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1

Alternative technologies to steam-methane reforming  

SciTech Connect (OSTI)

Steam-methane reforming (SMR) has been the conventional route for hydrogen and carbon monoxide production from natural gas feedstocks. However, several alternative technologies are currently finding favor for an increasing number of applications. The competing technologies include: steam-methane reforming combined with oxygen secondary reforming (SMR/O2R); autothermal reforming (ATR); thermal partial oxidation (POX). Each of these alternative technologies uses oxygen as a feedstock. Accordingly, if low-cost oxygen is available, they can be an attractive alternate to SMR with natural gas feedstocks. These technologies are composed technically and economically. The following conclusions can be drawn: (1) the SMR/O2R, ATR and POX technologies can be attractive if low-cost oxygen is available; (2) for competing technologies, the H{sub 2}/CO product ratio is typically the most important process parameter; (3) for low methane slip, the SMR/O2R, ATR and POX technologies are favored; (4) for full CO{sub 2} recycle, POX is usually better than ATR; (5) relative to POX, the ATR is a nonlicensed technology that avoids third-party involvement; (6) economics of each technology are dependent on the conditions and requirements for each project and must be evaluated on a case-by-case basis.

Tindall, B.M.; Crews, M.A. [Howe-Baker Engineers, Inc., Tyler, TX (United States)

1995-11-01T23:59:59.000Z

2

SOLAR UPGRADE OF METHANE USING DRY REFORMING IN DIRECT CONTACT BUBBLE REACTOR  

E-Print Network [OSTI]

process of a solar reformer of dry methane reforming was proposed to operate in a temperature range of 600SOLAR UPGRADE OF METHANE USING DRY REFORMING IN DIRECT CONTACT BUBBLE REACTOR Khalid Al-Ali 1 including lower melting point, thermal and chemical stability, acting simultaneously as heat transport

Paris-Sud XI, Université de

3

Steam methane reforming in molten carbonate salt. Final report  

SciTech Connect (OSTI)

This report documents the work accomplished on the project {open_quotes}Steam Methane Reforming in Molten Carbonate Salt.{close_quotes}. This effort has established the conceptual basis for molten carbonate-based steam reforming of methane. It has not proceeded to prototype verification, because corrosion concerns have led to reluctance on the part of large hydrogen producers to adopt the technology. Therefore the focus was shifted to a less corrosive embodiment of the same technology. After considerable development effort it was discovered that a European company (Catalysts and Chemicals Europe) was developing a similar process ({open_quotes}Regate{close_quotes}). Accordingly the focus was shifted a second time, to develop an improvement which is generic to both types of reforming. That work is still in progress, and shows substantial promise.

Erickson, D.C.

1996-05-01T23:59:59.000Z

4

Computational heterogeneous catalysis applied to steam methane reforming over nickel and nickel/silver catalysts  

E-Print Network [OSTI]

The steam methane reforming (SMR) reaction is the primary industrial means for producing hydrogen gas. As such, it is a critical support process for applications including petrochemical processing and ammonia synthesis. ...

Blaylock, Donnie Wayne

2011-01-01T23:59:59.000Z

5

Compatibility of selected ceramics with steam-methane reformer environments  

SciTech Connect (OSTI)

Conventional steam reforming of methane to synthesis gas (CO and H{sub 2}) hasa conversion efficiency of about 85%. Replacement of metal tubes in the reformer with ceramic tubes offers the potential for operation at temperatures high enough to increase the efficiency to 98-99%. However, the two candidate ceramic materials being given strongest consideration, sintered alpha Si carbide and Si carbide particulate-strengthened alumina, have been shown to react with components of the reformer environment. Extent of degradation as a function of steam partial pressure and exposure time has been studied, and results suggest limits under which these structural ceramics can be used in advanced steam-methane reformers.

Keiser, J.R.; Howell, M. [Oak Ridge National Lab., TN (United States); Williams, J.J.; Rosenberg, R.A. [Stone and Webster Engineering Corp., Boston, MA (United States)

1996-04-01T23:59:59.000Z

6

Autothermal reforming catalyst and process  

SciTech Connect (OSTI)

High activity steam reforming catalysts are described particularly adapted for use in autothermal reforming processes. A rhodium catalyst on a calcium oxide impregnated alumina substrate allow the autothermal reforming process to take place with substantially no carbon plugging at oxygen to carbon ratios below what had been considered critical for avoiding carbon plugging of the catalyst in the past.

Setzer, H. J.; Karavolis, S.; Lesieur, R. R.; Wnuck, W. G.

1984-09-25T23:59:59.000Z

7

Methane/nitrogen separation process  

DOE Patents [OSTI]

A membrane separation process is described for treating a gas stream containing methane and nitrogen, for example, natural gas. The separation process works by preferentially permeating methane and rejecting nitrogen. The authors have found that the process is able to meet natural gas pipeline specifications for nitrogen, with acceptably small methane loss, so long as the membrane can exhibit a methane/nitrogen selectivity of about 4, 5 or more. This selectivity can be achieved with some rubbery and super-glassy membranes at low temperatures. The process can also be used for separating ethylene from nitrogen. 11 figs.

Baker, R.W.; Lokhandwala, K.A.; Pinnau, I.; Segelke, S.

1997-09-23T23:59:59.000Z

8

Methane/nitrogen separation process  

DOE Patents [OSTI]

A membrane separation process for treating a gas stream containing methane and nitrogen, for example, natural gas. The separation process works by preferentially permeating methane and rejecting nitrogen. We have found that the process is able to meet natural gas pipeline specifications for nitrogen, with acceptably small methane loss, so long as the membrane can exhibit a methane/nitrogen selectivity of about 4, 5 or more. This selectivity can be achieved with some rubbery and super-glassy membranes at low temperatures. The process can also be used for separating ethylene from nitrogen.

Baker, Richard W. (Palo Alto, CA); Lokhandwala, Kaaeid A. (Menlo Park, CA); Pinnau, Ingo (Palo Alto, CA); Segelke, Scott (Mountain View, CA)

1997-01-01T23:59:59.000Z

9

Combined Steam Reforming and Partial Oxidation of Methane to Synthesis Gas under Electrical Discharge  

E-Print Network [OSTI]

Combined Steam Reforming and Partial Oxidation of Methane to Synthesis Gas under Electrical production from simultaneous steam reforming and partial oxidation of methane using an ac corona discharge production has been steam reforming, shown in reaction 4. It is very useful to use low-cost materials

Mallinson, Richard

10

SOFC Long Term Operation in Pure Methane by Gradual Internal Reforming S. Georgesa  

E-Print Network [OSTI]

SOFC Long Term Operation in Pure Methane by Gradual Internal Reforming S. Georgesa , N. Baillya , M was designed to be operated in pure methane, without reforming or carrier gas. The fuel cell was built up from-CGO catalytic layer. The operation principle is based on Gradual Internal Reforming. After an initiation in H2

Boyer, Edmond

11

Studies of mechanisms and kinetics of methane and ethane steam reforming on nickel catalysts  

SciTech Connect (OSTI)

Methane and ethane adsorption/desorption and reaction on steam-reforming catalysts, Ni(INCO), Ni/ZrO{sub 2}, and Ni/CaAl{sub 2}O{sub 4}, were studied by temperature-programmed desorption (TPD), temperature-programmed surface reaction (TPSR), and thermogravimetric (TGA) techniques. The data show that only a fraction of the methane adsorbed (determined by TPSR with H{sub 2}) on nickel catalysts is desorbed during TPD experiments. The results of TPD indicate supports and promoters affect the adsorption of methane and ethane, and transformation of adsorbed carbon species. Several carbon types formed during methane and ethane adsorptions including {alpha}, {beta}, {gamma}, vermicular (v), and graphitic (c) carbon can be identified by TPSR. These data indicate that the distribution of these carbon forms is also strongly a function of adsorption temperature and catalyst. The results show that there are significant quantities of CH{sub 4}, CO, and CO{sub 2} desorbed during TPSR reaction of H{sub 2}O with preadsorbed CH{sub 4}, CD{sub 4} and C{sub 2}H{sub 6}. The agreement between previously reported steady-state and the unsteady-state steam reforming reforming rates of this study indicates that the steam-reforming kinetic data can be quantitatively measured by TPSR experiments.

Hsieh, H.Y.

1988-01-01T23:59:59.000Z

12

Anaerobic digestion for methane generation and ammonia reforming for hydrogen production  

E-Print Network [OSTI]

,000,000 digesters, 2000 [14]), among other places [15,16]. These digesters operate to generate biogas, comprisingAnaerobic digestion for methane generation and ammonia reforming for hydrogen production Accepted 24 May 2013 Available online Keywords: Anaerobic digestion Ammonia Bioenergy Bioammonia Hydrogen

13

EFFECT OF H2 PRODUCED THROUGH STEAM-METHANE REFORMING ON CHP PLANT EFFICIENCY  

E-Print Network [OSTI]

1 EFFECT OF H2 PRODUCED THROUGH STEAM-METHANE REFORMING ON CHP PLANT EFFICIENCY O. Le Corre1 , C for a CHP plant based on spark ignition engine running under lean conditions. An overall auto combustion engine. The potential benefits of using H2 in spark ignition (SI) engines may be listed as follows

Paris-Sud XI, Université de

14

Process for separating nitrogen from methane using microchannel process technology  

DOE Patents [OSTI]

The disclosed invention relates to a process for separating methane or nitrogen from a fluid mixture comprising methane and nitrogen, the process comprising: (A) flowing the fluid mixture into a microchannel separator, the microchannel separator comprising a plurality of process microchannels containing a sorption medium, the fluid mixture being maintained in the microchannel separator until at least part of the methane or nitrogen is sorbed by the sorption medium, and removing non-sorbed parts of the fluid mixture from the microchannel separator; and (B) desorbing the methane or nitrogen from the sorption medium and removing the desorbed methane or nitrogen from the microchannel separator. The process is suitable for upgrading methane from coal mines, landfills, and other sub-quality sources.

Tonkovich, Anna Lee (Marysville, OH); Qiu, Dongming (Dublin, OH); Dritz, Terence Andrew (Worthington, OH); Neagle, Paul (Westerville, OH); Litt, Robert Dwayne (Westerville, OH); Arora, Ravi (Dublin, OH); Lamont, Michael Jay (Hilliard, OH); Pagnotto, Kristina M. (Cincinnati, OH)

2007-07-31T23:59:59.000Z

15

Synthesis and characterization of catalysts containing nickel for reforming methane with carbon dioxide  

E-Print Network [OSTI]

Methane with Carbon Dioxide. (August 1988) Michael Edward Sommer, B. S. , Rutgers University Chairman of Advisory Committee: Dr. Ahmed M. Gadalla An industrial Ni catalyst supported on CaO-TiOq-AlqOs was characterized and used for methane reforming... reduction to 15. 6m /g after reduction to 6, 35m /g after reaction. It should be noted that reduction of NiO is accompanied by contraction. Moreover, since CAs is more dense than CAs but comparable in density to aAlsOs (Table 2), the reaction of formation...

Sommer, Michael Edward

2012-06-07T23:59:59.000Z

16

Review of Novel Catalysts for Biomass Tar Cracking and Methane Reforming  

SciTech Connect (OSTI)

A review of the literature was conducted to examine the performance of catalysts other than conventional nickel catalysts, and alkaline earth and olivine based catalysts for treating hot raw product gas from a biomass gasifier to convert methane and tars into synthesis gas. Metal catalysts other than Ni included precious metals Rh, Ru, Ir, Pt, and Pd, as well as Cu, Co, and Fe in limited testing. Nickel catalysts promoted with Rh, Zr, Mn, Mo, Ti, Ag, or Sn were also examined, as were Ni catalysts on Ce2O3, TiO2, ZrO2, SiO2, and La2O3. In general, Rh stood out as a consistently superior metal catalyst for methane reforming, tar cracking, and minimizing carbon buildup on the catalyst. Ru and Ir also showed significant improvement over Ni for methane reforming. Ceria stood out as good support material and particularly good promoter material when added in small quantities to another support material such as alumina, zirconia, or olivine. Other promising supports were lanthana, zirconia, and titania.

Gerber, Mark A.

2007-10-10T23:59:59.000Z

17

Reforming The Government Hiring Process  

Broader source: Energy.gov [DOE]

The Department of Energy explains efforts made to simplify the federal hiring process within the Department, complete with video.

18

Modeling of Pressurized Electrochemistry and Steam-Methane Reforming in Solid Oxide Fuel Cells and the Effects on Thermal and Electrical Stack Performance  

SciTech Connect (OSTI)

Summarizes work done to extend the electrochemical performance and methane reforming submodels to include the effects of pressurization and to demonstrate this new modeling capability by simulating large stacks operating on methane-rich fuel under pressurized and non-pressurized conditions. Pressurized operation boosts electrochemical performance, alters the kinetics of methane reforming, and effects the equilibrium composition of methane fuels. This work developed constitutive submodels that couple the electrochemistry, reforming, and pressurization to yield an increased capability of the modeling tool for prediction of SOFC stack performance.

Recknagle, Kurtis P.; Khaleel, Mohammad A.

2009-03-01T23:59:59.000Z

19

Solar reforming of methane in a direct absorption catalytic reactor on a parabolic dish  

SciTech Connect (OSTI)

The concept of solar driven chemical reactions in a commercial-scale volumetric receiver/reactor on a parabolic concentrator was successfully demonstrated in the CAtalytically Enhanced Solar Absorption Receiver (CAESAR) test. Solar reforming of methane (CH{sub 4}) with carbon dioxide (CO{sub 2}) was achieved in a 64-cm diameter direct absorption reactor on a parabolic dish capable of 150 kW solar power. The reactor was a catalytic volumetric absorber consisting of a multi-layered, porous alumina foam disk coated with rhodium (Rh) catalyst. The system was operated during both steady-state and solar transient (cloud passage) conditions. The total solar power absorbed reached values up to 97 kW and the maximum methane conversion was 70%. Receiver thermal efficiencies ranged up to 85% and chemical efficiencies peaked at 54%. The absorber performed satisfactorily in promoting the reforming reaction during the tests without carbon formation. However, problems of cracking and degradation of the porous matrix, nonuniform dispersion of the Rh through the absorber, and catalyst deactivation due to sintering and possible encapsulation, must be resolved to achieve long-term operation and eventual commercialization. 17 refs., 11 figs., 1 tab.

Muir, J.F.; Hogan, R.E. Jr.; Skocypec, R.D. (Sandia National Labs., Albuquerque, NM (USA)); Buck, R. (Deutsche Forschungsanstalt fuer Luft- und Raumfahrt e.V. (DLR), Stuttgart (Germany, F.R.). Inst. fuer Technische Thermodynamik)

1990-01-01T23:59:59.000Z

20

Minimizing the formation of coke and methane on Co nanoparticles in steam reforming of biomass-derived oxygenates  

SciTech Connect (OSTI)

Fundamental understanding and control of chemical transformations are essential to the development of technically feasible and economically viable catalytic processes for efficient conversion of biomass to fuels and chemicals. Using an integrated experimental and theoretical approach, we report high hydrogen selectivity and catalyst durability of acetone steam reforming (ASR) on inert carbon supported Co nanoparticles. The observed catalytic performance is further elucidated on the basis of comprehensive first-principles calculations. Instead of being considered as an undesired intermediate prone for catalyst deactivation during bioethanol steam reforming (ESR), acetone is suggested as a key and desired intermediate in proposed two-stage ESR process that leads to high hydrogen selectivity and low methane formation on Co-based catalysts. The significance of the present work also sheds a light on controlling the chemical transformations of key intermediates in biomass conversion such as ketones. We gratefully acknowledge the financial support from U. S. Department of Energy (DOE), Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences, and the Laboratory directed research and development (LDRD) project of Pacific Northwest National Laboratory (PNNL). Computing time was granted by the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL). The EMSL is a U.S. DOE national scientific user facility located at PNNL, and sponsored by the U.S. DOE’s Office of Biological and Environmental Research.

Sun, Junming; Mei, Donghai; Karim, Ayman M.; Datye, Abhaya K.; Wang, Yong

2013-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "methane reforming process" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Methane steam reforming analysis in a palladium-based catalytic membrane reactor  

SciTech Connect (OSTI)

The methane steam reforming in a catalytic membrane reactor has been studied. A previous theoretical study of this reaction has been carried out. In the model a global kinetic rate as a function of three reactions over nickel catalyst as proposed by Xu and Froment has been considered. It has been shown that the counterflow configuration has, at high temperature (500 C), a marginal advantage on parallel flow and, also, that the space velocity cannot be considered a design variable for membrane reactors. A laboratory plant was realized utilizing membranes of Pd and Pd/Ag supported on Al{sub 2}O{sub 3}. The Pd membranes utilized have been prepared using the co-condensation technique and the electroless plating method. A comparison of the overall membrane performance has also been carried out. The experiments were aimed to study the effects of several parameters such as temperature, feed flow rate, and feed molar ratio on the methane conversion. The experimental results have been compared with the data predicted by the previously developed theoretical model.

Barbieri, G. [CNR, Rende (Italy). Inst. of Research on Membranes and Chemical Reactors Modeling] [CNR, Rende (Italy). Inst. of Research on Membranes and Chemical Reactors Modeling; Violante, V. [CR ENEA Frascati (Italy)] [CR ENEA Frascati (Italy); Maio, F.P. di; Criscuoli, A. [Univ. of Calabria, Rende (Italy). Dept. of Chemical Engineering and Materials] [Univ. of Calabria, Rende (Italy). Dept. of Chemical Engineering and Materials; Drioli, E. [CNR, Rende (Italy). Inst. of Research on Membranes and Chemical Reactors Modeling] [CNR, Rende (Italy). Inst. of Research on Membranes and Chemical Reactors Modeling; [Univ. of Calabria, Rende (Italy). Dept. of Chemical Engineering and Materials

1997-08-01T23:59:59.000Z

22

Process and apparatus for the production of hydrogen by steam reforming of hydrocarbon  

DOE Patents [OSTI]

In the steam reforming of hydrocarbon, particularly methane, under elevated temperature and pressure to produce hydrogen, a feed of steam and hydrocarbon is fed into a first reaction volume containing essentially only reforming catalyst to partially reform the feed. The balance of the feed and the reaction products of carbon dioxide and hydrogen are then fed into a second reaction volume containing a mixture of catalyst and adsorbent which removes the carbon dioxide from the reaction zone as it is formed. The process is conducted in a cycle which includes these reactions followed by countercurrent depressurization and purge of the adsorbent to regenerate it and repressurization of the reaction volumes preparatory to repeating the reaction-sorption phase of the cycle.

Sircar, Shivaji (Wescosville, PA); Hufton, Jeffrey Raymond (Fogelsville, PA); Nataraj, Shankar (Allentown, PA)

2000-01-01T23:59:59.000Z

23

Process Reform, Security and Suitability- December 17, 2008  

Broader source: Energy.gov [DOE]

This is to report on the progress made to improve the timeliness and effectiveness of our hiring and clearing decisions and the specific plan to reform the process further, in accordance with our initial proposals made in April ofthis year.

24

Integrated process for coalbed brine and methane disposal  

SciTech Connect (OSTI)

This paper describes a technology and project to demonstrate and commercialize a brine disposal process for converting the brine stream of a coalbed gas producing site into clean water for agricultural use and dry solids that can be recycled for industrial consumption. The process also utilizes coalbed methane (CBM) released from coal mining for the combustion process thereby substantially reducing the potential for methane emissions to the atmosphere. The technology is ideally suited for the treatment and disposal of produced brines generated from the development of coal mines and coalbed methane resources worldwide. Over the next 10 to 15 years, market potential for brine elimination equipment and services is estimated to be in the range of $1 billion.

Byam, J.W. Jr.; Tait, J.H.; Brandt, H.

1996-12-31T23:59:59.000Z

25

Dry reforming of hydrocarbon feedstocks  

SciTech Connect (OSTI)

Developments in catalyst technology for the dry reforming of hydrocarbon feedstocks are reviewed for methane, higher hydrocarbons and alcohols. Thermodynamics, mechanisms and the kinetics of dry reforming are also reviewed. The literature on Ni catalysts, bi-metallic Ni catalysts and the role of promoters on Ni catalysts is critically evaluated. The use of noble and transitional metal catalysts for dry reforming is discussed. The application of solid oxide and metal carbide catalysts to dry reforming is also evaluated. Finally, various mechanisms for catalyst deactivation are assessed. This review also examines the various process related issues associated with dry reforming such as its application and heat optimization. Novel approaches such as supercritical dry reforming and microwave assisted dry reforming are briefly expanded upon.

Shah, Yatish T. [Norfolk State University; Gardner, Todd H. [U.S. DOE

2014-01-01T23:59:59.000Z

26

Steam reforming analyzed  

SciTech Connect (OSTI)

This paper reports that maximum steam reformer operation without excessive coking reactions requires careful control of thermodynamic and kinetic conditions. Regardless of the syngas-based feedstock composition, carbon formation problems can be avoided while increasing reformer CO or H{sub 2} production. Steam reforming technology is best understood via: Primary steam reformer developments, Kinetics of methane steam reforming, Simulation of an industrial steam/CO{sub 2} reformer, Example conditions (steam/CO{sub 2} reforming), Thermodynamic approach (minimum to steam ratio). Hydrogen and carbon monoxide are two of the most important building blocks in the chemical industry. Hydrogen is mainly used in ammonia and methanol synthesis and petroleum refining. Carbon monoxide is used to produce pains, plastics, foams, pesticides and insecticides, to name a few. Production of H{sub 2} and CO is usually carried out by the following processes: Steam reforming (primary and secondary) of hydrocarbons, Partial oxidation of hydrocarbons, Coal gasification. Coal gasification and partial oxidation do not use catalysts and depend on partial combustion of the feedstock to internally supply reaction heat. Secondary (autothermal) reforming is a type of steam reforming that also uses the heat of partial combustion but afterwards uses a catalyst of promote the production of hydrogen and CO.

Wagner, E.S. (KTI Corp., San Dimas, CA (US)); Froment, G.F. (Ghent Rijksuniversiteit (Belgium))

1992-07-01T23:59:59.000Z

27

Highly Active and Stable MgAl2O4 Supported Rh and Ir Catalysts for Methane Steam Reforming: A Combined Experimental and Theoretical Study  

SciTech Connect (OSTI)

In this work we present a combined experimental and theoretical investigation of stable MgAl2O4 spinel-supported Rh and Ir catalysts for the steam methane reforming (SMR) reaction. Firstly, catalytic performance for a series of noble metal catalysts supported on MgAl2O4 spinel was evaluated for SMR at 600-850°C. Turnover rate at 850°C follows the order: Pd > Pt > Ir > Rh > Ru > Ni. However, Rh and Ir were found to have the best combination of activity and stability for methane steam reforming in the presence of simulated biomass-derived syngas. It was found that highly dispersed ~2 nm Rh and ~1 nm Ir clusters were formed on the MgAl2O4 spinel support. Scanning Transition Electron Microscopy (STEM) images show that excellent dispersion was maintained even under challenging high temperature conditions (e.g. at 850°C in the presence of steam) while Ir and Rh catalysts supported on Al2O3 were observed to sinter at increased rates under the same conditions. These observations were further confirmed by ab initio molecular dynamics (AIMD) simulations which find that ~1 nm Rh and Ir particles (50-atom cluster) bind strongly to the MgAl2O4 surfaces via a redox process leading to a strong metal-support interaction, thus helping anchor the metal clusters and reduce the tendency to sinter. Density functional theory (DFT) calculations suggest that these supported smaller Rh and Ir particles have a lower work function than larger more bulk-like ones, which enables them to activate both water and methane more effectively than larger particles, yet have a minimal influence on the relative stability of coke precursors. In addition, theoretical mechanistic studies were used to probe the relationship between structure and reactivity. Consistent with the experimental observations, our theoretical modeling results also suggest that the small spinel-supported Ir particle catalyst is more active than the counterpart of Rh catalyst for SMR. This work was financially supported by the United States Department of Energy (DOE)’s Bioenergy Technologies Office (BETO) and performed at the Pacific Northwest National Laboratory (PNNL). PNNL is a multi-program national laboratory operated for DOE by Battelle Memorial Institute. Computing time was granted by a user proposal at the Molecular Science Computing Facility in the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL) located at PNNL. Part of the computational time was provided by the National Energy Research Scientific Computing Center (NERSC).

Mei, Donghai; Glezakou, Vassiliki Alexandra; Lebarbier, Vanessa MC; Kovarik, Libor; Wan, Haiying; Albrecht, Karl O.; Gerber, Mark A.; Rousseau, Roger J.; Dagle, Robert A.

2014-07-01T23:59:59.000Z

28

Biomass reforming processes in hydrothermal media  

E-Print Network [OSTI]

While hydrothermal technologies offer distinct advantages in being able to process a wide variety of biomass feedstocks, the composition of the feedstock will have a large effect on the processing employed. This thesis ...

Peterson, Andrew A

2009-01-01T23:59:59.000Z

29

Cyclic process for producing methane with catalyst regeneration  

DOE Patents [OSTI]

Carbon monoxide-containing gas streams are passed over a catalyst capable of catalyzing the disproportionation of carbon monoxide so as to deposit a surface layer of active surface carbon on the catalyst essentially without formation of inactive coke thereon. The surface layer is contacted with steam and is thus converted to methane and CO.sub.2, from which a relatively pure methane product may be obtained. For practical commercial operations utilizing the two-step process of the invention of a cyclic basis, nickel, cobalt, ruthenium, thenium and alloys thereof are especially prepared for use in a metal state, with CO disproportionation being carried out at temperatures up to about 350.degree. C. and with the conversion of active surface carbon to methane being carried out by reaction with steam. The catalyst is employed in such cyclic operations without the necessity for employing a regeneration step as part of each processing cycle. Inactive carbon or coke that tends to form on the catalyst over the course of continuous operations utilizing such cyclic process is effectively and advantageously removed, on a periodic basis, in place of conventional burn off with an inert stream containing a low concentration of oxygen.

Frost, Albert C. (Congers, NY); Risch, Alan P. (New Fairfield, CT)

1980-01-01T23:59:59.000Z

30

A Novel Slurry-Based Biomass Reforming Process Final Technical Report  

SciTech Connect (OSTI)

This project was focused on developing a catalytic means of producing H2 from raw, ground biomass, such as fast growing poplar trees, willow trees, or switch grass. The use of a renewable, biomass feedstock with minimal processing can enable a carbon neutral means of producing H2 in that the carbon dioxide produced from the process can be used in the environment to produce additional biomass. For economically viable production of H2, the biomass is hydrolyzed and then reformed without any additional purification steps. Any unreacted biomass and other byproduct streams are burned to provide process energy. Thus, the development of a catalyst that can operate in the demanding corrosive environment and presence of potential poisons is vital to this approach. The concept for this project is shown in Figure 1. The initial feed is assumed to be a >5 wt% slurry of ground wood in dilute base, such as potassium carbonate (K2CO3). Base hydrolysis and reforming of the wood is carried out at high but sub-critical pressures and temperatures in the presence of a solid catalyst. A Pd alloy membrane allows the continuous removal of pure , while the retentate, including methane is used as fuel in the plant. The project showed that it is possible to economically produce H2 from woody biomass in a carbon neutral manner. Technoeconomic analyses using HYSYS and the DOE's H2A tool [1] were used to design a 2000 ton day-1 (dry basis) biomass to hydrogen plant with an efficiency of 46% to 56%, depending on the mode of operation and economic assumptions, exceeding the DOE 2012 target of 43%. The cost of producing the hydrogen from such a plant would be in the range of $1/kg H2 to $2/kg H2. By using raw biomass as a feedstock, the cost of producing hydrogen at large biomass consumption rates is more cost effective than steam reforming of hydrocarbons or biomass gasification and can achieve the overall cost goals of the DOE Fuel Cell Technologies Program. The complete conversion of wood to hydrogen, methane, and carbon dioxide was repeatedly demonstrated in batch reactors varying in size from 50 mL to 7.6 L. The different wood sources (e.g., swamp maple, poplar, and commercial wood flour) were converted in the presence of a heterogeneous catalyst and base at relatively low temperatures (e.g., 310 �������°C) at sub-critical pressures sufficient to maintain the liquid phase. Both precious metal and base metal catalysts were found to be active for the liquid phase hydrolysis and reforming of wood. Pt-based catalysts, particularly Pt-Re, were shown to be more selective toward breaking C-C bonds, resulting in a higher selectivity to hydrogen versus methane. Ni-based catalysts were found to prefer breaking C-O bonds, favoring the production of methane. The project showed that increasing the concentration of base (base to wood ratio) in the presence of Raney Ni catalysts resulted in greater selectivity toward hydrogen but at the expense of increasing the production of undesirable organic acids from the wood, lowering the amount of wood converted to gas. It was shown that by modifying Ni-based catalysts with dopants, it was possible to reduce the base concentration while maintaining the selectivity toward hydrogen and increasing wood conversion to gas versus organic acids. The final stage of the project was the construction and testing of a demonstration unit for H2 production. This continuous flow demonstration unit consisted of wood slurry and potassium carbonate feed pump systems, two reactors for hydrolysis and reforming, and a gas-liquid separation system. The technical challenges associated with unreacted wood fines and Raney Ni catalyst retention limited the demonstration unit to using a fixed bed Raney Ni catalyst form. The lower activity of the larger particle Raney Ni in turn limited the residence time and thus the wood mass flow feed rate to 50 g min-1 for a 1 wt% wood slurry. The project demonstrated continuous H2 yields with unmodified, fixed bed Raney Ni, from 63% to 100% with correspond

Sean C. Emerson; Timothy D. Davis; A. Peles; Ying She; Joshua Sheffel; Rhonda R. Willigan; Thomas H. Vanderspurt; Tianli Zhu

2011-09-30T23:59:59.000Z

31

Reformer-pressure swing adsorption process for the production of carbon monoxide  

SciTech Connect (OSTI)

An improved process for the production of carbon monoxide by the steam reforming of hydrocarbons is described comprising: (a) catalytically reacting a fluid hydrocarbon feed stream with steam in a steam reformer; (b) passing the reformer effluent containing hydrogen, carbon monoxide and carbon dioxide from the steam reformer, without scrubbing to remove the carbon dioxide content thereof, to a pressure swing adsorption system having at least four adsorbent beds, each bed of which, on a cyclic basis, undergoes a processing sequence; (c) recycling the carbon dioxide-rich stream to the steam reformer for reaction with additional quantities of the hydrocarbon feed stream being passed to the stream reformer to form additional quantities of carbon monoxide and hydrogen, with product recovery being enhanced and the need for employing a carbon dioxide wash system being obviated.

Fuderer, A.

1988-02-23T23:59:59.000Z

32

Study of Methane Reforming in Warm Non-Equilibrium Plasma Discharges  

E-Print Network [OSTI]

, temperature and other variables determine efficiency of conversion. An efficient process is identified by a high yield and low specific energy of production for the desired product. A study of previous work reveals that higher energy density systems are more...

Parimi, Sreekar

2012-02-14T23:59:59.000Z

33

Applications of solar reforming technology  

SciTech Connect (OSTI)

Research in recent years has demonstrated the efficient use of solar thermal energy for driving endothermic chemical reforming reactions in which hydrocarbons are reacted to form synthesis gas (syngas). Closed-loop reforming/methanation systems can be used for storage and transport of process heat and for short-term storage for peaking power generation. Open-loop systems can be used for direct fuel production; for production of syngas feedstock for further processing to specialty chemicals and plastics and bulk ammonia, hydrogen, and liquid fuels; and directly for industrial processes such as iron ore reduction. In addition, reforming of organic chemical wastes and hazardous materials can be accomplished using the high-efficiency destruction capabilities of steam reforming. To help identify the most promising areas for future development of this technology, we discuss in this paper the economics and market potential of these applications.

Spiewak, I. [Weizmann Inst. of Science, Rehovoth (Israel); Tyner, C.E. [Sandia National Labs., Albuquerque, NM (United States); Langnickel, U. [Deutsche Forschungsanstalt fuer Luft- und Raumfahrt e.V. (DLR), Koeln (Germany)

1993-11-01T23:59:59.000Z

34

Efficient gas-separation process to upgrade dilute methane stream for use as fuel  

DOE Patents [OSTI]

A membrane-based gas separation process for treating gas streams that contain methane in low concentrations. The invention involves flowing the stream to be treated across the feed side of a membrane and flowing a sweep gas stream, usually air, across the permeate side. Carbon dioxide permeates the membrane preferentially and is picked up in the sweep air stream on the permeate side; oxygen permeates in the other direction and is picked up in the methane-containing stream. The resulting residue stream is enriched in methane as well as oxygen and has an EMC value enabling it to be either flared or combusted by mixing with ordinary air.

Wijmans, Johannes G. (Menlo Park, CA); Merkel, Timothy C. (Menlo Park, CA); Lin, Haiqing (Mountain View, CA); Thompson, Scott (Brecksville, OH); Daniels, Ramin (San Jose, CA)

2012-03-06T23:59:59.000Z

35

Hydrogen Production from Methane Using Oxygen-permeable Ceramic Membranes  

E-Print Network [OSTI]

is the existence of hot spots in the catalyst bed due to the reaction exothermicity [1]. This hydrogen production process could be cost-effective if oxygen is provided by sources other than air separation plant. CO2 reforming (or dry reforming) of methane... information about equilibrium product compositions and equilibrium constants at different temperatures were provided by one of the former students in Dr Susan Williams’ research group [8]. Syngas can also be produced by coal gasification. The syngas...

Faraji, Sedigheh

2010-06-08T23:59:59.000Z

36

Cyclic process for producing methane in a tubular reactor with effective heat removal  

DOE Patents [OSTI]

Carbon monoxide-containing gas streams are converted to methane by a cyclic, essentially two-step process in which said carbon monoxide is disproportionated to form carbon dioxide and active surface carbon deposited on the surface of a catalyst, and said carbon is reacted with steam to form product methane and by-product carbon dioxide. The exothermic heat of reaction generated in each step is effectively removed during each complete cycle so as to avoid a build up of heat from cycle-to-cycle, with particularly advantageous techniques being employed for fixed bed, tubular and fluidized bed reactor operations.

Frost, Albert C. (Congers, NY); Yang, Chang-Lee (Spring Valley, NY)

1986-01-01T23:59:59.000Z

37

Cyclic process for producing methane from carbon monoxide with heat removal  

DOE Patents [OSTI]

Carbon monoxide-containing gas streams are converted to methane by a cyclic, essentially two-step process in which said carbon monoxide is disproportionated to form carbon dioxide and active surface carbon deposited on the surface of a catalyst, and said carbon is reacted with steam to form product methane and by-product carbon dioxide. The exothermic heat of reaction generated in each step is effectively removed during each complete cycle so as to avoid a build up of heat from cycle-to-cycle, with particularly advantageous techniques being employed for fixed bed, tubular and fluidized bed reactor operations.

Frost, Albert C. (Congers, NY); Yang, Chang-lee (Spring Valley, NY)

1982-01-01T23:59:59.000Z

38

REFORMING PROCESSES FOR MICRO COMBINED HEAT AND POWER SYSTEM BASED ON SOLID OXIDE FUEL CELL  

E-Print Network [OSTI]

REFORMING PROCESSES FOR MICRO COMBINED HEAT AND POWER SYSTEM BASED ON SOLID OXIDE FUEL CELL University Denmark ABSTRACT Solid oxide fuel cell (SOFC) is a promising technology for decentralized power be theoretically improved through integration in power cycles; the low emissions; and the pos- sibility of using

Berning, Torsten

39

Natural Gas Reforming | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Hydrogen Production Natural Gas Reforming Natural Gas Reforming Photo of Petroleum Refinery Natural gas reforming is an advanced and mature production process that builds upon...

40

Catalysis Letters 59 (1999) 9394 93 Stepwise methane steam reforming: a route to CO-free hydrogen  

E-Print Network [OSTI]

and could be an excellent hydrogen source for fuel cells and other devices or processes requiring CO as a primary fuel for fuel cells, it is highly desirable to develop processes which produce hydrogen free- move the last traces of CO which are capable of poisoning the electrode of a typical fuel cell

Goodman, Wayne

Note: This page contains sample records for the topic "methane reforming process" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

A review on recent advances in the numerical simulation for coalbed-methane-recovery process  

SciTech Connect (OSTI)

The recent advances in numerical simulation for primary coalbed methane (CBM) recovery and enhanced coalbed-methane recovery (ECBMR) processes are reviewed, primarily focusing on the progress that has occurred since the late 1980s. Two major issues regarding the numerical modeling will be discussed in this review: first, multicomponent gas transport in in-situ bulk coal and, second, changes of coal properties during methane (CH{sub 4}) production. For the former issues, a detailed review of more recent advances in modeling gas and water transport within a coal matrix is presented. Further, various factors influencing gas diffusion through the coal matrix will be highlighted as well, such as pore structure, concentration and pressure, and water effects. An ongoing bottleneck for evaluating total mass transport rate is developing a reasonable representation of multiscale pore space that considers coal type and rank. Moreover, few efforts have been concerned with modeling water-flow behavior in the coal matrix and its effects on CH{sub 4} production and on the exchange of carbon dioxide (CO{sub 2}) and CH{sub 4}. As for the second issue, theoretical coupled fluid-flow and geomechanical models have been proposed to describe the evolution of pore structure during CH{sub 4} production, instead of traditional empirical equations. However, there is currently no effective coupled model for engineering applications. Finally, perspectives on developing suitable simulation models for CBM production and for predicting CO{sub 2}-sequestration ECBMR are suggested.

Wei, X.R.; Wang, G.X.; Massarotto, P.; Golding, S.D.; Rudolph, V. [University of Queensland, Brisbane, Qld. (Australia)

2007-12-15T23:59:59.000Z

42

Integrated process and apparatus for the primary and secondary catalytic steam reforming of hydrocarbons  

SciTech Connect (OSTI)

An apparatus is described for the essentially autothermal, integrated primary and secondary reforming of hydrocarbons comprising: (a) an internally insulated outer reactor shell adapted for the positioning of primary and secondary reforming zones therein; (b) means defining a primary reforming zone within the outer reactor shell and having catalyst-containing reformer tubes positioned therein, the primary reforming zone not requiring an external fuel fired source of heat for the endothermic primary reforming reaction occurring therein; (c) means for introducing a fluid hydrocarbon feed stream and steam to the outer reactor shell for passage through the reformer tubes in the primary reforming zone; (d) means defining a secondary reforming zone within the outer reactor shell comprising a secondary reforming catalyst bed, a catalyst-free reaction space defining a feed end adjacent to the catalyst bed and a discharge end at the opposite side of the secondary reforming catalyst bed to the feed end; and (e) conduit means positioned entirely within the outer reactor shell and extending through the secondary reforming catalyst bed for passing partly reformed product effluent from the primary reforming zone to the catalyst-free reaction space in the secondary reforming zone.

Fuderer, A.

1987-03-17T23:59:59.000Z

43

MARINE BIOMASS SYSTEM: ANAEROBIC DIGESTION AND PRODUCTION OF METHANE  

E-Print Network [OSTI]

AND PRODUCTION OF METHANE Lawrence Berkeley LaboratoryDIGESTION AND PRODUCTION OF METHANE Kendall F. Haven MarkArrangement Kelp to Methane Processing Plant Schematic.

Haven, Kendall F.

2011-01-01T23:59:59.000Z

44

E-Print Network 3.0 - autothermal reformer processes Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

(ITM) Reactor - Air Products and Chemicals, Inc. Autothermal Reforming (ATR) - Praxair Inc. 12... Hydrogen Coordination Meeting Arthur Hartstein Program Manager Natural...

45

E-Print Network 3.0 - agrarian reform process Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Peace Agreement... and adopt entrenched positions in support of their interests. In Nepal, land reform is a constant source... groups. One of the main sources of conflict is...

46

A Process-based Analysis of Methane Exchanges Between Alaskan Terrestrial Ecosystems and the Atmosphere  

E-Print Network [OSTI]

We developed and used a new version of the Terrestrial Ecosystem Model (TEM) to study how rates of methane (CH4) emissions and consumption in Alaskan soils have changed over the past century in response to observed changes ...

Zhuang, Qianlai.

47

Methane conversion for application in fuel cells  

SciTech Connect (OSTI)

Conventional steam reformers are large and expensive for small scale fuel cell installations. But also the high endothermicity of the reforming reaction for the production of synthesis gas is a drawback. An alternative to conventional steam reforming is the partial oxidation of methane to synthesis gas. This process is slightly exothermic. The flexibility of the process makes small scale application possible. However, the partial oxidation process seems especially attractive for application within a high temperature fuel cell, because of relatively high CO/H{sub 2}-ratio for the output gases. In this paper the results of the study on the mechanism of the partial oxidation to synthesis gas on silica-supported nickel catalysts are discussed. Moreover, a process for the partial oxidation is proposed in which air instead of oxygen can be used. Based on the results of the mechanistic study two processes for the catalytic partial oxidation are proposed and simulated using the Aspen Plus flowsheeting program with which the mass and heat balances were optimized.

Mulder, A. [Gastec N.V., Apeldoorn (Netherlands); Looy, F. van [Utrecht Univ. (Netherlands). Dept. of Inorganic Chemistry; Waveren, A. van; Wingerden, A.J.M. van

1996-12-31T23:59:59.000Z

48

The Li'an ("Docketing") Process: Barriers to Initiating Lawsuits in China and Possible Reforms  

E-Print Network [OSTI]

Supreme People's Court ("SPC") found it necessary to pro-note 10, at 88-9. The 1999 SPC Five Year Reform Program ("On May 29, 1997, the SPC issued the Li'an ("Docketing") Work

Cheuk, Andrea

2008-01-01T23:59:59.000Z

49

Producing Clean Syngas via Catalytic Reforming for Fuels Production  

SciTech Connect (OSTI)

Thermochemical biomass conversion to fuels and chemicals can be achieved through gasification to syngas. The biomass derived raw syngas contains the building blocks of carbon monoxide and hydrogen as well as impurities such as tars, light hydrocarbons, and hydrogen sulfide. These impurities must be removed prior to fuel synthesis. We used catalytic reforming to convert tars and hydrocarbons to additional syngas, which increases biomass carbon utilization. In this work, nickel based, fluidizable tar reforming catalysts were synthesized and evaluated for tar and methane reforming performance with oak and model syngas in two types of pilot scale fluidized reactors (recirculating and recirculating regenerating). Because hydrogen sulfide (present in raw syngas and added to model syngas) reacts with the active nickel surface, regeneration with steam and hydrogen was required. Pre and post catalyst characterization showed changes specific to the syngas type used. Results of this work will be discussed in the context of selecting the best process for pilot scale demonstration.

Magrini, K. A.; Parent, Y.; Jablonski, W.; Yung, M.

2012-01-01T23:59:59.000Z

50

PYROLYSIS OF METHANE IN A SUPERSONIC, ARC-HEATED FLOW  

E-Print Network [OSTI]

1 PYROLYSIS OF METHANE IN A SUPERSONIC, ARC-HEATED FLOW F.K. Lu,* C.M. Roseberry, J.M. Meyers and D arc pyrolysis of methane at supersonic conditions, representative of conditions in the reformer- cate the feasibility of arc pyrolysis of methane. Introduction he high specific enthalpy of combustion

Texas at Arlington, University of

51

DUNCAN PRITCHARD Reforming Reformed Epistemology*  

E-Print Network [OSTI]

DUNCAN PRITCHARD Reforming Reformed Epistemology* 0. Introduction There has been a renaissance-called "reformed" defence of the rationality of reli- gious belief. The starting-point for this reformed conception concern here. Instead, I will be outlining one way in which the reformed epistemological stance can

Edinburgh, University of

52

Development of METHANE de-NOX Reburn Process for Wood Waste and Biomass Fired Stoker Boilers - Final Report - METHANE de-NOX Reburn Technology Manual  

SciTech Connect (OSTI)

The overall objective of this project was to demonstrate the effectiveness of the METHANE de-NOXź (MdN) Reburn process in the Forest Products Industry (FPI) to provide more efficient use of wood and sludge waste (biosolids) combustion for both energy generation and emissions reduction (specifically from nitrogen oxides (NOx)) and to promote the transfer of the technology to the wide range of wood waste-fired stoker boilers populating the FPI. This document, MdN Reburn Commercial Technology Manual, was prepared to be a resource to promote technology transfer and commercialization activities of MdN in the industry and to assist potential users understand its application and installation requirements. The Manual includes a compilation of MdN commercial design data from four different stoker boiler designs that were baseline tested as part of the development effort. Design information in the Manual include boiler CFD model studies, process design protocols, engineering data sheets and commercial installation drawings. Each design package is unique and implemented in a manner to meet specific mill requirements.

J. Rabovitser; B. Bryan; S. Wohadlo; S. Nester; J. Vaught; M. Tartan (Gas Technology Institute); R. Glickert (ESA Environmental Solutions)

2007-12-31T23:59:59.000Z

53

Oxygen Pathways and Carbon Dioxide Utilization in Methane Partial Oxidation in Ambient Temperature  

E-Print Network [OSTI]

- ronmental impact. Present technology uses steam reforming to produce synthesis gas which is converted into enhance- ment of the carbon balance of methane conversion by reforming with CO2 in order to "recycle

Mallinson, Richard

54

Process and apparatus for ammonia synthesis gas production  

SciTech Connect (OSTI)

An improved process is described for the production of ammonia synthesis gas which consists of: (a) catalytically reacting a hydrocarbon feed stream with steam in a primary reforming unit to form a primary reformed gas mixture containing hydrogen and carbon monoxide; (b) passing the primary reformed gas mixture to a secondary reforming unit for reaction of unconverted methane present therein with air, the amount of the air introduced to the secondary reforming unit being considerably in excess of that required to furnish the stoichiometric amount of nitrogen required for reaction with hydrogen for the ammonia synthesis; (c) subjecting the secondary reformed gas mixture to water gas shift conversion to convert most of the carbon monoxide present in the reformed gas mixture to hydrogen and carbon dioxide; (d) passing the thus-shifted gas mixture containing hydrogen, carbon dioxide, residual carbon monoxide, methane, argon and the excess nitrogen, without necessary treatment for removal of a major portion of the carbon dioxide content thereof and without methanation to remove carbon oxides to low levels, to a pressure swing adsorption system capable of selectively adsorbing carbon dioxide, carbon monoxide, methane and other impurities from the hydrogen and from a portion of the nitrogen present in the gas passed to the system.

Fuderer, A.

1986-06-03T23:59:59.000Z

55

Demonstration of Energy Efficient Steam Reforming in Microchannels for Automotive Fuel Processing  

SciTech Connect (OSTI)

A compact, energy efficient microchannel steam reforming system has been demonstrated. The unit generates sufficient reformate to provide H2 to a 10 kWe PEM fuel cell (when coupled with a water-gas shift and CO cleanup reactors). The overall volume of the reactor is 4.9 liters while that of the supporting network of heat exchangers is 1.7 liters . Use of a microchannel configuration in the steam reforming reactor produces rapid heat and mass transport which enables fast kinetics for the highly endothermic reaction. Heat is provided to the reactor by a combustion gas flowing in interleaved microchannels in cross flow with the reaction channels. A network of microchannel heat exchangers allows recovery of heat in the reformate product and combustion exhaust streams for use in vaporizing water and fuel, preheating reactants to reactor temperature and preheating combustion air. The microchannel architecture enables very compact and highly effective heat exchangers to be constructed. As a result of the heat exchange network, the system exhaust temperatures are typically ~50?C for the combustion gas and ~130?C for the reformate product while the reactor is operated at 750?C. While reforming isooctane at a rate sufficient to supply a 13.7 kWe fuel cell the system achieved 98.6% conversion with an estimated overall system efficiency after integration with WGS and PEM fuel cell of 44% (electrical output / LHV fuel). The efficiency estimate assumes integration with a WGS reactor (90% conversion CO to CO2 with 100% selectivity) and a PEM fuel cell (64% power conversion effectiveness with 85% H2 utilization for an overall 54% efficiency) and does not include parasitic losses for compression of combustion air. Acknowledgement The work described here was funded by the U.S. Department of Energy, Office of Transportation Technology as part of the OTT Fuel Cells Program.

Whyatt, Greg A.; TeGrotenhuis, Ward E.; Geeting, John GH; Davis, James M.; Wegeng, Robert S.; Pederson, Larry R.

2002-01-01T23:59:59.000Z

56

METHANE OXIDATION (AEROBIC) Helmut Brgmann  

E-Print Network [OSTI]

METHANE OXIDATION (AEROBIC) Helmut BĂŒrgmann Eawag, Swiss Federal Institute of Aquatic Science and Technology, Kastanienbaum, Switzerland Synonyms Methanotrophy Definition Methane oxidation is a microbial metabolic process for energy generation and carbon assimilation from methane that is carried out by specific

Wehrli, Bernhard

57

E-Print Network 3.0 - actinide reformer concept Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

OF PEANUT Summary: gasification -Storable inter. reforming: ethanol methanol methane Pyrolysis oil + + Figure 1. Overall concept... ENGINEERING SCALE UP OF RENEWABLE HYDROGEN...

58

The Optimization of Well Spacing in a Coalbed Methane Reservoir.  

E-Print Network [OSTI]

??Numerical reservoir simulation has been used to describe mechanism of methane gas desorption process, diffusion process, and fluid flow in a coalbed methane reservoir. The… (more)

Sinurat, Pahala Dominicus

2012-01-01T23:59:59.000Z

59

Process for producing methane from gas streams containing carbon monoxide and hydrogen  

DOE Patents [OSTI]

Carbon monoxide-containing gas streams are passed over a catalyst capable of catalyzing the disproportionation of carbon monoxide so as to deposit a surface layer of active surface carbon on the catalyst essentially without formation of inactive coke thereon. The surface layer is contacted with steam and is thus converted to methane and CO.sub.2, from which a relatively pure methane product may be obtained. While carbon monoxide-containing gas streams having hydrogen or water present therein can be used only the carbon monoxide available after reaction with said hydrogen or water is decomposed to form said active surface carbon. Although hydrogen or water will be converted, partially or completely, to methane that can be utilized in a combustion zone to generate heat for steam production or other energy recovery purposes, said hydrogen is selectively removed from a CO--H.sub.2 -containing feed stream by partial oxidation thereof prior to disproportionation of the CO content of said stream.

Frost, Albert C. (Congers, NY)

1980-01-01T23:59:59.000Z

60

,"Catalytic Reforming Downstream Processing of Fresh Feed Input"  

U.S. Energy Information Administration (EIA) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National and Regional Data; Row: NAICS Codes; Column: Energy SourcesWyoming"Coalbed Methane ProvedDry Natural GasMarketed Production

Note: This page contains sample records for the topic "methane reforming process" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Sorption-Enhanced Synthetic Natural Gas (SNG) Production from Syngas: A Novel Process Combining CO Methanation, Water-Gas Shift, and CO2 Capture  

SciTech Connect (OSTI)

Synthetic natural gas (SNG) production from syngas is under investigation again due to the desire for less dependency from imports and the opportunity for increasing coal utilization and reducing green house gas emission. CO methanation is highly exothermic and substantial heat is liberated which can lead to process thermal imbalance and deactivation of the catalyst. As a result, conversion per pass is limited and substantial syngas recycle is employed in conventional processes. Furthermore, the conversion of syngas to SNG is typically performed at moderate temperatures (275 to 325°C) to ensure high CH4 yields since this reaction is thermodynamically limited. In this study, the effectiveness of a novel integrated process for the SNG production from syngas at high temperature (i.e. 600?C) was investigated. This integrated process consists of combining a CO methanation nickel-based catalyst with a high temperature CO2 capture sorbent in a single reactor. Integration with CO2 separation eliminates the reverse-water-gas shift and the requirement for a separate water-gas shift (WGS) unit. Easing of thermodynamic constraint offers the opportunity of enhancing yield to CH4 at higher operating temperature (500-700șC) which also favors methanation kinetics and improves the overall process efficiency due to exploitation of reaction heat at higher temperatures. Furthermore, simultaneous CO2 capture eliminates green house gas emission. In this work, sorption-enhanced CO methanation was demonstrated using a mixture of a 68% CaO/32% MgAl2O4 sorbent and a CO methanation catalyst (Ni/Al2O3, Ni/MgAl2O4, or Ni/SiC) utilizing a syngas ratio (H2/CO) of 1, gas-hour-space velocity (GHSV) of 22 000 hr-1, pressure of 1 bar and a temperature of 600oC. These conditions resulted in ~90% yield to methane, which was maintained until the sorbent became saturated with CO2. By contrast, without the use of sorbent, equilibrium yield to methane is only 22%. Cyclic stability of the methanation catalyst and durability of the sorbent were also studied in the multiple carbonation-decarbonation cycle studies proving the potential of this integrated process in a practical application.

Lebarbier, Vanessa MC; Dagle, Robert A.; Kovarik, Libor; Albrecht, Karl O.; Li, Xiaohong S.; Li, Liyu; Taylor, Charles E.; Bao, Xinhe; Wang, Yong

2014-01-01T23:59:59.000Z

62

Liquid fuel reformer development: Autothermal reforming of Diesel fuel  

SciTech Connect (OSTI)

Argonne National Laboratory is developing a process to convert hydrocarbon fuels to clean hydrogen feeds for a polymer electrolyte fuel cell. The process incorporates an autothermal reforming catalyst that can process hydrocarbon feeds at lower temperatures than existing commercial catalysts. The authors have tested the catalyst with three diesel-type fuels: hexadecane, certified low-sulfur grade 1 diesel, and a standard grade 2 diesel. Hexadecane yielded products containing 60% hydrogen on a dry, nitrogen-free basis at 850 C, while maximum hydrogen product yields for the two diesel fuels were near 50%. Residual products in all cases included CO, CO{sub 2}, ethane, and methane. Further studies with grade 1 diesel showed improved conversion as the water:fuel ratio was increased from 1 to 2 at 850 C. Soot formation was reduced when the oxygen:carbon ratio was maintained at 1 at 850 C. There were no significant changes in hydrogen yield as the space velocity and the oxygen:fuel ratio were varied. Tests with a microchannel monolithic catalyst yielded similar or improved hydrogen levels at higher space velocities than with extruded pellets in a packed bed.

Pereira, C.; Bae, J-M.; Ahmed, S.; Krumpelt, M.

2000-07-24T23:59:59.000Z

63

POSSIBLE ROLE OF WETLANDS, PERMAFROST, AND METHANE HYDRATES IN THE METHANE  

E-Print Network [OSTI]

POSSIBLE ROLE OF WETLANDS, PERMAFROST, AND METHANE HYDRATES IN THE METHANE CYCLE UNDER FUTURE the available scientific literature on how natural sources and the atmospheric fate of methane may be affected by future climate change. We discuss how processes governing methane wetland emissions, per- mafrost thawing

Chappellaz, JĂ©rĂŽme

64

Process for reforming naphthene and paraffin-containing hydrocarbons in the naphtha boiling range and isomerizing C sub 5 -C sub 6 normal paraffin feedstock to produce a high octane gasoline  

SciTech Connect (OSTI)

This patent describes a process for reforming a naphthenic and paraffin-containing hydrocarbon feedstock to produce a reformate product having an increased octane rating by contacting the feedstock with a reforming catalyst in the presence of hydrogen at reforming conditions in a reforming zone, the reforming zone including a naphtha dehydrogenation zone and a paraffin dehydrocyclization zone wherein heated, pressurized hydrogen is added to the effluent stream from the naphtha dehydrogenation zone prior to charging the effluent stream to the paraffin dehydrocyclization zone to produce a first product stream comprising a gasoline range reformate product having an RON octane rating of at least about 90 and hydrogen wherein the reformate product is separated from the hydrogen in a reformate separation zone. It comprises: charging at least a portion of the heated, pressurized hydrogen with a C{sub 5}-C{sub 6} n-paraffin feedstock to an isomerization zone containing an isomerization catalyst at isomerization conditions to produce a second product stream containing an isomerized C{sub 5}-C{sub 6} product and passing the second product stream to the reformate separation zone and recovering at least a major portion of the isomerized C{sub 5}-C{sub 6} product with the reformate product.

Dalson, M.H.

1990-05-08T23:59:59.000Z

65

Steam reforming of fuel to hydrogen in fuel cells  

DOE Patents [OSTI]

A fuel cell capable of utilizing a hydrocarbon such as methane as fuel and having an internal dual catalyst system within the anode zone, the dual catalyst system including an anode catalyst supporting and in heat conducting relationship with a reforming catalyst with heat for the reforming reaction being supplied by the reaction at the anode catalyst.

Fraioli, Anthony V. (Hawthorne Woods, IL); Young, John E. (Woodridge, IL)

1984-01-01T23:59:59.000Z

66

Steam reforming of fuel to hydrogen in fuel cell  

DOE Patents [OSTI]

A fuel cell is described capable of utilizing a hydrocarbon such as methane as fuel and having an internal dual catalyst system within the anode zone, the dual catalyst system including an anode catalyst supporting and in heat conducting relationship with a reforming catalyst with heat for the reforming reaction being supplied by the reaction at the anode catalyst.

Young, J.E.; Fraioli, A.V.

1983-07-13T23:59:59.000Z

67

Quasielastic electron scattering from methane, methane-d4, methane-d2, ethylene, and 2-methylpropane  

E-Print Network [OSTI]

Quasielastic electron scattering from methane, methane-d4, methane-d2, ethylene, and 2-methylpropane, ethylene, methane, and two isotopically substituted methanes, CH2D2 and CD4, at a momentum constituent. For example, Fig. 1 of Ref. 2 shows that, for gaseous methane, above a certain momentum transfer

Hitchcock, Adam P.

68

Conversion of MixAlco Process Sludge to Liquid Transportation Fuels  

E-Print Network [OSTI]

of iron instead of cobalt is validated by the fact that the hydrogen production potential of biomass feedstock is low compared to steam reforming of methane which is usually accompanied by the WGS reaction. Since iron catalyst catalyzes the WGS...,33]. The pyrolysis of the MixAlco process sludge and other biomass feedstocks will generate syngas (H2 and CO) together with methane. External modification of the final syngas composition for use in the FTS catalyst may involve the steam reforming of the 3 CH...

Teiseh, Eliasu 1973-

2012-02-15T23:59:59.000Z

69

Journal of Catalysis 192, 316321 (2000) doi:10.1006/jcat.2000.2853, available online at http://www.idealibrary.com on  

E-Print Network [OSTI]

efficiency. Processes such as steam reforming of methane, partial oxidation of methane, and autothermal

Goodman, Wayne

2000-01-01T23:59:59.000Z

70

Enhanced coalbed methane recovery  

SciTech Connect (OSTI)

The recovery of coalbed methane can be enhanced by injecting CO{sub 2} in the coal seam at supercritical conditions. Through an in situ adsorption/desorption process the displaced methane is produced and the adsorbed CO{sub 2} is permanently stored. This is called enhanced coalbed methane recovery (ECBM) and it is a technique under investigation as a possible approach to the geological storage of CO{sub 2} in a carbon dioxide capture and storage system. This work reviews the state of the art on fundamental and practical aspects of the technology and summarizes the results of ECBM field tests. These prove the feasibility of ECBM recovery and highlight substantial opportunities for interdisciplinary research at the interface between earth sciences and chemical engineering.

Mazzotti, M.; Pini, R.; Storti, G. [ETH, Zurich (Switzerland). Inst. of Process Engineering

2009-01-15T23:59:59.000Z

71

Statistical validation and an empirical model of hydrogen production enhancement found by utilizing passive flow disturbance in the steam-reformation process  

SciTech Connect (OSTI)

A passive flow disturbance has been proven to enhance the conversion of fuel in a methanol-steam reformer. This study presents a statistical validation of the experiment based on a standard 2{sup k} factorial experiment design and the resulting empirical model of the enhanced hydrogen producing process. A factorial experiment design was used to statistically analyze the effects and interactions of various input factors in the experiment. Three input factors, including the number of flow disturbers, catalyst size, and reactant flow rate were investigated for their effects on the fuel conversion in the steam-reformation process. Based on the experimental results, an empirical model was developed and further evaluated with an uncertainty analysis and interior point data. (author)

Erickson, Paul A.; Liao, Chang-hsien [Department of Mechanical and Aeronautical Engineering, University of California, One Shields Avenue, Davis, CA 95616 (United States)

2007-11-15T23:59:59.000Z

72

Negative Valve Overlap Reforming Chemistry in Low-Oxygen Environments  

SciTech Connect (OSTI)

Fuel injection into the negative valve overlap (NVO) period is a common method for controlling combustion phasing in homogeneous charge compression ignition (HCCI) and other forms of advanced combustion. When fuel is injected into O2-deficient NVO conditions, a portion of the fuel can be converted to products containing significant levels of H2 and CO. Additionally, other short chain hydrocarbons are produced by means of thermal cracking, water-gas shift, and partial oxidation reactions. The present study experimentally investigates the fuel reforming chemistry that occurs during NVO. To this end, two very different experimental facilities are utilized and their results are compared. One facility is located at Oak Ridge National Laboratory, which uses a custom research engine cycle developed to isolate the NVO event from main combustion, allowing a steady stream of NVO reformate to be exhausted from the engine and chemically analyzed. The other experimental facility, located at Sandia National Laboratories, uses a dump valve to capture the exhaust from a single NVO event for analysis. Results from the two experiments are in excellent trend-wise agreement and indicate that the reforming process under low-O2 conditions produces substantial concentrations of H2, CO, methane, and other short-chain hydrocarbon species. The concentration of these species is found to be strongly dependent on fuel injection timing and injected fuel type, with weaker dependencies on NVO duration and initial temperature, indicating that NVO reforming is kinetically slow. Further, NVO reforming does not require a large energy input from the engine, meaning that it is not thermodynamically expensive. The implications of these results on HCCI and other forms of combustion are discussed in detail.

Szybist, James P [ORNL] [ORNL; Steeper, Richard R. [Sandia National Laboratories (SNL)] [Sandia National Laboratories (SNL); Splitter, Derek A [ORNL] [ORNL; Kalaskar, Vickey B [ORNL] [ORNL; Pihl, Josh A [ORNL] [ORNL; Daw, C Stuart [ORNL] [ORNL

2014-01-01T23:59:59.000Z

73

Thermodynamic evaluation of hydrogen production via bioethanol steam reforming  

SciTech Connect (OSTI)

In this article, a thermodynamic analysis for bioethanol steam reforming for hydrogen production is presented. Bioethanol is a newly proposed renewable energy carrier mainly produced from biomass fermentation. Reforming of bioethanol provides a promising method for hydrogen production from renewable resources. Steam reforming of ethanol (SRE) takes place under the action of a metal catalyst capable of breaking C-C bonds into smaller molecules. A large domain for the water/bioethanol molar ratio as well as the temperature and average pressure has been used in the present work. The interval of investigated temperature was 100-800°C, the pressure was in the range of 1-10 bar and the molar ratio was between 3-25. The variations of gaseous species concentration e.g. H{sub 2}, CO, CO{sub 2}, CH{sub 4} were analyzed. The concentrations of the main products (H{sub 2} and CO) at lower temperature are smaller than the ones at higher temperature due to by-products formation (methane, carbon dioxide, acetylene etc.). The concentration of H2 obtained in the process using high molar ratio (>20) is higher than the one at small molar ratio (near stoichiometric). When the pressure is increased the hydrogen concentration decreases. The results were compared with literature data for validation purposes.

Tasnadi-Asztalos, Zsolt; Cormos, Ana-Maria; Imre-Lucaci, Árpád; Cormos, C?lin C. [Babes-Bolyai University, Faculty of Chemistry and Chemical Engineering, Arany Janos 11, RO-400028, Cluj-Napoca (Romania)] [Babes-Bolyai University, Faculty of Chemistry and Chemical Engineering, Arany Janos 11, RO-400028, Cluj-Napoca (Romania)

2013-11-13T23:59:59.000Z

74

Methane Sulfonation A High-Yield Approach to the Sulfonation of  

E-Print Network [OSTI]

Methane Sulfonation A High-Yield Approach to the Sulfonation of Methane to Methanesulfonic Acid Initiated by H2O2 and a Metal Chloride** Sudip Mukhopadhyay and Alexis T. Bell* Methane is abundant reactivity of methane makes it difficult to develop commercially viable processes for methane conversion.[1

Bell, Alexis T.

75

Methane from UV-irradiated carbonaceous chondrites under simulated Martian conditions  

E-Print Network [OSTI]

Methane from UV-irradiated carbonaceous chondrites under simulated Martian conditions Andrew C process was studied for the production of methane from carbonaceous chondrites under simulated Martian conditions. Methane evolution rates from carbonaceous chondrites were found to be positively correlated

Schuerger, Andrew C.

76

Kinetic Consequences of Chemisorbed Oxygen Atoms during Methane Oxidation on Group VIII Metal Clusters  

E-Print Network [OSTI]

in practice through autothermal reforming, 19 a process inand catalyst deactivation. Autothermal reformers use O 2 inreactions. 7 These autothermal routes lead to sharp

Chin, Ya Huei

2011-01-01T23:59:59.000Z

77

DIRECT DECOMPOSITION OF METHANE TO HYDROGEN ON METAL LOADED ZEOLITE CATALYST  

SciTech Connect (OSTI)

The manufacture of hydrogen from natural gas is essential for the production of ultra clean transportation fuels. Not only is hydrogen necessary to upgrade low quality crude oils to high-quality, low sulfur ultra clean transportation fuels, hydrogen could eventually replace gasoline and diesel as the ultra clean transportation fuel of the future. Currently, refinery hydrogen is produced through the steam reforming of natural gas. Although efficient, the process is responsible for a significant portion of refinery CO2 emissions. This project is examining the direct catalytic decomposition of methane as an alternative to steam reforming. The energy required to produce one mole of hydrogen is slightly lower and the process does not require water-gas-shift or pressure-swing adsorption units. The decomposition process does not produce CO2 emissions and the product is not contaminated with CO -- a poison for PEM fuel cells. In this work we examined the direct catalytic decomposition of methane over a metal modified zeolite catalyst and the recovery of catalyst activity by calcination. A favorable production of hydrogen was obtained, when compared with previously reported nickel-zeolite supported catalysts. Reaction temperature had a strong influence on catalyst activity and on the type of carbon deposits. The catalyst utilized at 873 and 973 K could be regenerated without any significant loss of activity, however the catalyst utilized at 1073 K showed some loss of activity after regeneration.

Lucia M. Petkovic; Daniel M. Ginosar; Kyle C. Burch; Harry W. Rollins

2005-08-01T23:59:59.000Z

78

A study on coalbed methane reserve of Shanxi: Hedong coalfield reserve and its utilization  

SciTech Connect (OSTI)

Coalbed gas, i.e. coalbed methane, is considered an unconventional gas, formed during coal accumulation and preserved in coal seams. In the past, coalbed gas was considered a major hazard factor to the safety of mining and caused countless explosive events and great losses to the enterprises and even to the country. Early in 1960s and 70s, it was recognized that coalbed gas could be utilized as an energy resource and collected through tunnels in China. In 1995, the output of tunnel gas reached 500Mm{sup 3}, however, surface pumping is still at its beginning stage, test and appraisal; so far, no commercial development is being carried out in China. Hedong coalfield, situated in the west of Shanxi province and bordered by the Yellow River in the northwest and outcrop seams in the southeast, is 540km long (N-S) and 10--40 km wide (E-W) and covers an area of 17,000 km{sup 2} across 13 counties of Xinzou, Luliang, Linfen and Yuncheng prefectures. It is the No. 2 coalfield in Shanxi province and the well-known base of excellent coking coal and power coal in China. Hedong coalfield is not only rich in coal resource, but also in coalbed methane. This paper describes the geology of the coalfield (including structure, magmatic activity, coal seams and coal grade); the regularity of coalbed methane occurrence in the Hedong coalfield; the calculation of coalbed methane resource; and the use of coalbed methane for motor fuels and chemicals production. The total resource is 1468.93Gm{sup 3}. The production of motor fuels can be realized by the following processes: (a) synthetic methanol as substitute of gasoline; (b) F-T synthesis for synthetic gasoline and diesel oil; (c) Compressed natural gas as motor fuel; and (d) Liquefied natural gas as motor fuel. The production of organic chemicals is suggested with the following technology: (a) Two-stage steam reforming to convert methane to synthetic gas various organic chemicals can be produced therefrom; (b) Partial oxidation of methane to produce synthesis gas and acetylene; (c) Coalbed methane to produce hydrogen cyanide and chloromethanes; and (d) Coalbed methane to produce acrylonitrile, acetylene, ethylene, propylene and butylenes.

Kong, X.; Fan, R.; Hu, Y.; Wang, M.; Wang, M.; Chen, Z.; Li, M.; Peng, S. [Taiyuan Ke-jin Technology Development Service (China)

1997-12-31T23:59:59.000Z

79

Reforming Pyrolysis Aqueous Waste Streams to Process Hydrogen and Hydrocarbons Presentation for BETO 2015 Project Peer Review  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department ofT ib l L dDepartmentnews-flashes OfficeTexas |4 U.S.1: Reforming Pyrolysis

80

Data reconciliation and optimal operation of a catalytic naphtha reformer  

E-Print Network [OSTI]

-mail:skoge@chemeng.ntnu.no) #12;Abstract The naphtha reforming process converts low-octane gasoline blending compo- nents to high cases. #12;1 Introduction The naphtha reforming process converts low-octane gasoline blending compo-octane components for use in high-performance gasoline fuels. The reformer also has an important function

Skogestad, Sigurd

Note: This page contains sample records for the topic "methane reforming process" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Steam reforming utilizing high activity catalyst  

SciTech Connect (OSTI)

High activity, sulfur tolerant steam reforming catalysts are described comprising rhodium or nickel supported on lanthanum stabilized alumina or magnesium promoted lanthanum stabilized alumina. The catalysts have improved activity over conventionally used catalysts in the presence of sulfur containing hydrocarbon fuel (such as No. 2 fuel oil) in a steam reforming environment. The material has particular utility in autothermal, tubular, cyclic and adiabatic steam reforming processes.

Setzer, H. J.

1985-03-05T23:59:59.000Z

82

EA-1846: Demonstration of Carbon Dioxide Capture and Sequestration of Steam Methane Reforming Process Gas Used for Large-Scale Hydrogen Production, Port Arthur, Texas  

Broader source: Energy.gov [DOE]

DOE completed a final environmental assessment (EA) for a project under Area I of the Industrial Carbon Capture and Sequestration from Industrial Sources and Innovative Concepts for Beneficial CO2...

83

Production of methane-rich syngas from hydrocarbon fuels using multi-functional catalyst/capture agent  

DOE Patents [OSTI]

The disclosure provides a gasification process for the production of a methane-rich syngas at temperatures exceeding 700.degree. C. through the use of an alkali hydroxide MOH, using a gasification mixture comprised of at least 0.25 moles and less than 2 moles of water for each mole of carbon, and at least 0.15 moles and less than 2 moles of alkali hydroxide MOH for each mole of carbon. These relative amounts allow the production of a methane-rich syngas at temperatures exceeding 700.degree. C. by enabling a series of reactions which generate H.sub.2 and CH.sub.4, and mitigate the reforming of methane. The process provides a methane-rich syngas comprised of roughly 20% (dry molar percentage) CH.sub.4 at temperatures above 700.degree. C., and may effectively operate within an IGFC cycle at reactor temperatures between 700-900.degree. C. and pressures in excess of 10 atmospheres.

Siefert, Nicholas S; Shekhawat, Dushyant; Berry, David A; Surdoval, Wayne A

2014-12-30T23:59:59.000Z

84

Integrated autothermal reactor concepts for oxidative coupling and reforming of  

E-Print Network [OSTI]

#12;Integrated autothermal reactor concepts for oxidative coupling and reforming of methane #12-90-365-2985-3, DOI 10.3990/1.9789036529853 #12;INTEGRATED AUTOTHERMAL REACTOR CONCEPTS FOR OXIDATIVE COUPLING . . . . . . . . . . . . . . . . . . . . 31 2.5 Dual function catalyst particle . . . . . . . . . . . . . . . . . . . . . . 34 2.6 Autothermal

Twente, Universiteit

85

METHANE IN SUBSURFACE: MATHEMATICAL MODELING AND COMPUTATIONAL CHALLENGES  

E-Print Network [OSTI]

advanced models of adsorption occuring in coalbed methane recovery processes, and discuss the underlying methods, hysteresis, coalbed methane, mean-field equi- librium models AMS(MOS) subject classifications. 76 applications important for global climate and energy studies, namely Enhanced Coalbed Methane (ECBM) recovery

Peszynska, Malgorzata

86

Novel Reforming Catalysts  

SciTech Connect (OSTI)

Aqueous phase reforming is useful for processing oxygenated hydrocarbons to hydrogen and other more useful products. Current processing is hampered by the fact that oxide based catalysts are not stable under high temperature hydrothermal conditions. Silica in the form of structured MCM-41 is thermally a more stable support for Co and Ni than conventional high surface area amorphous silica but hydrothermal stability is not demonstrated. Carbon nanotube supports, in contrast, are highly stable under hydrothermal reaction conditions. In this project we show that carbon nanotubes are stable high activity/selectivity supports for the conversion of ethylene glycol to hydrogen.

Pfefferle, Lisa D; Haller, Gary L

2012-10-16T23:59:59.000Z

87

Recover heat from steam reforming  

SciTech Connect (OSTI)

Steam reforming is one of the most important chemical processes--it is used in the manufacture of ammonia, hydrogen, methanol, and many chemicals made from hydrogen and carbon monoxide. Furthermore, many current trends will increase its importance. For example, methanol for addition to gasoline is likely to be produced by steam reforming. Because steam reforming occurs at high temperatures--typically 750 C--900 C--it generates a large amount of waste heat. Clearly, heat recovery is crucial to process economics. A typical 50,000 Nm[sup 3]/h hydrogen plant using natural gas feed has a radiant heat duty of about 50 MW. At a radiant efficiency of 50% and fuel cost of $3/GJ, this means that the reformer fires $9 million worth of fuel per year. Obviously, this amount of fuel justifies a close loot at ways to reduce costs. This article first provides a brief overview of steam reforming. It then outlines the available heat-recovery options and explains how to select the best method.

Fleshman, J.D. (Foster Wheeler USA Corp., Livingston, NJ (United States))

1993-10-01T23:59:59.000Z

88

Hydraulic fracturing accelerates coalbed methane recovery  

SciTech Connect (OSTI)

Methane production from deep coal seams that never will be mined requires hydraulic fracturing for faster, optimal recovery. Since this can be a complex process, proper formation evaluation beforehand is essential, according to this paper.

Holditch, S.A. (Texas A and M Univ. (US)); Ely, J.W.; Semmelbeck, M.E.; Carter, R.H. (S.A. Holditch and Associates (US)); Hinkel, J.J.; Jeffrey, R.G. Jr. (Dowell Schlumberger (US))

1990-11-01T23:59:59.000Z

89

Development of a hydrogen generator for fuel cells based on the partial oxidation of methane  

SciTech Connect (OSTI)

As well known, the most acknowledged process for generation of hydrogen for fuel cells is based upon the steam reforming of methane or natural gas (SRM). The reaction is endothermic ({Delta}H{sub 298}= 206 kJ/mole) and high H{sub 2}O/CH{sub 4} ratios are required in order to limit coke formation at T higher than 1000 K. Moreover, it is a common practice that the process`s fuel economy is highly sensitive to proper heat fluxes and reactor design (tubular type) and to operational conditions. Efficient heat recovery can be accomplished only on large scale units (> 40,000 Nm{sup 3}/h), far from the range of interest of {open_quotes}on-site{close_quotes} fuel cells. Even if, to fit the needs of the fuel cell technology, medium sized external reforming units (50-200 Nm{sup 3} H{sub 2}/h) have been developed and/or planned for integration with both the first and the second generation fuel cells, amelioration in their heat recovery and efficiency is at the expense of an increased sophistication and therefore at higher per unit costs. In all cases, SRM requires an extra {open_quotes}fuel{close_quotes} supply (to substain the endothermicity of the reaction) in addition to stoichiometric requirements ({open_quotes}feed{close_quotes} gas). A valid alternative could be a process based on catalytic partial oxidation of CH{sub 4} (CSPOM), since the process is mildly exothermic ({Delta}H{sub 298}= -35.6 kJ/mole) and therefore not energy intensive. Consequently, great interest is expected from conversion of methane into syngas, if an autothermal, low energy intensive, compact and reliable process could be developed.

Recupero, V.; Torre, T.; Saija, G.; Fiordano, N. [Institute CNR-TAE, Lucia, Messina (Italy)

1996-12-31T23:59:59.000Z

90

Reforming of Liquid Hydrocarbons in a Novel Hydrogen-Selective Membrane-Based Fuel Processor  

SciTech Connect (OSTI)

In this work, asymmetric dense Pd/porous stainless steel composite membranes were fabricated by depositing palladium on the outer surface of the tubular support. The electroless plating method combined with an osmotic pressure field was used to deposit the palladium film. Surface morphology and microstructure of the composite membranes were characterized by SEM and EDX. The SEM and EDX analyses revealed strong adhesion of the plated pure palladium film on the substrate and dense coalescence of the Pd film. Membranes were further characterized by conducting permeability experiments with pure hydrogen, nitrogen, and helium gases at temperatures from 325 to 450 C and transmembrane pressure differences from 5 to 45 psi. The permeation results showed that the fabricated membranes have both high hydrogen permeability and selectivity. For example, the hydrogen permeability for a composite membrane with a 20 {micro}m Pd film was 3.02 x 10{sup -5} moles/m{sup 2}.s.Pa{sup 0.765} at 450 C. Hydrogen/nitrogen selectivity for this composite membrane was 1000 at 450 C with a transmembrane pressure difference of 14.7 psi. Steam reforming of methane is one of the most important chemical processes in hydrogen and syngas production. To investigate the usefulness of palladium-based composite membranes in membrane-reactor configuration for simultaneous production and separation of hydrogen, steam reforming of methane by equilibrium shift was studied. The steam reforming of methane using a packed-bed inert membrane tubular reactor (PBIMTR) was simulated. A two-dimensional pseudo-homogeneous reactor model with parallel flow configuration was developed for steam reforming of methane. The shell volume was taken as the feed and sweep gas was fed to the inside of the membrane tube. Radial diffusion was taken into account for concentration gradient in the radial direction due to hydrogen permeation through the membrane. With appropriate reaction rate expressions, a set of partial differential equations was derived using the continuity equation for the reaction system and then solved by finite difference method with appropriate boundary and initial conditions. An iterative scheme was used to obtain a converged solution. Membrane reactor performance was compared to that in a traditional non-membrane packed-bed reactor (PBR). Their performances were also compared with thermodynamic equilibrium values achievable in a conventional non-membrane reactor. Numerical results of the models show that the methane conversions in the PBIMTR are always higher than that in the PBR, as well as thermodynamic equilibrium conversions. For instance, at a reaction pressure of 6 atm, a temperature of 650 C, a space velocity of 900/16.0 SCCM/gm{sub cat}, a steam to methane molar feed ratio of 3.0, a sweep ratio of 0.15, the conversion in the membrane reactor is about 86.5%, while the conversion in the non-membrane reactor is about 50.8%. The corresponding equilibrium conversion is about 56.4%. The effects on the degree of conversion and hydrogen yield were analyzed for different parameters such as temperature, reactor pressure, feed and sweep flow rate, feed molar ratio, and space time. From the analysis of the model results, it is obvious that the membrane reactor operation can be optimized for conversion or yield through the choice of proper operating and design parameters. Comparisons with available literature data for both membrane and non-membrane reactors showed a good agreement.

Shamsuddin Ilias

2006-03-10T23:59:59.000Z

91

Methane Fluxes Between Terrestrial Ecosystems and the Atmosphere at Northern High Latitudes During the Past Century: A retrospective analysis with a process-based biogeochemistry model  

E-Print Network [OSTI]

We develop and use a new version of the Terrestrial Ecosystem Model (TEM) to study how rates of methane (CH4) emissions and consumption in high-latitude soils of the Northern Hemisphere have changed over the past century ...

Zhuang, Qianlai.

92

Emmanuel Picavet and Caroline Guibet Lafaye1 Principles and compromise in reform-related negotiation processes2  

E-Print Network [OSTI]

-following, when the rules are fairly general and call for interpretation (and this is generally the case when in the application and interpretation of underlying principles, which are 1 Respectively : Université Paris-1 of negotiation processes and for proper counselling to agents who take part in such processes. In particular

Paris-Sud XI, Université de

93

Methane production by attached film  

DOE Patents [OSTI]

A method for purifying wastewater of biodegradable organics by converting the organics to methane and carbon dioxide gases is disclosed, characterized by the use of an anaerobic attached film expanded bed reactor for the reaction process. Dilute organic waste material is initially seeded with a heterogeneous anaerobic bacteria population including a methane-producing bacteria. The seeded organic waste material is introduced into the bottom of the expanded bed reactor which includes a particulate support media coated with a polysaccharide film. A low-velocity upward flow of the organic waste material is established through the bed during which the attached bacterial film reacts with the organic material to produce methane and carbon dioxide gases, purified water, and a small amount of residual effluent material. The residual effluent material is filtered by the film as it flows upwardly through the reactor bed. In a preferred embodiment, partially treated effluent material is recycled from the top of the bed to the bottom of the bed for further treatment. The methane and carbon dioxide gases are then separated from the residual effluent material and purified water.

Jewell, William J. (202 Eastwood Ave., Ithaca, NY 14850)

1981-01-01T23:59:59.000Z

94

Methane Hydrate Field Program  

SciTech Connect (OSTI)

This final report document summarizes the activities undertaken and the output from three primary deliverables generated during this project. This fifteen month effort comprised numerous key steps including the creation of an international methane hydrate science team, determining and reporting the current state of marine methane hydrate research, convening an international workshop to collect the ideas needed to write a comprehensive Marine Methane Hydrate Field Research Plan and the development and publication of that plan. The following documents represent the primary deliverables of this project and are discussed in summary level detail in this final report. • Historical Methane Hydrate Project Review Report • Methane Hydrate Workshop Report • Topical Report: Marine Methane Hydrate Field Research Plan • Final Scientific/Technical Report

None

2013-12-31T23:59:59.000Z

95

Assessment of the SRI Gasification Process for Syngas Generation with HTGR Integration -- White Paper  

SciTech Connect (OSTI)

This white paper is intended to compare the technical and economic feasibility of syngas generation using the SRI gasification process coupled to several high-temperature gas-cooled reactors (HTGRs) with more traditional HTGR-integrated syngas generation techniques, including: (1) Gasification with high-temperature steam electrolysis (HTSE); (2) Steam methane reforming (SMR); and (3) Gasification with SMR with and without CO2 sequestration.

A.M. Gandrik

2012-04-01T23:59:59.000Z

96

SAES ST 909 PILOT SCALE METHANE CRACKING TESTS  

SciTech Connect (OSTI)

Pilot scale (500 gram) SAES St 909 methane cracking tests were conducted to determine material performance for tritium process applications. Tests that ran up to 1400 hours have been performed at 700 C, 202.7 kPa (1520 torr) with a 30 sccm feed of methane, with various impurities, in a 20 vol% hydrogen, balance helium, stream. A 2.5 vol% methane feed was reduced below 30 ppm for 631 hours. A feed of 1.1 vol% methane plus 1.4 vol% carbon dioxide was reduced below 30 ppm for 513 hours. The amount of carbon dioxide gettered by St 909 can be equated to an equivalent amount of methane gettered to estimate a reduced bed life for methane cracking. The effect of 0.4 vol % and 2.1 vol% nitrogen in the feed reduced the time to exceed 30 ppm methane to 362 and 45 hours, respectively, but the nitrogen equivalence to reduced methane gettering capacity was found to be dependent on the nitrogen feed composition. Decreased hydrogen concentrations increased methane getter rates while a drop of 30 C in one bed zone increased methane emissions by over a factor of 30. The impact of gettered nitrogen can be somewhat minimized if the nitrogen feed to the bed has been stopped and sufficient time given to recover the methane cracking rate.

Klein, J; Henry Sessions, H

2007-07-02T23:59:59.000Z

97

Methane Digester Loan Program  

Broader source: Energy.gov [DOE]

Established in 1998, the Minnesota Dept. of Agriculture Methane Digester Loan Program helps livestock producers install on-farm anaerobic digesters used for the production of electricity by...

98

Methanation assembly using multiple reactors  

DOE Patents [OSTI]

A methanation assembly for use with a water supply and a gas supply containing gas to be methanated in which a reactor assembly has a plurality of methanation reactors each for methanating gas input to the assembly and a gas delivery and cooling assembly adapted to deliver gas from the gas supply to each of said methanation reactors and to combine water from the water supply with the output of each methanation reactor being conveyed to a next methanation reactor and carry the mixture to such next methanation reactor.

Jahnke, Fred C.; Parab, Sanjay C.

2007-07-24T23:59:59.000Z

99

Mechanistic Studies on the Hydroxylation of Methane by Methane Monooxygenase  

E-Print Network [OSTI]

Mechanistic Studies on the Hydroxylation of Methane by Methane Monooxygenase Mu-Hyun Baik, Martin 2393 3.1. KIE in Methane Oxidations 2394 3.2. Primary and Secondary KIEs 2396 3.3. Other KIEs 2396 3 are bacteria that live on methane as their only source of carbon.1 The first step in their utilization

Baik, Mu-Hyun

100

Immigration reform and California agriculture  

E-Print Network [OSTI]

reform and California agriculture Philip Martin Professor,proposals for California agriculture. Immigration reformCenter. 196 CALIFORNIA AGRICULTURE • VOLUME 67 , NUMBER 4

Martin, Philip

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "methane reforming process" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Data reconciliation and optimal operation of a catalytic naphtha reformer  

E-Print Network [OSTI]

-mail:skoge@chemeng.ntnu.no) #12;Abstract The naphtha reforming process converts low-octane gasoline blending compo- nents to high process converts low-octane gasoline blending compo- nents to high-octane components for use in high-octane components for use in high-performance gasoline fuels. The reformer also has a important function

Skogestad, Sigurd

102

Partial oxidation fuel reforming for automotive power systems.  

SciTech Connect (OSTI)

For widespread use of fuel cells to power automobiles in the near future, it is necessary to convert gasoline or other transportation fuels to hydrogen on-board the vehicle. Partial oxidation reforming is particularly suited to this application as it eliminates the need for heat exchange at high temperatures. Such reformers offer rapid start and good dynamic performance. Lowering the temperature of the partial oxidation process, which requires the development of a suitable catalyst, can increase the reforming efficiency. Catalytic partial oxidation (or autothermal) reformers and non-catalytic partial oxidation reformers developed by various organizations are presently undergoing testing and demonstration. This paper summarizes the process chemistries as well as recent test data from several different reformers operating on gasoline, methanol, and other fuels.

Ahmed, S.; Chalk, S.; Krumpelt, M.; Kumar, R.; Milliken, J.

1999-09-07T23:59:59.000Z

103

FLUIDIZABLE CATALYSTS FOR PRODUCING HYDROGEN BY STEAM REFORMING BIOMASS PYROLYSIS LIQUIDS  

E-Print Network [OSTI]

FLUIDIZABLE CATALYSTS FOR PRODUCING HYDROGEN BY STEAM REFORMING BIOMASS PYROLYSIS LIQUIDS Kimberly established that biomass pyrolysis oil could be steam-reformed to generate hydrogen using non pyrolysis oil could be almost stoichiometrically converted to hydrogen. However, process performance

104

Electrochemical methane sensor  

DOE Patents [OSTI]

A method and instrument including an electrochemical cell for the detection and measurement of methane in a gas by the oxidation of methane electrochemically at a working electrode in a nonaqueous electrolyte at a voltage about 1.4 volts vs R.H.E. (the reversible hydrogen electrode potential in the same electrolyte), and the measurement of the electrical signal resulting from the electrochemical oxidation.

Zaromb, S.; Otagawa, T.; Stetter, J.R.

1984-08-27T23:59:59.000Z

105

Mixed Ionic/Electronic Conducting Ceramic Membranes for Oxygen-Assisted CO2 Reforming  

E-Print Network [OSTI]

Incorporating a SrFeCo0.5Ox (SFC) membrane into a CO2 reforming reactor doubles methane conversion with a powder Pt/ZrO2 catalyst. The deactivation of both Pt/ZrO2 and a Pt/CeZrO2 catalyst is also retarded substantially. Catalyst performance...

Slade, David

2010-03-29T23:59:59.000Z

106

Membrane-augmented cryogenic methane/nitrogen separation  

DOE Patents [OSTI]

A membrane separation process combined with a cryogenic separation process for treating a gas stream containing methane, nitrogen and at least one other component. The membrane separation process works by preferentially permeating methane and the other component and rejecting nitrogen. The process is particularly useful in removing components such as water, carbon dioxide or C.sub.3+ hydrocarbons that might otherwise freeze and plug the cryogenic equipment.

Lokhandwala, Kaaeid (Menlo Park, CA)

1997-01-01T23:59:59.000Z

107

Membrane-augmented cryogenic methane/nitrogen separation  

DOE Patents [OSTI]

A membrane separation process is described which is combined with a cryogenic separation process for treating a gas stream containing methane, nitrogen and at least one other component. The membrane separation process works by preferentially permeating methane and the other component and rejecting nitrogen. The process is particularly useful in removing components such as water, carbon dioxide or C{sub +2} hydrocarbons that might otherwise freeze and plug the cryogenic equipment. 10 figs.

Lokhandwala, K.

1997-07-15T23:59:59.000Z

108

Direct use of methane in coal liquefaction  

DOE Patents [OSTI]

This invention relates to a process for converting solid carbonaceous material, such as coal, to liquid and gaseous hydrocarbons utilizing methane, generally at a residence time of about 20-120 minutes at a temperature of 250.degree.-750.degree. C., preferably 350.degree.-450.degree. C., pressurized up to 6000 psi, and preferably in the 1000-2500 psi range, preferably directly utilizing methane 50-100% by volume in a mix of methane and hydrogen. A hydrogen donor solvent or liquid vehicle such as tetralin, tetrahydroquinoline, piperidine, and pyrolidine may be used in a slurry mix where the solvent feed is 0-100% by weight of the coal or carbonaceous feed. Carbonaceous feed material can either be natural, such as coal, wood, oil shale, petroleum, tar sands, etc., or man-made residual oils, tars, and heavy hydrocarbon residues from other processing systems.

Sundaram, Muthu S. (Shoreham, NY); Steinberg, Meyer (Melville, NY)

1987-01-01T23:59:59.000Z

109

Direct use of methane in coal liquefaction  

DOE Patents [OSTI]

This invention relates to a process for converting solid carbonaceous material, such as coal, to liquid and gaseous hydrocarbons utilizing methane, generally at a residence time of about 20 to 120 minutes at a temperature of 250 to 750/sup 0/C, preferably 350 to 450/sup 0/C, pressurized up to 6000 psi, and preferably in the 1000 to 2500 psi range, preferably directly utilizing methane 50 to 100% by volume in a mix of methane and hydrogen. A hydrogen donor solvent or liquid vehicle such as tetralin, tetrahydroquinoline, piperidine, and pyrolidine may be used in a slurry mix where the solvent feed is 0 to 100% by weight of the coal or carbonaceous feed. Carbonaceous feed material can either be natural, such as coal, wood, oil shale, petroleum, tar sands, etc., or man-made residual oils, tars, and heavy hydrocarbon residues from other processing systems. 1 fig.

Sundaram, M.S.; Steinberg, M.

1985-06-19T23:59:59.000Z

110

Catalytic reforming methods  

DOE Patents [OSTI]

A catalytic reforming method is disclosed herein. The method includes sequentially supplying a plurality of feedstocks of variable compositions to a reformer. The method further includes adding a respective predetermined co-reactant to each of the plurality of feedstocks to obtain a substantially constant output from the reformer for the plurality of feedstocks. The respective predetermined co-reactant is based on a C/H/O atomic composition for a respective one of the plurality of feedstocks and a predetermined C/H/O atomic composition for the substantially constant output.

Tadd, Andrew R; Schwank, Johannes

2013-05-14T23:59:59.000Z

111

LANDFILL OPERATION FOR CARBON SEQUESTRATION AND MAXIMUM METHANE EMISSION CONTROL  

SciTech Connect (OSTI)

''Conventional'' waste landfills emit methane, a potent greenhouse gas, in quantities such that landfill methane is a major factor in global climate change. Controlled landfilling is a novel approach to manage landfills for rapid completion of total gas generation, maximizing gas capture and minimizing emissions of methane to the atmosphere. With controlled landfilling, methane generation is accelerated and brought to much earlier completion by improving conditions for biological processes (principally moisture levels) in the landfill. Gas recovery efficiency approaches 100% through use of surface membrane cover over porous gas recovery layers operated at slight vacuum. A field demonstration project's results at the Yolo County Central Landfill near Davis, California are, to date, highly encouraging. Two major controlled landfilling benefits would be the reduction of landfill methane emissions to minuscule levels, and the recovery of greater amounts of landfill methane energy in much shorter times than with conventional landfill practice. With the large amount of US landfill methane generated, and greenhouse potency of methane, better landfill methane control can play a substantial role in reduction of US greenhouse gas emissions.

Don Augenstein

1999-01-11T23:59:59.000Z

112

UPGRADING METHANE USING ULTRA-FAST THERMAL SWING ADSORPTION  

SciTech Connect (OSTI)

The purpose of this project is to design and demonstrate an approach to upgrade low-BTU methane streams from coal mines to pipeline-quality natural gas. The objective of Phase I of the project was to assess the feasibility of upgrading low-Btu methane streams using ultra-fast thermal swing adsorption (TSA) using Velocys' modular microchannel process technology. The project is on schedule and under budget. For Task 1.1, the open literature, patent information, and vendor contacts were surveyed to identify adsorbent candidates for experimental validation and subsequent demonstration in an MPT-based ultra-fast TSA separation for methane upgrading. The leading candidates for preferential adsorption of methane over nitrogen are highly microporous carbons. A Molecular Gate{trademark} zeolite from Engelhard Corporation has emerged as a candidate. For Task 1.2, experimental evaluation of adsorbents was initiated, and data were collected on carbon (MGN-101) from PICA, Inc. This carbon demonstrated a preferential capacity for methane over nitrogen, as well as a reasonable thermal swing differential capacity for a 90% methane and 10% nitrogen mixture. A similar methane swing capacity at 2 psig was measured. The mixture composition is relevant because gob gas contains nearly 85% methane and must be purified to 97% methane for pipeline quality.

Anna Lee Tonkovich

2004-01-01T23:59:59.000Z

113

Journal of Electron Spectroscopy and Related Phenomena 155 (2007) 2834 Electron Compton scattering from methane and methane-d4  

E-Print Network [OSTI]

from methane and methane-d4 G. Coopera, A.P. Hitchcocka,, C.A. Chatzidimitriou-Dreismannb, M. Vosc]. © 2006 Elsevier B.V. All rights reserved. Keywords: Quasi-elastic electron scattering; Methane; CD4

Hitchcock, Adam P.

114

NETL - Fuel Reforming Facilities  

ScienceCinema (OSTI)

Research using NETL's Fuel Reforming Facilities explores catalytic issues inherent in fossil-energy related applications, including catalyst synthesis and characterization, reaction kinetics, catalyst activity and selectivity, catalyst deactivation, and stability.

None

2014-06-27T23:59:59.000Z

115

NETL - Fuel Reforming Facilities  

SciTech Connect (OSTI)

Research using NETL's Fuel Reforming Facilities explores catalytic issues inherent in fossil-energy related applications, including catalyst synthesis and characterization, reaction kinetics, catalyst activity and selectivity, catalyst deactivation, and stability.

None

2013-06-12T23:59:59.000Z

116

Exploiting coalbed methane and protecting the global environment  

SciTech Connect (OSTI)

The global climate change caused by greenhouse gases (GHGs) emission has received wide attention from all countries in the world. Global environmental protection as a common problem has confronted the human being. As a main component of coalbed methane, methane is an important factor influencing the production safety of coal mine and threatens the lives of miners. The recent research on environment science shows that methane is a very harmful GHG. Although methane gas has very little proportion in the GHGs emission and its stayed period is also very short, it has very obvious impact on the climate change. From the estimation, methane emission in the coal-mining process is only 10% of the total emission from human`s activities. As a clean energy, Methane has mature recovery technique before, during and after the process of mining. Thus, coalbed methane is the sole GHG generated in the human`s activities and being possible to be reclaimed and utilized. Compared with the global greenhouse effect of other GHGs emission abatement, coalbed methane emission abatement can be done in very low cost with many other benefits: (1) to protect global environment; (2) to improve obviously the safety of coal mine; and (3) to obtain a new kind of clean energy. Coal is the main energy in China, and coalbed contains very rich methane. According to the exploration result in recent years, about 30000{approximately}35000 billion m{sup 2} methane is contained in the coalbed below 2000 m in depth. China has formed a good development base in the field of reclamation and utilization of coalbed methane. The author hopes that wider international technical exchange and cooperation in the field will be carried out.

Yuheng, Gao

1996-12-31T23:59:59.000Z

117

BEHIND THE VEIL THE REFORM OF ISLAM IN INTER-WAR ALBANIA  

E-Print Network [OSTI]

107 BEHIND THE VEIL THE REFORM OF ISLAM IN INTER-WAR ALBANIA OR THE SEARCH FOR A "MODERN" of the country. The dominant role of secularist elites paved the way for the "reform of Islam." This process in the organization and reform of official religious institutions. For example, it interfered in the organization

Boyer, Edmond

118

Utilization of fuel cells to beneficially use coal mine methane. Final report  

SciTech Connect (OSTI)

DOE has been given the responsibility to encourage industry to recover and use methane that is currently being released to the atmosphere. At this time the only method being employed at the Left Fork Mine to remove methane is the mine ventilation system. The methane content was measured at one one-hundredth of a percent. To prevent this methane from being vented to the atmosphere, degasification wells are proposed. To use the coal mine methane, it is proposed to use phosphoric-acid fuel cells to convert methane to electric power. These fuel cells contain (1) a steam reformer to convert the methane to hydrogen (and carbon dioxide), (2) the fuel cell stack, and (3) a power conditioner that provides 200 kW of 60 Hz alternating current output. The environmental impacts and benefits of using this technology ware summarized in the report. The study indicates the methane emission reduction that could be achieved on a national and Global level. The important point being that this technology is economically viable as is demonstrated in the report.

Brown, J.T.; O`Brien, D.G.; Miller, A.R.; Atkins, R.; Sanders, M.

1996-03-01T23:59:59.000Z

119

The basics of coalbed methane  

SciTech Connect (OSTI)

The report is an overview of coalbed methane (CBM), also known as coal seam gas. It provides an overview of what coalbed methane is and the current status of global coalbed methane exploration and production. Topics covered in the report include: An analysis of the natural gas industry, including current and future production, consumption, and reserves; A detailed description of coalbed methane, its characteristics, and future potential; An analysis of the key business factors that are driving the increased interest in coalbed methane; An analysis of the barriers that are hindering the development of coalbed methane; An overview of the technologies used for coalbed methane production and water treatment; and Profiles of key coalbed methane producing countries. 25 figs., 5 tabs., 1 app.

NONE

2006-12-15T23:59:59.000Z

120

ISSUE PAPER METHANE AVOIDANCE FROM  

E-Print Network [OSTI]

ISSUE PAPER METHANE AVOIDANCE FROM COMPOSTING An Issue Paper for the: Climate Action Reserve...........................................................................................................39 6.2. Standard Methods for Quantifying Methane from Organic Waste in Landfills...40 6.3. GHG

Brown, Sally

Note: This page contains sample records for the topic "methane reforming process" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

5, 94059445, 2005 Methane emissions  

E-Print Network [OSTI]

ACPD 5, 9405­9445, 2005 Methane emissions from SCIAMACHY observations J. F. Meirink et al. Title and Physics Discussions Sensitivity analysis of methane emissions derived from SCIAMACHY observations through, 9405­9445, 2005 Methane emissions from SCIAMACHY observations J. F. Meirink et al. Title Page Abstract

Paris-Sud XI, Université de

122

4, 9931057, 2007 Methane hydrate  

E-Print Network [OSTI]

BGD 4, 993­1057, 2007 Methane hydrate stability and anthropogenic climate change D. Archer Title Discussions Biogeosciences Discussions is the access reviewed discussion forum of Biogeosciences Methane 2007 Correspondence to: D. Archer (d-archer@uchicago.edu) 993 #12;BGD 4, 993­1057, 2007 Methane hydrate

Paris-Sud XI, Université de

123

5, 243270, 2008 Methane emissions  

E-Print Network [OSTI]

BGD 5, 243­270, 2008 Methane emissions from plant biomass I. Vigano et al. Title Page Abstract and temperature on the emission of methane from plant biomass and structural components I. Vigano 1 , H. van.roeckmann@phys.uu.nl) 243 #12;BGD 5, 243­270, 2008 Methane emissions from plant biomass I. Vigano et al. Title Page Abstract

Paris-Sud XI, Université de

124

The Tri--Methane Rearrangement  

E-Print Network [OSTI]

The Tri--Methane Rearrangement #12;Cirkva, Vladimir; Zuraw, Michael J.; Zimmerman, Howard E.* Department of Chemistry, University of Wisconsin, Madison, WI 53706 #12;INTRODUCTION The tri--methane of a cyclopentene 5a, but only in crystalline medium. However, in the solution photochemistry of tri--methane system

Cirkva, Vladimir

125

6, 68416852, 2006 Methane emission  

E-Print Network [OSTI]

ACPD 6, 6841­6852, 2006 Methane emission from savanna grasses E. Sanhueza and L. Donoso Title Page Chemistry and Physics Discussions Methane emission from tropical savanna Trachypogon sp. grasses E. Sanhueza;ACPD 6, 6841­6852, 2006 Methane emission from savanna grasses E. Sanhueza and L. Donoso Title Page

Boyer, Edmond

126

The Tri--Methane Rearrangement  

E-Print Network [OSTI]

The Tri--Methane Rearrangement #12;CĂ­rkva, VladimĂ­r; Zuraw, Michael J.; Zimmerman, Howard E.* Department of Chemistry, University of Wisconsin, Madison, WI 53706 #12;INTRODUCTION The tri--methane of a cyclopentene 5a, but only in crystalline medium. However, in the solution photochemistry of tri--methane system

Cirkva, Vladimir

127

5, 23052341, 2008 Anaerobic methane  

E-Print Network [OSTI]

BGD 5, 2305­2341, 2008 Anaerobic methane oxidation in Black Sea sediments N. J. Knab et al. Title of Biogeosciences Regulation of anaerobic methane oxidation in sediments of the Black Sea N. J. Knab1 , B. A. Cragg2­2341, 2008 Anaerobic methane oxidation in Black Sea sediments N. J. Knab et al. Title Page Abstract

Paris-Sud XI, Université de

128

Thermodynamics of Hydrogen Production from Dimethyl Ether Steam Reforming and Hydrolysis  

SciTech Connect (OSTI)

The thermodynamic analyses of producing a hydrogen-rich fuel-cell feed from the process of dimethyl ether (DME) steam reforming were investigated as a function of steam-to-carbon ratio (0-4), temperature (100 C-600 C), pressure (1-5 atm), and product species: acetylene, ethanol, methanol, ethylene, methyl-ethyl ether, formaldehyde, formic acid, acetone, n-propanol, ethane and isopropyl alcohol. Results of the thermodynamic processing of dimethyl ether with steam indicate the complete conversion of dimethyl ether to hydrogen, carbon monoxide and carbon dioxide for temperatures greater than 200 C and steam-to-carbon ratios greater than 1.25 at atmospheric pressure (P = 1 atm). Increasing the operating pressure was observed to shift the equilibrium toward the reactants; increasing the pressure from 1 atm to 5 atm decreased the conversion of dimethyl ether from 99.5% to 76.2%. The order of thermodynamically stable products in decreasing mole fraction was methane, ethane, isopropyl alcohol, acetone, n-propanol, ethylene, ethanol, methyl-ethyl ether and methanol--formaldehyde, formic acid, and acetylene were not observed. The optimal processing conditions for dimethyl ether steam reforming occurred at a steam-to-carbon ratio of 1.5, a pressure of 1 atm, and a temperature of 200 C. Modeling the thermodynamics of dimethyl ether hydrolysis (with methanol as the only product considered), the equilibrium conversion of dimethyl ether is limited. The equilibrium conversion was observed to increase with temperature and steam-to-carbon ratio, resulting in a maximum dimethyl ether conversion of approximately 68% at a steam-to-carbon ratio of 4.5 and a processing temperature of 600 C. Thermodynamically, dimethyl ether processed with steam can produce hydrogen-rich fuel-cell feeds--with hydrogen concentrations exceeding 70%. This substantiates dimethyl ether as a viable source of hydrogen for PEM fuel cells.

T.A. Semelsberger

2004-10-01T23:59:59.000Z

129

Plasmatron Fuel Reformer Development and Internal Combustion...  

Broader source: Energy.gov (indexed) [DOE]

Plasmatron Fuel Reformer Development and Internal Combustion Engine Vehicle Applications Plasmatron Fuel Reformer Development and Internal Combustion Engine Vehicle Applications...

130

Reformers for the production of hydrogen from methanol and alternative fuels for fuel cell powered vehicles  

SciTech Connect (OSTI)

The objective of this study was (i) to assess the present state of technology of reformers that convert methanol (or other alternative fuels) to a hydrogen-rich gas mixture for use in a fuel cell, and (ii) to identify the R&D needs for developing reformers for transportation applications. Steam reforming and partial oxidation are the two basic types of fuel reforming processes. The former is endothermic while the latter is exothermic. Reformers are therefore typically designed as heat exchange systems, and the variety of designs used includes shell-and-tube, packed bed, annular, plate, and cyclic bed types. Catalysts used include noble metals and oxides of Cu, Zn, Cr, Al, Ni, and La. For transportation applications a reformer must be compact, lightweight, and rugged. It must also be capable of rapid start-up and good dynamic performance responsive to fluctuating loads. A partial oxidation reformer is likely to be better than a steam reformer based on these considerations, although its fuel conversion efficiency is expected to be lower than that of a steam reformer. A steam reformer better lends itself to thermal integration with the fuel cell system; however, the thermal independence of the reformer from the fuel cell stack is likely to yield much better dynamic performance of the reformer and the fuel cell propulsion power system. For both steam reforming and partial oxidation reforming, research is needed to develop compact, fast start-up, and dynamically responsive reformers. For transportation applications, steam reformers are likely to prove best for fuel cell/battery hybrid power systems, and partial oxidation reformers are likely to be the choice for stand-alone fuel cell power systems.

Kumar, R.; Ahmed, S.; Krumpelt, M.; Myles, K.M.

1992-08-01T23:59:59.000Z

131

Reformers for the production of hydrogen from methanol and alternative fuels for fuel cell powered vehicles  

SciTech Connect (OSTI)

The objective of this study was (i) to assess the present state of technology of reformers that convert methanol (or other alternative fuels) to a hydrogen-rich gas mixture for use in a fuel cell, and (ii) to identify the R D needs for developing reformers for transportation applications. Steam reforming and partial oxidation are the two basic types of fuel reforming processes. The former is endothermic while the latter is exothermic. Reformers are therefore typically designed as heat exchange systems, and the variety of designs used includes shell-and-tube, packed bed, annular, plate, and cyclic bed types. Catalysts used include noble metals and oxides of Cu, Zn, Cr, Al, Ni, and La. For transportation applications a reformer must be compact, lightweight, and rugged. It must also be capable of rapid start-up and good dynamic performance responsive to fluctuating loads. A partial oxidation reformer is likely to be better than a steam reformer based on these considerations, although its fuel conversion efficiency is expected to be lower than that of a steam reformer. A steam reformer better lends itself to thermal integration with the fuel cell system; however, the thermal independence of the reformer from the fuel cell stack is likely to yield much better dynamic performance of the reformer and the fuel cell propulsion power system. For both steam reforming and partial oxidation reforming, research is needed to develop compact, fast start-up, and dynamically responsive reformers. For transportation applications, steam reformers are likely to prove best for fuel cell/battery hybrid power systems, and partial oxidation reformers are likely to be the choice for stand-alone fuel cell power systems.

Kumar, R.; Ahmed, S.; Krumpelt, M.; Myles, K.M.

1992-08-01T23:59:59.000Z

132

Coal-Derived Warm Syngas Purification and CO2 Capture-Assisted Methane Production  

SciTech Connect (OSTI)

Gasifier-derived syngas from coal has many applications in the area of catalytic transformation to fuels and chemicals. Raw syngas must be treated to remove a number of impurities that would otherwise poison the synthesis catalysts. Inorganic impurities include alkali salts, chloride, sulfur compounds, heavy metals, ammonia, and various P, As, Sb, and Se- containing compounds. Systems comprising multiple sorbent and catalytic beds have been developed for the removal of impurities from gasified coal using a warm cleanup approach. This approach has the potential to be more economic than the currently available acid gas removal (AGR) approaches and improves upon currently available processes that do not provide the level of impurity removal that is required for catalytic synthesis application. Gasification also lends itself much more readily to the capture of CO2, important in the regulation and control of greenhouse gas emissions. CO2 capture material was developed and in this study was demonstrated to assist in methane production from the purified syngas. Simultaneous CO2 sorption enhances the CO methanation reaction through relaxation of thermodynamic constraint, thus providing economic benefit rather than simply consisting of an add-on cost for carbon capture and release. Molten and pre-molten LiNaKCO3 can promote MgO and MgO-based double salts to capture CO2 with high cycling capacity. A stable cycling CO2 capacity up to 13 mmol/g was demonstrated. This capture material was specifically developed in this study to operate in the same temperature range and therefore integrate effectively with warm gas cleanup and methane synthesis. By combining syngas methanation, water-gas-shift, and CO2 sorption in a single reactor, single pass yield to methane of 99% was demonstrated at 10 bar and 330oC when using a 20 wt% Ni/MgAl2O4 catalyst and a molten-phase promoted MgO-based sorbent. Under model feed conditions both the sorbent and catalyst exhibited favorable stability after multiple test cycles. The cleanup for warm gas cleanup of inorganics was broken down into three major steps: chloride removal, sulfur removal, and the removal for a multitude of trace metal contaminants. Na2CO3 was found to optimally remove chlorides at an operating temperature of 450șC. For sulfur removal two regenerable ZnO beds are used for bulk H2S removal at 450șC (<5 ppm S) and a non-regenerable ZnO bed for H2S polishing at 300șC (<40 ppb S). It was also found that sulfur from COS could be adsorbed (to levels below our detection limit of 40 ppb) in the presence of water that leads to no detectable slip of H2S. Finally, a sorbent material comprising of Cu and Ni was found to be effective in removing trace metal impurities such as AsH3 and PH3 when operating at 300șC. Proof-of-concept of the integrated cleanup process was demonstrated with gasifier-generated syngas produced at the Western Research Institute using Wyoming Decker Coal. When operating with a ~1 SLPM feed, multiple inorganic contaminant removal sorbents and a tar-reforming bed was able to remove the vast majority of contaminants from the raw syngas. A tar-reforming catalyst was employed due to the production of tars generated from the gasifier used in this particular study. It is envisioned that in a real application a commercial scale gasifier operating at a higher temperature would produce lesser amount of tar. Continuous operation of a poison-sensitive copper-based WGS catalyst located downstream from the cleanup steps resulted in successful demonstration. ?

Dagle, Robert A.; King, David L.; Li, Xiaohong S.; Xing, Rong; Spies, Kurt A.; Zhu, Yunhua; Rainbolt, James E.; Li, Liyu; Braunberger, B.

2014-10-31T23:59:59.000Z

133

FOOD REFORM MOVEMENTS Nicolas Larchet  

E-Print Network [OSTI]

FOOD REFORM MOVEMENTS Nicolas Larchet Social historians have broadly defined two cycles of American history characterized by an efflorescence of social movements aiming to reform both the individual to the 1920s. The reform impulse thrived wherever there was a perceived vice, abuse or corruption

Boyer, Edmond

134

Reforming the Private Insurance Market  

E-Print Network [OSTI]

SUMMARY s national health care reform efforts go forward, it is instructive to review states' experience INTRODUCTION he prospects for national health care reform are more promising than at any time since 1994. President Obama and Members of Congress have made health care reform a top priority and legislation

Kammen, Daniel M.

135

Commodity chemicals from natural gas by methane chlorination  

SciTech Connect (OSTI)

Ethylene and vinyl chloride monomer (VCM) can be produced from natural gas through methane chlorination by reacting methane and chlorine at 900/sup 0/C or higher. Experimental results indicate total ethylene equivalent yield from methane of 45%(wt) and marginal process economics. Fundamental kinetic modeling predicts improved C/sub 2/ yields of up to 70%(wt) at optimum reaction conditions. This optimum condition established the basis for the process design study to evaluate the potential for producing ethylene and VCM from natural gas. HCl by-product is recycled for economic viability. Using the Kel-Chlor process for recycling HCl, the proposed plant produces 27,200 TPA of C/sub 2/H/sub 4/ and 383,800 TPA of VCM. The Midwest is an ethylene consumption area requiring imports of ethylene derivatives from other regions. A methane chlorination plant located on a Midwestern natural gas pipeline network has a good commercial potential.

Che, S.C.; Minet, R.G.; Giacobbe, F.; Mullick, S.L.

1987-01-01T23:59:59.000Z

136

ARM - Methane Background Information  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc Documentation RUC : XDCResearchWarmingMethane Background Information Outreach Home Room News

137

ARM - Methane Gas  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc Documentation RUC : XDCResearchWarmingMethane Background Information Outreach Home Room

138

Coal Bed Methane Primer  

SciTech Connect (OSTI)

During the second half of the 1990's Coal Bed Methane (CBM) production increased dramatically nationwide to represent a significant new source of income and natural gas for many independent and established producers. Matching these soaring production rates during this period was a heightened public awareness of environmental concerns. These concerns left unexplained and under-addressed have created a significant growth in public involvement generating literally thousands of unfocused project comments for various regional NEPA efforts resulting in the delayed development of public and fee lands. The accelerating interest in CBM development coupled to the growth in public involvement has prompted the conceptualization of this project for the development of a CBM Primer. The Primer is designed to serve as a summary document, which introduces and encapsulates information pertinent to the development of Coal Bed Methane (CBM), including focused discussions of coal deposits, methane as a natural formed gas, split mineral estates, development techniques, operational issues, producing methods, applicable regulatory frameworks, land and resource management, mitigation measures, preparation of project plans, data availability, Indian Trust issues and relevant environmental technologies. An important aspect of gaining access to federal, state, tribal, or fee lands involves education of a broad array of stakeholders, including land and mineral owners, regulators, conservationists, tribal governments, special interest groups, and numerous others that could be impacted by the development of coal bed methane. Perhaps the most crucial aspect of successfully developing CBM resources is stakeholder education. Currently, an inconsistent picture of CBM exists. There is a significant lack of understanding on the parts of nearly all stakeholders, including industry, government, special interest groups, and land owners. It is envisioned the Primer would being used by a variety of stakeholders to present a consistent and complete synopsis of the key issues involved with CBM. In light of the numerous CBM NEPA documents under development this Primer could be used to support various public scoping meetings and required public hearings throughout the Western States in the coming years.

Dan Arthur; Bruce Langhus; Jon Seekins

2005-05-25T23:59:59.000Z

139

Methane production from ozonated pulp mill effluent  

SciTech Connect (OSTI)

A study was made of the production of methane from desugared spent sulfite liquor (SSL) reacted with ozone. The ozonated SSL was fed continuously to three anaerobic fermenters for three months as the sole source of carbon and energy. The fermenters were inoculated with anaerobic bacteria obtained from sewage sludge and acclimated for 1 month in ozonated SSL prior to continuous fermentation. Chemical and biological parameters such as COD, BOD, total sulfur content, redox potential, pH, fatty acid composition, and methane bacteria populations were monitored to determine changes in the SSL during fermentation. Methane production from ozone-treated SSL averaged 1.7 liters/ liter or 17 ml of CH/sub 4/ produced/gram of volatile solids fed. Fatty acis analysis of fermenter effluent indicated a net production of 58 mM/ liter of acetate during ozonated SSL fermentation. This acetic acid production shows future potential for further fermentation by protein-producing yeast. Although the rate of conversion of volatile solids to CH/sub 4/ in this process was not competitive with domestic or agricultural waste digesters, this study did indicate the potential benefits of ozonating organic wastes for increased methane fermentation yields.

Bremmon, C.E.; Jurgensen, M.F.; Patton, J.T.

1980-07-01T23:59:59.000Z

140

Methane present in an extrasolar planet atmosphere  

E-Print Network [OSTI]

Molecules present in exoplanetary atmospheres are expected to strongly influence the atmospheric radiation balance, trace dynamical and chemical processes, and indicate the presence of disequilibrium effects. Since molecules have the potential to reveal the exoplanet atmospheric conditions and chemistry, searching for them is a high priority. The rotational-vibrational transition bands of water, carbon monoxide, and methane are anticipated to be the primary sources of non-continuum opacity in hot-Jovian planets. Since these bands overlap in wavelength, and the corresponding signatures from them are weak, decisive identification requires precision infrared spectroscopy. Here we report on a near-infrared transmission spectrum of the planet HD 189733b showing the presence of methane. Additionally, a resolved water-vapour band at 1.9 microns confirms the recent claim of water in this object. On thermochemical grounds, carbon-monoxide is expected to be abundant in the upper atmosphere of hot-Jovian exoplanets; thus the detection of methane rather than carbon-monoxide in such a hot planet could signal the presence of a horizontal chemical gradient away from the permanent dayside, or it may imply an ill-understood photochemical mechanisms that leads to an enhancement of methane.

Mark R. Swain; Gautam Vasisht; Giovanna Tinetti

2008-02-07T23:59:59.000Z

Note: This page contains sample records for the topic "methane reforming process" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Multi-fuel reformers for fuel cells used in transportation. Multi-fuel reformers: Phase 1 -- Final report  

SciTech Connect (OSTI)

DOE has established the goal, through the Fuel Cells in Transportation Program, of fostering the rapid development and commercialization of fuel cells as economic competitors for the internal combustion engine. Central to this goal is a safe feasible means of supplying hydrogen of the required purity to the vehicular fuel cell system. Two basic strategies are being considered: (1) on-board fuel processing whereby alternative fuels such as methanol, ethanol or natural gas stored on the vehicle undergo reformation and subsequent processing to produce hydrogen, and (2) on-board storage of pure hydrogen provided by stationary fuel processing plants. This report analyzes fuel processor technologies, types of fuel and fuel cell options for on-board reformation. As the Phase 1 of a multi-phased program to develop a prototype multi-fuel reformer system for a fuel cell powered vehicle, the objective of this program was to evaluate the feasibility of a multi-fuel reformer concept and to select a reforming technology for further development in the Phase 2 program, with the ultimate goal of integration with a DOE-designated fuel cell and vehicle configuration. The basic reformer processes examined in this study included catalytic steam reforming (SR), non-catalytic partial oxidation (POX) and catalytic partial oxidation (also known as Autothermal Reforming, or ATR). Fuels under consideration in this study included methanol, ethanol, and natural gas. A systematic evaluation of reforming technologies, fuels, and transportation fuel cell applications was conducted for the purpose of selecting a suitable multi-fuel processor for further development and demonstration in a transportation application.

Not Available

1994-05-01T23:59:59.000Z

142

Modeling methane emissions from the Alaskan Yukon River basin, 19862005, by coupling a large-scale hydrological model  

E-Print Network [OSTI]

Modeling methane emissions from the Alaskan Yukon River basin, 1986­2005, by coupling a large-scale hydrological model and a process-based methane model Xiaoliang Lu1 and Qianlai Zhuang1,2 Received 25 August has been made in methane modeling for the Arctic. However, there is still large uncertainty

143

Proceedings of the international coalbed methane symposium. Volume 2  

SciTech Connect (OSTI)

Volume 2 contains 36 papers divided among the following sessions: Resources/development potential; Mine safety and productivity issues; Reservoir characterization, modeling, and well testing; and a Poster session whose papers discuss coal geology, well completion methods, origin of coalbed methane, rock mechanics of coal seams, geologic fractures in coal seams, and the use of coalbed methane for mitigation of greenhouse gases. All papers have been processed for inclusion on the data base.

NONE

1993-09-01T23:59:59.000Z

144

A novel technique for on-line coke gasification during propane steam reforming using forced CO2 cycling.  

E-Print Network [OSTI]

??Steam reforming is an important source of synthesis gas production that is used by major petrochemical processes such as ammonia, methanol and the Fisher-Tropsch process.… (more)

Alenazey, Feraih Sheradh

2011-01-01T23:59:59.000Z

145

Bioconversion of biomass to methane  

SciTech Connect (OSTI)

The conversion of biomass to methane is described. The biomethane potentials of various biomass feedstocks from our laboratory and literature is summarized.

Hashimoto, A.G. [Oregon State Univ., Corvallis, OR (United States)

1995-12-01T23:59:59.000Z

146

Thermally efficient melting and fuel reforming for glass making  

DOE Patents [OSTI]

An integrated process is described for utilizing waste heat from a glass making furnace. The hot off-gas from the furnace is initially partially cooled, then fed to a reformer. In the reformer, the partially cooled off-gas is further cooled against a hydrocarbon which is thus reformed into a synthesis gas, which is then fed into the glass making furnace as a fuel. The further cooled off-gas is then recycled back to absorb the heat from the hot off-gas to perform the initial cooling. 2 figures.

Chen, M.S.; Painter, C.F.; Pastore, S.P.; Roth, G.S.; Winchester, D.C.

1991-10-15T23:59:59.000Z

147

Thermally efficient melting and fuel reforming for glass making  

DOE Patents [OSTI]

An integrated process for utilizing waste heat from a glass making furnace. The hot off-gas from the furnace is initially partially cooled, then fed to a reformer. In the reformer, the partially cooled off-gas is further cooled against a hydrocarbon which is thus reformed into a synthesis gas, which is then fed into the glass making furnace as a fuel. The further cooled off-gas is then recycled back to absorb the heat from the hot off-gas to perform the initial cooling.

Chen, Michael S. (Zionsville, PA); Painter, Corning F. (Allentown, PA); Pastore, Steven P. (Allentown, PA); Roth, Gary S. (Trexlertown, PA); Winchester, David C. (Allentown, PA)

1991-01-01T23:59:59.000Z

148

VIBRATION->VIBRATION ENERGY TRANSFER IN METHANE  

E-Print Network [OSTI]

VIBRATION ENERGY TRANSFER IN METHANE Peter Hess, A. H. Kung,Rotation Spectra of Methane, U.S. Nat'L· Tech. Inform.tret t tllll. I. INTRODUCTION Methane is a relatively simple

Hess, Peter

2012-01-01T23:59:59.000Z

149

Coal Bed Methane Protection Act (Montana)  

Broader source: Energy.gov [DOE]

The Coal Bed Methane Protection Act establishes a long-term coal bed methane protection account and a coal bed methane protection program for the purpose of compensating private landowners and...

150

Methane oxidation over dual redox catalysts  

SciTech Connect (OSTI)

Catalytic oxidation of methane to partial oxidation products, primarily formaldehyde and C[sub 2] hydrocarbons, was found to be directed by the catalyst used. In this project, it was discovered that a moderate oxidative coupling catalyst for C[sub 2] hydrocarbons, zinc oxide, is modified by addition of small amounts of Cu and Fe dopants to yield fair yields of formaldehyde. A similar effect was observed with Cu/Sn/ZnO catalysts, and the presence of a redox Lewis acid, Fe[sup III] or Sn[sup IV], was found to be essential for the selectivity switch from C[sub 2] coupling products to formaldehyde. The principle of double doping with an oxygen activator (Cu) and the redox Lewis acid (Fe, Sn) was pursued further by synthesizing and testing the CuFe-ZSM-5 zeolite catalyst. The Cu[sup II](ion exchanged) Fe[sup III](framework)-ZSM-5 also displayed activity for formaldehyde synthesis, with space time yields exceeding 100 g/h-kg catalyst. However, the selectivity was low and earlier claims in the literature of selective oxidation of methane to methanol over CuFe-ZSM-5 were not reproduced. A new active and selective catalytic system (M=Sb,Bi,Sn)/SrO/La[sub 2]O[sub 3] has been discovered for potentially commercially attractive process for the conversion of methane to C[sub 2] hydrocarbons, (ii) a new principle has been demonstrated for selectivity switching from C[sub 2] hydrocarbon products to formaldehyde in methane oxidations over Cu,Fe-doped zinc oxide and ZSM-5, and (iii) a new approach has been initiated for using ultrafine metal dispersions for low temperature activation of methane for selective conversions. Item (iii) continues being supported by AMOCO while further developments related to items (i) and (ii) are the objective of our continued effort under the METC-AMOCO proposed joint program.

Klier, K.; Herman, R.G.; Sojka, Z.; DiCosimo, J.I.; DeTavernier, S.

1992-06-01T23:59:59.000Z

151

The use of advanced steam reforming technology for hydrogen production  

SciTech Connect (OSTI)

The demand for supplementary hydrogen production in refineries is growing significantly world-wide as environmental legislation concerning cleaner gasoline and diesel fuels is introduced. The main manufacturing method is by steam reforming. The process has been developed both to reduce the capital cost and increase efficiency, reliability and ease of operation. ICI Katalco`s Leading Concept Hydrogen or LCH process continues this process of improvement by replacing the conventional fired steam reformer with a type of heat exchange reformer known as the Gas Heated Reformer or GHR. The GHR was first used in the Leading Concept Ammonia process, LCA at ICI`s manufacturing site at Severnside, England and commissioned in 1988 and later in the Leading Concept Methanol (LCM) process for methanol at Melbourne, Australia and commissioned in 1994. The development of the LCH process follows on from both LCA and LCM processes. This paper describes the development and use of the GHR in steam reforming, and shows how the GHR can be used in LCH. A comparison between the LCH process and a conventional hydrogen plant is given, showing the benefits of the LCH process in certain circumstances.

Abbishaw, J.B.; Cromarty, B.J. [ICI Katalco, Billingham (United Kingdom)

1996-12-01T23:59:59.000Z

152

Methanol partial oxidation reformer  

DOE Patents [OSTI]

A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

1999-01-01T23:59:59.000Z

153

Methanol partial oxidation reformer  

DOE Patents [OSTI]

A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

2001-01-01T23:59:59.000Z

154

Methanol partial oxidation reformer  

DOE Patents [OSTI]

A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

Ahmed, S.; Kumar, R.; Krumpelt, M.

1999-08-17T23:59:59.000Z

155

Methanol partial oxidation reformer  

DOE Patents [OSTI]

A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

Ahmed, S.; Kumar, R.; Krumpelt, M.

1999-08-24T23:59:59.000Z

156

Fairness lost in immigration reform; Never before have sweeping changes to policies been undertaken with so little public debate or  

E-Print Network [OSTI]

Fairness lost in immigration reform; Never before have sweeping changes to policies been undertaken reform is unique neither in terms of its controversial substance nor in its lack of meaningful democratic processes. In the past, major immigration reform has typically been the result of parliamentary deliberation

Handy, Todd C.

157

methane hydrate science plan-final.indd  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2013 Principal Authors: Consor um for Ocean Leadership and the Methane Hydrate Project Science Team December 2013 DOE Award Number: DE-FE0010195 Project Title: Methane Hydrate...

158

A review of "Godly Reformers and their Opponents in Early Modern England: Religion in Norwich." by Matthew Reynolds  

E-Print Network [OSTI]

relatively uncontested Reformation, Norwich became Protestant ?in a process that was far from quiet? (35). The religious divisions the Reformation created remained rife, providing Laudian reforms with a measure of lay support within the city, which in turn... part of James? reign. Religious division was widespread, evident amongst the higher clergy attached to the Cathedral, where relations were defined by a split between those who stood against further reform and evangelical Protestants. In civic politics...

Baker, Geoff

2006-01-01T23:59:59.000Z

159

Coalbed Methane Production  

Gasoline and Diesel Fuel Update (EIA)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781Title: Telephone:shortOil andMCKEESPORTfor the 2012Methane

160

Steam reformer with catalytic combustor  

DOE Patents [OSTI]

A steam reformer is disclosed having an annular steam reforming catalyst bed formed by concentric cylinders and having a catalytic combustor located at the center of the innermost cylinder. Fuel is fed into the interior of the catalytic combustor and air is directed at the top of the combustor, creating a catalytic reaction which provides sufficient heat so as to maintain the catalytic reaction in the steam reforming catalyst bed. Alternatively, air is fed into the interior of the catalytic combustor and a fuel mixture is directed at the top. The catalytic combustor provides enhanced radiant and convective heat transfer to the reformer catalyst bed.

Voecks, Gerald E. (La Crescenta, CA)

1990-03-20T23:59:59.000Z

Note: This page contains sample records for the topic "methane reforming process" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Catalytic autothermal reforming increases fuel cell flexibility  

SciTech Connect (OSTI)

To give a better understanding of autothermal reforming (ATR), a process which offers an advantageous alternative to steam reforming for H/sub 2/ production for fuel cells because of the wider range of fuels which can be converted, the conversion of individual fuel components was studied. Attempts have been made to characterize the chemical reactions of light and heavy paraffins and aromatics in ATR. Results of studies to determine the effects of operating parameters on the carbon-forming tendency of each hydrocarbon type are reported. The catalyst used for the ATR process was three-layers of supported nickel catalysts, Norton NC-100 spheres in the top zone, cylindrical G-56B tablets in the bottom one, and either ICI 46-I or ICI 46-4 Raschig rings in the middle zone. A summary of the experimental studies of the ATR of n-hexane, n-tetradecane, benzene, and benzene solutions of naphthalene is presented. (BLM)

Flytzani-Stephanopoulos, M.; Voecks, G.E.

1981-12-01T23:59:59.000Z

162

Catalytic autothermal reforming of hydrocarbon fuels for fuel cells.  

SciTech Connect (OSTI)

Fuel cell development has seen remarkable progress in the past decade because of an increasing need to improve energy efficiency as well as to address concerns about the environmental consequences of using fossil fuel for producing electricity and for propulsion of vehicles [1]. The lack of an infrastructure for producing and distributing H{sub 2} has led to a research effort to develop on-board fuel processing technology for reforming hydrocarbon fuels to generate H{sub 2} [2]. The primary focus is on reforming gasoline, because a production and distribution infrastructure for gasoline already exists to supply internal combustion engines [3]. Existing reforming technology for the production of H{sub 2} from hydrocarbon feedstocks used in large-scale manufacturing processes, such as ammonia synthesis, is cost prohibitive when scaled down to the size of the fuel processor required for transportation applications (50-80 kWe) nor is it designed to meet the varying power demands and frequent shutoffs and restarts that will be experienced during normal drive cycles. To meet the performance targets required of a fuel processor for transportation applications will require new reforming reactor technology developed to meet the volume, weight, cost, and operational characteristics for transportation applications and the development of new reforming catalysts that exhibit a higher activity and better thermal and mechanical stability than reforming catalysts currently used in the production of H{sub 2} for large-scale manufacturing processes.

Krumpelt, M.; Krause, T.; Kopasz, J.; Carter, D.; Ahmed, S.

2002-01-11T23:59:59.000Z

163

What's right SHIP & Healthcare Reform Forum  

E-Print Network [OSTI]

&Health Reform What's right for you SHIP & Healthcare Reform Forum: What's Right for You This session will help you: * demystify the healthcare reform changes * explore your options * learn how

Walker, Matthew P.

164

Coal mine methane global review  

SciTech Connect (OSTI)

This is the second edition of the Coal Mine Methane Global Overview, updated in the summer of 2008. This document contains individual, comprehensive profiles that characterize the coal and coal mine methane sectors of 33 countries - 22 methane to market partners and an additional 11 coal-producing nations. The executive summary provides summary tables that include statistics on coal reserves, coal production, methane emissions, and CMM projects activity. An International Coal Mine Methane Projects Database accompanies this overview. It contains more detailed and comprehensive information on over two hundred CMM recovery and utilization projects around the world. Project information in the database is updated regularly. This document will be updated annually. Suggestions for updates and revisions can be submitted to the Administrative Support Group and will be incorporate into the document as appropriate.

NONE

2008-07-01T23:59:59.000Z

165

Development and Application of Advanced Models for Steam Hydrogasification: Process Design and Economic Evaluation  

E-Print Network [OSTI]

size gasification for syngas, substitute natural gas, andfor Biomass-Derived Syngas. NREL/ TP-510-34929. Golden, CO:either converted into syngas in the Steam Methane Reformer (

Lu, Xiaoming

2012-01-01T23:59:59.000Z

166

Where's the Beef? ConAgra's Approach to Energy Sources & Efficiency in Meat Processing  

E-Print Network [OSTI]

converts, chemically reforms, and neutralizes wastes producing oils (biodiesel), gases (methane, propane, butane), and carbons (clean coal, fertilizer). In addition, microturbines are installed to provide heat and power. This partnership will showcase...

Kananen, T. M.

167

Upgrading Methane Using Ultra-Fast Thermal Swing Adsorption  

SciTech Connect (OSTI)

The purpose of this project is to design and demonstrate an approach to upgrade low-BTU methane streams from coal mines to pipeline-quality natural gas. The objective of Phase I of the project was to assess the technical feasibility and cost of upgrading low-BTU methane streams using ultra-fast thermal swing adsorption (TSA) using Velocys modular microchannel process technology. The objective of Phase II is to demonstrate the process at the bench-scale. Natural gas upgrading systems have six main unit operations: feed compressor, dehydration unit, nitrogen rejection unit, deoxygenator, carbon dioxide scrubber, and a sales compressor. The NRU is the focus of the development program, and a bench-scale demonstration has been initiated. The Velocys NRU system targets producing methane with greater than 96% purity and at least 90% recovery for final commercial operation. A preliminary cost analysis of the methane upgrading system, including the Velocys NRU, suggests that costs below $2.00 per million (MM) BTU methane may be achieved. The cost for a conventional methane upgrading system is well above $2.30 per MM BTU, as benchmarked in an Environmental Protection Agency study. The project is on schedule and on budget. Task 4, a bench-scale demonstration of the ultra-fast TSA system is complete. Rapid thermal swing of an adsorbent bed using microchannels has been successfully demonstrated and the separation of a 70% methane and 30% nitrogen was purified to 92% methane. The bench-scale demonstration unit was small relative to the system dead volume for the initial phase of experiments and a purge step was added to sweep the dead volume prior to desorbing the bed and measuring purity. A technical and economic feasibility assessment was completed in Task 3. The proposed Velocys technology appears feasible for the methane upgrading market. Evaluated categories include adsorbent selection, rapid-cycle valve selection, microchannel manufacturability assessment, and system design and cost. The selected adsorbent, granular microporous carbon from either Barnaby-Sutcliffe or Calgon, experimentally demonstrated sufficient methane capacity under differential temperature at 100 pounds per square inch gauge. Several valve options were identified, including candidates that can operate millions of cycles between refurbishment. The microchannel adsorber and desorber designs were made using internal Velocys manufacturability standards, and the associated costs are acceptable as included with the complete nitrogen rejection unit (NRU) cost projection. A system design and cost estimate was completed for the NRU section of the methane upgrading system. As integrated into the complete system, the cost is in line with the market requirement.

Anna Lee Tonkovich

2005-07-01T23:59:59.000Z

168

Renewable Liquid Fuels Reforming | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Renewable Liquid Fuels Reforming The Program anticipates that distributed reforming of biomass-derived liquid fuels could be commercial during the transition to hydrogen and used...

169

Sulfonation of Methane Direct Liquid-Phase Sulfonation of Methane to  

E-Print Network [OSTI]

Sulfonation of Methane Direct Liquid-Phase Sulfonation of Methane to Methanesulfonic Acid by SO3 of methane to value-added prod- ucts is a significant contemporary challenge.[1] Methane is a very unreactive, consider- able effort has been devoted to the oxidation and oxidative carbonylation of methane.[2

Bell, Alexis T.

170

Review article Methane production by ruminants  

E-Print Network [OSTI]

Review article Methane production by ruminants: its contribution to global warming Angela R. MOSSa of methane in the global warming scenario and to examine the contribution to atmospheric methane made by enteric fermentation, mainly by rumi- nants. Agricultural emissions of methane in the EU-15 have recently

Paris-Sud XI, Université de

171

Process, including membrane separation, for separating hydrogen from hydrocarbons  

DOE Patents [OSTI]

Processes for providing improved methane removal and hydrogen reuse in reactors, particularly in refineries and petrochemical plants. The improved methane removal is achieved by selective purging, by passing gases in the reactor recycle loop across membranes selective in favor of methane over hydrogen, and capable of exhibiting a methane/hydrogen selectivity of at least about 2.5 under the process conditions.

Baker, Richard W. (Palo Alto, CA); Lokhandwala, Kaaeid A. (Union City, CA); He, Zhenjie (Fremont, CA); Pinnau, Ingo (Palo Alto, CA)

2001-01-01T23:59:59.000Z

172

Method of coalbed methane production  

SciTech Connect (OSTI)

This patent describes a method for producing coalbed methane from a coal seam containing coalbed methane and penetrated by at least one injection well and at least one producing well. It comprises: injecting an inert gas through the injection well and into the coal seam. The inert gas being a gas that does not react with the coal under conditions of use and that does not significantly adsorb to the coal; and producing a gas from the production well which consists essentially of the inert gas, coalbed methane, or mixtures thereof.

Puri, R.; Stein, M.H.

1989-11-28T23:59:59.000Z

173

Autothermal reforming catalyst having perovskite structure  

DOE Patents [OSTI]

The invention addressed two critical issues in fuel processing for fuel cell application, i.e. catalyst cost and operating stability. The existing state-of-the-art fuel reforming catalyst uses Rh and platinum supported over refractory oxide which add significant cost to the fuel cell system. Supported metals agglomerate under elevated temperature during reforming and decrease the catalyst activity. The catalyst is a perovskite oxide or a Ruddlesden-Popper type oxide containing rare-earth elements, catalytically active firs row transition metal elements, and stabilizing elements, such that the catalyst is a single phase in high temperature oxidizing conditions and maintains a primarily perovskite or Ruddlesden-Popper structure under high temperature reducing conditions. The catalyst can also contain alkaline earth dopants, which enhance the catalytic activity of the catalyst, but do not compromise the stability of the perovskite structure.

Krumpel, Michael (Naperville, IL); Liu, Di-Jia (Naperville, IL)

2009-03-24T23:59:59.000Z

174

Mars long has been considered a cold, dead planet.However,recent reports of methane  

E-Print Network [OSTI]

currently is being produced,since its calculated atmo- spheric lifetime of 400 years or less [Nair et al of the processes producing Martian atmospheric methane, and the places on Mars from which it arises, will have wide to form methane and water, and by the fermentation of a variety of organic substrates,including methanol

Manning, Craig

175

Microbe-Metazoan interactions at Pacific Ocean methane seeps  

E-Print Network [OSTI]

B) and those present within methane seep Euryarchaea ( PMI,margin: the influence of methane seeps and oxygen minimumisotope signatures and methane use by New Zealand cold seep

Thurber, Andrew R

2010-01-01T23:59:59.000Z

176

Microbe-metazoan interactions at Pacific Ocean methane seeps  

E-Print Network [OSTI]

B) and those present within methane seep Euryarchaea ( PMI,margin: the influence of methane seeps and oxygen minimumisotope signatures and methane use by New Zealand cold seep

Thurber, Andrew Reichmann

2010-01-01T23:59:59.000Z

177

Multipath Curved Planar Reformation of the Peripheral  

E-Print Network [OSTI]

Multipath Curved Planar Reformation of the Peripheral Arterial Tree in CT Angiography1 Justus that cause artifacts in multipath curved planar reformations (MPCPRs) of the peripheral arterial tree in 10-oblique multiplanar reformations perpendicular to the ves- sel centerline (10), and curved planar reformations

178

Optimization of Multiplanar Reformations from Isotropic  

E-Print Network [OSTI]

Optimization of Multiplanar Reformations from Isotropic Data Sets Acquired with 16­ Detector Row coronal reformations at vari- ous thicknesses were ranked qualitatively by three radiol- ogists. Effective reformations of data acquired in the custom phantom were compared, coronal reformations obtained with the 16

179

Toward a Reformalization of QSIM Benjamin Shults  

E-Print Network [OSTI]

Toward a Reformalization of QSIM Benjamin Shults Department of Mathematics University of Texas is to reformalize part of the framework of the Guaranteed Coverage Theorem for QSIM. The intention is not to reformalize every detail of the proof but merely to mention some areas whose reformalization lends deeper

Kuipers, Benjamin

180

The development of autocatalytic structural materials for use in the sulfur-iodine process for the production of hydrogen  

E-Print Network [OSTI]

The Sulfur-Iodine Cycle for the thermochemical production of hydrogen offers many benefits to traditional methods of hydrogen production. As opposed to steam methane reforming - the most prevalent method of hydrogen ...

Miu, Kevin (Kevin K.)

2006-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "methane reforming process" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

A method for measuring methane oxidation rates using low levels of 14C-labeled methane and accelerator mass spectrometry  

E-Print Network [OSTI]

the anaerobic oxidation of methane. Environ. Microbiol. 10(Field observations of methane concentra- tions and oxidationAnaerobic oxidation of methane above gas hydrates at Hydrate

2011-01-01T23:59:59.000Z

182

Methanation of gas streams containing carbon monoxide and hydrogen  

DOE Patents [OSTI]

Carbon monoxide-containing gas streams having a relatively high concentration of hydrogen are pretreated so as to remove the hydrogen in a recoverable form for use in the second step of a cyclic, essentially two-step process for the production of methane. The thus-treated streams are then passed over a catalyst to deposit a surface layer of active surface carbon thereon essentially without the formation of inactive coke. This active carbon is reacted with said hydrogen removed from the feed gas stream to form methane. The utilization of the CO in the feed gas stream is appreciably increased, enhancing the overall process for the production of relatively pure, low-cost methane from CO-containing waste gas streams.

Frost, Albert C. (Congers, NY)

1983-01-01T23:59:59.000Z

183

Advanced turbine systems program conceptual design and product development Task 8.3 - autothermal fuel reformer (ATR). Topical report  

SciTech Connect (OSTI)

Autothermal fuel reforming (ATR) consists of reacting a hydrocarbon fuel such as natural gas or diesel with steam to produce a hydrogen-rich {open_quotes}reformed{close_quotes} fuel. This work has been designed to investigate the fuel reformation and the product gas combustion under gas turbine conditions. The hydrogen-rich gas has a high flammability with a wide range of combustion stability. Being lighter and more reactive than methane, the hydrogen-rich gas mixes readily with air and can be burned at low fuel/air ratios producing inherently low emissions. The reformed fuel also has a low ignition temperature which makes low temperature catalytic combustion possible. ATR can be designed for use with a variety of alternative fuels including heavy crudes, biomass and coal-derived fuels. When the steam required for fuel reforming is raised by using energy from the gas turbine exhaust, cycle efficiency is improved because of the steam and fuel chemically recuperating. Reformation of natural gas or diesel fuels to a homogeneous hydrogen-rich fuel has been demonstrated. Performance tests on screening various reforming catalysts and operating conditions were conducted on a batch-tube reactor. Producing over 70 percent of hydrogen (on a dry basis) in the product stream was obtained using natural gas as a feedstock. Hydrogen concentration is seen to increase with temperature but less rapidly above 1300{degrees}F. The percent reforming increases as the steam to carbon ratio is increased. Two basic groups of reforming catalysts, nickel - and platinum-basis, have been tested for the reforming activity.

NONE

1996-11-01T23:59:59.000Z

184

LANDFILL OPERATION FOR CARBON SEQUESTRATION AND MAXIMUM METHANE EMISSION CONTROL  

SciTech Connect (OSTI)

Controlled landfilling is an approach to manage solid waste landfills, so as to rapidly complete methane generation, while maximizing gas capture and minimizing the usual emissions of methane to the atmosphere. With controlled landfilling, methane generation is accelerated to more rapid and earlier completion to full potential by improving conditions (principally moisture, but also temperature) to optimize biological processes occurring within the landfill. Gas is contained through use of surface membrane cover. Gas is captured via porous layers, under the cover, operated at slight vacuum. A field demonstration project has been ongoing under NETL sponsorship for the past several years near Davis, CA. Results have been extremely encouraging. Two major benefits of the technology are reduction of landfill methane emissions to minuscule levels, and the recovery of greater amounts of landfill methane energy in much shorter times, more predictably, than with conventional landfill practice. With the large amount of US landfill methane generated, and greenhouse potency of methane, better landfill methane control can play a substantial role both in reduction of US greenhouse gas emissions and in US renewable energy. The work described in this report, to demonstrate and advance this technology, has used two demonstration-scale cells of size (8000 metric tons [tonnes]), sufficient to replicate many heat and compaction characteristics of larger ''full-scale'' landfills. An enhanced demonstration cell has received moisture supplementation to field capacity. This is the maximum moisture waste can hold while still limiting liquid drainage rate to minimal and safely manageable levels. The enhanced landfill module was compared to a parallel control landfill module receiving no moisture additions. Gas recovery has continued for a period of over 4 years. It is quite encouraging that the enhanced cell methane recovery has been close to 10-fold that experienced with conventional landfills. This is the highest methane recovery rate per unit waste, and thus progress toward stabilization, documented anywhere for such a large waste mass. This high recovery rate is attributed to moisture, and elevated temperature attained inexpensively during startup. Economic analyses performed under Phase I of this NETL contract indicate ''greenhouse cost effectiveness'' to be excellent. Other benefits include substantial waste volume loss (over 30%) which translates to extended landfill life. Other environmental benefits include rapidly improved quality and stabilization (lowered pollutant levels) in liquid leachate which drains from the waste.

Don Augenstein; Ramin Yazdani; Rick Moore; Michelle Byars; Jeff Kieffer; Professor Morton Barlaz; Rinav Mehta

2000-02-26T23:59:59.000Z

185

ENGINEERING SCALE UP OF RENEWABLE HYDROGEN PRODUCTION BY CATALYTIC STEAM REFORMING OF PEANUT  

E-Print Network [OSTI]

ENGINEERING SCALE UP OF RENEWABLE HYDROGEN PRODUCTION BY CATALYTIC STEAM REFORMING OF PEANUT SHELLS, and academic organizations is developing a steam reforming process to be demonstrated on the gaseous byproducts of this engineering demonstration project. After an initial problem with the heaters that required modification

186

Heat exchanger for fuel cell power plant reformer  

DOE Patents [OSTI]

A heat exchanger uses the heat from processed fuel gas from a reformer for a fuel cell to superheat steam, to preheat raw fuel prior to entering the reformer and to heat a water-steam coolant mixture from the fuel cells. The processed fuel gas temperature is thus lowered to a level useful in the fuel cell reaction. The four temperature adjustments are accomplished in a single heat exchanger with only three heat transfer cores. The heat exchanger is preheated by circulating coolant and purge steam from the power section during startup of the latter.

Misage, Robert (Manchester, CT); Scheffler, Glenn W. (Tolland, CT); Setzer, Herbert J. (Ellington, CT); Margiott, Paul R. (Manchester, CT); Parenti, Jr., Edmund K. (Manchester, CT)

1988-01-01T23:59:59.000Z

187

Before the House Oversight and Government Reform Subcommittee...  

Office of Environmental Management (EM)

Oversight and Government Reform Subcommittee on Technology, Information Policy, Intergovernmental Relations, and Procurement Reform Before the House Oversight and Government Reform...

188

Characterization of Methane Degradation and Methane-Degrading Microbes in Alaska Coastal Water  

SciTech Connect (OSTI)

The net flux of methane from methane hydrates and other sources to the atmosphere depends on methane degradation as well as methane production and release from geological sources. The goal of this project was to examine methane-degrading archaea and organic carbon oxidizing bacteria in methane-rich and methane-poor sediments of the Beaufort Sea, Alaska. The Beaufort Sea system was sampled as part of a multi-disciplinary expedition (â??Methane in the Arctic Shelfâ? or MIDAS) in September 2009. Microbial communities were examined by quantitative PCR analyses of 16S rRNA genes and key methane degradation genes (pmoA and mcrA involved in aerobic and anaerobic methane degradation, respectively), tag pyrosequencing of 16S rRNA genes to determine the taxonomic make up of microbes in these sediments, and sequencing of all microbial genes (â??metagenomesâ?). The taxonomic and functional make-up of the microbial communities varied with methane concentrations, with some data suggesting higher abundances of potential methane-oxidizing archaea in methane-rich sediments. Sequence analysis of PCR amplicons revealed that most of the mcrA genes were from the ANME-2 group of methane oxidizers. According to metagenomic data, genes involved in methane degradation and other degradation pathways changed with sediment depth along with sulfate and methane concentrations. Most importantly, sulfate reduction genes decreased with depth while the anaerobic methane degradation gene (mcrA) increased along with methane concentrations. The number of potential methane degradation genes (mcrA) was low and inconsistent with other data indicating the large impact of methane on these sediments. The data can be reconciled if a small number of potential methane-oxidizing archaea mediates a large flux of carbon in these sediments. Our study is the first to report metagenomic data from sediments dominated by ANME-2 archaea and is one of the few to examine the entire microbial assemblage potentially involved in anaerobic methane oxidation.

David Kirchman

2011-12-31T23:59:59.000Z

189

Perspective: The road to reform  

SciTech Connect (OSTI)

The rapid transformation underway in the utility industry provides ample evidence that the reality of the Energy Policy Act of 1992 is sinking in. This law reflected Congress's conclusion that competition in wholesale power generation-at the plant busbar-is a demonstrable reality. It expressed the vision of a fully competitive wholesale generation market, with suppliers linked to markets through a grid that would provide service on a nondiscriminatory basis. But will consumers reap the full benefits of effective competition at the wholesale generation level Or will more disorderly forms of competition emerge, reflecting a hybrid of deregulation and old-fashioned monopoly tactics Along the latter course we run the risk of cost shifts among customer classes, customer defections, diminished utility cooperation, and higher overall costs to society. In short, the vision of a competitive market in wholesale generation will not come about without thoughtful efforts at defining the relevant market, as well as careful attention to the management of a difficult transition away from outmodes mindsets and regulatory models. As a national trade association representing independent power producers (IPPs) and suppliers of goods and services to the competitive wholesale electric generation industry, the Electric Generation Association (EGA) believes that constructive dialogue will yield the best approach to managing this difficult process of transition. In that spirit, the EGA Emerging Operational Issues Committee recently released a while paper, [open quotes]Electrifying Change: Strategies for Structural Reform in the Electric Industry,[close quotes] which forms the basis for this article.

Howe, J.B. (J. Makowski Associates Inc., Boston, MA (United States))

1994-04-01T23:59:59.000Z

190

Development of Sulfur and Carbon Tolerant Reforming Alloy Catalysts Aided by Fundamental Atomistics Insights  

SciTech Connect (OSTI)

Current hydrocarbon reforming catalysts suffer from rapid carbon and sulfur poisoning. Even though there is a tremendous incentive to develop more efficient catalysts, these materials are currently formulated using inefficient trial and error experimental approaches. We have utilized a novel hybrid experimental/theoretical approach, combining quantum Density Functional Theory (DFT) calculations and various state-of-the-art experimental tools, to formulate carbon tolerant reforming catalysts. We have employed DFT calculations to develop molecular insights into the elementary chemical transformations that lead to carbon poisoning of Ni catalysts. Based on the obtained molecular insights, we have identified, using DFT quantum calculation, Sn/Ni alloy as a potential carbon tolerant reforming catalyst. Sn/Ni alloy was synthesized and tested in steam reforming of methane, propane, and isooctane. We demonstrated that the alloy catalyst is carbon-tolerant under nearly stoichiometric steam-to-carbon ratios. Under these conditions, monometallic Ni is rapidly poisoned by sp2 carbon deposits. The research approach is distinguished by a few characteristics: (a) Knowledge-based, bottom-up approach, compared to the traditional trial and error approach, allows for a more efficient and systematic discovery of improved catalysts. (b) The focus is on exploring alloy materials which have been largely unexplored as potential reforming catalysts.

Suljo Linic

2006-08-31T23:59:59.000Z

191

Development of Sulfur and Carbon Tolerant Reforming Alloy Catalysts Aided Fundamental Atomistic Insights  

SciTech Connect (OSTI)

Current hydrocarbon reforming catalysts suffer from rapid carbon and sulfur poisoning. Even though there is a tremendous incentive to develop more efficient catalysts, these materials are currently formulated using inefficient trial and error experimental approaches. We have utilized a hybrid experimental/theoretical approach, combining quantum Density Functional Theory (DFT) calculations and various state-of-the-art experimental tools, to formulate carbon tolerant reforming catalysts. We have employed DFT calculations to develop molecular insights into the elementary chemical transformations that lead to carbon poisoning of Ni catalysts. Based on the obtained molecular insights, we have identified, using DFT quantum calculation, various Ni alloy catalysts as potential carbon tolerant reforming catalysts. The alloy catalysts were synthesized and tested in steam reforming and partial oxidation of methane, propane, and isooctane. We demonstrated that the alloy catalysts are much more carbon-tolerant than monometallic Ni catalysts under nearly stoichiometric steam-to-carbon ratios. Under these conditions, monometallic Ni is rapidly poisoned by sp2 carbon deposits. The research approach is distinguished by two characteristics: (a) knowledge-based, bottomup approach, compared to the traditional trial and error approach, allows for a more efficient and systematic discovery of improved catalysts. (b) the focus is on exploring alloy materials which have been largely unexplored as potential reforming catalysts.

Suljo Linic

2008-12-31T23:59:59.000Z

192

Upgrading Methane Using Ultra-Fast Thermal Swing Adsorption  

SciTech Connect (OSTI)

The purpose of this project is to design and demonstrate an approach to upgrade low-BTU methane streams from coal mines to pipeline-quality natural gas. The objective of Phase I of the project was to assess the technical feasibility and cost of upgrading low-BTU methane streams using ultra-fast thermal swing adsorption (TSA) using Velocys modular microchannel process technology. The objective of Phase II is to demonstrate the process at the bench scale. The project is on schedule and on budget. A technical and economic feasibility assessment was completed in Task 3. The proposed Velocys technology appears feasible for the methane upgrading market. Evaluated categories include adsorbent selection, rapid-cycle valve selection, microchannel manufacturability assessment, and system design and cost. The selected adsorbent, granular microporous carbon from either Barnaby-Sutcliffe or Calgon, experimentally demonstrated sufficient methane capacity under differential temperature at 100 pounds per square inch gauge. Several valve options were identified, including candidates that can operate millions of cycles between refurbishment. The microchannel adsorber and desorber designs were made using internal Velocys manufacturability standards, and the associated costs are acceptable as included with the complete nitrogen rejection unit (NRU) cost projection. A system design and cost estimate was completed for the NRU section of the methane upgrading system. As integrated into the complete system, the cost is in line with the market requirement. The system has six main unit operations: feed compressor, dehydration unit, nitrogen rejection unit, deoxygenator, carbon dioxide scrubber, and a sales compressor. The NRU is the focus of the development program, and a bench-scale demonstration will be initiated in the next fiscal year. The Velocys NRU system targets producing methane with greater than 96% purity and at least 90% recovery for final commercial operation. A preliminary cost analysis of the methane upgrading system, including the Velocys NRU, suggests that costs below $2.00 per million (MM) BTU methane may be achieved. The cost for a conventional methane upgrading system is well above $2.30 per MM BTU, as benchmarked in an Environmental Protection Agency study.

Anna Lee Tonkovich

2004-07-01T23:59:59.000Z

193

Conversion of methane to higher hydrocarbons (Biomimetic catalysis of the conversion of methane to methanol). Final report  

SciTech Connect (OSTI)

In addition to inorganic catalysts that react with methane, it is well-known that a select group of aerobic soil/water bacteria called methanotrophs can efficiently and selectively utilize methane as the sole source of their energy and carbon for cellular growth. The first reaction in this metabolic pathway is catalyzed by the enzyme methane monooxygenase (MMO) forming methanol. Methanol is a technology important product from this partial oxidation of methane since it can be easily converted to liquid hydrocarbon transportation fuels (gasoline), used directly as a liquid fuel or fuel additive itself, or serve as a feedstock for chemicals production. This naturally occurring biocatalyst (MMO) is accomplishing a technologically important transformation (methane directly to methanol) for which there is currently no analogous chemical (non-biological) process. The authors approach has been to use the biocatalyst, MMO, as the initial focus in the development of discrete chemical catalysts (biomimetic complexes) for methane conversion. The advantage of this approach is that it exploits a biocatalytic system already performing a desired transformation of methane. In addition, this approach generated needed new experimental information on catalyst structure and function in order to develop new catalysts rationally and systematically. The first task is a comparative mechanistic, biochemical, and spectroscopic investigation of MMO enzyme systems. This work was directed at developing a description of the structure and function of the catalytically active sites in sufficient detail to generate a biomimetic material. The second task involves the synthesis, characterization, and chemical reactions of discrete complexes that mimic the enzymatic active site. These complexes were synthesized based on their best current understanding of the MMO active site structure.

Watkins, B.E.; Taylor, R.T.; Satcher, J.H. [and others

1993-09-01T23:59:59.000Z

194

Methane escape from gas hydrate systems in marine environment, and methane-driven oceanic eruptions  

E-Print Network [OSTI]

Methane escape from gas hydrate systems in marine environment, and methane-driven oceanic eruptions quantities of CH4 are stored in marine sediment in the form of methane hydrate, bubbles, and dissolved CH4 in pore water. Here I discuss the various pathways for methane to enter the ocean and atmosphere

Zhang, Youxue

195

Activation of the C-H Bond of Methane by Intermediate Q of Methane Monooxygenase: A  

E-Print Network [OSTI]

Activation of the C-H Bond of Methane by Intermediate Q of Methane Monooxygenase: A Theoretical component (MMOH) of the multicomponent soluble methane monooxygenase (MMO) system catalyzes the oxidation of methane by dioxygen to form methanol and water at non-heme, dinuclear iron active sites. The catalytic

Gherman, Benjamin F.

196

Methane oxidation associated with submerged brown mosses reduces methane emissions from Siberian  

E-Print Network [OSTI]

Methane oxidation associated with submerged brown mosses reduces methane emissions from Siberian, University of Hamburg, Allende-Platz 2, 20146 Hamburg, Germany Summary 1. Methane (CH4) oxidation to Sphagnum species and low-pH peatlands. 2. Moss-associated methane oxidation (MAMO) can be an effective

Wehrli, Bernhard

197

Nonequilibrium clumped isotope signals in microbial methane  

E-Print Network [OSTI]

Methane is a key component in the global carbon cycle with a wide range of anthropogenic and natural sources. Although isotopic compositions of methane have traditionally aided source identification, the abundance of its ...

Wang, David T.

198

Testing of a Catalytic Partial Oxidation Diesel Reformer with a Solid Oxide Fuel Cell System  

SciTech Connect (OSTI)

Rural Alaska currently uses diesel generator sets to produce much of its power. The high energy content of diesel (i.e. ~140,000 BTU per gallon) makes it the fuel of choice because this reduces the volume of fuel that must be transported, stored, and consumed in generating the power. There is an existing investment in infrastructure for the distribution and use of diesel fuel. Problems do exist, however, in that diesel generators are not very efficient in their use of diesel, maintenance levels can be rather high as systems age, and the environmental issues related to present diesel generators are of concern. The Arctic Energy Technology Development Laboratory at the University of Alaska -- Fairbanks is sponsoring a project to address the issues mentioned above. The project takes two successful systems, a diesel reformer and a tubular solid oxide fuel cell unit, and jointly tests those systems with the objective of producing a for-purpose diesel fueled solid oxide fuel cell system that can be deployed in rural Alaska. The reformer will convert the diesel to a mixture of carbon monoxide and hydrogen that can be used as a fuel by the fuel cell. The high temperature nature of the solid oxide fuel cell (SOFC is capable of using this mixture to generate electricity and provide usable heat with higher efficiency and lower emissions. The high temperature nature of the SOFC is more compatible with the arctic climate than are low temperature technologies such as the proton exchange membrane fuel cells. This paper will look at the interaction of a SOFC system that is designed to internally reform methane and a catalytic partial oxidation (CPOX) diesel reformer. The diesel reformer produces a reformate that is approximately 140 BTU per scf (after removal of much of the reformate water) as compared to a methane based reformate that is over twice that value in BTU content. The project also considers the effect of altitude since the test location will be at 4800 feet with the consequential drop in oxygen content and necessary increases in flow rates.

Lyman Frost; Bob Carrington; Rodger McKain; Dennis Witmer

2005-03-01T23:59:59.000Z

199

Method for the photocatalytic conversion of methane  

DOE Patents [OSTI]

A method for converting methane to methanol is provided comprising subjecting the methane to visible light in the presence of a catalyst and an electron transfer agent. Another embodiment of the invention provides for a method for reacting methane and water to produce methanol and hydrogen comprising preparing a fluid containing methane, an electron transfer agent and a photolysis catalyst, and subjecting said fluid to visible light for an effective period of time. 3 figs.

Noceti, R.P.; Taylor, C.E.; D`Este, J.R.

1998-02-24T23:59:59.000Z

200

Method for the photocatalytic conversion of methane  

DOE Patents [OSTI]

A method for converting methane to methanol is provided comprising subjecting the methane to visible light in the presence of a catalyst and an electron transfer agent. Another embodiment of the invention provides for a method for reacting methane and water to produce methanol and hydrogen comprising preparing a fluid containing methane, an electron transfer agent and a photolysis catalyst, and subjecting said fluid to visible light for an effective period of time.

Noceti, Richard P. (Pittsburgh, PA); Taylor, Charles E. (Pittsburgh, PA); D'Este, Joseph R. (Pittsburgh, PA)

1998-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "methane reforming process" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Coalbed methane production case histories  

SciTech Connect (OSTI)

The production of methane gas from coal and coal-bearing rocks is one of the prime objectives of the Department of Energy's Methane Recovery from Coalbeds Project. This report contains brief description of wells that are presently producing gas from coal or coal-bearing rocks. Data from three gob gas production areas in Illinois, an in-mine horizontal borehole degasification, and eleven vertical boreholes are presented. Production charts and electric logs of the producing zones are included for some of the wells. Additional information on dry gas production from the San Juan Basin, Colorado/New Mexico and the Greater Green River Coal Region, Colorado/Wyoming is also included.

Not Available

1981-02-01T23:59:59.000Z

202

Methane adsorption on Devonian shales  

E-Print Network [OSTI]

METHANE ADSORPTION ON DEVONIAN SHALES A Thesis by FAN-CHANG LI Submitted to thc Office of Graclua4e Sturiics of texas AgiM Ulllvel'sliy in pari, ial fulfilhuent of t, hc requirements I'or t, hc degree of ii IAS'I'Elf OF SCIL'NCE December... 1992 Major Subject, : Chemical Engineering METHANE ADSORPTION ON DEVONIAN SHALES A Thesis l&y I'AN-CHANC LI Approved as to style and contcut by: A. T. 'vtratson (Chair of Commitl. ee) John C. Slattery (Member) Bruce . Hcrhcrt (Memhcr...

Li, Fan-Chang

1992-01-01T23:59:59.000Z

203

Biogeochemistry of Microbial Coal-Bed Methane  

E-Print Network [OSTI]

Biogeochemistry of Microbial Coal-Bed Methane Dariusz StrapoÂŽc,1, Maria Mastalerz,2 Katherine, biodegradation Abstract Microbial methane accumulations have been discovered in multiple coal- bearing basins low-maturity coals with predominantly microbial methane gas or uplifted coals containing older

Macalady, Jenn

204

6, 36113626, 2006 Effects of methane  

E-Print Network [OSTI]

ACPD 6, 3611­3626, 2006 Effects of methane outgassing on the Black Sea atmosphere K. Kourtidis et a Creative Commons License. Atmospheric Chemistry and Physics Discussions Effects of methane outgassing Effects of methane outgassing on the Black Sea atmosphere K. Kourtidis et al. Title Page Abstract

Paris-Sud XI, Université de

205

2, 11971241, 2005 Control of methane  

E-Print Network [OSTI]

BGD 2, 1197­1241, 2005 Control of methane efflux at the Tommeliten seep area H. Niemann et al Biogeosciences Discussions is the access reviewed discussion forum of Biogeosciences Methane emission;BGD 2, 1197­1241, 2005 Control of methane efflux at the Tommeliten seep area H. Niemann et al. Title

Boyer, Edmond

206

Methane generation from waste materials  

DOE Patents [OSTI]

An organic solid waste digester for producing methane from solid waste, the digester comprising a reactor vessel for holding solid waste, a sprinkler system for distributing water, bacteria, and nutrients over and through the solid waste, and a drainage system for capturing leachate that is then recirculated through the sprinkler system.

Samani, Zohrab A. (Las Cruces, NM); Hanson, Adrian T. (Las Cruces, NM); Macias-Corral, Maritza (Las Cruces, NM)

2010-03-23T23:59:59.000Z

207

Chemical Processing in High-Pressure Aqueous Environments. 7. Process Development for Catalytic Gasification of Wet Biomass Feedstocks  

SciTech Connect (OSTI)

Through the use of a metal catalyst, gasification of wet biomass can be accomplished with high levels of carbon conversion to gas at relatively low temperature (350 C). In the pressurized-water environment (20 MPa) near-total conversion of the organic structure of biomass to gases has been accomplished in the presence of a ruthenium metal catalyst. The process is essentially steam reforming as there is no added oxidizer or reagent other than water. In addition, the gas produced is a medium-heating value gas due to the synthesis of high-levels of methane, as dictated by thermodynamic equilibrium. Biomass trace components cause processing difficulties using the fixed catalyst bed tubular reactor system. Results are described for both bench-scale and scaled-up reactor systems.

Elliott, Douglas C.; Neuenschwander, Gary G.; Hart, Todd R.; Butner, Scott S.; Zacher, Alan H.; Engelhard, Mark H.; Young, James S.; McCready, David E.

2004-07-01T23:59:59.000Z

208

Progress toward Biomass and Coal-Derived Syngas Warm Cleanup: Proof-of-Concept Process Demonstration of Multicontaminant Removal for Biomass Application  

SciTech Connect (OSTI)

Systems comprising of multiple sorbent and catalytic beds have been developed for the warm syngas cleanup of coal- and biomass-derived syngas. Tailored specifically for biomass application the process described here consists of six primary unit operations: 1) Na2CO3 bed for HCl removal, 2) two regenerable ZnO beds for bulk H2S removal, 3) ZnO bed for H2S polishing, 4) NiCu/SBA-16 sorbent for trace metal (e.g. AsH3) removal, 5) steam reforming catalyst bed for tars and light hydrocarbons reformation and NH3 decomposition, and a 6) Cu-based LT-WGS catalyst bed. Simulated biomass-derived syngas containing a multitude of inorganic contaminants (H2S, AsH3, HCl, and NH3) and hydrocarbon additives (methane, ethylene, benzene, and naphthalene) was used to demonstrate process effectiveness. The efficiency of the process was demonstrated for a period of 175 hours, during which no signs of deactivation were observed. Post-run analysis revealed small levels of sulfur slipped through the sorbent bed train to the two downstream catalytic beds. Future improvements could be made to the trace metal polishing sorbent to ensure complete inorganic contaminant removal (to low ppb level) prior to the catalytic steps. However, dual, regenerating ZnO beds were effective for continuous removal for the vast majority of the sulfur present in the feed gas. The process was effective for complete AsH3 and HCl removal. The steam reforming catalyst completely reformed all the hydrocarbons present in the feed (methane, ethylene, benzene, and naphthalene) to additional syngas. However, post-run evaluation, under kinetically-controlled conditions, indicates deactivation of the steam reforming catalyst. Spent material characterization suggests this is attributed, in part, to coke formation, likely due to the presence of benzene and/or naphthalene in the feed. Future adaptation of this technology may require dual, regenerable steam reformers. The process and materials described in this report hold promise for a warm cleanup of a variety of contaminant species within warm syngas.

Howard, Christopher J.; Dagle, Robert A.; Lebarbier, Vanessa MC; Rainbolt, James E.; Li, Liyu; King, David L.

2013-06-19T23:59:59.000Z

209

Method of steam reforming methanol to hydrogen  

DOE Patents [OSTI]

The production of hydrogen by the catalyzed steam reforming of methanol is accomplished using a reformer of greatly reduced size and cost wherein a mixture of water and methanol is superheated to the gaseous state at temperatures of about 800.degree. to about 1,100.degree. F. and then fed to a reformer in direct contact with the catalyst bed contained therein, whereby the heat for the endothermic steam reforming reaction is derived directly from the superheated steam/methanol mixture.

Beshty, Bahjat S. (Lower Makefield, PA)

1990-01-01T23:59:59.000Z

210

Attrition resistant fluidizable reforming catalyst  

DOE Patents [OSTI]

A method of preparing a steam reforming catalyst characterized by improved resistance to attrition loss when used for cracking, reforming, water gas shift and gasification reactions on feedstock in a fluidized bed reactor, comprising: fabricating the ceramic support particle, coating a ceramic support by adding an aqueous solution of a precursor salt of a metal selected from the group consisting of Ni, Pt, Pd, Ru, Rh, Cr, Co, Mn, Mg, K, La and Fe and mixtures thereof to the ceramic support and calcining the coated ceramic in air to convert the metal salts to metal oxides.

Parent, Yves O. (Golden, CO); Magrini, Kim (Golden, CO); Landin, Steven M. (Conifer, CO); Ritland, Marcus A. (Palm Beach Shores, FL)

2011-03-29T23:59:59.000Z

211

Ion acceleration processes at reforming collisionless shocks  

E-Print Network [OSTI]

The identification of pre-acceleration mechanisms for cosmic ray ions in supernova remnant shocks is an important problem in astrophysics. Recent particle-in-cell (PIC) shock simulations have shown that inclusion of the full electron kinetics yields non-time-stationary solutions, in contrast to previous hybrid (kinetic ions, fluid electrons) simulations. Here, by running a PIC code at high phase space resolution, ion acceleration mechanisms associated with the time dependence of a supercritical collisionless perpendicular shock are examined. In particular the components of $\\int \\mathbf{F} \\cdot \\mathbf{v} dt$ are analysed along trajectories for ions that reach both high and low energies. Selection mechanisms for the ions that reach high energies are also examined. In contrast to quasi-stationary shock solutions, the suprathermal protons are selected from the background population on the basis of the time at which they arrive at the shock, and thus are generated in bursts.

R. E. Lee; S. C. Chapman; R. O. Dendy

2004-10-25T23:59:59.000Z

212

INTEGRAL CATALYTIC COMBUSTION/FUEL REFORMING  

E-Print Network [OSTI]

INTEGRAL CATALYTIC COMBUSTION/FUEL REFORMING FOR GAS TURBINE Prepared For: California Energy REPORT (FAR) INTEGRAL CATALYTIC COMBUSTION/FUEL REFORMING FOR GAS TURBINE CYCLES EISG AWARDEE University://www.energy.ca.gov/research/index.html. #12;Page 1 Integral Catalytic Combustion/Fuel Reforming for Gas Turbine Cycles EISG Grant # 99

213

Methane Digesters and Biogas Recovery - Masking the Environmental Consequences of Industrial Concentrated Livestock Production  

E-Print Network [OSTI]

Methane Digesters and Biogas Recovery-Masking theII. METHANE DIGESTERS AND BIOGAs RECOVERY- IN THE2011] METHANE DIGESTERS AND BIOGAS RECOVERY methane, and 64%

Di Camillo, Nicole G.

2011-01-01T23:59:59.000Z

214

Reduction of titania by methane-hydrogen-argon gas mixture  

SciTech Connect (OSTI)

Reduction of titania using methane-containing gas was investigated in a laboratory fixed-bed reactor in the temperature range 1,373 to 1,773 K. The reduction production product is titanium oxycarbide, which is a solid solution of TiC and TiO. At 1,373 K, the formation rate of TiC is very slow. The rate and extent of reaction increase with increasing temperature to 1,723 K. A further increase in temperature to 1,773 K does not affect the reaction rate and extent. An increase in methane concentration to 8 vol pct favors the reduction process. A further increase in methane concentration above 8 vol pct causes excessive carbon deposition, which has a negative effect on the reaction rate. Hydrogen partial pressure should be maintained above 35 vol pct to depress the cracking of methane. Addition of water vapor to the reducing gas strongly retards the reduction reaction, even at low concentrations of 1 to 2 vol pct. Carbon monoxide also depresses the reduction process, but its effect is significant only at higher concentrations, above 10 vol pct.

Zhang, G.; Ostrovski, O.

2000-02-01T23:59:59.000Z

215

Kinetics of methanation on nickel catalysts  

SciTech Connect (OSTI)

Extensive steady-state and transient measurements of the disproportionation of carbon monoxide, the hydrogenation of deposited carbon, and methanation of carbon monoxide were performed over 2 and 10% nickel on silica support. The results indicated that the methanation of carbon monoxide involves competitively adsorbed species; that the reaction is nearly zero order in carbon monoxide at 0.1-0.5 atm CO and 1 atm H/sub 2/, but negative at higher CO partial pressures and that it becomes less negative with increasing temperature or increasing hydrogen pressure; and that the reaction order with respect to hydrogen changes from 0.5 to 1.0 with increasing CO pressure and decreasing H/sub 2/ pressure. A reaction mechanism is proposed which consists of the molecular adsorption of CO, the dissociative adsorption of H/sub 2/, dissociation of the surface CO species, and reaction of two adsorbed hydrogen atoms with the oxygen; and a multistep hydrogenation and desorption process for the adsorbed carbon. The dissociation and reaction of adsorbed CO is probably the rate-limiting step. The kinetic behavior is best represented with the assumption of a heterogeneous catalyst surface, containing three types of sites of widely varying activity.

Ho, S.V.; Harriott, P.

1980-08-01T23:59:59.000Z

216

Chemical Processing in High-Pressure Aqueous Environments. 9. Process Development for Catalytic Gasification of Algae Feedstocks  

SciTech Connect (OSTI)

Through the use of a metal catalyst, gasification of wet algae slurries can be accomplished with high levels of carbon conversion to gas at relatively low temperature (350 C). In a pressurized-water environment (20 MPa), near-total conversion of the organic structure of the algae to gases has been achieved in the presence of a supported ruthenium metal catalyst. The process is essentially steam reforming, as there is no added oxidizer or reagent other than water. In addition, the gas produced is a medium-heating value gas due to the synthesis of high levels of methane, as dictated by thermodynamic equilibrium. As opposed to earlier work, biomass trace components were removed by processing steps so that they did not cause processing difficulties in the fixed catalyst bed tubular reactor system. As a result, the algae feedstocks, even those with high ash contents, were much more reliably processed. High conversions were obtained even with high slurry concentrations. Consistent catalyst operation in these short-term tests suggested good stability and minimal poisoning effects. High methane content in the product gas was noted with significant carbon dioxide captured in the aqueous byproduct in combination with alkali constituents and the ammonia byproduct derived from proteins in the algae. High conversion of algae to gas products was found with low levels of byproduct water contamination and low to moderate loss of carbon in the mineral separation step.

Elliott, Douglas C.; Hart, Todd R.; Neuenschwander, Gary G.; Rotness, Leslie J.; Olarte, Mariefel V.; Zacher, Alan H.

2012-07-26T23:59:59.000Z

217

NEPA Contracting Reform Guidance  

Broader source: Energy.gov (indexed) [DOE]

NEPA process costs < NEPA contractor evaluation procedures < details on the DOE NEPA Web site U.S. Department of Energy, Office of NEPA Policy and Assistance, December 1996...

218

The Methane to Markets Coal Mine Methane Subcommittee meeting  

SciTech Connect (OSTI)

The presentations (overheads/viewgraphs) include: a report from the Administrative Support Group; strategy updates from Australia, India, Italy, Mexico, Nigeria, Poland and the USA; coal mine methane update and IEA's strategy and activities; the power of VAM - technology application update; the emissions trading market; the voluntary emissions reduction market - creating profitable CMM projects in the USA; an Italian perspective towards a zero emission strategies; and the wrap-up and summary.

NONE

2008-07-01T23:59:59.000Z

219

Feasibility Analysis of Steam Reforming of Biodiesel by-product Glycerol to Make Hydrogen  

E-Print Network [OSTI]

, lubricants, cleaners, and semiconductor circuits. It can be used to make electricity. NASA is the primary user of hydrogen as energy fuel-called fuel cells- to power the shuttle?s electrical system (Hydrogen Energy, 2008). Hydrogen can fuel tomorrow?s fuel-cell... wide application in industries and refineries. In the United States, about 17.2 billion pounds of hydrogen are produced per year and 95% are from steam reforming of methane (Hydrogen Now). It can be used as a fuel in tomorrow?s fuel-cell vehicles...

Joshi, Manoj

2009-06-09T23:59:59.000Z

220

High Efficiency Solar-based Catalytic Structure for CO{sub 2} Reforming  

SciTech Connect (OSTI)

Throughout this project, we developed and optimized various photocatalyst structures for CO{sub 2} reforming into hydrocarbon fuels and various commodity chemical products. We also built several closed-loop and continuous fixed-bed photocatalytic reactor system prototypes for a larger-scale demonstration of CO{sub 2} reforming into hydrocarbons, mainly methane and formic acid. The results achieved have indicated that with each type of reactor and structure, high reforming yields can be obtained by refining the structural and operational conditions of the reactor, as well as by using various sacrificial agents (hole scavengers). We have also demonstrated, for the first time, that an aqueous solution containing acid whey (a common bio waste) is a highly effective hole scavenger for a solar-based photocatalytic reactor system and can help reform CO{sub 2} into several products at once. The optimization tasks performed throughout the project have resulted in efficiency increase in our conventional reactors from an initial 0.02% to about 0.25%, which is 10X higher than our original project goal. When acid whey was used as a sacrificial agent, the achieved energy efficiency for formic acid alone was ~0.4%, which is 16X that of our original project goal and higher than anything ever reported for a solar-based photocatalytic reactor. Therefore, by carefully selecting sacrificial agents, it should be possible to reach energy efficiency in the range of the photosynthetic efficiency of typical crop and biofuel plants (1-3%).

Menkara, Hisham

2013-09-30T23:59:59.000Z

Note: This page contains sample records for the topic "methane reforming process" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Steam Reforming of Low-Level Mixed Waste  

SciTech Connect (OSTI)

Under DOE Contract No. DE-AR21-95MC32091, Steam Reforming of Low-Level Mixed Waste, ThermoChem has successfully designed, fabricated and operated a nominal 90 pound per hour Process Development Unit (PDU) on various low-level mixed waste surrogates. The design construction, and testing of the PDU as well as performance and economic projections for a 500- lb/hr demonstration and commercial system are described. The overall system offers an environmentally safe, non-incinerating, cost-effective, and publicly acceptable method of processing LLMW. The steam-reforming technology was ranked the No. 1 non-incineration technology for destruction of hazardous organic wastes in a study commissioned by the Mixed Waste Focus Area published April 1997.1 The ThermoChem steam-reforming system has been developed over the last 13 years culminating in this successful test campaign on LLMW surrogates. Six surrogates were successfidly tested including a 750-hour test on material simulating a PCB- and Uranium- contaminated solid waste found at the Portsmouth Gaseous Diffusion Plant. The test results indicated essentially total (>99.9999oA) destruction of RCRA and TSCA hazardous halogenated organics, significant levels of volume reduction (> 400 to 1), and retention of radlonuclides in the volume-reduced solids. Cost studies have shown the steam-reforming system to be very cost competitive with more conventional and other emerging technologies.

None

1998-01-01T23:59:59.000Z

222

Nickel crystallite thermometry during methanation  

SciTech Connect (OSTI)

A magnetic method to measure the average temperature of superparamagnetic nickel crystallites has been applied during CO methanation. The method takes advantage of the temperature dependence of the low field magnetization of such catalysts; however, the adsorption of carbon monoxide and the formation of surface carbon species complicate the interpretation of results. Calibrations to account for temperature change and the adsorption of reactants are described. The calibration for the effects of CO is based on the assumption that the interaction of CO with nickel is the same for methanation and disproportionation. Interphase heat transfer calculations based on the thermometric data compare favorably with previous results from ethane hyrogenolysis, and give no indication of microscopic temperature differences between the nickel crystallites and support.

Ludlow, D.K.; Cale, T.S.

1986-01-01T23:59:59.000Z

223

Partial oxidation of methane to syngas in different reactor types  

SciTech Connect (OSTI)

The performance of Rh/ZnO/{gamma}-Al{sub 2}O{sub 3} catalyst for partial oxidation of methane to syngas was compared in fixed and fluidised bed reactors. Catalyst activity was found not to be a limiting factor under any experimental conditions and complete oxygen conversions were observed in all tests. In the fixed bed reactor both methane conversion and syngas selectivity were increasing with space velocity as the result of an autothermal effect. Satisfactory control of the catalyst temperature at high space velocities could only be achieved with addition of inert diluent or steam to the feed. Different conversion and selectivity patterns were observed in fluidised bed reactor. Methane conversion and carbon monoxide selectivity were decreasing with increasing gas flow. By contrast, hydrogen selectivity showed distinct maximum at medium space velocities. These results are interpreted in terms of catalyst backmixing and its effect on primary and secondary reactions. Improved temperature control was also achieved in fluidised bed reactor. Several experiments using fluidised bed reactor were carried out at elevated pressures. To eliminate the occurrence of non-catalytic gas phase reactions between methane and oxygen very short feed mixing times (< 1 ms) were employed. Despite these measures the reactor could not be successfully operated at pressures above 0.7 MPa. The implications of these findings for process development are discussed.

Lapszewicz, J.A.; Campbell, I.; Charlton, B.G.; Foulds, G.A. [CSIRO Division of Coal and Energy Technology, Menai (Australia)

1995-12-01T23:59:59.000Z

224

Assessing the Efficacy of the Aerobic Methanotrophic Biofilter in Methane Hydrate Environments  

SciTech Connect (OSTI)

In October 2008 the University of California at Santa Barbara (UCSB) initiated investigations of water column methane oxidation in methane hydrate environments, through a project funded by the National Energy Technology Laboratory (NETL) entitled: assessing the efficacy of the aerobic methanotrophic biofilter in methane hydrate environments. This Final Report describes the scientific advances and discoveries made under this award as well as the importance of these discoveries in the broader context of the research area. Benthic microbial mats inhabit the sea floor in areas where reduced chemicals such as sulfide reach the more oxidizing water that overlies the sediment. We set out to investigate the role that methanotrophs play in such mats at locations where methane reaches the sea floor along with sulfide. Mats were sampled from several seep environments and multiple sets were grown in-situ at a hydrocarbon seep in the Santa Barbara Basin. Mats grown in-situ were returned to the laboratory and used to perform stable isotope probing experiments in which they were treated with 13C-enriched methane. The microbial community was analyzed, demonstrating that three or more microbial groups became enriched in methane?s carbon: methanotrophs that presumably utilize methane directly, methylotrophs that presumably consume methanol excreted by the methanotrophs, and sulfide oxidizers that presumably consume carbon dioxide released by the methanotrophs and methylotrophs. Methanotrophs reached high relative abundance in mats grown on methane, but other bacterial processes include sulfide oxidation appeared to dominate mats, indicating that methanotrophy is not a dominant process in sustaining these benthic mats, but rather a secondary function modulated by methane availability. Methane that escapes the sediment in the deep ocean typically dissolved into the overlying water where it is available to methanotrophic bacteria. We set out to better understand the efficacy of this process as a biofilter by studying the distribution of methane oxidation and disposition of methanotrophic populations in the Pacific Ocean. We investigated several environments including the basins offshore California, the continental margin off Central America, and the shallow waters around gas seeps. We succeeded in identifying the distributions of activity in these environments, identified potential physical and chemical controls on methanotrophic activity, we further revealed details about the methanotrophic communities active in these settings, and we developed new approaches to study methanotrophic communities. These findings should improve our capacity to predict the methanotrophic response in ocean waters, and further our ability to generate specific hypotheses as to the ecology and efficacy of pelagic methanotrophic communites. The discharge of methane and other hydrocarbons to Gulf of Mexico that followed the sinking of the Deepwater Horizon provided a unique opportunity to study the methanotorphic biofilter in the deep ocean environment. We set out to understand the consumption of methane and the bloom of methanotrophs resulting from this event, as a window into the regional scale release of gas hydrate under rapid warming scenarios. We found that other hydrocarbon gases, notably propane and ethane, were preferred for consumption over methane, but that methane consumption accelerated rapidly and drove the depletion of methane within a matter of months after initial release. These results revealed the identity of the responsible community, and point to the importance of the seed population in determining the rate at which a methanotrophic community is able to respond to an input of methane. Collectively, these results provide a significant advance in our understanding of the marine methanotrohic biofilter, and further provide direction and context for future investigations of this important phenomenon. This project has resulted in fourteen publications to date, with five more circulating in draft form, and several others planned.

Valentine, David

2012-09-30T23:59:59.000Z

225

Effect of adding nitrogen on the yield of hydrogen cyanide in oxidative ammonolysis of methane  

SciTech Connect (OSTI)

On the basis of an empirical model of the process of oxidative ammonolysis of methane, a study was made of the effect of adding nitrogen to the initial methane-ammonia-air mixture. In the general case, the N{sub 2} introduction was shown to decrease the autothermal temperature of the synthesis, though at small flows of the initial mixture some increase in t{sub conv} is possible. An explanation of this phenomenon was proposed.

Grin, G.I.; Trusov, N.V.; Dmitriev, N.M.

1994-02-20T23:59:59.000Z

226

Verification of the Accountability Method as a Means to Classify Radioactive Wastes Processed Using THOR Fluidized Bed Steam Reforming at the Studsvik Processing Facility in Erwin, Tennessee, USA - 13087  

SciTech Connect (OSTI)

Studsviks' Processing Facility Erwin (SPFE) has been treating Low-Level Radioactive Waste using its patented THOR process for over 13 years. Studsvik has been mixing and processing wastes of the same waste classification but different chemical and isotopic characteristics for the full extent of this period as a general matter of operations. Studsvik utilizes the accountability method to track the movement of radionuclides from acceptance of waste, through processing, and finally in the classification of waste for disposal. Recently the NRC has proposed to revise the 1995 Branch Technical Position on Concentration Averaging and Encapsulation (1995 BTP on CA) with additional clarification (draft BTP on CA). The draft BTP on CA has paved the way for large scale blending of higher activity and lower activity waste to produce a single waste for the purpose of classification. With the onset of blending in the waste treatment industry, there is concern from the public and state regulators as to the robustness of the accountability method and the ability of processors to prevent the inclusion of hot spots in waste. To address these concerns and verify the accountability method as applied by the SPFE, as well as the SPFE's ability to control waste package classification, testing of actual waste packages was performed. Testing consisted of a comprehensive dose rate survey of a container of processed waste. Separately, the waste package was modeled chemically and radiologically. Comparing the observed and theoretical data demonstrated that actual dose rates were lower than, but consistent with, modeled dose rates. Moreover, the distribution of radioactivity confirms that the SPFE can produce a radiologically homogeneous waste form. The results of the study demonstrate: 1) the accountability method as applied by the SPFE is valid and produces expected results; 2) the SPFE can produce a radiologically homogeneous waste; and 3) the SPFE can effectively control the waste package classification. (authors)

Olander, Jonathan [Studsvik Processing Facility Erwin, 151 T.C. Runnion Rd., Erwin, TN 37650 (United States)] [Studsvik Processing Facility Erwin, 151 T.C. Runnion Rd., Erwin, TN 37650 (United States); Myers, Corey [Studsvik, Inc., 5605 Glenridge Drive, Suite 705, Atlanta, GA 30342 (United States)] [Studsvik, Inc., 5605 Glenridge Drive, Suite 705, Atlanta, GA 30342 (United States)

2013-07-01T23:59:59.000Z

227

Miscellaneous States Coalbed Methane Proved Reserves Revision...  

U.S. Energy Information Administration (EIA) Indexed Site

Revision Decreases (Billion Cubic Feet) Miscellaneous States Coalbed Methane Proved Reserves Revision Decreases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4...

228

,"Colorado Coalbed Methane Proved Reserves, Reserves Changes...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Colorado Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2013,"630...

229

,"Arkansas Coalbed Methane Proved Reserves, Reserves Changes...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Arkansas Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2013,"630...

230

,"Wyoming Coalbed Methane Proved Reserves, Reserves Changes,...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Wyoming Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2013,"630...

231

A guide to coalbed methane operations  

SciTech Connect (OSTI)

A guide to coalbed methane production is presented. The guide provides practical information on siting, drilling, completing, and producing coalbed methane wells. Information is presented for experienced coalbed methane producers and coalbed methane operations. The information will assist in making informed decisions about producing this resource. The information is presented in nine chapters on selecting and preparing of field site, drilling and casing the wellbore, wireline logging, completing the well, fracturing coal seams, selecting production equipment and facilities, operating wells and production equipment, treating and disposing of produced water, and testing the well.

Hollub, V.A.; Schafer, P.S.

1992-01-01T23:59:59.000Z

232

,"Montana Coalbed Methane Proved Reserves, Reserves Changes,...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Montana Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2013,"630...

233

,"Oklahoma Coalbed Methane Proved Reserves, Reserves Changes...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Oklahoma Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2013,"630...

234

,"Virginia Coalbed Methane Proved Reserves, Reserves Changes...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Virginia Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2013,"630...

235

CO2 Sequestration Enhances Coalbed Methane Production.  

E-Print Network [OSTI]

??Since 1980s, petroleum engineers and geologists have conducted researches on Enhanced Coalbed Methane Recovery (ECBM). During this period, many methods are introduced to enhance the… (more)

Pang, Yu

2013-01-01T23:59:59.000Z

236

,"Pennsylvania Coalbed Methane Proved Reserves, Reserves Changes...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Pennsylvania Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2013,"630...

237

,"Miscellaneous Coalbed Methane Proved Reserves, Reserves Changes...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves, Reserves Changes, and Production" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Late...

238

,"Alabama Coalbed Methane Proved Reserves, Reserves Changes,...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Alabama Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2013,"630...

239

Analysis and Methane Gas Separations Studies for City of Marsing, Idaho An Idaho National Laboratory Technical Assistance Program Study  

SciTech Connect (OSTI)

Introduction and Background Large amounts of methane in well water is a wide spread problem in North America. Methane gas from decaying biomass and oil and gas deposits escape into water wells typically through cracks or faults in otherwise non-porous rock strata producing saturated water systems. This methane saturated water can pose several problems in the delivery of drinking water. The problems range from pumps vapor locking (cavitating), to pump houses exploding. The City of Marsing requested Idaho National Laboratory (INL) to assist with some water analyses as well as to provide some engineering approaches to methane capture through the INL Technical Assistance Program (TAP). There are several engineering approaches to the removal of methane and natural gas from water sources that include gas stripping followed by compression and/or dehydration; membrane gas separators coupled with dehydration processes, membrane water contactors with dehydration processes.

Christopher Orme

2012-08-01T23:59:59.000Z

240

A conduit dilation model of methane venting from lake sediments  

E-Print Network [OSTI]

Methane is a potent greenhouse gas, but its effects on Earth's climate remain poorly constrained, in part due to uncertainties in global methane fluxes to the atmosphere. An important source of atmospheric methane is the ...

Ruppel, Carolyn

Note: This page contains sample records for the topic "methane reforming process" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

ANALYSIS OF METHANE PRODUCING COMMUNITIES WITHIN UNDERGROUND COAL BEDS  

E-Print Network [OSTI]

ANALYSIS OF METHANE PRODUCING COMMUNITIES WITHIN UNDERGROUND COAL BEDS by Elliott Paul Barnhart ..................................................................................14 Ability of the Consortium to Produce Methane from Coal and Metabolites ................16.............................................................................................21 Coal and Methane Production

Maxwell, Bruce D.

242

Methane productivity and nutrient recovery from manure Henrik B. Mller  

E-Print Network [OSTI]

Methane productivity and nutrient recovery from manure Henrik B. Műller Danish Institute This thesis, entitled "Methane productivity and nutrient recovery from manure" is presented in partial of digested and separated products.................... 13 3. Methane productivity and greenhouse gas emissions

243

Plasma-catalyzed fuel reformer  

DOE Patents [OSTI]

A reformer is disclosed that includes a plasma zone to receive a pre-heated mixture of reactants and ionize the reactants by applying an electrical potential thereto. A first thermally conductive surface surrounds the plasma zone and is configured to transfer heat from an external heat source into the plasma zone. The reformer further includes a reaction zone to chemically transform the ionized reactants into synthesis gas comprising hydrogen and carbon monoxide. A second thermally conductive surface surrounds the reaction zone and is configured to transfer heat from the external heat source into the reaction zone. The first thermally conductive surface and second thermally conductive surface are both directly exposed to the external heat source. A corresponding method and system are also disclosed and claimed herein.

Hartvigsen, Joseph J.; Elangovan, S.; Czernichowski, Piotr; Hollist, Michele

2013-06-11T23:59:59.000Z

244

The Carnol process for CO{sub 2} mitigation from power plants and the transportation sector  

SciTech Connect (OSTI)

A carbon dioxide (CO{sub 2}) mitigation process is developed which converts waste CO{sub 2}, primarily from coal-fired power plant stack gases, to methanol for use as a liquid fuel and a coproduct carbon for use as a materials commodity. The Carnol process chemistry consists of methane decomposition to produce hydrogen which is catalytically reacted with the recovered waste CO{sub 2} to produce methanol. The carbon is either stored or sold. A process design is modeled, and mass and energy balances are presented as a function of reactor pressure and temperature conditions. The Carnol process is a viable alternative to sequestering CO{sub 2} in the ocean for purposes of reducing CO{sub 2} emissions from coal burning power plants. Over 90% of the CO{sub 2} from the coal burning plant is used in the process which results in a net CO{sub 2} emission reduction of over 90% compared to that obtained for conventional methanol production by steam reforming of methane. Methanol, as an alternative liquid fuel for automotive engines and for fuel cells, achieves additional CO{sub 2} emission reduction benefits. The economics of the process is greatly enhanced when carbon can be sold as a materials commodity. The process design and economics could possibly be achieved by developing a molten metal (tin) methane decomposition reactor and a liquid phase, slurry catalyst, methanol synthesis reactor directly using the solvent saturated with CO{sub 2} scrubbed from the power plant stack gases. The application of CO{sub 2} mitigation technologies, such as the Carnol process, depends to some extent, on how serious the country and the world takes the global greenhouse gas warming problem.

Steinberg, M.

1995-12-01T23:59:59.000Z

245

The Carnol process for CO{sub 2} mitigation from power plants and the transportation sector  

SciTech Connect (OSTI)

A CO{sub 2} mitigation process is developed which converts waste CO{sub 2}, primarily recovered from coal-fired power plant stack gases with natural gas, to produce methanol as a liquid fuel and coproduct carbon as a materials commodity. The Carnol process chemistry consists of methane decomposition to produce hydrogen which is catalytically reacted with the recovered waste CO{sub 2} to produce methanol. The carbon is either stored or sold as a materials commodity. A process design is modelled and mass and energy balances are presented as a function of reactor pressure and temperature conditions. The Carnol process is a viable alternative to sequestering CO{sub 2} in the ocean for purposes of reducing CO{sub 2} emissions from coal burning power plants. Over 90% of the CO{sub 2} from the coal burning plant is used in the process which results in a net CO{sub 2} emission reduction of over 90% compared to that obtained for conventional methanol production by steam reforming of methane. Methanol as an alternative liquid fuel for automotive engines and for fuel cells achieves additional CO{sub 2} emission reduction benefits. The economics of the process is greatly enhanced when carbon can be sold as a materials commodity. Improvement in process design and economics should be achieved by developing a molten metal (tin) methane decomposition reactor and a liquid phase, slurry catalyst, methanol synthesis reactor directly using the solvent saturated with CO{sub 2} scrubbed from the power plant stack gases. The benefits of the process warrant its further development.

Steinberg, M.

1995-08-01T23:59:59.000Z

246

Methane oxidation over dual redox catalysts. Final report  

SciTech Connect (OSTI)

Catalytic oxidation of methane to partial oxidation products, primarily formaldehyde and C{sub 2} hydrocarbons, was found to be directed by the catalyst used. In this project, it was discovered that a moderate oxidative coupling catalyst for C{sub 2} hydrocarbons, zinc oxide, is modified by addition of small amounts of Cu and Fe dopants to yield fair yields of formaldehyde. A similar effect was observed with Cu/Sn/ZnO catalysts, and the presence of a redox Lewis acid, Fe{sup III} or Sn{sup IV}, was found to be essential for the selectivity switch from C{sub 2} coupling products to formaldehyde. The principle of double doping with an oxygen activator (Cu) and the redox Lewis acid (Fe, Sn) was pursued further by synthesizing and testing the CuFe-ZSM-5 zeolite catalyst. The Cu{sup II}(ion exchanged) Fe{sup III}(framework)-ZSM-5 also displayed activity for formaldehyde synthesis, with space time yields exceeding 100 g/h-kg catalyst. However, the selectivity was low and earlier claims in the literature of selective oxidation of methane to methanol over CuFe-ZSM-5 were not reproduced. A new active and selective catalytic system (M=Sb,Bi,Sn)/SrO/La{sub 2}O{sub 3} has been discovered for potentially commercially attractive process for the conversion of methane to C{sub 2} hydrocarbons, (ii) a new principle has been demonstrated for selectivity switching from C{sub 2} hydrocarbon products to formaldehyde in methane oxidations over Cu,Fe-doped zinc oxide and ZSM-5, and (iii) a new approach has been initiated for using ultrafine metal dispersions for low temperature activation of methane for selective conversions. Item (iii) continues being supported by AMOCO while further developments related to items (i) and (ii) are the objective of our continued effort under the METC-AMOCO proposed joint program.

Klier, K.; Herman, R.G.; Sojka, Z.; DiCosimo, J.I.; DeTavernier, S.

1992-06-01T23:59:59.000Z

247

DATA QUALITY OBJECTIVES FOR SELECTING WASTE SAMPLES FOR BENCH-SCALE REFORMER TREATABILITY STUDIES  

SciTech Connect (OSTI)

This document describes the data quality objectives to select archived samples located at the 222-S Laboratory for Bench-Scale Reforming testing. The type, quantity, and quality of the data required to select the samples for Fluid Bed Steam Reformer testing are discussed. In order to maximize the efficiency and minimize the time to treat Hanford tank waste in the Waste Treatment and Immobilization Plant, additional treatment processes may be required. One of the potential treatment processes is the fluidized bed steam reformer. A determination of the adequacy of the fluidized bed steam reformer process to treat Hanford tank waste is required. The initial step in determining the adequacy of the fluidized bed steam reformer process is to select archived waste samples from the 222-S Laboratory that will be used in a bench scale tests. Analyses of the selected samples will be required to confirm the samples meet the shipping requirements and for comparison to the bench scale reformer (BSR) test sample selection requirements.

BANNING DL

2011-02-11T23:59:59.000Z

248

Fluxes of methane between landfills and the atmosphere: Natural and engineered controls  

SciTech Connect (OSTI)

Field measurement of landfill methane emissions indicates natural variability spanning more than 2 seven orders of magnitude, from approximately 0.0004 to more than 4000 g m{sub -2} day{sup -1}. This wide range reflects net emissions resulting from production (methanogenesis), consumption (methanotrophic oxidation), and gaseous transport processes. The determination of an {open_quotes}average{close_quotes} emission rate for a given field site requires sampling designs and statistical techniques which consider spatial and temporal variability. Moreover, particularly at sites with pumped gas recovery systems, it is possible for methanotrophic microorganisms in aerated cover soils to oxidize all of the methane from landfill sources below and, additionally, to oxidize methane diffusing into cover soils from atmospheric sources above. In such cases, a reversed soil gas concentration gradient is observed in shallow cover soils, indicating bidirectional diffusional transport to the depth of optimum methane oxidation. Rates of landfill methane oxidation from field and laboratory incubation studies range up to 166 g m{sup -2} day{sup -1} among the highest for any natural setting, providing an effective natural control on net emissions. Estimates of worldwide landfill methane emissions to the atmosphere have ranged from 9 to 70 Tg yr{sup -1}, differing mainly in assumed methane yields from estimated quantities of landfilled refuse. At highly controlled landfill sites in developed countries, landfill methane is often collected via vertical wells or horizontal collectors. Recovery of landfill methane through engineered systems can provide both environmental and energy benefits by mitigating subsurface migration, reducing surface emissions, and providing an alternative energy resource for industrial boiler use, on-site electrical generation, or upgrading to a substitute natural gas.

Bogner, J. [Argonne National Lab., IL (United States); Meadows, M. [ETSU, Harwell, Oxfordshire (United Kingdom); Czepiel, P. [Harvard Univ., Cambridge, MA (United States)

1997-08-01T23:59:59.000Z

249

Methane Recovery from Hydrate-bearing Sediments  

SciTech Connect (OSTI)

Gas hydrates are crystalline compounds made of gas and water molecules. Methane hydrates are found in marine sediments and permafrost regions; extensive amounts of methane are trapped in the form of hydrates. Methane hydrate can be an energy resource, contribute to global warming, or cause seafloor instability. This study placed emphasis on gas recovery from hydrate bearing sediments and related phenomena. The unique behavior of hydrate-bearing sediments required the development of special research tools, including new numerical algorithms (tube- and pore-network models) and experimental devices (high pressure chambers and micromodels). Therefore, the research methodology combined experimental studies, particle-scale numerical simulations, and macro-scale analyses of coupled processes. Research conducted as part of this project started with hydrate formation in sediment pores and extended to production methods and emergent phenomena. In particular, the scope of the work addressed: (1) hydrate formation and growth in pores, the assessment of formation rate, tensile/adhesive strength and their impact on sediment-scale properties, including volume change during hydrate formation and dissociation; (2) the effect of physical properties such as gas solubility, salinity, pore size, and mixed gas conditions on hydrate formation and dissociation, and it implications such as oscillatory transient hydrate formation, dissolution within the hydrate stability field, initial hydrate lens formation, and phase boundary changes in real field situations; (3) fluid conductivity in relation to pore size distribution and spatial correlation and the emergence of phenomena such as flow focusing; (4) mixed fluid flow, with special emphasis on differences between invading gas and nucleating gas, implications on relative gas conductivity for reservoir simulations, and gas recovery efficiency; (5) identification of advantages and limitations in different gas production strategies with emphasis; (6) detailed study of CH4-CO2 exchange as a unique alternative to recover CH4 gas while sequestering CO2; (7) the relevance of fines in otherwise clean sand sediments on gas recovery and related phenomena such as fines migration and clogging, vuggy structure formation, and gas-driven fracture formation during gas production by depressurization.

J. Carlos Santamarina; Costas Tsouris

2011-04-30T23:59:59.000Z

250

Solar Reforming of Carbon Dioxide to Produce Diesel Fuel  

SciTech Connect (OSTI)

This project focused on the demonstration of an innovative technology, referred to as the Sunexus CO2 Solar Reformer, which utilizes waste CO2 as a feedstock for the efficient and economical production of synthetic diesel fuel using solar thermal energy as the primary energy input. The Sunexus technology employs a two stage process for the conversion of CO2 to diesel fuel. A solar reforming system, including a specially designed reactor and proprietary CO2 reforming catalyst, was developed and used to convert captured CO2 rich gas streams into syngas (primarily hydrogen and carbon monoxide) using concentrated solar energy at high conversion efficiencies. The second stage of the system (which has been demonstrated under other funding) involves the direct conversion of the syngas into synthetic diesel fuel using a proprietary catalyst (Terra) previously developed and validated by Pacific Renewable Fuels and Chemicals (PRFC). The overall system energy efficiency for conversion of CO2 to diesel fuel is 74%, due to the use of solar energy. The results herein describe modeling, design, construction, and testing of the Sunexus CO2 Solar Reformer. Extensive parametric testing of the solar reformer and candidate catalysts was conducted and chemical kinetic models were developed. Laboratory testing of the Solar Reformer was successfully completed using various gas mixtures, temperatures, and gas flow rates/space velocities to establish performance metrics which can be employed for the design of commercial plants. A variety of laboratory tests were conducted including dry reforming (CO2 and CH{sub 4}), combination dry/steam reforming (CO2, CH{sub 4} & H{sub 2}O), and tri-reforming (CO2, CH{sub 4}, H{sub 2}O & O{sub 2}). CH{sub 4} and CO2 conversions averaged 95-100% and 50-90% per reformer cycle, respectively, depending upon the temperatures and gas space velocities. No formation of carbon deposits (coking) on the catalyst was observed in any of these tests. A 16 ft. diameter, concentrating solar dish was modified to accommodate the Sunexus CO2 Solar Reformer and the integrated system was installed at the Pacific Renewable Fuels and Chemicals test site at McClellan, CA. Several test runs were conducted without catalyst during which the ceramic heat exchanger in the Sunexus Solar Reformer reached temperatures between 1,050 F (566 C) and 2,200 F (1,204 C) during the test period. A dry reforming mixture of CO2/CH{sub 4} (2.0/1.0 molar ratio) was chosen for all of the tests on the integrated solar dish/catalytic reformer during December 2010. Initial tests were carried out to determine heat transfer from the collimated solar beam to the catalytic reactor. The catalyst was operated successfully at a steady-state temperature of 1,125 F (607 C), which was sufficient to convert 35% of the 2/1 CO2/CH{sub 4} mixture to syngas. This conversion efficiency confirmed the results from laboratory testing of this catalyst which provided comparable syngas production efficiencies (40% at 1,200 F [650 C]) with a resulting syngas composition of 20% CO, 16% H{sub 2}, 39% CO2 and 25% CH{sub 4}. As based upon the laboratory results, it is predicted that 90% of the CO2 will be converted to syngas in the solar reformer at 1,440 F (782 C) resulting in a syngas composition of 50% CO: 43% H{sub 2}: 7% CO2: 0% CH{sub 4}. Laboratory tests show that the higher catalyst operating temperature of 1,440 F (782 C) for efficient conversion of CO2 can certainly be achieved by optimizing solar reactor heat transfer, which would result in the projected 90% CO2-to-syngas conversion efficiencies. Further testing will be carried out during 2011, through other funding support, to further optimize the solar dish CO2 reformer. Additional studies carried out in support of this project and described in this report include: (1) An Assessment of Potential Contaminants in Captured CO2 from Various Industrial Processes and Their Possible Effect on Sunexus CO2 Reforming Catalysts; (2) Recommended Measurement Methods for Assessing Contaminant Levels in Captured CO2 Streams; (3) An Asse

Dennis Schuetzle; Robert Schuetzle

2010-12-31T23:59:59.000Z

251

Three-dimensional model synthesis of the global methane cycle  

E-Print Network [OSTI]

39, Ehhalt, D. H. , The atmo•heric cycle of methane, Tellugworld-wide increase in t•heric methane, 1978-1987, Science,

1991-01-01T23:59:59.000Z

252

Prediction of coalbed methane reservoir performance with type curves.  

E-Print Network [OSTI]

??Coalbed methane is an unconventional gas resource that consists of methane production from the coal seams. CBM reservoirs are dual-porosity systems that are characterized by… (more)

Bhavsar, Amol Bhaskar.

2005-01-01T23:59:59.000Z

253

Diffusion Characterization of Coal for Enhanced Coalbed Methane Production.  

E-Print Network [OSTI]

??This thesis explores the concept of displacement of sorbed methane and enhancement of methane recovery by injection of CO2 into coal, while sequestering CO2. The… (more)

Chhajed, Pawan

2011-01-01T23:59:59.000Z

254

Development of gas production type curves for coalbed methane reservoirs.  

E-Print Network [OSTI]

??Coalbed methane is an unconventional gas resource that consists on methane production from the coal seams. The unique coal characteristic results in a dual-porosity system.… (more)

Garcia Arenas, Anangela.

2004-01-01T23:59:59.000Z

255

Direct Observation of the Active Center for Methane Dehydroaromatizati...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the Active Center for Methane Dehydroaromatization Using an Ultrahigh Field 95Mo NMR Spectroscopy. Direct Observation of the Active Center for Methane Dehydroaromatization Using an...

256

Studies of the Active Sites for Methane Dehydroaromatization...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the Active Sites for Methane Dehydroaromatization Using Ultrahigh-Field Solid-State Mo95 NMR Spectroscopy. Studies of the Active Sites for Methane Dehydroaromatization Using...

257

Scientists detect methane levels three times larger than expected...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

methane that actually preceded recent concerns about potential emissions from fracking," Dubey said. Scientists detect methane levels three times larger than expected over...

258

Coalbed Methane (CBM) is natural  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up fromDepartmentTieCelebrate Earth DayFuelsDepartmentPolicyClean,Coalbed Methane (CBM)

259

Lessons Learned from Prior Attempts at National Security Reform The Project on National Security Reform  

E-Print Network [OSTI]

Lessons Learned from Prior Attempts at National Security Reform The Project on National Security was their solution effective? 4. What implications for present-day reformers can be drawn from this reform? Lessons learned from each chapter are summarized at the end of each section, and a synthesis of these findings

Lewis, Robert Michael

260

Hydrogen from Biomass by Autothermal Reforming  

Broader source: Energy.gov [DOE]

Presentation by Lanny D. Schmidt at the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

Note: This page contains sample records for the topic "methane reforming process" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Distributed Bio-Oil Reforming (Presentation)  

SciTech Connect (OSTI)

This presentation by Bob Evans at the 2007 DOE Hydrogen Program Annual Merit Review Meeting provides information about NREL's distributed bio-oil reforming efforts.

Evans, R. J.; Czernik, S.; French, R.; Ratcliff, M.; Marda, J.; Dean, A. M.

2007-05-15T23:59:59.000Z

262

High Activity of Ce1-xNixO2-y for H2 Production through Ethanol Steam Reforming: Tuning Catalytic Performance through Metal-Oxide Interactions  

SciTech Connect (OSTI)

The importance of the oxide: Ce{sub 0.8}Ni{sub 0.2}O{sub 2-y} is an excellent catalyst for ethanol steam reforming. Metal-oxide interactions perturb the electronic properties of the small particles of metallic nickel present in the catalyst under the reaction conditions and thus suppress any methanation activity. The nickel embedded in ceria induces the formation of O vacancies, which facilitate cleavage of the OH bonds in ethanol and water.

G Zhou; L Barrio; S Agnoli; S Senanayake; J Evans; A Kubacka; M Estrella; J Hanson; A Martinez-Arias; et al.

2011-12-31T23:59:59.000Z

263

Hydropyrolysis process  

DOE Patents [OSTI]

An improved process for producing a methane-enriched gas wherein a hydrogen-deficient carbonaceous material is treated with a hydrogen-containing pyrolysis gas at an elevated temperature and pressure to produce a product gas mixture including methane, carbon monoxide and hydrogen. The improvement comprises passing the product gas mixture sequentially through a water-gas shift reaction zone and a gas separation zone to provide separate gas streams of methane and of a recycle gas comprising hydrogen, carbon monoxide and methane for recycle to the process. A controlled amount of steam also is provided which when combined with the recycle gas provides a pyrolysis gas for treatment of additional hydrogen-deficient carbonaceous material. The amount of steam used and the conditions within the water-gas shift reaction zone and gas separation zone are controlled to obtain a steady-state composition of pyrolysis gas which will comprise hydrogen as the principal constituent and a minor amount of carbon monoxide, steam and methane so that no external source of hydrogen is needed to supply the hydrogen requirements of the process. In accordance with a particularly preferred embodiment, conditions are controlled such that there also is produced a significant quantity of benzene as a valuable coproduct.

Ullman, Alan Z. (Northridge, CA); Silverman, Jacob (Woodland Hills, CA); Friedman, Joseph (Huntington Beach, CA)

1986-01-01T23:59:59.000Z

264

The 1991 coalbed methane symposium proceedings  

SciTech Connect (OSTI)

The proceedings of the 1991 coalbed methane symposium are presented. The proceedings contains 50 papers on environmental aspects of recovering methane from coal seams, reservoir characterization and testing mine safety and productivity, coalbed stimulation, geology and resource assessment, well completion and production technologies, reservoir modeling and case histories, and resources and technology.

Not Available

1991-01-01T23:59:59.000Z

265

Comparative case studies of health reform in England  

E-Print Network [OSTI]

Comparative case studies of health reform in England Report submitted to the Department of Health........................................................................................14 1.1 Presenting the Health System Reform policy agenda...................................14 1 ..........................................................................................64 Demand Side Reform.........................................

Birmingham, University of

266

Apparatus for production of synthesis gas using convective reforming  

SciTech Connect (OSTI)

This patent describes a system for the steam reforming of hydrocarbons into a hydrogen-rich gas. It comprises a convective reformer device having indirect heat exchange means for partially reforming a feed mixture of hydrocarbons and steam; a steam reforming furnace having a radiant section, reforming tubes in the radiant section, and means for producing radiant heat for the further reforming of the partially reformed effluent; an auto-thermal reformer for fully reforming the effluent; conduit means for passing the partially reformed effluent; conduit means for passing the effluent; and conduit means for passing the fully reformed effluent to supply the heat of reaction for the partial reformation of the hydrocarbon-steam feed mixture.

Karafian, M.; Tsang, I.C.

1991-04-09T23:59:59.000Z

267

Closing the Gaps in the Budgets of Methane and Nitrous Oxide  

SciTech Connect (OSTI)

Together methane and nitrous oxide contribute almost 40% of the estimated increase in radiative forcing caused by the buildup of greenhouse gases during the last 250 years (IPCC, 2007). These increases are attributed to human activities. Since the emissions of these gases are from biogenic sources and closely associated with living things in the major terrestrial ecosystems of the world, climate change is expected to cause feedbacks that may further increase emissions even from systems normally classified as natural. Our results support the idea that while past increases of methane were driven by direct emissions from human activities, some of these have reached their limits and that the future of methane changes may be determined by feedbacks from warming temperatures. The greatly increased current focus on the arctic and the fate of the carbon frozen in its permafrost is an example of such a feedback that could exceed the direct increases caused by future human activities (Zimov et al. 2006). Our research was aimed at three broad areas to address open questions about the global budgets of methane and nitrous oxide. These areas of inquiry were: The processes by which methane and nitrous oxide are emitted, new sources such as trees and plants, and integration of results to refine the global budgets both at present and of the past decades. For the process studies the main research was to quantify the effect of changes in the ambient temperature on the emissions of methane and nitrous oxide from rice agriculture. Additionally, the emissions of methane and nitrous oxide under present conditions were estimated using the experimental data on how fertilizer applications and water management affect emissions. Rice was chosen for detailed study because it is a prototype system of the wider terrestrial source, its role in methane emissions is well established, it is easy to cultivate and it represents a major anthropogenic source. Here we will discuss the highlights of the results that were obtained.

Khalil, Aslam; Rice, Andrew; Rasmussen, Reinhold

2013-11-22T23:59:59.000Z

268

Solid oxide fuel cell steam reforming power system  

DOE Patents [OSTI]

The present invention is a Solid Oxide Fuel Cell Reforming Power System that utilizes adiabatic reforming of reformate within this system. By utilizing adiabatic reforming of reformate within the system the system operates at a significantly higher efficiency than other Solid Oxide Reforming Power Systems that exist in the prior art. This is because energy is not lost while materials are cooled and reheated, instead the device operates at a higher temperature. This allows efficiencies higher than 65%.

Chick, Lawrence A.; Sprenkle, Vincent L.; Powell, Michael R.; Meinhardt, Kerry D.; Whyatt, Greg A.

2013-03-12T23:59:59.000Z

269

Improve syngas production using autothermal reforming  

SciTech Connect (OSTI)

Synthesis gas or syngas, i.e., mixtures of CO and H[sub 2], is a major route from hydrocarbons to many important bulk chemicals ranging from acetic acid to ammonia. Syngas conversion uses hydrocarbon feedstocks, steam, O[sub 2] and CO[sub 2], either separately or in combinations. Autothermal reforming (ATR) is a low-investment process using a simple reactor design. The process is soot-free due to burner design and fixed-bed catalyst. Developed in the late '50s, ATR's main application was for ammonia and methanol syntheses. In ammonia plants, hydrogen production was maximized by operating at high H[sub 2]O/C ratios ranging from 2.5 to 3.5 mole/mole. In methanol units, CO[sub 2] recycle adjusted the syngas composition. ATR is also used to co-produce CO and H[sub 2] as separate streams at H[sub 2]O/C ratios of 1.4 to 2.0 mole/mole. recent developments and optimizations allow cost-effective operation at very low H[sub 2]O/C feed ratios to produce CO-rich syngas. The paper describes the process, including feedstocks and reactor design, the chemical reactions, development and improvements to the process, test results, soot formation, burner design, burner testing, applications, thermodynamic calculations, industrial application, noncatalytic and catalytic partial oxidation, and future uses.

Christensen, T.S.; Primdahl, I.I. (Haldor Topsoe, Copenhagen (Denmark))

1994-03-01T23:59:59.000Z

270

Extension - Upgrading Methane Using Ultra-Fast Thermal Swing Adsorption  

SciTech Connect (OSTI)

The need for cost effective technologies for upgrading coal mine methane to pipeline quality natural gas is becoming ever greater. The current work presents and investigates a new approach to reduce the impact of the most costly step in the conventional technology, nitrogen rejection. The proposed approach is based on the Velocys microchannel platform, which is being developed to commercialize compact and cost efficient chemical processing technology. For this separation, ultra fast thermal swing sorption is enabled by the very high rates of heat and mass transfer inherent in microchannel processing. In a first phase of the project solid adsorbents were explored. Feasibility of ultrafast thermal swing was demonstrated but the available adsorbents had insufficient differential methane capacity to achieve the required commercial economics. In a second phase, ionic liquids were adopted as absorbents of choice, and experimental work and economic analyses, performed to gauge their potential, showed promise for this novel alternative. Final conclusions suggest that a combination of a required cost target for ionic liquids or a methane capacity increase or a combination of both is required for commercialization.

Anna Lee Tonkovich

2008-08-11T23:59:59.000Z

271

DATA QUALITY OBJECTIVES FOR SELECTING WASTE SAMPLES FOR THE BENCH STEAM REFORMER TEST  

SciTech Connect (OSTI)

This document describes the data quality objectives to select archived samples located at the 222-S Laboratory for Fluid Bed Steam Reformer testing. The type, quantity and quality of the data required to select the samples for Fluid Bed Steam Reformer testing are discussed. In order to maximize the efficiency and minimize the time to treat Hanford tank waste in the Waste Treatment and Immobilization Plant, additional treatment processes may be required. One of the potential treatment processes is the fluid bed steam reformer (FBSR). A determination of the adequacy of the FBSR process to treat Hanford tank waste is required. The initial step in determining the adequacy of the FBSR process is to select archived waste samples from the 222-S Laboratory that will be used to test the FBSR process. Analyses of the selected samples will be required to confirm the samples meet the testing criteria.

BANNING DL

2010-08-03T23:59:59.000Z

272

Design, Modeling, and Validation of a Flame Reformer for LNT...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Design, Modeling, and Validation of a Flame Reformer for LNT External Bypass Regeneration Design, Modeling, and Validation of a Flame Reformer for LNT External Bypass Regeneration...

273

Regulatory and Financial Reform of Federal Research Policy: Recommenda...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

and Financial Reform of Federal Research Policy: Recommendations to the NRC Committee on Research Universities Regulatory and Financial Reform of Federal Research Policy:...

274

Secretary Moniz to Present Project Management Reforms to the...  

Energy Savers [EERE]

Moniz to Present Project Management Reforms to the National Academy of Public Administration Secretary Moniz to Present Project Management Reforms to the National Academy of Public...

275

Diesel Reforming for Fuel Cell Auxiliary Power Units  

SciTech Connect (OSTI)

This objective of this project was to develop technology suitable for onboard reforming of diesel. The approach was to examine catalytic partial oxidation and steam reforming.

Borup, R.; Parkinson, W. J.; Inbody, M.; Brosha, E.L.; Guidry, D.R.

2005-01-27T23:59:59.000Z

276

Hydrogen generation from plasmatron reformers and use for diesel...  

Broader source: Energy.gov (indexed) [DOE]

Hydrogen generation from plasmatron reformers and use for diesel exhaust aftertreatment Hydrogen generation from plasmatron reformers and use for diesel exhaust aftertreatment 2003...

277

Comparative Investigation of Benzene Steam Reforming over Spinel...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Investigation of Benzene Steam Reforming over Spinel Supported Rh and Ir Catalysts. Comparative Investigation of Benzene Steam Reforming over Spinel Supported Rh and Ir Catalysts....

278

HYDROGEN GENERATION FROM PLASMATRON REFORMERS: A PROMISING TECHNOLOGY FOR NOX ADSORBER REGENERATION AND OTHER AUTOMOTIVE APPLICATIONS  

SciTech Connect (OSTI)

Plasmatron reformers are being developed at MIT and ArvinMeritor [1]. In these reformers a special low power electrical discharge is used to promote partial oxidation conversion of hydrocarbon fuels into hydrogen and CO. The partial oxidation reaction of this very fuel rich mixture is difficult to initiate. The plasmatron provides continuous enhanced volume initiation. To minimize electrode erosion and electrical power requirements, a low current, high voltage discharge with wide area electrodes is used. The reformers operate at or slightly above atmospheric pressure. Plasmatron reformers provide the advantages of rapid startup and transient response; efficient conversion of the fuel to hydrogen rich gas; compact size; relaxation or elimination of reformer catalyst requirements; and capability to process difficult to reform fuels, such as diesel and bio-oils. These advantages facilitate use of onboard hydrogen-generation technology for diesel exhaust after-treatment. Plasma-enhanced reformer technology can provide substantial conversion even without the use of a catalyst. Recent progress includes a substantial decrease in electrical power consumption (to about 200 W), increased flow rate (above 1 g/s of diesel fuel corresponding to approximately 40 kW of chemical energy), soot suppression and improvements in other operational features.. Plasmatron reformer technology has been evaluated for regeneration of NOx adsorber after-treatment systems. At ArvinMeritor tests were performed on a dual-leg NOx adsorber system using a Cummins 8.3L diesel engine both in a test cell and on a vehicle. A NOx adsorber system was tested using the plasmatron reformer as a regenerator and without the reformer i.e., with straight diesel fuel based regeneration as the baseline case. The plasmatron reformer was shown to improve NOx regeneration significantly compared to the baseline diesel case. The net result of these initial tests was a significant decrease in fuel penalty, roughly 50% at moderate adsorber temperatures. This fuel penalty improvement is accompanied by a dramatic drop in slipped hydrocarbon emissions, which decreased by 90% or more. Significant advantages are demonstrated across a wide range of engine conditions and temperatures. The study also indicated the potential to regenerate NOx adsorbers at low temperatures where diesel fuel based regeneration is not effective, such as those typical of idle conditions. Two vehicles, a bus and a light duty truck, have been equipped for plasmatron reformer NOx adsorber regeneration tests.

Bromberg, L.; Crane, S; Rabinovich, A.; Kong, Y; Cohn, D; Heywood, J; Alexeev, N.; Samokhin, A.

2003-08-24T23:59:59.000Z

279

Enabling Informed Adaptation of Reformed Instructional Materials  

E-Print Network [OSTI]

Enabling Informed Adaptation of Reformed Instructional Materials Rachel E. Scherr and Andrew Elby 20742 USA Abstract. Instructors inevitably need to adapt even the best reform materials to suit instructors, and video clips of students working on the materials. Our materials thus facilitate their own

Elby, Andy

280

Fuel cell integrated with steam reformer  

DOE Patents [OSTI]

A H.sub.2 -air fuel cell integrated with a steam reformer is disclosed wherein a superheated water/methanol mixture is fed to a catalytic reformer to provide a continuous supply of hydrogen to the fuel cell, the gases exhausted from the anode of the fuel cell providing the thermal energy, via combustion, for superheating the water/methanol mixture.

Beshty, Bahjat S. (Lower Makefield, PA); Whelan, James A. (Bricktown, NJ)

1987-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "methane reforming process" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Reformate Cleanup: The Case for Microchannel Architecture  

E-Print Network [OSTI]

Reformate Cleanup: The Case for Microchannel Architecture DOE Hydrogen and Fuel Cells 2003 Annual for MicrochannelMicrochannel ArchitectureArchitecture DOE Hydrogen and Fuel CellsDOE Hydrogen and Fuel Cells 2003, controls Integrated reformer/fuel cell demonstration at ~2 kWeFY 2002 WGS/PROX catalyst studies

282

Methanol Steam Reformer on a Silicon Wafer  

SciTech Connect (OSTI)

A study of the reforming rates, heat transfer and flow through a methanol reforming catalytic microreactor fabricated on a silicon wafer are presented. Comparison of computed and measured conversion efficiencies are shown to be favorable. Concepts for insulating the reactor while maintaining small overall size and starting operation from ambient temperature are analyzed.

Park, H; Malen, J; Piggott, T; Morse, J; Sopchak, D; Greif, R; Grigoropoulos, C; Havstad, M; Upadhye, R

2004-04-15T23:59:59.000Z

283

Department of Energy Advance Methane Hydrates Science and Technology Projects  

Broader source: Energy.gov [DOE]

Descriptions for Energy Department Methane Hydrates Science and Technology Projects, August 31, 2012

284

MARINE BIOMASS SYSTEM: ANAEROBIC DIGESTION AND PRODUCTION OF METHANE  

E-Print Network [OSTI]

University, School of Engineering, Ocean .. Engineel'ing-and nutrition, ocean engineering and methane generation. In

Haven, Kendall F.

2011-01-01T23:59:59.000Z

285

RICH METHANE PREMIXED LAMINAR FLAMES DOPED BY LIGHT UNSATURATED HYDROCARBONS  

E-Print Network [OSTI]

RICH METHANE PREMIXED LAMINAR FLAMES DOPED BY LIGHT UNSATURATED HYDROCARBONS PART I: ALLENE Full-length article SHORTENED RUNNING TITLE : METHANE FLAMES DOPED BY ALLENE OR PROPYNE * E investigated: a pure methane flame and two methane flames doped by allene and propyne, respectively. The gases

Paris-Sud XI, Université de

286

Anaerobic Methane Oxidation in a Landfill-Leachate Plume  

E-Print Network [OSTI]

Anaerobic Methane Oxidation in a Landfill-Leachate Plume E T H A N L . G R O S S M A N , * , L U I, and methane, and (2) negligible oxygen, nitrate, and sulfate concentrations. Methane concentrations and stable carbon isotope (13C) values suggest anaerobic methane oxidation was occurring within the plume and at its

Grossman, Ethan L.

287

Contribution of oceanic gas hydrate dissociation to the formation of Arctic Ocean methane plumes  

SciTech Connect (OSTI)

Vast quantities of methane are trapped in oceanic hydrate deposits, and there is concern that a rise in the ocean temperature will induce dissociation of these hydrate accumulations, potentially releasing large amounts of carbon into the atmosphere. Because methane is a powerful greenhouse gas, such a release could have dramatic climatic consequences. The recent discovery of active methane gas venting along the landward limit of the gas hydrate stability zone (GHSZ) on the shallow continental slope (150 m - 400 m) west of Svalbard suggests that this process may already have begun, but the source of the methane has not yet been determined. This study performs 2-D simulations of hydrate dissociation in conditions representative of the Arctic Ocean margin to assess whether such hydrates could contribute to the observed gas release. The results show that shallow, low-saturation hydrate deposits, if subjected to recently observed or future predicted temperature changes at the seafloor, can release quantities of methane at the magnitudes similar to what has been observed, and that the releases will be localized near the landward limit of the GHSZ. Both gradual and rapid warming is simulated, along with a parametric sensitivity analysis, and localized gas release is observed for most of the cases. These results resemble the recently published observations and strongly suggest that hydrate dissociation and methane release as a result of climate change may be a real phenomenon, that it could occur on decadal timescales, and that it already may be occurring.

Reagan, M.; Moridis, G.; Elliott, S.; Maltrud, M.

2011-06-01T23:59:59.000Z

288

Artificial neural networks assisted catalyst design and optimisation of methane steam reforming.  

E-Print Network [OSTI]

??Hydrogen has diverse industrial applications namely in ammonia synthesis, petroleum refining and methanol production. The advent of fuel cell technology had prompted hydrogen as an… (more)

Arcotumapathy, Viswanathan

2013-01-01T23:59:59.000Z

289

Steam reforming of low-level mixed waste. Final report  

SciTech Connect (OSTI)

ThermoChem has successfully designed, fabricated and operated a nominal 90 pound per hour Process Development Unit (PDU) on various low-level mixed waste surrogates. The design, construction, and testing of the PDU as well as performance and economic projections for a 300-lb/hr demonstration and commercial system are described. The overall system offers an environmentally safe, non-incinerating, cost-effective, and publicly acceptable method of processing LLMW. The steam-reforming technology was ranked the No. 1 non-incineration technology for destruction of hazardous organic wastes in a study commissioned by the Mixed Waste Focus Area and published in April 1997. The ThermoChem steam-reforming system has been developed over the last 13 years culminating in this successful test campaign on LLMW surrogates. Six surrogates were successfully tested including a 750-hour test on material simulating a PCB- and Uranium-contaminated solid waste found at the Portsmouth Gaseous Diffusion Plant. The test results indicated essentially total (> 99.9999%) destruction of RCRA and TSCA hazardous halogenated organics, significant levels of volume reduction (> 400 to 1), and retention of radionuclides in the volume-reduced solids. Economic evaluations have shown the steam-reforming system to be very cost competitive with more conventional and other emerging technologies.

NONE

1998-06-01T23:59:59.000Z

290

Determination of Methane Concentration Methane will be measured on the gas chromatogram using a FID (flame ionization)  

E-Print Network [OSTI]

Determination of Methane Concentration Methane will be measured on the gas chromatogram using a FID to equilibrate the methane between the air and water. · With the syringe pointing down, eject all the water fromL of gas in the syringe · We will now move to the GC lab in Starr 332 to measure methane. · Repeat

Vallino, Joseph J.

291

Formation of Liquid Methane-Water Mixture during Combustion of a Laminar Methane Jet at Supercritical Pressures  

E-Print Network [OSTI]

Formation of Liquid Methane-Water Mixture during Combustion of a Laminar Methane Jet in laminar jet flames of methane at elevated pressures in a high-pressure combustion chamber, we have MPa, after the laminar methane jet flame had been stabilized on a co-flow circular nozzle-type burner

GĂŒlder, Ă?mer L.

292

The role of methane in tropospheric chemistry  

E-Print Network [OSTI]

While methane is chemically quite inert to reactions with atmospheric molecular species, it does react with atomic species and molecular radicals. Because of its relatively large abundance in the global troposphere and ...

Golomb, D.

1989-01-01T23:59:59.000Z

293

Virginia Coalbed Methane Proved Reserves Extensions (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Extensions (Billion Cubic Feet) Virginia Coalbed Methane Proved Reserves Extensions (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

294

Oklahoma Coalbed Methane Proved Reserves Extensions (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Extensions (Billion Cubic Feet) Oklahoma Coalbed Methane Proved Reserves Extensions (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

295

Pennsylvania Coalbed Methane Proved Reserves Revision Decreases...  

U.S. Energy Information Administration (EIA) Indexed Site

Decreases (Billion Cubic Feet) Pennsylvania Coalbed Methane Proved Reserves Revision Decreases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

296

Virginia Coalbed Methane Proved Reserves Adjustments (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Adjustments (Billion Cubic Feet) Virginia Coalbed Methane Proved Reserves Adjustments (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

297

Arkansas Coalbed Methane Proved Reserves Adjustments (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Adjustments (Billion Cubic Feet) Arkansas Coalbed Methane Proved Reserves Adjustments (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

298

Colorado Coalbed Methane Proved Reserves Revision Increases ...  

U.S. Energy Information Administration (EIA) Indexed Site

Increases (Billion Cubic Feet) Colorado Coalbed Methane Proved Reserves Revision Increases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

299

Pennsylvania Coalbed Methane Proved Reserves Revision Increases...  

U.S. Energy Information Administration (EIA) Indexed Site

Increases (Billion Cubic Feet) Pennsylvania Coalbed Methane Proved Reserves Revision Increases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

300

Virginia Coalbed Methane Proved Reserves Revision Decreases ...  

U.S. Energy Information Administration (EIA) Indexed Site

Decreases (Billion Cubic Feet) Virginia Coalbed Methane Proved Reserves Revision Decreases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

Note: This page contains sample records for the topic "methane reforming process" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Colorado Coalbed Methane Proved Reserves Extensions (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Extensions (Billion Cubic Feet) Colorado Coalbed Methane Proved Reserves Extensions (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

302

Oklahoma Coalbed Methane Proved Reserves Revision Decreases ...  

U.S. Energy Information Administration (EIA) Indexed Site

Decreases (Billion Cubic Feet) Oklahoma Coalbed Methane Proved Reserves Revision Decreases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

303

Montana Coalbed Methane Proved Reserves Adjustments (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Adjustments (Billion Cubic Feet) Montana Coalbed Methane Proved Reserves Adjustments (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

304

Wyoming Coalbed Methane Proved Reserves Acquisitions (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Acquisitions (Billion Cubic Feet) Wyoming Coalbed Methane Proved Reserves Acquisitions (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

305

Wyoming Coalbed Methane Proved Reserves Adjustments (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Adjustments (Billion Cubic Feet) Wyoming Coalbed Methane Proved Reserves Adjustments (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

306

Arkansas Coalbed Methane Proved Reserves Revision Increases ...  

U.S. Energy Information Administration (EIA) Indexed Site

Increases (Billion Cubic Feet) Arkansas Coalbed Methane Proved Reserves Revision Increases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

307

Oklahoma Coalbed Methane Proved Reserves Revision Increases ...  

U.S. Energy Information Administration (EIA) Indexed Site

Increases (Billion Cubic Feet) Oklahoma Coalbed Methane Proved Reserves Revision Increases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

308

Miscellaneous States Coalbed Methane Proved Reserves Adjustments...  

U.S. Energy Information Administration (EIA) Indexed Site

Adjustments (Billion Cubic Feet) Miscellaneous States Coalbed Methane Proved Reserves Adjustments (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6...

309

Oklahoma Coalbed Methane Proved Reserves Adjustments (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Adjustments (Billion Cubic Feet) Oklahoma Coalbed Methane Proved Reserves Adjustments (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

310

Pennsylvania Coalbed Methane Proved Reserves Extensions (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Extensions (Billion Cubic Feet) Pennsylvania Coalbed Methane Proved Reserves Extensions (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

311

Colorado Coalbed Methane Proved Reserves Adjustments (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Adjustments (Billion Cubic Feet) Colorado Coalbed Methane Proved Reserves Adjustments (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

312

Arkansas Coalbed Methane Proved Reserves Acquisitions (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Acquisitions (Billion Cubic Feet) Arkansas Coalbed Methane Proved Reserves Acquisitions (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

313

Colorado Coalbed Methane Proved Reserves Acquisitions (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Acquisitions (Billion Cubic Feet) Colorado Coalbed Methane Proved Reserves Acquisitions (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

314

Oklahoma Coalbed Methane Proved Reserves Acquisitions (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Acquisitions (Billion Cubic Feet) Oklahoma Coalbed Methane Proved Reserves Acquisitions (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

315

Colorado Coalbed Methane Proved Reserves Revision Decreases ...  

U.S. Energy Information Administration (EIA) Indexed Site

Decreases (Billion Cubic Feet) Colorado Coalbed Methane Proved Reserves Revision Decreases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

316

Arkansas Coalbed Methane Proved Reserves Revision Decreases ...  

U.S. Energy Information Administration (EIA) Indexed Site

Decreases (Billion Cubic Feet) Arkansas Coalbed Methane Proved Reserves Revision Decreases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

317

Virginia Coalbed Methane Proved Reserves Revision Increases ...  

U.S. Energy Information Administration (EIA) Indexed Site

Increases (Billion Cubic Feet) Virginia Coalbed Methane Proved Reserves Revision Increases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

318

Pennsylvania Coalbed Methane Proved Reserves Adjustments (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Adjustments (Billion Cubic Feet) Pennsylvania Coalbed Methane Proved Reserves Adjustments (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

319

Transient Supersonic Methane-Air Flames  

E-Print Network [OSTI]

The purpose of this study was to investigate the thermochemical properties of a transient supersonic flame. Creation of the transient flame was controlled by pulsing air in 200 millisecond intervals into a combustor filled with flowing methane...

Richards, John L.

2012-07-16T23:59:59.000Z

320

AN UPDATE ON REFORM IN EASTERN EUROPE AND RUSSIA  

E-Print Network [OSTI]

AN UPDATE ON REFORM IN EASTERN EUROPE AND RUSSIA Jeffrey Sachs ABSTRACT: The paper reviews the experience of Poland and Russia with economic reform, with occasional comparison to China's experience. The author argues that macroeconomic chaos in Poland and Russia preceded reform and was allayed by reform

Note: This page contains sample records for the topic "methane reforming process" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

September 25, 2013 AFSCME Continues to Object to Pension Reform;  

E-Print Network [OSTI]

September 25, 2013 AFSCME Continues to Object to Pension Reform; UC Implements Latest Bargaining working conditions and reasonable pension reform. However, AFSCME has rejected UC's proposals. From the start, AFSCME leadership has objected to UC's responsible pension reform -- the kind of reform that

Leistikow, Bruce N.

322

REFORM, LOBBIES AND WELFARE: A COMMON AGENCY APPROACH  

E-Print Network [OSTI]

REFORM, LOBBIES AND WELFARE: A COMMON AGENCY APPROACH Cecilia TESTA London School of Economics are a reform and a compensating taxation. The main feature of the reform is that it creates gainers and losers on tax parameters. keywords: reform, lobbying, redistribution, economic welfare. 1 #12;Introduction

Royal Holloway, University of London

323

Diesel Reforming for Solid Oxide Fuel Cell Application  

SciTech Connect (OSTI)

This presentation discusses the development of a diesel reforming catalyst and catalytic system development.

Liu, D-J.; Sheen, S-H.; Krumpelt, M.

2005-01-27T23:59:59.000Z

324

Electricity reform in developing and transition countries: A reappraisal  

E-Print Network [OSTI]

Electricity reform in developing and transition countries: A reappraisal J.H. Williams, R. Ghanadan-oriented reforms in their electric power sectors. Despite the widespread adoption of a standard policy model features of non-OECD electricity reform and reappraises reform policies and underlying assumptions

Kammen, Daniel M.

325

Development of water production type curves for horizontal wells in coalbed methane reservoirs.  

E-Print Network [OSTI]

??Coalbed methane is an unconventional gas resource that consists of methane production from the coal seams. The key parameters for the evaluation of coalbed methane… (more)

Burka Narayana, Praveen Kumar.

2007-01-01T23:59:59.000Z

326

Tool to predict the production performance of vertical wells in a coalbed methane reservoir.  

E-Print Network [OSTI]

??Coalbed Methane (CBM) is an unconventional gas resource that consists of methane production from coal seams. Coalbed Methane gas production is controlled be interactions of… (more)

Enoh, Michael E.

2007-01-01T23:59:59.000Z

327

Methane Digesters and Biogas Recovery - Masking the Environmental Consequences of Industrial Concentrated Livestock Production  

E-Print Network [OSTI]

Methane Digesters and Biogas Recovery-Masking theII. METHANE DIGESTERS AND BIOGAs RECOVERY- IN THEEVEN BEYOND MANURE-ASSOCIATED METHANE EMISSIONS, INDUSTRIAL

Di Camillo, Nicole G.

2011-01-01T23:59:59.000Z

328

Diffusional methane fluxes within continental margin sediments and depositional constraints on formation factor estimates  

E-Print Network [OSTI]

Goldberg, E.D. , 1976. Methane production and consumption inanaerobic oxidation of methane. Nature, 407 , 623-626.profiles indicate in situ methane flux from underlying gas

Berg, Richard D.

2008-01-01T23:59:59.000Z

329

Marine methane cycle simulations for the period of early global warming  

E-Print Network [OSTI]

aspects of atmospheric methane, Global Biogeochem. Cycles 2,Budeus, Fate of vent derived methane in seawater above theHanfland, Pathways of methane in seawater: Plume spreading

Elliott, S.

2011-01-01T23:59:59.000Z

330

Hydrogen Safety Issues Compared to Safety Issues with Methane and Propane  

E-Print Network [OSTI]

Issues with Methane and Propane Michael A. Green LawrenceSAFETY ISSUES WITH METHANE AND PROPANE M. A. Green Lawrencehydrogen. Methane and propane are commonly used by ordinary

Green, Michael A.

2005-01-01T23:59:59.000Z

331

Techno-Economic Analysis of Bioconversion of Methane into Biofuel and Biochemical (Poster)  

SciTech Connect (OSTI)

In light of the relatively low price of natural gas and increasing demands of liquid transportation fuels and high-value chemicals, attention has begun to turn to novel biocatalyst for conversion of methane (CH4) into biofuels and biochemicals [1]. A techno-economic analysis (TEA) was performed for an integrated biorefinery process using biological conversion of methane, such as carbon yield, process efficiency, productivity (both lipid and acid), natural gas and other raw material prices, etc. This analysis is aimed to identify research challenges as well provide guidance for technology development.

Fei, Q.; Tao, L.; Pienkos, P .T.; Guarnieri, M.; Palou-Rivera, I.

2014-10-01T23:59:59.000Z

332

Internal reforming fuel cell assembly with simplified fuel feed  

DOE Patents [OSTI]

A fuel cell assembly in which fuel cells adapted to internally reform fuel and fuel reformers for reforming fuel are arranged in a fuel cell stack. The fuel inlet ports of the fuel cells and the fuel inlet ports and reformed fuel outlet ports of the fuel reformers are arranged on one face of the fuel cell stack. A manifold sealing encloses this face of the stack and a reformer fuel delivery system is arranged entirely within the region between the manifold and the one face of the stack. The fuel reformer has a foil wrapping and a cover member forming with the foil wrapping an enclosed structure.

Farooque, Mohammad (Huntington, CT); Novacco, Lawrence J. (Brookfield, CT); Allen, Jeffrey P. (Naugatuck, CT)

2001-01-01T23:59:59.000Z

333

Slovakian refiner operating new hybrid hydrogen-production process  

SciTech Connect (OSTI)

Chemko s.p. has implemented Uhde GmbH's new combined autothermal reforming (CAR) process into an existing hydrogen plant at its refinery in Strazske, Slovakia. The new technology uses a combination of steam reforming and partial oxidation processes to produce synthesis gas or hydrogen for use in refinery or petrochemical processes. The paper describes the CAR process, process development, the reactor, convective reformer, partial oxidation, and the demonstration unit.

Babik, A. (Chemko s.p., Strazske (Slovakia)); Kurt, J. (Uhde GmbH, Dortmund (Germany))

1994-03-21T23:59:59.000Z

334

INTEGRATED POWER GENERATION SYSTEMS FOR COAL MINE WASTE METHANE UTILIZATION  

SciTech Connect (OSTI)

An integrated system to utilize the waste coal mine methane (CMM) at the Federal No. 2 Coal Mine in West Virginia was designed and built. The system includes power generation, using internal combustion engines, along with gas processing equipment to upgrade sub-quality waste methane to pipeline quality standards. The power generation has a nominal capacity of 1,200 kw and the gas processing system can treat about 1 million cubic feet per day (1 MMCFD) of gas. The gas processing is based on the Northwest Fuel Development, Inc. (NW Fuel) proprietary continuous pressure swing adsorption (CPSA) process that can remove nitrogen from CMM streams. The two major components of the integrated system are synergistic. The byproduct gas stream from the gas processing equipment can be used as fuel for the power generating equipment. In return, the power generating equipment provides the nominal power requirements of the gas processing equipment. This Phase III effort followed Phase I, which was comprised of a feasibility study for the project, and Phase II, where the final design for the commercial-scale demonstration was completed. The fact that NW Fuel is desirous of continuing to operate the equipment on a commercial basis provides the validation for having advanced the project through all of these phases. The limitation experienced by the project during Phase III was that the CMM available to operate the CPSA system on a commercial basis was not of sufficiently high quality. NW Fuel's CPSA process is limited in its applicability, requiring a relatively high quality of gas as the feed to the process. The CPSA process was demonstrated during Phase III for a limited time, during which the processing capabilities met the expected results, but the process was never capable of providing pipeline quality gas from the available low quality CMM. The NW Fuel CPSA process is a low-cost ''polishing unit'' capable of removing a few percent nitrogen. It was never intended to process CMM streams containing high levels of nitrogen, as is now the case at the Federal No.2 Mine. Even lacking the CPSA pipeline delivery demonstration, the project was successful in laying the groundwork for future commercial applications of the integrated system. This operation can still provide a guide for other coal mines which need options for utilization of their methane resources. The designed system can be used as a complete template, or individual components of the system can be segregated and utilized separately at other mines. The use of the CMM not only provides an energy fuel from an otherwise wasted resource, but it also yields an environmental benefit by reducing greenhouse gas emissions. The methane has twenty times the greenhouse effect as compared to carbon dioxide, which the combustion of the methane generates. The net greenhouse gas emission mitigation is substantial.

Peet M. Soot; Dale R. Jesse; Michael E. Smith

2005-08-01T23:59:59.000Z

335

Steam reforming utilizing iron oxide catalyst  

SciTech Connect (OSTI)

High activity steam reforming iron oxide catalysts are described. Such catalysts can be unsupported utilizing at least 90% by weight iron oxide and various modifiers (Ai/sub 2/O/sub 3/, K/sub 2/O, CaO, SiO/sub 2/) or unmodified and supported on such things as alumina, CaO impregnated alumina, and lanthanum stabilized alumina. When used in steam reformers such as autothermal and tubular steam reformers, these catalysts demonstrate much improved resistance to carbon plugging.

Setzer, H. T.; Bett, J. A. S.

1985-06-11T23:59:59.000Z

336

Life Cycle Assessment of Hydrogen Production via Natural Gas Steam Reforming  

SciTech Connect (OSTI)

A life cycle assessment of hydrogen production via natural gas steam reforming was performed to examine the net emissions of greenhouse gases as well as other major environmental consequences. LCA is a systematic analytical method that helps identify and evaluate the environmental impacts of a specific process or competing processes.

Spath, P. L.; Mann, M. K.

2000-09-28T23:59:59.000Z

337

Electrical Generation Tax Reform Act (Montana)  

Broader source: Energy.gov [DOE]

This Act reforms taxes paid by electricity generators to reduce tax rates and imposes replacement taxes in response to the 1997 restructuring of the Montana electric utility industry that allows...

338

Electricity reform abroad and US investment  

SciTech Connect (OSTI)

This report reviews and analyzes the recent electricity reforms in Argentina, Australia, and the United Kingdom (UK) to illustrate how different models of privatization and reform have worked in practice. This report also analyzes the motivations of the U.S. companies who have invested in the electricity industries in these countries, which have become the largest targets of U.S. foreign investment in electricity. Two calculations of foreign investment are used. One is the foreign direct investment series produced by the U.S. Department of Commerce. The other is based on transactions in electric utilities of the three countries. The electricity reform and privatization experiences reviewed may offer some insight as to how the U.S. electricity industry might develop as a result of recent domestic reform efforts and deregulation at the state and national levels. 126 refs., 23 figs., 27 tabs.

NONE

1997-10-01T23:59:59.000Z

339

Device for cooling and humidifying reformate  

DOE Patents [OSTI]

Devices for cooling and humidifying a reformate stream from a reforming reactor as well as related methods, modules and systems includes a heat exchanger and a sprayer. The heat exchanger has an inlet, an outlet, and a conduit between the inlet and the outlet. The heat exchanger is adapted to allow a flow of a first fluid (e.g. water) inside the conduit and to establish a heat exchange relationship between the first fluid and a second fluid (e.g. reformate from a reforming reactor) flowing outside the conduit. The sprayer is coupled to the outlet of the heat exchanger for spraying the first fluid exiting the heat exchanger into the second fluid.

Zhao, Jian Lian (Belmont, MA); Northrop, William F. (Ann Arbor, MI)

2008-04-08T23:59:59.000Z

340

E-Print Network 3.0 - assessing welfare reform Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

reventionscience.umn.edu Summary: , poverty, welfare reform, school reform, and health- care reform. An emphasis is given to large... , and dissemination of a variety of programs...

Note: This page contains sample records for the topic "methane reforming process" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

E-Print Network 3.0 - active methane weather Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Chemistry 48 Universitt Stuttgart Auslandsorientierter Studiengang Summary: Potential of Coalbed Methane Recovery during Active Coalmin- ing... Methane Recovery from Active...

342

Methane for Power Generation in Muaro Jambi: A Green Prosperity Model Project  

SciTech Connect (OSTI)

NREL conducted eight model projects for Millennium Challenge Corporation's (MCC) Compact with Indonesia. Green Prosperity, the largest project of the Compact, seeks to address critical constraints to economic growth while supporting the Government of Indonesia's commitment to a more sustainable, less carbon-intensive future. This study evaluates electricity generation from the organic content of wastewater at a palm oil mill in Muaro Jambi, Sumatra. Palm mills use vast amounts of water in the production process resulting in problematic waste water called palm oil mill effluent (POME). The POME releases methane to the atmosphere in open ponds which could be covered to capture the methane to produce renewable electricity for rural villages. The study uses average Indonesia data to determine the economic viability of methane capture at a palm oil mill and also evaluates technology as well as social and environmental impacts of the project.

Moriarty, K.; Elchinger, M.; Hill, G.; Katz, J.; Barnett, J.

2014-07-01T23:59:59.000Z

343

Numerical modeling of methane venting from lake sediments  

E-Print Network [OSTI]

The dynamics of methane transport in lake sediments control the release of methane into the water column above, and the portion that reaches the atmosphere may contribute significantly to the greenhouse effect. The observed ...

Scandella, Benjamin P. (Benjamin Paul)

2010-01-01T23:59:59.000Z

344

Conversion of methane and acetylene into gasoline range hydrocarbons  

E-Print Network [OSTI]

Conversion of methane and acetylene to higher molecular weight hydrocarbons over zeolite catalyst (HZSM-5) was studied The reaction between methane and acetylene successfully produced high molecular weight hydrocarbons, such as naphthalene, benzene...

Alkhawaldeh, Ammar

2000-01-01T23:59:59.000Z

345

Natural Gas Infrastructure R&D and Methane Emissions Mitigation...  

Broader source: Energy.gov (indexed) [DOE]

Natural Gas Infrastructure R&D and Methane Emissions Mitigation Workshop Natural Gas Infrastructure R&D and Methane Emissions Mitigation Workshop November 12, 2014 11:00AM EST to...

346

Methane Adsorption and Dissociation and Oxygen Adsorption and...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Methane Adsorption and Dissociation and Oxygen Adsorption and Reaction with CO on Pd Nanoparticles on MgO(100) and on Pd(111). Methane Adsorption and Dissociation and Oxygen...

347

Diurnal variations in methane emission from rice plants  

E-Print Network [OSTI]

A greenhouse study was conducted to investigate the mechanisms causing diurnal variations in methane emission from rice plants (Oryza sativa L.). Methane emission was measured using a closed chamber system on individual rice plants at five stages...

Laskowski, Nicholas Aaron

2004-11-15T23:59:59.000Z

348

New Methane Hydrate Research: Investing in Our Energy Future...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Investing in Our Energy Future August 31, 2012 - 1:37pm Addthis Methane hydrates are 3D ice-lattice structures with natural gas locked inside. If methane hydrate is either warmed...

349

Hydrogen generation utilizing integrated CO2 removal with steam reforming  

DOE Patents [OSTI]

A steam reformer may comprise fluid inlet and outlet connections and have a substantially cylindrical geometry divided into reforming segments and reforming compartments extending longitudinally within the reformer, each being in fluid communication. With the fluid inlets and outlets. Further, methods for generating hydrogen may comprise steam reformation and material adsorption in one operation followed by regeneration of adsorbers in another operation. Cathode off-gas from a fuel cell may be used to regenerate and sweep the adsorbers, and the operations may cycle among a plurality of adsorption enhanced reformers to provide a continuous flow of hydrogen.

Duraiswamy, Kandaswamy; Chellappa, Anand S

2013-07-23T23:59:59.000Z

350

Demonstration of a Highly Efficient Solid Oxide Fuel Cell Power System Using Adiabatic Steam Reforming and Anode Gas Recirculation  

SciTech Connect (OSTI)

Solid oxide fuel cells (SOFC) are currently being developed for a wide variety of applications because of their high efficiency at multiple power levels. Applications for SOFCs encompass a large range of power levels including 1-2 kW residential combined heat and power applications, 100-250 kW sized systems for distributed generation and grid extension, and MW-scale power plants utilizing coal. This paper reports on the development of a highly efficient, small-scale SOFC power system operating on methane. The system uses adiabatic steam reforming of methane and anode gas recirculation to achieve high net electrical efficiency. The anode exit gas is recirculated and all of the heat and water required for the endothermic reforming reaction are provided by the anode gas emerging from the SOFC stack. Although the single-pass fuel utilization is only about 55%, because of the anode gas recirculation the overall fuel utilization is up to 93%. The demonstrated system achieved gross power output of 1650 to 2150 watts with a maximum net LHV efficiency of 56.7% at 1720 watts. Overall system efficiency could be further improved to over 60% with use of properly sized blowers.

Powell, Michael R.; Meinhardt, Kerry D.; Sprenkle, Vincent L.; Chick, Lawrence A.; Mcvay, Gary L.

2012-05-01T23:59:59.000Z

351

Journal of Molecular Catalysis A: Chemical 163 (2000) 918 Methane activation on Ni and Ru model catalysts  

E-Print Network [OSTI]

process involves the reaction of methane with steam to form syngas (a mixture of CO Corresponding author). and hydrogen). Syngas is reacted to methanol which is then converted to gasoline via the methanol to gasoline (MTG) process [10,11]. The Fischer­Tropsch process can be directly utilized to convert syngas

Goodman, Wayne

352

SCREENING TESTS FOR IMPROVED METHANE CRACKING MATERIALS  

SciTech Connect (OSTI)

Bench scale (1 to 6 gram) methane cracking tests have been performed on a variety of pure elements, some alloys, and SAES{reg_sign} commercial getters St 101, St 198, St 707, St 737, and St 909 to determine methane cracking performance (MCP) of 5% methane in a helium carrier at 700 C, 101.3 kPa (760 torr) with a 10 sccm feed. The MCP was almost absent from some materials tested while others showed varying degrees of MCP. Re, Cr, V, Gd, and Mo powders had good MCP, but limited capacities. Nickel supported on kieselguhr (Ni/k), a Zr-Ni alloy, and the SAES{reg_sign} getters had good MCP in a helium carrier. The MCP of these same materials was suppressed in a hydrogen carrier stream and the MCP of the Zr-based materials was reduced by nitride formation when tested with a nitrogen carrier gas.

Klein, J; Jeffrey Holder, J

2007-07-16T23:59:59.000Z

353

Gravimetric study of adsorbed intermediates in methanation of carbon monoxide  

SciTech Connect (OSTI)

The purpose of this study is to more fully elucidate the adsorbed intermediates and mechanism involved in catalytic methanation of CO on a typical nickel methanation catalyst. Rates of adsorption and desorption of surface species and of gasification of carbon were measured gravimetrically to determine their kinetics and possible roles in methanation. 19 refs.

Gardner, D.C.; Bartholomew, C.H.

1981-08-01T23:59:59.000Z

354

Planetary and Space Science 54 (2006) 11771187 Titan's methane cycle  

E-Print Network [OSTI]

Abstract Methane is key to sustaining Titan's thick nitrogen atmosphere. However, methane is destroyed and the pressure induced opacity in the infrared, particularly by CH4­N2 and H2­N2 collisions in the troposphere), whose reaction with carbon grains or carbon dioxide in the crustal pores produces methane gas

Atreya, Sushil

355

Measurements of Methane Emissions at Natural Gas Production Sites  

E-Print Network [OSTI]

Measurements of Methane Emissions at Natural Gas Production Sites in the United States #12;Why = 21 #12;Need for Study · Estimates of methane emissions from natural gas production , from academic in assumptions in estimating emissions · Measured data for some sources of methane emissions during natural gas

Lightsey, Glenn

356

An improved third order dipole moment surface for methane  

E-Print Network [OSTI]

An improved third order dipole moment surface for methane P. Cassam-Chenaši Laboratoire J and used to calculate the rotational spectrum of methane vibrational ground state, by means. Keywords: Dipole moment surface; methane; generalized mean field configuration interaction. Suggested

Paris-Sud XI, Université de

357

Methane-assisted combustion synthesis of nanocomposite tin dioxide materials  

E-Print Network [OSTI]

Methane-assisted combustion synthesis of nanocomposite tin dioxide materials S.D. Bakrania *, C and flow conditions using methane as a supplemental fuel. The experiments were carried out at atmospheric-phase precursor for metal additives. In the methane-assisted (MA) system, the inert carrier gas was replaced

Wooldridge, Margaret S.

358

ESTIMATING METHANE EMISSION AND OXIDATION FROM TWO TEMPORARY  

E-Print Network [OSTI]

ESTIMATING METHANE EMISSION AND OXIDATION FROM TWO TEMPORARY COVERS ON LANDFILLED MBT TREATED WASTE to oxidize the methane flux coming from the residual organic fraction. The first plant was operated without recovery of organic fraction and with concentration of the fine fraction in a cell. The methane fluxes were

Paris-Sud XI, Université de

359

Methane Activation with Rhenium Catalysts. 1. Bidentate Oxygenated Ligands  

E-Print Network [OSTI]

Methane Activation with Rhenium Catalysts. 1. Bidentate Oxygenated Ligands Jason M. Gonzales, Jonas, California 90089 ReceiVed July 31, 2006 Trends in methane activation have been explored for rhenium complexes proceeds with methane activation through a barrier of less than 35 kcal mol-1 . Study

Goddard III, William A.

360

Extreme Methane Emissions from a Swiss Hydropower Reservoir  

E-Print Network [OSTI]

Extreme Methane Emissions from a Swiss Hydropower Reservoir: Contribution from Bubbling Sediments manuscript received February 3, 2010. Accepted February 15, 2010. Methane emission pathways.Methanediffusionfromthesediment was generally low and seasonally stable and did not account for the high concentration of dissolved methane

Wehrli, Bernhard

Note: This page contains sample records for the topic "methane reforming process" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Monterey Bay Aquarium Research A robotic sub samples the methane  

E-Print Network [OSTI]

Monterey Bay Aquarium Research Institute A robotic sub samples the methane content of the seafloor.263 News Seafloor probe taps methane reservoir Greenhouse gas found in high abundance but risk of mass release uncertain. Nicola Jones A robotic submarine has been used to measure the amount of methane lurking

Tian, Weidong

362

Carbon and Hydrogen Isotopic Effects in Microbial Methane  

E-Print Network [OSTI]

6 Carbon and Hydrogen Isotopic Effects in Microbial Methane from Terrestrial Environments Jeffrey Chanton, Lia Chaser, Paul Glasser,Don Siegel Methane is the ultimate end-product of anaerobic respiration. Methane production via CO2 reduction does not consume CO2. Also, acetate can be written as 2CH20, so Eq. 6

Saleska, Scott

363

RICH METHANE PREMIXED LAMINAR FLAMES DOPED BY LIGHT UNSATURATED HYDROCARBONS  

E-Print Network [OSTI]

RICH METHANE PREMIXED LAMINAR FLAMES DOPED BY LIGHT UNSATURATED HYDROCARBONS PART III: CYCLOPENTENE-length article SHORTENED RUNNING TITLE : METHANE FLAMES DOPED BY CYCLOPENTENE * E-mail : pierre with the studies presented in the parts I and II of this paper, the structure of a laminar rich premixed methane

Paris-Sud XI, Université de

364

Methane in lakes and wetlands Microbiological production, ecosystem  

E-Print Network [OSTI]

Methane in lakes and wetlands Microbiological production, ecosystem uptake, climatological significance LAKES AND WETLANDS ­ A RELEVANT METHANE SOURCE Lakes and other wetlands are an important source of methane, the third most important greenhouse gas in the atmosphere. However, the absolute contribution

MĂŒhlemann, Oliver

365

The Tri--methane Rearrangement: Mechanistic and Exploratory Organic  

E-Print Network [OSTI]

The Tri--methane Rearrangement: Mechanistic and Exploratory Organic Photochemistry1 Howard E zimmerman@bert.chem.wisc.edu Received May 31, 2000 ABSTRACT The di--methane rearrangement is firmly established as a mode of synthesizing three-membered-ring compounds. We now report the tri-- methane

Cirkva, Vladimir

366

METHANE SOURCES AND SINKS IN UPPER OCEAN WATERS  

E-Print Network [OSTI]

METHANE SOURCES AND SINKS IN UPPER OCEAN WATERS A DISSERTATION SUBMITTED TO THE GRADUATE DIVISION the distribution of dissolved methane in ocean surface waters were investigated. Water column and sediment trap and Antarctic waters to the oliogotrophic ocean off Hawaii. The methane concentrations in most of the surface

Luther, Douglas S.

367

Dissociation of methane under high pressure Guoying Gao,1,a  

E-Print Network [OSTI]

Dissociation of methane under high pressure Guoying Gao,1,a Artem R. Oganov,2,a Yanming Ma,1,b Hui Received 15 May 2010; accepted 18 August 2010; published online 12 October 2010 Methane is an extremely of methane under extreme conditions are of great fundamental interest. Using the ab initio evolutionary

Oganov, Artem R.

368

Tropical methane emissions: A revised view from SCIAMACHY onboard ENVISAT  

E-Print Network [OSTI]

Tropical methane emissions: A revised view from SCIAMACHY onboard ENVISAT Christian Frankenberg,1; accepted 26 June 2008; published 12 August 2008. [1] Methane retrievals from near-infrared spectra recorded spectroscopic parameters, causing a substantial overestimation of methane correlated with high water vapor

Haak, Hein

369

RICH METHANE PREMIXED LAMINAR FLAMES DOPED BY LIGHT UNSATURATED HYDROCARBONS  

E-Print Network [OSTI]

RICH METHANE PREMIXED LAMINAR FLAMES DOPED BY LIGHT UNSATURATED HYDROCARBONS PART II: 1,3-BUTADIENE-length article SHORTENED RUNNING TITLE : METHANE FLAMES DOPED BY 1,3-BUTADIENE * E-mail : Pierre of this paper, the structure of a laminar rich premixed methane flame doped with 1,3-butadiene has been

Paris-Sud XI, Université de

370

Introduction In the past two centuries, atmospheric methane  

E-Print Network [OSTI]

90 Introduction In the past two centuries, atmospheric methane (Ch4) concentrations have more than doubled. Despite the about 20o times smaller atmospheric burden of methane compared to carbon dioxide (CO2 ; IPCC 4th assessment report, 2007), because on a per molecule basis methane is a much more effective

Haak, Hein

371

Methane Production: In the United States cattle emit about 5.5 million metric tons of methane per year into the  

E-Print Network [OSTI]

Methane Production: In the United States cattle emit about 5.5 million metric tons of methane per year into the atmosphere. o Accounts for 20% of methane emissions from human sources. Globally cattle produce about 80 million metric tons of methane annually. o Accounts for 28% of global methane emissions

Toohey, Darin W.

372

New constraints on methane fluxes and rates of anaerobic methane oxidation in a Gulf of Mexico brine pool via in situ mass spectrometry  

E-Print Network [OSTI]

New constraints on methane fluxes and rates of anaerobic methane oxidation in a Gulf of Mexico Keywords: Methane flux Mass spectrometer Brine pool Methane oxidation Gulf of Mexico a b s t r a c t Deep heterogeneity. In particular, biogeochemical fluxes of volatiles such as methane remain largely unconstrained

Girguis, Peter R.

373

Low Cost Autothermal Diesel Reforming Catalyst Development  

SciTech Connect (OSTI)

Catalytic autothermal reforming (ATR) represents an important step of converting fossil fuel to hydrogen rich reformate for use in solid oxide fuel cell (SOFC) stacks. The state-of-the-art reforming catalyst, at present, is a Rh based material which is effective but costly. The objective of our current research is to reduce the catalyst cost by finding an efficient ATR catalyst containing no rhodium. A group of perovskite based catalysts have been synthesized and evaluated under the reforming condition of a diesel surrogate fuel. Hydrogen yield, reforming efficiency, and conversion selectivity to carbon oxides of the catalyst ATR reaction are calculated and compared with the benchmark Rh based material. Several catalyst synthesis improvements were carried out including: 1) selectively doping metals on the A-site and B-site of the perovskite structure, 2) changing the support from perovskite to alumina, 3) altering the method of metal addition, and 4) using transition metals instead of noble metals. It was found that the catalytic activity changed little with modification of the A-site metal, while it displayed considerable dependence on the B-site metal. Perovskite supports performed much better than alumina based supports.

Shihadeh, J.; Liu, D.

2004-01-01T23:59:59.000Z

374

A method for measuring methane oxidation rates using low levels of 14C-labeled methane and accelerator mass spectrometry  

E-Print Network [OSTI]

oxidation of methane above gas hydrates at Hydrate Ridge, NEsediment from a marine gas hydrate area. Environ. Microbiol.

2011-01-01T23:59:59.000Z

375

STEAM REFORMING TECHNOLOGY DEMONSTRATION FOR THE DESTRUCTION OF ORGANICS ON ACTUAL DOE SAVANNAH RIVER SITE TANK 48H WASTE 9138  

SciTech Connect (OSTI)

This paper describes the design of the Bench-scale Steam Reformer (BSR); a processing unit for demonstrating steam reforming technology on actual radioactive waste [1]. It describes the operating conditions of the unit used for processing a sample of Savannah River Site (SRS) Tank 48H waste. Finally, it compares the results from processing the actual waste in the BSR to processing simulant waste in the BSR to processing simulant waste in a large pilot scale unit, the Fluidized Bed Steam Reformer (FBSR), operated at Hazen Research Inc. in Golden, CO. The purpose of this work was to prove that the actual waste reacted in the same manner as the simulant waste in order to validate the work performed in the pilot scale unit which could only use simulant waste.

Burket, P

2009-02-24T23:59:59.000Z

376

Electricity reform in Chile : lessons for developing countries  

E-Print Network [OSTI]

Chile was the first country in the world to implement a comprehensive reform of its electricity sector in the recent period. Among developing countries only Argentina has had a comparably comprehensive and successful reform. ...

Pollitt, Michael G.

2004-01-01T23:59:59.000Z

377

The Effect of Welfare Reform on Childbirth, Marriage, and Divorce  

E-Print Network [OSTI]

This dissertation contains two essays on the effect of welfare reform on child- birth, marriage, and divorce. In the first essay, I exploit the cross state variation in welfare reform implementation to identify its effect on birth rates. The results...

Pakdeethai, Pimrak

2010-10-12T23:59:59.000Z

378

SECOND GENERATION REFORMS IN CHILE, POWER EXCHANGE MODEL. THE SOLUTION?  

E-Print Network [OSTI]

SECOND GENERATION REFORMS IN CHILE, POWER EXCHANGE MODEL. THE SOLUTION? David Watts Paulo Atienza to participate. Chile was the pioneer introducing this kind of reforms, through the application of a centralized

Catholic University of Chile (Universidad CatĂłlica de Chile)

379

How Did Health Care Reform in Massachusetts Impact Insurance Premiums?  

E-Print Network [OSTI]

It is widely recognized that the 2006 Massachusetts health reforms served as a blueprint for national reform under the 2010 Affordable Care Act (ACA). As such, there is interest in using the Massachusetts experience to ...

Graves, John A.

380

MORE HEALTH CARE REFORM By Victor R. Fuchs  

E-Print Network [OSTI]

MORE HEALTH CARE REFORM By Victor R. Fuchs #12;2 | MORE HEALTH CARE REFORM The Robert Wood Johnson?................................................................................... 8 Government Payment for Health Care -- Causes and Consequences....................................................................................................................................................................................... 16 Health Care Is Different -- That's Why Expenditures Matter

Zalta, Edward N.

Note: This page contains sample records for the topic "methane reforming process" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Pyrochlore catalysts for hydrocarbon fuel reforming  

DOE Patents [OSTI]

A method of catalytically reforming a reactant gas mixture using a pyrochlore catalyst material comprised of one or more pyrochlores having the composition A2B2-y-zB'yB"zO7-.DELTA., where y>0 and z.gtoreq.0. Distribution of catalytically active metals throughout the structure at the B site creates an active and well dispersed metal locked into place in the crystal structure. This greatly reduces the metal sintering that typically occurs on supported catalysts used in reforming reactions, and reduces deactivation by sulfur and carbon. Further, oxygen mobility may also be enhanced by elemental exchange of promoters at sites in the pyrochlore. The pyrochlore catalyst material may be utilized in catalytic reforming reactions for the conversion of hydrocarbon fuels into synthesis gas (H2+CO) for fuel cells, among other uses.

Berry, David A.; Shekhawat, Dushyant; Haynes, Daniel; Smith, Mark; Spivey, James J.

2012-08-14T23:59:59.000Z

382

Thermally integrated staged methanol reformer and method  

DOE Patents [OSTI]

A thermally integrated two-stage methanol reformer including a heat exchanger and first and second reactors colocated in a common housing in which a gaseous heat transfer medium circulates to carry heat from the heat exchanger into the reactors. The heat transfer medium comprises principally hydrogen, carbon dioxide, methanol vapor and water vapor formed in a first stage reforming reaction. A small portion of the circulating heat transfer medium is drawn off and reacted in a second stage reforming reaction which substantially completes the reaction of the methanol and water remaining in the drawn-off portion. Preferably, a PrOx reactor will be included in the housing upstream of the heat exchanger to supplement the heat provided by the heat exchanger.

Skala, Glenn William (Churchville, NY); Hart-Predmore, David James (Rochester, NY); Pettit, William Henry (Rochester, NY); Borup, Rodney Lynn (East Rochester, NY)

2001-01-01T23:59:59.000Z

383

Unconventional gas resources. [Eastern Gas Shales, Western Gas Sands, Coalbed Methane, Methane from Geopressured Systems  

SciTech Connect (OSTI)

This document describes the program goals, research activities, and the role of the Federal Government in a strategic plan to reduce the uncertainties surrounding the reserve potential of the unconventional gas resources, namely, the Eastern Gas Shales, the Western Gas Sands, Coalbed Methane, and methane from Geopressured Aquifers. The intent is to provide a concise overview of the program and to identify the technical activities that must be completed in the successful achievement of the objectives.

Komar, C.A. (ed.)

1980-01-01T23:59:59.000Z

384

CHARM COST-EFFECTIVE HIGH-EFFICIENCY ADVANCED REFORMING MODULE FINAL TECHNICAL REPORT  

SciTech Connect (OSTI)

Background Creation of a hydrogen infrastructure is an important prerequisite of widespread fuel cell commercialization, especially for the automotive market. Hydrogen is an attractive fuel since it offers an opportunity to replace petroleum-based fuels, but hydrogen occurs naturally only in chemical compounds like water or hydrocarbons that must be chemically converted to produce it. While an ultimate goal is to produce hydrogen through renewable energy sources, steam methane reforming (SMR) of natural gas is currently the most economical solution to initiate the transition to a hydrogen economy. Centralized hydrogen generation using large industrial SMR plants is already in place to serve customers. Yet, because of the weight and size of cylinders needed to contain hydrogen gas or liquid, transportation of hydrogen may only be economical for short distances. Consequently, distributed natural gas reforming, which trades off the economies of scale of large plants for simplified delivery logistics, is an attractive alternative that could address immediate problems with the lack of hydrogen infrastructure.

Pollica, Darryl; Cross, James C; Sharma, Atul; Shi, Yanlong; Clawson, Lawrence; O'Brien, Chris; Gilhooly, Kara; Kim, Changsik; Quet, Pierre-Francois; Bowers, Brian

2009-09-02T23:59:59.000Z

385

Hydroelectric Reservoirs -the Carbon Dioxide and Methane  

E-Print Network [OSTI]

Hydroelectric Reservoirs - the Carbon Dioxide and Methane Emissions of a "Carbon Free" Energy an overview on the greenhouse gas production of hydroelectric reservoirs. The goals are to point out the main how big the greenhouse gas emissions from hydroelectric reservoirs are compared to thermo-power plants

Fischlin, Andreas

386

High Temperature Solar Splitting of Methane  

E-Print Network [OSTI]

-term commercialization opportunities #12;Why Use Solar Energy?Why Use Solar Energy? · High concentrations possible (>1000High Temperature Solar Splitting of Methane to Hydrogen and Carbon High Temperature Solar Splitting and worldwide) ­ Sufficient to power the world (if we choose to) · Advantages tradeoff against collection area

387

Formation and retention of methane in coal  

SciTech Connect (OSTI)

The formation and retention of methane in coalbeds was studied for ten Utah coal samples, one Colorado coal sample and eight coal samples from the Argonne Premium Coal Sample Bank.Methane gas content of the Utah and Colorado coals varied from zero to 9 cm{sup 3}/g. The Utah coals were all high volatile bituminous coals. The Colorado coal was a gassy medium volatile bituminous coal. The Argonne coals cover a range or rank from lignite to low volatile bituminous coal and were used to determine the effect of rank in laboratory studies. The methane content of six selected Utah coal seams and the Colorado coal seam was measured in situ using a special sample collection device and a bubble desorbometer. Coal samples were collected at each measurement site for laboratory analysis. The cleat and joint system was evaluated for the coal and surrounding rocks and geological conditions were noted. Permeability measurements were performed on selected samples and all samples were analyzed for proximate and ultimate analysis, petrographic analysis, {sup 13}C NMR dipolar-dephasing spectroscopy, and density analysis. The observed methane adsorption behavior was correlated with the chemical structure and physical properties of the coals.

Hucka, V.J.; Bodily, D.M.; Huang, H.

1992-05-15T23:59:59.000Z

388

Generating power with drained coal mine methane  

SciTech Connect (OSTI)

The article describes the three technologies most commonly used for generating electricity from coal mine methane: internal combustion engines, gas turbines, and microturbines. The most critical characteristics and features of these technologies, such as efficiency, output and size are highlighted. 5 refs.

NONE

2005-09-01T23:59:59.000Z

389

Technical Note Methane gas migration through geomembranes  

E-Print Network [OSTI]

coefficient of PVC, LLDPE, and HDPE geomembranes by performing the standard gas transport test (ASTM D1434). The measured methane gas permeability coefficient through a PVC geomembrane is 7.55 3 104 ml(STP).mil/m2.day thicknesses is proposed using the measured permeability coefficients for PVC, LLDPE, and HDPE geomembranes

390

Enhancement of Biogenic Coalbed Methane Production and Back Injection of Coalbed Methane Co-Produced Water  

SciTech Connect (OSTI)

Biogenic methane is a common constituent in deep subsurface environments such as coalbeds and oil shale beds. Coalbed methane (CBM) makes significant contributions to world natural gas industry and CBM production continues to increase. With increasing CBM production, the production of CBM co-produced water increases, which is an environmental concern. This study investigated the feasibility in re-using CBM co-produced water and other high sodic/saline water to enhance biogenic methane production from coal and other unconventional sources, such as oil shale. Microcosms were established with the selected carbon sources which included coal, oil shale, lignite, peat, and diesel-contaminated soil. Each microcosm contained either CBM coproduced water or groundwater with various enhancement and inhibitor combinations. Results indicated that the addition of nutrients and nutrients with additional carbon can enhance biogenic methane production from coal and oil shale. Methane production from oil shale was much greater than that from coal, which is possibly due to the greater amount of available Dissolved Organic Carbon (DOC) from oil shale. Inconclusive results were observed from the other sources since the incubation period was too low. WRI is continuing studies with biogenic methane production from oil shale.

Song Jin

2007-05-31T23:59:59.000Z

391

Wellcome Trust CONSULTATION RESPONSE Ofqual: A level Reform Consultation  

E-Print Network [OSTI]

Wellcome Trust CONSULTATION RESPONSE Ofqual: A level Reform Consultation September 2012 1 Ofqual: A Level Reform Consultation Response by the Wellcome Trust September 2012 Key Points National Subject to university. We are therefore pleased to respond to this consultation on reforming A levels. Our comments

Rambaut, Andrew

392

health reform mattersTM alert ATTORNEY ADVERTISINGropesgray.com  

E-Print Network [OSTI]

health reform mattersTM alert ATTORNEY ADVERTISINGropesgray.com On March 23, President Obama signed is tracking the myriad other developments of the new health reform law. You can find a wide range of related material, including enacting language, implementing documents, and analysis through the Health Reform

Chapman, Michael S.

393

Preliminary and incomplete A Modest Proposal for International Monetary Reform  

E-Print Network [OSTI]

Preliminary and incomplete A Modest Proposal for International Monetary Reform International Columbia University #12;- 1 - - 1 - #12;- 2 - A Modest Proposal for International Monetary Reform Bruce are fundamental aspects of the present system and that, without reform, they will continue to plague the global

Grishok, Alla

394

SECTORAL EFFECTS OF TAX REFORMS IN AN OPEN ECONOMY  

E-Print Network [OSTI]

SECTORAL EFFECTS OF TAX REFORMS IN AN OPEN ECONOMY Olivier CARDI Romain RESTOUT December, 2010 REFORMS IN AN OPEN ECONOMY Olivier CARDI UniversitŽe PanthŽeon-Assas ERMES Ecole Polytechnique Romain with traded and non traded goods to in- vestigate the sectoral effects of three tax reforms: i) two revenue

Boyer, Edmond

395

WHEN DOES FINANCIAL SECTOR (IN)STABILITY INDUCE FINANCIAL REFORMS?  

E-Print Network [OSTI]

WHEN DOES FINANCIAL SECTOR (IN)STABILITY INDUCE FINANCIAL REFORMS? Susie LEE Ingmar SCHUMACHER (in)stability induce financial reforms? Susie Lee1 Ingmar Schumacher2 October 26, 2011 Abstract The article studies whether financial sector (in)stability had an effect on reforms in the fi- nancial sector

Boyer, Edmond

396

the triple aim MEETING THE GOAL OF HEALTH REFORM  

E-Print Network [OSTI]

the triple aim MEETING THE GOAL OF HEALTH REFORM Produced by OHSU Strategic Communications -- emphasizing shared decision-making and coordination between providers -- could influence reform in a big way care. health reform is about getting better health outcomes for our communities, improving access

Chapman, Michael S.

397

Supported metal catalysts for alcohol/sugar alcohol steam reforming  

SciTech Connect (OSTI)

Despite extensive studies on hydrogen production via steam reforming of alcohols and sugar alcohols, catalysts typically suffer a variety of issues from poor hydrogen selectivity to rapid deactivation. Here, we summarize recent advances in fundamental understanding of functionality and structure of catalysts for alcohol/sugar alcohol steam reforming, and provide perspectives on further development required to design highly efficient steam reforming catalysts.

Davidson, Stephen; Zhang, He; Sun, Junming; Wang, Yong

2014-08-21T23:59:59.000Z

398

Effect of carbon dioxide and nitrogen on the diffusivity of methane confined in nano-porous carbon aerogel  

SciTech Connect (OSTI)

The microscopic diffusivity of methane (CH{sub 4}) confined in nano-porous carbon aerogel was investigated as a function of added carbon dioxide (CO{sub 2}) and nitrogen (N{sub 2}) pressure using quasi-elastic neutron scattering (QENS). In the range of the external pressure of 1-2.5 MPa, the self-diffusivity of methane was found to increase with CO{sub 2} pressure and remain practically unchanged in the N{sub 2} environment. Increasing mobility of methane with CO{sub 2} pressure suggests that the adsorbed CH4 molecules become gradually replaced by CO{sub 2} on the surface of carbon aerogel pores, whereas the presence of N{sub 2} does not induce the replacement. The molecular mobility of the methane, with or without added carbon dioxide and nitrogen, is described by the unrestricted diffusion model, which is characteristic of methane compressed in small pores. On the other hand, both nitrogen and carbon dioxide molecules in carbon aerogel, when studied alone, with no methane present, follow a jump diffusion process, characteristic of the molecular mobility in the densified adsorbed layers on the surface of the aerogel pores.

Mavila Chathoth, Suresh [ORNL; He, Lilin [ORNL; Mamontov, Eugene [ORNL; Melnichenko, Yuri B [ORNL

2012-01-01T23:59:59.000Z

399

Deep oxidation of methane on particles derived from YSZ-supported Pd-Pt-(O) coatings synthesized by pulsed filtered cathodic arc  

E-Print Network [OSTI]

2009) Deep oxidation of methane on particles derived fromAbstract Methane conversion tests were performed on Pd, PdOFigure captions Figure 1: Methane conversion a), methane

Horwat, D.

2009-01-01T23:59:59.000Z

400

PBMR as an Ideal Heat Source for High-Temperature Process Heat Applications  

SciTech Connect (OSTI)

The Pebble Bed Modular Reactor (PBMR) is an advanced helium-cooled, graphite-moderated High Temperature Gas-cooled Reactor (HTGR). A 400 MWt PBMR Demonstration Power Plant (DPP) for the production of electricity is being developed in South Africa. This PBMR technology is also an ideal heat source for process heat applications, including Steam Methane Reforming, steam for Oil Sands bitumen recovery, Hydrogen Production and co-generation (process heat and/or electricity and/or process steam) for petrochemical industries. The cycle configuration used to transport the heat of the reactor to the process plant or to convert the reactor's heat into electricity or steam directly influences the cycle efficiency and plant economics. The choice of cycle configuration depends on the process requirements and is influenced by practical considerations, component and material limitations, maintenance, controllability, safety, performance, risk and cost. This paper provides an overview of the use of a PBMR reactor for process applications and possible cycle configurations are presented for applications which require high temperature process heat and/or electricity. (authors)

Correia, Michael; Greyvenstein, Renee [PBMR - Pty Ltd., 1279 Mike Crawford Avenue, Centurion, 0046 (South Africa); Silady, Fred; Penfield, Scott [Technology Insights, 6540 Lusk Blvd, Suite C-102, San Diego, California 92121 (United States)

2006-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "methane reforming process" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Reduction of Non-CO2 Gas Emissions Through The In Situ Bioconversion of Methane  

SciTech Connect (OSTI)

The primary objectives of this research were to seek previously unidentified anaerobic methanotrophs and other microorganisms to be collected from methane seeps associated with coal outcrops. Subsurface application of these microbes into anaerobic environments has the potential to reduce methane seepage along coal outcrop belts and in coal mines, thereby preventing hazardous explosions. Depending upon the types and characteristics of the methanotrophs identified, it may be possible to apply the microbes to other sources of methane emissions, which include landfills, rice cultivation, and industrial sources where methane can accumulate under buildings. Finally, the microbes collected and identified during this research also had the potential for useful applications in the chemical industry, as well as in a variety of microbial processes. Sample collection focused on the South Fork of Texas Creek located approximately 15 miles east of Durango, Colorado. The creek is located near the subsurface contact between the coal-bearing Fruitland Formation and the underlying Pictured Cliffs Sandstone. The methane seeps occur within the creek and in areas adjacent to the creek where faulting may allow fluids and gases to migrate to the surface. These seeps appear to have been there prior to coalbed methane development as extensive microbial soils have developed. Our investigations screened more than 500 enrichments but were unable to convince us that anaerobic methane oxidation (AMO) was occurring and that anaerobic methanotrophs may not have been present in the samples collected. In all cases, visual and microscopic observations noted that the early stage enrichments contained viable microbial cells. However, as the levels of the readily substrates that were present in the environmental samples were progressively lowered through serial transfers, the numbers of cells in the enrichments sharply dropped and were eliminated. While the results were disappointing we acknowledge that anaerobic methane oxidizing (AOM) microorganisms are predominantly found in marine habitats and grow poorly under most laboratory conditions. One path for future research would be to use a small rotary rig to collect samples from deeper soil horizons, possibly adjacent to the coal-bearing horizons that may be more anaerobic.

Scott, A R; Mukhopadhyay, B; Balin, D F

2012-09-06T23:59:59.000Z

402

In Njeri Wamukonya, ed., Electricity Reform  

E-Print Network [OSTI]

electricity consumption in industrial countries has caused major air pollution problems. In fact, power plants maintain that governing the electricity industry according to market dynamics, rather than socioIn Njeri Wamukonya, ed., Electricity Reform: Social and Environmental Challenges Roskilde, Denmark

Delaware, University of

403

Affordable Care Act & Medicaid Reform in Wisconsin  

E-Print Network [OSTI]

Affordable Care Act & Medicaid Reform in Wisconsin Enrollment Trends Chartpack 2013-2014 ACA Open,731 Wisconsinites Living in Poverty Access Health Care Through Medicaid," Press Release, May 19, 2014. http://walker.wi.gov/newsroom/press-release/81731-wisconsinites-living-poverty-access-health-care-through- Medicaid Medicaid & CHIP: April 2014

Sheridan, Jennifer

404

Patent Reform: Aligning Reward and Contribution  

E-Print Network [OSTI]

4 Patent Reform: Aligning Reward and Contribution Carl Shapiro, University of California the current U.S. patent system allows patent holders to capture private rewards that exceed their social with the patent system and discourage in- novation by others. Economic efficiency is promoted if rewards to patent

Sadoulet, Elisabeth

405

SMALL SCALE FUEL CELL AND REFORMER SYSTEMS FOR REMOTE POWER  

SciTech Connect (OSTI)

New developments in fuel cell technologies offer the promise of clean, reliable affordable power, resulting in reduced environmental impacts and reduced dependence on foreign oil. These developments are of particular interest to the people of Alaska, where many residents live in remote villages, with no roads or electrical grids and a very high cost of energy, where small residential power systems could replace diesel generators. Fuel cells require hydrogen for efficient electrical production, however. Hydrogen purchased through conventional compressed gas suppliers is very expensive and not a viable option for use in remote villages, so hydrogen production is a critical piece of making fuel cells work in these areas. While some have proposed generating hydrogen from renewable resources such as wind, this does not appear to be an economically viable alternative at this time. Hydrogen can also be produced from hydrocarbon feed stocks, in a process known as reforming. This program is interested in testing and evaluating currently available reformers using transportable fuels: methanol, propane, gasoline, and diesel fuels. Of these, diesel fuels are of most interest, since the existing energy infrastructure of rural Alaska is based primarily on diesel fuels, but this is also the most difficult fuel to reform, due to the propensity for coke formation, due to both the high vaporization temperature and to the high sulfur content in these fuels. There are several competing fuel cell technologies being developed in industry today. Prior work at UAF focused on the use of PEM fuel cells and diesel reformers, with significant barriers identified to their use for power in remote areas, including stack lifetime, system efficiency, and cost. Solid Oxide Fuel Cells have demonstrated better stack lifetime and efficiency in demonstrations elsewhere (though cost still remains an issue), and procuring a system for testing was pursued. The primary function of UAF in the fuel cell industry is in the role of third party independent testing. In order for tests to be conducted, hardware must be purchased and delivered. The fuel cell industry is still in a pre-commercial state, however. Commercial products are defined as having a fixed set of specifications, fixed price, fixed delivery date, and a warrantee. Negotiations with fuel cell companies over these issues are often complex, and the results of these discussions often reveal much about the state of development of the technology. This work includes some of the results of these procurement experiments. Fuel cells may one day replace heat engines as the source of electrical power in remote areas. However, the results of this program to date indicate that currently available hardware is not developed sufficiently for these environments, and that significant time and resources will need to be committed for this to occur.

Dennis Witmer

2003-12-01T23:59:59.000Z

406

Microsoft Word - TEV-961 Rev 0.docx  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Evaluation Study Project No. 23843 Sensitivity of Hydrogen Production via Steam Methane Reforming to High Temperature Gas-Cooled Reactor Outlet Temperature Process Analysis...

407

iccs-air | netl.doe.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Air Products and Chemicals, Inc.: Demonstration of CO2 Capture and Sequestration of Steam Methane Reforming Process Gas Used for Large-Scale Hydrogen Production Allentown,...

408

Hydrocarbon reforming catalyst material and configuration of the same  

DOE Patents [OSTI]

A hydrocarbon reforming catalyst material comprising a catalyst support impregnated with catalyst is provided for reforming hydrocarbon fuel gases in an electrochemical generator. Elongated electrochemical cells convert the fuel to electrical power in the presence of an oxidant, after which the spent fuel is recirculated and combined with a fresh hydrocarbon feed fuel forming the reformable gas mixture which is fed to a reforming chamber containing a reforming catalyst material, where the reforming catalyst material includes discrete passageways integrally formed along the length of the catalyst support in the direction of reformable gas flow. The spent fuel and/or combusted exhaust gases discharged from the generator chamber transfer heat to the catalyst support, which in turn transfers heat to the reformable gas and to the catalyst, preferably via a number of discrete passageways disposed adjacent one another in the reforming catalyst support. The passageways can be slots extending inwardly from an outer surface of the support body, which slots are partly defined by an exterior confining wall. According to a preferred embodiment, the catalyst support is non-rigid, porous, fibrous alumina, wherein the fibers are substantially unsintered and compressible, and the reforming catalyst support is impregnated, at least in the discrete passageways with Ni and MgO, and has a number of internal slot passageways for reformable gas, the slot passageways being partly closed by a containing outer wall.

Singh, Prabhakar (Export, PA); Shockling, Larry A. (Plum Borough, PA); George, Raymond A. (Pittsburgh, PA); Basel, Richard A. (Plub Borough, PA)

1996-01-01T23:59:59.000Z

409

Hydrocarbon reforming catalyst material and configuration of the same  

DOE Patents [OSTI]

A hydrocarbon reforming catalyst material comprising a catalyst support impregnated with catalyst is provided for reforming hydrocarbon fuel gases in an electrochemical generator. Elongated electrochemical cells convert the fuel to electrical power in the presence of an oxidant, after which the spent fuel is recirculated and combined with a fresh hydrocarbon feed fuel forming the reformable gas mixture which is fed to a reforming chamber containing a reforming catalyst material, where the reforming catalyst material includes discrete passageways integrally formed along the length of the catalyst support in the direction of reformable gas flow. The spent fuel and/or combusted exhaust gases discharged from the generator chamber transfer heat to the catalyst support, which in turn transfers heat to the reformable gas and to the catalyst, preferably via a number of discrete passageways disposed adjacent one another in the reforming catalyst support. The passageways can be slots extending inwardly from an outer surface of the support body, which slots are partly defined by an exterior confining wall. According to a preferred embodiment, the catalyst support is non-rigid, porous, fibrous alumina, wherein the fibers are substantially unsintered and compressible, and the reforming catalyst support is impregnated, at least in the discrete passageways with Ni and MgO, and has a number of internal slot passageways for reformable gas, the slot passageways being partly closed by a containing outer wall. 5 figs.

Singh, P.; Shockling, L.A.; George, R.A.; Basel, R.A.

1996-06-18T23:59:59.000Z

410

Application of the Kellogg reforming exchanger system to large scale methanol plants  

SciTech Connect (OSTI)

In a majority of existing methanol production facilities, synthesis gas is furnished typically by a tubular fired steam reformer which uses natural gas as a feedstock. When one considers all synthesis gas produced from both ammonia and methanol plants, well over 80% is produced in a conventional reforming furnace. Steam reforming in a conventional sense, however, requires a considerable investment in both capital equipment and on-going maintenance and further, the use of such a unit operation will require heat recovery in the form of steam which forces the hand of the designer with respect to machinery driver selection. The authors have investigated alternatives to the coinventional approach with a view towards developing a process for methanol production that would be hopefully less expensive to construct, easier to operate and more reliable over the course of long term operation. In this paper, the authors present an alternative methanol plant process based on Kellogg`s proprietary reforming exchanger system (KRES). The flowsheet presented herein is for a 1500 MTPD facility that will produce US Federal Grade AA + methanol and will be compared on an economic basis to a conventional plant with respect to investment requirements and expected energy efficiency.

Joshi, G.; Schneider, R.V. III [M.W. Kellogg Co., Houston, TX (United States)

1995-12-31T23:59:59.000Z

411

Experimental and Numerical Observations of Hydrate Reformation during Depressurization in a Core-Scale Reactor  

SciTech Connect (OSTI)

Gas hydrate has been predicted to reform around a wellbore during depressurization-based gas production from gas hydrate-bearing reservoirs. This process has an adverse effect on gas production rates and it requires time and sometimes special measures to resume gas flow to producing wells. Due to lack of applicable field data, laboratory scale experiments remain a valuable source of information to study hydrate reformation. In this work, we report laboratory experiments and complementary numerical simulations executed to investigate the hydrate reformation phenomenon. Gas production from a pressure vessel filled with hydrate-bearing sand was induced by depressurization with and without heat flux through the boundaries. Hydrate decomposition was monitored with a medical X-ray CT scanner and pressure and temperature measurements. CT images of the hydrate-bearing sample were processed to provide 3-dimensional data of heterogeneous porosity and phase saturations suitable for numerical simulations. In the experiments, gas hydrate reformation was observed only in the case of no-heat supply from surroundings, a finding consistent with numerical simulation. By allowing gas production on either side of the core, numerical simulations showed that initial hydrate distribution patterns affect gas distribution and flow inside the sample. This is a direct consequence of the heterogeneous pore network resulting in varying hydraulic properties of the hydrate-bearing sediment.

Seol, Yongkoo; Myshakin, Evgeniy

2011-01-01T23:59:59.000Z

412

Fiftieth CCR reformer goes on stream in Germany  

SciTech Connect (OSTI)

The fiftieth continuous catalytic reformer built since this technology was introduced by UOP Process Division in 1971 has gone on stream in West Germany. The 21,300-b/sd unit is in Deutsche Shell AG's Godorf refinery. It is the sixth such unit put in service by Shell International. Others are in refineries at Harburg, West Germany; Shellhaven, England; Palau Bokum, Singapore; Pernis, Netherlands; and Geelong, Australia. CCR units operate at much higher severity than older reforming units. Severity is a function of higher octane, lower pressure, and feedstock. The operating severity or catalyst deactivation rate may be 20 times that of high pressure, low octane units. Continuous catalyst regeneration is then the key for maintaining long-term operations at steady state conditions. To facilitate continuous catalyst regeneration, the three reactors are stacked. This design permits the catalyst to move in essentially plug flow through the reactors at a rate determined by the rate of catalyst withdrawal to the regeneration section.

Not Available

1985-03-18T23:59:59.000Z

413

RESEARCH ARTICLE -BASED ON MIR INVESTIGATIONS IN LAKE GENEVA Spatial heterogeneity of benthic methane dynamics  

E-Print Network [OSTI]

methane dynamics in the subaquatic canyons of the Rhone River Delta (Lake Geneva) S. Sollberger · J. P methane (CH4) dynam- ics from river deltas with important organic matter accumulation have been recently Methane emission Á Methane production Introduction Atmospheric methane (CH4) concentration has dramati

Wehrli, Bernhard

414

RESEARCH ARTICLE -BASED ON MIR INVESTIGATIONS IN LAKE GENEVA Spatial heterogeneity of benthic methane dynamics  

E-Print Network [OSTI]

methane dynamics in the subaquatic canyons of the Rhone River Delta (Lake Geneva) S. Sollberger · J. P Abstract Heterogeneous benthic methane (CH4) dynam- ics from river deltas with important organic matter Particle size Á Methane emission Á Methane production Introduction Atmospheric methane (CH4) concentration

Wehrli, Bernhard

415

METHANE AND ETHANE ON THE BRIGHT KUIPER BELT OBJECT 2005 FY9 M. E. Brown,1  

E-Print Network [OSTI]

METHANE AND ETHANE ON THE BRIGHT KUIPER BELT OBJECT 2005 FY9 M. E. Brown,1 K. M. Barkume,1 G. A regime and by absorption due to methane in the near-infrared. The solid methane absorption lines through the methane. These long path lengths can be parameterized as a methane grain size of approximately

Brown, Michael E.

416

Methane Hydrate Field Studies | Department of Energy  

Energy Savers [EERE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |EnergyonSupport0.pdf5 OPAM SEMIANNUAL REPORTMAMay 20Field Studies Methane Hydrate Field

417

Methane Hydrate Production Feasibility | Department of Energy  

Energy Savers [EERE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |EnergyonSupport0.pdf5 OPAM SEMIANNUAL REPORTMAMay 20Field Studies Methane Hydrate

418

Methane activation on ruthenium: the nature of the surface intermediates T.V. Choudhary and D.W. Goodman*  

E-Print Network [OSTI]

) by steam reforming [1,2], partial oxidation [3,4], autothermal reforming [2,5] or CO2 reforming [6

Goodman, Wayne

419

Evaluation of Phytoremediation of Coal Bed Methane Product Water and Waters of Quality Similar to that Associated with Coal Bed Methane Reserves of the Powder River Basin, Montana and Wyoming  

SciTech Connect (OSTI)

U.S. emphasis on domestic energy independence, along with advances in knowledge of vast biogenically sourced coalbed methane reserves at relatively shallow sub-surface depths with the Powder River Basin, has resulted in rapid expansion of the coalbed methane industry in Wyoming and Montana. Techniques have recently been developed which constitute relatively efficient drilling and methane gas recovery and extraction techniques. However, this relatively efficient recovery requires aggressive reduction of hydrostatic pressure within water-saturated coal formations where the methane is trapped. Water removed from the coal formation during pumping is typically moderately saline and sodium-bicarbonate rich, and managed as an industrial waste product. Current approaches to coalbed methane product water management include: surface spreading on rangeland landscapes, managed irrigation of agricultural crop lands, direct discharge to ephermeral channels, permitted discharge of treated and untreated water to perennial streams, evaporation, subsurface injection at either shallow or deep depths. A Department of Energy-National Energy Technology Laboratory funded research award involved the investigation and assessment of: (1) phytoremediation as a water management technique for waste water produced in association with coalbed methane gas extraction; (2) feasibility of commercial-scale, low-impact industrial water treatment technologies for the reduction of salinity and sodicity in coalbed methane gas extraction by-product water; and (3) interactions of coalbed methane extraction by-product water with landscapes, vegetation, and water resources of the Powder River Basin. Prospective, greenhouse studies of salt tolerance and water use potential of indigenous, riparian vegetation species in saline-sodic environments confirmed the hypothesis that species such as Prairie cordgrass, Baltic rush, American bulrush, and Nuttall's alkaligrass will thrive in saline-sodic environments when water supplies sourced from coalbed methane extraction are plentiful. Constructed wetlands, planted to native, salt tolerant species demonstrated potential to utilize substantial volumes of coalbed methane product water, although plant community transitions to mono-culture and limited diversity communities is a likely consequence over time. Additionally, selected, cultured forage quality barley varieties and native plant species such as Quail bush, 4-wing saltbush, and seaside barley are capable of sustainable, high quality livestock forage production, when irrigated with coalbed methane product water sourced from the Powder River Basin. A consequence of long-term plant water use which was enumerated is elevated salinity and sodicity concentrations within soil and shallow alluvial groundwater into which coalbed methane product water might drain. The most significant conclusion of these investigations was the understanding that phytoremediation is not a viable, effective technique for management of coalbed methane product water under the present circumstances of produced water within the Powder River Basin. Phytoremediation is likely an effective approach to sodium and salt removal from salt-impaired sites after product water discharges are discontinued and site reclamation is desired. Coalbed methane product water of the Powder River Basin is most frequently impaired with respect to beneficial use quality by elevated sodicity, a water quality constituent which can cause swelling, slaking, and dispersion of smectite-dominated clay soils, such as commonly occurring within the Powder River Basin. To address this issue, a commercial-scale fluid-bed, cationic resin exchange treatment process and prototype operating treatment plant was developed and beta-tested by Drake Water Technologies under subcontract to this award. Drake Water Technologies secured U.S. Patent No. 7,368,059-B2, 'Method for removal of benevolent cations from contaminated water', a beta Drake Process Unit (DPU) was developed and deployed for operation in the Powder River Basin. First year operatio

James Bauder

2008-09-30T23:59:59.000Z

420

Carbon dioxide adsorption and methanation on ruthenium  

SciTech Connect (OSTI)

The adsorption and methanation of carbon dioxide on a ruthenium-silica catalyst were studied using temperature-programmed desorption (TPD) and temperature-programmed reaction (TPR). Carbon dioxide adsorption was found to be activated; CO/sub 2/ adsorption increased significantly as the temperature increased from 298 to 435 K. During adsorption, some of the CO/sub 2/ dissociated to carbon monoxide and oxygen; upon hydrogen exposure at room temperature, the oxygen reacted to water. Methanation of adsorbed CO and of adsorbed CO/sub 2/, using TPR in flowing hydrogen, yielded a CH/sub 4/ peak with a peak temperature of 459 K for both adsorbates, indicating that both reactions follow the same mechanism after adsorption. This peak temperature did not change with initial surface coverage of CO, indicating that methanation is first order in CO coverage. The desorption and reaction spectra for Ru/SiO/sub 2/ were similar to those previously obtained for Ni/SiO/sub 2/, but both CO/sub 2/ formation and CH/sub 4/ formation proceeded faster on Ru. Also, the details of CO desorption and the changes in CO/sub 2/ and CO desorptions with initial coverage were different on the two metals. 5 figures, 3 tables.

Zagli, E.; Falconer, J.L.

1981-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "methane reforming process" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Study of parameters affecting enhanced coal bed methane  

SciTech Connect (OSTI)

Laboratory and field scale trials conducted so far indicate that injection of CO{sub 2} and N{sub 2} into deep coalbeds has the potential to enhance coalbed methane (ECBM) recovery while simultaneously sequestering CO{sub 2}. The work has identified that the fundamental processes involved in CO{sub 2} sequestration/CBM recovery in deep coalbeds are not fully understood and further research is needed to advance this technology. ECBM is affected by several parameters; prominent among them are coal characteristics, in-situ conditions prevailing in deep coalbeds, and changes arising from the interaction of coal with various fluids. These parameters do not act independently, thereby making it difficult to isolate their impacts separately. An attempt has been made in this article to classify these parameters and understand their role in ECBM. Past work in this area is reviewed and the future work that is critical for an improved understanding of ECBM recovery is discussed.

Katyal, S.; Valix, M.; Thambimuthu, K. [University of Sydney, Sydney, NSW (Australia). Dept. of Chemical Engineering

2007-02-15T23:59:59.000Z

422

Coalbed-methane pilots - timing, design, and analysis  

SciTech Connect (OSTI)

Four distinct sequential phases form a recommended process for coalbed-methane (CBM)-prospect assessment: initial screening reconnaissance, pilot testing, and final appraisal. Stepping through these four phases provides a program of progressively ramping work and cost, while creating a series of discrete decision points at which analysis of results and risks can be assessed. While discussing each of these phases in some degree, this paper focuses on the third, the critically important pilot-testing phase. This paper contains roughly 30 specific recommendations and the fundamental rationale behind each recommendation to help ensure that a CBM pilot will fulfill its primary objectives of (1) demonstrating whether the subject coal reservoir will desorb and produce consequential gas and (2) gathering the data critical to evaluate and risk the prospect at the next-often most critical-decision point.

Roadifer, R.D.; Moore, T.R.

2009-10-15T23:59:59.000Z

423

Energy Department Expands Research into Methane Hydrates, a Vast...  

Broader source: Energy.gov (indexed) [DOE]

separate project funded by the EU through Universities of Bremen (Germany) and Tromso (Norway), will assess the response of methane hydrates to environmental changes at the...

424

Biomass Gasification and Methane Digester Property Tax Exemption  

Broader source: Energy.gov [DOE]

Michigan exempts certain energy production related farm facilities from real and personal property taxes. Among exempted property are certain methane digesters, biomass gasification equipment,...

425

,"North Louisiana Coalbed Methane Proved Reserves, Reserves Changes...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves, Reserves Changes, and Production" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Late...

426

,"Ohio Coalbed Methane Proved Reserves, Reserves Changes, and...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Ohio Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2010,"630...

427

,"U.S. Coalbed Methane Proved Reserves Extensions (Billion Cubic...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Coalbed Methane Proved Reserves Extensions (Billion Cubic Feet)",1,"Annual",2013 ,"Release...

428

Ohio Coalbed Methane Proved Reserves Revision Increases (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

W Withheld to avoid disclosure of individual company data. Release Date: 1242014 Next Release Date: 12312015 Referring Pages: Coalbed Methane Reserves Revision Increases...

429

Ohio Coalbed Methane Proved Reserves Adjustments (Billion Cubic...  

U.S. Energy Information Administration (EIA) Indexed Site

Available; W Withheld to avoid disclosure of individual company data. Release Date: 1242014 Next Release Date: 12312015 Referring Pages: Coalbed Methane Reserves Adjustments...

430

,"U.S. Coalbed Methane Proved Reserves New Field Discoveries...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Coalbed Methane Proved Reserves New Field Discoveries (Billion Cubic Feet)",1,"Annual",201...

431

,"Kansas Coalbed Methane Proved Reserves, Reserves Changes, and...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Kansas Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2013,"630...

432

Oklahoma Coalbed Methane Proved Reserves New Reservoir Discoveries...  

U.S. Energy Information Administration (EIA) Indexed Site

New Reservoir Discoveries in Old Fields (Billion Cubic Feet) Oklahoma Coalbed Methane Proved Reserves New Reservoir Discoveries in Old Fields (Billion Cubic Feet) Decade Year-0...

433

,"NM, West Coalbed Methane Proved Reserves, Reserves Changes...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves, Reserves Changes, and Production" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Late...

434

WATERJETTING: A NEW DRILLING TECHNIQUE IN COALBED METHANE RESERVOIRS.  

E-Print Network [OSTI]

??WATERJETTING: A NEW DRILLING TECHNIQUE IN COALBED METHANE RESERVOIRS Applications of waterjeting to drill horizontal wells for the purpose of degassing coalbeds prior to mining… (more)

Funmilayo, Gbenga M.

2010-01-01T23:59:59.000Z

435

,"U.S. Coalbed Methane Production (Billion Cubic Feet)"  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Coalbed Methane Production (Billion Cubic Feet)",1,"Annual",2013 ,"Release Date:","124...

436

,"U.S. Coalbed Methane Proved Reserves New Reservoir Discoveries...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Coalbed Methane Proved Reserves New Reservoir Discoveries in Old Fields (Billion Cubic...

437

,"West Virginia Coalbed Methane Proved Reserves, Reserves Changes...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","West Virginia Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2013,"630...

438

,"New Mexico Coalbed Methane Proved Reserves, Reserves Changes...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","New Mexico Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2013,"630...

439

,"TX, RRC District 2 Onshore Coalbed Methane Proved Reserves...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves, Reserves Changes, and Production" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Late...

440

,"U.S. Coalbed Methane Proved Reserves Acquisitions (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Coalbed Methane Proved Reserves Acquisitions (Billion Cubic Feet)",1,"Annual",2013...

Note: This page contains sample records for the topic "methane reforming process" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Wyoming Coalbed Methane Proved Reserves New Reservoir Discoveries...  

U.S. Energy Information Administration (EIA) Indexed Site

New Reservoir Discoveries in Old Fields (Billion Cubic Feet) Wyoming Coalbed Methane Proved Reserves New Reservoir Discoveries in Old Fields (Billion Cubic Feet) Decade Year-0...

442

,"U.S. Coalbed Methane Proved Reserves Revision Increases (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Coalbed Methane Proved Reserves Revision Increases (Billion Cubic Feet)",1,"Annual",2013...

443

,"U.S. Coalbed Methane Proved Reserves Adjustments (Billion Cubic...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Coalbed Methane Proved Reserves Adjustments (Billion Cubic Feet)",1,"Annual",2013...

444

,"Utah Coalbed Methane Proved Reserves, Reserves Changes, and...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Utah Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2013,"630...

445

,"TX, RRC District 10 Coalbed Methane Proved Reserves, Reserves...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves, Reserves Changes, and Production" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Late...

446

,"TX, RRC District 4 Onshore Coalbed Methane Proved Reserves...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves, Reserves Changes, and Production" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Late...

447

,"NM, East Coalbed Methane Proved Reserves, Reserves Changes...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves, Reserves Changes, and Production" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Late...

448

,"TX, RRC District 3 Onshore Coalbed Methane Proved Reserves...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves, Reserves Changes, and Production" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Late...

449

,"Texas Coalbed Methane Proved Reserves, Reserves Changes, and...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves, Reserves Changes, and Production" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Late...

450

,"U.S. Coalbed Methane Proved Reserves Revision Decreases (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Coalbed Methane Proved Reserves Revision Decreases (Billion Cubic Feet)",1,"Annual",2013...

451

Utah Coalbed Methane Proved Reserves New Reservoir Discoveries...  

U.S. Energy Information Administration (EIA) Indexed Site

New Reservoir Discoveries in Old Fields (Billion Cubic Feet) Utah Coalbed Methane Proved Reserves New Reservoir Discoveries in Old Fields (Billion Cubic Feet) Decade Year-0 Year-1...

452

Methane production during the anaerobic decomposition of composted and raw organic refuse in simulated landfill cells  

E-Print Network [OSTI]

Methane contributes 20% annually to increases in global warming, and is explosive at concentrations of 5-15% in air. Landfills contribute 15% to total methane emissions. This study was conducted to determine the potential decrease in methane...

West, Margrit Evelyn

1995-01-01T23:59:59.000Z

453

Analysis of a direct methane conversion to high molecular weight hydrocarbons  

E-Print Network [OSTI]

Methane conversion to heavier hydrocarbons was studied using electrical furnaces and a plasma apparatus. The experiments were performed with pure methane for the electrical furnace experiments while pure methane and additions such as hydrogen...

Al-Ghafran, Moh'd. J.

2000-01-01T23:59:59.000Z

454

Contribution of oceanic gas hydrate dissociation to the formation of Arctic Ocean methane plumes  

E-Print Network [OSTI]

Potential distribution of methane hydrate in the world'sisotopic evidence for methane hydrate instability duringHendy, L.L. , and R.J. Behl, Methane hydrates in quaternary

Reagan, M.

2012-01-01T23:59:59.000Z

455

Future methane, hydroxyl, and their uncertainties: key climate and emission parameters for future predictions  

E-Print Network [OSTI]

in tropospheric ozone and methane; global 3-D model studies,hydroxyl radical and methane life- time from the Atmosphericof meteorology and emissions on methane trends, 1990–2004,

Holmes, C. D; Prather, M. J; Sovde, O. A; Myhre, G.

2013-01-01T23:59:59.000Z

456

Methane in lakes and wetlands -Microbiological production, ecosystem uptake, climatological significance  

E-Print Network [OSTI]

1 Methane in lakes and wetlands - Microbiological production, ecosystem ZĂŒrcher, Fortunat Joos Global methane emissions from wet ecosystems 9:50 - 10 Were tropical wetlands C4-dominated during the glacial? A view from methane

MĂŒhlemann, Oliver

457

Methane Hydrate Dissociation by Depressurization in a Mount Elbert Sandstone Sample: Experimental Observations and Numerical Simulations  

E-Print Network [OSTI]

S.S.H. , 1987. Kinetics of Methane Hydrate Decomposition,T. J. , et al. (2007), Methane Hydrate Formation andCharting the future of methane hydrate research in the

Kneafsey, T.

2012-01-01T23:59:59.000Z

458

SUESS ET AL.: SEA FLOOR METHANE HYDRATES AT HYDRATE RIDGE, CASCADIA MARGIN Sea Floor Methane Hydrates at Hydrate Ridge, Cascadia Margin  

E-Print Network [OSTI]

SUESS ET AL.: SEA FLOOR METHANE HYDRATES AT HYDRATE RIDGE, CASCADIA MARGIN 1 Sea Floor Methane are exposed at the sea floor. A methane-oxidizing bacterial consortium populates the exposures of hydrate; colonies of vent macro-fauna are abundant as well. Discharge of methane from destabilized hydrate

Goldfinger, Chris

459

Mechanistic studies of electron transfer, complex formation, C-H bond activation, and product binding in soluble methane monooxygenase  

E-Print Network [OSTI]

Chapter 1. Soluble Methane Monooxygenase: Activation of Dioxygen and Methane The mechanisms by which soluble methane monooxygenase uses dioxygen to convert methane selectively to methanol have come into sharp focus. Diverse ...

Kopp, Daniel Arthur

2003-01-01T23:59:59.000Z

460

Autothermal hydrodesulfurizing reforming method and catalyst  

DOE Patents [OSTI]

A method for reforming a sulfur-containing carbonaceous fuel in which the sulfur-containing carbonaceous fuel is mixed with H.sub.2 O and an oxidant, forming a fuel/H.sub.2 O/oxidant mixture. The fuel H.sub.2 O/oxidant mixture is brought into contact with a catalyst composition comprising a dehydrogenation portion, an oxidation portion and a hydrodesulfurization portion, resulting in formation of a hydrogen-containing gas stream.

Krumpelt, Michael; Kopasz, John P.; Ahmed, Shabbir; Kao, Richard Li-chih; Randhava, Sarabjit Singh

2005-11-22T23:59:59.000Z

Note: This page contains sample records for the topic "methane reforming process" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Steam reforming as a method to treat Hanford underground storage tank (UST) wastes  

SciTech Connect (OSTI)

This report summarizes a Sandia program that included partnerships with Lawrence Livermore National Laboratory and Synthetica Technologies, Inc. to design and test a steam reforming system for treating Hanford underground storage tank (UST) wastes. The benefits of steam reforming the wastes include the resolution of tank safety issues and improved radionuclide separations. Steam reforming destroys organic materials by first gasifying, then reacting them with high temperature steam. Tests indicate that up to 99% of the organics could be removed from the UST wastes by steam exposure. In addition, it was shown that nitrates in the wastes could be destroyed by steam exposure if they were first distributed as a thin layer on a surface. High purity alumina and nickel alloys were shown to be good candidates for materials to be used in the severe environment associated with steam reforming the highly alkaline, high nitrate content wastes. Work was performed on designing, building, and demonstrating components of a 0.5 gallon per minute (gpm) system suitable for radioactive waste treatment. Scale-up of the unit to 20 gpm was also considered and is feasible. Finally, process demonstrations conducted on non-radioactive waste surrogates were carried out, including a successful demonstration of the technology at the 0.1 gpm scale.

Miller, J.E.; Kuehne, P.B. [eds.] [and others

1995-07-01T23:59:59.000Z

462

Autothermal Reforming of Renewable Fuels  

SciTech Connect (OSTI)

The conversion of biomass into energy and chemicals is a major research and technology challenge of this century, comparable to petroleum processing in the last century. Recently we have successfully transformed both volatile liquids and nonvolatile liquids and solids into syngas with no carbon formation in autothermal catalytic reactors with residence times of ~10 milliseconds. In the proposed research program we explore the mechanisms of these processes and their extensions to other biomass sources and applications by examining different feeds, catalysts, flow conditions, and steam addition to maximize production of either syngas or chemicals. We will systematically study the catalytic partial oxidation in millisecond autothermal reactors of solid biomass and the liquid products formed by pyrolysis of solid biomass. We will examine alcohols, polyols, esters, solid carbohydrates, and lignocellulose to try to maximize formation of either hydrogen and syngas or olefins and oxygenated chemicals. We will explore molecules and mixtures of practical interest as well as surrogate molecules that contain the functional groups of biofuels but are simpler to analyze and interpret. We will examine spatial profiles within the catalyst and transient and periodic operation of these reactors at pressures up to 10 atm to obtain data from which to explore more detailed mechanistic models and optimize performance to produce a specific desired product. New experiments will examine the conversion of syngas into biofuels such as methanol and dimethyl ether to explore the entire process of producing biofuels from biomass in small distributed systems. Experiments and modeling will be integrated to probe and understand detailed reaction kinetics and the processes by which solid biomass particles are transformed into syngas and chemicals by reactive flash volatilization.

Schmidt, Lanny D

2009-05-01T23:59:59.000Z

463

Catalyst and process development for hydrogen preparation from future fuel-cell feedstocks. Final report, October 1, 1978-June 30, 1981  

SciTech Connect (OSTI)

The objective of this contract was to develop and demonstrate processes for the production of gaseous fuel cell feeds from high sulfur distillate fuels. The processes considered and studied in this program were high temperature steam reforming with hydrogen recycle, catalytic partial oxidation, and autothermal reforming. Even with hydrogen recycle, high temerature steam reforming of No. 2 oil proved to be dfficult due to carbon formation in the preheat section. Several steam reforming catalysts were evaluated during this phase of the program. (WHK)

Hwang, H.S.; Feins, I.R.; Yarrington, R.M.

1981-09-01T23:59:59.000Z

464

Methane Digesters and Biogas Recovery - Masking the Environmental Consequences of Industrial Concentrated Livestock Production  

E-Print Network [OSTI]

DIGESTERS AND BIOGAS RECOVERY Digesters Do Not Address theMethane Digesters and Biogas Recovery-Masking theII. METHANE DIGESTERS AND BIOGAs RECOVERY- IN THE

Di Camillo, Nicole G.

2011-01-01T23:59:59.000Z

465

Development of gas production type curves for horizontal wells in coalbed methane reservoirs.  

E-Print Network [OSTI]

??Coalbed methane is an unconventional gas resource that consists of methane production from coal seams .The unique difference between CBM and conventional gas reservoirs is… (more)

Nfonsam, Allen Ekahnzok.

2006-01-01T23:59:59.000Z

466

Coalbed Methane Produced Water Screening Tool for Treatment Technology and Beneficial Use 2013 Supporting Information  

E-Print Network [OSTI]

Coalbed Methane Produced Water Screening Tool for Treatment Technology and Beneficial Use 2013 1 (to sustain instream #12;Coalbed Methane Produced Water Screening Tool for Treatment Technology

467

Presentations from the March 27th - 28th Methane Hydrates Advisory...  

Broader source: Energy.gov (indexed) [DOE]

the March 27th - 28th Methane Hydrates Advisory Committee Meeting Presentations from the March 27th - 28th Methane Hydrates Advisory Committee Meeting International Gas Hydrate...

468

E-Print Network 3.0 - anthropogenic methane emissions Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

regional assessments... and global lake methane emissions, contributing to the greenhouse effect, are poorly known. We developed... predictions of methane emissions from easily...

469

Methane Digesters and Biogas Recovery - Masking the Environmental Consequences of Industrial Concentrated Livestock Production  

E-Print Network [OSTI]

Methane Digesters and Biogas Recovery-Masking theII. METHANE DIGESTERS AND BIOGAs RECOVERY- IN THEA. Digesters Have Received Attention for Their Potential to

Di Camillo, Nicole G.

2011-01-01T23:59:59.000Z

470

1870 Organometallics 1994,13,1870-1877 Mechanism and Energetics for Dehydrogenation of Methane  

E-Print Network [OSTI]

1870 Organometallics 1994,13,1870-1877 Mechanism and Energetics for Dehydrogenation of Methane also activate CHI. 1. Introduction Becauseof the enormousworldwidereservesof methane (CH4)andthe

Goddard III, William A.

471

Experimental and kinetic study of autoignition in methane/ethane/air and methane/propane/air mixtures under engine-relevant conditions  

SciTech Connect (OSTI)

The ignition delay of homogeneous methane/air mixtures enriched with small fractions of ethane/propane was measured using the reflected-shock technique at temperatures from 900 to 1400 K and pressures from 16 to 40 bar. The results show complex effects of ethane/propane on the ignition of methane, but a common trend observed with both hydrocarbons is an increased promotion effect for temperatures below 1100 K. A detailed kinetic mechanism was used to investigate the interaction between ethane/propane and the ignition chemistry of methane under the above conditions. It was found that at relatively low temperatures, the reactions between ethane/propane and methylperoxy (CH{sub 3}O{sub 2}) lead to an enhanced rate of formation of OH radicals in the initiation phase of the ignition. By systematically applying the quasi-steady-state assumptions to the intermediate species involved in the main reaction path identified, we have achieved an analytical description of the ignition process in the transitional temperature regime. The analytical solutions agree reasonably well with the detailed kinetic model and the experimental results for both ignition delay and concentrations of major intermediate species.

Huang, J.; Bushe, W.K. [Department of Mechanical Engineering, University of British Columbia, 6950 Applied Science Lane, Vancouver, British Columbia (Canada V6T 1Z4)

2006-01-01T23:59:59.000Z

472

Detection and Production of Methane Hydrate  

SciTech Connect (OSTI)

This project seeks to understand regional differences in gas hydrate systems from the perspective of as an energy resource, geohazard, and long-term climate influence. Specifically, the effort will: (1) collect data and conceptual models that targets causes of gas hydrate variance, (2) construct numerical models that explain and predict regional-scale gas hydrate differences in 2-dimensions with minimal 'free parameters', (3) simulate hydrocarbon production from various gas hydrate systems to establish promising resource characteristics, (4) perturb different gas hydrate systems to assess potential impacts of hot fluids on seafloor stability and well stability, and (5) develop geophysical approaches that enable remote quantification of gas hydrate heterogeneities so that they can be characterized with minimal costly drilling. Our integrated program takes advantage of the fact that we have a close working team comprised of experts in distinct disciplines. The expected outcomes of this project are improved exploration and production technology for production of natural gas from methane hydrates and improved safety through understanding of seafloor and well bore stability in the presence of hydrates. The scope of this project was to more fully characterize, understand, and appreciate fundamental differences in the amount and distribution of gas hydrate and how this would affect the production potential of a hydrate accumulation in the marine environment. The effort combines existing information from locations in the ocean that are dominated by low permeability sediments with small amounts of high permeability sediments, one permafrost location where extensive hydrates exist in reservoir quality rocks and other locations deemed by mutual agreement of DOE and Rice to be appropriate. The initial ocean locations were Blake Ridge, Hydrate Ridge, Peru Margin and GOM. The permafrost location was Mallik. Although the ultimate goal of the project was to understand processes that control production potential of hydrates in marine settings, Mallik was included because of the extensive data collected in a producible hydrate accumulation. To date, such a location had not been studied in the oceanic environment. The project worked closely with ongoing projects (e.g. GOM JIP and offshore India) that are actively investigating potentially economic hydrate accumulations in marine settings. The overall approach was fivefold: (1) collect key data concerning hydrocarbon fluxes which is currently missing at all locations to be included in the study, (2) use this and existing data to build numerical models that can explain gas hydrate variance at all four locations, (3) simulate how natural gas could be produced from each location with different production strategies, (4) collect new sediment property data at these locations that are required for constraining fluxes, production simulations and assessing sediment stability, and (5) develop a method for remotely quantifying heterogeneities in gas hydrate and free gas distributions. While we generally restricted our efforts to the locations where key parameters can be measured or constrained, our ultimate aim was to make our efforts universally applicable to any hydrate accumulation.

George Hirasaki; Walter Chapman; Gerald Dickens; Colin Zelt; Brandon Dugan; Kishore Mohanty; Priyank Jaiswal

2011-12-31T23:59:59.000Z

473

FLUIDIZED BED STEAM REFORMING ENABLING ORGANIC HIGH LEVEL WASTE DISPOSAL  

SciTech Connect (OSTI)

Waste streams planned for generation by the Global Nuclear Energy Partnership (GNEP) and existing radioactive High Level Waste (HLW) streams containing organic compounds such as the Tank 48H waste stream at Savannah River Site have completed simulant and radioactive testing, respectfully, by Savannah River National Laboratory (SRNL). GNEP waste streams will include up to 53 wt% organic compounds and nitrates up to 56 wt%. Decomposition of high nitrate streams requires reducing conditions, e.g. provided by organic additives such as sugar or coal, to reduce NOX in the off-gas to N2 to meet Clean Air Act (CAA) standards during processing. Thus, organics will be present during the waste form stabilization process regardless of the GNEP processes utilized and exists in some of the high level radioactive waste tanks at Savannah River Site and Hanford Tank Farms, e.g. organics in the feed or organics used for nitrate destruction. Waste streams containing high organic concentrations cannot be stabilized with the existing HLW Best Developed Available Technology (BDAT) which is HLW vitrification (HLVIT) unless the organics are removed by pretreatment. The alternative waste stabilization pretreatment process of Fluidized Bed Steam Reforming (FBSR) operates at moderate temperatures (650-750 C) compared to vitrification (1150-1300 C). The FBSR process has been demonstrated on GNEP simulated waste and radioactive waste containing high organics from Tank 48H to convert organics to CAA compliant gases, create no secondary liquid waste streams and create a stable mineral waste form.

Williams, M

2008-05-09T23:59:59.000Z

474

Applied reaction dynamics: Efficient synthesis gas production via single collision partial oxidation of methane to CO on Rh,,111...  

E-Print Network [OSTI]

of the incident beam's translational energy, and approaches unity for energies greater than 1.3 eV. Comparison for methanol synthesis. One method is the direct partial oxidation of methane, CH4 + 1/2 O2 CO + 2H2. 1 This process has been extensively studied using high surface area supported Rh catalysts in flow reactors

Sibener, Steven

475

Distributed Reforming of Renewable Liquids via Water Splitting...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Renewable Liquids via Water Splitting using Oxygen Transport Membrane (OTM) (Presentation) Distributed Reforming of Renewable Liquids via Water Splitting using Oxygen Transport...

476

Bio-Derived Liquids to Hydrogen Distributed Reforming Working...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Production Systems, Sandy Thomas, H2Gen Integrated Short Contact Time Hydrogen Generator, Wei Wei, GE Global Research Distributed Bio-Oil Reforming, Darlene Steward,...

477

Agenda for the Derived Liquids to Hydrogen Distributed Reforming...  

Broader source: Energy.gov (indexed) [DOE]

Agenda for the Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG) Hydrogen Production Technical Team Research Review Agenda for the Derived Liquids to...

478

Bio-Derived Liquids to Hydrogen Distributed Reforming Working...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Working Group (BILIWG), Hydrogen Separation and Purification Working Group (PURIWG) & Hydrogen Production Technical Team Bio-Derived Liquids to Hydrogen Distributed Reforming...

479

Bio-Derived Liquids to Hydrogen Distributed Reforming Targets  

Broader source: Energy.gov [DOE]

Presentation by Arlene Anderson at the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

480

Bio-Derived Liquids to Hydrogen Distributed Reforming Working...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Contact Time Hydrogen Generator, Ke Liu, GE Global Research Hydrogen from Biomass by Autothermal Reforming, Lanny D. Schmidt, University of Minnesota Low-Cost Hydrogen from Ethanol...

Note: This page contains sample records for the topic "methane reforming process" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Welfare Impacts of Electricity Generation Sector Reform in the Philippines  

E-Print Network [OSTI]

the Government lost and there was an air pollution cost. The paper concludes that the reform with private sector participation increased social welfare....

Toba, Natsuko

2004-06-16T23:59:59.000Z

482

On-Board Ammonia Generation Using Delphi Diesel Fuel Reformer  

Broader source: Energy.gov (indexed) [DOE]

On-Board Ammonia Generation Using Delphi Diesel Fuel Reformer Mark Hemingway, Dr. Joachim Kupe, Joseph Bonadies, Mike Seino, Dr. John Kirwan, - Delphi Powertrain DEER, August...

483

advance hatchery reform: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Private Insurance Market Renewable Energy Websites Summary: SUMMARY s national health care reform efforts go forward, it is instructive to review states' experience INTRODUCTION...

484

Diesel Reformers for On-board Hydrogen Applications  

Broader source: Energy.gov (indexed) [DOE]

After-treatment Catalyst Clean Exhaust Effective Catalyst Regeneration Emission Reduction Electricity for On-road and Idling Loads SOFC APU Efficiency Boost Reformers for...

485

Methane Hydrate Program Annual Report to Congress  

Energy Savers [EERE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of Inspector General Office0-72.pdfGeorgeDoesn't32 Master EM ProjectMemoDepartmentFY 2010 Methane Hydrate

486

Coke profile and effect on methane/ethylene conversion process  

E-Print Network [OSTI]

The objective of this study was to investigate the coke profile with respect to time on stream and the change of product distribution due to catalyst deactivation. A fixed bed reactor was used to conduct this investigation. A series of runs were...

Al-Solami, Bandar

2002-01-01T23:59:59.000Z

487

Edinburgh Research Explorer Reforming State Pension provision in `Liberal' Anglo Saxon  

E-Print Network [OSTI]

Edinburgh Research Explorer Reforming State Pension provision in `Liberal' Anglo Saxon Countries, Vickerstaff, S & Loretto, W 2012, 'Reforming State Pension provision in `Liberal' Anglo Saxon Countries: Re University Press. Lain, D., Vickerstaff, S. & Loretto, W. 2012, "Reforming State Pension provision

Millar, Andrew J.

488

Assuring Equity Through Health and Health Care Reform Conference Registration Information (Type or Print)  

E-Print Network [OSTI]

Assuring Equity Through Health and Health Care Reform Conference Registration Information (Type Care Structural Reform: What's Happening in Albany and Washington? Changing the Social Determinants of Health Reform in the Pharmaceutical Industry Sustaining Community Health Workers Comparative

Brown, Lucy L.

489

Aligning modes of organization with technology: Critical transactions in the reform of infrastructures  

E-Print Network [OSTI]

1 Aligning modes of organization with technology: Critical transactions in the reform of their reform. Since infrastructures are characterized by strong technical complementarities, we explore the alignment between organization and technology and should be taken explicitly into account when reforming

Boyer, Edmond

490

Negotiating Education Reform: Teacher Evaluations and Incentives in Chile (1990-2010)  

E-Print Network [OSTI]

Reforms designed to improve the quality of teaching by reforming personnel practices, such as pay for performance arrangements, usually run into opposition from well-organized teacher unions that can either block reform ...

Mizala, Alejandra

491

Electricity Sector Reform in Developing Countries: A Survey of Empirical Evidence on Determinants and Performance  

E-Print Network [OSTI]

This paper reviews the empirical evidence on electricity reform in developing countries. We find that country institutions and sector governance play an important role in success and failure of reform; reforms appear to have increased operating...

Jamasb, Tooraj; Mota, Raffaella L; Newbery, David; Pollitt, Michael G.

2004-07-09T23:59:59.000Z

492

Formation mechanism for polycyclic aromatic hydrocarbons in methane flames  

E-Print Network [OSTI]

Formation mechanism for polycyclic aromatic hydrocarbons in methane flames K. Siegmanna) Swiss 96822 Received 24 August 1999; accepted 13 October 1999 A laminar diffusion flame of methane exhausts,7­17 coal-fired, electricity generating power plants,18,19 tobacco smoke,20 residential wood

Sattler, Klaus

493

Development of a Series of National Coalbed Methane Databases  

E-Print Network [OSTI]

Development of a Series of National Coalbed Methane Databases Mohaghegh, S. D., Nunsavathu, U Growing Interest in Coalbed Methane ­ Elevated natural gas prices ­ Demand for clean energy sources DatabaseDatabase One Location Reservoir & Sorption Collection ­ 126 Coalbed Areas ­ 34 Parameters Ordered

Mohaghegh, Shahab

494

Rapid communication Mapping urban pipeline leaks: Methane leaks across Boston  

E-Print Network [OSTI]

Rapid communication Mapping urban pipeline leaks: Methane leaks across Boston Nathan G. Phillips a of methane (CH4) in the United States. To assess pipeline emissions across a major city, we mapped CH4 leaks extraction and pipeline transmission are the largest human-derived source of emissions (EPA, 2012). However

Jackson, Robert B.

495

Photofragment imaging of methane Albert J. R. Heck  

E-Print Network [OSTI]

on CH4. © 1996 American Institute of Physics. S0021-9606 96 03810-3 INTRODUCTION Knowledge about the photo dissociation pathways of the methane molecule is of fundamental importance as it is of central, the photochemistry of methane in the atmosphere is mostly driven by intense solar atomic emission lines

Zare, Richard N.

496

The thermal decomposition of methane in a tubular reactor  

SciTech Connect (OSTI)

The reaction rate of methane decomposition using a tubular reactor having a 1 inch inside diameter with an 8 foot long heated zone was investigated in the temperature range of 700 to 900 C with pressures ranging from 28.2 to 56.1 atm. Representing the rate by a conventional model, {minus}dC{sub CH4}/dt= k1 C{sub CH4} {minus}k2 C{sub H2}{sup 2}, the rate constant k1 for methane decomposition was determined. The activation energy, 31.3 kcal/mol, calculated by an Arrhenius Plot was lower than for previously published results for methane decomposition. This result indicates that submicron particles found in the reactor adhere to the inside of the reactor and these submicron high surface area carbon particles tend to catalyze the methane decomposition. The rate constant has been found to be approximately constant at 900 C with pressure range cited above. The rate of methane decomposition increases with methane partial pressure in first-order. The rate of the methane decomposition is favored by higher temperatures and pressures while the thermochemical equilibrium of methane decomposition is favored by lower pressures. 8 refs., 7 figs., 2 tabs.

Kobayashi, Atsushi; Steinberg, M.

1992-01-01T23:59:59.000Z

497

Catalytic Tar Reforming for Cleanup and Conditioning of Biomass-derived Syngas  

SciTech Connect (OSTI)

Biomass gasification is being investigated to produce clean syngas from biomass or biorefinery residues as an intermediate that can be used directly as a fuel for integrated heat and power production or further refined and upgraded by various processing technologies. Conditioning of biomass-derived syngas, with an emphasis on tar reforming, to make it a suitable feed for high temperature, pressurized liquid fuels synthesis is the goal of current research efforts.

Dayton, D. C.; Bain, R. L.; Phillips, S. D.; Magrini-Bair, K.; Feik, C. J.

2006-01-01T23:59:59.000Z

498

Development of OTM Syngas Process and Testing of Syngas Derived Ulta-clean Fuels in Diesel Engines and Fuel Cells Budget Period 3  

SciTech Connect (OSTI)

This topical report summarizes work accomplished for the Program from January 1, 2003 through December 31,2004 in the following task areas: Task 1--Materials Development; Task 2--Composite Development; Task 4--Reactor Design and Process Optimization; Task 8--Fuels and Engine Testing; 8.1 International Diesel Engine Program; and Task IO: Program Management. Most of the key technical objectives for this budget period were achieved. Only partial success was achieved relative to cycle testing under pressure Major improvements in material performance and element reliability have been achieved. A breakthrough material system has driven the development of a compact planar reactor design capable of producing either hydrogen or syngas. The planar reactor shows significant advantages in thermal efficiency and costs compared to either steam methane reforming with CO{sub 2} recovery or autothermal reforming. The fuel and engine testing program is complete The single cylinder test engine evaluation of UCTF fuels begun in Budget Period 2 was finished this budget period. In addition, a study to evaluate new fuel formulations for an HCCl engine was completed.

E.T. Robinson; John Sirman; Prasad Apte; Xingun Gui; Tytus R. Bulicz; Dan Corgard; Siv Aasland; Kjersti Kleveland; Ann Hooper; Leo Bonnell; John Hemmings; Jack Chen; Bart A. Van Hassel

2004-12-31T23:59:59.000Z

499

E-Print Network 3.0 - animal reproductive processes Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

permission of the copyright owner. Further reproduction prohibited without permission. Economic reform and the process of global integration; Comments Summary: Reproduced with...

500

A STUDY ON SPHERICAL EXPANDING FLAME SPEEDS OF METHANE, ETHANE, AND METHANE/ETHANE MIXTURES AT ELEVATED PRESSURES  

E-Print Network [OSTI]

High-pressure experiments and chemical kinetics modeling were performed for laminar spherically expanding flames for methane/air, ethane/air, methane/ethane/air and propane/air mixtures at pressures between 1 and 10 atm and equivalence ratios...

De Vries, Jaap

2010-07-14T23:59:59.000Z