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Note: This page contains sample records for the topic "millivolt napl non-aqueous" from the National Library of EnergyBeta (NLEBeta).
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We encourage you to perform a real-time search of NLEBeta
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1

Smouldering Combustion of Organic Liquids in Porous Media for Remediating NAPL-contaminated Soils   

E-Print Network [OSTI]

This research investigated the potential of smouldering combustion to be employed as a remediation approach for soil contaminated by non-aqueous phase liquids (NAPLs). Small-scale (~15 cm), proof-of-concept experiments ...

Pironi, Paolo

2010-01-01T23:59:59.000Z

2

Project Overview: Successful Field-Scale in SITU Thermal NAPL Remediation  

SciTech Connect (OSTI)

The U.S. Department of Energy (DOE) successfully completed a field-scale remediation to remove non-aqueous phase liquids (NAPLs) from the subsurface at the Northeast Site on the Young-Rainey Science, Technology, and Research (STAR) Center, Largo, Florida. The Young-Rainey STAR Center is a former DOE facility that was previously known as the Pinellas Plant and the Pinellas STAR Center. The remediation project encompassed an area of 10,000 ft2 and depths extending to 35 ft below ground surface. Prior to the remediation, DOE evaluated technologies that had the potential to remove NAPLs from the subsurface at the site. Because of site conditions (clay lenses and an underlying clay layer that were thought to be contaminated), steam injection and electrical heating were considered to be the only technologies that had the potential to remove these NAPLs. In July 2001, DOE’s contractor awarded a subcontract for removal of NAPLs from a portion of the Northeast Site. The technologies used for remediation were a combination of steam-enhanced extraction and Electro-Thermal Dynamic Stripping Process, an electrical resistive heating technology. Construction of the remediation system was completed in September 2002. Remedial operations began immediately after construction, and active heating ended in February 2003. After operations were completed, confirmatory sampling was conducted during a 6-month period to verify the level of cleanup achieved. Additional confirmatory sampling was conducted 18 months after operations ended. Analytical results of the confirmatory sampling showed that NAPL concentrations were reduced significantly below the required cleanup goals and, in most cases, below the regulatory maximum contaminant levels. Lessons learned relative to the design, construction, operation, confirmatory sampling approach, and subcontracting could benefit managers of similar remediation projects.

Butherus, Michael [S.M. Stoller Corporation; Ingle, David S. [S.M. Stoller Corporation; Juhlin, Randall [S.M. Stoller Corporation; Daniel, Joseph [S.M. Stoller Corporation; none,

2004-10-24T23:59:59.000Z

3

Successful Field-Scale In Situ Thermal NAPL Remediation at the Young-Rainey Star Center  

SciTech Connect (OSTI)

The U.S. Department of Energy (DOE) successfully completed a fieldscale remediation to remove non-aqueous phase liquids (NAPLs) from the subsurface at a site on the Young-Rainey Science, Technology, and Research (STAR) Center, Largo, Florida. The STAR Center is a former DOE facility. The remediation project covered an area of 930 m2 (10,000 ft2) and depths extending to 10.5 m (35 ft) below ground surface. In July 2001, DOE’s contractor awarded a subcontract to SteamTech Environmental Services for removal of NAPLs from a portion of the Northeast Site. The technologies used for remediation were steam-enhanced extraction and Electro-Thermal Dynamic Stripping Process, an electrical resistive heating technology. McMillan-McGee Corporation implemented the process. Construction of the remediation system was completed in September 2002. Operations began immediately after construction, and active heating ended in February 2003. After operations were completed, confirmatory sampling was conducted over a 6-month period to verify the level of cleanup achieved. Results of the sampling showed that NAPL concentrations were reduced significantly below the required cleanup goals and, in most cases, below the regulatory maximum contaminant levels. Lessons learned relative to the design, construction, operation, confirmatory sampling approach, and subcontracting could benefit managers of similar remediation projects

Gavaskar, A.R. [ed.; Chen, A.S.C. [ed.; none,

2004-05-04T23:59:59.000Z

4

Phase Stability of Multicomponent NAPLs Containing PAHs  

E-Print Network [OSTI]

to produce complex synthetic NAPLs which can be used as surrogate materials to simulate the behavior of a contaminant is dependent on its phase state. For solid phase contaminants in contact with water, the maximum assessment, predicting remediation effectiveness, and experimental research. In this paper, we discuss NAPL

Peters, Catherine A.

5

Phenyl boron-based compounds as anion receptors for non-aqueous battery electrolytes  

DOE Patents [OSTI]

Novel fluorinated boronate-based compounds which act as anion receptors in non-aqueous battery electrolytes are provided. When added to non-aqueous battery electrolytes, the fluorinated boronate-based compounds of the invention enhance ionic conductivity and cation transference number of non-aqueous electrolytes. The fluorinated boronate-based anion receptors include different fluorinated alkyl and aryl groups.

Lee, Hung Sui (East Setauket, NY); Yang, Xiao-Qing (Port Jefferson Station, NY); McBreen, James (Bellport, NY); Sun, Xuehui (Middle Island, NY)

2002-01-01T23:59:59.000Z

6

A Practical Model for Mobile, Residual, and Entrapped NAPL in...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

A Practical Model for Mobile, Residual, and Entrapped NAPL in Water-Wet Porous Media. A Practical Model for Mobile, Residual, and Entrapped NAPL in Water-Wet Porous Media....

7

Secondary imbibition in NAPL-invaded mixed-wet sediments  

E-Print Network [OSTI]

Secondary imbibition in NAPL-invaded mixed-wet sediments Ahmed Al-Futaisia,b , Tad W. Patzekb to study the spontaneous and forced secondary imbibition of a NAPL-invaded sediment, as in the displacement-wet sediment, i.e., the receding contact angles are very small. However, depending on the surface mineralogy

Patzek, Tadeusz W.

8

Introduction The release of nonaqueous phase liquids (NAPLs) to  

E-Print Network [OSTI]

produced through the -decay of radium-226 Abstract Naturally occurring radon in ground water can create long-term sources of ground water contamination as the NAPL slowly dissolves into ground water (Mercer and Cohen 1990; Cohen and Mercer 1993). Effective remediation of subsurface NAPL contamination

Semprini, Lewis

9

Electrochemical studies of moderately boron doped polycrystalline diamond in non-aqueous solvent  

E-Print Network [OSTI]

Electrochemical studies of moderately boron doped polycrystalline diamond in non-aqueous solvent being marketed [83,84]. The first paper on the electrochemistry of boron doped polycrystalline diamond The electrochemistry of boron doped diamond is currently an active field of research. In the majority of studies

Bristol, University of

10

Application of a NAPL partitioning interwell tracer test (PITT) to support DNAPL remediation at the Sandia National Laboratories/New Mexico chemical waste landfill  

SciTech Connect (OSTI)

Chlorinated solvents as dense non-aqueous phase liquid (DNAPL) are present at a large number of hazardous waste sites across the U.S. and world. DNAPL is difficult to detect in the subsurface, much less characterize to any degree of accuracy. Without proper site characterization, remedial decisions are often difficult to make and technically effective, cost-efficient remediations are even more difficult to obtain. A new non-aqueous phase liquid (NAPL) characterization technology that is superior to conventional technologies has been developed and applied at full-scale. This technology, referred to as the Partitioning Interwell Tracer Test (PITT), has been adopted from oil-field practices and tailored to environmental application in the vadose and saturated zones. A PITT has been applied for the first time at full-scale to characterize DNAPL in the vadose zone. The PITT was applied in December 1995 beneath two side-by-side organic disposal pits at Sandia National Laboratories/New Mexico (SNL/NM) RCRA Interim Status Chemical Waste Landfill (CWL), located in Albuquerque, New Mexico. DNAPL, consisting of a mixture of chlorinated solvents, aromatic hydrocarbons, and PCE oils, is known to exist in at least one of the two buried pits. The vadose zone PITT was conducted by injecting a slug of non-partitioning and NAPL-partitioning tracers into and through a zone of interest under a controlled forced gradient. The forced gradient was created by a balanced extraction of soil gas at a location 55 feet from the injector. The extracted gas stream was sampled over time to define tracer break-through curves. Soil gas sampling ports from multilevel monitoring installations were sampled to define break-through curves at specific locations and depths. Analytical instrumentation such as gas chromatographs and a photoacoustical analyzers operated autonomously, were used for tracer detection.

Studer, J.E. [INTERA Inc., Albuquerque, NM (United States); Mariner, P.; Jin, M. [INTERA Inc., Austin, TX (United States)] [and others

1996-05-01T23:59:59.000Z

11

Method and device for removing a non-aqueous phase liquid from a groundwater system  

DOE Patents [OSTI]

A device for removing a non-aqueous phase liquid from a groundwater system includes a generally cylindrical push-rod defining an internal recess therein. The push-rod includes first and second end portions and an external liquid collection surface. A liquid collection member is detachably connected to the push-rod at one of the first and second end portions thereof. The method of the present invention for removing a non-aqueous phase liquid from a contaminated groundwater system includes providing a lance including an external hydrophobic liquid collection surface, an internal recess, and a collection chamber at the bottom end thereof. The lance is extended into the groundwater system such that the top end thereof remains above the ground surface. The liquid is then allowed to collect on the liquid collection surface, and flow downwardly by gravity into the collection chamber to be pumped upwardly through the internal recess in the lance.

Looney, Brian B. (Aiken, SC); Rossabi, Joseph (Aiken, SC); Riha, Brian D. (Augusta, GA)

2002-01-01T23:59:59.000Z

12

Long-Term Composition Dynamics of PAH-Containing NAPLs and  

E-Print Network [OSTI]

08544 Subsurface contaminants such as coal tar, creosote, diesel fuel, and other petroleum the factors governing human health risk assessment for multicomponent nonaqueous phase liquids (NAPLs of environmental pollution involving PAHs is subsurface contamination from nonaque- ous phase liquid (NAPL

Peters, Catherine A.

13

Preliminary analysis of NAPL behavior in soil-heated vapor extraction for in-situ environmental restoration  

SciTech Connect (OSTI)

Simulations of soil-heated vapor extraction have been performed to evaluate the NAPL removal performance as a function of borehole vacuum. The possibility of loss of NAPL containment, or NAPL migration into the unheated soil, is also evaluated in the simulations. A practical warning sign indicating migration of NAPL into the unheated zone is discussed.

Webb, S.W.; Phelan, J.M.

1995-10-01T23:59:59.000Z

14

Germany Picks Up Scent of In Solving Naples's Trash Crisis  

E-Print Network [OSTI]

1 Germany Picks Up Scent of Profit In Solving Naples's Trash Crisis By STACY MEICHTRY and ALMUT incinerators across Germany that have recently cut deals with the Italian government to burn up to 200,000 tons in northern Germany charge between 150 and 250 ($237 to $394) to incinerate one ton of waste, estimates

Columbia University

15

A Non-Aqueous Reduction Process for Purifying 153Gd Produced in Natural Europium Targets  

SciTech Connect (OSTI)

Gadolinium-153 is a low-energy gamma-emitter used in nuclear medicine imaging quality assurance. Produced in nuclear reactors using natural Eu2O3 targets, 153Gd is radiochemically separated from europium isotopes by europium reduction. However, conventional aqueous europium reduction produces hydrogen gas, a flammability hazard in radiological hot cells. We altered the traditional reduction method, using methanol as the process solvent to nearly eliminate hydrogen gas production. This new, non-aqueous reduction process demonstrates greater than 98% europium removal and gadolinium yields of 90%.

Johnsen, Amanda M.; Soderquist, Chuck Z.; McNamara, Bruce K.; Fisher, Darrell R.

2013-08-01T23:59:59.000Z

16

From Propaganda to Science: Looking at the World of Academies in Early Seventeenth-century Naples  

E-Print Network [OSTI]

Una Relazione Vicereale Sul Governo Del Regno Di Napoli Agliil settimo Anno del suo Governo (Naples: Beltrano, 1630), 51Paolo. Massime del governo spagnolo a Napoli, Introduzione

Gianfrancesco, Lorenza

2012-01-01T23:59:59.000Z

17

E-Print Network 3.0 - aquosa napls por Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

theory... can also potentially detect and quantify NAPL contamination. In this type of test, retardation factors Source: Istok, Jonathan "Jack" - School of Civil and...

18

The non-aqueous chemistry of uranium has been an active area of exploration in recent decades1,2  

E-Print Network [OSTI]

-purity depleted uranium produced as a by-product of nuclear isotope enrichment programmes. The early actinideThe non-aqueous chemistry of uranium has been an active area of exploration in recent decades1 for uranium will be created in part by the quest of researchers to understand the properties and potential

Cai, Long

19

Highly Quantitative Electrochemical Characterization of Non-Aqueous Electrolytes & Solid Electrolyte Interphases  

SciTech Connect (OSTI)

The methods to measure solid electrolyte interphase (SEI) electrochemical properties and SEI formation capability of non-aqueous electrolyte solutions are not adequately addressed in the literature. And yet, there is a strong demand in new electrolyte generations that promote stabilized SEIs and have an influence to resolve safety, calendar life and other limitations of Li-ion batteries. To fill this gap, in situ electrochemical approach with new descriptive criteria for highly quantitative characterization of SEI and electrolytes is proposed. These criteria are: SEI formation capacity, SEI corrosion rate, SEI maintenance rate, and SEI kinetic stability. These criteria are associated with battery parameters like irreversible capacity, self-discharge, shelf-life, power, etc. Therefore, they are especially useful for electrolyte development and standard fast screening, allowing a skillful approach to narrow down the search for the best electrolyte. The characterization protocol also allows retrieving information on interfacial resistance for SEI layers and the electrochemical window of electrolytes, the other important metrics of characterization. The method validation was done on electrolyte blends containing phosphazenes, developed at Idaho National Laboratory, as 1.2M LiPF6 [80 % EC-MEC (2:8) (v/v) + 20% Phosphazene variety] (v/v), which were targeted for safer electrolyte variations.

Sergiy V. Sazhin; Kevin L. Gering; Mason K. Harrup; Harry W. Rollins

2012-10-01T23:59:59.000Z

20

Cross borehole induced polarization to detect subsurface NAPL at the Savannah River Site, South Carolina  

E-Print Network [OSTI]

Spectral induced polarization measurements were acquired in six cross-borehole panels within four boreholes at the Savannah River Site. The investigation was performed to delineate the presence of dense non-aqueous phase ...

Lambert, Michael B. (Michael Brian), 1980-

2003-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "millivolt napl non-aqueous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Quantitative Chromatographic Determination of Dissolved Elemental Sulfur in the Non-aqueous Electrolyte for Lithium-Sulfur Batteries  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

A fast and reliable analytical method is reported for the quantitative determination of dissolved elemental sulfur in non-aqueous electrolytes for Li-S batteries. By using high performance liquid chromatography with a UV detector, the solubility of S in 12 different pure solvents and in 22 different electrolytes was determined. It was found that the solubility of elemental sulfur is dependent on the Lewis basicity, the polarity of solvents and the salt concentration in the electrolytes. In addition, the S content in the electrolyte recovered from a discharged Li-S battery was successfully determined by the proposed HPLC/UV method. Thus, the feasibility of the method to the online analysis for a Li-S battery is demonstrated. Interestingly, the S was found super-saturated in the electrolyte recovered from a discharged Li-S cell.

Zheng, Dong [Univ. of Massachusetts, Boston, MA (United States). Dept. of Chemistry; Yang, Xiao-Qing [Brookhaven National Laboratory (BNL), Upton, NY (United States). Chemistry Dept.; Zhang, Xuran [Wuhan Univ. of Technology, Hubei (China); Dept. of Chemistry; Li, Chao [Univ. of Massachusetts, Boston, MA (United States). Dept. of Chemistry; McKinnon, Meaghan E. [Univ. of Massachusetts, Boston, MA (United States). Dept. of Chemistry; Sadok, Rachel G. [Univ. of Massachusetts, Boston, MA (United States). Dept. of Chemistry; Qu, Deyu [Wuhan Univ. of Technology, Hubei (China); Dept. of Chemistry; Yu, Xiqian [Brookhaven National Laboratory (BNL), Upton, NY (United States). Chemistry Dept.; Lee, Hung-Sui [Brookhaven National Laboratory (BNL), Upton, NY (United States). Chemistry Dept.; Qu, Deyang [Univ. of Massachusetts, Boston, MA (United States). Dept. of Chemistry

2014-11-01T23:59:59.000Z

22

Non-Aqueous Solvation of n-Octanol and Ethanol: Spectroscopic and Computational Lori M. Levering, Carrigan J. Hayes, Karen M. Callahan, Christopher M. Hadad,* and  

E-Print Network [OSTI]

Non-Aqueous Solvation of n-Octanol and Ethanol: Spectroscopic and Computational Studies Lori M-H bonds in n-octanol and ethanol with the organic solvents carbon tetrachloride (CCl4), cyclohexane populations of each ethanol complex and are consistent with the experimental results. Additional spectra were

23

Refinement of the Kansas City Plant site conceptual model with respect to dense non-aqueous phase liquids (DNAPL)  

SciTech Connect (OSTI)

This document presents a refinement of the site conceptual model with respect to dense non-aqueous phase liquid (DNAPL) at the US Department of Energy Kansas City Plant (KCP). This refinement was prompted by a review of the literature and the results of a limited study that was conducted to evaluate whether pools of DNAPL were present in contaminated locations at the KCP. The field study relied on the micropurge method of sample collection. This method has been demonstrated as a successful approach for obtaining discrete samples within a limited aquifer zone. Samples were collected at five locations across 5-ft well screens located at the base of the alluvial aquifer at the KCP. The hypothesis was that if pools of DNAPL were present, the dissolved concentration would increase with depth. Four wells with highly contaminated groundwater were selected for the test. Three of the wells were located in areas where DNAPL was suspected, and one where no DNAPL was believed to be present. The results demonstrated no discernible pattern with depth for the four wells tested. A review of the data in light of the available technical literature suggests that the fine-grained nature of the aquifer materials precludes the formation of pools. Instead, DNAPL is trapped as discontinuous ganglia that are probably widespread throughout the aquifer. The discontinuous nature of the DNAPL distribution prevents the collection of groundwater samples with concentrations approaching saturation. Furthermore, the results indicate that attempts to remediate the aquifer with conventional approaches will not result in restoration to pristine conditions because the tortuous groundwater flow paths will inhibit the efficiency of fluid-flow-based treatments.

Korte, N.E.; Hall, S.C. [Oak Ridge National Lab., TN (United States); Baker, J.L. [AlliedSignal Corp., Kansas City, MO (United States). Dept. of Environmental Protection

1995-10-01T23:59:59.000Z

24

Prediction of the theoretical capacity of non-aqueous lithium-air Peng Tan, Zhaohuan Wei, W. Shyy, T.S. Zhao  

E-Print Network [OSTI]

/non-aqueous (hybrid), and solid-state. In aqueous [4­10], hybrid [11­16], and solid-state [17­24] lithium-air batter- ies, a solid-state layer is generally used to transport Li+ ions. The internal resistance associated with this solid plate can be a main factor that limits the performance of these types of battery. In non

Zhao, Tianshou

25

A Review of "Becoming Neapolitan. Citizen Culture in Baroque Naples" by John A. Marino  

E-Print Network [OSTI]

fail to see why art historians must give them a place of honor in future accounts of Western sculpture. John A. Marino. Becoming Neapolitan. Citizen Culture in Baroque Naples. Baltimore: The Johns Hopkins University Press, 2011. 342 pp. including... illustrations. $60. Review by r. burr litchfield, brown university. John Marino?s well written, carefully researched, and detailed book will be useful for those studying seventeenth-century Baroque festivities in their urban social setting. It contains a...

Litchfield, R. Burr

2011-01-01T23:59:59.000Z

26

HPPC EUROPAR August 31 Naples | Computer Architecture Group, Dept. Computer Science | 1 The Massively Parallel Computing Model GCA  

E-Print Network [OSTI]

HPPC ­ EUROPAR August 31 Naples | Computer Architecture Group, Dept. Computer Science | 1 Architecure Group #12;HPPC ­ EUROPAR August 31 Ischia | Computer Architecture Group, Dept. Computer Science Architecture Group, Dept. Computer Science | 3 Outline PART I: Global Cellular Automata (GCA) Cellular

Hoffmann, Rolf

27

Pore-scale analysis of thermal remediation of NAPL-contaminated subsurface environments  

E-Print Network [OSTI]

tension forces and (b) force ratios between forces as a function of oil saturation..??.??? 95 5-11 (a) Force ratio of push force to the driving force, showing the extent of contribution of push force to the driving force and (b) force ratios....9 0.95 1 1.05 1.1 1.15 1.2 0 20 40 60 80 100 T, oC ?, g /cm 3 ?w ?o (a) 0.135 0.136 0.137 0.138 0.139 0.14 0.141 0.142 0.143 0.144 0.145 0 20 40 60 80 100 T, oC ?? , g /cm 3 (b) Figure 2-1 Temperature-dependent change of (a) NAPL...

Ahn, Min

2009-05-15T23:59:59.000Z

28

Improved Predictions of Carbon Tetrachloride Contaminant Flow and Transport: Implementation of Kinetic Volatilization and Multicomponent NAPL Behavior  

SciTech Connect (OSTI)

Carbon tetrachloride (CT) was discharged to waste sites that are included in the 200-PW-1 Operable Unit in Hanford 200 West Area. Fluor Hanford, Inc. is conducting a Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) remedial investigation/feasibility study (RI/FS) for the 200-PW-1 Operable Unit. The RI/FS process and remedial investigations for the 200-PW-1, 200 PW-3, and 200-PW-6 Operable Units are described in the Plutonium/Organic-Rich Process Condensate/Process Waste Groups Operable Unit RI/FS Work Plan. As part of this overall effort, Pacific Northwest National Laboratory (PNNL) was contracted to improve the STOMP simulator (White and Oostrom, 2006) by incorporating kinetic volatilization of nonaqueous phase liquids (NAPL) and multicomponent flow and transport. This work supports the U.S. Department of Energy's (DOE's) efforts to characterize the nature and distribution of CT in the 200 West Area and subsequently select an appropriate final remedy. Previous numerical simulation results with the STOMP simulator have overestimated the effect of soil vapor extraction (SVE) on subsurface CT, showing rapid removal of considerably more CT than has actually been recovered so far. These previous multiphase simulations modeled CT mass transfer between phases based on equilibrium partitioning. Equilibrium volatilization can overestimate volatilization because mass transfer limitations present in the field are not considered. Previous simulations were also conducted by modeling the NAPL as a single component, CT. In reality, however, the NAPL mixture disposed of at the Hanford site contained several non-volatile and nearly insoluble organic components, resulting in time-variant fluid properties as the CT component volatilized or dissolved over time. Simulation of CT removal from a DNAPL mixture using single-component DNAPL properties typically leads to an overestimation of CT removal. Other possible reasons for the discrepancy between observed and simulated CT mass removal during SVE are differences between the actual and simulated (1) SVE flow rates, (2) fluid-media properties, and (3) disposal history (volumes, rates, and timing). In this report, numerical implementation of kinetic volatilization and multicomponent DNAPL flow and transport into the STOMP simulator (White and Oostrom, 2006) is described. The results of several test cases are presented and explained. The addition of these two major code enhancements increases the ability of the STOMP simulator to model complex subsurface flow and transport processes involving CT at the Hanford site.

Oostrom, Martinus; Zhang, Z. F.; Freedman, Vicky L.; Tartakovsky, Guzel D.

2008-09-29T23:59:59.000Z

29

A Review Essay: The Sexuality of Migration: Border Crossings and Mexican Immigrant Men (2009) by Lionel Lionel Cantú Jr. and edited by Nancy A. Naples and Salvador Vidal-Ortiz  

E-Print Network [OSTI]

. and edited by Nancy A. Naples and Salvador Vidal-Ortiz. New York: New York University Press, 2009, 256 pages, $22.00 Paper. Ray Sin University of Kansas Foucault reveals that sexuality and sexual identities are signifi- cant axes of power but it is only...

Ray, Sin

2009-01-01T23:59:59.000Z

30

Parallel Simulation of Bioreactive Multicomponent Transport Processes in  

E-Print Network [OSTI]

fuels (gasoline, diesel), petroleum byproducts (coal tar, creosote), and chlorinated solvents. In many in many non-aqueous phase liquids (NAPLs) or due to co-disposal/co-spillage (e.g., land#12;ll leachates

Kraeutle, Serge

31

NAPL Calculator - Energy Innovation Portal  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Opticalhttp://www.fnal.gov/directorate/nalcal/nalcal02_07_05_files/nalcal.gif Directorate - Events - FermilabSept2011 Page

32

Non-aqueous liquid compositions comprising ion exchange polymers  

DOE Patents [OSTI]

Compositions, and methods of making thereof, comprising from about 1% to about 5% of a perfluorinated sulfonic acid ionomer or a hydrocarbon-based ionomer; and from about 95% to about 99% of a solvent, said solvent consisting essentially of a polyol; wherein said composition is substantially free of water and wherein said ionomer is uniformly dispersed in said solvent.

Kim, Yu Seung (Los Alamos, NM); Lee, Kwan-Soo (Blacksburg, VA); Rockward, Tommy Q. T. (Rio Rancho, NM)

2011-07-19T23:59:59.000Z

33

Non-aqueous liquid compositions comprising ion exchange polymers  

DOE Patents [OSTI]

Compositions, and methods of making thereof, comprising from about 1% to about 5% of a perfluorinated sulfonic acid ionomer or a hydrocarbon-based ionomer; and from about 95% to about 99% of a solvent, said solvent consisting essentially of a polyol; wherein said composition is substantially free of water and wherein said ionomer is uniformly dispersed in said solvent.

Kim, Yu Seung; Lee, Kwan-Soo; Rockward, Tommy Q. T.

2013-03-12T23:59:59.000Z

34

Non-aqueous electrolyte for lithium-ion battery  

DOE Patents [OSTI]

The present technology relates to stabilizing additives and electrolytes containing the same for use in electrochemical devices such as lithium ion batteries and capacitors. The stabilizing additives include triazinane triones and bicyclic compounds comprising succinic anhydride, such as compounds of Formulas I and II described herein.

Zhang, Lu; Zhang, Zhengcheng; Amine, Khalil

2014-04-15T23:59:59.000Z

35

Non-aqueous solution preparation of doped and undoped lixmnyoz  

DOE Patents [OSTI]

A method for generation of phase-pure doped and undoped Li.sub.x Mn.sub.y O.sub.z precursors. The method of this invention uses organic solutions instead of aqueous solutions or nonsolution ball milling of dry powders to produce phase-pure precursors. These precursors can be used as cathodes for lithium-polymer electrolyte batteries. Dopants may be homogeneously incorporated to alter the characteristics of the powder.

Boyle, Timothy J. (5801 Eubank, N.E., Apt. #97, Albuquerque, NM 87111); Voigt, James A. (187 Aaramar La., Corrales, NM 87048)

1997-01-01T23:59:59.000Z

36

Fluorinated Arylboron Oxalate for Non-Aqueous Battery Electrolytes - Energy  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing ZirconiaPolicyFeasibilityFieldMinds" |beam damage in

37

Methods Note/ NAPL Source Zone Depletion Model  

E-Print Network [OSTI]

to evaluate groundwater contamination and cleanup times for four complex mixtures of concern in the railroad industry. Among the petroleum hydrocarbon mixtures considered, the cleanup time of diesel fuel was much LNAPLs adequately represent the economic risk of chemical spills. To assess the environmental risk

Barkan, Christopher P.L.

38

Naples, Maine: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to:46 -Energieprojekte3Informationof EnergyNapa County, California:Napier

39

Effect of immiscible liquid contaminants on P-wave transmission through natural aquifer samples  

SciTech Connect (OSTI)

We performed core-scale laboratory experiments to examine the effect of non-aqueous phase liquid (NAPL) contaminants on P-wave velocity and attenuation in heterogeneous media. This work is part of a larger project to develop crosswell seismic methods for minimally invasive NAPL detection. The test site is the former DOE Pinellas Plant in Florida, which has known NAPL contamination in the surficial aquifer. Field measurements revealed a zone of anomalously high seismic attenuation, which may be due to lithology and/or contaminants (NAPL or gas phase). Intact core was obtained from the field site, and P-wave transmission was measured by the pulse-transmission technique with a 500 kHz transducer. Two types of samples were tested: a clean fine sand from the upper portion of the surficial aquifer, and clayey-silty sand with shell fragments and phosphate nodules from the lower portion. Either NAPL trichloroethene or toluene was injected into the initially water-saturated sample. Maximum NAPL saturations ranged from 30 to 50% of the pore space. P-wave velocity varied by approximately 4% among the water-saturated samples, while velocities decreased by 5 to 9% in samples at maximum NAPL saturation compared to water-saturated conditions. The clay and silt fraction as well as the larger scatterers in the clayey-silty sands apparently caused greater P-wave attenuation compared to the clean sand. The presence of NAPLs caused a 34 to 54% decrease in amplitudes of the first arrival. The central frequency of the transmitted energy ranged from 85 to 200 kHz, and was sensitive to both grain texture and presence of NAPL. The results are consistent with previous trends observed in homogeneous sand packs. More data will be acquired to interpret P-wave tomograms from crosswell field measurements, determine the cause of high attenuation observed in the field data and evaluate the sensitivity of seismic methods for NAPL detection.

Geller, Jil T.; Ajo-Franklin, Jonathan B.; Majer, Ernest L.

2003-01-31T23:59:59.000Z

40

Non-aqueous liquid compositions comprising ion exchange polymers reference to related application  

DOE Patents [OSTI]

Compositions, and methods of making thereof, comprising from about 1% to about 5% of a perfluorinated sulfonic acid ionomer or a hydrocarbon-based ionomer; and from about 95% to about 99% of a solvent, said solvent consisting essentially of a polyol; wherein said composition is substantially free of water and wherein said ionomer is uniformly dispersed in said solvent.

Kim; Yu Seung (Los Alamos, NM), Lee; Kwan-Soo (Los Alamos, NM), Rockward; Tommy Q. T. (Rio Rancho, NM)

2012-08-07T23:59:59.000Z

Note: This page contains sample records for the topic "millivolt napl non-aqueous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Investigation of the Rechargeability of Li-O2 Batteries in Non-aqueous Electrolyte  

SciTech Connect (OSTI)

In order to understand the nature of the limited cycle life and poor energy efficiency associated with the secondary Li-O¬2 batteries the discharge products of primary Li-O2 cells at different depth of discharge (DOD) are systematically analyzed in this work. It is revealed that if discharged to 2.0 V a small amount of Li2O2 coexist with Li2CO3 and RO-(C=O)-OLi) in alkyl carbonate-based electrolyte. Further discharging the air electrodes to below 2.0 V the amount of Li2CO3 and LiRCO3 increases significantly due to the severe electrolyte decomposition. There is no Li2O detected in this alkyl carbonate electrolyte regardless of DOD. It is also found that the alkyl carbonate based electrolyte begins to decompose at 4.0 V during charging under the combined influences from the high surface area carbon, the nickel metal current collector and the oxygen atmosphere. Accordingly the impedance of the Li-O2 cell continues to increase after each discharge and recharge process indicating a repeated plating of insoluble lithium salts on the carbon surface. Therefore the whole carbon electrode becomes completely insulated only after a few cycles and loses the function of providing active tri-phase regions for the Li-oxygen batteries.

Xiao, Jie; Hu, Jian Z.; Wang, Deyu; Hu, Dehong; Xu, Wu; Graff, Gordon L.; Nie, Zimin; Liu, Jun; Zhang, Jiguang

2011-07-01T23:59:59.000Z

42

Microwave dielectric heating of non-aqueous droplets in a microfluidic device for nanoparticle synthesis  

E-Print Network [OSTI]

of segmented ow reactors, in comparison with their continuous counterparts, allows nanoliter volumes. Recent developments have been directed toward scaling out of the processes by adding reactors working to directly determine the temperature inside a single droplet. The maximum temperature achieved

43

Microscopic Insights into the Electrochemical Behavior of Non-aqueous Electrolytes in Supercapacitors  

SciTech Connect (OSTI)

Electric double-layer capacitors (EDLC) are electrical devices that store energy by adsorption of ionic species at the inner surface of porous electrodes. Compared with aqueous electrolytes, ionic liquid and organic electrolytes have the advantage of larger potential windows, making them attractive for the next generation of EDLC with superior energy and power densities. The performance of both ionic liquid and organic electrolyte EDLC hinges on the judicious selection of the electrode pore size and the electrolyte composition that requires a comprehension of the charging behavior from a microscopic view. In this perspective, we discuss predictions from the classical density functional theory (CDFT) on the dependence of the capacitance on the pore size for ionic-liquid and organic-electrolyte EDLC. CDFT is applicable to electrodes with the pore size ranging from that below the ionic dimensionality to mesoscopic scales, thus unique for investigating the electrochemical behavior of the confined electrolytes for EDLC applications.

Jiang, Deen [ORNL; Wu, Jianzhong [ORNL

2013-01-01T23:59:59.000Z

44

Northeast Site Non-Aqueous Phase Liquids Interim Measures Progress Report April through June 2003  

Office of Legacy Management (LM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou$0.C. 20545 OCT 28 1% - :NEW; I.-'7-TAC GJO-PIN

45

Northeast Site Non-Aqueous Phase Liquids Interim Measures Progress Report October through December 2002  

Office of Legacy Management (LM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou$0.C. 20545 OCT 28 1% - :NEW; I.-'7-TAC GJO-PIN700

46

Northeast Site Non-Aqueous Phase Liquids Interim Measures Progress Report-January through March 2003  

Office of Legacy Management (LM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou$0.C. 20545 OCT 28 1% - :NEW; I.-'7-TAC

47

Investigation of the Rechargeability of Li-O2 Batteries in Non-aqueous  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFunInfrared LandResponses toInvestigating

48

Final Report Northeast Site Area B NAPL Remediation Project  

Office of Legacy Management (LM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou$ EGcG ENERGYELIkNATION REPORTFairfield,

49

Microsoft Word - N0075800-NAPL April to June 04.doc  

Office of Legacy Management (LM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou$ EGcGand Surface

50

Northeast Site Area A NAPL Remediation Final Report.doc  

Office of Legacy Management (LM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou$0.C. 20545 OCT 28 1% - :NEW; I.-'

51

Kinetic investigation of catalytic disproportionation of superoxide ions in the non-aqueous electrolyte used in Li-air batteries  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

Superoxide reacts with carbonate solvents in Li–air batteries. Tris(pentafluorophenyl)borane is found to catalyze a more rapid superoxide (O2–) disproportionation reaction than the reaction between superoxide and propylene carbonate (PC). With this catalysis, the negative impact of the reaction between the electrolyte and O2– produced by the O2 reduction can be minimized. A simple kinetic study using ESR spectroscopy was reported to determine reaction orders and rate constants for the reaction between PC and superoxide, and the disproportionation of superoxide catalyzed by Tris(pentafluorophenyl)borane and Li ions. The reactions are found to be first order and the rate constants are 0.033 s–1 M–1, 0.020 s–1 M–1 and 0.67 s–1 M–1 for reactions with PC, Li ion and Tris(pentafluorophenyl)borane, respectively.

Wang, Qiang [Univ. of Massachusetts at Boston, Boston, MA (United States); Yang, Xiao -Qing [Brookhaven National Laboratory (BNL), Upton, NY (United States); Zheng, Doug [Univ. of Massachusetts at Boston, Boston, MA (United States); McKinnon, Meaghan E. [Univ. of Massachusetts at Boston, Boston, MA (United States); Qu, Deyang [Univ. of Massachusetts at Boston, Boston, MA (United States)

2015-01-01T23:59:59.000Z

52

HYDROGEL TRACER BEADS: THE DEVELOPMENT, MODIFICATION, AND TESTING OF AN INNOVATIVE TRACER FOR BETTER UNDERSTANDING LNAPL TRANSPORT IN KARST AQUIFERS  

SciTech Connect (OSTI)

The goal of this specific research task is to develop proxy tracers that mimic contaminant movement to better understand and predict contaminant fate and transport in karst aquifers. Hydrogel tracer beads are transported as a separate phase than water and can used as a proxy tracer to mimic the transport of non-aqueous phase liquids (NAPL). They can be constructed with different densities, sizes & chemical attributes. This poster describes the creation and optimization of the beads and the field testing of buoyant beads, including sampling, tracer analysis, and quantitative analysis. The buoyant beads are transported ahead of the dissolved solutes, suggesting that light NAPL (LNAPL) transport in karst may occur faster than predicted from traditional tracing techniques. The hydrogel beads were successful in illustrating this enhanced transport.

Amanda Laskoskie, Harry M. Edenborn, and Dorothy J. Vesper

2012-01-01T23:59:59.000Z

53

Acoustically enhanced remediation of contaminated soils and ground water. Volume 1  

SciTech Connect (OSTI)

The Phase 1 laboratory bench-scale investigation results have shown that acoustically enhanced remediation (AER) technology can significantly accelerate the ground water remediation of non-aqueous phase liquids (NAPLs) in unconsolidated soils. The testing also determined some of the acoustic parameters which maximize fluid and contaminant extraction rates. A technology merit and trade analysis identified the conditions under which AER could be successfully deployed in the field, and an analysis of existing acoustical sources and varying methods for their deployment found that AER technology can be successfully deployed in-situ. Current estimates of deployability indicate that a NAPL plume 150 ft in diameter can be readily remediated. This program focused on unconsolidated soils because of the large number of remediation sites located in this type of hydrogeologic setting throughout the nation. It also focused on NAPLs and low permeability soil because of the inherent difficult in the remediation of NAPLs and the significant time and cost impact caused by contaminated low permeability soils. This overall program is recommended for Phase 2 which will address the technology scaling requirements for a field scale test.

NONE

1995-10-01T23:59:59.000Z

54

Future Perspectives in melanoma research: Meeting report from the "Melanoma Research: a bridge Naples-USA. Naples, December 6th-7th 2010".  

E-Print Network [OSTI]

8:38. Pagès F, Berger A, Camus M, Sanchez-Cabo F, Costes A,Mlecnik B, Lagorce C, Tosolini M, Camus M, Berger A, Wind P,A, Bindea G, Berger A, Camus M, Gillard M, Bruneval P,

2011-01-01T23:59:59.000Z

55

Internal Reflection Sensor for the Cone Penetrometer  

SciTech Connect (OSTI)

The objectives of this project are to design, assemble, test, and demonstrate a prototype Internal Reflection Sensor (IRS) for the cone penetrometer. The sensor will ultimately be deployed during site characterization with the goal of providing real-time, in situ detection of NonAqueous Phase Liquids (NAPLs) in the subsurface. In the first phase of this program, we have designed and assembled an IRS module that interfaces directly to a standard cone penetrometer system. Laboratory tests demonstrated that the sensor responds in real-time to a wide variety of free phase NAPLs without interference from natural materials such as water and soil of various types or dissolved contaminants. In a preliminary field test, the sensor was able to locate NAPLs at thin, discrete depths in a soil test pit when deployed with a cone penetrometer. Ruggedness of the device was tested with a series of penetrometer pushes to the depth of refusal at a clean location. There was no visible damage to the sensor and its performance did not change in the course of these experiments. Based on the successes of the Phase I program, it is recommended that the project proceed to full-scale demonstration in Phase II.

Job Bello

1998-05-29T23:59:59.000Z

56

Pore-scale analysis of solubilization and mobilization of trapped NAPL blobs in porous media  

E-Print Network [OSTI]

was modified to quantify the onset of blob mobilization. Its value for water flooding was nearly 2-3 orders of magnitude greater than that of surfactant foam flooding. Next, to investigate the blob flow regime in porous media, a blob velocity was computed...

Yoon, Sun Hee

2009-06-02T23:59:59.000Z

57

Imaging the Angevin Patron Saint: Mary Magdalen in the Pipino Chapel in Naples  

E-Print Network [OSTI]

Cathedral of Lucera see, Egidi, “Colonia Saracena di Lucera”London: Longman, 1998. Egidi, Pietro “La Colonia Saracena diCharles II, see Pietro Egidi, “La Colonia Saracena di Lucera

Wilkins, Sarah S.

2012-01-01T23:59:59.000Z

58

An experimental study of horizontal barrier formation and containment of NAPLs by gelling liquids  

E-Print Network [OSTI]

[1990], much of the research on this topic can be found only in copies of company reports. Aul and Cervtk [1979] developed a method for grouting horizontal drainage holes in coalbeds. Karol [1990] noted that there has been a growing acceptance... grout for plugging horizontal methane-drainage holes. Lowther and Gabr [1997] experimented with urethane, a different grout, for the formation of hydraulic barriers. Voss et al. [1994] and May et al. [1986] studied chemical grouts for constructing...

Durmusoglu, Ertan

2012-06-07T23:59:59.000Z

59

Natural geological responses to anthropogenic alterations of the naples bay estuarine system  

E-Print Network [OSTI]

content. Grain size distribution for the grab samples and vibracores was evaluated using a Malvern? Mastersizer 2000 TM (Malvern, UK). The Mastersizer 2000 is a particle size analyzer using laser diffraction to produce a grain size distribution...

Fielder, Bryan Robert

2009-05-15T23:59:59.000Z

60

From Propaganda to Science: Looking at the World of Academies in Early Seventeenth-century Naples  

E-Print Network [OSTI]

Bohmerland, Sweitzerland, Netherland, Denmarke, Poland,Bohmerland, Sweitzerland, Netherland, Denmarke, Poland,

Gianfrancesco, Lorenza

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "millivolt napl non-aqueous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Determination of NAPL-Water Interfacial Areas in Well-Characterized Porous  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed Newcatalyst phasesData FilesShape, Density,TiO2(110). | EMSLDetermination of

62

Project Overview: Successful Field-Scale In Situ Thermal NAPL Remediation |  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of Energy Power.pdf11-161-LNG |September 15,2015 | Department ofThatGrid3 ProgramID Project NameDepartment

63

Microsoft Word - DOE_RM_DM-#100069-v1-NAPL_Quarterly_Oct-Dec_2004.DOC  

Office of Legacy Management (LM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou$ EGcGand Surface Water Samplingthrough December

64

Microsoft Word - DOE_RM_DM-#341474-v1-NAPL_Quarterly_April_-_June_2005.DOC  

Office of Legacy Management (LM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou$ EGcGand Surface Water Samplingthrough6 U.S.April67

65

Microsoft Word - DOE_RM_DM-#345139-v1-NAPL_Quarterly_Oct-Dec_2005.DOC  

Office of Legacy Management (LM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou$ EGcGand Surface Water Samplingthrough61 2005 - -L5

66

Microsoft Word - DOE_RM_DM-#350832-v1-NAPL_Quarterly_April-June_2006.DOC  

Office of Legacy Management (LM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou$ EGcGand Surface Water Samplingthrough61Northeast

67

Microsoft Word - N0071600-NAPL-Oct to Dec.doc  

Office of Legacy Management (LM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou$ EGcGand Surface WaterthroughLEGAL647005-TAC

68

Microsoft Word - N0074600-NAPL-Jan to March.doc  

Office of Legacy Management (LM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou$ EGcGand Surface WaterthroughLEGAL647005-TACJanuary

69

A Practical Model for Mobile, Residual, and Entrapped NAPL in Water-Wet  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert SouthwestTechnologies |November 2011A First LookMicroscopy for|

70

A comparison of models describing residual NAPL formation in the vadose  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert SouthwestTechnologies |November 2011A FirstEMSL ShellACalmodulin inU Tzone. |

71

Successful Field-Scale In Situ Thermal NAPL Remediation at the Young -  

Energy Savers [EERE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of Inspector GeneralDepartment of Energyof theRestoration at Young - Rainey Jan.Subscribe to4Successes of

72

Papertown: The Image of Naples and the Foundation of Poetry in Boccaccio’s Early Works  

E-Print Network [OSTI]

Pennsylvania Press, 1988. Battaglia-Ricci, Lucia. Ragionaretake into consideration L. Battaglia Ricci's beautiful book,23 Ibid, book 1, 1. 24 See L. Battaglia-Ricci, Ragionare nel

Alfano, Giancarlo

2012-01-01T23:59:59.000Z

73

Birori Goa Lima Mexico City Lisbon Naples Palermo Seville Soriano Liampo Villanovafranca Beyond Italy and New Spain  

E-Print Network [OSTI]

Italy and New Spain Itineraries for an Iberian Art History (1440-1640) Convened by Michael Cole Iberian Europe to the Kingdom of the New Spain. New proposals of itineraries for the origin and interpretation of corn cane sculptures Joana Barreto (Villa Medici, Rome): Spain, Italy, Flanders: Some Dynamics

Qian, Ning

74

Microsoft Word - DOE_RM_DM-#102768-v1-NAPL_Quarterly_Report_Jan-March_2005.ƒ  

Office of Legacy Management (LM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou$ EGcGand Surface Water Samplingthrough6 U.S.

75

Microsoft Word - DOE_RM_DM-#344133-v1-Final_NAPL_Quarterly_July-Sept_2005.Dƒ  

Office of Legacy Management (LM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou$ EGcGand Surface Water Samplingthrough61 2005 - -L

76

Microsoft Word - DOE_RM_DM-#99768-v1-NAPL_Quarterly_Report_for_July-Sept_20ƒ  

Office of Legacy Management (LM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou$ EGcGand Surface Waterthrough November 2006JulyJuly

77

The determination of sulfur-containing surfactants with a high pressure liquid chromatography-inductively coupled plasma emission spectrometry system  

E-Print Network [OSTI]

of the blank millivolt intensities 78 17 Average millivolt intensities for the nickel standard solution 79 Table Page 18 Standard deviations of the nickel standard millivolt intensities 80 19 Slopes of the calibration lines calculated from the blank... widely used sulfur-containing surfactants. The alkylbenzenesulfonates 1 strongly absorb in the UV region and, therefore are easily monitored by UV detectors. Other surfactants, such as alkyl sulfates 2 [13-17], alpha olefin sulfonates 3 [16...

Hobill, Jonathan Edward

1987-01-01T23:59:59.000Z

78

Giambattista Della Porta's Histrionic Science  

E-Print Network [OSTI]

istituzioni, culture di governo. Naples: Arte Tipografica,istituzioni, culture di governo (Naples: Arte criminals oversociale in Italia ed il governo di Filippo II” in Napoli e

Kodera, Sergius

2012-01-01T23:59:59.000Z

79

Mapping DNAPL transport contamination in sedimentary and fractured rock aquifers with high resolution borehole seismic imaging Project No. SF11SS13 FY01 Annual Report  

SciTech Connect (OSTI)

This report covers the work performed in the first year of a three-year project funded by the USDOE's Subsurface Contaminant Focus Area (SCFA). The objectives of this project are to develop, demonstrate and evaluate, at appropriate field sites, the utility of high frequency seismic imaging methods to detect and characterize non-aqueous phase liquid (NAPL) contamination in sedimentary and fractured rock aquifers. Field tests consist of crosswell seismic tomography acquired before, during and after any remediation action that would potentially affect fluid distributions. Where feasible, other characterization data is obtained, such as crosswell radar, borehole conductivity and cone penetration testing (CPT). Crosswell data are processed to obtain tomographic images, or two-dimensional distributions, of velocity and attenuation. The interpretation of the tomograms utilizes all available site characterization data to relate the geophysical attributes to lithology and fluid phase heterogeneities. Interpretations are validated by evaluation and testing of field cores. Laboratory tests on core retrieved from surveyed locations are performed to determine the relationships between geophysical parameters and solid and fluid phase composition. In the case of sedimentary aquifers, proof of principle has been demonstrated previously in homogeneous sand-packs at the centimeter and half-meter scale (Geller and Myer, 1995; Geller et al., 2000). The field tests will provide proof-of-principle at the field-scale, by working in an unconsolidated sand aquifer with known presence of NAPL. The ability to upscale from the laboratory to the field is evaluated by conducting field measurements over a range of frequencies that overlap the lowest frequencies used in the laboratory tests. In the fractured rock case, previous field work has shown that fracture zones can be detected by crosswell seismic tomography (Daley et al., 2001; Daley et al., 2000). Laboratory studies have demonstrated that the seismic wave signature is sensitive to the fracture stiffness, and that stiffness is affected by fracture-filling fluids (Pyrak-Nolte and Morris, 2000; Pyrak-Nolte, 1996). The field and laboratory experience provide a physical basis for the potential detection of fractures that would be the important flow paths for NAPL contaminants.

Geller, J.T.; Majer, E.L.; Peterson, J.E.; Williams, K.H.; Flexser, S.

2001-12-01T23:59:59.000Z

80

NATIONAL RADIO ASTRONOMY OBSERVATORY Green Bank, West Virginia  

E-Print Network [OSTI]

square law for low voltage and current. At high current the resistance of the diode and the load re function. The curve for Rx 1. 5 K ohm follows the square law curve for outputs from 10 millivolts to 150 millivolts. The Rx = 1. 5 K ohm curve starts near the one-diode curve and ap- proaches the two-diode curve

Groppi, Christopher

Note: This page contains sample records for the topic "millivolt napl non-aqueous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Prediction of risk-based screening levels for infiltration of volatile subsurface contaminants into buildings  

SciTech Connect (OSTI)

A Risk-Based Corrective Action (RBCA) approach is increasingly being used for the management of contaminated sites. Fundamental to this approach is the prediction of risk-based screening levels (RBSL) for operable exposure pathways. Screening level models currently used indicate that RBSLs for the indoor inhalation pathway can be significantly lower than other pathways typically considered. This paper presents the results of a screening level spreadsheet model used to predict human health risks resulting from infiltration of volatile organic compounds (VOCs) into buildings. The model was developed to derive RBSLs for soil and groundwater for possible future incorporation into the regulation of contaminated sites in British Columbia. Key features of the semi-analytical VOC infiltration model are steady-state diffusive mass transfer through soil coupled with advective and diffusive mass transfer through a cracked building floor slab or wall, source mass depletion of soil contaminants present using a mass balance approach, and the capability to incorporate multi-component chemical partitioning for soils containing non-aqueous phase liquid (NAPL). The critical factors affecting VOC infiltration and resulting health risks are presented.

Hers, I.; Zapf-Gilje, R.; Petrovic, S. [Golder Associates Ltd., Burnaby, British Columbia (Canada); Macfarlane, M.; McLenehan, R. [British Columbia Ministry of Environment, Lands and Parks, Victoria, British Columbia (Canada)

1997-09-01T23:59:59.000Z

82

Groundwater Fate and Transport Modeling for Texarkana Wood Preserving Company Superfund Site, Texarkana, Texas  

SciTech Connect (OSTI)

Fate and transport model results are presented for the Texarkana Wood Preserving Company (TWPC)superfund site. The conceptual model assumes two sources of contamination, specifically, the areas around the old and new process areas. Recent data show the presence of non-aqueous phase liquids (NAPL) in the aquifer that are also sources of dissolved contamination in the aquifer. A flow model was constructed and calibrated against measured hydraulic heads at permanent monitoring wells. Good matches were obtained between model simulated heads and most measured heads. An unexplained exception occurs at monitoring well MW-13 down gradient of the site beyond the measured contaminant plume where the model predicts heads that are more than 2 ft. lower than reported field measurements. Adjusting hydraulic parameters in the model could not account for this anomaly and still preserve the head matches at other wells. There is likely a moderate deficiency in the conceptual model or perhaps a data error. Other information such as substantial amounts of infiltrating surface water in the area or a correction in surveyed elevation would improve the flow model. A particle tracking model calculated a travel time from the new process area to the Day’s Creek discharge location on the order of 40 years. Travel times from the old process area to Day’s Creek were calculated to be on the order of 80 years. While these calculations are subject to some uncertainty, travel times of decades are indicated.

Arnett, Ronald Chester

1999-08-01T23:59:59.000Z

83

International Astronautical Congress, Naples, Italy. Copyright 2012 by the International Astronautical Federation. All rights reserved. IAC-12-D5.2.11 Page 1 of 14  

E-Print Network [OSTI]

by the European Space Agency (ESA) to conduct the operations for European scientific experiments on board

Tronci, Enrico

84

Voir Naples et pourrir. L'origine de la contamination chez les alchimistes (XVIe Vronique Adam, Universit Toulouse II Le Mirail  

E-Print Network [OSTI]

traités savants de l'antiquité greco-romaine et du monde arabo-persan, comme sur les textes religieux et

Boyer, Edmond

85

Turning greenhouse gases into gold  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

into an acidic solution of pyridine and CO2 and charging it with just 600 millivolts of electricity, the CO2 could be transformed into formic acid, formaldehyde and methanol. Now...

86

Systems integration and upgrade of an Engineering Flight Simulator  

E-Print Network [OSTI]

Training System Head-down-display Head-up-display Hertz (cycles per second) Level of detail Input / output Light emitting diode Multi Channel Option Millivolt SEI Serial Encoder Interface VME VERSA Module device TABLE OF CONTENTS Page ABSTRACT...

Alcorn, William Pleasant

2002-01-01T23:59:59.000Z

87

E-Print Network 3.0 - acute hospital bed Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Orlando, FL Summary: Downtown Naples Hospital Naples Acute Care 420 2,815.7 12;18 County Hospital Name City Type Number Beds... Hospital Clearwater Acute Care 687 2,130.9...

88

Streamline simulation of Surfactant Enhanced Aquifer Remediation  

E-Print Network [OSTI]

Nonaqueous Phase Liquids (NAPLS) are a recognized source of groundwater contamination. Surfactant Enhanced Aquifer Remediation (SEAR) shows promise in increasing the efficiency and effectiveness over traditional "pump and treat" NAPL remediation...

Tunison, Douglas Irvin

1996-01-01T23:59:59.000Z

89

Transport in Porous Media 38: 223240, 2000. c 2000 Kluwer Academic Publishers. Printed in the Netherlands.  

E-Print Network [OSTI]

in the Netherlands. 223 Laboratory, Field and Modeling Studies of Radon-222 as a Natural Tracer for Monitoring NAPL

Semprini, Lewis

90

Investigation of the Rechargeability of Li-O2 Batteries in Non...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the Rechargeability of Li-O2 Batteries in Non-aqueous Electrolyte. Investigation of the Rechargeability of Li-O2 Batteries in Non-aqueous Electrolyte. Abstract: In order to...

91

STMVOC User's Guide  

E-Print Network [OSTI]

heat capacity constant from Reid ct Format (5E12.5) RHOREF, TDENRF, DIFV0, TDIFRF, TEXPO RHOREF TDENRF reference NAPL (liquid)

Falta, R.W.

2010-01-01T23:59:59.000Z

92

Estimation of Interfacial Tension between Organic Liquid Mixtures...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

processes, including NAPL remediation with surfactants or alcohol flushing, enhanced oil recovery, and chemical separation technologies, yet available literature values are...

93

ZnS/Zn(O,OH)S-based buffer layer deposition for solar cells  

DOE Patents [OSTI]

The invention provides CBD ZnS/Zn(O,OH)S and spray deposited ZnS/Zn(O,OH)S buffer layers prepared from a solution of zinc salt, thiourea and ammonium hydroxide dissolved in a non-aqueous/aqueous solvent mixture or in 100% non-aqueous solvent. Non-aqueous solvents useful in the invention include methanol, isopropanol and triethyl-amine. One-step deposition procedures are described for CIS, CIGS and other solar cell devices.

Bhattacharya, Raghu N. (Littleton, CO)

2009-11-03T23:59:59.000Z

94

E-Print Network 3.0 - aqueous wastes wet Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fluid Wastes General Description Light hydrocarbons & non aqueous solvents Medium to heavy... -weight hydrocarbons etc. Low water content aqueous wastes Dirty solvents High...

95

A Discussion on Improved HTMs  

Broader source: Energy.gov (indexed) [DOE]

same polymer molecule. b) Membrane - Two-polymer composites. One polymer provides mechanical strength while the other polymer enables proton conduction. Strategy 2 - Non-aqueous...

96

REVIEW PAPER The case for sequencing the genome of the electric eel  

E-Print Network [OSTI]

of years, electric fish have evolved an exceptional capacity to generate aweak (millivolt) electric fieldinREVIEW PAPER The case for sequencing the genome of the electric eel Electrophorus electricus J. S July 2007) A substantial international community of biologists have proposed the electric eel

Stoddard, Philip

97

Environ. Sci. Technol. 1993, 27, 2831-2843 Coal Tar Dissolution in Water-Miscible Solvents: Experimental Evaluation  

E-Print Network [OSTI]

Mellon University, Pittsburgh, Pennsylvania 15213 Coal tar, a dense nonaqueous phase liquid (NAPL coal tar and water. Introduction Todaythereisgrowingconcernaboutnonaqueousphase liquids (NAPLs),a classEnviron. Sci. Technol. 1993, 27, 2831-2843 Coal Tar Dissolution in Water-Miscible Solvents

Peters, Catherine A.

98

Mass Transfer of Polynuclear Aromatic Hydrocarbons from  

E-Print Network [OSTI]

of the individual components of four synthetic dense non-aqueous phase liquid (DNAPL) mixtures into the aqueous hydrocarbons (PAHs), were designed to serve as models for coal tars and creosotes. The reactor employed (PAHs) are often present in the environment as components of such dense non- aqueous phase liquids

Peters, Catherine A.

99

Apparatus for hydrocarbon extraction  

DOE Patents [OSTI]

Systems and methods for hydrocarbon extraction from hydrocarbon-containing material. Such systems and methods relate to extracting hydrocarbon from hydrocarbon-containing material employing a non-aqueous extractant. Additionally, such systems and methods relate to recovering and reusing non-aqueous extractant employed for extracting hydrocarbon from hydrocarbon-containing material.

Bohnert, George W.; Verhulst, Galen G.

2013-03-19T23:59:59.000Z

100

Removing sulphur oxides from a fluid stream  

DOE Patents [OSTI]

A process for removing sulphur oxides from a fluid stream, such as flue gas, comprising: providing a non-aqueous absorption liquid containing at least one hydrophobic amine, the liquid being incompletely miscible with water; treating the fluid stream in an absorption zone with the non-aqueous absorption liquid to transfer at least part of the sulphur oxides into the non-aqueous absorption liquid and to form a sulphur oxide-hydrophobic amine-complex; causing the non-aqueous absorption liquid to be in liquid-liquid contact with an aqueous liquid whereby at least part of the sulphur oxide-hydrophobic amine-complex is hydrolyzed to release the hydrophobic amine and sulphurous hydrolysis products, and at least part of the sulphurous hydrolysis products is transferred into the aqueous liquid; separating the aqueous liquid from the non-aqueous absorption liquid. The process mitigates absorbent degradation problems caused by sulphur dioxide and oxygen in flue gas.

Katz, Torsten; Riemann, Christian; Bartling, Karsten; Rigby, Sean Taylor; Coleman, Luke James Ivor; Lail, Marty Alan

2014-04-08T23:59:59.000Z

Note: This page contains sample records for the topic "millivolt napl non-aqueous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

This book is dedicated to Harry Blum, who started it all.  

E-Print Network [OSTI]

This book is dedicated to Harry Blum, who started it all. #12;#12;Preface The last half century has," C. N. R., Pozzuoli, Naples, Italy. Ali Shokoufandeh Department of Computer Science, Drexel

Dudek, Gregory

102

Fluid Type Density 0.344 3.44E+02  

E-Print Network [OSTI]

. Ajo-Franklin * Jil T. Geller (LBNL) Ernest L. Majer (LBNL) John E. Peterson (LBNL) Kenneth H. Williams (LBNL) Jerry M. Harris (Stanford) Integrated Geophysical Characterization Of A NAPL-Contaminated Site

Ajo-Franklin, Jonathan

103

A Cinematic Nation: Representation, Regionalism, and the National Question in Postwar Italy  

E-Print Network [OSTI]

with little industrial development outside of localized metallurgical, mining, and handcraft endeavors centered in Naples and Palermo. Some citrus crops and grains were exported to France, Spain, and North America, but ties to northern Italian markets were...

Piepergerdes, Brent Jeffrey

2009-12-14T23:59:59.000Z

104

Numerical and experimental investigation of DNAPL removal mechanisms in a layered porous medium by means of soil vapor extraction  

SciTech Connect (OSTI)

The purpose of this work is to identify the mechanisms that govern the removal of carbon tetrachloride (CT) during soil vapor extraction (SVE) by comparing multiphase flow simulations with a detailed data set from a well-defined two-dimensional flow cell experiment. The flow cell was packed with two sandy soils including an embedded fine-grained sand layer. Gas concentrations at the outlet of the flow cell and 15 sampling ports inside the flow cell were measured during SVE. A dual-energy gamma radiation system was used to measure an initial NAPL saturation profile in a fine-grained sand layer. Imaging result from a dual-energy gamma radiation system with dyed CT mark along CT migration was used to construct the distribution of initial NAPL saturation in the flow cell for input to numerical simulations. Gas concentration results and photographs during SVE were compared to simulation results using a continuum-based multiphase flow simulator, STOMP (Subsurface Transport Over Multiple Phases). The measured effluent gas concentration decreased quickly at first, and then started to decrease gradually, resulting in long-term tailing. CT mass was removed quickly in coarse sand, followed by a slow removal from the fine-grained sand layer. An analytical solution for a one-dimensional advection and first-order volatilization model matched the tailing well with two fitting parameters. However, given detailed knowledge of the permeability field and initial NAPL distribution, we can predict the tailing and gas concentration profiles at sampling ports using equilibrium NAPL volatilization. NAPL flow occurs in the presence of free NAPL, and must be accounted for to accurately predict NAPL removal during the SVE experiment. The model prediction was accurate within the uncertainty of the measured or literature derived parameters (i.e., dispersivity and soil parameters). This study provides insights into the physical mechanisms of NAPL removal from a low permeability zone, and use of the local equilibrium assumption for NAPL volatilization during SVE. In addition, this study demonstrates that lack of detailed information regarding NAPL distribution and heterogeneity pattern lead overall NAPL removal to a kinetically controlled system at a 2-D flow cell scale.

Yoon, Hongkyu; Oostrom, Martinus; Wietsma, Thomas W.; Werth, Charles J.; Valocchi, Albert J.

2009-10-13T23:59:59.000Z

105

A comparative study of analytical models to estimate the LNAPL mound formation  

E-Print Network [OSTI]

is constant for the duration of the spreading. Secondly, the model does not consider the organic phase which is held up as residual saturation in the unsaturated zone above the water table. Holzer [1976] used the saltwater/freshwater analogy to study... hydrocarbon. Reible et al. , [1991] developed a model to describe the one-dimensional infiltra- tion of a NAPL through an unsaturated zone initially at residual water saturation. tion of a NAPL through an unsaturated zone initially at residual water...

Ahmed, Ashfaq

1994-01-01T23:59:59.000Z

106

CX-010908: Categorical Exclusion Determination | Department of...  

Broader source: Energy.gov (indexed) [DOE]

Determination Bench-Scale Development of a Non-Aqueous Solvent (NAS) Carbon Dioxide (CO2) Capture Process for Coal-Fired Power Plants CX(s) Applied: B3.6 Date: 09252013...

107

DNAPL remediation of fractured rock evaluated via numerical simulation   

E-Print Network [OSTI]

Fractured rock formations represent a valuable source of groundwater and can be highly susceptible to contamination by dense, non-aqueous phase liquids (DNAPLs). The goal of this research is to evaluate the effectiveness ...

Pang, Ti Wee

2010-01-01T23:59:59.000Z

108

NETL F 451.1/1-1, Categorical Exclusion Designation Form  

Broader source: Energy.gov (indexed) [DOE]

Linde, LLC SCCCapture Division FY14-15 1012013 - 9302015 Steve Mascaro Murray Hill, NJ Bench-Scale Development of a Non-Aqueous Solvent (NAS) CO2 Capture Process for...

109

NETL F 451.1/1-1, Categorical Exclusion Designation Form  

Broader source: Energy.gov (indexed) [DOE]

SCCCapture Division FY14-15 1012013 - 9302015 Steve Mascaro Research Triangle Park, Durham, NC Bench-Scale Development of a Non-Aqueous Solvent (NAS) CO2 Capture Process for...

110

TEMPO-based Catholyte for High Energy Density Nonaqueous Redox Flow Batteries  

SciTech Connect (OSTI)

We will present a novel design lithium-organic non-aqueous redox flow battery based on a TEMPO catholyte. This RFB produced desired electrochemical performance exceeding most of the currently reported nonaqueous RFB systems.

Wei, Xiaoliang; Xu, Wu; Vijayakumar, M.; Cosimbescu, Lelia; Liu, Tianbiao L.; Sprenkle, Vincent L.; Wang, Wei

2014-12-03T23:59:59.000Z

111

CX-012256: Categorical Exclusion Determination  

Broader source: Energy.gov [DOE]

Bench-Scale Development of a Non-Aqueous Solvent Carbon Dioxide Capture Process CX(s) Applied: B3.6 Date: 09/11/2014 Location(s): Norway Offices(s): National Energy Technology Laboratory

112

Experimental and theoretical modeling of DNAPL transport in vertical fractured media  

E-Print Network [OSTI]

In recent years, groundwater contamination by dense, non-aqueous phase liquids (DNAPLs) such as chlorinated solvents and polychlorinated biphenyls (PCBs) has become an important environmental concern in many industrialized ...

Levy, Laurent Claude, 1973-

2003-01-01T23:59:59.000Z

113

Scaling fluid content-pressure relations of different fluid systems in porous media  

SciTech Connect (OSTI)

Two-fluid-phase relations among fluid saturations (S) and pressures (P) have historically been used to predict S-P relations for three-fluid-phase systems consisting of a gas, nonaqueous phase liquid (NAPL), and water, because measurements of three-phase S-P relations are complex. Two-phase S-P relations of air-NAPL systems are generally used to predict the behavior between total-liquid saturations of three-phase systems and air-NAPL capillary pressures. Two-phase S-P relations of NAPL-water systems are generally used to predict the behavior between water saturations of three-phase systems and NAPL-water capillary pressures. Because S-P measurements are very time-consuming, investigators have attempted to scale S-P relations so that fewer measurements would be required. A S-P scaling technique is discussed in this paper, and methods to predict the scaling factors are evaluated.

Lenhard, R.J.

1994-04-01T23:59:59.000Z

114

The investigation of atmospheric humidity control by hot gas reheat  

E-Print Network [OSTI]

Number 1, 2, and 3 24 10 Psychrometric Chart with the Processes of Runs Number 1, 2, and 3 Superimposed Upon One Another 25 Nossle Performance Curvos 31 vi LIST OF SM30LS ~Sbol OF ~tit Cubic feet per minute Constant pressure specific heat... tempera- ture L2/T2 in. Hg in, H2O MV PD psig sp gr tdb Inches of mercury Inches of water Pounds mass Pounds mass dry air Pounds mass water vapor Millivolt s Pressure diff'erential (in. Hg) Gage pressure Heat added or re...

Whitlock, Paul Leroy

1963-01-01T23:59:59.000Z

115

Equilibria in aqueous iodine solutions  

E-Print Network [OSTI]

for the determination of pH and. 1odide concentration. This instrument, reads pH to 0. 001 pH units and millivolts to F 1 mv. An Orion Specific Ion Electrode, Iodide Model 94-53, was used in the iodide determination. A Corning Triple Purpose pH glass elect- rode... with such electrodes fully confirms this statement. The optimum concentration of Solution I was found to be between 5 x 10 and 10 H iodide. Error in ZIIF Although short-term reproducibility to within 0. 001 26 pH unit can in principle be achieved. with the glass...

Burger, Joanne Denise

1970-01-01T23:59:59.000Z

116

Enzocide - a chemical dip for the reduction of Salmonella on chicken breast skin  

E-Print Network [OSTI]

, Kansas City, MO) to a final product temperature of 79'C. Each sample was combined with three times as much water as the sample weight and blended in a Virtis Homogenizer 23 (Gardiner, NY) for one minute. Replicates of each sample were then placed... was connected to a Corning Science Products 240 pH meter (Corning, NY). Fifty mL of unknown solution and was added 1 mL of the 5 M NaNO, ionic strength adjustor solution to a 100 mL beaker and stirred. Millivolt readings were recorded after the solution had...

Bianchi, Aldo

1993-01-01T23:59:59.000Z

117

Transformer current sensor for superconducting magnetic coils  

DOE Patents [OSTI]

The present invention is a current transformer for operating currents larger than 2kA (two kiloamps) that is capable of detecting a millivolt level resistive voltage in the presence of a large inductive voltage. Specifically, the present invention includes substantially cylindrical primary turns arranged to carry a primary current and substantially cylindrical secondary turns arranged coaxially with and only partially within the primary turns, the secondary turns including an active winding and a dummy winding, the active and dummy windings being coaxial, longitudinally separated and arranged to mutually cancel voltages excited by commonly experienced magnetic fields, the active winding but not the dummy winding being arranged within the primary turns.

Shen, S.S.; Wilson, C.T.

1985-04-16T23:59:59.000Z

118

Lithium-titanium-oxide anodes for lithium batteries  

DOE Patents [OSTI]

A spinel-type structure with the general formula Li[Ti.sub.1.67 Li.sub.0.33-y M.sub.y ]O.sub.4, for 0non-aqueous electrochemical cell and in a non-aqueous battery comprising an plurality of cells, electrically connected, each cell comprising a negative electrode, an electrolyte and a positive electrode, the negative electrode consisting of the spinel-type structure disclosed.

Vaughey, John T. (Elmhurst, IL); Thackeray, Michael M. (Naperville, IL); Kahaian, Arthur J. (Chicago, IL); Jansen, Andrew N. (Bolingbrook, IL); Chen, Chun-hua (Westmont, IL)

2001-01-01T23:59:59.000Z

119

Pore-scale characteristics of multiphase flow in porous media: A comparison of airwater and oilwater experiments  

E-Print Network [OSTI]

Pore-scale characteristics of multiphase flow in porous media: A comparison of air­water and oil area, we have used a synchrotron-based CMT technique to obtain high-resolution 3D images of flow Ltd. All rights reserved. Keywords: Multi-phase flow; NAPLs; Porous media; Microtomography

Wildenschild, Dorthe

120

MODAL PARAMETER ESTIMATION FOR OPERATIONAL WIND TURBINES Emilio Di Lorenzo1, 2  

E-Print Network [OSTI]

MODAL PARAMETER ESTIMATION FOR OPERATIONAL WIND TURBINES Emilio Di Lorenzo1, 2 , Simone Manzato1 Claudio 21, 80125 Naples, Italy emilio.dilorenzo@lmsintl.com ABSTRACT Wind turbines are time. This assumption holds in the case of parked wind turbines, but not in the case of operating wind turbines

Boyer, Edmond

Note: This page contains sample records for the topic "millivolt napl non-aqueous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Management of Large-Scale International  

E-Print Network [OSTI]

. Shore C. Strawbridge G. Zollo Oak Ridge National Laboratory, USA Savannah River National Laboratory, USA River National Laboratory December 3, 2009 Fusion Power Associates Thirty-year Anniversary Meeting Oak Ridge National Laboratory, USA University of Naples Federico, Secundo, Italy #12;Project

122

ORIGINAL PAPER Conditional simulations of wateroil flow in heterogeneous porous  

E-Print Network [OSTI]

water standards. Thus, a small amount of NAPL can contaminate large volumes of groundwater over a long period of time. Therefore, it is very important to understand the processes associated with contaminant is a complicated mixture of hydrocarbon fluids, brine, porous rock and fractures. The structure of the void space

Lu, Zhiming

123

Euro Chordates: Ascidian Community Swims Ahead. The 4th International Tunicate Meeting  

E-Print Network [OSTI]

in the early 1990s, that is just before siRNA gene interference was discovered, leading to an explosive growth, Japan 4 Shimoda Marine Research Center, University of Tsukuba, Shimoda, Shizuoka, Japan 5 Stazione Zoologica "Anton Dohrn", Naples, Italy 6 Sars Centre for Marine Molecular Biology, Bergen High Technology

Villefranche sur mer

124

Earthquake early warning: Concepts, methods and physical grounds Claudio Satriano a,c,n  

E-Print Network [OSTI]

methodologies and procedures have been studied and developed. The leading experience of countries like Japan Federico II, Naples, Italy d Seismological Laboratory California Institute of Technology, USA a r t i c l e July 2010 a b s t r a c t Modern technology allows real-time seismic monitoring facilities to evolve

Wu, Yih-Min

125

Copyright 2009 The Author(s) Journal compilation 2009 National Ground Water Association.  

E-Print Network [OSTI]

Following a Release of Neat Ethanol onto Pre-existing NAPL by Brent P. Stafford, Natalie L. Cápiro, Pedro J.J. Alvarez, and William G. Rixey Abstract Neat ethanol (75.7 L) was released into the upper capillary zone the capillary zone to 10 cm below the water table. Maximum aqueous concentrations of ethanol were 20% v

Alvarez, Pedro J.

126

Nexans & Pirelli Awarded Major Energy Sector Contract  

E-Print Network [OSTI]

km (56 miles) of new high-voltage cables. The contract calls for the manufacture and laying of three. Pirelli will manufacture and install two submarine power cables and one telecommunications cable. These cables will be manufactured at Pirelli's Arco Felice (Naples), Italy plant. The Pirelli share

Kavehrad, Mohsen

127

Seismic waveform classification for automatic detection and improved location of volcanic events Charlotte Rowe and Jonathan MacCarthy, Los Alamos National Laboratory, Los Alamos, New  

E-Print Network [OSTI]

Charlotte Rowe and Jonathan MacCarthy, Los Alamos National Laboratory, Los Alamos, New Mexico, U, Menlo Park, California, U.S.A. Flora Giudicepietro, Osservatorio Vesuviano, Naples, Italy Richard: Dr. Charlotte Rowe EES-11, M.S. D-408 Los Alamos National Laboratory Los Alamos, new Mexico 87545 U

Rowe, Charlotte

128

A model for enhanced fluid percolation in porous media by application of low-frequency elastic waves  

E-Print Network [OSTI]

, primarily in connection with the appli- cations to enhanced oil recovery (EOR) and remediation of nonaqueousA model for enhanced fluid percolation in porous media by application of low-frequency elastic can significantly enhance transport of nonaqueous phase liquids (NAPLs) in porous media. Our analyses

Beresnev, Igor

129

Autonomous Remote Crack Displacement Monitoring of a Residence Near a Limestone  

E-Print Network [OSTI]

Autonomous Remote Crack Displacement Monitoring of a Residence Near a Limestone Quarry, Naples a limestone quarry. The object is to quantitatively compare crack re- sponse to blast-induced ground motion for construction and raw materials. For instance, neighbors of road aggregate quarries often perceive

130

CURRICULUM VITAE Kathryn Bard  

E-Print Network [OSTI]

of Naples "l'Orientale"/Boston University Excavations at Mersa/Wadi Gawasis, Egypt Degrees: Ph. Manzo. Mersa/Wadi Gawasis. A Pharaonic Harbor on the Red Sea. Cairo: Supreme Council of Antiquities-editor, with R. Fattovich, Harbor of the Pharaohs to the Land of Punt. Archaeological Investigations at Mersa/Wadi

Spence, Harlan Ernest

131

ARAMIS: An integrated risk assessment methodology for SEVESO Plants  

E-Print Network [OSTI]

, SEVESO, land use planning, risk reduction, safety barriers, safety culture, safety management the needs of various stakeholders concerned by the safety of industrial plants. ARAMIS is divided into six, published in "2. International Conference on safety and environment in process industry (CISAP-2), Naples

Paris-Sud XI, Université de

132

NATURAL HAZARDS ON ALLUVIAL FANS: THE VENEZUELA DEBRIS FLOW AND FLASH FLOOD DISASTER  

E-Print Network [OSTI]

NATURAL HAZARDS ON ALLUVIAL FANS: THE VENEZUELA DEBRIS FLOW AND FLASH FLOOD DISASTER In December Venezuela. Rainfall on December 2-3 totaled 200 millimeters (8 inches) and was followed by a major storm, Denver, Colorado, Naples, Italy, and Vargas, Venezuela. In time scales spanning thousands of years

Eaton, L. Scott

133

A stochastic analysis of transient two-phase flow in heterogeneous porous media  

E-Print Network [OSTI]

the finite element heat and mass (FEHM) transfer code, whose results are considered ``true'' solutions equation (KLME) approach is implemented to model stochastic transient water-NAPL two-phase flow model and Parker and Lenhard models are adopted. The log-transformed intrinsic permeability, soil pore

Lu, Zhiming

134

BIOCATALYSIS AND METABOLIC ENGINEERING CHEM /6760 Spring  

E-Print Network [OSTI]

in science and engineering. REQUIRED Biotransformations in Organic Chemistry, Kurt Faber TEXTS: Springer, 5th: revolutionizing the areas of pharmaceuticals, fine chemistry, and biofuels over the next years, as biologically: biocatalysis in non-aqueous media 13 02/21 Mid-term (open book, open notes) 14 02/26 Enzymes as products

Sherrill, David

135

Electrode compositions  

DOE Patents [OSTI]

An electrode composition is described for use as an electrode in a non-aqueous battery system. The electrode composition contains an electrically active powder in a solid polymer and, as a dispersant, a C{sub 8}-C{sub 15} alkyl capped oligomer of a hexanoic acid that is electrochemically inert at 2.5--4.5 volts.

Block, J.; Fan, X.

1998-10-27T23:59:59.000Z

136

CX-010909: Categorical Exclusion Determination  

Broader source: Energy.gov [DOE]

Bench-Scale Development of a Non-Aqueous Solvent (NAS) Carbon Dioxide (CO2) Capture Process for Coal-Fired Power Plants CX(s) Applied: A9, A11 Date: 09/25/2013 Location(s): New Jersey Offices(s): National Energy Technology Laboratory

137

motion of crystalline domains in an otherwise rigid solid-state Received 7 January; accepted 10 June 2002; doi:10.1038/nature00901.  

E-Print Network [OSTI]

non- aqueous cells. J. Power Sources 14, 153­166 (1985). 3. Ohzuku, T. & Hirai, T. An electrochromic., Morzilli, S. & Scrosati, B. The electrochromic characteristics of titanium oxide thin film electrodes. Solid State Ionics 20, 197­202 (1986). 5. Cantao, M. P., Cisneros, J. I. & Torresi, R. M. Electrochromic

Suslick, Kenneth S.

138

Development of Chemical Model to Predict the Interactions between Supercritical CO2and Fluid, and Rocks in EGS Reservoirs  

Broader source: Energy.gov [DOE]

This project will develop a chemical model, based on existing models and databases, that is capable of simulating chemical reactions between supercritical (SC) CO2 and Enhanced Geothermal System (EGS) reservoir rocks of various compositions in aqueous, non-aqueous and 2-phase environments.

139

Carbonation Mechanism of Reservoir Rock by Supercritical Carbon Dioxide  

Broader source: Energy.gov [DOE]

Project Objectives: Elucidate comprehensively the carbonation reaction mechanisms between supercritical carbon dioxide (scCO2) and reservoir rocks consisting of different mineralogical compositions in aqueous and non-aqueous environments at temperatures of up to 250ºC, and to develop chemical modeling of CO2-reservior rock interactions.

140

Author's personal copy Physica D 239 (2010) 18551866  

E-Print Network [OSTI]

, such as those occurring during remediation of contaminated soils using brine solutions and during the geological for containing and/or mobilizing dense non-aqueous phase liquids (DNAPLs) in contaminated subsurface systems through the introduction of brine solutions. The success of such techniques relies on the accurate

McLaughlin, Richard M.

Note: This page contains sample records for the topic "millivolt napl non-aqueous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Molecular dynamics (MD) calculation of the real zeta potential of neutral surfaces  

E-Print Network [OSTI]

Molecular dynamics (MD) simulations of the zeta potential are so poor that it has become common to term their predictions "apparent". Here we demonstrate how MD methods can predict zeta potentials accurate enough they can be termed "real". The critical new aspects of our method are: (1) integrating the net average charge in surface-parallel layers from the midpoint of the fluid layer (where the electrostatic potential is zero) to and then into two solid caps, (2) determining the position of slipping plane with separate Couette flow models, and (3) calculating the charge distribution and electrostatic potential under static conditions. The solids are charge neutral surfaces composed of atoms with zero charge or charge balanced monovalent or divalent ions. The zeta potentials calculated are within a few millivolts of measured values, and the measured values fall within the simulation error bars. The zeta potentials calculated with the Helmholtz and Smoluchowski equation following current practice are 10's of mi...

Liu, Hongyi

2013-01-01T23:59:59.000Z

142

Fundamental measure theory for the electric double layer: applications to blue-energy harvesting and water desalination  

E-Print Network [OSTI]

Capacitive mixing (CAPMIX) and capacitive deionization (CDI) are promising candidates for harvesting clean, renewable energy and for the energy efficient production of potable water, respectively. Both CAPMIX and CDI involve water-immersed porous carbon electrodes at voltages of the order of hundreds of millivolts, such that counter-ionic packing is important. We propose a density functional theory (DFT) to model the electric double layer which forms near the surfaces of these porous materials. The White-Bear mark II fundamental measure theory (FMT) functional is combined with a mean-field Coulombic and a MSA-type correction to describe the interplay between dense packing and electrostatics, in good agreement with MD simulations. Compared to less elaborate mean-field models our DFT calculations reveal a higher work output for blue-energy cycles and a higher energy demand for desalination cycles.

Andreas Härtel; Mathijs Janssen; Sela Samin; René van Roij

2014-11-20T23:59:59.000Z

143

Electrogenerative oxidation of lower alcohols to useful products  

DOE Patents [OSTI]

In the disclosed electrogenerative process for converting alcohols such as ethanol to aldehydes such as acetaldehyde, the alcohol starting material is an aqueous solution containing more than the azeotropic amount of water. Good first-pass conversions (<40% and more typically <50%) are obtained at operating cell voltages in the range of about 80 to about 350 millivolts at ordinary temperatures and pressures by using very high flow rates of alcohol to the exposed anode surface (i.e. the "gas" side of an anode whose other surface is in contact with the electrolyte). High molar flow rates of vaporized aqueous alcohol also help to keep formation of undesired byproducts at a low level.

Meshbesher, Thomas M. (4507 Weldin Rd., Wilmington, DE 19803)

1987-01-01T23:59:59.000Z

144

Landscape of superconducting membranes  

E-Print Network [OSTI]

The AdS/CFT correspondence may connect the landscape of string vacua and the `atomic landscape' of condensed matter physics. We study the stability of a landscape of IR fixed points of N=2 large N gauge theories in 2+1 dimensions, dual to Sasaki-Einstein compactifications of M theory, towards a superconducting state. By exhibiting instabilities of charged black holes in these compactifications, we show that many of these theories have charged operators that condense when the theory is placed at a finite chemical potential. We compute a statistical distribution of critical superconducting temperatures for a subset of these theories. With a chemical potential of one milliVolt, we find critical temperatures ranging between 0.24 and 165 degrees Kelvin.

Frederik Denef; Sean A. Hartnoll

2009-03-20T23:59:59.000Z

145

An investigation of pneumatic control on immiscible contaminant migration in confined aquifers  

E-Print Network [OSTI]

? dimensional (vertical and lateral) finite ? element contaminant groundwater simulator to investigate the migration of NAPL's in the unsaturated zone. The physical conception of this model is based upon the salt/fresh water interface problem occurring..., or the use of water-flooding in secondary recovery operations. " Faust[1985] and Faust et uk[1989] attested to the validity of known and accepted petroleum engineering mathematical models used to describe multiphase flow through porous media. Osborne...

Watts, John David

1991-01-01T23:59:59.000Z

146

Screening commercial surfactants suitable for remediating DNAPL source zones by solubilization  

SciTech Connect (OSTI)

Surfactants can enhance the removal of nonaqueous-phase-liquids (NAPLs) from porous media by two very different mechanisms: (1) increased solubilization that occurs in the presence of surfactant micelles and (2) mobilization of NAPL ganglia held by capillary forces. Solubilization technologies pose less risk of uncontrolled NAPL migration and are less complex to design. Since dense-NAPLs, like PCE, pose the greatest risk of migration, there is a need for more information on surfactants that are capable of solubilizing DNAPLs and removing them as water continuous, low viscosity, microemulsion without mobilization. Forty-two commercial, water-soluble surfactants were screened for PCE solubilization in batch experiments and one nonionic (Brij 97) and one anionic (SDS) surfactant were further evaluated in column experiments. Of the 42 surfactants that were screened, 12 nonionic surfactants with HLB values between 10.8 and 13.2 solubilized the most PCE. However, as PCE solubilization exceeded {approximately}40,000 mg/L, macroemulsion stability became a problem. Addition of IPA did not affect the amount of PCE solubilized but decreased macroemulsion stability, resulting in more rapid formation of Winsor Type 1 microemulsions. The most efficient surfactants were Brij 97 and Ritoleth 10, both being ethoxylated oleyl alcohol ethers, At 3 wt % IPA and surfactant, these surfactants solubilized >70,000 mg PCE/L. In column experiments, Brij 97/IPA removed >92% of the residual PCE in 11 pore volumes without mobilizing the PCE. An SDS/pentanol/IPA system removed 98% in {approximately}9.5 pore volumes, but about 30% of the PCE was mobilized. Removal of PCE was rate-limited with Brij 97/IPA, suggesting that flow interruption may be an effective remediation strategy.

Zhou, M.; Rhue, R.D.

2000-05-15T23:59:59.000Z

147

Il corso di Fisica teorica di Ettore Majorana: il ritrovamento del Documento Moreno  

E-Print Network [OSTI]

We analyze in some detail the course of Theoretical Physics held by Ettore Majorana at the University of Naples in 1938, just before his mysterious disappearance. In particular we give an account of the recently retrieved "Moreno Paper", where the lecture notes are reported. Six of these lectures are not present in the collection of the original manuscripts deposited at the Domus Galilaeana in Pisa, consisting of only ten lectures.

S. Esposito

2005-03-10T23:59:59.000Z

148

Available at www.sciencedirect.com journal homepage: www.elsevier.com/locate/watres  

E-Print Network [OSTI]

-grade ethanol transport and impacts to groundwater in a pilot-scale aquifer tank Natalie L. Ca´piroa,�, Brent P September 2006 Available online 28 November 2006 Keywords: Fuel-grade ethanol Capillary-zone Hydrocarbons Groundwater NAPL Vadose-zone Capillary-fringe Ethanol A B S T R A C T Fuel-grade ethanol (76 L of E95, 95% v

Alvarez, Pedro J.

149

Method of remediation of contaminants in porous media through minimization of bouyancy effects  

DOE Patents [OSTI]

A method for controlling vertical migration of contaminants in an aquifer includes introduction of a solubilizing solution having a surfactant and an alcohol or other light co-solvent. The surfactant is selected to solubilize the contaminant. The alcohol or other solvent is selected to provide the microemulsion with a substantially neutral buoyancy with respect to groundwater. The neutral buoyancy of the microemulsion prevents the normal downward movement which is typical of the solubilized dense non-aqueous phase liquid in surfactant-enhanced aquifer remediation. Thus, the risk that any significant amount of the solubilized dense non-aqueous contaminants will migrate vertically can be controlled. The relative tendency for vertical migration may also be reduced by increasing the injection rate or injected fluid viscosity (by adding polymer), or by reducing the well spacing.

Shook, G. Michael (Rigby, ID); Pope, Gary A. (Austin, TX)

1999-01-01T23:59:59.000Z

150

Proceedings of the international workshop on measurement and computation of turbulent nonpremixed flames  

SciTech Connect (OSTI)

This report documents the proceedings of the International Workshop on Measurement and Computation of Turbulent Nonpremixed Flames, held in Naples, Italy on July 26--27, 1996. Contents include materials that were distributed to participants at the beginning of the workshop, as well as a Summary of Workshop Accomplishments that was generated at the close to this Naples meeting. The Naples workshop involved sixty-one people from eleven countries. The primary objectives were: (1) to select a set of well-documented and relatively simple flames that would be appropriate for collaborative comparisons of model predictions; and (2) to specify common submodels to be used in these predictions, such that models for the coupling of turbulence and chemistry might be isolated and better understood. Studies involve hydrogen and natural gas fuels. These proceedings are also published on the Web and those interested in the ongoing process of data selection and model comparison should consult the workshop page for the most recent and complete information on these collaborative research efforts. The URL is: http://www/ca.sandia/gov/tdf/Workshop.html.

Barlow, R.S. [ed.

1996-10-01T23:59:59.000Z

151

Influence of Wetting and Mass Transfer Properties of Organic Chemical Mixtures in Vadose Zone Materials on Groundwater Contamination by Nonaqueous Phase Liquids  

SciTech Connect (OSTI)

Previous studies have found that organic acids, organic bases, and detergent-like chemicals change surface wettability. The wastewater and NAPL mixtures discharged at the Hanford site contain such chemicals, and their proportions likely change over time due to reaction-facilitated aging. The specific objectives of this work were to (1) determine the effect of organic chemical mixtures on surface wettability, (2) determine the effect of organic chemical mixtures on CCl4 volatilization rates from NAPL, and (3) accurately determine the migration, entrapment, and volatilization of organic chemical mixtures. Five tasks were proposed to achieve the project objectives. These are to (1) prepare representative batches of fresh and aged NAPL-wastewater mixtures, (2) to measure interfacial tension, contact angle, and capillary pressure-saturation profiles for the same mixtures, (3) to measure interphase mass transfer rates for the same mixtures using micromodels, (4) to measure multiphase flow and interphase mass transfer in large flow cell experiments, all using the same mixtures, and (5) to modify the multiphase flow simulator STOMP in order to account for updated P-S and interphase mass transfer relationships, and to simulate the impact of CCl4 in the vadose zone on groundwater contamination. Results and findings from these tasks and summarized in the attached final report.

Charles J Werth; Albert J Valocchi, Hongkyu Yoon

2011-05-21T23:59:59.000Z

152

Simplified one-pot synthesis of [.sup.18F]SFB for radiolabeling  

DOE Patents [OSTI]

A non-aqueous single pot synthesis of [.sup.18F]SFB is set forth. The [.sup.18F]SFB produced with this method is then used, for example, to label a peptide or an engineered antibody fragment (diabody) targeting human epidermal growth factor receptor 2 (HER2) as representative examples of labeled compounds for use as an injectable composition to locate abnormal tissue, specifically tumors within an animal or human using a PET scan.

Olma, Sebastian; Shen, Clifton Kwang-Fu

2013-07-16T23:59:59.000Z

153

JOURNAL DE PHYSIQUE Colioque C3, supplkment au n06, Tome 44,juin 1983 page C3-579  

E-Print Network [OSTI]

. This synthesis was also performed in a non aqueous medium pyrrole, N ( ~ t ) ~ BF4 in CH3CN, by DIAZ et a1J/mole. The electrochemical synthesis of polypyrrole films has been performed by DALL'OLIO et a1 in 1968 (1). The medium used was a solution of pyrrole and sulphuric acid in water. The polypyrrole film obtained was in the oxidation state

Paris-Sud XI, Université de

154

Pentavalent Uranium Chemistry - Synthetic Pursuit Of A Rare Oxidation State  

SciTech Connect (OSTI)

This feature article presents a comprehensive overview of pentavalent uranium systems in non-aqueous solution with a focus on the various synthetic avenues employed to access this unusual and very important oxidation state. Selected characterization data and theoretical aspects are also included. The purpose is to provide a perspective on this rapidly evolving field and identify new possibilities for future developments in pentavalent uranium chemistry.

Graves, Christopher R [Los Alamos National Laboratory; Kiplinger, Jaqueline L [Los Alamos National Laboratory

2009-01-01T23:59:59.000Z

155

Preface XIII 1 Introduction 1  

E-Print Network [OSTI]

and Suspensions 93 3.6.5 Surfactants and Wetting 94 3.6.6 Surfactants and Detergency 94 3.7 Other Lyophilic and Isoelectric Point 113 4.3.3 Electrodialysis 114 4.4 Electrostatic Properties in Non-aqueous Media 115 5 Colloid Stability 117 5.1 Electrostatic and Dispersion Forces 119 5.1.1 Repulsive Forces 120 5

Schramm, Laurier L.

156

Membrane reference electrode  

DOE Patents [OSTI]

A reference electrode utilizes a small thin, flat membrane of a highly conductive glass placed on a small diameter insulator tube having a reference material inside in contact with an internal voltage lead. When the sensor is placed in a non-aqueous ionic electrolytic solution, the concentration difference across the glass membrane generates a low voltage signal in precise relationship to the concentration of the species to be measured, with high spatial resolution. 2 figs.

Redey, L.; Bloom, I.D.

1988-01-21T23:59:59.000Z

157

Aza crown ether compounds as anion receptors  

DOE Patents [OSTI]

A family of aza-ether based compounds including linear, multi-branched and aza-crown ethers is provided. When added to non-aqueous battery electrolytes, the new family of aza-ether based compounds acts as neutral receptors to complex the anion moiety of the electrolyte salt thereby increasing the conductivity and the transference number of LI{sup +} ion in alkali metal batteries. 3 figs.

Lee, H.S.; Yang, X.O.; McBreen, J.

1998-08-04T23:59:59.000Z

158

Aza compounds as anion receptors  

DOE Patents [OSTI]

A family of aza-ether based compounds including linear, multi-branched and aza-crown ethers is provided. When added to non-aqueous battery electrolytes, the family of aza-ether based compounds acts as neutral receptors to complex the anion moiety of the electrolyte salt thereby increasing the conductivity and the transference number of Li{sup +} ion in alkali metal batteries. 3 figs.

Lee, H.S.; Yang, X.Q.; McBreen, J.

1998-01-06T23:59:59.000Z

159

Kuwaiti oil sector shows more signs of recovery  

SciTech Connect (OSTI)

This paper reports that Kuwait's oil sector continues to show signs of recovery from the Persian Gulf war. On Mar. 23 Kuwait Petroleum Co. (KPC) loaded the country's first shipment of liquefied petroleum gas for export since the Iraqi invasion in August 1990. In addition, the first shipment of Kuwaiti crude recovered from giant oil lakes formed by hundreds of wild wells sabotaged in the war was to arrive by tanker in Naples, Italy, late last month. The tanker is carrying 210,000 bbl of crude. However, the project to clean up the lakes and recover more oil, undertaken by Bechtel Corp. with Kuwait Oil Co. (KOC), has reached a stand still.

Not Available

1992-04-06T23:59:59.000Z

160

Electrolytic orthoborate salts for lithium batteries  

DOE Patents [OSTI]

Orthoborate salts suitable for use as electrolytes in lithium batteries and methods for making the electrolyte salts are provided. The electrolytic salts have one of the formulae (I). In this formula anionic orthoborate groups are capped with two bidentate chelating groups, Y1 and Y2. Certain preferred chelating groups are dibasic acid residues, most preferably oxalyl, malonyl and succinyl, disulfonic acid residues, sulfoacetic acid residues and halo-substituted alkylenes. The salts are soluble in non-aqueous solvents and polymeric gels and are useful components of lithium batteries in electrochemical devices.

Angell, Charles Austen [Mesa, AZ; Xu, Wu [Tempe, AZ

2009-05-05T23:59:59.000Z

Note: This page contains sample records for the topic "millivolt napl non-aqueous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Electrolytic orthoborate salts for lithium batteries  

DOE Patents [OSTI]

Orthoborate salts suitable for use as electrolytes in lithium batteries and methods for making the electrolyte salts are provided. The electrolytic salts have one of the formulae (I). In this formula anionic orthoborate groups are capped with two bidentate chelating groups, Y1 and Y2. Certain preferred chelating groups are dibasic acid residues, most preferably oxalyl, malonyl and succinyl, disulfonic acid residues, sulfoacetic acid residues and halo-substituted alkylenes. The salts are soluble in non-aqueous solvents and polymeric gels and are useful components of lithium batteries in electrochemical devices.

Angell, Charles Austen (Mesa, AZ); Xu, Wu (Tempe, AZ)

2008-01-01T23:59:59.000Z

162

Anodes for rechargeable lithium batteries  

DOE Patents [OSTI]

A negative electrode (12) for a non-aqueous electrochemical cell (10) with an intermetallic host structure containing two or more elements selected from the metal elements and silicon, capable of accommodating lithium within its crystallographic host structure such that when the host structure is lithiated it transforms to a lithiated zinc-blende-type structure. Both active elements (alloying with lithium) and inactive elements (non-alloying with lithium) are disclosed. Electrochemical cells and batteries as well as methods of making the negative electrode are disclosed.

Thackeray, Michael M. (Naperville, IL); Kepler, Keith D. (Mountain View, CA); Vaughey, John T. (Elmhurst, IL)

2003-01-01T23:59:59.000Z

163

Long life lithium batteries with stabilized electrodes  

DOE Patents [OSTI]

The present invention relates to non-aqueous electrolytes having electrode stabilizing additives, stabilized electrodes, and electrochemical devices containing the same. Thus the present invention provides electrolytes containing an alkali metal salt, a polar aprotic solvent, and an electrode stabilizing additive. In some embodiments the additives include a substituted or unsubstituted cyclic or spirocyclic hydrocarbon containing at least one oxygen atom and at least one alkenyl or alkynyl group. When used in electrochemical devices with, e.g., lithium manganese oxide spinel electrodes or olivine or carbon-coated olivine electrodes, the new electrolytes provide batteries with improved calendar and cycle life.

Amine, Khalil (Downers Grove, IL); Liu, Jun (Naperville, IL); Vissers, Donald R. (Naperville, IL); Lu, Wenquan (Darien, IL)

2009-03-24T23:59:59.000Z

164

High frequency titration of amines in nonaqueous solutions  

E-Print Network [OSTI]

results for the aliphatkc amines and nitrogen hetero- cyclic compounds tested and fair results for some ef the aromatic compounds. An attempt to determine the individual amounts of two bases with one titration was unsuccessful. TABLE OF C05TE5TS I5... may be extended to include the titration of amines in nonaqueous solutions. The quantitative determination of amines in non- aqueous solutions is a field in which only a relatively small amount of work has been done, the major portion of which has...

Witmer, William Byron

1958-01-01T23:59:59.000Z

165

An investigation of the transfer of alkali metal chlorides from dimethyl sulfoxide to water  

E-Print Network [OSTI]

-to-back' with water as the solvent in one cell and a non- aqueous solvent in the other. The two cells used in this investigation were each composed of silver-silver chloride electrodes in the same solution with dropping alkali metal amalgam electrodes. The solute.... The dropping amalgam electrodes are written only once since they were connected by a common amalgam reservoir. When the external circuit between the two silver-silver chloride electrodes was closed a current flowed and the net result oi the electrode...

Williams, Roger

1966-01-01T23:59:59.000Z

166

Monte Carlo Electromagnetic Cross Section Production Method for Low Energy Charged Particle Transport Through Single Molecules  

E-Print Network [OSTI]

: Nuclear Engineering Copyright 2013 Jonathan Robert Madsen ii ABSTRACT The present state of modeling radio-induced effects at the cellular level neglects to account for the microscopic inhomogeneity of the nucleus from the non-aqueous contents...: Dr. John Ford and Dr. Lisa Perez for all their assistance. I would also like to thank Dr. S?bastian Incerti of the Geant4-DNA collaboration, who proposed my membership to the Geant4 collaboration as a member of the Geant4- DNA project...

Madsen, Jonathan R

2013-08-13T23:59:59.000Z

167

Method for digesting a nitro-bearing explosive compound  

DOE Patents [OSTI]

The present invention is a process wherein superoxide radicals from superoxide salt are used to break down the explosive compounds. The process has an excellent reaction rate for degrading explosives, and operates at ambient temperature and atmospheric pressure in aqueous or non-aqueous conditions. Because the superoxide molecules are small, much smaller than an enzyme molecule for example, they can penetrate the microstructure of plastic explosives faster. The superoxide salt generates reactive hydroxyl radicals, which can destroy other organic contaminants, if necessary, along with digesting the explosive nitro-bearing compound.

Shah, Manish M. (Richland, WA)

2000-01-01T23:59:59.000Z

168

Chemical overcharge protection of lithium and lithium-ion secondary batteries  

DOE Patents [OSTI]

This invention features the use of redox reagents, dissolved in non-aqueous electrolytes, to provide overcharge protection for cells having lithium metal or lithium-ion negative electrodes (anodes). In particular, the invention features the use of a class of compounds consisting of thianthrene and its derivatives as redox shuttle reagents to provide overcharge protection. Specific examples of this invention are thianthrene and 2,7-diacetyl thianthrene. One example of a rechargeable battery in which 2,7-diacetyl thianthrene is used has carbon negative electrode (anode) and spinet LiMn{sub 2}O{sub 4} positive electrode (cathode). 8 figs.

Abraham, K.M.; Rohan, J.F.; Foo, C.C.; Pasquariello, D.M.

1999-01-12T23:59:59.000Z

169

Chemical overcharge protection of lithium and lithium-ion secondary batteries  

DOE Patents [OSTI]

This invention features the use of redox reagents, dissolved in non-aqueous electrolytes, to provide overcharge protection for cells having lithium metal or lithium-ion negative electrodes (anodes). In particular, the invention features the use of a class of compounds consisting of thianthrene and its derivatives as redox shuttle reagents to provide overcharge protection. Specific examples of this invention are thianthrene and 2,7-diacetyl thianthrene. One example of a rechargeable battery in which 2,7-diacetyl thianthrene is used has carbon negative electrode (anode) and spinet LiMn.sub.2 O.sub.4 positive electrode (cathode).

Abraham, Kuzhikalail M. (Needham, MA); Rohan, James F. (Cork City, IE); Foo, Conrad C. (Dedham, MA); Pasquariello, David M. (Pawtucket, RI)

1999-01-01T23:59:59.000Z

170

Influence of Controlled Viscous Dissipation on the Propagation of Strongly Nonlinear Waves in Stainless Steel Based Phononic Crystals  

E-Print Network [OSTI]

Strongly nonlinear phononic crystals were assembled from stainless steel spheres. Single solitary waves and splitting of an initial pulse into a train of solitary waves were investigated in different viscous media using motor oil and non-aqueous glycerol to introduce a controlled viscous dissipation. Experimental results indicate that the presence of a viscous fluid dramatically altered the splitting of the initial pulse into a train of solitary waves. Numerical simulations qualitatively describe the observed phenomena only when a dissipative term based on the relative velocity between particles is introduced.

E. B. Herbold; V. F. Nesterenko; C. Daraio

2005-12-22T23:59:59.000Z

171

Lithium metal oxide electrodes for lithium cells and batteries  

DOE Patents [OSTI]

A lithium metal oxide positive electrode for a non-aqueous lithium cell is disclosed. The cell is prepared in its initial discharged state and has a general formula xLiMO.sub.2.(1-x)Li.sub.2 M'O.sub.3 in which 0

Thackeray, Michael M. (Naperville, IL); Johnson, Christopher S. (Naperville, IL); Amine, Khalil (Downers Grove, IL); Kim, Jaekook (Naperville, IL)

2004-01-13T23:59:59.000Z

172

Semiconductor electrochemistry coal pyrite. Quarterly technical progress report, October--December 1994  

SciTech Connect (OSTI)

Pyrite dissolution in acidic solution was found to involve both electrochemical oxidation and chemical decomposition. The mechanism of chemical decomposition of pyrite in acidic solution may involve surface complexation of hydrogen ions. The anodic current of pyrite was relatively small in non-aqueous solution (acetonitrile) compared with that in aqueous solution. The implication is that the direct reaction of holes with S{sub 2}{sup 2{minus}} in the pyrite lattice was not significant and that the dissolution of pyrite required the presence of water. The anodic dissolution product was elemental sulfur which was detected by X-ray diffraction.

Osseo-Asare, K.; Wei, D.

1995-01-01T23:59:59.000Z

173

Long-term serviceability of elastomers in modern engine coolants  

SciTech Connect (OSTI)

The aging of elastomers in engine coolants after extended periods of service can be both a physical process (stress/strain relaxation) and/or a chemical change. Engine coolants are essentially aqueous and non-aqueous electrolytes coupled with inorganic inhibitor systems, as well as new organic acid systems. The long-term effects of this environment are reviewed. Chemical and functional tests are utilized to model these aging processes. This review will offer a better understanding of the long-term suitability of typical candidate elastomers.

Bussem, H.; Farinella, A.C.; Hertz, D.L. Jr. [Seals Eastern Inc., Red Bank, NJ (United States)

1999-08-01T23:59:59.000Z

174

Fundamental measure theory for the electric double layer: implications for blue-energy harvesting and water desalination  

E-Print Network [OSTI]

Capacitive mixing (CAPMIX) and capacitive deionization (CDI) are promising candidates for harvesting clean, renewable energy and for the energy efficient production of potable water, respectively. Both CAPMIX and CDI involve water-immersed porous carbon (supercapacitors) electrodes at voltages of the order of hundreds of millivolts, such that counter-ionic packing is important for the electric double layer (EDL) which forms near the surface of these porous materials. Thus, we propose a density functional theory (DFT) to model the EDL, where the White-Bear mark II fundamental measure theory functional is combined with a mean-field Coulombic and a mean spherical approximation-type correction to describe the interplay between dense packing and electrostatics, in good agreement with molecular dynamics simulations. We discuss the concentration-dependent potential rise due to changes in the chemical potential in capacitors in the context of an over-ideal theoretical description and its impact on energy harvesting and water desalination. Compared to less elaborate mean-field models our DFT calculations reveal a higher work output for blue-energy cycles and a higher energy demand for desalination cycles.

Andreas Härtel; Mathijs Janssen; Sela Samin; René van Roij

2015-03-06T23:59:59.000Z

175

Chemical oxidation of volatile and semi-volatile organic compounds in soil  

SciTech Connect (OSTI)

Subsurface contamination with fuel hydrocarbons or chlorinated hydrocarbons is prevalent throughout the Department of Energy (DOE) complex and in many sites managed by the Environmental Protection Agency (EPA) Superfund program. The most commonly reported chlorinated hydrocarbons (occurring > 50% of DOE contaminated sites) were trichloroethylene (TCE), 1, 1, 1,-trichloroethane (TCA), and tetrachloroethylene (PCE) with concentrations in the range of 0.2 {mu}g/kg to 12,000 mg/kg. The fuel hydrocarbons most frequently reported as being present at DOE sites include aromatic compounds and polyaromatic compounds such as phenanthrene, pyrene, and naphthalene. The primary sources of these semi-volatile organic compounds (SVOCs) are coal waste from coal fired electric power plants used at many of these facilities in the past and gasoline spills and leaks. Dense non-aqueous phase liquids (DNAPLs) can migrate within the subsurface for long periods of time along a variety of pathways including fractures, macropores, and micropores. Diffusion of contaminants in the non-aqueous, aqueous, and vapor phase can occur from the fractures and macropores into the matrix of fine-textured media. As a result of these contamination processes, removal of contaminants from the subsurface and the delivery of treatment agents into and throughout contaminated regions are often hindered, making rapid and extensive remediation difficult.

Gates, D.D.; Siegrist, R.L.; Cline, S.R.

1995-06-01T23:59:59.000Z

176

Crown Ethers in Nonaqueous Electrolytes for Lithium/Air Batteries  

SciTech Connect (OSTI)

The effects of three crown ethers, 12-crown-4, 15-crown-5, and 18-crown-6, as additives and co-solvents in non-aqueous electrolytes on the cell performance of primary Li/air batteries operated in a dry air environment were investigated. Crown ethers have large effects on the discharge performance of non-aqueous electrolytes in Li/air batteries. A small amount (normally less than 10% by weight or volume in electrolytes) of 12-Crown-4 and 15-crown-5 reduces the battery performance and a minimum discharge capacity appears at the crown ether content of ca. 5% in the electrolytes. However, when the content increases to about 15%, both crown ethers improve the capacity of Li/air cells by about 28% and 16%, respectively. 15-Crown-5 based electrolytes even show a maximum discharge capacity in the crown ether content range from 10% to 15%. On the other hand, the increase of 18-crown-6 amount in the electrolytes continuously lowers of the cell performance. The different battery performances of these three crown ethers in electrolytes are explained by the combined effects from the electrolytes’ contact angle, oxygen solubility, viscosity, ionic conductivity, and the stability of complexes formed between crown ether molecules and lithium ions.

Xu, Wu; Xiao, Jie; Wang, Deyu; Zhang, Jian; Zhang, Jiguang

2010-02-04T23:59:59.000Z

177

International Nuclear Energy Research Initiative Development of Computational Models for Pyrochemical Electrorefiners of Nuclear Waste Transmutation Systems  

SciTech Connect (OSTI)

In support of closing the nuclear fuel cycle using non-aqueous separations technology, this project aims to develop computational models of electrorefiners based on fundamental chemical and physical processes. Spent driver fuel from Experimental Breeder Reactor-II (EBR-II) is currently being electrorefined in the Fuel Conditioning Facility (FCF) at Idaho National Laboratory (INL). And Korea Atomic Energy Research Institute (KAERI) is developing electrorefining technology for future application to spent fuel treatment and management in the Republic of Korea (ROK). Electrorefining is a critical component of pyroprocessing, a non-aqueous chemical process which separates spent fuel into four streams: (1) uranium metal, (2) U/TRU metal, (3) metallic high-level waste containing cladding hulls and noble metal fission products, and (4) ceramic high-level waste containing sodium and active metal fission products. Having rigorous yet flexible electrorefiner models will facilitate process optimization and assist in trouble-shooting as necessary. To attain such models, INL/UI has focused on approaches to develop a computationally-light and portable two-dimensional (2D) model, while KAERI/SNU has investigated approaches to develop a computationally intensive three-dimensional (3D) model for detailed and fine-tuned simulation.

M.F. Simpson; K.-R. Kim

2010-12-01T23:59:59.000Z

178

Preparation of hydrophobic organic aeorgels  

DOE Patents [OSTI]

Synthetic methods for the preparation of hydrophobic organics aerogels. One method involves the sol-gel polymerization of 1,3-dimethoxybenzene or 1,3,5-trimethoxybenzene with formaldehyde in non-aqueous solvents. Using a procedure analogous to the preparation of resorcinol-formaldehyde (RF) aerogels, this approach generates wet gels that can be dried using either supercritical solvent extraction to generate the new organic aerogels or air dried to produce an xerogel. Other methods involve the sol-gel polymerization of 1,3,5 trihydroxy benzene (phloroglucinol) or 1,3 dihydroxy benzene (resorcinol) and various aldehydes in non-aqueous solvents. These methods use a procedure analogous to the one-step base and two-step base/acid catalyzed polycondensation of phloroglucinol and formaldehyde, but the base catalyst used is triethylamine. These methods can be applied to a variety of other sol-gel precursors and solvent systems. These hydrophobic organics aerogels have numerous application potentials in the field of material absorbers and water-proof insulation.

Baumann, Theodore F. (Tracy, CA); Satcher, Jr., Joe H. (Patterson, CA); Gash, Alexander E. (Livermore, CA)

2007-11-06T23:59:59.000Z

179

Preparation of hydrophobic organic aeorgels  

DOE Patents [OSTI]

Synthetic methods for the preparation of hydrophobic organics aerogels. One method involves the sol-gel polymerization of 1,3-dimethoxybenzene or 1,3,5-trimethoxybenzene with formaldehyde in non-aqueous solvents. Using a procedure analogous to the preparation of resorcinol-formaldehyde (RF) aerogels, this approach generates wet gels that can be dried using either supercritical solvent extraction to generate the new organic aerogels or air dried to produce an xerogel. Other methods involve the sol-gel polymerization of 1,3,5 trihydroxy benzene (phloroglucinol) or 1,3 dihydroxy benzene (resorcinol) and various aldehydes in non-aqueous solvents. These methods use a procedure analogous to the one-step base and two-step base/acid catalyzed polycondensation of phloroglucinol and formaldehyde, but the base catalyst used is triethylamine. These methods can be applied to a variety of other sol-gel precursors and solvent systems. These hydrophobic organics aerogels have numerous application potentials in the field of material absorbers and water-proof insulation.

Baumann, Theodore F.; Satcher Jr., Joe H.; Gash, Alexander E.

2004-10-19T23:59:59.000Z

180

Process to produce lithium-polymer batteries  

DOE Patents [OSTI]

A polymer bonded sheet product is described suitable for use as an electrode in a non-aqueous battery system. A porous electrode sheet is impregnated with a solid polymer electrolyte, so as to diffuse into the pores of the electrode. The composite is allowed to cool, and the electrolyte is entrapped in the porous electrode. The sheet products composed have the solid polymer electrolyte composition diffused into the active electrode material by melt-application of the solid polymer electrolyte composition into the porous electrode material sheet. The solid polymer electrolyte is maintained at a temperature that allows for rapid diffusion into the pores of the electrode. The composite electrolyte-electrode sheets are formed on current collectors and can be coated with solid polymer electrolyte prior to battery assembly. The interface between the solid polymer electrolyte composite electrodes and the solid polymer electrolyte coating has low resistance. 1 fig.

MacFadden, K.O.

1998-06-30T23:59:59.000Z

Note: This page contains sample records for the topic "millivolt napl non-aqueous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Lithium metal oxide electrodes for lithium cells and batteries  

DOE Patents [OSTI]

A lithium metal oxide positive electrode for a non-aqueous lithium cell is disclosed. The cell is prepared in its initial discharged state and has a general formula xLiMO2.(1-x)Li2M'O3 in which 0

Thackeray, Michael M.; Johnson, Christopher S.; Amine, Khalil; Kim, Jaekook

2006-11-14T23:59:59.000Z

182

Electrode for a lithium cell  

DOE Patents [OSTI]

This invention relates to a positive electrode for an electrochemical cell or battery, and to an electrochemical cell or battery; the invention relates more specifically to a positive electrode for a non-aqueous lithium cell or battery when the electrode is used therein. The positive electrode includes a composite metal oxide containing AgV.sub.3O.sub.8 as one component and one or more other components consisting of LiV.sub.3O.sub.8, Ag.sub.2V.sub.4O.sub.11, MnO.sub.2, CF.sub.x, AgF or Ag.sub.2O to increase the energy density of the cell, optionally in the presence of silver powder and/or silver foil to assist in current collection at the electrode and to improve the power capability of the cell or battery.

Thackeray, Michael M. (Naperville, IL); Vaughey, John T. (Elmhurst, IL); Dees, Dennis W. (Downers Grove, IL)

2008-10-14T23:59:59.000Z

183

Redox shuttles for overcharge protection of lithium batteries  

DOE Patents [OSTI]

The present invention is generally related to electrolytes containing novel redox shuttles for overcharge protection of lithium-ion batteries. The redox shuttles are capable of thousands hours of overcharge tolerance and have a redox potential at about 3-5.5 V vs. Li and particularly about 4.4-4.8 V vs. Li. Accordingly, in one aspect the invention provides electrolytes comprising an alkali metal salt; a polar aprotic solvent; and a redox shuttle additive that is an aromatic compound having at least one aromatic ring with four or more electronegative substituents, two or more oxygen atoms bonded to the aromatic ring, and no hydrogen atoms bonded to the aromatic ring; and wherein the electrolyte solution is substantially non-aqueous. Further there are provided electrochemical devices employing the electrolyte and methods of making the electrolyte.

Amine, Khalil (Downers Grove, IL); Chen, Zonghai (Downers Grove, IL); Wang, Qingzheng (San Jose, CA)

2010-12-14T23:59:59.000Z

184

Lithium-ion batteries with intrinsic pulse overcharge protection  

DOE Patents [OSTI]

The present invention relates in general to the field of lithium rechargeable batteries, and more particularly relates to the positive electrode design of lithium-ion batteries with improved high-rate pulse overcharge protection. Thus the present invention provides electrochemical devices containing a cathode comprising at least one primary positive material and at least one secondary positive material; an anode; and a non-aqueous electrolyte comprising a redox shuttle additive; wherein the redox potential of the redox shuttle additive is greater than the redox potential of the primary positive material; the redox potential of the redox shuttle additive is lower than the redox potential of the secondary positive material; and the redox shuttle additive is stable at least up to the redox potential of the secondary positive material.

Chen, Zonghai; Amine, Khalil

2013-02-05T23:59:59.000Z

185

Protective coating on positive lithium-metal-oxide electrodes for lithium batteries  

DOE Patents [OSTI]

A positive electrode for a non-aqueous lithium cell comprising a LiMn2-xMxO4 spinel structure in which M is one or more metal cations with an atomic number less than 52, such that the average oxidation state of the manganese ions is equal to or greater than 3.5, and in which 0.ltoreq.x.ltoreq.0.15, having one or more lithium spine oxide LiM'2O4 or lithiated spinel oxide Li1+yM'2O4 compounds on the surface thereof in which M' are cobalt cations and in which 0.ltoreq.y.ltoreq.1.

Johnson, Christopher S.; Thackeray, Michael M.; Kahaian, Arthur J.

2006-05-23T23:59:59.000Z

186

Simultaneous {sup 233}U and{sup 235}U characterization through the assay of delayed neutron temporal behavior  

SciTech Connect (OSTI)

Aqueous solutions containing dissolved uranium-233 and uranium-235 were irradiated for 60's in the SLOWPOKE-2 reactor at the Royal Military College of Canada. The temporal behavior of the delayed neutrons produced was recorded by the Facility's Delayed Neutron Counting (DNC) system. The percentage of uranium-233 as a function of total fissile mass present in each sample ranged from 0 to 100% and was predicted by the DNC system with average absolute errors of {+-} 4%. Future work will upgrade the system electronics and software to reduce both uncertainties in timings and electrical noise. Mixture analysis will also be expanded to include plutonium-239 and fissile materials contained in non-aqueous matrices. (authors)

Sellers, M. T.; Corcoran, E. C.; Kelly, D. G. [Dept. of Chemistry and Chemical Engineering, Royal Military College of Canada, Stn. Forces, P.O. Box 17000, Kingston, ON K7K 7B4 (Canada)

2012-07-01T23:59:59.000Z

187

New capabilities and applications for electrophoretically deposited coatings  

SciTech Connect (OSTI)

Our primary purpose in this test is to provide a brief general description of a few applications of various electrophoretic systems which have been investigated and have found use in various coating applications at Sandia National Laboratories. Both organic and inorganic suspensions in aqueous and non-aqueous media have been considered in these studies. Applications include high voltage insulating dielectrics, thermally conductive/electrically insulating films, adherent lubricating films, uniform photoresist films, glass coatings, and fissile uranium oxide/carbon composite films for studies of nuclear powered lasers. More recently, we have become interested in the beneficial environmental aspects of being able to provide protective polymer coatings which reduce or minimize the use of organic solvents required by traditional spray coat processes. Important practical factors which relate to film uniformity, adhesion, and composition are related to unique coating or plating capabilities and applications. 6 refs., 2 figs., 1 tab.

Sharp, D.J.

1991-01-01T23:59:59.000Z

188

ELECTRONIC SOLUTION SPECTRA FOR URANIUM AND NEPTUNIUM IN OXIDATION STATES (III) TO (VI) IN ANHYDROUS HYDROGEN FLUORIDE  

SciTech Connect (OSTI)

Spectra have been recorded for solutions in anhydrous hydrogen fluoride (AHF) of uranium and neptunium in oxidation states (III) to (VI). The spectra for U(III), Np(III) and Np(IV) in AHF are very similar to those in acidified aqueous solution, but that for U(IV) suggests that the cationic species is UF{sub 2}{sup 2+}. The AHF spectra for the elements in oxidation states (V) and (VI) are not comparable with those of the formally analogous aqueous solutions, where the elements exist as well-defined dioxo-cations. However, the AHF spectra can be related to spectra in the gas phase, in the solid state or in non-aqueous solvents for each element in its appropriate oxidation state.

Baluka, M.; Edelstein, N.; O'Donnell, T. A.

1980-10-01T23:59:59.000Z

189

Solvent for urethane adhesives and coatings and method of use  

DOE Patents [OSTI]

A solvent for urethane adhesives and coatings, the solvent having a carbaldehyde and a cyclic amide as constituents. In some embodiments the solvent consists only of miscible constituents. In some embodiments the carbaldehyde is benzaldehyde and in some embodiments the cyclic amide is N-methylpyrrolidone (M-pyrole). An extender may be added to the solvent. In some embodiments the extender is miscible with the other ingredients, and in some embodiments the extender is non-aqueous. For example, the extender may include isopropanol, ethanol, tetrahydro furfuryl alcohol, benzyl alcohol, Gamma-butyrolactone or a caprolactone. In some embodiments a carbaldehyde and a cyclic amide are heated and used to separate a urethane bonded to a component.

Simandl, Ronald F. (Knoxville, TN); Brown, John D. (Harriman, TN); Holt, Jerrid S. (Knoxville, TN)

2010-08-03T23:59:59.000Z

190

Mixed Salts of LiTFSI and LiBOB for Stable LiFePO4-Based Batteries at Elevated Temperatures  

SciTech Connect (OSTI)

To achieve stable long-term cycling stability at elevated temperatures, mixed salts of LiTFSI and LiBOB are used to replace LiPF6 salt in non-aqueous electrolytes for LiFePO4-based batteries. It is found that adding LiBOB in LiTFSI-based electrolytes effectively prevents the severe corrosion to Al current collectors that often is observed in LiTFSI-based electrolytes, which have high thermal stability. The cells using LiTFSI-LiBOB-based electrolytes demonstrate superior high temperature (60 ?C) stability and very similar room temperature performance (i.e., cycling stability and rate capability) when compared to cells using the LiPF6-based electrolyte.

Chen, Xilin; Xu, Wu; Engelhard, Mark H.; Zheng, Jianming; Zhang, Yaohui; Ding, Fei; Qian, Jiangfeng; Zhang, Jiguang

2014-01-13T23:59:59.000Z

191

Lithium metal oxide electrodes for lithium batteries  

DOE Patents [OSTI]

An uncycled electrode for a non-aqueous lithium electrochemical cell including a lithium metal oxide having the formula Li.sub.(2+2x)/(2+x)M'.sub.2x/(2+x)M.sub.(2-2x)/(2+x)O.sub.2-.delta., in which 0.ltoreq.x<1 and .delta. is less than 0.2, and in which M is a non-lithium metal ion with an average trivalent oxidation state selected from two or more of the first row transition metals or lighter metal elements in the periodic table, and M' is one or more ions with an average tetravalent oxidation state selected from the first and second row transition metal elements and Sn. Methods of preconditioning the electrodes are disclosed as are electrochemical cells and batteries containing the electrodes.

Thackeray, Michael M. (Naperville, IL); Kim, Jeom-Soo (Naperville, IL); Johnson, Christopher S. (Naperville, IL)

2008-01-01T23:59:59.000Z

192

Lithium Metal Oxide Electrodes For Lithium Cells And Batteries  

DOE Patents [OSTI]

A lithium metal oxide positive electrode for a non-aqueous lithium cell is disclosed. The cell is prepared in its initial discharged state and has a general formula xLiMO.sub.2.(1-x)Li.sub.2 M'O.sub.3 in which 0

Thackeray, Michael M. (Naperville, IL); Johnson, Christopher S. (Naperville, IL); Amine, Khalil (Downers Grove, IL); Kim, Jaekook (Naperville, IL)

2004-01-20T23:59:59.000Z

193

Manganese oxide composite electrodes for lithium batteries  

DOE Patents [OSTI]

An activated electrode for a non-aqueous electrochemical cell is disclosed with a precursor of a lithium metal oxide with the formula xLi.sub.2MnO.sub.3.(1-x)LiMn.sub.2-yM.sub.yO.sub.4 for 0

Thackeray, Michael M. (Naperville, IL); Johnson, Christopher S. (Naperville, IL); Li, Naichao (Croton on Hudson, NY)

2007-12-04T23:59:59.000Z

194

Lithium metal oxide electrodes for lithium cells and batteries  

DOE Patents [OSTI]

A lithium metal oxide positive electrode for a non-aqueous lithium cell is disclosed. The cell is prepared in its initial discharged state and has a general formula xLiMO.sub.2.(1-x)Li.sub.2M'O.sub.3 in which 0

Thackeray, Michael M. (Naperville, IL); Johnson, Christopher S. (Naperville, IL); Amine, Khalil (Oakbrook, IL)

2008-12-23T23:59:59.000Z

195

Manganese oxide composite electrodes for lithium batteries  

DOE Patents [OSTI]

An activated electrode for a non-aqueous electrochemical cell is disclosed with a precursor thereof a lithium metal oxide with the formula xLi.sub.2MnO.sub.3.(1-x)LiMn.sub.2-yM.sub.yO.sub.4 for 0.5

Johnson, Christopher S. (Naperville, IL); Kang, Sun-Ho (Naperville, IL); Thackeray, Michael M. (Naperville, IL)

2009-12-22T23:59:59.000Z

196

Electrohydrodynamic atomization (EHDA) assisted wet chemical synthesis of nickel nanoparticles  

SciTech Connect (OSTI)

Highlights: ? Electrohydrodynamic atomization (EHDA) assisted chemical synthesis of nickel nanoparticles is reported. ? Substituting water with non-aqueous media prevents the formation of nickel hydroxide. ? Size of particles decreased from 10 to 20 nm down to 2–4 nm by using multi-jet mode. ? Synthesized nanoparticles have diffraction patterns similar to amorphous materials. -- Abstract: In this study nickel nanoparticles were prepared via chemical reduction of nickel acetate using sodium borohydride using electrohydrodynamic atomization (EHDA) technique. This technique was used to spray a finely dispersed aerosol of nickel precursor solution into the reductive bath. Obtained particles were characterized by means of X-ray diffraction (XRD), UV–Visible spectroscopy, and transmission electron microscopy (TEM). Results confirmed the formation of nickel nanoparticles and showed that applying EHDA technique to chemical reduction method results in producing smaller particles with narrower size distribution in comparison with conventional reductive precipitation method.

Barzegar Vishlaghi, M. [Department of Mechanical Engineering, University of Tabriz, Tabriz (Iran, Islamic Republic of)] [Department of Mechanical Engineering, University of Tabriz, Tabriz (Iran, Islamic Republic of); Farzalipour Tabriz, M., E-mail: meisam.fa@gmail.com [Department of Mechanical Engineering, University of Tabriz, Tabriz (Iran, Islamic Republic of); Mohammad Moradi, O. [Department of Mechanical Engineering, University of Tabriz, Tabriz (Iran, Islamic Republic of)] [Department of Mechanical Engineering, University of Tabriz, Tabriz (Iran, Islamic Republic of)

2012-07-15T23:59:59.000Z

197

Process to produce lithium-polymer batteries  

DOE Patents [OSTI]

A polymer bonded sheet product suitable for use as an electrode in a non-aqueous battery system. A porous electrode sheet is impregnated with a solid polymer electrolyte, so as to diffuse into the pores of the electrode. The composite is allowed to cool, and the electrolyte is entrapped in the porous electrode. The sheet products composed have the solid polymer electrolyte composition diffused into the active electrode material by melt-application of the solid polymer electrolyte composition into the porous electrode material sheet. The solid polymer electrolyte is maintained at a temperature that allows for rapid diffusion into the pores of the electrode. The composite electrolyte-electrode sheets are formed on current collectors and can be coated with solid polymer electrolyte prior to battery assembly. The interface between the solid polymer electrolyte composite electrodes and the solid polymer electrolyte coating has low resistance.

MacFadden, Kenneth Orville (Highland, MD)

1998-01-01T23:59:59.000Z

198

Universal iso-density polarizable continuum model for molecular solvents  

E-Print Network [OSTI]

Implicit electron-density solvation models based on joint density-functional theory offer a computationally efficient solution to the problem of calculating thermodynamic quantities of solvated systems from first-principles quantum mechanics. However, despite much recent interest in such models, to date the applicability of such models to non-aqueous solvents has been limited because the determination of the model parameters requires fitting to a large database of experimental solvation energies for each new solvent considered. This work presents an alternate approach which allows development of new solvation models for a large class of protic and aprotic solvents from only simple, single-molecule ab initio calculations and readily available bulk thermodynamic data. We find that this model is accurate to nearly 1.7 kcal/mol even for solvents outside our development set.

Gunceler, Deniz

2014-01-01T23:59:59.000Z

199

Method for synthesizing pollucite from chabazite and cesium chloride  

DOE Patents [OSTI]

A method is described for immobilizing waste chlorides salts containing radionuclides and hazardous nuclear material for permanent disposal, and in particular, a method is described for immobilizing waste chloride salts containing cesium, in a synthetic form of pollucite. The method for synthesizing pollucite from chabazite and cesium chloride includes mixing dry, non-aqueous cesium chloride with chabazite and heating the mixture to a temperature greater than the melting temperature of the cesium chloride, or above about 700 C. The method further comprises significantly improving the rate of retention of cesium in ceramic products comprised of a salt-loaded zeolite by adding about 10% chabazite by weight to the salt-loaded zeolite prior to conversion at elevated temperatures and pressures to the ceramic composite. 3 figs.

Pereira, C.

1999-02-23T23:59:59.000Z

200

Method for synthesizing pollucite from chabazite and cesium chloride  

DOE Patents [OSTI]

A method for immobilizing waste chlorides salts containing radionuclides and hazardous nuclear material for permanent disposal, and in particular, a method for immobilizing waste chloride salts containing cesium, in a synthetic form of pollucite. The method for synthesizing pollucite from chabazite and cesium chloride includes mixing dry, non-aqueous cesium chloride with chabazite and heating the mixture to a temperature greater than the melting temperature of the cesium chloride, or above about 700.degree. C. The method further comprises significantly improving the rate of retention of cesium in ceramic products comprised of a salt-loaded zeolite by adding about 10% chabazite by weight to the salt-loaded zeolite prior to conversion at elevated temperatures and pressures to the ceramic composite.

Pereira, Candido (Naperville, IL)

1999-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "millivolt napl non-aqueous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Low-temperature lithium diffusion in simulated high-level boroaluminosilicate nuclear waste glasses  

SciTech Connect (OSTI)

Ion exchange is recognized as an integral, if underrepresented, mechanism influencing glass corrosion. However, due to the formation of various alteration layers in the presence of water, it is difficult to conclusively deconvolute the mechanisms of ion exchange from other processes occurring simultaneously during corrosion. In this work, an operationally inert non-aqueous solution was used as an alkali source material to isolate ion exchange and study the solid-state diffusion of lithium. Specifically, the experiments involved contacting glass coupons relevant to the immobilization of high-level nuclear waste, SON68 and CJ-6, which contained Li in natural isotope abundance, with a non-aqueous solution of 6LiCl dissolved in dimethyl sulfoxide at 90 °C for various time periods. The depth profiles of major elements in the glass coupons were measured using time-of-flight secondary ion mass spectrometry (ToF-SIMS). Lithium interdiffusion coefficients, DLi, were then calculated based on the measured depth profiles. The results indicate that the penetration of 6Li is rapid in both glasses with the simplified CJ-6 glass (D6Li ? 4.0-8.0 × 10-21 m2/s) exhibiting faster exchange than the more complex SON68 glass (DLi ? 2.0-4.0 × 10-21 m2/s). Additionally, sodium ions present in the glass were observed to participate in ion exchange reactions; however, different diffusion coefficients were necessary to fit the diffusion profiles of the two alkali ions. Implications of the diffusion coefficients obtained in the absence of alteration layers to the long-term performance of nuclear waste glasses in a geological repository system are also discussed.

Neeway, James J.; Kerisit, Sebastien N.; Gin, Stephane; Wang, Zhaoying; Zhu, Zihua; Ryan, Joseph V.

2014-12-01T23:59:59.000Z

202

Pore-scale flow characterization of low-interfacial tension flow through mixed-wet porous media with different pore geometries  

SciTech Connect (OSTI)

The low-interfacial tension flow through porous media occurs in surfactant-based enhanced oil recovery (EOR), soil clean-up, underground removal of the non-aqueous phase liquid and dense non-aqueous phase liquid, etc. In surfactant-based EOR processes, numerous works have been carried out to characterize - either qualitatively or quantitatively - the micro- and macro-scale flow behavior. What has been lacking is to link the statistics of oil blobs population (e.g., distribution of blob length and diameter) to the pore-scale phenomena and macro-scale quantities. In particular, no work has been reported to elucidate the effect of the ratio of pore body to throat diameter (i.e., aspect ratio) on the pore-scale characterization based on the blobs population statistics. The significance of the aspect ratio lies in that it describes the geometry of a porous medium and is one of the foremost morphological features. The aspect ratio is also one of the fundamental factors governing the pore-level events. This study presents the effect of aspect ratio on the statistical distribution of the blob length and equivalent diameter and links the blobs population statistics to the observed pore-level events. The pore-scale variation of the ratio of viscous-to-capillary forces acted on the oil blobs at the threshold of displacement is utilized to characterize the effect of blob length distribution at different aspect ratios. It also provides some insight into correlating the change in oil recovery efficiency and capillary number, by change in aspect ratio, with the change in blobs population statistics. (author)

Yadali Jamaloei, Benyamin [Petroleum Systems Engineering Department, Faculty of Engineering and Applied Science, The University of Regina, Regina, Saskatchewan (Canada); Petroleum Research Center, The Petroleum University of Technology, Tehran (Iran, Islamic Republic of); Asghari, Koorosh [Petroleum Systems Engineering Department, Faculty of Engineering and Applied Science, The University of Regina, Regina, Saskatchewan (Canada); Kharrat, Riyaz [Petroleum Research Center, The Petroleum University of Technology, Tehran (Iran, Islamic Republic of)

2011-01-15T23:59:59.000Z

203

Technetium Sorption by Cementitious Materials Under Reducing Conditions  

SciTech Connect (OSTI)

The objective of this study was to measure technetium ({sup 99}Tc) sorption to cementitious materials under reducing conditions to simulate Saltstone Disposal Facility conditions. {sup 99}Tc(VII) batch sorption experiments were conducted for 319 days in an inert glovebag with a variety of cementitious materials (aged cement, Vault 2, TR545, and TR547) containing varying amounts of blast furnace slag. Between 154 and 319 days, the {sup 99}Tc aqueous concentrations tended to remain constant and samples amended with different initial {sup 99}Tc concentrations, tended to merge at about 10{sup -9} M for Vault 2 (17% slag) and TR545 (90% slag) and 10{sup -8} M for TR547 (45% slag). This data provided strong evidence that solubility, and not adsorption (K{sub d} values), was controlling aqueous {sup 99}Tc concentrations. Laboratory data superimposed over thermodynamic speciation diagrams further supported the conclusion that solubility, and not adsorption controlled {sup 99}Tc aqueous concentrations. The oxidation state of the aqueous {sup 99}Tc at the end of the sorption experiment was determined by solvent extraction to be almost entirely {sup 99}Tc(VII). The pH of the present system was ~11.8. Previously proposed solubility controlling phases including Tc-sulfides may be present, but do not appear to control solubility. After the 319 day sorption period, the suspensions were removed from the glovebag and a desorption step under oxic conditions was conducted for 20 days by adding oxic, pH-buffered solutions to the suspensions. {sup 99}Tc aqueous concentrations increased by more than an order of magnitude and Eh increased by several hundred millivolts within 24 hours after the introduction of the oxic solutions. These desorption results are consistent with re-oxidation and dissolution/desorption of {sup 99}Tc(IV) phases possibly present in the cementitious materials after the anoxic sorption step of the experiment. Aqueous {sup 99}Tc concentrations continued to increase slowly until the termination of the desorption experiment after 20 days. Although the cementitious materials investigated demonstrated the ability to strongly sequester aqueous {sup 99}Tc under anoxic conditions, the introduction of oxygen resulted in the rapid remobilization of {sup 99}Tc. These studies provide experimental support for the use of a solubility based model under reducing saltstone conditions where Tc(IV) is expected to be the dominant species. The existing Kd model would be appropriate for oxidized saltstone conditions (aged saltstone, not directly evaluated in this study) where Tc(VII) is expected to be the dominant species.

Kaplan, Daniel I. [Savannah River Site (SRS), Aiken, SC (United States); Estes, Shanna L. [Environmental Engineering and Earth Sciences, Clemson University, Clemson, SC (United States); Powell, Brian A. [Environmental Engineering and Earth Sciences, Clemson University, Clemson, SC (United States)

2012-09-28T23:59:59.000Z

204

Particle Physics at the University of Pittsburgh Summary Report for Proposal Period FY'09-11  

SciTech Connect (OSTI)

Presented is the final summary report for grant DOE-FG02-91ER40646. The HEP group at the University consists of three tasks: B,D and L. Task B supports Pitt's CDF group at the energy frontier which includes Joe Boudreau and Paul Shepard. Work of the group includes Hao Song's thesis on the measurement of the B_c lifetime using exclusive J/psi+pion decays, and an update of the previous B_c semi-leptonic analyses under the supervision of Paul Shepard. Task D supports Pitt's neutrino group at the intensity frontier which includes PIs Dytman, Naples and Paolone. The group also includes postdoctoral research associate Danko, and thesis students Isvan (MINOS), Eberly (Minerva ), Ren (Minerva )and Hansen (T2K). This report summarizes their progress on ongoing experiments which are designed to make significant contributions to a detailed understanding of the neutrino mixing matrix. Task L supports Pitt's ATLAS group at the energy frontier and includes investigators Vladimir Savinov, James Mueller and Joe Boudreau. This group contributed both to hardware (calorimeter electronics, Savinov) and to software (Simulation, Detector Description, and Visualization: Boudreau and Mueller; MC generators: Savinov) and a summary of their progress is presented.

Boudreau, Joe; Dytman, Steven; Mueller, James; Naples, Donna; Paolone, Vittorio; Savinov, Vladimir

2012-10-01T23:59:59.000Z

205

TMVOC, simulator for multiple volatile organic chemicals  

SciTech Connect (OSTI)

TMVOC is a numerical simulator for three-phase non-isothermal flow of water, soil gas, and a multicomponent mixture of volatile organic chemicals (VOCs) in multidimensional heterogeneous porous media. It is an extension of the TOUGH2 general-purpose simulation program developed at the Lawrence Berkeley National Laboratory. TMVOC is designed for applications to contamination problems that involve hydrocarbon fuel or organic solvent spills in saturated and unsaturated zones. It can model contaminant behavior under ''natural'' environmental conditions, as well as for engineered systems, such as soil vapor extraction, groundwater pumping, or steam-assisted source remediation. TMVOC is upwards compatible with T2VOC (Falta et al., 1995) and can be initialized from T2VOC-style initial conditions. The main enhancements in TMVOC relative to T2VOC are as follows: a multicomponent mixture of volatile organic chemicals can be modeled; any and all combinations of the three phases water-oil-gas are treated; several non-condensible gases may be present; diffusion is treated in all phases in a manner that is fully coupled with phase partitioning. This paper gives a brief summary of the methodology used in TMVOC as well as highlighting some implementation issues. Simulation of a NAPL spill and subsequent remediation is discussed for a 2-D vertical section of a saturated-unsaturated flow problem.

Pruess, Karsten; Battistelli, Alfredo

2003-03-25T23:59:59.000Z

206

Remediation of DNAPLs in Low Permeability Soils. Innovative Technology Summary Report  

SciTech Connect (OSTI)

Dense, non-aqueous phase liquid (DNAPL) compounds like trichloroethene (TCE) and perchloroethene (PCE) are prevalent at U. S. Department of Energy (DOE), other government, and industrial sites. Their widespread presence in low permeability media (LPM) poses severe challenges for assessment of their behavior and implementation of effective remediation technologies. Most remedial methods that involve fluid flow perform poorly in LPM. Hydraulic fracturing can improve the performance of remediation methods such as vapor extraction, free-product recovery, soil flushing, steam stripping, bioremediation, bioventing, and air sparging in LPM by enhancing formation permeability through the creation of fractures filled with high-permeability materials, such as sand. Hydraulic fracturing can improve the performance of other remediation methods such as oxidation, reductive dechlorination, and bioaugmentation by enhancing delivery of reactive agents to the subsurface. Hydraulic fractures are typically created using a 2-in. steel casing and a drive point pushed into the subsurface by a pneumatic hammer. Hydraulic fracturing has been widely used for more than 50 years to stimulate the yield of wells recovering oil from rock at great depth and has recently been shown to stimulate the yield of wells recovering contaminated liquids and vapors from LPM at shallow depths. Hydraulic fracturing is an enabling technology for improving the performance of some remedial methods and is a key element in the implementation of other methods. This document contains information on the above-mentioned technology, including description, applicability, cost, and performance data.

None

2000-09-01T23:59:59.000Z

207

Subsurface contaminants focus area  

SciTech Connect (OSTI)

The US Department of Enregy (DOE) Subsurface Contaminants Focus Area is developing technologies to address environmental problems associated with hazardous and radioactive contaminants in soil and groundwater that exist throughout the DOE complex, including radionuclides, heavy metals; and dense non-aqueous phase liquids (DNAPLs). More than 5,700 known DOE groundwater plumes have contaminated over 600 billion gallons of water and 200 million cubic meters of soil. Migration of these plumes threatens local and regional water sources, and in some cases has already adversely impacted off-site rsources. In addition, the Subsurface Contaminants Focus Area is responsible for supplying technologies for the remediation of numerous landfills at DOE facilities. These landfills are estimated to contain over 3 million cubic meters of radioactive and hazardous buried Technology developed within this specialty area will provide efective methods to contain contaminant plumes and new or alternative technologies for development of in situ technologies to minimize waste disposal costs and potential worker exposure by treating plumes in place. While addressing contaminant plumes emanating from DOE landfills, the Subsurface Contaminants Focus Area is also working to develop new or alternative technologies for the in situ stabilization, and nonintrusive characterization of these disposal sites.

NONE

1996-08-01T23:59:59.000Z

208

Ionic liquids and ionic liquid acids with high temperature stability for fuel cell and other high temperature applications, method of making and cell employing same  

DOE Patents [OSTI]

Disclosed are developments in high temperature fuel cells including ionic liquids with high temperature stability and the storage of inorganic acids as di-anion salts of low volatility. The formation of ionically conducting liquids of this type having conductivities of unprecedented magnitude for non-aqueous systems is described. The stability of the di-anion configuration is shown to play a role in the high performance of the non-corrosive proton-transfer ionic liquids as high temperature fuel cell electrolytes. Performance of simple H.sub.2(g) electrolyte/O.sub.2(g) fuel cells with the new electrolytes is described. Superior performance both at ambient temperature and temperatures up to and above 200.degree. C. are achieved. Both neutral proton transfer salts and the acid salts with HSO.sup.-.sub.4 anions, give good results, the bisulphate case being particularly good at low temperatures and very high temperatures. The performance of all electrolytes is improved by the addition of a small amount of involatile base of pK.sub.a value intermediate between those of the acid and base that make the bulk electrolyte. The preferred case is the imidazole-doped ethylammonium hydrogensulfate which yields behavior superior in all respects to that of the industry standard phosphoric acid electrolyte.

Angell, C. Austen (Mesa, AZ); Xu, Wu (Broadview Heights, OH); Belieres, Jean-Philippe (Chandler, AZ); Yoshizawa, Masahiro (Tokyo, JP)

2011-01-11T23:59:59.000Z

209

LNAPL Removal from Unsaturated Porous Media using Surfactant Infiltration  

SciTech Connect (OSTI)

A series of unsaturated column experiments was performed to evaluate light non-aqueous phase liquid (LNAPL) fate and removal during surfactant solution infiltration. Surfactant-LNAPL phase behavior tests were conducted to optimize the remedial solutions. Packed sand and site sediment columns were first processed to establish representative LNAPL smear zone under unsaturated conditions. Infiltration of low-concentration surfactant was then applied in a stepwise flush mode, with 0.3 column pore volume (PV) of solution in each flush. The influence of infiltrated surfactant solution volume and pH on LNAPL removal was assessed. A LNAPL bank was observed at the very front of the first surfactant infiltration in each column, indicating that a very low surfactant concentration is needed to reduce the LNAPL-water interfacial tension sufficiently enough to mobilize trapped LNAPL under unsaturated conditions. More LNAPL was recovered as additional steps of surfactant infiltration were applied. Up to 99% LNAPL was removed after six infiltration steps, with less than 2.0 PV of total surfactant solution application, suggesting surfactant infiltration may be an effective method for vadose zone LNAPL remediation. The influence of pH tested in this study (3.99~10.85) was insignificant because the buffering capacity of the sediment kept the pH in the column higher than the zero point charge, pHzpc, of the sediment and therefore the difference between surfactant sorption was negligible.

Zhong, Lirong; Oostrom, Martinus

2012-11-19T23:59:59.000Z

210

Influences of Flow Transients and Porous Medium Heterogeneity on Colloid-Associated Contaminant Transport in the Vadose Zone  

SciTech Connect (OSTI)

Radionuclides, metals, and dense non-aqueous phase liquids have contaminated about six billion cubic meters of soil at Department of Energy (DOE) sites. The subsurface transport of many of these contaminants is facilitated by colloids (i.e., microscopic, waterborne particles). The first step in the transport of contaminants from their sources to off-site surface water and groundwater is migration through the vadose zone. Developing our understanding of the migration of colloids and colloid-associated contaminants through the vadose zone is critical to assessing and controlling the release of contaminants from DOE sites. In this study, we examined the mobilization, transport, and filtration (retention) of mineral colloids and colloidassociated radionuclides within unsaturated porous media. This investigation involved laboratory column experiments designed to identify properties that affect colloid mobilization and retention and pore-scale visualization experiments designed to elucidate mechanisms that govern these colloid-mass transfer processes. The experiments on colloid mobilization and retention were supplemented with experiments on radionuclide transport through porous media and on radionuclide adsorption to mineral colloids. Observations from all of these experiments – the column and visualization experiments with colloids and the experiments with radionuclides – were used to guide the development of mathematical models appropriate for describing colloids and colloid-facilitated radionuclide transport through the vadose zone.

James Saiers; Joseph Ryan

2006-07-02T23:59:59.000Z

211

Influences of Flow Transients and Porous Medium Heterogeneity on Colloid-Associated Contaminant Transport in the Vadose Zone  

SciTech Connect (OSTI)

Radionuclides, metals, and dense non-aqueous phase liquids have contaminated about six billion cubic meters of soil at Department of Energy (DOE) sites. The subsurface transport of many of these contaminants is facilitated by colloids (i.e., microscopic, waterborne particles). The first step in the transport of contaminants from their sources to off-site surface water and groundwater is migration through the vadose zone. Developing our understanding of the migration of colloids and colloid-associated contaminants through the vadose zone is critical to assessing and controlling the release of contaminants from DOE sites. In this study, we examined the mobilization, transport, and filtration (retention) of mineral colloids and colloid-associated radionuclides within unsaturated porous media. This investigation involved laboratory column experiments designed to identify properties that affect colloid mobilization and retention and pore-scale visualization experiments designed to elucidate mechanisms that govern these colloid-mass transfer processes. The experiments on colloid mobilization and retention were supplemented with experiments on radionuclide transport through porous media and on radionuclide adsorption to mineral colloids. Observations from all of these experiments – the column and visualization experiments with colloids and the experiments with radionuclides – were used to guide the development of mathematical models appropriate for describing colloids and colloid-facilitated radionuclide transport through the vadose zone.

James Saiers

2006-06-28T23:59:59.000Z

212

Hybrid joule heating/electro-osmosis process for extracting contaminants from soil layers  

DOE Patents [OSTI]

Joule (ohmic) heating and electro-osmosis are combined in a hybrid process for removal of both water-soluble contaminants and non-aqueous phase liquids from contaminated, low-permeability soil formations that are saturated. Central to this hybrid process is the partial desaturation of the formation or layer using electro-osmosis to remove a portion of the pore fluids by induction of a ground water flow to extraction wells. Joule heating is then performed on a partially desaturated formation. The joule heating and electro-osmosis operations can be carried out simultaneously or sequentially if the desaturation by electro-osmosis occurs initially. Joule heating of the desaturated formation results in a very effective transfer or partitioning of liquid state contaminants to the vapor phase. The heating also substantially increases the vapor phase pressure in the porous formation. As a result, the contaminant laden vapor phase is forced out into soil layers of a higher permeability where other conventional removal processes, such as steam stripping or ground water extraction can be used to capture the contaminants. This hybrid process is more energy efficient than joule heating or steam stripping for cleaning low permeability formations and can share electrodes to minimize facility costs.

Carrigan, Charles R.; Nitao, John J.

2003-06-10T23:59:59.000Z

213

Lithium metal oxide electrodes for lithium batteries  

DOE Patents [OSTI]

An uncycled preconditioned electrode for a non-aqueous lithium electrochemical cell including a lithium metal oxide having the formula xLi2-yHyO.xM'O2.(1-x)Li1-zHzMO2 in which 02-yHy.xM'O2.(1-x)Li1-zHzMO2 material is prepared by preconditioning a precursor lithium metal oxide (i.e., xLi2M'O3.(1-x)LiMO2) with a proton-containing medium with a pH<7.0 containing an inorganic acid. Methods of preparing the electrodes are disclosed, as are electrochemical cells and batteries containing the electrodes.

Thackeray, Michael M.; Johnson, Christopher S.; Amine, Khalil; Kang, Sun-Ho

2010-06-08T23:59:59.000Z

214

PCLC flake-based apparatus and method  

DOE Patents [OSTI]

A PCLC flake/fluid host suspension that enables dual-frequency, reverse drive reorientation and relaxation of the PCLC flakes is composed of a fluid host that is a mixture of: 94 to 99.5 wt % of a non-aqueous fluid medium having a dielectric constant value .di-elect cons., where 1<.di-elect cons.<7, a conductivity value .sigma., where 10.sup.-9>.sigma.>10.sup.-7 Siemens per meter (S/m), and a resistivity r, where 10.sup.7>r>10.sup.10 ohm-meters (.OMEGA.-m), and which is optically transparent in a selected wavelength range .DELTA..lamda.; 0.0025 to 0.25 wt % of an inorganic chloride salt; 0.0475 to 4.75 wt % water; and 0.25 to 2 wt % of an anionic surfactant; and 1 to 5 wt % of PCLC flakes suspended in the fluid host mixture. Various encapsulation forms and methods are disclosed including a Basic test cell, a Microwell, a Microcube, Direct encapsulation (I), Direct encapsulation (II), and Coacervation encapsulation. Applications to display devices are disclosed.

Cox, Gerald P; Fromen, Cathy A; Marshall, Kenneth L; Jacobs, Stephen D

2012-10-23T23:59:59.000Z

215

In-situ Spectroscopic and Structural Studies of Electrode Materials for Advanced Battery Applications  

SciTech Connect (OSTI)

Techniques have been developed and implemented to gain insight into fundamental factors that affect the performance of electrodes in Li and Li-ion batteries and other energy storage devices. These include experimental strategies for monitoring the Raman scattering spectra of single microparticles of carbon and transition metal oxides as a function of their state of charge. Measurements were performed in electrolytes of direct relevance to Li and Li-Ion batteries both in the static and dynamic modes. In addition, novel strategies were devised for performing conventional experiments in ultrahigh vacuum environments under conditions which eliminate effects associated with presence of impurities, using ultrapure electrolytes, both of the polymeric and ionic liquid type that display no measurable vapor pressure. Also examined was the reactivity of conventional non aqueous solvent toward ultrapure Li films as monitored in ultrahigh vacuum with external reflection Fourier transform infrared spectroscopy. Also pursued were efforts toward developing applying Raman-scattering for monitoring the flow of charge of a real Li ion battery. Such time-resolved, spatially-resolved measurements are key to validating the results of theoretical simulations involving real electrode structures.

Daniel A Scherson

2013-03-14T23:59:59.000Z

216

Compacted carbon for electrochemical cells  

DOE Patents [OSTI]

This invention provides compacted carbon that is useful in the electrode of an alkali metal/carbon electrochemical cell of improved capacity selected from the group consisting of: (a) coke having the following properties: (1) an x-ray density of at least 2.00 grams per cubic centimeters, (2) a closed porosity of no greater than 5%, and (3) an open porosity of no greater than 47%; and (b) graphite having the following properties: (1) an x-ray density of at least 2.20 grams per cubic centimeters, (2) a closed porosity of no greater than 5%, and (3) an open porosity of no greater than 25%. This invention also relates to an electrode for an alkali metal/carbon electrochemical cell comprising compacted carbon as described above and a binder. This invention further provides an alkali metal/carbon electrochemical cell comprising: (a) an electrode as described above, (b) a non-aqueous electrolytic solution comprising an organic aprotic solvent and an electrolytically conductive salt and an alkali metal, and (c) a counter electrode. 10 figs.

Greinke, R.A.; Lewis, I.C.

1997-10-14T23:59:59.000Z

217

Method of digesting an explosive nitro compound  

DOE Patents [OSTI]

The present invention is a process wherein bleaching oxidants are used to digest explosive nitro compounds. The process has an excellent reaction rate for digesting explosives and operates under multivariate conditions. Reaction solutions may be aqueous, non-aqueous or a combination thereof, and can also be any pH, but preferably have a pH between 2 and 9. The temperature may be ambient as well as any temperature above which freezing of the solution would occur and below which any degradation of the bleaching oxidant would occur or below which any explosive reaction would be initiated. The pressure may be any pressure, but is preferably ambient or atmospheric, or a pressure above a vapor pressure of the aqueous solution to avoid boiling of the solution. Because the bleaching oxidant molecules are small, much smaller than an enzyme molecule for example, they can penetrate the microstructure of plastic explosives faster. The bleaching oxidants generate reactive hydroxyl radicals, which can destroy other organic contaminants, if necessary, along with digesting the explosive nitro compound.

Shah, Manish M. (Richland, WA)

2000-01-01T23:59:59.000Z

218

Long-term proliferation and safeguards issues in future technologies  

SciTech Connect (OSTI)

The purpose of the task was to assess the effect of potential new technologies, nuclear and non-nuclear, on safeguards needs and non-proliferation policies, and to explore possible solutions to some of the problems envisaged. Eight subdivisions were considered: New Enrichment Technologies; Non-Aqueous Reprocessing Technologies; Fusion; Accelerator-Driven Reactor Systems; New Reactor Types; Heavy Water and Deuterium; Long-Term Storage of Spent Fuel; and Other Future Technologies (Non-Nuclear). For each of these subdivisions, a careful review of the current world-wide effort in the field provided a means of subjectively estimating the viability and qualitative probability of fruition of promising technologies. Technologies for which safeguards and non-proliferation requirements have been thoroughly considered by others were not restudied here (e.g., the Fast Breeder Reactor). The time scale considered was 5 to 40 years for possible initial demonstration although, in some cases, a somewhat optimistic viewpoint was embraced. Conventional nuclear-material safeguards are only part of the overall non-proliferation regime. Other aspects are international agreements, export controls on sensitive technologies, classification of information, intelligence gathering, and diplomatic initiatives. The focus here is on safeguards, export controls, and classification.

Keisch, B.; Auerbach, C.; Fainberg, A.; Fiarman, S.; Fishbone, L.G.; Higinbotham, W.A.; Lemley, J.R.; O'Brien, J.

1986-02-01T23:59:59.000Z

219

Dry Processing of Used Nuclear Fuel  

SciTech Connect (OSTI)

Dry (non-aqueous) separations technologies have been used for treatment of used nuclear fuel since the 1960s, and they are still being developed and demonstrated in many countries. Dry technologies offer potential advantages compared to traditional aqueous separations including: compactness, resistance to radiation effects, criticality control benefits, compatibility with advanced fuel types, and ability to produce low purity products. Within the Department of Energy’s Advanced Fuel Cycle Initiative, an electrochemical process employing molten salts is being developed for recycle of fast reactor fuel and treatment of light water reactor oxide fuel to produce a feed for fast reactors. Much of the development of this technology is based on treatment of used Experimental Breeder Reactor II (EBR-II) fuel, which is metallic. Electrochemical treatment of the EBR-II fuel has been ongoing in the Fuel Conditioning Facility, located at the Materials and Fuel Complex of Idaho National Laboratory since 1996. More than 3.8 metric tons of heavy metal of metallic fast reactor fuel have been treated using this technology. This paper will summarize the status of electrochemical development and demonstration activities with used nuclear fuel, including high-level waste work. A historic perspective on the background of dry processing will also be provided.

K. M. Goff; M. F. Simpson

2009-09-01T23:59:59.000Z

220

Alternative formulations of regenerable flue gas cleanup catalysts  

SciTech Connect (OSTI)

The major source of man-made SO{sub 2} in the atmosphere is the burning of coal for electric power generation. Coal-fired utility plants are also large sources of NO{sub x} pollution. Regenerable flue gas desulfurization/NO{sub x} abatement catalysts provide one mechanism of simultaneously removing SO{sub 2} and NO{sub x} species from flue gases released into the atmosphere. The purpose of this project is to examine routes of optimizing the adsorption efficiency, the adsorption capacity, and the ease of regeneration of regenerable flue gas cleanup catalysts. We are investigating two different mechanisms for accomplishing this goal. The first involves the use of different alkali and alkaline earth metals as promoters for the alumina sorbents to increase the surface basicity of the sorbent and thus adjust the number and distribution of adsorption sites. The second involves investigation of non-aqueous impregnation, as opposed to aqueous impregnation, as a method to obtain an evenly dispersed monolayer of the promoter on the surface.

Mitchell, M.B.; White, M.G.

1991-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "millivolt napl non-aqueous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Alternative formulations of regenerable flue gas cleanup catalysts. Progress report, September 1, 1990--August 31, 1991  

SciTech Connect (OSTI)

The major source of man-made SO{sub 2} in the atmosphere is the burning of coal for electric power generation. Coal-fired utility plants are also large sources of NO{sub x} pollution. Regenerable flue gas desulfurization/NO{sub x} abatement catalysts provide one mechanism of simultaneously removing SO{sub 2} and NO{sub x} species from flue gases released into the atmosphere. The purpose of this project is to examine routes of optimizing the adsorption efficiency, the adsorption capacity, and the ease of regeneration of regenerable flue gas cleanup catalysts. We are investigating two different mechanisms for accomplishing this goal. The first involves the use of different alkali and alkaline earth metals as promoters for the alumina sorbents to increase the surface basicity of the sorbent and thus adjust the number and distribution of adsorption sites. The second involves investigation of non-aqueous impregnation, as opposed to aqueous impregnation, as a method to obtain an evenly dispersed monolayer of the promoter on the surface.

Mitchell, M.B.; White, M.G.

1991-12-31T23:59:59.000Z

222

Hydrophobic ionic liquids  

DOE Patents [OSTI]

Ionic liquids having improved properties for application in non-aqueous batteries, electrochemical capacitors, electroplating, catalysis and chemical separations are disclosed. Exemplary compounds have one of the following formulas: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, and R.sub.6 are either H; F; separate alkyl groups of from 1 to 4 carbon atoms, respectively, or joined together to constitute a unitary alkylene radical of from 2 to 4 carbon atoms forming a ring structure converging on N; or separate phenyl groups; and wherein the alkyl groups, alkylene radicals or phenyl groups may be substituted with electron withdrawing groups, preferably F--, Cl--, CF.sub.3 --, SF.sub.5 --, CF.sub.3 S--, (CF.sub.3).sub.2 CHS-- or (CF.sub.3).sub.3 CS--; and X.sup.- is a non-Lewis acid-containing polyatomic anion having a van der Waals volume exceeding 100 .ANG..sup.3.

Koch, Victor R. (Lincoln, MA); Nanjundiah, Chenniah (Lynn, MA); Carlin, Richard T. (Nashua, NH)

1998-01-01T23:59:59.000Z

223

Hydrophobic ionic liquids  

DOE Patents [OSTI]

Ionic liquids having improved properties for application in non-aqueous batteries, electrochemical capacitors, electroplating, catalysis and chemical separations are disclosed. Exemplary compounds have one of the following formulas shown in a diagram wherein R{sub 1}, R{sub 2}, R{sub 3}, R{sub 4}, R{sub 5}, and R{sub 6} are either H; F; separate alkyl groups of from 1 to 4 carbon atoms, respectively, or joined together to constitute a unitary alkylene radical of from 2 to 4 carbon atoms forming a ring structure converging on N; or separate phenyl groups; and wherein the alkyl groups, alkylene radicals or phenyl groups may be substituted with electron withdrawing groups, preferably F-, Cl-, CF{sub 3}-, SF{sub 5}-, CF{sub 3}S-, (CF{sub 3}){sub 2}CHS- or (CF{sub 3}){sub 3}CS-; and X{sup {minus}} is a non-Lewis acid-containing polyatomic anion having a van der Waals volume exceeding 100 {angstrom}{sup 3}. 4 figs.

Koch, V.R.; Nanjundiah, C.; Carlin, R.T.

1998-10-27T23:59:59.000Z

224

The in-situ decontamination of sand and gravel aquifers by chemically enhanced solubilization of multiple-compound DNAPLs with surfactant solutions: Phase 1 -- Laboratory and pilot field-scale testing and Phase 2 -- Solubilization test and partitioning and interwell tracer tests. Final report  

SciTech Connect (OSTI)

Laboratory, numerical simulation, and field studies have been conducted to assess the potential use of micellar-surfactant solutions to solubilize chlorinated solvents contaminating sand and gravel aquifers. Ninety-nine surfactants were screened for their ability to solubilize trichloroethene (TCE), perchloroethylene (PCE), and carbon tetrachloride (CTET). The field test was conducted in the alluvial aquifer which is located 20 to 30 meters beneath a vapor degreasing operation at Paducah Gaseous Diffusion Plant. This aquifer has become contaminated with TCE due to leakage of perhaps 40,000 liters of TCE, which has generated a plume of dissolved TCE extending throughout an area of approximately 3 km{sup 2} in the aquifer. Most of the TCE is believed to be present in the overlying lacustrine deposits and in the aquifer itself as a dense, non-aqueous phase liquid, or DNAPL. The objective of the field test was to assess the efficacy of the surfactant for in situ TCE solubilization. Although the test demonstrated that sorbitan monooleate was unsuitable as a solubilizer in this aquifer, the single-well test was demonstrated to be a viable method for the in situ testing of surfactants or cosolvents prior to proceeding to full-scale remediation.

NONE

1997-10-24T23:59:59.000Z

225

Surfactant/detergent titration analysis method and apparatus for machine working fluids, surfactant-containing wastewater and the like  

DOE Patents [OSTI]

The present invention is an improved method and related apparatus for quantitatively analyzing machine working fluids and other aqueous compositions such as wastewater which contain various mixtures of cationic, neutral, and/or anionic surfactants, soluble soaps, and the like. The method utilizes a single-phase, non-aqueous, reactive titration composition containing water insoluble bismuth nitrate dissolved in glycerol for the titration reactant. The chemical reaction of the bismuth ion and glycerol with the surfactant in the test solutions results in formation of micelles, changes in micelle size, and the formation of insoluble bismuth soaps. These soaps are quantified by physical and chemical changes in the aqueous test solution. Both classical potentiometric analysis and turbidity measurements have been used as sensing techniques to determine the quantity of surfactant present in test solutions. This method is amenable to the analysis of various types of new, in-use, dirty or decomposed surfactants and detergents. It is a quick and efficient method utilizing a single-phase reaction without needing a separate extraction from the aqueous solution. It is adaptable to automated control with simple and reliable sensing methods. The method is applicable to a variety of compositions with concentrations from about 1% to about 10% weight. It is also applicable to the analysis of waste water containing surfactants with appropriate pre-treatments for concentration.

Smith, Douglas D. (Knoxville, TN); Hiller, John M. (Oak Ridge, TN)

1998-01-01T23:59:59.000Z

226

Surfactant/detergent titration analysis method and apparatus for machine working fluids, surfactant-containing wastewater and the like  

DOE Patents [OSTI]

The present invention is an improved method and related apparatus for quantitatively analyzing machine working fluids and other aqueous compositions such as wastewater which contain various mixtures of cationic, neutral, and/or anionic surfactants, soluble soaps, and the like. The method utilizes a single-phase, non-aqueous, reactive titration composition containing water insoluble bismuth nitrate dissolved in glycerol for the titration reactant. The chemical reaction of the bismuth ion and glycerol with the surfactant in the test solutions results in formation of micelles, changes in micelle size, and the formation of insoluble bismuth soaps. These soaps are quantified by physical and chemical changes in the aqueous test solution. Both classical potentiometric analysis and turbidity measurements have been used as sensing techniques to determine the quantity of surfactant present in test solutions. This method is amenable to the analysis of various types of new, in-use, dirty or decomposed surfactants and detergents. It is a quick and efficient method utilizing a single-phase reaction without needing a separate extraction from the aqueous solution. It is adaptable to automated control with simple and reliable sensing methods. The method is applicable to a variety of compositions with concentrations from about 1% to about 10% weight. It is also applicable to the analysis of waste water containing surfactants with appropriate pre-treatments for concentration. 1 fig.

Smith, D.D.; Hiller, J.M.

1998-02-24T23:59:59.000Z

227

Contaminant plumes containment and remediation focus area. Technology summary  

SciTech Connect (OSTI)

EM has established a new approach to managing environmental technology research and development in critical areas of interest to DOE. The Contaminant Plumes Containment and Remediation (Plumes) Focus Area is one of five areas targeted to implement the new approach, actively involving representatives from basic research, technology implementation, and regulatory communities in setting objectives and evaluating results. This document presents an overview of current EM activities within the Plumes Focus Area to describe to the appropriate organizations the current thrust of the program and developing input for its future direction. The Plumes Focus Area is developing remediation technologies that address environmental problems associated with certain priority contaminants found at DOE sites, including radionuclides, heavy metals, and dense non-aqueous phase liquids (DNAPLs). Technologies for cleaning up contaminants of concern to both DOE and other federal agencies, such as volatile organic compounds (VOCs), polychlorinated biphenyls (PCBs), and other organics and inorganic compounds, will be developed by leveraging resources in cooperation with industry and interagency programs.

NONE

1995-06-01T23:59:59.000Z

228

Electrochemical process for the preparation of nitrogen fertilizers  

DOE Patents [OSTI]

The present invention provides methods and apparatus for the preparation of nitrogen fertilizers including ammonium nitrate, urea, urea-ammonium nitrate, and/or ammonia, at low temperature and pressure, preferably at ambient temperature and pressure, utilizing a source of carbon, a source of nitrogen, and/or a source of hydrogen or hydrogen equivalent. Implementing an electrolyte serving as ionic charge carrier, (1) ammonium nitrate is produced via the reduction of a nitrogen source at the cathode and the oxidation of a nitrogen source at the anode; (2) urea or its isomers are produced via the simultaneous cathodic reduction of a carbon source and a nitrogen source; (3) ammonia is produced via the reduction of nitrogen source at the cathode and the oxidation of a hydrogen source or a hydrogen equivalent such as carbon monoxide or a mixture of carbon monoxide and hydrogen at the anode; and (4) urea-ammonium nitrate is produced via the simultaneous cathodic reduction of a carbon source and a nitrogen source, and anodic oxidation of a nitrogen source. The electrolyte can be aqueous, non-aqueous, or solid.

Aulich, Ted R. (Grand Forks, ND); Olson, Edwin S. (Grand Forks, ND); Jiang, Junhua (Grand Forks, ND)

2012-04-10T23:59:59.000Z

229

Electric current-producing device having sulfone-based electrolyte  

DOE Patents [OSTI]

Electrolytic solvents and applications of such solvents including electric current-producing devices. For example, a solvent can include a sulfone compound of R1--SO2--R2, with R1 being an alkyl group and R2 a partially oxygenated alkyl group, to exhibit high chemical and thermal stability and high oxidation resistance. For another example, a battery can include, between an anode and a cathode, an electrolyte which includes ionic electrolyte salts and a non-aqueous electrolyte solvent which includes a non-symmetrical, non-cyclic sulfone. The sulfone has a formula of R1--SO2--R2, wherein R1 is a linear or branched alkyl or partially or fully fluorinated linear or branched alkyl group having 1 to 7 carbon atoms, and R2 is a linear or branched or partially or fully fluorinated linear or branched oxygen containing alkyl group having 1 to 7 carbon atoms. The electrolyte can include an electrolyte co-solvent and an electrolyte additive for protective layer formation.

Angell, Charles Austen (Mesa, AZ); Sun, Xiao-Guang (Tempe, AZ)

2010-11-16T23:59:59.000Z

230

Advanced hydraulic fracturing methods to create in situ reactive barriers  

SciTech Connect (OSTI)

Many contaminated areas consist of a source area and a plume. In the source area, the contaminant moves vertically downward from a release point through the vadose zone to an underlying saturated region. Where contaminants are organic liquids, NAPL may accumulate on the water table, or it may continue to migrate downward through the saturated region. Early developments of permeable barrier technology have focused on intercepting horizontally moving plumes with vertical structures, such as trenches, filled with reactive material capable of immobilizing or degrading dissolved contaminants. This focus resulted in part from a need to economically treat the potentially large volumes of contaminated water in a plume, and in part from the availability of construction technology to create the vertical structures that could house reactive compounds. Contaminant source areas, however, have thus far remained largely excluded from the application of permeable barrier technology. One reason for this is the lack of conventional construction methods for creating suitable horizontal structures that would place reactive materials in the path of downward-moving contaminants. Methods of hydraulic fracturing have been widely used to create flat-lying to gently dipping layers of granular material in unconsolidated sediments. Most applications thus far have involved filling fractures with coarse-grained sand to create permeable layers that will increase the discharge of wells recovering contaminated water or vapor. However, it is possible to fill fractures with other compounds that alter the chemical composition of the subsurface. One early application involved development and field testing micro-encapsulated sodium percarbonate, a solid compound that releases oxygen and can create aerobic conditions suitable for biodegradation in the subsurface for several months.

Murdoch, L. [FRx Inc., Cincinnati, OH (United States); [Clemson Univ., SC (United States); Siegrist, B. [Oak Ridge National Lab., TN (United States); Vesper, S. [Univ. of Cincinnati, OH (United States)] [and others

1997-12-31T23:59:59.000Z

231

Colloquium: Majorana Fermions in nuclear, particle and solid-state physics  

E-Print Network [OSTI]

Ettore Majorana (1906-1938) disappeared while traveling by ship from Palermo to Naples in 1938. His fate has never been fully resolved and several articles have been written that explore the mystery itself. His demise intrigues us still today because of his seminal work, published the previous year, that established symmetric solutions to the Dirac equation that describe a fermionic particle that is its own anti-particle. This work has long had a significant impact in neutrino physics, where this fundamental question regarding the particle remains unanswered. But the formalism he developed has found many uses as there are now a number of candidate spin-1/2 neutral particles that may be truly neutral with no quantum number to distinguish them from their anti-particles. If such particles exist, they will influence many areas of nuclear and particle physics. Most notably the process of neutrinoless double beta decay can only exist if neutrinos are massive Majorana particles. Hence, many efforts to search for this process are underway. Majorana's influence doesn't stop with particle physics, however, even though that was his original consideration. The equations he derived also arise in solid state physics where they describe electronic states in materials with superconducting order. Of special interest here is the class of solutions of the Majorana equation in one and two spatial dimensions at exactly zero energy. These Majorana zero modes are endowed with some remarkable physical properties that may lead to advances in quantum computing and, in fact, there is evidence that they have been experimentally observed. This review first summarizes the basics of Majorana's theory and its implications. It then provides an overview of the rich experimental programs trying to find a fermion that is its own anti-particle in nuclear, particle, and solid state physics.

S. R. Elliott; M. Franz

2014-12-01T23:59:59.000Z

232

Electrochemical hydrogen Storage Systems  

SciTech Connect (OSTI)

As the global need for energy increases, scientists and engineers have found a possible solution by using hydrogen to power our world. Although hydrogen can be combusted as a fuel, it is considered an energy carrier for use in fuel cells wherein it is consumed (oxidized) without the production of greenhouse gases and produces electrical energy with high efficiency. Chemical storage of hydrogen involves release of hydrogen in a controlled manner from materials in which the hydrogen is covalently bound. Sodium borohydride and aminoborane are two materials given consideration as chemical hydrogen storage materials by the US Department of Energy. A very significant barrier to adoption of these materials as hydrogen carriers is their regeneration from 'spent fuel,' i.e., the material remaining after discharge of hydrogen. The U.S. Department of Energy (DOE) formed a Center of Excellence for Chemical Hydrogen Storage, and this work stems from that project. The DOE has identified boron hydrides as being the main compounds of interest as hydrogen storage materials. The various boron hydrides are then oxidized to release their hydrogen, thereby forming a 'spent fuel' in the form of a lower boron hydride or even a boron oxide. The ultimate goal of this project is to take the oxidized boron hydrides as the spent fuel and hydrogenate them back to their original form so they can be used again as a fuel. Thus this research is essentially a boron hydride recycling project. In this report, research directed at regeneration of sodium borohydride and aminoborane is described. For sodium borohydride, electrochemical reduction of boric acid and sodium metaborate (representing spent fuel) in alkaline, aqueous solution has been investigated. Similarly to literature reports (primarily patents), a variety of cathode materials were tried in these experiments. Additionally, approaches directed at overcoming electrostatic repulsion of borate anion from the cathode, not described in the previous literature for electrochemical reduction of spent fuels, have been attempted. A quantitative analytical method for measuring the concentration of sodium borohydride in alkaline aqueous solution has been developed as part of this work and is described herein. Finally, findings from stability tests for sodium borohydride in aqueous solutions of several different compositions are reported. For aminoborane, other research institutes have developed regeneration schemes involving tributyltin hydride. In this report, electrochemical reduction experiments attempting to regenerate tributyltin hydride from tributyltin chloride (a representative by-product of the regeneration scheme) are described. These experiments were performed in the non-aqueous solvents acetonitrile and 1,2-dimethoxyethane. A non-aqueous reference electrode for electrolysis experiments in acetonitrile was developed and is described. One class of boron hydrides, called polyhedral boranes, became of interest to the DOE due to their ability to contain a sufficient amount of hydrogen to meet program goals and because of their physical and chemical safety attributes. Unfortunately, the research performed here has shown that polyhedral boranes do not react in such a way as to allow enough hydrogen to be released, nor do they appear to undergo hydrogenation from the spent fuel form back to the original hydride. After the polyhedral boranes were investigated, the project goals remained the same but the hydrogen storage material was switched by the DOE to ammonia borane. Ammonia borane was found to undergo an irreversible hydrogen release process, so a direct hydrogenation was not able to occur. To achieve the hydrogenation of the spent ammonia borane fuel, an indirect hydrogenation reaction is possible by using compounds called organotin hydrides. In this process, the organotin hydrides will hydrogenate the spent ammonia borane fuel at the cost of their own oxidation, which forms organotin halides. To enable a closed-loop cycle, our task was then to be able to hydrogenate the organotin halides back to th

Dr. Digby Macdonald

2010-08-09T23:59:59.000Z

233

Purdue Hydrogen Systems Laboratory  

SciTech Connect (OSTI)

The Hydrogen Systems Laboratory in a unique partnership between Purdue University's main campus in West Lafayette and the Calumet campus was established and its capabilities were enhanced towards technology demonstrators. The laboratory engaged in basic research in hydrogen production and storage and initiated engineering systems research with performance goals established as per the USDOE Hydrogen, Fuel Cells, and Infrastructure Technologies Program. In the chemical storage and recycling part of the project, we worked towards maximum recycling yield via novel chemical selection and novel recycling pathways. With the basic potential of a large hydrogen yield from AB, we used it as an example chemical but have also discovered its limitations. Further, we discovered alternate storage chemicals that appear to have advantages over AB. We improved the slurry hydrolysis approach by using advanced slurry/solution mixing techniques. We demonstrated vehicle scale aqueous and non-aqueous slurry reactors to address various engineering issues in on-board chemical hydrogen storage systems. We measured the thermal properties of raw and spent AB. Further, we conducted experiments to determine reaction mechanisms and kinetics of hydrothermolysis in hydride-rich solutions and slurries. We also developed a continuous flow reactor and a laboratory scale fuel cell power generation system. The biological hydrogen production work summarized as Task 4.0 below, included investigating optimal hydrogen production cultures for different substrates, reducing the water content in the substrate, and integrating results from vacuum tube solar collector based pre and post processing tests into an enhanced energy system model. An automated testing device was used to finalize optimal hydrogen production conditions using statistical procedures. A 3 L commercial fermentor (New Brunswick, BioFlo 115) was used to finalize testing of larger samples and to consider issues related to scale up. Efforts continued to explore existing catalytic methods involving nano catalysts for capture of CO2 from the fermentation process.

Jay P Gore; Robert Kramer; Timothee L Pourpoint; P. V. Ramachandran; Arvind Varma; Yuan Zheng

2011-12-28T23:59:59.000Z

234

DEVELOPMENT OF ANALYTICAL METHODS FOR DETERMINING SUPPRESSOR CONCENTRATION IN THE MCU NEXT GENERATION SOLVENT (NGS)  

SciTech Connect (OSTI)

Savannah River National Laboratory (SRNL) was tasked with identifying and developing at least one, but preferably two methods for quantifying the suppressor in the Next Generation Solvent (NGS) system. The suppressor is a guanidine derivative, N,N',N"-tris(3,7-dimethyloctyl)guanidine (TiDG). A list of 10 possible methods was generated, and screening experiments were performed for 8 of the 10 methods. After completion of the screening experiments, the non-aqueous acid-base titration was determined to be the most promising, and was selected for further development as the primary method. {sup 1}H NMR also showed promising results from the screening experiments, and this method was selected for further development as the secondary method. Other methods, including {sup 36}Cl radiocounting and ion chromatography, also showed promise; however, due to the similarity to the primary method (titration) and the inability to differentiate between TiDG and TOA (tri-n-ocytlamine) in the blended solvent, {sup 1}H NMR was selected over these methods. Analysis of radioactive samples obtained from real waste ESS (extraction, scrub, strip) testing using the titration method showed good results. Based on these results, the titration method was selected as the method of choice for TiDG measurement. {sup 1}H NMR has been selected as the secondary (back-up) method, and additional work is planned to further develop this method and to verify the method using radioactive samples. Procedures for analyzing radioactive samples of both pure NGS and blended solvent were developed and issued for the both methods.

Taylor-Pashow, K.; Fondeur, F.; White, T.; Diprete, D.; Milliken, C.

2013-07-31T23:59:59.000Z

235

Novel Nonflammable Electrolytes for Secondary Magnesium Batteries and High Voltage Electrolytes for Electrochemcial Supercapacitors  

SciTech Connect (OSTI)

Magnesium has been used successfully in primary batteries, but its use in rechargeable cells has been stymied by the lack of suitable non-aqueous electrolyte that can conduct Mg+2 species, combined with poor stripping and plating properties. The development of a suitable cathode material for rechargeable magnesium batteries has also been a roadblock, but a nonflammable electrolyte is key. Likewise, the development of safe high voltage electrochemical supercapaitors has been stymied by the use of flammable solvents in the liquid electrolyte; to wit, acetonitrile. The purpose of the research conducted in this effort was to identify useful compositions of magnesium salts and polyphosphate solvents that would enable magnesium ions to be cycled within a secondary battery design. The polyphosphate solvents would provide the solvent for the magnesium salts while preventing the electrolyte from being flammable. This would enable these novel electrolytes to be considered as an alternative to THF-based electrolytes. In addition, we explored several of these solvents together with lithium slats for use as high voltage electrolytes for carbon-based electrochemical supercapacitors. The research was successful in that: 1) Magnesium imide dissolved in a phosphate ester solvent that contains a halogented phosphate ester appears to be the preferred electrolyte for a rechargeable Mg cell. 2) A combination of B-doped CNTs and vanadium phosphate appear to be the cathode of choice for a rechargeable Mg cell by virtue of higher voltage and better reversibility. 3) Magnesium alloys appear to perform better than pure magnesium when used in combination with the novel polyphosphate electrolytes. Also, this effort has established that Phoenix Innovationâ??s family of phosphonate/phosphate electrolytes together with specific lithium slats can be used in supercapacitor systems at voltages of greater than 10V.

Dr. Brian Dixon

2008-12-30T23:59:59.000Z

236

Remediation of a fractured clay soil contaminated with gasoline containing MTBE  

SciTech Connect (OSTI)

Gasoline and other light non-aqueous phase liquids (LNAPLs) released into fractured clay soils initially move by advection of the LNAPL through the fractures. Once advective movement of the LNAPL ceases, dissolution of the gasoline components into the pore water and diffusion into the intact blocks of clay becomes an important transport process. The aqueous-phase flux of each compound in the mixture depends in large part upon its aqueous solubility. For example, a low-solubility compound like isooctane remains primarily in the fracture in the LNAPL. A high-solubility compound, like methyl-tert-butyl ether (MTBE), dissolves readily and may move almost entirely into the clay matrix. The distribution of compounds between the matrix and the fractures will have an important impact on the rate at which the gasoline contaminated soil can be remediated. In this context, the presence of soluble additives like MTBE can significantly impact the risk and remediation time for the, soil. Beginning in 1993 a field study to examine the applicability of air flushing for remediation of low-permeability soils was sponsored by API. The study focused on a variety of soil vapor extraction (SVE) and in situ air sparging (IAS) approaches for mass removal and risk reduction. The source of gasoline contamination in this study was a release of 50 liters of a mixture containing 14 gasoline hydrocarbons ranging from pentane to naphthalene, and including MTBE. The mixture was released into the shallow subsurface and allowed to redistribute for 10 months prior to air flushing startup. Numerical modeling indicated that essentially all of the MTBE should have dissolved into the matrix. In contrast, essentially all of the isooctane should have remained in the LNAPL in the fractures.

Johnson, R.L.; Grady, D.E. [Oregon Graduate Institute, Portland, OR (United States); Walden, T. [BP Oil Europe, Brussels (Belgium)

1997-12-31T23:59:59.000Z

237

Environmental assessment for the Hoe Creek underground, Coal Gasification Test Site Remediation, Campbell County, Wyoming  

SciTech Connect (OSTI)

The U.S. Department of Energy (DOE) has prepared this EA to assess environmental and human health Issues and to determine potential impacts associated with the proposed Hoe Creek Underground Coal Gasification Test Site Remediation that would be performed at the Hoe Creek site in Campbell County, Wyoming. The Hoe Creek site is located south-southwest of the town of Gillette, Wyoming, and encompasses 71 acres of public land under the stewardship of the Bureau of Land Management. The proposed action identified in the EA is for the DOE to perform air sparging with bioremediation at the Hoe Creek site to remove contaminants resulting from underground coal gasification (UCG) experiments performed there by the DOE in the late 1970s. The proposed action would involve drilling additional wells at two of the UCG test sites to apply oxygen or hydrogen peroxide to the subsurface to volatilize benzene dissolved in the groundwater and enhance bioremediation of non-aqueous phase liquids present in the subsurface. Other alternatives considered are site excavation to remove contaminants, continuation of the annual pump and treat actions that have been used at the site over the last ten years to limit contaminant migration, and the no action alternative. Issues examined in detail in the EA are air quality, geology, human health and safety, noise, soils, solid and hazardous waste, threatened and endangered species, vegetation, water resources, and wildlife. Details of mitigative measures that could be used to limit any detrimental effects resulting from the proposed action or any of the alternatives are discussed, and information on anticipated effects identified by other government agencies is provided.

NONE

1997-10-01T23:59:59.000Z

238

Synthesis and application of new polymer bound catalysts  

SciTech Connect (OSTI)

Nitric acid has been shown to be a weak acid in acetonitrile. It is conceivable that a nitrate salt of a weakly Lewis acidic cation could furnish a ''naked'' nitrate anion as a basic catalyst in a variety of reactions in non-aqueous solvents. Such a nitrate salt could also be bound to a polymeric support via the cation, thereby allowing for reclamation and recycling of the nitrate ion. This subject is dealt with in Chapter 2, wherein my contributions consisted of performing all the reactions with the polymer supported catalyst and carrying out the experiments necessary to shed light on the reaction mechanisms. Chapter 3 contains a description of the structure and catalytic properties of an azidoproazaphosphatrane. This compound is an air-stable versatile catalyst that has proven useful not only homogeneously, but also when bound to a solid support. The synthesis of a polymer bound proazaphosphatrane containing a trivalent phosphorus is presented in Chapter 4. Such a compound has been sought after by our group for a number of years. Not only does the synthesis I have accomplished for it allow for easier separation of proazaphosphatrane catalysts from reaction mixtures, but recycling of the base is made much simpler. Proazaphosphatranes are useful homogeneous catalysts that activate atoms in other reagents, thus enhancing their reactivity. The next chapters deal with two such reactions with aldehydes and ketones, namely silylcyanations with trialkylsilylcyanides (Chapters 5 and 6) and reductions with poly(methylhydrosiloxane), in Chapter 7. In Chapter 5, Zhigang Wang performed the initial optimization and scoping of the reaction, while repetitions of the scoping experiments for reproducibility, determination of diastereomeric ratios, and experiments aimed at elucidating aspects of the mechanism were performed by me. The proazaphosphatrane coordinates to the silicon atom in both cases, thereby allowing the aforementioned reactions to proceed under much milder conditions. Proazaphosphatranes are also effective Broensted-Lowry bases. This is illustrated in Chapter 8 wherein a wide variety of conjugate addition reactions are catalyzed by proazaphosphatranes. In that chapter, repetitions of the nitroalkane addition reactions for reproducibility, improved spectral data for the products and comparisons of literature yields of all reactions were performed by the author.

Fetterly, Brandon Michael

2005-08-01T23:59:59.000Z

239

DOE-EMSP Final Report: Characterization of Changes in Colloid and DNAPL Affecting Surface Chemistry and Remediation  

SciTech Connect (OSTI)

The waste disposal to the M-area basin and A-14 outfall at the Savannah River Department of Energy facility in Aiken SC (USA) included a wide variety of inorganic aqueous flows and organic solvents in the form of dense non-aqueous phase liquids (DNAPL). The DNAPL has migrated through the subsurface resulting in widespread groundwater contamination. The goal of this research was to identify and quantify processes that could have affected the migration and remediation of the DNAPL in the subsurface. It was hypothesized that the variety of waste disposed at this site could have altered the mineral, microbial and DNAPL properties at this site relative to other DNAPL sites. The DNAPL was determined to have a very low interfacial tension and is suspected to be distributed in fine grained media, thereby reducing the effectiveness of soil vapor extraction remediation efforts. Although the DNAPL is primarily comprised of tetrachloroethene and trichloroethane, it also contains organic acids and several heavy metals. Experimental results suggest that iron from the aqueous and DNAPL phases undergoes precipitation and dechlorination reactions at the DNAPL-water interface, contributing to the low interfacial tension and acidity of the DNAPL. Biological activity in the contaminated region can also contribute to the low interfacial tension. PCE degrading bacteria produce biosurfactants and adhere to the DNAPL-water interface when stressed by high tetrachloroethene or low dissolved oxygen concentrations. The presence of iron can reduce the interfacial tension by nearly an order of magnitude, while the PCE degraders reduced the interfacial tension by nearly 50%. Abiotic changes in the mineral characteristics were not found to be substantially different between contaminated and background samples. The research completed here begins to shed some insight into the complexities of DNAPL fate and migration at sites where co-disposal of many different waste products occurred. Quantifying the low interfacial tension of the SRS DNAPL helps to formulate a new conceptual picture of the subsurface DNAPL migration and provides an explanation of the limited effectiveness of remediation efforts. Alternative designs for remediation that are more effective for sites with DNAPL in fine grained media are required.

Susan E. Powers; Stefan J. Grimberg; Miles Denham

2007-02-07T23:59:59.000Z

240

Radioactive Iodine and Krypton Control for Nuclear Fuel Reprocessing Facilities  

SciTech Connect (OSTI)

Nuclear fission results in the production of fission products and activation products, some of which tend to be volatile during used fuel reprocessing. These can evolve in volatile species in the reprocessing facility off-gas streams, depending on the separations and reprocessing technologies that are used. Radionuclides that have been identified as “volatile radionuclides” are noble gases (most notably isotopes of Kr and Xe); 3H; 14C; and 129I. Radionuclides that tend to form volatile species that evolve into reprocessing facility off-gas systems are more challenging to efficiently control compared to radionuclides that tend to stay in solid or liquid phases. Future used fuel reprocessing facilities in the United States can require efficient capture of some volatile radionuclides in their off-gas streams to meet regulatory emission requirements. In aqueous reprocessing, these radionuclides are most commonly expected to evolve into off-gas streams in tritiated water [3H2O (T2O) and 3HHO (THO)], radioactive CO2, noble gases, and gaseous HI, I2, or volatile organic iodides. The fate and speciation of these radionuclides from a non-aqueous fuel reprocessing facility is less well known at this time, but active investigations are in progress. An Off-Gas Sigma Team was formed in late FY 2009 to integrate and coordinate the Fuel Cycle Research and Development (FCR&D) activities directed towards the capture and sequestration of the these volatile radionuclides (Jubin 2012a). The Sigma Team concept was envisioned to bring together multidisciplinary teams from across the DOE complex that would work collaboratively to solve the technical challenges and to develop the scientific basis for the capture and immobilization technologies such that the sum of the efforts was greater than the individual parts. The Laboratories currently participating in this effort are Argonne National Laboratory (ANL), Idaho National Laboratory (INL), Oak Ridge National Laboratory (ORNL), Pacific Northwest National Laboratory (PNNL), and Sandia National Laboratories (SNL). This article focuses on control of volatile radionuclides that evolve during aqueous reprocessing of UNF. In particular, most of the work by the Off-gas Sigma Team has focused on the capture and sequestration of 129I and 85Kr, mainly because, as discussed below, control of 129I can require high efficiencies to meet regulatory requirements, and control of 85Kr using cryogenic processing, which has been the technology demonstrated and used commercially to date, can add considerable cost to a reprocessing facility.

Soelberg, Nicolas R. [Idaho National Laboratory, Idaho Falls, ID (United States); Garn, Troy [Idaho National Laboratory, Idaho Falls, ID (United States); Greenhalgh, Mitchell [Idaho National Laboratory, Idaho Falls, ID (United States); Law, Jack [Idaho National Laboratory, Idaho Falls, ID (United States); Jubin, Robert T. [Oak Ridge National Laboratory, Oak Ridge, TN (United States); Strachan, Denis M. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Thallapally, Praveen K. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

2013-07-22T23:59:59.000Z

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241

Zone Freezing Study for Pyrochemical Process Waste Minimization  

SciTech Connect (OSTI)

Pyroprocessing technology is a non-aqueous separation process for treatment of used nuclear fuel. At the heart of pyroprocessing lies the electrorefiner, which electrochemically dissolves uranium from the used fuel at the anode and deposits it onto a cathode. During this operation, sodium, transuranics, and fission product chlorides accumulate in the electrolyte salt (LiCl-KCl). These contaminates change the characteristics of the salt overtime and as a result, large volumes of contaminated salt are being removed, reprocessed and stored as radioactive waste. To reduce the storage volumes and improve recycling process for cost minimization, a salt purification method called zone freezing has been proposed at Korea Atomic Energy Research Institute (KAERI). Zone freezing is melt crystallization process similar to the vertical Bridgeman method. In this process, the eutectic salt is slowly cooled axially from top to bottom. As solidification occurs, the fission products are rejected from the solid interface and forced into the liquid phase. The resulting product is a grown crystal with the bulk of the fission products near the bottom of the salt ingot, where they can be easily be sectioned and removed. Despite successful feasibility report from KAERI on this process, there were many unexplored parameters to help understanding and improving its operational routines. Thus, this becomes the main motivation of this proposed study. The majority of this work has been focused on the CsCl-LiCl-KCl ternary salt. CeCl3-LiCl-KCl was also investigated to check whether or not this process is feasible for the trivalent species—surrogate for rare-earths and transuranics. For the main part of the work, several parameters were varied, they are: (1) the retort advancement rate—1.8, 3.2, and 5.0 mm/hr, (2) the crucible lid configurations—lid versus no-lid, (3) the amount or size of mixture—50 and 400 g, (4) the composition of CsCl in the salt—1, 3, and 5 wt%, and (5) the temperature differences between the high and low furnace zones—200 and 300 ?C. During each experiment, the temperatures at selected locations around the crucible were measured and recorded to provide temperature profiles. Following each experiment, samples were collected and elemental analysis was done to determine the composition of iii the salt. Several models—non-mixed, well-mixed, Favier, and hybrid—were explored to describe the zone freezing process. For CsCl-LiCl-KCl system, experimental results indicate that through this process up to 90% of the used salt can be recycled, effectively reducing waste volume by a factor of ten. The optimal configuration was found to be a 5.0 mm/hr rate with a lid configuration and a ?T of 200°C. The larger 400 g mixtures had recycle percentages similar to the 50 g mixtures; however, the throughput per time was greater for the 400 g case. As a result, the 400 g case is recommended. For the CeCl3-LiCl-KCl system, the result implies that it is possible to use this process to separate the rare-earth and transuranics chlorides. Different models were applied to only CsCl ternary system. The best fit model was the hybrid model as a result of a solute transport transition from non- mixed to well-mixed throughout the growing process.

Ammon Williams

2012-05-01T23:59:59.000Z

242

Theory, Investigation and Stability of Cathode Electrocatalytic Activity  

SciTech Connect (OSTI)

The main objective of this project is to systematically characterize the surface composition, morphology, and electro-catalytic properties of catalysts coated on LSCF, aiming to establish the scientific basis for rational design of high-performance cathodes by combining a porous backbone (such as LSCF) with a thin catalyst coating. The understanding gained will help us to optimize the composition and morphology of the catalyst layer and microstructure of the LSCF backbone for better performance. More specifically, the technical objectives include: (1) to characterize the surface composition, morphology, and electro-catalytic properties of catalysts coated on LSCF; (2) to characterize the microscopic details and stability of the LSCF-catalyst (e.g., LSM) interfaces; (3) to establish the scientific basis for rational design of high-performance cathodes by combining a porous backbone (such as LSCF) with a thin catalyst coating; and (4) to demonstrate that the performance and stability of porous LSCF cathodes can be enhanced by the application of a thin-film coating of LSM through a solution infiltration process in small homemade button cells and in commercially available cells of larger dimension. We have successfully developed dense, conformal LSM films with desired structure, composition, morphology, and thickness on the LSCF surfaces by two different infiltration processes: a non-aqueous and a water-based sol-gel process. It is demonstrated that the activity and stability of LSCF cathodes can be improved by the introduction of a thin-film LSM coating through an infiltration process. Surface and interface of the LSM-coated LSCF cathode were systematically characterized using advanced microscopy and spectroscopy techniques. TEM observation suggests that a layer of La and Sr oxide was formed on LSCF surfaces after annealing. With LSM infiltration, in contrast, we no longer observe such La/Sr oxide layer on the LSM-coated LSCF samples after annealing under similar conditions. This was also confirmed by x-ray analyses. For example, soft x-ray XANES data reveal that Co cations displace the Mn cations as being more favored to be reduced. Variations in the Sr-O in the annealed LSCF Fourier-transformed (FT) EXAFS suggest that some Sr segregation is occurring, but is not present in the annealed LSM-infiltrated LSCF cathode materials. Further, a surface enhanced Raman technique was also developed into to probe and map LSM and LSCF phase on underlying YSZ substrate, enabling us to capture important chemical information of cathode surfaces under practical operating conditions. Electrochemical models for the design of test cells and understanding of mechanism have been developed for the exploration of fundamental properties of electrode materials. Novel catalyst coatings through particle depositions (SDC, SSC, and LCC) or continuous thin films (PSM and PSCM) were successfully developed to improve the activity and stability of LSCF cathodes. Finally, we have demonstrated enhanced activity and stability of LSCF cathodes over longer periods of time in homemade and commercially available cells by an optimized LSM infiltration process. Microstructure examination of the tested cells did not show obvious differences between blank and infiltrated cells, suggesting that the infiltrated LSM may form a coherent film on the LSCF cathodes. There was no significant change in the morphology or microstructure of the LSCF cathode due to the structural similarity of LSCF and LSM. Raman analysis of the tested cells indicated small peaks emerging on the blank cells that correspond to trace amounts of secondary phase formation during operation (e.g., CoO{sub x}). The formation of this secondary phase might be attributed to performance degradation. In contrast, there was no such secondary phase observed in the LSM infiltrated cells, indicating that the LSM modification staved off secondary phase formation and thus improved the stability.

Ding, Dong; Liu, Mingfei; Lai, Samson; Blinn, Kevin; Liu, Meilin

2012-09-30T23:59:59.000Z

243

Using Acid Number as a Leading Indicator of Refrigeration and Air Conditioning System Performance  

SciTech Connect (OSTI)

This report summarizes a literature review to assess the acidity characteristics of the older mineral oil and newer polyolester (POE) refrigeration systems as well as to evaluate acid measuring techniques used in other non-aqueous systems which may be applicable for refrigeration systems. Failure in the older chlorofluorocarbon/hydrochlorofluorocarbon (CFC/HCFC) / mineral oil systems was primarily due to thermal degradation of the refrigerant which resulted in the formation of hydrochloric and hydrofluoric acids. These are strong mineral acids, which can, over time, severely corrode the system metals and lead to the formation of copper plating on iron surfaces. The oil lubricants used in the older systems were relatively stable and were not prone to hydrolytic degradation due to the low solubility of water in oil. The refrigerants in the newer hydrofluorocarbon (HFC)/POE systems are much more thermally stable than the older CFC/HCFC refrigerants and mineral acid formation is negligible. However, acidity is produced in the new systems by hydrolytic decomposition of the POE lubricants with water to produce the parent organic acids and alcohols used to prepare the POE. The individual acids can therefore vary but they are generally C5 to C9 carboxylic acids. Organic acids are much weaker and far less corrosive to metals than the mineral acids from the older systems but they can, over long time periods, react with metals to form carboxylic metal salts. The salts tend to accumulate in narrow areas such as capillary tubes, particularly if residual hydrocarbon processing chemicals are present in the system, which can lead to plugging. The rate of acid production from POEs varies on a number of factors including chemical structure, moisture levels, temperature, acid concentration and metals. The hydrolysis rate of reaction can be reduced by using driers to reduce the free water concentration and by using scavenging chemicals which react with the system acids. Total acid number (TAN), which includes both mineral acids and organic acids, is therefore a useful indicator which can be used to monitor the condition of the system in order to perform remedial maintenance, when required, to prevent system failure. The critical TAN value is the acid level at which remedial action should be taken to prevent the onset of rapid acid formation which can result in system failure. The level of 0.05 mg KOH/g of oil was established for CFC/mineral oil systems based on analysis of 700 used lubricants from operating systems and failed units. There is no consensus within the refrigeration industry as to the critical TAN value for HFC/POE systems, however, the value will be higher than the CFC/mineral oil systems critical TAN value because of the much weaker organic acids produced from POE. A similar study of used POE lubricants should be performed to establish a critical TAN limit for POE systems. Titrimetric analysis per ASTM procedures is the most commonly used method to determine TAN values in lubricants in the refrigeration industry and other industries dealing with lubricating oils. For field measurements, acid test kits are often used since they provide rapid, semi-quantitative TAN results.

Dennis Cartlidge; Hans Schellhase

2003-07-31T23:59:59.000Z

244

A Science-Based Understanding of Cermet Processing.  

SciTech Connect (OSTI)

AbstractThis report is a summary of the work completed in FY01 for science-based characterization of the processes used to fabricate 1) cermet vias in source feedthrus using slurry and paste-filling techniques and 2) cermet powder for dry pressing. Common defects found in cermet vias were characterized based on the ability of subsequent processing techniques (isopressing and firing) to remove the defects. Non-aqueous spray drying and mist granulation techniques were explored as alternative methods of creating CND50, the powder commonly used for dry pressed parts. Compaction and flow characteristics of these techniques were analyzed and compared to standard dry-ball-milled CND50. Due to processing changes, changes in microstructure can occur. A microstructure characterization technique was developed to numerically describe cermet microstructure. Machining and electrical properties of dry pressed parts were also analyzed and related to microstructure using this analytical technique.3 Executive SummaryThis report outlines accomplishments in the science-based understanding of cermet processing up to fiscal year 2002 for Sandia National Laboratories. The three main areas of work are centered on 1) increasing production yields of slurry-filled cermets, 2) evaluating the viability of high-solids-loading pastes for the same cermet components, and 3) optimizing cermet powder used in pressing processes (CND50). An additional development that was created as a result of the effort to fully understand the impacts of alternative processing techniques is the use of analytical methods to relate microstructure to physical properties. Recommendations are suggested at the end of this report. Summaries of these four efforts are as follows:1.Increase Production Yields of Slurry-Filled Cermet Vias Finalized slurry filling criteria were determined based on three designs of experiments where the following factors were analyzed: vacuum time, solids loading, pressure drop across the filter paper, slurry injection rate, via prewetting, slurry injection angle, filter paper prewetting, and slurry mixing time. Many of these factors did not have an influence on defect formation. In order of decreasing importance, critical factors for defect formation by slurry filling are vacuum time (20 sec. optimal), slurry solids loading (20.0 g of cermet with 13.00 g of DGBEA solvent (21.2 vol%)), filling with the pipette in a vertical position, and faster injection rates (~765 l/s) as preferable to slower. No further recommendations for improvement to this process can be suggested. All findings of the slurry filling process have been transferred to CeramTec, the supplier. Paste filling methods appear to show more promise of increasing production yields. The types of flaws commonly found in slurry-filled vias were identified and followed throughout the entire source feedthru process. In general, all sizes of cracks healed during isopressing and firing steps. Additionally, small to medium sized voids (less than 1/3 the via diameter) can be healed. Porosity will usually lead to via necking, which may cause the part to be out of specification. Large voids (greater 4 than 1/3 of the diameter) and partial fills are not healed or produce significant necking. 2.Viability of High-Solids-Loading-Cermet Paste for Filling Source Feedthru ViaThe paste-filling process is easy to implement and easier to use. The high solids loading (>40 vol %) reduces the incidence of drying defects, which are seen in slurry filled (~23 vol %) vias. Additionally, the way in which the vias are filled (the paste is pushed from entrance to exit, displacing air as the paste front progresses), reduces the chance of entrapped voids, which are common in the slurry filling process. From the fair number of samples already filled, the likelihood of this process being a viable and reliable process is very good. Issues of concern for the paste process, as with any new process, are any problems that may arise in subsequent manufacturing stages of the neutron tube that may be affected by subtle changes in

Cesarano, Joseph; Roach, Robert Allen; Kilgo, Alice C.; Susan, Donald F.; Van Ornum, David J.; Stuecker, John N.

2006-04-01T23:59:59.000Z

245

Alternative (Potentially Green) Separations Media: Aqueous Biphasic and Related Systems âÂ?Â? Extending the Frontier Final Report For Period September 1, 2002 âÂ?Â? January 31, 2007  

SciTech Connect (OSTI)

Through the current DoE-BES funding, we have extended our fundamental understanding of the critical phase separation of aqueous polymer solutions at the molecular level, and have developed a similar understanding of their application as novel solvent systems. Our principal aims included mode of delivery of the aqueous biphasic system (ABS) solvent system and the application of this system to problems of reactive extraction. In the former case we have developed novel solid phase analogues, in the form of cross-linked polyethylene glycol hydrogels, and in the latter case we have examined the role that ABS might play in reaction engineering, with a view to greener, simpler, and safer processes. We have also developed a new salt/salt ABS and have extended our understanding of this system as well. The major outcomes are as follows: (1) Through the use of variable temperature phase diagrams, coupled with differential scanning calorimetry (DSC) measurements of the phases, a better understanding of the thermodynamics of phase formation was obtained. Evidence to the existence and role of an upper critical solution temperature (UCST) or lower critical solution temperature (LCST) (or both) in these systems was gained. With variable temperature solute partitioning, thermodynamic parameters were calculated, and inter-system comparisons were made. Through the use of Abraham's linear solvation energy regression (LSER) the solvent-solute properties of liquid/liquid ABS were examined. We have shown that ABS are indeed very tunable and LSERs have been used as a tool to compare these systems to traditional organic/water and other liquid/liquid systems. (2) We have successfully shown the development of novel reaction media for chemical synthesis and reaction; Aqueous Biphasic Reactive Extraction (ABRE). As a proof of concept, we have shown the synthesis of adipic acid from cyclohexene in an ABS, which represents an important development in the exploitation of this technology. Previous oxidations of this type have relied on the use of phase transfer catalysts, which are expensive to produce and difficult to recover. In this reaction the polyethylene glycol (PEG) phase seems to function simultaneously as the phase transfer catalyst, the reaction solvent, and to provide the reaction driving force. (3) PEG hydrogels may be used as probes for their macroscopic analogues by which the molecular events underlying the phase behavior of polymer-salt systems can be investigated. The properties of covalently cross-linked PEG hydrogels have been studied. It was demonstrated that these hydrogels could be thought of as analogous to polymer/salt ABS without phase separation. The salts examined cause collapse of the hydrogel, and there is a physical limit to the degree of collapse that can be achieved. In addition, salts bringing about significant collapse are only prevented from reaching this limit by the limits of their own solubility. This lead to our discovery that PEG will phase separate with KSCN at high enough concentration of polymer and salt. We have also successfully shown the development of an IL-PEG hydrogel as well as a Si-modified PEG hydrogel. We have also demonstrated for the first time that this cross-linked PEG matrix has been used to gel non-aqueous solvents. (4) The use of hydrophilic ionic liquids (ILs) in separation schemes has been accomplished via a 'salting out' technique using inorganic, kosmotropic salts that is applicable to many classes of these materials. We have begun to obtain a deeper knowledge about the role that each component plays in the process, including that of the ionic liquid cation and anion, the kosmotropic salt cation and anions, as well as the distribution of water in the system. This is allowing us to design separation systems with desired properties. In addition, temperature studies on these aqueous biphasic systems are revealing thermodynamic data for the first time, so that we can quantitate the importance of entropic and enthalpic contributions to the biphase-forming process.

Robin D. Rogers

2007-06-25T23:59:59.000Z