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1

Methane, Nonmethane Hydrocarbons, Alkyl Nitrates, and Chlorinated Carbon  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Trace Gases in Whole-Air Samples Atmospheric Trace Gases in Whole-Air Samples Methane, Nonmethane Hydrocarbons, Alkyl Nitrates, and Chlorinated Carbon Compounds including 3 Chlorofluorocarbons (CFC-11, CFC-12, and CFC-113) in Whole-air Samples graphics Graphics data Data Investigator Donald Blake Department of Chemistry, University of California Irvine, California, 92697 USA Period of Record April 1979 - December 2012 Methods Whole-air samples are collected in conditioned, evacuated, 2-L stainless steel canisters; each canister is filled to ambient pressure over a period of about 1 minute (approximately 20 seconds to 2 minutes). These canisters are returned to the University of California at Irvine for chromatographic analysis. Analysis for methane includes gas chromatography with flame ionization, as

2

Biomass burning sources of nitrogen oxides, carbon monoxide, and non-methane hydrocarbons  

SciTech Connect

Biomass burning is an important source of many key tropospheric species, including aerosols, carbon dioxide (CO{sub 2}), nitrogen oxides (NO{sub {times}}=NO+NO{sub 2}), carbon monoxide (CO), methane (CH{sub 4}), nitrous oxide (N{sub 2}O), methyl bromide (CH{sub 3}Br), ammonia (NH{sub 3}), non-methane hydrocarbons (NMHCs) and other species. These emissions and their subsequent products act as pollutants and affect greenhouse warming of the atmosphere. One important by-product of biomass burning is tropospheric ozone, which is a pollutant that also absorbs infrared radiation. Ozone is formed when CO, CH{sub 4}, and NMHCs react in the presence of NO{sub {times}} and sunlight. Ozone concentrations in tropical regions (where the bulk of biomass burning occurs) may increase due to biomass burning. Additionally, biomass burning can increase the concentration of nitric acid (HNO{sub 3}), a key component of acid rain.

Atherton, C.S.

1995-11-01T23:59:59.000Z

3

Kinetics of biological methane oxidation in the presence of non-methane organic compounds in landfill bio-covers  

SciTech Connect

In this experimental program, the effects of non-methane organic compounds (NMOCs) on the biological methane (CH{sub 4}) oxidation process were examined. The investigation was performed on compost experiments incubated with CH{sub 4} and selected NMOCs under different environmental conditions. The selected NMOCs had different concentrations and their effects were tested as single compounds and mixtures of compounds. The results from all experimental sets showed a decrease in CH{sub 4} oxidation capacity of the landfill bio-cover with the increase in NMOCs concentrations. For example, in the experiment using compost with 100% moisture content at 35 deg. C without any NMOCs the V{sub max} value was 35.0 mug CH{sub 4}h{sup -1}g{sub wetwt}{sup -1}. This value was reduced to 19.1 mug CH{sub 4}h{sup -1}g{sub wetwt}{sup -1} when mixed NMOCs were present in the batch reactors under the same environmental conditions. The experimental oxidation rates of CH{sub 4} in the presence of single and mixed NMOCs were modeled using the uncompetitive inhibition model and kinetic parameters, including the dissociation constants, were obtained. Additionally, the degradation rates of the NMOCs and co-metabolic abilities of methanotrophic bacteria were estimated.

Albanna, Muna, E-mail: muna.albanna@gju.edu.j [Department of Civil Engineering, University of Ottawa, 161 Louis Pasteur St., Ottawa, Ontario, K1N 6N5 (Canada); Warith, Mostafa; Fernandes, Leta [Department of Civil Engineering, University of Ottawa, 161 Louis Pasteur St., Ottawa, Ontario, K1N 6N5 (Canada)

2010-02-15T23:59:59.000Z

4

Anthropogenic emissions of nonmethane hydrocarbons in the northeastern United States: Measured seasonal variations from  

E-Print Network (OSTI)

in relative emissions for this series of trace gases. Seasonal changes in n-butane and i-butane emissions may [Seinfeld and Pandis, 1998]. [3] In this study, we present the seasonality of C2-C6 (ethane, propane, n-butane, i-butane, n-pentane, i-pentane and n-hexane) hydrocarbons, NOy and CO as measured at Harvard Forest

Goldstein, Allen

5

Conversion of methane and acetylene into gasoline range hydrocarbons  

E-Print Network (OSTI)

Conversion of methane and acetylene to higher molecular weight hydrocarbons over zeolite catalyst (HZSM-5) was studied The reaction between methane and acetylene successfully produced high molecular weight hydrocarbons, such as naphthalene, benzene, indene, azulene, fluorene, and biphenyl substituted compounds. Also, lighter hydrocarbons, such as ethylene and isobutene were produced. The reaction was conducted at different operating temperatures and different molar feed composition. The results showed that the conversion of both reactants increased with increasing the operating temperature; for example a conversion of 95.1% was achieved for acetylene at 350°C and 98.6% at 412°C. In addition, the conversion of both reactants decreased with increasing the molar feed ratio of methane to acetylene. A conversion of 96.4% for acetylene was achieved at a molar feed ratio of 6 to 1 (methane to acetylene) and 80.9% at a molar feed ration of 20 to 1 (methane to acetylene). The reaction of methane and ethane over HZSM-5 catalyst also led to the production of high molecular weight hydrocarbons, mainly aromatics, and some lighter products such as propane, and ethylene. Also methane by itself showed the ability to react over HZSM-5 to produce a small amount of aromatics, and ethylene.

Alkhawaldeh, Ammar

2000-01-01T23:59:59.000Z

6

Methane-derived hydrocarbons produced under upper-mantle conditions  

SciTech Connect

There is widespread evidence that petroleum originates from biological processes. Whether hydrocarbons can also be produced from abiogenic precursor molecules under the high-pressure, high-temperature conditions characteristic of the upper mantle remains an open question. It has been proposed that hydrocarbons generated in the upper mantle could be transported through deep faults to shallower regions in the Earth's crust, and contribute to petroleum reserves. Here we use in situ Raman spectroscopy in laser-heated diamond anvil cells to monitor the chemical reactivity of methane and ethane under upper-mantle conditions. We show that when methane is exposed to pressures higher than 2 GPa, and to temperatures in the range of 1,000-1,500 K, it partially reacts to form saturated hydrocarbons containing 2-4 carbons (ethane, propane and butane) and molecular hydrogen and graphite. Conversely, exposure of ethane to similar conditions results in the production of methane, suggesting that the synthesis of saturated hydrocarbons is reversible. Our results support the suggestion that hydrocarbons heavier than methane can be produced by abiogenic processes in the upper mantle.

Kolesnikov, Anton; Kutcherov, Vladimir G.; Goncharov, Alexander F.; (CIW); (RITS)

2009-08-13T23:59:59.000Z

7

Catalysts for conversion of methane to higher hydrocarbons  

DOE Patents (OSTI)

Catalysts for converting methane to higher hydrocarbons such as ethane and ethylene in the presence of oxygen at temperatures in the range of about 700.degree. to 900.degree. C. are described. These catalysts comprise calcium oxide or gadolinium oxide respectively promoted with about 0.025-0.4 mole and about 0.1-0.7 mole sodium pyrophosphate. A preferred reaction temperature in a range of about 800.degree. to 850.degree. C. with a preferred oxygen-to-methane ratio of about 2:1 provides an essentially constant C.sub.2 hydrocarbon yield in the range of about 12 to 19 percent over a period of time greater than about 20 hours.

Siriwardane, Ranjani V. (Morgantown, WV)

1993-01-01T23:59:59.000Z

8

Catalysts for conversion of methane to higher hydrocarbons  

DOE Patents (OSTI)

Catalysts for converting methane to higher hydrocarbons such as ethane and ethylene in the presence of oxygen at temperatures in the range of about 700 to 900{degrees}C are described. These catalysts comprise calcium oxide or gadolinium oxide respectively promoted with about 0.025--0.4 mole and about 0.1--0.7 mole sodium pyrophosphate. A preferred reaction temperature in a range of about 800 to 850{degrees}C with a preferred oxygen-to-methane ratio of about 2:1 provides an essentially constant C{sub 2} hydrocarbon yield in the range of about 12 to 19 percent over a period of time greater than about 20 hours.

Siriwardane, R.V.

1991-05-15T23:59:59.000Z

9

Hypothesis for increased atmospheric methane input from hydrocarbon seeps on exposed continental shelves during glacial low sea level  

E-Print Network (OSTI)

.- 2 Sept.1998 '" HYDROGEN PRODUCTION FROM COAL AND COAL BED METHANE, USING BYPRODUCT CO2 FOR ENHANCED METHANE RECOVERY AND SEQUESTERING THE CO2 IN mE COAL BED RH Williams, Center for Energy and Environmental that are poorly endowed with conventional hydrocarbon resources but coal- and coal-bed-methane-rich would

Luyendyk, Bruce

10

Conversion of methane to higher hydrocarbons (Biomimetic catalysis of the conversion of methane to methanol). Final report  

DOE Green Energy (OSTI)

In addition to inorganic catalysts that react with methane, it is well-known that a select group of aerobic soil/water bacteria called methanotrophs can efficiently and selectively utilize methane as the sole source of their energy and carbon for cellular growth. The first reaction in this metabolic pathway is catalyzed by the enzyme methane monooxygenase (MMO) forming methanol. Methanol is a technology important product from this partial oxidation of methane since it can be easily converted to liquid hydrocarbon transportation fuels (gasoline), used directly as a liquid fuel or fuel additive itself, or serve as a feedstock for chemicals production. This naturally occurring biocatalyst (MMO) is accomplishing a technologically important transformation (methane directly to methanol) for which there is currently no analogous chemical (non-biological) process. The authors approach has been to use the biocatalyst, MMO, as the initial focus in the development of discrete chemical catalysts (biomimetic complexes) for methane conversion. The advantage of this approach is that it exploits a biocatalytic system already performing a desired transformation of methane. In addition, this approach generated needed new experimental information on catalyst structure and function in order to develop new catalysts rationally and systematically. The first task is a comparative mechanistic, biochemical, and spectroscopic investigation of MMO enzyme systems. This work was directed at developing a description of the structure and function of the catalytically active sites in sufficient detail to generate a biomimetic material. The second task involves the synthesis, characterization, and chemical reactions of discrete complexes that mimic the enzymatic active site. These complexes were synthesized based on their best current understanding of the MMO active site structure.

Watkins, B.E.; Taylor, R.T.; Satcher, J.H. [and others

1993-09-01T23:59:59.000Z

11

Formation mechanism for polycyclic aromatic hydrocarbons in methane flames  

E-Print Network (OSTI)

exhausts,7­17 coal-fired, electricity generating power plants,18,19 tobacco smoke,20 residential wood applications including heating systems and gas turbines for electric power generation.62­64 The combustion propane,57,58 butane,59 ethane,31,53,60 and other aliphatic61 flames. Methane is used as fuel in many

Sattler, Klaus

12

Direct catalytic conversion of methane and light hydrocarbon gases. Final report, October 1, 1986--July 31, 1989  

DOE Green Energy (OSTI)

This project explored conversion of methane to useful products by two techniques that do not involve oxidative coupling. The first approach was direct catalytic dehydrocoupling of methane to give hydrocarbons and hydrogen. The second approach was oxidation of methane to methanol by using heterogenized versions of catalysts that were developed as homogeneous models of cytochrome-P450, an enzyme that actively hydroxylates hydrocarbons by using molecular oxygen. Two possibilities exist for dehydrocoupling of methane to higher hydrocarbons: The first, oxidative coupling to ethane/ethylene and water, is the subject of intense current interest. Nonoxidative coupling to higher hydrocarbons and hydrogen is endothermic, but in the absence of coke formation the theoretical thermodynamic equilibrium yield of hydrocarbons varies from 25% at 827{degrees}C to 65% at 1100{degrees}C (at atmospheric pressure). In this project we synthesized novel, highly dispersed metal catalysts by attaching metal clusters to inorganic supports. The second approach mimics microbial metabolism of methane to produce methanol. The methane mono-oxygenase enzyme responsible for the oxidation of methane to methanol in biological systems has exceptional selectivity and very good rates. Enzyme mimics are systems that function as the enzymes do but overcome the problems of slow rates and poor stability. Most of that effort has focused on mimics of cytochrome P-450, which is a very active selective oxidation enzyme and has a metalloporphyrin at the active site. The interest in nonporphyrin mimics coincides with the interest in methane mono-oxygenase, whose active site has been identified as a {mu}-oxo dinuclear iron complex.We employed mimics of cytochrome P-450, heterogenized to provide additional stability. The oxidation of methane with molecular oxygen was investigated in a fixed-bed, down-flow reactor with various anchored metal phthalocyanines (PC) and porphyrins (TPP) as the catalysts.

Wilson, R.B. Jr.; Posin, B.M.; Chan, Yee-Wai

1995-06-01T23:59:59.000Z

13

Direct catalytic conversion of methane and light hydrocarbon gases. Quarterly report No. 2, January 16, 1987--April 15, 1987  

DOE Green Energy (OSTI)

The goal of this research is to develop catalysts that directly convert methane and light hydrocarbons to intermediates that can, as economics dictate, be subsequently converted either to liquid fuels or value-added chemicals. In this program we are exploring two approaches to developing such catalysts. The first approach consists of developing advanced catalysts for reforming methane. We will prepare the catalysts by reacting organometallic complexes of transition metals (Fe, Ru, Rh, and Re) with zeolitic and rare-earth-exchanged zeolitic supports to produce surfaceconfined metal complexes in the zeolite pores. Our second approach entails synthesizing the porphyrin and phthalocyanine complexes of Cr, Mn, Ru, Fe, and/or Co within the pores of zeolitic supports for use as selective oxidation catalysts for methane and light hydrocarbons. During the second quarter of this project, we concentrated on methane reforming. Two ruthenium clusters (Ru{sub 4} and Ru{sub 6}) supported on three types of support materials ({beta}-alumina, 5 {Angstrom} molecular sieves, and {gamma}-zeolite) were tested for methane reforming. The effects of cluster size, supporting material, and reaction conditions were evaluated. The methane conversions range from 1.74 to 10.11% at 750{degrees}C. The reaction product contains hydrogen, C{sub 2} hydrocarbons, and C{sub 6} or higher hydrocarbons. Up to 48.34% yield of hydrocarbon (C{sub 2}+) is obtained based on reacted methane. Some of these catalysts show very good coking resistance compared with a commercial ruthenium catalyst. Addition of oxygen to these reactions significantly increases the percent methane conversion at lower reaction temperature. However, carbon dioxide and water are the major products in the presence of oxygen.

Wilson, R.B. Jr.; Chan, Yee Wai

1987-05-21T23:59:59.000Z

14

GRI methane chemistry program review meeting  

SciTech Connect

Methane is an important greenhouse gas which affects the atmosphere directly by the absorption and re-emission of infrared radiation as well as indirectly, through chemical interactions. Emissions of several important greenhouse gases (GHGS) including methane are increasing, mainly due to human activity. Higher concentrations of these gases in the atmosphere are projected to cause a decrease in the amount of infrared radiation escaping to space, and a subsequent warming of global climate. It is therefore vital to understand not only the causes of increased production of methane and other GHGS, but the effect of higher GHG concentrations on climate, and the possibilities for reductions of these emissions. In GRI-UIUC methane project, the role of methane in climate change and greenhouse gas abatement strategies is being studied using several distinct approaches. First, a detailed treatment of the mechanisms controlling each important methane source and sink, and hence the atmospheric concentration of methane, is being developed for use with the UIUC Integrated Science Assessment Model. The focus of this study is to resolve the factors which determine methane emissions and removal, including human population, land use, energy demand, global temperature, and regional concentrations of the hydroxyl radical, carbon monoxide, nitrous oxides, non-methane hydrocarbons, water vapor, tropospheric and stratospheric ozone.

Dignon, J.; Grant, K.; Grossman, A.; Wuebles, D.; Brasseur, G.; Madronich, S.; Huang, T.; Chang, J.; Lott, B.

1997-02-01T23:59:59.000Z

15

Direct catalytic conversion of methane and light hydrocarbon gases. Quarterly report No. 5, November 16, 1987--January 15, 1988  

DOE Green Energy (OSTI)

The goal of this research is to develop catalysts that directly convert methane and light hydrocarbons to intermediates that later can be converted to either liquid fuels or value-added chemicals, as economics dictate. During this reporting period, we have synthesized and tested several novel catalysts for methane reforming (Tasks 1 and 2) and for partial oxidation of methane (Tasks 3 and 4). We started to test a mixed metal system, an FeRu{sub 3} cluster. This catalyst was supported both on zeolite and on magnesium oxide and the systems were tested for methane reforming at various reaction temperatures. We also prepared and tested a monomeric ruthenium catalyst supported on magnesium oxide. We found that methane is activated at a lower temperature with the basic magnesium oxide support than with acidic supports such as zeolite or alumina. Methane conversions increased with temperature, but the production of coke also increased. We prepared a sterically hindered ruthenium porphyrin encapsulated in a zeolite supercage for catalysis of methane oxidation. The results showed that only carbon dioxide was produced. Addition of axial base to this catalyst gave similar results. Another type of catalyst, cobalt Schiff base complexes, was also prepared and tested for methane oxidation. In this case, no methane conversion was observed at temperatures ranging from 200 to 450{degrees}C. These complexes do not appear to be stable under the reaction conditions.

Wilson, R.B. Jr.; Chan Yee Wai

1988-02-05T23:59:59.000Z

16

Direct catalytic conversion of methane and light hydrocarbon gases. Quarterly report No. 1, October 16, 1986--January 15, 1987  

DOE Green Energy (OSTI)

The United States will need to be able to convert coal to liquid fuels should current supplies be interrupted. The indirect method for producing fuel liquids is the gasification of the coal to synthesis gas (syngas) followed by Fischer-Tropsch synthesis to convert syngas to hydrocarbons. However, both the gasifier and the FTS processes result in the production of methane and/or light hydrocarbon by-product that negatively affect the economics of the production of liquid fuel from coal. The goal of SRI`s research is thus to develop catalysts that directly convert methane and light hydrocarbons to intermediates that can, as economics dictate, be subsequently converted either to liquid fuels or value-added chemicals. SRI project 2678 is exploring two approaches to achieving the stated goal. The first approach consists of developing advanced catalysts for reforming methane. We will prepare the catalysts by reacting organometallic complexes of transition metals (Fe, Ru, Rh, and Re) with zeolitic and rare earth exchanged zeolitic supports to produce surfaceconfined metal complexes in the zeolite pores. We will then decompose the organometallic complexes to obtain very stable, highly dispersed catalysts. Our second approach entails synthesizing the porphyrin and phthalocyanine complexes of Cr, Mn, Ru, Fe, and/or Co within the pores of zeolitic supports for use as selective oxidation catalysts for methane and light hydrocarbons. We will test the catalysts in a fixed-bed isothermal microreactor in a downflow mode at {approximately}100 psi. During the first quarter of this project, we have concentrated on methane oxidation to methanol. We have synthesized phthalocyanine oxidation catalysts containing different metals (Co, Fe, and Ru) within zeolite pores. our examination of their ability to oxidize methane to methanol has indicated preliminary positive results.

Wilson, R.B. Jr.; Chan, Yee Wai

1987-02-23T23:59:59.000Z

17

Direct catalytic conversion of methane and light hydrocarbon gases. Quarterly report No. 9, October 1--December 31, 1988  

DOE Green Energy (OSTI)

The goal of this research is to develop catalysts that directly convert methane and light hydrocarbons to intermediates that later can be converted to either liquid fuels or value-added chemicals, as economics dictate. During this reporting period, we completed our IR spectroscopic examination of the Ru{sub 4}/MgO and FeRu{sub 3}/MgO systems under nitrogen and methane by examining FeRu{sub 3}/MgO under methane. This system behaved quite differently than the same system under nitrogen. Under methane, only one very broad peak is observed at room temperature. Upon heating, the catalyst transformed so that by 300{degrees}C, the spectrum of FeRu{sub 3}/MgO under methane was the same as that of Ru{sub 4}/MgO. This suggests that methane promotes the segregation of the metals in the mixed metal system. The differences in catalytic activity between the FeRu{sub 3}/MgO and Ru{sub 4}/MgO systems may then be due to the presence of IR transparent species such as iron ions which cause different nucleation in the ruthenium clusters. We examined several systems for activity in the methane dehydrogenation reaction. Focusing on systems which produce C{sub 6} hydrocarbons since this is the most useful product. These systems all displayed low activity so that the amount of hydrocarbon product is very low. Some C{sub 6} hydrocarbon is observed over zeolite supports, but its production ceases after the first few hours of reaction. We prepared a new system, Ru{sub 4} supported on carbon, and examined its reactivity. Its activity was very low and in fact the carbon support had the same level of activity. We synthesized four new systems for examination as catalysts in the partial oxidation of methane. Three of these (PtTSPC/MgO, PtTSPC and PdTSPC on carbon) are analogs of PdTSPC/MgO. This system is of interest because we have observed the production of ethane from methane oxidation over PdTSPC/MgO at relatively low temperatures and we wished to explore its generality among close analogs.

Wilson, R.B. Jr.; Posin, B.M.; Chan, Yee Wai

1989-03-10T23:59:59.000Z

18

Direct catalytic conversion of methane and light hydrocarbon gases. Quarterly report No. 6, January 16, 1988--April 15, 1988  

DOE Green Energy (OSTI)

The goal of this research is to develop catalysts that directly convert methane and light hydrocarbons to intermediates that later can be converted to either liquid fuels or value-added chemicals, as economics dictate. During this reporting period, we synthesized several phthalocyanine catalysts supported on magnesia (MgO) in Task 3. In Task 4 we have tested these catalysts for oxidation of methane and did a number of blank experiments to determine the cause of the low methanol yield we have observed. Magnesia supported catalysts were prepared by first synthesizing the various metal tetrasulfophthalocyanines (TSPCs), converting them to the acid form, and then supporting these complexes on a basic support (MgO) by a neutralization reaction. The metals used were Ru, Pd, Cu, Fe, Co, Mn, and Mo. CoTSPC was also synthesized in zeolite Y using our standard template techniques described in Quarterly Report No. 1. These complexes were examined for catalytic activity in the oxidation of methane. The PdTSPC/MgO had greater activity, and oxidized some of the methane (selectivity of 2.8% from the methane oxidized at 375{degrees}C) to ethane. This is a much lower temperature for this reaction than previously reported in the literature. We also examined the reactivity of various components of the system in the oxidation of the product methanol. The reactor showed some activity for the oxidation of methanol to carbon dioxide. When zeolite or magnesia were added, this activity increased. The magnesia oxidized most of the methanol to carbon dioxide, while the zeolite reduced some of the methanol to hydrocarbons. With oxygen in the feed gas stream (i.e., the conditions of our methane oxidation), a very large fraction of the methanol was oxidized to carbon dioxide when passed over magnesia. From this, we can conclude that any methanol formed in the oxidation of methane would probably be destroyed very quickly on the catalyst bed.

Wilson, R.B. Jr.; Chan, Yee Wai; Posin, B.M.

1988-05-20T23:59:59.000Z

19

Direct catalytic conversion of methane and light hydrocarbon gases. Quarterly report No. 8, July 16--September 30, 1988  

DOE Green Energy (OSTI)

The goal of this research is to develop catalysts that directly convert methane and light hydrocarbons to intermediates that later can be converted to either liquid fuels or value-added chemicals, as economics dictate. During this reporting period, we investigated the behavior of some of our catalysts under working conditions using diffuse reflectance fourier transform infrared spectroscopy (DRIFT). Two catalysts (FeRu{sub 3} and Ru{sub 4} on magnesia) were examined under nitrogen, and the Ru{sub 4}/MgO system was examined under a methane/argon mixture. We synthesized ruthenium clusters supported on carbon as catalysts for methane reforming and new phthalocyanines to be used as catalyst precursors for oxidizing methane to methanol. The Ru{sub 4} and FeRu{sub 3} complexes supported on magnesia exhibited very different behavior in the DRIFT cell when heated under nitrogen. The FeRu{sub 3}/MgO system was completely decarbonylated by 400{degrees}C, while spectrum of the Ru{sub 4} system displayed carbonyl peaks until the temperature rose to over 600{degrees}C. The ru{sub 4}/MgO system behaved almost identically under methane/argon as it did under nitrogen in the carbonyl region. In the C-H region of the spectrum (2800-3100 cm{sup {minus}1}), peaks were observed under methane but not under nitrogen. The intensity of these peaks did not vary with temperature. We synthesized new catalysts by supporting the Ru{sub 4} and Ru{sub 6} clusters on carbon. Both acidic zeolites (Type Y or 5A) and basic magnesia (MgO) have been observed to react with hydrocarbons at high temperatures; these reactions generally lead to coking, then deactivation of the catalyst contained on these supports. We expect carbon to be a truly inert support.

Wilson, R.B. Jr.; Posin, B.M.; Chan, Yee Wai

1989-03-01T23:59:59.000Z

20

Direct catalytic conversion of methane and light hydrocarbon gases. Quarterly report No. 3, April 16--July 15, 1987  

DOE Green Energy (OSTI)

The goal of this research is to develop catalysts that directly convert methane and light hydrocarbons to intermediates that can, as economics dictate, be subsequently converted either to liquid fuels or value-added chemicals. In this program we are exploring two approaches to developing such catalysts. The first approach consists of developing advanced catalysts for reforming methane. We will prepare the catalysts by reacting organometallic complexes of transition metals (Fe, Ru, Rh, and Re) with zeolitic and rare-earth-exchanged zeolitic supports to produce surface-confined metal complexes in the zeolite pores. Our second approach entails synthesizing the porphyrin and phthalocyanine complexes of Cr, Mn, Ru, Fe, and/or Co within the pores of zeolitic supports for use as selective oxidation catalysts for methane and light hydrocarbons. During this reporting period, we concentrated on synthesizing and testing methane oxidation catalysts using the automated GC sampling system. We modified our preparation method of zeolite-encapsulated phthalocyanines (PC). The catalysts have higher complex loading, and the uncomplexed metal ions were back-exchanged by sodium ions (to remove any uncomplexed metal ions). Four metal ions were used: cobalt, iron, ruthenium, and manganese. We also synthesized four zeolite-encapsulated tetraphenylporphyrin (TPP) complexes using the same metals. These catalysts were tested for methane oxidation in the temperature range from 300{degrees} to 500{degrees}C at 50 psig pressure. The RUPC, COTPP, and MNTPP showed activity toward the formation of methanol. The RUPC zeolite gave the best methanol yield. The methane conversion was 4.8%, and the selectivity to methanol is 11.3% at 375{degrees}C. Again, the major products are carbon dioxide and water in every catalyst we tested during this reporting period.

Wilson, R.B. Jr.; Chan, Yee Wai

1987-08-28T23:59:59.000Z

Note: This page contains sample records for the topic "methane nonmethane hydrocarbons" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Biogenic Hydrocarbons in the Atmospheric Boundary Layer: A Review  

Science Conference Proceedings (OSTI)

Nonmethane hydrocarbons are ubiquitous trace atmospheric constituents yet they control the oxidation capacity of the atmosphere. Both anthropogenic and biogenic processes contribute to the release of hydrocarbons to the atmosphere. In this ...

J. D. Fuentes; L. Gu; M. Lerdau; R. Atkinson; D. Baldocchi; J. W. Bottenheim; P. Ciccioli; B. Lamb; C. Geron; A. Guenther; T. D. Sharkey; W. Stockwell

2000-07-01T23:59:59.000Z

22

Direct catalytic conversion of methane and light hydrocarbon gases. Quarterly report No. 4, August 16--October 15, 1987  

DOE Green Energy (OSTI)

The goals of this research project are to increase the methane conversion and improve the hydrocarbon production. For methane reforming, we achieved a conversion of up to 43% by adjusting the reaction conditions. Ruthenium clusters are effective catalysts but the selectivity to hydrocarbons needs to be improved. In evaluating the effect of cluster size for mononuclear, tetranuclear, and hexanuclear ruthenium complexes we found that the tetraruthenium cluster was by far the most effective catalyst. We began to study the mixed metal catalysts by synthesizing a FeRu{sub 3} cluster. We plan to vary the ratio of Fe to Ru by synthesizing Fe{sub 2}Ru{sub 2} and Fe{sub 3}Ru clusters. The type of the support also plays an important role in methane reforming. We briefly tested a basic support, magnesia, in addition to the acidic supports tested previously (alumina, 5A molecular sieve, and Y-zeolite). The results are promising. We will continue to investigate the role of the support. The effectiveness of using a hydrogen removal membrane is still in question. We purchased a new Pd/Ag membrane tube inside which a stainless steel spring is inserted. The steel spring will increase the strength of the otherwise fragile tube and it will support the tube during bending. We will build a new reactor using this membrane tube.

Wilson, R.B. Jr.; Chan, Yee Wai

1987-11-19T23:59:59.000Z

23

Direct catalytic conversion of methane and light hydrocarbon gases. Quarterly report No. 7, April 16, 1988--July 15, 1988  

DOE Green Energy (OSTI)

The goal of this research is to develop catalysts that directly convert methane and light hydrocarbons to intermediates that later can be converted to either liquid fuels or value-added chemicals, as economics dictate. During this reporting period, much of our effort focused on investigating the stability of the methane reforming catalysts (Task 2) with respect to storage time. Many of these catalysts demonstrated lessened activity when they were reexamined up to 18 months after they ere first synthesized and tested. We also synthesized and tested two new phthalocyanines supported on magnesia (MgO) for examination in the methane oxidation reaction. We reexamined many of the hexaruthenium and tetraruthenium clusters which had been supported on zeolite Y, zeolite 5A, alumina or magnesia. These reexaminations were conducted at relatively slow flow rates (15 ml/min), since previous studies had shown that the lower flow rates maximized the conversion of methane in this reaction. In every case, the catalyst exhibited diminished activity compared to the earlier runs. In addition, the selectivity of the catalysts changed as well; relatively less C{sub 2} and no C{sub 6} was observed in the reactions conducted during this reporting period. In the previous technical report we reported that palladium tetrasulfophthalocyanine (PDTSPC) supported on MgO exhibited exceptional activity in the methane oxidation reaction; it produced ethane at much lower temperatures than previously reported in the literature. We synthesized two close analogues of this compound, one with a different metal (nickel) from the same family as palladium, and the other with a different substituent (carboxylic acid rather than sulfonic acid) on the phthalocyanine ring. Both of these complexes were supported on magnesia, and tested for activity. The nickel complex displayed some activity, producing only carbon dioxide and water.

Wilson, R.B. Jr.; Chan, Yee Wai; Posin, B.M.

1988-08-31T23:59:59.000Z

24

Clay enhancement of methane, low molecular weight hydrocarbon and halocarbon conversion by methanotrophic bacteria  

DOE Patents (OSTI)

The invention described in this report relates to a combined system of an apparatus and a method of increasing the rates of oxidation of gases and hazardous vapors by methanotrophic and other bacteria. The gases of interest are methane and trichlorethylene and other hazardous vapors. In a preferred embodiment, the oxidation rate of methane is improved by the addition of clays, e.g., kaolin, sometimes called ``China clay.``

Apel, W.A.; Dugan, P.R.

1991-12-31T23:59:59.000Z

25

Clay enhancement of methane, low molecular weight hydrocarbon and halocarbon conversion by methanotrophic bacteria  

DOE Patents (OSTI)

An apparatus and method for increasing the rate of oxidation of toxic vapors by methanotrophic bacteria. The toxic vapors of interest are methane and trichloroethylene. The apparatus includes a gas phase bioreactor within a closed loop pumping system or a single pass system. The methanotrophic bacteria include Methylomonas methanica, Methylosinus trichosporium, and uncharacterized environmental enrichments.

Apel, William A. (Idaho Falls, ID); Dugan, Patrick R. (Idaho Falls, ID)

1995-01-01T23:59:59.000Z

26

Geochemical assessment of gaseous hydrocarbons: mixing of bacterial and thermogenic methane in the deep subsurface petroleum system, Gulf of Mexico continental slope  

E-Print Network (OSTI)

Mixtures of bacterial and thermogenic methane are found both at vents at the seafloor and in reservoirs in the deep subsurface of the Gulf of Mexico continental slope. The C1-C5 gas that most recently charged reservoirs of Jolliet (GC 184), Genesis (GC 160/161) and Petronius (VK 786) fields is estimated to include 17%-28%, 31%-51%, 31%-49% bacterial methane, respectively. Geochemical assessment of the reservoir gas in the fields show that the gas may be the product of thermal cracking of Upper Jurassic crude oil before final migration to the reservoirs. The gas from three different fields is of similar thermal maturity levels. In contrast to oil in reservoirs in the fields, which shows biodegradation effects, the C1-C5 reservoir gas is unaltered by biodegradation. Late gas migration may have occurred at or near present burial depth and flushed the reservoir system of previously biodegraded hydrocarbon gas to include any previous bacterial methane. Molecular and isotopic properties of reservoir gas and oil suggest that bacterial methane mixed with thermogenic hydrocarbon gas before entering the reservoirs. Thus the source of the bacterial methane is logically deeper than the present depth (>~4 km) and temperatures of the reservoirs. High sedimentation rate and low geothermal gradient may offer conditions favorable for generation and preservation of bacterial methane in deep subsurface petroleum system of the Gulf slope. Bacterial methane dispersed across the large drainage areas of the deep subsurface petroleum system may have been swept by migrating fluids at >4 km, and then charged both vents (GC 185, GC 233 and GC 286) at the seafloor and reservoirs in the deep subsurface. The volume of bacterial methane from geologically significant depth in rapidly subsiding basins may be underestimated.

Ozgul, Ercin

2002-08-01T23:59:59.000Z

27

Direct catalytic conversion of methane and light hydrocarbon gases. Quarterly report No. 10, January 1--March 31, 1989  

DOE Green Energy (OSTI)

The goal of this research is to develop catalysts that directly convert methane and light hydrocarbons to intermediates that later can be converted to either liquid fuels or value-added chemicals, as economics dictate. In this reporting period, we have utilized samples of magnesia differing in their pretreatment temperature. Both the hydrido-ruthenium complex H{sub 4}Ru{sub 4}(CO){sub 12} and its reaction product with triethyl aluminum were reacted with these samples. The two ruthenium clusters are expected to react with the magnesia surface in different ways: by deprotonation of the hydride through an acid-base reaction with the basic surface, or by hydrolysis of the aluminum-carbon bond of the triethyl aluminum adduct. The concentration of hydroxyl groups on the magnesia surface able to hydrolyze the aluminum-carbon bond for immobilation should vary depending on the temperature of the pretreatment; the concentration of basic sites which can deprotonate the cluster should also vary with temperature. These differences were borne out by the experiment. We also compared the activity of two batches of AlRu{sub 4}/MgO which had been synthesized at different times in the project. Both batches had approximately the same activity, but the newer batch had greater selectivity for C{sub 6+} hydrocarbons.

Wilson, R.B. Jr.; Posin, B.M.; Chan, Yee Wai

1989-05-19T23:59:59.000Z

28

Plasma—Methane Reformation  

INL thermal plasma methane reformation process produces hydrogen and elemental carbon from natural gas and other hydrocarbons, such as natural gas or ...

29

Source profiles for nonmethane organic compounds in the atmosphere of Cairo, Egypt.  

Science Conference Proceedings (OSTI)

Profiles of the sources of nonmethane organic compounds (NMOCs) were developed for emissions from vehicles, petroleum fuels (gasoline, liquefied petroleum gas (LPG), and natural gas), a petroleum refinery, a smelter, and a cast iron factory in Cairo, Egypt. More than 100 hydrocarbons and oxygenated hydrocarbons were tentatively identified and quantified. Gasoline-vapor and whole-gasoline profiles could be distinguished from the other profiles by high concentrations of the C{sub 5} and C{sub 6} saturated hydrocarbons. The vehicle emission profile was similar to the whole-gasoline profile, with the exception of the unsaturated and aromatic hydrocarbons, which were present at higher concentrations in the vehicle emission profile. High levels of the C{sub 2}-C{sub 4} saturated hydrocarbons, particularly n-butane, were characteristic features of the petroleum refinery emissions. The smelter and cast iron factory emissions were similar to the refinery emissions; however, the levels of benzene and toluene were greater in the former two sources. The LPG and natural gas emissions contained high concentrations of n-butane and ethane, respectively. The NMOC source profiles for Cairo were distinctly different from profiles for U.S. sources, indicating that NMOC source profiles are sensitive to the particular composition of petroleum fuels that are used in a location.

Doskey, P. V.; Fukui, Y.; Sultan, M.; Maghraby, A. A.; Taher, A.; Environmental Research; Cairo Univ.

1999-07-01T23:59:59.000Z

30

Modern Records of Radiatively Important Halogenated Compounds...  

NLE Websites -- All DOE Office Websites (Extended Search)

at CDIAC sites: Methane, Nonmethane Hydrocarbons, Alkyl Nitrates, and Chlorinated Carbon Compounds including three Chlorofluorocarbons (CFC-11, CFC-12, and CFC-113) in...

31

Graphics: Atmospheric Trace Gases in Whole-Air Samples  

NLE Websites -- All DOE Office Websites (Extended Search)

Graphics graphics Graphics: Atmospheric Trace Gases in Whole-Air Samples The following links are for methane, nonmethane hydrocarbons, alkyl nitrates, and chlorinated carbon...

32

The Extraction of the Thermal Emission Band of Methane from the Longwave Spectrum of the Atmosphere  

Science Conference Proceedings (OSTI)

The thermal emission band at 1306 cm?1 of atmospheric methane, an important greenhouse gas, is presented for a cold, clear day in January 1994. A spectrum of the nonmethane emission features has been simulated using the FASCD3P radiation code and ...

W. F. J. Evans; E. Puckrin

1995-12-01T23:59:59.000Z

33

Process for recovery of liquid hydrocarbons  

SciTech Connect

Methane is recovered as a gas for discharge to a pipeline from a gas stream containing methane and heavier hydrocarbons, principally ethane and propane. Separation is accomplished by condensing the heavier hydrocarbons and distilling the methane therefrom. A liquid product (LPG) comprising the heavier hydrocarbons is subsequently recovered and transferred to storage. Prior to being discharged to a pipeline, the recovered methane gas is compressed and in undergoing compression the gas is heated. The heat content of the gas is employed to reboil the refrigerant in an absorption refrigeration unit. The refrigeration unit is used to cool the LPG prior to its storage.

Millar, J.F.; Cockshott, J.E.

1978-04-11T23:59:59.000Z

34

Methane Main  

NLE Websites -- All DOE Office Websites (Extended Search)

the the Methane Hydrate Advisory Committee on Methane Hydrate Issues and Opportunities Including Assessment of Uncertainty of the Impact of Methane Hydrate on Global Climate Change December 2002 Report of the Methane Hydrate Advisory Committee on Methane Hydrate Issues and Opportunities Including Assessment of Uncertainty of the Impact of Methane Hydrate on Global Climate Change December 2002 i CONTENTS What is Methane Hydrate? ............................................................................................. 1 Why Methane Hydrate Matters for the United States? ..................................................... 4 Resource Potential of Methane Hydrate .......................................................................... 5 Implications of Methane Hydrate on Safety and Seafloor Stability

35

Selective methane oxidation over promoted oxide catalysts  

DOE Green Energy (OSTI)

Objective was to selectively oxidize methane to C{sub 2} hydrocarbons and to oxygenates, in particular formaldehyde and methanol, in high space time yields under relatively mild reaction conditions. Results in this document are reported under the headings: methane oxidation over silica, methane oxidation over Sr/La{sub 2}O{sub 3} catalysts, and oxidative coupling of methane over sulfate-doped Sr/La{sub 2}O{sub 3} catalysts. 24 refs, 10 figs, 4 tabs.

Klier, K.; Herman, R.G.

1993-12-31T23:59:59.000Z

36

Hydrogen Production from Methane Using Oxygen-permeable Ceramic Membranes.  

E-Print Network (OSTI)

??Non-porous ceramic membranes with mixed ionic and electronic conductivity have received significant interest as membrane reactor systems for the conversion of methane and higher hydrocarbons… (more)

Faraji, Sedigheh

2010-01-01T23:59:59.000Z

37

Resource Recovery of Coal Bed Methane Formation Water.  

E-Print Network (OSTI)

??During the excavation of natural gas, petroleum hydrocarbon-polluted brine water, termed production water, is drawn from the coal bed methane formations (CBMF) along with the… (more)

Bishop, Catherine Elizabeth

2006-01-01T23:59:59.000Z

38

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Seismic-Scale Rock Physics of Methane Hydrate Seismic-Scale Rock Physics of Methane Hydrate DE-FC26-05NT42663 Goal The goal of this project was to establish rock physics models for use in generating synthetic seismic signatures of methane hydrate reservoirs. Ultimately, the intent was to improve seismic detection and quantification of offshore and onshore methane hydrate accumulations. Performer Stanford University, Stanford, CA 94305 Background Gas hydrate reservoir characterization is, in principle, no different from traditional hydrocarbon reservoir characterization. The seismic response of the subsurface is determined by the spatial distribution of the elastic properties (properties of the subsurface that deform as seismic waves pass through it) and attenuation. By mapping changes in the elastic properties, scientists can identify geologic features, including hydrocarbon reservoirs.

39

Biomass Burning and the Production of Greenhouse Gases  

Science Conference Proceedings (OSTI)

Biomass burning is a source of greenhouse gases, carbon dioxide, methane, and nitrous oxide. In addition, biomass burning is a source of chemically active gases, including carbon monoxide, nonmethane hydrocarbons, and nitric oxide. These gases, along ...

Levine J. S.

1994-01-01T23:59:59.000Z

40

THERMOCATALYTIC CO2-FREE PRODUCTION OF HYDROGEN FROM HYDROCARBON FUELS  

E-Print Network (OSTI)

, preferential oxidation) and gas separation stages required by conventional technologies (e.g., steam reforming and carbon via sustainable catalytic decomposition of methane or other hydrocarbons using inexpensive-situ generation of catalytically active carbon species produced by co-decomposition of methane and unsaturated and

Note: This page contains sample records for the topic "methane nonmethane hydrocarbons" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Collisional processes of hydrocarbons in hydrogen plasmas  

DOE Green Energy (OSTI)

We have investigated the reactions of methane and its derivatives with hydrogen plasmas for use in modelling carbon and hydrocarbon transport in hydrogen plasmas. We provide quantitative information over the temperature range from 0.1 eV to 2 keV for the most significant reactions of methane and methane fragments with electrons and protons. We review the properties of each reaction, present graphs of the cross section and reaction rate coefficient, and give analytical fits for sigma and (sigmav). 34 refs.

Ehrhardt, A.B.; Langer, W.D.

1987-09-01T23:59:59.000Z

42

Direct use of methane in coal liquefaction  

DOE Patents (OSTI)

This invention relates to a process for converting solid carbonaceous material, such as coal, to liquid and gaseous hydrocarbons utilizing methane, generally at a residence time of about 20-120 minutes at a temperature of 250.degree.-750.degree. C., preferably 350.degree.-450.degree. C., pressurized up to 6000 psi, and preferably in the 1000-2500 psi range, preferably directly utilizing methane 50-100% by volume in a mix of methane and hydrogen. A hydrogen donor solvent or liquid vehicle such as tetralin, tetrahydroquinoline, piperidine, and pyrolidine may be used in a slurry mix where the solvent feed is 0-100% by weight of the coal or carbonaceous feed. Carbonaceous feed material can either be natural, such as coal, wood, oil shale, petroleum, tar sands, etc., or man-made residual oils, tars, and heavy hydrocarbon residues from other processing systems.

Sundaram, Muthu S. (Shoreham, NY); Steinberg, Meyer (Melville, NY)

1987-01-01T23:59:59.000Z

43

Direct use of methane in coal liquefaction  

DOE Patents (OSTI)

This invention relates to a process for converting solid carbonaceous material, such as coal, to liquid and gaseous hydrocarbons utilizing methane, generally at a residence time of about 20 to 120 minutes at a temperature of 250 to 750/sup 0/C, preferably 350 to 450/sup 0/C, pressurized up to 6000 psi, and preferably in the 1000 to 2500 psi range, preferably directly utilizing methane 50 to 100% by volume in a mix of methane and hydrogen. A hydrogen donor solvent or liquid vehicle such as tetralin, tetrahydroquinoline, piperidine, and pyrolidine may be used in a slurry mix where the solvent feed is 0 to 100% by weight of the coal or carbonaceous feed. Carbonaceous feed material can either be natural, such as coal, wood, oil shale, petroleum, tar sands, etc., or man-made residual oils, tars, and heavy hydrocarbon residues from other processing systems. 1 fig.

Sundaram, M.S.; Steinberg, M.

1985-06-19T23:59:59.000Z

44

The hydroxyl radical initiated oxidation of unsaturated hydrocarbons in the troposphere: a theoretical and experimental approach  

E-Print Network (OSTI)

Isoprene is the dominant non-methane organic compound emitted by vegetation into the atmosphere, with a global emission rate of ~ 500 Tg yr-1. Its oxidation serves as a major source of ground level ozone in North America during the summer months. Despite the significant impact on tropospheric chemistry, questions remain concerning the detailed oxidation mechanism. The initial step in the mechanism is the addition of OH to form four distinct isomers. The relative branching between these isomers influences the distribution of the final products. I present a comprehensive investigation into the mechanistic details of early steps in the oxidation mechanism of unsaturated hydrocarbons in the troposphere and employ theoretical and experimental techniques. To understand the detailed kinetics of the initial OH addition to unsaturated hydrocarbons, I first present a model developed for the ethylene-OH system. I present the details of a robust two-transition state model. I extend the developed two-transition state model to the case of OH addition to isoprene. Excellent agreement with observed temperature and pressure dependent rate constants affords a high confidence level in understanding of the kinetics and in the calculated branching ratio of the initial OH addition step. I then focus attention on the subsequent reactivity of the OH-isoprene adducts. Until recently, all four of the OH-isoprene adducts were supposed to have reacted with O2 via addition to form alkylperoxy radicals. Previous computational results suggest that two of the OH-isoprene adducts undergo an intramolecular cyclic isomerization followed by hydrogen abstraction by O2 to form stable carbonyl compounds. I have synthesized photolytic precursors, presenting a novel approach to probe the subsequent reactivity of individual hydroxyalkyl radicals. Initial verification of the cyclic isomerization pathway involved synthesis of the photolytic precursor corresponding to the 1,3-butadiene-OH adduct. A culmination of theoretical and experimental techniques allowed verification of the cyclic isomerization pathway. I synthesized the photolytic precursor, which provided a single isoprene-OH adduct. Employing laser photolysis/laser induced fluorescence, time-dependent multiplexed mass spectrometry, velocity map ion imaging, and theoretical techniques, we present the full characterization of the reactivity of the single isoprene-OH adduct in the presence of O2.

Tullos, Erin Elizabeth

2007-05-01T23:59:59.000Z

45

Coalbed Methane  

Energy.gov (U.S. Department of Energy (DOE))

Coalbed methane is natural gas found in coal deposits. It was once considered a nuisance and mine safety hazard, but today has become a valuable part of the U.S. energy portfolio. A major reason for this is resource characterization and the establishment of efficient recovery methods pioneered by Office of Fossil Energy R&D.

46

Steady-state and transient catalytic oxidation and coupling of methane  

DOE Green Energy (OSTI)

This project addresses the conversion of methane from natural gas into ethane, ethylene and higher hydrocarbons. Our research explores the mechanistic and practical implications of carrying out the methane oxidative coupling reaction in reactor designs other than conventional packed-beds with co-fed reactants. These alternate reactor designs are needed to prevent the full oxidation of methane, which limits C{sub 2}, yields in methane oxidative coupling reactions. The research strategy focuses on preventing contact between the 0{sub 2} reactant required for favorable overall thermodynamics and the C{sub 2+} products of methane coupling. The behavior of various reactor designs are simulated using detailed kinetic transport models. These simulations have suggested that the best way to prevent high C0{sub 2} yields is to separate the oxygen and hydrocarbon streams altogether. As a result, the project has focused on the experimental demonstration of proton transport membrane reactors for the selective conversion of methane into higher hydrocarbons.

Iglesia, E.; Perry, D.L.; Heinemann, H.

1995-06-01T23:59:59.000Z

47

Methane (CH4)  

NLE Websites -- All DOE Office Websites (Extended Search)

Methane (CH4) Gateway Pages to Methane Data Modern Records of Atmospheric Methane (CH4) and a 2000-year Ice-core Record from Law Dome, Antarctica 800,000-year Ice-Core Records of...

48

Membrane-augmented cryogenic methane/nitrogen separation  

DOE Patents (OSTI)

A membrane separation process combined with a cryogenic separation process for treating a gas stream containing methane, nitrogen and at least one other component. The membrane separation process works by preferentially permeating methane and the other component and rejecting nitrogen. The process is particularly useful in removing components such as water, carbon dioxide or C.sub.3+ hydrocarbons that might otherwise freeze and plug the cryogenic equipment.

Lokhandwala, Kaaeid (Menlo Park, CA)

1997-01-01T23:59:59.000Z

49

Membrane-augmented cryogenic methane/nitrogen separation  

DOE Patents (OSTI)

A membrane separation process is described which is combined with a cryogenic separation process for treating a gas stream containing methane, nitrogen and at least one other component. The membrane separation process works by preferentially permeating methane and the other component and rejecting nitrogen. The process is particularly useful in removing components such as water, carbon dioxide or C{sub +2} hydrocarbons that might otherwise freeze and plug the cryogenic equipment. 10 figs.

Lokhandwala, K.

1997-07-15T23:59:59.000Z

50

NIST: Methane Symmetry Operations  

Science Conference Proceedings (OSTI)

*. Bookmark and Share. Version History Methane Symmetry Operations. JT Hougen Optical Technology Division Gloria Wiersma ...

2010-10-05T23:59:59.000Z

51

: Plasma-Hydrocarbon conversion  

crude oil and hydrocarbon gases like natural gas, into lighter hydrocarbon materials (e.g. synthetic light oil).

52

Apparatus for hydrocarbon extraction  

DOE Patents (OSTI)

Systems and methods for hydrocarbon extraction from hydrocarbon-containing material. Such systems and methods relate to extracting hydrocarbon from hydrocarbon-containing material employing a non-aqueous extractant. Additionally, such systems and methods relate to recovering and reusing non-aqueous extractant employed for extracting hydrocarbon from hydrocarbon-containing material.

Bohnert, George W.; Verhulst, Galen G.

2013-03-19T23:59:59.000Z

53

DOE Announces $2 Million Funding for Methane Hydrates Projects | Department  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

DOE Announces $2 Million Funding for Methane Hydrates Projects DOE Announces $2 Million Funding for Methane Hydrates Projects DOE Announces $2 Million Funding for Methane Hydrates Projects November 7, 2005 - 12:43pm Addthis Seeks to Unlock World's Biggest Potential Source of "Ice That Burns" WASHINGTON, DC - The Department of Energy (DOE) today announced a total of $2 million in funding to five research projects that will assess the energy potential, safety, and environmental aspects of methane hydrate exploration and development. Termed the "ice that burns," methane hydrates are crystalline solids that release a flammable gas when melted. They are considered the Earth's biggest potential source of hydrocarbon energy and could be a key element in meeting natural gas demand in the United States,

54

Aerobic microorganism for the degradation of chlorinated aliphatic hydrocarbons  

DOE Patents (OSTI)

A chlorinated aliphatic hydrocarbon-degrading microorganism, having American Type Culture Collection accession numbers ATCC 53570 and 53571, in a biologically pure culture aseptically collected from a deep subsurface habitat and enhanced, mineralizes trichloroethylene and tetrachloroethylene to HCl, H.sub.2 O and Co.sub.2 under aerobic conditions stimulated by methane, acetate, methanol, tryptone-yeast extract, propane and propane-methane.

Fliermans, Carl B. (Augusta, GA)

1989-01-01T23:59:59.000Z

55

Aerobic microorganism for the degradation of chlorinated aliphatic hydrocarbons  

DOE Patents (OSTI)

This invention pertains to a chlorinated aliphatic hydrocarbon-degrading microorganism, having American Type Culture Collection accession numbers ATCC 53570 and 53571, in a biologically pure culture aseptically collected from a deep subsurface habitat and enhanced, mineralizes trichloroethylene and tetrachloroethylene to HCl, H{sub 2}O and CO{sub 2} under aerobic conditions stimulated by methane, acetate, methanol, tryptone-yeast extract, propane and propane-methane.

Fliermans, C.B.

1988-10-12T23:59:59.000Z

56

Heat pipe methanator  

DOE Patents (OSTI)

A heat pipe methanator for converting coal gas to methane. Gravity return heat pipes are employed to remove the heat of reaction from the methanation promoting catalyst, transmitting a portion of this heat to an incoming gas pre-heat section and delivering the remainder to a steam generating heat exchanger.

Ranken, William A. (Los Alamos, NM); Kemme, Joseph E. (Los Alamos, NM)

1976-07-27T23:59:59.000Z

57

NETL: Methane Hydrates - Methane Hydrate Reference Shelf  

NLE Websites -- All DOE Office Websites (Extended Search)

Reference Shelf Reference Shelf The Methane Hydrate Reference Shelf was created to provide a repository for information collected from projects funded as part of the National Methane Hydrate R&D Program. As output from the projects is received, it will be reviewed and then placed onto the reference shelf to be available to other methane hydrate researchers. Projects: DOE/NETL Projects : These pages contain detailed information on methane hydrate projects funded through the National Energy Technology Laboratory. Publications: Newsletter | Bibliography | Software | Reports | Program Publications | Photo Gallery Newsletter: Fire in the Ice: A publication highlighting the National Methane Hydrate R&D Program Bibliography: "Project Reports Bibliography"[PDF]: The bibliography lists publications resulting from DOE/NETL-sponsored

58

Process for the production of ethylene and other hydrocarbons from coal  

DOE Patents (OSTI)

A process for the production of economically significant amounts of ethyl and other hydrocarbon compounds, such as benzene, from coal is disclosed wherein coal is reacted with methane at a temperature in the approximate range of 500.degree. C. to 1100.degree. C. at a partial pressure less than about 200 psig for a period of less than 10 seconds. Ethylene and other hydrocarbon compounds may be separated from the product stream so produced, and the methane recycled for further production of ethylene. In another embodiment, other compounds produced, such as by-product tars, may be burned to heat the recycled methane.

Steinberg, Meyer (Huntington Station, NY); Fallon, Peter (East Moriches, NY)

1986-01-01T23:59:59.000Z

59

Kinetics simulation for natural gas conversion to unsaturated C? hydrocarbons  

E-Print Network (OSTI)

Natural gas resource is abundant and can be found throughout the world. But most natural gas reserves are at remote sites and considered stranded because of the extremely expensive transportation cost. Therefore advanced gas-to-liquid (GTL) techniques are being studied to convert natural gas to useful hydrocarbon liquids, which can be transported with far less cost. Direct pyrolysis of methane, followed by catalytic reaction, is a promising technology that can be commercialized in industry. In this process, methane is decomposed to ethylene, acetylene and carbon. Ethylene and acetylene are the desired products, while carbon formation should be stopped in the decomposition reaction. Some researchers have studied the dilution effect of various inert gases on carbon suppression. All previous results are based on the isothermal assumption. In this thesis, our simulator can be run under adiabatic conditions. We found there was a crossover temperature for carbon formation in the adiabatic case. Below the crossover temperature, the carbon formation from pure methane feed is higher than the one from a methane/hydrogen feed, while above the crossover temperature, the carbon formation from pure methane feed is lower than the one from a methane/hydrogen feed. In addition to the pure methane and methane/hydrogen feed, we also simulated the rich natural gas feed, rich natural gas with combustion gas, rich natural gas with combustion gas and methane recycle. We found the outlet temperature increases only slightly when we increase the initial feed temperature. Furthermore, the combustion gas or the recycled methane has a dilute effect, which increases the total heat capacity of reactants. The outlet temperature from the cracker will not drop so much when these gases are present, causing the methane conversion to increase correspondingly. Up to now there is no adiabatic simulator for methane pyrolysis. This work has significant meaning in practice, especially for rich natural gases.

Yang, Li

2003-01-01T23:59:59.000Z

60

Removing the Hydrocarbon from Hydrocarbon Flow ...  

Science Conference Proceedings (OSTI)

... gas and petroleum products. Therefore is important to have primary calibration standards with low uncertainty. NIST has several hydrocarbon liquid ...

2014-01-03T23:59:59.000Z

Note: This page contains sample records for the topic "methane nonmethane hydrocarbons" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Biomass burning and the production of greenhouse gases, in Climate Biosphere Interaction: Biogenic Emissions and the Environmental Effects of Climate Change, edited by  

E-Print Network (OSTI)

Biomass burning is a source of greenhouse gases, carbon dioxide, methane, and nitrous oxide. In addition, biomass burning is a source of chemically active gases, including carbon monoxide, nonmethane hydrocarbons, and nitric oxide. These gases, along with methane, lead to the chemical production of tropospheric ozone (another greenhouse gas) as well as control the concentration of the

Joel S. Levine

1994-01-01T23:59:59.000Z

62

Non-oxidative conversion of methane with continuous hydorgen removal  

SciTech Connect

The objective is to overcome the restrictions of non-oxidative methane pyrolysis and oxidative coupling of methane by transferring hydrogen across a selective inorganic membrane between methane and air streams, without simultaneous transport of hydrocarbon reactants or products. This will make the overall reaction system exothermic, remove the thermodynamic barrier to high conversion, and eliminate the formation of carbon oxides. Our approach is to couple C-H bond activation and hydrogen removal by passage of hydrogen atoms through a dense ceramic membrane. In our membrane reactor, catalytic methane pyrolysis produces C2+ hydrogen carbons and aromatics on the one side of the membrane and hydrogen is removed through an oxide film and combusted with air on the opposite side. This process leads to a net reaction with the stoichiometry and thermodynamic properties of oxidative coupling, but without contact between the carbon atoms and oxygen species.

Borry, R.W. III [California Univ., Berkeley, CA (United States). Dept. of Chemical Engineering; Iglesia, E. [California Univ., Berkeley, CA (United States). Lawrence Berkeley Lab.

1997-12-31T23:59:59.000Z

63

NETL: Methane Hydrates - Methane Hydrate Library  

NLE Websites -- All DOE Office Websites (Extended Search)

Ridge region Ongoing areas of study in the Hydrate Ridge region Map showing where gas hydrates occur off the Cascadia Margin Locations of methane hydrate off the Cascadia Margin...

64

NETL: Methane Hydrates - Methane Hydrate Reference Shelf  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrates Primer provides background and general information about the history of hydrate R&D, the science of methane hydrates, their occurrences, and R&D related issues. Photo...

65

Why not methane--5. Delivering methane  

SciTech Connect

A discussion showed that the methane delivery system in the U.S. consists of 350,000 mi of underground high-pressure pipelines, 650,000 mi of distribution mains and connections to 45 million energy users. This delivery system now carries much less natural gas than it could carry because of the regulation-caused shortages of recent years. The delivery system is also connected to an efficient storage system of exhausted underground gas wells into which methane from any source (e.g., gasification of coal or vegetation) could be pumped and then recovered as needed. This storage system could be readily expanded and could thus be used for strategic storage of methane. Enough methane could be stored to replace foreign oil if the foreign supply should be interrupted; and methane can be quickly delivered nation-wide, whereas strategic oil storage requires unusual and expensive provisions for delivery. Natural gas usage could be increased by 20Vertical Bar3< in two years and would reduce payments for imported oil by about $10 billion. Doubling the amount of methane used in the U.S. would eliminate the need for foreign oil entirely.

Luntey, E.

1979-01-01T23:59:59.000Z

66

Methane to methanol conversion  

DOE Green Energy (OSTI)

The purpose of this project is to develop a novel process by which natural gas or methane from coal gasification products can be converted to a transportable liquid fuel. It is proposed that methanol can be produced by the direct, partial oxidation of methane utilizing air or oxygen. It is anticipated that, compared to present technologies, the new process might offer significant economic advantages with respect to capital investment and methane feedstock purity requirements. Results to date are discussed. 6 refs.

Finch, F.T.; Danen, W.C.; Lyman, J.L.; Oldenborg, R.C.; Rofer, C.K.; Ferris, M.J.

1990-01-01T23:59:59.000Z

67

Coalbed Methane Production  

Gasoline and Diesel Fuel Update (EIA)

Methane Production (Billion Cubic Feet) Period: Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes 2006 2007 2008 2009...

68

Trends Online Methane Emissions  

NLE Websites -- All DOE Office Websites (Extended Search)

Emissions Introduction Annual Estimates of Global Anthropogenic Methane Emissions: 1860-1994 - D.I. Stern and R.K. Kaufmann Contents-Trends | CDIAC Home 102001...

69

Preliminary Geospatial Analysis of Arctic Ocean Hydrocarbon Resources  

SciTech Connect

Ice coverage of the Arctic Ocean is predicted to become thinner and to cover less area with time. The combination of more ice-free waters for exploration and navigation, along with increasing demand for hydrocarbons and improvements in technologies for the discovery and exploitation of new hydrocarbon resources have focused attention on the hydrocarbon potential of the Arctic Basin and its margins. The purpose of this document is to 1) summarize results of a review of published hydrocarbon resources in the Arctic, including both conventional oil and gas and methane hydrates and 2) develop a set of digital maps of the hydrocarbon potential of the Arctic Ocean. These maps can be combined with predictions of ice-free areas to enable estimates of the likely regions and sequence of hydrocarbon production development in the Arctic. In this report, conventional oil and gas resources are explicitly linked with potential gas hydrate resources. This has not been attempted previously and is particularly powerful as the likelihood of gas production from marine gas hydrates increases. Available or planned infrastructure, such as pipelines, combined with the geospatial distribution of hydrocarbons is a very strong determinant of the temporal-spatial development of Arctic hydrocarbon resources. Significant unknowns decrease the certainty of predictions for development of hydrocarbon resources. These include: 1) Areas in the Russian Arctic that are poorly mapped, 2) Disputed ownership: primarily the Lomonosov Ridge, 3) Lack of detailed information on gas hydrate distribution, and 4) Technical risk associated with the ability to extract methane gas from gas hydrates. Logistics may control areas of exploration more than hydrocarbon potential. Accessibility, established ownership, and leasing of exploration blocks may trump quality of source rock, reservoir, and size of target. With this in mind, the main areas that are likely to be explored first are the Bering Strait and Chukchi Sea, in spite of the fact that these areas do not have highest potential for future hydrocarbon reserves. Opportunities for improving the mapping and assessment of Arctic hydrocarbon resources include: 1) Refining hydrocarbon potential on a basin-by-basin basis, 2) Developing more realistic and detailed distribution of gas hydrate, and 3) Assessing the likely future scenarios for development of infrastructure and their interaction with hydrocarbon potential. It would also be useful to develop a more sophisticated approach to merging conventional and gas hydrate resource potential that considers the technical uncertainty associated with exploitation of gas hydrate resources. Taken together, additional work in these areas could significantly improve our understanding of the exploitation of Arctic hydrocarbons as ice-free areas increase in the future.

Long, Philip E.; Wurstner, Signe K.; Sullivan, E. C.; Schaef, Herbert T.; Bradley, Donald J.

2008-10-01T23:59:59.000Z

70

Methane Hydrate Advisory Committee Charter | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Charter Methane Hydrate Advisory Committee Charter Methane Hydrate Advisory Committee Charter Methane Hydrate Advisory Committee Charter...

71

NIST: Methane Symmetry Operations - Introduction  

Science Conference Proceedings (OSTI)

Methane Symmetry Operations. ... At least three T d symmetry classification systems are widely used at present in the methane literature [5-13]. ...

72

OXIDATION OF DRY HYDROCARBONS AT HIGH-POWER DENSITY ANODES  

DOE Green Energy (OSTI)

This work builds upon discoveries by the University of Pennsylvania and others pertaining to the oxidation of dry hydrocarbon fuels in high temperature solid oxide fuel cells. The work reported here was restricted primarily to dry methane and confirms that YSZ-based cells, having ceria in the anode as a catalyst and copper in the anode as a current collector, can operate on dry methane for extended periods. Thirty-three lab-scale cells of various designs were fabricated and operated under a variety of conditions. The longest-lived cell gave stable performance on dry methane at 800 C for over 305 hours. Only slight carbon deposition was noted at the completion of the test. A corresponding nickel/YSZ-based anode would have lasted for less than an hour under these test conditions (which included open circuit potential measurements) before carbon fouling essentially destroyed the cell. The best performing cell achieved 112 mW/cm{sub 2} on dry methane at 800 C. Several problems were encountered with carbon fouling and declining open circuit voltages in many of the test cells after switching from operation on hydrogen to dry methane. Although not rigorously confirmed by experimentation, the results suggested that air infiltration through less than perfect perimeter seals or pinholes in the electrolytes, or both gave rise to conditions that caused the carbon fouling and OCV decline. Small amounts of air reacting with methane in a partial oxidation reaction could produce carbon monoxide that, in turn, would deposit the carbon. If this mechanism is confirmed, it implies that near perfect hardware is required for extended operation. Some evidence was also found for the formation of electrical shorts, probably from carbon deposits bridging the electrolyte. Work with odorized methane and with methane containing 100-ppm hydrogen sulfide confirmed that copper is stable at 800 C in dry hydrocarbon fuels in the presence of sulfur. In a number of cases, but not exclusively, the performance life on dry methane with sulfur compounds was much longer than with dry methane alone. The effect of sulfur compounds in these cases appeared to correlate with inhibition of carbon deposition. Mixed results were obtained for the effect of the sulfur compounds on power density. Progress also was made in understanding the mechanisms involved in direct utilization of dry natural gas. Evidence was developed for three possible mechanisms for dry methane utilization in addition to the usually cited mechanism--direct oxidation of methane by oxygen anions. Further work is required at a fundamental level before the knowledge gained here can be translated into higher levels of performance.

K.Krist; O. Spaldon-Stewart; R. Remick

2004-03-01T23:59:59.000Z

73

Chlorofluorocarbons  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Trace Gases » Chlorofluorocarbons Atmospheric Trace Gases » Chlorofluorocarbons Chlorofluorocarbons CFC-11 (trichlorofluoromethane - CFCl2) Advanced Global Atmospheric Gases Experiment (AGAGE, Prinn et al.) Methane, Nonmethane Hydrocarbons, Alkyl Nitrates, and Chlorinated Carbon Compounds including 3 Chlorofluorocarbons (CFC-11, CFC-12, and CFC-113) in Whole-air Samples (Blake) Globally Averaged Atmospheric CFC-11 Concentrations: Monthly and Annual Data for the Period 1975-1992 (Khalil and Rasmussen) Atmospheric CFC, CCl4, and SF6 Historical Update (Bullister) CFC-12 (dichlorodifluoromethane - CF2Cl2) Advanced Global Atmospheric Gases Experiment (AGAGE, Prinn et al.) Methane, Nonmethane Hydrocarbons, Alkyl Nitrates, and Chlorinated Carbon Compounds including 3 Chlorofluorocarbons (CFC-11, CFC-12, and

74

Hydrocarbon solubility and its migration processes: a look at the present status  

DOE Green Energy (OSTI)

In this study we review the present status of knowledge of solubility of hydrocarbons and its implications on primary migration processes. The intent is to examine the solubility and the transportation mechanisms relevant to geopressured-geothermal reservoirs, although the discussion included here accommodates a wide range of related aspects. Influences of parameters associated with hydrocarbon (especially methane) solubility have been studied. We have sought to evaluate several primary hydrocarbon migration processes and to point out their attractive features as well as their limitations. A brief discussion of hydrocarbon generation processes is also included.

Mamun, C.K.; Ohkuma, H.; Sepehrnoori, K.

1985-12-01T23:59:59.000Z

75

Methane Hydrates - Methane Hydrate Graduate Fellowship  

NLE Websites -- All DOE Office Websites (Extended Search)

Future Supply and Emerging Resources Future Supply and Emerging Resources The National Methane Hydrates R&D Program - Graduate Fellowship Program Methane Hydrate Graduate Fellowship Program Jeffrey James Marlow, a graduate student in Geobiology at the California Institute of Technology, was recently selected as the 2012 recipient of the NETL-National Academy of Sciences (NAS) Methane Hydrate Research Fellowship. Please see page 15 of the March 2013 issue (Vol. 13, Issue 1) of Fire in the Ice for more information on the recipient. The Department of Energy has a long history of building synergistic relationships with research universities. Funding academic research is a "win-win-win" situation. The U.S. government is able to tap into some of the best minds available for solving national energy problems, the universities get the support they need to maintain cutting edge faculty and laboratories, and the students involved are provided with opportunities that help them along their chosen path of study, strengthening the national pool of scientists and engineers. According to Samuel Bodman, speaking about graduate research in methane hydrates, "Students are the foundation of our energy future, bringing new ideas and fresh perspectives to the energy industry. What better way to assure technology innovation than to encourage students working on the development of a resource that has the potential to tip our energy balance toward clean-burning, domestic fuels."

76

Selective methane oxidation over promoted oxide catalysts  

DOE Green Energy (OSTI)

Principal accomplishments have been achieved in all three areas of selective catalytic oxidation of methane that have been pursued in this research project. These accomplishments are centered on the development of catalyst systems that produce high space time yields of C{sub 2} hydrocarbon products, formaldehyde, and methanol from methane/air mixtures at moderate temperatures and at ambient pressure. The accomplishments can be summarized as the following: the SO{sub 4}{sup 2{minus}}/SrO/La{sub 2}O{sub 3} catalyst developed here has been further optimized to produce 2 kg of C{sub 2} hydrocarbons/kg catalyst/hr at 550C; V{sub 2}O{sub 5}SiO{sub 2} catalysts have been prepared that produce up to 1.5 kg formaldehyde/kg catalyst/hr at 630C with CO{sub 2} selectivities; and a novel dual bed catalyst system has been designed and tested that produces over 100 g methanol/kg catalyst/hr at 600C.

Klier, K.; Herman, R.G.

1995-06-01T23:59:59.000Z

77

Methane oxidation over dual redox catalysts  

SciTech Connect

The objective of this research is to develop approaches to direct catalytic oxidation of methane over oxides that are doubly doped with transition metal ions. The desired process aims at employing a double redox mechanism, where one redox couple is utilized for activation of oxygen and another for the trapping of CH{sub 3} radicals. The methyl radicals can either recombine, giving C{sub 2} hydrocarbons, or be converted, via electron transfer reaction, to carbocations. The latter species can react with surface OH{sup {minus}} groups to form methanol or formaldehyde. To choose from several possible catalytic systems, this research initially involved the characterization of the micromorphology and crystalline dimensions of zinc oxide catalysts doped with Cu, Fe, and Sn by scanning electron microscopy. In addition, the determination of surface composition and oxidation states by X-ray photoelectron spectroscopy was carried out. A newly constructed high temperature catalytic testing system has been calibrated (flow meters and temperature controllers), tested for possible gas leaks and integrated with a gas chromatographic analytical unit. A preliminary catalytic test study over a Cu/Fe/ZnO sample was performed. The following products of the methane coupling reaction was found: C{sub 2}H{sub 6}, C{sub 2}H{sub 4} and H{sub 2}O together with CO{sub 2}. The maximum space time yield of 14 mmol C{sub 2} hydrocarbons/g cat/h was obtained at 848{degrees}C.

Klier, K.; Herman, R.G.; Sojka, Z.

1989-09-01T23:59:59.000Z

78

Process for converting light alkanes to higher hydrocarbons  

DOE Patents (OSTI)

A process is disclosed for the production of aromatic-rich, gasoline boiling range hydrocarbons from the lower alkanes, particularly from methane. The process is carried out in two stages. In the first, alkane is reacted with oxygen and hydrogen chloride over an oxyhydrochlorination catalyst such as copper chloride with minor proportions of potassium chloride and rare earth chloride. This produces an intermediate gaseous mixture containing water and chlorinated alkanes. The chlorinated alkanes are contacted with a crystalline aluminosilicate catalyst in the hydrogen or metal promoted form to produce gasoline range hydrocarbons with a high proportion of aromatics and a small percentage of light hydrocarbons (C.sub.2 -C.sub.4). The light hydrocarbons can be recycled for further processing over the oxyhydrochlorination catalyst.

Noceti, Richard P. (Pittsburgh, PA); Taylor, Charles E. (Pittsburgh, PA)

1988-01-01T23:59:59.000Z

79

Computer program for determining the thermodynamic properties of light hydrocarbons  

DOE Green Energy (OSTI)

This program was written to be used as a subroutine. The program determines the thermodynamics of light hydrocarbons. The following light hydrocarbons can be analyzed: butane, ethane, ethylene, heptane, hexane, isobutane, isopentane, methane, octane, pentane, propane and propylene. The subroutine can evaluate a thermodynamic state for the light hydrocarbons given any of the following pairs of state quantities: pressure and quality, pressure and enthalpy, pressure and entropy, temperature and pressure, temperature and quality and temperature and specific volume. These six pairs of knowns allow the user to analyze any thermodynamic cycle utilizing a light hydrocarbon as the working fluid. The Starling--Benedict--Webb--Rubin equation of state was used. A brief description, flowchart, listing and required equations for each subroutine are included.

Riemer, D.H.; Jacobs, H.R.; Boehm, R.F.; Cook, D.S.

1976-01-01T23:59:59.000Z

80

Computer program for determining the thermodynamic properties of light hydrocarbons  

DOE Green Energy (OSTI)

This program was written to be used as a subroutine. The program determines the thermodynamics of light hydrocarbons. The following light hydrocarbons can be analyzed: butane, ethane, ethylene, heptane, hexane, isobutane, isopentane, methane, octane, pentane, propane and propylene. The subroutine can evaluate a thermodynamic state for the light hydrocarbons given any of the following pairs of state quantities: pressure and quality, pressure and enthalpy, pressure and entropy, temperature and pressure, temperature and quality and temperature and specific volume. These six pairs of knowns allow the user to analyze any thermodynamic cycle utilizing a light hydrocarbon as the working fluid. The Starling-Benedict-Webb-Rubin equation of state was used. This report contains a brief description, flowchart, listing and required equations for each subroutine.

Riemer, D.H.; Jacobs, H.R.; Boehm, R.F.; Cook, D.S.

1976-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "methane nonmethane hydrocarbons" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Methane Hydrate Advisory Committee Meeting Minutes | Department...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Methane Hydrate Advisory Committee Meeting Minutes Methane Hydrate Advisory Committee Meeting Minutes Methane Hydrate Advisory Committee Meeting Minutes June 6th - 7th, 2013...

82

Methane Hydrate Program  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

FY 2011 FY 2011 Methane Hydrate Program Report to Congress July 2012 United States Department of Energy Washington, DC 20585 Department of Energy | July 2012 FY 2011 Methane Hydrate Program Report to Congress | Page ii Message from the Secretary Section 968 of the Energy Policy Act of 2005 requires the Department of Energy to submit to Congress an annual report on the results of methane hydrate research. I am pleased to submit the enclosed report entitled U.S. Department of Energy FY 2011 Methane Hydrate Program Report to Congress. The report was prepared by the Department of Energy's Office of Fossil Energy and summarizes the progress being made in this important area of research. Pursuant to statutory requirements, this report is being provided to the following

83

Methane Hydrate Annual Reports  

Energy.gov (U.S. Department of Energy (DOE))

Section 968 of the Energy Policy Act of 2005 requires the Department of Energy to submit to Congress an annual report on the results of Methane Hydrate research. Listed are the Annual Reports per...

84

Methane Hydrate Program  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Fiscal Year 2012 Fiscal Year 2012 Methane Hydrate Program Report to Congress August 2013 United States Department of Energy Washington, DC 20585 Department of Energy | August 2013 Fiscal Year 2012 Methane Hydrate Program Report to Congress | Page ii Message from the Secretary Section 968 of the Energy Policy Act of 2005 requires the Department of Energy to submit to Congress an annual report on the actions taken to carry out methane hydrate research. I am pleased to submit the enclosed report, entitled U.S. Department of Energy Fiscal Year 2012 Methane Hydrate Program Report to Congress. The report was prepared by the Department of Energy's Office of Fossil Energy and summarizes the progress being made in this important area

85

Electrochemical methane sensor  

DOE Patents (OSTI)

A method and instrument including an electrochemical cell for the detection and measurement of methane in a gas by the oxidation of methane electrochemically at a working electrode in a nonaqueous electrolyte at a voltage about 1.4 volts vs R.H.E. (the reversible hydrogen electrode potential in the same electrolyte), and the measurement of the electrical signal resulting from the electrochemical oxidation.

Zaromb, S.; Otagawa, T.; Stetter, J.R.

1984-08-27T23:59:59.000Z

86

TRENDS: METHANE EMISSIONS - INTRODUCTION  

NLE Websites -- All DOE Office Websites (Extended Search)

Of the total direct radiative forcing of long-lived greenhouse gases (2.45 Of the total direct radiative forcing of long-lived greenhouse gases (2.45 Wm-2), almost 20% is attributable to methane (CH4), according to the 1995 report of the Intergovernmental Panel on Climate Change (IPCC 1995). Since the mid-1700s, the atmospheric concentration of methane has increased by about 145% (IPCC 1995). Thus, an understanding of the various sources of methane is important. Atmospheric methane is produced both from natural sources (e.g., wetlands) and from human activities (see global methane cycle, from Professor W.S. Reeburgh at the University of California Irvine). Total sources of methane to the atmosphere for the period 1980-1990 were about 535 (range of 410-660) Tg (1 Teragram = 1 million metric tons) CH4 per year, of which 160 (110-210) Tg CH4/yr were from natural sources and 375 (300-450) Tg CH4/yr

87

Thermocatalytic CO{sub 2}-Free Production of Hydrogen from Hydrocarbon Fuels - Final Report for the Period August 1999 - September 2000  

DOE Green Energy (OSTI)

The overall objective of this work is to develop a novel process for CO{sub 2}-free production of hydrogen via thermocatalytic decomposition (pyrolysis) of hydrocarbon fuels as a viable alternative to the conventional processes of methane steam reforming or partial oxidation. The objective of Phase I work was to demonstrate the technical feasibility of CO{sub 2}-free production of hydrogen and carbon from different hydrocarbons, including methane, propane and gasoline.

Nazim Muradov, Ph.D.

2000-10-01T23:59:59.000Z

88

Methane Hydrate | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Methane Hydrate Methane Hydrate Methane Hydrate Types of Methane Hydrate Deposits Types of Methane Hydrate Deposits Methane hydrate is a cage-like lattice of ice inside of which are trapped molecules of methane, the chief constituent of natural gas. If methane hydrate is either warmed or depressurized, it will revert back to water and natural gas. When brought to the earth's surface, one cubic meter of gas hydrate releases 164 cubic meters of natural gas. Hydrate deposits may be several hundred meters thick and generally occur in two types of settings: under Arctic permafrost, and beneath the ocean floor. Methane that forms hydrate can be both biogenic, created by biological activity in sediments, and thermogenic, created by geological processes deeper within the earth.

89

Plasma-induced conversion of surface-adsorbed hydrocarbons  

DOE Green Energy (OSTI)

Experimental results are reported for an electrical device for direct conversion of methane into higher hydrocarbons. A microchannel plate is excited with electrons from a photoemissive source, and electron impact ionization of methane on the inner surfaces of the microchannels creates an ion feedback process. The resulting low-density plasma creates higher hydrocarbons when charged particles impact the surfaces at grazing incidence. The production Of C{sub 2} to C{sub 8}-containing gases was noted, with a selectivity for C{sub 2} of 39% in one case. The proportions of converted products and the conversion rates depend upon the electrical voltage, the microchannel geometry, and the operating pressure. Conversion rates increase with operating pressure.

Sackinger, W.M.

1992-07-01T23:59:59.000Z

90

Plasma-induced conversion of surface-adsorbed hydrocarbons  

DOE Green Energy (OSTI)

Experimental results are reported for an electrical device for direct conversion of methane into higher hydrocarbons. A microchannel plate is excited with electrons from a photoemissive source, and electron impact ionization of methane on the inner surfaces of the microchannels creates an ion feedback process. The resulting low-density plasma creates higher hydrocarbons when charged particles impact the surfaces at grazing incidence. The production Of C{sub 2} to C{sub 8}-containing gases was noted, with a selectivity for C{sub 2} of 39% in one case. The proportions of converted products and the conversion rates depend upon the electrical voltage, the microchannel geometry, and the operating pressure. Conversion rates increase with operating pressure.

Sackinger, W.M.

1992-01-01T23:59:59.000Z

91

NETL: Methane Hydrates - Global Assessment of Methane Gas Hydrates  

NLE Websites -- All DOE Office Websites (Extended Search)

Assessment of Methane Gas Hydrates Last Reviewed 6142013 DE-FE0003060 Goal The goal of this project is to develop a global assessment of methane gas hydrates that will facilitate...

92

Production of valuable hydrocarbons by flash pyrolysis of oil shale  

DOE Patents (OSTI)

A process for the production of gas and liquid hydrocarbons from particulated oil shale by reaction with a pyrolysis gas at a temperature of from about 700/sup 0/C to about 1100/sup 0/C, at a pressure of from about 400 psi to about 600 psi, for a period of about 0.2 second to about 20 seconds. Such a pyrolysis gas includes methane, helium, or hydrogen. 3 figs., 3 tabs.

Steinberg, M.; Fallon, P.T.

1985-04-01T23:59:59.000Z

93

Conversion of ethane and of propane to higher olefin hydrocarbons  

DOE Green Energy (OSTI)

It has become apparent during the past few months that results obtained in the oxidative coupling of methane cannot be extended to ethane and propane. Good selectivities and yields for the oxydehydrogenation to olefins can be obtained but production of higher hydrocarbons is small. The present report summarizes results of experiments using zeolite based catalysts and compares these with basic oxide catalysts. The oxydehydrogenation of ethane over zeolite based catalysts (H[sup [minus plus

Heinemann, H.; Somorjai, G.A.

1992-09-01T23:59:59.000Z

94

OPERATION OF SOLID OXIDE FUEL CELL ANODES WITH PRACTICAL HYDROCARBON FUELS  

DOE Green Energy (OSTI)

This work was carried out to achieve a better understanding of how SOFC anodes work with real fuels. The motivation was to improve the fuel flexibility of SOFC anodes, thereby allowing simplification and cost reduction of SOFC power plants. The work was based on prior results indicating that Ni-YSZ anode-supported SOFCs can be operated directly on methane and natural gas, while SOFCs with novel anode compositions can work with higher hydrocarbons. While these results were promising, more work was clearly needed to establish the feasibility of these direct-hydrocarbon SOFCs. Basic information on hydrocarbon-anode reactions should be broadly useful because reformate fuel gas can contain residual hydrocarbons, especially methane. In the Phase I project, we have studied the reaction mechanisms of various hydrocarbons--including methane, natural gas, and higher hydrocarbons--on two kinds of Ni-containing anodes: conventional Ni-YSZ anodes and a novel ceramic-based anode composition that avoid problems with coking. The effect of sulfur impurities was also studied. The program was aimed both at achieving an understanding of the interactions between real fuels and SOFC anodes, and providing enough information to establish the feasibility of operating SOFC stacks directly on hydrocarbon fuels. A combination of techniques was used to provide insight into the hydrocarbon reactions at these anodes during SOFC operation. Differentially-pumped mass spectrometry was be used for product-gas analysis both with and without cell operation. Impedance spectroscopy was used in order to understand electrochemical rate-limiting steps. Open-circuit voltages measurements under a range of conditions was used to help determine anode electrochemical reactions. Life tests over a wide range of conditions were used to establish the conditions for stable operation of anode-supported SOFC stacks directly on methane. Redox cycling was carried out on ceramic-based anodes. Tests on sulfur tolerance of Ni-YSZ anodes were carried out.

Scott A. Barnett; Jiang Liu; Yuanbo Lin

2004-07-30T23:59:59.000Z

95

The basics of coalbed methane  

Science Conference Proceedings (OSTI)

The report is an overview of coalbed methane (CBM), also known as coal seam gas. It provides an overview of what coalbed methane is and the current status of global coalbed methane exploration and production. Topics covered in the report include: An analysis of the natural gas industry, including current and future production, consumption, and reserves; A detailed description of coalbed methane, its characteristics, and future potential; An analysis of the key business factors that are driving the increased interest in coalbed methane; An analysis of the barriers that are hindering the development of coalbed methane; An overview of the technologies used for coalbed methane production and water treatment; and Profiles of key coalbed methane producing countries. 25 figs., 5 tabs., 1 app.

NONE

2006-12-15T23:59:59.000Z

96

Methane Emissions - Energy Information Administration  

U.S. Energy Information Administration (EIA)

Carbon Dioxide Equivalent; Estimated 2003 ... for about 8.7 percent of total U.S. greenhouse gas emissions when weighted by methane’s global warming potential factor.

97

Enhanced coalbed methane recovery  

SciTech Connect

The recovery of coalbed methane can be enhanced by injecting CO{sub 2} in the coal seam at supercritical conditions. Through an in situ adsorption/desorption process the displaced methane is produced and the adsorbed CO{sub 2} is permanently stored. This is called enhanced coalbed methane recovery (ECBM) and it is a technique under investigation as a possible approach to the geological storage of CO{sub 2} in a carbon dioxide capture and storage system. This work reviews the state of the art on fundamental and practical aspects of the technology and summarizes the results of ECBM field tests. These prove the feasibility of ECBM recovery and highlight substantial opportunities for interdisciplinary research at the interface between earth sciences and chemical engineering.

Mazzotti, M.; Pini, R.; Storti, G. [ETH, Zurich (Switzerland). Inst. of Process Engineering

2009-01-15T23:59:59.000Z

98

Fundamental studies of the mechanism of catalytic reactions with catalysts effective in the gasification of carbon solids and the oxidative coupling of methane. Quarterly report, April 1, 1992--June 30, 1992  

DOE Green Energy (OSTI)

Work continued on the catalytic conversion of methane to produce C{sub 2}, C{sub 3},and C{sub 4} hydrocarbons. Progress is reported on the catalytic effects of Lithium Oxide and Magnesium Oxide catalysts.

Heinemann, H.; Somorjai, G.A.; Perry, D.L.

1992-06-01T23:59:59.000Z

99

A simulated countercurrent moving-bed chromatographic reactor for the oxidative coupling of methane: Experimental results  

DOE Green Energy (OSTI)

The oxidative coupling reaction of methane (OCM) represents a potential commercial ethylene production route. However, the highest reported yields do not exceed 20%. The methane coupling reaction is accompanied by the undesired conversion of methane to carbon oxides. The relative amount of oxygen and methane along with other parameters, including temperature, determine the favored reaction pathway. High hydrocarbon to oxygen feed ratios give high ethane/ethylene selectivities but at the expense of the hydrocarbon conversion. When the methane to oxygen feed ratio is low, combustion is favored. The simulated countercurrent moving-bed chromatographic reactor (SCMCR) is applied to the OCM. A modified experimental configuration is designed and evaluated. A four-section apparatus, each containing a reaction and two separation columns, is used to quickly separate the reactants and products using the principles of simulated countercurrent flow. Simultaneous reaction and separation of the reactive products column is desired, but unattainable because of an incompatibility between OCM reaction and separation temperatures. Microreactor yields with a samarium oxide catalyst gives yields between 2% and 10%. Yields as high as 50% are observed with the same catalyst and run conditions in the SCMCR. These yields are significantly higher than previously reported values. The effects of temperature, feed switching time, and methane to oxygen feed ratio have been investigated. The reactor, while not fully optimized, does give promise as an alternative production method for ethylene.

Tonkovich, A.L.Y. [Pacific Northwest Lab., Richland, WA (United States); Carr, R.W. [Univ. of Minnesota, Minneapolis, MN (United States). Dept. of Chemical Engineering and Materials Sciences

1994-09-01T23:59:59.000Z

100

Methane emissions from natural wetlands  

SciTech Connect

Analyses of air trapped in polar ice cores in conjunction with recent atmospheric measurements, indicate that the atmospheric methane concentration increased by about 250% during the past two or three hundred years (Rasmussen and Khalil, 1984). Because methane is a potent ``greenhouse`` gas, the increasing concentrations are expected to contribute to global warning (Dickinson and Cicerone, 1986). The timing of the methane increase suggests that it is related to the rapid growth of the human population and associated industrialization and agricultural development. The specific causes of the atmospheric methane concentration increase are not well known, but may relate to either increases in methane sources, decreases in the strengths of the sinks, or both.

Meyer, J.L. [Georgia Univ., Athens, GA (United States); Burke, R.A. Jr. [Environmental Protection Agency, Athens, GA (United States). Environmental Research Lab.

1993-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "methane nonmethane hydrocarbons" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Predicting methane fermentation biodegradability  

Science Conference Proceedings (OSTI)

Estimation of the feedstock digestibility in cows by procedures developed by Van Soest was performed. By feeding cows feedstuff of different lignin content, cell wall digestibility can be estimated. In this article a digestibility model has been employed and tested along with other models for the rapid prediction of substrate methane fermentation biodegradability.

Chandler, J.A.; Jewell, W.J.; Gossett, J.M.; Van Soest, P.J.; Robertson, J.B.

1980-01-01T23:59:59.000Z

102

The landfill methane balance: Model and practical applications  

SciTech Connect

A rational mass-balance framework is described for improved quantification of landfill methane processes at a given site. The methane balance model examines the partitioning of methane generated into methane recovered (via extraction systems), methane emitted, methane oxidized, methane migrated, and methane storage. This model encourages use of field-based data to better quantify rates of methane recovery and emissions.

Bogner, J.; Spokas, K.

1995-10-01T23:59:59.000Z

103

Atmospheric Environment 39 (2005) 28292838 Diurnal and seasonal cycles of ozone precursors observed from  

E-Print Network (OSTI)

characteristics. Ethane and propane, largely originated from leakage of natural gas or liquefied petroleum gases); Non-methane hydrocarbons (NMHCs); Liquefied petroleum gases (LPG); Temperature inversion ARTICLE) and nitrogen oxides (NO+NO2 ÂĽ NOx), ozone is photochemically pro- duced and can accumulate to hazardous levels

Wingenter, Oliver W.

104

BP Oil Spill and Air Chemistry Crude oil contains various hydrocarbons  

E-Print Network (OSTI)

BP Oil Spill and Air Chemistry Crude oil contains various hydrocarbons NOAA and CIRES here at CU went to the oil spill in an aircraft that was equipped with instruments to measure the air quality. 1/3 of the oil dissolved into the water column (methane completely, benzene and ethane almost completely) Showed

Toohey, Darin W.

105

Process, including PSA and membrane separation, for separating hydrogen from hydrocarbons  

DOE Patents (OSTI)

An improved process for separating hydrogen from hydrocarbons. The process includes a pressure swing adsorption step, a compression/cooling step and a membrane separation step. The membrane step relies on achieving a methane/hydrogen selectivity of at least about 2.5 under the conditions of the process.

Baker, Richard W. (Palo Alto, CA); Lokhandwala, Kaaeid A. (Union City, CA); He, Zhenjie (Fremont, CA); Pinnau, Ingo (Palo Alto, CA)

2001-01-01T23:59:59.000Z

106

Process for the production of ethylene and other hydrocarbons from coal  

DOE Patents (OSTI)

A process is claimed for the production of substantial amounts of ethylene and other hydrocarbon compounds, such as benzene from coal. Coal is reacted with methane at a temperature in the approximate range of 500/sup 0/C to 1100/sup 0/C at a partial pressure less than about 200 psig for a period of less than 10 seconds, and preferably at a temperature of approximately 850/sup 0/C, and a partial pressure of 50 psig for a period of approximately 2 seconds. Ethylene and other hydrocarbon compounds may be separated from the product stream so produced, and the methane recycled for further production of ethylene. In another embodiment, other compounds produced, such as by-product tars, may be burned to heat the recycled methane.

Steinberg, M.; Fallon, P.

1982-02-16T23:59:59.000Z

107

Assessing the Efficacy of the Aerobic Methanotrophic Biofilter in Methane Hydrate Environments  

SciTech Connect

In October 2008 the University of California at Santa Barbara (UCSB) initiated investigations of water column methane oxidation in methane hydrate environments, through a project funded by the National Energy Technology Laboratory (NETL) entitled: assessing the efficacy of the aerobic methanotrophic biofilter in methane hydrate environments. This Final Report describes the scientific advances and discoveries made under this award as well as the importance of these discoveries in the broader context of the research area. Benthic microbial mats inhabit the sea floor in areas where reduced chemicals such as sulfide reach the more oxidizing water that overlies the sediment. We set out to investigate the role that methanotrophs play in such mats at locations where methane reaches the sea floor along with sulfide. Mats were sampled from several seep environments and multiple sets were grown in-situ at a hydrocarbon seep in the Santa Barbara Basin. Mats grown in-situ were returned to the laboratory and used to perform stable isotope probing experiments in which they were treated with 13C-enriched methane. The microbial community was analyzed, demonstrating that three or more microbial groups became enriched in methane’s carbon: methanotrophs that presumably utilize methane directly, methylotrophs that presumably consume methanol excreted by the methanotrophs, and sulfide oxidizers that presumably consume carbon dioxide released by the methanotrophs and methylotrophs. Methanotrophs reached high relative abundance in mats grown on methane, but other bacterial processes include sulfide oxidation appeared to dominate mats, indicating that methanotrophy is not a dominant process in sustaining these benthic mats, but rather a secondary function modulated by methane availability. Methane that escapes the sediment in the deep ocean typically dissolved into the overlying water where it is available to methanotrophic bacteria. We set out to better understand the efficacy of this process as a biofilter by studying the distribution of methane oxidation and disposition of methanotrophic populations in the Pacific Ocean. We investigated several environments including the basins offshore California, the continental margin off Central America, and the shallow waters around gas seeps. We succeeded in identifying the distributions of activity in these environments, identified potential physical and chemical controls on methanotrophic activity, we further revealed details about the methanotrophic communities active in these settings, and we developed new approaches to study methanotrophic communities. These findings should improve our capacity to predict the methanotrophic response in ocean waters, and further our ability to generate specific hypotheses as to the ecology and efficacy of pelagic methanotrophic communites. The discharge of methane and other hydrocarbons to Gulf of Mexico that followed the sinking of the Deepwater Horizon provided a unique opportunity to study the methanotorphic biofilter in the deep ocean environment. We set out to understand the consumption of methane and the bloom of methanotrophs resulting from this event, as a window into the regional scale release of gas hydrate under rapid warming scenarios. We found that other hydrocarbon gases, notably propane and ethane, were preferred for consumption over methane, but that methane consumption accelerated rapidly and drove the depletion of methane within a matter of months after initial release. These results revealed the identity of the responsible community, and point to the importance of the seed population in determining the rate at which a methanotrophic community is able to respond to an input of methane. Collectively, these results provide a significant advance in our understanding of the marine methanotrohic biofilter, and further provide direction and context for future investigations of this important phenomenon. This project has resulted in fourteen publications to date, with five more circulating in draft form, and several others planned.

Valentine, David

2012-09-30T23:59:59.000Z

108

Plasma Processing Of Hydrocarbon  

SciTech Connect

The Idaho National Laboratory (INL) developed several patented plasma technologies for hydrocarbon processing. The INL patents include nonthermal and thermal plasma technologies for direct natural gas to liquid conversion, upgrading low value heavy oil to synthetic light crude, and to convert refinery bottom heavy streams directly to transportation fuel products. Proof of concepts has been demonstrated with bench scale plasma processes and systems to convert heavy and light hydrocarbons to higher market value products. This paper provides an overview of three selected INL patented plasma technologies for hydrocarbon conversion or upgrade.

Grandy, Jon D; Peter C. Kong; Brent A. Detering; Larry D. Zuck

2007-05-01T23:59:59.000Z

109

Activation of methane by transition metal-substituted aluminophosphate molecular sieves  

DOE Patents (OSTI)

Aluminophosphate molecular sieves substituted with cobalt, manganese or iron and having the AlPO.sub.4 -34 or AlPO.sub.4 -5, or related AlPO.sub.4 structure activate methane starting at approximately 350.degree. C. Between 400.degree. and 500.degree. C. and at methane pressures .ltoreq.1 atmosphere the rate of methane conversion increases steadily with typical conversion efficiencies at 500.degree. C. approaching 50% and selectivity to the production of C.sub.2+ hydrocarbons approaching 100%. The activation mechanism is based on reduction of the transition metal(III) form of the molecular sieve to the transition metal(II) form with accompanying oxidative dehydrogenation of the methane. Reoxidation of the - transition metal(II) form to the transition metal(III) form can be done either chemically (e.g., using O.sub.2) or electrochemically.

Iton, Lennox E. (Downers Grove, IL); Maroni, Victor A. (Naperville, IL)

1991-01-01T23:59:59.000Z

110

Coal-bed methane potential of Vancouver Island coalfields  

SciTech Connect

Commercially attractive quantities of coal-bed methane gas on Vancouver Island, British Columbia, are indicated from recent studies by the provincial Geological Survey Branch and independent consultants. Coal mining activity began in 1847, which provides large amount of data concerning drilling, mining, quality, and reserves. Presence of methane is corroborated by documented accounts of coal mine disasters. Coal measures are part of the Upper Cretaceous Nanaimo Group, which covers approximately 800 mi{sup 2} and are divided into two subbasins. Cretaceous strata rest unconformably on predominantly volcanic basement rocks and are controlled in their distribution by paleotopography. Maximum aggregate coal thickness in the Nanaimo subbasin is 30-60 ft in the Comox subbasin, greater than 40 ft. Post-Cretaceous faulting strongly influences the area. Tertiary intrusives have effected coal quality to some extent. Sampling of coal seams is currently underway to determine levels of thermal maturation. Vitrinite reflectance ranges from 0.59 to 3.21 (R{sub o} max). The majority of coals are of high-volatile B to A bituminous rank, with local variations near Tertiary intrusions. Test-well desorption data have indicated that coals can contain as much as 380 ft{sup 3} of methane per ton of coal. Gas samples taken were pipeline quality, about 95% methane, 4.5% heavier hydrocarbons, and 0.5% carbon dioxide. A conservative estimate of in-place methane resource is 800 bcf. Plans are currently underway to construct a natural gas pipeline from the mainland to service Vancouver Island. This would provide the necessary infrastructure to make extraction of the methane resource economic.

Kenyon, C. (Ministry of Energy, Mines, Petroleum Resources, Victoria, British Columbia (Canada)); Murray, D.K. (D. Keith Murray and Associates, Inc., Golden, CO (USA))

1990-05-01T23:59:59.000Z

111

Methane conversion to methanol  

DOE Green Energy (OSTI)

The objective of this research study is to demonstrate the effectiveness of a catalytic membrane reactor for the partial oxidation of methane. The specific goals are to demonstrate that we can improve product yield, demonstrate the optimal conditions for membrane reactor operation, determine the transport properties of the membrane, and provide demonstration of the process at the pilot plant scale. The last goal will be performed by Unocal, Inc., our industrial partner, upon successful completion of this study.

Noble, R.D.; Falconer, J.L.

1992-06-01T23:59:59.000Z

112

Coal Bed Methane Primer  

SciTech Connect

During the second half of the 1990's Coal Bed Methane (CBM) production increased dramatically nationwide to represent a significant new source of income and natural gas for many independent and established producers. Matching these soaring production rates during this period was a heightened public awareness of environmental concerns. These concerns left unexplained and under-addressed have created a significant growth in public involvement generating literally thousands of unfocused project comments for various regional NEPA efforts resulting in the delayed development of public and fee lands. The accelerating interest in CBM development coupled to the growth in public involvement has prompted the conceptualization of this project for the development of a CBM Primer. The Primer is designed to serve as a summary document, which introduces and encapsulates information pertinent to the development of Coal Bed Methane (CBM), including focused discussions of coal deposits, methane as a natural formed gas, split mineral estates, development techniques, operational issues, producing methods, applicable regulatory frameworks, land and resource management, mitigation measures, preparation of project plans, data availability, Indian Trust issues and relevant environmental technologies. An important aspect of gaining access to federal, state, tribal, or fee lands involves education of a broad array of stakeholders, including land and mineral owners, regulators, conservationists, tribal governments, special interest groups, and numerous others that could be impacted by the development of coal bed methane. Perhaps the most crucial aspect of successfully developing CBM resources is stakeholder education. Currently, an inconsistent picture of CBM exists. There is a significant lack of understanding on the parts of nearly all stakeholders, including industry, government, special interest groups, and land owners. It is envisioned the Primer would being used by a variety of stakeholders to present a consistent and complete synopsis of the key issues involved with CBM. In light of the numerous CBM NEPA documents under development this Primer could be used to support various public scoping meetings and required public hearings throughout the Western States in the coming years.

Dan Arthur; Bruce Langhus; Jon Seekins

2005-05-25T23:59:59.000Z

113

Characterization and analysis of Devonian shales as related to release of gaseous hydrocarbons. Well R-109, Washington County, Ohio  

DOE Green Energy (OSTI)

Coring of Well R-109 (Washington County, Ohio) was accomplished in August 1976. A total of 25 samples were collected. Hydrocarbon gas analyses indicate that higher chain hydrocarbon gases (C/sub 2/-C/sub 5/) make up a significant portion of total hydrocarbons in the shales, but methane is still the dominant single gas. Distinct relationships exist between the carbon and hydrocarbon gas contents, showing increase in hydrocarbon gas contents with increasing carbon. Similar relationships between hydrogen and hydrocarbon gas contents exist, though they are not as pronounced. Gas contents appear not to be related to the bulk densities in any quantitative manner, though organic contents (carbon and hydrogen) seem to be related to bulk density values much more clearly. R-109 shales are virtually impermeable to gases and other fluids, as attempted helium gas permeability measurements indicated extremely small (< 10/sup -12/ Darcy) permeability values.

Kalyoncu, R.S.; Boyer, J.P.; Snyder, M.J.

1979-06-20T23:59:59.000Z

114

Methane/nitrogen separation process  

DOE Patents (OSTI)

A membrane separation process for treating a gas stream containing methane and nitrogen, for example, natural gas. The separation process works by preferentially permeating methane and rejecting nitrogen. We have found that the process is able to meet natural gas pipeline specifications for nitrogen, with acceptably small methane loss, so long as the membrane can exhibit a methane/nitrogen selectivity of about 4, 5 or more. This selectivity can be achieved with some rubbery and super-glassy membranes at low temperatures. The process can also be used for separating ethylene from nitrogen.

Baker, Richard W. (Palo Alto, CA); Lokhandwala, Kaaeid A. (Menlo Park, CA); Pinnau, Ingo (Palo Alto, CA); Segelke, Scott (Mountain View, CA)

1997-01-01T23:59:59.000Z

115

Methane/nitrogen separation process  

DOE Patents (OSTI)

A membrane separation process is described for treating a gas stream containing methane and nitrogen, for example, natural gas. The separation process works by preferentially permeating methane and rejecting nitrogen. The authors have found that the process is able to meet natural gas pipeline specifications for nitrogen, with acceptably small methane loss, so long as the membrane can exhibit a methane/nitrogen selectivity of about 4, 5 or more. This selectivity can be achieved with some rubbery and super-glassy membranes at low temperatures. The process can also be used for separating ethylene from nitrogen. 11 figs.

Baker, R.W.; Lokhandwala, K.A.; Pinnau, I.; Segelke, S.

1997-09-23T23:59:59.000Z

116

NETL: Methane Hydrates - Interagency Coordination  

NLE Websites -- All DOE Office Websites (Extended Search)

Links to interagency pdf. The multi-faceted issues associated with naturally occurring methane hydrates demand a coordinated approach to studying (1) the potential of this resource...

117

Biomimetic methane oxidation. Final report, October 1, 1989--June 1, 1995  

DOE Green Energy (OSTI)

Transportation fuels are a critical energy commodity and they impact nearly every sector of this country. The need for transportation fuels is projected well into the next century. Consequently, there is a strong emphasis on the economical conversion of other domestic fossil energy resources to liquid hydrocarbons that can be used as transportation fuels. Natural gas is currently a readily available resource that has a positive future outlook considering its known and anticipated reserves. There is intense government and industrial interest in developing economic technologies to convert natural gas to liquid fuels. Methane, CH{sub 4}, is the primary hydrocarbon (85-95%) in natural gas. This document covers the following: production soluable of methane monooxygenase; production of particulate methane monooxygenase; production of methane monooxygenase in continuous culture; subunit resolution for active site identification of methylosinus trichosporium OB3b soluble methane monooxygenase; the synthesis and characterization of new copper coordination complexes contairing the asymmetric coordinating chelate ligand application to enzyme active site modeling; the synthesis and characterization of new iron coordination complexes utilizing an asymmetric coordinating chelate ligand; further characterization of new bionuclear iron complexes.

Watkins, B.E.; Satcher, J.H. Jr.; Droege, M.W.; Taylor, R.T.

1995-07-01T23:59:59.000Z

118

Direct conversion of methane to C sub 2 's and liquid fuels  

DOE Green Energy (OSTI)

Objectives of the project are to discover and evaluate novel catalytic systems for the conversion of methane or by-product light hydrocarbon gases either indirectly (through intermediate light gases rich in C{sub 2}'s) or directly to liquid hydrocarbon fuels, and to evaluate, from an engineering perspective, different conceptualized schemes. The approach is to carry out catalyst testing on several specific classes of potential catalysts for the conversion of methane selectively to C{sub 2} products. Promoted metal oxide catalysts were tested. Several of these exhibited similar high ethylene to ethane ratios and low carbon dioxide to carbon monoxide ratios observed for the NaCl/{alpha}-alumina catalyst system reported earlier. Research on catalysts containing potentially activated metals began with testing of metal molecular sieves. Silver catalysts were shown to be promising as low temperature catalysts. Perovskites were tested as potential methane coupling catalysts. A layered perovskite (K{sub 2}La{sub 2}Ti{sub 3}O{sub 10}) gave the highest C{sub 2} yield. Work continued on the economic evaluation of a hypothetical process converting methane to ethylene. An engineering model of the methane coupling system has been prepared. 47 refs., 17 figs., 57 tabs.

Warren, B.K.; Campbell, K.D.

1989-11-22T23:59:59.000Z

119

New Materials Make Methane Capture Possible  

Science Conference Proceedings (OSTI)

May 8, 2013... SBN, captured enough medium source methane to turn it to high purity methane, which in turn could be used to generate efficient electricity.

120

Enhanced Renewable Methane Production System | Argonne National...  

NLE Websites -- All DOE Office Websites (Extended Search)

Enhanced Renewable Methane Production System Technology available for licensing: Enhanced renewable methane production system provides a low-cost process that accelerates...

Note: This page contains sample records for the topic "methane nonmethane hydrocarbons" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Florida Coalbed Methane Production (Billion Cubic Feet)  

Annual Energy Outlook 2012 (EIA)

data. Release Date: 812013 Next Release Date: 812014 Referring Pages: Coalbed Methane Estimated Production Florida Coalbed Methane Proved Reserves, Reserves Changes, and...

122

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

with sampling and observation from the surface ship. Activities included collection of methane hydrate, sediment, water, and other materials from methane hydrate and seep sites...

123

NIST: Methane Symmetry Operations - Td Symmetry Species  

Science Conference Proceedings (OSTI)

Table of Contents Methane Symmetry Operations. 11. ... Magnetic-dipole transitions are observed in molecular-beam studies of methane [42]. ...

124

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

represent components of dynamic biogeochemical environments with inputs and outputs of methane, accurate rates of biological methane production are poorly understood. Recent...

125

Michigan Coalbed Methane Production (Billion Cubic Feet)  

Gasoline and Diesel Fuel Update (EIA)

data. Release Date: 812013 Next Release Date: 812014 Referring Pages: Coalbed Methane Estimated Production Michigan Coalbed Methane Proved Reserves, Reserves Changes, and...

126

Kentucky Coalbed Methane Production (Billion Cubic Feet)  

Gasoline and Diesel Fuel Update (EIA)

data. Release Date: 812013 Next Release Date: 812014 Referring Pages: Coalbed Methane Estimated Production Kentucky Coalbed Methane Proved Reserves, Reserves Changes, and...

127

MethaneHydrateRD_FC.indd  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Academies 2010 One of these is methane hydrate - molecules of natural gas trapped in ice crystals. Containing vast amounts of natural gas, methane hydrate occurs in a variety...

128

Novel catalysts for methane activation. Quarterly report No. 12, July 1, 1995--September 30, 1995  

DOE Green Energy (OSTI)

Fullerenes are a recently discovered allotrope of carbon that possess unusual properties, some of which may be ideal for methane activation. This project is designed to evaluate these carbon-based materials for conversion of methane into higher hydrocarbons. The project is divided into three technical tasks. Task 1 deals with synthesis and characterization of the fullerenes and fullerene soots, Task 2 with testing of the catalysts, and Task 3 with evaluation of the results and technical reporting. Due to money constraints we have not done any technical work during this period. However, we hope to continue our work and produce a final report including recommendations for future research when funds are available.

Hirschon, A.S.; Du, Y.; Wu, H.J. [and others

1995-12-01T23:59:59.000Z

129

Hydrocarbon adsorption system  

SciTech Connect

In a solid adsorbent hydrocarbon recovery system for processing natural gas, towers adapted for performing adsorbing, cooling, and regenerating functions are used. It is recommended that a regeneration gas be used of substantially uniform richness in hydrocarbons in the closed-cycle regeneration system. The natural gas stream is flowed through an adsorbent bed to remove liquid hydrocarbons. A portion of the stripped gas stream is flowed through a second adsorbent bed for cooling purposes. A heated, rich, regeneration gas is circulated through a closed-cycle regeneration system that includes a third adsorbent bed. This rich regeneration gas is combined with the stripped gas stream. These steps are repeated in a cyclic operation. (10 claims)

Humphries, C.L.

1966-11-29T23:59:59.000Z

130

Coal mine methane global review  

Science Conference Proceedings (OSTI)

This is the second edition of the Coal Mine Methane Global Overview, updated in the summer of 2008. This document contains individual, comprehensive profiles that characterize the coal and coal mine methane sectors of 33 countries - 22 methane to market partners and an additional 11 coal-producing nations. The executive summary provides summary tables that include statistics on coal reserves, coal production, methane emissions, and CMM projects activity. An International Coal Mine Methane Projects Database accompanies this overview. It contains more detailed and comprehensive information on over two hundred CMM recovery and utilization projects around the world. Project information in the database is updated regularly. This document will be updated annually. Suggestions for updates and revisions can be submitted to the Administrative Support Group and will be incorporate into the document as appropriate.

NONE

2008-07-01T23:59:59.000Z

131

Hydrocarbon/Total Combustibles Sensor  

the invention is an electrochemical hydrocarbon sensor that is more reliable and reproducible than any other hydrocarbon sensor on the market today. The patented method for producing the sensor ensures reproducibility and reduces the need for ...

132

Adsorption of binary hydrocarbon mixtures in carbon slit pores: A density functional theory study  

SciTech Connect

Adsorption of binary hydrocarbons mixtures involving methane in carbon slit pores is theoretically studied here from the viewpoints of separation and of the effect of impurities on methane storage. It is seen that even small amounts of ethane, propane, or butane can significantly reduce the methane capacity of carbons. Optimal pore sizes and pressures, depending on impurity concentration, are noted in the present work, suggesting that careful adsorbent and process design can lead to enhanced separation. These results are consistent with earlier literature studies for the infinite dilution limit. For methane storage applications a carbon micropore width of 11.4 {angstrom} (based on distance between centers of carbon atoms on opposing walls) is found to be the most suitable from the point of view of lower impurity uptake during high-pressure adsorption and greater impurity retention during low-pressure delivery. The results also theoretically confirm unusual recently reported observations of enhanced methane adsorption in the presence of a small amount of heavier hydrocarbon impurity.

Bhatia, S.K. [Univ. of Queensland, Brisbane, Queensland (Australia). Dept. of Chemical Engineering

1998-10-13T23:59:59.000Z

133

Dispersant solutions for dispersing hydrocarbons  

DOE Patents (OSTI)

A dispersant solution includes a hydrocarbon dispersing solution derived from a bacterium from ATCC 75527, ATCC 75529, or ATCC 55638.

Tyndall, Richard L. (Clinton, TN)

1997-01-01T23:59:59.000Z

134

Catalysts for hydrocarbon conversion  

Science Conference Proceedings (OSTI)

Catalyst, particularly useful in catalytic reforming and for producing highly pure aromatic hydrocarbons, comprising an alumina carrier and containing, expressed in proportion of the weight of the alumina carrier: 005 to 1% of platinum 01 to 4% of gallium, indium or thallium 01 to 2% of tungsten, and 1 to 10% of halogen.

Le P. J.; Malmaison, R.; Marcilly, C.; Martino, G.; Miquel, J.

1980-08-12T23:59:59.000Z

135

Methane coupling by membrane reactor. Quarterly technical progress report, December 25, 1994--March 24, 1995  

DOE Green Energy (OSTI)

Research efforts during this quarter concentrated on two issues. The first issue is related to the chemistry of oxygen conducting materials that could be used as dense membranes in the membrane reactors. Mixed oxides of La, Sr, Fe, Ce, Yb etc., were synthesized, characterized and studied for their catalytic activity towards the oxidative coupling of methane. Heavy metal oxides of lanthanum, strontium and iron, which form good oxygen conductors, showed very poor methane coupling activity. Perovskites of the Strontium-Cerium-Yitribium series showed moderate activity for methane coupling. These could be potential candidates for dense membrane synthesis, since they also have moderate oxygen conduction properties. The second area of research focus was the development of a radial flow catalytic membrane reactor in which methane coupling was carried out over a catalyst that was deposited inside the pores of a ceramic porous membrane. Catalytic results from the high temperature oxidative coupling of methane in these radial flow membrane reactors are presented in this report. By exploring the reactor performance in membranes of pore diameters of 2.0{mu}m, 0.2{mu}m, and 0.02{mu}m, the effect of the diffusional regime on the methane. coupling activity was demonstrated. The smallest pore diameter membranes exhibited lowest hydrocarbon selectivities.

Ma, Hua Yi

1995-06-06T23:59:59.000Z

136

Methane coupling by membrane reactor. Quarterly technical progress report, March 25, 1995--June 24, 1995  

DOE Green Energy (OSTI)

Research focus, for the development of a radial flow catalytic membrane reactor for studying methane coupling concentrated on understanding the effects of pore size on improving the hydrocarbon selectivity for the reaction. The effect of pressure on the reaction was also investigated. Experimental results from the catalytic studies of oxidative coupling of methane in the radial flow membrane reactors presented in this report augment earlier work on membranes of pore diameters of 2.0{mu}m, 0.2{mu}m, and 0.02{mu}m, indicating better performance with the larger pore diameter membranes. Higher operating pressures seem to enhance gas phase non-selective reactions during methane coupling. The chemistry of oxygen conducting materials that could be used as dense membranes in the membrane reactors was investigated by studying the catalytic activity of several oxygen conducting perovskites for methane coupling. Heavy metal oxides of lanthanum, strontium and iron, which form good oxygen conductors, showed very poor methane coupling activity. Perovskites of the Strontium-Cerium-Yttribium series showed moderate activity for methane coupling. These could serve as candidates for dense membrane synthesis, since they also have moderate oxygen conduction properties.

Yi Hua Ma

1995-10-11T23:59:59.000Z

137

NETL: Methane Hydrates - DOE/NETL Projects - Controls On Methane...  

NLE Websites -- All DOE Office Websites (Extended Search)

On Methane Expulsion During Melting Of Natural Gas Hydrate Systems Last Reviewed 6242013 DE-FE0010406 Goal The project goal is to predict, given characteristic climate-induced...

138

Reducing Open Cell Landfill Methane Emissions with a Bioactive Alternative Daily  

Science Conference Proceedings (OSTI)

Methane and carbon dioxide are formed in landfills as wastes degrade. Molecule-for-molecule, methane is about 20 times more potent than carbon dioxide at trapping heat in the earth's atmosphere, and thus, it is the methane emissions from landfills that are scrutinized. For example, if emissions composed of 60% methane and 40% carbon dioxide were changed to a mix that was 40% methane and 60% carbon dioxide, a 30% reduction in the landfill's global warming potential would result. A 10% methane, 90% carbon dioxide ratio will result in a 75% reduction in global warming potential compared to the baseline. Gas collection from a closed landfill can reduce emissions, and it is sometimes combined with a biocover, an engineered system where methane oxidizing bacteria living in a medium such as compost, convert landfill methane to carbon dioxide and water. Although methane oxidizing bacteria merely convert one greenhouse gas (methane) to another (carbon dioxide), this conversion can offer significant reductions in the overall greenhouse gas contribution, or global warming potential, associated with the landfill. What has not been addressed to date is the fact that methane can also escape from a landfill when the active cell is being filled with waste. Federal regulations require that newly deposited solid waste to be covered daily with a 6 in layer of soil or an alternative daily cover (ADC), such as a canvas tarp. The aim of this study was to assess the feasibility of immobilizing methane oxidizing bacteria into a tarp-like matrix that could be used for alternative daily cover at open landfill cells to prevent methane emissions. A unique method of isolating methanotrophs from landfill cover soil was used to create a liquid culture of mixed methanotrophs. A variety of prospective immobilization techniques were used to affix the bacteria in a tarp-like matrix. Both gel encapsulation of methanotrophs and gels with liquid cores containing methanotrophs were readily made but prone to rapid desiccation. Bacterial adsorption onto foam padding, natural sponge, and geotextile was successful. The most important factor for success appeared to be water holding capacity. Prototype biotarps made with geotextiles plus adsorbed methane oxidizing bacteria were tested for their responses to temperature, intermittent starvation, and washing (to simulate rainfall). The prototypes were mesophilic, and methane oxidation activity remained strong after one cycle of starvation but then declined with repeated cycles. Many of the cells detached with vigorous washing, but at least 30% appeared resistant to sloughing. While laboratory landfill simulations showed that four-layer composite biotarps made with two different types of geotextile could remove up to 50% of influent methane introduced at a flux rate of 22 g m{sup -2} d{sup -1}, field experiments did not yield high activity levels. Tests revealed that there were high hour-to-hour flux variations in the field, which, together with frequent rainfall events, confounded the field testing. Overall, the findings suggest that a methanotroph embedded biotarp appears to be a feasible strategy to mitigate methane emission from landfill cells, although the performance of field-tested biotarps was not robust here. Tarps will likely be best suited for spring and summer use, although the methane oxidizer population may be able to shift and adapt to lower temperatures. The starvation cycling of the tarp may require the capacity for intermittent reinoculation of the cells, although it is also possible that a subpopulation will adapt to the cycling and become dominant. Rainfall is not expected to be a major factor, because a baseline biofilm will be present to repopulate the tarp. If strong performance can be achieved and documented, the biotarp concept could be extended to include interception of other compounds beyond methane, such as volatile aromatic hydrocarbons and chlorinated solvents.

Helene Hilger; James Oliver; Jean Bogner; David Jones

2009-03-31T23:59:59.000Z

139

Methane Hydrate Advisory Committee Meeting Minutes, June 6th...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Methane Hydrate Advisory Committee Meeting Minutes, June 6th-7th, 2013 Methane Hydrate Advisory Committee Meeting Minutes, June 6th-7th, 2013 Methane Hydrate Advisory Committee...

140

Methane Hydrate Research and Development Act of 2000 | Department...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Research and Development Act of 2000 Methane Hydrate Research and Development Act of 2000 Methane Hydrate Research and Development Act of 2000 Methane Hydrate Research and...

Note: This page contains sample records for the topic "methane nonmethane hydrocarbons" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Methane Hydrate Advisory Committee Meeting Minutes, January 2010...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

January 2010 Methane Hydrate Advisory Committee Meeting Minutes, January 2010 Methane Hydrate Advisory Committee Meeting Minutes January, 2010 Atlanta, GA Methane Hydrate Advisory...

142

Department of Energy Advance Methane Hydrates Science and Technology...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Advance Methane Hydrates Science and Technology Projects Department of Energy Advance Methane Hydrates Science and Technology Projects Descriptions for Energy Department Methane...

143

Methane Hydrate Advisory Committee Meeting Minutes, March 2010...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

March 2010 Methane Hydrate Advisory Committee Meeting Minutes, March 2010 Methane Hydrate Advisory Committee Meeting Minutes March 2010 Washington, DC Methane Hydrate Advisory...

144

NETL: Methane Hydrates - Hydrate Newsletter  

NLE Websites -- All DOE Office Websites (Extended Search)

Methane Hydrate R&D Program Newsletter Methane Hydrate R&D Program Newsletter An image of a hydrate burning overlayed with the Newsletter Title: Fire in the Ice The methane hydrate newsletter, Fire in the Ice, is a bi-annual publication highlighting the latest developments in international gas hydrates R&D. Fire in the Ice promotes the exchange of information amoung those involved in gas hydrates research and development, and also recognizes the efforts of a hydrate researcher in each issue. The newsletter now reaches nearly 1300 scientists and other interested individuals in sixteen countries. To subscribe electronically to Fire in the Ice please send an email to karl.lang@contr.netl.doe.gov Please click on the links below to access issues of "Fire in the Ice". More on Methane Hydrates

145

Methane Credit | Open Energy Information  

Open Energy Info (EERE)

Methane Credit Methane Credit Jump to: navigation, search Name Methane Credit Place Charlotte, North Carolina Zip 28273 Product Specialises in utilising methane produced on municipal landfill sites. Coordinates 35.2225°, -80.837539° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":35.2225,"lon":-80.837539,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

146

Hydrocarbon reclaimer system  

SciTech Connect

This patent describes a filtering process for filtering sludge from a finished product oil storage tank and thereby separating solids from oil and hydrocarbon. The process requires no added water, solvents or diluents. It comprises: pumping a volume sludge from a finished product oil storage tank to a mixing tank; mixing the sludge; sampling the sludge to determine solid content; adding filter aid comprising diatomaceous earth to the mixing tank; mixing the filter aid with the sludge in the mixing tank; enclosing and sealing a plurality of filter plates inside a horizontal plate filter; pressurizing the horizontal plate filter by operation of pump means; pumping the sludge from the mixing tank through the horizontal plate filter to filter out solids; recirculating the sludge from the horizontal plate filter back through the mixing tank; and pumping a purified hydrocarbon and water filtrate from the horizontal plate filter.

Uremovich, M.J.

1990-09-04T23:59:59.000Z

147

FROZEN HYDROCARBONS IN COMETS  

SciTech Connect

Recent investigations of the luminescence of frozen hydrocarbon particles of icy cometary halos have been carried out. The process of luminescence of organic icy particles in a short-wavelength solar radiation field is considered. A comparative analysis of observed and laboratory data leads to 72 luminescent emission lines in the spectrum of the comet 153P/Ikeya-Zhang. The concept of cometary relict matter is presented, and the creation of a database of unidentified cometary emission lines is proposed.

Simonia, Irakli, E-mail: irakli.simonia@jcu.edu.au [School of Graduate Studies, Ilia State University, 3/5 Cholokashvili Street, Tbilisi, 0162 (Georgia); Center for Astronomy, James Cook University, Townsville QLD 4811 (Australia)

2011-02-15T23:59:59.000Z

148

THERMOCHEMISTRY OF HYDROCARBON RADICALS  

DOE Green Energy (OSTI)

Gas phase negative ion chemistry methods are employed to determine enthalpies of formation of hydrocarbon radicals that are important in combustion processes and to investigate the dynamics of ion-molecule reactions. Using guided ion beam tandem mass spectrometry, we measure collisional threshold energies of endoergic proton transfer and hydrogen atom transfer reactions of hydrocarbon molecules with negative reagent ions. The measured reaction threshold energies for proton transfer yield the relative gas phase acidities. In an alternative methodology, competitive collision-induced dissociation of proton-bound ion-molecule complexes provides accurate gas phase acidities relative to a reference acid. Combined with the electron affinity of the R {center_dot} radical, the gas phase acidity yields the RH bond dissociation energy of the corresponding neutral molecule, or equivalently the enthalpy of formation of the R{center_dot} organic radical, using equation: D(R-H) = {Delta}{sub acid}H(RH) + EA(R) - IE(H). The threshold energy for hydrogen abstraction from a hydrocarbon molecule yields its hydrogen atom affinity relative to the reagent anion, providing the RH bond dissociation energy directly. Electronic structure calculations are used to evaluate the possibility of potential energy barriers or dynamical constrictions along the reaction path, and as input for RRKM and phase space theory calculations. In newer experiments, we have measured the product velocity distributions to obtain additional information on the energetics and dynamics of the reactions.

Kent M. Ervin, Principal Investigator

2004-08-17T23:59:59.000Z

149

Surface detection of free hydrocarbon microseepage from subsurface petroleum accumulation: case study  

SciTech Connect

In January 1979, Pemex began a 2-yr test project designed to evaluate the surface detection of free hydrocarbon microseepage as an integrated exploration tool. The tests were performed by analyzing samples collected over fields selected to represent various hydrocarbon entrapment conditions. The structure selected is a lenticular anticline that produces oil from an Austin equivalent at 2500 m and dry gas from the Jurassic at approximately 3500 m. The 350 surface samples definitely indicate that methane is seeping into the near-surface sediments and forming a distinct anomaly directly above the 2 superimposed reservoirs. Apparently, only the methane is able to migrate through the stratigraphic section, and the heavier components, if they were able to escape from the Cretaceous reservoir, have been stripped and retained by the sediments. The surface anomaly appears to contain elements of both a circular halo and a centralized anomaly that overlies the apex of the producing structure.

Brown, S.W.; Salce, J.

1981-05-01T23:59:59.000Z

150

OXIDATIVE COUPLING OF METHANE USING INORGANIC MEMBRANE REACTORS  

Science Conference Proceedings (OSTI)

The objective of this research is to study the oxidative coupling of methane in catalytic inorganic membrane reactors. A specific target is to achieve conversion of methane to C{sub 2} hydrocarbons at very high selectivity and higher yields than in conventional non-porous, co-feed, fixed bed reactors by controlling the oxygen supply through the membrane. A membrane reactor has the advantage of precisely controlling the rate of delivery of oxygen to the catalyst. This facility permits balancing the rate of oxidation and reduction of the catalyst. In addition, membrane reactors minimize the concentration of gas phase oxygen thus reducing non selective gas phase reactions, which are believed to be a main route for the formation of CO{sub x} products. Such gas phase reactions are a cause of decreased selectivity in the oxidative coupling of methane in conventional flow reactors. Membrane reactors could also produce higher product yields by providing better distribution of the reactant gases over the catalyst than the conventional plug flow reactors. Membrane reactor technology also offers the potential for modifying the membranes both to improve catalytic properties as well as to regulate the rate of the permeation/diffusion of reactants through the membrane to minimize by-product generation. Other benefits also exist with membrane reactors, such as the mitigation of thermal hot-spots for highly exothermic reactions such as the oxidative coupling of methane. The application of catalytically active inorganic membranes has potential for drastically increasing the yield of reactions which are currently limited by either thermodynamic equilibria, product inhibition, or kinetic selectivity.

Dr. Y.H. Ma; Dr. W.R. Moser; Dr. A.G. Dixon; Dr. A.M. Ramachandra; Dr. Y. Lu; C. Binkerd

1998-04-01T23:59:59.000Z

151

Coalbed Methane Proved Reserves  

Gasoline and Diesel Fuel Update (EIA)

Coalbed Methane Proved Reserves (Billion Cubic Feet) Period: Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes 2003 2004 2005 2006 2007 2008 View History U.S. 18,743 18,390 19,892 19,620 21,874 20,798 1989-2008 Alabama 1,665 1,900 1,773 2,068 2,126 1,727 1989-2008 Alaska 0 0 2007-2008 Arkansas 31 31 2007-2008 California 0 0 2007-2008 Colorado 6,473 5,787 6,772 6,344 7,869 8,238 1989-2008 Florida 0 0 2007-2008 Kansas 340 301 2007-2008 Kentucky 0 0 2007-2008 Louisiana 7 9 2007-2008 North 7 9 2007-2008 South Onshore 0 0 2007-2008 South Offshore 0 0 2007-2008 Michigan 0 0 2007-2008 Mississippi 0 0 2007-2008 Montana 66 75 2007-2008 New Mexico 4,396 5,166 5,249 4,894 4,169 3,991 1989-2008

152

Method for simultaneous recovery of hydrogen from water and from hydrocarbons  

DOE Patents (OSTI)

Method for simultaneous recovery of hydrogen and hydrogen isotopes from water and from hydrocarbons. A palladium membrane, when utilized in cooperation with a nickel catalyst in a reactor, has been found to drive reactions such as water gas shift, steam reforming and methane cracking to substantial completion by removing the product hydrogen from the reacting mixture. In addition, ultrapure hydrogen is produced, thereby eliminating the need for an additional processing step.

Willms, R. Scott (Los Alamos, NM)

1996-01-01T23:59:59.000Z

153

Characterization of Methane Degradation and Methane-Degrading Microbes in Alaska Coastal Water  

SciTech Connect

The net flux of methane from methane hydrates and other sources to the atmosphere depends on methane degradation as well as methane production and release from geological sources. The goal of this project was to examine methane-degrading archaea and organic carbon oxidizing bacteria in methane-rich and methane-poor sediments of the Beaufort Sea, Alaska. The Beaufort Sea system was sampled as part of a multi-disciplinary expedition (â??Methane in the Arctic Shelfâ?ť or MIDAS) in September 2009. Microbial communities were examined by quantitative PCR analyses of 16S rRNA genes and key methane degradation genes (pmoA and mcrA involved in aerobic and anaerobic methane degradation, respectively), tag pyrosequencing of 16S rRNA genes to determine the taxonomic make up of microbes in these sediments, and sequencing of all microbial genes (â??metagenomesâ?ť). The taxonomic and functional make-up of the microbial communities varied with methane concentrations, with some data suggesting higher abundances of potential methane-oxidizing archaea in methane-rich sediments. Sequence analysis of PCR amplicons revealed that most of the mcrA genes were from the ANME-2 group of methane oxidizers. According to metagenomic data, genes involved in methane degradation and other degradation pathways changed with sediment depth along with sulfate and methane concentrations. Most importantly, sulfate reduction genes decreased with depth while the anaerobic methane degradation gene (mcrA) increased along with methane concentrations. The number of potential methane degradation genes (mcrA) was low and inconsistent with other data indicating the large impact of methane on these sediments. The data can be reconciled if a small number of potential methane-oxidizing archaea mediates a large flux of carbon in these sediments. Our study is the first to report metagenomic data from sediments dominated by ANME-2 archaea and is one of the few to examine the entire microbial assemblage potentially involved in anaerobic methane oxidation.

David Kirchman

2011-12-31T23:59:59.000Z

154

NETL: Methane Hydrates - Global Assessment of Methane Gas Hydrates  

NLE Websites -- All DOE Office Websites (Extended Search)

Global Assessment of Methane Gas Hydrates Last Reviewed 12/18/2013 Global Assessment of Methane Gas Hydrates Last Reviewed 12/18/2013 DE-FE0003060 Goal The goal of this project is to develop a global assessment of methane gas hydrates that will facilitate informed decision-making regarding the potential development of gas hydrate resources between the scientific community and other stakeholders/decision makers. The Assessment will provide science-based information on the role of gas hydrates in natural climate change and the carbon cycle, their sensitivity to climate change, and the potential environmental and socio-economic impacts of hydrate production. Performers Stiftelsen GRID-Arendal, Arendal, Norway Funding Institutions United Nations Environment Programme (UNEP) Statoil Schlumberger United States Department of Energy (USDOE)

155

Using Ionic Liquids in Selective Hydrocarbon Conversion Processes  

DOE Green Energy (OSTI)

This is the Final Report of the five-year project Using Ionic Liquids in Selective Hydrocarbon Conversion Processes (DE-FC36-04GO14276, July 1, 2004- June 30, 2009), in which we present our major accomplishments with detailed descriptions of our experimental and theoretical efforts. Upon the successful conduction of this project, we have followed our proposed breakdown work structure completing most of the technical tasks. Finally, we have developed and demonstrated several optimized homogenously catalytic methane conversion systems involving applications of novel ionic liquids, which present much more superior performance than the Catalytica system (the best-to-date system) in terms of three times higher reaction rates and longer catalysts lifetime and much stronger resistance to water deactivation. We have developed in-depth mechanistic understandings on the complicated chemistry involved in homogenously catalytic methane oxidation as well as developed the unique yet effective experimental protocols (reactors, analytical tools and screening methodologies) for achieving a highly efficient yet economically feasible and environmentally friendly catalytic methane conversion system. The most important findings have been published, patented as well as reported to DOE in this Final Report and our 20 Quarterly Reports.

Tang, Yongchun; Periana, Roy; Chen, Weiqun; van Duin, Adri; Nielsen, Robert; Shuler, Patrick; Ma, Qisheng; Blanco, Mario; Li, Zaiwei; Oxgaard, Jonas; Cheng, Jihong; Cheung, Sam; Pudar, Sanja

2009-09-28T23:59:59.000Z

156

HYDROCARBON LIQUID FLOW CALIBRATION SERVICE ...  

Science Conference Proceedings (OSTI)

... and is the cross correlation coefficient ... a NIST Hydrocarbon Liquid Flow Calibration Facility ... FED2004-56790, 2004 Heat Transfer/Fluids Engineering ...

2012-05-21T23:59:59.000Z

157

Why Sequence a Methane-Oxidizing Archaean?  

NLE Websites -- All DOE Office Websites (Extended Search)

a Methane-Oxidizing Archaeon? a Methane-Oxidizing Archaeon? Methane is a potent greenhouse gas whose atmospheric concentration has increased significantly because of anthropogenic activities and fluctuated naturally over glacial and interglacial cycles. While the importance of methane in Earth's climate dynamics has been well established, the global processes regulating its oceanic cycling remain poorly understood. Although there are high rates of methane production in many marine sedimentary environments (including a number that have been targeted as petroleum reserves), net methane sources from the ocean to the atmosphere appear to be small. This is due in large part to a biogeochemical process known as the anaerobic oxidation of methane (AOM). Microbially mediated AOM reduces methane flux from ocean to atmosphere, stimulates subsurface microbial

158

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Assessing the Efficacy of the Aerobic Methanotropic Biofilter in Methane Hydrate Environments Last Reviewed 1/8/2013 Assessing the Efficacy of the Aerobic Methanotropic Biofilter in Methane Hydrate Environments Last Reviewed 1/8/2013 DE-NT0005667 Goal The goal of this project is to assess the efficacy of aerobic methanotrophy in preventing the escape of methane from marine, hydrate-bearing reservoirs to the atmosphere and ultimately to better define the role of aerobic methanotrophy in the global carbon cycle. Graph overlayed on photo - Methane seeps with the resulting methane plume Methane seeps with the resulting methane plume, Geophysical Research Letters, November 2007 Performers University of California – Santa Barbara, Santa Barbara (UCSB), CA 93106 Background The global methane reservoir in the form of gas hydrate is estimated at 500–10,000 Gt (KVENVOLDEN, 1995; MILKOV, 2004). This pool of carbon

159

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

as described by Dillon, et al. (1998). Failure would be accompanied by the release of methane gas, but a portion of the methane is likely to be oxidized unless the gas release is...

160

Miscellaneous States Coalbed Methane Proved Reserves (Billion...  

Gasoline and Diesel Fuel Update (EIA)

Coalbed Methane Proved Reserves (Billion Cubic Feet) Miscellaneous States Coalbed Methane Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

Note: This page contains sample records for the topic "methane nonmethane hydrocarbons" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Methane Degradation and Methane-Degrading Microbes in Alaska Coastal Waters Last Reviewed 5152012 DE-NT0005666 Goal The goal of this project is gain a better understanding of...

162

NETL: News Release - Methane Hydrate Production Technologies...  

NLE Websites -- All DOE Office Websites (Extended Search)

of CO2 molecules for methane molecules in the solid-water hydrate lattice, the release of methane gas, and the permanent storage of CO2 in the formation. This field experiment will...

163

coalbed methane | OpenEI  

Open Energy Info (EERE)

coalbed methane coalbed methane Dataset Summary Description (Abstract): Each TMY is a data set of hourly values of solar radiation and meteorological elements for a 1-year period. Solar radiation is modeled using the NREL METSTAT model, with surface observed cloud cover being the principal model input. The container file contains one TMY file for each selected station in the region, plus documentation files and a TMY data reader file for use with Microsoft Excel. (Purpose): Simulations Source NREL Date Released April 30th, 2005 (9 years ago) Date Updated November 07th, 2007 (7 years ago) Keywords coalbed methane GEF Kenya NREL SWERA TMY UNEP Data application/zip icon Download Data (zip, 5.4 MiB) Quality Metrics Level of Review Some Review Comment Temporal and Spatial Coverage

164

Method for the photocatalytic conversion of methane  

DOE Patents (OSTI)

A method for converting methane to methanol is provided comprising subjecting the methane to visible light in the presence of a catalyst and an electron transfer agent. Another embodiment of the invention provides for a method for reacting methane and water to produce methanol and hydrogen comprising preparing a fluid containing methane, an electron transfer agent and a photolysis catalyst, and subjecting said fluid to visible light for an effective period of time.

Noceti, Richard P. (Pittsburgh, PA); Taylor, Charles E. (Pittsburgh, PA); D' Este, Joseph R. (Pittsburgh, PA)

1998-01-01T23:59:59.000Z

165

Method for the photocatalytic conversion of methane  

DOE Patents (OSTI)

A method for converting methane to methanol is provided comprising subjecting the methane to visible light in the presence of a catalyst and an electron transfer agent. Another embodiment of the invention provides for a method for reacting methane and water to produce methanol and hydrogen comprising preparing a fluid containing methane, an electron transfer agent and a photolysis catalyst, and subjecting said fluid to visible light for an effective period of time. 3 figs.

Noceti, R.P.; Taylor, C.E.; D`Este, J.R.

1998-02-24T23:59:59.000Z

166

QUEST FOR NEW MATERIALS FOR METHANE STORAGE ...  

Science Conference Proceedings (OSTI)

Quest for New Materials for Methane Storage: Gas Adsorption and Neutron Diffraction Measurements. Yang Peng, 1,2 Vaiva ...

167

EIA - Greenhouse Gas Emissions - Methane Emissions  

U.S. Energy Information Administration (EIA)

Residential wood consumption accounted for just over 45 percent of U.S. methane emissions from stationary combustion in 2009.

168

NIST: Methane Symmetry Operations - Nuclear spin functions  

Science Conference Proceedings (OSTI)

Methane Symmetry Operations. 9. Symmetry Properties of Laboratory-Fixed Nuclear Spin Functions, Nuclear Spin Statistics, and Parities. ...

169

Methane Emissions from Rice Fields - Final Report  

SciTech Connect

Methane (Ch4) is a greenhouse gas regarded second only to carbon dioxide in its ability to cause global warming. Methane is important because of its relatively fast increase, and also because it is, per molecule, some 60 times more effective than carbon dioxide in causing global warming. The largest present anthropogenic sources of methane are rice fields, cattle and biomass burning.

Khalil, M. Aslam; Rasmussen,Reinhold A.

2002-12-03T23:59:59.000Z

170

Biogeochemistry of Microbial Coal-Bed Methane  

E-Print Network (OSTI)

Biogeochemistry of Microbial Coal-Bed Methane Dariusz Strapo´c,1, Maria Mastalerz,2 Katherine, biodegradation Abstract Microbial methane accumulations have been discovered in multiple coal- bearing basins low-maturity coals with predominantly microbial methane gas or uplifted coals containing older

Macalady, Jenn

171

Thermocatalytic CO2-Free Production of Hydrogen from Hydrocarbon Fuels  

DOE Green Energy (OSTI)

The main objective of this project is the development of an economically viable thermocatalytic process for production of hydrogen and carbon from natural gas or other hydrocarbon fuels with minimal environmental impact. The three major technical goals of this project are: (1) to accomplish efficient production of hydrogen and carbon via sustainable catalytic decomposition of methane or other hydrocarbons using inexpensive and durable carbon catalysts, (2) to obviate the concurrent production of CO/CO{sub 2} byproducts and drastically reduce CO{sub 2} emissions from the process, and (3) to produce valuable carbon products in order to reduce the cost of hydrogen production The important feature of the process is that the reaction is catalyzed by carbon particulates produced in the process, so no external catalyst is required (except for the start-up operation). This results in the following advantages: (1) no CO/CO{sub 2} byproducts are generated during hydrocarbon decomposition stage, (2) no expensive catalysts are used in the process, (3) several valuable forms of carbon can be produced in the process depending on the process conditions (e.g., turbostratic carbon, pyrolytic graphite, spherical carbon particles, carbon filaments etc.), and (4) CO{sub 2} emissions could be drastically reduced (compared to conventional processes).

University of Central Florida

2004-01-30T23:59:59.000Z

172

Methane generation from waste materials  

DOE Patents (OSTI)

An organic solid waste digester for producing methane from solid waste, the digester comprising a reactor vessel for holding solid waste, a sprinkler system for distributing water, bacteria, and nutrients over and through the solid waste, and a drainage system for capturing leachate that is then recirculated through the sprinkler system.

Samani, Zohrab A. (Las Cruces, NM); Hanson, Adrian T. (Las Cruces, NM); Macias-Corral, Maritza (Las Cruces, NM)

2010-03-23T23:59:59.000Z

173

Methane production by attached film  

DOE Patents (OSTI)

A method for purifying wastewater of biodegradable organics by converting the organics to methane and carbon dioxide gases is disclosed, characterized by the use of an anaerobic attached film expanded bed reactor for the reaction process. Dilute organic waste material is initially seeded with a heterogeneous anaerobic bacteria population including a methane-producing bacteria. The seeded organic waste material is introduced into the bottom of the expanded bed reactor which includes a particulate support media coated with a polysaccharide film. A low-velocity upward flow of the organic waste material is established through the bed during which the attached bacterial film reacts with the organic material to produce methane and carbon dioxide gases, purified water, and a small amount of residual effluent material. The residual effluent material is filtered by the film as it flows upwardly through the reactor bed. In a preferred embodiment, partially treated effluent material is recycled from the top of the bed to the bottom of the bed for further treatment. The methane and carbon dioxide gases are then separated from the residual effluent material and purified water.

Jewell, William J. (202 Eastwood Ave., Ithaca, NY 14850)

1981-01-01T23:59:59.000Z

174

Methane Digesters and Biogas Recovery - Masking the Environmental Consequences of Industrial Concentrated Livestock Production  

E-Print Network (OSTI)

Methane Digesters and Biogas Recovery-Masking theII. METHANE DIGESTERS AND BIOGAs RECOVERY- IN THE2011] METHANE DIGESTERS AND BIOGAS RECOVERY methane, and 64%

Di Camillo, Nicole G.

2011-01-01T23:59:59.000Z

175

Volume and accessibility of entrained (solution) methane in deep geopressured reservoirs - tertiary formations of the Texas Gulf Coast. Final report  

DOE Green Energy (OSTI)

The objective of this project was to appraise the total volume of in-place methane dissolved in formation waters of deep sandstone reservoirs of the onshore Texas Gulf Coast within the stratigraphic section extending from the base of significant hydrocarbon production (8000 ft)* to the deepest significant sandstone occurrence. The area of investigation is about 50,000 mi/sup 2/. Factors that determine the total methane resource are reservoir bulk volume, porosity, and methane solubility; the latter is controlled by the temperature, pressure, and salinity of formation waters. Regional assessment of the volume and the distribution of potential sandstone reservoirs was made from a data base of 880 electrical well logs, from which a grid of 24 dip cross sections and 4 strike cross sections was constructed. Solution methane content in each of nine formations or divisions of formations was determined for each subdivision. The distribution of solution methane in the Gulf Coast was described on the basis of five reservoir models. Each model was characterized by depositional environment, reservoir continuity, porosity, permeability, and methane solubility.

Gregory, A.R.; Dodge, M.M.; Posey, J.S.; Morton, R.A.

1980-10-01T23:59:59.000Z

176

Methane Hydrate Production Feasibility | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Production Feasibility Production Feasibility Methane Hydrate Production Feasibility The red curves are temperature profiles for various water depths; the blue line shows methane hydrate stability relative to temperature and pressure. The area enclosed by the two curves represents the area of methane hydrate stability. The red curves are temperature profiles for various water depths; the blue line shows methane hydrate stability relative to temperature and pressure. The area enclosed by the two curves represents the area of methane hydrate stability. Methane, the predominant component of natural gas, forms hydrate in the presence of water, low temperatures and high pressures. Alternatively, when the temperature is increased or the pressure decreased so that hydrates are outside their stability field, they dissociate into methane and water.

177

Methane Hydrate Advisory Committee | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Methane Hydrate Advisory Methane Hydrate Advisory Committee Methane Hydrate Advisory Committee The Methane Hydrate Advisory Committee was created in response to provisions of the Methane Hydrate Research and Development Act of 2000 and reauthorized by the Energy Policy Act of 2005. The Committee is to advise the Secretary of Energy on potential applications of methane hydrate; assist in developing recommendations and priorities for the methane hydrate research and development program; and submit to Congress one or more reports on an assessment of the research program and an assessment of the DOE 5-year research plan. The Committee's charter stipulates that up to 15 members can be appointed by the Secretary of Energy, representing institutions of higher education, industrial enterprises and oceanographic institutions and state agencies.

178

Selective methane oxidation over promoted oxide catalysts. Topical report, September 8, 1992--September 7, 1996  

DOE Green Energy (OSTI)

The objective of this research was to selectively oxidize methane to C{sub 2} hydrocarbons and to oxygenates, in particular formaldehyde and methanol, in high space time yields using air at the oxidant under milder reaction conditions that heretofore employed over industrially practical oxide catalysts. The research carried out under this US DOE-METC contract was divided into the following three tasks: Task 1, maximizing selective methane oxidation to C{sub 2}{sup +} products over promoted SrO/La{sub 2}O{sub 3} catalysts; Task 2, selective methane oxidation to oxygenates; and Task 3, catalyst characterization and optimization. Principal accomplishments include the following: the 1 wt% SO{sub 4}{sup 2{minus}}/SrO/La{sub 2}O{sub 3} promoted catalyst developed here produced over 2 kg of C{sub 2} hydrocarbons/kg catalyst/hr at 550 C; V{sub 2}O{sub 5}/SiO{sub 2} catalysts have been prepared that produce up to 1.5 kg formaldehyde/kg catalyst/hr at 630 C with low CO{sub 2} selectivities; and a novel dual bed catalyst system has been designed and utilized to produce over 100 g methanol/kg catalyst/hr at 600 C with the presence of steam in the reactant mixture.

Klier, K.; Herman, R.G.

1996-12-31T23:59:59.000Z

179

Selective methane oxidation over promoted oxide catalysts. Quarterly report, March--May 1995  

DOE Green Energy (OSTI)

The objective of this research is the selective oxidative coupling of methane to C{sub 2}H{sub 4} hydrocarbons and oxygenates, in particular formaldehyde and methanol. Air, oxygen or carbon dioxide, rather than nitrous oxide will be utilized as the oxidizing gas at high gas hourly space velocity, but mild reaction conditions (500-700 {degrees}C, 1 atm total pressure). All the investigated processes are catalytic, aiming at minimizing gas phase reactions that are difficult to control. The research is divided into the following three tasks: (1) maximizing selective methane oxidation to C{sub 2}H{sub 4} products over promoted Sr/La{sub 2}O{sub 3}; (2) selective methane oxidation to oxygenates; and (3) catalyst characterization and optimization. Task 1 dealt with the preparation, testing, and optimization of acidic promoted lanthana-based catalysts for the synthesis of C{sub 2}H{sub 4} hydrocarbons and is essentially completed. Task 2 aims at the formation and optimization of promoted catalysts for the synthesis of oxygenates, in particular formaldehyde and methanol. Task 3 involves characterization of the most promising catalysts so that optimization can be achieved under Task 2. Accomplishments for this period are presented.

Klier, K.; Herman, R.G.; Wang, Chaun-Bao; Shi, Chunlei; Sun, Qun

1995-08-01T23:59:59.000Z

180

Brian Giebel  

Science Conference Proceedings (OSTI)

... and sampling protocols for measuring the stable carbon ( 13 C) isotopic composition of trace organic compounds including methane, non-methane ...

2013-08-15T23:59:59.000Z

Note: This page contains sample records for the topic "methane nonmethane hydrocarbons" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Turbulent burning rates of methane and methane-hydrogen mixtures  

Science Conference Proceedings (OSTI)

Methane and methane-hydrogen (10%, 20% and 50% hydrogen by volume) mixtures have been ignited in a fan stirred bomb in turbulence and filmed using high speed cine schlieren imaging. Measurements were performed at 0.1 MPa (absolute) and 360 K. A turbulent burning velocity was determined for a range of turbulence velocities and equivalence ratios. Experimental laminar burning velocities and Markstein numbers were also derived. For all fuels the turbulent burning velocity increased with turbulence velocity. The addition of hydrogen generally resulted in increased turbulent and laminar burning velocity and decreased Markstein number. Those flames that were less sensitive to stretch (lower Markstein number) burned faster under turbulent conditions, especially as the turbulence levels were increased, compared to stretch-sensitive (high Markstein number) flames. (author)

Fairweather, M. [School of Process, Environmental and Materials Engineering, University of Leeds, Leeds LS2 9JT (United Kingdom); Ormsby, M.P.; Sheppard, C.G.W. [School of Mechanical Engineering, University of Leeds, Leeds LS2 9JT (United Kingdom); Woolley, R. [Department of Mechanical Engineering, University of Sheffield, Sheffield S1 3JD (United Kingdom)

2009-04-15T23:59:59.000Z

182

Influence of gas feed composition and pressure on the catalytic conversion of CO{sub 2} to hydrocarbons using a traditional cobalt-based Fischer-Tropsch catalyst  

SciTech Connect

The hydrogenation of CO{sub 2} using a traditional Fischer-Tropsch Co-Pt/Al{sub 2}O{sub 3} catalyst for the production of valuable hydrocarbon materials is investigated. The ability to direct product distribution was measured as a function of different feed gas ratios of H{sub 2} and CO{sub 2} (3:1, 2:1, and 1:1) as well as operating pressures (ranging from 450 to 150 psig). As the feed gas ratio was changed from 3:1 to 2:1 and 1:1, the production distribution shifted from methane toward higher chain hydrocarbons. This change in feed gas ratio is believed to lower the methanation ability of Co in favor of chain growth, with possibly two different active sites for methane and C2-C4 products. Furthermore, with decreasing pressure, the methane conversion drops slightly in favor of C{sub 2}-C{sub 4} paraffins. Even though under certain reaction conditions product distribution can be shifted slightly away from the formation of methane, the catalyst studied behaves like a methanation catalyst in the hydrogenation of CO{sub 2}. 36 refs., 2 figs., 4 tabs.

Robert W. Dorner; Dennis R. Hardy; Frederick W. Williams; Burtron H. Davis; Heather D. Willauer [Naval Research Laboratory, Washington, DC (United States). Navy Technology Center for Safety and Survivability Branch

2009-08-15T23:59:59.000Z

183

Hydrocarbons in the deep earth  

NLE Websites -- All DOE Office Websites (Extended Search)

composed of the elements hydrogen and carbon) are the main building block of crude oil and natural gas. Hydrocarbons contribute to the global carbon cycle (one of the most...

184

Hydrocarbon adsorption apparatus and process  

SciTech Connect

A method of recovering hydrocarbons from natural gas by the use of solid adsorbents consists of 3 steps. The main flow stream of natural gas is passed through a first and only bed of solid adsorbent so that at least a portion of the hydrocarbons present is adsorbed in the bed. A heated regeneration gas is next passed through a second bed of solid adsorbent so that at least a portion of the hydrocarbons is desorbed from the bed. The main flow of natural gas is passed through the second and only bed when in a heated condition after regeneration and the flow of heated regeneration gas is passed through the first bed. The hydrocarbons desorbed from the first and second beds from the regeneration gas are recovered while the previous 3 steps are repeated. (6 claims)

Humphries, C.L.

1966-12-06T23:59:59.000Z

185

Novel catalysts for methane activation. Quarterly report No. 4, July 1, 1993--September 30, 1993  

DOE Green Energy (OSTI)

The objectives of this project are to test novel fullerene based catalysts for application in methane activation. Fullerenes are a recently discovered allotrope of carbon that have been found to possess unusual properties, some of which may be ideal for methane conversion to higher hydrocarbons. The project is divided into three technical tasks. Task 1 deals with the synthesis and characterization of the fullerenes and fullerene soots, Task 2 with the testing of the catalysts, and Task 3 with the evaluation of the results and technical reporting requirements. This quarter the authors concentrated on Task 2. In this task they expanded the capabilities of the system so they can include the effect of diluents during the methane activation experiments and continued work on evaluating the fullerene soot. They investigated the base-line conditions for both thermal reactions and soot-catalyzed reactions of methane. They also added the capability to add diluents such as hydrogen and helium into the reaction system to determine their respective effects on selectivity during the methane activation experiments. They found that the fullerene soot significantly decreased the threshold for the methane activation and C{sub 2} products at temperatures as low as 800{degrees}C, whereas the pure thermal reaction required temperatures in the range of 900 to 950{degrees}C. However, under their conditions the selectivity to C{sub 2} was much lower for the fullerene soot, than for the thermal case. They found that the presence of H{sub 2} helped the selectivity to some degree at a given temperature, but still formed a considerable amount of coke under these condition.

Hirschon, A.S.; Wu, H.J.; Malhotra, R.; Wilson, R.B.

1993-12-03T23:59:59.000Z

186

DEVELOPMENT OF A CATALYST/SORBENT FOR METHANE REFORMING  

DOE Green Energy (OSTI)

This work has led to the initial development of a very promising material that has the potential to greatly simplify hydrocarbon reforming for the production of hydrogen and to improve the overall efficiency and economics of the process. This material, which was derived from an advanced calcium-based sorbent, was composed of core-in-shell pellets such that each pellet consisted of a CaO core and an alumina-based shell. By incorporating a nickel catalyst in the shell, a combined catalyst and sorbent was prepared to facilitate the reaction of hydrocarbons with steam. It was shown that this material not only catalyzes the reactions of methane and propane with steam, it also absorbs CO{sub 2} simultaneously, and thereby separates the principal reaction products, H{sub 2} and CO{sub 2}. Furthermore, the absorption of CO{sub 2} permits the water gas shift reaction to proceed much further towards completion at temperatures where otherwise it would be limited severely by thermodynamic equilibrium. Therefore, an additional water gas shift reaction step would not be required to achieve low concentrations of CO. In a laboratory test of methane reforming at 600 C and 1 atm it was possible to produce a gaseous product containing 96 mole% H{sub 2} (dry basis) while also achieving a H{sub 2} yield of 95%. Methane reforming under these conditions without CO{sub 2} absorption provided a H{sub 2} concentration of 75 mole% and yield of 82%. Similar results were achieved in a test of propane reforming at 560 C and 1 atm which produced a product containing 96 mole% H{sub 2} while CO{sub 2} was being absorbed but which contained only 69 mole% H{sub 2} while CO{sub 2} was not being absorbed. These results were achieved with an improved catalyst support that was developed by replacing a portion of the {alpha}-alumina in the original shell material with {gamma}-alumina having a much greater surface area. This replacement had the unfortunate consequence of reducing the overall compressive strength of the core-in-shell pellets. Therefore, a preliminary study of the factors that control the surface area and compressive strength of the shell material was conducted. The important factors were identified as the relative concentrations and particle size distributions of the {alpha}-alumina, {gamma}-alumina, and limestone particles plus the calcination temperature and time used for sintering the shell material. An optimization of these factors in the future could lead to the development of a material that has both the necessary mechanical strength and catalytic activity.

B.H. Shanks; T.D. Wheelock; Justinus A. Satrio; Timothy Diehl; Brigitte Vollmer

2004-09-27T23:59:59.000Z

187

Dairy methane generator. Final report  

Science Conference Proceedings (OSTI)

Details of the work completed under this contract are presented. During the winter of 1979-80 three students enrolled, in the Mechanical Design Engineering Technology program at the Pennsylvania State University's Capitol Campus (Middletown, PA), undertook a feasibility study for the utilization of the manure generated by the dairy cows located on Mr. Thomas B. Williams farm for the generation and use of methane gas. The results of their effort was the design of an Anaerobic Digester/Electric Generation System. This preliminary designed system was later changed and improved by another group of P.S.U. MDET students in the spring of 1980. The final design included working drawings and an economic analysis of the estimated investment necessary to complete the Methane Generator/Electric Power Generation System.

Williams, T.B.

1981-09-30T23:59:59.000Z

188

Methane coupling by membrane reactor. Quarterly technical progress report, June 25, 1995--September 24, 1995  

DOE Green Energy (OSTI)

The research focus, for the development of a radial flow catalytic membrane reactor for studying methane coupling, concentrated on understanding the effects of pore size, catalyst loading and catalyst distribution inside the membrane, on the hydrocarbon selectivity. The experimental results from the catalytic studies of oxidative coupling of methane in the radial flow membrane reactors are summarized in this report and the reactor performances of three radial flow reactors with pore sizes of 0.02 {mu}m are interpreted by the energy dispersive X-ray digital mapping (EDX) technique. A conventional fixed bed catalytic reactor was set up and run under the same conditions as were used for the radial flow reactor studies. Two sources of samarium oxide catalysts were used in these experiments and their performances were compared in terms of C{sub 2} selectivity at same methane conversion. Compared to the monoclinic form of samarium oxide, the catalyst with cubic form was more active and selective for methane oxidative coupling. A general reactor model for oxidation reactions with distributed feed of oxygen and product removal strategies was proposed. Six types of feeding modes were analyzed and their feed distributions were optimized such that the desired product yields at the reactor outlet were maximized.

NONE

1995-12-12T23:59:59.000Z

189

Activation of methane by transition metal-substituted aluminophosphate molecular sieves  

DOE Patents (OSTI)

Aluminophosphate molecular sieves substituted with cobalt, manganese or iron and having the AlPO{sub 4}-34 or AlPO{sub 4}-5, or related AlPO{sub 4} structure activate methane starting at approximately 350{degree}C. Between 400 and 500{degree}C and at methane pressures {le} 1 atmosphere the rate of methane conversion increases steadily with typical conversion efficiencies at 500{degree}C approaching 50% and selectivity to the production of C{sub 2+} hydrocarbons approaching 100%. The cobalt substituted AlPO{sub 4}-34 structure (CoAPSO-34) produces ethylene, ethane, propylene, and propane in varying proportions, depending on reaction conditions. The cobalt-substituted AlPO{sub 4}-5 (CoAPSO-5) produces polypropylene in very high yield, with ethane, ethylene, and propane also produced. The activation mechanism is based on reduction of the transition metal (III) from of the molecular sieve to the transition metal(II) form with accompanying oxidative dehydrogenation of the methane. Reoxidation of the transition metal(II) form to the transition metal (III) form can be done either chemically (e.g., using O{sub 2}) or electrochemically. 4 figs.

Iton, L.E.; Maroni, V.A.

1990-03-16T23:59:59.000Z

190

Direct conversion of light hydrocarbon gases to liquid fuel  

DOE Green Energy (OSTI)

Amoco Oil Company is investigating the direct conversion of light hydrocarbon gases to liquid fuels via partial oxidation. This report describes work completed in the first quarter of the two-year project (first quarter FY 1990). Task 1 of the work, preparation of the Project Management Plan, has been completed. Work was started and progress made on three other tasks during this quarter: Task 2. Modification of an existing Amoco pilot plant to handle the conditions of this project. Minor modifications were made to increase the maximum operating pressure to 1500 psig. Other more extensive modifications are being designed, including addition of an oxygen compressor and recycle system. Task 3.1. Evaluation of a Los Alamos National Laboratory methane oxidation kinetic model for suitability in guiding the experimental portions of this project. Task 3.2. Process variable (e.g. temperature, pressure, residence time) studies to determine optimal partial oxidation conditions. 1 fig.

Foral, M.J.

1990-01-01T23:59:59.000Z

191

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Characterization and Decomposition Kinetic Studies of Methane Hydrate in Host Sediments under Subsurface Mimic Conditions Last Reviewed 02/17/2010 Characterization and Decomposition Kinetic Studies of Methane Hydrate in Host Sediments under Subsurface Mimic Conditions Last Reviewed 02/17/2010 EST-380-NEDA Goal The purpose of this study is to establish sediment lithology and quantification of methane in hydrates hosted in fine-grained sediments from the Gulf of Mexico (GoM), a marine site of methane hydrate occurrence. The results will help establish a correlation between laboratory data and hydrate accumulation field data on dispersed hydrates in the natural environment. Performer Brookhaven National Laboratory (BNL), Upton, New York 11973 Background Gas hydrates are located in permafrost and marine environments and show potential as a vast methane source worldwide. However, methane is about 17 times more potent a greenhouse gas than CO2 and the inherent instability of

192

High Hydrogen, Low Methane Syngas from Low-Rank Coals for Coal-to-Liquids  

NLE Websites -- All DOE Office Websites (Extended Search)

High Hydrogen, Low Methane Syngas from Low-Rank Coals for Coal-to-Liquids Production High Hydrogen, Low Methane Syngas from Low-Rank Coals for Coal-to-Liquids Production Southern Research Institute (SRI) Project Number: FE0012054 Project Description The focus of the project will be to develop, test, and optimize steam-reforming catalysts for converting tars, C2+ hydrocarbons, NH3, and CH4 in high-temperature and sulfur environments, increasing the ratio of hydrogen in syngas, as part of a modified, advanced gasification platform for the conversion of low-rank coals to syngas for coal-to-liquid and integrated gasification combined cycle applications. Project Details Program Background and Project Benefits Project Scope and Technology Readiness Level Accomplishments Contacts, Duration, and Cost Project Images Abstract Performer website: Southern Research Institute

193

Selective methane oxidation over promoted oxide catalysts. Quarterly report, September 1 - November 30, 1995  

DOE Green Energy (OSTI)

The objective of this research is the selective oxidation of methane to C{sub 2}H{sub 4} hydrocarbons and to oxygenates, in particular formaldehyde and methanol. Air, oxygen, or carbon dioxide rather than nitrous oxide, are utilized as the oxidizing gas at high gas hourly space velocity but mild reaction conditions (500-700{degrees}C, 1 atm total pressure). All the investigated processes are catalytic, aiming at minimizing gas phase reactions that are difficult to control. During this quarter, solid state {sup 51}V NMR and double catalyst bed experiments were conducted to demonstrate the unfavorable effect of the presence of bulk crystalline V{sub 2}O{sub 5} in V{sub 2}O{sub 5}-SiO{sub 2} xerogel catalysts on selective oxidation of methane to methanol and formaldehyde. Results are discussed.

Klier, Kamil; Herman, R.G.; Wang, C.B. [USDOE Morgantown Energy Technology Center, WV (United States)

1995-12-31T23:59:59.000Z

194

An interatomic potential for saturated hydrocarbons based on the modified embedded-atom method  

E-Print Network (OSTI)

In this work, we developed an interatomic potential for saturated hydrocarbons using the modified embedded-atom method (MEAM), a semi-empirical many-body potential based on density functional theory and pair potentials. We parameterized the potential by fitting to a large experimental and first-principles (FP) database consisting of 1) bond distances, bond angles, and atomization energies at 0 K of a homologous series of alkanes and their select isomers from methane to n-octane, 2) the potential energy curves of H2, CH, and C2 diatomics, 3) the potential energy curves of hydrogen, methane, ethane, and propane dimers, i.e., (H2)2, (CH4)2, (C2H6)2, and (C3H8)2, respectively, and 5) pressure-volume-temperature (PVT) data of a dense high-pressure methane system with the density of 0.5534 g/cc. We compared the atomization energies and geometries of a range of linear alkanes, cycloalkanes, and free radicals calculated from the MEAM potential to those calculated by other commonly used potentials for hydrocarbons, i....

Nouranian, S; Gwaltney, S R; Baskes, M I; Horstemeyer, M F

2013-01-01T23:59:59.000Z

195

Methane Hydrates R&D Program  

NLE Websites -- All DOE Office Websites (Extended Search)

Methane Hydrates R&D Program Methane Hydrates R&D Program Gas hydrates are a naturally-occurring combination of methane gas and water that form under specific conditions of low temperature and high pressure. Once thought to be rare in nature, gas hydrates are now known to occur in great abundance in association with arctic permafrost and in the shallow sediments of the deep-water continental shelves. The most recent estimates of gas hydrate abundance suggest that they contain

196

Table 16. Coalbed Methane Proved Reserves, Reserves ...  

U.S. Energy Information Administration (EIA)

aIncludes Illinois and Indiana. Note: The above table is based on coalbed methane proved reserves and production volumes as reported to the EIA on ...

197

EIA - Greenhouse Gas Emissions - Methane Emissions  

Gasoline and Diesel Fuel Update (EIA)

oil production dropping by 28 percent from 1990 to 2009, methane emissions from petroleum exploration and production have declined by the same percentage. Residential wood...

198

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Seol, Y. and T. J. Kneafsey, Methane hydrate induced permeability modification for multiphase flow in unsaturated porous media, Journal of Geophysical Research, 2011, In...

199

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

NETL ORD Methane Hydrate Research - Thermal Properties of Hydrate Tool Development Last Reviewed 3182013 Project Goal The goal of this project is increased understanding of...

200

NETL: Methane Hydrates - Hydrate Model Code Comparison  

NLE Websites -- All DOE Office Websites (Extended Search)

Reservoir Simulator Code Comparison Study An International Effort to Compare Methane Hydrate Reservoir Simulators Code Comparison Logo The National Energy Technology Laboratory...

Note: This page contains sample records for the topic "methane nonmethane hydrocarbons" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

of gas hydrates. The effort aims to quantify the mechanical characteristics of methane hydrate and hydrate cemented sediments for use in models of the dynamic behavior of...

202

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

in Support of Characterization of Recoverable Resources from Methane Hydrate Deposits Last Reviewed 5102012 ESD05-048 Goal The project is bringing new laboratory measurements and...

203

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Methane Hydrate Projects If you need help finding information on a particular project, please contact the content manager. Search Hydrates Projects Active Projects | Completed...

204

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

characterization and temporal variation of methane seepage from thermokarst lakes on the Alaska North Slope in response to Arctic climate change Last Reviewed 632013 DE-NT0005665...

205

,"California - Coastal Region Coalbed Methane Proved Reserves...  

U.S. Energy Information Administration (EIA) Indexed Site

- Coastal Region Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","...

206

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

in the Gulf of Mexico and 2) NRL's Advanced Research Initiative on shallow sediment methane seeps. Geochemical data coupled with heat flow probe data were used to estimate...

207

Methane Hydrate Advisory Committee Meeting Minutes | Department...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

16, 2013 Washington, DC July 16, 2013 Meeting Minutes More Documents & Publications Methane Hydrate Advisory Committee Meeting Minutes Electricity Advisory Committee Notice of Open...

208

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

late Quaternary. An investigation of the nature of deposition and alteration of the methane hydrate in cores from the Umnak Plateau in the southeastern Bering Sea was conducted...

209

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

establishing high-priority geographical regions of prospective interest, in terms of methane volume estimates; c). Prediction of environmental effects and geologic risks at the...

210

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

goal was to develop new methodologies to characterize the physical properties of methane hydrate and hydrate sediment systems. Performers Westport Technology Center...

211

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

during NGHP Expedition 01 Background Gas hydrate distribution in sediments depends on methane supply, which in turn depends on fluid flow. When drilling data are available to...

212

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Methane Hydrate Research - Geoscience Evaluations and Field Studies Last Reviewed 3182013 Project Goals The primary goals of the DOENETL Natural Gas Hydrate Field Studies...

213

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

(RUS) technique to examine hydrate formationdissociation processes. For determining methane abundance and location on a grain-to-grain scale, a completely new method of...

214

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

natural and simulated sediment samples, and to use these sediments as hosts to form methane hydrate and to investigate the kinetics of hydrate formation and dissociation...

215

,"Federal Offshore California Coalbed Methane Proved Reserves...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

216

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

for this sample, but Raman bands from both samples were essentially identical: methane and ethane along with trace amounts of isobutene and trans-butane. Small angle...

217

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

on the behavior of gas hydrates in their natural environment under either production (methane gas extraction) or climate change scenarios. This research is closely linked with...

218

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Determine the potential impacts of gas hydrate instability in terms of the release of methane into seafloor sediments, the ocean and the atmosphere. Performers University of...

219

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Decomposition Kinetic Studies of Methane Hydrate in Host Sediments under Subsurface Mimic Conditions Last Reviewed 02172010 EST-380-NEDA Goal The purpose of this study is to...

220

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

and presentations as well as a listing of funded students can be found in the Methane Hydrate Program Bibliography PDF. A final report is available by request. Contact...

Note: This page contains sample records for the topic "methane nonmethane hydrocarbons" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

,"Miscellaneous States Coalbed Methane Proved Reserves (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

222

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

and presentations as well as a listing of funded students can be found in the Methane Hydrate Program Bibliography PDF. Final Project Report PDF-23MB - October, 2009...

223

,"Pennsylvania Coalbed Methane Proved Reserves (Billion Cubic...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

224

NETL: Methane Hydrates - ANS Research Project  

NLE Websites -- All DOE Office Websites (Extended Search)

Characterization project has resulted in a characterization of two large prospective methane hydrate accumulations (or trends); the Eileen Trend, which underlies but extends well...

225

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Structure and Physical Properties of Methane Hydrate Deposit at Blake Ridge Last Reviewed 02052010 Bathymetric location map of the Blake Ridge study area Bathymetric location map...

226

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Horizon spill approximately 10 miles from the observatory showed increased levels of methane at two depths where detectable levels had not been seen in the past. The evidence...

227

NETL: Methane Hydrates - ANS Research Project  

NLE Websites -- All DOE Office Websites (Extended Search)

Slope represents an important milestone in an ongoing evaluation of Alaskan Arctic methane hydrate potential. This evaluation, a joint effort of DOE, USGS, BP Exploration...

228

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Survey, Woods Hole Field Center Location Woods Hole Massachusetts Background Oceanic methane hydrates are a major emerging research topic spanning energy resource issues, global...

229

New Materials Make Methane Capture Possible  

Science Conference Proceedings (OSTI)

May 8, 2013... and FER, were able to concentrate dilute methane streams into moderate concentrations that could be used to treat coal-mine ventilation air.

230

Coal bed methane reservoir simulation studies.  

E-Print Network (OSTI)

??The purpose of this study is to perform simulation studies for a specific coal bed methane reservoir. First, the theory and reservoir engineering aspects of… (more)

Karimi, Kaveh

2005-01-01T23:59:59.000Z

231

methane hydrate science plan-final.indd  

NLE Websites -- All DOE Office Websites (Extended Search)

Industrial Revolu on. Methane in the atmosphere comes from many sources, including wetlands, rice cul va on, termites, cows and other ruminants, forest fi res, and fossil fuel...

232

Method for the photocatalytic conversion of methane  

DOE Patents (OSTI)

The invention relates to a method for converting methane and water to methanol and hydrogen using visible light and a catalyst.

Noceti, R.P.; Taylor, C.E.; D' Este, J.R.

1996-12-01T23:59:59.000Z

233

A conduit dilation model of methane venting from lake sediments  

E-Print Network (OSTI)

Methane is a potent greenhouse gas, but its effects on Earth's climate remain poorly constrained, in part due to uncertainties in global methane fluxes to the atmosphere. An important source of atmospheric methane is the ...

Ruppel, Carolyn

234

Utah Coalbed Methane Proved Reserves New Field Discoveries (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Release Date: 812013 Next Release Date: 812014 Referring Pages: Coalbed Methane New Field Discoveries Utah Coalbed Methane Proved Reserves, Reserves Changes, and Production...

235

Changes related to "Coal Bed Methane Protection Act (Montana...  

Open Energy Info (EERE)

Special page Share this page on Facebook icon Twitter icon Changes related to "Coal Bed Methane Protection Act (Montana)" Coal Bed Methane Protection Act (Montana)...

236

Pages that link to "Coal Bed Methane Protection Act (Montana...  

Open Energy Info (EERE)

Edit History Share this page on Facebook icon Twitter icon Pages that link to "Coal Bed Methane Protection Act (Montana)" Coal Bed Methane Protection Act (Montana)...

237

Louisiana--South Onshore Coalbed Methane Production (Billion...  

Gasoline and Diesel Fuel Update (EIA)

data. Release Date: 812013 Next Release Date: 812014 Referring Pages: Coalbed Methane Estimated Production LA, South Onshore Coalbed Methane Proved Reserves, Reserves...

238

California (with State off) Coalbed Methane Production (Billion...  

Gasoline and Diesel Fuel Update (EIA)

data. Release Date: 812013 Next Release Date: 812014 Referring Pages: Coalbed Methane Estimated Production California Coalbed Methane Proved Reserves, Reserves Changes,...

239

Other States Natural Gas Coalbed Methane, Reserves Based Production...  

Gasoline and Diesel Fuel Update (EIA)

Other States Natural Gas Coalbed Methane, Reserves Based Production (Billion Cubic Feet) Other States Natural Gas Coalbed Methane, Reserves Based Production (Billion Cubic Feet)...

240

Texas (with State Offshore) Coalbed Methane Production (Billion...  

Annual Energy Outlook 2012 (EIA)

data. Release Date: 812013 Next Release Date: 812014 Referring Pages: Coalbed Methane Estimated Production Texas Coalbed Methane Proved Reserves, Reserves Changes, and...

Note: This page contains sample records for the topic "methane nonmethane hydrocarbons" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Texas--RRC District 8 Coalbed Methane Production (Billion Cubic...  

Annual Energy Outlook 2012 (EIA)

data. Release Date: 812013 Next Release Date: 812014 Referring Pages: Coalbed Methane Estimated Production TX, RRC District 8 Coalbed Methane Proved Reserves, Reserves...

242

Texas--RRC District 5 Coalbed Methane Production (Billion Cubic...  

Annual Energy Outlook 2012 (EIA)

data. Release Date: 812013 Next Release Date: 812014 Referring Pages: Coalbed Methane Estimated Production TX, RRC District 5 Coalbed Methane Proved Reserves, Reserves...

243

Texas--RRC District 3 Onshore Coalbed Methane Proved Reserves...  

Annual Energy Outlook 2012 (EIA)

data. Release Date: 812013 Next Release Date: 812014 Referring Pages: Coalbed Methane Proved Reserves as of Dec. 31 TX, RRC District 3 Onshore Coalbed Methane Proved...

244

Texas--RRC District 6 Coalbed Methane Production (Billion Cubic...  

Annual Energy Outlook 2012 (EIA)

data. Release Date: 812013 Next Release Date: 812014 Referring Pages: Coalbed Methane Estimated Production TX, RRC District 6 Coalbed Methane Proved Reserves, Reserves...

245

Texas--RRC District 5 Coalbed Methane Proved Reserves (Billion...  

Gasoline and Diesel Fuel Update (EIA)

data. Release Date: 812013 Next Release Date: 812014 Referring Pages: Coalbed Methane Proved Reserves as of Dec. 31 TX, RRC District 5 Coalbed Methane Proved Reserves,...

246

Lower 48 Federal Offshore Coalbed Methane Production (Billion...  

Annual Energy Outlook 2012 (EIA)

data. Release Date: 812013 Next Release Date: 812014 Referring Pages: Coalbed Methane Estimated Production Federal Offshore U.S. Coalbed Methane Proved Reserves, Reserves...

247

Texas--RRC District 9 Coalbed Methane Production (Billion Cubic...  

Gasoline and Diesel Fuel Update (EIA)

data. Release Date: 812013 Next Release Date: 812014 Referring Pages: Coalbed Methane Estimated Production TX, RRC District 9 Coalbed Methane Proved Reserves, Reserves...

248

Louisiana--South Onshore Coalbed Methane Proved Reserves (Billion...  

Annual Energy Outlook 2012 (EIA)

data. Release Date: 812013 Next Release Date: 812014 Referring Pages: Coalbed Methane Proved Reserves as of Dec. 31 LA, South Onshore Coalbed Methane Proved Reserves,...

249

Alaska (with Total Offshore) Coalbed Methane Proved Reserves...  

Gasoline and Diesel Fuel Update (EIA)

data. Release Date: 812013 Next Release Date: 812014 Referring Pages: Coalbed Methane Proved Reserves as of Dec. 31 Alaska Coalbed Methane Proved Reserves, Reserves...

250

Texas--RRC District 6 Coalbed Methane Proved Reserves (Billion...  

Annual Energy Outlook 2012 (EIA)

data. Release Date: 812013 Next Release Date: 812014 Referring Pages: Coalbed Methane Proved Reserves as of Dec. 31 TX, RRC District 6 Coalbed Methane Proved Reserves,...

251

Texas--RRC District 3 Onshore Coalbed Methane Production (Billion...  

Annual Energy Outlook 2012 (EIA)

data. Release Date: 812013 Next Release Date: 812014 Referring Pages: Coalbed Methane Estimated Production TX, RRC District 3 Onshore Coalbed Methane Proved Reserves,...

252

Texas--RRC District 4 Onshore Coalbed Methane Production (Billion...  

Gasoline and Diesel Fuel Update (EIA)

data. Release Date: 812013 Next Release Date: 812014 Referring Pages: Coalbed Methane Estimated Production TX, RRC District 4 Onshore Coalbed Methane Proved Reserves,...

253

North Dakota Coalbed Methane Proved Reserves (Billion Cubic Feet...  

Gasoline and Diesel Fuel Update (EIA)

data. Release Date: 812013 Next Release Date: 812014 Referring Pages: Coalbed Methane Proved Reserves as of Dec. 31 North Dakota Coalbed Methane Proved Reserves, Reserves...

254

Texas--RRC District 10 Coalbed Methane Proved Reserves (Billion...  

Gasoline and Diesel Fuel Update (EIA)

data. Release Date: 812013 Next Release Date: 812014 Referring Pages: Coalbed Methane Proved Reserves as of Dec. 31 TX, RRC District 10 Coalbed Methane Proved Reserves,...

255

Texas--RRC District 1 Coalbed Methane Production (Billion Cubic...  

Gasoline and Diesel Fuel Update (EIA)

data. Release Date: 812013 Next Release Date: 812014 Referring Pages: Coalbed Methane Estimated Production TX, RRC District 1 Coalbed Methane Proved Reserves, Reserves...

256

Texas--RRC District 4 Onshore Coalbed Methane Proved Reserves...  

Annual Energy Outlook 2012 (EIA)

data. Release Date: 812013 Next Release Date: 812014 Referring Pages: Coalbed Methane Proved Reserves as of Dec. 31 TX, RRC District 4 Onshore Coalbed Methane Proved...

257

Texas--RRC District 1 Coalbed Methane Proved Reserves (Billion...  

Gasoline and Diesel Fuel Update (EIA)

data. Release Date: 812013 Next Release Date: 812014 Referring Pages: Coalbed Methane Proved Reserves as of Dec. 31 TX, RRC District 1 Coalbed Methane Proved Reserves,...

258

Methane Hydrate Advisory Committee Meeting Minutes, October 2011...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

October 2011 Methane Hydrate Advisory Committee Meeting Minutes, October 2011 Methane Hydrate Advisory Committee Meeting Minutes October 2011 Washington, DC Advisory Committee...

259

New York Coalbed Methane Production (Billion Cubic Feet)  

Gasoline and Diesel Fuel Update (EIA)

data. Release Date: 812013 Next Release Date: 812014 Referring Pages: Coalbed Methane Estimated Production New York Coalbed Methane Proved Reserves, Reserves Changes, and...

260

Texas--RRC District 10 Coalbed Methane Production (Billion Cubic...  

Annual Energy Outlook 2012 (EIA)

data. Release Date: 812013 Next Release Date: 812014 Referring Pages: Coalbed Methane Estimated Production TX, RRC District 10 Coalbed Methane Proved Reserves, Reserves...

Note: This page contains sample records for the topic "methane nonmethane hydrocarbons" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

North Dakota Coalbed Methane Production (Billion Cubic Feet)  

Annual Energy Outlook 2012 (EIA)

data. Release Date: 812013 Next Release Date: 812014 Referring Pages: Coalbed Methane Estimated Production North Dakota Coalbed Methane Proved Reserves, Reserves Changes,...

262

Louisiana--State Offshore Coalbed Methane Production (Billion...  

Gasoline and Diesel Fuel Update (EIA)

data. Release Date: 812013 Next Release Date: 812014 Referring Pages: Coalbed Methane Estimated Production LA, State Offshore Coalbed Methane Proved Reserves, Reserves...

263

Texas--RRC District 9 Coalbed Methane Proved Reserves (Billion...  

Gasoline and Diesel Fuel Update (EIA)

data. Release Date: 812013 Next Release Date: 812014 Referring Pages: Coalbed Methane Proved Reserves as of Dec. 31 TX, RRC District 9 Coalbed Methane Proved Reserves,...

264

Texas--RRC District 2 Onshore Coalbed Methane Production (Billion...  

Gasoline and Diesel Fuel Update (EIA)

data. Release Date: 812013 Next Release Date: 812014 Referring Pages: Coalbed Methane Estimated Production TX, RRC District 2 Onshore Coalbed Methane Proved Reserves,...

265

Texas--State Offshore Coalbed Methane Proved Reserves (Billion...  

Annual Energy Outlook 2012 (EIA)

data. Release Date: 812013 Next Release Date: 812014 Referring Pages: Coalbed Methane Proved Reserves as of Dec. 31 TX, State Offshore Coalbed Methane Proved Reserves,...

266

Alaska (with Total Offshore) Coalbed Methane Production (Billion...  

Gasoline and Diesel Fuel Update (EIA)

data. Release Date: 812013 Next Release Date: 812014 Referring Pages: Coalbed Methane Estimated Production Alaska Coalbed Methane Proved Reserves, Reserves Changes, and...

267

Texas--State Offshore Coalbed Methane Production (Billion Cubic...  

Gasoline and Diesel Fuel Update (EIA)

data. Release Date: 812013 Next Release Date: 812014 Referring Pages: Coalbed Methane Estimated Production TX, State Offshore Coalbed Methane Proved Reserves, Reserves...

268

Mississippi (with State off) Coalbed Methane Proved Reserves...  

Annual Energy Outlook 2012 (EIA)

data. Release Date: 812013 Next Release Date: 812014 Referring Pages: Coalbed Methane Proved Reserves as of Dec. 31 Mississippi Coalbed Methane Proved Reserves, Reserves...

269

Why sequence functional metagenomics of methane and nitrogen...  

NLE Websites -- All DOE Office Websites (Extended Search)

functional metagenomics of methane and nitrogen cycles in freshwater lakes? Methane is a more potent greenhouse gas than carbon dioxide, but it is also a potential source of...

270

Airborne observations of methane emissions from rice cultivation...  

NLE Websites -- All DOE Office Websites (Extended Search)

Airborne observations of methane emissions from rice cultivation in the Sacramento Valley of California Title Airborne observations of methane emissions from rice cultivation in...

271

METHANE HYDRATE ADVISORY COMMITTEE U.S. DEPARTMENT OF ENERGY  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

METHANE HYDRATE ADVISORY COMMITTEE U.S. DEPARTMENT OF ENERGY Advisory Committee Charter 1. Committee's Official Designation. Methane Hydrate Advisory Committee (MHAC) 2. Authority....

272

Kentucky Coalbed Methane Proved Reserves (Billion Cubic Feet...  

Annual Energy Outlook 2012 (EIA)

data. Release Date: 812013 Next Release Date: 812014 Referring Pages: Coalbed Methane Proved Reserves as of Dec. 31 Kentucky Coalbed Methane Proved Reserves, Reserves...

273

Texas--RRC District 8 Coalbed Methane Proved Reserves (Billion...  

Gasoline and Diesel Fuel Update (EIA)

data. Release Date: 812013 Next Release Date: 812014 Referring Pages: Coalbed Methane Proved Reserves as of Dec. 31 TX, RRC District 8 Coalbed Methane Proved Reserves,...

274

Mississippi (with State off) Coalbed Methane Production (Billion...  

Annual Energy Outlook 2012 (EIA)

data. Release Date: 812013 Next Release Date: 812014 Referring Pages: Coalbed Methane Estimated Production Mississippi Coalbed Methane Proved Reserves, Reserves Changes,...

275

Other States Natural Gas Coalbed Methane, Proved Reserves (Billion...  

Gasoline and Diesel Fuel Update (EIA)

Other States Natural Gas Coalbed Methane, Proved Reserves (Billion Cubic Feet) Other States Natural Gas Coalbed Methane, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1...

276

NETL: Methane Hydrates - DOE/NETL Projects - Application of Crunch...  

NLE Websites -- All DOE Office Websites (Extended Search)

multi-dimensional reactive transport simulation code to constrain modern day methane fluxes and to reconstruct past episodes of methane flux that can be correlated with...

277

Direct aromatization of methane. Quarterly technical progress report Number 5, 1 October 1993--31 December 1993  

DOE Green Energy (OSTI)

A study into the pyrolysis of methane in the absence of a quench has been completed. The unquenched reaction was studied at temperatures between 900 and 1,200 C and methane flows of 80--800 Scc/min. At 1,100 C and a methane flow rate ranging between 267 and 800 Scc/minute, methane conversions ranged between 31--48% with the major detectable product being benzene. At the low flow rates a significant amount of a black heavy product, primarily coke, was also formed. The reaction was also studied in a quenched mode. At 1,100 C, methane flow rate of 500 Scc/min, and a water flow rate of 216 mL/hr, a conversion of 33% was achieved with over 60% of the products being C{sub 4}+ hydrocarbons. Although a significant amount of heavy products were still formed, these were of a lighter color than those formed in the unquenched model suggesting a lower average molecular weight.

Not Available

1994-02-01T23:59:59.000Z

278

Reaction of Si(111) Surface with Saturated Hydrocarbon  

SciTech Connect

Reaction of Si(111) surface with saturated hydrocarbon such as methane (CH{sub 4}) and ethane (C{sub 2}H{sub 6}) was carried out in a gas source molecular beam epitaxy (GSMBE). After carbonization, structures formed on the surface were observed by in situ reflection high-energy electron diffraction (RHEED). Structures transition formed on the surface were 7x7, {delta}-7x7, 1x1, and SiC structures. In the case of CH{sub 4}, the Si surfaces were carbonized at 800 deg. C for 120 min (7.2x10{sup 4} L) with a W-filament of 2800 deg. C, and SiC layers were obtained. In the case of C{sub 2}H{sub 6}, the mixture of 7x7 and SiC structure was observed. Decomposition of hydrocarbon was characterized in quadrupole mass spectroscopy (QMS) measurements. An atomic force microscopy (AFM) image of the mixture of 7x7 and SiC shows a wandering shape. Whereas, the SiC layer shows a regular step. This result seems to be related to the different in the amount of CH{sub 3} molecules on the surface.

Suryana, Risa [Department of Physics, Faculty of Mathematics and Natural Sciences, Sebelas Maret University Jl. Ir. Sutami 36A Kentingan Surakarta 57126 (Indonesia); Nakahara, Hitoshi; Saito, Yahachi [Department of Quantum Engineering, Graduate School of Engineering, Nagoya University Furo-cho, Chikusa-ku, Nagoya 464-8603 (Japan); Ichimiya, Ayahiko [Department of Mathematical and Physical Science, Faculty of Science, Japan Women's University Mejirodai 2-8-1, Tokyo 112-8681 (Japan)

2011-12-10T23:59:59.000Z

279

Cleanup of hydrocarbon conversion system  

Science Conference Proceedings (OSTI)

This patent describes a process for the catalytic reforming of a substantially contaminant-free second hydrocarbon feed using a second reforming catalyst, in a catalytic-reforming system having equipment contaminated through contact with a contaminant-containing prior feed. It comprises: contacting the first hydrocarbon feed in the catalytic-reforming system at first reforming conditions with a first reforming catalyst until contaminant removal from the conversion system is substantially completed and the system is contaminant-free; thereafter replacing the first reforming catalyst in the contaminant-free catalytic-reforming system with a second reforming catalyst; and thereafter contacting the second hydrocarbon feed in the contaminant-free catalytic-reforming system with the second reforming catalyst at second reforming conditions.

Peer, R.L.; Russ, M.B.

1990-07-10T23:59:59.000Z

280

Enrichment of light hydrocarbon mixture  

Science Conference Proceedings (OSTI)

Light hydrocarbon enrichment is accomplished using a vertically oriented distillation column having a plurality of vertically oriented, nonselective micro/mesoporous hollow fibers. Vapor having, for example, both propylene and propane is sent upward through the distillation column in between the hollow fibers. Vapor exits neat the top of the column and is condensed to form a liquid phase that is directed back downward through the lumen of the hollow fibers. As vapor continues to ascend and liquid continues to countercurrently descend, the liquid at the bottom of the column becomes enriched in a higher boiling point, light hydrocarbon (propane, for example) and the vapor at the top becomes enriched in a lower boiling point light hydrocarbon (propylene, for example). The hollow fiber becomes wetted with liquid during the process.

Yang, Dali (Los Alamos, NM); Devlin, David (Santa Fe, NM); Barbero, Robert S. (Santa Cruz, NM); Carrera, Martin E. (Naperville, IL); Colling, Craig W. (Warrenville, IL)

2011-11-29T23:59:59.000Z

Note: This page contains sample records for the topic "methane nonmethane hydrocarbons" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Enrichment of light hydrocarbon mixture  

DOE Patents (OSTI)

Light hydrocarbon enrichment is accomplished using a vertically oriented distillation column having a plurality of vertically oriented, nonselective micro/mesoporous hollow fibers. Vapor having, for example, both propylene and propane is sent upward through the distillation column in between the hollow fibers. Vapor exits neat the top of the column and is condensed to form a liquid phase that is directed back downward through the lumen of the hollow fibers. As vapor continues to ascend and liquid continues to countercurrently descend, the liquid at the bottom of the column becomes enriched in a higher boiling point, light hydrocarbon (propane, for example) and the vapor at the top becomes enriched in a lower boiling point light hydrocarbon (propylene, for example). The hollow fiber becomes wetted with liquid during the process.

Yang; Dali (Los Alamos, NM); Devlin, David (Santa Fe, NM); Barbero, Robert S. (Santa Cruz, NM); Carrera, Martin E. (Naperville, IL); Colling, Craig W. (Warrenville, IL)

2010-08-10T23:59:59.000Z

282

Manifold methods for methane combustion  

SciTech Connect

Objective is to develop a new method for studying realistic chemistry in turbulent methane combustion with NO{sub x} mechanism. The realistic chemistry is a simplification to a more detailed chemistry based on the manifold method; accuracy is determined by interaction between the transport process and the chemical reaction. In this new (tree) method, probability density function or partially stirred reactor calculations are performed. Compared with the reduced mechanism, manifold, and tabulation methods, the new method overcomes drawbacks of the reduced mechanism method and preserves the advantages of the manifold method. Accuracy is achieved by specifying the size of the cell.

Yang, B.; Pope, S.B. [Cornell Univ., Ithaca, NY (United States)

1995-12-31T23:59:59.000Z

283

Biological enhancement of hydrocarbon extraction  

SciTech Connect

A method of microbial enhanced oil recovery for recovering oil from an oil-bearing rock formation is provided. The methodology uses a consortium of bacteria including a mixture of surfactant producing bacteria and non-surfactant enzyme producing bacteria which may release hydrocarbons from bitumen containing sands. The described bioprocess can work with existing petroleum recovery protocols. The consortium microorganisms are also useful for treatment of above oil sands, ground waste tailings, subsurface oil recovery, and similar materials to enhance remediation and/or recovery of additional hydrocarbons from the materials.

Brigmon, Robin L. (North Augusta, SC); Berry, Christopher J. (Aiken, SC)

2009-01-06T23:59:59.000Z

284

Detection and Production of Methane Hydrate  

Science Conference Proceedings (OSTI)

This project seeks to understand regional differences in gas hydrate systems from the perspective of as an energy resource, geohazard, and long-term climate influence. Specifically, the effort will: (1) collect data and conceptual models that targets causes of gas hydrate variance, (2) construct numerical models that explain and predict regional-scale gas hydrate differences in 2-dimensions with minimal 'free parameters', (3) simulate hydrocarbon production from various gas hydrate systems to establish promising resource characteristics, (4) perturb different gas hydrate systems to assess potential impacts of hot fluids on seafloor stability and well stability, and (5) develop geophysical approaches that enable remote quantification of gas hydrate heterogeneities so that they can be characterized with minimal costly drilling. Our integrated program takes advantage of the fact that we have a close working team comprised of experts in distinct disciplines. The expected outcomes of this project are improved exploration and production technology for production of natural gas from methane hydrates and improved safety through understanding of seafloor and well bore stability in the presence of hydrates. The scope of this project was to more fully characterize, understand, and appreciate fundamental differences in the amount and distribution of gas hydrate and how this would affect the production potential of a hydrate accumulation in the marine environment. The effort combines existing information from locations in the ocean that are dominated by low permeability sediments with small amounts of high permeability sediments, one permafrost location where extensive hydrates exist in reservoir quality rocks and other locations deemed by mutual agreement of DOE and Rice to be appropriate. The initial ocean locations were Blake Ridge, Hydrate Ridge, Peru Margin and GOM. The permafrost location was Mallik. Although the ultimate goal of the project was to understand processes that control production potential of hydrates in marine settings, Mallik was included because of the extensive data collected in a producible hydrate accumulation. To date, such a location had not been studied in the oceanic environment. The project worked closely with ongoing projects (e.g. GOM JIP and offshore India) that are actively investigating potentially economic hydrate accumulations in marine settings. The overall approach was fivefold: (1) collect key data concerning hydrocarbon fluxes which is currently missing at all locations to be included in the study, (2) use this and existing data to build numerical models that can explain gas hydrate variance at all four locations, (3) simulate how natural gas could be produced from each location with different production strategies, (4) collect new sediment property data at these locations that are required for constraining fluxes, production simulations and assessing sediment stability, and (5) develop a method for remotely quantifying heterogeneities in gas hydrate and free gas distributions. While we generally restricted our efforts to the locations where key parameters can be measured or constrained, our ultimate aim was to make our efforts universally applicable to any hydrate accumulation.

George Hirasaki; Walter Chapman; Gerald Dickens; Colin Zelt; Brandon Dugan; Kishore Mohanty; Priyank Jaiswal

2011-12-31T23:59:59.000Z

285

Arctic Methane, Hydrates, and Global Climate  

NLE Websites -- All DOE Office Websites (Extended Search)

Arctic Methane, Hydrates, and Global Climate Arctic Methane, Hydrates, and Global Climate Speaker(s): Matthew T. Reagan Date: March 17, 2010 - 12:00pm Location: 90-3122 Paleooceanographic evidence has been used to postulate that methane may have had a significant role in regulating past climate. However, the behavior of contemporary permafrost deposits and oceanic methane hydrate deposits subjected to rapid temperature changes, like those now occurring in the arctic and those predicted under future climate change scenarios, has only recently been investigated. A recent expedition to the west coast of Spitsbergen discovered substantial methane gas plumes exiting the seafloor at depths that correspond to the upper limit of the receding gas hydrate stability zone. It has been suggested that these plumes may be the

286

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Methane Recovery from Hydrate-bearing Sediments Last Reviewed 11/30/2011 Methane Recovery from Hydrate-bearing Sediments Last Reviewed 11/30/2011 DE-FC26-06NT42963 Goal The goal of this project is to develop observational and experimental data that can provide a better understanding of the basic mechanisms at work in a methane hydrate reservoir that is under production. To this end, a thorough physical understanding of underlying phenomena associated with methane hydrate production will be acquired through unique, multi-scale experiments and associated analyses. In addition, one or more mathematical models that account for the observed phenomena and provide insights that may help to optimize methane hydrate production methods will be developed. Performers Georgia Tech Research Corporation, Atlanta, Georgia 30332 Oak Ridge National Laboratory (ORNL), Oak Ridge, Tennessee 37831

287

Development of a Raman spectroscopy technique to detect alternate transportation fuel hydrocarbon intermediates in complex combustion environments.  

Science Conference Proceedings (OSTI)

Spontaneous Raman spectra for important hydrocarbon fuels and combustion intermediates were recorded over a range of low-to-moderate flame temperatures using the multiscalar measurement facility located at Sandia/CA. Recorded spectra were extrapolated to higher flame temperatures and then converted into empirical spectral libraries that can readily be incorporated into existing post-processing analysis models that account for crosstalk from overlapping hydrocarbon channel signal. Performance testing of the developed libraries and reduction methods was conducted through an examination of results from well-characterized laminar reference flames, and was found to provide good agreement. The diagnostic development allows for temporally and spatially resolved flame measurements of speciated hydrocarbon concentrations whose parent is more chemically complex than methane. Such data are needed to validate increasingly complex flame simulations.

Ekoto, Isaac W.; Barlow, Robert S.

2012-12-01T23:59:59.000Z

288

Catalytic Conversion of Bioethanol to Hydrocarbons ...  

Conventional biomass to hydrocarbon conversion is generally not commercially feasible, due to costs of the conversion process.

289

Hydrocarbons from plants and trees  

DOE Green Energy (OSTI)

The way energy was used in the US in 1980 was examined. A diagram shows the development of energy from its source to its end use. The following are described: the carbon dioxide problem - the greenhouse effect, sugar cane as an energy source, hydrocarbon-producing plants and trees, and isoprenoids from plants and trees. (MHR)

Calvin, M.

1982-07-01T23:59:59.000Z

290

Process and apparatus for the production of hydrogen by steam reforming of hydrocarbon  

DOE Patents (OSTI)

In the steam reforming of hydrocarbon, particularly methane, under elevated temperature and pressure to produce hydrogen, a feed of steam and hydrocarbon is fed into a first reaction volume containing essentially only reforming catalyst to partially reform the feed. The balance of the feed and the reaction products of carbon dioxide and hydrogen are then fed into a second reaction volume containing a mixture of catalyst and adsorbent which removes the carbon dioxide from the reaction zone as it is formed. The process is conducted in a cycle which includes these reactions followed by countercurrent depressurization and purge of the adsorbent to regenerate it and repressurization of the reaction volumes preparatory to repeating the reaction-sorption phase of the cycle.

Sircar, Shivaji (Wescosville, PA); Hufton, Jeffrey Raymond (Fogelsville, PA); Nataraj, Shankar (Allentown, PA)

2000-01-01T23:59:59.000Z

291

Screening and Ranking of Hydrocarbon Reservoirs for CO2 Storage in the Alberta Basin, Canada  

NLE Websites -- All DOE Office Websites (Extended Search)

Screening and Ranking of Hydrocarbon Reservoirs for CO Screening and Ranking of Hydrocarbon Reservoirs for CO 2 Storage in the Alberta Basin, Canada Stefan Bachu (Stefan.Bachu@gov.ab.ca; 780-427-1517) Alberta Energy and Utilities Board 4999-98 Avenue Edmonton, AB, T6B 2X3, Canada Introduction Human activity since the industrial revolution has had the effect of increasing atmospheric concentrations of gases with a greenhouse effect, such as carbon dioxide (CO 2 ) and methane (CH 4 ), leading to climate warming and weather changes (Bryant, 1997; Jepma and Munasinghe, 1998). Because of its relative abundance compared with the other greenhouse gases, CO 2 is by far the most important, being responsible for about 64% of the enhanced "greenhouse effect" (Bryant, 1997). Given their inherent advantages, such as availability, competitive cost, ease of

292

A Parameterized Interatomic Potential for Saturated Hydrocarbons ...  

Science Conference Proceedings (OSTI)

The experimental PVT data for methane, ethane, propane, and butane systems with different densities were predicted reasonably well by MEAM. Proceedings ...

293

Department of Energy Advance Methane Hydrates Science and Technology Projects  

Energy.gov (U.S. Department of Energy (DOE))

Descriptions for Energy Department Methane Hydrates Science and Technology Projects, August 31, 2012

294

Natural gas conversion to higher hydrocarbons using plasma interactions with surfaces. Final report  

DOE Green Energy (OSTI)

Experiments are reported in which a methane plasma is created, and the methyl ions and hydrogen ions are accelerated within a microchannel array so that they interact with neutral methane molecules on the inside surfaces of the microchannels. No catalysts are used, and the device operates at room temperature. Impact energies of the ions are in the range of 10 eV to greater than 100 eV, and the energy delivered in the interaction at the surfaces causes the production of larger hydrocarbon molecules, such as C{sub 2}H{sub 2}, C{sub 2}H{sub 4}, and C{sub 2}H{sub 6}, along with C{sub 3}, C{sub 4}, C{sub 5}m C{sub 6}, C{sub 7}m and C{sub 8} molecules. There is a decreasing percentage of larger molecules produced, in comparison with the C{sub 2} and C{sub 3} types. Conversion effectiveness is greater at higher pressure, due to the increased ionic activity. The yield of the higher hydrocarbons depends upon the external voltage used, and voltage can be used as a control parameter to adjust the output mixture proportions. A conversion energy of 2.59 kilowatt hours/killogram of output has been demonstrated, and a reduction of this by a factor of 10 is possible using known techniques. In batch experiments, the selectivity for C{sub 2} has varied from 47% to 88%, and selectivity for C{sub 6} has ranged from 0% to 12.8%. Other hydrocarbon selectivities also span a wide and useful range. The estimated costs for hydrocarbons produced with this technology are in the range of $200 per tonne, in production quantities, depending upon natural gas costs. Pilot production experiments are recommended to make these estimates more precise, and to address strategies for scaling the technology up to production levels. Applications are discussed.

Sackinger, W.M.; Kamath, V.A.; Morgan, B.L.; Airey, R.W.

1993-12-01T23:59:59.000Z

295

Remote sensor improves methane leakage surveys  

SciTech Connect

The remote sensing methane detector (RSMD) described in this paper is the result of a twelve year cooperative research program sponsored by the Columbia Gas System Service Corp., Environmental Research and Technology, Inc. and the Gas Research Institute. It is a hand-held, rechargeable battery-powered sensor that operates eight hours on one charge with a sensitivity very specific to methane. It can be scanned along the right of way to detect any methane in its path, up to at least 50 feet away. The RSMD is methane specific in that it only sense methane with minor sensitivity to ethane. This makes it particularly useful in industrial areas where present instruments are confused by solvents. It cannot be poisoned by silicones or leaded gasoline, since it is an optical system. When a cloud of methane has been detected by the RSMD, a sample cell attachment can be used to determine methane concentration in parts per million. A low power microcomputer is used in the RSMD to control its operation.

Eberle, A.C.; Kebabian, P.L.; Kruse, J.R.

1984-12-01T23:59:59.000Z

296

Methane oxidation over dual redox catalysts. Quarterly technical progress report, July--September 1989  

SciTech Connect

The objective of this research is to develop approaches to direct catalytic oxidation of methane over oxides that are doubly doped with transition metal ions. The desired process aims at employing a double redox mechanism, where one redox couple is utilized for activation of oxygen and another for the trapping of CH{sub 3} radicals. The methyl radicals can either recombine, giving C{sub 2} hydrocarbons, or be converted, via electron transfer reaction, to carbocations. The latter species can react with surface OH{sup {minus}} groups to form methanol or formaldehyde. To choose from several possible catalytic systems, this research initially involved the characterization of the micromorphology and crystalline dimensions of zinc oxide catalysts doped with Cu, Fe, and Sn by scanning electron microscopy. In addition, the determination of surface composition and oxidation states by X-ray photoelectron spectroscopy was carried out. A newly constructed high temperature catalytic testing system has been calibrated (flow meters and temperature controllers), tested for possible gas leaks and integrated with a gas chromatographic analytical unit. A preliminary catalytic test study over a Cu/Fe/ZnO sample was performed. The following products of the methane coupling reaction was found: C{sub 2}H{sub 6}, C{sub 2}H{sub 4} and H{sub 2}O together with CO{sub 2}. The maximum space time yield of 14 mmol C{sub 2} hydrocarbons/g cat/h was obtained at 848{degrees}C.

Klier, K.; Herman, R.G.; Sojka, Z.

1989-09-01T23:59:59.000Z

297

Syngas Upgrading to Hydrocarbon Fuels Technology Pathway  

DOE Green Energy (OSTI)

This technology pathway case investigates the upgrading of woody biomass derived synthesis gas (syngas) to hydrocarbon biofuels. While this specific discussion focuses on the conversion of syngas via a methanol intermediate to hydrocarbon blendstocks, there are a number of alternative conversion routes for production of hydrocarbons through a wide array of intermediates from syngas. Future work will also consider the variations to this pathway to determine the most economically viable and lowest risk conversion route. Technical barriers and key research needs have been identified that should be pursued for the syngas-to-hydrocarbon pathway to be competitive with petroleum-derived gasoline-, diesel- and jet-range hydrocarbon blendstocks.

Talmadge, M.; Biddy, M.; Dutta, A.; Jones, S.; Meyer, A.

2013-03-01T23:59:59.000Z

298

New Methane Hydrate Research: Investing in Our Energy Future | Department  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Methane Hydrate Research: Investing in Our Energy Future Methane Hydrate Research: Investing in Our Energy Future New Methane Hydrate Research: Investing in Our Energy Future August 31, 2012 - 1:37pm Addthis Methane hydrates are 3D ice-lattice structures with natural gas locked inside. If methane hydrate is either warmed or depressurized, it will release the trapped natural gas. Methane hydrates are 3D ice-lattice structures with natural gas locked inside. If methane hydrate is either warmed or depressurized, it will release the trapped natural gas. Jenny Hakun What Are Methane Hydrates? Methane hydrates are 3D ice-lattice structures with natural gas locked inside. The substance looks remarkably like white ice, but it does not behave like ice. If methane hydrate is either warmed or depressurized, it will release the trapped natural gas.

299

Methane Hydrates and Climate Change | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Hydrates and Climate Change Hydrates and Climate Change Methane Hydrates and Climate Change Methane hydrates store huge volumes of methane formed by the bacterial decay of organic matter or leaked from underlying oil and natural gas deposits. The active formation of methane hydrates in the shallow crust prevents methane, a greenhouse gas, from entering the atmosphere. On the other hand, warming of arctic sediments or ocean waters has the potential to cause methane hydrate to dissociate, releasing methane into the deepwater sediments, the ocean or atmosphere. DOE is conducting research to understand the mechanisms and volumes involved in these little-studied processes. DOE environmental and climate change research projects related to Arctic methane hydrate deposits include: Characterization of Methane Degradation and Methane-Degrading

300

Study of Methane Reforming in Warm Non-Equilibrium Plasma Discharges  

E-Print Network (OSTI)

Utilization of natural gas in remote locations necessitates on-site conversion of methane into liquid fuels or high value products. The first step in forming high value products is the production of ethylene and acetylene. Non-thermal plasmas, due to their unique nonequilibrium characteristics, offer advantages over traditional methods of methane reforming. Different kinds of non-thermal plasmas are being investigated for methane reforming. Parameters of these processes like flow rate, discharge size, temperature and other variables determine efficiency of conversion. An efficient process is identified by a high yield and low specific energy of production for the desired product. A study of previous work reveals that higher energy density systems are more efficient for methane conversion to higher hydrocarbons as compared to low energy density systems. Some of the best results were found to be in the regime of warm discharges. Thermal equilibrium studies indicate that higher yields of ethylene are possible with an optimal control of reaction kinetics and fast quenching. With this idea, two different glow discharge reactor systems are designed and constructed for investigation of methane reforming. A counter flow micro plasma discharge system was used to investigate the trends of methane reforming products and the control parameters were optimized to get best possible ethylene yields while minimizing its specific energy. Later a magnetic glow discharge system is used and better results are obtained. Energy costs lower than thermal equilibrium calculations were achieved with magnetic glow discharge systems for both ethylene and acetylene. Yields are obtained from measurements of product concentrations using gas chromatography and power measurements are done using oscilloscope. Energy balance and mass balances are performed for product measurement accuracy and carbon deposition calculations. Carbon deposition is minimized through control of the temperature and residence time conditions in magnetic glow discharges. Ethylene production is observed to have lower specific energies at higher powers and lower flow rates in both reactors. An ethylene selectivity of 40 percent is achieved at an energy cost of 458MJ/Kg and an input energy cost of 5 MJ/Kg of methane.

Parimi, Sreekar

2010-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "methane nonmethane hydrocarbons" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Diffusive Accumulation of Methane Bubbles in Seabed  

E-Print Network (OSTI)

We consider seabed bearing methane bubbles. In the absence of fractures the bubbles are immovably trapped in a porous matrix by surface tension forces; therefore the dominant mechanism of transfer of gas mass becomes the diffusion of gas molecules through the liquid. The adequate description of this process requires accounting "other-than-normal" (non-Fickian) diffusion effects, thermodiffusion and gravity action. We evaluate the diffusive flux of aqueous methane and predict the possibility of existence of bubble mass accumulation zones (which can appear independently from the presence/absence of hydrate stability zone) and effect of non-Fickian drift on the capacity of shallow and deep methane-hydrate deposits.

Goldobin, D S; Levesley, J; Lovell, M A; Rochelle, C A; Jackson, P; Haywood, A; Hunter, S; Rees, J

2010-01-01T23:59:59.000Z

302

METHOD FOR PRODUCING ISOTOPIC METHANES AND PARTIALLY HALOGENATED DERIVATIVES THEROF  

DOE Patents (OSTI)

A method is given for producing isotopic methanes and/ or partially halogenated derivatives. Lithium hydride, deuteride, or tritide is reacted with a halogenated methane or with a halogenated methane in combination with free halogen. The process is conveniently carried out by passing a halogenated methane preferably at low pressures or in an admixture with an inert gas through a fixed bed of finely divided lithium hydride heated initially to temperatures of 100 to 200 deg C depending upon the halogenated methane used.

Frazer, J.W.

1959-08-18T23:59:59.000Z

303

Flammability Characteristics of Hydrogen and Its Mixtures with Light Hydrocarbons at Atmospheric and Sub-atmospheric Pressures  

E-Print Network (OSTI)

Knowledge of flammability limits is essential in the prevention of fire and explosion. There are two limits of flammability, upper flammability limit (UFL) and lower flammability limit (LFL), which define the flammable region of a combustible gas/vapor. This research focuses on the flammability limits of hydrogen and its binary mixtures with light hydrocarbons (methane, ethane, n-butane, and ethylene) at sub-atmospheric pressures. The flammability limits of hydrogen, light hydrocarbons, and binary mixtures of hydrogen and each hydrocarbon were determined experimentally at room temperature (20şC) and initial pressures ranging from 1.0 atm to 0.1 atm. The experiments were conducted in a closed cylindrical stainless steel vessel with upward flame propagation. It was found that the flammable region of hydrogen initially widens when the pressure decreases from 1.0 atm to 0.3 atm, then narrows with the further decrease of pressure. In contrast, the flammable regions of the hydrocarbons narrow when the pressure decreases. For hydrogen and the hydrocarbons, pressure has a much greater impact on the UFLs than on the LFLs. For binary mixtures of hydrogen and the hydrocarbons, the flammable regions of all mixtures widen when the fraction of hydrogen in the mixture increases. When the pressure decreases, the flammable regions of all mixtures narrow. The applications of Le Chatelier’s rule and the Calculated Adiabatic Flame Temperature (CAFT) model to the flammability limits of the mixtures were verified. It was found that Le Chatelier’s rule could predict the flammability limits much better than the CAFT model. The adiabatic flame temperatures (AFTs), an important parameter in the risk assessment of fire and explosion, of hydrogen and the hydrocarbons were also calculated. The influence of sub-atmospheric pressures on the AFTs was investigated. A linear relationship between the AFT and the corresponding flammability limit is derived. Furthermore, the consequence of fire relating to hydrogen and the hydrocarbons is discussed based on the AFTs of the chemicals.

Le, Thuy Minh Hai

2013-08-01T23:59:59.000Z

304

Using Carbon Dioxide to Enhance Recovery of Methane from Gas Hydrate Reservoirs: Final Summary Report  

Science Conference Proceedings (OSTI)

Carbon dioxide sequestration coupled with hydrocarbon resource recovery is often economically attractive. Use of CO2 for enhanced recovery of oil, conventional natural gas, and coal-bed methane are in various stages of common practice. In this report, we discuss a new technique utilizing CO2 for enhanced recovery of an unconventional but potentially very important source of natural gas, gas hydrate. We have focused our attention on the Alaska North Slope where approximately 640 Tcf of natural gas reserves in the form of gas hydrate have been identified. Alaska is also unique in that potential future CO2 sources are nearby, and petroleum infrastructure exists or is being planned that could bring the produced gas to market or for use locally. The EGHR (Enhanced Gas Hydrate Recovery) concept takes advantage of the physical and thermodynamic properties of mixtures in the H2O-CO2 system combined with controlled multiphase flow, heat, and mass transport processes in hydrate-bearing porous media. A chemical-free method is used to deliver a LCO2-Lw microemulsion into the gas hydrate bearing porous medium. The microemulsion is injected at a temperature higher than the stability point of methane hydrate, which upon contacting the methane hydrate decomposes its crystalline lattice and releases the enclathrated gas. Small scale column experiments show injection of the emulsion into a CH4 hydrate rich sand results in the release of CH4 gas and the formation of CO2 hydrate

McGrail, B. Peter; Schaef, Herbert T.; White, Mark D.; Zhu, Tao; Kulkarni, Abhijeet S.; Hunter, Robert B.; Patil, Shirish L.; Owen, Antionette T.; Martin, P F.

2007-09-01T23:59:59.000Z

305

Direct conversion of methane to C sub 2 's and liquid fuels  

DOE Green Energy (OSTI)

The objectives of the project are to discover and evaluate novel catalytic systems for the conversion of methane or by-product light hydrocarbon gases either indirectly (through intermediate light gases rich in C{sub 2}'s) or directly to liquid hydrocarbon fuels, and to evaluate, from an engineering perspective, different conceptualized schemes. The approach is to carry out catalyst testing on several specific classes of potential catalysts for the conversion of methane selectively to C{sub 2} products. The behavior of alkaline earth/metal oxide/halide catalysts containing strontium was found to be different from the behavior of catalysts containing barium. Two approaches were pursued to avoid the heterogeneous/homogeneous mechanism in order to achieve higher C{sub 2} selectivity/methane conversion combinations. One approach was to eliminate or minimize the typical gas phase combustion chemistry and make more of the reaction occur on the surface of the catalyst by using silver. Another approach was to change the gas phase chemistry to depart from the typical combustion reaction network by using vapor-phase catalysts. The layered perovskite K{sub 2}La{sub 2}Ti{sub 3}O{sub 10} was further studied. Modifications of process and catalyst variables for LaCaMnCoO{sub 6} catalysts resulted in catalysts with superior performance. Results obtained with a literature catalyst Na{sub 2}CO{sub 3}/Pr{sub 6}O{sub 11} were better than those obtained with NaCO{sub 3}/Pr-Ce oxide or Na{sub 2}CO{sub 3}/Ag-Pr-Ce oxide. 52 refs., 15 figs., 9 tabs.

Warren, B.K.; Campbell, K.D.; Matherne, J.L.; Kinkade, N.E.

1990-03-12T23:59:59.000Z

306

Production and Ebullition of Methane in a Shallow Eutrophic Lake (Lake Elsinore, CA)  

E-Print Network (OSTI)

monoxide, methane, carbon dioxide and total gaseous mercuryFluxes of methane and carbon dioxide from a small productiveebullition of methane and carbon dioxide from a eutrophied

Martinez, Denise Nicole

2012-01-01T23:59:59.000Z

307

Hydrogen Safety Issues Compared to Safety Issues with Methane and Propane  

E-Print Network (OSTI)

Issues with Methane and Propane Michael A. Green LawrenceSAFETY ISSUES WITH METHANE AND PROPANE M. A. Green Lawrencehydrogen. Methane and propane are commonly used by ordinary

Green, Michael A.

2005-01-01T23:59:59.000Z

308

Hydrocarbon Technologies | Open Energy Information  

Open Energy Info (EERE)

Hydrocarbon Technologies Hydrocarbon Technologies Place Lawrenceville, New Jersey Zip 8648 Sector Efficiency Product String representation "Technology-base ... onmental risks." is too long. Coordinates 36.761678°, -77.845048° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":36.761678,"lon":-77.845048,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

309

Methane Digester Loan Program | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Methane Digester Loan Program Methane Digester Loan Program Methane Digester Loan Program < Back Eligibility Agricultural Savings Category Bioenergy Maximum Rebate RFA can provide up to $250,000 of loan principal Program Info Funding Source Minnesota Rural Finance Authority (RFA) State Minnesota Program Type State Loan Program Rebate Amount RFA participation limited to 45% of loan principal Provider Minnesota Department of Agriculture Established in 1998, the Minnesota Dept. of Agriculture Methane Digester Loan Program helps livestock producers install on-farm anaerobic digesters used for the production of electricity by providing zero-interest loans to eligible borrowers. The loan program is part of the Rural Finance Authority (RFA) revolving loan fund, through which farmers can receive financial aid

310

Methane Hydrate Program Annual Report to Congress  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

FY 2010 FY 2010 Methane Hydrate Program Annual Report to Congress September 2011 U.S. Department of ENERGY United States Department of Energy Washington, DC 20585 Department of Energy | September 2011 FY 2010 Methane Hydrate Program Annual Report to Congress | Page 2 Message from the Secretary Section 968 of the Energy Policy Act of 2005 requires the Department of Energy to submit to Congress an annual report on the results of methane hydrate research. I am pleased to submit the enclosed report entitled, U.S. Department of Energy FY 2010 Methane Hydrate Program Report to Congress. The report was prepared by the Department of Energy's Office of Fossil Energy and summarizes the progress being made in this important area of

311

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Laboratory Studies in Support of Characterization of Recoverable Resources from Methane Hydrate Deposits Last Reviewed 5/10/2012 Laboratory Studies in Support of Characterization of Recoverable Resources from Methane Hydrate Deposits Last Reviewed 5/10/2012 ESD05-048 Goal The project is bringing new laboratory measurements and evaluation techniques to bear on the difficult problems of characterization and gas recovery from methane hydrate deposits. Performer Lawrence Berkeley National Laboratory, Berkeley, CA 94720 Background LBNL is performing laboratory tests to provide data to support the characterization and development of methane hydrate deposits. Major areas of research underway include hydrologic measurements, combined geomechanical/geophysical measurements, and synthetic hydrate formation studies. Hydrologic Measurements Relatively little research has been done to experimentally determine

312

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Collection and Microbiological Analysis of Gas Hydrate Cores Collection and Microbiological Analysis of Gas Hydrate Cores FWP-4340-60 and FWP-42C1-01 Goal Determine the presence and activity of methanogens in methane hydrate-bearing sediments. Background The project was set up to determine a fundamental modeling parameter - the amount of methane generated in deep sediments by methanogenic microorganisms. This would allow methane distribution models of gas hydrate reservoirs to accurately reflect an unknown volume and the distribution of biogenic methane within in a reservoir. The personnel at INEL have experience in similar biologic research and are considered to be experts by their global peers. Performer Idaho National Engineering and Environmental Laboratory (INEEL) - sample collection and analysis Location

313

Arkansas Coalbed Methane Production (Billion Cubic Feet)  

Annual Energy Outlook 2012 (EIA)

Production (Billion Cubic Feet) Arkansas Coalbed Methane Production (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 2 3 3 3...

314

Alabama Coalbed Methane Production (Billion Cubic Feet)  

Gasoline and Diesel Fuel Update (EIA)

Production (Billion Cubic Feet) Alabama Coalbed Methane Production (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 23...

315

Kansas Coalbed Methane Production (Billion Cubic Feet)  

Annual Energy Outlook 2012 (EIA)

Production (Billion Cubic Feet) Kansas Coalbed Methane Production (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 17 25 38...

316

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Sampling and Characterization of Naturally Occurring Methane Hydrate Using the DV JOIDES Resolution Last Reviewed 02052010 DE-FC26-01NT41329 photo of a man showing the pressure...

317

Virginia Coalbed Methane Production (Billion Cubic Feet)  

Annual Energy Outlook 2012 (EIA)

Production (Billion Cubic Feet) Virginia Coalbed Methane Production (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 56 81...

318

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

that the hydrate in this region occurs in patchy deposits and may require a high methane flux from the subsurface in order to form more continuous drilling prospects. Project...

319

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

DE-AF26-01NT00370 Goal The goal of the project is to better characterize potential methane hydrate drilling sites in the Gulf of Mexico for the Ocean Drilling Program....

320

Wyoming Coalbed Methane Production (Billion Cubic Feet)  

Gasoline and Diesel Fuel Update (EIA)

Production (Billion Cubic Feet) Wyoming Coalbed Methane Production (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 133 278...

Note: This page contains sample records for the topic "methane nonmethane hydrocarbons" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

area, known as Mississippi Canyon lease block 118, is well-known for the occurrence of methane hydrate and is the location of the University of Mississippis gas hydrate...

322

Oklahoma Coalbed Methane Production (Billion Cubic Feet)  

Gasoline and Diesel Fuel Update (EIA)

Production (Billion Cubic Feet) Oklahoma Coalbed Methane Production (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 58 68...

323

Methane Hydrates - Mt. Elbert Well Log Data  

NLE Websites -- All DOE Office Websites (Extended Search)

more. Project background information - Alaska North Slope Gas Hydrate Reservoir Characterization - DE-FC26-01NT41332 More information on the National Methane Hydrates R&D Program...

324

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

FWP-4340-60 and FWP-42C1-01 Goal Determine the presence and activity of methanogens in methane hydrate-bearing sediments. Background The project was set up to determine a...

325

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

of high chloride concentration and no sulfate reduction zone, indicating areas of high methane flux. The February 2005 RV Pelican cruise was a follow-up to the May 2004 cruise....

326

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Efficacy of the Aerobic Methanotropic Biofilter in Methane Hydrate Environments Last Reviewed 182013 DE-NT0005667 Goal The goal of this project is to assess the efficacy of...

327

Montana Coalbed Methane Production (Billion Cubic Feet)  

Annual Energy Outlook 2012 (EIA)

Production (Billion Cubic Feet) Montana Coalbed Methane Production (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 12 12 13...

328

Pennsylvania Coalbed Methane Production (Billion Cubic Feet)  

Annual Energy Outlook 2012 (EIA)

Production (Billion Cubic Feet) Pennsylvania Coalbed Methane Production (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 3 5...

329

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

to develop a two-dimensional, basin-scale model for the deep sediment biosphere with methane dynamics to provide a better picture of the distribution of hydrates on the sea floor...

330

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Goal The overall objective of this project is to develop a new method to assess methane hydrate distribution using 3-D seismic data calibrated to wellbore data. The method...

331

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Production of Methane Hydrate Last Reviewed 5152012 DE-FC26-06NT42960 Goal The goal of this project is to improve the understanding of regional and local differences in gas...

332

The role of methane in tropospheric chemistry  

E-Print Network (OSTI)

While methane is chemically quite inert to reactions with atmospheric molecular species, it does react with atomic species and molecular radicals. Because of its relatively large abundance in the global troposphere and ...

Golomb, D.

1989-01-01T23:59:59.000Z

333

Deep desulfurization of hydrocarbon fuels  

SciTech Connect

The invention relates to processes for reducing the sulfur content in hydrocarbon fuels such as gasoline, diesel fuel and jet fuel. The invention provides a method and materials for producing ultra low sulfur content transportation fuels for motor vehicles as well as for applications such as fuel cells. The materials and method of the invention may be used at ambient or elevated temperatures and at ambient or elevated pressures without the need for hydrogen.

Song, Chunshan (State College, PA); Ma, Xiaoliang (State College, PA); Sprague, Michael J. (Calgary, CA); Subramani, Velu (State College, PA)

2012-04-17T23:59:59.000Z

334

Catalyst for utilization of methane in selective catalytic reduction of NO{sub x}, Task 2.6  

DOE Green Energy (OSTI)

Selective catalytic reduction (SCR) of nitrogen oxides(NO{sub x}) in flue gas or engine exhaust gas with hydrocarbons as the reductant has great potential for less expense, less pollution, and easier operation than SCR with ammonia. Methane is the preferred reducing gas because of its low cost and low toxicity. Stable, low-cost catalysts for SCR with methane are required to demonstrate this technology for controlling NO{sub x} emissions. Several cobalt and nickel catalysts on synthetic clay and uranium oxide supports were investigated for their activities in reducing NO{sub x} with methane in the presence of air. The efficiency of the synthetic clay-supported nickel and cobalt catalysts for nitric oxide (NO) reduction with methane as the reducing gas was poor. The nickel oxide-uranium oxide catalyst, which was chosen for its high stability, was also ineffective. Results from the two-step experiments conducted at two-temperatures produced some interesting information on the reactions of methane with the catalysts and the reactivity of the carbonaceous intermediate. The carbonaceous material formed from methane dissociation at 450{degrees}C not only reduces NO to N{sub 2}O at lower temperatures, but also prevents oxidation of NO to NO{sub 2}. Unfortunately, the carbonaceous forms that reduce the NO are not available for reactions at 400{degrees}C in the presence of oxygen. A two-step process employing this chemistry would be difficult because the catalyst would have to be cycled between the two temperatures. Also the desired reduction to nitrogen is not very efficient.

Olson, E.S.; Sharma, R.K.

1996-02-01T23:59:59.000Z

335

Methane level rise blamed in greenhouse effect  

SciTech Connect

As scientists continue to probe effects of global warming trends and the greenhouse effect, increasing attention is being placed on the impact of methane. Last year, scientists at the University of California in Irvine found there were almost 1.7 parts per million of methane in the troposphere- 11% higher that a decade ago and climbing at 1% annually. European scientists came up with similar analyses, and the belief is that methane is currently 2.4 times higher than it has ever been in the last 160,000 years. The big challenge now is to identify the sources of the methane. About 15 to 20% can be traced to oil and gas wells, coal mining and other tapping of the gas trapped in the planet's crust. Other sources are bacteria working in tropical rain forests, burned-off clearings, etc. Cattle figure high on the list of methane generators. When domesticated herds of sheep, goats, pigs, etc. are figured, the total rises to 73 million metric tons per year- a 435% increase since 1890. Rice paddies are also rated a major source of methane. It's estimated that 115 million metric tons rise from rice paddies a year, as much as is coming from natural swamps and wetlands. When scientists added up all the published estimates of methane production, the total ranged from 400 million to 640 million metric tons a year. Estimates of how much methane the atmosphere can handle are similarly uncertain, ranging from 300 million to 650 million metric tons a year.

1989-01-01T23:59:59.000Z

336

Predicting methane accumulations generated from humic Carboniferous coals in the Donbas fold belt (Ukraine)  

Science Conference Proceedings (OSTI)

The numerical modeling of the Ukrainian part of the Donbas fold belt indicates that the coalification pattern was controlled mainly by the maximum burial depth of coal seams and the heat flow (HF) (40-75 mW/m{sup 2}) during the Permian. The coalification pattern was overprinted by magmatic events during the Late Permian in the south syncline (150 mW/m{sup 2}) and during the Permian-Triassic in the north of the Krasnoarmeisk region (120 mW/m{sup 2}). The coalification pattern shows a strong increase in vitrinite reflectance values toward the east and southeastern parts of the study area likely caused by (1) an eastward increase in burial depth, (2) a probable eastward increase in HF, and, (3) probable magmatic activity. An increase in total erosion toward the eastern and southeastern parts was also observed with a maximum erosional amount of approximately 8 km (5 mi) in the southeastern part of the study area. The basin modeling of this area predicts that the main phase of hydrocarbon generation occurred during the Carboniferous-Early Permian subsidence. The magmatic events that occurred during the Permian-Triassic caused renewed pulses of hydrocarbon generation. A large amount of the generated hydrocarbons was lost to the surface because of a lack of seals. However, the numerical simulation predicts accumulations of about 2 tcf (57 billion m{sup 3}) of methane generated from Carboniferous coals in the south and main synclines, where Lower Permian seal rocks are preserved. Finally, this study provides data on methane resources along the northern flank

Alsaab, D.; Elie, M.; Izart, A.; Sachsenhofer, R.F.; Privalov, V.A. [Paradigm Co., Nancy (France)

2008-08-15T23:59:59.000Z

337

Development and demonstration of advanced technologies for direct electrochemical oxidation of hydrocarbons (methanol, methane, propane)  

SciTech Connect

Direct methanol fuel cells use methanol directly as a fuel, rather than the reformate typically required by fuel cells, thus eliminating the reformer and fuel processing train. In this program, Giner, Inc. advanced development of two types of direct methanol fuel cells for military applications. Advancements in direct methanol proton-exchange membrane fuel cell (DMPEMFC) technology included developement of a Pt-Ru anode catalyst and an associated electrode structure which provided some of the highest DMPEMFC performance reported to date. Scale-up from a laboratory-scale single cell to a 5-cell stack of practical area, providing over 100 W of power, was also demonstrated. Stable stack performance was achieved in over 300 hours of daily on/off cycling. Direct methanol aqueous carbonate fuel cells were also advanced with development of an anode catalyst and successful operation at decreased pressure. Improved materials for the cell separator/matrix and the hardware were also identified.

Kosek, J.A.; LaConti, A.B.

1994-07-01T23:59:59.000Z

338

Methane cracking over a bituminous coal char  

Science Conference Proceedings (OSTI)

Methane cracking over a bed of Chinese bituminous coal char was studied using a fixed-bed reactor at atmospheric pressure and temperatures between 1073 and 1223 K. Methane conversion over the fresh char increased with increasing temperature to 90% at 1223 K. Hydrogen was the only gas-phase product that was detected during the experimentation. The char was shown to exert a significant catalytic effect on methane cracking by comparing results from experiments with the raw char and demineralised char as well as from blank experiments using quartz. It was further shown that the ash was not the source of the catalytic effect of the char. However, both methane conversion and hydrogen yield decreased with increasing reaction time, irrespective of other experimental conditions, indicating that the char rapidly became deactivated following the exposure to methane. It was speculated that the deposition of carbon from methane cracking was responsible for this deactivation, which is supported by scanning electron microscopy (SEM) image analysis. It was demonstrated that the catalytic activity of the deactivated char can be partially recovered by burning off the carbon deposits with an oxidizing gas mixture containing 0.46% oxygen. 10 refs., 11 figs., 1 tab.

Zhi-qiang Sun; Jin-hu Wu; Mohammad Haghighi; John Bromly; Esther Ng; Hui Ling Wee; Yang Wang; Dong-ke Zhang [Chinese Academy of Sciences, Taiyuan (China). Institute of Coal Chemistry

2007-06-15T23:59:59.000Z

339

Pore accessibility of methane and carbon dioxide in coals  

Science Conference Proceedings (OSTI)

Two Australian coals were heat-treated, and the accessibility of the pore space to CH{sub 4} and CO{sub 2} was investigated. Samples heat-treated at 573 and 673 K exhibit larger adsorption/desorption hysteresis and smaller surface areas (measured by CO{sub 2} adsorption at 273 K) than untreated samples. For samples heat-treated at 773 K, however, the surface area increased by 50% and the hysteresis was lower, compared to untreated samples. These results demonstrate that volatile hydrocarbons at pore mouths are the cause of energy barriers that prevent adsorbing molecules from passing through. A conceptual model is proposed to illustrate changes in activation energy at constricted pore mouths. Also, the results suggest that both adsorption and desorption isotherms should be measured to determine kinetically inaccessible pore spaces in order to correctly estimate CH{sub 4} recovery and CO{sub 2} storage capacity. The results have importance to the problem of estimating CH{sub 4} recovery and CO{sub 2} storage capacity for CO{sub 2} geosequestration as part of a CO{sub 2}-enhanced coal bed methane recovery operation. 28 refs., 11 figs., 5 tabs.

Jun-Seok Bae; Suresh K. Bhatia; Victor Rudolph; Paul Massarotto [University of Queensland, Qld. (Australia). Division of Chemical Engineering

2009-05-15T23:59:59.000Z

340

Coke profile and effect on methane/ethylene conversion process  

E-Print Network (OSTI)

The objective of this study was to investigate the coke profile with respect to time on stream and the change of product distribution due to catalyst deactivation. A fixed bed reactor was used to conduct this investigation. A series of runs were conducted using the Engelhard catalyst with fixed operating conditions. The only variable was the time on stream of each run. Six experiments were conducted starting with one hour time on stream up to six hours with an increment of one hour. In each experiment data on product flow rate, reactor temperature, and product distribution were collected. And at the end of each run, the amount of coke deposited on the catalyst was measured. Hydrogen concentration in the product distribution decreased as a function of time on stream. On the other hand, low and high end hydrocarbons increased with time on stream. The coke deposition kinetics for the catalyst at the process operating conditions can be estimated using Voorhies' empirical formula. The coke profile inside the reactor showed that the coke reaction follows a parallel mechanism to the main reaction. Ethylene was found to be the main coke precursor; however, the participation of methane in the coke reaction could not be neglected.

Al-Solami, Bandar

2002-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "methane nonmethane hydrocarbons" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Capture and Use of Coal Mine Ventilation-Air Methane  

NLE Websites -- All DOE Office Websites (Extended Search)

Capture and use of Coal Mine Capture and use of Coal Mine Ventilation - air Methane Background Methane emissions from coal mines represent about 10 percent of the U.S. anthropogenic methane released to the atmosphere. Methane-the second most important non-water greenhouse gas-is 21 times as powerful as carbon dioxide (CO 2 ) in its global warming potential. Ventilation-air methane (VAM)-the exhaust air from underground coal mines-is the largest source of coal mine methane, accounting for about half of the methane emitted from coal mines in the United States. Unfortunately, because of the low methane concentration (0.3-1.5 percent) in ventilation air, its beneficial use is difficult. However, oxidizing the methane to CO 2 and water reduces its global warming potential by 87 percent. A thermal

342

Process, including membrane separation, for separating hydrogen from hydrocarbons  

DOE Patents (OSTI)

Processes for providing improved methane removal and hydrogen reuse in reactors, particularly in refineries and petrochemical plants. The improved methane removal is achieved by selective purging, by passing gases in the reactor recycle loop across membranes selective in favor of methane over hydrogen, and capable of exhibiting a methane/hydrogen selectivity of at least about 2.5 under the process conditions.

Baker, Richard W. (Palo Alto, CA); Lokhandwala, Kaaeid A. (Union City, CA); He, Zhenjie (Fremont, CA); Pinnau, Ingo (Palo Alto, CA)

2001-01-01T23:59:59.000Z

343

Separation and Purification of Methane from coal-Bed Methane via the Hydrate Technology  

Science Conference Proceedings (OSTI)

The separation of methane from coal-bed methane (CBM) via hydrate process using tetrahydrofuran (THF) + sodium dodecyl sulfate (SDS) as additives was investigated in this work. The effect of additives, the concentration of the additives and hydrate memory ... Keywords: CBM, hydrate, separation, THF, SDS

Cai Jing; Chen Zhaoyang; Li Xiaosen; Xu Chungang

2010-12-01T23:59:59.000Z

344

HYDROCARBON AND SULFUR SENSORS FOR SOFC SYSTEMS  

DOE Green Energy (OSTI)

The following report summarizes work conducted during the Phase I program Hydrocarbon and Sulfur Sensors for SOFC Systems under contract No. DE-FC26-02NT41576. For the SOFC application, sensors are required to monitor hydrocarbons and sulfur in order to increase the operation life of SOFC components. This report discusses the development of two such sensors, one based on thick film approach for sulfur monitoring and the second galvanic based for hydrocarbon monitoring.

A.M. Azad; Chris Holt; Todd Lesousky; Scott Swartz

2003-11-01T23:59:59.000Z

345

Selective methane oxidation over promoted oxide catalysts. Quarterly technical progress report, September 8, 1992--November 30, 1992  

DOE Green Energy (OSTI)

Support effects on catalytic reactions, especially of highly exothermic oxidation reactions, can be very significant. Since we had shown that a MoO{sub 3}/SiO{sub 2} catalyst, especially when used in a double bed configuration with a Sr/La{sub 2}O{sub 3} catalyst, can selectively oxidize methane to formaldehyde, the role of the SiO{sub 2} support was investigated. Therefore, partial oxidation of methane by oxygen to form formaldehyde, carbon oxides, and C{sub 2} products (ethane and ethene) has been studied over silica catalyst supports (fumed Cabosil and Grace 636 silica gel) in the 630-780{degrees}C temperature range under ambient pressure. When relatively high gas hourly space velocities (GHSV) were utilized, the silica catalysts exhibit high space time yields (at low conversions) for methane partial oxidation to formaldehyde, and the C{sub 2} hydrocarbons were found to be parallel products with formaldehyde. In general, the selectivities toward CO were high while those toward CO{sub 2} were low. Based on the present results obtained by a double catalyst bed experiment, the observations of product composition dependence on the variation of GHSV (i.e. gas residence time), and differences in apparent activation energies of formation of C{sub 2}H{sub 6}, and CH{sub 2}O, a reaction mechanism is proposed for the activation of methane over the silica surface. This mechanism can explain the observed product distribution patterns (specifically the parallel formation of formaldehyde and C{sub 2} hydrocarbons).

Klier, K.; Herman, R.G.; Sun, Q.; Sarkany, J.

1993-01-01T23:59:59.000Z

346

Extracting value from coal mine methane  

Science Conference Proceedings (OSTI)

Emerging US policy to regulate greenhouse gas (GHG) emissions through a cap-and-trade program presents mine managers with a new opportunity to explore and develop methane utilization or abatement projects that generate value from the anodization of carbon offset credits. In addition, the rising focus on US energy security and domestic energy supply is promoting mine managers and engineers to give further consideration to the importance of their methane gas by-products. The market through which coal mine methane offset projects can be developed and carbon offset credits monetized is quickly maturing. While many methane utilization projects have previously been uneconomical, the carbon offset credit market provides a new set of financing tools for mine engineers to capitalize these projects today. Currently , there are two certification programs that have approved project protocols for CMM projects. The Voluntary Carbon Standard (VCS) offers a methodology approved under the Clean Development Mechanism, the international compliance based offset market under the Kyoto Protocol. The VCS protocol is applicable to projects that combust ventilation air methane (VAM) and methane extracted from pre-and post-mine drainage systems. The Chicago Climate Exchange (CCX), which operates a voluntary yet binding cap-and-trade market, also has an approved protocol for CMM projects. CCX's protocol can be applied to projects combusting VAM, and methane extracted from pre-and-post-mine drainage systems, as well as abandoned mines. The article describes two case studies - Developing a gob gas utilization project financed by carbon offset credits and First VAM oxidation system to be commissioned at an operating mine in the US. 1 tab., 4 photos.

Liebert, B. [Verdao Group (United States)

2009-06-15T23:59:59.000Z

347

Catalytic Conversion of Bioethanol to Hydrocarbons  

ORNL 2011-G00219/jcn UT-B ID 201002414 08.2011 Catalytic Conversion of Bioethanol to Hydrocarbons Technology Summary A method for catalytically converting an alcohol ...

348

Membrane separation of hydrocarbons using cycloparaffinic solvents  

DOE Patents (OSTI)

Heavy crude oils which contain metal contaminants such as nickel, vanadium and iron may be separated from light hydrocarbon oils by passing a solution of the crude oil dissolved in a cycloparaffinic hydrocarbon solvent containing from about 5 to about 8 carbon atoms by passing through a polymeric membrane which is capable of maintaining its integrity in the presence of hydrocarbon compounds. The light hydrocarbon oils which possess relatively low molecular weights will be recovered as the permeate while the heavy oils which possess relatively high molecular weights as well as the metal contaminants will be recovered as the retentate.

Kulkarni, Sudhir S. (Hoffman Estates, IL); Chang, Y. Alice (Westmont, IL); Gatsis, John G. (Des Plaines, IL); Funk, Edward W. (Highland Park, IL)

1988-01-01T23:59:59.000Z

349

Catalytic Conversion of Bioethanol to Hydrocarbons  

ORNL 2011-G00219/jcn UT-B ID 201002414 08.2011 Catalytic Conversion of Bioethanol to Hydrocarbons Technology Summary A method for catalytically ...

350

Nox reduction system utilizing pulsed hydrocarbon injection  

DOE Patents (OSTI)

Hydrocarbon co-reductants, such as diesel fuel, are added by pulsed injection to internal combustion engine exhaust to reduce exhaust NO.sub.x to N.sub.2 in the presence of a catalyst. Exhaust NO.sub.x reduction of at least 50% in the emissions is achieved with the addition of less than 5% fuel as a source of the hydrocarbon co-reductants. By means of pulsing the hydrocarbon flow, the amount of pulsed hydrocarbon vapor (itself a pollutant) can be minimized relative to the amount of NO.sub.x species removed.

Brusasco, Raymond M. (Livermore, CA); Penetrante, Bernardino M. (San Ramon, CA); Vogtlin, George E. (Fremont, CA); Merritt, Bernard T. (Livermore, CA)

2001-01-01T23:59:59.000Z

351

Membrane separation of hydrocarbons using cycloparaffinic solvents  

DOE Patents (OSTI)

Heavy crude oils which contain metal contaminants such as nickel, vanadium and iron may be separated from light hydrocarbon oils by passing a solution of the crude oil dissolved in a cycloparaffinic hydrocarbon solvent containing from about 5 to about 8 carbon atoms by passing through a polymeric membrane which is capable of maintaining its integrity in the presence of hydrocarbon compounds. The light hydrocarbon oils which possess relatively low molecular weights will be recovered as the permeate while the heavy oils which possess relatively high molecular weights as well as the metal contaminants will be recovered as the retentate.

Kulkarni, S.S.; Chang, Y.A.; Gatsis, J.G.; Funk, E.W.

1988-06-14T23:59:59.000Z

352

Variability of Gas Composition and Flux Intensity in Natural Marine Hydrocarbon Seeps  

E-Print Network (OSTI)

2 Methane Ethane Propane Butane nd nd nd nd October 4, 2004methane, ethane, propane, and butane. Methods The flux buoyfor methane, ethane, propane, butane, oxygen, nitrogen, and

Clark, J F; Schwager, Katherine; Washburn, Libe

2005-01-01T23:59:59.000Z

353

Methane Power Inc | Open Energy Information  

Open Energy Info (EERE)

Methane Power Inc Methane Power Inc Jump to: navigation, search Logo: Methane Power Inc. Name Methane Power Inc. Address 121 Edinburgh South Drive Place Cary, NC Zip 27511 Sector Renewable Energy Product Methane Power is a renewable energy project developer that focuses on landfill gas-to-energy projects. Currently, they are a supplier of landfill gas generated energy to Duke Energy in North Carolina. Phone number 919-297-7206 Website http://www.methanepower.net Coordinates 35.7395875°, -78.8029226° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":35.7395875,"lon":-78.8029226,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

354

Coal bed methane global market potential  

Science Conference Proceedings (OSTI)

Worldwide increases in energy prices, as well as the increased potential for project financing derived from emissions credits, have renewed focus on coal bed methane (CBM) and coal mine methane (CMM) projects in coal-producing countries around the world. Globally, CBM utilization projects (in the operational, development, or planning stages) capture and utilize methane from gassy underground coal mines in at least 13 countries. The total methane emission reductions that could be achieved by these projects are approximately 135 billion cubic feet per year (equal to 14.8 million tons of carbon equivalent per year). This global activity level reflects a growing awareness of the technological practicality and the economic attractiveness of coal mine methane recovery and use. This report outlines the potential of the global CBM market. Contents: An overview of CBM; Challenges and issues; Technologies to generate power from CAM; Global CBM/CMM utilization; Country highlights; Ranking of countries with the largest CMM development potential (Australia, Canada, China, Germany, Mexico, Poland, Russia, Ukraine, United Kingdom, USA, Bulgaria, Czech Republic, France, India, Japan, Kazakhstan, South Africa); Planning CBM/CMM projects; Pre-feasibility and feasibility studies; Demonstration projects; Development plan and application process; Equity and debt; Carbon financing; Government sponsors; Private sponsors; Project risk reduction support; Examples of integrated project financing; Glossary.

Drazga, B. (ed.)

2007-01-16T23:59:59.000Z

355

ANALYSIS OF METHANE PRODUCING COMMUNITIES WITHIN UNDERGROUND COAL BEDS  

E-Print Network (OSTI)

ANALYSIS OF METHANE PRODUCING COMMUNITIES WITHIN UNDERGROUND COAL BEDS by Elliott Paul Barnhart.........................................................................................8 Coal and Metabolite Enrichment Studies ..................................................................................14 Ability of the Consortium to Produce Methane from Coal and Metabolites ................16

Maxwell, Bruce D.

356

MARINE BIOMASS SYSTEM: ANAEROBIC DIGESTION AND PRODUCTION OF METHANE  

E-Print Network (OSTI)

The basic energy conversion system being considered in thisEnergy Fixation and Conversion with Algal Bacterial Systems/energy producer based on current methane prices. bility of a kelp to methane conversion system

Haven, Kendall F.

2011-01-01T23:59:59.000Z

357

On the Sources of Methane to the Los Angeles Atmosphere  

NLE Websites -- All DOE Office Websites (Extended Search)

On the Sources of Methane to the Los Angeles Atmosphere Title On the Sources of Methane to the Los Angeles Atmosphere Publication Type Journal Article Year of Publication 2012...

358

Kansas Coalbed Methane Proved Reserves (Billion Cubic Feet)  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet) Kansas Coalbed Methane Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

359

Oklahoma Coalbed Methane Proved Reserves (Billion Cubic Feet...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet) Oklahoma Coalbed Methane Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

360

Ohio Coalbed Methane Proved Reserves (Billion Cubic Feet)  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet) Ohio Coalbed Methane Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

Note: This page contains sample records for the topic "methane nonmethane hydrocarbons" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

New Mexico--West Coalbed Methane Proved Reserves (Billion Cubic...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet) New Mexico--West Coalbed Methane Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6...

362

Eastern States Coalbed Methane Proved Reserves (Billion Cubic...  

Annual Energy Outlook 2012 (EIA)

Eastern States Coalbed Methane Proved Reserves (Billion Cubic Feet) Eastern States Coalbed Methane Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4...

363

Western States Coalbed Methane Proved Reserves (Billion Cubic...  

Annual Energy Outlook 2012 (EIA)

Western States Coalbed Methane Proved Reserves (Billion Cubic Feet) Western States Coalbed Methane Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4...

364

New Mexico Coalbed Methane Proved Reserves (Billion Cubic Feet...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet) New Mexico Coalbed Methane Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

365

Pennsylvania Coalbed Methane Proved Reserves (Billion Cubic Feet...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet) Pennsylvania Coalbed Methane Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6...

366

Eastern States Coalbed Methane Production (Billion Cubic Feet...  

Annual Energy Outlook 2012 (EIA)

Coalbed Methane Production (Billion Cubic Feet) Eastern States Coalbed Methane Production (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

367

Western States Coalbed Methane Production (Billion Cubic Feet...  

Annual Energy Outlook 2012 (EIA)

Western States Coalbed Methane Production (Billion Cubic Feet) Western States Coalbed Methane Production (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

368

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Gas Hydrate Production Trial Using CO2 / CH4 Exchange Completed Gas Hydrate Production Trial Using CO2 / CH4 Exchange Completed DE-NT0006553 Goal The goal of this project is to define, plan, conduct and evaluate the results of a field trial of a methane hydrate production methodology whereby carbon dioxide (CO2) molecules are exchanged in situ for methane (CH4) molecules within a hydrate structure, releasing the methane for production. The objective is to evaluate the viability of this hydrate production technique and to understand the implications of the process at a field scale. image showing Conceptual rendering of proposed CO2 - CH4 exchange methodology for the production of natural gas from hydrates Conceptual rendering of proposed CO2 - CH4 exchange methodology for the

369

SCREENING TESTS FOR IMPROVED METHANE CRACKING MATERIALS  

DOE Green Energy (OSTI)

Bench scale (1 to 6 gram) methane cracking tests have been performed on a variety of pure elements, some alloys, and SAES{reg_sign} commercial getters St 101, St 198, St 707, St 737, and St 909 to determine methane cracking performance (MCP) of 5% methane in a helium carrier at 700 C, 101.3 kPa (760 torr) with a 10 sccm feed. The MCP was almost absent from some materials tested while others showed varying degrees of MCP. Re, Cr, V, Gd, and Mo powders had good MCP, but limited capacities. Nickel supported on kieselguhr (Ni/k), a Zr-Ni alloy, and the SAES{reg_sign} getters had good MCP in a helium carrier. The MCP of these same materials was suppressed in a hydrogen carrier stream and the MCP of the Zr-based materials was reduced by nitride formation when tested with a nitrogen carrier gas.

Klein, J; Jeffrey Holder, J

2007-07-16T23:59:59.000Z

370

MethaneHydrateRD_FC.indd  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

gas is an important energy gas is an important energy resource for the United States, providing nearly one-quarter of total energy use. The Department of Energy's Office of Fossil Energy (FE) has played a major role in developing technologies to help tap new, unconventional sources of natural gas. FOSSIL ENERGY RESEARCH BENEFITS Methane Hydrate R&D "The (DOE) Program has supported and managed a high-quality research portf olio that has enabled signifi cant progress toward the (DOE) Program's long-term goals." The Nati onal Academies 2010 One of these is methane hydrate - molecules of natural gas trapped in ice crystals. Containing vast amounts of natural gas, methane hydrate occurs in a variety of forms in sediments within and below thick permafrost in Arctic regions, and in the

371

CFD Modeling of Methane Production from Hydrate-Bearing Reservoir  

Science Conference Proceedings (OSTI)

Methane hydrate is being examined as a next-generation energy resource to replace oil and natural gas. The U.S. Geological Survey estimates that methane hydrate may contain more organic carbon the the world's coal, oil, and natural gas combined. To assist in developing this unfamiliar resource, the National Energy Technology Laboratory has undertaken intensive research in understanding the fate of methane hydrate in geological reservoirs. This presentation reports preliminary computational fluid dynamics predictions of methane production from a subsurface reservoir.

Gamwo, I.K.; Myshakin, E.M.; Warzinski, R.P.

2007-04-01T23:59:59.000Z

372

Conversion of organic solids to hydrocarbons  

DOE Patents (OSTI)

A method of converting organic solids to liquid and gaseous hydrocarbons includes impregnating an organic solid with photosensitizing ions and exposing the impregnated solid to light in a non-oxidizing atmosphere for a time sufficient to photocatalytically reduce the solid to at least one of a liquid and a gaseous hydrocarbon.

Greenbaum, Elias (Oak Ridge, TN)

1995-01-01T23:59:59.000Z

373

Conversion of organic solids to hydrocarbons  

DOE Patents (OSTI)

A method of converting organic solids to liquid and gaseous hydrocarbons includes impregnating an organic solid with photosensitizing ions and exposing the impregnated solid to light in a non-oxidizing atmosphere for a time sufficient to photocatalytically reduce the solid to at least one of a liquid and a gaseous hydrocarbon. 5 Figs.

Greenbaum, E.

1995-05-23T23:59:59.000Z

374

Multivariate statistical evaluation of equilibrium methane adsorption isotherms of coal  

SciTech Connect

The adsorption of methane by coals varies over a broad range of values and appears to depend on a complex function related to coal rank. In order to evaluate these variations in methane adsorption 100 coal samples were analyzed. The paper presents some preliminary results of this study based on multivariate statistical evaluation of equilibrium methane adsorption isotherm data, coal petrology, and vitrinite reflectance.

Schwarzer, R.S.; Bayliss, G.S.

1982-01-01T23:59:59.000Z

375

Renewable Energy 32 (2007) 12431257 Methane generation in landfills  

E-Print Network (OSTI)

2006 Abstract Methane gas is a by-product of landfilling municipal solid wastes (MSW). Most tonnes of methane annually, 70% of which is used to generate heat and/or electricity. The landfill gas. All rights reserved. Keywords: Landfill gas; Renewable energy; Municipal solid waste; Biogas; Methane

Columbia University

376

Detection and Production of Methane Hydrate  

NLE Websites -- All DOE Office Websites (Extended Search)

July-September 2007 July-September 2007 Detection and Production of Methane Hydrate Submitted by: Rice University University of Houston George J. Hirasaki Department of Chemical and Biomolecular Engineering Rice University - MS 362 6100 Main St. Houston, TX 77251-1892 Phone: 713-348-5416; FAX: 713-348-5478; Email: gjh@rice.edu Prepared for: United States Department of Energy National Energy Technology Laboratory December, 2007 Office of Fossil Energy Table of Contents DOE Methane Hydrate Program Peer Review.................................................. 3 Task 5: Carbon Inputs and Outputs to Gas Hydrate Systems ........................... 3 Task 6: Numerical Models for Quantification of Hydrate and Free Gas Accumulations....................................................................................................

377

Method for removal of methane from coalbeds  

DOE Patents (OSTI)

A method for removing methane gas from underground coalbeds prior to mining the coal which comprises drilling at least one borehole from the surface into the coalbed. The borehole is started at a slant rather than directly vertically, and as it descends, a gradual curve is followed until a horizontal position is reached where the desired portion of the coalbed is intersected. Approaching the coalbed in this manner and fracturing the coalbed in the major natural fraction direction cause release of large amounts of the trapped methane gas.

Pasini, III, Joseph (Morgantown, WV); Overbey, Jr., William K. (Morgantown, WV)

1976-01-01T23:59:59.000Z

378

Carbon Monoxide, Ozone, Hydrocarbon Air Quality Standards, and...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Carbon Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related Emission Requirements (Ohio) Carbon Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related Emission...

379

Underground storage of natural gas, liquid hydrocarbons, and...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Underground storage of natural gas, liquid hydrocarbons, and carbon dioxide (Louisiana) Underground storage of natural gas, liquid hydrocarbons, and carbon dioxide (Louisiana)...

380

Biogeochemistry of Isoprenoid Production and Anaerobic Hydrocarbon Biodgeradation.  

E-Print Network (OSTI)

??This dissertation is an exploration of microbial isoprenoid production and destruction by anaerobic hydrocarbon biodegradation. Isoprenoids are methyl-branched hydrocarbons, and include biomarkers from all three… (more)

Dawson, Katherine

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "methane nonmethane hydrocarbons" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

New constraints on methane fluxes and rates of anaerobic methane oxidation in a Gulf of Mexico brine pool via in situ mass spectrometry  

E-Print Network (OSTI)

New constraints on methane fluxes and rates of anaerobic methane oxidation in a Gulf of Mexico Keywords: Methane flux Mass spectrometer Brine pool Methane oxidation Gulf of Mexico a b s t r a c t Deep report direct measurements of methane concentrations made in a Gulf of Mexico brine pool located

Girguis, Peter R.

382

Thermal device and method for production of carbon monoxide and hydrogen by thermal dissociation of hydrocarbon gases  

DOE Patents (OSTI)

Carbon monoxide is produced in a fast quench reactor. The production of carbon monoxide includes injecting carbon dioxide and some air into a reactor chamber having a high temperature at its inlet and a rapidly expanding a reactant stream, such as a restrictive convergent-divergent nozzle at its outlet end. Carbon dioxide and other reactants such as methane and other low molecular weight hydrocarbons are injected into the reactor chamber. Other gas may be added at different stages in the process to form a desired end product and prevent back reactions. The resulting heated gaseous stream is then rapidly cooled by expansion of the gaseous stream.

Detering, Brent A. (Idaho Falls, ID); Kong, Peter C. (Idaho Falls, ID)

2001-01-01T23:59:59.000Z

383

Hydrocarbon-fuel/combustion-chamber-liner materials compatibility. Interim final report, 7 November 1986-31 October 1989  

SciTech Connect

Results of material compatibility experiments using hydrocarbon fuels in contact with copper-based combustion chamber liner materials are presented. Mil-Spec RP-1, n- dodecane, propane, and methane fuels were tested in contact with OFHC, NASA-Z, and ZrCu coppers. Two distinct test methods were employed. Static tests, in which copper coupons were exposed to fuel for long durations at constant temperature and pressure, provided compatibility data in a precisely controlled environment. Dynamic tests, using the Aerojet Carbothermal Test Facility, provided fuel and copper compatibility data under realistic booster engine service conditions. Tests were conducted using very pure grades of each fuel and fuels to which a contaminant, e.g., ethylene or methyl mercaptan, was added to define the role played by fuel impurities. Conclusions are reached as to degradation mechanisms and effects, methods for the elimination of these mechanisms, selection of copper alloy combustion chamber liners, and hydrocarbon fuel purchase specifications.

Gage, M.L.

1990-04-01T23:59:59.000Z

384

Methane coupling by membrane reactor. Quarterly technical progress report, March 25, 1993--June 24, 1993  

DOE Green Energy (OSTI)

The goal of this research is to develop and study an inorganic catalytic membrane reactor which will allow the oxidative coupling of methane to C{sub 2} hydrocarbons at near 100% selectivity and relatively higher conversion, by control of the oxygen supply through the membrane. The reactor setup has been completed. Repairs and purchase of new mass flow control equipment have been undertaken to enable accurate quantitative analysis of gas mixtures using the GC-MS. A four point sub miniature thermocouple assembly has been installed which allows temperature gaskets and seals have been tried to achieve good sealing at reaction temperatures. Gas permeability data have been obtained to monitor the change in porosity of a 20 nm pore size {alpha}-alumina membrane with increasing number of perovskite depositions.

Yi Hua Ma

1993-06-25T23:59:59.000Z

385

Unconventional gas resources. [Eastern Gas Shales, Western Gas Sands, Coalbed Methane, Methane from Geopressured Systems  

DOE Green Energy (OSTI)

This document describes the program goals, research activities, and the role of the Federal Government in a strategic plan to reduce the uncertainties surrounding the reserve potential of the unconventional gas resources, namely, the Eastern Gas Shales, the Western Gas Sands, Coalbed Methane, and methane from Geopressured Aquifers. The intent is to provide a concise overview of the program and to identify the technical activities that must be completed in the successful achievement of the objectives.

Komar, C.A. (ed.)

1980-01-01T23:59:59.000Z

386

File:Methane.pdf | Open Energy Information  

Open Energy Info (EERE)

Methane.pdf Methane.pdf Jump to: navigation, search File File history File usage File:Methane.pdf Size of this preview: 448 × 600 pixels. Go to page 1 2 3 4 5 Go! next page → next page → Full resolution ‎(1,218 × 1,630 pixels, file size: 929 KB, MIME type: application/pdf, 5 pages) File history Click on a date/time to view the file as it appeared at that time. Date/Time Thumbnail Dimensions User Comment current 15:51, 9 February 2012 Thumbnail for version as of 15:51, 9 February 2012 1,218 × 1,630, 5 pages (929 KB) Graham7781 (Talk | contribs) You cannot overwrite this file. Edit this file using an external application (See the setup instructions for more information) File usage The following page links to this file: Hydraulic Fracturing Retrieved from "http://en.openei.org/w/index.php?title=File:Methane.pdf&oldid=404017"

387

Methane Hydrates R&D U S  

NLE Websites -- All DOE Office Websites (Extended Search)

the Power of Working Together Interagency Coordination on Methane Hydrates R&D U . S . D e p a r t m e n t o f E n e r g y * O f f i c e o f F o s s i l E n e r g y N a t i o n a l...

388

California - Coastal Region Coalbed Methane Proved Reserves ...  

Annual Energy Outlook 2012 (EIA)

Coastal Region Coalbed Methane Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 0 0 0 0 0 2010's 0 0 - No...

389

Federal Offshore California Coalbed Methane Proved Reserves ...  

Annual Energy Outlook 2012 (EIA)

Offshore California Coalbed Methane Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 0 0 0 0 0 2010's 0 0 -...

390

Generating power with drained coal mine methane  

SciTech Connect

The article describes the three technologies most commonly used for generating electricity from coal mine methane: internal combustion engines, gas turbines, and microturbines. The most critical characteristics and features of these technologies, such as efficiency, output and size are highlighted. 5 refs.

NONE

2005-09-01T23:59:59.000Z

391

Enhancement of Biogenic Coalbed Methane Production and Back Injection of Coalbed Methane Co-Produced Water  

Science Conference Proceedings (OSTI)

Biogenic methane is a common constituent in deep subsurface environments such as coalbeds and oil shale beds. Coalbed methane (CBM) makes significant contributions to world natural gas industry and CBM production continues to increase. With increasing CBM production, the production of CBM co-produced water increases, which is an environmental concern. This study investigated the feasibility in re-using CBM co-produced water and other high sodic/saline water to enhance biogenic methane production from coal and other unconventional sources, such as oil shale. Microcosms were established with the selected carbon sources which included coal, oil shale, lignite, peat, and diesel-contaminated soil. Each microcosm contained either CBM coproduced water or groundwater with various enhancement and inhibitor combinations. Results indicated that the addition of nutrients and nutrients with additional carbon can enhance biogenic methane production from coal and oil shale. Methane production from oil shale was much greater than that from coal, which is possibly due to the greater amount of available Dissolved Organic Carbon (DOC) from oil shale. Inconclusive results were observed from the other sources since the incubation period was too low. WRI is continuing studies with biogenic methane production from oil shale.

Song Jin

2007-05-31T23:59:59.000Z

392

SAES ST 909 PILOT SCALE METHANE CRACKING TESTS  

DOE Green Energy (OSTI)

Pilot scale (500 gram) SAES St 909 methane cracking tests were conducted to determine material performance for tritium process applications. Tests that ran up to 1400 hours have been performed at 700 C, 202.7 kPa (1520 torr) with a 30 sccm feed of methane, with various impurities, in a 20 vol% hydrogen, balance helium, stream. A 2.5 vol% methane feed was reduced below 30 ppm for 631 hours. A feed of 1.1 vol% methane plus 1.4 vol% carbon dioxide was reduced below 30 ppm for 513 hours. The amount of carbon dioxide gettered by St 909 can be equated to an equivalent amount of methane gettered to estimate a reduced bed life for methane cracking. The effect of 0.4 vol % and 2.1 vol% nitrogen in the feed reduced the time to exceed 30 ppm methane to 362 and 45 hours, respectively, but the nitrogen equivalence to reduced methane gettering capacity was found to be dependent on the nitrogen feed composition. Decreased hydrogen concentrations increased methane getter rates while a drop of 30 C in one bed zone increased methane emissions by over a factor of 30. The impact of gettered nitrogen can be somewhat minimized if the nitrogen feed to the bed has been stopped and sufficient time given to recover the methane cracking rate.

Klein, J; Henry Sessions, H

2007-07-02T23:59:59.000Z

393

Coal Bed Methane Protection Act (Montana) | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Coal Bed Methane Protection Act (Montana) Coal Bed Methane Protection Act (Montana) Coal Bed Methane Protection Act (Montana) < Back Eligibility Utility Fed. Government Commercial Agricultural Investor-Owned Utility State/Provincial Govt Industrial Construction Municipal/Public Utility Local Government Rural Electric Cooperative Tribal Government Institutional Fuel Distributor Program Info State Montana Program Type Environmental Regulations Provider Montana Department of Natural Resources and Conservation The Coal Bed Methane Protection Act establishes a long-term coal bed methane protection account and a coal bed methane protection program for the purpose of compensating private landowners and water right holders for damage to land and to water quality and availability that is attributable to the development of coal bed methane wells. The Act aims to provide for

394

Methane Hydrates - The National R&D Program  

NLE Websites -- All DOE Office Websites (Extended Search)

Methane Hydrates R&D Program Methane Hydrates R&D Program The National Methane Hydrates R&D Program Welcome to the information portal for the National Methane Hydrate R&D Program. Over the past eight years, research carried out under this program has resulted in significant advances in our understanding of methane hydrates, their role in nature, and their potential as a future energy resource. This success is largely due to an unprecedented level of cooperation between federal agencies, industry, national laboratories, and academic institutions. For a quick introduction to methane hydrate and its potential as a fuel source, please read the 2011 Methane Hydrates Primer. Information on other elements of the program can be found under the remaining Key Links. Read More.

395

The Effects of Dissolved Methane upon Liquid Argon Scintillation Light  

E-Print Network (OSTI)

In this paper we report on measurements of the effects of dissolved methane upon argon scintillation light. We monitor the light yield from an alpha source held 20 cm from a cryogenic photomultiplier tube (PMT) assembly as methane is injected into a high-purity liquid argon volume. We observe significant suppression of the scintillation light yield by dissolved methane at the 10 part per billion (ppb) level. By examining the late scintillation light time constant, we determine that this loss is caused by an absorption process and also see some evidence of methane-induced scintillation quenching at higher concentrations (50-100 ppb). Using a second PMT assembly we look for visible re-emission features from the dissolved methane which have been reported in gas-phase argon methane mixtures, and we find no evidence of visible re-emission from liquid-phase argon methane mixtures at concentrations between 10 ppb and 0.1%.

B. J. P. Jones; T. Alexander; H. O. Back; G. Collin; J. M. Conrad; A. Greene; T. Katori; S. Pordes; M. Toups

2013-08-16T23:59:59.000Z

396

Operation of an aircraft engine using liquefied methane fuel  

SciTech Connect

The operation of a reciprocating aircraft engine on methane fuel is demonstrated. Since storage of the methane fuel in the gaseous state would impractical for a flight fuel system, a liquid storage system was used. System valving was configured to deliver only liquid methane to the engine supply line. The equipment description includes photo and diagram illustrations of the liquid methane storage dewar, and photos of the methane heat exchanger, pressure regulator and air-fuel mixer. The engine test results are presented for gasoline and methane in terms of RPM, horsepower, fuel flow, specific energy consumption and standard conditions horsepower. Conclusions include the finding that conversion of an aircraft reciprocating engine to operate on liquified methane is possible with very satisfactory results.

Raymer, J.A.

1982-01-01T23:59:59.000Z

397

Methane coupling by membrane reactor. Quarterly technical progress report, March 25--June 24, 1996  

DOE Green Energy (OSTI)

The experimental study was continued on methane oxidative coupling using an oxygen-permeable dense membrane reactor. The oxygen permeance through the dense membrane was measured and preliminary experiments were conducted with the catalytic membrane reactor. The oxygen permeance was found to be similar to that obtained earlier without catalyst packing. No C{sub 2} hydrocarbons were observed in the catalytic membrane reactor for methane coupling. In order to reduce the non-selective, total oxidation activity of the dense membrane material, the inner surface of the dense membrane tube was deposited by the sol-gel technique with BaCe{sub 0.6}Sm{sub 0.4}O{sub 3}, which is a catalytic, oxygen-conductive material without total oxidation catalytic activity. The dense membrane tube was examined by XRD before and after the deposition. Catalytic experiments with the coated dense membrane reactor were carried out and higher C{sub 2} selectivity was observed than with the co-feed reactor.

NONE

1996-08-28T23:59:59.000Z

398

Production of hydrogen bromide by bromine-methane reactions at elevated temperature.  

SciTech Connect

Hydrogen bromide is a potentially useful intermediate for hydrogen production by electrolysis because it has a low cell potential and is extremely soluble in water. Processes have been proposed to exploit these properties, but among the important issues to be resolved is the efficiency of HBr production from hydrocarbon precursors. This investigation evaluated a fundamental facet of such a technology by studying the reaction of methane and bromine at elevated temperature to determine the yield and kinetics of HBr formation. Laboratory experimentation and computational chemistry were combined to provide a description of this reaction for possible application to reactor design at a larger scale. Experimental studies with a tubular flow reactor were used to survey a range of reactant ratios and reactor residence times at temperatures between 500 C and 800 C. At temperatures near 800 C with excess methane, conversions of bromine to HBr exceeded 90% and reaction products included solid carbon (soot) in stoichiometric amounts. At lower temperatures, HBr conversion was significantly reduced, the products included much less soot, and the formation of bromocarbon compounds was indicated qualitatively. Calculations of chemical equilibrium behavior and reaction kinetics for the experimental conditions were performed using the Sandia CHEMKIN package. An elementary multistep mechanism for the gas-phase chemistry was used together with a surface mechanism that assumed facile deposition of radical species at the reactor walls. Simulations with the laminar-flow boundary-layer code of the CHEMKIN package gave reasonable agreement with experimental data.

Bradshaw, Robert W.; Larson, Richard S.

2003-05-01T23:59:59.000Z

399

Selective photooxidation of hydrocarbons in zeolites by oxygen  

DOE Patents (OSTI)

A selective photooxidation process for the conversion of hydrocarbon molecules to partially oxygenated derivatives, which comprises the steps of adsorbing a hydrocarbon and oxygen onto a dehydrated zeolite support matrix to form a hydrocarbon-oxygen contact pair, and subsequently exposing the hydrocarbon-oxygen contact pair to visible light, thereby forming a partially oxygenated derivative.

Frei, Heinz (Berkeley, CA); Blatter, Fritz (Berkeley, CA); Sun, Hai (Berkeley, CA)

1998-01-01T23:59:59.000Z

400

Regulation of methane genes and genome expression  

DOE Green Energy (OSTI)

At the start of this project, it was known that methanogens were Archaeabacteria (now Archaea) and were therefore predicted to have gene expression and regulatory systems different from Bacteria, but few of the molecular biology details were established. The goals were then to establish the structures and organizations of genes in methanogens, and to develop the genetic technologies needed to investigate and dissect methanogen gene expression and regulation in vivo. By cloning and sequencing, we established the gene and operon structures of all of the “methane” genes that encode the enzymes that catalyze methane biosynthesis from carbon dioxide and hydrogen. This work identified unique sequences in the methane gene that we designated mcrA, that encodes the largest subunit of methyl-coenzyme M reductase, that could be used to identify methanogen DNA and establish methanogen phylogenetic relationships. McrA sequences are now the accepted standard and used extensively as hybridization probes to identify and quantify methanogens in environmental research. With the methane genes in hand, we used northern blot and then later whole-genome microarray hybridization analyses to establish how growth phase and substrate availability regulated methane gene expression in Methanobacterium thermautotrophicus ?H (now Methanothermobacter thermautotrophicus). Isoenzymes or pairs of functionally equivalent enzymes catalyze several steps in the hydrogen-dependent reduction of carbon dioxide to methane. We established that hydrogen availability determine which of these pairs of methane genes is expressed and therefore which of the alternative enzymes is employed to catalyze methane biosynthesis under different environmental conditions. As were unable to establish a reliable genetic system for M. thermautotrophicus, we developed in vitro transcription as an alternative system to investigate methanogen gene expression and regulation. This led to the discovery that an archaeal protein, designated TFE, that had sequences in common with the eukaryotic general transcription factor TFIIE, stimulated archaeal transcription initiation and that the archaeal TATA-box binding protein (TBP) remained attached to the promoter region whereas the transcription factor TFB dissociated from the template DNA following initiation. DNA sequences that directed the localized assembly of archaeal histones into archaeal nucleosomes were identified, and we established that transcription by an archaeal RNA polymerase was slowed but not blocked by archaeal nucleosomes. We developed a new protocol to purify archaeal RNA polymerases and with this enzyme and additional improvements to the in vitro transcription system, we established the template requirements for archaeal transcription termination, investigated the activities of proteins predicted to be methane gene regulators, and established how TrpY, a novel archaeal regulator of expression of the tryptophan biosynthetic operon functions in M. thermautotrophicus. This also resulted in the discovery that almost all M. thermautotrophicus mutants isolated as spontaneously resistant to 5-methyl tryptophan (5MTR) had mutations in trpY and were therefore 5MTR through de-repressed trp operon expression. This established a very simple, practical procedure to determine and quantify the DNA sequence changes that result from exposure of this Archaeon to any experimental mutagenesis protocol. Following the discovery that the Thermococcus kodakaraensis was amenable to genetic manipulation, we established this technology at OSU and subsequently added plasmid expression, a reporter system and additional genetic selections to the T. kodakaraensis genetic toolbox. We established that transcription and translation are coupled in this Archaeon, and by combining in vitro transcription and in vivo genetics, we documented that both TFB1 and TFB2 support transcription initiation in T. kodakaraensis. We quantified the roles of ribosome binding sequences and alternative initiation codons in translation initiation, established that polarity e

John N. Reeve

2009-09-09T23:59:59.000Z

Note: This page contains sample records for the topic "methane nonmethane hydrocarbons" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Measuring Hydroxyl Radicals during the Oxidation of Methane, Ethane, Ethylene, and Acetylene in a Shock Tube Using UV Absorption Spectroscopy  

E-Print Network (OSTI)

The hydroxyl (OH) radical is a common intermediate species in any hydrogen- or hydrocarbon-based flame. Investigating OH at elevated temperatures and pressures is not a trivial task, and many considerations must be made to fully study the molecule. Shock tubes can provide the experimenter with a wide range of temperatures and pressures to investigate a variety of combustion characteristics including, but not limited to, OH kinetic profiles. Described in this dissertation is the diagnostic used to measure OH within a shock tube using UV absorption spectroscopy from an enhanced UV Xenon lamp passed through a spectrometer. OH absorption was made over a narrow range of wavelengths around 309.551 nm within the widely studied OH X?A ground vibrational transition region. Experiments have been performed in the shock-tube facility at Texas A&M University using this OH absorption diagnostic. A calibration mixture of stoichiometric H2/O2 diluted in 98% argon by volume was tested initially and compared with a well-known hydrogen-based kinetics mechanism to generate an absorption coefficient correlation. This correlation is valid over the range of conditions observed in the experiments at two pressures near 2 and 13 atm and temperatures from 1182 to 2017 K. Tests were completed using the absorption coefficient correlation on stoichiometric mixtures of methane, methane and water, ethane, ethylene, and acetylene to compare against a comprehensive, detailed chemical kinetics mechanism which considers up through C5 hydrocarbons. Measurements of methane show good agreement in peak OH formation and ignition delay time when compared with the mechanism. Improvements can be made in the shape of the methane-oxygen OH profile, and sensitivity and rate of production analyses were performed with the mechanism to identify key reactions for tuning. Similar results were found for methane-water-oxygen mixtures with no difference in profile shape or ignition delay time noted. There is room for improvement between the mechanism and measured values of OH for ethane-, ethylene-, and acetylene-based mixtures, although interesting pre-ignition features are nonetheless captured relatively well by the mechanism. Uncertainty in the measurement comes from the inherent noise in the photomultiplier tube signal and is ±25-150 ppm for the 2-atm experiments and ±6-25 ppm for the 13-atm experiments.

Aul, Christopher J

2013-05-01T23:59:59.000Z

402

HYDROCARBONS FROM PLANTS: ANALYTICAL METHODS AND OBSERVATIONS  

E-Print Network (OSTI)

W. and Calvin, M. J. Amer. Oil Chern. Assoc. Science,· 208,of the production of oil and alcohol from hydrocarbon-Figure 1 Cumulative U.S. crude oil discoveries as a function

Calvin, Melvin

2013-01-01T23:59:59.000Z

403

Thermodynamic Properties of Acetic Acid + Hydrocarbons ...  

Science Conference Proceedings (OSTI)

Thermodynamic Properties of Acetic Acid + Hydrocarbons Mixtures L. Negadi1,C,S, N. Ainous2, A. Negadi1, I. Mokbel2, A. Kaci3 and J. Jose2 ...

2006-07-20T23:59:59.000Z

404

Process for Photochemical Chlorination of Hydrocarbons  

DOE Patents (OSTI)

A process for chlorination of a major portion of the hydrogen atoms of paraffinic hydrocarbons of five or more carbon atoms may be replaced by subjecting the hydrocarbon to the action of chlorine under active light. The initial chlorination is begun at 25 to 30 deg C with the chlorine diluted with HCl. The later stages may be carried out with undiluted chlorine and the temperature gradually raised to about 129 deg C.

Beanblossom, W.S.

1950-10-31T23:59:59.000Z

405

Formation of hydrocarbons by bacteria and algae  

SciTech Connect

A literature review has been performed summarizing studies on hydrocarbon synthesis by microorganisms. Certain algal and bacterial species produce hydrocarbons in large quantities, 70 to 80% of dry cell mass, when in a controlled environment. The nutritional requirements of these organisms are simple: CO/sub 2/ and mineral salts. The studies were initiated to determine whether or not microorganisms played a role in petroleum formation. 90 references. (DMC)

Tornabene, T.G.

1980-12-01T23:59:59.000Z

406

Clean, economical, underwater (hydrocarbon) storage  

SciTech Connect

A consortium consisting of Howaldtswerke-Deutsche Werft A.G., Phoenix Gummiwerke A.G., Strabag Bau-A.G., and Bugsier Reederei und Bergungs-A.G. offers a plausible solution to the large-scale underwater storage of hydrocarbons. Up to 20 storage compartments of 8000 cu m capacity can be assembled for a capacity of 160,000 cu m. Each compartment is divided in half by a nylon-reinforced polyurethane diaphragm which isolates oil or other products on one side from sea-water ballast on the other side. As oil is pumped into storage on one side of the diaphragm, the diaphragm moves and ballast on the other side is displaced to the sea. Ballast re-enters the compartment during unloading. The system can enable small offshore platforms to produce more economically. Cargo tankers load at 8000 cu m/hr. The tanks will be used in 200 m or greater water depths. The loading station is installed in a buoy 30 m below the water surface.

1978-08-01T23:59:59.000Z

407

Effect of bubble size and density on methane conversion to hydrate  

SciTech Connect

Research is underway at NETL to understand the physical properties of methane hydrates. One area of investigation is the storage of methane as methane hydrates. An economical and efficient means of storing methane in hydrates opens many commercial opportunities such as transport of stranded gas, off-peak storage of line gas, etc.We have observed during our investigations that the ability to convert methane to methane hydrate is enhanced by foaming of the methane–water solution using a surfactant. The density of the foam, along with the bubble size, is important in the conversion of methane to methane hydrate.

Leske, J.; Taylor, C.E.; Ladner, E.P.

2007-03-01T23:59:59.000Z

408

In situ thermally enhanced biodegradation of petroleum fuel hydrocarbons and halogenated organic solvents  

DOE Patents (OSTI)

An in situ thermally enhanced microbial remediation strategy and a method for the biodegradation of toxic petroleum fuel hydrocarbon and halogenated organic solvent contaminants. The method utilizes nonpathogenic, thermophilic bacteria for the thermal biodegradation of toxic and carcinogenic contaminants, such as benzene, toluene, ethylbenzene and xylenes, from fuel leaks and the chlorinated ethenes, such as trichloroethylene, chlorinated ethanes, such as 1,1,1-trichloroethane, and chlorinated methanes, such as chloroform, from past solvent cleaning practices. The method relies on and takes advantage of the pre-existing heated conditions and the array of delivery/recovery wells that are created and in place following primary subsurface contaminant volatilization efforts via thermal approaches, such as dynamic underground steam-electrical heating.

Taylor, Robert T. (Livermore, CA); Jackson, Kenneth J. (San Leandro, CA); Duba, Alfred G. (Livermore, CA); Chen, Ching-I (Danville, CA)

1998-01-01T23:59:59.000Z

409

In situ thermally enhanced biodegradation of petroleum fuel hydrocarbons and halogenated organic solvents  

DOE Patents (OSTI)

An in situ thermally enhanced microbial remediation strategy and a method for the biodegradation of toxic petroleum fuel hydrocarbon and halogenated organic solvent contaminants are described. The method utilizes nonpathogenic, thermophilic bacteria for the thermal biodegradation of toxic and carcinogenic contaminants, such as benzene, toluene, ethylbenzene and xylenes, from fuel leaks and the chlorinated ethenes, such as trichloroethylene, chlorinated ethanes, such as 1,1,1-trichloroethane, and chlorinated methanes, such as chloroform, from past solvent cleaning practices. The method relies on and takes advantage of the pre-existing heated conditions and the array of delivery/recovery wells that are created and in place following primary subsurface contaminant volatilization efforts via thermal approaches, such as dynamic underground steam-electrical heating. 21 figs.

Taylor, R.T.; Jackson, K.J.; Duba, A.G.; Chen, C.I.

1998-05-19T23:59:59.000Z

410

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Methane Hydrate Production from Alaskan Permafrost Last Reviewed 02/05/2010 Methane Hydrate Production from Alaskan Permafrost Last Reviewed 02/05/2010 DE-FC26-01NT41331 photo of new Anadarko drilling rig in place at Hot Ice No.1 on Alaska's North Slope Hot Ice No. 1 Drilling Platform courtesy Anadarko Petroleum Corp. Goal The goal of the project was to develop technologies for drilling and recovering hydrates in arctic areas. The specific objectives were to drill, core, and test a well through the hydrate stability zone in northern Alaska Performers Maurer Technology, Inc.* - Project coordination with DOE Anadarko Petroleum Corporation - Overall project management for the design, construction, and operation of the Arctic Drilling Platform and mobile core lab, and field coring operations Noble Engineering and Development* - Real time data collection and

411

Detection and Production of Methane Hydrate  

NLE Websites -- All DOE Office Websites (Extended Search)

Oil & Natural Gas Technology Oil & Natural Gas Technology DOE Award No.: DE-FC26-06NT42960 Quarterly Progress Report Reporting Period: April-June 2007 Detection and Production of Methane Hydrate Submitted by: Department of Chemical and Biomolecular Engineering Rice University - MS 362 6100 Main St. Houston, TX 77251-1892 Prepared for: United States Department of Energy National Energy Technology Laboratory August, 2007 Office of Fossil Energy Detection and Production of Methane Hydrate Quarterly Progress Report Reporting Period: April-June 2007 Prepared by: George Hirasaki Rice University August 2007 CONTRACT NO. DE-FC26-06NT42960 Department of Chemical and Biomolecular Engineering Rice University - MS 362 6100 Main St. Houston, TX 77251-1892 Phone: 713-348-5416; Fax: 713-348-5478; Email: gjh@rice.edu

412

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

In Situ Sampling and Characterization of Naturally Occurring Methane Hydrate Using the D/V JOIDES Resolution Last Reviewed 02/05/2010 In Situ Sampling and Characterization of Naturally Occurring Methane Hydrate Using the D/V JOIDES Resolution Last Reviewed 02/05/2010 DE-FC26-01NT41329 photo of a man showing the pressure core sampler on the deck of JOIDES Resolution Pressure core sampler on deck courtesy Texas A&M University Goal The goal of the project was to characterize hydrate accumulation at Hydrate Ridge (offshore Oregon) and improve the ability to use geophysical and subsurface logging to identify hydrates. A follow-on goal was to characterize hydrate accumulation at offshore Vancouver Island, BC, Canada. Background This project focused on physically verifying the existence of hydrates at Hydrate Ridge through the collection of pressurized and non-pressurized core samples and logging data. This study developed and tested tools to

413

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Detection and Production of Methane Hydrate Last Reviewed 5/15/2012 Detection and Production of Methane Hydrate Last Reviewed 5/15/2012 DE-FC26-06NT42960 Goal The goal of this project is to improve the understanding of regional and local differences in gas hydrate systems from three perspectives: as an energy resource, as a geohazard, and as a long-term influence on global climate. Performers Rice University, Houston, TX University of Texas, Austin, TX Oklahoma State University, Stillwater, OK Background Heterogeneity in the distribution of gas hydrate accumulations impacts all aspects of research into gas hydrate natural systems. The challenge is to delineate, understand, and appreciate these differences at the regional and local scales, where differences in in situ concentrations are relevant to the importance of gas hydrate as a resource, a geohazard, and a factor in

414

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

- Methane Hydrate Research - Geoscience Evaluations and Field Studies Last Reviewed 3/18/2013 - Methane Hydrate Research - Geoscience Evaluations and Field Studies Last Reviewed 3/18/2013 Project Goals The primary goals of the DOE/NETL Natural Gas Hydrate Field Studies (NGHFS) project are: Conduct field-based studies that advance the ability to predict, detect, characterize, and understand distribution of and controls on natural gas hydrate occurrences. Analyze geologic, geochemical, and microbiologic data for indications of past and current changes to the stability of natural gas hydrate in marine settings. Develop links between the U.S. Gas Hydrate Program and international R&D efforts through direct participation in international field programs and workshops. Evaluate the potential role natural gas hydrates may play in the global carbon cycle through analysis of modern and paleo-natural gas

415

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

– Formation and Dissociation of Methane Hydrates Last Reviewed 07/7/2011 – Formation and Dissociation of Methane Hydrates Last Reviewed 07/7/2011 Project Objective Observe hydrate formation and dissociation phenomena in various porous media and characterize hydrate-bearing sediments by estimating physical properties (kinetic parameters for hydrate formation and dissociation, thermal conductivity, permeability, relative permeability, and mechanical strength) to enhance fundamental understanding on hydrate formation and accumulation and to support numerical simulations and potential gas hydrate production Project Performers Yongkoo Seol – NETL Office of Research & Development Jeong Choi – Oak Ridge Institute for Science and Education Jongho Cha-Virginia Polytech Institute Project Location National Energy Technology Laboratory - Morgantown, West Virginia

416

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Phase 1 - Characterization and Qualification of the Methane Hydrate Resource Potential Associated with the Barrow Gas Fields Phase 1 - Characterization and Qualification of the Methane Hydrate Resource Potential Associated with the Barrow Gas Fields DE-FC26-06NT42962 Goal The goal of this project is to characterize and quantify the postulated gas hydrate resource associated with the Barrow Gas Fields – three producing fields located in a permafrost region near Barrow, the North Slope's biggest population center and economic hub. Map of the North Slope Borough showing the location of its eight major communities, including Barrow, the site of this research project. Map of the North Slope Borough showing the location of its eight major communities, including Barrow, the site of this research project. Performers North Slope Borough, Barrow, Alaska (North Slope Borough) 99723

417

Methane Hydrate Field Studies | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Field Studies Field Studies Methane Hydrate Field Studies Arctic/Alaska North Slope Field Studies Since 2001, DOE has conducted field trials of exploration and production technology in the Alaska North Slope. Although Alaska methane hydrate resources are smaller than marine deposits and currently lack outlets to commercial markets, Alaska provides an excellent laboratory to study E&P technology. The research also has implications for various Alaska resources, including potential gas hydrate resources for local communities, conventional "stranded" gas, as well as Alaska's large unconventional oil resources. The hydrate deposits have been delineated in the process of developing underlying oil fields, and drilling costs are much lower than offshore. DOE-BP Project

418

TITAN'S TRANSPORT-DRIVEN METHANE CYCLE  

SciTech Connect

The mechanisms behind the occurrence of large cloud outbursts and precipitation on Titan have been disputed. A global- and annual-mean estimate of surface fluxes indicated only 1% of the insolation, or {approx}0.04 W m{sup -2}, is exchanged as sensible and/or latent fluxes. Since these fluxes are responsible for driving atmospheric convection, it has been argued that moist convection should be quite rare and precipitation even rarer, even if evaporation globally dominates the surface-atmosphere energy exchange. In contrast, climate simulations indicate substantial cloud formation and/or precipitation. We argue that the top-of-atmosphere (TOA) radiative imbalance is diagnostic of horizontal heat transport by Titan's atmosphere, and thus constrains the strength of the methane cycle. Simple calculations show the TOA radiative imbalance is {approx}0.5-1 W m{sup -2} in Titan's equatorial region, which implies 2-3 MW of latitudinal heat transport by the atmosphere. Our simulation of Titan's climate suggests this transport may occur primarily as latent heat, with net evaporation at the equator and net accumulation at higher latitudes. Thus, the methane cycle could be 10-20 times previous estimates. Opposing seasonal transport at solstices, compensation by sensible heat transport, and focusing of precipitation by large-scale dynamics could further enhance the local, instantaneous strength of Titan's methane cycle by a factor of several. A limited supply of surface liquids in regions of large surface radiative imbalance may throttle the methane cycle, and if so, we predict more frequent large storms over the lakes district during Titan's northern summer.

Mitchell, Jonathan L. [Department of Earth and Space Sciences, Department of Atmospheric and Oceanic Sciences, University of California, Los Angeles, CA 90095 (United States)

2012-09-10T23:59:59.000Z

419

Thermal Conversion of Methane to Acetylene  

DOE Green Energy (OSTI)

This report describes the experimental demonstration of a process for the direct thermal conversion of methane to acetylene. The process utilizes a thermal plasma heat source to dissociation products react to form a mixture of acetylene and hydrogen. The use of a supersonic expansion of the hot gas is investigated as a method of rapidly cooling (quenching) the product stream to prevent further reaction or thermal decomposition of the acetylene which can lower the overall efficiency of the process.

Fincke, James Russell; Anderson, Raymond Paul; Hyde, Timothy Allen; Wright, Randy Ben; Bewley, Randy Lee; Haggard, Delon C; Swank, William David

2000-01-01T23:59:59.000Z

420

Enhanced carbon monoxide utilization in methanation process  

DOE Green Energy (OSTI)

Carbon monoxide - containing gas streams are passed over a catalyst to deposit a surface layer of active surface carbon thereon essentially without the formation of inactive coke. The active carbon is subsequently reacted with steam or hydrogen to form methane. Surprisingly, hydrogen and water vapor present in the feed gas do not adversely affect CO utilization significantly, and such hydrogen actually results in a significant increase in CO utilization.

Elek, Louis F. (Peekskill, NY); Frost, Albert C. (Congers, NY)

1984-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "methane nonmethane hydrocarbons" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Influence of Reduction Pretreatment and Methane Reforming on Nickel Solubility in YSZ Grains and Nickel Sintering within Ni-YSZ SOFC Anode Materials  

Science Conference Proceedings (OSTI)

Internal reforming of hydrocarbon fuels (e.g. methane or natural gas) can improve the thermal efficiency of solid oxide fuel cells (SOFC) by balancing exothermic electrochemical oxidation of H2 and CO at the anode/cathode interface with endothermic steam reforming reactions on the anode1. Generally the rate of reforming is much greater than the rate of H2 and CO oxidation leading to extensive thermal gradients across the cell that can compromise the physical integrity of the cell. Therefore, methods to control reformation activity and predict thermal gradients are needed. Computational modeling is used to predict thermal gradients and fuel conversion profiles across the cell, thus accurate and predictable methane reforming kinetics are required. Significant discrepancies in activation energy, rate expressions, and rate constants for methane reforming over nickel-yttria stabilized zirconia (Ni-YSZ) are reported in the open literature1-4. The objective of this work is to provide clarity on factors leading to discrepancies in kinetic information reported in the literature and identify potential methods to control reforming rates over NiYSZ anodes. Effects of pretreatment and reforming on Ni microstructure and activity of NiYSZ anodes for methane reforming were examined under open-circuit conditions.

Strohm, James J.; King, David L.; Saraf, Laxmikant V.; Lea, Alan S.; Wang, Chong M.; Singh, Prabhakar

2009-08-15T23:59:59.000Z

422

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Support of Gulf of Mexico Hydrate Research Consortium: Activities to Support Establishment of Sea Floor Monitoring Station Support of Gulf of Mexico Hydrate Research Consortium: Activities to Support Establishment of Sea Floor Monitoring Station DE-FC26-02NT41328 Goal Determine the potential impacts of gas hydrate instability in terms of the release of methane into seafloor sediments, the ocean and the atmosphere. Performers University of California, San Diego (Scripps Institution of Oceanography) - manage geochemical, hydrological and sedimentological investigations Texas A&M University - manage field monitoring program Location La Jolla, California 92093 Background This project will monitor, characterize, and quantify the rates of formation and dissociation of methane gas hydrates at and near the seafloor in the northern Gulf of Mexico, and determine linkages between formation/dissociation and physical/chemical parameters of the deposits over the course of a year. The stability and response of shallow gas hydrates to temperature and chemical perturbations will be monitored in situ, and localized seafloor and water column environmental impacts of hydrate formation and dissociation characterized. The following will be determined: 1) The equilibrium/steady state conditions for structure II methane gas hydrates at the field site,2) whether the system is in dynamic equilibrium and the local hydrology is characterized by steady state episodic fluid flow, and 3) how fluid fluxes and fluid composition work together to dynamically influence gas hydrate stability.

423

METHANE HYDRATE ADVISORY COMMITTEE U.S. Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

METHANE HYDRATE ADVISORY COMMITTEE METHANE HYDRATE ADVISORY COMMITTEE U.S. Department of Energy Advisory Committee Charter - - - - ---- ---- ------~ 1. Committee's Official Designation. Methane Hydrate Advisory Committee (MHAC) 2. Authority:. This charter establishes the Methane Hydrate Advisory Committee (Committee) pursuant to Title IX, Subtitle F, Section 968, Methane Hydrate Research of the Energy Policy Act of 2005 (EPACT), Public Law 109-58. This charter establishes the MHAC under the authority of the Department of Energy (DOE). The MHAC is being renewed in accordance with the provisions of the Federal Advisory Committee Act (FACA), as amended, 5 U.S.C., App.2. 3. Objectives and Scope of Activities. The Committee provides advice to the Secretary of Energy by developing recommendations and broad programmatic priorities for the methane

424

International Cooperation in Methane Hydrates | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Oil & Gas » Methane Hydrate » Oil & Gas » Methane Hydrate » International Cooperation in Methane Hydrates International Cooperation in Methane Hydrates In 1982 the multi-national Deep Sea Drilling Program (DSDP) recovered the first subsea substantial methane hydrate deposits, which spurred methane hydrate research in the US and other countries. The successor programs, the Ocean Drilling Program (ODP) and the Integrated Ocean Drilling Program (IODP) sampled hydrate deposits off Oregon (ODP 204, 2002) and in the Cascadia Margin off Vancouver Island, Canada (ODP 146, 1992 and IODP 311, 2005). In the Atlantic Ocean off the US, ODP Leg 146 sampled hydrate deposits on the Blake Ridge and Carolina Rise in 1995. International cooperation helps scientists in the US and other countries

425

Process for separating nitrogen from methane using microchannel process technology  

DOE Patents (OSTI)

The disclosed invention relates to a process for separating methane or nitrogen from a fluid mixture comprising methane and nitrogen, the process comprising: (A) flowing the fluid mixture into a microchannel separator, the microchannel separator comprising a plurality of process microchannels containing a sorption medium, the fluid mixture being maintained in the microchannel separator until at least part of the methane or nitrogen is sorbed by the sorption medium, and removing non-sorbed parts of the fluid mixture from the microchannel separator; and (B) desorbing the methane or nitrogen from the sorption medium and removing the desorbed methane or nitrogen from the microchannel separator. The process is suitable for upgrading methane from coal mines, landfills, and other sub-quality sources.

Tonkovich, Anna Lee (Marysville, OH); Qiu, Dongming (Dublin, OH); Dritz, Terence Andrew (Worthington, OH); Neagle, Paul (Westerville, OH); Litt, Robert Dwayne (Westerville, OH); Arora, Ravi (Dublin, OH); Lamont, Michael Jay (Hilliard, OH); Pagnotto, Kristina M. (Cincinnati, OH)

2007-07-31T23:59:59.000Z

426

Utah Coalbed Methane Proved Reserves New Reservoir Discoveries...  

U.S. Energy Information Administration (EIA) Indexed Site

New Reservoir Discoveries in Old Fields (Billion Cubic Feet) Utah Coalbed Methane Proved Reserves New Reservoir Discoveries in Old Fields (Billion Cubic Feet) Decade Year-0 Year-1...

427

,"Utah Coalbed Methane Proved Reserves, Reserves Changes, and...  

U.S. Energy Information Administration (EIA) Indexed Site

,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Utah Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2011,"6...

428

LANDFILL OPERATION FOR CARBON SEQUESTRATION AND MAXIMUM METHANE EMISSION CONTROL  

SciTech Connect

''Conventional'' waste landfills emit methane, a potent greenhouse gas, in quantities such that landfill methane is a major factor in global climate change. Controlled landfilling is a novel approach to manage landfills for rapid completion of total gas generation, maximizing gas capture and minimizing emissions of methane to the atmosphere. With controlled landfilling, methane generation is accelerated and brought to much earlier completion by improving conditions for biological processes (principally moisture levels) in the landfill. Gas recovery efficiency approaches 100% through use of surface membrane cover over porous gas recovery layers operated at slight vacuum. A field demonstration project's results at the Yolo County Central Landfill near Davis, California are, to date, highly encouraging. Two major controlled landfilling benefits would be the reduction of landfill methane emissions to minuscule levels, and the recovery of greater amounts of landfill methane energy in much shorter times than with conventional landfill practice. With the large amount of US landfill methane generated, and greenhouse potency of methane, better landfill methane control can play a substantial role in reduction of US greenhouse gas emissions.

Don Augenstein

1999-01-11T23:59:59.000Z

429

Methane Hydrate Research and Modeling | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Research and Modeling Clean Coal Carbon Capture and Storage Oil & Gas Methane Hydrate LNG Offshore Drilling Enhanced Oil Recovery Shale Gas Research is focused on understanding...

430

Powder River Basin (WY, MT) Coal and Coalbed Methane: Evaluating...  

Open Energy Info (EERE)

Powder River Basin (WY, MT) Coal and Coalbed Methane: Evaluating and Revising 100 Years of Studies The USGS published a USGS Professional Paper in 2010 entitled 

431

Powder River Basin (WY, MT) Coal and Coalbed Methane: Evaluating...  

Open Energy Info (EERE)

Search Share this page on Facebook icon Twitter icon Powder River Basin (WY, MT) Coal and Coalbed Methane: Evaluating and Revising 100 Years of Studies Dataset Summary...

432

Coalbed Methane Resources in the Powder River Basin: Lithologic...  

Open Energy Info (EERE)

in Wyoming and North Dakota. Specifically, the analysis looked at: total gas desorbed, coal quality, and high-pressure methane adsorption isotherm data from 963 cored coal samples...

433

Effect of matrix shrinkage on permeability of coalbed methane reservoirs .  

E-Print Network (OSTI)

??The dynamic nature of coalbed methane reservoir permeability makes the continuous modeling of the flow process difficult. Knowledge of conventional reservoir modeling is of little… (more)

Tandon, Rohit, 1966-

1991-01-01T23:59:59.000Z

434

NETL: Methane Hydrates - DOE/NETL Projects - Advanced Hydrate...  

NLE Websites -- All DOE Office Websites (Extended Search)

is to develop analytical techniques capable of quantitatively evaluating the nature of methane hydrate reservoir systems through modeling of their acoustic response using...

435

,"Texas--RRC District 2 Onshore Coalbed Methane Proved Reserves...  

U.S. Energy Information Administration (EIA) Indexed Site

2 Onshore Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest...

436

NETL: Methane Hydrates - DOE/NETL Projects - GAS HYDRATE DYNAMICS...  

NLE Websites -- All DOE Office Websites (Extended Search)

the first systematic geochemical and microbiological data to constrain subseafloor methane sinks and the spatio-temporal changes in the nature of microbial systems and pore...

437

,"Lower 48 Federal Offshore Coalbed Methane Proved Reserves ...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

438

,"U.S. Coalbed Methane Proved Reserves Adjustments (Billion Cubic...  

U.S. Energy Information Administration (EIA) Indexed Site

ame","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Coalbed Methane Proved Reserves Adjustments (Billion Cubic Feet)",1,"Annual",2011 ,"Release...

439

,"U.S. Coalbed Methane Proved Reserves (Billion Cubic Feet)"  

U.S. Energy Information Administration (EIA) Indexed Site

ame","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Coalbed Methane Proved Reserves (Billion Cubic Feet)",1,"Annual",2011 ,"Release Date:","812013"...

440

,"Oklahoma Coalbed Methane Proved Reserves (Billion Cubic Feet...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

Note: This page contains sample records for the topic "methane nonmethane hydrocarbons" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

,"California - Los Angeles Basin Onshore Coalbed Methane Proved...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

442

,"Colorado Coalbed Methane Proved Reserves (Billion Cubic Feet...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

443

,"Texas--RRC District 8 Coalbed Methane Proved Reserves (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

444

,"Utah Coalbed Methane Proved Reserves (Billion Cubic Feet)"  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

445

,"Wyoming Coalbed Methane Proved Reserves (Billion Cubic Feet...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

446

Table 16: Coalbed methane proved reserves and production, 2007...  

U.S. Energy Information Administration (EIA) Indexed Site

: Coalbed methane proved reserves and production, 2007 - 2011" "billion cubic feet" ,,"Reserves",,,,,,"Production" "State and Subdivision",,2007,2008,2009,2010,2011,,2007,2008,2009...

447

,"Alabama Coalbed Methane Proved Reserves (Billion Cubic Feet...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

448

NETL-ORD Methane Hydrate Project - Micro XCT Characterization...  

NLE Websites -- All DOE Office Websites (Extended Search)

the experimental systempressure vessel development and system parameter optimization, methane hydrate will be formed and dissociated in packed sediments. Micro-XCT scans will be...

449

,"U.S. Coalbed Methane Proved Reserves, Reserves Changes, and...  

U.S. Energy Information Administration (EIA) Indexed Site

ame","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2011,"6301989"...

450

,"Texas--RRC District 9 Coalbed Methane Proved Reserves (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

451

,"Texas--State Offshore Coalbed Methane Proved Reserves (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

452

,"Michigan Coalbed Methane Proved Reserves (Billion Cubic Feet...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

453

,"Virginia Coalbed Methane Proved Reserves (Billion Cubic Feet...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

454

,"Montana Coalbed Methane Proved Reserves (Billion Cubic Feet...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

455

,"Kansas Coalbed Methane Proved Reserves (Billion Cubic Feet...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

456

,"U.S. Coalbed Methane Proved Reserves Revision Increases (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

ame","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Coalbed Methane Proved Reserves Revision Increases (Billion Cubic Feet)",1,"Annual",2011 ,"Release...

457

,"Texas--RRC District 5 Coalbed Methane Proved Reserves (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

458

,"Texas--RRC District 10 Coalbed Methane Proved Reserves (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

459

NETL: Methane Hydrates - DOE/NETL Projects - Verification Of...  

NLE Websites -- All DOE Office Websites (Extended Search)

will help to determine bottomhole pressure, predict more accurate production rates of methane and water, and facilitate the selection of hydrate reservoirs for economic...

460

,"Ohio Coalbed Methane Proved Reserves (Billion Cubic Feet)"  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

Note: This page contains sample records for the topic "methane nonmethane hydrocarbons" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

,"North Dakota Coalbed Methane Proved Reserves (Billion Cubic...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

462

,"Louisiana--North Coalbed Methane Proved Reserves (Billion Cubic...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

463

NETL: Methane Hydrates - DOE/NETL Projects - Properties of Hydrate...  

NLE Websites -- All DOE Office Websites (Extended Search)

is to measure physical, chemical, mechanical, and hydrologic property changes in methane hydrate-bearing sediments subjected to injection of carbon dioxide and nitrogen....

464

,"Florida Coalbed Methane Proved Reserves (Billion Cubic Feet...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

465

Converting Methane to Methanol: Structural Insight into the Reaction...  

NLE Websites -- All DOE Office Websites (Extended Search)

Biology, Wayne State University, School of Medicine, Detroit, Michigan 48201, USA. Methane-oxidizing bacteria (methanotrophs) are extremely attractive from a chemist's...

466

,"U.S. Coalbed Methane Proved Reserves Acquisitions (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

ame","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Coalbed Methane Proved Reserves Acquisitions (Billion Cubic Feet)",1,"Annual",2011 ,"Release...

467

NETL: Methane Hydrates - DOE/NETL Projects - Development of a...  

NLE Websites -- All DOE Office Websites (Extended Search)

activities to assess the geologic occurrence, regional context, and characteristics of methane hydrate deposits along the continental margins of the U.S. with an emphasis on the...

468

,"New Mexico--East Coalbed Methane Proved Reserves (Billion Cubic...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

469

,"U.S. Coalbed Methane Proved Reserves Revision Decreases (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

ame","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Coalbed Methane Proved Reserves Revision Decreases (Billion Cubic Feet)",1,"Annual",2011 ,"Release...

470

Department of Energy Advance Methane Hydrates Science and Technology  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Advance Methane Hydrates Science and Technology Projects Dollars awarded will go to research the advance understanding of the nature and occurrence of Deepwater and Arctic gas...

471

,"New Mexico Coalbed Methane Proved Reserves (Billion Cubic Feet...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

472

,"Texas--RRC District 4 Onshore Coalbed Methane Proved Reserves...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

473

,"West Virginia Coalbed Methane Proved Reserves (Billion Cubic...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

474

,"New York Coalbed Methane Proved Reserves (Billion Cubic Feet...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

475

Table 16. Coalbed methane proved reserves and production, 2007 - 2011  

U.S. Energy Information Administration (EIA)

Table 16: Coalbed methane proved reserves and production, 2007 – 2011 billion cubic feet State and Subdivision 2007 2008 2009 2010 2011 2007 2008 2009 2010 2011

476

EA-1157: Methyl Chloride via Oxyhydrochlorination of Methane...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

1157: Methyl Chloride via Oxyhydrochlorination of Methane: A Building Black for Chemicals and Fuels from Natural Gas, Carrollton, Kentucky EA-1157: Methyl Chloride via...

477

NETL: Methane Hydrates - DOE/NETL Projects - Mapping Permafrost...  

NLE Websites -- All DOE Office Websites (Extended Search)

20 percent of the land area in the northern hemisphere and often contains associated methane hydrate. Numerous studies have indicated that permafrost and hydrate are actively...

478

,"Louisiana--State Offshore Coalbed Methane Proved Reserves ...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

479

,"New Mexico--West Coalbed Methane Proved Reserves (Billion Cubic...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

480

,"Kentucky Coalbed Methane Proved Reserves (Billion Cubic Feet...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

Note: This page contains sample records for the topic "methane nonmethane hydrocarbons" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

,"Texas (with State Offshore) Coalbed Methane Proved Reserves...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

482

,"Texas--RRC District 1 Coalbed Methane Proved Reserves (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

483

,"Arkansas Coalbed Methane Proved Reserves (Billion Cubic Feet...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

484

NETL: Methane Hydrates - Gas Hydrate Research in Deep Sea Sediments...  

NLE Websites -- All DOE Office Websites (Extended Search)

Biogeochemistry Section, Naval Research Laboratory, Washington, D.C. 20375 Background Methane is a potent greenhouse gas necessitating a better understanding of the mechanisms...

485

,"Lower 48 States Coalbed Methane Proved Reserves (Billion Cubic...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

486

NETL-ORD Methane Hydrate Project - Experimental Analysis and...  

NLE Websites -- All DOE Office Websites (Extended Search)

to describe the experimentally-observed stress-strain behavior as a function of methane hydrate saturation All the experimental data and their relationships will be...

487

,"Federal Offshore--Texas Coalbed Methane Proved Reserves (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

488

,"Texas--RRC District 6 Coalbed Methane Proved Reserves (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

489

,"U.S. Coalbed Methane Proved Reserves New Reservoir Discoveries...  

U.S. Energy Information Administration (EIA) Indexed Site

ame","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Coalbed Methane Proved Reserves New Reservoir Discoveries in Old Fields (Billion Cubic...

490

,"California - San Joaquin Basin Onshore Coalbed Methane Proved...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

491

NETL: Methane Hydrates - DOE/JIP GOM Hydrate Research Cruise  

NLE Websites -- All DOE Office Websites (Extended Search)

Analysis - Fugro Operations and Geotechnical Investigations PDF-7.13MB National Methane Hydrate R&D Program website. Photos: Photo Gallery - miscellaneous - Photos from...

492

,"Louisiana (with State Offshore) Coalbed Methane Proved Reserves...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

493

,"California--State Offshore Coalbed Methane Proved Reserves...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

494

NETL: Methane Hydrates - DOE/NETL Projects - Reconstructing Paleo...  

NLE Websites -- All DOE Office Websites (Extended Search)

to track diagenetic changes that are associated with the anaerobic oxidation of methane. To achieve this goal, this project aims to (1) reconstruct the paleo-positions of...

495

,"Alaska (with Total Offshore) Coalbed Methane Proved Reserves...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

496

,"Louisiana--South Onshore Coalbed Methane Proved Reserves (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

497

NETL: Methane Hydrates - 2012 Ignik Sikumi gas hydrate field...  

NLE Websites -- All DOE Office Websites (Extended Search)

fluid, by flowmeters in the Low-flow Gas Measurement Skid. Compositional analysis of methane, nitrogen, carbon dioxide, and tracers pumped during injection are being monitored...

498

Evaluation of Fluid Transport Properties of Coal Bed Methane Reservoirs.  

E-Print Network (OSTI)

??Determination of petro-physical properties of coal bed methane (CBM) reservoirs is essential in evaluating a potential prospect for commercial exploitation. In particular, permeability is the… (more)

Alexis, Dennis Arun

2013-01-01T23:59:59.000Z

499

,"Ohio Coalbed Methane Proved Reserves, Reserves Changes, and...  

U.S. Energy Information Administration (EIA) Indexed Site

,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Ohio Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2010,"...

500

UPGRADING METHANE USING ULTRA-FAST THERMAL SWING ADSORPTION  

SciTech Connect

The purpose of this project is to design and demonstrate an approach to upgrade low-BTU methane streams from coal mines to pipeline-quality natural gas. The objective of Phase I of the project was to assess the feasibility of upgrading low-Btu methane streams using ultra-fast thermal swing adsorption (TSA) using Velocys' modular microchannel process technology. The project is on schedule and under budget. For Task 1.1, the open literature, patent information, and vendor contacts were surveyed to identify adsorbent candidates for experimental validation and subsequent demonstration in an MPT-based ultra-fast TSA separation for methane upgrading. The leading candidates for preferential adsorption of methane over nitrogen are highly microporous carbons. A Molecular Gate{trademark} zeolite from Engelhard Corporation has emerged as a candidate. For Task 1.2, experimental evaluation of adsorbents was initiated, and data were collected on carbon (MGN-101) from PICA, Inc. This carbon demonstrated a preferential capacity for methane over nitrogen, as well as a reasonable thermal swing differential capacity for a 90% methane and 10% nitrogen mixture. A similar methane swing capacity at 2 psig was measured. The mixture composition is relevant because gob gas contains nearly 85% methane and must be purified to 97% methane for pipeline quality.

Anna Lee Tonkovich

2004-01-01T23:59:59.000Z