rajive

    2004-01-06

    With highly heterogeneous groups or streams of minerals, physical segregation using online quality measurements is an economically important first stage of the mineral beneficiation process. Segregation enables high quality fractions of the stream to bypass processing, such as cleaning operations, thereby reducing the associated costs and avoiding the yield losses inherent in any downstream separation process. The present invention includes various methods for reliably segregating a mineral stream into at least one fraction meeting desired quality specifications while at the same time maximizing yield of that fraction.

  15. LOW TEMPERATURE GEOTHERMAL MINERAL RECOVERY PROGRAM 02/11/2014...

    Broader source: Energy.gov (indexed) [DOE]

    mineral-webinar.pdf More Documents & Publications LOW TEMPERATURE GEOTHERMAL MINERAL RECOVERY PROGRAM Geothermal Play Fairway Analysis Geothermal Play Fairway Analysis...

  16. Astoria Mineral Hot Springs Pool & Spa Low Temperature Geothermal...

    Open Energy Info (EERE)

    Astoria Mineral Hot Springs Pool & Spa Low Temperature Geothermal Facility Jump to: navigation, search Name Astoria Mineral Hot Springs Pool & Spa Low Temperature Geothermal...

  17. ITP Mining: Mining Industry of the Future Mineral Processing...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of the Future Mineral Processing Technology Roadmap ITP Mining: Mining Industry of the Future Mineral Processing Technology Roadmap mptroadmap.pdf More Documents & Publications ITP...

  18. H. R. S. 182 - Reservation and Disposition of Government Mineral...

    Open Energy Info (EERE)

    Mineral Rights (2012). Retrieved from "http:en.openei.orgwindex.php?titleH.R.S.182-ReservationandDispositionofGovernmentMineralRights&oldid801574" ...

  19. DOE - Office of Legacy Management -- International Minerals and...

    Office of Legacy Management (LM)

    International Minerals and Chemical Corp - Pilot Plant - FL 02 FUSRAP Considered Sites Site: International Minerals and Chemical Corp - Pilot Plant (FL.02) Designated Name: Not...

  20. California Ethanol Power CE P | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar Energy LLC JumpBiossenceBrunswick,Calendar Home > CommunityHelp toPower CE

  1. Goodman Manufacturing: Order (2012-CE-1509) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12,Executive CompensationEnergyGet Current:5 Department of2-CE-1509) Goodman

  2. Sustainable growth and valuation of mineral reserves

    E-Print Network [OSTI]

    Adelman, Morris Albert

    1994-01-01

    The annual change in the value of an in-ground mineral is equal to the increase or decrease of inventories ("reserves"), multiplied by the market value of a reserve unit. The limited shrinking resource base does not exist. ...

  3. Engineered yeast for enhanced CO2 mineralization

    E-Print Network [OSTI]

    Barbero, Roberto Juan

    2013-01-01

    In this work, a biologically catalysed CO2 mineralization process for the capture of CO2 from point sources was designed, constructed at a laboratory scale, and, using standard chemical process scale-up protocols, was ...

  4. The influence of nano-architectured CeOx supports in RhPd/CeO? for the catalytic ethanol steam reforming reaction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Divins, N. J.; Senanayake, S. D.; Casanovas, A.; Xu, W.; Trovarelli, A.; Llorca, J.

    2015-01-19

    The ethanol steam reforming (ESR) reaction has been tested over RhPd supported on polycrystalline ceria in comparison to structured supports composed of nanoshaped CeO? cubes and CeO? rods tailored towards the production of hydrogen. At 650-700 K the hydrogen yield follows the trend RhPd/CeO?-cubes > RhPd/CeO? -rods > RhPd/CeO?- polycrystalline, whereas at temperatures higher than 800 K the catalytic performance of all samples is similar and close to the thermodynamic equilibrium. The improved performance of RhPd/CeO?-cubes and RhPd/CeO? -rods for ESR at low temperature is mainly ascribed to higher water-gas shift activity and a strong interaction between the bimetallic -more »oxide support interaction. STEM analysis shows the existence of RhPd alloyed nanoparticles in all samples, with no apparent relationship between ESR performance and RhPd particle size. X-ray diffraction under operating conditions shows metal reorganization on {100} and {110} ceria crystallographic planes during catalyst activation and ESR, but not on {111} ceria crystallographic planes. The RhPd reconstructing and tuned activation over ceria nanocubes and nanorods is considered the main reason for better catalytic activity with respect to conventional catalysts based on polycrystalline ceria« less

  5. Capillary electrophoresis-fluorescence line narrowing system (CE-FLNS) for on-line structural characterization

    DOE Patents [OSTI]

    Jankowiak, Ryszard J. (Ames, IA); Small, Gerald J. (Ames, IA); Shields, Peter A. (Reading, MA)

    1999-04-27

    Capillary electrophoresis (CE) is interfaced with low temperature fluorescence line-narrowing (FLN) spectroscopy for on-line structural characterization of separated molecular analytes.

  6. Ethanol Steam Reforming on Co/CeO2: The Effect of ZnO Promoter

    SciTech Connect (OSTI)

    Davidson, Stephen; Sun, Junming; Wang, Yong

    2013-12-02

    A series of ZnO promoted Co/CeO2 catalysts were synthesized and characterized using XRD, TEM, H2-TPR, CO chemisorption, O2-TPO, IR-Py, and CO2-TPD. The effects of ZnO on the catalytic performances of Co/CeO2 were studied in ethanol steam reforming. It was found that the addition of ZnO facilitated the oxidation of Co0 via enhanced oxygen mobility of the CeO2 support which decreased the activity of Co/CeO2 in C–C bond cleavage of ethanol. 3 wt% ZnO promoted Co/CeO2 exhibited minimum CO and CH4 selectivity and maximum CO2 selectivity. This resulted from the combined effects of the following factors with increasing ZnO loading: (1) enhanced oxygen mobility of CeO2 facilitated the oxidation of CHx and CO to form CO2; (2) increased ZnO coverage on CeO2 surface reduced the interaction between CHx/CO and Co/CeO2; and (3) suppressed CO adsorption on Co0 reduced CO oxidation rate to form CO2. In addition, the addition of ZnO also modified the surface acidity and basicity of CeO2, which consequently affected the C2–C4 product distributions.

  7. Neutron Scattering of CeNi at the Spallation Neutron Source at...

    Office of Scientific and Technical Information (OSTI)

    Spallation Neutron Source at Oak Ridge National Laboratory: A Preliminary Report Citation Details In-Document Search Title: Neutron Scattering of CeNi at the Spallation Neutron...

  8. Capillary electrophoresis-fluorescence line narrowing system (CE-FLNS) for on-line structural characterization

    DOE Patents [OSTI]

    Jankowiak, R.J.; Small, G.J.; Shields, P.A.

    1999-04-27

    Capillary electrophoresis (CE) is interfaced with low temperature fluorescence line-narrowing (FLN) spectroscopy for on-line structural characterization of separated molecular analytes. 21 figs.

  9. EST-CE QU'ON VOlT ATRAVERS UN MICROSCOPE? '

    E-Print Network [OSTI]

    Aubin, David

    'aimable autonsatJon de1auteur etde Blackwell Publishing. EST-CE QU'ON VOlT ATRAVERS UN MICROSCOPE? 239 Les

  10. Thermal Variation of Ce Valence in Mixed Valence–Kondo Lattice Systems CeT2(Si1-xGex)2 with T= Mn and Ni

    SciTech Connect (OSTI)

    Liang,G.; Croft, M.

    2008-01-01

    The results on the thermal variation of Ce L3-valence in CeT2(Si1-xGex)2 series with 0{le}x{le}1 and T=Mn and Ni are reported. It is observed that for both series, the Ce valence increases with decreasing temperature and has little thermal variation for samples in the nearly trivalent regime. The magnitude of this thermal variation in the T=Mn series is much greater than in the T=Ni series. The results are explained by the degenerate Anderson model and correlated with the specific heat data.

  11. Magnetic minerals produced by magnetotactic bacteria Balzs Arat1

    E-Print Network [OSTI]

    Dunin-Borkowski, Rafal E.

    Magnetic minerals produced by magnetotactic bacteria Balázs Arató1 , Mihály Pósfai1 and Rafal E-controlled mineralization Abstract. Magnetotactic bacteria produce intracellular magnetic minerals that have distinct for studying the biological membrane around the mineral grains. Our goals were to deduce the possible growth

  12. MINER{nu}A Test Beam Commissioning

    SciTech Connect (OSTI)

    Higuera, A.; Castorena, J.; Urrutia, Z.; Felix, J.; Zavala, G.

    2009-12-17

    MINER{nu}A Main INjector ExpeRiment {nu}-A is a high-statistic neutrino scattering experiment that will ran in the NuMI Beam Hall at Fermilab. To calibrate the energy response of the MINER{nu}A detector, a beamline is being designed for the MINER{nu}A Test Beam Detector (TBD). The TBD is a replica of the full MINER{nu}A detector at small scale for calibration studies of the main detector. The beamline design consists of the following parts: a copper target, used to generate tertiaries from an incoming secondary beam; a steel collimator for tertiaries, which also serves as a dump for the incoming beam; a time of fight system (scintillator planes); four wire chambers, for angle measurements and tracking; and two dipole magnets, used as an spectrometer. During last October, the first commissioning run of the MINER{nu}A Test Beam took place in the Meson Test Beam Facility at Fermilab. We commissioned the target and collimator of the new tertiary beamline.

  13. TraCE -TRANSPORTATION CENTER EPFL 09 Sep 2009 sonia.lavadinho@epfl.ch STRC Ascona

    E-Print Network [OSTI]

    Bierlaire, Michel

    & capillary walking (TUBE & WALK LONDON) #12;TraCE - TRANSPORTATION CENTER EPFL 09 Sep 2009 soniaTraCE - TRANSPORTATION CENTER EPFL 09 Sep 2009 sonia.lavadinho@epfl.ch STRC Ascona 11 Potentials for combining walking and public transport at the agglomeration scale THE MULTIMODAL WALKER #12;Tra

  14. Approved Module Information for CE2106, 2014/5 Module Title/Name: Reaction Kinetics & Equilibrium

    E-Print Network [OSTI]

    Neirotti, Juan Pablo

    Approved Module Information for CE2106, 2014/5 Module Title/Name: Reaction Kinetics & Equilibrium Thermodynamics Module Code: CE2106 School: Engineering and Applied Science Module Type: Standard Module New Module? No Module Credits: 10 Module Management Information Module Leader Name Mark Leaper Email Address

  15. CertifiCAtion of performAnCe indiCAtors ........ 110 Curtin's institutionAl

    E-Print Network [OSTI]

    Mucina, Ladislav

    and performance enhance capacity and financial sustainability l total Research income ($) Ranking Strengthen research capability and performance enhance capacity and financial sustainability m CooperaCertifiCAtion of performAnCe indiCAtors ........ 110 Curtin's institutionAl performAnCe indi

  16. Preparation and properties of ce-doped TiO{sub 2} photocatalyst

    SciTech Connect (OSTI)

    Yan, Ningning; Zhu, Zhongqi; Zhang, Jin [Yunnan Key Laboratory of Nanomaterials and Technology, Yunnan University, Kunming 650091 (China)] [Yunnan Key Laboratory of Nanomaterials and Technology, Yunnan University, Kunming 650091 (China); Zhao, Zongyan [School of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093 (China)] [School of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093 (China); Liu, Qingju, E-mail: qjliu@ynu.edu.cn [Yunnan Key Laboratory of Nanomaterials and Technology, Yunnan University, Kunming 650091 (China)] [Yunnan Key Laboratory of Nanomaterials and Technology, Yunnan University, Kunming 650091 (China)

    2012-08-15

    Highlights: ? The cerium ion doped TiO{sub 2} (Ce-TiO{sub 2}) powders were prepared and characterized. ? The spectrum absorption region of Ce-TiO{sub 2} is red-shifted to visible light. ? The recombination of photo-generated electron-hole pairs of Ce-TiO{sub 2} is inhibited. ? The photocatalytic activity was effected by Ce ion content and greatly improved. -- Abstract: TiO{sub 2} nanoparticles doped with different content of Ce ion were prepared by sol–gel method. The samples were characterized by XRD, XPS, TEM, UV–Vis, and PL, the photocatalytic activity was evaluated by photocatalytic degradation of methylene blue (MB) under the irradiation of fluorescent lamp. The results indicate that Ce ion is incorporated into the lattice of TiO{sub 2}, which can restrain the increase of grain size, broaden the absorption region to visible light, and inhibit the recombination of the photo-generated electron and hole pairs. Moreover, the photocatalytic activity of Ce-TiO{sub 2} in MB degradation is evidently enhanced. The MB degradation rate of the sample with Ce:Ti = 0.33% (molar ratio) in 8 h is 90.03%, which is much higher than that of P25 (68.19%).

  17. Ternary ceramic alloys of Zr-Ce-Hf oxides

    DOE Patents [OSTI]

    Becher, P.F.; Funkenbusch, E.F.

    1990-11-20

    A ternary ceramic alloy is described which produces toughening of zirconia and zirconia composites through the stress transformation from tetragonal phase to monoclinic phase. This alloy, having the general formula Ce[sub x]Hf[sub y]Zr[sub 1[minus]x[minus]y]O[sub 2], is produced through the addition of appropriate amounts of ceria and hafnia to the zirconia. Typically, improved toughness is achieved with about 5 to about 15 mol % ceria and up to about 40 mol % hafnia. The preparation of alloys of these compositions are given together with data as to the densities, tetragonal phase content, hardness and fracture toughness. The alloys are useful in preparing zirconia bodies as well as reinforcing ceramic composites. 1 fig.

  18. Ternary ceramic alloys of ZR-CE-HF oxides

    DOE Patents [OSTI]

    Becher, Paul F. (Oak Ridge, TN); Funkenbusch, Eric F. (White Bear Lake, MN)

    1990-01-01

    A ternary ceramic alloy which produces toughening of zirconia and zirconia composites through the stress transformation from tetragonal phase to monoclinic phase. This alloy, having the general formula Ce.sub.x Hf.sub.y Zn.sub.1-x-y O.sub.2, is produced through the addition of appropriate amounts of ceria and hafnia to the zirconia. Typically, improved toughness is achieved with about 5 to about 15 mol % ceria and up to about 40 mol % hafnia. The preparation of alloys of these compositions are given together with data as to the densities, tetragonal phase content, hardness and fracture toughness. The alloys are useful in preparing zirconia bodies as well as reinforcing ceramic composites.

  19. Inelastic magnetic neutron scattering in CePd{sub 3}.

    SciTech Connect (OSTI)

    Lawrence, J. M.; Fanelli, V. R.; Goremychkin, E. A.; Osborn, R.; Bauer, E. D.; McClellan, K. J.; Christianson, A. D.; Univ. of California at Irvine; LANL; ORNL

    2008-01-01

    We have performed time-of-flight neutron scattering measurements on a single crystal of the intermediate valence compound CePd{sub 3}. At 10 K, a Kondo-esque inelastic magnetic scattering peak occurs near {Delta}E = 60 meV with maximum intensity for momentum transfer Q near the (1/2, 1/2, 0) zone boundary. Spectral weight is transferred to lower energy as Q varies until at zone center the intensity at 60 meV is considerably weaker. These results are in qualitative accord with predictions of the Anderson lattice. The Q-dependence may resolve an older controversy concerning the low-temperature scattering. We discuss the relationship of these results to our recent results in YbAl{sub 3}.

  20. Injury experience in metallic mineral mining, 1992

    SciTech Connect (OSTI)

    Not Available

    1994-05-01

    This Mine Safety and Health Administration (MSHA) informational report reviews in detail the occupational injury and illness experience of metallic mineral mining in the United States for 1992. Data reported by operators of mining establishments concerning work injuries are summarized by work location, accident classification, part of body injured, nature of injury, occupation, and principal type of mineral. Related information on employment, worktime, and operating activity also is presented. Data reported by independent contractors performing certain work at mining locations are depicted separately in this report. For ease of comparison with other metal and nonmetallic mineral mining industries and with coal mining, summary reference tabulations are included at the end of both the operator and the contractor sections of this report.

  1. Fergusonite-type CeNbO{sub 4+?}: Single crystal growth, symmetry revision and conductivity

    SciTech Connect (OSTI)

    Bayliss, Ryan D. [Department of Materials, Imperial College London, Prince Consort Road, London, SW7 2BP (United Kingdom); Pramana, Stevin S.; An, Tao; Wei, Fengxia; Kloc, Christian L. [School of Materials Science and Engineering, 50 Nanyang Avenue, Nanyang Technological University, 639798 (Singapore); White, Andrew J.P. [Chemical Crystallography Laboratory, Department of Chemistry, Imperial College London, Exhibition Road, London, SW7 2AZ (United Kingdom); Skinner, Stephen J. [Department of Materials, Imperial College London, Prince Consort Road, London, SW7 2BP (United Kingdom); White, Timothy J. [School of Materials Science and Engineering, 50 Nanyang Avenue, Nanyang Technological University, 639798 (Singapore); Baikie, Tom, E-mail: tbaikie@ntu.edu.sg [School of Materials Science and Engineering, 50 Nanyang Avenue, Nanyang Technological University, 639798 (Singapore)

    2013-08-15

    Large fergusonite-type (ABO{sub 4}, A=Ce, B=Nb) oxide crystals, a prototype electrolyte composition for solid oxide fuel cells (SOFC), were prepared for the first time in a floating zone mirror furnace under air or argon atmospheres. While CeNbO{sub 4} grown in air contained CeNbO{sub 4.08} as a minor impurity that compromised structural analysis, the argon atmosphere yielded a single phase crystal of monoclinic CeNbO{sub 4}, as confirmed by selected area electron diffraction, powder and single crystal X-ray diffraction. The structure was determined in the standard space group setting C12/c1 (No. 15), rather than the commonly adopted I12/a1. AC impedance spectroscopy conducted under argon found that stoichiometric CeNbO{sub 4} single crystals showed lower conductivity compared to CeNbO{sub 4+?} confirming interstitial oxygen can penetrate through fergusonite and is responsible for the higher conductivity associated with these oxides. - Graphical abstract: Large fergusonite-type CeNbO{sub 4} crystals were prepared for the first time in a floating zone mirror furnace. Crystal growth in an argon atmosphere yielded a single phase monoclinic CeNbO4, as confirmed by selected area electron diffraction, powder and single crystal X-ray diffraction. The structure was determined in the standard space group setting C12/c1 (No. 15), rather than the commonly adopted I12/a1. AC impedance spectroscopy found CeNbO{sub 4} single crystals showed lower conductivity compared to CeNbO{sub 4+?} confirming interstitial oxygen can penetrate through fergusonite and is responsible for the higher conductivity associated with these oxides. Highlights: • Preparation of single crystals of CeNbO{sub 4} using a floating zone mirror furnace. • Correction to the crystal symmetry of the monoclinic form of CeNbO{sub 4}. • Report the conductivity of a single crystal of CeNbO{sub 4}.

  2. Curtin university of teChnology annual report 2011 107 PerForMAnCe indiCAtors

    E-Print Network [OSTI]

    Mucina, Ladislav

    research capability and performance Enhance capacity and financial sustainability l Total Research IncomeCurtin university of teChnology annual report 2011 107 PerForMAnCe indiCAtors CertifiCation of performanCe inDiCators.......................... 108 Curtin's institutional performanCe in

  3. Goldschmidt Conference Abstracts 2005 Mineral Surface Reactivity

    E-Print Network [OSTI]

    Sparks, Donald L.

    Goldschmidt Conference Abstracts 2005 Mineral Surface Reactivity A492 "Hydration" of rhyolitic of Tennessee, Knoxville, Tennessee 37996, USA 2 Chemical Sciences Division, MS 6110, P.O. Box 2008, Bldg. 4500S, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831-6110, USA 3 Chemical Sciences Division, MS

  4. Minerals Processing Research Institute Louisiana State University

    E-Print Network [OSTI]

    Pike, Ralph W.

    Biomass Feedstocks into Chemical Production Complexes using New and Existing Processes by Ralph W. Pike, Director Debalina Sengupta Graduate Research Assistant Minerals Processing Research Institute 1139 Energy Coast and Environment Building Louisiana State University Baton Rouge, LA 70803 and Thomas A. Hertwig

  5. Earth Minerals Did you read chapter 29

    E-Print Network [OSTI]

    Hart, Gus

    1 Chapter 29 Earth Minerals Did you read chapter 29 before coming to class? A. Yes B. No Lets play that begins in Hawaii Other "Hot Spots" around the world The interior structure of Earth has been determined outer core #12;2 What is different on earth (as opposed to other planets)? Continents Why does

  6. Ce-MXRF: the power of separation with bench top element sensitive detection

    SciTech Connect (OSTI)

    Miller, T. C. (Thomasin C.); Joseph, M. R. (Martha R.); Havrilla, G. J. (George J.)

    2002-01-01

    Capillary electrophoresis (CE) is a proven separation technique that offers highly efficient separation, rapid analysis, and minute sample consumption. When combined with a element specific detection scheme, it can be used for chemical speciation of biologically and environmentally relevant species such as metal containing proteins. In this study, a new tool was developed for separation and elemental detection. Specifically, a simple CE apparatus was constructed using a thin-walled fused Si capillary and interfaced with a bench top micro x-ray fluorescence (MXRF) system. X-ray excitation and detection of the separated sample volumes was performed using an EDAX Eagle II micro x-ray fluorescence system equipped with a Rh target excitation source and a SiLi detector. It was demonstrated that the system could be used for the separation and detection of two metals from one another, specifically Cu{sup 2+} and Co{sup 2+}. Free Co{sup 2+} could also be isolated from Co{sup 2+} bound to cyanocobalamin (Vitamin B-12). Other systems that were explored were the separation of two organics, ferritin from cyanocobalamin as well as the separation of the different Cu and Zn isoforms of metallothinein. CE-MXRF was also used to separate the important serum isoforms of transferrin. Direct comparisons were made between CE-MXRF system and other elemental separation techniques such as CE-PIXE, CE-synchrotron-XRF, and CE-ICPMS.

  7. Hydrothermal growth and morphology evolution of CePO{sub 4} aggregates by a complexing method

    SciTech Connect (OSTI)

    Ma Lin [Department of Chemistry, Zhejiang University, Hangzhou 310027 (China); Chen Weixiang [Department of Chemistry, Zhejiang University, Hangzhou 310027 (China)], E-mail: weixiangchen@css.zju.edu.cn; Zheng Yifan [Institute of Industrial Catalysis, Zhejiang University of Technology, Hangzhou 310014 (China); Xu Zhude [Department of Chemistry, Zhejiang University, Hangzhou 310027 (China)

    2008-11-03

    A facile hydrothermal route assisted by Na{sub 2}H{sub 2}EDTA (ethylenediaminetetraacetic acid disodium) has been successfully developed to prepare uniform cerium phosphate (CePO{sub 4}) aggregates with different morphologies, such as peanut-like and spindle-like. It was found that the as-prepared uniform CePO{sub 4} aggregates were constructed with many nearly parallel aligned nanorods. The molar ratio of EDTA/Ce{sup 3+}, solution pH and reaction time had great influences on the morphologies and sizes of the CePO{sub 4} samples. In our process of synthesis, Na{sub 2}H{sub 2}EDTA played important roles as complexing reagent and inducing agent on the formation of CePO{sub 4} aggregates. The possible growth mechanism for CePO{sub 4} aggregates was presented. Ce{sub 0.9}Tb{sub 0.1}PO{sub 4} aggregates with different morphologies were also prepared and their photoluminescence properties were characterized.

  8. Studies on Ca2+-Doped CeBr3 Scintillating Materials

    SciTech Connect (OSTI)

    Guss, P. [NSTec; Foster, M. E. [SNL; Wong, B. M. [SNL; Doty, F. P. [SNL; Shah, K. [RMD; Squillante, M. [RMD; Glodo, J. [RMD; Yuan, D. [NSTec

    2013-07-03

    Despite the outstanding scintillation performance characteristics of cerium tribromide (CeBr3) and cerium-activated lanthanum tribromide (LaBr3:Ce), their commercial availability and application is limited due to the difficulties of growing large, crack-free single crystals from these fragile materials. The objective of this investigation was to employ aliovalent doping to increase crystal strength while maintaining the optical properties of the crystal. One divalent dopant (Ca2+) was investigated as a dopant to strengthen CeBr3 without negatively impacting scintillation performance. Ingots containing nominal concentrations of 1.9% of the Ca2+ dopant were grown. Preliminary scintillation measurements are presented for this aliovalently doped scintillator. Ca2+-doped CeBr3 exhibited little or no change in the peak fluorescence emission for 371 nm optical excitation for CeBr3. The structural, electronic, and optical properties of CeBr3 crystals were investigated using the density functional theory within generalized gradient approximation. The calculated lattice parameters are in good agreement with the experimental data. The energy band structures and density of states were obtained. The optical properties of CeBr3, including the dielectric function, were calculated.

  9. Report on "Methodologies for Investigating Microbial-Mineral Interactions: A Clay Minerals Society Short Course"

    SciTech Connect (OSTI)

    Patricia A. Maurice

    2010-02-08

    A workshop entitled, “Methods of Investigating Microbial-Mineral Interactions,” was held at the Clay Minerals Society meeting at the Pacific Northwest National Laboratory in Richland, WA on June 19, 2004. The workshop was organized by Patricia A. Maurice (University of Notre Dame) and Lesley A. Warren (McMaster University, CA). Speakers included: Dr. P. Bennett, Dr. J. Fredrickson (PNNL), Dr. S. Lower (Ohio State University), Dr. P. Maurice, Dr. S. Myneni (Princeton University), Dr. E. Shock (Arizona State), Dr. M. Tien (Penn State), Dr. L. Warren, and Dr. J. Zachara (PNNL). There were approximately 75 attendees at the workshop, including more than 20 students. A workshop volume was published by the Clay Minerals Society [Methods for Study of Microbe-Mineral Interactions (2006), CMS Workshop Lectures, vol. 14?(Patricia A. Maurice and Leslie A. Warren, eds.) ISBN 978-1-881208-15-0, 166 pp.

  10. 2.20 Properties of Rocks and Minerals -Magnetic Properties of Rocks and Minerals

    E-Print Network [OSTI]

    Dunin-Borkowski, Rafal E.

    Scale Exchange Interactions and Magnetic Structure in Fe-Bearing Oxides Atomistic Simulations2.20 Properties of Rocks and Minerals - Magnetic Properties of Rocks and Minerals R. J. Harrison, R.20.5.1.3 2.20.5.2 2.20.5.2.1 2.20.5.2.2 2.20.5.2.3 2.20.5.2.4 Introduction Magnetism at the Atomic Length

  11. Magnitude of the magnetic exchange interaction in the heavy-fermion antiferromagnet CeRhIn?

    SciTech Connect (OSTI)

    Das, Pinaki [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Lin, S. -Z. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Ghimire, N.? J. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Huang, K. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Univ. of California, San Diego, La Jolla, CA (United States); Ronning, F. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Bauer, E.? D. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Thompson, J.? D. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Batista, C.? D. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Ehlers, G. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Janoschek, M. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

    2014-12-01

    We have used high-resolution neutron spectroscopy experiments to determine the complete spin wave spectrum of the heavy-fermion antiferromagnet CeRhIn?. The spin wave dispersion can be quantitatively reproduced with a simple frustrated J??J? model that also naturally explains the magnetic spin-spiral ground state of CeRhIn? and yields a dominant in-plane nearest-neighbor magnetic exchange constant J?=0.74(3)??meV. Our results pave the way to a quantitative understanding of the rich low-temperature phase diagram of the prominent CeTIn? (T = Co, Rh, Ir) class of heavy-fermion materials.

  12. Molecular Characterization of Bacterial Respiration on Minerals

    SciTech Connect (OSTI)

    Blake, Robert C.

    2013-04-26

    The overall aim of this project was to contribute to our fundamental understanding of proteins and biological processes under extreme environmental conditions. We sought to define the biochemical and physiological mechanisms that underlie biodegradative and other cellular processes in normal, extreme, and engineered environments. Toward that end, we sought to understand the substrate oxidation pathways, the electron transport mechanisms, and the modes of energy conservation employed during respiration by bacteria on soluble iron and insoluble sulfide minerals. In accordance with these general aims, the specific aims were two-fold: To identify, separate, and characterize the extracellular biomolecules necessary for aerobic respiration on iron under strongly acidic conditions; and to elucidate the molecular principles whereby these bacteria recognize and adhere to their insoluble mineral substrates under harsh environmental conditions. The results of these studies were described in a total of nineteen manuscripts. Highlights include the following: 1. The complete genome of Acidithiobacillus ferrooxidans ATCC 23270 (type strain) was sequenced in collaboration with the DOE Joint Genome Institute; 2. Genomic and mass spectrometry-based proteomic methods were used to evaluate gene expression and in situ microbial activity in a low-complexity natural acid mine drainage microbial biofilm community. This was the first effort to successfully analyze a natural community using these techniques; 3. Detailed functional and structural studies were conducted on rusticyanin, an acid-stable electron transfer protein purified from cell-free extracts of At. ferrooxidans. The three-dimensional structure of reduced rusticyanin was determined from a combination of homonuclear proton and heteronuclear 15N- and 13C-edited NMR spectra. Concomitantly, the three-dimensional structure of oxidized rusticyanin was determined by X-ray crystallography to a resolution of 1.9 A by multiwavelength anomalous dispersion (MAD) phasing; 4. An acid-stable red cytochrome with a novel absorbance peak at 579 nm was purified from cell-free extracts of L. ferriphilum. Functional studies demonstrated that this cytochrome was an important component of the aerobic iron respiratory chain in this organism; 5. The specific adhesion of At. ferrooxidans to pyrite is mediated by an extracellular protein that was identified as aporusticyanin. The adhesion of At. ferrooxidans to minerals was characterized by high affinity binding that exhibited a high specificity for pyrite over other sulfide minerals. The principal biopolymer involved in this high-affinity adhesion to pyrite was isolated by mineral affinity chromatography and identified as aporusticyanin. The adhesion of purified aporusticyanin to minerals was observed to adhere to different mineral with a pattern of reactivity identical to that observed with the intact bacterium. Further, preincubation of pyrite with excess exogenous aporusticyanin served to inhibit the adherence of intact cells to the surface of the mineral, indicating that the protein and the cells adhered to the pyrite in a mutually exclusive manner. Taken together, these observations support a model where aporusticyanin located on the surface of the bacterial cell acts as a mineral-specific receptor for the initial adherence of At. ferrooxidans to solid pyrite; 6. The specific adhesion of L. ferriphilum to pyrite was mediated by a different acid-stable extracellular protein than aporusticyanin; and 7. A prototype integrating cavity absorption meter (ICAM) was assembled to determine whether this novel spectrophotometer could be used to study cellular respiration in situ.

  13. Geochemical and Petrological Investigations into Mantle Minerals from Experiments and Natural Samples

    E-Print Network [OSTI]

    Macris, Catherine Amy

    2012-01-01

    A. Schauble (2010) Inter-mineral Iron Isotope Fractionationand E. Tonui (2008) Inter-mineral Iron Isotope Fractionation+ (aq) with carbonate minerals. Geochimica et Cosmochimica

  14. Mineral balances, including in drinking water, estimated for Merced County dairy herds

    E-Print Network [OSTI]

    Castillo, Alejandro R Dr.; Santos, Jose Eduardo P.; Tabone, Tom J.

    2007-01-01

    et al. (1994). TABLE 3. Estimates of daily mineral intake,drinking-water mineral contributionand net mineral excretion in lactating cows on Merced County

  15. Yield and Mineral Element Concentration of Beetroot in Response to Nutrient Source in Hydroponic Solution

    E-Print Network [OSTI]

    Egilla, Jonathan N.

    2009-01-01

    analysis as a guide for mineral nutrition of sugar beets.SEM. x Sufficiency range of mineral elements determined fromon the yield, and tissue mineral element concentration of

  16. Mineral transformation and biomass accumulation associated with uranium bioremediation at Rifle, Colorado

    E-Print Network [OSTI]

    Li, L.

    2009-01-01

    iron(III) oxyhydroxides: effects of mineral solubility andMineral Transformation and Biomass Accumulation Associatedthe accumulation of new mineral phases and biomass. Word

  17. Bone mineral density and fractures in older men with chronic obstructive pulmonary disease or asthma

    E-Print Network [OSTI]

    Dam, T.-T.; Harrison, S.; Fink, H. A.; Ramsdell, J.; Barrett-Connor, E.

    2010-01-01

    x ORIGINAL ARTICLE Bone mineral density and fractures inwas associated with lower bone mineral density (BMD) at theKeywords Bone loss . Bone mineral density . Elderly .

  18. Pressure Calibration by the Infrared Absorption Spectrum of Mineral Oil

    E-Print Network [OSTI]

    Collins, Gary S.

    Pressure Calibration by the Infrared Absorption Spectrum of Mineral Oil H. Child, Kenyon College effect is seen in the infrared absorption spectrum of mineral oil. The frequency of two peaks increases as pressure is applied to the mineral oil. At a pressure of about 1 kbar (100 MPa), both peaks are distinct

  19. State of Oregon Department of Geology and Mineral Industries

    E-Print Network [OSTI]

    Goldfinger, Chris

    State of Oregon Department of Geology and Mineral Industries Vicki S. McConnell, State Geologist A ND M INERALINDUSTRIES 1937 2009 1 Oregon Department of Geology and Mineral Industries, Coastal Field Department of Geology and Mineral Industries Special Paper 41 Published in conformance with ORS 516

  20. Direct imaging of nanoscale magnetic interactions in minerals

    E-Print Network [OSTI]

    Dunin-Borkowski, Rafal E.

    Direct imaging of nanoscale magnetic interactions in minerals Richard J. Harrison*, Rafal E. Dunin. Magnetite is the most strongly magnetic mineral in nature. Small particles of magnetite in single-domain (SD and pseudo-SD particles (1). In most igneous rocks, the grain size of primary magnetic minerals exceeds

  1. FAT-miner: Mining Frequent Attribute Trees Jeroen De Knijf

    E-Print Network [OSTI]

    Utrecht, Universiteit

    FAT-miner: Mining Frequent Attribute Trees Jeroen De Knijf Department of Information and Computing Sciences, Utrecht University Technical Report UU-CS-2006-053 www.cs.uu.nl ISSN: 0924-3275 #12;FAT-miner is neglected. We present FAT-miner, an algorithm for frequent pattern discovery in tree structured data

  2. ORIGINAL ARTICLE FGF and ERK signaling coordinately regulate mineralization-

    E-Print Network [OSTI]

    ORIGINAL ARTICLE FGF and ERK signaling coordinately regulate mineralization- related genes and play for Bone and Mineral Research and Springer 2011 Abstract To examine the roles of FGF and ERK MAPK signaling-Y4. This experiment identified a number of miner- alization-related genes that were regulated by FGF2

  3. Errors-in-variables problems in transient electromagnetic mineral exploration

    E-Print Network [OSTI]

    Braslavsky, Julio H.

    Errors-in-variables problems in transient electromagnetic mineral exploration K. Lau, J. H in transient electromagnetic mineral exploration. A specific sub-problem of interest in this area geological surveys, dia- mond drilling, and airborne mineral exploration. Our interest here is with ground

  4. Mineral formation during simulated leaks of Hanford waste tanks

    E-Print Network [OSTI]

    Flury, Markus

    Mineral formation during simulated leaks of Hanford waste tanks Youjun Deng a , James B. Harsh a at the US DOE Hanford Site, Washington, caus- ing mineral dissolution and re-precipitation upon contact with subsurface sediments. The main mineral precipitation and transformation pathways were studied in solutions

  5. LUNAR MINERALS James Papike, Lawrence Taylor, and Steven Simon

    E-Print Network [OSTI]

    Rathbun, Julie A.

    LUNAR MINERALS James Papike, Lawrence Taylor, and Steven Simon The lunar rocks described--make it easy to distinguish them from terrestrial rocks. However, the minerals that make up lunar rocks are (with a few notable exceptions) minerals that are also found on Earth. Both lunar and terrestrial rocks

  6. Mineralization by Inhibitor Exclusion THE CALCIFICATION OF COLLAGEN WITH FETUINS

    E-Print Network [OSTI]

    Price, Paul A.

    Mineralization by Inhibitor Exclusion THE CALCIFICATION OF COLLAGEN WITH FETUINS Received is to understand the mechanisms that deposit mineral within collagen fibrils, and as a first step we recentlyDa protein are excluded. Based on these observations, we proposed a novel mechanism for fibril mineralization

  7. Carbon Mineralization and Labile Organic Carbon Pools in the Sandy

    E-Print Network [OSTI]

    Grunwald, Sabine

    Carbon Mineralization and Labile Organic Carbon Pools in the Sandy Soils of a North Florida mineralization were best explained by TOC (62%) and hot-water- extractable C (59%), whereas acid-hydrolyzable C mineralization and clay content were directly linearly correlated, indicating a possible stimulatory effect

  8. Thermal infrared emission spectroscopy of the pyroxene mineral series

    E-Print Network [OSTI]

    Hamilton, Victoria E.

    Thermal infrared emission spectroscopy of the pyroxene mineral series Victoria E. Hamilton within the two structural groups, as well as minerals within solid solution series. The exact number of reststrahlen features observed and their positions are dependent on mineral structure and cation occupancy

  9. 5th Annual Data Miner Survey 2011 Survey Summary Report

    E-Print Network [OSTI]

    Morik, Katharina

    5th Annual Data Miner Survey ­ 2011 Survey Summary Report ­ Rexer Analytics For more information Outline · Overview & Key Findings · Where & How Data Miners Work · Data Mining Tools: Usage & Satisfaction Overview & Key Findings #12;© 2012 Rexer Analytics 4 2011 Data Miner Survey: Overview 40% 27% 18% Corporate

  10. The Link between Clay Mineral Weathering and the Stabilization of

    E-Print Network [OSTI]

    Sparks, Donald L.

    The Link between Clay Mineral Weathering and the Stabilization of Ni Surface Precipitates R O B E R 19717 The formation of transition-metal surface precipitates may occur during sorption to clay minerals formation are poorly understood. We monitored changes in the reversibility of Ni sorbed to a clay mineral

  11. An Overview of KING FAHD UNIVERSITY OF PETROLEUM & MINERALS

    E-Print Network [OSTI]

    Almulhem, Ahmad

    An Overview of KING FAHD UNIVERSITY OF PETROLEUM & MINERALS KFUPM An Overview of KING FAHD UNIVERSITY OF PETROLEUM & MINERALS KFUPM #12;Topics Background and Campus Graduate Studies Research ... Then and Now College of Petroleum and Minerals, 1963 KFUPM now... · A college · 2-year technical college · 76

  12. KING FAHD UNIVERSITY OF PETROLEUM & MINERALS DEANSHIP OF GRADUATE STUDIES

    E-Print Network [OSTI]

    Almulhem, Ahmad

    KING FAHD UNIVERSITY OF PETROLEUM & MINERALS DEANSHIP OF GRADUATE STUDIES Online Academic Services Services for Graduate Students. #12;King Fahd University of Petroleum & Minerals Deanship of Graduate ................................................................................................... 7 #12;King Fahd University of Petroleum & Minerals Deanship of Graduate Studies 1 | P a g e Academic

  13. KING FAHD UNIVERSITY OF PETROLEUM & MINERALS DEANSHIP OF GRADUATE STUDIES

    E-Print Network [OSTI]

    Almulhem, Ahmad

    KING FAHD UNIVERSITY OF PETROLEUM & MINERALS DEANSHIP OF GRADUATE STUDIES Online Academic Services Coordinators. #12;King Fahd University of Petroleum & Minerals Deanship of Graduate Studies i | P a g e .................................................................................................................... 19 #12;King Fahd University of Petroleum & Minerals Deanship of Graduate Studies 1 | P a g e Graduate

  14. MIXTURES OF FINE-GRAINED MINERALS KAOLINITE AND CARBONATE GRAINS

    E-Print Network [OSTI]

    Palomino, Angelica M.

    MIXTURES OF FINE-GRAINED MINERALS À KAOLINITE AND CARBONATE GRAINS ANGELICA M. PALOMINO 1, *, SUSAN, Georgia 30332-0355, USA Abstract--The behavior of mineral mixtures can be significantly different from properties of the individual minerals, and their ensuing effects on interparticle interactions and fabric

  15. Phosphorus K-edge XANES Spectroscopy of Mineral Standards

    SciTech Connect (OSTI)

    E Ingall; J Brandes; J Diaz; M de Jonge; D Paterson; I McNulty; C Elliott; P Northrup

    2011-12-31

    Phosphorus K-edge X-ray absorption near-edge structure (XANES) spectroscopy was performed on phosphate mineral specimens including (a) twelve specimens from the apatite group covering a range of compositional variation and crystallinity; (b) six non-apatite calcium-rich phosphate minerals; (c) 15 aluminium-rich phosphate minerals; (d) ten phosphate minerals rich in either reduced iron or manganese; (e) four phosphate minerals rich in either oxidized iron or manganese; (f) eight phosphate minerals rich in either magnesium, copper, lead, zinc or rare-earth elements; and (g) four uranium phosphate minerals. The identity of all minerals examined in this study was independently confirmed using X-ray powder diffraction. Minerals were distinguished using XANES spectra with a combination of pre-edge features, edge position, peak shapes and post-edge features. Shared spectral features were observed in minerals with compositions dominated by the same specific cation. Analyses of apatite-group minerals indicate that XANES spectral patterns are not strongly affected by variations in composition and crystallinity typical of natural mineral specimens.

  16. Carbon Sequestration via Mineral Carbonation: Overview and Assessment

    E-Print Network [OSTI]

    1 Carbon Sequestration via Mineral Carbonation: Overview and Assessment 14 March 2002 Howard Herzog overview and assessment of carbon sequestration by mineral carbonation (referred to as "mineral sequestration R&D. The first is that carbonates have a lower energy state than CO2. Therefore, at least

  17. Lattice instabilities in heavy fermion superconductors. [CeCu/sub 2/Si/sub 2/; CeAl/sub 3/; CeCu/sub 6/; UBe/sub 13/; UPt/sub 3/

    SciTech Connect (OSTI)

    Wohlleben, D.

    1987-01-01

    This paper shows that while in nonsuperconducting HF systems such as CeCu/sub 6/, CeAl/sub 3/ and stoichiometric CeCu/sub 2/Si/sub 2/, the large electronic ..gamma.. is due to a very narrow f band, in the three HF superconductors UBe/sub 13/, UPt/sub 3/ and nonstochiometric CeCu/sub 2/Si/sub 2/, it is not. The f band of these systems, as measured by their response to magnetic fields in three different ways, is much wider than suggested by the large ..gamma... According to their actual f band width, the HF superconductors belong into the Bantam Fermion class. It is argued that most of the large ..gamma.. of the HF superconductors is not of electronic origin and that it is instead caused by the precursor of a martensitic phase transition of the lattice or by a crystallographic phase mixture, i.e., that it is due to the displacive degrees of freedom. This suggests that the superconductivity of all three HF superconductors is caused by some special, low energy phonons rather than by a narrow f band. 52 refs., 4 figs., 3 tabs.

  18. Unconventional behavior of the Ce3Pt23Si11 ferromagnet C. Opagiste,1,

    E-Print Network [OSTI]

    Boyer, Edmond

    23Si11 is in equilibrium with the non-centrosymetric heavy fermion superconductor CePt3Si, when and presents a heavy fermion supercon- ducting state at Tc = 750 mK. Many studies on the superconductivity

  19. Life Cycle Analysis of the Production of Aviation Fuels Using the CE-CERT Process

    E-Print Network [OSTI]

    Hu, Sangran

    2012-01-01

    energy crop cultivation 16 . The second and third generation biofuels have much better potential as aviation fuelenergy, a CBTL process with CE-CERT process combined is expected to be of great potential in Fischer-Tropsch synthetic aviation fuel

  20. LIMITATIONS ON THE RESOLUTION OF YAG:CE BEAM PROFILE MONITOR...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    performance to other diagnostics. 2 Experimental Set-up And Initial Results An aluminum-base target was constructed with the two YAG:Ce crystals (0.50 mm and 0.25 mm thick...

  1. Pressure-Induced Structural Phase Transition in CeNi: X-ray and...

    Office of Scientific and Technical Information (OSTI)

    Pressure-Induced Structural Phase Transition in CeNi: X-ray and Neutron Scattering Studies and First-Principles Calculations Citation Details In-Document Search This content will...

  2. Structure and magnetic properties of Ce?(Ni/Al/Ga)??-A...

    Office of Scientific and Technical Information (OSTI)

    Ce(NiAlGa)-A new phase with the LaAl structure type Janka, Oliver Univ. of California, Davis, CA (United States); Westfalische Wilhelms-Universitat, Munster...

  3. A comparison of the structure and localized magnetism in Ce{sub 2}PdGa{sub 12} with the heavy fermion CePdGa{sub 6}

    SciTech Connect (OSTI)

    Macaluso, Robin T. [Department of Chemistry, Louisiana State University, Baton Rouge, LA 70803 (United States); Millican, Jasmine N. [Department of Chemistry, Louisiana State University, Baton Rouge, LA 70803 (United States); Nakatsuji, Satoru [Department of Physics, Kyoto University, Kyoto, Japan 606-8502 (Japan); Lee, Han-Oh [Department of Physics, University of California, Davis, CA 95616 (United States); Carter, B. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Moreno, Nelson O. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Fisk, Zachary [Department of Physics, University of California, Davis, CA 95616 (United States); Chan, Julia Y. [Department of Chemistry, Louisiana State University, Baton Rouge, LA 70803 (United States)]. E-mail: jchan@lsu.edu

    2005-11-15

    Single crystals of Ce{sub 2}PdGa{sub 12} have been synthesized in Ga flux and characterized by X-ray diffraction. This compound crystallizes in the tetragonal P4/nbm space group, Z=2 with lattice parameters of a=6.1040(2)A and c=15.5490(6)A. It shows strongly anisotropic magnetism and orders antiferromagnetically at T{sub N}{approx}11K. A field-induced metamagnetic transition to the ferromagnetic state is observed below T{sub N}. Structure-property relationships with the related heavy-fermion antiferromagnet CePdGa{sub 6} are discussed.

  4. IEED Energy and Mineral Development Grants

    Broader source: Energy.gov [DOE]

    The Secretary of the Interior, through the Office of lndian Energy and Economic Development (IEED), is soliciting grant proposals from federally recognized Indian tribes and tribal energy resource development organizations for projects that assess, evaluate, or otherwise promote the processing, use, or development of energy and mineral resources on Indian lands. Grant awards are subject to the availability of funds as appropriated by Congress and allotted to IEED.

  5. Results for aliovalent doping of CeBr{sub 3} with Ca{sup 2+}

    SciTech Connect (OSTI)

    Guss, Paul; Foster, Michael E.; Wong, Bryan M.; Patrick Doty, F.; Shah, Kanai; Squillante, Michael R.; Shirwadkar, Urmila; Hawrami, Rastgo; Tower, Joshua; Yuan, Ding

    2014-01-21

    Despite the outstanding scintillation performance characteristics of cerium tribromide (CeBr{sub 3}) and cerium-activated lanthanum tribromide, their commercial availability and application are limited due to the difficulties of growing large, crack-free single crystals from these fragile materials. This investigation employed aliovalent doping to increase crystal strength while maintaining the optical properties of the crystal. One divalent dopant (Ca{sup 2+}) was used as a dopant to strengthen CeBr{sub 3} without negatively impacting scintillation performance. Ingots containing nominal concentrations of 1.9% of the Ca{sup 2+} dopant were grown, i.e., 1.9% of the CeBr{sub 3} molecules were replaced by CaBr{sub 2} molecules, to match our target replacement of 1 out of 54 cerium atoms be replaced by a calcium atom. Precisely the mixture was composed of 2.26 g of CaBr{sub 2} added to 222.14 g of CeBr{sub 3}. Preliminary scintillation measurements are presented for this aliovalently doped scintillator. Ca{sup 2+}-doped CeBr{sub 3} exhibited little or no change in the peak fluorescence emission for 371?nm optical excitation for CeBr{sub 3}. The structural, electronic, and optical properties of CeBr{sub 3} crystals were studied using the density functional theory within the generalized gradient approximation. Calculated lattice parameters are in agreement with the experimental data. The energy band structures and density of states were obtained. The optical properties of CeBr{sub 3}, including the dielectric function, were calculated.

  6. This article was downloaded by:[King Fahd University of Petroleum and Minerals] [King Fahd University of Petroleum and Minerals

    E-Print Network [OSTI]

    Al-Qahtani, Hussain M.

    This article was downloaded by:[King Fahd University of Petroleum and Minerals] [King Fahd University of Petroleum and Minerals] On: 20 May 2007 Access Details: [subscription number 777447308. © Taylor and Francis 2007 #12;DownloadedBy:[KingFahdUniversityofPetroleumandMinerals]At:14:1620May2007

  7. Structure and scintillation yield of Ce-doped Al–Ga substituted yttrium garnet

    SciTech Connect (OSTI)

    Sidletskiy, Oleg; Kononets, Valerii; Lebbou, Kheirreddine; Neicheva, Svetlana; Voloshina, Olesya; Bondar, Valerii; Baumer, Vyacheslav; Belikov, Konstantin; Gektin, Alexander; Grinyov, Boris; Joubert, Marie-France

    2012-11-15

    Highlights: ? Range of Y{sub 3}(Al{sub 1?x}Ga{sub x}){sub 5}O{sub 12}:Ce solid solution crystals are grown from melt by the Czochralski method. ? Light yield of mixed crystals reaches 130% of the YAG:Ce value at x ? 0.4. ? ?1% of antisite defects is formed in YGG:Ce, but no evidence of this is obtained for the rest of crystals. -- Abstract: Structure and scintillation yield of Y{sub 3}(Al{sub 1?x}Ga{sub x}){sub 5}O{sub 12}:Ce solid solution crystals are studied. Crystals are grown from melt by the Czochralski method. Distribution of host cations in crystal lattice is determined. Quantity of antisite defects in crystals is evaluated using XRD and atomic emission spectroscopy data. Trend of light output at Al/Ga substitution in Y{sub 3}(Al{sub 1?x}Ga{sub x}){sub 5}O{sub 12}:Ce is determined for the first time. Light output in mixed crystals reaches 130% comparative to Ce-doped yttrium–aluminum garnet. Luminescence properties at Al/Ga substitution are evaluated.

  8. An Update on Improvements to NiCE Support for RELAP-7

    SciTech Connect (OSTI)

    McCaskey, Alex; Wojtowicz, Anna; Deyton, Jordan H.; Patterson, Taylor C.; Billings, Jay Jay

    2015-01-01

    The Multiphysics Object-Oriented Simulation Environment (MOOSE) is a framework that facilitates the development of applications that rely on finite-element analysis to solve a coupled, nonlinear system of partial differential equations. RELAP-7 represents an update to the venerable RELAP-5 simulator that is built upon this framework and attempts to model the balance-of-plant concerns in a full nuclear plant. This report details the continued support and integration of RELAP-7 and the NEAMS Integrated Computational Environment (NiCE). RELAP-7 is fully supported by the NiCE due to on-going work to tightly integrate NiCE with the MOOSE framework, and subsequently the applications built upon it. NiCE development throughout the first quarter of FY15 has focused on improvements, bug fixes, and feature additions to existing MOOSE-based application support. Specifically, this report will focus on improvements to the NiCE MOOSE Model Builder, the MOOSE application job launcher, and the 3D Nuclear Plant Viewer. This report also includes a comprehensive tutorial that guides RELAP-7 users through the basic NiCE workflow: from input generation and 3D Plant modeling, to massively parallel job launch and post-simulation data visualization.

  9. # Application Location Model Used Temperature Water Quality Macrophytes Periphyton Zooplankton Fish Year Project Started 1 Center Hill Lake Tennessee CE-QUAL-W2 X X 1979

    E-Print Network [OSTI]

    Wells, Scott A.

    Reservoir 2 Oregon CE-QUAL-W2 X 1999 11 Upper Bull Run River Oregon CE-QUAL-W2 X 1999 12 Lower Bull Run CE-QUAL-W2 X X 1979 3 Tualatin River Oregon CE-QUAL-W2 X X 1991 4 Hagg Lake Oregon CE-QUAL-W2 X X X CE-QUAL-W2 X X X 1991, 2005 7 Smith and Bybee Lakes Oregon CE-QUAL-W2 X X 1992 8 Klamath River - Lake

  10. Mineral content analysis of atmospheric dust using hyperspectral information from space

    E-Print Network [OSTI]

    Kostinski, Alex

    Mineral content analysis of atmospheric dust using hyperspectral information from space A one of the world's largest sources of atmospheric mineral dust. Mineral composition optical properties, and mineral deposition to Amazon forests. In this study we examine hyperspectral

  11. Approved Module Information for CE1009, 2014/5 Module Title/Name: Introduction to Transfer Processes Module Code: CE1009

    E-Print Network [OSTI]

    Neirotti, Juan Pablo

    the student: * a knowledge of the fundamentals of heat transfer theory, and of the practical applications of conductive heat transfer theory * a knowledge of the fundamentals of fluid mechanics theory * a knowledgeApproved Module Information for CE1009, 2014/5 Module Title/Name: Introduction to Transfer

  12. Approved Module Information for CE1004, 2014/5 Module Title/Name: Process and Product Design Module Code: CE1004

    E-Print Network [OSTI]

    Neirotti, Juan Pablo

    . * Concept of scale * Product innovation - customer needs, ideas generation, ideas selection, productApproved Module Information for CE1004, 2014/5 Module Title/Name: Process and Product Design Module on a realistic project Product Design * To understand the difference between commodity and speciality chemicals

  13. Approved Module Information for CE3003, 2014/5 Module Title/Name: Advanced Process Design Project Module Code: CE3003

    E-Print Network [OSTI]

    Neirotti, Juan Pablo

    Module Code: CE3003 School: Engineering and Applied Science Module Type: Project New Module? No Module) Programmes in which available: BEng/MEng Chemical Engineering. Available to Exchange Students? Not Specified. The Design Problem is intended to test the student's ability to apply the principles of Chemical Engineering

  14. Sustainable Water Management in the Minerals Industry 1 SUSTAINABLE WATER MANAGEMENT IN THE MINERALS

    E-Print Network [OSTI]

    McGuinness, Mark

    is the amount and control of salt content in the used water dams. While there may be several dams at a givenSustainable Water Management in the Minerals Industry 1 SUSTAINABLE WATER MANAGEMENT interest. It arises in the provision of water for Queensland coal mines, where additional water

  15. SkyMine Carbon Mineralization Pilot Project

    SciTech Connect (OSTI)

    Christenson, Norm; Walters, Jerel

    2014-12-31

    This Topical Report addresses accomplishments achieved during Phase 2b of the SkyMine® Carbon Mineralization Pilot Project. The primary objectives of this project are to design, construct, and operate a system to capture CO2 from a slipstream of flue gas from a commercial coal-fired cement kiln, convert that CO2 to products having commercial value (i.e., beneficial use), show the economic viability of the CO2 capture and conversion process, and thereby advance the technology to the point of readiness for commercial scale demonstration and deployment. The overall process is carbon negative, resulting in mineralization of CO2 that would otherwise be released into the atmosphere. The project will also substantiate market opportunities for the technology by sales of chemicals into existing markets, and identify opportunities to improve technology performance and reduce costs at the commercial scale. The project is being conducted in two phases. The primary objectives of Phase 1 were to evaluate proven SkyMine® process chemistry for commercial pilot-scale operation and complete the preliminary design for the pilot plant to be built and operated in Phase 2, complete a NEPA evaluation, and develop a comprehensive carbon life cycle analysis. The objective of Phase 2b was to build the pilot plant to be operated and tested in Phase 2c.

  16. Fischer-Tropsch Synthesis. Reduction Behavior and Catalytic Activity of Fe-Ce Systems

    SciTech Connect (OSTI)

    Perez-Alonso, F.J.; Ojeda, M.; Herranz, T.; Fierro, J.L.G. [Instituto de Catalisis y Petroleoquimica (CSIC), c/Marie Curie 2, 28049 Madrid (Spain); Bengoa, J.F.; Marchetti, S.G. [CINDECA, Facultad de Ciencias Exactas, Facultad de Ingenieria, UNLP, CICBA, CONICET, Calle 47 No 257, 1900 La Plata (Argentina)

    2005-04-26

    Several Fe-Ce catalysts for FT synthesis were prepared following two different methods: coprecipitation from Fe and Ce nitrate solutions and a physical mixture of pure Fe and Ce precursors. The iron phases present in the activated catalysts were identified by XRD and Moessbauer spectroscopy. A good correlation between both techniques was found. The results revealed that the cerium oxide in the samples prepared by coprecipitation produces two effects: (i), stabilization of metastable species (Fe1-xO), and (ii), a decrease in the crystallite size of the iron species upon increasing Ce-contents, as inferred from an increase in superparamagnetic species. The catalysts were tested in CO hydrogenation in a flow reactor. It was found that selectivity towards light olefins increases for the coprecipitated Ce-containing catalysts, whereas CO conversion followed the opposite trend. Since the Fe1-xO phase was detected in these catalysts, it is suggested that the formation of the Fe1-xO phase would be responsible for the drop in catalytic activity.

  17. Selective flotation of phosphate minerals with hydroxamate collectors

    DOE Patents [OSTI]

    Miller, Jan D. (Salt Lake City, UT); Wang, Xuming (Salt Lake City, UT); Li, Minhua (Salt Lake City, UT)

    2002-01-01

    A method is disclosed for separating phosphate minerals from a mineral mixture, particularly from high-dolomite containing phosphate ores. The method involves conditioning the mineral mixture by contacting in an aqueous in environment with a collector in an amount sufficient for promoting flotation of phosphate minerals. The collector is a hydroxamate compound of the formula; ##STR1## wherein R is generally hydrophobic and chosen such that the collector has solubility or dispersion properties it can be distributed in the mineral mixture, typically an alkyl, aryl, or alkylaryl group having 6 to 18 carbon atoms. M is a cation, typically hydrogen, an alkali metal or an alkaline earth metal. Preferably, the collector also comprises an alcohol of the formula, R'--OH wherein R' is generally hydrophobic and chosen such that the collector has solubility or dispersion properties so that it can be distributed in the mineral mixture, typically an alkyl, aryl, or alkylaryl group having 6 to 18 carbon atoms.

  18. A Comparative Study of the Water Gas Shift Reaction Over Platinum Catalysts Supported on CeO2, TiO2 and Ce-Modified TiO2

    SciTech Connect (OSTI)

    Gonzalez, I.; Navarro, R; Wen, W; Marinkovic, N; Rodriguez, J; Rosa, F; Fierro, J

    2010-01-01

    WGS reaction has been investigated on catalysts based on platinum supported over CeO{sub 2}, TiO{sub 2} and Ce-modified TiO{sub 2}. XPS and XANES analyses performed on calcined catalysts revealed a close contact between Pt precursors and cerium species on CeO{sub 2} and Ce-modified TiO{sub 2} supports. TPR results corroborate the intimate contact between Pt and cerium entities in the Pt/Ce-TiO{sub 2} catalyst that facilitates the reducibility of the support at low temperatures while the Ce-O-Ti surface interactions established in the Ce-modified TiO{sub 2} support decreases the reduction of TiO{sub 2} at high temperature. The changes in the support reducibility leads to significant differences in the WGS activity of the studied catalysts. Pt supported on Ce-modified TiO{sub 2} support exhibits better activity than those corresponding to individual CeO{sub 2} and TiO{sub 2}-supported catalysts. Additionally, the Ce-TiO{sub 2}-supported catalyst displays better stability at reaction temperatures higher than 573 K that observed on pure TiO{sub 2}-supported counterpart. Activity measurements, when coupled with the physicochemical characterization of catalysts suggest that the modifications in the surface reducibility of the support play an essential role in the enhancement of activity and stability observed when Pt is supported on the Ce-modified TiO{sub 2} substrate.

  19. Mineral Deformation at Earth's Core-Mantle Boundary

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    its interior to the surface via convection. Convection not only manifests itself in the plastic deformation of mineral phases due to stress, but it also drives plate tectonics....

  20. Potential of Mineral Uptake Efficiency by Some Apple Rootstocks

    E-Print Network [OSTI]

    Amiri, Mohammad E; Fallahi, Esmail

    2009-01-01

    1999. Drought tolerance of apple rootstocks: Production andwater relations of five apple rootstocks. Acta Horticultureon Mineral Composition of Apple Leaves. J. Am. Soc. Hort.

  1. Molecular Simulation of Carbon Dioxide Brine and Clay Mineral...

    Office of Scientific and Technical Information (OSTI)

    Molecular Simulation of Carbon Dioxide Brine and Clay Mineral Interactions and Determination of Contact Angles. Citation Details In-Document Search Title: Molecular Simulation of...

  2. Australasian Code for Reporting of Exploration Results, Mineral...

    Open Energy Info (EERE)

    (JORC) Published The Joint Ore Reserves Committee of The Australasian Institute of Mining and Metallurgy, Australian Institute of Geoscientists, and Minerals Council of...

  3. Epithermal Gold Mineralization and a Geothermal Resource at Blue...

    Open Energy Info (EERE)

    Epithermal Gold Mineralization and a Geothermal Resource at Blue Mountain, Humboldt County, Nevada Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal...

  4. An Overview of Hydrothermal Alteration and Vein Mineralization...

    Open Energy Info (EERE)

    Overview of Hydrothermal Alteration and Vein Mineralization in Continental Scientific Drilling Program Core Hole VC-2B, Valles Caldera, New Mexico Jump to: navigation, search...

  5. Mechanism of Methane Chemical Looping Combustion with Hematite Promoted with CeO2

    SciTech Connect (OSTI)

    Miller, Duane D.; Siriwardane, Ranjani

    2013-08-01

    Chemical looping combustion (CLC) is a promising technology for fossil fuel combustion that produces sequestration-ready CO{sub 2} stream, reducing the energy penalty of CO{sub 2} separation from flue gases. An effective oxygen carrier for CLC will readily react with the fuel gas and will be reoxidized upon contact with oxygen. This study investigated the development of a CeO{sub 2}-promoted Fe{sub 2}O{sub 3}?hematite oxygen carrier suitable for the methane CLC process. Composition of CeO{sub 2} is between 5 and 25 wt % and is lower than what is generally used for supports in Fe{sub 2}O{sub 3} carrier preparations. The incorporation of CeO{sub 2} to the natural ore hematite strongly modifies the reduction behavior in comparison to that of CeO{sub 2} and hematite alone. Temperature-programmed reaction studies revealed that the addition of even 5 wt % CeO{sub 2} enhances the reaction capacity of the Fe{sub 2}O{sub 3} oxygen carrier by promoting the decomposition and partial oxidation of methane. Fixed-bed reactor data showed that the 5 wt % cerium oxides with 95 wt % iron oxide produce 2 times as much carbon dioxide in comparison to the sum of carbon dioxide produced when the oxides were tested separately. This effect is likely due to the reaction of CeO{sub 2} with methane forming intermediates, which are reactive for extracting oxygen from Fe{sub 2}O{sub 3} at a considerably faster rate than the rate of the direct reaction of Fe{sub 2}O{sub 3} with methane. These studies reveal that 5 wt % CeO{sub 2}/Fe{sub 2}O{sub 3} gives stable conversions over 15 reduction/oxidation cycles. Lab-scale reactor studies (pulsed mode) suggest the methane reacts initially with CeO{sub 2} lattice oxygen to form partial oxidation products (CO + H{sub 2}), which continue to react with oxygen from neighboring Fe{sub 2}O{sub 3}, leading to its complete oxidation to form CO{sub 2}. The reduced cerium oxide promotes the methane decomposition reaction to form C + H{sub 2}, which continue to react with Fe{sub 2}O{sub 3}/Fe{sub 3}O{sub 4} to form CO/CO{sub 2} and H{sub 2}O. This mechanism is supported by the characterization studies, which also suggest that the formation of carbonaceous intermediates may affect the reaction rate and selectivity of the oxygen carrier.

  6. Optical properties of the Ce and La ditelluride charge density wave compounds

    SciTech Connect (OSTI)

    Lavagnini, M.; Sacchetti, A.; Degiorgi, L.; /Zurich, ETH; Shin, K.Y.; Fisher, I.R.; /Stanford U., Geballe Lab. /Stanford U., Appl. Phys. Dept.

    2010-02-15

    The La and Ce di-tellurides LaTe{sub 2} and CeTe{sub 2} are deep in the charge-density-wave (CDW) ground state even at 300 K. We have collected their electrodynamic response over a broad spectral range from the far infrared up to the ultraviolet. We establish the energy scale of the single particle excitation across the CDW gap. Moreover, we find that the CDW collective state gaps a very large portion of the Fermi surface. Similarly to the related rare earth tri-tellurides, we envisage that interactions and Umklapp processes play a role in the onset of the CDW broken symmetry ground state.

  7. Transmission Electron Microscopy Investigation of Krypton Bubbles in Polycrystalline CeO2

    SciTech Connect (OSTI)

    Lingfeng He; Clarissa Yablinsky; Mahima Gupta; Jian Gan; Marquis A. Kirk; Todd R. Allen

    2013-05-01

    To gain an understanding of gas bubble transport in oxide nuclear fuel, this paper uses polycrystalline CeO2, composed of both nanograins and micrograins, as a surrogate material for UO2. The CeO2 was implanted with 150-keV Kr ions up to a dose of 1 x 1016 ions/cm2 at 600 degrees C. Transmission electron microscopy characterizations of small Kr bubbles in nanograin and micrograin regions were compared. The grain boundary acted as an efficient defect sink, as evidenced by smaller bubbles and a lower bubble density in the nanograin region as compared to the micrograin region.

  8. Respiratory disease in Utah coal miners

    SciTech Connect (OSTI)

    Rom, W.N.; Kanner, R.E.; Renzetti, A.D. Jr.; Shigeoka, J.W.; Barkman, H.W.; Nichols, M.; Turner, W.A.; Coleman, M.; Wright, W.E.

    1981-04-01

    Two hundred forty-two Utah underground coal miners volunteered to participate in a respiratory disease study. They were an older group (mean, 56 years of age) and had spent a mean of 29 years in the coal-mining industry. The prevalence of chronic bronchitis was 57%, and that of coal worker's pneumoconiosis, 25%; only one worker had progressive massive fibrosis. Significant impairment of pulmonary function was found among those with a history of cigarette smoking. Chronic bronchitis or coal worker's penumoconiosis among nonsmokers did not impair pulmonary function. There was a significant association among the nonsmokers between increasing exposure to coal dust and coal worker's pneumoconiosis, but not for changes in pulmonary function. Coal mine dust had a significant influence in causing the symptom complex of chronic cough and sputum production, and coal worker's pneumoconiosis.

  9. Respiratory disease in Utah coal miners

    SciTech Connect (OSTI)

    Rom, W.N.; Kanner, R.E.; Renzetti, A.D. Jr.; Shigeoka, J.W.; Barkman, H.W.; Nichols, M.; Turner, W.A.; Coleman, M.; Wright, W.E.

    1981-04-01

    Two hundred forty-two Utah underground coal miners volunteered to participate in a respiratory disease study. They were an older group (mean, 56 years of age) and had spent a mean of 29 years in the coal-mining industry. The prevalence of chronic bronchitis was 57%, and that of coal worker's pneumoconiosis, 25%; only one worker had progressive massive fibrosis. Significant impairment of pulmonary function was found among those with a history of cigarette smoking. Chronic bronchitis or coal worker's pneumoconiosis among nonsmokers did not impair pulmonary function. There was a significant association among the nonsmokers between increasing exposure to coal dust and coal worker's pneumoconiosis, but not for changes in pulmonary function. Coal mine dust had a significant influence in causing the symptom complex of chronic cough and sputum production, and coal worker's pneumoconiosis.

  10. Mineral resources and mineral resource potential of the Panamint Dunes Wilderness Study Area, Inyo County, California

    SciTech Connect (OSTI)

    Kennedy, G.L.; Kilburn, J.E.; Conrad, J.E.; Leszcykowski, A.M.

    1984-01-01

    This report presents the results of a mineral survey of the Panamint Dunes Wilderness Study Area (CDCA-127), California Desert Conservation Area, Inyo County, California. The Panamint Dunes Wilderness Study Area has an identified volcanic cinder resource and few areas with mineral resource potential. Hydrothermal deposits of lead-zinc-silver occur in veins and small replacement bodies along and near the Lemoigne thrust fault on the eastern side of the wilderness study area. Two workings, the Big Four mine with 35,000 tons of inferred subeconomic lead-zinc-silver resources and a moderate potential for additional resources, and the Apple 1 claim with low potential for lead-zinc-silver resources, are surrounded by the study area but are specifically excluded from it. A low resource potential for lead-zinc-silver is assigned to other exposures along the Lemoigne thrust, although metallic minerals were not detected at these places. The Green Quartz prospect, located near the northern tip of the study area, has low resource potential for copper in quartz pegmatities in quartz monzonite of the Hunter Mountain batholith. Nonmetallic mineral resources consist of volcanic cinders and quartz sand. An estimated 900,000 tons of inferred cinder reserves are present at Cal Trans borrow pit MS 242, on the southern margin of the study area. The Panamint Valley dune field, encompassing 480 acres in the north-central part of the study area, has only low resource potential for silica because of impurities. Other sources of silica and outside the study area are of both higher purity and closer to possible markets. 19 refs., 2 figs., 1 tab.

  11. Daylight photocatalysis performance of biomorphic CeO{sub 2} hollow fibers prepared with lens cleaning paper as biotemplate

    SciTech Connect (OSTI)

    Qian, Junchao; Chen, Feng [Department of Material Science and Engineering, Jiangsu University, 212013 Zhenjiang (China)] [Department of Material Science and Engineering, Jiangsu University, 212013 Zhenjiang (China); Wang, Fang; Zhao, Xiaobing [Department of Materials Science and Engineering, Changzhou University, 213164 Changzhou (China)] [Department of Materials Science and Engineering, Changzhou University, 213164 Changzhou (China); Chen, Zhigang, E-mail: ziyou1900@gmail.com [Department of Material Science and Engineering, Jiangsu University, 212013 Zhenjiang (China) [Department of Material Science and Engineering, Jiangsu University, 212013 Zhenjiang (China); Jiangsu Key Laboratory for Environment Functional Materials, 215009 Suzhou University of Science and Technology, Suzhou (China); State Key laboratory of Crystal Material, Shandong University, 250100 Jinan (China)

    2012-08-15

    Highlights: ? A novel, simple and eco-friendly approach for hierarchical, biomorphic CeO{sub 2} hollow fibers with mesoporous tube walls is presented by using paper as template. ? The biomorphic CeO{sub 2} fibers was composed of nanosheets with bimodal pore-size mesoporous distribution and exhibited high light-harvesting under sunlight irradiation. ? The CeO{sub 2} microfibers biomimicking the natural plant structures have promising application for photodegradation of organic pollutants in water. -- Abstract: Hierarchical, biomorphic CeO{sub 2} hollow fibers with mesoporous tube walls have been fabricated using lens cleaning paper as biotemplates. After sintered at 550 °C in air, the cellulosic fibers of paper were converted into micro-tubes composing of CeO{sub 2} crystallites with grain size about 8 nm. The photocatalytic activity of the CeO{sub 2} fibers was evaluated by photodegradation efficiency of methylene blue in aqueous solution under daylight irradiation. The characterized results show that the CeO{sub 2} fibers faithfully replicated micro-fibrous structure derived from original template and possessed dramatic enhanced photocatalytic activity compared with bulk CeO{sub 2}. This simple biotemplate method provides a cost-effective and eco-friendly route to obtain high performance photocatalysts.

  12. The NiCE Discussion Room: Integrating Paper and Digital Media to Support Co-Located Group Meetings

    E-Print Network [OSTI]

    -based interfaces, multi-user input, digital meeting room, design ACM Classification Keywords H5.3. GroupThe NiCE Discussion Room: Integrating Paper and Digital Media to Support Co-Located Group Meetings or replicate. We introduce a novel digital meeting room design, the NiCE Discussion Room, which integrates

  13. Aging behavior and precipitates analysis of the CuCrZrCe alloy Yi Zhang a,b,d,n

    E-Print Network [OSTI]

    Volinsky, Alex A.

    Aging behavior and precipitates analysis of the Cu­Cr­Zr­Ce alloy Yi Zhang a,b,d,n , Alex A October 2015 Keywords: Cu­Cr­Zr­Ce alloy Cold rolling Aging treatment Microstructure Physical properties rolling and aging for 16 h at 300 °C. Under the same aging conditions, without cold rolling, the hardness

  14. ORIGINAL PAPER Comparison of manure compost and mineral fertilizer

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ORIGINAL PAPER Comparison of manure compost and mineral fertilizer for hybrid poplar plantation and methods Composted sheep manure (10 and 20 kg/tree) at planting was compared to N and P mineral Contrary to what we expected, compost treatments neither increased root development nor tree water status

  15. U.S. Geological Survey China's Growing Appetite for Minerals

    E-Print Network [OSTI]

    (markets) · National security USGS research on minerals in development cycle-- o Based on 1929 work of USGS: Coal 45 1 Oil 4.7 6 Industrial minerals: Cement 42 1 Fluorspar 55 1 Rare earths 85 1 Metals: Aluminum 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 Year Millionmetrictons Canada China

  16. Calcite Mineral Scaling Potentials of High-Temperature Geothermal Wells

    E-Print Network [OSTI]

    Karlsson, Brynjar

    #12;i Calcite Mineral Scaling Potentials of High-Temperature Geothermal Wells Alvin I. Remoroza-Temperature Geothermal Wells Alvin I. Remoroza 60 ECTS thesis submitted in partial fulfillment of a Magister Scientiarum #12;iv Calcite Mineral Scaling Potentials of High-Temperature Geothermal Wells 60 ECTS thesis

  17. Cesium Adsorption on Clay Minerals: An EXAFS Spectroscopic

    E-Print Network [OSTI]

    Chorover, Jon

    Cesium Adsorption on Clay Minerals: An EXAFS Spectroscopic Investigation B E N J A M I N C . B O, Arizona 85721-0038 Cesium adsorption on the clay minerals vermiculite and montmorilloniteisdescribedasafunctionofsurfacecoverage using extended X-ray adsorption fine structure spectroscopy (EXAFS). Cesium (Cs) possessed

  18. SULFATE AND NITRATE COATINGS ON MINERAL DUSTS: CRYSTALLINE OR AQUEOUS?

    E-Print Network [OSTI]

    SULFATE AND NITRATE COATINGS ON MINERAL DUSTS: CRYSTALLINE OR AQUEOUS? Scot T. Martin, Hui Observational evidence shows that mineral dusts in Asian outflows become coated by sulfates and nitrates. Layer), and the asymmetry parameter. The aqueous coatings also provide milieu for aqueous chemical reactions

  19. State of Oregon Department of Geology and Mineral Industries

    E-Print Network [OSTI]

    Goldfinger, Chris

    State of Oregon Department of Geology and Mineral Industries Vicki S. McConnell, State Geologist Open-File Report O-08-14 PRELIMINARY GEOLOGIC MAPS OF THE CORVALLIS, WREN, AND MARYS PEAK 7 G Y A ND M INERALINDUSTRIES 1937 2008 1 Oregon Department of Geology and Mineral Industries, Grants

  20. KING FAHD UNIVERSITY OF PETROLEUM & MINERALS DEANSHIP OF GRADUATE STUDIES

    E-Print Network [OSTI]

    Almulhem, Ahmad

    KING FAHD UNIVERSITY OF PETROLEUM & MINERALS DEANSHIP OF GRADUATE STUDIES Online Academic Services the Online Academic Services related to Theses/Dissertations. #12;King Fahd University of Petroleum................................................................... 7 #12;King Fahd University of Petroleum & Minerals Deanship of Graduate Studies 1 | P a g e Graduate

  1. Chemical composition, mineral content and cholesterol levels of some regular

    E-Print Network [OSTI]

    Boyer, Edmond

    Note Chemical composition, mineral content and cholesterol levels of some regular and reduced from cow's milk, were analyzed for basic nutrients (water, protein, fat, ash and lactose), cholesterol and selected minerals (Na, Ca, K, Mg, P and Zn). The moisture contents of Labneh (78.6 g·100 g-1 ) and Double

  2. 1. Mineral Exploration Regulation in British Columbia Health, Safety and Reclamation Code

    E-Print Network [OSTI]

    Bolch, Tobias

    for or to produce coal, mineral bearing substances, placer minerals, rock, limestone, earth, clay, sand or gravel mineral, coal, sand, gravel or rock, or (b) the production of a mineral, a placer mineral, coal, sand under the Criminal Code of Canada for criminal acts or negligence in the workplace. Further information

  3. Charge dynamics of Ce-based compounds: Connection between the mixed valent and Kondo-insulator states

    SciTech Connect (OSTI)

    Bucher, B. [Laboratorium fuer Festkoerperphysik, Eidgenoessische Technische Hochschule Zuerich, 8093 Zuerich (Switzerland)] [Laboratorium fuer Festkoerperphysik, Eidgenoessische Technische Hochschule Zuerich, 8093 Zuerich (Switzerland); Schlesinger, Z. [IBM, Thomas J. Watson Research Center, Yorktown Heights, New York 10958 (United States)] [IBM, Thomas J. Watson Research Center, Yorktown Heights, New York 10958 (United States); Mandrus, D.; Fisk, Z.; Sarrao, J. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)] [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); DiTusa, J.F.; Oglesby, C.; Aeppli, G.; Bucher, E. [AT& T Bell Laboratories, Murray Hill, New Jersey 07974 (United States)] [AT& T Bell Laboratories, Murray Hill, New Jersey 07974 (United States)

    1996-02-01

    The reflectivities of the mixed-valent compounds CeSn{sub 3} and CePd{sub 3} have been measured to obtain the optical conductivity as a function of temperature. Both compounds show a renormalization of the low-energy Drude conductivity at low temperatures. In addition, for the low-carrier-density compound CePd{sub 3}, but not for high-carrier-density CeSn{sub 3}, substantial spectral weight lost from the conductivity below 1000 cm{sup {minus}1} reappears in the frequency range 2000{endash}10000 cm{sup {minus}1}, indicating that CePd{sub 3} can be considered a lightly doped Kondo insulator. {copyright} {ital 1996 The American Physical Society.}

  4. Noise Estimation from a Single Image Ce Liu William T. Freeman

    E-Print Network [OSTI]

    Freeman, William T.

    Noise Estimation from a Single Image Ce Liu William T. Freeman CS and AI Lab, MIT {celiu to the image noise level, making it an important quantity to es- timate. We show how to estimate an upper bound on the noise level from a single image based on a piecewise smooth image prior model and measured CCD camera

  5. The CompuTer SCienCe program The bachelor of science degree in computer science

    E-Print Network [OSTI]

    Suzuki, Masatsugu

    The CompuTer SCienCe program The bachelor of science degree in computer science offered in the fundamentals of computer science, elements of practical application and an appreciation for liberal learning to work within various areas of computer science and to work across other disciplines. program edu

  6. DEPARTMENT OF THE NAVY OFfiCE OF THE CHIEF OF NAVAL OPERATIONS

    E-Print Network [OSTI]

    DEPARTMENT OF THE NAVY OFfiCE OF THE CHIEF OF NAVAL OPERATIONS 2000 NAVY PENTAGON WASHINGTON, DC: Chief of Naval Operations Subj , NAVY PASSENGER TRAVEL Ref: (al 000 Di rective 5154.29 of 9 Marc h 1993 on the management , execution, and funding of passenger travel for Navy personne l . This i n struction

  7. Phase transition and possible metallization in CeVO{sub 4} under pressure

    SciTech Connect (OSTI)

    Garg, Alka B.; Shanavas, K.V.; Wani, B.N.; Sharma, Surinder M.

    2013-07-15

    Phase stability of CeVO{sub 4} under pressure has been investigated using synchrotron based angle dispersive x-ray diffraction (ADXRD), electrical resistance and first principles calculations. The results indicate that the ambient zircon structure of the compound transforms to a low symmetry monoclinic monazite phase beyond 3.8 GPa with nearly 8.6% volume discontinuity. Beyond 11 GPa, the pattern could be fitted to a similar monazite structure which is about 12.7% denser and has a much larger monoclinic beta angle. On pressure release the first monoclinic phase is recovered. The electrical resistance data show a large drop in resistance with pressure indicating substantial narrowing down of the band gap. Electronic structure calculations support these observations and suggest possible pressure induced metallization in this material. - Pressure induced structural phase transition in CeVO{sub 4} as observed by x- ray diffraction (pressure vs. volume) and possible metallization in CeVO{sub 4} through electrical resistance and first principles electronic structure calculations. - Highlights: • Structural and electrical behavior of CeVO{sub 4} under pressure studied using x-ray diffraction and electrical resistance measurements and first principles calculations. • Two successive structural transitions confirmed by experiment and theory: zircon–monazite I–monazite II. • Band gap collapse and possible metallization is indicated by electrical resistance measurements and electronic structure calculations under pressure. • Novel observation of lower bulk modulus in the high pressure phase (both by experiment and calculations) explained through structural analysis.

  8. Temperature-dependent luminescence of Ce3+ in gallium-substituted

    E-Print Network [OSTI]

    Walker, D. Greg

    were prepared via a simple combustion synthe- sis method and had the formula Y2.97Ce0.03 3 Al1-xGax 5O width of 0.1 nm. The pulse width was 4ns at a characteristic energy of 300 J. The excitation pulse

  9. Energy Based Methods in Wind Turbine Control CeSOS Highlights and AMOS Visions

    E-Print Network [OSTI]

    Nørvåg, Kjetil

    Energy Based Methods in Wind Turbine Control CeSOS Highlights and AMOS Visions Morten D. Pedersen 1 / 26 #12;This talk 1 Background 2 Understanding the Wind Turbine 3 Nonlinear Turbine Modeling 4;Background The Problem Previously stable wind turbine systems began exhibiting resonant behavior when put

  10. Technical Report No. 480 CE: The Classi er Estimator Framework for Data mining

    E-Print Network [OSTI]

    Dalkilic, Mehmet

    Technical Report No. 480 CE: The Classi er Estimator Framework for Data mining Mehmet M. Dalkilic a coherent framework for data mining in the relational model. Observing that data mining depends on two. The classi er indicates the target of the data mining investigation. The classi er may be di cult to express

  11. Title: SPONSORSHIP OR CE APPROVAL OF NON-SCHOOL OF NURSING CONTINUING EDUCATION OFFERING

    E-Print Network [OSTI]

    Chapman, Michael S.

    1 Title: SPONSORSHIP OR CE APPROVAL OF NON-SCHOOL OF NURSING CONTINUING EDUCATION OFFERING Index: School of Nursing sponsorship and/or approval of a continuing education offering given by individuals by approving offerings given by non-School of Nursing faculty. Implementing Procedures: Responsible Party

  12. Research activities in the Norwegian Deepwater Programme Conference on CeSOS Highlights and AMOS Visions

    E-Print Network [OSTI]

    Nørvåg, Kjetil

    Research activities in the Norwegian Deepwater Programme Conference on CeSOS Highlights and AMOS Visions Rolf Baarholm, Statoil 6/5/2013 #12;- Norwegian Deepwater Programme - VIV characterization) in the Norwegian Sea. Later extended to include 16th 17th 18th 19th 20th and 21st round deepwater licences. About

  13. Author's personal copy Prepration and photoluminescence properties of Ce doped lutetium silicate

    E-Print Network [OSTI]

    Cao, Guozhong

    Author's personal copy Prepration and photoluminescence properties of Ce doped lutetium silicate: Received 3 September 2010 Accepted 2 November 2010 Available online 12 November 2010 Keywords: Lutetium silicate Cerium Solegel Photoluminescence Lu2SiO5 a b s t r a c t Cerium doped lutetium silicate powders

  14. ARTIFIC~L r~rELUOE~CE 189 STRIPS: A New Approach to the

    E-Print Network [OSTI]

    Pratt, Vaughan

    can be proven to be true. STRIPS represents a world n,~del as an arbitrary collection offirst-order, a world model is r~presented by a set of well- formed formulas (wffs) of the first-order predicateARTIFIC~L r~rELUOE~CE 189 STRIPS: A New Approach to the Application of .Theorem Proving to Problem

  15. CE-QUAL-W2 Version 3: Hydrodynamic and Water Quality River Basin Modeling

    E-Print Network [OSTI]

    Wells, Scott A.

    and Oregon; the Bull Run River basin composed of 3 water sup- ply reservoirs and 2 river sections with a 2CE-QUAL-W2 Version 3: Hydrodynamic and Water Quality River Basin Modeling S. A. Wells Department for deep, long, and narrow waterbodies. The current model, Version 2, has been used in over 200 river

  16. Hydrodynamic and water quality river basin modeling using CE-QUAL-W2 version 3

    E-Print Network [OSTI]

    Wells, Scott A.

    of the Lower Snake River in the Northwestern USA; the Bull Run River basin composed of 3 water supplyHydrodynamic and water quality river basin modeling using CE-QUAL-W2 version 3 Scott A. Wells for deep, long, and narrow waterbodies. The current model, Version 2, has been used in over 200 river

  17. Log of Changes to IMA Mineral List This log file was begun in June 2010 to keep track of changes to the IMA list of minerals

    E-Print Network [OSTI]

    Downs, Robert T.

    1 Log of Changes to IMA Mineral List This log file was begun in June 2010 to keep track of changes to the IMA list of minerals at http://rruff.info/IMA. 2 August 2013: Eltyubyuite: New mineral descriptions of wadalite: a new mineral from the Northern Caucasus, Kabardino-Balkaria, Russia. European Journal

  18. Synthesis and crystal structure of two new cerium rhodium oxides: Ce{sub 2/3-x}Rh{sup 3+}{sub 2}O{sub 4} (x{approx}0.12) with Ce mixed valency and Ce{sup 4+}Rh{sup 3+}{sub 2}O{sub 5}

    SciTech Connect (OSTI)

    Mizoguchi, Hiroshi; Zakharov, L.N.; Bhuvanesh, N.S.P.; Sleight, A.W.; Subramanian, M.A.

    2011-06-15

    The new compounds Ce{sub 2/3-x}Rh{sub 2}O{sub 4} (x{approx}0.11-0.14) and CeRh{sub 2}O{sub 5} have been prepared. Their structures were determined from single crystal X-ray diffraction data. Electrical and magnetic properties were also evaluated. Based on the structural analysis and physical properties, oxidation states for CeRh{sub 2}O{sub 5} can be assigned as Ce{sup 4+}Rh{sup 3+}{sub 2}O{sub 5}. A small variation in x was detected for Ce{sub 2/3-x}Rh{sub 2}O{sub 4} indicating a formula ranging from Ce{sup 3.64+}{sub 0.55}Rh{sup 3+}{sub 2}O{sub 4} to Ce{sup 3.81+}{sub 0.525}Rh{sup 3+}{sub 2}O{sub 4}. - Graphical abstract: The new compounds Ce{sub 2/3-x}Rh{sub 2}O{sub 4} (x{approx}0.11-0.14) and CeRh{sub 2}O{sub 5} have been prepared and their structures were determined from single crystal X-ray diffraction data. Electrical and magnetic properties were also evaluated. Highlights: > The new compounds CeRh{sub 2}O{sub 5} and Ce{sub 2/3-x}Rh{sub 2}O{sub 4} (x{approx}0.11-0.14) have been prepared. > Their structures were determined from single crystal X-ray diffraction data. > Valence picture is Ce{sup 4+}Rh{sup 3+}{sub 2}O{sub 5} and Ce{sup 3.64+}{sub 0.55}Rh{sup 3+}{sub 2}O{sub 4} to Ce{sup 3.81+}{sub 0.525}Rh{sup 3+}{sub 2}O{sub 4}.

  19. Chemically Accelerated Carbon Mineralization: Chemical and Biological Catalytic Enhancement of Weathering of Silicate Minerals as Novel Carbon Capture and Storage

    SciTech Connect (OSTI)

    None

    2010-07-01

    IMPACCT Project: Columbia University is developing a process to pull CO2 out of the exhaust gas of coal-fired power plants and turn it into a solid that can be easily and safely transported, stored above ground, or integrated into value-added products (e.g. paper filler, plastic filler, construction materials, etc.). In nature, the reaction of CO2 with various minerals over long periods of time will yield a solid carbonate—this process is known as carbon mineralization. The use of carbon mineralization as a CO2 capture and storage method is limited by the speeds at which these minerals can be dissolved and CO2 can be hydrated. To facilitate this, Columbia University is using a unique process and a combination of chemical catalysts which increase the mineral dissolution rate, and the enzymatic catalyst carbonic anhydrase which speeds up the hydration of CO2.

  20. (U) Equation of State and Compaction Modeling for CeO2

    SciTech Connect (OSTI)

    Fredenburg, David A.; Chisolm, Eric D.

    2014-10-20

    Recent efforts have focused on developing a solid-liquid and three-phase equation of state (EOS) for CeO2, while parallel experimental efforts have focused on obtaining high-fidelity Hugoniot measurements on CeO2 in the porous state. The current work examines the robustness of two CeO2 SESAME equations of state, a solid-liquid EOS, 96170, and a three-phase EOS, 96171, by validating the EOS against a suite of high-pressure shock compression experiments on initially porous CeO2. At lower pressures compaction is considered by incorporating a two-term exponential form of the P-compaction model, using three separate definitions for ?(P). Simulations are executed spanning the partially compacted and fully compacted EOS regimes over the pressure range 0.5 - 109 GPa. Comparison of calculated Hugoniot results with those obtained experimentally indicate good agreement for all definitions of ?(P) with both the solid-liquid and three-phase EOS in the low-pressure compaction regime. At higher pressures the three-phase EOS does a better job at predicting the measured Hugoniot response, though at the highest pressures EOS 96171 predicts a less compliant response than is observed experimentally. Measured material velocity profiles of the shock-wave after it has transmitted through the powder are also compared with those simulated using with solid-liquid and three-phase EOS. Profiles lend insight into limits of the current experimental design, as well as the threshold conditions for the shock-induced phase transition in CeO2.

  1. Sulfur tolerant metal doped Fe/Ce catalysts for high temperature WGS reaction at low steam to CO ratios XPS and Mssbauer spectroscopic study

    E-Print Network [OSTI]

    Boolchand, Punit

    spectroscopy TPR XPS CeO2 Magnetite a b s t r a c t High temperature water gas shift reaction (WGS) at low/Ce and Co-, Zr-, Hf-, and Mo-doped Fe/Ce catalysts compared to the activated catalysts. For Cr-doped FeSulfur tolerant metal doped Fe/Ce catalysts for high temperature WGS reaction at low steam to CO

  2. The solubility and kinetics of minerals under CO2-EGS geothermal conditions: Comparison of experimental and modeling results

    E-Print Network [OSTI]

    Xu, T.

    2014-01-01

    of rate parameters of water-mineral interaction kinetics forKinetic rate law for mineral dissolution and precipitationwhere n denotes kinetic mineral index, positive values of r

  3. The role of reaction affinity and secondary minerals in regulating chemical weathering rates at the Santa Cruz Soil Chronosequence, California

    E-Print Network [OSTI]

    Maher, K.

    2009-01-01

    on Reaction- Rates among Minerals and Aqueous-Solutions .1.as a result of secondary mineral precipitation and approachterm and Contemporary Mineral Weathering rates. Geochim.

  4. Integrating Steel Production with Mineral Carbon Sequestration

    SciTech Connect (OSTI)

    Klaus Lackner; Paul Doby; Tuncel Yegulalp; Samuel Krevor; Christopher Graves

    2008-05-01

    The objectives of the project were (i) to develop a combination iron oxide production and carbon sequestration plant that will use serpentine ores as the source of iron and the extraction tailings as the storage element for CO2 disposal, (ii) the identification of locations within the US where this process may be implemented and (iii) to create a standardized process to characterize the serpentine deposits in terms of carbon disposal capacity and iron and steel production capacity. The first objective was not accomplished. The research failed to identify a technique to accelerate direct aqueous mineral carbonation, the limiting step in the integration of steel production and carbon sequestration. Objective (ii) was accomplished. It was found that the sequestration potential of the ultramafic resource surfaces in the US and Puerto Rico is approximately 4,647 Gt of CO2 or over 500 years of current US production of CO2. Lastly, a computer model was developed to investigate the impact of various system parameters (recoveries and efficiencies and capacities of different system components) and serpentinite quality as well as incorporation of CO2 from sources outside the steel industry.

  5. SkyMine Carbon Mineralization Pilot Project

    SciTech Connect (OSTI)

    Joe Jones; Clive Barton; Mark Clayton; Al Yablonsky; David Legere

    2010-09-30

    This Topical Report addresses accomplishments achieved during Phase 1 of the SkyMine{reg_sign} Carbon Mineralization Pilot Project. The primary objectives of this project are to design, construct, and operate a system to capture CO{sub 2} from a slipstream of flue gas from a commercial coal-fired cement kiln, convert that CO{sub 2} to products having commercial value (i.e., beneficial use), show the economic viability of the CO{sub 2} capture and conversion process, and thereby advance the technology to a point of readiness for commercial scale demonstration and proliferation. The project will also substantiate market opportunities for the technology by sales of chemicals into existing markets, and identify opportunities to improve technology performance and reduce costs at commercial scale. The primary objectives of Phase 1 of the project were to elaborate proven SkyMine{reg_sign} process chemistry to commercial pilot-scale operation and complete the preliminary design ('Reference Plant Design') for the pilot plant to be built and operated in Phase 2. Additionally, during Phase 1, information necessary to inform a DOE determination regarding NEPA requirements for the project was developed, and a comprehensive carbon lifecycle analysis was completed. These items were included in the formal application for funding under Phase 2. All Phase 1 objectives were successfully met on schedule and within budget.

  6. Frequency and temperature dependence in electromagnetic properties of Martian analog minerals

    E-Print Network [OSTI]

    Stillman, David E.

    Frequency and temperature dependence in electromagnetic properties of Martian analog minerals David), Frequency and temperature dependence in electromagnetic properties of Martian analog minerals, J. Geophys energy [Grimm et al., 2006]. Lastly, dielectric and magnetic relaxations of Martian subsurface minerals

  7. Bone Mineral Density, Bone Turnover, and Systemic Inflammation in Non-cirrhotics with Chronic Hepatitis C

    E-Print Network [OSTI]

    Lai, JC; Shoback, DM; Zipperstein, J; Lizaola, B; Tseng, S; Terrault, NA

    2015-01-01

    Mun˜oz-Torres M, et al. Bone mineral density, serum insulin-et al. Osteoporosis and bone mineral metabolism disorders in1069-9. 11. George J. Bone mineral density and disorders of

  8. Assessment of industrial minerals and rocks in the controlled area

    SciTech Connect (OSTI)

    Castor, S.B.; Lock, D.E.

    1996-08-01

    Yucca Mountain in Nye County, Nevada, is a potential site for a permanent repository for high-level nuclear waste in Miocene ash flow tuff. The Yucca Mountain controlled area occupies approximately 98 km{sup 2} that includes the potential repository site. The Yucca Mountain controlled area is located within the southwestern Nevada volcanic field, a large area of Miocene volcanism that includes at least four major calderas or cauldrons. It is sited on a remnant of a Neogene volcanic plateau that was centered around the Timber Mountain caldera complex. The Yucca Mountain region contains many occurrences of valuable or potentially valuable industrial minerals, including deposits with past or current production of construction aggregate, borate minerals, clay, building stone, fluorspar, silicate, and zeolites. The existence of these deposits in the region and the occurrence of certain mineral materials at Yucca Mountain, indicate that the controlled area may have potential for industrial mineral and rock deposits. Consideration of the industrial mineral potential within the Yucca Mountain controlled area is mainly based on petrographic and lithologic studies of samples from drill holes in Yucca Mountain. Clay minerals, zeolites, fluorite, and barite, as minerals that are produced economically in Nevada, have been identified in samples from drill holes in Yucca Mountain.

  9. Availability of Potash in Some Soil-Forming Minerals 

    E-Print Network [OSTI]

    Fraps, G. S. (George Stronach)

    1921-01-01

    AVAILABILITY OF POTASH IN SOME SOIL-FORMING MINERALS . knowledge of the availability of potash in minerals which occur in ,,,, soil is important to soil chemistry. It aids in the interpretation of the analysis of the soil and in judging methods of analysis.... McCaughey and Fry (Bulletin 91 of the Bureau of Soils, U. S. De- partment of Agriculture) have found that four primary minerals in tht soil are the chief carriers of potash. These are biotite, muscovite, ortho- clase, and microcline. Potash may...

  10. Structure and magnetic properties of Ce?(Ni/Al/Ga)??—A new phase with the La?Al?? structure type

    SciTech Connect (OSTI)

    Janka, Oliver; Shang, Tian; Baumbach, Ryan E.; Bauer, Eric D.; Thompson, Joe D.; Kauzlarich, Susan M.

    2015-03-01

    Single crystals of Ce?(Ni/Al/Ga)?? were obtained from an Al flux reaction. Single crystals of the title compound crystallizing in the orthorhombic space group Immm (No. 71, Z = 2) with a = 436.38(14), b = 1004.5(3) and c = 1293.4(4) pm. This is a standardized unit cell of the previously published La?Al?? structure type. Wavelength dispersive microprobe provides the composition of Ce?.?????Ni?.?????Al?.?????Ga?.?????. Single crystal refinement provides the composition Ce?Ni?.??Al?.??Ga?.?? with substitution of the Ni and Ga on the Al1 and Al4 sites with the Al2 and Al3 solely occupied by Al. Magnetic susceptibility measurements reveal antiferromagnetic ordering with TN = 4.8 K and there is no evidence for a ferromagnetic ordering that has been reported for Ce?Al??. The effective magnetic moment was found to be ?eff = 1.9?B/Ce, which is lower than the expected value for trivalent Ce (2.54?B/Ce).

  11. Exploring Frontiers in Kinetics and Mechanisms of Geochemical Processes at the Mineral/Water Interface

    E-Print Network [OSTI]

    Sparks, Donald L.

    Exploring Frontiers in Kinetics and Mechanisms of Geochemical Processes at the Mineral geochemical processes including surface complexation, mineral transformations, and oxidation

  12. Mineral transformation and biomass accumulation associated with uranium bioremediation at Rifle, Colorado

    E-Print Network [OSTI]

    Li, L.

    2009-01-01

    phase transformation and biomass accumulation associatedMineral Transformation and Biomass Accumulation Associatedof new mineral phases and biomass. Word count: 5496 (text) +

  13. Magnitude of the magnetic exchange interaction in the heavy-fermion antiferromagnet CeRhIn5

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Das, Pinaki; Lin, S. -Z.; Ghimire, N. J.; Huang, K.; Ronning, F.; Bauer, E. D.; Thompson, J. D.; Batista, C. D.; Ehlers, G.; Janoschek, M.

    2014-12-08

    We have used high-resolution neutron spectroscopy experiments to determine the complete spin wave spectrum of the heavy-fermion antiferromagnet CeRhIn?. The spin wave dispersion can be quantitatively reproduced with a simple frustrated J?-J? model that also naturally explains the magnetic spin-spiral ground state of CeRhIn? and yields a dominant in-plane nearest-neighbor magnetic exchange constant J?=0.74(3) meV. Our results lead the way to a quantitative understanding of the rich low-temperature phase diagram of the prominent CeTIn? (T = Co, Rh, Ir) class of heavy-fermion materials.

  14. Select Minerals and Potable Use of Reclaimed Wastewaters 

    E-Print Network [OSTI]

    Wolf, H.

    1977-01-01

    The long-observed relationships of an influence of drinking water mineral content on heart-circulatory deaths are developed to indicate that sodium -- when present in sufficiently high concentrations -- may be detrimental to human health...

  15. A Review Of Water Contents Of Nominally Anhydrous Natural Minerals...

    Open Energy Info (EERE)

    A Review Of Water Contents Of Nominally Anhydrous Natural Minerals In The Mantles Of Earth, Mars And The Moon Jump to: navigation, search OpenEI Reference LibraryAdd to library...

  16. Mercury Contents of Natural Thermal and Mineral Fluids, In- U...

    Open Energy Info (EERE)

    OpenEI Reference LibraryAdd to library Book Section: Mercury Contents of Natural Thermal and Mineral Fluids, In- U.S. Geological Survey Professional Paper 713 Abstract...

  17. Immersion freezing of clay minerals and bacterial ice nuclei

    E-Print Network [OSTI]

    Hiranuma, Naruki

    2013-01-01

    The immersion mode ice nucleation efficiency of clay minerals and biological aerosols has been investigated using the AIDA (Aerosol Interaction and Dynamics in the Atmosphere) cloud chamber. Both monodisperse and polydisperse ...

  18. Mineral Deformation at Earth's Core-Mantle Boundary

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mineral Deformation at Earth's Core-Mantle Boundary Print Earth is a dynamic planet in which convection takes place on the scale of thousands of kilometers. Because Earth is mostly...

  19. King Fahd University of Petroleum & Minerals DEPARTMENT OF MATHEMATICAL SCIENCES

    E-Print Network [OSTI]

    Mustafa, M. Tahir

    King Fahd University of Petroleum & Minerals DEPARTMENT OF MATHEMATICAL SCIENCES Technical Report of the map. Recall that a map : Mm Nn is said to be harmonic if it extremizes the associated energy

  20. Inducing Mineral Precipitation in Groundwater by Addition of Phosphate

    SciTech Connect (OSTI)

    Karen E. Wright; Yoshiko Fujita; Thomas Hartmann; Mark Conrad

    2011-10-01

    Induced precipitation of phosphate minerals to scavenge trace metals and radionuclides from groundwater is a potential remediation approach for contaminated aquifers. Phosphate minerals can sequester trace elements by primary mineral formation, solid solution formation and/or adsorption, and they are poorly soluble under many environmental conditions, making them attractive for long-term sustainable remediation. The success of such engineered schemes will depend on the particular mineral phases generated, their rates of formation, and their long term stability. The purpose of this study was to examine the precipitation of calcium phosphate minerals under conditions representative of a natural groundwater. Because microorganisms are present in groundwater, and because some proposed schemes for induced phosphate mineral precipitation rely on the stimulation of native groundwater populations, we also tested the effect of bacterial cells (initial densities of 105 and 107 ml-1) within the precipitation medium. We also tested the effect of a trace mixture of propionic, isovaleric, formic and butyric acids (total concentration 0.035 mM). The experiments showed that the general progression of mineral precipitation was similar under all of the conditions, with initial formation of amorphous calcium carbonate, and transformation to poorly crystalline hydroxyapatite (HAP) by the end of the week-long experiments. The presence of the bacterial cells appeared to delay precipitation, although by the end of 7 days the overall extent of precipitation was similar for all of the treatments. The stoichiometry of the final precipitates as well as results of Rietveld refinement of x-ray diffraction data indicated that the treatments including organic acids and bacterial cells resulted in increased distortion of the HAP crystal lattice, with the higher concentration of cells resulting in the greatest distortion. Uptake of Sr into the phosphate minerals was decreased in the treatments with cells and organic acids, compared to the control. The results of the experiments enable a greater understanding of the challenges associated with phosphate-based remediation schemes for contaminated environments.

  1. Preparation of new morphological ZnO and Ce-doped ZnO

    SciTech Connect (OSTI)

    Chelouche, A.; Djouadi, D.; Aksas, A. [Laboratoire de Génie de l'Environnement, Université A. Mira de Béjaia, Route de Targua Ouzemmour Béjaia (Algeria)

    2013-12-16

    ZnO micro-tori and cerium doped hexangulars ZnO have been prepared by the sol-gel method under methanol hypercritical conditions of temperature and pressure. X-ray diffraction (XRD) measurement has revealed the high crystalline quality and the nanometric size of the samples. Scanning electron microscopy (SEM) has shown that the ZnO powder has a torus-like shape while that of ZnO:Ce has a hexangular-like shape, either standing free or inserted into the cores of ZnO tori. Transmission electron microscopy (TEM) has revealed that the ZnO particles have sizes between 25 and 30 nm while Ce-doped ZnO grains have diameters ranging from 75 nm to 100 nm. Photoluminescence spectra at room temperature of the samples have revealed that the introduction of cerium in ZnO reduces the emission intensity lines, particularly the ZnO red and green ones.

  2. PSD Methods Comparison and Discrimination Efficiency Study for LaBr3:Ce Detector

    E-Print Network [OSTI]

    Cang, Jirong; Zeng, Zhi; Cheng, Jianping; Liu, Yinong; Li, Junli

    2015-01-01

    LaBr3:Ce scintillator has been widely studied for nuclear spectroscopy because of its optimal energy resolution (efficient and a potential method to suppress the alpha background from the 227Ac. In this paper, a detailed comparison of 3 digital PSD algorithms, the Charge Comparison Method, the Mean Time Method and the Gamma-Alpha Model Analysis Method, for alpha and gamma discrimination in LaBr3:Ce was done. The algorithm parameters and discrimination efficiency were analyzed and optimized for each method. Moreover, for the CCM, the correlation between the CCM feature value distribution and the total charge (energy) was quantitatively analyzed, and a fitting equation of the correlation is inferred and verified with experiment. With the equation, an energy-dependent threshold was chosen to optimize the discrim...

  3. Single to Multiquasiparticle Excitations in the Itinerant Helical Magnet CeRhIn5

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stock, C.; Rodriguez-Rivera, J. A.; Schmalzl, K.; Rodriguez, E. E.; Stunault, A.; Petrovic, C.

    2015-06-19

    Neutron scattering is used to measure the quantum spin fluctuations in CeRhIn5 - the parent material of the eXIn5 superconducting series. Out-of-plane spin fluctuations are gapped and localized in momentum, similar to the spin excitons in CeCoIn5. The in-plane fluctuations consist of sharp spin-wave excitations parameterized by a nearest neighbor exchange JRKKY =0.88 ± 0.05 meV that crossover to a temporally and spatially broad multiparticle spectrum with energies of ~ 2 × JRKKY . This continuum represents composite fluctuations that illustrate the breakdown of single magnons originating from the delicate energy balance between localized 4f and itinerant behavior in amore »heavy metal. The experiment therefore shows how quasiparticle behavior is changed by the close proximity of quantum criticality.« less

  4. Reactivity and reaction intermediates for acetic acid adsorbed on CeO2(111)

    SciTech Connect (OSTI)

    Calaza, Florencia; Chen, Tsung-Liang; Mullins, David R; Xu, Ye; Overbury, Steven {Steve} H

    2015-01-01

    Adsorption and reaction of acetic acid on a CeO2(1 1 1) surface was studied by a combination of ultra-highvacuum based methods including temperature desorption spectroscopy (TPD), soft X-ray photoelectronspectroscopy (sXPS), near edge X-ray absorption spectroscopy (NEXAFS) and reflection absorption IRspectroscopy (RAIRS), together with density functional theory (DFT) calculations. TPD shows that thedesorption products are strongly dependent upon the initial oxidation state of the CeO2surface, includingselectivity between acetone and acetaldehyde products. The combination of sXPS and NEXAFS demon-strate that acetate forms upon adsorption at low temperature and is stable to above 500 K, above whichpoint ketene, acetone and acetic acid desorb. DFT and RAIRS show that below 500 K, bridge bondedacetate coexists with a moiety formed by adsorption of an acetate at an oxygen vacancy, formed bywater desorption.

  5. Public Administration Department SPRING 2014 Schedule C = Core, MP = Management Perceptive, CE = Culminating Experience

    E-Print Network [OSTI]

    Design & Change Management Hybrid: 7:30pm--8:45pm on 1/27 & 3/17; 6:00pm--8:45pm on 2/10, 2/24, 4/7, 411/4/2014 TENTATIVE Public Administration Department SPRING 2014 Schedule C = Core, MP = Management Perceptive, CE = Culminating Experience MPA Elective Emphases Courses: PM = Public Management, NP = Nonprofit

  6. Investigation into Nanostructured Lanthanum Halides and CeBr{sub 3} for Nuclear Radiation Detection

    SciTech Connect (OSTI)

    Guss, P., Guise, R., Mukhopadhyay, S., Yuan, D.

    2011-06-22

    This slide-show presents work on radiation detection with nanostructured lanthanum halides and CeBr{sub 3}. The goal is to extend the gamma energy response on both low and high-energy regimes by demonstrating the ability to detect low-energy x-rays and relatively high-energy activation prompt gamma rays simultaneously using the nano-structured lanthanum bromide, lanthanum fluoride, cerium bromide, or other nanocrystal material. Homogeneous and nano structure cases are compared.

  7. One-dimensional chain structures produced by Ce on Si(111)

    E-Print Network [OSTI]

    Kim, Sehun

    of rare-earth metals on semicon- ductors, especially Si [1], by self-assembly has at- tracted considerable) surfaces have been reported for various rare-earth metals (e.g., Ce [6­8], Sm [9], Er [10,11], Eu [12 structures have been reported for many rare-earth metals, such as 3 · 2, 5 · 1, and 7 · 1 for Sm, 5 · 2

  8. Synthesis of Transient Climate Evolution of the last 21-kyr (SynTraCE-21)

    SciTech Connect (OSTI)

    Zhengyu Liu

    2011-05-06

    Climate evolution in the last 21,000 years provides critical observations for testing state-of-the-art climate models on the simulation of climate evolution and abrupt climate changes. Proxy evidences and new modeling activities have led to rapid advances in our understanding of climate change for this past time period. This funding helps to support the first international SynTraCE-21k workshop at Mount Hood, Oregon from 10-13 October, 2010.

  9. Remarkably robust and correlated coherence and antiferromagnetism in (Ce1-x Lax)Cu?Ge?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hodovanets, H.; Bud’ko, S.? L.; Straszheim, W.? E.; Taufour, V.; Mun, E.? D.; Kim, H.; Flint, R.; Canfield, P.? C.

    2015-06-08

    We present magnetic susceptibility, resistivity, specific heat, and thermoelectric power measurements on (Ce1-x Lax)Cu?Ge? single crystals (0 ? x ? 1). With La substitution, the antiferromagnetic temperature TN is suppressed in an almost linear fashion and moves below 0.36 K, the base temperature of our measurements for x > 0.8. Surprisingly, in addition to robust antiferromagnetism, the system also shows low temperature coherent scattering below Tcoh up to ~ 0.9 of La, indicating a small percolation limit ~ 9% of Ce. Tcoh as a function of magnetic field was found to have different behavior for x more »> 0.9. Remarkably, (Tcoh)² at H = 0 was found to be linearly proportional to TN. The jump in the magnetic specific heat ?Cm at TN as a function of TK/TN for (Ce1-x Lax)Cu?Ge? follows the theoretical prediction based on the molecular field calculation for the S = 1/2 resonant level model.« less

  10. Hydrides of CeNi/sub 5/, MmNi/sub 5/, Ca/sub 0/ /sub 2/(Ce/sub 0/ /sub 65/Mm/sub 0/ /sub 35/)/sub 0/ /sub 8/Ni/sub 5/, Ca/sub 0/ /sub 2/Ce/sub 0/ /sub 8/Ni/sub 5/, Ca/sub 0/ /sub 2/Mm/sub 0/ /sub 8/Ni/sub 5/, and mixed CeNi/sub 5//MmNi/sub 5/

    SciTech Connect (OSTI)

    Lakner, J.F.; Chow, T.S.

    1982-09-01

    Six intermetallic alloys (CeNi/sub 5/, MmNi/sub 5/, Ca/sub 0/ /sub 2/(Ce/sub 0/ /sub 65/Mm/sub 0/ /sub 35/)/sub 0/ /sub 8/Ni/sub 5/, Ca/sub 0/ /sub 2/Ce/sub 0/ /sub 8/Ni/sub 5/, Ca/sub 0/ /sub 2/Mm/sub 0/ /sub 8/Ni/sub 5/, and a mixed alloy, CeNi/sub 5//MmNi/sub 5/) were investigated with respect to their suitability to provide high hydrogen capacity and their potential for use in providing substantial hydrogen pressure at both low and high temperatures. A second phase of our investigation dealt with ball-milling and hydriding and dehydriding cycles to produce fine particles for use in hydride powder transfer studies. A summary of several Van't Hoff plots is also included for hydride-forming alloys.

  11. Specific heat of CeRhIn5: Pressure-driven evolution of the ground state from antiferromagnetism to superconductivity

    E-Print Network [OSTI]

    2001-01-01

    Specific Heat of CeRhIn5: Pressure–Driven Evolution of the32306 Measurements of the specific heat of antiferromagneticsee text). Fig. 2. (a) The specific heat, for representative

  12. Emission properties and back-bombardment for CeB{sub 6} compared to LaB{sub 6}

    SciTech Connect (OSTI)

    Bakr, Mahmoud; Kawai, M.; Kii, T.; Zen, H.; Masuda, K.; Ohgaki, H.

    2015-02-14

    The emission properties of CeB{sub 6} compared to LaB{sub 6} thermionic cathodes have been measured using an electrostatic DC gun. Obtaining knowledge of the emission properties is the first step in understanding the back-bombardment effect that limits wide usage of thermionic radio-frequency electron guns. The effect of back-bombardment electrons on CeB{sub 6} compared to LaB{sub 6} was studied using a numerical simulation model. The results show that for 6??s pulse duration with input radio-frequency power of 8 MW, CeB{sub 6} should experience 14% lower temperature increase and 21% lower current density rise compared to LaB{sub 6}. We conclude that CeB{sub 6} has the potential to become the future replacement for LaB{sub 6} thermionic cathodes in radio-frequency electron guns.

  13. Impact of the CE mark approval on exit opportunities and validation for early stage medical device companies

    E-Print Network [OSTI]

    Kothari, Ashish (Ashish Shrikant)

    2011-01-01

    The aim of this thesis was to look at the impact of acquiring the CE marking approval on the outcome of early stage medical device companies, specifically its impact on strategic acquisition opportunities and on valuation. ...

  14. Making the Best Use of What you Have Asia Intellectual Capital Alliances a te ectua Cap ta a ce

    E-Print Network [OSTI]

    BYOBBYOB ­ Making the Best Use of What you Have Asia Intellectual Capital Alliances a te ectua Cap ta a ce 24 October 2011 Copyright © 2011 Asia Intellectual Capital Alliance. All rights reserved. #12

  15. Late Antique Plague Ships: Sixth-Century C.E. Trade Routes and Their Role in Transmitting the Justinianic Plague 

    E-Print Network [OSTI]

    Kofahl, Meko

    2013-07-29

    The major European epidemic of bubonic plague in the sixth century C.E. – named for the ruling Byzantine emperor, Justinian – devastated the empire at the same time that outside pressures in the form of Goths, Vandals, ...

  16. Report TKK-ENY-9 Mineral carbonation for long-term storage of CO2

    E-Print Network [OSTI]

    Zevenhoven, Ron

    Report TKK-ENY-9 Mineral carbonation for long-term storage of CO2 from flue gases Jens Kohlmann 1 University of Technology was "Mineral carbonation for long-term storage of CO2 from flue gases"; the progress storage by mineral carbonation in Finland (CO2 lagring genom mineral karbonering i Finland)" Ron

  17. Study of Interactions Between Microbes and Minerals by Scanning Transmission X-Ray Microscopy (STXM)

    E-Print Network [OSTI]

    Benzerara, K; Tyliszczak, T

    2007-01-01

    Study of Interactions Between Microbes and Minerals by Scanning Transmission X-Ray Microscopy (STXM)

  18. Net mineralization of N at deeper soil depths as a potential mechanism for sustained forest production

    E-Print Network [OSTI]

    Net mineralization of N at deeper soil depths as a potential mechanism for sustained forest of microbial consumption of mineral N were reduced relative to production. Overall, up to 60% of potential gross N mineralization and 100% of potential net N mineralization occurred below 15 cm depth

  19. Rock Cycle and Rocks Lab Rocks are aggregates of one or many minerals.

    E-Print Network [OSTI]

    Li, X. Rong

    Rock Cycle and Rocks Lab Rocks are aggregates of one or many minerals. Three types of rocks: A of their sizes, shapes and arrangement. Rule of Thumb: The size of mineral crystals in an igneous rock may, there is not enough time for large mineral crystals to form (e.g. obsidian) Igneous Rock Mineral Compositions

  20. 4.4 Nanoscale: Mineral Weathering Boundary RI Dorn, Arizona State University, Tempe, AZ, USA

    E-Print Network [OSTI]

    Dorn, Ron

    4.4 Nanoscale: Mineral Weathering Boundary RI Dorn, Arizona State University, Tempe, AZ, USA SJ-scattered detector. Biotic weathering Mineral weathering caused by life, including bacteria, fungi, algae, plants of elements such as silica or iron. Etching of minerals Mineral dissolution is not an even produce; areas

  1. V-Miner: Using Enhanced Parallel Coordinates to Mine Product Design and Test Data 1

    E-Print Network [OSTI]

    Illinois at Chicago, University of

    V-Miner: Using Enhanced Parallel Coordinates to Mine Product Design and Test Data 1 Kaidi Zhao patterns can be easily detected visually. The Visual Miner (V-Miner) software includes both automated or data mining. This paper begins with an introduction to the proposed techniques and the V-Miner system

  2. PTYS 109 LAB EXPLORATION AND DISCOVERY IN PLANETARY SCIENCE ROCKS AND MINERALS 133

    E-Print Network [OSTI]

    Cohen, Barbara Anne

    PTYS 109 LAB EXPLORATION AND DISCOVERY IN PLANETARY SCIENCE ROCKS AND MINERALS 133 Rocks and Minerals I. OBJECTIVES One of the many ways to study Earth is by examining the rocks that make up its types of rocks and minerals; · determine the formation and the history of each rock and mineral; · infer

  3. Effect of oxygen vacancy on half metallicity in Ni-doped CeO{sub 2} diluted magnetic semiconductor

    SciTech Connect (OSTI)

    Saini, Hardev S. Saini, G. S. S.; Singh, Mukhtiyar; Kashyap, Manish K.

    2015-05-15

    The electronic and magnetic properties of Ni-doped CeO{sub 2} diluted amgentic semiconductor (DMS) including the effect of oxygen vacancy (V{sub o}) with doping concentration, x = 0.125 have been calculated using FPLAPW method based on Density Functional Theory (DFT) as implemented in WIEN2k. In the present supercell approach, the XC potential was constructed using GGA+U formalism in which Coulomb correction is applied to standard GGA functional within the parameterization of Perdew-Burke-Ernzerhof (PBE). We have found that the ground state properties of bulk CeO{sub 2} compound have been modified significantly due to the substitution of Ni-dopant at the cation (Ce) site with/without V{sub O} and realized that the ferromagnetism in CeO{sub 2} remarkably depends on the V{sub o} concentrations. The presence of V{sub o}, in Ni-doped CeO{sub 2}, can leads to strong ferromagnetic coupling between the nearest neighboring Ni-ions and induces a HMF in this compound. Such ferromagnetic exchange coupling is mainly attributed to spin splitting of Ni-d states, via electrons trapped in V{sub o}. The HMF characteristics of Ni-doped CeO{sub 2} including V{sub o} makes it an ideal material for spintronic devices.

  4. Effect of Sodium on the Catalytic Properties of VOx/CeO2 Catalysts for Oxidative Dehydrogenation of Methanol

    SciTech Connect (OSTI)

    Li, Yan; Wei, Zhehao; Sun, Junming; Gao, Feng; Peden, Charles HF; Wang, Yong

    2013-03-21

    A series of VOx/CeO2 catalysts with various sodium loadings (Na/V ratio from 0 to 1) has been studied for oxidative dehydrogenation (ODH) of methanol. The effect of sodium on the surface structure, redox properties, and surface acidity/basicity of VOx/CeO2 was investigated using hydrogen temperature-programmed reduction (H2-TPR), Raman spectroscopy, and Diffuse Reflectance Infrared Fourier Transform spectroscopy (DRIFT). The experimental results indicate that the effect of sodium on VOx/CeO2 is highly dependent on the Na/V ratio. At a low Na/V ratio (Na/V<0.25), sodium addition only slightly decreases the redox properties of VOx/CeO2 and has little effect on its activity and selectivity to formaldehyde, even though the Brönsted acidity is almost completely eliminated at a Na/V ratio of 0.25. At a high Na/V ratio (Na/V>0.25), sodium addition greatly alters the nature of the active sites by V-O-Ce bond cleavage and V-O-Na bond formation, leading to significantly reduced activity of the VOx/CeO2 catalysts. At Na/V>0.25, the selectivity to formaldehyde also decreases with increasing Na/V ratio due to: (1) the suppressed reducibility of VOx, and (2) increased basicity leading to increased CO2.

  5. Diagenesis and clay mineral formation at Gale Crater, Mars

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bridges, J. C.; Schwenzer, S. P.; Leveille, R.; Westall, F.; Wiens, R. C.; Mangold, N.; Bristow, T.; Edwards, P.; Berger, G.

    2015-01-18

    The Mars Science Laboratory rover Curiosity found host rocks of basaltic composition and alteration assemblages containing clay minerals at Yellowknife Bay, Gale Crater. On the basis of the observed host rock and alteration minerals, we present results of equilibrium thermochemical modeling of the Sheepbed mudstones of Yellowknife Bay in order to constrain the formation conditions of its secondary mineral assemblage. Building on conclusions from sedimentary observations by the Mars Science Laboratory team, we assume diagenetic, in situ alteration. The modeling shows that the mineral assemblage formed by the reaction of a CO?-poor and oxidizing, dilute aqueous solution (Gale Portage Water)more »in an open system with the Fe-rich basaltic-composition sedimentary rocks at 10–50°C and water/rock ratio (mass of rock reacted with the starting fluid) of 100–1000, pH of ~7.5–12. Model alteration assemblages predominantly contain phyllosilicates (Fe-smectite, chlorite), the bulk composition of a mixture of which is close to that of saponite inferred from Chemistry and Mineralogy data and to that of saponite observed in the nakhlite Martian meteorites and terrestrial analogues. To match the observed clay mineral chemistry, inhomogeneous dissolution dominated by the amorphous phase and olivine is required. We therefore deduce a dissolving composition of approximately 70% amorphous material, with 20% olivine, and 10% whole rock component.« less

  6. Carbon K-edge Spectra of Carbonate Minerals

    SciTech Connect (OSTI)

    Brandes, J.; Wirick, S; Jacobsen, C

    2010-01-01

    Carbon K-edge X-ray spectroscopy has been applied to the study of a wide range of organic samples, from polymers and coals to interstellar dust particles. Identification of carbonaceous materials within these samples is accomplished by the pattern of resonances in the 280-320 eV energy region. Carbonate minerals are often encountered in the study of natural samples, and have been identified by a distinctive resonance at 290.3 eV. Here C K-edge and Ca L-edge spectra from a range of carbonate minerals are presented. Although all carbonates exhibit a sharp 290 eV resonance, both the precise position of this resonance and the positions of other resonances vary among minerals. The relative strengths of the different carbonate resonances also vary with crystal orientation to the linearly polarized X-ray beam. Intriguingly, several carbonate minerals also exhibit a strong 288.6 eV resonance, consistent with the position of a carbonyl resonance rather than carbonate. Calcite and aragonite, although indistinguishable spectrally at the C K-edge, exhibited significantly different spectra at the Ca L-edge. The distinctive spectral fingerprints of carbonates provide an identification tool, allowing for the examination of such processes as carbon sequestration in minerals, Mn substitution in marine calcium carbonates (dolomitization) and serpentinization of basalts.

  7. Lab 1 Mineral Utility Lab notes The physical world is made up of a vast number of different minerals. Later on in

    E-Print Network [OSTI]

    Li, X. Rong

    Lab 1 Mineral Utility Lab notes The physical world is made up of a vast number of different minerals. Later on in the course, we will learn about some of the more common rock-forming ones them, e.g. gold, silver, and even salt or "halite". These and most other minerals have to be extracted

  8. Iowa State Mining and Mineral Resources Research Institute

    SciTech Connect (OSTI)

    Not Available

    1990-08-01

    This final report describes the activities of the Iowa State Mining and Mineral Resources Research Institute (ISMMRRI) at Iowa State University for the period July 1, 1989, to June 30, 1990. Activities include research in mining- and mineral-related areas, education and training of scientists and engineers in these fields, administration of the Institute, and cooperative interactions with industry, government agencies, and other research centers. During this period, ISMMRRI has supported research efforts to: (1) Investigate methods of leaching zinc from sphalerite-containing ores. (2) Study the geochemistry and geology of an Archean gold deposit and of a gold-telluride deposit. (3) Enchance how-quality aggregates for use in construction. (4) Pre-clean coal by triboelectric charging in a fluidized-bed. (5) Characterize the crystal/grain alignment during processing of yttrium-barium-copper-perovskite (1-2-3) superconductors. (5) Study the fluid inclusion properties of a fluorite district. (6) Study the impacts of surface mining on community planning. (7) Assess the hydrophobicity of coal and pyrite for beneficiation. (8) Investigate the use of photoacoustic absorption spectroscopy for monitoring unburnt carbon in the exhaust gas from coal-fired boilers. The education and training program continued within the interdepartmental graduate minor in mineral resources includes courses in such areas as mining methods, mineral processing, industrial minerals, extractive metallurgy, coal science and technology, and reclamation of mined land. In addition, ISMMRRI hosted the 3rd International Conference on Processing and Utilization of High-Sulfur Coals in Ames, Iowa. The Institute continues to interact with industry in order to foster increased cooperation between academia and the mining and mineral community.

  9. Surface-structure sensitivity of CeO2 nanocrystals in photocatalysis and enhancing the reactivity with nanogold

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lei, Wanying; Zhang, Tingting; Gu, Lin; Liu, Ping; Rodriguez, José A.; Liu, Gang; Liu, Minghua

    2015-06-19

    Structure–function correlations are a central theme in heterogeneous (photo)catalysis. In this research, using aberration-corrected scanning transmission electron microscopy (STEM), the atomic surface structures of well-defined one-dimensional (1D) CeO2 nanorods (NRs) and 3D nanocubes (NCs) are directly visualized at subangstrom resolution. CeO2 NCs predominantly expose the {100} facet, with {110} and {111} as minor cutoff facets at the respective edges and corners. Notably, the outermost surface layer of the {100} facet is nearly O-terminated. Neither surface relaxations nor reconstructions on {100} are observed, indicating unusual polarity compensation, which is primarily mediated by near-surface oxygen vacancies. The surface of CeO2 NRs ismore »highly stepped, with the enclosed {110} facet exposing Ce cations and O anions on terraces. On the basis of STEM profile-view imaging and electronic structure analysis, the photoreactivity of CeO2 nanocrystals toward aqueous methyl orange degradation under UV is revealed to be surface-structure-sensitive, following the order: {110} >> {100}. The underlying surface-structure sensitivity can be attributed to the variation in low-coordinate surface cerium cations between {110} and {100} facets. To further enhance light absorption, Au nanoparticles (NPs) are deposited on CeO2 NRs to form Au/CeO2 plasmonic nanocomposites, which dramatically promotes the photoreactivity that is Au particle size- and excitation light wavelength-dependent. The mechanisms responsible for the enhancement of photocatalytic activity are discussed, highlighting the crucial role of photoexcited charge carrier transfer.« less

  10. Structure and magnetic properties of Ba{sub 5}Ce{sub 1.25}Mn{sub 3.75}O{sub 15}, a new 10H-polytype in the Ba-Ce-Mn-O system

    SciTech Connect (OSTI)

    Macias, Mario A.; Mentre, Olivier; Cuello, Gabriel J.; Gauthier, Gilles H.

    2013-02-15

    Based on the peculiar magnetic properties that are observed in pseudo one-dimensional manganites, we decided to synthesize the new Ba{sub 5}Ce{sub 1.25}Mn{sub 3.75}O{sub 15} compound. The preparation was performed by solid state reaction in air at about 1350 Degree-Sign C, for which we found that the compound crystallizes in a hexagonal symmetry with space group P6{sub 3}/mmc (No-194) and cell parameters a=b=5.7861(2) A and c=23.902(1) A. The structural description was correlated with neutron diffraction and bond valence calculations, confirming the presence of Ce{sup 4+} and Mn{sup 4+} segregated in the different crystallographic positions. Ba{sub 5}Ce{sub 1.25}Mn{sub 3.75}O{sub 15} displays evidence for strong AFM couplings already set at room temperature. The main arrangement of Mn{sup 4+} in magnetically isolated tetramers of face-sharing octahedra is responsible for a metamagnetic-like transition around 50 K. - Graphical abstract: The new Ba{sub 5}Ce{sub 1.25}Mn{sub 3.75}O{sub 15} polytype shows strong AFM couplings in magnetically isolated [Ce{sub 0.25}Mn{sub 3.75}O{sub 15}] tetramers of face-sharing octahedral, resulting in a metamagnetic-like transition around 50 K. Highlights: Black-Right-Pointing-Pointer Ba{sub 5}Ce{sub 1.25}Mn{sub 3.75}O{sub 15}, a new 10H polytype, has been prepared in the Ba-Ce-Mn-O system. Black-Right-Pointing-Pointer The compound crystallizes in the P6{sub 3}/mmc space group with (cchhh){sub 2} stacking sequence. Black-Right-Pointing-Pointer [Ce{sub 0.25}Mn{sub 3.75}O{sub 15}] tetramers are separated by [CeO{sub 6}] octahedra in the structure. Black-Right-Pointing-Pointer Instead of robust AFM ordering, a metamagnetic-like transition is found around 50 K.

  11. Mineral Deformation at Earth's Core-Mantle Boundary

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines light on77 PAGE OFDetectionBenchmark Performance 111.1MineralMineral

  12. Pulse studies to decipher the role of surface morphology in CuO/CeO? nanocatalysts for the water gas shift reaction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rodriguez, Jose A.; Zhao, Fuzhen; Liu, Zongyuan; Xu, Wenqian; Yao, Siyu; Si, Rui; Johnston-Peck, Aaron C.; Martinez-Arias, Arturo; Hanson, Jonathan C.; Senanayake, Sanjaya D.

    2015-01-23

    The water-gas shift reaction (WGS, CO + H?O ? CO?) was studied over CuO/CeO? catalysts with two different ceria particle morphohologies, in the form of nanospheres (ns) and nanocubes (nc). To understand the strong dependence of the WGS reaction activity on the ceria nanoshapes, pulses of CO (without and with water vapor) were employed during in situ X-ray diffraction (XRD) and X-ray absoprtion near edge structure (XANES) measurements done to characterize the catalysts. The results showed that CuO/CeO? (ns) exhibited a substantially better activity than CuO/CeO? (nc). The higher activity was associated with the unique properties of CuO/CeO? (ns), suchmore »as the easier reduction of highly dispersed CuO to metallic Cu, the stability of metallic Cu and a larger concentration Ce³? in CeO? (ns).« less

  13. Pulse studies to decipher the role of surface morphology in CuO/CeO? nanocatalysts for the water gas shift reaction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rodriguez, Jose A. [Brookhaven National Lab. (BNL), Upton, NY (United States); Zhao, Fuzhen [South-Central Univ. for Nationalities, Wuhan, Hubei (China); Brookhaven National Lab., Upton, NY (United States); Liu, Zongyuan [Brookhaven National Lab. (BNL), Upton, NY (United States); Xu, Wenqian [Brookhaven National Lab. (BNL), Upton, NY (United States); Yao, Siyu [Brookhaven National Lab. (BNL), Upton, NY (United States); Si, Rui [Brookhaven National Lab. (BNL), Upton, NY (United States); Johnston-Peck, Aaron C. [Brookhaven National Lab. (BNL), Upton, NY (United States); Martinez-Arias, Arturo [Inst. de Catalisis y Petroleoquimica, Consejo Superior de Investigaciones Cientificas, Madrid (Spain); Hanson, Jonathan C. [Brookhaven National Lab. (BNL), Upton, NY (United States); Senanayake, Sanjaya D. [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2015-03-01

    The water-gas shift reaction (WGS, CO + H?O ? CO?) was studied over CuO/CeO? catalysts with two different ceria particle morphohologies, in the form of nanospheres (ns) and nanocubes (nc). To understand the strong dependence of the WGS reaction activity on the ceria nanoshapes, pulses of CO (without and with water vapor) were employed during in situ X-ray diffraction (XRD) and X-ray absoprtion near edge structure (XANES) measurements done to characterize the catalysts. The results showed that CuO/CeO? (ns) exhibited a substantially better activity than CuO/CeO? (nc). The higher activity was associated with the unique properties of CuO/CeO? (ns), such as the easier reduction of highly dispersed CuO to metallic Cu, the stability of metallic Cu and a larger concentration Ce³? in CeO? (ns).

  14. XRD, lead equivalent and UV-VIS properties study of Ce and Pr lead silicate glasses

    SciTech Connect (OSTI)

    Alias, Nor Hayati, E-mail: norhayati@nuclearmalaysia.gov.my; Abdullah, Wan Shafie Wan, E-mail: norhayati@nuclearmalaysia.gov.my; Isa, Norriza Mohd, E-mail: norhayati@nuclearmalaysia.gov.my; Isa, Muhammad Jamal Md, E-mail: norhayati@nuclearmalaysia.gov.my; Zali, Nurazila Mat; Abdullah, Nuhaslinda Ee [Malaysian Nuclear Agency, 43000, Bangi, Kajang, Selangor (Malaysia); Muhammad, Azali [Malaysian Society for Non-Destructive Testing (Malaysia)

    2014-02-12

    In this work, Cerium (Ce) and Praseodymium (Pr) containing lead silicate glasses were produced with 2 different molar ratios low (0.2 wt%) and high (0.4wt%). These types of glasses can satisfy the characteristics required for radiation shielding glasses and minimize the lead composition in glass. The radiation shielding properties of the synthesized glasses is explained in the form of lead equivalent study. The XRD diffraction and UV-VIS analysis were performed to observe the structural changes of the synthesis glasses at 1.5 Gy gamma radiation exposures.

  15. DFT+U Study of CeO2 and Its Native Defects

    E-Print Network [OSTI]

    Huang, Bolong; Gillen, Roland; Robertson, John

    2014-10-14

    , Frenkel defect, pseudopotential transferability, oxidation catalyst 1. Introduction CeO2 is an important lanthanide oxide which is widely used as an oxygen buffer in car exhaust catalysts1, as a fast ion conductor in solid state fuel cells2, as a... as optimization of pseudopotentials47. The PBE functional was chosen for PBE+U calculations with a kinetic cutoff energy of 750eV, which expands the valence electrons states in a plane-wave basis set. The ensemble DFT (EDFT) method of Marzari et al48 is used...

  16. Nanostructured LaF{sub 3}:Ce Quantum Dot Nuclear Radiation Detector

    SciTech Connect (OSTI)

    Guss, P., Guise, R., Reed, M., Mukhopadhyay, S., Yuan, D.

    2010-11-01

    Many radioactive isotopes have low energy X-rays and high energy gamma rays of interest for detection. The goal of the work presented was to demonstrate the possibility of measuring both low-energy X-rays and relatively high-energy gamma rays simultaneously using the nano-structured lanthanum bromide, lanthanum fluoride, or cerium bromide. The key accomplishments of the project was the building and acquisition of the LaF3:Ce nanocomposite detectors. Nanocomposite detectors are sensitive to {gamma}’s as well as n’s and X-rays.

  17. DOI-BLM-ID-110-2009-3825-CE | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTIONRobertsdale, Alabama (UtilityInstruments Inc Jump to:67-2006-12 Jump to:110-2009-3825-CE Jump to:

  18. BaCe1-xPdxO3-(0 e x e 0.1): Redox Controlled Ingress and Egress of Palladium in a Perovskite

    E-Print Network [OSTI]

    Rappe, Andrew M.

    BaCe1-xPdxO3- (0 e x e 0.1): Redox Controlled Ingress and Egress of Palladium in a Perovskite Jun-ray photoelectron spectroscopy that Pd2+ ions can be substituted for Ce in perovskite BaCeO3 and that, under description of the structure. The Pd2+-containing perovskite phases extrude elemental face-centered cubic

  19. Nickel deficiency in RENi2-xP2 (RE=La, Ce, Pr). Combined crystallographic and physical property studies

    SciTech Connect (OSTI)

    Bauer, Eric D; Ronning, Filip; Thompson, Joe D; Sarrao, John L; Bobev, S; Xia, S

    2008-01-01

    Large single crystals from RENi{sub 2-x}P{sub 2} (RE = La, Ce, Pr) were synthesized from the pure elements using Sn as a metal flux, and their structures were established by X-ray crystallography. The title compounds were confirmed to crystallize in the body-centered tetragonal ThCr{sub 2}Si{sub 2} structure type (space group I4/mmm (No. 139); Pearson's symbol tI10), but with a significant stoichiometry breadth with respect to the transition metal. Systematic synthetic work, coupled with accurate structure refinements indicated strong correlation between the degree of Ni-deficiency and the reaction conditions. For four different PrNi{sub 2-x}P{sub 2} (x {le} 0.5) samples, temperature dependent dc magnetization measurements indicated typical local moment 4f-magnetism and a stable Pr{sup 3+} ground state. Field-dependent heat capacity data confirmed a ferromagnetic order at low temperature, and the variations of T{sub c} with the concentration of Ni defects are discussed. LaNi{sub 2-x}P{sub 2}, as expected was found to be Pauli-like paramagnetic in the studied temperature regime, while the Ce-analog CeNi{sub 2-x}P{sub 2} (x = 0.28(1)) showed the characteristics of a mixed valent Ce{sup 3+}/Ce{sup 4+} system with a possible Kondo temperature on the order of 230 K.

  20. Electronic structure of the heavy-fermion caged compound Ce?Pd??X? (X = Si, Ge) studied by density functional theory and photoelectron spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yamaoka, Hitoshi; Jarrige, Ignace; Schwier, Eike F.; Arita, Masashi; Shimada, Kenya; Tsujii, Naohito; Jiang, Jian; Hayashi, Hirokazu; Iwasawa, Hideaki; Namatame, Hirofumi; et al

    2015-03-30

    The electronic structure of Ce?Pd??X? (X = Si, Ge) has been studied using detailed density functional theory (DFT) calculations and high-resolution photoelectron spectroscopy (PES) measurements. The orbital decomposition of the electronic structure by DFT calculations indicates that Ce atoms at the (8c) site surrounded by 16 Pd atoms have a more localized nature and a tendency to be magnetic. Ce atoms in the (4a) site surrounded by 12 Pd and 6 X atoms, on the other, show only a negligible magnetic moment. In the photoemission valence-band spectra we observe a strong f? (Ce??) component with a small fraction of f¹more »(Ce³?) component. The spectral weight of f¹ component near the Fermi level Ce?Pd??Si? is stronger than that for Ce?Pd??Ge? at the 4d-4f resonance, suggesting stronger c-f hybridization in the former. This may hint to the origin of the large electronic specific coefficient of Ce?Pd??Si? compared to Ce?Pd??Ge?.« less

  1. Electronic structure of the heavy-fermion caged compound Ce3Pd20X6(X=Si,Ge) studied by density functional theory and photoelectron spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yamaoka, Hitoshi; Schwier, Eike F.; Arita, Masashi; Shimada, Kenya; Tsujii, Naohito; Jarrige, Ignace; Jiang, Jian; Hayashi, Hirokazu; Iwasawa, Hideaki; Namatame, Hirofumi; et al

    2015-03-30

    The electronic structure of Ce?Pd??X? (X = Si, Ge) has been studied using detailed density functional theory (DFT) calculations and high-resolution photoelectron spectroscopy (PES) measurements. The orbital decomposition of the electronic structure by DFT calculations indicates that Ce atoms at the (8c) site surrounded by 16 Pd atoms have a more localized nature and a tendency to be magnetic. Ce atoms in the (4a) site surrounded by 12 Pd and 6 X atoms, on the other, show only a negligible magnetic moment. In the photoemission valence-band spectra we observe a strong f? (Ce??) component with a small fraction of f¹more »(Ce³?) component. The spectral weight of f¹ component near the Fermi level Ce?Pd??Si? is stronger than that for Ce?Pd??Ge? at the 4d-4f resonance, suggesting stronger c-f hybridization in the former. This may hint to the origin of the large electronic specific coefficient of Ce?Pd??Si? compared to Ce?Pd??Ge?.« less

  2. Mineral resources of the Sacatar Meadows Wilderness study Area, Tulare and Inyo counties, California

    SciTech Connect (OSTI)

    Diggles, M.F.; Frisken, J.G.; Griscom, A.; Kuizon, L.

    1988-01-01

    At the request of the US Bureau of Land Management, approximately 11,447 acres of the Sacatar Meadows Wilderness Study Area were evaluated for mineral resources (known) and mineral resource potential (undiscovered). No mineral resources were identified. There are five areas of low mineral resource potential (tungsten and molybdenum) in and near the study area. The host rocks for these minerals are Mesozoic-age granitic rocks of the Sierra Nevada Batholith and calcareous metamorphic roof-pendant rocks. The area has no geothermal energy, energy mineral, or oil and gas resource potential.

  3. New Mexico Bureau of Geology & Mineral Resources A DIVISION OF

    E-Print Network [OSTI]

    Borchers, Brian

    , The Barnett Shale in southeastern New Mexico: Distribution, thickness, and source rock characterization: New interpretation and mapping techniques. Broadhead, R.F., 2010, The Woodford Shale in southeastern New MexicoNew Mexico Bureau of Geology & Mineral Resources A DIVISION OF NEW MEXICO INSTITUTE OF MINING

  4. Rheological properties of minerals and rocks Shun-ichiro Karato

    E-Print Network [OSTI]

    1 Rheological properties of minerals and rocks Shun-ichiro Karato Yale University Department Earth" (edited by S. Karato) Wiley-Blackwell #12; 2 SUMMARY Plastic deformation in Earth and planetary. The rheological properties in the upper mantle are controlled mostly by temperature, pressure and water content

  5. Proxies and Measurement Techniques for Mineral Dust in

    E-Print Network [OSTI]

    Fischer, Hubertus

    concentrations, which are typically a factor 100, differ between the methods by up to a factor of 2Proxies and Measurement Techniques for Mineral Dust in Antarctic Ice Cores U R S R U T H , * , C, Centre for Ice and Climate, Niels Bohr Institute, University of Copenhagen, Denmark, Department

  6. KING FAHD UNIVERSITY OF PETROLEUM & MINERALS Dhahran, Saudi Arabia

    E-Print Network [OSTI]

    Abu-Khamsin, Sidqi

    KING FAHD UNIVERSITY OF PETROLEUM & MINERALS Dhahran, Saudi Arabia Basic Properties of Reservoir. INTRODUCTION 1 1.1 The nature of petroleum 1 1.2 The petroleum reservoir 1 1.3 Significance of rock properties) to asphaltenes containing hundreds of carbon atoms. Like coal, petroleum constitutes a prime source

  7. Invest in Your Bones Bone Mineral Calcium and Vitamin D

    E-Print Network [OSTI]

    Invest in Your Bones Bone Mineral Calcium and Vitamin D Leaflet 4 One common misconception is that calcium is only needed for growing children. In reality, both calcium and vitamin D are needed to maintain of calcium from your bones. Vitamin D promotes the absorption of calcium in the gut, which is necessary

  8. Mineral mesopore effects on nitrogenous organic matter Andrew R. Zimmermana,

    E-Print Network [OSTI]

    Chorover, Jon

    as sequestration of pollutants in soils and sediments (Luthy et al., 1997), turnover of natural soil organic carbon that organic matter (OM) may be protected from enzymatic degradation by sequestration within mineral mesopores observations. These results provide a potential mechanism for the selective sequestration and preservation

  9. Lidar fluorosensing of mineral oil spills on the sea surface

    E-Print Network [OSTI]

    Oldenburg, Carl von Ossietzky Universität

    be discriminated from heavy fuel, and from less harmful substances like fish oil or vegetable oil, Fig. 3, whichLidar fluorosensing of mineral oil spills on the sea surface Theo Hengstermann and Rainer Reuter Airborne .fluorosensor measurements over maritime oil spills show that this method enables a sensitive

  10. Mineral density volume gradients in normal and diseased human tissues

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Djomehri, Sabra I.; Candell, Susan; Case, Thomas; Browning, Alyssa; Marshall, Grayson W.; Yun, Wenbing; Lau, S. H.; Webb, Samuel; Ho, Sunita P.; Aikawa, Elena

    2015-04-09

    Clinical computed tomography provides a single mineral density (MD) value for heterogeneous calcified tissues containing early and late stage pathologic formations. The novel aspect of this study is that, it extends current quantitative methods of mapping mineral density gradients to three dimensions, discretizes early and late mineralized stages, identifies elemental distribution in discretized volumes, and correlates measured MD with respective calcium (Ca) to phosphorus (P) and Ca to zinc (Zn) elemental ratios. To accomplish this, MD variations identified using polychromatic radiation from a high resolution micro-computed tomography (micro-CT) benchtop unit were correlated with elemental mapping obtained from a microprobe X-raymore »fluorescence (XRF) using synchrotron monochromatic radiation. Digital segmentation of tomograms from normal and diseased tissues (N=5 per group; 40-60 year old males) contained significant mineral density variations (enamel: 2820-3095mg/cc, bone: 570-1415mg/cc, cementum: 1240-1340mg/cc, dentin: 1480-1590mg/cc, cementum affected by periodontitis: 1100-1220mg/cc, hypomineralized carious dentin: 345-1450mg/cc, hypermineralized carious dentin: 1815-2740mg/cc, and dental calculus: 1290-1770mg/cc). A plausible linear correlation between segmented MD volumes and elemental ratios within these volumes was established, and Ca/P ratios for dentin (1.49), hypomineralized dentin (0.32-0.46), cementum (1.51), and bone (1.68) were observed. Furthermore, varying Ca/Zn ratios were distinguished in adapted compared to normal tissues, such as in bone (855-2765) and in cementum (595-990), highlighting Zn as an influential element in prompting observed adaptive properties. Hence, results provide insights on mineral density gradients with elemental concentrations and elemental footprints that in turn could aid in elucidating mechanistic processes for pathologic formations.« less

  11. Heavy mineral distribution in stream sediment of Tapah area, Perak, Malaysia

    SciTech Connect (OSTI)

    Sibon, Mahat Hj [Jabatan Mineral dan Geosains Malaysia, 40000 Shah Alam, Selangor, Malaysia and Program Geologi, Pusat Pengajian Sains Sekitaran dan Sumber Alam, Fakulti Sains dan Teknologi, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia); Jamil, Habibah; Umor, Mohd Rozi [Program Geologi, Pusat Pengajian Sains Sekitaran dan Sumber Alam, Fakulti Sains dan Teknologi, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia); Hassan, Wan Fuad Wan [Jabatan Geologi, Fakulti Sains Universiti Malaya, 50603 Kuala Lumpur (Malaysia)

    2013-11-27

    This paper aims to provide the overview of occurrence, distribution and origin of the heavy minerals in the study area. A total of 45 selected stream sediment heavy mineral concentrate samples were panned using standard dulangs, dried and separated from other light minerals using bromoform. The heavy minerals were separated into different fractions at different amperes using Frantz Isodynamic magnetic separator. Mineral identification was done using binocular microscope augmented by X-ray diffraction analyses. Mineral abundance data were analysed graphically using triangular diagrams to show their origin. Dominant minerals present in the heavy mineral samples collected are ilmenite, cassiterite, tourmaline, zircon, topaz, and magnetite. The less common minerals, present in trace amounts are hematite, xenotime, allanite, monazite, rutile, anatase, leucoxene, chromite, garnet and olivine. Examination of the heavy mineral assemblage shows that they originated from granite batholiths of the Main Range, Changkat Rembian as well as from the metasedimentary rock in the area. The gold flakes present are found together with cassiterite and topaz indicating that gold originates from the mineralized veins contact-metamorphosed metasedimentary rocks. Almost all samples collected contain cassiterite grains in various amounts. From the mineral assemblage, the source of cassiterite originates from the mineralized quartz veins that cut granitic rocks of Main Range, Changkat Rembian as well as the metasedimentary rock in the area. Greisenized veins containing quartz, mica and tourmaline with the presence of wolframite and arsenopyrite also contribute to the presence of cassiterite in this study area.

  12. Update on the CeC PoP 704 MHz 5-cell cavity cryomodule design and fabrication

    SciTech Connect (OSTI)

    Brutus, J. C.; Belomestnykh, S.; Ben-Zvi, I.; Grimm, T.; Huang, Y.; Jecks, R.; Kelly, M.; Litvinenko, V.; Pinayev, I.; Reid, T.; Skaritka, J.; Snydstrup, L.; Than, R.; Tuozzolo, J.; Xu, W.; Yancey, J.; Gerbick, S.

    2015-05-03

    A 5-cell SRF cavity operating at 704 MHz will be used for the Coherent Electron Cooling Proof of Principle (CeC PoP) system under development for the Relativistic Heavy Ion Collider (RHIC) at Brookhaven National Laboratory. The CeC PoP experiment will demonstrate the new technique of cooling proton and ion beams that may increase the beam luminosity in certain cases, by as much as tenfold. The 704 MHz cavity will accelerate 2 MeV electrons from a 112 MHz SRF gun up to 22MeV. This paper provides an overview of the design, the project status and schedule of the 704 MHz 5-cell SRF for CeC PoP experiment.

  13. Influence of solvent on the morphology and photocatalytic properties of ZnS decorated CeO{sub 2} nanoparticles

    SciTech Connect (OSTI)

    Raubach, Cristiane W. Polastro, Lisânias; Ferrer, Mateus M.; Perrin, Andre; Perrin, Christiane; Albuquerque, Anderson R.; Buzolin, Prescila G. C.; Sambrano, Julio R.; Santana, Yuri B. V. de; Varela, José A.; Longo, Elson

    2014-06-07

    Herein, we report a theoretical and experimental study on the photocatalytic activity of CeO{sub 2} ZnS, and ZnS decorated CeO{sub 2} nanoparticles prepared by a microwave-assisted solvothermal method. Theoretical models were established to analyze electron transitions primarily at the interface between CeO{sub 2} and ZnS. As observed, the particle morphology strongly influenced the photocatalytic degradation of organic dye Rhodamine B. A model was proposed to rationalize the photocatalytic behavior of the prepared decorated systems taking into account different extrinsic and intrinsic defect distributions, including order-disorder effects at interfacial and intra-facial regions, and vacancy concentration.

  14. Bone density and geometry in juvenile racehorses fed differing amounts of minerals 

    E-Print Network [OSTI]

    Nolan, Meghan Muire

    2002-01-01

    This study was conducted to further elucidate the mineral requirements of the juvenile horse in training. Horses were fed rations containing differing amounts of calcium, phosphorus and magnesium and in reference to mineral intake, groups were...

  15. Rend Lake College celebrates the opening of a new coal miner training facility

    SciTech Connect (OSTI)

    Buchsbaum, L.

    2009-09-15

    The Coal Miner Training Center at Rend Lake College recently hosted the Illinois Mining Institute's annual conference and a regional mine rescue competition. The article gives an outline of the coal miner training and refresher course offered. 3 photos.

  16. Abiotic/Biotic Degradation and Mineralization of N-Nitrosodimethylamine in Aquifer Sediments

    SciTech Connect (OSTI)

    Szecsody, James E.; McKinley, James P.; Breshears, Andrew T.; Crocker, Fiona H.

    2008-10-14

    The N-nitrosodimethylamine (NDMA) degradation rate and mineralization rate were measured in two aquifer sediments that received treatments to create oxic, reducing, and sequential reducing/oxic environments. Chemically reduced sediments rapidly abiotically degraded NDMA to nontoxic dimethylamine (DMA) to parts per trillion levels, then degraded to further products. NDMA was partially mineralized in reduced sediments (6 to 28 percent) at a slow rate (half-life 3,460 h) by an unknown abiotic/biotic pathway. In contrast, NDMA was mineralized more rapidly (half-life 342 h) and to a greater extent (30 to 81 percent) in oxic sediments with propane addition, likely by a propane monooxygenase pathway. NDMA mineralization in sequential reduced sediment followed by oxic sediment treatment did result in slightly more rapid mineralization and a greater mineralization extent relative to reduced systems. These increases were minor, so aerobic NDMA mineralization with oxygen and propane addition was the most viable in situ NDMA mineralization strategy.

  17. Geophysical technique for mineral exploration and discrimination based on electromagnetic methods and associated systems

    DOE Patents [OSTI]

    Zhdanov; Michael S. (Salt Lake City, UT)

    2008-01-29

    Mineral exploration needs a reliable method to distinguish between uneconomic mineral deposits and economic mineralization. A method and system includes a geophysical technique for subsurface material characterization, mineral exploration and mineral discrimination. The technique introduced in this invention detects induced polarization effects in electromagnetic data and uses remote geophysical observations to determine the parameters of an effective conductivity relaxation model using a composite analytical multi-phase model of the rock formations. The conductivity relaxation model and analytical model can be used to determine parameters related by analytical expressions to the physical characteristics of the microstructure of the rocks and minerals. These parameters are ultimately used for the discrimination of different components in underground formations, and in this way provide an ability to distinguish between uneconomic mineral deposits and zones of economic mineralization using geophysical remote sensing technology.

  18. rspb.royalsocietypublishing.org Cite this article: Miner EJ, Gurven M, Kaplan

    E-Print Network [OSTI]

    Cosmides, Leda

    rspb.royalsocietypublishing.org Research Cite this article: Miner EJ, Gurven M, Kaplan H, Gaulin. Miner, Michael Gurven, Hillard Kaplan and Steven J. C. Gaulin Department of Anthropology, University

  19. Copyright: King Fahd University of Petroleum & Minerals; http://www.kfupm.edu.sa

    E-Print Network [OSTI]

    El-Alfy, El-Sayed

    © Copyright: King Fahd University of Petroleum & Minerals; http://www.kfupm.edu.sa MPLS Network SYSTEMS AND APPLICATIONS, VOLS 1-3; pp: 1058-1064; Vol: ## King Fahd University of Petroleum & Minerals

  20. Mineral Dust Entrainment and Deposition (DEAD) model: Description and 1990s dust climatology

    E-Print Network [OSTI]

    Newman, David

    Mineral Dust Entrainment and Deposition (DEAD) model: Description and 1990s dust climatology to 1999 is simulated with our mineral aerosol entrainment and deposition module embedded in a chemical transport model. Mobilization processes include entrainment thresholds for saltation, moisture inhibition

  1. Effects of mineral spatial distribution on reaction rates in porous media

    E-Print Network [OSTI]

    Peters, Catherine A.

    on reaction rates in porous media. Pore-scale network models were constructed to represent sandstones mineral phases, with some minerals more reactive than others. For example, many sandstones contain

  2. Global estimates of mineral dust aerosol iron and aluminum solubility that account for particle size using diffusion-controlled and surface-area-controlled approximations

    E-Print Network [OSTI]

    2012-01-01

    T. D. Jickells (2006), Mineral particle size as a control onInvestigating Microbial-Mineral Interactions, CMS Workshopstudy of iron-containing mineral dust source materials, J.

  3. Measurement of accessible reactive surface area in a sandstone, with application to CO2 mineralization

    E-Print Network [OSTI]

    Landrot, G.

    2013-01-01

    characterization approach employed in this study is suitable for mapping the mineral distribution and pore structure found in a reservoir

  4. Flexible Statistical Models for Growth Fragments: a Study of Bone Mineral Acquisition

    E-Print Network [OSTI]

    Hastie, Trevor

    mineral called dual energy x-ray absorptiom- 2 #12; etry (DXA). To date, most of these investigations have

  5. Modeling dust as component minerals in the Community Atmosphere Model: development of framework and impact on radiative forcing

    E-Print Network [OSTI]

    2015-01-01

    S. , and Colin, J. -L. : Miner- alogy as a critical factorCAM5, the simulation with miner- alogy has relatively highforcing for both models with miner- alogy. For CAM4, while

  6. Hard Rock Miners` Phthisis in 19th and Early 20th Century Britain: From Diagnosis to Compensation

    E-Print Network [OSTI]

    Mintz, Fredric

    2009-01-01

    F.R.C.P. (1903). Discussion of Miners' Phthisis. The BritishD.Sc. , F.R.C.P. (1903). Miners' Diseases discussed at thethe Transvaal, Pretoria. Gold Miners' Phthisis. The Lancet (

  7. Automated simulation of areal bone mineral density assessment in the distal radius from high-resolution peripheral quantitative computed tomography

    E-Print Network [OSTI]

    Burghardt, A. J.; Kazakia, G. J.; Link, T. M.; Majumdar, S.

    2009-01-01

    of osteoporotic fractures. J Bone Miner Res 16:1108–1119 3.of Osteoporotic Fractures. J Bone Miner Res 18:1947–1954 4.and calcaneus. J Bone Miner Res 14:1167–1174 7. Muller R,

  8. A new approach to examining scorpion peg sensilla: the mineral oil flood technique

    E-Print Network [OSTI]

    Gaffin, Doug

    A new approach to examining scorpion peg sensilla: the mineral oil flood technique Elizabeth D approach to examining scorpion peg sensilla: the mineral oil flood technique Elizabeth D. Knowlton evaluated the efficacy of the new mineral oil flood technique. From early indications, we think this new

  9. Mineral sequestration of CO2 by aqueous carbonation of1 coal combustion fly-ash2

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Mineral sequestration of CO2 by aqueous carbonation of1 coal combustion fly-ash2 3 G. Montes that could possibly4 contribute to reducing carbon dioxide emissions is the in-situ mineral sequestration (long term5 geological storage) or the ex-situ mineral sequestration (controlled industrial reactors

  10. 1. Department, Course Number, Title ORE 678, Marine Mineral Resources Engineering

    E-Print Network [OSTI]

    Covered · Introduction to Marine Minerals · Peak Everything - Running out of Commodities · Manganese Nodules and Marine Mining · Deep Sea Mining Technology · Minerals Processing · Offshore Oil and Gas · Oil and Gas Technology, Future Oil Sources and Issues · Economics of Marine Minerals · World Metal Markets

  11. Forward Security in Threshold Signature Schemes MICHEL ABDALLA SARA MINER y CHANATHIP NAMPREMPRE z

    E-Print Network [OSTI]

    International Association for Cryptologic Research (IACR)

    Forward Security in Threshold Signature Schemes MICHEL ABDALLA #3; SARA MINER y CHANATHIP of the Bellare­Miner forward­secure signature scheme, which is Fiat­Shamir­based. One scheme uses multiplicative secret sharing, and we prove it forward­secure based on the security of the Bellare­Miner scheme. We

  12. Tracks of dissolved minerals Pictures from Opportunity's panoramic camera and microscopic

    E-Print Network [OSTI]

    Tracks of dissolved minerals Pictures from Opportunity's panoramic camera and microscopic imager is familiar to geologists as the sites where crystals of salt minerals form within rocks that sit in briny minerals. On the front: Scraping up clues Spirit's stuck right front wheel scraped a trench in the Mars

  13. Phase shifting speckle interferometry for determination of strain and Young's modulus of mineralized

    E-Print Network [OSTI]

    Friesem, Asher A.

    of mineralized biological materials: a study of tooth dentin compression in water Paul Zaslansky Weizmann-8-9342552, Fax: 972-8-9344136 Abstract. Mineralized biological materials have complex hierarchical graded online Apr. 26, 2005. 1 Introduction Mineralized biological materials have complex structures ranging

  14. Modeling of the magnetic behavior of -Fe2O3 nanoparticles mineralized in ferritin

    E-Print Network [OSTI]

    Idzerda, Yves

    Modeling of the magnetic behavior of -Fe2O3 nanoparticles mineralized in ferritin Damon Resnick maghemite mineralized inside ferritin protein cages has been investigated with a vibrating sample be emptied of its con- tents and mineralized with a multitude of different materials, forming highly uniform

  15. HOUSEHOLD AND STRUCTURAL INSECTS Mineral Oil and Aliphatic Alcohols: Toxicity and Analysis of Synergistic

    E-Print Network [OSTI]

    O'Brien, Timothy E.

    HOUSEHOLD AND STRUCTURAL INSECTS Mineral Oil and Aliphatic Alcohols: Toxicity and Analysis. Entomol. 104(5): 1680Ð1686 (2011); DOI: http://dx.doi.org/10.1603/EC10440 ABSTRACT Two mineral oils and 12 and some- times repeated applications. Mineral oils, and other petroleum distillates, are often used

  16. Zoology 109 (2006) 164168 Mineralized Cartilage in the skeleton of chondrichthyan fishes

    E-Print Network [OSTI]

    Summers, Adam P.

    2006-01-01

    ZOOLOGY Zoology 109 (2006) 164­168 Mineralized Cartilage in the skeleton of chondrichthyan fishes; Mineralization; Calcified cartilage; Tesserae Introduction The breadth of morphological variation of the mineralized cartilage of the endoskeleton of chon- drichthyan fishes (sharks, rays, and chimaeras) has led

  17. Physicochemical Controls on the Formation of Polynuclear Metal Complexes at Clay Mineral Surfaces

    E-Print Network [OSTI]

    Sparks, Donald L.

    Physicochemical Controls on the Formation of Polynuclear Metal Complexes at Clay Mineral Surfaces R. G. Ford Metal sorption to clay minerals may lead to the formation of secondary precipitates structurally similar to the mineral takovite. Saturation with respect to this phase is promoted, in part

  18. Flexible Statistical Models for Growth Fragments: a Study of Bone Mineral Acquisition

    E-Print Network [OSTI]

    Hastie, Trevor

    Flexible Statistical Models for Growth Fragments: a Study of Bone Mineral Acquisition Trevor J describe some statistical modeling of longitudinal data from a pediatric study of bone mineral acquisition- surements of bone mineral density are available for each subject, taken roughly one year apart, and between

  19. Rapid Communication On the origin of the toughness of mineralized tissue

    E-Print Network [OSTI]

    Ritchie, Robert

    Rapid Communication On the origin of the toughness of mineralized tissue: microcracking or crack in mineralized tissues, such as bone and dentin, have been identified--microcracking and crack bridging. While the perspective of developing a micromechanistic framework for understanding fracture behavior of mineralized

  20. JOURNAL OF BONE AND MINERAL RESEARCH Volume 7, Number 12, 1992

    E-Print Network [OSTI]

    Chuong, Cheng-Ming

    JOURNAL OF BONE AND MINERAL RESEARCH Volume 7, Number 12, 1992 Mary Ann Liebert, Inc., Publishers behavior and molecular ex- pression before it finally becomes a mineralizing osteocyte. The progression, extracellular maturation, and mineralization -are identified. (3.4) Many molecules functioning as growth fac

  1. Predicted Effect of Minerals on Pretreatment 1013 Applied Biochemistry and Biotechnology Vol. 113116, 2004

    E-Print Network [OSTI]

    California at Riverside, University of

    Predicted Effect of Minerals on Pretreatment 1013 Applied Biochemistry and Biotechnology Vol. 113 of Mineral Neutralization and Bisulfate Formation on Hydrogen Ion Concentration for Dilute Sulfuric Acid, such as agricultural residues and forest wastes, can have a significant mineral content. It has been shown

  2. MINERAL FINE STRUCTURE OF THE AMERICAN LOBSTER CUTICLE JOSEPH G. KUNKEL,1

    E-Print Network [OSTI]

    Kunkel, Joseph G.

    MINERAL FINE STRUCTURE OF THE AMERICAN LOBSTER CUTICLE JOSEPH G. KUNKEL,1 * WOLFRAM NAGEL2 minerals. We propose that calcite is invested in neutralizing an acidifying environment modulated to the epicuticle covering this mineralized surface unleashes an immediate efflux of carbonate, accentuating

  3. A Non-Stationary Errors-in-Variables Method with Application to Mineral Exploration

    E-Print Network [OSTI]

    Braslavsky, Julio H.

    A Non-Stationary Errors-in-Variables Method with Application to Mineral Exploration K. Lau 1 J. H-cancellation in transient electromagnetic mineral exploration. Alternative methods for noise cancellation in these systems for this class of systems is proposed and applied to a problem arising in mineral exploration. An errors

  4. The Origin of Life: Chemical Evolution of a Metabolic System in a Mineral Honeycomb?

    E-Print Network [OSTI]

    Czárán, Tamás

    The Origin of Life: Chemical Evolution of a Metabolic System in a Mineral Honeycomb? Sergio our previous models of chemical evolution on mineral surfaces, in which selection was the consequence into the pores of the mineral substrate. Based on cellular automaton simulations we argue that the effect

  5. Saharan mineral dust transport into the Caribbean: Observed atmospheric controls and trends

    E-Print Network [OSTI]

    Hameed, Sultan

    Saharan mineral dust transport into the Caribbean: Observed atmospheric controls and trends O. M December 2007; published 15 April 2008. [1] Each summer large amounts of mineral dust from the Sahara in this region. In this paper we analyze summer season interannual variability of North African mineral dust over

  6. The influence of mineral detritus on rock varnish formation Ronald I. Dorn a,

    E-Print Network [OSTI]

    Dorn, Ron

    The influence of mineral detritus on rock varnish formation Ronald I. Dorn a, , David H. Krinsley b of aeolian mineral is not incorporated into manganiferous rock varnish. Of those dust particles that are enveloped, submicron sized oval-shaped quartz minerals are the most common type of detritus seen

  7. JOURNAL OF BONE AND MINERAL RESEARCH Volume 24, Number 2, 2009

    E-Print Network [OSTI]

    Ritchie, Robert

    JOURNAL OF BONE AND MINERAL RESEARCH Volume 24, Number 2, 2009 Published online on October 13, 2008; doi: 10.1359/JBMR.81005 Ó 2009 American Society for Bone and Mineral Research Prolonged Treatments With Antiresorptive Agents and PTH Have Different Effects on Bone Strength and the Degree of Mineralization in Old

  8. Mineral replacement rate of olivine by chrysotile and brucite under high alkaline conditions

    E-Print Network [OSTI]

    Montes-Hernandez, German

    Mineral replacement rate of olivine by chrysotile and brucite under high alkaline conditions Romain Available online 8 March 2012 Keywords: A1. Mineral replacement rate A1. Serpentinization A1. TG analyses B1. Alkaline medium B2. Chrysotile nanotubes a b s t r a c t Olivine mineral replacement by serpentine is one

  9. 1529-6466/03/0054-0008$05.00 Biologically Controlled Mineralization

    E-Print Network [OSTI]

    Dove, Patricia M.

    1529-6466/03/0054-0008$05.00 Biologically Controlled Mineralization in Prokaryotes Dennis A or Superkingdoms, the Bacteria and the Archaea, mediate the formation of a large number of diverse minerals. They are known to do this either through biologically induced mineralization (BIM) (Lowenstam 1981) (the subject

  10. Magnetic mineral transport and sorting in the swash-zone: northern Lake Erie, Canada

    E-Print Network [OSTI]

    Hatfield, Robert

    Magnetic mineral transport and sorting in the swash-zone: northern Lake Erie, Canada ERIC GALLAWAY mineral placer deposits on beaches consisting primarily of non-magnetic sediment. Work was conducted on the cross-shore and longshore transport of heavy magnetic minerals using magnetic susceptibility

  11. PR-Miner: Automatically Extracting Implicit Programming Rules and Detecting Violations in Large Software Code

    E-Print Network [OSTI]

    Zhou, Yuanyuan

    PR-Miner: Automatically Extracting Implicit Programming Rules and Detecting Violations in Large a general method called PR-Miner that uses a data mining technique called frequent itemset mining. Benefiting from frequent itemset mining, PR-Miner can extract pro- gramming rules in general forms (without

  12. R E V I E W Mineral soil carbon fluxes in forests and implications for

    E-Print Network [OSTI]

    Keeton, William S.

    R E V I E W Mineral soil carbon fluxes in forests and implications for carbon balance assessments and mitigate climate change. Large amounts of carbon (C) are stored in deep mineral forest soils, but are often not considered in accounting for global C fluxes because mineral soil C is commonly thought to be relatively

  13. A Principled Approach to Mining From Noisy Logs Using Heuristics Miner

    E-Print Network [OSTI]

    Tino, Peter

    A Principled Approach to Mining From Noisy Logs Using Heuristics Miner Philip Weber, Behzad Bordbar Miner algorithm, and demonstrate on a simple example. We show that for a given model it is possible in the the robustness of Heuristics Miner to different types of noise. I. INTRODUCTION Process mining is the learning

  14. THE LINK BETWEEN CLAY MINERAL WEATHERING AND THE FORMATION OF NI SURFACE PRECIPITATES

    E-Print Network [OSTI]

    Sparks, Donald L.

    THE LINK BETWEEN CLAY MINERAL WEATHERING AND THE FORMATION OF NI SURFACE PRECIPITATES Andreas C minerals may proceed via formation of surface precipitates, which may lead to a significant long the formation of several mineral phases with distinct solubilities. While turbostratic a-type metal hydroxides

  15. Mineral-specific chemical weathering rates over millennial timescales: Measurements at Rio Icacos, Puerto Rico

    E-Print Network [OSTI]

    Kirchner, James W.

    Mineral-specific chemical weathering rates over millennial timescales: Measurements at Rio Icacos 2010 Accepted 26 July 2010 Editor: J.D. Blum Keywords: Chemical weathering Mineral weathering Cosmogenic nuclides Rio Icacos Puerto Rico Mineral weathering plays a prominent role in many biogeochemical

  16. The global distribution of mineral dust and its impacts on the climate system: A review

    E-Print Network [OSTI]

    Hickman, Mark

    The global distribution of mineral dust and its impacts on the climate system: A review O. Alizadeh Received in revised form 5 November 2013 Accepted 6 November 2013 Available online 20 November 2013 Mineral. Current understanding of spatial and temporal variations of mineral dust, as well as its impacts

  17. Mineralization of ancient carbon in the subsurface of riparian forests Noel P. Gurwick,1,2

    E-Print Network [OSTI]

    Gold, Art

    Mineralization of ancient carbon in the subsurface of riparian forests Noel P. Gurwick,1,2 Daniel M C mineralization rates can support ecosystem-relevant rates of denitrification. Buried horizons and 14 C dating of dissolved inorganic carbon revealed that ancient SOC mineralization was common

  18. JOURNAL OF BONE AND MINERAL RESEARCH Volume 24, Number 11, 2009

    E-Print Network [OSTI]

    Burgoyne, Chris

    JOURNAL OF BONE AND MINERAL RESEARCH Volume 24, Number 11, 2009 Published online on May 4, 2009; doi: 10.1359/JBMR.090504 Ó 2009 American Society for Bone and Mineral Research Femoral Neck Trabecular fracture cases have sufficient trabecular bone for anabolic therapies to build on. J Bone Miner Res 2009;24:1808

  19. Elasticity measurements on minerals: a review ROSS J. ANGEL1,*, JENNIFER M. JACKSON2

    E-Print Network [OSTI]

    Jackson, Jennifer M.

    Elasticity measurements on minerals: a review ROSS J. ANGEL1,*, JENNIFER M. JACKSON2 , HANS J 91125, USA 3 Deutsches Geoforschungszentrum, 14473 Potsdam, Germany Abstract: The elasticity of minerals in the experimental methods used to determine the elastic properties of minerals. Not only have new techniques become

  20. Accuracy and performance of linear unmixing techniques for detecting minerals on OMEGA/MEx

    E-Print Network [OSTI]

    Dobigeon, Nicolas

    Accuracy and performance of linear unmixing techniques for detecting minerals on OMEGA/MEx F minerals on a huge hyperspectral dataset (> To) is a difficult task that we proposed to address using identified areas with very strong signatures of mafic minerals (orthopyroxene, clinopyroxene, olivine

  1. Ion microprobe survey of the grain-scale oxygen isotope geochemistry of minerals in metamorphic rocks

    E-Print Network [OSTI]

    Meyers, Stephen R.

    Ion microprobe survey of the grain-scale oxygen isotope geochemistry of minerals in metamorphic standards) were made of 73 minerals in 23 samples. Both intercrystalline and intracrystalline variability in d18 O is greater in contact than in regional metamorphic rocks. Of 27 minerals analyzed in contact

  2. Copyright: King Fahd University of Petroleum & Minerals; http://www.kfupm.edu.sa

    E-Print Network [OSTI]

    El-Alfy, El-Sayed

    © Copyright: King Fahd University of Petroleum & Minerals; http://www.kfupm.edu.sa A Heuristic. of Pet. & Miner., Dhahran; Advanced Communication Technology, The 9th International conference of Petroleum & Minerals http://www.kfupm.edu.sa Summary A primary goal of this paper is to develop a heuristic

  3. Copyright: King Fahd University of Petroleum & Minerals; http://www.kfupm.edu.sa

    E-Print Network [OSTI]

    El-Alfy, El-Sayed

    © Copyright: King Fahd University of Petroleum & Minerals; http://www.kfupm.edu.sa On Optimal SYSTEMS AND APPLICATIONS, VOLS 1 AND 2; pp: 819-824; Vol: ## King Fahd University of Petroleum & Minerals: King Fahd University of Petroleum & Minerals; http://www.kfupm.edu.sa 15. YU F, 2004, EFFICIENT MULTI

  4. Copyright: King Fahd University of Petroleum & Minerals; http://www.kfupm.edu.sa

    E-Print Network [OSTI]

    El-Alfy, El-Sayed

    © Copyright: King Fahd University of Petroleum & Minerals; http://www.kfupm.edu.sa A Learning-Dong Yao Heffes, H.;Dept. of Comput. Sci., King Fahd Univ. of Pet. & Miner., Dhahran; Wireless & Minerals http://www.kfupm.edu.sa Summary An efficient channel allocation policy that prioritizes handoffs

  5. Structure and Dynamics of Monolayer Growth at Mineral-Water Interfaces

    E-Print Network [OSTI]

    Richmond, Geraldine L.

    Structure and Dynamics of Monolayer Growth at Mineral-Water Interfaces Geri Richmond Department of adsorption processes at mineral-water interfaces. In particular, surface enhanced infrared (IR) techniques insights into structure and dynamics of these interfaces. The driving forces behind adsorption at mineral

  6. Enhanced Magneto-optic Kerr Effect and Magnetic Properties of CeY[subscript 2]Fe[subscript 5]O[subscript 12] Epitaxial Thin Films

    E-Print Network [OSTI]

    Kehlberger, Andreas

    The magnetic and magneto-optic properties of epitaxial CeY[subscript 2]Fe[subscript 5]O[subscript 12] (Ce ? YIG) and Y[subscript 3]Fe[subscript 5]O[subscript 12] (yttrium iron garnet or YIG) thin films grown by pulsed laser ...

  7. Thermal and magnetic properties of La-doped Ce1-yLayGe1.80 with 0

    E-Print Network [OSTI]

    Li, Jing

    Thermal and magnetic properties of La-doped Ce1-yLayGe1.80 with 0 Department of Physics, Temple University, Philadelphia, Pennsylvania 19122 J. A. Zan Jet Propulsion 2006 CeGex with 1.71 x 2.0 crystallizes in an orthorhombic structure and exhibits two magnetic

  8. Journal of Electron Spectroscopy and Related Phenomena 136 (2004) 1520 Temperature-dependence of Kondo resonance in CeSi2 studied by

    E-Print Network [OSTI]

    Oh, Se-Jung

    2004-01-01

    ). heavy-electron compounds [7]. In Ce-based heavy Fermion systems, the Kondo energy scale, , typically spectroscopy (RPES); Single impurity Anderson model (SIAM) 1. Introduction In the photoemission community, Ce photoemission (UPS) can reach this resolution limits currently. The most commonly used method to extract the 4f

  9. An active atmospheric methane sink in high Arctic mineral cryosols

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lau, Maggie C.Y.; Stackhouse, B.; Layton, Alice C.; Chauhan, Archana; Vishnivetskaya, T. A.; Chourey, Karuna; Mykytczuk, N. C.S.; Bennett, Phil C.; Lamarche-Gagnon, G.; Burton, N.; et al

    2015-04-14

    The transition of Arctic carbon-rich cryosols into methane (CH?)-emitting wetlands due to global warming is a rising concern. However, the spatially predominant mineral cryosols and their CH? emission potential are poorly understood. Fluxes measured in situ and estimated under laboratory conditions coupled with -omics analysis indicate (1) mineral cryosols in the Canadian high Arctic contain atmospheric CH?-oxidizing bacteria; (2) the atmospheric CH? uptake flux increases with ground temperature; and, as a result, (3) the atmospheric CH? sink strength will increase by a factor of 5-30 as the Arctic warms by 5-15 °C over a century. We demonstrated that acidic mineralmore »cryosols have previously unrecognized potential of negative CH? feedback.« less

  10. Investigating Radiation Shielding Properties of Different Mineral Origin Heavyweight Concretes

    SciTech Connect (OSTI)

    Basyigit, Celalettin; Uysal, Volkan; Kilincarslan, Semsettin; Akkas, Ayse; Mavi, Betuel; Guenoglu, Kadir; Akkurt, Iskender

    2011-12-26

    The radiation although has hazardous effects for human health, developing technologies bring lots of usage fields to radiation like in medicine and nuclear power station buildings. In this case protecting from undesirable radiation is a necessity for human health. Heavyweight concrete is one of the most important materials used in where radiation should be shielded, like those areas. In this study, used heavyweight aggregates of different mineral origin (Limonite, Siderite), in order to prepare different series in concrete mixtures and investigated radiation shielding properties. The experimental results on measuring the radiation shielding, the heavyweight concrete prepared with heavyweight aggregates of different mineral origin show that, are useful radiation absorbents when they used in concrete mixtures.

  11. Intercalation of Trichloroethene by Sediment-Associated Clay Minerals

    SciTech Connect (OSTI)

    Matthieu, Donald E.; Brusseau, Mark; Johnson, G. R.; Artiola, J. L.; Bowden, Mark E.; Curry, J. E.

    2013-01-01

    The objective of this research was to examine the potential for intercalation of trichloroethene (TCE) by clay minerals associated with aquifer sediments. Sediment samples were collected from a field site inTucson, AZ. Two widely used Montmorillonite specimen clays were employed as controls. X-ray diffraction, conducted with a controlled-environment chamber, was used to characterize smectite interlayer dspacing for three treatments (bulk air-dry sample, sample mixed with synthetic groundwater, sample mixed with TCE-saturated synthetic groundwater). The results show that the d-spacing measured for the samples treated with TCE-saturated synthetic groundwater are larger (*26%) than those of the untreated samples for all field samples as well as the specimen clays. These results indicate that TCE was intercalated by the clay minerals, which may have contributed to the extensive elution tailing observed in prior miscible-displacement experiments conducted with this sediment.

  12. Method of analysis of asbestiform minerals by thermoluminescence

    DOE Patents [OSTI]

    Fisher, Gerald L. (Davis, CA); Bradley, Edward W. (Davis, CA)

    1980-01-01

    A method for the qualitative and quantitative analysis of asbestiform minerals, including the steps of subjecting a sample to be analyzed to the thermoluminescent analysis, annealing the sample, subjecting the sample to ionizing radiation, and subjecting the sample to a second thermoluminescent analysis. Glow curves are derived from the two thermoluminescent analyses and their shapes then compared to established glow curves of known asbestiform minerals to identify the type of asbestiform in the sample. Also, during at least one of the analyses, the thermoluminescent response for each sample is integrated during a linear heating period of the analysis in order to derive the total thermoluminescence per milligram of sample. This total is a measure of the quantity of asbestiform in the sample and may also be used to identify the source of the sample.

  13. Cost Assessment of CO2 Sequestration by Mineral Carbonation 

    E-Print Network [OSTI]

    Yeboah, F. E.; Yegulalp, T. M.; Singh, H.

    2006-01-01

    in the generation of electrical energy. The concept of clean coal technology will be introduced. This will then be followed by a description of sequestration by mineral carbonation. The various processes involved in sequestration process will also be discussed... Policy 31, p. 1315 – 1326. 4. Yeboah, F.E., 2004, Valuation of Clean Energy Investments – The Case of the Zero Emission Coal (ZEC) Technology. Unpublished Doctoral Dissertation, Fu School of Engineering, Columbia University, New York, NY. 5...

  14. Hydrodesulfurization and hydrodenitrogenation catalysts obtained from coal mineral matter

    DOE Patents [OSTI]

    Liu, Kindtoken H. D. (Newark, DE); Hamrin, Jr., Charles E. (Lexington, KY)

    1982-01-01

    A hydrotreating catalyst is prepared from coal mineral matter obtained by low temperature ashing coals of relatively low bassanite content by the steps of: (a) depositing on the low temperature ash 0.25-3 grams of an iron or nickel salt in water per gram of ash and drying a resulting slurry; (b) crushing and sizing a resulting solid; and (c) heating the thus-sized solid powder in hydrogen.

  15. Mineral County, Colorado: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History ViewMayo, Maryland: Energy ResourcesDec 2005 WindPROLLCWashington: EnergyMinatare,Miner

  16. Radioactive Mineral Occurences in Nevada | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onRAPID/Geothermal/Exploration/Colorado <RAPID/Geothermal/Water Use/NevadaaToolsRadioactive Mineral Occurences in

  17. Superior performance of Ni-W-Ce mixed-metal oxide catalysts for ethanol steam reforming: Synergistic effects of W- and Ni-dopants

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rodriguez, Jose A.; Liu, Zongyuan; Xu, Wenqian; Yao, Siyu; Johnson-Peck, Aaron C.; Zhao, Fuzhen; Michorczyk, Piotr; Kubacka, Anna; Stach, Eric A.; Fernandez-Garica, Marcos; et al

    2014-11-26

    The ethanol steam reforming (ESR) reaction was studied over a series of Ni-W-Ce oxide catalysts. The structures of the catalysts were characterized using in-situ techniques including X-ray diffraction, Pair Distribution Function, X-ray absorption fine structure and transmission electron microscopy; while possible surface intermediates for the ESR reaction were investigated by Diffuse Reflectance Infrared Fourier Transform Spectroscopy. In these materials, all the W and part of the Ni were incorporated into the CeO? lattice, with the remaining Ni forming highly dispersed nano NiO (more »The Ni-W-Ce systeme exhibited a much larger lattice strain than those seen for Ni-Ce and W-Ce. Synergistic effects between Ni and W inside ceria produced a substantial amount of defects and O vacancies that led to high catalytic activity, selectivity and stability (i.e. resistance to coke formation) during ethanol steam reforming.« less

  18. Nanostructured Lanthanum Halides and CeBr3 for Nuclear Radiation and Detection

    SciTech Connect (OSTI)

    Paul Guss, Sanjoy Mukhopadhyay, Ron Guise, Ding Yuan

    2010-06-09

    Scintillator materials are used to detect, and in some cases identify, gamma rays. Higher performance scintillators are expensive, hard to manufacture, fragile, and sometimes require liquid nitrogen or cooling engines. But whereas lower-quality scintillators are cheap, easy to manufacture, and more rugged, their performance is lower. At issue: can the desirable qualities of high-and low-performance scintillators be combined to achieve better performance at lower cost? Preliminary experiments show that a LaF{sub 3}:Ce oleic acid-based nanocomposite exhibits a photopeak when exposed to {sup 137}Cs source gamma-radiation. The chemical synthesis of the cerium-doped lanthanum halide nanoparticles are scalable and large quantities of material can be produced at a time, unlike typical crystal growth processes such as the Bridgeman process. Using a polymer composite (Figure 1), produced by LANL, initial measurements of the unloaded and 8% LaF{sub 3}:Ce-loaded sample have been made using {sup 137}Cs sources. Figure 2 shows an energy spectrum acquired for CeF{sub 3}. The lighter plot is the measured polymer-only spectrum and the black plot is the spectrum from the nanocomposite scintillator. As the development of this material continues, the energy resolution is expected to improve and the photopeak-to-Compton ratio will become greater at higher loadings. These measurements show the expected Compton edge in the polymer-only sample, and the Compton edge and photo-peak expected in the nanophosphor composites that LANL has produced. Using a porous VYCORR with CdSe/ZnS core shell quantum dots, Letant has demonstrated that he has obtained signatures of the 241Am photopeak with energy resolution as good at NaI (Figure 3). We begin with the fact that CeBr{sub 3} crystals do not have a self-activity component as strong as the lanthanum halides. The radioactive 0.090% {sup 138}La component of lanthanum leads to significant self-activity, which will be a problem for very large detector volumes. Yet a significant strength of the nanostructure detector concept is the ability to create extremely large detector volumes by mixing nanoparticles into a transparent matrix. This would argue for use of nanoparticles other than lanthanum halides. Nanocomposites are easy to prepare; it is much less costly to use nanocomposites than to grow large whole crystals of these materials. The material can be fabricated at an industrial scale, further reducing cost. This material potentially offers the performance of $300/cc material (e.g., lanthanum bromide) at a cost of $1/cc. Because the material acts as a plastic, it is rugged and flexible, and can be made in large sheets, increasing the sensitivity of a detector using it. It would operate at ambient temperatures. Very large volumes of detector may be produced at greatly reduced cost, enhancing the non-proliferation posture of the nation for the same dollar value.

  19. Vortex Lattice Studies in CeCoIn? with H?c

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Das, P.; White, J. S.; Holmes, A. T.; Gerber, S.; Forgan, E. M.; Bianchi, A. D.; Kenzelmann, M.; Zolliker, M.; Gavilano, J. L.; Bauer, E. D.; et al

    2012-02-01

    We present small angle neutron scattering studies of the vortex lattice (VL) in CeCoIn? with magnetic fields applied parallel (H) to the antinodal [100] and nodal [110] directions. For H II 100], a single VL orientation is observed, while a 90° reorientation transition is found for H II [110]. For both field orientations and VL configurations we find a distorted hexagonal VL with an anisotropy, ?=2.0±0.05. The VL form factor shows strong Pauli paramagnetic effects similar to what have previously been reported for H II [001]. At high fields, above which the upper critical field (Hc2) becomes a first-order transition,more »an increased disordering of the VL is observed.« less

  20. Effect of aging upon CE and B and W control rod drives

    SciTech Connect (OSTI)

    Grove, E.; Gunther, W.

    1992-05-01

    The effect of aging upon the Babcock & Wilcox (B&W) and Combustion Engineering (CE) Control Rod Drive (CRD) systems has been evaluated as part of the US NRC Nuclear Plant Aging Research (NPAR) program. Operating experience data for the 1980--1990 time period was reviewed to identify predominant failure modes, causes, and effects. These results, in conjunction with an assessment of component materials and operating environment, conclude that both systems are susceptible to age degradation. System failures have resulted in significant plant effects, including power reductions, plant shutdowns, scrams, and Engineered Safety Feature (ESF) actuation. Current industry inspection and maintenance practices were assessed. Some of these practices effectively address aging, while others do not.

  1. Effect of aging upon CE and B and W control rod drives

    SciTech Connect (OSTI)

    Grove, E.; Gunther, W.

    1992-01-01

    The effect of aging upon the Babcock Wilcox (B W) and Combustion Engineering (CE) Control Rod Drive (CRD) systems has been evaluated as part of the US NRC Nuclear Plant Aging Research (NPAR) program. Operating experience data for the 1980--1990 time period was reviewed to identify predominant failure modes, causes, and effects. These results, in conjunction with an assessment of component materials and operating environment, conclude that both systems are susceptible to age degradation. System failures have resulted in significant plant effects, including power reductions, plant shutdowns, scrams, and Engineered Safety Feature (ESF) actuation. Current industry inspection and maintenance practices were assessed. Some of these practices effectively address aging, while others do not.

  2. Observations of heterogeneous reactions between Asian pollution and mineral dust over the Eastern North Pacific during INTEX-B

    E-Print Network [OSTI]

    2009-01-01

    light scattering, due to competition between pollution andAsian pollution and mineral dust Table 8. Changes to lightpollution and mineral dust Table 6. Comparison of light

  3. Investigation of the physical properties of the tetragonal CeMAl4Si2 (M = Rh, Ir, Pt) compounds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ghimire, N. J.; Ronning, F.; Williams, D. J.; Scott, B. L.; Luo, Yongkang; Thompson, J. D.; Bauer, E. D.

    2014-12-15

    The synthesis, crystal structure and physical properties studied by means of x-ray diffraction, magnetic, thermal and transport measurements of CeMAl4Si2 (M = Rh, Ir, Pt) are reported, along with the electronic structure calculations for LaMAl4Si2 (M = Rh, Ir, Pt). These materials adopt a tetragonal crystal structure (space group P4/mmm) comprised of BaAl4 blocks, separated by MAl2 units, stacked along the c-axis. Both CeRhAl4Si2 and CeIrAl4Si2 order antiferromagnetically below TN1 = 14 and 16 K, respectively, and undergo a second antiferromagnetic transitition at lower temperature (TN2 = 9 and 14 K, respectively). CePtAl4Si2 orders ferromagnetically below TC = 3 Kmore »with an ordered moment of ?sat = 0.8 ?B for a magnetic field applied perpendicular to the c-axis. Electronic structure calculations reveal quasi-2D character of the Fermi surface.« less

  4. Novel CeO2-based Screen-Printed Potentiometric Electrodes for pH monitoring S. Betelu1*

    E-Print Network [OSTI]

    Boyer, Edmond

    in Europe to isolate and store radioactive waste. In France, the Callovo-Oxfordian formation (COx) is a possible candidate for nuclear waste storage. This work investigates the applicability of CeO2-based oxides or are anticipated in the COx formation during its evolution as radioactive waste repository due mainly

  5. The effect of Ce{sup 4+} incorporation on structural, morphological and photocatalytic characters of ZnO nanoparticles

    SciTech Connect (OSTI)

    Kannadasan, N.; Shanmugam, N. Cholan, S.; Sathishkumar, K.; Viruthagiri, G.; Poonguzhali, R.

    2014-11-15

    We report a simple chemical precipitation method for the preparation of undoped and cerium doped ZnO nanocrystals. The concentration of cerium in the products can be controlled in the range of 0.025–0.125 mol. The structure and chemical compositions of the products were characterized by X-ray diffraction, X-ray photoelectron spectroscopy; energy dispersive spectrum and Fourier transform infrared spectroscopy. The results demonstrate that Ce{sup 4+} ions were successfully incorporated into the lattice position of Zn{sup 2+} ions in ZnO. The morphology of the products was analyzed by field emission scanning electron microscopy and confirmed by high resolution transmission electron microscope analysis. The optical properties of the products were studied by ultraviolet–visible and room temperature photoluminescence measurements. The photoluminescence emission spectra of Ce-doped ZnO showed enhanced visible emissions as a result of 5d ? 4f transition of cerium. In particular, a novel photocatalytic activity of the products was assessed using methylene blue. The obtained result reveals that Ce-doped products show higher reduction efficiency for methylene blue than the undoped ZnO. - Highlights: • Nanocrystals of ZnO and ZnO:Ce{sup 4+} were grown. • XPS results confirmed the incorporated cerium in tetravalence. • PL emission exhibited 5d ? 4f transition on cerium doping. • Doped ZnO decolorizes MB faster than undoped ZnO.

  6. ME 227 CE 212 MATH 223 GE 210 CMPT 116 ABE 211CHE 210 GE 213# MATH 224

    E-Print Network [OSTI]

    Saskatchewan, University of

    GE 120 ME 227 CE 212 MATH 223 GE 210 CMPT 116 ABE 211CHE 210 GE 213# MATH 224 ABE 295 ABE 212 can be taken in either term. GE 124 MATH 110 MATH 124CHEM 115 PHYS 155 3RD YEAR GE 125 GE 110 COMM 102

  7. This form is downloadable from CEE Student Resources website: http://www.ce.washington.edu/students/undergrad.html H: Advising/Sr Yr Plan Sheet Rev.4/26/2012

    E-Print Network [OSTI]

    Eberhard, Marc O.

    This form is downloadable from CEE Student Resources website: http://www.ce.washington.edu/students/undergrad.html for the following year will be available online at www.ce.washington.edu/students/timeschedule.html. After meeting

  8. Velocityconductivity relationships for mantle mineral assemblages in Archean cratonic lithosphere based on a review of laboratory data and HashinShtrikman

    E-Print Network [OSTI]

    Jones, Alan G.

    Velocity­conductivity relationships for mantle mineral assemblages in Archean cratonic lithosphere Mineral physics Extremal bounds Velocity­conductivity relationship Can mineral physics and mixing theories. Using phenomenologically-derived state equations for individual minerals coupled with multi

  9. Electrical anisotropy of mineralized and non mineralized rocks T.J. Katsube, M.E. Best*, and Jones, A.G., Geological Survey of Canada

    E-Print Network [OSTI]

    Jones, Alan G.

    PP 10.2 Electrical anisotropy of mineralized and non mineralized rocks T.J. Katsube, M.E. Best*, and Jones, A.G., Geological Survey of Canada Summary Significant electrical resistivity anisotropy, up to 1 to understand the electrical mechanisms involved in such anisotropic processes in order to provide information

  10. Local structure and polarization resistance of Ce doped SrMnO{sub 3} using extended x-ray fine structure analysis

    SciTech Connect (OSTI)

    Ryu, Jiseung; Lee, Heesoo, E-mail: heesoo@pusan.ac.kr [School of Materials Science and Engineering, Pusan National University, Busan 609-735 (Korea, Republic of)

    2014-09-15

    Changes to the local structure of Sr and Mn atoms in Sr{sub 1?x}Ce{sub x}MnO{sub 3} (SCM) according to increasing Ce content and the effect of the structural change on the polarization resistance of SCM were investigated. The reduction of manganese was confirmed by the absorption edge shift of the Mn K-edge toward lower energies. The noise of oscillation in extended X-ray absorption fine structure k{sup 3}? data at Mn K-edge reveals the distortion of the local structure of Mn atoms, and the peak that indicates the bonding length of Mn-O, Sr/Ce, and -Mn decreased with the addition of Ce content in Fourier transformations of the Mn K-edge. The distortion of the local structure at Mn atoms was affected by the reduced manganese ions having larger ionic radii than Mn{sup 4+}. Meanwhile, few distortions of local atomic structures of Sr atoms occurred, and the average nearest neighboring distances of Sr-O and Sr-Mn are ?2.13?Å and ?2.95?Å, respectively. The average bonding lengths of the Ce-O and Ce-Mn increased because the ionic radius of substituted Ce ion with 12 coordination number is smaller than that of Sr ion, which leads the reduction of Mn ions and the distortion of local structure at the substituted A-site. Therefore, we reasoned that the distortion of the local atomic structure at Mn atoms in MnO{sub 6} and Ce atoms in A-site is one of the causes for interrupting oxygen ion transfers as a geometric factor, which results in an increase in the polarization resistance of SCM within the Ce composition range from 10?mol.?% to 30?mol.?%.

  11. NOVEL IN-SITU METAL AND MINERAL EXTRACTION TECHNOLOGY

    SciTech Connect (OSTI)

    Glenn O'Gorman; Hans von Michaelis; Gregory J. Olson

    2004-09-22

    This white paper summarizes the state of art of in-situ leaching of metals and minerals, and describes a new technology concept employing improved fragmentation of ores underground in order to prepare the ore for more efficient in-situ leaching, combined with technology to continuously improve solution flow patterns through the ore during the leaching process. The process parameters and economic benefits of combining the new concept with chemical and biological leaching are described. A summary is provided of the next steps required to demonstrate the technology with the goal of enabling more widespread use of in-situ leaching.

  12. Potassium Fixation and Supply by Soils with Mixed Clay Minerals

    E-Print Network [OSTI]

    Hipp, Billy W.

    1969-01-01

    potassium Fixation and Supply By Soils With Misd Clay Minerals I KUS A&M UNIVERSITY Tcrv Agricultural Experiment Station r i 0. Kunkel, Acting Director, College Station, Texas Summary to the plants while Cameron clay supplied onl!. Studies were made... of plants for any one crop period. The plants were n , with distilled water throughout the experiment. ' Ther I Previous work by Hipp and Thomas (3) pointed out the importance of clay type in the assessment of K avail- ability in certain soils of Texas...

  13. Measurement of bone mineral content in caged and active cats 

    E-Print Network [OSTI]

    Tveter, Diane Ellen

    1988-01-01

    errors but these can be reduced by using two different x-ray energies. Dual energy CT operates on a basis similar to dual photon absorptiometry (explained below). The difference in attenuation between tissue and bone is greater for a lower energy... to act as a soft tissue equivalent (35). Effects of fat and soft tissue are decreased when dual energy CT is used (33). Data from each of the two different photon energies are combined and result in images of soft tissue and bone mineral regions. Beam...

  14. Miner County, South Dakota: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History ViewMayo, Maryland: Energy ResourcesDec 2005 WindPROLLCWashington: EnergyMinatare,Miner County,

  15. Mineral County, Montana: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History ViewMayo, Maryland: Energy ResourcesDec 2005 WindPROLLCWashington: EnergyMinatare,MinerMontana:

  16. Mineral Recovery from Geothermal Fluids | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History ViewMayo, Maryland: Energy ResourcesDec 2005 WindPROLLCWashington:West Virginia: EnergyMineral

  17. Mineral Deformation at Earth's Core-Mantle Boundary

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines light on77 PAGE OFDetectionBenchmark Performance 111.1 33.033.0MinMineral

  18. Mineral Deformation at Earth's Core-Mantle Boundary

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines light on77 PAGE OFDetectionBenchmark Performance 111.1Mineral Deformation

  19. Mineral Deformation at Earth's Core-Mantle Boundary

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines light on77 PAGE OFDetectionBenchmark Performance 111.1Mineral

  20. CMI Course Inventory: Mineral Economics and Business | Critical Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room News PublicationsAudits &Bradbury Science Museum6 Shares1-0005-000CDInstitute Mineral

  1. Beach Minerals Company Pvt Ltd BMCPL | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EAandAmminexInformationArkansas:Information DeliHaven West,Minerals

  2. Mineral Deformation at Earth's Core-Mantle Boundary

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJessework uses concrete7 Assessment ofLana7,Mimicking theMineral Deformation at

  3. The Inhibition of Calcium Phosphate Precipitation by Fetuin Is Accompanied by the Formation of a Fetuin-Mineral Complex*

    E-Print Network [OSTI]

    Price, Paul A.

    of a Fetuin-Mineral Complex* Received for publication, January 22, 2003, and in revised form, April 1, 2003 of the fetuin-mineral complex, a high molecular mass com- plex of calcium phosphate mineral and the proteins fe inhibited the precip- itation of calcium phosphate mineral when the concen- tration of calcium and phosphate

  4. A new technique for imaging Mineralized Fibrils on Bovine Trabecular Bone Fracture Surfaces by Atomic Force Microscopy

    E-Print Network [OSTI]

    Hansma, Paul

    A new technique for imaging Mineralized Fibrils on Bovine Trabecular Bone Fracture Surfaces coated with extrafibrillar mineral particles. The mineral particles are distinctly different in different collagen fibrils. If the observed particles can be verified to be native extrafibrillar mineral, this could

  5. Understanding Depth Variation of Deep Seismicity from in situ Measurements of Mineral Strengths at High Pressures

    SciTech Connect (OSTI)

    Chen, J.

    2010-01-01

    Strengths of major minerals of Earth's mantle have been measured using in situ synchrotron X-ray diffraction at high pressures. Analysis of the diffraction peak widths is used to derive the yield strengths. Systematic analysis of the experimental result for olivine, wadsleyite, ringwoodite and perovskite indicates that minerals in the upper mantle, the transition zone and the lower mantle have very distinct strength character. Increasing temperature weakens the upper mantle mineral, olivine, significantly. At high temperature and high pressure, the transition zone minerals, wadsleyite and ringwoodite, have higher strengths than the upper mantle mineral. Among all the minerals studied, the lower mantle mineral, perovskite, has the highest strength. While both the upper mantle and the transition zone minerals show a notable strength drop, the strength of the lower mantle mineral shows just an increase of relaxation rate (no strength drop) when the temperature is increased stepwise by 200 K. The strength characteristics of these major mantle minerals at high pressures and temperatures indicate that yield strength may play a crucial role in defining the profile of deep earthquake occurrence with depth.

  6. Pressure-Induced Structural Phase Transition in CeNi: X-ray and Neutron Scattering Studies and First-Principles Calculations

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mirmelstein, A.; Podlesnyak, Andrey A.; dos Santos, Antonio M.; Ehlers, Georg; Kerbel, O.; Matvienko, V.; Sefat, A. S.; Saporov, B.; Halder, G. J.; Tobin, J. G.

    2015-08-03

    The pressure-induced structural phase transition in the intermediate-valence compound CeNi has been investigated by x-ray and neutron powder diffraction techniques. It is shown that the structure of the pressure-induced CeNi phase (phases) can be described in terms of the Pnma space group. Equations of state for CeNi on both sides of the phase transition are derived and an approximate P-T phase diagram is suggested for Pmore »the phase transition.« less

  7. Active Layer Soil Carbon and Nutrient Mineralization, Barrow, Alaska, 2012

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Stan D. Wullschleger; Holly M. Vander Stel; Colleen Iversen; Victoria L. Sloan; Richard J. Norby; Mallory P. Ladd; Jason K. Keller; Ariane Jong; Joanne Childs; Deanne J. Brice

    2015-10-29

    This data set consists of bulk soil characteristics as well as carbon and nutrient mineralization rates of active layer soils manually collected from the field in August, 2012, frozen, and then thawed and incubated across a range of temperatures in the laboratory for 28 day periods in 2013-2015. The soils were collected from four replicate polygons in each of the four Areas (A, B, C, and D) of Intensive Site 1 at the Next-Generation Ecosystem Experiments (NGEE) Arctic site near Barrow, Alaska. Soil samples were coincident with the established Vegetation Plots that are located in center, edge, and trough microtopography in each polygon. Data included are 1) bulk soil characteristics including carbon, nitrogen, gravimetric water content, bulk density, and pH in 5-cm depth increments and also by soil horizon, 2) carbon, nitrogen, and phosphorus mineralization rates for soil horizons incubated aerobically (and in one case both aerobically and anaerobically) for 28 days at temperatures that included 2, 4, 8, and 12 degrees C. Additional soil and incubation data are forthcoming. They will be available when published as part of another paper that includes additional replicate analyses.

  8. Regulation of biological tissue mineralization through post-nucleation shielding

    E-Print Network [OSTI]

    Joshua C. Chang; Robert M. Miura

    2015-01-29

    In vertebrates, insufficient availability of calcium and phosphate ions in extracellular fluids leads to loss of bone density and neuronal hyper-excitability. To counteract this problem, calcium ions are present at high concentrations throughout body fluids -- at concentrations exceeding the saturation point. This condition leads to the opposite situation where unwanted mineral sedimentation may occur. Remarkably, ectopic or out-of-place sedimentation into soft tissues is rare, in spite of the thermodynamic driving factors. This fortunate fact is due to the presence of auto-regulatory proteins that are found in abundance in bodily fluids. Yet, many important inflammatory disorders such as atherosclerosis and osteoarthritis are associated with this undesired calcification. Hence, it is important to gain an understanding of the regulatory process and the conditions under which it can go awry. In this Letter, we use ideas from mean-field classical nucleation theory to study the regulation of sedimentation of calcium phosphate salts in biological tissues through the mechanism of post-nuclear shielding of nascent mineral particles by binding proteins. A critical concentration of regulatory protein is identified as a function of the physical parameters that describe the system.

  9. Q-dependence of the spin fluctuations in the intermediate valence compound CePd3

    SciTech Connect (OSTI)

    Fanelli, V. R.; Lawrence, J. M.; Goremychkin, E. A.; Osborn, R.; Bauer, E. D.; McClellan, K. J.; Thompson, J. D.; Booth, C. H.; Christianson, A. D.; Riseborough, P. S.

    2014-06-25

    We report inelastic neutron scattering experiments on a single crystal of the intermediate valence compound CePd3. At 300 K the magnetic scattering is quasielastic, with half-width G = 23 meV, and is independent of momentum transfer Q. At low temperature, the Q-averaged magnetic spectrum is inelastic, exhibiting a broad peak centered near E-max = 55 meV. These results, together with the temperature dependence of the susceptibility, 4f occupation number, and specific heat, can be fit by the Kondo/Anderson impurity model. The low temperature scattering near Emax, however, shows significant variations with Q, reflecting the coherence of the 4f lattice. The intensity is maximal at (1/2, 1/2, 0), intermediate at (1/2, 0, 0) and (0, 0, 0), and weak at (1/2, 1/2, 1/2). We discuss this Q-dependence in terms of current ideas about coherence in heavy fermion systems.

  10. Kondo hole behavior in Ce{sub 0.97} La{sub 0.03}Pd{sub 3}

    SciTech Connect (OSTI)

    Lawrence, J.M.; Graf, T.; Hundley, M.F.; Mandrus, D.; Thompson, J.D. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)] [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Lacerda, A.; Torikachvili, M.S. [National High Magnetic Field Laboratory, Pulse Facility, Los Alamos, New Mexico 87545 (United States)] [National High Magnetic Field Laboratory, Pulse Facility, Los Alamos, New Mexico 87545 (United States); Sarrao, J.L.; Fisk, Z. [National High Magnetic Field Laboratory, Florida State University, Tallahassee, Florida 32306 (United States)] [National High Magnetic Field Laboratory, Florida State University, Tallahassee, Florida 32306 (United States)

    1996-05-01

    We present results for the resistivity, the magnetoresistance, and the specific heat of Ce{sub 0.97}La{sub 0.03}Pd{sub 3} and CePd{sub 3}. The impurity contributions to these measurements follow the predictions of the single-impurity Kondo model for a Kondo temperature {ital T}{sub {ital L}}{approx_equal}65 K, assuming that the impurity behaves as a crystal-field split ({Gamma}{sub 7}) doublet. Assuming a {ital J}=5/2 impurity, the value of {ital T}{sub {ital L}} needed to fit these experiments varies from 65 to 125 K. The contribution to the susceptibility may be too small to be explained by the model. These results address whether the nonmagnetic impurity behaves as a Kondo hole. {copyright} {ital 1996 The American Physical Society.}

  11. Superconducting epitaxial thin films of CeNi{sub x}Bi{sub 2} with a bismuth square net structure

    SciTech Connect (OSTI)

    Buckow, Alexander; Kupka, Katharina; Retzlaff, Reiner; Kurian, Jose; Alff, Lambert [Institute of Materials Science, Technische Universitaet Darmstadt, 64287 Darmstadt (Germany)

    2012-10-15

    We have grown highly epitaxial and phase pure thin films of the arsenic-free pnictide compound CeNi{sub x}Bi{sub 2} on (100) MgO substrates by reactive molecular beam epitaxy (RMBE). X-ray diffraction and reflection high-energy electron diffraction of the films confirm the ZrCuSiAs structure with a Bi square net layer. Superconductivity was observed in magnetization and resistivity measurements for x= 0.75 to 0.93 in these CeNi{sub x}Bi{sub 2} thin films with the highest critical temperature of 4.05 K and a resistive transition width of 0.1 K for x= 0.86. Our results indicate that thin film deposition by RMBE provides a tool to synthesize high-quality pnictide superconductors of the novel 112 type.

  12. ME 227 CE 212 MATH 223 GE 210 CMPT 116 ABE 211CHE 210 GE 213# MATH 224

    E-Print Network [OSTI]

    Saskatchewan, University of

    GE 120 ME 227 CE 212 MATH 223 GE 210 CMPT 116 ABE 211CHE 210 GE 213# MATH 224 ABE 295 ABE 212Elective* Elective* AB E 311 ABE 313 ABE 312 GE 348#ABE 323 co-requisite ABE 327 HSS#@ HSS#@ ABE 324 GE 300# ABE 395 4TH YEAR ABE Elec* ABE Elec* ABE Elec*ABE 422 GE 449# Ag Elec* T.E.* T.E.* ABE Elec* Ag Elec

  13. Synthesis and properties of Sr2CeO4 blue emission powder phosphor for field emission displays

    E-Print Network [OSTI]

    Wang, Zhong L.

    oxalate NH4 2C2O4·H2O, Fisher, 99 % were used as raw materials. First, dissolving Sr NO3 2 and Ce NO3 3·6H Institute of Technology, Atlanta, Georgia 30332 Zhong Lin Wang School of Materials Science and Engineering phosphor, because wide band gap materials are required and the eye sensitivity is quite low in the blue

  14. J. metamorphic Geol., 2000, 18, 2340 Amphibolites with staurolite and other aluminous minerals

    E-Print Network [OSTI]

    Sandiford, Mike

    J. metamorphic Geol., 2000, 18, 23­40 Amphibolites with staurolite and other aluminous minerals: calculated mineral equilibria in NCFMASH J. ARNOLD,1 R. POWELL2 AND M. SANDIFORD3 1Department of Earth, temperature and fluid composition. The mineral equilibria in the Na 2 O­CaO­FeO­ MgO­Al 2 O 3 ­SiO 2 ­H 2 O

  15. Quantitative determination of mineral composition by powder x-ray diffraction

    DOE Patents [OSTI]

    Pawloski, G.A.

    1984-08-10

    An external standard intensity ratio method is used for quantitatively determining mineralogic compositions of samples by x-ray diffraction. The method uses ratios of x-ray intensity peaks from a single run. Constants are previously determined for each mineral which is to be quantitatively measured. Ratios of the highest intensity peak of each mineral to be quantified in the sample and the highest intensity peak of a reference mineral contained in the sample are used to calculate sample composition.

  16. JOURNAL DE PHYSIQUE Colloque C6, supplkment au no8, Tome 39, aotit 1978, page C6-781 PARAMAGNETIC SUSCEPTIBILITY OF UPt AND CePt

    E-Print Network [OSTI]

    Boyer, Edmond

    . While U and Ce both even superconduct in elemental form (under pressure) ; they can, too, support in an inert atmosphere. The UPt data were taken in a superconducting susceptometer with a measuring field

  17. Interpretation of In-Situ Tests (P.W. Mayne, October 2002, Georgia Tech: www.ce.gatech.edu/~geosys) FLOW PROPERTIES from PIEZOCONE DISSIPATION TESTS

    E-Print Network [OSTI]

    Mayne, Paul W.

    .ce.gatech.edu/~geosys) FLOW PROPERTIES from PIEZOCONE DISSIPATION TESTS Soils exhibit flow properties that control hydraulic, fat plastic clays may require 2 to 3 days for complete equalization. Representative dissipation curves

  18. STATLER COLLEGE OF ENGINEERING AND MINERAL RESOURCES FRESHMAN ENGINEERING OUT OF CLASS EXPERIENCE FORM

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    STATLER COLLEGE OF ENGINEERING AND MINERAL RESOURCES ­ FRESHMAN ENGINEERING OUT OF CLASS EXPERIENCE FORM Describe the Out of Class Experience that you attended. Print all information legibly

  19. Society for Geology Applied to Ore Deposits GENEVA MINERALS: Industry and Academia

    E-Print Network [OSTI]

    Halazonetis, Thanos

    Society for Geology Applied to Ore Deposits GENEVA MINERALS: Industry and Academia Creating links Tripodi, Vanga Resources, Geneva · A student view of economic geology. Honza Catchpole, President

  20. Three Packets of Minerals of the Periodic Table of Chemical Elements and Chemical Compounds

    E-Print Network [OSTI]

    Mikhail M. Labushev

    2013-03-20

    The concepts of alpha- and beta-packets of the periodic table of chemical elements and chemical compounds are defined. The first of the 47 minerals alpha-packets is composed. In it all minerals are arranged in increasing Iav index of proportionality of atomic weights of composing chemical elements, the same way as chemical elements are located in increasing atomic weights in the Periodic table. The packet includes 93 known minerals and two compounds - N2O5 and CO2 - being actually minerals. Beta-packet of oxides and hydroxides minerals includes 88 known minerals and five chemical compounds - N2O5, CO2, CO, SO3 and SO2. Two minerals of the packet have not been determined yet. Besides, beta-packet of minerals with sulfur, selenium or arsenic is composed, with one mineral not defined yet. The results of the calculations can be used for further development of the Periodic Table of Chemical Elements and Chemical Compounds and their properties investigation.

  1. Three Packets of Minerals of the Periodic Table of Chemical Elements and Chemical Compounds

    E-Print Network [OSTI]

    Labushev, Mikhail M

    2013-01-01

    The concepts of alpha- and beta-packets of the periodic table of chemical elements and chemical compounds are defined. The first of the 47 minerals alpha-packets is composed. In it all minerals are arranged in increasing Iav index of proportionality of atomic weights of composing chemical elements, the same way as chemical elements are located in increasing atomic weights in the Periodic table. The packet includes 93 known minerals and two compounds - N2O5 and CO2 - being actually minerals. Beta-packet of oxides and hydroxides minerals includes 88 known minerals and five chemical compounds - N2O5, CO2, CO, SO3 and SO2. Two minerals of the packet have not been determined yet. Besides, beta-packet of minerals with sulfur, selenium or arsenic is composed, with one mineral not defined yet. The results of the calculations can be used for further development of the Periodic Table of Chemical Elements and Chemical Compounds and their properties investigation.

  2. Fundamental study of CO2-H2O-mineral interactions for carbon...

    Office of Scientific and Technical Information (OSTI)

    E.; Wang, Yifeng; Matteo, Edward N.; Meserole, Stephen P.; Tallant, David Robert In the supercritical CO2-water-mineral systems relevant to subsurface CO2 sequestration,...

  3. H.R.S. 182-1 - Reservation and Disposition of Government Mineral...

    Open Energy Info (EERE)

    Rights, Definitions (2012). Retrieved from "http:en.openei.orgwindex.php?titleH.R.S.182-1-ReservationandDispositionofGovernmentMineralRights,Definitions&oldid8...

  4. The effect of minerals on the reactivity of coal char treated thermally

    SciTech Connect (OSTI)

    Zhang, S.; Lu, J.; Zhao, B.; Zhang, J.; Yue, G. [Shanghai University of Science & Technology, Shanghai (China)

    2008-07-01

    The effect of minerals on the reactivity of coal char is addressed in this article. The chars were prepared in N{sub 2} under the inert conditions from the raw coals and their demineralized samples. Thermo-gravimetric analysis (TGA) was used to examine the effect of the minerals in the coals on the reactivity of the derived chars. The effect of minerals on the reactivity of YXV char is different from that on the reactivity of JJV char. The behavior of minerals differs from each other and can be attributed to the different amount, nature, and distribution in the two coals.

  5. Title 43 CFR 3814 Disposal of Reserved Minerals Under the Stockraising...

    Open Energy Info (EERE)

    Reserved Minerals Under the Stockraising Homestead Act Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- Federal RegulationFederal Regulation:...

  6. Euclid's proposition III.35 says that if AB and CD are chords of a circle intersecting in a point E, then AE EB = CE ED.

    E-Print Network [OSTI]

    be the diameter passing through E. Then, a special case of the proposition is to show that AE · EB = FE · EG. In fact, it is enough to show this special case, because if AE · EB = FE · EG and if CE · ED = FE · EG, then by transitivity, AE · EB = CE · ED. Hence, we will proceed to prove that AE · EB = FE · EG. Let r be the radius

  7. Methanol conversion to light olefins over nanostructured CeAPSO-34 catalyst: Thermodynamic analysis of overall reactions and effect of template type on catalytic properties and performance

    SciTech Connect (OSTI)

    Aghamohammadi, Sogand; Haghighi, Mohammad; Charghand, Mojtaba

    2014-02-01

    Graphical abstract: In this research nanostructured CeAPSO-34 was synthesized to explore the effect of TEAOH and morpholine on its physiochemical properties and MTO performance. Prepared catalysts were characterized with XRD, FESEM, BET, FTIR and NH3-TPD techniques. The results indicated that the nature of the template determines the physiochemical properties of CeAPSO-34 due to different rate of crystal growth. The catalyst obtained by using morpholine showed longer life time as well as sustaining light olefins selectivity at higher values. Furthermore, a comprehensive thermodynamic analysis of overall reactions network was carried out to address the major channels of methanol to olefins conversion. - Highlights: • Introduction of Ce into SAPO-34 framework. • Comparison of CeAPSO-34 synthesized using morpholine and TEAOH. • The nature of the template determines the physiochemical properties of CeAPSO-34. • Morpholine enhances catalyst lifetime in MTO process. • Presenting a complete reaction network for MTO process. - Abstract: TEAOH and morpholine were employed in synthesis of nanostructured CeAPSO-34 molecular sieve and used in methanol to olefins conversion. Prepared samples were characterized by XRD, FESEM, EDX, BET, FTIR and NH{sub 3}-TPD techniques. XRD patterns reflected the higher crystallinity of the catalyst synthesized with morpholine. The FESEM results indicated that the nature of the template determines the morphology of nanostructured CeAPSO-34 due to different rate of crystal growth. There was a meaningful difference in the strength of both strong and weak acid sites for CeAPSO-34 catalysts synthesized with TEAOH and morpholine templates. The catalyst synthesized with morpholine showed higher desorption temperature of both weak and strong acid sites evidenced by NH{sub 3}-TPD characterization. The catalyst obtained using morpholine template had the longer lifetime and sustained desired light olefins at higher values. A comprehensive thermodynamic analysis of overall reactions network was carried out to address the major channels of methanol to olefins conversion.

  8. Crystalline Electric Field as a Probe for Long-Range Antiferromagnetic Order and Superconducting State of CeFeAsO1-xFx

    SciTech Connect (OSTI)

    Chi, Songxue; Adroja, D. T.; GUIDI, T.; Bewley, Robert I.; Li, Shiliang; Zhao, Jun; Lynn, J. W.; Brown, C. M.; Qiu, Y.; Chen, G. F,; Luo, J. L.; Wang, N. L.; Dai, Pengcheng

    2008-01-01

    We use inelastic neutron scattering to study the crystalline electric field (CEF) excitations of Ce{sup 3+} in CeFeAsO{sub 1-x}F{sub x} (x=0, 0.16). For nonsuperconducting CeFeAsO, the Ce CEF levels have three magnetic doublets in the paramagnetic state, but these doublets split into six singlets when the Fe ions order antiferromagnetically. For superconducting CeFeAsO{sub 0.84}F{sub 0.16} (T{sub c} = 41 K), where the static antiferromagnetic order is suppressed, the Ce CEF levels have three magnetic doublets at {h_bar}{sub {omega}} = 0, 18.7, 58.4 meV at all temperatures. Careful measurements of the intrinsic linewidth {Lambda} and the peak position of the 18.7 meV mode reveal a clear anomaly at T{sub c}, consistent with a strong enhancement of local magnetic susceptibility {chi}{double_prime}({h_bar}{sub {omega}}) below T{sub c}. These results suggest that CEF excitations in the rare-earth oxypnictides can be used as a probe of spin dynamics in the nearby FeAs planes.

  9. Superior performance of Ni-W-Ce mixed-metal oxide catalysts for ethanol steam reforming: Synergistic effects of W- and Ni-dopants

    SciTech Connect (OSTI)

    Rodriguez, Jose A.; Liu, Zongyuan; Xu, Wenqian; Yao, Siyu; Johnson-Peck, Aaron C.; Zhao, Fuzhen; Michorczyk, Piotr; Kubacka, Anna; Stach, Eric A.; Fernandez-Garica, Marcos; Senanayake, Sanjaya D.

    2014-11-26

    The ethanol steam reforming (ESR) reaction was studied over a series of Ni-W-Ce oxide catalysts. The structures of the catalysts were characterized using in-situ techniques including X-ray diffraction, Pair Distribution Function, X-ray absorption fine structure and transmission electron microscopy; while possible surface intermediates for the ESR reaction were investigated by Diffuse Reflectance Infrared Fourier Transform Spectroscopy. In these materials, all the W and part of the Ni were incorporated into the CeO? lattice, with the remaining Ni forming highly dispersed nano NiO (< 2 nm) outside the Ni-W-Ce oxide structure. The nano NiO was reduced to Ni under ESR conditions. The Ni-W-Ce systeme exhibited a much larger lattice strain than those seen for Ni-Ce and W-Ce. Synergistic effects between Ni and W inside ceria produced a substantial amount of defects and O vacancies that led to high catalytic activity, selectivity and stability (i.e. resistance to coke formation) during ethanol steam reforming.

  10. Superior performance of Ni-W-Ce mixed-metal oxide catalysts for ethanol steam reforming: Synergistic effects of W- and Ni-dopants

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rodriguez, Jose A. [Brookhaven National Lab. (BNL), Upton, NY (United States); State Univ. of New York Stony Brook, Stony Brook, NY (United States); Liu, Zongyuan [Brookhaven National Lab. (BNL), Upton, NY (United States); State Univ. of New York Stony Brook, Stony Brook, NY (United States); Xu, Wenqian [Brookhaven National Lab. (BNL), Upton, NY (United States); Yao, Siyu [Brookhaven National Lab. (BNL), Upton, NY (United States); Johnson-Peck, Aaron C. [Brookhaven National Lab. (BNL), Upton, NY (United States); Zhao, Fuzhen [Brookhaven National Lab. (BNL), Upton, NY (United States); Michorczyk, Piotr [Inst. de Catalisis y Petroleoquimica, Madrid (Spain); Kubacka, Anna [Inst. de Catalisis y Petroleoquimica, Madrid (Spain); Stach, Eric A. [Brookhaven National Lab. (BNL), Upton, NY (United States); Fernandez-Garica, Marcos [State Univ. of New York Stony Brook, Stony Brook, NY (United States); Senanayake, Sanjaya D. [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2015-01-01

    The ethanol steam reforming (ESR) reaction was studied over a series of Ni-W-Ce oxide catalysts. The structures of the catalysts were characterized using in-situ techniques including X-ray diffraction, Pair Distribution Function, X-ray absorption fine structure and transmission electron microscopy; while possible surface intermediates for the ESR reaction were investigated by Diffuse Reflectance Infrared Fourier Transform Spectroscopy. In these materials, all the W and part of the Ni were incorporated into the CeO? lattice, with the remaining Ni forming highly dispersed nano NiO (< 2 nm) outside the Ni-W-Ce oxide structure. The nano NiO was reduced to Ni under ESR conditions. The Ni-W-Ce systeme exhibited a much larger lattice strain than those seen for Ni-Ce and W-Ce. Synergistic effects between Ni and W inside ceria produced a substantial amount of defects and O vacancies that led to high catalytic activity, selectivity and stability (i.e. resistance to coke formation) during ethanol steam reforming.

  11. A ferromagnetic quantum critical point in heavy-fermion iron oxypnictide CeFe{sub 1?x}Cr{sub x}PO

    SciTech Connect (OSTI)

    Okano, T.; Matoba, M.; Kamihara, Y.; Kitao, S.; Seto, M.; Atou, T.; Itoh, M.

    2015-05-07

    We report crystallographic and magnetic properties of layered iron oxypnictide CeFe{sub 1?x}Cr{sub x}PO (x?=?0.000–0.692). Interlayer distances between Ce{sub 2}O{sub 2} and (Fe{sub 1?x}Cr{sub x}){sub 2}P{sub 2} layers increase as a function of x, suggesting suppression of Kondo coupling among hybridized conducting orbitals and localized Ce 4f orbitals. CeFe{sub 1?x}Cr{sub x}PO (x?=?0.100–0.384) exhibits finite ferromagnetic transition temperatures (T{sub curie}) obtained by Arrott plots, although {sup 57}Fe Mössbauer spectra reveal paramagnetic Fe sublattice at T???4.2?K. These results indicate that the ferromagnetic phase transitions of samples are mainly due to Ce sublattice. For the samples with x???0.500, no ferromagnetic order is observed down to 2?K. These results verify that ferromagnetic quantum critical points of CeFe{sub 1?x}Cr{sub x}PO appear at 0.045???x???0.100 and 0.384???x???0.500.

  12. Antiferromagnetic Kondo lattice in the layered compound CePd1–xBi? and comparison to the superconductor LaPd1–xBi?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Han, Fei; Wan, Xiangang; Phelan, Daniel; Stoumpos, Constantinos C.; Sturza, Mihai; Malliakas, Christos D.; Li, Qing'an; Han, Tian-Heng; Zhao, Qingbiao; Chung, Duck Young; et al

    2015-07-13

    The layered compound CePd1–xBi? with the tetragonal ZrCuSi?-type structure was obtained from excess Bi flux. Magnetic susceptibility data of CePd1–xBi? show an antiferromagnetic ordering below 6 K and are anisotropic along the c axis and the ab plane. The anisotropy is attributed to crystal-electric-field (CEF) effects and a CEF model which is able to describe the susceptibility data is given. An enhanced Sommerfeld coefficient ? of 0.191 J mol Ce?¹ K?² obtained from specific-heat measurement suggests a moderate Kondo effect in CePd1–xBi?. Other than the antiferromagnetic peak at 6 K, the resistivity curve shows a shoulderlike behavior around 75 Kmore »which could be attributed to the interplay between Kondo and CEF effects. Magnetoresistance and Hall-effect measurements suggest that the interplay reconstructs the Fermi-surface topology of CePd1–xBi? around 75 K. Electronic structure calculations reveal that the Pd vacancies are important to the magnetic structure and enhance the CEF effects which quench the orbital moment of Ce at low temperatures.« less

  13. Osage oil: Mineral law, murder, mayhem, and manipulation

    SciTech Connect (OSTI)

    Strickland, R.

    1995-12-31

    The greatest of the 20th century Osage chiefs, Fred Lookout, feared what the rich oil bonanza under tribal lands would do to his people. He forsaw that oil wealth could turn into a curse as well as a blessing, and it was both. The story of Osage oil is a case history in the failure of law, the failure of Indian policy and the struggle for survival of the indomitable spirit of a great Native people force to deal with both the curse and the blessing of black gold. This article examines law and policy as seen in Osage oil regulation, outlining the legal controls of the land and mineral regulatory system and briefly exploring the breakdowns of the system.

  14. Catalytic effects of minerals on NOx emission from coal combustion

    SciTech Connect (OSTI)

    Yao, M.Y.; Che, D.F.

    2007-07-01

    The catalytic effects of inherent mineral matters on NOx emissions from coal combustion have been investigated by a thermo-gravimetric analyzer (TGA) equipped with a gas analyzer. The effect of demineralization and the individual effect of Na, K, Ca, Mg, and Fe on the formation of NOx are studied as well as the combined catalytic effects of Ca + Na and Ca + Ti. Demineralization causes more Fuel-N to retain in the char, and reduction of NOx mostly. But the mechanistic effect on NOx formation varies from coal to coal. Ca and Mg promote NOx emission. Na, K, Fe suppress NOx formation to different extents. The effect of transition element Fe is the most obvious. The combination of Ca + Na and Ca + Ti can realize the simultaneous control of sulfur dioxide and nitrogen oxides emissions.

  15. Plutonium Oxidation and Subsequent Reduction by Mn (IV) Minerals

    SciTech Connect (OSTI)

    KAPLAN, DANIEL

    2005-09-13

    Plutonium sorbed to rock tuff was preferentially associated with manganese oxides. On tuff and synthetic pyrolusite (Mn{sup IV}O{sub 2}), Pu(IV) or Pu(V) was initially oxidized, but over time Pu(IV) became the predominant oxidation state of sorbed Pu. Reduction of Pu(V/VI), even on non-oxidizing surfaces, is proposed to result from a lower Gibbs free energy of the hydrolyzed Pu(IV) surface species versus that of the Pu(V) or Pu(VI) surface species. This work suggests that despite initial oxidation of sorbed Pu by oxidizing surfaces to more soluble forms, the less mobile form of Pu, Pu(IV), will dominate Pu solid phase speciation during long term geologic storage. The safe design of a radioactive waste or spent nuclear fuel geologic repository requires a risk assessment of radionuclides that may potentially be released into the surrounding environment. Geochemical knowledge of the radionuclide and the surrounding environment is required for predicting subsurface fate and transport. Although difficult even in simple systems, this task grows increasingly complicated for constituents, like Pu, that exhibit complex environmental chemistries. The environmental behavior of Pu can be influenced by complexation, precipitation, adsorption, colloid formation, and oxidation/reduction (redox) reactions (1-3). To predict the environmental mobility of Pu, the most important of these factors is Pu oxidation state. This is because Pu(IV) is generally 2 to 3 orders of magnitude less mobile than Pu(V) in most environments (4). Further complicating matters, Pu commonly exists simultaneously in several oxidation states (5, 6). Choppin (7) reported Pu may exist as Pu(IV), Pu(V), or Pu(VI) oxic natural groundwaters. It is generally accepted that plutonium associated with suspended particulate matter is predominantly Pu(IV) (8-10), whereas Pu in the aqueous phase is predominantly Pu(V) (2, 11-13). The influence of the character of Mn-containing minerals expected to be found in subsurface repository environments on Pu oxidation state distributions has been the subject of much recent research. Kenney-Kennicutt and Morse (14), Duff et al. (15), and Morgenstern and Choppin (16) observed oxidation of Pu facilitated by Mn(IV)-bearing minerals. Conversely, Shaughnessy et al. (17) used X-ray Absorption near-edge spectroscopy (XANES) to show reduction of Pu(VI) by hausmannite (Mn{sup II}Mn{sub 2}{sup III}O{sub 4}) and manganite ({gamma}-Mn{sup III}OOH) and Kersting et al., (18) observed reduction of Pu(VI) by pyrolusite (Mn{sup IV}O{sub 2}). In this paper, we attempt to reconcile the apparently conflicting datasets by showing that Mn-bearing minerals can indeed oxidize Pu, however, if the oxidized species remains on the solid phase, the oxidation step competes with the formation of Pu(IV) that becomes the predominant solid phase Pu species with time. The experimental approach we took was to conduct longer term (approximately two years later) oxidation state analyses on the Pu sorbed to Yucca Mountain tuff (initial analysis reported by Duff et al., (15)) and measure the time-dependant changes in the oxidation state distribution of Pu in the presence of the Mn mineral pyrolusite.

  16. Uranium mineralization in fluorine-enriched volcanic rocks

    SciTech Connect (OSTI)

    Burt, D.M.; Sheridan, M.F.; Bikun, J.; Christiansen, E.; Correa, B.; Murphy, B.; Self, S.

    1980-09-01

    Several uranium and other lithophile element deposits are located within or adjacent to small middle to late Cenozoic, fluorine-rich rhyolitic dome complexes. Examples studied include Spor Mountain, Utah (Be-U-F), the Honeycomb Hills, Utah (Be-U), the Wah Wah Mountains, Utah (U-F), and the Black Range-Sierra Cuchillo, New Mexico (Sn-Be-W-F). The formation of these and similar deposits begins with the emplacement of a rhyolitic magma, enriched in lithophile metals and complexing fluorine, that rises to a shallow crustal level, where its roof zone may become further enriched in volatiles and the ore elements. During initial explosive volcanic activity, aprons of lithicrich tuffs are erupted around the vents. These early pyroclastic deposits commonly host the mineralization, due to their initial enrichment in the lithophile elements, their permeability, and the reactivity of their foreign lithic inclusions (particularly carbonate rocks). The pyroclastics are capped and preserved by thick topaz rhyolite domes and flows that can serve as a source of heat and of additional quantities of ore elements. Devitrification, vapor-phase crystallization, or fumarolic alteration may free the ore elements from the glassy matrix and place them in a form readily leached by percolating meteoric waters. Heat from the rhyolitic sheets drives such waters through the system, generally into and up the vents and out through the early tuffs. Secondary alteration zones (K-feldspar, sericite, silica, clays, fluorite, carbonate, and zeolites) and economic mineral concentrations may form in response to this low temperature (less than 200 C) circulation. After cooling, meteoric water continues to migrate through the system, modifying the distribution and concentration of the ore elements (especially uranium).

  17. SESAME 96170, a solid-liquid equation of state for CeO2

    SciTech Connect (OSTI)

    Chisolm, Eric D.

    2014-05-02

    I describe an equation of state (EOS) for the low-pressure solid phase and liquid phase of cerium (IV) oxide, CeO2. The models and parameters used to calculate the EOS are presented in detail, and I compare with data for the full-density crystal. Hugoniot data are available only for high-porosity powders, and I discuss difficulties in comparing with such data. I have constructed SESAME 96170, an EOS for cerium (IV) oxide that includes the ambient solid and liquid phases. The EOS extends over the full standard SESAME range, but should not be used at low temperatures and high densities because of the lack of a high-pressure solid phase. I have described the models used to compute the three terms of the EOS (cold curve, nuclear, and thermal electronic), and I have given the parameters used in the models. They were determined by comparison with experimental data at P = 1 atm, including the constant-pressure specific heat, coefficient of thermal expansion, and melting and boiling points. The EOS compares well with data in its intended range of validity, but the presence of high-frequency optical modes in its phonon spectrum limits the agreement of our models with thermal data. The next step is to construct a multiphase EOS that includes the low- and high-pressure solid phases and the liquid. The DAC data from Duclos will most strongly constrain the parameters of the high-pressure solid. A remaining issue is the comparison of the crystal-density EOS with experimental Hugoniot data, which are taken at much lower initial data because the samples are porous powders. A satisfactory means of modeling porosity, allowing comparison of theory and experiment, has not yet been produced.

  18. The effect of modifications of dietary fat, fiber and sodium with magnesium deficiency on serum lipids and minerals, tissue and femur minerals and femur load force 

    E-Print Network [OSTI]

    Howe, Cathlyn Ann

    1992-01-01

    concentration of selected tissues and femur, and load force of femurs. The minerals investigated were magnesium, calcium, phosphorus and zinc. The control (C) diet was based upon the AIM-76 diet formulation; the American (A) included average fat, fiber... in those in the A and R groups, respectively. Renal calcium was not affected by magnesium deficiency except in the rats fed the recommended diets. The RL rats had higher renal calcium than R animals. Cardiac mineral concentrations were higher in the C...

  19. Structural and magnetic properties in the polymorphs of CeRh{sub 0.5}Ge{sub 1.5}

    SciTech Connect (OSTI)

    Kalsi, Deepti; Subbarao, Udumula [New Chemistry Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore-560064 (India); Rayaprol, Sudhindra [UGC-DAE Consortium for Scientific Research, R-5 Shed, B.A.R.C Campus, Trombay, Mumbai-400085 (India); Peter, Sebastian C., E-mail: sebastiancp@jncasr.ac.in [New Chemistry Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore-560064 (India)

    2014-04-01

    We investigate the structural and magnetic properties in the polymorphs of a new compound CeRh{sub 0.5}Ge{sub 1.5}. Depending upon the starting materials, and the slightly different synthesis method, we find that CeRh{sub 0.5}Ge{sub 1.5} compound exists in two different space groups. The first compound, ?-CeRh{sub 0.5}Ge{sub 1.5} crystallizes in tetragonal ?-ThSi{sub 2} structure type in space group I4{sub 1}/amd with lattice parameters, a=4.2034(6) Å and c=14.770(3) Å. In this structure, the cerium atoms occupy the position between the Rh/Ge tetrahedral layers. On the other hand, the second compound, namely ?-CeRh{sub 0.5}Ge{sub 1.5} crystallizes in the AlB{sub 2} type hexagonal structure in space group P6/mmm, with lattice parameters, a=4.2615(7) Å and c=4.1813(9) Å. The crystal structure of ?-CeRh{sub 0.5}Ge{sub 1.5} consists of two dimensional Rh/Ge hexagonal units and the cerium atoms are sandwiched between them. Magnetization studies exhibit magnetic ordering, as evident from a sharp peak in the plot of magnetic susceptibility measured as a function of temperature in a fixed magnetic field, in ?-CeRh{sub 0.5}Ge{sub 1.5} and ?-CeRh{sub 0.5}Ge{sub 1.5} at 3.6 K and 12 K, respectively. Structural and magnetic properties of both compounds are presented and discussed here. - Graphical abstract: Two polymorphs of a new compound CeRh{sub 0.5}Ge{sub 1.5} in the ?-ThSi{sub 2} and AlB{sub 2} structure types were synthesized by arc melting. The magnetic measurements of both CeRh{sub 0.5}Ge{sub 1.5} phases suggest spin-glass behavior. - Highlights: • A new compound CeRh{sub 0.5}Ge{sub 1.5} in two difference phases was synthesized by arc melting. • The crystal structure of both compounds was determined from the single crystal XRD. • Isothermal relaxation measurements suggesting spin-glass like anomalies in both phases.

  20. Hierarchical heterogeneity at the CeOx-TiO? interface: Electronic and geometric structural influence on the photocatalytic activity of oxide on oxide nanostructures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Luo, Si [Brookhaven National Lab. (BNL), Upton, NY (United States); Nguyen-Phan, Thuy-Duong [Brookhaven National Lab. (BNL), Upton, NY (United States); Johnston-Peck, Aaron C. [Brookhaven National Lab. (BNL), Upton, NY (United States); Barrio, Laura [CSIC - Inst. de Catalisis y Petroleoquimica, Madrid (Spain); Sallis, Shawn [Binghamton Univ., NY (United States); Arena, Dario A. [Brookhaven National Lab. (BNL), Upton, NY (United States); Kundu, Shankhamala [Brookhaven National Lab. (BNL), Upton, NY (United States); Xu, Wenqian [Brookhaven National Lab. (BNL), Upton, NY (United States); Piper, Louis F. J. [Binghamton Univ., NY (United States); Stach, Eric A. [Brookhaven National Lab. (BNL), Upton, NY (United States); Polyansky, Dmitry E. [Brookhaven National Lab. (BNL), Upton, NY (United States); Fujita, Etsuko [Brookhaven National Lab. (BNL), Upton, NY (United States); Rodriguez, José A. [Brookhaven National Lab. (BNL), Upton, NY (United States); CSIC - Inst. de Catalisis y Petroleoquimica, Madrid (Spain); Senanayake, Sanjaya D. [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2015-01-27

    Mixed oxide interfaces are critical for delivering active components of demanding catalytic processes such as the photo-catalytic splitting of water. We have studied CeOxTiO? catalysts with low ceria loadings of 1 wt%, 3 wt% and 6 wt% that were prepared with wet impregnation methods to favor a strong interaction between CeOx and TiO?. In these materials the interfaces between CeOx-TiO? have been sequentially loaded (1%, 3% and 6%), with and without Pt (0.5 wt%). The structure and properties of the catalysts were characterized using several X-ray and electron based techniques including XRD, XPS, UPS, NEXAFS, UV-Vis and HR-STEM/STEM-EELS, to unravel the local morphology, bulk structure, surface states and electronic structure. The combination of all these techniques allow us to analyze in a systematic way the complete structural and electronic properties that prevail at the CeOx-TiO? interface. Fluorite structured nano crystallites of ceria on anatase-structured titania were identified by both XRD and NEXAFS. A sequential increasing of the CeOx loading led to the formation of clusters, then plates and finally nano particles in a hierarchical manner on the TiO? support. The electronic structures of these catalysts indicate that the interaction between TiO? and CeO? is closely related to the local morphology of nanostructured CeO?. Ce³? cations were detected at the surface of CeO? and at the interface of the two oxides. In addition, the titania is perturbed by the interaction with ceria and also with Pt. The photocatalytic activity for the splitting of H?O using UV light was measured for these materials and correlated with our understanding of the electronic and structural properties. Optimal catalytic performance and photo response results were found for the 1 wt% CeOx-TiO? catalyst where low dimensional geometry of the ceria provided ideal electronic and geometrical properties. The structural and electronic properties of the interface were critical for the photocatalytic performance of this mixed-oxide nanocatalyst system.

  1. Hierarchical Heterogeneity at the CeO x –TiO 2 Interface: Electronic and Geometric Structural Influence on the Photocatalytic Activity of Oxide on Oxide Nanostructures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Luo, Si; Nguyen-Phan, Thuy-Duong; Johnston-Peck, Aaron C.; Barrio, Laura; Sallis, Shawn; Arena, Dario A.; Kundu, Shankhamala; Xu, Wenqian; Piper, Louis F. J.; Stach, Eric A.; et al

    2015-01-13

    Mixed oxide interfaces are critical for delivering active components of demanding catalytic processes such as the photo-catalytic splitting of water. We have studied CeOxTiO? catalysts with low ceria loadings of 1 wt%, 3 wt% and 6 wt% that were prepared with wet impregnation methods to favor a strong interaction between CeOx and TiO?. In these materials the interfaces between CeOx-TiO? have been sequentially loaded (1%, 3% and 6%), with and without Pt (0.5 wt%). The structure and properties of the catalysts were characterized using several X-ray and electron based techniques including XRD, XPS, UPS, NEXAFS, UV-Vis and HR-STEM/STEM-EELS, to unravelmore »the local morphology, bulk structure, surface states and electronic structure. The combination of all these techniques allow us to analyze in a systematic way the complete structural and electronic properties that prevail at the CeOx-TiO? interface. Fluorite structured nano crystallites of ceria on anatase-structured titania were identified by both XRD and NEXAFS. A sequential increasing of the CeOx loading led to the formation of clusters, then plates and finally nano particles in a hierarchical manner on the TiO? support. The electronic structures of these catalysts indicate that the interaction between TiO? and CeO? is closely related to the local morphology of nanostructured CeO?. Ce³? cations were detected at the surface of CeO? and at the interface of the two oxides. In addition, the titania is perturbed by the interaction with ceria and also with Pt. The photocatalytic activity for the splitting of H?O using UV light was measured for these materials and correlated with our understanding of the electronic and structural properties. Optimal catalytic performance and photo response results were found for the 1 wt% CeOx-TiO? catalyst where low dimensional geometry of the ceria provided ideal electronic and geometrical properties. The structural and electronic properties of the interface were critical for the photocatalytic performance of this mixed-oxide nanocatalyst system.« less

  2. Hierarchical heterogeneity at the CeOx-TiO? interface: Electronic and geometric structural influence on the photocatalytic activity of oxide on oxide nanostructures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    None

    2015-01-13

    Mixed oxide interfaces are critical for delivering active components of demanding catalytic processes such as the photo-catalytic splitting of water. We have studied CeOxTiO? catalysts with low ceria loadings of 1 wt%, 3 wt% and 6 wt% that were prepared with wet impregnation methods to favor a strong interaction between CeOx and TiO?. In these materials the interfaces between CeOx-TiO? have been sequentially loaded (1%, 3% and 6%), with and without Pt (0.5 wt%). The structure and properties of the catalysts were characterized using several X-ray and electron based techniques including XRD, XPS, UPS, NEXAFS, UV-Vis and HR-STEM/STEM-EELS, to unravelmore »the local morphology, bulk structure, surface states and electronic structure. The combination of all these techniques allow us to analyze in a systematic way the complete structural and electronic properties that prevail at the CeOx-TiO? interface. Fluorite structured nano crystallites of ceria on anatase-structured titania were identified by both XRD and NEXAFS. A sequential increasing of the CeOx loading led to the formation of clusters, then plates and finally nano particles in a hierarchical manner on the TiO? support. The electronic structures of these catalysts indicate that the interaction between TiO? and CeO? is closely related to the local morphology of nanostructured CeO?. Ce³? cations were detected at the surface of CeO? and at the interface of the two oxides. In addition, the titania is perturbed by the interaction with ceria and also with Pt. The photocatalytic activity for the splitting of H?O using UV light was measured for these materials and correlated with our understanding of the electronic and structural properties. Optimal catalytic performance and photo response results were found for the 1 wt% CeOx-TiO? catalyst where low dimensional geometry of the ceria provided ideal electronic and geometrical properties. The structural and electronic properties of the interface were critical for the photocatalytic performance of this mixed-oxide nanocatalyst system.« less

  3. Mineral dust emission from the Bodele Depression, northern Chad, during BoDEx 2005

    E-Print Network [OSTI]

    Washington, Richard

    distribution of this diatomite dust estimated from sun photometer data, using a modified Aeronet retrieval loadings results in a reduction in surface daytime maximum temperature of around 7°C in the Bode´le´ region-blown terrestrial mineral dust. The distribution, properties of mineral dust and its climate impact are poorly

  4. Characterizing coal and mineral mines as a regional source of stress to stream fish assemblages

    E-Print Network [OSTI]

    Characterizing coal and mineral mines as a regional source of stress to stream fish assemblages, impervious surface or urban land use), mining had a more pronounced and consistent impact on fish assemblages biota to coal and mineral mines located in stream catchments have historically been conducted

  5. U.S. Geological Survey Energy and Minerals Science Strategy--A Resource Lifecycle Approach

    E-Print Network [OSTI]

    of Agriculture National Agricultural Imagery Program. Wind turbines. Photograph by Don Becker, USGS. The BlueU.S. Geological Survey Energy and Minerals Science Strategy--A Resource Lifecycle Approach Circular and Minerals Science Strategy--A Resource Lifecycle Approach By Richard C. Ferrero, Jonathan J. Kolak, Donald J

  6. PEPPER (JALAPEO): Capsicum annuum L., `Milta' CONTROL OF SILVERLEAF WHITEFLY IN PEPPER WITH HORTICULTURAL MINERAL OIL

    E-Print Network [OSTI]

    Ma, Lena

    WITH HORTICULTURAL MINERAL OIL AND OTHER INSECTICIDES, 2004 P. A. Stansly University of Florida/IFAS Southwest of horticultural mineral oil (HMO) and various pesticide regimes directed primarily at pepper weevil. Greenhouse of the HMO, PureSpray Green Oil, were made starting 14 Apr using a high clearance sprayer operating at 200

  7. Electrical conductivity of minerals and rocks Shun-ichiro Karato1

    E-Print Network [OSTI]

    1 Electrical conductivity of minerals and rocks Shun-ichiro Karato1 and Duojun Wang1,2 1 : Yale-Blackwell #12;2 SUMMARY Electrical conductivity of most minerals is sensitive to hydrogen (water) content, temperature, major element chemistry and oxygen fugacity. The influence of these parameters on electrical

  8. An epidemiological study of salt miners in diesel and nondiesel mines

    SciTech Connect (OSTI)

    Gamble, J.; Jones, W.; Hudak, J.

    1983-01-01

    A cross-sectional study of 5 NaCl mines and 259 miners addressed the following questions: 1) Is there an association of increased respiratory symptoms, radiographic findings, and reduced pulmonary function with exposure to nitrogen dioxide (NO2) and/or respirable particulate (RP) among these miners. 2) Is there increased morbidity of these miners compared to other working populations. Personal samples of NO2 and respirable particulate for jobs in each mine were used to estimate cumulative exposure. NO2 is used as a surrogate measure of diesel exposure. Cough was associated with age and smoking, dyspnea with age; neither symptom was associated with exposure (years worked, estimated cumulative NO2 or RP exposure). Phlegm was associated with age, smoking, and exposure. Reduced pulmonary function (FVC, FEV1, peak, flow, FEF50, FEF75) showed no association with exposure. There was one case of small rounded and one case of small irregular opacities; pneumoconiosis was not analyzed further. Compared to underground coal miners, above ground coal miners, potash miners, and nonmining workers, the study population after adjustment for age and smoking generally showed no increased prevalence of cough, phlegm, dyspnea, or obstruction (FEV1/FVC less than 0.7). Obstruction in younger salt miners and phlegm in older salt miners was elevated compared to nonmining workers. Mean predicted pulmonary function was reduced 2-4% for FEV1 and FVC, 7-13% for FEF50, and 18-22% for FEF75 below all comparison populations.

  9. Metallogeny of precious and base metal mineralization in the Murchison Greenstone Belt, South Africa

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Metallogeny of precious and base metal mineralization in the Murchison Greenstone Belt, South The 3.09-2.97 Ga Murchison Greenstone Belt is an important metallotect in the northern Kaapvaal Craton that the major styles of orogenic Au-Sb and the Cu-Zn VMS mineralization in the Murchison Greenstone Belt

  10. Kinetics of Mineral Dissolution and Growth as Reciprocal Microscopic Surface Processes Across

    E-Print Network [OSTI]

    Dove, Patricia M.

    and defects of minerals and materials. Keywords: mineral, dissolution, demineralization, growth, AFM, surface scientists alike are investigating the formation and demineralization of ionic and covalently bonded phases' methods that evaluated the rates and mechanisms of growth and demineralization using indirect methods

  11. Running Head: Correlation of Microbial Communities with Caclium Carbonate1 (Travertine) Mineral Precipitation2

    E-Print Network [OSTI]

    Goldenfeld, Nigel

    Precipitation2 3 4 Correlation of Microbial Communities with Calcium Carbonate (Travertine)5 Mineral Precipitation at Mammoth Hot Springs, Yellowstone National Park, USA6 George T. Bonheyo1, 3 , Jorge Frias-Lopez1 of changing environmental conditions and associated calcium carbonate mineral18 precipitation along the spring

  12. Recent Leaf-Litter-Derived Carbon Is Not a Major Source for Mineral Soil Microbial Communities

    E-Print Network [OSTI]

    Post, Wilfred M.

    Recent Leaf-Litter-Derived Carbon Is Not a Major Source for Mineral Soil Microbial Communities mineral soil microbes. ·The results provided quantitative evidence that root-derived C is the major (>60: Microbial communities in soil A horizons derive their carbon from several potential sources: organic carbon

  13. Analysis of stream sediment reconnaissance data for mineral resources from the Montrose NTMS Quadrangle, Colorado

    SciTech Connect (OSTI)

    Beyth, M.; Broxton, D.; McInteer, C.; Averett, W.R.; Stablein, N.K.

    1980-06-01

    Multivariate statistical analysis to support the National Uranium Resource Evaluation and to evaluate strategic and other commercially important mineral resources was carried out on Hydrogeochemical and Stream Sediment Reconnaissance data from the Montrose quadrangle, Colorado. The analysis suggests that: (1) the southern Colorado Mineral Belt is an area favorable for uranium mineral occurrences; (2) carnotite-type occurrences are likely in the nose of the Gunnison Uplift; (3) uranium mineral occurrences may be present along the western and northern margins of the West Elk crater; (4) a base-metal mineralized area is associated with the Uncompahgre Uplift; and (5) uranium and base metals are associated in some areas, and both are often controlled by faults trending west-northwest and north.

  14. Fabrication and microstructure of cerium doped lutetium aluminum garnet (Ce:LuAG) transparent ceramics by solid-state reaction method

    SciTech Connect (OSTI)

    Li, Junlang; Xu, Jian; Shi, Ying; Qi, Hongfang; Xie, Jianjun; Lei, Fang

    2014-07-01

    Highlights: • We fabricate Ce doped lutetium aluminum garnet ceramics by solid-state method. • The raw materials include Lu{sub 2}O{sub 3} nanopowders synthesized by co-precipitation method. • The density of the transparent ceramics reach 99.7% of the theoretical value. • The optical transmittance of the bulk ceramic at 550 nm was 57.48%. • Some scattering centers decrease the optical characteristic of the ceramic. - Abstract: Polycrystalline Ce{sup 3+} doped lutetium aluminum garnet (Ce:LuAG) transparent ceramics fabricated by one step solid-state reaction method using synthetic nano-sized Lu{sub 2}O{sub 3}, commercial ?-Al{sub 2}O{sub 3} and CeO{sub 2} powders were investigated in this paper. The green compacts shaped by the mixed powders were successfully densified into Ce:LuAG transparent ceramics after vacuum sintering at 1750 °C for 10 h. The in-line optical transmittance of the Ce:LuAG ceramic made by home-made Lu{sub 2}O{sub 3} powders could reach 57.48% at 550 nm, which was higher than that of the ceramic made by commercial Lu{sub 2}O{sub 3} powders (22.96%). The microstructure observation showed that light scattering centers caused by micro-pores, aluminum segregation and refraction index inhomogeneities induced the decrease of optical transparency of the Ce:LuAG ceramics, which should be removed and optimized in the future work.

  15. Degradation of dome cutting minerals in Hanford waste

    SciTech Connect (OSTI)

    Reynolds, Jacob G.; Huber, Heinz J.; Cooke, Gary A.

    2013-01-11

    At the Hanford Tank Farms, recent changes in retrieval technology require cutting new risers in several single-shell tanks. The Hanford Tank Farm Operator is using water jet technology with abrasive silicate minerals such as garnet or olivine to cut through the concrete and rebar dome. The abrasiveness of these minerals, which become part of the high-level waste stream, may enhance the erosion of waste processing equipment. However, garnet and olivine are not thermodynamically stable in Hanford waste, slowly degrading over time. How likely these materials are to dissolve completely in the waste before the waste is processed in the Waste Treatment and Immobilization Plant can be evaluated using theoretical analysis for olivine and collected direct experimental evidence for garnet. Based on an extensive literature study, a large number of primary silicates decompose into sodalite and cancrinite when exposed to Hanford waste. Given sufficient time, the sodalite also degrades into cancrinite. Even though cancrinite has not been directly added to any Hanford tanks during process times, it is the most common silicate observed in current Hanford waste. By analogy, olivine and garnet are expected to ultimately also decompose into cancrinite. Garnet used in a concrete cutting demonstration was immersed in a simulated supernate representing the estimated composition of the liquid retrieving waste from Hanford tank 241-C-107 at both ambient and elevated temperatures. This simulant was amended with extra NaOH to determine if adding caustic would help enhance the degradation rate of garnet. The results showed that the garnet degradation rate was highest at the highest NaOH concentration and temperature. At the end of 12 weeks, however, the garnet grains were mostly intact, even when immersed in 2 molar NaOH at 80 deg C. Cancrinite was identified as the degradation product on the surface of the garnet grains. In the case of olivine, the rate of degradation in the high-pH regimes of a waste tank is expected to depend on two main parameters: carbonate is expected to slow olivine degradation rates, whereas hydroxide is expected to enhance olivine dissolution rates. Which of these two competing dissolution drivers will have a larger impact on the dissolution rate in the specific environment of a waste tank is currently not identifiable. In general, cancrinite is much smaller and less hard than either olivine or garnet, so would be expected to be less erosive to processing equipment. Complete degradation of either garnet or olivine prior to being processed at the Waste Treatment and Immobilization Plant cannot be confirmed, however.

  16. Degradation of Dome Cutting Minerals in Hanford Waste - 13100

    SciTech Connect (OSTI)

    Reynolds, Jacob G.; Cooke, Gary A.; Huber, Heinz J. [Washington River Protection Solutions, LLC, P.O. Box 850, Richland, WA 99352 (United States)] [Washington River Protection Solutions, LLC, P.O. Box 850, Richland, WA 99352 (United States)

    2013-07-01

    At the Hanford Tank Farms, recent changes in retrieval technology require cutting new risers in several single-shell tanks. The Hanford Tank Farm Operator is using water jet technology with abrasive silicate minerals such as garnet or olivine to cut through the concrete and rebar dome. The abrasiveness of these minerals, which become part of the high-level waste stream, may enhance the erosion of waste processing equipment. However, garnet and olivine are not thermodynamically stable in Hanford waste, slowly degrading over time. How likely these materials are to dissolve completely in the waste before the waste is processed in the Waste Treatment and Immobilization Plant can be evaluated using theoretical analysis for olivine and collected direct experimental evidence for garnet. Based on an extensive literature study, a large number of primary silicates decompose into sodalite and cancrinite when exposed to Hanford waste. Given sufficient time, the sodalite also degrades into cancrinite. Even though cancrinite has not been directly added to any Hanford tanks during process times, it is the most common silicate observed in current Hanford waste. By analogy, olivine and garnet are expected to ultimately also decompose into cancrinite. Garnet used in a concrete cutting demonstration was immersed in a simulated supernate representing the estimated composition of the liquid retrieving waste from Hanford tank 241-C-107 at both ambient and elevated temperatures. This simulant was amended with extra NaOH to determine if adding caustic would help enhance the degradation rate of garnet. The results showed that the garnet degradation rate was highest at the highest NaOH concentration and temperature. At the end of 12 weeks, however, the garnet grains were mostly intact, even when immersed in 2 molar NaOH at 80 deg. C. Cancrinite was identified as the degradation product on the surface of the garnet grains. In the case of olivine, the rate of degradation in the high-pH regimes of a waste tank is expected to depend on two main parameters: carbonate is expected to slow olivine degradation rates, whereas hydroxide is expected to enhance olivine dissolution rates. Which of these two competing dissolution drivers will have a larger impact on the dissolution rate in the specific environment of a waste tank is currently not identifiable. In general, cancrinite is much smaller and less hard than either olivine or garnet, so would be expected to be less erosive to processing equipment. Complete degradation of either garnet or olivine prior to being processed at the Waste Treatment and Immobilization Plant cannot be confirmed, however. (authors)

  17. Comparative Gamma Spectroscopy with SrI2(Eu), GYGAG(Ce) and Bi-loaded Plastic Scintillators

    SciTech Connect (OSTI)

    Cherepy, N J

    2010-11-19

    We are developing new scintillator materials that offer potential for high resolution gamma ray spectroscopy at low cost. Single crystal SrI{sub 2}(Eu) offers {approx}3% resolution at 662 keV, in sizes of {approx}1 in{sup 3}. We have developed ceramics processing technology allowing us to achieve cubic inch scale transparent ceramic scintillators offering gamma spectroscopy performance superior to NaI(Tl). We fabricated a bismuth-loaded plastic scintillator that demonstrates energy resolution of {approx}8% at 662 keV in small sizes. Gamma ray spectroscopy can be used to identify the presence of weak radioactive sources within natural background. The ability to discriminate close-lying spectral lines is strongly dependent upon the energy resolution of the detector. In addition to excellent energy resolution, large volume detectors are needed to acquire sufficient events, for example, to identify a radioactive anomaly moving past a detector. We have employed a 'directed search' methodology for identifying potential scintillator materials candidates, resulting in the discovery of Europium-doped Strontium Iodide, SrI{sub 2}(Eu), Cerium-doped Gadolinium Garnet, GYGAG(Ce), and Bismuth-loaded Polymers. These scintillators possess very low self-radioactivity, offer energy resolution of 3-8% at 662 keV, and have potential to be grown cost-effectively to sizes similar to the most widely deployed gamma spectroscopy scintillator, Thallium-doped Sodium Iodide, NaI(Tl). In this study, gamma ray spectra of a variety of sources, were obtained employing SrI{sub 2}(Eu), GYGAG(Ce), Bi-loaded polymers, LaBr{sub 3}(Ce), and NaI(Tl). The effects of detector size, energy resolution, and background radioactivity (including self-radioactivity) on the ability to distinguish weak sources is quantified, based on a simple model, and qualitatively compared to laboratory data.

  18. Effects of aluminosilicate minerals in clay soil fractions on pore water hydroxide ion concentrations in soil/cement matrices 

    E-Print Network [OSTI]

    Cook, Evan Russell

    1998-01-01

    between clay minerals and calcium hydroxide. Pozzolanic reactions between aluminosilicate minerals in soils and portiandite or calcium silicate hydrate, generated by cement hydration, may significantly reduce the hydroxide ion concentration in soi...

  19. The mineral content of water as a variable in the quality control of reconstituted non-fat dry milk products 

    E-Print Network [OSTI]

    Kapsalis, John G.

    1959-01-01

    Expansive clay mineral contamination of road aggregate materials in Texas is a persistent problem. Hydrous layer silicate minerals - particularly smectites - in concretes are associated with decreased strength and durability in Portland cement...

  20. The aggregation of clay minerals and marine microalgal cells : physicochemical theory and implications for controlling harmful algal blooms

    E-Print Network [OSTI]

    Sengco, Mario Rhuel

    2001-01-01

    In recent years, the use of clay minerals has emerged as one of the most promising strategies for directly controlling harmful algal blooms (HABs). Its principle is based on the mutual aggregation of algal cells and mineral ...

  1. Generation and reactivity of putative support systems, Ce-Al neutral binary oxide nanoclusters: CO oxidation and C–H bond activation

    SciTech Connect (OSTI)

    Wang, Zhe-Chen; Yin, Shi; Bernstein, Elliot R.

    2013-11-21

    Both ceria (CeO{sub 2}) and alumina (Al{sub 2}O{sub 3}) are very important catalyst support materials. Neutral binary oxide nanoclusters (NBONCs), Ce{sub x}Al{sub y}O{sub z}, are generated and detected in the gas phase and their reactivity with carbon monoxide (CO) and butane (C{sub 4}H{sub 10}) is studied. The very active species CeAlO{sub 4}{sup •} can react with CO and butane via O atom transfer (OAT) and H atom transfer (HAT), respectively. Other Ce{sub x}Al{sub y}O{sub z} NBONCs do not show reactivities toward CO and C{sub 4}H{sub 10}. The structures, as well as the reactivities, of Ce{sub x}Al{sub y}O{sub z} NBONCs are studied theoretically employing density functional theory (DFT) calculations. The ground state CeAlO{sub 4}{sup •} NBONC possesses a kite-shaped structure with an O{sub t}CeO{sub b}O{sub b}AlO{sub t} configuration (O{sub t}, terminal oxygen; O{sub b}, bridging oxygen). An unpaired electron is localized on the O{sub t} atom of the AlO{sub t} moiety rather than the CeO{sub t} moiety: this O{sub t} centered radical moiety plays a very important role for the reactivity of the CeAlO{sub 4}{sup •} NBONC. The reactivities of Ce{sub 2}O{sub 4}, CeAlO{sub 4}{sup •}, and Al{sub 2}O{sub 4} toward CO are compared, emphasizing the importance of a spin-localized terminal oxygen for these reactions. Intramolecular charge distributions do not appear to play a role in the reactivities of these neutral clusters, but could be important for charged isoelectronic BONCs. DFT studies show that the reaction of CeAlO{sub 4}{sup •} with C{sub 4}H{sub 10} to form the CeAlO{sub 4}H•C{sub 4}H{sub 9}{sup •} encounter complex is barrierless. While HAT processes have been previously characterized for cationic and anionic oxide clusters, the reported study is the first observation of a HAT process supported by a ground state neutral oxide cluster. Mechanisms for catalytic oxidation of CO over surfaces of Al{sub x}O{sub y}/M{sub m}O{sub n} or M{sub m}O{sub n}/Al{sub x}O{sub y} materials are proposed consistent with the presented experimental and theoretical results.

  2. Mineral ecophysiological evidence for microbial activity in banded iron formation

    SciTech Connect (OSTI)

    Li, Dr. Yi-Liang [University of Tennessee, Knoxville (UTK); Konhauser, Dr, Kurt [University of Alberta; Cole, David R [ORNL; Phelps, Tommy Joe [ORNL

    2011-01-01

    The phosphorus composition of banded-iron formations (BIFs) has been used as a proxy for Precambrian seawater composition and the paleoeredox state of Earth's surface environment. However, it is unclear whether the phosphorus in BIFs originally entered the sediment as a sorbed component of the iron oxyhydroxide particles, or whether it was incorporated into the biomass of marine phytoplankton. We conducted high-resolution mineral analyses and report here the first detection of an Fe(III) acetate salt, as well as nanocrystals of apatite in association with magnetite, in the 2.48 Ga Dales Gorge Member of the Brockman Iron Formation (a BIF), Hamersley, Western Australia. The clusters of apatite are similar in size and morphology to biogenic apatite crystals resulting from biomass decay in Phanerozoic marine sediments, while the formation of an Fe(III) acetate salt and magnetite not only implies the original presence of biomass in the BIF sediments, but also that organic carbon likely served as an electron donor during bacterial Fe(III) reduction. This study is important because it suggests that phytoplankton may have played a key role in the transfer of phosphorus (and other trace elements) from the photic zone to the seafloor.

  3. Electrical properties of dispersions of graphene in mineral oil

    SciTech Connect (OSTI)

    Monteiro, O. R.

    2014-02-03

    Dispersions of graphene in mineral oil have been prepared and electrical conductivity and permittivity have been measured. The direct current (DC) conductivity of the dispersions depends on the surface characteristics of the graphene platelets and followed a percolation model with a percolation threshold ranging from 0.05 to 0.1?wt. %. The difference in DC conductivities can be attributed to different states of aggregation of the graphene platelets and to the inter-particle electron transfer, which is affected by the surface radicals. The frequency-dependent conductivity (?(?)) and permittivity (?(?)) were also measured. The conductivity of dispersions with particle contents much greater than the percolation threshold remains constant and equal to the DC conductivity at low frequencies ? with and followed a power-law ?(?)???{sup s} dependence at very high frequencies with s?0.9. For dispersions with graphene concentration near the percolation threshold, a third regime was displayed at intermediate frequencies indicative of interfacial polarization consistent with Maxwell-Wagner effect typically observed in mixtures of two (or more) phases with very distinct electrical and dielectric properties.

  4. Geothermal Geodatabase for Wagon Wheel Hot Springs, Mineral County, Colorado

    SciTech Connect (OSTI)

    Zehner, Richard

    2012-11-01

    Geothermal Geodatabase for Wagon Wheel Hot Springs, Mineral County, Colorado By Richard “Rick” Zehner Geothermal Development Associates Reno Nevada USA 775.737.7806 rzehner@gdareno.com For Flint Geothermal LLC, Denver Colorado Part of DOE Grant EE0002828 2013 This is an ESRI geodatabase version 10, together with an ESRI MXD file version 10.2 Data is in UTM Zone 13 NAD27 projection North boundary: approximately 4,189,000 South boundary: approximately 4,170,000 West boundary: approximately 330,000 East boundary: approximately 351,000 This geodatabase was built to cover several geothermal targets developed by Flint Geothermal in 2012 during a search for high-temperature systems that could be exploited for electric power development. Several of the thermal springs at Wagon Wheel Gap have geochemistry and geothermometry values indicative of high-temperature systems. The datasets in the geodatabase are a mixture of public domain data as well as data collected by Flint Geothermal, now being made public. It is assumed that the user has internet access, for the mxd file accesses ESRI’s GIS servers. Datasets include: 1. Results of reconnaissance shallow (2 meter) temperature surveys 2. Air photo lineaments 3. Groundwater geochemistry 4. Power lines 5. Georeferenced geologic map of Routt County 6. Various 1:24,000 scale topographic maps

  5. Comparative Federal Budgeting of Medical Entitlements: The Cases of the End-Stage Renal Disease and Coal Miner Pneumoconiosus Programs

    E-Print Network [OSTI]

    Chow, Jack C

    1985-01-01

    p.267. Corrigan, R. , "Miners Rally to Block Black LungStage Renal Disease and Coal Miner Pneumoconiosus ProgramsChapter Two: The Federal Coal Miner Black Lung Entitlement &

  6. 069 MCNITORINGTHE GROWTH OF SEODNDARYPRECIPITATES UPON METALSORPTICN CM CLAY MINERALS AND ALUMINUM OXIDES USING X-RAY ABSORPTICN FINE STRUCIURE (XAFS)

    E-Print Network [OSTI]

    Sparks, Donald L.

    069 MCNITORINGTHE GROWTH OF SEODNDARYPRECIPITATES UPON METALSORPTICN CM CLAY MINERALS AND ALUMINUM and oxide minerals is typically fast initially, then the rates gradually diminish. In the literature on surfaces of clay minerals and aluminum oxides. #12;

  7. Spectroscopic and X-ray diffraction investigation of the behavior of hanksite and tychite at high pressures, and a model for the compressibility of sulfate minerals

    E-Print Network [OSTI]

    Palaich, SEM; Manning, CE; Schauble, E; Kavner, A

    2013-01-01

    Physics and Chemistry of Minerals, 37, 5, 265–282. Chen,and Smith, G.I. (1965) Mineral equilibria in the Searlesstudy of the behavior of mineral barite by X?ray dif-

  8. Accessory mineral U–Th–Pb ages and 40Ar/39Ar eruption chronology, and their bearing on rhyolitic magma evolution in the Pleistocene Coso volcanic field, California

    E-Print Network [OSTI]

    Simon, Justin I.; Vazquez, Jorge A.; Renne, Paul R.; Schmitt, Axel K.; Bacon, Charles R.; Reid, Mary R.

    2009-01-01

    Contrib Mineral Petrol (2009) 158:421–446 DOIORIGINAL PAPER Accessory mineral U–Th–Pb ages and 40 Ar/ 39Flagstaff, AZ, USA Contrib Mineral Petrol (2009) 158:421–446

  9. Theoretical constraints on the effects of pH, salinity, and temperature on clumped isotope signatures of dissolved inorganic carbon species and precipitating carbonate minerals

    E-Print Network [OSTI]

    Hill, PS; Tripati, AK; Schauble, EA

    2014-01-01

    bonds in carbonate minerals: a new kind of paleothermometer.species and carbonate minerals. J. Phys. Chem. A 112, 542–Fe2+(aq) with carbonate minerals. Geochim. Cosmochim. Acta

  10. SECONDARY MINERALS FOUND IN CORES DC2 Al AND DC2 TAKEN FROM THE GRANDE RONDE BASALT FORMATION, PASCO BASIN, WASHINGTON

    E-Print Network [OSTI]

    Teague, L.S.

    2010-01-01

    of secondary and primary mineral phases in basalts of theB. , 1975. Perched silia minerals on mordenite fibers. Jour.lt;. UC—70 I SECONDARY MINERALS FOUND IN CORES DC2 AI AND

  11. Electronic and optical properties of layered RE{sub 2}Ti{sub 2}O{sub 7} (RE = Ce and Pr) from first principles

    SciTech Connect (OSTI)

    Sayede, A.; Khenata, R.; Chahed, A.; Benhelal, O.

    2013-05-07

    We have studied the structural and electronic properties of Ce{sub 2}Ti{sub 2}O{sub 7} (CeTO) and Pr{sub 2}Ti{sub 2}O{sub 7} (PrTO) by first-principles density functional theory calculations. The computed structural parameters are in fairly good agreement with the available experimental findings. Band structure calculations using the GGA+U approach predict an insulating ground state for the herein studied compounds. The insulating band gaps of 2.00 eV and 2.83 eV are found for CeTO and PrTO, respectively. The analysis of the density of states reveals that the strongly localized RE 4f levels act as charge-trapping sites, predicting a lower photocatalytic activity for CeTO. We have also calculated the optical properties for both CeTO and PrTO. Based on these properties, it is predicted that these titanates are insensitive to ultra-violet radiation, while they are more sensitive to frequencies of the radiation in visible and early UV regions.

  12. Superior performance of Ni–W–Ce mixed-metal oxide catalysts for ethanol steam reforming: Synergistic effects of W- and Ni-dopants

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Zongyuan; Xu, Wenqian; Yao, Siyu; Johnson-Peck, Aaron C.; Zhao, Fuzhen; Michorczyk, Piotr; Kubacka, Anna; Stach, Eric A.; Fernández-García, Marcos; Senanayake, Sanjaya D.; et al

    2014-11-26

    In this study, the ethanol steam reforming (ESR) reaction was examined over a series of Ni-W-Ce oxide catalysts. The structures of the catalysts were characterized using in-situ techniques including X-ray diffraction, Pair Distribution Function, X-ray absorption fine structure and transmission electron microscopy; while possible surface intermediates for the ESR reaction were investigated by Diffuse Reflectance Infrared Fourier Transform Spectroscopy. In these materials, all the W and part of the Ni were incorporated into the CeO? lattice, with the remaining Ni forming highly dispersed nano NiO (more »under ESR conditions. The Ni-W-Ce systeme exhibited a much larger lattice strain than those seen for Ni-Ce and W-Ce. Synergistic effects between Ni and W inside ceria produced a substantial amount of defects and O vacancies that led to high catalytic activity, selectivity and stability (i.e. resistance to coke formation) during ethanol steam reforming.« less

  13. PUBLISHED BY THE AMERICAN ARACHNOLOGICAL SOCIETY A new approach to examining scorpion peg sensilla: the mineral oil flood technique

    E-Print Network [OSTI]

    Gaffin, Doug

    : the mineral oil flood technique Elizabeth D. Knowlton and Douglas D. Gaffin: Department of Zoology, University peg sensilla: the mineral oil flood technique Elizabeth D. Knowlton and Douglas D. Gaffin: Department opening. We developed an improved method of chemical stimulant delivery called the mineral oil flood

  14. Oxygen isotope fractionation effects in soil water via interaction with cations (Mg, Ca, K, Na) adsorbed to phyllosilicate clay minerals

    E-Print Network [OSTI]

    Goldsmith, Greg

    ) adsorbed to phyllosilicate clay minerals Erik Oerter a, , Kari Finstad a , Justin Schaefer b , Gregory R the isotope effects caused by high CEC clays in mineral­water systems, we created a series of monominerallic with quartz to determine the isotope effect of non-, or very minimally-, charged mineral surfaces. The d18 O

  15. PII S0016-7037(00)00525-1 Nanoforms: A new type of protein-associated mineralization

    E-Print Network [OSTI]

    Zare, Richard N.

    PII S0016-7037(00)00525-1 Nanoforms: A new type of protein-associated mineralization HOJATOLLAH of hydroxyapatite and proteins and constitute a novel form of protein-associated mineralization. No detectable cell of mineralization in nanoforms is also compared to matrix-mediated calcification in vertebrates. Copyright © 2001

  16. DETERMINING SOURCE OF EJECTA USING HEAVY MINERAL PROVENANCE TECHNIQUES; A MANICOUAGAN DISTAL EJECTA CASE STUDY. S. Thackrey1

    E-Print Network [OSTI]

    Rutten, Rob

    DETERMINING SOURCE OF EJECTA USING HEAVY MINERAL PROVENANCE TECHNIQUES; A MANICOUAGAN DISTAL EJECTA that utilises already well- documented applications of heavy minerals for provenance studies [11]. Defining of rocks on Earth will exhibit a heavy mineral suit to some degree. The target rocks at Manicouagan

  17. Secondary mineral formation in the White River tephra in grassland and forest soils in central Yukon Territory

    E-Print Network [OSTI]

    Sanborn, Paul

    Secondary mineral formation in the White River tephra in grassland and forest soils in central July 2005. Strickland, A. J., Arocena, J. M., Sanborn, P. and Smith, C. A. S. 2005. Secondary mineral-arid climate were investigated to evaluate the formation of secondary minerals within the White River tephra

  18. Mineralization of Carbon and Nitrogen from Freeze-and Oven-Dried Plant Material Added to Soil

    E-Print Network [OSTI]

    Florida, University of

    Mineralization of Carbon and Nitrogen from Freeze- and Oven-Dried Plant Material Added to Soil K. K is a common procedure used in mineralization or decompositionstudies. A lab- oratory study was conducted the mineral content of the plant material compared to freeze drying. The total C and N was not significantly

  19. The degree of bone mineralization is maintained with single intravenous bisphosphonates in aged estrogen-deficient rats and

    E-Print Network [OSTI]

    Ritchie, Robert

    The degree of bone mineralization is maintained with single intravenous bisphosphonates in aged greater than can be explained by an increase in bone mineral density. In this study, 18-month Fischer 344 to measure lumbar vertebral bone microarchitecture, the degree of bone mineralization (DBM

  20. Serum Levels of the Fetuin-Mineral Complex Correlate with Artery Calcification in the Rat*S

    E-Print Network [OSTI]

    Price, Paul A.

    Serum Levels of the Fetuin-Mineral Complex Correlate with Artery Calcification in the Rat- mineral complex in serum and vitamin D-induced artery calcification. The first experiment shows that there is a fetuin-mineral complex in the blood of rats in which extensive calcification of the artery media has been

  1. Start | Author Index 742-3 Rates and Mechanisms of Arsenite Oxidation by Nano-Mn(IV) Oxide Mineral Phases.

    E-Print Network [OSTI]

    Sparks, Donald L.

    Start | Author Index 742-3 Rates and Mechanisms of Arsenite Oxidation by Nano-Mn(IV) Oxide Mineral is thought to generally occur through either biologically or mineral-surface mediated Mn(II) oxidation. These two oxidation pathways result in the formation of nanometer-size Mn(IV) minerals. Compared

  2. The use of micro-FTIR to characterize soil minerals and Boron adsorption S. Pittiglio and H.E. Doner

    E-Print Network [OSTI]

    The use of micro-FTIR to characterize soil minerals and Boron adsorption S. Pittiglio and H in soils. Our goals for this last proposal period were: 1) to build a spectral library of clay minerals, oxides and boron containing minerals commonly found in California soils. This library would be used

  3. Adhesion and the Surface Energy Components of Natural Minerals and Aggregates 

    E-Print Network [OSTI]

    Miller, Clint Matthew

    2011-10-21

    with reverse osmosis water to remove large particles and then with distilled water. The minerals were then placed in an oven (Fisher Isotemp 200 series) at 75-80?C for at least one day. The samples were then allowed to cool for one hour and then were carried... component of the surface energy of the mineral, ?MineralWat is the equilibrium film pressure of water vapor on the solid, ?TotalWat is the total surface tension of water vapor, ??LWWat is the dispersive component of water vapor, ???Wat is the base...

  4. Detection and Quantification of Expansive Clay Minerals in Geologically-Diverse Texas Aggregate Fines 

    E-Print Network [OSTI]

    Russell, George 1983-

    2012-11-28

    minerals identified from XRD pattern of Jones Mill clay ???... 48 4.2 Rankin clay with HIM plateau at 12 ? of ?Mg, RT? treatment ............... 48 4.3 Armor aggregate with palygorskite (10.6 ?) and sepiolite (12.2 ?) ?.. 49 4.4 Fibrous palygorskite... and sepiolite minerals in Armor clay (29000X) ?. 50 4.5 Clay mineral quantities in aggregate fines (- 2 mm starting material) ?. 54 4.6 SEM image of high-crystallinity kaolinite ?books? in Rankin fines ?? 59 4.7 SEM images of Scarmado, Tolar, and Yarrington...

  5. Micro-Analysis of Actinide Minerals for Nuclear Forensics and Treaty Verification

    SciTech Connect (OSTI)

    M. Morey, M. Manard, R. Russo, G. Havrilla

    2012-03-22

    Micro-Raman spectroscopy has been demonstrated to be a viable tool for nondestructive determination of the crystal phase of relevant minerals. Collecting spectra on particles down to 5 microns in size was completed. Some minerals studied were weak scatterers and were better studied with the other techniques. A decent graphical software package should easily be able to compare collected spectra to a spectral library as well as subtract out matrix vibration peaks. Due to the success and unequivocal determination of the most common mineral false positive (zircon), it is clear that Raman has a future for complementary, rapid determination of unknown particulate samples containing actinides.

  6. Utilization of coal associated minerals. Quarterly report No. 11, April 1-June 30, 1980

    SciTech Connect (OSTI)

    Slonaker, J. F.; Akers, D. J.; Alderman, J. K.

    1980-08-29

    The purpose of this research program is to examine the effects of coal mineral materials on coal waste by-product utilization and to investigate new and improved methods for the utilization of waste by-products from cleaning, combustion and conversion processing of coal. The intermediate objectives include: (1) the examination of the effects of cleaning, gasification and combustion on coal mineral materials; and (2) the changes which occur in the coal wastes as a result of both form and distribution of mineral materials in feed coals in conjunction with the coal treatment effects resulting from coal cleaning or either gasification or combustion.

  7. Rapid Microwave Preparation of Highly Efficient Ce[superscript 3+]-Substituted Garnet Phosphors for Solid State White Lighting

    SciTech Connect (OSTI)

    Birkel, Alexander; Denault, Kristin A.; George, Nathan C.; Doll, Courtney E.; Héry, Bathylle; Mikhailovsky, Alexander A.; Birkel, Christina S.; Hong, Byung-Chul; Seshadri, Ram (UCSB); (Mitsubishi)

    2012-04-30

    Ce{sup 3+}-substituted aluminum garnet compounds of yttrium (Y{sub 3}Al{sub 5}O{sub 12}) and lutetium (Lu{sub 3}Al{sub 5}O{sub 12}) - both important compounds in the generation of (In,Ga)N-based solid state white lighting - have been prepared using a simple microwave heating technique involving the use of a microwave susceptor to provide the initial heat source. Carbon used as the susceptor additionally creates a reducing atmosphere around the sample that helps stabilize the desired luminescent compound. High quality, phase-pure materials are prepared within a fraction of the time and using a fraction of the energy required in a conventional ceramic preparation; the microwave technique allows for a reduction of about 95% in preparation time, making it possible to obtain phase pure, Ce{sup 3+}-substituted garnet compounds in under 20 min of reaction time. It is estimated that the overall reduction in energy compared with ceramic routes as practiced in the lab is close to 99%. Conventionally prepared material is compared with material prepared using microwave heating in terms of structure, morphology, and optical properties, including quantum yield and thermal quenching of luminescence. Finally, the microwave-prepared compounds have been incorporated into light-emitting diode 'caps' to test their performance characteristics in a real device, in terms of their photon efficiency and color coordinates.

  8. CE IGCC repowering project: Clean Coal II Project. Annual report, 1 January, 1992--31 December, 1992

    SciTech Connect (OSTI)

    Not Available

    1993-12-01

    CE is participating in a $270 million coal gasification combined cycle repowering project that will provide a nominal 60 MW of electricity to City, Water, light and Power (CWL and P) in Springfield, Illinois. The IGCC system will consist of CE`s air-blown entrained flow two-stage gasifier; an advanced hot gas cleanup system; a combustion turbine adapted to use low-Btu gas: and all necessary coal handling equipment. The project is currently in the second budget period of five. The major activities during this budgeted period are: Establishment of an approved for design (AFD) engineering package; development of a detailed cost estimate; resolution of project business issues; CWL and P renewal and replacement activities; and application for environmental air permits. The Project Management Plan was updated. The conceptual design of the plant was completed and a cost and schedule baseline for the project was established previously in Budget Period One. This information was used to establish AFD Process Flow Diagrams, Piping and Instrument Diagrams, Equipment Data Sheets, material take offs, site modification plans and other information necessary to develop a plus or minus 20% cost estimate. Environmental permitting activities are continuing. At the end of 1992 the major activities remaining for Budget Period two is to finish the cost estimate and complete the Continuation Request Documents.

  9. A Prototype of LaBr3:Ce in situ Gamma-Ray Spectrometer for Marine Environmental Monitoring

    E-Print Network [OSTI]

    Zeng, Zhi; Pan, Xingyu; Xue, Tao; Ma, Hao; Yi, Hongchang; Cheng, Jianping

    2015-01-01

    A prototype of LaBr3:Ce in situ gamma-ray spectrometer for marine environmental monitoring is developed and applied for in situ measurement. A 3-inch LaBr3:Ce scintillator is used in the detector, and a digital pulse process electronics is chosen as the pulse height analyzer. For this prototype, the energy response of the spectrometer is linear and the energy resolution of 662keV is 2.6% (much better than NaI). With the measurement of the prototype in a water tank filled with 137Cs, the detect efficiency for 137Cs is (0.288 0.01)cps/(Bq/L), which is close to the result of Monte Carlo simulation, 0.283cps/(Bq/L). With this measurement, the MDAC for 137Cs in one hour has been calculated to 0.78Bq/L, better than that of NaI(Tl) in-situ gamma spectrometer, which is ~1.0Bq/L.

  10. A Prototype of LaBr3:Ce in situ Gamma-Ray Spectrometer for Marine Environmental Monitoring

    E-Print Network [OSTI]

    Ming Zeng; Zhi Zeng; Jirong Cang; Xingyu Pan; Tao Xue; Hao Ma; Hongchang Yi; Jianping Cheng

    2015-04-20

    A prototype of LaBr3:Ce in situ gamma-ray spectrometer for marine environmental monitoring is developed and applied for in situ measurement. A 3-inch LaBr3:Ce scintillator is used in the detector, and a digital pulse process electronics is chosen as the pulse height analyzer. For this prototype, the energy response of the spectrometer is linear and the energy resolution of 662keV is 2.6% (much better than NaI). With the measurement of the prototype in a water tank filled with 137Cs, the detect efficiency for 137Cs is (0.288 0.01)cps/(Bq/L), which is close to the result of Monte Carlo simulation, 0.283cps/(Bq/L). With this measurement, the MDAC for 137Cs in one hour has been calculated to 0.78Bq/L, better than that of NaI(Tl) in-situ gamma spectrometer, which is ~1.0Bq/L.

  11. Global estimates of mineral dust aerosol iron and aluminum solubility that account for particle size using diffusion-controlled and surface-area-controlled approximations

    E-Print Network [OSTI]

    2012-01-01

    L. A. Warren, pp. 151–210, Clay Miner. Soc. , Chantilly, Va.and J. -L. Colin (2008), Miner- alogy as a critical factor

  12. Chemical Reduction of Nd1.85Ce0.15CuO4??Powders in Supercritical Sodium Ammonia Solutions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dias, Yasmin; Wang, Hui; Zhou, Haiqing; Lin, Feng; Lan, Yucheng

    2015-01-01

    Nd1.85Ce0.15CuO4??powders are chemically reduced in supercritical sodium ammonia solutions from room temperature to 350°C. The crystallographic structure of the reduced powders is investigated from Rietveld refinement of X-ray powder diffraction. The atomic positions are maintained constant within experimental errors while temperature factors of all atoms increase significantly after the chemical treatments, especially of Nd/Ce atoms. The ammonothermally reduced Nd1.85Ce0.15CuO4??powders show diamagnetic below 24?K which is contributed to the lower oxygen content and higher temperature factors of atoms in the treated compound. The ammonothermal method paves a new way to reduce oxides in supercritical solutions near room temperature.

  13. Chemical Reduction of Nd 1.85 Ce 0.15 CuO 4? ? Powders in Supercritical Sodium Ammonia Solutions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dias, Yasmin; Wang, Hui; Zhou, Haiqing; Lin, Feng; Lan, Yucheng

    2015-01-01

    Nd 1.85 Ce 0.15 CuO 4? ? powders are chemically reduced in supercritical sodium ammonia solutions from room temperature to 350°C. The crystallographic structure of the reduced powders is investigated from Rietveld refinement of X-ray powder diffraction. The atomic positions are maintained constant within experimental errors while temperature factors of all atoms increase significantly after the chemical treatments, especially of Nd/Ce atoms. The ammonothermally reduced Nd 1.85 Ce 0.15 CuO 4? ? powders show diamagnetic below 24?K which is contributed to the lower oxygen content and higher temperature factors of atoms in the treated compound.more »The ammonothermal method paves a new way to reduce oxides in supercritical solutions near room temperature. « less

  14. Thiolate ligands as a double-edged sword for CO oxidation on CeO2-supported Au25(SR)18 nanoclusters

    SciTech Connect (OSTI)

    Wu, Zili [ORNL; Jiang, Deen [ORNL; Mann, Amanda K [ORNL; Mullins, David R [ORNL; Qiao, Zhen-an [University of Tennessee, Knoxville (UTK); Allard Jr, Lawrence Frederick [ORNL; Zeng, Chenjie [Carnegie Mellon University (CMU); Jin, Rongchao [Carnegie Mellon University (CMU); Overbury, Steven {Steve} H [ORNL

    2014-01-01

    The effect of thiolate ligands was explored on the catalysis of CeO2-rod supported Au25(SR)18 (SR = -SCH2-CH2-Ph) by using CO oxidation as a probe reaction. Reaction kinetic tests, in situ IR and X-ray absorption spectroscopy, and density functional theory (DFT) were employed to understand how the thiolate ligands affect the nature of active sites, activation of CO and O2, as well as the reaction mechanism and kinetics. The intact Au25(SR)18 on CeO2-rod is found not able to adsorb CO. Only when the thiolate ligands are partially removed, starting from the interface between Au25(SR)18 and CeO2 at temperatures of 423 K and above, can the adsorption of CO be observed by IR. DFT calculations suggest that CO adsorbs favorably on the exposed gold atoms. Accordingly, the CO oxidation light-off temperature shifts to lower temperature. Several types of Au sites are probed by IR of CO adsorption during the ligand removal process. The cationic Au sites (charged between 0 and +1) are found to play the major role for low temperature CO oxidation. Similar activation energy and reaction rate are found for CO oxidation on differently treated Au25(SR)18/CeO2-rod, suggesting a simple site-blocking effect of the thiolate ligands in Au nanoclusters catalysis. Isotopic labelling experiments clearly indicate that CO oxidation on Au25(SR)18/CeO2-rod proceeds predominantly via the redox mechanism where CeO2 activates O2 while CO is activated on the de-thiolated gold sites. These results points to a double-edged sword role played by the thiolate ligands on Au25 nanoclusters for CO oxidation.

  15. Reactivity of pulverized coals during combustion catalyzed by CeO{sub 2} and Fe{sub 2}O{sub 3}

    SciTech Connect (OSTI)

    Gong, Xuzhong; Guo, Zhancheng; Wang, Zhi

    2010-02-15

    Effects of CeO{sub 2} and Fe{sub 2}O{sub 3} on combustion reactivity of several fuels, including three ranks of coals, graphite and anthracite chars, were investigated using thermo-gravimetric analyzer. The results indicated that the combustion reactivity of all the samples except lignite was improved with CeO{sub 2} or Fe{sub 2}O{sub 3} addition. It was interesting to note that the ignition temperatures of anthracite were decreased by 50 C and 53 C, respectively, with CeO{sub 2} and Fe{sub 2}O{sub 3} addition and that its combustion rates were increased to 15.4%/min and 12.2%/min. Ignition temperatures of lignite with CeO{sub 2} and Fe{sub 2}O{sub 3} addition were 250 C and 226 C, and the combustion rates were 12.8% and 19.3%/min, respectively. When compared with those of lignite without catalysts, no obvious catalytic effects of the two catalysts on its combustion reactivity were revealed. The results from the combustion of the three rank pulverized coals catalyzed by CeO{sub 2} and Fe{sub 2}O{sub 3} indicated significant effects of the two catalysts on fixed carbon combustion. And it was found that the higher the fuel rank, the better the catalytic effect. The results of combustion from two kinds of anthracite chars showed obvious effects of anthracite pyrolysis catalyzed by CeO{sub 2} and Fe{sub 2}O{sub 3} on its combustion reactivity. (author)

  16. Magnetic hardening of Ce1+xFe11–yCoyTi with ThMn12 structure by melt spinning

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhou, Chen; Sun, Kewei; Pinkerton, Frederick E.; Kramer, M. J.

    2015-04-15

    A recent study on the intrinsic magnetic properties of CeFe11–yCoyTi has revealed that substituting one Co for Fe retains the favorable magnetocrystalline anisotropy Ha found in the ternary Fe end member, while enhancing the Curie temperature Tc and saturation magnetization 4?Ms. These findings warrant further optimization around Co substitution y = 1 to try to exploit the hard magnetic properties of these Ce-based magnets. Both Ce and Co concentrations in Ce1+xFe11–yCoyTi have been optimized in the range of x = 0 – 0.2 and y = 0 –1.5. It was found that Co substitution effectively enhances all hard magnetic properties,more »although the values are still lower than those predicted from the intrinsic magnetic properties. Specifically, Tc increases from 210 °C to 285 – 350 °C; 4?M19 (magnetization at 19 kOe) from 8.9 kG to 10.5 – 11.5 kG, remanence Br from 3.1 kG to 4.1 – 4.5 kG, and most importantly, Hci from 1.1 kOe to 1.5 kOe. As a result, the room temperature energy product (BH)max has been increased by over 100% from 0.7 MGOe in Ce1.1Fe11Ti to 1.5 MGOe in Ce1.05Fe9.75Co1.25Ti. Microscopy analysis indicates that the addition of Co refines the grain size and promotes chemical homogeneity at the microscopic scale. As a result, the beneficial effect of Co on the microstructure contributes to the improved hard magnetic properties.« less

  17. Miners and mining in the Late Bronze Age: a multidisciplinary study from

    E-Print Network [OSTI]

    Nicolussi, Kurt

    the principal motors of Bronze Age society. The skills and risks of mining lie behind the weapons, tools and seeds, providing a sketch of dedicated prehistoric labourers in their habitat. The Mauken miners were

  18. Sorption of polycyclic aromatic hydrocarbons to minerals and low-organic-carbon aquifer sediments 

    E-Print Network [OSTI]

    Grimaldi, Gabriel Orlando

    1999-01-01

    The molecular mechanisms and major geochemical factors ics. controlling the sorption of nontoxic organic chemicals (NOC) to mineral surfaces in low-organic-carbon soils and sediments remain unclear. The objectives of this research were to study...

  19. Soil Nitrogen Mineralization Potential for Improved Fertilizer Recommendations and Decreased Nitrate Contamination of Groundwater 

    E-Print Network [OSTI]

    Franzluebbers, Alan; Haney, Richard; Hons, Frank

    1995-01-01

    In order to prevent overfertilization, which could lead to groundwater contamination, rapid and accurate soil testing procedures are needed to evaluate agricultural surface soils for their potential to mineralize C and N. Our objectives were...

  20. The effect of mineral surface chemistry on the biodegradation of petroleum 

    E-Print Network [OSTI]

    Allan, Katherine Ann

    1997-01-01

    the biodegradation of a crude oil in soils with different characteristics including mineral surface chemistry, organic matter content, and surface area in order to determine the impact of soil chemistry on bioavailability and biodegradability of petroleum. Two soils...

  1. Leaching of antimony from polyethylene terephthalate (PET) bottles into mineral water

    E-Print Network [OSTI]

    Short, Daniel

    Leaching of antimony from polyethylene terephthalate (PET) bottles into mineral water Szilvia April 2009 Available online 21 May 2009 Keywords: Antimony Water Leaching Polyethylene terephthalate SODIS The Sb leaching from polyethylene terephthalate (PET) package material into 10 different brands

  2. Characterization of cement minerals, cements and their reaction products at the atomic and nano scale 

    E-Print Network [OSTI]

    Skibsted, Joergen; Hall, Christopher

    Recent advances and highlights in characterization methods are reviewed for cement minerals, cements and their reaction products. The emphasis is on X-ray and neutron diffraction, and on nuclear magnetic resonance methods, ...

  3. Cal. PRC Section 6909 - Oil and Gas and Mineral Leases: Geothermal...

    Open Energy Info (EERE)

    Cal. PRC Section 6909 - Oil and Gas and Mineral Leases: Geothermal Resources Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: Cal....

  4. 1. Department, Course Number, Title ORE 678, Marine Mineral Resources Engineering

    E-Print Network [OSTI]

    Frandsen, Jannette B.

    and environmental sciences and economics. Pre: Consent 4. Prerequisites Applied mechanics Engineering economics 5 Education Program outcome 2 : Basic science, mathematics, & engineering Program Outcome 4: Ocean engineering1. Department, Course Number, Title ORE 678, Marine Mineral Resources Engineering 2. Designation

  5. Beyond the resource curse : mineral resources and development in Guinea-Conakry

    E-Print Network [OSTI]

    Diallo, Thierno Amadou

    2015-01-01

    Natural resource endowments are no guarantee of socioeconomic development. Many developing countries are rich in natural resources (minerals, oil, gas, hydropower), and yet many of their citizens remain in poverty and their ...

  6. Diffraction Studies from Minerals to Organics - Lessons Learned from Materials Analyses

    SciTech Connect (OSTI)

    Whitfield, Pamela S [ORNL

    2014-01-01

    In many regards the study of materials and minerals by powder diffraction techniques are complimentary, with techniques honed in one field equally applicable to the other. As a long-time materials researcher many of the examples are of techniques developed for materials analysis applied to minerals. However in a couple of cases the study of new minerals was the initiation into techniques later used in materials-based studies. Hopefully they will show that the study of new minerals structures can provide opportunities to add new methodologies and approaches to future problems. In keeping with the AXAA many of the examples have an Australian connection, the materials ranging from organics to battery materials.

  7. Quantifying the role of the electronics industry in managing conflict minerals using printers

    E-Print Network [OSTI]

    Lee, Jason S., S.B. Massachusetts Institute of Technology

    2014-01-01

    The electronics manufacturing industry has been experiencing a fast-changing landscape with recent legislations targeting the supply chains for the 3TG minerals: tin, tantalum, tungsten, and gold mined from the Democratic ...

  8. Identifying soils with potential of expanding sulfate mineral formation using electromagnetic induction 

    E-Print Network [OSTI]

    Fox, Miranda Lynn

    2004-11-15

    Sulfate-bearing soils are a problem in highway construction as they combine with materials used for lime stabilization to form minerals, particularly ettringite, that expand and induce heave in the stabilized soil. This ...

  9. Application Of Fluid Inclusion And Rock-Gas Analysis In Mineral...

    Open Energy Info (EERE)

    mineral surfaces by heating. The most abundant of these gases, besides H2O, are usually CO2, CH4, CO and N2. We have used a gas chromatograph to analyze these gases in fluid...

  10. Evidence for the generation of juvenile granitic crust during continental extension, Mineral Mountains Batholith, Utah

    E-Print Network [OSTI]

    Coleman, Drew S.; Walker, J. Douglas

    1992-07-10

    Field, chemical and isotopic data from the Miocene Mineral Mountains batholith in southwest Utah are consistent with the batholith being derived through differentiation of material recently separated from the lithospheric ...

  11. Lu.sub.1-xI.sub.3:Ce.sub.x-a scintillator for gamma-ray spectroscopy and time-of-flight pet

    DOE Patents [OSTI]

    Shah, Kanai S. (Newton, MA)

    2008-02-12

    The present invention includes very fast scintillator materials including lutetium iodide doped with Cerium (Lu.sub.1-xI.sub.3:Ce.sub.x; LuI.sub.3:Ce). The LuI.sub.3 scintillator material has surprisingly good characteristics including high light output, high gamma-ray stopping efficiency, fast response, low cost, good proportionality, and minimal afterglow that the material is useful for gamma-ray spectroscopy, medical imaging, nuclear and high energy physics research, diffraction, non-destructive testing, nuclear treaty verification and safeguards, and geological exploration.

  12. Effect of Trace Mineral Supplementation on Gastric Ulcers in Exercising Yearling Horses 

    E-Print Network [OSTI]

    Hayes, Alexa Dawn

    2010-10-12

    MINERAL SUPPLEMENTATION ON GASTRIC ULCERS IN EXERCISING YEARLING HORSES A Thesis by ALEXA DAWN HAYES Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER... OF SCIENCE August 2009 Major Subject: Animal Science EFFECT OF TRACE MINERAL SUPPLEMENTATION ON GASTRIC ULCERS IN EXERCISING YEARLING HORSES A Thesis by ALEXA DAWN HAYES Submitted to the Office of Graduate Studies of Texas A...

  13. The substitution of sodium for calcium in the mineral nutrition of cotton 

    E-Print Network [OSTI]

    Whitenberg, David Calvin

    1959-01-01

    LIBRARY A & M O' LLEOE OF TEXA5 THE SUBSTITUTION OF SODIUM FOR CALCIUM IN THE MINERAL NUTRITION OF COTTON A Thesis By DAVID CALVIN WHITENBERG Submit. ted to the Graduate School of the Agricultural and Mechanical College of Texas in partial... fulfillment of the requirements for the degree of MASTER OF SCIENCE January 19 59 Major Subject: Plant Physiology THE SUBSTITUTION OF SODIUM FOR CALCIUM IN THE MINERAL NUTRITION OF COTTON A Thesis By DAVID CALVIN WHITENBERG Approved as to style...

  14. FLUIDIZED BED STEAM REFORMED MINERAL WASTE FORMS: CHARACTERIZATION AND DURABILITY TESTING

    SciTech Connect (OSTI)

    Jantzen, C; Troy Lorier, T; John Pareizs, J; James Marra, J

    2006-12-06

    Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of high sodium low activity wastes (LAW) such as those existing at the Hanford site, at the Idaho National Laboratory (INL), and the Savannah River Site (SRS). The addition of clay, charcoal, and a catalyst as co-reactants with the waste denitrates the aqueous wastes and forms a granular mineral waste form that can subsequently be made into a monolith for disposal if necessary. The waste form produced is a multiphase mineral assemblage of Na-Al-Si (NAS) feldspathoid minerals with cage and ring structures and iron bearing spinel minerals. The mineralization occurs at moderate temperatures between 650-750 C in the presence of superheated steam. The cage and ring structured feldspathoid minerals atomically bond radionuclides like Tc-99 and Cs-137 and anions such as SO{sub 4}, I, F, and Cl. The spinel minerals stabilize Resource Conservation and Recovery Act (RCRA) hazardous species such as Cr and Ni. Granular mineral waste forms were made from (1) a basic Hanford Envelope A low activity waste (LAW) simulant and (2) an acidic INL simulant commonly referred to as sodium bearing waste (SBW) in pilot scale facilities at the Science Applications International Corporation (SAIC) Science and Technology Applications Research (STAR) facility in Idaho Falls, ID. The FBSR waste forms were characterized and the durability tested via ASTM C1285 (Product Consistency Test), the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP), and the Single Pass Flow Through (SPFT) test. The results of the SPFT testing and the activation energies for dissolution are discussed in this study.

  15. FLUIDIZED BED STEAM REFORMED MINERAL WASTE FORMS: CHARACTERIZATION AND DURABILITY TESTING

    SciTech Connect (OSTI)

    Jantzen, C; Troy Lorier, T; John Pareizs, J; James Marra, J

    2007-03-31

    Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of high sodium low activity wastes (LAW) such as those existing at the Hanford site, at the Idaho National Laboratory (INL), and the Savannah River Site (SRS). The addition of clay, charcoal, and a catalyst as co-reactants with the waste denitrates the aqueous wastes and forms a granular mineral waste form that can subsequently be made into a monolith for disposal if necessary. The waste form produced is a multiphase mineral assemblage of Na-Al-Si (NAS) feldspathoid minerals with cage and ring structures and iron bearing spinel minerals. The mineralization occurs at moderate temperatures between 650-750 C in the presence of superheated steam. The cage and ring structured feldspathoid minerals atomically bond radionuclides like Tc-99 and Cs-137 and anions such as SO4, I, F, and Cl. The spinel minerals stabilize Resource Conservation and Recovery Act (RCRA) hazardous species such as Cr and Ni. Granular mineral waste forms were made from (1) a basic Hanford Envelope A low-activity waste (LAW) simulant and (2) an acidic INL simulant commonly referred to as sodium bearing waste (SBW) in pilot scale facilities at the Science Applications International Corporation (SAIC) Science and Technology Applications Research (STAR) facility in Idaho Falls, ID. The FBSR waste forms were characterized and the durability tested via ASTM C1285 (Product Consistency Test), the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP), and the Single Pass Flow Through (SPFT) test. The results of the SPFT testing and the activation energies for dissolution are discussed in this study.

  16. Mineral Sequestration of Carbon Dixoide in a Sandstone-Shale System

    SciTech Connect (OSTI)

    Xu, Tianfu; Apps, John A.; Pruess, Karsten

    2004-07-09

    A conceptual model of CO2 injection in bedded sandstone-shale sequences has been developed using hydrogeologic properties and mineral compositions commonly encountered in Gulf Coast sediments. Numerical simulations were performed with the reactive fluid flow and geochemical transport code TOUGHREACT to analyze mass transfer between sandstone and shale layers and CO2 immobilization through carbonate precipitation. Results indicate that most CO2 sequestration occurs in the sandstone. The major CO2 trapping minerals are dawsonite and ankerite. The CO2 mineral-trapping capacity after 100,000 years reaches about 90 kg per cubic meter of the medium. The CO2 trapping capacity depends on primary mineral composition. Precipitation of siderite and ankerite requires Fe+2 supplied mainly by chlorite and some by hematite dissolution and reduction. Precipitation of dawsonite requires Na+ provided by oligoclase dissolution. The initial abundance of chlorite and oligoclase therefore affects the CO2 mineral trapping capacity. The sequestration time required depends on the kinetic rate of mineral dissolution and precipitation. Dawsonite reaction kinetics is not well understood, and sensitivity regarding the precipitation rate was examined. The addition of CO2 as secondary carbonates results in decreased porosity. The leaching of chemical constituents from the interior of the shale causes slightly increased porosity. The limited information currently available for the mineralogy of natural high-pressure CO2 gas reservoirs is also generally consistent with our simulation. The ''numerical experiments'' give a detailed understanding of the dynamic evolution of a sandstone-shale geochemical system.

  17. Carbonation of Rock Minerals by Supercritical Carbon Dioxide at 250 degrees C.

    SciTech Connect (OSTI)

    Sugama, T.; Ecker, L.; Butcher, T.

    2010-06-01

    Wet powder-samples of five rock minerals, granite, albite, hornblende, diorite, and biotite mica, were exposed in supercritical carbon dioxide (scCO2) for 3 days at 250 C under 17.23 MPa pressure, and then the susceptibility of the various crystalline phases present in these mineral structures to reactions with hot scCO2 was investigated by XRD and FT-IR. The anorthite present in diorite was identified as the most vulnerable phase to carbonation. In contrast, biotite displayed a great resistance, although its phase was transformed hydrothermally to sanidine and quartz. Granite comprised of two phases, anorthoclase-type albite and quartz. The carbonation of former phase led to the formation of amorphous sodium and potassium carbonates coexisting with the clay-like by-products of the carbonation reaction. The reactivity of quartz to scCO2 was minimal, if any. Among these rock minerals, only hornblende formed crystalline carbonation products, such as calcite and magnesite after exposure, reflecting the likelihood of an increase in its volume. Based upon the feldspar ternary diagram, the carbonation rate of various different minerals in the plagioclase feldspar family depended primarily on the amount of anorthite. On the other hand, alkali feldspar minerals involving anorthoclase-type albite and sanidine had a lower reactivity with scCO2, compared with that of plagioclase feldspar minerals.

  18. Electronic and thermoelectric properties of Ce{sub 3}Te{sub 4} and La{sub 3}Te{sub 4} computed with density functional theory with on-site Coulomb interaction correction

    SciTech Connect (OSTI)

    Vo, Trinh; Allmen, Paul von; Huang, Chen-Kuo; Ma, James; Bux, Sabah; Fleurial, Jean-Pierre [Jet Propulsion Laboratory, California Institute of Technology, Pasadena, California 91109 (United States)

    2014-10-07

    The electronic properties and Seebeck coefficients of Ce{sub 3}Te{sub 4} and La{sub 3}Te{sub 4} are computed using Density Functional Theory with on-site Coulomb interaction correction. We found that the Seebeck coefficients of Ce{sub 3}Te{sub 4} and La{sub 3}Te{sub 4} are almost equal at temperatures larger than the Curie temperature of Ce{sub 3}Te{sub 4}, and in good agreement with the measurements reported by May et al. [Phys. Rev. B 86, 035135 (2012)]. At temperatures below the Curie temperature, the Seebeck coefficient of Ce{sub 3}Te{sub 4} increases due to the ferromagnetic ordering, which leads the f-electron of Ce to contribute to the Seebeck coefficient in the relevant range of electron concentration.

  19. Magnetic properties of CeFe11-xCoxTi with ThMn12 structure

    SciTech Connect (OSTI)

    Zhou, C; Pinkerton, FE; Herbst, JF

    2014-05-07

    A series of novel alloys CeFe11-xCoxTi (0 <= x <= 11) with ThMn12 structure has been successfully prepared by melt-spinning. The Curie temperature T-c increases with Co content x, reaching a maximum of 689 degrees C at x = 9 and declining to 664 degrees C at complete Co filling (x = 11). The room temperature saturation magnetization 4 pi M-s and magnetocrystalline anisotropy H-a have been estimated by fitting the first quadrant demagnetization curve with the Stoner-Wohlfarth model. 4 pi M-s first increases with increasing Co up to x = 3, then decrease. H-a has a complex dependence on Co content, which is indicative of a change in the easy magnetization direction from axis to plane and back as the Co content increases. (C) 2014 AIP Publishing LLC.

  20. Low pressure CO? hydrogenation to methanol over gold nanoparticles activated on a CeOx/TiO? interface

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yang, Xiaofang; Boscoboinik, J. Anibal; Kattel, Shyam; Senanayake, Sanjaya D.; Nie, Xiaowa; Graciani, Jesus; Rodriguez, Jose A.; Liu, Ping; Stacchiola, Dario J.; Chen, Jingguang G.

    2015-07-28

    Capture and recycling of CO? into valuable chemicals such as alcohols could help mitigate its emissions into the atmosphere. Due to its inert nature, the activation of CO? is a critical step in improving the overall reaction kinetics during its chemical conversion. Although pure gold is an inert noble metal and cannot catalyze hydrogenation reactions, it can be activated when deposited as nanoparticles on the appropriate oxide support. In this combined experimental and theoretical study, it is shown that an electronic polarization at the metal–oxide interface of Au nanoparticles anchored and stabilized on a CeOx/TiO? substrate generates active centers formore »CO? adsorption and its low pressure hydrogenation, leading to a higher selectivity toward methanol. In conclusion, this study illustrates the importance of localized electronic properties and structure in catalysis for achieving higher alcohol selectivity from CO? hydrogenation.« less