National Library of Energy BETA

Sample records for metric tons sulfur

  1. DOE Will Dispose of 34 Metric Tons of Plutonium by Turning it...

    National Nuclear Security Administration (NNSA)

    Will Dispose of 34 Metric Tons of Plutonium by Turning it into Fuel for Civilian Reactors | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People...

  2. DOE to Remove 200 Metric Tons of Highly Enriched Uranium from...

    Broader source: Energy.gov (indexed) [DOE]

    Administration (NNSA) will remove up to 200 metric tons (MT) of Highly Enriched Uranium (HEU), in the coming decades, from further use as fissile material in U.S. nuclear...

  3. Methane Production: In the United States cattle emit about 5.5 million metric tons of methane per year into the

    E-Print Network [OSTI]

    Toohey, Darin W.

    Methane Production: In the United States cattle emit about 5.5 million metric tons of methane per year into the atmosphere. o Accounts for 20% of methane emissions from human sources. Globally cattle produce about 80 million metric tons of methane annually. o Accounts for 28% of global methane emissions

  4. RARE EARTHS1 [Data in metric tons of rare-earth oxide (REO) content unless otherwise noted

    E-Print Network [OSTI]

    ) -- -- -- -- 20 Rare-earth metals, alloy 880 867 784 679 210 Cerium compounds 2,170 2,590 2,680 2,080 1,190 Mixed (monazite or various thorium materials) -- -- 1 61 23 Rare-earth metals, alloys 636 733 1,470 1,390 6128 RARE EARTHS1 [Data in metric tons of rare-earth oxide (REO) content unless otherwise noted

  5. (Data in metric tons unless otherwise noted) Domestic Production and Use: Indium was not recovered from ores in the United States in 2007. Indium-containing

    E-Print Network [OSTI]

    gallium diselenide (CIGS) solar cells require approximately 50 metric tons of indium to produce 1 gigawatt of solar power. Research was underway to develop a low-cost manufacturing process for flexible CIGS solar cells that would yield high productio

  6. (Data in metric tons of lithium content unless otherwise noted) Domestic Production and Use: The only commercially active lithium mine in the United States was a brine

    E-Print Network [OSTI]

    --United States: 2008 2009 2010 2011 2012 e Production W W W W W Imports for consumption 3,160 1,890 1,960 2,850 2 production capacity. Industry analysts and the major lithium producers expected worldwide consumption94 LITHIUM (Data in metric tons of lithium content unless otherwise noted) Domestic Production

  7. (Data in thousand metric tons of copper content unless otherwise noted) Domestic Production and Use: U.S. mine production of copper in 2013 increased by 4% to about 1.22 million tons,

    E-Print Network [OSTI]

    .9% and consumption was projected to remain essentially unchanged. U.S. mine production increased by about 4% in 2013 Production and Use: U.S. mine production of copper in 2013 increased by 4% to about 1.22 million tons of production--accounted for more than 99% of domestic mine production; copper also was recovered in Idaho

  8. Biogenic sulfur emissions in the SURE region

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.; Robinson, E.; Pack, M.R.

    1980-09-01

    The objective of this study was to estimate the magnitude of biogenic sulfur emissions from the northeastern United States - defined as the EPRI Sulfate Regional Experiment (SURE) study area. Initial laboratory efforts developed and validated a portable sulfur sampling system and a sensitive, gas chromatographic analytical detection system. Twenty-one separate sites were visited in 1977 to obtain a representative sulfur emission sampling of soil orders, suborders, and wetlands. The procedure determined the quantity of sulfur added to sulfur-free sweep air by the soil flux as the clean air was blown through the dynamic enclosure set over the selected sampling area. This study represents the first systematic sampling for biogenic sulfur over such a wide range of soils and such a large land area. The major impacts upon the measured sulfur flux were found to include soil orders, temperature, sunlight intensity, tidal effects along coastal areas. A mathematical model was developed for biogenic sulfur emissions which related these field variables to the mean seasonal and annual ambient temperatures regimes for each SURE grid and the percentage of each soil order within each grid. This model showed that at least 53,500 metric tons (MT) of biogenic sulfur are emitted from the SURE land surfaces and approximately 10,000 MT are emitted from the oceanic fraction of the SURE grids. This equates to a land sulfur flux of nearly 0.02 gram of sulfur per square meter per yr, or about 0.6% of the reported anthropogenic emissions withn the SURE study area. Based upon these data and the summertime Bermuda high clockwise circulation of maritime air across Florida and the Gulf Coast states northward through the SURE area, the total land biogenic sulfur emission contribution to the SURE area atmospheric sulfur burden might approach 1 to 2.5% of the anthropogenic.

  9. Sulfur-Free Selective Pulping 

    E-Print Network [OSTI]

    Dimmel, D. R.; Bozell, J. J.

    1994-01-01

    an increase in pulping rate and yields, which translates to less energy required per ton of product. Less sulfur means a simplified process, lower odor emissions, and a decrease requirement for bleaching chemicals, meaning less organics being discharged...

  10. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    tons)", "Sulfur dioxide (short tons)",3978753 "Nitrogen oxide (short tons)",2411564 "Carbon dioxide (thousand metric tons)",2172355 "Sulfur dioxide (lbsMWh)",2 "Nitrogen oxide...

  11. An Aerosol Condensation Model for Sulfur Trioxide

    SciTech Connect (OSTI)

    Grant, K E

    2008-02-07

    This document describes a model for condensation of sulfuric acid aerosol given an initial concentration and/or source of gaseous sulfur trioxide (e.g. fuming from oleum). The model includes the thermochemical effects on aerosol condensation and air parcel buoyancy. Condensation is assumed to occur heterogeneously onto a preexisting background aerosol distribution. The model development is both a revisiting of research initially presented at the Fall 2001 American Geophysical Union Meeting [1] and a further extension to provide new capabilities for current atmospheric dispersion modeling efforts [2]. Sulfuric acid is one of the most widely used of all industrial chemicals. In 1992, world consumption of sulfuric acid was 145 million metric tons, with 42.4 Mt (mega-tons) consumed in the United States [10]. In 2001, of 37.5 Mt consumed in the U.S., 74% went into producing phosphate fertilizers [11]. Another significant use is in mining industries. Lawuyi and Fingas [7] estimate that, in 1996, 68% of use was for fertilizers and 5.8% was for mining. They note that H{sub 2}SO{sub 4} use has been and should continue to be very stable. In the United States, the elimination of MTBE (methyl tertiary-butyl ether) and the use of ethanol for gasoline production are further increasing the demand for petroleum alkylate. Alkylate producers have a choice of either a hydrofluoric acid or sulfuric acid process. Both processes are widely used today. Concerns, however, over the safety or potential regulation of hydrofluoric acid are likely to result in most of the growth being for the sulfuric acid process, further increasing demand [11]. The implication of sulfuric acid being a pervasive industrial chemical is that transport is also pervasive. Often, this is in the form of oleum tankers, having around 30% free sulfur trioxide. Although sulfuric acid itself is not a volatile substance, fuming sulfuric acid (referred to as oleum) is [7], the volatile product being sulfur trioxide. Sulfate aerosols and mist may form in the atmosphere on tank rupture. From chemical spill data from 1990-1996, Lawuyi02 and Fingas [7] prioritize sulfuric acid as sixth most serious. During this period, they note 155 spills totaling 13 Mt, out of a supply volume of 3700 Mt. Lawuyi and Fingas [7] summarize information on three major sulfuric acid spills. On 12 February 1984, 93 tons of sulfuric acid were spilled when 14 railroad cars derailed near MacTier, Parry Sound, Ontario. On 13 December 1978, 51 railroad cars derailed near Springhill, Nova Scotia. One car, containing 93% sulfuric acid, ruptured, spilling nearly its entire contents. In July 1993, 20 to 50 tons of fuming sulfuric acid spilled at the General Chemical Corp. plant in Richmond, California, a major industrial center near San Francisco. The release occurred when oleum was being loaded into a nonfuming acid railroad tank car that contained only a rupture disk as a safety device. The tank car was overheated and this rupture disk blew. The resulting cloud of sulfuric acid drifted northeast with prevailing winds over a number of populated areas. More than 3,000 people subsequently sought medical attention for burning eyes, coughing, headaches, and nausea. Almost all were treated and released on the day of the spill. By the day after the release, another 5,000 people had sought medical attention. The spill forced the closure of five freeways in the region as well as some Bay Area Rapid Transit System stations. Apart from corrosive toxicity, there is the additional hazard that the reactions of sulfur trioxide and sulfuric acid vapors with water are extremely exothermic [10, 11]. While the vapors are intrinsically denser than air, there is thus the likelihood of strong, warming-induced buoyancy from reactions with ambient water vapor, water-containing aerosol droplets, and wet environmental surface. Nordin [12] relates just such an occurrence following the Richmond, CA spill, with the plume observed to rise to 300 m. For all practical purposes, sulfur trioxide was the constituent released from the heated tank

  12. DOE Partner Begins Injecting 50,000 Tons of CO2 in Michigan Basin

    Broader source: Energy.gov [DOE]

    Building on an initial injection project of 10,000 metric tons of carbon dioxide into a Michigan geologic formation, a U.S. Department of Energy team of regional partners has begun injecting 50,000 additional tons into the formation, which is believed capable of storing hundreds of years worth of CO2, a greenhouse gas that contributes to climate change.

  13. (Data in metric tons of strontium content unless otherwise noted)

    E-Print Network [OSTI]

    2010 2011 2012 2013 e Production -- -- -- -- -- Imports for consumption: Strontium minerals 6,420 2 the potential for celestite consumption in drilling fluids. In descending order of production, China, Spain Production and Use: Although deposits of strontium minerals occur widely throughout the United States

  14. (Data in metric tons of silver content unless otherwise noted)

    E-Print Network [OSTI]

    in casino chips, freeway toll transponders, gasoline speed purchase devices, passports, and on packages,680 6,600 Exports 2 797 685 478 796 1,000 Consumption, apparent 5,250 6,300 4,600 7,220 7,850 Price September 2011, silver prices averaged $36.39 per troy ounce. The overall rise in silver prices corresponded

  15. (Data in metric tons of gold content unless otherwise noted)

    E-Print Network [OSTI]

    , expansion projects, and development projects were placed on hold because of the drop in the price of gold,140 8,140 Price, dollars per troy ounce 4 975 1,228 1,572 1,673 1,400 Employment, mine and mill, number, and Issues: The estimated gold price in 2013 was 16% lower than the price in 2012. This was the first time

  16. Energy Department Sponsored Project Captures One Millionth Metric Ton of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015 Infographic courtesy ofDepartmentPortland PublicCyclingCO2 | Department

  17. Billion Ton Study—A Historical Perspective

    Broader source: Energy.gov [DOE]

    Breakout Session 1A: Biomass Feedstocks for the Bioeconomy Billion Ton Study—A Historical Perspective Bryce Stokes, Senior Advisor, CNJV

  18. Self-benchmarking Guide for Data Centers: Metrics, Benchmarks, Actions

    E-Print Network [OSTI]

    Mathew, Paul

    2010-01-01

    good practice” for data center infrastructure efficiency metric. Data Center Benchmarking Guidegood practice benchmark and 0.6 kW/ton as a better practice benchmark. Data Center Benchmarking Guide

  19. Table 1. 2013 Summary statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    tons)",, "Sulfur dioxide (short tons)",4202,43 "Nitrogen oxide (short tons)",18043,37 "Carbon dioxide (thousand metric tons)",3768,44 "Sulfur dioxide (lbsMWh)",1.3,29 "Nitrogen...

  20. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    tons)",, "Sulfur dioxide (short tons)",6565,42 "Nitrogen oxide (short tons)",7627,46 "Carbon dioxide (thousand metric tons)",1942,49 "Sulfur dioxide (lbsMWh)",0.9,37 "Nitrogen...

  1. Table 1. 2013 Summary statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    tons)",, "Sulfur dioxide (short tons)",2241,47 "Nitrogen oxide (short tons)",2585,48 "Carbon dioxide (thousand metric tons)",4722,43 "Sulfur dioxide (lbsMWh)",0.6,40 "Nitrogen...

  2. Table 1. 2013 Summary statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    tons)",, "Sulfur dioxide (short tons)",2109,48 "Nitrogen oxide (short tons)",96842,5 "Carbon dioxide (thousand metric tons)",57323,13 "Sulfur dioxide (lbsMWh)",0,49 "Nitrogen...

  3. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    tons)",, "Sulfur dioxide (short tons)",71,50 "Nitrogen oxide (short tons)",792,50 "Carbon dioxide (thousand metric tons)",15,51 "Sulfur dioxide (lbsMWh)",0,50 "Nitrogen oxide...

  4. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    tons)",, "Sulfur dioxide (short tons)",7436,41 "Nitrogen oxide (short tons)",16438,39 "Carbon dioxide (thousand metric tons)",15690,37 "Sulfur dioxide (lbsMWh)",0.4,43 "Nitrogen...

  5. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    tons)",, "Sulfur dioxide (short tons)",3196,46 "Nitrogen oxide (short tons)",15299,40 "Carbon dioxide (thousand metric tons)",15789,36 "Sulfur dioxide (lbsMWh)",0.1,48 "Nitrogen...

  6. Table 1. 2013 Summary statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    tons)",, "Sulfur dioxide (short tons)",3512,45 "Nitrogen oxide (short tons)",9372,45 "Carbon dioxide (thousand metric tons)",8726,41 "Sulfur dioxide (lbsMWh)",0.2,47 "Nitrogen...

  7. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    tons)",, "Sulfur dioxide (short tons)",1271,49 "Nitrogen oxide (short tons)",1161,49 "Carbon dioxide (thousand metric tons)",2838,48 "Sulfur dioxide (lbsMWh)",0.4,44 "Nitrogen...

  8. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    tons)",, "Sulfur dioxide (short tons)",3733,44 "Nitrogen oxide (short tons)",5057,47 "Carbon dioxide (thousand metric tons)",3447,46 "Sulfur dioxide (lbsMWh)",0.4,45 "Nitrogen...

  9. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    tons)",, "Sulfur dioxide (short tons)",13365,38 "Nitrogen oxide (short tons)",9607,44 "Carbon dioxide (thousand metric tons)",3675,45 "Sulfur dioxide (lbsMWh)",1.9,23 "Nitrogen...

  10. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    tons)",, "Sulfur dioxide (short tons)",237091,5 "Nitrogen oxide (short tons)",86058,8 "Carbon dioxide (thousand metric tons)",67193,10 "Sulfur dioxide (lbsMWh)",4.5,3 "Nitrogen...

  11. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    tons)",, "Sulfur dioxide (short tons)",190782,7 "Nitrogen oxide (short tons)",87201,7 "Carbon dioxide (thousand metric tons)",85304,7 "Sulfur dioxide (lbsMWh)",4.3,4 "Nitrogen...

  12. Table 1. 2013 Summary statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    tons)",, "Sulfur dioxide (short tons)",0,51 "Nitrogen oxide (short tons)",148,51 "Carbon dioxide (thousand metric tons)",49,50 "Sulfur dioxide (lbsMWh)",0,51 "Nitrogen oxide...

  13. Metric Presentation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Success Story Some Metrics That Supported It 8 Office of Electricity Delivery and Energy Reliability MODERN GRID S T R A T E G Y An example - Nuclear Power Industry Objective...

  14. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    "Sulfur dioxide (short tons)",87718,17 "Nitrogen oxide (short tons)",24490,32 "Carbon dioxide (thousand metric tons)",22633,33 "Sulfur dioxide (lbsMWh)",3.3,9 "Nitrogen...

  15. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    "Sulfur dioxide (short tons)",47671,25 "Nitrogen oxide (short tons)",19035,36 "Carbon dioxide (thousand metric tons)",28809,30 "Sulfur dioxide (lbsMWh)",1,35 "Nitrogen...

  16. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    "Sulfur dioxide (short tons)",13259,39 "Nitrogen oxide (short tons)",17975,38 "Carbon dioxide (thousand metric tons)",12543,39 "Sulfur dioxide (lbsMWh)",0.2,46 "Nitrogen...

  17. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    "Sulfur dioxide (short tons)",123735,10 "Nitrogen oxide (short tons)",55462,20 "Carbon dioxide (thousand metric tons)",56812,15 "Sulfur dioxide (lbsMWh)",2,20 "Nitrogen...

  18. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    "Sulfur dioxide (short tons)",203951,6 "Nitrogen oxide (short tons)",63358,11 "Carbon dioxide (thousand metric tons)",97812,6 "Sulfur dioxide (lbsMWh)",2,21 "Nitrogen...

  19. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    "Sulfur dioxide (short tons)",30027,30 "Nitrogen oxide (short tons)",30860,30 "Carbon dioxide (thousand metric tons)",33125,27 "Sulfur dioxide (lbsMWh)",1.2,30 "Nitrogen...

  20. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    "Sulfur dioxide (short tons)",86204,18 "Nitrogen oxide (short tons)",23189,33 "Carbon dioxide (thousand metric tons)",38118,22 "Sulfur dioxide (lbsMWh)",2.2,19 "Nitrogen...

  1. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    "Sulfur dioxide (short tons)",12339,40 "Nitrogen oxide (short tons)",15150,41 "Carbon dioxide (thousand metric tons)",14735,38 "Sulfur dioxide (lbsMWh)",0.8,38 "Nitrogen...

  2. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    "Sulfur dioxide (short tons)",68077,21 "Nitrogen oxide (short tons)",39706,27 "Carbon dioxide (thousand metric tons)",34686,25 "Sulfur dioxide (lbsMWh)",1.8,26 "Nitrogen...

  3. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    "Sulfur dioxide (short tons)",17511,35 "Nitrogen oxide (short tons)",13803,42 "Carbon dioxide (thousand metric tons)",9500,40 "Sulfur dioxide (lbsMWh)",0.6,39 "Nitrogen...

  4. Table 1. 2013 Summary statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    "Sulfur dioxide (short tons)",41539,26 "Nitrogen oxide (short tons)",21995,34 "Carbon dioxide (thousand metric tons)",18950,34 "Sulfur dioxide (lbsMWh)",2.3,17 "Nitrogen...

  5. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    "Sulfur dioxide (short tons)",17735,34 "Nitrogen oxide (short tons)",59055,16 "Carbon dioxide (thousand metric tons)",28535,31 "Sulfur dioxide (lbsMWh)",1,36 "Nitrogen...

  6. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    "Sulfur dioxide (short tons)",346873,2 "Nitrogen oxide (short tons)",102526,4 "Carbon dioxide (thousand metric tons)",102466,4 "Sulfur dioxide (lbsMWh)",5.1,1 "Nitrogen...

  7. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    "Sulfur dioxide (short tons)",157488,8 "Nitrogen oxide (short tons)",78033,10 "Carbon dioxide (thousand metric tons)",78344,8 "Sulfur dioxide (lbsMWh)",3.4,8 "Nitrogen...

  8. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    "Sulfur dioxide (short tons)",106879,14 "Nitrogen oxide (short tons)",44657,25 "Carbon dioxide (thousand metric tons)",39175,21 "Sulfur dioxide (lbsMWh)",3.8,6 "Nitrogen...

  9. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    "Sulfur dioxide (short tons)",80418,19 "Nitrogen oxide (short tons)",57024,17 "Carbon dioxide (thousand metric tons)",46268,19 "Sulfur dioxide (lbsMWh)",2.2,18 "Nitrogen...

  10. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    "Sulfur dioxide (short tons)",30947,29 "Nitrogen oxide (short tons)",44824,24 "Carbon dioxide (thousand metric tons)",33456,26 "Sulfur dioxide (lbsMWh)",0.5,41 "Nitrogen...

  11. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    "Sulfur dioxide (short tons)",122578,11 "Nitrogen oxide (short tons)",82286,9 "Carbon dioxide (thousand metric tons)",58274,12 "Sulfur dioxide (lbsMWh)",2.4,16 "Nitrogen...

  12. Table 1. 2013 Summary statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    "Sulfur dioxide (short tons)",40012,27 "Nitrogen oxide (short tons)",49623,21 "Carbon dioxide (thousand metric tons)",39387,20 "Sulfur dioxide (lbsMWh)",1.5,27 "Nitrogen...

  13. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    "Sulfur dioxide (short tons)",66884,22 "Nitrogen oxide (short tons)",31505,29 "Carbon dioxide (thousand metric tons)",28043,32 "Sulfur dioxide (lbsMWh)",3.6,7 "Nitrogen...

  14. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    "Sulfur dioxide (short tons)",93888,15 "Nitrogen oxide (short tons)",60229,14 "Carbon dioxide (thousand metric tons)",68862,9 "Sulfur dioxide (lbsMWh)",2.5,14 "Nitrogen...

  15. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    "Sulfur dioxide (short tons)",49587,24 "Nitrogen oxide (short tons)",55615,19 "Carbon dioxide (thousand metric tons)",50687,17 "Sulfur dioxide (lbsMWh)",1.9,24 "Nitrogen...

  16. Table 1. 2013 Summary statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    "Sulfur dioxide (short tons)",23716,31 "Nitrogen oxide (short tons)",59416,15 "Carbon dioxide (thousand metric tons)",55342,16 "Sulfur dioxide (lbsMWh)",0.4,42 "Nitrogen...

  17. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    "Sulfur dioxide (short tons)",273718,4 "Nitrogen oxide (short tons)",121681,3 "Carbon dioxide (thousand metric tons)",98895,5 "Sulfur dioxide (lbsMWh)",5,2 "Nitrogen oxide...

  18. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    "Sulfur dioxide (short tons)",20710,33 "Nitrogen oxide (short tons)",25416,31 "Carbon dioxide (thousand metric tons)",7428,42 "Sulfur dioxide (lbsMWh)",4,5 "Nitrogen oxide...

  19. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    "Sulfur dioxide (short tons)",16865,36 "Nitrogen oxide (short tons)",21789,35 "Carbon dioxide (thousand metric tons)",16951,35 "Sulfur dioxide (lbsMWh)",1.2,31 "Nitrogen...

  20. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    "Sulfur dioxide (short tons)",383728,1 "Nitrogen oxide (short tons)",228695,1 "Carbon dioxide (thousand metric tons)",257465,1 "Sulfur dioxide (lbsMWh)",1.8,25 "Nitrogen...

  1. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    "Sulfur dioxide (short tons)",23670,32 "Nitrogen oxide (short tons)",62296,13 "Carbon dioxide (thousand metric tons)",35699,24 "Sulfur dioxide (lbsMWh)",1.1,33 "Nitrogen...

  2. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    "Sulfur dioxide (short tons)",71293,20 "Nitrogen oxide (short tons)",62397,12 "Carbon dioxide (thousand metric tons)",56940,14 "Sulfur dioxide (lbsMWh)",1.1,32 "Nitrogen...

  3. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    "Sulfur dioxide (short tons)",56854,23 "Nitrogen oxide (short tons)",48454,22 "Carbon dioxide (thousand metric tons)",30274,28 "Sulfur dioxide (lbsMWh)",3.2,11 "Nitrogen...

  4. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    "Sulfur dioxide (short tons)",117797,12 "Nitrogen oxide (short tons)",88345,6 "Carbon dioxide (thousand metric tons)",108431,3 "Sulfur dioxide (lbsMWh)",1.1,34 "Nitrogen...

  5. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    "Sulfur dioxide (short tons)",15347,37 "Nitrogen oxide (short tons)",11430,43 "Carbon dioxide (thousand metric tons)",3228,47 "Sulfur dioxide (lbsMWh)",3,12 "Nitrogen...

  6. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    "Sulfur dioxide (short tons)",108306,13 "Nitrogen oxide (short tons)",44114,26 "Carbon dioxide (thousand metric tons)",47686,18 "Sulfur dioxide (lbsMWh)",3.3,10 "Nitrogen...

  7. Table 1. 2013 Summary Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    "Sulfur dioxide (short tons)",276851,3 "Nitrogen oxide (short tons)",151148,2 "Carbon dioxide (thousand metric tons)",108729,2 "Sulfur dioxide (lbsMWh)",2.4,15 "Nitrogen...

  8. Table 1. 2013 Summary statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    "Sulfur dioxide (short tons)",35625,28 "Nitrogen oxide (short tons)",36972,28 "Carbon dioxide (thousand metric tons)",29255,29 "Sulfur dioxide (lbsMWh)",1.4,28 "Nitrogen...

  9. Uses of lunar sulfur

    SciTech Connect (OSTI)

    Vaniman, D.T.; Pettit, D.R.; Heiken, G.

    1988-01-01

    Sulfur and sulfur compounds have a wide range of applications for their fluid, electrical, chemical and biochemical properties. Although low in abundance on the Moon (/approximately/0.1% in mare soils), sulfur is surface-correlated and relatively extractable. Co-production of sulfur during oxygen extraction from ilmenite-rich soils could yield sulfur in masses up to 10% of the mass of oxygen produced. Sulfur deserves serious consideration as a lunar resource. 29 refs., 3 figs.

  10. Sulfuric acid-sulfur heat storage cycle

    DOE Patents [OSTI]

    Norman, John H. (LaJolla, CA)

    1983-12-20

    A method of storing heat is provided utilizing a chemical cycle which interconverts sulfuric acid and sulfur. The method can be used to levelize the energy obtained from intermittent heat sources, such as solar collectors. Dilute sulfuric acid is concentrated by evaporation of water, and the concentrated sulfuric acid is boiled and decomposed using intense heat from the heat source, forming sulfur dioxide and oxygen. The sulfur dioxide is reacted with water in a disproportionation reaction yielding dilute sulfuric acid, which is recycled, and elemental sulfur. The sulfur has substantial potential chemical energy and represents the storage of a significant portion of the energy obtained from the heat source. The sulfur is burned whenever required to release the stored energy. A particularly advantageous use of the heat storage method is in conjunction with a solar-powered facility which uses the Bunsen reaction in a water-splitting process. The energy storage method is used to levelize the availability of solar energy while some of the sulfur dioxide produced in the heat storage reactions is converted to sulfuric acid in the Bunsen reaction.

  11. (Data in million metric tons of usable ore unless otherwise noted)

    E-Print Network [OSTI]

    than that in 2012 owing to reduced consumption for steel production. Two production lines were idled Production and Use: In 2013, mines in Michigan and Minnesota shipped 99% of the usable ore produced for the majority of production. The United States was estimated to have produced and consumed 2% of the world

  12. 10,248,196 Metric Tons of CO2 Injected as of June 19, 2015 |...

    Energy Savers [EERE]

    210,526 passenger vehicles. The projects currently injecting CO2 within DOE's Regional Carbon Sequestration Partnership Program and the Major Demonstration Program are detailed...

  13. 6.347 metric tons of netting and rope worth $ 10 million .

    E-Print Network [OSTI]

    and is feasible using equipment commonly found in most Chesapeake Bay shucking houses . INTRODUCTION " Red liquor to the following spring (Lear. 195 8). T hus. "red" oys- ters can be a problem to shucking houses for the ent ire Marine Resources Center. appear to follow an extended warm fa ll (Nelson. 1948). A method of eliminating

  14. 10,180,047 Metric Tons of CO2 Injected as of May 28, 2015 | Department...

    Broader source: Energy.gov (indexed) [DOE]

    210,526 passenger vehicles. The projects currently injecting CO2 within DOE's Regional Carbon Sequestration Partnership Program and the Major Demonstration Program are detailed...

  15. haden in the South Atlantic summer fishery alone was 34,435 metric tons.

    E-Print Network [OSTI]

    . CHEEK National Marine Fisheries Service Atlantic Estuolrine Fisheries Center Beaufort, NC 28516 four were available. Specimens ranged from 12 to 580 mm standard length (SL). Specimens smaller than about 60 mm SL were x-rayed with a soft-ray machine and larger specimens with a hard-ray machine. Counts

  16. 10,422,136 Metric Tons of CO2 Injected as of August 21, 2015...

    Broader source: Energy.gov (indexed) [DOE]

    The projects currently injecting CO2 within DOE's Regional Carbon Sequestration Partnership Program and the Major Demonstration Program are detailed below. Regional Carbon...

  17. RARE EARTHS1 (Data in metric tons of rare-earth oxide (REO) content, unless noted)

    E-Print Network [OSTI]

    Imports:3 Thorium ore (monazite) -- -- -- -- 22 Rare-earth metals, alloys 271 352 235 284 406 Cerium Exports:3 Thorium ore, monazite -- -- 3 27 -- Rare-earth metals, alloys 71 44 194 329 456 Cerium compounds. Rare-earth metals, whether or not intermixed or interalloyed 2805.30.0000 5.0% ad val. 31.3% ad val

  18. DOE Will Dispose of 34 Metric Tons of Plutonium by Turning it into Fuel for

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouthReporteeo | National/%2A en Office ofAmendment 000002Turns

  19. Energy Department Project Captures and Stores One Million Metric Tons of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015 Infographic courtesy ofDepartment ofDepartmentTechnologiesEffortsCarbon

  20. 10,651,176 Metric Tons of CO2 Injected as of September 16, 2015 |

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirley Ann JacksonDepartment of EnergyResearchers at

  1. U.S. Removes Nine Metric Tons of Plutonium From Nuclear Weapons Stockpile |

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirley Ann Jackson About1996HowFOAShowing YouNeedof Energy Fish and WildlifeofDepartment of

  2. 11,202,720 Metric Tons of CO2 Injected as of October 14, 2015 | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels DataEnergy Webinar: Demonstration ofDepartment ofof Energy withof

  3. DOE to Remove 200 Metric Tons of Highly Enriched Uranium from U.S. Nuclear

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergy A plug-in electricLaboratory | DepartmentDOE ZeroofBatteriesHybridNational

  4. Department of Energy Releases New 'Billion-Ton' Study Highlighting...

    Energy Savers [EERE]

    The U.S. Department of Energy today released a report - 2011 U.S. Billion-Ton Update: Biomass Supply for a Bioenergy and Bioproducts Industry - detailing U.S. biomass feedstock...

  5. Sulfur recovery process

    SciTech Connect (OSTI)

    Hise, R.E.; Cook, W.J.

    1991-06-04

    This paper describes a method for recovering sulfur from a process feed stream mixture of gases comprising sulfur-containing compounds including hydrogen sulfide using the Claus reaction to convert sulfur-containing compounds to elemental sulfur and crystallization to separate sulfur-containing compounds from a tail gas of the Claus reaction for further processing as a recycle stream. It comprises: providing a Claus feed stream containing a stoichiometric excess of hydrogen sulfide, the Claus feed stream including the process feed stream and the recycles stream; introducing the Claus feed stream and an oxidizing agent into a sulfur recovery unit for converting sulfur-containing compounds in the Claus feed stream to elemental sulfur; withdrawing the tail gas from the sulfur recovery unit; separating water from the tail gas to producing a dehydrated tail gas; separating sulfur-containing compounds including carbonyl sulfide from the dehydrated tail gas as an excluded material by crystallization and withdrawing an excluded material-enriched output from the crystallization to produce the recycle stream; and combining the recycle stream with the process feed stream to produce the Claus feed stream.

  6. Metrics for enterprise transformation

    E-Print Network [OSTI]

    Blackburn, Craig D. (Craig David), S. M. Massachusetts Institute of Technology

    2009-01-01

    The objective of this thesis is to depict the role of metrics in the evolving journey of enterprise transformation. To this end, three propositions are explored: (i) metrics and measurement systems drive transformation, ...

  7. Buildings Performance Metrics Terminology

    Broader source: Energy.gov [DOE]

    This document provides the terms and definitions used in the Department of Energys Performance Metrics Research Project.

  8. ADVANCED SULFUR CONTROL CONCEPTS

    SciTech Connect (OSTI)

    Apostolos A. Nikolopoulos; Santosh K. Gangwal; William J. McMichael; Jeffrey W. Portzer

    2003-01-01

    Conventional sulfur removal in integrated gasification combined cycle (IGCC) power plants involves numerous steps: COS (carbonyl sulfide) hydrolysis, amine scrubbing/regeneration, Claus process, and tail-gas treatment. Advanced sulfur removal in IGCC systems involves typically the use of zinc oxide-based sorbents. The sulfides sorbent is regenerated using dilute air to produce a dilute SO{sub 2} (sulfur dioxide) tail gas. Under previous contracts the highly effective first generation Direct Sulfur Recovery Process (DSRP) for catalytic reduction of this SO{sub 2} tail gas to elemental sulfur was developed. This process is currently undergoing field-testing. In this project, advanced concepts were evaluated to reduce the number of unit operations in sulfur removal and recovery. Substantial effort was directed towards developing sorbents that could be directly regenerated to elemental sulfur in an Advanced Hot Gas Process (AHGP). Development of this process has been described in detail in Appendices A-F. RTI began the development of the Single-step Sulfur Recovery Process (SSRP) to eliminate the use of sorbents and multiple reactors in sulfur removal and recovery. This process showed promising preliminary results and thus further process development of AHGP was abandoned in favor of SSRP. The SSRP is a direct Claus process that consists of injecting SO{sub 2} directly into the quenched coal gas from a coal gasifier, and reacting the H{sub 2}S-SO{sub 2} mixture over a selective catalyst to both remove and recover sulfur in a single step. The process is conducted at gasifier pressure and 125 to 160 C. The proposed commercial embodiment of the SSRP involves a liquid phase of molten sulfur with dispersed catalyst in a slurry bubble-column reactor (SBCR).

  9. Elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, M.; Zhicheng Hu.

    1993-09-07

    An improved catalytic reduction process for the direct recovery of elemental sulfur from various SO[sub 2]-containing industrial gas streams. The catalytic process provides combined high activity and selectivity for the reduction of SO[sub 2] to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over certain catalyst formulations based on cerium oxide. The process is a single-stage, catalytic sulfur recovery process in conjunction with regenerators, such as those used in dry, regenerative flue gas desulfurization or other processes, involving direct reduction of the SO[sub 2] in the regenerator off gas stream to elemental sulfur in the presence of a catalyst. 4 figures.

  10. Elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, Maria (Winchester, MA); Hu, Zhicheng (Somerville, MA)

    1993-01-01

    An improved catalytic reduction process for the direct recovery of elemental sulfur from various SO.sub.2 -containing industrial gas streams. The catalytic process provides combined high activity and selectivity for the reduction of SO.sub.2 to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over certain catalyst formulations based on cerium oxide. The process is a single-stage, catalytic sulfur recovery process in conjunction with regenerators, such as those used in dry, regenerative flue gas desulfurization or other processes, involving direct reduction of the SO.sub.2 in the regenerator off gas stream to elemental sulfur in the presence of a catalyst.

  11. Biogenic sulfur source strengths

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.; Robinson, E.; Pack, M.R.; Bamesberger, W.L.

    1981-12-01

    Conclusions are presented from a 4-yr field measurement study of biogenic sulfur gas emissions from soils, and some water and vegetated surfaces, at 35 locales in the eastern and southeastern United States. More than one soil order was examined whenever possible to increase the data base obtained from the 11 major soil orders comprising the study area. Data analysis and emission model development were based upon an (80 x 80)-km/sup 2/ grid system. The measured sulfur fluxes, adjusted for the annual mean temperature for each sampling locale, weigted by the percentage of each soil order within each grid, and averaged for each of the east-west grid tiers from 47/sup 0/N to 25/sup 0/N latitude, showed an exponential north-to-south increase in total sulfur gas flux. Our model predits an additional increase of nearly 25-fold in sulfur flux between 25/sup 0/N and the equator.

  12. Surveillance Metrics Sensitivity Study

    SciTech Connect (OSTI)

    Bierbaum, R; Hamada, M; Robertson, A

    2011-11-01

    In September of 2009, a Tri-Lab team was formed to develop a set of metrics relating to the NNSA nuclear weapon surveillance program. The purpose of the metrics was to develop a more quantitative and/or qualitative metric(s) describing the results of realized or non-realized surveillance activities on our confidence in reporting reliability and assessing the stockpile. As a part of this effort, a statistical sub-team investigated various techniques and developed a complementary set of statistical metrics that could serve as a foundation for characterizing aspects of meeting the surveillance program objectives. The metrics are a combination of tolerance limit calculations and power calculations, intending to answer level-of-confidence type questions with respect to the ability to detect certain undesirable behaviors (catastrophic defects, margin insufficiency defects, and deviations from a model). Note that the metrics are not intended to gauge product performance but instead the adequacy of surveillance. This report gives a short description of four metrics types that were explored and the results of a sensitivity study conducted to investigate their behavior for various inputs. The results of the sensitivity study can be used to set the risk parameters that specify the level of stockpile problem that the surveillance program should be addressing.

  13. Surveillance metrics sensitivity study.

    SciTech Connect (OSTI)

    Hamada, Michael S.; Bierbaum, Rene Lynn; Robertson, Alix A.

    2011-09-01

    In September of 2009, a Tri-Lab team was formed to develop a set of metrics relating to the NNSA nuclear weapon surveillance program. The purpose of the metrics was to develop a more quantitative and/or qualitative metric(s) describing the results of realized or non-realized surveillance activities on our confidence in reporting reliability and assessing the stockpile. As a part of this effort, a statistical sub-team investigated various techniques and developed a complementary set of statistical metrics that could serve as a foundation for characterizing aspects of meeting the surveillance program objectives. The metrics are a combination of tolerance limit calculations and power calculations, intending to answer level-of-confidence type questions with respect to the ability to detect certain undesirable behaviors (catastrophic defects, margin insufficiency defects, and deviations from a model). Note that the metrics are not intended to gauge product performance but instead the adequacy of surveillance. This report gives a short description of four metrics types that were explored and the results of a sensitivity study conducted to investigate their behavior for various inputs. The results of the sensitivity study can be used to set the risk parameters that specify the level of stockpile problem that the surveillance program should be addressing.

  14. Generalized utility metrics for supercomputers

    E-Print Network [OSTI]

    Strohmaier, Erich

    2009-01-01

    2007:1–12 Generalized utility metrics for supercomputers 12.ISSUE PAPER Generalized utility metrics for supercomputersproblem of ranking the utility of supercom- puter systems

  15. LOW SULFUR HOME HEATING OIL DEMONSTRATION PROJECT SUMMARY REPORT.

    SciTech Connect (OSTI)

    BATEY, J.E.; MCDONALD, R.J.

    2005-06-01

    This project was funded by NYSERDA and has clearly demonstrated many advantages of using low sulfur content heating oil to provide thermal comfort in homes. Prior laboratory research in the United States and Canada had indicated a number of potential benefits of using lower sulfur (0.05%) heating oil. However, this prior research has not resulted in the widespread use of low sulfur fuel oil in the marketplace. The research project described in this report was conducted with the assistance of a well-established fuel oil marketer in New York State (NYS) and has provided clear proof of the many real-world advantages of marketing and using low sulfur content No. 2 fuel oil. The very positive experience of the participating marketer over the past three years has already helped to establish low sulfur heating oil as a viable option for many other fuel marketers. In large part, based on the initial findings of this project and the experience of the participating NYS oilheat marketer, the National Oilheat Research Alliance (NORA) has already fully supported a resolution calling for the voluntary use of low sulfur (0.05 percent) home heating oil nationwide. The NORA resolution has the goal of converting eighty percent of all oil-heated homes to the lower sulfur fuel (0.05 percent by weight) by the year 2007. The Oilheat Manufacturers Association (OMA) has also passed a resolution fully supporting the use of lower sulfur home heating oil in the equipment they manufacture. These are important endorsements by prominent national oil heat associations. Using lower sulfur heating oil substantially lowers boiler and furnace fouling rates. Laboratory studies had indicated an almost linear relationship between sulfur content in the oil and fouling rates. The completed NYSERDA project has verified past laboratory studies in over 1,000 occupied residential homes over the course of three heating seasons. In fact, the reduction in fouling rates so clearly demonstrated by this project is almost the same as predicted by past laboratory studies. Fouling deposition rates are reduced by a factor of two to three by using lower sulfur oil. This translates to a potential for substantial service cost savings by extending the interval between labor-intensive cleanings of the internal surfaces of the heating systems in these homes. In addition, the time required for annual service calls can be lowered, reducing service costs and customer inconvenience. The analyses conducted as part of this field demonstration project indicates that service costs can be reduced by up to $200 million a year nationwide by using lower sulfur oil and extending vacuum cleaning intervals depending on the labor costs and existing cleaning intervals. The ratio of cost savings to added fuel costs is economically attractive based on past fuel price differentials for the lower sulfur product. The ratio of cost savings to added costs vary widely as a function of hourly service rates and the additional cost for lower sulfur oil. For typical values, the expected benefit is a factor of two to four higher than the added fuel cost. This means that for every dollar spent on higher fuel cost, two to four dollars can be saved by lowered vacuum cleaning costs when the cleaning intervals are extended. Information contained in this report can be used by individual oil marketers to estimate the benefit to cost ratio for their specific applications. Sulfur oxide and nitrogen oxide air emissions are reduced substantially by using lower sulfur fuel oil in homes. Sulfur oxides emissions are lowered by 75 percent by switching from fuel 0.20 percent to 0.05 percent sulfur oil. This is a reduction of 63,000 tons a year nationwide. In New York State, sulfur oxide emissions are reduced by 13,000 tons a year. This translates to a total value of $12 million a year in Sulfur Oxide Emission Reduction Credits for an emission credit cost of $195 a ton. While this ''environmental cost'' dollar savings is smaller than the potential service costs reduction, it is very significant. It represents an important red

  16. 1,153-ton Waste Vault Removed from 300 Area - Vault held waste...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1,153-ton Waste Vault Removed from 300 Area - Vault held waste tanks with contamination from Hanford's former laboratory facilities 1,153-ton Waste Vault Removed from 300 Area -...

  17. U.S. Manufacturers Save $1 Billion, 11 Million Tons of CO2 through...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Manufacturers Save 1 Billion, 11 Million Tons of CO2 through Energy Efficiency Investments U.S. Manufacturers Save 1 Billion, 11 Million Tons of CO2 through Energy Efficiency...

  18. U.S. Manufacturers Save $1 Billion, 11 Million Tons of CO2 through...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    U.S. Manufacturers Save 1 Billion, 11 Million Tons of CO2 through Energy Efficiency Investments U.S. Manufacturers Save 1 Billion, 11 Million Tons of CO2 through Energy...

  19. Process for forming sulfuric acid

    DOE Patents [OSTI]

    Lu, Wen-Tong P. (Upper St. Clair, PA)

    1981-01-01

    An improved electrode is disclosed for the anode in a sulfur cycle hydrogen generation process where sulfur dioxie is oxidized to form sulfuric acid at the anode. The active compound in the electrode is palladium, palladium oxide, an alloy of palladium, or a mixture thereof. The active compound may be deposited on a porous, stable, conductive substrate.

  20. Advanced Byproduct Recovery: Direct Catalytic Reduction of Sulfur Dioxide to Elemental Sulfur. Fifth quarterly technical progress report, December 1996

    SciTech Connect (OSTI)

    NONE

    1996-12-01

    More than 170 wet scrubber systems applied, to 72,000 MW of U.S., coal-fired, utility boilers are in operation or under construction. In these systems, the sulfur dioxide removed from the boiler flue gas is permanently bound to a sorbent material, such as lime or limestone. The sulfated sorbent must be disposed of as a waste product or, in some cases, sold as a byproduct (e.g. gypsum). Due to the abundance and low cost of naturally occurring gypsum, and the costs associated with producing an industrial quality product, less than 7% of these scrubbers are configured to produce usable gypsum (and only 1% of all units actually sell the byproduct). The disposal of solid waste from each of these scrubbers requires a landfill area of approximately 200 to 400 acres. In the U.S., a total of 19 million tons of disposable FGD byproduct are produced, transported and disposed of in landfills annually. The use of regenerable sorbent technologies has the potential to reduce or eliminate solid waste production, transportation and disposal. In a regenerable sorbent system, the sulfur dioxide in the boiler flue gas is removed by the sorbent in an adsorber. The S0{sub 2}s subsequently released, in higher concentration, in a regenerator. All regenerable systems produce an off-gas stream from the regenerator that must be processed further in order to obtain a salable byproduct, such as elemental sulfur, sulfuric acid or liquid S0{sub 2}.

  1. Defining a Standard Metric for Electricity Savings

    SciTech Connect (OSTI)

    Brown, Marilyn; Akbari, Hashem; Blumstein, Carl; Koomey, Jonathan; Brown, Richard; Calwell, Chris; Carter, Sheryl; Cavanagh, Ralph; Chang, Audrey; Claridge, David; Craig, Paul; Diamond, Rick; Eto, Joseph H.; Fulkerson, William; Gadgil, Ashok; Geller, Howard; Goldemberg, Jose; Goldman, Chuck; Goldstein, David B.; Greenberg, Steve; Hafemeister, David; Harris, Jeff; Harvey, Hal; Heitz, Eric; Hirst, Eric; Hummel, Holmes; Kammen, Dan; Kelly, Henry; Laitner, Skip; Levine, Mark; Lovins, Amory; Masters, Gil; McMahon, James E.; Meier, Alan; Messenger, Michael; Millhone, John; Mills, Evan; Nadel, Steve; Nordman, Bruce; Price, Lynn; Romm, Joe; Ross, Marc; Rufo, Michael; Sathaye, Jayant; Schipper, Lee; Schneider, Stephen H; Sweeney, James L; Verdict, Malcolm; Vorsatz, Diana; Wang, Devra; Weinberg, Carl; Wilk, Richard; Wilson, John; Worrell, Ernst

    2009-03-01

    The growing investment by governments and electric utilities in energy efficiency programs highlights the need for simple tools to help assess and explain the size of the potential resource. One technique that is commonly used in this effort is to characterize electricity savings in terms of avoided power plants, because it is easier for people to visualize a power plant than it is to understand an abstraction such as billions of kilowatt-hours. Unfortunately, there is no standardization around the characteristics of such power plants. In this letter we define parameters for a standard avoided power plant that have physical meaning and intuitive plausibility, for use in back-of-the-envelope calculations. For the prototypical plant this article settles on a 500 MW existing coal plant operating at a 70percent capacity factor with 7percent T&D losses. Displacing such a plant for one year would save 3 billion kW h per year at the meter and reduce emissions by 3 million metric tons of CO2 per year. The proposed name for this metric is the Rosenfeld, in keeping with the tradition among scientists of naming units in honor of the person most responsible for the discovery and widespread adoption of the underlying scientific principle in question--Dr. Arthur H. Rosenfeld.

  2. Cyber threat metrics.

    SciTech Connect (OSTI)

    Frye, Jason Neal; Veitch, Cynthia K.; Mateski, Mark Elliot; Michalski, John T.; Harris, James Mark; Trevino, Cassandra M.; Maruoka, Scott

    2012-03-01

    Threats are generally much easier to list than to describe, and much easier to describe than to measure. As a result, many organizations list threats. Fewer describe them in useful terms, and still fewer measure them in meaningful ways. This is particularly true in the dynamic and nebulous domain of cyber threats - a domain that tends to resist easy measurement and, in some cases, appears to defy any measurement. We believe the problem is tractable. In this report we describe threat metrics and models for characterizing threats consistently and unambiguously. The purpose of this report is to support the Operational Threat Assessment (OTA) phase of risk and vulnerability assessment. To this end, we focus on the task of characterizing cyber threats using consistent threat metrics and models. In particular, we address threat metrics and models for describing malicious cyber threats to US FCEB agencies and systems.

  3. RARE EARTHS1 [Data in metric tons of rare-earth oxide (REO) content unless otherwise noted

    E-Print Network [OSTI]

    ,380 840 1,350 1,400 Rare-earth metals, alloys 1,470 1,390 4,920 1,380 3,400 Other rare-earth compounds 1,750 5,480 2,300 Rare-earth oxides, compounds 9,900 8,820 5,130 3,980 3,700 Rare-earth metals, alloy 784 scrap. Import Sources (2007­10): Rare-earth metals, compounds, etc.: China, 79%; France, 6%; Estonia, 4

  4. RARE EARTHS1 (Data in metric tons of rare-earth oxide (REO) content, unless otherwise noted)

    E-Print Network [OSTI]

    concentratese 10,000 5,000 5,000 5,000 5,000 Imports:2 Thorium ore (monazite) 11 -- -- -- -- Rare-earth metals,720 7,760 11,200 9,070 Ferrocerium, alloys 121 117 120 118 138 Exports:2 Rare-earth metals, alloys 991-2000): Monazite: Australia, 67%; and France, 33%. Rare-earth metals, compounds, etc.: China, 74%; France, 21

  5. RARE EARTHS1 (Data in metric tons of rare-earth oxide (REO) content, unless otherwise noted)

    E-Print Network [OSTI]

    concentratese 5,000 5,000 5,000 5,000 5,000 Imports:2 Thorium ore (monazite) -- -- -- -- -- Rare-earth metals,720 7,760 11,200 9,150 6,930 Ferrocerium, alloys 117 120 118 118 100 Exports:2 Rare-earth metals, alloys-2001): Rare-earth metals, compounds, etc.: China, 66%; France, 27%; Japan, 3%; Estonia, 2%; and other, 2

  6. RARE EARTHS1 (Data in metric tons of rare-earth oxide (REO) content, unless otherwise noted)

    E-Print Network [OSTI]

    ) 56 11 -- -- -- Rare-earth metals, alloys 429 529 953 1,780 2,370 Cerium compounds 3,180 1,810 4,940 3 metals, alloys 250 991 724 1,600 1,830 Cerium compounds 6,100 5,890 4,640 3,960 3,870 Other rare-earth-99): Monazite: Australia, 67%; France, 33%; Rare-earth metals, compounds, etc.: China, 71%; France, 23%; Japan

  7. RARE EARTHS1 (Data in metric tons of rare-earth oxide (REO) content unless otherwise noted)

    E-Print Network [OSTI]

    ,260 10,900 11,400 8,550 10,600 Ferrocerium, alloys 89 111 105 130 140 Exports:2 Rare-earth metals, alloys-05): Rare-earth metals, compounds, etc.: China, 76%; France, 9%; Japan, 4%; Russia, 3%; and other, 8.20.0000 Free. Rare-earth metals, whether or not intermixed or interalloyed 2805.30.0000 5.0% ad val. Cerium

  8. RARE EARTHS1 [Data in metric tons of rare-earth oxide (REO) content unless otherwise noted

    E-Print Network [OSTI]

    at Mountain Pass were further processed into rare-earth compounds and metal products. The United States,980 3,770 2,840 5,800 Rare-earth metals, alloy 226 525 468 240 390 Exports: 2 Cerium compounds 840 1,350 1,640 992 730 Rare-earth metals, alloys 4,930 1,380 3,030 2,080 1,000 Other rare-earth compounds 455

  9. RARE EARTHS1 (Data in metric tons of rare-earth oxide (REO) content, unless otherwise noted)

    E-Print Network [OSTI]

    Thorium ore (monazite) -- -- -- 22 -- Rare-earth metals, alloys 352 235 284 905 442 Cerium compounds 806 1:3 Thorium ore, monazite -- 3 27 -- -- Rare-earth metals, alloys 44 194 329 444 272 Cerium compounds.20.0000 Free Free. Rare-earth metals, whether or not intermixed or interalloyed 2805.30.0000 5.0% ad val. 31

  10. RARE EARTHS1 (Data in metric tons of rare-earth oxide (REO) content, unless otherwise noted)

    E-Print Network [OSTI]

    -- -- -- -- Imports: Thorium ore (monazite) -- 22 56 11 --3 Rare-earth metals, alloys 284 905 429 529 760 Cerium 121 123 Exports: Thorium ore, monazite 27 -- -- -- --3 Rare-earth metals, alloys 329 444 250 991 856 (monazite) 2612.20.0000 Free Free. Rare-earth metals, whether or not intermixed or interalloyed 2805

  11. RARE EARTHS1 [Data in metric tons of rare-earth oxide (REO) content unless otherwise noted

    E-Print Network [OSTI]

    ) -- -- -- -- -- Rare-earth metals, alloy 867 784 564 188 250 Cerium compounds 2,590 2,680 2,080 1,500 1,400 Mixed REOs (monazite or various thorium materials) -- 1 61 18 1 Rare-earth metals, alloys 733 1,470 1,390 4,920 640 categories increased when compared with those of 2009--the categories "Rare-earth metals, alloy" and "Rare-earth

  12. RARE EARTHS1 (Data in metric tons of rare-earth oxide (REO) content unless otherwise noted)

    E-Print Network [OSTI]

    ) -- -- -- -- -- Rare-earth metals, alloy 1,420 1,450 1,130 804 945 Cerium compounds 3,850 2,540 2,630 1,880 2,210 Mixed, compounds 9,150 7,260 10,900 11,400 9,800 Ferrocerium, alloys 118 89 111 105 142 Exports:2 Rare-earth metals-04): Rare-earth metals, compounds, etc.: China, 76%; France, 14%; Japan, 6%; Austria, 2%; and other, 2

  13. RARE EARTHS1 [Data in metric tons of rare-earth oxide (REO) content unless otherwise noted

    E-Print Network [OSTI]

    at Mountain Pass, CA, were further processed into rare-earth compounds and metal products. The United States -- -- -- -- 7,000 Exports: 2 Cerium compounds 1,380 840 1,350 1,640 1,100 Rare-earth metals, alloys 1,390 4,980 3,770 2,700 Rare-earth metals, alloy 679 226 525 468 280 Thorium ore (monazite or various thorium

  14. RARE EARTHS1 (Data in metric tons of rare-earth oxide (REO) content, unless otherwise noted)

    E-Print Network [OSTI]

    , compounds 7,760 11,200 9,150 7,260 10,900 Ferrocerium, alloys 120 118 118 89 111 Exports:2 Rare-earth metals Sources (1999-2002): Rare-earth metals, compounds, etc.: China, 66%; France, 25%; Japan, 4%; Estonia, 3) 2612.20.0000 Free. Rare-earth metals, whether or not intermixed or interalloyed 2805.30.0000 5.0% ad

  15. RARE EARTHS1 (Data in metric tons of rare-earth oxide (REO) content unless otherwise noted)

    E-Print Network [OSTI]

    -- Rare-earth metals, alloy 1,130 804 880 867 831 Cerium compounds 2,630 1,880 2,170 2,590 3,090 Mixed metals, alloys 1,190 1,010 636 733 1,470 Cerium compounds 1,940 2,280 2,210 2,010 1,690 Other rare-earth-06): Rare-earth metals, compounds, etc.: China, 84%; France, 6%; Japan, 4%; Russia, 2%; and other, 4

  16. RARE EARTHS1 (Data in metric tons of rare-earth oxide (REO) content unless otherwise noted)

    E-Print Network [OSTI]

    or various thorium materials) -- -- -- -- -- Rare-earth metals, alloy 804 880 867 784 807 Cerium compounds 1 metals, alloys 1,010 636 733 1,470 1,580 Cerium compounds 2,280 2,210 2,010 1,470 1,620 Other rare-earth (2004-07): Rare-earth metals, compounds, etc.: China, 87%; France, 5%; Japan, 4%; Russia, 2%; and other

  17. RARE EARTHS1 (Data in metric tons of rare-earth oxide (REO) content unless otherwise noted)

    E-Print Network [OSTI]

    ) -- -- -- -- -- Rare-earth metals, alloy 2,470 1,420 1,450 1,130 790 Cerium compounds 4,310 3,850 2,540 2,630 1 metals, alloys 1,650 884 1,300 1,190 1,240 Cerium compounds 4,050 4,110 2,740 1,940 2,000 Other rare-earth-03): Rare-earth metals, compounds, etc.: China, 67%; France, 17%; Japan, 4%; Estonia, 4%; and other, 8

  18. RARE EARTHS1 (Data in metric tons of rare-earth oxide (REO) content, unless otherwise noted)

    E-Print Network [OSTI]

    10,000 e 5,000 5,000 Imports:3 Thorium ore (monazite) 22 56 11 -- -- Rare-earth metals, alloys 905,720 5,600 Ferrocerium, alloys 78 107 121 117 122 Exports:3 Rare-earth metals, alloys 444 250 991 724 1%; Rare-earth metals, compounds, etc.: China, 75%; France, 19%; Japan, 3%; United Kingdom, 1%; and other

  19. RARE EARTHS1 (Data in metric tons of rare-earth oxide (REO) content, unless otherwise noted)

    E-Print Network [OSTI]

    : Thorium ore (monazite) -- -- 22 56 --3 Rare-earth metals, alloys 235 284 905 429 507 Cerium compounds 1 Exports: Thorium ore, monazite 3 27 -- -- --3 Rare-earth metals, alloys 194 329 444 250 879 Cerium for individual rare-earth metals and compounds, with most import categories slightly behind 1996's record high

  20. Materials management in an internationally safeguarded fuels reprocessing plant. [1500 and 210 metric tons heavy metal per year

    SciTech Connect (OSTI)

    Hakkila, E.A.; Cobb, D.D.; Dayem, H.A.; Dietz, R.J.; Kern, E.A.; Markin, J.T.; Shipley, J.P.; Barnes, J.W.; Scheinman, L.

    1980-04-01

    The second volume describes the requirements and functions of materials measurement and accounting systems (MMAS) and conceptual designs for an MMAS incorporating both conventional and near-real-time (dynamic) measurement and accounting techniques. Effectiveness evaluations, based on recently developed modeling, simulation, and analysis procedures, show that conventional accountability can meet IAEA goal quantities and detection times in these reference facilities only for low-enriched uranium. Dynamic materials accounting may meet IAEA goals for detecting the abrupt (1-3 weeks) diversion of 8 kg of plutonium. Current materials accounting techniques probably cannot meet the 1-y protracted-diversion goal of 8 kg for plutonium.

  1. Stratospheric sulfur oxidation kinetics

    SciTech Connect (OSTI)

    Jayne, J.T.; Worsnop, D.R.; Kolb, C.E. [Aerodyne Research, Inc., Billerica, MA (United States)] [and others

    1995-12-31

    Oxidation of SO2 to H2SO4 in the atmosphere is believed to involve the reaction of SO3 with water. It is commonly assumed that this is an important step leading to homogeneous nucleation of H2SO4 aerosol particles. Heterogeneous chemistry on sulfuric acid aerosols regulate much of the ozone photochemistry in the lower stratosphere and are also believed to have significant effect on the climate. Understanding aerosol loading requires a detailed knowledge of the stratospheric sulfur budget, including its oxidation kinetics. Here we present results of a laboratory project studying a key step in the oxidation process, the homogeneous reaction between SO3 and H2O vapor. Kinetic measurements are performed in a high-pressure turbulent fast-flow reactor (fabricated at MIT) which minimizes heterogeneous loss of SO3 on reactorwalls. The rate of decay of SO3 and the appearance of H2SO4 is monitored in the presence of excess water vapor. Gas phase reactants and products are detected via an atmospheric pressure chemical ionization mass spectrometer which is coupled to the exit of the flow reactor. Sulfuric acid nucleation studies can also be performed using the turbulent flow reactor. Initial measurements using a particle detector (based on Mie scattering) showed that aerosol formation and particle size distribution are controlled by varying the SO3/H2O gas ratio and the reactor temperature. Results for the reaction SO3J+ H2O show a second order dependence in water vapor density and a strong negative temperature dependence. The results, measured in the range -30C to +95C, imply that an SO3.H2O adduct and/or a water dimer species is likely involved in the reaction mechanism. Results of recent theoretical calculations on the SO3 + H2O system also support the finding that two water molecules are involved. Implications for the gas phase production of sulfuric acid in the atmosphere will be discussed.

  2. Neutrino physics with multi-ton scale liquid xenon detectors

    SciTech Connect (OSTI)

    Baudis, L.; Ferella, A.; Kish, A.; Manalaysay, A.; Undagoitia, T. Marrodán; Schumann, M., E-mail: laura.baudis@physik.uzh.ch, E-mail: alfredo.ferella@lngs.infn.it, E-mail: alexkish@physik.uzh.ch, E-mail: aaronm@ucdavis.edu, E-mail: marrodan@mpi-hd.mpg.de, E-mail: marc.schumann@lhep.unibe.ch [Physik Institut, University of Zürich, Winterthurerstrasse 190, Zürich, CH-8057 (Switzerland)

    2014-01-01

    We study the sensitivity of large-scale xenon detectors to low-energy solar neutrinos, to coherent neutrino-nucleus scattering and to neutrinoless double beta decay. As a concrete example, we consider the xenon part of the proposed DARWIN (Dark Matter WIMP Search with Noble Liquids) experiment. We perform detailed Monte Carlo simulations of the expected backgrounds, considering realistic energy resolutions and thresholds in the detector. In a low-energy window of 2–30 keV, where the sensitivity to solar pp and {sup 7}Be-neutrinos is highest, an integrated pp-neutrino rate of 5900 events can be reached in a fiducial mass of 14 tons of natural xenon, after 5 years of data. The pp-neutrino flux could thus be measured with a statistical uncertainty around 1%, reaching the precision of solar model predictions. These low-energy solar neutrinos will be the limiting background to the dark matter search channel for WIMP-nucleon cross sections below ? 2 × 10{sup ?48} cm{sup 2} and WIMP masses around 50 GeV?c{sup ?2}, for an assumed 99.5% rejection of electronic recoils due to elastic neutrino-electron scatters. Nuclear recoils from coherent scattering of solar neutrinos will limit the sensitivity to WIMP masses below ? 6 GeV?c{sup ?2} to cross sections above ? 4 × 10{sup ?45}cm{sup 2}. DARWIN could reach a competitive half-life sensitivity of 5.6 × 10{sup 26} y to the neutrinoless double beta decay of {sup 136}Xe after 5 years of data, using 6 tons of natural xenon in the central detector region.

  3. Catalyst for the reduction of sulfur dioxide to elemental sulfur

    DOE Patents [OSTI]

    Jin, Y.; Yu, Q.; Chang, S.G.

    1996-02-27

    The inventive catalysts allow for the reduction of sulfur dioxide to elemental sulfur in smokestack scrubber environments. The catalysts have a very high sulfur yield of over 90% and space velocity of 10,000 h{sup {minus}1}. They also have the capacity to convert waste gases generated during the initial conversion into elemental sulfur. The catalysts have inexpensive components, and are inexpensive to produce. The net impact of the invention is to make this technology practically available to industrial applications. 21 figs.

  4. Method of removing and recovering elemental sulfur from highly reducing gas streams containing sulfur gases

    DOE Patents [OSTI]

    Gangwal, Santosh K.; Nikolopoulos, Apostolos A.; Dorchak, Thomas P.; Dorchak, Mary Anne

    2005-11-08

    A method is provided for removal of sulfur gases and recovery of elemental sulfur from sulfur gas containing supply streams, such as syngas or coal gas, by contacting the supply stream with a catalyst, that is either an activated carbon or an oxide based catalyst, and an oxidant, such as sulfur dioxide, in a reaction medium such as molten sulfur, to convert the sulfur gases in the supply stream to elemental sulfur, and recovering the elemental sulfur by separation from the reaction medium.

  5. Evaluation of Sulfur in Syngas

    SciTech Connect (OSTI)

    None

    2006-04-01

    This project will define the options and costs at different scales of technology that can be used to remove sulfur from syngas.

  6. Process for removing sulfur from sulfur-containing gases

    DOE Patents [OSTI]

    Rochelle, Gary T. (Austin, TX); Jozewicz, Wojciech (Chapel Hill, NC)

    1989-01-01

    The present disclosure relates to improved processes for treating hot sulfur-containing flue gas to remove sulfur therefrom. Processes in accorda The government may own certain rights in the present invention pursuant to EPA Cooperative Agreement CR 81-1531.

  7. Removal of 1,082-Ton Reactor Among Richland Operations Office...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    from groundwater across the site ahead of schedule and pumped a record volume of water through treatment facilities to remove contamination, with more than 130 tons of...

  8. U.S. Billion-Ton Update. Biomass Supply for a Bioenergy and Bioproducts Industry

    SciTech Connect (OSTI)

    none,

    2011-08-01

    This report is an update to the 2005 Billion-Ton Study that addresses shotcomings and questions that arose from the original report..

  9. U.S. Billion-Ton Update: Biomass Supply for a Bioenergy and Bioproduct...

    Broader source: Energy.gov (indexed) [DOE]

    2005 report, "Biomass as a Feedstock for a Bioenergy and Bioproducts Industry: The Technical Feasibility of a Billion-Ton Annual Supply" billiontonupdate.pdf More Documents &...

  10. Generalized Fubini-Study Metric and Fisher Information Metric

    E-Print Network [OSTI]

    Debasis Mondal

    2015-03-13

    We provide an experimentally measurable local gauge $U(1)$ invariant Fubini-Study (FS) metric for mixed states. Like the FS metric for pure states, it also captures only the quantum part of the uncertainty in the evolution Hamiltonian. We show that this satisfies the quantum Cramer-Rao bound and thus arrive at a more general and measurable bound. Upon imposing the monotonicity condition, it reduces to the square-root derivative quantum Fisher Information. We show that on the Fisher information metric space dynamical phase is zero. A relation between square root derivative and logarithmic derivative is formulated such that both give the same Fisher information. We generalize the Fubini-Study metric for mixed states further and arrive at a set of Fubini-Study metric---called $\\alpha$ metric. This newly defined $\\alpha$ metric also satisfies the Cramer-Rao bound. Again by imposing the monotonicity condition on this metric, we derive the monotone $\\alpha$ metric. It reduces to the Fisher information metric for $\\alpha=1$.

  11. Volume efficient sodium sulfur battery

    DOE Patents [OSTI]

    Mikkor, Mati (Ann Arbor, MI)

    1980-01-01

    In accordance with the teachings of this specification, a sodium sulfur battery is formed as follows. A plurality of box shaped sulfur electrodes are provided, the outer surfaces of which are defined by an electrolyte material. Each of the electrodes have length and width dimensions substantially greater than the thicknesses thereof as well as upwardly facing surface and a downwardly facing surface. An electrode structure is contained in each of the sulfur electrodes. A holding structure is provided for holding the plurality of sulfur electrodes in a stacked condition with the upwardly facing surface of one sulfur electrode in facing relationship to the downwardly facing surface of another sulfur electrode thereabove. A small thickness dimension separates each of the stacked electrodes thereby defining between each pair of sulfur electrodes a volume which receives the sodium reactant. A reservoir is provided for containing sodium. A manifold structure interconnects the volumes between the sulfur electrodes and the reservoir. A metering structure controls the flow of sodium between the reservoir and the manifold structure.

  12. Quotients of Metric Spaces

    E-Print Network [OSTI]

    Herman, Robert A.

    1968-01-01

    . PRELIMINARIES 1 CHAPTER II . SFACBS IN WHICH SEQUENCES SUFFICE 6 CHAPTER III . QUOTIENTS OF SEPARABLE METRIC SPACES Ik CHAPTER IV. GENERAL QUOTIENT SPACES 25 CHAPTER V. CLOSED QUOTIENT MAPS 35 CHAPTER VI. OPEN QUOTIENT MAPS 50 CHAPTER VII. OPEN AND CLOSED... QUOTIENT MAPS 55 CHAPTER VIII. ANOTHER RESULT 6l BIBLIOGRAPHY 65 CHAPTER I. PRELIMINARIES We begin by stating some basic definitions and theorems. Definition 1 . 1 ; Let f be a function from a topological space X onto a set Y. Then the quotient...

  13. ARM - 2009 Performance Metrics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.TheoryTuesday, August 10, 20102016 NewsUsers' Executive09 I N9 Performance Metrics

  14. The Space of Metric Spaces

    E-Print Network [OSTI]

    *D. J. Kelleher

    2013-11-16

    The Space of Metric Spaces. *D. J. Kelleher1. 1Department of Mathematics. University of Connecticut. UConn— SIGMA Seminar — Fall 2013. D. J. Kelleher.

  15. August 2003 IT SECURITY METRICS

    E-Print Network [OSTI]

    August 2003 IT SECURITY METRICS Elizabeth B. Lennon, Editor Information Technology Laboratory approach to measuring information security. Evaluating security at the sys tem level, IT security metrics and techniques contained in NIST SP 800-26, Security Self-Assessment Guide for Information Technology Systems

  16. Method of preparing graphene-sulfur nanocomposites for rechargeable...

    Office of Scientific and Technical Information (OSTI)

    Method of preparing graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes Citation Details In-Document Search Title: Method of preparing graphene-sulfur...

  17. Moab Project Disposes 2 Million Tons of Uranium Mill Tailings with Recovery Act Funds

    Broader source: Energy.gov [DOE]

    The Moab Uranium Mill Tailings Remedial Action Project reached its primary American Recovery and Reinvestment Act milestone ahead of schedule on Wednesday with the disposal of 2 million tons of...

  18. Delivering Tons to the Register: Energy Efficient Design and Operation of Residential Cooling Systems

    E-Print Network [OSTI]

    Delivering Tons to the Register: Energy Efficient Design and Operation of Residential Cooling Systems Jeffrey Siegel, Lawrence Berkeley National Laboratory Iain Walker, Lawrence Berkeley National and air conditioner performance. These parameters included placing the entire air conditioning system

  19. Experimental and computational investigations of sulfur-resistant bimetallic catalysts for reforming of biomass gasification products

    SciTech Connect (OSTI)

    Rangan, Meghana; Yung, Matthew M.; Medlin, J. William (NREL); (Colorado)

    2011-11-17

    A combination of density functional theory (DFT) calculations and experimental studies of supported catalysts was used to identify H{sub 2}S-resistant biomass gasification product reforming catalysts. DFT calculations were used to search for bimetallic, nickel-based (1 1 1) surfaces with lower sulfur adsorption energies and enhanced ethylene adsorption energies. These metrics were used as predictors for H{sub 2}S resistance and activity toward steam reforming of ethylene, respectively. Relative to Ni, DFT studies found that the Ni/Sn surface alloy exhibited enhanced sulfur resistance and the Ni/Ru system exhibited an improved ethylene binding energy with a small increase in sulfur binding energy. A series of supported bimetallic nickel catalysts was prepared and screened under model ethylene reforming conditions and simulated biomass tar reforming conditions. The observed experimental trends in activity were consistent with theoretical predictions, with observed reforming activities in the order Ni/Ru > Ni > Ni/Sn. Interestingly, Ni/Ru showed a high level of resistance to sulfur poisoning compared with Ni. This sulfur resistance can be partly explained by trends in sulfur versus ethylene binding energy at different types of sites across the bimetallic surface.

  20. Daylight metrics and energy savings

    SciTech Connect (OSTI)

    Mardaljevic, John; Heschong, Lisa; Lee, Eleanor

    2009-12-31

    The drive towards sustainable, low-energy buildings has increased the need for simple, yet accurate methods to evaluate whether a daylit building meets minimum standards for energy and human comfort performance. Current metrics do not account for the temporal and spatial aspects of daylight, nor of occupants comfort or interventions. This paper reviews the historical basis of current compliance methods for achieving daylit buildings, proposes a technical basis for development of better metrics, and provides two case study examples to stimulate dialogue on how metrics can be applied in a practical, real-world context.

  1. Module 6 - Metrics, Performance Measurements and Forecasting...

    Broader source: Energy.gov (indexed) [DOE]

    the metrics and performance measurement tools used in Earned Value. This module reviews metrics such as cost and schedule variance along with cost and schedule performance indices....

  2. Microsoft Word - QER Resilience Metrics - Technical Workshp ...

    Broader source: Energy.gov (indexed) [DOE]

    resiliency metrics for the energy sector and use cases o The framing of a resilience roadmap, and the implication and consequences of introducing new energy resilience metrics...

  3. On the Origin of Sulfur

    E-Print Network [OSTI]

    Nils Ryde; David L. Lambert

    2005-10-05

    We present our work on the halo evolution of sulfur, based on observations of the S I lines around 9220 A for ten stars for which the S abundance was obtained previously from much weaker S I lines at 8694 A. We cannot confirm the rise and the high [S/Fe] abundances for low [Fe/H], as claimed in the literature from analysis of the 8694 A lines. The reasons for claims of an increase in [S/Fe] with decreasing [Fe/H] are probably twofold: uncertainties in the measurements of the weak 8694 A lines, and systematic errors in metallicity determinations from Fe I lines. The near-infrared sulfur triplet at 9212.9, 9228.1, and 9237.5 A are preferred for an abundance analysis of sulfur for metal-poor stars. Our work was presented in full by Ryde & Lambert (2004).

  4. Segmental alternations and metrical theory

    E-Print Network [OSTI]

    Vaysman, Olga

    2009-01-01

    This dissertation focuses on phonological alternations that are influenced or constrained by word-internal prosody, i.e. prominence and foot structure, and what these alternations can tell us about metrical theory. Detailed ...

  5. Normalization of Process Safety Metrics 

    E-Print Network [OSTI]

    Wang, Mengtian

    2012-10-19

    and organizational risks, there is an emerging need to evaluate the process safety implementation across an organization through measurements. Thus, the process safety metric is applied as a powerful tool that measures safety activities, status, and performance...

  6. Phantom Metrics With Killing Spinors

    E-Print Network [OSTI]

    Sabra, W A

    2015-01-01

    We study metric solutions of Einstein-anti-Maxwell theory admitting Killing spinors. The analogue of the IWP metric which admits a space-like Killing vector is found and is expressed in terms of a complex function satisfying the wave equation in flat (2+1)-dimensional space-time. As examples, electric and magnetic Kasner spaces are constructed by allowing the solution to depend only on the time coordinate. Euclidean solutions are also presented.

  7. Two stage sorption of sulfur compounds

    DOE Patents [OSTI]

    Moore, William E. (Manassas, VA)

    1992-01-01

    A two stage method for reducing the sulfur content of exhaust gases is disclosed. Alkali- or alkaline-earth-based sorbent is totally or partially vaporized and introduced into a sulfur-containing gas stream. The activated sorbent can be introduced in the reaction zone or the exhaust gases of a combustor or a gasifier. High efficiencies of sulfur removal can be achieved.

  8. Safety considerations for the use of sulfur in sulfur-modified pavement materials 

    E-Print Network [OSTI]

    Jacobs, Carolyn Yuriko

    1980-01-01

    Liquid Sulfur Page v111 ix 33 33 35 IV Symptoms of Poisoning . First Aid SULFUR IN THE PAVING INDUSTRY General Sand-Asphalt-Sulfur Pavements (SAS) ', , Sulfur-Extended Asphalt Pavements (SEA) Sulfur Concrete EVALUATION OF RISKS AND SAFETY... RECOMMENDATIONS General Stationary Sources Mobile Sources Maintenance 40 41 43 43 44 45 46 Hot-Mix Recycling VI EMISSIONS MONITORING METHODS General Area Monitoring - Continuous Samplina Short Term Sampling (" Grab" Sampling) Personnel Monitoring...

  9. The 1990 Clean Air Act and the implicit price of sulfur in coal - article no. 41

    SciTech Connect (OSTI)

    Lange, I.; Bellas, A.S. [US EPA, Washington, DC (United States)

    2007-07-01

    Prior to implementation of the 1990 Clean Air Act Amendments (CAAA), many estimates of the marginal cost of SO{sub 2} abatement were provided to guide policy makers. Numerous studies estimated the marginal cost of abatement to be between $250 and $760 per ton, though permits initially traded well below $200 and remained below $220 until 2004. We use a fixed effects estimator and a hedonic price model of coal purchases in order to determine the implicit price of sulfur. Data on contract coal purchases are divided into regulatory regimes based on when the contract was signed or re-negotiated. We find that purchases by Phase I plants made under contracts signed or re-negotiated after the passage of the 1990 CAAA show an implicit price of SO{sub 2} of approximately $50 per ton, an amount much closer to the eventual permit price. The implicit market price of sulfur seems to have revealed better information than did the calculations of industry experts.

  10. Horizon thermodynamics and composite metrics

    E-Print Network [OSTI]

    Lorenzo Sindoni

    2012-11-12

    We examine the conditions under which the thermodynamic behaviour of gravity can be explained within an emergent gravity scenario, where the metric is defined as a composite operator. We show that due to the availability of a boundary of a boundary principle for the quantum effective action, Clausius-like relations can always be constructed. Hence, any true explanation of the thermodynamic nature of the metric tensor has to be referred to an equilibration process, associated to the presence of an H-theorem, possibly driven by decoherence induced by the pregeometric degrees of freedom, and their entanglement with the geometric ones.

  11. Planning for the 400,000 tons/year AISI ironmaking demonstration plant

    SciTech Connect (OSTI)

    Aukrust, E. (LTV Steel Corp., Cleveland, OH (United States). AISI Direct Steelmaking Program)

    1993-01-01

    The American Iron and Steel Institute (AISI) has formulated a four-year program to design, construct, and operate a 400,000 net ton per year ironmaking demonstration plant. The plant will employ the coal-based ironmaking process developed under a 1989 cooperative agreement with DOE. AISI will manage the design and construction to be completed in the first two years and operate the plant for the second two years with a variety or ores, coals, and fluxes. Campaigns of increasing length are planned to optimize operations. After successful operation, the plant will be taken over by the host company. Results of studies to date indicate that, on a commercial scale, the AISI process will use 27% less energy and have variable operating costs $10 per ton lower and capital costs of $160 per annual ton, compared to the $250 per annual ton rebuild cost for the coke oven-blast furnace process it will replace. The process will enable the domestic steel industry to become more competitive by reducing its capital and operating cost. Furthermore, by eliminating the pollution problems associated with coke production and by completely enclosing the smelting reactions, this process represents a major step towards an environmentally friendly steel industry.

  12. 2 million tons per year: A performing biofuels supply chain for

    E-Print Network [OSTI]

    1 2 million tons per year: A performing biofuels supply chain for EU aviation NOTE It is understood that in the context of this text the term "biofuel(s) use in aviation" categorically implies "sustainably produced biofuel(s)" according to the EU legislation. June 2011 #12;2 This technical paper was drafted

  13. A Concept for a Scalable 2 kTon Liquid Argon TPC Detector for Astroparticle Physics

    E-Print Network [OSTI]

    D. B. Cline; F. Sergiampietri

    2005-09-14

    This paper describes the results of a study on the general lines, main construction criteria, crucial points, parameters and required preliminary R&D activities for the construction of a LAr (liquid argon) imaging detector with active mass in the 10-100 kTon range. Such detectors are crucial for supernova detection, proton decay, LBL neutrino physics and other astroparticle physics applications.

  14. A Concept for a Scalable 2 kTon Liquid Argon TPC Detector for Astroparticle Physics

    E-Print Network [OSTI]

    McDonald, Kirk

    astroparticle physics applications. 1 Introduction The on-surface test of the 300-ton ICARUS module made the detection technique, that even with some possible improvements or changes is the well-established ICARUS one is optimized. A cylindrical vessel with the height equal to the diameter has the same S/V ratio than

  15. Agility metric sensitivity using linear error theory 

    E-Print Network [OSTI]

    Smith, David Matthew

    2000-01-01

    Aircraft agility metrics have been proposed for use to measure the performance and capability of aircraft onboard while in-flight. The sensitivity of these metrics to various types of errors and uncertainties is not ...

  16. Contribution of isotopologue self-shielding to sulfur mass-independent fractionation during sulfur dioxide photolysis

    E-Print Network [OSTI]

    Lyons, J. R.

    Signatures of sulfur mass-independent fractionation (S-MIF) are observed for sulfur minerals in Archean rocks, and for modern stratospheric sulfate aerosols (SSA) deposited in polar ice. Ultraviolet light photolysis of ...

  17. HYDROCARBON AND SULFUR SENSORS FOR SOFC SYSTEMS

    SciTech Connect (OSTI)

    A.M. Azad; Chris Holt; Todd Lesousky; Scott Swartz

    2003-11-01

    The following report summarizes work conducted during the Phase I program Hydrocarbon and Sulfur Sensors for SOFC Systems under contract No. DE-FC26-02NT41576. For the SOFC application, sensors are required to monitor hydrocarbons and sulfur in order to increase the operation life of SOFC components. This report discusses the development of two such sensors, one based on thick film approach for sulfur monitoring and the second galvanic based for hydrocarbon monitoring.

  18. Definition of GPRA08 benefits metrics

    SciTech Connect (OSTI)

    None, None

    2009-01-18

    Background information for the FY 2007 GPRA methodology review on the definitions of GPRA08 benefits metrics.

  19. U.S. Billion-Ton Update: Biomass Supply for a Bioenergy and Bioproducts Industry

    SciTech Connect (OSTI)

    Downing, Mark; Eaton, Laurence M; Graham, Robin Lambert; Langholtz, Matthew H; Perlack, Robert D; Turhollow Jr, Anthony F; Stokes, Bryce; Brandt, Craig C

    2011-08-01

    The report, Biomass as Feedstock for a Bioenergy and Bioproducts Industry: The Technical Feasibility of a Billion-Ton Annual Supply (generally referred to as the Billion-Ton Study or 2005 BTS), was an estimate of 'potential' biomass based on numerous assumptions about current and future inventory, production capacity, availability, and technology. The analysis was made to determine if conterminous U.S. agriculture and forestry resources had the capability to produce at least one billion dry tons of sustainable biomass annually to displace 30% or more of the nation's present petroleum consumption. An effort was made to use conservative estimates to assure confidence in having sufficient supply to reach the goal. The potential biomass was projected to be reasonably available around mid-century when large-scale biorefineries are likely to exist. The study emphasized primary sources of forest- and agriculture-derived biomass, such as logging residues, fuel treatment thinnings, crop residues, and perennially grown grasses and trees. These primary sources have the greatest potential to supply large, reliable, and sustainable quantities of biomass. While the primary sources were emphasized, estimates of secondary residue and tertiary waste resources of biomass were also provided. The original Billion-Ton Resource Assessment, published in 2005, was divided into two parts-forest-derived resources and agriculture-derived resources. The forest resources included residues produced during the harvesting of merchantable timber, forest residues, and small-diameter trees that could become available through initiatives to reduce fire hazards and improve forest health; forest residues from land conversion; fuelwood extracted from forests; residues generated at primary forest product processing mills; and urban wood wastes, municipal solid wastes (MSW), and construction and demolition (C&D) debris. For these forest resources, only residues, wastes, and small-diameter trees were considered. The 2005 BTS did not attempt to include any wood that would normally be used for higher-valued products (e.g., pulpwood) that could potentially shift to bioenergy applications. This would have required a separate economic analysis, which was not part of the 2005 BTS. The agriculture resources in the 2005 BTS included grains used for biofuels production; crop residues derived primarily from corn, wheat, and small grains; and animal manures and other residues. The cropland resource analysis also included estimates of perennial energy crops (e.g., herbaceous grasses, such as switchgrass, woody crops like hybrid poplar, as well as willow grown under short rotations and more intensive management than conventional plantation forests). Woody crops were included under cropland resources because it was assumed that they would be grown on a combination of cropland and pasture rather than forestland. In the 2005 BTS, current resource availability was estimated at 278 million dry tons annually from forestlands and slightly more than 194 million dry tons annually from croplands. These annual quantities increase to about 370 million dry tons from forestlands and to nearly 1 billion dry tons from croplands under scenario conditions of high-yield growth and large-scale plantings of perennial grasses and woody tree crops. This high-yield scenario reflects a mid-century timescale ({approx}2040-2050). Under conditions of lower-yield growth, estimated resource potential was projected to be about 320 and 580 million dry tons for forest and cropland biomass, respectively. As noted earlier, the 2005 BTS emphasized the primary resources (agricultural and forestry residues and energy crops) because they represent nearly 80% of the long-term resource potential. Since publication of the BTS in April 2005, there have been some rather dramatic changes in energy markets. In fact, just prior to the actual publication of the BTS, world oil prices started to increase as a result of a burgeoning worldwide demand and concerns about long-term supplies. By the end of the summer, oil pri

  20. Hybrid metric-Palatini gravity

    E-Print Network [OSTI]

    Capozziello, Salvatore; Koivisto, Tomi S; Lobo, Francisco S N; Olmo, Gonzalo J

    2015-01-01

    Recently, the phenomenology of f(R) gravity has been scrutinized motivated by the possibility to account for the self-accelerated cosmic expansion without invoking dark energy sources. Besides, this kind of modified gravity is capable of addressing the dynamics of several self-gravitating systems alternatively to the presence of dark matter. It has been established that both metric and Palatini versions of these theories have interesting features but also manifest severe and different downsides. A hybrid combination of theories, containing elements from both these two formalisms, turns out to be also very successful accounting for the observed phenomenology and is able to avoid some drawbacks of the original approaches. This article reviews the formulation of this hybrid metric-Palatini approach and its main achievements in passing the local tests and in applications to astrophysical and cosmological scenarios, where it provides a unified approach to the problems of dark energy and dark matter.

  1. Multi-Metric Sustainability Analysis

    SciTech Connect (OSTI)

    Cowlin, S.; Heimiller, D.; Macknick, J.; Mann, M.; Pless, J.; Munoz, D.

    2014-12-01

    A readily accessible framework that allows for evaluating impacts and comparing tradeoffs among factors in energy policy, expansion planning, and investment decision making is lacking. Recognizing this, the Joint Institute for Strategic Energy Analysis (JISEA) funded an exploration of multi-metric sustainability analysis (MMSA) to provide energy decision makers with a means to make more comprehensive comparisons of energy technologies. The resulting MMSA tool lets decision makers simultaneously compare technologies and potential deployment locations.

  2. How well will ton-scale dark matter direct detection experiments constrain minimal supersymmetry?

    SciTech Connect (OSTI)

    Akrami, Yashar; Savage, Christopher; Scott, Pat; Conrad, Jan; Edsjö, Joakim E-mail: savage@fysik.su.se E-mail: conrad@fysik.su.se

    2011-04-01

    Weakly interacting massive particles (WIMPs) are amongst the most interesting dark matter (DM) candidates. Many DM candidates naturally arise in theories beyond the standard model (SM) of particle physics, like weak-scale supersymmetry (SUSY). Experiments aim to detect WIMPs by scattering, annihilation or direct production, and thereby determine the underlying theory to which they belong, along with its parameters. Here we examine the prospects for further constraining the Constrained Minimal Supersymmetric Standard Model (CMSSM) with future ton-scale direct detection experiments. We consider ton-scale extrapolations of three current experiments: CDMS, XENON and COUPP, with 1000 kg-years of raw exposure each. We assume energy resolutions, energy ranges and efficiencies similar to the current versions of the experiments, and include backgrounds at target levels. Our analysis is based on full likelihood constructions for the experiments. We also take into account present uncertainties on hadronic matrix elements for neutralino-quark couplings, and on halo model parameters. We generate synthetic data based on four benchmark points and scan over the CMSSM parameter space using nested sampling. We construct both Bayesian posterior PDFs and frequentist profile likelihoods for the model parameters, as well as the mass and various cross-sections of the lightest neutralino. Future ton-scale experiments will help substantially in constraining supersymmetry, especially when results of experiments primarily targeting spin-dependent nuclear scattering are combined with those directed more toward spin-independent interactions.

  3. How well will ton-scale dark matter direct detection experiments constrain minimal supersymmetry?

    E-Print Network [OSTI]

    Yashar Akrami; Christopher Savage; Pat Scott; Jan Conrad; Joakim Edsjö

    2011-04-18

    Weakly interacting massive particles (WIMPs) are amongst the most interesting dark matter (DM) candidates. Many DM candidates naturally arise in theories beyond the standard model (SM) of particle physics, like weak-scale supersymmetry (SUSY). Experiments aim to detect WIMPs by scattering, annihilation or direct production, and thereby determine the underlying theory to which they belong, along with its parameters. Here we examine the prospects for further constraining the Constrained Minimal Supersymmetric Standard Model (CMSSM) with future ton-scale direct detection experiments. We consider ton-scale extrapolations of three current experiments: CDMS, XENON and COUPP, with 1000 kg-years of raw exposure each. We assume energy resolutions, energy ranges and efficiencies similar to the current versions of the experiments, and include backgrounds at target levels. Our analysis is based on full likelihood constructions for the experiments. We also take into account present uncertainties on hadronic matrix elements for neutralino-quark couplings, and on halo model parameters. We generate synthetic data based on four benchmark points and scan over the CMSSM parameter space using nested sampling. We construct both Bayesian posterior PDFs and frequentist profile likelihoods for the model parameters, as well as the mass and various cross-sections of the lightest neutralino. Future ton-scale experiments will help substantially in constraining supersymmetry, especially when results of experiments primarily targeting spin-dependent nuclear scattering are combined with those directed more toward spin-independent interactions.

  4. Sulfur oxide adsorbents and emissions control

    DOE Patents [OSTI]

    Li, Liyu (Richland, WA); King, David L. (Richland, WA)

    2006-12-26

    High capacity sulfur oxide absorbents utilizing manganese-based octahedral molecular sieve (Mn--OMS) materials are disclosed. An emissions reduction system for a combustion exhaust includes a scrubber 24 containing these high capacity sulfur oxide absorbents located upstream from a NOX filter 26 or particulate trap.

  5. Microbial Architecture of Environmental Sulfur Processes: A

    E-Print Network [OSTI]

    Hitchcock, Adam P.

    potential impacts on water quality, including acid generation in acid mine drainage (AMD) environments, 2009. Accepted July 9, 2009. Microbial oxidation of sulfur-rich mining waste materials drives acid mine drainage (AMD) and affects the global sulfur biogeochemical cycle. The generation of AMD is a complex

  6. Additives and Cathode Materials for High-Energy Lithium Sulfur...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries 2013 DOE Hydrogen and Fuel Cells...

  7. Method of removal of sulfur from coal and petroleum products

    DOE Patents [OSTI]

    Verkade, John G. (Ames, IA); Mohan, Thyagarajan (Ames, IA); Angelici, Robert J. (Ames, IA)

    1995-01-01

    A method for the removal of sulfur from sulfur-bearing materials such as coal and petroleum products using organophosphine and organophosphite compounds is provided.

  8. (Data in metric tons, unless noted) Domestic Production and Use: No indium was recovered from ores in the United States in 1995. Domestic indium

    E-Print Network [OSTI]

    from ores in the United States in 1995. Domestic indium production was derived from the upgrading producers of indium metal and indium products in 1995. Several firms produced high-purity indium shapes detectors, high-speed transistors, and high-efficiency photovoltaic devices. Estimated uses in 1995 were

  9. Comparing Resource Adequacy Metrics: Preprint

    SciTech Connect (OSTI)

    Ibanez, E.; Milligan, M.

    2014-09-01

    As the penetration of variable generation (wind and solar) increases around the world, there is an accompanying growing interest and importance in accurately assessing the contribution that these resources can make toward planning reserve. This contribution, also known as the capacity credit or capacity value of the resource, is best quantified by using a probabilistic measure of overall resource adequacy. In recognizing the variable nature of these renewable resources, there has been interest in exploring the use of reliability metrics other than loss of load expectation. In this paper, we undertake some comparisons using data from the Western Electricity Coordinating Council in the western United States.

  10. Metric Signature Transitions in Optical Metamaterials

    E-Print Network [OSTI]

    Igor I. Smolyaninov; Evgenii E. Narimanov

    2010-07-07

    We demonstrate that the extraordinary waves in indefinite metamaterials experience (- - + +) effective metric signature. During a metric signature change transition in such a metamaterial, a Minkowski space-time is "created" together with large number of particles populating this space-time. Such metamaterial models provide a table top realization of metric signature change events suggested to occur in Bose-Einstein condensates and quantum gravity theories.

  11. Catalyst for elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, M.; Liu, W.

    1995-01-24

    A catalytic reduction process is described for the direct recovery of elemental sulfur from various SO[sub 2]-containing industrial gas streams. The catalytic process provides high activity and selectivity, as well as stability in the reaction atmosphere, for the reduction of SO[sub 2] to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over a metal oxide composite catalyst having one of the following empirical formulas: [(FO[sub 2])[sub 1[minus]n](RO)[sub n

  12. Performance Metrics Tiers | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Tiers The performance metrics defined by the Commercial Buildings Integration Program offer different tiers of information to address the needs of various users. On this page you...

  13. Defining a Standard Metric for Electricity Savings

    E-Print Network [OSTI]

    Koomey, Jonathan

    2009-01-01

    1991. The Potential for Electricity Efficiency Improvementswww.eia.doe.gov/cneaf/electricity/page/eia860.html>. FigureA STANDARD METRIC FOR ELECTRICITY SAVINGS Jonathan Koomey*,

  14. Three-dimensional metrics as deformations of a constant curvature metric

    E-Print Network [OSTI]

    B. Coll; J. Llosa; D. Soler

    2001-04-23

    Any three-dimensional Riemannian metric can be locally obtained by deforming a constant curvature metric along one direction. The general interest of this result, both in geometry and physics, and related open problems are stressed.

  15. Method for reducing the sulfur content of a sulfur-containing hydrocarbon stream

    SciTech Connect (OSTI)

    Mahajan, Devinder

    2004-12-28

    The sulfur content of a liquid hydrocarbon stream is reduced under mild conditions by contracting a sulfur-containing liquid hydrocarbon stream with transition metal particles containing the transition metal in a zero oxidation state under conditions sufficient to provide a hydrocarbon product having a reduced sulfur content and metal sulfide particles. The transition metal particles can be produced in situ by adding a transition metal precursor, e.g., a transition metal carbonyl compound, to the sulfur-containing liquid feed stream and sonicating the feed steam/transition metal precursor combination under conditions sufficient to produce the transition metal particles.

  16. Process for removing sulfur from coal

    DOE Patents [OSTI]

    Aida, T.; Squires, T.G.; Venier, C.G.

    1983-08-11

    A process is disclosed for the removal of divalent organic and inorganic sulfur compounds from coal and other carbonaceous material. A slurry of pulverized carbonaceous material is contacted with an electrophilic oxidant which selectively oxidizes the divalent organic and inorganic compounds to trivalent and tetravalent compounds. The carbonaceous material is then contacted with a molten caustic which dissolves the oxidized sulfur compounds away from the hydrocarbon matrix.

  17. Conical Kähler–Einstein Metrics Revisited

    E-Print Network [OSTI]

    2014-08-08

    From now on in this paper, we assume X is a smooth Fano manifold, and D is a ... not unique, we can still identify the correct limit Kähler–Einstein metric in the moduli space. ... implies that there is no Kähler–Einstein metric on P2 which bends.

  18. Gathering Text Entry Metrics on Android Devices

    E-Print Network [OSTI]

    MacKenzie, Scott

    Gathering Text Entry Metrics on Android Devices Abstract We developed an application to gather text entry speed and accuracy metrics on Android devices. This paper details the features of the application, Android OS ACM Classification Keywords H.5.2 Information interfaces and presentation (e.g., HCI): User

  19. A Physics of Bounded Metric Spaces

    E-Print Network [OSTI]

    Pierre Peretto

    1997-06-25

    We consider the possibility of obtaining emergent properties of physical spaces endowed with structures analogous to that of collective models put forward by classical statistical physics. We show that, assuming that a so-called "metric scale" does exist, one can indeed recover a number of properties of physical spaces such as the Minkowski metric, the relativistic quantum dynamics and the electroweak theory.

  20. Quality Metrics for Business Process Models

    E-Print Network [OSTI]

    van der Aalst, Wil

    1 Quality Metrics for Business Process Models Irene Vanderfeesten1 , Jorge Cardoso2 , Jan Mendling3-Koivisto, 2001). This chapter elaborates on the importance of quality metrics for business process modeling to this composi- tional structure, a business process model consists of activities, each of which con- tains

  1. Smart Grid Status and Metrics Report Appendices

    SciTech Connect (OSTI)

    Balducci, Patrick J.; Antonopoulos, Chrissi A.; Clements, Samuel L.; Gorrissen, Willy J.; Kirkham, Harold; Ruiz, Kathleen A.; Smith, David L.; Weimar, Mark R.; Gardner, Chris; Varney, Jeff

    2014-07-01

    A smart grid uses digital power control and communication technology to improve the reliability, security, flexibility, and efficiency of the electric system, from large generation through the delivery systems to electricity consumers and a growing number of distributed generation and storage resources. To convey progress made in achieving the vision of a smart grid, this report uses a set of six characteristics derived from the National Energy Technology Laboratory Modern Grid Strategy. The Smart Grid Status and Metrics Report defines and examines 21 metrics that collectively provide insight into the grid’s capacity to embody these characteristics. This appendix presents papers covering each of the 21 metrics identified in Section 2.1 of the Smart Grid Status and Metrics Report. These metric papers were prepared in advance of the main body of the report and collectively form its informational backbone.

  2. Bi-metric pseudo-Finslerian spacetimes

    E-Print Network [OSTI]

    Skakala, Jozef

    2010-01-01

    Finsler spacetimes have become increasingly popular within the theoretical physics community over the last two decades. Because physicists need to use pseudo-Finsler structures to describe propagation}of signals, there will be nonzero null vectors in both the tangent and cotangent spaces --- this causes significant problems in that many of the mathematical results normally obtained for "usual" (Euclidean signature) Finsler structures either do not apply, or require significant modifications to their formulation and/or proof. We shall first provide a few basic definitions, explicitly demonstrating the interpretation of bi-metric theories in terms of pseudo-Finsler norms. We shall then discuss the tricky issues that arise when trying to construct an appropriate pseudo-Finsler metric appropriate to bi-metric spacetimes. Whereas in Euclidian signature the construction of the Finsler metric typically fails at the zero vector, in Lorentzian signature the Finsler metric is typically ill-defined on the entire null co...

  3. Sulfur Dioxide Crossover during the Production of Hydrogen and Sulfuric Acid in a PEM Electrolyzer

    E-Print Network [OSTI]

    Weidner, John W.

    Sulfur Dioxide Crossover during the Production of Hydrogen and Sulfuric Acid in a PEM Electrolyzer membrane PEM electrolyzer has been investigated as a viable system for the electrolysis step of the electrolyzer and membranes developed to limit SO2 crossover. © 2009 The Electrochemical Society. DOI: 10

  4. Metrics for border management systems.

    SciTech Connect (OSTI)

    Duggan, Ruth Ann

    2009-07-01

    There are as many unique and disparate manifestations of border systems as there are borders to protect. Border Security is a highly complex system analysis problem with global, regional, national, sector, and border element dimensions for land, water, and air domains. The complexity increases with the multiple, and sometimes conflicting, missions for regulating the flow of people and goods across borders, while securing them for national security. These systems include frontier border surveillance, immigration management and customs functions that must operate in a variety of weather, terrain, operational conditions, cultural constraints, and geopolitical contexts. As part of a Laboratory Directed Research and Development Project 08-684 (Year 1), the team developed a reference framework to decompose this complex system into international/regional, national, and border elements levels covering customs, immigration, and border policing functions. This generalized architecture is relevant to both domestic and international borders. As part of year two of this project (09-1204), the team determined relevant relative measures to better understand border management performance. This paper describes those relative metrics and how they can be used to improve border management systems.

  5. Direct Observation of Sulfur Radicals as Reaction Media in Lithium Sulfur Batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Qiang; Zheng, Jianming; Walter, Eric; Pan, Huilin; Lv, Dongping; Zuo, Pengjian; Chen, Honghao; Deng, Z. D.; Liaw, Bor Y.; Yu, Xiqian; et al

    2015-01-09

    Lithium sulfur (Li-S) battery has been regaining tremendous interest in recent years because of its attractive attributes such as high gravimetric energy, low cost and environmental benignity. However, it is still not conclusively known how polysulfide ring/chain participates in the whole cycling and whether the discharge and charge processes follow the same pathway. Herein, we demonstrate the direct observation of sulfur radicals by using in situ electron paramagnetic resonance (EPR) technique. Based on the concentration changes of sulfur radicals at different potentials and the electrochemical characteristics of the cell, it is revealed that the chemical and electrochemical reactions in Li-Smore »cell are driving each other to proceed through sulfur radicals, leading to two completely different reaction pathways during discharge and charge. The proposed radical mechanism may provide new perspectives to investigate the interactions between sulfur species and the electrolyte, inspiring novel strategies to develop Li-S battery technology.« less

  6. Direct Observation of Sulfur Radicals as Reaction Media in Lithium Sulfur Batteries

    SciTech Connect (OSTI)

    Wang, Qiang [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Zheng, Jianming [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Walter, Eric [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Pan, Huilin [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Lv, Dongping [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Zuo, Pengjian [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Chen, Honghao [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Deng, Z. D. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Liaw, Bor Y. [School of Ocean and Earth Science and Technology, Hawaii Natural Energy Institute, (United States); Yu, Xiqian [Brookhaven National Laboratory, Upton, NY (United States); Yang, Xiao-Qing [Brookhaven National Laboratory, Upton, NY (United States); Zhang, Ji-Guang [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Liu, Jun [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Xiao, Jie [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

    2014-12-09

    Lithium sulfur (Li-S) battery has been regaining tremendous interest in recent years because of its attractive attributes such as high gravimetric energy, low cost and environmental benignity. However, it is still not conclusively known how polysulfide ring/chain participates in the whole cycling and whether the discharge and charge processes follow the same pathway. Herein, we demonstrate the direct observation of sulfur radicals by using in situ electron paramagnetic resonance (EPR) technique. Based on the concentration changes of sulfur radicals at different potentials and the electrochemical characteristics of the cell, it is revealed that the chemical and electrochemical reactions in Li-S cell are driving each other to proceed through sulfur radicals, leading to two completely different reaction pathways during discharge and charge. The proposed radical mechanism may provide new perspectives to investigate the interactions between sulfur species and the electrolyte, inspiring novel strategies to develop Li-S battery technology.

  7. Direct Observation of Sulfur Radicals as Reaction Media in lithium Sulfur Batteries

    SciTech Connect (OSTI)

    Wang, Qiang; Zheng, Jianming; Walter, Eric D.; Pan, Huilin; Lu, Dongping; Zuo, Pengjian; Chen, Honghao; Deng, Zhiqun; Liaw, Bor Yann; Yu, Xiqian; Yang, Xiaoning; Zhang, Jiguang; Liu, Jun; Xiao, Jie

    2014-12-09

    Lithium sulfur (Li-S) battery has been regaining tremendous interest in recent years because of its attractive attributes such as high gravimetric energy, low cost and environmental benignity. However, it is still not conclusively known how polysulfide ring/chain participates in the whole cycling and whether the discharge and charge process follow the same pathway. Herein, we demonstrate the direct observation of sulfur radicals by using in situ electron paramagnetic resonance (EPR) technique. Based on the concentration changes of sulfur radicals at different potentials, it is revealed that the chemical and electrochemical reactions in Li-S cell are driven each other to proceed through sulfur radicals, leading to two completely different reaction pathways during discharge and charge. The proposed radical mechanism may provide new insights to investigate the interactions between sulfur species and the electrolyte, inspiring novel strategies to develop Li-S battery technology.

  8. Cracked lifting lug welds on ten-ton UF{sub 6} cylinders

    SciTech Connect (OSTI)

    Dorning, R.E. [Martin Marietta Energy Systems, Inc., Piketon, OH (United States)

    1991-12-31

    Ten-ton, Type 48X, UF{sub 6} cylinders are used at the Portsmouth Gaseous Diffusion Plant to withdraw enriched uranium hexafluoride from the cascade, transfer enriched uranium hexafluoride to customer cylinders, and feed enriched product to the cascade. To accomplish these activities, the cylinders are lifted by cranes and straddle carriers which engage the cylinder lifting lugs. In August of 1988, weld cracks on two lifting lugs were discovered during preparation to lift a cylinder. The cylinder was rejected and tagged out, and an investigating committee formed to determine the cause of cracking and recommend remedial actions. Further investigation revealed the problem may be general to this class of cylinder in this use cycle. This paper discusses the actions taken at the Portsmouth site to deal with the cracked lifting lug weld problem. The actions include inspection activities, interim corrective actions, metallurgical evaluation of cracked welds, weld repairs, and current monitoring/inspection program.

  9. Ricci Flow of Biaxial Bianchi IX Metrics

    E-Print Network [OSTI]

    G. Holzegel; T. Schmelzer; C. Warnick

    2007-06-12

    We use the Ricci flow with surgery to study four-dimensional SU(2) x U(1)-symmetric metrics on a manifold with fixed boundary given by a squashed 3-sphere. Depending on the initial metric we show that the flow converges to either the Taub-Bolt or the Taub-NUT metric, the latter case potentially requiring surgery at some point in the evolution. The Ricci flow allows us to explore the Euclidean action landscape within this symmetry class. This work extends the recent work of Headrick and Wiseman to more interesting topologies.

  10. Quantum chaos and operator fidelity metric

    E-Print Network [OSTI]

    Paolo Giorda; Paolo Zanardi

    2009-03-06

    We show that the recently introduced operator fidelity metric provides a natural tool to investigate the cross-over to quantum chaotic behaviour. This metric is an information-theoretic measure of the global stability of a unitary evolution against perturbations. We use random matrix theory arguments to conjecture that the operator fidelity metric can be used as an "order parameter" to discriminates phases with regular behaviour from quantum chaotic ones. A numerical study of the onset of chaotic in the Dicke model is given in order to support the conjecture

  11. Energy-Momentum Distribution in Weyl Metrics

    E-Print Network [OSTI]

    M. Sharif; Tasnim Fatima

    2005-07-16

    In this paper, we evaluate energy and momentum density distributions for the Weyl metric by using the well-known prescriptions of Einstein, Landau-Lifshitz, Papaterou and M$\\ddot{o}$ller. The metric under consideration is the static axisymmetric vacuum solution to the Einstein field equations and one of the field equations represents the Laplace equation. Curzon metric is the special case of this spacetime. We find that the energy density is different for each prescription. However, momentum turns out to be constant in each case.

  12. Conceptual Framework for Developing Resilience Metrics for the...

    Office of Environmental Management (EM)

    Conceptual Framework for Developing Resilience Metrics for the Electricity, Oil, and Gas Sectors in the United States Conceptual Framework for Developing Resilience Metrics for the...

  13. Geodesic completeness of diagonal $G_2$ metrics

    E-Print Network [OSTI]

    L. Fernández-Jambrina

    2009-04-10

    In this talk a sufficient condition for a diagonal orthogonally transitive cylindrical $G_2$ metric to be geodesically complete is given. The condition is weak enough to comprise all known diagonal perfect fluid cosmological models that are non-singular.

  14. Thermodynamic motivations of spherically symmetric static metrics

    E-Print Network [OSTI]

    H. Moradpour; S. Nasirimoghadam

    2015-06-14

    Bearing the thermodynamic arguments together with the two definitions of mass in mind, we try to find metrics with spherical symmetry. We consider the adiabatic condition along with the Gong-Wang mass, and evaluate the $g_{rr}$ element which points to a null hypersurface. In addition, we generalize the thermodynamics laws to this hypersurface to find its temperature and thus the corresponding surface gravity which enables us to get a relation for the $g_{tt}$ element. Finally, we investigate the mathematical and physical properties of the discovered metric in the Einstein relativity framework which shows that the primary mentioned null hypersurface is an event horizon. We also show that if one considers the Misner-Sharp mass in the calculations, the Schwarzschild metric will be got. The relationship between the two mass definitions in each metric is studied. The results of considering the geometrical surface gravity are also addressed.

  15. Thermodynamic motivations of spherically symmetric static metrics

    E-Print Network [OSTI]

    Moradpour, H

    2015-01-01

    Bearing the thermodynamic arguments together with the two definitions of mass in mind, we try to find metrics with spherical symmetry. We consider the adiabatic condition along with the Gong-Wang mass, and evaluate the $g_{rr}$ element which points to a null hypersurface. In addition, we generalize the thermodynamics laws to this hypersurface to find its temperature and thus the corresponding surface gravity which enables us to get a relation for the $g_{tt}$ element. Finally, we investigate the mathematical and physical properties of the discovered metric in the Einstein relativity framework which shows that the primary mentioned null hypersurface is an event horizon. We also show that if one considers the Misner-Sharp mass in the calculations, the Schwarzschild metric will be got. The relationship between the two mass definitions in each metric is studied. The results of considering the geometrical surface gravity are also addressed.

  16. Clean Cities Annual Metrics Report 2009 (Revised)

    SciTech Connect (OSTI)

    Johnson, C.

    2011-08-01

    Document provides Clean Cities coalition metrics about the use of alternative fuels; the deployment of alternative fuel vehicles, hybrid electric vehicles (HEVs), and idle reduction initiatives; fuel economy activities; and programs to reduce vehicle miles driven.

  17. Method of making a sodium sulfur battery

    DOE Patents [OSTI]

    Elkins, P. E.

    1981-09-22

    A method of making a portion of a sodium sulfur battery is disclosed. The battery portion made is a portion of the container which defines the volume for the cathodic reactant materials which are sulfur and sodium polysulfide materials. The container portion is defined by an outer metal casing with a graphite liner contained therein, the graphite liner having a coating on its internal diameter for sealing off the porosity thereof. The steel outer container and graphite pipe are united by a method which insures that at the operating temperature of the battery, relatively low electrical resistance exists between the two materials because they are in intimate contact with one another. 3 figs.

  18. Multiple-sulfur isotope effects during photolysis of carbonyl sulfide

    E-Print Network [OSTI]

    Lin, Ying

    Laboratory experiments were carried out to determine sulfur isotope effects during ultraviolet photolysis of carbonyl sulfide (OCS) to carbon monoxide (CO) and elemental sulfur (S[superscript 0]). The OCS gas at 3.7 to 501 ...

  19. EPA Diesel Rule and the Sulfur Effects (DECSE) Project

    SciTech Connect (OSTI)

    2009-05-08

    The VT program collaborated with industry stakeholders and the EPA (in an effort initiated in 1998 called Diesel Emission Control – Sulfur Effects study, otherwise known as DECSE) to quantify the effects of fuel sulfur on emission control technologies.

  20. Process for removing sulfur from sulfur-containing gases: high calcium fly-ash

    DOE Patents [OSTI]

    Rochelle, Gary T. (Austin, TX); Chang, John C. S. (Cary, NC)

    1991-01-01

    The present disclosure relates to improved processes for treating hot sulfur-containing flue gas to remove sulfur therefrom. Processes in accordance with the present invention include preparing an aqueous slurry composed of a calcium alkali source and a source of reactive silica and/or alumina, heating the slurry to above-ambient temperatures for a period of time in order to facilitate the formation of sulfur-absorbing calcium silicates or aluminates, and treating the gas with the heat-treated slurry components. Examples disclosed herein demonstrate the utility of these processes in achieving improved sulfur-absorbing capabilities. Additionally, disclosure is provided which illustrates preferred configurations for employing the present processes both as a dry sorbent injection and for use in conjunction with a spray dryer and/or bagfilter. Retrofit application to existing systems is also addressed.

  1. Mass-independent sulfur isotope fractionation during photochemistry of sulfur dioxide

    E-Print Network [OSTI]

    Whitehill, Andrew (Andrew Richard)

    2015-01-01

    Mass-independent sulfur isotope signatures are observed in Archean and early Paleoproterozoic sedimentary sulfate and sulfide minerals, and provide the most robust constraints on early atmospheric oxygen levels. Smaller ...

  2. Inference and Labeling of Metric-Induced Network Topologies

    E-Print Network [OSTI]

    Byers, John W.

    PERISCOPE, a Linux embodiment of MINT constructions. We instantiate MINT and PERISCOPE for a specific metric

  3. Metrics for Evaluating the Accuracy of Solar Power Forecasting (Presentation)

    SciTech Connect (OSTI)

    Zhang, J.; Hodge, B.; Florita, A.; Lu, S.; Hamann, H.; Banunarayanan, V.

    2013-10-01

    This presentation proposes a suite of metrics for evaluating the performance of solar power forecasting.

  4. Policy Analysis Changing Trends in Sulfur Emissions

    E-Print Network [OSTI]

    Jacobson, Mark

    Goddard Institute for Space Studies, New York, New York, and Disaster Prevention Research Institute, Kyoto in Asia where the pressing environ- mental problems of urban pollution, acid deposition, and climate change are intimately linked to sulfur (1). Over the last 25 years the primary energy demand in Asia has

  5. On the galactic chemical evolution of sulfur

    E-Print Network [OSTI]

    N. Ryde; D. L. Lambert

    2003-12-02

    Sulfur abundances have been determined for ten stars to resolve a debate in the literature on the Galactic chemical evolution of sulfur in the halo phase of the Milky Way. Our analysis is based on observations of the S I lines at 9212.9, 9228.1, and 9237.5 A for stars for which the S abundance was obtained previously from much weaker S I lines at 8694.0 and 8694.6 A. In contrast to the previous results showing [S/Fe] to rise steadily with decreasing [Fe/H], our results show that [S/Fe] is approximately constant for metal-poor stars ([Fe/H] < -1) at [S/Fe] = +0.3. Thus, sulfur behaves in a similar way to the other alpha elements, with an approximately constant [S/Fe] for metallicities lower than [Fe/H] = -1. We suggest that the reason for the earlier claims of a rise of [S/Fe] is partly due to the use of the weak S I 8694.0 and 8694.6 A lines and partly uncertainties in the determination of the metallicity when using Fe I lines. The S I 9212.9, 9228.1, and 9237.5 A lines are preferred for an abundance analysis of sulfur for metal-poor stars.

  6. Sulfur removal from high-sulfur Illinois coal by low-temperature perchloroethylene (PCE) extraction

    SciTech Connect (OSTI)

    Chou, M.I.M.

    1991-01-01

    A pre-combustion coal desulfurization process at 120{degree}C using perchloroethylene (PCE) to remove up to 70% of the organic sulfur has been developed by the Midwest Ore Processing Co. (MWOPC). However, this process has not yet proven to be as successful with Illinois coals as it has for Ohio and Indiana coals. The organic sulfur removal has been achieved only with highly oxidized Illinois coals containing high sulfatic sulfur. A logical explanation for this observation is vital to successful process optimization for the use of Illinois coals. In addition, the high levels of organic sulfur removals observed by the MWOPC may be due to certain errors involved in the ASTM data interpretation; this needs verification. For example, elemental sulfur extracted by the PCE may be derived from pyrite oxidation during coal pre-oxidation, but it may be interpreted as organic sulfur removed by the PCE using ASTM analysis. The goals of this research are: (1) to independently confirm and possibly to improve the organic sulfur removal from Illinois coals with the PCE desulfurization process reported by the MWOPC, (2) to verify the forms-of-sulfur determination using the ASTM method for the PCE process evaluation, and (3) to determine the suitability of Illinois coals for use in the PCE desulfurization process. This project involves the Illinois State Geological Survey (ISGS), Eastern Illinois University (EIU), the University of Illinois-Urbana/Champaign (UI-UC), and the University of Kentucky, Lexington (UK). This is the first year of a two-year project.

  7. High temperature experiments on a 4 tons UF6 container TENERIFE program

    SciTech Connect (OSTI)

    Casselman, C.; Duret, B.; Seiler, J.M.; Ringot, C.; Warniez, P.

    1991-12-31

    The paper presents an experimental program (called TENERIFE) whose aim is to investigate the behaviour of a cylinder containing UF{sub 6} when exposed to a high temperature fire for model validation. Taking into account the experiments performed in the past, the modelization needs further information in order to be able to predict the behaviour of a real size cylinder when engulfed in a 800{degrees}C fire, as specified in the regulation. The main unknowns are related to (1) the UF{sub 6} behaviour beyond the critical point, (2) the relationship between temperature field and internal pressure and (3) the equivalent conductivity of the solid UF{sub 6}. In order to investigate these phenomena in a representative way it is foreseen to perform experiments with a cylinder of real diameter, but reduced length, containing 4 tons of UF{sub 6}. This cylinder will be placed in an electrically heated furnace. A confinement vessel prevents any dispersion of UF{sub 6}. The heat flux delivered by the furnace will be calibrated by specific tests. The cylinder will be changed for each test.

  8. Performance and results of the LBNE 35 ton membrane cryostat prototype

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Montanari, David; Adamowski, Mark; Hahn, Alan; Norris, Barry; Reichenbacher, Juergen; Rucinski, Russell; Stewart, Jim; Tope, Terry

    2015-07-15

    We report on the performance and commissioning of the first membrane cryostat to be used for scientific application. The Long Baseline Neutrino Experiment (LBNE) has designed and fabricated a membrane cryostat prototype in collaboration with Ishikawajima-Harima Heavy Industries Co., Ltd. (IHI). LBNE has designed and fabricated the supporting cryogenic system infrastructure and successfully commissioned and operated the first membrane cryostat. Original goals of the prototype are: to demonstrate the membrane cryostat technology in terms of thermal performance, feasibility for liquid argon and leak tightness; to demonstrate that we can remove all the impurities from the vessel and achieve the puritymore »requirements in a membrane cryostat without evacuation; to demonstrate that we can achieve and maintain the purity requirements of the liquid argon using mol sieve and copper filters. The purity requirements of a large liquid argon detector such as LBNE are contaminants below 200 parts per trillion (ppt) oxygen equivalent. LBNE is planning the design and construction of a large liquid argon detector. This presentation will present requirements, design and construction of the LBNE 35 ton membrane cryostat prototype, and detail the commissioning and performance. The experience and results of this prototype are extremely important for the development of the LBNE detector.« less

  9. The Composition Of A Disrupted Extrasolar Planetesimal At SDSS J0845+2257 (Ton 345)

    E-Print Network [OSTI]

    Wilson, David J; Koester, Detlev; Toloza, Odette; Pala, Anna F; Breedt, Elmé; Parsons, Steven G

    2015-01-01

    We present a detailed study of the metal-polluted DB white dwarf SDSS J0845+2257 (Ton 345). Using high-resolution HST/COS and VLT spectroscopy, we have detected hydrogen and eleven metals in the atmosphere of the white dwarf. The origin of these metals is almost certainly the circumstellar disc of dusty and gaseous debris from a tidally-disrupted planetesimal, accreting at a rate of 1.6E10 gs^-1. Studying the chemical abundances of the accreted material demonstrates that the planetesimal had a composition similar to the Earth, dominated by rocky silicates and metallic iron, with a low water content. The mass of metals within the convection zone of the white dwarf corresponds to an asteroid of at least ~130-170 km in diameter, although the presence of ongoing accretion from the debris disc implies that the planetesimal was probably larger than this. While a previous abundance study of the accreted material has shown an anomalously high mass fraction of carbon (15 percent) compared to the bulk Earth, our indepe...

  10. Global MSW Generation in 2007 estimated at two billion tons Global Waste Management Market Assessment 2007, Key Note Publications Ltd ,

    E-Print Network [OSTI]

    Columbia University

    Global MSW Generation in 2007 estimated at two billion tons Global Waste Management Market analyses the global waste market, with particular reference to municipal solid waste (MSW). Key Note. Industrial waste generally has a greater tonnage than MSW, but its management is the responsibility

  11. Average Stumpage Prices Measured in Price per Ton for Forest Products Large Pine Sawtimber Small Pine Sawtimber Hardwood Sawtimber

    E-Print Network [OSTI]

    Average Stumpage Prices Measured in Price per Ton for Forest Products Large Pine Sawtimber Small Pine Sawtimber Hardwood Sawtimber Year Unweighte d Average Prices Weighted Average Prices Average of Unweighted and Weighted Prices Unweighted Average Prices Weighted Average Prices Average of Unweighted

  12. Average Stumpage Prices Measured in Price per Ton for Forest Products Large Pine Sawtimber Small Pine Sawtimber Hardwood Sawtimber

    E-Print Network [OSTI]

    Average Stumpage Prices Measured in Price per Ton for Forest Products Large Pine Sawtimber Small Pine Sawtimber Hardwood Sawtimber Year Unweighted Average Prices Weighted Average Prices Average of Unweighted and Weighted Prices Unweighted Average Prices Weighted Average Prices Average of Unweighted

  13. Average Stumpage Prices Measured in Price per Ton for Forest Products Large Pine Sawtimber Small Pine Sawtimber Hardwood Sawtimber

    E-Print Network [OSTI]

    Average Stumpage Prices Measured in Price per Ton for Forest Products Large Pine Sawtimber Small Pine Sawtimber Hardwood Sawtimber Year Unweighted Average Prices Weighted Average Prices Simple average of Unweighted and Weighted Prices Unweighted Average Prices Weighted Average Prices Simple average of Unweighted

  14. METRICS FOR WAYFINDING 1 Three Levels of Metric for Evaluating Wayfinding

    E-Print Network [OSTI]

    Ruddle, Roy

    Lessels School of Computing, University of Leeds, Leeds, LS2 9JT, UK. email: royr@comp.leeds.ac.uk Tel a detailed review of research into VE wayfinding. A case study from research into the fidelity into two major sections. The first reviews metrics in #12;METRICS FOR WAYFINDING 4 each of the three levels

  15. Cleanroom Energy Efficiency: Metrics and Benchmarks

    SciTech Connect (OSTI)

    International SEMATECH Manufacturing Initiative; Mathew, Paul A.; Tschudi, William; Sartor, Dale; Beasley, James

    2010-07-07

    Cleanrooms are among the most energy-intensive types of facilities. This is primarily due to the cleanliness requirements that result in high airflow rates and system static pressures, as well as process requirements that result in high cooling loads. Various studies have shown that there is a wide range of cleanroom energy efficiencies and that facility managers may not be aware of how energy efficient their cleanroom facility can be relative to other cleanroom facilities with the same cleanliness requirements. Metrics and benchmarks are an effective way to compare one facility to another and to track the performance of a given facility over time. This article presents the key metrics and benchmarks that facility managers can use to assess, track, and manage their cleanroom energy efficiency or to set energy efficiency targets for new construction. These include system-level metrics such as air change rates, air handling W/cfm, and filter pressure drops. Operational data are presented from over 20 different cleanrooms that were benchmarked with these metrics and that are part of the cleanroom benchmark dataset maintained by Lawrence Berkeley National Laboratory (LBNL). Overall production efficiency metrics for cleanrooms in 28 semiconductor manufacturing facilities in the United States and recorded in the Fabs21 database are also presented.

  16. Method to prevent sulfur accumulation in membrane electrode assembly

    DOE Patents [OSTI]

    Steimke, John L; Steeper, Timothy J; Herman, David T

    2014-04-29

    A method of operating a hybrid sulfur electrolyzer to generate hydrogen is provided that includes the steps of providing an anolyte with a concentration of sulfur dioxide, and applying a current. During steady state generation of hydrogen a plot of applied current density versus concentration of sulfur dioxide is below a boundary line. The boundary line may be linear and extend through the origin of the graph with a slope of 0.001 in which the current density is measured in mA/cm2 and the concentration of sulfur dioxide is measured in moles of sulfur dioxide per liter of anolyte.

  17. CATALYST EVALUATION FOR A SULFUR DIOXIDE-DEPOLARIZED ELECTROLYZER

    SciTech Connect (OSTI)

    Hobbs, D; Hector Colon-Mercado, H

    2007-01-31

    Thermochemical processes are being developed to provide global-scale quantities of hydrogen. A variant on sulfur-based thermochemical cycles is the Hybrid Sulfur (HyS) Process which uses a sulfur dioxide depolarized electrolyzer (SDE) to produce the hydrogen. Testing examined the activity and stability of platinum and palladium as the electrocatalyst for the SDE in sulfuric acid solutions. Cyclic and linear sweep voltammetry revealed that platinum provided better catalytic activity with much lower potentials and higher currents than palladium. Testing also showed that the catalyst activity is strongly influenced by the concentration of the sulfuric acid electrolyte.

  18. Enhanced Accident Tolerant LWR Fuels: Metrics Development

    SciTech Connect (OSTI)

    Shannon Bragg-Sitton; Lori Braase; Rose Montgomery; Chris Stanek; Robert Montgomery; Lance Snead; Larry Ott; Mike Billone

    2013-09-01

    The Department of Energy (DOE) Fuel Cycle Research and Development (FCRD) Advanced Fuels Campaign (AFC) is conducting research and development on enhanced Accident Tolerant Fuels (ATF) for light water reactors (LWRs). This mission emphasizes the development of novel fuel and cladding concepts to replace the current zirconium alloy-uranium dioxide (UO2) fuel system. The overall mission of the ATF research is to develop advanced fuels/cladding with improved performance, reliability and safety characteristics during normal operations and accident conditions, while minimizing waste generation. The initial effort will focus on implementation in operating reactors or reactors with design certifications. To initiate the development of quantitative metrics for ATR, a LWR Enhanced Accident Tolerant Fuels Metrics Development Workshop was held in October 2012 in Germantown, MD. This paper summarizes the outcome of that workshop and the current status of metrics development for LWR ATF.

  19. Metrics for comparison of crystallographic maps

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Urzhumtsev, Alexandre; Afonine, Pavel V.; Lunin, Vladimir Y.; Terwilliger, Thomas C.; Adams, Paul D.

    2014-10-01

    Numerical comparison of crystallographic contour maps is used extensively in structure solution and model refinement, analysis and validation. However, traditional metrics such as the map correlation coefficient (map CC, real-space CC or RSCC) sometimes contradict the results of visual assessment of the corresponding maps. This article explains such apparent contradictions and suggests new metrics and tools to compare crystallographic contour maps. The key to the new methods is rank scaling of the Fourier syntheses. The new metrics are complementary to the usual map CC and can be more helpful in map comparison, in particular when only some of their aspects,more »such as regions of high density, are of interest.« less

  20. Computing and Using Metrics in the ADS

    E-Print Network [OSTI]

    Henneken, Edwin A; Kurtz, Michael J; Grant, Carolyn S; Thompson, Donna; Luker, Jay; Chyla, Roman; Holachek, Alexandra; Murray, Stephen S

    2014-01-01

    Finding measures for research impact, be it for individuals, institutions, instruments or projects, has gained a lot of popularity. More papers than ever are being written on new impact measures, and problems with existing measures are being pointed out on a regular basis. Funding agencies require impact statistics in their reports, job candidates incorporate them in their resumes, and publication metrics have even been used in at least one recent court case. To support this need for research impact indicators, the SAO/NASA Astrophysics Data System (ADS) has developed a service which provides a broad overview of various impact measures. In this presentation we discuss how the ADS can be used to quench the thirst for impact measures. We will also discuss a couple of the lesser known indicators in the metrics overview and the main issues to be aware of when compiling publication-based metrics in the ADS, namely author name ambiguity and citation incompleteness.

  1. Fuel-rich sulfur capture in a combustion environment

    SciTech Connect (OSTI)

    Lindgren, E.R.; Pershing, D.W.; Kirchgessner, D.A.; Drehmel, D.C.

    1992-01-01

    The paper discusses the use of a refactory-lined, natural gas furnace to study the fuel-rich sulfur capture reactions of calcium sorbents under typical combustion conditions. The fuel-rich sulfur species hydrogen sulfide and carbonyl sulfide were monitored in a nearly continuous fashion using a gas chromatograph equiped with a flame photometric detector and an automatic system that sampled every 30 seconds. Below the fuel-rich zone, 25% excess air was added, and the ultimate fuel-lean capture was simultaneously measured using a continuous sulfur dioxide monitor. Under fuel-rich conditions, high levels of sulfur capture were obtained, and calcium utilization increased with sulfur concentration. The ultimate lean capture was found to be weakly dependent on sulfur concentration and independent of the sulfur capture level obtained in the fuel-rich zone.

  2. A Proposal for a Ton Scale Bubble Chamber for Dark Matter Detection

    SciTech Connect (OSTI)

    Collar, Juan; Dahl, C.Eric; Fustin, Drew; Robinson, Alan; Behnke, Ed; Behnke, Joshua; Breznau, William; Connor, Austin; Kuehnemund, Emily Grace; Levine, Ilan; Moan, Timothy; /Indiana U., South Bend /Fermilab

    2010-10-07

    The nature of non-baryonic dark matter is one of the most intriguing questions for particle physics at the start of the 21st century. There is ample evidence for its existence, but almost nothing is known of its properties. WIMPs are a very appealing candidate particle and several experimental campaigns are underway around the world to search for these particles via the nuclear recoils that they should induce. The COUPP series of bubble chambers has played a significant role in the WIMP search. Through a sequence of detectors of increasing size, a number of R&D issues have arisen and been solved, and the technology has now been advanced to the point where the construction of large chambers requires a modest research effort, some development, but mostly just engineering. It is within this context that we propose to build the next COUPP detector - COUPP-500, a ton scale device to be built over the next three years at Fermilab and then deployed deep underground at SNOLAB. The primary advantages of the COUPP approach over other technologies are: (1) The ability to reject electron and gamma backgrounds by arranging the chamber thermodynamics such that these particles do not even trigger the detector. (2) The ability to suppress neutron backgrounds by having the radioactively impure detection elements far from the active volume and by using the self-shielding of a large device and the high granularity to identify multiple bubbles. (3) The ability to build large chambers cheaply and with a choice of target fluids. (4) The ability to increase the size of the chambers without changing the size or complexity of the data acquisition. (5) Sensitivity to spin-dependent and spin-independent WIMP couplings. These key advantages should enable the goal of one background event in a ton-year of exposure to be achieved. The conceptual design of COUPP-500 is scaled from the preceding devices. In many cases all that is needed is a simple scaling up of components previously used. Calibration and R&D are still needed on some aspects of the system. We know we have the ability to distinguish alpha-induced events from nuclear recoils, but we do not yet know whether the combination of material purity and rejection are good enough to run for a year with no alpha background. We also need to have more detailed measurements of the detector threshold and a better understanding of its high gamma rejection. In addition, there are important checks to make on the longevity of the detector components in the hydraulic fluid and on the chemistry of the active fluid. The 2009 PASAG report explicitly supported the construction of the COUPP-500 device in all funding scenarios. The NSF has shown similar enthusiasm. It awarded one of its DUSEL S4 grants to assist in the engineering needed to build COUPP-500. The currently estimated cost of COUPP-500 is $8M, about half the $15M-$20M price tag expected by the PASAG report for a next generation dark matter search experiment. The COUPP-500 device will have a spin independent WIMP-nucleus cross-section sensitivity of 6 x 10{sup -47} cm{sup 2} after a background-free year of running. This device should then provide the benchmark against which all other WIMP searches are measured.

  3. Costs to reduce sulfur dioxide emissions

    SciTech Connect (OSTI)

    None

    1982-03-01

    Central to the resolution of the acid rain issue are debates about the costs and benefits of controlling man-made emissions of chemicals that may cause acid rain. In this briefing, the position of those who are calling for immediate action and implicating coal-fired powerplants as the cause of the problem is examined. The costs of controlling sulfur dioxide emissions using alternative control methods available today are presented. No attempt is made to calculate the benefits of reducing these emissions since insufficient information is available to provide even a rough estimate. Information is presented in two steps. First, costs are presented as obtained through straightforward calculations based upon simplifying but realistic assumptions. Next, the costs of sulfur dioxide control obtained through several large-scale analyses are presented, and these results are compared with those obtained through the first method.

  4. Catalyst for elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, Maria (Winchester, MA); Liu, Wei (Cambridge, MA)

    1995-01-01

    A catalytic reduction process for the direct recovery of elemental sulfur from various SO.sub.2 -containing industrial gas streams. The catalytic process provides high activity and selectivity, as well as stability in the reaction atmosphere, for the reduction of SO.sub.2 to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over a metal oxide composite catalyst having one of the following empirical formulas: [(OF.sub.2).sub.1-n (RO.sub.1)n].sub.1-k M.sub.k, [(FO.sub.2).sub.1-n (RO.sub.1.5).sub.n ].sub.1-k M.sub.k, or [Ln.sub.x Zr.sub.1-x O.sub.2-0.5x ].sub.1-k M.sub.k wherein FO.sub.2 is a fluorite-type oxide; RO represents an alkaline earth oxide; RO.sub.1.5 is a Group IIIB or rare earth oxide; Ln is a rare earth element having an atomic number from 57 to 65 or mixtures thereof; M is a transition metal or a mixture of transition metals; n is a number having a value from 0.0 to 0.35; k is a number having a value from 0.0 to about 0.5; and x is a number having a value from about 0.45 to about 0.55.

  5. Fourier Transform, Riemann Surfaces and Indefinite Metric

    E-Print Network [OSTI]

    Fominov, Yakov

    Fourier Transform, Riemann Surfaces and Indefinite Metric P. G. Grinevich, S.P.Novikov Zakharov Park, College Park, USA #12;What is Fourier Transform in Riemann Surfaces? Which Problems need it? Discrete Analog of The Fourier/Laurent bases in Riemann Sur- faces was constructed by Krichever-Novikov (KN

  6. Towards a Multidimensional Geometric Metric for Sustainability

    E-Print Network [OSTI]

    Collins, Gary S.

    Towards a Multidimensional Geometric Metric for Sustainability Noah Granieri1, Gaurav Ameta2 1's REU program under grant number 0754370 Results Geometric results from Sustainability Data ·All aspect sustainability aspect values change depending on fuel sources for energy production. Designers may choose what

  7. RAY PRESERVING METRICS AND APPLICATIONS JAIGYOUNG CHOE

    E-Print Network [OSTI]

    Choe, Jaigyoung

    of the two-dimensional hyper- bolic plane H2 (-2 ) with Gauss curvature -2 RAY PRESERVING METRICS AND APPLICATIONS JAIGYOUNG CHOE 1. INTRODUCTION Let be an m-dimensional as the union of the line segments from p to q, over all q . And for a k-dimensional submanifold N Rn

  8. New Metrics for Blog Mining Brian Ulicnya

    E-Print Network [OSTI]

    Baclawski, Kenneth B.

    New Metrics for Blog Mining Brian Ulicnya , Ken Baclawskia , Amy Magnusb a VIStology, Inc., 5, Suite 325 , Arlington, VA 22203 ABSTRACT Blogs represent an important new arena for knowledge discovery-human) information sources monitoring important local and global events, and other blogs, for items of interest upon

  9. An Attack Surface Metric Pratyusa K. Manadhata

    E-Print Network [OSTI]

    K. Manadhata This research was sponsored in part by the Defense Advanced Research Project Agency by the National Science Foundation under grants no. CCR-0121547 and CNS-0433540, SAP Labs, LLC under award no metrics has recently become more pressing. In this thesis, we introduce the measure of a software system

  10. Clean Cities 2010 Annual Metrics Report

    SciTech Connect (OSTI)

    Johnson, C.

    2012-10-01

    This report details the petroleum savings and vehicle emissions reductions achieved by the U.S. Department of Energy's Clean Cities program in 2010. The report also details other performance metrics, including the number of stakeholders in Clean Cities coalitions, outreach activities by coalitions and national laboratories, and alternative fuel vehicles deployed.

  11. Clean Cities 2011 Annual Metrics Report

    SciTech Connect (OSTI)

    Johnson, C.

    2012-12-01

    This report details the petroleum savings and vehicle emissions reductions achieved by the U.S. Department of Energy's Clean Cities program in 2011. The report also details other performance metrics, including the number of stakeholders in Clean Cities coalitions, outreach activities by coalitions and national laboratories, and alternative fuel vehicles deployed.

  12. On the Jacobi-Metric Stability Criterion

    E-Print Network [OSTI]

    M. A. Gonzalez Leon; J. L. Hernandez Pastora

    2007-05-30

    We investigate the exact relation existing between the stability equation for the solutions of a mechanical system and the geodesic deviation equation of the associated geodesic problem in the Jacobi metric constructed via the Maupertuis-Jacobi Principle. We conclude that the dynamical and geometrical approaches to the stability/instability problem are not equivalent.

  13. Performance Metrics Research Project - Final Report

    SciTech Connect (OSTI)

    Deru, M.; Torcellini, P.

    2005-10-01

    NREL began work for DOE on this project to standardize the measurement and characterization of building energy performance. NREL's primary research objectives were to determine which performance metrics have greatest value for determining energy performance and to develop standard definitions and methods of measuring and reporting that performance.

  14. Status of ArDM-1t: First observations from operation with a full ton-scale liquid argon target

    E-Print Network [OSTI]

    ArDM Collaboration; J. Calvo; C. Cantini; M. Daniel; U. Degunda; S. Di Luise; L. Epprecht; A. Gendotti; S. Horikawa; L. Knecht; B. Montes; W. Mu; M. Munoz; S. Murphy; G. Natterer; K. Nguyen; K. Nikolics; L. Periale; C. Regenfus; L. Romero; A. Rubbia; R. Santorelli; F. Sergiampietri; D. Sgalaberna; T. Viant; S. Wu

    2015-05-10

    ArDM-1t is the first operating ton-scale liquid argon detector for direct search of Dark Matter particles. Developed at CERN as Recognized Experiment RE18, the experiment has been approved in 2010 to be installed in the Spanish underground site LSC (Laboratorio Subterraneo de Canfranc). Under the label of LSC EXP-08-2010 the ArDM detector underwent an intensive period of technical completion and safety approval until the recent filling of the target vessel with almost 2 ton of liquid argon. This report describes the experimental achievements during commissioning of ArDM and the transition into a stage of first physics data taking in single phase operational mode. We present preliminary observations from this run. A first indication for the background discrimination power of LAr detectors at the ton-scale is shown. We present an outlook for completing the detector with the electric drift field and upgrade of the scintillation light readout system with novel detector modules based on SiPMs in order to improve the light yield.

  15. Process for production of synthesis gas with reduced sulfur content

    DOE Patents [OSTI]

    Najjar, Mitri S. (Hopewell Junction, NY); Corbeels, Roger J. (Wappingers Falls, NY); Kokturk, Uygur (Wappingers Falls, NY)

    1989-01-01

    A process for the partial oxidation of a sulfur- and silicate-containing carbonaceous fuel to produce a synthesis gas with reduced sulfur content which comprises partially oxidizing said fuel at a temperature in the range of 1800.degree.-2200.degree. F. in the presence of a temperature moderator, an oxygen-containing gas and a sulfur capture additive which comprises an iron-containing compound portion and a sodium-containing compound portion to produce a synthesis gas comprising H.sub.2 and CO with a reduced sulfur content and a molten slag which comprises (i) a sulfur-containing sodium-iron silicate phase and (ii) a sodium-iron sulfide phase. The sulfur capture additive may optionally comprise a copper-containing compound portion.

  16. Sulfur control in ion-conducting membrane systems

    DOE Patents [OSTI]

    Stein, VanEric Edward; Richards, Robin Edward; Brengel, David Douglas; Carolan, Michael Francis

    2003-08-05

    A method for controlling the sulfur dioxide partial pressure in a pressurized, heated, oxygen-containing gas mixture which is contacted with an ion-conducting metallic oxide membrane which permeates oxygen ions. The sulfur dioxide partial pressure in the oxygen-depleted non-permeate gas from the membrane module is maintained below a critical sulfur dioxide partial pressure, p.sub.SO2 *, to protect the membrane material from reacting with sulfur dioxide and reducing the oxygen flux of the membrane. Each ion-conducting metallic oxide material has a characteristic critical sulfur dioxide partial pressure which is useful in determining the required level of sulfur removal from the feed gas and/or from the fuel gas used in a direct-fired feed gas heater.

  17. Evaluation Criteria for Human-Automation Performance Metrics

    E-Print Network [OSTI]

    Pina, Patricia Elena

    Previous research has identified broad metric classes for human-automation performance to facilitate metric selection, as well as understanding and comparison of research results. However, there is still lack of an objective ...

  18. The Jacobi-metric for timelike geodesics in static spacetimes

    E-Print Network [OSTI]

    G. W. Gibbons

    2015-09-09

    It is shown that the free motion of massive particles moving in static spacetimes are given by the geodesics of an energy-dependent Riemannian metric on the spatial sections analogous to Jacobi's metric in classical dynamics. In the massless limit Jacobi's metric coincides with the energy independent Fermat or optical metric. For stationary metrics, it is known that the motion of massless particles is given by the geodesics of an energy independent Finslerian metric of Randers type. The motion of massive particles is governed by neither a Riemannian nor a Finslerian metric. The properies of the Jacobi metric for massive particles moving outside the horizon of a Schwarschild black hole are described. By constrast with the massless case, the Gaussian curvature of the equatorial sections is not always negative.

  19. The Jacobi-metric for timelike geodesics in static spacetimes

    E-Print Network [OSTI]

    Gibbons, G W

    2015-01-01

    It is shown that the free motion of massive particles moving in static spacetimes are given by the geodesics of an energy-dependent Riemannian metric on the spatial sections analogous to Jacobi's metric in classical dynamics. In the massless limit Jacobi's metric coincides with the energy independent Fermat or optical metric. For stationary metrics, it is known that the motion of massless particles is given by the geodesics of an energy independent Finslerian metric of Randers type. The motion of massive particles is governed by neither a Riemannian nor a Finslerian metric. The properies of the Jacobi metric for massive particles moving outside the horizon of a Schwarschild black hole are described. By constrast with the massless case, the Gaussian curvature of the equatorial sections is not always negative.

  20. Sulfide catalysts for reducing SO2 to elemental sulfur

    DOE Patents [OSTI]

    Jin, Yun (Peking, CN); Yu, Qiquan (Peking, CN); Chang, Shih-Ger (El Cerrito, CA)

    2001-01-01

    A highly efficient sulfide catalyst for reducing sulfur dioxide to elemental sulfur, which maximizes the selectivity of elemental sulfur over byproducts and has a high conversion efficiency. Various feed stream contaminants, such as water vapor are well tolerated. Additionally, hydrogen, carbon monoxide, or hydrogen sulfides can be employed as the reducing gases while maintaining high conversion efficiency. This allows a much wider range of uses and higher level of feed stream contaminants than prior art catalysts.

  1. Development of a multiple metric index for macroinvertebrates collected from lower Missouri River floodplain wetlands

    E-Print Network [OSTI]

    Koontz, Jason Alexander

    2010-07-26

    of a priori Stressor Groups ................................................................................. 27 2.8 Metric Response ................................................................................................................... 28... 2.8 Metric Redundancy............................................................................................................... 28 2.9 Scoring Individual Metrics and Final Index...

  2. Projections of Full-Fuel-Cycle Energy and Emissions Metrics

    E-Print Network [OSTI]

    Coughlin, Katie

    2013-01-01

    coal production by region, coal type, and sulfur content infrom AEO 2011 and AEO 2012. Coal Type Bituminous Bituminousproportions of total coal output by mining type. To estimate

  3. Effect of Environmental Factors on Sulfur Gas Emissions from Drywall

    E-Print Network [OSTI]

    Maddalena, Randy

    2012-01-01

    sulfide (H 2 S), carbonyl sulfide (OCS), sulfur dioxide (SOof hydrogen sulfide, carbonyl sulfide, methyl mercaptan,associated with the carbonyl sulfide that typically had very

  4. More Economical Sulfur Removal for Fuel Processing Plants

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    crude oil it is present in sulfur-containing organic compounds which are converted into hydrocarbons and H 2 S during the removal process (hydrodesulfurization). In both cases,...

  5. Metrics Are Fitness Functions Too Mark Harman John Clark

    E-Print Network [OSTI]

    Singer, Jeremy

    that there is an alternative, complementary, view of a metric: as a fitness function, used to guide a search for optimal' (MAFF) approach offers a number of additional benefits to metrics research and practice because systems. It describes the properties of a metric which make it a good fitness function and explains

  6. Gauge - invariant fluctuations of the metric in stochastic inflation

    E-Print Network [OSTI]

    Mauricio Bellini

    2000-01-07

    I derive the stochastic equation for the perturbations of the metric for a gauge - invariant energy - momemtum - tensor (EMT) in stochastic inflation. A quantization for the field that describes the gauge - invariant perturbations for the metric is developed. In a power - law expansion for the universe the amplitude for these perturbations on a background metric could be very important in the infrared sector.

  7. Complex geometry and pre-metric electromagnetism

    E-Print Network [OSTI]

    D. H. Delphenich

    2004-12-10

    The intimate link between complex geometry and the problem of the pre-metric formulation of electromagnetism is explored. In particular, the relationship between 3+1 decompositions of R4 and the decompositions of the vector space of bivectors over R4 into real and imaginary subspaces relative to a choice of complex structure is emphasized. The role of the various scalar products on the space of bivectors that are defined in terms of a volume element on R4 and a complex structure on the space of bivectors that makes it C-linear isomorphic to C3 is discussed in the context of formulation of a theory of electromagnetism in which the Lorentzian metric on spacetime follows as a consequence of the existence of electromagnetic waves, not a prior assumption.

  8. Network Community Detection on Metric Space

    E-Print Network [OSTI]

    Saha, Suman

    2015-01-01

    Community detection in a complex network is an important problem of much interest in recent years. In general, a community detection algorithm chooses an objective function and captures the communities of the network by optimizing the objective function, and then, one uses various heuristics to solve the optimization problem to extract the interesting communities for the user. In this article, we demonstrate the procedure to transform a graph into points of a metric space and develop the methods of community detection with the help of a metric defined for a pair of points. We have also studied and analyzed the community structure of the network therein. The results obtained with our approach are very competitive with most of the well-known algorithms in the literature, and this is justified over the large collection of datasets. On the other hand, it can be observed that time taken by our algorithm is quite less compared to other methods and justifies the theoretical findings.

  9. Quantum metric fluctuations and Hawking radiation

    E-Print Network [OSTI]

    R. Parentani

    2000-09-05

    In this Letter we study the gravitational interactions between outgoing configurations giving rise to Hawking radiation and in-falling configurations. When the latter are in their ground state, the near horizon interactions lead to collective effects which express themselves as metric fluctuations and which induce dissipation, as in Brownian motion. This dissipation prevents the appearance of trans-Planckian frequencies and leads to a description of Hawking radiation which is very similar to that obtained from sound propagation in condensed matter models.

  10. Smart Grid Status and Metrics Report

    SciTech Connect (OSTI)

    Balducci, Patrick J.; Weimar, Mark R.; Kirkham, Harold

    2014-07-01

    To convey progress made in achieving the vision of a smart grid, this report uses a set of six characteristics derived from the National Energy Technology Laboratory Modern Grid Strategy. It measures 21 metrics to provide insight into the grid’s capacity to embody these characteristics. This report looks across a spectrum of smart grid concerns to measure the status of smart grid deployment and impacts.

  11. Nonflame, source-induced sulfur fluorescence detector for sulfur-containing compounds

    SciTech Connect (OSTI)

    Gage, D.R.; Farwell, S.O.

    1980-12-01

    Results of some preliminary investigations of the fluorescence spectra of S/sub 2/ and the non-flame production of S/sub 2/ from sulfur-containing molecules are reported. Passage of the gas to be analyzed through a catalyst-oven containing a plug of NiO/sub 2//Al/sub 2/O/sub 3/ catalyst containing 10 wt% NiO/sub 2/ and heated to 400/sup 0/C resulted in conversion of H/sub 2/S to S/sub 2/ and elemental sulfur. The S/sub 2/ was detected by measurement of its fluorescence bands at 260 and 310nm, and elemental sulfur condensed on the cool parts of the apparatus. However, determination of sulfur-content of gas mixtures with the apparatus described herein were not as repeatable as desired, and the work is being continued on various facets of the non-flame system with work being directed toward the evaluation of different catalysts, catalyst temperature, design of a smaller detector geometry utilizing a pulsed-light excitation source, a windowless cell, and optical filters instead of monochromators to select the S/sub 2/ excitation and emission wavelengths. (BLM)

  12. Sodium-tetravalent sulfur molten chloroaluminate cell

    DOE Patents [OSTI]

    Mamantov, Gleb (Knoxville, TN)

    1985-04-02

    A sodium-tetravalent sulfur molten chloroaluminate cell with a .beta."-alumina sodium ion conductor having a S-Al mole ratio of above about 0.15 in an acidic molten chloroaluminate cathode composition is disclosed. The cathode composition has an AlCl.sub.3 -NaCl mole percent ratio of above about 70-30 at theoretical full charge. The cell provides high energy densities at low temperatures and provides high energy densities and high power densities at moderate temperatures.

  13. Sulfur removal and comminution of carbonaceous material

    DOE Patents [OSTI]

    Narain, N.K.; Ruether, J.A.; Smith, D.N.

    1987-10-07

    Finely divided, clean coal or other carbonaceous material is provided by forming a slurry of coarse coal in aqueous alkali solution and heating the slurry under pressure to above the critical conditions of steam. The supercritical fluid penetrates and is trapped in the porosity of the coal as it swells in a thermoplastic condition at elevated temperature. By a sudden, explosive release of pressure the coal is fractured into finely divided particles with release of sulfur-containing gases and minerals. The finely divided coal is recovered from the minerals for use as a clean coal product. 2 figs.

  14. Sulfur removal and comminution of carbonaceous material

    DOE Patents [OSTI]

    Narain, Nand K. (Bethel Park, PA); Ruether, John A. (McMurray, PA); Smith, Dennis N. (Herminie, PA)

    1988-01-01

    Finely divided, clean coal or other carbonaceous material is provided by forming a slurry of coarse coal in aqueous alkali solution and heating the slurry under pressure to above the critical conditions of steam. The supercritical fluid penetrates and is trapped in the porosity of the coal as it swells in a thermoplastic condition at elevated temperature. By a sudden, explosive release of pressure the coal is fractured into finely divided particles with release of sulfur-containing gases and minerals. The finely divided coal is recovered from the minerals for use as a clean coal product.

  15. An Evolutionary Arms Race for Sulfur

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room News Publications TraditionalWith PropaneNaturalTestAn Evolutionary Arms Race for Sulfur An

  16. Using ISC & GIS to predict sulfur deposition from coal-fired power plants 

    E-Print Network [OSTI]

    Lopez, Jose Ignacio

    1993-01-01

    The goal of this research project was to determine if atmospheric sources have the potential of contributing significantly to the sulfur content of grazed forage. Sulfur deposition resulting from sulfur dioxide emissions from coal- fired power...

  17. X-ray reprocessing in Narrow-Line Seyfert 1 Galaxies: Ton S180 and Ark 564

    E-Print Network [OSTI]

    A. Janiuk; P. T. Zycki; B. Czerny

    2000-05-08

    We present the results of spectral analysis of the ASCA data for the Narrow-Line Seyfert 1 galaxy (NLS1) Ton S180 and simultaneous ASCA and RXTE data modelling for the NLS1 Ark 564. We model both the primary and reflected continuum as well as the iron K alpha line, the energy of which depends on the ionization state of the reprocessor. We show that the reprocessing matter is mildly ionized, and we find the soft to hard luminosity ratio to be about 2.5. The accretion rate approximately corresponds to the Eddington limit value.

  18. Quantifying Individual Potential Contributions of the Hybrid Sulfur Electrolyzer

    E-Print Network [OSTI]

    Weidner, John W.

    Quantifying Individual Potential Contributions of the Hybrid Sulfur Electrolyzer John A. Staser for the hybrid sulfur electrolyzer is controlled mainly by water transport in the cell. Water is required electrolyzer performance and operation. Experimental The experimental setup was the same as that described

  19. Sulfur removal from diesel fuel-contaminated methanol.

    SciTech Connect (OSTI)

    Lee, S. H. D.; Kumar, R.; Krumpelt, M.; Chemical Engineering

    2002-03-01

    Methanol is considered to be a potential on-board fuel for fuel cell-powered vehicles. In current distribution systems for liquid fuels used in the transportation sector, commodity methanol can occasionally become contaminated with the sulfur in diesel fuel or gasoline. This sulfur would poison the catalytic materials used in fuel reformers for fuel cells. We tested the removal of this sulfur by means of ten activated carbons (AC) that are commercially available. Tests were conducted with methanol doped with 1 vol.% grade D-2 diesel fuel containing 0.29% sulfur, which was present essentially as 33-35 wt.% benzothiophenes (BTs) and 65-67 wt.% dibenzothiophenes (DBT). In general, coconut shell-based carbons activated by high-temperature steam were more effective at sulfur removal than coal-based carbons. Equilibrium sorption data showed linear increase in sulfur capture with the increase of sulfur concentration in methanol. Both types of carbons had similar breakthrough characteristics, with the dynamic sorption capacity of each being about one-third of its equilibrium sorption capacity. Results of this study suggest that a fixed-bed sorber of granular AC can be used, such as in refueling stations, for the removal of sulfur in diesel fuel-contaminated methanol.

  20. Integrated boiler, superheater, and decomposer for sulfuric acid decomposition

    DOE Patents [OSTI]

    Moore, Robert (Edgewood, NM); Pickard, Paul S. (Albuquerque, NM); Parma, Jr., Edward J. (Albuquerque, NM); Vernon, Milton E. (Albuquerque, NM); Gelbard, Fred (Albuquerque, NM); Lenard, Roger X. (Edgewood, NM)

    2010-01-12

    A method and apparatus, constructed of ceramics and other corrosion resistant materials, for decomposing sulfuric acid into sulfur dioxide, oxygen and water using an integrated boiler, superheater, and decomposer unit comprising a bayonet-type, dual-tube, counter-flow heat exchanger with a catalytic insert and a central baffle to increase recuperation efficiency.

  1. Process for removing pyritic sulfur from bituminous coals

    DOE Patents [OSTI]

    Pawlak, Wanda (Edmonton, CA); Janiak, Jerzy S. (Edmonton, CA); Turak, Ali A. (Edmonton, CA); Ignasiak, Boleslaw L. (Edmonton, CA)

    1990-01-01

    A process is provided for removing pyritic sulfur and lowering ash content of bituminous coals by grinding the feed coal, subjecting it to micro-agglomeration with a bridging liquid containing heavy oil, separating the microagglomerates and separating them to a water wash to remove suspended pyritic sulfur. In one embodiment the coal is subjected to a second micro-agglomeration step.

  2. Linearization of Moffat's Symmetric Complex Metric Gravity

    E-Print Network [OSTI]

    Joakim Munkhammar

    2009-09-19

    In this paper we investigate a complex symmetric generalization of general relativity and in particular we investigate its linearized field equations. We begin by reviewing some basic definitions and structures in Moffat's symmetric complex metric field theory of gravity. We then move on to derive the linearized retarded complex field equations. In addition to this we also derive a linearization of Moffat's field equations based on the more rigorous Fermi coordinate approach. In conclusion it is shown that the linearized symmetric complex field equations leads to a complex form of gravitomagnetism. We also briefly review the gravitational wave equation from the source less linearized symmetric complex field equations and discuss some open problems.

  3. Metrics For Comparing Plasma Mass Filters

    SciTech Connect (OSTI)

    Abraham J. Fetterman and Nathaniel J. Fisch

    2012-08-15

    High-throughput mass separation of nuclear waste may be useful for optimal storage, disposal, or environmental remediation. The most dangerous part of nuclear waste is the fission product, which produces most of the heat and medium-term radiation. Plasmas are well-suited to separating nuclear waste because they can separate many different species in a single step. A number of plasma devices have been designed for such mass separation, but there has been no standardized comparison between these devices. We define a standard metric, the separative power per unit volume, and derive it for three different plasma mass filters: the plasma centrifuge, Ohkawa filter, and the magnetic centrifugal mass filter. __________________________________________________

  4. Metrics for comparing plasma mass filters

    SciTech Connect (OSTI)

    Fetterman, Abraham J.; Fisch, Nathaniel J.

    2011-10-15

    High-throughput mass separation of nuclear waste may be useful for optimal storage, disposal, or environmental remediation. The most dangerous part of nuclear waste is the fission product, which produces most of the heat and medium-term radiation. Plasmas are well-suited to separating nuclear waste because they can separate many different species in a single step. A number of plasma devices have been designed for such mass separation, but there has been no standardized comparison between these devices. We define a standard metric, the separative power per unit volume, and derive it for three different plasma mass filters: the plasma centrifuge, Ohkawa filter, and the magnetic centrifugal mass filter.

  5. FY 2013 Metric Summary | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergy A plug-inPPLforLDRD Report to Congress MoreHyd rog en Tan41FY 2013 Q1 Metric

  6. Clean Cities 2013 Annual Metrics Report

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home PageBlender PumpVehiclesThe Heat Is onis3 Annual Metrics Report

  7. Clean Cities 2014 Annual Metrics Report

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home PageBlender PumpVehiclesThe Heat Is onis3 Annual Metrics4

  8. Performance and cost models for the direct sulfur recovery process. Task 1 Topical report, Volume 3

    SciTech Connect (OSTI)

    Frey, H.C. [North Carolina State Univ., Raleigh, NC (United States); Williams, R.B. [Carneigie Mellon Univ., Pittsburgh, PA (United States)

    1995-09-01

    The purpose of this project is to develop performance and cost models of the Direct Sulfur Recovery Process (DSRP). The DSRP is an emerging technology for sulfur recovery from advanced power generation technologies such as Integrated Gasification Combined Cycle (IGCC) systems. In IGCC systems, sulfur present in the coal is captured by gas cleanup technologies to avoid creating emissions of sulfur dioxide to the atmosphere. The sulfur that is separated from the coal gas stream must be collected. Leading options for dealing with the sulfur include byproduct recovery as either sulfur or sulfuric acid. Sulfur is a preferred byproduct, because it is easier to handle and therefore does not depend as strongly upon the location of potential customers as is the case for sulfuric acid. This report describes the need for new sulfur recovery technologies.

  9. Superradiance on the Reissner-Nordstrom metric

    E-Print Network [OSTI]

    Laurent Di Menza; Jean-Philippe Nicolas

    2015-06-22

    In this article, we study the superradiance of charged scalar fields on the sub-extremal Reissner-Nordstrom metric, a mechanism by which such fields can extract energy from a static spherically symmetric charged black hole. A geometrical way of measuring the amount of energy extracted is proposed. Then we investigate the question numerically. The toy-model and the numerical methods used in our simulations are presented and the problem of long time measurement of the outgoing energy flux is discussed. We provide a numerical example of a field exhibiting a behaviour analogous to the Penrose process: an incoming wave packet which splits, as it approaches the black hole, into an incoming part with negative energy and an outgoing part with more energy than the initial incoming one. We also show another type of superradiant solution for which the energy extraction is more important. Hyperradiant behaviour is not observed, which is an indication that the Reissner-Nordstrom metric is linearly stable in the sub-extremal case.

  10. Measurable Control System Security through Ideal Driven Technical Metrics

    SciTech Connect (OSTI)

    Miles McQueen; Wayne Boyer; Sean McBride; Marie Farrar; Zachary Tudor

    2008-01-01

    The Department of Homeland Security National Cyber Security Division supported development of a small set of security ideals as a framework to establish measurable control systems security. Based on these ideals, a draft set of proposed technical metrics was developed to allow control systems owner-operators to track improvements or degradations in their individual control systems security posture. The technical metrics development effort included review and evaluation of over thirty metrics-related documents. On the bases of complexity, ambiguity, or misleading and distorting effects the metrics identified during the reviews were determined to be weaker than necessary to aid defense against the myriad threats posed by cyber-terrorism to human safety, as well as to economic prosperity. Using the results of our metrics review and the set of security ideals as a starting point for metrics development, we identified thirteen potential technical metrics - with at least one metric supporting each ideal. Two case study applications of the ideals and thirteen metrics to control systems were then performed to establish potential difficulties in applying both the ideals and the metrics. The case studies resulted in no changes to the ideals, and only a few deletions and refinements to the thirteen potential metrics. This led to a final proposed set of ten core technical metrics. To further validate the security ideals, the modifications made to the original thirteen potential metrics, and the final proposed set of ten core metrics, seven separate control systems security assessments performed over the past three years were reviewed for findings and recommended mitigations. These findings and mitigations were then mapped to the security ideals and metrics to assess gaps in their coverage. The mappings indicated that there are no gaps in the security ideals and that the ten core technical metrics provide significant coverage of standard security issues with 87% coverage. Based on the two case studies and evaluation of the seven assessments, the security ideals demonstrated their value in guiding security thinking. Further, the final set of core technical metrics has been demonstrated to be both usable in the control system environment and provide significant coverage of standard security issues.

  11. On the Hamilton approach to the metric GR

    E-Print Network [OSTI]

    Frolov, Alexei M

    2015-01-01

    Basic principles of the Hamilton approach developed for the metric General Relativity (Einstein`s GR) are discussed. In particular, we derive the Hamiltonian of the metric GR in the explicit form. This Hamiltonian is a quadratic function of the momenta $\\pi^{mn}$ conjugate to the spatial components $g_{mn}$ of the metric tensor $g_{\\alpha\\beta}$. The Hamilton approach is used to analyze some problems of metric GR, including the internal structure of propagating gravitational waves and quantization of the metric GR. We also derive the Schr\\"{o}dinger equation for the free Gravitational field and show that actual gravitational field cannot propagate as pure harmonic oscillations, or harmonic gravitational waves. A number of inequalities useful in the metric GR are derived.

  12. Warm inflation and scalar perturbations of the metric

    E-Print Network [OSTI]

    Mauricio Bellini

    2001-01-16

    A second-order expansion for the quantum fluctuations of the matter field was considered in the framework of the warm inflation scenario. The friction and Hubble parameters were expended by means of a semiclassical approach. The fluctuations of the Hubble parameter generates fluctuations of the metric. These metric fluctuations produce an effective term of curvature. The power spectrum for the metric fluctuations can be calculated on the infrared sector.

  13. On isotropic metric of Schwarzschild solution of Einstein equation

    E-Print Network [OSTI]

    T. Mei

    2006-10-24

    The known static isotropic metric of Schwarzschild solution of Einstein equation cannot cover with the range of r<2MG, a new isotropic metric of Schwarzschild solution is obtained. The new isotropic metric has the characters: (1) It is dynamic and periodic. (2) It has infinite singularities of the spacetime. (3) It cannot cover with the range of 0metric.

  14. Conceptual Framework for Developing Resilience Metrics for the...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Conceptual Framework for Developing Resilience Metrics for the Electricity, Oil, and Gas Sectors in the United States (September 2014) Conceptual Framework for Developing...

  15. Resilient Control Systems Practical Metrics Basis for Defining Mission Impact

    SciTech Connect (OSTI)

    Craig G. Rieger

    2014-08-01

    "Resilience” describes how systems operate at an acceptable level of normalcy despite disturbances or threats. In this paper we first consider the cognitive, cyber-physical interdependencies inherent in critical infrastructure systems and how resilience differs from reliability to mitigate these risks. Terminology and metrics basis are provided to integrate the cognitive, cyber-physical aspects that should be considered when defining solutions for resilience. A practical approach is taken to roll this metrics basis up to system integrity and business case metrics that establish “proper operation” and “impact.” A notional chemical processing plant is the use case for demonstrating how the system integrity metrics can be applied to establish performance, and

  16. Stable determination of generic simple metrics from the hyperbolic ...

    E-Print Network [OSTI]

    problem of recovering such metrics from the Dirichlet-to-Neumann map associated ..... Using a partition of unity, one can extend ' in a small neighborhood of @?.

  17. Integration of Sustainability Metrics into Design Cases and State...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Conversion Stage Life Cycle Inventory * Fossil GHGs * Fossil Energy Use * Fuel Yield * Carbon-to-Fuel Efficiency * Water Consumption * Wastewater Generation Sustainability Metrics...

  18. Non-perturbative scalar gauge-invariant metric fluctuations from the Ponce de Leon metric in the STM theory of gravity

    E-Print Network [OSTI]

    Mariano Anabitarte; Mauricio Bellini

    2008-02-20

    We study our non-perturbative formalism to describe scalar gauge-invariant metric fluctuations by extending the Ponce de Leon metric.

  19. Amphiphilic Surface Modification of Hollow Carbon Nanofibers for Improved Cycle Life of Lithium Sulfur Batteries

    E-Print Network [OSTI]

    Cui, Yi

    Sulfur Batteries Guangyuan Zheng, Qianfan Zhang, Judy J. Cha, Yuan Yang, Weiyang Li, Zhi Wei Seh, and Yi lithium sulfur batteries, due to their high specific energy and relatively low cost. Despite recent progress in addressing the various problems of sulfur cathodes, lithium sulfur batteries still exhibit

  20. Low Temperature Sorbents for Removal of Sulfur Compounds from Fluid Feed Streams

    DOE Patents [OSTI]

    Siriwardane, Ranjani

    2004-06-01

    A sorbent material is provided comprising a material reactive with sulfur, a binder unreactive with sulfur and an inert material, wherein the sorbent absorbs the sulfur at temperatures between 30 and 200 C. Sulfur absorption capacity as high as 22 weight percent has been observed with these materials.

  1. Taking out 1 billion tons of CO2: The magic of China's 11th Five-Year Plan?

    SciTech Connect (OSTI)

    Zhou, Nan; Lin, Jiang; Zhou, Nan; Levine, Mark; Fridley, David

    2007-07-01

    China's 11th Five-Year Plan (FYP) sets an ambitious target for energy-efficiency improvement: energy intensity of the country's gross domestic product (GDP) should be reduced by 20% from 2005 to 2010 (NDRC, 2006). This is the first time that a quantitative and binding target has been set for energy efficiency, and signals a major shift in China's strategic thinking about its long-term economic and energy development. The 20% energy intensity target also translates into an annual reduction of over 1.5 billion tons of CO2 by 2010, making the Chinese effort one of most significant carbon mitigation effort in the world today. While it is still too early to tell whether China will achieve this target, this paper attempts to understand the trend in energy intensity in China and to explore a variety of options toward meeting the 20% target using a detailed end-use energy model.

  2. System for adding sulfur to a fuel cell stack system for improved fuel cell stability

    DOE Patents [OSTI]

    Mukerjee, Subhasish; Haltiner, Jr., Karl J; Weissman, Jeffrey G

    2013-08-13

    A system for adding sulfur to a reformate stream feeding a fuel cell stack, having a sulfur source for providing sulfur to the reformate stream and a metering device in fluid connection with the sulfur source and the reformate stream. The metering device injects sulfur from the sulfur source to the reformate stream at a predetermined rate, thereby providing a conditioned reformate stream to the fuel cell stack. The system provides a conditioned reformate stream having a predetermined sulfur concentration that gives an acceptable balance of minimal drop in initial power with the desired maximum stability of operation over prolonged periods for the fuel cell stack.

  3. Clean Cities 2013 Annual Metrics Report

    SciTech Connect (OSTI)

    Johnson, C.; Singer, M.

    2014-10-01

    Each year, the U.S. Department of Energy asks its Clean Cities program coordinators to submit annual reports of their activities and accomplishments for the previous calendar year. Data and information are submitted via an online database that is maintained as part of the Alternative Fuels Data Center (AFDC) at the National Renewable Energy Laboratory (NREL). Coordinators submit a range of data that characterize the membership, funding, projects, and activities of their coalitions. They also submit data about sales of alternative fuels, deployment of alternative fuel vehicles (AFVs) and hybrid electric vehicles (HEVs), idle-reduction (IR) initiatives, fuel economy activities, and programs to reduce vehicle miles traveled (VMT). NREL analyzes the data and translates them into petroleum-use reduction impacts, which are summarized in this 2013 Annual Metrics Report.

  4. Bi-metric Gravity and "Dark Matter"

    E-Print Network [OSTI]

    I. T. Drummond

    2000-08-18

    We present a bi-metric theory of gravity containing a length scale of galactic size. For distances less than this scale the theory satisfies the standard tests of General Relativity. For distances greater than this scale the theory yields an effective gravitational constant much larger than the locally observed value of Newton's constant. The transition from one regime to the other through the galactic scale can explain the observed rotation curves of galaxies and hence the effects normally attributed to the presence of dark matter. Phenomena on an extragalactic scale such as galactic clusters and the expansion of the universe are controlled by the enhanced gravitational coupling. This provides an explanation of the missing matter normally invoked to account for the observed value of Hubble's constant in relation to observed matter.

  5. Methods and results for stress analyses on 14-ton, thin-wall depleted UF{sub 6} cylinders

    SciTech Connect (OSTI)

    Kirkpatrick, J.R.; Chung, C.K.; Frazier, J.L.; Kelley, D.K.

    1996-10-01

    Uranium enrichment operations at the three US gaseous diffusion plants produce depleted uranium hexafluoride (DUF{sub 6}) as a residential product. At the present time, the inventory of DUF{sub 6} in this country is more than half a million tons. The inventory of DUF{sub 6} is contained in metal storage cylinders, most of which are located at the gaseous diffusion plants. The principal objective of the project is to ensure the integrity of the cylinders to prevent causing an environmental hazard by releasing the contents of the cylinders into the atmosphere. Another objective is to maintain the cylinders in such a manner that the DUF{sub 6} may eventually be converted to a less hazardous material for final disposition. An important task in the DUF{sub 6} cylinders management project is determining how much corrosion of the walls can be tolerated before the cylinders are in danger of being damaged during routine handling and shipping operations. Another task is determining how to handle cylinders that have already been damaged in a manner that will minimize the chance that a breach will occur or that the size of an existing breach will be significantly increased. A number of finite element stress analysis (FESA) calculations have been done to analyze the stresses for three conditions: (1) while the cylinder is being lifted, (2) when a cylinder is resting on two cylinders under it in the customary two-tier stacking array, and (3) when a cylinder is resting on tis chocks on the ground. Various documents describe some of the results and discuss some of the methods whereby they have been obtained. The objective of the present report is to document as many of the FESA cases done at Oak Ridge for 14-ton thin-wall cylinders as possible, giving results and a description of the calculations in some detail.

  6. Abatement of Air Pollution: Control of Sulfur Compound Emissions...

    Broader source: Energy.gov (indexed) [DOE]

    set limits on the sulfur content of allowable fuels (1.0% by weight, dry basis) for combustion, as well as for the heat input of any fuel burning equipment (250,000 Btuhour)....

  7. Physiology of multiple sulfur isotope fractionation during microbial sulfate reduction

    E-Print Network [OSTI]

    Sim, Min Sub

    2012-01-01

    Microbial sulfate reduction (MSR) utilizes sulfate as an electron acceptor and produces sulfide that is depleted in heavy isotopes of sulfur relative to starting sulfate. The fractionation of S-isotopes is commonly used ...

  8. Impact of Sulfur Oxides on Mercury Capture by Activated Carbon

    SciTech Connect (OSTI)

    Presto, A.A.; Granite, E.J.

    2007-09-15

    Recent field tests of mercury removal with activated carbon injection (ACI) have revealed that mercury capture is limited in flue gases containing high concentrations of sulfur oxides (SOx). In order to gain a more complete understanding of the impact of SOx on ACI, mercury capture was tested under varying conditions of SO2 and SO3 concentrations using a packed bed reactor and simulated flue gas (SFG). The final mercury content of the activated carbons is independent of the SO2 concentration in the SFG, but the presence of SO3 inhibits mercury capture even at the lowest concentration tested (20 ppm). The mercury removal capacity decreases as the sulfur content of the used activated carbons increases from 1 to 10%. In one extreme case, an activated carbon with 10% sulfur, prepared by H2SO4 impregnation, shows almost no mercury capacity. The results suggest that mercury and sulfur oxides are in competition for the same binding sites on the carbon surface.

  9. Carbonyl sulfide: potential agent of atmospheric sulfur corrosion

    SciTech Connect (OSTI)

    Graedel, T.E.; Kammlott, G.W.; Franey, J.P.

    1981-05-08

    Laboratory exposure experiments demonstrate that carbonyl sulfide in wet air corrodes copper at 22/sup 0/C at a rate that is approximately linear with total exposure (the product of exposure time and carbonyl sulfide concentration). The corrosion rate is similar to that of hydrogen sulfide, a widely recognized corrodant. The much greater average atmospheric abundance of carbonyl sulfide compared with that of hydrogen sulfide or sulfur dioxide suggests that carbonyl sulfide may be a major agent of atmospheric sulfur corrosion.

  10. Ultra Low Sulfur Home Heating Oil Demonstration Project

    SciTech Connect (OSTI)

    Batey, John E.; McDonald, Roger

    2015-09-30

    This Ultra Low Sulfur (ULS) Home Heating Oil Demonstration Project was funded by the New York State Energy Research and Development Authority (NYSERDA) and has successfully quantified the environmental and economic benefits of switching to ULS (15 PPM sulfur) heating oil. It advances a prior field study of Low Sulfur (500 ppm sulfur) heating oil funded by NYSERDA and laboratory research conducted by Brookhaven National Laboratory (BNL) and Canadian researchers. The sulfur oxide and particulate matter (PM) emissions are greatly reduced as are boiler cleaning costs through extending cleaning intervals. Both the sulfur oxide and PM emission rates are directly related to the fuel oil sulfur content. The sulfur oxide and PM emission rates approach near-zero levels by switching heating equipment to ULS fuel oil, and these emissions become comparable to heating equipment fired by natural gas. This demonstration project included an in-depth review and analysis of service records for both the ULS and control groups to determine any difference in the service needs for the two groups. The detailed service records for both groups were collected and analyzed and the results were entered into two spreadsheets that enabled a quantitative side-by-side comparison of equipment service for the entire duration of the ULS test project. The service frequency for the ULS and control group were very similar and did indicate increased service frequency for the ULS group. In fact, the service frequency with the ULS group was slightly less (7.5 percent) than the control group. The only exception was that three burner fuel pump required replacement for the ULS group and none were required for the control group.

  11. An electrochemical Claus process for sulfur recovery

    SciTech Connect (OSTI)

    Pujare, N.U.; Tsai, K.J.; Sammuells, A.F. (Eltron Research, Inc., Aurora, IL (US))

    1989-12-01

    Electrochemical oxidation of H{sub 2}S to give sulfur and water was achieved at 900{degrees}C using fuel cells possessing the general configuration where anode electrocatalysts experimentally investigated for promoting the subject oxidation reaction included WS{sub 2} and the thiospinels CuNi{sub 2}S{sub 4}, CuCo{sub 2}S{sub 4}, CuFe{sub 2}S{sub 4}, and NiFe{sub 2}S{sub 4}. The predominant oxidizable electroactive species present in the fuel cell anode compartment was suggested to be hydrogen originating from the initial thermal dissociation of H{sub 2}S (H{sub 2}S {r reversible} H{sub 2} + 1/2 S{sub 2}) at fuel cell operating temperatures. Rapid anode kinetics were found for the anodic reaction with the empirical trend for exchange currents (i{sub o}) per geometric area being found to be NiFe{sub 2}S{sub 4}{gt}WS{sub 2}{gt}CuCo{sub 2}S{sub 4}{gt}CuFe{sub 2}S{sub 4}{approx equal}NiCo{sub 2}S{sub 4}{gt}CuNi{sub 2}S{sub 4}.

  12. A Content Propagation Metric for Efficient Content Distribution

    E-Print Network [OSTI]

    Keinan, Alon

    A Content Propagation Metric for Efficient Content Distribution Ryan S. Peterson Cornell University@cs.cornell.edu ABSTRACT Efficient content distribution in large networks comprising data- centers, end hosts, and distributed in-network caches is a diffi- cult problem. Existing systems rely on mechanisms and metrics

  13. Metrics for Evaluating Conventional and Renewable Energy Technologies (Presentation)

    SciTech Connect (OSTI)

    Mann, M. K.

    2013-01-01

    With numerous options for the future of natural gas, how do we know we're going down the right path? How do we designate a metric to measure and demonstrate change and progress, and how does that metric incorporate all stakeholders and scenarios?

  14. Primordial fluctuations of the metric in the warm inflation scenario

    E-Print Network [OSTI]

    Mauricio Bellini

    2000-05-16

    I consider a semiclassical expansion of the scalar field in the warm inflation scenario. I study the evolution for the fluctuations of the metric around the Friedmann-Robertson-Walker one. The formalism predicts that, in the power-law expansion universe, the fluctuations of the metric decreases with time.

  15. Self-benchmarking Guide for Data Centers: Metrics, Benchmarks, Actions

    E-Print Network [OSTI]

    LBNL-3393E Self-benchmarking Guide for Data Centers: Metrics, Benchmarks, Actions Paul Mathew (CEC), and by the U.S. Department of Energy, under Contract No. DE-AC02- 05CH11231. #12;Data Center ........................................................................................................3 3. Overall Data Center Performance Metrics

  16. A Primer on Hardware Security: Models, Methods, and Metrics

    E-Print Network [OSTI]

    INVITED P A P E R A Primer on Hardware Security: Models, Methods, and Metrics The paper is a primer on hardware security threat models, metrics, and remedies. By Masoud Rostami, Farinaz Koushanfar, and Ramesh) production supply chain has intro- duced hardware-based vulnerabilities. Existing literature in hardware

  17. PRIMARY RESEARCH PAPER Summer stream temperature metrics for predicting brook

    E-Print Network [OSTI]

    Vermont, University of

    -012-1336-1 #12;affected by warm water temperatures. Long-term stream temperature monitoring is useful biological surveys; thus, using temperature is appealing as a first-cut metric for monitoring fishPRIMARY RESEARCH PAPER Summer stream temperature metrics for predicting brook trout (Salvelinus

  18. Scalars, Vectors and Tensors from Metric-Affine Gravity

    E-Print Network [OSTI]

    Karahan, Canan N; Demir, Durmus A

    2011-01-01

    The metric-affine gravity provides a useful framework for analyzing gravitational dynamics since it treats metric tensor and affine connection as fundamentally independent variables. In this work, we show that, a metric-affine gravity theory composed of the invariants formed from non-metricity, torsion and curvature tensors decomposes exhaustively into a theory of scalar, vector and tensor fields. These fields are natural candidates for the ones needed by various cosmological phenomena. Indeed, we show that the model accommodates TeVeS gravity (relativistic modified gravity theory), vector inflation, and aether-like models. Detailed analyses of these and other phenomena can lead to a standard metric-affine gravity model encoding scalars, vectors and tensors necessitated by cosmology.

  19. Scalars, Vectors and Tensors from Metric-Affine Gravity

    E-Print Network [OSTI]

    Canan N. Karahan; Asli Altas; Durmus A. Demir

    2013-02-02

    The metric-affine gravity provides a useful framework for analyzing gravitational dynamics since it treats metric tensor and affine connection as fundamentally independent variables. In this work, we show that, a metric-affine gravity theory composed of the invariants formed from non-metricity, torsion and curvature tensors can be decomposed into a theory of scalar, vector and tensor fields. These fields are natural candidates for the ones needed by various cosmological and other phenomena. Indeed, we show that the model accommodates TeVeS gravity (relativistic modified gravity theory), vector inflation, and aether-like models. Detailed analyses of these and other phenomena can lead to a standard metric-affine gravity model encoding scalars, vectors and tensors.

  20. Can Fault Prediction Models and Metrics be Used for Vulnerability Prediction? Yonghee Shin and Laurie Williams

    E-Print Network [OSTI]

    Young, R. Michael

    are built with traditional metrics of complexity, code churn, and fault history. We have performed to the code [17]. Hence, complexity metrics and code churn metrics have been used for fault prediction [5, 17 fault prediction metrics ­ complexity, code churn, and fault history metrics for vulnerability

  1. Practical Diagnostics for Evaluating Residential Commissioning Metrics

    SciTech Connect (OSTI)

    Wray, Craig; Walker, Iain; Siegel, Jeff; Sherman, Max

    2002-06-11

    In this report, we identify and describe 24 practical diagnostics that are ready now to evaluate residential commissioning metrics, and that we expect to include in the commissioning guide. Our discussion in the main body of this report is limited to existing diagnostics in areas of particular concern with significant interactions: envelope and HVAC systems. These areas include insulation quality, windows, airtightness, envelope moisture, fan and duct system airflows, duct leakage, cooling equipment charge, and combustion appliance backdrafting with spillage. Appendix C describes the 83 other diagnostics that we have examined in the course of this project, but that are not ready or are inappropriate for residential commissioning. Combined with Appendix B, Table 1 in the main body of the report summarizes the advantages and disadvantages of all 107 diagnostics. We first describe what residential commissioning is, its characteristic elements, and how one might structure its process. Our intent in this discussion is to formulate and clarify these issues, but is largely preliminary because such a practice does not yet exist. Subsequent sections of the report describe metrics one can use in residential commissioning, along with the consolidated set of 24 practical diagnostics that the building industry can use now to evaluate them. Where possible, we also discuss the accuracy and usability of diagnostics, based on recent laboratory work and field studies by LBNL staff and others in more than 100 houses. These studies concentrate on evaluating diagnostics in the following four areas: the DeltaQ duct leakage test, air-handler airflow tests, supply and return grille airflow tests, and refrigerant charge tests. Appendix A describes those efforts in detail. In addition, where possible, we identify the costs to purchase diagnostic equipment and the amount of time required to conduct the diagnostics. Table 1 summarizes these data. Individual equipment costs for the 24 practical diagnostics range from a few hundred dollars to many thousands of dollars. The higher costs are associated with infrared thermography and state-of-the-art automated diagnostic systems. Most tests can be performed in one hour or less, using equipment priced toward the lower end of the cost spectrum.

  2. Lithium-Sulfur Batteries: Development of High Energy Lithium-Sulfur Cells for Electric Vehicle Applications

    SciTech Connect (OSTI)

    2010-10-01

    BEEST Project: Sion Power is developing a lithium-sulfur (Li-S) battery, a potentially cost-effective alternative to the Li-Ion battery that could store 400% more energy per pound. All batteries have 3 key parts—a positive and negative electrode and an electrolyte—that exchange ions to store and release electricity. Using different materials for these components changes a battery’s chemistry and its ability to power a vehicle. Traditional Li-S batteries experience adverse reactions between the electrolyte and lithium-based negative electrode that ultimately limit the battery to less than 50 charge cycles. Sion Power will sandwich the lithium- and sulfur-based electrode films around a separator that protects the negative electrode and increases the number of charges the battery can complete in its lifetime. The design could eventually allow for a battery with 400% greater storage capacity per pound than Li-Ion batteries and the ability to complete more than 500 recharge cycles.

  3. Generalized Transformation Design: metrics, speeds, and diffusion

    E-Print Network [OSTI]

    Kinsler, Paul

    2015-01-01

    We show that a unified and maximally generalized approach to spatial transformation design is possible, one that encompasses all second order waves, rays, or diffusion processes in anisotropic media. At the design step it is \\emph{not} necessary to specify the physical process for which a specific device will be -- or is intended to be -- built. The primary approximation required is that the effect of wave impedance is neglected, an attribute that plays no role in ray propagation, and therefore is not relevant for pure ray devices; another constraint is that spatial variation in material parameters may need to be sufficiently small. Device construction relies on how we can re-imagine the abstract mathematical notion of a metric on a manifold as a speed-squared matrix (or a diffusion matrix), a step which also specifies the means by which transformation devices will actually be built. Notably, we can conclude that a generalised ray theory that allows for anisotropic indexes (speeds) generates the same predicti...

  4. (Data in metric tons of yttrium oxide (Y O ) content, unless otherwise noted)2 3 Domestic Production and Use: The rare-earth element, yttrium, was mined as a constituent of the mineral bastnasite,

    E-Print Network [OSTI]

    /31/98 Thorium ores and concentrates (monazite) 2612.20.0000 Free Free. Rare-earth metals, scandium and yttrium Domestic Production and Use: The rare-earth element, yttrium, was mined as a constituent of the mineral bastnasite, but was not recovered as a separate element during processing. Bastnasite, a rare-earth

  5. (Data in metric tons of yttrium oxide (Y2O3) content, unless noted) Domestic Production and Use: The rare-earth element, yttrium, was mined by one company as a constituent of the

    E-Print Network [OSTI]

    ores and concentrates (monazite) 2612.20.0000 Free Free. Rare-earth metals, scandium and yttrium Production and Use: The rare-earth element, yttrium, was mined by one company as a constituent of the mineral bastnasite, but was not recovered as a separate element during processing. Bastnasite, a rare-earth

  6. (Data in metric tons of yttrium oxide (Y2O3) content unless otherwise noted) Domestic Production and Use: The rare-earth element yttrium was not mined in the United States in 2005. All

    E-Print Network [OSTI]

    -31-05 Thorium ores and concentrates (monazite) 2612.20.0000 Free. Rare-earth metals, scandium and yttrium Production and Use: The rare-earth element yttrium was not mined in the United States in 2005. All yttrium and compounds containing by weight >19% to rare-earth compounds, including

  7. [Data in metric tons of yttrium oxide (Y2O3) content unless otherwise noted] Domestic Production and Use: Rare earths were mined by one U.S. company in 2012. Bastnasite, a rare-earth

    E-Print Network [OSTI]

    and concentrates (monazite) 2612.20.0000 Free. Rare-earth metals, scandium and yttrium, whether or not intermixed Production and Use: Rare earths were mined by one U.S. company in 2012. Bastnasite, a rare-earth% Y2O3 2846.90.4000 Free. Other rare-earth compounds, including yttrium oxide >85% Y2O3, yttrium

  8. (Data in metric tons of yttrium oxide (Y O ) content, unless otherwise noted)2 3 Domestic Production and Use: The rare-earth element, yttrium, was mined by one company as a constituent of the

    E-Print Network [OSTI]

    /31/96 Thorium ores and concentrates (monazite) 2612.20.0000 Free Free. Rare-earth metals, scandium and yttrium Domestic Production and Use: The rare-earth element, yttrium, was mined by one company as a constituent of the mineral bastnasite, but was not recovered as a separate element during processing. Bastnasite, a rare-earth

  9. (Data in metric tons of yttrium oxide (Y2O3) content, unless otherwise noted) Domestic Production and Use: The rare-earth element yttrium was mined as a constituent of the mineral bastnasite,

    E-Print Network [OSTI]

    and concentrates (monazite) 2612.20.0000 Free. Rare-earth metals, scandium and yttrium, whether or not intermixed Production and Use: The rare-earth element yttrium was mined as a constituent of the mineral bastnasite, but was not recovered as a separate element during processing. Bastnasite, a rare-earth fluocarbonate mineral, was mined

  10. (Data in metric tons of yttrium oxide (Y2O3) content unless otherwise noted) Domestic Production and Use: The rare-earth element yttrium was not mined in the United States in 2009. All

    E-Print Network [OSTI]

    . Rare-earth metals, scandium and yttrium, whether or not intermixed or interalloyed 2805.30.0000 5.0% ad Production and Use: The rare-earth element yttrium was not mined in the United States in 2009. All yttrium. Other rare-earth compounds, including yttrium oxide >85% Y2O3, yttrium nitrate, and other individual

  11. (Data in metric tons of yttrium oxide (Y2O3) content unless otherwise noted) Domestic Production and Use: The rare-earth element yttrium was not mined in the United States in 2006. All

    E-Print Network [OSTI]

    -31-06 Thorium ores and concentrates (monazite) 2612.20.0000 Free. Rare-earth metals, scandium and yttrium Production and Use: The rare-earth element yttrium was not mined in the United States in 2006. All yttrium and compounds containing by weight >19% to rare-earth compounds, including

  12. (Data in metric tons of yttrium oxide (Y2O3) content unless otherwise noted) Domestic Production and Use: The rare-earth element yttrium was not mined in the United States in 2008. All

    E-Print Network [OSTI]

    12-31-08 Thorium ores and concentrates (monazite) 2612.20.0000 Free. Rare-earth metals, scandium Production and Use: The rare-earth element yttrium was not mined in the United States in 2008. All yttrium and compounds containing by weight >19% to rare-earth compounds, including

  13. (Data in metric tons of yttrium oxide (Y O ) content, unless otherwise noted)2 3 Domestic Production and Use: The rare-earth element, yttrium, was mined by one company as a constituent of the

    E-Print Network [OSTI]

    .20.0000 Free Free. Rare-earth metals, scandium and yttrium, whether or not intermixed or interalloyed 2805 Domestic Production and Use: The rare-earth element, yttrium, was mined by one company as a constituent of the mineral bastnasite, but was not recovered as a separate element during processing. Bastnasite, a rare-earth

  14. [Data in metric tons of yttrium oxide (Y2O3) content unless otherwise noted] Domestic Production and Use: The rare-earth element yttrium was not mined in the United States in 2010. All

    E-Print Network [OSTI]

    . Rare-earth metals, scandium and yttrium, whether or not intermixed or interalloyed 2805.30.0000 5.0% ad Production and Use: The rare-earth element yttrium was not mined in the United States in 2010. All yttrium. Other rare-earth compounds, including yttrium oxide >85% Y2O3, yttrium nitrate, and other individual

  15. (Data in metric tons of yttrium oxide (Y2O3) content, unless otherwise noted) Domestic Production and Use: The rare-earth element, yttrium, was mined as a constituent of the mineral

    E-Print Network [OSTI]

    .20.0000 Free. Rare-earth metals, scandium and yttrium, whether or not intermixed or interalloyed 2805.30.0000 5 Production and Use: The rare-earth element, yttrium, was mined as a constituent of the mineral bastnasite, but was not recovered as a separate element during processing. Bastnasite, a rare-earth fluocarbonate mineral, was mined

  16. (Data in metric tons of yttrium oxide (Y2O3) content unless otherwise noted) Domestic Production and Use: The rare-earth element yttrium was not mined in the United States in 2004. Yttrium

    E-Print Network [OSTI]

    Relations 12-31-04 Thorium ores and concentrates (monazite) 2612.20.0000 Free. Rare-earth metals, scandium Production and Use: The rare-earth element yttrium was not mined in the United States in 2004. Yttrium and compounds containing by weight >19% to rare-earth compounds, including

  17. (Data in metric tons of yttrium oxide (Y2O3) content, unless otherwise noted) Domestic Production and Use: The rare-earth element yttrium was not mined in the United States in 2003.

    E-Print Network [OSTI]

    Relations 12/31/03 Thorium ores and concentrates (monazite) 2612.20.0000 Free. Rare-earth metals, scandium Production and Use: The rare-earth element yttrium was not mined in the United States in 2003. Yttrium and compounds containing by weight >19% to rare-earth compounds, including

  18. (Data in thousand metric tons of silicon content unless otherwise noted) Domestic Production and Use: Estimated value of silicon alloys and metal produced in the United States in 2012

    E-Print Network [OSTI]

    and aluminum alloys and the chemical industry. The semiconductor and solar industries, which manufacture chips%; and other, 5%. Silicon metal: Brazil, 41%; South Africa, 20%; Canada, 12%; Australia, 9%; and other, 18 materials source for aluminum-silicon alloys--was projected to increase by 10% in 2012 compared

  19. (Data in thousand metric tons of silicon content unless otherwise noted) Domestic Production and Use: Estimated value of silicon alloys produced in the United States in 2010 was $770

    E-Print Network [OSTI]

    producers of aluminum and aluminum alloys and the chemical industry. The semiconductor and solar industries%; South Africa, 28%; Canada, 17%; Australia, 10%; and other, 1%. Total: China, 26%; Brazil, 21%; Norway apparent consumption by 38%. This was in line with the projected 38% increase in domestic steel production

  20. (Data in thousand metric tons of silicon content unless otherwise noted) Domestic Production and Use: Estimated value of silicon alloys and metal produced in the United States in 2011

    E-Print Network [OSTI]

    and aluminum alloys and the chemical industry. The semiconductor and solar industries, which manufacture chips%; and other, 4%. Silicon metal: Brazil, 39%; South Africa, 22%; Canada, 13%; Australia, 10%; and other, 16 secondary aluminum production--the primary materials source for aluminum-silicon alloys--was projected

  1. Schwarzschild-like metric and a quantum vacuum

    E-Print Network [OSTI]

    P. R. Silva

    2013-02-01

    A quantum vacuum, represented by a viscous fluid, is added to the Einstein vacuum, surrounding a spherical distribution of mass. This gives as a solution, in spherical coordinates, a Schwarzschild-like metric. The plot of g00 and g11 components of the metric, as a function of the radial coordinate, display the same qualitative behavior as that of the Schwarzschild metric. However, the temperature of the event horizon is equal to the Hawking temperature multiplied by a factor of two, while the entropy is equal to half of the Bekenstein one.

  2. Chemical reactions of UF{sub 6} with water on ingress to damaged model 48X 10 ton cylinder

    SciTech Connect (OSTI)

    Rothman, A.B.

    1996-02-01

    Chemistry studies of the effects of water flooding in Model 48X 10-ton UF{sub 6} storage cylinders, as a result of impact fractures, were conducted to support the Safety Analysis Report for Packaging (SARP) review of the Paducah Tiger Overpack for transportation of those cylinders. The objectives of the study were to determine the maximum amount of water that could be admitted to the interior of such a damaged cylinder, the resulting geometries and chemical compositions from reactions of water with the UF{sub 6} contents of the cylinder, and the end-state water moderated and reflected configurations for input to nuclear criticality safety analyses. The case identified for analysis was the flooding of the inside of a cylinder, submerged horizontally in 3 ft of water. The flooding was driven by an initial pressure drop of 13 psig, through an assumed fracture (1/32 in. wide {times} 1/2 in. deep {times} 18 in. long) in the barrel of the cylinder. During the initial addition of water, transient back pressures occur from the effects of the heats of reaction and solution at the water/UF{sub 6} interface, with some chugging as more water is added to alternately coot the reaction surface and then heat it again as the added water reacts with more UF{sub 6}.

  3. Sulfur gas emissions from stored flue-gas-desulfurization sludges

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.

    1980-01-01

    In field studies conducted for the Electric Power Research Institute by the University of Washington (1978) and the University of Idaho (1979), 13 gas samples from sludge storage sites at coal-burning power plants were analyzed by wall-coated open-tube cryogenic capillary-column gas chromatography with a sulfur-selective flame-photometric detector. Hydrogen sulfide, carbonyl sulfide, dimethyl sulfide, carbon disulfide, and dimethyl disulfide were identified in varying concentrations and ratios in the emissions from both operating sludge ponds and landfills and from FGD sludge surfaces that had been stored in the open for 3-32 mo or longer. Other sulfur compounds, probably propanethiols, were found in emissions from some sludges. Chemical ''stabilization/fixation'' sulfate-sulfite ratio, sludge water content, and temperature were the most significant variables controlling sulfur gas production. The average sulfur emissions from each of the 13 FGD storage sites ranged from 0.01 to 0.26 g/sq m/yr sulfur.

  4. Process for removal of sulfur compounds from fuel gases

    DOE Patents [OSTI]

    Moore, Raymond H. (Richland, WA); Stegen, Gary E. (Richland, WA)

    1978-01-01

    Fuel gases such as those produced in the gasification of coal are stripped of sulfur compounds and particulate matter by contact with molten metal salt. The fuel gas and salt are intimately mixed by passage through a venturi or other constriction in which the fuel gas entrains the molten salt as dispersed droplets to a gas-liquid separator. The separated molten salt is divided into a major and a minor flow portion with the minor flow portion passing on to a regenerator in which it is contacted with steam and carbon dioxide as strip gas to remove sulfur compounds. The strip gas is further processed to recover sulfur. The depleted, minor flow portion of salt is passed again into contact with the fuel gas for further sulfur removal from the gas. The sulfur depleted, fuel gas then flows through a solid absorbent for removal of salt droplets. The minor flow portion of the molten salt is then recombined with the major flow portion for feed to the venturi.

  5. Weigh options for meeting future gasoline sulfur specifications

    SciTech Connect (OSTI)

    Johnson, T.E.

    1997-03-01

    The most frequently mentioned methods for reducing pool gasoline sulfur to the 50-ppm range are FCC feed hydrotreating and desulfurization of heavy cat naptha (HCN). Of these, cat feed hydrotreating (CFH) is preferred because of the compelling economics of improved FCC gasoline yield. Also, the additional C{sub 3}/C{sub 4} olefin yield opens up the possibility of additional production of sulfur-free alkylate and oxygenate. In addition to the obvious yield benefits, the ability to upgrade lower quality, higher sulfur stocks for inclusion in the FCC charge slate, while lowering flue gas SO{sub x} emissions, is also advantageous to the refiner. However, depending o the level of FCC feed sulfur and the severity of hydrotreating used, it may not be possible to meet 50-ppm sulfur in the gasoline pool. Two possible solutions to this problem are to use: (1) a very severe cat feed hydrotreating operation (i.e., 98%-plus desulfurization), (2) partial conversion hydrocracking.

  6. Gas phase reaction of sulfur trioxide with water vapor

    SciTech Connect (OSTI)

    Kolb, C.E.; Molina, M.J.; Jayne, J.T.; Meads, R.F.; Worsnop, D.R.

    1994-12-31

    Sulfur trioxide (SO3) has long been known to react with water to produce sulfuric acid (H2S04). It has been commonly assumed that the gas phase reaction in the Earth`s atmosphere between SO3 and water vapor to produce sulfuric acid vapor is an important step in the production of sulfuric acid aerosol particles. The kinetics of the gas phase reaction of SO3 with water vapor have previously been studied by Castleman and co-workers, Wang et al and Reiner and Arnold. Each of these studies was carried out in a flow reactor, with the first two studies performed at low pressure (1-10 Torr) and the latter from approx. 30 to 260 Torr. Each of these studies measured SO3 decays over a range of H2O vapor levels, obtaining data consistent with interpreting the reaction of gaseous SO3 and H2O as a bimolecular process. It is not clear why previous experimental studies failed to observe a nonlinear dependence of SO3 consumption on water vapor concentration. It is probable that sufficient water dimer exists in much of the Earth`s atmosphere to allow dimer reactions to participate in sulfuric acid vapor formation.

  7. ADDITIVE TESTING FOR IMPROVED SULFUR RETENTION: PRELIMINARY REPORT

    SciTech Connect (OSTI)

    Amoroso, J.; Fox, K.

    2011-09-07

    The Savannah River National Laboratory is collaborating with Alfred University to evaluate the potential for additives in borosilicate glass to improve sulfur retention. This preliminary report provides further background on the incorporation of sulfur in glass and outlines the experiments that are being performed by the collaborators. A simulated waste glass composition has been selected for the experimental studies. The first phase of experimental work will evaluate the impacts of BaO, PbO, and V{sub 2}O{sub 5} at concentrations of 1.0, 2.0, and 5.0 wt % on sulfate retention in simulated high level waste borosilicate glass. The second phase of experimental work will evaluate the effects of time at the melt temperature on sulfur retention. The resulting samples will be characterized to determine the amount of sulfur remaining as well as to identify the formation of any crystalline phases. The results will be used to guide the future selection of frits and glass forming chemicals in vitrifying Department of Energy wastes containing high sulfur concentrations.

  8. Process and system for removing sulfur from sulfur-containing gaseous streams

    DOE Patents [OSTI]

    Basu, Arunabha (Aurora, IL); Meyer, Howard S. (Hoffman Estates, IL); Lynn, Scott (Pleasant Hill, CA); Leppin, Dennis (Chicago, IL); Wangerow, James R. (Medinah, IL)

    2012-08-14

    A multi-stage UCSRP process and system for removal of sulfur from a gaseous stream in which the gaseous stream, which contains a first amount of H.sub.2S, is provided to a first stage UCSRP reactor vessel operating in an excess SO.sub.2 mode at a first amount of SO.sub.2, producing an effluent gas having a reduced amount of SO.sub.2, and in which the effluent gas is provided to a second stage UCSRP reactor vessel operating in an excess H.sub.2S mode, producing a product gas having an amount of H.sub.2S less than said first amount of H.sub.2S.

  9. The Development of Warm Gas Cleanup Technologies for the Removal of Sulfur Containing Species from Steam Hydrogasification

    E-Print Network [OSTI]

    Luo, Qian

    2012-01-01

    S breakthrough time and sulfur capture capacity increased asspace velocity on H 2 S on sulfur capture capacity for H 2 Sbased on the optimal sulfur capture capacity under CE-CERT

  10. Preliminary Investigation of Sulfur Loading in Hanford LAW Glass

    SciTech Connect (OSTI)

    Vienna, John D.; Hrma, Pavel R.; Buchmiller, William C.; Ricklefs, Joel S.

    2004-04-01

    A preliminary estimate was developed for loading limits for high-sulfur low-activity waste (LAW) feeds that will be vitrified into borosilicate glass at the Hanford Site in the waste-cleanup effort. Previous studies reported in the literature were consulted to provide a basis for the estimate. The examination of previous studies led to questions about sulfur loading in Hanford LAW glass, and scoping tests were performed to help answer these questions. These results of these tests indicated that a formulation approach developed by Vienna and colleagues shows promise for maximizing LAW loading in glass. However, there is a clear need for follow-on work. The potential for significantly lowering the amount of LAW glass produced at Hanford (after the initial phase of processing) because of higher sulfur tolerances may outweigh the cost and effort required to perform the necessary testing.

  11. Advanced byproduct recovery: Direct catalytic reduction of sulfur dioxide to elemental sulfur. Fourth quarterly technical progress report

    SciTech Connect (OSTI)

    NONE

    1997-01-01

    The team of Arthur D. Little, Tufts University and Engelhard Corporation are conducting Phase 1 of a four and a half year, two-phase effort to develop and scale-up an advanced byproduct recovery technology that is a direct, single-stage, catalytic process for converting sulfur dioxide to elemental sulfur. This catalytic process reduces SO{sub 2} over a fluorite-type oxide (such as ceria and zirconia). The catalytic activity can be significantly promoted by active transition metals, such as copper. More than 95% elemental sulfur yield, corresponding to almost complete sulfur dioxide conversion, was obtained over a Cu-Ce-O oxide catalyst as part of an on-going DOE-sponsored, University Coal Research Program. This type of mixed metal oxide catalyst has stable activity, high selectivity for sulfur production, and is resistant to water and carbon dioxide poisoning. Tests with CO and CH{sub 4} reducing gases indicate that the catalyst has the potential for flexibility with regard to the composition of the reducing gas, making it attractive for utility use. The performance of the catalyst is consistently good over a range of SO{sub 2} inlet concentration (0.1 to 10%) indicating its flexibility in treating SO{sub 2} tail gases as well as high concentration streams.

  12. Gromov-Hausdorff Distance for Quantum Metric Spaces

    E-Print Network [OSTI]

    Marc A. Rieffel

    2003-02-20

    By a quantum metric space we mean a C^*-algebra (or more generally an order-unit space) equipped with a generalization of the Lipschitz seminorm on functions which is defined by an ordinary metric. We develop for compact quantum metric spaces a version of Gromov-Hausdorff distance. We show that the basic theorems of the classical theory have natural quantum analogues. Our main example involves the quantum tori, $A_{\\th}$. We show, for consistently defined ``metrics'', that if a sequence $\\{\\th_n\\}$ of parameters converges to a parameter $\\th$, then the sequence $\\{A_{\\th_n}\\}$ of quantum tori converges in quantum Gromov-Hausdorff distance to $A_{\\th}$.

  13. Guidelines and Metrics for Configurable and Sustainable Architectural Knowledge Modelling

    E-Print Network [OSTI]

    Brezany, Peter

    Guidelines and Metrics for Configurable and Sustainable Architectural Knowledge Modelling ABSTRACT erosion, architecture knowledge, technical sustainability, technical debt. 1. INTRODUCTION Architectural to achieve architecture sustainability. Our main contributions of this paper is a configurable meta

  14. A Topography-Preserving Latent Variable Model with Learning Metrics

    E-Print Network [OSTI]

    Kaski, Samuel

    A Topography-Preserving Latent Variable Model with Learning Metrics Samuel Kaski and Janne grid to the input spa- ce. The mapping preserves the topography but measures local distances in terms

  15. Square Root of Metric: The Geometry Background of Unified Theory?

    E-Print Network [OSTI]

    De-Sheng Li

    2015-09-29

    We use the square root of inverse metric described by $l=u^{\\dagger} \\gamma^{a} u \\theta_{a}$ construct an $U(4)$ gauge invariant, locally Lorentz invariant and generally covariant Lagrangian $\\mathcal{L}=\

  16. PROPAGATION OF SINGULARITIES FOR ROUGH METRICS HART F. SMITH

    E-Print Network [OSTI]

    Smith, Hart F.

    PROPAGATION OF SINGULARITIES FOR ROUGH METRICS HART F. SMITH Abstract. We use a wave packet the Simons Foundation (# 266371 to Hart Smith). 1 #12;2 HART F. SMITH H¨ormander's theorem [9] on propagation

  17. A Graph Analytic Metric for Mitigating Advanced Persistent Threat

    SciTech Connect (OSTI)

    Johnson, John R.; Hogan, Emilie A.

    2013-06-04

    This paper introduces a novel graph analytic metric that can be used to measure the potential vulnerability of a cyber network to specific types of attacks that use lateral movement and privilege escalation such as the well known Pass The Hash, (PTH). The metric is computed from an oriented subgraph of the underlying cyber network induced by selecting only those edges for which a given property holds between the two vertices of the edge. The metric with respect to a select node on the subgraph is defined as the likelihood that the select node is reachable from another arbitrary node in the graph. This metric can be calculated dynamically from the authorization and auditing layers during the network security authorization phase and will potentially enable predictive deterrence against attacks such as PTH.

  18. Analyses Of Two End-User Software Vulnerability Exposure Metrics

    SciTech Connect (OSTI)

    Jason L. Wright; Miles McQueen; Lawrence Wellman

    2012-08-01

    The risk due to software vulnerabilities will not be completely resolved in the near future. Instead, putting reliable vulnerability measures into the hands of end-users so that informed decisions can be made regarding the relative security exposure incurred by choosing one software package over another is of importance. To that end, we propose two new security metrics, average active vulnerabilities (AAV) and vulnerability free days (VFD). These metrics capture both the speed with which new vulnerabilities are reported to vendors and the rate at which software vendors fix them. We then examine how the metrics are computed using currently available datasets and demonstrate their estimation in a simulation experiment using four different browsers as a case study. Finally, we discuss how the metrics may be used by the various stakeholders of software and to software usage decisions.

  19. Analysis of Solar Cell Quality Using Voltage Metrics: Preprint

    SciTech Connect (OSTI)

    Toberer, E. S.; Tamboli, A. C.; Steiner, M.; Kurtz, S.

    2012-06-01

    The highest efficiency solar cells provide both excellent voltage and current. Of these, the open-circuit voltage (Voc) is more frequently viewed as an indicator of the material quality. However, since the Voc also depends on the band gap of the material, the difference between the band gap and the Voc is a better metric for comparing material quality of unlike materials. To take this one step further, since Voc also depends on the shape of the absorption edge, we propose to use the ultimate metric: the difference between the measured Voc and the Voc calculated from the external quantum efficiency using a detailed balance approach. This metric is less sensitive to changes in cell design and definition of band gap. The paper defines how to implement this metric and demonstrates how it can be useful in tracking improvements in Voc, especially as Voc approaches its theoretical maximum.

  20. Direct sulfur recovery during sorbent regeneration. Final report

    SciTech Connect (OSTI)

    Nelson, S.G.; Little, R.C. [Sorbent Technologies Corp., Twinsburg, OH (United States)

    1993-08-01

    The objective of this research project was to improve the direct elemental sulfur yields that occur during the regeneration of SO{sub 2}-saturated MgO-vermiculite sorbents (MagSorbents) by examining three approaches or strategies. The three approaches were regeneration-gas recycle, high-pressure regeneration, and catalytic reduction of the SO{sub 2} gas using a new catalyst developed by Research Triangle Institute (RTI). Prior to the project, Sorbent Technologies Corporation (Sorbtech) had developed a sorbent-regeneration process that yielded directly a pure elemental sulfur product. In the process, typically about 25 to 35 percent of the liberated S0{sub 2} was converted directly to elemental sulfur. The goal of this project was to achieve a conversion rate of over 90 percent. Good success was attained in the project. About 90 percent or more conversion was achieved with two of the approaches that were examined, regeneration-gas recycle and use of the RTI catalyst. Of these approaches, regeneration-gas recycle gave the best results (essentially 100 percent conversion in some cases). In the regeneration-gas recycle approach, saturated sorbent is simply heated to about 750{degree}C in a reducing gas (methane) atmosphere. During heating, a gas containing elemental sulfur, water vapor, H{sub 2}S, S0{sub 2}, and C0{sub 2} is evolved. The elemental sulfur and water vapor in the gas stream are condensed and removed, and the remaining gas is recycled back through the sorbent bed. After several recycles, the S0{sub 2} and H{sub 2}S completely disappear from the gas stream, and the stream contains only elemental sulfur, water vapor and C0{sub 2}.

  1. Improving fractionation lowers butane sulfur level at Saudi gas plant

    SciTech Connect (OSTI)

    Harruff, L.G.; Martinie, G.D.; Rahman, A. [Saudi Arabian Oil Co., Dhahran (Saudi Arabia)

    1998-10-12

    Increasing the debutanizer reflux/feed ratio to improve fractionation at an eastern Saudi Arabian NGL plant reduced high sulfur in the butane product. The sulfur resulted from dimethyl sulfide (DMS) contamination in the feed stream from an offshore crude-oil reservoir in the northern Arabian Gulf. The contamination is limited to two northeastern offshore gas-oil separation plants operated by Saudi Arabian Oil Co. (Saudi Aramco) and, therefore, cannot be transported to facilities outside the Eastern Province. Two technically acceptable solutions for removing this contaminant were investigated: 13X molecular-sieve adsorption of the DMS and increased fractionation efficiency. The latter would force DMS into the debutanizer bottoms.

  2. Hydrogen and sulfur recovery from hydrogen sulfide wastes

    DOE Patents [OSTI]

    Harkness, J.B.L.; Gorski, A.J.; Daniels, E.J.

    1993-05-18

    A process is described for generating hydrogen and elemental sulfur from hydrogen sulfide waste in which the hydrogen sulfide is [dis]associated under plasma conditions and a portion of the hydrogen output is used in a catalytic reduction unit to convert sulfur-containing impurities to hydrogen sulfide for recycle, the process also including the addition of an ionizing gas such as argon to initiate the plasma reaction at lower energy, a preheater for the input to the reactor and an internal adjustable choke in the reactor for enhanced coupling with the microwave energy input.

  3. Hydrogen and sulfur recovery from hydrogen sulfide wastes

    DOE Patents [OSTI]

    Harkness, John B. L. (Naperville, IL); Gorski, Anthony J. (Woodridge, IL); Daniels, Edward J. (Oak Lawn, IL)

    1993-01-01

    A process for generating hydrogen and elemental sulfur from hydrogen sulfide waste in which the hydrogen sulfide is associated under plasma conditions and a portion of the hydrogen output is used in a catalytic reduction unit to convert sulfur-containing impurities to hydrogen sulfide for recycle, the process also including the addition of an ionizing gas such as argon to initiate the plasma reaction at lower energy, a preheater for the input to the reactor and an internal adjustable choke in the reactor for enhanced coupling with the microwave energy input.

  4. Measures of agreement between computation and experiment:validation metrics.

    SciTech Connect (OSTI)

    Barone, Matthew Franklin; Oberkampf, William Louis

    2005-08-01

    With the increasing role of computational modeling in engineering design, performance estimation, and safety assessment, improved methods are needed for comparing computational results and experimental measurements. Traditional methods of graphically comparing computational and experimental results, though valuable, are essentially qualitative. Computable measures are needed that can quantitatively compare computational and experimental results over a range of input, or control, variables and sharpen assessment of computational accuracy. This type of measure has been recently referred to as a validation metric. We discuss various features that we believe should be incorporated in a validation metric and also features that should be excluded. We develop a new validation metric that is based on the statistical concept of confidence intervals. Using this fundamental concept, we construct two specific metrics: one that requires interpolation of experimental data and one that requires regression (curve fitting) of experimental data. We apply the metrics to three example problems: thermal decomposition of a polyurethane foam, a turbulent buoyant plume of helium, and compressibility effects on the growth rate of a turbulent free-shear layer. We discuss how the present metrics are easily interpretable for assessing computational model accuracy, as well as the impact of experimental measurement uncertainty on the accuracy assessment.

  5. Conformal Transformations in Metric-Affine Gravity and Ghosts

    E-Print Network [OSTI]

    Canan N. Karahan; Oktay Dogangun; Durmus A. Demir

    2012-05-20

    Conformal transformations play a widespread role in gravity theories in regard to their cosmological and other implications. In the pure metric theory of gravity, conformal transformations change the frame to a new one wherein one obtains a conformal-invariant scalar-tensor theory such that the scalar field, deriving from the conformal factor, is a ghost. In this work, conformal transformations and ghosts will be analyzed in the framework of the metric-affine theory of gravity. Within this framework, metric and connection are independent variables, and hence, transform independently under conformal transformations. It will be shown that, if affine connection is invariant under conformal transformations then the scalar field under concern is a non-ghost, non-dynamical field. It is an auxiliary field at the classical level, and might develop a kinetic term at the quantum level. Alternatively, if connection transforms additively with a structure similar to yet more general than that of the Levi-Civita connection, the resulting action describes the gravitational dynamics correctly, and more importantly, the scalar field becomes a dynamical non-ghost field. The equations of motion, for generic geometrical and matter-sector variables, do not reduce connection to the Levi-Civita connection, and hence, independence of connection from metric is maintained. Therefore, metric-affine gravity provides an arena in which ghosts arising from conformal factor are avoided thanks to the independence of connection from the metric.

  6. Structural insight into the assembly of iron-sulfur clusters and their function in radical generation

    E-Print Network [OSTI]

    Vey, Jessica L. (Jessica Lynn)

    2008-01-01

    This thesis addresses two emerging areas in the study of iron-sulfur cluster biochemistry: bioassembly of iron-sulfur clusters, and their involvement in initiation of radical chemistry. The structure of a cysteine desulfurase ...

  7. KINETICS AND MECHANISM FOR THE CATALYTIC OXIDATION OF SULFUR DIOXIDE ON CARBON IN AQUEOUS SUSPENSIONS

    E-Print Network [OSTI]

    Brodzinsky, R.

    2012-01-01

    AND MECHANISM FOR THE CATALYTIC OXIDATION OF SULFUR DIOXIDEmechanism for the catalytic oxidation of in an aqueous sus1ECHANISf 1 1 FOR TilE CATALYTIC OXIDATION OF SULFUR DIOXIDE

  8. A design strategy applied to sulfur resistant lean NOx̳ automotive catalysts

    E-Print Network [OSTI]

    Tang, Hairong

    2005-01-01

    Catalyst poisoning due to sulfur compounds derived from fuel sulfur presents a major challenge, intractable thus far, to development of many advanced technologies for automotive catalysts such as the lean NOx, trap. Under ...

  9. System for adding sulfur to a fuel cell stack system for improved fuel cell stability

    DOE Patents [OSTI]

    Mukerjee, Subhasish (Pittsford, NY); Haltiner, Jr., Karl J (Fairport, NY); Weissman, Jeffrey G. (West Henrietta, NY)

    2012-03-06

    A system for adding sulfur to a fuel cell stack, having a reformer adapted to reform a hydrocarbon fuel stream containing sulfur contaminants, thereby providing a reformate stream having sulfur; a sulfur trap fluidly coupled downstream of the reformer for removing sulfur from the reformate stream, thereby providing a desulfurized reformate stream; and a metering device in fluid communication with the reformate stream upstream of the sulfur trap and with the desulfurized reformate stream downstream of the sulfur trap. The metering device is adapted to bypass a portion of the reformate stream to mix with the desulfurized reformate stream, thereby producing a conditioned reformate stream having a predetermined sulfur concentration that gives an acceptable balance of minimal drop in initial power with the desired maximum stability of operation over prolonged periods for the fuel cell stack.

  10. XAX: a multi-ton, multi-target detection system for dark matter, double beta decay and pp solar neutrinos

    E-Print Network [OSTI]

    K. Arisaka; H. Wang; P. F. Smith; D. Cline; A. Teymourian; E. Brown; W. Ooi; D. Aharoni; C. W. Lam; K. Lung; S. Davies; M. Price

    2009-01-07

    A multi-target detection system XAX, comprising concentric 10 ton targets of 136Xe and 129/131Xe, together with a geometrically similar or larger target of liquid Ar, is described. Each is configured as a two-phase scintillation/ionization TPC detector, enhanced by a full 4pi array of ultra-low radioactivity Quartz Photon Intensifying Detectors (QUPIDs) replacing the conventional photomultipliers for detection of scintillation light. It is shown that background levels in XAX can be reduced to the level required for dark matter particle (WIMP) mass measurement at a 10^-10 pb WIMP-nucleon cross section, with single-event sensitivity below 10^-11 pb. The use of multiple target elements allows for confirmation of the A^2 dependence of a coherent cross section, and the different Xe isotopes provide information on the spin-dependence of the dark matter interaction. The event rates observed by Xe and Ar would modulate annually with opposite phases from each other for WIMP mass >~100 GeV/c^2. The large target mass of 136Xe and high degree of background reduction allow neutrinoless double beta decay to be observed with lifetimes of 10^27-10^28 years, corresponding to the Majorana neutrino mass range 0.01-0.1 eV, the most likely range from observed neutrino mass differences. The use of a 136Xe-depleted 129/131Xe target will also allow measurement of the pp solar neutrino spectrum to a precision of 1-2%.

  11. Review of corrosion in 10- and 14-ton mild steel depleted UF{sub 6} storage cylinders

    SciTech Connect (OSTI)

    Lykins, M.L.

    1995-08-01

    A literature review was conducted to determine the type, extent and severity of corrosion found in the 10- and 14-ton mild steel depleted UF{sub 6} storage cylinders. Also discussed in this review is corrosion found in the valves and plugs used in the cylinders. Corrosion of the cylinders is a gradual process which occurs slowly over time. Understanding corrosion of the cylinders is an important concern for long term storage of the UF{sub 6} in the cylinder yards, as well as the final disposition of the depleted UF{sub 6} tails inventory in the future. The following conclusions are made from the literature review: (1) The general external corrosion rate of the cylinders is about 1 to 2 mils per year (1 mil = 0.001{double_prime}). The highest general external corrosion rate was over 5 mpy on the 48G type cylinders. (2) General internal corrosion from the depleted UF{sub 6} is negligible under normal storage conditions. Crevice corrosion can occur at the cylinder/saddle interface from the retention of water in this area. Crevice corrosion can occur at the cylinder/skirt interface on the older skirted cylinders due to the lack of water drainage in this area. Crevice corrosion can occur on cylinders that have been in ground contact. Crevice corrosion and galvanic corrosion can occur where the stainless steel I.D. nameplates are attached to the cylinder. The packing nuts on the bronze one-inch valves used in the cylinders are susceptible to stress corrosion cracking (SCC). Mechanical damage from routine handling can lead to a breach in a cylinder with subsequent accelerated corrosion of the mild steel due to attack from HF and other UF{sub 6} hydrolysis by-products.

  12. Low Quality Natural Gas Sulfur Removal and Recovery CNG Claus Sulfur Recovery Process

    SciTech Connect (OSTI)

    Klint, V.W.; Dale, P.R.; Stephenson, C.

    1997-10-01

    Increased use of natural gas (methane) in the domestic energy market will force the development of large non-producing gas reserves now considered to be low quality. Large reserves of low quality natural gas (LQNG) contaminated with hydrogen sulfide (H{sub 2}S), carbon dioxide (CO{sub 2}) and nitrogen (N) are available but not suitable for treatment using current conventional gas treating methods due to economic and environmental constraints. A group of three technologies have been integrated to allow for processing of these LQNG reserves; the Controlled Freeze Zone (CFZ) process for hydrocarbon / acid gas separation; the Triple Point Crystallizer (TPC) process for H{sub 2}S / C0{sub 2} separation and the CNG Claus process for recovery of elemental sulfur from H{sub 2}S. The combined CFZ/TPC/CNG Claus group of processes is one program aimed at developing an alternative gas treating technology which is both economically and environmentally suitable for developing these low quality natural gas reserves. The CFZ/TPC/CNG Claus process is capable of treating low quality natural gas containing >10% C0{sub 2} and measurable levels of H{sub 2}S and N{sub 2} to pipeline specifications. The integrated CFZ / CNG Claus Process or the stand-alone CNG Claus Process has a number of attractive features for treating LQNG. The processes are capable of treating raw gas with a variety of trace contaminant components. The processes can also accommodate large changes in raw gas composition and flow rates. The combined processes are capable of achieving virtually undetectable levels of H{sub 2}S and significantly less than 2% CO in the product methane. The separation processes operate at pressure and deliver a high pressure (ca. 100 psia) acid gas (H{sub 2}S) stream for processing in the CNG Claus unit. This allows for substantial reductions in plant vessel size as compared to conventional Claus / Tail gas treating technologies. A close integration of the components of the CNG Claus process also allow for use of the methane/H{sub 2}S separation unit as a Claus tail gas treating unit by recycling the CNG Claus tail gas stream. This allows for virtually 100 percent sulfur recovery efficiency (virtually zero SO{sub 2} emissions) by recycling the sulfur laden tail gas to extinction. The use of the tail gas recycle scheme also deemphasizes the conventional requirement in Claus units to have high unit conversion efficiency and thereby make the operation much less affected by process upsets and feed gas composition changes. The development of these technologies has been ongoing for many years and both the CFZ and the TPC processes have been demonstrated at large pilot plant scales. On the other hand, prior to this project, the CNG Claus process had not been proven at any scale. Therefore, the primary objective of this portion of the program was to design, build and operate a pilot scale CNG Claus unit and demonstrate the required fundamental reaction chemistry and also demonstrate the viability of a reasonably sized working unit.

  13. A. Paytan and E.T. Gray Chapter 9 Sulfur Isotope Stratigraphy

    E-Print Network [OSTI]

    Paytan, Adina

    A. Paytan and E.T. Gray Chapter 9 Sulfur Isotope Stratigraphy Abstract: The sulfur isotopic.4. Measurement and Materials for Sulfur Isotope Stratigraphy 171 9.4.1. Isotope Analyses 171 9.4.2. Materials. The features in the record can also be used to correlate between stratigraphic sections and sequences

  14. The variability of methane, nitrous oxide and sulfur hexafluoride in Northeast India*

    E-Print Network [OSTI]

    The variability of methane, nitrous oxide and sulfur hexafluoride in Northeast India* A.L. Ganesan of methane, nitrous oxide and sulfur hexafluoride in Northeast India A. L. Ganesan1, A. Chatterjee2, R. G-frequency atmospheric measurements of methane (CH4), nitrous oxide (N2O) and sulfur hexafluo- ride (SF6) from Darjeeling

  15. Nitrogen dioxide, sulfur dioxide, and ammonia detector for remote sensing of vehicle emissions

    E-Print Network [OSTI]

    Denver, University of

    sulfur diesel fuel is less expensive due to reduced taxes and as such may be prone to illegal use in on-road November 2005; published online 18 January 2006 A remote sensor for measuring on-road vehicles passing of reducing sulfur in fuel for all mobile sources. This process begins with ultralow sulfur on-road diesel

  16. Paper 2008-01-0434 Effects of Sulfur Level and Anisotropy of Sulfide Inclusions on

    E-Print Network [OSTI]

    Fatemi, Ali

    to fatigue strength, the high sulfur material had up to 25% lower fatigue strength than the ultra low sulfur, monotonic tensile and CVN impact behavior of SAE 4140 steel with high (0.077% S), low (0.012% S) and ultra low (0.004% S) sulfur contents at two hardness levels (40 HRC and 50 HRC). The longitudinally oriented

  17. Doped carbon-sulfur species nanocomposite cathode for Li--S batteries

    DOE Patents [OSTI]

    Wang, Donghai; Xu, Tianren; Song, Jiangxuan

    2015-12-29

    We report a heteroatom-doped carbon framework that acts both as conductive network and polysulfide immobilizer for lithium-sulfur cathodes. The doped carbon forms chemical bonding with elemental sulfur and/or sulfur compound. This can significantly inhibit the diffusion of lithium polysulfides in the electrolyte, leading to high capacity retention and high coulombic efficiency.

  18. Vapor phase elemental sulfur amendment for sequestering mercury in contaminated soil

    DOE Patents [OSTI]

    Looney, Brian B.; Denham, Miles E.; Jackson, Dennis G.

    2014-07-08

    The process of treating elemental mercury within the soil is provided by introducing into the soil a heated vapor phase of elemental sulfur. As the vapor phase of elemental sulfur cools, sulfur is precipitated within the soil and then reacts with any elemental mercury thereby producing a reaction product that is less hazardous than elemental mercury.

  19. On Metric Ramsey-Type Phenomena Yair Bartal Nathan Linial Manor Mendel Assaf Naor

    E-Print Network [OSTI]

    Bartal, Yair

    On Metric Ramsey-Type Phenomena Yair Bartal Nathan Linial Manor Mendel Assaf Naor Abstract The main space theory or as part of Ramsey Theory in combinatorics. Given a #12;nite metric space on n points, we.2 Generic upper bounds via metric composition . . . . . . . . . . . . . . . . . . . . . . 6 3 Metric Ramsey

  20. Attrition resistant, zinc titanate-containing, reduced sulfur sorbents

    DOE Patents [OSTI]

    Vierheilig, Albert A.; Gupta, Raghubir P.; Turk, Brian S.

    2004-11-02

    The disclosure is directed to sorbent compositions for removing reduced sulfur species (e.g., H.sub.2 S, COS and CS.sub.2) a feed stream. The sorbent is formed from a multi-phase composition including a zinc titanate phase and a zinc oxide-aluminate phase. The sorbent composition is substantially free of unreacted alumina.

  1. Catalyst added to Claus furnace reduces sulfur losses

    SciTech Connect (OSTI)

    Luinstra, E.A.; d'Haene, P.E. (Shell Canada Ltd., Toronto, ON (Canada). Oakville Research Centre)

    1989-07-01

    Several substances effectively catalyze the reduction of carbon disulfide in Claus gas streams at Claus reaction furnace conditions (about 1,000{sup 0}C). Some conversion of carbonyl sulfide also occurs. Carbon disulfide and carbonyl sulfide as well-known problem compounds that reduce sulfur recovery efficiency in many sulfur recovery plants. Installation of a suitable catalytic material in the reaction furnace promises significant improvement of Claus plant efficiency, and prolonged life of the catalytic converters. Almost every Claus sulfur recovery plant makes some carbon disulfide (CS/sub 2/) and carbonyl sulfide (COS) in the reaction furnace, and in many of these plants, these compounds constitute a significant problem. CS/sub 2/ and COS often comprise more than 50% of sulfur losses in the tail gas. This article reexamines the issue of CS/sub 2/ and COS in the Claus plant. The relative importance of these two troublesome components is explored with data accumulated from Shell Canada Claus plants. The authors discuss which factors tend to produce these components. Then a method for reducing CS/sub 2/ and COS virtually at the source will be introduced.

  2. Emission of reduced malodorous sulfur gases from wastewater treatment plants

    SciTech Connect (OSTI)

    Devai, I.; DeLaune, R.D.

    1999-03-01

    The emission of malodorous gaseous compounds from wastewater collection and treatment facilities is a growing maintenance and environmental problem. Numerous gaseous compounds with low odor detection thresholds are emitted from these facilities. Sulfur-bearing gases represent compounds with the lowest odor detection threshold. Using solid adsorbent preconcentration and gas chromatographic methods, the quantity and composition of reduced malodorous sulfur gases emitted from various steps of the treatment process were determined in wastewater treatment plants in Baton Rouge, Louisiana. Hydrogen sulfide, which is a malodorous, corrosive, and potentially toxic gas, was the most dominant volatile reduced sulfur (S) compound measured. Concentrations were not only more than the odor detection threshold of hydrogen sulfide, but above levels that may affect health during long-term exposure. The concentrations of methanethiol, dimethyl sulfide, carbon disulfide, and carbonyl sulfide were significantly less than hydrogen sulfide. However, even though emissions of reduced sulfur gases other than hydrogen sulfide were low, previous studies suggested that long-term exposure to such levels may cause respiratory problems and other symptoms.

  3. Sulfur tolerant molten carbonate fuel cell anode and process

    DOE Patents [OSTI]

    Remick, Robert J. (Naperville, IL)

    1990-01-01

    Molten carbonate fuel cell anodes incorporating a sulfur tolerant carbon monoxide to hydrogen water-gas-shift catalyst provide in situ conversion of carbon monoxide to hydrogen for improved fuel cell operation using fuel gas mixtures of over about 10 volume percent carbon monoxide and up to about 10 ppm hydrogen sulfide.

  4. Auction design and the market for sulfur dioxide emissions

    E-Print Network [OSTI]

    Joskow, Paul L.

    1996-01-01

    Title IV of the Clean Air Act Amendments of 1990 created a market for electric utility emissions of sulfur dioxide (SO2). Recent papers have argued that flaws in the design of the auctions that are part of this market have ...

  5. Hydroprocessing key issue in low-sulfur' era

    SciTech Connect (OSTI)

    Not Available

    1993-07-26

    Refiners gave heavy attention to hydroprocessing operations at the most recent National Petroleum Refiners Association annual question and answer session on refining and petrochemical technology. Among the topics covered were diesel color, blending to meet diesel sulfur specs, and ammonia injection in hydrocracking units. The panelists also related their experiences with increasing vacuum gas oil conversion in hydrocracking operations. These discussions are reproduced here.

  6. Sulfur controls edge closer in acid-rain debate

    SciTech Connect (OSTI)

    Not Available

    1984-10-04

    The role of airborne sulfur emissions from midwestern and southern coal-fired power plants in exacerbating the acid rain problem is discussed. This problem is discussed from the standpoint of legislation, compliance costs, scrubber performance and cost, and chemistry of acid rains.

  7. Workshop on sulfur chemistry in flue gas desulfurization

    SciTech Connect (OSTI)

    Wallace, W.E. Jr.

    1980-05-01

    The Flue Gas Desulfurization Workshop was held at Morgantown, West Virginia, June 7-8, 1979. The presentations dealt with the chemistry of sulfur and calcium compounds in scrubbers. DOE and EPRI programs in this area are described. Ten papers have been entered individually into EDB and ERA. (LTN)

  8. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2000-12-01

    This document summarizes progress on the Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period April 1, 2000 through September 30, 2000. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid will also be determined, as will the removal of arsenic, a known poison for NOX selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), First Energy Corporation, and the Dravo Lime Company are project co-funders. URS Corporation is the prime contractor. This is the second reporting period for the subject Cooperative Agreement. During this period, the first of four short-term sorbent injection tests were conducted at the First Energy Bruce Mansfield Plant. This test determined the effectiveness of dolomite injection through out-of-service burners as a means of controlling sulfuric acid emissions from this unit. The tests showed that dolomite injection could achieve up to 95% sulfuric acid removal. Balance of plant impacts on furnace slagging and fouling, air heater fouling, ash loss-on-ignition, and the flue gas desulfurization system were also determined. These results are presented and discussed in this report.

  9. Use of metrics in an effective ALARA program

    SciTech Connect (OSTI)

    Bates, B.B. Jr. [Los Alamos National Laboratory, NM (United States)

    1996-06-01

    ALARA radiological protection programs require metrics to meet their objectives. Sources of metrics include external dosimetry; internal dosimetry; radiological occurrences from the occurrence reporting an processing system (ORPS); and radiological incident reports (RIR). The sources themselves contain an abundance of specific {open_quotes}indicators.{close_quotes} To choose the site-specific indicators that will be tracked and trended requires careful review. Justification is needed to defend the indicators selected and maybe even stronger justification is needed for those indicators that are available, but not chosen as a metric. Historically, the many different sources of information resided in a plethora of locations. Even the same type of metric had data located in different areas and could not be easily totaled for the entire Site. This required the end user to expend valuable time and effort to locate the data they needed. To address this problem, a central metrics database has been developed so that a customer can have all their questions addressed quickly and correctly. The database was developed in the beginning to answer some of the customer`s most frequently asked questions. IL is now also a tool to communicate the status of the radiation protection program to facility managers. Finally, it also addresses requirements contained in the Rad Con manual and the 10CFR835 implementation guides. The database uses currently available, {open_quotes}user friendly,{close_quotes} software and contains information from RIR`s, ORPS, and external dosimetry records specific to ALARA performance indicators. The database is expandable to allow new metrics input. Specific reports have been developed to assist customers in their tracking and trending of ALARA metrics. These include quarterly performance indicator reports, monthly radiological incident reports, monthly external dose history and goals tracking reports, and the future use of performance indexing.

  10. Sulfur removal from high-sulfur Illinois coal by low-temperature perchloroethylene (PCE) extraction. Technical report, December 1, 1991--February 29, 1992

    SciTech Connect (OSTI)

    Chou, M.I.M; Lytle, J.M.; Ruch, R.R.; Kruse, C.W.; Chaven, C.; Hackley, K.C.; Hughes, R.E.; Harvey, R.D.; Frost, J.K. [Illinois State Geological Survey, Champaign, IL (United States); Buchanan, D.H. [Eastern Illinois Univ., Charleston, IL (United States); Stucki, J.W. [Illinois Univ., Urbana, IL (United States); Huffman, G.; Huggins, F.E. [Kentucky Univ., Lexington, KY (United States)

    1992-09-01

    A pre-combustion coal desulfurization process at 120{degree}C using perchloroethylene (PCE) to remove up to 70% of the organic sulfur has been developed by the Midwest Ore Processing Co. (MWOPC). However, this process has not yet proven to be as successful with Illinois coals as it has for Ohio and Indiana coals. In addition, the high levels of organic sulfur removals observed by the MWOPC may be due to certain errors involved in the ASTM data interpretation; this needs verification. For example, elemental sulfur extracted by the PCE may be derived from pyrite oxidation during coal preoxidation, but it may be interpreted as organic sulfur removed by the PCE using ASTM analysis. The purposes of this research are to independently confirm and possibly to improve the organic sulfur removal from Illinois coals with the PCE desulfurization process reported by the MWOPC and to verify the forms-of-sulfur determination using the ASTM method for the PCE process evaluation.

  11. ENGINEERING EVALUATION OF HOT-GAS DESULFURIZATION WITH SULFUR RECOVERY

    SciTech Connect (OSTI)

    G.W. ROBERTS; J.W. PORTZER; S.C. KOZUP; S.K. GANGWAL

    1998-05-31

    Engineering evaluations and economic comparisons of two hot-gas desulfurization (HGD) processes with elemental sulfur recovery, being developed by Research Triangle Institute, are presented. In the first process, known as the Direct Sulfur Recovery Process (DSRP), the SO{sub 2} tail gas from air regeneration of zinc-based HGD sorbent is catalytically reduced to elemental sulfur with high selectivity using a small slipstream of coal gas. DSRP is a highly efficient first-generation process, promising sulfur recoveries as high as 99% in a single reaction stage. In the second process, known as the Advanced Hot Gas Process (AHGP), the zinc-based HGD sorbent is modified with iron so that the iron portion of the sorbent can be regenerated using SO{sub 2} . This is followed by air regeneration to fully regenerate the sorbent and provide the required SO{sub 2} for iron regeneration. This second-generation process uses less coal gas than DSRP. Commercial embodiments of both processes were developed. Process simulations with mass and energy balances were conducted using ASPEN Plus. Results show that AHGP is a more complex process to operate and may require more labor cost than the DSRP. Also capital costs for the AHGP are higher than those for the DSRP. However, annual operating costs for the AHGP appear to be considerably less than those for the DSRP with a potential break-even point between the two processes after just 2 years of operation for an integrated gasification combined cycle (IGCC) power plant using 3 to 5 wt% sulfur coal. Thus, despite its complexity, the potential savings with the AHGP encourage further development and scaleup of this advanced process.

  12. Biomass as Feedstock for a Bioenergy and Bioproducts Industry: The Technical Feasibility of a Billion-Ton Annual Supply, April 2005

    SciTech Connect (OSTI)

    2005-04-01

    The purpose of this report is to determine whether the land resources of the United States are capable of producing a sustainable supply of biomass sufficient to displace 30 percent or more of the country’s present petroleum consumption – the goal set by the Biomass R&D Technical Advisory Committee in their vision for biomass technologies. Accomplishing this goal would require approximately 1 billion dry tons of biomass feedstock per year.

  13. Effective use of metrics in an ALARA program

    SciTech Connect (OSTI)

    Bates, B.B. Jr.

    1996-07-01

    ALARA radiological protection programs require metrics to meet their objectives. Sources of metrics include; external dosimetry; internal dosimetry; radiological occurrences from the occurrence reporting and processing system (ORPS); and radiological incident reports (RIR). The sources themselves contain an abundance of specific ``indicators``. To choose the site-specific indicators that will be tracked and trended requires careful review. This required the end users to expend valuable time and effort to locate the data they needed. To address this problem, a central metrics database has been developed so that customers can have all their questions addressed quickly and correctly. The database was developed in the beginning to answer some of the customer`s most frequently asked questions. It is now also a tool to communicate the status of the radiation protection program to facility managers. Finally it also addresses requirements contained in the Rad Con manual and the 10CFR835 implementation guides. The database uses currently available, ``user friendly``, software and contains information from RIR`s, ORPS, and external dosimetry records specific to ALARA performance indicators. The database is expandable to allow new metrics input. Specific reports have been developed to assist customers in their tracking and trending of ALARA metrics.

  14. Metrics Evolution in an Energy Research & Development Program

    SciTech Connect (OSTI)

    Brent Dixon

    2011-08-01

    All technology programs progress through three phases: Discovery, Definition, and Deployment. The form and application of program metrics needs to evolve with each phase. During the discovery phase, the program determines what is achievable. A set of tools is needed to define program goals, to analyze credible technical options, and to ensure that the options are compatible and meet the program objectives. A metrics system that scores the potential performance of technical options is part of this system of tools, supporting screening of concepts and aiding in the overall definition of objectives. During the definition phase, the program defines what specifically is wanted. What is achievable is translated into specific systems and specific technical options are selected and optimized. A metrics system can help with the identification of options for optimization and the selection of the option for deployment. During the deployment phase, the program shows that the selected system works. Demonstration projects are established and classical systems engineering is employed. During this phase, the metrics communicate system performance. This paper discusses an approach to metrics evolution within the Department of Energy's Nuclear Fuel Cycle R&D Program, which is working to improve the sustainability of nuclear energy.

  15. The Non-Metricity Formulation of General Relativity

    E-Print Network [OSTI]

    Igor Mol

    2015-01-13

    After recalling the differential geometry of non-metric connections in the formalism of differential forms, we introduce the idea of a Non-Metricity (NM) connection, whose connection $1$--forms coincides with the non-metricity $1$--forms for a class of cobase fields. Then we formulate a theory of gravitation (equivalent to General Relativity (GR)) which admits a geometrical interpretation in a flat torsionless space where the gravitational field is completely manifest in the non-metricity of a NM connection. We define and then apply the non-metricity gauge to a gravitational Lagrangian density discovered by Wallner and which is equivalent to the Einstein-Hilbert Lagrangian density. The Einstein equations coupled to the matter currents $\\left( \\mathcal{J}_{\\alpha}\\right) $ thus becomes $\\delta dg_{\\alpha}=\\mathcal{T}_{\\alpha}+\\mathcal{J}_{\\alpha}$, where $\\left( \\mathcal{T}_{\\alpha}\\right) $ is identified as the gravitational energy-momentum currents, to which we shall find a relatively simple and physically appealing form. It is also shown that in the gravitational analogue of the Lorenz gauge, our field equations can be written as a system of Proca equations, which may be of interest in the study of propagation of gravitational-electromagnetic waves.

  16. Sulfur Based Thermochemical Heat Storage for Baseload Concentrated Solar Power Generation

    SciTech Connect (OSTI)

    wong, bunsen

    2014-11-20

    This project investigates the engineering and economic feasibility of supplying baseload power using a concentrating solar power (CSP) plant integrated with sulfur based thermochemical heat storage. The technology stores high temperature solar heat in the chemical bonds of elemental sulfur. Energy is recovered as high temperature heat upon sulfur combustion. Extensive developmental and design work associated with sulfur dioxide (SO2) disproportionation and sulfuric acid (H2SO4) decomposition chemical reactions used in this technology had been carried out in the two completed phases of this project. The feasibility and economics of the proposed concept was demonstrated and determined.

  17. Method of burning sulfur-containing fuels in a fluidized bed boiler

    DOE Patents [OSTI]

    Jones, Brian C. (Windsor, CT)

    1982-01-01

    A method of burning a sulfur-containing fuel in a fluidized bed of sulfur oxide sorbent wherein the overall utilization of sulfur oxide sorbent is increased by comminuting the bed drain solids to a smaller average particle size, preferably on the order of 50 microns, and reinjecting the comminuted bed drain solids into the bed. In comminuting the bed drain solids, particles of spent sulfur sorbent contained therein are fractured thereby exposing unreacted sorbent surface. Upon reinjecting the comminuted bed drain solids into the bed, the newly-exposed unreacted sorbent surface is available for sulfur oxide sorption, thereby increasing overall sorbent utilization.

  18. Advanced byproduct recovery: Direct catalytic reduction of sulfur dioxide to elemental sulfur. Quarterly report, April 1--June 30, 1997

    SciTech Connect (OSTI)

    NONE

    1997-12-31

    The team of Arthur D. Little, Tufts University and Engelhard Corporation are conducting Phase 1 of a four and a half year, two-phase effort to develop and scale-up an advanced byproduct recovery technology that is a direct, single-stage, catalytic process for converting sulfur dioxide to elemental sulfur. This catalytic process reduces SO{sub 2} over a fluorite-type oxide (such as ceria and zirconia). The catalytic activity can be significantly promoted by active transition metals, such as copper. More than 95% elemental sulfur yield, corresponding to almost complete sulfur dioxide conversion, was obtained over a Cu-Ce-O oxide catalyst as part of an on-going DOE-sponsored, University Coal Research Program. This type of mixed metal oxide catalyst has stable activity, high selectivity for sulfur production, and is resistant to water and carbon dioxide poisoning. Tests with CO and CH{sub 4} reducing gases indicate that the catalyst has the potential for flexibility with regard to the composition of the reducing gas, making it attractive for utility use. The performance of the catalyst is consistently good over a range of SO{sub 2} inlet concentration (0.1 to 10%) indicating its flexibility in treating SO{sub 2} tail gases as well as high concentration streams. The principal objective of the Phase 1 program is to identify and evaluate the performance of a catalyst which is robust and flexible with regard to choice of reducing gas. In order to achieve this goal, the authors have planned a structured program including: Market/process/cost/evaluation; Lab-scale catalyst preparation/optimization studies; Lab-scale, bulk/supported catalyst kinetic studies; Bench-scale catalyst/process studies; and Utility review. Progress is reported from all three organizations.

  19. Conformal Transformations in Metric-Affine Gravity and Ghosts

    E-Print Network [OSTI]

    Karahan, Canan N; Demir, Durmus A

    2012-01-01

    Conformal transformations play a widespread role in gravity theories in regard to their cosmological and other implications. In the pure metric theory of gravity, conformal transformations change the frame to a new one wherein one obtains a conformal-invariant scalar-tensor theory such that the scalar field, deriving from the conformal factor, is a ghost. In this work, conformal transformations and ghosts will be analyzed in the framework of the metric-affine theory of gravity. Within this framework, metric and connection are independent variables, and hence, transform independently under conformal transformations. It will be shown that, if affine connection is invariant under conformal transformations then the scalar field under concern is a non-ghost, non-dynamical field. It is an auxiliary field at the classical level, and might develop a kinetic term at the quantum level. Alternatively, if connection transforms additively with a structure similar to yet more general than that of the Levi-Civita connection...

  20. Metrics for Evaluating the Accuracy of Solar Power Forecasting: Preprint

    SciTech Connect (OSTI)

    Zhang, J.; Hodge, B. M.; Florita, A.; Lu, S.; Hamann, H. F.; Banunarayanan, V.

    2013-10-01

    Forecasting solar energy generation is a challenging task due to the variety of solar power systems and weather regimes encountered. Forecast inaccuracies can result in substantial economic losses and power system reliability issues. This paper presents a suite of generally applicable and value-based metrics for solar forecasting for a comprehensive set of scenarios (i.e., different time horizons, geographic locations, applications, etc.). In addition, a comprehensive framework is developed to analyze the sensitivity of the proposed metrics to three types of solar forecasting improvements using a design of experiments methodology, in conjunction with response surface and sensitivity analysis methods. The results show that the developed metrics can efficiently evaluate the quality of solar forecasts, and assess the economic and reliability impact of improved solar forecasting.

  1. Tidal deformation of a slowly rotating material body. External metric

    E-Print Network [OSTI]

    Philippe Landry; Eric Poisson

    2015-07-31

    We construct the external metric of a slowly rotating, tidally deformed material body in general relativity. The tidal forces acting on the body are assumed to be weak and to vary slowly with time, and the metric is obtained as a perturbation of a background metric that describes the external geometry of an isolated, slowly rotating body. The tidal environment is generic and characterized by two symmetric-tracefree tidal moments E_{ab} and B_{ab}, and the body is characterized by its mass M, its radius R, and a dimensionless angular-momentum vector \\chi^a new quantities, which we designate as rotational-tidal Love numbers. All these Love numbers are gauge invariant in the usual sense of perturbation theory, and all vanish when the body is a black hole.

  2. An Automated Evaluation Metric for Chinese Text Entry

    E-Print Network [OSTI]

    Jiang, Mike Tian-Jian; Lin, Jaimie; Lin, Jerry; Hsu, Wen-Lien

    2007-01-01

    In this paper, we propose an automated evaluation metric for text entry. We also consider possible improvements to existing text entry evaluation metrics, such as the minimum string distance error rate, keystrokes per character, cost per correction, and a unified approach proposed by MacKenzie, so they can accommodate the special characteristics of Chinese text. Current methods lack an integrated concern about both typing speed and accuracy for Chinese text entry evaluation. Our goal is to remove the bias that arises due to human factors. First, we propose a new metric, called the correction penalty (P), based on Fitts' law and Hick's law. Next, we transform it into the approximate amortized cost (AAC) of information theory. An analysis of the AAC of Chinese text input methods with different context lengths is also presented.

  3. Integrated Process Configuration for High-Temperature Sulfur Mitigation during Biomass Conversion via Indirect Gasification

    SciTech Connect (OSTI)

    Dutta. A.; Cheah, S.; Bain, R.; Feik, C.; Magrini-Bair, K.; Phillips, S.

    2012-06-20

    Sulfur present in biomass often causes catalyst deactivation during downstream operations after gasification. Early removal of sulfur from the syngas stream post-gasification is possible via process rearrangements and can be beneficial for maintaining a low-sulfur environment for all downstream operations. High-temperature sulfur sorbents have superior performance and capacity under drier syngas conditions. The reconfigured process discussed in this paper is comprised of indirect biomass gasification using dry recycled gas from downstream operations, which produces a drier syngas stream and, consequently, more-efficient sulfur removal at high temperatures using regenerable sorbents. A combination of experimental results from NREL's fluidizable Ni-based reforming catalyst, fluidizable Mn-based sulfur sorbent, and process modeling information show that using a coupled process of dry gasification with high-temperature sulfur removal can improve the performance of Ni-based reforming catalysts significantly.

  4. Primer Control System Cyber Security Framework and Technical Metrics

    SciTech Connect (OSTI)

    Wayne F. Boyer; Miles A. McQueen

    2008-05-01

    The Department of Homeland Security National Cyber Security Division supported development of a control system cyber security framework and a set of technical metrics to aid owner-operators in tracking control systems security. The framework defines seven relevant cyber security dimensions and provides the foundation for thinking about control system security. Based on the developed security framework, a set of ten technical metrics are recommended that allow control systems owner-operators to track improvements or degradations in their individual control systems security posture.

  5. Calabi-Yau metrics for quotients and complete intersections

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Braun, Volker; Brelidze, Tamaz; Douglas, Michael R.; Ovrut, Burt A.

    2008-05-22

    We extend previous computations of Calabi-Yau metrics on projective hypersurfaces to free quotients, complete intersections, and free quotients of complete intersections. In particular, we construct these metrics on generic quintics, four-generation quotients of the quintic, Schoen Calabi-Yau complete intersections and the quotient of a Schoen manifold with Z? x Z? fundamental group that was previously used to construct a heterotic standard model. Various numerical investigations into the dependence of Donaldson's algorithm on the integration scheme, as well as on the Kähler and complex structure moduli, are also performed.

  6. Method of making sulfur-resistant composite metal membranes

    DOE Patents [OSTI]

    Way, J. Douglas (Boulder, CO) [Boulder, CO; Lusk, Mark (Golden, CO) [Golden, CO; Thoen, Paul (Littleton, CO) [Littleton, CO

    2012-01-24

    The invention provides thin, hydrogen-permeable, sulfur-resistant membranes formed from palladium or palladium-alloy coatings on porous, ceramic or metal supports. Also disclosed are methods of making these membranes via sequential electroless plating techniques, wherein the method of making the membrane includes decomposing any organic ligands present on the substrate, reducing the palladium crystallites on the substrate to reduced palladium crystallites, depositing a film of palladium metal on the substrate and then depositing a second, gold film on the palladium film. These two metal films are then annealed at a temperature between about 200.degree. C. and about 1200.degree. C. to form a sulfur-resistant, composite PdAu alloy membrane.

  7. Modeling sulfur dioxide capture in a pulverized coal combustor

    SciTech Connect (OSTI)

    Nair, R.B.; Yavuzkurt, S. [Pennsylvania State Univ., University Park, PA (United States)

    1997-04-01

    The formation and capture of sulfur dioxide in a pulverized coal combustor is investigated. A two-dimensional, steady, axisymmetric code, PCGC-2 (Pulverized Coal Gasification and Combustion-two Dimensional), originally developed at Brigham Young University, has been used to simulate combustion of the pulverized coal. This paper represents part of a project to investigate simultaneously enhancing sulfur capture and particulate agglomeration in combustor effluents. Results from the code have been compared to experimental data obtained from MTCI`s (Manufacturing Technology and Conversion International) test pulse combustor, which generates sound pressure levels of {approximately}180 dB. The overall goal behind the pulse combustor program at MTCI is to develop combustors for stationary gas turbines that use relatively inexpensive coal-based fuels. This study attempts to model the capture of sulfur dioxide when injected into a pulse combustor firing micronized coal. While this work does not presume to model the complex gas flow-field generated by the pulsating flow, the effects of the acoustic field are expressed by increased heat and mass transfer to the particles (coal/sorbent) in question. A comprehensive calcination-sintering-sulfation model for single particles was used to model the capture of sulfur dioxide by limestone sorbent. Processes controlling sulfation are external heat and mass transfer, pore diffusion, diffusion through the product layer of CaSO{sub 4}, sintering, and calcination. The model was incorporated into the PCGC-2 program. Comparisons of exit concentrations of SO{sub 2} showed a fairly good agreement (within {approximately}10 percent) with the experimental results from MTCI.

  8. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2000-12-01

    A test program is being sponsored by the US Department of Energy (DOE), EPRI, FirstEnergy, and TVA to investigate furnace injection of alkaline sorbents as a means of reducing sulfuric acid concentrations in the flue gas from coal-fired boilers. This test program is being conducted at the FirstEnergy Bruce Mansfield Plant (BMP), although later testing will be conducted at a TVA plant. A sorbent injection test was conducted the week of April 18, 2000. The test was the first of several short-term (one- to two-week duration) tests to investigate the effectiveness of various alkaline sorbents for sulfuric acid control and the effects of these sorbents on boiler equipment performance. This first short-term test investigated the effect of injecting dry dolomite powder (CaCO{sub 3} {center_dot} MgCO{sub 3}), a mineral similar to limestone, into the furnace of Unit 2. During the test program, various analytical techniques were used to assess the effects of sorbent injection. These primarily included sampling with the controlled condensation system (CCS) for determining flue gas SO{sub 3} content and an acid dew-point (ADP) meter for determining the sulfuric acid dew point (and, indirectly, the concentration of sulfuric acid) of the flue gas. EPA Reference Method 26a was used for determining hydrochloric acid (HCl) and hydrofluoric acid (HF), as well and chlorine (Cl{sub 2}) and fluorine (F{sub 2}) concentrations in the flue gas. Fly ash resistivity was measured using a Southern Research Institute (SRI) point-to-plane resistivity probe, and unburned carbon in fly ash was determined by loss on ignition (LOI). Coal samples were also collected and analyzed for a variety of parameters. Finally, visual observations were made of boiler furnace and convective pass surfaces prior to and during sorbent injection.

  9. Glass surface deactivants for sulfur-containing gases

    SciTech Connect (OSTI)

    Farwell, S.O.; Gluck, S.J.

    1980-10-01

    In gas chromatographic technique for measuring reduced sulfur-containing gases in biogenic air fluxes, the major problem seemed to be the irreversible adsorption of the polar sulfur compounds on the glass surfaces of the cryogenic sampling traps. This article discusses the comparative degrees of Pyrex glass surface passivation for over 25 chemical deactivants and their related pretreatment procedures. Since H/sub 2/S was discovered to be the sulfur compound with a consistently lower recovery efficiency than COS, CH/sub 3/SH, CH/sub 3/SCH, CS/sub 2/ or CH/sub 3/SSCH/sub 3/, the percent recovery for H/sub 2/S was employed as the indicator of effectiveness for the various deactivation treatments. Tables are presented summarizing the mean H/sub 2/S recoveries for chlorosilane deactivants and for the mean H/sub 2/S recoveries for different pyrex surface pretreatments with an octadecyltrialkoxysilane deactivation. The general conclusion of this investigation is that the relative degree of passivation for glass surfaces by present deactivation techniques is dependent on the types of analyzed compounds and the nature of the glass surface.

  10. Sibley station low-sulfur coal conversion program

    SciTech Connect (OSTI)

    Rupinskas, R.L. [Sargent & Lundy LLC, Chicago, IL (United States); Rembold, D.F. [Missouri Public Service, Kansas City, MO (United States)

    1995-03-01

    After embarking on an upgrade project in 1986 that was designed to allow efficient and reliable operation of its coal-fired Sibley station through 2010, Missouri Public Service (MPS) faced the uncertainty of impending acid-rain legislation. To protect its investment in the Sibley Rebuild Program, the utility evaluated compliance options based on the emerging legislation and concluded that switching to low-sulfur coal offered the least-cost compliance approach. Compared to installing a scrubber, switching to a low-sulfur coal was also more straightforward, although not without challenges and complications. This paper reviews the Sibley low-sulfur coal conversion program. At Sibley, fuel switching was chosen only after numerous internal and external studies; it withstood late challenges from natural gas and allowance trading. Switching demanded additional equipment to blend Power River Basin coals and other coals, and demanded additional and upgraded protective equipment in the areas of fire protection, dust collection, and explosion prevention. In the year since the coal conversion project was completed the facility has operated reliably, the economic benefits of the lower cost Powder River Basin coals have been realized, and the station has also met the requirements of both phases of the acid rain legislation. Fuel switching at Sibley required a team approach and careful analysis. The coal conversion project also required attention and dedication by team members in order to minimize fuel costs while maintaining optimum plant efficiency and availability.

  11. Removal of nitrogen and sulfur from oil-shale

    SciTech Connect (OSTI)

    Olmstead, W.N.

    1986-01-28

    This patent describes a process for enhancing the removal of nitrogen and sulfur from oil-shale. The process consists of: (a) contacting the oil-shale with a sufficient amount of an aqueous base solution comprised of at least a stoichiometric amount of one or more alkali metal or alkaline-earth metal hydroxides based on the total amount of nitrogen and sulfur present in the oil-shale. Also necessary is an amount sufficient to form a two-phase liquid, solid system, a temperature from about 50/sup 0/C to about 350/sup 0/C., and pressures sufficient to maintain the solution in liquid form; (b) separating the effluents from the treated oil-shale, wherein the resulting liquid effluent contains nitrogen moieties and sulfur moieties from the oil-shale and any resulting gaseous effluent contains nitrogen moieties from the oil-shale, and (c) converting organic material of the treated oil-shale to shale-oil at a temperature from about 450/sup 0/C to about 550/sup 0/C.

  12. How to Obtain Reproducible Results for Lithium Sulfur Batteries

    SciTech Connect (OSTI)

    Zheng, Jianming; Lu, Dongping; Gu, Meng; Wang, Chong M.; Zhang, Jiguang; Liu, Jun; Xiao, Jie

    2013-01-01

    The basic requirements for getting reliable Li-S battery data have been discussed in this work. Unlike Li-ion batteries, electrolyte-rich environment significantly affects the cycling stability of Li-S batteries prepared and tested under the same conditions. The reason has been assigned to the different concentrations of polysulfide-containing electrolytes in the cells, which have profound influences on both sulfur cathode and lithium anode. At optimized S/E ratio of 50 g L-1, a good balance among electrolyte viscosity, wetting ability, diffusion rate dissolved polysulfide and nucleation/growth of short-chain Li2S/Li2S2 has been built along with largely reduced contamination on the lithium anode side. Accordingly, good cyclability, high reversible capacity and Coulombic efficiency are achieved in Li-S cell with controlled S/E ratio without any additive. Other factors such as sulfur content in the composite and sulfur loading on the electrode also need careful concern in Li-S system in order to generate reproducible results and gauge the various methods used to improve Li-S battery technology.

  13. Process for recovery of sulfur from acid gases

    DOE Patents [OSTI]

    Towler, Gavin P. (Kirkbymoorside, GB2); Lynn, Scott (Pleasant Hill, CA)

    1995-01-01

    Elemental sulfur is recovered from the H.sub.2 S present in gases derived from fossil fuels by heating the H.sub.2 S with CO.sub.2 in a high-temperature reactor in the presence of a catalyst selected as one which enhances the thermal dissociation of H.sub.2 S to H.sub.2 and S.sub.2. The equilibrium of the thermal decomposition of H.sub.2 S is shifted by the equilibration of the water-gas-shift reaction so as to favor elemental sulfur formation. The primary products of the overall reaction are S.sub.2, CO, H.sub.2 and H.sub.2 O. Small amounts of COS, SO.sub.2 and CS.sub.2 may also form. Rapid quenching of the reaction mixture results in a substantial increase in the efficiency of the conversion of H.sub.2 S to elemental sulfur. Plant economy is further advanced by treating the product gases to remove byproduct carbonyl sulfide by hydrolysis, which converts the COS back to CO.sub.2 and H.sub.2 S. Unreacted CO.sub.2 and H.sub.2 S are removed from the product gas and recycled to the reactor, leaving a gas consisting chiefly of H.sub.2 and CO, which has value either as a fuel or as a chemical feedstock and recovers the hydrogen value from the H.sub.2 S.

  14. Lithium-Sulfur Batteries: from Liquid to Solid Cells?

    SciTech Connect (OSTI)

    Lin, Zhan [ORNL; Liang, Chengdu [ORNL

    2015-01-01

    Lithium-sulfur (Li-S) batteries supply a theoretical specific energy 5 times higher than that of lithium-ion batteries (2,500 vs. ~500 Wh kg-1). However, the insulating properties and polysulfide shuttle effects of the sulfur cathode and the safety concerns of the lithium anode in liquid electrolytes are still key limitations to practical use of traditional Li-S batteries. In this review, we start with a brief discussion on fundamentals of Li-S batteries and key challenges associated with the conventional liquid cells. Then, we introduce the most recent progresses in the liquid systems, including the sulfur positive electrodes, the lithium negative electrodes, and the electrolytes and binders. We discuss the significance of investigating electrode reaction mechanisms in liquid cells using in-situ techniques to monitor the compositional and morphological changes. By moving from the traditional liquid cells to recent solid cells, we discuss the importance of this game-changing shift with positive advances in both solid electrolytes and electrode materials. Finally, the opportunities and perspectives for future research on Li-S batteries are presented.

  15. A Comprehensive and Comparative Metric for Information Security

    E-Print Network [OSTI]

    Breu, Ruth

    A Comprehensive and Comparative Metric for Information Security Steffen Weiß1 , Oliver Weissmann2 security GmbH, Germany Abstract Measurement of information security is important for organizations , Falko Dressler1* 1 Dept. of Computer Science 7, University of Erlangen, Germany 2 atsec information

  16. Harmonic maps on domains with piecewise Lipschitz continuous metrics

    E-Print Network [OSTI]

    Wang, Changyou

    Harmonic maps on domains with piecewise Lipschitz continuous metrics Haigang Li , Changyou Wang consider harmonic map from (, g) to a compact Rie- mannian manifold (N, h) Rk without boundary. We generalize the notion of stationary harmonic maps and prove their partial regularity. We also discuss

  17. Linear harmonic oscillator in spaces with degenerate metrics

    E-Print Network [OSTI]

    N. A. Gromov

    2006-03-02

    With the help of contraction method we study the harmonic oscillator in spaces with degenerate metrics, namely, on Galilei plane and in the flat 3D Cayley-Klein spaces $R_3(j_2,j_3).$ It is shown that the inner degrees of freedom are appeared which physical dimensions are different from the dimension of the space.

  18. Quantitative Metrics of Social Response for Autism Diagnosis*

    E-Print Network [OSTI]

    Scassellati, Brian

    Quantitative Metrics of Social Response for Autism Diagnosis* Brian Scassellati Department and treatment of autism, a pervasive developmental disorder which results in selective impairment of social to address critical problems in diagnosing autism. We provide preliminary data and observations on how

  19. EERE Portfolio: Primary Benefits Metrics for FY09

    SciTech Connect (OSTI)

    [EERE

    2011-11-17

    This collection of data tables shows the benefits metrics related to energy security, environmental impacts, and economic impacts for both the entire EERE portfolio of renewable energy technologies as well as the individual technologies. Data are presented for the years 2015, 2020, 2030, and 2050, for both the NEMS and MARKAL models.

  20. MESUR: USAGE-BASED METRICS OF SCHOLARLY IMPACT

    SciTech Connect (OSTI)

    BOLLEN, JOHAN [Los Alamos National Laboratory; RODRIGUEZ, MARKO A. [Los Alamos National Laboratory; VAN DE SOMPEL, HERBERT [Los Alamos National Laboratory

    2007-01-30

    The evaluation of scholarly communication items is now largely a matter of expert opinion or metrics derived from citation data. Both approaches can fail to take into account the myriad of factors that shape scholarly impact. Usage data has emerged as a promising complement to existing methods o fassessment but the formal groundwork to reliably and validly apply usage-based metrics of schlolarly impact is lacking. The Andrew W. Mellon Foundation funded MESUR project constitutes a systematic effort to define, validate and cross-validate a range of usage-based metrics of schlolarly impact by creating a semantic model of the scholarly communication process. The constructed model will serve as the basis of a creating a large-scale semantic network that seamlessly relates citation, bibliographic and usage data from a variety of sources. A subsequent program that uses the established semantic network as a reference data set will determine the characteristics and semantics of a variety of usage-based metrics of schlolarly impact. This paper outlines the architecture and methodology adopted by the MESUR project and its future direction.

  1. Structured Testing: A Testing Methodology Using the Cyclomatic Complexity Metric

    E-Print Network [OSTI]

    Riabov, Vladimir V.

    The purpose of this document is to describe the structured testing methodology for software testing, also uses the control flow structure of software to establish path cover- age criteria. The resultant testCabe, object oriented, software development, software diagnostic, software metrics, software testing

  2. Thermodynamics and the naked singularity in the Gamma-metric

    E-Print Network [OSTI]

    K. Lochan; D. Malafarina; T. P. Singh

    2010-09-23

    We investigate a possible way of establishing a parallel between the third law of black hole mechanics, and the strong version of the third law of thermodynamics. We calculate the surface gravity and area for a naked singular null surface in the Gamma-metric and explain in what sense this behaviour violates thermodynamics.

  3. A Case Study in Developing Process Unit Energy Metrics 

    E-Print Network [OSTI]

    Davis, J. L.; Van Atta, B.

    2006-01-01

    At the 2005 IETC Conference, KBC (Davis and Knight) submitted a paper on Integrating Process Unit Energy Metrics into a Plant Energy Managemenet System. For the 2006 conference, KBC wishes to submit a paper that details an actual case study where...

  4. Metrics-driven development of an autonomous indoor

    E-Print Network [OSTI]

    Differential drive Ground-truth camera Sonars and IR Pan-tilt unit IMU Platform: depth-only perception #12 Obstacle avoidance Lag estimator Drive controller Differential drive Horizontal scan Path tracking in large environments #12;Key metric of autonomy: mean time to failure #12;10 Atrium Lounge Hallway

  5. New set of metrics for the computational performance

    E-Print Network [OSTI]

    New set of metrics for the computational performance of IS-ENES Earth System Models TR/CMGC/14/73 U performance of Earth System Models is developed and used for an initial performance analysis of the EC models.................................................................................................................................5 2.1 List of Participating Earth System Models

  6. Kerr-NUT-AdS metrics and string theory 

    E-Print Network [OSTI]

    Chen, Wei

    2009-05-15

    With the advent of supergravity and superstring theory, it is of great importance to study higher-dimensional solutions to the Einstein equations. In this dissertation, we study the higher dimensional Kerr-AdS metrics, and show how they admit...

  7. Dynamic Adaptive Search Based Software Engineering Needs Fast Approximate Metrics

    E-Print Network [OSTI]

    Harman, Mark

    1 Dynamic Adaptive Search Based Software Engineering Needs Fast Approximate Metrics Mark Harman. University College Dublin, Ireland. Abstract--Search Based Software Engineering (SBSE) uses fitness functions to guide an automated search for solutions to challenging software engineering problems. The fitness

  8. Calculation and Optimization of Thresholds for Sets of Software Metrics

    E-Print Network [OSTI]

    Grabowski, Jens

    ,grabowski,waack}@cs.uni-goettingen.de Abstract. Many software quality models use software metrics to determine qual- ity attributes of software/IEC, 2005). To up- hold the required standard of quality, the assessment and assurance of software quality characteristics are an import part of the execution of software projects. In many models to assess the quality

  9. Using Software Metrics Tools for Maintenance Decisions: A Classroom Exercise

    E-Print Network [OSTI]

    Katchabaw, Michael James

    identify modules with low software quality; renovating those modules would be a step toward improving (Bauer) taught a senior under­ graduate course entitled ``Software Processes, Measure­ ments and Quality''. The course concentrated on the use of software metrics to evaluate software quality. We decided to use

  10. Metrics and Smoothing of TranslationInvariant Radon

    E-Print Network [OSTI]

    Greenblatt, Michael

    Metrics and Smoothing of Translation­Invariant Radon Transforms Along Curves Michael Greenblatt 1: (617) 253­4358 Running head: Radon Transforms 1 This research was supported in part by NSF grant DMS­invariant Radon transforms along curves for # # # and p

  11. An effective theory of metrics with maximal acceleration

    E-Print Network [OSTI]

    Ricardo Gallego Torromé

    2015-10-15

    A geometric theory for spacetimes whose world lines associated with physical particles have an upper bound for the proper acceleration is developed. After some fundamental remarks on the requirements that the classical dynamics for point particles should hold, the notion of generalized metric and a theory of maximal proper acceleration are introduced. A perturbative approach to metrics of maximal proper acceleration is discussed and we show how it provides a consistent theory where the associated Lorentzian metric corresponds to the limit when the maximal proper acceleration goes to infinity. Then several of the physical and kinematical properties of the maximal acceleration metric are investigated, including a discussion of the rudiments of the causal theory and the introduction of the notions of radar distance and celerity function. We discuss the corresponding modification of the Einstein mass-energy relation when the associated Lorentzian geometry is flat. In such context it is also proved that the physical dispersion relation is relativistic. Two possible physical scenarios where the modified mass-energy relation could be confronted against experiment are briefly discussed.

  12. Mining Simulation Metrics for Failure Triage in Regression Testing

    E-Print Network [OSTI]

    Veneris, Andreas

    are grouped by applying data-mining clustering algorithms. Fi- nally, the generated failure clustersMining Simulation Metrics for Failure Triage in Regression Testing Zissis Poulos1 , Andreas Veneris of failures can be exposed. These failures need to be properly grouped and distributed among engineers

  13. Methods, Metrics and Motivation for a Green Computer Science Program

    E-Print Network [OSTI]

    Way, Thomas

    and, more recently, economically sensible [13]. "Going Green" implies reducing your energy useMethods, Metrics and Motivation for a Green Computer Science Program Mujtaba Talebi and Thomas Way are uniquely positioned to promote greater awareness of Green Computing, using the academic setting

  14. Metrics and Benchmarks for Energy Efficiency in Laboratories

    SciTech Connect (OSTI)

    Mathew, Paul

    2007-10-26

    A wide spectrum of laboratory owners, ranging from universities to federal agencies, have explicit goals for energy efficiency in their facilities. For example, the Energy Policy Act of 2005 (EPACT 2005) requires all new federal buildings to exceed ASHRAE 90.1-2004 1 by at least 30 percent. The University of California Regents Policy requires all new construction to exceed California Title 24 2 by at least 20 percent. A new laboratory is much more likely to meet energy efficiency goals if quantitative metrics and targets are explicitly specified in programming documents and tracked during the course of the delivery process. If efficiency targets are not explicitly and properly defined, any additional capital costs or design time associated with attaining higher efficiencies can be difficult to justify. The purpose of this guide is to provide guidance on how to specify and compute energy efficiency metrics and benchmarks for laboratories, at the whole building as well as the system level. The information in this guide can be used to incorporate quantitative metrics and targets into the programming of new laboratory facilities. Many of these metrics can also be applied to evaluate existing facilities. For information on strategies and technologies to achieve energy efficiency, the reader is referred to Labs21 resources, including technology best practice guides, case studies, and the design guide (available at www.labs21century.gov/toolkit).

  15. Metric Attractors for Smooth Unimodal Maps Jacek Graczyk

    E-Print Network [OSTI]

    Sands, Duncan

    Metric Attractors for Smooth Unimodal Maps Jacek Graczyk #3; Dept. of Math. University of Paris XI 91405 Orsay Cedex France Duncan Sands CNRS, Dept. of Math. University of Paris XI 91405 Orsay Cedex attractor for some dynamics if the basin of attraction B(A) := fx : !(x) #26; Ag of A has positive Lebesgue

  16. Urgent need for a common metric to make precipitation

    E-Print Network [OSTI]

    Dukes, Jeffrey

    Letters Urgent need for a common metric to make precipitation manipulation experiments comparable of altered precipitation patterns, by contrast, have received far less atten- tion. The results of precipitation manipulation experiments were only recently synthesized for the first time (Wu et al., 2011

  17. Einstein static Universe in hybrid metric-Palatini gravity

    E-Print Network [OSTI]

    Christian G. Boehmer; Francisco S. N. Lobo; Nicola Tamanini

    2015-02-18

    Hybrid metric-Palatini gravity is a recent and novel approach to modified theories of gravity, which consists of adding to the metric Einstein-Hilbert Lagrangian an f(R) term constructed a la Palatini. It was shown that the theory passes local tests even if the scalar field is very light, and thus implies the existence of a long-range scalar field, which is able to modify the dynamics in galactic and cosmological scales, but leaves the Solar System unaffected. In this work, motivated by the possibility that the Universe may have started out in an asymptotically Einstein static state in the inflationary universe context, we analyse the stability of the Einstein static Universe by considering linear homogeneous perturbations in the respective dynamically equivalent scalar-tensor representation of hybrid metric-Palatini gravity. Considering linear homogeneous perturbations, the stability regions of the Einstein static universe are parametrized by the first and second derivatives of the scalar potential, and it is explicitly shown that a large class of stable solutions exists in the respective parameter space, in the context of hybrid metric-Palatini gravity.

  18. RECENT ADVANCES IN THE DEVELOPMENT OF THE HYBRID SULFUR PROCESS FOR HYDROGEN PRODUCTION

    SciTech Connect (OSTI)

    Hobbs, D.

    2010-07-22

    Thermochemical processes are being developed to provide global-scale quantities of hydrogen. A variant on sulfur-based thermochemical cycles is the Hybrid Sulfur (HyS) Process, which uses a sulfur dioxide depolarized electrolyzer (SDE) to produce the hydrogen. In the HyS Process, sulfur dioxide is oxidized in the presence of water at the electrolyzer anode to produce sulfuric acid and protons. The protons are transported through a cation-exchange membrane electrolyte to the cathode and are reduced to form hydrogen. In the second stage of the process, the sulfuric acid by-product from the electrolyzer is thermally decomposed at high temperature to produce sulfur dioxide and oxygen. The two gases are separated and the sulfur dioxide recycled to the electrolyzer for oxidation. The Savannah River National Laboratory (SRNL) has been exploring a fuel-cell design concept for the SDE using an anolyte feed comprised of concentrated sulfuric acid saturated with sulfur dioxide. The advantages of this design concept include high electrochemical efficiency and small footprint compared to a parallel-plate electrolyzer design. This paper will provide a summary of recent advances in the development of the SDE for the HyS process.

  19. Natural sulfur flux from the Gulf of Mexico: dimethyl sulfide, carbonyl sulfide, and sulfur dioxide. Technical report

    SciTech Connect (OSTI)

    Van Valin, C.C.; Luria, M.; Wellman, D.L.; Gunter, R.L.; Pueschel, R.F.

    1987-06-01

    Atmospheric measurements of natural sulfur compounds were performed over the northern Gulf of Mexico during the late summer months of 1984. Air samples were collected with an instrumented aircraft at elevations of 30-3500 m, during both day and night. Most air samples were representative of the clean maritime atmosphere, although some were from continental contaminated air during periods of offshore flow at the coastline. In all samples, carbonyl sulfide concentrations were within the range of 400-500 pptv. Conversely, the dimethyl sulfide concentrations showed significant variability: during clean atmospheric conditions the average of all measurements was 27 pptv, whereas under polluted conditions the average was 7 pptv. Measureable quantities of dimethyl sulfide (>5 pptv) were not observed above the boundary layer. The average sulfur dioxide concentration measured in the marine (clean) atmosphere was 215 pptv, which is consistent with the oxidation of dimethyl sulfide being its major source.

  20. Quantitative Chromatographic Determination of Dissolved Elemental Sulfur in the Non-aqueous Electrolyte for Lithium-Sulfur Batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Dong; Yang, Xiao-Qing; Zhang, Xuran; Li, Chao; McKinnon, Meaghan E.; Sadok, Rachel G.; Qu, Deyu; Yu, Xiqian; Lee, Hung-Sui; Qu, Deyang

    2014-12-02

    A fast and reliable analytical method is reported for the quantitative determination of dissolved elemental sulfur in non-aqueous electrolytes for Li-S batteries. By using high performance liquid chromatography with a UV detector, the solubility of S in 12 different pure solvents and in 22 different electrolytes was determined. It was found that the solubility of elemental sulfur is dependent on the Lewis basicity, the polarity of solvents and the salt concentration in the electrolytes. In addition, the S content in the electrolyte recovered from a discharged Li-S battery was successfully determined by the proposed HPLC/UV method. Thus, the feasibility ofmore »the method to the online analysis for a Li-S battery is demonstrated. Interestingly, the S was found super-saturated in the electrolyte recovered from a discharged Li-S cell.« less

  1. Quantitative Chromatographic Determination of Dissolved Elemental Sulfur in the Non-aqueous Electrolyte for Lithium-Sulfur Batteries

    SciTech Connect (OSTI)

    Zheng, Dong [Univ. of Massachusetts, Boston, MA (United States). Dept. of Chemistry; Yang, Xiao-Qing [Brookhaven National Laboratory (BNL), Upton, NY (United States). Chemistry Dept.; Zhang, Xuran [Wuhan Univ. of Technology, Hubei (China); Dept. of Chemistry; Li, Chao [Univ. of Massachusetts, Boston, MA (United States). Dept. of Chemistry; McKinnon, Meaghan E. [Univ. of Massachusetts, Boston, MA (United States). Dept. of Chemistry; Sadok, Rachel G. [Univ. of Massachusetts, Boston, MA (United States). Dept. of Chemistry; Qu, Deyu [Wuhan Univ. of Technology, Hubei (China); Dept. of Chemistry; Yu, Xiqian [Brookhaven National Laboratory (BNL), Upton, NY (United States). Chemistry Dept.; Lee, Hung-Sui [Brookhaven National Laboratory (BNL), Upton, NY (United States). Chemistry Dept.; Qu, Deyang [Univ. of Massachusetts, Boston, MA (United States). Dept. of Chemistry

    2014-11-01

    A fast and reliable analytical method is reported for the quantitative determination of dissolved elemental sulfur in non-aqueous electrolytes for Li-S batteries. By using high performance liquid chromatography with a UV detector, the solubility of S in 12 different pure solvents and in 22 different electrolytes was determined. It was found that the solubility of elemental sulfur is dependent on the Lewis basicity, the polarity of solvents and the salt concentration in the electrolytes. In addition, the S content in the electrolyte recovered from a discharged Li-S battery was successfully determined by the proposed HPLC/UV method. Thus, the feasibility of the method to the online analysis for a Li-S battery is demonstrated. Interestingly, the S was found super-saturated in the electrolyte recovered from a discharged Li-S cell.

  2. Quantitative Chromatographic Determination of Dissolved Elemental Sulfur in the Non-aqueous Electrolyte for Lithium-Sulfur Batteries

    SciTech Connect (OSTI)

    Zheng, Dong; Yang, Xiao-Qing; Zhang, Xuran; Li, Chao; McKinnon, Meaghan E.; Sadok, Rachel G.; Qu, Deyu; Yu, Xiqian; Lee, Hung-Sui; Qu, Deyang

    2014-12-02

    A fast and reliable analytical method is reported for the quantitative determination of dissolved elemental sulfur in non-aqueous electrolytes for Li-S batteries. By using high performance liquid chromatography with a UV detector, the solubility of S in 12 different pure solvents and in 22 different electrolytes was determined. It was found that the solubility of elemental sulfur is dependent on the Lewis basicity, the polarity of solvents and the salt concentration in the electrolytes. In addition, the S content in the electrolyte recovered from a discharged Li-S battery was successfully determined by the proposed HPLC/UV method. Thus, the feasibility of the method to the online analysis for a Li-S battery is demonstrated. Interestingly, the S was found super-saturated in the electrolyte recovered from a discharged Li-S cell.

  3. Advanced product recovery: Direct catalytic reduction of sulfur dioxide to elemental sulfur. Third quarterly technical progress report

    SciTech Connect (OSTI)

    NONE

    1996-07-01

    More than 170 wet scrubber systems applied to 72,000 MW of US, coal-fired, utility boilers are in operation or under construction. In these systems, the sulfur dioxide removed form the boiler flue gas is permanently bound to a sorbent material, such as lime or limestone. The sulfated sorbent must be disposed of as a waste product or, in some cases, sold as a byproduct (e.g. gypsum). The use of regenerable sorbent technologies has the potential to reduce or eliminate solid waste production, transportation and disposal. Arthur D. Little, Inc., together with its industry and commercialization advisor, Engelhard Corporation, and its university partner, Tufts, plans to develop and scale-up an advanced, byproduct recovery technology that is a direct, catalytic process for reducing sulfur dioxide to elemental sulfur. The principal objective of the Phase 1 program is to identify and evaluate the performance of a catalyst which is robust and flexible with regard to choice of reducing gas. In order to achieve this goal, they have planned a structured program including: market/process/cost/evaluation; lab-scale catalyst preparation/optimization studies; lab-scale, bulk/supported catalyst kinetic studies; bench-scale catalyst/process studies; and utility review. This catalytic process reduces SO{sub 2} over a fluorite-type oxide (such as ceria and zirconia). The catalytic activity can be significantly promoted by active transition metals, such as copper. This type of mixed metal oxide catalyst has stable activity, high selectivity for sulfur production, and is resistant to water and carbon dioxide poisoning.

  4. Production of low-sulfur binder pitch from high-sulfur Illinois coals. Technical report, September 1--November 30, 1994

    SciTech Connect (OSTI)

    Knight, R.A. [Inst. of Gas Technology, Chicago, IL (United States)

    1994-12-31

    The objective of this project is to produce electrode binder pitch with sulfur content below 0.6 wt% from high-sulfur Illinois coal mild gasification liquids. In this project, two approaches to sulfur reduction are being explored in conjunction with thermocracking: (1) the use of conventionally cleaned coal with low ({approximately}1%) sulfur as a mild gasification feedstock, and (2) direct biodesulfurization of the liquids prior to thermocracking. In Case 1, the crude pitch is being produced by mild gasification of IBC-109 coal in an existing IGT bench-scale reactor, followed by distillation of the scrubbing solvent and light-to-middle oils to isolate the crude pitch. In Case 2, the crude pitch for biodesulfurization is the same material previously studied, which was obtained from Illinois No. 6 coal tests conducted in the IGT mild gasification PRU in 1990. Biodesulfurization is to be performed by contacting the pitch with Rhodococcus Rhodochrous either as live cultures or in the form of concentrated biocatalyst. Following preparation of the crude pitches, pitch upgrading experiments are to be conducted in a continuous flash thermocracker (FTC) constructed in previous ICCI-sponsored studies. The finished pitch is then characterized for physical and chemical properties (density, softening point, QI, TI, coking value, and elemental composition), and compared to typical specifications for binder pitches. This quarter, 45 kg of IBC-109 coal was obtained and sized to 40 x 80 mesh for mild gasification. Laboratory experiments were conducted to identify means of dispersing or emulsifying pitch in water to render is accessible to biocatalysts, and exploratory desulfurization tests on one-gram pitch samples were begun.

  5. ENERGY EFFICIENCY LIMITS FOR A RECUPERATIVE BAYONET SULFURIC ACID DECOMPOSITION REACTOR FOR SULFUR CYCLE THERMOCHEMICAL HYDROGEN PRODUCTION

    SciTech Connect (OSTI)

    Gorensek, M.; Edwards, T.

    2009-06-11

    A recuperative bayonet reactor design for the high-temperature sulfuric acid decomposition step in sulfur-based thermochemical hydrogen cycles was evaluated using pinch analysis in conjunction with statistical methods. The objective was to establish the minimum energy requirement. Taking hydrogen production via alkaline electrolysis with nuclear power as the benchmark, the acid decomposition step can consume no more than 450 kJ/mol SO{sub 2} for sulfur cycles to be competitive. The lowest value of the minimum heating target, 320.9 kJ/mol SO{sub 2}, was found at the highest pressure (90 bar) and peak process temperature (900 C) considered, and at a feed concentration of 42.5 mol% H{sub 2}SO{sub 4}. This should be low enough for a practical water-splitting process, even including the additional energy required to concentrate the acid feed. Lower temperatures consistently gave higher minimum heating targets. The lowest peak process temperature that could meet the 450-kJ/mol SO{sub 2} benchmark was 750 C. If the decomposition reactor were to be heated indirectly by an advanced gas-cooled reactor heat source (50 C temperature difference between primary and secondary coolants, 25 C minimum temperature difference between the secondary coolant and the process), then sulfur cycles using this concept could be competitive with alkaline electrolysis provided the primary heat source temperature is at least 825 C. The bayonet design will not be practical if the (primary heat source) reactor outlet temperature is below 825 C.

  6. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2002-04-29

    This document summarizes progress on Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period October 1, 2001 through March 31, 2002. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid is also being determined, as is the removal of arsenic, a known poison for NO{sub X} selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), FirstEnergy Corporation, American Electric Power (AEP) and the Dravo Lime Company are project co-funders. URS Corporation is the prime contractor. This is the fifth reporting period for the subject Cooperative Agreement. During the previous (fourth) period, two long-term sorbent injection tests were conducted, one on Unit 3 at FirstEnergy's Bruce Mansfield Plant (BMP) and one on Unit 1 at AEP's Gavin Plant. Those tests determined the effectiveness of injecting alkaline slurries into the upper furnace of the boiler as a means of controlling sulfuric acid emissions from these units. The alkaline slurries tested included commercially available magnesium hydroxide slurry (Gavin Plant) and a byproduct magnesium hydroxide slurry (at both Gavin and BMP). The tests showed that injecting either the commercial or the byproduct magnesium hydroxide slurry could achieve up to 70-75% overall sulfuric acid removal. At BMP, the overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Plant, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NO{sub X} control than at removing SO{sub 3} formed in the furnace. The SO{sub 3} removal results were presented in the previous semi-annual technical progress report (April 1, 2001 through September 30, 2001). During the current reporting period, additional balance of plant impact information was determined for one of the two tests. These additional balance-of-plant results are presented and discussed in this report. There was no other technical progress to report, because all planned testing as part of this project has been completed.

  7. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2001-11-06

    This document summarizes progress on Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period April 1, 2001 through September 30, 2001. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid is also being determined, as is the removal of arsenic, a known poison for NO{sub x} selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), FirstEnergy Corporation, and the Dravo Lime Company are project co-funders. URS Corporation is the prime contractor. During the current period, American Electric Power (AEP) joined the project as an additional co-funder and as a provider of a host site for testing. This is the fourth reporting period for the subject Cooperative Agreement. During this period, two long-term sorbent injection tests were conducted, one on Unit 3 at FirstEnergy's Bruce Mansfield Plant (BMP) and one on Unit 1 at AEP's Gavin Station. These tests determined the effectiveness of injecting alkaline slurries into the upper furnace of the boiler as a means of controlling sulfuric acid emissions from these units. The alkaline slurries tested included commercially available magnesium hydroxide slurry (Gavin Station), and a byproduct magnesium hydroxide slurry (both Gavin Station and BMP). The tests showed that injecting either the commercial or the byproduct magnesium hydroxide slurry could achieve up to 70 to 75% sulfuric acid removal. At BMP, the overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Station, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NO{sub x} control than at removing SO{sub 3} formed in the furnace. Balance of plant impacts, primarily on the ESP particulate control device, were also determined during both tests. These results are presented and discussed in this report.

  8. A nuclear criticality safety assessment of the loss of moderation control in 2 1/2 and 10-ton cylinders containing enriched UF{sub 6}

    SciTech Connect (OSTI)

    Newvahner, R.L. [Martin Marietta Energy Systems, Inc., Piketon, OH (United States); Pryor, W.A. [PAI Corp., Oak Ridge, TN (United States)

    1991-12-31

    Moderation control for maintaining nuclear criticality safety in 2 {1/2}-ton, 10-ton, and 14-ton cylinders containing enriched uranium hexafluoride (UF{sub 6}) has been used safely within the nuclear industry for over thirty years, and is dependent on cylinder integrity and containment. This assessment evaluates the loss of moderation control by the breaching of containment and entry of water into the cylinders. The first objective of this study was to estimate the required amounts of water entering these large UF{sub 6} cylinders to react with, and to moderate the uranium compounds sufficiently to cause criticality. Hypothetical accident situations were modeled as a uranyl fluoride (UO{sub 2}F{sub 2}) slab above a UF{sub 6} hemicylinder, and a UO{sub 2}F{sub 2} sphere centered within a UF{sub 6} hemicylinder. These situations were investigated by computational analyses utilizing the KENO V.a Monte Carlo Computer Code. The results were used to estimate both the masses of water required for criticality, and the limiting masses of water that could be considered safe. The second objective of the assessment was to calculate the time available for emergency control actions before a criticality would occur, i.e., a {open_quotes}safetime{close_quotes}, for various sources of water and different size openings in a breached cylinder. In the situations considered, except the case for a fire hose, the safetime appears adequate for emergency control actions. The assessment shows that current practices for handling moderation controlled cylinders of low enriched UF{sub 6}, along with the continuation of established personnel training programs, ensure nuclear criticality safety for routine and emergency operations.

  9. Lithium Polysulfidophosphates: A Family of Lithium-Conducting Sulfur-Rich Compounds for Lithium-Sulfur Batteries

    SciTech Connect (OSTI)

    Lin, Zhan [ORNL] [ORNL; Liu, Zengcai [ORNL] [ORNL; Fu, Wujun [ORNL] [ORNL; Dudney, Nancy J [ORNL] [ORNL; Liang, Chengdu [ORNL] [ORNL

    2013-01-01

    Given the great potential for improving the energy density of state-of-the-art lithium-ion batteries by a factor of 5, a breakthrough in lithium-sulfur (Li-S) batteries will have a dramatic impact in a broad scope of energy related fields. Conventional Li-S batteries that use liquid electrolytes are intrinsically short-lived with low energy efficiency. The challenges stem from the poor electronic and ionic conductivities of elemental sulfur and its discharge products. We report herein lithium polysulfidophosphates (LPSP), a family of sulfur-rich compounds, as the enabler of long-lasting and energy-efficient Li-S batteries. LPSP have ionic conductivities of 3.0 10-5 S cm-1 at 25 oC, which is 8 orders of magnitude higher than that of Li2S (~10-13 S cm-1). The high Li-ion conductivity of LPSP is the salient characteristic of these compounds that impart the excellent cycling performance to Li-S batteries. In addition, the batteries are configured in an all-solid state that promises the safe cycling of high-energy batteries with metallic lithium anodes.

  10. Authorized Limits for the Release of a 25 Ton Locomotive, Serial Number 21547, at the Area 25 Engine Maintenance, Assembly, and Disassembly Facility, Nevada Test Site, Nevada

    SciTech Connect (OSTI)

    Jeremy Gwin and Douglas Frenette

    2010-04-08

    This document contains process knowledge and radiological data and analysis to support approval for release of the 25-ton locomotive, Serial Number 21547, at the Area 25 Engine Maintenance, Assembly, and Disassembly (EMAD) Facility, located on the Nevada Test Site (NTS). The 25-ton locomotive is a small, one-of-a-kind locomotive used to move railcars in support of the Nuclear Engine for Rocket Vehicle Application project. This locomotive was identified as having significant historical value by the Nevada State Railroad Museum in Boulder City, Nevada, where it will be used as a display piece. A substantial effort to characterize the radiological conditions of the locomotive was undertaken by the NTS Management and Operations Contractor, National Security Technologies, LLC (NSTec). During this characterization process, seven small areas on the locomotive had contamination levels that exceeded the NTS release criteria (limits consistent with U.S. Department of Energy [DOE] Order DOE O 5400.5, “Radiation Protection of the Public and the Environment”). The decision was made to perform radiological decontamination of these known accessible impacted areas to further the release process. On February 9, 2010, NSTec personnel completed decontamination of these seven areas to within the NTS release criteria. Although all accessible areas of the locomotive had been successfully decontaminated to within NTS release criteria, it was plausible that inaccessible areas of the locomotive (i.e., those areas on the locomotive where it was not possible to perform radiological surveys) could potentially have contamination above unrestricted release limits. To access the majority of these inaccessible areas, the locomotive would have to be disassembled. A complete disassembly for a full radiological survey could have permanently destroyed parts and would have ruined the historical value of the locomotive. Complete disassembly would also add an unreasonable financial burden for the contractor. A decision was reached between the NTS regulator and NSTec, opting for alternative authorized limits from DOE Headquarters. In doing so, NSTec personnel performed a dose model using the DOE-approved modeling code RESRAD-BUILD v3.5 to evaluate scenarios. The parameters used in the dose model were conservative. NSTec’s Radiological Engineering Calculation, REC-2010-001, “Public Dose Estimate from the EMAD 25 Ton Locomotive,” concluded that the four scenarios evaluated were below the 25-millirem per year limit, the “likely” dose scenarios met the “few millirem in a year” criteria, and that the EMAD 25-ton locomotive met the radiological requirements to be released with residual radioactivity to the public.

  11. Development and Application of Advanced Models for Steam Hydrogasification: Process Design and Economic Evaluation

    E-Print Network [OSTI]

    Lu, Xiaoming

    2012-01-01

    MWh electricity, 12% IRR Coal Price, $/metric ton BreakevenCERT-3B 42 $/metric ton coal price Electricity Sale Price,electricity, 42 $/metric ton coal price IRR, percent Figure

  12. Choosing good distance metrics and local planners for probabilistic roadmap motion planning methods 

    E-Print Network [OSTI]

    Bayazit, Osman Burchan

    1998-01-01

    This thesis presents a comparative evaluation of different distance metrics and local planners within the context of probabilistic roadmap methods for motion planning. Both C-space and Workspace distance metrics and local planners are considered...

  13. Modified Anti-de-Sitter Metric, Light-Front Quantized QCD, and...

    Office of Scientific and Technical Information (OSTI)

    Modified Anti-de-Sitter Metric, Light-Front Quantized QCD, and Conformal Quantum Mechanics Citation Details In-Document Search Title: Modified Anti-de-Sitter Metric, Light-Front...

  14. Co-Designing Sustainable Communities: The Identification and Incorporation of Social Performance Metrics in Native American Sustainable Housing and Renewable Energy System Design

    E-Print Network [OSTI]

    Shelby, Ryan

    2013-01-01

    to (1) situate sustainability and its performance metrics inconcept of sustainability and their performance metrics. Thefor sustainability and the social performance metrics for

  15. Characterization of symmetric monotone metrics on the state space of quantum systems

    E-Print Network [OSTI]

    Frank Hansen

    2006-03-29

    The quantum Fisher information is a Riemannian metric, defined on the state space of a quantum system, which is symmetric and decreasing under stochastic mappings. Contrary to the classical case such a metric is not unique. We complete the characterization, initiated by Morozova, Chentsov and Petz, of these metrics by providing a closed and tractable formula for the set of Morozova-Chentsov functions. In addition, we provide a continuously increasing bridge between the smallest and largest symmetric monotone metrics.

  16. SULFUR REMOVAL FROM PIPE LINE NATURAL GAS FUEL: APPLICATION TO FUEL CELL POWER GENERATION SYSTEMS

    SciTech Connect (OSTI)

    King, David L.; Birnbaum, Jerome C.; Singh, Prabhakar

    2003-11-21

    Pipeline natural gas is being considered as the fuel of choice for utilization in fuel cell-based distributed generation systems because of its abundant supply and the existing supply infrastructure (1). For effective utilization in fuel cells, pipeline gas requires efficient removal of sulfur impurities (naturally occurring sulfur compounds or sulfur bearing odorants) to prevent the electrical performance degradation of the fuel cell system. Sulfur odorants such as thiols and sulfides are added to pipeline natural gas and to LPG to ensure safe handling during transportation and utilization. The odorants allow the detection of minute gas line leaks, thereby minimizing the potential for explosions or fires.

  17. Fact #824: June 9, 2014 EPA Sulfur Standards for Gasoline | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for Gasoline Sulfur naturally occurs in gasoline and diesel fuel, contributing to pollution when the fuel is burned. Beginning in 2004, standards were set on the amount of...

  18. Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Information AdministrationPetroleum Marketing Annual 1998 Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales Type, and PAD District (Cents per Gallon Excluding...

  19. Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales...

    Gasoline and Diesel Fuel Update (EIA)

    Information AdministrationPetroleum Marketing Annual 1999 Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales Type, and PAD District (Cents per Gallon Excluding...

  20. Portable instrument and method for detecting reduced sulfur compounds in a gas

    DOE Patents [OSTI]

    Gaffney, J.S.; Kelly, T.J.; Tanner, R.L.

    1983-06-01

    A portable real time instrument for detecting concentrations in the part per billion range of reduced sulfur compounds in a sample gas. Ozonized air or oxygen and reduced sulfur compounds in a sample gas stream react to produce chemiluminescence in a reaction chamber and the emitted light is filtered and observed by a photomultiplier to detect reduced sulfur compounds. Selective response to individual sulfur compounds is achieved by varying reaction chamber temperature and ozone and sample gas flows, and by the use of either air or oxygen as the ozone source gas.

  1. Sulfur barrier for use with in situ processes for treating formations

    DOE Patents [OSTI]

    Vinegar, Harold J. (Bellaire, TX); Christensen, Del Scot (Friendswood, TX)

    2009-12-15

    Methods for forming a barrier around at least a portion of a treatment area in a subsurface formation are described herein. Sulfur may be introduced into one or more wellbores located inside a perimeter of a treatment area in the formation having a permeability of at least 0.1 darcy. At least some of the sulfur is allowed to move towards portions of the formation cooler than the melting point of sulfur to solidify the sulfur in the formation to form the barrier.

  2. A Long-Life, High-Rate Lithium/Sulfur Cell: A Multifaceted Approach...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Long-Life, High-Rate LithiumSulfur Cell: A Multifaceted Approach to Enhancing Cell Performance Min-Kyu Song, , Yuegang Zhang,* ,, and Elton J. Cairns* ,, The...

  3. Status of Heavy Vehicle Diesel Emission Control Sulfur Effects (DECSE) Test Program

    SciTech Connect (OSTI)

    George Sverdrup

    1999-06-07

    DECSE test program is well under way to providing data on effects of sulfur levels in diesel fuel on performance of emission control technologies.

  4. QUATERNIONIC KAHLER AND SPIN(7) METRICS ARISING FROM QUATERNIONIC CONTACT EINSTEIN STRUCTURES

    E-Print Network [OSTI]

    Vassilev, Dimiter N.

    QUATERNIONIC K¨AHLER AND SPIN(7) METRICS ARISING FROM QUATERNIONIC CONTACT EINSTEIN STRUCTURES L construct left invariant quaternionic contact (qc) structures on Lie groups with zero and non-zero torsion, equipped with a certain qc structure, has a quaternionic K¨ahler metric as well as a metric with holonomy

  5. On Some Low Distortion Metric Ramsey Problems Yair Bartal # Nathan Linial + Manor Mendel # Assaf Naor

    E-Print Network [OSTI]

    Bartal, Yair

    On Some Low Distortion Metric Ramsey Problems Yair Bartal # Nathan Linial + Manor Mendel # Assaf Naor December 17, 2002 Abstract In this note, we consider the metric Ramsey problem for the normed metric spaces, no four points of which embed isometrically in # p . 1 Introduction A Ramsey­type theorem

  6. Evaluation of ocean carbon cycle models with data-based metrics K. Matsumoto,1

    E-Print Network [OSTI]

    Drange, Helge

    Evaluation of ocean carbon cycle models with data-based metrics K. Matsumoto,1 J. L. Sarmiento,2 R), Evaluation of ocean carbon cycle models with data-based metrics, Geophys. Res. Lett., 31, L07303, doi:10 of quantitative, data-based metrics of model skill. Further complications arise because models have different

  7. On the use of software quality metrics to im-prove physical properties of embedded systems

    E-Print Network [OSTI]

    Wagner, Flávio Rech

    On the use of software quality metrics to im- prove physical properties of embedded systems Ricardo Abstract: As software production achieves a growing importance in the embed- ded systems world, quality of the correlation between software quality metrics and physical metrics for embedded software. By means

  8. JBOOMT: Jade Bird Object-Oriented Metrics Tool* Tao XIE, Wanghong YUAN, Hong MEI, Fuqing YANG

    E-Print Network [OSTI]

    Xie, Tao

    on software productivity and software quality control has spurred the research on software metrics technology-oriented program and thus evaluate the quality of the software according to the specified hierarchical metrics quality, there exist needs for better technique of software development and software metrics during

  9. Rank and Relevance in Novelty and Diversity Metrics for Recommender Systems

    E-Print Network [OSTI]

    Castells Universidad Autónoma de Madrid Escuela Politécnica Superior, Departamento de Ingeniería for the definition of novelty and diversity metrics that unifies and generalizes several state of the art metrics. We a for- mal metric framework that unifies and generalizes several state of the art measures, and en

  10. WESTERN U.S. STREAM FLOW METRIC DATASET Providing scientific knowledge and technology to sustain

    E-Print Network [OSTI]

    . These are based on daily simulations of the Variable Infiltration Capacity (VIC) macroscale hydrologic model, hydrologic modeling, variable infiltration capacity (VIC), flow metrics, aquatic communities Flow metrics metric da- taset makes it possible to study the effects of droughts, changes in snow- pack, water

  11. Sulfur removal from high-sulfur Illinois coal by low-temperature perchloroethylene (PCE) extraction. Final technical report, September 1, 1991--August 31, 1992

    SciTech Connect (OSTI)

    Chou, M.I.M.; Lytle, J.M. [Illinois State Geological Survey, Champaign, IL (United States); Buchanan, D.H. [Eastern Illinois Univ., Charleston, IL (United States)] [and others

    1992-12-31

    The purposes of this Testing and Materials (ASTM) forms of sulfur analysis. The purposes of this research are to independently confirm and possibly to improve the organic sulfur removal from Illinois coals with the PCE desulfurization process and to verify the forms-of-sulfur determination using the ASTM method for the PCE process evaluation. Problem that limits commercial application of the PCE process is the high chlorine content in the PCE-treated coals. Hence, to develop a dechlorination procedure to remove excess PCE from the PCE-treated coal is an additional goal of this investigation. MWOPC`s results have been repeated on fresh IBC-104 coal. Oxidation of coals was found to affect subsequent PCE desulfurization. Elemental sulfur is more amenable to removal by PCE. Ohio 5/6 coal appears to produce elemental sulfur more readily than Illinois coal during oxidation. Data from X-Ray Diffraction spectroscopy indicate that sulfate in the oxidized Illinois IBC-104 coal is mainly in gypsum form, whereas, sulfate in oxidized Ohio 5/6 sample is mainly in szomolnokite form. These data suggest that the oxidation reaction for Ohio 5/6 coal might occur under catalytic conditions which readily convert pyrite to produce FeSO{sub 4} and elemental sulfur. The higher elemental sulfur content in that coal results in higher ASTM organic sulfur removal by PCE extraction. From mass balance calculation, 96% of the total sulfur and greater than 95% of total iron were accounted for during our PCE tests with both long-term ambient-oxidized IBC-104 coal and ambient-oxidized Ohio 516 coal.

  12. Effect of Environmental Factors on Sulfur Gas Emissions from Drywall

    SciTech Connect (OSTI)

    Maddalena, Randy

    2011-08-20

    Problem drywall installed in U.S. homes is suspected of being a source of odorous and potentially corrosive indoor pollutants. The U.S. Consumer Product Safety Commission's (CPSC) investigation of problem drywall incorporates three parallel tracks: (1) evaluating the relationship between the drywall and reported health symptoms; (2) evaluating the relationship between the drywall and electrical and fire safety issues in affected homes; and (3) tracing the origin and the distribution of the drywall. To assess the potential impact on human health and to support testing for electrical and fire safety, the CPSC has initiated a series of laboratory tests that provide elemental characterization of drywall, characterization of chemical emissions, and in-home air sampling. The chemical emission testing was conducted at Lawrence Berkeley National Laboratory (LBNL). The LBNL study consisted of two phases. In Phase 1 of this study, LBNL tested thirty drywall samples provided by CPSC and reported standard emission factors for volatile organic compounds (VOCs), aldehydes, reactive sulfur gases (RSGs) and volatile sulfur compounds (VSCs). The standard emission factors were determined using small (10.75 liter) dynamic test chambers housed in a constant temperature environmental chamber. The tests were all run at 25 C, 50% relative humidity (RH) and with an area-specific ventilation rate of {approx}1.5 cubic meters per square meter of emitting surface per hour [m{sup 3}/m{sup 2}/h]. The thirty samples that were tested in Phase 1 included seventeen that were manufactured in China in 2005, 2006 and 2009, and thirteen that were manufactured in North America in 2009. The measured emission factors for VOCs and aldehydes were generally low and did not differ significantly between the Chinese and North American drywall. Eight of the samples tested had elevated emissions of volatile sulfur-containing compounds with total RSG emission factors between 32 and 258 micrograms per square meter per hour [{micro}g/m{sup 2}/h]. The dominant sulfur containing compounds in the RSG emission stream were hydrogen sulfide with emission factors between 17-201 {micro}g/m{sup 2}/h, and sulfur dioxide with emission factors between 8-64 {micro}g/m{sup 2}/h. The four highest emitting samples also had a unique signature of VSC emissions including > 40 higher molecular weight sulfur-containing compounds although the emission rate for the VSCs was several orders of magnitude lower than that of the RSGs. All of the high emitting drywall samples were manufactured in China in 2005-2006. Results from Phase 1 provided baseline emission factors for drywall samples manufactured in China and in North America but the results exclude variations in environmental conditions that may exist in homes or other built structures, including various combinations of temperature, RH, ventilation rate and the influence of coatings such as texture and paints. The objective of Phase 2 was to quantify the effect of temperature and RH on the RSG emission factors for uncoated drywall, and to measure the effect of plaster and paint coatings on RSG emission factors from drywall. Additional experiments were also performed to assess the influence of ventilation rate on measured emission factors for drywall.

  13. SULFURIC ACID REMOVAL PROCESS EVALUATION: SHORT-TERM RESULTS

    SciTech Connect (OSTI)

    Gary M. Blythe; Richard McMillan

    2002-02-04

    The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. Sulfuric acid controls are becoming of increasing interest to utilities with coal-fired units for a number of reasons. Sulfuric acid is a Toxic Release Inventory species, a precursor to acid aerosol/condensable emissions, and can cause a variety of plant operation problems such as air heater plugging and fouling, back-end corrosion, and plume opacity. These issues will likely be exacerbated with the retrofit of SCR for NO{sub x} control on some coal-fired plants, as SCR catalysts are known to further oxidize a portion of the flue gas SO{sub 2} to SO{sub 3}. The project is testing the effectiveness of furnace injection of four different calcium- and/or magnesium-based alkaline sorbents on full-scale utility boilers. These reagents have been tested during four one- to two-week tests conducted on two First Energy Bruce Mansfield Plant units. One of the sorbents tested was a magnesium hydroxide slurry produced from a wet flue gas desulfurization system waste stream, from a system that employs a Thiosorbic{reg_sign} Lime scrubbing process. The other three sorbents are available commercially and include dolomite, pressure-hydrated dolomitic lime, and commercial magnesium hydroxide. The dolomite reagent was injected as a dry powder through out-of-service burners, while the other three reagents were injected as slurries through air-atomizing nozzles into the front wall of upper furnace, either across from the nose of the furnace or across from the pendant superheater tubes. After completing the four one- to two-week tests, the most promising sorbents were selected for longer-term (approximately 25-day) full-scale tests. The longer-term tests are being conducted to confirm the effectiveness of the sorbents tested over extended operation and to determine balance-of-plant impacts. This reports presents the results of the short-term tests; the long-term test results will be reported in a later document. The short-term test results showed that three of the four reagents tested, dolomite powder, commercial magnesium hydroxide slurry, and byproduct magnesium hydroxide slurry, were able to achieve 90% or greater removal of sulfuric acid compared to baseline levels. The molar ratio of alkali to flue gas sulfuric acid content (under baseline conditions) required to achieve 90% sulfuric acid removal was lowest for the byproduct magnesium hydroxide slurry. However, this result may be confounded because this was the only one of the three slurries tested with injection near the top of the furnace across from the pendant superheater platens. Injection at the higher level was demonstrated to be advantageous for this reagent over injection lower in the furnace, where the other slurries were tested.

  14. SULFURIC ACID REMOVAL PROCESS EVALUATION: LONG-TERM RESULTS

    SciTech Connect (OSTI)

    Gary M. Blythe; Richard McMillan

    2002-07-03

    The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The project is being co-funded by the U.S. DOE National Energy Technology Laboratory, under Cooperative Agreement DE-FC26-99FT40718, along with EPRI, the American Electric Power Company (AEP), FirstEnergy Corp., the Tennessee Valley Authority, and Dravo Lime, Inc. Sulfuric acid controls are becoming of increasing interest to power generators with coal-fired units for a number of reasons. Sulfuric acid is a Toxic Release Inventory species and can cause a variety of plant operation problems such as air heater plugging and fouling, back-end corrosion, and plume opacity. These issues will likely be exacerbated with the retrofit of selective catalytic reduction (SCR) for NO{sub x} control on many coal-fired plants, as SCR catalysts are known to further oxidize a portion of the flue gas SO{sub 2} to SO{sub 3}. The project previously tested the effectiveness of furnace injection of four different calcium-and/or magnesium-based alkaline sorbents on full-scale utility boilers. These reagents were tested during four one- to two-week tests conducted on two FirstEnergy Bruce Mansfield Plant (BMP) units. One of the sorbents tested was a magnesium hydroxide byproduct slurry produced from a modified Thiosorbic{reg_sign} Lime wet flue gas desulfurization system. The other three sorbents are available commercially and include dolomite, pressure-hydrated dolomitic lime, and commercial magnesium hydroxide. The dolomite reagent was injected as a dry powder through out-of-service burners, while the other three reagents were injected as slurries through air-atomizing nozzles inserted through the front wall of the upper furnace, either across from the nose of the furnace or across from the pendant superheater tubes. After completing the four one- to two-week tests, the most promising sorbents were selected for longer-term (approximately 25-day) full-scale tests on two different units. The longer-term tests were conducted to confirm the effectiveness of the sorbents tested over extended operation on two different boilers, and to determine balance-of-plant impacts. The first long-term test was conducted on FirstEnergy's BMP, Unit 3, and the second test was conducted on AEP's Gavin Plant, Unit 1. The Gavin Plant testing provided an opportunity to evaluate the effects of sorbent injected into the furnace on SO{sub 3} formed across an operating SCR reactor. This report presents the results from those long-term tests. The tests determined the effectiveness of injecting commercially available magnesium hydroxide slurry (Gavin Plant) and byproduct magnesium hydroxide slurry (both Gavin Plant and BMP) for sulfuric acid control. The results show that injecting either slurry could achieve up to 70 to 75% overall sulfuric acid removal. At BMP, this overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Plant, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NOX control than at removing SO{sub 3} formed in the furnace. The long-term tests also determined balance-of-plant impacts from slurry injection during the two tests. These include impacts on boiler back-end temperatures and pressure drops, SCR catalyst properties, ESP performance, removal of other flue gas species, and flue gas opacity. For the most part the balance-of-plant impacts were neutral to positive, although adverse effects on ESP performance became an issue during the BMP test.

  15. SULFURIC ACID REMOVAL PROCESS EVALUATION: SHORT-TERM RESULTS

    SciTech Connect (OSTI)

    Gary M. Blythe; Richard McMillan

    2002-03-04

    The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. Sulfuric acid controls are becoming of increasing interest to utilities with coal-fired units for a number of reasons. Sulfuric acid is a Toxic Release Inventory species, a precursor to acid aerosol/condensable emissions, and can cause a variety of plant operation problems such as air heater plugging and fouling, back-end corrosion, and plume opacity. These issues will likely be exacerbated with the retrofit of SCR for NOX control on some coal-fired plants, as SCR catalysts are known to further oxidize a portion of the flue gas SO{sub 2} to SO{sub 3}. The project is testing the effectiveness of furnace injection of four different calcium- and/or magnesium-based alkaline sorbents on full-scale utility boilers. These reagents have been tested during four one- to two-week tests conducted on two FirstEnergy Bruce Mansfield Plant units. One of the sorbents tested was a magnesium hydroxide slurry produced from a wet flue gas desulfurization system waste stream, from a system that employs a Thiosorbic{reg_sign} Lime scrubbing process. The other three sorbents are available commercially and include dolomite, pressure-hydrated dolomitic lime, and commercial magnesium hydroxide. The dolomite reagent was injected as a dry powder through out-of-service burners, while the other three reagents were injected as slurries through air-atomizing nozzles into the front wall of upper furnace, either across from the nose of the furnace or across from the pendant superheater tubes. After completing the four one- to two-week tests, the most promising sorbents were selected for longer-term (approximately 25-day) full-scale tests. The longer-term tests are being conducted to confirm the effectiveness of the sorbents tested over extended operation and to determine balance-of-plant impacts. This reports presents the results of the short-term tests; the long-term test results will be reported in a later document. The short-term test results showed that three of the four reagents tested, dolomite powder, commercial magnesium hydroxide slurry, and byproduct magnesium hydroxide slurry, were able to achieve 90% or greater removal of sulfuric acid compared to baseline levels. The molar ratio of alkali to flue gas sulfuric acid content (under baseline conditions) required to achieve 90% sulfuric acid removal was lowest for the byproduct magnesium hydroxide slurry. However, this result may be confounded because this was the only one of the three slurries tested with injection near the top of the furnace across from the pendant superheater platens. Injection at the higher level was demonstrated to be advantageous for this reagent over injection lower in the furnace, where the other slurries were tested.

  16. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2003-10-01

    This document summarizes progress on Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period April 1, 2003 through September, 2003. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid is also being determined, as is the removal of arsenic, a known poison for NO{sub x} selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), FirstEnergy Corporation, American Electric Power (AEP) and the Dravo Lime Company are project co-funders. URS Group is the prime contractor. This is the eighth reporting period for the subject Cooperative Agreement. During previous reporting periods, two long-term sorbent injection tests were conducted, one on Unit 3 at FirstEnergy's Bruce Mansfield Plant (BMP) and one on Unit 1 at AEP's Gavin Plant. Those tests determined the effectiveness of injecting alkaline slurries into the upper furnace of the boiler as a means of controlling sulfuric acid emissions from these units. The alkaline slurries tested included commercially available magnesium hydroxide slurry (Gavin Plant), and a byproduct magnesium hydroxide slurry (both Gavin Plant and BMP). The tests showed that injecting either the commercial or the byproduct magnesium hydroxide slurry could achieve up to 70-75% overall sulfuric acid removal. At BMP, the overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Plant, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NO{sub x} control than at removing SO{sub 3} formed in the furnace. The SO{sub 3} removal results were presented in the semi-annual Technical Progress Report for the time period April 1, 2001 through September 30, 2001. Additional balance of plant impact information for the two tests was reported in the Technical Progress Report for the time period October 1, 2001 through March 30, 2002. Additional information became available about the effects of byproduct magnesium hydroxide injection on SCR catalyst coupons during the long-term test at BMP, and those results were reported in the report for the time period April 1, 2002 through September 30, 2002. During the current period, process economic estimates were developed, comparing the costs of the furnace magnesium hydroxide slurry injection process tested as part of this project to a number of other candidate SO{sub 3}/sulfuric acid control technologies for coal-fired power plants. The results of this economic evaluation are included in this progress report.

  17. Advanced Space Propulsion Based on Vacuum (Spacetime Metric) Engineering

    E-Print Network [OSTI]

    Harold E. Puthoff

    2012-02-03

    A theme that has come to the fore in advanced planning for long-range space exploration is the concept that empty space itself (the quantum vacuum, or spacetime metric) might be engineered so as to provide energy/thrust for future space vehicles. Although far-reaching, such a proposal is solidly grounded in modern physical theory, and therefore the possibility that matter/vacuum interactions might be engineered for space-flight applications is not a priori ruled out. As examples, the current development of theoretical physics addresses such topics as warp drives, traversable wormholes and time machines that provide for such vacuum engineering possibilities. We provide here from a broad perspective the physics and correlates/consequences of the engineering of the spacetime metric.

  18. On the existence of certain axisymmetric interior metrics

    SciTech Connect (OSTI)

    Angulo Santacruz, C.; Batic, D.; Nowakowski, M.

    2010-08-15

    One of the effects of noncommutative coordinate operators is that the delta function connected to the quantum mechanical amplitude between states sharp to the position operator gets smeared by a Gaussian distribution. Although this is not the full account of the effects of noncommutativity, this effect is, in particular, important as it removes the point singularities of Schwarzschild and Reissner-Nordstroem solutions. In this context, it seems to be of some importance to probe also into ringlike singularities which appear in the Kerr case. In particular, starting with an anisotropic energy-momentum tensor and a general axisymmetric ansatz of the metric together with an arbitrary mass distribution (e.g., Gaussian), we derive the full set of Einstein equations that the noncommutative geometry inspired Kerr solution should satisfy. Using these equations we prove two theorems regarding the existence of certain Kerr metrics inspired by noncommutative geometry.

  19. Development of Technology Readiness Level (TRL) Metrics and Risk Measures

    SciTech Connect (OSTI)

    Engel, David W.; Dalton, Angela C.; Anderson, K. K.; Sivaramakrishnan, Chandrika; Lansing, Carina

    2012-10-01

    This is an internal project milestone report to document the CCSI Element 7 team's progress on developing Technology Readiness Level (TRL) metrics and risk measures. In this report, we provide a brief overview of the current technology readiness assessment research, document the development of technology readiness levels (TRLs) specific to carbon capture technologies, describe the risk measures and uncertainty quantification approaches used in our research, and conclude by discussing the next steps that the CCSI Task 7 team aims to accomplish.

  20. UNIFIED APPROACH TO CONFORMALLY INVARIANT METRICS ON RIEMANN SURFACES

    E-Print Network [OSTI]

    Sugawa, Toshiyuki

    -metrics aeR defined for all Riemann surfaces R i* *s said to be holomorphically contractive if f*aeR0 aeRR aeR kR for all Riemann surfaces R, where cR and kR den* *ote the Carath-metri* *cs aeR is said to be monotone if aeR0 aeR holds for each Riemann surface R and for each

  1. Cosmology via Metric-Independent Volume-Form Dynamics

    E-Print Network [OSTI]

    Guendelman, Eduardo; Pacheva, Svetlana

    2015-01-01

    The method of non-Riemannian volume-forms (metric-independent covariant integration measure densities on the spacetime manifold) is applied to construct a unified model of dynamical dark energy plus dark matter as a dust fluid resulting from a hidden Noether symmetry of the pertinent scalar field Lagrangian. Canonical Hamiltonian treatment and Wheeler-DeWitt quantization of the latter model are briefly discussed.

  2. Colliding Wave Solutions in a Symmetric Non-metric Theory

    E-Print Network [OSTI]

    Ozay Gurtug; Mustafa Halilsoy

    2008-09-22

    A method is given to generate the non-linear interaction (collision) of linearly polarized gravity coupled torsion waves in a non-metric theory. Explicit examples are given in which strong mutual focussing of gravitational waves containing impulsive and shock components coupled with torsion waves does not result in a curvature singularity. However, the collision of purely torsion waves displays a curvature singularity in the region of interaction.

  3. The d-bar-Neumann operator and the Kobayashi metric 

    E-Print Network [OSTI]

    Kim, Mijoung

    2004-09-30

    compactness of the partialdiff-Neumann operator and the property K in any convex domain. We also find a local property of the Kobayashi metric [Theorem IV.1], in which the domain is not necessary pseudoconvex. We find a more general condition than finite type... . . . . . . . . . . . . . . . . . . . 7 1. L2 Existence Theorem . . . . . . . . . . . . . . . . . . 8 2. Globally Regular Operators . . . . . . . . . . . . . . . 10 3. Compactness in the partialdiff-Neumann Problem . . . . . . . 11 III INHERITANCE OF NONCOMPACTNESS OF THE partialdiff...

  4. A solvent system to provide selective removal of sulfur compounds

    SciTech Connect (OSTI)

    Pearce, R.L.; Bacon, T.R.

    1986-01-01

    Energy costs and SRU inefficiencies resulting from utilization of low strength MEA technology induced a large refinery to convert to MDEA. One of the seven product streams being treated required extremely low carbonyl sulfide in the treated product. This required careful consideration in making the decision to convert. However, the conclusions were that the advantages outweighed the disadvantages. When the initial converted operations verified a need to improve the carbonyl sulfide removal, GAS/SPEC Tech Service produced an innovative solution which allowed for efficient operation at acceptable COS specification, lower energy utilization, reduced solvent losses, and improved sulfur recovery unit operation.

  5. Removal of sulfur and nitrogen containing pollutants from discharge gases

    DOE Patents [OSTI]

    Joubert, James I. (Pittsburgh, PA)

    1986-01-01

    Oxides of sulfur and of nitrogen are removed from waste gases by reaction with an unsupported copper oxide powder to form copper sulfate. The resulting copper sulfate is dissolved in water to effect separation from insoluble mineral ash and dried to form solid copper sulfate pentahydrate. This solid sulfate is thermally decomposed to finely divided copper oxide powder with high specific surface area. The copper oxide powder is recycled into contact with the waste gases requiring cleanup. A reducing gas can be introduced to convert the oxide of nitrogen pollutants to nitrogen.

  6. Method of preparing graphene-sulfur nanocomposites for rechargeable

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing(JournalspectroscopyReport) |(Patent) | SciTech Connect Patent:lithium-sulfur

  7. Sulfur gas emissions from stored flue gas desulfurization solids. Final report

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.

    1981-10-01

    The emissions of volatile, sulfur-containing compounds from the surfaces of 13 flue gas desulfurization (FGD) solids field storage sites have been characterized. The sulfur gas emissions from these storage surfaces were determined by measuring the sulfur gas enhancement of sulfur-free sweep air passing through a dynamic emission flux chamber placed over selected sampling areas. Samples of the enclosure sweep air were cryogenically concentrated in surface-deactivated Pyrex U traps. Analyses were conducted by wall-coated, open-tubular, capillary column, cryogenic, temperature-programmed gas chromatography using a sulfur-selective flame photometric detector. Several major variables associated with FGD sludge production processes were examined in relation to the measured range and variations in sulfur fluxes including: the sulfur dioxide scrubbing reagent used, sludge sulfite oxidation, unfixed or stabilized (fixed) FGD solids, and ponding or landfill storage. The composition and concentration of the measured sulfur gas emissions were found to vary with the type of solids, the effectiveness of rainwater drainage from the landfill surface, the method of impoundment, and the sulfate/sulfite ratio of the solids. The FGD solids emissions may contain hydrogen sulfide, carbonyl sulfide, dimethyl sulfide, carbon disulfide, and dimethyl disulfide in varying concentrations and ratios. In addition, up to four unidentified organo-sulfur compounds were found in the emissions from four different FGD solids. The measured, total sulfur emissions ranged from less than 0.01 to nearly 0.3 kg of sulfur per day for an equivalent 40.5 hectare (100 acre) FGD solids impoundment surface.

  8. On the electromagnetic constitutive laws that are equivalent to spacetime metrics

    E-Print Network [OSTI]

    D. H. Delphenich

    2014-09-17

    The raising of both indices in the components of the Minkowski electromagnetic field strength 2-form to give the components of the electromagnetic excitation bivector field can be regarded as being equivalent to an electromagnetic constitutive law, as well as being defined by the components of the spacetime metric. This notion is clarified, and the nature of the equivalent dielectric tensors and magnetic permeability tensors that are defined by some common spacetime metrics is discussed. The relationship of the basic construction to effective metrics is discussed, and, in particular, the fact that this effective metric is more general than the Gordon metric.

  9. Comparing the risk profiles of renewable and natural gas electricity contracts: A summary of the California Department of Water Resources contracts

    E-Print Network [OSTI]

    Bachrach, Devra; Wiser, Ryan; Bolinger, Mark; Golove, William

    2003-01-01

    per kWh) i f a $10 per metric ton carbon allowance priceper kWh) i f a $100 per metric ton carbon allowance price

  10. ULTRA-LOW SULFUR REDUCTION EMISSION CONTROL DEVICE/DEVELOPMENT OF AN ON-BOARD FUEL SULFUR TRAP

    SciTech Connect (OSTI)

    Ron Rohrbach; Gary Zulauf; Tim Gavin

    2003-04-01

    Honeywell is actively working on a 3-year program to develop and demonstrate proof-of-concept for an ''on-vehicle'' desulfurization fuel filter for heavy-duty diesel engines. Integration of the filter into the vehicle fuel system will reduce the adverse effects sulfur has on post combustion emission control devices such as NO{sub x} adsorbers. The NO{sub x} adsorber may be required to meet the proposed new EPA Tier II and ''2007-Rule'' emission standards. The proposed filter concept is based on Honeywell's reactive filtration technology and experience in liquids handling and conditioning. A regeneration and recycling plan for the spent filters will also be examined. We have chosen to develop and demonstrate this technology based on criteria set forth for a heavy duty CIDI engine system because it represents a more challenging set of conditions of service intervals and overall fuel usage over light duty systems. It is anticipated that the technology developed for heavy-duty applications will be applicable to light-duty as well. Further, technology developed under this proposal would also have application for the use of liquid based fuels for fuel cell power generation. The program consists of four phases. Phase I will focus on developing a concept design and analysis and resolution of technical barriers concerning removal of sulfur-containing species in low sulfur fuels. In Phase II we will concentrate on prototype filter design and preparation followed by qualification testing of this component in a fuel line application. Phase III will study life cycle and regeneration options for the spent filter. Phase IV will focus on efficacy and life testing and component integration. The project team will include a number of partners, with Honeywell International as the prime contractor. The partners include an emission control technology developer (Honeywell International), a fuel technology developer (Marathon Ashland Petroleum), a catalyst technology developer (Johnson Matthey), a CIDI engine manufacturer (Mack Trucks Inc.), a filter recycler (American Wastes Industries), and a low-sulfur fuel supplier (Equilon, a joint venture between Shell and Texaco).

  11. Crystal structure studies on sulfur oxygenase reductase from Acidianus tengchongensis

    SciTech Connect (OSTI)

    Li Mei [National Laboratory of Biomacromolecules, Institute of Biophysics, Chinese Academy of Sciences, 15 Datun Road, Chaoyang District, Beijing 100101 (China); Chen Zhiwei [State Key Laboratory of Microbial Resources, Institute of Microbiology, Chinese Academy of Sciences, Beijing 100101 (China); Zhang Pingfeng; Pan Xiaowei [National Laboratory of Biomacromolecules, Institute of Biophysics, Chinese Academy of Sciences, 15 Datun Road, Chaoyang District, Beijing 100101 (China); Graduate University of the Chinese Academy of Sciences, Beijing 100049 (China); Jiang Chengying [State Key Laboratory of Microbial Resources, Institute of Microbiology, Chinese Academy of Sciences, Beijing 100101 (China); An Xiaomin [National Laboratory of Biomacromolecules, Institute of Biophysics, Chinese Academy of Sciences, 15 Datun Road, Chaoyang District, Beijing 100101 (China); Liu Shuangjiang [State Key Laboratory of Microbial Resources, Institute of Microbiology, Chinese Academy of Sciences, Beijing 100101 (China); Chang Wenrui [National Laboratory of Biomacromolecules, Institute of Biophysics, Chinese Academy of Sciences, 15 Datun Road, Chaoyang District, Beijing 100101 (China)], E-mail: wrchang@sun5.ibp.ac.cn

    2008-05-09

    Sulfur oxygenase reductase (SOR) simultaneously catalyzes oxidation and reduction of elemental sulfur to produce sulfite, thiosulfate, and sulfide in the presence of molecular oxygen. In this study, crystal structures of wild type and mutants of SOR from Acidianus tengchongensis (SOR-AT) in two different crystal forms were determined and it was observed that 24 identical SOR monomers form a hollow sphere. Within the icosatetramer sphere, the tetramer and trimer channels were proposed as the paths for the substrate and products, respectively. Moreover, a comparison of SOR-AT with SOR-AA (SOR from Acidianus ambivalens) structures showed that significant differences existed at the active site. Firstly, Cys31 is not persulfurated in SOR-AT structures. Secondly, the iron atom is five-coordinated rather than six-coordinated, since one of the water molecules ligated to the iron atom in the SOR-AA structure is lost. Consequently, the binding sites of substrates and a hypothetical catalytic process of SOR were proposed.

  12. Catalysts for the selective oxidation of hydrogen sulfide to sulfur

    DOE Patents [OSTI]

    Srinivas, Girish (Thornton, CO); Bai, Chuansheng (Baton Rouge, LA)

    2000-08-08

    This invention provides catalysts for the oxidation of hydrogen sulfide. In particular, the invention provides catalysts for the partial oxidation of hydrogen sulfide to elemental sulfur and water. The catalytically active component of the catalyst comprises a mixture of metal oxides containing titanium oxide and one or more metal oxides which can be selected from the group of metal oxides or mixtures of metal oxides of transition metals or lanthanide metals. Preferred metal oxides for combination with TiO.sub.2 in the catalysts of this invention include oxides of V, Cr, Mn, Fe, Co, Ni, Cu, Nb, Mo, Tc, Ru, Rh, Hf, Ta, W, Au, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu. Catalysts which comprise a homogeneous mixture of titanium oxide and niobium (Nb) oxide are also provided. A preferred method for preparing the precursor homogenous mixture of metal hydroxides is by coprecipitation of titanium hydroxide with one or more other selected metal hydroxides. Catalysts of this invention have improved activity and/or selectivity for elemental sulfur production. Further improvements of activity and/or selectivity can be obtained by introducing relatively low amounts (up to about 5 mol %)of a promoter metal oxide (preferably of metals other than titanium and that of the selected second metal oxide) into the homogeneous metal/titanium oxide catalysts of this invention.

  13. Sulfur isotope fractionation during oxidation of sulfur dioxide: gas-phase oxidation by OH radicals and aqueous oxidation by H2O2, O3 and iron catalysis

    E-Print Network [OSTI]

    Harris, E.

    The oxidation of SO[subscript 2] to sulfate is a key reaction in determining the role of sulfate in the environment through its effect on aerosol size distribution and composition. Sulfur isotope analysis has been used to ...

  14. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2003-06-01

    This document summarizes progress on Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period October 1, 2002 through March 31, 2003. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid is also being determined, as is the removal of arsenic, a known poison for NO{sub x} selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), FirstEnergy Corporation, American Electric Power (AEP) and the Dravo Lime Company are project co-funders. URS Group is the prime contractor. This is the seventh reporting period for the subject Cooperative Agreement. During previous reporting periods, two long-term sorbent injection tests were conducted, one on Unit 3 at FirstEnergy's Bruce Mansfield Plant (BMP) and one on Unit 1 at AEP's Gavin Plant. Those tests determined the effectiveness of injecting alkaline slurries into the upper furnace of the boiler as a means of controlling sulfuric acid emissions from these units. The alkaline slurries tested included commercially available magnesium hydroxide slurry (Gavin Plant), and a byproduct magnesium hydroxide slurry (both Gavin Plant and BMP). The tests showed that injecting either the commercial or the byproduct magnesium hydroxide slurry could achieve up to 70-75% overall sulfuric acid removal. At BMP, the overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Plant, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NO{sub x} control than at removing SO{sub 3} formed in the furnace. The SO3 removal results were presented in the semi-annual Technical Progress Report for the time period April 1, 2001 through September 30, 2001. Additional balance of plant impact information for the two tests was reported in the Technical Progress Report for the time period October 1, 2001 through March 30, 2002. Additional information became available about the effects of byproduct magnesium hydroxide injection on SCR catalyst coupons during the long-term test at BMP, and those results were reported in the previous report (April 1, 2002 through September 30, 2002). During the current period, there was no technical progress to report, because all planned testing as part of this project has been completed. The project period of performance was extended to allow the conduct of testing of another SO{sub 3} control technology, the sodium bisulfite injection process. However, these additional tests have not yet been conducted.

  15. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID REMOVAL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2004-01-01

    The objective of this project has been to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The project was co-funded by the U.S. DOE National Energy Technology Laboratory under Cooperative Agreement DE-FC26-99FT40718, along with EPRI, the American Electric Power Company (AEP), FirstEnergy Corporation, the Tennessee Valley Authority, and Carmeuse North America. Sulfuric acid controls are becoming of increased interest for coal-fired power generating units for a number of reasons. In particular, sulfuric acid can cause plant operation problems such as air heater plugging and fouling, back-end corrosion, and plume opacity. These issues will likely be exacerbated with the retrofit of selective catalytic reduction (SCR) for NOX control, as SCR catalysts are known to further oxidize a portion of the flue gas SO{sub 2} to SO{sub 3}. The project tested the effectiveness of furnace injection of four different magnesium-based or dolomitic alkaline sorbents on full-scale utility boilers. These reagents were tested during one- to two-week tests conducted on two FirstEnergy Bruce Mansfield Plant (BMP) units. One of the sorbents tested was a magnesium hydroxide slurry byproduct from a modified Thiosorbic{reg_sign} Lime wet flue gas desulfurization process. The other three sorbents are available commercially and include dolomite, pressure-hydrated dolomitic lime, and commercially available magnesium hydroxide. The dolomite reagent was injected as a dry powder through out-of-service burners. The other three reagents were injected as slurries through air-atomizing nozzles inserted through the front wall of the upper furnace. After completing the four one- to two-week tests, the most promising sorbents were selected for longer-term (approximately 25-day) full-scale tests on two different units. The longer-term tests were conducted to confirm sorbent effectiveness over extended operation on two different boilers, and to determine balance-of-plant impacts. The first long-term test was conducted on FirstEnergy's BMP Unit 3, and the second was conducted on AEP's Gavin Plant, Unit 1. The Gavin Plant test provided an opportunity to evaluate the effects of sorbent injected into the furnace on SO{sub 3} formed across an operating SCR reactor. A final task in the project was to compare projected costs for furnace injection of magnesium hydroxide slurries to estimated costs for other potential sulfuric acid control technologies. Estimates were developed for reagent and utility costs, and capital costs, for furnace injection of magnesium hydroxide slurries and seven other sulfuric acid control technologies. The estimates were based on retrofit application to a model coal-fired plant.

  16. Mechanistic Studies on the Formation of Trifluoromethyl Sulfur Pentafluoride, SF5CF3sa Greenhouse Gas

    E-Print Network [OSTI]

    Kaiser, Ralf I.

    Mechanistic Studies on the Formation of Trifluoromethyl Sulfur Pentafluoride, SF5CF3sa Greenhouse that a source for this potentially dangerous greenhouse gas might be the recombination of SF5(X2A1) and CF3(X2A1 the strongest greenhouse gas trifluoromethyl sulfur pentafluoride (SF5CF3) with a radiative force of 0.59 W m-2

  17. Adsorbed sulfur-gas methods for both near-surface exploration and downhole logging

    SciTech Connect (OSTI)

    Farwell, S.O.; Barinaga, C.J.; Dolenc, M.R.; Farwell, G.H.

    1986-08-01

    The use of sulfur-containing gases in petroleum exploration is supported by (1) the idea that sulfur may play a role in petroleum genesis, (2) the corresponding existence of sulfur-containing compounds in petroleum and the potential for vertical migration of the low-molecular-weight sulfur species from these reservoirs, (3) the production of H/sub 2/S by anaerobic microorganism populations that develop in the subsurface areas overlying petroleum reservoirs due to the concomitant supply of hydrocarbon nutrients, (4) the recent discovery of near-surface accumulations of pyrite and marcasite as the source of induction potential anomalies over certain fields, and (5) the strong adsorptive affinities of sulfur gases to solid surfaces, which enhance both the concentration and localization of such sulfur-expressed anomalies. During the past 3 years, numerous near-surface soil samples and well cuttings from the Utah-Wyoming Overthrust belt have been analyzed for adsorbed sulfur-gas content by two novel analytical techniques: thermal desorption/metal foil collection/flash desorption/sulfur-selective detection (TD/MFC/FD/SSD) and thermal desorption/cryogenic preconcentration/high-resolution-gas chromatography/optimized-flame photometry (TD/CP/HRGC/OFP).

  18. Assessing historical global sulfur emission patterns for the period 1850--1990

    SciTech Connect (OSTI)

    Lefohn, A.S.; Husar, J.D.; Husar, R.B.; Brimblecombe, P.

    1996-07-19

    Anthropogenic sulfur dioxide emissions from energy-producing and metal production activities have become an important factor in better understanding the relationship between humans and the environment. Concerns about (1) acid rain effects on the environment and (2) anthropogenic aerosols affecting possible global change have prompted interest in the transformation and fate of sulfur in the environment. One step in assessing the importance of sulfur emissions is the development of a reliable regional emission inventory of sulfur as a function of time. The objective of this research effort was to create a homogeneous database for historical sulfur emission estimates for the world. The time from 1850--1990 was selected to include the period of industrialization form the time the main production of fuels and minerals began until the most recent year for which complete production data exist. This research effort attempts to correct some of the deficiencies associated with previous global sulfur emission estimates by (1) identifying those production activities that resulted in sulfur emissions by country and (2) calculating historical emission trends by country across years. An important component of this study was the comparison of the sulfur emission results with those of previous studies.

  19. Understanding the Role of Different Conductive Polymers in Improving the Nanostructured Sulfur Cathode Performance

    E-Print Network [OSTI]

    Cui, Yi

    structural configurations of conductive polymer-sulfur composites employed in previous studies. In this workUnderstanding the Role of Different Conductive Polymers in Improving the Nanostructured Sulfur for the confinement of lithium polysulfides. However, the roles of different conductive polymers

  20. In Operando X-ray Diffraction and Transmission X-ray Microscopy of Lithium Sulfur Batteries

    E-Print Network [OSTI]

    Cui, Yi

    In Operando X-ray Diffraction and Transmission X-ray Microscopy of Lithium Sulfur Batteries Johanna Information ABSTRACT: Rechargeable lithium-sulfur (Li-S) batteries hold great potential for high not well understood. In this Article, these changes in Li-S batteries are studied in operando by X

  1. High-performance hollow sulfur nanostructured battery cathode through a scalable, room temperature,

    E-Print Network [OSTI]

    Cui, Yi

    capacity of 849 and 610 mAh/g at 2C and 4C, respectively. lithium sulfur battery | energy storage | long energy storage (1­4). To achieve a quantum leap in the batteries specific energy density, new electrodeHigh-performance hollow sulfur nanostructured battery cathode through a scalable, room temperature

  2. Surface Science 415 (1998) 2936 Structural studies of sulfur-passivated GaAs (100)

    E-Print Network [OSTI]

    Zhang, Yanchao

    1998-01-01

    . Keywords: Atomic force microscopy; Gallium arsenide; Low-energy electron diffraction; Roughness; SulfurSurface Science 415 (1998) 29­36 Structural studies of sulfur-passivated GaAs (100) surfaces Abstract We present the results of Auger electron spectroscopy (AES), low-energy electron diffraction (LEED

  3. Sulfur surface chemistry on the platinum gate of a silicon carbide based hydrogen sensor

    E-Print Network [OSTI]

    Tobin, Roger G.

    Sulfur surface chemistry on the platinum gate of a silicon carbide based hydrogen sensor Yung Ho September 2007 We have investigated the effects of sulfur contamination on a Pt-gate silicon carbide based monitoring, solid-oxide fuel cells, and coal gasification, require operation at much higher temperatures than

  4. Memory-Assisted Exciton Diffusion in the Chlorosome Light-Harvesting Antenna of Green Sulfur Bacteria

    E-Print Network [OSTI]

    Saikin, Semion

    Memory-Assisted Exciton Diffusion in the Chlorosome Light- Harvesting Antenna of Green Sulfur of bacteriochlorophylls (BChls) enclosed by a lipid monolayer.1-4 They can capture light and transfer it in a form. In green sulfur bacteria, light energy absorbed by the rolls is transferred via a baseplate9 to the Fenna

  5. The sulfur content of volcanic gases on Mars Fabrice Gaillard, a

    E-Print Network [OSTI]

    Boyer, Edmond

    The sulfur content of volcanic gases on Mars Fabrice Gaillard, a and Bruno Scaillet1, a a CNRS sulfur contents of the martian regolith and lack of detection of extensive carbonate deposits suggest that the latest geological events that shaped the landscapes of Mars were dominated by acidic waters possibly

  6. Sulfur removal from high-sulfur Illinois coal by low-temperature perchloroethylene (PCE) extraction. Technical report, September 1, 1991--November 30, 1991

    SciTech Connect (OSTI)

    Chou, M.I.M.

    1991-12-31

    A pre-combustion coal desulfurization process at 120{degree}C using perchloroethylene (PCE) to remove up to 70% of the organic sulfur has been developed by the Midwest Ore Processing Co. (MWOPC). However, this process has not yet proven to be as successful with Illinois coals as it has for Ohio and Indiana coals. The organic sulfur removal has been achieved only with highly oxidized Illinois coals containing high sulfatic sulfur. A logical explanation for this observation is vital to successful process optimization for the use of Illinois coals. In addition, the high levels of organic sulfur removals observed by the MWOPC may be due to certain errors involved in the ASTM data interpretation; this needs verification. For example, elemental sulfur extracted by the PCE may be derived from pyrite oxidation during coal pre-oxidation, but it may be interpreted as organic sulfur removed by the PCE using ASTM analysis. The goals of this research are: (1) to independently confirm and possibly to improve the organic sulfur removal from Illinois coals with the PCE desulfurization process reported by the MWOPC, (2) to verify the forms-of-sulfur determination using the ASTM method for the PCE process evaluation, and (3) to determine the suitability of Illinois coals for use in the PCE desulfurization process. This project involves the Illinois State Geological Survey (ISGS), Eastern Illinois University (EIU), the University of Illinois-Urbana/Champaign (UI-UC), and the University of Kentucky, Lexington (UK). This is the first year of a two-year project.

  7. Nitrous oxide as a substitute for sulfur hexafluoride in the ANSI/ASHRAE 110 Method of hood performance evaluation

    E-Print Network [OSTI]

    Guffey, Eric J. (Eric Jemison)

    2011-01-01

    The ANSI/ASHRAE 110 Method is the standard test for laboratory hood containment performance. Sulfur hexafluoride is specified as the gas most suitable for this test and is most commonly used. Sulfur hexafluoride use has ...

  8. Fractionation of sulfur isotopes by Desulfovibrio vulgaris mutants lacking hydrogenases or type I tetraheme cytochrome c[subscript 3

    E-Print Network [OSTI]

    Sim, Min Sub

    The sulfur isotope effect produced by sulfate reducing microbes is commonly used to trace biogeochemical cycles of sulfur and carbon in aquatic and sedimentary environments. To test the contribution of intracellular coupling ...

  9. Sulfur removal from high-sulfur Illinois coal by low-temperature perchloroethylene (PCE) extraction. [Quarterly] technical report, March 1, 1993--May 31, 1993

    SciTech Connect (OSTI)

    Chou, M.I.M. [Illinois State Geological Survey, Champaign, IL (United States); Buchanan, D.H. [Eastern Illinois Univ., Charleston, IL (United States); Stucki, J.W. [Illinois Univ., Urbana, IL (United States)

    1993-09-01

    The purposes of this project are: to independently confirm and possibly to improve the organic sulfur removal from Illinois coals with the PCE process developed by the Midwest Ore Processing Co. (MWOPC), to verify the forms-of-sulfur determination using the ASTM method for evaluation of the PCE process, and to develop a dechlorination procedure to remove excess PCE from the PCE-treated coal. The objectives for the second year are: to verify the possible effects of PCE treatment on coal-derived FeS{sub 2}, FeSO{sub 4}, and Fe{sub 2}(SO{sub 4}){sub 3} on ASTM coal analysis, to investigate the behavior of sulfur during oxidation and PCE desulfurization using the isotopically signatured coal sample, to investigate the effects of conditions and/or reagents on the oxidation of the organic-sulfur-model compounds, to evaluate the extended oxidation condition on the organic sulfur removal by PCE desulfurization, and to study other innovative pretreatment processes for the removal of organic sulfur from coal under mild conditions.

  10. Effect of Prussian blue on organic sulfur of coal in aqueous medium

    SciTech Connect (OSTI)

    Demirbas, A. [Selcuk University, Konya (Turkey). Dept. of Chemical Engineering

    2007-01-15

    This study is an attempt to desulfurize organic sulfur from coal samples with ferric hexacyanoferrate (II), Fe{sub 4} (Fe(CN){sub 6}), as the desulfurization agent. Effect of temperature, particle size and concentration of ferrocyanide ion on desulfurization from the coal samples has been investigated. The temperature and stirring time are the most important parameters for the level of desulfurization of organic sulfur. Removal of organic sulfur content increased continuously with increasing temperature from 298 to 368 K. The organic sulfur removal rate sharply increases from 10 min to 30 min stirring time. After 30 min, it reaches a value of plateau. Particle size between -100 mesh and -200 mesh slightly affects the amount of organic sulfur removal. Gradual increase in the concentration of ferric hexacyanoferrate (II) raised the magnitude of desulfurization, but at higher concentration, the variation is not significant.

  11. Sulfur dioxide capture in the combustion of mixtures of lime, refuse-derived fuel, and coal

    SciTech Connect (OSTI)

    Churney, K.L.; Buckley, T.J. . Center for Chemical Technology)

    1990-06-01

    Chlorine and sulfur mass balance studies have been carried out in the combustion of mixtures of lime, refuse-derived fuel, and coal in the NIST multikilogram capacity batch combustor. The catalytic effect of manganese dioxide on the trapping of sulfur dioxide by lime was examined. Under our conditions, only 4% of the chlorine was trapped in the ash and no effect of manganese dioxide was observed. Between 42 and 14% of the total sulfur was trapped in the ash, depending upon the lime concentration. The effect of manganese dioxide on sulfur capture was not detectable. The temperature of the ash was estimated to be near 1200{degrees}C, which was in agreement with that calculated from sulfur dioxide capture thermodynamics. 10 refs., 12 figs., 10 tabs.

  12. Sulfur Poisoning and Regeneration of NOx Storage-Reduction Cu/K2Ti2O5 Qiang Wang,*,

    E-Print Network [OSTI]

    Guo, John Zhanhu

    Sulfur Poisoning and Regeneration of NOx Storage-Reduction Cu/K2Ti2O5 Catalyst Qiang Wang,*, Jiahua NOx through the NOx storage-reduction (NSR) process. However, its NSR performance in the presence of sulfur has not been investigated. In this article, the sulfur poisoning of the NOx storage-reduction

  13. Methanol Reaction with Sulfuric Acid: A Vibrational Spectroscopic Study Lisa L. Van Loon and Heather C. Allen*

    E-Print Network [OSTI]

    Methanol Reaction with Sulfuric Acid: A Vibrational Spectroscopic Study Lisa L. Van Loon 43210 ReceiVed: May 27, 2004; In Final Form: August 19, 2004 The reaction between methanol and sulfuric peak in the 800 cm-1 region, not present in either the neat methanol or concentrated sulfuric acid

  14. Population, Economy and Energy Use’s Influence on Sulfur Emissions in the United States Since 1900 

    E-Print Network [OSTI]

    Kissock, J. K.; Husar, R. B.

    1990-01-01

    and the transition from coal to less sulfur intensive fuels have reduced sulfur emissions. The net effect of all drivers has been moderate growth in sulfur emissions from 1900 to present. Since 1973, increased energy efficiency and the shift from an industrial to a...

  15. Characterization of all possible orbits in the Schwarzschild metric revisited

    E-Print Network [OSTI]

    F. T. Hioe; David Kuebel

    2012-07-30

    All possible orbital trajectories and their analytical expressions in the Schwarzschild metric are presented in a single complete map characterized by two dimensionless parameters. While three possible pairs of parameters with different advantages are described, the parameter space that gives the most convenient reduction to the Newtonian case is singled out and used which leads to a new insight on Newtonian limits among other results. Numerous analytic relations are presented. A comparison is made with the widely used formulation and presentation given by S. Chandrasekhar.

  16. Polarizable vacuum analysis of the gravitational metric tensor

    E-Print Network [OSTI]

    Xing-Hao Ye

    2009-03-21

    The gravitational metric tensor implies a variable dielectric tensor of vacuum around gravitational matter. The curved spacetime in general relativity is then associated with a polarizable vacuum. It is found that the number density of the virtual dipoles in vacuum decreases with the distance from the gravitational centre. This result offers a polarizable vacuum interpretation of the gravitational force. Also, the anisotropy of vacuum polarization is briefly discussed, which appeals for observational proof of anisotropic light propagation in a vacuum altered by gravitational or electromagnetic field.

  17. Metrics for the National SCADA Test Bed Program

    SciTech Connect (OSTI)

    Craig, Philip A.; Mortensen, J.; Dagle, Jeffery E.

    2008-12-05

    The U.S. Department of Energy Office of Electricity Delivery and Energy Reliability (DOE-OE) National SCADA Test Bed (NSTB) Program is providing valuable inputs into the electric industry by performing topical research and development (R&D) to secure next generation and legacy control systems. In addition, the program conducts vulnerability and risk analysis, develops tools, and performs industry liaison, outreach and awareness activities. These activities will enhance the secure and reliable delivery of energy for the United States. This report will describe metrics that could be utilized to provide feedback to help enhance the effectiveness of the NSTB Program.

  18. On the metric structure of space-time

    E-Print Network [OSTI]

    Jochen Rau

    2010-09-28

    I present an analysis of the physical assumptions needed to obtain the metric structure of space-time. For this purpose I combine the axiomatic approach pioneered by Robb with ideas drawn from works on Weyl's "Raumproblem". The concept of a Lorentzian manifold is replaced by the weaker concept of an "event manifold", defined in terms of volume element, causal structure and affine connection(s). Exploiting properties of its structure group, I show that distinguishing Lorentzian manifolds from other classes of event manifolds requires the key idea of general relativity: namely that the manifold's physical structure, rather than being fixed, is itself a variable.

  19. User's Guide to the Energy Charting and Metrics Tool (ECAM)

    SciTech Connect (OSTI)

    Taasevigen, Danny J.; Koran, William

    2012-02-28

    The intent of this user guide is to provide a brief description of the functionality of the Energy Charting and Metrics (ECAM) tool, including the expanded building re-tuning functionality developed for Pacific Northwest National laboratory (PNNL). This document describes the tool's general functions and features, and offers detailed instructions for PNNL building re-tuning charts, a feature in ECAM intended to help building owners and operators look at trend data (recommended 15-minute time intervals) in a series of charts (both time series and scatter) to analyze air-handler, zone, and central plant information gathered from a building automation system (BAS).

  20. Widget:CrazyEggMetrics | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EA EISTJThinWarsaw,What Is a SmallAnchorText JumpsourceCrazyEggMetrics Jump