National Library of Energy BETA

Sample records for millstone smit hs

  1. Connecticut Nuclear Profile - Millstone

    U.S. Energy Information Administration (EIA) Indexed Site

    Millstone" "Unit","Summer capacity (mw)","Net generation (thousand mwh)","Summer capacity factor (percent)","Type","Commercial operation date","License expiration date" 2,869,"7,415",97.4,"PWR","application/vnd.ms-excel","application/vnd.ms-excel" 3,"1,233","9,336",86.4,"PWR","application/vnd.ms-excel","application/vnd.ms-excel"

  2. PIA - HS Web Services (HSWS) | Department of Energy

    Energy Savers [EERE]

    PIA - HS Web Services (HSWS) PIA - HS Web Services (HSWS) PIA - HS Web Services (HSWS) PDF icon PIA - HS Web Services (HSWS) More Documents & Publications PIA - INL PeopleSoft -...

  3. PIA - HS Web Services (HSWS) | Department of Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Web Services (HSWS) PIA - HS Web Services (HSWS) PIA - HS Web Services (HSWS) PIA - HS Web Services (HSWS) (376.72 KB) More Documents & Publications PIA - INL PeopleSoft - Human ...

  4. 1,"Millstone","Nuclear","Dominion Nuclear Conn Inc",2122.5

    U.S. Energy Information Administration (EIA) Indexed Site

    Connecticut" ,"Plant","Primary energy source","Operating company","Net summer capacity (MW)" 1,"Millstone","Nuclear","Dominion Nuclear Conn Inc",2122.5 2,"Middletown","Petroleum","Middletown Power LLC",770.2 3,"Lake Road Generating Plant","Natural gas","Lake Road Generating Co LP",757.3 4,"Kleen Energy Systems Project","Natural

  5. PIA - HS Correspondence Tracking System (HSCT) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Correspondence Tracking System (HSCT) PIA - HS Correspondence Tracking System (HSCT) PIA - HS Correspondence Tracking System (HSCT) PIA - HS Correspondence Tracking System (HSCT) (265.33 KB) More Documents & Publications PIA - INL SECURITY INFORMATION MANAGEMENT SYSTEM BUSINESS ENCLAVE PIA - INL PeopleSoft - Human Resource System PIA - Human Resources - Personal Information Change Request - Idaho National Engineering Laboratory

  6. Justin H.S. Breaux | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Justin H.S. Breaux Justin Breaux is a science writer and digital communications specialist in Argonne's Communications, Education and Public Affairs Division. Contact him at (630) 252-5823 or media@anl.gov

  7. Connecticut Nuclear Profile - Millstone

    U.S. Energy Information Administration (EIA) Indexed Site

    ...vnd.ms-excel" 3,"1,233","9,336",86.4,"PWR","applicationvnd.ms-excel","applicationvnd.ms-excel" ,"2,103","16,750",90.9 "Data for 2010" "PWR Pressurized Light Water Reactor."

  8. File:Wind-turbine-economics-lp-HS.pdf | Open Energy Information

    Open Energy Info (EERE)

    Wind-turbine-economics-lp-HS.pdf Jump to: navigation, search File File history File usage Metadata File:Wind-turbine-economics-lp-HS.pdf Size of this preview: 463 599 pixels....

  9. File:Getting-to-know-your-turbine-HS.pdf | Open Energy Information

    Open Energy Info (EERE)

    turbine-HS.pdf Jump to: navigation, search File File history File usage Metadata File:Getting-to-know-your-turbine-HS.pdf Size of this preview: 463 599 pixels. Other resolution:...

  10. 10 CFR 850, Request for Information- Docket Number: HS-RM-10-CBDPP- Ed Kvartek

    Office of Energy Efficiency and Renewable Energy (EERE)

    Commenter: Ed Kvartek 10 CFR 850 - Request for Information Docket Number: HS-RM-10-CBDPP Comment Close Date: 2/22/2011

  11. 10 CFR 850, Request for Information- Docket Number: HS-RM-10-CBDPP- Reginald Gaylord

    Broader source: Energy.gov [DOE]

    Commenter: Reginald Gaylord 10 CFR 850 - Request for Information Docket Number: HS-RM-10-CBDPP Comment Close Date: 2/22/2011

  12. 10 CFR 850, Request for Information- Docket Number: HS-RM-10-CBDPP- Cameron Anderson

    Broader source: Energy.gov [DOE]

    Commenter: Cameron Anderson 10 CFR 850 - Request for Information Docket Number: HS-RM-10-CBDPP Comment Close Date: 2/22/2011

  13. 10 CFR 850, Request for Information- Docket Number: HS-RM-10-CBDPP- Cheryl Floreen

    Broader source: Energy.gov [DOE]

    Commenter: Cheryl Floreen 10 CFR 850 - Request for Information Docket Number: HS-RM-10-CBDPP Comment Close Date: 2/22/2011

  14. 10 CFR 850, Request for Information- Docket Number: HS-RM-10-CBDPP- Steven Jahn

    Broader source: Energy.gov [DOE]

    Commenter: Steven Jahn 10 CFR 850 - Request for Information Docket Number: HS-RM-10-CBDPP Comment Close Date: 2/22/2011

  15. 10 CFR 850, Request for Information- Docket Number: HS-RM-10-CBDPP- Mark Fisher

    Broader source: Energy.gov [DOE]

    Commenter: Mark Fisher 10 CFR 850 - Request for Information Docket Number: HS-RM-10-CBDPP Comment Close Date: 2/22/2011

  16. 10 CFR 850, Request for Information- Docket Number: HS-RM-10-CBDPP- Bret Moscon

    Broader source: Energy.gov [DOE]

    Commenter: Bret Moscon 10 CFR 850 - Request for Information Docket Number: HS-RM-10-CBDPP Comment Close Date: 2/22/2011

  17. 10 CFR 850, Request for Information- Docket Number: HS-RM-10-CBDPP- Marc Kolanz

    Broader source: Energy.gov [DOE]

    Commenter: Marc Kolanz 10 CFR 850 - Request for Information Docket Number: HS-RM-10-CBDPP Comment Close Date: 2/22/2011

  18. 10 CFR 850, Request for Information- Docket Number: HS-RM-10-CBDPP- Jim Withers

    Broader source: Energy.gov [DOE]

    Commenter: Jim Withers 10 CFR 850 - Request for Information Docket Number: HS-RM-10-CBDPP Comment Close Date: 2/22/2011

  19. 10 CFR 850, Request for Information- Docket Number: HS-RM-10-CBDPP- William R. Kleem

    Broader source: Energy.gov [DOE]

    Commenter: William R. Kleem 10 CFR 850 - Request for Information Docket Number: HS-RM-10-CBDPP Comment Close Date: 2/22/2011

  20. 10 CFR 850, Request for Information- Docket Number: HS-RM-10-CBDPP- J. Chris Cantwell

    Broader source: Energy.gov [DOE]

    Commenter: J. Chris Cantwell 10 CFR 850 - Request for Information Docket Number: HS-RM-10-CBDPP Comment Close Date: 2/22/2011

  1. 10 CFR 850, Request for Information- Docket Number: HS-RM-10-CBDPP- Mario Moreno

    Broader source: Energy.gov [DOE]

    Commenter: Mario Moreno 10 CFR 850 - Request for Information Docket Number: HS-RM-10-CBDPP Comment Close Date: 2/22/2011

  2. 10 CFR 850, Request for Information- Docket Number: HS-RM-10-CBDPP- Susan Leckband

    Broader source: Energy.gov [DOE]

    Commenter: Susan Leckband 10 CFR 850 - Request for Information Docket Number: HS-RM-10-CBDPP Comment Close Date: 2/22/2011

  3. 10 CFR 850, Request for Information- Docket Number: HS-RM-10-CBDPP- Pete Stafford

    Broader source: Energy.gov [DOE]

    Commenter: Pete Stafford 10 CFR 850 - Request for Information Docket Number: HS-RM-10-CBDPP Comment Close Date: 2/22/2011

  4. 10 CFR 850, Request for Information- Docket Number: HS-RM-10-CBDPP- Faye Vleger

    Broader source: Energy.gov [DOE]

    Commenter: Faye Vleger 10 CFR 850 - Request for Information Docket Number: HS-RM-10-CBDPP Comment Close Date: 2/22/2011

  5. 10 CFR 850, Request for Information- Docket Number: HS-RM-10-CBDPP- Scott Stafford

    Broader source: Energy.gov [DOE]

    Commenter: Scott Stafford 10 CFR 850 - Request for Information Docket Number: HS-RM-10-CBDPP Comment Close Date: 2/22/2011

  6. 10 CFR 850, Request for Information- Docket Number: HS-RM-10-CBDPP- Anoop Agrawal

    Broader source: Energy.gov [DOE]

    Commenter: Anoop Agrawal 10 CFR 850 - Request for Information Docket Number: HS-RM-10-CBDPP Comment Close Date: 2/22/2011

  7. 10 CFR 850, Request for Information- Docket Number: HS-RM-10-CBDPP- Thomas W. Morris

    Broader source: Energy.gov [DOE]

    Commenter: Thomas W. Morris 10 CFR 850 - Request for Information Docket Number: HS-RM-10-CBDPP Comment Close Date: 2/22/2011

  8. 10 CFR 850, Request for Information- Docket Number: HS-RM-10-CBDPP- Jamie Stalker

    Broader source: Energy.gov [DOE]

    Commenter: Jamie Stalker 10 CFR 850 - Request for Information Docket Number: HS-RM-10-CBDPP Comment Close Date: 2/22/2011

  9. 10 CFR 850, Request for Information- Docket Number: HS-RM-10-CBDPP- Curtis Valle

    Broader source: Energy.gov [DOE]

    Commenter: Curtis Valle 10 CFR 850 - Request for Information Docket Number: HS-RM-10-CBDPP Comment Close Date: 2/22/2011

  10. 10 CFR 850, Request for Information- Docket Number: HS-RM-10-CBDPP- Roby Enge

    Broader source: Energy.gov [DOE]

    Commenter: Roby Enge 10 CFR 850 - Request for Information Docket Number: HS-RM-10-CBDPP Comment Close Date: 2/22/2011

  11. 10 CFR 850, Request for Information- Docket Number: HS-RM-10-CBDPP- Richard L. Dickson

    Broader source: Energy.gov [DOE]

    Commenter: Richard L. Dickson 10 CFR 850 - Request for Information Docket Number: HS-RM-10-CBDPP Comment Close Date: 2/22/2011

  12. 10 CFR 850, Request for Information- Docket Number: HS-RM-10-CBDPP- Timothy Bolden

    Broader source: Energy.gov [DOE]

    Commenter: Timothy Bolden 10 CFR 850 - Request for Information Docket Number: HS-RM-10-CBDPP Comment Close Date: 2/22/2011

  13. 10 CFR 850, Request for Information- Docket Number: HS-RM-10-CBDPP- Scott Yundt

    Broader source: Energy.gov [DOE]

    Commenter: Scott Yundt 10 CFR 850 - Request for Information Docket Number: HS-RM-10-CBDPP Comment Close Date: 2/22/2011

  14. 10 CFR 850, Request for Information- Docket Number: HS-RM-10-CBDPP- Thomas Peterson

    Broader source: Energy.gov [DOE]

    Commenter: Thomas Peterson 10 CFR 850 - Request for Information Docket Number: HS-RM-10-CBDPP Comment Close Date: 2/22/2011

  15. 10 CFR 850, Request for Information- Docket Number: HS-RM-10-CBDPP- Terry Vaughn

    Broader source: Energy.gov [DOE]

    Commenter: Terry Vaughn 10 CFR 850 - Request for Information Docket Number: HS-RM-10-CBDPP Comment Close Date: 2/22/2011

  16. 10 CFR 850, Request for Information- Docket Number: HS-RM-10-CBDPP- Paul A. Schulte

    Broader source: Energy.gov [DOE]

    Commenter: Paul A. Schulte 10 CFR 850 - Request for Information Docket Number: HS-RM-10-CBDPP Comment Close Date: 2/22/2011

  17. 10 CFR 850, Request for Information- Docket Number: HS-RM-10-CBDPP- Joseph Herndon

    Broader source: Energy.gov [DOE]

    Commenter: Joseph Herndon 10 CFR 850 - Request for Information Docket Number: HS-RM-10-CBDPP Comment Close Date: 2/22/2011

  18. 10 CFR 850, Request for Information- Docket Number: HS-RM-10-CBDPP- Michael Brisson

    Office of Energy Efficiency and Renewable Energy (EERE)

    Commenter: Michael Brisson 10 CFR 850 - Request for Information Docket Number: HS-RM-10-CBDPP Comment Close Date: 2/22/2011

  19. 10 CFR 850, Request for Information- Docket Number: HS-RM-10-CBDPP- Kenneth Meyer

    Broader source: Energy.gov [DOE]

    Commenter: Kenneth Meyer 10 CFR 850 - Request for Information Docket Number: HS-RM-10-CBDPP Comment Close Date: 2/22/2011

  20. 10 CFR 850, Request for Information- Docket Number: HS-RM-10-CBDPP- John Walter

    Broader source: Energy.gov [DOE]

    Commenter: John Walter 10 CFR 850 - Request for Information Docket Number: HS-RM-10-CBDPP Comment Close Date: 2/22/2011

  1. 10 CFR 850, Request for Information- Docket Number: HS-RM-10-CBDPP- Mark Strauch

    Broader source: Energy.gov [DOE]

    Commenter: Mark Strauch 10 CFR 850 - Request for Information Docket Number: HS-RM-10-CBDPP Comment Close Date: 2/22/2011

  2. 10 CFR 850, Request for Information- Docket Number: HS-RM-10-CBDPP- Troy Bodily

    Broader source: Energy.gov [DOE]

    Commenter: Troy Bodily 10 CFR 850 - Request for Information Docket Number: HS-RM-10-CBDPP Comment Close Date: 2/22/2011

  3. Summit Appliance: ENERGY STAR Referral (CF11ES, Midea HS-390C) | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Summit Appliance: ENERGY STAR Referral (CF11ES, Midea HS-390C) Summit Appliance: ENERGY STAR Referral (CF11ES, Midea HS-390C) October 28, 2011 DOE referred the matter of Summit freezer model CF11ES, which is manufactured by Midea and distributed under the Midea brand as model HS-390C, to the U.S. Environmental Protection Agency, brand manager for the ENERGY STAR Program, for appropriate action after DOE testing showed that the model does not meet the ENERGY STAR specification.

  4. Adsorbing H?S onto a single graphene sheet: A possible gas sensor

    SciTech Connect (OSTI)

    Reshak, A. H.; Auluck, S.

    2014-09-14

    The electronic structure of pristine graphene sheet and the resulting structure of adsorbing a single molecule of H?S on pristine graphene in three different sites (bridge, top, and hollow) are studied using the full potential linearized augmented plane wave method. Our calculations show that the adsorption of H?S molecule on the bridge site opens up a small direct energy gap of about 0.1 eV at symmetry point M, while adsorption of H?S on top site opens a gap of 0.3 eV around the symmetry point K. We find that adsorbed H?S onto the hollow site of pristine graphene sheet causes to push the conduction band minimum and the valence band maximum towards Fermi level resulting in a metallic behavior. Comparing the angular momentum decomposition of the atoms projected electronic density of states of pristine graphene sheet with that of H?Sgraphene for three different cases, we find a significant influence of the location of the H?S molecule on the electronic properties especially the strong hybridization between H?S molecule and graphene sheet.

  5. DEVELOPMENT OF THE HS99 AIR TRANSPORT TYPE A FISSILE PACKAGE

    SciTech Connect (OSTI)

    Blanton, P.; Eberl, K.

    2012-07-10

    An air-transport Type A Fissile radioactive shipping package for the transport of special form uranium sources has been developed by the Savannah River National Laboratory (SRNL) for the Department of Homeland Security. The Package model number is HS99 for Homeland Security Model 99. This paper presents the major design features of the HS99 and highlights engineered materials necessary for meeting the design requirements for this light-weight Type AF packaging. A discussion is provided demonstrating how the HS99 complies with the regulatory safety requirements of the Nuclear Regulatory Commission. The paper summarizes the results of structural testing to specified in 10 CFR 71 for Normal Conditions of Transport and Hypothetical Accident Conditions events. Planned and proposed future missions for this packaging are also addressed.

  6. PHOTOMETRIC ANALYSIS OF HS Aqr, EG Cep, VW LMi, AND DU Boo

    SciTech Connect (OSTI)

    Djurasevic, G.; Latkovic, O.; Bastuerk, Oe.; Y Latin-Small-Letter-Dotless-I lmaz, M.; Cal Latin-Small-Letter-Dotless-I skan, S.; Senavc Latin-Small-Letter-Dotless-I , H. V.; K Latin-Small-Letter-Dotless-I l Latin-Small-Letter-Dotless-I coglu, T.; Ekmekci, F.; Tanr Latin-Small-Letter-Dotless-I verdi, T.

    2013-03-15

    We analyze new multicolor light curves for four close late-type binaries: HS Aqr, EG Cep, VW LMi, and DU Boo, in order to determine the orbital and physical parameters of the systems and estimate the distances. The analysis is done using the modeling code of G. Djurasevic, and is based on up-to-date measurements of spectroscopic elements. All four systems have complex, asymmetric light curves that we model by including bright or dark spots on one or both components. Our findings indicate that HS Aqr and EG Cep are in semi-detached, while VW LMi and DU Boo are in overcontact configurations.

  7. 10 CFR 850, Request for Information- Docket Number: HS-RM-10-CBDPP- Alliance for Water Efficiency (AWE)

    Broader source: Energy.gov [DOE]

    Commenter: Alliance for Water Efficiency (AWE) 10 CFR 850 - Request for Information Docket Number: HS-RM-10-CBDPP Comment Close Date: 2/22/2011

  8. 10 CFR 850, Request for Information- Docket Number: HS-RM-10-CBDPP- Christopher R. McKean

    Broader source: Energy.gov [DOE]

    Commenter: Christopher R. McKean 10 CFR 850 - Request for Information Docket Number: HS-RM-10-CBDPP Comment Close Date: 2/22/2011

  9. Fusion-fission and quasifission in the reactions with heavy ions leading to the formation of Hs

    SciTech Connect (OSTI)

    Itkis, I. M.; Itkis, M. G.; Knyazheva, G. N.; Kozulin, E. M.

    2012-10-20

    Mass and energy distributions of binary reaction products obtained in the reactions {sup 22}Ne+{sup 249}Cf,{sup 26}Mg+{sup 248}Cm,{sup 36}S+{sup 238}U and {sup 58}Fe+{sup 208}Pb leading to Hs isotopes have been measured. At energies below the Coulomb barrier the bimodal fission of Hs*, formed in the reaction {sup 26}Mg+{sup 248}Cm, is observed. In the reaction {sup 36}S+{sup 238}U the considerable part of the symmetric fragments arises from the quasifission process. At energies above the Coulomb barrier the symmetric fragments originate mainly from fusion-fission process for both reactions with Mg and S ions. In the case of the {sup 58}Fe+{sup 208}Pb reaction the quasifission process dominates at all measured energies. The pre- and post-scission neutron multiplicities as a function of the fragment mass have been obtained for the reactions studied.

  10. Fission and quasifission modes in heavy-ion-induced reactions leading to the formation of Hs{sup *}

    SciTech Connect (OSTI)

    Itkis, I. M.; Kozulin, E. M.; Itkis, M. G.; Knyazheva, G. N.; Bogachev, A. A.; Chernysheva, E. V.; Krupa, L.; Oganessian, Yu. Ts.; Zagrebaev, V. I.; Rusanov, A. Ya.; Goennenwein, F.; Dorvaux, O.; Stuttge, L.; Hanappe, F.; Vardaci, E.; Goes Brennand, E. de

    2011-06-15

    Mass and energy distributions of binary reaction products obtained in the reactions {sup 22}Ne+{sup 249}Cf,{sup 26}Mg+{sup 248}Cm, {sup 36}S+{sup 238}U, and {sup 58}Fe+{sup 208}Pb have been measured. All reactions lead to Hs isotopes. At energies below the Coulomb barrier the bimodal fission of Hs{sup *}, formed in the reaction {sup 26}Mg+{sup 248}Cm, is observed. In the reaction {sup 36}S+{sup 238}U, leading to the formation of a similar compound nucleus, the main part of the symmetric fragments arises from the quasifission process. At energies above the Coulomb barrier fusion-fission is the main process leading to the formation of symmetric fragments for both reactions with Mg and S ions. In the case of the {sup 58}Fe+{sup 208}Pb reaction the quasifission process dominates at all measured energies.

  11. THE He II POST-REIONIZATION EPOCH: HST/COS OBSERVATIONS OF THE QUASAR HS1700+6416

    SciTech Connect (OSTI)

    Syphers, David; Shull, J. Michael, E-mail: david.syphers@colorado.edu, E-mail: michael.shull@colorado.edu [CASA, Department of Astrophysical and Planetary Sciences, University of Colorado, Boulder, CO 80309 (United States)

    2013-03-10

    The reionization epoch of singly ionized helium (He II) is believed to start at redshifts z {approx} 3.5-4 and be nearly complete by z {approx_equal} 2.7. We explore the post-reionization epoch with far-ultraviolet spectra of the bright, high-redshift quasar HS1700+6416 taken by the Cosmic Origins Spectrograph (COS) on the Hubble Space Telescope, which show strong He II ({lambda}303.78) absorption shortward of the QSO redshift, z{sub QSO} = 2.75. We discuss these data as they probe the post-reionization history of He II and the local ionization environment around the quasar and transverse to the line of sight, finding that quasars are likely responsible for much of the ionization. We compare previous spectra taken by the Far-Ultraviolet Spectroscopic Explorer to the current COS data, which have a substantially higher signal-to-noise ratio. The Gunn-Peterson trough recovers at lower redshifts, with the effective optical depth falling from {tau}{sub eff} {approx_equal} 1.8 at z {approx} 2.7 to {tau}{sub eff} {approx_equal} 0.7 at z {approx} 2.3, higher than has been reported in earlier work. We see an interesting excess of flux near the He II Ly{alpha} break, which could be quasar line emission, although likely not He II Ly{alpha}. We present spectra of four possible transverse-proximity quasars, although the UV hardness data are not of sufficient quality to say if their effects are seen along the HS1700 sightline.

  12. Y H-S I-H HATIOHAL LEAth~~Y~~OF' OtUO ' Industrial Hygiene No...

    Office of Legacy Management (LM)

    H-S I-H HATIOHAL LEAthYOF' OtUO ' Industrial Hygiene No. P.O. Box 158)At.' He&bykation Sample Nos. ? Sk. 0 qq Cinchnail 31;Obio Type of SampleCI" lz -- HEALTH AND SAFETY ...

  13. Computer simulation of the CSPAD, ePix10k, and RayonixMX170HS X-ray detectors

    SciTech Connect (OSTI)

    Tina, Adrienne

    2015-08-21

    The invention of free-electron lasers (FELs) has opened a door to an entirely new level of scientific research. The Linac Coherent Light Source (LCLS) at SLAC National Accelerator Laboratory is an X-ray FEL that houses several instruments, each with its own unique X-ray applications. This light source is revolutionary in that while its properties allow for a whole new range of scientific opportunities, it also poses numerous challenges. For example, the intensity of a focused X-ray beam is enough to damage a sample in one mere pulse; however, the pulse speed and extreme brightness of the source together are enough to obtain enough information about that sample, so that no further measurements are necessary. An important device in the radiation detection process, particularly for X-ray imaging, is the detector. The power of the LCLS X-rays has instigated a need for better performing detectors. The research conducted for this project consisted of the study of X-ray detectors to imitate their behaviors in a computer program. The analysis of the Rayonix MX170-HS, CSPAD, and ePix10k in particular helped to understand their properties. This program simulated the interaction of X-ray photons with these detectors to discern the patterns of their responses. A scientist’s selection process of a detector for a specific experiment is simplified from the characterization of the detectors in the program.

  14. Headspace solid-phase microextraction (HS-SPME) for the determination of benzene, toluene, ethylbenzene, and xylenes (BTEX) in foundry molding sand

    SciTech Connect (OSTI)

    Dungan, R.S. [USDA ARS, Beltsville, MD (United States). Environmental Management & Byproducts Utilization Laboratory

    2005-07-01

    The use of headspace solid-phase microextraction (HS-SPME) to determine benzene, toluene, ethylbenzene, and xylenes (BTEX) in foundry molding sand, specifically a 'green sand' (clay-bonded sand) was investigated. The BTEX extraction was conducted using a 75 {mu} M carboxen-polydimethylsiloxane (CAR-PDMS) fiber, which was suspended above 10 g of sample. The SPME fiber was desorbed in a gas chromatograph injector port (280{sup o}C for 1 min) and the analytes were characterized by mass spectrometry. The effects of extraction time and temperature, water content, and clay and bituminous coal percentage on HS-SPME of BTEX were investigated. Because green sands contain bentonite clay and carbonaceous material such as crushed bituminous coal, a matrix effect was observed. The detection limits for BTEX were determined to be {lt}= 0.18 ng g{sup -1} of green sand.

  15. Sorption of carboxylic acid from carboxylic salt solutions at pHs close to or above the pK[sub a] of the acid, with regeneration with an aqueous solution of ammonia or low-molecular-weight alkylamine

    DOE Patents [OSTI]

    King, C.J.; Tung, L.A.

    1992-07-21

    Carboxylic acids are sorbed from aqueous feedstocks at pHs close to or above the acids' pH[sub a] into a strongly basic organic liquid phase or onto a basic solid adsorbent or moderately basic ion exchange resin. The acids are freed from the sorbent phase by treating it with aqueous alkylamine or ammonia thus forming an alkylammonium or ammonium carboxylate which dewatered and decomposed to the desired carboxylic acid and the alkylamine or ammonia. 8 figs.

  16. Berend Smit | Center for Gas SeparationsRelevant to Clean Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ...ultifunctionalization of Covalent Organic Polymers for Enhanced Carbon Capture. J. Amer. Chem. ... (MOFs): Designing Isoreticular MOF-5 Analogues Comprising Commercially ...

  17. Microsoft Word - 15-HS.02 Rev 8

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... 101413 Deleted in subsection 5.3.1 physical examination requirement. Modified... Technician EPA U.S. Environmental Protection Agency EST Emergency Services ...

  18. Computational Methods | Center for Gas SeparationsRelevant to...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Next List Maciej Haranczyk Maciej Haranczyk Laura Gagliardi Laura Gagliardi AMS 0246 Jeffrey Neaton Prendergast David Prendergast Berend Smit Berend Smit whitelam Stephen Whitelam...

  19. SHERPA DHS HS-STEM Summer Internship Summary Paper

    SciTech Connect (OSTI)

    Smith, Max Olan

    2015-07-01

    This report describes the Standard Unified Modeling and Mapping Integration Toolkit (SUMMIT) and how it can be used to prepare and plan for homeland emergencies.

  20. Interim reliability-evaluation program: analysis of the Millstone Point Unit 1 nuclear power plant. Volume IV. Appendix B. 9 through B. 19 and C

    SciTech Connect (OSTI)

    Curry, J J; Gallagher, D W; Modarres, M; Radder, J A

    1983-05-01

    Appendices are presented concerning isolation condenser makeup; vapor suppression system; station air system; reactor building closed cooling water system; turbine building secondary closed water system; service water system; emergency service water system; fire protection system; emergency ac power; dc power system; event probability estimation; methodology of accident sequence quantification; and assignment of dominant sequences to release categories.

  1. EIA - State Nuclear Profiles

    U.S. Energy Information Administration (EIA) Indexed Site

    ... The 500-acre site was formerly a granite quarry. Construction Cost: 8.845 billion (2007 USD)2 Reactor Descriptions: Millstone 2 and Millstone 3 are pressurized water reactors. ...

  2. File:Tip-top-tip-speed-teacher-HS.pdf | Open Energy Information

    Open Energy Info (EERE)

    this file. Metadata This file contains additional information, probably added from the digital camera or scanner used to create or digitize it. If the file has been modified from...

  3. File:Power-in-practice-and-theory-teacher-HS.pdf | Open Energy...

    Open Energy Info (EERE)

    this file. Metadata This file contains additional information, probably added from the digital camera or scanner used to create or digitize it. If the file has been modified from...

  4. File:Power-in-practice-and-theory-student-HS.pdf | Open Energy...

    Open Energy Info (EERE)

    this file. Metadata This file contains additional information, probably added from the digital camera or scanner used to create or digitize it. If the file has been modified from...

  5. File:Tip-top-tip-speed-student-HS.pdf | Open Energy Information

    Open Energy Info (EERE)

    this file. Metadata This file contains additional information, probably added from the digital camera or scanner used to create or digitize it. If the file has been modified from...

  6. File:Modeling-power-efficiency-and-tip-speed-ratio-student-HS...

    Open Energy Info (EERE)

    2014 1,650 1,275 (97 KB) Foteri (Talk | contribs) Category:Wind for Schools Portal CurriculaCategory:Wind for Schools High School Curricula You cannot overwrite this...

  7. File:Modeling-power-efficiency-and-tip-speed-ratios-teacher-HS...

    Open Energy Info (EERE)

    2014 1,650 1,275 (109 KB) Foteri (Talk | contribs) Category:Wind for Schools Portal CurriculaCategory:Wind for Schools High School Curricula You cannot overwrite this...

  8. File:What-speed-do-we-need-student-HS.pdf | Open Energy Information

    Open Energy Info (EERE)

    1,650 1,275, 3 pages (122 KB) Foteri (Talk | contribs) Category:Wind for Schools Portal CurriculaCategory:Wind for Schools High School Curricula You cannot overwrite this...

  9. File:What-speed-do-we-need-teacher-HS.pdf | Open Energy Information

    Open Energy Info (EERE)

    1,650 1,275, 3 pages (128 KB) Foteri (Talk | contribs) Category:Wind for Schools Portal CurriculaCategory:Wind for Schools High School Curricula You cannot overwrite this...

  10. NERSC Hosts HS Students on Job Shadow Day- NERSC Center News...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to be able to get an up close look about things that we are seriously considering as professions. Everyone was so friendly and informative not only about what they do currently at...

  11. Materials Data on LiHS (SG:135) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  12. Materials Data on NaHS (SG:160) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  13. Materials Data on LiHS (SG:54) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  14. File:Tip-top-tip-speed-lp-HS.pdf | Open Energy Information

    Open Energy Info (EERE)

    metadata was last modified 08:54, 7 August 2013 Software used Acrobat PDFMaker 9.0 for Word Conversion program Adobe PDF Library 9.0 Encrypted no Page size 612 x 792 pts (letter)...

  15. File:Power-in-practice-and-theory-lp-HS.pdf | Open Energy Information

    Open Energy Info (EERE)

    metadata was last modified 08:54, 7 August 2013 Software used Acrobat PDFMaker 9.0 for Word Conversion program Adobe PDF Library 9.0 Encrypted no Page size 612 x 792 pts (letter)...

  16. File:What-speed-do-we-need-lp-HS.pdf | Open Energy Information

    Open Energy Info (EERE)

    metadata was last modified 08:56, 7 August 2013 Software used Acrobat PDFMaker 9.0 for Word Conversion program Adobe PDF Library 9.0 Encrypted no Page size 612 x 792 pts (letter)...

  17. File:Wind-for-schools entire curriculum-HS.pdf | Open Energy...

    Open Energy Info (EERE)

    metadata was last modified 08:58, 7 August 2013 Software used Acrobat PDFMaker 9.0 for Word Conversion program Adobe PDF Library 9.0 Encrypted no Page size 612 x 792 pts (letter)...

  18. File:Wind-farm-policy-simulation lp-HS.pdf | Open Energy Information

    Open Energy Info (EERE)

    metadata was last modified 08:57, 7 August 2013 Software used Acrobat PDFMaker 9.0 for Word Conversion program Adobe PDF Library 9.0 Encrypted no Page size 612 x 792 pts (letter)...

  19. File:When-the-wind-doesn't-blow-lp-HS.pdf | Open Energy Information

    Open Energy Info (EERE)

    metadata was last modified 08:57, 7 August 2013 Software used Acrobat PDFMaker 9.0 for Word Conversion program Adobe PDF Library 9.0 Encrypted no Page size 612 x 792 pts (letter)...

  20. File:Modeling-power-efficiency-and-tip-speed-ratio-lp-HS.pdf...

    Open Energy Info (EERE)

    metadata was last modified 08:55, 7 August 2013 Software used Acrobat PDFMaker 9.0 for Word Conversion program Adobe PDF Library 9.0 Encrypted no Page size 612 x 792 pts (letter)...

  1. Nanoporous Materials Seminar | Center for Gas SeparationsRelevant...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    May 25, 2016 Feng Xue (University of Minnesota, PI: Tsapatsis) Synthesis of Metal-Organic Framework Nanosheets for Supported Membranes Rocio Mercado (UC Berkeley, PI: Smit) In ...

  2. May 25, 2016 | Center for Gas SeparationsRelevant to Clean Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Previous Next List Feng Xue (University of Minnesota, PI: Tsapatsis) Synthesis of Metal-Organic Framework Nanosheets for Supported Membranes Rocio Mercado (UC Berkeley, PI: Smit) ...

  3. Jeffrey Neaton | Center for Gas SeparationsRelevant to Clean...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Neaton, Jeffrey B.; Long, Jeffrey R; Smit, Berend; and Gagliardi, Laura The Mechanism of Carbon Dioxide Adsorption in an Alkylamine-Functionalized Metal-Organic Framework, J. Am. ...

  4. Laura Gagliardi | Center for Gas SeparationsRelevant to Clean...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Neaton, Jeffrey B.; Long, Jeffrey R; Smit, Berend; and Gagliardi, Laura The Mechanism of Carbon Dioxide Adsorption in an Alkylamine-Functionalized Metal-Organic Framework, J. Am. ...

  5. Li-Chiang Lin | Center for Gas SeparationsRelevant to Clean Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Neaton, Jeffrey B.; Long, Jeffrey R; Smit, Berend; and Gagliardi, Laura The Mechanism of Carbon Dioxide Adsorption in an Alkylamine-Functionalized Metal-Organic Framework, J. Am. ...

  6. Cory Simon | Center for Gas SeparationsRelevant to Clean Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    industrially relevant mixture of xenon and krypton. EFRC Publications Simon, Cory M.; Mercado, Rocio; Schnell, Sondre; Smit, Berend; and Haranczyk, Maciej. What Are the Best...

  7. What Are the Best Materials to Separate a Xenon/Krypton Mixture...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Best Materials to Separate a XenonKrypton Mixture? Previous Next List Simon, Cory M.; Mercado, Rocio; Schnell, Sondre; Smit, Berend; and Haranczyk, Maciej. What Are the Best...

  8. Addressing Challenges of Identifying Geometrically Diverse Sets...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Addressing Challenges of Identifying Geometrically Diverse Sets of Crystalline Porous Materials Previous Next List R. L. Martin, B. Smit, and M. Haranczyk, J. Chem Inf. Model. 52...

  9. A hybrid absorption-adsorption method to efficiently capture...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Wu, Jin Wang, Xueteng Gao, Yining Lv, Yong Pan, Xiaoxin Zhang, Xianren Zhang, Lanying Yang, Changyu Sun, Berend Smit & Wenchuan Wang, Nature Communications 5, 5147 (2014) DOI:...

  10. Adsorption and diffusion in zeolites: the pitfall of isotypic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Adsorption and diffusion in zeolites: the pitfall of isotypic crystal structures Previous Next List Nils E.R. Zimmermann, Maciej Haranczyk, Manju Sharma, Bei Liu, Berend Smit &...

  11. Mapping of Functional Groups in Metal-Organic Frameworks | Center...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mapping of Functional Groups in Metal-Organic Frameworks Previous Next List Xueqian Kong, Hexiang Deng, Fangyong Yan, Jihan Kim, Joseph A. Swisher, Berend Smit, Omar M. Yaghi,...

  12. Diffusion in confinement: kinetic simulations of self- and collective...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    confinement: kinetic simulations of self- and collective diffusion behavior of adsorbed gases Previous Next List M. K. F. Abouelnasr and B. Smit, PCCP 14 (33), 11600 (2012) DOI:...

  13. Chemical Hieroglyphs: Abstract Depiction of Complex Void Space...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemical Hieroglyphs: Abstract Depiction of Complex Void Space Topology of Nanoporous Materials Previous Next List Kevin Theisen, Berend Smit and Maciej Haranczyk, J. Chem. Inf. ...

  14. Microsoft Word - FullRpt_HS0402808_SS_LL_Z_rev042008 finalApril2.doc

    U.S. Energy Information Administration (EIA) Indexed Site

    SR/CNEAF/2008-01 Federal Financial Interventions and Subsidies in Energy Markets 2007 April 2008 Energy Information Administration Office of Coal, Nuclear, Electric, and Alternate Fuels U.S. Department of Energy Washington, DC 20585 This report was prepared by the Energy Information Administration, the independent statistical and analytical agency within the Department of Energy. The information contained herein should be attributed to the Energy Information Administration and should not be

  15. Water Adsorption in Metal-Organic Frameworks with Open-Metal...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water Adsorption in Metal-Organic Frameworks with Open-Metal Sites Previous Next List Xuan Peng, Li-Chiang Lin, Weizhen Sun and Berend Smit, AIChe J. 6, 677-687 (2015) DOI:...

  16. Nanoscale Chemical Imaging of a Working Catalyst

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in point. The complex chemistry associated with the iron-based catalyst has made even the identity of the active catalyst at work an unsolved mystery. At the ALS, de Smit et al....

  17. Evaluating mixture adsorption models using molecular simulation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    molecular simulation Previous Next List Joseph A. Swisher, Li-Chiang Lin, Jihan Kim, Berend Smit, AICHE J., 59, 3054-3064 (2013) DOI: 10.1002aic.14058 Abstract: The design of ...

  18. New materials for methane capture from dilute and medium-concentration...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New materials for methane capture from dilute and medium-concentration sources Previous Next List J. Kim, A. Maiti, L.-C. Lin, J. K. Stolaroff, B. Smit, and R. D. Aines, Nature...

  19. 3, Hans D. Jensen

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    effect is that the magnetic moment8 of odd- proton nuclei should deviate from the S&m&it lines.l In a constant magnetic field vithf 4 -22 1 the interaction term (2) 'becomes8 ...

  20. High-Throughput Characterization of Porous Materials Using Graphics...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    High-Throughput Characterization of Porous Materials Using Graphics Processing Units Previous Next List J. Kim, R. L. Martin, O. Rubel, M. Haranczyk, and B. Smit, J. Chem. Theory...

  1. Carbon Dioxide Capture: Prospects for New Materials | Center...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Carbon Dioxide Capture: Prospects for New Materials Previous Next List D. M. D'Alessandro, B. Smit, and J. R. Long, Angew. Chem.-Int. Edit. 49 (35), 6058 (2010) DOI: 10.1002...

  2. Molecular Simulation Study of the Competitive Adsorption of H2O...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Simulation Study of the Competitive Adsorption of H2O and CO2 in Zeolite 13X Previous Next List Lennart Joos, Joseph A. Swisher, and Berend Smit, Langmuir 29, 15936-15942 (2013)...

  3. Electron Bernstein Wave Emission and Mode Conversion Physics...

    Office of Scientific and Technical Information (OSTI)

    ... P. Beiersdorfer, M. Gu, M. Bitter, L. Delgado-Aparicio, K. W. Hill, M. Reinke, J. E. ... Review of Scientific Instruments 71, 2360 (2000). 19 H. G. Kaper, D. W. Smits, U. Schwarz, ...

  4. Efficient Monte Carlo Simulations of Gas Molecules Inside Porous...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Efficient Monte Carlo Simulations of Gas Molecules Inside Porous Materials Previous Next List J. Kim and B. Smit, J. Chem. Theory Comput. 8 (7), 2336 (2012) DOI: 10.1021ct3003699 ...

  5. Final-HRP-Memo-712-Clarifications-Under-the-Existing-Rule-Signed...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Jim O'Brien, HS-30 John Boulden, HS-40 Larry D. Wilcher, HS-50 Regina Cano, HS-50 Mike Zimmerman, HS-90 David Bivans, EM-44 Gene Runkle, SC-3 Earl Hicks, SC-31.3 Michael Lempke, ...

  6. State Nuclear Profiles 2010

    U.S. Energy Information Administration (EIA) Indexed Site

    and net generation, 2010 Millstone Unit 2, Unit 3 2,103 16,750 100.0 Dominion Nuclear Conn ... "Annual Electric Generator Report," and Form EIA-923, "Power Plant Operations Report." ...

  7. EIA - State Nuclear Profiles

    U.S. Energy Information Administration (EIA) Indexed Site

    ...231986 11252045 2,103 16,750 90.4 Data for 2010 PWR Pressurized Light Water Reactor. ... Construction Cost: 8.845 billion (2007 USD)2 Reactor Descriptions: Millstone 2 and ...

  8. Impacts of Long-term Drought on Power Systems in the U.S. Southwest...

    Office of Environmental Management (EM)

    ... heat wave conditions. Low water levels affect coal-fired and nuclear power plants' operations: - The Millstone nuclear plant in Waterford, CT had to shut down one of its ...

  9. SSRL BEAM PORT SCHEDULE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    FACI FACI FACI FACI 8050 C.SMITH 9A65 K.ZHANG FACI FACI FACI FACI CHANGE8050 C.SMIT MC CHECKOUT9A65 MC CHECKOUT9A40 FACI FACI FACI FACI 8050 C.SMITH 9A65 K.ZHANG 9A40 ...

  10. GPU Computational Screening

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    GPU Computational Screening of Carbon Capture Materials J. Kim 1 , A Koniges 1 , R. Martin 1 , M. Haranczyk 1 , J. Swisher 2 , and B. Smit 1,2 1 Lawrence Berkeley National Laboratory, Berkeley, CA 94720 2 Department of Chemical Engineering, University of California, Berkeley, Berkeley, CA 94720 E-mail: jihankim@lbl.gov Abstract. In order to reduce the current costs associated with carbon capture technologies, novel materials such as zeolites and metal-organic frameworks that are based on

  11. Resources | Center for Gas Separations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resources Outreach Center for Gas Separations: The Film by World Energy TV Carbon Capture Course Since 2011, Berend Smit and Jeffrey Reimer have taught a course on carbon capture in collaboration with four other researchers and lectures at UC Berkeley and Lawrence Berkeley National Lab. As part of the Berkeley Energy and Climate Lectures, the joint graduate/undergraduate course encompasses an informative and detailed survey of carbon capture, geological sequestration, and alternative

  12. Carbon Capture (Carbon Cycle 2.0)

    ScienceCinema (OSTI)

    Smit, Berend

    2011-06-08

    Berend Smit speaks at the Carbon Cycle 2.0 kick-off symposium Feb. 3, 2010. We emit more carbon into the atmosphere than natural processes are able to remove - an imbalance with negative consequences. Carbon Cycle 2.0 is a Berkeley Lab initiative to provide the science needed to restore this balance by integrating the Labs diverse research activities and delivering creative solutions toward a carbon-neutral energy future. http://carboncycle2.lbl.gov/

  13. NERSC-ScienceHighlightsJuly2013.ppt

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    July 2013 NERSC Science Highlights --- 1 --- NERSC User Science Highlights Materials Model is able to predict which of a million or so potential materials might be best for carbon capture (B. Smit, LBNL) Materials NERSC collaboration yields software that is a key enabler in the high- throughput computational materials science initiative (S. Ong, MIT) Climate NERSC simulations contribute to a study finding that emission regulations reduced soot and climate change impact in California W. Collins

  14. Slide 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mail-Order Metal-Organic Frameworks (MOFs): Designing Isoreticular MOF-5 Analogues Comprising Commercially Available Organic Molecules R. L. Martin, L.-C. Lin, K. Jariwala, B. Smit, M. Haranczyk, J. Phys. Chem. C 2013, 117 (23), 12159-12167. Highlighted on cover. Work was performed at University of California Berkeley and Lawrence Berkeley National Laboratory Scientific Achievement A database of isoreticular MOF-5 analogues comprising all commercially- available alternative linkers was

  15. Integrated Safety Management System Guide (Volume 1) for use with Safety Management System Policies (DOE P 450.4, DOE P 450.5, and DOE P 450.6); The Functions, Responsibilities, and Authorities Manual; and DOE Acquisition Regulation

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2001-03-01

    This Department of Energy (DOE) Integrated Safety Management System (ISMS) Guide is approved for use by the Office of Environment, Safety and Health (EH) and the National Nuclear Security Administration (NNSA). This Guide is available for use by all DOE components and their contractors. This Guide is a consensus document coordinated by EH and prepared under the direction of the DOE Safety Management Implementation Team (SMIT). Canceled by DOE G 450.4-1C.

  16. Vol 1, Integrated Safety Management System Guide (Volume 1), Chapter IV - Approved on March 28, 2000 and Added to the Guide

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2000-03-28

    This Department of Energy (DOE) Integrated Safety Management System (ISMS) Guide is approved for use by the Office of Environment, Safety and Health (EH) and is available for use by all DOE components and their contractors. This Guide is a consensus document coordinated by EH and prepared under the direction of the DOE Safety Management Implementation Team (SMIT). Canceled by DOE G 450.4-1B.

  17. Integrated Safety Management System Guide (Volume 1) for use with Safety Management System Policies (DOE P 450.4, DOE P 450.5, and DOE P 450.6); The Functions, Responsibilities, and Authorities Manual; and DOE Acquisition Regulation

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2001-03-01

    This Department of Energy (DOE) Integrated Safety Management System (ISMS) Guide is approved for use by the Office of Environment, Safety and Health (EH) and the National Nuclear Security Administration (NNSA). This Guide is available for use by all DOE components and their contractors. This Guide is a consensus document coordinated by EH and prepared under the direction of the DOE Safety Management Implementation Team (SMIT). Replaces DOE G 450.4-1A. Canceled by DOE G 450.4-1C.

  18. Vol 2, Integrated Safety Management System Guide

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1999-05-27

    This Department of Energy (DOE) Integrated Safety Management System (ISMS) Guide is approved for use by the Office of Environment, Safety and Health (EH) and is available for use by all DOE components and their contractors. This Guide is a consensus document coordinated by EH and prepared under the direction of the DOE Safety Management Implementation Team (SMIT). Canceled by DOE G 450.4-1B.

  19. Safety

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    safety Safety All JLF participants must comply fully with all LLNL safety regulations and procedures by becoming a Registered User of the facility. All JLF participants must complete available LLNL safety training: HS5200-W Laser Safety HS4258-W Beryllium Awareness HS4261-W Lead Awareness HS5220-W Electrical Safety Awareness HS6001-W General Employee Radiological HS4240-W Chemical Safety HS4680-W PPE To access these training modules link here [LTRAIN] from inside LLNL, or here from anywhere. All

  20. Electron-density comparisons between radar observations and 3-D ionospheric model calculations. Master's thesis

    SciTech Connect (OSTI)

    Johnson, M.W.

    1990-01-01

    A comparison of electron densities calculated from the Utah State University First-Principals Ionospheric Model with simultaneous observations taken at Sondrestrom, Millstone, and Arecibo incoherent-scatter radars was undertaken to better understanding the response of the ionosphere at these longitudinally similar yet latitudinally separated locations. The comparison included over 50 days distributed over 3 1/2 years roughly symmetrical about the last solar-minimum in 1986. The overall trend of the comparison was that to first-order the model reproduces electron densities responding to diurnal, seasonal, geomagnetic, and solar-cycle variations for all three radars. However, some model-observation discrepancies were found. These include, failure of the model to correctly produce an evening peak at Millstone, fall-spring equinox differences at Sondrestrom, tidal structure at Arecibo, and daytime NmF2 values at Arecibo.

  1. Participant Registration Procedure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    operations / participant registration procedure Participant Registration Procedure Under The "Safety" banner in the JLF Website "Policies and Procedures" Section: Complete Laser Eye Examination. Complete in LTRAIN HS5200-W Laser Safety. Complete in LTRAIN HS4258-W Beryllium (Be) Awareness. Complete in LTRAIN HS4261-W Lead (Pb) Awareness. Complete in LTRAIN HS5229-W Electrical Safety Awareness. Complete in LTRAIN HS-6001-W General Employee Radiological Training. Complete in

  2. Nuclear Regulatory Commission issuances

    SciTech Connect (OSTI)

    1996-04-01

    This report includes the issuances received during the April 1996 reporting period from the Commission, the Atomic Safety and Licensing Boards, the Administrative Law Judges, the Directors` Decisions, and the Decisions on Petitions for Rulemaking. Included are issuances pertaining to: (1) Yankee Nuclear Power Station, (2) Georgia Tech Research Reactor, (3) River Bend Station, (4) Millstone Unit 1, (5) Thermo-Lag fire barrier material, and (6) Louisiana Energy Services.

  3. Undergraduate Program Salary Structure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    26,520 12.75 HS +2 Completion of second year and minimum of 48 semester hours (salary cap for students pursuing an Associate's Degree) 29,120 14.00 HS +3 Completion of third...

  4. Contractor Past Performance Information

    Energy Savers [EERE]

    ... HS0000018 PARAGON TECHNICAL SERVICES, INC. R499 8,563,358.25 HS0000088 GET-NSA R699 8,484,899.09 DT0002641 HIGHLAND TECHNOLOGY SERVICES INC. R499 7,435,000.19 ...

  5. Homeland Security Science, Technology, Engineering, Mathematics Career Development Program Report

    SciTech Connect (OSTI)

    Bryson, Kathleen H.

    2009-11-06

    Report including the background, reserach and recommendations to expand the current DHS HS-STEM Career Development Program.

  6. Microsoft PowerPoint - New Materials for CH4 Capture-slide_AM [Read-Only]

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    We have discovered a handful of zeolite structures that have sufficient methane (CH 4 ) adsorption capacity as well as appropriate CH 4 /CO 2 and CH 4 /N 2 selectivity to be technologically promising for methane capture from dilute and medium-concentration sources. J Kim, A Maiti, L-C Lin, J Stolaroff, B Smit, R Aines, Nat. Commun. (2013). Doi: 10.1038/ncomms2697 New Materials for Methane Capture from Dilute and Medium-concentration Sources Significance and Impact Methane is an important

  7. Slide 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Evaluating different classes of porous materials for carbon capture J. M. Huck, L. Lin, A. H. Berger, M. Niknam Shahrak, R. L. Martin, A. S. Bhown, M. Haranczyk, K. Reuter, and B. Smit, Energy and Environmental Science (2014) [10.1039/c4ee02636e] Work was performed at UC Berkeley, TU Munich, EPRI, LBNL, and EPFL Characteristic plot of parasitic energy for coal (red circles), natural gas (blue squares), and direct air capture (green triangles) as function of Henry coefficient. Top right:

  8. Slide 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bloch, E. D.; Hudson, M. R.; Mason, J. A.; Chavan, S.; Crocellà, V.; Howe, J. D.; Lee, K.; Dzubak, A. L.; Queen, W. L.; Zadrozny, J. M.; Geier, S. J.; Lin, L.- C.; Gagliardi, L.; Smit, B.; Neaton, J. B.; Bordiga, S.; Brown, C. M.; Long, J. R. J. Am. Chem. Soc. 2014, 136, 10752-10761. Reversible CO Binding in Metal-Organic Frameworks Scientific Achievement Six metal-organic frameworks with different exposed divalent metal cations can bind CO reversibly and at high capacity Significance and

  9. BIG RU N INDIANA LAKESHORE RUN E LUMBER CIT Y WARSAW JOHNST

    U.S. Energy Information Administration (EIA) Indexed Site

    RU N INDIANA LAKESHORE RUN E LUMBER CIT Y WARSAW JOHNST OWN BU RNSIDE MILLSTONE FROSTBUR G JUN EAU PLU MVILLE CHERRY HILL KAN E BOSWELL MAR ION CENT ER CREEKSIDE SALTSBUR G POINT N BLAIR SVILL E COU NCIL RU N SIGEL LEWISVILLE BEAR C REEK AR MBRUST OHIOPYLE HALLT ON BR OOKVILLE MAR KTON NOL O RAT HMEL COR SICA MAR CHAND SMIC KSBU RG HOWE APOLLO SEVEN SPRIN GS YAT ESBORO MCNEES LUCIND A GEORGE PIN EY LEEPER TIMBLIN WILL ET FERGUSON CLIMAX PANIC DAVY HILL TIDIOUT E GRAMPIAN SLIGO ROC KVI LLE

  10. Connecticut Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Connecticut nuclear power plants, summer capacity and net generation, 2010" "Plant name/total reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net generation (percent)","Owner" "Millstone Unit 2, Unit 3","2,103","16,750",100.0,"Dominion Nuclear Conn Inc" "1 Plant 2 Reactors","2,103","16,750",100.0

  11. Insights from an overview of four PRAs

    SciTech Connect (OSTI)

    Fitzpatrick, R.; Arrieta, L.; Teichmann, T.; Davis, P.

    1986-01-01

    This paper summarizes the findings of an investigation of four probabilistic risk assessments (PRAs), those for Millstone 3, Seabrook, Shoreham, and Oconee 3, performed by Brookhaven National Laboratory (BNL) for the Reliability and Risk Assessment Branch of the US Nuclear Regulatory Commission (NRC). This group of four PRAs was subjected to an overview process with the basic goal of ascertaining what insights might be gained (beyond those already documented within the individual PRAs) by an independent evaluation of the group with respect to nuclear plant safety and vulnerability. Specifically, the objectives of the study were (1) to identify and rank initiators, systems, components, and failure modes from dominant accident sequences according to their contribution to core melt probability and public risk; and (2) to derive from this process plant-specific and generic insights. The effort was not intended to verify the specific details and results of each PRA but rather - having accepted the results - to see what they might mean in a more global context. The NRC had previously sponsored full detailed reviews of each of these PRAs, but only two, those for Millstone 3 and Shoreham, were completed and documented in time to allow their consideration within the study. This paper also presents some comments and insights into the amenability of certain features of these PRAs to this type of overview process.

  12. Fabrication and test of short helical solenoid model based on YBCO tape

    SciTech Connect (OSTI)

    Yu, M.; Lombardo, V.; Lopes, M.L.; Turrioni, D.; Zlobin, A.V.; Flanagan, G.; Johnson, R.P.; /MUONS Inc., Batavia

    2011-03-01

    A helical cooling channel (HCC) is a new technique proposed for six-dimensional (6D) cooling of muon beams. To achieve the optimal cooling rate, the high field section of HCC need to be developed, which suggests using High Temperature Superconductors (HTS). This paper updates the parameters of a YBCO based helical solenoid (HS) model, describes the fabrication of HS segments (double-pancake units) and the assembly of six-coil short HS model with two dummy cavity insertions. Three HS segments and the six-coil short model were tested. The results are presented and discussed.

  13. March 7, 2012, USW Health Safety and Environment Conference Presentati...

    Office of Environmental Management (EM)

    DOE Worker Safety and Health Regulatory Enforcement Kevin Dressman Director, Office of Worker Safety and Health Enforcement (HS-41) Office of Health, Safety and Security U.S....

  14. SASIG Conference Call Minutes- June 14, 2012

    Broader source: Energy.gov [DOE]

    The Office of Departmental Personnel Security (HS-53) forwarded the revised Security Termination Statement to the HSS forms manager on May 15 to be finalized.

  15. December 4, 2008; HSS/Union Working Group Meeting on 2008 HSS...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Worker Health and Safety (HS-10) Current and Planned Former Worker Program and ... This also meets records provisions established under CFR 851. FOR DECEMBER 4 HSSUNION ...

  16. Microsoft Word - DOE-ID-INL-15-005.docx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Test Range Complex (CITRC) - National and Homeland Security (N&HS) Electrical Upgrades to Power Burst ... categorical exclusion from 10 Code of Federal Regulation (CFR) ...

  17. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... David S. ; Masutani, Chikahide ; Tainer, John A. ; Hanaoka, Fumio ; et al Humore man DNA polymerase (HsPol ) plays an important role in translesion synthesis (TLS), ...

  18. Gardner Energy Management | Open Energy Information

    Open Energy Info (EERE)

    Gardner Energy Management Jump to: navigation, search Name: Gardner Energy Management Place: Bristol, United Kingdom Zip: BS1 2HS Product: UK-based steam trap manufacturer....

  19. Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    LECTURES AND TALKS: Location June 20 - 24 Sunday/19 Monday/20 Tuesday/21 Wednesday/22 Thursday/23 Friday/24 Saturday/25 breakfast breakfast breakfast breakfast breakfast breakfast breakfast 201 Chapman Hall 9:00 - 10:15 Jacobs (HDM) Jacobs (HDM) Jacobs (HDM) Jacobs (HDM) Makins (HS) Lobby 10:15 - 10:45 Break Break Break Break Break 201 Chapman Hall 10:45 - noon Evdokimov (HDM) Makins (HS) Makins (HS) Makins (HS) Formaggio (nu) TBA noon - 14:00 lunch lunch lunch lunch lunch lunch 201 Chapman Hall

  20. ORISE: ORISE is accepting applications for the 2015 U.S. Department...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for students majoring in homeland security-related science, technology, engineering and mathematics (HS-STEM) disciplines. The program is administered for DHS through ORISE,...

  1. Federal Register Notice, CBDPP Final Rule | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications 10 CFR 850, Notice of Proposed Rulemaking 10 CFR 850, Request for Information - Docket Number: HS-RM-10-CBDPP - Marc Kolanz Economic Assessment for ...

  2. Preliminary performance of HT datalink

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Cieslewski, Grzegorz

    Preliminary performance of HT HS datalink at room temperature over 5000ft of wireline. The data shows ablility of the datalink to adapt by decreasing speed.

  3. Independent Activity Report, Los Alamos National Laboratory ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    July 2012 Independent Activity Report, Los Alamos National Laboratory - July 2012 July 2012 Initial Meeting of Representatives from LANL, LASO, and HS-45 To Review Progress and...

  4. Overview and Challenges of Thin Film Solar Electric Technologies

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Challenges of Thin Film Solar Electric Technologies H.S. Ullal Presented at the World Renewable Energy Congress X and Exhibition 2008 Glasgow, Scotland, United Kingdom July ...

  5. Health Physics Support Assistant | Princeton Plasma Physics Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Saville Requisition Number: 1500691 POSITIONAL SUMMARY: To support the Health Physics Dosimeter program, records management (both archival and electronic) and to backup the ES&HS...

  6. ORISE: Undergraduates Research Experiences - Leslie Koyama

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Homeland Security HS-STEM Summer Internship Program, isolates colonies of E. coli in preparation for large scale protein purification. For Leslie Koyama, the possibility...

  7. NMMSS Orientation

    National Nuclear Security Administration (NNSA)

    in U-233 or U-235) 11 More Abbreviations Terms (continued) * DOE (Department of Energy) - NNSA (National Nuclear Security Administration) - HS-1.22 (Office of Information...

  8. Preliminary performance of HT datalink

    SciTech Connect (OSTI)

    Cieslewski, Grzegorz

    2014-02-11

    Preliminary performance of HT HS datalink at room temperature over 5000ft of wireline. The data shows ablility of the datalink to adapt by decreasing speed.

  9. Microsoft Word - Final Report Package Transmittal - FY 2010 FS...

    Energy Savers [EERE]

    Assistant Secretary for Nuclear Energy, NE-1 Director, ... Secretary for Environmental Management, EM-1 Principal Deputy ... of Health, Safety and Security, HS-1 Deputy Director ...

  10. Aprun MAN Page

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Aprun MAN Page Aprun MAN Page aprun -a arch -b -B -cc cpulist | keyword -cp cpuplacementfilename -d depth -D value -L nodelist -m sizeh|hs -n...

  11. SASIG Conference Call Minutes- July 12, 2012

    Broader source: Energy.gov [DOE]

    The Incidents of Security Concern Technical Standard, for which Sabeena Khanna is the HS-51 representative, is in the final concurrence phase in RevCom.

  12. ISSUED

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    02/09/16 WP 15-HS.02 Revision 9 Occupational Health Program Cognizant Department: Safety and Health Approved by: Tom Ferguson ISSUED WIPP Occupational Health Program WP 15-HS.02, Rev. 9 2 TABLE OF CONTENTS CHANGE HISTORY SUMMARY ..................................................................................... 4 ABBREVIATIONS AND ACRONYMS ............................................................................. 5 PREFACE

  13. Developing safety culture-rocket science or common sense?

    SciTech Connect (OSTI)

    Mahn, J.A.

    1998-08-01

    Despite evidence of significant management contributions to the causes of major accidents, recent events at Millstone Nuclear Power Station in the US and Ontario Hydro in Canada might lead one to conclude that the significance of safety culture, and the role of management in developing and maintaining an appropriate safety culture, is either not being understood or not being taken serious as integral to the safe operation of some complex, high-reliability operations. It is the purpose of this paper to address four aspects of management that are particularly important to safety culture, and to illustrate how development of an appropriate safety culture is more a matter of common sense than rocket science.

  14. Storm-induced changes of the topside ionosphere as deduced from incoherent-scatter radars. Master's thesis

    SciTech Connect (OSTI)

    Lunn, K.J.

    1990-01-01

    Incoherent scatter radar observations from Millstone Hill, Saint Santin, and Arecibo are used to illustrate changes of the topside ionosphere during a geomagnetic storm. These observations consist of electron density, electron and ion temperatures, and ion velocity components parallel and perpendicular to the magnetic field. These parameters can further describe changes in ion composition, electric fields, and neutral winds. Attention is given to a specific storm during the Equinox Transition Study (ETS) of September 1984. In order to isolate the storm effects in the topside ionosphere, a comparison will be made between a disturbed and quiet day. A novel result from this study is the finding of correlated oscillations between parallel and perpendicular ion velocity components which are apparently storm induced. Previously, these oscillations have been observed primarily at night, but now it's noticed that during storm conditions there are prominent oscillations during the day.

  15. Inhibition of IRAK-4 activity for rescuing endotoxin LPS-induced septic mortality in mice by lonicerae flos extract

    SciTech Connect (OSTI)

    Park, Sun Hong; Roh, Eunmiri; Kim, Hyun Soo; Baek, Seung-Il; Choi, Nam Song; Kim, Narae; Hwang, Bang Yeon; Han, Sang-Bae; Kim, Youngsoo

    2013-12-13

    Highlights: •Lonicerae flos extract (HS-23) is a clinical candidate, Phase I for sepsis treatment. •Here, HS-23 or its major constituents rescued LPS-induced septic mortality in mice. •As a mechanism, they directly inhibited IRAK-4-catalyzed kinase activity. •Thus, they suppressed LPS-induced expression of NF-κB/AP-1-target inflammatory genes. -- Abstract: Lonicerae flos extract (HS-23) is a clinical candidate currently undergoing Phase I trial in lipopolysaccharide (LPS)-injected healthy human volunteers, but its molecular basis remains to be defined. Here, we investigated protective effects of HS-23 or its major constituents on Escherichia coli LPS-induced septic mortality in mice. Intravenous treatment with HS-23 rescued LPS-intoxicated C57BL/6J mice under septic conditions, and decreased the levels of cytokines such as tumor necrosis factor α (TNF-α), interleukin (IL)-1β and high-mobility group box-1 (HMGB-1) in the blood. Chlorogenic acid (CGA) and its isomers were assigned as major constituents of HS-23 in the protection against endotoxemia. As a molecular mechanism, HS-23 or CGA isomers inhibited endotoxin LPS-induced autophosphorylation of the IL-1 receptor-associated kinase 4 (IRAK-4) in mouse peritoneal macrophages as well as the kinase activity of IRAK-4 in cell-free reactions. HS-23 consequently suppressed downstream pathways critical for LPS-induced activation of nuclear factor (NF)-κB or activating protein 1 (AP-1) in the peritoneal macrophages. HS-23 also inhibited various toll-like receptor agonists-induced nitric oxide (NO) production, and down-regulated LPS-induced expression of NF-κB/AP-1-target inflammatory genes in the cells. Taken together, HS-23 or CGA isomers exhibited anti-inflammatory therapy against LPS-induced septic mortality in mice, at least in part, mediated through the inhibition of IRAK-4.

  16. Synthesis and characterization of mixed monolayer protected gold nanorods and their Raman activities

    SciTech Connect (OSTI)

    Mlambo, Mbuso; Mdluli, Phumlani S.; Shumbula, Poslet; Mpelane, Siyasanga; Moloto, Nosipho; Skepu, Amanda; Tshikhudo, Robert

    2013-10-15

    Graphical abstract: Gold nanorods surface functionalization. - Highlights: • Mixed monolayer protected gold nanorods. • Surface enhanced Raman spectroscopy. • HS-(CH{sub 2}){sub 11}-NHCO-coumarin as a Raman active compound. - Abstract: The cetyltrimethylammonium bromide (CTAB) gold nanorods (AuNRs) were prepared by seed-mediated route followed by the addition of a Raman active compound (HS-(CH{sub 2}){sub 11}-NHCO-coumarin) on the gold nanorods surfaces. Different stoichiometric mixtures of HS-(CH{sub 2}){sub 11}-NHCO-coumarin and HS-PEG-(CH{sub 2}){sub 11}COOH were evaluated for their Raman activities. The lowest stoichiometric ratio HS-(CH{sub 2}){sub 11}-NHCO-coumarin adsorbed on gold nanorods surface was detected and enhanced by Raman spectroscopy. The produced mixed monolayer protected gold nanorods were characterized by UV-vis spectrometer for optical properties, transmission electron microscope (TEM) for structural properties (shape and aspect ratio) and their zeta potentials (charges) were obtained from ZetaSizer to determine the stability of the produced mixed monolayer protected gold nanorods. The Raman results showed a surface enhanced Raman scattering (SERS) enhancement at the lowest stoichiometric ratio of 1% HS-(CH{sub 2}){sub 11}-NHCO-coumarin compared to high ratio of 50% HS-(CH{sub 2}){sub 11}-NHCO-coumarin on the surface of gold nanorods.

  17. Holey Silicon as an Efficient Thermoelectric Material

    SciTech Connect (OSTI)

    Tang, Jinyao; Wang, Hung-Ta; Hyun Lee, Dong; Fardy, Melissa; Huo, Ziyang; Russell, Thomas P.; Yang, Peidong

    2010-09-30

    This work investigated the thermoelectric properties of thin silicon membranes that have been decorated with high density of nanoscopic holes. These ?holey silicon? (HS) structures were fabricated by either nanosphere or block-copolymer lithography, both of which are scalable for practical device application. By reducing the pitch of the hexagonal holey pattern down to 55 nm with 35percent porosity, the thermal conductivity of HS is consistently reduced by 2 orders of magnitude and approaches the amorphous limit. With a ZT value of 0.4 at room temperature, the thermoelectric performance of HS is comparable with the best value recorded in silicon nanowire system.

  18. The rise of X-ray beam chemistry | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Justin H.S. Breaux at (630) 252-5823 or media@anl.gov. Connect Find an Argonne expert by subject. Follow Argonne on Twitter, Facebook, Google+ and LinkedIn. For inquiries on...

  19. Sweet spot: Disabling antibiotic-resistant bacteria | Argonne...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Justin H.S. Breaux at (630) 252-5823 or media@anl.gov. Connect Find an Argonne expert by subject. Follow Argonne on Twitter, Facebook, Google+ and LinkedIn. For inquiries on...

  20. Status Update on Action 2c: Criteria Review and Approach Document (CRAD) for Performing Assessments of Activity-level Work Planning and Control

    Broader source: Energy.gov [DOE]

    Slide Presentation by Bradley K. Davy, Director, Office of Worker Safety and Health Assistance, HS. Criteria Review and Approach Document (CRAD) for Performing Assessments of Activity- Level Work Planning and Control. DOE CRAD Development Approach.

  1. December 4, 2008; HSS/Union Working Group Meeting on 2008 HSS...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... these requirements are covered under 10 CFR 851; HS-10 has developed and will provide a matrix on all of the DOE worker health and safety training requirements under the 851 Rule. ...

  2. BIOENERGIZEME INFOGRAPHIC CHALLENGE: What is Biogas?

    Broader source: Energy.gov [DOE]

    This infographic was created by students from Sparks HS in Sparks, NV, as part of the U.S. Department of Energy-BioenergizeME Infographic Challenge. The BioenergizeME Infographic Challenge...

  3. BIOENERGIZEME INFOGRAPHIC CHALLENGE: BIOfuel

    Office of Energy Efficiency and Renewable Energy (EERE)

    This infographic was created by students from Broad Run HS in Ashburn, VA, as part of the U.S. Department of Energy-BioenergizeME Infographic Challenge. The BioenergizeME Infographic Challenge...

  4. BIOENERGIZEME INFOGRAPHIC CHALLENGE: What is Biomass?

    Broader source: Energy.gov [DOE]

    This infographic was created by students from Sparks HS in Sparks, NV, as part of the U.S. Department of Energy-BioenergizeME Infographic Challenge. The BioenergizeME Infographic Challenge...

  5. BIOENERGIZEME INFOGRAPHIC CHALLENGE: Biomass Reduces Carbon Dioxide

    Broader source: Energy.gov [DOE]

    This infographic was created by students from Sparks HS in Sparks, NV, as part of the U.S. Department of Energy-BioenergizeME Infographic Challenge. The BioenergizeME Infographic Challenge...

  6. BIOENERGIZEME INFOGRAPHIC CHALLENGE: Bessie's Biofuel

    Broader source: Energy.gov [DOE]

    This infographic was created by students from Smithtown HS East in St. James, NY, as part of the U.S. Department of Energy-BioenergizeME Infographic Challenge. The BioenergizeME Infographic...

  7. FIA-14-0001 - In the Matter of Donna Deedy | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Donna Deedy filed an Appeal regarding a request that she filed under the Freedom of ... Deedy. In her Appeal, Ms. Deedy challenged the adequacy of HS' search, maintaining that ...

  8. BIOENERGIZEME INFOGRAPHIC CHALLENGE: Cellulosic Ethanol

    Broader source: Energy.gov [DOE]

    This infographic was created by students from Williamsburg HS for Architecture and Design in Brooklyn, NY, as part of the U.S. Department of Energy-BioenergizeME Infographic Challenge. The...

  9. Microsoft Word - DOE-ID-INL-16-004.docx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (N&HS) personnel with a new field station office near the Safety Test Facility ... DOE-ID NEPA CX DETERMINATION Idaho National Laboratory Page 2 of 2 CX Posting No.: ...

  10. Microsoft Word - DOE-ID-INL-16-004 R1.docx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of 4 CX Posting No.: DOE-ID-INL-16-004 R1 Original EC The proposed action would provide National & Homeland Security (N&HS) personnel with a new field station office near the ...

  11. BIOENERGIZEME INFOGRAPHIC CHALLENGE: Corn to Ethanol the Process

    Broader source: Energy.gov [DOE]

    This infographic was created by students from Broad Run HS in Ashburn, VA, as part of the U.S. Department of Energy-BioenergizeME Infographic Challenge. The BioenergizeME Infographic Challenge...

  12. BIOENERGIZEME INFOGRAPHIC CHALLENGE: Iowa Ethanol Production

    Broader source: Energy.gov [DOE]

    This infographic was created by students from Sparks HS in Sparks, NV, as part of the U.S. Department of Energy-BioenergizeME Infographic Challenge. The BioenergizeME Infographic Challenge...

  13. Midea: Noncompliance Determination (2010-SE-0110)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Midea America Corporation finding that basic model number HS-390C, a chest freezer, does not comport with the energy conservation standards.

  14. BIOENERGIZEME INFOGRAPHIC CHALLENGE: Travel to the Future with Bioenergy

    Broader source: Energy.gov [DOE]

    This infographic was created by students from Smithtown HS East in St. James, NY, as part of the U.S. Department of Energy-BioenergizeME Infographic Challenge. The BioenergizeME Infographic...

  15. BIOENERGIZEME INFOGRAPHIC CHALLENGE: From Fields to Fuel

    Broader source: Energy.gov [DOE]

    This infographic was created by students from Smithtown HS East in St. James, NY, as part of the U.S. Department of Energy-BioenergizeME Infographic Challenge. The BioenergizeME Infographic...

  16. Shape-shifting groups of nanorods release heat differently |...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Shape-shifting groups of nanorods release heat differently By Justin H.S. Breaux * ... of the transfer of heat at the nanoscale cause nanoparticles to change shape in ensembles. ...

  17. EIS-0302: Transfer of the Heat Source/Radioisotope Thermoelectric Generator Assembly and Test Operations From the Mound Site

    Broader source: Energy.gov [DOE]

    This EIS analyzes DOE's proposed transfer of the Heat Source/Radioisotope Thermoelectric Generator (HS/RTG) operations at the Mound Site near Miamisburg, Ohio, to an alternative DOE site.

  18. BIOENERGIZEME INFOGRAPHIC CHALLENGE: History of Biomass

    Broader source: Energy.gov [DOE]

    This infographic was created by students from Broad Run HS in Ashburn, VA, as part of the U.S. Department of Energy-BioenergizeME Infographic Challenge. The BioenergizeME Infographic Challenge...

  19. Environment/Health/Safety (EHS)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Health Services HS Home Clinical Services Policies and Procedures Presentations Forms Contact Us AED Building 26 (510) 486-6266 Monday - Friday 7:00 am - 4:30 pm In case of...

  20. 2012 Annual Workforce Analysis and Staffing Plan Report - Carlsbad

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    , NA-SH-40 * ED J. Yarrington, HS-10 ED G. Basabilvazo, CBFO ED A. Cooper, CBFO ED J. Waters, CBFO ED DOE M&RC *ED denotes electronic distribution Annual Workforce Analysis and...

  1. BIOENERGIZEME INFOGRAPHIC CHALLENGE: Environmental Benefits of Bioenergy Corn Can Save the Earth

    Broader source: Energy.gov [DOE]

    This infographic was created by students from Smithtown HS East in St. James, NY, as part of the U.S. Department of Energy-BioenergizeME Infographic Challenge. The BioenergizeME Infographic...

  2. BIOENERGIZEME INFOGRAPHIC CHALLENGE: Bioenergy Through Time

    Broader source: Energy.gov [DOE]

    This infographic was created by students from Robinson HS in Tampa, FL, as part of the U.S. Department of Energy-BioenergizeME Infographic Challenge. The BioenergizeME Infographic Challenge...

  3. Introduction of Afternoon Topics and Expectations

    Broader source: Energy.gov [DOE]

    Appreciation and overview remarks by DOE Integrated Safety Management Co-champions Patricia R. Worthington, HSS Director, Office of Health and Safety, HS-10 and Ray J. Corey, Assistant Manager for Safety and Environment, DOE Richland Operations Office.

  4. Welcome, Purpose, and Introductions

    Broader source: Energy.gov [DOE]

    Appreciation and overview remarks by DOE Integrated Safety Management Co-champions Patricia R. Worthington, HSS Director, Office of Health and Safety, HS-10 and Ray J. Corey, Assistant Manager for Safety and Environment, DOE Richland Operations Office.

  5. How is a document containing UCNI marked? | Department of Energy

    Energy Savers [EERE]

    must include the abbreviation "UCNI," the Reviewing Official's name and organization, and the guidance used to make the UCNI determination (e.g., UCNI; Jane Smith, HS-90; CG-SS-4). ...

  6. Impact Assessments | Department of Energy

    Energy Savers [EERE]

    Tracking System (HSCT) (pdf) Hs Web Services (HSWS) (pdf) HSS Electronic ... (pdf) PIV System-PIA (pdf) GovTrip (pdf) WEB govTrip (DOE data) (pdf) WEB HSPD 12 ...

  7. HORIZON SENSING

    SciTech Connect (OSTI)

    Larry G. Stolarczyk, Sc.D.

    2002-07-31

    Real-time horizon sensing (HS) on continuous mining (CM) machines is becoming an industry tool. Installation and testing of production-grade HS systems has been ongoing this quarter at Oxbow Mining Company, Monterey Coal Company (EXXON), FMC Trona, Twentymile Coal Company (RAG America), and SASOL Coal. Detailed monitoring of system function, user experience, and mining benefits is ongoing. All horizon sensor components have finished MSHA (United States) and IEC (International) certification.

  8. One Direction: Researchers grow nanocircuitry with semiconducting graphene

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    nanoribbons | Argonne National Laboratory Contact Us For more information, contact Justin H.S. Breaux at (630) 252-5823 or media@anl.gov. Connect Find an Argonne expert by subject. Follow Argonne on Twitter, Facebook, Google+ and LinkedIn. For inquiries on commercializing Argonne technology or partnering with Argonne to solve your R&D or production challenges, contact partners@anl.gov. One Direction: Researchers grow nanocircuitry with semiconducting graphene nanoribbons By Justin H.S.

  9. U.S. Department of Energy Office of Inspector General Ofice of Audit Services

    Office of Environmental Management (EM)

    of Health, Safety and Security Office of Analysis, HS-24 December 19, 2013 Responses to Frequently Asked Questions on DOE O 232.2, Occurrence Reporting and Processing of Operations Information Page 1 of 30 Responses to Frequently Asked Questions on DOE O 232.2, Occurrence Reporting and Processing of Operations Information Office of Analysis, HS-24 December 19, 2013 The intent of these responses to frequently asked questions (FAQ) is to provide additional insights for Department of Energy (DOE)

  10. July 10-11, 2012, HSS Focus Group Training Work Group - Attendees

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    HSS Focus Group Training Work Group Meeting Minutes July 10 & 11, 2012 Attendees Pete Stafford BCTD Gary Karnofski HAMMER Karen McGinnis HAMMER Karen Boardman NTC Evan Dunne NTC Pete Turcic NTC Ted Giltz HAMMER Julie Johnston EFCOG Pete O'Connell HS-11 Dan Marsick HS-11 Chip Hughes NIEHS Ted Outwater NIEHS Sharon Beard NIEHS Jim Remington NIEHS Kathy Ahlmark NIEHS Brian Killand HAMMER Randy Coleman HAMMER Bob Legard HAMMER Deborah Weinstock NIEHS Belinda Holley, Sandia Doug Stephens, USW

  11. Alu repeats as markers for forensic DNA analyses

    SciTech Connect (OSTI)

    Batzer, M.A.; Alegria-Hartman, M.; Kass, D.H.

    1994-01-01

    The Human-Specific (HS) subfamily of Alu sequences is comprised of a group of 500 nearly identical members which are almost exclusively restricted to the human genome. Individual subfamily members share an average of 98.9% nucleotide identity with the HS subfamily consensus sequence, and have an average age of 2.8 million years. We have developed a Polymerase Chain Reaction (PCR) based assay using primers complementary to the 5 inch and 3 inch unique flanking DNA sequences from each HS Alu that allow the locus to be assayed for the presence or absence of the Alu repeat. The dimorphic HS Alu sequences probably inserted in the human genome after the radiation of modem humans (within the last 200,000-one million years) and represent a unique source of information for human population genetics and forensic DNA analyses. These sites can be developed into Dimorphic Alu Sequence Tagged Sites (DASTS) for the Human Genome Project. HS Alu family member insertions differ from other types of polymorphism (e.g. Variable Number of Tandem Repeat [VNTR] or Restriction Fragment Length Polymorphism [RFLP]) in that polymorphisms due to Alu insertions arise as a result of a unique event which has occurred only one time in the human population and spread through the population from that point. Therefore, individuals that share HS Alu repeats inherited these elements from a common ancestor. Most VNTR and RFLP polymorphisms may arise multiple times in parallel within a population.

  12. Cadmium complexation with bisulfide

    SciTech Connect (OSTI)

    Wang, F.; Tessier, A.

    1999-12-01

    The authors have used in situ dialysis to measure the solubility of CdS(s) in sulfidic solutions. The solubility product for the reaction CdS(s) + H{sup +} {l{underscore}reversible} Cd{sup 2+} + HS{sup {minus}} at 25 C and 1 atm was found to be 10{sup {minus}14.15{+-}0.06} and 10{sup {minus}14.40{+-}0.03} for a crystalline product and to be 10{sup {minus}14.15{+-}0.06} for two precipitates, respectively. They show that the solubility of these three solids at various pH values and sulfide concentrations can be reproduced adequately by the following four bisulfide complexes: CdHS{sup +}, Cd(HS){sub 2}, Cd(HS){sub 3}{sup {minus}}, and Cd(HS){sub 4}{sup 2{minus}}; the log K{sub n} values for the general equation Cd{sup 2+} + nHS{sup {minus}} {r{underscore}reversible} Cd(HS){sub n}{sup 2{minus}n} are 7.38 {+-} 0.68, 14.43 {+-} 0.01, 16026 & 0.58, and 18.43 {+-} 0.05, respectively. The species CdOHS{sup {minus}}, which has been reported previously, does not explain their experimental results. Calculations using estimated concentrations of organic ligands (humic substances and organic thiols) known to be present in natural waters indicate that sulfide complexes largely dominate Cd speciation in natural waters at {Sigma}S(-II) {ge} 10{sup {minus}6} M.

  13. Increasing reserves through improved evaluation of low contrast pay sands: Lower Lagunillas, Bloque IV, Lake Maracaibo

    SciTech Connect (OSTI)

    Bryant, I.D.; Herron, M.; Matteson, A.; Ramamoorthy, R.

    1996-08-01

    Pay sands have traditionally been defined in the Lower Lagunillas reservoir by applying porosity and saturation cutoffs following a Waxman-Smits evaluation. This strategy has proven useful to identify sands which historically provided prolific production when completed over multiple zones in vertical wells. However, zones that were not attractive completion targets in vertical wells have been shown to be attractive targets for dedicated horizontal infill wells. The mineralogy of samples from old cores has been determined by Fourier Transform infrared spectroscopy. This mineralogical model has been implemented to provide improved evaluations of the shaly sands. This evaluation suggests that in-place oil volumes may be up to 23% higher. In new infill wells, FMI logs indicate that non-traditional pay zones comprise thinly laminated sands and shales. Incorporation of the these high resolution logs into high resolution petrophysical evaluations yields further increases in evaluated oil volumes of 44% in these zones. A recently drilled infill well has established that these zones can produce oil at economic rates in a horizontal drainhole.

  14. Plant maintenance and plant life extension issue, 2009

    SciTech Connect (OSTI)

    Agnihotri, Newal

    2009-03-15

    The focus of the March-April issue is on plant maintenance and plant life extension. Major articles include the following: Application of modeling and simulation to nuclear power plants, by Berry Gibson, IBM, and Rolf Gibbels, Dassault Systems; Steam generators with tight manufacturing procedures, by Ei Kadokami, Mitsubishi Heavy Industries; SG design based on operational experience and R and D, by Jun Tang, Babcock and Wilcox Canada; Confident to deliver reliable performance, by Bruce Bevilacqua, Westinghouse Nuclear; An evolutionary plant design, by Martin Parece, AREVA NP, Inc.; and, Designed for optimum production, by Danny Roderick, GE Hitachi Nuclear Energy. Industry Innovation articles include: Controlling alloy 600 degradation, by John Wilson, Exelon Nuclear Corporation; Condensate polishing innovation, by Lewis Crone, Dominion Millstone Power Station; Reducing deposits in steam generators, by the Electric Power Research Institute; and, Minimizing Radiological effluent releases, by the Electric Power Research Institute. The plant profile article is titled 2008 - a year of 'firsts' for AmerenUE's Callaway plant, by Rick Eastman, AmerenUE.

  15. FABSOAR--A Fabry-Perot Spectrometer for Oxygen A-band Research Final Technical Report

    SciTech Connect (OSTI)

    Watchorn, Steven

    2010-09-10

    Because this was a Phase I project, it did not add extensively to the body of A-band knowledge. There was no basic research performed on that subject. The principal addition was that a mechanical and optical design for a triple-etalon Fabry-Perot interferometer (FABSOAR) capable of A-band sensing was sketched out and shown to be within readily feasible instrument fabrication parameters. The parameters for the proposed triple-etalon Fabry-Perot were shown to be very similar to existing Fabry-Perots built by Scientific Solutions. The mechanical design for the FABSOAR instrument incorporated the design of previous Scientific Solutions imagers, condensing the three three-inch-diameter etalons into a single, sturdy tube. The design allowed for the inclusion of a commercial off-the-shelf (COTS) filter wheel and a thermocooled CCD detector from Andor. The tube has supports to mount to a horizontal or vertical opticaltable surface, and was to be coupled to a Scientific Solutions pointing head at the Millstone Hill Observatory in Massachusetts for Phase II calibration and testing.

  16. 1986 EPRI radwaste workshop: Proceedings

    SciTech Connect (OSTI)

    Not Available

    1988-10-01

    The proceedings of the eighth radwaste workshop are presented. The workshop presentations and discussion sessions addressed: Waste Minimization and On-Site Storage, Regulatory Issues, and Radwaste Equipment Operating Experience. Significant accomplishments in waste volume reduction and resultant cost savings were demonstrated by the actual results achieved with the implementation of dedicated management supported volume reduction programs at Brunswick and Crystal River Unit /number sign/3. On-site storage implementation is being accomplished at the Duane Arnold Energy Center of Iowa Electric by construction of a low level radwaste processing and storage facility. The design of this facility was described. The regulatory lectures covered disposal site issues and an update on waste transportation regulations. Current regulatory issues were addressed by a representative of the NRC. The lectures on radwaste equipment operating experience discussed radwaste evaporator experience at Callaway, steam generator chemical cleaning waste processing at Millstone Unit /number sign/2 and comparison testing of General Electric and Westinghouse-Hittman super compactors at Idaho National Engineering Laboratory. Individual papers were processed separately for the data base.

  17. Recurrent nonsense mutations within the type VII collagen gene in patients with severe recessive dystrophic epidermolysis bullosa

    SciTech Connect (OSTI)

    Hovnanian, A.; Hilal, L.; Goossens, M. ); Blanchet-Bardon, C.; Prost, Y. de ); Christiano, A.M.; Uitto, J. )

    1994-08-01

    The generalized mutilating form of recessive dystrophic epidermolysis bullosa (i.e., the Hallopeau-Siemens type; HS-RDEB) is a life-threatening disease characterized by extreme mucocutaneous fragility associated with absent or markedly altered anchoring fibrils (AF). Recently, the authors reported linkage between HS-RDEB and the type VII collagen gene (COL7A1), which encodes the major component of AF. In this study, they investigated 52 unrelated HS-RDEB patients and 2 patients with RDEB inversa for the presence, at CpG dinucleotides, of mutations changing CGA arginine codons to premature stop codons TGA within the COL7A1 gene. Eight exons containing 10 CGA codons located in the amino-terminal domain of the COL7A1 gene were studied. Mutation analysis was performed using denaturing gradient gel electrophoresis of PCR-amplified genomic fragments. Direct sequencing of PCR-amplified products with altered electrophoretic mobility led to the characterization of three premature stop codons, each in a single COL7A1 allele, in four patients. Two patients (one affected with HS-RDEB and the other with RDEB inversa) have the same C-to-T transition at arginine codon 109. Two other HS-RDEB patients have a C-to-T transition at arginine 1213 and 1216, respectively. These nonsense mutations predict the truncation of [approximately]56%-92% of the polypeptide, including the collagenous and the noncollagenous NC-2 domains. On the basis of linkage analysis, which showed no evidence for locus heterogeneity in RDEB, it is expected that these patients are compound heterozygotes and have additional mutations on the other COL7A1 allele, leading to impaired AF formation. These results indicate that stop mutations within the COL7A1 gene can underlie both HS-RDEB and RDEB inversa, thus providing further evidence for the implication of this gene in RDEB. 46 refs., 3 figs., 1 tab.

  18. Lessons Learned from Alternative Transportation Fuels: Modeling Transition Dynamics

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Lessons Learned from Alternative Transportation Fuels: Modeling Transition Dynamics C. Welch Technical Report NREL/TP-540-39446 February 2006 Lessons Learned from Alternative Transportation Fuels: Modeling Transition Dynamics C. Welch Prepared under Task Nos. HS04.2000 and HS06.1002 Technical Report NREL/TP-540-39446 February 2006 National Renewable Energy Laboratory 1617 Cole Boulevard, Golden, Colorado 80401-3393 303-275-3000 * www.nrel.gov Operated for the U.S. Department of Energy Office of

  19. NMMSS Newsletter, March 16, 2009 Special Edition

    National Nuclear Security Administration (NNSA)

    Department of Energy Peter Dessaules 301/903-4525 Pete.Dessaules@hq.doe.gov Nuclear Regulatory Commission Brian Horn 301/492-3122 Brian.Horn@nrc.gov DOE International POC James Crabtree 301/903-6008 James.Crabtree@hq.doe.gov NRC International POC Santiago Aguilar 301/492-3569 Santiago.Aguilar@nrc.gov SIMEX Routing: RHEGGTN U.S. Department of Energy NMMSS program, HS-1.22 301/903-6251 Classified: Inner Envelope Attn: NMMSS program, HS-1.22 U.S. Department of Energy P.O. Box A Germantown, MD

  20. High-Sensitivity C-Reactive Protein Complements Plasma Epstein-Barr Virus Deoxyribonucleic Acid Prognostication in Nasopharyngeal Carcinoma: A Large-Scale Retrospective and Prospective Cohort Study

    SciTech Connect (OSTI)

    Tang, Lin-Quan; Li, Chao-Feng; Chen, Qiu-Yan; Zhang, Lu; Lai, Xiao-Ping; He, Yun; Xu, Yun-Xiu-Xiu; Hu, Dong-Peng; Wen, Shi-Hua; Peng, Yu-Tuan; Chen, Wen-Hui; Liu, Huai; Guo, Shan-Shan; Liu, Li-Ting; Li, Jing; Zhang, Jing-Ping; and others

    2015-02-01

    Purpose: To evaluate the effects of combining the assessment of circulating high-sensitivity C-reactive protein (hs-CRP) with that of Epstein-Barr virus DNA (EBV DNA) in the pretherapy prognostication of nasopharyngeal carcinoma (NPC). Patients and Methods: Three independent cohorts of NPC patients (training set of n=3113, internal validation set of n=1556, and prospective validation set of n=1668) were studied. Determinants of disease-free survival, distant metastasis–free survival, and overall survival were assessed by multivariate analysis. Hazard ratios and survival probabilities of the patient groups, segregated by clinical stage (T1-2N0-1M0, T3-4N0-1M0, T1-2N2-3M0, and T3-4N2-3M0) and EBV DNA load (low or high) alone, and also according to hs-CRP level (low or high), were compared. Results: Elevated hs-CRP and EBV DNA levels were significantly correlated with poor disease-free survival, distant metastasis–free survival, and overall survival in both the training and validation sets. Associations were similar and remained significant after excluding patients with cardiovascular disease, diabetes, and chronic hepatitis B. Patients with advanced-stage disease were segregated by high EBV DNA levels and high hs-CRP level into a poorest-risk group, and participants with either high EBV DNA but low hs-CRP level or high hs-CRP but low EBV DNA values had poorer survival compared with the bottom values for both biomarkers. These findings demonstrate a significant improvement in the prognostic ability of conventional advanced NPC staging. Conclusion: Baseline plasma EBV DNA and serum hs-CRP levels were significantly correlated with survival in NPC patients. The combined interpretation of EBV DNA with hs-CRP levels led to refinement of the risks for the patient subsets, with improved risk discrimination in patients with advanced-stage disease.

  1. Certification for DOE P 456.1

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2014-10-02

    The Department of Energy (DOE) Policy 456.1, Secretarial Policy Statement on Nanoscale Safety, has been reviewed by HS and has been deemed to be in compliance with related Departmental Directives, Secretarial Delegations, organizational structure, budget guidelines, regulations, standards, Office of Management and Budget guidance, relevant Memoranda of Understanding, and public laws.

  2. Midea: Amended Noncompliance Determination (2010-SE-0110, 2012-SE-1402)

    Broader source: Energy.gov [DOE]

    DOE issued an Amended Notice of Noncompliance Determination to Midea America Corp., Hefei Hualing Co., Ltd., and China Refrigeration Industry Co., Ltd. finding that basic model HD-146F, a refrigerator-freezer, and basic model HS-390C, a freezer, do not comport with the energy conservation standards.

  3. Method of mechanical holding of cantilever chip for tip-scan high-speed atomic force microscope

    SciTech Connect (OSTI)

    Fukuda, Shingo; Uchihashi, Takayuki; Ando, Toshio

    2015-06-15

    In tip-scan atomic force microscopy (AFM) that scans a cantilever chip in the three dimensions, the chip body is held on the Z-scanner with a holder. However, this holding is not easy for high-speed (HS) AFM because the holder that should have a small mass has to be able to clamp the cantilever chip firmly without deteriorating the Z-scanners fast performance, and because repeated exchange of cantilever chips should not damage the Z-scanner. This is one of the reasons that tip-scan HS-AFM has not been established, despite its advantages over sample stage-scan HS-AFM. Here, we present a novel method of cantilever chip holding which meets all conditions required for tip-scan HS-AFM. The superior performance of this novel chip holding mechanism is demonstrated by imaging of the ?{sub 3}?{sub 3} subcomplex of F{sub 1}-ATPase in dynamic action at ?7 frames/s.

  4. DOE HQ Special Needs in an Emergency

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    T he in fo rm at io n m ay be ag gr eg at ed in to li st s, ch ar ts , an d or gr ap hs . In fo rm at io n pr ov id ed ne ed on ly de sc ri be th e ki nd of as si st an ce re qu ...

  5. arXiv:hep-th/0108076v2 20 Aug 2001

    Office of Scientific and Technical Information (OSTI)

    ... The proper area of the stable soliton is given by A AnJ p*Hs V 2n2N l2 s. (2.40) Thus ... Born-Infeld term is given by - dt (( de tG )l2G00Gl3dtA 3) + J + f F 12 + - 0. (2.51...

  6. AEC ADMIN Files

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    b 1 ; e n r d m d r n f n n t b n r k S U I t e h e u REQ*';T FOR ... All Cost-type Contractors CONG 21%; H*S AUTHORIZED SP;"?KIL w R P S W R K --I ...

  7. A=15N (1976AJ04)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for 15N) GENERAL: See also (1970AJ04) and Table 15.4 Table of Energy Levels (in PDF or PS) here. Shell model: (1968GO01, 1969UL03, 1970CO1H, 1970FR11, 1970GO1H, 1970HS02,...

  8. Program Information | National Nuclear Security Administration | (NNSA)

    National Nuclear Security Administration (NNSA)

    Program Information FY 2015 Performance Evaluation Plan (PEP) FY 2013 Performance Evaluation Report (PER) International Union, Security, Police and Fire Professionals of America Contract International Association of Machinists and Aerospace Workers Agreement HS&E Management System Description and Worker Safety and Health Program 2015 Small Business Program (FY 2009 - 2015); Link to FY 2014 Negotiated Subcontracting Goals with Agencies (including DOE)

  9. CX-010771: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Relocation of National and Homeland Security (N&HS) activities from Transient Reactor Experiment and Test Facility (TREAT) to Critical Infrastructure Test Range Complex (CITRC) CX(s) Applied: B1.15 Date: 07/30/2013 Location(s): Idaho Offices(s): Nuclear Energy

  10. Molecular assemblies as protective barriers and adhesion promotion interlayer

    DOE Patents [OSTI]

    King, David E.; Czanderna, Alvin W.; Kennedy, Cheryl E.

    1996-01-01

    A protective diffusion barrier having adhesive qualifies for metalized surfaces is provided by a passivating agent having the formula HS--(CH.sub.2).sub.11 --COOH Which forms a very dense, transparent organized molecular assembly or layer that is impervious to water, alkali, and other impurities and corrosive substances that typically attack metal surfaces.

  11. Molecular assemblies as protective barriers and adhesion promotion interlayer

    DOE Patents [OSTI]

    King, D.E.; Czanderna, A.W.; Kennedy, C.E.

    1996-01-30

    A protective diffusion barrier having adhesive qualities for metalized surfaces is provided by a passivating agent having the formula HS--(CH{sub 2}){sub 11}--COOH which forms a very dense, transparent organized molecular assembly or layer that is impervious to water, alkali, and other impurities and corrosive substances that typically attack metal surfaces. 8 figs.

  12. Licensing of spent fuel dry storage and consolidated rod storage: A Review of Issues and Experiences

    SciTech Connect (OSTI)

    Bailey, W.J.

    1990-02-01

    The results of this study, performed by Pacific Northwest Laboratory (PNL) and sponsored by the US Department of Energy (DOE), respond to the nuclear industry's recommendation that a report be prepared that collects and describes the licensing issues (and their resolutions) that confront a new applicant requesting approval from the US Nuclear Regulatory Commission (NRC) for dry storage of spent fuel or for large-scale storage of consolidated spent fuel rods in pools. The issues are identified in comments, questions, and requests from the NRC during its review of applicants' submittals. Included in the report are discussions of (1) the 18 topical reports on cask and module designs for dry storage fuel that have been submitted to the NRC, (2) the three license applications for dry storage of spent fuel at independent spent fuel storage installations (ISFSIs) that have been submitted to the NRC, and (3) the three applications (one of which was later withdrawn) for large-scale storage of consolidated fuel rods in existing spent fuel storage pools at reactors that were submitted tot he NRC. For each of the applications submitted, examples of some of the issues (and suggestions for their resolutions) are described. The issues and their resolutions are also covered in detail in an example in each of the three subject areas: (1) the application for the CASTOR V/21 dry spent fuel storage cask, (2) the application for the ISFSI for dry storage of spent fuel at Surry, and (3) the application for full-scale wet storage of consolidated spent fuel at Millstone-2. The conclusions in the report include examples of major issues that applicants have encountered. Recommendations for future applicants to follow are listed. 401 refs., 26 tabs.

  13. High-performance, low Pt content catalysts for the electroreduction of oxygen in polymer-electrolyte fuel cells

    SciTech Connect (OSTI)

    Fournier, J.; Faubert, G.; Tilquin, J.Y.; Cote, R.; Guay, D.; Dodelet, J.P.

    1997-01-01

    Pt-included and Pt-supported catalysts have been synthesized using graphite and carbon black supports of various specific areas. The graphites are KS6 (20 m{sup 2}/g), HS100 (110 m{sup 2}/g), and HS300 (305 m{sup 2}/g) from Lonza, and the carbon blacks are Vulcan (254 m{sup 2}/g) and Black Pearls (1475 m{sup 2}/g) from Cabot. The Pt-included and Pt-supported catalysts were used at the cathode of a H{sub 2}/O{sub 2} fuel cell, and their polarization curves were compared to each other and to those of various Pt-supported catalysts from E-TEK. In the high current region of interest to fuel cell developers, it is shown that Pt-supported catalysts perform better than Pt-included ones when the specific area of the support is small. The contrary is true when the specific area of the support is large. The best catalysts are HS300-Pti [8.3 weight percent (w/o) Pt included in HS300 graphite] and Vu-Pti (6.1 w/o Pt included in Vulcan XC-72R). These catalysts display very high mass and specific activities for O{sub 2} reduction. Furthermore, the iR-corrected polarization curves of both HS300-Pti (with a Pt loading of 0.110 mg/cm{sup 2}) and Vu-Pti (with a Pt loading of 0.070 mg/cm{sup 2}) cross at high current the polarization curve of the electrode prepared with E-TEK20 (20 w/o of supported Pt, with a Pt loading of 0.287 mg/cm{sup 2}). Pt inclusion in graphite or carbon black is therefore an interesting way of reducing the Pt loading of fuel cell cathodes without lowering electrochemical performance. HS300-Pti have been characterized by X-ray diffraction, transmission electron microscopy, and X-ray photoelectron spectroscopy. These analyses indicate that they both contain metallic Pt and Pt(II and IV) oxides and/or hydroxides.

  14. HORIZON SENSING

    SciTech Connect (OSTI)

    Larry G. Stolarczyk

    2003-03-18

    With the aid of a DOE grant (No. DE-FC26-01NT41050), Stolar Research Corporation (Stolar) developed the Horizon Sensor (HS) to distinguish between the different layers of a coal seam. Mounted on mining machine cutter drums, HS units can detect or sense the horizon between the coal seam and the roof and floor rock, providing the opportunity to accurately mine the section of the seam most desired. HS also enables accurate cutting of minimum height if that is the operator's objective. Often when cutting is done out-of-seam, the head-positioning function facilitates a fixed mining height to minimize dilution. With this technology, miners can still be at a remote location, yet cut only the clean coal, resulting in a much more efficient overall process. The objectives of this project were to demonstrate the feasibility of horizon sensing on mining machines and demonstrate that Horizon Sensing can allow coal to be cut cleaner and more efficiently. Stolar's primary goal was to develop the Horizon Sensor (HS) into an enabling technology for full or partial automation or ''agile mining''. This technical innovation (R&D 100 Award Winner) is quickly demonstrating improvements in productivity and miner safety at several prominent coal mines in the United States. In addition, the HS system can enable the cutting of cleaner coal. Stolar has driven the HS program on the philosophy that cutting cleaner coal means burning cleaner coal. The sensor, located inches from the cutting bits, is based upon the physics principles of a Resonant Microstrip Patch Antenna (RMPA). When it is in proximity of the rock-coal interface, the RMPA impedance varies depending on the thickness of uncut coal. The impedance is measured by the computer-controlled electronics and then sent by radio waves to the mining machine. The worker at the machine can read the data via a Graphical User Interface, displaying a color-coded image of the coal being cut, and direct the machine appropriately. The Horizon Sensor

  15. The effect of welding parameters on penetration in GTA welds

    SciTech Connect (OSTI)

    Shirali, A.A. ); Mills, K.C. )

    1993-07-01

    The effect of various welding parameters on the penetration of GTA welds has been investigated. Increases in welding speed were found to reduce penetration; however, increases in welding current were observed to increase the penetration in high sulfur (HS) casts and decrease penetration in low sulfur (LS) steels. Plots of penetration as a function of increasing linear energy (the heat supplied per unit length of weld) revealed a similar trend with increased penetration in HS casts, but the penetration in LS casts was unaffected by increases in linear energy. These results support the Burgardt-Heiple proposition that changes in welding parameters on penetration can be explained in terms of their effect, sequentially, on the temperature gradient and the Marangoni forces operating in the weld pool. Increases in arc length were found to decrease weld penetration regardless of the sulfur concentration of the steel, and the effects of electrode geometry and welding position on weld penetration were also investigated.

  16. A=10B (1974AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4AJ01) (See Energy Level Diagrams for 10B) GENERAL: See also (1966LA04) and Table 10.5 [Table of Energy Levels] (in PDF or PS). Shell model: (1961KO1A, 1965CO25, 1966HA18, 1966MA1P, 1966WI1E, 1967CO32, 1967EV1C, 1967HS1A, 1967PI1B, 1968GO01, 1969VA1C, 1970CO1H, 1971NO02, 1972LE1L, 1973HA49, 1973JO1K, 1973KU03, 1973SA30). Cluster and α-particle model: (1965NE1B, 1967TA1C, 1969BA1J, 1969HU1F, 1969NA1M, 1970NA06, 1971NO02, 1972LE1L, 1973KU03). Special levels: (1967CO32, 1967HS1A, 1968GO01,

  17. A=14N (1976AJ04)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    76AJ04) (See Energy Level Diagrams for 14N) GENERAL: See also (1970AJ04) and Table 14.11 [Table of Energy Levels] (in PDF or PS). Shell model: (1970CO1H, 1970FR13, 1970HS02, 1970UL01, 1971NO02, 1972LE1L, 1972LI06, 1973IG02, 1973KU03, 1973SA30, 1974KI1B, 1975DI04, 1975MI12, 1975VE01). Collective and deformed models: (1972LA12). Cluster model: (1969BA1J, 1969KU1B, 1970KO26, 1971NO02, 1972LE1L, 1973KU03, 1975CH1V). Special levels: (1969HA1F, 1971HS05, 1971JA13, 1971MC15, 1971NO02, 1972LA12,

  18. Volovik effect and Fermi-liquid behavior in the s-wave superconductor CaPd2As2: As75 NMR-NQR measurements

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ding, Q. -P.; Wiecki, P.; Anand, V. K.; Sangeetha, N. S.; Lee, Y.; Johnston, D. C.; Furukawa, Y.

    2016-04-07

    The electronic and magnetic properties of the collapsed-tetragonal CaPd2As2 superconductor (SC) with a transition temperature of 1.27 K have been investigated by 75As nuclear magnetic resonance (NMR) and nuclear quadrupole resonance (NQR) measurements. The temperature (T) dependence of the nuclear spin lattice relaxation rates (1/T1) and the Knight shifts indicate the absence of magnetic correlations in the normal state. In the SC state, 1/T1 measured by 75As NQR shows a clear Hebel-Slichter (HS) peak just below Tc and decreases exponentially at lower T, confirming a conventional s-wave SC. Additionally, the Volovik effect, also known as the Doppler shift effect, hasmore » been clearly evidenced by the observation of the suppression of the HS peak with applied magnetic field.« less

  19. Quality Assurance Plan for Heat Source/Radioisotope Thermoelectric Generator Programs

    SciTech Connect (OSTI)

    Gabriel, D. M.; Miller, G. D.; Bohne, W. A.

    1995-03-16

    The purpose of this document is to serve as the Quality Assurance Plan for Heat Source/Radioisotope Thermoelectric Generator (HS/RTG) programs performed at EG&G Mound Applied Technologies. As such, it identifies and describes the systems and activities in place to support the requirements contained in DOE Order 5700.6C as reflected in MD-10334, Mound Quality Policy and Responsibilities and the DOE/RPSD supplement, OSA/PQAR-1, Programmatic Quality Assurance Requirements for Space and Terrestrial Nuclear Power Systems. Unique program requirements, including additions, modifications, and exceptions to these quality requirements, are contained in the appendices of this plan. Additional appendices will be added as new programs and activities are added to Mound's HS/RTG mission assignment.

  20. The New Era: NOCs Reach Out for Resources Bob Fryklund, IHS Energy

    U.S. Energy Information Administration (EIA) Indexed Site

    supply and market impacts of US unconventional oil production growth Andrew Slaughter, Vice-President, Energy Insight, IHS Presentation to EIA 2013 Energy Conference June 18 th 2013 Washington, DC CONFIDENTIAL © 2013, All rights reserved, IHS CERA., 55 Cambridge Parkway, Cambridge, Massachusetts 02142 No portion of this presentation may be reproduced, reused or otherwise distributed in any form without prior written consent. Copyright © 2013HS Inc. All Rights Reserved. 1 Today's Themes * US

  1. HORIZON SENSING (PROPOSAL NO.51)

    SciTech Connect (OSTI)

    Larry G. Stolarczyk

    2003-07-01

    Real-time horizon sensing on continuous mining machines is becoming an industry tool. Installation and testing of production-grade Horizon Sensor (HS) systems continued this quarter at Monterey Coal Company (ExxonMobil), Mountain Coal Company West Elk Mine (Arch), and Ohio Valley Coal Company (OVC). Monitoring of system function, user experience, and mining benefits is ongoing. All horizon sensor components have finished MSHA (U.S.) and IEC (International) certification.

  2. BIOENERGIZEME INFOGRAPHIC CHALLENGE: Algae Biofuel | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Algae Biofuel BIOENERGIZEME INFOGRAPHIC CHALLENGE: Algae Biofuel BIOENERGIZEME INFOGRAPHIC CHALLENGE: Algae Biofuel This infographic was created by students from Seward HS in Seward, AK, as part of the U.S. Department of Energy-BioenergizeME Infographic Challenge. The BioenergizeME Infographic Challenge encourages young people to improve their foundational understanding of bioenergy, which is a broad and complex topic. The ideas expressed in these infographics reflect where students are in the

  3. Midea: Order (2010-SE-0110, 2012-SE-1402, 2012-SE-1404, 2013-SE-1401)

    Broader source: Energy.gov [DOE]

    DOE ordered Midea America Corp., Hefei Hualing Co., Ltd., and China Refrigeration Industry Co., Ltd., to pay a $4,579,949 ($4,562,838 plus one percent interest) civil penalty after finding Midea had manufactured and distributed in commerce in the U.S. a large quantity of basic models HD-146F, HS-390C, UL-WD145-D, and UL-WD195-D of noncompliant refrigerator-freezers and freezers.

  4. HORIZON SENSING (PROPOSAL NO.51)

    SciTech Connect (OSTI)

    Larry G. Stolarczyk

    2003-07-30

    Real-time horizon sensing on continuous mining (CM) machines is becoming an industry tool. Installation and testing of production-grade Horizon Sensor (HS) systems has been ongoing this quarter at Monterey Coal Company (ExxonMobil), Mountain Coal Company West Elk Mine (Arch), Deserado Mining Company (Blue Mountain Energy), and The Ohio Valley Coal Company (TOVCC). Monitoring of system function, user experience, and mining benefits is ongoing. All horizon sensor components have finished MSHA (U.S.) and IEC (International) certification.

  5. HORIZON SENSING (PROPOSAL No.51)

    SciTech Connect (OSTI)

    Larry G. Stolarczyk, Sc.D.

    2002-04-30

    Real-time horizon sensing on continuous mining machines is becoming an industry tool. Installation and testing of production-grade HS systems has been ongoing this quarter at Monterey Coal Company (EXXON), FMC Trona, Twentymile Coal Company (RAG America), and SASOL Coal. Detailed monitoring of system function, user experience, and mining benefits is ongoing. All horizon sensor components have finished MSHA (U.S.) and IEC (International) certification.

  6. ORISE: ORISE is accepting applications for the 2015 U.S. Department of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Homeland Security Summer Internship Program U.S. Department of Homeland Security Summer Internship Program Program represents opportunity for students to perform research at federal facilities located across the U.S. FOR IMMEDIATE RELEASE Nov. 20, 2014 FY15-04 OAK RIDGE, Tenn.-ORISE is currently accepting applications for the 2015 U.S. Department of Homeland Security HS-STEM Summer Internship Program, which is a 10-week summer internship program for students majoring in homeland

  7. A moist aquaplanet variant of the HeldSuarez test for atmospheric model dynamical cores

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Thatcher, D. R.; Jablonowski, C.

    2015-09-29

    A moist idealized test case (MITC) for atmospheric model dynamical cores is presented. The MITC is based on the HeldSuarez (HS) test that was developed for dry simulations on a flat Earth and replaces the full physical parameterization package with a Newtonian temperature relaxation and Rayleigh damping of the low-level winds. This new variant of the HS test includes moisture and thereby sheds light on the non-linear dynamics-physics moisture feedbacks without the complexity of full physics parameterization packages. In particular, it adds simplified moist processes to the HS forcing to model large-scale condensation, boundary layer mixing, and the exchange ofmorelatent and sensible heat between the atmospheric surface and an ocean-covered planet. Using a variety of dynamical cores of NCAR's Community Atmosphere Model (CAM), this paper demonstrates that the inclusion of the moist idealized physics package leads to climatic states that closely resemble aquaplanet simulations with complex physical parameterizations. This establishes that the MITC approach generates reasonable atmospheric circulations and can be used for a broad range of scientific investigations. This paper provides examples of two application areas. First, the test case reveals the characteristics of the physics-dynamics coupling technique and reproduces coupling issues seen in full-physics simulations. In particular, it is shown that sudden adjustments of the prognostic fields due to moist physics tendencies can trigger undesirable large-scale gravity waves, which can be remedied by a more gradual application of the physical forcing. Second, the moist idealized test case can be used to intercompare dynamical cores. These examples demonstrate the versatility of the MITC approach and suggestions are made for further application areas. The new moist variant of the HS test can be considered a test case of intermediate complexity.less

  8. A moist aquaplanet variant of the Held–Suarez test for atmospheric model dynamical cores

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Thatcher, Diana R.; Jablonowski, Christiane

    2016-04-04

    A moist idealized test case (MITC) for atmospheric model dynamical cores is presented. The MITC is based on the Held–Suarez (HS) test that was developed for dry simulations on “a flat Earth” and replaces the full physical parameterization package with a Newtonian temperature relaxation and Rayleigh damping of the low-level winds. This new variant of the HS test includes moisture and thereby sheds light on the nonlinear dynamics–physics moisture feedbacks without the complexity of full-physics parameterization packages. In particular, it adds simplified moist processes to the HS forcing to model large-scale condensation, boundary-layer mixing, and the exchange of latent and sensible heat betweenmore » the atmospheric surface and an ocean-covered planet. Using a variety of dynamical cores of the National Center for Atmospheric Research (NCAR)'s Community Atmosphere Model (CAM), this paper demonstrates that the inclusion of the moist idealized physics package leads to climatic states that closely resemble aquaplanet simulations with complex physical parameterizations. This establishes that the MITC approach generates reasonable atmospheric circulations and can be used for a broad range of scientific investigations. This paper provides examples of two application areas. First, the test case reveals the characteristics of the physics–dynamics coupling technique and reproduces coupling issues seen in full-physics simulations. In particular, it is shown that sudden adjustments of the prognostic fields due to moist physics tendencies can trigger undesirable large-scale gravity waves, which can be remedied by a more gradual application of the physical forcing. Second, the moist idealized test case can be used to intercompare dynamical cores. These examples demonstrate the versatility of the MITC approach and suggestions are made for further application areas. The new moist variant of the HS test can be considered a test case of intermediate complexity.« less

  9. Office of Inspector General report on audit of shutdown and transition of the Mound Plant

    SciTech Connect (OSTI)

    1997-06-24

    With the end of the Cold War, the Department of Energy (Department) has greatly reduced the production of nuclear weapons and redirected the capabilities and focus of the weapons complex. As part of this redirection, the Mound Plant was transferred from a Defense Program site to an Environmental Management site with emphasis on accelerated cleanup and transition of facilities and personal property to the local community. This audit was initiated to determine if the shutdown and transition of the Mound Plant was progressing effectively and efficiently. The Department prepared a Nonnuclear Consolidation Plan (NCP) designed to reduce its costs of operation by closing and consolidating facilities. In contrast to the goal of the NCP, the Department plans to keep a portion of the Mound Plant open solely to perform work for other Federal agencies. Specifically, the Department has decided to continue assembling and testing isotopic heat sources and radioisotope thermoelectric generators (HS/RTG) at the Mound Plant despite the transfer or planned transfer of all other production operations.The Office of Nuclear Energy, Science and Technology decided to continue its HS/RTG operations at the Mound Plant without adequately considering the overall economic goals of the Department. As a result, the Department may not achieve the savings envisioned by the NCP. Also, the Department may incur between $4 million and $8.5 million more than necessary each year to continue its HS/RTG operations at the Mound Plant. Additionally, if the HS/RTG operations stay at the Mound Plant, the Department will spend more than $3 million to consolidate these operations into one location.

  10. Independent Activity Report, Los Alamos National Laboratory - April 2013 |

    Office of Environmental Management (EM)

    February 2013 | Department of Energy February 2013 Independent Activity Report, Lawrence Livermore National Laboratory - February 2013 February 2013 Lawrence Livermore National Laboratory Operational Drill at the B332 Plutonium Facility [HIAR LLNL-2013-02-27] The Livermore Site Office (LSO) and Lawrence Livermore National Security, LLC (LLNS) requested personnel from the U.S. Department of Energy (DOE) Office of Safety and Emergency Management Evaluations (HS-45) to observe an operational

  11. Scanning ARM Cloud Radars Part I: Operational Sampling Strategies

    SciTech Connect (OSTI)

    Kollias, Pavlos; Bharadwaj, Nitin; Widener, Kevin B.; Jo, Ieng; Johnson, Karen

    2014-03-01

    Probing clouds in three-dimensions has never been done with scanning millimeter-wavelength (cloud) radars in a continuous operating environment. The acquisition of scanning cloud radars by the Atmospheric Radiation Measurement (ARM) program and research institutions around the world generate the need for developing operational scan strategies for cloud radars. Here, the first generation of sampling strategies for the Scanning ARM Cloud Radars (SACRs) is discussed. These scan strategies are designed to address the scientific objectives of the ARM program, however, they introduce an initial framework for operational scanning cloud radars. While the weather community uses scan strategies that are based on a sequence of scans at constant elevations, the SACRs scan strategies are based on a sequence of scans at constant azimuth. This is attributed to the cloud properties that are vastly different for rain and snow shafts that are the primary target of precipitation radars. A cloud surveillance scan strategy is introduced (HS-RHI) based on a sequence of horizon-to-horizon Range Height Indicator (RHI) scans that sample the hemispherical sky (HS). The HS-RHI scan strategy is repeated every 30 min to provide a static view of the cloud conditions around the SACR location. Between HS-RHI scan strategies other scan strategies are introduced depending on the cloud conditions. The SACRs are pointing vertically in the case of measurable precipitation at the ground. The radar reflectivities are corrected for water vapor attenuation and non-meteorological detection are removed. A hydrometeor detection mask is introduced based on the difference of cloud and noise statistics is discussed.

  12. DOE F 1300.5 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    5 DOE F 1300.5 Form used by DOE Technical Standards Program Office, Office of Nuclear Safety Policy and Assistance (HS-21) to track project information. PROJECT REGISTRATION AND APPROVAL REQUEST (36.9 KB) More Documents & Publications DOE-TSPP-4, Registering a Technical Standard Project - July 1, 2009 REGISTERING A TECHNICAL STANDARD PROJECT DOE-TSPP-1, Technical Standards Program Responsibilities - July 1, 2009

  13. DOE Sustainability Support Information Brief on Executive Order 12898,

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Federal Actions to Address Environmental Justice in Minority and Low-Income Populations | Department of Energy DOE Sustainability Support Information Brief on Executive Order 12898, Federal Actions to Address Environmental Justice in Minority and Low-Income Populations DOE Sustainability Support Information Brief on Executive Order 12898, Federal Actions to Address Environmental Justice in Minority and Low-Income Populations November, 2012 HS-21-IB-2012-28 This Sustainability Support

  14. Identifying, Implementing and Complying with Environment, Safety and Health Requirements

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1996-05-15

    This Policy sets forth the framework for identifying, implementing and complying with environment, safety and health (ES&H) requirements so that work is performed in the DOE complex in a manner that ensures adequate protection of workers, the public and the environment. Ownership of this policy is shared between GC and HS. Cancels DOE P 450.2. Canceled by DOE P 450.4A.

  15. Cisco Systems Funds "Whisker" Growth Research at the ALS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cisco Systems Funds "Whisker" Growth Research at the ALS Print Lead-free components have been increasingly used in electronics manufacturing since the European Union passed its 2003 Restriction of Hazardous Substances Directive (RoHS), which banned the use of certain hazardous materials in electrical and electronic equipment. To ensure the long-term reliability of mission-critical equipment such as networking hardware, a significant amount of research and development must be undertaken

  16. High School Co-op Program Salary Structure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Salary Structure High School Co-op Program Salary Structure Point your career towards Los Alamos Lab: work with the best minds on the planet in an inclusive environment that is rich in intellectual vitality and opportunities for growth. Contact Student Programs (505) 667-4866 Email High school internship program salary structure Program Description Yearly Hourly High school intern High school senior $21,320/yr $10.25/hr Post HS graduate High school graduate (limited to 90-day appointment)

  17. 2016 Annual Workforce Analysis and Staffing Plan Report - DOE Oak Ridge Office of Environmental Management

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (4193) United States Government Department of Energy Oak Ridge Office of Environmental Management memorandum DATE: January 19, 2016 REPLY TO ATTN OF: EM-90:Cange SUBJECT: 2015 OAK RIDGE OFFICE OF ENVIRONMENTAL MANAGEMENT ANNUAL WORKFORCE ANALYSIS AND STAFFING PLAN TO: Karen L. Boardman, Chairperson, Federal Technical Capability Panel, HS-70 The Oak Ridge Office of Environmental Management (OREM) has produced the required OREM Annual Workforce Analysis and Staffing Plan. The attached report

  18. Suspect/Counterfeit Item Awareness Training Manual

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Suspect/Counterfeit Items Awareness Training U.S. Department of Energy Health, Safety and Security Office of Corporate Safety Analysis This training document is in the process of being revised by the Office of Analysis (HS-24) through a partnership with the Energy Facility Contractors Group. In the interim, the Suspect/ Counterfeit Headmark List (page 11) has been updated with the most current version. June 2007 Revision 6 Suspect/Counterfeit Items Training Sponsored by the Office of Analysis

  19. Kevin Banks | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Kevin Banks By Justin H.S. Breaux * October 6, 2014 Tweet EmailPrint Kevin Banks is a freshman at the Milwaukee School of Engineering, where he studies biomedical engineering. As an intern within the Chicago Scholars Argonne Future Research Program, Kevin conducted research this summer in Argonne's Energy Systems division. His research seeks to increase energy efficiency by reducing friction and wear on machines using engine oils. "What I liked most about my internship experience was

  20. A moist aquaplanet variant of the Held–Suarez test for atmospheric model dynamical cores

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Thatcher, Diana R.; Jablonowski, Christiane

    2016-04-04

    A moist idealized test case (MITC) for atmospheric model dynamical cores is presented. The MITC is based on the Held–Suarez (HS) test that was developed for dry simulations on “a flat Earth” and replaces the full physical parameterization package with a Newtonian temperature relaxation and Rayleigh damping of the low-level winds. This new variant of the HS test includes moisture and thereby sheds light on the nonlinear dynamics–physics moisture feedbacks without the complexity of full-physics parameterization packages. In particular, it adds simplified moist processes to the HS forcing to model large-scale condensation, boundary-layer mixing, and the exchange of latent and sensible heat betweenmore » the atmospheric surface and an ocean-covered planet. Using a variety of dynamical cores of the National Center for Atmospheric Research (NCAR)'s Community Atmosphere Model (CAM), this paper demonstrates that the inclusion of the moist idealized physics package leads to climatic states that closely resemble aquaplanet simulations with complex physical parameterizations. This establishes that the MITC approach generates reasonable atmospheric circulations and can be used for a broad range of scientific investigations. This paper provides examples of two application areas. First, the test case reveals the characteristics of the physics–dynamics coupling technique and reproduces coupling issues seen in full-physics simulations. In particular, it is shown that sudden adjustments of the prognostic fields due to moist physics tendencies can trigger undesirable large-scale gravity waves, which can be remedied by a more gradual application of the physical forcing. Second, the moist idealized test case can be used to intercompare dynamical cores. These examples demonstrate the versatility of the MITC approach and suggestions are made for further application areas. Furthermore, the new moist variant of the HS test can be considered a test case of intermediate

  1. Publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Model Verification and Validation Model Verification and Validation Publications Publications are organized by topic. Contact Institute Director Charles Farrar (505) 663-5330 Email UCSD EI Director Michael Todd (858) 534-5951 Professional Staff Assistant Jutta Kayser (505) 663-5649 Email Administrative Assistant Stacy Baker (505) 663-5233 Email Decision-Making for Science-Based Predictive Modeling Atamturktur, H.S., Egeberg, M.C., Hemez, F.M., Stevens, G.N., "Defining Coverage of an

  2. DATE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    09-003 SECTION A. Project Title: Removal of Central Facilities Area (CFA)-661 Interior Walls and Mezzanine. SECTION B. Project Description The initial action to be covered under this Environmental Checklist will be removal of the mezzanines from CFA-661 to provide for material storage and work space for the National and Homeland Security (N&HS) Wireless Test Bed project. More specifically, this involves storage of electronic equipment, antennas and antenna masts, personnel supplies, and a

  3. Health, Safety & Environment System Description and Worker Safety & Health Program

    National Nuclear Security Administration (NNSA)

    FY2015 HEALTH, SAFETY AND ENVIRONMENT MANAGEMENT SYSTEM DESCRIPTION and WORKER SAFETY & HEALTH PROGRAM Honeywell Federal Manufacturing & Technologies HS&E Management System Description 1 Honeywell Approval: KCFO Approval: Original Signed by Don Fitzpatrick 8/27/14 Original Signed by Sherry Kinsey-Cannon 8/27/14 Donald J. Fitzpatrick, Director Date Sherry Kinsey-Cannon, Date HSE&F Acting Assistant Manager Office of Operations KCFO Worker Safety & Health Program 2 Honeywell

  4. July 2012, HSS Focus Group Strategic Initiatives Work Group - Status Overviews

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Strategic Initiatives Work Group Status Overview Accomplishments: 1. June 26. Telecom with USW - Informative near-miss occurrence reporting. 2. June 29. HS-24 finalized and released the Injury and Illness Dashboard. Near Term Goals/Activities: 1. Work Group meeting to be scheduled - address union-expressed issues related to under reporting/near miss reporting; presentation of Injury and Illness Dashboard tool. 2. Work Group action plan to be further developed based on the meeting discussion.

  5. July 2012, Work Force Retention Work Group Status Overview

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Work Force Retention Work Group Status Overview Accomplishments: 1. Progress on the completion of the 10 CFR 1046 modifications to address barriers to workforce retention. Written response to public comment is being drafted by HS-51. 2. Pro-Force (PF) union representative, Randy Lawson, identified this accomplishment as the single most significant step toward PF workforce retention in over 20 years. 3. Draft re-charter of PF Career Options Committee (PFCOC) to establish a PF Working Group

  6. June 11, 2009, HSS/Union Task Meeting on 2009 HSS/Union Task Progress - 2009 inspection schedule

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    9/09 Office of Independent Oversight Office of Environment, Safety, and Health Evaluations (HS-64) Inspection Schedule CY 2009 Site Inspection Activity Date Lawrence Berkeley National Laboratory ES&H Inspection * Scoping visit * Planning (onsite) * Planning (offsite) * Data collection visit * Analysis & Report Writing * Validation and closeout December 3-4 (2008) January 5-9 (2009) January 21-23 January 26 - February 6 February 9-20 February 24-26 (SC) Pacific Northwest National

  7. June 11, 2009, HSS/Union Task Meeting on 2009 HSS/Union Task Progress - Task Leads Schedule

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    05-09 TASK PLAN/SCHEDULE I. TRAINING REQUIREMENTS A. Identify basic DOE site access requirements [Leads: NTC/SMWIA/HS-10] What are the common general training requirements necessary to work at DOE sites. Jul 09 - Oct 09 1. Collect data from existing resources; research successful models, determine application to DOE 2. Compare NTC site visit results 3. Develop general requirements findings proposal and a matrix of recommended coursework Dec 09 4. Identify process for

  8. Independent Activity Report, Lawrence Livermore National Laboratory -

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    February 2013 | Department of Energy February 2013 Independent Activity Report, Lawrence Livermore National Laboratory - February 2013 February 2013 Lawrence Livermore National Laboratory Operational Drill at the B332 Plutonium Facility [HIAR LLNL-2013-02-27] The Livermore Site Office (LSO) and Lawrence Livermore National Security, LLC (LLNS) requested personnel from the U.S. Department of Energy (DOE) Office of Safety and Emergency Management Evaluations (HS-45) to observe an operational

  9. Sorption of carboxylic acid from carboxylic salt solutions at PHS close to or above the pK.sub.a of the acid, with regeneration with an aqueous solution of ammonia or low-molecular-weight alkylamine

    DOE Patents [OSTI]

    King, C. Judson; Tung, Lisa A.

    1992-01-01

    Carboxylic acids are sorbed from aqueous feedstocks at pHs close to or above the acids' pH.sub.a into a strongly basic organic liquid phase or onto a basic solid adsorbent or moderately basic ion exchange resin. the acids are freed from the sorbent phase by treating it with aqueous alkylamine or ammonia thus forming an alkylammonium or ammonium carobxylate which dewatered and decomposed to the desired carboxylic acid and the alkylamine or ammonia.

  10. Conference shows high school girls their scientific future | Argonne

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    National Laboratory J'Tia Taylor (left), a nonproliferation technical specialist in Argonne's Nuclear Engineering Division, speaks with event attendees. Click to enlarge. J'Tia Taylor (left), a nonproliferation technical specialist in Argonne's Nuclear Engineering Division, speaks with event attendees. Click to enlarge. Conference shows high school girls their scientific future By Justin H.S. Breaux * April 7, 2014 Tweet EmailPrint ARGONNE, Ill. - Nearly 400 high school girls from the

  11. Coupling MM5 with ISOLSM:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Yun (Helen) He 1 Coupling MM5 with ISOLSM: Development, Testing, and Application W.J. Riley, H.S. Cooley, Y. He*, M.S. Torn Lawrence Berkeley National Laboratory June 2003 Yun (Helen) He 2 Outline ! Introduction ! Model Integration ! Model Configuration ! Model Testing ! Simulation and Impacts of Winter Wheat Harvest ! Conclusions ! Observations and Future Work June 2003 Yun (Helen) He 3 Introduction ! CO 2 fluxes and other trace-gas exchanges are tightly coupled to the surface water and energy

  12. Characterization of a Y-Family DNA Polymerase eta from the Eukaryotic ThermophileAlvinella pompejana

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kashiwagi, Sayo; Kuraoka, Isao; Fujiwara, Yoshie; Hitomi, Kenichi; Cheng, Quen J.; Fuss, Jill O.; Shin, David S.; Masutani, Chikahide; Tainer, John A.; Hanaoka, Fumio; et al

    2010-01-01

    Human DNA polymerase?(HsPol?) plays an important role in translesion synthesis (TLS), which allows for replication past DNA damage such as UV-inducedcis-syncyclobutane pyrimidine dimers (CPDs). Here, we characterized ApPol?from the thermophilic wormAlvinella pompejana, which inhabits deep-sea hydrothermal vent chimneys. ApPol?shares sequence homology with HsPol?and contains domains for binding ubiquitin and proliferating cell nuclear antigen. Sun-induced UV does not penetrateAlvinella'senvironment; however, this novel DNA polymerase catalyzed efficient and accurate TLS past CPD, as well as 7,8-dihydro-8-oxoguanine and isomers of thymine glycol induced by reactive oxygen species. In addition, we found that ApPol?is more thermostable than HsPol?, as expected from its habitat temperature.moreMoreover, the activity of this enzyme was retained in the presence of a higher concentration of organic solvents. Therefore, ApPol?provides a robust, human-like Pol?that is more active after exposure to high temperatures and organic solvents.less

  13. Electronic structure of the ingredient planes of the cuprate superconductor Bi2Sr2CuO6+δ: A comparison study with Bi2Sr2CaCu2O8+δ

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yan -Feng Lv; Gu, G. D.; Wang, Wen -Lin; Ding, Hao; Wang, Yang; Ding, Ying; Zhong, Ruidan; Schneeloch, John; Wang, Lili; He, Ke; et al

    2016-04-15

    By means of low-temperature scanning tunneling microscopy, we report on the electronic structures of the BiO and SrO planes of the Bi2Sr2CuO6+δ (Bi-2201) superconductor prepared by argon-ion bombardment and annealing. Depending on post annealing conditions, the BiO planes exhibit either a pseudogap (PG) with sharp coherence peaks and an anomalously large gap magnitude of 49 meV or van Hove singularity (vHS) near the Fermi level, while the SrO is always characteristic of a PG-like feature. This contrasts with the Bi2Sr2CaCu2O8+δ (Bi-2212) superconductor where vHS occurs solely on the SrO plane. We disclose the interstitial oxygen dopants (δ in the formulas)more » as a primary cause for the occurrence of vHS, which are located dominantly around the BiO and SrO planes, respectively, in Bi-2201 and Bi-2212. This is supported by the contrasting structural buckling amplitude of the BiO and SrO planes in the two superconductors. Furthermore, our findings provide solid evidence for the irrelevance of PG to the superconductivity in the two superconductors, as well as insights into why Bi-2212 can achieve a higher superconducting transition temperature than Bi-2201, and by implication, the mechanism of cuprate superconductivity.« less

  14. Free Energy Calculations of Crystalline Hard Sphere Complexes Using Density Functional Theory

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gunawardana, K. G.S.H.; Song, Xueyu

    2014-12-22

    Recently developed fundamental measure density functional theory (FMT) is used to study binary hard sphere (HS) complexes in crystalline phases. By comparing the excess free energy, pressure and phase diagram, we show that the fundamental measure functional yields good agreements to the available simulation results of AB, AB2 and AB13 crystals. Additionally, we use this functional to study the HS models of five binary crystals, Cu5Zr(C15b), Cu51Zr14(β), Cu10Zr7(φ), CuZr(B2) and CuZr2 (C11b), which are observed in the Cu-Zr system. The FMT functional gives well behaved minimum for most of the hard sphere crystal complexes in the two dimensional Gaussian space,more » namely a crystalline phase. However, the current version of FMT functional (white Bear) fails to give a stable minimum for the structure Cu10Zr7(φ). We argue that the observed solid phases for the HS models of the Cu-Zr system are true thermodynamic stable phases and can be used as a reference system in perturbation calculations.« less

  15. Free Energy Calculations of Crystalline Hard Sphere Complexes Using Density Functional Theory

    SciTech Connect (OSTI)

    Gunawardana, K. G.S.H.; Song, Xueyu

    2014-12-22

    Recently developed fundamental measure density functional theory (FMT) is used to study binary hard sphere (HS) complexes in crystalline phases. By comparing the excess free energy, pressure and phase diagram, we show that the fundamental measure functional yields good agreements to the available simulation results of AB, AB2 and AB13 crystals. Additionally, we use this functional to study the HS models of five binary crystals, Cu5Zr(C15b), Cu51Zr14(?), Cu10Zr7(?), CuZr(B2) and CuZr2 (C11b), which are observed in the Cu-Zr system. The FMT functional gives well behaved minimum for most of the hard sphere crystal complexes in the two dimensional Gaussian space, namely a crystalline phase. However, the current version of FMT functional (white Bear) fails to give a stable minimum for the structure Cu10Zr7(?). We argue that the observed solid phases for the HS models of the Cu-Zr system are true thermodynamic stable phases and can be used as a reference system in perturbation calculations.

  16. Characterization of a Y-Family DNA Polymerase eta from the Eukaryotic Thermophile Alvinella pompejana

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kashiwagi, Sayo; Kuraoka, Isao; Fujiwara, Yoshie; Hitomi, Kenichi; Cheng, Quen J.; Fuss, Jill O.; Shin, David S.; Masutani, Chikahide; Tainer, John A.; Hanaoka, Fumio; et al

    2010-01-01

    Humore » man DNA polymerase η (HsPol η ) plays an important role in translesion synthesis (TLS), which allows for replication past DNA damage such as UV-induced cis-syn cyclobutane pyrimidine dimers (CPDs). Here, we characterized ApPol η from the thermophilic worm Alvinella pompejana , which inhabits deep-sea hydrothermal vent chimneys. ApPol η shares sequence homology with HsPol η and contains domains for binding ubiquitin and proliferating cell nuclear antigen. Sun-induced UV does not penetrate Alvinella's environment; however, this novel DNA polymerase catalyzed efficient and accurate TLS past CPD, as well as 7,8-dihydro-8-oxoguanine and isomers of thymine glycol induced by reactive oxygen species. In addition, we found that ApPol η is more thermostable than HsPol η , as expected from its habitat temperature. Moreover, the activity of this enzyme was retained in the presence of a higher concentration of organic solvents. Therefore, ApPol η provides a robust, human-like Pol η that is more active after exposure to high temperatures and organic solvents.« less

  17. Joint spatio-spectral based edge detection for multispectral infrared imagery.

    SciTech Connect (OSTI)

    Krishna, Sanjay; Hayat, Majeed M.; Bender, Steven C.; Sharma, Yagya D.; Jang, Woo-Yong; Paskalva, Biliana S.

    2010-06-01

    Image segmentation is one of the most important and difficult tasks in digital image processing. It represents a key stage of automated image analysis and interpretation. Segmentation algorithms for gray-scale images utilize basic properties of intensity values such as discontinuity and similarity. However, it is possible to enhance edge-detection capability by means of using spectral information provided by multispectral (MS) or hyperspectral (HS) imagery. In this paper we consider image segmentation algorithms for multispectral images with particular emphasis on detection of multi-color or multispectral edges. More specifically, we report on an algorithm for joint spatio-spectral (JSS) edge detection. By joint we mean simultaneous utilization of spatial and spectral characteristics of a given MS or HS image. The JSS-based edge-detection approach, termed Spectral Ratio Contrast (SRC) edge-detection algorithm, utilizes the novel concept of matching edge signatures. The edge signature represents a combination of spectral ratios calculated using bands that enhance the spectral contrast between the two materials. In conjunction with a spatial mask, the edge signature give rise to a multispectral operator that can be viewed as a three-dimensional extension of the mask. In the extended mask, the third (spectral) dimension of each hyper-pixel can be chosen independently. The SRC is verified using MS and HS imagery from a quantum-dot in a well infrared (IR) focal plane array, and the Airborne Hyperspectral Imager.

  18. The distribution of an illustrated timeline wall chart and teacher's guide of 20th century physics

    SciTech Connect (OSTI)

    Schwartz, Brian

    2000-12-26

    The American Physical Society's part of its centennial celebration in March of 1999 decided to develop a timeline wall chart on the history of 20th century physics. This resulted in eleven consecutive posters, which when mounted side by side, create a 23-foot mural. The timeline exhibits and describes the millstones of physics in images and words. The timeline functions as a chronology, a work of art, a permanent open textbook, and a gigantic photo album covering a hundred years in the life of the community of physicists and the existence of the American Physical Society. Each of the eleven posters begins with a brief essay that places a major scientific achievement of the decade in its historical context. Large portraits of the essays' subjects include youthful photographs of Marie Curie, Albert Einstein, and Richard Feynman among others, to help put a face on science. Below the essays, a total of over 130 individual discoveries and inventions, explained in dated text boxes with accompanying images, form the backbone of the timeline. For ease of comprehension, this wealth of material is organized into five color-coded story lines the stretch horizontally across the hundred years of the 20th century. The five story lines are: Cosmic Scale, relate the story of astrophysics and cosmology; Human Scale, refers to the physics of the more familiar distances from the global to the microscopic; Atomic Scale, focuses on the submicroscopic world of atoms, nuclei and quarks; Living World, chronicles the interaction of physics with biology and medicine; Technology, traces the applications of physic to everyday living. Woven into the bottom border of the timeline are period images of significant works of art, architecture, and technological artifacts such as telephones, automobiles, aircraft, computers, and appliances. The last poster, covering the years since 1995, differs from the others. Its essay concerns the prospect for physics into the next century, and is illustrated

  19. Atherosclerosis induced by arsenic in drinking water in rats through altering lipid metabolism

    SciTech Connect (OSTI)

    Cheng, Tain-Junn; Chuu, Jiunn-Jye; Chang, Chia-Yu; Tsai, Wan-Chen; Chen, Kuan-Jung; Guo, How-Ran

    2011-10-15

    Arsenic in drinking water is a global environmental health problem, and the exposure may increase cardiovascular and cerebrovascular diseases mortalities, most likely through causing atherosclerosis. However, the mechanism of atherosclerosis formation after arsenic exposure is still unclear. To study the mechanism of atherosclerosis formation after arsenic exposure and explore the role of high cholesterol diet (HCD) in this process, we fed spontaneous hypertensive rats and Wistar Kyoto rats with basal diet or HCD and provided with them drinking water containing arsenic at different ages and orders for 20 consecutive weeks. We measured high density lipoprotein cholesterol (HDL-C), low density lipoprotein cholesterol (LDL-C), total cholesterol, triglycerides, heat shock protein 70 (HSP 70), and high sensitive C-reactive protein (hs-CRP) at predetermined intervals and determined expressions of cholesteryl ester transfer protein-1 (CETP-1) and liver X receptor {beta} (LXR{beta}) in the liver. Atherosclerosis was determined by examining the aorta with hematoxylin and eosin stain. After 20 weeks, we found arsenic, alone or combined with HCD, may promote atherosclerosis formation with transient increases in HSP 70 and hs-CRP. Early combination exposure decreased the HDL-C/LDL-C ratio without changing the levels of total cholesterol and triglyceride until 30 weeks old. Both CETP-1 and LXR{beta} activities were suppressed, most significantly in early combination exposure. In conclusion, arsenic exposure may induce atherosclerosis through modifying reverse cholesterol transport in cholesterol metabolism and suppressing LXR{beta} and CEPT-1 expressions. For decreasing atherosclerosis related mortality associated with arsenic, preventing exposure from environmental sources in early life is an important element. - Highlights: > Arsenic causes cardiovascular and cerebrovascular diseases through atherosclerosis. > Arsenic may promote atherosclerosis with transient increase in HSP

  20. High Speed/ Low Effluent Process for Ethanol

    SciTech Connect (OSTI)

    M. Clark Dale

    2006-10-30

    n this project, BPI demonstrated a new ethanol fermentation technology, termed the High Speed/ Low Effluent (HS/LE) process on both lab and large pilot scale as it would apply to wet mill and/or dry mill corn ethanol production. The HS/LE process allows very rapid fermentations, with 18 to 22% sugar syrups converted to 9 to 11% ethanol beers in 6 to 12 hours using either a consecutive batch or continuous cascade implementation. This represents a 5 to 8X increase in fermentation speeds over conventional 72 hour batch fermentations which are the norm in the fuel ethanol industry today. The consecutive batch technology was demonstrated on a large pilot scale (4,800 L) in a dry mill corn ethanol plant near Cedar Rapids, IA (Xethanol Biofuels). The pilot demonstrated that 12 hour fermentations can be accomplished on an industrial scale in a non-sterile industrial environment. Other objectives met in this project included development of a Low Energy (LE) Distillation process which reduces the energy requirements for distillation from about 14,000 BTU/gal steam ($0.126/gal with natural gas @ $9.00 MCF) to as low as 0.40 KW/gal electrical requirements ($0.022/gal with electricity @ $0.055/KWH). BPI also worked on the development of processes that would allow application of the HS/LE fermentation process to dry mill ethanol plants. A High-Value Corn ethanol plant concept was developed to produce 1) corn germ/oil, 2) corn bran, 3) ethanol, 4) zein protein, and 5) nutritional protein, giving multiple higher value products from the incoming corn stream.

  1. Structural effects of protein aging: Terminal marking by deamidation in human triosephosphate isomerase

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Torres-Larios, Alfredo; Enríquez-Flores, Sergio; Méndez, Sara -Teresa; Castillo-Villanueva, Adriana; Gómez-Manzo, Saúl; Velázquez, Gabriel López-; Marcial-Quino, Jaime; Torres-Arroyo, Angélica; García-Torres, Itzhel; Reyes-Vivas, Horacio; et al

    2015-04-17

    Deamidation, the loss of the ammonium group of asparagine and glutamine to form aspartic and glutamic acid, is one of the most commonly occurring post-translational modifications in proteins. Since deamidation rates are encoded in the protein structure, it has been proposed that they can serve as molecular clocks for the timing of biological processes such as protein turnover, development and aging. Despite the importance of this process, there is a lack of detailed structural information explaining the effects of deamidation on the structure of proteins. Here, we studied the effects of deamidation on human triosephosphate isomerase (HsTIM), an enzyme formore » which deamidation of N15 and N71 has been long recognized as the signal for terminal marking of the protein. Deamidation was mimicked by site directed mutagenesis; thus, three mutants of HsTIM (N15D, N71D and N15D/N71D) were characterized. The results show that the N71D mutant resembles, structurally and functionally, the wild type enzyme. In contrast, the N15D mutant displays all the detrimental effects related to deamidation. The N15D/N71D mutant shows only minor additional effects when compared with the N15D mutation, supporting that deamidation of N71 induces negligible effects. The crystal structures show that, in contrast to the N71D mutant, where minimal alterations are observed, the N15D mutation forms new interactions that perturb the structure of loop 1 and loop 3, both critical components of the catalytic site and the interface of HsTIM. Based on a phylogenetic analysis of TIM sequences, we propose the conservation of this mechanism for mammalian TIMs.« less

  2. Revisions to the Facility Safety Order and DOE-STD-1066 | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Revisions to the Facility Safety Order and DOE-STD-1066 Revisions to the Facility Safety Order and DOE-STD-1066 May 15, 2012 Presenter: Jim Bisker, Fire Protection Program Manager, Office of Health, Safety and Security (HS-32) Topics Covered: Facility Safety Order Revisions Order 420.1 C Specifics DOE-STD-1066 Fire Protection Program Specifics Revisions to the Facility Safety Order and DOE-STD-1066 (412.73 KB) More Documents & Publications DOE Order 420.1C Briefing DOE O 420.1B/1C

  3. TO I PROM'

    Office of Legacy Management (LM)

    TO I PROM' . : h/lemordhdzm i . UNITED STATES GOVERNMENT Merril Eisenbud, Director, Health and Safety DAT!' Jun.2, 1950 M tisiqn Hanson mats, C+i&, Radiation Branch,'Health and S&&y Div. " HS&HB !llGpurpo?e of the rlsltwy ta +mestigatemetho&asedattt&in- &+latdcn to pmtectpersozmel partic+arlyagalnstthebighexierg zw+tAom from the various particle accelerators attheUniver8ity. 'I+'w+c at& Badiation~bor+tirgis divided in~'tm'classifica- tions. Dr. ljelson B.

  4. Aprun MAN Page

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    aprun » Aprun MAN Page Aprun MAN Page aprun [-a arch ] [-b ] [-B] [-cc cpu_list | keyword ] [-cp cpu_placement_file_name ] [-d depth ] [-D value ] [-L node_list ] [-m size[h|hs] ] [-n pes ] [-N pes_per_node ][-F access mode ] [-q ] [-r cores][-S pes_per_numa_node ] [-sl list_of_numa_nodes ] [-sn numa_nodes_per_node ] [-ss ] [-T ] [-t sec ] executable [ arguments_for_executable ] IMPLEMENTATION Cray Linux Environment (CLE) DESCRIPTION To run an application on CNL compute nodes, use the

  5. Thin Film CIGS and CdTe Photovoltaic Technologies: Commercialization, Critical Issues, and Applications; Preprint

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Thin Film CIGS and CdTe Photovoltaic Technologies: Commercialization, Critical Issues, and Applications Preprint H.S. Ullal and B. von Roedern To be presented at the 22nd European Photovoltaic Solar Energy Conference (PVSEC) and Exhibition Milan, Italy September 3-7, 2007 Conference Paper NREL/CP-520-42058 September 2007 NREL is operated by Midwest Research Institute ● Battelle Contract No. DE-AC36-99-GO10337 NOTICE The submitted manuscript has been offered by an employee of the Midwest

  6. Vacuum ultraviolet photoionization and photodissociation of polyatomic molecules and radicals

    SciTech Connect (OSTI)

    Ng, C.Y.

    1993-12-01

    In the past decade, tremendous progress has been made in understanding the photodissociation (PD) dynamics of triatomic molecules. However, the PD study of radicals, especially polyatomic radicals, has remained essentially an unexplored research area. Detailed state-to-state PD cross sections for radicals in the UV and VUV provide challenges not only for dynamical calculations, but also for ab initio quantum chemical studies. The authors have developed a laser based pump-probe apparatus for the measurement of absolute PD cross sections for CH{sub 3}S and HS is summarized.

  7. November 6, 2008; HSS/Union Working Group Meeting on Aging Workforce/Strategic Initiatives - DOE Illness and Injury Surveillance Program Worker Health Summary, 1995-2004

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    U.S. Department of Energy Illness and Injury Surveillance Program Worker Health Summary, 1995-2004 Questions or comments about this report or the Department of Energy's (DOE) Illness and Injury Surveillance Program (IISP) may be directed to: Dr. Cliff Strader at cliff.strader@hq.doe.gov or Dr. Bonnie Richter at bonnie.richter@hq.doe.gov United States Department of Energy Office of Health, Safety and Security Office of Illness and Injury Prevention Programs, HS-13 1000 Independence Avenue, SW

  8. Field Survey of Cactus Crater Storage Facility (Runit Dome)

    SciTech Connect (OSTI)

    Douglas Miller, Terence Holland

    2008-10-31

    The US Department of Energy, Office of Health and Safety (DOE/HS-10), requested that National Security Technologies, LLC, Environmental Management directorate (NSTec/EM) perform a field survey of the Cactus Crater Storage Facility (Runit Dome), similar to past surveys conducted at their request. This field survey was conducted in conjunction with a Lawrence Livermore National Laboratory (LLNL) mission on Runit Island in the Enewetak Atoll in the Republic of the Marshall Islands (RMI). The survey was strictly a visual survey, backed up by digital photos and a written description of the current condition.

  9. Fleet Briefings | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fleet Briefings Fleet Briefings CITI Briefing.pdf (139.2 KB) DOE - Agency Meeting - FedFleet 2012-2.pdf (1.89 MB) DOE Fed Fleet WEX Program Reviewl.pdf (1.46 MB) DOE Motor Vehicle Accidents and FEOSH-mccabe-final-with HS-20 comments-061912 (2).pdf (195.2 KB) FEMP Briefing.pdf (469.98 KB) INL Coach Bus Brief.pdf (971.92 KB) NREL Brief.pdf (1.98 MB) More Documents & Publications FEMP Exterior Solid-State Lighting Technology Pilot Federal Utility Partnership Working Group Meeting: Washington

  10. Inspiring the next generation of computational thinkers | Argonne National

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laboratory Illinois Math and Science Academy senior Tavis Reed delivered a keynote to students on his research and path to STEM. Illinois Math and Science Academy senior Tavis Reed delivered a keynote to students on his research and path to STEM. Inspiring the next generation of computational thinkers By Justin H.S. Breaux * January 13, 2016 Tweet EmailPrint The City of Chicago and the U.S. Department of Energy's (DOE's) Argonne National Laboratory came together this winter for a My

  11. Richard A. Meserve President Emeritus

    Office of Environmental Management (EM)

    Energy Revisions to the Facility Safety Order and DOE-STD-1066 Revisions to the Facility Safety Order and DOE-STD-1066 May 15, 2012 Presenter: Jim Bisker, Fire Protection Program Manager, Office of Health, Safety and Security (HS-32) Topics Covered: Facility Safety Order Revisions Order 420.1 C Specifics DOE-STD-1066 Fire Protection Program Specifics Revisions to the Facility Safety Order and DOE-STD-1066 (412.73 KB) More Documents & Publications DOE Order 420.1C Briefing DOE O 420.1B/1C

  12. PrintRes_PeriodicChartPostCard2014

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    0 Hg Mercury 35 Br Bromine 43 c echnetium 93 Np Neptunium 94 Pu Plutonium 95 Am Americium 96 Cm Curium 97 Bk Berkelium 98 Cf Californium 99 Es Einsteinium 100 Fm Fermium 101 Md Mendelevium 102 No Nobelium 105 107 106 108 109 111 110 112 Db Dubnium Sg Hs Hassium Bh Seaborgium Bohrium Mt Meitnerium Uun Ununnilium Uuu Unununium 114 116 103 Lr Lawrencium 104 Rf Rutherfordium Uub Ununbium Uuq Ununquadium Uuh Ununhexium T T 17 Cl Chlorine 18 Ar Argon 1 H Hydrogen 86 Rn Radon 10 Ne Neon 2 He Helium 9 O

  13. Modest hypoxia significantly reduces triglyceride content and lipid droplet size in 3T3-L1 adipocytes

    SciTech Connect (OSTI)

    Hashimoto, Takeshi; Yokokawa, Takumi; Endo, Yuriko; Iwanaka, Nobumasa; Higashida, Kazuhiko; Faculty of Sport Science, Waseda University, 2-579-15 Mikajima, Tokorozawa, Saitama 359-1192 ; Taguchi, Sadayoshi

    2013-10-11

    Highlights: Long-term hypoxia decreased the size of LDs and lipid storage in 3T3-L1 adipocytes. Long-term hypoxia increased basal lipolysis in 3T3-L1 adipocytes. Hypoxia decreased lipid-associated proteins in 3T3-L1 adipocytes. Hypoxia decreased basal glucose uptake and lipogenic proteins in 3T3-L1 adipocytes. Hypoxia-mediated lipogenesis may be an attractive therapeutic target against obesity. -- Abstract: Background: A previous study has demonstrated that endurance training under hypoxia results in a greater reduction in body fat mass compared to exercise under normoxia. However, the cellular and molecular mechanisms that underlie this hypoxia-mediated reduction in fat mass remain uncertain. Here, we examine the effects of modest hypoxia on adipocyte function. Methods: Differentiated 3T3-L1 adipocytes were incubated at 5% O{sub 2} for 1 week (long-term hypoxia, HL) or one day (short-term hypoxia, HS) and compared with a normoxia control (NC). Results: HL, but not HS, resulted in a significant reduction in lipid droplet size and triglyceride content (by 50%) compared to NC (p < 0.01). As estimated by glycerol release, isoproterenol-induced lipolysis was significantly lowered by hypoxia, whereas the release of free fatty acids under the basal condition was prominently enhanced with HL compared to NC or HS (p < 0.01). Lipolysis-associated proteins, such as perilipin 1 and hormone-sensitive lipase, were unchanged, whereas adipose triglyceride lipase and its activator protein CGI-58 were decreased with HL in comparison to NC. Interestingly, such lipogenic proteins as fatty acid synthase, lipin-1, and peroxisome proliferator-activated receptor gamma were decreased. Furthermore, the uptake of glucose, the major precursor of 3-glycerol phosphate for triglyceride synthesis, was significantly reduced in HL compared to NC or HS (p < 0.01). Conclusion: We conclude that hypoxia has a direct impact on reducing the triglyceride content and lipid droplet size via decreased

  14. Slide 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    * Retro-aldol reactions (RA) of ketohexoses were performed at temperatures ca. 100 °C on catalysts previously known to catalyze 1,2-carbon shift (1,2-CS) reactions * Coupling with spatially-separated 1,2-hydride shift (1,2-HS) active sites allowed for tandem-catalytic production of alkyl lactates from hexoses at moderate temperatures Moderate Temperature Retro-Aldol Reactions of Hexoses for the Production of Lactates Work was performed at the California Institute of Technology by the group of

  15. U.S. Department of Energy Illness and Injury Surveillance Program Worker Health Summary, 1995-2004

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    U.S. Department of Energy Illness and Injury Surveillance Program Worker Health Summary, 1995-2004 Questions or comments about this report or the Department of Energy's (DOE) Illness and Injury Surveillance Program (IISP) may be directed to: Dr. Cliff Strader at cliff.strader@hq.doe.gov or Dr. Bonnie Richter at bonnie.richter@hq.doe.gov United States Department of Energy Offi ce of Health, Safety and Security Offi ce of Illness and Injury Prevention Programs, HS-13 1000 Independence Avenue, SW

  16. U.S. Department of Energy Office of Health, Safety, and Security Illness and Injury Surveillance Program Worker HeLth at a Glance, 2000-2009

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    U.S. Department of Energy Illness and Injury Surveillance Program Worker Health At A Glance, 2000-2009 Questions or comments about this report or the Department of Energy's (DOE) Illness and Injury Surveillance Program (IISP) within the offce of Health, Safety and Security may be directed to: Dr. Cliff Strader at cliff.strader@hq.doe.gov or Dr. Bonnie Richter at bonnie.richter@hq.doe.gov Mail Stop HS-13 / GTN Building United States Department of Energy 1000 Independence Avenue, S.W. Washington,

  17. Personalized energy | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    This article was published in the spring 2016 issue of Argonne Now, the laboratory science magazine. Click for the rest of the issue. Personalized energy By Justin H.S. Breaux * March 7, 2016 Tweet EmailPrint The local food movement is booming. Can we do the same for electricity? This article was originally published in the spring 2016 issue of Argonne Now, the laboratory's science magazine. Being cut off from electricity doesn't just affect whether we can make a phone call or heat dinner; it

  18. Microsoft Word - Fire_Safety_Committee_Membership.doc

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cole, Matt Office Of Science (SC 31.1) (301) 903-8388 Matt.Cole@science.doe.gov Boyll, David Savannah River Operations Office (803) 952-8000 David.Boyll@srs.gov West, Dale Name Organization Work Phone E-mail Co-Chairs Christenson, Craig EM-Office Of River Protection (509) 376-5367 craig_p_christenson@orp.doe.gov Bisker, James Office Of Health Safety & Security (HS-21) (301) 903-6542 Jim.Bisker@hq.doe.gov Emergency Services Committee Chair Masters, Michael UT-Battelle (865) 241-3323

  19. NAME

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Record Liaison Officers (RLO) Distribution List NAME PROGRAM PROGRAM OFFICE PHONE EMAIL Auch, Joan NA-122.21 National Nuclear Security Administration 202-586-1852 Joan.auch@nnsa.doe.gov Barnes, Claude GC Office of the General Counsel 202-586-2957 claude.barnes@hq.doe.gov Black, Helen EE Office of Energy Efficiency and Renewable Energy 202-586-8563 helen.black@hq.doe.gov Briggs, Felecia (alternate POC) HS Office of Health, Safety and Security 301-903-8803 felecia.briggs@hq.doe.gov Cambrel,

  20. POTENTIAL MARKETS FOR HIGH-BTU GAS FROM COAL

    SciTech Connect (OSTI)

    Booz, Allen, and Hamilton, Inc.,

    1980-04-01

    It has become increasilngly clear that the energy-related ilemna facing this nation is both a long-term and deepening problem. A widespread recognition of the critical nature of our energy balance, or imbalance, evolved from the Arab Oil Embargo of 1973. The seeds of this crisis were sown in the prior decade, however, as our consumption of known energy reserves outpaced our developing of new reserves. The resultant increasing dependence on foreign energy supplies hs triggered serious fuel shortages, dramatic price increases, and a pervsive sense of unertainty and confusion throughout the country.

  1. June 11, 2009, HSS/Union Task Meeting on 2009 HSS/Union Task Progress - Assessing Training Gaps in ORPS

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Training Gaps Using DOE's Occurrence Reporting and Processing System (ORPS) HSS/Union Meeting June 11, 2009 2 Highlights Training is a contributing cause in about 15% of DOE operational events (about 150 per year) * Poor management practices are the most common training cause * Poor training programs are next (cited about 50 times per year) Of ORPS-reported injuries, about 17% had training as a contributing cause (101 of 594) * About 30 per year HS-30 will develop a report with a few more

  2. Coupling MM5 with LSM1: Development, Testing, and Application - MM5_workshop

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MM5 with ISOLSM: Development, Testing, and Applications W.J. Riley 1 , H.S. Cooley 1,2 , Y. He* 1 , M.S. Torn 1 1 Lawrence Berkeley National Laboratory, Berkeley, CA 2 Energy and Resources Group, U.C. Berkeley, CA 1. INTRODUCTION Surface water and energy fluxes are tightly coupled with CO 2 exchanges between the ecosystem and atmosphere. Other surface-to- atmosphere trace-gas exchanges of interest in climate change research (e.g., N 2 O, CH 4 , C 18 OO, and H 2 18 O) are also strongly impacted

  3. Search For a Consistent Mean-Field Treatment of Magnetic Properties of Yittrium-Cobalt-5 Under Moderate Hydrostatic Stress

    SciTech Connect (OSTI)

    Benedict, Lorin X.; Aberg, Daniel; Soderlind, Per; Sadigh, Babak; Daene, Markus

    2015-10-26

    We explore the use of particular variants of DFT + U and DFT + orbital polarization (OP) to calculate the electronic structure and magnetic properties of YCo5 under hydrostatic pressures up to 600 kbar. While the speci c DFT + U (with U= 0.75 eV) and DFT + OP schemes we employ produce magneto-crystalline anisotropy energies for YCo5 in good agreement with experiments performed in ambient conditions, our DFT + U results are shown to greatly overestimate the pressure at which a high-spin to low-spin (HS-LS) transition is known to occur. In contrast, our DFT + OP results predict the HS-LS transition to occur at the same stress as DFT, and in better agreement with experiment. This sensitivity suggests that care should be taken when attempting to model magnetic properties with self-interaction and/or correlation corrections to DFT for this and related materials, and highlights the usefulness of moderate pressure as an additional parameter to vary when discriminating between candidate theoretical schemes.

  4. Superior Conductive Solid-like Electrolytes: Nanoconfining Liquids within the Hollow Structures

    SciTech Connect (OSTI)

    Zhang, Jinshui; Bai, Ying; Sun, Xiao-Guang; Li, Yunchao; Guo, Bingkun; Chen, Jihua; Veith, Gabriel M; Hensley, Dale K; Paranthaman, Mariappan Parans; Goodenough, John B; Dai, Sheng

    2015-01-01

    The growth and proliferation of lithium (Li) dendrites during cell recharge is unavoidable, which seriously hinders the development and application of rechargeable Li metal batteries. Solid electrolytes with robust mechanical modulus are regarded as a promising approach to overcome the dendrite problems. However, their room-temperature ionic conductivities are usually too low to reach the level required for normal battery operation. Here, a class of novel solid electrolytes with liquid-like room-temperature ionic conductivities (> 1 mS cm-1) has been successfully synthesized by taking advantage of the unique nanoarchitectures of hollow silica (HS) spheres to confine liquid electrolytes in hollow space to afford high conductivities. In a symmetric lithium/lithium cell, such kind of solid-like electrolytes demonstrates a robust performance against Li dendrite problems, well stabilizing the cell system from short circuiting in a long-time operation at current densities ranging from 0.16 to 0.32 mA cm-2. Moreover, the high flexibility and compatibility of HS nanoarchitectures, in principle, enables broad tunability to choose desired liquids for the fabrication of other kinds of solid-like electrolytes, such as those containing Na+, Mg2+ or Al3+ as conductive media, providing a useful alternative strategy for the development of next generation rechargeable batteries.

  5. On the role of the simplest S-nitrosothiol, HSNO, in atmospheric and biological processes

    SciTech Connect (OSTI)

    Hochlaf, Majdi Linguerri, Roberto; Francisco, Joseph S.

    2013-12-21

    Using state-of-the-art theoretical methods, we investigate the lowest electronic states of singlet and triplet spin multiplicities of HSNO. These computations are done using configuration interaction ab initio methods and the aug-cc-pV5Z basis set. One-dimensional cuts of the six-dimensional potential energy surfaces of these electronic states along the HS, SN stretches and HSN, SNO bending and torsion coordinates are calculated. Several avoided crossings and conical intersections are found. We computed also radiative lifetimes and spin-orbit couplings of these electronic states. Our work shows that the dynamics on these excited states is very complex, and suggest that multi-step mechanisms will populate the ground state via radiationless processes or lead to predissociation or intramolecular isomerization. For instance, these potentials are used to propose mechanisms for the IR, Vis, and UV light-induced cis-trans interconversions of HSNO and reactivity towards HS + NO and H + SNO products. Our findings are in good agreement with previous experimental studies on the photochemistry of HSNO. The atmospheric implication of HSNO is also discussed.

  6. High-speed atomic force microscope based on an astigmatic detection system

    SciTech Connect (OSTI)

    Liao, H.-S.; Chen, Y.-H.; Hwu, E.-T.; Chang, C.-S.; Hwang, I.-S.; Ding, R.-F.; Huang, H.-F.; Wang, W.-M.; Huang, K.-Y.

    2014-10-15

    High-speed atomic force microscopy (HS-AFM) enables visualizing dynamic behaviors of biological molecules under physiological conditions at a temporal resolution of 1s or shorter. A small cantilever with a high resonance frequency is crucial in increasing the scan speed. However, detecting mechanical resonances of small cantilevers is technically challenging. In this study, we constructed an atomic force microscope using a digital versatile disc (DVD) pickup head to detect cantilever deflections. In addition, a flexure-guided scanner and a sinusoidal scan method were implemented. In this work, we imaged a grating sample in air by using a regular cantilever and a small cantilever with a resonance frequency of 5.5 MHz. Poor tracking was seen at the scan rate of 50 line/s when a cantilever for regular AFM imaging was used. Using a small cantilever at the scan rate of 100 line/s revealed no significant degradation in the topographic images. The results indicate that a smaller cantilever can achieve a higher scan rate and superior force sensitivity. This work shows the potential for using a DVD pickup head in future HS-AFM technology.

  7. Synthesis and new structure shaping mechanism of silica particles formed at high pH

    SciTech Connect (OSTI)

    Zhang, Henan; Zhao, Yu; Akins, Daniel L.

    2012-10-15

    For the sol-gel synthesis of silica particles under high pH catalytic conditions (pH>12) in water/ethanol solvent, we have deduced that the competing dynamics of chemical etching and sol-gel process can explain the types of silica particles formed and their morphologies. We have demonstrated that emulsion droplets that are generated by adding tetraethyl orthosilicate (TEOS) to a water-ethanol solution serve as soft templates for hollow spherical silica (1-2 {mu}m). And if the emulsion is converted by the sol-gel process, one finds that suspended solid silica spheres of diameter of {approx}900 nm are formed. Moreover, several other factors are found to play fundamental roles in determining the final morphologies of silica particles, such as by variation of the pH (in our case, using OH{sup -}) to a level where condensation dominates; by changing the volume ratios of water/ethanol; and using an emulsifier (specifically, CTAB) - Graphical abstract: 'Local chemical etching' and sol-gel process have been proposed to interpret the control of morphologies of silica particles through varying initial pHs in syntheses. Highlights: Black-Right-Pointing-Pointer Different initial pHs in our syntheses provides morphological control of silica particles. Black-Right-Pointing-Pointer 'Local chemical etching' and sol-gel process describes the formation of silica spheres. Black-Right-Pointing-Pointer The formation of emulsions generates hollow silica particles.

  8. Site-Scale Saturated Zone Flow Model

    SciTech Connect (OSTI)

    G. Zyvoloski

    2003-12-17

    The purpose of this model report is to document the components of the site-scale saturated-zone flow model at Yucca Mountain, Nevada, in accordance with administrative procedure (AP)-SIII.lOQ, ''Models''. This report provides validation and confidence in the flow model that was developed for site recommendation (SR) and will be used to provide flow fields in support of the Total Systems Performance Assessment (TSPA) for the License Application. The output from this report provides the flow model used in the ''Site-Scale Saturated Zone Transport'', MDL-NBS-HS-000010 Rev 01 (BSC 2003 [162419]). The Site-Scale Saturated Zone Transport model then provides output to the SZ Transport Abstraction Model (BSC 2003 [164870]). In particular, the output from the SZ site-scale flow model is used to simulate the groundwater flow pathways and radionuclide transport to the accessible environment for use in the TSPA calculations. Since the development and calibration of the saturated-zone flow model, more data have been gathered for use in model validation and confidence building, including new water-level data from Nye County wells, single- and multiple-well hydraulic testing data, and new hydrochemistry data. In addition, a new hydrogeologic framework model (HFM), which incorporates Nye County wells lithology, also provides geologic data for corroboration and confidence in the flow model. The intended use of this work is to provide a flow model that generates flow fields to simulate radionuclide transport in saturated porous rock and alluvium under natural or forced gradient flow conditions. The flow model simulations are completed using the three-dimensional (3-D), finite-element, flow, heat, and transport computer code, FEHM Version (V) 2.20 (software tracking number (STN): 10086-2.20-00; LANL 2003 [161725]). Concurrently, process-level transport model and methodology for calculating radionuclide transport in the saturated zone at Yucca Mountain using FEHM V 2.20 are being

  9. Devices, systems, and methods for microscale isoelectric fractionation

    DOE Patents [OSTI]

    Sommer, Gregory J; Hatch, Anson V; Wang, Ying-Chih; Singh, Anup K

    2015-04-14

    Embodiments of the present invention provide devices, systems, and methods for microscale isoelectric fractionation. Analytes in a sample may be isolated according to their isoelectric point within a fractionation microchannel. A microfluidic device according to an embodiment of the invention includes a substrate at least partially defining a fractionation microchannel. The fractionation microchannel has at least one cross-sectional dimension equal to or less than 1 mm. A plurality of membranes of different pHs are disposed in the microchannel. Analytes having an isoelectric point between the pH of the membranes may be collected in a region of the fractionation channel between the first and second membranes through isoelectric fractionation.

  10. Final Project Report: Release of aged contaminants from weathered sediments: Effects of sorbate speciation on scaling of reactive transport

    SciTech Connect (OSTI)

    Jon Chorover, University of Arizona; Peggy O'????Day, University of California, Merced; Karl Mueller, Penn State University; Wooyong Um, Pacific Northwest National Laboratory; Carl Steefel, Lawrence Berkeley National Laboratory

    2012-10-01

    Hanford sediments impacted by hyperalkaline high level radioactive waste have undergone incongruent silicate mineral weathering concurrent with contaminant uptake. In this project, we studied the impact of background pore water (BPW) on strontium, cesium and iodine desorption and transport in Hanford sediments that were experimentally weathered by contact with simulated hyperalkaline tank waste leachate (STWL) solutions. Using those lab-weathered Hanford sediments (HS) and model precipitates formed during nucleation from homogeneous STWL solutions (HN), we (i) provided detailed characterization of reaction products over a matrix of field-relevant gradients in contaminant concentration, PCO2, and reaction time; (ii) improved molecular-scale understanding of how sorbate speciation controls contaminant desorption from weathered sediments upon removal of caustic sources; and (iii) developed a mechanistic, predictive model of meso- to field-scale contaminant reactive transport under these conditions.

  11. DOE 2008 occupational radiation exposure

    SciTech Connect (OSTI)

    none,

    2009-10-01

    The U.S. Department of Energy (DOE) Office of Corporate Safety Analysis (HS-30) within the Office of Health, Safety and Security (HSS) publishes the annual DOE Occupational Radiation Exposure Report to provide an overview of the status of radiation protection practices at DOE. The DOE 2008 Occupational Radiation Exposure Report provides an evaluation of DOE-wide performance regarding compliance with DOE Part 835 dose limits and as low as reasonably achievable (ALARA) process requirements. In addition, the report provides data to DOE organizations responsible for developing policies for protection of individuals from the effects of radiation. This report provides a summary and an analysis of occupational radiation exposure information from the monitoring of individuals involved in DOE activities. The occupational radiation exposure information is analyzed in terms of aggregate data, dose to individuals, and dose by site over the past 5 years.

  12. Active DOE Completed Projects

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Completed) Project Number Title Document ID SLM / ORG Author / Phone / Email Status / Review Date P1137-2007REV Fire ProtecƟon Engineering FAQS DOE-STD-1137-2014 Karen Boardman (NNSA) P1181-2004REV Facility Maintenance Management DOE-STD-1181-2014 Karen Boardman FuncƟon Area QualiĮcaƟon Standard (HS-70) P1182-2004REV Civil Structural Engineering, FuncƟonal DOE-STD-1182-2014 Karen Boardman Area QualiĮcaƟon Standard (AU-70) P2013-03 ProtecƟve Force ConƟngency Planning DOE-HDBK-1213-2014

  13. DOE occupational radiation exposure 2007 report

    SciTech Connect (OSTI)

    none,

    2007-12-31

    The U.S. Department of Energy (DOE) Office of Corporate Safety Analysis (HS-30) within the Office of Health, Safety and Security (HSS) publishes the annual DOE Occupational Radiation Exposure Report to provide an overview of the status of radiation protection practices at DOE.* The annual DOEOccupational Radiation Exposure 2007 Report provides an evaluation of DOE-wide performance regarding compliance with DOE Part 835 dose limits and ALARA process requirements. In addition the report provides data to DOE organizations responsible for developing policies for protection of individuals from the effects of radiation. This report provides a summary and an analysis of occupational radiation exposure information from the monitoring of individuals involved in DOE activities. The occupational radiation exposure information is analyzed in terms of aggregate data, dose to individuals, and dose by site over the past five years.

  14. Methods for producing hydrogen (BI) sulfide and/or removing metals

    DOE Patents [OSTI]

    Truex, Michael J [Richland, WA; Peyton, Brent M [Pullman, WA; Toth, James J [Kennewick, WA

    2002-05-14

    The present invention is a process wherein sulfide production by bacteria is efficiently turned on and off, using pH adjustment. The adjustment of pH impacts sulfide production by bacteria by altering the relative amounts of H.sub.2 S and HS-- in solution and thereby control the inhibition of the bacterial metabolism that produces sulfide. This process can be used to make a bioreactor produce sulfide "on-demand" so that the production of sulfide can be matched to its use as a metal precipitation reagent. The present invention is of significance because it enables the use of a biological reactor, a cost effective sulfide production system, by making the biological reactor produce hydrogen sulfide "on demand", and therefore responsive to production schedules, waste stream generation rate, and health and safety requirements/goals.

  15. Energy Information Administration

    U.S. Energy Information Administration (EIA) Indexed Site

    Energy Conference 2015 Energy Storage: State of the Industry Katherine Hamilton, Advisor to ESA katherine@38northsolutions.com Storage T echnologies: A cross t he G rid 2 ESA M embers Trajectory o f t he I ndustry "just o ne w ord..." 4 According t o m arket r esearch fi rm I HS, energy s torage g rowth w ill " explode" from . 34 G W i n 2 012---2013 t o 6 G W b y 2017 a nd o ver 4 0 G W b y 2 022. Trajectory o f t he I ndustry 5 * The U .S. i nstalled 6 1.9 M W o f e nergy

  16. THE KFIB EXPERIMENT

    SciTech Connect (OSTI)

    Youngblood, Gerald E.; Senor, David J.; Jones, Russell H.; Kowbel, W.; Kohyama, A.

    2000-06-30

    Several rod-shaped specimens with uniaxially packed fibers (Hi-Nicalon™, Hi-Nicalon™ Type S, Tyranno™ SA and Amoco K1100™ types) in a pre-ceramic polymer matrix were fabricated. By using appropriate analytic models, the bare fiber thermal conductivity (Kf) will be determined as a function of temperature up to 1000°C before and after irradiation for samples cut from these rods. Preliminary thermal conductivity data for unirradiated fibers (Hi-Nicalon™ and Tyranno™ SA-B SiC and K1100™ graphite) and for three types of unirradiated composites made from these fibers (2D-Nicalon S/SiC multilayer/CVI-SiC, 3D-Nicalon S/PIP-SiC, and 2D-8HS Tyrannohex™ HP) are presented.

  17. rVISTA for Comparative Sequence-Based Discovery of Functional Transcription Factor Binding Sites

    SciTech Connect (OSTI)

    Loots, Gabriela G.; Ovcharenko, Ivan; Pachter, Lior; Dubchak, Inna; Rubin, Edward M.

    2002-03-08

    Identifying transcriptional regulatory elements represents a significant challenge in annotating the genomes of higher vertebrates. We have developed a computational tool, rVISTA, for high-throughput discovery of cis-regulatory elements that combines transcription factor binding site prediction and the analysis of inter-species sequence conservation. Here, we illustrate the ability of rVISTA to identify true transcription factor binding sites through the analysis of AP-1 and NFAT binding sites in the 1 Mb well-annotated cytokine gene cluster1 (Hs5q31; Mm11). The exploitation of orthologous human-mouse data set resulted in the elimination of 95 percent of the 38,000 binding sites predicted upon analysis of the human sequence alone, while it identified 87 percent of the experimentally verified binding sites in this region.

  18. Gallatin fossil plant: Evaluation of waste reduction opportunities

    SciTech Connect (OSTI)

    McEntyre, C.L.; Harris, R.A.

    1995-10-01

    As part of the business planning process, Fossil and Hydro Power set a goal for each facility to reduce noncombustion related solid waste generation by 10% from FY 1994 levels by the end of FY 1995 and by 30% by the end of FY 1997. Facility managers wanted help in identifying and understanding the waste streams at their facilities. A task team performed a pilot waste assessment using the processes described in F and H`s Solid Waste Procedure and EPA`s Facility Pollution Prevention Guide. Objectives were to develop a baseline by conducting a Site Assessment for generation of noncombustion solid waste and identification to the extent practicable of existing solid waste management costs. Several options for reducing wastes generation, improving operations, and reducing costs were identified.

  19. Flocculation of model algae under shear.

    SciTech Connect (OSTI)

    Pierce, Flint; Lechman, Jeremy B.

    2010-11-01

    We present results of molecular dynamics simulations of the flocculation of model algae particles under shear. We study the evolution of the cluster size distribution as well as the steady-state distribution as a function of shear rates and algae interaction parameters. Algal interactions are modeled through a DLVO-type potential, a combination of a HS colloid potential (Everaers) and a yukawa/colloid electrostatic potential. The effect of hydrodynamic interactions on aggregation is explored. Cluster strucuture is determined from the algae-algae radial distribution function as well as the structure factor. DLVO parameters including size, salt concentration, surface potential, initial volume fraction, etc. are varied to model different species of algae under a variety of environmental conditions.

  20. Metal chelate process to remove pollutants from fluids

    DOE Patents [OSTI]

    Chang, S.G.T.

    1994-12-06

    The present invention relates to improved methods using an organic iron chelate to remove pollutants from fluids, such as flue gas. Specifically, the present invention relates to a process to remove NO[sub x] and optionally SO[sub 2] from a fluid using a metal ion (Fe[sup 2+]) chelate wherein the ligand is a dimercapto compound wherein the --SH groups are attached to adjacent carbon atoms (HS--C--C--SH) or (SH--C--CCSH) and contain a polar functional group so that the ligand of DMC chelate is water soluble. Alternatively, the DMC is covalently attached to a water insoluble substrate such as a polymer or resin, e.g., polystyrene. The chelate is regenerated using electroreduction or a chemical additive. The dimercapto compound bonded to a water insoluble substrate is also useful to lower the concentration or remove hazardous metal ions from an aqueous solution. 26 figures.

  1. Metal chelate process to remove pollutants from fluids

    DOE Patents [OSTI]

    Chang, Shih-Ger T.

    1994-01-01

    The present invention relates to improved methods using an organic iron chelate to remove pollutants from fluids, such as flue gas. Specifically, the present invention relates to a process to remove NO.sub.x and optionally SO.sub.2 from a fluid using a metal ion (Fe.sup.2+) chelate wherein the ligand is a dimercapto compound wherein the --SH groups are attached to adjacent carbon atoms (HS--C--C--SH) or (SH--C--CCSH) and contain a polar functional group so that the ligand of DMC chelate is water soluble. Alternatively, the DMC' is covalently attached to a water insoluble substrate such as a polymer or resin, e.g., polystyrene. The chelate is regenerated using electroreduction or a chemical additive. The dimercapto compound bonded to a water insoluble substrate is also useful to lower the concentration or remove hazardous metal ions from an aqueous solution.

  2. R

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SHE R esearch a t R IKEN/GARIS Kosuke M orita Department o f P hysics, K yushu U niversity, Research G roup f or Superheavy E lement, R IKEN Nishina C enter RIKEN Kyushu U niv. 2015/3/31 Superheavy N uclei 2 015 T exas A &M U niv. 1 2014/11/08 2 科学を語る会@九大西新プラザ 3 120 119 118 117 116 115 114 113 112 Rg Ds Mt Hs Bh Sg Db Rf 162 184 262 266 265 264 262 261 261 260 259 258 257 258 260 259 260 261 262 263 262 261 SHE A A A α---decay Spontaneous fi ssion β + o r E C d

  3. Alkaline Membrane Fuel Cell Workshop Welcome and OverviewInnovation

    Office of Environmental Management (EM)

    Aleutian Pribilof Islands Wind Feasibility and Energy Weatherization and Training Bruce Wright APIA Senior Scientist 2005 Wind Feasibility Studies: False Pass, Nikolski Sand Point, St. George, and Current Wind Energy Development Status Communities KwH Cost KwH (1,000,000) Diesel Demand (1,000 gals) KwHs Per Gallon King Cove 0.26 3.79 162 23 Akutan 0.32 0.52 44 12 Unalaska 0.36 34.48 2,194 16 False Pass 0.42 N/A N/A N/A St. Paul 0.46 4.59 389 12 Sand Point 0.52 4.03 317 13 AVERAGE 0.53 2.21 177

  4. Electrofishing survey of the Great Miami River, September 1992. Annual report

    SciTech Connect (OSTI)

    Miller, M.C.; Bixby, R.; Engman, J.; Ross, L.; Stocker, L.

    1993-03-01

    At the end of summer in 1992 the fishery of the Great Miami River took an unexpected deviation from the stasis of past years as an intense suspended algal bloom decreased the compositional diversity found at the lower GMR stations. Daytime supersaturation of oxygen and elevated pHs, reaching 9 by midday during the month of August, undoubtedly caused severe deficits of oxygen at night. Despite the aeration at every riffle, the intensities of the biological processes in the water were sufficient to cause very high positive and negative excursions of oxygen over the day and night cycle. This report documents a fish harvest that was conducted as part of the oxygen excess/deficit study.

  5. Excitation functions for the production of superheavy nuclei in cold fusion reactions

    SciTech Connect (OSTI)

    Smolanczuk, Robert

    2000-01-01

    Excitation energy dependence of the cross sections of the reactions {sup 208}Pb{sub 126}({sup 50}Ti{sub 28},1n){sup 257}Rf{sub 153} and {sup 208}Pb{sub 126}({sup 58}Fe{sub 32},1n){sup 265}Hs{sub 157} is calculated and compared with the experimental data measured at GSI-Darmstadt. Such a dependence is also calculated for the reaction {sup 208}Pb{sub 126}({sup 86}Kr{sub 50},1n){sup 293}118{sub 175} reported recently by the Berkeley group, and for reactions which may lead to the synthesis of element 119 and production of its odd-Z descendants. Recommendations for future experiments based on the present study are presented. (c) 1999 The American Physical Society.

  6. Radiological Emergency Response Health and Safety Manual

    SciTech Connect (OSTI)

    D. R. Bowman

    2001-05-01

    This manual was created to provide health and safety (H&S) guidance for emergency response operations. The manual is organized in sections that define each aspect of H and S Management for emergency responses. The sections are as follows: Responsibilities; Health Physics; Industrial Hygiene; Safety; Environmental Compliance; Medical; and Record Maintenance. Each section gives guidance on the types of training expected for managers and responders, safety processes and procedures to be followed when performing work, and what is expected of managers and participants. Also included are generic forms that will be used to facilitate or document activities during an emergency response. These ensure consistency in creating useful real-time and archival records and help to prevent the loss or omission of information.

  7. Water-Level Data Analysis for the Saturated Zone Site-Scale Flow and Transport Model

    SciTech Connect (OSTI)

    P. Tucci

    2001-12-20

    This Analysis/Model Report (AMR) documents an updated analysis of water-level data performed to provide the saturated-zone, site-scale flow and transport model (CRWMS M&O 2000) with the configuration of the potentiometric surface, target water-level data, and hydraulic gradients for model calibration. The previous analysis was presented in ANL-NBS-HS-000034, Rev 00 ICN 01, Water-Level Data Analysis for the Saturated Zone Site-Scale Flow and Transport Model (USGS 2001). This analysis is designed to use updated water-level data as the basis for estimating water-level altitudes and the potentiometric surface in the SZ site-scale flow and transport model domain. The objectives of this revision are to develop computer files containing (1) water-level data within the model area (DTN: GS010908312332.002), (2) a table of known vertical head differences (DTN: GS0109083 12332.003), and (3) a potentiometric-surface map (DTN: GS010608312332.001) using an alternate concept from that presented in ANL-NBS-HS-000034, Rev 00 ICN 01 for the area north of Yucca Mountain. The updated water-level data include data obtained from the Nye County Early Warning Drilling Program (EWDP) and data from borehole USW WT-24. In addition to being utilized by the SZ site-scale flow and transport model, the water-level data and potentiometric-surface map contained within this report will be available to other government agencies and water users for ground-water management purposes. The potentiometric surface defines an upper boundary of the site-scale flow model, as well as provides information useful to estimation of the magnitude and direction of lateral ground-water flow within the flow system. Therefore, the analysis documented in this revision is important to SZ flow and transport calculations in support of total system performance assessment.

  8. Radium-226 and low pH in groundwater due to oxidation of authigenic pyrite; Savannah River Site, South Carolina

    SciTech Connect (OSTI)

    KUBILIUS, WALTER

    2005-12-21

    The origin of elevated radium-226 in groundwater beneath a sanitary landfill at the Savannah River Site (SRS) was investigated. Nearly one hundred monitoring wells are developed in the Steed Pond Aquifer (SPA), which consists of 100-150 ft of Coastal Plain sand, iron oxides, and minor clay. Wells screened in the upper and middle portions of the aquifer have average Ra-226 between 0.5 and 2.5 pCi/L, and average pHs above 4.7. However, wells screened near the base of the aquifer exhibit higher average Ra-226 concentrations of 2.5 to 4.6 pCi/L, with some measurements exceeding the MCL of 5 pCi/L, and show average pHs of 4.1 to 4.7. These wells are not downgradient of the landfill, and are not impacted by landfill leachate. The Crouch Branch Confining Unit (CBCU) underlies the aquifer, and is composed partly of reduced gray/brown clay with lignite and authigenic pyrite. Gamma ray logs show that the SPA has low gamma counts, but the CBCU is consistently elevated. Groundwater with high radium/low pH also contains elevated sulfate concentrations. pH calculations indicate that sulfate is in the form of sulfuric acid. A model for the origin of elevated Ra-226 levels in deeper SPA wells envisions infiltration of oxygenated SPA groundwater into reduced pyritic CBCU sediments, with consequent oxidative pyrite dissolution, and acidification of groundwater. Then, naturally occurring CBCU radium dissolves, and mixes into the Steed Pond Aquifer.

  9. RCRA Facility Investigation Plan K-1004 Area Lab Drain and the K-1007-B Pond - Oak Ridge Gaseous Diffusion Plant - Oak Ridge, Tennessee

    SciTech Connect (OSTI)

    ORGDP, Martin Marietta Energy Systems Inc.

    1988-12-01

    Within the confines of the Oak Ridge Gaseous Diffusion Plant (ORGDP) are hazardous waste treatment, storage, and disposal facilities; some are in operation while others are no longer in use. these solid waste management units (SWMUs) are subject to assessment by the US Environmental Protection Agency (EPA). The RCRA Facility Investigation (RFI) Plans are scheduled to be submitted for all units during calendar years 1987 and 1988. The RFI Plan - General Document (K/HS-132) includes information applicable to all the ORGDP SMWUs and serves as a reference document for the site-specific RFI plans. This document is the site-specific RFI Plan for the K-1004 Area Lab Drain (ALD) and the K-1007-B Pond. This plan is based upon requirements described in the draft document, RFI Guidance, Vols. I-IV, December 1987 (EPA 530/SW-87-001). This unit is regulated by Section 3004(u) of the 1984 Hazardous and Solid Waste Amendments (HSWA) to the Resource Conservation Recovery Act (RCRA). Contained within this document are geographical, historical, operational, geological, and hydrological data specific to the K-1004 ALD and the K-1007-B Pond. The potential for release of contamination through the various media to receptors is addressed. A sampling plan is proposed to further determine the extent (if any) of release of contamination to the surrounding environment. Included are health and safety procedures to be followed when implementing the sampling plan. Quality control (QC) procedures for remedial action occurring on the Oak Ridge Reservation (ORR) are presented in 'The Environmental Surveillance Procedures Quality Control Program, Martin Marietta Energy Systems, Inc., (ESH/Sub/87-21706/1), and quality assurance (QA) guidelines for ORGDP investigations are contained in The K-25 Remedial Actions Program Quality Assurance Plan, K/HS-231.

  10. New porous titanium–niobium oxide for photocatalytic degradation of bromocresol green dye in aqueous solution

    SciTech Connect (OSTI)

    Chaleshtori, Maryam Zarei; Hosseini, Mahsa; Edalatpour, Roya; Masud, S.M. Sarif; Chianelli, Russell R.

    2013-10-15

    Graphical abstract: The photocatalytic activity of different porous titanium–niobium oxides was evaluated toward degradation of bromocresol green (BG) under UV light. A better catalytic activity was observed for all samples at lower pH. Catalysts have a stronger ability for degradation of BG in acid media than in alkaline media. - Highlights: • Different highly structured titanium–niobium oxides have been prepared using improved methods of synthesis. • Photo-degradation of bromocresol green dye (BG) with nanostructure titanium–niobium oxide catalysts was carried out under UV light. • The photo-catalytic activity of all catalysts was higher in lower pH. • Titanium–niobium oxide catalysts are considerably stable and reusable. - Abstract: In this study, high surface area semiconductors, non porous and porous titanium–niobium oxides derived from KTiNbO{sub 5} were synthesized, characterized and developed for their utility as photocatalysts for decontamination with sunlight. These materials were then used in the photocatalytic degradation of bromocresol green dye (BG) in aqueous solution using UV light and their catalytic activities were evaluated at various pHs. For all catalysts, the photocatalytic degradation of BG was most efficient in acidic solutions. Results show that the new porous oxides have large porous and high surface areas and high catalytic activity. A topotactic dehydration treatment greatly improves catalyst performance at various pHs. Stability and long term activity of porous materials (topo and non-topo) in photocatalysis reactions was also tested. These results suggest that the new materials can be used to efficiently purify contaminated water.

  11. Wave functions of the super-Tonks-Girardeau gas and the trapped one-dimensional hard-sphere Bose gas

    SciTech Connect (OSTI)

    Girardeau, M. D.; Astrakharchik, G. E.

    2010-06-15

    Recent theoretical and experimental results demonstrate a close connection between the super-Tonks-Girardeau (STG) gas and a one-dimensional (1D) hard-sphere Bose (HSB) gas with hard-sphere diameter nearly equal to the 1D scattering length a{sub 1D} of the STG gas, a highly excited gaslike state with nodes only at interparticle separations |x{sub jl}|=x{sub node{approx_equal}}a{sub 1D}. It is shown herein that when the coupling constant g{sub B} in the Lieb-Liniger interaction g{sub B{delta}}(x{sub jl}) is negative and |x{sub 12}|{>=}x{sub node}, the STG and HSB wave functions for N=2 particles are not merely similar, but identical; the only difference between the STG and HSB wave functions is that the STG wave function allows a small penetration into the region |x{sub 12}|hs}=x{sub node}, the HSB wave function vanishes when |x{sub 12}|hs}. Arguments are given suggesting that the same theorem holds also for N>2. The STG and HSB wave functions for N=2 are given exactly in terms of a parabolic cylinder function, and for N{>=}2, x{sub node} is given accurately by a simple parabola. The metastability of the STG phase generated by a sudden change of the coupling constant from large positive to large negative values is explained in terms of the very small overlap between the ground state of the Tonks-Girardeau gas and collapsed cluster states.

  12. Electrodic voltages in the presence of dissolved sulfide: Implications for monitoring natural microbial activity

    SciTech Connect (OSTI)

    Slater, L.; Ntarlagiannis, D.; Yee, N.; O'Brien, M.; Zhang, C.; Williams, K. H.

    2008-10-01

    There is growing interest in the development of new monitoring strategies for obtaining spatially extensive data diagnostic of microbial processes occurring in the earth. Open-circuit potentials arising from variable redox conditions in the fluid local-to-electrode surfaces (electrodic potentials) were recorded for a pair of silver-silver chloride electrodes in a column experiment, whereby a natural wetland soil containing a known community of sulfate reducers was continuously fed with a sulfate-rich nutrient medium. Measurements were made between five electrodes equally spaced along the column and a reference electrode placed on the column inflow. The presence of a sulfate reducing microbial population, coupled with observations of decreasing sulfate levels, formation of black precipitate (likely iron sulfide),elevated solid phase sulfide, and a characteristic sulfurous smell, suggest microbial-driven sulfate reduction (sulfide generation) in our column. Based on the known sensitivity of a silver electrode to dissolved sulfide concentration, we interpret the electrodic potentials approaching 700 mV recorded in this experiment as an indicator of the bisulfide (HS-) concentration gradients in the column. The measurement of the spatial and temporal variation in these electrodic potentials provides a simple and rapid method for monitoring patterns of relative HS- concentration that are indicative of the activity of sulfate-reducing bacteria. Our measurements have implications both for the autonomous monitoring of anaerobic microbial processes in the subsurface and the performance of self-potential electrodes, where it is critical to isolate, and perhaps quantify, electrochemical interfaces contributing to observed potentials.

  13. The reduction of Np(VI) and Pu(VI) by organic chelating agents.

    SciTech Connect (OSTI)

    Reed, D.T.; Aase, S.B.; Banaszak, J.E.

    1998-03-19

    The reduction of NpO{sup 2+} and PuO{sub 2}{sup 2+} by oxalate. citrate, and ethylenediaminetetraacetic acid (EDTA) was investigated in low ionic strength media and brines. This was done to help establish the stability of the An(VI) oxidation state in the presence of organic complexants. The stability of the An(VI) oxidation state depended on the pH and relative strength of the various oxidation state-specific complexes. At low ionic strength and pH 6, NpO{sub 2}O{sup 2+} was rapidly reduced to form NpO{sub 2}{sup +} organic complexes. At longer times, Np(IV) organic complexes were observed in the presence of citrate. PuO{sub 2}{sup 2+} was predominantly reduced to Pu{sup 4+}, resulting in the formation of organic complexes or polymeric/hydrolytic precipitates. The relative rates of reduction to the An(V) complex were EDTA > citrate > oxalate. Subsequent reduction to An(IV) complexes, however, occurred in the following order: citrate > EDTA > oxalate because of the stability of the An(V)-EDTA complex. The presence of organic complexants led to the rapid reduction of NpO{sub 2}{sup 2+} and PuO{sub 2}P{sup 2+} in G-seep brine at pHs 5 and 7. At pHs 8 and 10 in ERDA-6 brine, carbonate and hydrolytic complexes predominated and slowed down or prevented the reduction of An(VI) by the organics present.

  14. Warming and glacier recession in the Rakaia valley, Southern Alps of New Zealand, during Heinrich Stadial 1

    SciTech Connect (OSTI)

    Aaron E. Putnam; Joerg M. Schaefe; George H .Denton; DavidJ. A. Barrell; Bjørn G. Andersen; Tobias N.B. Koffman; Ann V. Rowan; Robert C. Finkel; Dylan H. Rood; Roseanne Schwartz; Marcus J. Vandergoes; Mitchell A. Plummer; Simon H. Brocklehurst; Samuel E. Kelley; Kathryn L. Ladig

    2013-11-01

    Front (STF) south of Australia between approximately 17,800 and approximately 16,000 yrs ago coincides with the warming over the Rakaia valley, and suggests a close link between Southern Ocean frontal boundary positions and southern mid-latitude climate. Most of the deglacial warming in the Southern Alps occurred during the early part of Heinrich Stadial 1 (HS1) of the North Atlantic region. Because the STF is associated with the position of the westerly wind belt, our findings support the concept that a southward shift of Earth's wind belts accompanied the early part of HS1 cooling in the North Atlantic, leading to warming and deglaciation in southern middle latitudes.

  15. Infant sex-specific placental cadmium and DNA methylation associations

    SciTech Connect (OSTI)

    Mohanty, April F.; Farin, Fred M.; Bammler, Theo K.; MacDonald, James W.; Afsharinejad, Zahra; Burbacher, Thomas M.; Siscovick, David S.; and others

    2015-04-15

    Background: Recent evidence suggests that maternal cadmium (Cd) burden and fetal growth associations may vary by fetal sex. However, mechanisms contributing to these differences are unknown. Objectives: Among 24 maternal-infant pairs, we investigated infant sex-specific associations between placental Cd and placental genome-wide DNA methylation. Methods: We used ANOVA models to examine sex-stratified associations of placental Cd (dichotomized into high/low Cd using sex-specific Cd median cutoffs) with DNA methylation at each cytosine-phosphate-guanine site or region. Statistical significance was defined using a false discovery rate cutoff (<0.10). Results: Medians of placental Cd among females and males were 5 and 2 ng/g, respectively. Among females, three sites (near ADP-ribosylation factor-like 9 (ARL9), siah E3 ubiquitin protein ligase family member 3 (SIAH3), and heparin sulfate (glucosamine) 3-O-sulfotransferase 4 (HS3ST4) and one region on chromosome 7 (including carnitine O-octanoyltransferase (CROT) and TP5S target 1 (TP53TG1)) were hypomethylated in high Cd placentas. Among males, high placental Cd was associated with methylation of three sites, two (hypomethylated) near MDS1 and EVI1 complex locus (MECOM) and one (hypermethylated) near spalt-like transcription factor 1 (SALL1), and two regions (both hypomethylated, one on chromosome 3 including MECOM and another on chromosome 8 including rho guanine nucleotide exchange factor (GEF) 10 (ARHGEF10). Differentially methylated sites were at or close to transcription start sites of genes involved in cell damage response (SIAH3, HS3ST4, TP53TG1) in females and cell differentiation, angiogenesis and organ development (MECOM, SALL1) in males. Conclusions: Our preliminary study supports infant sex-specific placental Cd-DNA methylation associations, possibly accounting for previously reported differences in Cd-fetal growth associations across fetal sex. Larger studies are needed to replicate and extend these

  16. Polybrominated diphenyl ethers in e-waste: Level and transfer in a typical e-waste recycling site in Shanghai, Eastern China

    SciTech Connect (OSTI)

    Li, Yue; Duan, Yan-Ping, E-mail: duanyanping@tongji.edu.cn; Huang, Fan; Yang, Jing; Xiang, Nan; Meng, Xiang-Zhou; Chen, Ling

    2014-06-01

    Highlights: PBDEs were detected in the majority of e-waste. PBDEs were found in TVs made in China after 1990. The levels of ?PBDEs in e-waste made in Japan far exceed the threshold limit of RoHS. The inappropriate recycling and disposal of e-waste is an important source of PBDEs. - Abstract: Very few data for polybrominated diphenyl ethers (PBDEs) were available in the electronic waste (e-waste) as one of the most PBDEs emission source. This study reported concentrations of PBDEs in e-waste including printer, rice cooker, computer monitor, TV, electric iron and water dispenser, as well as dust from e-waste, e-waste dismantling workshop and surface soil from inside and outside of an e-waste recycling plant in Shanghai, Eastern China. The results showed that PBDEs were detected in the majority of e-waste, and the concentrations of ?PBDEs ranged from not detected to 175 g/kg, with a mean value of 10.8 g/kg. PBDEs were found in TVs made in China after 1990. The mean concentrations of ?PBDEs in e-waste made in Korea, Japan, Singapore and China were 1.84 g/kg, 20.5 g/kg, 0.91 g/kg, 4.48 g/kg, respectively. The levels of ?PBDEs in e-waste made in Japan far exceed the threshold limit of RoHS (1.00 g/kg). BDE-209 dominated in e-waste, accounting for over 93%. The compositional patterns of PBDEs congeners resembled the profile of Saytex 102E, indicating the source of deca-BDE. Among the samples of dust and surface soil from a typical e-waste recycling site, the highest concentrations of ?{sub 18}PBDEs and BDE-209 were found in dust in e-waste, ranging from 1960 to 340,710 ng/g and from 910 to 320,400 ng/g, which were 12 orders of magnitude higher than other samples. It suggested that PBDEs released from e-waste via dust, and then transferred to surrounding environment.

  17. Scanning ARM Cloud Radars. Part II: Data Quality Control and Processing

    SciTech Connect (OSTI)

    Kollias, Pavlos; Jo, Ieng; Borque, Paloma; Tatarevic, Aleksandra; Lamer, Katia; Bharadwaj, Nitin; Widener, Kevin B.; Johnson, Karen L.; Clothiaux, Eugene E.

    2014-03-01

    The Scanning ARM Cloud Radars (SACRs) are the primary instruments for documenting the four-dimensional structure and evolution of clouds within a 20-30 km radius from the ARM fixed and mobile sites. Here, the post-processing of the calibrated SACR measurements is discussed. First, a feature mask algorithm that objectively determines the presence of significant radar returns is described. The feature mask algorithm is based on the statistical properties of radar receiver noise. It accounts for atmospheric emission and is applicable even for SACR profiles with few or no signal-free range gates. Using the nearest-in-time atmospheric sounding, the SACR radar reflectivities are corrected for gaseous attenuation (water vapor and oxygen) using a line-by-line absorption model. Despite having a high pulse repetition frequency, the SACR has a narrow Nyquist velocity limit and thus Doppler velocity folding is commonly observed. An unfolding algorithm that makes use of a first guess for the true Doppler velocity using horizontal wind measurements from the nearest sounding is described. The retrieval of the horizontal wind profile from the HS-RHI SACR scan observations and/or nearest sounding is described. The retrieved horizontal wind profile can be used to adaptively configure SACR scan strategies that depend on wind direction. Several remaining challenges are discussed, including the removal of insect and second-trip echoes. The described algorithms significantly enhance SACR data quality and constitute an important step towards the utilization of SACR measurements for cloud research.

  18. THE SENSITIVITY OF CARBON STEELS' SUSCEPTIBILITY TO LOCALIZED CORROSION TO THE PH OF NITRATE BASED NUCLEAR WASTES

    SciTech Connect (OSTI)

    BOOMER KD

    2010-01-14

    The Hanford tank reservation contains approximately 50 million gallons of liquid legacy radioactive waste from cold war weapons production, which is stored in 177 underground storage tanks. The tanks will be in use until waste processing operations are completed. The wastes tend to be high pH (over 10) and nitrate based. Under these alkaline conditions carbon steels tend to be passive and undergo relatively slow uniform corrosion. However, the presence of nitrate and other aggressive species, can lead to pitting and stress corrosion cracking. This work is a continuation of previous work that investigated the propensity of steels to suffer pitting and stress corrosion cracking in various waste simulants. The focus of this work is an investigation of the sensitivity of the steels' pitting and stress corrosion cracking susceptibility tosimulant pH. Previous work demonstrated that wastes that are high in aggressive nitrate and low in inhibitory nitrite are susceptible to localized corrosion. However, the previous work involved wastes with pH 12 or higher. The current work involves wastes with lower pH of 10 or 11. It is expected that at these lower pHs that a higher nitrite-to-nitrate ratio will be necessary to ensure tank integrity. This experimental work involved both electrochemical testing, and slow strain rate testing at either the free corrosion potential or under anodic polarization. The results of the current work will be discussed, and compared to work previously presented.

  19. Electronic structure and electron-phonon coupling in TiH$_2$

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shanavas, Kavungal Veedu; Lindsay, Lucas R.; Parker, David S.

    2016-06-15

    Calculations using first principles methods and strong coupling theory are carried out to understand the electronic structure and superconductivity in cubic and tetragonal TiHmore » $_2$. A large electronic density of states at the Fermi level in the cubic phase arises from Ti-$$t_{2g}$$ states and leads to a structural instability against tetragonal distortion at low temperatures. However, constraining the in-plane lattice constants diminishes the energy gain associated with the tetragonal distortion, allowing the cubic phase to be stable at low temperatures. Furthermore, calculated phonon dispersions show decoupled acoustic and optic modes arising from Ti and H vibrations, respectively and frequencies of optic modes to be rather high. The cubic phase has a large electron-phonon coupling parameter $$\\lambda$$ and critical temperature of several K. Contribution of the hydrogen sublattice to $$\\lambda$$ is found to be small in this material, which we understand from strong coupling theory to be due to the small H-$s$ DOS at the Fermi level and high energy of hydrogen modes at the tetrahedral sites.« less

  20. Technical reference book for the Energy Economic Data Base Program (EEDB)

    SciTech Connect (OSTI)

    Not Available

    1986-12-01

    This distribution is the latest in a series published since 1978. The overall program purpose is to provide periodically updated, detailed base construction cost estimates for large nuclear electric operating plants. These data, which are representative of current US powerplant construction cost experience, are a useful contribution to program planning by the Office of the Assistant Secretary for Nuclear Energy. The eighth update incorporates the results of a comprehensive update of the technical and cost information for the pressurized water reactor (PWR), large scale prototype breeder reactor nuclear powerplant (LSPB), and 488 MWe high sulfur, coal-fired powerplant (HS5) data models. During the Phase VIII update, the LSPB, which was first incorporated into the previous update, was brought into full conformance with EEDB ground rules, and the level of detail of the data models was extended to the EEDB fully detailed level. We remind the user that the LSPB must still be considered a second-of-a-kind, pre-commercial unit, and any comparisons of it with other EEDB data models should be carefully made recognizing dissimilarity achievement of design and cost maturity, particularly for the nuclear steam supply system and other equipment.

  1. Release of aged contaminants from weathered sediments: Effects of sorbate speciation on scaling of reactive transport

    SciTech Connect (OSTI)

    Chorover, Jon; Perdrial, Nico; Mueller, Karl; Strepka, Caleb; O???¢????????Day, Peggy; Rivera, Nelson; Um, Wooyong; Chang, Hyun-Shik; Steefel, Carl; Thompson, Aaron

    2012-11-05

    Hanford sediments impacted by hyperalkaline high level radioactive waste have undergone incongruent silicate mineral weathering concurrent with contaminant uptake. In this project, we studied the impact of background pore water (BPW) on strontium, cesium and iodine desorption and transport in Hanford sediments that were experimentally weathered by contact with simulated hyperalkaline tank waste leachate (STWL) solutions. Using those lab-weathered Hanford sediments (HS) and model precipitates formed during nucleation from homogeneous STWL solutions (HN), we (i) provided thorough characterization of reaction products over a matrix of field-relevant gradients in contaminant concentration, partial pressure of carbon dioxide, and reaction time; (ii) improved molecular-scale understanding of how sorbate speciation controls contaminant desorption from weathered sediments upon removal of caustic sources; and (iii) developed a mechanistic, predictive model of meso- to field-scale contaminant reactive transport under these conditions. In this final report, we provide detailed descriptions of our results from this three-year study, completed in 2012 following a one-year no cost extension.

  2. Measurements of Direct CP Violation, CPT Symmetry, and Other Parameters in the Neutral Kaon System

    SciTech Connect (OSTI)

    Worcester, Elizabeth Turner; /Chicago U.

    2007-12-01

    The authors present precision measurements of the direct CP violation parameter, Re({epsilon}{prime}/{epsilon}), the kaon parameters, {Delta}m and {tau}{sub S}, and the CPT tests, {phi}{sub {+-}} and {Delta}{phi}, in neutral kaon decays. These results are based on the full dataset collected by the KTeV experiment at Fermi National Accelerator Laboratory during 1996, 1997, and 1999. This dataset contains {approx} 15 million K {yields} {pi}{sup 0}{pi}{sup 0} decays and {approx} 69 million K {yields} {pi}{sup +}{pi}{sup -} decays. They describe significant improvements to the precision of these measurements relative to previous KTeV analyses. They find Re({epsilon}{prime}/{epsilon}) = [19.2 {+-} 1.1(stat) {+-} 1.8(syst)] x 10{sup -4}, {Delta}m = (5265 {+-} 10) x 10{sup 6} hs{sup -1}, and {tau}{sub S} = (89.62 {+-} 0.05) x 10{sup -12} s. They measure {phi}{sub {+-}} = (44.09 {+-} 1.00){sup o} and {Delta}{phi} = (0.29 {+-} 0.31){sup o}; these results are consistent with CPT symmetry.

  3. Hazardous Substance Release Reporting Under CERCLA, EPCR {section}304 and DOE Emergency Management System (EMS) and DOE Occurrence Reporting Requirements. Environmental Guidance

    SciTech Connect (OSTI)

    Traceski, T.T.

    1994-06-01

    Releases of various substances from DOE facilities may be subject to reporting requirements under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) and the Emergency Planning and Community Right-to-Know Act (EPCRA), as well as DOE`s internal ``Occurrence Reporting and Processing of Operations Information`` and the ``Emergency Management System`` (EMS). CERCLA and EPCPA are Federal laws that require immediate reporting of a release of a Hazardous Substance (HS) and an Extremely Hazardous Substance (EHS), respectively, in a Reportable Quantity (RQ) or more within a 24-hour period. This guidance uses a flowchart, supplemental information, and tables to provide an overview of the process to be followed, and more detailed explanations of the actions that must be performed, when chemical releases of HSs, EHSs, pollutants, or contaminants occur at DOE facilities. This guidance should be used in conjunction with, rather than in lieu of, applicable laws, regulations, and DOE Orders. Relevant laws, regulations, and DOE Orders are referenced throughout this guidance.

  4. Final Technical Report on STTR Project DE-FG02-04ER86191 Hydrogen Cryostat for Muon Beam Cooling

    SciTech Connect (OSTI)

    Johnson, Rolland P.

    2008-05-07

    The project was to develop cryostat designs that could be used for muon beam cooling channels where hydrogen would circulate through refrigerators and the beam-cooling channel to simultaneously refrigerate 1) high-temperature-superconductor (HTS) magnet coils, 2) cold copper RF cavities, and 3) the hydrogen that is heated by the muon beam. In an application where a large amount of hydrogen is naturally present because it is the optimum ionization cooling material, it was reasonable to explore its use with HTS magnets and cold, but not superconducting, RF cavities. In this project we developed computer programs for simulations and analysis and conducted experimental programs to examine the parameters and technological limitations of the materials and designs of Helical Cooling Channel (HCC) components (magnet conductor, RF cavities, absorber windows, heat transport, energy absorber, and refrigerant).The project showed that although a hydrogen cryostat is not the optimum solution for muon ionization cooling channels, the studies of the cooling channel components that define the cryostat requirements led to fundamental advances. In particular, two new lines of promising development were opened up, regarding very high field HTS magnets and the HS concept, that have led to new proposals and funded projects.

  5. Influence of surface modification adopting thermal treatments on dispersion of detonation nanodiamond

    SciTech Connect (OSTI)

    Xu Xiangyang . E-mail: xiangyang.xu@sohu.com; Yu Zhiming; Zhu Yongwei; Wang Baichun

    2005-03-15

    In order to improve the dispersion of detonation nanodiamonds (ND) in aqueous and non-aqueous media, a series of thermal treatments have been conducted in air ambient to modify ND surface. Small angle X-ray scattering (SAXS) technique and high resolution transmission electron microscopy (HRTEM) were introduced to observe the primary size of ND. Differential thermal analysis (DTA), X-ray diffraction (XRD) methodology, X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared (FTIR) spectroscopy were adopted to analyze the structure, bonds at surfaces of the treated ND. Malvern instrument Zetasizer3000HS was used for measuring the surface electric potential and the size distribution of ND. As thermal treatments can cause graphitization and oxidization of functional groups at the surface, ND treated at high temperature is correspondingly more negatively charged in an aqueous medium, and the increased absolute value of zeta potential ensures the electrostatic stability of ND particles. Specially, after being treated at a temperature more than 850K, ND can be well dispersed in various media.

  6. INTEGRAL SPI observations of Cygnus X-1 in the soft state: What about the jet contribution in hard X-rays?

    SciTech Connect (OSTI)

    Jourdain, E.; Roques, J. P.; Chauvin, M.

    2014-07-01

    During the first 7 yr of the INTEGRAL mission (2003-2009), Cyg X-1 has essentially been detected in its hard state (HS), with some incursions in intermediate HSs. This long, spectrally stable period allowed in particular the measurement of the polarization of the high-energy component that has long been observed above 200 keV in this peculiar object. This result strongly suggests that here we see the contribution of the jet, known to emit a strong synchrotron radio emission. In 2010 June, Cyg X-1 underwent a completed transition toward a soft state (SS). It gave us the unique opportunity to study in detail the corona emission in this spectral state, and to investigate in particular the behavior of the jet contribution. Indeed, during the SS, the hard X-ray emission decreases drastically, with its maximum energy shifted toward lower energy and its flux divided by a factor of ?5-10. Interestingly, the radio emission follows a similar drop, supporting the correlation between the jet emission and the hard component, even though the flux is too low to quantify the polarization characteristics.

  7. Evaluation of GafChromic EBT prototype B for external beam dose verification

    SciTech Connect (OSTI)

    Todorovic, M.; Fischer, M.; Cremers, F.; Thom, E.; Schmidt, R.

    2006-05-15

    The capability of the new GafChromic EBT prototype B for external beam dose verification is investigated in this paper. First the general characteristics of this film (dose response, postirradiation coloration, influence of calibration field size) were derived using a flat-bed scanner. In the dose range from 0.1 to 8 Gy, the sensitivity of the EBT prototype B film is ten times higher than the response of the GafChromic HS, which so far was the GafChromic film with the highest sensitivity. Compared with the Kodak EDR2 film, the response of the EBT is higher by a factor of 3 in the dose range from 0.1 to 8 Gy. The GafChromic EBT almost does not show a temporal growth of the optical density and there is no influence of the chosen calibration field size on the dose response curve obtained from this data. A MatLab program was written to evaluate the two-dimensional dose distributions from treatment planning systems and GafChromic EBT film measurements. Verification of external beam therapy (SRT, IMRT) using the above-mentioned approach resulted in very small differences between the planned and the applied dose. The GafChromic EBT prototype B together with the flat-bed scanner and MatLab is a successful approach for making the advantages of the GafChromic films applicable for verification of external beam therapy.

  8. University of Massachusetts Marine Renewable Energy Center Waverider Bouy Data

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Lohrenz, Steven

    2015-10-07

    The compressed (.zip) file contains Datawell MK-III Directional Waverider binary and unpacked data files as well as a description of the data and manuals for the instrumentation. The data files are contained in the two directories within the zip file, ''Apr_July_2012'' and ''Jun_Sept_2013''. Time series and summary data were recorded in the buoy to binary files with extensions '.RDT' and '.SDT', respectively. These are located in the subdirectories 'Data_Raw' in each of the top-level deployment directories. '.RDT' files contain 3 days of time series (at 1.28 Hz) in 30 minute "bursts". Each '.SDT' file contains summary statistics for the month indicated computed at half-hour intervals for each burst. Each deployment directory also contains a description (in 'File.list') of the Datawell binary data files, and a figure ('Hs_vs_yearday') showing the significant wave height associated with each .RDT file (decoded from the filename). The corresponding unpacked Matlab .mat files are contained in the subdirectories 'Data_Mat'. These files have the extension '.mat' but use the root filename of the source .RDT and .SDT files.

  9. KPNA7, a nuclear transport receptor, promotes malignant properties of pancreatic cancer cells in vitro

    SciTech Connect (OSTI)

    Laurila, Eeva; Vuorinen, Elisa; Savinainen, Kimmo; Rauhala, Hanna; Kallioniemi, Anne

    2014-03-10

    Pancreatic cancer is an aggressive malignancy and one of the leading causes of cancer deaths. The high mortality rate is mostly due to the lack of appropriate tools for early detection of the disease and a shortage of effective therapies. We have previously shown that karyopherin alpha 7 (KPNA7), the newest member of the alpha karyopherin family of nuclear import receptors, is frequently amplified and overexpressed in pancreatic cancer. Here, we report that KPNA7 expression is absent in practically all normal human adult tissues but elevated in several pancreatic cancer cell lines. Inhibition of KPNA7 expression in AsPC-1 and Hs700T pancreatic cancer cells led to a reduction in cell growth and decreased anchorage independent growth, as well as increased autophagy. The cell growth effects were accompanied by an induction of the cell cycle regulator p21 and a G1 arrest of the cell cycle. Interestingly, the p21 induction was caused by increased mRNA synthesis and not defective nuclear transport. These data strongly demonstrate that KPNA7 silencing inhibits the malignant properties of pancreatic cancer cells in vitro and thereby provide the first evidence on the functional role for KPNA7 in human cancer. - Highlights: KPNA7 expression is elevated in several pancreatic cancer cell lines. KPNA7 silencing in high expressing cancer cells leads to growth inhibition. The cell growth reduction is associated with p21 induction and G1 arrest. KPNA7 silencing is also accompanied with increased autophagy.

  10. Conducting targets for /sup -/p production of ACOL past experience and prospects

    SciTech Connect (OSTI)

    Eaton, T.W.; Hancock, S.; Johnson, C.D.; Jones, E.; Maury, S.; Milner, S.; Schnuriger, J.C.; Sherwood, T.R.

    1985-10-01

    The Antiproton Collector (ACOL) project at CERN calls for a production target providing at least twice as many antiprotons into a given acceptance as the present passive target. The pulsed target under study must be able to withstand large current pulses of a hundred kiloamperes or more for 10 to 20 ..mu..s whilst at the same time it is hit by the proton beam of up to 2 X 10/sup 13/ ppp. Because of the very high radioactivity of the target region this new device should show a sufficient reliability before it hS put into operation. Previous experimental work with an active target, both in the laboratory and in the AA proton beam line, has shown that such a target gives a measured gain of 50% in the /sup -/p production yield, although the problem of making an assembly to withstand many weeks of pulsing has not been solved. A comparison of the main features of the four tests made in the AA is given. The mechanical and thermal behavior of a conducting metallic, solid or liquid target is studied, with particular emphasis on the shock wave, the thermal expansion and the magnetic unstable pinch effects, by means of computer calculations. A preliminary design of a metal conducting target is reported.

  11. Hydration of a low-alkali CEM III/B-SiO{sub 2} cement (LAC)

    SciTech Connect (OSTI)

    Lothenbach, Barbara; Le Saout, Gwenn; Ben Haha, Mohsen; Figi, Renato; Wieland, Erich

    2012-02-15

    The hydration of a low-alkali cement based on CEM III/B blended with 10 wt.% of nanosilica has been studied. The nanosilica reacted within the first days and 90% of the slag reacted within 3.5 years. C-S-H (Ca/Si {approx} 1.2, Al/Si {approx} 0.12), calcite, hydrotalcite, ettringite and possibly straetlingite were the main hydrates. The pore water composition revealed ten times lower alkali concentrations than in Portland cements. Reducing conditions (HS{sup -}) and a pH value of 12.2 were observed. Between 1 month and 3.5 years of hydration more hydrates were formed due to the ongoing slag reaction but no significant differences in the composition of the pore solution or solid phase assemblage were observed. On the basis of thermodynamic calculations it is predicted that siliceous hydrogarnet could form in the long-term and, in the presence of siliceous hydrogarnet, also thaumasite. Nevertheless, even after 3.5 year hydration, neither siliceous hydrogarnet nor thaumasite have been observed.

  12. Oracle Database DBFS Hierarchical Storage Overview

    SciTech Connect (OSTI)

    Rivenes, A

    2011-07-25

    The National Ignition Facility (NIF) at the Lawrence Livermore National Laboratory creates large numbers of images during each shot cycle for the analysis of optics, target inspection and target diagnostics. These images must be readily accessible once they are created and available for the 30 year lifetime of the facility. The Livermore Computing Center (LC) runs a High Performance Storage System (HPSS) that is capable of storing NIF's estimated 1 petabyte of diagnostic images at a fraction of what it would cost NIF to operate its own automated tape library. With Oracle 11g Release 2 database, it is now possible to create an application transparent, hierarchical storage system using the LC's HPSS. Using the Oracle DBMS-LOB and DBMS-DBFS-HS packages a SecureFile LOB can now be archived to storage outside of the database and accessed seamlessly through a DBFS 'link'. NIF has chosen to use this technology to implement a hierarchical store for its image based SecureFile LOBs. Using a modified external store and DBFS links, files are written to and read from a disk 'staging area' using Oracle's backup utility. Database external procedure calls invoke OS based scripts to manage a staging area and the transfer of the backup files between the staging area and the Lab's HPSS.

  13. Interstaple Dithiol Cross-Linking in Au(25)(SR)(18) Nanomolecules: A Combined Mass Spectrometric and Computational Study

    SciTech Connect (OSTI)

    Jiang, Deen; Dass, Amala; Tschumper, Gregory; Mattern, Daniell; Van Dornshuld, Eric; Kota, Rajesh; Jupally, Vijay

    2011-01-01

    A systematic study of cross-linking chemistry of the Au{sub 25}(SR){sub 18} nanomolecule by dithiols of varying chain length, HS-(CH2)n-SH where n = 2, 3, 4, 5, and 6, is presented here. Monothiolated Au{sub 25} has six [RSAuSRAuSR] staple motifs on its surface, and MALDI mass spectrometry data of the ligand exchanged clusters show that propane (C3) and butane (C4) dithiols have ideal chain lengths for interstaple cross-linking and that up to six C3 or C4 dithiols can be facilely exchanged onto the cluster surface. Propanedithiol predominately exchanges with two monothiols at a time, making cross-linking bridges, while butanedithiol can exchange with either one or two monothiols at a time. The extent of cross-linking can be controlled by the Au{sub 25}(SR){sub 18} to dithiol ratio, the reaction time of ligand exchange, or the addition of a hydrophobic tail to the dithiol. MALDI MS suggests that during ethane (C2) dithiol exchange, two ethanedithiols become connected by a disulfide bond; this result is supported by density functional theory (DFT) prediction of the optimal chain length for the intrastaple coupling. Both optical absorption spectroscopy and DFT computations show that the electronic structure of the Au{sub 25} nanomolecule retains its main features after exchange of up to eight monothiol ligands.

  14. Inter-staple Dithiol Crosslinking in Au25(SR)18 Nanomolecules: A Combined Mass Spectrometric and Computational Study

    SciTech Connect (OSTI)

    Dass, Amala; Jiang, Deen; Jupally, Vijay; Kota, Rajesh; Mattern, Daniell; Tschumper, Gregory; Van Dornshuld, Eric

    2011-01-01

    A systematic study of cross-linking chemistry of the Au{sub 25}(SR){sub 18} nanomolecule by dithiols of varying chain length, HS-(CH{sub 2}){sub n}-SH where n = 2, 3, 4, 5, and 6, is presented here. Monothiolated Au{sub 25} has six [RSAuSRAuSR] staple motifs on its surface, and MALDI mass spectrometry data of the ligand exchanged clusters show that propane (C3) and butane (C4) dithiols have ideal chain lengths for interstaple cross-linking and that up to six C3 or C4 dithiols can be facilely exchanged onto the cluster surface. Propanedithiol predominately exchanges with two monothiols at a time, making cross-linking bridges, while butanedithiol can exchange with either one or two monothiols at a time. The extent of cross-linking can be controlled by the Au{sub 25}(SR){sub 18} to dithiol ratio, the reaction time of ligand exchange, or the addition of a hydrophobic tail to the dithiol. MALDI MS suggests that during ethane (C2) dithiol exchange, two ethanedithiols become connected by a disulfide bond; this result is supported by density functional theory (DFT) prediction of the optimal chain length for the intrastaple coupling. Both optical absorption spectroscopy and DFT computations show that the electronic structure of the Au{sub 25} nanomolecule retains its main features after exchange of up to eight monothiol ligands.

  15. Demonstration of electronic pattern switching and 10x pattern demagnification in a maskless micro-ion beam reduction lithography system

    SciTech Connect (OSTI)

    Ngo, V.V.; Akker, B.; Leung, K.N.; Noh, I.; Scott, K.L.; Wilde, S.

    2002-05-31

    A proof-of-principle ion projection lithography (IPL) system called Maskless Micro-ion beam Reduction Lithography (MMRL) has been developed and tested at the Lawrence Berkeley National Laboratory (LBNL) for future integrated circuits (ICs) manufacturing and thin film media patterning [1]. This MMRL system is aimed at completely eliminating the first stage of the conventional IPL system [2] that contains the complicated beam optics design in front of the stencil mask and the mask itself. It consists of a multicusp RF plasma generator, a multi-beamlet pattern generator, and an all-electrostatic ion optical column. Results from ion beam exposures on PMMA and Shipley UVII-HS resists using 75 keV H+ are presented in this paper. Proof-of-principle electronic pattern switching together with 10x reduction ion optics (using a pattern generator made of nine 50-{micro}m switchable apertures) has been performed and is reported in this paper. In addition, the fabrication of a micro-fabricated pattern generator [3] on an SOI membrane is also presented.

  16. Free-complement local-Schrdinger-equation method for solving the Schrdinger equation of atoms and molecules: Basic theories and features

    SciTech Connect (OSTI)

    Nakatsuji, Hiroshi Nakashima, Hiroyuki

    2015-02-28

    The free-complement (FC) method is a general method for solving the Schrdinger equation (SE): The produced wave function has the potentially exact structure as the solution of the Schrdinger equation. The variables included are determined either by using the variational principle (FC-VP) or by imposing the local Schrdinger equations (FC-LSE) at the chosen set of the sampling points. The latter method, referred to as the local Schrdinger equation (LSE) method, is integral-free and therefore applicable to any atom and molecule. The purpose of this paper is to formulate the basic theories of the LSE method and explain their basic features. First, we formulate three variants of the LSE method, the AB, HS, and H{sup T}Q methods, and explain their properties. Then, the natures of the LSE methods are clarified in some detail using the simple examples of the hydrogen atom and the Hookes atom. Finally, the ideas obtained in this study are applied to solving the SE of the helium atom highly accurately with the FC-LSE method. The results are very encouraging: we could get the worlds most accurate energy of the helium atom within the sampling-type methodologies, which is comparable to those obtained with the FC-VP method. Thus, the FC-LSE method is an easy and yet a powerful integral-free method for solving the Schrdinger equation of general atoms and molecules.

  17. Adsorption isotherm special study. Final report

    SciTech Connect (OSTI)

    1993-05-01

    The study was designed to identify methods to determine adsorption applicable to Uranium Mill Tailings Remedial Action (UMTRA) Project sites, and to determine how changes in aquifer conditions affect metal adsorption, resulting retardation factors, and estimated contaminant migration rates. EPA and ASTM procedures were used to estimate sediment sorption of U, As, and Mo under varying groundwater geochemical conditions. Aquifer matrix materials from three distinct locations at the DOE UMTRA Project site in Rifle, CO, were used as the adsorbents under different pH conditions; these conditions stimulated geochemical environments under the tailings, near the tailings, and downgradient from the tailings. Grain size, total surface area, bulk and clay mineralogy, and petrography of the sediments were characterized. U and Mo yielded linear isotherms, while As had nonlinear ones. U and Mo were adsorbed strongly on sediments acidified to levels similar to tailings leachate. Changes in pH had much less effect on As adsorption. Mo was adsorbed very little at pH 7-7.3, U was weakly sorbed, and As was moderately sorbed. Velocities were estimated for metal transport at different pHs. Results show that the aquifer materials must be characterized to estimate metal transport velocities in aquifers and to develop groundwater restoration strategies for the UMTRA project.

  18. Spectral induced polarization and electrodic potential monitoring of microbially mediated iron sulfide transformations

    SciTech Connect (OSTI)

    Hubbard, Susan; Personna, Y.R.; Ntarlagiannis, D.; Slater, L.; Yee, N.; O'Brien, M.; Hubbard, S.

    2008-02-15

    Stimulated sulfate-reduction is a bioremediation technique utilized for the sequestration of heavy metals in the subsurface.We performed laboratory column experiments to investigate the geoelectrical response of iron sulfide transformations by Desulfo vibriovulgaris. Two geoelectrical methods, (1) spectral induced polarization (SIP), and (2) electrodic potential measurements, were investigated. Aqueous geochemistry (sulfate, lactate, sulfide, and acetate), observations of precipitates (identified from electron microscopy as iron sulfide), and electrodic potentials on bisulfide ion (HS) sensitive silver-silver chloride (Ag-AgCl) electrodes (630 mV) were diagnostic of induced transitions between an aerobic iron sulfide forming conditions and aerobic conditions promoting iron sulfide dissolution. The SIP data showed 10m rad anomalies during iron sulfide mineralization accompanying microbial activity under an anaerobic transition. These anomalies disappeared during iron sulfide dissolution under the subsequent aerobic transition. SIP model parameters based on a Cole-Cole relaxation model of the polarization at the mineral-fluid interface were converted to (1) estimated biomineral surface area to pore volume (Sp), and (2) an equivalent polarizable sphere diameter (d) controlling the relaxation time. The temporal variation in these model parameters is consistent with filling and emptying of pores by iron sulfide biofilms, as the system transitions between anaerobic (pore filling) and aerobic (pore emptying) conditions. The results suggest that combined SIP and electrodic potential measurements might be used to monitor spatiotemporal variability in microbial iron sulfide transformations in the field.

  19. Femtosecond Measurements Of Size-Dependent Spin Crossover In FeII(pyz)Pt(CN)4 Nanocrystals

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sagar, D. M.; Baddour, Frederick G.; Konold, Patrick; Ullom, Joel; Ruddy, Daniel A.; Johnson, Justin C.; Jimenez, Ralph

    2016-01-07

    We report a femtosecond time-resolved spectroscopic study of size-dependent dynamics in nanocrystals (NCs) of Fe(pyz)Pt(CN)4. We observe that smaller NCs (123 or 78 nm cross section and < 25 nm thickness) exhibit signatures of spin crossover (SCO) with time constants of ~ 5-10 ps whereas larger NCs with 375 nm cross section and 43 nm thickness exhibit a weaker SCO signature accompanied by strong spectral shifting on a ~20 ps time scale. For the small NCs, the fast dynamics appear to result from thermal promotion of residual low-spin states to high-spin states following nonradiative decay, and the size dependence ismore » postulated to arise from differing high-spin vs low-spin fractions in domains residing in strained surface regions. The SCO is less efficient in larger NCs owing to their larger size and hence lower residual LS/HS fractions. Our results suggest that size-dependent dynamics can be controlled by tuning surface energy in NCs with dimensions below ~25 nm for use in energy harvesting, spin switching, and other applications.« less

  20. Selective inhibition of CO sub 2 transport in a cyanobacterium

    SciTech Connect (OSTI)

    Espie, G. (Concordia Univ., Montreal, Quebec (Canada)); Miller, A.; Canvin, D. (Queen's Univ., Kingston, Ontario (Canada))

    1989-04-01

    As determined by mass spectrometry, the active transport of CO{sub 2} was reversibly inhibited by both hydrogen sulfide (H{sub 2}S) and carbonyl sulfide (COS). Carbonyl sulfide was an alternate substrate for the CO{sub 2} transport system and its uptake was inhibited by CO{sub 2} and H{sub 2}S. Uptake of H{sub 2}S was not detected and it was found that H{sub 2}S, rather than HS{sup {minus}}, inhibited CO{sub 2} transport. At concentrations which substantially inhibited CO{sub 2} transport (150 {mu}M), neither H{sub 2}S nor COS inhibited Na{sup +}-dependent HCO{sub 3}{sup {minus}} transport as judged by measurements of chlorophyll a fluorescence yield and photosynthesis. The inhibition of CO{sub 2} transport resulted in the extracellular (CO{sub 2}) rising far above its equilibrium level. This effect was dependent on the presence of Na{sup +} and ongoing HCO{sub 3}{sup {minus}} transport. Inhibition of CO{sub 2} transport by H{sub 2}S and COS was independent of Na{sup +}. These results are interpreted to indicate that CO{sub 2} and HCO{sub 3}{sup {minus}} are transported into the cell by separate carrier systems.

  1. AmeriFlux US-Dk1 Duke Forest-open field

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Novick, Kim [Indiana University; Oishi, Chris [USDA Forest Service; Stoy, Paul [Montana State University

    2016-01-01

    This is the AmeriFlux version of the carbon flux data for the site US-Dk1 Duke Forest-open field. Site Description - The Duke Forest grass field is approximately 480×305 m, dominated by the C3 grass Festuca arundinacea Shreb. (tall fescue) includes minor components of C3 herbs and the C4 grass Schizachyrium scoparium (Michx.) Nash, not considered here. The site was burned in 1979 and is mowed annually during the summer for hay according to local practices. Lai, C.T. and G.G. Katul, 2000, "The dynamic role of root-water uptake in coupling potential to actual transpiration" , Advances in Water Resources, 23, 427-439; Novick , K.A., P. C. Stoy, G. G. Katul, D. S. Ellsworth, M. B. S. Siqueira, J. Juang, R. Oren, 2004, Carbon dioxide and water vapor exchange in a warm temperate grassland, Oecologia, 138, 259-274; Stoy PC, Katul GG, Siqueira MBS, Juang J-Y, McCarthy HR, Oishi AC, Uebelherr JM, Kim H-S, Oren R (2006). Separating the effects of climate and vegetation on evapotranspiration along a successional chronosequence in the southeastern U.S. Global Change Biology 12:2115-2135

  2. Investigating the Hydrolysis Reactions of a Chemical Warfare Agent Surrogate. A Systematic Study using 1H, 13C, 17O, 19F, 31P, and 35Cl NMR Spectroscopy

    SciTech Connect (OSTI)

    Alam, Todd M.; Wilson, Brendan W.

    2015-07-24

    During the summer of 2015, I participated in the DHS HS-STEM fellowship at Sandia National Laboratories (SNL, NM) under the supervision of Dr. Todd M. Alam in his Nuclear Magnetic Resonance (NMR) Spectroscopy research group. While with the group, my main project involved pursing various hydrolysis reactions with Diethyl Chlorophosphate (DECP), a surrogate for the agent Sarin (GB). Specifically, I performed different hydrolysis reactions, monitored and tracked the different phosphorous containing species using phosphorous (31P) NMR spectroscopy. With the data collected, I performed kinetics studies mapping the rates of DECP hydrolysis. I also used the NMR of different nuclei such as 1H, 13C, 17O, and 35Cl to help understand the complexity of the reactions that take place. Finally, my last task at SNL was to work with Insensitive Nuclei Enhanced by Polarization Transfer (INEPT) NMR Spectroscopy optimizing conditions for 19F- 31P filtering NMR experiments.

  3. Acute radiation syndrones and their management

    SciTech Connect (OSTI)

    Cronkite, E.P.

    1988-01-01

    Radiation syndromes produced by large doses of ionizing radiation are divided into three general groups depending on dose of radiation and time after exposure. The CNS syndrome requires many thousands of rad, appears in minutes to hours, and kills within hours to days. The GIS appears after doses of a few hundred to 2000 rad. It is characterized by nausea, vomiting, diarrhea, and disturbances of water and electrolyte metabolism. It has a high mortality in the first week after exposure. Survivors will then experience the HS as a result of marrow aplasia. Depending on dose, survival is possible with antibiotic and transfusion therapy. The relationship of granulocyte depression to mortality in dogs and human beings is illustrated. The role of depth dose pattern of mortality of radiation exposure is described and used as an indication of why air exposure doses may be misleading. The therapy of radiation injury is described based on antibiotics, transfusion therapy, and use of molecular regulators. The limited role of matched allogenic bone marrow transplants is discussed. 52 refs., 13 figs.

  4. CHEMISTRY IN DIFFUSE CLOUDS WITH TRANSIENT MICROSTRUCTURE

    SciTech Connect (OSTI)

    Cecchi-Pestellini, C.; Casu, S.; Williams, D. A.; Viti, S.

    2009-12-01

    Microstructure is observed on many lines of sight in the diffuse interstellar medium, mainly through variations in atomic line absorptions on timescales of a decade or less. This timescale implies that microstructure exists on a size scale comparable with that of the solar system; it is overpressured and transient. Both observations and theory confirm that a specific chemistry occurs in microstructure. We therefore explore a model of diffuse interstellar gas in which the chemistry in diffuse clouds is supplemented by chemistry in many transient and tiny perturbations. These perturbations are here assumed to be of unidentified origin, but it is assumed that ambipolar diffusion occurs within them. For plausible physical parameters, we find that this model can account for the range of molecular column densities observed in diffuse clouds, including species not usually accounted for by conventional models. Some molecular ions, predicted to be generated in the microstructure (including HS{sup +}, CH{sup +} {sub 2}, CH{sup +} {sub 3}, H{sub 2}O{sup +}, and H{sub 3}O{sup +}) but not yet observed in diffuse clouds, should be present at levels that may allow their detection.

  5. Application of principal component analysis (PCA) and improved joint probability distributions to the inverse first-order reliability method (I-FORM) for predicting extreme sea states

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Eckert-Gallup, Aubrey C.; Sallaberry, Cédric J.; Dallman, Ann R.; Neary, Vincent S.

    2016-01-06

    Environmental contours describing extreme sea states are generated as the input for numerical or physical model simulations as a part of the standard current practice for designing marine structures to survive extreme sea states. These environmental contours are characterized by combinations of significant wave height (Hs) and either energy period (Te) or peak period (Tp) values calculated for a given recurrence interval using a set of data based on hindcast simulations or buoy observations over a sufficient period of record. The use of the inverse first-order reliability method (I-FORM) is a standard design practice for generating environmental contours. This papermore » develops enhanced methodologies for data analysis prior to the application of the I-FORM, including the use of principal component analysis (PCA) to create an uncorrelated representation of the variables under consideration as well as new distribution and parameter fitting techniques. As a result, these modifications better represent the measured data and, therefore, should contribute to the development of more realistic representations of environmental contours of extreme sea states for determining design loads for marine structures.« less

  6. A Study on Removal of Iodine, Iodide Ion, and Iodate Ion from Radioactive Wastewater

    SciTech Connect (OSTI)

    Yim, S.P.; Kim, K.R.; Lee, M.S.; Chung, H.; Shim, M.H.; Lee, C.K.

    2006-07-01

    For the two methods to remove iodine, the iodide ion and the iodate ion from radioactive waste water, we proposed previously, the main reactions were experimentally investigated to examine the feasibility of them. One is the reaction of the iodide ion and the iodate ion. In this reaction, it was confirmed that the reaction rate is faster with a pH of less than 2 and, to undergo the reaction faster under the condition of pH 2, an addition of excess iodide ions and iodate ions is necessary. Another is the reduction of the iodate ion and the iodine by pyrite. In the experiment, it was found that when the iodate ion in the solution is in contact with pyrite, it is reduced to iodine on the surface of the pyrite and the produced iodine is consecutively reduced to the iodide ion. The reaction occurred at room temperature under a wide range of pHs. Based on the results of this preliminary study, it is expected that a more substantial method could be prepared for the effective removal of an iodine mixture from radioactive wastewater. (authors)

  7. Interfacial aggregation of a nonionic surfactant: Effect on the stability of silica suspensions

    SciTech Connect (OSTI)

    Giordano-Palmino, F.; Denoyel, R.; Rouquerol, J. . Centre de thermodynamique et Microcalorimetrie)

    1994-06-01

    Nonionic surfactants are in widespread use in technological applications such as flotation, detergency, suspension stabilization (paints, ceramic preparation, pharmaceuticals, cosmetics), and enhanced oil recovery. The adsorption of the nonionic surfactant TX 100 in two silica suspensions (Ludox HS40 and Syton W30) has been studied with the aim of relating the structure of the adsorbed layer to the stability of the suspension. First, a thermodynamic study based on the determination of adsorption isotherms and displacement enthalpies as a function of pH and solid/liquid ratio was carried out and lead to the conclusion that such a surfactant forms micelle-like aggregates on the silica surface. Then, a stability study based on visual observation, turbidimetry, and particle size determination (by photon correlation spectroscopy) was performed in order to determine the TX 100 concentration range in which flocculation occurs. Considering that the surface is covered with micelle-like aggregates in the flocculation range and that the [zeta]-potential (determined by microelectrophoresis) has varied only slightly at the onset of flocculation, it is concluded that the flocculation mechanism is a bridging of particles by surface micelles. This bridging of particles by aggregates similar in size and shape could be an explanation of the presence, in such systems, of optimum flocculation at half surface coverage.

  8. Subsurface Uranium Fate and Transport: Integrated Experiments and Modeling of Coupled Biogeochemical Mechanisms of Nanocrystalline Uraninite Oxidation by Fe(III)-(hydr)oxides - Project Final Report

    SciTech Connect (OSTI)

    Peyton, Brent M. [Montana State University; Timothy, Ginn R. [University of California Davis; Sani, Rajesh K. [South Dakota School of Mines and Technology

    2013-08-14

    have measured elevated U concentrations in oxic iron-rich sediments. To translate experimental results into numerical analysis of U fate and transport, a reaction network was developed based on Sani et al. (2004) to simulate U(VI) bioreduction with concomitant UO2 reoxidation in the presence of hematite or ferrihydrite. The reduction phase considers SRB reduction (using lactate) with the reductive dissolution of Fe(III) solids, which is set to be microbially mediated as well as abiotically driven by sulfide. Model results show the oxidation of HS by Fe(III) directly competes with UO2 reoxidation as Fe(III) oxidizes HS preferentially over UO2. The majority of Fe reduction is predicted to be abiotic, with ferrihydrite becoming fully consumed by reaction with sulfide. Predicted total dissolved carbonate concentrations from the degradation of lactate are elevated (log(pCO2) ~ 1) and, in the hematite system, yield close to two orders-of-magnitude higher U(VI) concentrations than under initial carbonate concentrations of 3 mM. Modeling of U(VI) bioreduction with concomitant reoxidation of UO2 in the presence of ferrihydrite was also extended to a two-dimensional field-scale groundwater flow and biogeochemically reactive transport model for the South Oyster site in eastern Virginia. This model was developed to simulate the field-scale immobilization and subsequent reoxidation of U by a biologically mediated reaction network.

  9. Curvature and ionization-induced reversible hydrogen storage in metalized hexagonal B{sub 36}

    SciTech Connect (OSTI)

    Liu, Chun-Sheng Wang, Xiangfu; Yan, Xiaohong; Ye, Xiao-Juan; Zeng, Zhi

    2014-11-21

    The synthesis of quasiplanar boron clusters (B{sub 36}) with a central hexagonal hole provides the first experimental evidence that a single-atomic-layer borophene with hexagonal vacancies is potentially viable [Z. Piazza, H. Hu, W. Li, Y. Zhao, J. Li, and L. S. Wang, Nat. Commun. 5, 3113 (2014)]. However, owing to the hexagonal holes, tunning the electronic and physical properties of B{sub 36} through chemical modifications is not fully understood. Based on (van der Waals corrected-) density functional theory, we show that Li adsorbed on B{sub 36} and B{sub 36}{sup ?} clusters can serve as reversible hydrogen storage media. The present results indicate that the curvature and ionization of substrates can enhance the bond strength of Li due to the energetically favorable B 2p-Li 2p orbitals hybridization. Both the polarization mechanism and the orbital hybridization between H-s orbitals and Li-2s2p orbitals contribute to the adsorption of H{sub 2} molecules and the resulting adsorption energy lies between the physisorbed and chemisorbed states. Interestingly, the number of H{sub 2} in the hydrogen storage medium can be measured by the appearance of the negative differential resistance behavior at different bias voltage regions. Furthermore, the cluster-assembled hydrogen storage materials constructed by metalized B{sub 36} clusters do not cause a decrease in the number of adsorbed hydrogen molecules per Li. The system reported here is favorable for the reversible hydrogen adsorption/desorption at ambient conditions.

  10. Upgrading RESRAD-RDD and Planning for Improvised Nuclear Device Incidents--The RESRAD-RDD&IND

    Broader source: Energy.gov [DOE]

    Upgrading RESRAD-RDD and Planning for Improvised Nuclear Device Incidents--The RESRAD-RDD&IND Abstract: The RESRAD-RDD code was developed through the interagency Operational Guidelines Task Group (OGT) to assist decision makers, emergency responders, and emergency preparedness planners for response to radiological dispersal device incidents (RDD). The RESRAD-RDD code was released as a companion software tool in 2009 to support the OGT Manual—Preliminary Report on Operational Guidelines Developed for Use in Emergency Preparedness and Response to a Radiological Dispersal Device Incident (DOE/HS-0001). The original RESRAD-RDD code was Microsoft Excel based software with the user interface written in Visual Basic. This version of RESRAD-RDD is being converted to a database driven software that runs on Windows 7 operating system in the .NET environment. The new RESRAD-RDD code is being tested to make sure it reproduces old code results. The new code runs faster than the old spreadsheets code by a factor of 10 or so, fewer clicks are required for the same calculations, operational guidelines can be easily located, and the reports can be written to PDFs instead of HTML. Additional radionuclides are also being added to the new RESRAD-RDD code. An Improvised Nuclear Device (IND) scenario is also being added to the code and about 44 - 60 radionuclides will be added to handle IND incident. A new OGT Task Group is in the process of updating the OGT Manual and providing guidance on the development of the IND scenario and methodology. The new code, RESRAD-RDD&IND is expected to be released in early 2015. Charley Yu*, Argonne National Laboratory ; Carlos Corredor, U.S. Department of Energy; Jing-Jy Cheng, Argonne National Laboratory; Sunita Kamboj, Argonne National Laboratory; David LePoire, Argonne National Laboratory; Paul Flood, Argonne National Laboratory

  11. Optimization of the pyrolysis process of empty fruit bunch (EFB) in a fixed-bed reactor through a central composite design (CCD)

    SciTech Connect (OSTI)

    Mohamed, Alina Rahayu; Hamzah, Zainab; Daud, Mohamed Zulkali Mohamed

    2014-07-10

    The production of crude palm oil from the processing of palm fresh fruit bunches in the palm oil mills in Malaysia hs resulted in a huge quantity of empty fruit bunch (EFB) accumulated. The EFB was used as a feedstock in the pyrolysis process using a fixed-bed reactor in the present study. The optimization of process parameters such as pyrolysis temperature (factor A), biomass particle size (factor B) and holding time (factor C) were investigated through Central Composite Design (CCD) using Stat-Ease Design Expert software version 7 with bio-oil yield considered as the response. Twenty experimental runs were conducted. The results were completely analyzed by Analysis of Variance (ANOVA). The model was statistically significant. All factors studied were significant with p-values < 0.05. The pyrolysis temperature (factor A) was considered as the most significant parameter because its F-value of 116.29 was the highest. The value of R{sup 2} was 0.9564 which indicated that the selected factors and its levels showed high correlation to the production of bio-oil from EFB pyrolysis process. A quadratic model equation was developed and employed to predict the highest theoretical bio-oil yield. The maximum bio-oil yield of 46.2 % was achieved at pyrolysis temperature of 442.15 °C using the EFB particle size of 866 μm which corresponded to the EFB particle size in the range of 710–1000 μm and holding time of 483 seconds.

  12. SU-E-J-104: Evaluation of Accuracy for Various Deformable Image Registrations with Virtual Deformation QA Software

    SciTech Connect (OSTI)

    Han, S; Kim, K; Kim, M; Jung, H; Ji, Y; Choi, S; Park, S

    2015-06-15

    Purpose: The accuracy of deformable image registration (DIR) has a significant dosimetric impact in radiation treatment planning. We evaluated accuracy of various DIR algorithms using virtual deformation QA software (ImSimQA, Oncology System Limited, UK). Methods: The reference image (Iref) and volume (Vref) was first generated with IMSIMQA software. We deformed Iref with axial movement of deformation point and Vref depending on the type of deformation that are the deformation1 is to increase the Vref (relaxation) and the deformation 2 is to decrease the Vref (contraction) .The deformed image (Idef) and volume (Vdef) were inversely deformed to Iref and Vref using DIR algorithms. As a Result, we acquired deformed image (Iid) and volume (Vid). The DIR algorithms were optical flow (HS, IOF) and demons (MD, FD) of the DIRART. The image similarity evaluation between Iref and Iid was calculated by Normalized Mutual Information (NMI) and Normalized Cross Correlation (NCC). The value of Dice Similarity Coefficient (DSC) was used for evaluation of volume similarity. Results: When moving distance of deformation point was 4 mm, the value of NMI was above 1.81 and NCC was above 0.99 in all DIR algorithms. Since the degree of deformation was increased, the degree of image similarity was decreased. When the Vref increased or decreased about 12%, the difference between Vref and Vid was within ±5% regardless of the type of deformation. The value of DSC was above 0.95 in deformation1 except for the MD algorithm. In case of deformation 2, that of DSC was above 0.95 in all DIR algorithms. Conclusion: The Idef and Vdef have not been completely restored to Iref and Vref and the accuracy of DIR algorithms was different depending on the degree of deformation. Hence, the performance of DIR algorithms should be verified for the desired applications.

  13. Vegetation classification in southern pine mixed hardwood forests using airborne scanning laser point data.

    SciTech Connect (OSTI)

    McGaughey, Robert J.; Reutebuch, Stephen E.

    2012-09-01

    Forests of the southeastern United States are dominated by a relatively small number of conifer species. However, many of these forests also have a hardwood component composed of a wide variety of species that are found in all canopy positions. The presence or absence of hardwood species and their position in the canopy often dictates management activities such as thinning or prescribed burning. In addition, the characteristics of the under- and mid-story layers, often dominated by hardwood species, are key factors when assessing suitable habitat for threatened and endangered species such as the Red Cockaded Woodpecker (Picoides borealis) (RCW), making information describing the hardwood component important to forest managers. General classification of cover types using LIDAR data has been reported (Song et al. 2002, Brennan and Webster 2006) but most efforts focusing on the identification of individual species or species groups rely on some type of imagery to provide more complete spectral information for the study area. Brandtberg (2007) found that use of intensity data significantly improved LIDAR detection and classification of three leaf-off deciduous eastern species: oaks (Quercus spp.), red maple (Acer rubrum L.), and yellow poplar (Liriodendron tulipifera L.). Our primary objective was to determine the proportion of hardwood species present in the canopy using only the LIDAR point data and derived products. However, the presence of several hardwood species that retain their foliage through the winter months complicated our analyses. We present two classification approaches. The first identifies areas containing hardwood and softwood (conifer) species (H/S) and the second identifies vegetation with foliage absent or present (FA/FP) at the time of the LIDAR data acquisition. The classification results were used to develop predictor variables for forest inventory models. The ability to incorporate the proportion of hardwood and softwood was important to the

  14. Detailed Characterization of a Nanosecond-Lived Excited State: X-ray and Theoretical Investigation of the Quintet State in Photoexcited [Fe(terpy) 2 ] 2+

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Vanko, Gyorgy; Bordage, Amelie; Papai, Matyas; Haldrup, Kristoffer; Glatzel, Pieter; March, Anne Marie; Doumy, Gilles; Britz, Alexander; Galler, Andreas; Assefa, Tadesse; et al

    2015-03-19

    Theoretical predictions show that depending on the populations of the Fe 3dxy, 3dxz, and 3dyz orbitals two possible quintet states can exist for the high-spin state of the photoswitchable model system [Fe(terpy)2]2+. The differences in the structure and molecular properties of these 5B2 and 5E quintets are very small and pose a substantial challenge for experiments to resolve them. Yet for a better understanding of the physics of this system, which can lead to the design of novel molecules with enhanced photoswitching performance, it is vital to determine which high-spin state is reached in the transitions that follow the lightmore » excitation. The quintet state can be prepared with a short laser pulse and can be studied with cutting-edge time-resolved X-ray techniques. Here we report on the application of an extended set of X-ray spectroscopy and scattering techniques applied to investigate the quintet state of [Fe(terpy)2]2+ 80 ps after light excitation. High-quality X-ray absorption, nonresonant emission, and resonant emission spectra as well as X-ray diffuse scattering data clearly reflect the formation of the high-spin state of the [Fe(terpy)2]2+ molecule; moreover, extended X-ray absorption fine structure spectroscopy resolves the Fe–ligand bond-length variations with unprecedented bond-length accuracy in time-resolved experiments. With ab initio calculations we determine why, in contrast to most related systems, one configurational mode is insufficient for the description of the low-spin (LS)–high-spin (HS) transition. We identify the electronic structure origin of the differences between the two possible quintet modes, and finally, we unambiguously identify the formed quintet state as 5E, in agreement with our theoretical expectations.« less

  15. STUDIES OF THE SPONTANEOUS COMBUSTION OF LOW RANK COALS AND LIGNITES

    SciTech Connect (OSTI)

    Joseph M. Okoh; Joseph N.D. Dodoo

    2005-07-26

    Spontaneous combustion has always been a problem in coal utilization especially in the storage and transportation of coal. In the United States, approximately 11% of underground coal mine fires are attributed to spontaneous coal combustion. The incidence of such fires is expected to increase with increased consumption of lower rank coals. The cause is usually suspected to be the reabsorption of moisture and oxidation. To understand the mechanisms of spontaneous combustion this study was conducted to (1) define the initial and final products during the low temperature (10 to 60 C) oxidation of coal at different partial pressures of O{sub 2}, (2) determine the rate of oxidation, and (3) measure the reaction enthalpy. The reaction rate (R) and propensity towards spontaneous combustion were evaluated in terms of the initial rate method for the mass gained due to adsorbed O{sub 2}. Equipment that was used consisted of a FT-IR (Fourier Transform-Infrared Spectrometer, Perkin Elmer), an accelerated surface area porosimeter (ASAP, Micromeritics model 2010), thermogravimetric analyzer (TGA, Cahn Microbalance TG 121) and a differential scanning calorimeter (DSC, Q1000, thermal analysis instruments). Their combination yielded data that established a relation between adsorption of oxygen and reaction enthalpy. The head space/ gas chromatograph/ mass spectrometer system (HS/GC/MS) was used to identify volatiles evolved during oxidation. The coal samples used were Beulah lignite and Wyodak (sub-bituminous). Oxygen (O{sub 2}) absorption rates ranged from 0.202 mg O{sub 2}/mg coal hr for coal sample No.20 (Beulah pyrolyzed at 300 C) to 6.05 mg O{sub 2}/mg coal hr for coal sample No.8 (wyodak aged and pyrolyzed at 300 C). Aging of coal followed by pyrolysis was observed to contribute to higher reaction rates. Reaction enthalpies ranged from 0.42 to 1580 kcal/gm/mol O{sub 2}.

  16. Spectral content of buried Ag foils at 10{sup 16} W/cm{sup 2} laser illumination

    SciTech Connect (OSTI)

    Huntington, C. M. Maddox, B. R.; Park, H.-S.; Prisbrey, S.; Remington, B. A.

    2014-11-15

    Sources of 5–12 keV thermal Heα x-rays are readily generated by laser irradiation of mid-Z foils at intensities >10{sup 14} W/cm{sup 2}, and are widely used as probes for inertial confinement fusion and high-energy-density experiments. Higher energy 17–50 keV x-ray sources are efficiently produced from “cold” Kα emission using short pulse, petawatt lasers at intensities >10{sup 18} W/cm{sup 2} [H.-S. Park, B. R. Maddox et al., “High-resolution 17–75 keV backlighters for high energy density experiments,” Phys. Plasmas 15(7), 072705 (2008); B. R. Maddox, H. S. Park, B. A. Remington et al., “Absolute measurements of x-ray backlighter sources at energies above 10 keV,” Phys. Plasmas 18(5), 056709 (2011)]. However, when long pulse (>1 ns) lasers are used with Z > 30 elements, the spectrum contains contributions from both K shell transitions and from ionized atomic states. Here we show that by sandwiching a silver foil between layers of high-density carbon, the ratio of Kα:Heα in the x-ray spectrum is significant increased over directly illuminated Ag foils, with narrower lines from K-shell transitions. Additionally, the emission volume is more localized for the sandwiched target, producing a more planar x-ray sheet. This technique may be useful for generating probes requiring spectral purity and a limited spatial extent, for example, in incoherent x-ray Thomson scattering experiments.

  17. A study of shock mitigating materials in a split Hopkins bar configuration. Phase 2

    SciTech Connect (OSTI)

    Bateman, V.I.; Brown, F.A.; Hansen, N.R.

    1997-12-31

    Sandia National Laboratories (SNL) designs mechanical systems with electronics that must survive high shock environments. These mechanical systems include penetrators that must survive soil and rock penetration, nuclear transportation casks that must survive transportation environments, and laydown weapons that must survive delivery impact. These mechanical systems contain electronics that may operate during and after the high shock environment and that must be protected from the high shock environments. A study has been started to improve the packaging techniques for the advanced electronics utilized in these mechanical systems because current packaging techniques are inadequate for these sensitive electronics. In many cases, it has been found that the packaging techniques currently used not only do not mitigate the shock environment but actually amplify the shock environment. An ambitious goal for this packaging study is to avoid amplification and possibly attenuate the shock environment before it reached the electronics contained in the various mechanical systems. Here, a study to compare two thickness values, 0.125 and 0.250 in. of five materials, GE RTV 630, HS II Silicone, Polysulfide Rubber, Sylgard 184, and Teflon for their shock mitigating characteristics with a split Hopkinson bar configuration has been completed. The five materials have been tested in both unconfined and confined conditions at ambient temperature and with two applied loads of 750 {mu}{epsilon} peak (25 fps peak) with a 100 {micro}s duration, measured at 10% amplitude, and 1500 {mu}{epsilon} peak (50 fps peak) with a 100 {micro}s duration, measured at 10% amplitude. The five materials have been tested at ambient, cold ({minus}65 F), and hot (+165 F) for the unconfined condition with the 750 {mu}{epsilon} peak (25 fps peak) applied load. Time domain and frequency domain analyses of the split Hopkinson bar data have been performed to compare how these materials lengthen the shock pulse

  18. Comparison of small photon beams measured using radiochromic and silver-halide films in solid water phantoms

    SciTech Connect (OSTI)

    Zeidan, Omar A.; Li, Jonathan G.; Low, Daniel A.; Dempsey, James F.

    2004-10-01

    In this study, we compared the dosimetric properties of four of the most commonly used films for megavoltage photon-beam dosimetry when irradiated under identical conditions by small multileaf-collimator (MLC) defined beamlets. Two silver-halide films (SHFs), Kodak XV2 and EDR2, and two radiochromic films (RCFs), Gafchromic HS and MD55-2, were irradiated by MLC-defined 1x1 cm{sup 2} beamlets from a Varian 2100 C/D linac equipped with a 120-leaf MLC. The beamlets were delivered with the accelerator gantry set laterally (90 deg. rotation) upon a solid-water compression film phantom at 100 cm source-to-surface distance which was positioned with the films parallel to the beam axis. Beamlets were delivered at central axis, 5.0 cm, and 10.5 cm off-axis for both leaf-end and leaf-side defined beamlets. The film dosimetry was performed using a quantitative optical density (OD) imaging system that was validated in a previous study. No significant differences between SHF and RCF measurements were observed in percentage depth doses, horizontal depth profiles, or two-dimension spatial isodose distributions in both the central axis and off-axis measurements. We found that regardless of the type of film used, RCF or SHF, a consistent data set for small beam dose modeling was generated. Previous validation studies based on the use of RCF and OD imaging system would indicate that all film produce an accurate result for small beam characterization.

  19. User's Guide for RESRAD-OFFSITE

    SciTech Connect (OSTI)

    Gnanapragasam, E.; Yu, C.

    2015-04-01

    The RESRAD-OFFSITE code can be used to model the radiological dose or risk to an offsite receptor. This User’s Guide for RESRAD-OFFSITE Version 3.1 is an update of the User’s Guide for RESRAD-OFFSITE Version 2 contained in the Appendix A of the User’s Manual for RESRAD-OFFSITE Version 2 (ANL/EVS/TM/07-1, DOE/HS-0005, NUREG/CR-6937). This user’s guide presents the basic information necessary to use Version 3.1 of the code. It also points to the help file and other documents that provide more detailed information about the inputs, the input forms and features/tools in the code; two of the features (overriding the source term and computing area factors) are discussed in the appendices to this guide. Section 2 describes how to download and install the code and then verify the installation of the code. Section 3 shows ways to navigate through the input screens to simulate various exposure scenarios and to view the results in graphics and text reports. Section 4 has screen shots of each input form in the code and provides basic information about each parameter to increase the user’s understanding of the code. Section 5 outlines the contents of all the text reports and the graphical output. It also describes the commands in the two output viewers. Section 6 deals with the probabilistic and sensitivity analysis tools available in the code. Section 7 details the various ways of obtaining help in the code.

  20. Emergency Doses (ED) - Revision 3: A calculator code for environmental dose computations

    SciTech Connect (OSTI)

    Rittmann, P.D.

    1990-12-01

    The calculator program ED (Emergency Doses) was developed from several HP-41CV calculator programs documented in the report Seven Health Physics Calculator Programs for the HP-41CV, RHO-HS-ST-5P (Rittman 1984). The program was developed to enable estimates of offsite impacts more rapidly and reliably than was possible with the software available for emergency response at that time. The ED - Revision 3, documented in this report, revises the inhalation dose model to match that of ICRP 30, and adds the simple estimates for air concentration downwind from a chemical release. In addition, the method for calculating the Pasquill dispersion parameters was revised to match the GENII code within the limitations of a hand-held calculator (e.g., plume rise and building wake effects are not included). The summary report generator for printed output, which had been present in the code from the original version, was eliminated in Revision 3 to make room for the dispersion model, the chemical release portion, and the methods of looping back to an input menu until there is no further no change. This program runs on the Hewlett-Packard programmable calculators known as the HP-41CV and the HP-41CX. The documentation for ED - Revision 3 includes a guide for users, sample problems, detailed verification tests and results, model descriptions, code description (with program listing), and independent peer review. This software is intended to be used by individuals with some training in the use of air transport models. There are some user inputs that require intelligent application of the model to the actual conditions of the accident. The results calculated using ED - Revision 3 are only correct to the extent allowed by the mathematical models. 9 refs., 36 tabs.

  1. Independent Review of Simulation of Net Infiltration for Present-Day and Potential Future Climates

    SciTech Connect (OSTI)

    Review Panel: Soroosh Sorooshian, Ph.D., Panel Chairperson, University of California, Irvine; Jan M. H. Hendrickx, Ph.D., New Mexico Institute of Mining and Technology; Binayak P. Mohanty, Ph.D., Texas A&M University; Scott W. Tyler, Ph.D., University of Nevada, Reno; Tian-Chyi Jim Yeh, Ph.D., University of Arizona -- ORISE Review Facilitators: Robert S. Turner, Ph.D., Technical Review Group Manager, Oak Ridge Institute for Science and Education; Brian R. Herndon, Project Manager, Oak Ridge Institute for Science and Education; Russ Manning, Technical Writer /Editor, Haselwood Enterprises, Inc.

    2008-08-30

    The DOE Office of Civilian Radioactive Waste Management (OCRWM) tasked Oak Ridge Institute for Science and Education (ORISE) with providing an independent expert review of the documented model and prediction results for net infiltration of water into the unsaturated zone at Yucca Mountain. The specific purpose of the model, as documented in the report MDL-NBS-HS-000023, Rev. 01, is “to provide a spatial representation, including epistemic and aleatory uncertainty, of the predicted mean annual net infiltration at the Yucca Mountain site ...” (p. 1-1) The expert review panel assembled by ORISE concluded that the model report does not provide a technically credible spatial representation of net infiltration at Yucca Mountain. Specifically, the ORISE Review Panel found that: • A critical lack of site-specific meteorological, surface, and subsurface information prevents verification of (i) the net infiltration estimates, (ii) the uncertainty estimates of parameters caused by their spatial variability, and (iii) the assumptions used by the modelers (ranges and distributions) for the characterization of parameters. The paucity of site-specific data used by the modeling team for model implementation and validation is a major deficiency in this effort. • The model does not incorporate at least one potentially important hydrologic process. Subsurface lateral flow is not accounted for by the model, and the assumption that the effect of subsurface lateral flow is negligible is not adequately justified. This issue is especially critical for the wetter climate periods. This omission may be one reason the model results appear to underestimate net infiltration beneath wash environments and therefore imprecisely represent the spatial variability of net infiltration. • While the model uses assumptions consistently, such as uniform soil depths and a constant vegetation rooting depth, such assumptions may not be appropriate for this net infiltration simulation because they

  2. Energy confinement and magnetic field generation in the SSPX spheromak

    SciTech Connect (OSTI)

    Hudson, B; McLean, H S; Wood, R D; Hooper, E B; Hill, D N; Jayakumar, J; Moller, J; Romero-Talamas, C; Casper, T A; LoDestro, L L; Pearlstein, L D; Johnson, III, J A; Mezonlin, E

    2008-02-11

    The Sustained Spheromak Physics Experiment (SSPX) [E.B. Hooper, et. al., Nuclear Fusion, Vol. 39, No. 7] explores the physics of efficient magnetic field buildup and energy confinement, both essential parts of advancing the spheromak concept. Extending the spheromak formation phase increases the efficiency of magnetic field generation with the maximum edge magnetic field for a given injector current (B/I) from 0.65 T/MA previously to 0.9 T/MA. We have achieved the highest electron temperatures (T{sub e}) recorded for a spheromak with T{sub e} > 500 eV, toroidal magnetic field {approx}1 T and toroidal current ({approx}1 MA) [R.D. Wood, D.N. Hill, H.S. McLean, E.B. Hooper, B.F. Hudson, J.M. Moller, 'Improved magnetic field generation efficiency and higher temperature spheromak plasmas', submitted to Physical Review Letters]. Extending the sustainment phase to > 8 ms extends the period of low magnetic fluctuations (< 1 %) by 50%. The NIMROD 3-D resistive MHD code [C.R. Sovinec, T.A. Gianakon, E.D. Held, S.E. Kruger and D.D. Schnack, The NIMROD Team, Phys. Plasmas 10, 1727 (2003)] reproduces the observed flux amplification {Psi}{sub pol}/{Psi}{sub gun}. Successive gun pulses are demonstrated to maintain the magnetic field in a quasi-steady state against resistive decay. Initial measurements of neutral particle flux in multi-pulse operation show charge-exchange power loss < 1% of gun input power and dominantly collisional majority ion heating. The evolution of electron temperature shows a distinct and robust feature of spheromak formation: a hollow-to-peaked T{sub e}(r) associated with q {approx} 1/2.

  3. An analytical coarse-graining method which preserves the free energy, structural correlations, and thermodynamic state of polymer melts from the atomistic to the mesoscale

    SciTech Connect (OSTI)

    McCarty, J.; Clark, A. J.; Copperman, J.; Guenza, M. G.

    2014-05-28

    Structural and thermodynamic consistency of coarse-graining models across multiple length scales is essential for the predictive role of multi-scale modeling and molecular dynamic simulations that use mesoscale descriptions. Our approach is a coarse-grained model based on integral equation theory, which can represent polymer chains at variable levels of chemical details. The model is analytical and depends on molecular and thermodynamic parameters of the system under study, as well as on the direct correlation function in the k ? 0 limit, c{sub 0}. A numerical solution to the PRISM integral equations is used to determine c{sub 0}, by adjusting the value of the effective hard sphere diameter, d{sub HS}, to agree with the predicted equation of state. This single quantity parameterizes the coarse-grained potential, which is used to perform mesoscale simulations that are directly compared with atomistic-level simulations of the same system. We test our coarse-graining formalism by comparing structural correlations, isothermal compressibility, equation of state, Helmholtz and Gibbs free energies, and potential energy and entropy using both united atom and coarse-grained descriptions. We find quantitative agreement between the analytical formalism for the thermodynamic properties, and the results of Molecular Dynamics simulations, independent of the chosen level of representation. In the mesoscale description, the potential energy of the soft-particle interaction becomes a free energy in the coarse-grained coordinates which preserves the excess free energy from an ideal gas across all levels of description. The structural consistency between the united-atom and mesoscale descriptions means the relative entropy between descriptions has been minimized without any variational optimization parameters. The approach is general and applicable to any polymeric system in different thermodynamic conditions.

  4. Ligand field and intermolecular interactions tuning the magnetic properties of spin-crossover Fe(II) polymer with 4,4′-bipyridine

    SciTech Connect (OSTI)

    Luo, Yang-Hui; Liu, Qing-Ling; Yang, Li-Jing; Ling, Yang; Wang, Wei; Sun, Bai-Wang

    2015-02-15

    A new spin crossover coordination polymer (SCO-CPs) of Fe(II)-4,4′-bipyridine (4,4′-bipy) family: (Fe(4,4′-bipy){sub 2}(H{sub 2}O){sub 2})·(4,4′-bipy)· 8(H{sub 2}O)·2(ClO{sub 4}) (3), which displays half spin transitions between 100 and 300 K, has been synthesized and structurally characterized. Compound 3 featured with two-dimensional (2-D) grids connected by hydrogen bonds and π…π packing between one-dimensional (1-D) chains, the 2-D grids expand to three-dimensional (3-D) architecture supported by a “S-shaped holder” involving lattice 4-4′-bipy, water molecules and perchlorate anion. We compared 3 with the other two analogous complexes: ((Fe(4,4′-bipy) (H{sub 2}O){sub 2} (NCS){sub 2})·4,4′-bipy, 1 and (Fe(4,4′-bipy){sub 2}(NCS){sub 2})·mSolv, 2) through Hirshfeld surfaces analysis, which revealed that the low ligand field strength (NCS{sup −}) and lone-pair…H contacts contribute to the stabilization of HS (high-spin) state of the Fe(II) ion, while the high ligand field strength (4,4′-bipy) and strong intermolecular contacts (hydrogen bonds and π…π packing interactions) make for the LS (low-spin) state. - Highlights: ●A new member of Fe(||)-4,4′-bipy family has been prepared. ●It displays half spin transitions tuned by ligand field and intermolecular interactions. ●We have made a detailed comparison of this new member with two other analogous complexes.

  5. Mechanisms of G1 cell cycle arrest and apoptosis in myeloma cells induced by hybrid-compound histone deacetylase inhibitor

    SciTech Connect (OSTI)

    Fujii, Seiko; Division of Maxillofacial Surgery, Kyushu Dental University ; Okinaga, Toshinori; Ariyoshi, Wataru; Oral Biology Research Center, Kyushu Dental University ; Takahashi, Osamu; Iwanaga, Kenjiro; Nishino, Norikazu; Tominaga, Kazuhiro; Nishihara, Tatsuji; Oral Biology Research Center, Kyushu Dental University

    2013-05-10

    Highlights: •Novel histone deacetylase inhibitor Ky-2, remarkably inhibits myeloma cell growth. •Ky-2 demonstrates no cytotoxicity against normal lymphocytic cells. •Ky-2 induces cell cycle arrest through the cell cycle-associated proteins. •Ky-2 induces Bcl-2-inhibitable apoptosis through a caspase-dependent cascade. -- Abstract: Objectives: Histone deacetylase (HDAC) inhibitors are new therapeutic agents, used to treat various types of malignant cancers. In the present study, we investigated the effects of Ky-2, a hybrid-compound HDAC inhibitor, on the growth of mouse myeloma cells. Materials and methods: Myeloma cells, HS-72, P3U1, and mouse normal cells were used in this study. Effect of HDAC inhibitors on cell viability was determined by WST-assay and trypan blue assay. Cell cycle was analyzed using flow cytometer. The expression of cell cycle regulatory and the apoptosis associated proteins were examined by Western blot analysis. Hoechst’s staining was used to detect apoptotic cells. Results: Our findings showed that Ky-2 decreased the levels of HDACs, while it enhanced acetylation of histone H3. Myeloma cell proliferation was inhibited by Ky-2 treatment. Interestingly, Ky-2 had no cytotoxic effects on mouse normal cells. Ky-2 treatment induced G1-phase cell cycle arrest and accumulation of a sub-G1 phase population, while Western blotting analysis revealed that expressions of the cell cycle-associated proteins were up-regulated. Also, Ky-2 enhanced the cleavage of caspase-9 and -3 in myeloma cells, followed by DNA fragmentation. In addition, Ky-2 was not found to induce apoptosis in bcl-2 overexpressing myeloma cells. Conclusion: These findings suggest that Ky-2 induces apoptosis via a caspase-dependent cascade and Bcl-2-inhibitable mechanism in myeloma cells.

  6. Intergalactic medium emission observations with the cosmic web imager. I. The circum-QSO medium of QSO 1549+19, and evidence for a filamentary gas inflow

    SciTech Connect (OSTI)

    Martin, D. Christopher; Chang, Daphne; Matuszewski, Matt; Morrissey, Patrick; Rahman, Shahin; Moore, Anna; Steidel, Charles C.

    2014-05-10

    The Palomar Cosmic Web Imager (PCWI), an integral field spectrograph designed to detect and map low surface brightness emission, has obtained imaging spectroscopic maps of Ly? from the circum-QSO medium (CQM) of QSO HS1549+19 at redshift z = 2.843. Extensive extended emission is detected from the CQM, consistent with fluorescent and pumped Ly? produced by the ionizing and Ly? continuum of the QSO. Many features present in PCWI spectral images match those detected in narrow-band images. Filamentary structures with narrow line profiles are detected in several cases as long as 250-400 kpc. One of these is centered at a velocity redshifted with respect to the systemic velocity, and displays a spatially collimated and kinematically cold line profile increasing in velocity width approaching the QSO. This suggests that the filament gas is infalling onto the QSO, perhaps in a cold accretion flow. Because of the strong ionizing flux, the neutral column density is low, typically N(H I)?10{sup 12}--10{sup 15} cm{sup ?2}, and the line center optical depth is also low (typically ?{sub 0} < 10), insufficient to display well separated double peak emission characteristic of higher line optical depths. With a simple ionization and cloud model we can very roughly estimate the total gas mass (log M {sub gas} = 12.5 0.5) and the total (log M {sub tot} = 13.3 0.5). We can also calculate a kinematic mass from the total line profile (2 10{sup 13} M {sub ?}), which agrees with the mass estimated from the gas emission. The intensity-binned spectrum of the CQM shows a progression in kinematic properties consistent with heirarchical structure formation.

  7. Microbial mineral colonization across a subsurface redox transition zone

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Converse, Brandon J.; McKinley, James P.; Resch, Charles T.; Roden, Eric E.

    2015-08-28

    Here our study employed 16S rRNA gene amplicon pyrosequencing to examine the hypothesis that chemolithotrophic Fe(II)-oxidizing bacteria (FeOB) would preferentially colonize the Fe(II)-bearing mineral biotite compared to quartz sand when the minerals were incubated in situ within a subsurface redox transition zone (RTZ) at the Hanford 300 Area site in Richland, WA, USA. The work was motivated by the recently documented presence of neutral-pH chemolithotrophic FeOB capable of oxidizing structural Fe(II) in primary silicate and secondary phyllosilicate minerals in 300 Area sediments and groundwater (Benzine et al., 2013). Sterilized portions of sand+biotite or sand alone were incubated in situ formore » 5 months within a multilevel sampling (MLS) apparatus that spanned a ca. 2-m interval across the RTZ in two separate groundwater wells. Parallel MLS measurements of aqueous geochemical species were performed prior to deployment of the minerals. Contrary to expectations, the 16S rRNA gene libraries showed no significant difference in microbial communities that colonized the sand+biotite vs. sand-only deployments. Both mineral-associated and groundwater communities were dominated by heterotrophic taxa, with organisms from the Pseudomonadaceae accounting for up to 70% of all reads from the colonized minerals. These results are consistent with previous results indicating the capacity for heterotrophic metabolism (including anaerobic metabolism below the RTZ) as well as the predominance of heterotrophic taxa within 300 Area sediments and groundwater. Although heterotrophic organisms clearly dominated the colonized minerals, several putative lithotrophic (NH4+, H2, Fe(II), and HS- oxidizing) taxa were detected in significant abundance above and within the RTZ. Such organisms may play a role in the coupling of anaerobic microbial metabolism to oxidative pathways with attendant impacts on elemental cycling and redox-sensitive contaminant behavior in the vicinity of the RTZ.« less

  8. Cytotoxicity of monodispersed chitosan nanoparticles against the Caco-2 cells

    SciTech Connect (OSTI)

    Loh, Jing Wen; Saunders, Martin; Lim, Lee-Yong

    2012-08-01

    Published toxicology data on chitosan nanoparticles (NP) often lack direct correlation to the in situ size and surface characteristics of the nanoparticles, and the repeated NP assaults as experienced in chronic use. The aim of this paper was to breach these gaps. Chitosan nanoparticles synthesized by spinning disc processing were characterised for size and zeta potential in HBSS and EMEM at pHs 6.0 and 7.4. Cytotoxicity against the Caco-2 cells was evaluated by measuring the changes in intracellular mitochondrial dehydrogenase activity, TEER and sodium fluorescein transport data and cell morphology. Cellular uptake of NP was observed under the confocal microscope. Contrary to established norms, the collective data suggest that the in vitro cytotoxicity of NP against the Caco-2 cells was less influenced by positive surface charges than by the particle size. Particle size was in turn determined by the pH of the medium in which the NP was dispersed, with the mean size ranging from 25 to 333 nm. At exposure concentration of 0.1%, NP of 25 ± 7 nm (zeta potential 5.3 ± 2.8 mV) was internalised by the Caco-2 cells, and the particles were observed to inflict extensive damage to the intracellular organelles. Concurrently, the transport of materials along the paracellular pathway was significantly facilitated. The Caco-2 cells were, however, capable of recovering from such assaults 5 days following NP removal, although a repeat NP exposure was observed to produce similar effects to the 1st exposure, with the cells exhibiting comparable resiliency to the 2nd assault. -- Highlights: ► Chitosan nanoparticles reduced mitochondrial dehydrogenase activity. ► Cellular uptake of chitosan nanoparticles was observed. ► Chitosan nanoparticles inflicted extensive damage to the cell morphology. ► The transport of materials along the paracellular pathway was facilitated.

  9. Contribution of counterions and degree of ionization for birefringence creation and relaxation kinetics parameters of PAH/PAZO films

    SciTech Connect (OSTI)

    Raposo, Maria Monteiro Timóteo, Ana Rita; Ribeiro, Paulo A.; Ferreira, Quirina; Botelho do Rego, Ana Maria

    2015-09-21

    Photo induced birefringent materials can be used to develop optical and conversion energy devices, and consequently, the study of the variables that influences the creation and relaxation of birefringence should be carefully analyzed. In this work, the parameters of birefringence creation and relaxation kinetics curves obtained on layer-by-layer (LBL) films, prepared from azo-polyectrolyte poly[1-[4-(3-carboxy-4 hydroxyphenylazo) benzene sulfonamido]-1,2-ethanediyl, sodium salt] (PAZO) and poly(allylamine hydrochloride)(PAH), are related with the presence of counterions and the degree of ionization of the polyelectrolytes. Those kinetics curves obtained on PAH/PAZO LBL films, prepared from PAH solutions with different pHs and maintaining the pH of PAZO solution constant at pH = 9, were analyzed taking into account the films composition which was characterized by X-ray photoelectron spectroscopy. The creation and relaxation birefringence curves are justified by two processes: one associated to local mobility of the azobenzene with a characteristic time 30 s and intensity constant and other associated with polymeric chains mobility with the characteristic time and intensity decreasing with pH. These results allow us to conclude that the birefringence creation process, associated to local mobility of azobenzenes is independent of the degree of ionization and of number of counterions or co-ions present while the birefringence creation process associated to mobility of chains have its characteristic time and intensity dependent of both degree of ionization and number of counterions. The birefringence relaxation processes are dependent of the degree of ionization. The analysis of the films composition revealed, in addition, the presence of a protonated secondary or tertiary amine revealing that PAZO may have positive charges and consequently a zwitterionic behavior.

  10. ENO1 promotes tumor proliferation and cell adhesion mediated drug resistance (CAM-DR) in Non-Hodgkin's Lymphomas

    SciTech Connect (OSTI)

    Zhu, Xinghua; Miao, Xiaobing; Wu, Yaxun; Li, Chunsun; Guo, Yan; Liu, Yushan; Chen, Yali; Lu, Xiaoyun; Wang, Yuchan; He, Song

    2015-07-15

    Enolases are glycolytic enzymes responsible for the ATP-generated conversion of 2-phosphoglycerate to phosphoenolpyruvate. In addition to the glycolytic function, Enolase 1 (ENO1) has been reported up-regulation in several tumor tissues. In this study, we investigated the expression and biologic function of ENO1 in Non-Hodgkin's Lymphomas (NHLs). Clinically, by western blot analysis we observed that ENO1 expression was apparently higher in diffuse large B-cell lymphoma than in the reactive lymphoid tissues. Subsequently, immunohistochemical staining of 144 NHLs suggested that the expression of ENO1 was significantly lower in the indolent lymphomas compared with the progressive lymphomas. Further, we identified ENO1 as an independent prognostic factor, and it was significantly correlated with overall survival of NHL patients. In addition, we found that ENO1 could promote cell proliferation, regulate cell cycle associated gene and PI3K/AKT signaling pathway in NHLs. Finally, we verified that ENO1 participated in the process of lymphoma cell adhesion mediated drug resistance (CAM-DR). Adhesion to FN or HS5 cells significantly protected OCI-Ly8 and Daudi cells from cytotoxicity compared with those cultured in suspension, and these effects were attenuated when transfected with ENO1-siRNA. Based on the study, we propose that inhibition of ENO1 expression may be a novel strategy for therapy for NHLs patients, and it may be a target for drug resistance. - Highlights: • ENO1 expression is reversely correlated with clinical outcomes of patients with NHLs. • ENO1 promotes the proliferation of NHL cells. • ENO1 regulates cell adhesion mediated drug resistance.

  11. Reductive deconstruction of organosolv lignin catalyzed by zeolite supported nickel nanoparticles

    SciTech Connect (OSTI)

    Kasakov, Stanislav; Shi, Hui; Camaioni, Donald M.; Zhao, Chen; Barath, Eszter; Jentys, Andreas; Lercher, Johannes A.

    2015-11-01

    Mechanistic aspects of deconstruction and hydrodeoxygenation of organosolv lignin using supported Ni catalysts with (Ni/HZSM-5 and Ni/HBEA) and without Brønsted acid sites (Ni/SiO2) are reported. Lignin was deconstructed and converted to saturated cyclic hydrocarbons ranging from C5 to C14. In the one-stage reaction, full conversion with total yield of 70 ± 5 wt.% saturated hydrocarbons was achieved at 593 K and 20 bar H2. The organosolv lignin used consists of seven to eight monolignol subunits and has an average molecular weight of ca. 1200 g mol-1. The monolignols were mainly guaiacyl, syringyl and phenylcoumaran, randomly interconnected through β-O-4, 4-O-5, β-1, 5-5’ and β-β ether bonds. In situ IR spectroscopy was used to follow the changes in lignin constituents during reaction. The proposed reaction pathways for the catalytic transformation of this organosolv lignin to alkanes start with the hydrogenolysis of aryl alkyl ether bonds, followed by hydrogenation of the aromatic compounds on Ni to cyclic alcohols. Oxygen is removed from the alcohols via dehydration on Brønsted acid sites to yield cyclic alkenes that are further hydrogenated to alkanes. Formation of condensation products may occur via intermolecular recombination of aromatic monomers or alkylation of aromatic compounds by alkenes. The financial support from TUM-PNNL cooperation project “Development of new methods for in situ characterization in liquid phase reactions” (CN-177939) is highly appreciated. The work by S.K., H.S., and J.A.L was partially supported by the US Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences.

  12. Surface complexation of neptunium (V) onto whole cells and cell componets of Shewanella alga

    SciTech Connect (OSTI)

    Reed, Donald Timothy; Deo, Randhir P; Rittmann, Bruce E; Songkasiri, Warinthorn

    2008-01-01

    We systematically quantified surface complexation of neptunium(V) onto whole cells of Shewanella alga strain BrY and onto cell wall and extracellular polymeric substances (EPS) of S. alga. We first performed acid and base titrations and used the mathematical model FITEQL with constant-capacitance surface-complexation to determine the concentrations and deprotonation constants of specific surface functional groups. Deprotonation constants most likely corresponded to a carboxyl site associated with amino acids (pK{sub a} {approx} 2.4), a carboxyl group not associated with amino acids (pK{sub a} {approx} 5), a phosphoryl site (pK{sub a} {approx} 7.2), and an amine site (pK{sub a} > 10). We then carried out batch sorption experiments with Np(V) and each of the S. alga components at different pHs. Results show that solution pH influenced the speciation of Np(V) and each of the surface functional groups. We used the speciation sub-model of the biogeochemical model CCBATCH to compute the stability constants for Np(V) complexation to each surface functional group. The stability constants were similar for each functional group on S. alga bacterial whole cells, cell walls, and EPS, and they explain the complicated sorption patterns when they are combined with the aqueous-phase speciation of Np(V). For pH < 8, NpO{sub 2}{sup +} was the dominant form of Np(V), and its log K values for the low-pK{sub a} carboxyl, other carboxyl, and phosphoryl groups were 1.75, 1.75, and 2.5 to 3.1, respectively. For pH greater than 8, the key surface ligand was amine >XNH3+, which complexed with NpO{sub 2}(CO{sub 3}){sub 3}{sup 5-}. The log K for NpO{sub 2}(CO{sub 3}){sub 3}{sup 5-} complexed onto the amine groups was 3.1 to 3.6. All of the log K values are similar to those of Np(V) complexes with aqueous carboxyl and N-containing carboxyl ligands. These results point towards the important role of surface complexation in defining key actinide-microbiological interactions in the subsurface.

  13. MEASURING MICROLENSING USING SPECTRA OF MULTIPLY LENSED QUASARS

    SciTech Connect (OSTI)

    Motta, V.; Mediavilla, E.; Munoz, J. A. E-mail: emg@iac.es E-mail: jmunoz@uv.es

    2012-08-10

    We report on a program of spectroscopic observations of gravitationally lensed QSOs with multiple images. We seek to establish whether microlensing is occurring in each QSO image using only single-epoch observations. We calculate flux ratios for the cores of emission lines in image pairs to set a baseline for no microlensing. The offset of the continuum flux ratios relative to this baseline yields the microlensing magnification free from extinction, as extinction affects the continuum and the lines equally. When we find chromatic microlensing, we attempt to constrain the size of the QSO accretion disk. SDSSJ1004+4112 and HE1104-1805 show chromatic microlensing with amplitudes 0.2 < |{Delta}m| < 0.6 and 0.2 < |{Delta}m| < 0.4 mag, respectively. Modeling the accretion disk with a Gaussian source (I{proportional_to}exp (- R{sup 2}/2r{sup 2}{sub s})) of size r{sub s} {proportional_to}{lambda}{sup p} and using magnification maps to simulate microlensing, we find r{sub s} ({lambda}3363) = 7 {+-} 3 lt-day(18.1 {+-} 7.8 Multiplication-Sign 10{sup 15} cm) and p = 1.1 {+-} 0.4 for SDSS1004+4112, and r{sub s} ({lambda}3363) = 6 {+-} 2 lt-day(15.5 {+-} 5.2 Multiplication-Sign 10{sup 15} cm) and p = 0.7 {+-} 0.1 for HE1104-1805. For SDSSJ1029+2623, we find strong chromaticity of {approx}0.4 mag in the continuum flux ratio, which probably arises from microlensing, although not all the available data fit within this explanation. For Q0957+561, we measure B - A magnitude differences of 0.4 mag, much greater than the {approx}0.05 mag amplitude usually inferred from light-curve variability. It may substantially modify the current interpretations of microlensing in this system, likely favoring the hypothesis of smaller sources and/or larger microdeflectors. For HS0818+1227, our data yield possible evidence of microlensing.

  14. Spin Equilibria in Monomeric Manganocenes: Solid State Magnetic and EXAFS Studies

    SciTech Connect (OSTI)

    Walter, M. D.; Sofield, C. D.; Booth, C. H.; Andersen, R. A.

    2009-02-09

    Magnetic susceptibility measurements and X-ray data confirm that tert-butyl-substituted manganocenes [(Me{sub 3}C){sub n}C{sub 5}H{sub 5?n}]{sub 2}Mn (n = 1, 2) follow the trend previously observed with the methylated manganocenes; that is, electron-donating groups attached to the Cp ring stabilize the low-spin (LS) electronic ground state relative to Cp{sub 2}Mn and exhibit higher spin-crossover (SCO) temperatures. However, introducing three CMe{sub 3} groups on each ring gives a temperature-invariant high-spin (HS) state manganocene. The origin of the high-spin state in [1,2,4-(Me{sub 3}C){sub 3}C{sub 5}H{sub 2}]{sub 2}Mn is due to the significant bulk of the [1,2,4-(Me{sub 3}C){sub 3}C{sub 5}H{sub 2}]{sup -} ligand, which is sufficient to generate severe inter-ring steric strain that prevents the realization of the low-spin state. Interestingly, the spin transition in [1,3-(Me{sub 3}C){sub 2}C{sub 5}H{sub 3}]{sub 2}Mn is accompanied by a phase transition resulting in a significant irreversible hysteresis ({Delta}T{sub c} = 16 K). This structural transition was also observed by extended X-ray absorption fine-structure (EXAFS) measurements. Magnetic susceptibility studies and X-ray diffraction data on SiMe{sub 3}-substituted manganocenes [(Me{sub 3}Si){sub n}C{sub 5}H{sub 5-n}]{sub 2}Mn (n = 1, 2, 3) show high-spin configurations in these cases. Although tetra- and hexasubstituted manganocenes are high-spin at all accessible temperatures, the disubstituted manganocenes exhibit a small low-spin admixture at low temperature. In this respect it behaves similarly to [(Me{sub 3}C)(Me{sub 3}Si)C{sub 5}H{sub 3}]{sub 2}Mn, which has a constant low-spin admixture up to 90 K and then gradually converts to high-spin. Thermal spin-trapping can be observed for [(Me{sub 3}C)(Me{sub 3}Si)C{sub 5}H{sub 3}]{sub 2}Mn on rapid cooling.

  15. A nanostructure-initiator mass spectrometry-based enzyme activity assay

    SciTech Connect (OSTI)

    Siuzdak, Gary; Northen, Trent R.; Lee, Jinq-Chyi; Hoang, Linh; Raymond, Jason; Hwang, Der-Ren; Yannone, Steven M.; Wong, Chi-Huey; Siuzdak, Gary

    2008-03-10

    We describe a Nanostructure-Initiator Mass Spectrometry (NIMS) enzymatic (Nimzyme) assay in which enzyme substrates are immobilized on the mass spectrometry surface by using fluorous-phase interactions. This 'soft' immobilization allows efficient desorption/ionization while also enabling the use of surface-washing steps to reduce signal suppression from complex biological samples, which results from the preferential retention of the tagged products and reactants. The Nimzyme assay is sensitive to subpicogram levels of enzyme, detects both addition and cleavage reactions (sialyltransferase and galactosidase), is applicable over a wide range of pHs and temperatures, and can measure activity directly from crude cell lysates. The ability of the Nimzyme assay to analyze complex mixtures is illustrated by identifying and directly characterizing {beta}-1,4-galactosidase activity from a thermophilic microbial community lysate. The optimal enzyme temperature and pH were found to be 65 C and 5.5, respectively, and the activity was inhibited by both phenylethyl-{beta}-d-thiogalactopyranoside and deoxygalactonojirimycin. Metagenomic analysis of the community suggests that the activity is from an uncultured, unsequenced {gamma}-proteobacterium. In general, this assay provides an efficient method for detection and characterization of enzymatic activities in complex biological mixtures prior to sequencing or cloning efforts. More generally, this approach may have important applications for screening both enzymatic and inhibitor libraries, constructing and screening glycan microarrays, and complementing fluorous-phase organic synthesis. The interest in leveraging mass spectrometry for studying enzyme activities in complex biological samples derives from its high sensitivity and specificity; however, signal suppression and significant sample preparation requirements limit its overall utility (1). Here we describe a Nanostructure-Initiator Mass Spectrometry (NIMS) enzymatic (Nimzyme

  16. Framing effectiveness in impact assessment: Discourse accommodation in controversial infrastructure development

    SciTech Connect (OSTI)

    Rozema, Jaap G.; Bond, Alan J.

    2015-01-15

    There is ongoing debate about the effectiveness of impact assessment tools, which matters both because of the threat to future practice of the tools which are frequently perceived to be ineffective, and because of the disillusionment that can ensue, and controversy generated, amongst stakeholders in a decision context where opportunities for meaningful debate have not been provided. In this article we regard debate about the meaning of effectiveness in impact assessment as an inevitable consequence of increased participation in environmental decision-making, and therefore frame effectiveness based on an inclusive democracy role to mean the extent to which impact assessment can accommodate civil society discourse. Our aim is to investigate effectiveness based on this framing by looking at one type of impact assessment – environmental impact assessment (EIA) – in two controversial project proposals: the HS2 rail network in England; and the A4DS motorway in the Netherlands. Documentary analysis and interviews held with key civil society stakeholders have been deployed to identify discourses that were mobilised in the cases. EIA was found to be able to accommodate only one out of four discourses that were identified; for the other three it did not provide the space for the arguments that characterised opposition. The conclusion in relation to debate on framings of effectiveness is that EIA will not be considered effective by the majority of stakeholders. EIA was established to support decision-making through a better understanding of impacts, so its ineffectiveness is unsurprising when its role is perceived to be broader. However, there remains a need to map discourses in different decision contexts and to analyse the extent to which the range of discourses are accommodated throughout the decision process, and the role of impact assessment in those processes, before recommendations can be made to either improve impact assessment effectiveness, or whether it is

  17. Nature of Catalytic Active Sites Present on the Surface of Advanced Bulk Tantalum Mixed Oxide Photocatalysts

    SciTech Connect (OSTI)

    Phivilay, Somphonh; Puretzky, Alexander A; Domen, Kazunari Domen; Wachs, Israel

    2013-01-01

    The most active photocatalyst system for water splitting under UV irradiation (270 nm) is the promoted 0.2%NiO/NaTaO3:2%La photocatalyst with optimized photonic efficiency (P.E.) of 56%, but fundamental issues about the nature of the surface catalytic active sites and their involvement in the photocatalytic process still need to be clarified. This is the first study to apply cutting edge surface spectroscopic analyses to determine the surface nature of tantalum mixed oxide photocatalysts. Surface analysis with HR-XPS (1-3nm) and HS-LEIS (0.3nm) spectroscopy indicates that the NiO and La2O3 promoters are concentrated in the surface region of the bulk NaTaO3 phase. The La2O3 is concentrated on the NaTaO3 outermost surface layers while NiO is distributed throughout the NaTaO3 surface region (1-3nm). Raman and UV-vis spectroscopy revealed that the bulk molecular and electronic structures, respectively, of NaTaO3 were not modified by the addition of the La2O3 and NiO promoters, with La2O3 resulting in a slightly more ordered structure. Photoluminescence (PL) spectroscopy reveals that the addition of La2O3 and NiO produces a greater number of electron traps resulting in the suppression of the recombination of excited electrons/holes. In contrast to earlier reports, the La2O3 is only a textural promoter (increasing the BET surface area ~7x by stabilizing smaller NaTaO3 particles), but causes a ~3x decrease in the specific photocatalytic TORs ( mol H2/m2/h) rate because surface La2O3 blocks exposed catalytic active NaTaO3 sites. The NiO promoter was found to be a potent electronic promoter that enhances the NaTaO3 surface normalized TORs by a factor of ~10-50 and TOF by a factor of ~10. The level of NiO promotion is the same in the absence and presence of La2O3 demonstrating that there is no promotional synergistic interaction between the NiO and La2O3 promoters. This study demonstrates the important contributions of the photocatalyst surface properties to the fundamental

  18. Over-expression of human endosulfatase-1 exacerbates cadmium-induced injury to transformed human lung cells in vitro

    SciTech Connect (OSTI)

    Zhang, Huiying; Department of Environmental and Molecular Toxicology, College of Agriculture and Life Sciences, NC State University, Raleigh, NC 27695 ; Newman, Donna R.; Bonner, James C.; Sannes, Philip L.

    2012-11-15

    Environmental exposure to cadmium is known to cause damage to alveolar epithelial cells of the lung, impair their capacity to repair, and result in permanent structural alterations. Cell surface heparan sulfate proteoglycans (HSPGs) can modulate cell responses to injury through their interactions with soluble effector molecules. These interactions are often sulfate specific, and the removal of sulfate groups from HS side chains could be expected to influence cellular injury, such as that caused by exposure to cadmium. The goal of this study was to define the role 6-O-sulfate plays in cellular responses to cadmium exposure in two pulmonary epithelial cancer cell lines (H292 and A549) and in normal human primary alveolar type II (hAT2) cells. Sulfate levels were modified by transduced transient over-expression of 6-O-endosulfatase (HSulf-1), a membrane-bound enzyme which specifically removes 6-O-sulfate groups from HSPG side chains. Results showed that cadmium decreased cell viability and activated apoptosis pathways at low concentrations in hAT2 cells but not in the cancer cells. HSulf-1 over-expression, on the contrary, decreased cell viability and activated apoptosis pathways in H292 and A549 cells but not in hAT2 cells. When combined with cadmium, HSulf-1 over-expression further decreased cell viability and exacerbated the activation of apoptosis pathways in the transformed cells but did not add to the toxicity in hAT2 cells. The finding that HSulf-1 sensitizes these cancer cells and intensifies the injury induced by cadmium suggests that 6-O-sulfate groups on HSPGs may play important roles in protection against certain environmental toxicants, such as heavy metals. -- Highlights: ? Primary human lung alveolar type 2 (hAT2) cells and H292 and A549 cells were used. ? Cadmium induced apoptosis in hAT2 cells but not in H292 or A549 cells. ? HSulf-1exacerbates apoptosis induced by cadmium in H292 and A549 but not hAT2 cells.

  19. Extrinsic and intrinsic properties in metalinsulator transition of hydrothermally prepared vanadium dioxide crystals

    SciTech Connect (OSTI)

    Lee, Myeongsoon; Kim, Don

    2014-03-01

    The clear insulator (monoclinic-VO{sub 2}) to metal (rutile-VO{sub 2}) transition (IMT) was observed in electrical conductivity and differential scanning calorimeter (DSC) measurements at around 340 K, which is IMT temperature (T{sub H}), in the hydrothermally prepared VO{sub 2} crystals. The occurrence of metal to insulator transition (MIT) temperature (T{sub C}) was observed below 333 K during the first resistance measurement cycle in the most of cases. The sudden jump of the electrical resistance at IMT and MIT points was amplified several times than that of the first cycle during the repeated successive thermal cycles (heating and cooling across the IMT and MIT temperatures). T{sub C} and T{sub H} shifted to higher temperature by the repeated successive thermal cycles. This shift and the amplified jump might be related to the mechanical stress between the VO{sub 2} crystals, i.e. extrinsic properties. However, the starting point of MIT, T{sub CS} = ? 336 K, and the starting point of IMT, T{sub HS} = ? 338 K, kept almost constant during the repeated thermal cycles (< 10 times). These two temperatures may be related to the intrinsic properties of the VO{sub 2}: the phase transitions initiated at these temperatures regardless of the number of the repeated thermal cycles. The neat surface of the VO{sub 2} crystals was severely damaged and the average size of particles reduced from 110 nm to 7090 nm after extensively repeated thermal cycles (> 70 times). The damaged surface and the smaller particles, which would be originated from the mechanical stress caused by crystal volume change during the first order transition of the VO{sub 2}, would weaken the electrical conduction path (loosen grain boundaries) between the VO{sub 2} single crystals and would result in the amplified jump at the following MIT. This report may boost the study for the improved stability and lifetime of the VO{sub 2} based electronic devices. - Highlights: The sharp phase transition in

  20. SU-E-I-82: PET Radiopharmaceuticals for Prostate Cancer Imaging: A Review

    SciTech Connect (OSTI)

    Fernandes, F; Silva, D da; Rodrigues, L

    2015-06-15

    Purpose: The aim of this work was to review new and clinical practice PET radiopharmaceuticals for prostate cancer imaging. Methods: PET radiopharmaceuticals were reviewed on the main databases. Availability, dosimetry, accuracy and limitations were considered. Results: The following radioisotopes with respective physical half-life and mean positron energy were found: {sup 18}F (109,7 min, 249,8 keV), {sup 89}Zr (78,4 hs, 395,5 keV), {sup 11}C (20,4 min, 385,7 keV) and {sup 68}Ga (67,8 min, 836 keV). {sup 68}Ga was the only one not produced by cyclotron. Radiopharmaceuticals uptake by glucose metabolism ({sup 18}F-FDG), lipogenesis ({sup 11}C-Choline and {sup 11}C-Acetate), amino acid transport (Anti-{sup 18}F-FACBC), bone matrix ({sup 18}F-NaF), prostatespecific membrane antigen ({sup 68}Ga-PSMA and {sup 89}Zr-J591), CXCR receptors ({sup 89}Ga-Pentixafor), adrenal receptors ({sup 18}F-FDHT) and gastrin release peptide receptor (bombesin analogue). Most of radiopharmaceuticals are urinary excretion, so bladder is the critical organ. 11C-choline (pancreas), Anti-{sup 18}FFACBC (liver) and {sup 18}F-FBDC (stomach wall) are the exception. Higher effective dose was seen {sup 18}F-NaF (27 μSv/MBq) while the lowest was {sup 11}CAcetate (3,5 μSv/MBq). Conclusion: Even though {sup 18}F-FDG has a large availability its high urinary excretion and poor uptake to slow growing disease offers weak results for prostate cancer. Better accuracy is obtained when {sup 18}F-NaF is used for bone metastatic investigation although physicians tend to choose bone scintigraphy probably due to its cost and practice. Many guidelines in oncology consider {sup 11}C or {sup 18}F labeled with Choline the gold standard for biochemical relapse after radical treatment. Local, lymph node and distant metastatic relapse can be evaluated at same time with this radiopharmaceutical. There is no consensus over bigger urinary excretion for {sup 18}F labeling. Anti-{sup 18}F-FACBC, {sup 68}Ga-PSMA and {sup

  1. Supramolecular Catalysis of Orthoformate Hydrolysis in Basic Solution: An Enzyme-Like Mechanism

    SciTech Connect (OSTI)

    Pluth, Michael D.; Bergman, Robert G.; Raymond, Kenneth N.

    2008-04-17

    Magnetic susceptibility measurements and X-ray data confirm that tert-butyl substituted manganocenes [(Me{sub 3}C){sub n}C{sub 5}H{sub 5-n}]{sub 2}Mn (n= 1, 2) follow the trend previously observed with the methylated manganocenes, i.e., electron donating groups attached to the Cp ring stabilize the low-spin (LS) electronic ground state relative to Cp{sub 2}Mn and exhibit higher spin-crossover (SCO) temperatures. However, introducing three CMe3 groups on each ring gives a temperature invariant high-spin (HS) state manganocene. The origin of the high-spin state in [1,2,4-(Me{sub 3}C){sub 3}C{sub 5}H{sub 2}]{sub 2}Mn is due to the significant bulk of the [1,2,4-(Me{sub 3}C){sub 3}C{sub 5}H{sub 2}]{sup -} ligand, which is sufficient to generate severe inter-ring steric strain that prevents the realization of the low-spin state. Interestingly, the spin transition in [1,3-(Me{sub 3}C){sub 2}C{sub 5}H{sub 3}]{sub 2}Mn is accompanied by a phase transition resulting in a significant irreversible hysteresis ({Delta}T{sub c} = 16 K). This structural transition was also observed by extended X-ray absorption fine-structure (EXAFS) measurements. Magnetic susceptibility studies and X-ray diffraction data on SiMe{sub 3} substituted manganocenes [(Me{sub 3}Si){sub n}C{sub 5}H{sub 5-n}]{sub 2}Mn (n= 1, 2, 3) show high-spin configuration in these cases. Although tetra- and hexasubstituted manganocenes are high-spin at all accessible temperatures, the disubstituted manganocenes exhibit a small low-spin admixture at low temperature. In this respect it behaves similarly to [(Me{sub 3}C)(Me{sub 3}Si)C{sub 5}H{sub 3}]{sub 2}Mn, which has a constant low-spin admixture up to 90 K and then gradually converts to high-spin. Thermal spin-trapping can be observed for [(Me{sub 3}C)(Me{sub 3}Si)C{sub 5}H{sub 3}]{sub 2}Mn on rapid cooling.

  2. Narrowband Lyman-continuum imaging of galaxies at z ? 2.85

    SciTech Connect (OSTI)

    Mostardi, R. E.; Shapley, A. E.; Nestor, D. B.; Steidel, C. C.; Trainor, R. F.; Reddy, N. A.

    2013-12-10

    We present results from a survey for z ? 2.85 Lyman-continuum (LyC) emission in the HS1549+1933 field and place constraints on the amount of ionizing radiation escaping from star-forming galaxies. Using a custom narrowband filter (NB3420) tuned to wavelengths just below the Lyman limit at z ? 2.82, we probe the LyC spectral region of 49 Lyman break galaxies (LBGs) and 91 Ly? emitters (LAEs) spectroscopically confirmed at z ? 2.82. Four LBGs and seven LAEs are detected in NB3420. Using V-band data probing the rest-frame nonionizing UV, we observe that many NB3420-detected galaxies exhibit spatial offsets between their LyC and nonionizing UV emission and are characterized by extremely blue NB3420V colors, corresponding to low ratios of nonionizing to ionizing radiation (F {sub UV}/F {sub LyC}) that are in tension with current stellar population synthesis models. We measure average values of (F {sub UV}/F {sub LyC}) for our LBG and LAE samples, correcting for foreground galaxy contamination and H I absorption in the intergalactic medium. We find (F{sub UV}/F{sub LyC}){sub corr}{sup LBG}=8245 and (F{sub UV}/F{sub LyC}){sub corr}{sup LAE}=7.43.6. These flux density ratios correspond, respectively, to relative LyC escape fractions of f{sub esc,} {sub rel}{sup LBG}=5%--8% and f{sub esc,} {sub rel}{sup LAE}=18%--49%, absolute LyC escape fractions of f{sub esc}{sup LBG}=1%--2% and f{sub esc}{sup LAE}=5%--15%, and a comoving LyC emissivity from star-forming galaxies of 8.8-15.0 10{sup 24} erg s{sup 1} Hz{sup 1} Mpc{sup 3}. In order to study the differential properties of galaxies with and without LyC detections, we analyze narrowband Ly? imaging and rest-frame near-infrared imaging, finding that while LAEs with LyC detections have lower Ly? equivalent widths on average, there is no substantial difference in the rest-frame near-infrared colors of LBGs or LAEs with and without LyC detections. These preliminary results are consistent with an orientation-dependent model

  3. Formation of superheavy elements in cold fusion reactions

    SciTech Connect (OSTI)

    Smolanczuk, Robert

    2001-04-01

    We calculate the formation cross sections of transactinides (superheavy elements), as well as heavy actinides (No and Lr), which have been or might be obtained in fusion reactions with the evaporation of only one neutron. We use both more realistic fusion barrier and survival probability of the compound nucleus in comparison with the original phenomenological model [Phys. Rev. C 59, 2634 (1999)] that prompted the Berkeley experiment on the synthesis of a new superheavy element 118 [Phys. Rev. Lett. 83, 1104 (1999)]. Calculations are performed for asymmetric and symmetric target-projectile combinations and for reactions with stable and radioactive-ion beams. The formation cross sections measured at GSI-Darmstadt for transactinides and heavy actinides, as well as that for superheavy element 118 reported by the LBNL-Berkeley group, are reproduced within a factor of 2.4, on average. Based on the obtained relatively large cross sections, we predict that optimal reactions with stable beams for the synthesis of so far unobserved superheavy elements 119, 120, and 121 are {sup 209}Bi({sup 86}Kr, 1n){sup 294}119, {sup 208}Pb({sup 88}Sr, 1n){sup 295}120, and {sup 209}Bi({sup 88}Sr, 1n){sup 296}121, respectively. This is because of the magic of both the target and the projectile that leads to larger Q value and, consequently, lower effective fusion barrier with larger transmission probability. The same effect is responsible for relatively large cross sections predicted for the symmetric reactions {sup 136}Xe({sup 124}Sn, 1n){sup 259}Rf, {sup 136}Xe({sup 136}Xe, 1n){sup 271}Hs,{sup 138}Ba({sup 136}Xe, 1n){sup 273}110, and {sup 140}Ce({sup 136}Xe, 1n){sup 275}112. Although shell effects in the magic nuclei {sup 124}Sn, {sup 136}Xe, {sup 138}Ba, and {sup 140}Ce are not as strong as in {sup 208}Pb and {sup 209}Bi, they act on both the target and the projectile and lead to the prediction of measurable cross sections.

  4. Spontaneous Fission Modes and Lifetimes of Superheavy Elements in the Nuclear Density Functional Theory

    SciTech Connect (OSTI)

    Staszczak, A,

    2013-01-01

    Background: The reactions with the neutron-rich 48Ca beam and actinide targets resulted in the detection of new superheavy (SH) nuclides with Z=104 118. The unambiguous identification of the new isotopes, however, still poses a problem because their -decay chains terminate by spontaneous fission (SF) before reaching the known region of the nuclear chart. The understanding of the competition between -decay and SF channels in SH nuclei is, therefore, of crucial importance for our ability to map the SH region and to assess its extent.

    Purpose: We perform self-consistent calculations of the competing decay modes of even-even SH isotopes with 108 Z 126 and 148 N 188.

    Methods: We use the state-of-the-art computational framework based on self-consistent symmetry-unrestricted nuclear density functional theory capable of describing the competition between nuclear attraction and electrostatic repulsion. We apply the SkM* Skyrme energy density functional. The collective mass tensor of the fissioning superfluid nucleus is computed by means of the cranking approximation to the adiabatic time-dependent Hartree-Fock-Bogoliubov (HFB) approach. This paper constitutes a systematic self-consistent study of spontaneous fission in the SH region, carried out at a full HFB level, that simultaneously takes into account both triaxiality and reflection asymmetry.

    Results: Breaking axial symmetry and parity turns out to be crucial for a realistic estimate of collective action; it results in lowering SF lifetimes by more than 7 orders of magnitude in some cases. We predict two competing SF modes: reflection symmetric modes and reflection asymmetric modes.

    Conclusions: The shortest-lived SH isotopes decay by SF; they are expected to lie in a narrow corridor formed by 280Hs, 284Fl, and 118284Uuo that separates the regions of SH nuclei synthesized in cold-fusion and hot-fusion reactions. The region of long-lived SH nuclei is expected to be centered on 294Ds with a total half-life of

  5. Uranium Removal from Contaminated Groundwater by Synthetic Resins

    SciTech Connect (OSTI)

    Phillips, Debra H.; Gu, Baohua; Watson, David B; Parmele, C. S.

    2008-01-01

    Synthetic resins are shown to be effective in removing uranium from contaminated groundwater. Batch and field column tests showed that strong-base anion-exchange resins were more effective in removing uranium from both near-neutral-pH (6.5)- and high-pH (8)-low-nitrate-containing ground waters, than metal-chelating resins, which removed more uranium from acidic-pH (5)-high-nitrate-containing groundwater from the Oak Ridge Reservation (ORR) Y-12 S-3 Ponds area in Tennessee, USA. Dowex 1-X8 and Purolite A-520E anion-exchange resins removed more uranium from high-pH (8)-low-nitrate-containing synthetic groundwater in batch tests than metal-chelating resins. The Dowex{trademark} 21K anion-exchange resin achieved a cumulative loading capacity of 49.8 mg g{sup -1} before breakthrough in a field column test using near-neutral-pH (6.5)-low-nitrate-containing groundwater. However, in an acidic-pH (5)-high-nitrate-containing groundwater, metal-chelating resins Diphonix and Chelex-100 removed more uranium than anion-exchange resins. In 15 mL of acidic-pH (5)-high-nitrate-containing groundwater spiked with 20 mg L{sup -1} uranium, the uranium concentrations ranged from 0.95 mg L{sup -1} at 1-h equilibrium to 0.08 mg L{sup -1} at 24-h equilibrium for Diphonix and 0.17 mg L{sup -1} at 1-h equilibrium to 0.03 mg L{sup -1} at 24-h equilibrium for Chelex-100. Chelex-100 removed more uranium in the first 10 min in the 100 mL of acidic-(pH 5)-high-nitrate-containing groundwater (5 mg L{sup -1} uranium); however, after 10 min, Diphonix equaled or out-performed Chelex-100. This study presents an improved understanding of the selectivity and sorption kinetics of a range of ion-exchange resins that remove uranium from both low- and high-nitrate-containing groundwaters with varying pHs.

  6. Ambient H sub 2 S monitoring in the vicinity of Hawaii's first geothermal power plant

    SciTech Connect (OSTI)

    Morrow, J.W. ); Thomas, D.M. ); Burkard, H.D. )

    1988-01-01

    In December, 1975, work began on Hawaii's first successful geothermal well in the East Rift Zone of Kilauea Volcano on the Island of Hawaii (Figure 1). By July, 1976, the well, named Hawaii Geothermal Project - A (HGP-A), was complete to a depth of almost 2 km and had encountered a volcanically driven hydrothermal system having a temperature in excess of 358{degrees} C and a fluid chemistry composed of a mixture of seawater, meteoric water, and volcanic volatiles. The principal chemical constituents of the fluid are listed in Table I. Note the relatively high H{sub 2}S concentration which ranged 900 - 1,000 ppmw. During the early testing of the well, the superheated geothermal fluid was allowed to flash at normal atmospheric pressure with steam and noncondensable gases being released unabated into the atmosphere. The high H{sub 2}S and noise (120 dBA) levels and the close proximity of the Leilani Estates residential subdivision were cause for concern and efforts were thus made to mitigate these impacts. Certain elements of the initial test protocol required that the well be allowed to flow freely and unabated. During these periods public notice and prewarning were the most feasible means of mitigation. At other times, the mixed fluid is separated into steam and brine phases with the steam phase being treated with NaOH and then released through a rock muffler. The brine phase is released through a separate muffling system. Chemical treatment of the stream with NaOH converts the H{sub 2}S into a soluble sulfide salt through the following reaction: H{sub 2}S(g) + NaOH {r arrow} NaHS(s) + H{sub 2}O. This paper discusses early flow testing revealed that the well was able to produce a steady flow of approximately 50,000 kg per hour of steam and water at a pressure of 1200 kPA and thus appeared suitable for power generation.

  7. Influence of catalyst synthesis method on selective catalytic reduction (SCR) of NO by NH3 with V2O5-WO3/TiO2 catalysts

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    He, Yuanyuan; Ford, Michael E.; Zhu, Minghui; Liu, Qingcai; Tumuluri, Uma; Wu, Zili; Wachs, Israel E.

    2016-04-14

    We compared the molecular structures, surface acidity and catalytic activity for NO/NH3/O2 SCR of V2O5-WO3/TiO2 catalysts for two different synthesis methods: co-precipitation of aqueous vanadium and tungsten oxide precursors with TiO(OH)2 and by incipient wetness impregnation of the aqueous precursors on a reference crystalline TiO2 support (P25; primarily anatase phase). Bulk analysis by XRD showed that co-precipitation results in small and/or poorly ordered TiO2(anatase) particles and that VOx and WOx do not form solid solutions with the bulk titania lattice. Surface analysis of the co-precipitated catalyst by High Sensitivity-Low Energy Ion Scattering (HS-LEIS) confirms that the VOx and WOx aremore » surface segregated for the co-precipitated catalysts. In situ Raman and IR spectroscopy revealed that the vanadium and tungsten oxide components are present as surface mono-oxo O = VO3 and O = WO4 sites on the TiO2 supports. Co-precipitation was shown for the first time to also form new mono-oxo surface VO4 and WO4 sites that appear to be anchored at surface defects of the TiO2 support. IR analysis of chemisorbed ammonia showed the presence of both surface NH3* on Lewis acid sites and surface NH4+* on Brønsted acid sites. TPSR spectroscopy demonstrated that the specific SCR kinetics was controlled by the redox surface VO4 species and that the surface kinetics was independent of TiO2 synthesis method or presence of surface WO5 sites. SCR reaction studies revealed that the surface WO5 sites possess minimal activity below ~325 °C and their primary function is to increase the adsorption capacity of ammonia. A relationship between the SCR activity and surface acidity was not found. The SCR reaction is controlled by the surface VO4 sites that initiate the reaction at ~200 °C. The co-precipitated catalysts were always more active than the corresponding impregnated catalysts. Finally, we ascribe the higher activity of the co-precipitated catalysts to the presence of

  8. Physical Properties of Hanford Transuranic Waste Sludge

    SciTech Connect (OSTI)

    Berg, John C.

    2005-06-01

    Equipment that was purchased in the abbreviated year 1 of this project has been used during year 2 to study the fundamental behavior of materials that simulate the behavior of the Hanford transuranic waste sludge. Two significant results have been found, and each has been submitted for publication. Both studies found non-DLVO behavior in simulant systems. These separate but related studies were performed concurrently. It was previously shown in Rassat et al.'s report Physical and Liquid Chemical Simulant Formulations for Transuranic Wastes in Hanford Single-Shell Tanks that colloidal clays behave similarly to transuranic waste sludge (PNNL-14333, National Technical Information Service, U.S. Dept. of Commerce). Rassat et al. also discussed the pH and salt content of actual waste materials. It was shown that these materials exist at high pHs, generally above 10, and at high salt content, approximately 1.5 M from a mixture of different salts. A type of clay commonly studied, due to its uniformity, is a synthetic hectorite, Laponite. Therefore the work performed over the course of the last year was done mainly using suspensions of Laponite at high pH and involving high salt concentrations. One study was titled ''Relating Clay Rheology to Colloidal Parameters''. It has been submitted to the Journal of Colloid and INterface Science and is currently in the review process. The idea was to gain the ability to use measurable quantities to predict the flow behavior of clay systems, which should be similar to transuranic waste sludge. Leong et al. had previously shown that the yield stress of colloidal slurries of titania and alumina could be predicted, given the measurement of the accessible parameter zeta potential (Leong YK et al. J Chem Soc Faraday Trans, 19 (1993) 2473). Colloidal clays have a fundamentally different morphology and surface charge distribution than the spheroidal, uniformly charged colloids previously studied. This study was therefore performed in order to

  9. STRUCTURE AND FUNCTION OF SUBSURFACE MICROBIAL COMMUNITIES AFFECTING RADIONUCLIDE TRANSPORT AND BIOIMMOBILIZATION

    SciTech Connect (OSTI)

    Joel E. Kostka; Lee Kerkhof; Kuk-Jeong Chin; Martin Keller; Joseph W. Stucki

    2011-06-15

    to science all show high sequence identity to sequences retrieved from ORFRC subsurface. (2) Based on physiological and phylogenetic characterization, two new species of subsurface bacteria were described: the metal-reducer Geobacter daltonii, and the denitrifier Rhodanobacter denitrificans. (3) Strains isolated from the ORFRC show that Rhodanobacter species are well adapted to the contaminated subsurface. Strains 2APBS1 and 116-2 grow at high salt (3% NaCl), low pH (3.5) and tolerate high concentrations of nitrate (400mM) and nitrite (100mM). Strain 2APBS1 was demonstrated to grow at in situ acidic pHs down to 2.5. (4) R. denitrificans strain 2APBS1 is the first described Rhodanobacter species shown to denitrify. Nitrate is almost entirely converted to N2O, which may account for the large accumulation of N2O in the ORFRC subsurface. (5) G. daltonii, isolated from uranium- and hydrocarbon-contaminated subsurface sediments of the ORFRC, is the first organism from the subsurface clade of the genus Geobacter that is capable of growth on aromatic hydrocarbons. (6) High quality draft genome sequences and a complete eco-physiological description are completed for R. denitrificans strain 2APBS1 and G. daltonii strain FRC-32. (7) Given their demonstrated relevance to DOE remediation efforts and the availability of detailed genotypic/phenotypic characterization, Rhodanobacter denitrificans strain 2APBS1 and Geobacter daltonii strain FRC-32 represent ideal model organisms to provide a predictive understanding of subsurface microbial activity through metabolic modeling. Tasks II and III-Diversity and distribution of active anaerobes and Mechanisms linking electron transport and the fate of radionuclides: (1) Our study showed that members of genus Rhodanobacter and Geobacter are abundant and active in the uranium and nitrate contaminated subsurface. In the contaminant source zone of the Oak Ridge site, Rhodanobacter spp. are the predominant, active organisms detected (comprising