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Note: This page contains sample records for the topic "methyl esters biodiesel" from the National Library of EnergyBeta (NLEBeta).
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1

Combustion chemical kinetics of biodiesel and related compounds (methyl and ethyl esters): Experiments and  

E-Print Network [OSTI]

1 Combustion chemical kinetics of biodiesel and related compounds (methyl and ethyl esters transportation fuel dedicated to the diesel engine, biodiesel, with an emphasis on ethyl esters because of biodiesel and related components, the main gaps in the field are highlighted to facilitate the convergence

Paris-Sud XI, Université de

2

arrhizus ethyl esters: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

1. Introduction Biodiesel, consisting of the methyl or ethyl ester of fatty acids with biodiesel. To the extent that these deal with biodiesel from virgin vegetable fatty acids,...

3

Detailed Chemical Kinetic Reaction Mechanism for Biodiesel Components Methyl Stearate and Methyl Oleate  

SciTech Connect (OSTI)

New chemical kinetic reaction mechanisms are developed for two of the five major components of biodiesel fuel, methyl stearate and methyl oleate. The mechanisms are produced using existing reaction classes and rules for reaction rates, with additional reaction classes to describe other reactions unique to methyl ester species. Mechanism capabilities were examined by computing fuel/air autoignition delay times and comparing the results with more conventional hydrocarbon fuels for which experimental results are available. Additional comparisons were carried out with measured results taken from jet-stirred reactor experiments for rapeseed methyl ester fuels. In both sets of computational tests, methyl oleate was found to be slightly less reactive than methyl stearate, and an explanation of this observation is made showing that the double bond in methyl oleate inhibits certain low temperature chain branching reaction pathways important in methyl stearate. The resulting detailed chemical kinetic reaction mechanism includes more approximately 3500 chemical species and more than 17,000 chemical reactions.

Naik, C; Westbrook, C K; Herbinet, O; Pitz, W J; Mehl, M

2010-01-22T23:59:59.000Z

4

Detailed chemical kinetic reaction mechanism for biodiesel components methyl stearate and methyl oleate  

E-Print Network [OSTI]

Detailed chemical kinetic reaction mechanism for biodiesel components methyl stearate and methyl are developed for two of the five major components of biodiesel fuel, methyl stearate and methyl oleate renewable sources, can reduce net emissions of greenhouse gases. An important class of biodiesel fuels

Paris-Sud XI, Université de

5

Determination of Total Lipids as Fatty Acid Methyl Esters (FAME...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

will be replaced by an ester bond between the fatty acid and a methyl group, producing methyl esters of the fatty acids (FAME) and free glycerol. 1.4 The FAME are then...

6

Experimental study of the oxidation of large surrogates for diesel and biodiesel fuels  

E-Print Network [OSTI]

Experimental study of the oxidation of large surrogates for diesel and biodiesel fuels Mohammed of the oxidation of two blend surrogates for diesel and biodiesel fuels, n-decane/n-hexadecane and n-alkanes and methyl esters. Keywords: Oxidation; Diesel; Biodiesel; Methyl esters; n-Decane; n-Hexadecane; Methyl

Paris-Sud XI, Université de

7

A review of chromatographic characterization techniques for biodiesel and biodiesel blends.  

SciTech Connect (OSTI)

This review surveys chromatographic technology that has been applied to the characterization of biodiesel and its blends. Typically, biodiesel consists of fatty acid methyl esters produced by transesterification of plant or animal derived triacylglycerols. Primary attention is given to the determination of trace impurities in biodiesel, such as methanol, glycerol, mono-, di-, and triacylglycerols, and sterol glucosides. The determination of the fatty acid methyl esters, trace impurities in biodiesel, and the determination of the biodiesel content of commercial blends of biodiesel in conventional diesel are also addressed.

Pauls, R. E. (Chemical Sciences and Engineering Division)

2011-05-01T23:59:59.000Z

8

Modeling study of the lowtemperature oxidation of large methyl esters from C11 to C19  

E-Print Network [OSTI]

in biodiesel fuels has been investigated. Models have been developed for these species and then detailed; Biodiesel fuels; Modeling; Oxidation * Corresponding author: Olivier Herbinet Laboratory of Reaction the differences with the combustion of alkanes induced by the ester function. While biodiesel fuels deriving from

Boyer, Edmond

9

GAS TURBINES AND BIODIESEL : A CLARIFICATION OF THE RELATIVE  

E-Print Network [OSTI]

1 GAS TURBINES AND BIODIESEL : A CLARIFICATION OF THE RELATIVE NOX INDICES OF FAME, GASOIL greenhouse gases emissions and the dependence on oil resources. Biodiesels are Fatty Acid Methyl Esters: rapeseed ("RME"), soybean ("SME"), sunflower, palm etc. A fraction of biodiesel has also an animal origin

Paris-Sud XI, Université de

10

Production and Characterization of Jatropha Oil Methyl Ester  

E-Print Network [OSTI]

pollution concern. Utilization of biodiesel produced from Jatropha oil by transesterification process is one

P. Venkateswara Rao; G. Srinivasa Rao

11

Biodiesel Production and its Emissions and Performance: A Review  

E-Print Network [OSTI]

AbstractThis paper presents a brief review on the current status of biodiesel production and its performance and emission characteristics as compression ignition engine fuel. This study is based on the reports on biodiesel fuel published in the current literature by different researchers. Biodiesel can be produced from crude vegetable oil, non-edible oil, waste frying oil, animal tallow and also from algae by a chemical process called transesterification. Biodiesel is also called methyl or ethyl ester of the corresponding feedstocks from which it has been produced. Biodiesel is completely miscible with diesel oil, thus allowing the use of blends of petro-diesel and biodiesel in any percentage. Presently, biodiesel is blended with mineral diesel and used as fuel. Biodiesel fueled CI engines perform more or less in the same way as that fueled with the mineral fuel. Exhaust emissions are significantly improved due the use of biodiesel or blends of biodiesel and mineral diesel.

Ambarish Datta; Bijan Kumar M

12

Electrochemical method for producing a biodiesel mixture comprising fatty acid alkyl esters and glycerol  

SciTech Connect (OSTI)

The present invention relates to an integrated method and system for the simultaneous production of biodiesel from free fatty acids (via esterification) and from triglycerides (via transesterification) within the same reaction chamber. More specifically, one preferred embodiment of the invention relates to a method and system for the production of biodiesel using an electrodeionization stack, wherein an ion exchange resin matrix acts as a heterogeneous catalyst for simultaneous esterification and transesterification reactions between a feedstock and a lower alcohol to produce biodiesel, wherein the feedstock contains significant levels of free fatty acid. In addition, because of the use of a heterogeneous catalyst, the glycerol and biodiesel have much lower salt concentrations than raw biodiesel produced by conventional transesterification processes. The present invention makes it much easier to purify glycerol and biodiesel.

Lin, YuPo J; St. Martin, Edward J

2013-08-13T23:59:59.000Z

13

acid methyl esters: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

3 (> 170 o C). Each fraction was analyzed composition of fatty acid ethyl esters using gas chromatography (GC). The result showed that the yield medium chain fatty acid ethyl...

14

acid methyl ester: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

3 (> 170 o C). Each fraction was analyzed composition of fatty acid ethyl esters using gas chromatography (GC). The result showed that the yield medium chain fatty acid ethyl...

15

Detailed chemical kinetic oxidation mechanism for a biodiesel surrogate  

SciTech Connect (OSTI)

A detailed chemical kinetic mechanism has been developed and used to study the oxidation of methyl decanoate, a surrogate for biodiesel fuels. This model has been built by following the rules established by Curran et al. for the oxidation of n-heptane and it includes all the reactions known to be pertinent to both low and high temperatures. Computed results have been compared with methyl decanoate experiments in an engine and oxidation of rapeseed oil methyl esters in a jet stirred reactor. An important feature of this mechanism is its ability to reproduce the early formation of carbon dioxide that is unique to biofuels and due to the presence of the ester group in the reactant. The model also predicts ignition delay times and OH profiles very close to observed values in shock tube experiments fueled by n-decane. These model capabilities indicate that large n-alkanes can be good surrogates for large methyl esters and biodiesel fuels to predict overall reactivity, but some kinetic details, including early CO{sub 2} production from biodiesel fuels, can be predicted only by a detailed kinetic mechanism for a true methyl ester fuel. The present methyl decanoate mechanism provides a realistic kinetic tool for simulation of biodiesel fuels.

Herbinet, O; Pitz, W J; Westbrook, C K

2007-09-20T23:59:59.000Z

16

Detailed chemical kinetic oxidation mechanism for a biodiesel surrogate  

SciTech Connect (OSTI)

A detailed chemical kinetic mechanism has been developed and used to study the oxidation of methyl decanoate, a surrogate for biodiesel fuels. This model has been built by following the rules established by Curran et al. for the oxidation of n-heptane and it includes all the reactions known to be pertinent to both low and high temperatures. Computed results have been compared with methyl decanoate experiments in an engine and oxidation of rapeseed oil methyl esters in a jet stirred reactor. An important feature of this mechanism is its ability to reproduce the early formation of carbon dioxide that is unique to biofuels and due to the presence of the ester group in the reactant. The model also predicts ignition delay times and OH profiles very close to observed values in shock tube experiments fueled by n-decane. These model capabilities indicate that large n-alkanes can be good surrogates for large methyl esters and biodiesel fuels to predict overall reactivity, but some kinetic details, including early CO2 production from biodiesel fuels, can be predicted only by a detailed kinetic mechanism for a true methyl ester fuel. The present methyl decanoate mechanism provides a realistic kinetic tool for simulation of biodiesel fuels.

Herbinet, O; Pitz, W J; Westbrook, C K

2007-09-17T23:59:59.000Z

17

Detailed chemical kinetic oxidation mechanism for a biodiesel surrogate  

SciTech Connect (OSTI)

A detailed chemical kinetic mechanism has been developed and used to study the oxidation of methyl decanoate, a surrogate for biodiesel fuels. This model has been built by following the rules established by Curran and co-workers for the oxidation of n-heptane and it includes all the reactions known to be pertinent to both low and high temperatures. Computed results have been compared with methyl decanoate experiments in an engine and oxidation of rapeseed oil methyl esters in a jet-stirred reactor. An important feature of this mechanism is its ability to reproduce the early formation of carbon dioxide that is unique to biofuels and due to the presence of the ester group in the reactant. The model also predicts ignition delay times and OH profiles very close to observed values in shock tube experiments fueled by n-decane. These model capabilities indicate that large n-alkanes can be good surrogates for large methyl esters and biodiesel fuels to predict overall reactivity, but some kinetic details, including early CO{sub 2} production from biodiesel fuels, can be predicted only by a detailed kinetic mechanism for a true methyl ester fuel. The present methyl decanoate mechanism provides a realistic kinetic tool for simulation of biodiesel fuels. (author)

Herbinet, Olivier; Pitz, William J.; Westbrook, Charles K. [Lawrence Livermore National Laboratory, Livermore, CA 94550 (United States)

2008-08-15T23:59:59.000Z

18

Infrared Study of the Molecular Orientation in Ultrathin Films of Behenic Acid Methyl Ester: Comparison between  

E-Print Network [OSTI]

Infrared Study of the Molecular Orientation in Ultrathin Films of Behenic Acid Methyl Ester-Blodgett transfer. The presence in the infrared spectra of several bands due to the methylene wagging and twisting and infrared spectroscopy have been developed to study these films. Infrared spectroscopy is particularly

Pezolet, Michel

19

Modelling Study of the Low-Temperature Oxidation of Large Methyl Esters J. Biet, V. Warth, O. Herbinet*  

E-Print Network [OSTI]

-decane / methyl palmitate mixture in a jet-stirred reactor. This paper also presents the construction and a comparison of models for methyl esters from C7 up to C17 in terms of conversion in a jet-stirred reactor, the development of renewable energy is more vital than ever [1,2]. The production of biofuels such as methyl

Paris-Sud XI, Université de

20

Detailed chemical kinetic mechanism for the oxidation of biodiesel fuels blend surrogate.  

SciTech Connect (OSTI)

Detailed chemical kinetic mechanisms were developed and used to study the oxidation of two large unsaturated esters: methyl-5-decenoate and methyl-9-decenoate. These models were built from a previous methyl decanoate mechanism and were compared with rapeseed oil methyl esters oxidation experiments in a jet stirred reactor. A comparative study of the reactivity of these three oxygenated compounds was performed and the differences in the distribution of the products of the reaction were highlighted showing the influence of the presence and the position of a double bond in the chain. Blend surrogates, containing methyl decanoate, methyl-5-decenoate, methyl-9-decenoate and n-alkanes, were tested against rapeseed oil methyl esters and methyl palmitate/n-decane experiments. These surrogate models are realistic kinetic tools allowing the study of the combustion of biodiesel fuels in diesel and homogeneous charge compression ignition engines.

Herbinet, O; Pitz, W J; Westbrook, C K

2009-07-21T23:59:59.000Z

Note: This page contains sample records for the topic "methyl esters biodiesel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Characterization of Biodiesel Oxidation and Oxidation Products  

SciTech Connect (OSTI)

Features a literature review of 130 technical references pertaining to fatty oil and fatty ester stability chemistry in biodiesel fuels.

Not Available

2005-08-01T23:59:59.000Z

22

Production of Biodiesel from Jatropha Oil (Jatropha curcas) in Pilot Plant  

E-Print Network [OSTI]

AbstractIn this research, among the chemical properties, free fatty acid value of jatropha oil was determined to be 22.6%, 5.23% and 8.8 % respectively. Total, free and combined glycerol percent of raw jatropha oil were 8.27 %, 0.58 % and 7.69 % respectively. Yield of biodiesel from jatropha oil at optimal sodium hydroxide catalyst concentration 1%, reaction temperature 65C, reaction time one hour and molar ratio of methanol to oil 6:1 was 92 % from lab scale. Yield of biodiesel from jatropha oil at optimal potassium hydroxide catalyst concentration 1%, reaction temperature room temperature, reaction time 5 hours and molar ratio of ethanol to oil 8:1 was 90% from the lab scale. Biodiesel was also produced from pilot plant at optimum transesterification process condition as stated above. The yield of biodiesel (methyl ester) and ethyl ester were 92 % and 90% on the basis of refined jatropha oil in the pilot plant scale. The capacity of biodiesel pilot plant is 30 gal / day. The fuel properties of biodiesel, namely cetane index, flash point, pour point, kinematic viscosity, specific gravity, color, copper strip corrosion, acid value, water and sediment and distillation at 90 % recovery, were found to be within the limits of American Society for Testing and Materials (ASTM) specifications for biodiesel and diesel fuel. The fuel consumption of the engine which used biodiesel produced from free fatty acid content 5.23 % in raw jatropha oil is more than the fuel consumption of the engine which used biodiesel produced from free fatty acid content 1 % in refined raw jatropha oil. Keywordsrenewable energy, biodiesel, transesterification, methyl ester, ethyl ester, pilot plant. I.

Tint Tint Kywe; Mya Mya Oo

23

E-Print Network 3.0 - acidmethyl ester concentration Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

or polymers, which, if in high enough concentration, can... methyl ester (CME) Canola ethyl ester (CEE) Mustard methyl ester (MME) Soy methyl ester (SME... degraded....

24

E-Print Network 3.0 - activated ester terminated Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to oxidation, contact with water, andor microbial activity... methyl ester (CME) Canola ethyl ester (CEE) Mustard methyl ester (MME) Soy methyl ester (SME... degraded....

25

ALKALI CATALYSED PRODUCTION OF BIODIESEL FUEL FROM NIGERIAN CITRUS SEEDS OIL  

E-Print Network [OSTI]

biodiesel production was investigated. Fatty acid alkyl esters were produced from orange seed oil, grape

unknown authors

26

Kinetic Modeling of Combustion Characteristics of Real Biodiesel Fuels  

SciTech Connect (OSTI)

Biodiesel fuels are of much interest today either for replacing or blending with conventional fuels for automotive applications. Predicting engine effects of using biodiesel fuel requires accurate understanding of the combustion characteristics of the fuel, which can be acquired through analysis using reliable detailed reaction mechanisms. Unlike gasoline or diesel that consists of hundreds of chemical compounds, biodiesel fuels contain only a limited number of compounds. Over 90% of the biodiesel fraction is composed of 5 unique long-chain C{sub 18} and C{sub 16} saturated and unsaturated methyl esters. This makes modeling of real biodiesel fuel possible without the need for a fuel surrogate. To this end, a detailed chemical kinetic mechanism has been developed for determining the combustion characteristics of a pure biodiesel (B100) fuel, applicable from low- to high-temperature oxidation regimes. This model has been built based on reaction rate rules established in previous studies at Lawrence Livermore National Laboratory. Computed results are compared with the few fundamental experimental data that exist for biodiesel fuel and its components. In addition, computed results have been compared with experimental data for other long-chain hydrocarbons that are similar in structure to the biodiesel components.

Naik, C V; Westbrook, C K

2009-04-08T23:59:59.000Z

27

Non-Edible Plant Oils as New Sources for Biodiesel Production  

E-Print Network [OSTI]

Abstract: Due to the concern on the availability of recoverable fossil fuel reserves and the environmental problems caused by the use those fossil fuels, considerable attention has been given to biodiesel production as an alternative to petrodiesel. However, as the biodiesel is produced from vegetable oils and animal fats, there are concerns that biodiesel feedstock may compete with food supply in the long-term. Hence, the recent focus is to find oil bearing plants that produce non-edible oils as the feedstock for biodiesel production. In this paper, two plant species, soapnut (Sapindus mukorossi) and jatropha (jatropha curcas, L.) are discussed as newer sources of oil for biodiesel production. Experimental analysis showed that both oils have great potential to be used as feedstock for biodiesel production. Fatty acid methyl ester (FAME) from cold pressed soapnut seed oil was envisaged as biodiesel source for the first time. Soapnut oil was found to have average of 9.1 % free FA, 84.43 % triglycerides, 4.88 % sterol and 1.59 % others. Jatropha oil contains approximately 14 % free FA, approximately 5 % higher than soapnut oil. Soapnut oil biodiesel contains approximately 85 % unsaturated FA while jatropha oil biodiesel was found to have approximately 80 % unsaturated FA. Oleic acid was found to be the dominant FA in both soapnut and jatropha biodiesel. Over 97 % conversion to FAME was achieved for both soapnut and jatropha oil.

Arjun B. Chhetri; Martin S. Tango; Suzanne M. Budge; K. Chris Watts

28

Synthesis, droplet combustion, and sooting characteristics of biodiesel produced from waste vegetable oils  

SciTech Connect (OSTI)

In light of the potential of fatty acid methyl ester (FAME, i.e. biodiesel) as a renewable energy source, an innovative acid catalyzed process was developed for the synthesis of biodiesel from waste vegetable oils. The synthesized biodiesels were analytically characterized for their major components, molar fraction and molecular weight of each component, the average molecular weight, and the heat of combustion. Their droplet combustion characteristics in terms of the burning rate, flame size, and sooting tendency were subsequently determined in a high-temperature, freely-falling droplet apparatus. Results show that the biodiesel droplet has higher burning rate, and that biodiesel in general has a lower propensity to soot because its molecular oxygen content promotes the oxidation of the soot precursors.

Li, T. X.; Zhu, D. L.; Akafuah, N.; Saito, K.; Law, C. K.

2011-01-01T23:59:59.000Z

29

Effect of Unburned Methyl Esters on the NOx Conversion of Fe-Zeolite SCR Catalyst  

SciTech Connect (OSTI)

Engine and flow reactor experiments were conducted to determine the impact of biodiesel relative to ultra-low-sulfur diesel (ULSD) on inhibition of the selective catalytic reduction (SCR) reaction over an Fe-zeolite catalyst. Fe-zeolite SCR catalysts have the ability to adsorb and store unburned hydrocarbons (HC) at temperatures below 300 C. These stored HCs inhibit or block NO{sub x}-ammonia reaction sites at low temperatures. Although biodiesel is not a hydrocarbon, similar effects are anticipated for unburned biodiesel and its organic combustion products. Flow reactor experiments indicate that in the absence of exposure to HC or B100, NO{sub x} conversion begins at between 100 and 200 C. When exposure to unburned fuel occurs at higher temperatures (250-400 C), the catalyst is able to adsorb a greater mass of biodiesel than of ULSD. Experiments show that when the catalyst is masked with ULSD, NO{sub x} conversion is inhibited until it is heated to 400 C. However, when masked with biodiesel, NO{sub x} conversion is observed to begin at temperatures as low as 200 C. Engine test results also show low-temperature recovery from HC storage. Engine tests indicate that, overall, the SCR system has a faster recovery from HC masking with biodiesel. This is at least partially due to a reduction in exhaust HCs, and thus total HC exposure with biodiesel.

Williams, A.; Ratcliff, M.; Pedersen, D.; McCormick, R.; Cavataio, G.; Ura, J.

2010-03-01T23:59:59.000Z

30

Production of Biodiesel from Vegetable Oil Using CaO Catalyst & Analysis of Its Performance in Four Stroke Diesel Engine  

E-Print Network [OSTI]

Abstract- The production of biodiesel from vegetable oils stands as a new versatile method of energy generation in the present scenario. Biodiesel is obtained by the transesterification of long chain fatty acids in presence of catalysts. Transesterification is an attractive and widely accepted technique. The purpose of the transesterification process is to lower the viscosity of the oil. The most important variables affecting methyl ester yield during the transesterification reaction are the molar ratio of alcohol to vegetable oil, reaction temperature, catalyst amount and time. Biodiesel is renewable, biodegradable, non-toxic, and essentially free of sulfur and aromatics. It can be used in diesel engines by blending with conventional diesel in various proportions. Biodiesel seems to be a realistic fuel for future. It has become more attractive recently because of its environmental benefits. This paper discuses the production of biodiesel from

Sruthi Gopal; Sajitha C. M; Uma Krishnakumar

31

Detailed chemical kinetic mechanism for the oxidation of biodiesel fuels blend surrogate  

E-Print Network [OSTI]

1 Detailed chemical kinetic mechanism for the oxidation of biodiesel fuels blend surrogate of biodiesel fuels in diesel and homogeneous charge compression ignition engines. Keywords: Methyl decanoate; Methyl decenoate; Surrogate; Oxidation; Biodiesel fuels; Kinetic modeling; Engine; Low

Paris-Sud XI, Université de

32

Emissions and engine performance from blends of soya and canola methyl esters with ARB {number_sign}2 diesel in a DCC 6V92TA MUI engine  

SciTech Connect (OSTI)

A Detroit Diesel 6V92TA MUI engine was operated on several blends of EPA No. 2 diesel, California ARB No. 2 diesel, soya methyl ester (SME) and canola methyl ester (CME). Various fuels and fuel blend characteristics were determined and engine emissions from these fuels and blends were compared. Increasing percentages of SME and CME blended with either ARB or EPA diesels led to increased emissions of NO{sub x}, CO{sub 2} and soluble particulate matter. Also noted were reductions in total hydrocarbons, CO and insoluble particulate matter. Chassis dynamometer tests conducted on a 20/80 SME/ARB blend showed similar emissions trends. The data suggest that certain methyl ester/No. 2 diesel blends in conjunction with delays in engine timing and technologies that reduce the soluble fraction of particulate emissions merit further exploration as emissions reducing fuel options for North American mass transits (except in California, which mandates ARB diesel).

Spataru, A.; Romig, C.

1995-12-31T23:59:59.000Z

33

Emissions and engine performance from blends of soya and canola methyl esters with ARB No. 2 diesel in a DDC 6V92TA MUI engine  

SciTech Connect (OSTI)

A Detroit Diesel 6V92TA MUI engine was operated on several blends of EPA No. 2 diesel, soya methyl ester (SME) and canola methyl ester (CME). Various fuels and fuel blend characteristics were determined and engine emissions from these fuels and blends were compared. Increasing percentages of SME and CME blended with either ARB or EPA diesels led to increased emissions of NO{sub x}, CO{sub 2} and soluble particulate matter. Also noted were reductions in total hydrocarbons, CO and insoluble particulate matter. Chassis dynamometer tests conducted on a 20/80 SME/ARB blend showed similar emission trends. The data suggest that certain methyl ester/No. 2 diesel blends in conjunction with technologies that reduce the soluble fraction of particulate emissions merit further exploration as emissions reducing fuel options for North American mass transit sectors (except California, which mandates ARB diesel).

Spataru, A.; Romig, C. [ADEPT Group, Inc., Los Angeles, CA (United States)

1995-11-01T23:59:59.000Z

34

An Experimental and Kinetic Modeling Study of Methyl Decanoate Combustion  

SciTech Connect (OSTI)

Biodiesel is typically a mixture of long chain fatty acid methyl esters for use in compression ignition engines. Improving biofuel engine performance requires understanding its fundamental combustion properties and the pathways of combustion. This research study presents new combustion data for methyl decanoate in an opposed-flow diffusion flame. An improved detailed chemical kinetic model for methyl decanoate combustion is developed, which serves as the basis for deriving a skeletal mechanism via the direct relation graph method. The novel skeletal mechanism consists of 648 species and 2998 reactions. This mechanism well predicts the methyl decanoate opposed-flow diffusion flame data. The results from the flame simulations indicate that methyl decanoate is consumed via abstraction of hydrogen atoms to produce fuel radicals, which lead to the production of alkenes. The ester moiety in methyl decanoate leads to the formation of low molecular weight oxygenated compounds such as carbon monoxide, formaldehyde, and ketene.

Sarathy, S M; Thomson, M J; Pitz, W J; Lu, T

2010-02-19T23:59:59.000Z

35

E-Print Network 3.0 - anhydroecgonine methyl ester Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Idaho Collection: Environmental Sciences and Ecology 9 A Novel Post-translational Modification of Yeast Elongation Factor 1A Summary: that is released as volatile methyl groups...

36

Standard Thermodynamic Functions of Tripeptides N-Formyl-L-Methionyl-L-Leucyl-L-Phenylalaninol and N-Formyl-L-Methionyl-L-Leucyl-L-Phenylalanine Methyl Ester  

E-Print Network [OSTI]

The heat capacities of tripeptides N-formyl-l-methionyl-l-leucyl-l-phenylalaninol (N-f-MLF-OH) and N-formyl-l-methionyl-l-leucyl-l-phenylalanine methyl ester (N-f-MLF-OMe) were measured by precision adiabatic vacuum ...

Markin, Alexey V.

37

UTILIZING WATER EMULSIFICATION TO REDUCE NOX AND PARTICULATE EMISSIONS ASSOCIATED WITH BIODIESEL  

SciTech Connect (OSTI)

A key barrier limiting extended utilization of biodiesel is higher NOx emissions compared to petrodiesel fuels. The reason for this effect is unclear, but various researchers have attributed this phenomena to the higher liquid bulk modulus associated with biodiesel and the additional heat released during the breaking of C-C double bonds in the methyl ester groups. In this study water was incorporated into neat biodiesel (B100) as an emulsion in an attempt to lower NOx and particulate matter (PM) emissions. A biodiesel emulsion containing 10wt% water was formulated and evaluated against an ultra-low sulfur petroleum diesel (ULSD) and neat biodiesel (B100) in a light-duty diesel engine operated at 1500RPM and at loads of 68Nm (50ft-lbs) and 102Nm (75ft-lbs). The influence of exhaust gas recirculation (EGR) was also examined. The incorporation of water was found to significantly lower the NOx emissions of B100, while maintaining fuel efficiency when operating at 0 and 27% EGR. The soot fraction of the particulates (as determined using an opacity meter) was much lower for the B100 and B100-water emulsion compared ULSD. In contrast, total PM mass (for the three fuel types) was unchanged for the 0% EGR condition but was significantly lower for the B100 and B100-emulsion during the 27% EGR condition compared to the ULSD fuel. Analysis of the emissions and heat release data indicate that water enhances air-fuel premixing to maintain fuel economy and lower soot formation. The exhaust chemistry of the biodiesel base fuels (B100 and water-emulsified B100) was found to be unique in that they contained measurable levels of methyl alkenoates, which were not found for the ULSD. These compounds were formed by the partial cracking of the methyl ester groups during combustion.

Kass, Michael D [ORNL; Lewis Sr, Samuel Arthur [ORNL; Lee, Doh-Won [ORNL; Huff, Shean P [ORNL; Storey, John Morse [ORNL; Swartz, Matthew M [ORNL; Wagner, Robert M [ORNL

2009-01-01T23:59:59.000Z

38

Mississippi State Biodiesel Production Project  

SciTech Connect (OSTI)

Biodiesel is a renewable fuel conventionally generated from vegetable oils and animal fats that conforms to ASTM D6751. Depending on the free fatty acid content of the feedstock, biodiesel is produced via transesterification, esterification, or a combination of these processes. Currently the cost of the feedstock accounts for more than 80% of biodiesel production cost. The main goal of this project was to evaluate and develop non-conventional feedstocks and novel processes for producing biodiesel. One of the most novel and promising feedstocks evaluated involves the use of readily available microorganisms as a lipid source. Municipal wastewater treatment facilities (MWWTF) in the USA produce (dry basis) of microbial sludge annually. This sludge is composed of a variety of organisms, which consume organic matter in wastewater. The content of phospholipids in these cells have been estimated at 24% to 25% of dry mass. Since phospholipids can be transesterified they could serve as a ready source of biodiesel. Examination of the various transesterification methods shows that in situ conversion of lipids to FAMEs provides the highest overall yield of biodiesel. If one assumes a 7.0% overall yield of FAMEs from dry sewage sludge on a weight basis, the cost per gallon of extracted lipid would be $3.11. Since the lipid is converted to FAMEs, also known as biodiesel, in the in Situ extraction process, the product can be used as is for renewable fuel. As transesterification efficiency increases the cost per gallon drops quickly, hitting $2.01 at 15.0% overall yield. An overall yield of 10.0% is required to obtain biodiesel at $2.50 per gallon, allowing it to compete with soybean oil in the marketplace. Twelve plant species with potential for oil production were tested at Mississippi State, MS. Of the species tested, canola, rapeseed and birdseed rape appear to have potential in Mississippi as winter annual crops because of yield. Two perennial crops were investigated, Chinese tallow tree and tung tree. High seed yields from these species are possible because, there stature allows for a third dimension in yield (up). Harvest regimes have already been worked out with tung, and the large seed makes shedding of the seed with tree shakers possible. While tallow tree seed yields can be mind boggling (12,000 kg seed/ha at 40% oil), genotypes that shed seed easily are currently not known. Efficient methods were developed to isolate polyunsaturated fatty acid methyl esters from bio-diesel. The hypothesis to isolate this class of fatty acids, which are used as popular dietary supplements and prescription medicine (OMACOR), was that they bind transition metal ions much stronger than their harmful saturated analogs. AgBF4 has the highest extraction ability among all the metal ions tested. Glycerol is a key product from the production of biodiesel. It is produced during the transesterification process by cleaving the fatty acids from the glycerol backbone (the fatty acids are used as part of the biodiesel, which is a fatty acid methyl ester). Glycerol is a non-toxic compound with many uses; however, if a surplus exists in the future, more uses for the produced glycerol needs to be found. Another phase of the project was to find an add-on process to the biodiesel production process that will convert the glycerol by-product into more valuable substances for end uses other than food or cosmetics, focusing at present on 1,3-propanediol and lactic acid.All three MSU cultures produced products at concentrations below that of the benchmark microorganisms. There was one notable isolate the caught the eye of the investigators and that was culture J6 due to the ability of this microorganism to co-produce both products and one in particularly high concentrations. This culture with more understanding of its metabolic pathways could prove a useful biological agent for the conversion of glycerol. Heterogeneous catalysis was examined as an alternative to overcome the disadvantages of homogeneous transesterification, such as the presence of salts in the glycer

Rafael Hernandez; Todd French; Sandun Fernando; Tingyu Li; Dwane Braasch; Juan Silva; Brian Baldwin

2008-03-20T23:59:59.000Z

39

Detailed chemical kinetic reaction mechanisms for soy and rapeseed biodiesel fuels  

E-Print Network [OSTI]

Detailed chemical kinetic reaction mechanisms for soy and rapeseed biodiesel fuels C.K. Westbrooka chemical kinetic reaction mechanism is developed for the five major components of soy biodiesel and rapeseed biodiesel fuels. These components, methyl stearate, methyl oleate, methyl linoleate, methyl

Paris-Sud XI, Université de

40

Process Intensification in Base-Catalyzed Biodiesel Production  

SciTech Connect (OSTI)

Biodiesel is considered a means to diversify our supply of transportation fuel, addressing the goal of reducing our dependence on oil. Recent interest has resulted in biodiesel manufacture becoming more widely undertaken by commercial enterprises that are interested in minimizing the cost of feedstock materials and waste production, as well as maximizing the efficiency of production. Various means to accelerate batch processing have been investigated. Oak Ridge National Laboratory has experience in developing process intensification methods for nuclear separations, and this paper will discuss how technologies developed for very different applications have been modified for continuous reaction/separation of biodiesel. In collaboration with an industrial partner, this work addresses the aspect of base-catalyzed biodiesel production that limits it to a slow batch process. In particular, we have found that interfacial mass transfer and phase separation control the transesterification process and have developed a continuous two-phase reactor for online production of a methyl ester and glycerol. Enhancing the mass transfer has additional benefits such as being able to use an alcohol-to-oil phase ratio closer to stoichiometric than in conventional processing, hence minimizing the amount of solvent that has to be recycled and reducing post-processing clean up costs. Various technical issues associated with the application of process intensification technology will be discussed, including scale-up from the laboratory to a pilot-scale undertaking.

McFarlane, Joanna [ORNL] [ORNL; Birdwell Jr, Joseph F [ORNL] [ORNL; Tsouris, Costas [ORNL] [ORNL; Jennings, Hal L [ORNL] [ORNL

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "methyl esters biodiesel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Comparative Experimental Investigation of Combustion, Performance and Emission in a Single Cylinder Thermal Barrier Coated Diesel Engine using Diesel and Neem Biodiesel  

E-Print Network [OSTI]

Abstract- The use of methyl esters of vegetable oil known as biodiesel are increasingly popular because of their low impact on environment, green alternate fuel and most interestingly it's use in engines does not require major modification in the engine hardware. Use of biodiesel as sole fuel in conventional direct injection diesel engine results in combustion problems, hence it is proposed to use the biodiesel in low heat rejection (LHR) diesel engines with its significance characteristics of higher operating temperature, maximum heat release, higher brake thermal efficiency (BTE) and ability to handle the lower calorific value (CV) fuel. In this work biodiesel from Neem oil called as Neem oil methyl ester (NOME) was used as sole fuel in conventional diesel engine and LHR direct injection (Dl) diesel engine. The low heat rejection engine was developed with uniform ceramic coating of combustion chamber (includes piston crown, cylinder head, valves and cylinder liner) by partially stabilized /zirconia (PSZ) of 0.5 mm thickness. The experimental investigation was carried out in a single cylinder water-cooled LHR direct injection diesel engine. In this investigation, the combustion, performance and emission analysis were carried out in a diesel and biodiesel fueled conventional and LHR engine under identical operating conditions. The test result of biodiesel fueled LHR engine was quite identical to that of the conventional diesel engine. The brake thermal efficiency (BTE) of LHR engine with biodiesel is decreased marginally than LHR engine operated with diesel. Carbon monoxide (CO) and Hydrocarbon (HC) emission levels are decreased. The results of this comparative experimental investigation reveals that, some of the drawbacks of

M C Navindgi; Dr. Maheswar Dutta; Dr. B. Sudheer Prem Kumar

42

Biodiesel Blends  

SciTech Connect (OSTI)

A 2-page fact sheet discussing general biodiesel blends and the improvement in engine performance and emissions.

Not Available

2005-04-01T23:59:59.000Z

43

Kinetic Model Development for the Combustion of Particulate Matter from Conventional and Soy Methyl Ester Diesel Fuels  

SciTech Connect (OSTI)

The primary objective of this research has been to investigate how the oxidation characteristics of diesel particulate matter (PM) are affected by blending soy-based biodiesel fuel with conventional ultra low sulfur diesel (ULSD) fuel. PM produced in a light duty engine from different biodiesel-conventional fuel blends was subjected to a range of physical and chemical measurements in order to better understand the mechanisms by which fuel-related changes to oxidation reactivity are brought about. These observations were then incorporated into a kinetic model to predict PM oxidation. Nanostructure of the fixed carbon was investigated by HR-TEM and showed that particulates from biodiesel had a more open structure than particulates generated from conventional diesel fuel, which was confirmed by BET surface area measurements. Surface area evolution with extent of oxidation reaction was measured for PM from ULSD and biodiesel. Biodiesel particulate has a significantly larger surface area for the first 40% of conversion, at which point the samples become quite similar. Oxidation characteristics of nascent PM and the fixed carbon portion were measured by temperature programmed oxidation (TPO) and it was noted that increased biodiesel blending lowered the light-off temperature as well as the temperature where the peak rate of oxidation occurred. A shift in the oxidation profiles of all fuels was seen when the mobile carbon fraction was removed, leaving only the fixed carbon, however the trend in temperature advantage of the biofuel blending remained. The mobile carbon fraction was measured by temperature programmed desorption found to generally increase with increasing biodiesel blend level. The relative change in the light-off temperatures for the nascent and fixed carbon samples was found to be related to the fraction of mobile carbon. Effective Arrhenius parameters for fixed carbon oxidation were directly measured with isothermal, differential oxidation experiments. Normalizing the reaction rate to the total carbon surface area available for reaction allowed for the definition of a single reaction rate with constant activation energy (112.5 {+-} 5.8 kJ/mol) for the oxidation of PM, independent of its fuel source. A kinetic model incorporating the surface area dependence of fixed carbon oxidation rate and the impact of the mobile carbon fraction was constructed and validated against experimental data.

Strzelec, Andrea [ORNL

2009-12-01T23:59:59.000Z

44

Biodiesel production using waste frying oil  

SciTech Connect (OSTI)

Research highlights: {yields} Waste sunflower frying oil is successfully converted to biodiesel using lipase as catalyst. {yields} Various process parameters that affects the conversion of transesterification reaction such as temperature, enzyme concentration, methanol: oil ratio and solvent are optimized. {yields} Inhibitory effect of methanol on lipase is reduced by adding methanol in three stages. {yields} Polar solvents like n-hexane and n-heptane increases the conversion of tranesterification reaction. - Abstract: Waste sunflower frying oil is used in biodiesel production by transesterification using an enzyme as a catalyst in a batch reactor. Various microbial lipases have been used in transesterification reaction to select an optimum lipase. The effects of various parameters such as temperature, methanol:oil ratio, enzyme concentration and solvent on the conversion of methyl ester have been studied. The Pseudomonas fluorescens enzyme yielded the highest conversion. Using the P. fluorescens enzyme, the optimum conditions included a temperature of 45 deg. C, an enzyme concentration of 5% and a methanol:oil molar ratio 3:1. To avoid an inhibitory effect, the addition of methanol was performed in three stages. The conversion obtained after 24 h of reaction increased from 55.8% to 63.84% because of the stage-wise addition of methanol. The addition of a non-polar solvent result in a higher conversion compared to polar solvents. Transesterification of waste sunflower frying oil under the optimum conditions and single-stage methanol addition was compared to the refined sunflower oil.

Charpe, Trupti W. [Chemical Engineering Department, Institute of Chemical Technology, Matunga, Mumbai 400 019 (India); Rathod, Virendra K., E-mail: vk.rathod@ictmumbai.edu.in [Chemical Engineering Department, Institute of Chemical Technology, Matunga, Mumbai 400 019 (India)

2011-01-15T23:59:59.000Z

45

Biodiesel Fuel  

E-Print Network [OSTI]

publication 442-880 There are broad and increasing interests across the nation in using domestic, renewable bioenergy. Virginia farmers and transportation fleets use considerable amounts of diesel fuel in their operations. Biodiesel is an excellent alternative fuel for the diesel engines. Biodiesel can be produced from crops commonly grown in Virginia, such as soybean and canola, and has almost the same performance as petrodiesel. The purpose of this publication is to introduce the basics of biodiesel fuel and address some myths and answer some questions about biodiesel fuel before farmers and fleet owners use this type of fuel. ASTM standard for biodiesel (ASTM D6751) Biodiesel fuel, hereafter referred to as simply biodiesel,

unknown authors

46

Biodiesel research progress 1992-1997  

SciTech Connect (OSTI)

The US Department of Energy (DOE) Office of Fuels Development began evaluating the potential of various alternative fuels, including biodiesel, as replacement fuels for traditional transportation fuels. Biodiesel is derived from a variety of biological materials from waste vegetable grease to soybean oil. This alkyl ester could be used as a replacement, blend, or additive to diesel fuel. This document is a comprehensive summary of relevant biodiesel and biodiesel-related research, development demonstration, and commercialization projects completed and/or started in the US between 1992 and 1997. It was designed for use as a reference tool to the evaluating biodiesel`s potential as a clean-burning alternative motor fuel. It encompasses, federally, academically, and privately funded projects. Research projects are presented under the following topical sections: Production; Fuel characteristics; Engine data; Regulatory and legislative activities; Commercialization activities; Economics and environment; and Outreach and education.

Tyson, K.S. [ed.

1998-04-01T23:59:59.000Z

47

Detailed chemical kinetic oxidation mechanism for a biodiesel Olivier Herbineta  

E-Print Network [OSTI]

Detailed chemical kinetic oxidation mechanism for a biodiesel surrogate Olivier Herbineta , William of methyl decanoate, a surrogate for biodiesel fuels. This model has been built by following the rules and biodiesel fuels to predict overall reactivity, but some kinetic details, including early CO2 production from

Paris-Sud XI, Université de

48

Transportation and its Infrastructure  

E-Print Network [OSTI]

fuels include ethanol, biodiesel and methanol, and syntheticEsterification Vegetable oil Biodiesel (esters) Bio oilsuch as ethanol, methanol, biodiesel, di-methyl esters (DME)

2007-01-01T23:59:59.000Z

49

EXPERIMENTAL INVESTIGATION OF PERFORMANCE PARAMETERS OF SINGLE CYLINDER FOUR STROKE DI DIESEL ENGINE OPERATING ON NEEM OIL BIODIESEL AND ITS BLENDS  

E-Print Network [OSTI]

Increasing oil prices, and global warming activates the research and development of substitute energy resources to maintain economic development. The methyl esters of vegetable oil, known as biodiesel are becoming popular because of their low ecological effect and potential as a green substitute for compression ignition engine. The main objective of this study is to investigate the performance of neem oil methyl ester on a single cylinder, four stroke, direct injection, and 8 HP capacity diesel engine. The Experimental research has been performed to analyze the performance of different blends 20 % (BD20), 50 % (BD50), and 100 % (BD100) of neem oil biodiesel. Biodiesel, when compared to conventional diesel fuel, results showed that the brake specific fuel consumption and brake specific energy consumption are higher and brake thermal efficiency less during testing of engine. The brake specific energy consumption is increased by 0.60 % to 8.25 % and brake thermal efficiency decreased by 0.57 % to 7.62 % at 12 kg engine brake load as compared to diesel fuel. When the fuel consumption of biodiesel is compared to diesel fuel it observed that the fuel consumption was increased by 2.5 % to 19.5 % than that of diesel fuel for B20, B50 and B100 bends at 12 kg engine brake load. It is observed that the performance of biodiesel blends is less as compared to plain diesel and during testing of diesel engine run normally for all engine loads. It is investigated that the neem oil biodiesel 20 % blend showed very close performance when compared to plain diesel and hence can be used as an alternative fuel for conventional diesel in the future.

Rob Res; Dharmendra Yadav; Nitin Shrivastava; Vipin Shrivastava

50

Biodiesel Basics (Fact Sheet)  

SciTech Connect (OSTI)

This fact sheet provides a brief introduction to biodiesel, including a discussion of biodiesel blends, which blends are best for which vehicles, where to buy biodiesel, how biodiesel compares to diesel fuel in terms of performance, how biodiesel performs in cold weather, whether biodiesel use will plug vehicle filters, how long-term biodiesel use may affect engines, biodiesel fuel standards, and whether biodiesel burns cleaner than diesel fuel. The fact sheet also dismisses the use of vegetable oil as a motor fuel.

Not Available

2014-06-01T23:59:59.000Z

51

In-cylinder pressure characteristics of a CI engine using blends of diesel fuel and methyl esters of beef tallow  

SciTech Connect (OSTI)

A Cummins N14-410 diesel engine was operated on 12 fuels produced by blending methyl tallowate, methyl soyate, and ethanol with no. 2 diesel fuel. Engine in-cylinder pressure data were used to evaluate engine performance. Peak cylinder pressures for each fuel blend at all engine speeds were lower than peak pressure for diesel fuel with the exception of the 80% diesel, 13% methyl tallowate, and 7% ethanol; and the 80% diesel, 6.5% methyl tallowate, 6.5% methyl soyate and 7% ethanol blends. The indicated mean effective pressure (IMEP) values for all fuel blends were less than for diesel fuel. The differences in IMEP values correlated with differences in power output of the engine. Similarly, maximum rates of pressure rise for most fuel blends were less than for diesel fuel. It was concluded that the fuel blends used in this study would have no detrimental long-term effects on engine performance, wear, and knock. 6 refs., 4 figs., 7 tabs.

Ali, Y.; Hanna, M.A.; Borg, J.E. [Univ. of Nebraska, Lincoln, NE (United States)

1996-05-01T23:59:59.000Z

52

Absolute Biodiesel Potential Country Name  

E-Print Network [OSTI]

Absolute Biodiesel Potential Country Name Production Cost ($/liter) Potential Biodiesel Volume,234 0% 0% #12;Absolute Biodiesel Potential Country Name Production Cost ($/liter) Potential Biodiesel;Absolute Biodiesel Potential Country Name Production Cost ($/liter) Potential Biodiesel Volume (liters

Wisconsin at Madison, University of

53

Fundamental Study of the Oxidation Characteristics and Pollutant Emissions of Model Biodiesel Fuels  

SciTech Connect (OSTI)

In this study, the oxidation characteristics of biodiesel fuels are investigated with the goal of contributing toward the fundamental understanding of their combustion characteristics and evaluating the effect of using these alternative fuels on engine performance as well as on the environment. The focus of the study is on pure fatty acid methyl-esters (FAME,) that can serve as surrogate compounds for real biodiesels. The experiments are conducted in the stagnation-flow configuration, which allows for the systematic evaluation of fundamental combustion and emission characteristics. In this paper, the focus is primarily on the pollutant emission characteristics of two C{sub 4} FAMEs, namely, methyl-butanoate and methyl-crotonate, whose behavior is compared with that of n-butane and n-pentane. To provide insight into the mechanisms of pollutant formation for these fuels, the experimental data are compared with computed results using a model with consistent C{sub 1}?C{sub 4} oxidation and NO{sub x} formation kinetics.

Feng, Q.; Wang, Y. L.; Egolfopoulos, Fokion N.; Tsotsis, T. T.

2010-01-01T23:59:59.000Z

54

Fueling America Through Renewable Resources What Is Biodiesel?  

E-Print Network [OSTI]

The use of vegetable oil as a fuel source in diesel engines is as old as the diesel engine itself. However, the demand to develop and utilize plant oils and animal fats as biodiesel fuels has been limited until recently. The technical definition of biodiesel is: The mono alkyl esters of long fatty acids derived from renewable lipid feedstock such as vegetable oils or animal fats, for use in compression ignition (diesel) engines (National Biodiesel Board, 1996). In simple terms, biodiesel is a renewable fuel manufactured from methanol and vegetable oil, animal fats, and recycled cooking fats (U.S. Department of Energy, 2006). The term biodiesel itself is often misrepresented and misused. Biodiesel only refers to 100 % pure fuel (B100) that meets the definition above and specific standards given

Shawn P. Conley; Department Of Agronomy

55

Physical and chemical comparison of soot in hydrocarbon and biodiesel fuel diffusion flames: A study of model and commercial fuels  

SciTech Connect (OSTI)

Data are presented to compare soot formation in both surrogate and practical fatty acid methyl ester biodiesel and petroleum fuel diffusion flames. The approach here uses differential mobility analysis to follow the size distributions and electrical charge of soot particles as they evolve in the flame, and laser ablation particle mass spectrometry to elucidate their composition. Qualitatively, these soot properties exhibit a remarkably similar development along the flames. The size distributions begin as a single mode of precursor nanoparticles, evolve through a bimodal phase marking the onset of aggregate formation, and end in a self preserving mode of fractal-like particles. Both biodiesel and hydrocarbon fuels yield a common soot composition dominated by C{sub x}H{sub y}{sup +} ions, stabilomer PAHs, and fullerenes in the positive ion mass spectrum, and C{sub x}{sup -} and C{sub 2x}H{sup -} in the negative ion spectrum. These ion intensities initially grow with height in the diffusion flames, but then decline during later stages, consistent with soot carbonization. There are important quantitative differences between fuels. The surrogate biodiesel fuel methyl butanoate substantially reduces soot levels, but soot formation and evolution in this flame are delayed relative to both soy and petroleum fuels. In contrast, soots from soy and hexadecane flames exhibit nearly quantitative agreement in their size distribution and composition profiles with height, suggesting similar soot precursor chemistry. (author)

Matti Maricq, M. [Research and Advanced Engineering, Ford Motor Company, Dearborn, MI (United States)

2011-01-15T23:59:59.000Z

56

Research Article In Situ Biodiesel Production from Fast-Growing and High Oil  

E-Print Network [OSTI]

which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. Rice straw hydrolysate was used as lignocellulose-based carbon source for Chlorella pyrenoidosa cultivation and the feasibility of in situ biodiesel production was investigated. 13.7 g/L sugar was obtained by enzymatic hydrolyzation of rice straw. Chlorella pyrenoidosa showed a rapid growth in the rice straw hydrolysate medium, the maximum biomass concentration of 2.83 g/L was obtained in only 48 hours. The lipid content of the cells reached as high as 56.3%. In situ transesterification was performed for biodiesel production. The optimized condition was 1 g algal powder, 6 mL n-hexane, and 4 mL methanol with 0.5 M sulfuric acid at the temperature of 90 ? C in 2-hour reaction time, under which over 99 % methyl ester content and about 95 % biodiesel yield were obtained. The results suggested that the method has great potential in the production of biofuels with lignocellulose as an alternative carbon source for microalgae cultivation. 1.

Content Chlorella; Rice Straw Hydrolysate; Penglin Li; Xiaoling Miao; Rongxiu Li; Jianjiang Zhong

57

Quality Parameters and Chemical Analysis for Biodiesel Produced in the United States in 2011  

SciTech Connect (OSTI)

Samples of biodiesel (B100) from producers and terminals in 2011were tested for critical properties: free and total glycerin, flash point, cloud point, oxidation stability, cold soak filterability, and metals. Failure rates for cold soak filterability and oxidation stability were below 5%. One sample failed flash point due to excess methanol. One sample failed oxidation stability and metal content. Overall, 95% of the samples from this survey met biodiesel quality specification ASTM D6751. In 2007, a sampling of B100 from production facilities showed that nearly 90% met D6751. In samples meeting D6751, calcium was found above the method detection limit in nearly half the samples. Feedstock analysis revealed half the biodiesel was produced from soy and half was from mixed feedstocks. The saturated fatty acid methyl ester concentration of the B100 was compared to the saturated monoglyceride concentration as a percent of total monoglyceride. The real-world correlation of these properties was very good. The results of liquid chromatograph measurement of monoglycerides were compared to ASTM D6751. Agreement between the two methods was good, particularly for total monoglycerides and unsaturated monoglycerides. Because only very low levels of saturated monoglycerides measured, the two methods had more variability, but the correlation was still acceptable.

Alleman, T. L.; Fouts, L.; Chupka, G.

2013-03-01T23:59:59.000Z

58

Recent progress in biodiesel production and testing at the University of Idaho  

SciTech Connect (OSTI)

Biodiesel from vegetable oil and animal fats has been studied at the University of Idaho since 1979. Recent research is directed toward developing and demonstrating commercial technologies. During the last year an on-road vehicle was driven coast-to-coast on Biodiesel for a total of 14,068 km (8742 miles). As part of this on-road testing, the vehicle was tested for emissions on a chassis dynamometer at the LA-MTA emissions test facility in Los Angeles, California. Tests included HC, CO, CO{sub 2}, NOx, and PM. The two cycles used in the tests included a modified arterial cycle and the EPA cycle for heavy duty vehicles. Biodiesel research has included producing both methyl and ethyl esters from tallow, canola, soybean oil and rapeseed oil. These eight fuels have been subjected to fuel characterization tests according to the ASAE proposed Engineering Practice, Reporting of Fuel Properties with Testing Diesel Engines and Alternative Fuels Derived from Biological Materials, X552; and short term injector coking tests and performance tests in a turbocharged, DI, CI engine. Two-hundred hour EMA endurance tests in 3-cylinder, DI, CI engines are in progress with each of the fuels.

Peterson, C.; Reece, D.; Thompson, J. [Univ. of Idaho, Moscow, ID (United States)] [and others

1995-11-01T23:59:59.000Z

59

A COMBINED REACTION/PRODUCT RECOVERY PROCESS FOR THE CONTINUOUS PRODUCTION OF BIODIESEL  

SciTech Connect (OSTI)

Oak Ridge National Laboratory (ORNL) and Nu-Energie, LLC entered into a Cooperative Research And Development Agreement (CRADA) for the purpose of demonstrating and deploying a novel technology for the continuous synthesis and recovery of biodiesel from the transesterification of triglycerides. The focus of the work was the demonstration of a combination Couette reactor and centrifugal separator - an invention of ORNL researchers - that facilitates both product synthesis and recovery from reaction byproducts in the same apparatus. At present, transesterification of triglycerides to produce biodiesel is performed in batch-type reactors with an excess of a chemical catalyst, which is required to achieve high reactant conversions in reasonable reaction times (e.g., 1 hour). The need for long reactor residence times requires use of large reactors and ancillary equipment (e.g., feed and product tankage), and correspondingly large facilities, in order to obtain the economy of scale required to make the process economically viable. Hence, the goal of this CRADA was to demonstrate successful, extended operation of a laboratory-scale reactor/separator prototype to process typical industrial reactant materials, and to design, fabricate, and test a production-scale unit for deployment at the biodiesel production site. Because of its ease of operation, rapid attainment of steady state, high mass transfer and phase separation efficiencies, and compact size, a centrifugal contactor was chosen for intensification of the biodiesel production process. The unit was modified to increase the residence time from a few seconds to minutes*. For this application, liquid phases were introduced into the reactor as separate streams. One was composed of the methanol and base catalyst and the other was the soy oil used in the experiments. Following reaction in the mixing zone, the immiscible glycerine and methyl ester products were separated in the high speed rotor and collected from separate ports. Results from laboratory operations showed that the ASTM specification for bound acylglycerides was achieved only at extended reaction times ({approx}25 min) using a single-stage batch contact at elevated temperature and pressure. In the single-pass configuration, the time required gives no throughput advantage over the current batch reaction process. The limitation seems to be the presence of glycerine, which hinders complete conversion because of reversible reactions. Significant improvement in quality was indicated after a second and third passes, where product from the first stage was collected and separated from the glycerine, and further reacted with a minor addition of methanol. Chemical kinetics calculations suggest that five consecutive stages of 2 min residence time would produce better than ASTM specification fuel with no addition of methanol past the first stage. Additional stages may increase the capital investment, but the increase should be offset by reduced operating costs and a factor of 3 higher throughput. Biodiesel, a mixture of methyl esters, is made commercially from the transesterification of oil, often soy oil (see Reaction 1). The kinetics of the transesterification process is rapid; however, multiphase separations after the synthesis of the fuel can be problematic. Therefore, the process is typically run in batch mode. The biodiesel fuel and the glycerine product take several hours to separate. In addition, to push yields to completion, an excess of methoxide catalyst is typically used, which has to be removed from both the biodiesel and the glycerine phase after reaction. Washing steps are often employed to remove free fatty acids, which can lead to undesirable saponification. Standards for biodiesel purity are based either on the removal of contaminants before the oil feedstock is esterified or on the separation of unwanted by-products. Various methods have been examined to enhance either the pretreatment of biodiesel feedstocks or the posttreatment of reaction products, including the use of a cavitation reactor in the process i

Birdwell, J.F., Jr.; McFarlane, J.; Schuh, D.L.; Tsouris, C; Day, J.N. (Nu-Energie, LLC); Hullette, J.N. (Nu-Energie, LLC)

2009-09-01T23:59:59.000Z

60

Emissions Benefits From Renewable Fuels and Other Alternatives for Heavy-Duty Vehicles  

E-Print Network [OSTI]

x emissions from biodiesel in newer engine technologies in afeedstock, biodiesel blend level, engine technology, andBiodiesel, Petrodiesel, Neat Methyl Esters, and Alkanes in a New Technology

Hajbabaei, Maryam

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "methyl esters biodiesel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

The Transition to a Carbon-Neutral Energy Economy: Exploring UCSD's Role  

E-Print Network [OSTI]

for ethyl/methyl esters (biodiesel). The world currentlyfuels such as ethanol and biodiesel hold huge promise forIn another example, biodiesel is extracted from seed oils,

2006-01-01T23:59:59.000Z

62

Analytical Framework to Evaluate Emission Control Systems for Marine Engines  

E-Print Network [OSTI]

Ignition Engine Fueled with Biodiesel Blends. Society ofRegulated emissions from biodiesel fuels from on/ off-roadEffects of Methyl Ester Biodiesel Blends on NOx Emissions.

Jayaram, Varalakshmi

2010-01-01T23:59:59.000Z

63

Emissions Benefits From Renewable Fuels and Other Alternatives for Heavy-Duty Vehicles  

E-Print Network [OSTI]

feedstock, biodiesel blend level, engine technology, andx emissions from biodiesel in newer engine technologies in aBiodiesel, Petrodiesel, Neat Methyl Esters, and Alkanes in a New Technology

Hajbabaei, Maryam

2013-01-01T23:59:59.000Z

64

Biodiesel Progress: ASTM Specifications and 2nd Generation Biodiesel...  

Broader source: Energy.gov (indexed) [DOE]

Progress: ASTM Specifications and 2nd Generation Biodiesel Biodiesel Progress: ASTM Specifications and 2nd Generation Biodiesel Presentation given at the 2007 Diesel...

65

Biodiesel Progress: ASTM Specifications and 2nd Generation Biodiesel  

Broader source: Energy.gov (indexed) [DOE]

Progress: ASTM Specifications and 2 nd Generation Biodiesel Steve Howell Technical Director National Biodiesel Board Detroit, Michigan August 15, 2007 Today's Topics Biodiesel...

66

Quantitative NMR Analysis of Partially Substituted Biodiesel Glycerols  

SciTech Connect (OSTI)

Phosphitylation of hydroxyl groups in biodiesel samples with 2-chloro-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane followed by 31P-NMR analysis provides a rapid quantitative analytical technique for the determination of substitution patterns on partially esterified glycerols. The unique 31P-NMR chemical shift data was established with a series mono and di-substituted fatty acid esters of glycerol and then utilized to characterize an industrial sample of partially processed biodiesel.

Nagy, M.; Alleman, T. L.; Dyer, T.; Ragauskas, A. J.

2009-01-01T23:59:59.000Z

67

Production of Biodiesel  

E-Print Network [OSTI]

catalyst concentration play a vital role on the yield of biodiesel produced from seed oil. The effect of

Akhihiero E. T; Oghenejoboh K. M; Umukoro P. O

68

Saponification rates of esters in aqueous dioxane  

E-Print Network [OSTI]

trimethylacetate Ethyl n-'valerate Ethyl isovalerate Ethyl me thylethyla c e tate Ethyl trimethylacetate k in liter/Cmoles min.) 25? 35? 45? 4.56 9.21 13.6 1.73 3.35 5.56 1.10 2.01 3.50 0.469 0.970 1.51 2.27 4.05 6.65 0.793 1.36 2.18 0.360 0.635 0.............................. .......... 9 Methyl and Ethyl Esters of n-Valeric Acid . . . . 9 Methyl and Ethyl Esters of Isovaleric Acid . . . 10 Methyl and Ethyl Esters of Methylethylacetic A c i d ...................................... 11 Methyl and Ethyl Esters...

Christian, John Donald

1952-01-01T23:59:59.000Z

69

Biodiesel Buccaneers Brodie Burke Sara  

E-Print Network [OSTI]

Biodiesel Buccaneers Brodie Burke Sara #12;Questions of the hour Can we make biodiesel at a cheaper cost than buying biodiesel/petroleum diesel at the pump in Olympia? How does methanol compare to ethanol and does it affect the cost and efficiency of biodiesel? http://www.mpgmagazine.com/biodiesel

70

Emerging Scope for Biodiesel for Energy Security and Environmental Protection  

E-Print Network [OSTI]

Abstract---The global fuel crisis in the recent times has generated awareness amongst many countries of their vulnerability to oil embargoes and shortages. Considerable attention has been focused on the development of alternative fuel sources. The Motor vehicle population has also increased tremendously over the last decade in India. Environmental degradation is another outcome of growth in motor vehicle population. One of the strategies adopted to curb deteriorating environmental quality is the use of alternative fuels like Ethanol and biodiesel. Bio-Diesel is being looked upon as a renewable source of energy, which can partially substitute the diesel fuel. Special interest is being shown in view of the potential of this fuel to provide energy security and environment protection. Biodiesel, alkyl ester of fatty acids derived from vegetable oils, is emerging as a technically feasible, economically competitive and environmentally sustainable alternative to diesel. The base catalyzed continuous transesterification of vegetable oils having low viscosity, low free fatty acids and low saturated oil- glycerides is currently the preferred process for biodiesel production. India, continue to have shortage of petroleum products including diesel. We cannot divert our edible oils for biodiesel production due to their continued shortage and are consciously developing biodiesel based on nonedible oils. The efforts being made to have the prospect of providing India a leadership position in renewable energy. However, massive efforts and active multi-agency participation are required for techno- commercial success of biodiesel in India.

Sukhwinder Singh; Dr. S K Mahla

71

Experimental Investigation of Biodiesel Production from Waste Mustard Oil  

E-Print Network [OSTI]

The demand for petroleum is increasing with each passing day. This may be attributed to the limited resources of petroleum crude. Hence there is an urgent need of developing alternative energy sources to meet the ever increasing energy demand. Biofuels are currently being considered from multidimensional perspectives, i.e. depleting fossil fuels, resources, environmental health, energy security and agricultural economy. The two most common types of biofuels are ethanol and biodiesel [1]. Biodiesel is a promising alternative fuel to replace petroleum-based diesel that is produced primarily from vegetable oil, animal fat and waste mustard oil. The vegetable oils which are rich in oxygen can be used as future alternate fuels for the operation of diesel engine [2]. Biodiesel is produced from wasted mustard oil through alkali catalyzed transesterification process. Biodiesel is simple to use, biodegradable, non-toxic and essentially free of sulfur and aromatics. Physical properties like density, flash point, kinematic viscosity, cloud point and pour point were found out for biodiesel produced from waste mustard oil. The same characteristic study was also carried out for conventional diesel fuel and used as a baseline for comparison. The values obtained from waste mustard oil ethyl ester (biodiesel) is closely matched with the conventional diesel fuel and it can be used in diesel engine without any modification. Biodiesel can be used in pure form (B100) or may be blended with petroleum diesel at any concentration in most injection pump diesel engines.

Rajat Subhra Samanta; Mukunda Kumar Das

72

Graphene composite for improvement in the conversion efficiency of flexible poly 3-hexyl-thiophene:[6,6]-phenyl C{sub 71} butyric acid methyl ester polymer solar cells  

SciTech Connect (OSTI)

The solution of thin graphene-sheets obtained from a simple ultrasonic exfoliation process was found to chemically interact with [6,6]-phenyl C{sub 71} butyric acid methyl ester (PCBM) molecules. The thinner graphene-sheets have significantly altered the positions of highest occupied molecular orbital and lowest unoccupied molecular orbital of PCBM, which is beneficial for the enhancement of the open circuit voltage of the solar cells. Flexible bulk heterojunction solar cells fabricated using poly 3-hexylthiophene (P3HT):PCBM-graphene exhibited a power conversion efficiency of 2.51%, which is a ?2-fold increase as compared to those fabricated using P3HT:PCBM. Inclusion of graphene-sheets not only improved the open-circuit voltage but also enhanced the short-circuit current density owing to an improved electron transport.

Chauhan, A. K., E-mail: akchau@barc.gov.in, E-mail: akc.barc@gmail.com; Gusain, Abhay; Jha, P.; Koiry, S. P.; Saxena, Vibha; Veerender, P.; Aswal, D. K.; Gupta, S. K. [Technical Physics Division, Bhabha Atomic Research Centre, Trombay, Mumbai-400085 (India)

2014-03-31T23:59:59.000Z

73

The Production and Analysis of Biodiesel from Waste Chicken Skin and Pork Skin Fat and a Comparison of Fuel Properties to Petroleum Derived Diesel Fuel  

E-Print Network [OSTI]

AbstractPeople today are increasingly health conscious and therefore shopkeepers tend to dispose of fatty chicken and pork skin. Chicken and pork skins thus are sources of solid waste that are usually not utilized. This paper deals with the production of useful biodiesel from utilizing the waste chicken and pork skins. Fat from the waste chicken and pork skins (sourced from local shops), was first extracted and subjected to transesterification. The products of transesterification were FAME (Fatty acid methyl esters) and glycerol. The FAME produced was tested for five parameters namely calorific value, pour point and cloud point when compared to ASTM E2515-11 standard values. Comparison of the obtained values of the five parameters with the standard values for diesel was performed to determine the viability of the biodiesel produced. The results of this experiment showed that the calorific values of FAME produced from chicken skin and pork skin fat were close to that of petroleum derived diesel. However, two test parameters namely kinematic viscosity and pour point differed when compared to diesel; this problem can be circumvented by modifying an automobiles internal combustion engine. Due to the relatively high yield value of biodiesel, it is feasible to utilize chicken skin and pork skin fat at a rural level to produce FAME that can be an alternative to diesel in this time of acute fuel scarcity.

Krish T Bharat; Agni Bhattacharya

74

Biodiesel Production from Linseed Oil and Performance Study of a Diesel Engine 40 BIODIESEL PRODUCTION FROM LINSEED OIL AND PERFORMANCE STUDY OF A DIESEL ENGINE WITH DIESEL BIO-DIESEL FUELS  

E-Print Network [OSTI]

Abstract: The use of biodiesel is rapidly expanding around the world, making it imperative to fully understand the impacts of biodiesel on the diesel engine combustion process and pollutant formation. Biodiesel is known as the mono alkyl esters of long chain fatty acids derived from renewable lipid feedstock, such as vegetable oils or animal fats, for use in compression ignition (diesel) engines. Biodiesel was made by transesterification from linseed oil. In aspect of Bangladesh linseed can play an important role in the production of alternative diesel fuel. The climatic and soil condition of our country is convenient for the production of linseed (Linum Usitatissimum) crop. In the first phase of this work optimization of different parameters for biodiesel production were investigated. In the second phase the performance study of a diesel engine with diesel biodiesel blends were carried out. The results showed that with the variation of catalyst, methanol and reaction time; variation of biodiesel production was realized. About 88 % biodiesel production was experienced with 20 % methanol, 0.5% NaOH catalyst and at 550C. The results also showed that when compared with neat diesel fuel, biodiesel gives almost similar thermal efficiency, lower carbon monoxide (CO) and particulate matter (PM) while slightly higher nitrogen oxide (NOx) emission was experienced.

Md. Nurun Nabi; S. M. Najmul Hoque

75

Biodiesel Safety and Best Management  

E-Print Network [OSTI]

Biodiesel Safety and Best Management Practices for Small-Scale Noncommercial Use and Production you produce biodiesel: · Chemical-resistantgloves(butylrubberisbestfor methanol and lye........................................................................... 1 FuelOptionsfromBiomassOilFeedstocks ......................... 1 UsingBiodiesel

Lee, Dongwon

76

Harmonization of Biodiesel Specifications  

SciTech Connect (OSTI)

Worldwide biodiesel production has grown dramatically over the last several years. Biodiesel standards vary across countries and regions, and there is a call for harmonization. For harmonization to become a reality, standards have to be adapted to cover all feedstocks. Additionally, all feedstocks cannot meet all specifications, so harmonization will require standards to either tighten or relax. For harmonization to succeed, the biodiesel market must be expanded with the alignment of test methods and specification limits, not contracted.

Alleman, T. L.

2008-02-01T23:59:59.000Z

77

Biodiesel Research Update  

Broader source: Energy.gov (indexed) [DOE]

Office of FreedomCAR and Vehicle Technologies Fuels Technology Subprogram U.S. Biodiesel Feedstock Supply Analysis * 1.7 billion annual gallon existing resource * Additional...

78

Genomic Prospecting for Microbial Biodiesel Production  

E-Print Network [OSTI]

prospecting for microbial biodiesel production AthanasiosAC02-06NA25396. Abstract Biodiesel is defined as fatty acidfor the competitive production of biodiesel. 1. Introduction

Lykidis, Athanasios

2008-01-01T23:59:59.000Z

79

Effects of Biodiesel on NOx Emissions  

SciTech Connect (OSTI)

A presentation about the effects of biodiesel on nitrogen oxide emissions presented at the ARB Biodiesel Workshop June 8, 2005.

McCormick, R.

2005-06-01T23:59:59.000Z

80

Biodiesel R&D at NREL  

SciTech Connect (OSTI)

Discusses NREL's biodiesel research priorities and some current research results, including those concerning biodiesel quality and stability.

McCormick, R.; Alleman, T.; Barnitt, R.; Clark, W.; Hayes, B.; Ireland, J.; Proc, K.; Ratcliff, M.; Thornton, M.; Whitacre, S.; Williams, A.

2006-02-06T23:59:59.000Z

Note: This page contains sample records for the topic "methyl esters biodiesel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Developing New Alternative Energy in Virginia: Bio-Diesel from Algae  

SciTech Connect (OSTI)

The overall objective of this study was to select chemical processing equipment, install and operate that equipment to directly convert algae to biodiesel via a reaction patented by Old Dominion University (Pat. No. US 8,080,679B2). This reaction is a high temperature (250- 330{degrees}C) methylation reaction utilizing tetramethylammonium hydroxide (TMAH) to produce biodiesel. As originally envisioned, algal biomass could be treated with TMAH in methanol without the need to separately extract triacylglycerides (TAG). The reactor temperature allows volatilization and condensation of the methyl esters whereas the spent algae solids can be utilized as a high-value fertilizer because they are minimally charred. During the course of this work and immediately prior to commencing, we discovered that glycerol, a major by-product of the conventional transesterification reaction for biofuels, is not formed but rather three methoxylated glycerol derivatives are produced. These derivatives are high-value specialty green chemicals that strongly upgrade the economics of the process, rendering this approach as one that now values the biofuel only as a by-product, the main value products being the methoxylated glycerols. A horizontal agitated thin-film evaporator (one square foot heat transfer area) proved effective as the primary reactor facilitating the reaction and vaporization of the products, and subsequent discharge of the spent algae solids that are suitable for supplementing petrochemicalbased fertilizers for agriculture. Because of the size chosen for the reactor, we encountered problems with delivery of the algal feed to the reaction zone, but envision that this problem could easily disappear upon scale-up or can be replaced economically by incorporating an extraction process. The objective for production of biodiesel from algae in quantities that could be tested could not be met, but we implemented use of soybean oil as a surrogate TAG feed to overcome this limitation. The positive economics of this process are influenced by the following: 1. the weight percent of dry algae in suspension that can be fed into the evaporator, 2. the alga species ability to produce a higher yield of biodiesel, 3. the isolation of valuable methoxylated by-products, 4. recycling and regeneration of methanol and TMAH, and 5. the market value of biodiesel, commercial agricultural fertilizer, and the three methoxylated by-products. The negative economics of the process are the following: 1. the cost of producing dried, ground algae, 2. the capital cost of the equipment required for feedstock mixing, reaction, separation and recovery of products, and reactant recycling, and 3. the electrical cost and other utilities. In this report, the economic factors and results are assembled to predict the commercialization cost and its viability. This direct conversion process and equipment discussed herein can be adapted for various feedstocks including: other algal species, vegetable oil, jatropha oil, peanut oil, sunflower oil, and other TAG containing raw materials as a renewable energy resource.

Hatcher, Patrick [Old Dominion University

2012-03-29T23:59:59.000Z

82

1 THE BRAZILIAN BIODIESEL PROGRAM  

E-Print Network [OSTI]

countries; (2) promote the production of biodiesel in different regions of the country by using a diverse

Munir Y. Soares; Margareth O. Pavan; Clara Barufi; Clio Bermann; Virgnia Parente

83

A novel approach for the characterization of a bilayer of phenyl-c71-butyric-acid-methyl ester and pentacene using ultraviolet photoemission spectroscopy and argon gas cluster ion beam sputtering process  

SciTech Connect (OSTI)

The material arrangement and energy level alignment of an organic bilayer comprising of phenyl-c71-butyric-acid-methyl ester (PCBM-71) and pentacene were studied using ultraviolet photoelectron spectroscopy (UPS) and the argon gas cluster ion beam (GCIB) sputtering process. Although there is a small difference in the full width at half maximum of the carbon C 1s core level peaks and differences in the oxygen O 1s core levels of an X-ray photoemission spectroscopy spectra, these differences are insufficient to clearly distinguish between PCBM-71 and pentacene layers and to classify the interface and bulk regions. On the other hand, the valence band structures in the UPS spectra contain completely distinct configurations for the PCBM-71 and pentacene layers, even when they have similar atomic compositions. According to the valence band structures of the PCBM-71/pentacene/electrodes, the highest unoccupied molecular orbital (HOMO) region of pentacene is at least 0.8 eV closer to the Fermi level than that of PCBM-71 and it does not overlap with any of the chemical states in the valence band structure of PCBM-71. Therefore, by just following the variations in the area of the HOMO region of pentacene, the interface/bulk regions of the PCBM/pentacene layers were distinctly categorized. Besides, the variation of valence band structures as a function of the Ar GCIB sputtering time fully corroborated with the surface morphologies observed in the atomic force microscope images. In summary, we believe that the novel approach, which involves UPS analysis in conjunction with Ar GCIB sputtering, can be one of the best methods to characterize the material distribution and energy level alignments of stacks of organic layers.

Yun, Dong-Jin; Chung, JaeGwan; Jung, Changhoon; Chung, Yeonji; Kim, SeongHeon; Lee, Seunghyup; Kim, Ki-Hong; Han, Hyouksoo; Park, Gyeong-Su; Park, SungHoon [Analytical Science Laboratory of Samsung Advanced Institute of Technology, P.O. Box 14-1, Yongin 446-712 (Korea, Republic of)] [Analytical Science Laboratory of Samsung Advanced Institute of Technology, P.O. Box 14-1, Yongin 446-712 (Korea, Republic of)

2013-09-07T23:59:59.000Z

84

Biodiesel Production From Animal Fats And Its Impact On The Diesel Engine With Ethanol-Diesel Blends: A Review  

E-Print Network [OSTI]

Abstract Mainly animal fats and vegetable oils are used for the production of biodiesel. Several types of fuels can be derived from triacylglycerol-containing feedstock. Biodiesel which is defined as the mono-alkyl esters of vegetable oils or animal fats. Biodiesel is produced by transesterifying the oil or fat with an alcohol (methanol/ethanol) under mild conditions in the presence of a base catalyst. This paper discuses fuel production, fuel properties, environmental effects including exhaust emissions and co-products. This also describes the use of glycerol which is the by-product in esterification process along with biodiesel. The impact of blending of biodiesel with ethanol and diesel on the diesel engine has described.

Darunde Dhiraj S; Prof Deshmukh Mangesh M

85

Study of Performance Characteristics of Diesel Engine Fuelled with Diesel, Yellow Grease Biodiesel and its Blends  

E-Print Network [OSTI]

Abstract The feedstock used in our experiment for the production of biodiesel was Yellow Grease. The whole experiment was divided into two parts: Production and Testing. Production involves Transesterification of free fatty acids in yellow grease to form yellow grease alkyl esters. The process of testing involved calculation of the physio chemical properties, acid value, density, kinematics viscosity and various performance characteristics. The properties obtained were similar to the standards of biodiesel set by ASTM D6751. The conclusions derived from the experiments conducted were that the break thermal efficiency with biodiesel blends was little lower than that of diesel. The break specific energy consumption for B20, B40, B60, B80 and B100 is slightly higher than neat diesel. At all loads, diesel was found to have the lowet exhaust tempearture and the temperature for the different blends showed the upward trend with increasing concentration of biodiesel in the blends.

Virender Singh; Shubham Saxena; Shibayan Ghosh; Ankit Agrawal

86

Galib, Biodiesel from jatropha oil as an alternative fuel for diesel engine  

E-Print Network [OSTI]

Abstract The world is getting modernized and industrialized day by day. As a result vehicles and engines are increasing. But energy sources used in these engines are limited and decreasing gradually. This situation leads to seek an alternative fuel for diesel engine. Biodiesel is an alternative fuel for diesel engine. The esters of vegetables oil animal fats are known as Biodiesel. This paper investigates the prospect of making of biodiesel from jatropha oil. Jatropha curcas is a renewable non-edible plant. Jatropha is a wildly growing hardy plant in arid and semi-arid regions of the country on degraded soils having low fertility and moisture. The seeds of Jatropha contain 50-60 % oil. In this study the oil has been converted to biodiesel by the well-known transesterification process and used it to diesel engine for performance evaluation.

Kazi Mostafijur Rahman; Mohammad Mashud; Md. Roknuzzaman; Asadullah Al Galib

87

Snohomish County Biodiesel Project  

SciTech Connect (OSTI)

Snohomish County in western Washington State began converting its vehicle fleet to use a blend of biodiesel and petroleum diesel in 2005. As prices for biodiesel rose due to increased demand for this cleaner-burning fuel, Snohomish County looked to its farmers to ???¢????????grow???¢??????? this fuel locally. Suitable seed crops that can be crushed to extract oil for use as biodiesel feedstock include canola, mustard, and camelina. The residue, or mash, has high value as an animal feed. County farmers began with 52 acres of canola and mustard crops in 2006, increasing to 250 acres and 356 tons in 2008. In 2009, this number decreased to about 150 acres and 300 tons due to increased price for mustard seed.

Terrill Chang; Deanna Carveth

2010-02-01T23:59:59.000Z

88

Monthly Biodiesel Production Report  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecember 2005 (Thousand9,0,InformationU.S. Crude Oil3 13,,8.1 64.1BiodieselBiodiesel

89

Experimental Autoignition of C4-C6 Saturated and Unsaturated Methyl and Ethyl Esters H. Bennadji*, J. Biet, L. Coniglio-Jaubert, F. Billaud, P.A. Glaude, F. Battin-Leclerc  

E-Print Network [OSTI]

is an alternative fuel which can be used directly to a diesel engine without modifying the engine system. Basically lubricity and no sulfur content [2]. It can be stored just like mineral diesel and hence does not require separate infrastructure. The use of biodiesel in conventional diesel engines results in substantial

Boyer, Edmond

90

Algae Biodiesel: Commercialization  

E-Print Network [OSTI]

be grown year around 11 · Can grow algae in produced water from oil and gas wells. This water is considered · Understand need for adequate quantities of economically renewable feedstock that produces an oil which can testing 5/2006 ·Made first biodiesel from local freshwater algae 6/2006 ·Inoculated first outdoor tank 8

Tullos, Desiree

91

Modeling the Auto-Ignition of Biodiesel Blends with a Multi-Step Model  

SciTech Connect (OSTI)

There is growing interest in using biodiesel in place of or in blends with petrodiesel in diesel engines; however, biodiesel oxidation chemistry is complicated to directly model and existing surrogate kinetic models are very large, making them computationally expensive. The present study describes a method for predicting the ignition behavior of blends of n-heptane and methyl butanoate, fuels whose blends have been used in the past as a surrogate for biodiesel. The autoignition is predicted using a multistep (8-step) model in order to reduce computational time and make this a viable tool for implementation into engine simulation codes. A detailed reaction mechanism for n-heptane-methyl butanoate blends was used as a basis for validating the multistep model results. The ignition delay trends predicted by the multistep model for the n-heptane-methyl butanoate blends matched well with that of the detailed CHEMKIN model for the majority of conditions tested.

Toulson, Dr. Elisa [Michigan State University, East Lansing; Allen, Casey M [Michigan State University, East Lansing; Miller, Dennis J [Michigan State University, East Lansing; McFarlane, Joanna [ORNL; Schock, Harold [Michigan State University, East Lansing; Lee, Tonghun [Michigan State University, East Lansing

2011-01-01T23:59:59.000Z

92

2004 Biodiesel Handling and Use Guidelines (Revised)  

SciTech Connect (OSTI)

This document is a guide for those who blend, distribute, and use biodiesel and biodiesel blends. It is intended to fleets and individual users, blenders, distributors, and those involved in related activities understand procedures for handling and using biodiesel.

Not Available

2004-11-01T23:59:59.000Z

93

Biodiesel from microalgae beats Yusuf Chisti  

E-Print Network [OSTI]

Biodiesel from microalgae beats bioethanol Yusuf Chisti School of Engineering, Massey University- derived transport fuels, which contribute to global warming and are of limited availability. Biodiesel, biodiesel and bioethanol produced from agricul- tural crops using existing methods cannot sustainably

94

Emissions Benefits From Renewable Fuels and Other Alternatives for Heavy-Duty Vehicles  

E-Print Network [OSTI]

Effects of Methyl Ester Biodiesel Blends on NOx Emissions.Increase When Burning Biodiesel; A New (Old) Theory. FuelE. ; Natarajan, M. Effects of Biodiesel Fuels Upon Criteria

Hajbabaei, Maryam

2013-01-01T23:59:59.000Z

95

Costilla County Biodiesel Pilot Project  

SciTech Connect (OSTI)

The Costilla County Biodiesel Pilot Project has demonstrated the compatibility of biodiesel technology and economics on a local scale. The project has been committed to making homegrown biodiesel a viable form of community economic development. The project has benefited by reducing risks by building the facility gradually and avoiding large initial outlays of money for facilities and technologies. A primary advantage of this type of community-scale biodiesel production is that it allows for a relatively independent, local solution to fuel production. Successfully using locally sourced feedstocks and putting the fuel into local use emphasizes the feasibility of different business models under the biodiesel tent and that there is more than just a one size fits all template for successful biodiesel production.

Doon, Ben; Quintana, Dan

2011-08-25T23:59:59.000Z

96

DPF Performance with Biodiesel Blends  

Broader source: Energy.gov (indexed) [DOE]

DPF Performance with Biodiesel Blends Aaron Williams, Bob McCormick, Bob Hayes, John Ireland National Renewable Energy Laboratory Howard L. Fang Cummins, Inc. Diesel Engine...

97

Alternative Fuel Tool Kit How to Implement: Biodiesel  

E-Print Network [OSTI]

1 8/18/2014 Alternative Fuel Tool Kit How to Implement: Biodiesel Contents Introduction to Biodiesel......................................................................................................................................................2 Biodiesel Availability in North Carolina

98

Quality, Stability, Performance, and Emission Impacts of Biodiesel...  

Broader source: Energy.gov (indexed) [DOE]

already exceeds 5% of the on-highway diesel market Biodiesel also reduces greenhouse gas emissions relative to petroleum 3 Barriers 1. Biodiesel quality: Some biodiesel...

99

E85 and Biodiesel Deployment (Presentation)  

SciTech Connect (OSTI)

Presentation outlines industry trends and statistics revolving around the use and production of ethanol and biodiesel.

Harrow, G.

2007-09-18T23:59:59.000Z

100

Monthly Biodiesel Production Report  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecember 2005 (Thousand9,0,InformationU.S. Crude Oil3 13,,8.1 64.1Biodiesel

Note: This page contains sample records for the topic "methyl esters biodiesel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Monthly Biodiesel Production Report  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecember 2005 (Thousand9,0,InformationU.S. Crude Oil3 13,,8.1Biodiesel producers and

102

Monthly Biodiesel Production Report  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecember 2005 (Thousand9,0,InformationU.S. Crude Oil3 13,,8.1Biodiesel producers

103

Experimental Investigation of Biodiesel Production from Waste Mustard Oil  

E-Print Network [OSTI]

economy. The two most common types of biofuels are ethanol and biodiesel [1]. Biodiesel is a promising

Rajat Subhra Samanta; Mukunda Kumar Das

104

ALKALI CATALYSED PRODUCTION OF BIODIESEL FUEL FROM NIGERIAN CITRUS SEEDS OIL  

E-Print Network [OSTI]

The potential of oil extracted from the seeds of three different Nigerian citrus fruits for biodiesel production was investigated. Fatty acid alkyl esters were produced from orange seed oil, grape seed oil and tangerine seed oil by transesterification of the oils with ethanol using potassium hydroxide as a catalyst. In the conversion of the citrus seed oils to alkyl esters (biodiesel), the grape seed oil gave the highest yield of 90.6%, while the tangerine seed oil and orange seed oil gave a yield of 83.1 % and 78.5%, respectively. Fuel properties of the seed oil and its biodiesel were determined. The results showed that orange seed oil had a density of 730 Kg/m 3, a viscosity of 36.5 mm 2 /s, and a pour point of- 14 o C; while its biodiesel fuel had a density of 892 Kg/m 3, a viscosity of 5.60 mm 2 /s, and a pour point of- 25 o C. Grape seed oil had a density of 675 Kg/m 3, a viscosity of 39.5 mm 2 /s, and a pour point of- 12 o C, while its biodiesel fuel had a density of 890 Kg/m 3, a viscosity of 4.80 mm 2 /s, and a pour point of- 22 o C. Tangerine seed oil had an acid value of 1.40 mg/g, a density of 568 Kg/m 3, a viscosity of 37.3 mm 2 /s, and a pour point of- 15 o C, while its biodiesel fuel had an acid value of 0.22 mg/g, a density of 895 Kg/m 3, a viscosity of 5.30 mm 2 /s, and a pour point of- 24 o C.

unknown authors

105

Stability of Biodiesel and Biodiesel Blends: Interim Report  

SciTech Connect (OSTI)

This is an interim report for a study of biodiesel oxidative stability. It describes characterization and accelerated stability test results for 19 B100 samples and six diesel fuels.

McCormick, R. L.; Alleman, T. L.; Waynick, J. A.; Westbrook, S. R.; Porter, S.

2006-04-01T23:59:59.000Z

106

E-Print Network 3.0 - alcohol aldehyde esters Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

5087-5090,1988 0040-403988 3.00 + .oO Printed in Great Britain Pergamon Press plc Summary: been shown to convert aldehydes to methyl esters, whereas secondary alcohols...

107

Biodiesel: Cost and reactant comparison 1 Biodiesel: Cost and reactant comparison  

E-Print Network [OSTI]

Biodiesel: Cost and reactant comparison 1 Biodiesel: Cost and reactant comparison Burke Anderson-2008 Abstract: Alternative fuel resources such as biodiesel are important to combat fossil fuel use reduction. Biodiesel is made through a process of transesterification that can be preformed in a variety

108

Global Biodiesel Market Trends,Global Biodiesel Market Trends, Outlook and OpportunitiesOutlook and Opportunities  

E-Print Network [OSTI]

Global Biodiesel Market Trends,Global Biodiesel Market Trends, Outlook and OpportunitiesPresident, Emerging Markets Online http://www.emerginghttp://www.emerging--markets.commarkets.com Author, Biodiesel 2020: A Global Market SurveyAuthor, Biodiesel 2020: A Global Market Survey Columnist

109

A numerical study comparing the combustion and emission characteristics of biodiesel with petrodiesel.  

SciTech Connect (OSTI)

Combustion and emission characteristics of compression ignition engines strongly depend upon inner-nozzle flow and spray behavior. These processes control the fuel-air mixing, which in turn is critical for the combustion process. Previous studies by us highlighted the differences in the physical and chemical properties of petrodiesel and biodiesel, which significantly altered the inner-nozzle flow and spray structure. The current study is another step in this direction to gain a fundamental understanding on the influence of fuel properties on the combustion and emission characteristics of the compression ignition engine. n-Heptane and methyl butanoate were selected as surrogates for diesel and biodiesel fuels, respectively, because the chemical kinetic pathways were well-understood. Liquid length and flame lift-off length for diesel and biodiesel fuels were validated against data available in the literature. Liquid lengths were always higher for biodiesel because of its higher heat of vaporization, which resulted in increased interplay between spray and combustion processes under all conditions investigated. Ambient air entrainment was also lower for biodiesel mainly because of slower atomization and breakup. The mechanism for flame stabilization is further analyzed by estimating the turbulent burning velocity for both of the fuels. This analysis revealed that neither flame propagation nor isolated ignition kernels upstream and detached from high-temperature regions can be the mechanism for flame stabilization. Flame propagation speeds were observed to be similar for both fuels. Biodiesel predicted lower soot concentrations, which were also reflected in reduced C{sub 2}H{sub 2} mole fractions. Although prompt NO{sub x} was higher for biodiesel, total NO{sub x} was lower because of reduced thermal NO{sub x}. The ignition delay and NO{sub x} emissions predicted by these simulations do not agree with trends reported in the literature; hence, this study highlights the need for better fuel surrogates for diesel and biodiesel fuels.

Som, S.; Longman, D. (Energy Systems)

2011-04-01T23:59:59.000Z

110

EFFECTS OF BIODIESEL BLENDING ON EXHAUST EMISSIONS  

E-Print Network [OSTI]

Rising fuel costs and energy demands, combined with growing concern over health related and environmental concerns, have led to increased interest in the use of biodiesel. Biodiesel can be utilized as a direct replacement ...

Guo, Jing

2011-08-31T23:59:59.000Z

111

Biodiesel Production and Blending Tax Credit (Kentucky)  

Broader source: Energy.gov [DOE]

blended biodiesel does not qualify. The biodiesel tax credit is applied against the corporation income tax imposed under KRS 141.040 and/or the limited liability entity tax (LLET) imposed under KRS...

112

Biodiesel is Working Hard in Kentucky  

SciTech Connect (OSTI)

This 4-page Clean Cities fact sheet describes the use of biodiesel fuel in 6 school districts throughout Kentucky. It contains usage information for each school district, as well as contact information for local Clean Cities Coordinators and Biodiesel suppliers.

Not Available

2004-04-01T23:59:59.000Z

113

Biodiesel Engine Testing MECH-457 Final Report  

E-Print Network [OSTI]

Biodiesel Engine Testing MECH-457 Final Report Submitted to Jon Mikkelsen April 11, 2005 Darren at UBC has begun producing biodiesel fuel from waste cooking oils acquired from campus kitchens. Using biodiesel in a four-cylinder, 30 hp Kubota engine (V1305). This engine was chosen because it is used

114

World Biodiesel Markets The Outlook to 2010  

E-Print Network [OSTI]

World Biodiesel Markets The Outlook to 2010 A special study from F.O. Licht and Agra CEAS This important new study provides a detailed analysis of the global biodiesel market and the outlook for growth, including the regulatory and trade framework, feedstock supply and price developments, biodiesel production

115

TESC Farmhouse Biodiesel Project Processor Manual  

E-Print Network [OSTI]

1 TESC Farmhouse Biodiesel Project Processor Manual #12;2 Thank you (in no particular order) to: David Rack, Sam Stout, and Kolby Bray-Hoagland for starting the Evergreen Biodiesel Project; our faculty Sara Keehfuss, Burke Anderson, Brodie Pettit (the Biodiesel Buccaneers) and Andrew York

116

Development and Validation of a Reduced Reaction Mechanism for Biodiesel-Fueled Engine Simulations- SAE 2008-01-1378  

SciTech Connect (OSTI)

In the present study a skeletal chemical reaction mechanism for biodiesel surrogate fuel was developed and validated for multi-dimensional engine combustion simulations. The reduced mechanism was generated from an existing detailed methyl butanoate oxidation mechanism containing 264 species and 1219 reactions. The reduction process included flux analysis, ignition sensitivity analysis, and optimization of reaction rate constants under constant volume conditions. The current reduced mechanism consists of 41 species and 150 reactions and gives predictions in excellent agreement with those of the comprehensive mechanism. In order to validate the mechanism under biodiesel-fueled engine conditions, it was combined with another skeletal mechanism for n-heptane oxidation. This combined reaction mechanism, ERC-Bio, contains 53 species and 156 reactions, which can be used for diesel/biodiesel blend engine simulations. Biodiesel-fueled engine operation was successfully simulated using the ERC-Bio mechanism.

Brakora, Jessica L [ORNL; Ra, Youngchul [ORNL; Reitz, Rolf [University of Wisconsin; McFarlane, Joanna [ORNL; Daw, C Stuart [ORNL

2008-01-01T23:59:59.000Z

117

International Journal of Mechanical & Mechatronics IJMME-IJENS Vol: 10 No: 03 1 BIODIESEL FROM JATROPHA OIL AS AN ALTERNATIVE FUEL FOR DIESEL ENGINE  

E-Print Network [OSTI]

AbstractThe world is getting modernized and industrialized day by day. As a result vehicles and engines are increasing. But energy sources used in these engines are limited and decreasing gradually. This situation leads to seek an alternative fuel for diesel engine. Biodiesel is an alternative fuel for diesel engine. The esters of vegetables oil animal fats are known as Biodiesel. This paper investigates the prospect of making of biodiesel from jatropha oil. Jatropha curcas is a renewable non-edible plant. Jatropha is a wildly growing hardy plant in arid and semi-arid regions of the country on degraded soils having low fertility and moisture. The seeds of Jatropha contain 50-60 % oil. In this study the oil has been converted to biodiesel by the well-known transesterification process and used it to diesel engine for performance evaluation.

Kazi Mostafijur Rahman; Mohammad Mashud; Md. Roknuzzaman; Asadullah Al Galib

118

www.mdpi.com/journal/ijms Physical Properties of Normal Grade Biodiesel and Winter Grade Biodiesel  

E-Print Network [OSTI]

Abstract: In this study, optical and thermal properties of normal grade and winter grade palm oil biodiesel were investigated. Surface Plasmon Resonance and Photopyroelectric technique were used to evaluate the samples. The dispersion curve and thermal diffusivity were obtained. Consequently, the variation of refractive index, as a function of wavelength in normal grade biodiesel is faster than winter grade palm oil biodiesel, and the thermal diffusivity of winter grade biodiesel is higher than the thermal diffusivity of normal grade biodiesel. This is attributed to the higher palmitic acid C16:0 content in normal grade than in winter grade palm oil biodiesel.

Amir Reza Sadrolhosseini; Mohd Maarof Moksin; Harrison Lau; Lik Nang; Monir Norozi; W. Mahmood; Mat Yunus; Azmi Zakaria

2011-01-01T23:59:59.000Z

119

ao diesel mineral: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

feasibility of karanja seed oilby modified the fuel using karanja methyl ester(biodiesel)blends withmineral diesel. This experimentation evaluatethe performance and emission...

120

administered diesel exhaust: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Injection Diesel Engine Using Pongamia Oil CiteSeer Summary: Abstract The use of biodiesel, the methyl esters of vegetable oils are becoming popular due to their low...

Note: This page contains sample records for the topic "methyl esters biodiesel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Upcoming Events Upcoming Biodiesel Events  

E-Print Network [OSTI]

- 29, 2010 Coronada Rockford, IL www.ibed2010.com/ Bioenergy Markets Turkey Green Power Conferences.eng.iastate.edu/ Biodiesel Congress F.O. Lichts September 22-24, 2010 Mercure Grant Hotel Sao Paulo, Brazil www.agra-net.com/content/agra/ips/pdf/Marketing www.opisnet.com/fleetfueling/index.html International Bioenergy Days NIU and Rockford, IL September 26

122

Optimum Requirements for the Synthesis of Biodiesel Using Fatty Acid Distillates  

E-Print Network [OSTI]

The optimum requirements of temperature, retention time, mole ratio of reactants and catalyst for the direct synthesis of biodiesel from fatty acid distillates of palm kernel oil using tetraoxosulphate (VI) acid as catalyst was studied. The following parameters were used for the efficient and economic production of biodiesel: eight (8) moles of methanol per mole of fatty acid, 0.06 mole of tetraoxosulphate (VI) acid per mole of fatty acid, a retention time of sixty (60) minutes and reaction temperature of 65 OC. And this gave a maximum percentage yield of 98.4. Other parameters obtained include: an acid value of 0.1683 mg KOH/g, iodine value of 15.3549, flash point of 209 OC, viscosity of 3.7957 mm2s-1, density of 0.8776 g cm-3, water content of 400.05 mg kg-1, soap content of 2.30 mg/kg, and ester content of 98.804 %. From the obtained parameters, the biodiesel produced from fatty acid distillates of palm kernel oil reaches prescribed international standards for biodiesel production.

Akunna E. Ejele

123

Impact of Biodiesel on Ash Emissions and Lubricant Properties...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Biodiesel on Ash Emissions and Lubricant Properties Affecting Fuel Economy and Engine Wear Impact of Biodiesel on Ash Emissions and Lubricant Properties Affecting Fuel Economy and...

124

Effect of Jatropha based Biodiesel, on Engine Hardware Reliability...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Jatropha based Biodiesel, on Engine Hardware Reliability, Emission and Performance Effect of Jatropha based Biodiesel, on Engine Hardware Reliability, Emission and Performance...

125

Quality, Stability, Performance, and Emission Impacts of Biodiesel...  

Broader source: Energy.gov (indexed) [DOE]

Quality, Stability, Performance, and Emission Impacts of Biodiesel Blends Quality, Stability, Performance, and Emission Impacts of Biodiesel Blends Presentation from the U.S. DOE...

126

Impacts of Rail Pressure and Biodiesel Composition on Soot Nanostructu...  

Broader source: Energy.gov (indexed) [DOE]

Impacts of Rail Pressure and Biodiesel Composition on Soot Nanostructure Impacts of Rail Pressure and Biodiesel Composition on Soot Nanostructure Fractal dimensions of particle...

127

Emission Performance of Modern Diesel Engines Fueled with Biodiesel...  

Broader source: Energy.gov (indexed) [DOE]

Emission Performance of Modern Diesel Engines Fueled with Biodiesel Emission Performance of Modern Diesel Engines Fueled with Biodiesel This study presents full quantification of...

128

Biodiesel Effects on Diesel Particle Filter Performance: Milestone Report  

SciTech Connect (OSTI)

Research results on the performance of biodiesel and biodiesel blends with ultra-low sulfur diesel (ULSD) and a diesel particle filter (DPF).

Williams, A.; McCormick, R. L.; Hayes, R.; Ireland, J.

2006-03-01T23:59:59.000Z

129

Enterprise converting buses to biodiesel | Department of Energy  

Energy Savers [EERE]

Enterprise converting buses to biodiesel Enterprise converting buses to biodiesel April 1, 2010 - 6:48pm Addthis Paul Lester Communications Specialist, Office of Energy Efficiency...

130

Impact of Biodiesel Metals on the Performance and Durability...  

Broader source: Energy.gov (indexed) [DOE]

Impact of Biodiesel Metals on the Performance and Durability of DOC and DPF Technologies Impact of Biodiesel Metals on the Performance and Durability of DOC and DPF Technologies...

131

Evaluation of Biodiesel Fuels from Supercritical Fluid Processing...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Biodiesel Fuels from Supercritical Fluid Processing with the Advanced Distillation Curve Method Evaluation of Biodiesel Fuels from Supercritical Fluid Processing with the Advanced...

132

Development and Validation of a Reduced Mechanism for Biodiesel...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Validation of a Reduced Mechanism for Biodiesel Surrogates for Compression Ignition Engine Applications Development and Validation of a Reduced Mechanism for Biodiesel Surrogates...

133

Effects of Fuel Dilution with Biodiesel on Lubricant Acidity...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Effects of Fuel Dilution with Biodiesel on Lubricant Acidity, Oxidation and Corrosion Effects of Fuel Dilution with Biodiesel on Lubricant Acidity, Oxidation and Corrosion...

134

Profitable Biodiesel Potential from Increased Agricultural Yields Country Name  

E-Print Network [OSTI]

Profitable Biodiesel Potential from Increased Agricultural Yields Country Name Production Cost ($/liter) Potential Biodiesel Volume (liters) Total Export Profits ($) HDI Rank GDP/ cap Corrupt Rank FDI

Wisconsin at Madison, University of

135

Survey of the Quality and Stability of Biodiesel and Biodiesel Blends in the United States in 2004  

SciTech Connect (OSTI)

Reports results gathered in 2004 from quality and stability surveys in the United States of biodiesel (B100) and 20% biodiesel (B20) in petroleum diesel.

McCormick, R. L.; Alleman, T. L.; Ratcliffe, M.; Moens, L.; Lawrence, R.

2005-10-01T23:59:59.000Z

136

Impacts of Biodiesel on Emission Control Devices  

Broader source: Energy.gov (indexed) [DOE]

Biodiesel on Emission Control Devices Todd J. Toops and Bruce G. Bunting Oak Ridge National Laboratory D. William Brookshear and Ke Nguyen University of Tennessee - Knoxville DEER...

137

Biodiesel Impact on Engine Lubricant Oil Dilution  

Broader source: Energy.gov (indexed) [DOE]

Efficiency and Renewable Energy operated by the Alliance for Sustainable Energy, LLC Biodiesel Impact on Engine Lubricant Oil Dilution Motivation * Modern diesel engines utilize...

138

Biodiesel's Enabling Characteristics in Attaining Low Temperature...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Combustion Discusses reasons and physical significance of cool-flame behavior of biodiesel on improving low temperature diesel combustion deer11jacobs.pdf More Documents &...

139

WSF Biodiesel Demonstration Project Final Report  

SciTech Connect (OSTI)

In 2004, WSF canceled a biodiesel fuel test because of product quality issues that caused the fuel purifiers to clog. The cancelation of this test and the poor results negatively impacted the use of biodiesel in marine application in the Pacific Northwest. In 2006, The U.S. Department of Energy awarded the Puget Sound Clean Air Agency a grant to manage a scientific study investigating appropriate fuel specifications for biodiesel, fuel handling procedures and to conduct a fuel test using biodiesel fuels in WSF operations. The Agency put together a project team comprised of experts in fields of biodiesel research and analysis, biodiesel production, marine engineering and WSF personnel. The team reviewed biodiesel technical papers, reviewed the 2004 fuel test results, designed a fuel test plan and provided technical assistance during the test. The research reviewed the available information on the 2004 fuel test and conducted mock laboratory experiments, but was not able to determine why the fuel filters clogged. The team then conducted a literature review and designed a fuel test plan. The team implemented a controlled introduction of biodiesel fuels to the test vessels while monitoring the environmental conditions on the vessels and checking fuel quality throughout the fuel distribution system. The fuel test was conducted on the same three vessels that participated in the canceled 2004 test using the same ferry routes. Each vessel used biodiesel produced from a different feedstock (i.e. soy, canola and yellow grease). The vessels all ran on ultra low sulfur diesel blended with biodiesel. The percentage of biodiesel was incrementally raised form from 5 to 20 percent. Once the vessels reached the 20 percent level, they continued at this blend ratio for the remainder of the test. Fuel samples were taken from the fuel manufacturer, during fueling operations and at several points onboard each vessel. WSF Engineers monitored the performance of the fuel systems and engines. Each test vessel did experience a microbial growth bloom that produced a build up of material in the fuel purifiers similar to material witnessed in the 2004 fuel test. A biocide was added with each fuel shipment and the problem subsided. In January of 2009, the WSF successfully completed an eleven month biodiesel fuel test using approximately 1,395,000 gallons of biodiesel blended fuels. The project demonstrated that biodiesel can be used successfully in marine vessels and that current ASTM specifications are satisfactory for marine vessels. Microbial growth in biodiesel diesel interface should be monitored. An inspection of the engines showed no signs of being negatively impacted by the test.

Washington State University; University of Idaho; The Glosten Associates, Inc.; Imperium Renewables, Inc.

2009-04-30T23:59:59.000Z

140

Composition of the wax fraction of bitumen from methylated brown coals  

SciTech Connect (OSTI)

Changes in the group and individual compositions of the wax fractions of bitumen in the course of brown coal methylation were studied. With the use of IR and NMR spectroscopy and chromatography-mass spectrometry, it was found that the esters of methylated coal waxes consisted of the native esters of fatty acids and the methyl esters of these acids formed as a result of an alkylation treatment. Esterification and transesterification were predominant among the reactions of aliphatic fraction components. A positive effect of methanol alkylation on an increase in the yield of the aliphatic fractions was found.

S.I. Zherebtsov; A.I. Moiseev [Russian Academy of Sciences, Kemerovo (Russian Federation). Institute of Coal and Coal Chemistry

2009-04-15T23:59:59.000Z

Note: This page contains sample records for the topic "methyl esters biodiesel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Dieselzymes: development of a stable and methanol tolerant lipase for biodiesel production by directed evolution  

E-Print Network [OSTI]

J, Campelo JM, Romero AA: Biodiesel as feasible petrol fueltowards ever greener biodiesel production. Biotechnol Adv 3.T, Bielecki S: Enzymatic biodiesel synthesis - key factors

Korman, Tyler P; Sahachartsiri, Bobby; Charbonneau, David M; Huang, Grace L; Beauregard, Marc; Bowie, James U

2013-01-01T23:59:59.000Z

142

Production and Application of Biodiesel A Case Study  

E-Print Network [OSTI]

petroleum products is biodiesel for many reasons, mainly increasing demand and scarcity of petroleum

unknown authors

143

Emerging Scope for Biodiesel for Energy Security and Environmental Protection  

E-Print Network [OSTI]

currently the preferred process for biodiesel production. India, continue to have shortage of petroleum

Sukhwinder Singh; Dr. S K Mahla

144

Transactions of the ASABE Vol. 50(1): 161-165 E 2007 American Society of Agricultural and Biological Engineers ISSN 0001-2351 161  

E-Print Network [OSTI]

and Biological Engineers ISSN 0001-2351 161 BIODIESEL PRODUCTION USING STATIC MIXERS J. C. Thompson, B. B. He production. Biodiesel (canola methyl ester) was produced under varying conditions using a closed-loop static for biodiesel quality control. It was found that static mixers can be used for biodiesel production. In fact

He, Brian

145

ORNL 2010-G00953/jcn UT-B IDs 200702012, 200701972  

E-Print Network [OSTI]

by ORNL researchers. This method is specifically applicable to the production of biodiesel through and then separate products and by-products. Multiple devices may be used to purify the biodiesel product ·· Biodiesel production ·· Synthesis of methyl esters ·· Separation of biodiesel from immiscible glycerol by-products

146

Syntheses of 11 F-labeled carboxylic esters within a  

E-Print Network [OSTI]

and with reduced infusion rate. Radioactive methyl ester 4b was obtained from the reaction of 1 (10 mM) with 2b in 56% decay-corrected radiochemical yield (RCY) at an infusion rate of 10 mL min21 , and when the infusion rate was reduced to 1 mL min21 , the RCY increased to 88%. The synthesis of the non

Shen, Jun

147

A computational investigation of diesel and biodiesel combustion and NOx formation in a light-duty compression ignition engine  

SciTech Connect (OSTI)

Diesel and biodiesel combustion in a multi-cylinder light duty diesel engine were simulated during a closed cycle (from IVC to EVO), using a commercial computational fluid dynamics (CFD) code, CONVERGE, coupled with detailed chemical kinetics. The computational domain was constructed based on engine geometry and compression ratio measurements. A skeletal n-heptane-based diesel mechanism developed by researchers at Chalmers University of Technology and a reduced biodiesel mechanism derived and validated by Luo and co-workers were applied to model the combustion chemistry. The biodiesel mechanism contains 89 species and 364 reactions and uses methyl decanoate, methyl-9- decenoate, and n-heptane as the surrogate fuel mixture. The Kelvin-Helmholtz and Rayleigh-Taylor (KH-RT) spray breakup model for diesel and biodiesel was calibrated to account for the differences in physical properties of the fuels which result in variations in atomization and spray development characteristics. The simulations were able to capture the experimentally observed pressure and apparent heat release rate trends for both the fuels over a range of engine loads (BMEPs from 2.5 to 10 bar) and fuel injection timings (from 0???° BTDC to 10???° BTDC), thus validating the overall modeling approach as well as the chemical kinetic models of diesel and biodiesel surrogates. Moreover, quantitative NOx predictions for diesel combustion and qualitative NOx predictions for biodiesel combustion were obtained with the CFD simulations and the in-cylinder temperature trends were correlated to the NOx trends."

Wang, Zihan; Srinivasan, Kalyan K.; Krishnan, Sundar R.; Som, Sibendu

2012-04-24T23:59:59.000Z

148

Method of making alkyl esters  

DOE Patents [OSTI]

Methods of making alkyl esters are described herein. The methods are capable of using raw, unprocessed, low-cost feedstocks and waste grease. Generally, the method involves converting a glyceride source to a fatty acid composition and esterifying the fatty acid composition to make alkyl esters. In an embodiment, a method of making alkyl esters comprises providing a glyceride source. The method further comprises converting the glyceride source to a fatty acid composition comprising free fatty acids and less than about 1% glyceride by mass. Moreover, the method comprises esterifying the fatty acid composition in the presence of a solid acid catalyst at a temperature ranging firm about 70.degree. C. to about 120.degree. C. to produce alkyl esters, such that at least 85% of the free fatty acids are converted to alkyl esters. The method also incorporates the use of packed bed reactors for glyceride conversion and/or fatty acid esterification to make alkyl esters.

Elliott, Brian (Wheat Ridge, CO)

2010-09-14T23:59:59.000Z

149

Alternative Fuels Data Center: Biodiesel  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation InInformationCenterResearch Highlights MediaFuelAbout UsAdvisoryUpcoming16,199Biodiesel

150

Better Biodiesel | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin: Energy ResourcesJersey: EnergyBerthoud,Biodiesel Place: Orem, Utah Zip: 84057

151

Taua Biodiesel | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia:FAQ < RAPID Jump to:Seadov Pty LtdSteen,Ltd Jump to:Taos County, New Mexico: EnergyTargetJumpTaua Biodiesel

152

Empirical Study of the Stability of Biodiesel and Biodiesel Blends: Milestone Report  

SciTech Connect (OSTI)

The objective of this work was to develop a database that supports specific proposals for a stability test and specification for biodiesel and biodiesel blends. B100 samples from 19 biodiesel producers were obtained in December of 2005 and January of 2006 and tested for stability. Eight of these samples were then selected for additional study, including long-term storage tests and blending at 5% and 20% with a number of ultra-low sulfur diesel fuels.

McCormick, R. L.; Westbrook, S. R.

2007-05-01T23:59:59.000Z

153

Biodiesel and Other Renewable Diesel Fuels  

SciTech Connect (OSTI)

Present federal tax incentives apply to certain types of biomass-derived diesel fuels, which in energy policy and tax laws are described either as renewable diesel or biodiesel. To understand the distinctions between these diesel types it is necessary to understand the technologies used to produce them and the properties of the resulting products. This fact sheet contains definitions of renewable and biodiesel and discusses the processes used to convert biomass to diesel fuel and the properties of biodiesel and renewable diesel fuels.

Not Available

2006-11-01T23:59:59.000Z

154

Comparison of Simulated and Experimental Combustion of Biodiesel Blends in a Single Cylinder Diesel HCCI Engine  

SciTech Connect (OSTI)

The effect of biodiesel content on homogeneous charge compression ignition (HCCI) engine performance has been investigated both experimentally and by computer simulation. Combustion experiments were performed in a single cylinder HCCI engine using blends of soy biodiesel in ultra low sulfur diesel, with concentrations ranging from 0 to 50 vol% and equivalence ratios ( ) from 0.38 to 0.48. Data from the engine tests included combustion analysis and exhaust composition analysis with standard gaseous emissions equipment. The engine utilized a custom port fuel injection strategy to provide highly premixed charges of fuel and air, making it possible to compare the results with single zone chemical kinetics simulations that were performed using CHEMKIN III, with a reaction set including 670 species and over 3000 reactions. The reaction mechanism incorporated equations for the combustion of a paraffinic fuel, n-heptane, and an oxygenated component, methyl butanoate, as well as reactions for the formation of NOx. The zero-dimensional model did a reasonably good job of predicting the HCCI combustion event, correctly predicting intake temperature effects on the phasing of both low temperature heat release (LTHR) and the main combustion event. It also did a good job of predicting the magnitude of LTHR. Differences between the simulation and experimental data included the dependence on biodiesel concentration and the duration of both LTHR and the main combustion event. The probable reasons for these differences are the changing derived cetane number (DCN) of the model fuel blend with biodiesel concentration, and the inability of the model to account for stratification of temperature and . The simulation also showed that concentrations of intermediate species produced during LTHR are dependent on the magnitude of LTHR, but otherwise the addition of biodiesel has no discernable effect.

Szybist, James P [ORNL; McFarlane, Joanna [ORNL; Bunting, Bruce G [ORNL

2007-01-01T23:59:59.000Z

155

Biodiesel ASTM Update and Future Technical Needs  

Broader source: Energy.gov (indexed) [DOE]

ASTM Update and Future Technical Needs Steve Howell Technical Director National Biodiesel Board ASTM Current Status ASTM D6751 is the approved standard for B100 for blending up to...

156

BIODIESEL BLENDS IN SPACE HEATING EQUIPMENT.  

SciTech Connect (OSTI)

Biodiesel is a diesel-like fuel that is derived from processing vegetable oils from various sources, such as soy oil, rapeseed or canola oil, and also waste vegetable oils resulting from cooking use. Brookhaven National laboratory initiated an evaluation of the performance of blends of biodiesel and home heating oil in space heating applications under the sponsorship of the Department of Energy (DOE) through the National Renewable Energy Laboratory (NREL). This report is a result of this work performed in the laboratory. A number of blends of varying amounts of a biodiesel in home heating fuel were tested in both a residential heating system and a commercial size boiler. The results demonstrate that blends of biodiesel and heating oil can be used with few or no modifications to the equipment or operating practices in space heating. The results also showed that there were environmental benefits from the biodiesel addition in terms of reductions in smoke and in Nitrogen Oxides (NOx). The latter result was particularly surprising and of course welcome, in view of the previous results in diesel engines where no changes had been seen. Residential size combustion equipment is presently not subject to NOx regulation. If reductions in NOx similar to those observed here hold up in larger size (commercial and industrial) boilers, a significant increase in the use of biodiesel-like fuel blends could become possible.

KRISHNA,C.R.

2001-12-01T23:59:59.000Z

157

Physical properties of bio-diesel & Implications for use of bio-diesel in diesel engines  

SciTech Connect (OSTI)

In this study we identify components of a typical biodiesel fuel and estimate both their individual and mixed thermo-physical and transport properties. We then use the estimated mixture properties in computational simulations to gauge the extent to which combustion is modified when biodiesel is substituted for conventional diesel fuel. Our simulation studies included both regular diesel combustion (DI) and premixed charge compression ignition (PCCI). Preliminary results indicate that biodiesel ignition is significantly delayed due to slower liquid evaporation, with the effects being more pronounced for DI than PCCI. The lower vapor pressure and higher liquid heat capacity of biodiesel are two key contributors to this slower rate of evaporation. Other physical properties are more similar between the two fuels, and their impacts are not clearly evident in the present study. Future studies of diesel combustion sensitivity to both physical and chemical properties of biodiesel are suggested.

Chakravarthy, Veerathu K [ORNL; McFarlane, Joanna [ORNL; Daw, C Stuart [ORNL; Ra, Youngchul [ORNL; Griffin, Jelani K [ORNL; Reitz, Rolf [University of Wisconsin

2008-01-01T23:59:59.000Z

158

BioDiesel Content On-board monitoring  

Broader source: Energy.gov (indexed) [DOE]

2008 - all rights reserved 1 (tm) BioDiesel Content On-board monitoring BioDiesel Content On-board monitoring August 6th, 2008 Copyright SP3H 2007 -- all rights reserved 2 Biofuel...

159

Impact of Biodiesel Metals on the Performance and Durability...  

Broader source: Energy.gov (indexed) [DOE]

accelerated test method to expose diesel catalysts - 8 DOCs, 8 DPFs and 4 SCRs * Biodiesel ash did not adversely impact the back pressure of a DPF * Biodiesel ash caused...

160

Impact of Biodiesel on Fuel System Component Durability  

SciTech Connect (OSTI)

A study of the effects of biodiesel blends on fuel system components and the physical characteristics of elastomer materials.

Terry, B.

2005-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "methyl esters biodiesel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Commentary Biodiesel Exhaust: The Need for Health Effects Research  

E-Print Network [OSTI]

Jobs Creation Bill HR 4520 marked an important turning point for the future production of biodiesel in

Kimberly J. Swanson; Michael C. Madden; Andrew J. Ghio

2007-01-01T23:59:59.000Z

162

Controls and Measurements of KU Engine Test Cells for Biodiesel, SynGas, and Assisted Biodiesel Combustion  

E-Print Network [OSTI]

the following: University of Kansas's Feedstock-to-Tailpipe Initiative's Synthesis Gas Reforming rig, Feedstock-to-Tailpipe Initiative's Biodiesel Single Cylinder Test Stand, and a unique Reformate Assisted Biodiesel Combustion architecture. The main...

Cecrle, Eric Daniel

2011-04-06T23:59:59.000Z

163

Project Recap Humanitarian Engineering Biodiesel Boiler System for Steam Generator  

E-Print Network [OSTI]

Project Recap Humanitarian Engineering ­ Biodiesel Boiler System for Steam Generator Currently 70 biodiesel boiler system to drive a steam engine generator. This system is to provide electricity the customer needs, a boiler fueled by biodiesel and outputting to a steam engine was decided upon. The system

Demirel, Melik C.

164

Beyond Biodiesel Running on Straight Vegetable Oil (SVO)  

E-Print Network [OSTI]

20 Beyond Biodiesel ­ Running on Straight Vegetable Oil (SVO) The green tree has many branches in the development and promotion of biodiesel for nearly two decades. Technologies based on the use of hydrogen in a low-percentage mixture with petroleum fuel. Hence the development of biodiesel. Paul Trella, New

Kaye, Jason P.

165

Oxidative Reforming of Biodiesel Over Molybdenum (IV) Oxide  

E-Print Network [OSTI]

Oxidative Reforming of Biodiesel Over Molybdenum (IV) Oxide Jessica Whalen, Oscar Marin Flores, Su University INTRODUCTION Energy consumption continues to skyrocket worldwide. Biodiesel is a renewable fuel as potential feedstock in solid oxide fuel cells. Petroleum based fuels become scarcer daily, and biodiesel

Collins, Gary S.

166

A First Law Thermodynamic Analysis of Biodiesel Production From Soybean  

E-Print Network [OSTI]

A First Law Thermodynamic Analysis of Biodiesel Production From Soybean Tad W. Patzek Department@mail.utexas.edu April 13, 2009 Abstract A proper First Law energy balance of the soybean biodiesel cycle shows that the overall efficiency of biodiesel production is 0.18, i.e., only 1 in 5 parts of the solar energy

Patzek, Tadeusz W.

167

THE UNIVERSITY OF BRITISH COLUMBIA Biodiesel Engine Compatibility Study  

E-Print Network [OSTI]

THE UNIVERSITY OF BRITISH COLUMBIA MECH 456 Biodiesel Engine Compatibility Study Submitted to: Dr 456 Biodiesel Engine Compatibility Study i Executive Summary The objectives of this project were to show the effects of varying U.B.C. biodiesel content in fuel on engine performance, to observe

168

www.postersession.com Performance Analysis of Cottonseed Biodiesel  

E-Print Network [OSTI]

printed by www.postersession.com Performance Analysis of Cottonseed Biodiesel Sherwin Davoud1. Making biodiesel from crude cottonseed oil is difficult because transesterification doesn't take place Administration. (2007). Federal and State Ethanol and Biodiesel Requirements. Retrieved from http

Hutcheon, James M.

169

Optimal biodiesel production using bioethanol: Towards process integration.  

E-Print Network [OSTI]

Optimal biodiesel production using bioethanol: Towards process integration. Kristen Severson Ave. Pittsburgh PA 15213 Abstract. In this paper we optimize the production of biodiesel to recover the ethanol, separate the polar and non polar phases and purify the glycerol and biodiesel

Grossmann, Ignacio E.

170

Optimization and heat and water integration for biodiesel production  

E-Print Network [OSTI]

1 Optimization and heat and water integration for biodiesel production from cooking oil generation of biodiesel using waste cooking oil and algae oil. We consider 5 different technologies is to simultaneously optimize and heat integrate the production of biodiesel from each of the different oil sources

Grossmann, Ignacio E.

171

Reachability Analysis of Stochastic Hybrid Systems: A Biodiesel Production System  

E-Print Network [OSTI]

Reachability Analysis of Stochastic Hybrid Systems: A Biodiesel Production System Derek Riley problem because it provides a formal framework to analyze complex systems. Biodiesel production is a realistic biochemical process that can be modeled and analyzed using SHS methods. Analysis of a biodiesel

Koutsoukos, Xenofon D.

172

Aridity and Algae: Biodiesel Production in Arizona Jenna Bloxom  

E-Print Network [OSTI]

Aridity and Algae: Biodiesel Production in Arizona Jenna Bloxom Advisor: Dr. Scott Whiteford Center and biodiesel industry in Arizona on the state's water supply and policies. Analyzing potential political extensive literature review of current publications and studies concerning algae biomass and biodiesel

Fay, Noah

173

Biosolids for Biodiesel USDA SBIR 2003-000450  

E-Print Network [OSTI]

Biosolids for Biodiesel USDA SBIR 2003-000450 Phase I Final Report Prepared by Emerald Ranches #12;Biosolids for Biodiesel USDA SBIR 2003-000450 Phase I Final Report Background The goal of this Phase I for the production of biodiesel fuel. It is desirable to use biosolids as a fertilizer for canola for two reasons

Brown, Sally

174

Argentinean soy based biodiesel: an introduction to production and impacts  

E-Print Network [OSTI]

Argentinean soy based biodiesel: an introduction to production and impacts Julia Tomei and Paul biodiesel: an introduction to production and impacts Julia Tomeia * and Paul Upham b a Department(s) alone and not the Tyndall Centre. #12;Argentinean soy based biodiesel: an introduction to production

Watson, Andrew

175

Optimization of Experimental Conditions for Biodiesel Production  

E-Print Network [OSTI]

Abstract-- This study is based on optimizing the experimental conditions of biodiesel production by base-catalyzed transesterification using waste cooking oil (WCO). In this study, the key parameters varied were methanol (20, 25, 30, 35, and 40%), sodium hydroxide (0.4, 0.6, 0.8, 0.9 and 1.0g), reaction time (40, 60, 90, 100 and 120 minutes) and reaction temperature (50, 52, 55, 58, and 60 o C). Maximum biodiesel yield of 86 % was obtained at optimum conditions of 30 % methanol concentration, 0.4g of NaOH concentration, 60 o C reaction temperature and 90 minutes of operation. Biodiesel produced meets American Standard of Testing and Materials (ASTM) standards of biodiesel fuel: viscosity (4.0564 4.9824cSt), density (0.8790 0.8819g/cm 3), flash point (157 168 o C), pour point (0 to-3 o C) and calculated cetane index (7.45 8.26). Index Term-- Biodiesel, fossil fuel, methanol, transesterification, waste cooking oil.

Ayoola Ayodeji A; Hymore Fredrick K; E Mathew A; Udeh Ifeoma N

176

Department of Biological Engineering Fall 2012 Solar Innovations Inc. Biodiesel Fleet Fuel  

E-Print Network [OSTI]

PENNSTATE Department of Biological Engineering Fall 2012 Solar Innovations Inc. Biodiesel Fleet work. The goal was to research and implement biodiesel into their fleet by finding the best biodiesel for the implementation of biodiesel into their fleet. This will include: · Prospective suppliers of biodiesel fuel

Demirel, Melik C.

177

Environmental, economic, and energetic costs and benefits of biodiesel and ethanol biofuels  

E-Print Network [OSTI]

Environmental, economic, and energetic costs and benefits of biodiesel and ethanol biofuels Jason in its production, whereas biodiesel yields 93% more. Compared with ethanol, biodiesel releases just 1% by the production and combustion of ethanol and 41% by biodiesel. Biodiesel also releases less air pollutants per

Minnesota, University of

178

Big Biodiesel LLC | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin: Energy ResourcesJersey: EnergyBerthoud,Biodiesel Place:Forge07. ItBiodiesel LLC

179

Lipid Analysis of Neochloris oleoabundans by Liquid State NMR  

E-Print Network [OSTI]

for biodiesel production. To demonstrate the viability of this approach, 13 C NMR was used to analyze the lipid relevance to biodiesel production. Biotechnol. Bioeng. 2010;106: 573­583. ? 2010 Wiley Periodicals, Inc contains fatty acid methyl esters. There are multiple production pathways capable of producing biodiesel

180

WI Biodiesel Blending Progream Final Report  

SciTech Connect (OSTI)

The Wisconsin State Energy Office?¢????s (SEO) primary mission is to implement cost?¢???effective, reliable, balanced, and environmentally?¢???friendly clean energy projects. To support this mission the Wisconsin Biodiesel Blending Program was created to financially support the installation infrastructure necessary to directly sustain biodiesel blending and distribution at petroleum terminal facilities throughout Wisconsin. The SEO secured a federal directed award of $600,000 over 2.25 years. With these funds, the SEO supported the construction of inline biodiesel blending facilities at two petroleum terminals in Wisconsin. The Federal funding provided through the state provided a little less than half of the necessary investment to construct the terminals, with the balance put forth by the partners. Wisconsin is now home to two new biodiesel blending terminals. Fusion Renewables on Jones Island (in the City of Milwaukee) will offer a B100 blend to both bulk and retail customers. CITGO is currently providing a B5 blend to all customers at their Granville, WI terminal north of the City of Milwaukee.

Redmond, Maria E; Levy, Megan M

2013-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "methyl esters biodiesel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

A numerical investigation into the anomalous slight NOx increase when burning biodiesel; A new (old) theory  

E-Print Network [OSTI]

G. et al, 2005. The Biodiesel Handbook. AOCS Publishing,x Increase When Burning Biodiesel; A New (Old) Theory GeorgeIncrease When Burning Biodiesel; A New (Old) Theory. Fuel

Ban-Weiss, George A.; Chen, J.Y.; Buchholz, Bruce A.; Dibble, Robert W.

2007-01-01T23:59:59.000Z

182

Impact of Biodiesel on the Near-term Performance and Long-term...  

Broader source: Energy.gov (indexed) [DOE]

Temperature and higher NO 2 :NOx have negligible impact on overall NOx Conversion Biodiesel Near-term Impacts Literature Review "Effect of Biodiesel Blends on Urea...

183

E-Print Network 3.0 - algal biodiesel utilization Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

that is further converted to biodiesel in a separate... 3 ) is the energy content of biogas; y is the yield of biodiesel ... Source: Louisiana Forest Products Development Center...

184

Production and Application of Biodiesel A Case Study  

E-Print Network [OSTI]

AbstractThe true fact that everyone has to accept for search of alternative fuels apart from petroleum products is biodiesel for many reasons, mainly increasing demand and scarcity of petroleum products and to preserve the wealth of nature to be used for coming generations. The reason of non implementation of biodiesel in day-to-day life is because of few limitations. Many scientists are in progress for a new dimension of research in biodiesel plantation, cultivation and its usage in engines. This paper highlights the importance of biodiesel production techniques such as supercritical methanolysis, ultrasonication method and microwave technique by which maximum biodiesel can be produced. The new approach of using nano particle in biodiesel shows very good results in reducing the level of pollutant gases in the engine exhaust and increased performance without any engine modification is also discussed briefly in this case study. KeywordsHydrodeoxygeneration, nano particle, ultrasonication, microwave technique I.

unknown authors

185

Messiah College Biodiesel Fuel Generation Project Final Technical Report  

SciTech Connect (OSTI)

Many obvious and significant concerns arise when considering the concept of small-scale biodiesel production. Does the fuel produced meet the stringent requirements set by the commercial biodiesel industry? Is the process safe? How are small-scale producers collecting and transporting waste vegetable oil? How is waste from the biodiesel production process handled by small-scale producers? These concerns and many others were the focus of the research preformed in the Messiah College Biodiesel Fuel Generation project over the last three years. This project was a unique research program in which undergraduate engineering students at Messiah College set out to research the feasibility of small-biodiesel production for application on a campus of approximately 3000 students. This Department of Energy (DOE) funded research program developed out of almost a decade of small-scale biodiesel research and development work performed by students at Messiah College. Over the course of the last three years the research team focused on four key areas related to small-scale biodiesel production: Quality Testing and Assurance, Process and Processor Research, Process and Processor Development, and Community Education. The objectives for the Messiah College Biodiesel Fuel Generation Project included the following: 1. Preparing a laboratory facility for the development and optimization of processors and processes, ASTM quality assurance, and performance testing of biodiesel fuels. 2. Developing scalable processor and process designs suitable for ASTM certifiable small-scale biodiesel production, with the goals of cost reduction and increased quality. 3. Conduct research into biodiesel process improvement and cost optimization using various biodiesel feedstocks and production ingredients.

Zummo, Michael M; Munson, J; Derr, A; Zemple, T; Bray, S; Studer, B; Miller, J; Beckler, J; Hahn, A; Martinez, P; Herndon, B; Lee, T; Newswanger, T; Wassall, M

2012-03-30T23:59:59.000Z

186

Emission Performance of Modern Diesel Engines Fueled with Biodiesel  

Broader source: Energy.gov (indexed) [DOE]

Emission Performance of Modern Diesel Engines Fueled with Biodiesel Aaron Williams, Jonathan Burton, Xin He and Robert L. McCormick National Renewable Energy Laboratory October 5,...

187

Impact of Biodiesel on Modern Diesel Engine Emissions  

Broader source: Energy.gov (indexed) [DOE]

Impact of Biodiesel on Modern Diesel Engine Emissions Vehicle Technologies Program Merit Review - Fuels and Lubricants Technologies PI: Bob McCormick Presenter: Aaron Williams May...

188

Biodiesel Utilization: Update on Recent Analytical Techniques (Presentation)  

SciTech Connect (OSTI)

To understand and increase the use of biodiesel, analytical methods need to be shared and compared to ensure that accurate data are gathered on this complex fuel.

Alleman, T. L.; Fouts, L.; Luecke, J.; Thornton, M.; McAlpin, C.

2009-05-01T23:59:59.000Z

189

Biodiesel Handling and Use Guide: Fourth Edition (Revised)  

SciTech Connect (OSTI)

Intended for those who blend, distribute, and use biodiesel and its blends, this guide contains procedures for handling and using these fuels.

Not Available

2009-01-01T23:59:59.000Z

190

Effect of Biodiesel Blends on Diesel Particulate Filter Performance  

SciTech Connect (OSTI)

Presents results of tests of ultra-low sulfur diesel blended with soy-biodiesel at 5 percent using a Cummins ISB engine with a diesel particulate filter.

Williams, A.; McCormick, R. L.; Hayes, R. R.; Ireland, J.; Fang, H. L.

2006-11-01T23:59:59.000Z

191

Vehicle Technologies Office: Improving Biodiesel and Other Fuels...  

Energy Savers [EERE]

Quality Vehicle Technologies Office: Improving Biodiesel and Other Fuels' Quality For biofuels to succeed in the marketplace, they must be easy to use with a minimum of problems....

192

Fast gas chromatographic separation of biodiesel.  

SciTech Connect (OSTI)

A high-speed gas chromatographic method has been developed to determine the FAME distribution of B100 biodiesel. The capillary column used in this work has dimensions of 20 m x 0.100 mm and is coated with a polyethylene glycol film. Analysis times are typically on the order of 4-5 min depending upon the composition of the B100. The application of this method to a variety of vegetable and animal derived B100 is demonstrated. Quantitative results obtained with this method were in close agreement with those obtained by a more conventional approach on a 100 m column. The method, coupled with solid-phase extraction, was also found suitable to determine the B100 content of biodiesel-diesel blends.

Pauls, R. E. (Chemical Sciences and Engineering Division)

2011-05-01T23:59:59.000Z

193

Alternative Fuels Data Center: Biodiesel Related Links  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onAlternative FuelInfrastructure Development toBiodiesel

194

The Effects of Trans-Esterification of Castor Seed Oil Using Ethanol, Methanol and their Blends on the Properties and Yields of Biodiesel  

E-Print Network [OSTI]

The effects of ethanol, methanol and their blends at different percentage mixtures on the properties and yields of biodiesel at varied trans-esterification times and temperatures using sodium hydroxide as a base catalyst have been investigated. At 70 o C, the optimum yields were: for ethanol 88.4%, 94.2%, 94.8%, and 95.2 % and for methanol, 90.6%, 95.6%, 96.0%, and 96.4% at 1 hour, 2 hours, 3 hours and 4 hours respectively. The biodiesel yields increased as time of reaction progressed for both solvents but the yields obtained from methanol were generally higher than those from ethanol. A mixture of both solvents at 50 % each produced the overall highest of biodiesel yield of 98.6 % at 70 o C and in 4 hours compared to either solvent used alone at the same time and temperature. The properties such as densities, viscosities, flash points and pour points of the biodiesels tested were found to conform to ASTM standards. The average values were as follows: densities at 15 o C, were 0.8951, 0.8876 and 0.8832g/cm 3; viscosities (at 40 o C) were 4.7160cSt, 4.7380cSt and 4.5055cSt; flash points were 140.9 o C, 147.4 o C and 161.6 o C while for pour points they were-2.4375 o C,-1.6875 o C and-6 o C for ethyl, methyl and ethyl/methyl biodiesel respectively.

Vincent Enontiemonria; Ayoola Ayodeji; Anawe Paul; Apeye Lucky; Oteri Ogheneofego

195

Methods of making alkyl esters  

DOE Patents [OSTI]

A method comprising contacting an alcohol, a feed comprising one or more glycerides and equal to or greater than 2 wt % of one or more free fatty acids, and a solid acid catalyst, a nanostructured polymer catalyst, or a sulfated zirconia catalyst in one or more reactors, and recovering from the one or more reactors an effluent comprising equal to or greater than about 75 wt % alkyl ester and equal to or less than about 5 wt % glyceride.

Elliott, Brian (Wheat Ridge, CO)

2010-08-03T23:59:59.000Z

196

Galib, Biodiesel from jatropha oil as an alternative fuel for diesel engine  

E-Print Network [OSTI]

investigates the prospect of making of biodiesel from jatropha oil. Jatropha curcas is a renewable non

Kazi Mostafijur Rahman; Mohammad Mashud; Md. Roknuzzaman; Asadullah Al Galib

197

Studies on Characterization of raw Jatropha oil and its biodiesels with relevance of diesel  

E-Print Network [OSTI]

biodiesel produced from jatropha oil by transesterification process represents one of the most promising

V. B. Shambhu; T. K. Bhattacharya; L. K. Nayak; S. Das

2013-01-01T23:59:59.000Z

198

Non-Edible Plant Oils as New Sources for Biodiesel Production  

E-Print Network [OSTI]

biodiesel production. In this paper, two plant species, soapnut (Sapindus mukorossi) and jatropha (jatropha

Arjun B. Chhetri; Martin S. Tango; Suzanne M. Budge; K. Chris Watts

199

Reachability Analysis of a Biodiesel Production System Using Stochastic Hybrid Systems  

E-Print Network [OSTI]

Reachability Analysis of a Biodiesel Production System Using Stochastic Hybrid Systems Derek Riley defines the creation of biodiesel from soybean oil and methanol. Modeling and analyzing the biodiesel. In this paper we model a biodiesel production system as a stochastic hybrid system, and we present

Koutsoukos, Xenofon D.

200

An Intensified Reaction/Product Recovery Process for the Continuous Production of Biodiesel  

E-Print Network [OSTI]

of Biodiesel Cooperative Research into Biobased Fuels between ORNL and Nu-Energie Biodiesel: This project years. Increased use of domestic biofuels will provide a clean and secure source of energy. Biodiesel. Project Background: Conventional reaction and separations used in biodiesel production are done in time

Note: This page contains sample records for the topic "methyl esters biodiesel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Supporting Information for: A Global Comparison of National Biodiesel Production Potentials  

E-Print Network [OSTI]

Supporting Information for: A Global Comparison of National Biodiesel Production Potentials Matt Biodiesel Potential · Table S.2: Variables Used in Calculating Biodiesel Volumes and Prices · Figure S.3: U) · Table S.5: Well-Managed Vegetable Oil Yields · Table S.6: A Complete List of Absolute Biodiesel

Wisconsin at Madison, University of

202

Biodiesel Sim: Crowdsourcing Simulations for Complex Model Analysis Derek Riley, Xiaowei Zhang, Xenofon Koutsoukos  

E-Print Network [OSTI]

Biodiesel Sim: Crowdsourcing Simulations for Complex Model Analysis Derek Riley, Xiaowei Zhang Computation, Biodiesel Abstract Biodiesel is an alternative fuel source that can be easily made by novices of the proces- sor. A biodiesel processor is a complex system that can be modeled and simulated using formal

Koutsoukos, Xenofon D.

203

Ethanol production using corn, switchgrass, and wood; Biodiesel production using soybean and  

E-Print Network [OSTI]

production using wood biomass required 57 % more fossil energy than the ethanol fuel produced. Biodiesel

David Pimentel; Tad W. Patzek

2005-01-01T23:59:59.000Z

204

Commentary Biodiesel Exhaust: The Need for Health Effects Research  

E-Print Network [OSTI]

BACKGROUND: Biodiesel is a diesel fuel alternative that has shown potential of becoming a commercially accepted part of the United States energy infrastructure. In November 2004, the signing of the Jobs Creation Bill HR 4520 marked an important turning point for the future production of biodiesel in the United States because it offers a federal excise tax credit. By the end of 2005, industry production was 75 million gallons, a 300 % increase in 1 year. Current industry capacity, however, stands at just over 300 million gallons/year, and current expansion and new plant construction could double the industrys capacity within a few years. Biodiesel exhaust emission has been extensively characterized under field and laboratory conditions, but there have been limited cytotoxicity and mutagenicity studies on the effects of biodiesel exhaust in biologic systems. OBJECTIVES: We reviewed pertinent medical literature and addressed recommendations on testing specific research needs in the field of biodiesel toxicity. DISCUSSION: Employment of biodiesel fuel is favorably viewed, and there are suggestions that its exhaust emissions are less likely to present any risk to human health relative to petroleum diesel emissions. CONCLUSION: The speculative nature of a reduction in health effects based on chemical composition of biodiesel exhaust needs to be followed up with investigations in biologic systems. KEY WORDS: air pollution, biodiesel, diesel exhaust, diesel fuels, lung diseases, vehicle emissions. Environ Health Perspect 115:496499 (2007). doi:10.1289/ehp.9631 available via

Kimberly J. Swanson; Michael C. Madden; Andrew J. Ghio

2007-01-01T23:59:59.000Z

205

Hydrogen and Syngas Production from Biodiesel Derived Crude Glycerol  

E-Print Network [OSTI]

In the past decade, the production of biodiesel has increased dramatically. One of the major by-products of biodiesel production is crude glycerol, which is expensive to refine. As a result, the price of crude glycerol has plummeted to the point...

Silvey, Luke

2012-05-31T23:59:59.000Z

206

Method of making a cyanate ester foam  

DOE Patents [OSTI]

A cyanate ester resin mixture with at least one cyanate ester resin, an isocyanate foaming resin, other co-curatives such as polyol or epoxy compounds, a surfactant, and a catalyst/water can react to form a foaming resin that can be cured at a temperature greater than 50.degree. C. to form a cyanate ester foam. The cyanate ester foam can be heated to a temperature greater than 400.degree. C. in a non-oxidative atmosphere to provide a carbonaceous char foam.

Celina, Mathias C.; Giron, Nicholas Henry

2014-08-05T23:59:59.000Z

207

Ris Energy Report 5 Renewable-based fuels for transport 4 Introduction  

E-Print Network [OSTI]

- etable oils. Interesterification of the glyceride molecule using an alcohol, usually methanol, produces, in which methanol is reacted with glycerides to produce glycerin and methyl esters. biodiesel may also

208

Improved Soybean Oil for Biodiesel Fuel  

SciTech Connect (OSTI)

The goal of this program was to generate information on the utility of soybean germplasm that produces oil, high in oleic acid and low in saturated fatty acids, for its use as a biodiesel. Moreover, data was ascertained on the quality of the derived soybean meal (protein component), and the agronomic performance of this novel soybean germplasm. Gathering data on these later two areas is critical, with respect to the first, soybean meal (protein) component is a major driver for commodity soybean, which is utilized as feed supplements in cattle, swine, poultry and more recently aquaculture production. Hence, it is imperative that the resultant modulation in the fatty acid profile of the oil does not compromise the quality of the derived meal, for if it does, the net value of the novel soybean will be drastically reduced. Similarly, if the improved oil trait negative impacts the agronomics (i.e. yield) of the soybean, this in turn will reduce the value of the trait. Over the course of this program oil was extruded from approximately 350 bushels of soybean designated 335-13, which produces oil high in oleic acid (>85%) and low in saturated fatty acid (<6%). As predicted improvement in cold flow parameters were observed as compared to standard commodity soybean oil. Moreover, engine tests revealed that biodiesel derived from this novel oil mitigated NOx emissions. Seed quality of this soybean was not compromised with respect to total oil and protein, nor was the amino acid profile of the derived meal as compared to the respective control soybean cultivar with a conventional fatty acid profile. Importantly, the high oleic acid/low saturated fatty acids oil trait was not impacted by environment and yield was not compromised. Improving the genetic potential of soybean by exploiting the tools of biotechnology to improve upon the lipid quality of the seed for use in industrial applications such as biodiesel will aid in expanding the market for the crop. This in turn, may lead to job creation in rural areas of the country and help stimulate the agricultural economy. Moreover, production of soybean with enhanced oil quality for biodiesel may increase the attractiveness of this renewable, environmentally friendly fuel.

Tom Clemente; Jon Van Gerpen

2007-11-30T23:59:59.000Z

209

Biodiesel Fuel Basics | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative FuelsBSCmemo.pdf BSCmemo.pdf BSCmemo.pdfBetter BuildingsBetterBiodiesel Fuel Basics

210

Brownfield Biodiesel LLC | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin: EnergyBoston Areais a village inBrownfield Biodiesel LLC Jump to: navigation,

211

General Biodiesel Incorporated | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision has beenFfe2fb55-352f-473b-a2dd-50ae8b27f0a6TheoreticalFuelCellGemini Solar Development CompanyBiodiesel

212

Alternative Fuels Data Center: Biodiesel Vehicle Emissions  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc Documentation RUCProductstwrmrAreSmartWay TransportEthanolAll-Electric VehiclesBiodiesel Vehicle

213

Rheology of silicon carbide/vinyl ester nanocomposites  

E-Print Network [OSTI]

New York, 1999. SILICON CARBIDE/VINYL ESTER NANOCOMPOSITESRheology of Silicon Carbide/Vinyl Ester NanocompositesABSTRACT: Silicon carbide (SiC) nanoparticles with no

Yong, Virginia; Hahn, H. Thomas

2006-01-01T23:59:59.000Z

214

Genomic Prospecting for Microbial Biodiesel Production  

SciTech Connect (OSTI)

Biodiesel is defined as fatty acid mono-alkylesters and is produced from triacylglycerols. In the current article we provide an overview of the structure, diversity and regulation of the metabolic pathways leading to intracellular fatty acid and triacylglycerol accumulation in three types of organisms (bacteria, algae and fungi) of potential biotechnological interest and discuss possible intervention points to increase the cellular lipid content. The key steps that regulate carbon allocation and distribution in lipids include the formation of malonyl-CoA, the synthesis of fatty acids and their attachment onto the glycerol backbone, and the formation of triacylglycerols. The lipid biosynthetic genes and pathways are largely known for select model organisms. Comparative genomics allows the examination of these pathways in organisms of biotechnological interest and reveals the evolution of divergent and yet uncharacterized regulatory mechanisms. Utilization of microbial systems for triacylglycerol and fatty acid production is in its infancy; however, genomic information and technologies combined with synthetic biology concepts provide the opportunity to further exploit microbes for the competitive production of biodiesel.

Lykidis, Athanasios; Lykidis, Athanasios; Ivanova, Natalia

2008-03-20T23:59:59.000Z

215

Formation Kinetics of Nitric Oxide of Biodiesel Relative to Petroleum Diesel under Comparable Oxygen Equivalence Ratio in a Homogeneous Reactor  

E-Print Network [OSTI]

Interest in biodiesel has piqued with advent of stringent emissions regulations. Biodiesel is a viable substitute for petroleum diesel because biodiesel produces significantly lower particulate and soot emissions relative to petroleum diesel. Higher...

Rathore, Gurlovleen K.

2011-10-21T23:59:59.000Z

216

Biodiesel synthesis using calcined layered double hydroxide catalysts  

SciTech Connect (OSTI)

The catalytic properties of calcined Li-Al, Mg-Al and Mg-Fe layered double hydroxides (LDHs) were examined in two transesterification reactions, namely, the reaction of glyceryl tributyrate with methanol, and the reaction of soybean oil with methanol. While the Li-Al catalysts showed high activity in these reactions at the reflux temperature of methanol, the Mg-Fe and Mg-Al catalysts exhibited much lower methyl ester yields. CO2 TPD measurements revealed the presence of sites of weak, medium and strong basicity on both Mg-Al and Li-Al catalysts, the latter showing higher concentrations of medium and strong base sites; by implication, these are the main sites active in transesterification catalyzed by calcined Li-Al LDHs. Maximum activity was observed for the Li-Al catalysts when a calcination temperature of 450-500 aC was applied, corresponding to decomposition of the layered double hydroxide to the mixed oxide without formation of crystalline lithium aluminate phases.

Schumaker, J. Link [University of Kentucky; Crofcheck, Czarena [University of Kentucky; TAckett, S. Adam [University of Kentucky; Santillan-Jimenez, Eduardo [University of Kentucky; Morgan, Tonya [University of Kentucky; Ji, Yaying [University of Kentucky; Crocker, Mark [University of Kentucky; Toops, Todd J [ORNL

2008-01-01T23:59:59.000Z

217

Process for the generation of .alpha., .beta.-unsaturated carboxylic acids and esters using niobium catalyst  

DOE Patents [OSTI]

A process using a niobium catalyst includes the step of reacting an ester or carboxylic acid with oxygen and an alcohol in the presence a niobium catalyst to respectively produce an .alpha.,.beta.-unsaturated ester or carboxylic acid. Methanol may be used as the alcohol, and the ester or carboxylic acid may be passed over the niobium catalyst in a vapor stream containing oxygen and methanol. Alternatively, the process using a niobium catalyst may involve the step of reacting an ester and oxygen in the presence the niobium catalyst to produce an .alpha.,.beta.-unsaturated carboxylic acid. In this case the ester may be a methyl ester. In either case, niobium oxide may be used as the niobium catalyst with the niobium oxide being present on a support. The support may be an oxide selected from the group consisting of silicon oxide, aluminum oxide, titanium oxide and mixtures thereof. The catalyst may be formed by reacting niobium fluoride with the oxide serving as the support. The niobium catalyst may contain elemental niobium within the range of 1 wt % to 70 wt %, and more preferably within the range of 10 wt % to 30 wt %. The process may be operated at a temperature from 150 to 450.degree. C. and preferably from 250 to 350.degree. C. The process may be operated at a pressure from 0.1 to 15 atm. absolute and preferably from 0.5-5 atm. absolute. The flow rate of reactants may be from 10 to 10,000 L/kg.sub.(cat) /h, and preferably from 100 to 1,000 L/kg.sub.(cat) /h.

Gogate, Makarand Ratnakav (Durham, NC); Spivey, James Jerome (Cary, NC); Zoeller, Joseph Robert (Kingsport, TN)

1999-01-01T23:59:59.000Z

218

Quality, Performance, and Emission Impacts of Biodiesel Blends  

Broader source: Energy.gov (indexed) [DOE]

Impacts of Biodiesel Blends Bob McCormick (PI) With Teresa Alleman, Wendy Clark, Lisa Fouts, John Ireland, Mike Lammert, Jon Luecke, Dan Pedersen, Ken Proc, Matt Ratcliff, Matt...

219

Algal Harvesting for Biodiesel Production: Comparing Centrifugation and Electrocoagulation  

E-Print Network [OSTI]

Electrocoagulation was compared to centrifugation at pilot scale for harvesting Nannochloris oculata and Nannochloropsis salina for biodiesel production. The pilot scale testing is a proof of concept and no optimization was conducted. Testing used...

Kovalcik, Derek John

2013-08-09T23:59:59.000Z

220

Impacts of Rail Pressure and Biodiesel Composition on Soot Nanostructu...  

Broader source: Energy.gov (indexed) [DOE]

Rail Pressure and Biodiesel Composition on Soot Nanostructure P-20 Ye, P 1 ; Sun, C-X 1 ; Lapuerta, M 2 ; Agudelo, J 3 ; Vander Wal, R 1 ; Boehman, AL 1 , Toops, TJ 4 ; Daw, CS 4...

Note: This page contains sample records for the topic "methyl esters biodiesel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Interactions of chlorosulfonated polyethylene geomembranes with aliphatic esters: Sorption and diffusion phenomena  

SciTech Connect (OSTI)

The resistance of chlorosulfonated polyethylene geomembranes to nine aliphatic esters viz., methyl acetate, ethyl acetate, methyl acetoacetate, n-butyl acetate, diethyl oxalate, iso-amyl acetate, diethyl malonate, and diethyl succinate was investigated in the temperature interval 25--60 C by measuring the liquid sorption using a gravimetric method. A Fickian diffusion equation was used to calculate the diffusion coefficients, and these data were dependent on the type of ester molecules and their interactions with the geomembrane in additions to temperature and solvent concentration. The activation energy values for the diffusion process were in the range 18--41 kJ/mole and the heat of sorption varied from 0.61 to 18.50 kJ/mole. the sorption/swelling results were found to follow the first order kinetics. Solvent front velocities were calculated from the sorption data. The statistical error analysis has been presented in order to judge the reliability of the technique used. The experimental data and calculated parameters were used to discuss transport results in terms of membrane-solvent interactions. None of the esters showed any degradative effects on the geomembrane used.

Aminabhavi, T.M.; Munnolli, R.S. [Karnatak Univ. (India). Dept. of Chemistry] [Karnatak Univ. (India). Dept. of Chemistry; Ortego, J.D. [Lamar Univ., Beaumont, TX (United States)] [Lamar Univ., Beaumont, TX (United States)

1995-07-01T23:59:59.000Z

222

Design and Analysis of Flexible Biodiesel Processes with Multiple Feedstocks  

E-Print Network [OSTI]

DESIGN AND ANALYSIS OF FLEXIBLE BIODIESEL PROCESSES WITH MULTIPLE FEEDSTOCKS A Dissertation by GRACE AMARACHUKWU POKOO-AIKINS Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... of the requirements for the degree of DOCTOR OF PHILOSOPHY August 2010 Major Subject: Chemical Engineering DESIGN AND ANALYSIS OF FLEXIBLE BIODIESEL PROCESSES WITH MULTIPLE FEEDSTOCKS A Dissertation by GRACE AMARACHUKWU POKOO...

Pokoo-Aikins, Grace Amarachukwu

2011-10-21T23:59:59.000Z

223

Cost implications of feedstock combinations for community sized biodiesel production  

SciTech Connect (OSTI)

Biodiesel can be processed from oilseeds or animal fats and used in unmodified diesel engines. This fuel has been produced commercially in Europe for three years. Research indicates that biodiesel can replace diesel fuel without causing harmful effects to an unmodified engine and can reduce harmful emissions . Some European biodiesel plants operate at the community level effectively supplying both fuel and animal feeds. This study examines multiple feedstocks that could be utilized by a community sized biodiesel plant. The model plant used is a 500,000 gallon processing facility. The model plant is assumed to be installed in an existing grain handling facility or feed mill. Animal fats would be purchased from outside sources and oilseeds would be provided by area producers. Producers would retain ownership of the oilseeds and pay a processing fee to the cooperative. Oilseeds would be extruded before being separated into meal and crude oil. The crude oil would be esterified into biodiesel using continuous flow esterification technology. This study concludes under specific conditions, biodiesel can be processed economically at the community level. The results indicate that without farm program benefits to minor oilseeds, soybeans are the most economic feedstock to use in a community based operation. Realistic price information suggests that biodiesel (from soybeans) could be produced for $1.26 per gallon. If producers participate in government programs and are capable of growing minor oilseeds, canola may represent a better feedstock than soybeans. Achieving the lowest costs of production depends on the value assigned to co-product credits such as oilseed meal. The more producers pay for high protein meal for their livestock and poultry, the lower the residual price of biodiesel.

Weber, J.A.; Van Dyne, D.L. [Univ. of Missouri, Columbia, MO (United States)

1993-12-31T23:59:59.000Z

224

Process for the preparation of an energetic nitrate ester  

DOE Patents [OSTI]

A process for the preparation of an energetic nitrate ester compound and related intermediates is provided.

Chavez, David E; Naud, Darren L; Hiskey, Michael A

2013-12-17T23:59:59.000Z

225

Demonstration of the feasibility of milking lipids from algae for biodiesel production  

E-Print Network [OSTI]

A major challenge to the development of industrial-scale biodiesel production from cultured algae is the identification of energy efficient and cost effective methods of harvesting/dewatering algal cells. Producing 1 gallon of biodiesel from algae...

Coiner, Ryan Lee

2011-12-31T23:59:59.000Z

226

Investigating the Use of Ion Exchange Resins for Processing Biodiesel Feedstocks  

E-Print Network [OSTI]

Ion exchange resins, commonly used in water treatment, demonstrate promise for the production of biodiesel from biomass feedstocks. The goal of this presented PhD research is to investigate novel uses of ion exchange resins for processing biodiesel...

Jamal, Yousuf 1973-

2012-11-27T23:59:59.000Z

227

Investigation of Bio-Diesel Fueled Engines under Low-Temperature...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Bio-Diesel Fueled Engines under Low-Temperature Combustion Strategies Investigation of Bio-Diesel Fueled Engines under Low-Temperature Combustion Strategies ftp01lee.pdf More...

228

Impact of Biodiesel-Based Na on the Selective Catalytic Reduction...  

Broader source: Energy.gov (indexed) [DOE]

Impact of Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of NOx Using Cu-zeolite Impact of Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of NOx Using...

229

Applications of Highly Cross Linked Mixed Bed Ion Exchange Resins in Biodiesel Processing  

E-Print Network [OSTI]

Biofuels are a promising solution to society's quest for sustainable energy. In the transportation sector, biodiesel is the leading alternative diesel fuel currently in use today. However, the current global and domestic production of biodiesel...

Jamal, Yousuf

2010-10-12T23:59:59.000Z

230

Impact of Biodiesel on the Near-term Performance and Long-term...  

Broader source: Energy.gov (indexed) [DOE]

Impact of Biodiesel on the Near-term Performance and Long-term Durability of Advanced Aftertreatment Systems Impact of Biodiesel on the Near-term Performance and Long-term...

231

Pollutant Emissions from Biodiesels in Diesel Engine Tests and On-road Tests  

E-Print Network [OSTI]

Interest in biodiesel use is increasing due to concerns over the availability and environmental impact of petroleum fuels. In this study, we analyzed biodiesels prepared from seven different feedstocks: waste cooking oil, rapeseed oil, olive oil...

Zhong, Yue

2012-08-31T23:59:59.000Z

232

Would You Consider Driving a Vehicle that Can Run on Biodiesel...  

Broader source: Energy.gov (indexed) [DOE]

Would You Consider Driving a Vehicle that Can Run on Biodiesel? Would You Consider Driving a Vehicle that Can Run on Biodiesel? September 16, 2010 - 7:30am Addthis On Monday,...

233

Biodiesel Effects on the Operation of U.S. Light Duty Tier 2...  

Broader source: Energy.gov (indexed) [DOE]

Biodiesel Effects on the Operation of U.S. Light Duty Tier 2 Engine and Aftertreatment Systems Biodiesel Effects on the Operation of U.S. Light Duty Tier 2 Engine and...

234

Biodiesel Effects on the Operation of U.S. Light-Duty Tier 2...  

Broader source: Energy.gov (indexed) [DOE]

Biodiesel Effects on the Operation of U.S. Light-Duty Tier 2 Engine and Aftertreatment Systems Biodiesel Effects on the Operation of U.S. Light-Duty Tier 2 Engine and...

235

100,000-Mile Evaluation of Transit Buses Operated on Biodiesel...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

00,000-Mile Evaluation of Transit Buses Operated on Biodiesel Blends (B20) 100,000-Mile Evaluation of Transit Buses Operated on Biodiesel Blends (B20) Presentation given at DEER...

236

Combining Biodiesel and EGR for Low-Temperature NOx and PM Reductions...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Biodiesel and EGR for Low-Temperature NOx and PM Reductions Combining Biodiesel and EGR for Low-Temperature NOx and PM Reductions Poster presentation at the 2007 Diesel...

237

System-Response Issues Imposed by Biodiesel in a Medium-Duty...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

System-Response Issues Imposed by Biodiesel in a Medium-Duty Diesel Engine System-Response Issues Imposed by Biodiesel in a Medium-Duty Diesel Engine The objective of the current...

238

Synthesis of a new energetic nitrate ester  

SciTech Connect (OSTI)

Nitrate esters have been known as useful energetic materials since the discovery of nitroglycerin by Ascanio Sobrero in 1846. The development of methods to increase the safety and utility of nitroglycerin by Alfred Nobel led to the revolutionary improvement in the utility of nitroglycerin in explosive applications in the form of dynamite. Since then, many nitrate esters have been prepared and incorporated into military applications such as double-based propellants, detonators and as energetic plasticizers. Nitrate esters have also been shown to have vasodilatory effects in humans and thus have been studied and used for treatments of ailments such as angina. The mechanism of the biological response towards nitrate esters has been elucidated recently. Interestingly, many of the nitrate esters used for military purposes are liquids (ethylene glycol dinitrate, propylene glycol dinitrate, etc). Pentaerythritol tetranitrate (PETN) is one of the only solid nitrate esters, besides nitrocellulose, that is used in any application. Unfortunately, PETN melting point is above 100 {sup o}C, and thus must be pressed as a solid for detonator applications. A more practical material would be a melt-castable explosive, for potential simplification of manufacturing processes. Herein we describe the synthesis of a new energetic nitrate ester (1) that is a solid at ambient temperatures, has a melting point of 85-86 {sup o}C and has the highest density of any known nitrate ester composed only of carbon, hydrogen, nitrogen and oxygen. We also describe the chemical, thermal and sensitivity properties of 1 as well as some preliminary explosive performance data.

Chavez, David E [Los Alamos National Laboratory

2008-01-01T23:59:59.000Z

239

Evaluation and Comparison of Test Methods to Measure the Oxidation Stability of Neat Biodiesel  

SciTech Connect (OSTI)

The purpose of this project was to compare and evaluate several candidate test methods for evaluating oxidation stability of biodiesel.

Westbrook, S. R.

2005-11-01T23:59:59.000Z

240

EXPERIMENTAL INVESTIGATION ON JATROPHA OIL AS A BIODIESEL FUEL WITH ANALYSIS OF ITS EMISSION  

E-Print Network [OSTI]

jatropha oil can be a good choice as a biodiesel for diesel engines. Experimental results have shown it as

unknown authors

Note: This page contains sample records for the topic "methyl esters biodiesel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Matrix Optimization for the MALDI-TOF-MS Analysis of Trace Biodiesel Components (Poster)  

SciTech Connect (OSTI)

Trace biodiesel components that could reduce the fuel's operability in cold weather are analyzed using MALDI-TOF mass spectrometry.

McAlpin, C. R.; Voorhees, K. J.; Alleman, T. L.; McCormick, R. L.

2009-01-01T23:59:59.000Z

242

Comparative Analysis of the Effect of Different Alkaline Catalysts on Biodiesel Yield  

E-Print Network [OSTI]

materials for production. A cost build-up analysis of biodiesel production from J. curcas oil shows that

Cynthia Ofori-boateng; Ebenezer M. Kwofie; Moses Y. Mensah

243

Towards the optimal integrated production of biodiesel with internal recycling of methanol  

E-Print Network [OSTI]

1 Towards the optimal integrated production of biodiesel with internal recycling of methanol of the production methanol from glycerol and its integration in the production of biodiesel from algae. We propose a limited superstructure where the glycerol from biodiesel is first reformed for which steam reforming

Grossmann, Ignacio E.

244

Ris Energy Report 2 Biodiesel is produced from vegetable oils that have been  

E-Print Network [OSTI]

6.2 Risø Energy Report 2 Biodiesel is produced from vegetable oils that have been chemically (canola) oil with methanol. Biodiesel can be burned directly in diesel engines. Robert Diesel himself, but it was not until the oil crisis of the 1970s that biofuels attracted serious interest. Biodiesel is reported

245

Mass Production of Biodiesel From Algae UROP Summer 2008 Project Proposal  

E-Print Network [OSTI]

1 Mass Production of Biodiesel From Algae UROP Summer 2008 Project Proposal Steven A. Biorn Faculty at the University of Minnesota Twin Cities campus. The project involves the mass production of biodiesel and other to make biodiesel is well understood, this project offers an alternative to current methods by using

Minnesota, University of

246

Sustainable distributed biodiesel manufacturing under uncertainty: An interval-parameter-programming-based approach  

E-Print Network [OSTI]

Sustainable distributed biodiesel manufacturing under uncertainty: An interval A sophisticated biodiesel manufacturing study demonstrated methodological efficacy. a r t i c l e i n f o Article Simulation Uncertainty a b s t r a c t Biodiesel, a clean-burning alternative fuel, can be produced using

Huang, Yinlun

247

Relatively low-cost solutions could improve reliability while making biodiesel blends an affordable option.  

E-Print Network [OSTI]

Relatively low-cost solutions could improve reliability while making biodiesel blends an affordable option. While biodiesel has very low production costs and the potential to displace up to 10% of petroleum diesel, until now, issues with cold weather performance have prevented biodiesel blends from being

248

Sustainability Analysis of African Palm Biodiesel in Ecuador: An Environmental, Socio-cultural, and Artistic Perspective  

E-Print Network [OSTI]

Sustainability Analysis of African Palm Biodiesel in Ecuador: An Environmental, Socio Analysis of African Palm Biodiesel in Ecuador: An Environmental, Socio-cultural, and Artistic Perspective-based biodiesel, which is currently imported by the Unites States. An analysis of this specific interaction

249

Application of Uncertainty and Sensitivity Analysis to a Kinetic Model for Enzymatic Biodiesel Production  

E-Print Network [OSTI]

Application of Uncertainty and Sensitivity Analysis to a Kinetic Model for Enzymatic Biodiesel benefits of using uncertainty and sensitivity analysis in the kinetics of enzymatic biodiesel production, Monte-Carlo Simulations, Enzymatic Biodiesel 1. INTRODUCTION In order to determine the optimal

Mosegaard, Klaus

250

Renewable and alteRnative eneRgy Fact Sheet Using Biodiesel Fuel in Your Engine  

E-Print Network [OSTI]

Renewable and alteRnative eneRgy Fact Sheet Using Biodiesel Fuel in Your Engine introduction Biodiesel is an engine fuel that is created by chemically reacting fatty acids and alcohol. Practically sodium hydroxide). Biodiesel is much more suitable for use as an engine fuel than straight vegetable oil

Boyer, Elizabeth W.

251

Evaluating the Potential for Large-Scale Biodiesel Deployments in a Global Context  

E-Print Network [OSTI]

Evaluating the Potential for Large-Scale Biodiesel Deployments in a Global Context by Matthew Johnston. All rights reserved. #12;#12;Evaluating the Potential for Large-Scale Biodiesel Deployments on the subject of biodiesel, but I can only hope she takes comfort knowing now much I appreciate everything she

Wisconsin at Madison, University of

252

Bioconversion of dairy manure by black soldier fly (Diptera: Stratiomyidae) for biodiesel and sugar production  

E-Print Network [OSTI]

Bioconversion of dairy manure by black soldier fly (Diptera: Stratiomyidae) for biodiesel and sugar (BSFL) are consid- ered as a new biotechnology to convert dairy manure into biodiesel and sugar. BSFL from BSFL by petroleum ether, and then be treated with a two-step method to produce biodiesel

Tomberlin, Jeff

253

Factors Affecting the Stability of Biodiesel Sold in the United States  

SciTech Connect (OSTI)

As part of a survey of biodiesel quality and stability in the United States, 27 biodiesel (B100) samples were collected from blenders and distributor nationwide. For this sample set, 85% met all of the requirements of the industry standard for biodiesel, ASTM D6751.

McCormick, R. L.; Ratcliff, M.; Moens, L.; Lawrence, R.

2006-01-01T23:59:59.000Z

254

Western Kentucky University Research Foundation Biodiesel Project  

SciTech Connect (OSTI)

Petroleum-based liquid hydrocarbons is exclusively major energy source in the transportation sector. Thus, it is the major CO{sub 2} source which is the associated with greenhouse effect. In the United States alone, petroleum consumption in the transportation sector approaches 13.8 million barrels per day (Mbbl/d). It is corresponding to a release of 0.53 gigatons of carbon per year (GtC/yr), which accounts for approximate 7.6 % of the current global release of CO{sub 2} from all of the fossil fuel usage (7 GtC/yr). For the long term, the conventional petroleum production is predicted to peak in as little as the next 10 years to as high as the next 50 years. Negative environmental consequences, the frequently roaring petroleum prices, increasing petroleum utilization and concerns about competitive supplies of petroleum have driven dramatic interest in producing alternative transportation fuels, such as electricity-based, hydrogen-based and bio-based transportation alternative fuels. Use of either of electricity-based or hydrogen-based alternative energy in the transportation sector is currently laden with technical and economical challenges. The current energy density of commercial batteries is 175 Wh/kg of battery. At a storage pressure of 680 atm, the lower heating value (LHV) of H{sub 2} is 1.32 kWh/liter. In contrast, the corresponding energy density for gasoline can reach as high as 8.88 kWh/liter. Furthermore, the convenience of using a liquid hydrocarbon fuel through the existing infrastructures is a big deterrent to replacement by both batteries and hydrogen. Biomass-derived ethanol and bio-diesel (biofuels) can be two promising and predominant U.S. alternative transportation fuels. Both their energy densities and physical properties are comparable to their relatives of petroleum-based gasoline and diesel, however, biofuels are significantly environmental-benign. Ethanol can be made from the sugar-based or starch-based biomass materials, which is easily fermented to create ethanol. In the United States almost all starch ethanol is mainly manufactured from corn grains. The technology for manufacturing corn ethanol can be considered mature as of the late 1980s. In 2005, 14.3 % of the U.S. corn harvest was processed to produce 1.48 x10{sup 10} liters of ethanol, energetically equivalent to 1.72 % of U.S. gasoline usage. Soybean oil is extracted from 1.5 % of the U.S. soybean harvest to produce 2.56 x 10{sup 8} liters of bio-diesel, which was 0.09 % of U.S. diesel usage. However, reaching maximum rates of bio-fuel supply from corn and soybeans is unlikely because these crops are presently major contributors to human food supplies through livestock feed and direct consumption. Moreover, there currently arguments on that the conversion of many types of many natural landscapes to grow corn for feedstock is likely to create substantial carbon emissions that will exacerbate globe warming. On the other hand, there is a large underutilized resource of cellulose biomass from trees, grasses, and nonedible parts of crops that could serve as a feedstock. One of the potentially significant new bio-fuels is so called "cellulosic ethanol", which is dependent on break-down by microbes or enzymes. Because of technological limitations (the wider variety of molecular structures in cellulose and hemicellulose requires a wider variety of microorganisms to break them down) and other cost hurdles (such as lower kinetics), cellulosic ethanol can currently remain in lab scales. Considering farm yields, commodity and fuel prices, farm energy and agrichemical inputs, production plant efficiencies, byproduct production, greenhouse gas (GHG) emissions, and other environmental effects, a life-cycle evaluation of competitive indicated that corn ethanol yields 25 % more energy than the energy invested in its production, whereas soybean bio-diesel yields 93 % more. Relative to the fossil fuels they displace, greenhouse gas emissions are reduced 12 % by the production and combustion of ethanol and 41 % by bio-diesel. Bio-diesel also releases less ai

Pan, Wei-Ping [Principal Investigator] [Principal Investigator; Cao, Yan [Co-Principal Investigator] [Co-Principal Investigator

2013-03-15T23:59:59.000Z

255

Design of a Small-Scale Biodiesel Production System Jeffrey Anderson, Jessica Caceres, Ali Khazaei, Jedidiah Shirey  

E-Print Network [OSTI]

Design of a Small-Scale Biodiesel Production System Jeffrey Anderson, Jessica Caceres, Ali Khazaei acreage and biodiesel output. Monte Carlo Simulation Objective: 1) Biodiesel Production Simulation: Determines biodiesel yield and Net Energy Ration of each crop alternative 1) Business Simulation: Determines

256

Biogenic greenhouse gas emissions linked to the life cycles of biodiesel derived from European rapeseed and Brazilian soybeans  

E-Print Network [OSTI]

Biogenic greenhouse gas emissions linked to the life cycles of biodiesel derived from European determinants of life cycle emissions of greenhouse gases linked to the life cycle of biodiesel from European rapeseed and Brazilian soybeans. For biodiesel from European rapeseed and for biodiesel from Brazilian

257

18-Membered cyclic esters derived from glycolide and lactide: preparations, structures and coordination to sodium ions  

SciTech Connect (OSTI)

From reactions between glycolide or lactide (4 equiv.) with 4-dimethylaminopyridine, DMAP (1 equiv.) and NaBPh4 (1 equiv.) in benzene at 70 C the cyclic ester adducts (CH{sub 2}C(O)O){sub 6}NaBPh{sub 4} and (CHMeC(O)O){sub 6}NaBPh{sub 4} are formed respectively. The structures of the salts Na[(S,R,S,R,S,R)-(CH{sub 3}CHC(O)O){sub 6}]{sub 2}BPh{sub 4} {center_dot} CH{sub 3}CN and (CH{sub 2}C(O)O){sub 6}NaBPh{sub 4} {center_dot} (CH{sub 3}CN){sub 2} are reported. The cyclic esters were separated by chromatography and the structures of (CH{sub 2}C(O)O){sub 6}, (S,R,R,R,R,R)-(CHMeC(O)O){sub 6} and (S,S,R,R,R,R)-(CHMeC(O)O){sub 6} were determined. The {sup 1}H and {sup 13}C NMR data are reported for one of each of the six enantiomers of (CHMeC(O)O){sub 6} and the two meso isomers. The mechanism for the formation of these 18-membered rings is discussed in terms of an initial reaction between DMAP and NaBPh{sub 4} in hot benzene that produces NaPh and DMAP:BPh{sub 3} in the presence of the monomer lactide. The cyclic esters (CHMeC(O)O){sub 6} can also be obtained from the reaction between polylactide, PLA, in the presence of DMAP and NaBPh{sub 4}. The cyclic esters 3-methyl-1,4-dioxane-2,5-dione and 3,6,6-trimethyl-1,4-dioxane-2,5-dione undergo similar ring enlarging reactions to give cyclic 18-membered ring esters as determined by ESI-MS.

Chisholm, Malcolm H.; Gallucci, Judith C.; Yin, Hongfeng (OSU)

2008-06-30T23:59:59.000Z

258

Potential feedstock supply and costs for biodiesel production  

SciTech Connect (OSTI)

Without considering technology constraints, tallows and waste greases have definite potential as feedstocks for the production of biodiesel in the United States. These materials are less expensive than most oils produced from oilseed crops such as soybeans, sunflowers, canola and rapeseed. At current crude petroleum prices, biodiesel derived from any of these materials will be more expensive than diesel derived from petroleum. However, when compared to other clean burning alternate fuels, recent data suggest biodiesel blends produced from any of these feedstocks may be the lowest total cost alternative fuel in certain areas of the United States. Economic feasibility analyses were performed to investigate the cost of producing biodiesel ($/gallon) subject to variances in feedstock cost, by-product credit (glycerol and meal) and capital costs. Cost of production per gallon of esterified biodiesel from soybean, sunflower, tallow and yellow grease ranged from $0.96 to $3.39 subject to feedstock and chemical costs, by-product credit and system capital cost.

Nelson, R.G. [Kansas State Univ., Manhattan, KS (United States); Howell, S.A. [MARC-IV, Bucyrus, KS (United States); Weber, J.A. [Univ. of Missouri, Columbia, MO (United States)

1994-12-31T23:59:59.000Z

259

Effects of Canola Biodiesel on a DI Diesel Engine Performance and Emissions  

E-Print Network [OSTI]

Abstract- A direct injection (DI) diesel engine is tested with different biodiesel-diesel blends, such as B0 (neat diesel), B5 (i.e., 5 vol. % biodiesel and 95 vol. % diesel), B10 (10 vol. % biodiesel), B20 (20 vol. % biodiesel), B50 (50 vol. % biodiesel), and B100 (neat biodiesel) for performance and emissions under different load conditions. Engine performance is examined by measuring brake specific fuel consumption (bsfc) and fuel conversion efficiency (? f). The emission of carbon monoxide (CO), hydrocarbon (HC), nitric oxide (NO), nitrogen dioxide (NO 2), nitrogen oxides (NOx), carbon dioxide (CO 2) and others are measured. Biodiesel shows a significant CO and HC reduction compared to diesel under low load operation; under high load operation, however, CO with biodiesel is increased a little and HC emissions are very similar to that with diesel. On the other hand, under low load operation, NOx emission with biodiesel is significantly increased than diesel; however, under high load operation, there is almost no change in NOx emissions with biodiesel and diesel. Index Term- Canola biodiesel, diesel engine, engine performance, exhaust emissions.

Murari Mohon Roy; Majed Alawi; Wilson Wang

260

Los Alamos National Laboratory considers the use of biodiesel.  

SciTech Connect (OSTI)

A new EPA-approved alternative fuel, called biodiesel, may soon be used at Los Alamos National Laboratory in everything from diesel trucks to laboratory equipment. Biodiesel transforms vegetable oils into a renewable, cleaner energy source that can be used in any machinery that uses diesel fuel. For the past couple years, the Laboratory has been exploring the possibility of switching over to soybean-based biodiesel. This change could lead to many health and environmental benefits, as well as help reduce the nation's dependence on foreign oil. Biodiesel is a clean, renewable diesel fuel substitute made from soybean and other vegetable oil crops, as well as from recycled cooking oils. A chemical process breaks down the vegetable oil into a usable form. Vegetable oil has a chain of about 18 carbons and ordinary diesel has about 12 or 13 carbons. The process breaks the carbon chains of the vegetable oil and separates out the glycerin (a fatty substance used in creams and soaps). The co-product of glycerin can be used by pharmaceutical and cosmetic companies, as well as many other markets. Once the chains are shortened and the glycerin is removed from the oil, the remaining liquid is similar to petroleum diesel fuel. It can be burned in pure form or in a blend of any proportion with petroleum diesel. To be considered an alternative fuel source by the EPA, the blend must be at least 20 percent biodiesel (B20). According to the U.S. Department of Energy (DOE), biodiesel is America's fastest growing alternative fuel.

Matlin, M. K. (Marla K.)

2002-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "methyl esters biodiesel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Alabama Institute for Deaf and Blind Biodiesel Project Green  

SciTech Connect (OSTI)

Through extensive collaboration, Alabama Institute for Deaf and Blind (AIDB) is Alabama's first educational entity to initiate a biodiesel public education, student training and production program, Project Green. With state and national replication potential, Project Green benefits local businesses and city infrastructures within a 120-mile radius; provides alternative education to Alabama school systems and to schools for the deaf and blind in Appalachian States; trains students with sensory and/or multiple disabilities in the acquisition and production of biodiesel; and educates the external public on alternative fuels benefits.

Edmiston, Jessica L

2012-09-28T23:59:59.000Z

262

BioFacts: Fueling a stronger economy, Biodiesel. Revision 2  

SciTech Connect (OSTI)

Biodiesel is a substitute for or an additive to diesel fuel that is derived from the oils and fats of plants. It is an alternative fuel that can be used in diesel engines and provides power similar to conventional diesel fuel. It is a biodegradable transportation fuel that contributes little, if any, net carbon dioxide or sulfur to the atmosphere, and is low in particulate emission. It is a renewable, domestically produced liquid fuel that can help reduce US dependence on foreign oil imports. This overview presents the resource potential, history, processing techniques, US DOE programs cost and utilization potential of biodiesel fuels.

NONE

1995-01-01T23:59:59.000Z

263

Nucleophilic substitutions of 1-alkenylcyclopropyl esters and 1-alkynylcyclopropyl chlorides catalyzed by palladium (0)  

SciTech Connect (OSTI)

The 1-ethenylcyclopropylsulfonates 2e,f and 2-cyclopropylideneethyl esters 10b,c, readily available from cyclopropanone hemiacetal 1, undergo regioselective Pd(0) catalyzed nucleophilic substitution via the unsymmetric 1,1-dimethylene-{pi}-allyl complex 23. With stabilized anions (enolates of malonic ester, {beta}-dicarbonyl compounds, {beta}-sulfonyl ester, and Schiff bases as well as acetate anion, sulfonamide anion, etc.) the nucleophilic substitution occurs at the terminal vinylic position exclusively, providing cyclopropylideneethyl derivatives as building blocks of high synthetic potential. Competition experiments have disclosed that 1-ethenylcyclopropyl tosylate (2e) and cyclopropylideneethyl acetate (10b) are more reactive than dimethylallyl acetates 19 and 22, respectively. Use of chiral phosphines as ligands in the palladium catalyst can provide optically active methylenecyclopropane derivatives. With phenyl-, methyl-, and even n-butylzinc chloride as nucleophiles, the reaction apparently proceeds with initial transfer of the organic residue to palladium, followed by reductive elimination entailing tertiary substitution on the cyclopropane ring exclusively; the same type of product is obtained with azide and bis(trimethylsilyl)amide. But the site of hydride attack to yield reduction products depends on the hydride source. 1-Alkynylcyclopropyl chlorides 12, 13, and 14 react only with organozinc chlorides (nonstabilized nucleophiles) to provide mixtures of ethenylidenecyclopropanes 65 and alkynylcyclopropanes 66, via the {sigma}-palladium complexes 69 and 70, while chloride 15 undergoes mainly reduction. Other transition metal catalysts (Ni, Mo) also induce substitutions, but with poorer regioselectivity. 81 refs., 9 figs., 3 tabs.

Stolle, A. [George-August-Universitaet, Goettingen (Germany)]|[Universite de Paris-Sud, Orsay (France); Ollivier, J.; Salauen, J. [Universite de Paris-Sud, Orsay (France)] [and others

1992-05-20T23:59:59.000Z

264

Coalition Cooperation Defines Roadmap for E85 and Biodiesel  

SciTech Connect (OSTI)

This Clean Cities success story relates how Colorado's Colorado Biofuels Coalition was formed and provides guidance on forming other such coalitions. This Colorado's coalition sucessfully increase the number of fueling stations providing biofuels and has goals to the number even more. Plans also include assisting with financing infrastructure, making alternative fuels available to more fleets, and educating about E85 and biodiesel use.

Not Available

2007-06-01T23:59:59.000Z

265

acetates isoamyl esters: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

any change in fuel injection parameters, but for higher substitution of diesel with biodiesel i.e. from 20 % to 100%, fuel injection pressure must be increased by 50 to 100...

266

Analysis of Smoke of Diesel Engine by Using Biodiesel as Fuel  

E-Print Network [OSTI]

Abstract- This study represents the analysis of smoke of biodiesel by using smoke tester. In this article biodiesel is taken as a fuel instead of diesel and quantity of emitted pollutants HC and CO is evaluated by taking different quantity of biodiesel at different load. This work shows how use of biodiesel will affect the emission of pollutants. Diesel Engine is compression ignition engine and use diesel as fuel, in this engine alternative fuel can be used. One alternate fuel is biodiesel. Biodiesel can be used in pure form or may be blended with petroleum diesel at any concentration in most injection pump diesel engines and also can be used in Vehicle, Railway, and Aircraft as heating oil.

Gayatri Kushwah; Methanol

267

Optimization of combustion performance and emission of Jatropha biodiesel in a turbocharged LHR diesel engine;.  

E-Print Network [OSTI]

??Bio-diesel derived from the vegetable oils are identified as an excellent alternate fuel for petroleum based diesel fuel used in diesel engines. However, the performance (more)

Rajendra Prasath B

2013-01-01T23:59:59.000Z

268

Effects of bio-diesel fuel blends on the performance and emissions of diesel engine.  

E-Print Network [OSTI]

??This study presents an experimental investigation into the effects of running biodiesel fuel blends on conventional diesel engines. Bio fuels provide a way to produce (more)

Bastiani, Sergio.

2008-01-01T23:59:59.000Z

269

Biodiesel Effects on the Operation of U.S. Light-Duty Tier 2...  

Broader source: Energy.gov (indexed) [DOE]

NOx Adsorber SCR System Summary and Conclusions Overview Evaluate the impact of Biodiesel fuel blends on the performance of advanced emission control systems for light-duty...

270

Biodiesel Effects on the Operation of U.S. Light Duty Tier 2...  

Broader source: Energy.gov (indexed) [DOE]

Test Results Summary and Conclusions Project Goals Evaluate the impact of Biodiesel fuel blends on the performance of advanced emission control systems for light-duty...

271

Analysis Of Exhaust Emission Of Internal Combustion Engine Using Biodiesel Blend  

E-Print Network [OSTI]

Abstract-The main purpose of this research is to study the effect of various blends of an environmental friendly alternative fuel such as biodiesel on the performance of diesel engine. In the Present investigation experimental work has been carried out to analyze the performance and exhaust emission characteristics of a single cylinder internal combustion engine fuelled with biodiesel blend at the different load. In this experiment the biodiesel which is use as a waste cooking oil (WCO) biodiesel.To investigation of the emission characteristics of the engine loads, which is supplied from the alternator. The experiment was carried out different load i.e. (NO LOAD, 100W 200W, 500W, 1000W, 1500W, 2000W, 2500W & 3000Watt) at engine speed 1500 rpm/min. A test was applied in which an engine was fuel with diesel and seven different blends of diesel. Biodiesel (B5, B10, B20, B40, B60, B80, B100) made from waste cooking oil and the results were analyzed.The emission of were measured carbon monoxide (CO), hydrocarbon carbon(HC), Oxides of nitrogen (NOX) and oxygen ().The experimental results will be compared with biodiesel blends and diesel. The biodiesel results of (WCO) in lower emission of hydro carbon (HC) and (CO) and increase emission of (NO2). This study showed that the results of exhaust emission of biodiesel blends were lower than the diesel fuel. Keyword- Biodiesel (WCO), diesel engine, gas analyzer, Exhaust emission. I.

Suvendu Mohanty; Dr. Om Prakash; Reasearch Scholar

272

Production of Biodiesel from Jatropha Oil (Jatropha curcas) in Pilot Plant  

E-Print Network [OSTI]

jatropha oil were 8.27 %, 0.58 % and 7.69 % respectively. Yield of biodiesel from jatropha oil at optimal

Tint Tint Kywe; Mya Mya Oo

273

Effect of SoyEffect of Soy--Based B20 Biodiesel on Fuel UseBased B20 Biodiesel on Fuel Use and Emissions of 15 Construction Vehiclesand Emissions of 15 Construction Vehicles  

E-Print Network [OSTI]

Effect of SoyEffect of Soy--Based B20 Biodiesel on Fuel UseBased B20 Biodiesel on Fuel Use Tests with B20 Biodiesel ­ Based on Regular NCDOT Duty Schedule Overview of Study Design for Field for Other Pollutants B20 Biodiesel Tier 0Tier 0 VehicleVehicle Tier 1Tier 1 Tier 2Tier 2 Tier 3Tier 3 0 40

Frey, H. Christopher

274

Biodiesel Fuel Property Effects on Particulate Matter Reactivity  

SciTech Connect (OSTI)

Controlling diesel particulate emissions to meet the 2007 U.S. standard requires the use of a diesel particulate filter (DPF). The reactivity of soot, or the carbon fraction of particulate matter, in the DPF and the kinetics of soot oxidation are important in achieving better control of aftertreatment devices. Studies showed that biodiesel in the fuel can increase soot reactivity. This study therefore investigated which biodiesel fuel properties impact reactivity. Three fuel properties of interest included fuel oxygen content and functionality, fuel aromatic content, and the presence of alkali metals. To determine fuel effects on soot reactivity, the performance of a catalyzed DPF was measured with different test fuels through engine testing and thermo-gravimetric analysis. Results showed no dependence on the aromatic content or the presence of alkali metals in the fuel. The presence and form of fuel oxygen was the dominant contributor to faster DPF regeneration times and soot reactivity.

Williams, A.; Black, S.; McCormick, R. L.

2010-06-01T23:59:59.000Z

275

Biodiesel is produced from a wide variety of oilseed crops. In Europe, canola is the major biodiesel crop while in the U.S. soybeans dominate. Montana State University researchers have developed a  

E-Print Network [OSTI]

Technology Biodiesel is produced from a wide variety of oilseed crops. In Europe, canola is the major biodiesel crop while in the U.S. soybeans dominate. Montana State University researchers have plants used for biodiesel. Seed oil content increases are induced by puroindoline genes which promote

Maxwell, Bruce D.

276

Biodiesel is produced from a wide variety of oilseed crops. In Europe, canola is the major biodiesel crop while in the U.S. soybeans dominates. Montana State University and USDA researchers have  

E-Print Network [OSTI]

Technology Biodiesel is produced from a wide variety of oilseed crops. In Europe, canola is the major biodiesel crop while in the U.S. soybeans dominates. Montana State University and USDA researchers to work for a broad range of oilseed plants including biodiesel and cereal crops. Increased oil

Maxwell, Bruce D.

277

Biodiesel Safety and Best Management Practices for Small-Scale  

E-Print Network [OSTI]

The following gear should be on hand each time you produce biodiesel: Chemical-resistant gloves (butyl rubber is best for methanol and lye) Chemistry goggles (indirect vented) and face shield Dust mask or cartridge respirator Eyewash bottle with saline solution Small spray bottle with vinegar for neutralizing lye spills Access to running water Telephone in case of emergency and emergency telephone numbers Fire extinguishers (ABC or CO) 2

Noncommercial Use

278

Galveston Bay Biodiesel LP GBB | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, search Equivalent URIFrontier,JumpGahanna,Galveston Bay Biodiesel LP GBB

279

Biodiesel as an Alternative Energy Resource in Southwest Nigeria  

E-Print Network [OSTI]

The Nigerian state faces unique issues that may provide an opportunity for rural economic growth. One of such is that major urban areas in the southwest of the country are beginning to have population increase and hence air quality problems that will require actions to reduce sources of pollution. One major pollution source is from exhaust emissions from cars and trucks. The use of alternative fuel sources such as biodiesel can make a significant reduction in certain exhaust emissions thus reducing pollution and improving air quality. The opportunity for economic growth in a single product economy like ours could lie in the processing of soybean oil and other suitable feedstocks produced within the country into biodiesel. The new fuel can be used by vehicles traversing the country thus reduce air pollution and providing another market for agricultural feedstocks while creating a value added market for animal fats and spent oils from industrial facilities. The benefits of biodiesel go far beyond the clean burning nature of the product. Bio diesel is a renewable resource helping to reduce the dependence of the economy on limited resources and imports, create a market for farmers and reduce the amount of waste oil, fat and grease being dumped into landfills and sewers.

Ajide O. O

280

PERFORMANCE OF THE CAPSTONE C30 MICROTURBINE ON BIODIESEL BENDS.  

SciTech Connect (OSTI)

This report will describe the tests of biodiesel blends as a fuel in a Capstone oil fired microturbine (C30) with a nominal rating of 30 kW. The blends, in ASTM No. 2 heating oil, ranged from 0% to 100% biodiesel. No changes were made to the microturbine system for operation on the blends. Apart from the data that the control computer acquires on various turbine parameters, measurements were made in the hot gas exhaust from the turbine. The results from this performance testing and from the atomization tests reported previously provide some insight into the use of biodiesel blends in microturbines of this type. The routine use of such blends would need more tests to establish that the life of the critical components of the microturbine are not diminished from what they are on the baseline diesel or heating fuel. Of course, the extension to 'widespread' use of such blends in generating systems based on the microturbine is also determined by economic and other considerations.

KRISHNA,C.R.

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "methyl esters biodiesel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

UBC Social Ecological Economic Development Studies (SEEDS) Student Report Development of sulfonated carbon catalysts for integrated biodiesel production  

E-Print Network [OSTI]

carbon catalysts for integrated biodiesel production Jidon Adrian Bin Janaun University of British of sulfonated carbon catalysts for integrated biodiesel production by Jidon Adrian Bin Janaun M.Sc. in Chemical security, climate change, and environmental protection attract the use of biodiesel as an alternative fuel

282

UBC Social Ecological Economic Development Studies (SEEDS) Student Report Investigation of Solid Acid Catalyst Functionalization for the Production of Biodiesel  

E-Print Network [OSTI]

Acid Catalyst Functionalization for the Production of Biodiesel Elliot James Nash University of British Functionalization for the Production of Biodiesel By Elliot James Nash Thesis CHBE 493/494 4 April 2013 The Faculty;ii Abstract The adoption of biodiesel as an alternative fuel is gaining momentum despite its large

283

Comparative Analysis of the Effect of Different Alkaline Catalysts on Biodiesel Yield  

E-Print Network [OSTI]

Abstract: A major challenge in the biodiesel industry is the comparatively high cost of raw materials for production. A cost build-up analysis of biodiesel production from J. curcas oil shows that catalyst alone contributes about 50.9 % of the total production cost. This paper aims at highlighting the effects of two different commonly used catalysts on the yield of biodiesel. Samples of biodiesel were produced by three different methods namely single stage transesterification (SST), double stage transesterification (DST) and foolproof (FP) processes in which sodium hydroxide (NaOH) and potassium hydroxide (KOH) were used. The effects of each catalyst on the production yield were analyzed and compared. NaOH gave production yields of 79%, 81% and 84 % for the SST, DST and FP processes respectively. KOH produced comparatively lower yields of 68%, 71 % and 75 % for SST, DST and fool proof processes respectively. Although the use of KOH slightly raises the cost of biodiesel production as compared to NaOH, the local production of KOH from cocoa husks could minimize the production cost. Abbreviations: BDF = Biodiesel fuel; PDF = Petroleum diesel fuel; DF = Diesel fuel Key words: Transesterification Alkaline catalysts Biodiesel yield Biodiesel KOH NaOH

Cynthia Ofori-boateng; Ebenezer M. Kwofie; Moses Y. Mensah

284

Biodiesel Clears the Air in Underground Mines, Clean Cities, Fact Sheet, June 2009  

SciTech Connect (OSTI)

Mining companies are using biodiesel in their equipment to help clear the air of diesel particulate matter (DPM). This action improves air quality and protects miners' lungs. Though using biodiesel has some challenges in cold weather, tax incentives, and health benefits make it a viable option.

Not Available

2009-06-01T23:59:59.000Z

285

Life cycle inventory of biodiesel and petroleum diesel for use in an urban bus. Final report  

SciTech Connect (OSTI)

This report presents the findings from a study of the life cycle inventories for petroleum diesel and biodiesel. It presents information on raw materials extracted from the environment, energy resources consumed, and air, water, and solid waste emissions generated. Biodiesel is a renewable diesel fuel substitute. It can be made from a variety of natural oils and fats. Biodiesel is made by chemically combining any natural oil or fat with an alcohol such as methanol or ethanol. Methanol has been the most commonly used alcohol in the commercial production of biodiesel. In Europe, biodiesel is widely available in both its neat form (100% biodiesel, also known as B1OO) and in blends with petroleum diesel. European biodiesel is made predominantly from rapeseed oil (a cousin of canola oil). In the United States, initial interest in producing and using biodiesel has focused on the use of soybean oil as the primary feedstock mainly because the United States is the largest producer of soybean oil in the world. 170 figs., 148 tabs.

Sheehan, J.; Camobreco, V.; Duffield, J.; Graboski, M.; Shapouri, H.

1998-05-01T23:59:59.000Z

286

Low Temperature Autoignition of C8H16O2 Ethyl and Methyl Esters...  

Broader source: Energy.gov (indexed) [DOE]

500 600 700 800 900 1000 300 320 340 360 380 400 420 Apparent Heat Release Rate (kJDeg) Bulk Cylinder Gas Temperature (K) CA (Deg) -0.01 0.01 0.03 0.05 0.07 0.09 0.11 50 250 450...

287

Experimental and Computational Thermochemical Study of 2-and 3-Thiopheneacetic Acid Methyl Esters  

E-Print Network [OSTI]

, biodiagnostics, electronic and optoelectronic devices, and conductive polymers. The present study reports found widespread use in modern drug design,3 biodiagnostics,4 electronic and optoelectronic devices,5

Chickos, James S.

288

SciTech Connect: Determination of Total Lipids as Fatty Acid Methyl Esters  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administrationcontroller systems controllerAdditiveBetatronAerogel Deep BedDemonstration

289

Low Temperature Autoignition of C8H16O2 Ethyl and Methyl Esters in a  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensionalthe10IO1OP001Long-Term Storage ofEnergyReactivity SI

290

Ester, Alaska: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address:011-DNA Jump37. It isInformationexplains a4 Climate Zone Subtype A.Essex is aEster,

291

System Dynamics Sustainability Model of Palm-Oil Based Biodiesel Production Chain in Indonesia  

E-Print Network [OSTI]

The nature of biodiesel production itself is complex with multisectors and multi-actors conditions, and with addition of sustainability issues from various stakeholder, created a complex challenges for developing the biodiesel industry. In order to understand of the complexity, this research developed a comprehensive sustainability model to draw the relationships and analyze the effects of government policy for stimulating biodiesel industry using the combination methods of process mapping, financial modeling, life cycle analysis (LCA) and business sustainability strategy. The model combines its output translated into a complete sustainability index of financial, social and environment. The model simulation results show that accomplishment of a sustainable biodiesel production within the target and timeframe is impossible without releasing the subsidized price of diesel fuel and further directions from the government. I Index Terms biodiesel, system dynamics, sustainability

Akhmad Hidayatno; Aziiz Sutrisno; Yuri M. Zagloel; Widodo W. Purwanto

292

Preparation of .alpha.,.beta.-unsaturated carboxylic acids and esters  

DOE Patents [OSTI]

Disclosed is a process for the preparation of .alpha.,.beta.-unsaturated carboxylic acids and esters thereof which comprises contacting formaldehyde or a source of formaldehyde with a carboxylic acid, ester or anhydride in the presence of a catalyst comprising an oxide of niobium.

Gogate, Makarand Ratnakar (Durham, NC); Spivey, James Jerry (Cary, NC); Zoeller, Joseph Robert (Kingsport, TN)

1998-01-01T23:59:59.000Z

293

Preparation of {alpha},{beta}-unsaturated carboxylic acids and esters  

DOE Patents [OSTI]

Disclosed is a process for the preparation of {alpha},{beta}-unsaturated carboxylic acids and esters thereof which comprises contacting formaldehyde or a source of formaldehyde with a carboxylic acid, ester or anhydride in the presence of a catalyst comprising an oxide of niobium.

Gogate, M.R.; Spivey, J.J.; Zoeller, J.R.

1998-09-15T23:59:59.000Z

294

E-Print Network 3.0 - activated ester self-assembled Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ester) Summary: behavior of DNA with the polymer to form self-assembled PHP esterDNA complexes was characterized... 3 and 4). Condensation of Polyanion by...

295

E-Print Network 3.0 - acid ester homologs Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

acid ester hydrolase from Acetobacter turbidans Jolanda J. Polderman-Tijmes, Peter A. Jekel, Erik J. de... acid ester hydrolase from ... Source: Groningen, Rijksuniversiteit -...

296

E-Print Network 3.0 - acid esters evaluated Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Abstract... This paper describes an exploratory study on the synthesis of fatty acidpotato starch esters using... : potato starch, fatty acid starch esters, starch laurate, ......

297

E-Print Network 3.0 - acetic acid esters Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and plasticized acetate esters were considerably improved... fatty esters (C8C18) of potato starch and corn amylose using fatty acid chlorides and pyridine... exploratory...

298

Biodiesel Revs Up Its Applications | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Year in Review: Top Five EEREDepartment ofEnergyEnergyBetterMake Fuels andBiodiesel Revs Up

299

Big Daddy s Biodiesel Inc | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin: Energy ResourcesJersey: EnergyBerthoud,Biodiesel Place:Forge07.Daddy s

300

Impacts of Biodiesel on Emission Control Devices | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensionalthe U.S. Department-2023 Idaho4Fuel Consumptionproblem ofBiodiesel

Note: This page contains sample records for the topic "methyl esters biodiesel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Alternative Fuels Data Center: Biodiesel Truck Transports Capitol Christmas  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth (AOD)ProductssondeadjustsondeadjustAbout theOFFICE OF RESEARCHThermalPlug-inTexasFleetBiodiesel

302

Measurement of biodiesel blend and conventional diesel spray structure using x-ray radiography.  

SciTech Connect (OSTI)

The near-nozzle structure of several nonevaporating biodiesel-blend sprays has been studied using X-ray radiography. Radiography allows quantitative measurements of the fuel distribution in sprays to be made with high temporal and spatial resolution. Measurements have been made at different values of injection pressure, ambient density, and with two different nozzle geometries to understand the influences of these parameters on the spray structure of the biodiesel blend. These measurements have been compared with corresponding measurements of Viscor, a diesel calibration fluid, to demonstrate the fuel effects on the spray structure. Generally, the biodiesel-blend spray has a similar structure to the spray of Viscor. For the nonhydroground nozzle used in this study, the biodiesel-blend spray has a slightly slower penetration into the ambient gas than the Viscor spray. The cone angle of the biodiesel-blend spray is generally smaller than that of the Viscor spray, indicating that the biodiesel-blend spray is denser than the Viscor spray. For the hydroground nozzle, both fuels produce sprays with initially wide cone angles that transition to narrow sprays during the steady-state portion of the injection event. These variations in cone angle with time occur later for the biodiesel-blend spray than for the Viscor spray, indicating that the dynamics of the injector needle as it opens are somewhat different for the two fuels.

Kastengren, A. L.; Powell, C. F.; Wang, Y. J.; IM, K. S.; Wang, J.

2009-11-01T23:59:59.000Z

303

Simulating flame lift-off characteristics of diesel and biodiesel fuels using detailed chemical-kinetic mechanisms and LES turbulence model.  

SciTech Connect (OSTI)

Combustion in direct-injection diesel engines occurs in a lifted, turbulent diffusion flame mode. Numerous studies indicate that the combustion and emissions in such engines are strongly influenced by the lifted flame characteristics, which are in turn determined by fuel and air mixing in the upstream region of the lifted flame, and consequently by the liquid breakup and spray development processes. From a numerical standpoint, these spray combustion processes depend heavily on the choice of underlying spray, combustion, and turbulence models. The present numerical study investigates the influence of different chemical kinetic mechanisms for diesel and biodiesel fuels, as well as Reynolds-averaged Navier-Stokes (RANS) and large eddy simulation (LES) turbulence models on predicting flame lift-off lengths (LOLs) and ignition delays. Specifically, two chemical kinetic mechanisms for n-heptane (NHPT) and three for biodiesel surrogates are investigated. In addition, the RNG k-{epsilon} (RANS) model is compared to the Smagorinsky based LES turbulence model. Using adaptive grid resolution, minimum grid sizes of 250 {micro}m and 125 {micro}m were obtained for the RANS and LES cases respectively. Validations of these models were performed against experimental data from Sandia National Laboratories in a constant volume combustion chamber. Ignition delay and flame lift-off validations were performed at different ambient temperature conditions. The LES model predicts lower ignition delays and qualitatively better flame structures compared to the RNG k-{epsilon} model. The use of realistic chemistry and a ternary surrogate mixture, which consists of methyl decanoate, methyl 9-decenoate, and NHPT, results in better predicted LOLs and ignition delays. For diesel fuel though, only marginal improvements are observed by using larger size mechanisms. However, these improved predictions come at a significant increase in computational cost.

Som, S; Longman, D. E.; Luo, Z; Plomer, M; Lu, T; Senecal, P.K.; Pomraning, E (Energy Systems); (Univ. of Connecticut); (CONVERGENT Science)

2012-01-01T23:59:59.000Z

304

A comparison of injector flow and spray characteristics of biodiesel with petrodiesel.  

SciTech Connect (OSTI)

Performance and emission characteristics of compression ignition engines depend strongly on inner nozzle flow and spray behavior. These processes control the fuel air mixing, which in turn is critical for the combustion process. The differences in the physical properties of petrodiesel and biodiesel are expected to significantly alter the inner nozzle flow and spray structure and, thus, the performance and emission characteristics of the engine. In this study, the inner nozzle flow dynamics of these fuels are characterized by using the mixture-based cavitation model in FLUENT v6.3. Because of its lower vapor pressure, biodiesel was observed to cavitate less than petrodiesel. Higher viscosity of biodiesel resulted in loss of flow efficiency and reduction in injection velocity. Turbulence levels at the nozzle orifice exit were also lower for biodiesel. Using the recently developed KH-ACT model, which incorporates the effects of cavitation and turbulence in addition to aerodynamic breakup, the inner nozzle flow simulations are coupled with the spray simulations in a 'quasi-dynamic' fashion. Thus, the influence of inner nozzle flow differences on spray development of these fuels could be captured, in addition to the effects of their physical properties. Spray penetration was marginally higher for biodiesel, while cone angle was lower, which was attributed to its poor atomization characteristics. The computed liquid lengths of petrodiesel and biodiesel were compared with data from Sandia National Laboratories. Liquid lengths were higher for biodiesel due to its higher boiling temperature and heat of vaporization. Though the simulations captured this trend well, the liquid lengths were underpredicted, which was attributed to uncertainty about the properties of biodiesel used in the experiments. Parametric studies were performed to determine a single parameter that could be used to account for the observed differences in the fuel injection and spray behavior of petrodiesel and biodiesel; fuel temperature seems to be the best parameter to tune.

Som, S.; Longman, D. E; Ramirez, A. I.; Aggarwal, S. K. (Energy Systems)

2010-12-01T23:59:59.000Z

305

Low-Temperature Biodiesel Research Reveals Potential Key to Successful Blend Performance (Fact Sheet)  

SciTech Connect (OSTI)

Relatively low-cost solutions could improve reliability while making biodiesel blends an affordable option. While biodiesel has very low production costs and the potential to displace up to 10% of petroleum diesel, until now, issues with cold weather performance have prevented biodiesel blends from being widely adopted. Some biodiesel blends have exhibited unexplained low-temperature performance problems even at blend levels as low as 2% by volume. The most common low-temperature performance issue is vehicle stalling caused by fuel filter clogging, which prevents fuel from reaching the engine. Research at the National Renewable Energy Laboratory (NREL) reveals the properties responsible for these problems, clearing a path for the development of solutions and expanded use of energy-conserving and low-emissions alternative fuel. NREL researchers set out to study the unpredictable nature of biodiesel crystallization, the condition that impedes the flow of fuel in cold weather. Their research revealed for the first time that saturated monoglyceride impurities common to the biodiesel manufacturing process create crystals that can cause fuel filter clogging and other problems when cooling at slow rates. Biodiesel low-temperature operational problems are commonly referred to as 'precipitates above the cloud point (CP).' NREL's Advanced Biofuels team spiked distilled soy and animal fat-derived B100, as well as B20, B10, and B5 biodiesel blends with three saturated monoglycerides (SMGs) at concentration levels comparable to those of real-world fuels. Above a threshold or eutectic concentration, the SMGs (monomyristin, monopalmitin, and monostearin) were shown to significantly raise the biodiesel CP, and had an even greater impact on the final melting temperature. Researchers discovered that upon cooling, monoglyceride initially precipitates as a metastable crystal, but it transforms over time or upon slight heating into a more stable crystal with a much lower solubility and higher melting temperature - and with increased potential to cause vehicle performance issues. This explains why fuel-filter clogging typically occurs over the course of long, repeated diurnal cooling cycles. The elevated final melting points mean that restarting vehicles with clogged filters can be difficult even after ambient temperatures have warmed to well above CP. By examining how biodiesel impurities affect filtration and crystallization during warming and cooling cycles, NREL researchers uncovered an explanation for poor biodiesel performance at low temperatures. The observation of a eutectic point, or a concentration below which SMGs have no effect, indicates that SMGs do not have to be completely removed from biodiesel to solve low-temperature performance problems.

Not Available

2012-02-01T23:59:59.000Z

306

Effects of Biodiesel and Engine Load on Some Emission Characteristics of a Direct Injection Diesel Engine  

E-Print Network [OSTI]

In this research, experiments were conducted on a 4-cylinder direct-injection diesel engine using biodiesel as an alternative fuel and their blends to investigate the emission characteristics of the engine under four engine loads (25%, 40%, 65 % and 80%) at an engine speed of 1800 rev/min. A test was applied in which an engine was fueled with diesel and four different blends of diesel/ biodiesel (B20, B40, B60 and B80) made from waste frying oil and the results were analyzed. The use of biodiesel resulted in lower emissions of hydrocarbon (HC) and CO and increased emissions

Alireza Shirneshan; Morteza Almassi; Barat Ghobadian; Ali Mohammad Borghei; Gholam Hassan Najafi

2012-01-01T23:59:59.000Z

307

Investigation and Optimization of Biodiesel Chemistry for HCCI Combustion  

SciTech Connect (OSTI)

Over the past 5 years, ORNL has run 95 diesel range fuels in homogene-ous charge compression ignition (HCCI), including 40 bio-diesels and associated diesel fuels in their blending. The bio-diesel blends varied in oxygen content, iodine number, cetane, boiling point distribution, chemical composition, and some contained nitrogen. All fuels were run in an HCCI engine at 1800 rpm, in the power range of 2.5 to 4.5 bar IMEP, using intake air heating for combustion phasing control, and at a compression ratio of 10.6. The engine response to fuel variables has been analyzed statistically. Generally, the engine responded well to fuels with lower nitrogen and oxygen, lower cetane, and lower aromatics. Because of the wide range of fuels combined in the model, it provides only a broad overview of the engine response. It is recommended that data be truncated and re-modeled to obtain finer resolution of engine response to particular fuel variables.

Bunting, Bruce G [ORNL] [ORNL; Bunce, Michael [ORNL] [ORNL; Joyce, Blake [ORNL] [ORNL; Crawford, Robert W [Rincon Ranch Consulting] [Rincon Ranch Consulting

2011-01-01T23:59:59.000Z

308

Investigation and Optimization of Biodiesel Chemistry for HCCI Combustion  

SciTech Connect (OSTI)

Over the past 5 years, ORNL has run 95 diesel range fuels in homogene-ous charge compression ignition (HCCI), including 40 bio-diesels and associated diesel fuels in their blending. The bio-diesel blends varied in oxygen content, iodine number, cetane, boiling point distribution, chemical composition, and some contained nitrogen. All fuels were run in an HCCI engine at 1800 rpm, in the power range of 2.5 to 4.5 bar IMEP, using intake air heating for combustion phasing control, and at a compression ratio of 10.6. The engine response to fuel variables has been analyzed statistically. Generally, the engine responded well to fuels with lower nitrogen and oxygen, lower cetane, and lower aromatics. Because of the wide range of fuels combined in the model, it provides only a broad overview of the engine response. It is recommended that data be truncated and re-modeled to obtain finer resolution of engine response to particular fuel variables.

Bunting, Bruce G. [ORNL; Bunce, Michael [ORNL; Joyce, Blake [ORNL; Crawford, Robert W. [Rincon Ranch Consulting

2014-06-23T23:59:59.000Z

309

Power and Torque Characteristics of Diesel Engine Fuelled by Palm-Kernel Oil Biodiesel  

E-Print Network [OSTI]

Short-term engine performance tests were carried out on test diesel engine fuelled with Palm kernel oil (PKO) biodiesel. The biodiesel fuel was produced through transesterification process using 100g PKO, 20.0 % ethanol (wt%), 1.0 % potassium hydroxide catalyst at 60C reaction temperature and 90min. reaction time. The diesel engine was attached to a general electric dynamometer. Torque and power delivered by the engine were monitored throughout the 24-hour test duration at 1300, 1500, 1700, 2000, 2250 and 2500rpm. At all engine speeds tested, results showed that torque and power outputs for PKO biodiesel were generally lower than those for petroleum diesel. Also, Peak torque for PKO biodiesel occurred at a lower engine speed compared to diesel.

Oguntola J Alamu; Ezra A Adeleke; Nurudeen O. Adekunle; Salam O; Oguntola J Alamu; Ezra A Adeleke; Nurudeen O Adekunle; Salam O Ismaila

310

Process simulation, integration and optimization of blending of petrodiesel with biodiesel  

E-Print Network [OSTI]

strategies to meet these requirements. The primary objective of this work is to analyze alternatives for producing ULSD. In addition to the conventional approach of revamping existing hydrotreating facilities, the option of blending petrodiesel with biodiesel...

Wang, Ting

2009-05-15T23:59:59.000Z

311

Laser-induced breakdown spectroscopy measurement in methane and biodiesel flames using an ungated detector  

SciTech Connect (OSTI)

Laser-induced breakdown spectroscopy (LIBS) has been applied to measure the equivalence ratio of CH4/air flames using gated detection. In this work, we have developed an ungated, miniature LIBS-based sensor for studying CH4/air and biodiesel flames. We have used this sensor to characterize the biodiesel flame. LIBS spectra of biodiesel flames were recorded with different ethanol concentrations in the biodiesel and also at different axial locations within the flame. The sensor performance was evaluated with a CH4/air flame. LIBS signals of N, O, and H from a CH4/air flame were used to determine the equivalence ratio. A linear relationship between the intensity ratio of H and O lines and the calculated equivalence ratio were obtained with this sensor.

Eseller, Kemal E.; Yueh, Fang Y.; Singh, Jagdish P

2008-11-01T23:59:59.000Z

312

Application of Real Options Analysis in the Valuation of Investment in Biodiesel Production  

E-Print Network [OSTI]

to value investment projects that have flexibility in them tend to underestimate the values of the projects, because they fail to capture the value of the flexibility embedded in such projects. For biodiesel production, such flexibility may include...

Yeboah, F. E.; Shahbazi, A.; Yeboah, O.A.; Singh, H.; Holcomb, F. H.

2011-01-01T23:59:59.000Z

313

Life-Cycle Assessment of the Use of Jatropha Biodiesel in Indian Locomotives (Revised)  

SciTech Connect (OSTI)

With India's transportation sector relying heavily on imported petroleum-based fuels, the Planning Commission of India and the Indian government recommended the increased use of blended biodiesel in transportation fleets, identifying Jatropha as a potentially important biomass feedstock. The Indian Oil Corporation and Indian Railways are collaborating to increase the use of biodiesel blends in Indian locomotives with blends of up to B20, aiming to reduce GHG emissions and decrease petroleum consumption. To help evaluate the potential for Jatropha-based biodiesel in achieving sustainability and energy security goals, this study examines the life cycle, net GHG emission, net energy ratio, and petroleum displacement impacts of integrating Jatropha-based biodiesel into locomotive operations in India. In addition, this study identifies the parameters that have the greatest impact on the sustainability of the system.

Whitaker, M.; Heath, G.

2009-03-01T23:59:59.000Z

314

Effects of Biodiesel Operation on Light-Duty Tier 2 Engine and Emission Control Systems: Preprint  

SciTech Connect (OSTI)

This paper documents the impact of biodiesel blends on engine-out emissions as well as overall system performance in terms of emissions control system calibration and overall system efficiency.

Tatur, M.; Nanjundaswamy, H.; Tomazic, D.; Thornton, M.

2008-08-01T23:59:59.000Z

315

Anaerobic Co-digestion of Chicken Processing Wastewater and Crude Glycerol from Biodiesel  

E-Print Network [OSTI]

The main objective of this thesis was to study the anaerobic digestion (AD) of wastewater from a chicken processing facility and of crude glycerol from local biodiesel operations. The AD of these substrates was conducted in bench-scale reactors...

Foucault, Lucas Jose

2011-10-21T23:59:59.000Z

316

Impact of Biodiesel-Based Na on the Selective Catalytic Reduction...  

Broader source: Energy.gov (indexed) [DOE]

Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of NO x Using Cu-zeolite D. William Brookshear 1 , Todd J. Toops 2 , William Rohr 1 , Ke Nguyen 1 , and Bruce G....

317

Impacts of Biodiesel Fuel Blends Oil Dilution on Light-Duty Diesel Engine Operation  

SciTech Connect (OSTI)

Assesses oil dilution impacts on a diesel engine operating with a diesel particle filter, NOx storage, a selective catalytic reduction emission control system, and a soy-based 20% biodiesel fuel blend.

Thornton, M. J.; Alleman, T. L.; Luecke, J.; McCormick, R. L.

2009-08-01T23:59:59.000Z

318

Novel Solid Base Catalysts for the Production of Biodiesel from Lipids  

E-Print Network [OSTI]

The primary commercial biodiesel production processes use homogeneous base catalysts which cause separation and wastewater discharge problems. Solid base catalysts can overcome these drawbacks. However, a solid base catalyst with high activity...

Zhao, Lina

2010-12-17T23:59:59.000Z

319

Engine Performance and Exhaust Emissions of a Diesel Engine From Various Biodiesel Feedstock  

E-Print Network [OSTI]

Increasing fuel prices, stricter government policies, and technological developments made it possible to seek for renewable alternatives, called biofuels, to petroleum fuel. Biodiesel, a biofuel that is produced from chemically mixing animal fat...

Santos, Bjorn Sanchez

2011-02-22T23:59:59.000Z

320

Dieselzymes: development of a stable and methanol tolerant lipase for biodiesel production by directed evolution  

E-Print Network [OSTI]

metha- nol and 1.5 ml of canola oil. This mixture provides aconverting ~76% of the canola oil to biodiesel within 20with less than 15% of the canola oil being converted to

Korman, Tyler P; Sahachartsiri, Bobby; Charbonneau, David M; Huang, Grace L; Beauregard, Marc; Bowie, James U

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "methyl esters biodiesel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Emissions comparison between petroleum diesel and biodiesel in a medium-duty diesel engine  

E-Print Network [OSTI]

EMISSIONS COMPARISON BETWEEN PETROLEUM DIESEL AND BIODIESEL IN A MEDIUM-DUTY DIESEL ENGINE A Thesis by BRANDON T. TOMPKINS Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE December 2008 Major Subject: Mechanical Engineering EMISSIONS COMPARISON BETWEEN PETROLEUM DIESEL AND BIODIESEL IN A MEDIUM-DUTY DIESEL ENGINE A Thesis by BRANDON T...

Tompkins, Brandon T.

2009-05-15T23:59:59.000Z

322

Preparation and recovery of methacrylic acid and its esters  

SciTech Connect (OSTI)

This patent describes a process for the vapor phase catalytic oxydehydrogenation of isobutyric acid or its esters to form methacrylic acid or its esters wherein the gaseous product is condensed and purified. The improvement described here consists of adding to the gaseous product at or about the point of its condensation from 1 to 6000 ppm of a surfactant material selected from the group consisting of an anionic a cationic and non-ionic surfactant.

Frank, P.J.; Hite, J.R.

1986-07-15T23:59:59.000Z

323

Investigation of engine performance and exhaust gas emissions by using bio-diesel in compression ignition engine and optimisation of bio-diesel production from feedstock by using response surface methodology.  

E-Print Network [OSTI]

??Bio-diesel, derived from the transesterification of vegetable oils or animal fats with simple alcohols, has attracted more and more attention recently. As a cleaner burning (more)

Abuhabaya, Abdullah

2012-01-01T23:59:59.000Z

324

A Numerical Investigation into the Anomalous Slight NOx Increase when Burning Biodiesel: A New (Old) Theory  

SciTech Connect (OSTI)

Biodiesel is a notable alternative to petroleum derived diesel fuel because it comes from natural domestic sources and thus reduces dependence on diminishing petroleum fuel from foreign sources, it likely lowers lifecycle greenhouse gas emissions, and it lowers an engine's emission of most pollutants as compared to petroleum derived diesel. However, the use of biodiesel often slightly increases a diesel engine's emission of smog forming nitrogen oxides (NO{sub x}) relative to petroleum diesel. In this paper, previously proposed theories for this slight NOx increase are reviewed, including theories based on biodiesel's cetane number, which leads to differing amounts of charge preheating, and theories based on the fuel's bulk modulus, which affects injection timing. This paper proposes an additional theory for the slight NO{sub x} increase of biodiesel. Biodiesel typically contains more double bonded molecules than petroleum derived diesel. These double bonded molecules have a slightly higher adiabatic flame temperature, which leads to the increase in NOx production for biodiesel. Our theory was verified using numerical simulations to show a NOx increase, due to the double bonded molecules, that is consistent with observation. Further, the details of these numerical simulations show that NOx is predominantly due to the Zeldovich mechanism.

Ban-Weiss, G A; Chen, J Y; Buchholz, B A; Dibble, R W

2007-01-30T23:59:59.000Z

325

Continuous Production of Biodiesel Via an Intensified Reactive/Extractive Process  

SciTech Connect (OSTI)

Biodiesel is considered as a means to diversify our supply of transportation fuel, addressing the goal of reducing our dependence on oil. For a number of reasons ranging from production issues to end use, biodiesel represents only a small fraction of the transportation fuel used worldwide. This work addresses the aspect of biodiesel production that limits it to a slow batch process. Conventional production methods are batch in nature, based on the assumption that the rates of the key chemical reactions are slow. The hypothesis motivating this work is that the reaction kinetics for the transesterification of the reagent triglyceride is sufficiently fast, particularly in an excess of catalyst, and that interfacial mass transfer and phase separation control the process. If this is the case, an intensified two-phase reactor adapted from solvent extraction equipment may be utilized to greatly increase biodiesel production rates by increasing interphase transport and phase separation. To prove this idea, we are investigating two aspects: (1) determining the rate-limiting step in biodiesel production by evaluating the reaction kinetics, and (2) enhancing biodiesel production rates by using an intensified reactor. A centrifugal contactor combining interphase mass transfer, chemical reaction, and phase separation is employed for process intensification.

Tsouris, Costas [ORNL] [ORNL; McFarlane, Joanna [ORNL] [ORNL; Birdwell Jr, Joseph F [ORNL] [ORNL; Jennings, Hal L [ORNL] [ORNL

2008-01-01T23:59:59.000Z

326

Exploration of Novel Fuels for Gas Turbine (ENV-406) Modeling of T60 Test Rig with Diesel & Biodiesel Fuels  

E-Print Network [OSTI]

& Biodiesel Fuels Mémoire Mina Youssef Maîtrise en génie mécanique Maître ès sciences (M.Sc.) Québec, Canada de biodiesel B20. La matrice de test numérique constitue de quatre cas d'écoulement réactifs c to simulate the liquid combustion of conventional and non- conventional biodiesel fuels, in particularly the B

327

Direct conversion of algal biomass to biofuel  

SciTech Connect (OSTI)

A method and system for providing direct conversion of algal biomass. Optionally, the method and system can be used to directly convert dry algal biomass to biodiesels under microwave irradiation by combining the reaction and combining steps. Alternatively, wet algae can be directly processed and converted to fatty acid methyl esters, which have the major components of biodiesels, by reacting with methanol at predetermined pressure and temperature ranges.

Deng, Shuguang; Patil, Prafulla D; Gude, Veera Gnaneswar

2014-10-14T23:59:59.000Z

328

The following are appendices A, B1 and B2 of our paper, "Integrated Process Modeling and Product Design of Biodiesel Manufacturing", that appears in the Industrial and  

E-Print Network [OSTI]

Design of Biodiesel Manufacturing", that appears in the Industrial and Engineering Chemistry Research a Biodiesel Process Model To access NIST TDE Data Engine in Aspen Plus version 2006.5 or V7.0 Step 1. Enter

Liu, Y. A.

329

Strategic Utilization of Paper/Wood Waste for Biodiesel Fuel Art J. Ragauskas, Institute of Paper Science and Technology; Georgia Institute of Technology, Atlanta, GA.  

E-Print Network [OSTI]

Strategic Utilization of Paper/Wood Waste for Biodiesel Fuel Art J. Ragauskas, Institute of Paper lignocellulosics to biodiesel fuel Feedstocks ABSTRACT This poster examines the potential of utilizing waste paper CelluloseHemicelluloseLigninResource Cracking and Refining of Polysaccharides Bio-Diesel Substitutes

330

Biodiesel: a case study of the impact of new rules regarding the classification and labelling of physical and chemical properties of chemicals  

E-Print Network [OSTI]

Biodiesel: a case study of the impact of new rules regarding the classification and labelling.janes@ineris.fr, guy.marlair@ineris.fr, patricia.rotureau@ineris.fr 1. Introduction Biodiesel and any co-products or intermediate chemicals produced and used from the biodiesel industry fall under the scope of the regulation

Paris-Sud XI, Université de

331

future science group 479ISSN 1759-726910.4155/BFS.12.35 2012 Future Science Ltd Biodiesel production involves the transesterification of  

E-Print Network [OSTI]

future science group 479ISSN 1759-726910.4155/BFS.12.35 © 2012 Future Science Ltd Biodiesel the mass transfer Application of ultrasonication in transesterification processes for biodiesel production Brian He* & Jon H Van Gerpen In biodiesel production, adequate mixing is required to create sufficient

He, Brian

332

Isotopic Tracing of Fuel Carbon in the Emissions of a Compression-Ignition Engine Fueled with Biodiesel Blends  

SciTech Connect (OSTI)

Experimental tests were conducted on a Cummins 85.9 direct-injected diesel engine fueled with biodiesel blends. 20% and 50% blend levels were tested, as was 100% (neat) biodiesel. Emissions of particulate matter (PM), nitrogen oxides (NO{sub x}), hydrocarbons (HC) and CO were measured under steady-state operating conditions. The effect of biodiesel on PM emissions was mixed; however, the contribution of the volatile organic fraction to total PM was greater for the higher biodiesel blend levels. When only non-volatile PM mass was considered, reductions were observed for the biodiesel blends as well as for neat biodiesel. The biodiesel test fuels increased NO{sub x}, while HC and CO emissions were reduced. PM collected on quartz filters during the experimental runs were analyzed for carbon-14 content using accelerator mass spectrometry (AMs). These measurements revealed that carbon from the biodiesel portion of the blended fuel was marginally less likely to contribute to PM, compared to the carbon from the diesel portion of the fuel. The results are different than those obtained in previous tests with the oxygenate ethanol, which was observed to be far less likely contribute to PM than the diesel component of the blended fuel. The data suggests that chemical structure of the oxygen- carbon bonds in an oxygenate affects the PM formation process.

Buchholz, B A; Cheng, A S; Dibble, R W

2003-03-03T23:59:59.000Z

333

Comparison of Real-World Fuel Use and Emissions for Dump Trucks Fueled with B20 Biodiesel Versus Petroleum Diesel  

E-Print Network [OSTI]

Versus Petroleum Diesel By H. Christopher Frey, Ph.D. Professor Department of Civil, Construction-world in-use on-road emissions of selected diesel vehicles, fueled with B20 biodiesel and petroleum diesel was tested for one day on B20 biodiesel and for one day on petroleum diesel. On average, there were 4.5 duty

Frey, H. Christopher

334

Low-temperature emission spectra of 9-alkylanthracene esters: Dimer photodecomposition and monomer pair interactions in polymer hosts  

SciTech Connect (OSTI)

Effects due to variation in the alkyl chain length of photodimers of 9-alkylanthracene esters on their photodecomposition efficiencies at 12 K and, by implication, the photoproduct migration as a function of temperature within polymer hosts are investigated. It is shown that dimers with longer alkyl chains have a lower photodecomposition efficiency. The extent of photoproduct migration within the polymer following photodecomposition was also studied as a function of alkyl chain length. This migration and its modulation of the interaction between the separating monomers is shown to affect the emission spectrum. Thus, monomer migration was studied in temperature cycling experiments. It was also found, for the polymer hosts investigated - poly(methyl methacrylate), poly(vinyl chloride), and polystyrene - that these properties are host dependent. This result is probably due to the void space differences that exist among these polymers. 17 refs., 10 figs.

Salt, K.; Scott, G.W. (Univ. of California, Riverside, CA (United States))

1994-10-06T23:59:59.000Z

335

95 Production and Testing of Coconut Oil Biodiesel Fuel and its Blend  

E-Print Network [OSTI]

Many researchers have successfully worked on generating energy from different alternative sources including solar and biological sources such as the conversion of trapped energy from sunlight to electricity and conversion of some renewable agricultural products to fuel. This work considers the use of coconut oil for the production of alternative renewable and environmental friendly biodiesel fuel as an alternative to conventional diesel fuel. Test quantities of coconut oil biodiesel were produced through transesterification reaction using 100g coconut oil, 20.0 % ethanol (wt % coconut oil), 0.8% potassium hydroxide catalyst at 65C reaction temperature and 120 min. reaction time. The experiment was carried out three times and average results evaluated. Low yield of the biodiesel (10.4%) was obtained. The coconut oil biodiesel produced was subsequently blended with petroleum diesel and characterized as alternative diesel fuel through some ASTM standard fuel tests. The products were further evaluated by comparing specific gravity and viscosity of the biodiesel blend, the raw coconut oil and conventional petroleum diesel.

Oguntola J Alamu; Opeoluwa Dehinbo; Adedoyin M Sulaiman; Oguntola J. Alamu; Opeoluwa Dehinbo; Adedoyin M. Sulaiman

336

BIODIESEL AS AN ALTERNATE FUEL FOR POLLUTION CONTROL IN DIESEL ENGINE  

E-Print Network [OSTI]

Diesel vehicles are the major source for air pollution; there is great potential for global warming due to discharge of greenhouse gases like CO2 from vehicles. Many lung problems are connected with particulate matter emitted by diesel vehicle including dust, soot and smoke. People are exposed to pollution even as they talk or when stir up the dust when they walk. Biodiesel is a non-toxic, biodegradable and renewable fuel. Compared to diesel fuel, biodiesel produces no sulfur, no net carbon dioxide, less carbon monoxide and more oxygen. More free oxygen leads to the complete combustion and reduced emission. Overall biodiesel emissions are very less compared to diesel fuel emissions which is promising pollution free environment. Abundant source of vegetable oil in India and its ease of conversion to biodiesel help to save large expenditure done on import of petroleum products and economic growth of country. Biodiesel also generates huge rural employment and degraded lands can be restored due to plantation of oil plants which help in reducing pollution. Extensive research is going on in different countries on different types of vegetable oils like sunflower oil, karanj oil, linseed oil, soya been oil, palm oil, and many more, which can be used in those countries as per availability, our research is in progress on CNSL and its blend with diesel, research is going on in right direction and likely to get surprising

Mr. Paresh K. Kasundra; Prof Ashish; V. Gohil

337

On droplet combustion of biodiesel fuel mixed with diesel/alkanes in microgravity condition  

SciTech Connect (OSTI)

The burning characteristics of a biodiesel droplet mixed with diesel or alkanes such as dodecane and hexadecane were experimentally studied in a reduced-gravity environment so as to create a spherically symmetrical flame without the influence of natural convection due to buoyancy. Small droplets on the order of 500 {mu}m in diameter were initially injected via a piezoelectric technique onto the cross point intersected by two thin carbon fibers; these were prepared inside a combustion chamber that was housed in a drag shield, which was freely dropped onto a foam cushion. It was found that, for single component droplets, the tendency to form a rigid soot shell was relatively small for biodiesel fuel as compared to that exhibited by the other tested fuels. The soot created drifted away readily, showing a puffing phenomenon; this could be related to the distinct molecular structure of biodiesel leading to unique soot layers that were more vulnerable to oxidative reactivity as compared to the soot generated by diesel or alkanes. The addition of biodiesel to these more traditional fuels also presented better performance with respect to annihilating the soot shell, particularly for diesel. The burning rate generally follows that of multi-component fuels, by some means in terms of a lever rule, whereas the mixture of biodiesel and dodecane exhibits a somewhat nonlinear relation with the added fraction of dodecane. This might be related to the formation of a soot shell. (author)

Pan, Kuo-Long; Li, Je-Wei; Chen, Chien-Pei; Wang, Ching-Hua [Department of Mechanical Engineering, National Taiwan University, Taipei 10617 (China)

2009-10-15T23:59:59.000Z

338

Polyol esters as HFC-134a compressor lubricants  

SciTech Connect (OSTI)

A polyol ester-based lubricant has been applied to HFC-134a household refrigerator compressors, because of its good miscibility with HFC-134a refrigerant, and there is a possibility that it will be applied to automobile air conditions. For better performance, further improvements are needed regarding miscibility, lubricity and chemical stability of the lubricant, because such systems are often used under extreme conditions. This report discusses the required properties and ways to improve performance of polyol esters as HFC-134a compressor lubricants. 7 refs., 14 figs., 4 tabs.

Komatsuzaki, S.; Homma, Y.; Itoh, Y. [Hitachi Ltd. (Japan)] [and others

1994-10-01T23:59:59.000Z

339

E-Print Network 3.0 - acyl-coa esters antagonize Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

B. Magnetic properties a b s t r a c t FeVinyl ester... surfactant or coupling agent. Vinyl ester monomer serves as a coupling agent with one side covalently bound Source: Guo,...

340

www.ext.vt.edu Produced by Communications and Marketing, College of Agriculture and Life Sciences,  

E-Print Network [OSTI]

-ester is a scientific term for the biodiesel fuel produced when methanol is used in the biodiesel production process. CH for biodiesel production ­ trans, 1890 Extension Program, Virginia State, Petersburg. publication 442-885 Small-Scale Biodiesel

Liskiewicz, Maciej

Note: This page contains sample records for the topic "methyl esters biodiesel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Experimental and Computational Studies of the Combustion of Classical and Alternative Fuels  

E-Print Network [OSTI]

kinetic model for the biodiesel surrogate, methyl butanoate,surrogates for diesel and biodiesel fuels, Combustion andas model compounds for biodiesel, Proceed- ings of the

Niemann, Ulrich

342

STUDY OF BIODIESEL AS A FUEL FOR CI ENGINES AND ITS ENVIRONMENTAL EFFECTS: A RESEARCH REVIEW Mukesh Kumar 1  

E-Print Network [OSTI]

Biodiesel will play an increasing role in fulfilling the worlds energy requirement. The world has experienced negative effect from the fossil fuel such as global warming and acid rain etc. With the increase in consumption of biodiesel, its impact on environment has raised a discussion around the world. Energy requirement of the world will increase in coming future and is projected to increase by 50 % from 2005 to 2030. The paper presents the results of biodiesel combustion emission on the environment. A review of literature available in the field of vegetable oil usage has identified many advantages. Vegetable oil is produced domestically which helps to reduce costly petroleum imports, it is biodegradable, nontoxic, contains low aromatics and sulphur and hence, is environment friendly. The biodiesel shows no obvious NOx emission difference from the pure diesel fuel at low and medium engine loads. Biodiesel blend ratios have little effect on the NO/NOx ratio at medium and high engine loads. The CO emission of biodiesel increases at low engine loads. The HC emissions show a continuous reduction with increasing biodiesel blend ratios. There is a good correlation between smoke reduction and the ratio of the biodiesel blends. The addition of biodiesel fuel increases formaldehyde emission. A series of engine tests, with and without preheating have been conducted using each of the above fuel blends for comparative performance evaluation. The results of the experiment in each case were compared with baseline data of diesel fuel. Significant improvements have been observed in the performance parameters of the engine as well as exhaust emissions, when lower blends of karanja oil were used with preheating and also without preheating. Karanja oil blends with diesel (up to K50) without preheating as well as with preheating, can replace diesel for operating the CI engines.

Onkar Singh

343

Life Cycle Assessment Comparing the Use of Jatropha Biodiesel in the Indian Road and Rail Sectors  

SciTech Connect (OSTI)

This life cycle assessment of Jatropha biodiesel production and use evaluates the net greenhouse gas (GHG) emission (not considering land-use change), net energy value (NEV), and net petroleum consumption impacts of substituting Jatropha biodiesel for conventional petroleum diesel in India. Several blends of biodiesel with petroleum diesel are evaluated for the rail freight, rail passenger, road freight, and road-passenger transport sectors that currently rely heavily on petroleum diesel. For the base case, Jatropha cultivation, processing, and use conditions that were analyzed, the use of B20 results in a net reduction in GHG emissions and petroleum consumption of 14% and 17%, respectively, and a NEV increase of 58% compared with the use of 100% petroleum diesel. While the road-passenger transport sector provides the greatest sustainability benefits per 1000 gross tonne kilometers, the road freight sector eventually provides the greatest absolute benefits owing to substantially higher projected utilization by year 2020. Nevertheless, introduction of biodiesel to the rail sector might present the fewest logistic and capital expenditure challenges in the near term. Sensitivity analyses confirmed that the sustainability benefits are maintained under multiple plausible cultivation, processing, and distribution scenarios. However, the sustainability of any individual Jatropha plantation will depend on site-specific conditions.

Whitaker, M.; Heath, G.

2010-05-01T23:59:59.000Z

344

Analysis of Biodiesel Blends Samples Collected in the United States in 2008 (Revised)  

SciTech Connect (OSTI)

NREL sampled and tested the quality of U.S. B20 (20% biodiesel, 80% petroleum diesel) in 2008; 32 samples from retail locations and fleets were tested against a proposed ASTM D7467 B6-B20 specification, now in effect.

Alleman, T. L.; Fouts, L.; McCormick, R. L.

2010-12-01T23:59:59.000Z

345

Permanent Closure of MFC Biodiesel Underground Storage Tank 99ANL00013  

SciTech Connect (OSTI)

This closure package documents the site assessment and permanent closure of the Materials and Fuels Complex biodiesel underground storage tank 99ANL00013 in accordance with the regulatory requirements established in 40 CFR 280.71, Technical Standards and Corrective Action Requirements for Owners and Operators of Underground Storage Tanks: Out-of-Service UST Systems and Closure.

Kerry L. Nisson

2012-10-01T23:59:59.000Z

346

Advantages of Biofuels B100 biodiesel has many benefits over traditional, petroleum-based  

E-Print Network [OSTI]

Advantages of Biofuels B100 biodiesel has many benefits over traditional, petroleum-based diesel fuel. It reduces air pollution, costs less than petroleum diesel, and results in cleaner engines Reduces operating and maintenance costs by 20-40% vs. petroleum-based fuels Human Health Benefits Reduces

347

Operation of a solid oxide fuel cell on biodiesel with a partial oxidation reformer  

SciTech Connect (OSTI)

The National Energy Technology Laboratorys Office of Research & Development (NETL/ORD) has successfully demonstrated the operation of a solid oxide fuel cell (SOFC) using reformed biodiesel. The biodiesel for the project was produced and characterized by West Virginia State University (WVSU). This project had two main aspects: 1) demonstrate a catalyst formulation on monolith for biodiesel fuel reforming; and 2) establish SOFC stack test stand capabilities. Both aspects have been completed successfully. For the first aspect, inhouse patented catalyst specifications were developed, fabricated and tested. Parametric reforming studies of biofuels provided data on fuel composition, catalyst degradation, syngas composition, and operating parameters required for successful reforming and integration with the SOFC test stand. For the second aspect, a stack test fixture (STF) for standardized testing, developed by Pacific Northwest National Laboratory (PNNL) and Lawrence Berkeley National Laboratory (LBNL) for the Solid Energy Conversion Alliance (SECA) Program, was engineered and constructed at NETL. To facilitate the demonstration of the STF, NETL employed H.C. Starck Ceramics GmbH & Co. (Germany) anode supported solid oxide cells. In addition, anode supported cells, SS441 end plates, and cell frames were transferred from PNNL to NETL. The stack assembly and conditioning procedures, including stack welding and sealing, contact paste application, binder burn-out, seal-setting, hot standby, and other stack assembly and conditioning methods were transferred to NETL. In the future, fuel cell stacks provided by SECA or other developers could be tested at the STF to validate SOFC performance on various fuels. The STF operated on hydrogen for over 1000 hrs before switching over to reformed biodiesel for 100 hrs of operation. Combining these first two aspects led to demonstrating the biodiesel syngas in the STF. A reformer was built and used to convert 0.5 ml/min of biodiesel into mostly hydrogen and carbon monoxide (syngas.) The syngas was fed to the STF and fuel cell stack. The results presented in this experimental report document one of the first times a SOFC has been operated on syngas from reformed biodiesel.

Siefert, N, Shekhawat, D.; Gemmen, R.; Berry, D.

2010-01-01T23:59:59.000Z

348

E-Print Network 3.0 - alkyl hydroperoxide reductase Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Methyl Esters J. Biet, V. Warth, O. Herbinet* Summary: hydroperoxides methyl esters, acrolein and OH and methyl ester alkyl radicals from unsaturated hydroperoxide... for...

349

Phosphate ester inhibitors solve naphthenic acid corrosion problems  

SciTech Connect (OSTI)

Crude oils containing naphthenic acids can cause a variety of corrosion problems in any of several process areas. But because of the complexity of naphthenic acid corrosion, no routine technique is available for predicting corrosion from this source. Certain high-temperature corrosion inhibitors with a general phosphate ester structure have shown good mitigation of naphthenic acid corrosion in commercial applications. A description of two such cases will help refiners know what to look for to prevent similar occurrences in their plants.

Babaian-Kibala, E. (Nalco Chemical Co., Sugar Land, TX (United States))

1994-02-28T23:59:59.000Z

350

Operational and policy implications of managing uncertainty in quality and emissions of multi-feedstock biodiesel systems  

E-Print Network [OSTI]

As an alternative transportation fuel to petrodiesel, biodiesel has been widely promoted within national energy portfolio targets across the world. Early estimations of low lifecycle greenhouse gas (GHG) emissions of ...

Gl?en, Ece

2012-01-01T23:59:59.000Z

351

Investigation on Nitric Oxide and Soot of Biodiesel and Conventional Diesel using a Medium Duty Diesel Engine  

E-Print Network [OSTI]

Biodiesel has been suggested as an alternative fuel to the petroleum diesel fuel. It beneficially reduces regulated emission gases, but increases NOx (nitric oxide and nitrogen dioxide) Thus, the increase in NOx is the barrier for potential growth...

Song, Hoseok

2012-07-16T23:59:59.000Z

352

Investigation of the Difference in Cool Flame Characteristics between Petroleum Diesel and Soybean Biodiesel Operating in Low Temperature Combustion Mode  

E-Print Network [OSTI]

. The focus of this study is to investigate the difference in the cool flame combustion characteristics between petroleum diesel and soybean biodiesel, when operating in low temperature combustion mode. Previous studies have attributed the absence of the cool...

Muthu Narayanan, Aditya

2014-01-16T23:59:59.000Z

353

A determination of the heats of combustion of the five-carbon fatty acids and their methyl and ethyl esters  

E-Print Network [OSTI]

; g7;P~. X% FATTI ACXDS ND TAX'. K~~~. Ah. ' RKg', Ei~K'~ P~ FuXVQJ~ ef %he 1&aydgewetie fea %he Twine of ~ of . "-elmer F~ F QQXly xy, ay~ Oe esther w9atew to thank Lh ~ C+ K ~ eeet W 9 H~ Vetoes ebs 45xoe~ @de esesaveh The ~ also ~ to thsnk N... of preparation had to be used? Tbongh sane diff ioalt and tins oonsnaing than sxxidationx the prsparatdon through the Orignard synthesis prosed quite satisfaotory? Isobntyl ~ prepared frcxa the aloohol was converted to isobutgrl nayvvxtuxs bread, de whioh...

Gilby, Ralph F

1952-01-01T23:59:59.000Z

354

Determination of Total Lipids as Fatty Acid Methyl Esters (FAME) by in situ Transesterification: Laboratory Analytical Procedure (LAP)  

Office of Scientific and Technical Information (OSTI)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinan antagonist Journal Article: Crystal structureComposite--FOR IMMEDIATE RELEASE April 13, 2000 NEWS

355

E-Print Network 3.0 - antiproliferative cephalotaxus esters Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

JP, Perchellet EM. Phorbol ester tumor promoters and multistage skin carcinogenesis. ISI Atlas... . Perchellet EM, Gali HU, Gao XM, Perchellet JP. Ability of the nonphorbol...

356

Methods and catalysts for making biodiesel from the transesterification and esterification of unrefined oils  

SciTech Connect (OSTI)

A method of forming a biodiesel product and a heterogeneous catalyst system used to form said product that has a high tolerance for the presence of water and free fatty acids (FFA) in the oil feedstock is disclosed. This catalyst system may simultaneously catalyze both the esterification of FAA and the transesterification of triglycerides present in the oil feedstock. The catalyst system according to one aspect of the present disclosure represents a class of zinc and lanthanum oxide heterogeneous catalysts that include different ratios of zinc oxide to lanthanum oxides (Zn:La ratio) ranging from about 10:0 to 0:10. The Zn:La ratio in the catalyst is believed to have an effect on the number and reactivity of Lewis acid and base sites, as well as the transesterification of glycerides, the esterification of fatty acids, and the hydrolysis of glycerides and biodiesel.

Yan, Shuli (Detroit, MI); Salley, Steven O. (Grosse Pointe Park, MI); Ng, K. Y. Simon (West Bloomfield, MI)

2012-04-24T23:59:59.000Z

357

Biodiesel Impact on Engine Lubricant Dilution During Active Regeneration of Aftertreatment Systems  

SciTech Connect (OSTI)

Experiments were conducted with ultra low sulfur diesel (ULSD) and 20% biodiesel blends (B20) to compare lube oil dilution levels and lubricant properties for systems using late in-cylinder fuel injection for aftertreatment regeneration. Lube oil dilution was measured by gas chromatography (GC) following ASTM method D3524 to measure diesel content, by Fourier transform infrared (FTIR) spectrometry following a modified ASTM method D7371 to measure biodiesel content, and by a newly developed back-flush GC method that simultaneously measures both diesel and biodiesel. Heavy-duty (HD) engine testing was conducted on a 2008 6.7L Cummins ISB equipped with a diesel oxidation catalyst (DOC) and diesel particle filter (DPF). Stage one of engine testing consisted of 10 consecutive repeats of a forced DPF regeneration event. This continuous operation with late in-cylinder fuel injection served as a method to accelerate lube-oil dilution. Stage two consisted of 16 hours of normal engine operation over a transient test cycle, which created an opportunity for any accumulated fuel in the oil sump to evaporate. Light duty (LD) vehicle testing was conducted on a 2010 VW Jetta equipped with DOC, DPF and a NOx storage catalyst (NSC). Vehicle testing comprised approximately 4,000 miles of operation on a mileage-accumulation dynamometer (MAD) using the U.S. Environmental Protection Agency's Highway Fuel Economy Cycle because of the relatively low engine oil and exhaust temperatures, and high DPF regeneration frequency of this cycle relative to other cycles examined. Comparison of the lube oil dilution analysis methods suggests that D3524 does not measure dilution by biodiesel. The new back-flush GC method provided analysis for both diesel and biodiesel, in a shorter time and with lower detection limit. Thus all lube oil dilution results in this paper are based on this method. Analysis of the HD lube-oil samples showed only 1.5% to 1.6% fuel dilution for both fuels during continuous operation under DPF regeneration events. During the second stage of HD testing, the ULSD lube-oil dilution levels fell from 1.5% to 0.8%, while for B20, lube-oil dilution levels fell from 1.6% to 1.0%, but the fuel in the oil was 36% biodiesel. For the LD vehicle tests, the frequency of DPF regeneration events was observed to be the same for both ULSD and B20. No significant difference between the two fuels' estimated soot loading was detected by the engine control unit (ECU), although a 23% slower rate of increase in differential pressure across DPF was observed with B20. It appears that the ECU estimated soot loading is based on the engine map, not taking advantage of the lower engine-out particulate matter from the use of biodiesel. After 4,000 miles of LD vehicle operation with ULSD, fuel dilution in the lube-oil samples showed total dilution levels of 4.1% diesel. After 4,000 miles of operation with B20, total fuel in oil dilution levels were 6.7% consisting of 3.6% diesel fuel and 3.1% biodiesel. Extrapolation to the 10,000-mile oil drain interval with B20 suggests that the total fuel content in the oil could reach 12%, compared to 5% for operation on ULSD. Analysis of the oil samples also included measurement of total acid number, total base number, viscosity, soot, metals and wear scar; however, little difference in these parameters was noted.

He, X.; Williams, A.; Christensen, E.; Burton, J.; McCormick, R.

2011-12-01T23:59:59.000Z

358

Homogeneous Hydrogenation of CO2 to Methyl Formate Utilizing Switchable Ionic Liquids  

SciTech Connect (OSTI)

Capture of CO2 and subsequent hydrogenation allows for base/alcohol-catalyzed conversion of CO2 to methylformate in one pot. The conversion of CO2 proceeds via alkylcarbonates, to formate salts and then formate esters, which can be catalyzed by base and alcohol with the only byproduct being water. The system operates at mild conditions (300 psi H2, 140 ?C). Reactivity is strongly influenced by temperature and choice of solvent. In the presence of excess of base (DBU) formate is predominant product while in excess of methanol methyl formate is major product. 110 ?C yields formate salts, 140 ?C promotes methylformate. The authors acknowledge internal Laboratory Directed Re-search and Development (LDRD) funding from Pacific Northwest National Laboratory (PNNL). PNNL is operated by Battelle for the U.S. Department of Energy.

Yadav, Mahendra (ORCID:0000000202660382); Linehan, John C.; Karkamkar, Abhijeet J.; Van Der Eide, Edwin F.; Heldebrant, David J.

2014-09-15T23:59:59.000Z

359

Regulated Emissions from Biodiesel Tested in Heavy-Duty Engines Meeting 2004 Emission Standards  

SciTech Connect (OSTI)

Biodiesel produced from soybean oil, canola oil, yellow grease, and beef tallow was tested in two heavy-duty engines. The biodiesels were tested neat and as 20% by volume blends with a 15 ppm sulfur petroleum-derived diesel fuel. The test engines were the following: 2002 Cummins ISB and 2003 DDC Series 60. Both engines met the 2004 U.S. emission standard of 2.5 g/bhp-h NO{sub x}+HC (3.35 g/kW-h) and utilized exhaust gas recirculation (EGR). All emission tests employed the heavy-duty transient procedure as specified in the U.S. Code of Federal Regulations. Reduction in PM emissions and increase in NO{sub x} emissions were observed for all biodiesels in all engines, confirming observations made in older engines. On average PM was reduced by 25% and NO{sub x} increased by 3% for the two engines tested for a variety of B20 blends. These changes are slightly larger in magnitude, but in the same range as observed in older engines. The cetane improver 2-ethyl hexyl nitrate was shown to have no measurable effect on NO{sub x} emissions from B20 in these engines, in contrast to observations reported for older engines. The effect of intake air humidity on NO{sub x} emissions from the Cummins ISB was quantified. The CFR NO{sub x}/humidity correction factor was shown to be valid for an engine equipped with EGR, operating at 1700 m above sea level, and operating on conventional or biodiesel.

McCormick, R. L.; Tennant, C. J.; Hayes, R. R.; Black, S.; Ireland, J.; McDaniel, T.; Williams, A.; Frailey, M.; Sharp, C. A.

2005-11-01T23:59:59.000Z

360

St. Louis Metro Biodiesel (B20) Transit Bus Evaluation: 12-Month Final Report  

SciTech Connect (OSTI)

The St. Louis Metro Bodiesel Transit Bus Evaluation project is being conducted under a Cooperative Research and Development Agreement between NREL and the National Biodiesel Board to evaluate the extended in-use performance of buses operating on B20 fuel. The objective of this research project is to compare B20 and ultra-low sulfur diesel buses in terms of fuel economy, veicles maintenance, engine performance, component wear, and lube oil performance.

Barnitt, R.; McCormick, R. L.; Lammert, M.

2008-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "methyl esters biodiesel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Impact of Biodiesel Impurities on the Performance and Durability of DOC, DPF and SCR Technologies  

SciTech Connect (OSTI)

It is estimated that operating continuously on a B20 fuel containing the current allowable ASTM specification limits for metal impurities in biodiesel could result in a doubling of ash exposure relative to lube-oil derived ash. The purpose of this study was to determine if a fuel containing metals at the ASTM limits could cause adverse impacts on the performance and durability of diesel emission control systems. An accelerated durability test method was developed to determine the potential impact of these biodiesel impurities. The test program included engine testing with multiple DPF substrate types as well as DOC and SCR catalysts. The results showed no significant degradation in the thermo-mechanical properties of cordierite, aluminum titanate, or silicon carbide DPFs after exposure to 150,000 mile equivalent biodiesel ash and thermal aging. However, exposure of a cordierite DPF to 435,000 mile equivalent aging resulted in a 69% decrease in the thermal shock resistance parameter. It is estimated that the additional ash from 150,000 miles of biodiesel use would also result in a moderate increases in exhaust backpressure for a DPF. A decrease in DOC activity was seen after exposure to 150,000 mile equivalent aging, resulting in higher HC slip and a reduction in NO{sub 2} formation. The metal-zeolite SCR catalyst experienced a slight loss in activity after exposure to 435,000 mile equivalent aging. This catalyst, placed downstream of the DPF, showed a 5% reduction in overall NOx conversion activity over the HDDT test cycle.

Williams, A.; McCormick, R.; Luecke, J.; Brezny, R.; Geisselmann, A.; Voss, K.; Hallstrom, K.; Leustek, M.; Parsons, J.; Abi-Akar, H.

2011-06-01T23:59:59.000Z

362

Biodiesel Vehicle and Infrastructure Codes and Standards Citations (Brochure), NREL (National Renewable Energy Laboratory)  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data CenterEnergyAuthorization for(EV) Road User Assessment SystemBiodiesel

363

Synthesis and Decarboxylative Coupling of Sulfonyl Acetic Esters  

E-Print Network [OSTI]

-product salts with CO 2 -making it a green alternative. Despite the potential of this methodology, surprisingly, very little 10 was done over the next two decades since Saegusa and Tsuji provided proof of concept. 8 In 2004, 11 Erin Burger, a fellow... the concentration; most of these reactions were run with an initial ester concentration of ~0.1 M. Increasing the reaction concentration to 0.2 M, with respect to substrate, typically results in 23 ~10% higher yields compared to those shown Table 1...

Weaver, Jimmie Dean

2010-04-28T23:59:59.000Z

364

Impact of Biodiesel Impurities on the Performance and Durability of DOC, DPF and SCR Technologies: Preprint  

SciTech Connect (OSTI)

An accelerated durability test method determined the potential impact of biodiesel ash impurities, including engine testing with multiple diesel particulate filter substrate types, as well as diesel oxidation catalyst and selective catalyst reduction catalysts. The results showed no significant degradation in the thermo-mechanical properties of a DPF after exposure to 150,000-mile equivalent biodiesel ash and thermal aging. However, exposure to 435,000-mile equivalent aging resulted in a 69% decrease in thermal shock resistance. A decrease in DOC activity was seen after exposure to 150,000-mile equivalent aging, resulting in higher hydrocarbon slip and a reduction in NO2 formation. The SCR catalyst experienced a slight loss in activity after exposure to 435,000-mile equivalent aging. The SCR catalyst, placed downstream of the DPF and exposed to B20 exhaust suffered a 5% reduction in overall NOx conversion activity over the HDDT test cycle. It is estimated that the additional ash from 150,000 miles of biodiesel use would also result in a moderate increases in exhaust backpressure for a DPF. The results of this study suggest that long-term operation with B20 at the current specification limits for alkali and alkaline earth metal impurities will adversely impact the performance of DOC, DPF and SCR systems.

Williams, A.; McCormick, R.; Luecke, J.; Brezny, R.; Geisselmann, A.; Voss, K.; Hallstrom, K.; Leustek, M.; Parsons, J.; Abi-Akar, H.

2011-04-01T23:59:59.000Z

365

Investigation of Bio-Diesel Fueled Engines under Low-Temperature Combustion Strategies  

SciTech Connect (OSTI)

In accordance with meeting DOE technical targets this research was aimed at developing and optimizing new fuel injection technologies and strategies for the combustion of clean burning renewable fuels in diesel engines. In addition a simultaneous minimum 20% improvement in fuel economy was targeted with the aid of this novel advanced combustion system. Biodiesel and other renewable fuels have unique properties that can be leveraged to reduce emissions and increase engine efficiency. This research is an investigation into the combustion characteristics of biodiesel and its impacts on the performance of a Low Temperature Combustion (LTC) engine, which is a novel engine configuration that incorporates technologies and strategies for simultaneously reducing NOx and particulate emissions while increasing engine efficiency. Generating fundamental knowledge about the properties of biodiesel and blends with petroleum-derived diesel and their impact on in-cylinder fuel atomization and combustion processes was an important initial step to being able to optimize fuel injection strategies as well as introduce new technologies. With the benefit of this knowledge experiments were performed on both optical and metal LTC engines in which combustion and emissions could be observed and measured under realistic conditions. With the aid these experiments and detailed combustion models strategies were identified and applied in order to improve fuel economy and simultaneously reduce emissions.

Chia-fon F. Lee; Alan C. Hansen

2010-09-30T23:59:59.000Z

366

Final report on LDRD project : biodiesel production from vegetable oils using slit-channel reactors.  

SciTech Connect (OSTI)

This report documents work done for a late-start LDRD project, which was carried out during the last quarter of FY07. The objective of this project was to experimentally explore the feasibility of converting vegetable (e.g., soybean) oils to biodiesel by employing slit-channel reactors and solid catalysts. We first designed and fabricated several slit-channel reactors with varying channel depths, and employed them to investigate the improved performance of slit-channel reactors over traditional batch reactors using a NaOH liquid catalyst. We then evaluated the effectiveness of several solid catalysts, including CaO, ZnO, MgO, ZrO{sub 2}, calcium gluconate, and heteropolyacid or HPA (Cs{sub 2.5}H{sub 0.5}PW{sub 12}O{sub 40}), for catalyzing the soybean oil-to-biodiesel transesterification reaction. We found that the slit-channel reactor performance improves as channel depth decreases, as expected; and the conversion efficiency of a slit-channel reactor is significantly higher when its channel is very shallow. We further confirmed CaO as having the highest catalytic activity among the solid catalysts tested, and we demonstrated for the first time calcium gluconate as a promising solid catalyst for converting soybean oil to biodiesel, based on our preliminary batch-mode conversion experiments.

Kalu, E. Eric (FAMU-FSU College of Engineering, Tallahassee, FL); Chen, Ken Shuang

2008-01-01T23:59:59.000Z

367

Cooking Up More Uses for the Leftovers of Biofuel Production -N... http://www.nytimes.com/2007/08/08/business/08biodiesel.html?ei=... 1 of 3 8/8/07 10:49 AM  

E-Print Network [OSTI]

/08/08/business/08biodiesel.html?ei=... 1 of 3 8/8/07 10:49 AM August 8, 2007 THE ENERGY CHALLENGE Cooking Up More grass. They will have found innovative uses for a byproduct of the production of biodiesel fuel, glycerol. This, in turn, could help transform the biodiesel industry into something that more closely

Kimbrough, Steven Orla

368

Carbon-Oxygen Bond Activation in Esters by Platinum(0): Cleavage of the Less Reactive Bond  

E-Print Network [OSTI]

esters in the presence of trialkylphosphines to give -allyl addition products.2 Acetate and benzoate-O oxidative addition to give -allyl products. Vinyl esters (acetate and benzoate) were also reported of the solution. Reaction with Allyl Acetate. Treatment of 1 with 10 equiv of allyl acetate in p-xylene-d10 at 160

Jones, William D.

369

alternative 2-c-methyl-d-erythritol 4-phosphate: Topics by E...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Transportation Fuels? Alternative Fuels, the Smart Choice: Alternative fuels - biodiesel, electricity, ethanol (E85), natural gas 9 Alternating and Empty Alternating...

370

Structural Interactions within Lithium Salt Solvates: Cyclic Carbonates and Esters  

SciTech Connect (OSTI)

Only limited information is available regarding the manner in which cyclic carbonate and ester solvents coordinate Li+ cations in electrolyte solutions for lithium batteries. One approach to gleaning significant insight into these interactions is to examine crystalline solvate structures. To this end, eight new solvate structures are reported with ethylene carbonate, ?-butyrolactone and ?-valerolactone: (EC)3:LiClO4, (EC)2:LiClO4, (EC)2:LiBF4, (GBL)4:LiPF6, (GBL)1:LiClO4, (GVL)1:LiClO4, (GBL)1:LiBF4 and (GBL)1:LiCF3SO3. The crystal structure of (EC)1:LiCF3SO3 is also re-reported for comparison. These structures enable the factors which govern the manner in which the ions are coordinated and the ion/solvent packingin the solid-stateto be scrutinized in detail.

Seo, D. M.; Afroz, Taliman; Allen, Joshua L.; Boyle, Paul D.; Trulove, Paul C.; De Long, Hugh C.; Henderson, Wesley A.

2014-11-13T23:59:59.000Z

371

Quantitative relationships between structure and reactivity of aliphatic esters  

E-Print Network [OSTI]

~rity of' cstor and bsso s~lution (100 nl. ), 0. 02/76 ii &ol~rfty of nixture of' base and ester solution, 0. 01186 '! t, R& "inutco Qhm 1176 1/d x 10 (1/R 1/R ) x 10 1/t (1/2 - 1 ~Rt} x 1(P o 0 0, (~90' 7 9, 0 11. 0 1': 6 Q, ypCQ 1 940 Jg.... 210 1. 1$ 0, y~? -l. r4 0, 215 -O. g Wtc on i'. ethyl a b 0 1' 0. 00 -0. 'V -0, 67 1, 06 -0, 70 -1. 24 -1. 74 -2. 46 -0 69 (n-y) loC ~k 1 ~ 2iFgG 1, 169' d. 87l7 &47100 O. -fPjO 0. 1752 -0. 1700 a b a, :al'erenoe 5', roI'orenoo 9...

Yager, Billy Joe

1960-01-01T23:59:59.000Z

372

Isothermal vapor-liquid equilibria for 2-methyl-2-butanol + 2-methyl-1-butanol + 1-pentanol  

SciTech Connect (OSTI)

Vapor-liquid equilibria (VLE) for 2-methyl-2-butanol + 2-methyl-1-butanol and 2-methyl-2-butanol + 2-methyl-1-butanol + 1-pentanol have been measured at 373.15 K. The binary VLE results have been correlated by different liquid-phase activity coefficient models. The binary interaction parameters obtained from Wilson, NRTL, and UNIQUAC models in this and a previously study are used to predict the VLE data for the ternary system. Vapor-liquid equilibrium (VLE) data are necessary for the design of distillation processes.

Aucejo, A.; Burguet, M.C.; Monton, J.B.; Munoz, R.; Sanchotello, M.; Vazquez, M.I. (Univ. of Valencia (Spain). Dept. de Ingenieria Quimica)

1994-07-01T23:59:59.000Z

373

Biodiesel_Fuel_Management_Best_Practices_Report.pdf | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Year in Review: Top Five EEREDepartment ofEnergyEnergyBetterMake Fuels andBiodiesel Revs

374

Alternative Fuels Data Center: Biodiesel and Propane Fuel Buses for Dallas  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth (AOD)ProductssondeadjustsondeadjustAbout theOFFICE OF RESEARCHThermalPlug-inTexasFleetBiodieselCounty

375

E-Print Network 3.0 - acid 2-benzothiazolylthiomethyl ester Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

results for: acid 2-benzothiazolylthiomethyl ester Page: << < 1 2 3 4 5 > >> 1 GTQ, Chemistry 212, Dr. Glaser, FS96 --1 --GTQ on Lactones. (30 points, reaction chem., mechanistic...

376

E-Print Network 3.0 - acetoacetic acid esters Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sample search results for: acetoacetic acid esters Page: << < 1 2 3 4 5 > >> 1 GTQ, Chemistry 212, Dr. Glaser, FS96 --1 --GTQ on Michael Reactions. (20 points, synthesis,...

377

ICCBT 2008 -F -(07) pp79-94 Palm Biodiesel an Alternative Green Renewable Energy for the  

E-Print Network [OSTI]

ICCBT 2008 - F - (07) ­ pp79-94 ICCBT2008 Palm Biodiesel an Alternative Green Renewable Energy increased the interest on alternative energy sources. Clean and renewable biofuels have been touted as an alternative source of green renewable energy through a survey conducted from previously researched findings

Ducatelle, Frederick

378

Biodiesel Drives Florida Power & Light's EPAct Alternative Compliance Strategy; EPAct Alternative Fuel Transportation Program: Success Story (Fact Sheet)  

SciTech Connect (OSTI)

This success story highlights how Florida Power & Light Company has successfully complied with the Energy Policy Act of 1992 (EPAct) through Alternative Compliance using biodiesel technologies and how it has become a biofuel leader, reducing petroleum use and pollutant emissions throughout Florida.

Not Available

2010-05-01T23:59:59.000Z

379

Process Simulation and Evaluation of Alternative Solvents for Jatropha Curcas L. Seed Oil Extraction in Biodiesel Production  

E-Print Network [OSTI]

Jatropha curcas L. is a drought-resistant plant which can be grown in poor soil and marginal lands. The use of Jatropha seed oil to produce biodiesel has been widely studied in recent years. Results showed that it is one of the most promising...

Chiou, Ming-Hao

2012-10-19T23:59:59.000Z

380

Enhancement of CO2 and H2 Uptake for the Production of Biodiesel in Cupriavidus Necator  

SciTech Connect (OSTI)

Cupriavidus necator fixes CO{sub 2} through the Calvin-Benson-Bassham (CBB) cycle using electrons and energy obtained from the oxidation of H{sub 2}. Producing biodiesel-equivalent electrofuel from renewable CO{sub 2} and H{sub 2} has immense potential, especially if the fuel is compatible with the existing fuel infrastructure. This research addressed enhanced substrate utilization by focusing on two strategies: (1) optimizing transcriptional regulations to afford over-expression of Ribulose-1,5-bisphosphate carboxylase/oxygenase (RubisCO), the enzyme responsible for assimilation of CO{sub 2} into the CBB cycle; and (2) hydrogenase over-expression by introduction of additional copies of genes encoding a membrane-bound hydrogenase (MBH), a soluble hydrogenase (SH), and their maturation machinery to enhance oxidation of H{sub 2} to generate NAD(P)H and ATP required for CO{sub 2} fixation. Incorporation of these strategies into a single production strain resulted in 6-fold CO{sub 2} and 3-fold H{sub 2} uptake improvement, in vitro, with the overarching goal of providing abundant reducing equivalents towards the economic production of biodiesel in C. necator.

Sullivan, R. P.; Eckert, C. A.; Balzer, G. J.; Yu, J.; Maness, P. C.

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "methyl esters biodiesel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

O uso do biodiesel de mamona como fonte alternativa de energia : possveis repercusses sobre o semi-rido.  

E-Print Network [OSTI]

??The aim of this project was to study bio-diesel fuel as an alternative source of renewable, non-polluting, environmentally friendly energy, given contemporary societys concerns with (more)

Adriana Aparecida Isola Vilar

2006-01-01T23:59:59.000Z

382

Biodiesel Emissions Testing with a Modern Diesel Engine - Equipment Only: Cooperative Research and Development Final Report, CRADA Number CRD-10-399  

SciTech Connect (OSTI)

To evaluate the emissions and performance impact of biodiesel in a modern diesel engine equipped with a diesel particulate filter. This testing is in support of the Non-Petroleum Based Fuels (NPBF) 2010 Annual Operating Plan (AOP).

Williams, A.

2013-06-01T23:59:59.000Z

383

Experimental Pathology Laboratories, Inc. Methyl-Tertiary-Butyl Ether  

E-Print Network [OSTI]

COORDINATOR'S REPORT FOR LIFETIME CARCINOGENICITY STUDY OF METHYL-TERTIARY-BUTYL ETHER (MTBE) IN SPRAGUE CARCINOGENICITY STUDY OF METHYL-TERTIARY-BUTYL ETHER (MTBE) IN SPRAGUE-DAWLEY RATS CONDUCTED AT THE CANCER

Baker, Chris I.

384

Comparative Dynamics of Leucine Methyl Groups in FMOC-Leucine...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Dynamics of Leucine Methyl Groups in FMOC-Leucine and in a ProteinHydrophobic Core Probed by Solid-State Deuteron Comparative Dynamics of Leucine Methyl Groups in FMOC-Leucine and...

385

Sub-millimeter sized methyl butanoate droplet combustion: Microgravity experiments  

E-Print Network [OSTI]

-dependent, sphero-symmetric droplet combustion simulation that includes detailed gas phase chemical kineticsSub-millimeter sized methyl butanoate droplet combustion: Microgravity experiments and detailed 2012 Abstract Combustion characteristics of isolated sub-millimeter sized methyl butanoate (MB

Walter, M.Todd

386

Vapor-liquid equilibria for systems of 1-butanol with 2-methyl-1-butanol, 3-methyl-1-butanol, 2-methyl-2-butanol, and 3-methyl-2-butanol at 30 and 100 kPa  

SciTech Connect (OSTI)

Vapor-liquid equilibrium data were measured for binary systems of 1-butanol with 2-methyl-1-butanol, 3-methyl-1-butanol, 2-methyl-2-butanol, and 3-methyl-2-butanol at 30 and 100 kPa. The experimental data obtained in this work are thermodynamically consistent according to a point-to-point consistency test, and deviation from ideal behavior is small in all cases. They can be equally well correlated with the Margules, Van Laar, Wilson, NRTL, and UNIQUAC equations.

Aucejo, A.; Burguet, M.C.; Monton, J.B.; Munoz, R.; Sanchotello, M.; Vazquez, M.I. (Univ. de Valencia (Spain). Dept. de Ingenieria Quimica)

1994-04-01T23:59:59.000Z

387

Federal and State Ethanol and Biodiesel Requirements (released in AEO2007)  

Reports and Publications (EIA)

The Energy Policy Act 2005 requires that the use of renewable motor fuels be increased from the 2004 level of just over 4 billion gallons to a minimum of 7.5 billion gallons in 2012, after which the requirement grows at a rate equal to the growth of the gasoline pool. The law does not require that every gallon of gasoline or diesel fuel be blended with renewable fuels. Refiners are free to use renewable fuels, such as ethanol and biodiesel, in geographic regions and fuel formulations that make the most sense, as long as they meet the overall standard. Conventional gasoline and diesel can be blended with renewables without any change to the petroleum components, although fuels used in areas with air quality problems are likely to require adjustment to the base gasoline or diesel fuel if they are to be blended with renewables.

2007-01-01T23:59:59.000Z

388

Effect of Storage on Stability of Biodiesel Produced from Selected Seed Oils  

E-Print Network [OSTI]

Abstract: This work reports the results of the study of the effect of storage on the physico-chemical properties of biodiesel produced from Ricinus communis (Castor), Heavea brasiliensis (Rubber), Gossypium hirsutum (Cotton), Azadirachta indica (Neem), Glycin max (Soya bean), and Jatropha curcas (Jatropha oils) stored in an open air environment for a period of ten months. At the end of this test period, peroxide value of JME increased to (126.60meq/Kg),CME(71.75meq/Kg),SME(77.80meq/Kg),NME(111.65meq/K g), COME (59.65meq/Kg), RME (162.55meq/Kg), kinematic viscosity JME

M. Ndana; B. Garba; L. G. Hassan; U. Z. Faruk

389

ZnO nanoparticle catalysts for use in biodiesel production and method of making  

SciTech Connect (OSTI)

A method of forming a biodiesel product and a heterogeneous catalyst system used to form said product that has a high tolerance for the presence of water and free fatty acids (FFA) in the oil feedstock is disclosed. This catalyst system may simultaneously catalyze both the esterification of FAA and the transesterification of triglycerides present in the oil feedstock. The catalyst system is comprised of a mixture of zinc oxide and a second metal oxide. The zinc oxide includes a mixture of amorphous zinc oxide and zinc oxide nanocrystals, the zinc nanocrystals having a mean grain size between about 20 and 80 nanometers with at least one of the nanocrystals including a mesopore having a diameter of about 5 to 15 nanometers. Preferably, the second metal oxide is a lanthanum oxide, the lanthanum oxide being selected as one from the group of La.sub.2CO.sub.5, LaOOH, and combinations or mixtures thereof.

Yan, Shuli; Salley, Steven O; Ng, K. Y. Simon

2014-11-25T23:59:59.000Z

390

Impact of Biodiesel on the Oxidation Kinetics and Morphology of Diesel Particulate  

SciTech Connect (OSTI)

We compare the oxidation characteristics of four different diesel particulates generated with a modern light-duty engine. The four particulates represent engine fueling with conventional ultra-low sulfur diesel (ULSD), biodiesel, and two intermediate blends of these fuels. The comparisons discussed here are based on complementary measurements implemented in a laboratory micro-reactor, including temperature programmed desorption and oxidation, pulsed isothermal oxidation, and BET surface area. From these measurements we have derived models that are consistent with the observed oxidation reactivity differences. When accessible surface area effects are properly accounted for, the oxidation kinetics of the fixed carbon components were found to consistently exhibit an Arrhenius activation energy of 113 6 kJ/mol. Release of volatile carbon from the as-collected particulate appears to follow a temperaturedependent rate law.

Strzelec, Andrea [ORNL] [ORNL; Toops, Todd J [ORNL] [ORNL; Daw, C Stuart [ORNL] [ORNL

2011-01-01T23:59:59.000Z

391

E-Print Network 3.0 - amplified methylation polymorphism Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Environmental Sciences and Ecology 2 Infraspecific DNA Methylation Polymorphism in Cotton (Gossypium Summary: Infraspecific DNA Methylation Polymorphism in Cotton (Gossypium...

392

Investigation of the Effects of Biodiesel-based Na on Emissions Control Components  

SciTech Connect (OSTI)

A single-cylinder diesel engine was used to investigate the impact of biodiesel-based Na on emissions control components using specially blended 20% biodiesel fuel (B20). The emissions control components investigated were a diesel oxidation catalyst (DOC), a Cu-zeolite-based NH{sub 3}-SCR (selective catalytic reduction) catalyst, and a diesel particulate filter (DPF). Both light-duty vehicle, DOC-SCR-DPF, and heavy-duty vehicle, DOC-DPF-SCR, emissions control configurations were employed. The accelerated Na aging is achieved by introducing elevated Na levels in the fuel, to represent full useful life exposure, and periodically increasing the exhaust temperature to replicate DPF regeneration. To assess the validity of the implemented accelerated Na aging protocol, engine-aged lean NO{sub x} traps (LNTs), DOCs and DPFs are also evaluated. To fully characterize the impact on the catalytic activity the LNT, DOC and SCR catalysts were evaluated using a bench flow reactor. The evaluation of the aged DOC samples and LNT show little to no deactivation as a result of Na contamination. However, the SCR in the light-duty configuration (DOC-SCR-DPF) was severely affected by Na contamination, especially when NO was the only fed NO{sub x} source. In the heavy-duty configuration (DOC-DPF-SCR), no impact is observed in the SCR NO{sub x} reduction activity. Electron probe micro-analysis (EPMA) reveals that Na contamination on the LNT, DOC, and SCR samples is present throughout the length of the catalysts with a higher concentration on the washcoat surface. In both the long-term engine-aged DPF and the accelerated Na-aged DPFs, there is significant Na ash present in the upstream channels; however, in the engine-aged sample lube oil-based ash is the predominant constituent.

Brookshear, D. William [University of Tennessee, Knoxville (UTK); Nguyen, Ke [University of Tennessee, Knoxville (UTK); Toops, Todd J [ORNL; Bunting, Bruce G [ORNL; Howe, Janet E [ORNL

2012-01-01T23:59:59.000Z

393

Insights antifibrotic mechanism of methyl palmitate: Impact on nuclear factor kappa B and proinflammatory cytokines  

SciTech Connect (OSTI)

Fibrosis accompanies most chronic liver disorders and is a major factor contributing to hepatic failure. Therefore, the need for an effective treatment is evident. The present study was designed to assess the potential antifibrotic effect of MP and whether MP can attenuate the severity of oxidative stress and inflammatory response in chronic liver injury. Male albino rats were treated with either CCl{sub 4} (1 ml/kg, twice a week) and/or MP (300 mg/kg, three times a week) for six weeks. CCl{sub 4}-intoxication significantly increased liver weight, serum aminotransferases, total cholesterol and triglycerides while decreased albumin level and these effects were prevented by co-treatment with MP. As indicators of oxidative stress, CCl{sub 4}-intoxication caused significant glutathione depletion and lipid peroxidation while MP co-treatment preserved them within normal values. As markers of fibrosis, hydroxyproline content and ?-SMA expression increased markedly in the CCl{sub 4} group and MP prevented these alterations. Histopathological examination by both light and electron microscope further confirmed the protective efficacy of MP. To elucidate the antifibrotic mechanisms of MP, the expression of NF-?B, iNOS and COX-2 and the tissue levels of TNF-? and nitric oxide were assessed; CCl{sub 4} increased the expression of NF-?B and all downstream inflammatory cascade while MP co-treatment inhibited them. Collectively these findings indicate that MP possesses a potent antifibrotic effect which may be partly a consequence of its antioxidant and anti-inflammatory properties. -- Highlights: ? Methyl palmitate is free fatty acid methyl ester. ? It possesses a strong antifibrotic effect. ? It inhibits NF-?B and the consequent proinflammatory and oxidative stress response.

Mantawy, Eman M.; Tadros, Mariane G. [Department of Pharmacology and Toxicology, Faculty of Pharmacy, Ain Shams University, Cairo (Egypt)] [Department of Pharmacology and Toxicology, Faculty of Pharmacy, Ain Shams University, Cairo (Egypt); Awad, Azza S. [Department of Pharmacology and Toxicology, Faulty of Pharmacy, Al-Azhar University, Cairo (Egypt)] [Department of Pharmacology and Toxicology, Faulty of Pharmacy, Al-Azhar University, Cairo (Egypt); Hassan, Dina A.A. [Department of Histology, Faculty of Medicine, Al-Azhar University, Cairo (Egypt)] [Department of Histology, Faculty of Medicine, Al-Azhar University, Cairo (Egypt); El-Demerdash, Ebtehal, E-mail: ebtehal_dm@yahoo.com [Department of Pharmacology and Toxicology, Faculty of Pharmacy, Ain Shams University, Cairo (Egypt)] [Department of Pharmacology and Toxicology, Faculty of Pharmacy, Ain Shams University, Cairo (Egypt)

2012-01-01T23:59:59.000Z

394

Lubricant return comparison of naphthenic and polyol ester oils in R-134a household refrigeration applications  

SciTech Connect (OSTI)

This paper presents mineral oils and polyol esters as possible lubricant options for domestic refrigeration applications employing R-134a as the heat exchange fluid. A performance comparison, based on data presented, is made between the mineral oils and polyol esters evaluated. To more closely examine lubricant return with N-70 and R-134a and ensure that the oil is not contributing to any deterioration in efficiency due to its accumulation in evaporators, a special test unit was designed with a difficult oil return configuration and its performance carefully monitored. Oil return with a hydrofluorocarbon-miscible polyol ester, R-133-O was also evaluated in this setup and its performance results compared to those obtained with the naphthenic refrigeration oil.

Reyes-Gavilan, J.L.; Flak, G.T.; Tritcak, T.R. [Witco Corp., Oakland, NJ (United States)

1996-12-31T23:59:59.000Z

395

Oxidation and methylation of dissolved elemental mercury by anaerobic bacteria  

SciTech Connect (OSTI)

Methylmercury is a neurotoxin that poses significant health risks to humans. Some anaerobic sulphate- and iron-reducing bacteria can methylate oxidized forms of mercury, generating methylmercury1-4. One strain of sulphate-reducing bacteria (Desulfovibrio desulfuricans ND132) can also methylate elemental mercury5. The prevalence of this trait among different bacterial strains and species remains unclear, however. Here, we compare the ability of two strains of the sulphate-reducing bacterium Desulfovibrio and one strain of the iron-reducing bacterium Geobacter to oxidise and methylate elemental mercury in a series of laboratory incubations. Experiments were carried out under dark, anaerobic conditions, in the presence of environmentally-relevant concentrations of elemental mercury. We report differences in the ability of these organisms to oxidise and methylate elemental mercury. In line with recent findings5, we show that Desulfovibrio desulfuricans ND132 can both oxidise and methylate elemental mercury. However, the rate of methylation of elemental mercury is only about one third the rate of methylation of oxidized mercury. We also show that Desulfovibrio alaskensis G20 can oxidise, but not methylate, elemental mercury. Geobacter sulfurreducens PCA is able to oxidise and methylate elemental mercury in the presence of cysteine. We suggest that the activity of methylating and non-methylating bacteria may together enhance the formation of methylmercury in anaerobic environments.

Hu, Haiyan [ORNL] [ORNL; Lin, Hui [ORNL] [ORNL; Zheng, Wang [ORNL] [ORNL; Tomanicek, Stephen J [ORNL] [ORNL; Johs, Alexander [ORNL] [ORNL; Feng, Xinbin [ORNL] [ORNL; Elias, Dwayne A [ORNL] [ORNL; Liang, Liyuan [ORNL] [ORNL; Liang, Liyuan [ORNL] [ORNL; Gu, Baohua [ORNL] [ORNL

2013-01-01T23:59:59.000Z

396

Viscosity of aqueous and cyanate ester suspensions containing alumina nanoparticles  

SciTech Connect (OSTI)

The viscosities of both aqueous and cyanate ester monomer (BECy) based suspensions of alumina nanoparticle were studied. The applications for these suspensions are different: aqueous suspensions of alumina nanoparticles are used in the production of technical ceramics made by slip casting or tape casting, and the BECy based suspensions are being developed for use in an injection-type composite repair resin. In the case of aqueous suspensions, it is advantageous to achieve a high solids content with low viscosity in order to produce a high quality product. The addition of a dispersant is useful so that higher solids content suspensions can be used with lower viscosities. For BECy suspensions, the addition of nanoparticles to the BECy resin is expected to enhance the mechanical properties of the cured composite. The addition of saccharides to aqueous suspensions leads to viscosity reduction. Through DSC measurements it was found that the saccharide molecules formed a solution with water and this resulted in lowering the melting temperature of the free water according to classic freezing point depression. Saccharides also lowered the melting temperature of the bound water, but this followed a different rule. The shear thinning and melting behaviors of the suspensions were used to develop a model based on fractal-type agglomeration. It is believed that the structure of the particle flocs in these suspensions changes with the addition of saccharides which leads to the resultant viscosity decrease. The viscosity of the BECy suspensions increased with solids content, and the viscosity increase was greater than predicted by the classical Einstein equation for dilute suspensions. Instead, the Mooney equation fits the viscosity behavior well from 0-20 vol% solids. The viscosity reduction achieved at high particle loadings by the addition of benzoic acid was also investigated by NMR. It appears that the benzoic acid interacts with the surface of the alumina particle which may be the cause of the viscosity reduction. The flow behavior of alumina particles in water and BECy is markedly different. Aqueous alumina suspensions are shear thinning at all alumina loadings and capable of 50 vol% loading before losing fluidity whereas BECy/alumina suspensions show Newtonian behavior up to 5 vol%, and above 5 vol% show shear thinning at all shear rates. Highly loaded suspensions (i.e. 20vol% alumina) exhibit shear thinning at low and moderate shear rates and shear thickening at higher shear rates. The maximum particle loading for a fluid suspension, in this case, appears to be about 20 vol%. The difference in the viscosity of these suspensions must be related to the solvent-particle interactions for each system. The reason is not exactly known, but there are some notable differences between BECy and water. Water molecules are {approx}0.28 nm in length and highly hydrogen bonded with a low viscosity (1 mPa's) whereas in the cyanate ester (BECy) system, the solvent molecule is about 1.2 nm, in the largest dimension, with surfaces of varied charge distribution throughout the molecule. The viscosity of the monomer is also reasonably low for organic polymer precursor, about 7 mPa's. Nanoparticles in water tend to agglomerate and form flocs which are broken with the shear force applied during viscosity measurement. The particle-particle interaction is very important in this system. In BECy, the particles appear to be well dispersed and not as interactive. The solvent-particle interaction appears to be most important. It is not known exactly how the alumina particles interact with the monomer, but NMR suggests hydrogen bonding. These hydrogen bonds between the particle and monomer could very well affect the viscosity. A conclusion that can be reached in this work is that the presence of hydroxyl groups on the surface of the alumina particles is significant and seems to affect the interactions between other particles and the solvent. Thus, the hydrogen bonding between particles, particle/additive and/or particle/solvent dictates the behavior of nanos

Lawler, Katherine

2009-08-05T23:59:59.000Z

397

Production of methyl tert-alkyl ethers  

SciTech Connect (OSTI)

The transition to the use of unleaded gasolines has required the replacement of tetraethyl lead by oxygen-containing compounds such as methanol, ethanol, and ethers, which are termed {open_quotes}oxygenates{close_quotes} in the technical literature. These may be used in commercial gasolines in amounts of 10-15% by volume, equivalent to 2% oxygen by weight. When methyl tert-butyl ether (MTBE) is used, the oxygen content may amount to 2.7% by weight. This oxygenate gives a significant improvement of knock resistance of naphtha fractions, the greatest effects being observed for straight-run naphthas and reformer naphthas produced under normal conditions; the MTBE also improves the engine power and economy characteristics and lowers the carbon monoxide content in the exhaust by 15-30% and the hydrocarbon content by 7-8%. This paper describes methods for the production of MTBE and also methyl tert-alkyl ethers.

Trofimov, V.A.

1995-01-01T23:59:59.000Z

398

Photocatalyzed multiple additions of amines to {alpha}, {beta}-unsaturated esters and nitriles  

SciTech Connect (OSTI)

Photoelectron-transfer-catalyzed intermolecular carbon-carbon bond formation of primary, secondary, and tertiary amines with {alpha}, {beta}-unsaturated esters and nitriles using photosensitizers such as anthraquinone, acridone, and dicyanoanthracene has been investigated. The addition of {alpha}-aminoalkyl radicals, generated via photoelectron-transfer processes, to olefinic substrates and the subsequent 1,5-hydrogen abstraction reactions of the amine-olefin adduct radicals lead to a number of interesting multiple-olefin-added products. The adducts of the primary and secondary amines with {alpha}, {beta}-unsaturated esters undergo further cyclizations to give spiro and cyclic lactams, respectively.

Das, S.; Kumar, J.S.D.; Thomas, K.G.; Shivaramayya, K. [Regional Research Lab., Trivandrum (India); George, M.V. [Regional Research Lab., Trivandrum (India)]|[Univ. of Notre Dame, IN (United States)

1994-02-11T23:59:59.000Z

399

Anti-inflammatory activity of methyl palmitate and ethyl palmitate in different experimental rat models  

SciTech Connect (OSTI)

Methyl palmitate (MP) and ethyl palmitate (EP) are naturally occurring fatty acid esters reported as inflammatory cell inhibitors. In the current study, the potential anti-inflammatory activity of MP and EP was evaluated in different experimental rat models. Results showed that MP and EP caused reduction of carrageenan-induced rat paw edema in addition to diminishing prostaglandin E2 (PGE2) level in the inflammatory exudates. In lipopolysaccharide (LPS)-induced endotoxemia in rats, MP and EP reduced plasma levels of tumor necrosis factor-? (TNF-?) and interleukin-6 (IL-6). MP and EP decreased NF-?B expression in liver and lung tissues and ameliorated histopathological changes caused by LPS. Topical application of MP and EP reduced ear edema induced by croton oil in rats. In the same animal model, MP and EP reduced neutrophil infiltration, as indicated by decreased myeloperoxidase (MPO) activity. In conclusion, this study demonstrates the effectiveness of MP and EP in combating inflammation in several experimental models. -- Highlights: ? Efficacy of MP and EP in combating inflammation was displayed in several models. ? MP and EP reduced carrageenan-induced rat paw edema and prostaglandin E2 level. ? MP and EP decreased TNF-? and IL-6 levels in experimental endotoxemia. ? MP and EP reduced NF-?B expression and histological changes in rat liver and lung. ? MP and EP reduced croton oil-induced ear edema and neutrophil infiltration.

Saeed, Noha M. [Department of Pharmacology and Toxicology, Faculty of Pharmacy, Egyptian Russian University, Cairo (Egypt)] [Department of Pharmacology and Toxicology, Faculty of Pharmacy, Egyptian Russian University, Cairo (Egypt); El-Demerdash, Ebtehal [Department of Pharmacology and Toxicology, Faculty of Pharmacy, Ain Shams University, Cairo (Egypt)] [Department of Pharmacology and Toxicology, Faculty of Pharmacy, Ain Shams University, Cairo (Egypt); Abdel-Rahman, Hanaa M. [Department of Pharmacology and Toxicology, Faculty of Pharmacy, Egyptian Russian University, Cairo (Egypt)] [Department of Pharmacology and Toxicology, Faculty of Pharmacy, Egyptian Russian University, Cairo (Egypt); Algandaby, Mardi M. [Department of Biology (Botany), Faculty of Science, King Abdulaziz University, Jeddah (Saudi Arabia)] [Department of Biology (Botany), Faculty of Science, King Abdulaziz University, Jeddah (Saudi Arabia); Al-Abbasi, Fahad A. [Department of Biochemistry, Faculty of Science, King Abdulaziz University, Jeddah (Saudi Arabia)] [Department of Biochemistry, Faculty of Science, King Abdulaziz University, Jeddah (Saudi Arabia); Abdel-Naim, Ashraf B., E-mail: abnaim@pharma.asu.edu.eg [Department of Pharmacology and Toxicology, Faculty of Pharmacy, Ain Shams University, Cairo (Egypt)

2012-10-01T23:59:59.000Z

400

The UV/H2O2 advanced oxidation process in UV disinfection units : removal of selected phosphate esters by hydroxyl radical  

E-Print Network [OSTI]

In this work, the issue of how to remove phosphate esters from drinking water is examined. From the various treatment processes available, the oxidation of phosphate esters through hydroxyl radical generated by the UV/H202 ...

Machairas, Alexandros, 1980-

2004-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "methyl esters biodiesel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

{gamma} Irradiation-induced degradation of organochlorinated pollutants in fatty esters and in Cod  

SciTech Connect (OSTI)

The {gamma} irradiation-induced degradation of 2,2-bis(4-chlorophenyl)-1,1,1-trichloroethane (DDT), 2,2-bis(4-chlorophenyl)-1,1-dichloroethane (DDD), and 2,2-bis(4-chlorophenyl)-1,1-dichloroethylene (DDE) dissolved in methyl myristate and methyl oleate was studied. DDT and DDE produced DDD and 2,2-bis(4-chlorophenyl)chloroethylene (DDMU) respectively, in agreement with a previous study performed with aliphatic solvents. The degradation of these two former compounds was larger in methyl myristate than in methyl oleate and addition products between methyl myristate and the organochlorines were found. While DDD, DDE, and many PCB congeners in a cod sample were not measurably degraded at 15 KGy, DDT underwent 30% degradation. 9 refs., 1 fig., 2 tabs.

Lepine, F.L.; Brochu, F.; Milot, S. [Institut Armand-Frappier, Quebec (Canada)] [and others

1995-02-01T23:59:59.000Z

402

Lithium Diisopropylamide-Mediated Reactions of Imines, Unsaturated Esters, Epoxides, and Aryl Carbamates  

E-Print Network [OSTI]

Lithium Diisopropylamide-Mediated Reactions of Imines, Unsaturated Esters, Epoxides, and Aryl: Several reactions mediated by lithium diisopropylamide (LDA) with added hexamethylphos- phoramide (HMPA, and selectivities of organolithium reactions.1 A preponderance of what is known about solvation of lithium ions

Collum, David B.

403

A density functional theory model of mechanically activated silyl ester hydrolysis  

SciTech Connect (OSTI)

To elucidate the mechanism of the mechanically activated dissociation of chemical bonds between carboxymethylated amylose (CMA) and silane functionalized silicon dioxide, we have investigated the dissociation kinetics of the bonds connecting CMA to silicon oxide surfaces with density functional calculations including the effects of force, solvent polarizability, and pH. We have determined the activation energies, the pre-exponential factors, and the reaction rate constants of candidate reactions. The weakest bond was found to be the silyl ester bond between the silicon and the alkoxy oxygen atom. Under acidic conditions, spontaneous proton addition occurs close to the silyl ester such that neutral reactions become insignificant. Upon proton addition at the most favored position, the activation energy for bond hydrolysis becomes 31 kJ?mol{sup ?1}, which agrees very well with experimental observation. Heterolytic bond scission in the protonated molecule has a much higher activation energy. The experimentally observed bi-exponential rupture kinetics can be explained by different side groups attached to the silicon atom of the silyl ester. The fact that different side groups lead to different dissociation kinetics provides an opportunity to deliberately modify and tune the kinetic parameters of mechanically activated bond dissociation of silyl esters.

Pill, Michael F.; Schmidt, Sebastian W. [Department of Applied Sciences and Mechatronics, Munich University of Applied Sciences, Lothstr. 34, 80335 Munich (Germany) [Department of Applied Sciences and Mechatronics, Munich University of Applied Sciences, Lothstr. 34, 80335 Munich (Germany); Institut fr Physikalische Chemie, Christian-Albrechts-Universitt zu Kiel, Olshausenstrae 40, 24098 Kiel (Germany); Center for Nanoscience (CeNS), Geschwister-Scholl-Platz 1, 80539 Munich (Germany); Beyer, Martin K. [Institut fr Physikalische Chemie, Christian-Albrechts-Universitt zu Kiel, Olshausenstrae 40, 24098 Kiel (Germany) [Institut fr Physikalische Chemie, Christian-Albrechts-Universitt zu Kiel, Olshausenstrae 40, 24098 Kiel (Germany); Institut fr Ionenphysik und Angewandte Physik, Leopold-Franzens-Universitt Innsbruck, Technikerstrae 25, 6020 Innsbruck (Austria); Clausen-Schaumann, Hauke [Department of Applied Sciences and Mechatronics, Munich University of Applied Sciences, Lothstr. 34, 80335 Munich (Germany) [Department of Applied Sciences and Mechatronics, Munich University of Applied Sciences, Lothstr. 34, 80335 Munich (Germany); Center for Nanoscience (CeNS), Geschwister-Scholl-Platz 1, 80539 Munich (Germany); Kersch, Alfred, E-mail: akersch@hm.edu [Department of Applied Sciences and Mechatronics, Munich University of Applied Sciences, Lothstr. 34, 80335 Munich (Germany)] [Department of Applied Sciences and Mechatronics, Munich University of Applied Sciences, Lothstr. 34, 80335 Munich (Germany)

2014-01-28T23:59:59.000Z

404

E-Print Network 3.0 - acid ester derivatives Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sample search results for: acid ester derivatives Page: << < 1 2 3 4 5 > >> 1 Exam 2, Chemistry 212, Dr. Glaser, FS96 --1 --C h e m i s t r y 2 1 2 --F a l l S e m e s t e r 1 9 9...

405

Cationic Hyperbranched Poly(amino ester): A Novel Class of DNA Condensing Molecule with Cationic  

E-Print Network [OSTI]

molecules.3 It is generally accepted that the high transfection efficiency of PEI or PAMAM comparedCationic Hyperbranched Poly(amino ester): A Novel Class of DNA Condensing Molecule with Cationic to utilize these highly branched molecules in a variety of applications involving combinatorial chemistry

Park, Jong-Sang

406

Methyl viologen radical reactions with several oxidizing agents. [Gamma Radiation  

SciTech Connect (OSTI)

The rates of oxidation of the methyl viologen radical by peroxodisulfate and hydrogen peroxide has been investigated. The methyl viologen free radical was produced by pulse radiolysis. The reaction of the peroxodisulfate radical with the methyl viologen radical was first order in both species, and the reaction rate constant is reported. A el-radiation study revealed a chain decomposition of the peroxodisulfate radical involving the methyl viologen radical when methanol, ethanol, or 2-propanol was present. Loss of the methyl viologen radical was then no longer observed to be a simple first-order reaction. The reaction of hydrogen peroxide with the methyl viologen radical was very slow in the presence of 1 M methanol. A much faster reaction in the absence of methanol was interpreted to be a reaction of the methyl viologen radical with the peroxy radicals. Hydrogen peroxide, in contrast to the chain decomposition of peroxodisulfate radicals, does not participate in a chain reaction involving the methyl viologen radical and methanol. Rate constants for the reaction of methyl viologen radical with dichromate radical, iodate radical, and ferricyanide radical are reported.

Levey, G.; Ebbesen, T.W.

1983-01-01T23:59:59.000Z

407

Lithium modified zeolite synthesis for conversion of biodiesel-derived glycerol to polyglycerol  

SciTech Connect (OSTI)

Basic zeolite has received significant attention in the catalysis community. These zeolites modified with alkaline are the potential replacement for existing zeolite catalysts due to its unique features with added advantages. The present paper covers the preparation of lithium modified zeolite Y (Li-ZeY) and its activity for solvent free conversion of biodiesel-derived glycerol to polyglycerol via etherification process. The modified zeolite was well characterized by X-ray diffraction (XRD), Scanning Electron Microscope (SEM) and Nitrogen Adsorption. The SEM images showed that there was no change in morphology of modified zeolite structure after lithium modification. XRD patterns showed that the structure of zeolite was sustained after lithium modification. The surface properties of parent and modified zeolite was also observed N{sub 2} adsortion-desorption technique and found some changes in surface area and pore size. In addition, the basic strength of prepared materials was measured by Hammet indicators and found that basic strength of Li-ZeY was highly improved. This modified zeolite was found highly thermal stable and active heterogamous basic catalyst for conversion of solvent free glycerol to polyglycerol. This reaction was conducted at different temperatures and 260 C was found most active temperature for this process for reaction time from 6 to 12 h over this basic catalyst in the absence of solvent.

Ayoub, Muhammad, E-mail: muhammad.ayoub@petronas.com.my [Department of Chemical Engineering, Universiti Teknologi PETRONAS, 31750, Tronoh, Perak, Malaysia and School of Chemical Engineering, Universiti Sains Malaysia, 43000, Pinang (Malaysia); Abdullah, Ahmad Zuhairi, E-mail: chzuhairi@usm.my [School of Chemical Engineering, Universiti Sains Malaysia, 43000, Pinang (Malaysia); Inayat, Abrar, E-mail: abrar.inayat@petronas.com.my [Department of Chemical Engineering, Universiti Teknologi PETRONAS, 31750, Tronoh, Perak (Malaysia)

2014-10-24T23:59:59.000Z

408

IDAHO BIODIESEL INFRASTRUCTURE PROJECT DOE'S INITIATIVE ON COOPERATIVE PROGRAMS WITH STATES FOR RESEARCH, DEVELOPMENT AND DEMONSTRATION GRANT NO. DE-FC36-02GO12021. Final report  

SciTech Connect (OSTI)

The Idaho Energy Division issued a Request for Proposal (RFP) on March 14, 2006, inviting qualified licensed fuel wholesalers, fuel retailers, and vehicle fleet operators to provide proposals to construct and/or install infrastructure for biodiesel utilization in Idaho. The intent was to improve the ability of private and/or non-Federal public entities in Idaho to store, transport, or offer for sale biodiesel within the state. The RFP provided up $100,000 for co-funding the projects with a minimum 50% cash cost match. Four contracts were subsequetnly awarded that resulted in three new bidodiesel storage facilities immediately serving about 45 fueling stations from Sandpoint to Boise. The project also attracted considerable media attention and Idaho became more knowledgeable about biodiesel.

CROCKETT, JOHN

2006-12-31T23:59:59.000Z

409

Hydrogenated soy ethyl ester (HySEE) from ethanol and waste vegetable oil  

SciTech Connect (OSTI)

Biodiesel is gaining recognition in the United States as a renewable fuel which may be used as an alternative to diesel fuel without any modifications to the engine. Currently the cost of this fuel is the factor that limits its use. One way to reduce the cost of biodiesel is to use a less expensive form of vegetable oil such as waste oil from a processing plant. These operations use mainly hydrogenated soybean oil, some tallow and some Canola as their frying oils. It is estimated that there are several million pounds of waste vegetable oil from these operations. Additional waste frying oil is available from smaller processors, off-grade oil seeds and restaurants. This paper reports on developing a process to produce the first 945 liters (250 gallons) of HySEE using recipes developed at the University of Idaho; fuel characterization tests on the HySEE according to the ASAE proposed Engineering Practice for Testing of Fuels from Biological Materials, X552; short term injector coking tests and performance tests in a turbocharged, DI, CI engine; and a 300 hour screening test in a single cylinder, IDI, CI engine.

Peterson, C.; Reece, D.; Thompson, J. [Univ. of Idaho, Moscow, ID (United States)] [and others

1995-11-01T23:59:59.000Z

410

FLAME-SAMPLING PHOTOIONIZATION MASS SPECTROSCOPY - FINAL TECHNICAL REPORT  

SciTech Connect (OSTI)

Research focused on detailed studies of the complex combustion chemistry of oxygenated, bio-derived fuels. In particular, studies were done of the flame chemistry of simple methyl and ethyl esters chosen as surrogates for the long-chain esters that are primary constituents of biodiesel fuels. The principal goals of these studies were: (1) show how fuel-specific structural differences including degree of unsaturation, linear vs. branched chain structures, and methoxy vs. ethoxy functions affect fueldestruction pathways, (2) understand the chemistry leading to potential increases in the emissions of hazardous air pollutants including aldehydes and ketones inherent in the use of biodiesel fuels, and (3) define the key chemical reaction mechanisms responsible for observed reductions in polycyclic aromatic hydrocarbons and particulate matter when oxygenated fuels are used as replacements for conventional fuels.

Hansen, Nils

2013-02-12T23:59:59.000Z

411

ORTH/VIM proteins that regulate DNA methylation are functional ubiquitin E3 ligases  

E-Print Network [OSTI]

ORTH/VIM proteins that regulate DNA methylation are functional ubiquitin E3 ligases Edward Kraft1 methylation status in vivo. Keywords: RING, E3 ligase, DNA methylation, ubiquitylation, ORTH/VIM, SRA

Jacobsen, Steve

412

Host cells and methods for producing 3-methyl-2-buten-1-ol, 3-methyl-3-buten-1-ol, and 3-methyl-butan-1-ol  

DOE Patents [OSTI]

The invention provides for a method for producing a 5-carbon alcohol in a genetically modified host cell. In one embodiment, the method comprises culturing a genetically modified host cell which expresses a first enzyme capable of catalyzing the dephosphorylation of an isopentenyl pyrophosphate (IPP) or dimethylallyl diphosphate (DMAPP), such as a Bacillus subtilis phosphatase (YhfR), under a suitable condition so that 5-carbon alcohol is 3-methyl-2-buten-1-ol and/or 3-methyl-3-buten-1-ol is produced. Optionally, the host cell may further comprise a second enzyme capable of reducing a 3-methyl-2-buten-1-ol to 3-methyl-butan-1-ol, such as a reductase.

Chou, Howard H. (Berkeley, CA); Keasling, Jay D. (Berkeley, CA)

2011-07-26T23:59:59.000Z

413

OBSERVATIONS IN REACTIVITY BETWEEN BH CONTAINING COMPOUNDS AND ORGANOMETALLIC REAGENTS: SYNTHESIS OF BORONIC ACIDS, BORONIC ESTERS, AND MAGNESIUM HYDRIDES  

E-Print Network [OSTI]

Reaction of BH 3 :THF with magnesium hydride byproduct. A.It was also observed that magnesium hydride can partiallyACIDS, BORONIC ESTERS, AND MAGNESIUM HYDRIDES A dissertation

Clary, Jacob William

2012-01-01T23:59:59.000Z

414

Evaluation of bisphenol E cyanate ester for the resin-injection repair of advanced composites  

SciTech Connect (OSTI)

This thesis is a compilation of a general introduction and literature review that ties together the subsequent chapters which consist of two journal articles that have yet to be submitted for publication. The overall topic relates to the evaluation and application of a new class of cyanate ester resin with unique properties that lend it applicable to use as a resin for injection repair of high glass transition temperature polymer matrix composites. The first article (Chapter 2) details the evaluation and optimization of adhesive properties of this cyanate ester and alumina nanocomposites under different conditions. The second article (Chapter 3) describes the development and evaluation of an injection repair system for repairing delaminations in polymer matrix composites.

Wilber Yaote Lio

2009-12-19T23:59:59.000Z

415

The effects of solvent mixtures on the gel permeation chromatography of alkanes, fatty acids, and fatty acid esters  

E-Print Network [OSTI]

THE EFFECTS OF SOLVENT MIXTURES ON THE GEL PERMEATION CHROMATOGRAPHY OF ALKANES, FATTY ACIDS, AND FATTY ACID ESTERS A Thesis PATRICK LEE BOLTON Submitted to the Graduate College of Texas A&M University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE December 1985 Major Subject: Chemistry THE EFFECTS OP SOLVENT MIXTURES ON THE GEL PERMEATION CHROMATOGRAPHY OF ALKANES, FATTY ACIDS, AND FATTY ACID ESTERS A Thesis by PATRICK LEE BOLTON Approved...

Bolton, Patrick Lee

1985-01-01T23:59:59.000Z

416

E-Print Network 3.0 - arsenic methylation profiles Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: , urinary arsenic methylation profiles, and urothelial carcinoma susceptibility. Food Chem. Toxicol. 46, 929... and in vitro studies suggest that methylated arsenic...

417

The use of novel biodegradable, optically active and nanostructured poly(amide-ester-imide) as a polymer matrix for preparation of modified ZnO based bionanocomposites  

SciTech Connect (OSTI)

Highlights: Black-Right-Pointing-Pointer A novel biodegradable and nanostructured PAEI based on two amino acids, was synthesized. Black-Right-Pointing-Pointer ZnO nanoparticles were modified via two different silane coupling agents. Black-Right-Pointing-Pointer PAEI/modified ZnO BNCs were synthesized through ultrasound irradiation. Black-Right-Pointing-Pointer ZnO particles were dispersed homogeneously in PAEI matrix on nanoscale. Black-Right-Pointing-Pointer The effect of ZnO nanoparticles on the properties of synthesized polymer was examined. -- Abstract: A novel biodegradable and nanostructured poly(amide-ester-imide) (PAEI) based on two different amino acids, was synthesized via direct polycondensation of biodegradable N,N Prime -bis[2-(methyl-3-(4-hydroxyphenyl)propanoate)]isophthaldiamide and N,N Prime -(pyromellitoyl)-bis-L-phenylalanine diacid. The resulting polymer was characterized by FT-IR, {sup 1}H NMR, specific rotation, elemental analysis, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), X-ray diffraction (XRD) and field emission scanning electron microscopy (FE-SEM) analysis. The synthesized polymer showed good thermal stability with nano and sphere structure. Then PAEI/ZnO bionanocomposites (BNCs) were fabricated via interaction of pure PAEI and ZnO nanoparticles. The surface of ZnO was modified with two different silane coupling agents. PAEI/ZnO BNCs were studied and characterized by FT-IR, XRD, UV/vis, FE-SEM and TEM. The TEM and FE-SEM results indicated that the nanoparticles were dispersed homogeneously in PAEI matrix on nanoscale. Furthermore the effect of ZnO nanoparticle on the thermal stability of the polymer was investigated with TGA and DSC technique.

Abdolmaleki, Amir, E-mail: abdolmaleki@cc.iut.ac.ir [Department of Chemistry, Isfahan University of Technology, Isfahan 84156-83111, Islamic Republic of Iran (Iran, Islamic Republic of) [Department of Chemistry, Isfahan University of Technology, Isfahan 84156-83111, Islamic Republic of Iran (Iran, Islamic Republic of); Nanotechnology and Advanced Materials Institute, Isfahan University of Technology, Isfahan 84156-83111, Islamic Republic of Iran (Iran, Islamic Republic of); Mallakpour, Shadpour, E-mail: mallak@cc.iut.ac.ir [Organic Polymer Chemistry Research Laboratory, Department of Chemistry, Isfahan University of Technology, Isfahan 84156-83111, Islamic Republic of Iran (Iran, Islamic Republic of) [Organic Polymer Chemistry Research Laboratory, Department of Chemistry, Isfahan University of Technology, Isfahan 84156-83111, Islamic Republic of Iran (Iran, Islamic Republic of); Nanotechnology and Advanced Materials Institute, Isfahan University of Technology, Isfahan 84156-83111, Islamic Republic of Iran (Iran, Islamic Republic of); Borandeh, Sedigheh [Department of Chemistry, Isfahan University of Technology, Isfahan 84156-83111, Islamic Republic of Iran (Iran, Islamic Republic of)] [Department of Chemistry, Isfahan University of Technology, Isfahan 84156-83111, Islamic Republic of Iran (Iran, Islamic Republic of)

2012-05-15T23:59:59.000Z

418

Process for producing biodiesel, lubricants, and fuel and lubricant additives in a critical fluid medium  

DOE Patents [OSTI]

A process for producing alkyl esters useful in biofuels and lubricants by transesterifying glyceride- or esterifying free fatty acid-containing substances in a single critical phase medium is disclosed. The critical phase medium provides increased reaction rates, decreases the loss of catalyst or catalyst activity and improves the overall yield of desired product. The process involves the steps of dissolving an input glyceride- or free fatty acid-containing substance with an alcohol or water into a critical fluid medium; reacting the glyceride- or free fatty acid-containing substance with the alcohol or water input over either a solid or liquid acidic or basic catalyst and sequentially separating the products from each other and from the critical fluid medium, which critical fluid medium can then be recycled back in the process. The process significantly reduces the cost of producing additives or alternatives to automotive fuels and lubricants utilizing inexpensive glyceride- or free fatty acid-containing substances, such as animal fats, vegetable oils, rendered fats, and restaurant grease.

Ginosar, Daniel M.; Fox, Robert V.

2005-05-03T23:59:59.000Z

419

Methyl bromide emissions to the atmosphere from temperate woodland ecosystems  

E-Print Network [OSTI]

The environmental importance of methyl bromide (CH3Br) arises from its contribution to stratospheric ozone loss processes and, as a consequence, its emissions from anthropogenic sources are subject to the Montreal Protocol. A better understanding...

Drewer, Julia; Heal, Kate V; Smith, Keith A; Heal, Mathew R

2008-01-01T23:59:59.000Z

420

The Genetics of de novo Methylation in Arabidopsis thaliana  

E-Print Network [OSTI]

domains akin to UHRF1 and the VIM proteins. These proteinsthe VARIANT IN METHYLATION (VIM) family. In higher orderUHRF1 in mammal or the VIM proteins in plants. UHRF1/VIM

Greenberg, Maxim Van Cleef

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "methyl esters biodiesel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Regulation of yeast development by mRNA methylation  

E-Print Network [OSTI]

The internal methylation of mRNA post-transcriptionally is an essential component of the mRNA editing machinery in virtually every eukaryotic system. Despite this ubiquity, little is known about the relevance, consequences ...

Agarwala, Sudeep D

2012-01-01T23:59:59.000Z

422

akap12 promoter methylation: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

(MEK) with hydrogen peroxide (H2O2), is widely used in industry as a radicalThermal Hazard Analysis of Methyl Ethyl Ketone Peroxide Ron-Hsin Chang, Chi-Min Shu and Po-Yin Yeh...

423

Control of mercury methylation in wetlands through iron addition  

E-Print Network [OSTI]

Mason, R. P. ; Flegal, A. R. , Mercury speciation in the SanP. ; Flegal, A. R. , Decadal mercury trends in San FranciscoP. G. ; Nelson, D. C. , Mercury methylation from unexpected

Sedlak, David L; Ulrich, Patrick D

2009-01-01T23:59:59.000Z

424

Methyl arsenic adsorption and desorption behavior on iron oxides  

E-Print Network [OSTI]

METHYL ARSENIC ADSORPTION AND DESORPTION BEHAVIOR ON IRON OXIDES A Thesis by BRANDON JAMES LAFFERTY Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE May 2004 Major Subject: Soil Science METHYL ARSENIC ADSORPTION AND DESORPTION BEHAVIOR ON IRON OXIDES A Thesis by BRANDON JAMES LAFFERTY Submitted to Texas A&M University...

Lafferty, Brandon James

2005-08-29T23:59:59.000Z

425

The synthesis of some N-methylated aminoalkylphosphonic acids  

E-Print Network [OSTI]

(XLIII) were o heated with diethyl hydrogenphosphonate (XVI) at approximately 100 until the evolution of dimethylarnine (XXX) ceased. The 1-dimethyl- amino 1-alkenes (XLIV) reacted exothermically with diethyl hydro- genphosphonate (XVI) once... exothermically with methyl iodide at room temperature whereas the other eaters, which contained more bulky (R) substituents, did not. Secondly, the betaine obtained m the highest yield, N, N, N-trimethyl-N-(phosphono- methyl)ammonium hydroxide, mner salt...

Eikenberry, Jon Nathan

1966-01-01T23:59:59.000Z

426

Emissions From Various Biodiesel Sources Compared to a Range of Diesel Fuels in DPF Equipped Diesel Engines  

SciTech Connect (OSTI)

The purpose of this study was to measure the impact of various sources of petroleum-based and bio-based diesel fuels on regulated emissions and fuel economy in diesel particulate filter (DPF) equipped diesel engines. Two model year 2008 diesel engines were tested with nine fuels including a certification ultra-low sulfur diesel (ULSD), local ULSD, high aromatic ULSD, low aromatic ULSD, and twenty percent blends of biodiesel derived from algae, camelina, soy, tallow, and yellow grease. Regulated emissions were measured over the heavy duty diesel transient test cycle. Measurements were also made of DPF-out particle size distribution and total particle count from a 13-mode steady state test using a fast mobility particle sizer. Test engines were a 2008 Cummins ISB and a 2008 International Maxx Force 10, both equipped with actively regenerated DPFs. Fuel consumption was roughly 2% greater over the transient test cycle for the B20 blends versus certification ULSD in both engines, consistent with the slightly lower energy content of biodiesel. Unlike studies conducted on older model engines, these engines equipped with diesel oxidation catalysts and DPFs showed small or no measurable fuel effect on the tailpipe emissions of total hydrocarbons (THC), carbon monoxide (CO) and particulate matter (PM). No differences in particle size distribution or total particle count were seen in a comparison of certification ULSD and B20 soy, with the exception of engine idling conditions where B20 produced a small reduction in the number of nucleation mode particles. In the Cummins engine, B20 prepared from algae, camelina, soy, and tallow resulted in an approximately 2.5% increase in nitrogen oxides (NO{sub x}) compared to the base fuel. The International engine demonstrated a higher degree of variability for NO{sub x} emissions, and fuel effects could not be resolved (p > 0.05). The group of petroleum diesel test fuels produced a range of NO{sub x} emissions very similar to that caused by blending of biodiesel. Test cycles where an active regeneration of the DPF occurred resulted in a nearly threefold increase in NO{sub x} emissions and a 15% increase in fuel consumption. The full quantification of DPF regeneration events further complicates the accurate calculation of fuel impacts on emissions and fuel consumption.

Williams, A.; Burton, J.; Christensen, E.; McCormick, R. L.; Tester, J.

2011-01-01T23:59:59.000Z

427

Transportation and its Infrastructure  

E-Print Network [OSTI]

Biodiesel (esters) Bio oil Diesel (CxHy) carbon emissions.August (2006), 40:H-Bio, The Clean Diesel. eq. based onsynthetic diesel, biodiesel and bio oil. In addition, there

2007-01-01T23:59:59.000Z

428

A quantitative study of the effect of structure on the saponification rates of aliphatic esters  

E-Print Network [OSTI]

of aliphatic ~sters&" (H? ST 'I'basis& The agricul- tural and Hechanicul dolls~", e of Texas, iugust, 1960) ~ J 6 6 11, '. 9. , t 9 ' ~tt ', 10, 41 (199&). APPENDIX 41 TABLE Ssponificstion of Ethyl Acetate st 35 Ca Run 1 Run 2 Time, Resistance Nin... Bennyl Propiona te 14. 55 5. 477 4+041 Oi9992 )o219 Z ~ 420 0. 4604 Oe04956 9i553 TABLE Seoond Order Rate Constants for n-Butyrates Ester h35 2 ~ 1 -1 li aole sino Nethyl n Sutyrate Ethyl a-Butyrate a Propyl n Sutyrate Isopropyl n...

Gonzalez, Federico P

1961-01-01T23:59:59.000Z

429

Photoionization of methyl t-butyl ether (MTBE) and t-octyl methyl ether (TOME) and analysis of their pyrolyses by  

E-Print Network [OSTI]

Photoionization of methyl t-butyl ether (MTBE) and t-octyl methyl ether (TOME) and analysis 1999; accepted 20 July 1999 Abstract The pyrolysis products of neutral methyl-d3 t-butyl ether (MTBE-d3 from thermal cracking patterns. MTBE and TOME both exhibit base peaks at m/z 73 (which shifts to m/z 76

Morton, Thomas Hellman

430

Degradation of the molecular weight and nitrate ester content of cellulose nitrate on thermal aging. [PBX-9404  

SciTech Connect (OSTI)

Changes in molecular weight and nitrate ester content for cellulose nitrate (NC), either pure or as a constituent of PBX-9404, were determined as a function of time and temperature. Changes in the number-averaged molecular weight, M/sub n/, are described by the simple theory of random chain scission, and M/sub n/ is found to correlate well with nitrate ester loss. Significant differences are seen between NC aged in the isolated condition and aged as the binder in PBX-9404.

Leider, H R

1981-06-01T23:59:59.000Z

431

On the spherically symmetrical combustion of methyl decanoate droplets and comparisons with detailed numerical modeling  

E-Print Network [OSTI]

.e., 40­50% for CI compared to 25­30% for SI). As such, diesel power has the potential for an immediate impact on petroleum consumption, especially when conventional diesel is blended with bio-diesel fuels [3­5]. Blending diesel fuel with a fuel derived from sustainable sources will have an immediate impact

Walter, M.Todd

432

Nested methylation-specific polymerase chain reaction cancer detection method  

DOE Patents [OSTI]

A molecular marker-based method for monitoring and detecting cancer in humans. Aberrant methylation of gene promoters is a marker for cancer risk in humans. A two-stage, or "nested" polymerase chain reaction method is disclosed for detecting methylated DNA sequences at sufficiently high levels of sensitivity to permit cancer screening in biological fluid samples, such as sputum, obtained non-invasively. The method is for detecting the aberrant methylation of the p16 gene, O 6-methylguanine-DNA methyltransferase gene, Death-associated protein kinase gene, RAS-associated family 1 gene, or other gene promoters. The method offers a potentially powerful approach to population-based screening for the detection of lung and other cancers.

Belinsky, Steven A. (Albuquerque, NM); Palmisano, William A. (Edgewood, NM)

2007-05-08T23:59:59.000Z

433

Methods for detection of methyl-CpG dinucleotides  

DOE Patents [OSTI]

The invention provides methods for enriching methyl-CpG sequences from a DNA sample. The method makes use of conversion of cytosine residues to uracil under conditions in which methyl-cytosine residues are preserved. Additional methods of the invention enable to preservation of the context of me-CpG dinucleotides. The invention also provides a recombinant, full length and substantially pure McrA protein (rMcrA) for binding and isolation of DNA fragments containing the sequence 5'-C.sup.MeCpGG-3'. Methods for making and using the rMcrA protein, and derivatives thereof are provided.

Dunn, John J.

2013-01-29T23:59:59.000Z

434

Methods for detection of methyl-CpG dinucleotides  

DOE Patents [OSTI]

The invention provides methods for enriching methyl-CpG sequences from a DNA sample. The method makes use of conversion of cytosine residues to uracil under conditions in which methyl-cytosine residues are preserved. Additional methods of the invention enable to preservation of the context of me-CpG dinucleotides. The invention also provides a recombinant, full length and substantially pure McrA protein (rMcrA) for binding and isolation of DNA fragments containing the sequence 5'-C.sup.MeCpGG-3'. Methods for making and using the rMcrA protein, and derivatives thereof are provided.

Dunn, John J

2013-11-26T23:59:59.000Z

435

Methods for detection of methyl-CpG dinucleotides  

DOE Patents [OSTI]

The invention provides methods for enriching methyl-CpG sequences from a DNA sample. The method makes use of conversion of cytosine residues to uracil under conditions in which methyl-cytosine residues are preserved. Additional methods of the invention enable to preservation of the context of me-CpG dinucleotides. The invention also provides a recombinant, full length and substantially pure McrA protein (rMcrA) for binding and isolation of DNA fragments containing the sequence 5'-C.sup.MeCpGG-3'. Methods for making and using the rMcrA protein, and derivatives thereof are provided.

Dunn, John J.

2012-09-11T23:59:59.000Z

436

Effects of hydration water on protein methyl group dynamics insolution  

SciTech Connect (OSTI)

Elastic and quasielastic neutron scattering experiments have been used to investigate the dynamics of methyl groups in a protein-model hydrophobic peptide in solution. The results suggest that, when the hydrophobic side chains are hydrated by a single hydration water layer, the only allowed motions are confined and attributed to librational and rotational movement associated with the methyl groups. They provide unique experimental evidence that the structural and dynamical properties of the interfacial water strongly influence the side-chain dynamics and the activation of diffusive motion.

Russo D; Hura GL; Copley JRD

2007-01-01T23:59:59.000Z

437

1,4-Addition of Lithium Diisopropylamide to Unsaturated Esters: Role of Rate-Limiting Deaggregation, Autocatalysis,  

E-Print Network [OSTI]

1,4-Addition of Lithium Diisopropylamide to Unsaturated Esters: Role of Rate-Limiting Deaggregation, Autocatalysis, Lithium Chloride Catalysis, and Other Mixed Aggregation Effects Yun Ma, Alexander C. Hoepker.edu Abstract: Lithium diisopropylamide (LDA) in tetrahydrofuran at -78 °C undergoes 1,4-addition

Collum, David B.

438

Algorithms and Applications for Spatial Data Mining Martin Ester, Hans-Peter Kriegel, Jrg Sander (University of Munich)  

E-Print Network [OSTI]

- 1 - Algorithms and Applications for Spatial Data Mining Martin Ester, Hans-Peter Kriegel, Jörg) for an overview of spatial data mining). Finding implicit reg- ularities, rules or patterns hidden in spatial for spatial data is more complex than for relational data. This applies to both the efficiency of algorithms

Kriegel, Hans-Peter

439

Injection repair of carbon fiber/bismaleimide composite panels with bisphenol E cyanate ester resin  

SciTech Connect (OSTI)

Resin injection of bisphenol E cyanate ester, a low viscosity resin that cures into a high temperature thermoset polymer, is investigated as a reliable repair method to restore strength and stiffness in delaminated carbon fiber/bismaleimide composites used in aircraft panels. The influence of temperature on the viscosity of the uncured resin was measured to optimize the injection conditions for high resin infiltration into the delaminations. The repair efficiency of the resin was evaluated by varying the panel thickness and the method by which the delamination damage was created in the composite specimens. Ultrasonic scanning (C-scan), flash thermography images, and cross-section analysis of repaired panels revealed excellent resin infiltration into the damaged region. Evaluation of mechanical repair efficiency using both bending stiffness and in-plain compressive strength of the composite panels as the repair metrics showed values exceeding 100%.

Thunga, Mahendra [Ames Laboratory; Bauer, Amy [Iowa State University; Obusek, Kristine [Fleet Readiness Center East; Meilunas, Ray [Naval Air Warfare Center Aircraft Division; Akinc, Mufit [Ames Laboratory; Kessler, Michael R [Ames Laboratory

2014-08-01T23:59:59.000Z

440

Rheological behavior and cryogenic properties of cyanate ester/epoxy insulation material for fusion superconducting magnet  

SciTech Connect (OSTI)

In a Tokamak fusion reactor device like ITER, insulation materials for superconducting magnets are usually fabricated by a vacuum pressure impregnation (VPI) process. Thus these insulation materials must exhibit low viscosity, long working life as well as good radiation resistance. Previous studies have indicated that cyanate ester (CE) blended with epoxy has an excellent resistance against neutron irradiation which is expected to be a candidate insulation material for a fusion magnet. In this work, the rheological behavior of a CE/epoxy (CE/EP) blend containing 40% CE was investigated with non-isothermal and isothermal viscosity experiments. Furthermore, the cryogenic mechanical and electrical properties of the composite were evaluated in terms of interlaminar shear strength and electrical breakdown strength. The results showed that CE/epoxy blend had a very low viscosity and an exceptionally long processing life of about 4 days at 60 C.

Wu, Z. X.; Huang, C. J. [Key Laboratory of Cryogenics, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, PR (China); Li, L. F. [Key Laboratory of Cryogenics, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, PR China and State Key Laboratory of Technologies in Space Cryogenic Propellants, Technical Institute of Physics and Chemistry, C (China); Li, J. W. [Key Laboratory of Cryogenics, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, PR China and University of Chinese Academy of Sciences, Beijing 100049, PR (China); Tan, R.; Tu, Y. P. [North China Electric Power University, Beijing 102206, PR (China)

2014-01-27T23:59:59.000Z

Note: This page contains sample records for the topic "methyl esters biodiesel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

E-Print Network 3.0 - anhydride-vinyl methyl ether Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

4-Methyl-2-pentanol Other secondary alcohols... - quire handling with precautions. Acrolein tert-Butyl methyl ether Di(1-propynl) ether n... Methoxy-1,3,5,7- cyclooctatetraene...

442

Freezing of Dynamics of a Methyl Group in a Protein Hydrophobic...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Freezing of Dynamics of a Methyl Group in a Protein Hydrophobic Core at Cryogenic Temperatures by Deuteron NMR Spectroscopy. Freezing of Dynamics of a Methyl Group in a Protein...

443

Environmental and age effects on methylation changes in human brain and blood cells  

E-Print Network [OSTI]

Previous studies have shown that DNA methylation may 1 e associated with disease, aging, the rate of aging and genetics. In this thesis, age is accurately predicted from DNA methylation in brain and blood tissues using two ...

Giguzinsky, Orit

2014-01-01T23:59:59.000Z

444

Ultrafast photochemistry of methyl hydroperoxide on ice particles  

E-Print Network [OSTI]

Ultrafast photochemistry of methyl hydroperoxide on ice particles M. A. Kambouresa , S. AOOH, on water clusters produces a surprisingly wide range of products on a subpicosecond time scale | photodissociation Photoinduced processes at surfaces of water or ice are of interest in atmospheric chemistry

Nizkorodov, Sergey

445

Proceedings of the 1995 SAE alternative fuels conference. P-294  

SciTech Connect (OSTI)

This volume contains 32 papers and five panel discussions related to the fuel substitution of trucks, automobiles, buses, cargo handling equipment, diesel passenger cars, and pickup trucks. Fuels discussed include liquefied natural gas, natural gas, ethanol fuels, methanol fuels, dimethyl ether, methyl esters from various sources (rape oil, used cooking oils, soya, and canola oils), hydrogen fuels, and biodiesel. Other topics include fuel cell powered vehicles, infrastructure requirements for fuel substitution, and economics. Papers have been processed separately for inclusion on the data base.

NONE

1995-12-31T23:59:59.000Z

446

Phase 1 Methyl Iodide Deep-Bed Adsorption Tests  

SciTech Connect (OSTI)

Nuclear fission results in the production of fission products (FPs) and activation products including iodine-129, which could evolve into used fuel reprocessing facility off-gas systems, and could require off-gas control to limit air emissions to levels within acceptable emission limits. Research, demonstrations, and some reprocessing plant experience have indicated that diatomic iodine can be captured with efficiencies high enough to meet regulatory requirements. Research on the capture of organic iodides has also been performed, but to a lesser extent [Jubin 2012b]. Several questions remain open regarding the capture of iodine bound in organic compounds. Deep-bed methyl iodide adsorption testing has progressed according to a multi-laboratory methyl iodide adsorption test plan. This report summarizes the first phase of methyl iodide adsorption work performed according to this test plan using the deep-bed iodine adsorption test system at the Idaho National Laboratory (INL), performed during Fiscal Year (FY) 2013 and early FY-2014. Testing has been performed to address questions posed in the test plan, and followed the testing outline in the test plan. Tests established detection limits, developed procedures for sample analysis with minimal analytical interferences, and confirmed earlier results that show that the methyl iodide reacts when in contact with the AgZ sorbent, and not significantly in the gas flow upstream of the sorbent. The reaction(s) enable separation of the iodine from the organic moiety, so that the iodine can chemisorb onto the sorbent. The organic moiety can form other compounds, some of which are organic compounds that are detected and can be tentatively identified using GC-FID and GCMS. Test results also show that other gas constituents (NOx and/or H2O) can affect the methyl iodide reactions. With NOx and H2O present in the gas stream, the majority of uncaptured iodine exiting iodine-laden sorbent beds is in the form of I2 or HI, species that are soluble in NaOH scrubbing solution for iodine analysis. But when NOx and H2O are not present, then the majority of the uncaptured iodine exiting iodine-laden sorbent is in the form of methyl iodide. Methyl iodide adsorption efficiencies have been high enough so that initial DFs exceed 1,000 to 10,000. The methyl iodide mass transfer zone depths are estimated at 4-8 inches, possibly deeper than mass transfer zone depths estimated for I2 adsorption on AgZ. Additional deep-bed testing and analyses are recommended to (a) expand the data base for methyl iodide adsorption under various conditions specified in the methyl iodide test plan, and (b) provide more data for evaluating organic iodide reactions and reaction byproducts for different potential adsorption conditions.

Nick Soelberg; Tony Watson

2014-08-01T23:59:59.000Z

447

Experimental Studies for CPF and SCR Model, Control System, and OBD Development for Engines Using Diesel and Biodiesel Fuels  

SciTech Connect (OSTI)

The research carried out on this project developed experimentally validated Diesel Oxidation Catalyst (DOC), Diesel Particulate Filter (DPF), and Selective Catalytic Reduction (SCR) high?fidelity models that served as the basis for the reduced order models used for internal state estimation. The high?fidelity and reduced order/estimator codes were evaluated by the industrial partners with feedback to MTU that improved the codes. Ammonia, particulate matter (PM) mass retained, PM concentration, and NOX sensors were evaluated and used in conjunction with the estimator codes. The data collected from PM experiments were used to develop the PM kinetics using the high?fidelity DPF code for both NO2 assisted oxidation and thermal oxidation for Ultra Low Sulfur Fuel (ULSF), and B10 and B20 biodiesel fuels. Nine SAE papers were presented and this technology transfer process should provide the basis for industry to improve the OBD and control of urea injection and fuel injection for active regeneration of the PM in the DPF using the computational techniques developed. This knowledge will provide industry the ability to reduce the emissions and fuel consumption from vehicles in the field. Four MS and three PhD Mechanical Engineering students were supported on this project and their thesis research provided them with expertise in experimental, modeling, and controls in aftertreatment systems.

Johnson, John; Naber, Jeffrey; Parker, Gordon; Yang, Song-Lin; Stevens, Andrews; Pihl, Josh

2013-04-30T23:59:59.000Z

448

Targeted Enhancement of H2 and CO2 Uptake for Autotrophic Production of Biodiesel in the Lithoautotrophic Bacterium Ralsonia Eutropha  

SciTech Connect (OSTI)

CO2 and H2 are promising feedstocks for production of valuable biocompounds. Ralstonia eutropha utilizes these feedstocks to generate energy (ATP) and reductant (NAD(P)H) via oxidation of H2 by a membrane-bound (MBH) and a soluble hydrogenase (SH) for CO2 fixation by the Calvin-Benson-Bassham (CBB) cycle. Increased expression of the enzyme that fixes CO2 (RubisCO) resulted in 6-fold activity improvement in vitro, while increased expression of the MBH operon or the SH operon plus MBH operon maturation factors necessary for activity resulted in a 10-fold enhancement. Current research involves genetic manipulation of two endogenous cbb operons for increased expression, analysis of expression and activity of CBB/MBH/SH, cofactor ratios, and downstream products during autotrophic growth in control versus enhanced strains, and development of strategies for long-term, optimal overexpression. These studies will improve our understanding of autotrophic metabolism and provide a chassis strain for autotrophic production of biodiesel and other valuable carbon biocompounds.

Eckert, C. A.; Sullivan, R.; Johnson, C.; Yu, J.; Maness, P. C.

2013-01-01T23:59:59.000Z

449

Biodiesel versus diesel exposure: Enhanced pulmonary inflammation, oxidative stress, and differential morphological changes in the mouse lung  

SciTech Connect (OSTI)

The use of biodiesel (BD) or its blends with petroleum diesel (D) is considered to be a viable approach to reduce occupational and environmental exposures to particulate matter (PM). Due to its lower particulate mass emissions compared to D, use of BD is thought to alleviate adverse health effects. Considering BD fuel is mainly composed of unsaturated fatty acids, we hypothesize that BD exhaust particles could induce pronounced adverse outcomes, due to their ability to readily oxidize. The main objective of this study was to compare the effects of particles generated by engine fueled with neat BD and neat petroleum-based D. Biomarkers of tissue damage and inflammation were significantly elevated in lungs of mice exposed to BD particulates. Additionally, BD particulates caused a significant accumulation of oxidatively modified proteins and an increase in 4-hydroxynonenal. The up-regulation of inflammatory cytokines/chemokines/growth factors was higher in lungs upon BD particulate exposure. Histological evaluation of lung sections indicated presence of lymphocytic infiltrate and impaired clearance with prolonged retention of BD particulate in pigment laden macrophages. Taken together, these results clearly indicate that BD exhaust particles could exert more toxic effects compared to D. - Highlights: Exposure of mice to BDPM caused higher pulmonary toxicity compared to DPM. Oxidative stress and inflammation were higher in BD vs to D exposed mice. Inflammatory lymphocyte infiltrates were seen only in lungs of mice exposed to BD. Ineffective clearance, prolonged PM retention was present only after BD exposure.

Yanamala, Naveena, E-mail: wqu1@cdc.gov [Pathology and Physiology Research Branch/NIOSH/CDC, Morgantown, WV 26505 (United States); Hatfield, Meghan K., E-mail: wla4@cdc.gov [Pathology and Physiology Research Branch/NIOSH/CDC, Morgantown, WV 26505 (United States); Farcas, Mariana T., E-mail: woe7@cdc.gov [Pathology and Physiology Research Branch/NIOSH/CDC, Morgantown, WV 26505 (United States); Schwegler-Berry, Diane [Pathology and Physiology Research Branch/NIOSH/CDC, Morgantown, WV 26505 (United States); Hummer, Jon A., E-mail: qzh3@cdc.gov [Office of Mine Safety and Health Research/NIOSH/CDC, Pittsburgh, PA 15236 (United States); Shurin, Michael R., E-mail: shurinmr@upmc.edu [Department of Pathology, University of Pittsburgh Medical Center, Pittsburgh, PA (United States); Birch, M. Eileen, E-mail: mib2@cdc.gov [NIOSH/CDC, 4676 Columbia Parkway, Cincinnati, OH 45226 (United States); Gutkin, Dmitriy W., E-mail: dwgutkin@hotmail.com [Department of Pathology, University of Pittsburgh Medical Center, Pittsburgh, PA (United States); Kisin, Elena, E-mail: edk8@cdc.gov [Pathology and Physiology Research Branch/NIOSH/CDC, Morgantown, WV 26505 (United States); Kagan, Valerian E., E-mail: kagan@pitt.edu [Department of Environmental and Occupational Health, University of Pittsburgh, PA (United States); Bugarski, Aleksandar D., E-mail: zjl1@cdc.gov [Office of Mine Safety and Health Research/NIOSH/CDC, Pittsburgh, PA 15236 (United States); Shvedova, Anna A., E-mail: ats1@cdc.gov [Pathology and Physiology Research Branch/NIOSH/CDC, Morgantown, WV 26505 (United States); Department Physiology and Pharmacology, WVU, Morgantown, WV 26505 (United States)

2013-10-15T23:59:59.000Z

450

Plug repairs of marine glass fiber / vinyl ester laminates subjected to in-plane shear stress or in-plane bending moment  

E-Print Network [OSTI]

Glass fiber / vinyl ester composite laminates represent an important class of modem fiber composites being proposed or used in state-of-the-art shipbuilding. This thesis examined the effectiveness of chopped strand mat ...

Urrutia Valenzuela, Roberto

2010-01-01T23:59:59.000Z

451

Mercury Methylation in Mine Wastes Collected from Abandoned Mercury Mines in the USA  

SciTech Connect (OSTI)

Mercury mines contain highly elevated Hg contents, but more problematic environmentally are elemental Hg and soluble Hg salts produced during ore retorting that remain in wastes at mine sites. Under certain conditions, these inorganic Hg compounds convert to bioavailable, highly toxic organic Hg forms. Speciation and transformation of Hg was studied in wastes collected from abandoned Hg mines at McDermitt, NV, and Terlingua, TX, which are moderate size on an international scale and produced about 10,000 and 5,000 t of elemental Hg, respectively. In waste samples, we measured total Hg and methyl-Hg contents, identified various Hg compounds using Hg-thermo-desorption pyrolysis, and determined rates of Hg methylation and methyl-Hg demethylation using isotopic-tracer methods. Pyrolysis analysis of mine wastes showed variable amounts of cinnabar, metacinnabar, Hg salts, elemental Hg, and elemental Hg sorbed onto particulates such as clay and Fe-oxides. Mine wastes with the highest methyl-Hg contents correspond to those with elemental Hg and particulate-sorbed elemental Hg, and also produced the highest laboratory-estimated potential Hg methylation rates, as much as 4.8%/day. Samples containing dominantly cinnabar showed little or no Hg methylation. Mine wastes with high methyl-Hg contents generally showed low methyl-Hg demethylation, suggesting that Hg methylation was dominant. Both mines are located in semiarid climates, and during this study, streambeds below the mines were dry. Total Hg contents in stream sediment collected below the mines show significant dilution, and methyl-Hg contents were typically below the limit of determination. Methylation of Hg downstream from Hg mines is probably lower in arid climates due to lack of mine-water runoff and lower microbial activity. The correspondence of mine wastes containing elemental Hg and high methyl-Hg contents suggests that Hg0 oxidizes to Hg2+, which is subsequently bioavailable for microbial Hg methylation.

Gray, John E. (U.S. Geological Survey); Hines, Mark E. (Massachusetts, Univ Of); Biester, Harald (Heidelberg College); Lasorsa, Brenda K. (BATTELLE (PACIFIC NW LAB))

2003-05-01T23:59:59.000Z

452

E-Print Network 3.0 - acibenzolar-s-methyl para controle Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

a coffee-leaf extract formulation in tomato Summary: ), acibenzolar-S-methyl (Bion) or water (control) and three days subsequently infected with the tomato pathogen... in the...

453

Durability of Poly (Methyl Methacrylate) Lenses Used in Concentrating Photovoltaics (Presentation)  

SciTech Connect (OSTI)

This presentation reports the findings of NREL's screen test to characterize the durability of poly (methyl methacrylate) lenses used in concentrated photovoltaics.

Miller, D.; Gedvilas, L.; To, B.; Kennedy, C.; Kurtz, S.

2010-10-21T23:59:59.000Z

454

Synthesis of an acid addition salt of delta-aminolevulinic acid from 5-bromo levulinic acid esters  

DOE Patents [OSTI]

A process is disclosed for preparing an acid addition salt of delta-aminolevulinic acid comprising. The process involves dissolving a lower alkyl 5-bromolevulinate and an alkali metal diformylamide in an organic solvent selected from the group consisting of acetonitrile, methanol, tetrahydrofuran, 2-methyltetrahydrofuran and methylformate or mixtures to form a suspension of an alkyl 5-(N,N-diformylamino) levulinate ester; and hydrolyzing the alkyl 5-(N,N-diformylamino) levulinate with an inorganic acid to form an acid addition salt of delta-amino levulinic acid.

Moens, L.

1999-05-25T23:59:59.000Z

455

Synthesis of an acid addition salt of delta-aminolevulinic acid from 5-bromo levulinic acid esters  

DOE Patents [OSTI]

A process of preparing an acid addition salt of delta-aminolevulinic acid comprising: dissolving a lower alkyl 5-bromolevulinate and an alkali metal diformylamide in an organic solvent selected from the group consisting of acetonitrile, methanol, tetrahydrofuran, 2-methyltetrahydrofuran and methylformate or mixtures thereof to form a suspension of an alkyl 5-(N,N-diformylamino) levulinate ester; and hydrolyzing said alkyl 5-(N,N-diformylamino) levulinate with an inorganic acid to form an acid addition salt of delta-amino levulinic acid.

Moens, Luc (Lakewood, CO)

1999-01-01T23:59:59.000Z

456

Mechanism for the hydrolysis of organophosphates and investigations into the stereoselective hydrolysis of organophosphorus Esters by Phosphotriesterase.  

E-Print Network [OSTI]

. The rate constants and stereoselectivity ratios for a number of active site mutants have been determined. H254Y/L303T PTE reverses the stereoselective preference of phosphonate and phosphinate substrates. The PTE stereoselectivity of O-methyl, O...

Aubert, Sarah Dwyer

2006-04-12T23:59:59.000Z

457

Characterization of the Deltaproteobacteria in contaminated and uncontaminated stream sediments and identification of potential mercury methylators  

SciTech Connect (OSTI)

Microbial communities were examined in surface stream sediments at 5 contaminated sites and 1 control site near Oak Ridge, TN, USA, to identify bacteria that could be contributing to mercury (Hg) methylation. The phylogenetic composition of the sediment bacterial community was examined over 3 quarterly sampling periods (36 samples) using 16S rRNA gene pyrosequencing. Only 3064 sequences (0.85% of the total community) were identified as Deltaproteobacteria, the only group known to methylate Hg, using the Ribosomal Database Project classifier at the 99% confidence threshold. Constrained ordination techniques indicated statistically significant positive linear correlations between Desulfobulbus spp., Desulfonema spp. and Desulfobacca spp. and methyl-Hg concentrations at the Hg-contaminated sites. In contrast, the distribution of organisms related to Byssovorax spp. was significantly correlated to inorganic carbon, nitrate and uranium concentrations but not to Hg or methyl-Hg. Overall, the abundance and richness of Deltaproteobacteria sequences were higher in uncontaminated sediments, while the majority of the members present at the contaminated sites were either known potential metal-reducers/methylators or metal tolerant species. Given the abundance relative to other known Hg methylators and the association with methyl-Hg, Desulfobulbus spp. is considered a prime candidate for involvement in Hg methylation in these streams.

Mosher, Jennifer [ORNL; Vishnivetskaya, Tatiana A [ORNL; Elias, Dwayne A [ORNL; Podar, Mircea [ORNL; Brooks, Scott C [ORNL; Brown, Steven D [ORNL; Brandt, Craig C [ORNL; Palumbo, Anthony Vito [ORNL

2012-01-01T23:59:59.000Z

458

Arsenic Methylation and Bladder Cancer Risk in CaseControl Studies in Argentina and the  

E-Print Network [OSTI]

Arsenic Methylation and Bladder Cancer Risk in Case­Control Studies in Argentina and the United's susceptibility to bladder cancer. Methods: Urinary methylation products were measured in subjects from Argentina (114 cases and 114 controls) and the United States (23 cases and 49 controls). Results: In Argentina

California at Berkeley, University of

459

et al. (2008) identified several additional methylation sites on FOXO1 that ap-  

E-Print Network [OSTI]

, it remains to be deter- mined how methylation alters the activity and posttranslational regulation. In this light, methylation could, therefore, play a very general role in the regulation of FOXO1 activity serve as a link between aging and age-related diseases such as diabe- tes and cancer. FOXO dysregulation

Hertel, Klemens J.

460

Treatment of Methyl tert-Butyl Ether Vapors in Biotrickling Filters. 2.  

E-Print Network [OSTI]

vapors of methyl tert-butyl ether (MTBE), a gasoline additive of great environmental concern MTBE treatment are discussed. Introduction The rapidly rising number of reports of groundwater con- taminated with the gasoline additive methyl tert-butyl ether (MTBE) has raised concerns about its

Note: This page contains sample records for the topic "methyl esters biodiesel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Atmospheric Methyl Tertiary Butyl Ether (MTBE) at a Rural Mountain Site in California  

E-Print Network [OSTI]

Atmospheric Methyl Tertiary Butyl Ether (MTBE) at a Rural Mountain Site in California Gunnar W. Schade,* Gabrielle B. Dreyfus, and Allen H. Goldstein ABSTRACT (CARB) measured MTBE in urban regions in 1995­ 1996, reporting a range of 0.4 to 13.2 ppbv in the LosMethyl tertiary butyl ether (MTBE

Cohen, Ronald C.

462

Environmental Microbiology (2001) 3(6), 407416 Methyl tert-butyl ether (MTBE) degradation by a  

E-Print Network [OSTI]

Environmental Microbiology (2001) 3(6), 407±416 Methyl tert-butyl ether (MTBE) degradation of California, Riverside, Riverside, CA 92521, USA. Summary The widespread use of methyl tert-butyl ether (MTBE is often proposed as the most promising alter- native after treatment. However, MTBE biodegradation appears

463

Mercury methylation in oxygen deficient zones of the oceans: No evidence for the predominance of anaerobes  

E-Print Network [OSTI]

Mercury methylation in oxygen deficient zones of the oceans: No evidence for the predominance Keywords: Methylmercury Oxygen minimum zone Arabian Sea Equatorial Eastern Pacific Mercury methylation Although a large fraction of the world's population is exposed to mercury through consumption of marine

Morel, François M. M.

464

Multifunctional Properties of Cyanate Ester Composites with SiO2 Coated Fe3O4 Fillers  

SciTech Connect (OSTI)

SiO2 coated Fe3O4 submicrometer spherical particles (a conducting core/insulating shell configuration) are fabricated using a hydrothermal method and are loaded at 10 and 20 vol % into a bisphenol E cyanate ester matrix for synthesis of multifunctional composites. The dielectric constant of the resulting composites is found to be enhanced over a wide frequency and temperature range while the low dielectric loss tangent of the neat cyanate ester polymer is largely preserved up to 160 ?C due to the insulating SiO2 coating on individual conductive Fe3O4 submicrometer spheres. These composites also demonstrate high dielectric breakdown strengths at room temperature. Dynamic mechanical analysis indicates that the storage modulus of the composite with a 20 vol % filler loading is twice as high as that of neat resin, but the glass transition temperature considerably decreases with increasing filler content. Magnetic measurements reveal a large saturation magnetization and negligibly low coercivity and remanent magnetization in these composites.

Sun, Weixing; Sun, Wuzhu; Kessler, Michael R.; Bowler, Nicola; Dennis, Kevin W.; McCallum, R. William; Li, Qi; Tan, Xiaoli

2013-02-22T23:59:59.000Z

465

Novel Biological Conversion of Hydrogen and Carbon Dioxide Directly into Biodiesel: Cooperative Research and Development Final Report, CRADA Number: CRD-10-408  

SciTech Connect (OSTI)

OPX Biotechnologies, Inc. (OPX), the National Renewable Energy Laboratory (NREL), and Johnson Matthey will develop and optimize a novel, engineered microorganism that directly produces biodiesel from renewable hydrogen (H2) and carbon dioxide (CO2). The proposed process will fix CO2 utilizing H2 to generate an infrastructure-compatible, energy-dense fuel at costs of less than $2.50 per gallon, with water being produced as the primary byproduct. NREL will perform metabolic engineering on the bacterium Cupriavidus necator (formerly Ralstonia eutropha) and a techno-economic analysis to guide future scale-up work. H2 and CO2 uptakes rates will be genetically increased, production of free fatty acids will be enhanced and their degradation pathway blocked in order to meet the ultimate program goals.

Maness, P. C.

2014-06-01T23:59:59.000Z

466

Performance and Emissions Characteristics of Bio-Diesel (B100)-Ignited Methane and Propane Combustion in a Four Cylinder Turbocharged Compression Ignition Engine  

SciTech Connect (OSTI)

Different combustion strategies and fuel sources are needed to deal with increasing fuel efficiency demands and emission restrictions. One possible strategy is dual fueling using readily available resources. Propane and natural gas are readily available with the current infrastructure and biodiesel is growing in popularity as a renewable fuel. This paper presents experimental results from dual fuel combustion of methane (as a surrogate for natural gas) and propane as primary fuels with biodiesel pilots in a 1.9 liter, turbocharged, 4 cylinder diesel engine at 1800 rev/min. Experiments were performed with different percentage energy substitutions (PES) of propane and methane and at different brake mean effective pressures (BMEP/bmep). Brake thermal efficiency (BTE) and emissions (NOx, HC, CO, CO2, O2 and smoke) were also measured. Maximum PES levels for B100-methane dual fuelling were limited to 70% at 2.5 bar bmep and 48% at 10 bar bmep, and corresponding values for B100-propane dual fuelling were 64% and 43%, respectively. Maximum PES was limited by misfire at 2.5 bar bmep and the onset of engine knock at 10 bar bmep. Dual fuel BTEs approached straight B100 values at 10 bar bmep while they were significantly lower than B100 values at 2.5 bar bmep. In general dual fuelling was beneficial in reducing NOx and smoke emissions by 33% and 50%, respectively from baseline B100 levels; however, both CO and THC emissions were significantly higher than baseline B100 levels at all PES and loads.

Shoemaker, N. T.; Gibson, C. M.; Polk, A. C.; Krishnan, S. R.; Srinivasan, K. K.

2011-10-05T23:59:59.000Z

467

Methyl-CpG island-associated genome signature tags  

DOE Patents [OSTI]

Disclosed is a method for analyzing the organismic complexity of a sample through analysis of the nucleic acid in the sample. In the disclosed method, through a series of steps, including digestion with a type II restriction enzyme, ligation of capture adapters and linkers and digestion with a type IIS restriction enzyme, genome signature tags are produced. The sequences of a statistically significant number of the signature tags are determined and the sequences are used to identify and quantify the organisms in the sample. Various embodiments of the invention described herein include methods for using single point genome signature tags to analyze the related families present in a sample, methods for analyzing sequences associated with hyper- and hypo-methylated CpG islands, methods for visualizing organismic complexity change in a sampling location over time and methods for generating the genome signature tag profile of a sample of fragmented DNA.

Dunn, John J

2014-05-20T23:59:59.000Z

468

THE JOURNAL OF CHEMICAL PHYSICS 138, 054301 (2013) Photodissociation dynamics of the methyl perthiyl radical at 248 nm  

E-Print Network [OSTI]

the photodissociation of the methyl perthiyl radical CH3SS at 248 nm. The radical was produced by flash pyrolysis

Neumark, Daniel M.

469

Optical measurements of methyl group tunneling in molecular crystals: Temperature dependence of the nuclear spin conversion rate  

E-Print Network [OSTI]

) The tunneling methyl groups in dimethyl-s-tetrazine (DMST) doped single crystals of durene were investigated

470

Biodiesel: Today's Agricultural Fuel  

SciTech Connect (OSTI)

Presented at ''Bioenergy: The Future of Rural America'' meeting in Westminster, Colorado on November 6, 2003.

Tyson, K. S.

2003-11-01T23:59:59.000Z

471

Monthly Biodiesel Production Report  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecember 2005 (Thousand9,0,InformationU.S. Crude Oil3 13,,8.1 64.1

472

Monthly Biodiesel Production Report  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecember 2005 (Thousand9,0,InformationU.S. Crude Oil3 13,,8.1

473

Biodiesel | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin: Energy ResourcesJersey:form View source History ViewSystemsof TexasFlorida

474

3 Micro-mechanics based derivation of the materials constitutive 4 relations for carbon-nanotube reinforced poly-vinyl-ester-epoxy  

E-Print Network [OSTI]

, carbon nanotube-reinforced polymer-ma- 45trix composite) materials have spurred considerable 46interest relations for carbon-nanotube reinforced poly-vinyl-ester-epoxy 5 based composites 6 Mica Grujicic Y. P. Sun mechanical reinforcements for 59lightweight composite systems. However, the material 60and the processing

Grujicic, Mica

475

Journal of Materials Science, 2012, 47(14): p. 5596-5604 Thermal expansion behavior of hollow glass particle/vinyl ester composites  

E-Print Network [OSTI]

with the addition of glass microballoons for the twelve compositions of syntactic foams characterized using glass particle/vinyl ester composites Vasanth Chakravarthy Shunmugasamy, Dinesh Pinisetty and Nikhil filled composites (syntactic foams), the coefficient of thermal expansion (CTE) can be controlled by two

Gupta, Nikhil

476

Genomic DNA methylation in various developmental stages of two plant pathogenic fungi  

E-Print Network [OSTI]

blotting procedure. The blots were then hybridized with DNA probes from the highly repeated Neurospora crassa rDNA repeat unit labeled with [a. P] dCTP in a random-primed oligolabeling reaction. Results of the hybridizations were visualized... shows s. high degree of methylation at the inner (3') C in both stages (mycelia and sclerotia) at the genomic level. The rRNA genes exhibit the same high level of methylation at the 3' C with the addition of some stage specific methylation...

Schliesing, Laura Jo

1990-01-01T23:59:59.000Z

477

Guiding optimal biofuels : a comparative analysis of the biochemical production of ethanol and fatty acid ethyl esters from switchgrass.  

SciTech Connect (OSTI)

In the current study, processes to produce either ethanol or a representative fatty acid ethyl ester (FAEE) via the fermentation of sugars liberated from lignocellulosic materials pretreated in acid or alkaline environments are analyzed in terms of economic and environmental metrics. Simplified process models are introduced and employed to estimate process performance, and Monte Carlo analyses were carried out to identify key sources of uncertainty and variability. We find that the near-term performance of processes to produce FAEE is significantly worse than that of ethanol production processes for all metrics considered, primarily due to poor fermentation yields and higher electricity demands for aerobic fermentation. In the longer term, the reduced cost and energy requirements of FAEE separation processes will be at least partially offset by inherent limitations in the relevant metabolic pathways that constrain the maximum yield potential of FAEE from biomass-derived sugars.

Paap, Scott M.; West, Todd H.; Manley, Dawn Kataoka; Dibble, Dean C.; Simmons, Blake Alexander; Steen, Eric J. [Joint BioEnergy Institute, Emeryville, CA; Beller, Harry R. [Lawrence Berkeley National Laboratory, Berkeley, CA; Keasling, Jay D. [Lawrence Berkeley National Laboratory, Berkeley, CA; Chang, Shiyan [Tsinghua University, Beijing, PR China

2013-01-01T23:59:59.000Z

478

Anti-inflammatory and antifibrotic effects of methyl palmitate  

SciTech Connect (OSTI)

Methyl palmitate (MP) has been shown earlier to inhibit Kupffer cells and rat peritoneal macrophages. To evaluate the potential of MP to inhibit the activation of other macrophages, RAW cells (macrophages of alveolar origin) were treated with varying concentrations of MP (0.25, 0.5, 1 mM). Assessment of cytotoxicity using MTT assay revealed that 0.25 and 0.5 mM are not toxic to RAW cells. MP was able to inhibit the phagocytic function of RAW cells. Treatment of cells with MP 24 hours prior to LPS stimulation significantly decreased nitric oxide release and altered the pattern of cytokines release; there was a significant decrease in TNF-{alpha} and a significant increase in IL-10 compared to the controls. However, there is a non-significant change in IL-6 level. Furthermore, phosphorylation of inhibitory kappa B (I{kappa}B{alpha}) protein was significantly decreased in RAW cells treated with 0.5 mM MP after LPS stimulation. Based upon the in-vitro results, it was examined whether MP treatment will be effective in preventing bleomycin-induced lung inflammation and fibrosis in-vivo. Bleomycin given by itself caused destruction of the lung architecture characterized by pulmonary fibrosis with collapse of air alveoli and emphysematous. Bleomycin induced a significant increase in hydroxyproline level and activated NF-{kappa}B, p65 expression in the lung. MP co-treatment significantly ameliorated bleomycin effects. These results suggest that MP has a potential of inhibiting macrophages in general. The present study demonstrated for the first time that MP has anti-inflammatory and antifibrotic effect that could be through NF-kB inhibition. Thus MP like molecule could be a promising anti-inflammatory and antifibrotic drug. - Research Highlights: >Methyl palmitate is a universal macrophage inhibitor. >It could be a promising nucleus of anti-inflammatory and antifibrotic drugs. >The underlying mechanism of these effects could be through NF-kB inhibition.

El-Demerdash, Ebtehal, E-mail: ebtehal_dm@yahoo.com

2011-08-01T23:59:59.000Z

479

Bioremediation of the organophosphate methyl parathion using genetically engineered and native organisms  

E-Print Network [OSTI]

to remediate hazardous substances at significantly higher rates than found with natural systems. Specifically, degradation of methyl parathion (MP) by hydrolysis with a genetically engineered Escherichia coli was investigated along with degradation of one...

Diaz Casas, Adriana Z.

2005-11-01T23:59:59.000Z

480

Thermomechanical properties of polyhedral oligomeric silsequioxane- poly(methyl methacrylate) nanocomposites  

E-Print Network [OSTI]

Poly(methyl methacrylate)s (PMMA) containing polyhedral oligomeric silsesquioxane (POSS) nanoparticles (d [approx.] 1.5 nm) were subjected to heological, mechanical, and morphological tests to determine the effects that ...

Kopesky, Edward Thomas

2005-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "methyl esters biodiesel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

A unique regulatory phase of DNA methylation in the early mammalian embryo  

E-Print Network [OSTI]

DNA methylation is highly dynamic during mammalian embryogenesis. It is broadly accepted that the paternal genome is actively depleted of 5-methylcytosine at fertilization, followed by passive loss that reaches a minimum ...

Chan, Michelle M.

482

active methyl tert-butyl: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

by Fusarium solani CiteSeer Summary: Fusarium solani degraded methyl tert-butyl ether (MTBE) and other oxygenated compounds from gasoline including tert-butyl alcohol (TBA). The...

483

Halogenated 1'-methyl-1,2'-bipyrroles (MBPs) in the Norwestern Atlantic  

E-Print Network [OSTI]

Halogenated 1'-methyl-1,2'-bipyrroles (MBPs) are a distinctive class of marine organic compounds. They are naturally produced, they have a unique carbon structure, they are highly halogenated, and they bioaccumulate in ...

Pangallo, Kristin C

2009-01-01T23:59:59.000Z

484

Temporal and spatial variation in methyl bromide emissions from a salt marsh  

E-Print Network [OSTI]

Methyl bromide (CH3Br) is a trace gas involved in stratospheric ozone depletion with both anthropogenic and natural sources. Estimates of natural source strengths are highly uncertain. In this study, >320 highly temporally ...

Drewer, Julia; Heal, Mathew R; Heal, Kate V; Smith, Keith A

2006-01-01T23:59:59.000Z

485

An evaluation of the 3M Organic Vapor Monitor #3500 as a short term exposure limit sampling device for acetone, methyl ethyl ketone, and methyl iso butyl ketone  

E-Print Network [OSTI]

. An exploded view of the monitor is illustrated in Figure 1. The theory of diffusive sampling considers a concentration gra- dient between the ambient air and the adsorbent to be the driving force for sampling. For the adsorption to be controlled by diffu...AN EVALUATION OF THE 3M ORGANIC VAPOR MONITOR 43500 AS A SHOR'I TERM EXPOSURE LIMIT SAMPLING DEVICE FOR ACETONE, METHYL ETHYL KETONE, AND METHYL ISO BUTYL KETONE A Thesis by LLOYD B. ANDREW III Submitted to the Graduate College of Texas ASM...

Andrew, Lloyd B.

2012-06-07T23:59:59.000Z

486

Chromosome-wide mapping of DNA methylation patterns in normal and malignant prostate cells reveals pervasive methylation of gene-associated and conserved intergenic sequences  

E-Print Network [OSTI]

G island [13-15], chromosome-wide [15], or genome-wide [16] til- ing microarrays or to analyze by next generation sequen- cing [17,18]. Here, we describe the use of an MBD-chip approach (Figure 1A) to compare the chromosome-wide DNA methylation patterns... identified as differentially methylated in the LNCaP cells compared to the PrEC cells. We could then compare the distribution of CpG dinucleotide content and number of regions overlapping CpG islands in these simulated data sets with these parameters in our...

Yegnasubramanian, Srinivasan; Wu, Zhijin; Haffner, Michael C; Esopi, David; Aryee, Martin J; Badrinath, Raghav; He, Tony L; Morgan, James D; Carvalho, Benilton S; Zheng, Qizhi; De Marzo, Angelo M; Irizarry, Rafael A; Nelson, William G

2011-06-13T23:59:59.000Z

487

Radio-methyl vorozole and methods for making and using the same  

DOE Patents [OSTI]

Radiotracer vorozole compounds for in vivo and in vitro assaying, studying and imaging cytochrome P450 aromatase enzymes in humans, animals, and tissues and methods for making and using the same are provided. [N-radio-methyl] vorozole substantially separated from an N-3 radio-methyl isomer of vorozole is provided. Separation is accomplished through use of chromatography resins providing multiple mechanisms of selectivity.

Kim, Sung Won; Biegon, Anat; Fowler, Joanna S.

2014-08-05T23:59:59.000Z

488

Radio-methyl vorozole and methods for making and using the same  

DOE Patents [OSTI]

Radiotracer vorozole compounds for in vivo and in vitro assaying, studying and imaging cytochrome P450 aromatase enzymes in humans, animals, and tissues and methods for making and using the same are provided. [N-radio-methyl] vorozole substantially separated from an N-3 radio-methyl isomer of vorozole is provided. Separation is accomplished through use of chromatography resins providing multiple mechanisms of selectivity.

Kim, Sung Won; Biegon, Anat; Fowler, Joanna S.

2014-08-12T23:59:59.000Z

489

State Restrictions on Methyl Tertiary Butyl Ether (released in AEO2006)  

Reports and Publications (EIA)

By the end of 2005, 25 states had barred, or passed laws banning, any more than trace levels of methyl tertiary butyl ether (MTBE) in their gasoline supplies, and legislation to ban MTBE was pending in 4 others. Some state laws address only MTBE; others also address ethers such as ethyl tertiary butyl ether (ETBE) and tertiary amyl methyl ether (TAME). Annual Energy Outlook 2006 assumes that all state MTBE bans prohibit the use of all ethers for gasoline blending.

2006-01-01T23:59:59.000Z

490

INVOLVED IN DE NOVO 2-containing complex involved in RNA-directed DNA methylation in Arabidopsis  

SciTech Connect (OSTI)

At least three pathways control maintenance of DNA cytosine methylation in Arabidopsis thaliana. However, the RNA-directed DNA methylation (RdDM) pathway is solely responsible for establishment of this silencing mark. We previously described INVOLVED IN DE NOVO 2 (IDN2) as being an RNA-binding RdDM component that is required for DNA methylation establishment. In this study, we describe the discovery of two partially redundant proteins that are paralogous to IDN2 and that form a stable complex with IDN2 in vivo. Null mutations in both genes, termed IDN2-LIKE 1 and IDN2-LIKE 2 (IDNL1 and IDNL2), result in a phenotype that mirrors, but does not further enhance, the idn2 mutant phenotype. Genetic analysis suggests that this complex acts in a step in the downstream portion of the RdDM pathway. We also have performed structural analysis showing that the IDN2 XS domain adopts an RNA recognition motif (RRM) fold. Finally, genome-wide DNA methylation and expression analysis confirms the placement of the IDN proteins in an RdDM pathway that affects DNA methylation and transcriptional control at many sites in the genome. Results from this study identify and describe two unique components of the RdDM machinery, adding to our understanding of DNA methylation control in the Arabidopsis genome.

Ausin, Israel; Greenberg, Maxim V.C.; Simanshu, Dhirendra K.; Hale, Christopher J.; Vashisht, Ajay A.; Simon, Stacey A.; Lee, Tzuu-fen; Feng, Suhua; Espaola, Sophia D.; Meyers, Blake C.; Wohlschlegel, James A.; Patel, Dinshaw J.; Jacobsen, Steven E. (UCLA); (MSKCC); (Delaware)

2012-10-23T23:59:59.000Z

491

Alcohol to Ester 21 ALCOHOL TO ESTER  

E-Print Network [OSTI]

.) Attach a Claisen adapter to the flask. Place a thermometer adapter with a thermometer in the main arm of the Claisen adapter so that the thermometer point is immersed in the liquid (but not so deep sulfuric acid (may be strong exotherm). Rapidly plug the Claisen adapter (with thermometer and condenser

Jasperse, Craig P.

492

Polystyrene/Poly(methyl methacrylate) Blends in the Presence of Cyclohexane: Selective Solvent Washing or Equilibrium Adsorption?  

E-Print Network [OSTI]

-cyclohexane (PS:CH), poly(methyl methacrylate)-carbon tetrachloride (PMMA:CCl4), and PS:CCl4 adsorbing

493

Biogeochemistry of arsenic in natural waters: The importance of methylated species  

SciTech Connect (OSTI)

Water samples from a number of lakes and estuaries, mostly in California, showed measurable concentrations of methylated arsenic (equivalent to 1-59% of total As) with the exception of one highly alkaline lake. Neither depleted phosphate concentrations nor high dissolved salts correlated with the appearance of methylated forms of As. A temporal study of As speciation in Davis Creek Reservoir, a seasonally anoxic lake in northern California, demonstrated that dimethylarsinic acid increased sufficiently to become the dominant form of dissolved As within the surface photic zone during late summer and fall. Methylated forms decreased while arsenate increased when the lake over-turned in early December, which suggested a degradation of dimethylarsinic acid to arsenate.

Anderson, L.C.D.; Bruland, K.W. (Univ. of California, Santa Cruz (USA))

1991-03-01T23:59:59.000Z

494

Salt effect on the isobaric vapor-liquid equilibrium of the methyl acetate + methanol system  

SciTech Connect (OSTI)

The effect of sodium thiocyanate at constant salt mole fraction from 0.01 to 0.05 and at saturation on the vapor-liquid equilibrium (VLE) of methyl acetate + methanol has been studied at 101.32 kPa using a modified Othmer equilibrium still. The salt exhibited both salting-in and salting-out effects on the methyl acetate, the azeotrope being eliminated at saturation. The results were correlated using the extended UNIQUAC model of Sander et al. and the electrolytic NRTL model of Mock et al.

Iliuta, M.C.; Thyrion, F.C. [Louvain Univ., Louvain-la-Neuve (Belgium). Chemical Engineering Inst.] [Louvain Univ., Louvain-la-Neuve (Belgium). Chemical Engineering Inst.; Landauer, O.M. [Univ. Politehnica Bucharest (Romania)] [Univ. Politehnica Bucharest (Romania)

1996-07-01T23:59:59.000Z

495

Kinetics of the reduction of methyl viologen with hydrogen on a colloidal Pt catalyst  

SciTech Connect (OSTI)

The evolution of H/sub 2/ on a Pt catalyst under the influence of one-electron reductors is part of the photocatalytic process of decomposition of H/sub 2/O into H/sub 2/ and O/sub 2/. As a model reaction we selected the reduction of methyl viologen. The bonding constant for hydrogen on colloidal Pt, as well as the effective rate constant of the heterolytic splitting of H/sub 2/ on the same Pt catalyst are determined. A mathematical description of the reduction of methyl viologen with hydrogen is suggested.

Maier, V.E.; Shafirovich, V.Ya.

1988-10-01T23:59:59.000Z

496

Acute environmental toxicity and persistence of methyl salicylate: A chemical agent simulant. Final report  

SciTech Connect (OSTI)

The interactions of methyl salicylate with plant foliage and soils were assessed using aerosol/vapor exposure methods. Measurements of deposition velocity and residence times for soils and foliar surfaces are reported. Severe plant contact toxicity was observed at foliar mass-loading levels above 4 {mu}g/cm{sup 2} leaf; however, recovery was noted after four to fourteen days. Methyl salicylate has a short-term effect on soil dehydrogenase activity, but not phosphatase activity. Results of the earthworm bioassay indicated only minimal effects on survival.

Cataldo, D.A.; Ligotke, M.W.; Harvey, S.D.; Fellows, R.J.; Li, S.W.

1994-06-01T23:59:59.000Z

497

Effect of Amino Acid Subsititution in Set1 on Histone H3 Methylation and Gene Silencing in Saaccharomyces Cerevisiae  

E-Print Network [OSTI]

EFFECT OF AMINO ACID SUBSITITUTION IN SET1 ON HISTONE H3 METHYLATION AND GENE SILENCING IN SAACCHAROMYCES CEREVISIAE A Senior Honors Thesis by MORGAN CHATEAU Submitted to the Office...3 Methylation and Gene Silencing in Saccharomyces cerevisiae (April 2008) Morgan Chateau Department of Biochemistry and Biophysics Texas A&M University Fellows Advisor: Associate Professor Dr. Mary Bryk Department of Biochemistry...

Chateau, Morgan

2008-08-24T23:59:59.000Z

498

IDENTIFYING THE USAGE PATTERNS OF METHYL TERT-BUTYL ETHER (MTBE) AND OTHER OXYGENATES IN GASOLINE USING GASOLINE  

E-Print Network [OSTI]

IDENTIFYING THE USAGE PATTERNS OF METHYL TERT-BUTYL ETHER (MTBE) AND OTHER OXYGENATES IN GASOLINE USING GASOLINE SURVEYS By Michael J. Moran, Rick M. Clawges, and John S. Zogorski U.S. Geological Survey 1608 Mt. View Rapid City, SD 57702 Methyl tert-butyl ether (MTBE) is commonly added to gasoline

499

ARE Update Volume 9, Number 3  

E-Print Network [OSTI]

land for energy production. agriculture to meet world foodworld community climate change and energy shortages. began today to increase ethanol productionworld crop esters, biodiesel has one of the highest energy balances land for biofuel production,

2006-01-01T23:59:59.000Z

500

Yuzhong Liu Curriculum vitae  

E-Print Network [OSTI]

Curriculum vitae 2 · Detoxification of phorbol esters in Jatropha Curcas seeds, which contain 30-35% oil and could be a potential source of biodiesel · Seeds of Jatropha Curcas were incubated with soil

Yaghi, Omar M.