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Note: This page contains sample records for the topic "methanol ocean thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Thermally integrated staged methanol reformer and method  

DOE Patents [OSTI]

A thermally integrated two-stage methanol reformer including a heat exchanger and first and second reactors colocated in a common housing in which a gaseous heat transfer medium circulates to carry heat from the heat exchanger into the reactors. The heat transfer medium comprises principally hydrogen, carbon dioxide, methanol vapor and water vapor formed in a first stage reforming reaction. A small portion of the circulating heat transfer medium is drawn off and reacted in a second stage reforming reaction which substantially completes the reaction of the methanol and water remaining in the drawn-off portion. Preferably, a PrOx reactor will be included in the housing upstream of the heat exchanger to supplement the heat provided by the heat exchanger.

Skala, Glenn William (Churchville, NY); Hart-Predmore, David James (Rochester, NY); Pettit, William Henry (Rochester, NY); Borup, Rodney Lynn (East Rochester, NY)

2001-01-01T23:59:59.000Z

2

Ocean Thermal Extractable Energy Visualization: Final Technical...  

Office of Environmental Management (EM)

Ocean Thermal Extractable Energy Visualization: Final Technical Report Ocean Thermal Extractable Energy Visualization: Final Technical Report Report about the Ocean Thermal...

3

OCEAN THERMAL ENERGY CONVERSION PROGRAMMATIC ENVIRONMENTAL ASSESSMENT  

E-Print Network [OSTI]

M.D. (editor) Ocean Thermal Energy Conversion (OTEC) Draftin Ocean Thermal Energy Conversion (OTEC) technology haveThe Ocean Thermal Energy Conversion (OTEC) 2rogrammatic

Sands, M.Dale

2013-01-01T23:59:59.000Z

4

OCEAN THERMAL ENERGY CONVERSION PROGRAMMATIC ENVIRONMENTAL ASSESSMENT  

E-Print Network [OSTI]

M.D. (editor) Ocean Thermal Energy Conversion (OTEC) Draftof ocean thermal energy conversion technology. U.S. Depart~June 1-11, 1980 OCEAN THERMAL ENERGY CONVERSION PROGRAMMATIC

Sands, M.Dale

2013-01-01T23:59:59.000Z

5

OCEAN THERMAL ENERGY CONVERSION PROGRAMMATIC ENVIRONMENTAL ASSESSMENT  

E-Print Network [OSTI]

M.D. (editor) Ocean Thermal Energy Conversion (OTEC) Draftr:he comnercialization of ocean thermal energy conversionJune 1-11, 1980 OCEAN THERMAL ENERGY CONVERSION PROGRAMMATIC

Sands, M.Dale

2013-01-01T23:59:59.000Z

6

OCEAN THERMAL ENERGY CONVERSION PROGRAMMATIC ENVIRONMENTAL ASSESSMENT  

E-Print Network [OSTI]

Sands, M.D. (editor) Ocean Thermal Energy Conversion (OTEC)r:he comnercialization of ocean thermal energy conversionJune 1-11, 1980 OCEAN THERMAL ENERGY CONVERSION PROGRAMMATIC

Sands, M.Dale

2013-01-01T23:59:59.000Z

7

DRAFT. ENVIRONMENTAL ASSESSMENT OCEAN THERMAL ENERGY CONVERSION (OTEC) PILOT PLANTS  

E-Print Network [OSTI]

Fifth Ocean Thermal Energy Conversion Conference, Februarythe Sixth Ocean Thermal Energy Conversion Conference. OceanSixth Ocean Thermal Energy conversion Conference. June 19-

Sullivan, S.M.

2014-01-01T23:59:59.000Z

8

Ocean Thermal Energy Conversion LUIS A. VEGA  

E-Print Network [OSTI]

Ocean Thermal Energy Conversion LUIS A. VEGA Hawaii Natural Energy Institute, School of Ocean depths of 20 m (surface water) and 1,000 m. OTEC Ocean Thermal Energy Conversion, the process of converting the ocean thermal energy into electricity. OTEC transfer function The relationship between

9

DRAFT. ENVIRONMENTAL ASSESSMENT OCEAN THERMAL ENERGY CONVERSION (OTEC) PILOT PLANTS  

E-Print Network [OSTI]

Commercial ocean thermal energy conversion ( OTEC) plants byand M.D. Sands. Ocean thermal energy conversion (OTEC) pilotfield of ocean thermal energy conversion discharges. I~. L.

Sullivan, S.M.

2014-01-01T23:59:59.000Z

10

OCEAN THERMAL ENERGY CONVERSION (OTEC) PROGRAMMATIC ENVIRONMENTAL ANALYSIS  

E-Print Network [OSTI]

of ocean thermal energy conversion technology. U.S. DOE.Open cycle ocean thermal energy conversion. A preliminaryof the Fifth Ocean Thermal Energy Conversion Conference,

Sands, M. D.

2011-01-01T23:59:59.000Z

11

ENVIRONMENTAL ASSESSMENT OCEAN THERMAL ENERGY CONVERSION (OTEC) PILOT PLANTS  

E-Print Network [OSTI]

Sands. 1980. Ocean thermal energy conversion (OTEC) pilotCommercial ocean thermal energy conversion (OTEC) plants byof the Fifth Ocean Thermal Energy Conversion Conference,

Sullivan, S.M.

2014-01-01T23:59:59.000Z

12

ENVIRONMENTAL ASSESSMENT OCEAN THERMAL ENERGY CONVERSION (OTEC) PILOT PLANTS  

E-Print Network [OSTI]

Fifth Ocean Thermal Energy Conversion Conference, FebruarySixth Ocean Thermal Energy Conversion Conference, June 19-Fifth Ocean Thermal Energy Conversion Conference, February

Sullivan, S.M.

2014-01-01T23:59:59.000Z

13

OCEAN THERMAL ENERGY CONVERSION (OTEC) PROGRAMMATIC ENVIRONMENTAL ANALYSIS  

E-Print Network [OSTI]

Fifth Ocean Thermal Energy Conversion Conference, FebruaryFifth Ocean Thermal Energy Conversion Conference, FebruarySixth Ocean Thermal Energy Conversion Conference. June 19-

Sands, M. D.

2011-01-01T23:59:59.000Z

14

OCEAN THERMAL ENERGY CONVERSION: AN OVERALL ENVIRONMENTAL ASSESSMENT  

E-Print Network [OSTI]

1980 :. i l OCEAN THERMAL ENERGY CONVERSION: ENVIRONMENTALM.D. (editor). 1980. Ocean Thermal Energy Conversion DraftDevelopment Plan. Ocean Thermal Energy Conversion. U.S. DOE

Sands, M.Dale

2013-01-01T23:59:59.000Z

15

ENVIRONMENTAL ASSESSMENT OCEAN THERMAL ENERGY CONVERSION (OTEC) PILOT PLANTS  

E-Print Network [OSTI]

Commercial ocean thermal energy conversion (OTEC) plants byof the Fifth Ocean Thermal Energy Conversion Conference,Sands. 1980. Ocean thermal energy conversion (OTEC) pilot

Sullivan, S.M.

2014-01-01T23:59:59.000Z

16

OCEAN THERMAL ENERGY CONVERSION (OTEC) PROGRAMMATIC ENVIRONMENTAL ANALYSIS  

E-Print Network [OSTI]

of ocean thermal energy conversion technology. U.S. DOE.Open cycle ocean thermal energy conversion. A preliminaryCompany. Ocean thermal energy conversion mission analysis

Sands, M. D.

2011-01-01T23:59:59.000Z

17

Ocean Thermal Energy Conversion: Potential Environmental Impacts and Fisheries  

E-Print Network [OSTI]

Ocean Thermal Energy Conversion: Potential Environmental Impacts and Fisheries Christina M Comfort Institute #12;Ocean Thermal Energy Conversion (OTEC) · Renewable energy ­ ocean thermal gradient · Large

Hawai'i at Manoa, University of

18

DRAFT. ENVIRONMENTAL ASSESSMENT OCEAN THERMAL ENERGY CONVERSION (OTEC) PILOT PLANTS  

E-Print Network [OSTI]

Commercial ocean thermal energy conversion ( OTEC) plants byfield of ocean thermal energy conversion discharges. I~. L.II of the Sixth Ocean Thermal Energy conversion Conference.

Sullivan, S.M.

2014-01-01T23:59:59.000Z

19

ENVIRONMENTAL ASSESSMENT OCEAN THERMAL ENERGY CONVERSION (OTEC) PILOT PLANTS  

E-Print Network [OSTI]

Commercial ocean thermal energy conversion (OTEC) plants bySands. 1980. Ocean thermal energy conversion (OTEC) pilotof the Ocean Thermal Energy Conversion (OTEC) Biofouling,

Sullivan, S.M.

2014-01-01T23:59:59.000Z

20

OCEAN THERMAL ENERGY CONVERSION (OTEC) PROGRAMMATIC ENVIRONMENTAL ANALYSIS  

E-Print Network [OSTI]

of the Ocean Thermal Energy Conversion (OTEC) Biofouling,development of ocean thermal energy conversion (OTEC) plant-impact assessment ocean thermal energy conversion (OTEC)

Sands, M. D.

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "methanol ocean thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

DRAFT. ENVIRONMENTAL ASSESSMENT OCEAN THERMAL ENERGY CONVERSION (OTEC) PILOT PLANTS  

E-Print Network [OSTI]

Commercial ocean thermal energy conversion ( OTEC) plants bySands. Ocean thermal energy conversion (OTEC) pilot plantof the Ocean Thermal Energy Conversion (OTEC) Biofouling,

Sullivan, S.M.

2014-01-01T23:59:59.000Z

22

DRAFT. ENVIRONMENTAL ASSESSMENT OCEAN THERMAL ENERGY CONVERSION (OTEC) PILOT PLANTS  

E-Print Network [OSTI]

1979. Commercial ocean thermal energy conversion ( OTEC)field of ocean thermal energy conversion discharges. I~. L.II of the Sixth Ocean Thermal Energy conversion Conference.

Sullivan, S.M.

2014-01-01T23:59:59.000Z

23

ENVIRONMENTAL ASSESSMENT OCEAN THERMAL ENERGY CONVERSION (OTEC) PILOT PLANTS  

E-Print Network [OSTI]

1979. Commercial ocean thermal energy conversion (OTEC)of the Fifth Ocean Thermal Energy Conversion Conference,Sands. 1980. Ocean thermal energy conversion (OTEC) pilot

Sullivan, S.M.

2014-01-01T23:59:59.000Z

24

OCEAN THERMAL ENERGY CONVERSION: AN OVERALL ENVIRONMENTAL ASSESSMENT  

E-Print Network [OSTI]

M.D. (editor). 1980. Ocean Thermal Energy Conversion Draft1980 :. i l OCEAN THERMAL ENERGY CONVERSION: ENVIRONMENTALDevelopment Plan. Ocean Thermal Energy Conversion. U.S. DOE

Sands, M.Dale

2013-01-01T23:59:59.000Z

25

OCEAN THERMAL ENERGY CONVERSION (OTEC) PROGRAMMATIC ENVIRONMENTAL ANALYSIS  

E-Print Network [OSTI]

for the commercialization of ocean thermal energy conversionE. Hathaway. Open cycle ocean thermal energy conversion. AElectric Company. Ocean thermal energy conversion mission

Sands, M. D.

2011-01-01T23:59:59.000Z

26

DRAFT. ENVIRONMENTAL ASSESSMENT OCEAN THERMAL ENERGY CONVERSION (OTEC) PILOT PLANTS  

E-Print Network [OSTI]

1979. Commercial ocean thermal energy conversion ( OTEC)the intermediate field of ocean thermal energy conversionII of the Sixth Ocean Thermal Energy conversion Conference.

Sullivan, S.M.

2014-01-01T23:59:59.000Z

27

ENVIRONMENTAL ASSESSMENT OCEAN THERMAL ENERGY CONVERSION (OTEC) PILOT PLANTS  

E-Print Network [OSTI]

1979. Commercial ocean thermal energy conversion (OTEC)of the Fifth Ocean Thermal Energy Conversion Conference,and M.D. Sands. 1980. Ocean thermal energy conversion (OTEC)

Sullivan, S.M.

2014-01-01T23:59:59.000Z

28

Ocean Thermal | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth's HeatMexico:CommunityNorthwest BasinOahu, Hawaii:EnergyOpenTheOceanThermal

29

Ocean Thermal Resource and Site Selection Criteria (January 2011) luisvega@hawaii.edu Ocean Thermal Resources  

E-Print Network [OSTI]

Ocean Thermal Resource and Site Selection Criteria (January 2011) luisvega@hawaii.edu 1 Ocean Thermal Resources The vast size of the ocean thermal resource and the baseload capability of OTEC systems of Hawaii throughout the year and at all times of the day. This is an indigenous renewable energy resource

30

Assessment of ocean thermal energy conversion  

E-Print Network [OSTI]

Ocean thermal energy conversion (OTEC) is a promising renewable energy technology to generate electricity and has other applications such as production of freshwater, seawater air-conditioning, marine culture and chilled-soil ...

Muralidharan, Shylesh

2012-01-01T23:59:59.000Z

31

OCEAN THERMAL ENERGY CONVERSION (OTEC) PROGRAMMATIC ENVIRONMENTAL ANALYSIS  

E-Print Network [OSTI]

for the commercialization of ocean thermal energy conversionOpen cycle ocean thermal energy conversion. A preliminary1978. 'Open cycle thermal energy converS1on. A preliminary

Sands, M. D.

2011-01-01T23:59:59.000Z

32

COMMERCIAL FISHERY DATA FROM A PROPOSED OCEAN THERMAL ENERGY CONVERSION (OTEC) SITE IN PUERTO RICO  

E-Print Network [OSTI]

proposed Ocean Thermal Energy Conversion (OTEC) sites toassessment: ocean thermal energy conversion (OTEC) program;operation of Ocean Thermal Energy Conversion (OTEC) power

Ryan, Constance J.

2013-01-01T23:59:59.000Z

33

A PRELIMINARY EVALUATION OF IMPINGEMENT AND ENTRAINMENT BY OCEAN THERMAL ENERGY CONVERSION (OTEC) PLANTS  

E-Print Network [OSTI]

Assessment, Ocean Thermal Energy Conversion (OTEC) ProgramAssessment Ocean Thermal Energy Conversion (OTEC), U.S.recommendations for Ocean Thermal Energy Conversion (OTEC)

Sullivan, S.M.

2013-01-01T23:59:59.000Z

34

A PRELIMINARY EVALUATION OF IMPINGEMENT AND ENTRAINMENT BY OCEAN THERMAL ENERGY CONVERSION (OTEC) PLANTS  

E-Print Network [OSTI]

Assessment, Ocean Thermal Energy Conversion (OTEC) ProgramAssessment Ocean Thermal Energy Conversion (OTEC), U.S.for Ocean Thermal Energy Conversion (OTEC) plants. Argonne,

Sullivan, S.M.

2013-01-01T23:59:59.000Z

35

COMMERCIAL FISHERY DATA FROM A PROPOSED OCEAN THERMAL ENERGY CONVERSION (OTEC) SITE IN PUERTO RICO  

E-Print Network [OSTI]

assessment: ocean thermal energy conversion (OTEC) program;proposed Ocean Thermal Energy Conversion (OTEC) sites tooperation of Ocean Thermal Energy Conversion (OTEC) power

Ryan, Constance J.

2013-01-01T23:59:59.000Z

36

A PRELIMINARY EVALUATION OF IMPINGEMENT AND ENTRAINMENT BY OCEAN THERMAL ENERGY CONVERSION (OTEC) PLANTS  

E-Print Network [OSTI]

nental Assessment, Ocean Thermal Energy Conversion (OTEC)Impact Assessment Ocean Thermal Energy Conversion (OTEC),Intake Screens for Ocean Thermal Energy M.S. Thesis. Oregon

Sullivan, S.M.

2013-01-01T23:59:59.000Z

37

COMMERCIAL FISHERY DATA FROM A PROPOSED OCEAN THERMAL ENERGY CONVERSION (OTEC) SITE IN PUERTO RICO  

E-Print Network [OSTI]

at several proposed Ocean Thermal Energy Conversion (OTEC)Environmental assessment: ocean thermal energy conversion (The operation of Ocean Thermal Energy Conversion (OTEC)

Ryan, Constance J.

2013-01-01T23:59:59.000Z

38

Ocean Thermal Resources off the Hawaiian Islands luisvega@hawaii.edu Ocean Thermal Resources off the Hawaiian Islands  

E-Print Network [OSTI]

information to assist developers of ocean thermal energy conversion (OTEC) systems in site selection Energy Conversion The immense size of the ocean thermal resource and the baseload capability of OTECOcean Thermal Resources off the Hawaiian Islands luisvega@hawaii.edu 1 Ocean Thermal Resources off

39

Ocean Thermal Energy Conversion Mostly about USA  

E-Print Network [OSTI]

Ocean Thermal Energy Conversion History Mostly about USA 1980's to 1990's and bias towards Vega Structures (Plantships) · Bottom-Mounted Structures · Model Basin Tests/ At-Sea Tests · 210 kW OC-OTEC) #12;#12;Claude's Off Rio de Janeiro (1933) · Floating Ice Plant: 2.2 MW OC- OTEC to produce 2000

40

NAVFAC Ocean Thermal Energy Conversion (OTEC) Project  

E-Print Network [OSTI]

NAVFAC Ocean Thermal Energy Conversion (OTEC) Project Contract Number N62583-09-C-0083 CDRL A014 OTEC Mini-Spar Pilot Plant 9 December 2011 OTEC-2011-001-4 Prepared for: Naval Facilities; distribution is unlimited. #12; Configuration Report and Development Plan Volume 4 Site Specific OTEC

Note: This page contains sample records for the topic "methanol ocean thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

August 2011 Environmental Assessment of Ocean Thermal Energy  

E-Print Network [OSTI]

August 2011 1 Environmental Assessment of Ocean Thermal Energy Conversion in Hawaii Available data prompted ocean thermal energy conversion (OTEC) technology to be re-considered for use in Hawaii for OTEC development. Keywords- Ocean thermal energy conversion, OTEC, renewable energy, Hawaii

42

Open cycle ocean thermal energy conversion system  

DOE Patents [OSTI]

An improved open cycle ocean thermal energy conversion system including a flash evaporator for vaporizing relatively warm ocean surface water and an axial flow, elastic fluid turbine having a vertical shaft and axis of rotation. The warm ocean water is transmitted to the evaporator through a first prestressed concrete skirt-conduit structure circumferentially situated about the axis of rotation. The unflashed warm ocean water exits the evaporator through a second prestressed concrete skirt-conduit structure located circumferentially about and radially within the first skirt-conduit structure. The radially inner surface of the second skirt conduit structure constitutes a cylinder which functions as the turbine's outer casing and obviates the need for a conventional outer housing. The turbine includes a radially enlarged disc element attached to the shaft for supporting at least one axial row of radially directed blades through which the steam is expanded. A prestressed concrete inner casing structure of the turbine has upstream and downstream portions respectively situated upstream and downstream from the disc element. The radially outer surfaces of the inner casing portions and radially outer periphery of the axially interposed disc cooperatively form a downwardly radially inwardly tapered surface. An annular steam flowpath of increasing flow area in the downward axial direction is radially bounded by the inner and outer prestressed concrete casing structures. The inner casing portions each include a transversely situated prestressed concrete circular wall for rotatably supporting the turbine shaft and associated structure. The turbine blades are substantially radially coextensive with the steam flowpath and receive steam from the evaporator through an annular array of prestressed concrete stationary vanes which extend between the inner and outer casings to provide structural support therefor and impart a desired flow direction to the steam.

Wittig, J. Michael (West Goshen, PA)

1980-01-01T23:59:59.000Z

43

E. Guilyardi G. Madec L. Terray The role of lateral ocean physics in the upper ocean thermal balance  

E-Print Network [OSTI]

inertia and to its opacity, the ocean stores vast amounts of energy, away from a direct contactE. Guilyardi á G. Madec á L. Terray The role of lateral ocean physics in the upper ocean thermal balance of a coupled ocean-atmosphere GCM Received: 24 January 2000 / Accepted: 11 September 2000 Abstract

Guilyardi, Eric

44

OCEAN THERMAL ENERGY CONVERSION ECOLOGICAL DATA REPORT FROM 0. S. S. RESEARCHER IN GULF OF MEXICO, JULY 12-23, 1977.  

E-Print Network [OSTI]

LBL-8945 GOTEC-01 OCEAN THERMAL ENERGY CONVERSION ECOLOGICALThree Proposed Ocean Thermal Energy Conversion (OTEC) Sites:an operating Ocean Thermal Energy Conversion plant were in-

Quinby-Hunt, M.S.

2008-01-01T23:59:59.000Z

45

OCEAN THERMAL ENERGY CONVERSION PRELIMINARY DATA REPORT FOR THE NOVEMBER 1977 GOTEC-02 CRUISE TO THE GULF OF MEXICO MOBILE SITE  

E-Print Network [OSTI]

9437 GOTEC-02 OCEAN THERMAL ENERGY CONVERSION PRELIMINARYto potential Ocean Thermal Energy Conversion (OTEC) sites inThree Proposed Ocean Thermal Energy Conversion (OTEC) Sites:

Commins, M.L.

2010-01-01T23:59:59.000Z

46

OCEAN THERMAL ENERGY CONVERSION PRELIMINARY DATA REPORT FOR THE NOVEMBER 1977 GOTEC-02 CRUISE TO THE GULF OF MEXICO MOBILE SITE  

E-Print Network [OSTI]

9437 GOTEC-02 OCEAN THERMAL ENERGY CONVERSION PRELIMINARYThree Proposed Ocean Thermal Energy Conversion (OTEC) Sites:al. , (1979) Ocean Thermal Energy Conversion, Eco- logical

Commins, M.L.

2010-01-01T23:59:59.000Z

47

OCEAN THERMAL ENERGY CONVERSION ECOLOGICAL DATA REPORT FROM 0. S. S. RESEARCHER IN GULF OF MEXICO, JULY 12-23, 1977.  

E-Print Network [OSTI]

LBL-8945 GOTEC-01 OCEAN THERMAL ENERGY CONVERSION ECOLOGICALat Three Proposed Ocean Thermal Energy Conversion (OTEC)effect of an operating Ocean Thermal Energy Conversion plant

Quinby-Hunt, M.S.

2008-01-01T23:59:59.000Z

48

OCEAN THERMAL ENERGY CONVERSION PRELIMINARY DATA REPORT FOR THE NOVEMBER 1977 GOTEC-02 CRUISE TO THE GULF OF MEXICO MOBILE SITE  

E-Print Network [OSTI]

9437 GOTEC-02 OCEAN THERMAL ENERGY CONVERSION PRELIMINARYcruises to potential Ocean Thermal Energy Conversion (OTEC)at Three Proposed Ocean Thermal Energy Conversion (OTEC)

Commins, M.L.

2010-01-01T23:59:59.000Z

49

OCEAN THERMAL ENERGY CONVERSION PRELIMINARY DATA REPORT FOR THE NOVEMBER 1977 GOTEC-02 CRUISE TO THE GULF OF MEXICO MOBILE SITE  

E-Print Network [OSTI]

to potential Ocean Thermal Energy Conversion (OTEC) sites inThree Proposed Ocean Thermal Energy Conversion (OTEC) Sites:

Commins, M.L.

2010-01-01T23:59:59.000Z

50

2007 Survey of Energy Resources World Energy Council 2007 Ocean Thermal Energy Conversion COUNTRY NOTES  

E-Print Network [OSTI]

2007 Survey of Energy Resources World Energy Council 2007 Ocean Thermal Energy Conversion 573 and personal communication. Valuable inputs were provided by Don Lennard of Ocean Thermal Energy Conversion organisation. Australia At an ocean energy workshop held in Townsville, northern Queensland in September 2005

51

Ocean thermal energy conversion plants : experimental and analytical study of mixing and recirculation  

E-Print Network [OSTI]

Ocean thermal energy conversion (OTEC) is a method of generating power using the vertical temperature gradient of the tropical ocean as an energy source. Experimental and analytical studies have been carried out to determine ...

Jirka, Gerhard H.

52

Near-inertial and thermal to atmospheric forcing in the North Atlantic Ocean  

E-Print Network [OSTI]

Observational and modeling techniques are employed to investigate the thermal and inertial upper ocean response to wind and buoyancy forcing in the North Atlantic Ocean. First, the seasonal kinetic energy variability of ...

Silverthorne, Katherine E

2010-01-01T23:59:59.000Z

53

Carbon dioxide release from ocean thermal energy conversion (OTEC) cycles  

SciTech Connect (OSTI)

This paper presents the results of recent measurements of CO{sub 2} release from an open-cycle ocean thermal energy conversion (OTEC) experiment. Based on these data, the rate of short-term CO{sub 2} release from future open-cycle OTEC plants is projected to be 15 to 25 times smaller than that from fossil-fueled electric power plants. OTEC system that incorporate subsurface mixed discharge are expected to result in no long-term release. OTEC plants can significantly reduce CO{sub 2} emissions when substituted for fossil-fueled power generation. 12 refs., 4 figs., 3 tabs.

Green, H.J. (Solar Energy Research Inst., Golden, CO (USA)); Guenther, P.R. (Scripps Institution of Oceanography, La Jolla, CA (USA))

1990-09-01T23:59:59.000Z

54

COMMERCIAL FISHERY DATA FROM A PROPOSED OCEAN THERMAL ENERGY CONVERSION (OTEC) SITE IN PUERTO RICO  

E-Print Network [OSTI]

Ocean Thermal Energy Conversion (OTEC) sites to identify thefishery resources at potential OTEC sites. At this time, thethermal energy conversion (OTEC) program; preoperational

Ryan, Constance J.

2013-01-01T23:59:59.000Z

55

Economics of Ocean Thermal Energy Conversion Luis A. Vega, Ph.D.  

E-Print Network [OSTI]

Economics of Ocean Thermal Energy Conversion (OTEC) by Luis A. Vega, Ph.D. Published by the American Society of Civil Engineers (ASCE) Chapter 7 of "Ocean Energy Recovery: The State of the Art" 1992 #12;Published in Ocean Energy Recovery, pp 152-181, ASCE (1992) ii Table of Contents Tables /Figures

56

Modeling the Physical and Biochemical Influence of Ocean Thermal Energy Conversion Plant Discharges into their Adjacent Waters  

Broader source: Energy.gov [DOE]

Modeling the Physical and Biochemical Influence of Ocean Thermal Energy Conversion Plant Discharges into their Adjacent Waters

57

Draft environmental assessment: Ocean Thermal Energy Conversion (OTEC) Pilot Plants  

SciTech Connect (OSTI)

This Environmental Assessment (EA) has been prepared, in accordance with the National Environmental Policy Act of 1969, for the deployment and operation of a commercial 40-Megawatt (MW) Ocean Thermal Energy Conversion (OTEC) Pilot Plant (hereafter called the Pilot Plant). A description of the proposed action is presented, and a generic environment typical of the candidate Pilot Plant siting regions is described. An assessment of the potential environmental impacts associated with the proposed action is given, and the risk of credible accidents and mitigating measures to reduce these risks are considered. The Federal and State plans and policies the proposed action will encompass are described. Alternatives to the proposed action are presented. Appendix A presents the navigation and environmental information contained in the US Coast Pilot for each of the candidate sites; Appendix B provides a brief description of the methods and calculations used in the EA. It is concluded that environmental disturbances associated with Pilot Plant activities could potentially cause significant environmental impacts; however, the magnitude of these potential impacts cannot presently be assessed, due to insufficient engineering and environmental information. A site- and design-specific OTEC Pilot Plant Environmental Impact Statement (EIS) is required to resolve the potentially significant environmental effects associated with Pilot Plant deployment and operation. (WHK)

Sullivan, S.M.; Sands, M.D.; Donat, J.R.; Jepsen, P.; Smookler, M.; Villa, J.F.

1981-02-01T23:59:59.000Z

58

Ocean Thermal Energy Conversion (OTEC) Programmatic Environmental Analysis--Appendices  

SciTech Connect (OSTI)

The programmatic environmental analysis is an initial assessment of Ocean Thermal Energy Conversion (OTEC) technology considering development, demonstration and commercialization. It is concluded that the OTEC development program should continue because the development, demonstration, and commercialization on a single-plant deployment basis should not present significant environmental impacts. However, several areas within the OTEC program require further investigation in order to assess the potential for environmental impacts from OTEC operation, particularly in large-scale deployments and in defining alternatives to closed-cycle biofouling control: (1) Larger-scale deployments of OTEC clusters or parks require further investigations in order to assess optimal platform siting distances necessary to minimize adverse environmental impacts. (2) The deployment and operation of the preoperational platform (OTEC-1) and future demonstration platforms must be carefully monitored to refine environmental assessment predictions, and to provide design modifications which may mitigate or reduce environmental impacts for larger-scale operations. These platforms will provide a valuable opportunity to fully evaluate the intake and discharge configurations, biofouling control methods, and both short-term and long-term environmental effects associated with platform operations. (3) Successful development of OTEC technology to use the maximal resource capabilities and to minimize environmental effects will require a concerted environmental management program, encompassing many different disciplines and environmental specialties. This volume contains these appendices: Appendix A -- Deployment Scenario; Appendix B -- OTEC Regional Characterization; and Appendix C -- Impact and Related Calculations.

Authors, Various

1980-01-01T23:59:59.000Z

59

OCEAN THERMAL ENERGY CONVERSION (OTEC) PROGRAMMATIC ENVIRONMENTAL ANALYSIS  

E-Print Network [OSTI]

sheet] map I - 732). General Electric Company. Ocean thermalby Washom et al. General Electric (1977), Francis (1977),selected is based on General Electric estimated the ammonia

Sands, M. D.

2011-01-01T23:59:59.000Z

60

Response of oceanic hydrate-bearing sediments to thermal stresses  

E-Print Network [OSTI]

are often observed in unconsolidated oceanic sediments11.wellbore assembly if a weak unconsolidated porous medium isevidence, because of the unconsolidated, unlithified nature

Moridis, G.J.; Kowalsky, M.B.

2006-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "methanol ocean thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Ocean thermal energy. Quarterly report, October-December 1981  

SciTech Connect (OSTI)

This quarterly report summarizes work on the following tasks: OTEC methanol; approaches for financing OTEC proof-of-concept experimental vessels; investigation of OTEC-ammonia as an alternative fuel; review of electrolyzer development programs and requirements; hybrid geothermal-OTEC power plants: single-cycle performance; estimates; and hybrid geothermal-OTEC power plants: dual-cycle performance estimates.

Not Available

1981-12-30T23:59:59.000Z

62

Potential environmental consequences of ocean thermal energy conversion (OTEC) plants. A workshop  

SciTech Connect (OSTI)

The concept of generating electrical power from the temperature difference between surface and deep ocean waters was advanced over a century ago. A pilot plant was constructed in the Caribbean during the 1920's but commercialization did not follow. The US Department of Energy (DOE) earlier planned to construct a single operational 10MWe Ocean Thermal Energy Conversion (OTEC) plant by 1986. However, Public Law P.L.-96-310, the Ocean Thermal Energy Conversion Research, Development and Demonstration Act, and P.L.-96-320, the Ocean Thermal Energy Conversion Act of 1980, now call for acceleration of the development of OTEC plants, with capacities of 100 MWe in 1986, 500 MWe in 1989, and 10,000 MWe by 1999 and provide for licensing and permitting and loan guarantees after the technology has been demonstrated.

Walsh, J.J. (ed.)

1981-05-01T23:59:59.000Z

63

USE OF MIXTURES AS WORKING FLUIDS IN OCEAN THERMAL ENERGY CONVERSION CYCLES  

E-Print Network [OSTI]

Mixtures offer potential advantages over pure compounds as working fluids in ocean thermal energy conversion cycles. Power plant capital costs per unit of energy output can be reduced using mixtures because of increased thermal efficiency and/or decreased heat exchanger size requirements. Mixtures

Khan Zafar Iqbal; Kenneth E. Starling

64

List of Ocean Thermal Incentives | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth's Heat JumpInc Place:KeystoneSolarList of GeothermalMethanol

65

ENVIRONMENTAL ASSESSMENT OCEAN THERMAL ENERGY CONVERSION (OTEC) PILOT PLANTS  

E-Print Network [OSTI]

the external fluid mechanics of OTEC plants: report coveringocean thermal energy conversion (OTEC) plants by mid-1980's.1980. A baseline design of a 40-MW OTEC Pilot Johns Hopkins

Sullivan, S.M.

2014-01-01T23:59:59.000Z

66

Ocean Thermal Energy Conversion Basics | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Year in3.pdfEnergyDepartment of Energy(National1 -OSSGasof Energy Ocean EnergyRenewable

67

Ocean Thermal Extractable Energy Visualization: Final Technical Report  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Year in3.pdfEnergyDepartment of Energy(National1 -OSSGasof Energy Ocean

68

Ocean Thermal Energy Conversion Primer L. A. Vega, Ph.D.  

E-Print Network [OSTI]

source and the heat sink required for a heat engine. A practical application is found in a system (heat engine) designed to transform the thermal energy into electricity. This is referred to as OTEC for Ocean seawater is flash-evaporated in a vacuum chamber. The resulting low-pressure steam is used to drive

69

Open cycle ocean thermal energy conversion system structure  

DOE Patents [OSTI]

A generally mushroom-shaped, open cycle OTEC system and distilled water producer which has a skirt-conduit structure extending from the enlarged portion of the mushroom to the ocean. The enlarged part of the mushroom houses a toroidal casing flash evaporator which produces steam which expands through a vertical rotor turbine, partially situated in the center of the blossom portion and partially situated in the mushroom's stem portion. Upon expansion through the turbine, the motive steam enters a shell and tube condenser annularly disposed about the rotor axis and axially situated beneath the turbine in the stem portion. Relatively warm ocean water is circulated up through the radially outer skirt-conduit structure entering the evaporator through a radially outer portion thereof, flashing a portion thereof into motive steam, and draining the unflashed portion from the evaporator through a radially inner skirt-conduit structure. Relatively cold cooling water enters the annular condenser through the radially inner edge and travels radially outwardly into a channel situated along the radially outer edge of the condenser. The channel is also included in the radially inner skirt-conduit structure. The cooling water is segregated from the potable, motive steam condensate which can be used for human consumption or other processes requiring high purity water. The expansion energy of the motive steam is partially converted into rotational mechanical energy of the turbine rotor when the steam is expanded through the shaft attached blades. Such mechanical energy drives a generator also included in the enlarged mushroom portion for producing electrical energy. Such power generation equipment arrangement provides a compact power system from which additional benefits may be obtained by fabricating the enclosing equipment, housings and component casings from low density materials, such as prestressed concrete, to permit those casings and housings to also function as a floating support vessel.

Wittig, J. Michael (West Goshen, PA)

1980-01-01T23:59:59.000Z

70

Ocean thermal plantships for production of ammonia as the hydrogen carrier.  

SciTech Connect (OSTI)

Conventional petroleum, natural gas, and coal are the primary sources of energy that have underpinned modern civilization. Their continued availability in the projected quantities required and the impacts of emission of greenhouse gases (GHGs) on the environment are issues at the forefront of world concerns. New primary sources of energy are being sought that would significantly reduce the emissions of GHGs. One such primary source that can help supply energy, water, and fertilizer without GHG emissions is available in the heretofore unexploited thermal gradients of the tropical oceans. The world's oceans are the largest natural collector and reservoir of solar energy. The potential of ocean energy is limitless for producing base-load electric power or ammonia as the hydrogen carrier and fresh water from seawater. However, until now, ocean energy has been virtually untapped. The general perception is that ocean thermal energy is limited to tropical countries. Therefore, the full potential of at-sea production of (1) ammonia as a hydrogen carrier and (2) desalinated water has not been adequately evaluated. Using ocean thermal plantships for the at-sea co-production of ammonia as a hydrogen carrier and desalinated water offer potential energy, environmental, and economic benefits that support the development of the technology. The introduction of a new widespread solution to our projected energy supply requires lead times of a decade or more. Although continuation of the ocean thermal program from the 1970s would likely have put us in a mitigating position in the early 2000s, we still have a window of opportunity to dedicate some of our conventional energy sources to the development of this renewable energy by the time new sources would be critically needed. The primary objective of this project is to evaluate the technical and economic viability of ocean thermal plantships for the production of ammonia as the hydrogen carrier. This objective is achieved by completing project tasks that consist of updating the John Hopkins University/Applied Physics Laboratory (JHU/APL) pilot plantship design and extrapolating it to commercial plantships, evaluating a new energy-efficient ammonia synthesis process, evaluating the co-production of desalinated water on plantships, and developing a conceptual design of a satellite plantships system for commercial-scale ammonia production. In addition, an industrial workshop was organized to present the results and develop future goals for commercialization of ocean thermal plantships by 2015. The following goals, arranged in chronological order, were examined at the workshop: (1) Global displacement of petroleum-fuel-based (diesel, fuel oil, naphtha) power generation for freeing up these fuels for transportation, chemical feedstock, and other high-valued uses; (2) At-sea production of desalinated water for regions of critical water shortages; (3) Displacement of carbon-based feed stocks and energy for production of ammonia fertilizers; (4) Development of hydrogen supply to allow economic processing of heavy crude oils and upgrading oil sands; (5) Development of ammonia-fueled distributed energy to displace natural-gas fueled power generation to free up natural gas for higher-value uses and the mitigation of issues associated with imported liquefied natural gas (LNG); and (6) Use of ammonia as a hydrogen carrier for transportation.

Panchal, C.B.; Pandolfini, P. P.; Kumm, W. H.; Energy Systems; Johns Hopkins Univ.; Arctic Energies, Ltd.

2009-12-02T23:59:59.000Z

71

Near and far field models of external fluid mechanics of Ocean Thermal Energy Conversion (OTEC) power plants  

E-Print Network [OSTI]

The world is facing the challenge of finding new renewable sources of energy - first, in response to fossil fuel reserve depletion, and second, to reduce greenhouse gas emissions. Ocean Thermal Energy Conversion (OTEC) can ...

Rodrguez Buo, Mariana

2013-01-01T23:59:59.000Z

72

Research on the external fluid mechanics of ocean thermal energy conversion plants : report covering experiments in a current  

E-Print Network [OSTI]

This report describes a set of experiments in a physical model study to explore plume transport and recirculation potential for a range of generic Ocean Thermal Energy Conversion (OTEC) plant designs and ambient conditions. ...

Fry, David J. (David James)

1981-01-01T23:59:59.000Z

73

Ocean Thermal Energy Conversion Life Cycle Cost Assessment, Final Technical Report, 30 May 2012  

SciTech Connect (OSTI)

The Ocean Thermal Energy Conversion (OTEC) Life Cycle Cost Assessment (OLCCA) is a study performed by members of the Lockheed Martin (LM) OTEC Team under funding from the Department of Energy (DOE), Award No. DE-EE0002663, dated 01/01/2010. OLCCA objectives are to estimate procurement, operations and maintenance, and overhaul costs for two types of OTEC plants: -Plants moored to the sea floor where the electricity produced by the OTEC plant is directly connected to the grid ashore via a marine power cable (Grid Connected OTEC plants) -Open-ocean grazing OTEC plant-ships producing an energy carrier that is transported to designated ports (Energy Carrier OTEC plants) Costs are developed using the concept of levelized cost of energy established by DOE for use in comparing electricity costs from various generating systems. One area of system costs that had not been developed in detail prior to this analysis was the operations and sustainment (O&S) cost for both types of OTEC plants. Procurement costs, generally referred to as capital expense and O&S costs (operations and maintenance (O&M) costs plus overhaul and replacement costs), are assessed over the 30 year operational life of the plants and an annual annuity calculated to achieve a levelized cost (constant across entire plant life). Dividing this levelized cost by the average annual energy production results in a levelized cost of electricity, or LCOE, for the OTEC plants. Technical and production efficiency enhancements that could result in a lower value of the OTEC LCOE were also explored. The thermal OTEC resource for Oahu, Hawai?¢????i and projected build out plan were developed. The estimate of the OTEC resource and LCOE values for the planned OTEC systems enable this information to be displayed as energy supplied versus levelized cost of the supplied energy; this curve is referred to as an Energy Supply Curve. The Oahu Energy Supply Curve represents initial OTEC deployment starting in 2018 and demonstrates the predicted economies of scale as technology and efficiency improvements are realized and larger more economical plants deployed. Utilizing global high resolution OTEC resource assessment from the Ocean Thermal Extractable Energy Visualization (OTEEV) project (an independent DOE project), Global Energy Supply Curves were generated for Grid Connected and Energy Carrier OTEC plants deployed in 2045 when the predicted technology and efficiencies improvements are fully realized. The Global Energy Supply Curves present the LCOE versus capacity in ascending order with the richest, lowest cost resource locations being harvested first. These curves demonstrate the vast ocean thermal resource and potential OTEC capacity that can be harvested with little change in LCOE.

Martel, Laura; Smith, Paul; Rizea, Steven; Van Ryzin, Joe; Morgan, Charles; Noland, Gary; Pavlosky, Rick; Thomas, Michael

2012-06-30T23:59:59.000Z

74

OCEAN THERMAL ENERGY CONVERSION PRELIMINARY DATA REPORT FOR THE NOVEMBER 1977 GOTEC-02 CRUISE TO THE GULF OF MEXICO MOBILE SITE  

E-Print Network [OSTI]

Ocean Thermal Energy Conversion (OTEC) sites in the Gulf ofBiofoul- ing and Corrosion of OTEC plants ~ Selected Sites.Thermal Energy Conversion (OTEC) Sites: Puerto Rico, St.

Commins, M.L.

2010-01-01T23:59:59.000Z

75

Ocean Thermal Extractable Energy Visualization- Final Technical Report on Award DE-EE0002664. October 28, 2012  

SciTech Connect (OSTI)

The Ocean Thermal Extractable Energy Visualization (OTEEV) project focuses on assessing the Maximum Practicably Extractable Energy (MPEE) from the world's ocean thermal resources. MPEE is defined as being sustainable and technically feasible, given today's state-of-the-art ocean energy technology. Under this project the OTEEV team developed a comprehensive Geospatial Information System (GIS) dataset and software tool, and used the tool to provide a meaningful assessment of MPEE from the global and domestic U.S. ocean thermal resources. The OTEEV project leverages existing NREL renewable energy GIS technologies and integrates extractable energy estimated from quality-controlled data and projected optimal achievable energy conversion rates. Input data are synthesized from a broad range of existing in-situ measurements and ground-truthed numerical models with temporal and spatial resolutions sufficient to reflect the local resource. Energy production rates are calculated for regions based on conversion rates estimated for current technology, local energy density of the resource, and sustainable resource extraction. Plant spacing and maximum production rates are then estimated based on a default plant size and transmission mechanisms. The resulting data are organized, displayed, and accessed using a multi-layered GIS mapping tool, http://maps.nrel.gov/mhk_atlas with a user-friendly graphical user interface.

Ascari, Matthew B.; Hanson, Howard P.; Rauchenstein, Lynn; Van Zwieten, James; Bharathan, Desikan; Heimiller, Donna; Langle, Nicholas; Scott, George N.; Potemra, James; Nagurny, N. John; Jansen, Eugene

2012-10-28T23:59:59.000Z

76

Recycling of wasted energy : thermal to electrical energy conversion  

E-Print Network [OSTI]

geo-thermal energy, ocean thermal energy, wasted heat ingeothermal energy, ocean thermal energy, wasted heat inthermal energy, geo/ocean-thermal energy, wasted heat in

Lim, Hyuck

2011-01-01T23:59:59.000Z

77

Lyapunov Exponents of a Simple Stochastic Model of the Thermally and Wind-Driven Ocean Circulation  

E-Print Network [OSTI]

August 8, 2002 Present Address: School of Earth and Ocean Sciences, University of Victoria, P.O. Box 3055 STN CSC,Victoria BC, Canada, V8P 5C2 0 #12;Abstract A reformulation of the simple model

Monahan, Adam Hugh

78

A PRELIMINARY EVALUATION OF IMPINGEMENT AND ENTRAINMENT BY OCEAN THERMAL ENERGY CONVERSION (OTEC) PLANTS  

E-Print Network [OSTI]

Thermal Energy Conversion (OTEC) Program PreoperationalThermal Energy Conversion (OTEC), U.S. Department of Energy,aspects of the screens for OTEC intake systems. U.S. Energy

Sullivan, S.M.

2013-01-01T23:59:59.000Z

79

E-Print Network 3.0 - atmosphere-ocean thermal contrast Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

thermal orbits at two contrasting grid locations in the millennial simulation of the ECHO-G coupled... Characterizing land surface processes: A quantitative analysis using...

80

Methanol partial oxidation reformer  

DOE Patents [OSTI]

A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

1999-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "methanol ocean thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Methanol partial oxidation reformer  

DOE Patents [OSTI]

A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

2001-01-01T23:59:59.000Z

82

Methanol partial oxidation reformer  

DOE Patents [OSTI]

A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

Ahmed, S.; Kumar, R.; Krumpelt, M.

1999-08-17T23:59:59.000Z

83

Methanol partial oxidation reformer  

DOE Patents [OSTI]

A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

Ahmed, S.; Kumar, R.; Krumpelt, M.

1999-08-24T23:59:59.000Z

84

Economics of Ocean Thermal Energy Conversion (OTEC): Luis A. Vega Ph.D., National Marine Renewable Energy Center at the University of Hawai'i  

E-Print Network [OSTI]

OTC 21016 Economics of Ocean Thermal Energy Conversion (OTEC): An Update Luis A. Vega Ph and we will face a steadily diminishing petroleum supply. This situation justifies re-evaluating OTEC should begin to implement the first generation of OTEC plantships providing electricity, via submarine

85

Ocean thermal energy conversion power system development. Final design report: PSD-I, Phase II  

SciTech Connect (OSTI)

The PSD-I program provides a heat exchanger sytem consisting of an evaporator, condenser and various ancillaries with ammonia used as a working fluid in a closed simulated Rankine cycle. It is to be installed on the Chepachet Research Vessel for test and evaluation of a number of OTEC concepts in a true ocean environment. It is one of several test articles to be tested. Primary design concerns include control of biofouling, corrosion and erosion of aluminum tubes, selection of materials, and the development of a basis for scale-up to large heat exchangers so as to ultimately demonstrate economic feasibility on a commercial scale. The PSD-I test article is devised to verify thermodynamic, environmental, and mechanical performance of basic design concepts. The detailed design, development, fabrication, checklist, delivery, installation support, and operation support for the Test Article Heat Exchangers are described. (WHK)

None

1980-06-30T23:59:59.000Z

86

Produce syngas for methanol  

SciTech Connect (OSTI)

Combined reforming, in which an oxygen reforming reactor is added downstream from a conventional tubular reactor to produce syngas for methanol, achieves a substantial reduction in energy consumption with the least impact on the environment. This paper reports that the advantages of this process scheme are as follows: 8% to 10% reduction in the consumption of natural gas per ton of methanol, The size of the primary reformer is reduced, Reduction of syngas compression requirement due to increased syngas pressure, Reduced steam consumption, Production of syngas with the stoichiometric composition required by methanol synthesis. Synthesis gases for the production of methanol and synfuels are basically mixtures of hydrogen and carbon oxides. They have been produced from natural gas by steam reforming, autothermal reforming and noncatalytic partial oxidation.

Farina, G.L. (Foster Wheeler International Corp., Milan (IT))

1992-03-01T23:59:59.000Z

87

Ocean and Resources Engineering is the application of ocean science and engineering to the challenging conditions  

E-Print Network [OSTI]

engineering, mixing and transport, water quality, ocean thermal energy conversion, hydrogen. GENO PAWLAK

Frandsen, Jannette B.

88

A review of global ocean temperature observations: Implications for ocean heat content estimates and climate change  

E-Print Network [OSTI]

oceans; their extensive total volume and large thermal capacity require a larger injection of energy

2013-01-01T23:59:59.000Z

89

Study of domestic social and economic impacts of ocean thermal energy conversion (OTEC) commercial development. Volume II. Industry profiles  

SciTech Connect (OSTI)

Econoimc profiles of the industries most affected by the construction, deployment, and operation of Ocean Thermal Energy Conversion (OTEC) powerplants are presented. Six industries which will contribute materials and/or components to the construction of OTEC plants have been identified and are profiled here. These industries are: steel industry, concrete industry, titanium metal industry, fabricated structural metals industry, fiber glass-reinforced plastics industry, and electrical transmission cable industry. The economic profiles for these industries detail the industry's history, its financial and economic characteristics, its technological and production traits, resource constraints that might impede its operation, and its relation to OTEC. Some of the historical data collected and described in the profile include output, value of shipments, number of firms, prices, employment, imports and exports, and supply-demand forecasts. For most of the profiled industries, data from 1958 through 1980 were examined. In addition, profiles are included on the sectors of the economy which will actualy construct, deploy, and supply the OTEC platforms.

None

1981-12-22T23:59:59.000Z

90

Conceptual design of an open-cycle ocean thermal energy conversion net power-producing experiment (OC-OTEC NPPE)  

SciTech Connect (OSTI)

This report describes the conceptual design of an experiment to investigate heat and mass transfer and to assess the viability of open-cycle ocean thermal energy conversion (OC-OTEC). The experiment will be developed in two stages, the Heat- and Mass-Transfer Experimental Apparatus (HMTEA) and the Net Power-Producing Experiment (NPPE). The goal for the HMTEA is to test heat exchangers. The goal for the NPPE is to experimentally verify OC-OTEC's feasibility by installing a turbine and testing the power-generating system. The design effort met the goals of both the HMTEA and the NPPE, and duplication of hardware was minimal. The choices made for the design resource water flow rates are consistent with the availability of cold and warm seawater as a result of the seawater systems upgrade carried out by the US Department of Energy (DOE), the state of Hawaii, and the Pacific International Center for High Technology Research. The choices regarding configuration of the system were made based on projected performance, degree of technical risk, schedule, and cost. The cost for the future phase of the design and the development of the HMTEA/NPPE is consistent with the projected future program funding levels. The HMTEA and NPPE were designed cooperatively by PICHTR, Argonne National Laboratory, and Solar Energy Research Institute under the guidance of DOE. The experiment will be located at the DOE's Seacoast Test Facility at the Natural Energy Laboratory of Hawaii, Kailua-Kona, Hawaii. 71 refs., 41 figs., 34 tabs.

Bharathan, D.; Green, H.J.; Link, H.F.; Parsons, B.K.; Parsons, J.M.; Zangrando, F.

1990-07-01T23:59:59.000Z

91

The Methanol Economy Project  

SciTech Connect (OSTI)

The Methanol Economy Project is based on the concept of replacing fossil fuels with methanol generated either from renewable resources or abundant natural (shale) gas. The full methanol cycle was investigated in this project, from production of methanol through bromination of methane, bireforming of methane to syngas, CO{sub 2} capture using supported amines, co-electrolysis of CO{sub 2} and water to formate and syngas, decomposition of formate to CO{sub 2} and H{sub 2}, and use of formic acid in a direct formic acid fuel cell. Each of these projects achieved milestones and provided new insights into their respective fields. ? Direct electrophilic bromination of methane to methyl bromide followed by hydrolysis to yield methanol was investigated on a wide variety of catalyst systems, but hydrolysis proved impractical for large-scale industrial application. ? Bireforming the correct ratio of methane, CO{sub 2}, and water on a NiO / MgO catalyst yielded the right proportion of H{sub 2}:CO (2:1) and proved to be stable for at least 250 hours of operation at 400 psi (28 atm). ? CO{sub 2} capture utilizing supported polyethyleneimines yielded a system capable of adsorbing CO{sub 2} from the air and release at nominal temperatures with negligible amine leaching. ? CO{sub 2} electrolysis to formate and syngas showed considerable increases in rate and selectivity by performing the reaction in a high pressure flow electrolyzer. ? Formic acid was shown to decompose selectively to CO{sub 2} and H{sub 2} using either Ru or Ir based homogeneous catalysts. ? Direct formic acid fuel cells were also investigated and showed higher than 40% voltage efficiency using reduced loadings of precious metals. A technoeconomic analysis was conducted to assess the viability of taking each of these processes to the industrial scale by applying the data gathered during the experiments to approximations based on currently used industrial processes. Several of these processes show significant promise for industrial scale up and use towards improving our nations energy independence.

Olah, George; Prakash, G.K.

2013-12-31T23:59:59.000Z

92

Measurements of gas sorption from seawater and the influence of gas release on open-cycle ocean thermal energy conversion (OC-OTEC) system performance  

SciTech Connect (OSTI)

The technical community has questioned the validity and cost-effectiveness of open-cycle ocean thermal energy conversion (OC-OTEC) systems because of the unknown effect of noncondensable gas on heat exchanger performance and the power needed to run vacuum equipment to remove this gas. To date, studies of seawater gas desorption have not been prototypical for system level analysis. This study gives preliminary gas desorption data on a vertical spout, direct contact evaporator and multiple condenser geometries. Results indicate that dissolved gas can be substantially removed before the seawater enters the heat exchange process, reducing the uncertainty and effect of inert gas on heat exchanger performance.

Penney, T.R.; Althof, J.A.

1985-06-01T23:59:59.000Z

93

Methanol | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to:46 -Energieprojekte GmbH Jump to: navigation,Metalysis Jump to:DecMethanol Jump to:

94

Methanol-reinforced kraft pulping  

SciTech Connect (OSTI)

The addition of methanol to a high-sulfidity kraft cook on Scandinavian softwood chips was studied under different process conditions. Delignification and the degradation of carbohydrates were accelerated, but the effect on delignification was greater. Thus, methanol addition improved selectivity. The positive effect of methanol could also be observed for modified kraft cooks having a leveled out alkali concentration and lower concentration of sodium ions and dissolved lignin at the end of the cook. Methanol addition had no discernible effect on pulp strength or on pulp bleachability.

Norman, E.; Olm, L.; Teder, A. (STFI, Stockholm (Sweden))

1993-03-01T23:59:59.000Z

95

MTBE, methanol prices rise  

SciTech Connect (OSTI)

After several months of drifting lower in line with declining autumn gasoline prices, tabs for methyl tert-butyl ether (MTBE) have turned around. There has been no big demand surge, but consumers and traders are beginning to build up inventories in advance of a series of midwinter shutdowns and turnarounds by producers. Spot prices, which dropped as low as 75 cts/gal, have rebounded to 90 cts/gal fob. Eager for a positive glimmer, methanol producers posted a 3-cts/gal increase in contract prices this month. It marks the first upward idea since February. In that time contract prices have dropped 75% from $1.55/gal to 39 cts/gal. A hard winter has hit early in much of the US sending natural gas prices up sharply. At the same time, formaldehyde and acetic acid markets remain firm, and with MTBE rebounding, methanol producers feel entitled to a piece of the action. {open_quotes}I don`t buy into this claim that MTBE demand is up and I don`t think producers can justify even a 3-cts/gal increase,{close_quotes} says one. {open_quotes}There is nothing in the economy to warrant a run-up. Housing starts are weaker, and demand is down at least 80,000 bbl/day with the MTBE shutdown.{close_quotes}

Morris, G.D.L.; Cornitius, T.

1995-12-20T23:59:59.000Z

96

THE FURNACE COMBUSTION AND RADIATION CHARACTERISTICS OF METHANOL AND A METHANOL/COAL SLURRY  

E-Print Network [OSTI]

Coal The economics of producing methanol and other fuels aresome discussion of producing methanol as a by-product from

Grosshandler, W.L.

2010-01-01T23:59:59.000Z

97

Ocean thermal energy conversion preliminary data report for the November 1977 GOTEC-02 cruise to the Gulf of Mexico Mobile Site  

SciTech Connect (OSTI)

This is the second in a series of preliminary data reports from cruises to potential Ocean Thermal Energy Conversion (OTEC) sites in the Gulf of Mexico. The data are from the GOTEC-02 cruise to a site at approximately 29/sup 0/N, 88/sup 0/W, the Mobile Site. Twelve oceanographic stations were visited. Due to bad weather, the results are scanty. The reader will note that much of the data is questionable. Current meter results are presented elsewhere (Molinari, Hazelworth and Ortman, 1979). Determinations of the biomass indicators - chlorophyll a, phaeophytins and adenosine triphosphate - and zooplankton, are presented. Results were generally those that might have been predicted from previous studies in the area.

Commins, M. L; Duncan, C. P.; Estrella, D. J.; Frisch, J. D.; Horne, A. J.; Jones, K.; Johnson, P. W.; Oldson, J. C.; Quinby-Hunt, M. S.; Ryan, C. J.; Sandusky, J. C.; Tatro, M.; Wilde, P.

1980-03-01T23:59:59.000Z

98

Modeling the Physical and Biochemical Influence of Ocean Thermal Energy Conversion Plant Discharges into their Adjacent Waters  

SciTech Connect (OSTI)

This paper describes the modeling work by Makai Ocean Engineering, Inc. to simulate the biochemical effects of of the nutrient-enhanced seawater plumes that are discharged by one or several 100 megawatt OTEC plants. The modeling is needed to properly design OTEC plants that can operate sustainably with acceptably low biological impact. In order to quantify the effect of discharge configuration and phytoplankton response, Makai Ocean Engineering implemented a biological and physical model for the waters surrounding O`ahu, Hawai`i, using the EPA-approved Environmental Fluid Dynamics Code (EFDC). Each EFDC grid cell was approximately 1 square kilometer by 20 meters deep, and used a time step of three hours. The biological model was set up to simulate the biochemical response for three classes of organisms: Picoplankton (< 2 um) such as prochlorococccus, nanoplankton (2-20 um), and microplankton (> 20 um) e.g., diatoms. The dynamic biological phytoplankton model was calibrated using chemical and biological data collected for the Hawaii Ocean Time Series (HOTS) project. Peer review of the biological modeling was performed. The physical oceanography model uses boundary conditions from a surrounding Hawai'i Regional Ocean Model, (ROM) operated by the University of Hawai`i and the National Atmospheric and Oceanic Administration. The ROM provided tides, basin scale circulation, mesoscale variability, and atmospheric forcing into the edges of the EFDC computational domain. This model is the most accurate and sophisticated Hawai'ian Regional Ocean Model presently available, assimilating real-time oceanographic observations, as well as model calibration based upon temperature, current and salinity data collected during 2010 near the simulated OTEC site. The ROM program manager peer-reviewed Makai's implementation of the ROM output into our EFDC model. The supporting oceanographic data was collected for a Naval Facilities Engineering Command / Makai project. Results: The model was run for a 100 MW OTEC Plant consisting of four separate ducts, discharging a total combined flow rate of 420 m3/s of warm water and 320 m3/s of cold water in a mixed discharge at 70 meters deep. Each duct was assumed to have a discharge port diameter of 10.5m producing a downward discharge velocity of about 2.18 m/s. The natural system, as measured in the HOTS program, has an average concentration of 10-15 mgC/m3. To calibrate the biological model, we first ran the model with no OTEC plant and varied biological parameters until the simulated data was a good match to the HOTS observations. This modeling showed that phytoplankton concentration were patchy and highly dynamic. The patchiness was a good match with the data variability observed within the HOTS data sets. We then ran the model with simulated OTEC intake and discharge flows and associated nutrients. Directly under the OTEC plant, the near-field plume has an average terminal depth of 172 meters, with a volumetric dilution of 13:1. The average terminal plume temperature was 19.8oC. Nitrate concentrations are 1 to 2 umol/kg above ambient. The advecting plume then further dilutes to less than 1 umol/kg above ambient within a few kilometers downstream, while remaining at depth. Because this terminal near-field plume is well below the 1% light limited depths (~120m), no immediate biological utilization of the nutrients occurs. As the nitrate is advected and dispersed downstream, a fraction of the deep ocean nutrients (< 0.5 umol/kg perturbation) mix upward where they are utilized by the ambient phytoplankton population. This occurs approximately twenty-five kilometers downstream from the plant at 110 - 70 meters depth. For pico-phytoplankton, modeling results indicate that this nutrient perturbation causes a phytoplankton perturbation of approximately 1 mgC/m3 (~10% of average ambient concentrations) that covers an area 10x5 km in size at the 70 to 90m depth. Thus, the perturbations are well within the natural variability of the system, generally corresponding to a 10 to 15% increase above the a

PAT GRANDELLI, P.E.; GREG ROCHELEAU; JOHN HAMRICK, Ph.D.; MATT CHURCH, Ph.D.; BRIAN POWELL, Ph.D.

2012-09-29T23:59:59.000Z

99

THE FURNACE COMBUSTION AND RADIATION CHARACTERISTICS OF METHANOL AND A METHANOL/COAL SLURRY  

E-Print Network [OSTI]

Spectral Intensity With 5% Coal (x ::: 86.9 cm) CalculatedPredictions B. Methanol/Coal Slurry as the Fuel TemperatureMethanol as the Fuel B. Methanol/Coal Slurry as the Fuel C.

Grosshandler, W.L.

2010-01-01T23:59:59.000Z

100

Makai Ocean Engineering, Inc. Otec Plume Biochemical Simulation of a 100MW  

E-Print Network [OSTI]

the Physical and Biochemical Influence of Ocean Thermal Energy Conversion Plant Discharges into their Adjacent

Note: This page contains sample records for the topic "methanol ocean thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Rapid starting methanol reactor system  

DOE Patents [OSTI]

The invention relates to a methanol-to-hydrogen cracking reactor for use with a fuel cell vehicular power plant. The system is particularly designed for rapid start-up of the catalytic methanol cracking reactor after an extended shut-down period, i.e., after the vehicular fuel cell power plant has been inoperative overnight. Rapid system start-up is accomplished by a combination of direct and indirect heating of the cracking catalyst. Initially, liquid methanol is burned with a stoichiometric or slightly lean air mixture in the combustion chamber of the reactor assembly. The hot combustion gas travels down a flue gas chamber in heat exchange relationship with the catalytic cracking chamber transferring heat across the catalyst chamber wall to heat the catalyst indirectly. The combustion gas is then diverted back through the catalyst bed to heat the catalyst pellets directly. When the cracking reactor temperature reaches operating temperature, methanol combustion is stopped and a hot gas valve is switched to route the flue gas overboard, with methanol being fed directly to the catalytic cracking reactor. Thereafter, the burner operates on excess hydrogen from the fuel cells.

Chludzinski, Paul J. (38 Berkshire St., Swampscott, MA 01907); Dantowitz, Philip (39 Nancy Ave., Peabody, MA 01960); McElroy, James F. (12 Old Cart Rd., Hamilton, MA 01936)

1984-01-01T23:59:59.000Z

102

Development and Demonstration of a Relocatable Ocean OSSE System: Optimizing Ocean Observations for Hurricane Forecast  

E-Print Network [OSTI]

forecasts for individual storms and improved seasonal forecast of the ocean thermal energy availableDevelopment and Demonstration of a Relocatable Ocean OSSE System: Optimizing Ocean Observations in the Gulf of Mexico is being extended to provide NOAA the ability to evaluate new ocean observing systems

103

Short Communication Three ocean state indices implemented in  

E-Print Network [OSTI]

), the tropical cyclone heat potential, showing the thermal energy available in the ocean to enhance or decreaseShort Communication Three ocean state indices implemented in the Mercator-Ocean operational suite L., and Soulat, F. 2008. Three ocean state indices implemented in the Mercator-Ocean operational suite. ­ ICES

Ribes, Aurélien

104

Air Breathing Direct Methanol Fuel Cell  

DOE Patents [OSTI]

A method for activating a membrane electrode assembly for a direct methanol fuel cell is disclosed. The method comprises operating the fuel cell with humidified hydrogen as the fuel followed by running the fuel cell with methanol as the fuel.

Ren; Xiaoming (Los Alamos, NM)

2003-07-22T23:59:59.000Z

105

Thermal springs list for the United States; National Oceanic and Atmospheric Administration Key to Geophysical Records Documentation No. 12  

SciTech Connect (OSTI)

The compilation has 1702 thermal spring locations in 23 of the 50 States, arranged alphabetically by State (Postal Service abbreviation) and degrees of latitude and longitude within the State. It shows spring name, surface temperature in degrees Fahrenheit and degrees Celsius; USGS Professional Paper 492 number, USGS Circular 790 number, NOAA number, north to south on each degree of latitude and longitude of the listed. USGS 1:250,000-scale (AMS) map; and the USGS topographic map coverage, 1:63360- or 1:62500-scale (15-minute) or 1:24000-scale (7.5-minute) quadrangle also included is an alphabetized list showing only the spring name and the State in which it is located. Unnamed springs are omitted. The list includes natural surface hydrothermal features: springs, pools, mud pots, mud volcanoes, geysers, fumaroles, and steam vents at temperature of 20{sup 0}C (68[sup 0}F) or greater. It does not include wells or mines, except at sites where they supplement or replace natural vents presently or recently active, or, in some places, where orifices are not distinguishable as natural or artificial. The listed springs are located on the USGS 1:250,000 (AMS) topographic maps. (MHR)

Berry, G.W.; Grim, P.J.; Ikelman, J.A. (comps.)

1980-06-01T23:59:59.000Z

106

6, 39453963, 2006 Methanol inside aged  

E-Print Network [OSTI]

. The oxidation of methane (and other hydrocarbons) can also produce methanol primarily via the self reactionACPD 6, 3945­3963, 2006 Methanol inside aged tropical biomass burning plumes G. Dufour et al. Title Chemistry and Physics Discussions First space-borne measurements of methanol inside aged tropical biomass

107

Enhanced methanol utilization in direct methanol fuel cell  

DOE Patents [OSTI]

The fuel utilization of a direct methanol fuel cell is enhanced for improved cell efficiency. Distribution plates at the anode and cathode of the fuel cell are configured to distribute reactants vertically and laterally uniformly over a catalyzed membrane surface of the fuel cell. A conductive sheet between the anode distribution plate and the anodic membrane surface forms a mass transport barrier to the methanol fuel that is large relative to a mass transport barrier for a gaseous hydrogen fuel cell. In a preferred embodiment, the distribution plate is a perforated corrugated sheet. The mass transport barrier may be conveniently increased by increasing the thickness of an anode conductive sheet adjacent the membrane surface of the fuel cell.

Ren, Xiaoming (Los Alamos, NM); Gottesfeld, Shimshon (Los Alamos, NM)

2001-10-02T23:59:59.000Z

108

Direct methanol fuel cell and system  

DOE Patents [OSTI]

A fuel cell having an anode and a cathode and a polymer electrolyte membrane located between anode and cathode gas diffusion backings uses a methanol vapor fuel supply. A permeable polymer electrolyte membrane having a permeability effective to sustain a carbon dioxide flux equivalent to at least 10 mA/cm.sup.2 provides for removal of carbon dioxide produced at the anode by reaction of methanol with water. Another aspect of the present invention includes a superabsorpent polymer material placed in proximity to the anode gas diffusion backing to hold liquid methanol or liquid methanol solution without wetting the anode gas diffusion backing so that methanol vapor from the liquid methanol or liquid methanol-water solution is supplied to the membrane.

Wilson, Mahlon S. (Los Alamos, NM)

2004-10-26T23:59:59.000Z

109

Methanol production method and system  

DOE Patents [OSTI]

Ethanol is selectively produced from the reaction of methanol with carbon monoxide and hydrogen in the presence of a transition metal carbonyl catalyst. Methanol serves as a solvent and may be accompanied by a less volatile co-solvent. The solution includes the transition metal carbonyl catalysts and a basic metal salt such as an alkali metal or alkaline earth metal formate, carbonate or bicarbonate. A gas containing a high carbon monoxide to hydrogen ratio, as is present in a typical gasifer product, is contacted with the solution for the preferential production of ethanol with minimal water as a byproduct. Fractionation of the reaction solution provides substantially pure ethanol product and allows return of the catalysts for reuse.

Chen, Michael J. (Darien, IL); Rathke, Jerome W. (Bolingbrook, IL)

1984-01-01T23:59:59.000Z

110

Method of steam reforming methanol to hydrogen  

DOE Patents [OSTI]

The production of hydrogen by the catalyzed steam reforming of methanol is accomplished using a reformer of greatly reduced size and cost wherein a mixture of water and methanol is superheated to the gaseous state at temperatures of about 800.degree. to about 1,100.degree. F. and then fed to a reformer in direct contact with the catalyst bed contained therein, whereby the heat for the endothermic steam reforming reaction is derived directly from the superheated steam/methanol mixture.

Beshty, Bahjat S. (Lower Makefield, PA)

1990-01-01T23:59:59.000Z

111

DCNS, OTEC roadmap May 2013 DCNSDCNS -Ocean Energy Business Unit  

E-Print Network [OSTI]

© DCNS, OTEC roadmap ­ May 2013 © DCNSDCNS - Ocean Energy Business Unit Emmanuel BROCHARD, VP OTEC positioning for DCNS on Ocean Energy Provider of added-value · On Ocean Thermal Energy Conversion, Floating #12;© DCNS, OTEC roadmap ­ May 2013 4 DNCS invests in 4 ocean energy technologies Keypoints OTEC

112

Flexible ocean upwelling pipe  

DOE Patents [OSTI]

In an ocean thermal energy conversion facility, a cold water riser pipe is releasably supported at its upper end by the hull of the floating facility. The pipe is substantially vertical and has its lower end far below the hull above the ocean floor. The pipe is defined essentially entirely of a material which has a modulus of elasticity substantially less than that of steel, e.g., high density polyethylene, so that the pipe is flexible and compliant to rather than resistant to applied bending moments. The position of the lower end of the pipe relative to the hull is stabilized by a weight suspended below the lower end of the pipe on a flexible line. The pipe, apart from the weight, is positively buoyant. If support of the upper end of the pipe is released, the pipe sinks to the ocean floor, but is not damaged as the length of the line between the pipe and the weight is sufficient to allow the buoyant pipe to come to a stop within the line length after the weight contacts the ocean floor, and thereafter to float submerged above the ocean floor while moored to the ocean floor by the weight. The upper end of the pipe, while supported by the hull, communicates to a sump in the hull in which the water level is maintained below the ambient water level. The sump volume is sufficient to keep the pipe full during heaving of the hull, thereby preventing collapse of the pipe.

Person, Abraham (Los Alamitos, CA)

1980-01-01T23:59:59.000Z

113

BRUCE HOWE Chair and Professor , PhD 1986, UC San Diego. Ocean observatories, ocean acoustic tomography, sensor webs  

E-Print Network [OSTI]

. NIHOUS Associate Professor, PhD 1983, UC Berkeley. Ocean Thermal Energy Conversion (OTEC), marineFaculty BRUCE HOWE Chair and Professor , PhD 1986, UC San Diego. Ocean observatories, ocean in the ocean, atmospheric and ionospheric tomography. KWOK FAI CHEUNG Professor , PhD 1991, British Columbia

Frandsen, Jannette B.

114

Estimation of OTEC Global Resources with an Ocean General Circulation Model  

E-Print Network [OSTI]

Ocean Thermal Energy Conversion (OTEC) relies on the availability of temperature differencesEstimation of OTEC Global Resources with an Ocean General Circulation Model Krishnakumar Rajagopalan Postdoctoral Fellow Department of Ocean and Resources Engineering University of Hawai'i Abstract

Frandsen, Jannette B.

115

Recovery of methanol in an MTBE process  

SciTech Connect (OSTI)

In a process for the manufacture of methyltertiarybutylether (MTBE) in which methanol and a mixture of C/sub 4/ hydrocarbons containing isobutylene are contacted in a reaction zone containing an ion-exchange resin catalyst under suitable conditions to effect the reaction of methanol and isobutylene to produce a reaction product containing MTBE, unreacted methanol, unreacted isobutylene and other C/sub 4/ hydrocarbons, the reaction product is introduced to a fractionation zone wherein it is separated into a bottoms product comprising essentially MTBE and an overhead product containing unreacted methanol, unreacted isobutylene, and other C/sub 4/ hydrocarbons, and the overhead product is introduced to an absorption zone wherein the methanol is absorbed; the improvement is described which comprises utilizing silica gel as adsorbent and regenerating the silica gel adsorbent in a closed loop by contacting the silica gel absorbent with a desorption gas stream at an elevated temperature for a sufficient period of time to remove absorbed methanol, cooling the effluent from the adsorption zone to condense desorbed methanol removing desorbed methanol from the system and recycling the desorption gas to the adsorption zone.

Whisenhunt, D.E.; Byers, G.L.; Hattiangadi, U.S.

1988-05-31T23:59:59.000Z

116

Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel...  

Broader source: Energy.gov (indexed) [DOE]

Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel Cell Applications Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel Cell Applications Presentation...

117

Makai Ocean Engineering, Inc.'s Recent OTEC Activities at NELHA  

E-Print Network [OSTI]

, and operator of an Ocean Thermal Energy Conversion (OTEC) power plant and heat exchanger test facility at NELHA

Frandsen, Jannette B.

118

OCEAN THERMAL ENERGY CONVERSION ECOLOGICAL DATA REPORT FROM 0. S. S. RESEARCHER IN GULF OF MEXICO, JULY 12-23, 1977.  

E-Print Network [OSTI]

Biofouling and Corrosion of OTEC Plants at Selected Sites.the Placement of a Moored OTEC Plant. Atlantic OceanographicThermal Energy Conversion (OTEC) Sites: Puerto Rico, St.

Quinby-Hunt, M.S.

2008-01-01T23:59:59.000Z

119

Methanol synthesis in a trickle bed reactor  

E-Print Network [OSTI]

kinetic models for methanol synthesis under the assumption that the rate limiting step was the reaction between an adsorbed CO molecule and two adsorbed H2 molecules. The experiment was conducted over a Cu/ZnO/Cr~03 catalyst in a fixed bed reactor... to account for the large degree of initial deactivation. However, Rozovskii (1980) claimed the opposite and stated that methanol is made from carbon dioxide and no methanol is produced from Hz/CO mixtures over the Cu/ZnO/Alz03 catalyst. Liu et al. (1984...

Tjandra, Sinoto

1992-01-01T23:59:59.000Z

120

Methanol engine conversion feasibility study: Phase 1  

SciTech Connect (OSTI)

This report documents the selection of the surface-assisted ignition technique to convert two-stroke Diesel-cycle engines to methanol fuel. This study was the first phase of the Florida Department of Transportation methanol bus engine development project. It determined both the feasibility and technical approach for converting Diesel-cycle engines to methanol fuel. State-of-the-art conversion options, associated fuel formulations, and anticipated performance were identified. Economic considerations and technical limitations were examined. The surface-assisted conversion was determined to be feasible and was recommended for hardware development.

Not Available

1983-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "methanol ocean thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Total to withdraw from Qatar methanol - MTBE?  

SciTech Connect (OSTI)

Total is rumored to be withdrawing from the $700-million methanol and methyl tert-butyl ether (MTBE) Qatar Fuel Additives Co., (Qafac) project. The French company has a 12.5% stake in the project. Similar equity is held by three other foreign investors: Canada`s International Octane, Taiwan`s Chinese Petroleum Corp., and Lee Change Yung Chemical Industrial Corp. Total is said to want Qafac to concentrate on methanol only. The project involves plant unit sizes of 610,000 m.t./year of MTBE and 825,000 m.t./year of methanol. Total declines to comment.

NONE

1996-05-01T23:59:59.000Z

122

Final Technical Report Modeling the Physical and Biochemical Influence of Ocean  

E-Print Network [OSTI]

Influence of Ocean Thermal Energy Conversion Plant Discharges into their Adjacent Waters DOE AWARD NO. DE sustainably with acceptably low biological impact. Ocean Thermal Energy Conversion (OTEC) uses large flowsFinal Technical Report Modeling the Physical and Biochemical Influence of Ocean Thermal Energy

123

Comprehensive Ocean Drilling  

E-Print Network [OSTI]

Comprehensive Ocean Drilling Bibliography containing citations related to the Deep Sea Drilling Project, Ocean Drilling Program, Integrated Ocean Drilling Program, and International Ocean Discovery Program Last updated: May 2014 #12;Comprehensive Bibliography Comprehensive Ocean Drilling Bibliography

124

Homogeneous catalyst formulations for methanol production  

DOE Patents [OSTI]

There is disclosed synthesis of CH.sub.3 OH from carbon monoxide and hydrogen using an extremely active homogeneous catalyst for methanol synthesis directly from synthesis gas. The catalyst operates preferably between 100.degree.-150.degree. C. and preferably at 100-150 psia synthesis gas to produce methanol. Use can be made of syngas mixtures which contain considerable quantities of other gases, such as nitrogen, methane or excess hydrogen. The catalyst is composed of two components: (a) a transition metal carbonyl complex and (b) an alkoxide component. In the simplest formulation, component (a) is a complex of nickel tetracarbonyl and component (b) is methoxide (CH.sub.3 O.sup.-), both being dissolved in a methanol solvent system. The presence of a co-solvent such as p-dioxane, THF, polyalcohols, ethers, hydrocarbons, and crown ethers accelerates the methanol synthesis reaction.

Mahajan, Devinder (Port Jefferson, NY); Sapienza, Richard S. (Shoreham, NY); Slegeir, William A. (Hampton Bays, NY); O'Hare, Thomas E. (Huntington Station, NY)

1991-02-12T23:59:59.000Z

125

Homogeneous catalyst formulations for methanol production  

DOE Patents [OSTI]

There is disclosed synthesis of CH.sub.3 OH from carbon monoxide and hydrogen using an extremely active homogeneous catalyst for methanol synthesis directly from synthesis gas. The catalyst operates preferably between 100.degree.-150.degree. C. and preferably at 100-150 psia synthesis gas to produce methanol. Use can be made of syngas mixtures which contain considerable quantities of other gases, such as nitrogen, methane or excess hydrogen. The catalyst is composed of two components: (a) a transition metal carbonyl complex and (b) an alkoxide component. In the simplest formulation, component (a) is a complex of nickel tetracarbonyl and component (b) is methoxide (CH.sub.3 O.sup.13 ), both being dissolved in a methanol solvent system. The presence of a co-solvent such as p-dioxane, THF, polyalcohols, ethers, hydrocarbons, and crown ethers accelerates the methanol synthesis reaction.

Mahajan, Devinder (Port Jefferson, NY); Sapienza, Richard S. (Shoreham, NY); Slegeir, William A. (Hampton Bays, NY); O'Hare, Thomas E. (Huntington Station, NY)

1990-01-01T23:59:59.000Z

126

Methanol-Tolerant Cathode Catalyst Composite For Direct Methanol Fuel Cells  

DOE Patents [OSTI]

A direct methanol fuel cell (DMFC) having a methanol fuel supply, oxidant supply, and its membrane electrode assembly (MEA) formed of an anode electrode and a cathode electrode with a membrane therebetween, a methanol oxidation catalyst adjacent the anode electrode and the membrane, an oxidant reduction catalyst adjacent the cathode electrode and the membrane, comprises an oxidant reduction catalyst layer of a platinum-chromium alloy so that oxidation at the cathode of methanol that crosses from the anode through the membrane to the cathode is reduced with a concomitant increase of net electrical potential at the cathode electrode.

Zhu, Yimin (Los Alamos, NM); Zelenay, Piotr (Los Alamos, NM)

2006-03-21T23:59:59.000Z

127

Methanol-tolerant cathode catalyst composite for direct methanol fuel cells  

DOE Patents [OSTI]

A direct methanol fuel cell (DMFC) having a methanol fuel supply, oxidant supply, and its membrane electrode assembly (MEA) formed of an anode electrode and a cathode electrode with a membrane therebetween, a methanol oxidation catalyst adjacent the anode electrode and the membrane, an oxidant reduction catalyst adjacent the cathode electrode and the membrane, comprises an oxidant reduction catalyst layer of Pt.sub.3Cr/C so that oxidation at the cathode of methanol that crosses from the anode through the membrane to the cathode is reduced with a concomitant increase of net electrical potential at the cathode electrode.

Zhu, Yimin (Los Alamos, NM); Zelenay, Piotr (Los Alamos, NM)

2006-09-05T23:59:59.000Z

128

Vacuum-ultraviolet (VUV) photoionization of small methanol and methanol-water clusters  

SciTech Connect (OSTI)

In this work we report on thevacuum-ultraviolet (VUV) photoionization of small methanol and methanol-water clusters. Clusters of methanol with water are generated via co-expansion of the gas phase constituents in a continuous supersonic jet expansion of methanol and water seeded in Ar. The resulting clusters are investigated by single photon ionization with tunable vacuumultraviolet synchrotron radiation and mass analyzed using reflectron mass spectrometry. Protonated methanol clusters of the form (CH3OH)nH + (n=1-12) dominate the mass spectrum below the ionization energy of the methanol monomer. With an increase in water concentration, small amounts of mixed clusters of the form (CH3OH)n(H2O)H + (n=2-11) are detected. The only unprotonated species observed in this work are the methanol monomer and dimer. Appearance energies are obtained from the photoionization efficiency (PIE) curves for CH3OH +, (CH 3OH)2 +, (CH3OH)nH + (n=1-9), and (CH 3OH)n(H2O)H + (n=2-9 ) as a function of photon energy. With an increase in the water content in the molecular beam, there is an enhancement of photoionization intensity for methanol dimer and protonated methanol monomer at threshold. These results are compared and contrasted to previous experimental observations.

Ahmed, Musahid; Ahmed, Musahid; Wilson, Kevin R.; Belau, Leonid; Kostko, Oleg

2008-05-12T23:59:59.000Z

129

Vacuum-Ultraviolet (VUV) Photoionization of Small Methanol and Methanol-Water Clusters  

SciTech Connect (OSTI)

In this work, we report on the vacuum-ultraviolet (VUV) photoionization of small methanol and methanol-water clusters. Clusters of methanol with water are generated via co-expansion of the gas phase constituents in a continuous supersonic jet expansion of methanol and water seeded in Ar. The resulting clusters are investigated by single photon ionization with tunable vacuum-ultraviolet synchrotron radiation and mass analyzed using reflectron mass spectrometry. Protonated methanol clusters of the form (CH3OH)nH+(n = 1-12) dominate the mass spectrum below the ionization energy of the methanol monomer. With an increase in water concentration, small amounts of mixed clusters of the form (CH3OH n(H2O)H+ (n = 2-11) are detected. The only unprotonated species observed in this work are the methanol monomer and dimer. Appearance energies are obtained from the photoionization efficiency (PIE) curves for CH3OH+, (CH3OH)2+, (CH3OH)nH+ (n = 1-9), and (CH3OH)n(H2O)H+ (n = 2-9) as a function of photon energy. With an increasein the water content in the molecular beam, there is an enhancement of photoionization intensity for the methanol dimer and protonated methanol monomer at threshold. These results are compared and contrasted to previous experimental observations.

Kostko, Oleg; Belau, Leonid; Wilson, Kevin R.; Ahmed, Musahid

2008-04-24T23:59:59.000Z

130

Recycling of wasted energy : thermal to electrical energy conversion  

E-Print Network [OSTI]

solar radiation, and the geothermal energy. [16] Fig. 1.1.thermal energy, geothermal energy, wasted heat from athermal energy, geothermal energy, ocean thermal energy,

Lim, Hyuck

2011-01-01T23:59:59.000Z

131

Technology and economics of gas utilization: Methanol  

SciTech Connect (OSTI)

The paper reviews the current and emerging technology for the conversion of natural gas into methanol and assesses its impact on the production economics. Technologies of potential use for offshore developments of large gas reserves or associated gas are discussed. New technologies for the production of methanol synthesis-gas, such as autothermal reforming and GHR technology, are described and the economic advantages over conventional steam reforming are quantified. New methanol synthesis technology, such as slurry phase reactors, are outlined but appear to offer little advantage over conventional technology for offshore gas utilization. The purification of methanol for fuel and chemical grade product is outlined and the cost of transport presented. The data presented gives an overview of the production costs for production of methanol from large gas reserves (> 1Tcf, 25--35PJ/a) and smaller scale reserves (10--20MMscfd, 4--10PJ/a). The variation of the production cost of methanol with gas price indicates that the gas price is the principal economic consideration. However, adoption of new technology will improve production economics by an amount equivalent to an incremental gas cost of about $0.5/GJ. For gas reserves of low development cost, the adoption of new technology is not a prerequisite to economic viability.

Seddon, D.

1994-12-31T23:59:59.000Z

132

Estimates of Cabbeling in the Global Ocean  

E-Print Network [OSTI]

Owing to the larger thermal expansion coefficient at higher temperatures, more buoyancy is put into the ocean by heating than is removed by cooling at low temperatures. The authors show that, even with globally balanced ...

Schmitt, Raymond W.

133

Ocean Climate Change: Comparison of Acoustic  

E-Print Network [OSTI]

Ocean Climate Change: Comparison of Acoustic Tomography, Satellite Altimetry, and Modeling The ATOC to thermal expansion. Interpreting climate change signals from fluctuations in sea level is therefore in the advective heat flux. Changes in oceanic heat storage are a major expected element of future climate shifts

Frandsen, Jannette B.

134

Electronic Effect in Methanol Dehydrogenation on Pt Surfaces: Potential Control during Methanol Electrooxidation  

E-Print Network [OSTI]

advanced insight into the design of an optimal catalyst as the anode for direct methanol fuel cells. SECTION: Energy Conversion and Storage; Energy and Charge Transport Fuel cells are promising alternative energy conversion. Polymer electrolyte membrane fuel cells (PEMFCs) and direct methanol fuel cells (DMFCs

Park, Byungwoo

135

A sandwich structured membrane for direct methanol fuel cells operating with neat methanol  

E-Print Network [OSTI]

A sandwich structured membrane for direct methanol fuel cells operating with neat methanol Q.X. Wu membrane enables improvements in cell performance. a r t i c l e i n f o Article history: Received 31 October 2012 Received in revised form 4 December 2012 Accepted 3 January 2013 Keywords: Fuel cell Direct

Zhao, Tianshou

136

Preferential oxidation of methanol and carbon monoxide for gas cleanup during methanol fuel processing  

SciTech Connect (OSTI)

Methanol fuel processing generates hydrogen for low-temperature, PEM fuel cell systems now being considered for transportation and other applications. Although liquid methanol fuel is convenient for this application, existing fuel processing techniques generate contaminants that degrade fuel cell performance. Through mathematical models and laboratory experiments chemical processing is described that removes CO and other contaminants from the anode feed stream.

Birdsell, S.A.; Vanderborgh, N.E.; Inbody, M.A. [Los Alamos National Lab., NM (United States)

1993-07-01T23:59:59.000Z

137

The Energetics of Ocean Heat Transport ANAND GNANADESIKAN  

E-Print Network [OSTI]

between mechanical energy supply and thermal energy transport associated with the ocean circulation modeling studies of ocean tide generation and energy conversion (Simmons et al. 2004; Arbic et al. 2004a of recent papers have argued that the mechanical energy budget of the ocean places constraints on how

Vallis, Geoff

138

Transport across 48N in the Atlantic Ocean RICK LUMPKIN  

E-Print Network [OSTI]

. Introduction The partition of energy and freshwater flux between the ocean and the atmosphere and among various decomposition of ocean heat transport into thermal wind, gyre, and Ekman components for a rough estimateTransport across 48°N in the Atlantic Ocean RICK LUMPKIN NOAA/Atlantic Oceanographic

139

Falling MTBE demand bursts the methanol bubble  

SciTech Connect (OSTI)

Methanol spot markets in Europe and the US have been hit hard by weakening demand from methyl tert-butyl ether (MTBE) producers. In Europe, spot prices for domestic T2 product have dropped to DM620-DM630/m.t. fob from early-January prices above DM800/m.t. and US spot prices have slipped to $1.05/gal fob from $1.35/gal. While chemical applications for methanol show sustained demand, sharp methanol hikes during 1994 have priced MTBE out of the gasoline-additive market. {open_quotes}We`ve learned an important lesson. We killed [MTBE] applications in the rest of the world,{close_quotes} says one European methanol producer. Even with methanol currently at DM620/m.t., another manufacturer points out, MTBE production costs still total $300/m.t., $30/m.t. more than MTBE spot prices. Since late 1994, Europe`s 3.3-million m.t./year MTBE production has been cut back 30%.

Wiesmann, G.; Cornitius, T.

1995-03-01T23:59:59.000Z

140

Opportunities for coal to methanol conversion  

SciTech Connect (OSTI)

The accumulations of mining residues in the anthracite coal regions of Pennsylvania offer a unique opportunity to convert the coal content into methanol that could be utilized in that area as an alternative to gasoline or to extend the supplies through blending. Additional demand may develop through the requirements of public utility gas turbines located in that region. The cost to run this refuse through coal preparation plants may result in a clean coal at about $17.00 per ton. After gasification and synthesis in a 5000 ton per day facility, a cost of methanol of approximately $3.84 per million Btu is obtained using utility financing. If the coal is to be brought in by truck or rail from a distance of approximately 60 miles, the cost of methanol would range between $4.64 and $5.50 per million Btu depending upon the mode of transportation. The distribution costs to move the methanol from the synthesis plant to the pump could add, at a minimum, $2.36 per million Btu to the cost. In total, the delivered cost at the pump for methanol produced from coal mining wastes could range between $6.20 and $7.86 per million Btu.

Not Available

1980-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "methanol ocean thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Methanex considers methanol, MTBE in Qatar  

SciTech Connect (OSTI)

CW has learned that Methanex Corp. is considering entering one of two methanol and methyl tert-butyl ether (MTBE) projects in Qatar. Executive v.p. Michael Wilson says that part of the company`s New Zealand plant could be moved to a site in Qatar, which would lower capital costs for the possible project by $75 million-$100 million. Both Qatar General Petroleum Corp. and Qatar Fuel Additives are developing methanol and MTBE projects at Umm Said, Qatar. Methanex says its goal is to ensure low-cost feedstocks.

NONE

1995-12-13T23:59:59.000Z

142

786 IEEE JOURNAL OF OCEANIC ENGINEERING, VOL. 32, NO. 4, OCTOBER 2007 Peer-Reviewed Technical Communication  

E-Print Network [OSTI]

acknowledged as a vast renewable energy source. The energy is stored in oceans partly as thermal energy, partly: wave energy, marine and tidal current energy, ocean thermal energy, energy from salinity gradients have been suggested. Ocean thermal energy conversion is possible in locations with large temperature

Paris-Sud XI, Université de

143

Liquid phase methanol reactor staging process for the production of methanol  

DOE Patents [OSTI]

The present invention is a process for the production of methanol from a syngas feed containing carbon monoxide, carbon dioxide and hydrogen. Basically, the process is the combination of two liquid phase methanol reactors into a staging process, such that each reactor is operated to favor a particular reaction mechanism. In the first reactor, the operation is controlled to favor the hydrogenation of carbon monoxide, and in the second reactor, the operation is controlled so as to favor the hydrogenation of carbon dioxide. This staging process results in substantial increases in methanol yield.

Bonnell, Leo W. (Macungie, PA); Perka, Alan T. (Macungie, PA); Roberts, George W. (Emmaus, PA)

1988-01-01T23:59:59.000Z

144

Prediction of Transport Properties by Molecular Simulation: Methanol and Ethanol and their mixture  

E-Print Network [OSTI]

Transport properties of liquid methanol and ethanol are predicted by molecular dynamics simulation. The molecular models for the alcohols are rigid, non-polarizable and of united-atom type. They were developed in preceding work using experimental vapor-liquid equilibrium data only. Self- and Maxwell-Stefan diffusion coefficients as well as the shear viscosity of methanol, ethanol and their binary mixture are determined using equilibrium molecular dynamics and the Green-Kubo formalism. Non-equilibrium molecular dynamics is used for predicting the thermal conductivity of the two pure substances. The transport properties of the fluids are calculated over a wide temperature range at ambient pressure and compared with experimental and simulation data from the literature. Overall, a very good agreement with the experiment is found. For instance, the self-diffusion coefficient and the shear viscosity are predicted with average deviations of less 8% for the pure alcohols and 12% for the mixture. The predicted thermal...

Guevara-Carrion, Gabriela; Vrabec, Jadran; Hasse, Hans

2009-01-01T23:59:59.000Z

145

Improving Ocean Model Initialization for Coupled Tropical Cyclone Forecast Models Using GODAE Nowcasts  

E-Print Network [OSTI]

in available thermal energy associated with energetic boundary currents and ocean eddies require their accurate temperature (SST) cooling. The potential for the ocean to support intensification depends on the thermal energy available to the storm, which in turn depends on both the temperature and thickness of the upper-ocean

Shay, Lynn K. "Nick"

146

Warm ocean anomaly, air sea fluxes, and the rapid intensification of tropical cyclone Nargis (2008)  

E-Print Network [OSTI]

's coasts great danger. As ocean is the energy source for intensification [Emanuel, 1999; Shay et al., 2000; Lin et al., 2005, 2008; Wu et al., 2007; I.-I. Lin et al., Upper ocean thermal structure to Monthly Weather Review, 2008], in this work we investigate the role of upper ocean thermal structure (UOTS

Texas at Austin. University of

147

Theoretical study of syngas hydrogenation to methanol on the...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

study of syngas hydrogenation to methanol on the polar Zn-terminated ZnO(0001) surface. Theoretical study of syngas hydrogenation to methanol on the polar Zn-terminated ZnO(0001)...

148

Methanol Steam Reformer on a Silicon Wafer  

SciTech Connect (OSTI)

A study of the reforming rates, heat transfer and flow through a methanol reforming catalytic microreactor fabricated on a silicon wafer are presented. Comparison of computed and measured conversion efficiencies are shown to be favorable. Concepts for insulating the reactor while maintaining small overall size and starting operation from ambient temperature are analyzed.

Park, H; Malen, J; Piggott, T; Morse, J; Sopchak, D; Greif, R; Grigoropoulos, C; Havstad, M; Upadhye, R

2004-04-15T23:59:59.000Z

149

THE FURNACE COMBUSTION AND RADIATION CHARACTERISTICS OF METHANOL AND A METHANOL/COAL SLURRY  

E-Print Network [OSTI]

of NO and N02 in a Turbulent Propane/Air Di fusion Flame,"Fuel Methanol Ethanol Ethane Propane i so Octane n - Cetanestage of the secondary Propane, at A spark air line contains

Grosshandler, W.L.

2010-01-01T23:59:59.000Z

150

Methanol production from Eucalyptus wood chips. Final report  

SciTech Connect (OSTI)

This feasibility study includes all phases of methanol production from seedling to delivery of finished methanol. The study examines: production of 55 million, high quality, Eucalyptus seedlings through tissue culture; establishment of a Eucalyptus energy plantation on approximately 70,000 acres; engineering for a 100 million gallon-per-day methanol production facility; potential environmental impacts of the whole project; safety and health aspects of producing and using methanol; and development of site specific cost estimates.

Fishkind, H.H.

1982-06-01T23:59:59.000Z

151

Isothermal vapor-liquid equilibria for methanol + ethanol + water, methanol + water, and ethanol + water  

SciTech Connect (OSTI)

Isothermal vapor-liquid equilibria were measured for the ternary system methanol + ethanol + water and its constituent binary systems of methanol + water and ethanol + water at 323.15, 328.15, and 333.15 K. The apparatus that was used made it possible to control the measured temperature and total pressure by computer. The experimental binary data were correlated by the NRTL equation. The ternary system was predicted using the binary NRTL parameters with good accuracy.

Kurihara, Kiyofumi; Takeda, Kouichi; Kojima, Kazuo [Nihon Univ., Tokyo (Japan). Dept. of Industrial Chemistry; Minoura, Tsuyoshi [Mitui Engineering and Shipbuilding Co., Ltd., Tokyo (Japan)

1995-05-01T23:59:59.000Z

152

Photoelectron imaging of large anionic methanol clusters: ,,n70460...  

E-Print Network [OSTI]

been described elsewhere.9 Methanol cluster anions were produced by passing argon through a reservoirPhotoelectron imaging of large anionic methanol clusters: ,,MeOH...n - ,,n?70­460... Aster Kammrath Electron solvation in methanol anion clusters, MeOH n - n 70­460 , is studied by photoelectron imaging. Two

Neumark, Daniel M.

153

Molecular Dynamics of Methanol Monocation (CH3OH+ ) in Strong  

E-Print Network [OSTI]

ultrafast hydrogen migration.7,8 The 38 fs 800 nm pump pulse produced methanol monocation, and a probe pulseMolecular Dynamics of Methanol Monocation (CH3OH+ ) in Strong Laser Fields Bishnu Thapa and H surfaces of methanol neutral, monocation, and singlet and triplet dication were explored using the CBS

Schlegel, H. Bernhard

154

Hydrogen Production for Fuel Cells Via Reforming Coal-Derived Methanol  

SciTech Connect (OSTI)

Hydrogen can be produced from many feed stocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the fourth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of July 1-Sept 30, 2004 along with a recap of progress from the start of the project on Oct 1, 2003 to Sept 30, 2004. All of the projects are proceeding on or slightly ahead of schedule. This year saw progress in several areas. These areas are: (1) External and internal evaluation of coal based methanol and a fuel cell grade baseline fuel, (2) Design set up and initial testing of three laboratory scale steam reformers, (3) Design, set up and initial testing of a laboratory scale autothermal reactor, (4) Hydrogen generation from coal-derived methanol using steam reformation, (5) Experiments to determine the axial and radial thermal profiles of the steam reformers, (6) Initial catalyst degradation studies with steam reformation and coal based methanol, and (7) Experimental investigations of heat and mass transfer enhancement methods by flow field manipulation. All of the projects are proceeding on or slightly ahead of schedule.

Paul A. Erickson

2004-09-30T23:59:59.000Z

155

Micro Fuel Cells Direct Methanol Fuel Cells  

E-Print Network [OSTI]

energy density of 1.5 Wh/cc; 1.5Wh/g = X5; x10 energy density of Li ion battery * Direct & complete Content (Wh) Volume(cm^3) Li-Ion Battery DMFC #12;Micro Fuel Cells TM State of MTI Micro Fuel Cells Energy Content (Wh) Volume(cm^3) Li-Ion Battery DMFC #12;Direct Methanol Fuel Cell Technology

156

Enzymatic conversion of carbon dioxide to methanol: Enhanced methanol production in silica sol-gel matrices  

SciTech Connect (OSTI)

Strategies for effective conversion of atmospheric CO{sub 2} to methanol offer promising new technologies not only for recycling of the greenhouse gas but also for an efficient production of fuel alternatives. Partial hydrogenation of carbon dioxide has been accomplished by means of heterogeneous catalysis, electrocatalysis, and photocatalysis. Oxide-based catalysts are predominantly used for industrial fixation of carbon dioxide. A unique approach in this direction involves the use of enzymes as catalysts for conversion of carbon dioxide to methanol. The use of enzymes is particularly appealing since it provides a facile low-temperature route for generation of methanol directly from gaseous carbon dioxide. The authors report an enzymatically coupled sequential reduction of carbon dioxide to methanol by using a series of reactions catalyzed by three different dehydrogenases. Overall, the process involves an initial reduction of CO{sub 2} to formate catalyzed by formate dehydrogenase (F{sub ate}DH), followed by reduction of formate to formaldehyde by formaldehyde dehydrogenase (F{sub ald}DH), and finally formaldehyde is reduced to methanol by alcohol dehydrogenase (ADH). In this process, reduced nicotinamide adenine dinucleotide (NADH) acts as a terminal electron donor for each dehydrogenase-catalyzed reduction.

Obert, R.; Dave, B.C.

1999-12-29T23:59:59.000Z

157

Ocean Observing Ocean Observing Systems (OOS)  

E-Print Network [OSTI]

, national, and global scales. · Ocean Observing Systems serve: Fishing industry National security Coastal properties, such as salinity, temperature, and waves Satellite maps of sea surface temperature NATIONAL Integrated Ocean Observing System (IOOS) 11 REGIONAL Systems, including: MANY LOCAL Systems

Schladow, S. Geoffrey

158

Hydrogen Production for Fuel Cells Via Reforming Coal-Derived Methanol  

SciTech Connect (OSTI)

Hydrogen can be produced from many feed stocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the third report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of April 1-June 30, 2004. This quarter saw progress in five areas. These areas are: (1) External evaluation of coal based methanol and the fuel cell grade baseline fuel, (2) Design, set up and initial testing of the autothermal reactor, (3) Experiments to determine the axial and radial thermal profiles of the steam reformers, (4) Catalyst degradation studies, and (5) Experimental investigations of heat and mass transfer enhancement methods by flow field manipulation. All of the projects are proceeding on or slightly ahead of schedule.

Paul A. Erickson

2004-06-30T23:59:59.000Z

159

Improving simulations of the upper ocean by inclusion of surface waves in the MellorYamada turbulence scheme  

E-Print Network [OSTI]

mixing. Surface waves can enhance turbulence kinetic energy and mixing of the upper ocean via wave interaction on the MellorYamada scheme and upper ocean thermal structure are examined and compared with each scheme. The behaviors of the MellorYamada scheme, as well as the simulated upper ocean thermal structure

Ezer,Tal

160

Liquefaction of natural gas to methanol for shipping and storage  

SciTech Connect (OSTI)

The penetration of natural gas into distant markets can be substantially increased by a new methanol synthesis process under development at the Brookhaven National Laboratory. The new methanol process is made possible by the discovery of a catalyst that drops synthesis temperatures from about 275/sup 0/C to about 100/sup 0/C. The new low temperature liquid catalyst can convert synthesis gas completely to methanol in a single pass through the methanol synthesis reactor. This characteristic leads to a further major improvement in the methanol plant. As a result of process design factors made possible by the BNL catalyst, the plant required to convert natural gas to methanol is very simple. Conversion of natural gas to methanol requires two chemical reactions, both of which are exothermic, and thus represent a loss of heating value in the feed natural gas. This loss is about 20% of the feed gas energy, and is, therefore, higher than the 10% loss in energy in natural gas liquefaction, which is a simpler physical - not a chemical - change. The energy disadvantage of the methanol option must be balanced against the advantage of a much lower capital investment requirement made possible by the new BNL synthesis. Preliminary estimates show that methanol conversion and shipping require an investment for liquefaction to methanol, and shipping liquefied methanol that can range from 35 to 50% of the capital needed for the LNG plant and LNG tanker fleet. This large reduction in capital requirements is expected to make liquefaction to methanol attractive in many cases where the LNG capital needs are prohibitive. 3 tabs.

O'Hare, T.E.; Sapienza, R.S.; Mahajan, D.; Skaperdas, G.T.

1986-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "methanol ocean thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

GEOPHYSICAL RESEARCH LETTERS, VOL. 0, NO. 0, PAGES 0-0, M 0, 2001 On the Pacific Ocean regime shift  

E-Print Network [OSTI]

GEOPHYSICAL RESEARCH LETTERS, VOL. 0, NO. 0, PAGES 0-0, M 0, 2001 On the Pacific Ocean regime shift variability of Pacific Ocean upper ocean heat content is examined for the 1948-1998 period using gridded-wide phenomenon affecting the thermal structure from 60 S to 70 N. EOF analysis of the Pacific Ocean heat content

162

List of Methanol Incentives | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth's Heat JumpInc Place:KeystoneSolarList of GeothermalMethanol Incentives Jump to:

163

(Non) formation of methanol by direct hydrogenation of formate...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

produces significant quantities of methanol, although decomposition of formate to carbon dioxide and hydrogen remains the dominant reaction pathway. Simultaneous production...

164

Methanol production from eucalyptus wood chips. Attachment IV. Health and safety aspects of the eucalypt biomass to methanol energy system  

SciTech Connect (OSTI)

The basic eucalyptus-to-methanol energy process is described and possible health and safety risks are identified at all steps of the process. The toxicology and treatment for exposure to these substances are described and mitigating measures are proposed. The health and safety impacts and risks of the wood gasification/methanol synthesis system are compared to those of the coal liquefaction and conversion system. The scope of this report includes the health and safety risks of workers (1) in the laboratory and greenhouse, where eucalyptus seedlings are developed, (2) at the biomass plantation, where these seedlings are planted and mature trees harvested, (3) transporting these logs and chips to the refinery, (4) in the hammermill, where the logs and chips will be reduced to small particles, (5) in the methanol synthesis plant, where the wood particles will be converted to methanol, and (6) transporting and dispensing the methanol. Finally, the health and safety risks of consumers using methanol is discussed.

Fishkind, H.H.

1982-06-01T23:59:59.000Z

165

Proton exchange membrane materials for the advancement of direct methanol fuel-cell technology  

DOE Patents [OSTI]

A new class of hybrid organic-inorganic materials, and methods of synthesis, that can be used as a proton exchange membrane in a direct methanol fuel cell. In contrast with Nafion.RTM. PEM materials, which have random sulfonation, the new class of materials have ordered sulfonation achieved through self-assembly of alternating polyimide segments of different molecular weights comprising, for example, highly sulfonated hydrophilic PDA-DASA polyimide segment alternating with an unsulfonated hydrophobic 6FDA-DAS polyimide segment. An inorganic phase, e.g., 0.5 5 wt % TEOS, can be incorporated in the sulfonated polyimide copolymer to further improve its properties. The new materials exhibit reduced swelling when exposed to water, increased thermal stability, and decreased O.sub.2 and H.sub.2 gas permeability, while retaining proton conductivities similar to Nafion.RTM.. These improved properties may allow direct methanol fuel cells to operate at higher temperatures and with higher efficiencies due to reduced methanol crossover.

Cornelius, Christopher J. (Albuquerque, NM)

2006-04-04T23:59:59.000Z

166

Communication China's growing methanol economy and its implications for energy  

E-Print Network [OSTI]

but scarce oil and natural gas. Adapting to such limitations, it has developed a chemical industry, with the rest coming from natural gas (Peng, 2011). Methanol is commonly used to produce formaldehyde, methylCommunication China's growing methanol economy and its implications for energy and the environment

Jackson, Robert B.

167

Adsorption of intact methanol on Ru,,0001... Pawel Gazdzicki,1  

E-Print Network [OSTI]

in applications such as the direct methanol fuel cell, where Ru/Pt alloys are used as catalysts for dehydration and hydrogen/ deuterium as suggested in the literature is therefore discarded. At very low coverages or by annealing a low coverage methanol layer, hydrogen bonding leads to cluster formation, as evidenced

168

OCEAN THERMAL ENERGY CONVERSION PROGRAMMATIC ENVIRONMENTAL ASSESSMENT  

E-Print Network [OSTI]

l l,eve l Ventil.u:ion ( el OTEC H . . ard Level (f) Type ofW.E. and R.N. Manley, 1979. OTEC Commercialization Analysis.Assessment for Operational OTEC Platforms A Progress Report.

Sands, M.Dale

2013-01-01T23:59:59.000Z

169

Ocean Thermal Energy Conversion Mostly about USA  

E-Print Network [OSTI]

-OTEC Experimental Plant · Designs/ Lessons Learned/ EIA · Economics/Updated Resource Data · Revival (New Century) 2 offshore end 4th Attempt: CWP working some thermodynamic data obtained 5luisvega@hawaii.edu #12;#12;#12;Claude's Off Rio de Janeiro (1933) · Floating Ice Plant: 2.2 MW OC- OTEC to produce 2000 tonnes of Ice

170

Mechanistic Studies of Methanol Synthesis over Cu from CO/CO2...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Methanol Synthesis over Cu from COCO2H2H2O Mixtures: the Source of C in Methanol and the Role of Water Mechanistic Studies of Methanol Synthesis over Cu from COCO2H2H2O...

171

Low temperature catalyst system for methanol production  

DOE Patents [OSTI]

This patent discloses a catalyst and process useful at low temperatures (150/sup 0/C) and preferably in the range 80 to 120/sup 0/C used in the production of methanol from carbon monoxide and hydrogen. The catalyst components are used in slurry form and comprise (1) a complex reducing agent derived from the component structure NaH-ROH-M(OAc)/sub 2/ where M is selected from the group consisting of Ni, Pd, and Co and R is a lower alkyl group containing 1 to 6 carbon atoms and (2) a metal carbonyl of a group VI (Mo, Cr, W) metal. For the first component, Nic is preferred (where M = Ni and R = tertiary amyl). For the second component, Mo(CO)/sub 6/ is preferred. The mixture is subjected to a conditioning or activating step under temperature and pressure, similar to the parameters given above, to afford the active catalyst.

Sapienza, R.S.; Slegeir, W.A.; O'Hare, T.E.

1984-04-20T23:59:59.000Z

172

Low temperature catalysts for methanol production  

DOE Patents [OSTI]

A catalyst and process useful at low temperatures (below about 160 C) and preferably in the range 80--120 C used in the production of methanol from carbon monoxide and hydrogen are disclosed. The catalyst is used in slurry form and comprises a complex reducing agent derived from the component structure NaH--RONa-M(OAc)[sub 2] where M is selected from the group consisting of Ni, Pd, and Co and R is a lower alkyl group containing 1--6 carbon atoms. This catalyst is preferably used alone but is also effective in combination with a metal carbonyl of a group VI (Mo, Cr, W) metal. The preferred catalyst precursor is Nic (where M = Ni and R = tertiary amyl). Mo(CO)[sub 6] is the preferred metal carbonyl if such component is used. The catalyst is subjected to a conditioning or activating step under temperature and pressure, similar to the parameters given above, to afford the active catalyst.

Sapienza, R.S.; Slegeir, W.A.; O'Hare, T.E.; Mahajan, D.

1986-09-30T23:59:59.000Z

173

Methanol adsorption and decomposition on rhodium  

SciTech Connect (OSTI)

The decomposition of methanol on rhodium probed from {approximately}200 atomic sites of the (001) or (111) planes or Rh field emitter crystals but randomly with regard to crystallographic zones was studied by pulsed field desorption mass spectrometry. High electric field pulses were used to quantitatively desorb the final products, carbon monoxide and hydrogen, thus achieving steady-state conditions. Substantial amounts of methoxy (mainly desorbed as CH{sub 3}{sup +} ions) were also present at the surface. Applying a steady electric field, F{sub R} {ge} 4 V/nm, between the field pulses, led to a deceleration of the decomposition reaction and to increase of the amount of adsorbed CH{sub 3}O and CH{sub 2}O species. There were indicators that the rate-determining step of the reaction is C-H bond cleavage in adsorbed methoxy to form the CH{sub 2}O intermediate. This was supported by the observation of a kinetic isotope effect in the formation of CD{sub 2}O and CHDO from methyl-d{sub 2}-alcohol, CHD{sub 2}OH. Here, the C-H bond breaking to form the CD{sub 2}O was found to be twice as fast as the breaking of the C-D bond which results in CHDO. Field ion microscopy was applied to investigate the influence of the reaction on the structure of the whole hemispherical single crystal surface. There were neither topographic changes nor corrosion of the Rh surface after field-free exposure to 2 Pa methanol at temperatures up to 423 K.

Chuah, G.K.; Kruse, N.; Schmidt, W.A.; Block, J.H.; Abend, G. (Fritz-Haber-Institut der Max-Planck-Gesellschaft, Berlin (Germany, F.R.))

1989-10-01T23:59:59.000Z

174

Methanol synthesis using a catalyst combination of alkali or alkaline earth salts and reduced copper chromite for methanol synthesis  

DOE Patents [OSTI]

The present invention relates to a novel route for the synthesis of methanol, and more specifically to the production of methanol by contacting synthesis gas under relatively mild conditions in a slurry phase with a catalyst combination comprising reduced copper chromite and basic alkali salts or alkaline earth salts. The present invention allows the synthesis of methanol to occur in the temperature range of approximately 100.degree.-160.degree. C. and the pressure range of 40-65 atm. The process produces methanol with up to 90% syngas conversion per pass and up to 95% methanol selectivity. The only major by-product is a small amount of easily separated methyl formate. Very small amounts of water, carbon dioxide and dimethyl ether are also produced. The present catalyst combination also is capable of tolerating fluctuations in the H.sub.2 /CO ratio without major deleterious effect on the reaction rate. Furthermore, carbon dioxide and water are also tolerated without substantial catalyst deactivation.

Tierney, John W. (Pittsburgh, PA); Wender, Irving (Pittsburgh, PA); Palekar, Vishwesh M. (Pittsburgh, PA)

1993-01-01T23:59:59.000Z

175

Methanol production from Eucalyptus wood chips. Working Document 9. Economics of producing methanol from Eucalyptus in Central Florida  

SciTech Connect (OSTI)

A detailed feasibility study of producing methanol from Eucalyptus in Central Florida encompasses all phases of production - from seedling to delivery of finished methanol. The project includes the following components: (1) production of 55 million, high quality, Eucalyptus seedlings through tissue culture; (2) establishment of a Eucalyptus energy plantation on approximately 70,000 acres; and (3) engineering for a 100 million gallon-per-year methanol production facility. In addition, the potential environmental impacts of the whole project were examined, safety and health aspects of producing and using methanol were analyzed, and site specific cost estimates were made. The economics of the project are presented here. Each of the three major components of the project - tissue culture lab, energy plantation, and methanol refinery - are examined individually. In each case a site specific analysis of the potential return on investment was conducted.

Fishkind, H.H.

1982-06-01T23:59:59.000Z

176

Method of converting environmentally pollutant waste gases to methanol  

SciTech Connect (OSTI)

A continuous flow method is described of converting environmentally pollutant by-product gases emitted during the manufacture of silicon carbide to methanol comprising: (a) operating a plurality of batch furnaces of a silicon carbide manufacturing plant thereby producing silicon carbide and emitting by-product gases during the operation of the furnaces; (b) staggering the operation of the batch furnaces to achieve a continuous emission of the by-product gases; (c) continuously flowing the by-product gases as emitted from the batch furnaces directly to a methanol manufacturing plant; (d) cleansing the by-product gases of particulate matter, including removing the element sulfur from the by-product gases, as they are flowed to the methanol manufacturing plant, sufficiently for use of the by-product gases in producing methanol; and (e) immediately producing methanol from the by-product gases at the methanol manufacturing plant whereby the producing of silicon carbide is joined with the producing of methanol as a unified process.

Pfingstl, H.; Martyniuk, W.; Hennepin, A. Ill; McNally, T.; Myers, R.; Eberle, L.

1993-08-03T23:59:59.000Z

177

The production of methanol by the Brookhaven National Laboratory process  

SciTech Connect (OSTI)

The purpose of this study was to develop a capital cost estimate and methanol production costs for a new methanol process under development at the Brookhaven National Laboratory (BNL). The cost of fuel delivered to the US Gulf Coast is compared with fuel produced by a conventional methanol process and a liquefied natural gas (LNG) process. The new methanol process is made possible by the development of a new liquid phase catalyst. The new liquid catalyst system can convert synthesis gas almost completely to methanol in a SINGLE pass through the methanol synthesis reactor. This catalyst system reduces synthesis reaction temperatures from about 260{degree}C to about 100{degree}C, permitting isothermal synthesis conditions, in contrast to the temperature gradients in currently available pelleted, solid catalysts. Natural gas feedstock can be processed at pressures under 250 psia. Since nitrogen in the synthesis gas can be tolerated, the autothermal reforming step (combination of partial oxidation and steam reforming over a nickel catalyst) uses preheated air rather than oxygen. However, even with nitrogen present, the volume of gas fed to the reactor can still be smaller than the volume of gas that must be circulated in a conventional reactor, which operates with low conversions and requires high recycle volumes. The characteristics of the BNL system permits a major improvement in methanol plant design and economics. 11 figs., 15 tabs.

Miller, D.B.; Williams, J.J.; Johnson, A.R.

1990-11-01T23:59:59.000Z

178

Ocean Engineering Development Team  

E-Print Network [OSTI]

Ocean Engineering Hydrofoil Development Team Justin Eickmeier Mirela Dalanaj Jason Gray Matt test bed for future hydrofoil designs. 5) To create future student interest in the Ocean Engineering Efficiency and Acceleration. #12;Design Team Justin Eickmeier Team Leader Major: Ocean Engineering, Junior

Wood, Stephen L.

179

Novel Materials for High Efficiency Direct Methanol Fuel Cells  

SciTech Connect (OSTI)

Direct methanol fuel cell membranes were developed using blends of different polyelectrolytes with PVDF. The membranes showed complex relationships between polyelectrolyte chemistry, morphology, and processing. Although the PVDF grade was found to have little effect on the membrane permselectivity, it does impact membrane conductivity and methanol permeation values. Other factors, such as varying the polyelectrolyte polarity, using varying crosslinking agents, and adjusting the equivalent weight of the membranes impacted methanol permeation, permselectivity, and areal resistance. We now understand, within the scope of the project work completed, how these inter-related performance properties can be tailored to achieve a balance of performance.

Carson, Stephen; Mountz, David; He, Wensheng; Zhang, Tao

2013-12-31T23:59:59.000Z

180

Arctic ocean long-term acoustic monitoring : ambient noise, environmental correlates, and transients north of Barrow, Alaska  

E-Print Network [OSTI]

Ocean namely the thickness and concentration of perennial ice coverage is crucial in allowing the water column to retain thermal energy

Roth, Ethan H.

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "methanol ocean thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Improving simulations of the upper-ocean by inclusion of4 surface waves in the Mellor-Yamada turbulence scheme5  

E-Print Network [OSTI]

kinetic energy and mixing of the upper ocean33 via wave breaking and non-breaking wave35 upper-ocean thermal structure are examined and compared with each other using36 one. The behaviors of the Mellor-Yamada39 scheme, as well as the simulated upper-ocean thermal structure

Ezer,Tal

182

Low temperature catalysts for methanol production  

DOE Patents [OSTI]

A catalyst and process useful at low temperatures (below about 160.degree. C.) and preferably in the range 80.degree.-120.degree. C. used in the production of methanol from carbon monoxide and hydrogen is disclosed. The catalyst is used in slurry form and comprises a complex reducing agent derived from the component structure NaH--RONa--M(OAc).sub.2 where M is selected from the group consisting of Ni, Pd, and Co and R is a lower alkyl group containing 1-6 carbon atoms. This catalyst is preferably used alone but is also effective in combination with a metal carbonyl of a group VI (Mo, Cr, W) metal. The preferred catalyst precursor is Nic (where M=Ni and R=tertiary amyl). Mo(CO).sub.6 is the preferred metal carbonyl if such component is used. The catalyst is subjected to a conditioning or activating step under temperature and pressure, similar to the parameters given above, to afford the active catalyst.

Sapienza, Richard S. (1 Miller Ave., Shoreham, NY 11786); Slegeir, William A. (7 Florence Rd., Hampton Bays, NY 11946); O'Hare, Thomas E. (11 Geiger Pl., Huntington Station, NY 11746); Mahajan, Devinder (14 Locust Ct., Selden, NY 11784)

1986-01-01T23:59:59.000Z

183

Low temperature catalysts for methanol production  

DOE Patents [OSTI]

A catalyst and process useful at low temperatures (below about 160/sup 0/C) and preferably in the range 80 to 120/sup 0/C used in the production of methanol from carbon monoxide and hydrogen is disclosed. The catalyst is used in slurry form and comprises a complex reducing agent derived from the component structure NaH-RONa-M(OAc)/sub 2/ where M is selected from the group consisting of Ni, Pd, and Co and R is a lower alkyl group containing 1 to 6 carbon atoms. This catalyst is preferably used alone but is also effective in combination with a metal carbonyl of a group VI (Mo, Cr, W) metal. The preferred catalyst precursor is Nic (where M = Ni and R = tertiary amyl). Mo(CO)/sub 6/ is the preferred metal carbonyl if such component is used. The catalyst is subjected to a conditioning or activating step under temperature and pressure, similar to the parameters given above, to afford the active catalyst.

Sapienza, R.S.; Slegeir, W.A.; O'Hare, T.E.; Mahajan, D.

1985-03-12T23:59:59.000Z

184

Low temperature catalysts for methanol production  

DOE Patents [OSTI]

A catalyst and process useful at low temperatures (below about 160 C) and preferably in the range 80--120 C used in the production of methanol from carbon monoxide and hydrogen are disclosed. The catalyst is used in slurry form and comprises a complex reducing agent derived from the component structure NaH--RONa-M(OAc)[sub 2] where M is selected from the group consisting of Ni, Pd, and Co and R is a lower alkyl group containing 1-6 carbon atoms. This catalyst is preferably used alone but is also effective in combination with a metal carbonyl of a group VI (Mo, Cr, W) metal. The preferred catalyst precursor is NiC (where M = Ni and R = tertiary amyl). Mo(CO)[sub 6] is the preferred metal carbonyl if such component is used. The catalyst is subjected to a conditioning or activating step under temperature and pressure, similar to the parameters given above, to afford the active catalyst.

Sapienza, R.S.; Slegeir, W.A.; O'Hare, T.E.; Mahajan, D.

1986-10-28T23:59:59.000Z

185

From CO2 to Methanol via Novel Nanocatalysts  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Here, Graciani et al. report on a new nanocatalyst that can do just that for CO2- in producing methanol, a key industrial chemical commonly used to make other chemicals and...

186

Coadsorption of methanol and isobutene on HY zeolite  

SciTech Connect (OSTI)

In order to develop a better understanding of methyl tert-butyl ether (MTBE) synthesis on zeolites, the coadsorption of methanol and isobutene on HY zeolite was investigated using IR spectroscopy. Initial adsorption of isobutene alone at 35{degree}C led to rapid oligomerization yielding strongly bound oligomers. The subsequent coadsorption of methanol did not induce any changes in the zeolite-adsorbate complexes. TPD following the coadsorption showed that the Bronsted acid sites could be restored by temperature treatment above approximately 300{degree}C. When methanol was adsorbed first and isobutene was subsequently coadsorbed, MTBE was formed even at 35{degree}C on the catalyst surface. MTBE desorbed easily at a temperature of 70{degree}C, restoring a major fraction of the Bronsted acid sites. Methanol was concluded to decrease the probability of oligomerization by effectively competing for the acid sites. 34 refs., 6 figs.

Kogelbauer, A.; Goodwin, J.G. Jr. [Univ. of Pittsburgh, PA (United States); Lercher, J.A. [Univ. of Twente, Enschede (Netherlands)

1995-05-25T23:59:59.000Z

187

Mechanistic Studies of Methanol Oxidation to Formaldehyde on Isolated Vanadate Sites Supported on MCM-48  

E-Print Network [OSTI]

. Methanol reacts reversibly, at a ratio of approximately 1 methanol per V, with one V-O-Si to produce both V-state reaction conditions, CH2O is produced as the dominant product of methanol oxidation at temperatures belowMechanistic Studies of Methanol Oxidation to Formaldehyde on Isolated Vanadate Sites Supported

Bell, Alexis T.

188

Design of Extraction Column Methanol Recovery System for the TAME Reactive Distillation Process  

E-Print Network [OSTI]

, methanol recovery 1. Introduction A process of producing TAME via reactive distillation has been presented the bulk of the reaction between C5 and methanol to produce TAME and a reactive distillation. MethanolDesign of Extraction Column Methanol Recovery System for the TAME Reactive Distillation Process

Al-Arfaj, Muhammad A.

189

Structural dynamics of hydrogen bonded methanol oligomers: Vibrational transient hole burning studies of spectral diffusion  

E-Print Network [OSTI]

-d in a solution containing 0.8% methanol-d/23% methanol-h in carbon tetrachloride. Methanol-d molecules that both-d in an isotopically mixed solu- tion of methanol dissolved in carbon tetrachloride.11­13 The first step involved

Fayer, Michael D.

190

Evaluation of reformed methanol as an automotive engine fuel  

E-Print Network [OSTI]

EVALUATION OF REFORMED METHANOL AS AN AUTOMOTIVE ENGINE FUEL A Thesis by DAVID MICHAEL MCCALL Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE December... 1903 Major Subject: Mechanical Engineering EVALUATION OF REFORMED METHANOL AS AN AUTOMOTIVE ENGINE FUEL A Thesis by DAVID MICHAEL MCCALL Approved as to style and content by: Dr. T. R. Lalk (Chairman o f Committee ) Dr. R. R. Davison (Member...

McCall, David M

1983-01-01T23:59:59.000Z

191

Improved Flow-Field Structures for Direct Methanol Fuel Cells  

SciTech Connect (OSTI)

The direct methanol fuel cell (DMFC) is ideal if high energy-density liquid fuels are required. Liquid fuels have advantages over compressed hydrogen including higher energy density and ease of handling. Although state-of-the-art DMFCs exhibit manageable degradation rates, excessive fuel crossover diminishes system energy and power density. Although use of dilute methanol mitigates crossover, the concomitant lowering of the gross fuel energy density (GFED) demands a complex balance-of-plant (BOP) that includes higher flow rates, external exhaust recirculation, etc. An alternative approach is redesign of the fuel delivery system to accommodate concentrated methanol. NuVant Systems Inc. (NuVant) will maximize the GFED by design and assembly of a DMFC that uses near neat methanol. The approach is to tune the diffusion of highly concentrated methanol (to the anode catalytic layer) to the back-diffusion of water formed at the cathode (i.e. in situ generation of dilute methanol at the anode layer). Crossover will be minimized without compromising the GFED by innovative integration of the anode flow-field and the diffusion layer. The integrated flow-field-diffusion-layers (IFDLs) will widen the current and potential DMFC operating ranges and enable the use of cathodes optimized for hydrogen-air fuel cells.

Gurau, Bogdan

2013-05-31T23:59:59.000Z

192

INTEGRATED OCEAN DRILLING PROGRAM 2011 OCEAN DRILLING CITATION REPORT  

E-Print Network [OSTI]

INTEGRATED OCEAN DRILLING PROGRAM 2011 OCEAN DRILLING CITATION REPORT covering citations related to the Deep Sea Drilling Project, Ocean Drilling Program, and Integrated Ocean Drilling Program from Geo Drilling Program Publication Services September 2011 #12;OVERVIEW OF THE OCEAN DRILLING CITATION DATABASE

193

Influence of upper-ocean stratification on tropical cyclone-induced surface cooling in the Bay of Bengal  

E-Print Network [OSTI]

in oceanic stratification rather than to differences in TC wind energy input. During the postmonsoon season, a deeper thermal stratification combined with a considerable upper-ocean freshening strongly inhibits that TCs primarily draw their energy from evaporation at the ocean surface [Riehl, 1950]. TCs generally

194

Methanol fumigation of a light duty automotive diesel engine  

SciTech Connect (OSTI)

An Oldsmobile 5.7 l V-8 diesel engine was fumigated with methanol in amounts up to 40% of the fuel energy. The primary objectives of this study were to determine the effect of methanol fumigation on fuel efficiency, smoke, nitric oxide emission, and the occurrence of severe knock. An assessment of the biological activity for samples of the raw exhaust particulate and its soluable organic extract was also made using both the Ames Salmonella typhimurium test and the Bacillus subtilis Comptest. Results are presented for a test matrix consisting of twelve steady state operating conditions chosen to reflect over-the-road operation of a diesel engine powered automobile. Generally methanol fumigation was found to decrease NO emission for all conditions, to have a slight effect on smoke opacity, and to have a beneficial effect on fuel efficiency at higher loads. Also at higher loads the methanol was found to induce what was defined as knock limited operation. While the biological activity of the raw particulate was generally found to be lower than that of the soluble organic fraction, the fumigation of methanol appears to enhance this activity in both cases.

Houser, K.R.; Lestz, S.S.; Dukovich, M.; Yasbin, R.E.

1980-01-01T23:59:59.000Z

195

Thermal Fluids  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Thermal Fluids The Thermal Fluids and Heat Transfer program works on thermal hydraulic reactor safety code development and experimental heat transferthermal hydraulics. The...

196

Arnold Schwarzenegger CALIFORNIA OCEAN WAVE  

E-Print Network [OSTI]

Arnold Schwarzenegger Governor CALIFORNIA OCEAN WAVE ENERGY ASSESSMENT Prepared For: California this report as follows: Previsic, Mirko. 2006. California Ocean Wave Energy Assessment. California Energy Systems Integration · Transportation California Ocean Wave Energy Assessment is the final report

197

Ocean General Circulation Models  

SciTech Connect (OSTI)

1. Definition of Subject The purpose of this text is to provide an introduction to aspects of oceanic general circulation models (OGCMs), an important component of Climate System or Earth System Model (ESM). The role of the ocean in ESMs is described in Chapter XX (EDITOR: PLEASE FIND THE COUPLED CLIMATE or EARTH SYSTEM MODELING CHAPTERS). The emerging need for understanding the Earths climate system and especially projecting its future evolution has encouraged scientists to explore the dynamical, physical, and biogeochemical processes in the ocean. Understanding the role of these processes in the climate system is an interesting and challenging scientific subject. For example, a research question how much extra heat or CO2 generated by anthropogenic activities can be stored in the deep ocean is not only scientifically interesting but also important in projecting future climate of the earth. Thus, OGCMs have been developed and applied to investigate the various oceanic processes and their role in the climate system.

Yoon, Jin-Ho; Ma, Po-Lun

2012-09-30T23:59:59.000Z

198

Methanol injection and recovery in a large turboexpander plant. [Canada  

SciTech Connect (OSTI)

Methanol is used to prevent hydrate formation in Petro-Canada's 2000 MMSCFD Empress expander plant. Injection and recovery facilities have operated essentially trouble-free since start-up late in 1979. A portion of the methanol recovery section has been modified to provide removal of the H/sub 2/S and most of the COS from the propane product stream, concurrent with methanol recovery. The Empress straddle plant strips natural gas liquids from pipeline gas leaving Alberta for eastern Canadian and U.S. markets. The original cold oil absorption plant, started up in 1964 and expanded in 1967, recovered over 90% of the propane and virtually all of the heavier components. In 1976, a market for ethane was secured as feedstock for the world-scale ethylene complex under construction in Alberta, and it was decided to replace the cold oil plant with a turboexpander facility. The plant and its operations are described in some detail. 2 refs.

Nelson, K.; Wolfe, L.

1981-01-01T23:59:59.000Z

199

Space Science: Atmosphere Thermal Structure  

E-Print Network [OSTI]

Space Science: Atmosphere Part -2 Thermal Structure Review tropospheres Absorption of Radiation Adiabatic Lapse Rate ~ 9 K/km Slightly smaller than our estimate Pressure ~3000ft under ocean surface thickness (positive up) is the solar zenith angle Fs is the solar energy flux at frequency (when

Johnson, Robert E.

200

Single-cell protein from methanol with Enterobacter aerogenes  

SciTech Connect (OSTI)

An identified Enterobacter aerogenes utilizing methanol as a sole carbon source was studied for the optimization of biomass production and the reduction of its nucleic acid content. Results indicated that the highest yield and conversion were obtained at 0.5% methanol. The addition of seawater as a source of trace elements has an adverse effect. However, the addition of urea as source of nitrogen enhanced the growth of E. aerogenes. Heat shock at 60 degrees C for one minute followed by incubation at 50 degrees C for 2 hours caused 72.6% reduction in the nucleic acid. 12 references.

Gnan, S.O.; Abodreheba, A.O.

1987-02-20T23:59:59.000Z

Note: This page contains sample records for the topic "methanol ocean thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Environmental information volume: Liquid Phase Methanol (LPMEOH{trademark}) project  

SciTech Connect (OSTI)

The purpose of this project is to demonstrate the commercial viability of the Liquid Phase Methanol Process using coal-derived synthesis gas, a mixture of hydrogen and carbon monoxide. This report describes the proposed actions, alternative to the proposed action, the existing environment at the coal gasification plant at Kingsport, Tennessee, environmental impacts, regulatory requirements, offsite fuel testing, and DME addition to methanol production. Appendices include the air permit application, solid waste permits, water permit, existing air permits, agency correspondence, and Eastman and Air Products literature.

NONE

1996-05-01T23:59:59.000Z

202

Constraining oceanic dust deposition using surface ocean dissolved Al  

E-Print Network [OSTI]

Constraining oceanic dust deposition using surface ocean dissolved Al Qin Han,1 J. Keith Moore,1; accepted 7 December 2007; published 12 April 2008. [1] We use measurements of ocean surface dissolved Al (DEAD) model to constrain dust deposition to the oceans. Our Al database contains all available

Zender, Charles

203

A review of global ocean temperature observations: Implications for ocean heat content estimates and climate change  

E-Print Network [OSTI]

and communications, in Ocean Engineering Planning and Designmicropro?ler, Engineering in the Ocean Environment, Ocean engineering diagnostic data will be transmitted. 5. GLOBAL OCEAN

2013-01-01T23:59:59.000Z

204

Methanol Synthesis from CO2 Hydrogenation over a Pd4/In2O3 Model...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Methanol Synthesis from CO2 Hydrogenation over a Pd4In2O3 Model Catalyst: A Combined DFT and Kinetic Study. Methanol Synthesis from CO2 Hydrogenation over a Pd4In2O3 Model...

205

Active Oxygen Vacancy Site for Methanol Synthesis from CO2 Hydrogenati...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxygen Vacancy Site for Methanol Synthesis from CO2 Hydrogenation on In2O3(110): A DFT Study. Active Oxygen Vacancy Site for Methanol Synthesis from CO2 Hydrogenation on...

206

E-Print Network 3.0 - air-breathing direct methanol Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Res. 2005; 29:10411050 Summary: , U.S.A. SUMMARY An 8-cell air-breathing direct methanol fuel cell (DMFC) stack with the active area... of an air-breathing direct methanol fuel...

207

An Investigation of Different Methods of Fabricating Membrane Electrode Assemblies for Methanol Fuel Cells  

E-Print Network [OSTI]

Methanol fuel cells are electrochemical conversion devices that produce electricity from methanol fuel. The current process of fabricating membrane electrode assemblies (MEAs) is tedious and if it is not sufficiently ...

Hall, Kwame (Kwame J.)

2009-01-01T23:59:59.000Z

208

PdZnAl Catalysts for the Reactions of Water-Gas-Shift, Methanol...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

PdZnAl Catalysts for the Reactions of Water-Gas-Shift, Methanol Steam Reforming, and Reverse-Water-Gas-Shift. PdZnAl Catalysts for the Reactions of Water-Gas-Shift, Methanol Steam...

209

Direct Methanol Fuel Cell Experimental and Model Validation Study  

E-Print Network [OSTI]

Direct Methanol Fuel Cell Experimental and Model Validation Study M. Mench, J. Scott, S. Thynell boundary Fuel cell performance Current density distribution measurements Conclusions #12;3 Method, flow rate, species inlet and fuel cell temperature, and humidity. Transparent polycarbonate windows

Wang, Chao-Yang

210

Methanol market slowly tightens as Brazil starts soaking up material  

SciTech Connect (OSTI)

Although the US methanol market's response to mandated oxygen requirements in reformulated gasoline has been disappointing, the European market has surprisingly been tightening in recent weeks and looks set for a price rise in first-quarter 1993. The tightness is being felt mainly in the Mediterranean market, where the Libyan methanol plant is running at only 70% because of problems with gas feedstock supplies. More significantly, the Brazilian government has now given the go-ahead for a yearlong extension on imports of methanol for use as an ethanol replacement in fuel blending. The new authorization sets a monthly import limit of 48,000 m.t. during that period. Libya is an important supplier of methanol to the Brazilian market and has already shipped about 20,000 m.t. since the authorization was given. Another major supplier to Brazil is Russia, from its two giant 750,000-m.t./year plants at Gubakha and Tomsk. The material is shipped from the terminal at Yuzhnyy on the Black Sea, in Ukrainian territory since the collapse of the Soviet Union.

Young, I.

1992-11-25T23:59:59.000Z

211

Romania program targets methanol and Fischer-Tropsch research  

SciTech Connect (OSTI)

Currently, the chemical organic industry, the petrochemical and engine fuels industry in Romania are entirely based on hydrocarbons from oil. To reduce the oil dependence of this sector and to ensure the stipulated growth rate of 8-9%, research and development programs have been set up with a view to the diversification of raw materials. In research on hydrocarbons from alcohol conversion, three process variants are known, i.e. olefins from methanol, gasolines from methanol and a combined gasolines and aromatic hydrocarbons from methanol. The Romanian process of methanol conversion to hydrocarbons is very flexible, with all the variants mentioned being carried out in the same plant by modifying the catalysts. In research on hydrocarbons from synthesis gas a modern process is being developed for gasification of brown coal in a fluidized bed, under pressure, in the presence of oxygen and water vapors. In the field of carbon oxide hydrogenation, studies have been carried out on selective Fischer-Tropsch processes in which the reaction products are high value hydrocarbon fractions.

Not Available

1987-03-01T23:59:59.000Z

212

ATOM-ECONOMICAL PATHWAYS TO METHANOL FUEL CELL FROM BIOMASS  

SciTech Connect (OSTI)

An economical production of alcohol fuels from biomass, a feedstock low in carbon and high in water content, is of interest. At Brookhaven National Laboratory (BNL), a Liquid Phase Low Temperature (LPLT) concept is under development to improve the economics by maximizing the conversion of energy carrier atoms (C,H) into energy liquids (fuel). So far, the LPLT concept has been successfully applied to obtain highly efficient methanol synthesis. This synthesis was achieved with specifically designed soluble catalysts, at temperatures < 150 C. A subsequent study at BNL yielded a water-gas-shift (WGS) catalyst for the production of hydrogen from a feedstock of carbon monoxide and H{sub 2}O at temperatures < 120 C. With these LPLT technologies as a background, this paper extends the discussion of the LPLT concept to include methanol decomposition into 3 moles of H{sub 2} per mole of methanol. The implication of these technologies for the atom-economical pathways to methanol fuel cell from biomass is discussed.

MAHAJAN,D.; WEGRZYN,J.E.

1999-03-01T23:59:59.000Z

213

On direct and indirect methanol fuel cells for transportation applications  

SciTech Connect (OSTI)

Power densities in electrolyte Direct Methanol Fuel Cells have been achieved which are only three times lower than those achieved with similar reformate/air fuel cells. Remaining issues are: improved anode catalyst activity, demonstrated long-term stable performance, and high fuel efficiencies.

Ren, Xiaoming; Wilson, M.S.; Gottesfeld, S.

1995-09-01T23:59:59.000Z

214

A new blending agent and its effects on methanol-gasoline fuels  

SciTech Connect (OSTI)

The major difficulty encountered with the use of methanol-gasoline blends as SI engine fuel is their tendency to phase separation due to the hydrophilic properties of methanol. Phase separation can lead to some utilization problems. Using a blending agent for the methanol-gasoline system is the common approach taken towards solving the phase separation problem. In this study introduces fraction of molasses fuel oil as an effective new blending agent for methanol-gasoline fuel.

Karaosmanoglu, F.; Isigiguer-Erguedenler, A.; Aksoy, H.A.

2000-04-01T23:59:59.000Z

215

Isobaric vapor-liquid equilibria for methanol + ethanol + water and the three constituent binary systems  

SciTech Connect (OSTI)

Vapor-liquid equilibrium data for methanol + ethanol + water and its three constituent binary systems methanol + ethanol, ethanol + water, and methanol + water were measured at 101.3 kPa using a liquid-vapor ebullition-type equilibrium still. The experimental binary data were correlated by the NRTL equation. The ternary system methanol + ethanol + water was predicted by means of the binary NRTL parameters with good accuracy.

Kurihara, Kiyofumi; Nakamichi, Mikiyoshi; Kojima, Kazuo (Nihon Univ., Tokyo (Japan). Dept. of Industrial Chemistry)

1993-07-01T23:59:59.000Z

216

Novel Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts (Presentation)  

SciTech Connect (OSTI)

This presentation is a summary of a Novel Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts.

Dinh, H.; Gennett, T.

2010-06-11T23:59:59.000Z

217

Simple ocean carbon cycle models  

SciTech Connect (OSTI)

Simple ocean carbon cycle models can be used to calculate the rate at which the oceans are likely to absorb CO{sub 2} from the atmosphere. For problems involving steady-state ocean circulation, well calibrated ocean models produce results that are very similar to results obtained using general circulation models. Hence, simple ocean carbon cycle models may be appropriate for use in studies in which the time or expense of running large scale general circulation models would be prohibitive. Simple ocean models have the advantage of being based on a small number of explicit assumptions. The simplicity of these ocean models facilitates the understanding of model results.

Caldeira, K. [Lawrence Livermore National Lab., CA (United States); Hoffert, M.I. [New York Univ., NY (United States). Dept. of Earth System Sciences; Siegenthaler, U. [Bern Univ. (Switzerland). Inst. fuer Physik

1994-02-01T23:59:59.000Z

218

E-Print Network 3.0 - archean ocean analogue Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

results for: archean ocean analogue Page: << < 1 2 3 4 5 > >> 1 Thermal history of the Earth and its petrological expression Claude Herzberg a, Summary: Earth, which may be why...

219

OBSERVING SYSTEM SIMULATION EXPERIMENTS ON THE OAH'U REGIONAL OCEAN MODEL  

E-Print Network [OSTI]

Thermal Energy Conversion (OTEC) site off the south coast of Oah'u as well as the circulation of Mamala analyses of the observing systems were conducted at the outflow plume depth of a potential pilot Ocean

Luther, Douglas S.

220

The Effects Of High Pressure-High Temperature On Some Physical Properties Of Ocean Sediments  

E-Print Network [OSTI]

A series of laboratory experiments was conducted with four ocean sediments, two biogenic oozes and two clays. Permeability and thermal conductivity were directly measured as a function of porosity and the testing program ...

Morin, Roger

1983-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "methanol ocean thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Performance modeling and cell design for high concentration methanol fuel cells  

E-Print Network [OSTI]

) it reduces the fuel efficiency (methanol is reacted without producing electrical current). We canChapter 50 Performance modeling and cell design for high concentration methanol fuel cells C. E The direct methanol fuel cell (DMFC) has become a lead- ing contender to replace the lithium-ion (Li

222

Correlating Catalytic Methanol Oxidation with the Structure and Oxidation State of Size-Selected Pt Nanoparticles  

E-Print Network [OSTI]

of this process is a limiting factor in the performance of direct methanol fuel cells, which produce electricityCorrelating Catalytic Methanol Oxidation with the Structure and Oxidation State of Size-Selected Pt nanoparticles (NPs) prepared by micelle encapsulation and supported on -Al2O3 during the oxidation of methanol

Kik, Pieter

223

Seasonal measurements of acetone and methanol: Abundances and implications for atmospheric budgets  

E-Print Network [OSTI]

, 2002] and photochemical produc- tion from hydrocarbon precursors. Methanol is often the most abundantSeasonal measurements of acetone and methanol: Abundances and implications for atmospheric budgets December 2005; published 21 February 2006. [1] Acetone and methanol have been measured hourly at a rural

Cohen, Ronald C.

224

Catalysis Today 53 (1999) 433441 New insights into methanol synthesis catalysts from X-ray absorption  

E-Print Network [OSTI]

O and Cr2O3 mixtures and produced methanol in low yields from CO­H2 mixtures at high temperatures (593Catalysis Today 53 (1999) 433­441 New insights into methanol synthesis catalysts from X a consistent structural picture of methanol synthesis catalysts. Copper metal is the principal Cu species

Iglesia, Enrique

225

Department of Energy and Mineral Engineering Spring 2012 BP Methanol Separation  

E-Print Network [OSTI]

issues in the well heads. To counteract this problem, methanol is injected into the produced water stream-effective system that would remove methanol from the produced water stream. Objectives Our objective was to reduce the methanol concentration of either one of two produced water samples. Specifically, our goal was to reduce

Demirel, Melik C.

226

Eects of convection instability due to incompatibility between ocean dynamics and surface forcings  

E-Print Network [OSTI]

- bility between a surface temperature climatology and a given ocean model, into which the climatology by thermal and wind forcing only. Initially, the temperature climatology is forcefully assimilated climatology. In areas characterized by sharp oceanic fronts and high convective activity, the OGCM, due

Paris-Sud XI, Université de

227

Direct numerical simulation of an iron rain in the magma ocean  

E-Print Network [OSTI]

investigate the conversion of gravitational energy into viscous heating and the thermal equilibration betweenDirect numerical simulation of an iron rain in the magma ocean H. Ichikawa,1,2 S. Labrosse,1 and K of metal in a magma ocean. The model, using a fully Lagrangian approach called the moving particle semi

Paris-Sud XI, Université de

228

Ocean Heat Transport , Overturning Circulations, and some fine-resolution ASOF dynamics  

E-Print Network [OSTI]

thermal agitation -internal energy of the fluid is typically 10 orders of magnitude greater thanOcean Heat Transport , Overturning Circulations, and some fine-resolution ASOF dynamics P.B. Rhines & S. Häkkinen #12;· Many basic tenets of ocean circulation are being challenged, and they relate

229

Technical and economic feasibility of a Thermal Gradient Utilization Cycle (TGUC) power plant  

E-Print Network [OSTI]

Energy Conversion unit mass mass flow rate life of system Ocean Thermal Energy Conversion power pressure heat flow Rl R4 TGUC TP T2 total primary energy subsidy expressed as BTU input per 1000 BTU output thermal energy subsidy expressed... has grown in energy technologies that use renewable resources such as solar (thermal conversion, ocean thermal energy conversion, photovoltaics, wind and biomass conversion), geothermal and magnetohydrodynamics (MHD) . A new concept that can...

Raiji, Ashok

1980-01-01T23:59:59.000Z

230

Commercial-scale demonstration of the Liquid Phase Methanol (LPMEOH{trademark}) Process. Peroxide formation of dimethyl ether in methanol mixtures  

SciTech Connect (OSTI)

Organic peroxides could form when dimethyl ether in methanol is stored for three to six months at a time. The objective of this work was to determine the level of peroxide formation from dimethyl ether in reagent grade methanol and raw methanol at room temperature under 3 atmospheres (45 psig) of air. Raw methanol is methanol made from syngas by the LPMEOH Process without distillation. Aliphatic ethers tend to react slowly with oxygen from the air to form unstable peroxides. However, there are no reports on peroxide formation from dimethyl ether. After 172 days of testing, dimethyl ether in either reagent methanol or raw methanol at room temperature and under 60--70 psig pressure of air does not form detectable peroxides. Lack of detectable peroxides suggests that dimethyl ether or dimethyl ether and methanol may be stored at ambient conditions. Since the compositions of {approximately} 1.3 mol% or {approximately} 4.5 mol% dimethyl ether in methanol do not form peroxides, these compositions can be considered for diesel fuel or an atmospheric turbine fuel, respectively.

Waller, F.J.

1997-11-01T23:59:59.000Z

231

Methanol production from eucalyptus wood chips. Attachment V. The Florida eucalyptus energy farm: environmental impacts  

SciTech Connect (OSTI)

The overall environmental impact of the eucalyptus to methanol energy system in Florida is assessed. The environmental impacts associated with the following steps of the process are considered: (1) the greenhouse and laboratory; (2) the eucalyptus plantation; (3) transporting the mature logs; (4) the hammermill; and (5) the methanol synthesis plant. Next, the environmental effects of methanol as an undiluted motor fuel, methanol as a gasoline blend, and gasoline as motor fuels are compared. Finally, the environmental effects of the eucalypt gasification/methanol synthesis system are compared to the coal liquefaction and conversion system.

Fishkind, H.H.

1982-06-01T23:59:59.000Z

232

Evaluation and Sensitivity Analysis of an Ocean Model Response to Hurricane Ivan G. R. HALLIWELL JR.,* L. K. SHAY, AND J. K. BREWSTER  

E-Print Network [OSTI]

provides the thermal energy for intensification, errors and biases in the ocean compo- nent of coupled TCEvaluation and Sensitivity Analysis of an Ocean Model Response to Hurricane Ivan G. R. HALLIWELL JR December 2009) ABSTRACT An ocean model response to Hurricane Ivan (2004) over the northwest Caribbean Sea

233

Water and Climate 2. Circulation of ocean and atmosphere; climate  

E-Print Network [OSTI]

to high latitude and part of that thermal energy is FW: latent heat Gill Atmosphere-Ocean Dynamics integrated vertically (annual mean) ERA40 Atlas ECMWF HIGH: ICTZ, monsoon regions, Amazon.... convergent March 2005 from satellite radiometer AMSR-E. Ranges up to 6.5 cm FW in tropics #12;#12;Relative humidity

234

Atmosphere and Ocean: Water (drought topic begins at slide 26)  

E-Print Network [OSTI]

Atmosphere and Ocean: Water (drought topic begins at slide 26) UW Hon220c Energy & Environment in the atmosphere: 50-70% of the greenhouse effect; ½ the flow of thermal energy from laEtude (like SeaXle and its sister city, Bergen Norway. Meehl et al. Geophysical

235

High specific power, direct methanol fuel cell stack  

DOE Patents [OSTI]

The present invention is a fuel cell stack including at least one direct methanol fuel cell. A cathode manifold is used to convey ambient air to each fuel cell, and an anode manifold is used to convey liquid methanol fuel to each fuel cell. Tie-bolt penetrations and tie-bolts are spaced evenly around the perimeter to hold the fuel cell stack together. Each fuel cell uses two graphite-based plates. One plate includes a cathode active area that is defined by serpentine channels connecting the inlet manifold with an integral flow restrictor to the outlet manifold. The other plate includes an anode active area defined by serpentine channels connecting the inlet and outlet of the anode manifold. Located between the two plates is the fuel cell active region.

Ramsey, John C. (Los Alamos, NM); Wilson, Mahlon S. (Los Alamos, NM)

2007-05-08T23:59:59.000Z

236

Ocean energy conversion systems annual research report  

SciTech Connect (OSTI)

Alternative power cycle concepts to the closed-cycle Rankine are evaluated and those that show potential for delivering power in a cost-effective and environmentally acceptable fashion are explored. Concepts are classified according to the ocean energy resource: thermal, waves, currents, and salinity gradient. Research projects have been funded and reported in each of these areas. The lift of seawater entrained in a vertical steam flow can provide potential energy for a conventional hydraulic turbine conversion system. Quantification of the process and assessment of potential costs must be completed to support concept evaluation. Exploratory development is being completed in thermoelectricity and 2-phase nozzles for other thermal concepts. Wave energy concepts are being evaluated by analysis and model testing with present emphasis on pneumatic turbines and wave focussing. Likewise, several conversion approaches to ocean current energy are being evaluated. The use of salinity resources requires further research in membranes or the development of membraneless processes. Using the thermal resource in a Claude cycle process as a power converter is promising, and a program of R and D and subsystem development has been initiated to provide confirmation of the preliminary conclusion.

Not Available

1981-03-01T23:59:59.000Z

237

Vapor-liquid equilibria for methanol + tetraethylene glycol dimethyl ether  

SciTech Connect (OSTI)

Vapor-liquid equilibrium (P-T-x) for the methanol + tetraethylene glycol dimethyl ether binary system were obtained by the static method in the range of temperatures from 293.15 to 423.15 K at 10 K intervals. The modified vapor pressure apparatus used is described. The Kuczynsky method was used to calculate the liquid and vapor composition and the activity coefficients of methanol from the initial composition of the sample and the measured pressure and temperature. The results were correlated by the NRTL and UNIQUAC temperature dependent activity coefficient models. This system shows nearly ideal behavior at 323.15 K, but positive deviations from ideality at lower temperatures and negative deviations at higher temperatures are observed. The activity coefficients become more negative with the increase in temperature and mole fraction of methanol. The excess molar enthalpy using the Gibss-Helmholtz equation and the NRTL and UNIQUAC parameters were calculated at 303.15 K and compared with experimental data. This binary system shows promise as a working pair for high-temperature heat pump applications.

Esteve, X.; Chaudhari, S.K.; Coronas, A. [Univ. Rovira i Virgili, Tarragona (Spain). Dept. of Electrical and Mechanical Engineering

1995-11-01T23:59:59.000Z

238

Massachusetts Ocean Management Plan (Massachusetts)  

Broader source: Energy.gov [DOE]

The Massachusetts Ocean Act of 2008 required the states Secretary of Energy and Environmental Affairs to develop a comprehensive ocean management plan for the state by the end of 2009. That plan...

239

Oxidation of Methanol on 2nd and 3rd Row Group VIII Transition Metals (Pt, Ir, Os, Pd, Rh, and Ru): Application to Direct Methanol  

E-Print Network [OSTI]

to electric energy in a hydrogen/oxygen fuel cell was demon- strated. Although hydrogen/oxygen fuel cells): Application to Direct Methanol Fuel Cells Jeremy Kua and William A. Goddard III* Contribution from and designing new catalysts. We find that methanol dehydrogenation is most facile on Pt, with the hydrogens

Goddard III, William A.

240

Ninth Annual Ocean Renewable Energy Conference  

Broader source: Energy.gov [DOE]

The future of clean, renewable ocean wave energy will be discussed in depth at the 2014 Ocean Renewable Energy Conference.

Note: This page contains sample records for the topic "methanol ocean thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

November 2002 OCEAN DRILLING PROGRAM  

E-Print Network [OSTI]

November 2002 OCEAN DRILLING PROGRAM LEG 208 SCIENTIFIC PROSPECTUS EARLY CENOZOIC EXTREME CLIMATES -------------------------------- Dr. Jack Baldauf Deputy Director of Science Operations Ocean Drilling Program Texas A&M University Leg Project Manager and Staff Scientist Ocean Drilling Program Texas A&M University 1000 Discovery

242

February 2002 OCEAN DRILLING PROGRAM  

E-Print Network [OSTI]

February 2002 OCEAN DRILLING PROGRAM LEG 204 SCIENTIFIC PROSPECTUS DRILLING GAS HYDRATES ON HYDRATE -------------------------------- Dr. Jack Baldauf Deputy Director of Science Operations Ocean Drilling Program Texas A&M University Richter Leg Project Manager and Staff Scientist Ocean Drilling Program Texas A&M University 1000 Discovery

243

December 2001 OCEAN DRILLING PROGRAM  

E-Print Network [OSTI]

December 2001 OCEAN DRILLING PROGRAM LEG 203 SCIENTIFIC PROSPECTUS DRILLING AT THE EQUATORIAL -------------------------------- Dr. Jack Bauldauf Deputy Director of Science Operations Ocean Drilling Program Texas A&M University. Acton Leg Project Manager and Staff Scientist Ocean Drilling Program Texas A&M University 1000 Discovery

244

An Analysis of Methanol and Hydrogen Production via High-Temperature Electrolysis Using the Sodium Cooled Advanced Fast Reactor  

SciTech Connect (OSTI)

Integration of an advanced, sodium-cooled fast spectrum reactor into nuclear hybrid energy system (NHES) architectures is the focus of the present study. A techno-economic evaluation of several conceptual system designs was performed for the integration of a sodium-cooled Advanced Fast Reactor (AFR) with the electric grid in conjunction with wind-generated electricity. Cases in which excess thermal and electrical energy would be reapportioned within an integrated energy system to a chemical plant are presented. The process applications evaluated include hydrogen production via high temperature steam electrolysis and methanol production via steam methane reforming to produce carbon monoxide and hydrogen which feed a methanol synthesis reactor. Three power cycles were considered for integration with the AFR, including subcritical and supercritical Rankine cycles and a modified supercritical carbon dioxide modified Brayton cycle. The thermal efficiencies of all of the modeled power conversions units were greater than 40%. A thermal efficiency of 42% was adopted in economic studies because two of the cycles either performed at that level or could potentially do so (subcritical Rankine and S-CO2 Brayton). Each of the evaluated hybrid architectures would be technically feasible but would demonstrate a different internal rate of return (IRR) as a function of multiple parameters; all evaluated configurations showed a positive IRR. As expected, integration of an AFR with a chemical plant increases the IRR when must-take wind-generated electricity is added to the energy system. Additional dynamic system analyses are recommended to draw detailed conclusions on the feasibility and economic benefits associated with AFR-hybrid energy system operation.

Shannon M. Bragg-Sitton; Richard D. Boardman; Robert S. Cherry; Wesley R. Deason; Michael G. McKellar

2014-03-01T23:59:59.000Z

245

Modelling of partially-resolved oceanic symmetric instability  

E-Print Network [OSTI]

for the energy sources ? Corresponding author. Address: DAMTP, Centre for Mathematical Sciences, Wilberforce Road, Cambridge CB3 0WA, United Kingdom. Tel.: +44 01223 337030. E-mail address: J.R.Taylor@damtp.cam.ac.uk (J.R. Taylor). Ocean Modelling 82 (2014) 15... of the surface ocean at strong fronts. Energetically, SI can be described as a small-scale shear instabil- ity that extracts energy from the vertically-sheared thermal wind (Taylor and Ferrari, 2010; Thomas and Taylor, 2010) and acts as a mediator...

Bachman, S. D.; Taylor, J. R.

2014-08-04T23:59:59.000Z

246

Methanol production with elemental phosphorus byproduct gas: technical and economic feasibility  

SciTech Connect (OSTI)

The technical and economic feasibility of using a typical, elemental, phosphorus byproduct gas stream in methanol production is assessed. The purpose of the study is to explore the potential of a substitute for natural gas. The first part of the study establishes economic tradeoffs between several alternative methods of supplying the hydrogen which is needed in the methanol synthesis process to react with CO from the off gas. The preferred alternative is the Battelle Process, which uses natural gas in combination with the off gas in an economically sized methanol plant. The second part of the study presents a preliminary basic design of a plant to (1) clean and compress the off gas, (2) return recovered phosphorus to the phosphorus plant, and (3) produce methanol by the Battelle Process. Use of elemental phosphorus byproduct gas in methanol production appears to be technically feasible. The Battelle Process shows a definite but relatively small economic advantage over conventional methanol manufacture based on natural gas alone. The process would be economically feasible only where natural gas supply and methanol market conditions at a phosphorus plant are not significantly less favorable than at competing methanol plants. If off-gas streams from two or more phosphorus plants could be combined, production of methanol using only offgas might also be economically feasible. The North American methanol market, however, does not seem likely to require another new methanol project until after 1990. The off-gas cleanup, compression, and phosphorus-recovery system could be used to produce a CO-rich stream that could be economically attractive for production of several other chemicals besides methanol.

Lyke, S.E.; Moore, R.H.

1981-01-01T23:59:59.000Z

247

From CO2 to Methanol via Novel Nanocatalysts  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing ZirconiaPolicyFeasibilityFieldMinds"OfficeTour theFrom CO2 to Methanol via

248

From CO2 to Methanol via Novel Nanocatalysts  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing ZirconiaPolicyFeasibilityFieldMinds"OfficeTour theFrom CO2 to Methanol

249

From CO2 to Methanol via Novel Nanocatalysts  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing ZirconiaPolicyFeasibilityFieldMinds"OfficeTour theFrom CO2 to MethanolFrom

250

From CO2 to Methanol via Novel Nanocatalysts  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-SeriesFlickr Flickr Editor's note: SincePlantFreedomofFrom CO2 to Methanol via

251

From CO2 to Methanol via Novel Nanocatalysts  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-SeriesFlickr Flickr Editor's note: SincePlantFreedomofFrom CO2 to Methanol

252

From CO2 to Methanol via Novel Nanocatalysts  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-SeriesFlickr Flickr Editor's note: SincePlantFreedomofFrom CO2 to MethanolFrom

253

Liquid-liquid equilibrium of cyclohexane-n-hexane-methanol mixtures; Effect of water content  

SciTech Connect (OSTI)

Experimental liquid-liquid equilibrium data for the ternary system cyclohexane-n-hexane-methanol and for the binary systems n-hexane-methanol and cyclohexane-methanol are presented over a temperature range from 284 to 298{Kappa} at pressure of 0.1 MPa. Attention is given to the effect of the purity of methanol as far as the water content is concerned. The data are correlated by means of excess Gibbs energy models (NRTL and UNIQUAC), and the binary interaction parameters are reported.

Alessi, P.; Fermeglia, M.; Kikic, I. (Istituto di Chimica Applicata e Industriale, University of Trieste, via Valerio 2, I-34127 Trieste (IT))

1989-04-01T23:59:59.000Z

254

Indirect conversion of coal to methanol and gasoline: product price vs product slate  

SciTech Connect (OSTI)

The Oak Ridge National Laboratory (ORNL) conducts process analysis and engineering evaluation studies for the Department of Energy to provide, on a consistent basis, technical and economic assessments of processes and systems for coal conversion and utilization. Such assessments permit better understanding of the relative technical and economic potential of these processes. The objective of the work described here was to provide an assessment of the technical feasibility, economic competitiveness, and environmental acceptability of selected indirect coal liquefaction processes on a uniform, consistent, and impartial basis. Particular emphasis is placed on production of methanol as a principal product or methanol production for conversion to gasoline. Potential uses for the methanol are combustion in peaking-type turbines or blending with gasoline to yield motor fuel. Conversion of methanol to gasoline is accomplished through the use of the Mobil methanol-to-gasoline (MTG) process. Under the guidance of ORNL, Fluor Engineers and Constructors, Houston Division, prepared four conceptual process designs for indirect conversion of a Western subbituminous coal to either methanol or gasoline. The conceptual designs are based on the use of consistent technology for the core of the plant (gasification through methanol synthesis) with additional processing as necessary for production of different liquid products of interest. The bases for the conceptual designs are given. The case designations are: methanol production for turbine-grade fuel; methanol production for gasoline blending; gasoline production with coproduction of SNG; and gasoline production maximized.

Wham, R.M.; McCracken, D.J.; Forrester, R.C. III

1980-01-01T23:59:59.000Z

255

Optimizing membrane electrode assembly of direct methanol fuel cells for portable power.  

E-Print Network [OSTI]

??Direct methanol fuel cells (DMFCs) for portable power applications require high power density, high-energy conversion efficiency and compactness. These requirements translate to fundamental properties of (more)

Liu, Fuqiang

2006-01-01T23:59:59.000Z

256

Understanding the effect of modifying elements in supported vanadia bilayered catalysts for methanol oxidation to formaldehyde  

E-Print Network [OSTI]

that methanol initially adsorbs dissociatively producingmethanol dissociatively adsorbs across a V-O- support bond, producingmethanol dissociatively adsorbs across a V-O-Si bond producing

Vining, William Collins

2011-01-01T23:59:59.000Z

257

A self-regulated passive fuel-feed system for passive direct methanol fuel cells.  

E-Print Network [OSTI]

??Unlike active direct methanol fuel cells (DMFCs) that require liquid pumps and gas compressors to supply reactants, the design of passive DMFCs eliminates these ancillary (more)

Chan, Yeuk Him

2007-01-01T23:59:59.000Z

258

E-Print Network 3.0 - acute methanol toxicity Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: that bind to transthyretin, a thyroxine binding protein. 12;Toxicity of Dioxins Acute Toxicity Varies... ) to acetaldehyde to acetate to acetyl CoA Methanol ...

259

STATISTICAL PROPERTIES OF 12.2 GHz METHANOL MASERS ASSOCIATED WITH A COMPLETE SAMPLE OF 6.7 GHz METHANOL MASERS  

SciTech Connect (OSTI)

We present definitive detection statistics for 12.2 GHz methanol masers toward a complete sample of 6.7 GHz methanol masers detected in the Methanol Multibeam survey south of declination -20{sup 0}. In total, we detect 250 12.2 GHz methanol masers toward 580 6.7 GHz methanol masers. This equates to a detection rate of 43.1%, which is lower than that of previous significant searches of comparable sensitivity. Both the velocity ranges and the flux densities of the target 6.7 GHz sources surpass that of their 12.2 GHz companion in almost all cases. Eighty percent of the detected 12.2 GHz methanol maser peaks are coincident in velocity with the 6.7 GHz maser peak. Our data support an evolutionary scenario whereby the 12.2 GHz sources are associated with a somewhat later evolutionary stage than the 6.7 GHz sources devoid of this transition. Furthermore, we find that the 6.7 GHz and 12.2 GHz methanol sources increase in luminosity as they evolve. In addition to this, evidence for an increase in velocity range with evolution is presented. This implies that it is not only the luminosity but also the volume of gas conducive to the different maser transitions that increases as the sources evolve. Comparison with GLIMPSE mid-infrared sources has revealed a coincidence rate between the locations of the 6.7 GHz methanol masers and GLIMPSE point sources similar to that achieved in previous studies. Overall, the properties of the GLIMPSE sources with and without 12.2 GHz counterparts are similar. There is a higher 12.2 GHz detection rate toward those 6.7 GHz methanol masers that are coincident with extended green objects.

Breen, S. L.; Caswell, J. L.; Green, J. A.; Voronkov, M. A. [CSIRO Astronomy and Space Science, P.O. Box 76, Epping, NSW 1710 (Australia); Ellingsen, S. P. [School of Mathematics and Physics, University of Tasmania, Private Bag 37, Hobart, Tasmania 7001 (Australia); Fuller, G. A.; Quinn, L. J.; Avison, A., E-mail: Shari.Breen@csiro.au [Jodrell Bank Centre for Astrophysics, Alan Turing Building, School of Physics and Astronomy, University of Manchester, Manchester M13 9PL (United Kingdom)

2011-06-01T23:59:59.000Z

260

Drilling deep through the ocean crust into the upper mantle Benot Ildefonse (1) and Mission Moho proponents (2)  

E-Print Network [OSTI]

Drilling deep through the ocean crust into the upper mantle Benoît Ildefonse (1) and Mission Moho the inventory of global thermal, chemical and associated biological fluxes. Drilling an ultra-deep hole, and into the uppermost mantle is a long-standing goal of scientific ocean drilling; it remains critical to answer many

Demouchy, Sylvie

Note: This page contains sample records for the topic "methanol ocean thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Desorption Kinetics of Methanol, Ethanol, and Water from Graphene  

SciTech Connect (OSTI)

The desorption kinetics of methanol, ethanol, and water from graphene covered Pt(111) are investigated. The temperature programmed desorption (TPD) spectra for both methanol and ethanol have well-resolved first, second, third, and multilayer layer desorption peaks. The alignment of the leading edges is consistent with zero-order desorption kinetics from all layers. In contrast, for water the first and second layers are not resolved. At low water coverages (< 1 ML) the initial desorption leading edges are aligned but then fall out of alignment at higher temperatures. For thicker water layers (10 to 100 ML), the desorption leading edges are in alignment throughout the desorption of the film. The coverage dependence of the desorption behavoir suggests that at low water coverages the non-alignment of the desorption leading edges is due to water dewetting from the graphene substrate. Kinetic simulations reveal that the experimental results are consistent with zero-order desorption. The simulations also show that fractional order desorption kinetics would be readily apparent in the experimental TPD spectra.

Smith, R. Scott; Matthiesen, Jesper; Kay, Bruce D.

2014-09-18T23:59:59.000Z

262

Ocean dynamics and thermodynamics in the tropical Indo- Pacific region  

E-Print Network [OSTI]

Pacific Oceans . . . . . . . . . . . . . . . . . . . . . . . . . . . . .currents in the tropical Pacific Ocean. J. Phys. Oceanogr. ,in the eastern tropical Pacific Ocean associated with the

Drushka, Kyla

2011-01-01T23:59:59.000Z

263

INTEGRATED OCEAN DRILLING PROGRAM United States Implementing Organization  

E-Print Network [OSTI]

INTEGRATED OCEAN DRILLING PROGRAM United States Implementing Organization Consortium for Ocean: National Science Foundation _______________________________ David L. Divins Director, Ocean Drilling

264

Methanol Fractionation of Softwood Kraft Lignin: Impact on the Lignin Properties  

SciTech Connect (OSTI)

The development of technologies to tune lignin properties for high-performance lignin-based materials is crucial for the utilization of lignin in various applications. Here, the effect of methanol (MeOH) fractionation on the molecular weight, molecular weight distribution, glass transition temperature (Tg), thermal decomposition, and chemical structure of lignin were investigated. Repeated MeOH fractionation of softwood Kraft lignin successfully removed the low-molecular-weight fraction. The separated high-molecular-weight lignin showed a Tg of 211 C and a char yield of 47%, much higher than those of asreceived lignin (Tg 153 C, char yield 41%). The MeOH-soluble fraction of lignin showed an increased low-molecular-weight fraction and a lower Tg (117 C) and char yield (32%). The amount of low-molecular-weight fraction showed a quantitative correlation with both 1/Tg and char yield in a linear regression. This study demonstrated the efficient purification or fractionation technology for lignin; it also established a theoretical and empirical correlation between the physical characteristics of fractionated lignins.

Saito, Tomonori [ORNL] [ORNL; Perkins, Joshua H [ORNL] [ORNL; Vautard, Frederic [ORNL] [ORNL; Meyer III, Harry M [ORNL] [ORNL; Messman, Jamie M [ORNL] [ORNL; Tolnai, Balazs [ORNL] [ORNL; Naskar, Amit K [ORNL] [ORNL

2014-01-01T23:59:59.000Z

265

INTEGRATED OCEAN DRILLING PROGRAM United States Implementing Organization  

E-Print Network [OSTI]

INTEGRATED OCEAN DRILLING PROGRAM United States Implementing Organization Consortium for Ocean. ______________________________ David L. Divins Director, Ocean Drilling Programs Consortium for Ocean Leadership, Inc. Washington, D

266

INTEGRATED OCEAN DRILLING PROGRAM United States Implementing Organization  

E-Print Network [OSTI]

INTEGRATED OCEAN DRILLING PROGRAM United States Implementing Organization Consortium for Ocean. _______________________________ David L. Divins Director, Ocean Drilling Programs Consortium for Ocean Leadership, Inc. Washington, D

267

INTEGRATED OCEAN DRILLING PROGRAM United States Implementing Organization  

E-Print Network [OSTI]

INTEGRATED OCEAN DRILLING PROGRAM United States Implementing Organization Consortium for Ocean _______________________________ David L. Divins Director, Ocean Drilling Programs Consortium for Ocean Leadership, Inc. Washington, D

268

Reformers for the production of hydrogen from methanol and alternative fuels for fuel cell powered vehicles  

SciTech Connect (OSTI)

The objective of this study was (i) to assess the present state of technology of reformers that convert methanol (or other alternative fuels) to a hydrogen-rich gas mixture for use in a fuel cell, and (ii) to identify the R&D needs for developing reformers for transportation applications. Steam reforming and partial oxidation are the two basic types of fuel reforming processes. The former is endothermic while the latter is exothermic. Reformers are therefore typically designed as heat exchange systems, and the variety of designs used includes shell-and-tube, packed bed, annular, plate, and cyclic bed types. Catalysts used include noble metals and oxides of Cu, Zn, Cr, Al, Ni, and La. For transportation applications a reformer must be compact, lightweight, and rugged. It must also be capable of rapid start-up and good dynamic performance responsive to fluctuating loads. A partial oxidation reformer is likely to be better than a steam reformer based on these considerations, although its fuel conversion efficiency is expected to be lower than that of a steam reformer. A steam reformer better lends itself to thermal integration with the fuel cell system; however, the thermal independence of the reformer from the fuel cell stack is likely to yield much better dynamic performance of the reformer and the fuel cell propulsion power system. For both steam reforming and partial oxidation reforming, research is needed to develop compact, fast start-up, and dynamically responsive reformers. For transportation applications, steam reformers are likely to prove best for fuel cell/battery hybrid power systems, and partial oxidation reformers are likely to be the choice for stand-alone fuel cell power systems.

Kumar, R.; Ahmed, S.; Krumpelt, M.; Myles, K.M.

1992-08-01T23:59:59.000Z

269

Reformers for the production of hydrogen from methanol and alternative fuels for fuel cell powered vehicles  

SciTech Connect (OSTI)

The objective of this study was (i) to assess the present state of technology of reformers that convert methanol (or other alternative fuels) to a hydrogen-rich gas mixture for use in a fuel cell, and (ii) to identify the R D needs for developing reformers for transportation applications. Steam reforming and partial oxidation are the two basic types of fuel reforming processes. The former is endothermic while the latter is exothermic. Reformers are therefore typically designed as heat exchange systems, and the variety of designs used includes shell-and-tube, packed bed, annular, plate, and cyclic bed types. Catalysts used include noble metals and oxides of Cu, Zn, Cr, Al, Ni, and La. For transportation applications a reformer must be compact, lightweight, and rugged. It must also be capable of rapid start-up and good dynamic performance responsive to fluctuating loads. A partial oxidation reformer is likely to be better than a steam reformer based on these considerations, although its fuel conversion efficiency is expected to be lower than that of a steam reformer. A steam reformer better lends itself to thermal integration with the fuel cell system; however, the thermal independence of the reformer from the fuel cell stack is likely to yield much better dynamic performance of the reformer and the fuel cell propulsion power system. For both steam reforming and partial oxidation reforming, research is needed to develop compact, fast start-up, and dynamically responsive reformers. For transportation applications, steam reformers are likely to prove best for fuel cell/battery hybrid power systems, and partial oxidation reformers are likely to be the choice for stand-alone fuel cell power systems.

Kumar, R.; Ahmed, S.; Krumpelt, M.; Myles, K.M.

1992-08-01T23:59:59.000Z

270

MID-ATLANTIC REGIONAL OCEAN RESEARCH PLAN  

E-Print Network [OSTI]

................................................................................. 24 #12;v ASMFC Atlantic States Marine Fisheries Commission BOEM Bureau of Ocean Energy Management BMPMID-ATLANTIC REGIONAL OCEAN RESEARCH PLAN SEPTEMBER 2012 Sea Grant Mid-Atlantic Ocean Research #12;MID-ATLANTIC REGIONAL OCEAN RESEARCH PLAN SEPTEMBER 2012 Sea Grant Mid-Atlantic Ocean Research

271

P h y s i c a l O c e a n o g r a p h y D i v i s i o n Optimizing Ocean Observations for Hurricane Forecast Improvement  

E-Print Network [OSTI]

forecasts for individual storms and improved seasonal forecast of the ocean thermal energy availableP h y s i c a l O c e a n o g r a p h y D i v i s i o n Optimizing Ocean Observations for Hurricane to provide NOAA the ability to evaluate new ocean observing systems, and alternate deployments of existing

272

APPLICATION OF MEMS TECHNOLOGY TO MICRO DIRECT METHANOL FUEL CELL Xiaowei Liu*  

E-Print Network [OSTI]

APPLICATION OF MEMS TECHNOLOGY TO MICRO DIRECT METHANOL FUEL CELL Xiaowei Liu* , Chunguang Suo, email: lxw@hit.edu.cn) ABSTRACT In view of micro fuel cells, the silicon processes are employed for microfabrication of the micro direct methanol fuel cell (DMFC). Using the MEMS technology we have successfully made

Paris-Sud XI, Universit de

273

Methane-to-Methanol Conversion by Gas-Phase Transition Metal Oxide Cations: Experiment and Theory  

E-Print Network [OSTI]

Methane-to-Methanol Conversion by Gas-Phase Transition Metal Oxide Cations: Experiment and Theory Ricardo B. Metz Department of Chemistry, University of Massachusetts, Amherst, MA 01003 USA Abstract Gas such as methanol has attracted great experimental and theoretical interest due to its importance as an industrial

Metz, Ricardo B.

274

Mechanism of O2 Activation and Methanol Production by (Di(2-pyridyl)methanesulfonate)PtII  

E-Print Network [OSTI]

conversion of methane to methanol at low temper- ature is crucial for transportation of shale gas produced it to methanol and its derivatives. In this system, the kinetics of the oxidation of Pt(II) is important because activation and selective conversion of Pt(II) monomethyl complex (dpms)PtII Me(OH2) to its monomethyl Pt

Goddard III, William A.

275

Performance and endurance of a high temperature PEM fuel cell operated on methanol reformate  

E-Print Network [OSTI]

Performance and endurance of a high temperature PEM fuel cell operated on methanol reformate Samuel September 2014 Available online xxx Keywords: High temperature PEM Fuel cell Methanol Impedance spectroscopy]. The report forecasts even more success for fuel cells in the near future. Proton exchange membrane (PEM) fuel

Kær, Søren Knudsen

276

Electrochimica Acta 52 (2007) 43174324 Porous current collectors for passive direct methanol fuel cells  

E-Print Network [OSTI]

Electrochimica Acta 52 (2007) 43174324 Porous current collectors for passive direct methanol fuel methanol fuel cell (DMFC) with its cathode current collector made of porous metal foam was investigated that the passive DMFC having the porous current collector yielded much higher and much more stable performance than

Zhao, Tianshou

2007-01-01T23:59:59.000Z

277

Effect of Transient Hydrogen Evolution/Oxidation Reactions on the OCV of Direct Methanol Fuel Cells  

E-Print Network [OSTI]

Effect of Transient Hydrogen Evolution/Oxidation Reactions on the OCV of Direct Methanol Fuel Cells of a direct methanol fuel cell DMFC was observed to undergo an overshoot before it stabilized during at the catalyst layer, resulting in a transient reference hydrogen electrode, which allows quantifying

Zhao, Tianshou

278

Towards the optimal integrated production of biodiesel with internal recycling of methanol  

E-Print Network [OSTI]

1 Towards the optimal integrated production of biodiesel with internal recycling of methanol of the production methanol from glycerol and its integration in the production of biodiesel from algae. We propose a limited superstructure where the glycerol from biodiesel is first reformed for which steam reforming

Grossmann, Ignacio E.

279

Spectroscopy and dynamics of mixtures of water with acetone, acetonitrile, and methanol  

E-Print Network [OSTI]

Spectroscopy and dynamics of mixtures of water with acetone, acetonitrile, and methanol Dean S mixtures of water with acetone, acetonitrile, and methanol over their entire range of compositions have and acetonitrile mixtures. Spatial distribution functions are reported for the acetone/water system. © 2000

280

Hydrogen Bond Dissociation and Reformation in Methanol Oligomers Following Hydroxyl Stretch Relaxation  

E-Print Network [OSTI]

Hydrogen Bond Dissociation and Reformation in Methanol Oligomers Following Hydroxyl Stretch, 2002 Vibrational relaxation and hydrogen bond dynamics in methanol-d dissolved in CCl4 have been-d molecules both accepting and donating hydrogen bonds at 2500 cm-1 . Following vibrational relaxation

Fayer, Michael D.

Note: This page contains sample records for the topic "methanol ocean thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

ARM - Oceanic Properties  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc Documentation RUC : XDCResearchWarmingMethane Background InformationNewsMediaAlaskaNewsOceanic

282

Ocean Engineering at UNH THE OCEAN ENGINEERING program at UNH provides students with hands-on  

E-Print Network [OSTI]

-on opportunities for research in ocean renewable energy, remotely operated vehicles, ocean mapping, ocean acousticsOcean Engineering at UNH THE OCEAN ENGINEERING program at UNH provides students with hands, and coastal processes. The Jere A. Chase Ocean Engineering Laboratory is equipped with state

Pringle, James "Jamie"

283

Methanol synthesis using a catalyst combination of alkali or alkaline earth salts and reduced copper chromite  

DOE Patents [OSTI]

The present invention relates to a novel route for the synthesis of methanol, and more specifically to the production of methanol by contacting synthesis gas under relatively mild conditions in a slurry phase with a catalyst combination comprising reduced copper chromite and basic alkali salts or alkaline earth salts. The present invention allows the synthesis of methanol to occur in the temperature range of approximately 100.degree.-160.degree. C. and the pressure range of 40-65 atm. The process produces methanol with up to 90% syngas conversion per pass and up to 95% methanol selectivity. The only major by-product is a small amount of easily separated methyl formate. Very small amounts of water, carbon dioxide and dimethyl ether are also produced. The present catalyst combination also is capable of tolerating fluctuations in the H.sub.2 /CO ratio without major deleterious effect on the reaction rate. Furthermore, carbon dioxide and water are also tolerated without substantial catalyst deactivation.

Tierney, John W. (Pittsburgh, PA); Wender, Irving (Pittsburgh, PA); Palekar, Vishwesh M. (Pittsburgh, PA)

1995-01-01T23:59:59.000Z

284

Methanol synthesis using a catalyst combination of alkali or alkaline earth salts and reduced copper chromite  

DOE Patents [OSTI]

The present invention relates to a novel route for the synthesis of methanol, and more specifically to the production of methanol by contacting synthesis gas under relatively mild conditions in a slurry phase with a catalyst combination comprising reduced copper chromite and basic alkali salts or alkaline earth salts. The present invention allows the synthesis of methanol to occur in the temperature range of approximately 100--160 C and the pressure range of 40--65 atm. The process produces methanol with up to 90% syngas conversion per pass and up to 95% methanol selectivity. The only major by-product is a small amount of easily separated methyl formate. Very small amounts of water, carbon dioxide and dimethyl ether are also produced. The present catalyst combination also is capable of tolerating fluctuations in the H[sub 2]/CO ratio without major deleterious effect on the reaction rate. Furthermore, carbon dioxide and water are also tolerated without substantial catalyst deactivation.

Tierney, J.W.; Wender, I.; Palekar, V.M.

1995-01-24T23:59:59.000Z

285

The Influence of Chain Dynamics on the Far Infrared Spectrum of Liquid Methanol-Water Mixtures  

SciTech Connect (OSTI)

Far-infrared absorption spectroscopy has been used to study the low frequency ({center_dot} 100 cm{sup -1}) intermolecular modes of methanol in mixtures with water. With the aid of a first principles molecular dynamics simulation on an equivalent system, a detailed understanding about the origin of the low frequency IR modes has been established. The total dipole spectrum from the simulation suggests that the bands appearing in the experimental spectra at approximately 55 cm{sup -1} and 70 cm{sup -1} in methanol and methanol-rich mixtures arise from both fluctuations and torsional motions occurring within the methanol hydrogen-bonded chains. The influence of these modes on both the solvation dynamics and the relaxation mechanisms in the liquid are discussed within the context of recent experimental and theoretical results that have emerged from studies focusing on the short time dynamics in the methanol hydrogen bond network.

Woods, K.N.; /Stanford U., Phys. Dept.; Wiedemann, H.; /SLAC, SSRL; ,

2005-07-12T23:59:59.000Z

286

Modeling of the anode side of a direct methanol fuel cell with analytical solutions  

E-Print Network [OSTI]

In this work, analytical solutions were derived (for any methanol oxidation reaction order) for the profiles of methanol concentration and proton current density by assuming diffusion mass transport mechanism, Tafel kinetics, and fast proton transport in the anodic catalyst layer of a direct methanol fuel cell. An expression for the Thiele modulus that allows to express the anodic overpotential as a function of the cell current, and kinetic and mass transfer parameters was obtained. For high cell current densities, it was found that the Thiele modulus ($\\phi^2$) varies quadratically with cell current density; yielding a simple correlation between anodic overpotential and cell current density. Analytical solutions were derived for the profiles of both local methanol concentration in the catalyst layer and local anodic current density in the catalyst layer. Under the assumptions of the model presented here, in general, the local methanol concentration in the catalyst layer cannot be expressed as an explicit fun...

Mosquera, Martn A

2010-01-01T23:59:59.000Z

287

Process for producing carbon monoxide and hydrogen from methanol  

SciTech Connect (OSTI)

A process is described for producing carbon monoxide and hydrogen which comprises contacting methanol vapor at a temperature of 200 degrees to 300 degrees C with an indirectly heated zinc containing catalyst to obtain an effluent gas in which the components of carbon monoxide and hydrogen constitute at least 90% by volume of said gas. At least a part of the impurities from said effluent gas are removed and said effluent gas is deparated into its carbon monoxide and hydrogen components by adsorption. The effluent gas can be separated into its carbon monoxide and hydrogen components by use of a plurality of adsorbers containing zeolite-type molecular sieve material where the zeolite is substantially permeable to hydrogen but sorbs carbon monoxide.

Jockel, H.; Marschner, F.; Moller, F.W.; Mortel, H.

1982-02-23T23:59:59.000Z

288

Direct Methanol Fuel Cell Prototype Demonstration for Consumer Electronics Applications  

SciTech Connect (OSTI)

This report is the final technical report for DOE Program DE-FC36-04GO14301 titled Direct Methanol Fuel Cell Prototype Demonstration for Consumer Electronics Applications. Due to the public nature of this report some of the content reported in confidential reports and meetings to the DOE is not covered in detail in this report and some of the content has been normalized to not show actual values. There is a comparison of the projects accomplishments with the objectives, an overview of some of the key subsystem work, and a review of the three levels of prototypes demonstrated during the program. There is also a description of the eventual commercial product and market this work is leading towards. The work completed under this program has significantly increased the understanding of how Direct Methanol Fuel Cells (DMFC) can be deployed successfully to power consumer electronic devices. The prototype testing has demonstrated the benefits a direct methanol fuel cell system has over batteries typically used for powering consumer electronic devices. Three generations of prototypes have been developed and tested for performance, robustness and life. The technologies researched and utilized in the fuel cell stack and related subsystems for these prototypes are leveraged from advances in other industries such as the hydrogen fueled PEM fuel cell industry. The work under this program advanced the state of the art of direct methanol fuel cells. The system developed by MTI micro fuel cells aided by this program differs significantly from conventional DMFC designs and offers compelling advantages in the areas of performance, life, size, and simplicity. The program has progressed as planned resulting in the completion of the scope of work and available funding in December 2008. All 18 of the final P3 prototypes builds have been tested and the results showed significant improvements over P2 prototypes in build yield, initial performance, and durability. The systems have demonstrated robust operation when tested at various orientations, temperatures, and humidity levels. Durability testing has progressed significantly over the course of the program. MEA, engine, and system level steady state testing has demonstrated degradation rates acceptable for initial product introduction. Test duration of over 5000 hrs has been achieved at both the MEA and breadboard system level. P3 level prototype life testing on engines (stacks with reactant conditioning) showed degradation rates comparable to carefully constructed lab fixtures. This was a major improvement over the P2 and P1 engine designs, which exhibited substantial reductions in life and performance between the lab cell and the actual engine. Over the course of the work on the P3 technology set, a platform approach was taken to the system design. By working in this direction, a number of product iterations with substantial market potential were identified. Although the main effort has been the development of a prototype charger for consumer electronic devices, multiple other product concepts were developed during the program showing the wide variety of potential applications.

Carlstrom, Charles, M., Jr.

2009-07-07T23:59:59.000Z

289

Modeling Ocean Ecosystems: The PARADIGM Program  

E-Print Network [OSTI]

The role of the oceans in Earth systems ecology, and the effects of climate variability on the ocean and its ecosystems, can be understood only by observing, describing, and ultimately predicting the state of the ocean as ...

Rothstein, Lewis M.

290

Pelagic Polychaetes of the Pacific Ocean  

E-Print Network [OSTI]

Polyc'kaetes of the Pacific Ocean CLAPARtDE,E. 1868. LesPolyc'haetes of the Pacific Ocean KINBERG, J. G. H. 1866.Polyc'kaetes of the Pacific Ocean TREADWELL, A. L. 1906.

Dales, K Phillips

1957-01-01T23:59:59.000Z

291

OCEAN DRILLING PROGRAM LEG 190 SCIENTIFIC PROSPECTUS  

E-Print Network [OSTI]

164 Japan __________________ Dr. Jack Baldauf Deputy Director of Science Operations Ocean Drilling under the international Ocean Drilling Program, which is managed by Joint Oceanographic Institutions) Natural Environment Research Council (United Kingdom) European Science Foundation Consortium for the Ocean

292

California Small Hydropower and Ocean Wave Energy  

E-Print Network [OSTI]

California Small Hydropower and Ocean Wave Energy Resources IN SUPPORT OF THE 2005 INTEGRATED....................................................................................................................... 9 Ocean Wave Energy................................................................. 21 #12;ii List of Tables Table 1 California Small Hydropower And Ocean Wave Energy Resources Table 2

293

Recovery Act: Advanced Direct Methanol Fuel Cell for Mobile Computing  

SciTech Connect (OSTI)

ABSTRACT Project Title: Recovery Act: Advanced Direct Methanol Fuel Cell for Mobile Computing PROJECT OBJECTIVE The objective of the project was to advance portable fuel cell system technology towards the commercial targets of power density, energy density and lifetime. These targets were laid out in the DOEs R&D roadmap to develop an advanced direct methanol fuel cell power supply that meets commercial entry requirements. Such a power supply will enable mobile computers to operate non-stop, unplugged from the wall power outlet, by using the high energy density of methanol fuel contained in a replaceable fuel cartridge. Specifically this project focused on balance-of-plant component integration and miniaturization, as well as extensive component, subassembly and integrated system durability and validation testing. This design has resulted in a pre-production power supply design and a prototype that meet the rigorous demands of consumer electronic applications. PROJECT TASKS The proposed work plan was designed to meet the project objectives, which corresponded directly with the objectives outlined in the Funding Opportunity Announcement: To engineer the fuel cell balance-of-plant and packaging to meet the needs of consumer electronic systems, specifically at power levels required for mobile computing. UNF used existing balance-of-plant component technologies developed under its current US Army CERDEC project, as well as a previous DOE project completed by PolyFuel, to further refine them to both miniaturize and integrate their functionality to increase the system power density and energy density. Benefits of UNFs novel passive water recycling MEA (membrane electrode assembly) and the simplified system architecture it enabled formed the foundation of the design approach. The package design was hardened to address orientation independence, shock, vibration, and environmental requirements. Fuel cartridge and fuel subsystems were improved to ensure effective fuel containment. PROJECT OVERVIEW The University of North Florida (UNF), with project partner the University of Florida, recently completed the Department of Energy (DOE) project entitled Advanced Direct Methanol Fuel Cell for Mobile Computing. The primary objective of the project was to advance portable fuel cell system technology towards the commercial targets as laid out in the DOE R&D roadmap by developing a 20-watt, direct methanol fuel cell (DMFC), portable power supply based on the UNF innovative passive water recovery MEA. Extensive component, sub-system, and system development and testing was undertaken to meet the rigorous demands of the consumer electronic application. Numerous brassboard (nonpackaged) systems were developed to optimize the integration process and facilitating control algorithm development. The culmination of the development effort was a fully-integrated, DMFC, power supply (referred to as DP4). The project goals were 40 W/kg for specific power, 55 W/l for power density, and 575 Whr/l for energy density. It should be noted that the specific power and power density were for the power section only, and did not include the hybrid battery. The energy density is based on three, 200 ml, fuel cartridges, and also did not include the hybrid battery. The results show that the DP4 system configured without the methanol concentration sensor exceeded all performance goals, achieving 41.5 W/kg for specific power, 55.3 W/l for power density, and 623 Whr/l for energy density. During the project, the DOE revised its technical targets, and the definition of many of these targets, for the portable power application. With this revision, specific power, power density, specific energy (Whr/kg), and energy density are based on the total system, including fuel tank, fuel, and hybridization battery. Fuel capacity is not defined, but the same value is required for all calculations. Test data showed that the DP4 exceeded all 2011 Technical Status values; for example, the DP4 energy density was 373 Whr/l versus the DOE 2011 status of 200 Whr/l. For the

Fletcher, James H. [University of North Florida; Cox, Philip [University of North Florida; Harrington, William J [University of North Florida; Campbell, Joseph L [University of North Florida

2013-09-03T23:59:59.000Z

294

November 2002 OCEAN DRILLING PROGRAM  

E-Print Network [OSTI]

November 2002 OCEAN DRILLING PROGRAM LEG 209 SCIENTIFIC PROSPECTUS DRILLING MANTLE PERIDOTITE ALONG Drilling Program Texas A&M University 1000 Discovery Drive College Station TX 77845-9547 USA -------------------------------- Dr. D. Jay Miller Leg Project Manager and Staff Scientist Ocean Drilling Program Texas A&M University

295

January 2003 OCEAN DRILLING PROGRAM  

E-Print Network [OSTI]

January 2003 OCEAN DRILLING PROGRAM LEG 210 SCIENTIFIC PROSPECTUS DRILLING THE NEWFOUNDLAND HALF OF THE NEWFOUNDLAND­IBERIA TRANSECT: THE FIRST CONJUGATE MARGIN DRILLING IN A NON-VOLCANIC RIFT Brian E. Tucholke Co Baldauf Deputy Director of Science Operations Ocean Drilling Program Texas A&M University 1000 Discovery

296

The Plastic Ocean Michael Gonsior  

E-Print Network [OSTI]

The Plastic Ocean Michael Gonsior Bonnie Monteleone, William Cooper, Jennifer O'Keefe, Pamela Seaton, and Maureen Conte #12;#12;#12;Plastic does not biodegrade it photo-degrades breaking down is the plastic cheese wrap? Unfortunately, marine creatures mistake plastics in the ocean for food #12

Boynton, Walter R.

297

GENERATING ELECTRICITY USING OCEAN WAVES  

E-Print Network [OSTI]

GENERATING ELECTRICITY USING OCEAN WAVES A RENEWABLE SOURCE OF ENERGY REPORT FOR THE HONG KONG ELECTRIC COMPANY LIMITED Dr L F Yeung Mr Paul Hodgson Dr Robin Bradbeer July 2007 #12;Ocean Waves and construction of equipment that could measure and log wave conditions and tide levels at Hoi Ha Wan. Prototypes

Bradbeer, Robin Sarah

298

Herzig, P.M., Humphris, S.E., Miller, D.J., and Zierenberg, R.A. (Eds.), 1998 Proceedings of the Ocean Drilling Program, Scientific Results, Vol. 158  

E-Print Network [OSTI]

and related hydrothermal processes (RIDGE, 1992; Ocean Drilling Program [ODP], 1996). Conduction through of the Ocean Drilling Program, Scientific Results, Vol. 158 329 24. THERMAL PROPERTIES OF TAG HYDROTHERMAL hydrothermal field, located in the rift valley of the Mid-Atlantic Ridge near 26°N, 45°W. Thermal conductivity

299

In Proc of Direct Methanol Fuel Cell Symposium, 199th Electrochem.l Soc. Mtg, Washington DC, 3/01.  

E-Print Network [OSTI]

In Proc of Direct Methanol Fuel Cell Symposium, 199th Electrochem.l Soc. Mtg, Washington DC, 3/01. MATHEMATICAL MODELING OF LIQUID-FEED DIRECT METHANOL FUEL CELLS Z. H. Wang and C. Y. Wang Electrochemical methanol fuel cells (DMFC). Diffusion and convection of both gas and liquid phases are considered

Wang, Chao-Yang

300

Enhancement of water retention in the membrane electrode assembly for direct methanol fuel cells operating with neat  

E-Print Network [OSTI]

to achieve the neat-methanol operation is to passively transport the water produced at the cathode throughEnhancement of water retention in the membrane electrode assembly for direct methanol fuel cells operating with neat methanol Q.X. Wu, T.S. Zhao*, R. Chen, W.W. Yang Department of Mechanical Engineering

Zhao, Tianshou

Note: This page contains sample records for the topic "methanol ocean thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Effect of water concentration in the anode catalyst layer on the performance of direct methanol fuel cells operating  

E-Print Network [OSTI]

significantly increase the methanol-crossover rate, producing an unfavorable * Corresponding author. DepartmentEffect of water concentration in the anode catalyst layer on the performance of direct methanol fuel cells operating with neat methanol Q.X. Wu a , S.Y. Shen a , Y.L. He b , T.S. Zhao a

Zhao, Tianshou

302

Correlating catalytic methanol oxidation with the structure and oxidation state of size-1 selected Pt nanoparticles2  

E-Print Network [OSTI]

in the performance of direct methanol fuel cells (DMFC), which produce electricity from11 liquid fuel without1 Correlating catalytic methanol oxidation with the structure and oxidation state of size-1 * Corresponding author: roldan@ucf.edu9 Keywords: platinum; methanol oxidation; operando; XAS; EXAFS; alumina

Kik, Pieter

303

Abrupt Decline in the Open-Circuit Voltage of Direct Methanol Fuel Cells at Critical Oxygen Feed Rate  

E-Print Network [OSTI]

Abrupt Decline in the Open-Circuit Voltage of Direct Methanol Fuel Cells at Critical Oxygen Feed and Technology, Clear Water Bay, Kowloon, Hong Kong, China The open-circuit voltage OCV of a direct methanol fuel cell DMFC was measured by varying the cathode oxygen flow rate OFR while keeping the methanol

Zhao, Tianshou

304

Test method for the measurement of methanol emissions from stationary sources  

SciTech Connect (OSTI)

Methanol was designated under Title III of the Clean Air Act Amendments of 1990 as a pollutant to be regulated. A test method has been developed for the measurement of methanol emissions from stationary sources. The methanol sampling train (MST) consists of a glass-lined heated probe, two condensate knockout traps, and three sorbent cartridges packed with Anasorb 747. The Anasorb samples were desorbed with a 1:1 mixture of carbon disulfide and N,N-dimethylformamide. All samples were analyzed by gas chromatography with flame ionization detection. Following laboratory testing, field tests of the MST and the National Council of the Paper Industry for Air and Stream Improvement (NCASI) sampling method for methanol were conducted at two pulp and paper mills. In accordance with EPA Methol 301, two pairs of trains were run in parallel for six runs, collecting a total of 24 samples by each method. During each run, half of the trains were spiked with a known amount of methanol. The sampling location at the first test was an inlet vent to a softwood bleach plant scrubber where the methanol concentration was about 30 ppm. A second field test was conducted at the vent of a black liquor oxidation tank where the methanol concentration was about 350 ppm. Samples were shown to be stable for at least 2 weeks after collection.

Pate, B.A.; Peterson, M.R.; Rickman, E.E.; Jayanty, R.K.M.

1994-05-01T23:59:59.000Z

305

Response of oceanic hydrate-bearing sediments to thermal stresses  

E-Print Network [OSTI]

mass of water produced from the gravel pack (M W ).Wellbore designs with gravel packs that allow gas ventingattributed to a sand or gravel pack emplaced during drilling

Moridis, G.J.; Kowalsky, M.B.

2006-01-01T23:59:59.000Z

306

OCEAN THERMAL ENERGY CONVERSION (OTEC) PROGRAMMATIC ENVIRONMENTAL ANALYSIS  

E-Print Network [OSTI]

skipjack tuna, Katsuwonnus pelamis, in an offshore area oflittle tuna), Katsuwonus pelamis (skipj ack), spp. ,

Sands, M. D.

2011-01-01T23:59:59.000Z

307

DRAFT. ENVIRONMENTAL ASSESSMENT OCEAN THERMAL ENERGY CONVERSION (OTEC) PILOT PLANTS  

E-Print Network [OSTI]

the external fluid mechanics of OTEC plants: report coveringthermal energy conversion ( OTEC) plants by mid-1980 1 s.distributiion at potential OTEC sites. p. 7D-4/1-4/5. In

Sullivan, S.M.

2014-01-01T23:59:59.000Z

308

OCEAN THERMAL ENERGY CONVERSION: AN OVERALL ENVIRONMENTAL ASSESSMENT  

E-Print Network [OSTI]

Environmental Assessment OTEC Pilot Plant. Prepared forDraft Environmental Assessment Mini-OTEC Second Deployment.matic EA are within the OTEC technology and include the

Sands, M.Dale

2013-01-01T23:59:59.000Z

309

OCEAN THERMAL ENERGY CONVERSION (OTEC) PROGRAMMATIC ENVIRONMENTAL ANALYSIS  

E-Print Network [OSTI]

SCENARIO . . . . . . . . . . OTEC RESOURCE REGIONALC-1 ILLUSTRATIONS Number Title OTEC Systems Development Gulfof Mexico Moored OTEC Resource Area . . . . . . . . . . .

Sands, M. D.

2011-01-01T23:59:59.000Z

310

OCEAN THERMAL ENERGY CONVERSION (OTEC) PROGRAMMATIC ENVIRONMENTAL ANALYSIS  

E-Print Network [OSTI]

industrial users. Costs and per kWh increased from to 2.7rf-30, 1978, the average cost per kWh was 6.09i for residential

Sands, M. D.

2011-01-01T23:59:59.000Z

311

OCEAN THERMAL ENERGY CONVERSION (OTEC) PROGRAMMATIC ENVIRONMENTAL ANALYSIS  

E-Print Network [OSTI]

Occupational Safety and Health Administration (OSHA) safety, and the Coast Guard covers mar1ne covers some offshore

Sands, M. D.

2011-01-01T23:59:59.000Z

312

OCEAN THERMAL ENERGY CONVERSION (OTEC) PROGRAMMATIC ENVIRONMENTAL ANALYSIS  

SciTech Connect (OSTI)

This programmatic environmental analysis is an initial assessment of OTEC technology considering development, demonstration and commercialization; it is concluded that the OTEC development program should continue because the development, demonstration, and commercialization on a single-plant deployment basis should not present significant environmental impacts. However, several areas within the OTEC program require further investigation in order to assess the potential for environmental impacts from OTEC operation, particularly in large-scale deployments and in defining alternatives to closed-cycle biofouling control: (1) Larger-scale deployments of OTEC clusters or parks require further investigations in order to assess optimal platform siting distances necessary to minimize adverse environmental impacts. (2) The deployment and operation of the preoperational platform (OTEC-1) and future demonstration platforms must be carefully monitored to refine environmental assessment predictions, and to provide design modifications which may mitigate or reduce environmental impacts for larger-scale operations. These platforms will provide a valuable opportunity to fully evaluate the intake and discharge configurations, biofouling control methods, and both short-term and long-term environmental effects associated with platform operations. (3) Successful development of OTEC technology to use the maximal resource capabilities and to minimize environmental effects will require a concerted environmental management program, encompassing many different disciplines and environmental specialties.

Sands, M. D.

1980-01-01T23:59:59.000Z

313

The Potential Impact of Ocean Thermal Energy Conversion (OTEC)  

E-Print Network [OSTI]

The major responsibilities of the National Marine Fisheries Service (NMFS) are to monitor and assess the abundance and geographic distribution of fishery resources, to understand and predict fluctuations in the quantity and distribution of these resources, and to establish levels for their optimum use. NMFS is also charged with the development and implementation of policies for managing national fishing grounds, development and enforcemeJlt of domestic fisheries regulations, surveillance of foreign fishing off United States coastal waters, and the development and enforcement of international fishery agreements and policies. NMFS also assists the fishing industry through marketing service and economic analysis programs, and mortgage insurance and vessel cunstruction subsidies. It collects, analyzes, and publishes statistics on various phases of the industry.

On Fisheries; Edward P. Myers; Donald E. Hoss; Walter M. Matsumoto; David S. Peters; Michael P. Seki; Richard N. Uchida; John D. Ditmars; Robert A. Paddock

1986-01-01T23:59:59.000Z

314

OCEAN THERMAL ENERGY CONVERSION (OTEC) PROGRAMMATIC ENVIRONMENTAL ANALYSIS  

E-Print Network [OSTI]

aspects of siting OTEC plants offshore the United States ongas. phosgene Offshore ammonia plant-ships will presentan facility offshore may expose the plant to power outages

Sands, M. D.

2011-01-01T23:59:59.000Z

315

OCEAN THERMAL ENERGY CONVERSION (OTEC) PROGRAMMATIC ENVIRONMENTAL ANALYSIS  

E-Print Network [OSTI]

Electricity - Hawaii is almost totally dependent upon imported petroleum A natural energy source of geothermal

Sands, M. D.

2011-01-01T23:59:59.000Z

316

OCEAN THERMAL ENERGY CONVERSION (OTEC) PROGRAMMATIC ENVIRONMENTAL ANALYSIS  

E-Print Network [OSTI]

by liquifaction and fractional distillation of air (EPA, Thefractional elements nitrogen pure form. Nitrogen \\'lill be extracted from the atmosphere by means of liquefaction and distillation,

Sands, M. D.

2011-01-01T23:59:59.000Z

317

Ocean Thermal Extractable Energy Visualization: Final Technical Report |  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergyENERGY TAXBalanced ScorecardReactor TechnologyOFFICE: I Oak Ridge,8 8EnergyQ1

318

Response of oceanic hydrate-bearing sediments to thermal stresses  

E-Print Network [OSTI]

c) aqueous, gas and hydrate phase saturations, (d) waterIntrinsic Rate of Methane Gas Hydrate Decomposition, Chem.Western Nankai Trough, in Gas Hydrates: Challenges for the

Moridis, G.J.; Kowalsky, M.B.

2006-01-01T23:59:59.000Z

319

NREL-Ocean Energy Thermal Conversion | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to:46 -Energieprojekte3Informationof Energy Calculator Jump to: navigation,

320

A REVIEW OF GLOBAL OCEAN TEMPERATURE OBSERVATIONS: IMPLICATIONS FOR OCEAN  

E-Print Network [OSTI]

by taking an inventory of changes in energy storage. The main storage is in the ocean, the latest values, Energy Sustainable Economic, Earth's energy imbalance, and thermosteric sea level rise. Up-to-date estimates are provided

Note: This page contains sample records for the topic "methanol ocean thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

composition of putative oceans on  

E-Print Network [OSTI]

#12;Results: Oceanic water composition · Oceanic water is a NaCl-CaCl2 solution · Large Cl mass · Cl in a "soda ocean" Temperature, o C 100 200 300 400 500 Concentration,mole/kgH2O 0.01 0.1 1 Cl- CaCl2 CaCl+ Na calcite · Quartz · Na-K feldspars · Anhydrite · Pyrite · Hematite/magnetite · Evaporites: NaCl+CaCl2 350o

Treiman, Allan H.

322

Ocean Studies Board annual report 1990  

SciTech Connect (OSTI)

Activities of the Ocean Studies Board fall into three broad categories: promoting the health of ocean sciences in the United States, encouraging the protection and wise use of the ocean and its resources, and applying ocean science to improve national security.

Not Available

1991-12-31T23:59:59.000Z

323

Ocean Studies Board annual report 1990  

SciTech Connect (OSTI)

Activities of the Ocean Studies Board fall into three broad categories: promoting the health of ocean sciences in the United States, encouraging the protection and wise use of the ocean and its resources, and applying ocean science to improve national security.

Not Available

1991-01-01T23:59:59.000Z

324

Heat Content Changes in the Pacific Ocean  

E-Print Network [OSTI]

Heat Content Changes in the Pacific Ocean The Acoustic Thermometry of Ocean Cli- mate (ATOC assimilating ocean observations and changes expected from surface heat fluxes as measured by the daily National are a result of advection of heat by ocean currents. We calculate that the most likely cause of the discrepancy

Frandsen, Jannette B.

325

OCEAN-ATMOSPHERE INTERACTION AND TROPICAL CLIMATE  

E-Print Network [OSTI]

radiation is the ultimate source of energy for motions in the atmosphere and ocean. Most absorption of solar radiation takes place on the Earth surface, the majority of which is occupied by oceans. Thus oceanic modulate surface radiative flux. Thus, the ocean and atmosphere are a coupled system and their interaction

Xie, Shang-Ping

326

OCEAN DRILLING PROGRAM LEG 165 SCIENTIFIC PROSPECTUS  

E-Print Network [OSTI]

OCEAN DRILLING PROGRAM LEG 165 SCIENTIFIC PROSPECTUS CARIBBEAN OCEAN HISTORY AND THE CRETACEOUS Scientist, Leg 165 Ocean Drilling Program Texas A&M University Research Park 1000 Discovery Drive College of any portion requires the written consent of the Director, Ocean Drilling Program, Texas A&M University

327

OCEAN DRILLING PROGRAM LEG 104 SCIENTIFIC PROSPECTUS  

E-Print Network [OSTI]

OCEAN DRILLING PROGRAM LEG 104 SCIENTIFIC PROSPECTUS NORWEGIAN SEA Olav Eldholm Co-Chief Scientist Ocean Drilling Program Texas A & M University College Station, Texas 77843-3469 Pni±ip o Rabinowitz Director Ocean Drilling Program Robert B Kidd Manager of Science Operations Ocean Drilling Program Louis E

328

OCEAN DRILLING PROGRAM LEG 110 SCIENTIFIC PROSPECTUS  

E-Print Network [OSTI]

OCEAN DRILLING PROGRAM LEG 110 SCIENTIFIC PROSPECTUS LESSER ANTILLES FOREARC J. Casey Moore Staff Science Representative, Leg 110 Ocean Drilling Program Texas A&M University College Station, TX 77843-3469 Philip D. Direct* Ocean Drilling Program Robert B. Kidd Manager of Science Operations Ocean

329

INSTRUCTIONS INTEGRATED OCEAN DRILLING PROGRAM (IODP)  

E-Print Network [OSTI]

INSTRUCTIONS FOR THE INTEGRATED OCEAN DRILLING PROGRAM (IODP) MANUSCRIPT AND PHOTOGRAPH COPYRIGHT, Integrated Ocean Drilling Program, 1000 Discovery Drive, College Station, Texas 77845, USA A signed copyright of the Integrated Ocean Drilling Program or any other publications of the Integrated Ocean Drilling Program. Author

330

OCEAN DRILLING PROGRAM LEG 109 PRELIMINARY REPORT  

E-Print Network [OSTI]

OCEAN DRILLING PROGRAM LEG 109 PRELIMINARY REPORT BARE ROCK DRILLING IN THE MID-ATLANTIC RIDGE RIFT 109 Ocean Drilling Program Texas A & M University College Station, TX 77843-3469 Philip D. Rabinowitz Director Ocean Drilling Program Robert B. Kidd Manager of Science Operations Ocean Drilling Program Louis E

331

n CAPABILITY STATEMENT Centre for Ocean Engineering,  

E-Print Network [OSTI]

n CAPABILITY STATEMENT Centre for Ocean Engineering, Science and Technology Overview The Centre for Ocean Engineering, Science and Technology (COEST) is dedicated to the ocean, the most fascinating and the most challenging environment for human endeavour. COEST brings together the disciplines of ocean

Liley, David

332

4, 709732, 2007 Ice-shelf ocean  

E-Print Network [OSTI]

OSD 4, 709732, 2007 Ice-shelf ocean interactions at Fimbul Ice Shelf M. R. Price Title Page published in Ocean Science Discussions are under open-access review for the journal Ocean Science Ice-shelf ocean interactions at Fimbul Ice Shelf, Antarctica from oxygen isotope ratio measurements M. R. Price 1

Boyer, Edmond

333

SHAPE SELECTIVE NANOCATALYSTS FOR DIRECT METHANOL FUEL CELL APPLICATIONS  

SciTech Connect (OSTI)

While gold and platinum have long been recognized for their beauty and value, researchers at the Savannah River National Laboratory (SRNL) are working on the nano-level to use these elements for creative solutions to our nation's energy and security needs. Multiinterdisciplinary teams consisting of chemists, materials scientists, physicists, computational scientists, and engineers are exploring unchartered territories with shape-selective nanocatalysts for the development of novel, cost effective and environmentally friendly energy solutions to meet global energy needs. This nanotechnology is vital, particularly as it relates to fuel cells.SRNL researchers have taken process, chemical, and materials discoveries and translated them for technological solution and deployment. The group has developed state-of-the art shape-selective core-shell-alloy-type gold-platinum nanostructures with outstanding catalytic capabilities that address many of the shortcomings of the Direct Methanol Fuel Cell (DMFC). The newly developed nanostructures not only busted the performance of the platinum catalyst, but also reduced the material cost and overall weight of the fuel cell.

Murph, S.

2012-09-12T23:59:59.000Z

334

The environment of the strongest galactic methanol maser  

E-Print Network [OSTI]

The high-mass star-forming site G009.62-00.20E hosts the 6.7 GHz methanol maser source with the greatest flux density in the Galaxy which has been flaring periodically over the last ten years. We performed high-resolution astrometric measurements of the CH3OH, H2O, and OH maser emission and 7 mm continuum in the region. The radio continuum emission was resolved in two sources separated by 1300 AU. The CH3OH maser cloudlets are distributed along two north-south ridges of emission to the east and west of the strongest radio continuum component. This component likely pinpoints a massive young stellar object which heats up its dusty envelope, providing a constant IR pumping for the Class II CH3OH maser transitions. We suggest that the periodic maser activity may be accounted for by an independent, pulsating, IR radiation field provided by a bloated protostar in the vicinity of the brightest masers. We also report about the discovery of an elliptical distribution of CH3OH maser emission in the region of periodic v...

Sanna, A; Carrasco-Gonzalez, C; Reid, M J; Ellingsen, S P; Brunthaler, A; Moscadelli, L; Cesaroni, R; Krishnan, V

2015-01-01T23:59:59.000Z

335

Exploring the Deep... Exploring the Ocean Environment Unit 1The Ocean Basins  

E-Print Network [OSTI]

GEO/OC 103 Exploring the Deep... Lab 2 #12;Exploring the Ocean Environment Unit 1­The Ocean Basins Ocean origins 19 How did the oceans form? Scientists believe that the oceans developed early ). This early atmosphere reflected much of the solar radiation striking Earth, allowing the surface to cool

Wright, Dawn Jeannine

336

Penetration of solar radiation in the upper ocean: A numerical model for oceanic and coastal waters  

E-Print Network [OSTI]

Penetration of solar radiation in the upper ocean: A numerical model for oceanic and coastal waters in the upper ocean, the vertical distribution of solar radiation (ESR) in the shortwave domain plays (2005), Penetration of solar radiation in the upper ocean: A numerical model for oceanic and coastal

Lee, Zhongping

337

Mercury in the Anthropocene Ocean  

E-Print Network [OSTI]

The toxic metal mercury is present only at trace levels in the ocean, but it accumulates in fish at concentrations high enough to pose a threat to human and environmental health. Human activity has dramatically altered the ...

Lamborg, Carl

338

The methanol-to-hydrocarbons reaction : Influence of acid strength on the mechanism of olefin formation.  

E-Print Network [OSTI]

??The methanol-to-hydrocarbons (MTH) reaction is a flexible alternative step in the upgrading of natural gas, coal or biomass. By tuning the catalyst and process conditions, (more)

Erichsen, Marius Westgrd

2010-01-01T23:59:59.000Z

339

Design of high-ionic conductivity electrodes for direct methanol fuel cells  

E-Print Network [OSTI]

Carbon-supported porous electrodes are used in low-temperature fuel cells to provide maximum catalyst surface area, while taking up little volume and using minimum catalyst material. In Direct Methanol Fuel Cells (DMFCs), ...

Schrauth, Anthony J

2011-01-01T23:59:59.000Z

340

Two-phase microfluidics, heat and mass transport in direct methanol fuel cells  

E-Print Network [OSTI]

CHAPTER 9 Two-phase microfluidics, heat and mass transport in direct methanol fuel cells G. Lu & C, including two-phase microfluidics, heat and mass transport. We explain how the better understanding

Note: This page contains sample records for the topic "methanol ocean thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Conversion of methanol to light olefins on SAPO-34: kinetic modeling and reactor design  

E-Print Network [OSTI]

design of an MTO reactor, accounting for the strong exothermicity of the process. Multi-bed adiabatic and fluidized bed technologies show good potential for the industrial process for the conversion of methanol into olefins....

Al Wahabi, Saeed M. H.

2005-02-17T23:59:59.000Z

342

E-Print Network 3.0 - agaricus blazei methanolic Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

direct methanol fuel cell DMFC and show that the overall mass... current density of an in-house-fabricated DMFC with different flow fields for various ... Source: Zhao, Tianshou -...

343

Methane Oxidation to Methanol without CO2 Emission: Catalysis by Atomic Negative Ions  

E-Print Network [OSTI]

The catalytic activities of the atomic Y-, Ru-, At-, In-, Pd-, Ag-, Pt-, and Os- ions have been investigated theoretically using the atomic Au- ion as the benchmark for the selective partial oxidation of methane to methanol without CO2 emission. Dispersion-corrected density-functional theory has been used for the investigation. From the energy barrier calculations and the thermodynamics of the reactions, we conclude that the catalytic effect of the atomic Ag-, At-, Ru-, and Os- ions is higher than that of the atomic Au- ion catalysis of CH4 conversion to methanol. By controlling the temperature around 290K (Os-), 300K (Ag-), 310K (At-), 320K (Ru-) and 325K (Au-) methane can be completely oxidized to methanol without the emission of CO2. We conclude by recommending the investigation of the catalytic activities of combinations of the above negative ions for significant enhancement of the selective partial oxidation of methane to methanol.

Tesfamichael, Aron; Felfli, Zineb; Msezane, Alfred Z

2014-01-01T23:59:59.000Z

344

Selective enrichment of a methanol-utilizing consortium using pulp & paper mill waste streams  

SciTech Connect (OSTI)

Efficient utilization of carbon inputs is critical to the economic viability of the current forest products sector. Input carbon losses occur in various locations within a pulp mill, including losses as volatile organics and wastewater . Opportunities exist to capture this carbon in the form of value-added products such as biodegradable polymers. Waste activated sludge from a pulp mill wastewater facility was enriched for 80 days for a methanol-utilizing consortium with the goal of using this consortium to produce biopolymers from methanol-rich pulp mill waste streams. Five enrichment conditions were utilized: three high-methanol streams from the kraft mill foul condensate system, one methanol-amended stream from the mill wastewater plant, and one methanol-only enrichment. Enrichment reactors were operated aerobically in sequencing batch mode at neutral pH and 25C with a hydraulic residence time and a solids retention time of four days. Non-enriched waste activated sludge did not consume methanol or reduce chemical oxygen demand. With enrichment, however, the chemical oxygen demand reduction over 24 hour feed/decant cycles ranged from 79 to 89 %, and methanol concentrations dropped below method detection limits. Neither the non-enriched waste activated sludge nor any of the enrichment cultures accumulated polyhydroxyalkanoates (PHAs) under conditions of nitrogen sufficiency. Similarly, the non-enriched waste activated sludge did not accumulate PHAs under nitrogen limited conditions. By contrast, enriched cultures accumulated PHAs to nearly 14% on a dry weight basis under nitrogen limited conditions. This indicates that selectively-enriched pulp mill waste activated sludge can serve as an inoculum for PHA production from methanol-rich pulp mill effluents.

Gregory R. Mockos; William A. Smith; Frank J. Loge; David N. Thompson

2007-04-01T23:59:59.000Z

345

The Influence of Chain Dynamics on theFar-Infrared Spectrum of Liquid Methanol  

SciTech Connect (OSTI)

Far-infrared absorption spectroscopy is used to investigate the low frequency ({center_dot} 100 cm{sup -1}) intermolecular interactions in liquid methanol. Using an intense source of far-infrared radiation, modes are elucidated at approximately 30 cm{sup -1} and 70 cm{sup -1} in the absorption spectrum. These modes are believed to arise from intermolecular bending and librational motions respectively and are successfully reproduced in an ab initio molecular dynamics simulation of methanol.

Woods, K.N.; /Stanford U., Phys. Dept.; Wiedemann, H.; /SLAC, SSRL; ,

2005-07-11T23:59:59.000Z

346

Development of microprocessor control for a V-6 engine fueled by prevaporized methanol  

E-Print Network [OSTI]

DEVELOPMENT OF MICROPROCESSOR CONTROL FOR A V 6 ENGINE FUELED BY PREVAPORIZED METHANOL A Thesis by DONALD F. SCHNEIDER Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree... of MASTER OF SCIENCE August 19SS Major Subject: Chemical Engineering DEVELOPMENT OF MICROPROCESSOR CONTROL FOR A V 6 ENGINE FUELED BY PREVAPORIZED METHANOL A Thesis by DONALD F. SCHNEIDER Approved as to style and content by: JP& r~ R. R. Davison...

Schneider, Donald F.

1985-01-01T23:59:59.000Z

347

Methanol production from eucalyptus wood chips. Attachment III. Florida's eucalyptus energy farm and methanol refinery: the background environment  

SciTech Connect (OSTI)

A wide array of general background information is presented on the Central Florida area in which the eucalyptus energy plantation and methanol refinery will be located. Five counties in Central Florida may be affected by the project, DeSoto, Hardee, Hillsborough, Manatee, and Polk. The human resources of the area are reviewed. Included are overviews of population demographic and economic trends. Land use patterns and the transportation are system described, and the region's archeological and recreational resources are evaluated. The region's air quality is emphasized. The overall climate is described along with noise and air shed properties. An analysis of the region's water resources is included. Ground water is discussed first followed by an analysis of surface water. Then the overall quality and water supply/demand balance for the area is evaluated. An overview of the region's biota is presented. Included here are discussions of the general ecosystems in Central Florida, and an analysis of areas with important biological significance. Finally, land resources are examined.

Fishkind, H.H.

1982-04-01T23:59:59.000Z

348

Ocean Barrier Layers Effect on Tropical Cyclone Intensification  

SciTech Connect (OSTI)

Improving a tropical cyclone's forecast and mitigating its destructive potential requires knowledge of various environmental factors that influence the cyclone's path and intensity. Herein, using a combination of observations and model simulations, we systematically demonstrate that tropical cyclone intensification is significantly affected by salinity-induced barrier layers, which are 'quasi-permanent' features in the upper tropical oceans. When tropical cyclones pass over regions with barrier layers, the increased stratification and stability within the layer reduce storm-induced vertical mixing and sea surface temperature cooling. This causes an increase in enthalpy flux from the ocean to the atmosphere and, consequently, an intensification of tropical cyclones. On average, the tropical cyclone intensification rate is nearly 50% higher over regions with barrier layers, compared to regions without. Our finding, which underscores the importance of observing not only the upper-ocean thermal structure but also the salinity structure in deep tropical barrier layer regions, may be a key to more skillful predictions of tropical cyclone intensities through improved ocean state estimates and simulations of barrier layer processes. As the hydrological cycle responds to global warming, any associated changes in the barrier layer distribution must be considered in projecting future tropical cyclone activity.

Balaguru, Karthik; Chang, P.; Saravanan, R.; Leung, Lai-Yung R.; Xu, Zhao; Li, M.; Hsieh, J.

2012-09-04T23:59:59.000Z

349

Deployment, release and recovery of ocean riser pipes  

DOE Patents [OSTI]

An ocean thermal energy conversion facility includes a long pipe assembly which is supported at its upper end by the hull of the floating facility. Cold water flows to the facility from deep in the ocean. The pipe assembly comprises an elongate pipe construction and a weight connected to the lower end of the construction by a line of selected length. A floatation collar is connected to the construction at its upper end to cause the construction to have positive buoyancy and a center of buoyancy closer to the upper end of the construction than its center of mass. The weight renders the entire pipe assembly negatively buoyant. In the event that support of the pipe assembly should be lost, as by release of the assembly from the facility hull in an emergency, the assembly sinks to the ocean floor where it is moored by the weight. The pipe construction floats submerged above the ocean floor in a substantially vertical attitude which facilitates recovery of the assembly.

Person, Abraham (Los Alamitos, CA); Wetmore, Sherman B. (Westminster, CA); McNary, James F. (Santa Ana, CA)

1980-11-18T23:59:59.000Z

350

Open ocean DMS air/sea fluxes over the eastern South Pacific Ocean  

E-Print Network [OSTI]

over the North Pacific Ocean, J. Geophys. Res. - Atmos. ,air/sea fluxes over S. Pacific Ocean References Asher, W.in the equa- torial Pacific Ocean ( 1982 to 1996): Evidence

Marandino, C. A; De Bruyn, W. J; Miller, S. D; Saltzman, E. S

2009-01-01T23:59:59.000Z

351

INTEGRATED OCEAN DRILLING PROGRAM United States Implementing Organization  

E-Print Network [OSTI]

INTEGRATED OCEAN DRILLING PROGRAM United States Implementing Organization Consortium for Ocean. _______________________________ Steven R. Bohlen President, Joint Oceanographic Institutions Division Executive Director, Ocean Drilling

352

INTEGRATED OCEAN DRILLING PROGRAM United States Implementing Organization  

E-Print Network [OSTI]

INTEGRATED OCEAN DRILLING PROGRAM United States Implementing Organization Consortium for Ocean. Bohlen President, Joint Oceanographic Institutions Division Executive Director, Ocean Drilling Programs

353

Warm Bias and Parameterization of Boundary Upwelling in Ocean Models  

SciTech Connect (OSTI)

It has been demonstrated that Eastern Boundary Currents (EBC) are a baroclinic intensification of the interior circulation of the ocean due to the emergence of mesoscale eddies in response to the sharp buoyancy gradients driven by the wind-stress and the thermal surface forcing. The eddies accomplish the heat and salt transport necessary to insure that the subsurface flow is adiabatic, compensating for the heat and salt transport effected by the mean currents. The EBC thus generated occurs on a cross-shore scale of order 20-100 km, and thus this scale needs to be resolved in climate models in order to capture the meridional transport by the EBC. Our result indicate that changes in the near shore currents on the oceanic eastern boundaries are linked not just to local forcing, such as coastal changes in the winds, but depend on the basin-wide circulation as well.

Cessi, Paola; Wolfe, Christopher

2012-11-06T23:59:59.000Z

354

Ocean Fertilization and Other Climate Change Mitigation Strategies: An Overview  

SciTech Connect (OSTI)

In order to evaluate ocean fertilization in the larger context of other proposed strategies for reducing the threat of the global warming, a wide range of different climate change mitigation approaches are compared in terms of their long-term potential, stage of development, relative costs and potential risks, as well as public acceptance. This broad comparative analysis is carried out for the following climate change mitigation strategies: supply-side and end-use efficiency improvements, terrestrial and geological carbon sequestration, CO2 ocean disposal and iron fertilization, nuclear power, and renewable energy generation from biomass, passive solar, solar thermal, photovoltaics, hydroelectric and wind. In addition, because of the inherent problems of conducting an objective comparative cost-benefit analysis, two non-technological solutions to global warming are also discussed: curbing population growth and transitioning to a steady-state economy.

Huesemann, Michael H.

2008-07-29T23:59:59.000Z

355

Continental insulation, mantle cooling, and the surface area of oceans and continents  

E-Print Network [OSTI]

Continental insulation, mantle cooling, and the surface area of oceans and continents A. Lenardica May 2005 Abstract It is generally assumed that continents, acting as thermal insulation above. The theory predicts that parameter regimes exist for which increased continental insulation has no effect

Manga, Michael

356

A thermally self-sustained micro solid-oxide fuel-cell stack with high power density  

E-Print Network [OSTI]

A thermally self-sustained micro solid-oxide fuel-cell stack with high power density Zongping Shao1 for portable power generation1,2 . Accordingly, polymer-electrolyte direct- methanol fuel cells design challenges and cannot operate with hydrocarbon fuels of higher energy density. Solid-oxide fuel

Haile, Sossina M.

357

Carbon dioxide hydrogenation to form methanol via a reverse-water-gas-shift reaction (the CAMERE process)  

SciTech Connect (OSTI)

The CAMERE process (carbon dioxide hydrogenation to form methanol via a reverse-water-gas-shift reaction) was developed and evaluated. The reverse-water-gas-shift reactor and the methanol synthesis reactor were serially aligned to form methanol from CO{sub 2} hydrogenation. Carbon dioxide was converted to CO and water by the reverse-water-gas-shift reaction (RWReaction) to remove water before methanol was synthesized. With the elimination of water by RWReaction, the purge gas volume was minimized as the recycle gas volume decreased. Because of the minimum purge gas loss by the pretreatment of RWReactor, the overall methanol yield increased up to 89% from 69%. An active and stable catalyst with the composition of Cu/ZnO/ZrO{sub 2}/Ga{sub 2}O{sub 3} (5:3:1:1) was developed. The system was optimized and compared with the commercial methanol synthesis processes from natural gas and coal.

Joo, O.S.; Jung, K.D.; Han, S.H.; Uhm, S.J. [Korea Inst. of Science and Technology, Seoul (Korea, Republic of). Catalysis Lab.] [Korea Inst. of Science and Technology, Seoul (Korea, Republic of). Catalysis Lab.; Moon, I. [Yonsei Univ., Seoul (Korea, Republic of). Dept. of Chemical Engineering] [Yonsei Univ., Seoul (Korea, Republic of). Dept. of Chemical Engineering; Rozovskii, A.Y.; Lin, G.I. [A.V. Topchiev Inst. of Petrochemical Synthesis, Moscow (Russian Federation)] [A.V. Topchiev Inst. of Petrochemical Synthesis, Moscow (Russian Federation)

1999-05-01T23:59:59.000Z

358

Experimental Evaluation of a Pt-based Heat Exchanger Methanol Reformer for a HTPEM Fuel Cell Stack  

E-Print Network [OSTI]

) Included in this reaction is the decomposition of methanol, which produces CO: CH3OH CO + 2H2 (90.5 kJ mol a picture of the methanol reformer which has been designed to produce hydrogen for a 1 kWe HTPEM fuel cellExperimental Evaluation of a Pt-based Heat Exchanger Methanol Reformer for a HTPEM Fuel Cell Stack

Berning, Torsten

359

AQUIFER THERMAL ENERGY STORAGE  

E-Print Network [OSTI]

using aquifers for thermal energy storage. Problems outlinedmatical Modeling of Thermal Energy Storage in Aquifers,"ings of Aquifer Thermal Energy Storage Workshop, Lawrence

Tsang, C.-F.

2011-01-01T23:59:59.000Z

360

AQUIFER THERMAL ENERGY STORAGE  

E-Print Network [OSTI]

aquifers for thermal energy storage. Problems outlined aboveModeling of Thermal Energy Storage in Aquifers," Proceed-ings of Aquifer Thermal Energy Storage Workshop, Lawrence

Tsang, C.-F.

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "methanol ocean thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

AQUIFER THERMAL ENERGY STORAGE  

E-Print Network [OSTI]

using aquifers for thermal energy storage. Problems outlinedmatical Modeling of Thermal Energy Storage in Aquifers,"Proceed- ings of Aquifer Thermal Energy Storage Workshop,

Tsang, C.-F.

2011-01-01T23:59:59.000Z

362

In-situ characterization of adsorbed species on methanol synthesis catalysts by FT-IR spectroscopy  

SciTech Connect (OSTI)

Transmission infrared spectroscopy was used to characterize adsorbed species on methanol synthesis catalysts during reaction conditions. A copper carbonyl, bidentate formate, and methoxy species were identified as stable surface groups. An adsorbed formaldehyde species was unstable at the reaction temperature, but could be observed on the catalyst surface at the beginning of the reaction. Surface species were very similar for feed mixtures of 1) carbon monoxide and hydrogen, 2) carbon monoxide, carbon dioxide, and hydrogen, and 3) formic acid and hydrogen. The role of copper in methanol synthesis catalysts was to increase the adsorption of carbon monoxide to form a linear carbonyl species. This carbonly promoted the hydrogenation of formate groups. The formate species was adsorbed on a zinc site (Zn/sub ..beta../) different from the zinc site (Zn/sub ..gamma../) on which formaldehyde and methoxy groups were adsorbed. The rate-determining step in methanol synthesis was determined to be the reaction of hydrogen from a hydroxyl species adsorbed on another zinc site (Zn/sub ..cap alpha../) with a methoxy group to yield methanol. It was established that at the experimental conditions used in this study, the methanol synthesis reaction was far from equilibrium while the water-gas shift reaction was near equilibrium.

Edwards, J.F.

1984-01-01T23:59:59.000Z

363

In situ characterization of adsorbed species on methanol synthesis catalysts by FT-IR spectroscopy  

SciTech Connect (OSTI)

Transmission infrared spectroscopy was used to characterize adsorbed species on methanol synthesis catalysts during reaction conditions. A copper carbonyl, bidentate formate, and methoxy species were identified as stable surface groups. An adsorbed formaldehyde species was unstable at the reaction temperature, but could be observed on the catalyst surface at the beginning of the reaction. Surface species were very similar for feed mixtures of (1) carbon monoxide and hydrogen, (2) carbon monoxide, carbon dioxide, and hydrogen, and (3) formic acid and hydrogen. The role of copper in methanol synthesis catalysts was to increase the adsorption of carbon monoxide to form a linear carbonyl species. This carbonyl promoted the hydrogenation of formate groups. The formate species was adsorbed on a zinc site (Zn/sub ..beta../) different from the zinc site (Zn/sub ..gamma../) on which formaldehyde and methoxy groups were adsorbed. The rate-determining step in methanol synthesis was determined to be the reaction of hydrogen from a hydroxyl species adsorbed on another zinc site (Zn/sub ..cap alpha../) with a methoxy group to yield methanol. It was established that at the experimental conditions used in this study, the methanol synthesis reaction was far from equilibrium while the water-gas shift reaction was near equilibrium. 186 references, 83 figures, 28 tables.

Edwards, J.F.

1984-06-01T23:59:59.000Z

364

Direct methanol fuel cells for transportation applications. Quarterly technical report, June 1996--September 1996  

SciTech Connect (OSTI)

The purpose of this research and development effort is to advance the performance and viability of direct methanol fuel cell technology for light-duty transportation applications. For fuel cells to be an attractive alternative to conventional automotive power plants, the fuel cell stack combined with the fuel processor and ancillary systems must be competitive in terms of both performance and costs. A major advantage for the direct methanol fuel cell is that a fuel processor is not required. A direct methanol fuel cell has the potential of satisfying the demanding requirements for transportation applications, such as rapid start-up and rapid refueling. The preliminary goals of this effort are: (1) 310 W/l, (2) 445 W/kg, and (3) potential manufacturing costs of $48/kW. In the twelve month period for phase 1, the following critical areas will be investigated: (1) an improved proton-exchange membrane that is more impermeable to methanol, (2) improved cathode catalysts, and (3) advanced anode catalysts. In addition, these components will be combined to form membrane-electrode assemblies (MEA`s) and evaluated in subscale tests. Finally a conceptual design and program plan will be developed for the construction of a 5 kW direct methanol stack in phase II of the program.

Fuller, T.F.; Kunz, H.R.; Moore, R.

1996-11-01T23:59:59.000Z

365

Microbial Community Changes in Response to Ethanol or Methanol Amendments for U(VI) Reduction  

SciTech Connect (OSTI)

Microbial community responses to ethanol, methanol and methanol + humics amendments in relationship to uranium bioremediation were studied in laboratory microcosm experiments using sediments and ground water from a uranium-contaminated site in Oak Ridge, Tennessee. Ethanol addition always resulted in uranium reduction at rate of 0.8-1.0 mol l-1 d-1 while methanol addition did so occasionally at rate 0.95 mol l-1 d-1. The type of carbon source added, the duration of incubation, and the sampling site influenced the bacterial community structure upon incubation. Analysis of 16S rRNA gene clone libraries indicated (1) bacterial communities found in ethanol- and methanol-amended samples with U(VI) reduction were similar due to presence of -Proteobacteria, and -Proteobacteria (members of the families Burkholderiaceae, Comamonadaceae, Oxalobacteraceae, and Rhodocyclaceae); (2) methanol-amended samples without U(VI) reduction exhibited the lowest diversity and the bacterial community contained 69.2-92.8% of the family Methylophilaceae; and (3) the addition of humics resulted in an increase of phylogenetic diversity of -Proteobacteria (Rodoferax, Polaromonas, Janthinobacterium, Methylophilales, unclassified) and Firmicutes (Desulfosporosinus, Clostridium).

Vishnivetskaya, Tatiana A [ORNL; Brandt, Craig C [ORNL; Madden, Andrew [University of Oklahoma, Norman; Drake, Meghan M [ORNL; Kostka, Joel [Florida State University; Akob, Denise M. [Florida State University; Kusel, Kirsten [Friedrich Schiller University Jena, Jena Germany; Palumbo, Anthony Vito [ORNL

2010-01-01T23:59:59.000Z

366

Application of the Kellogg reforming exchanger system to large scale methanol plants  

SciTech Connect (OSTI)

In a majority of existing methanol production facilities, synthesis gas is furnished typically by a tubular fired steam reformer which uses natural gas as a feedstock. When one considers all synthesis gas produced from both ammonia and methanol plants, well over 80% is produced in a conventional reforming furnace. Steam reforming in a conventional sense, however, requires a considerable investment in both capital equipment and on-going maintenance and further, the use of such a unit operation will require heat recovery in the form of steam which forces the hand of the designer with respect to machinery driver selection. The authors have investigated alternatives to the coinventional approach with a view towards developing a process for methanol production that would be hopefully less expensive to construct, easier to operate and more reliable over the course of long term operation. In this paper, the authors present an alternative methanol plant process based on Kellogg`s proprietary reforming exchanger system (KRES). The flowsheet presented herein is for a 1500 MTPD facility that will produce US Federal Grade AA + methanol and will be compared on an economic basis to a conventional plant with respect to investment requirements and expected energy efficiency.

Joshi, G.; Schneider, R.V. III [M.W. Kellogg Co., Houston, TX (United States)

1995-12-31T23:59:59.000Z

367

Mechanistic models of oceanic nitrogen fixation  

E-Print Network [OSTI]

Oceanic nitrogen fixation and biogeochemical interactions between the nitrogen, phosphorus and iron cycles have important implications for the control of primary production and carbon storage in the ocean. The biological ...

Monteiro, Fanny

2009-01-01T23:59:59.000Z

368

OCEAN DRILLING PROGRAM LEG 207 SCIENTIFIC PROSPECTUS  

E-Print Network [OSTI]

3E3 Canada -------------------------------- Dr. Jack Bauldauf Deputy Director of Science Operations the international Ocean Drilling Program, which is managed by Joint Oceanographic Institutions, Inc., under contract Foundation (United States) Natural Environment Research Council (United Kingdom) Ocean Research Institute

369

"What Controls the Structure and Stability of the Ocean Meridional Overturning Circulation: Implications for Abrupt Climate Change?"  

SciTech Connect (OSTI)

The central goal of this research project is to understand the properties of the ocean meridional overturning circulation (MOC) a topic critical for understanding climate variability and stability on a variety of timescales (from decadal to centennial and longer). Specifically, we have explored various factors that control the MOC stability and decadal variability in the Atlantic and the ocean thermal structure in general, including the possibility abrupt climate change. We have also continued efforts on improving the performance of coupled ocean-atmosphere GCMs.

Fedorov, Alexey [Yale University] [Yale University

2013-11-23T23:59:59.000Z

370

Oceanic nutrient and oxygen transports and bounds on export production during the World Ocean Circulation Experiment  

E-Print Network [OSTI]

of intense climate interest. A large fraction of the carbon fixed in the oceanic surface waters is recycledOceanic nutrient and oxygen transports and bounds on export production during the World Ocean are estimated from selected hydrographic sections from the World Ocean Circulation Experiment spanning the world

Wunsch, Carl

371

Pacific Ocean Contribution to the Asymmetry in Eastern Indian Ocean Variability CAROLINE C. UMMENHOFER*  

E-Print Network [OSTI]

Pacific Ocean Contribution to the Asymmetry in Eastern Indian Ocean Variability CAROLINE C is restricted to the Indian or Pacific Ocean only, support the interpretation of forcing mechanisms for large Indian Ocean atmospheric forcing versus remote influences from Pacific wind forcing: low events develop

Ummenhofer, Caroline C.

372

Ocean Sci., 5, 313327, 2009 www.ocean-sci.net/5/313/2009/  

E-Print Network [OSTI]

. The role of the penetration length scale of short- wave radiation into the surface ocean and its impact of the shortwave radiation hitting the ocean sur- face is absorbed and scattered at depths considerably shal- lowerOcean Sci., 5, 313­327, 2009 www.ocean-sci.net/5/313/2009/ © Author(s) 2009. This work

Gnanadesikan, Anand

373

AANNUALNNUAL RREPORTEPORT Integrated Ocean Drilling ProgramIntegrated Ocean Drilling Program  

E-Print Network [OSTI]

AANNUALNNUAL RREPORTEPORT Integrated Ocean Drilling ProgramIntegrated Ocean Drilling Program U ANNUAL REPORT #12;#12;Integrated Ocean Drilling Program United States Implementing Organization JOI T his Integrated Ocean Drilling Program (IODP)-U.S. Implementing Organization (USIO) Fiscal Year 2006

374

Constraining Oceanic dust deposition using surface 1 ocean dissolved Al 2  

E-Print Network [OSTI]

Constraining Oceanic dust deposition using surface 1 ocean dissolved Al 2 Qin Han, J. Keith Moore, Charles Zender, Chris Measures, David Hydes 3 Abstract 4 We use measurements of ocean surface dissolved Al and Deposition 6 (DEAD) model, to constrain dust deposition to the oceans. Our Al database contains 7 all

Zender, Charles

375

Oceanic processes associated with anomalous events in the Indian Ocean with relevance to 19971998  

E-Print Network [OSTI]

Oceanic processes associated with anomalous events in the Indian Ocean with relevance to 1997 Abstract. An anomalous climatic event occurred in the Indian Ocean (IO) region during 1997­1998, which 1997, warm SSTAs appeared in the western IO, and they peaked in February 1998. An ocean general

Wang, Yuqing

376

National Oceanic and Atmospheric Administration's (NOAA) Oceans and Human Health Initiative  

E-Print Network [OSTI]

. We receive many benefits from the oceans from seafood, recreation and transportation industriesNational Oceanic and Atmospheric Administration's (NOAA) Oceans and Human Health Initiative (OHHI) is taking a new look at how the health of our ocean impacts our own health and well- being, and in turn how

377

Oceans and ClimateOceans and Climate PeterPeter RhinesRhines 11  

E-Print Network [OSTI]

say, the ocean is a great thermometer/thermometer/halometerhalometer Levitus, Antonov, Boyer+ Stephens

378

Career Opportunity in Ocean Energy POSITION TITLE: Director of Renewable Ocean Energy Research Program  

E-Print Network [OSTI]

Career Opportunity in Ocean Energy POSITION TITLE: Director of Renewable Ocean Energy Research: The Coastal Studies Institute (CSI) is seeking a dynamic individual to lead its Renewable Ocean Energy Program for a multi-institutional and multi-disciplinary renewable ocean energy research program. The position

379

Ocean Sci., 3, 337344, 2007 www.ocean-sci.net/3/337/2007/  

E-Print Network [OSTI]

1/3 of the total tidal energy dissipation, in the ocean basins through "internal" waves breaking, eOcean Sci., 3, 337­344, 2007 www.ocean-sci.net/3/337/2007/ © Author(s) 2007. This work is licensed under a Creative Commons License. Ocean Science Unpredictability of internal M2 H. van Haren Netherlands

Boyer, Edmond

380

Ocean Sci., 3, 461482, 2007 www.ocean-sci.net/3/461/2007/  

E-Print Network [OSTI]

Ocean Sci., 3, 461­482, 2007 www.ocean-sci.net/3/461/2007/ © Author(s) 2007. This work is licensed under a Creative Commons License. Ocean Science Effects of mesoscale eddies on global ocean Environment Laboratories, International Atomic Energy Agency, Monaco *now at: Institute of Biogeochemistry

Paris-Sud XI, Université de

Note: This page contains sample records for the topic "methanol ocean thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Call title: "The ocean of tomorrow" Call identifier: FP7-OCEAN-2010  

E-Print Network [OSTI]

challenges in ocean management Theme 5 ­ Energy Area ENERGY.10.1 Call "The ocean of tomorrow" ­ Joining1 Call title: "The ocean of tomorrow" · Call identifier: FP7-OCEAN-2010 · Date of publication: 30, and Biotechnology (KBBE) - EUR 6 million from Theme 5 ­ Energy - EUR 10.5 million from Theme 6 ­ Environment

Milano-Bicocca, Università

382

The effect of ocean mixed layer depth on climate in slab ocean aquaplanet experiments  

E-Print Network [OSTI]

a severely reduced (&50 %) meridi- onal energy transport relative to the deep ocean runs. As a resultThe effect of ocean mixed layer depth on climate in slab ocean aquaplanet experiments Aaron Donohoe online: 28 June 2013 ? Springer-Verlag Berlin Heidelberg 2013 Abstract The effect of ocean mixed layer

Battisti, David

383

OCEAN DRILLING PROGRAM LEG 205 SCIENTIFIC PROSPECTUS  

E-Print Network [OSTI]

OCEAN DRILLING PROGRAM LEG 205 SCIENTIFIC PROSPECTUS FLUID FLOW AND SUBDUCTION FLUXES ACROSS __________________ Dr. Jack Baldauf Deputy Director of Science Operations Ocean Drilling Program Texas A&M University Manager and Staff Scientist Ocean Drilling Program Texas A&M University 1000 Discovery Drive College

384

OCEAN DRILLING PROGRAM LEG 202 SCIENTIFIC PROSPECTUS  

E-Print Network [OSTI]

OCEAN DRILLING PROGRAM LEG 202 SCIENTIFIC PROSPECTUS SOUTHEAST PACIFIC PALEOCEANOGRAPHIC TRANSECTS __________________ Dr. Jack Baldauf Deputy Director of Science Operations Ocean Drilling Program Texas A&M University Manager and Staff Scientist Ocean Drilling Program Texas A&M University 1000 Discovery Drive College

385

OCEAN DRILLING PROGRAM LEG 195 SCIENTIFIC PROSPECTUS  

E-Print Network [OSTI]

OCEAN DRILLING PROGRAM LEG 195 SCIENTIFIC PROSPECTUS MARIANA CONVERGENT MARGIN/ WEST PHILIPPINE SEA Baldauf Deputy Director of Science Operations Ocean Drilling Program Texas A&M University 1000 Discovery and Staff Scientist Ocean Drilling Program Texas A&M University 1000 Discovery Drive College Station TX

386

OCEAN DRILLING PROGRAM LEG 185 SCIENTIFIC PROSPECTUS  

E-Print Network [OSTI]

OCEAN DRILLING PROGRAM LEG 185 SCIENTIFIC PROSPECTUS IZU-MARIANA MARGIN Dr. Terry Plank Co France Dr. Carlota Escutia Staff Scientist Ocean Drilling Program Texas A&M University Research Park 1000 the written consent of the Director, Ocean Drilling Program, Texas A&M University Research Park, 1000

387

OCEAN DRILLING PROGRAM LEG 100 SCIENTIFIC PROSPECTUS  

E-Print Network [OSTI]

OCEAN DRILLING PROGRAM LEG 100 SCIENTIFIC PROSPECTUS SHAKEDOWN AND SEA TRIALS CRUISE Philip D. Rabinowitz Co-Chief Scientist, Leg 100 Ocean Drilling Program Texas A&M University College Station, TX 77843 William J. Merrell Co-Chief Scientist, Leg 100 Ocean Drilling Program Texas A&M University College Station

388

SHIPBOARD SCIENTISTS1 OCEAN DRILLING PROGRAM  

E-Print Network [OSTI]

SHIPBOARD SCIENTISTS1 HANDBOOK OCEAN DRILLING PROGRAM TEXAS A&M UNIVERSITY TECHNICAL NOTE 3 portion requires the written consent of the Director, Ocean Drilling Program, Texas A&M University be obtained from the Director, Ocean Drilling Program, Texas A & M University Research Park, 1000 Discovery

389

OCEAN DRILLING PROGRAM LEG 100 REPORT  

E-Print Network [OSTI]

OCEAN DRILLING PROGRAM LEG 100 REPORT NORTHEASTERN GULF OF MEXICO Philip D Rabinowitz Co-Chief Scientist, Leg 100 Ocean Drilling Program Texas A&M University College Station, TX 77843 William J. Merrell Co-Chief Scientist, Leg 100 Ocean Drilling Program Texas A&M University College Station, TX 77843

390

OCEAN DRILLING PROGRAM LEG 200 SCIENTIFIC PROSPECTUS  

E-Print Network [OSTI]

OCEAN DRILLING PROGRAM LEG 200 SCIENTIFIC PROSPECTUS DRILLING AT THE H2O LONG-TERM SEAFLOOR Director of Science Operations Ocean Drilling Program Texas A&M University 1000 Discovery Drive College Ocean Drilling Program Texas A&M University 1000 Discovery Drive College Station TX 77845-9547 USA

391

OCEAN DRILLING PROGRAM LEG 159 SCIENTIFIC PROSPECTUS  

E-Print Network [OSTI]

OCEAN DRILLING PROGRAM LEG 159 SCIENTIFIC PROSPECTUS THE COTE D'IVOIRE - GHANA TRANSFORM MARGIN, Leg 159 Ocean Drilling Program Texas A&M University Research Park 1000 Discovery Drive College Station requires the written consent of the Director, Ocean Drilling Program, Texas A&M University Research Park

392

OCEAN DRILLING PROGRAM LEG 140 PRELIMINARY REPORT  

E-Print Network [OSTI]

OCEAN DRILLING PROGRAM LEG 140 PRELIMINARY REPORT HOLE 504B Dr. Henry Dick Dr. Jörg Erzinger Co Giessen Federal Republic of Germany Dr. Laura Stokking Staff Scientist, Leg 140 Ocean Drilling Program Copies of this publication may be obtained from the Director, Ocean Drilling Program, Texas A

393

OCEAN DRILLING PROGRAM LEG 199 SCIENTIFIC PROSPECTUS  

E-Print Network [OSTI]

OCEAN DRILLING PROGRAM LEG 199 SCIENTIFIC PROSPECTUS PALEOGENE EQUATORIAL TRANSECT Dr. Mitchell __________________ Dr. Jack Baldauf Deputy Director of Science Operations Ocean Drilling Program Texas A&M University Project Manager and Staff Scientist Ocean Drilling Program Texas A&M University 1000 Discovery Drive

394

OCEAN DRILLING PROGRAM LEG 196 SCIENTIFIC PROSPECTUS  

E-Print Network [OSTI]

OCEAN DRILLING PROGRAM LEG 196 SCIENTIFIC PROSPECTUS LOGGING WHILE DRILLING AND ADVANCED CORKS Deputy Director of Science Operations Ocean Drilling Program Texas A&M University 1000 Discovery Drive Scientist Ocean Drilling Program Texas A&M University 1000 Discovery Drive College Station TX 77845-9547 USA

395

OCEAN DRILLING PROGRAM LEG 105 SCIENTIFIC PROSPECTUS  

E-Print Network [OSTI]

OCEAN DRILLING PROGRAM LEG 105 SCIENTIFIC PROSPECTUS LABRADOR SEA - BAFFIN BAY Dr. Michael A. Bradford Clement Staff Science Representative, Leg 105 Ocean Drilling Program Texas A & M University College Station, TX 77843-3469" Philip Director Ocean Drilling Program Robert B. Kidd Manager of Science

396

OCEAN DRILLING PROGRAM LEG 108 SCIENTIFIC PROSPECTUS  

E-Print Network [OSTI]

OCEAN DRILLING PROGRAM LEG 108 SCIENTIFIC PROSPECTUS NORTHWEST AFRICA Dr. William Ruddiman Co Federal Republic of Germany Dr. Jack G. Baldauf Staff Scientist, Leg 108 Ocean Drilling Program Texas A & M University College Station, Texas 77843-3469 Philip W Rabin Direct Ocean Drilling Program

397

OCEAN DRILLING PROGRAM LEG 118 SCIENTIFIC PROSPECTUS  

E-Print Network [OSTI]

OCEAN DRILLING PROGRAM LEG 118 SCIENTIFIC PROSPECTUS FRACTURE ZONE DRILLING ON THE SOUTHWEST INDIAN Oceanographic Institution Woods Hole, MA 02543 Andrew C. Adamson Staff Scientist, Leg 118 Ocean Drilling Program the written consent of the Director, Ocean Drilling Program, Texas A&M University Research Park, 1000

398

Ocean Optics Environmental Optics, Nanoscience Division  

E-Print Network [OSTI]

suspended solids swept up from the floor of the Gulf of Mexico The right picture shows a phytoplankton bloom and changes observed. This can be used to monitor pollution in our oceans and methods taken when levels become such as ocean pollution, currents and warming, and to see how the oceans are affecting the health of our planet

Strathclyde, University of

399

www.hboi.fau.edu Ocean Energy  

E-Print Network [OSTI]

www.hboi.fau.edu Ocean Energy Collaboration: A Charge for Engineers BULLETIN Summer 2012 Beginning the State of Florida provided $5 million to establish the Center for Ocean Energy Technology at FAU. In 2010 to ocean energy research; the others are in Hawaii and the Pacific Northwest. Bill Baxley is the SNMREC

Fernandez, Eduardo

400

Kinetic and thermodynamic study of the liquid-phase etherification of isoamylenes with methanol  

SciTech Connect (OSTI)

The kinetics and thermodynamics of liquid-phase etherification of isoamylenes with methanol on ion exchange catalyst (Amberlyst 15) were studied. Thermodynamic properties and rate data were obtained in a batch reactor operating under 1,013 kPa and 323--353 K. The kinetic equation was modeled following the Langmuir-Hinshelwood-Hougen-Watson formalism according to a proposed surface mechanism where the rate-controlling step is the surface reaction. According to the experimental results, methanol adsorbs very strongly on the active sites, covering them completely, and thus the reaction follows an apparent first-order behavior. The isoamylenes, according to the proposed mechanism, adsorb simultaneously on the same single active center already occupied by methanol, migrating through the liquid layer formed by the alcohol around the catalyst to react in the acidic site. From the proposed mechanism a model was suggested and the kinetic and thermodynamic parameters were obtained using nonlinear estimation methods.

Piccoli, R.L. (Copesul-Cia Petroquimica do Sul, Triunfo (Brazil)); Lovisi, H.R. (Petroflex-Ind. e Comercio, Duque de Caxias (Brazil))

1995-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "methanol ocean thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Process for the conversion of carbonaceous feedstocks to particulate carbon and methanol  

DOE Patents [OSTI]

A process is described for the production of a pollutant-free particulate carbon (i.e., a substantially ash-, sulfur- and nitrogen-free carbon) from carbonaceous feedstocks. The basic process involves de-oxygenating one of the gas streams formed in a cyclic hydropyrolysis-methane pyrolysis process in order to improve conversion of the initial carbonaceous feedstock. De-oxygenation is effected by catalytically converting carbon monoxide, carbon dioxide, and hydrogen contained in one of the pyrolysis gas streams, preferably the latter, to a methanol co-product. There are thus produced two products whose use is known per se, viz., a substantially pollutant-free particulate carbon black and methanol. These products may be admixed in the form of a liquid slurry of carbon black in methanol. 3 figs.

Steinberg, M.; Grohse, E.W.

1995-06-27T23:59:59.000Z

402

Process for the conversion of carbonaceous feedstocks to particulate carbon and methanol  

DOE Patents [OSTI]

A process for the production of a pollutant-free particulate carbon (i.e., a substantially ash-, sulfur- and nitrogen-free carbon) from carbonaceous feedstocks. The basic process involves de-oxygenating one of the gas streams formed in a cyclic hydropyrolysis-methane pyrolysis process in order to improve conversion of the initial carbonaceous feedstock. De-oxygenation is effected by catalytically converting carbon monoxide, carbon dioxide, and hydrogen contained in one of the pyrolysis gas streams, preferably the latter, to a methanol co-product. There are thus produced two products whose use is known per se, viz., a substantially pollutant-free particulate carbon black and methanol. These products may be admixed in the form of a liquid slurry of carbon black in methanol.

Steinberg, Meyer (Melville, NY); Grohse, Edward W. (Port Jefferson, NY)

1995-01-01T23:59:59.000Z

403

Vapor-liquid equilibria for the system benzene-thiophene-methanol  

SciTech Connect (OSTI)

Isothermal vapor pressure data over the whole range of composition were obtained for the system benzene-thiophene-methanol. Data were taken at temperatures of 35, 40, and 45 /sup 0/C by using a static equilibrium cell. The systems benzene-methanol and thiophene-methanol are highly nonideal, while the system benzene-thiophene shows a very small deviation from ideality. The models suggested by Wilson and by Renon and Prausnitz (NRTL) and the modified equation of Abrams and Prausnitz (UNIQUAC) were used in the reduction of data. Physical parameters of these equations obtained from the binary data were used to predict the ternary system. The Wilson equation gives the best fit for the binary as well as the ternary data. Also, this equation gives the best prediction for the ternary system.

Triday, J.O.; Rodriguez, P.

1985-01-01T23:59:59.000Z

404

HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL  

SciTech Connect (OSTI)

Hydrogen can be produced from many feed stocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the second report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of January 1--March 31, 2004. This quarter saw progress in five areas. These areas are: (1) Internal and external evaluations of coal based methanol and the fuel cell grade baseline fuel; (2) Experimental investigations of heat and mass transfer enhancement methods by flow field manipulation; (3) Design and set up of the autothermal reactor; (4) Steam reformation of Coal Based Methanol; and (5) Initial catalyst degradation studies. All of the projects are proceeding on or slightly ahead of schedule.

Paul A. Erickson

2004-04-01T23:59:59.000Z

405

Kinetics of liquid phase catalytic dehydration of methanol to dimethyl ether  

SciTech Connect (OSTI)

This paper reports the kinetics of the liquid phase catalytic dehydration of methanol to dimethyl ether investigated. The experiments were carried out under low concentrations of feed in a 1-L stirred autoclave, according to a statistical experimental design. The inert liquid phase used for this investigation was a 78:22 blend of paraffinic and naphthenic mineral oils. A complete thermodynamic analysis was carried out in order to determine the liquid phase concentrations of the dissolved species. A global kinetic model was developed for the rate of dimethyl ether synthesis in terms of the liquid phase concentration of methanol. The activation energy of the reaction was found to be 18,830 cal/gmol. Based on a step-wise linear regression analysis of the kinetic data, the order of the reaction which gave the best fit was 0.28 with respect to methanol.

Gogate, M.R.; Lee, B.G.; Lee, S. (Akron Univ., OH (USA). Dept. of Chemical Engineering); Kulik, C.J. (Electric Power Research Inst., Palo Alto, CA (USA))

1990-01-01T23:59:59.000Z

406

Behaviour and thermal experience of adult sockeye salmon migrating through stratified  

E-Print Network [OSTI]

entirely by endogenous energy reserves as individuals cease feeding before leaving the ocean en routeBehaviour and thermal experience of adult sockeye salmon migrating through stratified lakes near water temperatures by utilising thermal refugia in cool-water tributaries (Berman & Quinn 1991; Goniea

Cooke, Steven J.

407

WIDESPREAD METHANOL EMISSION FROM THE GALACTIC CENTER: THE ROLE OF COSMIC RAYS  

SciTech Connect (OSTI)

We report the discovery of a widespread population of collisionally excited methanol J = 4{sub -1} to 3{sub 0} E sources at 36.2 GHz from the inner 66' Multiplication-Sign 18' (160 Multiplication-Sign 43 pc) of the Galactic center. This spectral feature was imaged with a spectral resolution of 16.6 km s{sup -1} taken from 41 channels of a Very Large Array continuum survey of the Galactic center region. The revelation of 356 methanol sources, most of which are maser candidates, suggests a large abundance of methanol in the gas phase in the Galactic center region. There is also spatial and kinematic correlation between SiO (2-1) and CH{sub 3}OH emission from four Galactic center clouds: the +50 and +20 km s{sup -1} clouds and G0.13-0.13 and G0.25 + 0.01. The enhanced abundance of methanol is accounted for in terms of induced photodesorption by cosmic rays as they travel through a molecular core, collide, dissociate, ionize, and excite Lyman Werner transitions of H{sub 2}. A time-dependent chemical model in which cosmic rays drive the chemistry of the gas predicts CH{sub 3}OH abundance of 10{sup -8} to 10{sup -7} on a chemical timescale of 5 Multiplication-Sign 10{sup 4} to 5 Multiplication-Sign 10{sup 5} years. The average methanol abundance produced by the release of methanol from grain surfaces is consistent with the available data.

Yusef-Zadeh, F.; Royster, M. [Department of Physics and Astronomy and Center for Interdisciplinary Exploration and Research in Astrophysics (CIERA), Northwestern University, Evanston, IL 60208 (United States); Cotton, W. [National Radio Astronomy Observatory, Charlottesville, VA 22903 (United States); Viti, S. [Department of Physics and Astronomy, University College London, Gower St. London, WCIE 6BT (United Kingdom); Wardle, M. [Department of Physics and Astronomy, Macquarie University, Sydney NSW 2109 (Australia)

2013-02-20T23:59:59.000Z

408

(Non) formation of methanol by direct hydrogenation of formate on copper catalysts  

SciTech Connect (OSTI)

We have attempted to hydrogenate adsorbed formate species on copper catalysts to probe the importance of this postulated mechanistic step in methanol synthesis. Surface formate coverages up to 0.25 were produced at temperatures between 413K and 453K on supported (Cu/SiO2) copper and unsupported copper catalysts. The adlayers were produced by various methods including (1) steady state catalytic conditions in CO2-H2 (3:1, 6 bar) atmospheres, and (2) by exposure of the catalysts to formic acid. As reported in earlier work, the catalytic surface at steady state contains bidentate formate species with coverages up to saturation levels of ~ 0.25 at the low temperatures of this study. The reactivity of these formate adlayers was investigated at relevant reaction temperatures in atmospheres containing up to 6 bar H2 partial pressure by simultaneous mass spectrometry (MS) and infrared (IR) spectroscopy measurements. The yield of methanol during the attempted hydrogenation (titration) of these adlayers was insignificant (<0.2 mol % of the formate adlayer) even in dry hydrogen partial pressures up to 6 bar. Hydrogen titration of formate species produced from formic acid also failed to produce significant quantities of methanol, and attempted titration in gases consisting of CO-hydrogen mixtures or dry CO2 were also unproductive. The formate decomposition kinetics, measured by IR, were also unaffected by these changes in the gas composition. Similar experiments on unsupported copper also failed to show any methanol. From these results, we conclude that methanol synthesis on copper cannot result from the direct hydrogenation of (bidentate) formate species in simple steps involving adsorbed H species alone. Furthermore, experiments performed on both supported (Cu/SiO2) and unsupported copper catalysts gave similar results implying that the methanol synthesis reaction mechanism only involves metal surface chemistry. Pre-exposure of the bidentate formate adlayer to oxidation by O2 or N2O produces a change to a monodentate configuration. Attempted titration of this monodentate formate/O coadsorbed layer in dry hydrogen produces significant quantities of methanol, although decomposition of formate to carbon dioxide and hydrogen remains the dominant reaction pathway. Simultaneous production of water is also observed during this titration as the copper surface is re-reduced. These results indicate that co-adsorbates related to surface oxygen or water-derived species may be critical to methanol production on copper, perhaps assisting in the hydrogenation of adsorbed formate to adsorbed methoxyl.

Yang, Yong; Mims, Charles A.; Disselkamp, Robert S.; Kwak, Ja Hun; Peden, Charles HF; Campbell, C. T.

2010-10-14T23:59:59.000Z

409

HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL  

SciTech Connect (OSTI)

Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the sixth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of January 1-March 31, 2005. This quarter saw progress in four areas. These areas are: (1) Autothermal reforming of coal derived methanol, (2) Catalyst deactivation, (3) Steam reformer transient response, and (4) Catalyst degradation with bluff bodies. All of the projects are proceeding on or slightly ahead of schedule.

Paul A. Erickson

2005-04-01T23:59:59.000Z

410

Conversion of synthesis gas and methanol to hydrocarbons using zeolite catalysts  

E-Print Network [OSTI]

of methanol to hydrocarbons: 2CHsOH ~ (CH, ), O ~ C, -C, Olefinsr paraf f ins aromatics (2l coke This pathway and stoichiometry illustrates that conversion of methanol will yield a maximum of 43. 75 % by weight hydrocarbons and 56. 25% water. Langner... is readily calculated. CO + 2Ht ? + CHsOH /)G tppx = 12. 1 kcal/mol (3) With a feed ratio of 2/1 Hz/CO, the equilibrium CO conversion at 573K and 1, 500 psi is 46. 1%. Commercially, the conversions are much less than equilibrium. It would be desirable...

Matthews, Michael Anthony

2012-06-07T23:59:59.000Z

411

The role of specific solvent modes in the non-radiative relaxation of an excess electron in methanol  

E-Print Network [OSTI]

in methanol A.A. Mosyak, O.V. Prezhdo1 , P.J. Rossky* Department of Chemistry and Biochemistry, University electronic excited state of an excess electron in methanol. Compared to water, we find that the presence volume combine to produce a three-fold decrease in the magnitude of the non- adiabatic coupling

412

Design and Control of High Temperature PEM Fuel Cell Systems using Methanol Reformers with Air or Liquid Heat Integration  

E-Print Network [OSTI]

Design and Control of High Temperature PEM Fuel Cell Systems using Methanol Reformers with Air PEM fuel cell systems fuelled by steam reformed methanol. Various fuel cell system solutions exist, they mainly differ depending on the desired fuel used. High temperature PEM (HTPEM) fuel cells offer

Berning, Torsten

413

Droplet Dynamics Changes in Electrostatic Sprays of Methanol-Water Mixtures Zohra Olumee, John H. Callahan, and Akos Vertes*,  

E-Print Network [OSTI]

conductivity, dielectric constant, surface tension, viscosity, and density) and on the spraying conditionsDroplet Dynamics Changes in Electrostatic Sprays of Methanol-Water Mixtures Zohra Olumee, John H generated from methanol-water mixtures. We investigated spraying conditions close to those of electrospray

Vertes, Akos

414

Catalytic conversion of methanol to low molecular weight olefins in a fluidized bed reactor  

E-Print Network [OSTI]

followed by a polimerization of the divalent carbenoid species to explain the olefinic formation. H-CH, -OH -----~ HaO + :CHa n:CH, -----~ (CH, )n n=2, 3, 4, 5 Swabb and Gates (1972), in their study of the dehydration of methanol over H...

Garza Tobias, Ricardo

1983-01-01T23:59:59.000Z

415

Three-Dimensional Simulations of Liquid Feed Direct Methanol Wenpeng Liu*,a  

E-Print Network [OSTI]

by electrochemical kinetics and methanol crossover but also by water transport and by their complex interactions are not repeated here. In order to compete with lithium-ion batteries, a portable DMFC system must overcome several, and optimiza- tion of various interactive transport and electrochemical processes that occur in portable DMFCs

416

The nature and formation of coke in the reaction of methanol to hydrocarbons over chabazite  

E-Print Network [OSTI]

). Reactant: methanol t-butanol 1-heotanol Reaction conditions Temp. (K) LHSV (hr ) 644 1. 0 644 1. 0 644 0. 7 Conversion (g) 1 00 100 99. 9 Hydrocarbon distribution (wt g) methane ethane ethylene propane propylene i-butane n-butane bu...

McLaughlin, Kenneth Woot

1983-01-01T23:59:59.000Z

417

Author's personal copy Methanol oxidation in nanostructured platinum/cerium-phosphate thin films  

E-Print Network [OSTI]

rights reserved. 1. Introduction Direct methanol fuel cells (DMFCs) have been considered to be one chosen metals in low-temperature fuel cells. However, it is hard to avoid CO adsorption on a bare Pt and optimize several types of catalysts [1]. Pure platinum as an anode catalyst is one of the most frequently

Park, Byungwoo

418

Gasoline from Wood via Integrated Gasification, Synthesis, and Methanol-to-Gasoline Technologies  

SciTech Connect (OSTI)

This report documents the National Renewable Energy Laboratory's (NREL's) assessment of the feasibility of making gasoline via the methanol-to-gasoline route using syngas from a 2,000 dry metric tonne/day (2,205 U.S. ton/day) biomass-fed facility. A new technoeconomic model was developed in Aspen Plus for this study, based on the model developed for NREL's thermochemical ethanol design report (Phillips et al. 2007). The necessary process changes were incorporated into a biomass-to-gasoline model using a methanol synthesis operation followed by conversion, upgrading, and finishing to gasoline. Using a methodology similar to that used in previous NREL design reports and a feedstock cost of $50.70/dry ton ($55.89/dry metric tonne), the estimated plant gate price is $16.60/MMBtu ($15.73/GJ) (U.S. $2007) for gasoline and liquefied petroleum gas (LPG) produced from biomass via gasification of wood, methanol synthesis, and the methanol-to-gasoline process. The corresponding unit prices for gasoline and LPG are $1.95/gallon ($0.52/liter) and $1.53/gallon ($0.40/liter) with yields of 55.1 and 9.3 gallons per U.S. ton of dry biomass (229.9 and 38.8 liters per metric tonne of dry biomass), respectively.

Phillips, S. D.; Tarud, J. K.; Biddy, M. J.; Dutta, A.

2011-01-01T23:59:59.000Z

419

Thermal conductivity of thermal-battery insulations  

SciTech Connect (OSTI)

The thermal conductivities of a variety of insulating materials used in thermal batteries were measured in atmospheres of argon and helium using several techniques. (Helium was used to simulate the hydrogen atmosphere that results when a Li(Si)/FeS{sub 2} thermal battery ages.) The guarded-hot-plate method was used with the Min-K insulation because of its extremely low thermal conductivity. For comparison purposes, the thermal conductivity of the Min-K insulating board was also measured using the hot-probe method. The thermal-comparator method was used for the rigid Fiberfrax board and Fiberfrax paper. The thermal conductivity of the paper was measured under several levels of compression to simulate the conditions of the insulating wrap used on the stack in a thermal battery. The results of preliminary thermal-characterization tests with several silica aerogel materials are also presented.

Guidotti, R.A.; Moss, M.

1995-08-01T23:59:59.000Z

420

Methanol vaporization and injection system for internal combustion engine  

SciTech Connect (OSTI)

An engine equipped with an alcohol vaporization injection system operates as a four stroke cycle diesel engine that transfers the heat of exiting exhaust gases and cylinder head walls to the fuel. The engine runs on alcohol. The alcohol becomes vaporized and its pressure is high enough so that when a valve is opened between the high pressure fuel line and the combustion chamber (when it is at the peak of its compression ratio) enough alcohol will enter the combustion chamber to allow proper combustion. The overall advantages to this type of alcohol vaporization injection system is that it adds relatively few new mechanisms to the spark ignition four cycle internal combustion engine to enable it to operate as a diesel engine with a high thermal efficiency. This alcohol injection system exploits the engine's need for greater volumes of alcohol caused by the alcohol's relatively low heat of combustion (When compared to gasoline) by using this greater volume of fuel to return greater quantities of heat back to the engine to a much greater degree than other fuels can.

Bayley, R.I.

1980-05-06T23:59:59.000Z

Note: This page contains sample records for the topic "methanol ocean thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Impact of the Southern ocean winds on sea-ice - ocean interaction and its associated global ocean circulation in a warming world  

E-Print Network [OSTI]

This dissertation discusses a linkage between the Southern Ocean (SO) winds and the global ocean circulation in the framework of a coarse-resolution global ocean general circulation model coupled to a sea-ice model. In addition to reexamination...

Cheon, Woo Geunn

2009-05-15T23:59:59.000Z

422

A High-Yield, Liquid-Phase Approach for the Partial Oxidation of Methane to Methanol using SO3 as the Oxidant  

E-Print Network [OSTI]

approach for producing methanol from methane in a three-step, liquid phase process is reported is hydrolyzed in the presence of an organic solvent, to produce an organic phase con- taining methanol the facile separation of methanol. Con- centrated sulfuric acid is produced as a by-product, which can either

Bell, Alexis T.

423

High Temperature Thermal Array for Next Generation Solar Thermal...  

Broader source: Energy.gov (indexed) [DOE]

High Temperature Thermal Array for Next Generation Solar Thermal Power Production High Temperature Thermal Array for Next Generation Solar Thermal Power Production This...

424

On the World-wide Circulation of the Deeper Waters of the World Ocean  

E-Print Network [OSTI]

circulation of the Pacific Ocean: Flow patterns, tracers,in preparing the figures. Fig. 1 Pacific Ocean winds Fig.2 Pacific Ocean circulation Fig. 4 Pacific Ocean potential

Reid, Joseph L

2009-01-01T23:59:59.000Z

425

Horizontal stirring in the global ocean  

E-Print Network [OSTI]

Horizontal mixing and the distribution of coherent structures in the global ocean are analyzed using Finite-Size Lyapunov Exponents (FSLE), computed for the surface velocity field derived from the Ocean general circulation model For the Earth Simulator (OFES). FSLEs measure horizontal stirring and dispersion; additionally, the transport barriers which organize the oceanic flow can roughly be identified with the ridges of the FSLE field. We have performed a detailed statistical study, particularizing for the behaviour of the two hemispheres and different ocean basins. The computed Probability Distributions Functions (PDFs) of FSLE are broad and asymmetric. Horizontal mixing is generally more active in the northern hemisphere than in the southern one. Nevertheless the Southern Ocean is the most active ocean, and the Pacific the less active one. A striking result is that the main currents can be classified in two 'activity classes': Western Boundary Currents, which have broad PDFs with large FSLE values, and Eas...

Hernndez-Carrasco, I; Hernndez-Garca, E; Turiel, A

2011-01-01T23:59:59.000Z

426

Seasonal thermal energy storage  

SciTech Connect (OSTI)

This report describes the following: (1) the US Department of Energy Seasonal Thermal Energy Storage Program, (2) aquifer thermal energy storage technology, (3) alternative STES technology, (4) foreign studies in seasonal thermal energy storage, and (5) economic assessment.

Allen, R.D.; Kannberg, L.D.; Raymond, J.R.

1984-05-01T23:59:59.000Z

427

A Theoretical Study of Methanol Synthesis from CO(2) Hydrogenation on Metal-doped Cu(111) Surfaces  

SciTech Connect (OSTI)

Density functional theory (DFT) calculations and Kinetic Monte Carlo (KMC) simulations were employed to investigate the methanol synthesis reaction from CO{sub 2} hydrogenation (CO{sub 2} + 3H{sub 2} {yields} CH{sub 3}OH + H{sub 2}O) on metal-doped Cu(111) surfaces. Both the formate pathway and the reverse water-gas shift (RWGS) reaction followed by a CO hydrogenation pathway (RWGS + CO-Hydro) were considered in the study. Our calculations showed that the overall methanol yield increased in the sequence: Au/Cu(111) < Cu(111) < Pd/Cu(111) < Rh/Cu(111) < Pt/Cu(111) < Ni/Cu(111). On Au/Cu(111) and Cu(111), the formate pathway dominates the methanol production. Doping Au does not help the methanol synthesis on Cu(111). Pd, Rh, Pt, and Ni are able to promote the methanol production on Cu(111), where the conversion via the RWGS + CO-Hydro pathway is much faster than that via the formate pathway. Further kinetic analysis revealed that the methanol yield on Cu(111) was controlled by three factors: the dioxomethylene hydrogenation barrier, the CO binding energy, and the CO hydrogenation barrier. Accordingly, two possible descriptors are identified which can be used to describe the catalytic activity of Cu-based catalysts toward methanol synthesis. One is the activation barrier of dioxomethylene hydrogenation, and the other is the CO binding energy. An ideal Cu-based catalyst for the methanol synthesis via CO{sub 2} hydrogenation should be able to hydrogenate dioxomethylene easily and bond CO moderately, being strong enough to favor the desired CO hydrogenation rather than CO desorption but weak enough to prevent CO poisoning. In this way, the methanol production via both the formate and the RWGS + CO-Hydro pathways can be facilitated.

Liu P.; Yang, Y.; White, M.G.

2012-01-12T23:59:59.000Z

428

Introduction to the Ocean Drilling Program JOIDES RESOLUTION  

E-Print Network [OSTI]

Introduction to the Ocean Drilling Program JOIDES RESOLUTION OCEAN DRILLING PROGRAM TECHNICAL NOTE 11 1989 #12;TEXAS A&M UNIVERSITY #12;INTRODUCTION TO THE OCEAN DRILLING PROGRAM Ocean Drilling Program Texas A&M University Technical Note No. 11 Anne Gilbert Graham Ocean Drilling Program Texas A

429

2007 OCEAN DRILLING CITATION REPORT Covering Deep Sea Drilling Project-  

E-Print Network [OSTI]

2007 OCEAN DRILLING CITATION REPORT Covering Deep Sea Drilling Project- and Ocean Drilling Program Services on behalf of the Integrated Ocean Drilling Program September 2007 #12;#12;OVERVIEW OF THE OCEAN DRILLING CITATION DATABASE The Ocean Drilling Citation Database, which in February 2007 contained

430

Ocean Viral Metagenomics (2010 JGI User Meeting)  

ScienceCinema (OSTI)

Forest Rohwer from San Diego State University talks about "Ocean Viral Metagenomics" on March 25, 2010 at the 5th Annual DOE JGI User Meeting

Rohwer, Forest

2011-04-26T23:59:59.000Z

431

Hydropower and Ocean Energy Resources and Technologies  

Broader source: Energy.gov [DOE]

This page provides a brief overview of hydropower and ocean energy resources and technologies supplemented by specific information to apply these technologies within the Federal sector.

432

OceanObs 1999 G GRIFFITHS et al. OceanObs 99  

E-Print Network [OSTI]

, telecoms, defence, science, monitoring Hugin, Odyssey, OE X, R-One Robot, Martin, LDUUV, Autosub #12;Ocean

Griffiths, Gwyn

433

Thermal unobtainiums? The perfect thermal conductor and  

E-Print Network [OSTI]

contribute to thermal resistance · Isotopically pure diamond has highest thermal conductivity of any material materials: disordered layered crystals Conclude with some thoughts on promising, high-risk, research even in a computer model. #12;Thermal resistance is created by Umklapp scattering (U

Braun, Paul

434

COMMERCIAL-SCALE DEMONSTRATION OF THE LIQUID PHASE METHANOL (LPMEOH) PROCESS  

SciTech Connect (OSTI)

This project, which was sponsored by the U.S. Department of Energy (DOE) under the Clean Coal Technology Program to demonstrate the production of methanol from coal-derived synthesis gas (syngas), has completed the 69-month operating phase of the program. The purpose of this Final Report for the ''Commercial-Scale Demonstration of the Liquid Phase Methanol (LPMEOH{trademark}) Process'' is to provide the public with details on the performance and economics of the technology. The LPMEOH{trademark} Demonstration Project was a $213.7 million cooperative agreement between the DOE and Air Products Liquid Phase Conversion Company, L.P. (the Partnership). The DOE's cost share was $92,708,370 with the remaining funds coming from the Partnership. The LPMEOH{trademark} demonstration unit is located at the Eastman Chemical Company (Eastman) chemicals-from-coal complex in Kingsport, Tennessee. The technology was the product of a cooperative development effort by Air Products and Chemicals, Inc. (Air Products) and DOE in a program that started in 1981. Developed to enhance electric power generation using integrated gasification combined cycle (IGCC) technology, the LPMEOH{trademark} Process is ideally suited for directly processing gases produced by modern coal gasifiers. Originally tested at the Alternative Fuels Development Unit (AFDU), a small, DOE-owned process development facility in LaPorte, Texas, the technology provides several improvements essential for the economic coproduction of methanol and electricity directly from gasified coal. This liquid phase process suspends fine catalyst particles in an inert liquid, forming a slurry. The slurry dissipates the heat of the chemical reaction away from the catalyst surface, protecting the catalyst, and allowing the methanol synthesis reaction to proceed at higher rates. The LPMEOH{trademark} Demonstration Project accomplished the objectives set out in the Cooperative Agreement with DOE for this Clean Coal Technology project. Overall plant availability (defined as the percentage of time that the LPMEOH{trademark} demonstration unit was able to operate, with the exclusion of scheduled outages) was 97.5%, and the longest operating run without interruption of any kind was 94 days. Over 103.9 million gallons of methanol was produced; Eastman accepted all of the available methanol for use in the production of methyl acetate, and ultimately cellulose acetate and acetic acid.

E.C. Heydorn; B.W. Diamond; R.D. Lilly

2003-06-01T23:59:59.000Z

435

Commercial-Scale Demonstration of the Liquid Phase Methanol (LPMEOTH) Process  

SciTech Connect (OSTI)

The Liquid Phase Methanol (LPMEOW) Demonstration Project at Kingsport, Tennessee, is a $213.7 million cooperative agreement between the U.S. Department of Energy (DOE) and Air Products Liquid Phase Conversion Company, L.P. (the Partnership) to produce methanol from coal-derived synthesis gas (syngas). Air Products and Chemicals, Inc. (Air Products) and Eastman Chemical Company (Eastman) formed the Partnership to execute the Demonstration Project. The LPMEOI-P Process Demonstration Unit was built at a site located at the Eastman coal-to-chemicals complex in Kingsport. During this quarter, initial planning and procurement work continued on the seven project sites which have been accepted for participation in the off-site, product-use test program. Approximately 12,000 gallons of fuel-grade methanol (98+ wt% methanol, 4 wt% water) produced during operation on carbon monoxide (CO)-rich syngas at the LPMEOW Demonstration Unit was loaded into trailers and shipped off-site for Mure product-use testing. At one of the projects, three buses have been tested on chemical-grade methanol and on fhel-grade methanol from the LPMEOW Demonstration Project. During the reporting period, planning for a proof-of-concept test run of the Liquid Phase Dimethyl Ether (LPDME~ Process at the Alternative Fuels Development Unit (AFDU) in LaPorte, TX continued. The commercial catalyst manufacturer (Calsicat) has prepared the first batch of dehydration catalyst in large-scale equipment. Air Products will test a sample of this material in the laboratory autoclave. Catalyst activity, as defined by the ratio of the rate constant at any point in time to the rate constant for freshly reduced catalyst (as determined in the laborato~ autoclave), was monitored for the initial extended operation at the lower initial reactor operating temperature of 235oC. At this condition, the decrease in catalyst activity with time from the period 20 December 1997 through 27 January 1998 occurred at a rate of 1.0% per day, which represented a significant improvement over the 3.4Yi per day decline measured during the initial six weeks of operation in April and May of 1997. The deactivation rate also improved from the longer-term rate of 1.6% per day calculated throughout the summer and autumn of 1997.

None

1998-12-21T23:59:59.000Z

436

Author's personal copy A novel ocean color index to detect oating algae in the global oceans  

E-Print Network [OSTI]

Author's personal copy A novel ocean color index to detect oating algae in the global oceans December 2008 Received in revised form 15 May 2009 Accepted 23 May 2009 Keywords: Floating Algae Index (FAI Remote sensing Ocean color Climate data record Various types of oating algae have been reported in open

Meyers, Steven D.

437

2006 Ocean Drilling Citation Report Overview of the Ocean Drilling Citation Database  

E-Print Network [OSTI]

2006 Ocean Drilling Citation Report Overview of the Ocean Drilling Citation Database The Ocean Drilling Citation Database, which contained almost 22,000 citation records related to the Deep Sea Drilling Institute (AGI). The database has been on line since August 2002. Beginning in 2006, citation records

438

Summer Courses in Ocean Optics and Biogeochemistry: "Monitoring the Oceans with Coastal Observatories" and  

E-Print Network [OSTI]

Summer Courses in Ocean Optics and Biogeochemistry: "Monitoring the Oceans with Coastal integration of optical approaches into oceanographic research in general. OBJECTIVES These two courses created and optical oceanography and ocean color remote sensing to learn the fundamentals of optics in a coastal

Boss, Emmanuel S.

439

Ocean Sci., 3, 299310, 2007 www.ocean-sci.net/3/299/2007/  

E-Print Network [OSTI]

and industrial fisheries, are experiencing a constant increase, significantly affecting the marine ecosystemOcean Sci., 3, 299­310, 2007 www.ocean-sci.net/3/299/2007/ © Author(s) 2007. This work is licensed under a Creative Commons License. Ocean Science Observing the Mediterranean Sea from space: 21 years

Boyer, Edmond

440

Research on Ocean Resources, Marine Geo-Engineering and Climate Change -New Regulations: Implications for Ocean  

E-Print Network [OSTI]

Research on Ocean Resources, Marine Geo-Engineering and Climate Change - New Regulations: Implications for Ocean Engineers Dr. Philomène Verlaan Visiting Colleague, Department of Oceanography & Senior Framework for Scientific Research Involving Ocean Fertilization", a definition of marine geo-engineering

Frandsen, Jannette B.

Note: This page contains sample records for the topic "methanol ocean thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

ARM - Lesson Plans: Ocean Currents  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc Documentation RUC : XDCResearch Related InformationAcid Rain OutreachMoving Water andOcean

442

Thermal Control & System Integration  

Broader source: Energy.gov [DOE]

The thermal control and system integration activity focuses on issues such as the integration of motor and power control technologies and the development of advanced thermal control technologies....

443

MAJOR STRUCTURES OF THE INNER GALAXY DELINEATED BY 6.7 GHz METHANOL MASERS  

SciTech Connect (OSTI)

We explore the longitude-velocity distribution of 6.7 GHz methanol masers in the context of the inner structure of our Galaxy. We analyze the correlation in velocities within this distribution and identify density enhancements indicating large-scale regions of enhanced star formation. These are interpreted as the starting points of the spiral arms and the interaction of the Galactic bar with the 3 kpc arms. The methanol masers support the presence of a long thin bar with a 45{sup 0} orientation. Signatures of the full 3 kpc arm structure are seen, including a prominent tangent at approximately -22{sup 0} Galactic longitude. We compare this distribution with existing models of the gas dynamics of our Galaxy. The 3 kpc arm structure appears likely to correspond to the radius of corotation resonance of the bar, with the bar on its inner surface and the starting points of the spiral arms on its outer surface.

Green, J. A.; Caswell, J. L.; McClure-Griffiths, N. M.; Breen, S. L.; Voronkov, M. A. [CSIRO Astronomy and Space Science, Australia Telescope National Facility, P.O. Box 76, Epping, NSW 1710 (Australia); Avison, A.; Fuller, G. A.; Gray, M. D. [Jodrell Bank Centre for Astrophysics, Alan Turing Building, University of Manchester, Manchester, M13 9PL (United Kingdom); Burton, M. G. [School of Physics, University of New South Wales, Sydney, NSW 2052 (Australia); Ellingsen, S. P. [School of Mathematics and Physics, University of Tasmania, Private Bag 37, Hobart, TAS 7001 (Australia); Pestalozzi, M. [INAF/IFSI, via del Fosso del Cabaliere 100, I-00133 Roma (Italy); Thompson, M. A. [Centre for Astrophysics Research, Science and Technology Research Institute, University of Hertfordshire, College Lane, Hatfield, AL10 9AB (United Kingdom)

2011-05-20T23:59:59.000Z

444

Theoretical model for methanol formation from CO and H/sub 2/ on zinc oxide surfaces  

SciTech Connect (OSTI)

Models are developed for the polar (0001) and nonpolar (1010) surfaces of ZnO in order to consider methanol formation from adsorbed carbon monoxide and hydrogen atoms. The heats of adsorption of H/sub x/CO and OH/sub x/CO (x = 0-3) species involved in methanol formation are computed to determine the enthalpy changes of reaction. Reaction sequences involving formyl or formate intermediates are considered. The reaction mechanism is catalyzed by the Cu/sup +/ to proceed through a methoxy intermediate on Cu/sup +//ZnO with a lower of the energy pathway. The ZnO surfaces are poor donors and function primarily as acceptors of electron density from CO. The donor role of Cu/sup +/ is demonstrated on the polar surface by increasing the heat of adsorption of acceptor adspecies and decreasing the heat of adsorption of donor adspecies. 22 references, 8 figures, 4 tables.

Baetzold, R.C.

1985-09-12T23:59:59.000Z

445

Mechanism of methanol synthesis from carbon monoxide and hydrogen on copper catalysts  

SciTech Connect (OSTI)

The authors examine possible mechanisms of methanol synthesis from carbon monoxide and hydrogen on supported copper catalysts. Two broad categories of reaction mechanism can be identified: (a) Type I: Carbon monoxide, adsorbed on the copper surface, is hydrogenated by the addition of hydrogen atoms while the C-O bond remains intact. A second C-O bond is neither formed nor broken. (b) Type II: Carbon monoxide (or a partially hydrogenated intermediate, e.g., HCO) reacts with an oxygen atom on the catalyst surface to give an intermediate, typically a formate, which contains two C-O bonds. Subsequent reaction leads overall to methanol and the reformation of the surface oxygen atom. Both mechanisms are discussed.

Fakley, M.E.; Jennings, J.R.; Spencer, M.S. (ICI Chemicals and Polymers Ltd, Billingham, Cleveland (England))

1989-08-01T23:59:59.000Z

446

HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL  

SciTech Connect (OSTI)

Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the ninth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of October 1, 2005-December 31, 2005. This quarter saw progress in four areas. These areas are: (1) reformate purification, (2) heat transfer enhancement, (3) autothermal reforming coal-derived methanol degradation test; and (4) model development for fuel cell system integration. The project is on schedule and is now shifting towards the design of an integrated PEM fuel cell system capable of using the coal-derived product. This system includes a membrane clean up unit and a commercially available PEM fuel cell.

Paul A. Erickson

2006-01-01T23:59:59.000Z

447

HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL  

SciTech Connect (OSTI)

Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the tenth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of January 1-March 31, 2006. This quarter saw progress in six areas. These areas are: (1) The effect of catalyst dimension on steam reforming, (2) Transient characteristics of autothermal reforming, (3) Rich and lean autothermal reformation startup, (4) Autothermal reformation degradation with coal derived methanol, (5) Reformate purification system, and (6) Fuel cell system integration. All of the projects are proceeding on or slightly ahead of schedule.

Paul A. Erickson

2006-04-01T23:59:59.000Z

448

Hydrogen Production for Fuel Cells Via Reforming Coal-Derived Methanol  

SciTech Connect (OSTI)

Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the seventh report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of April 1-June 31, 2005. This quarter saw progress in these areas. These areas are: (1) Steam reformer transient response, (2) Heat transfer enhancement, (3) Catalyst degradation, (4) Catalyst degradation with bluff bodies, and (5) Autothermal reforming of coal-derived methanol. All of the projects are proceeding on or slightly ahead of schedule.

Paul A. Erickson

2005-06-30T23:59:59.000Z

449

Effect of under-inhibition with methanol and ethylene glycol on the hydrate control process  

SciTech Connect (OSTI)

Hydrate control can be achieved by chemical injection. Currently, methanol and ethylene glycol are the most widely used inhibitors in offshore hydrate control operations. To achieve effective hydrate inhibition, a sufficient amount of inhibitor must be injected to shift the thermodynamic equilibrium condition for hydrate formation outside the pipeline operating pressure and temperature. Recently published field experiments showed that hydrate blockages form more readily in under-inhibited systems than in systems completely without inhibitor. A laboratory study is conducted to determine the effect of low concentration (1--5wt%) methanol and ethylene glycol on the hydrate formation process. The results show that, although these chemicals are effective hydrate inhibitors when added in sufficient quantities, they actually enhance the rate of hydrate formation when added at low concentrations to the water. Furthermore, the presence of these chemicals seems to affect the size of the forming hydrate particles.

Yousif, M.H.

1996-12-31T23:59:59.000Z

450

WABASH RIVER INTEGRATED METHANOL AND POWER PRODUCTION FROM CLEAN COAL TECHNOLOGIES (IMPPCCT)  

SciTech Connect (OSTI)

The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project is evaluating integrated electrical power generation and methanol production through clean coal technologies. The project is conducted by a multi-industry team lead by Gasification Engineering Corporation (GEC), a company of Global Energy Inc., and supported by Air Products and Chemicals, Inc., Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation. Three project phases are planned for execution over several years, including: (1) Feasibility study and conceptual design for an integrated demonstration facility, and for fence-line commercial embodiment plants (CEP) operated at Dow Chemical or Dow Corning chemical plant locations (2) Research, development, and testing to define any technology gaps or critical design and integration issues (3) Engineering design and financing plan to install an integrated commercial demonstration facility at the existing Wabash River Energy Limited (WREL) plant in West Terre Haute, Indiana.

Albert Tsang

2003-03-14T23:59:59.000Z

451

EVN observations of 6.7 GHz methanol masers from Medicina survey  

E-Print Network [OSTI]

We report VLBI observations of methanol masers in the brightest 5(1)-6(0) A+ transition at 6.7 GHz in NGC 281W, 18151-1208 and 19388+2357. Using the fringe rate method absolute positions were obtained for all observed sources. A linear ordered structure with a velocity gradient was revealed in NGC 281W. Under assumption that such structure is an edge-on Keplerian disk around the central object with a mass of 30Msun located at a distance of 3.5 kpc from the Sun, we estimated that methanol masers are situated at the distance about 400 a.u. from the center of the disk. A second epoch of observations was reported for L1206, GL2789 and 20062+3550. The upper limits on the relative motions of maser spots are estimated to be 4.7 km/s and 28 km/s for L1206 and GL2789 respectively.

Voronkov, M A; Palagi, F; Tofani, G

2002-01-01T23:59:59.000Z

452

EVN observations of 6.7 GHz methanol masers from Medicina survey  

E-Print Network [OSTI]

We report VLBI observations of methanol masers in the brightest 5(1)-6(0) A+ transition at 6.7 GHz in NGC 281W, 18151-1208 and 19388+2357. Using the fringe rate method absolute positions were obtained for all observed sources. A linear ordered structure with a velocity gradient was revealed in NGC 281W. Under assumption that such structure is an edge-on Keplerian disk around the central object with a mass of 30Msun located at a distance of 3.5 kpc from the Sun, we estimated that methanol masers are situated at the distance about 400 a.u. from the center of the disk. A second epoch of observations was reported for L1206, GL2789 and 20062+3550. The upper limits on the relative motions of maser spots are estimated to be 4.7 km/s and 28 km/s for L1206 and GL2789 respectively.

M. A. Voronkov; V. I. Slysh; F. Palagi; G. Tofani

2002-05-31T23:59:59.000Z

453

Biological and physical regulation of the oceanic fixed nitrogen reservoir  

E-Print Network [OSTI]

2 in the subtropical North Pacific Ocean. Nature 412: 635-38in the eastern tropical Pacific Ocean. Marine Chemistry 16:and N 2 fixation in the Pacific Ocean. Global Biogeochemical

Weber, Thomas Smith

2013-01-01T23:59:59.000Z

454

Seismic and Biological Sources of Ambient Ocean Sound /  

E-Print Network [OSTI]

the most efficient radiation in the ocean. Sounds of seismicmost efficient radiation in the ocean. Of any remote sensingRadiation of Sound The underwater world is never silent. Even a hydrophone placed in the ocean

Freeman, Simon Eric

2013-01-01T23:59:59.000Z

455

INTEGRATED OCEAN DRILLING PROGRAM United States Implementing Organization  

E-Print Network [OSTI]

INTEGRATED OCEAN DRILLING PROGRAM United States Implementing Organization JOI Alliance Joint _______________________________ Steven R. Bohlen President, Joint Oceanographic Institutions Executive Director, Ocean Drilling Programs of work for Integrated Ocean Drilling Program (IODP) activities and deliverables for the current fiscal

456

Oceanic alkyl nitrates as a natural source of tropospheric ozone  

E-Print Network [OSTI]

over the equatorial Pacific Ocean during Saga 3, J. Geophys.the troposphere over the Pacific Ocean during PEM- Tropics Ain the tropical Pacific Ocean, Geophys. Res. Lett. , 32,

Neu, Jessica L; Lawler, Michael J; Prather, Michael J; Saltzman, Eric S

2008-01-01T23:59:59.000Z

457

Jere Chase Ocean Engineering Lab, Durham, NH Directions & Parking  

E-Print Network [OSTI]

Jere Chase Ocean Engineering Lab, Durham, NH Directions & Parking Jere Chase Ocean Engineering Lab of the University of New Hampshire. Parking is available at the Jere A. Chase Ocean Engineering Building. Directions

458

Graduate Study and Research in Ocean and Resources Engineering  

E-Print Network [OSTI]

Guide to Graduate Study and Research in Ocean and Resources Engineering University of Hawaii REQUIREMENTS ............................................... 16 Ocean and Resources Engineering Page 3 #12;Page 4 Ocean and Resources Engineering BACKGROUND Hawaii's unique location, climate and marine

Frandsen, Jannette B.

459

ORE 601 Ocean and Resources Engineering Laboratory Designation  

E-Print Network [OSTI]

ORE 601 Ocean and Resources Engineering Laboratory Designation Core course Catalog Description This course aims to provide ocean and resources engineering students with the fundamentals necessary Program Outcome 2: Basic science, mathematics, & engineering Program Outcome 3: Ocean engineering core

Frandsen, Jannette B.

460

Isobaric vapor-liquid equilibria of methanol + 1-octanol and ethanol + 1-octanol mixtures  

SciTech Connect (OSTI)

Isobaric vapor-liquid equilibrium data for methanol + 1-octanol and ethanol + 1-octanol have been measured at 101.325 kPa. The results were checked for thermodynamic consistency using Fredenslund et al.`s test, correlated using Wilson, NRTL, and UNIQUAC equations for the liquid phase activity coefficients, and compared with the predictions of the ASOG, UNIFAC, and modified UNIFAC group contribution methods.

Arce, A.; Blanco, A.; Soto, A.; Tojo, J. [Univ. of Santiago de Compostela (Spain). Chemical Engineering Dept.

1995-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "methanol ocean thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Total pressure measurements for pentane + methanol + ethanol at 303. 15 K  

SciTech Connect (OSTI)

In this paper total pressure is reported as a function of liquid-phase composition for pentane + methanol + ethanol at 303.15 K. The data were reduced using Barker's method. The excess Gibbs energy of the liquid phase is represented by a rational function obtained by making an empirical modification to the nonrandom two-liquid (NRTL) equation. The resulting fit to the data is superior to that obtained using a previous representation based on a modified Margules equation.

Reimers, J.L.; Bhethanabotla, V.R.; Campbell, S.W. (Dept. of Chemical Engineering, Univ. of South Florida, Tampa, FL (US))

1992-01-01T23:59:59.000Z

462

Kinetics of methyl radical-hydroxyl radical collisions and methanol decomposition.  

SciTech Connect (OSTI)

The CH{sub 3} + OH bimolecular reaction and the dissociation of methanol are studied theoretically at conditions relevant to combustion chemistry. Kinetics for the CH{sub 3} + OH barrierless association reaction and for the H + CH{sub 2}OH and H + CH{sub 3}O product channels are determined in the high-pressure limit using variable reaction coordinate transition state theory and multireference electronic structure calculations to evaluate the fragment interaction energies. The CH{sub 3} + OH {yields} {sup 3}CH{sub 2} + H{sub 2}O abstraction reaction and the H{sub 2} + HCOH and H{sub 2} + H{sub 2}CO product channels feature localized dynamical bottlenecks and are treated using variational transition state theory and QCISD(T) energies extrapolated to the complete basis set limit. The {sup 1}CH{sub 2} + H{sub 2}O product channel has two dynamical regimes, featuring both an inner saddle point and an outer barrierless region, and it is shown that a microcanonical two-state model is necessary to properly describe the association rate for this reaction over a broad temperature range. Experimental channel energies for the methanol system are reevaluated using the Active Thermochemical Tables (ATcT) approach. Pressure dependent, phenomenological rate coefficients for the CH{sub 3} + OH bimolecular reaction and for methanol decomposition are determined via master equation simulations. The predicted results agree well with experimental results, including those from a companion high-temperature shock tube determination for the decomposition of methanol.

Jasper, A. W.; Klippenstein, S. J.; Harding, L. B.; Ruscic, B.; Chemistry

2007-01-01T23:59:59.000Z

463

Commercial-Scale Demonstration of the Liquid Phase methanol (LPMEOH) Process A DOE Assessment  

SciTech Connect (OSTI)

The U.S. Department of Energy (DOE) Clean Coal Technology (CCT) Program seeks to offer the energy marketplace more efficient and environmentally benign coal utilization technology options by demonstrating them in industrial settings. This document is a DOE post-project assessment (PPA) of one of the projects selected in Round III of the CCT Program, the commercial-scale demonstration of the Liquid Phase Methanol (LPMEOH{trademark}) Process, initially described in a Report to Congress by DOE in 1992. Methanol is an important, large-volume chemical with many uses. The desire to demonstrate a new process for the production of methanol from coal, prompted Air Products and Chemicals, Inc. (Air Products) to submit a proposal to DOE. In October 1992, DOE awarded a cooperative agreement to Air Products to conduct this project. In March 1995, this cooperative agreement was transferred to Air Products Liquid Phase Conversion Company, L.P. (the Partnership), a partnership between Air Products and Eastman Chemical Company (Eastman). DOE provided 43 percent of the total project funding of $213.7 million. Operation of the LPMEOH Demonstration Unit, which is sited at Eastman's chemicals-from-coal complex in Kingsport, Tennessee, commenced in April 1997. Although operation of the CCT project was completed in December 2002, Eastman continues to operate the LPMEOH Demonstration Unit for the production of methanol. The independent evaluation contained herein is based primarily on information from Volume 2 of the project's Final Report (Air Products Liquid Phase Conversion Co., L.P. 2003), as well as other references cited.

National Energy Technology Laboratory

2003-10-27T23:59:59.000Z

464

Technoeconomic Comparison of Biofuels: Ethanol, Methanol, and Gasoline from Gasification of Woody Residues (Presentation)  

SciTech Connect (OSTI)

This presentation provides a technoeconomic comparison of three biofuels - ethanol, methanol, and gasoline - produced by gasification of woody biomass residues. The presentation includes a brief discussion of the three fuels evaluated; discussion of equivalent feedstock and front end processes; discussion of back end processes for each fuel; process comparisons of efficiencies, yields, and water usage; and economic assumptions and results, including a plant gate price (PGP) for each fuel.

Tarud, J.; Phillips, S.

2011-08-01T23:59:59.000Z

465

Mechanistic Studies of Methanol Synthesis over Cu from CO/CO2/H2/H2O Mixtures: the Source of C in Methanol and the Role of Water  

SciTech Connect (OSTI)

The low temperature (403 453K) conversions of CO:hydrogen and CO2:hydrogen mixtures (6 bar total pressure) to methanol over copper catalysts are both assisted by the presence of small amounts of water (mole fraction ~0.04%-0.5%). For CO2:hydrogen reaction mixtures, the water product from both methanol synthesis and reverse water gas shift serves to initiate both reactions in an autocatalytic manner. In the case of CO:D2 mixtures, very little methanol is produced until small amounts of water are added. The effect of water on methanol production is more immediate than in CO2:D2, yet the steady state rates are similar. Tracer experiments in 13CO:12CO2:hydrogen (with or without added water), show that the dominant source of C in the methanol product gradually shifts from CO2 to CO as the temperature is lowered. Cu-bound formate, the major IR visible surface species under CO2:hydrogen, is not visible in CO:moist hydrogen. Though formate is visible in the tracer experiments, the symmetric stretch is absent. These results, in conjunction with recent DFT calculations on Cu(111), point to carboxyl as a common intermediate for both methanol synthesis and reverse water gas shift, with formate playing a spectator co-adsorbate role.

Yang, Yong; Mims, Charles A.; Mei, Donghai; Peden, Charles HF; Campbell, Charles T.

2013-02-01T23:59:59.000Z

466

Structural and Electrochemical Characterization of Binary, Ternary, and Quaternary Platinum Alloy Catalysts for Methanol Electro-oxidation1  

E-Print Network [OSTI]

Structural and Electrochemical Characterization of Binary, Ternary, and Quaternary Platinum Alloy methanol fuel cells (DMFC's) at 60 °C show that the best Pt-Ru-Os-Ir compositions are markedly superior

467

Vibrational relaxation of the free terminal hydroxyl stretch in methanol oligomers: Indirect pathway to hydrogen bond breaking  

E-Print Network [OSTI]

Vibrational relaxation of methanol-d MeOD in carbon tetrachloride has been investigated via ultrafast infrared such as carbon tetrachloride (CCl4) or alkanes. Unlike water, which is only sparingly soluble in nonpolar

Fayer, Michael D.

468

Membranen aus [(A)n(B)m]x-Multiblockcopolymeren fr den Einsatz in der Direkt-Methanol-Brennstoffzelle (DMFC).  

E-Print Network [OSTI]

??Aramide and arylene ether multiblock copolymers of (AB)n-type with various degrees of sulfonation have been prepared for use in direct methanol fuel cells. Aramid- und (more)

Taeger, Antje

2005-01-01T23:59:59.000Z

469

EXPANDED VERY LARGE ARRAY DETECTION OF 36.2 GHz CLASS I METHANOL MASERS IN SAGITTARIUS A  

E-Print Network [OSTI]

We report on the interferometric detection of 36.2 GHz Class I methanol emission with the new 27-40 GHz Ka-band receivers available on the Expanded Very Large Array (EVLA). The brightness temperatures of the interferometric ...

Sjouwerman, Lornt O.

470

Ocean Conditions, Salmon, and Climate Change  

E-Print Network [OSTI]

Ocean Conditions, Salmon, and Climate Change John Ferguson1 NOAA Fisheries Northwest Fisheries're finding - adult forecasts and climate change) #12;1. Past (for context) · The coastal pelagic ecosystem/survival #12;NE Pacific Ocean fisheries productivity, 200 BC to 2000 AD (by Finney et al. 2002 Nature) Main

471

Legal Implications of CO2 Ocean Storage  

E-Print Network [OSTI]

role in naturally removing carbon dioxide from the atmosphere, the ocean is considered an essential dioxide in addition to the vast quantities already stored naturally. A few recent research to contradict each other regarding the use of the ocean as a "sink" or disposal area for carbon dioxide. On one

472

Automated Sensor Networks to Advance Ocean Science  

E-Print Network [OSTI]

satellite telecom- munications. A regional cabled observa- tory will "wire" a single region in the north- eastern Pacific Ocean with a high-speed optical and power grid. The coastal com- ponent will expand ocean- observing network in the Mid-Atlantic Bight waters (MAB, spanning offshore regions from

473

OCEAN DRILLING PROGRAM LEG 179 SCIENTIFIC PROSPECTUS  

E-Print Network [OSTI]

OCEAN DRILLING PROGRAM LEG 179 SCIENTIFIC PROSPECTUS HAMMER DRILLING and NERO Dr. Jack Casey Chief.S.A. Tom Pettigrew Chief Engineer, Leg 179 Ocean Drilling Program Texas A&M University Research Park 1000 Drilling Program Texas A&M University Research Park 1000 Discovery Drive College Station, Texas 77845

474

OCEAN DRILLING PROGRAM LEG 132 PRELIMINARY REPORT  

E-Print Network [OSTI]

OCEAN DRILLING PROGRAM LEG 132 PRELIMINARY REPORT ENGINEERING II: WESTERN AND CENTRAL PACIFIC Mr. Michael A. Storms Supervisor of Development Engineering Ocean Drilling Program Texas A&M University and Drilling Operations ODP/TAMU Timothy J.G. Francis Deputy Director ODP/TAMU September 1990 #12;This informal

475

ESF Consortium for Ocean Drilling White Paper  

E-Print Network [OSTI]

ESF Consortium for Ocean Drilling (ECOD) White Paper An ESF Programme September 2003 #12;The, maintains the ship over a specific location while drilling into water depths up to 27,000 feet. A seven Amsterdam, The Netherlands #12;1 ESF Consortium for Ocean Drilling (ECOD) White Paper Foreword 3

Purkis, Sam

476

OCEAN DRILLING PROGRAM LEG 191 SCIENTIFIC PROSPECTUS  

E-Print Network [OSTI]

OCEAN DRILLING PROGRAM LEG 191 SCIENTIFIC PROSPECTUS NORTHWEST PACIFIC SEISMIC OBSERVATORY AND HAMMER DRILL ENGINEERING TESTS Dr. Toshihiko Kanazawa Co-Chief Scientist Earthquake Research Institute Director of Science Operations Ocean Drilling Program Texas A&M University 1000 Discovery Drive College

477

OCEAN DRILLING PROGRAM LEG 192 SCIENTIFIC PROSPECTUS  

E-Print Network [OSTI]

OCEAN DRILLING PROGRAM LEG 192 SCIENTIFIC PROSPECTUS BASEMENT DRILLING OF THE ONTONG JAVA PLATEAU of Science Operations Ocean Drilling Program Texas A&M University 1000 Discovery Drive College Station, TX Drilling Program Texas A&M University 1000 Discovery Drive College Station, TX 77845-9547 U.S.A. May 2000

478

OCEAN DRILLING PROGRAM LEG 120 SCIENTIFIC PROSPECTUS  

E-Print Network [OSTI]

OCEAN DRILLING PROGRAM LEG 120 SCIENTIFIC PROSPECTUS CENTRAL KERGUELEN PLATEAU Dr. Roland Schlich Drilling Program Texas A&M University College Station, TX 77841 Philip D.VRabinowitz Director ^^~-- ODP of the Director, Ocean Drilling Program, Texas A&M University Research Park, 1000 Discovery Drive, College Station

479

OCEAN DRILLING PROGRAM LEG 106 PRELIMINARY REPORT  

E-Print Network [OSTI]

OCEAN DRILLING PROGRAM LEG 106 PRELIMINARY REPORT BARE ROCK DRILLING IN THE MID-ATLANTIC RIDGE RIFT 106 Ocean Drilling Program Texas A & M University College Station, TX 77843-3469 ±nuwiLZ" ector ODP Drilling Program, Texas A & M University, College Station, Texas 77843-3469. In some cases, orders

480

LEG 142 PRELIMINARY REPORT OCEAN DRILLING PROGRAM  

E-Print Network [OSTI]

LEG 142 PRELIMINARY REPORT OCEAN DRILLING PROGRAM ENGINEERING PRELIMINARY REPORT NO. 3 EAST PACIFIC RISE 1992 #12;OCEAN DRILLING PROGRAM LEG 142 PRELIMINARY REPORT East Pacific Rise Dr. Rodey Batiza Co 96822 Mr. Michael A. Storms Operations Superintendent/ Assistant Manager of Engineering and Drilling

Note: This page contains sample records for the topic "methanol ocean thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Statistical mechanics and ocean circulation Rick Salmon  

E-Print Network [OSTI]

Statistical mechanics and ocean circulation Rick Salmon Scripps Institution of Oceanography, UCSD equilibrium statistical mechanics based upon the conservation of energy and potential enstrophy to the mass. The equilibrium state resembles the buoyancy structure actually observed. Key words: statistical mechanics, ocean

Salmon, Rick

482

Wavelet Spectrum Analysis and Ocean Wind Waves  

E-Print Network [OSTI]

Wavelet Spectrum Analysis and Ocean Wind Waves Paul C. Liu Abstract. Wavelet spectrum analysis is applied to a set of measured ocean wind waves data collected during the 1990 SWADE {Surface Wave Dynamics Experi- ment) program. The results reveal significantly new and previously unexplored Insights on wave

483

Ocean and Sea Ice SAF Technical Note  

E-Print Network [OSTI]

Ocean and Sea Ice SAF Technical Note SAF/OSI/CDOP/KNMI/TEC/RP/147 Validation of ASCAT 12.5-km winds The Ocean and Sea Ice Satellite Application Facility (OSI SAF) delivers an operational level 2 wind product produces a level 1 product with 12.5-km WVC spacing that has a resolution of approximately 25 km. Since

Stoffelen, Ad

484

Ocean and Sea Ice SAF Technical Note  

E-Print Network [OSTI]

Ocean and Sea Ice SAF Technical Note SAF/OSI/CDOP2/KNMI/TEC/RP/194 Quality Control of Ku. The OSCAT level 2a data are available in near-real time and OWDP is used at KNMI to produce the Ocean and Sea Ice (OSI) SAF wind product which is made available to users. A beta version of OWDP is also

Stoffelen, Ad

485

OCEAN DRILLING PROGRAM LEG 180 PRELIMINARY REPORT  

E-Print Network [OSTI]

OCEAN DRILLING PROGRAM LEG 180 PRELIMINARY REPORT ACTIVE CONTINENTAL EXTENSION IN THE WESTERN WOODLARK BASIN, PAPUA NEW GUINEA Dr. Philippe Huchon CNRS, Laboratoire de Géologie ?cole Normale Supérieure and Technology University of Hawaii at Manoa 2525 Correa Road Honolulu, HI 96822-2285 U.S.A. Dr. Adam Klaus Ocean

486

OCEAN DRILLING PROGRAM LEG 136 PRELIMINARY REPORT  

E-Print Network [OSTI]

Operations ODP/TAI Timothy J.G. Francis Deputy Director ODP/TAMU May 1991 #12;This informal report Ocean Drilling Program, which is managed by Joint Oceanographic Institutions, Inc., under contract Environment Research Council (United Kingdom) Ocean Research Institute of the University of Tokyo (Japan) Any

487

OCEAN DRILLING PROGRAM LEG 132 ENGINEERING PROSPECTUS  

E-Print Network [OSTI]

OCEAN DRILLING PROGRAM LEG 132 ENGINEERING PROSPECTUS WESTERN AND CENTRAL PACIFIC Mr. Michael A. Storms Supervisor of Development Engineering Ocean Drilling Program Texas A & M University College Manager of Engineering and Drilling Operations ODP/TAMU Louis E. Garrison Deputy Director ODP

488

Ocean Engineering 33 (2006) 22092223 Technical Note  

E-Print Network [OSTI]

Ocean Engineering 33 (2006) 2209­2223 Technical Note Pulsatile vortex generators for low-speed maneuvering of small underwater vehicles Kamran Mohseni? Department of Aerospace Engineering Sciences, science writer). #12;1. Introduction Oceans hold the key to the origin and continuity of life on the Earth

Mohseni, Kamran

489

Aquantis Ocean Current Turbine Development Project Report  

SciTech Connect (OSTI)

The Aquantis Current Plane (C-Plane) technology developed by Dehlsen Associates, LLC (DA) and Aquantis, Inc. is an ocean current turbine designed to extract kinetic energy from ocean currents. The technology is capable of achieving competitively priced base-load, continuous, and reliable power generation from a source of renewable energy not before possible in this scale or form.

Fleming, Alex J.

2014-08-23T23:59:59.000Z

490

OCEAN DRILLING PROGRAM LEG 111 SCIENTIFIC PROSPECTUS  

E-Print Network [OSTI]

under the international Ocean Drilling Program which is managed by Joint Oceanographic Institutions, Inc by the following agencies: Department of Energy, Mines and Resources (Canada) Deutsche ForschungsgemeinschaftOCEAN DRILLING PROGRAM LEG 111 SCIENTIFIC PROSPECTUS DSDP HOLE 504B REVISITED Keir Becker

491

TUNING OF SIZE AND SHAPE OF AU-PT NANOCATALYST FOR DIRECT METHANOL FUEL CELLS  

SciTech Connect (OSTI)

In this paper, we report the precise control of the size, shape and surface morphology of Au-Pt nanocatalysts (cubes, blocks, octahedrons and dogbones) synthesized via a seed-mediated approach. Gold 'seeds' of different aspect ratios (1 to 4.2), grown by a silver-assisted approach, were used as templates for high-yield production of novel Au-Pt nanocatalysts at a low temperature (40 C). Characterization by electron microscopy (SEM, TEM, HRTEM), energy dispersive X-ray analysis (EDX), UV-Vis spectroscopy, zeta-potential (surface charge), atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS) and inductively coupled plasma mass spectrometry (ICP-MS) were used to better understand their physico-chemical properties, preferred reactivities and underlying nanoparticle growth mechanism. A rotating disk electrode was used to evaluate the Au-Pt nanocatalysts electrochemical performance in the oxygen reduction reaction (ORR) and the methanol oxidation reaction (MOR) of direct methanol fuel cells. The results indicate the Au-Pt dogbones are partially and in some cases completely unaffected by methanol poisoning during the evaluation of the ORR. The ORR performance of the octahedron particles in the absence of MeOH is superior to that of the Au-Pt dogbones and Pt-black, however its performance is affected by the presence of MeOH.

Murph, S.

2011-04-20T23:59:59.000Z

492

Assistant Professor, Ocean Engineering The Department of Ocean Engineering at the University of Rhode Island (URI) invites  

E-Print Network [OSTI]

Assistant Professor, Ocean Engineering The Department of Ocean Engineering at the University of Rhode Island (URI) invites applications for a tenure-track faculty position in ocean energy systems

Frandsen, Jannette B.

493

Promotive SMSI effect for hydrogenation of carbon dioxide to methanol on a Pd/CeO{sub 2} catalyst  

SciTech Connect (OSTI)

This article reports strong metal support interaction (SMSI) appearing in supported palladium catalysts which improves greatly the selectivity and lifetime of the catalysts for methanol synthesis from CO{sub 2} hydrogenation. Catalytic hydrogenation of carbon dioxide into valuable chemicals and fuels such as methanol has recently been recognized as one of the promising recycling technologies for emitted CO{sub 2}. 33 refs., 1 fig., 3 tabs.

NONE

1994-11-01T23:59:59.000Z

494

Thermal Management of Solar Cells  

E-Print Network [OSTI]

a better thermal conductance and when ceramic particles areor ceramic fillers that enhances thermal conductivity. Solid

Saadah, Mohammed Ahmed

2013-01-01T23:59:59.000Z

495

INTEGRATED OCEAN DRILLING PROGRAM United States Implementing Organization  

E-Print Network [OSTI]

1 INTEGRATED OCEAN DRILLING PROGRAM United States Implementing Organization JOI Alliance Joint _______________________________ Steven R. Bohlen President, Joint Oceanographic Institutions Executive Director, Ocean Drilling Programs

496

INTEGRATED OCEAN DRILLING PROGRAM United States Implementing Organization  

E-Print Network [OSTI]

1 INTEGRATED OCEAN DRILLING PROGRAM United States Implementing Organization JOI Alliance Joint, Ocean Drilling Programs Joint Oceanographic Institutions, Inc. Washington DC 20005 19 July 2005 #12

497

INTEGRATED OCEAN DRILLING PROGRAM United States Implementing Organization  

E-Print Network [OSTI]

INTEGRATED OCEAN DRILLING PROGRAM United States Implementing Organization JOI Alliance Joint President, Joint Oceanographic Institutions Executive Director, Ocean Drilling Programs Joint Oceanographic

498

Mapping and Assessment of the United States Ocean Wave Energy...  

Office of Environmental Management (EM)

States Ocean Wave Energy Resource Mapping and Assessment of the United States Ocean Wave Energy Resource This report describes the analysis and results of a rigorous assessment of...

499

The Subcommittee on Water, Power, and Oceans House Committee...  

Energy Savers [EERE]

The Subcommittee on Water, Power, and Oceans House Committee on Natural Resources The Subcommittee on Water, Power, and Oceans House Committee on Natural Resources Testimony of...

500

Before the Subcommittee on Water, Power, and Oceans - House Natural...  

Energy Savers [EERE]

Water, Power, and Oceans - House Natural Resources Committee Before the Subcommittee on Water, Power, and Oceans - House Natural Resources Committee Testimony of Kenneth E. Legg,...