Sample records for methane propane gas

  1. Hydrogen Safety Issues Compared to Safety Issues with Methane and Propane

    E-Print Network [OSTI]

    Green, Michael A.

    2005-01-01T23:59:59.000Z

    Issues with Methane and Propane Michael A. Green LawrenceSAFETY ISSUES WITH METHANE AND PROPANE M. A. Green Lawrencehydrogen. Methane and propane are commonly used by ordinary

  2. Author's personal copy Unified behaviour of maximum soot yields of methane, ethane and propane

    E-Print Network [OSTI]

    Gülder, Ömer L.

    Author's personal copy Unified behaviour of maximum soot yields of methane, ethane and propane the current study and the previous measurements in similar flames with methane, ethane, and propane flames

  3. Novel Methane, Ethane, and Propane Oxidizing Bacteria at Marine Hydrocarbon Seeps Identified by Stable Isotope Probing

    E-Print Network [OSTI]

    Sessions, Alex L.

    Novel Methane, Ethane, and Propane Oxidizing Bacteria at Marine Hydrocarbon Seeps Identified by Stable Isotope Probing Running Title: Novel Methane, Ethane, and Propane Oxidizing Bacteria Section incubating sediment with 13 C-labeled methane, ethane, or propane, we5 confirmed the incorporation of 13 C

  4. Molecular Properties of the "Ideal" Inhaled Anesthetic: Studies of Fluorinated Methanes, Ethanes, Propanes,

    E-Print Network [OSTI]

    Hudlicky, Tomas

    , Propanes, and Butanes E. 1Eger, 11, MD*, J. Liu, MD*, D. D. Koblin, PhD, MDt, M. J. Laster, DVM*, S. Taheri unfluorinated, partially fluorinated, and perfluorinated methanes, ethanes, propanes, and butanes to define fluorinated methanes, ethanes, propanes, and butanes, also obtaining limited data on longer- chained alkanes

  5. QER- Comment of National Propane Gas Association

    Broader source: Energy.gov [DOE]

    Ladies and Gentlemen: Please find attached the QER comments of the National Propane Gas Association. Please feel to contact us if we can provide further information. Thank you for your attention to our submission.

  6. National propane safety week caps fifth anniversary of GAS Check

    SciTech Connect (OSTI)

    Prowler, S.

    1990-09-01T23:59:59.000Z

    This paper reports on National Propane Safety Week. The publicity encompassed everything from preventative maintenance to safe winter storage of cylinders. This campaign focused much of its attention on GAS (gas appliance system) Check, the propane industry's most well-known safety program.

  7. Comparison of propane and methane performance and emissions in a turbocharged direct injection dual fuel engine

    SciTech Connect (OSTI)

    Gibson, C. M.; Polk, A. C.; Shoemaker, N. T.; Srinivasan, K. K.; Krishnan, S. R.

    2011-04-20T23:59:59.000Z

    With increasingly restrictive NO x and particulate matter emissions standards, the recent discovery of new natural gas reserves, and the possibility of producing propane efficiently from biomass sources, dual fueling strategies have become more attractive. This paper presents experimental results from dual fuel operation of a four-cylinder turbocharged direct injection (DI) diesel engine with propane or methane (a natural gas surrogate) as the primary fuel and diesel as the ignition source. Experiments were performed with the stock engine control unit at a constant speed of 1800 rpm, and a wide range of brake mean effective pressures (BMEPs) (2.7-11.6 bars) and percent energy substitutions (PESs) of C 3 H 8 and CH 4. Brake thermal efficiencies (BTEs) and emissions (NO x, smoke, total hydrocarbons (THCs), CO, and CO 2) were measured. Maximum PES levels of about 80-95% with CH 4 and 40-92% with C 3 H 8 were achieved. Maximum PES was limited by poor combustion efficiencies and engine misfire at low loads for both C 3 H 8 and CH 4, and the onset of knock above 9 bar BMEP for C 3 H 8. While dual fuel BTEs were lower than straight diesel BTEs at low loads, they approached diesel BTE values at high loads. For dual fuel operation, NO x and smoke reductions (from diesel values) were as high as 66-68% and 97%, respectively, but CO and THC emissions were significantly higher with increasing PES at all engine loads

  8. 4-70C Propane (molar mass = 44.1 kg/kmol) poses a greater fire danger than methane (molar mass = 16 kg/kmol) since propane is heavier than air (molar mass = 29 kg/kmol), and it will settle near the floor.

    E-Print Network [OSTI]

    Bahrami, Majid

    4-36 Ideal Gas 4-70C Propane (molar mass = 44.1 kg/kmol) poses a greater fire danger than methane (molar mass = 16 kg/kmol) since propane is heavier than air (molar mass = 29 kg/kmol), and it will settle MATERIAL. © 2008 The McGraw-Hill Companies, Inc. Limited distribution permitted only to teachers

  9. ARM - Methane Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadap Documentation TDMADAP : XDCnarrowbandheat flux ARMMeasurementsMethane Gas Outreach Home Room

  10. Performance and Emissions Characteristics of Bio-Diesel (B100)-Ignited Methane and Propane Combustion in a Four Cylinder Turbocharged Compression Ignition Engine

    SciTech Connect (OSTI)

    Shoemaker, N. T.; Gibson, C. M.; Polk, A. C.; Krishnan, S. R.; Srinivasan, K. K.

    2011-10-05T23:59:59.000Z

    Different combustion strategies and fuel sources are needed to deal with increasing fuel efficiency demands and emission restrictions. One possible strategy is dual fueling using readily available resources. Propane and natural gas are readily available with the current infrastructure and biodiesel is growing in popularity as a renewable fuel. This paper presents experimental results from dual fuel combustion of methane (as a surrogate for natural gas) and propane as primary fuels with biodiesel pilots in a 1.9 liter, turbocharged, 4 cylinder diesel engine at 1800 rev/min. Experiments were performed with different percentage energy substitutions (PES) of propane and methane and at different brake mean effective pressures (BMEP/bmep). Brake thermal efficiency (BTE) and emissions (NOx, HC, CO, CO2, O2 and smoke) were also measured. Maximum PES levels for B100-methane dual fuelling were limited to 70% at 2.5 bar bmep and 48% at 10 bar bmep, and corresponding values for B100-propane dual fuelling were 64% and 43%, respectively. Maximum PES was limited by misfire at 2.5 bar bmep and the onset of engine knock at 10 bar bmep. Dual fuel BTEs approached straight B100 values at 10 bar bmep while they were significantly lower than B100 values at 2.5 bar bmep. In general dual fuelling was beneficial in reducing NOx and smoke emissions by 33% and 50%, respectively from baseline B100 levels; however, both CO and THC emissions were significantly higher than baseline B100 levels at all PES and loads.

  11. Automatic isochoric apparatus for PVT and phase equilibrium studies of natural gas mixtures

    E-Print Network [OSTI]

    Zhou, Jingjun

    2009-05-15T23:59:59.000Z

    ........................................................................................ 51 RESULTS AND DISCUSSION .................................................................................... 54 Carbon Dioxide and Propane Measurement........................................................... 54 91% Methane Natural Gas... 94% Methane Natural Gas ..................................................................................... 65 Phase Boundary....................................................................................... 65...

  12. Analysis of ignition behavior in a turbocharged direct injection dual fuel engine using propane and methane as primary fuels

    SciTech Connect (OSTI)

    Polk, A. C.; Gibson, C. M.; Shoemaker, N. T.; Srinivasan, K. K.; Krishnan, S. R.

    2011-10-05T23:59:59.000Z

    This paper presents experimental analyses of the ignition delay (ID) behavior for diesel-ignited propane and diesel-ignited methane dual fuel combustion. Two sets of experiments were performed at a constant speed (1800 rev/min) using a 4-cylinder direct injection diesel engine with the stock ECU and a wastegated turbocharger. First, the effects of fuel-air equivalence ratios (���© pilot �¢���¼ 0.2-0.6 and ���© overall �¢���¼ 0.2-0.9) on IDs were quantified. Second, the effects of gaseous fuel percent energy substitution (PES) and brake mean effective pressure (BMEP) (from 2.5 to 10 bar) on IDs were investigated. With constant ���© pilot (> 0.5), increasing ���© overall with propane initially decreased ID but eventually led to premature propane autoignition; however, the corresponding effects with methane were relatively minor. Cyclic variations in the start of combustion (SOC) increased with increasing ���© overall (at constant ���© pilot), more significantly for propane than for methane. With increasing PES at constant BMEP, the ID showed a nonlinear (initially increasing and later decreasing) trend at low BMEPs for propane but a linearly decreasing trend at high BMEPs. For methane, increasing PES only increased IDs at all BMEPs. At low BMEPs, increasing PES led to significantly higher cyclic SOC variations and SOC advancement for both propane and methane. Finally, the engine ignition delay (EID) was also shown to be a useful metric to understand the influence of ID on dual fuel combustion.

  13. Experimental and kinetic study of autoignition in methane/ethane/air and methane/propane/air mixtures under engine-relevant conditions

    SciTech Connect (OSTI)

    Huang, J.; Bushe, W.K. [Department of Mechanical Engineering, University of British Columbia, 6950 Applied Science Lane, Vancouver, British Columbia (Canada V6T 1Z4)

    2006-01-01T23:59:59.000Z

    The ignition delay of homogeneous methane/air mixtures enriched with small fractions of ethane/propane was measured using the reflected-shock technique at temperatures from 900 to 1400 K and pressures from 16 to 40 bar. The results show complex effects of ethane/propane on the ignition of methane, but a common trend observed with both hydrocarbons is an increased promotion effect for temperatures below 1100 K. A detailed kinetic mechanism was used to investigate the interaction between ethane/propane and the ignition chemistry of methane under the above conditions. It was found that at relatively low temperatures, the reactions between ethane/propane and methylperoxy (CH{sub 3}O{sub 2}) lead to an enhanced rate of formation of OH radicals in the initiation phase of the ignition. By systematically applying the quasi-steady-state assumptions to the intermediate species involved in the main reaction path identified, we have achieved an analytical description of the ignition process in the transitional temperature regime. The analytical solutions agree reasonably well with the detailed kinetic model and the experimental results for both ignition delay and concentrations of major intermediate species.

  14. Experimental studies of steam-propane and enriched gas injection for the Minas light crude oil 

    E-Print Network [OSTI]

    Yudishtira, Wan Dedi

    2003-01-01T23:59:59.000Z

    Experimental studies were carried out to compare the benefits of propane as an additive in steam injection and in lean gas injection to enhance production for the Minas light crude oil (34?API). The studies on steam-propane were specifically...

  15. Experimental studies of steam-propane and enriched gas injection for the Minas light crude oil

    E-Print Network [OSTI]

    Yudishtira, Wan Dedi

    2003-01-01T23:59:59.000Z

    Experimental studies were carried out to compare the benefits of propane as an additive in steam injection and in lean gas injection to enhance production for the Minas light crude oil (34?API). The studies on steam-propane were specifically...

  16. Natural Gas Infrastructure R&D and Methane Emissions Mitigation...

    Energy Savers [EERE]

    Natural Gas Infrastructure R&D and Methane Emissions Mitigation Workshop Natural Gas Infrastructure R&D and Methane Emissions Mitigation Workshop The Advanced Manufacturing Office...

  17. Unconventional gas resources. [Eastern Gas Shales, Western Gas Sands, Coalbed Methane, Methane from Geopressured Systems

    SciTech Connect (OSTI)

    Komar, C.A. (ed.)

    1980-01-01T23:59:59.000Z

    This document describes the program goals, research activities, and the role of the Federal Government in a strategic plan to reduce the uncertainties surrounding the reserve potential of the unconventional gas resources, namely, the Eastern Gas Shales, the Western Gas Sands, Coalbed Methane, and methane from Geopressured Aquifers. The intent is to provide a concise overview of the program and to identify the technical activities that must be completed in the successful achievement of the objectives.

  18. Investigation of the flame speeds of propane/methanol gas mixtures

    SciTech Connect (OSTI)

    Foote, K.L.; Villareal, J.

    1985-05-02T23:59:59.000Z

    A series of tests was conducted in an acoustically tuned flame tube in order to determine the laminar burning velocities in air of various propane/methanol gas mixtures. The experimental method is explained in detail, along with the tabular results. A 90% propane, 10% methanol mixture is shown to have a maximum burning velocity of 40.8 cm/s. A 65% propane, 35% methanol mixture has a maximum velocity of 41.8 cm/s. These maximum flame speeds are shown to be about the same as that of pure propane by the same method. Gulder has found evidence that the presence of methanol in some hydrocarbon fuels may actually inhibit combustion, but we see no apparent modifications in the combustion of propane when mixed with methanol.

  19. Reply to Saba and Orzechowski and Schon: Methane contamination of

    E-Print Network [OSTI]

    Jackson, Robert B.

    , and that the ratios of methane to ethane and propane were different [figure 4b (3)]. Furthermore, the methane present underground gas storage, leading to documented leaks into well water (5). The DEP correspondence they cite

  20. Synergistic effect of mixing dimethyl ether with methane, ethane, propane, and ethylene fuels on polycyclic aromatic hydrocarbon and soot formation

    SciTech Connect (OSTI)

    Yoon, S.S. [Corporate Research and Development Division, Hyundai-Kia Motors, Gyeonggi-do 445-706 (Korea); Anh, D.H. [Korea Electric Power Research Institute, Daejeon 305-380 (Korea); Chung, S.H. [School of Mechanical and Aerospace Engineering, Seoul National University, Seoul 151-742 (Korea)

    2008-08-15T23:59:59.000Z

    Characteristics of polycyclic aromatic hydrocarbon (PAH) and soot formation in counterflow diffusion flames of methane, ethane, propane, and ethylene fuels mixed with dimethyl ether (DME) have been investigated. Planar laser-induced incandescence and fluorescence techniques were employed to measure relative soot volume fractions and PAH concentrations, respectively. Results showed that even though DME is known to be a clean fuel in terms of soot formation, DME mixture with ethylene fuel increases PAH and soot formation significantly as compared to the pure ethylene case, while the mixture of DME with methane, ethane, and propane decreases PAH and soot formation. Numerical calculations adopting a detailed kinetics showed that DME can be decomposed to produce a relatively large number of methyl radicals in the low-temperature region where PAH forms and grows; thus the mixture of DME with ethylene increases CH{sub 3} radicals significantly in the PAH formation region. Considering that the increase in the concentration of O radicals is minimal in the PAH formation region with DME mixture, the enhancement of PAH and soot formation in the mixture flames of DME and ethylene can be explained based on the role of methyl radicals in PAH and soot formation. Methyl radicals can increase the concentration of propargyls, which could enhance incipient benzene ring formation through the propargyl recombination reaction and subsequent PAH growth. Thus, the result substantiates the importance of methyl radicals in PAH and soot formation, especially in the PAH formation region of diffusion flames. (author)

  1. Methane escape from gas hydrate systems in marine environment, and methane-driven oceanic eruptions

    E-Print Network [OSTI]

    Zhang, Youxue

    Methane escape from gas hydrate systems in marine environment, and methane-driven oceanic eruptions are suitable for gas hydrate stability [Lunine and Stevenson, 1985]. Enor- mous amounts of methane are stored as gas hydrate and free gas in the pore space of marine sediment [Kvenvolden, 1988; Buffet, 2000

  2. Effects of Propane/Natural Gas Blended Fuels on Gas Turbine Pollutant Emissions

    SciTech Connect (OSTI)

    Straub, D.L.; Ferguson, D.H.; Casleton, K.H.; Richards, G.A.

    2007-03-01T23:59:59.000Z

    Liquefied natural gas (LNG) imports to the U.S. are expected to grow significantly over the next 10-15 years. Likewise, it is expected that changes to the domestic gas supply may also introduce changes in natural gas composition. As a result of these anticipated changes, the composition of fuel sources may vary significantly from conventional domestic natural gas supplies. This paper will examine the effects of fuel variability on pollutant emissions for premixed gas turbine conditions. The experimental data presented in this paper have been collected from a pressurized single injector combustion test rig at the National Energy Technology Laboratory (NETL). The tests are conducted at 7.5 atm with a 588 K air preheat. A propane blending facility is used to vary the Wobbe Index of the site natural gas. The results indicate that propane addition of about five (vol.) percent does not lead to a significant change in the observed NOx or CO emissions. These results are different from data collected on some engine applications and potential reasons for these differences will be described.

  3. Technical Note Methane gas migration through geomembranes

    E-Print Network [OSTI]

    coefficient of PVC, LLDPE, and HDPE geomembranes by performing the standard gas transport test (ASTM D1434). The measured methane gas permeability coefficient through a PVC geomembrane is 7.55 3 104 ml(STP).mil/m2.day thicknesses is proposed using the measured permeability coefficients for PVC, LLDPE, and HDPE geomembranes

  4. Natural Gas Infrastructure R&D and Methane Emissions Mitigation...

    Broader source: Energy.gov (indexed) [DOE]

    Natural Gas Infrastructure R&D and Methane Emissions Mitigation Workshop Natural Gas Infrastructure R&D and Methane Emissions Mitigation Workshop November 12, 2014 11:00AM EST to...

  5. Measurements of Methane Emissions at Natural Gas Production Sites

    E-Print Network [OSTI]

    Lightsey, Glenn

    Measurements of Methane Emissions at Natural Gas Production Sites in the United States #12;Why = 21 #12;Need for Study · Estimates of methane emissions from natural gas production , from academic in assumptions in estimating emissions · Measured data for some sources of methane emissions during natural gas

  6. Dynamic light scattering in sooting premixed atmospheric-pressure methane-, propane-, ethene-, and propene-oxygen flames

    SciTech Connect (OSTI)

    Lamprecht, A.; Eimer, W.; Kohse-Hoeinghaus, K. [Univ. Bielefeld (Germany)] [Univ. Bielefeld (Germany)

    1999-07-01T23:59:59.000Z

    In a systematic investigation under well-defined flame conditions, dynamic light scattering (DLS) was applied to the determination of soot particle radii with the aim of examining the suitability of this technique for accurate soot particle sizing. In particular, flat premixed methane-, propane-, ethene-, and propene-oxygen flames at atmospheric pressure were investigated, and particle sizes were obtained as a function of stoichiometry and height above the burner surface. In combination with absorption measurements, soot volume fraction and particle number density were determined; also, the temperature was measured at each flame condition. In comparison to absorption techniques, attractive features of DLS are its independence of the particle refractive index and its insensitivity to fluorescence interference; also, it offers spatial resolution. In principle, additional information on the particle size distribution as well as on the global shape of the particles may be obtained from DLS experiments. This study is therefore an evaluation of the potential of DLS as a complement to other soot diagnostic techniques.

  7. Controlling Methane Emissions in the Natural Gas Sector: A Review...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Controlling Methane Emissions in the Natural Gas Sector: A Review of Federal & State Regulatory Frameworks Governing Production, Processing, Transmission, and Distribution...

  8. FROZEN HEAT A GLOBAL OUTLOOK ON METHANE GAS HYDRATES EXECUTIVE...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    governments are considering a diverse energy mix that includes a growing proportion of renewable energy sources and natural gas. Proponents of this approach suggest that methane...

  9. Quantum cascade laser investigations of CH4 and C2H2 interconversion in hydrocarbon/H2 gas mixtures during microwave plasma

    E-Print Network [OSTI]

    Bristol, University of

    described in Mankelevich et al. J. Appl. Phys. 104, 113304 2008 . The gas temperature distribution within source gases investigated methane, acetylene, ethane, propyne, propane, and butane are converted

  10. Measurements of Laminar Flame Velocity for Components of Natural Gas

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    flame velocity of components of natural gas, methane, ethane, propane, and nbutane as well as of binary% by volume (1). The laminar flame velocities of methane/air, ethane/air, and propane/air mixtures have on a plenum chamber with the radial temperature distribution measurement made by a series of thermocouples

  11. Etude cin\\'etique de CVD de pyrocarbone obtenu par pyrolyse de propane

    E-Print Network [OSTI]

    Ziegler-Devin, Isabelle; Marquaire, Paul-Marie

    2009-01-01T23:59:59.000Z

    High temeperature (900-1000\\degree C) low pressure (propane yields a pyrocarbon deposit, but also mainly hydrogen and hydrocarbons from methane to polyaromatics. 30 reaction products were exeperimentally quantified at different operating conditions. A detailed kinetic pyrolysis model (600 reactions) has been developed and validated based on the totality of experiments. This model includes a homogeneous model (describing the gas phase pyrolysis of propane) coupled with a heterogeneous model describing the pyrocarbon deposit.

  12. U.S. Natural Gas Supplemental Gas - Propane Air (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40 Buildingto17 34 44Year Jan Feb MarDecade Year-0 Year-1 Year-2 Year-3OtherPropane

  13. Published in Journal de Physique IV, vol 11, pp. Pr3-101 ---Pr3-108 Kinetic modelling of gas-phase decomposition of propane : correlation with pyrocarbon deposition

    E-Print Network [OSTI]

    Boyer, Edmond

    -phase decomposition of propane : correlation with pyrocarbon deposition Cédric Descamps, Gerard L. Vignoles , Olivier : A chemical kinetic model for gas-phase pyrolysis of propane has been set up, partially reduced, and validated the notion of "maturation" from propane to lighter hydrocarbons, then to aromatic compounds and PAHs. The gas

  14. The solubility of elemental sulfur in methane, carbon dioxide and hydrogen sulfide gas

    E-Print Network [OSTI]

    Wieland, Denton R.

    1958-01-01T23:59:59.000Z

    ABSTRACT The object of the work reported In this dissertation was to determine the solubility of sulfur in gaseous methane carbon dioxide, and hydrogen sulfide and in mixtures of these gases, at various pressures and temperatures* Sulfur solubility... of methane and propane (which has a critical pressure of approximately the same value of hydrogen sulfide) is 1500 psia. To have liquid in this system at 1500 psia, however, would require a maximum temperature of 20?F which is well below the minimum...

  15. Catalytic Methane Reduction in the Exhaust Gas of Combustion Engines

    E-Print Network [OSTI]

    Dunin-Borkowski, Rafal E.

    Catalytic Methane Reduction in the Exhaust Gas of Combustion Engines Peter Mauermann1,* , Michael Dornseiffer6 , Frank Amkreutz6 1 Institute for Combustion Engines , RWTH Aachen University, Schinkelstr. 8, D of the hydrocarbon exhaust of internal combustion engines. In contrast to other gaseous hydrocarbons, significant

  16. EIA - Greenhouse Gas Emissions - Methane Emissions

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at1,066,688 760,877 951,322 1,381,127byForms What'sAnnual23. Methane

  17. Dynamics of Propane in Silica Mesopores Formed upon Propylene Hydrogenation over Pt Nanoparticles by Time-Resolved FT-IR Spectroscopy

    E-Print Network [OSTI]

    Waslylenko, Walter; Frei, Heinz

    2008-01-01T23:59:59.000Z

    A steady state distribution of propane between gas andK). A steady state distribution of propane between gas phasesteady state distribution between propane inside and outside

  18. Gettering of hydrogen and methane from a helium gas mixture

    SciTech Connect (OSTI)

    Cárdenas, Rosa Elia, E-mail: recarde1@uiwtx.edu [Department of Physics, The University of the Incarnate Word, 4301 Broadway, San Antonio, Texas 78209 (United States); Stewart, Kenneth D.; Cowgill, Donald F., E-mail: dfcowgi@sandia.gov [Sandia National Laboratories, Hydrogen and Metallurgical Sciences, 7011 East Avenue, Livermore, California 94550 (United States)

    2014-11-01T23:59:59.000Z

    In this study, the authors developed an approach for accurately quantifying the helium content in a gas mixture also containing hydrogen and methane using commercially available getters. The authors performed a systematic study to examine how both H{sub 2} and CH{sub 4} can be removed simultaneously from the mixture using two SAES St 172{sup ®} getters operating at different temperatures. The remaining He within the gas mixture can then be measured directly using a capacitance manometer. The optimum combination involved operating one getter at 650?°C to decompose the methane, and the second at 110?°C to remove the hydrogen. This approach eliminated the need to reactivate the getters between measurements, thereby enabling multiple measurements to be made within a short time interval, with accuracy better than 1%. The authors anticipate that such an approach will be particularly useful for quantifying the He-3 in mixtures that include tritium, tritiated methane, and helium-3. The presence of tritiated methane, generated by tritium activity, often complicates such measurements.

  19. Gas separation with oligomer-modified inorganic membranes

    E-Print Network [OSTI]

    Javaid, Asad

    1999-01-01T23:59:59.000Z

    -based separation are presented. Alumina membranes with average pore sizes near 5 nm and 10 run were treated with various n-alkyl trichlorosilanes. Pure gas permeation studies using nitrogen, methane, and propane were performed to investigate the effects...

  20. Methane hydrate gas production: evaluating and exploiting the solid gas resource

    SciTech Connect (OSTI)

    McGuire, P.L.

    1981-01-01T23:59:59.000Z

    Methane hydrate gas could be a tremendous energy resource if methods can be devised to produce this gas economically. This paper examines two methods of producing gas from hydrate deposits by the injection of hot water or steam, and also examines the feasibility of hydraulic fracturing and pressure reduction as a hydrate gas production technique. A hydraulic fracturing technique suitable for hydrate reservoirs and a system for coring hydrate reservoirs are also described.

  1. Modeling of Oceanic Gas Hydrate Instability and Methane Release in Response to Climate Change

    E-Print Network [OSTI]

    Reagan, Matthew T.

    2008-01-01T23:59:59.000Z

    Potential effects of gas hydrate on human welfare. Proc.W.S. A review of methane and gas hydrates in the dynamic,Geology of Natural Gas Hydrates, M. Max, A.H. Johnson, W.P.

  2. Catalyst for the methanation of carbon monoxide in sour gas

    DOE Patents [OSTI]

    Kustes, William A. (Louisville, KY); Hausberger, Arthur L. (Louisville, KY)

    1985-01-01T23:59:59.000Z

    The invention involves the synergistic effect of the specific catalytic constituents on a specific series of carriers for the methanation of carbon monoxide in the presence of sulfur at relatively high temperatures and at low steam to gas ratios in the range of 0.2:1 or less. This effect was obtained with catalysts comprising the mixed sulfides and oxides of nickel and chromium supported on carriers comprising magnesium aluminate and magnesium silicate. Conversion of carbon monoxide to methane was in the range of from 40 to 80%. Tests of this combination of metal oxides and sulfides on other carriers and tests of other metal oxides and sulfides on the same carrier produced a much lower level of conversion.

  3. Methane-to-Methanol Conversion by Gas-Phase Transition Metal Oxide Cations: Experiment and Theory

    E-Print Network [OSTI]

    Metz, Ricardo B.

    Methane-to-Methanol Conversion by Gas-Phase Transition Metal Oxide Cations: Experiment and Theory-phase transition metal oxide cations can convert methane to methanol. Methane activation by MO+ is discussed such as methanol has attracted great experimental and theoretical interest due to its importance as an industrial

  4. Modeling the climate response to a massive methane release from gas hydrates

    E-Print Network [OSTI]

    Renssen, Hans

    Modeling the climate response to a massive methane release from gas hydrates H. Renssen and C. J release from gas hydrates, Paleoceanography, 19, PA2010, doi:10.1029/2003PA000968. 1. Introduction [2] Catastrophic releases of methane gas from hydrates (clathrates) have been mentioned to be responsible for rapid

  5. Gas Content of Gladys McCall Reservoir Brine A Topical Report

    Office of Scientific and Technical Information (OSTI)

    gas t o brine ratio. This w i l l result i n cubic feet of methane, ethane, propane, etc. per barrel of brine, Then, the contributions from sample points are added until...

  6. Fuels outlook for oil/propane

    SciTech Connect (OSTI)

    Weigand, P.

    1995-09-01T23:59:59.000Z

    The outlook for using oil and propane as fuels is outlined. The following topics are discussed: factors affecting price of the burner tip, supply and demand forecast, distribution costs and availability, alternate fuels economics, propane prices, No. 2 oil prices, natural gas vs. 1% residual HP prices, and future for industrial oil and propane consumers.

  7. TIME-VARYING FLAME IONIZATION SENSING APPLIED TO NATURAL GAS AND PROPANE BLENDS IN A PRESSURIZED LEAN PREMIXED (LPM) COMBUSTOR

    SciTech Connect (OSTI)

    D. L. Straub; B. T. Chorpening; E. D. Huckaby; J. D. Thornton; W. L. Fincham

    2008-06-13T23:59:59.000Z

    In-situ monitoring of combustion phenomena is a critical need for optimal operation and control of advanced gas turbine combustion systems. The concept described in this paper is based on naturally occurring flame ionization processes that accompany the combustion of hydrocarbon fuels. Previous work has shown that flame ionization techniques may be applied to detect flashback, lean blowout, and some aspects of thermo-acoustic combustion instabilities. Previous work has focused on application of DC electric fields. By application of time-varying electric fields, significant improvements to sensor capabilities have been observed. These data have been collected in a lean premixed combustion test rig operating at 0.51-0.76 MPa (5-7.5 atm) with air preheated to 588 K (600°F). Five percent of the total fuel flow is injected through the centerbody tip as a diffusion pilot. The fuel composition is varied independently by blending approximately 5% (volume) propane with the pipeline natural gas. The reference velocity through the premixing annulus is kept constant for all conditions at a nominal value of 70 m/s. The fuel-air equivalence ratio is varied independently from 0.46 – 0.58. Relative to the DC field version, the time-varying combustion control and diagnostic sensor (TV-CCADS) shows a significant improvement in the correlation between the measured flame ionization current and local fuel-air equivalence ratio. In testing with different fuel compositions, the triangle wave data show the most distinct change in flame ionization current in response to an increase in propane content. Continued development of this sensor technology will improve the capability to control advanced gas turbine combustion systems, and help address issues associated with variations in fuel supplies.

  8. LIQUID PROPANE GAS (LPG) STORAGE AREA BOILING LIQUID EXPANDING VAPOR EXPLOSION (BLEVE) ANALYSIS

    SciTech Connect (OSTI)

    PACE, M.E.

    2004-01-13T23:59:59.000Z

    The PHA and the FHAs for the SWOC MDSA (HNF-14741) identified multiple accident scenarios in which vehicles powered by flammable gases (e.g., propane), or combustible or flammable liquids (e.g., gasoline, LPG) are involved in accidents that result in an unconfined vapor cloud explosion (UVCE) or in a boiling liquid expanding vapor explosion (BLEVE), respectively. These accident scenarios are binned in the Bridge document as FIR-9 scenarios. They are postulated to occur in any of the MDSA facilities. The LPG storage area will be in the southeast corner of CWC that is relatively remote from store distaged MAR. The location is approximately 30 feet south of MO-289 and 250 feet east of 2401-W by CWC Gate 10 in a large staging area for unused pallets and equipment.

  9. Atmospheric composition, radiative forcing, and climate change as a consequence of a massive methane release from gas hydrates

    E-Print Network [OSTI]

    methane release from gas hydrates Gavin A. Schmidt and Drew T. Shindell National Aeronautics and Space of methane gas (CH4) from hydrate deposits on the continental slope. We investigate whether reported PETM, and climate change as a consequence of a massive methane release from gas hydrates, Paleoceanography, 18

  10. Efficient gas-separation process to upgrade dilute methane stream for use as fuel

    DOE Patents [OSTI]

    Wijmans, Johannes G. (Menlo Park, CA); Merkel, Timothy C. (Menlo Park, CA); Lin, Haiqing (Mountain View, CA); Thompson, Scott (Brecksville, OH); Daniels, Ramin (San Jose, CA)

    2012-03-06T23:59:59.000Z

    A membrane-based gas separation process for treating gas streams that contain methane in low concentrations. The invention involves flowing the stream to be treated across the feed side of a membrane and flowing a sweep gas stream, usually air, across the permeate side. Carbon dioxide permeates the membrane preferentially and is picked up in the sweep air stream on the permeate side; oxygen permeates in the other direction and is picked up in the methane-containing stream. The resulting residue stream is enriched in methane as well as oxygen and has an EMC value enabling it to be either flared or combusted by mixing with ordinary air.

  11. Combined Steam Reforming and Partial Oxidation of Methane to Synthesis Gas under Electrical Discharge

    E-Print Network [OSTI]

    Mallinson, Richard

    Combined Steam Reforming and Partial Oxidation of Methane to Synthesis Gas under Electrical production from simultaneous steam reforming and partial oxidation of methane using an ac corona discharge production has been steam reforming, shown in reaction 4. It is very useful to use low-cost materials

  12. Estimation of methane flux offshore SW Taiwan and the influence of tectonics on gas hydrate accumulation

    E-Print Network [OSTI]

    Lin, Andrew Tien-Shun

    Estimation of methane flux offshore SW Taiwan and the influence of tectonics on gas hydrate simulating reflectors (BSRs) imply the potential existence of gas hydrates offshore southwestern Taiwan settings in offshore SW Taiwan might strongly control the stability of gas hydrates, and thus affect

  13. Contribution of oceanic gas hydrate dissociation to the formation of Arctic Ocean methane plumes

    SciTech Connect (OSTI)

    Reagan, M.; Moridis, G.; Elliott, S.; Maltrud, M.

    2011-06-01T23:59:59.000Z

    Vast quantities of methane are trapped in oceanic hydrate deposits, and there is concern that a rise in the ocean temperature will induce dissociation of these hydrate accumulations, potentially releasing large amounts of carbon into the atmosphere. Because methane is a powerful greenhouse gas, such a release could have dramatic climatic consequences. The recent discovery of active methane gas venting along the landward limit of the gas hydrate stability zone (GHSZ) on the shallow continental slope (150 m - 400 m) west of Svalbard suggests that this process may already have begun, but the source of the methane has not yet been determined. This study performs 2-D simulations of hydrate dissociation in conditions representative of the Arctic Ocean margin to assess whether such hydrates could contribute to the observed gas release. The results show that shallow, low-saturation hydrate deposits, if subjected to recently observed or future predicted temperature changes at the seafloor, can release quantities of methane at the magnitudes similar to what has been observed, and that the releases will be localized near the landward limit of the GHSZ. Both gradual and rapid warming is simulated, along with a parametric sensitivity analysis, and localized gas release is observed for most of the cases. These results resemble the recently published observations and strongly suggest that hydrate dissociation and methane release as a result of climate change may be a real phenomenon, that it could occur on decadal timescales, and that it already may be occurring.

  14. Dynamics of Propane in Silica Mesopores Formed upon Propylene Hydrogenation over Pt Nanoparticles by Time-Resolved FT-IR Spectroscopy

    E-Print Network [OSTI]

    Waslylenko, Walter; Frei, Heinz

    2008-01-01T23:59:59.000Z

    state distribution of propane between gas and mesopore phaseWavenumber (cm ) B Gas Phase Propane 2968 cm k 1 = 3.1 ± 0.4slices showing the gas phase propane component at 216, 648,

  15. Gas-lift technology applied to dewatering of coalbed methane wells in the black warrior basin

    SciTech Connect (OSTI)

    Johnson, K.J.; Coats, A. (Otis Engineering Corp., Dallas, TX (United States)); Marinello, S.A. (Colorado School of Mines, Golden, CO (United States))

    1992-11-01T23:59:59.000Z

    Coalbed methane (CBM) wells are usually dewatered with sucker rod or progressive cavity pumps to reduce wellbore water levels, although not without problems. This paper describes high-volume artificial-lift technology that incorporates specifically designed gas-lift methods to dewater Black Warrior CBM wells. Gas lift provides improved well maintenance and production optimization by the use of conventional wireline service methods.

  16. Correlation between homogeneous propane pyrolysis and pyrocarbon deposition

    E-Print Network [OSTI]

    Boyer, Edmond

    Correlation between homogeneous propane pyrolysis and pyrocarbon deposition C´edric Descamps, G propane pyrolysis is studied in a 1-D hot-wall CVD furnace. The gas-phase pyrolysis is modelled in previous reports [6]: total pressure equal to 2 kPa, temperature between 900 K and 1400 K, and pure propane

  17. Study of the Low Temperature Oxidation of Propane Maximilien Cord

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Study of the Low Temperature Oxidation of Propane Maximilien Cord , Benoit Husson , Juan of China, Hefei, Anhui 230029, P. R. China Abstract The lowtemperature oxidation of propane oxidation of propane in the gas phase has been the subject of very few experimental studies, mainly

  18. Modeling of Oceanic Gas Hydrate Instability and Methane Release in Response to Climate Change

    SciTech Connect (OSTI)

    Reagan, Matthew; Reagan, Matthew T.; Moridis, George J.

    2008-04-15T23:59:59.000Z

    Paleooceanographic evidence has been used to postulate that methane from oceanic hydrates may have had a significant role in regulating global climate, implicating global oceanic deposits of methane gas hydrate as the main culprit in instances of rapid climate change that have occurred in the past. However, the behavior of contemporary oceanic methane hydrate deposits subjected to rapid temperature changes, like those predicted under future climate change scenarios, is poorly understood. To determine the fate of the carbon stored in these hydrates, we performed simulations of oceanic gas hydrate accumulations subjected to temperature changes at the seafloor and assessed the potential for methane release into the ocean. Our modeling analysis considered the properties of benthic sediments, the saturation and distribution of the hydrates, the ocean depth, the initial seafloor temperature, and for the first time, estimated the effect of benthic biogeochemical activity. The results show that shallow deposits--such as those found in arctic regions or in the Gulf of Mexico--can undergo rapid dissociation and produce significant methane fluxes of 2 to 13 mol/yr/m{sup 2} over a period of decades, and release up to 1,100 mol of methane per m{sup 2} of seafloor in a century. These fluxes may exceed the ability of the seafloor environment (via anaerobic oxidation of methane) to consume the released methane or sequester the carbon. These results will provide a source term to regional or global climate models in order to assess the coupling of gas hydrate deposits to changes in the global climate.

  19. Using Carbon Dioxide to Enhance Recovery of Methane from Gas Hydrate Reservoirs: Final Summary Report

    SciTech Connect (OSTI)

    McGrail, B. Peter; Schaef, Herbert T.; White, Mark D.; Zhu, Tao; Kulkarni, Abhijeet S.; Hunter, Robert B.; Patil, Shirish L.; Owen, Antionette T.; Martin, P F.

    2007-09-01T23:59:59.000Z

    Carbon dioxide sequestration coupled with hydrocarbon resource recovery is often economically attractive. Use of CO2 for enhanced recovery of oil, conventional natural gas, and coal-bed methane are in various stages of common practice. In this report, we discuss a new technique utilizing CO2 for enhanced recovery of an unconventional but potentially very important source of natural gas, gas hydrate. We have focused our attention on the Alaska North Slope where approximately 640 Tcf of natural gas reserves in the form of gas hydrate have been identified. Alaska is also unique in that potential future CO2 sources are nearby, and petroleum infrastructure exists or is being planned that could bring the produced gas to market or for use locally. The EGHR (Enhanced Gas Hydrate Recovery) concept takes advantage of the physical and thermodynamic properties of mixtures in the H2O-CO2 system combined with controlled multiphase flow, heat, and mass transport processes in hydrate-bearing porous media. A chemical-free method is used to deliver a LCO2-Lw microemulsion into the gas hydrate bearing porous medium. The microemulsion is injected at a temperature higher than the stability point of methane hydrate, which upon contacting the methane hydrate decomposes its crystalline lattice and releases the enclathrated gas. Small scale column experiments show injection of the emulsion into a CH4 hydrate rich sand results in the release of CH4 gas and the formation of CO2 hydrate

  20. Study of the Natural Gas Hydrate 'Trap Zone' and the Methane Hydrate Potential in the Sverdrup Basin, Canada

    SciTech Connect (OSTI)

    Majorowicz, J. A. [Northern Geothermal Consult. (Canada)], E-mail: majorowi@show.ca; Hannigan, P. K.; Osadetz, K. G. [Geological Survey of Canada, Calgary (Canada)

    2002-06-15T23:59:59.000Z

    The methane hydrate stability zone beneath Sverdrup Basin has developed to a depth of 2 km underneath the Canadian Arctic Islands and 1 km below sea level under the deepest part of the inter-island sea channels. It is not, however, a continuous zone. Methane hydrates are detected in this zone, but the gas hydrate/free gas contact occurs rarely. Interpretation of well logs indicate that methane hydrate occurs within the methane stability zone in 57 of 150 analyzed wells. Fourteen wells show the methane hydrate/free gas contact. Analysis of the distribution of methane hydrate and hydrate/gas contact occurrences with respect to the present methane hydrate stability zone indicate that, in most instances, the detected methane hydrate occurs well above the base of methane hydrate stability. This relationship suggests that these methane hydrates were formed in shallower strata than expected with respect to the present hydrate stability zone from methane gases which migrated upward into hydrate trap zones. Presently, only a small proportion of gas hydrate occurrences occur in close proximity to the base of predicted methane hydrate stability. The association of the majority of detected hydrates with deeply buried hydrocarbon discoveries, mostly conventional natural gas accumulations, or mapped seismic closures, some of which are dry, located in structures in western and central Sverdrup Basin, indicate the concurring relationship of hydrate occurrence with areas of high heat flow. Either present-day or paleo-high heat flows are relevant. Twenty-three hydrate occurrences coincide directly with underlying conventional hydrocarbon accumulations. Other gas hydrate occurrences are associated with structures filled with water with evidence of precursor hydrocarbons that were lost because of upward leakage.

  1. Analysis and Methane Gas Separations Studies for City of Marsing, Idaho An Idaho National Laboratory Technical Assistance Program Study

    SciTech Connect (OSTI)

    Christopher Orme

    2012-08-01T23:59:59.000Z

    Introduction and Background Large amounts of methane in well water is a wide spread problem in North America. Methane gas from decaying biomass and oil and gas deposits escape into water wells typically through cracks or faults in otherwise non-porous rock strata producing saturated water systems. This methane saturated water can pose several problems in the delivery of drinking water. The problems range from pumps vapor locking (cavitating), to pump houses exploding. The City of Marsing requested Idaho National Laboratory (INL) to assist with some water analyses as well as to provide some engineering approaches to methane capture through the INL Technical Assistance Program (TAP). There are several engineering approaches to the removal of methane and natural gas from water sources that include gas stripping followed by compression and/or dehydration; membrane gas separators coupled with dehydration processes, membrane water contactors with dehydration processes.

  2. AIRBORNE, OPTICAL REMOTE SENSNG OF METHANE AND ETHANE FOR NATURAL GAS PIPELINE LEAK DETECTION

    SciTech Connect (OSTI)

    Jerry Myers

    2005-04-15T23:59:59.000Z

    Ophir Corporation was awarded a contract by the U. S. Department of Energy, National Energy Technology Laboratory under the Project Title ''Airborne, Optical Remote Sensing of Methane and Ethane for Natural Gas Pipeline Leak Detection'' on October 14, 2002. The scope of the work involved designing and developing an airborne, optical remote sensor capable of sensing methane and, if possible, ethane for the detection of natural gas pipeline leaks. Flight testing using a custom dual wavelength, high power fiber amplifier was initiated in February 2005. Ophir successfully demonstrated the airborne system, showing that it was capable of discerning small amounts of methane from a simulated pipeline leak. Leak rates as low as 150 standard cubic feet per hour (scf/h) were detected by the airborne sensor.

  3. Incentives for Methane Mitigation and Energy-Efficiency Improvements in Case of Ukraine’s Natural Gas Transmission System

    SciTech Connect (OSTI)

    Roshchanka, Volha; Evans, Meredydd

    2014-06-01T23:59:59.000Z

    Reducing methane losses is a concern for climate change policy and energy policy. The energy sector is the major source of methane emissions into the atmosphere. Reducing methane emissions and avoiding combustion can be very cost-effective, but various barriers prevent such energy-efficiency measures from taking place. To date, few examples of industry-wide improvements exist. One example of substantial investments into upgrading natural gas transmission system comes from Ukraine. The Ukrainian transmission company, Ukrtransgaz, reduced its own system’s natural gas consumption by 68 percent in 2011 compared to the level in 2005. Evaluating reductions in methane emissions is challenging because of lack of accurate data and gaps in accounting methodologies. At the same time, Ukraine’s transmission system has undergone improvements that, at the very least, have contained methane emissions, if not substantially reduced them. In this paper, we describe recent developments in Ukraine’s natural gas transmission system and analyze the incentives that forced the sector to pay close attention to its methane losses. Ukraine is one of most energy-intensive countries, among the largest natural gas consumers in the world, and a significant emitter of methane. The country is also dependent on imports of natural gas. A combination of steep increases in the price of imported natural gas, and comprehensive domestic environmental and energy policies, regional integration policy, and international environmental agreements has created conditions for successful methane emission and combustion reductions. Learning about such case studies can help us design better policies elsewhere.

  4. Methane contamination of drinking water accompanying gas-well drilling and

    E-Print Network [OSTI]

    Methane contamination of drinking water accompanying gas-well drilling and hydraulic fracturing (received for review January 13, 2011) Directional drilling and hydraulic-fracturing technologies are dra use (1­5). Directional drilling and hydrau- lic-fracturing technologies are allowing expanded natural

  5. Methane contamination of drinking water accompanying gas-well drilling and

    E-Print Network [OSTI]

    Jackson, Robert B.

    Methane contamination of drinking water accompanying gas-well drilling and hydraulic fracturing (received for review January 13, 2011) Directional drilling and hydraulic-fracturing technologies are dra of energy use (1­5). Directional drilling and hydrau- lic-fracturing technologies are allowing expanded

  6. GAS METHANE HYDRATES-RESEARCH STATUS, ANNOTATED BIBLIOGRAPHY, AND ENERGY IMPLICATIONS

    SciTech Connect (OSTI)

    James Sorensen; Jaroslav Solc; Bethany Bolles

    2000-07-01T23:59:59.000Z

    The objective of this task as originally conceived was to compile an assessment of methane hydrate deposits in Alaska from available sources and to make a very preliminary evaluation of the technical and economic feasibility of producing methane from these deposits for remote power generation. Gas hydrates have recently become a target of increased scientific investigation both from the standpoint of their resource potential to the natural gas and oil industries and of their positive and negative implications for the global environment After we performed an extensive literature review and consulted with representatives of the U.S. Geological Survey (USGS), Canadian Geological Survey, and several oil companies, it became evident that, at the current stage of gas hydrate research, the available information on methane hydrates in Alaska does not provide sufficient grounds for reaching conclusions concerning their use for energy production. Hence, the original goals of this task could not be met, and the focus was changed to the compilation and review of published documents to serve as a baseline for possible future research at the Energy & Environmental Research Center (EERC). An extensive annotated bibliography of gas hydrate publications has been completed. The EERC will reassess its future research opportunities on methane hydrates to determine where significant initial contributions could be made within the scope of limited available resources.

  7. Propane on Titan

    E-Print Network [OSTI]

    H. G. Roe; T. K. Greathouse; M. J. Richter; J. H. Lacy

    2003-09-23T23:59:59.000Z

    We present the first observations of propane (C$_3$H$_8$) on Titan that unambiguously resolve propane features from other numerous stratospheric emissions. This is accomplished using a $R=\\lambda/\\delta\\lambda\\approx10^5$ spectrometer (TEXES) to observe propane's $\

  8. Geology, reservoir engineering and methane hydrate potential of the Walakpa Gas Field, North Slope, Alaska

    SciTech Connect (OSTI)

    Glenn, R.K.; Allen, W.W.

    1992-12-01T23:59:59.000Z

    The Walakpa Gas Field, located near the city of Barrow on Alaska's North Slope, has been proven to be methane-bearing at depths of 2000--2550 feet below sea level. The producing formation is a laterally continuous, south-dipping, Lower Cretaceous shelf sandstone. The updip extent of the reservoir has not been determined by drilling, but probably extends to at least 1900 feet below sea level. Reservoir temperatures in the updip portion of the reservoir may be low enough to allow the presence of in situ methane hydrates. Reservoir net pay however, decreases to the north. Depths to the base of permafrost in the area average 940 feet. Drilling techniques and production configuration in the Walakpa field were designed to minimize formation damage to the reservoir sandstone and to eliminate methane hydrates formed during production. Drilling development of the Walakpa field was a sequential updip and lateral stepout from a previously drilled, structurally lower confirmation well. Reservoir temperature, pressure, and gas chemistry data from the development wells confirm that they have been drilled in the free-methane portion of the reservoir. Future studies in the Walakpa field are planned to determine whether or not a component of the methane production is due to the dissociation of updip in situ hydrates.

  9. UNDERSTANDING METHANE EMISSIONS SOURCES AND VIABLE MITIGATION MEASURES IN THE NATURAL GAS TRANSMISSION SYSTEMS: RUSSIAN AND U.S. EXPERIENCE

    SciTech Connect (OSTI)

    Ishkov, A.; Akopova, Gretta; Evans, Meredydd; Yulkin, Grigory; Roshchanka, Volha; Waltzer, Suzie; Romanov, K.; Picard, David; Stepanenko, O.; Neretin, D.

    2011-10-01T23:59:59.000Z

    This article will compare the natural gas transmission systems in the U.S. and Russia and review experience with methane mitigation technologies in the two countries. Russia and the United States (U.S.) are the world's largest consumers and producers of natural gas, and consequently, have some of the largest natural gas infrastructure. This paper compares the natural gas transmission systems in Russia and the U.S., their methane emissions and experiences in implementing methane mitigation technologies. Given the scale of the two systems, many international oil and natural gas companies have expressed interest in better understanding the methane emission volumes and trends as well as the methane mitigation options. This paper compares the two transmission systems and documents experiences in Russia and the U.S. in implementing technologies and programs for methane mitigation. The systems are inherently different. For instance, while the U.S. natural gas transmission system is represented by many companies, which operate pipelines with various characteristics, in Russia predominately one company, Gazprom, operates the gas transmission system. However, companies in both countries found that reducing methane emissions can be feasible and profitable. Examples of technologies in use include replacing wet seals with dry seals, implementing Directed Inspection and Maintenance (DI&M) programs, performing pipeline pump-down, applying composite wrap for non-leaking pipeline defects and installing low-bleed pneumatics. The research methodology for this paper involved a review of information on methane emissions trends and mitigation measures, analytical and statistical data collection; accumulation and analysis of operational data on compressor seals and other emission sources; and analysis of technologies used in both countries to mitigate methane emissions in the transmission sector. Operators of natural gas transmission systems have many options to reduce natural gas losses. Depending on the value of gas, simple, low-cost measures, such as adjusting leaking equipment components, or larger-scale measures, such as installing dry seals on compressors, can be applied.

  10. Syngas Production from Propane Using Atmospheric Non-thermal Plasma

    E-Print Network [OSTI]

    Ouni, Fakhreddine; Cormier, Jean Marie; 10.1007/s11090-009-9166-2

    2009-01-01T23:59:59.000Z

    Propane steam reforming using a sliding discharge reactor was investigated under atmospheric pressure and low temperature (420 K). Non-thermal plasma steam reforming proceeded efficiently and hydrogen was formed as a main product (H2 concentration up to 50%). By-products (C2-hydrocarbons, methane, carbon dioxide) were measured with concentrations lower than 6%. The mean electrical power injected in the discharge is less than 2 kW. The process efficiency is described in terms of propane conversion rate, steam reforming and cracking selectivity, as well as by-products production. Chemical processes modelling based on classical thermodynamic equilibrium reactor is also proposed. Calculated data fit quiet well experimental results and indicate that the improvement of C3H8 conversion and then H2 production can be achieved by increasing the gas fraction through the discharge. By improving the reactor design, the non-thermal plasma has a potential for being an effective way for supplying hydrogen or synthesis gas.

  11. Nationwide: Southeast Propane Autogas Development Program Brings...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Southeast Propane Autogas Development Program Brings 1200 Propane Vehicles to the Road Nationwide: Southeast Propane Autogas Development Program Brings 1200 Propane Vehicles to the...

  12. New Natural Gas Storage and Transportation Capabilities Utilizing Rapid Methane Hydrate Formation Techniques

    SciTech Connect (OSTI)

    Brown, T.D.; Taylor, C.E.; Bernardo, M.

    2010-01-01T23:59:59.000Z

    Natural gas (methane as the major component) is a vital fossil fuel for the United States and around the world. One of the problems with some of this natural gas is that it is in remote areas where there is little or no local use for the gas. Nearly 50 percent worldwide natural gas reserves of ~6,254.4 trillion ft3 (tcf) is considered as stranded gas, with 36 percent or ~86 tcf of the U.S natural gas reserves totaling ~239 tcf, as stranded gas [1] [2]. The worldwide total does not include the new estimates by U.S. Geological Survey of 1,669 tcf of natural gas north of the Arctic Circle, [3] and the U.S. ~200,000 tcf of natural gas or methane hydrates, most of which are stranded gas reserves. Domestically and globally there is a need for newer and more economic storage, transportation and processing capabilities to deliver the natural gas to markets. In order to bring this resource to market, one of several expensive methods must be used: 1. Construction and operation of a natural gas pipeline 2. Construction of a storage and compression facility to compress the natural gas (CNG) at 3,000 to 3,600 psi, increasing its energy density to a point where it is more economical to ship, or 3. Construction of a cryogenic liquefaction facility to produce LNG, (requiring cryogenic temperatures at <-161 °C) and construction of a cryogenic receiving port. Each of these options for the transport requires large capital investment along with elaborate safety systems. The Department of Energy's Office of Research and Development Laboratories at the National Energy Technology Laboratory (NETL) is investigating new and novel approaches for rapid and continuous formation and production of synthetic NGHs. These synthetic hydrates can store up to 164 times their volume in gas while being maintained at 1 atmosphere and between -10 to -20°C for several weeks. Owing to these properties, new process for the economic storage and transportation of these synthetic hydrates could be envisioned for stranded gas reserves. The recent experiments and their results from the testing within NETL's 15-Liter Hydrate Cell Facility exhibit promising results. Introduction of water at the desired temperature and pressure through an NETL designed nozzle into a temperature controlled methane environment within the 15-Liter Hydrate Cell allowed for instantaneous formation of methane hydrates. The instantaneous and continuous hydrate formation process was repeated over several days while varying the flow rate of water, its' temperature, and the overall temperature of the methane environment. These results clearly indicated that hydrates formed immediately after the methane and water left the nozzle at temperatures above the freezing point of water throughout the range of operating conditions. [1] Oil and Gas Journal Vol. 160.48, Dec 22, 2008. [2] http://www.eia.doe.gov/oiaf/servicerpt/natgas/chapter3.html and http://www.eia.doe.gov/oiaf/servicerpt/natgas/pdf/tbl7.pdf [3] U.S. Geological Survey, “Circum-Arctic Resource Appraisal: Estimates of Undiscovered Oil and Gas North of the Arctic Circle,” May 2008.

  13. Methane Gas Utilization Project from Landfill at Ellery (NY)

    SciTech Connect (OSTI)

    Pantelis K. Panteli

    2012-01-10T23:59:59.000Z

    Landfill Gas to Electric Energy Generation and Transmission at Chautauqua County Landfill, Town of Ellery, New York. The goal of this project was to create a practical method with which the energy, of the landfill gas produced by the decomposing waste at the Chautauqua County Landfill, could be utilized. This goal was accomplished with the construction of a landfill gas to electric energy plant (originally 6.4MW and now 9.6MW) and the construction of an inter-connection power-line, from the power-plant to the nearest (5.5 miles) power-grid point.

  14. Methane mass balance at three landfill sites: What is the efficiency of capture by gas collection systems?

    SciTech Connect (OSTI)

    Spokas, K. [University of Minnesota, Department of Soil, Water, and Climate, St. Paul, MN (United States)]. E-mail: spokas@morris.ars.usda.gov; Bogner, J. [Landfills Inc., Wheaton, Illinois and University of Illinois, Chicago, IL (United States); Chanton, J.P. [Florida State University, Department of Oceanography, Tallahassee, FL (United States); Morcet, M. [Centre de Recherches pour l'Environnement l'Energie et le Dechet (CReeD), Veolia Environnement, Limay (France); Aran, C. [Centre de Recherches pour l'Environnement l'Energie et le Dechet (CReeD), Veolia Environnement, Limay (France); Graff, C. [University of Minnesota, Department of Soil, Water, and Climate, St. Paul, MN (United States); Golvan, Y. Moreau-Le [COLLEX Pty Ltd., CReeD, Veolia Environnement, Pyrmont NSW (Australia); Hebe, I. [Agence de l'Environnement et de la Maitrise de l'Energie (ADEME), French Agency for the Environment and Energy Management, Angers (France)

    2006-07-01T23:59:59.000Z

    Many developed countries have targeted landfill methane recovery among greenhouse gas mitigation strategies, since methane is the second most important greenhouse gas after carbon dioxide. Major questions remain with respect to actual methane production rates in field settings and the relative mass of methane that is recovered, emitted, oxidized by methanotrophic bacteria, laterally migrated, or temporarily stored within the landfill volume. This paper presents the results of extensive field campaigns at three landfill sites to elucidate the total methane balance and provide field measurements to quantify these pathways. We assessed the overall methane mass balance in field cells with a variety of designs, cover materials, and gas management strategies. Sites included different cell configurations, including temporary clay cover, final clay cover, geosynthetic clay liners, and geomembrane composite covers, and cells with and without gas collection systems. Methane emission rates ranged from -2.2 to >10,000 mg CH{sub 4} m{sup -2} d{sup -1}. Total methane oxidation rates ranged from 4% to 50% of the methane flux through the cover at sites with positive emissions. Oxidation of atmospheric methane was occurring in vegetated soils above a geomembrane. The results of these studies were used as the basis for guidelines by the French environment agency (ADEME) for default values for percent recovery: 35% for an operating cell with an active landfill gas (LFG) recovery system, 65% for a temporary covered cell with an active LFG recovery system, 85% for a cell with clay final cover and active LFG recovery, and 90% for a cell with a geomembrane final cover and active LFG recovery.

  15. Assessment of environmental health and safety issues associated with the commercialization of unconventional gas recovery: methane from coal seams

    SciTech Connect (OSTI)

    Ethridge, L.J.; Cowan, C.E.; Riedel, E.F.

    1980-07-01T23:59:59.000Z

    Potential public health and safety problems and the potential environmental impacts from the recovery of gas from coalbeds are identified and examined. The technology of methane recovery is described and economic and legal barriers to production are discussed. (ACR)

  16. Petrophysical Characterization and Reservoir Simulator for Methane Gas Production from Gulf of Mexico Hydrates

    SciTech Connect (OSTI)

    Kishore Mohanty; Bill Cook; Mustafa Hakimuddin; Ramanan Pitchumani; Damiola Ogunlana; Jon Burger; John Shillinglaw

    2006-06-30T23:59:59.000Z

    Gas hydrates are crystalline, ice-like compounds of gas and water molecules that are formed under certain thermodynamic conditions. Hydrate deposits occur naturally within ocean sediments just below the sea floor at temperatures and pressures existing below about 500 meters water depth. Gas hydrate is also stable in conjunction with the permafrost in the Arctic. Most marine gas hydrate is formed of microbially generated gas. It binds huge amounts of methane into the sediments. Estimates of the amounts of methane sequestered in gas hydrates worldwide are speculative and range from about 100,000 to 270,000,000 trillion cubic feet (modified from Kvenvolden, 1993). Gas hydrate is one of the fossil fuel resources that is yet untapped, but may play a major role in meeting the energy challenge of this century. In this project novel techniques were developed to form and dissociate methane hydrates in porous media, to measure acoustic properties and CT properties during hydrate dissociation in the presence of a porous medium. Hydrate depressurization experiments in cores were simulated with the use of TOUGHFx/HYDRATE simulator. Input/output software was developed to simulate variable pressure boundary condition and improve the ease of use of the simulator. A series of simulations needed to be run to mimic the variable pressure condition at the production well. The experiments can be matched qualitatively by the hydrate simulator. The temperature of the core falls during hydrate dissociation; the temperature drop is higher if the fluid withdrawal rate is higher. The pressure and temperature gradients are small within the core. The sodium iodide concentration affects the dissociation pressure and rate. This procedure and data will be useful in designing future hydrate studies.

  17. All-optical remote monitoring of propane gas using a 5-km-long, low-loss optical fiber link and an InGaP light-emitting diode in the 1. 68-. mu. m region

    SciTech Connect (OSTI)

    Chan, K.; Ito, H.; Inaba, H.

    1984-08-01T23:59:59.000Z

    We report the fully optical remote detection of low-level propane (C/sub 3/H/sub 8/) gas realized by the scheme based on a long distance, very low-loss silica optical fiber link connected to a compact absorption cell in conjunction with a high radiant InGaP light-emitting diode at 1.68 ..mu..m. For this application, the near-infrared absorption spectrum of propane was measured and studied to find very complicated bands around 1.69, 1.53, and 1.38 ..mu..m. This simple system, employing a 5-km-long silica optical fiber link, was demonstrated to be capable of achieving reproducibly the detection sensitivity less than 2.4 Torr for propane gas in air, i.e., about 14% of the lower explosion limit of propane density. This result verifies a large capability for major applications to various strategic points within the environment, such as industrial complexes as well as urban and residential areas, with considerably increased reliability and safety over the existing techniques.

  18. Methanation assembly using multiple reactors

    DOE Patents [OSTI]

    Jahnke, Fred C.; Parab, Sanjay C.

    2007-07-24T23:59:59.000Z

    A methanation assembly for use with a water supply and a gas supply containing gas to be methanated in which a reactor assembly has a plurality of methanation reactors each for methanating gas input to the assembly and a gas delivery and cooling assembly adapted to deliver gas from the gas supply to each of said methanation reactors and to combine water from the water supply with the output of each methanation reactor being conveyed to a next methanation reactor and carry the mixture to such next methanation reactor.

  19. Process for producing methane from gas streams containing carbon monoxide and hydrogen

    DOE Patents [OSTI]

    Frost, Albert C. (Congers, NY)

    1980-01-01T23:59:59.000Z

    Carbon monoxide-containing gas streams are passed over a catalyst capable of catalyzing the disproportionation of carbon monoxide so as to deposit a surface layer of active surface carbon on the catalyst essentially without formation of inactive coke thereon. The surface layer is contacted with steam and is thus converted to methane and CO.sub.2, from which a relatively pure methane product may be obtained. While carbon monoxide-containing gas streams having hydrogen or water present therein can be used only the carbon monoxide available after reaction with said hydrogen or water is decomposed to form said active surface carbon. Although hydrogen or water will be converted, partially or completely, to methane that can be utilized in a combustion zone to generate heat for steam production or other energy recovery purposes, said hydrogen is selectively removed from a CO--H.sub.2 -containing feed stream by partial oxidation thereof prior to disproportionation of the CO content of said stream.

  20. Production of natural gas from methane hydrate by a constant downhole pressure well

    SciTech Connect (OSTI)

    Ahmadi, G. (Clarkson Univ., Potsdam, NY); Ji, C. (Clarkson Univ., Potsdam, NY); Smith, D.H.

    2007-07-01T23:59:59.000Z

    Natural gas production from the dissociation of methane hydrate in a confined reservoir by a depressurizing downhole well was studied. The case that the well pressure was kept constant was treated, and two different linearization schemes in an axisymmetric configuration were used in the analysis. For different fixed well pressures and reservoir temperatures, approximate self similar solutions were obtained. Distributions of temperature, pressure and gas velocity field across the reservoir were evaluated. The distance of the decomposition front from the well and the natural gas production rate as functions of time were also computed. Time evolutions of the resulting profiles were presented in graphical forms, and their differences with the constant well output results were studied. It was shown that the gas production rate was a sensitive function of well pressure and reservoir temperature. The sensitivity of the results to the linearization scheme used was also studied.

  1. Final Scientific/Technical Report. A closed path methane and water vapor gas analyzer

    SciTech Connect (OSTI)

    Liukang, Xu; Dayle, McDermitt; Tyler, Anderson; Brad, Riensche; Anatoly, Komissarov; Julie, Howe

    2012-05-01T23:59:59.000Z

    Robust, economical, low-power and reliable closed-path methane (CH4), carbon dioxide (CO2), and water vapor (H2O) analyzers suitable for long-term measurements are not readily available commercially. Such analyzers are essential for quantifying the amount of CH4 and CO2 released from various ecosystems (wetlands, rice paddies, forests, etc.) and other surface contexts (e.g. landfills, animal husbandry lots, etc.), and for understanding the dynamics of the atmospheric CH4 and CO2 budget and their impact on climate change and global warming. The purpose of this project is to develop a closed-path methane, carbon dioxide gas and water vapor analyzer capable of long-term measurements in remote areas for global climate change and environmental research. The analyzer will be capable of being deployed over a wide range of ecosystems to understand methane and carbon dioxide exchange between the atmosphere and the surface. Measurements of methane and carbon dioxide exchange need to be made all year-round with limited maintenance requirements. During this Phase II effort, we successfully completed the design of the electronics, optical bench, trace gas detection method and mechanical infrastructure. We are using the technologies of two vertical cavity surface emitting lasers, a multiple-pass Herriott optical cell, wavelength modulation spectroscopy and direct absorption to measure methane, carbon dioxide, and water vapor. We also have designed the instrument application software, Field Programmable Gate Array (FPGA), along with partial completion of the embedded software. The optical bench has been tested in a lab setting with very good results. Major sources of optical noise have been identified and through design, the optical noise floor is approaching -60dB. Both laser modules can be temperature controlled to help maximize the stability of the analyzer. Additionally, a piezo electric transducer has been utilized to randomize the noise introduced from potential etalons. It is expected that all original specifications contained within the initial proposal will be met. We are currently in the beginning stages of assembling the first generation prototypes and finalizing the remaining design elements. The first prototypes will initially be tested in our environmental calibration chamber in which specific gas concentrations, temperature and humidity levels can be controlled. Once operation in this controlled setting is verified, the prototypes will be deployed at LI-COR�¢����s Experimental Research Station (LERS). Deployment at the LERS site will test the instrument�¢����s robustness in a real-world situation.

  2. DOE THREE-DIMENSIONAL STRUCTURE AND PHYSICAL PROPERTIES OF A METHANE HYDRATE DEPOSIT AND GAS RESERVOIR, BLAKE RIDGE

    SciTech Connect (OSTI)

    W. Steven Holbrook

    2004-11-11T23:59:59.000Z

    This report contains a summary of work conducted and results produced under the auspices of award DE-FC26-00NT40921, ''DOE Three-Dimensional Structure and Physical Properties of a Methane Hydrate Deposit and Gas Reservoir, Blake Ridge.'' This award supported acquisition, processing, and interpretation of two- and three-dimensional seismic reflection data over a large methane hydrate reservoir on the Blake Ridge, offshore South Carolina. The work supported by this project has led to important new conclusions regarding (1) the use of seismic reflection data to directly detect methane hydrate, (2) the migration and possible escape of free gas through the hydrate stability zone, and (3) the mechanical controls on the maximum thickness of the free gas zone and gas escape.

  3. Coal-bed methane - An unconventional but viable source of natural gas

    SciTech Connect (OSTI)

    Hallinger, D.E. (Southern California Gas Co., Los Angeles (United States))

    1991-02-01T23:59:59.000Z

    As of December 31, 1988, the potential Gas Committee, a group of industry experts, estimates that the remaining undiscovered potential supplies of natural gas amounted to 795.6 trillion cubic feet (TCF) in the United States, including the offshore areas. Besides the conventional sources, the sandstone and carbonate reservoirs that geologists have been looking for since Drake, there are a number of unconventional sources of natural gas. One of these, coal-bed methane (CBM) is being actively developed today and promises to provide significant additions to the proved reserves of this nation in the next ten years. The potential supplies of CBM are variously estimates to be between 400 to 1,000 tcf, or equal to the remaining undiscovered conventional supplies of natural gas. If these estimates are real, they will have a profound effect on forecasts of future prices and availability of natural gas. How valid are these estimates At what rate will this new source of natural gas come on stream The answers to these questions are dependent in part upon the uniqueness of the coal reservoir. Coal can contain more natural gas than a comparable size conventional reservoir. A coal reservoir exhibits positive production decline instead of the negative decline of conventional reservoirs. There are legal and economic considerations that will affect the development of this relatively new and exciting source of natural gas. All of these questions are discussed by the author.

  4. AIRBORNE, OPTICAL REMOTE SENSING OF METHANE AND ETHANE FOR NATURAL GAS PIPELINE LEAK DETECTION

    SciTech Connect (OSTI)

    Jerry Myers

    2003-05-13T23:59:59.000Z

    Ophir Corporation was awarded a contract by the U. S. Department of Energy, National Energy Technology Laboratory under the Project Title ''Airborne, Optical Remote Sensing of Methane and Ethane for Natural Gas Pipeline Leak Detection'' on October 14, 2002. This six-month technical report summarizes the progress for each of the proposed tasks, discusses project concerns, and outlines near-term goals. Ophir has completed a data survey of two major natural gas pipeline companies on the design requirements for an airborne, optical remote sensor. The results of this survey are disclosed in this report. A substantial amount of time was spent on modeling the expected optical signal at the receiver at different absorption wavelengths, and determining the impact of noise sources such as solar background, signal shot noise, and electronic noise on methane and ethane gas detection. Based upon the signal to noise modeling and industry input, Ophir finalized the design requirements for the airborne sensor, and released the critical sensor light source design requirements to qualified vendors. Responses from the vendors indicated that the light source was not commercially available, and will require a research and development effort to produce. Three vendors have responded positively with proposed design solutions. Ophir has decided to conduct short path optical laboratory experiments to verify the existence of methane and absorption at the specified wavelength, prior to proceeding with the light source selection. Techniques to eliminate common mode noise were also evaluated during the laboratory tests. Finally, Ophir has included a summary of the potential concerns for project success and has established future goals.

  5. AIRBORNE, OPTICAL REMOTE SENSING OF METHANE AND ETHANE FOR NATURAL GAS PIPLINE LEAK DETECTION

    SciTech Connect (OSTI)

    Jerry Myers

    2004-05-12T23:59:59.000Z

    Ophir Corporation was awarded a contract by the U. S. Department of Energy, National Energy Technology Laboratory under the Project Title ''Airborne, Optical Remote Sensing of Methane and Ethane for Natural Gas Pipeline Leak Detection'' on October 14, 2002. The third six-month technical report contains a summary of the progress made towards finalizing the design and assembling the airborne, remote methane and ethane sensor. The vendor has been chosen and is on contract to develop the light source with the appropriate linewidth and spectral shape to best utilize the Ophir gas correlation software. Ophir has expanded upon the target reflectance testing begun in the previous performance period by replacing the experimental receiving optics with the proposed airborne large aperture telescope, which is theoretically capable of capturing many times more signal return. The data gathered from these tests has shown the importance of optimizing the fiber optic receiving fiber to the receiving optic and has helped Ophir to optimize the design of the gas cells and narrowband optical filters. Finally, Ophir will discuss remaining project issues that may impact the success of the project.

  6. AIRBORNE, OPTICAL REMOTE SENSING OF METHANE AND ETHANE FOR NATURAL GAS PIPELINE LEAK DETECTION

    SciTech Connect (OSTI)

    Jerry Myers

    2003-11-12T23:59:59.000Z

    Ophir Corporation was awarded a contract by the U. S. Department of Energy, National Energy Technology Laboratory under the Project Title ''Airborne, Optical Remote Sensing of Methane and Ethane for Natural Gas Pipeline Leak Detection'' on October 14, 2002. This second six-month technical report summarizes the progress made towards defining, designing, and developing the hardware and software segments of the airborne, optical remote methane and ethane sensor. The most challenging task to date has been to identify a vendor capable of designing and developing a light source with the appropriate output wavelength and power. This report will document the work that has been done to identify design requirements, and potential vendors for the light source. Significant progress has also been made in characterizing the amount of light return available from a remote target at various distances from the light source. A great deal of time has been spent conducting laboratory and long-optical path target reflectance measurements. This is important since it helps to establish the overall optical output requirements for the sensor. It also reduces the relative uncertainty and risk associated with developing a custom light source. The data gathered from the optical path testing has been translated to the airborne transceiver design in such areas as: fiber coupling, optical detector selection, gas filters, and software analysis. Ophir will next, summarize the design progress of the transceiver hardware and software development. Finally, Ophir will discuss remaining project issues that may impact the success of the project.

  7. Propane Vehicle Demonstration Grant Program

    SciTech Connect (OSTI)

    Jack Mallinger

    2004-08-27T23:59:59.000Z

    Project Description: Propane Vehicle Demonstration Grants The Propane Vehicle Demonstration Grants was established to demonstrate the benefits of new propane equipment. The US Department of Energy, the Propane Education & Research Council (PERC) and the Propane Vehicle Council (PVC) partnered in this program. The project impacted ten different states, 179 vehicles, and 15 new propane fueling facilities. Based on estimates provided, this project generated a minimum of 1,441,000 new gallons of propane sold for the vehicle market annually. Additionally, two new off-road engines were brought to the market. Projects originally funded under this project were the City of Portland, Colorado, Kansas City, Impco Technologies, Jasper Engines, Maricopa County, New Jersey State, Port of Houston, Salt Lake City Newspaper, Suburban Propane, Mutual Liquid Propane and Ted Johnson.

  8. Geology, reservoir engineering and methane hydrate potential of the Walakpa Gas Field, North Slope, Alaska. Final report

    SciTech Connect (OSTI)

    Glenn, R.K.; Allen, W.W.

    1992-12-01T23:59:59.000Z

    The Walakpa Gas Field, located near the city of Barrow on Alaska`s North Slope, has been proven to be methane-bearing at depths of 2000--2550 feet below sea level. The producing formation is a laterally continuous, south-dipping, Lower Cretaceous shelf sandstone. The updip extent of the reservoir has not been determined by drilling, but probably extends to at least 1900 feet below sea level. Reservoir temperatures in the updip portion of the reservoir may be low enough to allow the presence of in situ methane hydrates. Reservoir net pay however, decreases to the north. Depths to the base of permafrost in the area average 940 feet. Drilling techniques and production configuration in the Walakpa field were designed to minimize formation damage to the reservoir sandstone and to eliminate methane hydrates formed during production. Drilling development of the Walakpa field was a sequential updip and lateral stepout from a previously drilled, structurally lower confirmation well. Reservoir temperature, pressure, and gas chemistry data from the development wells confirm that they have been drilled in the free-methane portion of the reservoir. Future studies in the Walakpa field are planned to determine whether or not a component of the methane production is due to the dissociation of updip in situ hydrates.

  9. Sorption-Enhanced Synthetic Natural Gas (SNG) Production from Syngas: A Novel Process Combining CO Methanation, Water-Gas Shift, and CO2 Capture

    SciTech Connect (OSTI)

    Lebarbier, Vanessa MC; Dagle, Robert A.; Kovarik, Libor; Albrecht, Karl O.; Li, Xiaohong S.; Li, Liyu; Taylor, Charles E.; Bao, Xinhe; Wang, Yong

    2014-01-01T23:59:59.000Z

    Synthetic natural gas (SNG) production from syngas is under investigation again due to the desire for less dependency from imports and the opportunity for increasing coal utilization and reducing green house gas emission. CO methanation is highly exothermic and substantial heat is liberated which can lead to process thermal imbalance and deactivation of the catalyst. As a result, conversion per pass is limited and substantial syngas recycle is employed in conventional processes. Furthermore, the conversion of syngas to SNG is typically performed at moderate temperatures (275 to 325°C) to ensure high CH4 yields since this reaction is thermodynamically limited. In this study, the effectiveness of a novel integrated process for the SNG production from syngas at high temperature (i.e. 600?C) was investigated. This integrated process consists of combining a CO methanation nickel-based catalyst with a high temperature CO2 capture sorbent in a single reactor. Integration with CO2 separation eliminates the reverse-water-gas shift and the requirement for a separate water-gas shift (WGS) unit. Easing of thermodynamic constraint offers the opportunity of enhancing yield to CH4 at higher operating temperature (500-700ºC) which also favors methanation kinetics and improves the overall process efficiency due to exploitation of reaction heat at higher temperatures. Furthermore, simultaneous CO2 capture eliminates green house gas emission. In this work, sorption-enhanced CO methanation was demonstrated using a mixture of a 68% CaO/32% MgAl2O4 sorbent and a CO methanation catalyst (Ni/Al2O3, Ni/MgAl2O4, or Ni/SiC) utilizing a syngas ratio (H2/CO) of 1, gas-hour-space velocity (GHSV) of 22 000 hr-1, pressure of 1 bar and a temperature of 600oC. These conditions resulted in ~90% yield to methane, which was maintained until the sorbent became saturated with CO2. By contrast, without the use of sorbent, equilibrium yield to methane is only 22%. Cyclic stability of the methanation catalyst and durability of the sorbent were also studied in the multiple carbonation-decarbonation cycle studies proving the potential of this integrated process in a practical application.

  10. Solid-State Gas Sensors:A Review A. M. Azad, S. A. Akbar,* S. G. Mhaisalkar,~ L. D. Birkefeld,** and K. S. Gotob

    E-Print Network [OSTI]

    Azad, Abdul-Majeed

    to briefly outline some of the environmental concerns. LP gas can form explosive mixture with ambient air and development. The application of these sensors range from air-to-fuel ratio control in combustion processes include: 02, H2, CO, CO2, NOx, SO=, propane, methane, ethanol, and so on. The semiconductor-based chemical

  11. Synthesis Gas Production from Partial Oxidation of Methane with Air in AC Electric Gas Discharge

    E-Print Network [OSTI]

    Mallinson, Richard

    depending on the ratio of hydrogen to carbon monoxide. Most synthesis gas is produced by the steam reform reaction. Industrially, steam reforming is performed over a Ni/ Al2O3 catalyst.9 The typical problem

  12. U.S. Natural Gas System Methane Emissions: State of Knowledge from LCAs, Inventories, and Atmospheric Measurements (Presentation)

    SciTech Connect (OSTI)

    Heath, G.

    2014-04-01T23:59:59.000Z

    Natural gas (NG) is a potential "bridge fuel" during transition to a decarbonized energy system: It emits less carbon dioxide during combustion than other fossil fuels and can be used in many industries. However, because of the high global warming potential of methane (CH4, the major component of NG), climate benefits from NG use depend on system leakage rates. Some recent estimates of leakage have challenged the benefits of switching from coal to NG, a large near-term greenhouse gas (GHG) reduction opportunity. During this presentation, Garvin will review evidence from multiple perspectives - life cycle assessments (LCAs), inventories and measurements - about NG leakage in the US. Particular attention will be paid to a recent article in Science magazine which reviewed over 20 years of published measurements to better understand what we know about total methane emissions and those from the oil and gas sectors. Scientific and policy implications of the state of knowledge will be discussed.

  13. Terr. Atmos. Ocean. Sci., Vol. 17, No. 4, 933-950, December 2006 Methane Venting in Gas Hydrate Potential Area Offshore of SW

    E-Print Network [OSTI]

    Lin, Andrew Tien-Shun

    933 Terr. Atmos. Ocean. Sci., Vol. 17, No. 4, 933-950, December 2006 Methane Venting in Gas Hydrate-mail: tyyang@ntu.edu.tw Water column samples were collected systematically in several poten- tial gas hydrate are considered to have originated from dissociation of gas hydrates and/or a deeper gas reservoir. (Key words

  14. Pennsylvania Farmland and Forest Land Assessment Act of 1974- Utilization of Land or Conveyance of Rights for Exploration or Extraction of Gas, Oil or Coal Bed Methane

    Broader source: Energy.gov [DOE]

    This act prescribes the procedure utilization of land or conveyance of rights for exploration or extraction of gas, oil or coal bed methane in agricultural and forest reserve areas.

  15. Quantifying methane oxidation in a landfill-cover soil by gas push-pull tests

    SciTech Connect (OSTI)

    Gomez, K.E. [Institute of Biogeochemistry and Pollutant Dynamics, ETH Zuerich, Universitaetstrasse 16, 8092 Zuerich (Switzerland)], E-mail: gomezke@hotmail.com; Gonzalez-Gil, G.; Lazzaro, A. [Institute of Biogeochemistry and Pollutant Dynamics, ETH Zuerich, Universitaetstrasse 16, 8092 Zuerich (Switzerland); Schroth, M.H. [Institute of Biogeochemistry and Pollutant Dynamics, ETH Zuerich, Universitaetstrasse 16, 8092 Zuerich (Switzerland)], E-mail: martin.schroth@env.ethz.ch

    2009-09-15T23:59:59.000Z

    Methane (CH{sub 4}) oxidation by aerobic methanotrophs in landfill-cover soils decreases emissions of landfill-produced CH{sub 4} to the atmosphere. To quantify in situ rates of CH{sub 4} oxidation we performed five gas push-pull tests (GPPTs) at each of two locations in the cover soil of the Lindenstock landfill (Liestal, Switzerland) over a 4 week period. GPPTs consist of the injection of a gas mixture containing CH{sub 4}, O{sub 2} and noble gas tracers followed by extraction from the same location. Quantification of first-order rate constants was based upon comparison of breakthrough curves of CH{sub 4} with either Ar or CH{sub 4} itself from a subsequent inactive GPPT containing acetylene as an inhibitor of CH{sub 4} oxidation. The maximum calculated first-order rate constant was 24.8 {+-} 0.8 h{sup -1} at location 1 and 18.9 {+-} 0.6 h{sup -1} at location 2. In general, location 2 had higher background CH{sub 4} concentrations in vertical profile samples than location 1. High background CH{sub 4} concentrations in the cover soil during some experiments adversely affected GPPT breakthrough curves and data interpretation. Real-time PCR verified the presence of a large population of methanotrophs at the two GPPT locations and comparison of stable carbon isotope fractionation of CH{sub 4} in an active GPPT and a subsequent inactive GPPT confirmed that microbial activity was responsible for the CH{sub 4} oxidation. The GPPT was shown to be a useful tool to reproducibly estimate in situ rates of CH{sub 4} oxidation in a landfill-cover soil when background CH{sub 4} concentrations were low.

  16. The catalytic oxidation of propane 

    E-Print Network [OSTI]

    Sanderson, Charles Frederick

    1949-01-01T23:59:59.000Z

    THE CATALYTIC OXIDATION OP PROPANE A Thesis By Charles Frederick Sandersont * * June 1949 Approval as to style and content recommended: Head of the Department of Chemical Engineering THE CATALYTICi OXIDATTON OF PROPANE A Thesis By Charles... Frederick ;Sandersonit * June 1949 THE CATALYTIC OXIDATION OP PROPANE A Thesis Submitted to the Faculty of the Agricultural and Mechanical College of Texas in Partial Fulfillment of the Requirements for the Degree of Doctor of Philosophy Major...

  17. The catalytic oxidation of propane

    E-Print Network [OSTI]

    Sanderson, Charles Frederick

    1949-01-01T23:59:59.000Z

    THE CATALYTIC OXIDATION OP PROPANE A Thesis By Charles Frederick Sandersont * * June 1949 Approval as to style and content recommended: Head of the Department of Chemical Engineering THE CATALYTICi OXIDATTON OF PROPANE A Thesis By Charles... Frederick ;Sandersonit * June 1949 THE CATALYTIC OXIDATION OP PROPANE A Thesis Submitted to the Faculty of the Agricultural and Mechanical College of Texas in Partial Fulfillment of the Requirements for the Degree of Doctor of Philosophy Major...

  18. Cracking of simulated oil refinery off-gas over a coal char, petroleum coke, and quartz

    SciTech Connect (OSTI)

    Yuan Zhang; Jin-hu Wu; Dong-ke Zhang [Chinese Academy of Sciences, Taiyuan (China). Institute of Coal Chemistry

    2008-03-15T23:59:59.000Z

    The cracking of oil refinery off-gas, simulated with a gas mixture containing methane (51%), ethylene (21.4%), ethane (21.1%), and propane (6.5%), over a coal char, petroleum coke, and quartz, respectively, has been studied in a fixed bed reactor. The experiments were performed at temperatures between 850 and 1000{sup o}C and at atmospheric pressure. The results show that the conversions of all species considered increased with increasing temperature. Ethane and propane completely decomposed over all three bed materials in the temperature range investigated. However, the higher initial conversion rates of methane and ethylene cracking at all temperatures were observed only over the coal char and not on the petroleum coke and quartz, indicating a significant catalytic effect of the coal char on methane and ethylene cracking. Methane and ethylene conversions decreased with reaction time due to deactivation of the coal char by carbon deposition on the char surface and, in the later stage of a cracking experiment, became negative, suggesting that methane and ethylene had been formed during the cracking of ethane and propane. 16 refs., 13 figs., 2 tabs.

  19. Clean Fuel Advanced Technology Public Education Campaign: Billboards According to the U.S. Department of Energy's July 2013 alternative fuel price report, the price of propane

    E-Print Network [OSTI]

    .S. Department of Energy's July 2013 alternative fuel price report, the price of propane (LPG) in North Carolina at least $1,000 in yearly fuel costs by driving on natural gas or propane. · According to the U

  20. Residential propane price increases

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropane price05, 2014propane

  1. Residential propane prices available

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropane price05,propane prices

  2. Residential propane prices decreases

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropane price05,propane prices5, 2014

  3. Residential propane prices increase

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropane price05,propane prices5,

  4. Residential propane prices increase

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropane price05,propane

  5. 2013 Propane Market Outlook

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less isNFebruary 2004AugustApril 20133 Audit2013 NUFOPlasma Propane

  6. Drilling and Production Testing the Methane Hydrate Resource Potential Associated with the Barrow Gas Fields

    SciTech Connect (OSTI)

    Steve McRae; Thomas Walsh; Michael Dunn; Michael Cook

    2010-02-22T23:59:59.000Z

    In November of 2008, the Department of Energy (DOE) and the North Slope Borough (NSB) committed funding to develop a drilling plan to test the presence of hydrates in the producing formation of at least one of the Barrow Gas Fields, and to develop a production surveillance plan to monitor the behavior of hydrates as dissociation occurs. This drilling and surveillance plan was supported by earlier studies in Phase 1 of the project, including hydrate stability zone modeling, material balance modeling, and full-field history-matched reservoir simulation, all of which support the presence of methane hydrate in association with the Barrow Gas Fields. This Phase 2 of the project, conducted over the past twelve months focused on selecting an optimal location for a hydrate test well; design of a logistics, drilling, completion and testing plan; and estimating costs for the activities. As originally proposed, the project was anticipated to benefit from industry activity in northwest Alaska, with opportunities to share equipment, personnel, services and mobilization and demobilization costs with one of the then-active exploration operators. The activity level dropped off, and this benefit evaporated, although plans for drilling of development wells in the BGF's matured, offering significant synergies and cost savings over a remote stand-alone drilling project. An optimal well location was chosen at the East Barrow No.18 well pad, and a vertical pilot/monitoring well and horizontal production test/surveillance well were engineered for drilling from this location. Both wells were designed with Distributed Temperature Survey (DTS) apparatus for monitoring of the hydrate-free gas interface. Once project scope was developed, a procurement process was implemented to engage the necessary service and equipment providers, and finalize project cost estimates. Based on cost proposals from vendors, total project estimated cost is $17.88 million dollars, inclusive of design work, permitting, barging, ice road/pad construction, drilling, completion, tie-in, long-term production testing and surveillance, data analysis and technology transfer. The PRA project team and North Slope have recommended moving forward to the execution phase of this project.

  7. Investigation of methane adsorption and its effect on gas transport in shale matrix through microscale and mesoscale simulations

    E-Print Network [OSTI]

    Li, ZhongZhen; Chen, Li; Kangd, Qinjun; He, Ya-Ling; Tao, Wen-Quan

    2015-01-01T23:59:59.000Z

    Methane adsorption and its effect on fluid flow in shale matrix are investigated through multi-scale simulation scheme by using molecular dynamics (MD) and lattice Boltzmann (LB) methods. Equilibrium MD simulations are conducted to study methane adsorption on the organic and inorganic walls of nanopores in shale matrix with different pore sizes and pressures. Density and pressure distributions within the adsorbed layer and the free gas region are discussed. The illumination of the MD results on larger scale LB simulations is presented. Pressure-dependent thickness of adsorbed layer should be adopted and the transport of adsorbed layer should be properly considered in LB simulations. LB simulations, which are based on a generalized Navier-Stokes equation for flow through low-permeability porous media with slippage, are conducted by taking into consideration the effects of adsorbed layer. It is found that competitive effects of slippage and adsorbed layer exist on the permeability of shale matrix, leading to di...

  8. Synthesis gas production with an adjustable H{sub 2}/CO ratio through the coal gasification process: effects of coal ranks and methane addition

    SciTech Connect (OSTI)

    Yan Cao; Zhengyang Gao; Jing Jin; Hongchang Zhou; Marten Cohron; Houying Zhao; Hongying Liu; Weiping Pan [Western Kentucky University (WKU), Bowling Green, KY (United States). Institute for Combustion Science and Environmental Technology (ICSET)

    2008-05-15T23:59:59.000Z

    Direct production of synthesis gas using coal as a cheap feedstock is attractive but challenging due to its low H{sub 2}/CO ratio of generated synthesis gas. Three typical U.S. coals of different ranks were tested in a 2.5 in. coal gasifier to investigate their gasification reactivity and adjustability on H{sub 2}/CO ratio of generated synthesis gas with or without the addition of methane. Tests indicated that lower-rank coals (lignite and sub-bituminous) have higher gasification reactivity than bituminous coals. The coal gasification reactivity is correlated to its synthesis-gas yield and the total percentage of H{sub 2} and CO in the synthesis gas, but not to the H{sub 2}/CO ratio. The H{sub 2}/CO ratio of coal gasification was found to be correlated to the rank of coals, especially the H/C ratio of coals. Methane addition into the dense phase of the pyrolysis and gasification zone of the cogasification reactor could make the best use of methane in adjusting the H{sub 2}/CO ratio of the generated synthesis gas. The maximum methane conversion efficiency, which was likely correlated to its gasification reactivity, could be achieved by 70% on average for all tested coals. The actual catalytic effect of generated coal chars on methane conversion seemed coal-dependent. The coal-gasification process benefits from methane addition and subsequent conversion on the adjustment of the H{sub 2}/CO ratio of synthesis gas. The methane conversion process benefits from the use of coal chars due to their catalytic effects. This implies that there were likely synergistic effects on both. 25 refs., 3 figs., 3

  9. Sulfur resistance of Group VIII transition metal promoted nickel catalysts for synthesis gas methanation 

    E-Print Network [OSTI]

    Hamlin, Kellee Hall

    1986-01-01T23:59:59.000Z

    and support. Finally a special thanks to my parents for their love and support throughout. TABLE OF CONTENTS CHAPTER I INTRODUCTION II LITERATURE REVIEW III APPARATUS AND PROCEDURE . Page Feed System Temperature Control and Heating Tubular Reactor...Os . . 44 CHAPTER I INTRODUCTION Methanation has been used for many years to remove traces of CO and COr from hydrogen rich gases such as those used for ammonia synthesis. Recent interest is primarily in the methanation of CO as the final step...

  10. Titan's Prolific Propane: The Cassini CIRS Perspective

    E-Print Network [OSTI]

    Nixon, C A; Flaud, J -M; Bezard, B; Teanby, N A; Irwin, P G J; Ansty, T M; Coustenis, A; Vinatier, S; Flasar, F M; 10.1016/j.pss.2009.06.021

    2009-01-01T23:59:59.000Z

    In this paper we select large spectral averages of data from the Cassini Composite Infrared Spectrometer (CIRS) obtained in limb-viewing mode at low latitudes (30S--30N), greatly increasing the path length and hence signal-to-noise ratio for optically thin trace species such as propane. By modeling and subtracting the emissions of other gas species, we demonstrate that at least six infrared bands of propane are detected by CIRS, including two not previously identified in Titan spectra. Using a new line list for the range 1300-1400cm -1, along with an existing GEISA list, we retrieve propane abundances from two bands at 748 and 1376 cm-1. At 748 cm-1 we retrieve 4.2 +/- 0.5 x 10(-7) (1-sigma error) at 2 mbar, in good agreement with previous studies, although lack of hotbands in the present spectral atlas remains a problem. We also determine 5.7 +/- 0.8 x 10(-7) at 2 mbar from the 1376 cm-1 band - a value that is probably affected by systematic errors including continuum gradients due to haze and also an imperf...

  11. Coalbed Methane Procduced Water Treatment Using Gas Hydrate Formation at the Wellhead

    SciTech Connect (OSTI)

    BC Technologies

    2009-12-30T23:59:59.000Z

    Water associated with coalbed methane (CBM) production is a significant and costly process waste stream, and economic treatment and/or disposal of this water is often the key to successful and profitable CBM development. In the past decade, advances have been made in the treatment of CBM produced water. However, produced water generally must be transported in some fashion to a centralized treatment and/or disposal facility. The cost of transporting this water, whether through the development of a water distribution system or by truck, is often greater than the cost of treatment or disposal. To address this economic issue, BC Technologies (BCT), in collaboration with Oak Ridge National Laboratory (ORNL) and International Petroleum Environmental Consortium (IPEC), proposed developing a mechanical unit that could be used to treat CBM produced water by forming gas hydrates at the wellhead. This process involves creating a gas hydrate, washing it and then disassociating hydrate into water and gas molecules. The application of this technology results in three process streams: purified water, brine, and gas. The purified water can be discharged or reused for a variety of beneficial purposes and the smaller brine can be disposed of using conventional strategies. The overall objectives of this research are to develop a new treatment method for produced water where it could be purified directly at the wellhead, to determine the effectiveness of hydrate formation for the treatment of produced water with proof of concept laboratory experiments, to design a prototype-scale injector and test it in the laboratory under realistic wellhead conditions, and to demonstrate the technology under field conditions. By treating the water on-site, producers could substantially reduce their surface handling costs and economically remove impurities to a quality that would support beneficial use. Batch bench-scale experiments of the hydrate formation process and research conducted at ORNL confirmed the feasibility of the process. However, researchers at BCT were unable to develop equipment suitable for continuous operation and demonstration of the process in the field was not attempted. The significant achievements of the research area: Bench-scale batch results using carbon dioxide indicate >40% of the feed water to the hydrate formation reactor was converted to hydrate in a single pass; The batch results also indicate >23% of the feed water to the hydrate formation reactor (>50% of the hydrate formed) was converted to purified water of a quality suitable for discharge; Continuous discharge and collection of hydrates was achieved at atmospheric pressure. Continuous hydrate formation and collection at atmospheric conditions was the most significant achievement and preliminary economics indicate that if the unit could be made operable, it is potentially economic. However, the inability to continuously separate the hydrate melt fraction left the concept not ready for field demonstration and the project was terminated after Phase Two research.

  12. Direct production of hydrogen and aromatics from methane or natural gas: Review of recent U.S. patents

    SciTech Connect (OSTI)

    Lucia M. Petkovic; Daniel M. Ginosar

    2012-03-01T23:59:59.000Z

    Since the year 2000, the United States Patent and Trademark Office (USPTO) has granted a dozen patents for inventions related to methane dehydroaromatization processes. One of them was granted to UOP LLC (Des Plaines). It relates to a catalyst composition and preparation method. Two patents were granted to Conoco Phillips Company (Houston, TX). One was aimed at securing a process and operating conditions for methane aromatization. The other was aimed at securing a process that may be integrated with separation of wellhead fluids and blending of the aromatics produced from the gas with the crude. Nine patents were granted to ExxonMobil Chemical Patents Inc. (Houston, TX). Most of these were aimed at securing a dehydroaromatization process where methane-containing feedstock moves counter currently to a particulate catalyst. The coked catalyst is heated or regenerated either in the reactor, by cyclic operation, or in annex equipment, and returned to the reactor. The reactor effluent stream may be separated in its main components and used or recycled as needed. A brief summary of those inventions is presented in this review.

  13. Natural Gas Ethanol Flex-Fuel

    E-Print Network [OSTI]

    Natural Gas Propane Electric Ethanol Flex-Fuel Biodiesel Vehicle Buyer's Guide Clean Cities 2012 . . . . . . . . . . . . . . . . . . . . . . . . 4 About This Guide . . . . . . . . . . . . . . . . . . . 5 Compressed Natural Gas and emissions. Alternative fueling infrastructure is expanding in many regions, making natural gas, propane

  14. Reduction of Non-CO2 Gas Emissions Through The In Situ Bioconversion of Methane

    SciTech Connect (OSTI)

    Scott, A R; Mukhopadhyay, B; Balin, D F

    2012-09-06T23:59:59.000Z

    The primary objectives of this research were to seek previously unidentified anaerobic methanotrophs and other microorganisms to be collected from methane seeps associated with coal outcrops. Subsurface application of these microbes into anaerobic environments has the potential to reduce methane seepage along coal outcrop belts and in coal mines, thereby preventing hazardous explosions. Depending upon the types and characteristics of the methanotrophs identified, it may be possible to apply the microbes to other sources of methane emissions, which include landfills, rice cultivation, and industrial sources where methane can accumulate under buildings. Finally, the microbes collected and identified during this research also had the potential for useful applications in the chemical industry, as well as in a variety of microbial processes. Sample collection focused on the South Fork of Texas Creek located approximately 15 miles east of Durango, Colorado. The creek is located near the subsurface contact between the coal-bearing Fruitland Formation and the underlying Pictured Cliffs Sandstone. The methane seeps occur within the creek and in areas adjacent to the creek where faulting may allow fluids and gases to migrate to the surface. These seeps appear to have been there prior to coalbed methane development as extensive microbial soils have developed. Our investigations screened more than 500 enrichments but were unable to convince us that anaerobic methane oxidation (AMO) was occurring and that anaerobic methanotrophs may not have been present in the samples collected. In all cases, visual and microscopic observations noted that the early stage enrichments contained viable microbial cells. However, as the levels of the readily substrates that were present in the environmental samples were progressively lowered through serial transfers, the numbers of cells in the enrichments sharply dropped and were eliminated. While the results were disappointing we acknowledge that anaerobic methane oxidizing (AOM) microorganisms are predominantly found in marine habitats and grow poorly under most laboratory conditions. One path for future research would be to use a small rotary rig to collect samples from deeper soil horizons, possibly adjacent to the coal-bearing horizons that may be more anaerobic.

  15. Ethane enrichment and propane depletion in subsurface gases indicate gas hydrate occurrence in marine sediments at southern Hydrate Ridge offshore Oregon

    SciTech Connect (OSTI)

    Milkov, Alexei V.; Claypool, G E.; Lee, Young-Joo; Torres, Marta E.; Borowski, W S.; Tomaru, H; Sassen, Roger; Long, Philip E.

    2004-07-02T23:59:59.000Z

    The recognition of finely disseminated gas hydrate in deep marine sediments heavily depends on various indirect techniques because this mineral quickly decomposes upon recovery from in situ pressure and temperature conditions. Here, we discuss molecular properties of closely spaced gas voids (formed as a result of core recovery) and gas hydrates from an area of relatively low gas flux at the flanks of the southern Hydrate Ridge Offshore Oregon (ODP Sites 1244, 1245 and 1247).

  16. Contribution of oceanic gas hydrate dissociation to the formation of Arctic Ocean methane plumes

    E-Print Network [OSTI]

    Reagan, M.

    2012-01-01T23:59:59.000Z

    V.A. Soloviev, Submarine Gas Hydrates. St. Petersburg, 1998.and stability of gas hydrate-related bottom-simulatingPotential effects of gas hydrate on human welfare, Proc.

  17. IMPROVEMENT OF METHANE STORAGE IN ACTIVATED CARBON USING METHANE HYDRATE

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    it to a gas hydrate formation. In fact, the gas hydrate formation in the remaining free porosity after manuscript, published in "Fifth International Conference on Gas Hydrates (ICGH 5),, Tromdheim : Norway (2005IMPROVEMENT OF METHANE STORAGE IN ACTIVATED CARBON USING METHANE HYDRATE M.L. Zanota(1) , L. Perier

  18. Sulfur resistance of Group VIII transition metal promoted nickel catalysts for synthesis gas methanation

    E-Print Network [OSTI]

    Hamlin, Kellee Hall

    1986-01-01T23:59:59.000Z

    their resistance to deactivation by Hxg. The nickel and promoters were adsorbed on the catalyst by a simple precipitation technique. To investigate catalyst activity and deactivation experimentally, a fixed bed tubular reactor was operated at atmospheric... AND PROCEDURE To investigate catalyst activity and deactivation experimentally, a fixed bed tubular reactor wae constructed for the synthesis gss methanation studies. The reactor system and supporting equipment are shown schematically in Figure 1, while...

  19. Liquid Propane Injection Technology Conductive to Today's North...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technology Conductive to Today's North American Specification Liquid Propane Injection Technology Conductive to Today's North American Specification Liquid propane injection...

  20. ACTION CONCENTRATION FOR MIXTURES OF VOLATILE ORGANIC COMPOUNDS (VOC) & METHANE & HYDROGEN

    SciTech Connect (OSTI)

    MARUSICH, R.M.

    2006-07-10T23:59:59.000Z

    Waste containers may contain volatile organic compounds (VOCs), methane, hydrogen and possibly propane. These constituents may occur individually or in mixtures. Determining if a waste container contains a flammable concentration of flammable gases and vapors (from VOCs) is important to the safety of the handling, repackaging and shipping activities. This report provides the basis for determining the flammability of mixtures of flammable gases and vapors. The concentration of a mixture that is at the lowest flammability limit for that mixture is called the action concentration. The action concentration can be determined using total VOC concentrations or actual concentration of each individual VOC. The concentrations of hydrogen and methane are included with the total VOC or individual VOC concentration to determine the action concentration. Concentrations below this point are not flammable. Waste containers with gas/vapor concentrations at or above the action concentration are considered flammable.

  1. Propane - A Mid-Heating Season Assessment

    Reports and Publications (EIA)

    2001-01-01T23:59:59.000Z

    This report will analyze some of the factors leading up to the rapid increase in propane demand and subsequent deterioration in supply that propelled propane prices to record high levels during December and early January.

  2. Costs Associated With Propane Vehicle Fueling Infrastructure

    SciTech Connect (OSTI)

    Smith, M.; Gonzales, J.

    2014-08-01T23:59:59.000Z

    This document is designed to help fleets understand the cost factors associated with propane vehicle fueling infrastructure. It provides an overview of the equipment and processes necessary to develop a propane fueling station and offers estimated cost ranges.

  3. A method for measuring methane oxidation rates using low levels of 14C-labeled methane and accelerator mass spectrometry

    E-Print Network [OSTI]

    2011-01-01T23:59:59.000Z

    oxidation of methane above gas hydrates at Hydrate Ridge, NEsediment from a marine gas hydrate area. Environ. Microbiol.

  4. 1, 2341, 2001 OH + propane and

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 1, 23­41, 2001 OH + propane and iodopropanes S. A. Carl and J. N. Crowley Title Page Abstract + propane and iodopropanes S. A. Carl and J. N. Crowley Title Page Abstract Introduction Conclusions #12;ACPD 1, 23­41, 2001 OH + propane and iodopropanes S. A. Carl and J. N. Crowley Title Page Abstract

  5. Methane/nitrogen separation process

    DOE Patents [OSTI]

    Baker, R.W.; Lokhandwala, K.A.; Pinnau, I.; Segelke, S.

    1997-09-23T23:59:59.000Z

    A membrane separation process is described for treating a gas stream containing methane and nitrogen, for example, natural gas. The separation process works by preferentially permeating methane and rejecting nitrogen. The authors have found that the process is able to meet natural gas pipeline specifications for nitrogen, with acceptably small methane loss, so long as the membrane can exhibit a methane/nitrogen selectivity of about 4, 5 or more. This selectivity can be achieved with some rubbery and super-glassy membranes at low temperatures. The process can also be used for separating ethylene from nitrogen. 11 figs.

  6. Methane/nitrogen separation process

    DOE Patents [OSTI]

    Baker, Richard W. (Palo Alto, CA); Lokhandwala, Kaaeid A. (Menlo Park, CA); Pinnau, Ingo (Palo Alto, CA); Segelke, Scott (Mountain View, CA)

    1997-01-01T23:59:59.000Z

    A membrane separation process for treating a gas stream containing methane and nitrogen, for example, natural gas. The separation process works by preferentially permeating methane and rejecting nitrogen. We have found that the process is able to meet natural gas pipeline specifications for nitrogen, with acceptably small methane loss, so long as the membrane can exhibit a methane/nitrogen selectivity of about 4, 5 or more. This selectivity can be achieved with some rubbery and super-glassy membranes at low temperatures. The process can also be used for separating ethylene from nitrogen.

  7. Clean Cities ozone air quality attainment and maintenance strategies that employ alternative fuel vehicles, with special emphasis on natural gas and propane

    SciTech Connect (OSTI)

    Santini, D.J.; Saricks, C.L.

    1998-08-04T23:59:59.000Z

    Air quality administrators across the nation are coming under greater pressure to find new strategies for further reducing automotive generated non-methane hydrocarbon (NMHC) and nitrogen oxide (NOx) emissions. The US Environmental Protection Agency (EPA) has established stringent emission reduction requirements for ozone non-attainment areas that have driven the vehicle industry to engineer vehicles meeting dramatically tightened standards. This paper describes an interim method for including alternative-fueled vehicles (AFVs) in the mix of strategies to achieve local and regional improvements in ozone air quality. This method could be used until EPA can develop the Mobile series of emissions estimation models to include AFVs and until such time that detailed work on AFV emissions totals by air quality planners and emissions inventory builders is warranted. The paper first describes the challenges confronting almost every effort to include AFVs in targeted emissions reduction programs, but points out that within these challenges resides an opportunity. Next, it discusses some basic relationships in the formation of ambient ozone from precursor emissions. It then describes several of the salient provisions of EPA`s new voluntary emissions initiative, which is called the Voluntary Mobile Source Emissions Reduction Program (VMEP). Recent emissions test data comparing gaseous-fuel light-duty AFVs with their gasoline-fueled counterparts is examined to estimate percent emissions reductions achievable with CNG and LPG vehicles. Examples of calculated MOBILE5b emission rates that would be used for summer ozone season planning purposes by an individual Air Quality Control Region (AQCR) are provided. A method is suggested for employing these data to compute appropriate voluntary emission reduction credits where such (lighter) AFVs would be acquired. It also points out, but does not quantify, the substantial reduction credits potentially achievable by substituting gaseous-fueled for gasoline-fueled heavy-duty vehicles. Finally, it raises and expands on the relevance of AFVs and their deployment to some other provisions embedded in EPA`s current guidance for implementing 1-hour NAAQS--standards which currently remain in effect--as tools to provide immediate reductions in ozone, without waiting for promised future clean technologies.

  8. Methane productivity and nutrient recovery from manure Henrik B. Mller

    E-Print Network [OSTI]

    Methane productivity and nutrient recovery from manure Henrik B. Møller Danish Institute This thesis, entitled "Methane productivity and nutrient recovery from manure" is presented in partial of digested and separated products.................... 13 3. Methane productivity and greenhouse gas emissions

  9. Propane Market Model documentation report

    SciTech Connect (OSTI)

    Not Available

    1993-12-01T23:59:59.000Z

    The purpose of this report is to define the objectives of the Propane Market Model (PMM), describe its basic approach, and to provide details on model functions. This report is intended as a reference document for model analysts, users, and the general public. Documentation of the model is in accordance with EIA`s legal obligation to provide adequate documentation in support of its models. The PMM performs a short-term (6- to 9-months) forecast of demand and price for consumer-grad propane in the national US market; it also calculates the end-of-month stock level during the term of the forecast. Another part of the model allows for short-term demand forecasts for certain individual Petroleum Administration for Defense (PAD) districts. The model is used to analyze market behavior assumptions or shocks and to determine the effect on market price, demand, and stock level.

  10. Assessing the Efficacy of the Aerobic Methanotrophic Biofilter in Methane Hydrate Environments

    SciTech Connect (OSTI)

    Valentine, David

    2012-09-30T23:59:59.000Z

    In October 2008 the University of California at Santa Barbara (UCSB) initiated investigations of water column methane oxidation in methane hydrate environments, through a project funded by the National Energy Technology Laboratory (NETL) entitled: assessing the efficacy of the aerobic methanotrophic biofilter in methane hydrate environments. This Final Report describes the scientific advances and discoveries made under this award as well as the importance of these discoveries in the broader context of the research area. Benthic microbial mats inhabit the sea floor in areas where reduced chemicals such as sulfide reach the more oxidizing water that overlies the sediment. We set out to investigate the role that methanotrophs play in such mats at locations where methane reaches the sea floor along with sulfide. Mats were sampled from several seep environments and multiple sets were grown in-situ at a hydrocarbon seep in the Santa Barbara Basin. Mats grown in-situ were returned to the laboratory and used to perform stable isotope probing experiments in which they were treated with 13C-enriched methane. The microbial community was analyzed, demonstrating that three or more microbial groups became enriched in methane?s carbon: methanotrophs that presumably utilize methane directly, methylotrophs that presumably consume methanol excreted by the methanotrophs, and sulfide oxidizers that presumably consume carbon dioxide released by the methanotrophs and methylotrophs. Methanotrophs reached high relative abundance in mats grown on methane, but other bacterial processes include sulfide oxidation appeared to dominate mats, indicating that methanotrophy is not a dominant process in sustaining these benthic mats, but rather a secondary function modulated by methane availability. Methane that escapes the sediment in the deep ocean typically dissolved into the overlying water where it is available to methanotrophic bacteria. We set out to better understand the efficacy of this process as a biofilter by studying the distribution of methane oxidation and disposition of methanotrophic populations in the Pacific Ocean. We investigated several environments including the basins offshore California, the continental margin off Central America, and the shallow waters around gas seeps. We succeeded in identifying the distributions of activity in these environments, identified potential physical and chemical controls on methanotrophic activity, we further revealed details about the methanotrophic communities active in these settings, and we developed new approaches to study methanotrophic communities. These findings should improve our capacity to predict the methanotrophic response in ocean waters, and further our ability to generate specific hypotheses as to the ecology and efficacy of pelagic methanotrophic communites. The discharge of methane and other hydrocarbons to Gulf of Mexico that followed the sinking of the Deepwater Horizon provided a unique opportunity to study the methanotorphic biofilter in the deep ocean environment. We set out to understand the consumption of methane and the bloom of methanotrophs resulting from this event, as a window into the regional scale release of gas hydrate under rapid warming scenarios. We found that other hydrocarbon gases, notably propane and ethane, were preferred for consumption over methane, but that methane consumption accelerated rapidly and drove the depletion of methane within a matter of months after initial release. These results revealed the identity of the responsible community, and point to the importance of the seed population in determining the rate at which a methanotrophic community is able to respond to an input of methane. Collectively, these results provide a significant advance in our understanding of the marine methanotrohic biofilter, and further provide direction and context for future investigations of this important phenomenon. This project has resulted in fourteen publications to date, with five more circulating in draft form, and several others planned.

  11. Russian Policy on Methane Emissions in the Oil and Gas Sector: A Case Study in Opportunities and Challenges in Reducing Short-Lived Forcers

    SciTech Connect (OSTI)

    Evans, Meredydd; Roshchanka, Volha

    2014-08-04T23:59:59.000Z

    This paper uses Russian policy in the oil and gas sector as a case study in assessing options and challenges for scaling-up emission reductions. We examine the challenges to achieving large-scale emission reductions, successes that companies have achieved to date, how Russia has sought to influence methane emissions through its environmental fine system, and options for helping companies achieve large-scale emission reductions in the future through simpler and clearer incentives.

  12. A multi-phase, micro-dispersion reactor for the continuous production of methane gas hydrate

    SciTech Connect (OSTI)

    Taboada Serrano, Patricia L [ORNL; Ulrich, Shannon M [ORNL; Szymcek, Phillip [ORNL; McCallum, Scott [Oak Ridge Associated Universities (ORAU); Phelps, Tommy Joe [ORNL; Palumbo, Anthony Vito [ORNL; Tsouris, Costas [ORNL

    2009-01-01T23:59:59.000Z

    A continuous-jet hydrate reactor originally developed to generate a CO2 hydrate stream has been modified to continuously produce CH4 hydrate. The reactor has been tested in the Seafloor Process Simulator (SPS), a 72-L pressure vessel available at Oak Ridge National Laboratory. During experiments, the reactor was submerged in water inside the SPS and received water from the surrounding through a submersible pump and CH4 externally through a gas booster pump. Thermodynamic conditions in the hydrate stability regime were employed in the experiments. The reactor produced a continuous stream of CH4 hydrate, and based on pressure values and amount of gas injected, the conversion of gas to hydrate was estimated. A conversion of up to 70% was achieved using this reactor.

  13. Natural Gas Infrastructure R&D and Methane Emissions Mitigation Workshop

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directed offOCHCO2:Introduction toManagement ofConverDyn NOPRNancyNationalNatural GasImports by Natural Gas

  14. Natural Gas Infrastructure R&D and Methane Emissions Mitigation Workshop

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directed offOCHCO2:Introduction toManagement ofConverDyn NOPRNancyNationalNatural GasImports by Natural Gas

  15. Silane-propane ignitor/burner

    DOE Patents [OSTI]

    Hill, Richard W. (Livermore, CA); Skinner, Dewey F. (Livermore, CA); Thorsness, Charles B. (Livermore, CA)

    1985-01-01T23:59:59.000Z

    A silane propane burner for an underground coal gasification process which is used to ignite the coal and to controllably retract the injection point by cutting the injection pipe. A narrow tube with a burner tip is positioned in the injection pipe through which an oxidant (oxygen or air) is flowed. A charge of silane followed by a supply of fuel, such as propane, is flowed through the tube. The silane spontaneously ignites on contact with oxygen and burns the propane fuel.

  16. Silane-propane ignitor/burner

    DOE Patents [OSTI]

    Hill, R.W.; Skinner, D.F. Jr.; Thorsness, C.B.

    1983-05-26T23:59:59.000Z

    A silane propane burner for an underground coal gasification process which is used to ignite the coal and to controllably retract the injection point by cutting the injection pipe. A narrow tube with a burner tip is positioned in the injection pipe through which an oxidant (oxygen or air) is flowed. A charge of silane followed by a supply of fuel, such as propane, is flowed through the tube. The silane spontaneously ignites on contact with oxygen and burns the propane fuel.

  17. Comparison of Hydrogen and Propane Fuels (Brochure)

    SciTech Connect (OSTI)

    Not Available

    2008-10-01T23:59:59.000Z

    Factsheet comparing the chemical, physical, and thermal properties of hydrogen and propane, designed to facilitate an understanding of the differences and similarites of the two fuels

  18. Comparison of Hydrogen and Propane Fuels (Brochure)

    SciTech Connect (OSTI)

    Not Available

    2009-04-01T23:59:59.000Z

    Factsheet comparing the chemical, physical, and thermal properties of hydrogen and propane, designed to facilitate an understanding of the differences and similarites of the two fuels.

  19. Natural Gas Infrastructure R&D and Methane Emissions Mitigation Workshop

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directed offOCHCO2:Introduction toManagement ofConverDyn NOPRNancyNationalNatural GasImports by Natural

  20. Natural Gas Infrastructure R&D and Methane Emissions Mitigation Workshop

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directed offOCHCO2:Introduction toManagement ofConverDyn NOPRNancyNationalNatural GasImports by Natural

  1. Natural Gas Infrastructure R&D and Methane Mitigation Woekshop Nov. 12-13, 2014

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directed offOCHCO2:Introduction toManagement ofConverDyn NOPRNancyNationalNatural GasImports by Natural

  2. Residential propane price decreases slightly

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropane price05, 2014propane price

  3. Heating Oil and Propane Update - Energy Information Administration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Petroleum Reports Heating Oil and Propane Update Weekly heating oil and propane prices are only collected during the heating season, which extends from October through March....

  4. Remote Sensing and Sea-Truth Measurements of Methane Flux to the Atmosphere (HYFLUX project)

    SciTech Connect (OSTI)

    Ian MacDonald

    2011-05-31T23:59:59.000Z

    A multi-disciplinary investigation of distribution and magnitude of methane fluxes from seafloor gas hydrate deposits in the Gulf of Mexico was conducted based on results obtained from satellite synthetic aperture radar (SAR) remote sensing and from sampling conducted during a research expedition to three sites where gas hydrate occurs (MC118, GC600, and GC185). Samples of sediments, water, and air were collected from the ship and from an ROV submersible using sediments cores, niskin bottles attached to the ROV and to a rosette, and an automated sea-air interface collector. The SAR images were used to quantify the magnitude and distribution of natural oil and gas seeps that produced perennial oil slicks on the ocean surface. A total of 176 SAR images were processed using a texture classifying neural network algorithm, which segmented the ocean surface into oil-free and oil-covered water. Geostatistical analysis indicates that there are a total of 1081 seep formations distributed over the entire Gulf of Mexico basin. Oil-covered water comprised an average of 780.0 sq. km (sd 86.03) distributed with an area of 147,370 sq. km. Persistent oil and gas seeps were also detected with SAR sampling on other ocean margins located in the Black Sea, western coast of Africa, and offshore Pakistan. Analysis of sediment cores from all three sites show profiles of sulfate, sulfide, calcium and alkalinity that indicated anaerobic oxidation of methane with precipitation of authigenic carbonates. Difference among the three sampling sites may reflect the relative magnitude of methane flux. Methane concentrations in water column samples collected by ROV and rosette deployments from MC118 ranged from {approx}33,000 nM at the seafloor to {approx}12 nM in the mixed layer with isolated peaks up to {approx}13,670 nM coincident with the top of the gas hydrate stability field. Average plume methane, ethane, and propane concentrations in the mixed layer are 7, 630, and 9,540 times saturation, respectively. Based on the contemporaneous wind speeds at this site, contemporary estimates of the diffusive fluxes from the mixed layer to the atmosphere for methane, ethane, and propane are 26.5, 2.10, and 2.78 {micro}mol/m{sup 2}d, respectively. Continuous measurements of air and sea surface concentrations of methane were made to obtain high spatial and temporal resolution of the diffusive net sea-to-air fluxes. The atmospheric methane fluctuated between 1.70 ppm and 2.40 ppm during the entire cruise except for high concentrations (up to 4.01 ppm) sampled during the end of the occupation of GC600 and the transit between GC600 and GC185. Results from interpolations within the survey areas show the daily methane fluxes to the atmosphere at the three sites range from 0.744 to 300 mol d-1. Considering that the majority of seeps in the GOM are deep (>500 m), elevated CH{sub 4} concentrations in near-surface waters resulting from bubble-mediated CH4 transport in the water column are expected to be widespread in the Gulf of Mexico.

  5. Natural gas cleanup: Evaluation of a molecular sieve carbon as a pressure swing adsorbent for the separation of methane/nitrogen mixtures

    SciTech Connect (OSTI)

    Grimes, R.W.

    1994-06-01T23:59:59.000Z

    This report describes the results of a preliminary evaluation to determine the technical feasibility of using a molecular sieve carbon manufactured by the Takeda Chemical Company of Japan in a pressure owing adsorption cycle for upgrading natural gas (methane) contaminated with nitrogen. Adsorption tests were conducted using this adsorbent in two, four, and five-step adsorption cycles. Separation performance was evaluated in terms of product purity, product recovery, and sorbent productivity for all tests. The tests were conducted in a small, single-column adsorption apparatus that held 120 grams of the adsorbent. Test variables included adsorption pressure, pressurization rate, purge rate and volume, feed rate, and flow direction in the steps from which the product was collected. Sorbent regeneration was accomplished by purging the column with the feed gas mixture for all but one test series where a pure methane purge was used. The ratio between the volumes of the pressurization gas and the purge gas streams was found to be an important factor in determining separation performance. Flow rates in the various cycle steps had no significant effect. Countercurrent flow in the blow-down and purge steps improved separation performance. Separation performance appears to improve with increasing adsorption pressure, but because there are a number of interrelated variables that are also effected by pressure, further testing will be needed to verify this. The work demonstrates that a molecular sieve carbon can be used to separate a mixture of methane and nitrogen when used in a pressure swing cycle with regeneration by purge. Further work is needed to increase product purity and product recovery.

  6. DEVELOPMENT OF A CATALYST/SORBENT FOR METHANE REFORMING

    SciTech Connect (OSTI)

    B.H. Shanks; T.D. Wheelock; Justinus A. Satrio; Timothy Diehl; Brigitte Vollmer

    2004-09-27T23:59:59.000Z

    This work has led to the initial development of a very promising material that has the potential to greatly simplify hydrocarbon reforming for the production of hydrogen and to improve the overall efficiency and economics of the process. This material, which was derived from an advanced calcium-based sorbent, was composed of core-in-shell pellets such that each pellet consisted of a CaO core and an alumina-based shell. By incorporating a nickel catalyst in the shell, a combined catalyst and sorbent was prepared to facilitate the reaction of hydrocarbons with steam. It was shown that this material not only catalyzes the reactions of methane and propane with steam, it also absorbs CO{sub 2} simultaneously, and thereby separates the principal reaction products, H{sub 2} and CO{sub 2}. Furthermore, the absorption of CO{sub 2} permits the water gas shift reaction to proceed much further towards completion at temperatures where otherwise it would be limited severely by thermodynamic equilibrium. Therefore, an additional water gas shift reaction step would not be required to achieve low concentrations of CO. In a laboratory test of methane reforming at 600 C and 1 atm it was possible to produce a gaseous product containing 96 mole% H{sub 2} (dry basis) while also achieving a H{sub 2} yield of 95%. Methane reforming under these conditions without CO{sub 2} absorption provided a H{sub 2} concentration of 75 mole% and yield of 82%. Similar results were achieved in a test of propane reforming at 560 C and 1 atm which produced a product containing 96 mole% H{sub 2} while CO{sub 2} was being absorbed but which contained only 69 mole% H{sub 2} while CO{sub 2} was not being absorbed. These results were achieved with an improved catalyst support that was developed by replacing a portion of the {alpha}-alumina in the original shell material with {gamma}-alumina having a much greater surface area. This replacement had the unfortunate consequence of reducing the overall compressive strength of the core-in-shell pellets. Therefore, a preliminary study of the factors that control the surface area and compressive strength of the shell material was conducted. The important factors were identified as the relative concentrations and particle size distributions of the {alpha}-alumina, {gamma}-alumina, and limestone particles plus the calcination temperature and time used for sintering the shell material. An optimization of these factors in the future could lead to the development of a material that has both the necessary mechanical strength and catalytic activity.

  7. RICH METHANE PREMIXED LAMINAR FLAMES DOPED BY LIGHT UNSATURATED HYDROCARBONS

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    /s at 333 K and mixtures containing 55.6% argon, 15.3% methane (99.95 %, pure supplied by Alphagaz - L'Air propyne, allene, propene, propane, 1-butene, 1,3-butadiene, 1,2-butadiene, vinylacetylene, diacetylene

  8. Synthesis gas formation by catalytic oxidation of methane in fluidized bed reactors

    SciTech Connect (OSTI)

    Bharadwaj, S.S.; Schmidt, L.D. (Univ. of Minnesota, Minneapolis (United States))

    1994-03-01T23:59:59.000Z

    The production of synthesis gas (CO + H[sub 2]) by the catalytic partial oxidation of CH[sub 4] in air or O[sub 2] in static fluidized beds at atmospheric pressure has been examined over Pt, Rh, and Ni catalysts coated on 100-[mu]m [alpha]-Al[sub 2]O[sub 3] beads. With CH[sub 4]/air feeds, CO and H[sub 2] selectivities as high as 95% with >90% CH[sub 4] conversion were obtained on Rh and Ni catalysts at contact times of 0.1-0.5 sec. Pt catalysts were found to have significantly lower selectivities for all the three catalysts were improved by heating the reaction mixture above the autothermal reactor temperature and using O[sub 2] instead of air. The selectivities and conversions were fairly constant over the range of contact time s used. Probable reaction pathways for CH[sub 4] oxidation in fluidized beds are discussed. 31 refs., 6 figs.

  9. Quantifying Sustainable Development with Sustainable Costs

    E-Print Network [OSTI]

    Pike, Ralph W.

    .6 Synthesis Gas Methane reforming 17.2 Propylene Propane dehydrogenation 4.3 Propylene Propane dehydrogenation · Syngas from CO2 and CH4 · Propane dehydrogenation · Propylene from propane and CO2 · Styrene from

  10. Predicting Methane Production in Dairy Mohammad Ramin

    E-Print Network [OSTI]

    Predicting Methane Production in Dairy Cows Mohammad Ramin Faculty of Natural Resources and Agricultural Sciences Department of Agricultural Research for Northern Sweden Umeå Doctoral Thesis Swedish (Karoline) #12;Predicting Methane Production in Dairy cows Abstract Methane is a potent greenhouse gas

  11. Impact of Fuel Interchangeability on dynamic Instabilities in Gas Turbine Engines

    SciTech Connect (OSTI)

    Ferguson, D.H.; Straub, D.L.; Richards, G.A.; Robey, E.H.

    2007-03-01T23:59:59.000Z

    Modern, low NOx emitting gas turbines typically utilize lean pre-mixed (LPM) combustion as a means of achieving target emissions goals. As stable combustion in LPM systems is somewhat intolerant to changes in operating conditions, precise engine tuning on a prescribed range of fuel properties is commonly performed to avoid dynamic instabilities. This has raised concerns regarding the use of imported liquefied natural gas (LNG) and natural gas liquids (NGL’s) to offset a reduction in the domestic natural gas supply, which when introduced into the pipeline could alter the fuel BTU content and subsequently exacerbate problems such as combustion instabilities. The intent of this study is to investigate the sensitivity of dynamically unstable test rigs to changes in fuel composition and heat content. Fuel Wobbe number was controlled by blending methane and natural gas with various amounts of ethane, propane and nitrogen. Changes in combustion instabilities were observed, in both atmospheric and pressurized test rigs, for fuels containing high concentrations of propane (> 62% by vol). However, pressure oscillations measured while operating on typical “LNG like” fuels did not appear to deviate significantly from natural gas and methane flame responses. Mechanisms thought to produce changes in the dynamic response are discussed.

  12. Adsorption Mechanism and Uptake of Methane in Covalent Organic Frameworks: Theory and Experiment

    E-Print Network [OSTI]

    Yaghi, Omar M.

    this disadvantage include · storing methane as liquefied natural gas (LNG, at 112 K) or compressed natural gas (CNG

  13. 29Counting Atoms in a Molecule The complex molecule Propanal

    E-Print Network [OSTI]

    29Counting Atoms in a Molecule The complex molecule Propanal was discovered in a dense interstellar is the ratio of carbon atoms to hydrogen atoms in propanal? Problem 4 - If the mass of a hydrogen atom of a propanal molecule in AMUs? Problem 5 - What is the complete chemical formula for propanal? C3 H __ O

  14. Alternative Fuel Tool Kit How to Implement: Propane

    E-Print Network [OSTI]

    1 08/2014 Alternative Fuel Tool Kit How to Implement: Propane Contents Introduction to Propane (LPG...........................................................................................................2 Benefits of Using Propane (LPG) for Transportation of Energy under Award Number DE-EE0006083. #12;2 08/2014 Introduction to Propane (LPG) for Transportation

  15. Evolutionary History of a Specialized P450 Propane Monooxygenase

    E-Print Network [OSTI]

    Arnold, Frances H.

    Evolutionary History of a Specialized P450 Propane Monooxygenase Rudi Fasan1 , Yergalem T-evolved P450 propane mono- oxygenase (P450PMO) having 20 heme domain substitutions compared to P450BM3 of propane activity. In contrast, refinement of the enzyme catalytic efficiency for propane oxidation (9000

  16. Propane vehicles : status, challenges, and opportunities.

    SciTech Connect (OSTI)

    Rood Werpy, M.; Burnham, A.; Bertram, K.; Energy Systems

    2010-06-17T23:59:59.000Z

    Propane as an auto fuel has a high octane value and has key properties required for spark-ignited internal combustion engines. To operate a vehicle on propane as either a dedicated fuel or bi-fuel (i.e., switching between gasoline and propane) vehicle, only a few modifications must be made to the engine. Until recently propane vehicles have commonly used a vapor pressure system that was somewhat similar to a carburetion system, wherein the propane would be vaporized and mixed with combustion air in the intake plenum of the engine. This leads to lower efficiency as more air, rather than fuel, is inducted into the cylinder for combustion (Myers 2009). A newer liquid injection system has become available that injects propane directly into the cylinder, resulting in no mixing penalty because air is not diluted with the gaseous fuel in the intake manifold. Use of a direct propane injection system will improve engine efficiency (Gupta 2009). Other systems include the sequential multi-port fuel injection system and a bi-fuel 'hybrid' sequential propane injection system. Carbureted systems remain in use but mostly for non-road applications. In the United States a closed-loop system is used in after-market conversions. This system incorporates an electronic sensor that provides constant feedback to the fuel controller to allow it to measure precisely the proper air/fuel ratio. A complete conversion system includes a fuel controller, pressure regulator valves, fuel injectors, electronics, fuel tank, and software. A slight power loss is expected in conversion to a vapor pressure system, but power can still be optimized with vehicle modifications of such items as the air/fuel mixture and compression ratios. Cold start issues are eliminated for vapor pressure systems since the air/fuel mixture is gaseous. In light-duty propane vehicles, the fuel tank is typically mounted in the trunk; for medium- and heavy-duty vans and trucks, the tank is located under the body of the vehicle. Propane tanks add weight to a vehicle and can slightly increase the consumption of fuel. On a gallon-to-gallon basis, the energy content of propane is 73% that of gasoline, thus requiring more propane fuel to travel an equivalent distance, even in an optimized engine (EERE 2009b).

  17. Knoxville Area Transit: Propane Hybrid Electric Trolleys

    SciTech Connect (OSTI)

    Not Available

    2005-04-01T23:59:59.000Z

    A 2-page fact sheet summarizing the evaluation done by the U.S. Department of Energy's Advanced Vehicle Testing Activity on the Knoxville Area Transit's use of propane hybrid electric trolleys.

  18. QER- Comment of Propane Education & Research Council

    Broader source: Energy.gov [DOE]

    I plan to attend and ask a question of the Secretary regarding propane supply for the upcoming winter. Please do not hesitate to call or email if you have questions. Tucker Perkins

  19. Effect of bubble size and density on methane conversion to hydrate

    SciTech Connect (OSTI)

    Leske, J.; Taylor, C.E.; Ladner, E.P.

    2007-03-01T23:59:59.000Z

    Research is underway at NETL to understand the physical properties of methane hydrates. One area of investigation is the storage of methane as methane hydrates. An economical and efficient means of storing methane in hydrates opens many commercial opportunities such as transport of stranded gas, off-peak storage of line gas, etc.We have observed during our investigations that the ability to convert methane to methane hydrate is enhanced by foaming of the methane–water solution using a surfactant. The density of the foam, along with the bubble size, is important in the conversion of methane to methane hydrate.

  20. Coalbed methane production case histories

    SciTech Connect (OSTI)

    Not Available

    1981-02-01T23:59:59.000Z

    The production of methane gas from coal and coal-bearing rocks is one of the prime objectives of the Department of Energy's Methane Recovery from Coalbeds Project. This report contains brief description of wells that are presently producing gas from coal or coal-bearing rocks. Data from three gob gas production areas in Illinois, an in-mine horizontal borehole degasification, and eleven vertical boreholes are presented. Production charts and electric logs of the producing zones are included for some of the wells. Additional information on dry gas production from the San Juan Basin, Colorado/New Mexico and the Greater Green River Coal Region, Colorado/Wyoming is also included.

  1. Syngas Production from Propane using Atmospheric Non-Thermal Plasma F. Ouni, A. Khacef*

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Syngas Production from Propane using Atmospheric Non-Thermal Plasma F. Ouni, A. Khacef* and J. M applications (1, 2) . Synthesis gas or syngas (mixture of hydrogen and carbon monoxide) are used as a major. The conventional reformers allowing syngas production are based on steam reforming of hydrocarbons (3) following

  2. The determination of compressibility factors of gaseous propane-nitrogen mixtures 

    E-Print Network [OSTI]

    Hodges, Don

    1952-01-01T23:59:59.000Z

    of thc Beg;voc cf kBSTBACT The propane-nitrogen system has been investigated in the gaseous phase at a temperature of 300 F. and at pressures up to 4/0 atmospheres. Compressibility curves for three mixtures of this system have been determined. A... the pressure corresponding to the "n " expansion ? th? the partial pressure of nitrogen the partial pressure oi' propane the total pressure of a gaseous system the universal gas constant (0. 08206 liter-atmosphere/ gram mole - oK) the absolute...

  3. The determination of compressibility factors of gaseous propane-nitrogen mixtures

    E-Print Network [OSTI]

    Hodges, Don

    1952-01-01T23:59:59.000Z

    of thc Beg;voc cf kBSTBACT The propane-nitrogen system has been investigated in the gaseous phase at a temperature of 300 F. and at pressures up to 4/0 atmospheres. Compressibility curves for three mixtures of this system have been determined. A... the pressure corresponding to the "n " expansion ? th? the partial pressure of nitrogen the partial pressure oi' propane the total pressure of a gaseous system the universal gas constant (0. 08206 liter-atmosphere/ gram mole - oK) the absolute...

  4. Methane emissions from MBT landfills

    SciTech Connect (OSTI)

    Heyer, K.-U., E-mail: heyer@ifas-hamburg.de; Hupe, K.; Stegmann, R.

    2013-09-15T23:59:59.000Z

    Highlights: • Compilation of methane generation potential of mechanical biological treated (MBT) municipal solid waste. • Impacts and kinetics of landfill gas production of MBT landfills, approach with differentiated half-lives. • Methane oxidation in the waste itself and in soil covers. • Estimation of methane emissions from MBT landfills in Germany. - Abstract: Within the scope of an investigation for the German Federal Environment Agency (“Umweltbundesamt”), the basics for the estimation of the methane emissions from the landfilling of mechanically and biologically treated waste (MBT) were developed. For this purpose, topical research including monitoring results regarding the gas balance at MBT landfills was evaluated. For waste treated to the required German standards, a methane formation potential of approximately 18–24 m{sup 3} CH{sub 4}/t of total dry solids may be expected. Monitoring results from MBT landfills show that a three-phase model with differentiated half-lives describes the degradation kinetics in the best way. This is due to the fact that during the first years of disposal, the anaerobic degradation processes still proceed relatively intensively. In addition in the long term (decades), a residual gas production at a low level is still to be expected. Most of the soils used in recultivation layer systems at German landfills show a relatively high methane oxidation capacity up to 5 l CH{sub 4}/(m{sup 2} h). However, measurements at MBT disposal sites indicate that the majority of the landfill gas (in particular at non-covered areas), leaves the landfill body via preferred gas emission zones (hot spots) without significant methane oxidation. Therefore, rather low methane oxidation factors are recommended for open and temporarily covered MBT landfills. Higher methane oxidation rates can be achieved when the soil/recultivation layer is adequately designed and operated. Based on the elaborated default values, the First Order Decay (FOD) model of the IPCC Guidelines for National Greenhouse Gas Inventories, 2006, was used to estimate the methane emissions from MBT landfills. Due to the calculation made by the authors emissions in the range of 60,000–135,000 t CO{sub 2-eq.}/a for all German MBT landfills can be expected. This wide range shows the uncertainties when the here used procedure and the limited available data are applied. It is therefore necessary to generate more data in the future in order to calculate more precise methane emission rates from MBT landfills. This is important for the overall calculation of the climate gas production in Germany which is required once a year by the German Government.

  5. State Heating Oil & Propane Program. Final report 1997/98 heating season

    SciTech Connect (OSTI)

    Hunton, G.

    1998-06-01T23:59:59.000Z

    The following is a summary report of the New Hampshire Governor`s Office of Energy and Community Services (ECS) participation in the State Heating Oil and Propane Program (SHOPP) for the 1997/98 heating season. SHOPP is a cooperative effort, linking energy offices in East Coast and Midwest states, with the Department of Energy (DOE), Energy Information Administration (EIA) for the purpose of collecting retail price data for heating oil and propane. The program is funded by the participating state with a matching grant from DOE. SHOPP was initiated in response to congressional inquires into supply difficulties and price spikes of heating oil and propane associated with the winter of 1989/90. This is important to New Hampshire because heating oil controls over 55% of the residential heating market statewide. Propane controls 10% of the heating market statewide and is widely used for water heating and cooking in areas of the state where natural gas is not available. Lower installation cost, convenience, lower operating costs compared to electricity, and its perception as a clean heating fuel have all worked to increase the popularity of propane in New Hampshire and should continue to do so in the future. Any disruption in supply of these heating fuels to New Hampshire could cause prices to skyrocket and leave many residents in the cold.

  6. Natural gas treatment process using PTMSP membrane

    DOE Patents [OSTI]

    Toy, L.G.; Pinnau, I.

    1996-03-26T23:59:59.000Z

    A process is described for separating C{sub 3}+ hydrocarbons, particularly propane and butane, from natural gas. The process uses a poly(trimethylsilylpropyne) membrane. 6 figs.

  7. Natural gas treatment process using PTMSP membrane

    DOE Patents [OSTI]

    Toy, Lora G. (San Francisco, CA); Pinnau, Ingo (Palo Alto, CA)

    1996-01-01T23:59:59.000Z

    A process for separating C.sub.3 + hydrocarbons, particularly propane and butane, from natural gas. The process uses a poly(trimethylsilylpropyne) membrane.

  8. CFD Modeling of Methane Production from Hydrate-Bearing Reservoir

    SciTech Connect (OSTI)

    Gamwo, I.K.; Myshakin, E.M.; Warzinski, R.P.

    2007-04-01T23:59:59.000Z

    Methane hydrate is being examined as a next-generation energy resource to replace oil and natural gas. The U.S. Geological Survey estimates that methane hydrate may contain more organic carbon the the world's coal, oil, and natural gas combined. To assist in developing this unfamiliar resource, the National Energy Technology Laboratory has undertaken intensive research in understanding the fate of methane hydrate in geological reservoirs. This presentation reports preliminary computational fluid dynamics predictions of methane production from a subsurface reservoir.

  9. Thermal dissociation behavior and dissociation enthalpies of methane-carbon dioxide mixed hydrates

    E-Print Network [OSTI]

    Kwon, T.H.

    2012-01-01T23:59:59.000Z

    Dissociation heat of mixed-gas hydrate composed of methaneInternational Conference on Gas Hydrates (ICGH 2008), 2008,and specific heats of gas hydrates under submarine and

  10. Presentations from the March 27th - 28th Methane Hydrates Advisory...

    Office of Environmental Management (EM)

    from the March 27th - 28th Methane Hydrates Advisory Committee Meeting International Gas Hydrate Research DOE's Natural Gas Hydrates Program Gas Hydrates as a Geohazard: What...

  11. Propane Vehicle and Infrastructure Codes and Standards Citations (Brochure)

    SciTech Connect (OSTI)

    Not Available

    2010-07-01T23:59:59.000Z

    This document lists codes and standards typically used for U.S. propane vehicle and infrastructure projects.

  12. Evolutionary History of a Specialized P450 Propane Monooxygenase

    E-Print Network [OSTI]

    Arnold, Frances H.

    Evolutionary History of a Specialized P450 Propane Monooxygenase Rudi Fasan1 , Yergalem T hydroxylase (P450BM3) to a laboratory-evolved P450 propane mono- oxygenase (P450PMO) having 20 heme domain substrate range and the emergence of propane activity. In contrast, refinement of the enzyme catalytic

  13. Portland Public School Children Move with Propane

    SciTech Connect (OSTI)

    Not Available

    2004-04-01T23:59:59.000Z

    This 2-page Clean Cities fact sheet describes the use of propane as a fuel source for Portland Public Schools' fleet of buses. It includes information on the history of the program, along with contact information for the local Clean Cities Coordinator and Portland Public Schools.

  14. Greenhouse gas reduction by recovery and utilization of landfill methane and CO{sub 2} technical and market feasibility study, Boului Landfill, Bucharest, Romania. Final report, September 30, 1997--September 19, 1998

    SciTech Connect (OSTI)

    Cook, W.J.; Brown, W.R.; Siwajek, L. [Acrion Technologies, Inc., Cleveland, OH (United States); Sanders, W.I. [Power Management Corp., Bellevue, WA (United States); Botgros, I. [Petrodesign, SA, Bucharest (Romania)

    1998-09-01T23:59:59.000Z

    The project is a landfill gas to energy project rated at about 4 megawatts (electric) at startup, increasing to 8 megawatts over time. The project site is Boului Landfill, near Bucharest, Romania. The project improves regional air quality, reduces emission of greenhouse gases, controls and utilizes landfill methane, and supplies electric power to the local grid. The technical and economic feasibility of pre-treating Boului landfill gas with Acrion`s new landfill gas cleanup technology prior to combustion for power production us attractive. Acrion`s gas treatment provides several benefits to the currently structured electric generation project: (1) increase energy density of landfill gas from about 500 Btu/ft{sup 3} to about 750 Btu/ft{sup 3}; (2) remove contaminants from landfill gas to prolong engine life and reduce maintenance;; (3) recover carbon dioxide from landfill gas for Romanian markets; and (4) reduce emission of greenhouse gases methane and carbon dioxide. Greenhouse gas emissions reduction attributable to successful implementation of the landfill gas to electric project, with commercial liquid CO{sub 2} recovery, is estimated to be 53 million metric tons of CO{sub 2} equivalent of its 15 year life.

  15. SCADA system aids BGE`s Notch Cliff propane-air facility

    SciTech Connect (OSTI)

    Miller, B.A. [Baltimore Gas and Electric Co., MD (United States)

    1997-02-01T23:59:59.000Z

    SCADA systems in the natural gas industry are commonly associated with distribution networks and transmission pipelines. There is however, another application for SCADA technology that is increasingly being utilized in the industry. By implementing automation technology and process control concepts more typically associated with industrial and petrochemical process facilities, Baltimore Gas and Electric Co. (BGE) has significantly improved the efficiency, performance, and safety at its Notch Cliff Propane-Air peak shaving facility. These results have contributed to BGE`s ongoing efforts to effectively operate in the competitive energy marketplace. When the Notch Cliff plant was built in the early 1960s, it was a state-of-the-art facility. The plant blends propane vapor and compressed air to create a supplement to the natural gas supply during peak demand periods.

  16. Coke profile and effect on methane/ethylene conversion process

    E-Print Network [OSTI]

    Al-Solami, Bandar

    2002-01-01T23:59:59.000Z

    with distance along the reactor, and therefore the coke distribution should follow a similar pattern. A distribution of coke deposits along the reactor was also observed by Noda er al. (1974) in a study of iso-pentane isomerization. In this case the coke..., methane, ethane, ethylene, propane, iso-butane, butane, iso-pentane, pentane and hexanes. Also, the flow rate of the effluent stream is measured using the bubble meter. The mole percentages of methane and ethylene are subtracted of the effluent stream...

  17. Mars long has been considered a cold, dead planet.However,recent reports of methane

    E-Print Network [OSTI]

    Manning, Craig

    , and not necessarily just methane-pro- ducing organisms. However,if these environments were found not to be inhabited as from the thermal pro- cessing of complex organic remnants of past life (thermogenesis). In the first (ethane,propane,butane). On Mars, more shallowly buried organic material from putative past life could

  18. New constraints on methane fluxes and rates of anaerobic methane oxidation in a Gulf of Mexico brine pool via in situ mass spectrometry

    E-Print Network [OSTI]

    Girguis, Peter R.

    , likely exceeding reserves of conventional oil and gas (Collett and Kuuskraa, 1998). In deep-ocean regionsNew constraints on methane fluxes and rates of anaerobic methane oxidation in a Gulf of Mexico Keywords: Methane flux Mass spectrometer Brine pool Methane oxidation Gulf of Mexico a b s t r a c t Deep

  19. An analysis of US propane markets, winter 1996-1997

    SciTech Connect (OSTI)

    NONE

    1997-06-01T23:59:59.000Z

    In late summer 1996, in response to relatively low inventory levels and tight world oil markets, prices for crude oil, natural gas, and products derived from both began to increase rapidly ahead of the winter heating season. Various government and private sector forecasts indicated the potential for supply shortfalls and sharp price increases, especially in the event of unusually severe winter weather. Following a rapid runup in gasoline prices in the spring of 1996, public concerns were mounting about a possibly similar situation in heating fuels, with potentially more serious consequences. In response to these concerns, the Energy Information Administration (EIA) participated in numerous briefings and meetings with Executive Branch officials, Congressional committee members and staff, State Energy Offices, and consumers. EIA instituted a coordinated series of actions to closely monitor the situation and inform the public. This study constitutes one of those actions: an examination of propane supply, demand, and price developments and trends.

  20. METHANE IN SUBSURFACE: MATHEMATICAL MODELING AND COMPUTATIONAL CHALLENGES

    E-Print Network [OSTI]

    Peszynska, Malgorzata

    consortium led by Chevron, in gas hydrate drilling, research expeditions [6], and observatories [5, 7] which help to evaluate methane hydrate as an energy resource. Although the existence of gas hydrates and energy recovery involving the evolution of methane gas in the subsurface. In particular, we develop

  1. Effect of propane-air on NGVs and vehicle fueling stations. Topical report, January 1-October 1, 1993

    SciTech Connect (OSTI)

    Liss, W.E.; Moulton, D.S.

    1994-06-01T23:59:59.000Z

    Propane-air (P/A) peakshaving is an important element of peak-load management for some U.S. gas utilities. P/A is used as a supplemental energy medium with natural gas and has been shown to operate satisfactorily in most natural gas applications. The propane levels injected are compatible with the pressures (under 200 psig) and temperatures (over 40 F) found in utility distribution networks. However, P/A can create problems for natural gas vehicles (NGVs) operating on compressed gas as well as NGV fueling stations. This report contains information on P/A peakshaving and its compatibility with NGVs by documenting condensation impacts at nine conditions--i.e., three propane levels and three temperatures. These data portray the depressurization of a vehicle tank, an area selected because it illustrates NGV operation and can discriminate between acceptable and potentially non-acceptable operating points. These analyses show, not surprisingly, a correlation exists between propane level, ambient temperature, and condensation.

  2. Coal Bed Methane Primer

    SciTech Connect (OSTI)

    Dan Arthur; Bruce Langhus; Jon Seekins

    2005-05-25T23:59:59.000Z

    During the second half of the 1990's Coal Bed Methane (CBM) production increased dramatically nationwide to represent a significant new source of income and natural gas for many independent and established producers. Matching these soaring production rates during this period was a heightened public awareness of environmental concerns. These concerns left unexplained and under-addressed have created a significant growth in public involvement generating literally thousands of unfocused project comments for various regional NEPA efforts resulting in the delayed development of public and fee lands. The accelerating interest in CBM development coupled to the growth in public involvement has prompted the conceptualization of this project for the development of a CBM Primer. The Primer is designed to serve as a summary document, which introduces and encapsulates information pertinent to the development of Coal Bed Methane (CBM), including focused discussions of coal deposits, methane as a natural formed gas, split mineral estates, development techniques, operational issues, producing methods, applicable regulatory frameworks, land and resource management, mitigation measures, preparation of project plans, data availability, Indian Trust issues and relevant environmental technologies. An important aspect of gaining access to federal, state, tribal, or fee lands involves education of a broad array of stakeholders, including land and mineral owners, regulators, conservationists, tribal governments, special interest groups, and numerous others that could be impacted by the development of coal bed methane. Perhaps the most crucial aspect of successfully developing CBM resources is stakeholder education. Currently, an inconsistent picture of CBM exists. There is a significant lack of understanding on the parts of nearly all stakeholders, including industry, government, special interest groups, and land owners. It is envisioned the Primer would being used by a variety of stakeholders to present a consistent and complete synopsis of the key issues involved with CBM. In light of the numerous CBM NEPA documents under development this Primer could be used to support various public scoping meetings and required public hearings throughout the Western States in the coming years.

  3. Energy Department Expands Research into Methane Hydrates, a Vast...

    Broader source: Energy.gov (indexed) [DOE]

    of methane in shallow subsurface and water columns, and the role gas hydrates play in carbon cycling. DOE Investment: approximately 650,000 Massachusetts Institute of...

  4. MethaneHydrateRD_FC.indd

    Office of Environmental Management (EM)

    source of natural gas in 1983. The Methane Hydrate Research and Development Act of 2000 established DOE as the lead U.S. agency for R&D in this fi eld. Early phases of...

  5. A study of carbon-14 of paleoatmospheric methane for the last glacial termination from ancient glacial ice

    E-Print Network [OSTI]

    Petrenko, Vasilii Victorovich

    2008-01-01T23:59:59.000Z

    Kastner, M. , 2001. Gas Hydrates in Convergent Margins:Significance, Natural Gas Hydrates: Occurence, Distributionof methane in natural gas hydrate. Organic Geochemistry 23,

  6. 6, 68416852, 2006 Methane emission

    E-Print Network [OSTI]

    Boyer, Edmond

    is an important greenhouse gas, whose radiative forcing (1750­1998) has been estimated to be 0.48 Wm -2 , 20). The methane bud-15 get (sources and sinks) was believed to be relatively well known, however, recently confusing results were obtained in studies of CH4 soil fluxes in the Venezuelan savanna region (Hao et al

  7. Table 49. Prime Supplier Sales Volumes of Aviation Fuels, Propane...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Marketing Annual 1999 Table 49. Prime Supplier Sales Volumes of Aviation Fuels, Propane, and Residual Fuel Oil by PAD District and State (Thousand Gallons per Day) -...

  8. Table 49. Prime Supplier Sales Volumes of Aviation Fuels, Propane...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    See footnotes at end of table. 49. Prime Supplier Sales Volumes of Aviation Fuels, Propane, and Residual Fuel Oil by PAD District and State 386 Energy Information...

  9. Table 49. Prime Supplier Sales Volumes of Aviation Fuels, Propane...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Marketing Annual 1995 Table 49. Prime Supplier Sales Volumes of Aviation Fuels, Propane, and Residual Fuel Oil by PAD District and State (Thousand Gallons per Day) -...

  10. Table 49. Prime Supplier Sales Volumes of Aviation Fuels, Propane...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Marketing Annual 1998 Table 49. Prime Supplier Sales Volumes of Aviation Fuels, Propane, and Residual Fuel Oil by PAD District and State (Thousand Gallons per Day) -...

  11. Microsoft Word - Joe Rose - Providence remarks.propane.JUR -...

    Broader source: Energy.gov (indexed) [DOE]

    for propane consumers in acquiring adequate supply at affordable prices. Crop drying demand of 500% of last year's demand combined with heating demand of 20% above the...

  12. Impact of Natural Gas Appliances on Pollutant Levels in California Homes

    E-Print Network [OSTI]

    Mullen, Nasim A.

    2014-01-01T23:59:59.000Z

    be combined with storage WH) N N N Propane Don't know/blan kstorage water heater) __ Other (describe) K.2 Is this water heater powered by natural gas, electricity or propane? [Propane __ Electric! Skip to §L K.3 Do you have more than one storage

  13. Diffusional methane fluxes within continental margin sediments and depositional constraints on formation factor estimates

    E-Print Network [OSTI]

    Berg, Richard D.

    2008-01-01T23:59:59.000Z

    methane flux from underlying gas hydrate. Geology , 24 (7),overlying the Blake Ridge gas hydrates. In Proceedings ofgas transport in shallow sediments of an accretionary complex, Southern Hydrate

  14. Winter fuels report, week ending February 12, 1993. [Contains Glossary and feature article on Midwest Propane Markets

    SciTech Connect (OSTI)

    Not Available

    1993-02-18T23:59:59.000Z

    The Winter Fuels Report is intended to provide concise, timely information to the industry, the press, policymakers, consumers, analysts, and State and local governments on the following topics: Distillate fuel oil net production, imports and stocks on a US level and for all Petroleum Administration for Defense Districts (PADD) and product supplied on a US level; propane net production, imports and stocks on a US level and for PADD's 1, II, and III; natural gas supply and disposition and underground storage for the US and consumption for all PADD'S; as well as selected National average prices. Residential and wholesale pricing data for heating oil and propane for those States participating in the joint Energy Information Administration (EIA)/State Heating Oil and Propane Program; selected cities; and a 6--10 Day, 30-Day, and 90-Day outlook for temperature and precipitation and US total heating degree-days by city.

  15. Kinetics and Mechanism of Oxidative Dehydrogenation of Propane on Vanadium, Molybdenum, and Tungsten Oxides

    E-Print Network [OSTI]

    Iglesia, Enrique

    Kinetics and Mechanism of Oxidative Dehydrogenation of Propane on Vanadium, Molybdenum catalysts confirmed that oxidative dehydrogenation of propane occurs via similar pathways, which involve for propane dehydrogenation and for propene combustion increase in the sequence VOx/ZrO2

  16. CONTRIBUTION A L'TUDE DES FLAMMES D'HYDROCARBURES. PROPANE ET ACTYLNE

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    CONTRIBUTION A L'ÉTUDE DES FLAMMES D'HYDROCARBURES. PROPANE ET ACÉTYLÈNE Par MM. JEAN VAN DER POLL du propane et de l'acétylène qui ont montré que, dans certains cas, les flammes oxy-propane et oxy

  17. Effect of catalyst structure on oxidative dehydrogenation of ethane and propane on alumina-supported vanadia

    E-Print Network [OSTI]

    Argyle, Morris D.; Chen, Kaidong; Bell, Alexis T.; Iglesia, Enrique

    2001-01-01T23:59:59.000Z

    catalysts: (a) ethane ODH, (b) propane ODH (663 K, 14 kPa CDehydrogenation of Ethane and Propane on Alumina-Supporteddehydrogenation of ethane and propane. UV-visible and Raman

  18. Semi-annual report for the unconventional gas recovery program, period ending March 31, 1980

    SciTech Connect (OSTI)

    Manilla, R.D.

    1980-06-01T23:59:59.000Z

    Four subprograms are reported on: methane recovery from coalbeds, Eastern gas shales, Western gas sands, and methane from geopressured aquifers. (DLC)

  19. Liquid Propane Injection Applications | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(FactDepartment ofLetterEconomy and EmissionsDepartment of EnergyLiquid propane

  20. Residential propane price decreases slightly decreases slightly

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropane price05, 2014propane price7,

  1. Alternative Fuels Data Center: Propane Related Links

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduceNewPropane Printable Version Share this

  2. LANDFILL OPERATION FOR CARBON SEQUESTRATION AND MAXIMUM METHANE EMISSION CONTROL

    SciTech Connect (OSTI)

    Don Augenstein

    1999-01-11T23:59:59.000Z

    ''Conventional'' waste landfills emit methane, a potent greenhouse gas, in quantities such that landfill methane is a major factor in global climate change. Controlled landfilling is a novel approach to manage landfills for rapid completion of total gas generation, maximizing gas capture and minimizing emissions of methane to the atmosphere. With controlled landfilling, methane generation is accelerated and brought to much earlier completion by improving conditions for biological processes (principally moisture levels) in the landfill. Gas recovery efficiency approaches 100% through use of surface membrane cover over porous gas recovery layers operated at slight vacuum. A field demonstration project's results at the Yolo County Central Landfill near Davis, California are, to date, highly encouraging. Two major controlled landfilling benefits would be the reduction of landfill methane emissions to minuscule levels, and the recovery of greater amounts of landfill methane energy in much shorter times than with conventional landfill practice. With the large amount of US landfill methane generated, and greenhouse potency of methane, better landfill methane control can play a substantial role in reduction of US greenhouse gas emissions.

  3. Safety evaluation for packaging (onsite) nitrogen trailers propane tanks

    SciTech Connect (OSTI)

    Ferrell, P.C.

    1998-01-28T23:59:59.000Z

    The purpose of the Safety Evaluation for Packaging (SEP) is the evaluation and authorization of the onsite transport of propane tanks that are mounted on the Lockheed Martin Hanford Corporation Characterization Project`s nitrogen trailers. This SEP authorizes onsite transport of the nitrogen trailers, including the propane tanks, until May 31, 1998. The three nitrogen trailers (HO-64-4966, HO-64-4968, and HO-64-5170) are rated for 1,361 kg (30,000 lb) and are equipped with tandem axles and pintel hitches. Permanently mounted on each trailer is a 5,678 L (1,500 gal) cryogenic dewar that is filled with nitrogen, and a propane fired water bath vaporizer system, and a 454 L (1 20 gal) propane tank. The nitrogen trailer system is operated only when it is disconnected from the tow vehicle and is leveled and stabilized. When the trailers are transported, the propane tanks are isolated via closed supply valves.

  4. Biogeochemical modelling of anaerobic vs. aerobic methane oxidation in a meromictic crater lake (Lake Pavin, France)

    E-Print Network [OSTI]

    Boyer, Edmond

    Géosciences, 1A rue de la Férolerie, 45071 Orléans Cedex 2, France Abstract Methane is a powerful greenhouse gas and its concentration in the atmosphere has increased over the past decades. Methane produced

  5. Magnitude and spatio-temporal variability of methane emissions from a eutrophic freshwater lake

    E-Print Network [OSTI]

    Varadharajan, Charuleka, 1980-

    2009-01-01T23:59:59.000Z

    Methane is the second most important greenhouse gas after carbon dioxide, and it can significantly impact global climate change. Considerable amounts of methane can be released to the atmosphere from freshwater lakes, ...

  6. Energy Policy Seminar Series: Climate impacts of methane-emitting energy technologies

    E-Print Network [OSTI]

    Chen, Kuang-Yu

    of greenhouse gases, most notably methane and carbon dioxide, and these gases have dissimilar properties. This research finds that methane-emitting energy such as natural gas becomes significantly more carbon dioxide

  7. Control of substrate access to the active site in methane monooxygenase

    E-Print Network [OSTI]

    Lee, Seung Jae

    Methanotrophs consume methane as their major carbon source and have an essential role in the global carbon cycle by limiting escape of this greenhouse gas to the atmosphere. These bacteria oxidize methane to methanol by ...

  8. Michigan residential heating oil and propane price survey: 1995--1996 heating season. Final report

    SciTech Connect (OSTI)

    Moriarty, C.

    1996-05-01T23:59:59.000Z

    This report summarizes the results of a survey of residential No. 2 distillate fuel (home heating oil) and liquefied petroleum gas (propane) prices over the 1995--1996 heating season in Michigan. The Michigan`s Public Service Commission (MPSC) conducted the survey under a cooperative agreement with the US Department of Energy`s (DOE) Energy Information Administration (EIA). This survey was funded in part by a grant from the DOE. From October 1995 through March 1996, the MPSC surveyed participating distributors by telephone for current residential retail home heating oil and propane prices. The MPSC transmitted the data via a computer modem to the EIA using the Petroleum Electronic Data Reporting Option (PEDRO). Survey results were published in aggregate on the MPSC World Wide Web site at http://ermisweb.state.mi.us/shopp. The page was updated with both residential and wholesale prices immediately following the transmission of the data to the EIA. The EIA constructed the survey using a sample of Michigan home heating oil and propane retailers. The sample accounts for different sales volumes, geographic location, and sources of primary supply.

  9. Modeling pure methane hydrate dissociation using a numerical simulator from a novel combination of X-ray computed tomography and macroscopic data

    E-Print Network [OSTI]

    Gupta, A.

    2010-01-01T23:59:59.000Z

    From The Mallik 2002 Gas Hydrate Production Research Wellrate constant of methane gas hydrate decomposition. CanadianJNOC/GSC Mallik 2L-38 Gas Hydrate Research Well, Mackenzie

  10. Enduring use of city gas keeps N. H. utility reminiscent of a simpler age

    SciTech Connect (OSTI)

    Not Available

    1991-01-01T23:59:59.000Z

    This article reports on a gas distribution company which produces and pipes a propane/air mixture. The distribution of this mixture is detailed.

  11. Thermal analysis of adsorptive natural gas storages during dynamic charge phase at room temperature

    SciTech Connect (OSTI)

    Ridha, Firas N.; Yunus, Rosli M.; Rashid, Mohd. [Department of Chemical Engineering, University of Technology Malaysia, 81310 UTM, Skudai, Johor (Malaysia); Ismail, Ahmad F. [Department of Gas Engineering, University of Technology Malaysia, 81310 UTM, Skudai, Johor (Malaysia)

    2007-10-15T23:59:59.000Z

    The thermal behavior of an adsorptive natural gas (ANG) vessel pressurized continuously with light hydrocarbon gases and their mixture at 27 C was analyzed using two different activated carbons. Activated carbon AC-L showed better isothermal storage capacity than AC-D due to its sufficient porous structure. However, higher adsorption capacity claimed more extreme thermal fluctuation represented by a temperature rise of 99.2 C at the center region of the bed charged continuously with methane at 1 L min{sup -1} up to pressure of 4 MPa, corresponding to 82.5 C in AC-D bed. Higher charge rate of 5 L min{sup -1} claimed severer thermal fluctuation of 116 C in AC-L/methane system calling for a serious reduction of 26.9% in the dynamic storage capacity with respect to the isothermal storage capacity. This reduction brought the storage system to a working pressure of about 2.5 MPa rather than the desired working pressure of {proportional_to}4 MPa (about 40% reduction in storage pressure). The severest temperature rise was at the center region caused by bed poor thermal conductivity leading to limited heat transfer. High ethane and propane portions in natural gas may contribute to the thermal fluctuation of the storage system as their heats of adsorption are higher than that for methane. (author)

  12. FreezeFrac Improves the Productivity of Gas Shales S. Enayatpour, E. Van Oort, T. Patzek, University of Texas At Austin

    E-Print Network [OSTI]

    Patzek, Tadeusz W.

    to unconventional hydrocarbon reservers such as oil shales, gas shales, tight gas sands, coalbed methane, and gas

  13. X-ray CT Observations of Methane Hydrate Distribution Changes over Time in a Natural Sediment Core from the BPX-DOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test Well

    SciTech Connect (OSTI)

    Kneafsey, T.J.; Rees, E.V.L.

    2010-03-01T23:59:59.000Z

    When maintained under hydrate-stable conditions, methane hydrate in laboratory samples is often considered a stable and immobile solid material. Currently, there do not appear to be any studies in which the long-term redistribution of hydrates in sediments has been investigated in the laboratory. These observations are important because if the location of hydrate in a sample were to change over time (e.g. by dissociating at one location and reforming at another), the properties of the sample that depend on hydrate saturation and pore space occupancy would also change. Observations of hydrate redistribution under stable conditions are also important in understanding natural hydrate deposits, as these may also change over time. The processes by which solid hydrate can move include dissociation, hydrate-former and water migration in the gas and liquid phases, and hydrate formation. Chemical potential gradients induced by temperature, pressure, and pore water or host sediment chemistry can drive these processes. A series of tests were performed on a formerly natural methane-hydrate-bearing core sample from the BPX-DOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test Well, in order to observe hydrate formation and morphology within this natural sediment, and changes over time using X-ray computed tomography (CT). Long-term observations (over several weeks) of methane hydrate in natural sediments were made to investigate spatial changes in hydrate saturation in the core. During the test sequence, mild buffered thermal and pressure oscillations occurred within the sample in response to laboratory temperature changes. These oscillations were small in magnitude, and conditions were maintained well within the hydrate stability zone.

  14. Can propane school buses save money and provide other benefits...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Can propane school buses save money and provide other benefits? October 1, 2014 Tweet EmailPrint School districts across the country are looking for ways to save money and be more...

  15. VEE-0040- In the Matter of Western Star Propane, Inc.

    Broader source: Energy.gov [DOE]

    On February 18, 1997, Western Star Propane, Inc. (Western) filed an Application for Exception with the Office of Hearings and Appeals (OHA) of the Department of Energy (DOE). In its application,...

  16. VEE-0060- In the Matter of Blakeman Propane, Inc.

    Broader source: Energy.gov [DOE]

    On May 11, 1999, Blakeman Propane, Inc. (Blakeman) of Moorcroft, Wyoming, filed an Application for Exception with the Office of Hearings and Appeals (OHA) of the Department of Energy (DOE). In its...

  17. Residential home heating oil and propane survey, 1991--1992

    SciTech Connect (OSTI)

    Not Available

    1992-05-01T23:59:59.000Z

    This report contains pricing and consumption data on heating oils and propane for the Maine residential sector during the heating season 1991--1992. The information was gathered by survey. (VC)

  18. Series 50 propane-fueled Nova bus: Engine development, installation, and field trials

    SciTech Connect (OSTI)

    Smith, B.

    1999-01-01T23:59:59.000Z

    The report describes a project to develop the Detroit Diesel series 50 liquefied propane gas (LPG) heavy-duty engine and to conduct demonstrations of LPG-fuelled buses at selected sites (Halifax Regional Municipality and three sites in the United States). The project included five main elements: Engine development and certification, chassis re-engineering and engine installation, field demonstration, LPG fuel testing, and LPG fuel variability testing. Lessons learned with regard to engine design and other issues are discussed, and recommendations are made for further development and testing.

  19. Selection of best drilling, completion and stimulation method for coalbed methane reservoirs

    E-Print Network [OSTI]

    Ramaswamy, Sunil

    2008-10-10T23:59:59.000Z

    reservoirs, coalbed methane (CBM) reservoirs, gas shales, oil shales, tar sands, heavy oil and gas hydrates. 1 All natural resources, such as gold, zinc, oil, gas, etc., are distributed log normally in nature. John Masters introduced the concept for oil...

  20. Selection of best drilling, completion and stimulation method for coalbed methane reservoirs

    E-Print Network [OSTI]

    Ramaswamy, Sunil

    2009-05-15T23:59:59.000Z

    reservoirs, coalbed methane (CBM) reservoirs, gas shales, oil shales, tar sands, heavy oil and gas hydrates. 1 All natural resources, such as gold, zinc, oil, gas, etc., are distributed log normally in nature. John Masters introduced the concept for oil...

  1. Southeast Propane AutoGas Development Program | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOriginEducationVideo »UsageSecretaryVideos Solid-State LightingSouth CarolinaEnergy2 DOE

  2. Southeast Propane AutoGas Development Program | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOriginEducationVideo »UsageSecretaryVideos Solid-State LightingSouth CarolinaEnergy2 DOE1

  3. Southeast Propane AutoGas Development Program | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOriginEducationVideo »UsageSecretaryVideos Solid-State LightingSouth CarolinaEnergy2 DOE10

  4. Sorption-Enhanced Synthetic Natural Gas (SNG) Production from...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sorption-Enhanced Synthetic Natural Gas (SNG) Production from Syngas: A Novel Process Combining CO Methanation, Water-Gas Shift, Sorption-Enhanced Synthetic Natural Gas (SNG)...

  5. Strategies for gas production from oceanic Class 3 hydrate accumulations

    E-Print Network [OSTI]

    Moridis, George J.; Reagan, Matthew T.

    2007-01-01T23:59:59.000Z

    coexistence of aqueous, gas and hydrate phases, indicatingIntrinsic Rate of Methane Gas Hydrate Decomposition”, Chem.Makogon, Y.F. , “Gas hydrates: frozen energy,” Recherche

  6. Production of olefins by oxidative dehydrogenation of propane and butane over monoliths at short contact times

    SciTech Connect (OSTI)

    Huff, M.; Schmidt, L.D. [Univ. of Minnesota, Minneapolis, MN (United States)] [Univ. of Minnesota, Minneapolis, MN (United States)

    1994-09-01T23:59:59.000Z

    The autothermal production of olefins from propane or n-butane by oxidative dehydrogenation and cracking in air or oxygen at atmospheric pressure over noble metal coated ceramic foam monoliths at contact times of {approximately}5 milliseconds has been studied. On Pt, synthesis gas (CO and H{sub 2}) dominates near its stoichiometry, while olefin production dominates at higher fuel-to-oxygen ratios. No carbon buildup is observed, and catalysts exhibit no deactivation over at least several days. On Rh, primarily synthesis gas is produced under these conditions, while on Pd, carbon deposition rapidly deactivates the catalyst. The authors observed up to 65% selectivity to olefins at nearly 100% conversion of propane or n-butane with a catalyst contact time of 5 ms. Ethylene selectivity is maximized by increasing the reaction temperature, either by preheating the reactants or by using oxygen enriched air. Propylene selectivity is maximized by lower temperature and shorter catalyst contact time. Very small amounts alkanes and higher molecular weight species are obtained, suggesting that a homogeneous pyrolysis mechanism is not occurring. A very simple reaction mechanism appears to explain the observed product distribution. Reactions are initiated by oxidative dehydrogenation of the alkane by adsorbed oxygen to form a surface alkyl. On Pt, {beta}-hydrogen and {beta}-alkyl elimination reactions of adsorbed alkyl dominate which lead to olefin production rather than cracking to C{sub s} and H{sub s}. 24 refs., 14 figs., 4 tabs.

  7. Methane Hydrate Field Program

    SciTech Connect (OSTI)

    None

    2013-12-31T23:59:59.000Z

    This final report document summarizes the activities undertaken and the output from three primary deliverables generated during this project. This fifteen month effort comprised numerous key steps including the creation of an international methane hydrate science team, determining and reporting the current state of marine methane hydrate research, convening an international workshop to collect the ideas needed to write a comprehensive Marine Methane Hydrate Field Research Plan and the development and publication of that plan. The following documents represent the primary deliverables of this project and are discussed in summary level detail in this final report. • Historical Methane Hydrate Project Review Report • Methane Hydrate Workshop Report • Topical Report: Marine Methane Hydrate Field Research Plan • Final Scientific/Technical Report

  8. Selective dehydrogenation of propane over novel catalytic materials

    SciTech Connect (OSTI)

    Sault, A.G.; Boespflug, E.P.; Martino, A.; Kawola, J.S.

    1998-02-01T23:59:59.000Z

    The conversion of small alkanes into alkenes represents an important chemical processing area; ethylene and propylene are the two most important organic chemicals manufactured in the U.S. These chemicals are currently manufactured by steam cracking of ethane and propane, an extremely energy intensive, nonselective process. The development of catalytic technologies (e.g., selective dehydrogenation) that can be used to produce ethylene and propylene from ethane and propane with greater selectivity and lower energy consumption than steam cracking will have a major impact on the chemical processing industry. This report details a study of two novel catalytic materials for the selective dehydrogenation of propane: Cr supported on hydrous titanium oxide ion-exchangers, and Pt nanoparticles encapsulated in silica and alumina aerogel and xerogel matrices.

  9. 2, 11971241, 2005 Control of methane

    E-Print Network [OSTI]

    Boyer, Edmond

    Version Interactive Discussion EGU Abstract The North Sea hosts large coal, oil and gas reservoirs of giant sulphide- oxidizing bacteria above patches of black sediments and carbonate crusts, which are exposed 10 to 50 cm above seafloor forming small reefs. These Methane-Derived Au- thigenic Carbonates

  10. Experimental studies of steam-propane injection for the Duri intermediate crude oil 

    E-Print Network [OSTI]

    Hendroyono, Arief

    2003-01-01T23:59:59.000Z

    Laboratory experimental studies were carried out to better understand production mechanisms involved in steam-propane injection and to investigate effects of expected field pressure and temperature conditions on steam-propane injection...

  11. Emissions from In-Use NG, Propane, and Diesel Fueled Heavy Duty...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    In-Use NG, Propane, and Diesel Fueled Heavy Duty Vehicles Emissions from In-Use NG, Propane, and Diesel Fueled Heavy Duty Vehicles Emissions tests of in-use heavy-duty vehicles...

  12. Consequences of propene and propane on plasma remediation of NOx Rajesh Doraia)

    E-Print Network [OSTI]

    Kushner, Mark

    Consequences of propene and propane on plasma remediation of NOx Rajesh Doraia) Department exhausts with hydrocarbons propane (C3H8) and propene (C3H6) has been investigated. In general

  13. Zeolitic Imidazolate Frameworks for Kinetic Separation of Propane and David H. Olson,

    E-Print Network [OSTI]

    Li, Jing

    Zeolitic Imidazolate Frameworks for Kinetic Separation of Propane and Propene Kunhao Li, David H the first examples of MMOFs that are capable of kinetic separation of propane and propene (propylene), which

  14. Experimental studies of steam-propane injection for the Duri intermediate crude oil

    E-Print Network [OSTI]

    Hendroyono, Arief

    2003-01-01T23:59:59.000Z

    Laboratory experimental studies were carried out to better understand production mechanisms involved in steam-propane injection and to investigate effects of expected field pressure and temperature conditions on steam-propane injection...

  15. Methane Hydrate Program

    Office of Environmental Management (EM)

    Biofilms in Fracture-Dominated Sediment that Anaerobically Oxidize Methane. Applied and Environmental Microbiology, 77, 7 pp. Brunner, C., Ingram, W., Meyers, S.,...

  16. Methane Digester Loan Program

    Broader source: Energy.gov [DOE]

    Established in 1998, the Minnesota Dept. of Agriculture Methane Digester Loan Program helps livestock producers install on-farm anaerobic digesters used for the production of electricity by...

  17. Conversion of methane and acetylene into gasoline range hydrocarbons

    E-Print Network [OSTI]

    Alkhawaldeh, Ammar

    2000-01-01T23:59:59.000Z

    Conversion Apparatus. . . 20 22 Temperature Profile Inside the Reactor. . 30 Methane and Acetylene Conversion over Time on Stream, T = 412 C, Molar Feed Ratio = 6/I (CH4/CqHr). . 36 Mass Flow Rate (g/s) of the Effluent Gas (Unreacted Methane... and Acetylene, Isobutane, Ethylene, and Nitrogen) from the Reactor Integrated over Time on Stream. 40 Mass Flow Rate (g/s) of the Gas Products (Isobutane and Ethylene) Integrated over Time on Stream. 41 Methane and Acetylene Conversion over Time on Stream...

  18. Alternative Fuels Data Center: Propane Powers Airport Shuttles in New

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduceNew HampshirePropaneOrleans Propane

  19. Propane Vehicle and Infrastructure Codes and Standards Chart (Revised) (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2011-02-01T23:59:59.000Z

    This chart shows the SDOs responsible for leading the support and development of key codes and standards for propane.

  20. METHANE IN SUBSURFACE: MATHEMATICAL MODELING AND COMPUTATIONAL CHALLENGES

    E-Print Network [OSTI]

    Peszynska, Malgorzata

    ), in collaboration with the U.S. Geological Survey (USGS), and an industry consortium led by Chevron, in gas hydrate as an energy resource. Although the existence of gas hydrates in nature has been known for many decades, our and energy recovery involving the evolution of methane gas in the subsurface. In particular, we develop

  1. Novel Pt/Mg(In)(Al)O catalysts for ethane and propane dehydrogenation Pingping Sun a

    E-Print Network [OSTI]

    Iglesia, Enrique

    Novel Pt/Mg(In)(Al)O catalysts for ethane and propane dehydrogenation Pingping Sun a , Georges and propane dehydrogenation reactions are strongly dependent on the bulk In/Pt ratio. For both reactants to alkene was nearly 100%. Coke deposition was observed after catalyst use for either ethane or propane

  2. A KINETIC STUDY OF AEROBIC PROPANE UPTAKE AND COMETABOLIC DEGRADATION OF CHLOROFORM,

    E-Print Network [OSTI]

    Semprini, Lewis

    A KINETIC STUDY OF AEROBIC PROPANE UPTAKE AND COMETABOLIC DEGRADATION OF CHLOROFORM, CIS the behavior of different consortiums of aerobic propane-utilizing microorganisms, with respect to both the lag time for growth after exposure to propane, and their ability to transform three chlorinated aliphatic

  3. Isotopic Tracer Studies of Reaction Pathways for Propane Oxidative Dehydrogenation on Molybdenum Oxide Catalysts

    E-Print Network [OSTI]

    Iglesia, Enrique

    Isotopic Tracer Studies of Reaction Pathways for Propane Oxidative Dehydrogenation on Molybdenum of propane over ZrO2-supported MoOx catalysts. Competitive reactions of C3H6 and CH3 13 CH2CH3 showed combustion of propene, or by direct combustion of propane. A mixture of C3H8 and C3D8 undergoes oxidative

  4. Functional Characterization of Propane-Enhanced N-Nitrosodimethylamine Degradation by

    E-Print Network [OSTI]

    Alvarez-Cohen, Lisa

    ARTICLE Functional Characterization of Propane-Enhanced N-Nitrosodimethylamine Degradation by Two: Propane-induced cometabolic degradation of n-nitrosodimethylamine (NDMA) by two propanotrophs is characterized through kinetic, gene presence, and expression studies. After growth on propane, resting cells

  5. Ceramic microreactors for on-site hydrogen production from high temperature steam reforming of propane{

    E-Print Network [OSTI]

    Kenis, Paul J. A.

    of propane{ Christian, Michael Mitchell and Paul J. A. Kenis* Received 31st May 2006, Accepted 10th August of propane into hydrogen at temperatures between 800 and 1000 uC. We characterized these microreactors. Kinetic analysis using a power law model showed reaction orders of 0.50 and 20.23 with respect to propane

  6. Fourier transform microwave spectrum of the propane-water complex: A prototypical water-hydrophobe system

    E-Print Network [OSTI]

    Cohen, Ronald C.

    Fourier transform microwave spectrum of the propane-water complex: A prototypical water) The Fourier transform microwave spectrum of the propane-water complex (C3H,-H,O) has been observed and analyzed. This spectrum includes transitions assigned to propane complexed with both the ortho and para

  7. Improved Product-Per-Glucose Yields in P450-Dependent Propane Biotransformations

    E-Print Network [OSTI]

    Arnold, Frances H.

    ARTICLE Improved Product-Per-Glucose Yields in P450-Dependent Propane Biotransformations Using propane monooxygenase prepared by directed evolu- tion [P450PMOR2; Fasan et al. (2007); Angew Chem Int Ed of the energy source (glucose) in the propane biotransformation com- pared to the native E. coli strain. Using

  8. Catalytic Properties of Supported MoO3 Catalysts for Oxidative Dehydrogenation of Propane

    E-Print Network [OSTI]

    Iglesia, Enrique

    Catalytic Properties of Supported MoO3 Catalysts for Oxidative Dehydrogenation of Propane Kaidong The effects of MoOx structure on propane oxidative dehydrogenation (ODH) rates and selectivity were examined with those obtained on MoOx/ZrO2. On MoOx/Al2O3 catalysts, propane turnover rate increased with increasing Mo

  9. High propylene/propane adsorption selectivity in a copper(catecholate)-decorated porous organic

    E-Print Network [OSTI]

    High propylene/propane adsorption selectivity in a copper(catecholate)-decorated porous organic and propane isotherms measured at ambient temperatures and ideal adsorption solution theory (IAST) calculations revealed increasing propylene/propane selectivities with increasing pressures. The eld of highly

  10. Layering and orientational ordering of propane on graphite: An experimental and simulation study

    E-Print Network [OSTI]

    Borguet, Eric

    Layering and orientational ordering of propane on graphite: An experimental and simulation study 2002; accepted 30 July 2002 We report the results of an experimental and theoretical study of propane and experiments show that propane adsorbs in a layer-by-layer fashion and exhibits continuous growth beyond

  11. Selective adsorption of ethylene over ethane and propylene over propane in the metalorganic

    E-Print Network [OSTI]

    Selective adsorption of ethylene over ethane and propylene over propane in the metal in the energy costs associated with the cryogenic separation of ethylene­ethane and propylene­propane mixtures adsorption data for ethylene, ethane, propylene, and propane at 45, 60, and 80 C for the entire series

  12. Experimental Study of Propane-Fueled Pulsed Detonation Rocket Frank K. Lu,* Jason M. Meyers,

    E-Print Network [OSTI]

    Texas at Arlington, University of

    1 Experimental Study of Propane-Fueled Pulsed Detonation Rocket Frank K. Lu,* Jason M. Meyers in comparison to cases without the spiral. Tests through a range of cycle frequencies up to 20 Hz in oxygen-propane spiral in a pulsed detonation engine operating with propane and oxygen. A high-energy igniter is used

  13. Structural and dynamic properties of propane coordinated to TpRh(CNR) from a confrontation

    E-Print Network [OSTI]

    Jones, William D.

    Structural and dynamic properties of propane coordinated to TpRh(CNR) from a confrontation between] in interaction with propane. Two complexes have been found as minima coordinated through either a methyl the methylene complex of propane into a methyl complex of pro- pane. This latter reaction has a much lower

  14. Ionization Spectroscopy of Conformational Isomers of Propanal: The Origin of the Conformational Preference

    E-Print Network [OSTI]

    Kim, Sang Kyu

    Ionization Spectroscopy of Conformational Isomers of Propanal: The Origin of the Conformational conformational isomers of propanal, cis and gauche, are investigated by the vacuum-UV mass- analyzed thresholdV and 9.9516 ( 0.0006 eV, respectively. cis-Propanal, which is the more stable conformer in the neutral

  15. PROPANE -C3H8 MSDS (Document # 001045) PAGE 1 OF 8 MATERIAL SAFETY DATA SHEET

    E-Print Network [OSTI]

    Choi, Kyu Yong

    PROPANE - C3H8 MSDS (Document # 001045) PAGE 1 OF 8 MATERIAL SAFETY DATA SHEET Prepared to U in an emergency? 1. PRODUCT IDENTIFICATION CHEMICAL NAME; CLASS: PROPANE - C3H8 Document Number: 001045 PRODUCT IN AIR ACGIH OSHA TLV STEL PEL STEL IDLH OTHER ppm ppm ppm ppm ppm Propane 74-98-6 > 96.0 Simple

  16. Coleman Two Burner Stove The Coleman Matchlight 2-Burner Propane Stove is especially designed for outdoor

    E-Print Network [OSTI]

    Walker, Lawrence R.

    Coleman Two Burner Stove The Coleman Matchlight 2-Burner Propane Stove is especially designed-burner propane stove has a high-pressure regulator that ensures a constant flame regardless of weather propane stove has a removable nickel-chrome-plated grate that makes for easy cleaning. The aluminized

  17. Absorption du rayonnement 12 et 8 millimtres par les vapeurs de propane sous pression

    E-Print Network [OSTI]

    Boyer, Edmond

    Absorption du rayonnement 12 et 8 millimètres par les vapeurs de propane sous pression A. Battaglia des pertes diélectriques (03B5") présentées par le propane gazeux aux fréquences de 24 et 36 GHz, à la Birnbaum. Abstract. 2014 Experimental study of dielectric losses (03B5") presented by gaseous propane

  18. Dehydrogenation of Propane to Propylene over Supported Model NiAu Catalysts

    E-Print Network [OSTI]

    Goodman, Wayne

    Dehydrogenation of Propane to Propylene over Supported Model Ni­Au Catalysts Zhen Yan · Yunxi Yao 2012 Ó Springer Science+Business Media, LLC 2012 Abstract Hydrogenolysis and dehydrogenation of propane. For the conversionofpropane in the presence of hydrogen, the dehydrogenation of propane to propylene was observed onthe Ni

  19. Synthesis and Characterization of Gold Clusters Ligated with 1,3-Bis(dicyclohexylphosphino)propane

    SciTech Connect (OSTI)

    Johnson, Grant E.; Priest, Thomas A.; Laskin, Julia

    2013-09-01T23:59:59.000Z

    In this multidisciplinary study we combine chemical reduction synthesis of novel gold clusters in solution with high-resolution analytical mass spectrometry (MS) to gain insight into the composition of the gold clusters and how their size, ionic charge state and ligand substitution influences their gas-phase fragmentation pathways. Ultra small cationic gold clusters ligated with 1,3-bis(dicyclohexylphosphino)propane (DCPP) were synthesized for the first time and introduced into the gas phase using electrospray ionization (ESI). Mass-selected cluster ions were fragmented employing collision induced dissociation (CID) and the product ions were analysed using MS. The solutions were found to contain the multiply charged cationic gold clusters Au9L43+, Au13L53+, Au6L32+, Au8L32+ and Au10L42+ (L = DCPP). The gas-phase fragmentation pathways of these cluster ions were examined systematically employing CID combined with MS. In addition, CID experiments were performed on related gold clusters of the same size and ionic charge state but capped with 1,3-bis(diphenylphosphino)propane (DPPP) ligands containing phenyl functional groups at the two phosphine centers instead of cyclohexane rings. It is shown that this relatively small change in the molecular substitution of the two phosphine centers in diphosphine ligands (C6H11 versus C6H5) exerts a pronounced influence on the size of the species that are preferentially formed in solution during reduction synthesis as well as the gas-phase fragmentation channels of otherwise identical gold cluster ions. The mass spectrometry results indicate that in addition to the length of the alkyl chain between the two phosphine centers, the substituents at the phosphine centers also play a crucial role in determining the composition, size and stability of diphosphine ligated gold clusters synthesized in solution.

  20. RMOTC - News - Methane Test 2013

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Energy (DOE), Los Alamos National Laboratory (LANL) and Chevron Corporation. The test was a methane controlled-release experiment and was designed to measure methane...

  1. Hybrid Neural Network for Gas Analysis Measuring System Kazimierz Brudzewski

    E-Print Network [OSTI]

    Osowski, Stanislaw

    mixtures of air with these four pollutants. The signals obtained from the sensors have been processed using with hybrid neural network, can be used to determine the individual analyte concentrations in the mixture as pollutants: carbon oxide, methane, propane/buthane and methanol vapour. A small array of five semiconductor

  2. Zeolitic imidazolate frameworks for kinetic separation of propane and propene

    SciTech Connect (OSTI)

    Li, Jing; Li, Kunhao; Olson, David H.

    2014-08-05T23:59:59.000Z

    Zeolitic Imidazolate Frameworks (ZIFs) characterized by organic ligands consisting of imidazole ligands that are either essentially all 2-chloroimidazole ligands or essentially all 2-bromoimidazole ligands are disclosed. Methods for separating propane and propene with the ZIFs of the present invention, as well as other ZIFs, are also disclosed.

  3. Experimental study on the formation and dissociation conditions of methane hydrates in porous media

    E-Print Network [OSTI]

    Jung, Woodong

    2002-01-01T23:59:59.000Z

    hydrates formed by methane gas and pure water in porous media. Methane gas hydrates were formed in a cell packed with 0.177-mm (0.007 in) diameter single sand (U.S. Sieve Series Designation Mesh No. 80) and 0.420-mm (0.017 in) diameter single sand (U...

  4. SCREENING TESTS FOR IMPROVED METHANE CRACKING MATERIALS

    SciTech Connect (OSTI)

    Klein, J; Jeffrey Holder, J

    2007-07-16T23:59:59.000Z

    Bench scale (1 to 6 gram) methane cracking tests have been performed on a variety of pure elements, some alloys, and SAES{reg_sign} commercial getters St 101, St 198, St 707, St 737, and St 909 to determine methane cracking performance (MCP) of 5% methane in a helium carrier at 700 C, 101.3 kPa (760 torr) with a 10 sccm feed. The MCP was almost absent from some materials tested while others showed varying degrees of MCP. Re, Cr, V, Gd, and Mo powders had good MCP, but limited capacities. Nickel supported on kieselguhr (Ni/k), a Zr-Ni alloy, and the SAES{reg_sign} getters had good MCP in a helium carrier. The MCP of these same materials was suppressed in a hydrogen carrier stream and the MCP of the Zr-based materials was reduced by nitride formation when tested with a nitrogen carrier gas.

  5. Screening tests for improved methane cracking materials

    SciTech Connect (OSTI)

    Klein, J. E.; Hoelder, J. S. [Savannah River National Laboratory, Aiken, SC 29808 (United States)

    2008-07-15T23:59:59.000Z

    Bench scale (1 to 6 gram) methane cracking tests have been performed on a variety of pure elements, some alloys, and SAES{sup R} commercial getters St 101, St 198, St 707, St 737, and St 909 to determine methane cracking performance (MCP) of 5% methane in a helium carrier at 700 deg.C, 101.3 kPa (760 torr) with a 10 seem feed. The MCP was almost absent from some materials tested while others showed varying degrees of MCP. Re, Cr, V, Gd, and Mo powders had good MCP, but limited capacities. Nickel supported on kieselguhr (Ni/k), a Zr-Ni alloy, and the SAESr getters had good MCP in a helium carrier. The MCP of these same materials was suppressed in a hydrogen carrier stream and the MCP of the Zr-based materials was reduced by nitride formation when tested with a nitrogen carrier gas. (authors)

  6. Experimental comparison of hot water/propane injection to steam/propane injection for recovery of heavy oil 

    E-Print Network [OSTI]

    Nesse, Thomas

    2005-02-17T23:59:59.000Z

    , attempts have been made to inject hot water instead of steam. The results have all been rather poor, the major problem being low sweep efficiency. The hot water just doesn?t enhance oil recovery enough. Adding propane to the steam injected in the reservoir...

  7. Experimental comparison of hot water/propane injection to steam/propane injection for recovery of heavy oil

    E-Print Network [OSTI]

    Nesse, Thomas

    2005-02-17T23:59:59.000Z

    , attempts have been made to inject hot water instead of steam. The results have all been rather poor, the major problem being low sweep efficiency. The hot water just doesn?t enhance oil recovery enough. Adding propane to the steam injected in the reservoir...

  8. Effect of a current polarisation on BIMEVOX membranes for oxidation of propane in a Catalytic Dense Membrane

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Effect of a current polarisation on BIMEVOX membranes for oxidation of propane in a Catalytic Dense of propane under OCV and under electrical bias. The propane conversion remained constantly equal to 12 by partial oxidation and oxidative dehydrogenation of propane, respectively. An anodic polarisation led

  9. Isotopic Tracer Studies of Propane Reactions on H-ZSM5 Zeolite Joseph A. Biscardi and Enrique Iglesia*

    E-Print Network [OSTI]

    Iglesia, Enrique

    Isotopic Tracer Studies of Propane Reactions on H-ZSM5 Zeolite Joseph A. Biscardi and Enrique unlabeled products from mixtures of propene and propane-2-13C reactants. Aromatic products of propane-2-13C-Parmer) that allowed differential reactor operation (propane reactions were

  10. Enhancement of Biogenic Coalbed Methane Production and Back Injection of Coalbed Methane Co-Produced Water

    SciTech Connect (OSTI)

    Song Jin

    2007-05-31T23:59:59.000Z

    Biogenic methane is a common constituent in deep subsurface environments such as coalbeds and oil shale beds. Coalbed methane (CBM) makes significant contributions to world natural gas industry and CBM production continues to increase. With increasing CBM production, the production of CBM co-produced water increases, which is an environmental concern. This study investigated the feasibility in re-using CBM co-produced water and other high sodic/saline water to enhance biogenic methane production from coal and other unconventional sources, such as oil shale. Microcosms were established with the selected carbon sources which included coal, oil shale, lignite, peat, and diesel-contaminated soil. Each microcosm contained either CBM coproduced water or groundwater with various enhancement and inhibitor combinations. Results indicated that the addition of nutrients and nutrients with additional carbon can enhance biogenic methane production from coal and oil shale. Methane production from oil shale was much greater than that from coal, which is possibly due to the greater amount of available Dissolved Organic Carbon (DOC) from oil shale. Inconclusive results were observed from the other sources since the incubation period was too low. WRI is continuing studies with biogenic methane production from oil shale.

  11. Methane coupling by membrane reactor. First quarterly report, 1997

    SciTech Connect (OSTI)

    Ma, Yi Hua

    1997-05-01T23:59:59.000Z

    The Mn-W-Na/SiO{sub 2} catalyst was studied by running the methane coupling reactions at different methane to oxygen ratios, temperatures and dilution gas flow rates. For methane to oxygen ratios less than 3, the C{sub 2} yield was almost the same; and C{sub 2} yield began to decrease as the methane to oxygen ratio was further increased. The optimal temperature observed was around 800{degrees}C, where the C{sub 2} yield reached a maximum value. Increasing the dilution gas (helium) flow rate resulted in higher C{sub 2} selectivity; however, after a certain dilution gas flow rate the C{sub 2} yield began to decrease due to a decrease in methane conversion as a result of the reduced contact time. The stability study of the catalyst showed that, after five successive run cycles, the C{sub 2} yield obtained decreased from 24% to 19% at 780 {degrees}C, and methane, oxygen and helium flow rates of 12.2, 4.1, and 44. 3 mm/min, respectively. XRD analysis showed that, after the reaction, the XRD peaks of the cristabolite and Na{sub 2}WO{sub 4} phases in the catalyst became smaller than those in the fresh catalyst, and that at least one new, unidentified phase was observed. Mn-W-Na/SiO{sub 2} catalyst was used as the methane oxidative coupling catalyst in a porous membrane reactor and its performance was compared with a packed reactor operated at similar conditions. Although the membrane reactor showed lower methane conversion at the same reaction conditions, it gave higher C{sub 2} selectivity and C{sub 2} yield at similar methane conversions.

  12. Working Draft

    Office of Environmental Management (EM)

    gases-including nitrogen, carbon dioxide, hydrogen sulfide, methane, ethane, and propane-and butanes and other volatile liquids) composition, and flash gas composition....

  13. Note: this is a web-based PDF publication revised on 10/8/12 that is regularly updated. Consult http://extension.psu.edu/water to

    E-Print Network [OSTI]

    Boyer, Elizabeth W.

    from mercaptan; a chemical odorant added to methane by a gas company before distribution to help and propane) in the home. Some b

  14. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Conventional original equipment manufacturer vehicles altered to operate on propane, natural gas, methane, ethanol, or electricity are classified as aftermarket AFV...

  15. Enhanced Microbial Pathways for Methane Production from Oil Shale

    SciTech Connect (OSTI)

    Paul Fallgren

    2009-02-15T23:59:59.000Z

    Methane from oil shale can potentially provide a significant contribution to natural gas industry, and it may be possible to increase and continue methane production by artificially enhancing methanogenic activity through the addition of various substrate and nutrient treatments. Western Research Institute in conjunction with Pick & Shovel Inc. and the U.S. Department of Energy conducted microcosm and scaled-up reactor studies to investigate the feasibility and optimization of biogenic methane production from oil shale. The microcosm study involving crushed oil shale showed the highest yield of methane was produced from oil shale pretreated with a basic solution and treated with nutrients. Incubation at 30 C, which is the estimated temperature in the subsurface where the oil shale originated, caused and increase in methane production. The methane production eventually decreased when pH of the system was above 9.00. In the scaled-up reactor study, pretreatment of the oil shale with a basic solution, nutrient enhancements, incubation at 30 C, and maintaining pH at circumneutral levels yielded the highest rate of biogenic methane production. From this study, the annual biogenic methane production rate was determined to be as high as 6042 cu. ft/ton oil shale.

  16. Natural Gas Variability In California: Environmental Impacts And Device Performance Combustion Modeling of Pollutant Emissions From a Residential Cooking Range

    SciTech Connect (OSTI)

    Tonse, S. R.; Singer, B. C.

    2011-07-01T23:59:59.000Z

    As part of a larger study of liquefied natural gas impacts on device performance and pollutant emissions for existing equipment in California, this report describes a cmoputer modeling study of a partially premixed flame issueing from a single cooktop burner port. The model consisted of a reactive computational fluid dynamics three-dimensional spatial grid and a 71-species chemical mechanism with propane combustion capability. Simulations were conducted with a simplified fuel mixture containing methane, ethane, and propane in proportions that yield properties similar to fuels distributed throughout much of California now and in recent years (baseline fuel), as well as with two variations of simulated liquefied natural gas blends. A variety of simulations were conducted with baseline fuel to explore the effect of several key parameters on pollutant formation and other flame characteristics. Simulations started with fuel and air issuing through the burner port, igniting, and continuing until the flame was steady with time. Conditions at this point were analyzed to understand fuel, secondary air and reaction product flows, regions of pollutant formation, and exhaust concentrations of carbon monoxide, nitric oxide and formaldehyde. A sensitivity study was conducted, varying the inflow parameters of this baseline gs about real-world operating conditions. Flame properties responded as expected from reactive flow theory. In the simulation, carbon monoxide levels were influenced more by the mixture's inflow velocity than by the gas-to-air ratio in the mixture issuing from the inflow port. Additional simulations were executed at two inflow conditions - high heat release and medium heat release - to examine the impact of replacing the baseline gas with two mixtures representative of liquefied natural gas. Flame properties and pollutant generation rates were very similar among the three fuel mixtures.

  17. National Grid (Gas) – Residential EnergyWise Rebate Programs

    Broader source: Energy.gov [DOE]

    National Grid's EnergyWise programs encourage energy efficiency amongst its residential customers. Interested customers who heat with gas, oil, or propane should schedule a free home energy audit...

  18. Home Energy Score Program Overview for the American Gas Association...

    Energy Savers [EERE]

    Here we can enter either the efficiency value -- the AFUE in the case of gas or propane or oil. If you don't know that, you can use an installed year. This gives a...

  19. Quarterly review of methane from coal seams Technology. Volume 7, Numbers 1 and 2. October 1989

    SciTech Connect (OSTI)

    Not Available

    1989-01-01T23:59:59.000Z

    Contents include: basin activities--(western Washington, Powder River Basin, Wyoming, Greater Green River Basin, Wyoming and Colorado, Piceance Basin, Colorado, San Juan Basin, Colorado and New Mexico, Raton Basin, Colorado and New Mexico, Black Warrior Basin, Alabama); features--(research in small-scale gas processing, GRI publications on coalbed methane, coalbed methane information sources); methane from coal seams research--(multiple coal seams project, hydrologic characterization of coal seams, spalling and the development of a hydraulic-fracturing strategy for coal, geologic evaluation of critical production parameters for coalbed methane resources, permeability changes resulting from gas desorption); technical events; departments.

  20. DOE Launches Natural Gas Infrastructure R&D Program Enhancing...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Launches Natural Gas Infrastructure R&D Program Enhancing Pipeline and Distribution System Operational Efficiency, Reducing Methane Emissions DOE Launches Natural Gas...

  1. Methanation in catalyst-sprayed tube wall reactors: a review

    SciTech Connect (OSTI)

    Pennline, H. W.; Schehl, R. R.; Haynes, W. P.; Forney, A. J.

    1980-09-01T23:59:59.000Z

    The design and operation of catalyst-sprayed tube wall reactors for methanation are discussed. Reactor tubes were either coated on the inner surface or on the outer surface with a Raney nickel catalyst. A liquid coolant, which was opposite the catalyst-reactant gas-side, removed the heat of methanation. Catalyst performance, reactor operating conditions, spent catalyst analyses, and other results are presented for five PDU tests.

  2. Methyl chloride via oxyhydrochlorination of methane: A building block for chemicals and fuels from natural gas. Quarterly technical progress report No. 01, September 30, 1996--December 31, 1996

    SciTech Connect (OSTI)

    Wineland, J.

    1997-01-16T23:59:59.000Z

    The objectives of this cooperative agreement are to develop the oxyhydrochlorination (OHC) process for the conversion of methane to methyl chloride. In the first Phase of the project, Dow Corning has developed a stable selective catalyst and demonstrated the technology on a laboratory and a pilot plant scale. Specific tasks to achieve these objectives have been developed as follows: TASK 1 Fundamental Technical and Economic Evaluation TASK 2 Catalyst Selection Optimization and Characterization Studies TASK 3 Pilot Plant Design TASK 4 Pilot Plant Detailed Engineering, Procurement and Construction TASK 5 Pilot Plant Startup and Operation TASK 6 Pilot Plant Process Optimization TASK 7 Pilot Plant Extended Operation TASK 8 Pilot Plant Economic Evaluation/Scale-up Decision Significant progress has been completed in Task 1 with the objective to complete a fundamental technical and economic evaluation of learning gathered the Phase I effort of this project. A decision to proceed with the project will be made after completion of this Task. A computer model of the reactor system has been developed, which includes heat and mass transfer effects as well as reactions. Model validation is in progress. The Absorber/Stripper technology evaluated and implemented on the Phase I PDU to recover chlorocarbons (including methyl chloride) from reaction products has been scaled to evaluate economics for a commercial scale plant. In a parallel exercise, alternate recovery technologies were investigated for economic evaluation, to assure that the minimum capital option is pursued for the Phase II design. Commercial scale plant equipment and total plant costs are being evaluated using information from the Phase I PDU, reactor modeling and recovery system evaluation to estimate capital and operating costs for a commercial scale OHC unit.

  3. Methane Recovery from Hydrate-bearing Sediments

    SciTech Connect (OSTI)

    J. Carlos Santamarina; Costas Tsouris

    2011-04-30T23:59:59.000Z

    Gas hydrates are crystalline compounds made of gas and water molecules. Methane hydrates are found in marine sediments and permafrost regions; extensive amounts of methane are trapped in the form of hydrates. Methane hydrate can be an energy resource, contribute to global warming, or cause seafloor instability. This study placed emphasis on gas recovery from hydrate bearing sediments and related phenomena. The unique behavior of hydrate-bearing sediments required the development of special research tools, including new numerical algorithms (tube- and pore-network models) and experimental devices (high pressure chambers and micromodels). Therefore, the research methodology combined experimental studies, particle-scale numerical simulations, and macro-scale analyses of coupled processes. Research conducted as part of this project started with hydrate formation in sediment pores and extended to production methods and emergent phenomena. In particular, the scope of the work addressed: (1) hydrate formation and growth in pores, the assessment of formation rate, tensile/adhesive strength and their impact on sediment-scale properties, including volume change during hydrate formation and dissociation; (2) the effect of physical properties such as gas solubility, salinity, pore size, and mixed gas conditions on hydrate formation and dissociation, and it implications such as oscillatory transient hydrate formation, dissolution within the hydrate stability field, initial hydrate lens formation, and phase boundary changes in real field situations; (3) fluid conductivity in relation to pore size distribution and spatial correlation and the emergence of phenomena such as flow focusing; (4) mixed fluid flow, with special emphasis on differences between invading gas and nucleating gas, implications on relative gas conductivity for reservoir simulations, and gas recovery efficiency; (5) identification of advantages and limitations in different gas production strategies with emphasis; (6) detailed study of CH4-CO2 exchange as a unique alternative to recover CH4 gas while sequestering CO2; (7) the relevance of fines in otherwise clean sand sediments on gas recovery and related phenomena such as fines migration and clogging, vuggy structure formation, and gas-driven fracture formation during gas production by depressurization.

  4. Experimental study on transmission of an overdriven detonation wave from propane/oxygen to propane/air

    SciTech Connect (OSTI)

    Li, J.; Lai, W.H. [National Cheng Kung University, Institute of Aeronautics and Astronautics, Tainan (China); Chung, K. [National Cheng Kung University, Aerospace Science and Technology Research Center, Tainan (China); Lu, F.K. [University of Texas at Arlington, Mechanical and Aerospace Engineering Department, Aerodynamics Research Center, TX 76019 (United States)

    2008-08-15T23:59:59.000Z

    Two sets of experiments were performed to achieve a strong overdriven state in a weaker mixture by propagating an overdriven detonation wave via a deflagration-to-detonation transition (DDT) process. First, preliminary experiments with a propane/oxygen mixture were used to evaluate the attenuation of the overdriven detonation wave in the DDT process. Next, experiments were performed wherein a propane/oxygen mixture was separated from a propane/air mixture by a thin diaphragm to observe the transmission of an overdriven detonation wave. Based on the characteristic relations, a simple wave intersection model was used to calculate the state of the transmitted detonation wave. The results showed that a rarefaction effect must be included to ensure that there is no overestimate of the post-transmission wave properties when the incident detonation wave is overdriven. The strength of the incident overdriven detonation wave plays an important role in the wave transmission process. The experimental results showed that a transmitted overdriven detonation wave occurs instantaneously with a strong incident overdriven detonation wave. The near-CJ state of the incident wave leads to a transmitted shock wave, and then the transition to the overdriven detonation wave occurs downstream. The attenuation process for the overdriven detonation wave decaying to a near-CJ state occurs in all tests. After the attenuation process, an unstable detonation wave was observed in most tests. This may be attributed to the increase in the cell width in the attenuation process that exceeds the detonability cell width limit. (author)

  5. LIQUID NATURAL GAS (LNG): AN ALTERNATIVE FUEL FROM LANDFILL GAS (LFG) AND WASTEWATER DIGESTER GAS

    SciTech Connect (OSTI)

    VANDOR,D.

    1999-03-01T23:59:59.000Z

    This Research and Development Subcontract sought to find economic, technical and policy links between methane recovery at landfill and wastewater treatment sites in New York and Maryland, and ways to use that methane as an alternative fuel--compressed natural gas (CNG) or liquid natural gas (LNG) -- in centrally fueled Alternative Fueled Vehicles (AFVs).

  6. Mechanistic Studies on the Hydroxylation of Methane by Methane Monooxygenase

    E-Print Network [OSTI]

    Baik, Mu-Hyun

    a relatively small transition metal- based active site28,29 to achieve a difficult chemical transformationMechanistic Studies on the Hydroxylation of Methane by Methane Monooxygenase Mu-Hyun Baik, Martin 2393 3.1. KIE in Methane Oxidations 2394 3.2. Primary and Secondary KIEs 2396 3.3. Other KIEs 2396 3

  7. Table A2. Refiner/Reseller Prices of Aviation Fuels, Propane...

    Gasoline and Diesel Fuel Update (EIA)

    Marketing Annual 1999 421 Table A2. RefinerReseller Prices of Aviation Fuels, Propane, and Kerosene, by PAD District, 1983-Present (Cents per Gallon Excluding Taxes) -...

  8. Table A2. Refiner/Reseller Prices of Aviation Fuels, Propane...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Marketing Annual 1995 467 Table A2. RefinerReseller Prices of Aviation Fuels, Propane, and Kerosene, by PAD District, 1983-Present (Cents per Gallon Excluding Taxes) -...

  9. Table 14. U.S. Propane (Consumer Grade) Prices by Sales Type

    U.S. Energy Information Administration (EIA) Indexed Site

    and EIA-782B, "Resellers'Retailers' Monthly Petroleum Product Sales Report." 14. U.S. Propane (Consumer Grade) Prices by Sales Type 28 Energy Information Administration ...

  10. Microsoft PowerPoint - Joe Rose.Providence.Propane Supply Infrastruct...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    from the Gulf Coast. * Growth in Canadian demand for diluent (Pentanes+) demand for the oil sands industry. American Shale Production In 2013, U.S. Propane Production Increased...

  11. Biofuels: Microbially Generated Methane and

    E-Print Network [OSTI]

    Wood, Thomas K.

    Biofuels: Microbially Generated Methane and Hydrogen Michael J McAnulty, Pennsylvania State, Thomas K; and Ferry, James G (March 2013) Biofuels: Microbially Generated Methane and Hydrogen. In: e

  12. Comparison of Kinetic and Equilibrium Reaction Models in Simulating the Behavior of Gas Hydrates in Porous Media

    E-Print Network [OSTI]

    Kowalsky, Michael B.; Moridis, George J.

    2006-01-01T23:59:59.000Z

    rate constant of methane gas hydrate decomposition, CanadianAdvances in the Study of Gas Hydrates, C. Taylor , J. Qwan,International Conference on Gas Hydrates, Trondheim, Norway,

  13. Formation and retention of methane in coal

    SciTech Connect (OSTI)

    Hucka, V.J.; Bodily, D.M.; Huang, H.

    1992-05-15T23:59:59.000Z

    The formation and retention of methane in coalbeds was studied for ten Utah coal samples, one Colorado coal sample and eight coal samples from the Argonne Premium Coal Sample Bank.Methane gas content of the Utah and Colorado coals varied from zero to 9 cm{sup 3}/g. The Utah coals were all high volatile bituminous coals. The Colorado coal was a gassy medium volatile bituminous coal. The Argonne coals cover a range or rank from lignite to low volatile bituminous coal and were used to determine the effect of rank in laboratory studies. The methane content of six selected Utah coal seams and the Colorado coal seam was measured in situ using a special sample collection device and a bubble desorbometer. Coal samples were collected at each measurement site for laboratory analysis. The cleat and joint system was evaluated for the coal and surrounding rocks and geological conditions were noted. Permeability measurements were performed on selected samples and all samples were analyzed for proximate and ultimate analysis, petrographic analysis, {sup 13}C NMR dipolar-dephasing spectroscopy, and density analysis. The observed methane adsorption behavior was correlated with the chemical structure and physical properties of the coals.

  14. LANDFILL OPERATION FOR CARBON SEQUESTRATION AND MAXIMUM METHANE EMISSION CONTROL

    SciTech Connect (OSTI)

    Don Augenstein; Ramin Yazdani; Rick Moore; Michelle Byars; Jeff Kieffer; Professor Morton Barlaz; Rinav Mehta

    2000-02-26T23:59:59.000Z

    Controlled landfilling is an approach to manage solid waste landfills, so as to rapidly complete methane generation, while maximizing gas capture and minimizing the usual emissions of methane to the atmosphere. With controlled landfilling, methane generation is accelerated to more rapid and earlier completion to full potential by improving conditions (principally moisture, but also temperature) to optimize biological processes occurring within the landfill. Gas is contained through use of surface membrane cover. Gas is captured via porous layers, under the cover, operated at slight vacuum. A field demonstration project has been ongoing under NETL sponsorship for the past several years near Davis, CA. Results have been extremely encouraging. Two major benefits of the technology are reduction of landfill methane emissions to minuscule levels, and the recovery of greater amounts of landfill methane energy in much shorter times, more predictably, than with conventional landfill practice. With the large amount of US landfill methane generated, and greenhouse potency of methane, better landfill methane control can play a substantial role both in reduction of US greenhouse gas emissions and in US renewable energy. The work described in this report, to demonstrate and advance this technology, has used two demonstration-scale cells of size (8000 metric tons [tonnes]), sufficient to replicate many heat and compaction characteristics of larger ''full-scale'' landfills. An enhanced demonstration cell has received moisture supplementation to field capacity. This is the maximum moisture waste can hold while still limiting liquid drainage rate to minimal and safely manageable levels. The enhanced landfill module was compared to a parallel control landfill module receiving no moisture additions. Gas recovery has continued for a period of over 4 years. It is quite encouraging that the enhanced cell methane recovery has been close to 10-fold that experienced with conventional landfills. This is the highest methane recovery rate per unit waste, and thus progress toward stabilization, documented anywhere for such a large waste mass. This high recovery rate is attributed to moisture, and elevated temperature attained inexpensively during startup. Economic analyses performed under Phase I of this NETL contract indicate ''greenhouse cost effectiveness'' to be excellent. Other benefits include substantial waste volume loss (over 30%) which translates to extended landfill life. Other environmental benefits include rapidly improved quality and stabilization (lowered pollutant levels) in liquid leachate which drains from the waste.

  15. Glow Discharge Enhanced Chemical Reaction: Application in Ammonia Synthesis and Hydrocarbon Gas Cleanup

    E-Print Network [OSTI]

    Ming, Pingjia

    2014-06-05T23:59:59.000Z

    hydrocarbons mixture such as EPE (74.8% methane, 8% ethane, 8% ethylene, 2.1% propane and 1.1% Propene). Non-thermal plasmas, due to their unique non-equilibrium characteristics, offer advantages as method of reforming at lower temperature (100-150 º...

  16. Methane hydrate research at NETL: Research to make methane production from hydrates a reality

    SciTech Connect (OSTI)

    Taylor, C.E.; Link, D.D.; English, N.

    2007-03-01T23:59:59.000Z

    Research is underway at NETL to understand the physical properties of methane hydrates. Five key areas of research that need further investigation have been identified. These five areas, i.e. thermal properties of hydrates in sediments, kinetics of natural hydrate dissociation, hysteresis effects, permeability of sediments to gas flow and capillary pressures within sediments, and hydrate distribution at porous scale, are important to the production models that will be used for producing methane from hydrate deposits. NETL is using both laboratory experiments and computational modeling to address these five key areas. The laboratory and computational research reinforce each other by providing feedback. The laboratory results are used in the computational models and the results from the computational modeling is used to help direct future laboratory research. The data generated at NETL will be used to help fulfill The National Methane Hydrate R&D Program of a “long-term supply of natural gas by developing the knowledge and technology base to allow commercial production of methane from domestic hydrate deposits by the year 2015” as outlined on the NETL Website [NETL Website, 2005. http://www.netl.doe.gov/scngo/Natural%20Gas/hydrates/index.html]. Laboratory research is accomplished in one of the numerous high-pressure hydrate cells available ranging in size from 0.15 mL to 15 L in volume. A dedicated high-pressure view cell within the Raman spectrometer allows for monitoring the formation and dissociation of hydrates. Thermal conductivity of hydrates (synthetic and natural) at a certain temperature and pressure is performed in a NETL-designed cell. Computational modeling studies are investigating the kinetics of hydrate formation and dissociation, modeling methane hydrate reservoirs, molecular dynamics simulations of hydrate formation, dissociation, and thermal properties, and Monte Carlo simulations of hydrate formation and dissociation.

  17. Propane cold neutron source: creation and operation experience

    SciTech Connect (OSTI)

    Zemlyanov, M. G.

    1997-09-01T23:59:59.000Z

    In most cold neutron sources, utilized until recently, liquid hydrogen, liquid deuterium and their mixtures were used as a moderating medium. The sources with the liquid hydrogen moderator offer the most specific effectiveness of cold neutron generation. But they are complicated in design, require special safety measures in the course of operation and are very expensive. In this connection, it is of undoubted interest to create a source which, although it yields the specific generation of cold neutrons comparable to the liquid hydrogen one, is safer in operation and simple in design. We assume such a source may be one which uses as a moderator liquid propane cooled to liquid nitrogen temperature.

  18. Alternative Fuels Data Center: Michigan Converts Vehicles to Propane,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduce OperatingPropane in OhioReducing

  19. Alternative Fuels Data Center: Propane Buses Shuttle Visitors in Maine

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduceNew HampshirePropane Buses Shuttle

  20. Alternative Fuels Data Center: Propane Fueling Infrastructure Development

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduceNew HampshirePropane Buses

  1. Alternative Fuels Data Center: Propane Fueling Station Locations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduceNew HampshirePropane BusesStation

  2. Alternative Fuels Data Center: Propane Mowers Help National Park Cut

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduceNew HampshirePropane

  3. Alternative Fuels Data Center: Propane Powers Fleets Across the Nation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduceNew HampshirePropaneOrleans

  4. Alternative Fuels Data Center: Propane School Buses Launched in Gloucester

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduceNewPropane Printable Version Share

  5. Alternative Fuels Data Center: Propane Tank Overfill Safety Advisory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduceNewPropane Printable Version

  6. Alternative Fuels Data Center: Propane Vans Keep Kansas City Transportation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduceNewPropane Printable VersionCompany

  7. Alternative Fuels Data Center: Renzenberger Inc Saves Money With Propane

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduceNewPropane PrintableTools

  8. Production of Organic Oxygenates in the Partial Oxidation of Methane in a Silent Electric Discharge Reactor

    E-Print Network [OSTI]

    Mallinson, Richard

    Production of Organic Oxygenates in the Partial Oxidation of Methane in a Silent Electric Discharge help reduce the problem of global warming. There are vast reserves of natural gas around the world.1, Room T 335, Norman, Oklahoma 73019 This study on the partial oxidation of methane in a silent electric

  9. Catalytic performance of vanadium incorporated MCM-41 catalysts for the partial oxidation of methane to formaldehyde

    E-Print Network [OSTI]

    Haller, Gary L.

    that of oil. Methane, as the principle component of the natural gas and by product of oil refining and chemical processing, has been considered as an important sustainable feedstock for the chemical industry­4]. Industrially, formaldehyde is produced from methane by a three-step process including: (i) high temperature

  10. Author's personal copy Methane seepage along the Hikurangi Margin of New Zealand: Geochemical

    E-Print Network [OSTI]

    Wehrli, Bernhard

    : Methane seepage gas hydrate water column sea surface carbon isotopes Hikurangi Margin The concentration and carbon isotope values of dissolved methane were measured in the water column at Rock Garden, Omakere­Temperature­Depth (CTD) operations were at Faure Site of Rock Garden. Here, seafloor bubble release was observed by ROV

  11. Experimental investigation of burning velocities of ultra-wet methane-air-steam mixtures

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    , steam, burning velocity, chemiluminescence, OH Introduction In ultra-wet gas turbines, the heatExperimental investigation of burning velocities of ultra-wet methane-air-steam mixtures Eric Abstract Global burning velocities of methane-air-steam mixtures are measured on prismatic laminar Bunsen

  12. Acetic Acid from the Carbonylation of Chloride Methane Over Rhodium Based Catalysts

    E-Print Network [OSTI]

    Bao, Xinhe

    on an indirect route via synthesis gas (syngas), i.e., methane is first con- verted to syngas before it is further transformed into other useful products [6]. However, the production of syngas from methane) 130:286­290 DOI 10.1007/s10562-009-0017-9 #12;[12], which is produced from syngas feedstock with Cu

  13. MOLECULAR SIMULATION OF PHASE EQUILIBRIA FOR WATER -METHANE AND WATER -ETHANE MIXTURES

    E-Print Network [OSTI]

    1 MOLECULAR SIMULATION OF PHASE EQUILIBRIA FOR WATER - METHANE AND WATER - ETHANE MIXTURES Jeffrey were used to calculate water - methane and water - ethane phase equilibria over a wide range and petrochemical industry, natural and petroleum gas production, and environmental control. For many

  14. High Methane Storage Capacity in Aluminum Metal-Organic Felipe Gandara, Hiroyasu Furukawa, Seungkyu Lee, and Omar M. Yaghi*

    E-Print Network [OSTI]

    Yaghi, Omar M.

    Information ABSTRACT: The use of porous materials to store natural gas in vehicles requires large amounts , and between 5 and 80 bar, 230 cm3 cm-3 . Methane is the main component of natural gas and represents about two

  15. Alternative technologies to steam-methane reforming

    SciTech Connect (OSTI)

    Tindall, B.M.; Crews, M.A. [Howe-Baker Engineers, Inc., Tyler, TX (United States)

    1995-11-01T23:59:59.000Z

    Steam-methane reforming (SMR) has been the conventional route for hydrogen and carbon monoxide production from natural gas feedstocks. However, several alternative technologies are currently finding favor for an increasing number of applications. The competing technologies include: steam-methane reforming combined with oxygen secondary reforming (SMR/O2R); autothermal reforming (ATR); thermal partial oxidation (POX). Each of these alternative technologies uses oxygen as a feedstock. Accordingly, if low-cost oxygen is available, they can be an attractive alternate to SMR with natural gas feedstocks. These technologies are composed technically and economically. The following conclusions can be drawn: (1) the SMR/O2R, ATR and POX technologies can be attractive if low-cost oxygen is available; (2) for competing technologies, the H{sub 2}/CO product ratio is typically the most important process parameter; (3) for low methane slip, the SMR/O2R, ATR and POX technologies are favored; (4) for full CO{sub 2} recycle, POX is usually better than ATR; (5) relative to POX, the ATR is a nonlicensed technology that avoids third-party involvement; (6) economics of each technology are dependent on the conditions and requirements for each project and must be evaluated on a case-by-case basis.

  16. Final report of the Rhode Island State Energy Office on residential no. 2 heating oil and propane prices [SHOPP

    SciTech Connect (OSTI)

    McClanahan, Janice

    2001-04-01T23:59:59.000Z

    Summary report on residential No.2 heating oil and propane prepared under grant. Summarizes the monitoring and analysis of heating oil and propane prices from October 2000 through March 2001.

  17. Further experimental studies of steam-propane injection to enhance recovery of Morichal oil 

    E-Print Network [OSTI]

    Ferguson,Mark Anthony

    2000-01-01T23:59:59.000Z

    In 1998-1999, experimental research was conducted by Goite at Texas A&M University into steam-propane injection to enhance oil recovery from the Morichal field, Venezuela. Goite's results showed that, compared with steam injection alone, steam-propane...

  18. Experimental studies of steam-propane injection to enhance recovery of an intermediate crude oil 

    E-Print Network [OSTI]

    Tinss, Judicael Christopher

    2001-01-01T23:59:59.000Z

    In the past few years, research has been conducted at Texas A&M University on steam-propane injection to enhance oil recovery from the Morichal field, Venezuela, which contains 13.5 ?API gravity oil. Experimental results show that a 5:100 propane...

  19. Experimental studies of steam-propane injection to enhance recovery of an intermediate crude oil

    E-Print Network [OSTI]

    Tinss, Judicael Christopher

    2001-01-01T23:59:59.000Z

    In the past few years, research has been conducted at Texas A&M University on steam-propane injection to enhance oil recovery from the Morichal field, Venezuela, which contains 13.5 ?API gravity oil. Experimental results show that a 5:100 propane...

  20. Further experimental studies of steam-propane injection to enhance recovery of Morichal oil

    E-Print Network [OSTI]

    Ferguson,Mark Anthony

    2000-01-01T23:59:59.000Z

    In 1998-1999, experimental research was conducted by Goite at Texas A&M University into steam-propane injection to enhance oil recovery from the Morichal field, Venezuela. Goite's results showed that, compared with steam injection alone, steam-propane...

  1. 9118 J. Am. Chem. SOC.1992, 114, 9118-9122 Propane Buwe

    E-Print Network [OSTI]

    Schlegel, H. Bernhard

    9118 J. Am. Chem. SOC.1992, 114, 9118-9122 Scheme 111 Propane Buwe X =CHI and Y = H lossofH2 Z = H-82-8; ethane, 74- 84-0; propane, 74-98-6;butane, 106-97-8. (28) The heats of formation for C3H2are the scaled

  2. State heating oil and propane program, 1994--1995 heating season. Final technical report

    SciTech Connect (OSTI)

    NONE

    1995-05-09T23:59:59.000Z

    Propane prices and No. 2 fuel prices during the 1994-1995 heating season are tabulated for the state of Ohio. Nineteen companies were included in the telephone survey of propane prices, and twenty two companies for the fuel oil prices. A bar graph is also presented for average residential prices of No. 2 heating oil.

  3. Far-infrared laser vibration-rotation-tunneling spectroscopy of the propane-water compkx: Torsional dynamics of the hydrogen

    E-Print Network [OSTI]

    Cohen, Ronald C.

    Far-infrared laser vibration-rotation-tunneling spectroscopy of the propane-water compkx: Torsional 1993) The far-infrared laservibration-rotation-tunneling (FIR-VRT) spectrumof the propane-water complex calculations. In the present paper and in its counterpart,13we present our results for the water-propane

  4. Non-oxidative reactions of propane on Zn/Na-ZSM5 Joseph A. Biscardi and Enrique Iglesia*

    E-Print Network [OSTI]

    Iglesia, Enrique

    Non-oxidative reactions of propane on Zn/Na-ZSM5 Joseph A. Biscardi and Enrique Iglesia* Department rates during propane conversion at 773 K on Zn/Na-ZSM5 are about ten times higher than on Zn/H-ZSM5 catalysts with similar Zn content. The total rate of propane conversion is also higher on Zn/Na-ZSM5

  5. J. Am. Chem. SOC.1988, 110, 8305-8319 8305 Hydrogenolysis of Ethane, Propane, n-Butane, and Neopentane

    E-Print Network [OSTI]

    Goodman, Wayne

    J. Am. Chem. SOC.1988, 110, 8305-8319 8305 Hydrogenolysis of Ethane, Propane, n, Pasadena, California 91125. Received February I, 1988 Abstract: The hydrogenolysisof ethane, propane, n for ethane, propane, and neopentane involvesthe cleavage of a single carbon-carbon bond, resulting

  6. Modeling of the formation of short-chain acids in propane flames F. Battin-Leclerc , 1

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Modeling of the formation of short-chain acids in propane flames F. Battin-Leclerc , 1 , A. Simulations of lean (equivalence ratios from 0.9 to 0.48) laminar premixed flames of propane stabilized in a combustion apparatus which can easily be modeled, a laminar premixed flame of propane at atmospheric pressure

  7. Kinetics and Reaction Pathways for Propane Dehydrogenation and Aromatization on Co/H-ZSM5 and H-ZSM5

    E-Print Network [OSTI]

    Iglesia, Enrique

    Kinetics and Reaction Pathways for Propane Dehydrogenation and Aromatization on Co/H-ZSM5 and H Co/H-ZSM5 catalyzes propane dehydrogenation and aromatization reactions. Initial product selectivities, product site-yields, and the 13C content and distribution in the products of 2-13C-propane show

  8. Analysis of core samples from the BPXA-DOE-USGS Mount Elbert gas hydrate stratigraphic test well: Insights into core disturbance and handling

    E-Print Network [OSTI]

    Kneafsey, Timothy J.

    2010-01-01T23:59:59.000Z

    and handling of natural gas hydrate. GSC Bulletin, 544: 263-naturally occurring gas hydrates: the structures of methaneDOE-USGS Mount Elbert gas hydrate stratigraphic test well:

  9. Natural gas cost for evaluating energy resource opportunities at Fort Stewart

    SciTech Connect (OSTI)

    Stucky, D.J.; Shankle, S.A.

    1993-01-01T23:59:59.000Z

    Ft. Stewart, a United States Army Forces Command (FORSCOM) installation located near Hinesville, Georgia, is currently undergoing an evaluation of its energy usage, which is being performed by Pacific Northwest Laboratory. In order to examine the energy resource opportunities (EROs) at Ft. Stewart, marginal fuel costs must be calculated. The marginal, or avoided, cost of gas service is used in conjunction with the estimated energy savings of an ERO to calculate the dollar value of those savings. In the case of natural gas, the costing becomes more complicated due to the installation of a propane-air mixing station. The propane-air station is being built under a shared energy savings (SES) contract. The building of a propane-air station allows Ft. Stewart to purchase natural gas from their local utility at an interruptible rate, which is lower than the rate for contracting natural gas on a firm basis. The propane-air station will also provide Ft. Stewart with fuel in the event that the natural gas supply is curtailed. While the propane-air station does not affect the actual cost of natural gas, it does affect the cost of services provided by gas. Because the propane-air station and the SES contract affect the cost of gas service, they must be included in the analysis. Our analysis indicates a marginal cost of gas service of 30.0 cents per therm, assuming a total propane usage by the mixing station of 42,278 gallons (38,600 therms) annually. Because the amount of propane that may be required in the event of a curtailment is small relative to the total service requirement, variations in the actual amount should not significantly affect the cost per therm.

  10. Determining the Fate of Methane Released from the Seafloor in Deep and Shallow Water Environments 

    E-Print Network [OSTI]

    Du, Mengran

    2014-08-12T23:59:59.000Z

    Marine gas seeps and accidental marine oil spills are sources of methane (CH_(4)) to the ocean, and potentially to the atmosphere, though the magnitude of the fluxes and dynamics of these systems are poorly defined. For example, the ultimate...

  11. Radiochemical Transformation of High Pressure Methane under Gamma, Electron, and Neutron Irradiation

    E-Print Network [OSTI]

    Clemens, Jeffrey Tyler

    2014-05-01T23:59:59.000Z

    The chemical effects of irradiation on high pressure methane and noble gas mixtures were investigated using gamma, electron beam, and neutron irradiation sources. The gamma source used was the La-140 source from the Nuclear Science Center (NSC...

  12. Oxygen Pathways and Carbon Dioxide Utilization in Methane Partial Oxidation in Ambient Temperature

    E-Print Network [OSTI]

    Mallinson, Richard

    - ronmental impact. Present technology uses steam reforming to produce synthesis gas which is converted into enhance- ment of the carbon balance of methane conversion by reforming with CO2 in order to "recycle

  13. Computational heterogeneous catalysis applied to steam methane reforming over nickel and nickel/silver catalysts

    E-Print Network [OSTI]

    Blaylock, Donnie Wayne

    2011-01-01T23:59:59.000Z

    The steam methane reforming (SMR) reaction is the primary industrial means for producing hydrogen gas. As such, it is a critical support process for applications including petrochemical processing and ammonia synthesis. ...

  14. Determining the Fate of Methane Released from the Seafloor in Deep and Shallow Water Environments

    E-Print Network [OSTI]

    Du, Mengran

    2014-08-12T23:59:59.000Z

    Marine gas seeps and accidental marine oil spills are sources of methane (CH_(4)) to the ocean, and potentially to the atmosphere, though the magnitude of the fluxes and dynamics of these systems are poorly defined. For example, the ultimate...

  15. Field Exploration of Methane Seep Near Atqasuk

    SciTech Connect (OSTI)

    Katey Walter, Dennis Witmer, Gwen Holdmann

    2008-12-31T23:59:59.000Z

    Methane (CH{sub 4}) in natural gas is a major energy source in the U.S., and is used extensively on Alaska's North Slope, including the oilfields in Prudhoe Bay, the community of Barrow, and the National Petroleum Reserve, Alaska (NPRA). Smaller villages, however, are dependent on imported diesel fuel for both power and heating, resulting in some of the highest energy costs in the U.S. and crippling local economies. Numerous CH{sub 4} gas seeps have been observed on wetlands near Atqasuk, Alaska (in the NPRA), and initial measurements have indicated flow rates of 3,000-5,000 ft{sup 3} day{sup -1} (60-100 kg CH{sub 4} day{sup -1}). Gas samples collected in 1996 indicated biogenic origin, although more recent sampling indicated a mixture of biogenic and thermogenic gas. In this study, we (1) quantified the amount of CH{sub 4} generated by several seeps and evaluated their potential use as an unconventional gas source for the village of Atqasuk; (2) collected gas and analyzed its composition from multiple seeps several miles apart to see if the source is the same, or if gas is being generated locally from isolated biogenic sources; and (3) assessed the potential magnitude of natural CH{sub 4} gas seeps for future use in climate change modeling.

  16. The commercial production of coalbed methane: A review of 53 wells in the Black Warrior Basin

    SciTech Connect (OSTI)

    Dunn, B.W.

    1984-09-01T23:59:59.000Z

    This paper reviews the actual performance of 53 conventionally drilled vertical coalbed methane wells developed by a joint coal industry/gas industry effort. The unique characteristics of the coalbed reservoir are briefly described. Actual gas production and computer model predictions are compared and the costs and revenues are discussed with specific emphasis on the economic results. This paper differs from previous technically oriented discussions of coalbed methane production in that economic viability, initially established in February of 1982, continues to be demonstrated.

  17. X-ray CT Observations of Methane Hydrate Distribution Changes over Time in a Natural Sediment Core from the BPX-DOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test Well

    E-Print Network [OSTI]

    Kneafsey, T.J.

    2012-01-01T23:59:59.000Z

    and Englezos, P. , 2009. Gas hydrate formation in a variable1999. Formation of natural gas hydrates in marine sediments.1. Conceptual model of gas hydrate growth conditioned by

  18. RICH METHANE PREMIXED LAMINAR FLAMES DOPED BY LIGHT UNSATURATED HYDROCARBONS

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    RICH METHANE PREMIXED LAMINAR FLAMES DOPED BY LIGHT UNSATURATED HYDROCARBONS PART I: ALLENE developed in our laboratory for the reactions of C3-C4 unsaturated hydrocarbons. The main reaction pathways2007 #12;3 INTRODUCTION Soots and polyaromatic hydrocarbons (PAH), which are present in the exhaust gas

  19. ESTIMATING METHANE EMISSION AND OXIDATION FROM TWO TEMPORARY

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    layer waste gas composition were measured on two French MBT plants with aerobic pre-treatment process using old municipal solid waste material (Huber-Humer & al, 2007, 2008). Another result of these studies amount of fugitive methane emissions for landfills without waste pre-treatment (Tarimini & al, 2003

  20. Simulation of hydrogen and hydrogen-assisted propane ignition in Pt catalyzed microchannel

    SciTech Connect (OSTI)

    Seshadri, Vikram; Kaisare, Niket S. [Department of Chemical Engineering, Indian Institute of Technology - Madras, Chennai 600 036 (India)

    2010-11-15T23:59:59.000Z

    This paper deals with self-ignition of catalytic microburners from ambient cold-start conditions. First, reaction kinetics for hydrogen combustion is validated with experimental results from the literature, followed by validation of a simplified pseudo-2D microburner model. The model is then used to study the self-ignition behavior of lean hydrogen/air mixtures in a Platinum-catalyzed microburner. Hydrogen combustion on Pt is a very fast reaction. During cold start ignition, hydrogen conversion reaches 100% within the first few seconds and the reactor dynamics are governed by the ''thermal inertia'' of the microburner wall structure. The self-ignition property of hydrogen can be used to provide the energy required for propane ignition. Two different modes of hydrogen-assisted propane ignition are considered: co-feed mode, where the microburner inlet consists of premixed hydrogen/propane/air mixtures; and sequential feed mode, where the inlet feed is switched from hydrogen/air to propane/air mixtures after the microburner reaches propane ignition temperature. We show that hydrogen-assisted ignition is equivalent to selectively preheating the inlet section of the microburner. The time to reach steady state is lower at higher equivalence ratio, lower wall thermal conductivity, and higher inlet velocity for both the ignition modes. The ignition times and propane emissions are compared. Although the sequential feed mode requires slightly higher amount of hydrogen, the propane emissions are at least an order of magnitude lower than the other ignition modes. (author)

  1. Coal Bed Methane Protection Act (Montana)

    Broader source: Energy.gov [DOE]

    The Coal Bed Methane Protection Act establishes a long-term coal bed methane protection account and a coal bed methane protection program for the purpose of compensating private landowners and...

  2. Excitability in high-Lewis number premixed gas combustion

    SciTech Connect (OSTI)

    Pearlman, H. [NASA Lewis Research Center, Cleveland, OH (United States)] [NASA Lewis Research Center, Cleveland, OH (United States)

    1997-05-01T23:59:59.000Z

    The dynamical behavior of freely-propagating premixed gas flames in tubes is studied experimentally in the high-Lewis number (Le) regime using a mixture of butane and oxygen diluted with helium (Le {approx} 4.0). Steadily-propagating, stable flames develop traveling wave and spinning instabilities as the stoichiometry of the mixture approaches the lean flammability limit. These instabilities occur spontaneously and form target patterns and rotating spiral waves, bearing remarkable similarity with patterns observed in excitable media. Additional experiments are conducted on burner-stabilized flames and indicate that these instabilities also occur in three common air-diluted mixtures with smaller Le`s than their helium-diluted counterparts. Specifically, the instabilities are observed in stoichiometric and lean mixtures of butane-air (Le {approx} 2.1), propane-air (Le {approx} 1.9), and stoichiometric and rich mixtures of methane-air (Le {approx} 1.1) at sufficiently low mixture flow rates. Both experiments confirm model predictions that increasing conductive loss lowers the critical Le required for onset of instability.

  3. Effect of temperature and pressure on the dynamics of nanoconfined propane

    SciTech Connect (OSTI)

    Gautam, Siddharth, E-mail: gautam.25@osu.edu; Liu, Tingting, E-mail: gautam.25@osu.edu; Welch, Susan; Cole, David [School of Earth Sciences, The Ohio State University, 275 Mendenhall Laboratory, 125 S Oval Mall, Columbus, OH 43210 (United States); Rother, Gernot [Geochemistry and Interfacial Science Group, Chemical Science Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States); Jalarvo, Niina [Jülich Center for Neutron Sciences (JCNS-1), Forschungszentrum Jülich Outstation at Spallation Neutron Source(SNS), Chemical and Engineering Materials Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States); Mamontov, Eugene [Spallation Neutron Source (SNS), Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States)

    2014-04-24T23:59:59.000Z

    We report the effect of temperature and pressure on the dynamical properties of propane confined in nanoporous silica aerogel studied using quasielastic neutron scattering (QENS). Our results demonstrate that the effect of a change in the pressure dominates over the effect of temperature variation on the dynamics of propane nano-confined in silica aerogel. At low pressures, most of the propane molecules are strongly bound to the pore walls, only a small fraction is mobile. As the pressure is increased, the fraction of mobile molecules increases. A change in the mechanism of motion, from continuous diffusion at low pressures to jump diffusion at higher pressures has also been observed.

  4. Uncorking the bottle: What triggered the Paleocene/Eocene thermal maximum methane release?

    E-Print Network [OSTI]

    realms that has been attributed to a massive methane (CH4) release from marine gas hydrate reservoirs(s) to increase water temperatures rapidly enough to trigger the massive thermal dissociation of gas hydrate the sediment column and show the effect of the temperature change on the gas hydrate stability zone through

  5. Central-northern Appalachian coalbed methane flow grows

    SciTech Connect (OSTI)

    Lyons, P.C. [Geological Survey, Reston, VA (United States)

    1997-07-07T23:59:59.000Z

    Over the past decade in the US, coalbed methane (CBM) has become an increasingly important source of unconventional natural gas. The most significant CBM production occurs in the San Juan basin of Colorado and new Mexico and the Black Warrior basin of Alabama, which collective in 1995 accounted for about 94% of US CBM production. The paper discusses early CBM production, recent production, gas composition, undiscovered potential, and new exploration areas.

  6. Assessment of the methane oxidation capacity of compacted soils intended for use as landfill cover materials

    SciTech Connect (OSTI)

    Rachor, Ingke, E-mail: i.rachor@ifb.uni-hamburg.de [University of Hamburg, Institute of Soil Science, Allende-Platz 2, 20146 Hamburg (Germany); Gebert, Julia; Groengroeft, Alexander; Pfeiffer, Eva-Maria [University of Hamburg, Institute of Soil Science, Allende-Platz 2, 20146 Hamburg (Germany)

    2011-05-15T23:59:59.000Z

    The microbial oxidation of methane in engineered cover soils is considered a potent option for the mitigation of emissions from old landfills or sites containing wastes of low methane generation rates. A laboratory column study was conducted in order to derive design criteria that enable construction of an effective methane oxidising cover from the range of soils that are available to the landfill operator. Therefore, the methane oxidation capacity of different soils was assessed under simulated landfill conditions. Five sandy potential landfill top cover materials with varying contents of silt and clay were investigated with respect to methane oxidation and corresponding soil gas composition over a period of four months. The soils were compacted to 95% of their specific proctor density, resulting in bulk densities of 1.4-1.7 g cm{sup -3}, reflecting considerably unfavourable conditions for methane oxidation due to reduced air-filled porosity. The soil water content was adjusted to field capacity, resulting in water contents ranging from 16.2 to 48.5 vol.%. The investigated inlet fluxes ranged from 25 to about 100 g CH{sub 4} m{sup -2} d{sup -1}, covering the methane load proposed to allow for complete oxidation in landfill covers under Western European climate conditions and hence being suggested as a criterion for release from aftercare. The vertical distribution of gas concentrations, methane flux balances as well as stable carbon isotope studies allowed for clear process identifications. Higher inlet fluxes led to a reduction of the aerated zone, an increase in the absolute methane oxidation rate and a decline of the relative proportion of oxidized methane. For each material, a specific maximum oxidation rate was determined, which varied between 20 and 95 g CH{sub 4} m{sup -2} d{sup -1} and which was positively correlated to the air-filled porosity of the soil. Methane oxidation efficiencies and gas profile data imply a strong link between oxidation capacity and diffusive ingress of atmospheric air. For one material with elevated levels of fine particles and high organic matter content, methane production impeded the quantification of methane oxidation potentials. Regarding the design of landfill cover layers it was concluded that the magnitude of the expected methane load, the texture and expected compaction of the cover material are key variables that need to be known. Based on these, a column study can serve as an appropriate testing system to determine the methane oxidation capacity of a soil intended as landfill cover material.

  7. Enhanced Renewable Methane Production System | Argonne National...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Enhanced Renewable Methane Production System Technology available for licensing: Enhanced renewable methane production system provides a low-cost process that accelerates...

  8. A rapid compression machine study of the oxidation of propane in the negative temperature coefficient regime

    SciTech Connect (OSTI)

    Gallagher, S.M.; Curran, H.J.; Metcalfe, W.K.; Healy, D.; Simmie, J.M. [Combustion Chemistry Centre, National University of Ireland, Galway (Ireland); Bourque, G. [Rolls-Royce Canada, Montreal (Canada)

    2008-04-15T23:59:59.000Z

    The oxidation of propane has been studied in the temperature range 680-970 K at compressed gas pressures of 21, 27, and 37 atm and at varying equivalence ratios of 0.5, 1.0, and 2.0. These data are consistent with other experiments presented in the literature for alkane fuels in that, when ignition delay times are plotted as a function of temperature, a characteristic negative coefficient behavior is observed. In addition, these data were simulated using a detailed chemical kinetic model. It was found that qualitatively the model correctly simulated the effect of change in equivalence ratio and pressure, predicting that fuel-rich, high-pressure mixtures ignite fastest, while fuel-lean, low-pressure mixtures ignite slowest. Moreover, reactivity as a function of temperature is well captured, with the model predicting negative temperature coefficient behavior similar to the experiments. Quantitatively the model is faster than experiment for all mixtures at the lowest temperatures (650-750 K) and is also faster than experiment throughout the entire temperature range for fuel-lean mixtures. (author)

  9. Backward Raman amplification in a partially ionized gas A. A. Balakin,1

    E-Print Network [OSTI]

    was accessed 10,11 . The experimental success was achieved using a gas jet of propane, subse- quently ionized that would be most desired. Using the pro- pane gas jet, as opposed to pure hydrogen, eased conditions on the gas jet nozzle, since a lower gas pressure could pro- duce a higher density target. However, the use

  10. Compatibility of selected ceramics with steam-methane reformer environments

    SciTech Connect (OSTI)

    Keiser, J.R.; Howell, M. [Oak Ridge National Lab., TN (United States); Williams, J.J.; Rosenberg, R.A. [Stone and Webster Engineering Corp., Boston, MA (United States)

    1996-04-01T23:59:59.000Z

    Conventional steam reforming of methane to synthesis gas (CO and H{sub 2}) hasa conversion efficiency of about 85%. Replacement of metal tubes in the reformer with ceramic tubes offers the potential for operation at temperatures high enough to increase the efficiency to 98-99%. However, the two candidate ceramic materials being given strongest consideration, sintered alpha Si carbide and Si carbide particulate-strengthened alumina, have been shown to react with components of the reformer environment. Extent of degradation as a function of steam partial pressure and exposure time has been studied, and results suggest limits under which these structural ceramics can be used in advanced steam-methane reformers.

  11. International Cooperation in Methane Hydrates | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the.pdfBreaking ofOil & Gas » Methane Hydrate » International Cooperation in Methane

  12. Methanation of Carbon Dioxide

    E-Print Network [OSTI]

    Goodman, Daniel Jacob

    2013-01-01T23:59:59.000Z

    cycle plants, possibly with carbon capture and storage (CCS)natural gas plant with carbon capture and storage technology

  13. Methanation of Carbon Dioxide

    E-Print Network [OSTI]

    Goodman, Daniel Jacob

    2013-01-01T23:59:59.000Z

    gas plant with carbon capture and storage technology werewith carbon capture and storage (CCS) technology, to replace

  14. State heating oil and propane program: Final report. Survey of No.2 heating oil and propane prices at the retail level, October 1997 through March 1998

    SciTech Connect (OSTI)

    NONE

    1998-11-01T23:59:59.000Z

    The Energy Efficiency Division of the Vermont Department of Public Service (DPS) monitored the price and inventory of residential heating oil and propane during the 1997--98 heating season under a grant from the US Department of Energy`s Energy Information Administration (EIA). DPS staff collected data biweekly between October 5, 1997 and March 16, 1998 on the retail price of {number_sign}2 home heating oil and propane by telephone survey. Propane price quoted was based on the rate for a residential home heating customer using 1,000+ per year. The survey included a sample of fuel dealers selected by the EIA, plus additional dealers and fuels selected by the DPS. The EIA weighted, analyzed, and reported the data collected from their sample.

  15. Experimental and analytical studies of hydrocarbon yields under dry-, steam-, and steam-with-propane distillation 

    E-Print Network [OSTI]

    Jaiswal, Namit

    2007-09-17T23:59:59.000Z

    Simulation study has shown oil production is accelerated when propane is used as an additive during steam injection. To better understand this phenomenon, distillation experiments were performed using San Ardo crude oil (12oAPI). For comparison...

  16. Experimental study of Morichal heavy oil recovery using combined steam and propane injection 

    E-Print Network [OSTI]

    Goite Marcano, Jose Gregorio

    1999-01-01T23:59:59.000Z

    with steam (for the purpose of increasing steam recovery efficiency) are being evaluated. An experimental study has been performed to investigate the effect of combined steam and propane injection on recovery of heavy oil from the Morichal field, Venezuela...

  17. Experimental and analytical studies of hydrocarbon yields under dry-, steam-, and steam with propane-distillation 

    E-Print Network [OSTI]

    Ramirez Garnica, Marco Antonio

    2004-09-30T23:59:59.000Z

    Recent experimental and simulation studies -conducted at the Department of Petroleum Engineering at Texas A&M University - confirm oil production is accelerated when propane is used as an additive during steam injection. To better understand...

  18. Experimental study of Morichal heavy oil recovery using combined steam and propane injection

    E-Print Network [OSTI]

    Goite Marcano, Jose Gregorio

    1999-01-01T23:59:59.000Z

    with steam (for the purpose of increasing steam recovery efficiency) are being evaluated. An experimental study has been performed to investigate the effect of combined steam and propane injection on recovery of heavy oil from the Morichal field, Venezuela...

  19. Table A2. Refiner/Reseller Prices of Aviation Fuels, Propane...

    U.S. Energy Information Administration (EIA) Indexed Site

    - W 73.5 See footnotes at end of table. A2. RefinerReseller Prices of Aviation Fuels, Propane, and Kerosene, by PAD District, 1983-Present Energy Information Administration ...

  20. Analysis of tank deformation from fire induced ruptures and BLEVEs of 400 l propane tanks

    SciTech Connect (OSTI)

    Kielec, D.J.; Birk, A.M. [Queen`s Univ., Kingston, Ontario (Canada). Dept. of Mechanical Engineering

    1996-12-01T23:59:59.000Z

    A series of fire tests were conducted to study the thermal rupture of propane tanks. The tests involved 400 liter ASME automotive propane tanks filled to 80% capacity with commercial propane. The tanks were brought to failure using torches and pool fires. the resulting thermal ruptures varied in severity from minor fissures, measuring a few centimeters in length, to catastrophic failures where the tank was flattened on the ground. The catastrophic failures would typically be called Boiling Liquid Expanding Vapour Explosions (BLEVE). The objective of this work was to develop a correlation between the failure severity and the tank condition at failure. The deformed propane tanks were measured in detail and the extent of deformation was quantified. The tank failure severity was found to be a complex function of a number of tank and lading properties at failure. this paper presents the measured data from the tanks and a step by step description of how the correlation was determined.

  1. Analysis of fire-induced ruptures of 400-L propane tanks

    SciTech Connect (OSTI)

    Kielec, D.J.; Birk, A.M. [Queen`s Univ., Kingston, Ontario (Canada). Dept. of Mechanical Engineering

    1997-08-01T23:59:59.000Z

    A series of fire tests were conducted to study the thermal rupture of propane tanks. The tests involved 400-L ASME automotive propane tanks filled to 80% capacity with commercial propane. The tanks were brought to failure using torches and pool fires. The resulting thermal ruptures varied in severity from minor fissures, measuring a few centimeters in length, to catastrophic failures where the tank was flattened on the ground. The catastrophic failures would typically be called boiling liquid expanding vapor explosions (BLEVEs). The objective of this work was to develop a correlation between the failure severity and the tank condition at failure. The deformed propane tanks were measured in detail and the extent of deformation was quantified. The tank failure severity was found to be a complex function of a number of tank and lading properties at failure. This paper presents the measured data from the tanks and a step-by-step description of how the correlation was determined.

  2. Emissions from In-Use NG, Propane, and Diesel Fueled Heavy Duty...

    Broader source: Energy.gov (indexed) [DOE]

    Emissions from In-Use NG, Propane, and Diesel Fueled Heavy Duty Vehicles 2011 Directions in Engine-Efficiency and Emissions Research (DEER) October 3-6, 2011 Presented By: Kent...

  3. Experimental and analytical studies of hydrocarbon yields under dry-, steam-, and steam-with-propane distillation

    E-Print Network [OSTI]

    Jaiswal, Namit

    2007-09-17T23:59:59.000Z

    EXPERIMENTAL AND ANALYTICAL STUDIES OF HYDROCARBON YIELDS UNDER DRY-, STEAM-, AND STEAM-WITH- PROPANE DISTILLATION A Dissertation by NAMIT JAISWAL Submitted to the Office of Graduate Studies of Texas A&M University...-WITH- PROPANE-DISTILLATION A Dissertation by NAMIT JAISWAL Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of DOCTOR OF PHILOSOPHY Approved...

  4. X-ray CT Observations of Methane Hydrate Distribution Changes over Time in a Natural Sediment Core from the BPX-DOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test Well

    E-Print Network [OSTI]

    Kneafsey, T.J.

    2012-01-01T23:59:59.000Z

    and Englezos, P. , 2009. Gas hydrate formation in a variableDOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test WellFormation of natural gas hydrates in marine sediments. 1.

  5. Capture and Use of Coal Mine Ventilation Air Methane

    SciTech Connect (OSTI)

    Deborah Kosmack

    2008-10-31T23:59:59.000Z

    CONSOL Energy Inc., in conjunction with MEGTEC Systems, Inc., and the U.S. Department of Energy with the U.S. Environmental Protection Agency, designed, built, and operated a commercial-size thermal flow reversal reactor (TFRR) to evaluate its suitability to oxidize coal mine ventilation air methane (VAM). Coal mining, and particularly coal mine ventilation air, is a major source of anthropogenic methane emissions, a greenhouse gas. Ventilation air volumes are large and the concentration of methane in the ventilation air is low; thus making it difficult to use or abate these emissions. This test program was conducted with simulated coal mine VAM in advance of deploying the technology on active coal mine ventilation fans. The demonstration project team installed and operated a 30,000 cfm MEGTEC VOCSIDIZER oxidation system on an inactive coal mine in West Liberty, WV. The performance of the unit was monitored and evaluated during months of unmanned operation at mostly constant conditions. The operating and maintenance history and how it impacts the implementation of the technology on mine fans were investigated. Emission tests showed very low levels of all criteria pollutants at the stack. Parametric studies showed that the equipment can successfully operate at the design specification limits. The results verified the ability of the TFRR to oxidize {ge}95% of the low and variable concentration of methane in the ventilation air. This technology provides new opportunities to reduce greenhouse gas emissions by the reduction of methane emissions from coal mine ventilation air. A large commercial-size installation (180,000 cfm) on a single typical mine ventilation bleeder fan would reduce methane emissions by 11,000 to 22,100 short tons per year (the equivalent of 183,000 to 366,000 metric tonnes carbon dioxide).

  6. Applying guidance for methane emission estimation for landfills

    SciTech Connect (OSTI)

    Scharff, Heijo [NV Afvalzorg, Postbus 2, 1566 ZG Assendelft (Netherlands)]. E-mail: h.scharff@afvalzorg.nl; Jacobs, Joeri [NV Afvalzorg, Postbus 2, 1566 ZG Assendelft (Netherlands)]. E-mail: j.jacobs@afvalzorg.nl

    2006-07-01T23:59:59.000Z

    Quantification of methane emission from landfills is important to evaluate measures for reduction of greenhouse gas emissions. Both the United Nations and the European Union have adopted protocols to ensure quantification of methane emission from individual landfills. The purpose of these protocols is to disclose emission data to regulators and the general public. Criteria such as timeliness, completeness, certainty, comparability, consistency and transparency are set for inclusion of emission data in a publicly accessible database. All methods given as guidance to landfill operators to estimate landfill methane emissions are based on models. In this paper the consequences of applying six different models for estimates of three landfills are explored. It is not the intention of this paper to criticise or validate models. The modelling results are compared with whole site methane emission measurements. A huge difference in results is observed. This raises doubts about the accuracy of the models. It also indicates that at least some of the criteria previously mentioned are not met for the tools currently available to estimate methane emissions from individual landfills. This will inevitably lead to compiling and comparing data with an incomparable origin. Harmonisation of models is recommended. This may not necessarily reduce uncertainty, but it will at least result in comparable, consistent and transparent data.

  7. METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST

    SciTech Connect (OSTI)

    Donn McGuire; Steve Runyon; Richard Sigal; Bill Liddell; Thomas Williams; George Moridis

    2005-02-01T23:59:59.000Z

    Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project is in the final stages of a cost-shared partnership between Maurer Technology, Noble Corporation, Anadarko Petroleum, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. Hot Ice No. 1 was planned to test the Ugnu and West Sak sequences for gas hydrates and a concomitant free gas accumulation on Anadarko's 100% working interest acreage in section 30 of Township 9N, Range 8E of the Harrison Bay quadrangle of the North Slope of Alaska. The Ugnu and West Sak intervals are favorably positioned in the hydrate-stability zone over an area extending from Anadarko's acreage westward to the vicinity of the aforementioned gas-hydrate occurrences. This suggests that a large, north-to-south trending gas-hydrate accumulation may exist in that area. The presence of gas shows in the Ugnu and West Sak reservoirs in wells situated eastward and down dip of the Hot Ice location indicate that a free-gas accumulation may be trapped by gas hydrates. The Hot Ice No. 1 well was designed to core from the surface to the base of the West Sak interval using the revolutionary and new Arctic Drilling Platform in search of gas hydrate and free gas accumulations at depths of approximately 1200 to 2500 ft MD. A secondary objective was the gas-charged sands of the uppermost Campanian interval at approximately 3000 ft. Summary results of geophysical analysis of the well are presented in this report.

  8. Heat transfer coefficients for propane (R-290), isobutane (R-600a), and 50/50 mixture of propane and isobutane

    SciTech Connect (OSTI)

    Mathur, G.D. [Zexel USA Corp., Decatur, IL (United States)

    1998-12-31T23:59:59.000Z

    Tube-side heat transfer coefficients for single-phase flow, evaporation, and condensation are presented for propane (R-290), isobutane (R-600a), and a 50/50 mixture (by weight) of propane and isobutane. Heat transfer coefficients have been presented for smooth tubes based on the standard correlations available in the literature for pure refrigerants. The correlations for evaporation and condensation have previously been verified for R-12 and other refrigerants. The correlations for evaporation and condensation have previously been verified for R-12 and other refrigerants. The mass flux of the refrigerant is varied over a wide range that is typically encountered in residential, commercial, and automotive applications. Evaporation temperatures of {minus}6.7 C (20 F) and 4.4 C (40 F) and condensation temperatures of 37.8 C (100 F) and 48.9 C (120 F) have been used for this investigation. The heat transfer coefficients for hydrocarbons (R-290, R-600a, R-290/R-600a) have been compared with R-12 and R-134a. The REFPROP computer program developed by the National Institute of Standards and Technology (NIST) has been used to determine the thermodynamic properties for R-290, R-600a, and R-290/R-600a. This study shows that the heat transfer coefficients for hydrocarbons are significantly higher than those for both R-12 and R-134a. For the range of refrigerant temperatures and mass flux studied, single-phase vapor heat transfer coefficients for hydrocarbons are greater by 234% to 259% in comparison to R-12 and are greater by 167% to 181% in comparison to R-134a. The single-phase liquid heat transfer coefficients for hydrocarbons are greater by 193% to 245% in comparison to R-12; and are greater by 155% to 198% in comparison to R-134a. Average evaporative heat transfer coefficients for hydrocarbons are greater by 194% to 238% in comparison to R-12 and are greater by 157% to 192% in comparison to R-134a. Finally, average condensing coefficients are greater by 220% to 233% in comparison to R-12 and are greater by 177% to 187% in comparison to R-134a. Tables 3 through 6 show a summary of the heat transfer coefficient enhancement of the hydrocarbons in comparison to both R-12 and R-134a.

  9. This article appeared in a journal published by Elsevier. The attached copy is furnished to the author for internal non-commercial research

    E-Print Network [OSTI]

    Semprini, Lewis

    institution and sharing with colleagues. Other uses, including reproduction and distribution, or selling,2-dichloroethene (cis-DCE) using propane and methane as growth substrates. Tests were performed in groundwater con transformation rate coefficients. Evidence that gas-sparging of propane (or methane) and oxygen had stimulated

  10. Identification of the source of methane at a hazardous waste treatment facility using isotopic analysis

    SciTech Connect (OSTI)

    Hackley, K.C.; Liu, C.L. (Illinois State Geological Survey, Peabody, IL (United States)); Trainor, D.P. (Dames and Moore, Madison, WI (United States))

    1992-01-01T23:59:59.000Z

    Isotopic analyses have been used to determine the source of methane in subsurface sediments at a hazardous waste treatment facility in the Lake Calumet area of Chicago, Illinois. The study area is surrounded by landfills and other waste management operations and has a long history of waste disposal. The facility property consists of land constructed of approximately 15 feet of fill placed over lake sediments. The fill is underlain by successively older lacustrine and glacial till deposits to a maximum depth of approximately 80 feet. During a subsurface investigation of the site performed for a RCRA Facility Investigation of former solid waste management units (SWMUs) in the fill, significant quantities of methane were encountered in the natural deposits. Gas samples were collected from the headspace of 11 piezometers screened at depths of approximately 30, 40, and 50 feet beneath the surface. Methane concentrations up to 75% by volume were observed in some of the piezometers. Stable isotope analyses were completed on methane and associated CO[sub 2] separated from the gas samples. Radiocarbon (C-14) analyses were also completed on several of the samples. The delta C-13 results for the intermediate and deep zones are indicative of methane produced by microbial reduction of CO[sub 2]. The methane occurring in the shallow zone appears to be a mixture of methane from the intermediate zone and methane produced by microbial fermentation of naturally (nonanthropogenic) buried organic matter within the shallow lacustrine sediments. According to the isotopic and chemical results, the methane does not appear to be related to gas generation from nearby landfills or from organic wastes previously placed in the former facility SWMUs.

  11. Partial oxidation of methane to syngas in different reactor types

    SciTech Connect (OSTI)

    Lapszewicz, J.A.; Campbell, I.; Charlton, B.G.; Foulds, G.A. [CSIRO Division of Coal and Energy Technology, Menai (Australia)

    1995-12-01T23:59:59.000Z

    The performance of Rh/ZnO/{gamma}-Al{sub 2}O{sub 3} catalyst for partial oxidation of methane to syngas was compared in fixed and fluidised bed reactors. Catalyst activity was found not to be a limiting factor under any experimental conditions and complete oxygen conversions were observed in all tests. In the fixed bed reactor both methane conversion and syngas selectivity were increasing with space velocity as the result of an autothermal effect. Satisfactory control of the catalyst temperature at high space velocities could only be achieved with addition of inert diluent or steam to the feed. Different conversion and selectivity patterns were observed in fluidised bed reactor. Methane conversion and carbon monoxide selectivity were decreasing with increasing gas flow. By contrast, hydrogen selectivity showed distinct maximum at medium space velocities. These results are interpreted in terms of catalyst backmixing and its effect on primary and secondary reactions. Improved temperature control was also achieved in fluidised bed reactor. Several experiments using fluidised bed reactor were carried out at elevated pressures. To eliminate the occurrence of non-catalytic gas phase reactions between methane and oxygen very short feed mixing times (< 1 ms) were employed. Despite these measures the reactor could not be successfully operated at pressures above 0.7 MPa. The implications of these findings for process development are discussed.

  12. Assessment of the risk of transporting propane by truck and train

    SciTech Connect (OSTI)

    Geffen, C.A.

    1980-03-01T23:59:59.000Z

    The risk of shipping propane is discussed and the risk assessment methodology is summarized. The risk assessment model has been constructed as a series of separate analysis steps to allow the risk to be readily reevaluated as additional data becomes available or as postulated system characteristics change. The transportation system and accident environment, the responses of the shipping system to forces in transportation accidents, and release sequences are evaluated to determine both the likelihood and possible consequences of a release. Supportive data and analyses are given in the appendices. The risk assessment results are related to the year 1985 to allow a comparison with other reports in this series. Based on the information presented, accidents involving tank truck shipments of propane will be expected to occur at a rate of 320 every year; accidents involving bobtails would be expected at a rate of 250 every year. Train accidents involving propane shipments would be expected to occur at a rate of about 60 every year. A release of any amount of material from propane trucks, under both normal transportation and transport accident conditions, is to be expected at a rate of about 110 per year. Releases from propane rail tank cars would occur about 40 times a year. However, only those releases that occur during a transportation accident or involve a major tank defect will include sufficient propane to present the potential for danger to the public. These significant releases can be expected at the lower rate of about fourteen events per year for truck transport and about one event every two years for rail tank car transport. The estimated number of public fatalities resulting from these significant releases in 1985 is fifteen. About eleven fatalities per year result from tank truck operation, and approximately half a death per year stems from the movement of propane in rail tank cars.

  13. Upgrading Methane Using Ultra-Fast Thermal Swing Adsorption

    SciTech Connect (OSTI)

    Anna Lee Tonkovich

    2004-07-01T23:59:59.000Z

    The purpose of this project is to design and demonstrate an approach to upgrade low-BTU methane streams from coal mines to pipeline-quality natural gas. The objective of Phase I of the project was to assess the technical feasibility and cost of upgrading low-BTU methane streams using ultra-fast thermal swing adsorption (TSA) using Velocys modular microchannel process technology. The objective of Phase II is to demonstrate the process at the bench scale. The project is on schedule and on budget. A technical and economic feasibility assessment was completed in Task 3. The proposed Velocys technology appears feasible for the methane upgrading market. Evaluated categories include adsorbent selection, rapid-cycle valve selection, microchannel manufacturability assessment, and system design and cost. The selected adsorbent, granular microporous carbon from either Barnaby-Sutcliffe or Calgon, experimentally demonstrated sufficient methane capacity under differential temperature at 100 pounds per square inch gauge. Several valve options were identified, including candidates that can operate millions of cycles between refurbishment. The microchannel adsorber and desorber designs were made using internal Velocys manufacturability standards, and the associated costs are acceptable as included with the complete nitrogen rejection unit (NRU) cost projection. A system design and cost estimate was completed for the NRU section of the methane upgrading system. As integrated into the complete system, the cost is in line with the market requirement. The system has six main unit operations: feed compressor, dehydration unit, nitrogen rejection unit, deoxygenator, carbon dioxide scrubber, and a sales compressor. The NRU is the focus of the development program, and a bench-scale demonstration will be initiated in the next fiscal year. The Velocys NRU system targets producing methane with greater than 96% purity and at least 90% recovery for final commercial operation. A preliminary cost analysis of the methane upgrading system, including the Velocys NRU, suggests that costs below $2.00 per million (MM) BTU methane may be achieved. The cost for a conventional methane upgrading system is well above $2.30 per MM BTU, as benchmarked in an Environmental Protection Agency study.

  14. Lean and ultralean stretched propane-air counterflow flames

    SciTech Connect (OSTI)

    Cheng, Zhongxian; Pitz, Robert W. [Mechanical Engineering Department, Vanderbilt University, Box 1592, Station B, Nashville, TN 37235 (United States); Wehrmeyer, Joseph A. [Aerospace Testing Alliance, Building 1099, Avenue C, Arnold Air Force Base, TN 37389 (United States)

    2006-06-15T23:59:59.000Z

    Stretched laminar flame structures for a wide range of C{sub 3}H{sub 8}-air mixtures vs hot products are investigated by laser-based diagnostics and numerical simulation. The hot products are produced by a lean H{sub 2}-air premixed flame. The effect of stretch rate and equivalence ratio on four groups of C{sub 3}H{sub 8}-air flame structures is studied in detail by Raman scattering measurements and by numerical calculations of the major species concentration and temperature profiles. The equivalence ratio, f, is varied from a near-stoichiometric condition (f=0.86) to the sublean limit (f=0.44) and the stretch rate varies from 90 s{sup -1} to near extinction. For most of these C{sub 3}H{sub 8}-air lean mixtures, hot products are needed to maintain the flame. The significant feature of these flames is the relatively low flame temperatures (1200-1800 K). For this temperature range, the predicted C{sub 3}H{sub 8}-air flame structure is sensitive to the specific chemical kinetic mechanism. Two types of flame structures (a lean self-propagating flame and a lean diffusion-controlled flame) are obtained based on the combined effect of stretch and equivalence ratio. Three different mechanisms, the M5 mechanism, the Optimized mechanism, and the San Diego mechanism, are chosen for the numerical simulations. None of the propane chemical mechanisms give good agreement with the data over the entire range of flame conditions. (author)

  15. Hydronic Heating Coil Versus Propane Furnace, Rehoboth Beach, Delaware (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2014-01-01T23:59:59.000Z

    Insight Homes constructed two houses in Rehoboth Beach, Delaware, with identical floor plans and thermal envelopes but different heating and domestic hot water (DHW) systems. Each house is 1,715-ft2 with a single story, three bedrooms, two bathrooms, and the heating, ventilation, and air conditioning (HVAC) systems and ductwork located in conditioned crawlspaces. The standard house, which the builder offers as its standard production house, uses an air source heat pump (ASHP) with supplemental propane furnace heating. The Building America test house uses the same ASHP unit with supplemental heat provided by the DHW heater (a combined DHW and hydronic heating system, where the hydronic heating element is in the air handler). Both houses were occupied during the test period. Results indicate that efficiency of the two heating systems was not significantly different. Three issues dominate these results; lower system design performance resulting from the indoor refrigerant coil selected for the standard house, an incorrectly functioning defrost cycle in the standard house, and the low resolution of the natural gas monitoring equipment. The thermal comfort of both houses fell outside the ASHRAE Standard 55 heating range but was within the ACCA room-to-room temperature range when compared to the thermostat temperature. The monitored DHW draw schedules were input into EnergyPlus to evaluate the efficiency of the tankless hot water heater model using the two monitored profiles and the Building America House Simulation Protocols. The results indicate that the simulation is not significantly impacted by the draw profiles.

  16. Dynamics of Propane in Silica Mesopores Formed upon PropyleneHydrogenation over Pt Nanoparticles by Time-Resolved FT-IRSpectroscopy

    SciTech Connect (OSTI)

    Waslylenko, Walter; Frei, Heinz

    2007-01-31T23:59:59.000Z

    Propylene hydrogenation over Pt nanoparticles supported onmesoporous silica type SBA-15 was monitored by time-resolved FT-IRspectroscopy at 23 ms resolution using short propylene gas pulses thatjoined a continuous flow of hydrogen in N2 (1 atm total pressure).Experiments were conducted in the temperature range 323-413 K. Propanewas formed within 100 milliseconds or faster. The CH stretching regionrevealed distinct bands for propane molecules emerging inside thenanoscale channels of the silica support. Spectral analysis gave thedistribution of the propane product between support and surrounding gasphase as function of time. Kinetic analysis showed that the escape ofpropane molecules from the channels occurred within hundreds ofmilliseconds (3.1 + 0.4 s-1 at 383 K). A steady state distribution ofpropane between gas phase and mesoporous support is established as theproduct is swept from the catalyst zone by the continuous flow ofhydrogen co-reactant. This is the first direct spectroscopic observationof emerging products of heterogeneous catalysis on nanoporous supportsunder reaction conditions.

  17. No. 2 heating oil/propane program 1994--1995. Final report

    SciTech Connect (OSTI)

    McBrien, J.

    1995-05-01T23:59:59.000Z

    During the 1994--95 heating season, the Massachusetts Division of Energy Resources (DOER) participated in a joint data collection program between several state energy offices and the federal Department of Energy`s (DOE) Energy Information Administration (EIA). The purpose of the program was to collect and monitor retail and wholesale heating oil and propane prices and inventories from October 1994 through March 1995. This program augmented the existing Massachusetts data collection system and served several important functions. The information helped the federal and state governments respond to consumer, congressional and media inquiries regarding No. 2 oil and propane. The information also provided policy decision-makers with timely, accurate and consistent data to monitor current heating oil and propane markets and develop appropriate state responses when necessary. In addition, the communication network between states and the DOE was strengthened through this program. This final report begins with an overview of the unique events that had an impact on the petroleum markets prior to and during the reporting period. Next, the report summarizes the results from residential heating oil and propane price surveys conducted by DOER over the 1994--95 heating season. The report also incorporates the wholesale heating oil and propane prices and inventories collected by EIA and distributed to the states. Finally, the report outlines DOER`s use of the data.

  18. METHANE AND n-BUTANE OXIDATION WITH CO2 UNDER RADIOFREQUENCY PLASMAS OF MODERATE PRESSURES (*)

    E-Print Network [OSTI]

    Boyer, Edmond

    the gas to the reactor walls. It is capacitively coupled to the radiofrequency generator (35 MHz, 10 k ) and constant pressure of 20 torr. Experimental details on discharges parameters, sampling procedure, gas analy1205 METHANE AND n-BUTANE OXIDATION WITH CO2 UNDER RADIOFREQUENCY PLASMAS OF MODERATE PRESSURES

  19. Earth'sFuture Remote sensing of fugitive methane emissions from oil and

    E-Print Network [OSTI]

    Dickerson, Russell R.

    Earth'sFuture Remote sensing of fugitive methane emissions from oil and gas production in North and tight oil reservoirs to exploit formerly inaccessible or unprofitable energy resources in rock and oil provide an opportunity to achieve energy self-sufficiency and to reduce greenhouse gas emissions

  20. VOLUME 88 NUMBER 19 8 MAY 2007 Methane hydrate is a clathrate, an ice-like

    E-Print Network [OSTI]

    Mazzini, Adriano

    ., 1999; Bouriak et al., 2000; Hovland and Svensen, 2006], the pres- ence of gas hydrate had never been are lined with hydrate and whether any free gas exists in the chimneys, and to provide evidence209 VOLUME 88 NUMBER 19 8 MAY 2007 Methane hydrate is a clathrate, an ice-like solid formed from

  1. Large-scale simulation of methane dissociation along the West Spitzbergen Margin

    SciTech Connect (OSTI)

    Reagan, M.T.; Moridis, G.J.

    2009-07-15T23:59:59.000Z

    Vast quantities of methane are trapped in oceanic hydrate deposits, and there is concern that a rise in the ocean temperature will induce dissociation of these hydrate accumulations, potentially releasing large amounts of methane into the atmosphere. The recent discovery of active methane gas venting along the landward limit of the gas hydrate stability zone (GHSZ) on the shallow continental slope west of Spitsbergen could be an indication of this process, if the source of the methane can be confidently attributed to dissociating hydrates. In the first large-scale simulation study of its kind, we simulate shallow hydrate dissociation in conditions representative of the West Spitsbergen margin to test the hypothesis that the observed gas release originated from hydrates. The simulation results are consistent with this hypothesis, and are in remarkable agreement with the recently published observations. They show that shallow, low-saturation hydrate deposits, when subjected to temperature increases at the seafloor, can release significant quantities of methane, and that the releases will be localized near the landward limit of the top of the GHSZ. These results indicate the possibility that hydrate dissociation and methane release may be both a consequence and a cause of climate change.

  2. Water storage key factor in coalbed methane production

    SciTech Connect (OSTI)

    Luckianow, B.J. (Taurus Exploration Inc., Birmingham, AL (US)); Hall, W.L. (Dames and Moore, Atlanta, GA (US))

    1991-03-11T23:59:59.000Z

    Storage ponds provide a cost-effective means to temporarily retain water produced with coalbed methane and permit gas production during times when stream flow rates drop. Normally, water produced with the gas is run into nearby streams, with the dilution rate closely monitored and controlled by environmental agencies. During low stream flow in the Black Warrior basin, Ala., large volumes of produced water must be stored to prevent shut-in of coalbed methane fields. The authors discuss how they constructed such production water facilities for the Cedar Cove field to eliminate periodic field shut-ins as a result of excess water production. The effectiveness of such a storage approach is governed by receiving stream flow variability, production water flow characteristics, and the economics of storage pond construction.

  3. Reducing Open Cell Landfill Methane Emissions with a Bioactive Alternative Daily

    SciTech Connect (OSTI)

    Helene Hilger; James Oliver; Jean Bogner; David Jones

    2009-03-31T23:59:59.000Z

    Methane and carbon dioxide are formed in landfills as wastes degrade. Molecule-for-molecule, methane is about 20 times more potent than carbon dioxide at trapping heat in the earth's atmosphere, and thus, it is the methane emissions from landfills that are scrutinized. For example, if emissions composed of 60% methane and 40% carbon dioxide were changed to a mix that was 40% methane and 60% carbon dioxide, a 30% reduction in the landfill's global warming potential would result. A 10% methane, 90% carbon dioxide ratio will result in a 75% reduction in global warming potential compared to the baseline. Gas collection from a closed landfill can reduce emissions, and it is sometimes combined with a biocover, an engineered system where methane oxidizing bacteria living in a medium such as compost, convert landfill methane to carbon dioxide and water. Although methane oxidizing bacteria merely convert one greenhouse gas (methane) to another (carbon dioxide), this conversion can offer significant reductions in the overall greenhouse gas contribution, or global warming potential, associated with the landfill. What has not been addressed to date is the fact that methane can also escape from a landfill when the active cell is being filled with waste. Federal regulations require that newly deposited solid waste to be covered daily with a 6 in layer of soil or an alternative daily cover (ADC), such as a canvas tarp. The aim of this study was to assess the feasibility of immobilizing methane oxidizing bacteria into a tarp-like matrix that could be used for alternative daily cover at open landfill cells to prevent methane emissions. A unique method of isolating methanotrophs from landfill cover soil was used to create a liquid culture of mixed methanotrophs. A variety of prospective immobilization techniques were used to affix the bacteria in a tarp-like matrix. Both gel encapsulation of methanotrophs and gels with liquid cores containing methanotrophs were readily made but prone to rapid desiccation. Bacterial adsorption onto foam padding, natural sponge, and geotextile was successful. The most important factor for success appeared to be water holding capacity. Prototype biotarps made with geotextiles plus adsorbed methane oxidizing bacteria were tested for their responses to temperature, intermittent starvation, and washing (to simulate rainfall). The prototypes were mesophilic, and methane oxidation activity remained strong after one cycle of starvation but then declined with repeated cycles. Many of the cells detached with vigorous washing, but at least 30% appeared resistant to sloughing. While laboratory landfill simulations showed that four-layer composite biotarps made with two different types of geotextile could remove up to 50% of influent methane introduced at a flux rate of 22 g m{sup -2} d{sup -1}, field experiments did not yield high activity levels. Tests revealed that there were high hour-to-hour flux variations in the field, which, together with frequent rainfall events, confounded the field testing. Overall, the findings suggest that a methanotroph embedded biotarp appears to be a feasible strategy to mitigate methane emission from landfill cells, although the performance of field-tested biotarps was not robust here. Tarps will likely be best suited for spring and summer use, although the methane oxidizer population may be able to shift and adapt to lower temperatures. The starvation cycling of the tarp may require the capacity for intermittent reinoculation of the cells, although it is also possible that a subpopulation will adapt to the cycling and become dominant. Rainfall is not expected to be a major factor, because a baseline biofilm will be present to repopulate the tarp. If strong performance can be achieved and documented, the biotarp concept could be extended to include interception of other compounds beyond methane, such as volatile aromatic hydrocarbons and chlorinated solvents.

  4. Future designs of raw-gas conversion systems

    SciTech Connect (OSTI)

    Colton, J.W.; Fleming, D.K.

    1981-01-01T23:59:59.000Z

    Many different processes are available to convert raw gas to substitute natural gas (SNG). Several additional processes have been proposed and are now in development. An Institute of Gas Technology (IGT) computer program assesses the efficiency of various raw-gas conversion processes for the recovery of high-temperature enthalpy and the net export of high-pressure steam. The steam balance is a prime measure of economic attractiveness of the alternative processes. Of the currently available processes, the sequence that uses sour-gas shift followed by conventional cold sweetening and nickel-based multistage methanation is preferred. Certain novel process concepts beginning with sour-gas shift and hot-gas carbon dioxide removal should be a significant improvement. The improved processes will require either sulfur-tolerant methanation or hot-gas sulfur removal plus conventional methanation. In either case, the gas would not be cooled to room temperature before being entirely converted to methane.

  5. Characterization of Methane Degradation and Methane-Degrading Microbes in Alaska Coastal Water

    SciTech Connect (OSTI)

    David Kirchman

    2011-12-31T23:59:59.000Z

    The net flux of methane from methane hydrates and other sources to the atmosphere depends on methane degradation as well as methane production and release from geological sources. The goal of this project was to examine methane-degrading archaea and organic carbon oxidizing bacteria in methane-rich and methane-poor sediments of the Beaufort Sea, Alaska. The Beaufort Sea system was sampled as part of a multi-disciplinary expedition (â??Methane in the Arctic Shelfâ? or MIDAS) in September 2009. Microbial communities were examined by quantitative PCR analyses of 16S rRNA genes and key methane degradation genes (pmoA and mcrA involved in aerobic and anaerobic methane degradation, respectively), tag pyrosequencing of 16S rRNA genes to determine the taxonomic make up of microbes in these sediments, and sequencing of all microbial genes (â??metagenomesâ?). The taxonomic and functional make-up of the microbial communities varied with methane concentrations, with some data suggesting higher abundances of potential methane-oxidizing archaea in methane-rich sediments. Sequence analysis of PCR amplicons revealed that most of the mcrA genes were from the ANME-2 group of methane oxidizers. According to metagenomic data, genes involved in methane degradation and other degradation pathways changed with sediment depth along with sulfate and methane concentrations. Most importantly, sulfate reduction genes decreased with depth while the anaerobic methane degradation gene (mcrA) increased along with methane concentrations. The number of potential methane degradation genes (mcrA) was low and inconsistent with other data indicating the large impact of methane on these sediments. The data can be reconciled if a small number of potential methane-oxidizing archaea mediates a large flux of carbon in these sediments. Our study is the first to report metagenomic data from sediments dominated by ANME-2 archaea and is one of the few to examine the entire microbial assemblage potentially involved in anaerobic methane oxidation.

  6. No. 2 heating oil/propane program. Final report, 1992/93

    SciTech Connect (OSTI)

    McBrien, J.

    1993-05-01T23:59:59.000Z

    During the 1992--93 heating season, the Massachusetts Division Energy Resources (DOER) participated in a joint data collection program between several state energy offices and the federal Department of Energy`s (DOE) Energy Information Administration (EIA). The purpose of the program was to collect and monitor retail and wholesale heating oil and propane prices and inventories from October, 1992 through March, 1993. This final report begins with an overview of the unique events which had an impact on the petroleum markets prior to and during the reporting period. Next, the report summarizes the results from residential heating oil and propane price surveys conducted by DOER over the 1992--93 heating season. The report also incorporates the wholesale heating oil and propane prices and inventories collected by the EIA and distributed to the states. Finally, the report outlines DOER`s use of the data.

  7. Performance analysis of a series of hermetic reciprocating compressors working with R290 (propane) and R407C

    E-Print Network [OSTI]

    Fernández de Córdoba, Pedro

    Performance analysis of a series of hermetic reciprocating compressors working with R290 (propane Abstract In this paper, a series of compressors with different capacities and geometries working with propane as refrigerant are analyzed in terms of the compressor model developed by [E. Navarro, E. Granryd

  8. METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST

    SciTech Connect (OSTI)

    Thomas E. Williams; Keith Millheim; Bill Liddell

    2005-03-01T23:59:59.000Z

    Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Oil-field engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in Arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrates agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project is a cost-shared partnership between Maurer Technology, Anadarko Petroleum, Noble Corporation, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to help identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. As part of the project work scope, team members drilled and cored the HOT ICE No. 1 on Anadarko leases beginning in January 2003 and completed in March 2004. Due to scheduling constraints imposed by the Arctic drilling season, operations at the site were suspended between April 21, 2003 and January 30, 2004. An on-site core analysis laboratory was designed, constructed and used for determining physical characteristics of frozen core immediately after it was retrieved from the well. The well was drilled from a new and innovative Anadarko Arctic Platform that has a greatly reduced footprint and environmental impact. Final efforts of the project were to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists for future hydrate operations. Unfortunately, no gas hydrates were encountered in this well; however, a wealth of information was generated and is contained in the project reports.

  9. The determination of compressibility factors of gaseous propane-nitrogen mixtures 

    E-Print Network [OSTI]

    Dickson, Cecil Herman

    1955-01-01T23:59:59.000Z

    LIBRARY A A N O'iLLEOE OF 1EXAS THE DETERMINATION OF COMPRESSIBILITY FACTORS OF GASEOUS PROPANE-NITROGEIN MIXTURES A Thesis Cecil Herman Dickson Submitted to the Graduate School of the Agricultural and Mechanical College of' Texas in partial... f'ulf'illment of the requirements for the de~ree of MASTER OF SCIENCE Ma]or GubjectI Chemistry May I&55 THE DETERMINATION OF COMPRESSIBILITY FACTORS OF GASEOUS PROPANE-NITROGEN MIXTURES A Thesis Cecil Herman Dickson Approved as to style...

  10. The determination of compressibility factors of gaseous propane-nitrogen mixtures

    E-Print Network [OSTI]

    Dickson, Cecil Herman

    1955-01-01T23:59:59.000Z

    LIBRARY A A N O'iLLEOE OF 1EXAS THE DETERMINATION OF COMPRESSIBILITY FACTORS OF GASEOUS PROPANE-NITROGEIN MIXTURES A Thesis Cecil Herman Dickson Submitted to the Graduate School of the Agricultural and Mechanical College of' Texas in partial... f'ulf'illment of the requirements for the de~ree of MASTER OF SCIENCE Ma]or GubjectI Chemistry May I&55 THE DETERMINATION OF COMPRESSIBILITY FACTORS OF GASEOUS PROPANE-NITROGEN MIXTURES A Thesis Cecil Herman Dickson Approved as to style...

  11. Nonequilibrium clumped isotope signals in microbial methane

    E-Print Network [OSTI]

    Wang, David T.

    Methane is a key component in the global carbon cycle with a wide range of anthropogenic and natural sources. Although isotopic compositions of methane have traditionally aided source identification, the abundance of its ...

  12. Formation and retention of methane in coal. Final report

    SciTech Connect (OSTI)

    Hucka, V.J.; Bodily, D.M.; Huang, H.

    1992-05-15T23:59:59.000Z

    The formation and retention of methane in coalbeds was studied for ten Utah coal samples, one Colorado coal sample and eight coal samples from the Argonne Premium Coal Sample Bank.Methane gas content of the Utah and Colorado coals varied from zero to 9 cm{sup 3}/g. The Utah coals were all high volatile bituminous coals. The Colorado coal was a gassy medium volatile bituminous coal. The Argonne coals cover a range or rank from lignite to low volatile bituminous coal and were used to determine the effect of rank in laboratory studies. The methane content of six selected Utah coal seams and the Colorado coal seam was measured in situ using a special sample collection device and a bubble desorbometer. Coal samples were collected at each measurement site for laboratory analysis. The cleat and joint system was evaluated for the coal and surrounding rocks and geological conditions were noted. Permeability measurements were performed on selected samples and all samples were analyzed for proximate and ultimate analysis, petrographic analysis, {sup 13}C NMR dipolar-dephasing spectroscopy, and density analysis. The observed methane adsorption behavior was correlated with the chemical structure and physical properties of the coals.

  13. Variability of the methane trapping in martian subsurface clathrate hydrates

    E-Print Network [OSTI]

    Caroline Thomas; Olivier Mousis; Sylvain Picaud; Vincent Ballenegger

    2008-10-23T23:59:59.000Z

    Recent observations have evidenced traces of methane CH4 heterogeneously distributed in the martian atmosphere. However, because the lifetime of CH4 in the atmosphere of Mars is estimated to be around 300-600 years on the basis of photochemistry, its release from a subsurface reservoir or an active primary source of methane have been invoked in the recent literature. Among the existing scenarios, it has been proposed that clathrate hydrates located in the near subsurface of Mars could be at the origin of the small quantities of the detected CH4. Here, we accurately determine the composition of these clathrate hydrates, as a function of temperature and gas phase composition, by using a hybrid statistical thermodynamic model based on experimental data. Compared to other recent works, our model allows us to calculate the composition of clathrate hydrates formed from a more plausible composition of the martian atmosphere by considering its main compounds, i.e. carbon dioxyde, nitrogen and argon, together with methane. Besides, because there is no low temperature restriction in our model, we are able to determine the composition of clathrate hydrates formed at temperatures corresponding to the extreme ones measured in the polar caps. Our results show that methane enriched clathrate hydrates could be stable in the subsurface of Mars only if a primitive CH4-rich atmosphere has existed or if a subsurface source of CH4 has been (or is still) present.

  14. Improved Basin Analog System to Characterize Unconventional Gas Resource

    E-Print Network [OSTI]

    Wu, Wenyan 1983-

    2012-10-02T23:59:59.000Z

    , the BASIN software is combined with PRISE in the UGRA system to estimate unconventional resource potential in frontier basins. The PRISE software contains information about the resources (conventional gas, conventional oil, shale gas, coalbed methane...

  15. Method for the photocatalytic conversion of methane

    DOE Patents [OSTI]

    Noceti, R.P.; Taylor, C.E.; D`Este, J.R.

    1998-02-24T23:59:59.000Z

    A method for converting methane to methanol is provided comprising subjecting the methane to visible light in the presence of a catalyst and an electron transfer agent. Another embodiment of the invention provides for a method for reacting methane and water to produce methanol and hydrogen comprising preparing a fluid containing methane, an electron transfer agent and a photolysis catalyst, and subjecting said fluid to visible light for an effective period of time. 3 figs.

  16. Method for the photocatalytic conversion of methane

    DOE Patents [OSTI]

    Noceti, Richard P. (Pittsburgh, PA); Taylor, Charles E. (Pittsburgh, PA); D'Este, Joseph R. (Pittsburgh, PA)

    1998-01-01T23:59:59.000Z

    A method for converting methane to methanol is provided comprising subjecting the methane to visible light in the presence of a catalyst and an electron transfer agent. Another embodiment of the invention provides for a method for reacting methane and water to produce methanol and hydrogen comprising preparing a fluid containing methane, an electron transfer agent and a photolysis catalyst, and subjecting said fluid to visible light for an effective period of time.

  17. SUR LA POSSIBILIT D'UTILISATION D'UNE CHAMBRE A BULLES A PROPANE POUR L'TUDE DES RACTIONS NUCLAIRES

    E-Print Network [OSTI]

    Boyer, Edmond

    175 A. SUR LA POSSIBILITÉ D'UTILISATION D'UNE CHAMBRE A BULLES A PROPANE POUR L'ÉTUDE DES RÉACTIONS. - Mise au point et étude des caractéristiques du fonctionnement d'une chambre à bulles à propane de 6 135 MeV. Abstract. 2014 Adjustment and studies of some characteristics of a 6 litre propane bubble

  18. Single-Site Vanadyl Activation, Functionalization, and Reoxidation Reaction Mechanism for Propane Oxidative Dehydrogenation on the Cubic V4O10 Cluster

    E-Print Network [OSTI]

    Goddard III, William A.

    Single-Site Vanadyl Activation, Functionalization, and Reoxidation Reaction Mechanism for Propane of density functional theory) to examine the detailed mechanism for propane reacting with a V4O10 cluster to model the catalytic oxidative dehydrogenation (ODH) of propane on the V2O5(001) surface. We here report

  19. Structure and critical function of Fe and acid sites in Fe-ZSM-5 in propane oxidative dehydrogenation with N2O and N2O decomposition

    E-Print Network [OSTI]

    Sklenak, Stepan

    Structure and critical function of Fe and acid sites in Fe-ZSM-5 in propane oxidative species Steamed Fe-zeolites Mössbauer spectroscopy UV­Vis FTIR H2-TPR N2O decomposition Propane oxidative of propane to propene with N2O. The evacuated non-steamed FeH-ZSM-5 contained high concentration of Brønsted

  20. Chemical kinetic modeling of oxy-fuel combustion of sour gas for enhanced oil recovery

    E-Print Network [OSTI]

    Bongartz, Dominik

    2014-01-01T23:59:59.000Z

    Oxy-fuel combustion of sour gas, a mixture of natural gas (primarily methane (CH 4 )), carbon dioxide (CO 2 ), and hydrogen sulfide (H 2 S), could enable the utilization of large natural gas resources, especially when ...

  1. The effect of natural gas supply on US renewable energy and CO2emissions

    E-Print Network [OSTI]

    Shearer, C; Shearer, C; Bistline, J; Inman, M; Davis, SJ; Davis, SJ

    2014-01-01T23:59:59.000Z

    leaks from North American natural gas systems Science 343of methane emissions at natural gas production sites in theThe effect of natural gas supply on US renewable energy and

  2. Comparison of kinetic and equilibrium reaction models in simulating gas hydrate behavior in porous media

    E-Print Network [OSTI]

    Kowalsky, Michael B.; Moridis, George J.

    2006-01-01T23:59:59.000Z

    with Diapirism and Gas Hydrates at the Head of the Cape FearSea-Level Low Stands Above Gas Hydrate-Bearing Sediments.rate constant of methane gas hydrate decomposition. Canadian

  3. Basin scale assessment of gas hydrate dissociation in response to climate change

    E-Print Network [OSTI]

    Reagan, M.

    2012-01-01T23:59:59.000Z

    Moridis GJ. Oceanic gas hydrate instability and dissociationKA. Potential effects of gas hydrate on human welfare, Proc.WS. A review of methane and gas hydrates in the dynamic,

  4. Methane conversion for application in fuel cells

    SciTech Connect (OSTI)

    Mulder, A. [Gastec N.V., Apeldoorn (Netherlands); Looy, F. van [Utrecht Univ. (Netherlands). Dept. of Inorganic Chemistry; Waveren, A. van; Wingerden, A.J.M. van

    1996-12-31T23:59:59.000Z

    Conventional steam reformers are large and expensive for small scale fuel cell installations. But also the high endothermicity of the reforming reaction for the production of synthesis gas is a drawback. An alternative to conventional steam reforming is the partial oxidation of methane to synthesis gas. This process is slightly exothermic. The flexibility of the process makes small scale application possible. However, the partial oxidation process seems especially attractive for application within a high temperature fuel cell, because of relatively high CO/H{sub 2}-ratio for the output gases. In this paper the results of the study on the mechanism of the partial oxidation to synthesis gas on silica-supported nickel catalysts are discussed. Moreover, a process for the partial oxidation is proposed in which air instead of oxygen can be used. Based on the results of the mechanistic study two processes for the catalytic partial oxidation are proposed and simulated using the Aspen Plus flowsheeting program with which the mass and heat balances were optimized.

  5. Methane Activation Structural and Mechanistic Requirements for

    E-Print Network [OSTI]

    Iglesia, Enrique

    Methane Activation Structural and Mechanistic Requirements for Methane Activation and Chemical and petrochemical processes and in fuel cells. The strong bonds in CH4 (439 kJmolÀ1 [1] ) and the endothermic nature by BP as part of the Methane Conversion Cooperative Research Program at the University of California

  6. Methane adsorption on Devonian shales 

    E-Print Network [OSTI]

    Li, Fan-Chang

    1992-01-01T23:59:59.000Z

    METHANE ADSORPTION ON DEVONIAN SHALES A Thesis by FAN-CHANG LI Submitted to thc Office of Graclua4e Sturiics of texas AgiM Ulllvel'sliy in pari, ial fulfilhuent of t, hc requirements I'or t, hc degree of ii IAS'I'Elf OF SCIL'NCE December... 1992 Major Subject, : Chemical Engineering METHANE ADSORPTION ON DEVONIAN SHALES A Thesis l&y I'AN-CHANC LI Approved as to style and contcut by: A. T. 'vtratson (Chair of Commitl. ee) John C. Slattery (Member) Bruce . Hcrhcrt (Memhcr...

  7. Methane adsorption on Devonian shales

    E-Print Network [OSTI]

    Li, Fan-Chang

    1992-01-01T23:59:59.000Z

    METHANE ADSORPTION ON DEVONIAN SHALES A Thesis by FAN-CHANG LI Submitted to thc Office of Graclua4e Sturiics of texas AgiM Ulllvel'sliy in pari, ial fulfilhuent of t, hc requirements I'or t, hc degree of ii IAS'I'Elf OF SCIL'NCE December... 1992 Major Subject, : Chemical Engineering METHANE ADSORPTION ON DEVONIAN SHALES A Thesis l&y I'AN-CHANC LI Approved as to style and contcut by: A. T. 'vtratson (Chair of Commitl. ee) John C. Slattery (Member) Bruce . Hcrhcrt (Memhcr...

  8. OXIDATIVE COUPLING OF METHANE USING INORGANIC MEMBRANE REACTORS

    SciTech Connect (OSTI)

    Dr. Y.H. Ma; Dr. W.R. Moser; Dr. A.G. Dixon; Dr. A.M. Ramachandra; Dr. Y. Lu; C. Binkerd

    1998-04-01T23:59:59.000Z

    The objective of this research is to study the oxidative coupling of methane in catalytic inorganic membrane reactors. A specific target is to achieve conversion of methane to C{sub 2} hydrocarbons at very high selectivity and higher yields than in conventional non-porous, co-feed, fixed bed reactors by controlling the oxygen supply through the membrane. A membrane reactor has the advantage of precisely controlling the rate of delivery of oxygen to the catalyst. This facility permits balancing the rate of oxidation and reduction of the catalyst. In addition, membrane reactors minimize the concentration of gas phase oxygen thus reducing non selective gas phase reactions, which are believed to be a main route for the formation of CO{sub x} products. Such gas phase reactions are a cause of decreased selectivity in the oxidative coupling of methane in conventional flow reactors. Membrane reactors could also produce higher product yields by providing better distribution of the reactant gases over the catalyst than the conventional plug flow reactors. Membrane reactor technology also offers the potential for modifying the membranes both to improve catalytic properties as well as to regulate the rate of the permeation/diffusion of reactants through the membrane to minimize by-product generation. Other benefits also exist with membrane reactors, such as the mitigation of thermal hot-spots for highly exothermic reactions such as the oxidative coupling of methane. The application of catalytically active inorganic membranes has potential for drastically increasing the yield of reactions which are currently limited by either thermodynamic equilibria, product inhibition, or kinetic selectivity.

  9. Quarterly Review of Methane from Coal-Seams Technology. Volume 9, Number 1, November 1991

    SciTech Connect (OSTI)

    McBane, R.A.; Schwochow, S.D.; Stevens, S.H.

    1991-11-01T23:59:59.000Z

    The paper contains: basin activities--(Powder River Basin, Wyoming and Montana, Wind River Basin-Wyoming, Greater Green River coal region-Wyoming and Colorado, Uinta Basin-Utah, Piceance Basin-Colorado, San Juan Basin-Colorado and New Mexico, Raton Basin-Colorado and New Mexico, and Black Warrior Basin-Alabama); features--(relation between basin hydrology and fruitland gas composition, San Juan Basin, Colorado and New Mexico); methane from coal seams research--(western Cretaceous coal seam project, multiple coal seams project, coalbed methane technology development in the Appalachian Basin, methane from coal deposits technical evaluation and data base (reservoir engineering and analysis), development of formation evaluation technology for coalbed methane development, improved evaluation of coal reservoirs through specialized core analysis, and effective design, real-data analysis, and post-job evaluation of hydraulic fracturing treatments); technical events--(the Coalbed Methane Forums in Denver, Eastern Coalbed Methane Forum in Tuscaloosa, Society of Petroleum Engineers--Gas Technology Symposium, and Society for Mining, Metallurgy, and Exploration--annual meeting).

  10. TECHNICAL JUSTIFICATION FOR CHOOSING PROPANE AS A CALIBRATION AGENT FOR TOTAL FLAMMABLE VOLATILE ORGANIC COMPOUND (VOC) DETERMINATIONS

    SciTech Connect (OSTI)

    DOUGLAS, J.G.

    2006-07-06T23:59:59.000Z

    This document presents the technical justification for choosing and using propane as a calibration standard for estimating total flammable volatile organic compounds (VOCs) in an air matrix. A propane-in-nitrogen standard was selected based on a number of criteria: (1) has an analytical response similar to the VOCs of interest, (2) can be made with known accuracy and traceability, (3) is available with good purity, (4) has a matrix similar to the sample matrix, (5) is stable during storage and use, (6) is relatively non-hazardous, and (7) is a recognized standard for similar analytical applications. The Waste Retrieval Project (WRP) desires a fast, reliable, and inexpensive method for screening the flammable VOC content in the vapor-phase headspace of waste containers. Table 1 lists the flammable VOCs of interest to the WRP. The current method used to determine the VOC content of a container is to sample the container's headspace and submit the sample for gas chromatography--mass spectrometry (GC-MS) analysis. The driver for the VOC measurement requirement is safety: potentially flammable atmospheres in the waste containers must be allowed to diffuse prior to processing the container. The proposed flammable VOC screening method is to inject an aliquot of the headspace sample into an argon-doped pulsed-discharge helium ionization detector (Ar-PDHID) contained within a gas chromatograph. No actual chromatography is performed; the sample is transferred directly from a sample loop to the detector through a short, inert transfer line. The peak area resulting from the injected sample is proportional to the flammable VOC content of the sample. However, because the Ar-PDHID has different response factors for different flammable VOCs, a fundamental assumption must be made that the agent used to calibrate the detector is representative of the flammable VOCs of interest that may be in the headspace samples. At worst, we desire that calibration with the selected calibrating agent overestimate the value of the VOCs in a sample. By overestimating the VOC content of a sample, we want to minimize false negatives. A false negative is defined as incorrectly estimating the VOC content of the sample to be below programmatic action limits when, in fact, the sample,exceeds the action limits. The disadvantage of overestimating the flammable VOC content of a sample is that additional cost may be incurred because additional sampling and GC-MS analysis may be required to confirm results over programmatic action limits. Therefore, choosing an appropriate calibration standard for the Ar-PDHID is critical to avoid false negatives and to minimize additional analytical costs.

  11. Utilization of coal mine methane for methanol and SCP production. Topical report, May 5, 1995--March 4, 1996

    SciTech Connect (OSTI)

    NONE

    1998-12-31T23:59:59.000Z

    The feasibility of utilizing a biological process to reduce methane emissions from coal mines and to produce valuable single cell protein (SCP) and/or methanol as a product has been demonstrated. The quantities of coal mine methane from vent gas, gob wells, premining wells and abandoned mines have been determined in order to define the potential for utilizing mine gases as a resource. It is estimated that 300 MMCFD of methane is produced in the United States at a typical concentration of 0.2-0.6 percent in ventilation air. Of this total, almost 20 percent is produced from the four Jim Walter Resources (JWR) mines, which are located in very gassy coal seams. Worldwide vent gas production is estimated at 1 BCFD. Gob gas methane production in the U.S. is estimated to be 38 MMCFD. Very little gob gas is produced outside the U.S. In addition, it is estimated that abandoned mines may generate as much as 90 MMCFD of methane. In order to make a significant impact on coal mine methane emissions, technology which is able to utilize dilute vent gases as a resource must be developed. Purification of the methane from the vent gases would be very expensive and impractical. Therefore, the process application must be able to use a dilute methane stream. Biological conversion of this dilute methane (as well as the more concentrated gob gases) to produce single cell protein (SCP) and/or methanol has been demonstrated in the Bioengineering Resources, Inc. (BRI) laboratories. SCP is used as an animal feed supplement, which commands a high price, about $0.11 per pound.

  12. Simulation studies of steam-propane injection for the Hamaca heavy oil field 

    E-Print Network [OSTI]

    Venturini, Gilberto Jose

    2002-01-01T23:59:59.000Z

    Simulation studies were performed to evaluate a novel technology, steam-propane injection, for the heavy Hamaca crude oil. The oil has a gravity of 9.3?API and a viscosity of 25,000 cp at 50?C. Two types of simulation studies were performed: a...

  13. Metallurgical failure analysis of a propane tank boiling liquid expanding vapor explosion (BLEVE).

    SciTech Connect (OSTI)

    Kilgo, Alice C.; Eckelmeyer, Kenneth Hall; Susan, Donald Francis

    2005-01-01T23:59:59.000Z

    A severe fire and explosion occurred at a propane storage yard in Truth or Consequences, N.M., when a truck ran into the pumping and plumbing system beneath a large propane tank. The storage tank emptied when the liquid-phase excess flow valve tore out of the tank. The ensuing fire engulfed several propane delivery trucks, causing one of them to explode. A series of elevated-temperature stress-rupture tears developed along the top of a 9800 L (2600 gal) truck-mounted tank as it was heated by the fire. Unstable fracture then occurred suddenly along the length of the tank and around both end caps, along the girth welds connecting the end caps to the center portion of the tank. The remaining contents of the tank were suddenly released, aerosolized, and combusted, creating a powerful boiling liquid expanding vapor explosion (BLEVE). Based on metallography of the tank pieces, the approximate tank temperature at the onset of the BLEVE was determined. Metallurgical analysis of the ruptured tank also permitted several hypotheses regarding BLEVE mechanisms to be evaluated. Suggestions are made for additional work that could provide improved predictive capabilities regarding BLEVEs and for methods to decrease the susceptibility of propane tanks to BLEVEs.

  14. Simulation studies of steam-propane injection for the Hamaca heavy oil field

    E-Print Network [OSTI]

    Venturini, Gilberto Jose

    2002-01-01T23:59:59.000Z

    Simulation studies were performed to evaluate a novel technology, steam-propane injection, for the heavy Hamaca crude oil. The oil has a gravity of 9.3?API and a viscosity of 25,000 cp at 50?C. Two types of simulation studies were performed: a...

  15. Techno-Economic Analysis of Bioconversion of Methane into Biofuel and Biochemical (Poster)

    SciTech Connect (OSTI)

    Fei, Q.; Tao, L.; Pienkos, P .T.; Guarnieri, M.; Palou-Rivera, I.

    2014-10-01T23:59:59.000Z

    In light of the relatively low price of natural gas and increasing demands of liquid transportation fuels and high-value chemicals, attention has begun to turn to novel biocatalyst for conversion of methane (CH4) into biofuels and biochemicals [1]. A techno-economic analysis (TEA) was performed for an integrated biorefinery process using biological conversion of methane, such as carbon yield, process efficiency, productivity (both lipid and acid), natural gas and other raw material prices, etc. This analysis is aimed to identify research challenges as well provide guidance for technology development.

  16. Semi-annual report for the unconventional gas recovery program, period ending September 30, 1980

    SciTech Connect (OSTI)

    Manilla, R.D. (ed.)

    1980-11-01T23:59:59.000Z

    Progress is reported in research on methane recovery from coalbeds, eastern gas shales, western gas sands, and geopressured aquifers. In the methane from coalbeds project, data on information evaluation and management, resource and site assessment and characterization, model development, instrumentation, basic research, and production technology development are reported. In the methane from eastern gas shales project, data on resource characterization and inventory, extraction technology, and technology testing and verification are presented. In the western gas sands project, data on resource assessments, field tests and demonstrations and project management are reported. In the methane from geopressured aquifers project, data on resource assessment, supporting research, field tests and demonstrations, and technology transfer are reported.

  17. METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST

    SciTech Connect (OSTI)

    Donn McGuire; Thomas Williams; Bjorn Paulsson; Alexander Goertz

    2005-02-01T23:59:59.000Z

    Natural-gas hydrates have been encountered beneath the permafrost and considered a drilling hazard by the oil and gas industry for years. Drilling engineers working in Russia, Canada and the USA have documented numerous problems, including drilling kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrates as a potential energy source agree that the resource potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained from physical samples taken from actual hydrate-bearing rocks. This gas-hydrate project is a cost-shared partnership between Maurer Technology, Anadarko Petroleum, Noble Corporation, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. The project team drilled and continuously cored the Hot Ice No. 1 well on Anadarko-leased acreage beginning in FY 2003 and completed in 2004. An on-site core analysis laboratory was built and used for determining physical characteristics of hydrates and surrounding rock. After the well was logged, a 3D vertical seismic profile (VSP) was recorded to calibrate the shallow geologic section with seismic data and to investigate techniques to better resolve lateral subsurface variations of potential hydrate-bearing strata. Paulsson Geophysical Services, Inc. deployed their 80 level 3C clamped borehole seismic receiver array in the wellbore to record samples every 25 ft. Seismic vibrators were successively positioned at 1185 different surface positions in a circular pattern around the wellbore. This technique generated a 3D image of the subsurface. Correlations were generated of these seismic data with cores, logging, and other well data. Unfortunately, the Hot Ice No. 1 well did not encounter hydrates in the reservoir sands, although brine-saturated sands containing minor amounts of methane were encountered within the hydrate stability zone (HSZ). Synthetic seismograms created from well log data were in agreement with reflectivity data measured by the 3D VSP survey. Modeled synthetic seismograms indicated a detectable seismic response would be expected in the presence of hydrate-bearing sands. Such a response was detected in the 3D VSP data at locations up-dip to the west of the Hot Ice No. 1 wellbore. Results of this project suggest that the presence of hydrate-bearing strata may not be related as simply to HSZ thickness as previously thought. Geological complications of reservoir facies distribution within fluvial-deltaic environments will require sophisticated detection technologies to assess the locations of recoverable volumes of methane contained in hydrates. High-resolution surface seismic data and more rigorous well log data analysis offer the best near-term potential. The hydrate resource potential is huge, but better tools are needed to accurately assess their location, distribution and economic recoverability.

  18. Methane Digesters and Biogas Recovery - Masking the Environmental Consequences of Industrial Concentrated Livestock Production

    E-Print Network [OSTI]

    Di Camillo, Nicole G.

    2011-01-01T23:59:59.000Z

    Methane Digesters and Biogas Recovery-Masking theII. METHANE DIGESTERS AND BIOGAs RECOVERY- IN THE2011] METHANE DIGESTERS AND BIOGAS RECOVERY methane, and 64%

  19. Methane production by attached film

    DOE Patents [OSTI]

    Jewell, William J. (202 Eastwood Ave., Ithaca, NY 14850)

    1981-01-01T23:59:59.000Z

    A method for purifying wastewater of biodegradable organics by converting the organics to methane and carbon dioxide gases is disclosed, characterized by the use of an anaerobic attached film expanded bed reactor for the reaction process. Dilute organic waste material is initially seeded with a heterogeneous anaerobic bacteria population including a methane-producing bacteria. The seeded organic waste material is introduced into the bottom of the expanded bed reactor which includes a particulate support media coated with a polysaccharide film. A low-velocity upward flow of the organic waste material is established through the bed during which the attached bacterial film reacts with the organic material to produce methane and carbon dioxide gases, purified water, and a small amount of residual effluent material. The residual effluent material is filtered by the film as it flows upwardly through the reactor bed. In a preferred embodiment, partially treated effluent material is recycled from the top of the bed to the bottom of the bed for further treatment. The methane and carbon dioxide gases are then separated from the residual effluent material and purified water.

  20. Methane generation from waste materials

    DOE Patents [OSTI]

    Samani, Zohrab A. (Las Cruces, NM); Hanson, Adrian T. (Las Cruces, NM); Macias-Corral, Maritza (Las Cruces, NM)

    2010-03-23T23:59:59.000Z

    An organic solid waste digester for producing methane from solid waste, the digester comprising a reactor vessel for holding solid waste, a sprinkler system for distributing water, bacteria, and nutrients over and through the solid waste, and a drainage system for capturing leachate that is then recirculated through the sprinkler system.

  1. Novel Pt/Mg(In)(Al)O catalysts for ethane and propane dehydrogenation

    SciTech Connect (OSTI)

    Sun, Pingping; Siddiqi, Georges; Vining, William C.; Chi, Miaofang; Bell, Alexis T. (UCB); (ORNL)

    2011-10-28T23:59:59.000Z

    Catalysts for the dehydrogenation of light alkanes were prepared by dispersing Pt on the surface of a calcined hydrotalcite-like support containing indium, Mg(In)(Al)O. Upon reduction in H{sub 2} at temperatures above 673 K, bimetallic particles of PtIn are observed by TEM, which have an average diameter of 1 nm. Analysis of Pt LIII-edge extended X-ray absorption fine structure (EXAFS) data shows that the In content of the bimetallic particles increases with increasing bulk In/Pt ratio and reduction temperature. Pt LIII-edge X-ray absorption near edge structure (XANES) indicates that an increasing donation of electronic charge from In to Pt occurs with increasing In content in the PtIn particles. The activity and selectivity of the Pt/Mg(In)(Al)O catalysts for ethane and propane dehydrogenation reactions are strongly dependent on the bulk In/Pt ratio. For both reactants, maximum activity was achieved for a bulk In/Pt ratio of 0.48, and at this In/Pt ratio, the selectivity to alkene was nearly 100%. Coke deposition was observed after catalyst use for either ethane or propane dehydrogenation, and it was observed that the alloying of Pt with In greatly reduced the amount of coke deposited. Characterization of the deposit by Raman spectroscopy indicates that the coke is present as highly disordered graphite particles <30 nm in diameter. While the amount of coke deposited during ethane and propane dehydrogenation are comparable, the effects on activity are dependent on reactant composition. Coke deposition had no effect on ethane dehydrogenation activity, but caused a loss in propane dehydrogenation activity. This difference is attributed to the greater ease with which coke produced on the surface of PtIn nanoparticles migrates to the support during ethane dehydrogenation versus propane dehydrogenation.

  2. Methane Hydrates: Major Energy Source for the Future or Wishful Thinking?

    SciTech Connect (OSTI)

    Thomas, Charles Phillip

    2001-09-01T23:59:59.000Z

    Methane hydrates are methane bearing, ice-like materials that occur in abundance in permafrost areas such as on the North Slope of Alaska and Canada and as well as in offshore continental margin environments throughout the world including the Gulf of Mexico and the East and West Coasts of the United States. Methane hydrate accumulations in the United States are currently estimated to be about 200,000 Tcf, which is enormous when compared to the conventional recoverable resource estimate of 2300 Tcf. On a worldwide basis, the estimate is 700,000 Tcf or about two times the total carbon in coal, oil and conventional gas in the world. The enormous size of this resource, if producible to any degree, has significant implications for U.S. and worldwide clean energy supplies and global environmental issues. Historically the petroleum industry's interests in methane hydrates have primarily been related to safety issues such as wellbore stability while drilling, seafloor stability, platform subsidence, and pipeline plugging. Many questions remain to be answered to determine if any of this potential energy resource is technically and economically viable to produce. Major technical hurdles include: 1) methods to find, characterize, and evaluate the resource; 2) technology to safely and economically produce natural gas from methane hydrate deposits; and 3) safety and seafloor stability issues related to drilling through gas hydrate accumulations to produce conventional oil and gas. The petroleum engineering profession currently deals with gas hydrates in drilling and production operations and will be key to solving the technical and economic problems that must be overcome for methane hydrates to be part of the future energy mix in the world.

  3. Biomimetic methane oxidation. Final report, October 1, 1989--June 1, 1995

    SciTech Connect (OSTI)

    Watkins, B.E.; Satcher, J.H. Jr.; Droege, M.W.; Taylor, R.T.

    1995-07-01T23:59:59.000Z

    Transportation fuels are a critical energy commodity and they impact nearly every sector of this country. The need for transportation fuels is projected well into the next century. Consequently, there is a strong emphasis on the economical conversion of other domestic fossil energy resources to liquid hydrocarbons that can be used as transportation fuels. Natural gas is currently a readily available resource that has a positive future outlook considering its known and anticipated reserves. There is intense government and industrial interest in developing economic technologies to convert natural gas to liquid fuels. Methane, CH{sub 4}, is the primary hydrocarbon (85-95%) in natural gas. This document covers the following: production soluable of methane monooxygenase; production of particulate methane monooxygenase; production of methane monooxygenase in continuous culture; subunit resolution for active site identification of methylosinus trichosporium OB3b soluble methane monooxygenase; the synthesis and characterization of new copper coordination complexes contairing the asymmetric coordinating chelate ligand application to enzyme active site modeling; the synthesis and characterization of new iron coordination complexes utilizing an asymmetric coordinating chelate ligand; further characterization of new bionuclear iron complexes.

  4. METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST

    SciTech Connect (OSTI)

    Richard Sigal; Kent Newsham; Thomas Williams; Barry Freifeld; Timothy Kneafsey; Carl Sondergeld; Shandra Rai; Jonathan Kwan; Stephen Kirby; Robert Kleinberg; Doug Griffin

    2005-02-01T23:59:59.000Z

    Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. The work scope drilled and cored a well The Hot Ice No. 1 on Anadarko leases beginning in FY 2003 and completed in 2004. An on-site core analysis laboratory was built and utilized for determining the physical characteristics of the hydrates and surrounding rock. The well was drilled from a new Anadarko Arctic Platform that has a minimal footprint and environmental impact. The final efforts of the project are to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists developing reservoir models. No gas hydrates were encountered in this well; however, a wealth of information was generated and is contained in this report. The Hot Ice No. 1 well was drilled from the surface to a measured depth of 2300 ft. There was almost 100% core recovery from the bottom of surface casing at 107 ft to total depth. Based on the best estimate of the bottom of the methane hydrate stability zone (which used new data obtained from Hot Ice No. 1 and new analysis of data from adjacent wells), core was recovered over its complete range. Approximately 580 ft of porous, mostly frozen, sandstone and 155 of conglomerate were recovered in the Ugnu Formation and approximately 215 ft of porous sandstone were recovered in the West Sak Formation. There were gas shows in the bottom part of the Ugnu and throughout the West Sak. No hydrate-bearing zones were identified either in recovered core or on well logs. The base of the permafrost was found at about 1260 ft. With the exception of the deepest sands in the West Sak and some anomalous thin, tight zones, all sands recovered (after thawing) are unconsolidated with high porosity and high permeability. At 800 psi, Ugnu sands have an average porosity of 39.3% and geometrical mean permeability of 3.7 Darcys. Average grain density is 2.64 g/cc. West Sak sands have an average porosity of 35.5%, geometrical mean permeability of 0.3 Darcys, and average grain density of 2.70 g/cc. There were several 1-2 ft intervals of carbonate-cemented sandstone recovered from the West Sak. These intervals have porosities of only a few percent and very low permeability. On a well log they appear as resistive with a high sonic velocity. In shallow sections of other wells these usually are the only logs available. Given the presence of gas in Hot Ice No. 1, if only resistivity and sonic logs and a mud log had been available, tight sand zones may have been interpreted as containing hydrates. Although this finding does not imply that all previously mapped hydrate zones are merely tight sands, it does add a note of caution to the practice of interpreting the presence of hydrates from old well information. The methane hydrate stability zone below the Hot Ice No. 1 location includes thick sections of sandstone and conglomerate which would make excellent reservoir rocks for hydrates and below the permafrost zone shallow gas. The Ugnu formation comprises a more sand-rich section than does the West Sak formation, and the Ugnu sands when cleaned and dried are slightly more porous and significantly more permeable than the West Sak.

  5. Atmospheric methane flux from coals - preliminary investigation of coal mines and geologic structures in the Black Warrior Basin, Alabama

    SciTech Connect (OSTI)

    Clayton, J.L.; Leventhal, J.S.; Rice, D.D. (Geological Survey, Denver, CO (United States)); Pashin, J.C. (Geological Survey of Alabama, Tuscaloosa, AL (United States)); Mosher, B.; Czepiel, P. (Univ. of New Hampshire, Durham, NH (United States))

    1993-01-01T23:59:59.000Z

    Methane is an important greenhouse gas whose concentration in the atmosphere is increasing. Although this increase in atmospheric methane is correlative with growth in human population and activities, the exact causes for the increase are not fully understood. Because of increasing energy demand, particularly in developing countries where population is increasing, coal production is likely to increase over the next few decades and this could further increase the flux of atmospheric methane. In addition, no data are currently available on methane flux from coalbeds as a result of natural processes such as leakage at outcrops, or along faults and fractures that could provide avenues for methane migration upward from coal at depth. To better understand the global methane cycle and the role of fossil fuels in methane emissions, field measurements of methane emissions are needed from coalbeds, from areas of active mining, from coalbed gas production, and from undisturbed coals. In this paper, we report results of field measurements of CH[sub 4] emissions from surface and underground mines, fault zones, and coreholes in the Black Warrior Basin, Alabama. Ventilation of underground mines in Mary Lee group coals (of economic usage) gave the highest methane emissions rates - about 71,480,000 m[sup 3]/yr (2.5 Bcf or billion cubic feet) from one ventilation shaft. In contrast, very low emissions occurred from active or abandoned coreholes and from Brookwood group coals (of economic usage) exposed by surface mining (about 81 m[sup 3]/yr (2.9 Mcf or thousand cubic feet)). Methane flux of as much as about 500 m[sup 3]/yr occurs from a small section of a normal fault and associated joints exposed at Bankhead Lock and Dam. The carbon isotopic composition of CH[sub 4] collected at the Bankhead Fault ([delta][sup 13]C -49.3 permil) indicates a coalbed origin. 50 refs., 15 figs., 4 tabs.

  6. Gas-Phase Reactions of Doubly Charged Lanthanide Cations with Alkanes and Alkenes. Trends in Metal(2+) Reactivity

    SciTech Connect (OSTI)

    Gibson, John K.; Marcalo, Joaquim; Santos, Marta; Pires de Matos, Antonio; Haire, Richard G.

    2008-12-08T23:59:59.000Z

    The gas-phase reactivity of doubly-charged lanthanide cations, Ln2+ (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu), with alkanes (methane, ethane, propane, n-butane) and alkenes (ethene, propene, 1-butene) was studied by Fourier transform ion cyclotron resonance mass spectrometry. The reaction products consisted of different combinations of doubly-charged organometallic ions?adducts or species formed via metal-ion-induced hydrogen, dihydrogen, alkyl, or alkane eliminations from the hydrocarbons?and singly-charged ions that resulted from electron, hydride, or methide transfers from the hydrocarbons to the metal ions. The only lanthanide cations capable of activating the hydrocarbons to form doubly-charged organometallic ions were La2+, Ce2+, Gd2+, and Tb2+, which have ground-state or low-lying d1 electronic configurations. Lu2+, with an accessible d1 electronic configuration but a rather high electron affinity, reacted only through transfer channels. The remaining Ln2+ reacted via transfer channels or adduct formation. The different accessibilities of d1 electronic configurations and the range of electron affinities of the Ln2+ cations allowed for a detailed analysis of the trends for metal(2+) reactivity and the conditions for occurrence of bond activation, adduct formation, and electron, hydride, and methide transfers.

  7. UTILITIES PROBLEMS AND FAILURES Electrical or plumbing failure/Flooding/Water leak/Natural gas

    E-Print Network [OSTI]

    Fernandez, Eduardo

    UTILITIES PROBLEMS AND FAILURES Electrical or plumbing failure/Flooding/Water leak/Natural gas for electrical shock. NOTIFY University Police. What should I do if I smell natural or propane gas? LEAVE/Repair line, 7-6333, or CALL the Campus University Police or Security at (561) 297-3500 or 911

  8. INTEGRATED POWER GENERATION SYSTEMS FOR COAL MINE WASTE METHANE UTILIZATION

    SciTech Connect (OSTI)

    Peet M. Soot; Dale R. Jesse; Michael E. Smith

    2005-08-01T23:59:59.000Z

    An integrated system to utilize the waste coal mine methane (CMM) at the Federal No. 2 Coal Mine in West Virginia was designed and built. The system includes power generation, using internal combustion engines, along with gas processing equipment to upgrade sub-quality waste methane to pipeline quality standards. The power generation has a nominal capacity of 1,200 kw and the gas processing system can treat about 1 million cubic feet per day (1 MMCFD) of gas. The gas processing is based on the Northwest Fuel Development, Inc. (NW Fuel) proprietary continuous pressure swing adsorption (CPSA) process that can remove nitrogen from CMM streams. The two major components of the integrated system are synergistic. The byproduct gas stream from the gas processing equipment can be used as fuel for the power generating equipment. In return, the power generating equipment provides the nominal power requirements of the gas processing equipment. This Phase III effort followed Phase I, which was comprised of a feasibility study for the project, and Phase II, where the final design for the commercial-scale demonstration was completed. The fact that NW Fuel is desirous of continuing to operate the equipment on a commercial basis provides the validation for having advanced the project through all of these phases. The limitation experienced by the project during Phase III was that the CMM available to operate the CPSA system on a commercial basis was not of sufficiently high quality. NW Fuel's CPSA process is limited in its applicability, requiring a relatively high quality of gas as the feed to the process. The CPSA process was demonstrated during Phase III for a limited time, during which the processing capabilities met the expected results, but the process was never capable of providing pipeline quality gas from the available low quality CMM. The NW Fuel CPSA process is a low-cost ''polishing unit'' capable of removing a few percent nitrogen. It was never intended to process CMM streams containing high levels of nitrogen, as is now the case at the Federal No.2 Mine. Even lacking the CPSA pipeline delivery demonstration, the project was successful in laying the groundwork for future commercial applications of the integrated system. This operation can still provide a guide for other coal mines which need options for utilization of their methane resources. The designed system can be used as a complete template, or individual components of the system can be segregated and utilized separately at other mines. The use of the CMM not only provides an energy fuel from an otherwise wasted resource, but it also yields an environmental benefit by reducing greenhouse gas emissions. The methane has twenty times the greenhouse effect as compared to carbon dioxide, which the combustion of the methane generates. The net greenhouse gas emission mitigation is substantial.

  9. METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST

    SciTech Connect (OSTI)

    Ali Kadaster; Bill Liddell; Tommy Thompson; Thomas Williams; Michael Niedermayr

    2005-02-01T23:59:59.000Z

    Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project was a cost-shared partnership between Maurer Technology, Noble Corporation, Anadarko Petroleum, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. The work scope included drilling and coring a well (Hot Ice No. 1) on Anadarko leases beginning in FY 2003 and completed in 2004. During the first drilling season, operations were conducted at the site between January 28, 2003 to April 30, 2003. The well was spudded and drilled to a depth of 1403 ft. Due to the onset of warmer weather, work was then suspended for the season. Operations at the site were continued after the tundra was re-opened the following season. Between January 12, 2004 and March 19, 2004, the well was drilled and cored to a final depth of 2300 ft. An on-site core analysis laboratory was built and implemented for determining physical characteristics of the hydrates and surrounding rock. The well was drilled from a new Anadarko Arctic Platform that has a minimal footprint and environmental impact. Final efforts of the project are to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists developing reservoir models and to research teams for developing future gas-hydrate projects. No gas hydrates were encountered in this well; however, a wealth of information was generated and has been documented by the project team. This Topical Report documents drilling and coring operations and other daily activities.

  10. Appalachian basin coal-bed methane: Elephant or flea

    SciTech Connect (OSTI)

    Hunt, A.M. (Dames and Moore, Cincinnati, OH (United States))

    1991-08-01T23:59:59.000Z

    Historically, interest in the Appalachian basin coal-bed methane resource extends at least over the last 50 years. The Northern and Central Appalachian basins are estimated to contain 61 tcf and 5 tcf of coal-bed methane gas, respectively. Development of this resource has not kept pace with that of other basins, such as the Black Warrior basin of Alabama of the San Juan basin of northern New Mexico and Colorado. Without the benefit of modern completion, stimulation, and production technology, some older Appalachian basin coal-bed methane wells were reported to have produced in excess of 150 used here to characterize some past projects and their results. This work is not intended to comprise a comprehensive survey of all Appalachian basin projects, but rather to provide background information from which to proceed for those who may be interested in doing so. Several constraints to the development of this resource have been identified, including conflicting legal rights of ownership of the gas produced from the coal seams when coal and conventional oil and gas rights are controlled by separate parties. In addition, large leaseholds have been difficult to acquire and finding costs have been high. However, the threshold of minimum economic production may be relatively low when compared with other areas, because low-pressures pipelines are available and gas prices are among the highest in the nation. Interest in the commercial development of the resource seems to be on the increase with several projects currently active and more reported to be planned for the near future.

  11. The Methane to Markets Coal Mine Methane Subcommittee meeting

    SciTech Connect (OSTI)

    NONE

    2008-07-01T23:59:59.000Z

    The presentations (overheads/viewgraphs) include: a report from the Administrative Support Group; strategy updates from Australia, India, Italy, Mexico, Nigeria, Poland and the USA; coal mine methane update and IEA's strategy and activities; the power of VAM - technology application update; the emissions trading market; the voluntary emissions reduction market - creating profitable CMM projects in the USA; an Italian perspective towards a zero emission strategies; and the wrap-up and summary.

  12. Design and Operation of the Synthesis Gas Generator System for Reformed Propane and Glycerin Combustion

    E-Print Network [OSTI]

    Pickett, Derek

    2013-12-31T23:59:59.000Z

    110.6 million barrels per day by 2030 [1]. One possible source of alternative fuel, biodiesel, can be derived from biomass feedstocks (e.g., soybean). This bio-based diesel can augment or replace petroleum based diesel with little to no modifications...

  13. Impact of different plants on the gas profile of a landfill cover

    SciTech Connect (OSTI)

    Reichenauer, Thomas G., E-mail: thomas.reichenauer@ait.ac.at [Health and Environment Department, Environmental Resources and Technologies, AIT - Austrian Institute of Technology GmbH, 2444 Seibersdorf (Austria); Watzinger, Andrea; Riesing, Johann [Health and Environment Department, Environmental Resources and Technologies, AIT - Austrian Institute of Technology GmbH, 2444 Seibersdorf (Austria); Gerzabek, Martin H. [Institute of Soil Research, Department of Forest and Soil Sciences, University of Natural Resources and Applied Life Sciences, Peter Jordan-Strasse 82, 1190 Vienna (Austria)

    2011-05-15T23:59:59.000Z

    Research highlights: > Plants influence gas profile and methane oxidation in landfill covers. > Plants regulate water content and increase the availability of oxygen for methane oxidation. > Plant species with deep roots like alfalfa showed more stimulation of methane oxidation than plants with shallow root systems like grasses. - Abstract: Methane is an important greenhouse gas emitted from landfill sites and old waste dumps. Biological methane oxidation in landfill covers can help to reduce methane emissions. To determine the influence of different plant covers on this oxidation in a compost layer, we conducted a lysimeter study. We compared the effect of four different plant covers (grass, alfalfa + grass, miscanthus and black poplar) and of bare soil on the concentration of methane, carbon dioxide and oxygen in lysimeters filled with compost. Plants were essential for a sustainable reduction in methane concentrations, whereas in bare soil, methane oxidation declined already after 6 weeks. Enhanced microbial activity - expected in lysimeters with plants that were exposed to landfill gas - was supported by the increased temperature of the gas in the substrate and the higher methane oxidation potential. At the end of the first experimental year and from mid-April of the second experimental year, the methane concentration was most strongly reduced in the lysimeters containing alfalfa + grass, followed by poplar, miscanthus and grass. The observed differences probably reflect the different root morphology of the investigated plants, which influences oxygen transport to deeper compost layers and regulates the water content.

  14. Simulation study of the effect of well spacing, effect of permeability anisotropy, and effect of Palmer and Mansoori model on coalbed methane production 

    E-Print Network [OSTI]

    Zulkarnain, Ismail

    2006-04-12T23:59:59.000Z

    Interference for adjacent wells may be beneficial to Coalbed-Methane production. The effect is the acceleration of de-watering which should lead to earlier and higher gas rate peaks. It is inherent that permeability ...

  15. Geochemical assessment of gaseous hydrocarbons: mixing of bacterial and thermogenic methane in the deep subsurface petroleum system, Gulf of Mexico continental slope 

    E-Print Network [OSTI]

    Ozgul, Ercin

    2004-09-30T23:59:59.000Z

    Mixtures of bacterial and thermogenic methane are found both at vents at the seafloor and in reservoirs in the deep subsurface of the Gulf of Mexico continental slope. The C1-C5 gas that most recently charged reservoirs ...

  16. Treatment of gas from an in situ conversion process

    DOE Patents [OSTI]

    Diaz, Zaida (Katy, TX); Del Paggio, Alan Anthony (Spring, TX); Nair, Vijay (Katy, TX); Roes, Augustinus Wilhelmus Maria (Houston, TX)

    2011-12-06T23:59:59.000Z

    A method of producing methane is described. The method includes providing formation fluid from a subsurface in situ conversion process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes olefins. At least the olefins in the first gas stream are contacted with a hydrogen source in the presence of one or more catalysts and steam to produce a second gas stream. The second gas stream is contacted with a hydrogen source in the presence of one or more additional catalysts to produce a third gas stream. The third gas stream includes methane.

  17. Alternative Fuels Data Center: Airport Shuttles Run on Propane

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProducts (VAP)MassachusettsExperimental VehicleNatural GasVehicleTexasAirport

  18. Detection and Production of Methane Hydrate

    SciTech Connect (OSTI)

    George Hirasaki; Walter Chapman; Gerald Dickens; Colin Zelt; Brandon Dugan; Kishore Mohanty; Priyank Jaiswal

    2011-12-31T23:59:59.000Z

    This project seeks to understand regional differences in gas hydrate systems from the perspective of as an energy resource, geohazard, and long-term climate influence. Specifically, the effort will: (1) collect data and conceptual models that targets causes of gas hydrate variance, (2) construct numerical models that explain and predict regional-scale gas hydrate differences in 2-dimensions with minimal 'free parameters', (3) simulate hydrocarbon production from various gas hydrate systems to establish promising resource characteristics, (4) perturb different gas hydrate systems to assess potential impacts of hot fluids on seafloor stability and well stability, and (5) develop geophysical approaches that enable remote quantification of gas hydrate heterogeneities so that they can be characterized with minimal costly drilling. Our integrated program takes advantage of the fact that we have a close working team comprised of experts in distinct disciplines. The expected outcomes of this project are improved exploration and production technology for production of natural gas from methane hydrates and improved safety through understanding of seafloor and well bore stability in the presence of hydrates. The scope of this project was to more fully characterize, understand, and appreciate fundamental differences in the amount and distribution of gas hydrate and how this would affect the production potential of a hydrate accumulation in the marine environment. The effort combines existing information from locations in the ocean that are dominated by low permeability sediments with small amounts of high permeability sediments, one permafrost location where extensive hydrates exist in reservoir quality rocks and other locations deemed by mutual agreement of DOE and Rice to be appropriate. The initial ocean locations were Blake Ridge, Hydrate Ridge, Peru Margin and GOM. The permafrost location was Mallik. Although the ultimate goal of the project was to understand processes that control production potential of hydrates in marine settings, Mallik was included because of the extensive data collected in a producible hydrate accumulation. To date, such a location had not been studied in the oceanic environment. The project worked closely with ongoing projects (e.g. GOM JIP and offshore India) that are actively investigating potentially economic hydrate accumulations in marine settings. The overall approach was fivefold: (1) collect key data concerning hydrocarbon fluxes which is currently missing at all locations to be included in the study, (2) use this and existing data to build numerical models that can explain gas hydrate variance at all four locations, (3) simulate how natural gas could be produced from each location with different production strategies, (4) collect new sediment property data at these locations that are required for constraining fluxes, production simulations and assessing sediment stability, and (5) develop a method for remotely quantifying heterogeneities in gas hydrate and free gas distributions. While we generally restricted our efforts to the locations where key parameters can be measured or constrained, our ultimate aim was to make our efforts universally applicable to any hydrate accumulation.

  19. Modelling of stable isotope fractionation by methane oxidation and diffusion in landfill cover soils

    SciTech Connect (OSTI)

    Mahieu, Koenraad [Laboratory of Applied Physical Chemistry (ISOFYS), Ghent University, Coupure links 653, B-9000 Ghent (Belgium); Department of Applied Mathematics, Biometrics and Process Control (BIOMATH), Ghent University, Coupure links 653, B-9000 Ghent (Belgium)], E-mail: Koenraad.mahieu@lid.kviv.be; De Visscher, Alex [Department of Chemical and Petroleum Engineering, Schulich School of Engineering, University of Calgary, 2500 University Drive N.W., Calgary, Alberta, T2N 1N4 (Canada); Vanrolleghem, Peter A. [Department of Applied Mathematics, Biometrics and Process Control (BIOMATH), Ghent University, Coupure links 653, B-9000 Ghent (Belgium); Department of Civil Engineering (modelEAU), Universite Laval, Pavillon Pouliot, Quebec, G1K 7P4 (Canada); Van Cleemput, Oswald [Laboratory of Applied Physical Chemistry (ISOFYS), Ghent University, Coupure links 653, B-9000 Ghent (Belgium)

    2008-07-01T23:59:59.000Z

    A technique to measure biological methane oxidation in landfill cover soils that is gaining increased interest is the measurement of stable isotope fractionation in the methane. Usually to quantify methane oxidation, only fractionation by oxidation is taken into account. Recently it was shown that neglecting the isotope fractionation by diffusion results in underestimation of the methane oxidation. In this study a simulation model was developed that describes gas transport and methane oxidation in landfill cover soils. The model distinguishes between {sup 12}CH{sub 4}, {sup 13}CH{sub 4}, and {sup 12}CH{sub 3}D explicitly, and includes isotope fractionation by diffusion and oxidation. To evaluate the model, the simulations were compared with column experiments from previous studies. The predicted concentration profiles and isotopic profiles match the measured ones very well, with a root mean square deviation (RMSD) of 1.7 vol% in the concentration and a RMSD of 0.8 per mille in the {delta}{sup 13}C value, with {delta}{sup 13}C the relative {sup 13}C abundance as compared to an international standard. Overall, the comparison shows that a model-based isotope approach for the determination of methane oxidation efficiencies is feasible and superior to existing isotope methods.

  20. METHANE HYDRATE STUDIES: DELINEATING PROPERTIES OF HOST SEDIMENTS TO ESTABLISH REPRODUCIBLE DECOMPOSITION KINETICS.

    SciTech Connect (OSTI)

    Mahajan, Devinder; Jones, Keith W.; Feng, Huan; Winters, William J.

    2004-12-01T23:59:59.000Z

    The use of methane hydrate as an energy source requires development of a reliable method for its extraction from its highly dispersed locations in oceanic margin sediments and permafrost. The high pressure (up to 70 MPa) and low temperature (272 K to 278 K) conditions under which hydrates are stable in the marine environment can be mimicked in a laboratory setting and several kinetic studies of pure methane hydrate decomposition have been reported. However, the effect of host sediments on methane hydrate occurrence and decomposition are required to develop reliable hydrate models. In this paper, we describe methods to measure sediment properties as they relate to pore-space methane gas hydrate. Traditional geotechnical techniques are compared to the micrometer level by use of the synchrotron Computed Microtomography (CMT) technique. CMT was used to measure the porosity at the micrometer level and to show pore-space pathways through field samples. Porosities for three sediment samples: one from a site on Georges Bank and two from the known Blake Ridge methane hydrate site, from different depths below the mud line were measured by traditional drying and by the new CMT techniques and found to be in good agreement. The integration of the two analytical approaches is necessary to enable better understanding of methane hydrate interactions with the surrounding sediment particles.

  1. Design of New Materials for Methane Storage Tina Duren, Lev Sarkisov, Omar M. Yaghi, and Randall Q. Snurr*,

    E-Print Network [OSTI]

    Yaghi, Omar M.

    Design of New Materials for Methane Storage Tina Du¨ren, Lev Sarkisov, Omar M. Yaghi, and Randall Q is to replace gasoline and diesel with alternative fuels such as natural gas. In this report, we elucidate the desired characteristics of an optimal adsorbent for gas storage. The U.S. Department of Energy has

  2. Coal-bed methane - New energy for today and the future

    SciTech Connect (OSTI)

    Murray, D.K. (Keith Murray and Associates, Inc., Golden, CO (USA)); Schwochow, S.D. (Colorado School of Mines, Golden (USA))

    1990-05-01T23:59:59.000Z

    Coal is one of the richest known sources of hydrocarbons. This heterogeneous material has the unique characteristic of being both a source and a reservoir of natural gas. By virtue of their maturation to high rank some coals have the capacity to generate more than 8,000 ft{sup 3} of methane per ton of coal. Although most of this gas eventually has been lost over 400 trillion ft{sup 3} remains in place in US coal basins. The Potential Gas Committee has estimated that at least 90 trillion ft{sup 3} likely are recoverable. Coal-bed methane exploration requires application of both coal geology and petroleum geology as well as nonconventional approaches to reservoir engineering. With advanced technologies developed largely through cooperative efforts of the Gas Research Institute and industry, researchers and explorationists are better understanding the geological and engineering peculiarities of coal reservoirs. Commercial coal-bed methane development occurs basically in two diverse geologic settings: (1) thin, shallow coals of Pennsylvanian age in the Black Warrior and Appalachian basins and (2) thicker, deeper coals of Cretaceous age in the Rocky Mountains, principally the San Juan, Piceance, Raton, and Green River basins. Recent exploration has targeted shallow, anomalously thick but lower-rank, low-gas-content Tertiary coals in Wyoming. Coal basins in Washington, British Columbia, and Alberta also show potential. Methane in coal beds is an immense, virtually untapped source of environmentally acceptable, pipeline-quality energy. In light of increasing demand for natural gas, coal-bed methane is becoming an economically viable, low-risk exploratory and development objective.

  3. METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST

    SciTech Connect (OSTI)

    Steve Runyon; Mike Globe; Kent Newsham; Robert Kleinberg; Doug Griffin

    2005-02-01T23:59:59.000Z

    Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project was a cost-shared partnership between Maurer Technology, Noble Corporation, Anadarko Petroleum, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. The work scope included drilling and coring a well (Hot Ice No. 1) on Anadarko leases beginning in FY 2003 and completed in 2004. During the first drilling season, operations were conducted at the site between January 28, 2003 to April 30, 2003. The well was spudded and drilled to a depth of 1403 ft. Due to the onset of warmer weather, work was then suspended for the season. Operations at the site were continued after the tundra was re-opened the following season. Between January 12, 2004 and March 19, 2004, the well was drilled and cored to a final depth of 2300 ft. An on-site core analysis laboratory was built and utilized for determining the physical characteristics of the hydrates and surrounding rock. The well was drilled from a new Anadarko Arctic Platform that has a minimal footprint and environmental impact. The final efforts of the project are to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists planning hydrate exploration and development projects. No gas hydrates were encountered in this well; however, a wealth of information was generated and is contained in this and other project reports. This Topical Report contains details describing logging operations.

  4. METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST

    SciTech Connect (OSTI)

    Thomas E. Williams; Keith Millheim; Bill Liddell

    2005-02-01T23:59:59.000Z

    Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project is a cost-shared partnership between Maurer Technology, Anadarko Petroleum, Noble Corporation, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to help identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. As part of the project work scope, team members drilled and cored a well (the Hot Ice No. 1) on Anadarko leases beginning in January 2003 and completed in March 2004. Due to scheduling constraints imposed by the Arctic drilling season, operations at the site were suspended between April 21, 2003 and January 30, 2004. An on-site core analysis laboratory was constructed and used for determining physical characteristics of frozen core immediately after it was retrieved from the well. The well was drilled from a new and innovative Anadarko Arctic Platform that has a greatly reduced footprint and environmental impact. Final efforts of the project were to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists for future hydrate operations. No gas hydrates were encountered in this well; however, a wealth of information was generated and is contained in the project reports. Documenting the results of this effort are key to extracting lessons learned and maximizing the industry's benefits for future hydrate exploitation.

  5. Thermophysical property predictions of propane, propylene and their mixtures by Benedict-Webb-Rubin type equations of state 

    E-Print Network [OSTI]

    Bengani, Pramod Kumar

    1990-01-01T23:59:59.000Z

    THERMOPHYSICAL PROPERTY PREDICTIONS OF PROPANE, PROPYLENE AND THEIR MIXTURES BY BENEDICT-WEBB-RUBIN TYPE EQUATIONS OF STATE A Thesis by PRAMOD KUMAR BENGANI Submitted to the Office of Graduate Studies of Texas A & M University in partial... fulfillment of the requirements for the degree of MASTER OF SCIENCE December 1990 Major Subject: Chemical Engineering THERMOPHYSICAL PROPERTY PREDICTIONS OF PROPANE, PROPYLENE AND THEIR MIXTURES BY BENEDICT-WEBB-RUBIN TYPE EQUATIONS OF STATE A Thesis...

  6. EFFECT OF H2 PRODUCED THROUGH STEAM-METHANE REFORMING ON CHP PLANT EFFICIENCY

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 EFFECT OF H2 PRODUCED THROUGH STEAM-METHANE REFORMING ON CHP PLANT EFFICIENCY O. Le Corre1 , C for a CHP plant based on spark ignition engine running under lean conditions. An overall auto-fire or knock occurred. Keywords: Hydrogen, CHP, natural gas, power, efficiency, environmental impact. 1

  7. Clay enhancement of methane, low molecular weight hydrocarbon and halocarbon conversion by methanotrophic bacteria

    DOE Patents [OSTI]

    Apel, William A.; Dugan, Patrick R.

    1995-04-04T23:59:59.000Z

    An apparatus and method for increasing the rate of oxidation of toxic vapors by methanotrophic bacteria. The toxic vapors of interest are methane and trichloroethylene. The apparatus includes a gas phase bioreactor within a closed loop pumping system or a single pass system. The methanotrophic bacteria include Methylomonas methanica, Methylosinus trichosporium, and uncharacterized environmental enrichments.

  8. Clay enhancement of methane, low molecular weight hydrocarbon and halocarbon conversion by methanotrophic bacteria

    DOE Patents [OSTI]

    Apel, William A. (Idaho Falls, ID); Dugan, Patrick R. (Idaho Falls, ID)

    1995-01-01T23:59:59.000Z

    An apparatus and method for increasing the rate of oxidation of toxic vapors by methanotrophic bacteria. The toxic vapors of interest are methane and trichloroethylene. The apparatus includes a gas phase bioreactor within a closed loop pumping system or a single pass system. The methanotrophic bacteria include Methylomonas methanica, Methylosinus trichosporium, and uncharacterized environmental enrichments.

  9. Effect of Hydrogen Addition on the Flammability Limit of Stretched Methane/Air Premixed Flames

    E-Print Network [OSTI]

    Im, Hong G.

    ], thereby enabling stable combustion at lean mixture conditions. In the case of natural gas engines, enriching the fuel with hydrogen has the proven benefits of improving the combustion stability and reducingEffect of Hydrogen Addition on the Flammability Limit of Stretched Methane/Air Premixed Flames

  10. SUPPORTING INFORMATION Comparison of non-precious metal cathode materials for methane

    E-Print Network [OSTI]

    S1 SUPPORTING INFORMATION Comparison of non-precious metal cathode materials for methane production H2SO4, and again in de-ionized water. Butyl rubber stoppers were used to prevent loss of gas from thick and 43 mm diameter) were cut from large butyl rubber sheets (McMaster-Carr, Cleveland, OH, USA

  11. Effects of carbon dioxide injection on the displacement of methane and carbonate dissolution in sandstone cores

    E-Print Network [OSTI]

    Maduakor, Ekene Obioma

    2006-10-30T23:59:59.000Z

    psig and temperature of 60oC using a 1 foot long and 1 inch diameter Berea sandstone core. Pure CO2 and treated flue gas (99.433 % mole CO2) were injected into the Berea sandstone core initially saturated with methane at a pressure of 1500 psig and 800...

  12. The Role of the Ocean in the Atmospheric Budgets of Methyl Bromide, Methyl Chloride and Methane

    E-Print Network [OSTI]

    Hu, Lei

    2012-10-19T23:59:59.000Z

    , which was 700 (490 to 920) Gg yr^-1 and -370 (-440 to -280) Gg yr^-1, respectively. The ocean accounts for 10 - 19 % in the global CH3Cl emission and 6 - 9 % in its global sinks. Methane (CH4) is a potent greenhouse gas, which has a warming potential...

  13. Nitrogen removal from natural gas using two types of membranes

    DOE Patents [OSTI]

    Baker, Richard W.; Lokhandwala, Kaaeid A.; Wijmans, Johannes G.; Da Costa, Andre R.

    2003-10-07T23:59:59.000Z

    A process for treating natural gas or other methane-rich gas to remove excess nitrogen. The invention relies on two-stage membrane separation, using methane-selective membranes for the first stage and nitrogen-selective membranes for the second stage. The process enables the nitrogen content of the gas to be substantially reduced, without requiring the membranes to be operated at very low temperatures.

  14. Scaling methane oxidation: From laboratory incubation experiments to landfill cover field conditions

    SciTech Connect (OSTI)

    Abichou, Tarek, E-mail: abichou@eng.fsu.edu [Florida State University, Tallahassee, FL 32311 (United States); Mahieu, Koenraad; Chanton, Jeff [Florida State University, Tallahassee, FL 32311 (United States); Romdhane, Mehrez; Mansouri, Imane [Unite de Recherche M.A.C.S., Ecole Nationale d'Ingenieurs de Gabes, Route de Medenine, 6029 Gabes (Tunisia)

    2011-05-15T23:59:59.000Z

    Evaluating field-scale methane oxidation in landfill cover soils using numerical models is gaining interest in the solid waste industry as research has made it clear that methane oxidation in the field is a complex function of climatic conditions, soil type, cover design, and incoming flux of landfill gas from the waste mass. Numerical models can account for these parameters as they change with time and space under field conditions. In this study, we developed temperature, and water content correction factors for methane oxidation parameters. We also introduced a possible correction to account for the different soil structure under field conditions. These parameters were defined in laboratory incubation experiments performed on homogenized soil specimens and were used to predict the actual methane oxidation rates to be expected under field conditions. Water content and temperature corrections factors were obtained for the methane oxidation rate parameter to be used when modeling methane oxidation in the field. To predict in situ measured rates of methane with the model it was necessary to set the half saturation constant of methane and oxygen, K{sub m}, to 5%, approximately five times larger than laboratory measured values. We hypothesize that this discrepancy reflects differences in soil structure between homogenized soil conditions in the lab and actual aggregated soil structure in the field. When all of these correction factors were re-introduced into the oxidation module of our model, it was able to reproduce surface emissions (as measured by static flux chambers) and percent oxidation (as measured by stable isotope techniques) within the range measured in the field.

  15. Experimental and analytical studies of hydrocarbon yields under dry-, steam-, and steam with propane-distillation

    E-Print Network [OSTI]

    Ramirez Garnica, Marco Antonio

    2004-09-30T23:59:59.000Z

    from Instituto Mexicano del Petróleo (IMP), Dr. Fernando Rodriguez de la Garza, and Dr. Jose Luis Sanchez Bujanos from Petróleos Mexicanos (PEMEX), and Lawyer Rolando Rueda de Leon from Diario de Mexico, for their help and valuable advice. I would...-, and Steam with Propane-Distillation. (May 2004) Marco Antonio Ramírez-Garnica, B.S., Instituto Politécnico Nacional; M.S., Instituto Politécnico Nacional, México Chair of Advisory Committee: Dr. Daulat D. Mamora Recent experimental and simulation...

  16. Anaerobic Methane Oxidation in a Landfill-Leachate Plume

    E-Print Network [OSTI]

    Grossman, E. L.; Cifuentes, L. A.; Cozzarelli, I. M.

    2002-01-01T23:59:59.000Z

    , and (2) negligible oxygen, nitrate, and sulfate concentrations. Methane concentrations and stable carbon isotope (?13C) values suggest anaerobic methane oxidation was occurring within the plume and at its margins. Methane ?13C values increased from about...

  17. Thermoelectrics: The New Green Automotive Technology

    Broader source: Energy.gov (indexed) [DOE]

    C 18 H 30 Methanol CH 3 OH Ethanol C 2 H 5 OH Natural Gas (Primarily Methane, CH 4 ) Propane C 3 H 8 Combustion of Hydrocarbon Fuels Releases Carbon 9 | Vehicle Technologies...

  18. Extension - Upgrading Methane Using Ultra-Fast Thermal Swing Adsorption

    SciTech Connect (OSTI)

    Anna Lee Tonkovich

    2008-08-11T23:59:59.000Z

    The need for cost effective technologies for upgrading coal mine methane to pipeline quality natural gas is becoming ever greater. The current work presents and investigates a new approach to reduce the impact of the most costly step in the conventional technology, nitrogen rejection. The proposed approach is based on the Velocys microchannel platform, which is being developed to commercialize compact and cost efficient chemical processing technology. For this separation, ultra fast thermal swing sorption is enabled by the very high rates of heat and mass transfer inherent in microchannel processing. In a first phase of the project solid adsorbents were explored. Feasibility of ultrafast thermal swing was demonstrated but the available adsorbents had insufficient differential methane capacity to achieve the required commercial economics. In a second phase, ionic liquids were adopted as absorbents of choice, and experimental work and economic analyses, performed to gauge their potential, showed promise for this novel alternative. Final conclusions suggest that a combination of a required cost target for ionic liquids or a methane capacity increase or a combination of both is required for commercialization.

  19. An ab Initio Study on the Oxidative Coupling of Methane over a Lithium-Doped MgO Catalyst: Surface Defects and Mechanism

    E-Print Network [OSTI]

    Truong, Thanh N.

    utilization of methane, the primary component of natural gas, is becoming an immediate goal as we face issues of diminishing natural resources. Unfortunately, the remote locations of most natural gas reserves make transportation of this fuel economically unreasonable.1 One means to exploit the remote gas sources is to first

  20. California Food Processing Industry Wastewater Demonstration Project: Phase I Final Report

    E-Print Network [OSTI]

    Lewis, Glen

    2010-01-01T23:59:59.000Z

    report electricity, natural gas and propane usage and directetc. ), facility natural gas and propane usage. Integrate

  1. Scientists detect methane levels three times larger than expected...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    methane that actually preceded recent concerns about potential emissions from fracking," Dubey said. Scientists detect methane levels three times larger than expected over...

  2. Direct Observation of the Active Center for Methane Dehydroaromatizati...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Methane Dehydroaromatization Using an Ultrahigh Field 95Mo NMR Spectroscopy. Abstract: Direct conversion of methane to value-added chemicals remains a challenge from both...

  3. Completion methods in thick, multilayered tight gas sands

    E-Print Network [OSTI]

    Ogueri, Obinna Stavely

    2009-05-15T23:59:59.000Z

    Tight gas sands, coal-bed methane, and gas shales are commonly called unconventional reservoirs. Tight gas sands (TGS) are often described as formations with an expected average permeability of 0.1mD or less. Gas production rates from TGS reservoirs...

  4. Completion methods in thick, multilayered tight gas sands

    E-Print Network [OSTI]

    Ogueri, Obinna Stavely

    2008-10-10T23:59:59.000Z

    Tight gas sands, coal-bed methane, and gas shales are commonly called unconventional reservoirs. Tight gas sands (TGS) are often described as formations with an expected average permeability of 0.1mD or less. Gas production rates from TGS reservoirs...

  5. Analysis of coal and coal bed methane resources of Warrior basin, Alabama

    SciTech Connect (OSTI)

    Wicks, D.E.; McFall, K.S.; Malone, P.

    1987-09-01T23:59:59.000Z

    The Warrior basin in Alabama is the most active area in the US producing natural gas from coal beds. As of 1986, 300 coal-bed methane wells were producing from eight degasification fields, mainly from the Pennsylvanian coal seams along the eastern margin of the basin. Despite difficult market conditions, drilling and expansion are continuing. A detailed geologic analysis of Warrior basin coal-bed methane targets the areas of the basin that show the most promise for future gas production. The geologic analysis is based on extensive well and core data and basin-wide correlations of the Pennsylvanian coal groups. Four detailed cross sections were constructed, correlating the target coal groups in the basin, namely the Cobb, Pratt, Mary Lee, and Black Creek. They estimate that the Warrior basin contains nearly 20 tcf of in-place coal-bed methane, mainly in three of the target coal groups - the Pratt, Mary Lee, and Black Creek coals, with 4, 7, and 8 tcf, respectively. The east-central area of the basin contains the greatest volume of natural gas resource due to its concentration of thicker, higher ranked coals with high gas content. The geologic analysis also provided the underlying framework for the subsequent engineering analysis of economically recoverable gas reserves. For example, analysis of structure and tectonics showed the east-central area to be promising for gas recovery due to its proximity to the Appalachian structural front and consequent structural deformation and permeability enhancement.

  6. The Role of Isotopes in Monitoring Water Quality Impacts Associated with Shale Gas Drilling

    E-Print Network [OSTI]

    Wang, Z. Jane

    The Role of Isotopes in Monitoring Water Quality Impacts Associated with Shale Gas Drilling Methane contamination is usually due to natural causes; however, it can also be the result of drilling activities, including shale gas drilling. Monitoring techniques exist for detecting methane and, in some cases

  7. Cyclic process for producing methane in a tubular reactor with effective heat removal

    DOE Patents [OSTI]

    Frost, Albert C. (Congers, NY); Yang, Chang-Lee (Spring Valley, NY)

    1986-01-01T23:59:59.000Z

    Carbon monoxide-containing gas streams are converted to methane by a cyclic, essentially two-step process in which said carbon monoxide is disproportionated to form carbon dioxide and active surface carbon deposited on the surface of a catalyst, and said carbon is reacted with steam to form product methane and by-product carbon dioxide. The exothermic heat of reaction generated in each step is effectively removed during each complete cycle so as to avoid a build up of heat from cycle-to-cycle, with particularly advantageous techniques being employed for fixed bed, tubular and fluidized bed reactor operations.

  8. Cyclic process for producing methane from carbon monoxide with heat removal

    DOE Patents [OSTI]

    Frost, Albert C. (Congers, NY); Yang, Chang-lee (Spring Valley, NY)

    1982-01-01T23:59:59.000Z

    Carbon monoxide-containing gas streams are converted to methane by a cyclic, essentially two-step process in which said carbon monoxide is disproportionated to form carbon dioxide and active surface carbon deposited on the surface of a catalyst, and said carbon is reacted with steam to form product methane and by-product carbon dioxide. The exothermic heat of reaction generated in each step is effectively removed during each complete cycle so as to avoid a build up of heat from cycle-to-cycle, with particularly advantageous techniques being employed for fixed bed, tubular and fluidized bed reactor operations.

  9. Correlation of producing Fruitland Formation coals within the western outcrop and coalbed methane leakage on the Southern Ute Reservation

    SciTech Connect (OSTI)

    Carroll, Christopher J.; Mathews, Stephanie; Wickman, Barbara

    2000-07-07T23:59:59.000Z

    The Colorado Geological Survey and Southern Ute Indian Tribe proposed to determine the cause of several gas seeps which are occurring on the western outcrop of the coalbed methane producing Fruitland Formation on the Southern Ute Indian Reservation. Correlation between outcrop coals and subsurface coals was necessary to determine seep source in the northern part of the study area. Subsurface studies include structure and net coal isopach maps, stratigraphy was cross-sections, production maps, and a production database. Detailed coal stratigraphy was correlated through production wells near the outcrop region. These maps and cross-sections were correlated to new surface outcrop maps generated by the Colorado, Geological Survey and the Southern Ute Division of Energy Resources. Methane gas seepage has been noted historically within the study area. The total investigation may help determine if gas seepage is natural, a result of coalbed methane development, or some combination of the above.

  10. New insights into microbial responses to oil spills from the Deepwater Horizon incident

    E-Print Network [OSTI]

    Mason, O.U.

    2012-01-01T23:59:59.000Z

    C. J. Villanueva (2010). "Propane respiration jump-startsin samples that exhibited propane and ethane anomalies (loss of both ethane and propane relative to methane

  11. Numerical and experimental studies of ethanol flames and autoignition theory for higher alkanes

    E-Print Network [OSTI]

    Saxena, Priyank

    2007-01-01T23:59:59.000Z

    initiated ignition in methane-propane mixtures”, Combustiontemperature ignition of propane with MTBE as an additive:detonation in ethylene and propane mixtures”, Combustion and

  12. Coalbed Methane | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directed offOCHCO OverviewAttachments4 Chairs Meeting - AprilEvents CleanSeattle,Coalbed Methane Coalbed

  13. Methane Hydrate | Department of Energy

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122Commercial602 1,39732onMake Your Next Road TripMentor-ProtegeEnergy »Methane

  14. Methane Credit | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to: navigation, searchOfRose Bend <StevensMcClellan,II JumpMepsolarMesilla,Methane Credit Jump

  15. Strategic Planning, Design and Development of the Shale Gas Supply Chain Network

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    and fluids from the pure gas (methane) to produce what is known as "pipeline quality" dry natural gas.[2 in wells, providing raw materials for oil refineries or petrochemical plants, and as sources of energy.[3

  16. I/I ratios and halogen concentrations in pore waters of the Hydrate Ridge: Relevance for the origin of gas hydrates in ODP Leg 204

    E-Print Network [OSTI]

    Fehn, Udo

    in fluids associated with hydrocarbons, such as oil field brines (Moran et al., 1995) or coal-bed methane association of iodine with methane allows the identification of the organic source material responsible for iodine and methane in gas hydrates. In all cores, iodine concentrations were found to increase strongly

  17. Landfill Gas Fueled HCCI Demonstration System

    E-Print Network [OSTI]

    Blizman, Brandon J.; Makel, Darby B.; Mack, John Hunter; Dibble, Robert W.

    2006-01-01T23:59:59.000Z

    chemical- kinetic model of propane HCCI combustion,” SAEof a four-cylinder 1.9 l propane- fueled homogeneous chargethe fuel line can use propane from a tank and NG from the

  18. Temporal changes in gas hydrate mound topography and ecology: deep-sea time-lapse camera observations

    E-Print Network [OSTI]

    Vardaro, Michael Fredric

    2004-09-30T23:59:59.000Z

    . This is significant because methane is an important greenhouse gas trapping solar energy and contributing to global warming (Kvenvolden 1999). It has been observed that as water temperature increases gas hydrate begins to dissociate, releasing trapped gas (Mac... (Trehu, et al. 1999). If global warming results in an increase in global ocean temperatures, or if a seismic event destabilizes a large gas hydrate reservoir (Fig. I-3), it could result in the release of gas hydrate-bound methane into the water column...

  19. Simulation of methane production in a laboratory-scale reactor containing hydrate-bearing porous medium

    SciTech Connect (OSTI)

    Gamwo, I.K.; Myshakin, E.M.; Zhang, Wu; Warzinski, R.P.

    2008-01-01T23:59:59.000Z

    Production of methane, induced by depressurization of hydrate sediment in a reactor, was investigated by numerical simulations using a computational fluid dynamics code TOUGH+/Hydrate. The methane production rates were computed at well-pressure drops of 4.2, 14.7, and 29.5 MPa and at a reactor temperature of 21 0C. The predicted behavior of methane production from the reactor is consistent with field-scale simulations and observations. The production rate increases with pressure drop at the well. Evolution patterns of gas and hydrate distributions are similar to those obtained in field-scale simulations. These preliminary results clearly indicate that numerical simulators can be applied to laboratory-scale reactors to anticipate scenarios observed in field experiments.

  20. DEVELOPMENT OF COAL BED METHANE UTILIZING GIS TECHNOLOGIES

    SciTech Connect (OSTI)

    J. Daniel Arthur

    2003-04-01T23:59:59.000Z

    During the second half of the 1990's, Coal Bed Methane (CBM) production increased dramatically nationwide to represent a significant new source of income and natural gas for many independent and established producers. Matching these soaring production rates during this period were the advancements in Geographical Information Systems (GIS) technologies generating terra-bytes of new data for the oil and gas industry. Coupled to these accelerating initiatives are many environmental concerns relating to production wastes and water table depletion of fresh water resources. It is these concerns that prompted a vital need within the industry for the development of Best Management Practices (BMPs) and mitigation strategies utilizing GIS technologies for efficient environmental protection in conjunction with effective production of CBM. This was accomplished by developing a framework to take advantage of a combination of investigative field research joined with leading edge GIS technologies for the creation of environmentally characterized regions of study. Once evaluated these regions had BMP's developed to address their unique situations for Coal Bed Methane production and environmental protection. Results of the project will be used to support the MBOGC's Programmatic Environmental Impact Statement as required by the Montana Environmental Policy Act (MEPA) and by the BLM for NEPA related issues for acreage having federally owned minerals.

  1. Planar measurements of soot volume fraction and OH in a JP-8 pool fire Tara L. Henriksen a,*, Graham J. Nathan b

    E-Print Network [OSTI]

    Utah, University of

    a direct measurement, consistent with the influence of signal trapping. The axial and radial distributions methane, propane and ethylene diffusion flames [14,15]. Other recent studies have employed LII­19], and precessing jet bluff body flames of propane [20]. LII has also been employed in a scale model of a gas

  2. Low-Cost Methane Liquefaction Plant and Vehicle Refueling Station

    SciTech Connect (OSTI)

    B. Wilding; D. Bramwell

    1999-01-01T23:59:59.000Z

    The Idaho National Engineering and Environmental Laboratory (INEEL) is currently negotiating a collaborative effort with Pacific Gas and Electric (PG&E) that will advance the use of liquefied natural gas (LNG) as a vehicle fuel. We plan to develop and demonstrate a small-scale methane liquefaction plant (production of 5,000 to 10,000 gallons per day) and a low-cost ($150,000) LNG refueling station to supply fuel to LNG-powered transit buses and other heavy-duty vehicles. INEEL will perform the research and development work. PG&E will deploy the new facilities commercially in two demonstration projects, one in northern California, and one in southern California.

  3. MARINE BIOMASS SYSTEM: ANAEROBIC DIGESTION AND PRODUCTION OF METHANE

    E-Print Network [OSTI]

    Haven, Kendall F.

    2011-01-01T23:59:59.000Z

    University, School of Engineering, Ocean .. Engineel'ing-and nutrition, ocean engineering and methane generation. In

  4. Department of Energy Advance Methane Hydrates Science and Technology Projects

    Broader source: Energy.gov [DOE]

    Descriptions for Energy Department Methane Hydrates Science and Technology Projects, August 31, 2012

  5. A car-borne highly sensitive near-IR diode-laser methane detector

    SciTech Connect (OSTI)

    Berezin, A G; Ershov, Oleg V; Shapovalov, Yu P [Natural Science Center, A.M. Prokhorov General Physics Institute, Russian Academy of Sciences, Moscow (Russian Federation)

    2003-08-31T23:59:59.000Z

    A highly sensitive automated car-borne detector for measuring methane concentration in real time is designed, developed and tested under laboratory and field conditions. Measurements were made with the help of an uncooled tunable near-IR 1.65-{mu}m laser diode. The detector consists of a multipass optical cell with a 45-m long optical path and a base length of 0.5 m. The car-borne detector is intended for monitoring the methane concentration in air from the moving car to reveal the leakage of domestic gas. The sensitivity limit (standard deviation) under field conditions is 1 ppm (20 ppb under laboratory conditions) for a measuring time of 0.4 s. The measuring technique based on the detection of a single methane line ensured a high selectivity of methane detector relative to other gases. The methane detector can be easily modified for measuring other simple-molecule gases (e.g., CO, CO{sub 2}, HF, NO{sub 2}, H{sub 2}O) by replacing the diode laser and varying the parameters of the control program. (special issue devoted to the memory of academician a m prokhorov)

  6. Utah Natural Gas Number of Gas and Gas Condensate Wells (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5 Tables July 1996 Energy Information Administration Office ofthroughYear JanYear JanPropane, No.1Decade Year-0 Year-1Elements) Gas

  7. Water management technologies used by Marcellus Shale Gas Producers.

    SciTech Connect (OSTI)

    Veil, J. A.; Environmental Science Division

    2010-07-30T23:59:59.000Z

    Natural gas represents an important energy source for the United States. According to the U.S. Department of Energy's (DOE's) Energy Information Administration (EIA), about 22% of the country's energy needs are provided by natural gas. Historically, natural gas was produced from conventional vertical wells drilled into porous hydrocarbon-containing formations. During the past decade, operators have increasingly looked to other unconventional sources of natural gas, such as coal bed methane, tight gas sands, and gas shales.

  8. Alternative Fuels Data Center: Michigan School Buses Get Rolling on Propane

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduce OperatingPropane inMichigan School

  9. Alternative Fuels Data Center: Propane Rolls on as Reliable Fleet Fuel

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWP TWP RelatedCellulaseFuels andConversionsAssumptionsBenefitsPropane

  10. Kinetics simulation for natural gas conversion to unsaturated C? hydrocarbons

    E-Print Network [OSTI]

    Yang, Li

    2003-01-01T23:59:59.000Z

    ) techniques are being studied to convert natural gas to useful hydrocarbon liquids, which can be transported with far less cost. Direct pyrolysis of methane, followed by catalytic reaction, is a promising technology that can be commercialized in industry...

  11. Chem 350 Jasperse Ch. 3 Handouts 1 ALKANE NAMES (Memorize) (Sections 3.2)

    E-Print Network [OSTI]

    Jasperse, Craig P.

    C) Structure 1 Methane CH4 -162 H-(CH2)-H 2 Ethane C2H6 -89 H-(CH2)2-H 3 Propane C3H8 -42 H-(CH2)3-H 4 Butane C "Petroleum Gas" C2-C4 Propane C3 -42º Propane tanks, camping, etc. Gasoline C4-C9 30-180º

  12. New study shows prospects for unconventional natural gas

    SciTech Connect (OSTI)

    Sharer, J.C.; Rasmussen, J.J.

    1981-02-01T23:59:59.000Z

    With reserves of conventional sources of natural gas in the lower 48 expected to decline in coming decades, the potential of various supplemental gas sources is of critical interest to energy planners and decision makers. Substantial quantities of supplemental supplies can be produced domestically from Alaskan and unconventional sources or synthesized through conversion of organic materials. In addition, imports of LNG and pipeline gas from Canada and Mexico can further supplement the supply of gas available. Small quantities of gas already are being produced commercially from unconventional sources: approximately 0.8 tcf annually from western tight gas sands and 0.1 tcf from E. Devonian gas shales. A consensus is beginning to form in the gas industry on a reasonable range for forecasts of unconventional gas resources and potential production. The assessed resources include western tight gas sand, E. Devonian gas shales, coal seam methane, and methane from geopressured zones.

  13. Combustion: What is the Lower Heating Value (LHV) of Propane? Before we start: how reasonable is the use of the LHV? What is the dewpoint of the reaction products?

    E-Print Network [OSTI]

    Combustion: What is the Lower Heating Value (LHV) of Propane? Before we start: how reasonable temperature we can achieve with a propane-and-air blowtorch? We repeat this calculation for several different

  14. The catalytic oxidation of propane and propylene with air: total aldehyde production and selectivity at low conversions. 

    E-Print Network [OSTI]

    Looney, Franklin Sittig

    1950-01-01T23:59:59.000Z

    ~ Ths writer is izntebteg to pr, P G~ ~och Tor his assistance azsi guidance in this work aC to Br~ J+ 9 Kinds Tor his aery. suggestions eel Succor~ a The oxidation cf propane~ propylene and prcya~cregyimm mbetccres ctver a ~ aiucdna ~st in a flew... formation of aldehyde fran pure grade propane The ~ce of Within the range of variables of this investigation and with propylene ~& aldehyde pr~cn was f'ennd to bs independent of" residence Qorrcgations relating aldehyde pressure to ~ and cncygsn pressure...

  15. Shock tube and theoretical studies on the thermal decomposition of propane : evidence for a roaming radical channel.

    SciTech Connect (OSTI)

    Sivaramakrishnan, R.; Su, M.-C.; Michael, J. V.; Klippenstein, S. J.; Harding, L. B.; Ruscic, B. (Chemical Sciences and Engineering Division)

    2011-04-21T23:59:59.000Z

    The thermal decomposition of propane has been studied using both shock tube experiments and ab initio transition state theory-based master equation calculations. Dissociation rate constants for propane have been measured at high temperatures behind reflected shock waves using high-sensitivity H-ARAS detection and CH{sub 3} optical absorption. The two major dissociation channels at high temperature are C{sub 3}H{sub 8} {yields} CH{sub 3} + C{sub 2}H{sub 5} (eq 1a) and C{sub 3}H{sub 8} {yields} CH{sub 4} + C{sub 2}H{sub 4} (eq 1b). Ultra high-sensitivity ARAS detection of H-atoms produced from the decomposition of the product, C{sub 2}H{sub 5}, in (1a), allowed measurements of both the total decomposition rate constants, k{sub total}, and the branching to radical products, k{sub 1a}/k{sub total}. Theoretical analyses indicate that the molecular products are formed exclusively through the roaming radical mechanism and that radical products are formed exclusively through channel 1a. The experiments were performed over the temperature range 1417-1819 K and gave a minor contribution of (10 {+-} 8%) due to roaming. A multipass CH{sub 3} absorption diagnostic using a Zn resonance lamp was also developed and characterized in this work using the thermal decomposition of CH{sub 3}I as a reference reaction. The measured rate constants for CH{sub 3}I decomposition agreed with earlier determinations from this laboratory that were based on I-atom ARAS measurements. This CH{sub 3} diagnostic was then used to detect radicals from channel 1a allowing lower temperature (1202-1543 K) measurements of k1a to be determined. Variable reaction coordinate-transition state theory was used to predict the high pressure limits for channel (1a) and other bond fission reactions in C{sub 3}H{sub 8}. Conventional transition state theory calculations were also used to estimate rate constants for other tight transition state processes. These calculations predict a negligible contribution (<1%) from all other bond fission and tight transition state processes, indicating that the bond fission channel (1a) and the roaming channel (1b) are indeed the only active channels at the temperature and pressure ranges of the present experiments. The predicted reaction exo- and endothermicities are in excellent agreement with the current version of the Active Thermochemical Tables. Master equation calculations incorporating these transition state theory results yield predictions for the temperature and pressure dependence of the dissociation rate constants for channel 1a. The final theoretical results reliably reproduce the measured dissociation rate constants that are reported here and in the literature. The experimental data are well reproduced over the 500-2500 K and 1 x 10{sup -4} to 100 bar range (errors of {approx}15% or less) by the following Troe parameters for Ar as the bath gas: k{sub {infinity}} = 1.55 x 10{sup 24}T{sup -2.034} exp(-45490/T) s{sup -1}, k{sub 0} = 7.92 x 10{sup 53}T{sup -16.67} exp(-50380/T) cm{sup 3} s{sup -1}, and F{sub c} = 0.190 exp(-T/3091) + 0.810 exp(-T/128) + exp(-8829/T).

  16. Feasibility study: utilization of landfill gas for a vehicle fuel system, Rossman's landfill, Clackamas County, Oregon

    SciTech Connect (OSTI)

    None

    1981-01-01T23:59:59.000Z

    In 1978, a landfill operator in Oregon became interested in the technical and economic feasibility of recovering the methane generated in the landfill for the refueling of vehicles. DOE awarded a grant for a site-specific feasibility study of this concept. This study investigated the expected methane yield and the development of a conceptual gas-gathering system; gas processing, compressing, and storage systems; and methane-fueled vehicle systems. Cost estimates were made for each area of study. The results of the study are presented. Reasoning that gasoline prices will continue to rise and that approximately 18,000 vehicles in the US have been converted to operate on methane, a project is proposed to use this landfill as a demonstration site to produce and process methane and to fuel a fleet (50 to 400) vehicles with the gas produced in order to obtain performance and economic data on the systems used from gas collection through vehicle operation. (LCL)

  17. State Heating Oil and Propane Program, 1990--1991 heating season. Final technical report

    SciTech Connect (OSTI)

    Not Available

    1991-06-06T23:59:59.000Z

    The following discussion summarizes the survey approach and results of the Department of Public Service`s survey of retail fuel oil and propane prices during the 1990--91 heating season. The semi-monthly phone surveys were conducted in cooperation with the US Department of Energy`s State Fuel Oil and Propane Program, which coordinated surveys of heating fuel prices by 25 eastern and midwest states. This federal/state program serves as a method for fast collection, analysis, and dissemination of information on current residential prices. No other information source meets needs for timely retail price information over the course of the heating season. For the 1990--91 heating season, the Minnesota Department of Public Service (MN/DPS) expanded the scope of its survey effort to include regional price data. Surveys were conducted with 160 retailers, including 59 respondents from the DOE samples, to provide a reasonable sample size for each region. Fuel oil retailers were also asked for updates on their secondary inventory levels.

  18. State Heating Oil and Propane Program, 1990--1991 heating season

    SciTech Connect (OSTI)

    Not Available

    1991-06-06T23:59:59.000Z

    The following discussion summarizes the survey approach and results of the Department of Public Service's survey of retail fuel oil and propane prices during the 1990--91 heating season. The semi-monthly phone surveys were conducted in cooperation with the US Department of Energy's State Fuel Oil and Propane Program, which coordinated surveys of heating fuel prices by 25 eastern and midwest states. This federal/state program serves as a method for fast collection, analysis, and dissemination of information on current residential prices. No other information source meets needs for timely retail price information over the course of the heating season. For the 1990--91 heating season, the Minnesota Department of Public Service (MN/DPS) expanded the scope of its survey effort to include regional price data. Surveys were conducted with 160 retailers, including 59 respondents from the DOE samples, to provide a reasonable sample size for each region. Fuel oil retailers were also asked for updates on their secondary inventory levels.

  19. High Temperature Solar Splitting of Methane

    E-Print Network [OSTI]

    of Methane to Hydrogen and Carbon Allan Lewandowski (NREL) Alan Weimer (University of Colorado, Boulder) Team Members: CU: Jaimee Dahl, Karen Buechler, Chris Perkins NREL: Carl Bingham, Judy Netter Allan Lewandowski

  20. The role of methane in tropospheric chemistry

    E-Print Network [OSTI]

    Golomb, D.

    1989-01-01T23:59:59.000Z

    While methane is chemically quite inert to reactions with atmospheric molecular species, it does react with atomic species and molecular radicals. Because of its relatively large abundance in the global troposphere and ...