National Library of Energy BETA

Sample records for metamaterial transparent conductor

  1. Zinc oxyfluoride transparent conductor

    DOE Patents [OSTI]

    Gordon, Roy G.

    1991-02-05

    Transparent, electrically conductive and infrared-reflective films of zinc oxyfluoride are produced by chemical vapor deposition from vapor mixtures of zinc, oxygen and fluorine-containing compounds. The substitution of fluorine for some of the oxygen in zinc oxide results in dramatic increases in the electrical conductivity. For example, diethyl zinc, ethyl alcohol and hexafluoropropene vapors are reacted over a glass surface at 400.degree. C. to form a visibly transparent, electrically conductive, infrared reflective and ultraviolet absorptive film of zinc oxyfluoride. Such films are useful in liquid crystal display devices, solar cells, electrochromic absorbers and reflectors, energy-conserving heat mirrors, and antistatic coatings.

  2. Flexible transparent conductors based on metal nanowire networks

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Guo, Chuan Fei; Ren, Zhifeng

    2015-04-01

    Few conductors are transparent and flexible. Metals have the best electrical conductivity, but they are opaque and stiff in bulk form. However, metals can be transparent and flexible when they are very thin or properly arranged on the nanoscale. This review focuses on the flexible transparent conductors based on percolating networks of metal. Specifically, we discuss the fabrication, the means to improve the electrical conductivity, the large stretchability and its mechanism, and the applications of these metal networks. We also suggest some criteria for evaluating flexible transparent conductors and propose some new research directions in this emerging field.

  3. Nanostructured Transparent Conductors Have Potential for Thin-Film Photovoltaics (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-08-01

    Possible alternatives to transparent conductors show promise for enabling new processes and reducing costs.

  4. Transparent conductor-Si pillars heterojunction photodetector

    SciTech Connect (OSTI)

    Yun, Ju-Hyung; Kim, Joondong; Park, Yun Chang

    2014-08-14

    We report a high-performing heterojunction photodetector by enhanced surface effects. Periodically, patterned Si substrates were used to enlarge the photo-reactive regions and yield proportionally improved photo-responses. An optically transparent indium-tin-oxide (ITO) was deposited on a Si substrate and spontaneously formed an ITO/Si heterojunction. Due to an electrical conductive ITO film, ITO/Si heterojunction device can be operated at zero-bias, which effectively suppresses the dark current, resulting in better performances than those by a positive or a negative bias operation. This zero-bias operating heterojunction device exhibits a short response time (? 22.5?ms) due to the physical reaction to the incident light. We revealed that the location of the space charge region (SCR) is crucial for a specific photon-wavelength response. The SCR space has the highest collection efficiency of the photo-generated carriers. The photo-response can be maximized when we design the photodetector by superposing the SCR space over a corresponding photon-absorption length. The surface enhanced Si pillar devices significantly improved the photo-responses ratios from that of a planar Si device. According to this design scheme, a high photo-response ratio of 5560% was achieved at a wavelength of 600?nm. This surfaced-enhanced heterojunction design scheme would be a promising approach for various photoelectric applications.

  5. Preparation of transparent conductors ferroelectric memory materials and ferrites

    DOE Patents [OSTI]

    Bhattacharya, R.N.; Ginley, D.S.

    1998-07-28

    A process is described for the preparation by electrodeposition of metal oxide film and powder compounds for ferroelectric memory materials and ferrites wherein the metal oxide includes a plurality of metals. The process comprises providing an electrodeposition bath, providing soluble salts of the metals to this bath, electrically energizing the bath to thereby cause formation of a recoverable film of metal on the electrode, recovering the resultant film as a film or a powder, and recovering powder formed on the floor of the bath. The films and powders so produced are subsequently annealed to thereby produce metal oxide for use in electronic applications. The process can be employed to produce metal-doped metal oxide film and powder compounds for transparent conductors. The process for preparation of these metal-doped metal oxides follows that described above.

  6. Preparation of transparent conductors ferroelectric memory materials and ferrites

    DOE Patents [OSTI]

    Bhattacharya, Raghu Nath; Ginley, David S.

    1998-01-01

    A process for the preparation by electrodeposition of metal oxide film and powder compounds for ferroelectric memory materials and ferrites wherein the metal oxide includes a plurality of metals. The process comprises providing an electrodeposition bath, providing soluble salts of the metals to this bath, electrically energizing the bath to thereby cause formation of a recoverable film of metal on the electrode, recovering the resultant film as a film or a powder, and recovering powder formed on the floor of the bath. The films and powders so produced are subsequently annealed to thereby produce metal oxide for use in electronic applications. The process can be employed to produce metal-doped metal oxide film and powder compounds for transparent conductors. The process for preparation of these metal-doped metal oxides follows that described above.

  7. Low-loss metamaterial electromagnetically induced transparency based on electric toroidal dipolar response

    SciTech Connect (OSTI)

    Li, Hai-ming; Liu, Shao-bin Liu, Si-yuan; Ding, Guo-wen; Yang, Hua; Yu, Zhi-yang; Zhang, Hai-feng; Wang, Shen-yun

    2015-02-23

    In this paper, a low-loss and high transmission analogy of electromagnetically induced transparency based on electric toroidal dipolar response is numerically and experimentally demonstrated. It is obtained by the excitation of the low-loss electric toroidal dipolar response, which confines the magnetic field inside a dielectric substrate with toroidal geometry. The metamaterial electromagnetically induced transparency (EIT) structure is composed of the cut wire and asymmetric split-ring resonators. The transmission level is as high as 0.88, and the radiation loss is greatly suppressed, which can be proved by the surface currents distributions, the magnetic field distributions, and the imaginary parts of the effective permeability and permittivity. It offers an effective way to produce low-loss and high transmission metamaterial EIT.

  8. Transparent conductor-embedding nanolens for Si solar cells

    SciTech Connect (OSTI)

    Kim, Joondong E-mail: junsin@skku.edu Kumar, Melvin David; Yun, Ju-Hyung; Kim, Hongsik; Park, Hyeong-Ho; Lee, Eunsongyi; Kim, Dong-wook; Kim, Hyunyub; Kim, Mingeon; Yi, Junsin E-mail: junsin@skku.edu; Jeong, Chaehwan E-mail: junsin@skku.edu

    2015-04-13

    We present a large-scale applicable nanolens-embedding solar cell. An electrically conductive and optically transparent indium-tin-oxide (ITO) thin film was coated on a Si substrate. After then, periodically patterned ITO nanodome-arrays were formed on the ITO film by using a nano-imprint method. This structure is effective to reduce the incident light reflection for broad wavelengths and also efficient to drive the incident photons into a light-absorbing Si substrate. There exist two electric fields. One is by a p/n junction and the other is by the light absorption into Si. We designed nanolens structures to overlap two electric fields and demonstrate highly improved solar cell performances of current and voltage values from a planar structure.

  9. Metamaterials

    DOE Patents [OSTI]

    Smith, David R.; Schurig, David; Starr, Anthony F.; Mock, Jack J.

    2014-09-09

    One exemplary metamaterial is formed from a plurality of individual unit cells, at least a portion of which have a different permeability than others. The plurality of individual unit cells are arranged to provide a metamaterial having a gradient index along at least one axis. Such metamaterials can be used to form lenses, for example.

  10. All-dielectric metasurface analogue of electromagnetically induced transparency [High Quality Factor Fano-Resonant All-Dielectric Metamaterials

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yang, Yuanmu; Kravchenko, Ivan I.; Briggs, Dayrl P.; Valentine, Jason

    2014-12-16

    Fano-resonant plasmonic metamaterials and nanostructures have become a major focus of the nanophotonics fields over the past several years due their ability to produce high quality factor (Q-factor) resonances. The origin of such resonances is the interference between a broad and narrow resonance, ultimately allowing suppression of radiative damping. However, Fano-resonant plasmonic structures still suffer non-radiative damping due to Ohmic loss, ultimately limiting the achievable Q-factors to values less than ~10. Here, we report experimental demonstration of Fano-resonant silicon-based metamaterials that have a response that mimics the electromagnetically induced transparency (EIT) found in atomic systems. Due to extremely low absorptionmore » loss, a record-high quality factor (Q-factor) of 306 was experimentally observed. Furthermore, the unit cell of the metamaterial was designed with a feed-gap which results in strong local field enhancement in the surrounding medium resulting in strong light-matter interaction. This allows the metamaterial to serve as a refractive index sensor with a figure-of-merit (FOM) of 101, far exceeding the performance of previously demonstrated localized surface plasmon resonance sensors.« less

  11. Transparent Conductors from Carbon Nanotubes LBL-Assembled with Polymer Dopant with ?-? Electron Transfer

    SciTech Connect (OSTI)

    Zhu, Jian; Shim, Bong Sup; Di Prima, Matthew; Kotov, Nicholas A.

    2011-01-01

    Single-walled carbon nanotube (SWNT) and other carbon-based coatings are being considered as replacements for indium tin oxide (ITO). The problems of transparent conductors (TCs) coatings from SWNT and similar materials include poor mechanical properties, high roughness, low temperature resilience, and fast loss of conductivity. The simultaneous realization of these desirable characteristics can be achieved using high structural control of layer-by-layer (LBL) deposition, which is demonstrated by the assembly of hydroethyl cellulose (HOCS) and sulfonated polyetheretherketone (SPEEK)-SWNTs. A new type of SWNT doping based on electron transfer from valence bands of nanotubes to unoccupied levels of SPEEK through ?-? interactions was identified for this system. It leads to a conductivity of 1.1 10? S/m at 66 wt % loadings of SWNT. This is better than other polymer/SWNT composites and translates into surface conductivity of 920 ?/? and transmittance of 86.7% at 550 nm. The prepared LBL films also revealed unusually high temperature resilience up to 500 C, and low roughness of 3.5 nm (ITO glass -2.4 nm). Tensile modulus, ultimate strength, and toughness of such coatings are 13 2 GPa, 366 35 MPa, and 8 3 kJ/m, respectively, and exceed corresponding parameters of all similar TCs. The cumulative figure of merit, ?TC, which included the critical failure strain relevant for flexible electronics, was ?TC = 0.022 and should be compared to ?TC = 0.006 for commercial ITO. Further optimization is possible using stratified nanoscale coatings and improved doping from the macromolecular LBL components.

  12. Plasmonic Three-Dimensional Transparent Conductor Based on Al-Doped Zinc Oxide-Coated Nanostructured Glass Using Atomic Layer Deposition

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Malek, Gary A.; Aytug, Tolga; Liu, Qingfeng; Wu, Judy

    2015-04-02

    Transparent nanostructured glass coatings, fabricated on glass substrates, with a unique three-dimensional (3D) architecture were utilized as the foundation for the design of plasmonic 3D transparent conductors. Transformation of the non-conducting 3D structure to a conducting 3D network was accomplished through atomic layer deposition of aluminum-doped zinc oxide (AZO). After AZO growth, gold nanoparticles (AuNPs) were deposited by electronbeam evaporation to enhance light trapping and decrease the overall sheet resistance. Field emission scanning electron microscopy and atomic force microcopy images revealed the highly porous, nanostructured morphology of the AZO coated glass surface along with the in-plane dimensions of the depositedmore » AuNPs. Sheet resistance measurements conducted on the coated samples verified that the electrical properties of the 3D network are comparable to that of the untextured two-dimensional AZO coated glass substrates. In addition, transmittance measurements of the glass samples coated with various AZO thicknesses showed preservation of the highly transparent nature of each sample, while the AuNPs demonstrated enhanced light scattering as well as light-trapping capability.« less

  13. Plasmonic Three-Dimensional Transparent Conductor Based on Al-Doped Zinc Oxide-Coated Nanostructured Glass Using Atomic Layer Deposition

    SciTech Connect (OSTI)

    Malek, Gary A.; Aytug, Tolga; Liu, Qingfeng; Wu, Judy

    2015-04-02

    Transparent nanostructured glass coatings, fabricated on glass substrates, with a unique three-dimensional (3D) architecture were utilized as the foundation for the design of plasmonic 3D transparent conductors. Transformation of the non-conducting 3D structure to a conducting 3D network was accomplished through atomic layer deposition of aluminum-doped zinc oxide (AZO). After AZO growth, gold nanoparticles (AuNPs) were deposited by electronbeam evaporation to enhance light trapping and decrease the overall sheet resistance. Field emission scanning electron microscopy and atomic force microcopy images revealed the highly porous, nanostructured morphology of the AZO coated glass surface along with the in-plane dimensions of the deposited AuNPs. Sheet resistance measurements conducted on the coated samples verified that the electrical properties of the 3D network are comparable to that of the untextured two-dimensional AZO coated glass substrates. In addition, transmittance measurements of the glass samples coated with various AZO thicknesses showed preservation of the highly transparent nature of each sample, while the AuNPs demonstrated enhanced light scattering as well as light-trapping capability.

  14. Diameter-Refined Metallic Carbon Nanotubes as Optically Tunable Transparent

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Conductors | ANSER Center | Argonne-Northwestern National Laboratory Diameter-Refined Metallic Carbon Nanotubes as Optically Tunable Transparent Conductors Home > Research > ANSER Research Highlights > Diameter-Refined Metallic Carbon Nanotubes as Optically Tunable Transparent Conductors

  15. Terahertz metamaterials

    DOE Patents [OSTI]

    Peralta, Xomalin Guaiuli; Brener, Igal; O'Hara, John; Azad, Abul; Smirnova, Evgenya; Williams, John D.; Averitt, Richard D.

    2014-08-12

    Terahertz metamaterials comprise a periodic array of resonator elements disposed on a dielectric substrate or thin membrane, wherein the resonator elements have a structure that provides a tunable magnetic permeability or a tunable electric permittivity for incident electromagnetic radiation at a frequency greater than about 100 GHz and the periodic array has a lattice constant that is smaller than the wavelength of the incident electromagnetic radiation. Microfabricated metamaterials exhibit lower losses and can be assembled into three-dimensional structures that enable full coupling of incident electromagnetic terahertz radiation in two or three orthogonal directions. Furthermore, polarization sensitive and insensitive metamaterials at terahertz frequencies can enable new devices and applications.

  16. Aluminum plasmonic metamaterials for structural color printing

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cheng, Fei; Gao, Jie; Stan, Liliana; Rosenmann, Daniel; Czaplewski, David; Yang, Xiaodong

    2015-05-26

    We report a structural color printing platform based on aluminum plasmonic metamaterials supporting near perfect light absorption and narrow-band spectral response tunable across the visible spectrum to realize high-resolution, angle-insensitive color printing with high color purity and saturation. Additionally, the fabricated metamaterials can be protected by a transparent polymer thin layer for ambient use with further improved color performance. The demonstrated structural color printing with aluminum plasmonic metamaterials offers great potential for relevant applications such as security marking and information storage.

  17. Electrically tunable infrared metamaterial devices

    DOE Patents [OSTI]

    Brener, Igal; Jun, Young Chul

    2015-07-21

    A wavelength-tunable, depletion-type infrared metamaterial optical device is provided. The device includes a thin, highly doped epilayer whose electrical permittivity can become negative at some infrared wavelengths. This highly-doped buried layer optically couples with a metamaterial layer. Changes in the transmission spectrum of the device can be induced via the electrical control of this optical coupling. An embodiment includes a contact layer of semiconductor material that is sufficiently doped for operation as a contact layer and that is effectively transparent to an operating range of infrared wavelengths, a thin, highly doped buried layer of epitaxially grown semiconductor material that overlies the contact layer, and a metallized layer overlying the buried layer and patterned as a resonant metamaterial.

  18. Metamaterials | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Metamaterials Research Personnel Updates Publications Engineering a Light Touch Read More Carbon Layers Lead the Way towards a New Generation of Metamaterials Read More Novel Broadband Terahertz Light Emitters Read More Previous Pause Next Modeling Many of the technologies that underpin our economy and enable our standard of living depend on advanced materials. Therefore, the engine for progress in many scientific disciplines is the discovery and understanding of new materials. Metamaterials are

  19. Resonant dielectric metamaterials

    DOE Patents [OSTI]

    Loui, Hung; Carroll, James; Clem, Paul G; Sinclair, Michael B

    2014-12-02

    A resonant dielectric metamaterial comprises a first and a second set of dielectric scattering particles (e.g., spheres) having different permittivities arranged in a cubic array. The array can be an ordered or randomized array of particles. The resonant dielectric metamaterials are low-loss 3D isotropic materials with negative permittivity and permeability. Such isotropic double negative materials offer polarization and direction independent electromagnetic wave propagation.

  20. Transparent electrode for optical switch

    DOE Patents [OSTI]

    Goldhar, Julius; Henesian, Mark A.

    1986-01-01

    A low pressure gas electrode utilizing ionized gas in a glow discharge regime forms a transparent electrode for electro-optical switches. The transparent electrode comprises a low pressure gas region on both sides of the crystal. When the gas is ionized, e.g., by a glow discharge in the low pressure gas, the plasma formed is a good conductor. The gas electrode acts as a highly uniform conducting electrode. Since the plasma is transparent to a high energy laser beam passing through the crystal, the electrode is a transparent electrode. A crystal exposed from two sides to such a plasma can be charged up uniformly to any desired voltage. The plasma can be created either by the main high voltage pulser used to charge up the crystal or by auxiliary discharges or external sources of ionization. A typical configuration utilizes 10 torr argon in the discharge region adjacent to each crystal face.

  1. Active terahertz metamaterial devices

    DOE Patents [OSTI]

    Chen, Houtong; Padilla, Willie John; Averitt, Richard Douglas; O'Hara, John F.; Lee, Mark

    2010-11-02

    Metamaterial structures are taught which provide for the modulation of terahertz frequency signals. Each element within an array of metamaterial (MM) elements comprises multiple loops and at least one gap. The MM elements may comprise resonators with conductive loops and insulated gaps, or the inverse in which insulated loops are present with conductive gaps; each providing useful transmissive control properties. The metamaterial elements are fabricated on a semiconducting substrate configured with a means of enhancing or depleting electrons from near the gaps of the MM elements. An on to off transmissivity ratio of about 0.5 is achieved with this approach. Embodiments are described in which the MM elements incorporated within a Quantum Cascade Laser (QCL) to provide surface emitting (SE) properties.

  2. Magnetic Response and Negative Refractive Index of Metamaterials

    SciTech Connect (OSTI)

    Koschny, Th.; Zhou, J.; Soukoulis, C.M.

    2007-05-04

    We study the scaling of negative magnetic response of the SRR from microwave to upper THz frequencies. We show, that the linear scaling breaks down for SRR sizes below the order of 1 {micro}m. This breakdown is due to the contribution of the finite electron mass to the inductance of the effective LC oscillator. While at microwave frequencies metals can be treated as near-perfect conductors, close to optical frequencies they rather constitute lossy negative dielectrics. We also study the scaling of the losses in SRR as well as the higher order excitations or plasmon modes and their magnetic response. We discuss the non-resonant diamagnetic response of the SRR and the corresponding corrections to the shape of the frequency dependent effective permeability of the metamaterial. We discuss the connection of recently suggested alternative negative index metamaterial designs in a unified picture.

  3. Three-dimensional metamaterials

    DOE Patents [OSTI]

    Burckel, David Bruce

    2012-06-12

    A fabrication method is capable of creating canonical metamaterial structures arrayed in a three-dimensional geometry. The method uses a membrane suspended over a cavity with predefined pattern as a directional evaporation mask. Metallic and/or dielectric material can be evaporated at high vacuum through the patterned membrane to deposit resonator structures on the interior walls of the cavity, thereby providing a unit cell of micron-scale dimension. The method can produce volumetric metamaterial structures comprising layers of such unit cells of resonator structures.

  4. Optical Magnetism from Dielectric Resonator Metamaterials. (Conference...

    Office of Scientific and Technical Information (OSTI)

    Optical Magnetism from Dielectric Resonator Metamaterials. Citation Details In-Document Search Title: Optical Magnetism from Dielectric Resonator Metamaterials. Abstract not ...

  5. Metamaterials - new opportunity in manipulating terahertz radiation...

    Office of Scientific and Technical Information (OSTI)

    Metamaterials - new opportunity in manipulating terahertz radiation Citation Details In-Document Search Title: Metamaterials - new opportunity in manipulating terahertz radiation...

  6. Air transparent soundproof window

    SciTech Connect (OSTI)

    Kim, Sang-Hoon; Lee, Seong-Hyun

    2014-11-15

    A soundproof window or wall which is transparent to airflow is presented. The design is based on two wave theories: the theory of diffraction and the theory of acoustic metamaterials. It consists of a three-dimensional array of strong diffraction-type resonators with many holes centered on each individual resonator. The negative effective bulk modulus of the resonators produces evanescent wave, and at the same time the air holes with subwavelength diameter existed on the surfaces of the window for macroscopic air ventilation. The acoustic performance levels of two soundproof windows with air holes of 20mm and 50mm diameters were measured. The sound level was reduced by about 30 - 35dB in the frequency range of 400 - 5,000Hz with the 20mm window, and by about 20 - 35dB in the frequency range of 700 - 2,200Hz with the 50mm window. Multi stop-band was created by the multi-layers of the window. The attenuation length or the thickness of the window was limited by background noise. The effectiveness of the soundproof window with airflow was demonstrated by a real installation.

  7. Enhanced structural color generation in aluminum metamaterials coated with a thin polymer layer

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cheng, Fei; Yang, Xiaodong; Rosenmann, Daniel; Stan, Liliana; Czaplewski, David; Gao, Jie

    2015-09-18

    A high-resolution and angle-insensitive structural color generation platform is demonstrated based on triple-layer aluminum-silica-aluminum metamaterials supporting surface plasmon resonances tunable across the entire visible spectrum. The color performances of the fabricated aluminum metamaterials can be strongly enhanced by coating a thin transparent polymer layer on top. The results show that the presence of the polymer layer induces a better impedance matching for the plasmonic resonances to the free space so that strong light absorption can be obtained, leading to the generation of pure colors in cyan, magenta, yellow and black (CMYK) with high color saturation.

  8. Nanoporous plasmonic metamaterials

    SciTech Connect (OSTI)

    Biener, J; Nyce, G W; Hodge, A M; Biener, M M; Hamza, A V; Maier, S A

    2007-05-24

    We review different routes for the generation of nanoporous metallic foams and films exhibiting well-defined pore size and short-range order. Dealloying and templating allows the generation of both two- and three-dimensional structures which promise a well defined plasmonic response determined by material constituents and porosity. Viewed in the context of metamaterials, the ease of fabrication of samples covering macroscopic dimensions is highly promising, and suggests more in-depth investigations of the plasmonic and photonic properties of this material system for photonic applications.

  9. Mid-infrared tunable metamaterials

    DOE Patents [OSTI]

    Brener, Igal; Miao, Xiaoyu; Shaner, Eric A; Passmore, Brandon Scott; Jun, Young Chul

    2015-04-28

    A mid-infrared tunable metamaterial comprises an array of resonators on a semiconductor substrate having a large dependence of dielectric function on carrier concentration and a semiconductor plasma resonance that lies below the operating range, such as indium antimonide. Voltage biasing of the substrate generates a resonance shift in the metamaterial response that is tunable over a broad operating range. The mid-infrared tunable metamaterials have the potential to become the building blocks of chip based active optical devices in mid-infrared ranges, which can be used for many applications, such as thermal imaging, remote sensing, and environmental monitoring.

  10. Selective radiative heating of nanostructures using hyperbolic metamaterials

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ding, Ding; Minnich, Austin J

    2015-01-01

    Hyperbolic metamaterials (HMM) are of great interest due to their ability to break the diffraction limit for imaging and enhance near-field radiative heat transfer. Here we demonstrate that an annular, transparent HMM enables selective heating of a sub-wavelength plasmonic nanowire by controlling the angular mode number of a plasmonic resonance. A nanowire emitter, surrounded by an HMM, appears dark to incoming radiation from an adjacent nanowire emitter unless the second emitter is surrounded by an identical lens such that the wavelength and angular mode of the plasmonic resonance match. Our result can find applications in radiative thermal management.

  11. Floating insulated conductors for heating subsurface formations

    DOE Patents [OSTI]

    Burns, David; Goodwin, Charles R.

    2014-07-29

    A heating system for a subsurface formation includes a conduit located in a first opening in the subsurface formation. Three electrical conductors are located in the conduit. A return conductor is located inside the conduit. The return conductor is electrically coupled to the ends of the electrical conductors distal from the surface of the formation. Insulation is located inside the conduit. The insulation electrically insulates the three electrical conductors, the return conductor, and the conduit from each other.

  12. Coated Conductors Cylinder Ltd | Open Energy Information

    Open Energy Info (EERE)

    Ltd Jump to: navigation, search Name: Coated Conductors Cylinder Ltd. Place: Malvern, England, United Kingdom Zip: WR14 3SZ Product: Coated Conductors Consultancy Ltd. (3-Cs)...

  13. YBCO COATED CONDUCTORS

    SciTech Connect (OSTI)

    Paranthaman, Mariappan Parans

    2010-01-01

    Since the discovery of high-temperature superconductors (HTS) in 1986, both (Bi,Pb)2Sr2Ca2Cu3O10 (BSCCO or 2223 with a critical temperature, Tc of 110 K) and YBa2Cu3O7- (YBCO or 123 with a Tc of 91 K) have emerged as the leading candidate materials for the first generation (1G) and second generation (2G) high temperature superconductor wires or tapes that will carry high critical current density in liquid nitrogen temperatures [1-7]. The crystal structures and detailed fundamental properties of BSCCO and YBCO superconductors have been reviewed by Matsumoto in a separate chapter in this book. The U.S. Department of Energy s target price for the conductor is close to the current copper wire cost of $10-50/kA-meter, i.e. a meter of copper type conductor carrying 1000 A current costs ~ $ 50 [8]. The long-term goal for the DOE, Office of Electricity, Advanced Conductors and Cables program is to achieve HTS wire in 1000 meters long with current carrying capacity of 1000 A/cm [8]. Robust, high-performance HTS wire will certainly revolutionize the electric power grid and various other electric power equipments as well. Sumitomo Electric Power (Japan) has been widely recognized as the world leader in manufacturing the first-generation HTS wires based on BSCCO materials using the Oxide-Powder-In-Tube (OPIT) over-pressure process [9]. Typically, 1G HTS wires carry critical currents, Ic, of over 200 Amperes (A) in piece lengths of one kilometer lengths at the standard 4 mm width and ~ 200 m thickness. However, due to the higher cost of 1G wire, mainly because of the cost of Ag alloy sheath, the researchers shifted their effort towards the development of YBCO (second generation 2G) tapes in the last fifteen years [1-7]. One of the main obstacles to the ability to carry high critical currents in YBCO films has been the phenomenon of weak links, i.e., grain boundaries formed by the misalignment of neighboring YBCO grains are known to form obstacles to current flow [10]. By

  14. Sputtered pin amorphous silicon semi-conductor device and method therefor

    DOE Patents [OSTI]

    Moustakas, Theodore D.; Friedman, Robert A.

    1983-11-22

    A high efficiency amorphous silicon PIN semi-conductor device is constructed by the sequential sputtering of N, I and P layers of amorphous silicon and at least one semi-transparent ohmic electrode. A method of construction produces a PIN device, exhibiting enhanced physical integrity and facilitates ease of construction in a singular vacuum system and vacuum pump down procedure.

  15. Conductor for a fluid-cooled winding

    DOE Patents [OSTI]

    Kenney, Walter J.

    1983-01-01

    A conductor and method of making the conductor are provided for use in winding electrical coils which are cooled by a fluid communicating with the conductor. The conductor is cold worked through twisting and reshaping steps to form a generally rectangular cross section conductor having a plurality of helical cooling grooves extending axially of the conductor. The conductor configuration makes it suitable for a wide variety of winding applications and permits the use of simple strip insulation between turns and perforated sheet insulation between layers of the winding.

  16. DOE Science Showcase - Metamaterials | OSTI, US Dept of Energy...

    Office of Scientific and Technical Information (OSTI)

    DOE Science Showcase - Metamaterials Metamaterials are a new class of ... These materials represent a new frontier in materials science. For more information about ...

  17. Metamaterial flexible sheets could transform optics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    planar, lightweight, and broadband ... materials, called metamaterials, that give scientists new levels of control over light ... The research was reported online in Science ...

  18. Quartz antenna with hollow conductor

    DOE Patents [OSTI]

    Leung, Ka-Ngo; Benabou, Elie

    2002-01-01

    A radio frequency (RF) antenna for plasma ion sources is formed of a hollow metal conductor tube disposed within a glass tube. The hollow metal tubular conductor has an internal flow channel so that there will be no coolant leakage if the outer glass tube of the antenna breaks. A portion of the RF antenna is formed into a coil; the antenna is used for inductively coupling RF power to a plasma in an ion source chamber. The antenna is made by first inserting the metal tube inside the glass tube, and then forming the glass/metal composite tube into the desired coil shape.

  19. Fluctuational electrodynamics of hyperbolic metamaterials

    SciTech Connect (OSTI)

    Guo, Yu; Jacob, Zubin

    2014-06-21

    We give a detailed account of equilibrium and non-equilibrium fluctuational electrodynamics of hyperbolic metamaterials. We show the unifying aspects of two different approaches; one utilizes the second kind of fluctuation dissipation theorem and the other makes use of the scattering method. We analyze the near-field of hyperbolic media at finite temperatures and show that the lack of spatial coherence can be attributed to the multi-modal nature of super-Planckian thermal emission. We also adopt the analysis to phonon-polaritonic super-lattice metamaterials and describe the regimes suitable for experimental verification of our predicted effects. The results reveal that far-field thermal emission spectra are dominated by epsilon-near-zero and epsilon-near-pole responses as expected from Kirchoff's laws. Our work should aid both theorists and experimentalists to study complex media and engineer equilibrium and non-equilibrium fluctuations for applications in thermal photonics.

  20. Three-component gyrotropic metamaterial

    SciTech Connect (OSTI)

    Tralle, Igor, E-mail: tralle@ur.edu.pl; Zi?ba, Pawe?; Pa?ko, Wioletta [Faculty of Mathematics and Natural Sciences, Theoretical Physics Department, University of Rzeszw, Pigonia 1, 35-310 Rzeszw (Poland)

    2014-06-21

    All of the proposed ever since designs of metamaterials are characterized by ever-increasing sophistication of fabrication methods. Here, a comparatively simple recipe for the fabrication of a metamaterial, which is both gyrotropic and of the simultaneously negative permittivity and permeability, is proposed. The idea is to make a mixture of three ingredients, where one of them would be responsible for the negativity of ?, while the other two would be responsible for the negativity of ?. The first component of the mixture is the swarm of single-domain ferromagnetic nano-particles, immersed in a mixture of other two, silver and mercury cadmium telluride. By carrying out the computer simulations, the domains of gyromagnetic metamaterial exist, relative to all parameters characterizing the model, that is, the temperature, external magnetic field, parameters of nano-particles, and the fraction of cadmium in Hg{sub 1?x}Cd{sub x}Te-compound as well as relative concentrations of the mixture components are established.

  1. Three-dimensional infrared metamaterial with asymmetric transmission

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kenanakis, George; Xomalis, Aggelos; Selimis, Alexandros; Vamvakaki, Maria; Farsari, Maria; Kafesaki, Maria; Soukoulis, Costas M.; Economou, Eleftherios N.

    2015-01-14

    A novel three-dimensional (3D) metallic metamaterial structure with asymmetric transmission for linear polarization is demonstrated in the infrared spectral region. The structure was fabricated by direct laser writing and selective electroless silver coating, a straightforward, novel technique producing mechanically and chemically stable 3D photonic structures. The structure unit cell is composed of a pair of conductively coupled magnetic resonators, and the asymmetric transmission response results from interplay of electric and magnetic responses; this equips the structure with almost total opaqueness along one propagation direction versus satisfying transparency along the opposite one. It also offers easily adjustable impedance, 90° one-way puremore » optical activity and backward propagation possibility, resulting thus in unique capabilities in polarization control and isolation applications. We show also that scaling down the structure can make it capable of exhibiting its asymmetric transmission and its polarization capabilities in the optical region.« less

  2. Three-dimensional infrared metamaterial with asymmetric transmission

    SciTech Connect (OSTI)

    Kenanakis, George; Xomalis, Aggelos; Selimis, Alexandros; Vamvakaki, Maria; Farsari, Maria; Kafesaki, Maria; Soukoulis, Costas M.; Economou, Eleftherios N.

    2015-01-14

    A novel three-dimensional (3D) metallic metamaterial structure with asymmetric transmission for linear polarization is demonstrated in the infrared spectral region. The structure was fabricated by direct laser writing and selective electroless silver coating, a straightforward, novel technique producing mechanically and chemically stable 3D photonic structures. The structure unit cell is composed of a pair of conductively coupled magnetic resonators, and the asymmetric transmission response results from interplay of electric and magnetic responses; this equips the structure with almost total opaqueness along one propagation direction versus satisfying transparency along the opposite one. It also offers easily adjustable impedance, 90° one-way pure optical activity and backward propagation possibility, resulting thus in unique capabilities in polarization control and isolation applications. We show also that scaling down the structure can make it capable of exhibiting its asymmetric transmission and its polarization capabilities in the optical region.

  3. Conductor-polymer composite electrode materials

    DOE Patents [OSTI]

    Ginley, D.S.; Kurtz, S.R.; Smyrl, W.H.; Zeigler, J.M.

    1984-06-13

    A conductive composite material useful as an electrode, comprises a conductor and an organic polymer which is reversibly electrochemically dopable to change its electrical conductivity. Said polymer continuously surrounds the conductor in intimate electrical contact therewith and is prepared by electrochemical growth on said conductor or by reaction of its corresponding monomer(s) on said conductor which has been pre-impregnated or pre-coated with an activator for said polymerization. Amount of the conductor is sufficient to render the resultant composite electrically conductive even when the polymer is in an undoped insulating state.

  4. Temperature limited heater utilizing non-ferromagnetic conductor

    DOE Patents [OSTI]

    Vinegar; Harold J. , Harris; Christopher Kelvin

    2012-07-17

    A heater is described. The heater includes a ferromagnetic conductor and an electrical conductor electrically coupled to the ferromagnetic conductor. The ferromagnetic conductor is positioned relative to the electrical conductor such that an electromagnetic field produced by time-varying current flow in the ferromagnetic conductor confines a majority of the flow of the electrical current to the electrical conductor at temperatures below or near a selected temperature.

  5. Well conductor support structure and method for using

    SciTech Connect (OSTI)

    Turner, J.W.; Glasscock, M.S.

    1990-09-25

    This patent describes a conductor support module for supporting well conductors of an offshore platform, the conductor support module being separate from but integrable with the jacket of the offshore platform. It comprises: substantially parallel vertical support members; and horizontal conductor support members attached to the vertical support members, the vertical spacing between adjacent horizontal conductor support members being determined by the lateral support requirements of the well conductors; whereby lateral loads on the well conductors are transferred from the well conductors to the conductor support module and thereby to the offshore platform.

  6. US ITER toroidal field coil conductor...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ITER toroidal field coil conductor production requires miles of niobium-tin superconducting wire. Photo: Oxford Superconducting Technology Continued on page 6 INSIDE: ITER Site ...

  7. Metamaterial flexible sheets could transform optics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Metamaterial flexible sheets could transform optics Metamaterial flexible sheets could transform optics Advances would boost security screening systems, infrared thermal cameras, energy harvesting, and radar systems June 5, 2013 A burst of laser energy 50 times greater than the worldwide output of electrical power slams into an extremely thin foil target to produce neutrons at Los Alamos National Laboratory's TRIDENT laser facility during a recent experiment, which proved that laser-driven

  8. Doped LZO buffer layers for laminated conductors

    DOE Patents [OSTI]

    Paranthaman, Mariappan Parans [Knoxville, TN; Schoop, Urs [Westborough, MA; Goyal, Amit [Knoxville, TN; Thieme, Cornelis Leo Hans [Westborough, MA; Verebelyi, Darren T [Oxford, MA; Rupich, Martin W [Framingham, MA

    2010-03-23

    A laminated conductor includes a metallic substrate having a surface, a biaxially textured buffer layer supported by the surface of the substrate, the biaxially textured buffer layer comprising LZO and a dopant for mitigating metal diffusion through the LZO, and a biaxially textured conductor layer supported by the biaxially textured buffer layer.

  9. Pd conductor for thick film hydrogen sensor

    SciTech Connect (OSTI)

    Felten, J.J.; Hoffheins, B.S.; Lauf, R.J.

    1996-12-31

    Cooperation between a materials developer and sensor designers has resulted in a palladium conductor used ro design and build a new hydrogen sensor that has superior performance characteristics and is also inexpensive to manufacture. Material characteristics give it faster response time and greater thermal/mechanical stability. The thick film palladium conductor paste, which can be fired at 850{degrees}C-950{degrees}C, has provided device designers a practical conductor paste with which to produce the improved sensor. The conductor uses a high surface area Pd powder combined with a binder glass that is chemically very inert, which combination produces a porous conductor that has good adhesion and chemical resistance. The current sensor design consists of three or four thick film Layers. Because of the flexibility of thick film techniques, the sensor element can be configured to any desired size and shape for specific instrument needs.

  10. Holes Are a Positive Thing: Designing Conductors for Solar Photovoltai...

    Office of Science (SC) Website

    Holes Are a Positive Thing: Designing Conductors for Solar Photovoltaics Basic Energy ... Holes Are a Positive Thing: Designing Conductors for Solar Photovoltaics Predicted by ...

  11. Dirac semimetal films as spin conductors on topological substrates...

    Office of Scientific and Technical Information (OSTI)

    Dirac semimetal films as spin conductors on topological substrates Citation Details In-Document Search Title: Dirac semimetal films as spin conductors on topological substrates ...

  12. Dirac semimetal films as spin conductors on topological substrates...

    Office of Scientific and Technical Information (OSTI)

    Publisher's Accepted Manuscript: Dirac semimetal films as spin conductors on topological substrates Title: Dirac semimetal films as spin conductors on topological substrates ...

  13. A Dictionary for Transparency

    SciTech Connect (OSTI)

    Kouzes, Richard T.

    2001-11-15

    There are many terms that are used in association with the U.S. Defense Threat Reduction Agency (DTRA) Transparency Project associated with the Mayak Fissile Materials Storage Facility. This is a collection of proposed definitions of these terms.

  14. Dielectric insulating polyolefin compounds and conductor products insulated therewith

    DOE Patents [OSTI]

    MacKenzie, Jr., Burton T.; Prober, Maurice; Kiersztyn, Stanley E.

    1979-01-01

    Polyolefin compounds containing nitrile polysiloxane fluid which have improved electrical properties, and electrical conductors insulated therewith.

  15. Mushroom plasmonic metamaterial infrared absorbers

    SciTech Connect (OSTI)

    Ogawa, Shinpei Fujisawa, Daisuke; Hata, Hisatoshi; Uetsuki, Mitsuharu; Misaki, Koji; Kimata, Masafumi

    2015-01-26

    There has been a considerable amount of interest in the development of various types of electromagnetic wave absorbers for use in different wavelength ranges. In particular, infrared (IR) absorbers with wavelength selectivity can be applied to advanced uncooled IR sensors, which would be capable of identifying objects through their radiation spectrum. In the present study, mushroom plasmonic metamaterial absorbers (MPMAs) for the IR wavelength region were designed and fabricated. The MPMAs consist of a periodic array of thin metal micropatches connected to a thin metal plate with narrow silicon (Si) posts. A Si post height of 200 nm was achieved by isotropic XeF{sub 2} etching of a thin Si layer sandwiched between metal plates. This fabrication procedure is relatively simple and is consistent with complementary metal oxide semiconductor technology. The absorption spectra of the fabricated MPMAs were experimentally measured. In addition, theoretical calculations of their absorption properties were conducted using rigorous coupled wave analysis. Both the calculated and measured absorbance results demonstrated that these MPMAs can realize strong selective absorption at wavelengths beyond the period of the array by varying the micropatch width. Absorbance values greater than 90% were achieved. Dual- or single-mode absorption can also be selected by varying the width of the Si posts. Pixel structures using such MPMAs could be used as high responsivity, high resolution and fast uncooled IR sensors.

  16. Casimir interactions for anisotropic magnetodielectric metamaterials

    SciTech Connect (OSTI)

    Da Rosa, Felipe S; Dalvit, Diego A; Milonni, Peter W

    2008-01-01

    We extend our previous work on the generalization of the Casimir-Lifshitz theory to treat anisotropic magnetodielectric media, focusing on the forces between metals and magnetodielectric metamaterials and on the possibility of inferring magnetic effects by measurements of these forces.

  17. Conductor load bearing roller for a gas-insulated transmission line having a corrugated outer conductor

    DOE Patents [OSTI]

    Fischer, William H.; Yoon, Kue H.

    1984-04-10

    A gas-insulated transmission line includes a corrugated outer conductor, an inner conductor disposed within and insulated from the outer conductor by means of support insulators and an insulating gas, and a transport device for supporting and permitting movement of the inner conductor/insulating support assembly axially along the corrugated outer conductor without radial displacement. The transport device includes two movable contacts, such as skids or rollers, supported on a common pivot lever, the pivot lever being rotatably disposed about a pivot lever axis, which pivot lever axis is in turn disposed on the periphery of a support insulator or particle trap if one is used. The movable contacts are separated axially a distance equal to the axial distance between the peaks and valleys of the corrugations of the outer conductor and separated radially a distance equal to the radial distance between the peaks and valleys of the corrugations of the outer conductor. The transport device has the pivot lever axis disposed perpendicular to the direction of travel of the inner conductor/insulating support assembly.

  18. Reducing the losses of optical metamaterials

    SciTech Connect (OSTI)

    Fang, Anan

    2010-12-15

    The field of metamaterials is driven by fascinating and far-reaching theoretical visions, such as perfect lenses, invisibility cloaking, and enhanced optical nonlinearities. However, losses have become the major obstacle towards real world applications in the optical regime. Reducing the losses of optical metamaterials becomes necessary and extremely important. In this thesis, two approaches are taken to reduce the losses. One is to construct an indefinite medium. Indefinite media are materials where not all the principal components of the permittivity and permeability tensors have the same sign. They do not need the resonances to achieve negative permittivity, {var_epsilon}. So, the losses can be comparatively small. To obtain indefinite media, three-dimensional (3D) optical metallic nanowire media with different structures are designed. They are numerically demonstrated that they are homogeneous effective indefinite anisotropic media by showing that their dispersion relations are hyperbolic. Negative group refraction and pseudo focusing are observed. Another approach is to incorporate gain into metamaterial nanostructures. The nonlinearity of gain is included by a generic four-level atomic model. A computational scheme is presented, which allows for a self-consistent treatment of a dispersive metallic photonic metamaterial coupled to a gain material incorporated into the nanostructure using the finite-difference time-domain (FDTD) method. The loss compensations with gain are done for various structures, from 2D simplified models to 3D realistic structures. Results show the losses of optical metamaterials can be effectively compensated by gain. The effective gain coefficient of the combined system can be much larger than the bulk gain counterpart, due to the strong local-field enhancement.

  19. Remote Monitoring Transparency Program

    SciTech Connect (OSTI)

    Sukhoruchkin, V.K.; Shmelev, V.M.; Roumiantsev, A.N.; Croessmann, C.D.; Horton, R.D.; Matter, J.C.; Czajkowski, A.F.; Sheely, K.B.; Bieniawski, A.J.

    1996-12-31

    The objective of the Remote Monitoring Transparency Program is to evaluate and demonstrate the use of remote monitoring technologies to advance nonproliferation and transparency efforts that are currently being developed by Russia and the US without compromising the national security of the participating parties. Under a lab-to-lab transparency contract between Sandia National Laboratories (SNL) and the Kurchatov Institute (KI RRC), the Kurchatov Institute will analyze technical and procedural aspects of the application of remote monitoring as a transparency measure to monitor inventories of direct-use HEU and plutonium (e.g., material recovered from dismantled nuclear weapons). A goal of this program is to assist a broad range of political and technical experts in learning more about remote monitoring technologies that could be used to implement nonproliferation, arms control, and other security and confidence building measures. Specifically, this program will: (1) begin integrating Russian technologies into remote monitoring systems; (2) develop remote monitoring procedures that will assist in the application of remote monitoring techniques to monitor inventories of HEU and Pu from dismantled nuclear weapons; and (3) conduct a workshop to review remote monitoring fundamentals, demonstrate an integrated US/Russian remote monitoring will have on the national security of participating countries.

  20. Absorption and emission properties of photonic crystals and metamateri...

    Office of Scientific and Technical Information (OSTI)

    ThesisDissertation: Absorption and emission properties of photonic crystals and metamaterials Citation Details In-Document Search Title: Absorption and emission properties of ...

  1. Voltage Tunable Strong Coupling with Planar Metamaterials: From...

    Office of Scientific and Technical Information (OSTI)

    From Fundamentals to Optoelectronic Devices. Citation Details In-Document Search Title: Voltage Tunable Strong Coupling with Planar Metamaterials: From Fundamentals to ...

  2. Coupling Schemes in Terahertz Planar Metamaterials (Journal Article...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Coupling Schemes in Terahertz Planar Metamaterials Citation Details ... GrantContract Number: AC52-06NA25396 Type: Published Article Journal Name: International ...

  3. Resonant dielectric metamaterials (Patent) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    The resonant dielectric metamaterials are low-loss 3D isotropic materials with negative permittivity and permeability. Such isotropic double negative materials offer polarization ...

  4. Thermal conductor for high-energy electrochemical cells

    DOE Patents [OSTI]

    Hoffman, Joseph A.; Domroese, Michael K.; Lindeman, David D.; Radewald, Vern E.; Rouillard, Roger; Trice, Jennifer L.

    2000-01-01

    A thermal conductor for use with an electrochemical energy storage device is disclosed. The thermal conductor is attached to one or both of the anode and cathode contacts of an electrochemical cell. A resilient portion of the conductor varies in height or position to maintain contact between the conductor and an adjacent wall structure of a containment vessel in response to relative movement between the conductor and the wall structure. The thermal conductor conducts current into and out of the electrochemical cell and conducts thermal energy between the electrochemical cell and thermally conductive and electrically resistive material disposed between the conductor and the wall structure. The thermal conductor may be fabricated to include a resilient portion having one of a substantially C-shaped, double C-shaped, Z-shaped, V-shaped, O-shaped, S-shaped, or finger-shaped cross-section. An elastomeric spring element may be configured so as to be captured by the resilient conductor for purposes of enhancing the functionality of the thermal conductor. The spring element may include a protrusion that provides electrical insulation between the spring conductor and a spring conductor of an adjacently disposed electrochemical cell in the presence of relative movement between the cells and the wall structure. The thermal conductor may also be fabricated from a sheet of electrically conductive material and affixed to the contacts of a number of electrochemical cells.

  5. Quench propagation velocity for highly stabilized conductors

    SciTech Connect (OSTI)

    Mints, R.G. |; Ogitsu, T. |; Devred, A.

    1995-05-01

    Quench propagation velocity in conductors having a large amount of stabilizer outside the multifilamentary area is considered. It is shown that the current redistribution process between the multifilamentary area and the stabilizer can strongly effect the quench propagation. A criterion is derived determining the conditions under which the current redistribution process becomes significant, and a model of effective stabilizer area is suggested to describe its influence on the quench propagation velocity. As an illustration, the model is applied to calculate the adiabatic quench propagation velocity for a conductor geometry with a multifilamentary area embedded inside the stabilizer.

  6. Electrode with transparent series resistance for uniform switching of optical modulation devices

    DOE Patents [OSTI]

    Tench, D. Morgan; Cunningham, Michael A.; Kobrin, Paul H.

    2008-01-08

    Switching uniformity of an optical modulation device for controlling the propagation of electromagnetic radiation is improved by use of an electrode comprising an electrically resistive layer that is transparent to the radiation. The resistive layer is preferably an innerlayer of a wide-bandgap oxide sandwiched between layers of indium tin oxide or another transparent conductor, and may be of uniform thickness, or may be graded so as to provide further improvement in the switching uniformity. The electrode may be used with electrochromic and reversible electrochemical mirror (REM) smart window devices, as well as display devices based on various technologies.

  7. Stators with improved conductor assembly and method of making same

    DOE Patents [OSTI]

    Dang, Dang Dinh; Blissenbach, Rolf; Schauer, David; Wattleworth, John; Milani, Michael; Hatch, Erik

    2013-07-30

    A stator includes a stator core, a plurality of slots, and a conductor. The plurality of slots are formed within the stator core. The conductor is disposed continuously within at least two of the plurality of openings.

  8. Antiperovskite Li 3 OCl superionic conductor films for solid...

    Office of Scientific and Technical Information (OSTI)

    Antiperovskite Li 3 OCl superionic conductor films for solid-state Li-ion batteries Citation Details In-Document Search Title: Antiperovskite Li 3 OCl superionic conductor films ...

  9. Wireless energy transfer between anisotropic metamaterials shells

    SciTech Connect (OSTI)

    Daz-Rubio, Ana; Carbonell, Jorge; Snchez-Dehesa, Jos

    2014-06-15

    The behavior of strongly coupled Radial Photonic Crystals shells is investigated as a potential alternative to transfer electromagnetic energy wirelessly. These sub-wavelength resonant microstructures, which are based on anisotropic metamaterials, can produce efficient coupling phenomena due to their high quality factor. A configuration of selected constitutive parameters (permittivity and permeability) is analyzed in terms of its resonant characteristics. The coupling to loss ratio between two coupled resonators is calculated as a function of distance, the maximum (in excess of 300) is obtained when the shells are separated by three times their radius. Under practical conditions an 83% of maximum power transfer has been also estimated. -- Highlights: Anisotropic metamaterial shells exhibit high quality factors and sub-wavelength size. Exchange of electromagnetic energy between shells with high efficiency is analyzed. Strong coupling is supported with high wireless transfer efficiency. End-to-end energy transfer efficiencies higher than 83% can be predicted.

  10. Resistive coating for current conductors in cryogenic applications

    DOE Patents [OSTI]

    Hirayama, Chikara; Wagner, George R.

    1982-05-18

    This invention relates to a resistive or semiconducting coating for use on current conductors in cryogenic applications. This includes copper-clad superconductor wire, copper wire used for stabilizing superconductor magnets, and for hyperconductors. The coating is a film of cuprous sulfide (Cu.sub.2 S) that has been found not to degrade the properties of the conductors. It is very adherent to the respective conductors and satisfies the mechanical, thermal and electrical requirements of coatings for the conductors.

  11. CANCELLED - COLLOQUIUM: Metamaterials | Princeton Plasma Physics Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    May 6, 2015, 4:15pm to 5:30pm Colloquia MBG Auditorium CANCELLED - COLLOQUIUM: Metamaterials Professor Gennady Shvets University of Texas - Austin HELLO - THIS COLLOQUIUM HAS BEEN CANCELLED - AND MAY BE RESCHEDULED. Colloquium Committee: The Princeton Plasma Physics Laboratory 2016-2017 Colloquium Committee is comprised of the following people. Please feel free to contact them by e-mail regarding any possible speakers or topics for future colloquia. Carol Ann Austin, caustin@pppl.gov Soha Aslam,

  12. Multi-megampere current interruption from explosive deformation of conductors

    SciTech Connect (OSTI)

    Goforth, J.H.; Williams, A.H.; Marsh, S.P.

    1985-01-01

    Two approaches for using explosives to interrupt current flowing in solid conductors are described. One concept uses explosives to extrude the switch conductor into thin regions that fuse due to current in the switch. A preliminary scaling law is presented. The second approach employs dielectric jets to sever current carrying conductors. A feasibility experiment and an improved design are described.

  13. Full tape thickness feature conductors for EMI structures

    DOE Patents [OSTI]

    Peterson, Kenneth A.; Knudson, Richard T.; Smith, Frank R.; Barner, Gregory

    2014-06-10

    Generally annular full tape thickness conductors are formed in single or multiple tape layers, and then stacked to produce an annular solid conductive wall for enclosing an electromagnetic isolation cavity. The conductors may be formed using punch and fill operations, or by flowing conductor-containing material onto the tape edge surfaces that define the interior sidewalls of the cavity.

  14. Correlation effects in nuclear transparency

    SciTech Connect (OSTI)

    Frankfurt, L. L.; Moniz, Ernest J.; Sargsyan, M. M.; Strikman, M. I.

    1995-06-01

    The Glauber approximation is used to calculate the contribution of nucleon correlations in high-energy A(e,e'N) reactions. When the excitation energy of the residual nucleus is small, the increase of the nuclear transparency due to correlations between the struck nucleon and the other nucleons is mostly compensated by a decrease of the transparency due to the correlations between nondetected nucleons. We derive Glauber model predictions for nuclear transparency for the differential cross section when nuclear shell level excitations are measured. The role of correlations in color transparency is briefly discussed.

  15. Ionic conductors for solid oxide fuel cells

    DOE Patents [OSTI]

    Krumpelt, Michael; Bloom, Ira D.; Pullockaran, Jose D.; Myles, Kevin M.

    1993-01-01

    An electrolyte that operates at temperatures ranging from 600.degree. C. to 800.degree. C. is provided. The electrolyte conducts charge ionically as well as electronically. The ionic conductors include molecular framework structures having planes or channels large enough to transport oxides or hydrated protons and having net-positive or net-negative charges. Representative molecular framework structures include substituted aluminum phosphates, orthosilicates, silicoaluminates, cordierites, apatites, sodalites, and hollandites.

  16. Polymeric matrix materials for infrared metamaterials

    DOE Patents [OSTI]

    Dirk, Shawn M; Rasberry, Roger D; Rahimian, Kamyar

    2014-04-22

    A polymeric matrix material exhibits low loss at optical frequencies and facilitates the fabrication of all-dielectric metamaterials. The low-loss polymeric matrix material can be synthesized by providing an unsaturated polymer, comprising double or triple bonds; partially hydrogenating the unsaturated polymer; depositing a film of the partially hydrogenated polymer and a crosslinker on a substrate; and photopatterning the film by exposing the film to ultraviolet light through a patterning mask, thereby cross-linking at least some of the remaining unsaturated groups of the partially hydrogenated polymer in the exposed portions.

  17. Single-resonator double-negative metamaterial

    DOE Patents [OSTI]

    Warne, Larry K.; Basilio, Lorena I.; Langston, William L.; Johnson, William A.; Ihlefeld, Jon; Ginn, III, James C.; Clem, Paul G.; Sinclair, Michael B.

    2016-06-21

    Resonances can be tuned in dielectric resonators in order to construct single-resonator, negative-index metamaterials. For example, high-contrast inclusions in the form of metallic dipoles can be used to shift the first electric resonance down (in frequency) to the first magnetic resonance, or alternatively, air splits can be used to shift the first magnetic resonance up (in frequency) near the first electric resonance. Degenerate dielectric designs become especially useful in infrared- or visible-frequency applications where the resonator sizes associated with the lack of high-permittivity materials can become of sufficient size to enable propagation of higher-order lattice modes in the resulting medium.

  18. Coupling Schemes in Terahertz Planar Metamaterials

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Roy Chowdhury, Dibakar; Singh, Ranjan; Taylor, Antoinette J.; Chen, Hou-Tong; Zhang, Weili; Azad, Abul K.

    2012-01-01

    We present a review of the different coupling schemes in a planar array of terahertz metamaterials. The gap-to-gap near-field capacitive coupling between split-ring resonators in a unit cell leads to either blue shift or red shift of the fundamental inductive-capacitive ( LC ) resonance, depending on the position of the split gap. The inductive coupling is enhanced by decreasing the inter resonator distance resulting in strong blue shifts of the LC resonance. We observe the LC resonance tuning only when the split-ring resonators are in close proximity of each other; otherwise, they appear to be uncoupled. Conversely, the higher-ordermore » resonances are sensitive to the smallest change in the inter particle distance or split-ring resonator orientation and undergo tremendous resonance line reshaping giving rise to a sharp subradiant resonance mode which produces hot spots useful for sensing applications. Most of the coupling schemes in a metamaterial are based on a near-field effect, though there also exists a mechanism to couple the resonators through the excitation of lowest-order lattice mode which facilitates the long-range radiative or diffractive coupling in the split-ring resonator plane leading to resonance line narrowing of the fundamental as well as the higher order resonance modes.« less

  19. Mechanism of the metallic metamaterials coupled to the gain material

    SciTech Connect (OSTI)

    Huang, Zhixiang; Droulias, Sotiris; Koschny, Thomas; Soukoulis, Costas M.

    2014-10-11

    We present evidence of strong coupling between the gain material and the metallic metamaterials. It is of vital importance to understand the mechanism of the coupling of metamaterials with the gain medium. Using a four-level gain system, the numerical pump-probe experiments are performed in several configurations (splitring resonators (SRRs), inverse SRRs and fishnets) of metamaterials, demonstrating reduction of the resonator damping in all cases and hence the possibility for loss compensation. We find that the differential transmittance ?T/T can be negative in different SRR configurations, such as SRRs on the top of the gain substrate, gain in the SRR gap and gain covering the SRR structure, while in the fishnet metamaterial with gain ?T/T is positive.

  20. Mechanism of the metallic metamaterials coupled to the gain material

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Huang, Zhixiang; Droulias, Sotiris; Koschny, Thomas; Soukoulis, Costas M.

    2014-10-11

    We present evidence of strong coupling between the gain material and the metallic metamaterials. It is of vital importance to understand the mechanism of the coupling of metamaterials with the gain medium. Using a four-level gain system, the numerical pump-probe experiments are performed in several configurations (splitring resonators (SRRs), inverse SRRs and fishnets) of metamaterials, demonstrating reduction of the resonator damping in all cases and hence the possibility for loss compensation. We find that the differential transmittance ?T/T can be negative in different SRR configurations, such as SRRs on the top of the gain substrate, gain in the SRR gapmoreand gain covering the SRR structure, while in the fishnet metamaterial with gain ?T/T is positive.less

  1. Large-Scale All-Dielectric Metamaterial Perfect Reflectors

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Moitra, Parikshit; Slovick, Brian A.; li, Wei; Kravchencko, Ivan I.; Briggs, Dayrl P.; Krishnamurthy, S.; Valentine, Jason

    2015-05-08

    All-dielectric metamaterials offer a potential low-loss alternative to plasmonic metamaterials at optical frequencies. In this paper, we take advantage of the low absorption loss as well as the simple unit cell geometry to demonstrate large-scale (centimeter-sized) all-dielectric metamaterial perfect reflectors made from silicon cylinder resonators. These perfect reflectors, operating in the telecommunications band, were fabricated using self-assembly based nanosphere lithography. In spite of the disorder originating from the self-assembly process, the average reflectance of the metamaterial perfect reflectors is 99.7% at 1530 nm, surpassing the reflectance of metallic mirrors. Moreover, the spectral separation of the electric and magnetic resonances canmore » be chosen to achieve the required reflection bandwidth while maintaining a high tolerance to disorder. Finally, the scalability of this design could lead to new avenues of manipulating light for low-loss and large-area photonic applications.« less

  2. Sound reduction by metamaterial-based acoustic enclosure

    SciTech Connect (OSTI)

    Yao, Shanshan; Li, Pei; Zhou, Xiaoming; Hu, Gengkai

    2014-12-15

    In many practical systems, acoustic radiation control on noise sources contained within a finite volume by an acoustic enclosure is of great importance, but difficult to be accomplished at low frequencies due to the enhanced acoustic-structure interaction. In this work, we propose to use acoustic metamaterials as the enclosure to efficiently reduce sound radiation at their negative-mass frequencies. Based on a circularly-shaped metamaterial model, sound radiation properties by either central or eccentric sources are analyzed by numerical simulations for structured metamaterials. The parametric analyses demonstrate that the barrier thickness, the cavity size, the source type, and the eccentricity of the source have a profound effect on the sound reduction. It is found that increasing the thickness of the metamaterial barrier is an efficient approach to achieve large sound reduction over the negative-mass frequencies. These results are helpful in designing highly efficient acoustic enclosures for blockage of sound in low frequencies.

  3. Formation of rarefaction waves in origami-based metamaterials

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yasuda, H.; Chong, C.; Charalampidis, E. G.; Kevrekidis, P. G.; Yang, J.

    2016-04-15

    Here, we investigate the nonlinear wave dynamics of origami-based metamaterials composed of Tachi-Miura polyhedron (TMP) unit cells. These cells exhibit strain softening behavior under compression, which can be tuned by modifying their geometrical configurations or initial folded conditions. We assemble these TMP cells into a cluster of origami-based metamaterials, and we theoretically model and numerically analyze their wave transmission mechanism under external impact. Numerical simulations show that origami-based metamaterials can provide a prototypical platform for the formation of nonlinear coherent structures in the form of rarefaction waves, which feature a tensile wavefront upon the application of compression to the system.more » We also demonstrate the existence of numerically exact traveling rarefaction waves in an effective lumped-mass model. Origami-based metamaterials can be highly useful for mitigating shock waves, potentially enabling a wide variety of engineering applications.« less

  4. Single ion conductor cross-linked polymeric networks

    DOE Patents [OSTI]

    Kerr, John Borland; Wang, Shanger; Han, Yong Bong; Liu, Gao; Hou, Jun; Sloop, Steven Edward

    2005-10-18

    Single ion conductors comprising polymer electrolytes prepared by grafting a salt compound onto a comb-branch polymer or dendrimer are disclosed having superior properties.

  5. Single ion conductor cross-linked polymeric networks

    DOE Patents [OSTI]

    Kerr, John Borland; Wang, Shanger; Hou, Jun; Sloop, Steven Edward; Han, Yong Bong; Liu, Gao

    2011-03-08

    Single ion conductors comprising polymer electrolytes prepared by grafting a salt compound onto a comb-branch polymer or dendrimer are disclosed having superior properties.

  6. Flow Batteries Enabled by Nanoscale Percolating Conductor Networks...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5, 2014, Research Highlights Flow Batteries Enabled by Nanoscale Percolating Conductor Networks Images for Flow Batteries Scientific Achievement Created novel electronically ...

  7. Advanced Conductor Development with High Temperature Superconductors and Carbon Nanotubes

    SciTech Connect (OSTI)

    Holesinger, Terry George

    2015-11-17

    This is a report that describes advanced conductor research performed by LANL in preparation for the Colloquia at the University of New Mexico.

  8. Method for preparing a thick film conductor

    DOE Patents [OSTI]

    Nagesh, Voddarahalli K.; Fulrath, deceased, Richard M.

    1978-01-01

    A method for preparing a thick film conductor which comprises providing surface active glass particles, mixing the surface active glass particles with a thermally decomposable organometallic compound, for example, a silver resinate, and then decomposing the organometallic compound by heating, thereby chemically depositing metal on the glass particles. The glass particle mixture is applied to a suitable substrate either before or after the organometallic compound is thermally decomposed. The resulting system is then fired in an oxidizing atmosphere, providing a microstructure of glass particles substantially uniformly coated with metal.

  9. Building Energy Transparency Report | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transparency Report Building Energy Transparency Report This report discusses best practices in implementing benchmarking policies. It includes policy profiles from several cities ...

  10. Precise Application of Transparent Conductive Oxide Coatings...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Precise Application of Transparent Conductive Oxide Coatings for Flat Panel Displays and Photovoltaic Cells Technology available for licensing: New transparent conducting oxide ...

  11. Measuring the Impact of Benchmarking & Transparency - Methodologies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Measuring the Impact of Benchmarking & Transparency - Methodologies and the NYC Example Measuring the Impact of Benchmarking & Transparency - Methodologies and the NYC Example ...

  12. DOE Science Showcase - Metamaterials | OSTI, US Dept of Energy Office of

    Office of Scientific and Technical Information (OSTI)

    Scientific and Technical Information DOE Science Showcase - Metamaterials Metamaterials are a new class of artificially-structured materials that provides the ability to manipulate the flow of electromagnetic energy in ways that are not achievable with natural materials. These materials represent a new frontier in materials science. For more information about new devices being developed with these metamaterials, see In the OSTI Collections: Metamaterials, by Dr. William Watson, Physicist,

  13. Testing of the 3M Company ACCR Conductor

    SciTech Connect (OSTI)

    Stovall, J.P.; RIzy, D.T.; Kisner, R.A.; Deve, H.E.

    2010-09-15

    The 3M Company has developed a high-temperature low-sag conductor referred to as Aluminum- Conductor Composite-Reinforced or ACCR. The conductor uses an aluminum metal matrix material to replace the steel in conventional conductors so the core has a lower density and higher conductivity. The objective of this work is to accelerate the commercial acceptance by electric utilities of these new conductor designs by testing four representative conductor classes in controlled conditions. Overhead transmission lines use bare aluminum conductor strands wrapped around a steel core strands to transmit electricity. The typical cable is referred to as aluminum-conductor steel-reinforced (ACSR). The outer strands are aluminum, chosen for its conductivity, low weight, and low cost. The center strand is of steel for the strength required to support the weight without stretching the aluminum due to its ductility. The power density of a transmission corridor has been directly increased by increasing the voltage level. Transmission voltages have increased from 115-kV to 765- kV over the past 80 years. In the United States, further increasing the voltage level is not feasible at this point in time, so in order to further increase the power density of a transmission corridor, conductor designs that increase the current carrying capability have been examined. One of the key limiting factors in the design of a transmission line is the conductor sag which determines the clearance of the conductor above ground or underlying structures needed for electrical safety. Increasing the current carrying capability of a conductor increases the joule heating in the conductor which increases the conductor sag. A conductor designed for high-temperature and lowsag operation requires an engineered modification of the conductor materials. To make an advanced cable, the 3M Company solution has been the development of a composite conductor consisting of Nextel ceramic fibers to replace the steel core and

  14. Tunable hyperbolic metamaterials utilizing phase change heterostructures

    SciTech Connect (OSTI)

    Krishnamoorthy, Harish N. S.; Menon, Vinod M.; Zhou, You; Ramanathan, Shriram; Narimanov, Evgenii

    2014-03-24

    We present a metal-free tunable anisotropic metamaterial where the iso-frequency surface is tuned from elliptical to hyperbolic dispersion by exploiting the metal-insulator phase transition in the correlated material vanadium dioxide (VO{sub 2}). Using VO{sub 2}-TiO{sub 2} heterostructures, we demonstrate the transition in the effective dielectric constant parallel to the layers to undergo a sign change from positive to negative as the VO{sub 2} undergoes the phase transition. The possibility to tune the iso-frequency surface in real time using external perturbations such as temperature, voltage, or optical pulses creates new avenues for controlling light-matter interaction.

  15. YBCO COATED CONDUCTORS (Book) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    The U.S. Department of Energy s target price for the conductor is close to the current copper wire cost of 10-50kA-meter, i.e. a meter of copper type conductor carrying 1000 A ...

  16. Fluoroalkyl-phosphonic-acid-based proton conductors | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fluoroalkyl-phosphonic-acid-based proton conductors Fluoroalkyl-phosphonic-acid-based proton conductors A presentation to the High Temperature Membranes Working Group meeting, May 19, 2006. desmarteau.pdf (203.69 KB) More Documents & Publications HTMWG, May 18, 2009, Welcome! High Temperature Membrane Working Group Membrane Development for Medium and High Temperature PEMFC in Europe (Presentation)

  17. Non-binding conductor load bearing roller for a gas-insulated transmission line having a corrugated outer conductor

    DOE Patents [OSTI]

    Fischer, William H.

    1984-01-01

    A gas-insulated transmission line includes a corrugated outer conductor, an inner conductor disposed within and insulated from the outer conductor by means of support insulators and an insulating gas, and a non-binding transport device for supporting and permitting movement of the inner conductor/insulating support assembly axially along the corrugated outer conductor without radial displacement and for moving without binding along corrugations of any slope less than vertical. The transport device includes two movable contacts, such as skids or rollers, supported on a common pivot lever, the pivot lever being rotatably disposed about a pivot lever axis, which pivot lever axis is in turn disposed on the periphery of a support insulator or particle trap if one is used. The movable contacts are separated axially a distance equal to the axial distance between the peaks and valleys of the corrugations of the outer conductor and separated radially a distance equal to the radial distance between the peaks and valleys of the corrugations of the outer conductor. The transport device has the pivot lever axis disposed parallel to the motion of travel of the inner conductor/insulating support assembly.

  18. Nanocarbon-copper thin film as transparent electrode

    SciTech Connect (OSTI)

    Isaacs, R. A.; Zhu, H.; Preston, Colin; LeMieux, M.; Jaim, H. M. Iftekhar; Hu, L. Salamanca-Riba, L. G.; Mansour, A.; Zavalij, P. Y.; Rabin, O.

    2015-05-11

    Researchers seeking to enhance the properties of metals have long pursued incorporating carbon in the metallic host lattice in order to combine the strongly bonded electrons in the metal lattice that yield high ampacity and the free electrons available in carbon nanostructures that give rise to high conductivity. The incorporation of carbon nanostructures into the copper lattice has the potential to improve the current density of copper to meet the ever-increasing demands of nanoelectronic devices. We report on the structure and properties of carbon incorporated in concentrations up to 5 wt. % (∼22 at. %) into the crystal structure of copper. Carbon nanoparticles of 5 nm–200 nm in diameter in an interconnecting carbon matrix are formed within the bulk Cu samples. The carbon does not phase separate after subsequent melting and re-solidification despite the absence of a predicted solid solution at such concentrations in the C-Cu binary phase diagram. This material, so-called, Cu covetic, makes deposition of Cu films containing carbon with similar microstructure to the metal possible. Copper covetic films exhibit greater transparency, higher conductivity, and resistance to oxidation than pure copper films of the same thickness, making them a suitable choice for transparent conductors.

  19. Plasma bullets behavior in a tube covered by a conductor

    SciTech Connect (OSTI)

    Xian, Y. B.; Xu, H. T.; Lu, X. P. Pei, X. K.; Gong, W. W.; Lu, Y.; Liu, D. W.; Yang, Y.

    2015-06-15

    In this work, for better applications of atmospheric pressure plasma jets, the physics of plasma streamers in a glass tube with a part of it covered by a conductor is investigated. To better understand the propagation mechanism of plasma bullets in capillary tubes passing through a curved or narrow passage for some biomedical or material applications, the propagation of plasma streamers in a tube covered by a floating conductor is investigated. For a plasma streamer propagating in a tube covered by a conductor, the plasma streamer is suppressed and becomes shorter, and a secondary streamer is generated in the tube at the downstream end of the conductor. The larger the area covered by the conductor, or the thinner the tube, the stronger the plasma streamer is inhibited. The electric potential of the conductor is measured to be as high as 6 kV. On the other hand, a higher voltage applied on the HV electrode, or a higher gas flow rate will make the secondary plasma streamer longer. It is found that the capacitor formed by the conductor outside the tube and the wall of the tube plays an important role in inhibiting the original plasma streamer and generating the secondary streamer. Moreover, the active species generated by the original plasma play important role in generating a secondary plasma streamer.

  20. Review Article: The weak interactive characteristic of resonance cells and broadband effect of metamaterials

    SciTech Connect (OSTI)

    Zhao, Xiaopeng Song, Kun

    2014-10-15

    Metamaterials are artificial media designed to control electromagnetic wave propagation. Due to resonance, most present-day metamaterials inevitably suffer from narrow bandwidth, extremely limiting their practical applications. On the basis of tailored properties, a metamaterial within which each distinct unit cell resonates at its inherent frequency and has almost no coupling effect with the other ones, termed as weak interaction system, can be formulated. The total response of a weak interaction system can be treated as an overlap of the single resonance spectrum of each type of different unit cells. This intriguing feature therefore makes it possible to accomplish multiband or broadband metamaterials in a simple way. By introducing defects into metamaterials to form a weak interaction system, multiband and broadband electromagnetic metamaterials have first been experimentally demonstrated by our group. The similar concept can also be readily extended to acoustic and seismic metamaterials.

  1. Thermally induced nonlinear optical absorption in metamaterial perfect absorbers

    SciTech Connect (OSTI)

    Guddala, Sriram Kumar, Raghwendra; Ramakrishna, S. Anantha

    2015-03-16

    A metamaterial perfect absorber consisting of a tri-layer (Al/ZnS/Al) metal-dielectric-metal system with top aluminium nano-disks was fabricated by laser-interference lithography and lift-off processing. The metamaterial absorber had peak resonant absorbance at 1090 nm and showed nonlinear absorption for 600ps laser pulses at 1064 nm wavelength. A nonlinear saturation of reflectance was measured to be dependent on the average laser power incident and not the peak laser intensity. The nonlinear behaviour is shown to arise from the heating due to the absorbed radiation and photo-thermal changes in the dielectric properties of aluminium. The metamaterial absorber is seen to be damage resistant at large laser intensities of 25 MW/cm{sup 2}.

  2. Integrated digital metamaterials enables ultra-compact optical diodes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shen, Bing; Polson, Randy; Menon, Rajesh

    2015-01-01

    We applied nonlinear optimization to design integrated digital metamaterials in silicon for unidirectional energy flow. Two devices, one for each polarization state, were designed, fabricated, and characterized. Both devices offer comparable or higher transmission efficiencies and extinction ratios, are easier to fabricate, exhibit larger bandwidths and are more tolerant to fabrication errors, when compared to alternatives. Furthermore, each device footprint is only 3?m 3?m, which is the smallest optical diode ever reported. To illustrate the versatility of digital metamaterials, we also designed a polarization-independent optical diode.

  3. Optical properties of two-dimensional metamaterial photonic crystals

    SciTech Connect (OSTI)

    Meja-Salazar, J. R.

    2013-12-14

    In the present work, we theoretically study a 2D photonic crystal (PC) comprised by double negative (DNG) metamaterial cylinders, showing that such a system presents a superior light-matter interaction when compared with their single negative (SNG) plasmonic PC counterparts, suggesting a route to enhance the performance of sensors and photovoltaic cells. On the other hand, we have observed that depending on the frequency, the mode symmetry resembles either the case of SNG electric (SNG-E) or SNG magnetic (SNG-M) PC, suggesting that either the electric or magnetic character of the DNG metamaterial dominates in each case.

  4. High voltage switches having one or more floating conductor layers

    DOE Patents [OSTI]

    Werne, Roger W.; Sampayan, Stephen; Harris, John Richardson

    2015-11-24

    This patent document discloses high voltage switches that include one or more electrically floating conductor layers that are isolated from one another in the dielectric medium between the top and bottom switch electrodes. The presence of the one or more electrically floating conductor layers between the top and bottom switch electrodes allow the dielectric medium between the top and bottom switch electrodes to exhibit a higher breakdown voltage than the breakdown voltage when the one or more electrically floating conductor layers are not present between the top and bottom switch electrodes. This increased breakdown voltage in the presence of one or more electrically floating conductor layers in a dielectric medium enables the switch to supply a higher voltage for various high voltage circuits and electric systems.

  5. Solid-state Inorganic Lithium-Ion Conductors - Energy Innovation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find More Like This Return to Search Solid-state Inorganic Lithium-Ion Conductors ... milling system for preparation of electrodes for use in a solid state lithium-ion battery. ...

  6. SYNTHESIS AND CHARACTERIZATION OF PROTON CONDUCTORS

    SciTech Connect (OSTI)

    Brinkman, K.

    2010-02-18

    The morphological and electrical properties of yttrium (Y) and indium (In) doped barium cerate perovskites of the form BaIn{sub 0.3-x}Y{sub x}Ce{sub 0.7}O{sub 3-{delta}} (with x=0-0.3) prepared by a modified Pechini method were investigated as potential high temperature proton conductors with improved chemical stability. The sinterability increased with the increase of In-doping, and the perovskite phase was found in the BaIn{sub 0.3-x}Y{sub x}Ce{sub 0.7}O{sub 3-{delta}} solid solutions over the range 0 {le} x {le} 0.3. The conductivities decreased (from x to x, insert quantitative values) while the tolerance to wet CO{sub 2} improved for BaIn{sub 0.3-x}Y{sub x}Ce{sub 0.7}O{sub 3-{delta}} samples with an increase of In-doping.

  7. Preferential emission into epsilon-near-zero metamaterial [Invited

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Galfsky, Tal; Sun, Zheng; Jacob, Zubin; Menon, Vinod M.

    2015-11-23

    We report the use of epsilon near zero (ENZ) metamaterial to control spontaneous emission from Zinc-Oxide (ZnO) excitons. The ENZ material consists of alternating layers of silver and alumina with subwavelength thicknesses, resulting in an effective medium where one of the components of the dielectric constant approach zero between 370nm-440nm wavelength range. Bulk ZnO with photoluminescence maximum in the ENZ regime was deposited via atomic layer deposition to obtain a smooth film with near field coupling to the ENZ metamaterial. Preferential emission from the ZnO layer into the metamaterial with suppression of forward emission by 90% in comparison to ZnOmore » on silicon is observed. We attribute this observation to the presence of dispersionless plasmonic modes in the ENZ regime as shown by the results of theoretical modeling presented here. Integration of ENZ metamaterials with light emitters is an attractive platform for realizing a low threshold subwavelength laser.« less

  8. Unidirectional transmission using array of zero-refractive-index metamaterials

    SciTech Connect (OSTI)

    Fu, Yangyang; Xu, Lin; Hong Hang, Zhi; Chen, Huanyang

    2014-05-12

    In this Letter, we find that high efficient unidirectional transmission occurs for an array of prisms made of zero-refractive-index metamaterials. As a specific demonstration, we further design the device using Dirac-cone-like photonic crystals. The device can function for a broadband of spectrum. Numerical simulations are performed to verify the one-way wave functionality.

  9. Transparent electrode for optical switch

    DOE Patents [OSTI]

    Goldhar, J.; Henesian, M.A.

    1984-10-19

    The invention relates generally to optical switches and techniques for applying a voltage to an electro-optical crystal, and more particularly, to transparent electodes for an optical switch. System architectures for very large inertial confinement fusion (ICF) lasers require active optical elements with apertures on the order of one meter. Large aperture optical switches are needed for isolation of stages, switch-out from regenerative amplifier cavities and protection from target retroreflections.

  10. Active and Tunable Metamaterials based on Strong and Ultra-strong...

    Office of Scientific and Technical Information (OSTI)

    2013 held September 16-21, 2013 in Bordeaux, France.; Related Information: Proposed for presentation at the Metamaterials 2013 held September 16-21, 2013 in Bordeaux, France

  11. Realization of an all-dielectric zero-index optical metamaterial

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... of metamaterials: a rigorous homogenization theory via Whitney interpolation. J. Opt. Soc. ... Correspondence and requests for materials should be addressed to J.V. Competing financial ...

  12. Use of ion conductors in the pyrochemical reduction of oxides

    DOE Patents [OSTI]

    Miller, William E.; Tomczuk, Zygmunt

    1994-01-01

    An electrochemical process and electrochemical cell for reducing a metal oxide are provided. First the oxide is separated as oxygen gas using, for example, a ZrO.sub.2 oxygen ion conductor anode and the metal ions from the reduction salt are reduced and deposited on an ion conductor cathode, for example, sodium ion reduced on a .beta.-alumina sodium ion conductor cathode. The generation of and separation of oxygen gas avoids the problem with chemical back reaction of oxygen with active metals in the cell. The method also is characterized by a sequence of two steps where an inert cathode electrode is inserted into the electrochemical cell in the second step and the metallic component in the ion conductor is then used as the anode to cause electrochemical reduction of the metal ions formed in the first step from the metal oxide where oxygen gas formed at the anode. The use of ion conductors serves to isolate the active components from chemically reacting with certain chemicals in the cell. While applicable to a variety of metal oxides, the invention has special importance for reducing CaO to Ca.degree. used for reducing UO.sub.2 and PuO.sub.2 to U and Pu.

  13. Use of ion conductors in the pyrochemical reduction of oxides

    DOE Patents [OSTI]

    Miller, W.E.; Tomczuk, Z.

    1994-02-01

    An electrochemical process and electrochemical cell for reducing a metal oxide are provided. First the oxide is separated as oxygen gas using, for example, a ZrO[sub 2] oxygen ion conductor anode and the metal ions from the reduction salt are reduced and deposited on an ion conductor cathode, for example, sodium ion reduced on a [beta]-alumina sodium ion conductor cathode. The generation of and separation of oxygen gas avoids the problem with chemical back reaction of oxygen with active metals in the cell. The method also is characterized by a sequence of two steps where an inert cathode electrode is inserted into the electrochemical cell in the second step and the metallic component in the ion conductor is then used as the anode to cause electrochemical reduction of the metal ions formed in the first step from the metal oxide where oxygen gas formed at the anode. The use of ion conductors serves to isolate the active components from chemically reacting with certain chemicals in the cell. While applicable to a variety of metal oxides, the invention has special importance for reducing CaO to Ca[sup o] used for reducing UO[sub 2] and PuO[sub 2] to U and Pu. 2 figures.

  14. Opportunities for Improving Photovoltaic Performance with Better Transparent Contacts

    SciTech Connect (OSTI)

    Ginley, David S.; Perkins, John D.

    2015-06-14

    NREL and DOE recently held a workshop to assess the challenges, opportunities and potential impacts for improved transparent contacts (TCs) to positively impact current and emerging photovoltaic conversion technologies. Here, we report on the workshop outcomes based on the collective input and participation from industry, academia, national laboratories and DOE. A primary conclusion is that new emerging materials can have significant impacts on the overall performance, reliability and cost for commercial scale PV. One key observation is that TC's should no longer be thought of as a single-layer single-purpose material but as an integrated contact layer stack that includes a charge selective interface layer, a conducting layer and sometimes layers for reliability or light management. In addition, the long standing goal of developing of high performance atmospheric-pressure-processed TCs has finally been met by the rapidly improving Ag nanowire based composites with better than ITO performance from an all ink based process. Even the more conventional metal oxide materials are improving rapidly by introducing solution processed buffer layers, and even conductor layers. This rapid evolution has opened the way to high-throughput low-cost TC processing. Key desired metrics for TCs and approaches to achieving them are discussed.

  15. Conductor design for the VLHC transmission line magnet

    SciTech Connect (OSTI)

    Foster, G.W.; Kashikhin, V.; McAshan, M.; Mazur, P.O.; Piekarz, H.; Volk, J.T.; Walker, R.

    1999-03-01

    The transmission line magnet [1] is under development for the Very Large Hadron Collider (VLHC) at Fermilab with the expectation that it’s cost will be several times less (per Tesla-meter) than conventional superconducting magnets. It is a dual-aperture warm-iron superferric magnet built around an 80kA superconducting transmission line. The superconductor consists of 8 Rutherford (SSC Outer) cables in an Invar pipe jacket. The conductor design requirements and development program is described. A 100kA conductor test facility based on inductive coupling is described.

  16. Improvement of SOFC electrodes using mixed ionic-electronic conductors

    SciTech Connect (OSTI)

    Matsuzaki, Y.; Hishinuma, M.

    1996-12-31

    Since the electrode reaction of SOFC is limited to the proximity of a triple phase boundary (TPB), the local current density at the electrode and electrolyte interface is larger than mean current density, which causes large ohmic and electrode polarization. This paper describes an application of mixed ionic-electronic conductors to reduce such polarization by means of (1) enhancing ionic conductivity of the electrolyte surface layer by coating a high ionic conductors, and (2) reducing the local current density by increasing the electrochemically active sites.

  17. Dynamic frequency tuning of electric and magnetic metamaterial response

    DOE Patents [OSTI]

    O'Hara, John F; Averitt, Richard; Padilla, Willie; Chen, Hou-Tong

    2014-09-16

    A geometrically modifiable resonator is comprised of a resonator disposed on a substrate, and a means for geometrically modifying the resonator. The geometrically modifiable resonator can achieve active optical and/or electronic control of the frequency response in metamaterials and/or frequency selective surfaces, potentially with sub-picosecond response times. Additionally, the methods taught here can be applied to discrete geometrically modifiable circuit components such as inductors and capacitors. Principally, controlled conductivity regions, using either reversible photodoping or voltage induced depletion activation, are used to modify the geometries of circuit components, thus allowing frequency tuning of resonators without otherwise affecting the bulk substrate electrical properties. The concept is valid over any frequency range in which metamaterials are designed to operate.

  18. Transparent communications permit unmanned operations

    SciTech Connect (OSTI)

    1995-07-01

    Not-normally-manned platforms are not a new development. However, their use in harsher environments has until recently, been limited. Development of reliable communications networks capable of handling the large amounts of data required for process control in real time with distributed control systems (DCSs) has been a key factor in making the concept viable for harsher, more remote environments. The article below examines the transparent communications network and DCS installed on Pickerill field, offshore UK, by Fisher-Rosemount Systems and its operational parameters. Pickerill field, some 50 mi off the Lincolnshire coast, comprises two small unmanned platforms producing gas under remote control from Arco`s operations base at Great Yarmouth about 60 mi south. Reliable communication is required both with the two platforms offshore and with Conoco`s gas processing operators at Theddlethorpe. Fundamental to project success was the ability of the process control system to provide entirely secure and transparent communication with equipment offshore and thus enable operators at Great Yarmouth to interact with the process as if it were local to their control center.

  19. Sandia Develops Phased-Array Sources Based on Nonlinear Metamaterial

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nanocavities Develops Phased-Array Sources Based on Nonlinear Metamaterial Nanocavities - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery

  20. Acoustic wave propagation and stochastic effects in metamaterial absorbers

    SciTech Connect (OSTI)

    Christensen, J. Willatzen, M.

    2014-07-28

    We show how stochastic variations of the effective parameters of anisotropic structured metamaterials can lead to increased absorption of sound. For this, we derive an analytical model based on the Bourret approximation and illustrate the immediate connection between material disorder and attenuation of the averaged field. We demonstrate numerically that broadband absorption persists at oblique irradiation and that the influence of red noise comprising short spatial correlation lengths increases the absorption beyond what can be archived with a structured but ordered system.

  1. Scientists produce transparent, light-harvesting material

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transparent, light-harvesting material Scientists produce transparent, light-harvesting material The material could be used in development of transparent solar panels. November 3, 2010 Los Alamos National Laboratory sits on top of a once-remote mesa in northern New Mexico with the Jemez mountains as a backdrop to research and innovation covering multi-disciplines from bioscience, sustainable energy sources, to plasma physics and new materials. Los Alamos National Laboratory sits on top of a

  2. Scientists produce transparent, light-harvesting material

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The material could be used in development of transparent solar panels. November 3, 2010 Los ... "Potentially, with future refinement of this technology, windows in a home or office ...

  3. Optically transparent and environmentally durable superhydrophobic...

    Office of Scientific and Technical Information (OSTI)

    nanoparticles Citation Details In-Document Search Title: Optically transparent and environmentally durable superhydrophobic coating based on functionalized SiO2 nanoparticles ...

  4. Enhanced durability transparent superhydrophobic anti-soiling...

    Office of Scientific and Technical Information (OSTI)

    Title: Enhanced durability transparent superhydrophobic anti-soiling coatings for CSP applications Authors: Polyzos, Georgios 1 ; Schaeffer, Daniel A 1 ; Smith, Barton Barton ...

  5. Transparency: it's not just for windows

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transparency: it's not just for windows Los Alamos National Laboratory's database of environmental monitoring data is now directly viewable by the public. March 20, 2012...

  6. Atomically Bonded Transparent Superhydrophobic Coatings

    SciTech Connect (OSTI)

    Aytug, Tolga

    2015-08-01

    Maintaining clarity and avoiding the accumulation of water and dirt on optically transparent surfaces such as US military vehicle windshields, viewports, periscope optical head windows, and electronic equipment cover glasses are critical to providing a high level of visibility, improved survivability, and much-needed safety for warfighters in the field. Through a combination of physical vapor deposition techniques and the exploitation of metastable phase separation in low-alkali borosilicate, a novel technology was developed for the fabrication of optically transparent, porous nanostructured silica thin film coatings that are strongly bonded to glass platforms. The nanotextured films, initially structurally superhydrophilic, exhibit superior superhydrophobicity, hence antisoiling ability, following a simple but robust modification in surface chemistry. The surfaces yield water droplet contact angles as high as 172°. Moreover, the nanostructured nature of these coatings provides increased light scattering in the UV regime and reduced reflectivity (i.e., enhanced transmission) over a broad range of the visible spectrum. In addition to these functionalities, the coatings exhibit superior mechanical resistance to abrasion and are thermally stable to temperatures approaching 500°C. The overall process technology relies on industry standard equipment and inherently scalable manufacturing processes and demands only nontoxic, naturally abundant, and inexpensive base materials. Such coatings, applied to the optical components of current and future combat equipment and military vehicles will provide a significant strategic advantage for warfighters. The inherent self-cleaning properties of such superhydrophobic coatings will also mitigate biofouling of optical windows exposed to high-humidity conditions and can help decrease repair/replacement costs, reduce maintenance, and increase readiness by limiting equipment downtime.

  7. Multiwire conductor having greatly increased interwire resistance and method for making same

    DOE Patents [OSTI]

    Luhman, Thomas; Suenaga, Masaki

    1984-01-17

    An improved multiwire conductor of the type which is mechanically stabilized by a tin based solder filler. A solder filled conductor is heated to a temperature above its melting point for a period long enough to allow a substantial amount of copper to be dissolved from the wires comprising the conductor. The copper forms the brittle intermetallic compound Cu.sub.5 Sn.sub.6 with tin in the solder. After cooling the conductor is flexed causing a random cracking of the solder, and thereby increasing the interwire resistance of the conductor. The subject invention is particularly adapted for use with braided, ribbon-type solder filled superconductors.

  8. Multiwire conductor having increased interwire resistance and good mechanical stability and method for making same

    DOE Patents [OSTI]

    Luhman, Thomas; Klamut, Carl

    1984-02-14

    An improved multiwire conductor of the type which is mechanically stabilized by a solder filler. A solder filled conductor is heated to a temperature sufficient to make the solder brittle, but below the melting point of the solder. While still hot, the conductor is flexed, causing the solder to separate from the wires comprising the conductor, thereby increasing the interwire resistance. In one embodiment the conductor may be heated to a temperature above the eutectic temperature of the solder so that a controlled amount of solder is removed. The subject invention is particularly suited for use with braided, ribbon-type, solder filled superconductors.

  9. Multiwire conductor having increased interwire resistance and good mechanical stability and method for making same

    DOE Patents [OSTI]

    Luhman, T.; Klamut, C.

    1982-03-15

    An improved multiwire conductor of the type which is mechanically stabilized by a solder filler. A solder filled conductor is heated to a temperature sufficient to make the solder brittle, but below the melting point of the solder. While still hot, the conductor is flexed, causing the solder to separate from the wires comprising the conductor, thereby increasing the interwire resistance. In one embodiment the conductor may be heated to a temperature above the eutectic temperature of the solder so that a controlled amount of solder is removed. The subject invention is particularly suited for use with braided, ribbon-type, solder filled superconductors.

  10. Multiwire conductor having greatly increased interwire resistance and method for making same

    DOE Patents [OSTI]

    Luhman, T.; Suenaga, M.

    1982-03-15

    An improved multiwire conductor of the type which is mechanically stabilized by a tin based solder filler is described. A solder filled conductor is heated to a temperature above its melting point for a period long enough to allow a substantial amount of copper to be dissolved from the wires comprising the conductor. The copper forms the brittle intermetallic compound Cu/sub 5/Sn/sub 6/ with tin in the solder. After cooling the conductor is flexed causing a random cracking of the solder, and thereby increasing the interwire resistance of the conductor. The subject invention is particularly adapted for use with braided, ribbon-type solder filled superconductors.

  11. Wave propagation in photonic crystals and metamaterials: Surface waves, nonlinearity and chirality

    SciTech Connect (OSTI)

    Wang, Bingnan

    2009-12-03

    Photonic crystals and metamaterials, both composed of artificial structures, are two interesting areas in electromagnetism and optics. New phenomena in photonic crystals and metamaterials are being discovered, including some not found in natural materials. This thesis presents my research work in the two areas. Photonic crystals are periodically arranged artificial structures, mostly made from dielectric materials, with period on the same order of the wavelength of the working electromagnetic wave. The wave propagation in photonic crystals is determined by the Bragg scattering of the periodic structure. Photonic band-gaps can be present for a properly designed photonic crystal. Electromagnetic waves with frequency within the range of the band-gap are suppressed from propagating in the photonic crystal. With surface defects, a photonic crystal could support surface modes that are localized on the surface of the crystal, with mode frequencies within the band-gap. With line defects, a photonic crystal could allow the propagation of electromagnetic waves along the channels. The study of surface modes and waveguiding properties of a 2D photonic crystal will be presented in Chapter 1. Metamaterials are generally composed of artificial structures with sizes one order smaller than the wavelength and can be approximated as effective media. Effective macroscopic parameters such as electric permittivity {epsilon}, magnetic permeability {mu} are used to characterize the wave propagation in metamaterials. The fundamental structures of the metamaterials affect strongly their macroscopic properties. By designing the fundamental structures of the metamaterials, the effective parameters can be tuned and different electromagnetic properties can be achieved. One important aspect of metamaterial research is to get artificial magnetism. Metallic split-ring resonators (SRRs) and variants are widely used to build magnetic metamaterials with effective {mu} < 1 or even {mu} < 0. Varactor

  12. A Testing Platform for Validation of Overhead Conductor Aging Models and Understanding Thermal Limits

    SciTech Connect (OSTI)

    Irminger, Philip; Starke, Michael R; Dimitrovski, Aleksandar D; Young II, Marcus Aaron; Rizy, D Tom; Stovall, John P; Overholt, Philip N

    2014-01-01

    Power system equipment manufacturers and researchers continue to experiment with novel overhead electric conductor designs that support better conductor performance and address congestion issues. To address the technology gap in testing these novel designs, Oak Ridge National Laboratory constructed the Powerline Conductor Accelerated Testing (PCAT) facility to evaluate the performance of novel overhead conductors in an accelerated fashion in a field environment. Additionally, PCAT has the capability to test advanced sensors and measurement methods for accessing overhead conductor performance and condition. Equipped with extensive measurement and monitoring devices, PCAT provides a platform to improve/validate conductor computer models and assess the performance of novel conductors. The PCAT facility and its testing capabilities are described in this paper.

  13. Vacuum-surface flashover switch with cantilever conductors

    DOE Patents [OSTI]

    Caporaso, George J.; Sampayan, Stephen E.; Kirbie, Hugh C.

    2001-01-01

    A dielectric-wall linear accelerator is improved by a high-voltage, fast rise-time switch that includes a pair of electrodes between which are laminated alternating layers of isolated conductors and insulators. A high voltage is placed between the electrodes sufficient to stress the voltage breakdown of the insulator on command. A light trigger, such as a laser, is focused along at least one line along the edge surface of the laminated alternating layers of isolated conductors and insulators extending between the electrodes. The laser is energized to initiate a surface breakdown by a fluence of photons, thus causing the electrical switch to close very promptly. Such insulators and lasers are incorporated in a dielectric wall linear accelerator with Blumlein modules, and phasing is controlled by adjusting the length of fiber optic cables that carry the laser light to the insulator surface.

  14. Thin film electronic devices with conductive and transparent gas and moisture permeation barriers

    DOE Patents [OSTI]

    Simpson, Lin Jay

    2013-12-17

    A thin film stack (100, 200) is provided for use in electronic devices such as photovoltaic devices. The stack (100, 200) may be integrated with a substrate (110) such as a light transmitting/transmissive layer. A electrical conductor layer (120, 220) is formed on a surface of the substrate (110) or device layer such as a transparent conducting (TC) material layer (120,220) with pin holes or defects (224) caused by manufacturing. The stack (100) includes a thin film (130, 230) of metal that acts as a barrier for environmental contaminants (226, 228). The metal thin film (130,230) is deposited on the conductor layer (120, 220) and formed from a self-healing metal such as a metal that forms self-terminating oxides. A permeation plug or block (236) is formed in or adjacent to the thin film (130, 230) of metal at or proximate to the pin holes (224) to block further permeation of contaminants through the pin holes (224).

  15. Improving Data Transparency for the Distributed PV Interconnection...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Data Transparency for the Distributed PV Page 1 of 21 Interconnection Process Emergent ... The topic for today is: Improving Data Transparency for the Distributed PV Interconnection ...

  16. Aluminum-Alkaline Metal-Metal Composite Conductor - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Electricity Transmission Electricity Transmission Advanced Materials Advanced Materials Find More Like This Return to Search Aluminum-Alkaline Metal-Metal Composite Conductor Ames Laboratory Contact AMES About This Technology Technology Marketing Summary Iowa State University and Ames Laboratory researchers have developed a high strength, lightweight aluminum wire for high-voltage power transmission with reduced electrical resistance for overhead electrical lines. Description

  17. Aluminum-Alkaline Metal-Metal Composite Conductor - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Electricity Transmission Electricity Transmission Advanced Materials Advanced Materials Find More Like This Return to Search Aluminum-Alkaline Metal-Metal Composite Conductor Ames Laboratory Contact AMES About This Technology Technology Marketing Summary Researchers have developed a high strength, lightweight aluminum wire for high-voltage power transmission with reduced electrical resistance for overhead electrical lines. High-voltage electric power transmission cables based on pure

  18. Apparatus for measuring minority carrier lifetime using liquid conductor -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Innovation Portal Industrial Technologies Industrial Technologies Find More Like This Return to Search Apparatus for measuring minority carrier lifetime using liquid conductor National Renewable Energy Laboratory Contact NREL About This Technology Technology Marketing Summary Solar power generating capacity has grown from 83 MW in 2003 to over 7,200 MW in 2012, in the U.S. alone. As the solar industry grows, there is a significant need for quality control and testing methodologies.

  19. Thermoelectric effects in organic conductors in a strong magnetic field

    SciTech Connect (OSTI)

    Kirichenko, O. V.; Peschanskii, V. G. Hasan, R. A.

    2007-07-15

    The linear response of the electron system of a layered conductor to the temperature gradient in this system in a strong magnetic field is investigated theoretically. Thermoelectric emf is studied as a function of the magnitude and orientation of a strong external magnetic field; the experimental investigation of this function, combined with the study of the electric and thermal resistance, allows one to completely determine the structure of the energy spectrum of charge carriers.

  20. Graphene–Metamaterial Photodetectors for Integrated Infrared Sensing

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Luxmoore, Isaac. J.; Liu, Peter Q.; Li, Penglei; Faist, Jérôme; Nash, Geoffrey R.

    2016-05-31

    We study metamaterial-enhanced graphene photodetectors operating in the mid-IR to THz. The detector element consists of a graphene ribbon embedded within a dual-metal split ring resonator, which acts like a cavity to enhance the absorption of electromagnetic radiation by the graphene ribbon, while the asymmetric metal contacts enable photothermoelectric detection. The detectors we designed for the mid-IR demonstrate peak responsivity (referenced to total power) of ~120 mV/W at 1500 cm-1 and are employed in the spectroscopic evaluation of vibrational resonances, thus demonstrating a key step toward a platform for integrated surface-enhanced sensing.

  1. Capacitive micromachined ultrasonic transducer arrays as tunable acoustic metamaterials

    SciTech Connect (OSTI)

    Lani, Shane W. E-mail: karim.sabra@me.gatech.edu Sabra, Karim G.; Wasequr Rashid, M.; Hasler, Jennifer; Levent Degertekin, F.

    2014-02-03

    Capacitive Micromachined Ultrasonic Transducers (CMUTs) operating in immersion support dispersive evanescent waves due to the subwavelength periodic structure of electrostatically actuated membranes in the array. Evanescent wave characteristics also depend on the membrane resonance which is modified by the externally applied bias voltage, offering a mechanism to tune the CMUT array as an acoustic metamaterial. The dispersion and tunability characteristics are examined using a computationally efficient, mutual radiation impedance based approach to model a finite-size array and realistic parameters of variation. The simulations are verified, and tunability is demonstrated by experiments on a linear CMUT array operating in 2-12 MHz range.

  2. A tunable metamaterial dependent on electric field at terahertz with barium strontium titanate thin film

    SciTech Connect (OSTI)

    Bian, Yanlong; Zhai, Jiwei; Wu, Chao; Li, Hongqiang

    2014-01-27

    A tunable metamaterial with resonance frequency at terahertz (THz) was developed. Electromagnetic response of the metamaterial was characterized with THz time domain spectrometer at various direct current electric fields. The resonance frequency increased monotonously with increasing electric field. The finite difference time domain method was used to simulate the transmission spectra of the metamaterial at THz frequencies. By comparing the simulated resonance frequency with the experimental curve, dielectric property of the Ba{sub 0.6}Sr{sub 0.4}TiO{sub 3} (BST60) thin film at THz, over 033?kV/cm, was evaluated.

  3. Subtask 5: Functional nanostructured transparent electrode materials...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5: Functional nanostructured transparent electrode materials All papers by year Subtask 1 Subtask 2 Subtask 3 Subtask 4 Subtask 5 Jeon, K.-W. and Seo, D.-K. (2014) Concomitant...

  4. Transparency: it's not just for windows

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transparency: it's not just for windows Transparency: it's not just for windows Los Alamos National Laboratory's database of environmental monitoring data is now directly viewable by the public. March 20, 2012 Intellus environmental data The same environmental data used by LANL scientists can be viewed by anyone, anytime. Contact Environmental Communications & Public Involvement P.O. Box 1663 MS M996 Los Alamos, NM 87545 (505) 667-0216 Email "The new system contains more than 9 million

  5. Transparent conducting oxides and production thereof

    DOE Patents [OSTI]

    Gessert, Timothy A.; Yoshida, Yuki; Coutts, Timothy J.

    2014-06-10

    Transparent conducting oxides and production thereof are disclosed. An exemplary method of producing a transparent conducting oxide (TCO) material may comprise: providing a TCO target doped with either a high-permittivity oxide or a low-permittivity oxide in a process chamber. The method may also comprise depositing a metal oxide on the target in the process chamber to form a thin film having enhanced optical properties without substantially decreasing electrical quality.

  6. Transparent conducting oxides and production thereof

    DOE Patents [OSTI]

    Gessert, Timothy A; Yoshida, Yuki; Coutts, Timothy J

    2014-05-27

    Transparent conducting oxides and production thereof are disclosed. An exemplary method of producing a transparent conducting oxide (TCO) material may comprise: providing a TCO target (110) doped with either a high-permittivity oxide or a low-permittivity oxide in a process chamber (100). The method may also comprise depositing a metal oxide on the target (110) to form a thin film having enhanced optical properties without substantially decreasing electrical quality.

  7. High quality transparent conducting oxide thin films

    DOE Patents [OSTI]

    Gessert, Timothy A.; Duenow, Joel N.; Barnes, Teresa; Coutts, Timothy J.

    2012-08-28

    A transparent conducting oxide (TCO) film comprising: a TCO layer, and dopants selected from the elements consisting of Vanadium, Molybdenum, Tantalum, Niobium, Antimony, Titanium, Zirconium, and Hafnium, wherein the elements are n-type dopants; and wherein the transparent conducting oxide is characterized by an improved electron mobility of about 42 cm.sup.2/V-sec while simultaneously maintaining a high carrier density of .about.4.4e.times.10.sup.20 cm.sup.-3.

  8. Lutetium oxide-based transparent ceramic scintillators

    DOE Patents [OSTI]

    Seeley, Zachary; Cherepy, Nerine; Kuntz, Joshua; Payne, Stephen A.

    2016-01-19

    In one embodiment, a transparent ceramic of sintered nanoparticles includes gadolinium lutetium oxide doped with europium having a chemical composition (Lu.sub.1-xGd.sub.x).sub.2-YEu.sub.YO.sub.3, where X is any value within a range from about 0.05 to about 0.45 and Y is any value within a range from about 0.01 to about 0.2, and where the transparent ceramic exhibits a transparency characterized by a scatter coefficient of less than about 10%/cm. In another embodiment, a transparent ceramic scintillator of sintered nanoparticles, includes a body of sintered nanoparticles including gadolinium lutetium oxide doped with a rare earth activator (RE) having a chemical composition (Lu.sub.1-xGd.sub.x).sub.2-YRE.sub.YO.sub.3, where RE is selected from the group consisting of: Sm, Eu, Tb, and Dy, where the transparent ceramic exhibits a transparency characterized by a scatter coefficient of less than about 10%/cm.

  9. Vertically aligned gas-insulated transmission line having particle traps at the inner conductor

    DOE Patents [OSTI]

    Dale, Steinar J.

    1984-01-01

    Gas insulated electrical apparatus having first and second conductors separated by an insulating support within an insulating gas environment, and particle traps disposed along the surface of the high potential conductor for trapping and inactivating foreign particles which may be present within the insulating gas medium. Several embodiments of the invention were developed which are particularly suited for vertically aligned gas insulated transmission lines. The particle traps are grooves or cavities formed into the walls of the tubular inner conductor, without extending into the hollow portion of the conductor. In other embodiments, the traps are appendages or insert flanges extending from the inner conductor, with the insulator supports contacting the appendages instead of the inner conductor.

  10. Near-field radiative heat transfer between metamaterials coated with silicon carbide thin films

    SciTech Connect (OSTI)

    Basu, Soumyadipta Yang, Yue; Wang, Liping

    2015-01-19

    In this letter, we study the near-field radiative heat transfer between two metamaterial substrates coated with silicon carbide (SiC) thin films. It is known that metamaterials can enhance the near-field heat transfer over ordinary materials due to excitation of magnetic plasmons associated with s polarization, while strong surface phonon polariton exists for SiC. By careful tuning of the optical properties of metamaterial, it is possible to excite electrical and magnetic resonances for the metamaterial and surface phonon polaritons for SiC at different spectral regions, resulting in the enhanced heat transfer. The effect of the SiC film thickness at different vacuum gaps is investigated. Results obtained from this study will be beneficial for application of thin film coatings for energy harvesting.

  11. Comments on: New report offers best practice for transparent...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    sandia-national-laboratories-report-offers-best-practice-for-transparent-contract-language-of-pv-om-agreements...

  12. Getting Light in Shape with Metamaterials | U.S. DOE Office of Science (SC)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Getting Light in Shape with Metamaterials Basic Energy Sciences (BES) BES Home About Research Facilities Science Highlights Benefits of BES Funding Opportunities Basic Energy Sciences Advisory Committee (BESAC) Community Resources Contact Information Basic Energy Sciences U.S. Department of Energy SC-22/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-3081 F: (301) 903-6594 E: Email Us More Information » 07.26.16 Getting Light in Shape with Metamaterials

  13. Enhanced optical nonlinearities in the near-infrared using III-nitride heterostructures coupled to metamaterials

    SciTech Connect (OSTI)

    Wolf, Omri E-mail: ibrener@sandia.gov; Ma, Xuedan; Brener, Igal E-mail: ibrener@sandia.gov; Allerman, Andrew A.; Wendt, Joel R.; Shaner, Eric A.; Song, Alex Y.

    2015-10-12

    We use planar metamaterial resonators to enhance by more than two orders of magnitude the near infrared second harmonic generation obtained from intersubband transitions in III-Nitride heterostructures. The improvement arises from two factors: employing an asymmetric double quantum well design and aligning the resonators' cross-polarized resonances with the intersubband transition energies. The resulting nonlinear metamaterial operates at wavelengths where single photon detection is available, and represents a different class of sources for quantum photonics related phenomena.

  14. Enhanced optical nonlinearities in the near-infrared using III-nitride heterostructures coupled to metamaterials

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wolf, Omri; Allerman, Andrew A.; Ma, Xuedan; Wendt, Joel R.; Song, Alex Y.; Shaner, Eric A.; Brener, Igal

    2015-10-15

    We use planar metamaterial resonators to enhance, by more than two orders of magnitude, the optical second harmonic generation, in the near infrared, obtained from intersubband transitions in III-Nitride heterostructures. The improvement arises from two factors: employing an asymmetric double quantum well design and aligning the resonators’ cross-polarized resonances with the intersubband transition energies. The resulting nonlinear metamaterial operates at wavelengths where single photon detection is available, and represents a new class of sources for quantum photonics related phenomena.

  15. Response of High-Tc Superconductor Metamaterials to High Intensity THz

    Office of Scientific and Technical Information (OSTI)

    Radiation (Conference) | SciTech Connect Response of High-Tc Superconductor Metamaterials to High Intensity THz Radiation Citation Details In-Document Search Title: Response of High-Tc Superconductor Metamaterials to High Intensity THz Radiation Authors: Grady, Nathaniel [1] ; Perkins Jr., Bradford G. [2] ; Hwang, Harold Y. [2] ; Brandt, Nate [2] ; Torchinsky, Darius [2] ; Singh, Ranjan [1] ; Yan, Li [3] ; Jia, Quanxi [1] ; Trugman, Stuart A. [1] ; Taylor, Antoinette J. [1] ; Nelson, Keith

  16. Lithography-free large-area metamaterials for stable thermophotovoltaic energy conversion

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Coppens, Zachary J.; Kravchenko, Ivan I.; Valentine, Jason G.

    2016-02-08

    A large-area metamaterial thermal emitter is fabricated using facile, lithography-free techniques. The device is composed of conductive oxides, refractory ceramics, and noble metals and shows stable, selective emission after exposure to 1173 K for 22 h in oxidizing and inert atmospheres. Lastly, the results indicate that the metamaterial can be used to achieve high-performance thermophotovoltaic devices for applications such as portable power generation.

  17. Semi-flexible gas-insulated transmission line using protection tube in conductor plug-in joint

    DOE Patents [OSTI]

    Kommineni, Prasad R.

    1983-01-25

    A gas-insulated transmission line includes an outer sheath, an inner conductor, an insulating gas electrically insulating the inner conductor from the outer sheath, and insulating supports insulatably supporting the inner conductor within the outer sheath. The inner conductor is provided with flexibility by main conductor sections which are joined together through a conductor hub section and flexible flexing elements. Stress shields are provided to control the electric field at the locations of the conductor hub sections where the insulating supports are contacting the inner conductor. A plug and socket arrangement is utilized for joining adjacent sections of the inner conductor, and a protection tube is utilized inside the hollow plug to maintain proper alignment of the joint when the transmission line is bent.

  18. Semi-flexible gas-insulated transmission line using protection tube in conductor plug-in joint

    DOE Patents [OSTI]

    Kommineni, P.R.

    1983-01-25

    A gas-insulated transmission line includes an outer sheath, an inner conductor, an insulating gas electrically insulating the inner conductor from the outer sheath, and insulating supports insulatably supporting the inner conductor within the outer sheath. The inner conductor is provided with flexibility by main conductor sections which are joined together through a conductor hub section and flexible flexing elements. Stress shields are provided to control the electric field at the locations of the conductor hub sections where the insulating supports are contacting the inner conductor. A plug and socket arrangement is utilized for joining adjacent sections of the inner conductor, and a protection tube is utilized inside the hollow plug to maintain proper alignment of the joint when the transmission line is bent. 3 figs.

  19. On the cause of conductivity degradation in sodium strontium silicate ionic conductor

    SciTech Connect (OSTI)

    Jee, Y; Zhao, X; Huang, K

    2015-01-01

    Here we present strong experimental evidence that elucidates the fundamental cause for the conductivity degradation observed in Na-SrSiO3 ionic conductor.

  20. High temperature superconducting composite conductor and method for manufacturing the same

    DOE Patents [OSTI]

    Holesinger, Terry G.; Bingert, John F.

    2002-01-01

    A high temperature superconducting composite conductor is provided including a high temperature superconducting material surrounded by a noble metal layer, the high temperature superconducting composite conductor characterized as having a fill factor of greater than about 40. Additionally, the conductor can be further characterized as containing multiple cores of high temperature superconducting material surrounded by a noble metal layer, said multiple cores characterized as having substantially uniform geometry in the cross-sectional dimensions. Processes of forming such a high temperature superconducting composite conductor are also provided.

  1. Method for deposition of a conductor in integrated circuits

    DOE Patents [OSTI]

    Creighton, J.R.; Dominguez, F.; Johnson, A.W.; Omstead, T.R.

    1997-09-02

    A method is described for fabricating integrated semiconductor circuits and, more particularly, for the selective deposition of a conductor onto a substrate employing a chemical vapor deposition process. By way of example, tungsten can be selectively deposited onto a silicon substrate. At the onset of loss of selectivity of deposition of tungsten onto the silicon substrate, the deposition process is interrupted and unwanted tungsten which has deposited on a mask layer with the silicon substrate can be removed employing a halogen etchant. Thereafter, a plurality of deposition/etch back cycles can be carried out to achieve a predetermined thickness of tungsten. 2 figs.

  2. Method for deposition of a conductor in integrated circuits

    DOE Patents [OSTI]

    Creighton, J. Randall; Dominguez, Frank; Johnson, A. Wayne; Omstead, Thomas R.

    1997-01-01

    A method is described for fabricating integrated semiconductor circuits and, more particularly, for the selective deposition of a conductor onto a substrate employing a chemical vapor deposition process. By way of example, tungsten can be selectively deposited onto a silicon substrate. At the onset of loss of selectivity of deposition of tungsten onto the silicon substrate, the deposition process is interrupted and unwanted tungsten which has deposited on a mask layer with the silicon substrate can be removed employing a halogen etchant. Thereafter, a plurality of deposition/etch back cycles can be carried out to achieve a predetermined thickness of tungsten.

  3. Composite mixed oxide ionic and electronic conductors for hydrogen separation

    DOE Patents [OSTI]

    Gopalan, Srikanth; Pal, Uday B.; Karthikeyan, Annamalai; Hengdong, Cui

    2009-09-15

    A mixed ionic and electronic conducting membrane includes a two-phase solid state ceramic composite, wherein the first phase comprises an oxygen ion conductor and the second phase comprises an n-type electronically conductive oxide, wherein the electronically conductive oxide is stable at an oxygen partial pressure as low as 10.sup.-20 atm and has an electronic conductivity of at least 1 S/cm. A hydrogen separation system and related methods using the mixed ionic and electronic conducting membrane are described.

  4. Cubic Ionic Conductor Ceramics for Alkali Ion Batteries - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cuban Missile Crisis Cuban Missile Crisis Cuba Reconnaissance reveals Soviet missiles in Cuba. The United States blockades Cuba for 13 days until the Soviet Union agrees to remove its missiles Portal

    Advanced Materials Advanced Materials Find More Like This Return to Search Cubic Ionic Conductor Ceramics for Alkali Ion Batteries Brookhaven National Laboratory Contact BNL About This Technology Publications: PDF Document Publication Ionic conduction in cubic Na3TiP3O9N, a secondary Na-ion

  5. Phased-array sources based on nonlinear metamaterial nanocavities

    SciTech Connect (OSTI)

    Wolf, Omri; Campione, Salvatore; Benz, Alexander; Ravikumar, Arvind P.; Liu, Sheng; Luk, Ting S.; Kadlec, Emil Andrew; Shaner, Eric A.; Klem, John Frederick; Sinclair, Michael B.; Brener, Igal

    2015-07-01

    Coherent superposition of light from subwavelength sources is an attractive prospect for the manipulation of the direction, shape and polarization of optical beams. This phenomenon constitutes the basis of phased arrays, commonly used at microwave and radio frequencies. Here we propose a new concept for phased-array sources at infrared frequencies based on metamaterial nanocavities coupled to a highly nonlinear semiconductor heterostructure. Optical pumping of the nanocavity induces a localized, phase-locked, nonlinear resonant polarization that acts as a source feed for a higher-order resonance of the nanocavity. Varying the nanocavity design enables the production of beams with arbitrary shape and polarization. As an example, we demonstrate two second harmonic phased-array sources that perform two optical functions at the second harmonic wavelength (~5 μm): a beam splitter and a polarizing beam splitter. As a result, proper design of the nanocavity and nonlinear heterostructure will enable such phased arrays to span most of the infrared spectrum.

  6. Fabrication of transparent ceramics using nanoparticles

    DOE Patents [OSTI]

    Cherepy, Nerine J; Tillotson, Thomas M; Kuntz, Joshua D; Payne, Stephen A

    2012-09-18

    A method of fabrication of a transparent ceramic using nanoparticles synthesized via organic acid complexation-combustion includes providing metal salts, dissolving said metal salts to produce an aqueous salt solution, adding an organic chelating agent to produce a complexed-metal sol, heating said complexed-metal sol to produce a gel, drying said gel to produce a powder, combusting said powder to produce nano-particles, calcining said nano-particles to produce oxide nano-particles, forming said oxide nano-particles into a green body, and sintering said green body to produce the transparent ceramic.

  7. Process for forming transparent aerogel insulating arrays

    SciTech Connect (OSTI)

    Tewari, P.H.; Hunt, A.J.

    1986-09-09

    This patent describes a drying process for forming transparent aerogel insulating arrays of the type utilizing the steps of hydrolyzing and condensing alkoxides to form alcogels, and subsequently removing the alcohol therefrom to form aerogels, the improvement comprising the additional step, after alcogels are formed, of substituting a solvent having a critical temperature less than the critical temperature of the alcohol for the alcohol in the alcogels, and drying the resulting gels at a supercritical temperature for the solvent, to thereby provide a transparent aerogel array within a substantially reduced drying time period.

  8. Ceramic to metal attachment system. [Ceramic electrode to metal conductor in MHD generator

    DOE Patents [OSTI]

    Marchant, D.D.

    1983-06-10

    A composition and method are described for attaching a ceramic electrode to a metal conductor. A layer of randomly interlocked metal fibers saturated with polyimide resin is sandwiched between the ceramic electrode and the metal conductor. The polyimide resin is then polymerized providing bonding.

  9. Process for forming transparent aerogel insulating arrays

    DOE Patents [OSTI]

    Tewari, P.H.; Hunt, A.J.

    1985-09-04

    An improved supercritical drying process for forming transparent silica aerogel arrays is described. The process is of the type utilizing the steps of hydrolyzing and condensing aloxides to form alcogels. A subsequent step removes the alcohol to form aerogels. The improvement includes the additional step, after alcogels are formed, of substituting a solvent, such as CO/sub 2/, for the alcohol in the alcogels, the solvent having a critical temperature less than the critical temperature of the alcohol. The resulting gels are dried at a supercritical temperature for the selected solvent, such as CO/sub 2/, to thereby provide a transparent aerogel array within a substantially reduced (days-to-hours) time period. The supercritical drying occurs at about 40/sup 0/C instead of at about 270/sup 0/C. The improved process provides increased yields of large scale, structurally sound arrays. The transparent aerogel array, formed in sheets or slabs, as made in accordance with the improved process, can replace the air gap within a double glazed window, for example, to provide a substantial reduction in heat transfer. The thus formed transparent aerogel arrays may also be utilized, for example, in windows of refrigerators and ovens, or in the walls and doors thereof or as the active material in detectors for analyzing high energy elementary particles or cosmic rays.

  10. Process for forming transparent aerogel insulating arrays

    DOE Patents [OSTI]

    Tewari, Param H.; Hunt, Arlon J.

    1986-01-01

    An improved supercritical drying process for forming transparent silica aerogel arrays is described. The process is of the type utilizing the steps of hydrolyzing and condensing aloxides to form alcogels. A subsequent step removes the alcohol to form aerogels. The improvement includes the additional step, after alcogels are formed, of substituting a solvent, such as CO.sub.2, for the alcohol in the alcogels, the solvent having a critical temperature less than the critical temperature of the alcohol. The resulting gels are dried at a supercritical temperature for the selected solvent, such as CO.sub.2, to thereby provide a transparent aerogel array within a substantially reduced (days-to-hours) time period. The supercritical drying occurs at about 40.degree. C. instead of at about 270.degree. C. The improved process provides increased yields of large scale, structurally sound arrays. The transparent aerogel array, formed in sheets or slabs, as made in accordance with the improved process, can replace the air gap within a double glazed window, for example, to provide a substantial reduction in heat transfer. The thus formed transparent aerogel arrays may also be utilized, for example, in windows of refrigerators and ovens, or in the walls and doors thereof or as the active material in detectors for analyzing high energy elementry particles or cosmic rays.

  11. Overview of Russian HEU transparency issues

    SciTech Connect (OSTI)

    Kempf, C.R.; Bieniawski, A.

    1993-09-01

    The U.S. has signed an agreement with the Russian Federation for the purchase of 500 metric tons of highly-enriched uranium (HEU) taken from dismantled nuclear weapons. The HEU will be blended down to low-enriched uranium and will be transported to the U.S. to be used by fuel fabricators to make fuel for commercial nuclear power plants. Both the U.S. and Russia have been preparing to institute transparency measures to provide assurance that nonproliferation and arms control objectives specified in the agreement are met. This paper provides background information on the original agreement and on subsequent negotiations with the Russians, as well as discussion of technical aspects of developing transparency measures suited to the facilities and processes which are expected to be involved. Transparency has been defined as those agreed-upon measures which build confidence that arms control and non-proliferation objectives shared by the parties are met. Transparency is a departure from exhaustive, detailed arms control verification regimes of past agreements, which were based on a presumption of detecting transgressions as opposed to confirming compliance.

  12. Aerogel: a transparent insulator for solar applications

    SciTech Connect (OSTI)

    Hunt, A.J.; Russo, R.E.; Tewari, P.H.; Lofftus, K.D.

    1985-06-01

    Aerogel is a transparent, low density, insulating material suitable for a variety of solar applications. Significant energy savings can be realized by using aerogel for a window glazing material. Other possible applications include solar collector covers, transparent insulating jackets for direct gain passive solar devices, and situations that require both transparency and good insulation. Because silica aerogel has a low density (2 to 10% solid), it has a thermal conductivity as low as 0.014 W/m/sup 0/K without evacuation, and if evacuated, lower than 0.006 W/m/sup 0/K. It provides a clear view with only slight coloring due to its weak and nearly isotropic scattering of light. This paper describes significant progress made in the past year at our laboratory in the development of aerogel. We have improved the transparency, developed new preparation methods using less toxic materials, and initiated successful experiments in drying alcogels at near ambient temperature. Optical transmission, light scattering, and electron microscopy data show that CO/sub 2/ supercritical drying of alcogels produces aerogels similar in quality to those produced by high temperature supercritical drying. These advances make the commercial production of aerogel much more feasible.

  13. Admittance of multiterminal quantum Hall conductors at kilohertz frequencies

    SciTech Connect (OSTI)

    Hernndez, C.; Consejo, C.; Chaubet, C.; Degiovanni, P.

    2014-03-28

    We present an experimental study of the low frequency admittance of quantum Hall conductors in the [100?Hz, 1?MHz] frequency range. We show that the frequency dependence of the admittance of the sample strongly depends on the topology of the contacts connections. Our experimental results are well explained within the Christen and Bttiker approach for finite frequency transport in quantum Hall edge channels taking into account the influence of the coaxial cables capacitance. In the Hall bar geometry, we demonstrate that there exists a configuration in which the cable capacitance does not influence the admittance measurement of the sample. In this case, we measure the electrochemical capacitance of the sample and observe its dependence on the filling factor.

  14. Segmented saddle-shaped passive stabilization conductors for toroidal plasmas

    DOE Patents [OSTI]

    Leuer, J.A.

    1990-05-01

    A large toroidal vacuum chamber for plasma generation and confinement is lined with a toroidal blanket for shielding using modules segmented in the toroidal direction. To provide passive stabilization in the same manner as a conductive vacuum chamber wall, saddle-shaped conductor loops are provided on blanket modules centered on a midplane of the toroidal chamber with horizontal conductive bars above and below the midplane, and vertical conductive legs on opposite sides of each module to provide return current paths between the upper and lower horizontal conductive bars. The close proximity of the vertical legs provided on adjacent modules without making physical contact cancel the electromagnetic field of adjacent vertical legs. The conductive bars spaced equally above and below the midplane simulate toroidal conductive loops or hoops that are continuous, for vertical stabilization of the plasma even though they are actually segmented. 5 figs.

  15. Methods and apparatus for transparent display using scattering nanoparticles

    DOE Patents [OSTI]

    Hsu, Chia Wei; Qiu, Wenjun; Zhen, Bo; Shapira, Ofer; Soljacic, Marin

    2016-05-10

    Transparent displays enable many useful applications, including heads-up displays for cars and aircraft as well as displays on eyeglasses and glass windows. Unfortunately, transparent displays made of organic light-emitting diodes are typically expensive and opaque. Heads-up displays often require fixed light sources and have limited viewing angles. And transparent displays that use frequency conversion are typically energy inefficient. Conversely, the present transparent displays operate by scattering visible light from resonant nanoparticles with narrowband scattering cross sections and small absorption cross sections. More specifically, projecting an image onto a transparent screen doped with nanoparticles that selectively scatter light at the image wavelength(s) yields an image on the screen visible to an observer. Because the nanoparticles scatter light at only certain wavelengths, the screen is practically transparent under ambient light. Exemplary transparent scattering displays can be simple, inexpensive, scalable to large sizes, viewable over wide angular ranges, energy efficient, and transparent simultaneously.

  16. Controlling Surface Properties of Transparent Conducting Oxides | ANSER

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center | Argonne-Northwestern National Laboratory Controlling Surface Properties of Transparent Conducting Oxides Home > Research > ANSER Research Highlights > Controlling Surface Properties of Transparent Conducting Oxides

  17. Skin explosion of double-layer conductors in fast-rising high magnetic fields

    SciTech Connect (OSTI)

    Chaikovsky, S. A. Datsko, I. M.; Labetskaya, N. A.; Ratakhin, N. A.

    2014-04-15

    An experiment has been performed to study the electrical explosion of thick cylindrical conductors using the MIG pulsed power generator capable of producing a peak current of 2.5 MA within 100?ns rise time. The experimental goal was to compare the skin explosion of a solid conductor with that of a double-layer conductor whose outer layer had a lower conductivity than the inner one. It has been shown that in magnetic fields of peak induction up to 300?T and average induction rise rate 3??10{sup 9}?T/s, the double-layer structure of a conductor makes it possible to achieve higher magnetic induction at the conductor surface before it explodes. This can be accounted for, in particular, by the reduction of the ratio of the Joule heat density to the energy density of the magnetic field at the surface of a double-layer conductor due to redistribution of the current density over the conductor cross section.

  18. Optical Strong Coupling between near-Infrared Metamaterials and Intersubband Transitions in III-Nitride Heterostructures

    SciTech Connect (OSTI)

    Benz, Alexander; Campione, Salvatore; Moseley, Michael W.; Wierer, Jonathan J.; Allerman, Andrew A.; Wendt, Joel R.; Brener, Igal

    2014-08-25

    We present the design, realization, and characterization of optical strong light–matter coupling between intersubband transitions within a semiconductor heterostructures and planar metamaterials in the near-infrared spectral range. The strong light–matter coupling entity consists of a III-nitride intersubband superlattice heterostructure, providing a two-level system with a transition energy of ~0.8 eV (λ ~1.55 μm) and a planar “dogbone” metamaterial structure. Furthermore, as the bare metamaterial resonance frequency is varied across the intersubband resonance, a clear anticrossing behavior is observed in the frequency domain. We found that this strongly coupled entity could enable the realization of electrically tunable optical filters, a new class of efficient nonlinear optical materials, or intersubband-based light-emitting diodes.

  19. Electrically tunable terahertz wave modulator based on complementary metamaterial and graphene

    SciTech Connect (OSTI)

    He, Xun-jun, E-mail: hexunjun@hrbust.edu.cn; Li, Teng-yue; Wang, Lei; Wang, Jian-min; Jiang, Jiu-xing [Department of Electronic Science and technology, School of Applied Sciences, Harbin University of Science and Technology, Harbin 150080 (China); Yang, Guo-hui; Meng, Fan-yi; Wu, Qun [Department of Electronic and Communications Engineering, School of Electronic Information Engineering, Harbin Institute of Technology, Harbin 150001 (China)

    2014-05-07

    In this paper, we design and numerically demonstrate an electrically controllable light-matter interaction in a hybrid material/metamaterial system consisting of an artificially constructed cross cut-wire complementary metamaterial and an atomically thin graphene layer to realize terahertz (THz) wave modulator. By applying a bias voltage between the metamaterial and the graphene layer, this modulator can dynamically control the amplitude and phase of the transmitted wave near 1.43 THz. Moreover, the distributions of current density show that this large modulation depth can be attributed to the resonant electric field parallel to the graphene sheet. Therefore, the modulator performance indicates the enormous potential of graphene for developing sophisticated THz communication systems.

  20. Experimental demonstration of ultrasensitive sensing with terahertz metamaterial absorbers: A comparison with the metasurfaces

    SciTech Connect (OSTI)

    Cong, Longqing; Singh, Ranjan; Tan, Siyu; Yahiaoui, Riad; Yan, Fengping; Zhang, Weili

    2015-01-19

    Planar metasurfaces and plasmonic resonators have shown great promise for sensing applications across the electromagnetic domain ranging from the microwaves to the optical frequencies. However, these sensors suffer from lower figure of merit and sensitivity due to the radiative and the non-radiative loss channels in the plasmonic metamaterial systems. We demonstrate a metamaterial absorber based ultrasensitive sensing scheme at the terahertz frequencies with significantly enhanced sensitivity and an order of magnitude higher figure of merit compared to planar metasurfaces. Magnetic and electric resonant field enhancement in the impedance matched absorber cavity enables stronger interaction with the dielectric analyte. This finding opens up opportunities for perfect metamaterial absorbers to be applied as efficient sensors in the finger print region of the electromagnetic spectrum with several organic, explosive, and bio-molecules that have unique spectral signature at the terahertz frequencies.

  1. Optical Strong Coupling between near-Infrared Metamaterials and Intersubband Transitions in III-Nitride Heterostructures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Benz, Alexander; Campione, Salvatore; Moseley, Michael W.; Wierer, Jonathan J.; Allerman, Andrew A.; Wendt, Joel R.; Brener, Igal

    2014-08-25

    We present the design, realization, and characterization of optical strong light–matter coupling between intersubband transitions within a semiconductor heterostructures and planar metamaterials in the near-infrared spectral range. The strong light–matter coupling entity consists of a III-nitride intersubband superlattice heterostructure, providing a two-level system with a transition energy of ~0.8 eV (λ ~1.55 μm) and a planar “dogbone” metamaterial structure. Furthermore, as the bare metamaterial resonance frequency is varied across the intersubband resonance, a clear anticrossing behavior is observed in the frequency domain. We found that this strongly coupled entity could enable the realization of electrically tunable optical filters, a newmore » class of efficient nonlinear optical materials, or intersubband-based light-emitting diodes.« less

  2. Liquid fuel vaporizer and combustion chamber having an adjustable thermal conductor

    DOE Patents [OSTI]

    Powell, Michael R; Whyatt, Greg A; Howe, Daniel T; Fountain, Matthew S

    2014-03-04

    The efficiency and effectiveness of apparatuses for vaporizing and combusting liquid fuel can be improved using thermal conductors. For example, an apparatus having a liquid fuel vaporizer and a combustion chamber can be characterized by a thermal conductor that conducts heat from the combustion chamber to the vaporizer. The thermal conductor can be a movable member positioned at an insertion depth within the combustion chamber that corresponds to a rate of heat conduction from the combustion chamber to the vaporizer. The rate of heat conduction can, therefore, be adjusted by positioning the movable member at a different insertion depth.

  3. New Polymeric Proton Conductors for Water-free and High-temperature Fuel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cells | Department of Energy Polymeric Proton Conductors for Water-free and High-temperature Fuel Cells New Polymeric Proton Conductors for Water-free and High-temperature Fuel Cells Presentation on New Polymeric Proton Conductors for Water-free and High-temperature Fuel Cells to the High Temperature Membrane Working Group Meeting held in Arlington, Virginia, May 26,2005. htmwg05_kerr.pdf (158.09 KB) More Documents & Publications Polyelectrolyte Materials for High Temperature Fuel Cells

  4. Transparent ceramics and methods of preparation thereof

    DOE Patents [OSTI]

    Hollingsworth, Joel P. (Oakland, CA); Kuntz, Joshua D. (Livermore, CA); Seeley, Zachary M. (Pullman, WA); Soules, Thomas F. (Livermore, CA)

    2011-10-18

    According to one embodiment, a method for forming a transparent ceramic preform includes forming a suspension of oxide particles in a solvent, adding the suspension to a mold of a desired shape, and uniformly curing the suspension in the mold for forming a preform. The suspension includes a dispersant but does not include a gelling agent. In another embodiment, a method includes creating a mixture without a gelling agent, the mixture including: inorganic particles, a solvent, and a dispersant. The inorganic particles have a mean diameter of less than about 2000 nm. The method also includes agitating the mixture, adding the mixture to a mold, and curing the mixture in the mold at a temperature of less than about 80.degree. C. for forming a preform. Other methods for forming a transparent ceramic preform are also described according to several embodiments.

  5. Transparent monolithic metal ion containing nanophase aerogels

    SciTech Connect (OSTI)

    Risen, W. M., Jr.; Hu, X.; Ji, S.; Littrell, K.

    1999-12-01

    The formation of monolithic and transparent transition metal containing aerogels has been achieved through cooperative interactions of high molecular weight functionalized carbohydrates and silica precursors, which strongly influence the kinetics of gelation. After initial gelation, subsequent modification of the ligating character of the system, coordination of the group VIII metal ions, and supercritical extraction afford the aerogels. The structures at the nanophase level have been probed by photon and electron transmission and neutron scattering techniques to help elucidate the basis for structural integrity together with the small entity sizes that permit transparency in the visible range. They also help with understanding the chemical reactivities of the metal-containing sites in these very high surface area materials. These results are discussed in connection with new reaction studies.

  6. Transparent heat-spreader for optoelectronic applications

    DOE Patents [OSTI]

    Minano, Juan Carlos; Benitez, Pablo

    2014-11-04

    An optoelectronic cooling system is equally applicable to an LED collimator or a photovoltaic solar concentrator. A transparent fluid conveys heat from the optoelectronic chip to a hollow cover over the system aperture. The cooling system can keep a solar concentrator chip at the same temperature as found for a one-sun flat-plate solar cell. Natural convection or forced circulation can operate to convey heat from the chip to the cover.

  7. Laser-ablative engineering of phase singularities in plasmonic metamaterial arrays for biosensing applications

    SciTech Connect (OSTI)

    Aristov, Andrey I.; Kabashin, Andrei V.; Zywietz, Urs; Evlyukhin, Andrey B.; Reinhardt, Carsten; Chichkov, Boris N.

    2014-02-17

    By using methods of laser-induced transfer combined with nanoparticle lithography, we design and fabricate large-area gold nanoparticle-based metamaterial arrays exhibiting extreme Heaviside-like phase jumps in reflected light due to a strong diffractive coupling of localized plasmons. When employed in sensing schemes, these phase singularities provide the sensitivity of 5??10{sup 4} deg. of phase shift per refractive index unit change that is comparable with best values reported for plasmonic biosensors. The implementation of sensor platforms on the basis of such metamaterial arrays promises a drastic improvement of sensitivity and cost efficiency of plasmonic biosensing devices.

  8. Phased-array sources based on nonlinear metamaterial nanocavities

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wolf, Omri; Campione, Salvatore; Benz, Alexander; Ravikumar, Arvind P.; Liu, Sheng; Luk, Ting S.; Kadlec, Emil Andrew; Shaner, Eric A.; Klem, John Frederick; Sinclair, Michael B.; et al

    2015-07-01

    Coherent superposition of light from subwavelength sources is an attractive prospect for the manipulation of the direction, shape and polarization of optical beams. This phenomenon constitutes the basis of phased arrays, commonly used at microwave and radio frequencies. Here we propose a new concept for phased-array sources at infrared frequencies based on metamaterial nanocavities coupled to a highly nonlinear semiconductor heterostructure. Optical pumping of the nanocavity induces a localized, phase-locked, nonlinear resonant polarization that acts as a source feed for a higher-order resonance of the nanocavity. Varying the nanocavity design enables the production of beams with arbitrary shape and polarization.more » As an example, we demonstrate two second harmonic phased-array sources that perform two optical functions at the second harmonic wavelength (~5 μm): a beam splitter and a polarizing beam splitter. As a result, proper design of the nanocavity and nonlinear heterostructure will enable such phased arrays to span most of the infrared spectrum.« less

  9. Controllable Raman soliton self-frequency shift in nonlinear metamaterials

    SciTech Connect (OSTI)

    Xiang Yuanjiang; Wen Shuangchun; Guo Jun; Fan Dianyuan

    2011-09-15

    Controllable and dispersive magnetic permeability in the metamaterials (MMs) provides us more freedom to harness the propagation of ultrashort electromagnetic pulses at will. Here we discuss the controllability of the Raman soliton self-frequency shift (SSFS) in the MMs with a nonlinear electric polarization. First, we derive a generalized nonlinear Schroedinger equation suitable for few-cycle pulse propagation in the MMs with delayed Raman response, and demonstrate the Raman effect, high-order Raman-related nonlinearity, and high-order nonlinear dispersion terms occurring in this equation. Second, we present a theoretical investigation on the controllability of the Raman SSFS in the MMs. In particular, we identify the combined effects of the anomalous self-steepening (SS), third-order dispersion (TOD), and Raman effect on SSFS. It is shown that the positive SS effect suppresses SSFS; however, the negative SS effect enhances SSFS, and the positive TOD leads to the deceleration of SSFS. Finally, the effects of SS on the SSFS of the second-order soliton are also discussed.

  10. Spatiotemporal electromagnetic soliton and spatial ring formation in nonlinear metamaterials

    SciTech Connect (OSTI)

    Zhang Jinggui; Wen Shuangchun; Xiang Yuanjiang; Wang Youwen; Luo Hailu

    2010-02-15

    We present a systematic investigation of ultrashort electromagnetic pulse propagation in metamaterials (MMs) with simultaneous cubic electric and magnetic nonlinearity. We predict that spatiotemporal electromagnetic solitons may exist in the positive-index region of a MM with focusing nonlinearity and anomalous group velocity dispersion (GVD), as well as in the negative-index region of the MM with defocusing nonlinearity and normal GVD. The experimental circumstances for generating and manipulating spatiotemporal electromagnetic solitons can be created by elaborating appropriate MMs. In addition, we find that, in the negative-index region of a MM, a spatial ring may be formed as the electromagnetic pulse propagates for focusing nonlinearity and anomalous GVD; while the phenomenon of temporal splitting of the electromagnetic pulse may appear for the same case except for the defocusing nonlinearity. Finally, we demonstrate that the nonlinear magnetization makes the sign of effective electric nonlinear effect switchable due to the combined action of electric and magnetic nonlinearity, exerting a significant influence on the propagation of electromagnetic pulses.

  11. Second-order nonlinear optical metamaterials: ABC-type nanolaminates

    SciTech Connect (OSTI)

    Alloatti, L. Kieninger, C.; Lauermann, M.; Köhnle, K.; Froelich, A.; Wegener, M.; Frenzel, T.; Freude, W.; Leuthold, J.; Koos, C.

    2015-09-21

    We demonstrate a concept for second-order nonlinear metamaterials that can be obtained from non-metallic centrosymmetric constituents with inherently low optical absorption. The concept is based on iterative atomic-layer deposition of three different materials, A = Al{sub 2}O{sub 3}, B = TiO{sub 2}, and C = HfO{sub 2}. The centrosymmetry of the resulting ABC stack is broken since the ABC and the inverted CBA sequences are not equivalent—a necessary condition for non-zero second-order nonlinearity. In our experiments, we find that the bulk second-order nonlinear susceptibility depends on the density of interfaces, leading to a nonlinear susceptibility of 0.26 pm/V at a wavelength of 800 nm. ABC-type nanolaminates can be deposited on virtually any substrate and offer a promising route towards engineering of second-order optical nonlinearities at both infrared and visible wavelengths.

  12. Ultra-high Q even eigenmode resonance in terahertz metamaterials

    SciTech Connect (OSTI)

    Al-Naib, Ibraheem Dignam, Marc M.; Yang, Yuping; Zhang, Weili; Singh, Ranjan

    2015-01-05

    We report the simultaneous excitation of the odd and the even eigenmode resonances in a periodic array of square split-ring resonators, with four resonators per unit cell. When the electric field is parallel to their gaps, only the two well-studied odd eigenmodes are excited. As the resonators are rotated relative to one another, we observe the emergence and excitation of an extremely sharp even eigenmode. In uncoupled split-ring resonators, this even eigenmode is typically radiative in nature with a broad resonance linewidth and low Q-factor. However, in our coupled system, for specific range of rotation angles, our simulations revealed a remarkably high quality factor (Q ∼ 100) for this eigenmode, which has sub-radiant characteristics. This type of quad-supercell metamaterial offers the advantage of enabling access to all the three distinct resonance features of the split-ring resonator, which consists of two odd eigenmodes in addition to the high-Q even eigenmode, which could be exploited for high performance multiband filters and absorbers. The high Q even eigenmode could find applications in designing label free bio-sensors and for studying the enhanced light matter interaction effects.

  13. TRANSPARENT COATINGS FOR SOLAR CELLS RESEARCH

    SciTech Connect (OSTI)

    Glatkowski, P.J.; Landis, D.A.

    2013-04-16

    Todays solar cells are fabricated using metal oxide based transparent conductive coatings (TCC) or metal wires with optoelectronic performance exceeding that currently possible with Carbon Nanotube (CNT) based TCCs. The motivation for replacing current TCC is their inherent brittleness, high deposition cost, and high deposition temperatures; leading to reduced performance on thin substrates. With improved processing, application and characterization techniques Nanofiber and/or CNT based TCCs can overcome these shortcomings while offering the ability to be applied in atmospheric conditions using low cost coating processes At todays level of development, CNT based TCC are nearing commercial use in touch screens, some types of information displays (i.e. electronic paper), and certain military applications. However, the resistivity and transparency requirements for use in current commercial solar cells are more stringent than in many of these applications. Therefore, significant research on fundamental nanotube composition, dispersion and deposition are required to reach the required performance commanded by photovoltaic devices. The objective of this project was to research and develop transparent conductive coatings based on novel nanomaterial composite coatings, which comprise nanotubes, nanofibers, and other nanostructured materials along with binder materials. One objective was to show that these new nanomaterials perform at an electrical resistivity and optical transparency suitable for use in solar cells and other energy-related applications. A second objective was to generate new structures and chemistries with improved resistivity and transparency performance. The materials also included the binders and surface treatments that facilitate the utility of the electrically conductive portion of these composites in solar photovoltaic devices. Performance enhancement venues included: CNT purification and metallic tube separation techniques, chemical doping, CNT

  14. Method of forming macro-structured high surface area transparent conductive oxide electrodes

    DOE Patents [OSTI]

    Forman, Arnold J.; Chen, Zhebo; Jaramillo, Thomas F.

    2016-01-05

    A method of forming a high surface area transparent conducting electrode is provided that includes depositing a transparent conducting thin film on a conductive substrate, where the transparent conducting thin film includes transparent conductive particles and a solution-based transparent conducting adhesive layer which serves to coat and bind together the transparent conducting particles, and heat treating the transparent conducting adhesion layer on the conductive substrate, where an increased surface area transparent conducting electrode is formed.

  15. Enhanced Mixed Electronic-Ionic Conductors through Cation Ordering

    SciTech Connect (OSTI)

    Jacobson, Allan J.; Morgan, Dane; Grey, Clare

    2014-08-31

    The performance of many energy conversion and storage devices depend on the properties of mixed ionic-electronic conducting (miec) materials. Mixed or ambipolar conductors simultaneously transport ions and electrons and provide the critical interface between chemical and electrical energy in devices such as fuel cells, ion transport membranes, and batteries. Enhancements in storage capacity, reversibility, power density and device lifetime all require new materials and a better understanding of the fundamentals of ambipolar conductivity and surface reactivity.The high temperature properties of the ordered perovksites AA’B2O5+x, where A = rare earth ion, Y and B = Ba, Sr were studied. The work was motivated by the high oxygen transport and surface exchange rates observed for members of this class of mixed ionic and electronic conductors. A combined experimental and computational approach, including structural, electrochemical, and transport characterization and modeling was used. The approach attacks the problem simultaneously at global (e.g., neutron diffraction and impedance spectroscopy), local (e.g., pair distribution function, nuclear magnetic resonance) and molecular (ab initio thermokinetic modeling) length scales. The objectives of the work were to understand how the cation and associated anion order lead to exceptional ionic and electronic transport properties and surface reactivity in AA’B2O5+x perovskites. A variety of compounds were studied by X-ray and neutron diffraction, measurements of thermodynamics and transport and theoretically. These included PrBaCo2O5+x and NdBaCo2O5+x, PrBaCo2-xFexO6- δ (x = 0, 0.5, 1.0, 1.5 and 2) and LnBaCoFeO6- δ (Ln = La, Pr, Nd, Sm, Eu and Gd), Sr3YCo4O10.5, YBaMn2O5+x. A0.5A’0.5BO3 (where A=Y, Sc, La, Ce, Pr, Nd, Pm, Sm; A’= Sr

  16. Stress-tuned conductor-polymer composite for use in sensors

    DOE Patents [OSTI]

    Martin, James E; Read, Douglas H

    2013-10-22

    A method for making a composite polymeric material with electrical conductivity determined by stress-tuning of the conductor-polymer composite, and sensors made with the stress-tuned conductor-polymer composite made by this method. Stress tuning is achieved by mixing a miscible liquid into the polymer precursor solution or by absorbing into the precursor solution a soluble compound from vapor in contact with the polymer precursor solution. The conductor may or may not be ordered by application of a magnetic field. The composite is formed by polymerization with the stress-tuning agent in the polymer matrix. The stress-tuning agent is removed following polymerization to produce a conductor-polymer composite with a stress field that depends on the amount of stress-tuning agent employed.

  17. Metallographic autopsies of full-scale ITER prototype cable-in-conduit conductors after full cyclic testing in SULTAN: III. The importance of strand surface roughness in long twist pitch conductors

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sanabria, Charlie; Lee, Peter J.; Starch, William; Devred, Arnaud; Larbalestier, David C.

    2016-05-31

    As part of the ITER conductor qualification process, 3 m long Cable-in-Conduit Conductors (CICCs) were tested at the SULTAN facility under conditions simulating ITER operation so as to establish the current sharing temperature, Tcs, as a function of multiple full Lorentz force loading cycles. After a comprehensive evaluation of both the Toroidal Field (TF) and the Central Solenoid (CS) conductors, it was found that Tcs degradation was common in long twist pitch TF conductors while short twist pitch CS conductors showed some Tcs increase. However, one kind of TF conductors containing superconducting strand fabricated by the Bochvar Institute of Inorganicmore » Materials (VNIINM) avoided Tcs degradation despite having long twist pitch. In our earlier metallographic autopsies of long and short twist pitch CS conductors, we observed a substantially greater transverse strand movement under Lorentz force loading for long twist pitch conductors, while short twist pitch conductors had negligible transverse movement. With help from the literature, we concluded that the transverse movement was not the source of Tcs degradation but rather an increase of the compressive strain in the Nb3Sn filaments possibly induced by longitudinal movement of the wires. Like all TF conductors this TF VNIINM conductor showed large transverse motions under Lorentz force loading, but Tcs actually increased, as in all short twist pitch CS conductors. We here propose that the high surface roughness of the VNIINM strand may be responsible for the suppression of the compressive strain enhancement (characteristic of long twist pitch conductors). Furthermore, it appears that increasing strand surface roughness could improve the performance of long twist pitch CICCs.« less

  18. Low-loss LIGA-micromachined conductor-backed coplanar waveguide.

    SciTech Connect (OSTI)

    Forman, Michael A.

    2004-12-01

    A mesoscale low-loss LIGA-micromachined conductor-backed coplanar waveguide is presented. The 517 {micro}m lines are the tallest uniplanar LIGA-fabricated microwave transmission lines to date, as well as the first to be constructed of copper rather than nickel. The conductor-backed micromachined CPW on quartz achieves a measured attenuation of 0.064 dB/cm at 15.5 GHz.

  19. Doped Y.sub.2O.sub.3 buffer layers for laminated conductors

    DOE Patents [OSTI]

    Paranthaman, Mariappan Parans [Knoxville, TN; Schoop, Urs [Westborough, MA; Goyal, Amit [Knoxville, TN; Thieme, Cornelis Leo Hans [Westborough, MA; Verebelyi, Darren T [Oxford, MA; Rupich, Martin W [Framingham, MA

    2007-08-21

    A laminated conductor includes a metallic substrate having a surface, a biaxially textured buffer layer supported by the surface of the metallic substrate, the biaxially textured buffer layer comprising Y.sub.2O.sub.3 and a dopant for blocking cation diffusion through the Y.sub.2O.sub.3, and a biaxially textured conductor layer supported by the biaxially textured buffer layer.

  20. Qualification of the US made conductors for ITER TF magnet system

    SciTech Connect (OSTI)

    Martovetsky, N; Hatfield, D; Miller, J; Bruzzone, P; Stepanov, B; Seber, B

    2009-10-08

    The US Domestic Agency (USDA) is one of the six suppliers of the TF conductor for ITER. In order to qualify conductors according to ITER requirements we prepared several lengths of the CICC and short samples for testing in the SULTAN facility in CRPP, Switzerland. We also fully characterized the strands that were used in these SULTAN samples. Fabrication experience and test results are presented and discussed.

  1. Qualification of the US Made Conductors for ITER TF Magnet System

    SciTech Connect (OSTI)

    Martovetsky, Nicolai N; Hatfield, Daniel R; Miller, John R; Bruzzone, P.; Stepanov, B.; Seber, B.

    2010-01-01

    The US Domestic Agency (USDA) is one of the six suppliers of the TF conductor for ITER. In order to qualify conductors according to ITER requirements we prepared several lengths of the CICC and short samples for testing in the SULTAN facility in CRPP, Switzerland. We also fully characterized the strands that were used in these SULTAN samples. Fabrication experience and test results are presented and discussed.

  2. Conduction Mechanisms and Structure of Ionomeric Single-Ion Conductors

    SciTech Connect (OSTI)

    Colby, Ralph H.; Maranas, Janna K; Mueller, Karl T; Runt, James; Winey, Karen I

    2015-03-05

    Our team has designed using DFT (Gaussian) and synthesized low glass transition temperature single-ion conductors that are either polyanions that conduct small cations Li, Na, Cs or polycations that conduct small anions F, OH, Br. We utilize a wide range of complimentary experimental materials charactization tools to understand ion transport; differential scanning calorimetry, dielectric relaxation spectroscopy, infrared spectroscopy, nuclear magnetic resonance spectroscopy, linear viscoelasticity, X-ray scattering and molecular dynamics simulations. The glass transition temperature Tg needs to be as low as possible to facilitate ion transport, so the nonionic parts of the polymer need to be polar, flexible and have strong solvation interactions with the ions. The lowest Tg we have managed for polyanions conducting Li is -60 C. In contrast, polysiloxanes with PEO side chains and tetrabutylphosphonium cationic side groups have Tg ~ -75C that barely increases with ion content, as anticipated by DFT. A survey of all polyanions in the literature suggests that Tg < -80C is needed to achieve the 10-4 S/cm conductivity needed for battery separators.

  3. THE STABILITY AND ELECTRICAL PROPERTIES OF HIGH TEMPERATURE PROTON CONDUCTORS

    SciTech Connect (OSTI)

    Brinkman, K.

    2010-07-06

    The morphological and electrical properties of Ba{sub 1-x}Sr{sub x}Ce{sub 0.8}Y{sub 0.2}O{sub 3-{delta}} with x varying from 0 to 1 prepared by a modified Pechini method were investigated as potential high temperature proton conductors. Dense microstructures were achieved for all the samples upon sintering at 1500 C for 5 h. The phase structure analysis indicated that perovskite phase was formed for 0 {le} x {le} 0.2, while for x larger than 0.5, impurity phases of Sr{sub 2}CeO{sub 4} and Y{sub 2}O{sub 3} appeared. The tolerance to H{sub 2}O for the samples improved with the increase in Sr content when exposed to boiling water, while the electrical conductivity decreased from x = 0 to 1. However, the resistance to CO{sub 2} attack at elevated temperatures was not improved within the whole x range studied.

  4. Subwavelength silicon through-hole arrays as an all-dielectric broadband terahertz gradient index metamaterial

    SciTech Connect (OSTI)

    Park, Sang-Gil; Jeong, Ki-Hun; Lee, Kanghee; Han, Daehoon; Ahn, Jaewook

    2014-09-01

    Structuring at subwavelength scales brings out artificial media with anomalous optical features called metamaterials. All-dielectric metamaterials have high potential for practical applications over the whole electromagnetic spectrum owing to low loss and optical isotropy. Here, we report subwavelength silicon through-hole arrays as an all-dielectric gradient index metamaterial with broadband THz operation. The unit cell consists of a single subwavelength through-hole on highly resistive monocrystalline silicon. Depending on the fill-factor and period, the effective index was linearly modulated at 0.3–1.6 THz. The experimental results also demonstrate silicon gradient refractive index (Si-GRIN) lenses with parabolic index profiles through the spatial modification of a single unit cell along the radial direction. Si-GRIN lenses either focus 0.4–1.6 THz beam to the diffraction-limit or serve as a flat and thin solid immersion lens on the backside of THz photoconductive antenna for highly efficient pulse extraction. This all-dielectric gradient index metamaterial opens up opportunities for integrated THz GRIN optics.

  5. Controlling terahertz waves with meta-materials and photonic bandgap structures

    SciTech Connect (OSTI)

    Shchegolkov, Dmitry; Azad, Abul; O' Hara, John F; Moody, Nathan A; Simakov, Evgenya I

    2010-12-07

    We will describe research conducted at Los Alamos National Laboratory towards developing components for controlling terahertz waves. We employ meta-materials and, particularly, meta-films, as very compact absorbers for controlling quasioptical beams. We believe that dielectric photonic bandgap structures could replace ordinary metal waveguide devices at THz, since metal structures become extremely lossy in this frequency range.

  6. Nanostructured transparent conducting oxide electrochromic device

    DOE Patents [OSTI]

    Milliron, Delia; Tangirala, Ravisubhash; Llordes, Anna; Buonsanti, Raffaella; Garcia, Guillermo

    2016-05-17

    The embodiments described herein provide an electrochromic device. In an exemplary embodiment, the electrochromic device includes (1) a substrate and (2) a film supported by the substrate, where the film includes transparent conducting oxide (TCO) nanostructures. In a further embodiment, the electrochromic device further includes (a) an electrolyte, where the nanostructures are embedded in the electrolyte, resulting in an electrolyte, nanostructure mixture positioned above the substrate and (b) a counter electrode positioned above the mixture. In a further embodiment, the electrochromic device further includes a conductive coating deposited on the substrate between the substrate and the mixture. In a further embodiment, the electrochromic device further includes a second substrate positioned above the mixture.

  7. Transparent self-cleaning dust shield

    DOE Patents [OSTI]

    Mazumder, Malay K.; Sims, Robert A.; Wilson, James D.

    2005-06-28

    A transparent electromagnetic shield to protect solar panels and the like from dust deposition. The shield is a panel of clear non-conducting (dielectric) material with embedded parallel electrodes. The panel is coated with a semiconducting film. Desirably the electrodes are transparent. The electrodes are connected to a single-phase AC signal or to a multi-phase AC signal that produces a travelling electromagnetic wave. The electromagnetic field produced by the electrodes lifts dust particles away from the shield and repels charged particles. Deposited dust particles are removed when the electrodes are activated, regardless of the resistivity of the dust. Electrostatic charges on the panel are discharged by the semiconducting film. When used in conjunction with photovoltaic cells, the power for the device may be obtained from the cells themselves. For other surfaces, such as windshields, optical windows and the like, the power must be derived from an external source. One embodiment of the invention employs monitoring and detection devices to determine when the level of obscuration of the screen by dust has reached a threshold level requiring activation of the dust removal feature.

  8. TRANSPARENT HELIUM IN STRIPPED ENVELOPE SUPERNOVAE

    SciTech Connect (OSTI)

    Piro, Anthony L.; Morozova, Viktoriya S., E-mail: piro@caltech.edu [Theoretical Astrophysics, California Institute of Technology, 1200 E. California Blvd., M/C 350-17, Pasadena, CA 91125 (United States)

    2014-09-01

    Using simple arguments based on photometric light curves and velocity evolution, we propose that some stripped envelope supernovae (SNe) show signs that a significant fraction of their helium is effectively transparent. The main pieces of evidence are the relatively low velocities with little velocity evolution, as are expected deep inside an exploding star, along with temperatures that are too low to ionize helium. This means that the helium should not contribute to the shaping of the main SN light curve, and thus the total helium mass may be difficult to measure from simple light curve modeling. Conversely, such modeling may be more useful for constraining the mass of the carbon/oxygen core of the SN progenitor. Other stripped envelope SNe show higher velocities and larger velocity gradients, which require an additional opacity source (perhaps the mixing of heavier elements or radioactive nickel) to prevent the helium from being transparent. We discuss ways in which similar analysis can provide insights into the differences and similarities between SNe Ib and Ic, which will lead to a better understanding of their respective formation mechanisms.

  9. NEPA Process Transparency and Openness (DOE, 2009) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Process Transparency and Openness (DOE, 2009) NEPA Process Transparency and Openness (DOE, 2009) This memorandum describes the U.S. Department of Energy's (DOE's) policy for posting online the categorical exclusion determinations made by DOE NEPA Compliance Officers. Download Document NEPA Process Transparency and Openness (59.69 KB) More Documents & Publications Recommendations for the Preparation of Environmental Assessments and Environmental Impact Statements Second Edition (DOE, 2004) 10

  10. Powerpedia - Using Technology to Increase Transparency | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Powerpedia - Using Technology to Increase Transparency Powerpedia - Using Technology to Increase Transparency May 18, 2011 - 4:42pm Addthis The OCIO established a Department-wide wiki, Powerpedia, in early 2010 to facilitate knowledge capture and collaboration, and to increase efficiency. Leveraging lessons learned from the intelligence community's Intellipedia effort, the Department established Powerpedia to increase transparency and connect people and information together. Built on

  11. Promoting NEPA Transparency and Public Engagement | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Promoting NEPA Transparency and Public Engagement Promoting NEPA Transparency and Public Engagement June 3, 2011 - 1:14pm Addthis "NEPA is, at its core, a transparency statute," said Katie Scharf, Council on Environmental Quality (CEQ) Deputy General Counsel, in opening a panel discussion on using information technology to support open government initiatives, engage the public, and add value to NEPA analysis. At the March 9, 2011, event - hosted by CEQ for Federal NEPA and legal staff

  12. 15.02.10 RH Transparent Catalytic - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transparent Catalytic Nickel Oxide Protecting Films for Photoanodes Sun, K. et al. Stable solar-driven oxidation of water by semiconducting photoanodes protected by transparent catalytic nickel oxide films. PNAS 112 ( 12), 3612-3617, DOI: 10.1073/ pnas . 1423034112 (2015). Scientific Achievement Reactively sputtered NiOx layer provides a transparent, anti-reflective, conductive, chemically stable, inherently catalytic coating that stabilizes many efficient and technologically important

  13. 15.07.10 RH P-type Transparent - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    p -Type Transparent Conducting Oxide/n-Type Semiconductor Heterojunctions for Efficient and Stable Solar Water Oxidation Chen, L. et al. p -Type Transparent Conducting Oxide / n-Type Semiconductor Heterojunctions for Efficient and Stable Solar Water Oxidation. Journal of the American Chemical Society, 2015, DOI: 10.1021/ jacs . 5b03536 (2015). Scientific Achievement Efficient charge conduction from the light absorber to the water oxidation catalyst was realized with a transparent,

  14. III-V semiconductor nanoresonators-a new strategy for passive, active, and nonlinear all-dielectric metamaterials

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Sheng; Keeler, Gordon A.; Reno, John L.; Sinclair, Michael B.; Brener, Igal

    2016-06-10

    We demonstrate 2D and multilayer dielectric metamaterials made from III–V semiconductors using a monolithic fabrication process. The resulting structures could be used to recompress chirped femtosecond optical pulses and in a variety of other optical applications requiring low loss. Moreover, these III–V all-dielectric metamaterials could enable novel active applications such as efficient nonlinear frequency converters, light emitters, detectors, and modulators.

  15. Heavy duty insulator assemblies for 500-kV bulk power transmission line with large diameter octagonalbundled conductor

    SciTech Connect (OSTI)

    Tsujimoto, K.; Hayase, I.; Hirai, J.; Inove, M.; Naito, K.; Yukino, T.

    1982-11-01

    This paper describes the design procedure and the results of field tests on mechanical performances of insulator assemblies newly developed to support octagonal-bundled conductors for 500-kV bulk power transmission. Taking account of conductor-motion-induced peak tensile load, fatigue, torsional torque and others, a successful design has been achieved in two prototype assemblies for such heavy mechanical duties as encountered during conductor galloping or swing. This has been proved throughout three years of the field tests.

  16. Net Requirements Transparency Process for Slice/Block Customers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4, 2012 Net Requirements Transparency Process for SliceBlock Customers Description of Changes and a Response to Comments September 24, 2012 Background and Description of Changes:...

  17. UCSB researchers uncover fundamental limits on optical transparency...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a wide range of optoelectronic devices, such as solar cells, light-emitting diodes, and LCD touch screens. These materials can conduct electricity while being transparent to...

  18. Sorted Single-Walled Carbon Nanotube Films for Transparent Electrodes...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sorted Single-Walled Carbon Nanotube Films for Transparent Electrodes in Organic Solar Cells Home > Research > ANSER Research Highlights > Sorted Single-Walled Carbon Nanotube...

  19. New York City Benchmarking and Transparency Policy Impact Evaluation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    New York City's benchmarking and transparency policy, Local Law 84, and the results of the application of those methodologies to the early period of the policy's implementation. ...

  20. Benchmarking and Transparency Policy and Program Impact Evaluation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Benchmarking and Transparency Policy and Program Impact Evaluation Handbook Prepared for by the U.S. Department of Energy, this Handbook provides both a strategic planning ...

  1. Researchers Create Transparent Lithium-Ion Battery - Joint Center...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Stanford and SLAC National Accelerator Laboratory researchers have invented a transparent lithium-ion battery that is also highly flexible. It is comparable in cost to regular ...

  2. 15.07.10 RH P-type Transparent - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for Efficient and Stable Solar Water Oxidation Chen, L. et al. p -Type Transparent Conducting Oxide n-Type Semiconductor Heterojunctions for Efficient and Stable ...

  3. Transparent ceramics and methods of preparation thereof

    DOE Patents [OSTI]

    Hollingsworth, Joel P.; Kuntz, Joshua D.; Seeley, Zachary M.; Soules, Thomas F.

    2012-12-25

    A method for forming a transparent ceramic preform in one embodiment includes forming a suspension of oxide particles in a solvent, wherein the suspension includes a dispersant, with the proviso that the suspension does not include a gelling agent; and uniformly curing the suspension for forming a preform of gelled suspension. A method according to another embodiment includes creating a mixture of inorganic particles, a solvent and a dispersant, the inorganic particles having a mean diameter of less than about 2000 nm; agitating the mixture; adding the mixture to a mold; and curing the mixture in the mold for gelling the mixture, with the proviso that no gelling agent is added to the mixture.

  4. High carrier concentration p-type transparent conducting oxide films

    DOE Patents [OSTI]

    Yan, Yanfa; Zhang, Shengbai

    2005-06-21

    A p-type transparent conducting oxide film is provided which is consisting essentially of, the transparent conducting oxide and a molecular doping source, the oxide and doping source grown under conditions sufficient to deliver the doping source intact onto the oxide.

  5. Transparent Conductive Nano-Composites - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solar Photovoltaic Solar Photovoltaic Electricity Transmission Electricity Transmission Advanced Materials Advanced Materials Find More Like This Return to Search Transparent Conductive Nano-Composites Nanomaterials for Applications Ranging From Photovoltaic Cells to Display Technologies Oak Ridge National Laboratory Contact ORNL About This Technology Technology Marketing Summary Indium Tin Oxide, the most widely used commercial transparent conducting coating, has severe limitations such

  6. Thin Film Electronic Devices with Conductive and Transparent Gas and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Moisture Permeation Barriers - Energy Innovation Portal Solar Photovoltaic Solar Photovoltaic Electricity Transmission Electricity Transmission Advanced Materials Advanced Materials Find More Like This Return to Search Thin Film Electronic Devices with Conductive and Transparent Gas and Moisture Permeation Barriers National Renewable Energy Laboratory Contact NREL About This Technology Technology Marketing Summary Transparent conducting (TC) materials are extensively used in electronics and

  7. Insulated conductor temperature limited heater for subsurface heating coupled in a three-phase WYE configuration

    DOE Patents [OSTI]

    Vinegar, Harold J.; Sandberg, Chester Ledlie

    2010-11-09

    A heating system for a subsurface formation is described. The heating system includes a first heater, a second heater, and a third heater placed in an opening in the subsurface formation. Each heater includes: an electrical conductor; an insulation layer at least partially surrounding the electrical conductor; and an electrically conductive sheath at least partially surrounding the insulation layer. The electrical conductor is electrically coupled to the sheath at a lower end portion of the heater. The lower end portion is the portion of the heater distal from a surface of the opening. The first heater, the second heater, and the third heater are electrically coupled at the lower end portions of the heaters. The first heater, the second heater, and the third heater are configured to be electrically coupled in a three-phase wye configuration.

  8. Experimental study of the nonlinear diffusion of a magnetic field and skin explosion of cylindrical conductors

    SciTech Connect (OSTI)

    Chaikovsky, S. A.; Datsko, I. M.; Labetskaya, N. A.; Rybka, D. V.; Ratakhin, N. A.; Oreshkin, V. I.

    2015-11-15

    The paper presents the results of an experimental study of the skin explosion of cylindrical conductors of diameter 1–3 mm (copper, aluminum, titanium, steel 3, and stainless steel) at a peak magnetic field of 200–600 T. The experiments were carried out on the MIG pulsed power generator at a current of up to 2.5 MA and a current rise time of 100 ns. The surface explosion of a conductor was identified by the appearance of a flash of extreme ultraviolet radiation. A minimum magnetic induction has been determined below which no plasma is generated at the conductor surface. For copper, aluminum, steel 3, titanium, and stainless steel, the minimum magnetic induction has been estimated to be (to within 10%) 375, 270, 280, 220, and 245 T, respectively.

  9. Realizing high-quality ultra-large momentum states using semiconductor hyperbolic metamaterials

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Campione, Salvatore; Liu, Sheng; Luk, Ting S.; Sinclair, Michael B.

    2015-08-05

    We employ both the effective medium approximation (EMA) and Bloch theory to compare the dispersion properties of semiconductor hyperbolic metamaterials (SHMs) at mid-infrared frequencies and metallic hyperbolic metamaterials (MHMs) at visible frequencies. This analysis reveals the conditions under which the EMA can be safely applied for both MHMs and SHMs. We find that the combination of precise nanoscale layering and the longer infrared operating wavelengths puts the SHMs well within the effective medium limit and, in contrast to MHMs, allows for the attainment of very high photon momentum states. Additionally, SHMs allow for new phenomena such as ultrafast creation ofmore » the hyperbolic manifold through optical pumping. Furthermore, we examine the possibility of achieving ultrafast topological transitions through optical pumping which can photo-dope appropriately designed quantum wells on the femtosecond time scale.« less

  10. Incident angle insensitive tunable multichannel perfect absorber consisting of nonlinear plasma and matching metamaterials

    SciTech Connect (OSTI)

    Kong, Xiang-kun; Liu, Shao-Bin Bian, Bo-rui; Chen, Chen; Zhang, Hai-feng

    2014-12-15

    A novel, compact, and multichannel nonreciprocal absorber through a wave tunneling mechanism in epsilon-negative and matching metamaterials is theoretically proposed. Nonreciprocal absorption properties are acquired via the coupling together of evanescent and propagating waves in an asymmetric configuration, constituted of nonlinear plasma alternated with matching metamaterial. The absorption channel number can be adjusted by changing the periodic number. Due to the positive feedback between nonlinear permittivity of plasma and the inner electric field, bistable absorption and reflection are achieved. Moreover, compared with some truncated photonic crystal or multilayered designs proposed before, our design is more compact and independent of incident angle or polarization. This kind of multilayer structure offers additional opportunities to design novel omnidirectional electromagnetic wave absorbers.

  11. Broadband enhancement of local density of states using silicon-compatible hyperbolic metamaterials

    SciTech Connect (OSTI)

    Wang, Yu; Inampudi, Sandeep; Capretti, Antonio; Sugimoto, Hiroshi; Fujii, Minoru; Dal Negro, Luca

    2015-06-15

    Light emitting silicon quantum dots by colloidal synthesis were uniformly spin-coated into a 20 nm-thick film and deposited atop a hyperbolic metamaterial of alternating TiN and SiO{sub 2} sub-wavelength layers. Using steady-state and time-resolved photoluminescence spectroscopy as a function of the emission wavelength in partnership with rigorous electromagnetic modeling of dipolar emission, we demonstrate enhanced Local Density of States and coupling to high-k modes in a broad spectral range. These findings provide an alternative approach for the engineering of novel Si-compatible broadband sources that leverage the control of radiative transitions in hyperbolic metamaterials and the flexibility of the widespread Si platform.

  12. Indium tin oxide nanowires as hyperbolic metamaterials for near-field radiative heat transfer

    SciTech Connect (OSTI)

    Chang, Jui-Yung; Basu, Soumyadipta Wang, Liping

    2015-02-07

    We investigate near-field radiative heat transfer between Indium Tin Oxide (ITO) nanowire arrays which behave as type 1 and 2 hyperbolic metamaterials. Using spatial dispersion dependent effective medium theory to model the dielectric function of the nanowires, the impact of filling fraction on the heat transfer is analyzed. Depending on the filling fraction, it is possible to achieve both types of hyperbolic modes. At 150?nm vacuum gap, the heat transfer between the nanowires with 0.5 filling fraction can be 11 times higher than that between two bulk ITOs. For vacuum gaps less than 150?nm the heat transfer increases as the filling fraction decreases. Results obtained from this study will facilitate applications of ITO nanowires as hyperbolic metamaterials for energy systems.

  13. Metamaterials-based sensor to detect and locate nonlinear elastic sources

    SciTech Connect (OSTI)

    Gliozzi, Antonio S.; Scalerandi, Marco; Miniaci, Marco; Bosia, Federico; Pugno, Nicola M.

    2015-10-19

    In recent years, acoustic metamaterials have attracted increasing scientific interest for very diverse technological applications ranging from sound abatement to ultrasonic imaging, mainly due to their ability to act as band-stop filters. At the same time, the concept of chaotic cavities has been recently proposed as an efficient tool to enhance the quality of nonlinear signal analysis, particularly in the ultrasonic/acoustic case. The goal of the present paper is to merge the two concepts in order to propose a metamaterial-based device that can be used as a natural and selective linear filter for the detection of signals resulting from the propagation of elastic waves in nonlinear materials, e.g., in the presence of damage, and as a detector for the damage itself in time reversal experiments. Numerical simulations demonstrate the feasibility of the approach and the potential of the device in providing improved signal-to-noise ratios and enhanced focusing on the defect locations.

  14. An experimental verification of metamaterial coupled enhanced transmission for antenna applications

    SciTech Connect (OSTI)

    Pushpakaran, Sarin V.; Raj, Rohith K.; Pradeep, Anju; Ouseph, Lindo; Hari, Mridula; Chandroth, Aanandan; Pezholil, Mohanan; Kesavath, Vasudevan

    2014-02-10

    Inspired by the work of Bethe on electromagnetic transmission through subwavelength hole, there has been immense interest on the extraordinary transmission through subwavelength slot/slit on metal plates. The invention of metamaterials has boosted the extra ordinary transmission through subwavelength slots. We examine computationally and experimentally the concept of metamaterial cover using an array of split ring resonators (SRRs), for enhancing the transmission in a stacked dipole antenna working in the S band. The front to back ratio is considerably improved by enhancing the magnetic resonant strength in close proximity of the slit of the upper parasitic dipole. The effect of stacking height of the SRR monolayer on the resonant characteristics of the split ring resonators and its effect on antenna radiation characteristics has been studied.

  15. A 0.14 THz relativistic coaxial overmoded surface wave oscillator with metamaterial slow wave structure

    SciTech Connect (OSTI)

    Guo, Weijie; Wang, Jianguo Chen, Zaigao; Cai, Libing; Wang, Yue; Wang, Guangqiang; Qiao, Hailiang

    2014-12-15

    This paper presents a new kind of device for generating the high power terahertz wave by using a coaxial overmoded surface wave oscillator with metamaterial slow wave structure (SWS). A metallic metamaterial SWS is used to avoid the damage of the device driven by a high-voltage electron beam pulse. The overmoded structure is adopted to make it much easy to fabricate and assemble the whole device. The coaxial structure is used to suppress the mode competition in the overmoded device. Parameters of an electron beam and geometric structure are provided. Particle-in-cell simulation results show that the high power terahertz wave at the frequency of 0.14 THz is generated with the output power 255 MW and conversion efficiency about 21.3%.

  16. Super-Planckian far-zone thermal emission from asymmetric hyperbolic metamaterials

    SciTech Connect (OSTI)

    Nefedov, Igor S.; Melnikov, Leonid A.

    2014-10-20

    We demonstrate the production of strong directive thermal emissions in the far-field zone of asymmetric hyperbolic metamaterials (AHMs), exceeding that predicted by Planck's limit. Asymmetry is inherent to the uniaxial medium, where the optical axis is tilted with respect to medium interfaces. The use of AHMs is shown to enhance the free-space coupling efficiency of thermally radiated waves, resulting in Super-Planckian far-field thermal emission in certain directions. This effect is impossible in usual hyperbolic materials because emission of high density of states (DOS) photons into vacuum with smaller DOS is preserved by the total internal reflection. Different plasmonic metamaterials are proposed for realizing AHM media; the thermal emission from a AHM, based on a grapheme multilayer structure, is presented, as an example.

  17. Investigation of conductor swinging by wind and its application for design of compact transmission line

    SciTech Connect (OSTI)

    Tsujimoto, K.; Fujii, K.; Kubokawa, H.; Okomura, T.; Simojima, K.; Yoshioka, V.

    1982-11-01

    In Japan it has recently become necessary to shorten the interphase spacing in overhead transmission lines because of land limitations and economical considerations. In this connection, the authors have attempted to analyze, in-depth, the possibilities of shortened interphase spacing via conductor swinging caused by wind effects: one of the important factors in the design of more compact overhead lines. This paper describes not only the investigative results of conductor swinging that were obtained both through computer simulation and in 3 years of full scale field line testing, but also design methodology for compact overhead lines based on these results.

  18. Control of strong light-matter coupling using the capacitance of metamaterial nanocavities

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Benz, Alexander; Campione, Salvatore; Klem, John Frederick; Sinclair, Michael B.; Brener, Igal

    2015-01-27

    Metallic nanocavities with deep subwavelength mode volumes can lead to dramatic changes in the behavior of emitters placed in their vicinity. The resulting collocation and interaction often leads to strong coupling. We present for the first time experimental evidence that the Rabi splitting is directly proportional to the electrostatic capacitance associated with the metallic nanocavity. The system analyzed consists of different metamaterial geometries with the same resonance wavelength coupled to intersubband transitions in quantum wells.

  19. In the OSTI Collections: Metamaterials | OSTI, US Dept of Energy Office of

    Office of Scientific and Technical Information (OSTI)

    Scientific and Technical Information Metamaterials Negative refractive index Varying the response to terahertz light Other devices Solving technical problems References Research Organizations Reports available from OSTI's Information Bridge Additional reference Any material's physical properties are determined by what types of atoms it is made of and how those atoms are arranged. In ordinary solid materials, the atoms are arranged in basic, roughly nanometer-size units of a few atoms each,

  20. Tuning gain and bandwidth of traveling wave tubes using metamaterial beam-wave interaction structures

    SciTech Connect (OSTI)

    Lipton, Robert Polizzi, Anthony

    2014-10-14

    We employ metamaterial beam-wave interaction structures for tuning the gain and bandwidth of short traveling wave tubes. The interaction structures are made from metal rings of uniform cross section, which are periodically deployed along the length of the traveling wave tube. The aspect ratio of the ring cross sections is adjusted to control both gain and bandwidth. The frequency of operation is controlled by the filling fraction of the ring cross section with respect to the size of the period cell.

  1. Control of strong light-matter coupling using the capacitance of metamaterial nanocavities

    SciTech Connect (OSTI)

    Benz, Alexander; Campione, Salvatore; Klem, John Frederick; Sinclair, Michael B.; Brener, Igal

    2015-01-27

    Metallic nanocavities with deep subwavelength mode volumes can lead to dramatic changes in the behavior of emitters placed in their vicinity. The resulting collocation and interaction often leads to strong coupling. We present for the first time experimental evidence that the Rabi splitting is directly proportional to the electrostatic capacitance associated with the metallic nanocavity. As a result, the system analyzed consists of different metamaterial geometries with the same resonance wavelength coupled to intersubband transitions in quantum wells.

  2. Method and system for evaluating integrity of adherence of a conductor bond to a mating surface of a substrate

    DOE Patents [OSTI]

    Telschow, Kenneth L.; Siu, Bernard K.

    1996-01-01

    A method of evaluating integrity of adherence of a conductor bond to a substrate includes: a) impinging a plurality of light sources onto a substrate; b) detecting optical reflective signatures emanating from the substrate from the impinged light; c) determining location of a selected conductor bond on the substrate from the detected reflective signatures; d) determining a target site on the selected conductor bond from the detected reflective signatures; e) optically imparting an elastic wave at the target site through the selected conductor bond and into the substrate; f) optically detecting an elastic wave signature emanating from the substrate resulting from the optically imparting step; and g) determining integrity of adherence of the selected conductor bond to the substrate from the detected elastic wave signature emanating from the substrate. A system is disclosed which is capable of conducting the method.

  3. Method and system for evaluating integrity of adherence of a conductor bond to a mating surface of a substrate

    DOE Patents [OSTI]

    Telschow, K.L.; Siu, B.K.

    1996-07-09

    A method of evaluating integrity of adherence of a conductor bond to a substrate includes: (a) impinging a plurality of light sources onto a substrate; (b) detecting optical reflective signatures emanating from the substrate from the impinged light; (c) determining location of a selected conductor bond on the substrate from the detected reflective signatures; (d) determining a target site on the selected conductor bond from the detected reflective signatures; (e) optically imparting an elastic wave at the target site through the selected conductor bond and into the substrate; (f) optically detecting an elastic wave signature emanating from the substrate resulting from the optically imparting step; and (g) determining integrity of adherence of the selected conductor bond to the substrate from the detected elastic wave signature emanating from the substrate. A system is disclosed which is capable of conducting the method. 13 figs.

  4. Amplitude and phase-resolved measurements of optical metamaterials in the mid-infrared by phase matched electro-optic sampling.

    SciTech Connect (OSTI)

    Sinclair, Michael B.; Brener, Igal; Passmore, Brandon Scott; Wendt, Joel Robert; Bender, Daniel A.; Ten Eyck, Gregory A.

    2010-03-01

    We describe a time-domain spectroscopy system in the thermal infrared used for complete transmission and reflection characterization of metamaterials in amplitude and phase. The system uses a triple-output near-infrared ultrafast fiber laser, phase-locked difference frequency generation and phase-matched electro-optic sampling. We will present measurements of several metamaterials designs.

  5. Improving the Transparency of IAEA Safeguards Reporting

    SciTech Connect (OSTI)

    Toomey, Christopher; Hayman, Aaron M.; Wyse, Evan T.; Odlaug, Christopher S.

    2011-07-17

    In 2008, the Standing Advisory Group on Safeguards Implementation (SAGSI) indicated that the International Atomic Energy Agency's (IAEA) Safeguards Implementation Report (SIR) has not kept pace with the evolution of safeguards and provided the IAEA with a set of recommendations for improvement. The SIR is the primary mechanism for providing an overview of safeguards implementation in a given year and reporting on the annual safeguards findings and conclusions drawn by the Secretariat. As the IAEA transitions to State-level safeguards approaches, SIR reporting must adapt to reflect these evolutionary changes. This evolved report will better reflect the IAEA's transition to a more qualitative and information-driven approach, based upon State-as-a-whole considerations. This paper applies SAGSI's recommendations to the development of multiple models for an evolved SIR and finds that an SIR repurposed as a 'safeguards portal' could significantly enhance information delivery, clarity, and transparency. In addition, this paper finds that the 'portal concept' also appears to have value as a standardized information presentation and analysis platform for use by Country Officers, for continuity of knowledge purposes, and the IAEA Secretariat in the safeguards conclusion process. Accompanying this paper is a fully functional prototype of the 'portal' concept, built using commercial software and IAEA Annual Report data.

  6. III-V/Si Wafer Bonding Using Transparent, Conductive Oxide Interlayers...

    Office of Scientific and Technical Information (OSTI)

    III-VSi Wafer Bonding Using Transparent, Conductive Oxide Interlayers; Article No. 263904 Citation Details In-Document Search Title: III-VSi Wafer Bonding Using Transparent, ...

  7. Fabrication of anatase precipitated glass-ceramics possessing high transparency

    SciTech Connect (OSTI)

    Masai, Hirokazu; Toda, Tatsuya; Takahashi, Yoshihiro; Fujiwara, Takumi

    2009-04-13

    Transparent anatase precipitated glass-ceramics were fabricated using ZnO as a component. The particle size of precipitated anatase is several nanometers enough to possess high transparency. The preparation of the Bi-free transparent TiO{sub 2} glass-ceramic was attained by substitution of two different kinds of oxides for bismuth oxide. It is also noteworthy that we have demonstrated the crystallization of metastable anatase in the glass-ceramics as a main phase. The present bulk anatase glass-ceramics will open up an application field for a TiO{sub 2}-containing photocatalyst.

  8. Aluminum Stabilized NbTi Conductor Test Coil Design, Fabrication, and Test Results

    SciTech Connect (OSTI)

    Andreev, N.; Chlachidze, G.; Evbota, D.; Kashikhin, V.S.; Lamm, M.; Makarov, A.; Tartaglia, M.; Nakamoto, T.; Ogitsu, T.; Tanaka, K.; Yamamoto, A.; /KEK, Tsukuba

    2011-09-01

    A new generation of precision muon conversion experiments is planned at both Fermilab and KEK. These experiments will depend upon a complex set of solenoid magnets for the production, momentum selection and transport of a muon beam to a stopping target, and for tracking detector momentum analysis of candidate conversion electrons from the target. Baseline designs for the production and detector solenoids use NbTi cable that is heavily stabilized by an extruded high RRR aluminum jacket. A U.S.-Japan research collaboration has begun whose goal is to advance the development of optimized Al-NbTi conductors, gain experience with the technology of winding coils from this material, and test the conductor performance as modest length samples become available. For this purpose, a 'conductor test' solenoid with three coils was designed and built at Fermilab. A sample of the RIKEN Al-NbTi conductor from KEK was wound into a 'test' coil; this was sandwiched between two 'field' coils wound from doubled SSC cable, to increase the peak field on the RIKEN test coil. All three solenoid coils were epoxy impregnated, and utilized aluminum outer bandage rings to apply preload to the coils when cold. The design and fabrication details, and results of the magnet quench performance tests are presented and discussed.

  9. Mechanically stable, high aspect ratio, multifilar, wound, ribbon-type conductor and method for manufacturing same

    DOE Patents [OSTI]

    Cottingham, James G.

    1987-01-01

    A mechanically stable, wound, multifilar, ribbon-type conductor having a cross-sectional aspect ratio which may be greater than 12:1, comprising a plurality of conductive strands wound to form a flattened helix containing a plastic strip into which the strands have been pressed so as to form a bond between the strip and the strands. The bond mechanically stabilizes the conductor under tension, preventing it from collapsing into a tubular configuration. In preferred embodiments the plastic strip may be polytetrafluoroethylene, and the conductive strands may be formed from a superconductive material. Conductors in accordance with the present invention may be manufactured by winding a plurality of conductive strands around a hollow mandrel; the cross-section of a hollow mandrel; the cross-section of the mandrel continuously varying from substantially circular to a high aspect ratio elipse while maintaining a constant circumference. The wound conductive strands are drawn from the mandrel as a multifilar helix while simultaneously a plastic strip is fed through the hollow mandrel so that it is contained within the helix as it is withdrawn from the mandrel. The helical conductor is then compressed into a ribbon-like form and the strands are bonded to the plastic strip by a combination of heat and pressure.

  10. Mixed ionic-electronic conductor-based radiation detectors and methods of fabrication

    DOE Patents [OSTI]

    Conway, Adam; Beck, Patrick R; Graff, Robert T; Nelson, Art; Nikolic, Rebecca J; Payne, Stephen A; Voss, Lars; Kim, Hadong

    2015-04-07

    A method of fabricating a mixed ionic-electronic conductor (e.g. TlBr)-based radiation detector having halide-treated surfaces and associated methods of fabrication, which controls polarization of the mixed ionic-electronic MIEC material to improve stability and operational lifetime.

  11. Metal-free magnetic conductor substrates for placement-immune antenna assemblies

    DOE Patents [OSTI]

    Eubanks, Travis Wayne; Loui, Hung; McDonald, Jacob Jeremiah

    2015-09-29

    A magnetic conductor substrate produced for mounting to an antenna includes a sheet of dielectric lattice material having a length, a width and a thickness that is less than the length and less than the width. Within the sheet of dielectric lattice material is disposed an array of dielectric elements.

  12. Transparent Metal-Organic Framework/Polymer Mixed Matrix Membranes...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transparent Metal-Organic FrameworkPolymer Mixed Matrix Membranes as Water Vapor Barriers Previous Next List Bae, Youn Jue; Cho, Eun Seon; Qu, Fen; Sun, Daniel T.; Williams, ...

  13. 15.02.10 RH Transparent Catalytic - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transparent Catalytic Nickel Oxide Protecting Films for Photoanodes Sun, K. et al. Stable ... of 15-nm metallic Ni on quartz substrates Reprinted with permission from Sun, K. et al. ...

  14. New report offers best practice for transparent contract language...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Twitter Google + Vimeo Newsletter Signup SlideShare New report offers best practice for transparent contract language of PV O&M agreements HomeNews, News & Events, SolarNew ...

  15. Net Requirements Transparency Process for Slice/Block and Block...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 As part of its Net Requirements Transparency process, on July 31, 2013 BPA published the SliceBlock and Block customers' FY2012 and forecast FY2014 Total Retail Load (TRL) and...

  16. Slip casting nano-particle powders for making transparent ceramics

    DOE Patents [OSTI]

    Kuntz, Joshua D.; Soules, Thomas F.; Landingham, Richard Lee; Hollingsworth, Joel P.

    2011-04-12

    A method of making a transparent ceramic including the steps of providing nano-ceramic powders in a processed or unprocessed form, mixing the powders with de-ionized water, the step of mixing the powders with de-ionized water producing a slurry, sonifing the slurry to completely wet the powder and suspend the powder in the de-ionized water, separating very fine particles from the slurry, molding the slurry, and curing the slurry to produce the transparent ceramic.

  17. Highly Enriched Uranium Transparency Program | National Nuclear Security

    National Nuclear Security Administration (NNSA)

    Administration | (NNSA) Highly Enriched Uranium Transparency Program November 13, 2013 The U.S. National Nuclear Security Administration's (NNSA) Highly Enriched Uranium (HEU) Transparency Program reduces nuclear risk by monitoring the conversion of 500 metric tons (MT) of Russian HEU, enough material for 20,000 nuclear weapons, into low enriched uranium (LEU). This LEU is put into peaceful use in the United States, generating nearly 10% of all U.S. electrical power. The HEU Purchase

  18. Transparent Gold as a Platform for Adsorbed Protein

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Spectroelectrochemistry: Investigation of Cytochrome c and Azurin Transparent Gold as a Platform for Adsorbed Protein Spectroelectrochemistry: Investigation of Cytochrome c and Azurin Authors: Ashur, I., Schulz, O., McIntosh, C. L., Pinkas, I., Ros, R., and Jones, A. K. Title: Transparent Gold as a Platform for Adsorbed Protein Spectroelectrochemistry: Investigation of Cytochrome c and Azurin Source: Langmuir Year: 2012 Volume: 28 Pages: 5861-5871 ABSTRACT: The majority of protein

  19. High Aspect Ratio Metallic Structures for Use as Transparent Electrodes -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Innovation Portal Photovoltaic Solar Photovoltaic Advanced Materials Advanced Materials Find More Like This Return to Search High Aspect Ratio Metallic Structures for Use as Transparent Electrodes Ames Laboratory Contact AMES About This Technology Technology Marketing SummaryMetallic structures that can be used as transparent electrodes or to enhance the performance of solar cells or LEDs.DescriptionEfforts to develop new energy sources and more energy efficient devices has lead to

  20. DOE Policy on NEPA Process Transparency and Openness

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2, 2009 MEMORANDUM FOR HEADS OF D E P A R T M m ELEMENTS FROM: DANIEL B. PONE SUBJECT: NEPA Process Transparency and Openness President Obama's memorandum on "Transparency and Open Government," issued in the very first hours of his presidency on January 2 1,2009, announced his commitment to creating an unprecedented level of openness in Government. The President specifically called on executive agency heads to make information about agency operations and decisions available to the

  1. Precise Application of Transparent Conductive Oxide Coatings for Flat Panel

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Displays and Photovoltaic Cells | Argonne National Laboratory Precise Application of Transparent Conductive Oxide Coatings for Flat Panel Displays and Photovoltaic Cells Technology available for licensing: New transparent conducting oxide (TCO) coatings are deposited using atomic layer deposition (ALD). Provides uniform coating of complex, 3D nanostructures such as electrodes for next-generation PV cells Improved coating precision uses less material and reduces cost PDF icon

  2. Comparison of gold- and graphene-based resonant nanostructures for terahertz metamaterials and an ultrathin graphene-based modulator

    SciTech Connect (OSTI)

    Shen, Nian-Hai; Tassin, Philippe; Koschny, Thomas; Soukoulis, Costas M

    2014-09-01

    Graphene exhibits unique material properties, and in electromagnetic wave technology it raises the prospect of devices miniaturized down to the atomic length scale. Here we study split-ring resonator metamaterials made from graphene and we compare them to gold-based metamaterials. We find that graphene's huge reactive response derived from its large kinetic inductance allows for deeply subwavelength resonances, although its resonance strength is reduced due to higher dissipative loss damping and smaller dipole coupling. Nevertheless, tightly stacked graphene rings may provide for negative permeability and the electric dipole resonance of graphene meta-atoms turns out to be surprisingly strong. Based on these findings, we present a terahertz modulator based on a metamaterial with a multilayer stack of alternating patterned graphene sheets separated by dielectric spacers. Neighboring graphene flakes are biased against each other, resulting in modulation depths of over 75% at a transmission level of around 90%.

  3. Nuclear waste repository transparency technology test bed demonstrations at WIPP

    SciTech Connect (OSTI)

    BETSILL,J. DAVID; ELKINS,NED Z.; WU,CHUAN-FU; MEWHINNEY,JAMES D.; AAMODT,PAUL

    2000-01-27

    Secretary of Energy, Bill Richardson, has stated that one of the nuclear waste legacy issues is ``The challenge of managing the fuel cycle's back end and assuring the safe use of nuclear power.'' Waste management (i.e., the back end) is a domestic and international issue that must be addressed. A key tool in gaining acceptance of nuclear waste repository technologies is transparency. Transparency provides information to outside parties for independent assessment of safety, security, and legitimate use of materials. Transparency is a combination of technologies and processes that apply to all elements of the development, operation, and closure of a repository system. A test bed for nuclear repository transparency technologies has been proposed to develop a broad-based set of concepts and strategies for transparency monitoring of nuclear materials at the back end of the fuel/weapons cycle. WIPP is the world's first complete geologic repository system for nuclear materials at the back end of the cycle. While it is understood that WIPP does not currently require this type of transparency, this repository has been proposed as realistic demonstration site to generate and test ideas, methods, and technologies about what transparency may entail at the back end of the nuclear materials cycle, and which could be applicable to other international repository developments. An integrated set of transparency demonstrations was developed and deployed during the summer, and fall of 1999 as a proof-of-concept of the repository transparency technology concept. These demonstrations also provided valuable experience and insight into the implementation of future transparency technology development and application. These demonstrations included: Container Monitoring Rocky Flats to WIPP; Underground Container Monitoring; Real-Time Radiation and Environmental Monitoring; Integrated level of confidence in the system and information provided. As the world's only operating deep geologic

  4. NEPA Success Stories: Celebrating 40 Years of Transparency and Open Government

    Office of Energy Efficiency and Renewable Energy (EERE)

    NEPA Success Stories: Celebrating 40 Years of Transparency and Open Government, Environmental Law Institute, 2010.

  5. OSTIblog Articles in the metamaterials Topic | OSTI, US Dept of Energy

    Office of Scientific and Technical Information (OSTI)

    Office of Scientific and Technical Information metamaterials Topic OSTI's Amazing Dr. Watson by Kathy Chambers 17 Apr, 2013 in Products and Content 5440 DrWatsonBlog.jpg OSTI's Amazing Dr. Watson Read more about 5440 During the past year, Dr. William N. Watson, physicist, of DOE/OSTI's staff has posted quite a few very interesting white papers in OSTI's monthly Science Showcase on OSTI's Home Page. This quiet, unassuming man crafts prolific papers on popular science topics of interest to the

  6. Replication of patterned thin-film structures for use in plasmonics and metamaterials

    SciTech Connect (OSTI)

    Norris, David J; Han, Sang Eon; Bhan, Aditya; Nagpal, Prashant; Lindquist, Nathan Charles; Oh, Sang-Hyun

    2015-02-03

    The present invention provides templating methods for replicating patterned metal films from a template substrate such as for use in plasmonic devices and metamaterials. Advantageously, the template substrate is reusable and can provide plural copies of the structure of the template substrate. Because high-quality substrates that are inherently smooth and flat are available, patterned metal films in accordance with the present invention can advantageously provide surfaces that replicate the surface characteristics of the template substrate both in the patterned regions and in the unpatterned regions.

  7. Apparatus and method for measuring critical current properties of a coated conductor

    DOE Patents [OSTI]

    Mueller, Fred M.; Haenisch, Jens

    2012-07-24

    The transverse critical-current uniformity in a superconducting tape was determined using a magnetic knife apparatus. A critical current I.sub.c distribution and transverse critical current density J.sub.c distribution in YBCO coated conductors was measured nondestructively with high resolution using a magnetic knife apparatus. The method utilizes the strong depression of J.sub.c in applied magnetic fields. A narrow region of low, including zero, magnetic field in a surrounding higher field is moved transversely across a sample of coated conductor. This reveals the critical current density distribution. A Fourier series inversion process was used to determine the transverse J.sub.c distribution in the sample.

  8. Antiperovskite Li 3 OCl superionic conductor films for solid-state Li-ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lü, Xujie; Howard, John W.; Chen, Aiping; Zhu, Jinlong; Li, Shuai; Wu, Gang; Dowden, Paul; Xu, Hongwu; Zhao, Yusheng; Jia, Quanxi

    2016-02-02

    We prepared antiperovskite Li3OCl superionic conductor films via pulsed laser deposition using a composite target. A significantly enhanced ionic conductivity of 2.0 × 10-4 S cm-1 at room temperature is achieved, and this value is more than two orders of magnitude higher than that of its bulk counterpart. Moreover, the applicability of Li3OCl as a solid electrolyte for Li-ion batteries is demonstrated.

  9. Priority research areas to accelerate the development of practical ultraconductive copper conductors

    SciTech Connect (OSTI)

    Lee, Dominic F.; Burwell, Malcolm; Stillman, H.

    2015-09-01

    This report documents the findings at an Ultraconductive Copper Strategy Meeting held on March 11, 2015 in Washington DC. The aim of this meeting was to bring together researchers of ultraconductive copper in the U.S. to identify and prioritize critical non-proprietary research activities that will enhance the understanding in the material and accelerate its development into practical conductors. Every effort has been made to ensure that the discussion and findings are accurately reported in this document.

  10. Heteroclite electrochemical stability of an I based Li7P2S8I superionic conductor

    SciTech Connect (OSTI)

    Rangasamy, Ezhiylmurugan; Liu, Zengcai; Gobet, Mallory; Pilar, Kartik; Sahu, Gayatri; Greenbaum, Steve; Liang, Chengdu

    2015-01-01

    Stability from Instability: A Li7P2S8I solid state Li-ion conductor derived from -Li3PS4 and LiI demonstrates exceptional electrochemical stability. The oxidation instability of I is subverted nullified via its incorporation into the coordinated structure. The inclusion of I also creates stability with metallic Li anode while simultaneously improving the interfacial kinetics. Low temperature membrane processability enables facile fabrication of dense membranes, making it suitable for industrial adoption.

  11. Particle trap to sheath non-binding contact for a gas-insulated transmission line having a corrugated outer conductor

    DOE Patents [OSTI]

    Fischer, William H.

    1984-04-24

    A non-binding particle trap to outer sheath contact for use in gas insulated transmission lines having a corrugated outer conductor. The non-binding feature of the contact according to the teachings of the invention is accomplished by having a lever arm rotatably attached to a particle trap by a pivot support axis disposed parallel to the direction of travel of the inner conductor/insulator/particle trap assembly.

  12. FEMCAM Analysis of SULTAN Test Results for ITER Nb3SN Cable-conduit Conductors

    SciTech Connect (OSTI)

    Yuhu Zhai, Pierluigi Bruzzone, Ciro Calzolaio

    2013-03-19

    Performance degradation due to filament fracture of Nb3 Sn cable-in-conduit conductors (CICCs) is a critical issue in large-scale magnet designs such as ITER which is currently being constructed in the South of France. The critical current observed in most SULTAN TF CICC samples is significantly lower than expected and the voltage-current characteristic is seen to have a much broader transition from a single strand to the CICC. Moreover, most conductors exhibit the irreversible degradation due to filament fracture and strain relaxation under electromagnetic cyclic loading. With recent success in monitoring thermal strain distribution and its evolution under the electromagnetic cyclic loading from in situ measurement of critical temperature, we apply FEMCAM which includes strand filament breakage and local current sharing effects to SULTAN tested CICCs to study Nb3 Sn strain sensitivity and irreversible performance degradation. FEMCAM combines the thermal bending effect during cool down and the EM bending effect due to locally accumulating Lorentz force during magnet operation. It also includes strand filament fracture and related local current sharing for the calculation of cable n value. In this paper, we model continuous performance degradation under EM cyclic loading based on strain relaxation and the transition broadening upon cyclic loading to the extreme cases seen in SULTAN test data to better quantify conductor performance degradation.

  13. -------------------------------------------------------------------------------- Metamaterial composition comprising frequency-selective-surface resonant element disposed on/in a dielectric flake, methods, and applications

    DOE Patents [OSTI]

    Shelton, David; Boreman, Glenn; D'Archangel, Jeffrey

    2015-11-10

    Infrared metamaterial arrays containing Au elements immersed in a medium of benzocyclobutene (BCB) were fabricated and selectively etched to produce small square flakes with edge dimensions of approximately 20 .mu.m. Two unit-cell designs were fabricated: one employed crossed-dipole elements while the other utilized square-loop elements.

  14. Hyperbolic-metamaterial antennas for broadband enhancement of dipole emission to free space

    SciTech Connect (OSTI)

    Valagiannopoulos, C. A.; Mirmoosa, M. S.; Nefedov, I. S.; Tretyakov, S. A.; Simovski, C. R.

    2014-10-28

    Dipole emitters used in nano optics and nanophotonics (e.g., fluorescent molecules or quantum dots) are weak radiators and thus detecting the radiation of a single emitter gets possible only if it is significantly enhanced. For this enhancement, one often utilizes resonant nanoantennas (Purcell's effect); this method, however, requires the exact knowledge of source location and radiation frequency which constitute a significant drawback. One known possibility for broadband location-insensitive radiation enhancement is to use a layer of the so-called hyperbolic metamaterial. However, the enhanced radiated energy is mainly directed into the volume of the lossy medium, where it is lost to heating. In this work, we suggest specific shapes of macroscopic hyperbolic metamaterial samples to open radiation windows for enhanced radiation to free space. We show that hyperbolic media slabs with properly shaped macroscopic grooves convert the evanescent waves produced by a dipole into waves traveling in free space, which results in the enhancement of useful radiation by one to two orders of magnitude. That level of enhancement of radiation into free-space which is also wideband and of non-resonant nature has not been reported up to now. These results may open possibilities for realization of broadband and directive antennas, where the primary radiators are randomly positioned fluorescent molecules or quantum dots.

  15. Second harmonic generation from metamaterials strongly coupled to intersubband transitions in quantum wells

    SciTech Connect (OSTI)

    Campione, Salvatore; Benz, Alexander; Brener, Igal; Sinclair, Michael B.; Capolino, Filippo

    2014-03-31

    We theoretically analyze the second harmonic generation capacity of two-dimensional periodic metamaterials comprising sub-wavelength resonators strongly coupled to intersubband transitions in quantum wells (QWs) at mid-infrared frequencies. The metamaterial is designed to support a fundamental resonance at ∼30 THz and an orthogonally polarized resonance at the second harmonic frequency (∼60 THz), while the asymmetric quantum well structure is designed to provide a large second order susceptibility. Upon continuous wave illumination at the fundamental frequency we observe second harmonic signals in both the forward and backward directions, with the forward efficiency being larger. We calculate the overall second harmonic conversion efficiency of the forward wave to be ∼1.3 × 10{sup −2} W/W{sup 2}—a remarkably large value, given the deep sub-wavelength dimensions of the QW structure (about 1/15th of the free space wavelength of 10 μm). The results shown in this Letter provide a strategy for designing easily fabricated sources across the entire infrared spectrum through proper choice of QW and resonator designs.

  16. Surface-Plasmon Enhanced Transparent Electrodes in Organic Photovoltaics

    SciTech Connect (OSTI)

    Reilly III, T. H.; van de Lagemaat, J.; Tenent, R. C.; Morfa, A. J.; Rowlen, K. L.

    2008-01-01

    Random silver nanohole films were created through colloidal lithography techniques and metal vapor deposition. The transparent electrodes were characterized by uv-visible spectroscopy and incorporated into an organic solar cell. The test cells were evaluated for solar power-conversion efficiency and incident photon-to-current conversion efficiency. The incident photon-to-current conversion efficiency spectra displayed evidence that a nanohole film with 92 nm diameter holes induces surface-plasmon-enhanced photoconversion. The nanohole silver films demonstrate a promising route to removing the indium tin oxide transparent electrode that is ubiquitous in organic optoelectronics.

  17. Benchmarking and Transparency Policy and Program Impact Evaluation Handbook

    Broader source: Energy.gov [DOE]

    Prepared for by the U.S. Department of Energy, this Handbook provides both a strategic planning framework and standard methodologies to determined the energy and non-energy benefits of benchmarking and transparency policies and programs that recently began to proliferate in jurisdiction across the United States.

  18. Radiation-transparent windows, method for imaging fluid transfers

    DOE Patents [OSTI]

    Shu, Deming; Wang, Jin

    2011-07-26

    A thin, x-ray-transparent window system for environmental chambers involving pneumatic pressures above 40 bar is presented. The window allows for x-ray access to such phenomena as fuel sprays injected into a pressurized chamber that mimics realistic internal combustion engine cylinder operating conditions.

  19. New York City Benchmarking and Transparency Policy Impact Evaluation Report

    Broader source: Energy.gov [DOE]

    Prepared for the U.S. Department of Energy, this Report provides an understanding of both the approach and methodologies used to evaluate the New York City's benchmarking and transparency policy, Local Law 84, and the results of the application of those methodologies to the early period of the policy's implementation.

  20. Methods of fabricating a conductor assembly having a curvilinear arcuate shape

    DOE Patents [OSTI]

    Meinke, Rainer [Melbourne, FL

    2011-08-23

    A method for manufacture of a conductor assembly along a curvilinear axis. The assembly may be of the type which, when conducting current, generates a magnetic field or in which, in the presence of a changing magnetic field, a voltage is induced. In one example, the assembly includes a structure having a curved shape extending along the axis. A surface of the structure is positioned for formation of a channel along the curved shape. The structure is rotated about a second axis. While rotating the structure, a channel is formed in the surface that results in a helical shape in the structure. The channel extends both around and along the first axis.

  1. High current density electropolishing in the preparation of highly smooth substrate tapes for coated conductors

    DOE Patents [OSTI]

    Kreiskott, Sascha; Matias, Vladimir; Arendt, Paul N.; Foltyn, Stephen R.; Bronisz, Lawrence E.

    2009-03-31

    A continuous process of forming a highly smooth surface on a metallic tape by passing a metallic tape having an initial roughness through an acid bath contained within a polishing section of an electropolishing unit over a pre-selected period of time, and, passing a mean surface current density of at least 0.18 amperes per square centimeter through the metallic tape during the period of time the metallic tape is in the acid bath whereby the roughness of the metallic tape is reduced. Such a highly smooth metallic tape can serve as a base substrate in subsequent formation of a superconductive coated conductor.

  2. Influence of superconductor film composition on adhesion strength of coated conductors

    SciTech Connect (OSTI)

    Kesgin, Ibrahim; Khatri, Narayan; Liu, Yuhao; Delgado, Louis; Galstyan, Eduard; Selvamanickam, Venkat

    2015-11-20

    The effect of high temperature superconductor (HTS) film composition on the adhesion strength of rare- earth barium copper oxide coated conductors (CCs) has been studied. It has been found that the mechanical integrity of the superconductor layer is very susceptible to the defects especially those along the ab plane, probably due to the weak interfaces between the defects and the matrix. Gd and Y in the standard composition were substituted with Sm and the number of in-plane defects was drastically reduced. Consequently, a four-fold increase in adhesion or peeling strength in Sm-based CCs was achieved compared to the standard GdYBCO samples.

  3. Text-Alternative Version of TAP Webinar: Measuring the Impact of Benchmarking & Transparency

    Broader source: Energy.gov [DOE]

    Transcript of the June TAP webinar, Measuring the Impact of Benchmarking & Transparency - Methodologies and the NYC Example.

  4. Subaward Reporting For Federal Funding and Transparency Act of 2006 (FFATA)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Subaward Reporting For Federal Funding and Transparency Act of 2006 (FFATA) Subaward Reporting For Federal Funding and Transparency Act of 2006 (FFATA) The Federal Funding and Transparency Act of 2006 (FFATA) requires full disclosure of information on entities which received Federal funding from any Department at a single searchable web site. The purpose of FFATA is to provide total transparency to the public on how appropriated dollars are spent by the Federal

  5. Elastodynamic behavior of the three dimensional layer-by-layer metamaterial structure

    SciTech Connect (OSTI)

    Aravantinos-Zafiris, N.; Sigalas, M. M.; Economou, E. N.

    2014-10-07

    In this work, we numerically investigate for the first time the elastodynamic behavior of a three dimensional layer-by-layer rod structure, which is easy to fabricate and has already proved to be very efficient as a photonic crystal. The Finite Difference Time Domain method was used for the numerical calculations. For the rods, several materials were examined and the effects of all the geometric parameters of the structure were also numerically investigated. Additionally, two modifications of the structure were included in our calculations. The results obtained here (for certain geometric parameters), exhibiting a high ratio of longitudinal over transverse sound velocity and therefore a close approach to ideal pentamode behavior over a frequency range, clearly show that the layer-by-layer rod structure, besides being an efficient photonic crystal, is a very serious contender as an elastodynamic metamaterial.

  6. Quasi-phase-matching of the dual-band nonlinear left-handed metamaterial

    SciTech Connect (OSTI)

    Liu, Yahong Song, Kun; Gu, Shuai; Liu, Zhaojun; Guo, Lei; Zhao, Xiaopeng; Zhou, Xin

    2014-11-17

    We demonstrate a type of nonlinear meta-atom creating a dual-band nonlinear left-handed metamaterial (DNLHM). The DNLHM operates at two distinct left-handed frequency bands where there is an interval of one octave between the two center frequencies. Under the illumination of a high-power signal at the first left-handed frequency band corresponding to fundamental frequency (FF), second-harmonic generation (SHG) is observed at the second left-handed band. This means that our DNLHM supports backward-propagating waves both at FF and second-harmonic (SH) frequency. We also experimentally demonstrate quasi-phase-matching configurations for the backward SHG. This fancy parametric process can significantly transmits the SH generated by an incident FF wave.

  7. Full-wave simulation of a three-dimensional metamaterial prism

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Basilio, Lorena I.; Langston, William L.; Warne, Larry K.; Johnson, William A.; Sinclair, Michael B.

    2015-01-23

    In our article, a negative-index metamaterial prism based on a composite unit cell containing a split-ring resonator and a z-dipole is designed and simulated. The design approach combines simulations of a single unit cell to identify the appropriate cell design (yielding the desired negative-index behavior) together with subcell modeling (which simplifies the mesh representation of the resonator geometry and allows for a larger number of resonator cells to be handled). Furthermore, to describe the methodology used in designing a n = -1 refractive index prism, our results include the effective-medium parameters, the far-field scattered patterns, and the near-zone field distributionsmore » corresponding to a normally incident plane-wave excitation of the prism.« less

  8. All-metal metamaterial slow-wave structure for high-power sources with high efficiency

    SciTech Connect (OSTI)

    Wang, Yanshuai; Duan, Zhaoyun Tang, Xianfeng; Wang, Zhanliang; Zhang, Yabin; Gong, Yubin; Feng, Jinjun

    2015-10-12

    In this paper, we have proposed a metamaterial (MTM) which is suitable for the compact high-power vacuum electron devices. For example, an S-band slow-wave structure (SWS) based on the all-metal MTMs has been studied by both simulation and experiment. The results show that this MTM SWS is very helpful to miniaturize the high-power vacuum electron devices and largely improve the output power and the electronic efficiency. The simulation model of an S-band MTM backward wave oscillator (BWO) is built, and the particle-in-cell simulated results are presented here: a 2.454 GHz signal is generated and its peak output power is 4.0 MW with a higher electronic efficiency of 31.5% relative to the conventional BWOs.

  9. Effective-medium model of wire metamaterials in the problems of radiative heat transfer

    SciTech Connect (OSTI)

    Mirmoosa, M. S. Nefedov, I. S. Simovski, C. R.; Rüting, F.

    2014-06-21

    In the present work, we check the applicability of the effective medium model (EMM) to the problems of radiative heat transfer (RHT) through so-called wire metamaterials (WMMs)—composites comprising parallel arrays of metal nanowires. It is explained why this problem is so important for the development of prospective thermophotovoltaic (TPV) systems. Previous studies of the applicability of EMM for WMMs were targeted by the imaging applications of WMMs. The analogous study referring to the transfer of radiative heat is a separate problem that deserves extended investigations. We show that WMMs with practically realizable design parameters transmit the radiative heat as effectively homogeneous media. Existing EMM is an adequate tool for qualitative prediction of the magnitude of transferred radiative heat and of its effective frequency band.

  10. Coated conductors

    DOE Patents [OSTI]

    Arendt, Paul N.; Foltyn, Stephen R.; Stan, Liliana; Usov, Igor O.; Wang, Haiyan

    2010-06-15

    Articles are provided including a base substrate having a layer of an IBAD oriented material thereon, and, a layer of barium-containing material selected from the group consisting of barium zirconate, barium hafnate, barium titanate, barium strontium titanate, barium dysprosium zirconate, barium neodymium zirconate and barium samarium zirconate, or a cubic metal oxide material selected from the group consisting of rare earth zirconates and rare earth hafnates upon the layer of an IBAD oriented material. Such articles can further include thin films of high temperature superconductive oxides such as YBCO upon the layer of barium-containing material selected from the group consisting of barium zirconate, barium hafnate, barium titanate, barium strontium titanate, barium dysprosium zirconate, barium neodymium zirconate and barium samarium zirconate, or a cubic metal oxide material selected from the group consisting of rare earth zirconates and rare earth hafnates.

  11. A discussion on the interpretation and characterization of metafilms/metasurfaces: the two-dimensional equivalent of metamaterials

    SciTech Connect (OSTI)

    O'hara, John F; Azad, Abul K

    2008-01-01

    A metafilm (also referred to as a metasurface) is the surface equivalent of a metamaterial. More precisely, a metafilm is a surface distribution of suitable chosen electrically small scatterers. Metafilms are becoming popular as an alternative to full three-dimensional metamaterials. Unfortunately, many papers in the literature present incorrect interpretations and mischaracterizations of these metafilms. In fact, some of the characterizations presented in the literature result in non-unique parameters for a uniquely defined metafilm. In this paper we discuss an appropriate interpretation and characterization of metafilms and present a correct manner to characterize a metafilm. Additionally, we illustrate the error that results from an incorrect characterization of metafilms. We present various examples to emphasize these points. Finally we present a retrieval approach for determining the uniquely defined quantities (the electric and magnetic susceptibilities of its constituent scatterers) that characterize a metafilm.

  12. Life cycle cost study for coated conductor manufacture by electron beam and pulsed laser deposition systems

    SciTech Connect (OSTI)

    Chapman, J.N.

    1999-04-14

    The results of this study establish a framework for evaluation of the cost impact of many performance parameters in coated conductor manufacturing systems. Since the cost and concepts are based on early developmental results and engineering judgment, the study should be updated periodically based on latest data to enhance its usefulness. The study should be expanded to include other promising processes under consideration or development for manufacture of coated conductors. Review of this study by as wide a group of experts from industry, national laboratories and universities as possible is desirable to facilitate improving accuracy of the estimates and communication on the issues involved. The results for the case of achieving the $10/kA-m goal at a J{sub c} of 10{sup 5} a/cm{sup 2} applicable to applications requiring a magnetic field perpendicular to the direction of current flow may be viewed as somewhat discouraging. However, there is ample margin for improvement due to continued development and engineering that could enable meeting the goal of $10/kA-m.

  13. Enhancing grain boundary ionic conductivity in mixed ionic–electronic conductors

    SciTech Connect (OSTI)

    Lin, Ye; Fang, Shumin; Su, Dong; Brinkman, Kyle S.; Chen, Fanglin

    2015-04-10

    Mixed ionic–electronic conductors are widely used in devices for energy conversion and storage. Grain boundaries in these materials have nanoscale spatial dimensions, which can generate substantial resistance to ionic transport due to dopant segregation. Here, we report the concept of targeted phase formation in a Ce0.8Gd0.2O2₋δ–CoFe2O4 composite that serves to enhance the grain boundary ionic conductivity. Using transmission electron microscopy and spectroscopy approaches, we probe the grain boundary charge distribution and chemical environments altered by the phase reaction between the two constituents. The formation of an emergent phase successfully avoids segregation of the Gd dopant and depletion of oxygen vacancies at the Ce0.8Gd0.2O2₋δ–Ce0.8Gd0.2O2₋δ grain boundary. This results in superior grain boundary ionic conductivity as demonstrated by the enhanced oxygen permeation flux. Lastly, this work illustrates the control of mesoscale level transport properties in mixed ionic–electronic conductor composites through processing induced modifications of the grain boundary defect distribution.

  14. Magnetization and critical currents of tin-core multifilamentary Nb sub 3 Sn conductors

    SciTech Connect (OSTI)

    Ghosh, A.K.; Suenaga, M.

    1990-01-01

    This paper presents critical current and magnetization data for some multifilamentary Nb{sub 3}Sn wires that have been produced by the internal-tin method. A comparison of magnetization and transport critical current measurements show that filament bridging during heat treatment is a common occurrence leading to effective filament diameters that are sometimes an order of magnitude larger than the geometrical filament size. At present, J{sub c}'s (in the non-copper region) greater than 1300 A/mm{sup 2} at 10T have been achieved in some conductors, which also exhibit high losses. Low losses have only been seen in conductors with a high local ratio of niobium to copper. Also the use of (Nb-1%Ti) alloy instead of pure Nb helps to reduce low field loss and increase high field J{sub c}. Measurements of the temperature dependence of hysteretic loss to 5T indicate that loss decreases linearly with increasing temperature. 22 refs., 6 figs., 2 tabs.

  15. Correlation of anisotropy and directional conduction in β-Li3PS4 fast Li+ conductor

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chen, Yan; Cai, Lu; Liu, Zengcai; dela Cruz, Clarina R.; Liang, Chengdu; An, Ke

    2015-07-06

    Our letter reports the correlation of anisotropy and directional conduction in the fast Li+ conductor β-Li3PS4, one of the low-symmetry crystalline electrolyte candidates. The material has both high conductivity and good stability that serves well for the large-scale energy storage applications of all-solid-state lithium ion batteries. The anisotropic physical properties, demonstrated here by the thermal expansion coefficients, are crucial for compatibility in the solid-state system and battery performance. Neutron and X-ray powder diffraction measurements were done to determine the crystal structure and thermal stability. Moreover, the crystallographic b-axis was revealed as a fast expansion direction, while negligible thermal expansion wasmore » observed along the a-axis around the battery operating temperatures. The anisotropic behavior has its structural origin from the Li+ conduction channels with incomplete Li occupancy and a flexible connection of LiS4 and PS4 tetrahedra within the framework. This indicates a strong correlation in the direction of the ionic transport in the low-symmetry Li+ conductor.« less

  16. The Calculated and Measured Resistance for Splices between Conductors in a MICE Superconducting Coil

    SciTech Connect (OSTI)

    Green, Michael A.; Dietderich, Dan; Higley, Hugh; Pan, Heng; Tam, Darren; Trillaud, Federic; Wang, Li; Wu, Hong; Xu, Feng Yu

    2009-03-19

    The resistance of superconducting joints within MICE coils is an important issue particularly for the coupling coils. The MICE tracker solenoids have only two superconducting joints in the three spectrometer set (end coil 1, the center coil and end coil 2). The AFC magnets may have only a single joint within the coil. The coupling coils may have as many as fifteen joints within the coil, due to relatively short piece lengths of the superconductor. LBNL and ICST looked at three types of coil joints. They are: (1) cold fusion butt joints, (2) side-by-side lap joints, and (3) up-down lap joints. A theoretical calculation of the joint resistance was done at LBNL and checked by ICST. After looking at the theoretical resistance of the three types of joints, it was decided that the cold welded butt joint was not an attractive alternative for joints within a MICE superconducting magnet coil. Side-by-side and up-down lap joints were fabricated at ICST using two types of soft solder between the conductors. These conductor joints were tested at LBNL at liquid helium temperatures over a range of magnetic fields. The joint resistance was compared with the theoretical calculations. Measurements of splice strength were also made at 300 K and 77 K.

  17. Enhancing grain boundary ionic conductivity in mixed ionic–electronic conductors

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lin, Ye; Fang, Shumin; Su, Dong; Brinkman, Kyle S.; Chen, Fanglin

    2015-04-10

    Mixed ionic–electronic conductors are widely used in devices for energy conversion and storage. Grain boundaries in these materials have nanoscale spatial dimensions, which can generate substantial resistance to ionic transport due to dopant segregation. Here, we report the concept of targeted phase formation in a Ce0.8Gd0.2O2₋δ–CoFe2O4 composite that serves to enhance the grain boundary ionic conductivity. Using transmission electron microscopy and spectroscopy approaches, we probe the grain boundary charge distribution and chemical environments altered by the phase reaction between the two constituents. The formation of an emergent phase successfully avoids segregation of the Gd dopant and depletion of oxygen vacanciesmore » at the Ce0.8Gd0.2O2₋δ–Ce0.8Gd0.2O2₋δ grain boundary. This results in superior grain boundary ionic conductivity as demonstrated by the enhanced oxygen permeation flux. Lastly, this work illustrates the control of mesoscale level transport properties in mixed ionic–electronic conductor composites through processing induced modifications of the grain boundary defect distribution.« less

  18. Composition for forming an optically transparent, superhydrophobic coating

    DOE Patents [OSTI]

    Simpson, John T.; Lewis, Linda A.

    2015-12-29

    A composition for producing an optically clear, well bonded superhydrophobic coating includes a plurality of hydrophobic particles comprising an average particle size of about 200 nm or less, a binder at a binder concentration of from about 0.1 wt. % to about 0.5 wt. %, and a solvent. The hydrophobic particles may be present in the composition at a particle concentration of from about 0.1 wt. % to about 1 wt. %. An optically transparent, superhydrophobic surface includes a substrate, a plurality of hydrophobic particles having an average particle size of about 200 nm or less dispersed over the substrate, and a discontinuous binder layer bonding the hydrophobic particles to the substrate, where the hydrophobic particles and the binder layer form an optically transparent, superhydrophobic coating.

  19. 2005 Annual Health Physics Report for HEU Transparency Program

    SciTech Connect (OSTI)

    Radev, R

    2006-04-21

    During the 2005 calendar year, LLNL provided health physics support for the Highly Enriched Uranium Transparency Program (HEU-TP) in external and internal radiation protection and technical expertise into matters related to BDMS radioactive sources and Russian radiation safety regulatory compliance. For the calendar year 2005, there were 161 person-trips that required dose monitoring of the U.S. monitors. Of the 161 person-trips, 149 person-trips were SMVs and 12 person-trips were Transparency Monitoring Office (TMO) trips. Additionally, there were 11 monitoring visits by TMO monitors to facilities other than UEIE and 3 to UEIE itself. There were two monitoring visits (source changes) that were back to back with 16 monitors. Each of these concurring visits were treated as single person-trips for dosimetry purposes. Counted individually, there were 191 individual person-visits in 2005. The LLNL Safety Laboratories Division provided the dosimetry services for the HEU-TP monitors.

  20. Compound transparent ceramics and methods of preparation thereof

    DOE Patents [OSTI]

    Hollingsworth, Joel P.; Kuntz, Joshua D.; Soules, Thomas F.; Landingham, Richard L.

    2012-12-11

    According to one embodiment, a method for forming a composite transparent ceramic preform includes forming a first suspension of oxide particles in a first solvent which includes a first dispersant but does not include a gelling agent, adding the first suspension to a first mold of a desired shape, and uniformly curing the first suspension in the first mold until stable. The method also includes forming a second suspension of oxide particles in a second solvent which includes a second dispersant but does not include a gelling agent, adding the second suspension to the stable first suspension in a second mold of a desired shape encompassing the first suspension and the second suspension, and uniformly curing the second suspension in the second mold until stable. Other methods for forming a composite transparent ceramic preform are also described according to several other embodiments. Structures are also disclosed.

  1. A novel approach to Hugoniot measurements utilizing transparent crystals

    SciTech Connect (OSTI)

    Fratanduono, D. E.; Eggert, J. H.; Akin, M. C.; Chau, R.; Holmes, N. C.

    2013-01-01

    A new absolute equation of state measurement technique is described and demonstrated measuring the shock state and the refractive index of MgO up to 226GPa. This technique utilizes steady shock waves and the high-pressure transparency of MgO under dynamic shock compression and release. Hugoniot measurements performed using this technique are consistent with the previous measurements. A linear dependence of the shocked refractive index and density is observed up to 226GPa, over a magnitude greater in pressure that previous studies. The transparency of MgO along the principal Hugoniot is higher than any other material reported to date. We observe a significant change in the refractive index of MgO as the Hugoniot elastic limit is exceeded due to the transition from uniaxial to hydrostatic strain. Measurements of the elastic-plastic two-wave structure in MgO indicate a nucleation time for plastic deformation.

  2. Benchmarking & Transparency Policy and Program Impact Evaluation Handbook

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    & Transparency Policy and Program Impact Evaluation Handbook May 2015 Prepared for the U.S. Department of Energy by Navigant Consulting, Inc.and Steven Winter Associates, Inc. (This page intentionally left blank) Acknowledgments The authors wish to thank and acknowledge several organizations and individuals for their contributions to this impact evaluation handbook. Thanks are due to the following staff members of New York City's Offce of Long-term Planning and Sustainability and the Seattle

  3. Electromagnetically induced transparency with a partially standing drive field

    SciTech Connect (OSTI)

    Strekalov, Dmitry V.; Matsko, Andrey B.; Yu, Nan

    2007-11-15

    We study electromagnetically induced transparency in a vacuum rubidium atomic cell and show that reflected drive radiation results in the reshaping and shift of dark resonance. We show that those effects are connected with (i) Bragg reflection of the probe radiation in optically thick atomic coherent medium modulated by the standing-wave drive field, as well as with (ii) quantum interference enhanced absorption of the probe radiation in four-level N-configuration formed due to the reflected drive field.

  4. High Aspect Ratio Metallic Structures for Use as Transparent Electrodes -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Innovation Portal Solar Photovoltaic Solar Photovoltaic Find More Like This Return to Search High Aspect Ratio Metallic Structures for Use as Transparent Electrodes Ames Laboratory Contact AMES About This Technology Technology Marketing Summary Polymer-based photovoltaic devices have received intense interest in recent years because of their potential to provide low-cost solar energy conversion, flexibility, manufacturability, and light weight. However, the efficiency of organic solar

  5. Precise Application of Transparent Conductive Oxide Coatings for Flat Panel

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Displays and Photovoltaic Cells - Energy Innovation Portal Solar Photovoltaic Solar Photovoltaic Advanced Materials Advanced Materials Find More Like This Return to Search Precise Application of Transparent Conductive Oxide Coatings for Flat Panel Displays and Photovoltaic Cells Argonne National Laboratory Contact ANL About This Technology <p align="center"> New <em>ALD reaction chamber containing 12-in x 12-in piece of plate glass</em></p> New ALD reaction

  6. Method and apparatus for fabrication of high gradient insulators with parallel surface conductors spaced less than one millimeter apart

    DOE Patents [OSTI]

    Sanders, David M. (Livermore, CA); Decker, Derek E. (Livermore, CA)

    1999-01-01

    Optical patterns and lithographic techniques are used as part of a process to embed parallel and evenly spaced conductors in the non-planar surfaces of an insulator to produce high gradient insulators. The approach extends the size that high gradient insulating structures can be fabricated as well as improves the performance of those insulators by reducing the scale of the alternating parallel lines of insulator and conductor along the surface. This fabrication approach also substantially decreases the cost required to produce high gradient insulators.

  7. Seebeck Effects in N-Type and P-Type Polymers Driven Simultaneously by Surface Polarization and Entropy Differences Based on Conductor/Polymer/Conductor Thin-Film Devices

    SciTech Connect (OSTI)

    Hu, Dehua; Liu, Qing; Tisdale, Jeremy; Lei, Ting; Pei, Jian; Wang, Hsin; Urbas, Augustine; Hu, Bin

    2015-04-15

    This paper reports Seebeck effects driven by both surface polarization difference and entropy difference by using intramolecular charge-transfer states in n-type and p-type conjugated polymers, namely IIDT and IIDDT, based on vertical conductor/polymer/conductor thin-film devices. Large Seebeck coefficients of -898 V/K and 1300 V/K from are observed from n-type IIDT p-type IIDDT, respectively, when the charge-transfer states are generated by a white light illumination of 100 mW/cm2. Simultaneously, electrical conductivities are increased from almost insulating states in dark condition to conducting states under photoexcitation in both n-type IIDT and p-type IIDDT devices. We find that the intramolecular charge-transfer states can largely enhance Seebeck effects in the n-type IIDT and p-type IIDDT devices driven by both surface polarization difference and entropy difference. Furthermore, the Seebeck effects can be shifted between polarization and entropy regimes when electrical conductivities are changed. This reveals a new concept to develop Seebeck effects by controlling polarization and entropy regimes based on charge-transfer states in vertical conductor/polymer/conductor thin-film devices.

  8. Seebeck Effects in N-Type and P-Type Polymers Driven Simultaneously by Surface Polarization and Entropy Differences Based on Conductor/Polymer/Conductor Thin-Film Devices

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hu, Dehua; Liu, Qing; Tisdale, Jeremy; Lei, Ting; Pei, Jian; Wang, Hsin; Urbas, Augustine; Hu, Bin

    2015-04-15

    This paper reports Seebeck effects driven by both surface polarization difference and entropy difference by using intramolecular charge-transfer states in n-type and p-type conjugated polymers, namely IIDT and IIDDT, based on vertical conductor/polymer/conductor thin-film devices. Large Seebeck coefficients of -898 V/K and 1300 V/K from are observed from n-type IIDT p-type IIDDT, respectively, when the charge-transfer states are generated by a white light illumination of 100 mW/cm2. Simultaneously, electrical conductivities are increased from almost insulating states in dark condition to conducting states under photoexcitation in both n-type IIDT and p-type IIDDT devices. We find that the intramolecular charge-transfer states canmore » largely enhance Seebeck effects in the n-type IIDT and p-type IIDDT devices driven by both surface polarization difference and entropy difference. Furthermore, the Seebeck effects can be shifted between polarization and entropy regimes when electrical conductivities are changed. This reveals a new concept to develop Seebeck effects by controlling polarization and entropy regimes based on charge-transfer states in vertical conductor/polymer/conductor thin-film devices.« less

  9. Mechanically stable, high-aspect-ratio, multifilar, wound, ribbon-type conductor and method for manufacturing same

    DOE Patents [OSTI]

    Cottingham, J.G.

    1982-03-15

    A mechanically stable, wound, multifilar, ribbon-type conductor is described having a cross-sectional aspect ratio which may be greater than 12:1, comprising a plurality of conductive strands wound to form a flattened helix containing a plastic strip into which the strands have been pressed so as to form a bond between the strip and the strands. The bond mechanically stabilizes the conductor under tension, preventing it from collapsing into a tubular configuration. In preferred embodiments the plastic strip may be polytetrafluoroethylene, and the conductive strands may be formed from a superconductive material. Conductors in accordance with the present invention may be manufactured by winding a plurality of conductive strands around a hollow mandrel; the cross-section of a hollow mandrel; the cross-section of the mandrel continuously varying from substnatially circular to a high aspect ratio elipse while maintaining a constant circumference. The wound conductive strands are drawn from the mandrel as a multifilar helix while simultaneously a plastic strip is fed through the hollow mandrel so that it is contained within the helix as it is withdrawn from the mandrel. The helical conductor is then compressed into a ribbon-like form and the strands are bonded to the plastic strip by a combination of heat and pressure.

  10. Formation of multiple levels of porous silicon for buried insulators and conductors in silicon device technologies

    DOE Patents [OSTI]

    Blewer, Robert S.; Gullinger, Terry R.; Kelly, Michael J.; Tsao, Sylvia S.

    1991-01-01

    A method of forming a multiple level porous silicon substrate for semiconductor integrated circuits including anodizing non-porous silicon layers of a multi-layer silicon substrate to form multiple levels of porous silicon. At least one porous silicon layer is then oxidized to form an insulating layer and at least one other layer of porous silicon beneath the insulating layer is metallized to form a buried conductive layer. Preferably the insulating layer and conductive layer are separated by an anodization barrier formed of non-porous silicon. By etching through the anodization barrier and subsequently forming a metallized conductive layer, a fully or partially insulated buried conductor may be fabricated under single crystal silicon.

  11. Method of reducing multipole content in a conductor assembly during manufacture

    DOE Patents [OSTI]

    Meinke, Rainer

    2011-08-09

    A method for manufacture of a conductor assembly. The assembly is of the type which, when conducting current, generates a magnetic field or in which, in the presence of a changing magnetic field, a voltage is induced. In an example embodiment one or more first coil rows are formed. The assembly has multiple coil rows about an axis with outer coil rows formed about inner coil rows. A determination is made of deviations from specifications associated with the formed one or more first coil rows. One or more deviations correspond to a magnitude of a multipole field component which departs from a field specification. Based on the deviations, one or more wiring patterns are generated for one or more second coil rows to be formed about the one or more first coil rows. The one or more second coil rows are formed in the assembly. The magnitude of each multipole field component that departs from the field specification is offset.

  12. Method of reducing multipole content in a conductor assembly during manufacture

    DOE Patents [OSTI]

    Meinke, Rainer

    2013-08-20

    A method for manufacture of a conductor assembly. The assembly is of the type which, when conducting current, generates a magnetic field or in which, in the presence of a changing magnetic field, a voltage is induced. In an example embodiment one or more first coil rows are formed. The assembly has multiple coil rows about an axis with outer coil rows formed about inner coil rows. A determination is made of deviations from specifications associated with the formed one or more first coil rows. One or more deviations correspond to a magnitude of a multipole field component which departs from a field specification. Based on the deviations, one or more wiring patterns are generated for one or more second coil rows to be formed about the one or more first coil rows. The one or more second coil rows are formed in the assembly. The magnitude of each multipole field component that departs from the field specification is offset.

  13. Method of reducing multipole content in a conductor assembly during manufacture

    DOE Patents [OSTI]

    Meinke, Rainer

    2016-05-24

    A method for manufacture of a conductor assembly. The assembly is of the type which, when conducting current, generates a magnetic field or in which, in the presence of a changing magnetic field, a voltage is induced. In an example embodiment one or more first coil rows are formed. The assembly has multiple coil rows about an axis with outer coil rows formed about inner coil rows. A determination is made of deviations from specifications associated with the formed one or more first coil rows. One or more deviations correspond to a magnitude of a multipole field component which departs from a field specification. Based on the deviations, one or more wiring patterns are generated for one or more second coil rows to be formed about the one or more first coil rows. The one or more second coil rows are formed in the assembly. The magnitude of each multipole field component that departs from the field specification is offset.

  14. Transparent ceramic photo-optical semiconductor high power switches

    DOE Patents [OSTI]

    Werne, Roger W.; Sullivan, James S.; Landingham, Richard L.

    2016-01-19

    A photoconductive semiconductor switch according to one embodiment includes a structure of sintered nanoparticles of a high band gap material exhibiting a lower electrical resistance when excited by light relative to an electrical resistance thereof when not exposed to the light. A method according to one embodiment includes creating a mixture comprising particles, at least one dopant, and at least one solvent; adding the mixture to a mold; forming a green structure in the mold; and sintering the green structure to form a transparent ceramic. Additional system, methods and products are also presented.

  15. Nuclear transparency from quasielastic 12C(e,e'p)

    SciTech Connect (OSTI)

    D. Rohe; O. Benhar; C.S. Armstrong; R. Asaturyan; O.K. Baker; S. Bueltmann; C. Carasco; D. Day; R. Ent; H.C. Fenker; K. Garrow; A. Gasparian; P. Gueye; M. Hauger; A. Honegger; J. Jourdan; C.E. Keppel; G. Kubon; R. Lindgren; A. Lung; D.J. Mack; J.H. Mitchell; H. Mkrtchyan; D. Mocelj; K. Normand; T. Petitjean; O. Rondon; E. Segbefia; I. Sick; S. Stepanyan; L. Tang; F. Tiefenbacher; W.F. Vulcan; G. Warren; S.A. Wood; L. Yuan; M. Zeier; H. Zhu; B. Zihlmann

    2005-11-01

    We studied the reaction 12C(e,e'p) in quasielastic kinematics at momentum transfers between 0.6 and 1.8 (GeV/c){sup 2} covering the single-particle region. From this the nuclear transparency factors are extracted using two methods. The results are compared to theoretical predictions obtained using a generalization of Glauber theory described in this paper. Furthermore, the momentum distribution in the region of the 1s-state up to momenta of 300 MeV/c is obtained from the data and compared to the Correlated Basis Function theory and the Independent-Particle Shell model.

  16. Rapid process for producing transparent, monolithic porous glass

    DOE Patents [OSTI]

    Coronado, Paul R. (Livermore, CA)

    2006-02-14

    A process for making transparent porous glass monoliths from gels. The glass is produced much faster and in much larger sizes than present technology for making porous glass. The process reduces the cost of making large porous glass monoliths because: 1) the process does not require solvent exchange nor additives to the gel to increase the drying rates, 2) only moderate temperatures and pressures are used so relatively inexpensive equipment is needed, an 3) net-shape glass monoliths are possible using this process. The process depends on the use of temperature to control the partial pressure of the gel solvent in a closed vessel, resulting in controlled shrinking during drying.

  17. Electromagnetically induced transparency with quantized fields in optocavity mechanics

    SciTech Connect (OSTI)

    Huang Sumei; Agarwal, G. S.

    2011-04-15

    We report electromagnetically induced transparency (EIT) using quantized fields in optomechanical systems. The weak probe field is a narrowband squeezed field. We present a homodyne detection of EIT in the output quantum field. We find that the EIT dip exists even though the photon number in the squeezed vacuum is at the single-photon level. The EIT with quantized fields can be seen even at temperatures on the order of 100 mK, thus paving the way for using optomechanical systems as memory elements.

  18. DOE Policy on NEPA Process Transparency and Openness | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Policy on NEPA Process Transparency and Openness DOE Policy on NEPA Process Transparency and Openness Under the new policy, each Program and Field Office (including the National Nuclear Security Administration and the Power Marketing Administrations) will document and post online all categorical exclusion determinations involving classes of actions listed in Appendix B of the Department's NEPA implementing procedures, 10 C.F.R. Part 1021. DOE Policy on NEPA Process Transparency and Openness

  19. Characterization of transparent zinc oxide films prepared by electrochemical reaction

    SciTech Connect (OSTI)

    Izaki, Masanobu; Omi, Takashi

    1997-06-01

    Transparent zinc oxide (ZnO) films have been grown by galvanostatic cathodic deposition onto conductive glasses from a simple aqueous zinc nitrate electrolyte maintained at 335 K. The as-deposited ZnO films were characterized with Fourier transform infrared absorption spectroscopy, x-ray diffraction, scanning electron microscopy, optical transmission and absorption studies, and measurement of sheet resistivity as a function of cathodic current density. The ZnO films prepared had a wurtzite structure and exhibited an optical bandgap energy of 3.3 eV which is characteristic of ZnO. At a low cathodic current density of 0.05 mA/cm{sup 2}, ZnO films with excellent electrical characteristics have been obtained. A 2 {micro}m thick ZnO film with an optical transmittance of 72% was deposited by electrolysis for approximately 20 min at a cathodic current density of 10 mA/cm{sup 2}.

  20. Semi-transparent solar energy thermal storage device

    DOE Patents [OSTI]

    McClelland, John F.

    1985-06-18

    A visually transmitting solar energy absorbing thermal storage module includes a thermal storage liquid containment chamber defined by an interior solar absorber panel, an exterior transparent panel having a heat mirror surface substantially covering the exterior surface thereof and associated top, bottom and side walls, Evaporation of the thermal storage liquid is controlled by a low vapor pressure liquid layer that floats on and seals the top surface of the liquid. Porous filter plugs are placed in filler holes of the module. An algicide and a chelating compound are added to the liquid to control biological and chemical activity while retaining visual clarity. A plurality of modules may be supported in stacked relation by a support frame to form a thermal storage wall structure.

  1. Semi-transparent solar energy thermal storage device

    DOE Patents [OSTI]

    McClelland, John F.

    1986-04-08

    A visually transmitting solar energy absorbing thermal storage module includes a thermal storage liquid containment chamber defined by an interior solar absorber panel, an exterior transparent panel having a heat mirror surface substantially covering the exterior surface thereof and associated top, bottom and side walls. Evaporation of the thermal storage liquid is controlled by a low vapor pressure liquid layer that floats on and seals the top surface of the liquid. Porous filter plugs are placed in filler holes of the module. An algicide and a chelating compound are added to the liquid to control biological and chemical activity while retaining visual clarity. A plurality of modules may be supported in stacked relation by a support frame to form a thermal storage wall structure.

  2. Transparent electrical conducting films by activated reactive evaporation

    DOE Patents [OSTI]

    Bunshah, Rointan; Nath, Prem

    1982-01-01

    Process and apparatus for producing transparent electrical conducting thin films by activated reactive evaporation. Thin films of low melting point metals and alloys, such as indium oxide and indium oxide doped with tin, are produced by physical vapor deposition. The metal or alloy is vaporized by electrical resistance heating in a vacuum chamber, oxygen and an inert gas such as argon are introduced into the chamber, and vapor and gas are ionized by a beam of low energy electrons in a reaction zone between the resistance heater and the substrate. There is a reaction between the ionized oxygen and the metal vapor resulting in the metal oxide which deposits on the substrate as a thin film which is ready for use without requiring post deposition heat treatment.

  3. Electromagnetically induced transparency in paraffin-coated vapor cells

    SciTech Connect (OSTI)

    Klein, M.; Hohensee, M.; Walsworth, R. L. [Harvard-Smithsonian Center for Astrophysics, Cambridge, Massachusetts 02138 (United States); Department of Physics, Harvard University, Cambridge, Massachusetts 02138 (United States); Phillips, D. F. [Harvard-Smithsonian Center for Astrophysics, Cambridge, Massachusetts 02138 (United States)

    2011-01-15

    Antirelaxation coatings in atomic vapor cells allow ground-state coherent spin states to survive many collisions with the cell walls. This reduction in the ground-state decoherence rate gives rise to ultranarrow-bandwidth features in electromagnetically induced transparency (EIT) spectra, which can form the basis of, for example, long-time scale slow and stored light, sensitive magnetometers, and precise frequency standards. Here we study, both experimentally and theoretically, how Zeeman EIT contrast and width in paraffin-coated rubidium vapor cells are determined by cell and laser-beam geometry, laser intensity, and atomic density. Using a picture of Ramsey pulse sequences, where atoms alternately spend ''bright'' and ''dark'' time intervals inside and outside the laser beam, we explain the behavior of EIT features in coated cells, highlighting their unique characteristics and potential applications.

  4. Transparent bulk-size nanocomposites with high inorganic loading

    SciTech Connect (OSTI)

    Chen, Shi; Gaume, Romain

    2015-12-14

    With relatively high nanoparticle loading in polymer matrices, hybrid nanocomposites made by colloidal dispersion routes suffer from severe inhomogeneous agglomeration, a phenomenon that deteriorates light transmission even when the refractive indices of the inorganic and organic phases are closely matched. The dispersion of particles in a matrix is of paramount importance to obtain composites of high optical quality. Here, we describe an innovative, yet straightforward method to fabricate monolithic transparent hybrid nanocomposites with very high particle loading and high refractive index mismatch tolerance between the inorganic and organic constituents. We demonstrate 77% transmission at 800 nm in a 2 mm-thick acrylate polymer nanocomposite containing 61 vol. % CaF{sub 2} nanoparticles. Modeling shows that similar performance could easily be obtained with various inorganic phases relevant to a number of photonic applications.

  5. Optically transparent, scratch-resistant, diamond-like carbon coatings

    DOE Patents [OSTI]

    He, Xiao-Ming; Lee, Deok-Hyung; Nastasi, Michael A.; Walter, Kevin C.; Tuszewski, Michel G.

    2003-06-03

    A plasma-based method for the deposition of diamond-like carbon (DLC) coatings is described. The process uses a radio-frequency inductively coupled discharge to generate a plasma at relatively low gas pressures. The deposition process is environmentally friendly and scaleable to large areas, and components that have geometrically complicated surfaces can be processed. The method has been used to deposit adherent 100-400 nm thick DLC coatings on metals, glass, and polymers. These coatings are between three and four times harder than steel and are therefore scratch resistant, and transparent to visible light. Boron and silicon doping of the DLC coatings have produced coatings having improved optical properties and lower coating stress levels, but with slightly lower hardness.

  6. Hot Superplastic Powder Forging for Transparent nanocrystalline Ceramics

    SciTech Connect (OSTI)

    Cannon, W. Roger

    2006-05-22

    The program explored a completely new, economical method of manufacturing nanocrystalline ceramics, Hot Superplastic Powder Forging (HSPF). The goal of the work was the development of nanocrystalline/low porosity optically transparent zirconia/alumina. The high optical transparency should result from lack of grain boundary scattering since grains will be smaller than one tenth the wavelength of light and from elimination of porosity. An important technological potential for this process is manufacturing of envelopes for high-pressure sodium vapor lamps. The technique for fabricating monolithic nanocrystalline material does not begin with powder whose particle diameter is <100 nm as is commonly done. Instead it begins with powder whose particle diameter is on the order of 10-100 microns but contains nanocrystalline crystallites <<100 nm. Spherical particles are quenched from a melt and heat treated to achieve the desired microstructure. Under a moderate pressure within a die or a mold at temperatures of 1100C to 1300C densification is by plastic flow of superplastic particles. A nanocrystalline microstructure results, though some features are greater than 100nm. It was found, for instance, that in the fully dense Al2O3-ZrO2 eutectic specimens that a bicontinuous microstructure exists containing <100 nm ZrO2 particles in a matrix of Al2O3 grains extending over 1-2 microns. Crystallization, growth, phase development and creep during hot pressing and forging were studied for several compositions and so provided some details on development of polycrystalline microstructure from heating quenched ceramics.

  7. Particle trap to sheath contact for a gas-insulated transmission line having a corrugated outer conductor

    DOE Patents [OSTI]

    Fischer, William H.; Cookson, Alan H.; Yoon, Kue H.

    1984-04-10

    A particle trap to outer elongated conductor or sheath contact for gas-insulated transmission lines. The particle trap to outer sheath contact of the invention is applicable to gas-insulated transmission lines having either corrugated or non-corrugated outer sheaths. The contact of the invention includes an electrical contact disposed on a lever arm which in turn is rotatably disposed on the particle trap and biased in a direction to maintain contact between the electrical contact and the outer sheath.

  8. Optimum coil shape for a given volume of conductor to obtain maximum central field in an air core solenoid

    SciTech Connect (OSTI)

    Hernandez, P.

    1995-02-01

    This paper is an expansion of engineering notes prepared in 1961 to address the question of how to wind circular coils so as to obtain the maximum axial field with the minimum volume of conductor. At the time this was a germain question because of the advent of superconducting wires which were in very limited supply, and the rapid push for generation of very high fields, with little concern for uniformity.

  9. Broad Temperature Pinning Study of 15 mol.% Zr-Added (Gd, Y)-Ba-Cu-O MOCVD Coated Conductors

    SciTech Connect (OSTI)

    Xu, AX; Khatri, N; Liu, YH; Majkic, G; Galstyan, E; Selvamanickam, V; Chen, YM; Lei, CH; Abraimov, D; Hu, XB; Jaroszynski, J; Larbalestier, D

    2015-06-01

    BaZrO3 (BZO) nanocolumns have long been shown to be very effective for raising the pinning force F-p of REBa2Cu3Ox (REBCO, where RE = rare earth) films at high temperatures and recently at low temperatures too. We have successfully incorporated a high density of BZO nanorods into metal organic chemical vapor deposited (MOCVD) REBCO coated conductors via Zr addition. We found that, compared to the 7.5% Zr-added coated conductor, dense BZO nanorod arrays in the 15% Zr-added conductor are effective over the whole temperature range from 77 K down to 4.2 K. We attribute the substantially enhanced J(c) at 30 K to the weak uncorrelated pinning as well as the strong correlated pinning. Meanwhile, by tripling the REBCO layer thickness to similar to 2.8 mu m, the engineering critical current density J(e) at 30 K exceeds J(e) of optimized Nb-Ti wires at 4.2 K.

  10. Microstructure Characteristics of High Lift Factor MOCVD REBCO Coated Conductors With High Zr Content

    SciTech Connect (OSTI)

    Galstyan, E; Gharahcheshmeh, MH; Delgado, L; Xu, AX; Majkic, G; Selvamanickam, V

    2015-06-01

    We report the microstructural characteristics of high levels of Zr-added REBa2Cu3O7-x (RE = Gd, Y rare earth) coated conductors fabricated by Metal Organic Chemical Vapor Deposition (MOCVD). The enhancements of the lift factor defined as a ratio of the in-field (3 T, B parallel to c-axis) critical current density (J(c)) at 30 K and self-field J(c) at 77 K have been achieved for Zr addition levels of 20 and 25 mol% via optimization of deposition parameters. The presence of strong flux pinning is attributed to the aligned nanocolumns of BaZrO3 and nanoprecipitates embedded in REBa2Cu3O7-x matrix with good crystal quality. A high density of BZO nanorods with a typical size 6-8 nm and spacing of 20 nm has been observed. Moreover, the high Zr content was found to induce a high density of intrinsic defects, including stacking faults and dislocations. The correlation between in-field performance along the c-axis and microstructure of (Gd, Y) BCO film with a high level of Zr addition is discussed.

  11. Nuclear qualified in-containment electrical connectors and method of connecting electrical conductors

    DOE Patents [OSTI]

    Powell, J. G.

    1991-01-01

    A nuclear qualified in-containment electrical connection comprises an insulated, sheathed instrument lead having electrical conductors extending from one end thereof to provide two exposed lead wires, a watertight cable having electrical conducting wires therein and extending from one end of the cable to provide two lead wires therefrom, two butt splice connectors each connecting the ends of respective ones of the lead wires from the instrument lead and cable, a length of heat shrinkable plastic tubing positioned over each butt splice connector and an adjacent portion of a respective lead wire from the cable and heat shrunk into position, a length of heat shrinkable plastic tubing on the end portion of the instrument lead adjacent the lead wires therefrom and heat shrunk thereon and a length of outer heat shrinkable plastic tubing extending over the end portion of the instrument lead and the heat shrinkable tubing thereon and over the butt splice connectors and a portion of the cable adjacent the cable lead lines, the outer heat shrinkable tubing being heat shrunk into sealing position on the instrument lead and cable.

  12. Sorted Single-Walled Carbon Nanotube Films for Transparent Electrodes in

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Organic Solar Cells | ANSER Center | Argonne-Northwestern National Laboratory Sorted Single-Walled Carbon Nanotube Films for Transparent Electrodes in Organic Solar Cells Home > Research > ANSER Research Highlights > Sorted Single-Walled Carbon Nanotube Films for Transparent Electrodes in Organic Solar Cells

  13. Fully transparent organic transistors with junction-free metallic network electrodes

    SciTech Connect (OSTI)

    Pei, Ke; Wang, Zongrong; Ren, Xiaochen; Zhang, Zhichao; Peng, Boyu; Chan, Paddy K. L.

    2015-07-20

    We utilize highly transparent, junction-free metal network electrodes to fabricate fully transparent organic field effect transistors (OFETs). The patterned transparent Ag networks are developed by polymer crack template with adjustable line width and density. Sheet resistance of the network is 6.8 Ω/sq and optical transparency in the whole visible range is higher than 80%. The bottom contact OFETs with DNTT active layer and parylene-C dielectric insulator show a maximum field-effect mobility of 0.13 cm{sup 2}/V s (average mobility is 0.12 cm{sup 2}/V s) and on/off ratio is higher than 10{sup 7}. The current OFETs show great potential for applications in the next generation of transparent and flexible electronics.

  14. Near-infrared strong coupling between metamaterials and epsilon-near-zero modes in degenerately doped semiconductor nanolayers

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Campione, Salvatore; Wendt, Joel R.; Keeler, Gordon Arthur; Luk, Ting S.

    2016-01-01

    Epsilon-near-zero (ENZ) modes provide a new path for tailoring light–matter interactions at the nanoscale. In this paper, we analyze a strongly coupled system at near-infrared frequencies comprising plasmonic metamaterial resonators and ENZ modes supported by degenerately doped semiconductor nanolayers. In strongly coupled systems that combine optical cavities and intersubband transitions, the polariton splitting (i.e., the ratio of Rabi frequency to bare cavity frequency) scales with the square root of the wavelength, thus favoring the long-wavelength regime. In contrast, we observe that the polariton splitting in ENZ/metamaterial resonator systems increases linearly with the thickness of the nanolayer supporting the ENZ modes.more » In this work, we employ an indium-tin-oxide nanolayer and observe a large experimental polariton splitting of approximately 30% in the near-infrared. As a result, this approach opens up many promising applications, including nonlinear optical components and tunable optical filters based on controlling the polariton splitting by adjusting the frequency of the ENZ mode.« less

  15. Near-infrared strong coupling between metamaterials and epsilon-near-zero modes in degenerately doped semiconductor nanolayers

    SciTech Connect (OSTI)

    Campione, Salvatore; Wendt, Joel R.; Keeler, Gordon Arthur; Luk, Ting S.

    2016-01-01

    Epsilon-near-zero (ENZ) modes provide a new path for tailoring light–matter interactions at the nanoscale. In this paper, we analyze a strongly coupled system at near-infrared frequencies comprising plasmonic metamaterial resonators and ENZ modes supported by degenerately doped semiconductor nanolayers. In strongly coupled systems that combine optical cavities and intersubband transitions, the polariton splitting (i.e., the ratio of Rabi frequency to bare cavity frequency) scales with the square root of the wavelength, thus favoring the long-wavelength regime. In contrast, we observe that the polariton splitting in ENZ/metamaterial resonator systems increases linearly with the thickness of the nanolayer supporting the ENZ modes. In this work, we employ an indium-tin-oxide nanolayer and observe a large experimental polariton splitting of approximately 30% in the near-infrared. As a result, this approach opens up many promising applications, including nonlinear optical components and tunable optical filters based on controlling the polariton splitting by adjusting the frequency of the ENZ mode.

  16. Processing of transparent polycrystalline AlON:Ce3+ scintillators

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chen, Ching -Fong; Yang, Pin; King, Graham; Tegtmeier, Eric L.

    2015-10-23

    A new polycrystalline ceramic scintillator is reported for potential use in radiation detection and medical imaging applications. The goal was to develop cerium-activated aluminum oxynitride (AlON:Ce3+) ceramics, which can be produced using ceramic processes in comparison to the high-cost, low-yield single-crystal growth technique. A phase pure AlON:Ce3+ powder with cubic symmetry was successfully synthesized at high temperature under a reducing atmosphere to convert Ce4+ to Ce3+ in the solid solution. We explored two different activator concentrations (0.5 and 1.0 mol%). Fully dense and transparent AlON:Ce3+ ceramics were produced by a liquid-phase-assisted pressureless sintering. The crystal field splitting around the Ce3+more » activator in the AlON was comparable to the splitting induced by Br₋ and the Cl₋ ligands, which produced an emission spectrum perfectly matching the maximum quantum efficiency range of the photomultiplier tube for radiation detection. Both optical excitation and radiation ionizations in AlON:Ce3+ were demonstrated. Lastly, challenges and mechanisms related to the radioluminescence efficiency are discussed.« less

  17. High-performance, transparent conducting oxides based on cadmium stannate

    SciTech Connect (OSTI)

    Coutts, T.J.; Wu, X.; Mulligan, W.P.; Webb, J.M.

    1996-06-01

    We discuss the modeling of thin films of transparent conducting oxides and we compare the predictions with the observed properties of cadmium stannate. Thin films of this material were deposited using radio-frequency magnetron sputtering. The Drude free-carrier model is used to model the optical and electrical properties. The model demonstrates the need for high mobilities. The free-carrier absorbance in the visible spectrum is used as a comparative figure-of-merit for cadmium stannate and tin oxide. This shows that free-carrier absorbance is much less in cadmium stannate than in tin oxide. X-ray diffraction shows that annealed films consist of a single-phase spinel structure. The post-deposition annealing sequence is shown to be crucial to forming a single phase, which is vital for optimal optical and electrical properties. The films are typically high mobility (up to 65 cm{sup 2}V{sup -1}s{sup -1}) and have carrier concentrations as high as 10{sup 21} cm{sup -3}. Resistivities are as low as 1.3 10{sup -4} {Omega} cm, the lowest values reported for cadmium stannate. Atomic force microscopy indicates that the root-mean-square surface roughness is approximately {+-}15A. Cadmium stannate etches readily in both hydrofluoric and hydrochloric acid, which is a commanding advantage over tin oxide. 11 refs., 15 figs.

  18. Electromagnetically induced transparency resonances inverted in magnetic field

    SciTech Connect (OSTI)

    Sargsyan, A.; Sarkisyan, D. E-mail: david@ipr.sci.am; Pashayan-Leroy, Y.; Leroy, C.; Cartaleva, S.; Wilson-Gordon, A. D.; Auzinsh, M.

    2015-12-15

    The phenomenon of electromagnetically induced transparency (EIT) is investigated in a Λ-system of the {sup 87}Rb D{sub 1} line in an external transverse magnetic field. Two spectroscopic cells having strongly different values of the relaxation rates γ{sub rel} are used: an Rb cell with antirelaxation coating (L ∼ 1 cm) and an Rb nanometric- thin cell (nanocell) with a thickness of the atomic vapor column L = 795 nm. For the EIT in the nanocell, we have the usual EIT resonances characterized by a reduction in the absorption (dark resonance (DR)), whereas for the EIT in the Rb cell with an antirelaxation coating, the resonances demonstrate an increase in the absorption (bright resonances (BR)). We suppose that such an unusual behavior of the EIT resonances (i.e., the reversal of the sign from DR to BR) is caused by the influence of an alignment process. The influence of alignment strongly depends on the configuration of the coupling and probe frequencies as well as on the configuration of the magnetic field.

  19. Electronic structure of Al-doped ZnO transparent conductive thin films studied by x-ray absorption and emission spectroscopies

    SciTech Connect (OSTI)

    Huang, W. H.; Sun, S. J.; Chiou, J. W.; Chou, H.; Chan, T. S.; Lin, H.-J.; Kumar, Krishna; Guo, J.-H.

    2011-11-15

    This study used O K-, Zn L{sub 3}-, Zn K-, and Al K-edges x-ray absorption near-edge structure (XANES) and O K-edge x-ray emission spectroscopy (XES) measurements to investigate the electronic structure of transparent Al-doped ZnO (AZO) thin film conductors. The samples were prepared on glass substrates at a low temperature near 77 K by using a standard RF sputtering method. High-purity Ne (5N) was used as the sputtering gas. The crystallography of AZO thin films gradually transformed from the ZnO wurtize structure to an amorphous structure during sample deposition, which suggests the suitability to grow on flexible substrates, eliminating the severe degradation due to fragmentation by repeated bending. The O K- and Zn L{sub 3}-edges XANES spectra of AZO thin films revealed a decrease in the number of both O 2p and Zn 3d unoccupied states when the pressure of Ne was increased from 5 to 100 mTorr. In contrast, Al K-edges XANES spectra showed that the number of unoccupied states of Al 3p increased in conjunction with the pressure of Ne, indicating an electron transfer from Al to O atoms, and suggesting that Al doping increases the negative effective charge of oxygen ions. XES and XANES spectra of O 2p states at the O K-edge also revealed that Al doping not only raised the conduction-band-minimum, but also increased the valence-band-maximum and the band-gap. The results indicate that the reduction in conductivity of AZO thin films is due to the generation of ionic characters, the increase in band-gap, and the decrease in density of unoccupied states of oxygen.

  20. Transparent building-integrated PV modules. Phase 1: Comprehensive report

    SciTech Connect (OSTI)

    NONE

    1998-09-28

    This Comprehensive Report encompasses the activities that have been undertaken by Kiss + Cathcart, Architects, in conjunction with Energy Photovoltaics, Incorporated (EPV), to develop a flexible patterning system for thin-film photovoltaic (PV) modules for building applications. There are two basic methods for increasing transparency/light transmission by means of patterning the PV film: widening existing scribe lines, or scribing a second series of lines perpendicular to the first. These methods can yield essentially any degree of light transmission, but both result in visible patterns of light and dark on the panel surface. A third proposed method is to burn a grid of dots through the films, independent of the normal cell scribing. This method has the potential to produce a light-transmitting panel with no visible pattern. Ornamental patterns at larger scales can be created using combinations of these techniques. Kiss + Cathcart, Architects, in conjunction with EPV are currently developing a complementary process for the large-scale lamination of thin-film PVs, which enables building integrated (BIPV) modules to be produced in sizes up to 48 in. x 96 in. Flexible laser patterning will be used for three main purposes, all intended to broaden the appeal of the product to the building sector: To create semitransparent thin-film modules for skylights, and in some applications, for vision glazing.; to create patterns for ornamental effects. This application is similar to fritted glass, which is used for shading, visual screening, graphics, and other purposes; and to allow BIPV modules to be fabricated in various sizes and shapes with maximum control over electrical characteristics.

  1. The new geospatial tools: global transparency enhancing safeguards verification

    SciTech Connect (OSTI)

    Pabian, Frank Vincent

    2010-09-16

    This paper focuses on the importance and potential role of the new, freely available, geospatial tools for enhancing IAEA safeguards and how, together with commercial satellite imagery, they can be used to promote 'all-source synergy'. As additional 'open sources', these new geospatial tools have heralded a new era of 'global transparency' and they can be used to substantially augment existing information-driven safeguards gathering techniques, procedures, and analyses in the remote detection of undeclared facilities, as well as support ongoing monitoring and verification of various treaty (e.g., NPT, FMCT) relevant activities and programs. As an illustration of how these new geospatial tools may be applied, an original exemplar case study provides how it is possible to derive value-added follow-up information on some recent public media reporting of a former clandestine underground plutonium production complex (now being converted to a 'Tourist Attraction' given the site's abandonment by China in the early 1980s). That open source media reporting, when combined with subsequent commentary found in various Internet-based Blogs and Wikis, led to independent verification of the reporting with additional ground truth via 'crowdsourcing' (tourist photos as found on 'social networking' venues like Google Earth's Panoramio layer and Twitter). Confirmation of the precise geospatial location of the site (along with a more complete facility characterization incorporating 3-D Modeling and visualization) was only made possible following the acquisition of higher resolution commercial satellite imagery that could be correlated with the reporting, ground photos, and an interior diagram, through original imagery analysis of the overhead imagery.

  2. Magnetic transparent conducting oxide film and method of making

    DOE Patents [OSTI]

    Windisch, Jr., Charles F.; Exarhos, Gregory J.; Sharma, Shiv K.

    2004-07-13

    Cobalt-nickel oxide films of nominal 100 nm thickness, and resistivity as low as 0.06 .OMEGA..multidot.cm have been deposited by spin-casting from both aqueous and organic precursor solutions followed by annealing at 450.degree. C. in air. Films deposited on sapphire substrates exhibit a refractive index of about 1.7 and are relatively transparent in the wavelength region from 0.6 to 10.0 .mu.m. They are also magnetic. The electrical and spectroscopic properties of the oxides have been studied as a function of x=Co/(Co+Ni) ratio. An increase in film resistivity was found upon substitution of other cations (e.g., Zn.sup.2+, Al.sup.3+) for Ni in the spinel structure. However, some improvement in the mechanical properties of the films resulted. On the other hand, addition of small amounts of Li decreased the resistivity. A combination of XRD, XPS, UV/Vis and Raman spectroscopy indicated that NiCo.sub.2 O.sub.4 is the primary conducting component and that the conductivity reaches a maximum at this stoichiometry. When x<0.67, NiO forms leading to an increase in resistivity; when x>0.67, the oxide was all spinel but the increased Co content lowered the conductivity. The influence of cation charge state and site occupancy in the spinel structure markedly affects calculated electron band structures and contributes to a reduction of p-type conductivity, the formation of polarons, and the reduction in population of mobile charge carriers that tend to limit transmission in the infrared.

  3. GC Commits to Transparency on Nuclear Waste Fund Fee Adequacy Decisions

    Broader source: Energy.gov [DOE]

    Consistent with the Administration's commitment to transparency, DOE General Counsel Scott Blake Harris has decided that all future determinations as to the adequacy of the Nuclear Waste Fund fee...

  4. Evidence for the onset of color transparency in ρ0 electroproduction off nuclei

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Guo, L.; Hanretty, C.; Hicks, K.; Holt, R. J.; Hyde, C. E.; Ilieva, Y.; Ireland, D. G.; Ishkhanov, B. S.; Isupov, E. L.; Jawalker, S. S.; et al

    2012-05-11

    We have measured the nuclear transparency of the incoherent diffractive A(e,e'ρ0) process in 12C and 56Fe targets relative to 2H using a 5 GeV electron beam. The nuclear transparency, the ratio of the produced {rho}{sup 0}'s on a nucleus relative to deuterium, which is sensitive to ρA interaction, was studied as function of the coherence length (Ic), a lifetime of the hadronic fluctuation of the virtual photon, and the four-momentum transfer squared (Q2). Thus, while the transparency for both 12C and 56Fe showed no Ic dependence, a significant Q2 dependence was measured, which is consistent with calculations that included themore » color transparency effects.« less

  5. The Use of Large Transparent Ceramics in a High Powered, Diode...

    Office of Scientific and Technical Information (OSTI)

    Pumped Solid State Laser Citation Details In-Document Search Title: The Use of Large Transparent Ceramics in a High Powered, Diode Pumped Solid State Laser You are accessing ...

  6. Evidence for the onset of color transparency in ρ0 electroproduction off nuclei

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Guo, L.; Hanretty, C.; Hicks, K.; Holt, R. J.; Hyde, C. E.; Ilieva, Y.; Ireland, D. G.; Ishkhanov, B. S.; Isupov, E. L.; Jawalker, S. S.; et al

    2012-05-11

    We have measured the nuclear transparency of the incoherent diffractive A(e,e'ρ0) process in 12C and 56Fe targets relative to 2H using a 5 GeV electron beam. The nuclear transparency, the ratio of the produced {rho}{sup 0}'s on a nucleus relative to deuterium, which is sensitive to ρA interaction, was studied as function of the coherence length (Ic), a lifetime of the hadronic fluctuation of the virtual photon, and the four-momentum transfer squared (Q2). Thus, while the transparency for both 12C and 56Fe showed no Ic dependence, a significant Q2 dependence was measured, which is consistent with calculations that included themore »color transparency effects.« less

  7. Low-Cost, Haziness-Free, Transparent Insulation Based On a Porous Silica

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Material | Department of Energy Haziness-Free, Transparent Insulation Based On a Porous Silica Material Low-Cost, Haziness-Free, Transparent Insulation Based On a Porous Silica Material Image of porous silica material in alcohol.<br /> Photo credit: Oak Ridge National Lab Image of porous silica material in alcohol. Photo credit: Oak Ridge National Lab Lead Performer: Oak Ridge National Laboratory - Oak Ridge, TN Partner: VELUX Design and Development Company USA Inc., Greenwood, SC DOE

  8. Method for producing high carrier concentration p-Type transparent conducting oxides

    DOE Patents [OSTI]

    Li, Xiaonan; Yan, Yanfa; Coutts, Timothy J.; Gessert, Timothy A.; Dehart, Clay M.

    2009-04-14

    A method for producing transparent p-type conducting oxide films without co-doping plasma enhancement or high temperature comprising: a) introducing a dialkyl metal at ambient temperature and a saturated pressure in a carrier gas into a low pressure deposition chamber, and b) introducing NO alone or with an oxidizer into the chamber under an environment sufficient to produce a metal-rich condition to enable NO decomposition and atomic nitrogen incorporation into the formed transparent metal conducting oxide.

  9. Designing optical metamaterial with hyperbolic dispersion based on Al:ZnO/ZnO nano-layered structure using Atomic Layer Deposition technique

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kelly, Priscilla; Liu, Mingzhao; Kuznetsova, Lyuba

    2016-04-07

    In this study, nano-layered Al:ZnO/ZnO hyperbolic dispersion metamaterial with a large number of layers was fabricated using the atomic layer deposition (ALD) technique. Experimental dielectric functions for Al:ZnO/ZnO structures are obtained by an ellipsometry technique in the visible and near-infrared spectral ranges. The theoretical modeling of the Al:ZnO/ZnO dielectric permittivity is done using effective medium approximation. A method for analysis of spectroscopic ellipsometry data is demonstrated to extract the optical permittivity for this highly anisotropic nano-layered metamaterial. The results of the ellipsometry analysis show that Al:ZnO/ZnO structures with a 1:9 ALD cycle ratio exhibit hyperbolic dispersion transition change near 1.8more » μm wavelength.« less

  10. Fabrication of Transparent Capacitive Structure by Self-Assembled Thin Films

    SciTech Connect (OSTI)

    Zhang, Q.; Shing, Y. J.; Hua, Feng; Saraf, Laxmikant V.; Matson, Dean W.

    2008-06-01

    An approach to fabricating transparent electronic devices by using nanomaterial and nanofabrication is presented in this paper. A see-through capacitor is constructed from selfassembled silica nanoparticle layers that are stacked on the transparent substrate. The electrodes are made of indium tin oxide. Unlike the traditional processes used to fabricate such devices, the self-assembly approach enables one to synthesize the thin film layers at lower temperature and cost, and with a broader availability of nanomaterials. The vertical dimension of the selfassembled thin films can be precisely controlled, as well as the molecular order in the thin film layers. The shape of the capacitor is generated by planar micropatterning. The quartz crystal demonstrates the steady growth of the silica nanoparticle multilayer. In addition, because the nanomaterial synthesis and the device fabrication steps are separate, the device is not affected by the harsh conditions required for the material synthesis. A clear pattern is allowed over a large area on the substrate. The prepared capacitive structure has an optical transparency higher than 92% over the visible spectrum. The capacitive impedance is measured at different frequencies and fit the theoretical results. As one of the fundamental components, this type of capacitive structure can serve in the transparent circuits, interactive media and sensors, as well as being applicable to other transparent devices.

  11. Method for sputtering a PIN amorphous silicon semi-conductor device having partially crystallized P and N-layers

    DOE Patents [OSTI]

    Moustakas, Theodore D.; Maruska, H. Paul

    1985-07-09

    A high efficiency amorphous silicon PIN semiconductor device having partially crystallized (microcrystalline) P and N layers is constructed by the sequential sputtering of N, I and P layers and at least one semi-transparent ohmic electrode. The method of construction produces a PIN device, exhibiting enhanced electrical and optical properties, improved physical integrity, and facilitates the preparation in a singular vacuum system and vacuum pump down procedure.

  12. Characterization of a high-temperature superconducting conductor on round core cables in magnetic fields up to 20 T

    SciTech Connect (OSTI)

    van der Laan, D. C.; Noyes, P. D.; Miller, G. E.; Weijers, H. W.; Willering, G. P.

    2013-02-13

    The next generation of high-ï¬eld magnets that will operate at magnetic ï¬elds substantially above 20 T, or at temperatures substantially above 4.2 K, requires high-temperature superconductors (HTS). Conductor on round core (CORC) cables, in which RE-Ba{sub 2}Cu{sub 3}O{sub 7-{delta}} (RE = rare earth) (REBCO) coated conductors are wound in a helical fashion on a flexible core, are a practical and versatile HTS cable option for low-inductance, high-field magnets. We performed the first tests of CORC magnet cables in liquid helium in magnetic fields of up to 20 T. A record critical current I{sub c} of 5021 A was measured at 4.2 K and 19 T. In a cable with an outer diameter of 7.5 mm, this value corresponds to an engineering current density J{sub e} of 114 A mm{sup -2} , the highest J{sub e} ever reported for a superconducting cable at such high magnetic fields. Additionally, the first magnet wound from an HTS cable was constructed from a 6 m-long CORC cable. The 12-turn, double-layer magnet had an inner diameter of 9 cm and was tested in a magnetic field of 20 T, at which it had an I{sub c} of 1966 A. The cables were quenched repetitively without degradation during the measurements, demonstrating the feasibility of HTS CORC cables for use in high-field magnet applications.

  13. Transparent, near-infrared organic photovoltaic solar cells for window and energy-scavenging applications

    SciTech Connect (OSTI)

    Lunt, Richard R; Bulovic, Vladimir

    2011-03-14

    We fabricate near-infrared absorbing organic photovoltaics that are highly transparent to visible light. By optimizing near-infrared optical-interference, we demonstrate power efficiencies of 1.3±0.1% with simultaneous average visible transmission of >65% . Subsequent incorporation of near-infrared distributed-Bragg-reflector mirrors leads to an increase in the efficiency to 1.7±0.1% , approaching the 2.4±0.2% efficiency of the opaque cell, while maintaining high visible-transparency of >55% . Finally, we demonstrate that a series-integrated array of these transparent cells is capable of powering electronic devices under near-ambient lighting. This architecture suggests strategies for high-efficiency power-generating windows and highlights an application uniquely benefiting from excitonic electronics.

  14. Portable NDA Equipment for Enrichment Measurements in the HEU Transparency Program

    SciTech Connect (OSTI)

    Decman, D J; Bandong, B B; Wong, J L; Valentine, J D; Luke, S J

    2008-06-02

    The Highly Enriched Uranium (HEU) Transparency Program has used portable nondestructive assay (NDA) equipment to measure the {sup 235}U enrichment of material subject to the transparency agreement since 1997. The equipment is based on the 'enrichment meter' method and uses low-resolution sodium iodide (NaI(Tl)) detectors. Although systems using high-purity germanium (HPGe) detectors can produce more accurate results we have found that the results with NaI(Tl) detectors are quite adequate for the requirements of the transparency agreement. This paper will describe the details of the equipment's operation, calibration, testing, and deployment in Russia. We will also provide a comparison of the units originally deployed in 1997 with the upgraded systems that were deployed in 2003.

  15. Semi-transparent perovskite solar cells for tandems with silicon and CIGS

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bailie, Colin D.; Christoforo, M. Greyson; Mailoa, Jonathan P.; Bowring, Andrea R.; Unger, Eva L.; Nguyen, William H.; Burschka, Julian; Pellet, Norman; Lee, Jungwoo Z.; Grätzel, Michael; et al

    2014-12-23

    A promising approach for upgrading the performance of an established low-bandgap solar technology without adding much cost is to deposit a high bandgap polycrystalline semiconductor on top to make a tandem solar cell. We use a transparent silver nanowire electrode on perovskite solar cells to achieve a semi-transparent device. We place the semi-transparent cell in a mechanically-stacked tandem configuration onto copper indium gallium diselenide (CIGS) and low-quality multicrystalline silicon (Si) to achieve solid-state polycrystalline tandem solar cells with a net improvement in efficiency over the bottom cell alone. Furthermore, this work paves the way for integrating perovskites into a low-costmore » and high-efficiency (>25%) tandem cell.« less

  16. Transparent ultralow-density silica aerogels prepared by a two-step sol-gel process

    SciTech Connect (OSTI)

    Tillotson, T.M.; Hrubesh, L.W.

    1991-09-01

    Conventional silica sol-gel chemistry is limited for the production of transparent ultralow-density aerogels because (1) gelation is either slow or unachievable, and (2) even when gelation is achieved, the large pore sizes result in loss of transparency for aerogels <.020 g/cc. We have developed a two-step sol-gel process that circumvents the limitations of the conventional process and allows the formation of ultralow-density gels in a matter of hours. we have found that the gel time is dependent on the catalyst concentration. After supercritical extraction, the aerogels are transparent, uncracked tiles with densities as low as .003 g/cc. 6 figs., 11 refs.

  17. Atomic-Layer-Deposited Transparent Electrodes for Silicon Heterojunction Solar Cells

    SciTech Connect (OSTI)

    Demaurex, Benedicte; Seif, Johannes P.; Smit, Sjoerd; Macco, Bart; Kessels, W. M.; Geissbuhler, Jonas; De Wolf, Stefaan; Ballif, Christophe

    2014-11-01

    We examine damage-free transparent-electrode deposition to fabricate high-efficiency amorphous silicon/crystalline silicon heterojunction solar cells. Such solar cells usually feature sputtered transparent electrodes, the deposition of which may damage the layers underneath. Using atomic layer deposition, we insert thin protective films between the amorphous silicon layers and sputtered contacts and investigate their effect on device operation. We find that a 20-nm-thick protective layer suffices to preserve, unchanged, the amorphous silicon layers beneath. Insertion of such protective atomic-layer-deposited layers yields slightly higher internal voltages at low carrier injection levels. However, we identify the presence of a silicon oxide layer, formed during processing, between the amorphous silicon and the atomic-layer-deposited transparent electrode that acts as a barrier, impeding hole and electron collection.

  18. Spray-on anti-soiling coatings that exhibit high transparency and mechanical durability

    SciTech Connect (OSTI)

    Schaeffer, Daniel A; Polyzos, Georgios; Smith, Barton; Lee, Dominic F; Rajic, Slobodan; Datskos, Panos G; Hunter, Scott Robert

    2014-01-01

    A superhydrophobic (SH) surface has many characteristics, one of which is its self-cleaning, anti-soiling functionality, that are desirable across various industries. A transparent, self-cleaning surface utilizes the right combination of surface chemistry and roughness that force water droplets to form high water contact angles (CA). This in turn allows droplets to easily roll off and pick up dirt and debris across the surface. In theory this is simple but in practice this can be very difficult as superhydrophobicity and optical transparency are competitive. We have developed a simple, spray-on coating based on functionalized SiO2 nanoparticles that can easily be applied to surfaces whose application requires high transparency including, but not limited to, optical sensors, photovoltaics, sights, and lenses. In addition, these coatings exhibit practical mechanical and environmental durability that allow prolonged use of the coatings in harsh environments.

  19. Atomic-Layer-Deposited Transparent Electrodes for Silicon Heterojunction Solar Cells

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Demaurex, Benedicte; Seif, Johannes P.; Smit, Sjoerd; Macco, Bart; Kessels, W. M.; Geissbuhler, Jonas; De Wolf, Stefaan; Ballif, Christophe

    2014-11-01

    We examine damage-free transparent-electrode deposition to fabricate high-efficiency amorphous silicon/crystalline silicon heterojunction solar cells. Such solar cells usually feature sputtered transparent electrodes, the deposition of which may damage the layers underneath. Using atomic layer deposition, we insert thin protective films between the amorphous silicon layers and sputtered contacts and investigate their effect on device operation. We find that a 20-nm-thick protective layer suffices to preserve, unchanged, the amorphous silicon layers beneath. Insertion of such protective atomic-layer-deposited layers yields slightly higher internal voltages at low carrier injection levels. However, we identify the presence of a silicon oxide layer, formed during processing,more » between the amorphous silicon and the atomic-layer-deposited transparent electrode that acts as a barrier, impeding hole and electron collection.« less

  20. Proposal for broader United States-Russian transparency of nuclear arms reductions

    SciTech Connect (OSTI)

    Percival, C.M.; Ingle, T.H.; Bieniawski, A.J.

    1995-07-01

    During the January 1994 Summit Presidents Clinton and Yeltsin agreed on the goal of ensuring the ``transparency and irreversibility`` of the nuclear arms reduction process. As a result, negotiations are presently underway between the United States Government and the Russian Federation to confirm the stockpiles of plutonium and highly enriched uranium removed from nuclear weapons. In December 1994 the United States presented a paper to the Russian Federation proposing additional measures to provide broader transparency of nuclear arms reduction. The US Department of Energy is studying the implementation of these broader transparency measures at appropriate DOE facilities. The results of the studies include draft protocols for implementation, assessments of the implementation procedures and the impacts on the facilities and estimates of the cost to implement these measures at various facilities.

  1. Semi-transparent perovskite solar cells for tandems with silicon and CIGS

    SciTech Connect (OSTI)

    Bailie, Colin D.; Christoforo, M. Greyson; Mailoa, Jonathan P.; Bowring, Andrea R.; Unger, Eva L.; Nguyen, William H.; Burschka, Julian; Pellet, Norman; Lee, Jungwoo Z.; Grätzel, Michael; Noufi, Rommel; Buonassisi, Tonio; Salleo, Alberto; McGehee, Michael D.

    2014-12-23

    A promising approach for upgrading the performance of an established low-bandgap solar technology without adding much cost is to deposit a high bandgap polycrystalline semiconductor on top to make a tandem solar cell. We use a transparent silver nanowire electrode on perovskite solar cells to achieve a semi-transparent device. We place the semi-transparent cell in a mechanically-stacked tandem configuration onto copper indium gallium diselenide (CIGS) and low-quality multicrystalline silicon (Si) to achieve solid-state polycrystalline tandem solar cells with a net improvement in efficiency over the bottom cell alone. Furthermore, this work paves the way for integrating perovskites into a low-cost and high-efficiency (>25%) tandem cell.

  2. Performance of Europium-Doped Strontium Iodide, Transparent Ceramics and Bismuth-loaded Polymer Scintillators

    SciTech Connect (OSTI)

    Cherepy, Nerine; Payne, Stephen A.; Sturm, Benjamin; ONeal, S P; Seeley, Zachary; Drury, Owen; Haselhorst, L K; Rupert, B. L.; Sanner, Robert; Thelin, P; Fisher, S E; Hawrami, Rastgo; Shah, Kanai; Burger, Arnold; Ramey, Joanne Oxendine; Boatner, Lynn A

    2011-01-01

    Recently discovered scintillators for gamma ray spectroscopy, single crystal SrI2(Eu), GYGAG(Ce) transparent ceramic and Bismuth-loaded plastics offer resolution and fabrication advantages compared to commercial scintillators, such as NaI(Tl) and standard PVT plastic. Energy resolution at 662 keV of 2.7% is obtained with SrI2(Eu), while 4.5% is obtained with GYGAG(Ce). A new transparent ceramic scintillator for radiographic imaging systems, GLO(Eu) offers high light yield of ~75,000 Ph/MeV, high stopping, and low radiation damage. Implementation of single crystal SrI2(Eu), Gd-based transparent ceramics, and Bi-loaded plastic scintillators can advance the state-of-the art in ionizing radiation detection systems.

  3. Performance of Europium-Doped Strontium Iodide, Transparent Ceramics and Bismuth-loaded Polymer Scintillators

    SciTech Connect (OSTI)

    Cherepy, N J; Payne, S A; Sturm, B W; O'Neal, S P; Seeley, Z M; Drury, O B; Haselhorst, L K; Rupert, B L; Sanner, R D; Thelin, P A; Fisher, S E; Hawrami, R; Shah, K S; Burger, A; Ramey, J O; Boatner, L A

    2011-08-30

    Recently discovered scintillators for gamma ray spectroscopy, single crystal SrI{sub 2}(Eu), GYGAG(Ce) transparent ceramic and Bismuth-loaded plastics, offer resolution and fabrication advantages compared to commercial scintillators, such as NaI(Tl) and standard PVT plastic. Energy resolution at 662 keV of 2.7% is obtained with SrI{sub 2}(Eu), while 4.5% is obtained with GYGAG(Ce). A new transparent ceramic scintillator for radiographic imaging systems, GLO(Eu) offers high light yield of 70,000 Photons/MeV, high stopping, and low radiation damage. Implementation of single crystal SrI{sub 2}(Eu), Gd-based transparent ceramics, and Bi-loaded plastic scintillators can advance the state-of-the art in ionizing radiation detection systems.

  4. Electronic Durability of Flexible Transparent Films from Type-Specific Single-Wall Carbon Nanotubes

    SciTech Connect (OSTI)

    Harris, J; Iyer, S; Bernhardt, A; Huh, JY; Hudson, S; Fagan, J; Hobbie, E.

    2011-12-11

    The coupling between mechanical flexibility and electronic performance is evaluated for thin films of metallic and semiconducting single-wall carbon nanotubes (SWCNTs) deposited on compliant supports. Percolated networks of type-purified SWCNTs are assembled as thin conducting coatings on elastic polymer substrates, and the sheet resistance is measured as a function of compression and cyclic strain through impedance spectroscopy. The wrinkling topography, microstructure and transparency of the films are independently characterized using optical microscopy, electron microscopy, and optical absorption spectroscopy. Thin films made from metallic SWCNTs show better durability as flexible transparent conductive coatings, which we attribute to a combination of superior mechanical performance and higher interfacial conductivity.

  5. Three-terminal resistive switching memory in a transparent vertical-configuration device

    SciTech Connect (OSTI)

    Ungureanu, Mariana; Llopis, Roger; Casanova, Fèlix; Hueso, Luis E.

    2014-01-06

    The resistive switching phenomenon has attracted much attention recently for memory applications. It describes the reversible change in the resistance of a dielectric between two non-volatile states by the application of electrical pulses. Typical resistive switching memories are two-terminal devices formed by an oxide layer placed between two metal electrodes. Here, we report on the fabrication and operation of a three-terminal resistive switching memory that works as a reconfigurable logic component and offers an increased logic density on chip. The three-terminal memory device we present is transparent and could be further incorporated in transparent computing electronic technologies.

  6. Optical properties of transparent glassceramics containing lithiummica nanocrystals: Crystallization effect

    SciTech Connect (OSTI)

    Khani, V.; Alizadeh, P.; Shakeri, M.S.

    2013-09-01

    Graphical abstract: Optical properties of transparent Li{sub 2}OMgOAl{sub 2}O{sub 3}SiO{sub 2}F glasses containing lithiummica nanocrystals are studied and crystallization condition has been evaluated and optimized to produce transparent glassceramics. Crystallization temperatures were determined by differential thermal analysis and crystalline phases were identified and quantified by X-ray diffraction. Scanning electron microscopy was used for morphological variations and UVvis absorption spectroscopy for comparative analysis of transparency. In order to investigate the optical properties of transparent glassceramics, optical band gap, Fermi energy level and Urbach energy are calculated. The results of the investigation illustrate that band gap is reduced with increases in crystallization time and temperature. Enhanced orderliness in the arrangement of atoms might be regarded as possible reasons for the above changes. - Highlights: The optimum temperature and time of crystallization were determined. Limica nanocrystals with size of <30 nm were formed using a two-step heat-treatment. Optical band gap and Fermi energy of nanocrystalline materials decreased with increasing of crystallization temperature and time. Urbach band tailing was decreased with increasing of crystallization condition. - Abstract: Optical properties of transparent Li{sub 2}OMgOAl{sub 2}O{sub 3}SiO{sub 2}F glasses containing lithiummica nanocrystals were studied. The crystallization condition of these glasses was evaluated and optimized to produce transparent glassceramics. Crystallization temperatures were determined by differential thermal analysis and crystalline phases were identified and quantified by X-ray diffraction. Scanning electron microscopy was used to detect morphological changes and UVvis absorption spectroscopy was used for comparative analysis of transparency. In order to investigate the optical properties of the transparent glassceramics, optical band

  7. Disorder-induced transparency in a one-dimensional waveguide side coupled with optical cavities

    SciTech Connect (OSTI)

    Zhang, Yongyou Dong, Guangda; Zou, Bingsuo

    2014-05-07

    Disorder influence on photon transmission behavior is theoretically studied in a one-dimensional waveguide side coupled with a series of optical cavities. For this sake, we propose a concept of disorder-induced transparency appearing on the low-transmission spectral background. Two kinds of disorders, namely, disorders of optical cavity eigenfrequencies and relative phases in the waveguide side coupled with optical cavities are considered to show the disorder-induced transparency. They both can induce the optical transmission peaks on the low-transmission backgrounds. The statistical mean value of the transmission also increases with increasing the disorders of the cavity eigenfrequencies and relative phases.

  8. Development of epitaxial AlxSc1-xN for artificially structured metal/semiconductor superlattice metamaterials

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sands, Timothy D.; Stach, Eric A.; Saha, Bivas; Saber, Sammy; Naik, Gururaj V.; Boltasseva, Alexandra; Kvam, Eric P.

    2015-02-01

    Epitaxial nitride rocksalt metal/semiconductor superlattices are emerging as a novel class of artificially structured materials that have generated significant interest in recent years for their potential application in plasmonic and thermoelectric devices. Though most nitride metals are rocksalt, nitride semiconductors in general have hexagonal crystal structure. We report rocksalt aluminum scandium nitride (Al,Sc)N alloys as the semiconducting component in epitaxial rocksalt metal/semiconductor superlattices. The AlxSc1-xN alloys when deposited directly on MgO substrates are stabilized in a homogeneous rocksalt (single) phase when x < 0.51. Employing 20 nm TiN as a seed layer on MgO substrates, the homogeneity range for stabilizingmore » the rocksalt phase has been extended to x < 0.82 for a 120 nm film. The rocksalt AlxSc1-xN alloys show moderate direct bandgap bowing with a bowing parameter, B = 1.41 ± 0.19 eV. The direct bandgap of metastable rocksalt AlN is extrapolated to be 4.70 ± 0.20 eV. The tunable lattice parameter, bandgap, dielectric permittivity, and electronic properties of rocksalt AlxSc1-xN alloys enable high quality epitaxial rocksalt metal/AlxSc1-xN superlattices with a wide range of accessible metamaterials properties.« less

  9. Conductive polymer/fullerene blend thin films with honeycomb framework for transparent photovoltaic application

    DOE Patents [OSTI]

    Cotlet, Mircea; Wang, Hsing-Lin; Tsai, Hsinhan; Xu, Zhihua

    2015-04-21

    Optoelectronic devices and thin-film semiconductor compositions and methods for making same are disclosed. The methods provide for the synthesis of the disclosed composition. The thin-film semiconductor compositions disclosed herein have a unique configuration that exhibits efficient photo-induced charge transfer and high transparency to visible light.

  10. Photoactive transparent nano-crystalline glass-ceramic for remazole red dye degradation

    SciTech Connect (OSTI)

    Gad-Allah, Tarek A.; Margha, Fatma H.

    2012-12-15

    Graphical abstract: Display Omitted Highlights: ? Preparation and characterization of novel transparent nanocrystalline glass-ceramic. ? Precipitation of photoactive phases by using controlled heat-treatment. ? Conservation of transparency along with photoactivity. ? Using the prepared nanocrystalline glass-ceramic in water purification. -- Abstract: Transparent glass ceramic material was prepared from alkali-borosilicate glass containing titania by proper heat treatment scheme. The prepared samples were characterized using differential thermal analysis, X-ray diffraction, transmission electron microscope, selected area electron diffraction and UVvisible spectroscopy. The applied heat treatment program allowed the crystallization of nano-crystalline anatase, rutile, barium titanate, titanium borate and silicate phases while maintaining the transparency. The precipitated nano-crystalline anatase and rutile phases were responsible for the observed high photocatalytic activity of the prepared samples. Samples of 24.29 and 32.39 TiO{sub 2} wt% showed better efficiency for the decolorization of remazole red dye compared with commercial-TiO{sub 2} used in preparation of glass-ceramic. The reuse of prepared glass-ceramic photocatalyst with nearly same efficiency for different times was also proved.

  11. Generation of surface waves and low-frequency radiation under exposure of a conductor to a laser pulse focused by a cylindrical lens

    SciTech Connect (OSTI)

    Uryupin, S A; Frolov, A A

    2014-09-30

    We have developed a theory of generation of low-frequency radiation and surface waves under the pondermotive action of a femtosecond laser pulse irradiating a conductor along the normal and focused by a cylindrical lens. It is shown that for the chosen focusing method and specified values of laser pulse duration and flux density it is possible to significantly increase the total energy of both surface waves and low-frequency radiation. (terahertz radiation)

  12. Performance of pancake coils of parallel co-wound Ag/BSCCO tape conductors in static and ramped magnetic fields

    SciTech Connect (OSTI)

    Schwenterly, S.W.; Lue, J.W.; Lubell, M.S.; Walker, M.S.; Hazelton, D.W.; Haldar, P.; Rice, J.A.; Hoehn, J.G. Jr.; Motowidlo, L.R.

    1994-12-31

    Critical Currents are reported for several Ag/BSCCO single-pancake coils in static magnetic fields ranging from 0 to 5 T and temperatures from 4.2 K to 105 K. The sample coils were co-wound of one to six tape conductors in parallel. Since the closed loops formed in such an arrangement could lead to eddy current heating or instability in changing fields, one of the coils was also tested in helium gas, in fields ramped at rates of up to 1.5 T/s. For these quasi-adiabatic tests, at each temperature the transport current was set just below the critical value for a preset static field of 3.3 or 4.9 T. The field was then rapidly ramped down to zero, held for 20 sec, and then ramped back up to the original value. The maximum observed temperature transient of about 1.7 K occurred at 9 K, for a field change of 4.75 T. The temperature transients became negligible when the sample was immersed in liquid helium. Above 30 K, the transients were below 1 K. These results give confidence that parallel co-wound HTSC coils are stable in a rapidly-ramped magnetic field, without undue eddy current heating.

  13. Parameters influencing the deposition of methylammonium lead halide iodide in hole conductor free perovskite-based solar cells

    SciTech Connect (OSTI)

    Cohen, Bat-El; Gamliel, Shany; Etgar, Lioz

    2014-08-01

    Perovskite is a promising light harvester for use in photovoltaic solar cells. In recent years, the power conversion efficiency of perovskite solar cells has been dramatically increased, making them a competitive source of renewable energy. An important parameter when designing high efficiency perovskite-based solar cells is the perovskite deposition, which must be performed to create complete coverage and optimal film thickness. This paper describes an in-depth study on two-step deposition, separating the perovskite deposition into two precursors. The effects of spin velocity, annealing temperature, dipping time, and methylammonium iodide concentration on the photovoltaic performance are studied. Observations include that current density is affected by changing the spin velocity, while the fill factor changes mainly due to the dipping time and methylammonium iodide concentration. Interestingly, the open circuit voltage is almost unaffected by these parameters. Hole conductor free perovskite solar cells are used in this work, in order to minimize other possible effects. This study provides better understanding and control over the perovskite deposition through highly efficient, low-cost perovskite-based solar cells.

  14. Characterization of Alloys with Potential for Application in Cable-in-Conduit Conductors for High-Field Superconducting Magnets

    SciTech Connect (OSTI)

    Walsh, R.P.; Miller, J.R.; Toplosky, V.J.

    2004-06-28

    Since the introduction of the cable-in-conduit conductor (CICC) concept, a variety of alloys have been proposed for fabricating the jacket. The jacket provides primary containment of the supercritical helium coolant and is typically also the primary structural component for the magnet. These functions create requirements for strength, toughness, weldability, and fabricability in tubular form. When the CICC uses Nb3Sn, there are additional requirements to accommodate the manufacturing and heat-treatment processes for the superconductor as well as its strain-sensitive performance during operation. Both of the present favorite jacket alloys, Incoloy 908 and modified (ultra-low carbon) 316LN, have both demonstrated acceptable functionality as well as a few undesirable features. In this paper, we present data from cryogenic mechanical tests on a group of heat-resistant, high-strength superalloys that appear to offer equal or better mechanical performance (e.g. strength, toughness, and modulus) while mitigating the undesirable aspects (e.g. SAGBO in the case of I908 and thermal-expansion mismatch with Nb3Sn in the case of 316LN). Data are presented for each alloy in the as-received and aged conditions. These alloys are presently being considered as candidates for use in the next-generation hybrid magnet for the NHMFL but may also be of interest to the fusion and energy storage communities.

  15. Magnetic field and field orientation dependence of the critical current density in Bi-2212 round wires and other HTS conductors

    SciTech Connect (OSTI)

    Willis, J.O.; Holesinger, T.G.; Coulter, J.Y.; Maley, M.P.

    1996-10-01

    The authors have performed measurements of the magnetic field dependence of the critical current density J{sub c} of Bi-2212/Ag round wire produced by isothermal melt processing. In contrast to the case for flat tape, there is very little dependence of J{sub c} on the direction of the magnetic field as it is rotated normal to the wire axis, which is the direction of the nominal current flow. However, when the angle of the magnetic field direction is rotated from normal to the wire axis to parallel to that axis, J{sub c} at 64 K and 0.2 T increases by more than a factor of four. Again, this is in contrast to the results observed for Bi-2212/Ag and Bi-2223/Ag flat tapes, which show no anisotropy under similar experimental conditions. They can explain these differences in angular anisotropy by referring to the microstructure of these two conductor types, which have distinctly different types of grain alignment. They discuss the general behavior of the dependence of J{sub c} on the orientation of a magnetic field for high temperature superconductors.

  16. An Air-Stable Na3SbS4 Superionic Conductor Prepared by a Rapid and Economic Synthetic Procedure

    SciTech Connect (OSTI)

    Wang, Hui; Chen, Yan; Hood, Zachary; Peng, Rui; Samuthira Pandian, Amaresh; Keum, Jong Kahk; Wu, Zili; An, Ke; Liang, Chengdu

    2016-01-01

    All-solid-state sodium batteries, using abundant sodium resources and solid electrolyte, hold much promise for safe, low cost, large-scale energy storage. To realize the practical applications of all solid Na-ion batteries at ambient temperature, the solid electrolytes are required to have high ionic conductivity, chemical stability, and ideally, easy preparation. Ceramic electrolytes show higher ionic conductivity than polymers, but they often require extremely stringent synthesis conditions, either high sintering temperature above 1000 C or long-time, low-energy ball milling. Herein, we report a new synthesis route for Na3SbS4, a novel Na superionic conductor that needs much lower processing temperature below 200 C and easy operation. This new solid electrolyte exhibits a remarkable ionic conductivity of 1.05 mS cm-1 at 25 C and is chemically stable under ambient atmosphere. This synthesis process provides unique insight into the current state-of-the-art solid electrolyte preparation and opens new possibilities for the design of similar materials.

  17. An Air-Stable Na3SbS4 Superionic Conductor Prepared by a Rapid and Economic Synthetic Procedure

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Hui; Chen, Yan; Hood, Zachary; Peng, Rui; Samuthira Pandian, Amaresh; Keum, Jong Kahk; Wu, Zili; An, Ke; Liang, Chengdu

    2016-01-01

    All-solid-state sodium batteries, using abundant sodium resources and solid electrolyte, hold much promise for safe, low cost, large-scale energy storage. To realize the practical applications of all solid Na-ion batteries at ambient temperature, the solid electrolytes are required to have high ionic conductivity, chemical stability, and ideally, easy preparation. Ceramic electrolytes show higher ionic conductivity than polymers, but they often require extremely stringent synthesis conditions, either high sintering temperature above 1000 C or long-time, low-energy ball milling. Herein, we report a new synthesis route for Na3SbS4, a novel Na superionic conductor that needs much lower processing temperature below 200 Cmore » and easy operation. This new solid electrolyte exhibits a remarkable ionic conductivity of 1.05 mS cm-1 at 25 C and is chemically stable under ambient atmosphere. This synthesis process provides unique insight into the current state-of-the-art solid electrolyte preparation and opens new possibilities for the design of similar materials.« less

  18. Performance Evaluation of K-DEMO Cable-in-conduit Conductors Using the Florida Electro-Mechanical Cable Model

    SciTech Connect (OSTI)

    Zhai, Yuhu

    2013-07-16

    The United States ITER Project Office (USIPO) is responsible for design of the Toroidal Field (TF) insert coil, which will allow validation of the performance of significant lengths of the conductors to be used in the full scale TF coils in relevant conditions of field, current density and mechanical strain. The Japan Atomic Energy Agency (JAEA) will build the TF insert which will be tested at the Central Solenoid Model Coil (CSMC) Test facility at JAEA, Naka, Japan. Three dimensional mathematical model of TF Insert was created based on the initial design geometry data, and included the following features: orthotropic material properties of superconductor material and insulation; external magnetic field from CSMC, temperature dependent properties of the materials; pre-compression and plastic deformation in lap joint. Major geometrical characteristics of the design were preserved including cable jacket and insulation shape, mandrel outline, and support clamps and spacers. The model is capable of performing coupled structural, thermal, and electromagnetic analysis using ANSYS. Numerical simulations were performed for room temperature conditions; cool down to 4K, and the operating regime with 68kA current at 11.8 Tesla background field. Numerical simulations led to the final design of the coil producing the required strain levels on the cable, while simultaneously satisfying the ITER magnet structural design criteria.

  19. Humidity Effect on Nanoscale Electrochemistry in Solid Silver Ion Conductors and the Dual Nature of Its Locality

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yang, Sangmo; Strelcov, Evgheni; Paranthaman, Mariappan Parans; Tselev, Alexander; Noh, Tae Won; Kalinin, Sergei V.

    2015-01-07

    Scanning probe microscopy (SPM) is a powerful tool to investigate electrochemistry in nanoscale volumes. While most SPM-based studies have focused on reactions at the tip-surface junction, charge and mass conservation requires coupled and intrinsically non-local cathodic and anodic processes that can be significantly affected by ambient humidity. Here, we explore the role of water in both cathodic and anodic processes, associated charge transport, and topographic volume changes depending on the polarity of tip bias. The first-order reversal curve current-voltage technique combined with simultaneous detection of the sample topography, referred to as FORC-IVz, was applied to a silver solid ion conductor.more » We found that the protons generated from water affect silver ionic conduction, silver particle formation and dissolution, and mechanical integrity of the material. This work highlights the dual nature (simultaneously local and non-local) of electrochemical SPM studies, which should be considered for comprehensive understanding of nanoscale electrochemistry.« less

  20. Nonlinear space charge dynamics in mixed ionic-electronic conductors: Resistive switching and ferroelectric-like hysteresis of electromechanical response

    SciTech Connect (OSTI)

    Morozovska, Anna N.; Morozovsky, Nicholas V.; Eliseev, Eugene A.; Varenyk, Olexandr V.; Kim, Yunseok; Strelcov, Evgheni; Tselev, Alexander; Kalinin, Sergei V.

    2014-08-14

    We performed self-consistent modelling of nonlinear electrotransport and electromechanical response of thin films of mixed ionic-electronic conductors (MIEC) allowing for steric effects of mobile charged defects (ions, protons, or vacancies), electron degeneration, and Vegard stresses. We establish correlations between the features of the nonlinear space-charge dynamics, current-voltage, and bending-voltage curves for different types of the film electrodes. A pronounced ferroelectric-like hysteresis of the bending-voltage loops and current maxima on the double hysteresis current-voltage loops appear for the electron-transport electrodes. The double hysteresis loop with pronounced humps indicates a memristor-type resistive switching. The switching occurs due to the strong nonlinear coupling between the electronic and ionic subsystems. A sharp meta-stable maximum of the electron density appears near one open electrode and moves to another one during the periodic change of applied voltage. Our results can explain the nonlinear nature and correlation of electrical and mechanical memory effects in thin MIEC films. The analytical expression proving that the electrically induced bending of MIEC films can be detected by interferometric methods is derived.

  1. Single-walled carbon nanotube transparent conductive films fabricated by reductive dissolution and spray coating for organic photovoltaics

    SciTech Connect (OSTI)

    Ostfeld, Aminy E.; Arias, Ana Claudia; Catheline, Amlie; Ligsay, Kathleen; Kim, Kee-Chan; Fogden, Sin; Chen, Zhihua; Facchetti, Antonio

    2014-12-22

    Solutions of unbundled and unbroken single-walled carbon nanotubes have been prepared using a reductive dissolution process. Transparent conductive films spray-coated from these solutions show a nearly twofold improvement in the ratio of electrical conductivity to optical absorptivity versus those deposited from conventional aqueous dispersions, due to substantial de-aggregation and sizable nanotube lengths. These transparent electrodes have been utilized to fabricate P3HT-PCBM organic solar cells achieving power conversion efficiencies up to 2.3%, comparable to those of solar cells using indium tin oxide transparent electrodes.

  2. Investigation of fluorine-doped tin oxide based optically transparent E-shaped patch antenna for terahertz communications

    SciTech Connect (OSTI)

    Anand, S. E-mail: darak.mayur@gmail.com Darak, Mayur Sudesh E-mail: darak.mayur@gmail.com Kumar, D. Sriram E-mail: darak.mayur@gmail.com

    2014-10-15

    In this paper, a fluorine-doped tin oxide based optically transparent E-shaped patch antenna is designed and its radiation performance is analyzed in the 705 – 804 GHz band. As optically transparent antennas can be mounted on optical display, they facilitate the reduction of overall system size. The proposed antenna design is simulated using electromagnetic solver - Ansys HFSS and its characteristics such as impedance bandwidth, directivity, radiation efficiency and gain are observed. Results show that the fluorine-doped tin oxide based optically transparent patch antenna overcomes the conventional patch antenna limitations and thus the same can be used for solar cell antenna used in satellite systems.

  3. Growth and optical properties of partially transparent Eu doped CaF{sub 2} ceramic

    SciTech Connect (OSTI)

    Ghosh, Manoranjan Sen, Shashwati Pitale, S. S. Goutam, U. K. Shinde, Seema Patra, G. D. Gadkari, S. C.

    2014-04-24

    Partially transparent ceramic of 2 at.% Eu doped CaF{sub 2} have been grown preferentially towards [111] direction. For this purpose, Eu doped CaF{sub 2} nanoparticles (size?12 nm) obtained by a low temperature solution growth method has been pressed at 1000C under vacuum. The preferentially grown ceramic shows 15% transparency within the visible range of spectrum. As confirmed by the X-ray diffraction result, the hot pressed ceramic exhibits reduced lattice volume than the nanopowder. It indicates Eu{sup 3+} as the dominant substituting ions at the Ca{sup 2+} sites of CaF{sub 2} lattice in the hot pressed ceramic material. It is corroborated by the photoluminescence results of hot pressed ceramic which shows strong red emission corresponding to Eu{sup 3+} sites. However, photoluminescence of nanopowder exhibits intense peak in the blue region of the spectrum which is characteristics of Eu2+ sites.

  4. Overview of transparency issues under the US-Russian highly enriched uranium purchase agreement

    SciTech Connect (OSTI)

    Bieniawski, A.J.; Dougherty, D.R.

    1995-12-31

    The US has signed an Agreement with the Russian Federation for the purchase of 500 metric tons of highly enriched uranium (HEU) derived from dismantled Russian nuclear weapons. The BEU will be blended down to low-enriched uranium (LEU) in Russia and will be transported to the US to be used by fuel Fabricators to make fuel for commercial nuclear power plants. Both the United States and Russia have been preparing to institute transparency measures to provide confidence that the nonproliferation, physical protection, and material control and accounting requirements specified in the Agreement are met. This paper provides a background on the Agreement and subsequent on-going negotiations to develop transparency measures suited to the facilities and processes which are expected to be involved.

  5. Health and safety considerations for U. S. monitors in the Russian transparency program.

    SciTech Connect (OSTI)

    Boggs, C. J.

    1998-10-22

    In 1993 the US and the Russian Federation signed an agreement allowing the US to purchase highly enriched uranium (HEU) from Russia over a 20-year period. This Highly Enriched Uranium Purchase Agreement permits the purchase of 500 metric tons of HEU from dismantled Russian nuclear weapons in the form of low-enriched uranium (LEU) for use as power reactor fuel in the US. Under the HEU Agreement, the US and Russia are cooperating in a ''Transparency Program'' to ensure that arms control and nonproliferation objectives are being met. The Transparency Program measures, which are a departure from traditional, intrusive measures of verification, include sending individuals from the US to Russia to monitor the processing of the HEU.

  6. Tuning optical properties of transparent conducting barium stannate by dimensional reduction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Yuwei; Zhang, Lijun; Ma, Yanming; Singh, David J.

    2015-01-30

    We report calculations of the electronic structure and optical properties of doped n-type perovskite BaSnO3 and layered perovskites. While doped BaSnO3 retains its transparency for energies below the valence to conduction band onset, the doped layered compounds exhibit below band edge optical conductivity due to transitions from the lowest conduction band. This gives absorption in the visible for Ba2SnO4. It is important to minimize this phase in transparent conducting oxide (TCO) films. Ba3Sn2O7 and Ba4Sn3O10 have strong transitions only in the red and infrared, respectively. Thus, there may be opportunities for using these as wavelength filtering TCO.

  7. ZnO:H indium-free transparent conductive electrodes for active-matrix display applications

    SciTech Connect (OSTI)

    Chen, Shuming Wang, Sisi

    2014-12-01

    Transparent conductive electrodes based on hydrogen (H)-doped zinc oxide (ZnO) have been proposed for active-matrix (AM) display applications. When fabricated with optimal H plasma power and optimal plasma treatment time, the resulting ZnO:H films exhibit low sheet resistance of 200 Ω/◻ and high average transmission of 85% at a film thickness of 150 nm. The demonstrated transparent conductive ZnO:H films can potentially replace indium-tin-oxide and serve as pixel electrodes for organic light-emitting diodes as well as source/drain electrodes for ZnO-based thin-film transistors. Use of the proposed ZnO:H electrodes means that two photomask stages can be removed from the fabrication process flow for ZnO-based AM backplanes.

  8. Radiation Heat Transfer in 3 Dimensions for Semi-Transparent Materials....

    Energy Science and Technology Software Center (OSTI)

    2010-12-02

    The RAD3D software solves the critical heat transfer mechanisms that occur in production glass furnaces. The code includes state-of-the-art solution algorithms for efficient radiant interaction of the heating elements, furnace walls and internal furnace components. The code specifically solves the coupled radiative and conductive heating of semi-transparent materials such as glass to calculate the temperature distribution in the glass during processing.

  9. Improving Data Transparency for the Distributed PV Interconnection Process: Emergent Utility Practices and State Requirements

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    June 3, 2015 "Improving Data Transparency for the Distributed PV Interconnection Process: Emergent Utility Practices and State Requirements" Joslyn Sato, Hawaiian Electric Companies Michael Conway, Borrego Solar Systems, Inc. Kristen Ardani and Emerson Reiter, National Renewable Energy Laboratory (NREL) 2 Purpose of Today's Meeting * Learn how data reporting requirements for interconnection vary across States, how tracking and data reporting for interconnection requests is evolving

  10. Improving Data Transparency for the Distributed PV Interconnection Process: Emergent Utility Practices and State Requirements Transcript

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Data Transparency for the Distributed PV Page 1 of 21 Interconnection Process Emergent Utility Practices and State Requirements Kristen Adrani, Emerson Reiter, Joslyn Sato, Michael Conway Page 1 of 21 [Speaker: Kristen Ardani] Cover Slide: Thank you everyone for joining us for today's quarterly meeting of the Distributed Generation Interconnection Collaborative, or the DGIC. My name is Kristen Ardani. I'm a solar analyst here at NREL and I'll be moderating today's discussion. The topic for today

  11. New report offers best practice for transparent contract language of PV O&M

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    agreements offers best practice for transparent contract language of PV O&M agreements - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery

  12. Optically transparent and environmentally durable superhydrophobic coating based on functionalized SiO2 nanoparticles

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Schaeffer, Daniel A.; Polizos, Georgios; Smith, D. Barton; Lee, Dominic F.; Hunter, Scott R.; Datskos, Panos G.

    2015-01-09

    Optical surfaces such as mirrors and windows that are exposed to outdoor environmental conditions are susceptible to dust buildup and water condensation. The application of transparent superhydrophobic coatings on optical surfaces can improve outdoor performance via a self-cleaning effect similar to the Lotus effect. The contact angle (CA) of water droplets on a typical hydrophobic flat surface varies from 100° to 120°. Adding roughness or microtexture to a hydrophobic surface leads to an enhancement of hydrophobicity and the CA can be increased to a value in the range of 16≥0° to 175°. This result is remarkable because such behavior cannotmore » be explained using surface chemistry alone. When surface features are on the order of 100 nm or smaller, surfaces exhibit superhydrophobic behavior and maintain their optical transparency. In this work we discuss our results on transparent superhydrophobic coatings that can be applied across large surface areas. We have used functionalized silica nanoparticles to coat various optical elements and have measured the contact angle and optical transmission between 190 to 1100 nm on these elements. The functionalized silica nanoparticles were dissolved in a solution of the solvents isopropyl alcohol and 4-chlorobenzotrifluoride (PCBTF) and a proprietary ceramic binder (Cerakote ). Finally, this solution was spin-coated onto a variety of test glass substrates, and following a curing period of about 30 minutes, these coatings exhibited superhydrophobic behavior with a static CA ≥160°.« less

  13. Apparatus and procedure to characterize the surface quality of conductors by measuring the rate of cathode emission as a function of surface electric field strength

    DOE Patents [OSTI]

    Mestayer, Mac; Christo, Steve; Taylor, Mark

    2014-10-21

    A device and method for characterizing quality of a conducting surface. The device including a gaseous ionizing chamber having centrally located inside the chamber a conducting sample to be tested to which a negative potential is applied, a plurality of anode or "sense" wires spaced regularly about the central test wire, a plurality of "field wires" at a negative potential are spaced regularly around the sense, and a plurality of "guard wires" at a positive potential are spaced regularly around the field wires in the chamber. The method utilizing the device to measure emission currents from the conductor.

  14. Surface and mechanical properties of transparent polycrystalline YAG fabricated by SPS

    SciTech Connect (OSTI)

    Palmero, P.; Bonelli, B.; Fantozzi, G.; Spina, G.; Bonnefont, G.; Montanaro, L.; Chevalier, J.

    2013-07-15

    Graphical abstract: - Highlights: • Ultrasonication as effective, un-polluting dispersion route for YAG powders. • Annealing in the 700–900 °C range to increase the transparency. • Oxygen vacancies more crucial on the transmittance than C contamination. • SPS reliable method for transparent and ultra-fine polycrystalline YAG. • Very high hardness (16.5–17 GPa) for the fully dense, fine materials. - Abstract: YAG powder was synthesised by reverse-strike co-precipitation, calcined at 1000 °C and dispersed by either ball-milling with α-alumina (BM{sub A}) or zirconia (BMz) spheres or by ultrasonication (US). All the dispersed powders were consolidated by SPS to nearly theoretical density, but only the US powder gave rise to a transparent material (transmittance of about 60% at 600 nm, 1 mm thickness), characterised by an ultra-fine microstructure (average size of 330 nm). In the BM materials, Raman spectroscopy allowed to evidence some phonon vibrational shifts due to secondary phases deriving from pollution by the milling media, not detectable by XRD because present in small amounts. The transmittance of the as-sintered US sample was further increased by annealing in air at 900 °C; this was assigned to the restoration of some oxygen vacancies created in the reducing environment of the SPS chamber, as evidenced by XPS (X-ray photoelectron spectroscopy). Finally, US samples sintered in the 1250–1400 °C were submitted to a basic mechanical characterisation, showing a very good hardness, in spite of a moderate fracture toughness, especially for the fully dense and fine-grained materials sintered at 1300–1350 °C.

  15. The role of opacity and transparency in achieving strategic stability in South Asia.

    SciTech Connect (OSTI)

    Rajain, Arpit; Ashraf, Tariq Mahmud

    2005-08-01

    According to international relations theory, deterrence can be used as a tool to achieve stability between potentially hostile nations. India and Pakistan's long history of periodic crises raises the question of how they can achieve deterrence stability. 'Transparency' describes the flow of information between parties and plays a key role in establishing a deterrence relationship. This paper studies the balance needed between opacity and transparency in nuclear topics for the maintenance of deterrence stability between India and Pakistan. States with nuclear weapons are postulated to implement transparency in four categories: potential, capability, intent, and resolve. The study applies these categories to the nuclear components of the ongoing India-Pakistan Composite Dialogue Working Group for Peace and Security including CBMs. To focus our efforts, we defined four scenarios to characterize representative strategic/military/political conditions. The scenarios are combinations of these two sets of opposite poles: competition - cooperation; extremism - moderation (to be understood primarily in a religious/nationalistic sense). We describe each scenario in terms of select focal areas (nuclear doctrine, nuclear command and control, nuclear stockpile, nuclear delivery/defensive systems, and conventional force posture). The scenarios help frame the realm of possibilities, and have been described in terms of expected conditions for the focal areas. We then use the conditions in each scenario to prescribe a range of information-sharing actions that the two countries could take to increase stability. We also highlight the information that should not be shared. These actions can be political (e.g., declarations), procedural (e.g., advance notice of certain military activities), or technologically based (e.g., seismic monitoring of the nuclear test moratorium).

  16. Transparent hydrogel with enhanced water retention capacity by introducing highly hydratable salt

    SciTech Connect (OSTI)

    Bai, Yuanyuan; Xiang, Feng; Wang, Hong E-mail: suo@seas.harvard.edu; Chen, Baohong; Zhou, Jinxiong; Suo, Zhigang E-mail: suo@seas.harvard.edu

    2014-10-13

    Polyacrylamide hydrogels containing salt as electrolyte have been used as highly stretchable transparent electrodes in flexible electronics, but those hydrogels are easy to dry out due to water evaporation. Targeted, we try to enhance water retention capacity of polyacrylamide hydrogel by introducing highly hydratable salts into the hydrogel. These hydrogels show enhanced water retention capacity in different level. Specially, polyacrylamide hydrogel containing high content of lithium chloride can retain over 70% of its initial water even in environment with relative humidity of only 10% RH. The excellent water retention capacities of these hydrogels will make more applications of hydrogels become possible.

  17. Transparently wrap-gated semiconductor nanowire arrays for studies of gate-controlled photoluminescence

    SciTech Connect (OSTI)

    Nylund, Gustav; Storm, Kristian; Torstensson, Henrik; Wallentin, Jesper; Borgstrm, Magnus T.; Hessman, Dan; Samuelson, Lars

    2013-12-04

    We present a technique to measure gate-controlled photoluminescence (PL) on arrays of semiconductor nanowire (NW) capacitors using a transparent film of Indium-Tin-Oxide (ITO) wrapping around the nanowires as the gate electrode. By tuning the wrap-gate voltage, it is possible to increase the PL peak intensity of an array of undoped InP NWs by more than an order of magnitude. The fine structure of the PL spectrum reveals three subpeaks whose relative peak intensities change with gate voltage. We interpret this as gate-controlled state-filling of luminescing quantum dot segments formed by zincblende stacking faults in the mainly wurtzite NW crystal structure.

  18. Transparent TiO2 nanotube array photoelectrodes prepared via two-step anodization

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kim, Jin Young; Zhu, Kai; Neale, Nathan R.; Frank, Arthur J.

    2014-04-04

    Two-step anodization of transparent TiO2 nanotube arrays has been demonstrated with aid of a Nb-doped TiO2 buffer layer deposited between the Ti layer and TCO substrate. Enhanced physical adhesion and electrochemical stability provided by the buffer layer has been found to be important for successful implementation of the two-step anodization process. As a result, with the proposed approach, the morphology and thickness of NT arrays could be controlled very precisely, which in turn, influenced their optical and photoelectrochemical properties.

  19. Amorphous semiconducting and conducting transparent metal oxide thin films and production thereof

    DOE Patents [OSTI]

    Perkins, John; Van Hest, Marinus Franciscus Antonius Maria; Ginley, David; Taylor, Matthew; Neuman, George A.; Luten, Henry A.; Forgette, Jeffrey A.; Anderson, John S.

    2010-07-13

    Metal oxide thin films and production thereof are disclosed. An exemplary method of producing a metal oxide thin film may comprise introducing at least two metallic elements and oxygen into a process chamber to form a metal oxide. The method may also comprise depositing the metal oxide on a substrate in the process chamber. The method may also comprise simultaneously controlling a ratio of the at least two metallic elements and a stoichiometry of the oxygen during deposition. Exemplary amorphous metal oxide thin films produced according to the methods herein may exhibit highly transparent properties, highly conductive properties, and/or other opto-electronic properties.

  20. Damp-Heat Induced Degradation of Transparent Conducting Oxides for Thin Film Solar Cells (Presentation)

    SciTech Connect (OSTI)

    Pern, J.; Noufi, R.; Li, X.; DeHart, C.; To, B.

    2008-05-01

    The objectives are: (1) To achieve a high long-term performance reliability for the thin-film CIGS PV modules with more stable materials, device structure designs, and moisture-resistant encapsulation materials and schemes; (2) to evaluate the DH stability of various transparent conducting oxides (TCOs); (3) to identify the degradation mechanisms and quantify degradation rates; (4) to seek chemical and/or physical mitigation methods, and explore new materials. It's important to note that direct exposure to DH represents an extreme condition that a well-encapsulated thin film PV module may never experience.

  1. Graphene as transparent and current spreading electrode in silicon solar cell

    SciTech Connect (OSTI)

    Behura, Sanjay K. Nayak, Sasmita; Jani, Omkar; Mahala, Pramila

    2014-11-15

    Fabricated bi-layer graphene (BLG) has been studied as transparent and current spreading electrode (TCSE) for silicon solar cell, using TCAD-Silvaco 2D simulation. We have carried out comparative study using both Ag grids and BLG as current spreading electrode (CSE) and TCSE, respectively. Our study reveals that BLG based solar cell shows better efficiency of 24.85% than Ag-based cell (21.44%), in all of the critical aspects, including generation rate, recombination rate, electric field, potential and quantum efficiency. Further BLG based cell exhibits pronounce rectifying behavior, low saturation current, and good turn-on voltage while studying in dark.

  2. Architecture for coated conductors

    DOE Patents [OSTI]

    Foltyn, Stephen R.; Arendt, Paul N.; Wang, Haiyan; Stan, Liliana

    2010-06-01

    Articles are provided including a base substrate having a layer of an oriented cubic oxide material with a rock-salt-like structure layer thereon, and, a layer of epitaxial titanium nitride upon the layer of an oriented cubic oxide material having a rock-salt-like structure. Such articles can further include thin films of high temperature superconductive oxides such as YBCO upon the layer of epitaxial titanium nitride or upon a intermediate buffer layer upon the layer of epitaxial titanium nitride.

  3. Status of the United States-Russian Federation safeguards, transparency and irreversibility (STI) initiative for nuclear arms reductions

    SciTech Connect (OSTI)

    Czajkowski, A.F.; Bieniawski, A.J.; Percival, C.M.

    1996-12-31

    The US-Russian Federation initiative to provide safeguards, transparency, and irreversibility (STI) of nuclear arms reductions has been emphasized by several Presidential Joint Summit Statements as well as various agreements between the two parties. Beginning with the US and Russian Federation agreement in March, 1994, to host reciprocal inspections to confirm the stockpiles of plutonium removed from nuclear weapons, the US and Russia have been negotiating an STI regime to increase the transparency and irreversibility of nuclear arms reduction. In December, 1994, the US presented a paper to the Russian Federation proposing a regime of specific transparency measures to provide broader transparency and irreversibility of nuclear arms reductions. Presently the US considers STI to consist of the following measures: (1) agreement for cooperation (AFC); (2) stockpile data exchange agreement (SDEA); (3) mutual reciprocal inspections (MRI); (4) spot checks to confirm data exchanges (SC); and (5) limited Chain of Custody of Warheads Being Dismantled (LCC). The US and Russian have begun negotiations, which are in various stages of progress, on the first three of these measures. This paper will present a brief historical background of STI and discuss the transparency measures including the status of negotiation for each of the measures.

  4. Transparency and damage tolerance of patternable omniphobic lubricated surfaces based on inverse colloidal monolayers

    SciTech Connect (OSTI)

    Vogel, Nicolas; Belisle, Rebecca A.; Hatton, Benjamin; Wong, Tak-Sing; Aizenberg, Joanna

    2013-07-31

    A transparent coating that repels a wide variety of liquids, prevents staining, is capable of self-repair and is robust towards mechanical damage can have a broad technological impact, from solar cell coatings to self-cleaning optical devices. Here we employ colloidal templating to design transparent, nanoporous surface structures. A lubricant can be firmly locked into the structures and, owing to its fluidic nature, forms a defect-free, self-healing interface that eliminates the pinning of a second liquid applied to its surface, leading to efficient liquid repellency, prevention of adsorption of liquid-borne contaminants, and reduction of ice adhesion strength. We further show how this method can be applied to locally pattern the repellent character of the substrate, thus opening opportunities to spatially confine any simple or complex fluids. The coating is highly defect-tolerant due to its interconnected, honeycomb wall structure, and repellency prevails after the application of strong shear forces and mechanical damage. The regularity of the coating allows us to understand and predict the stability or failure of repellency as a function of lubricant layer thickness and defect distribution based on a simple geometric model.

  5. Participatory approach, acceptability and transparency of waste management LCAs: Case studies of Torino and Cuneo

    SciTech Connect (OSTI)

    Blengini, Gian Andrea; Fantoni, Moris; Busto, Mirko; Genon, Giuseppe; Zanetti, Maria Chiara

    2012-09-15

    Highlights: Black-Right-Pointing-Pointer Life Cycle Assessment is still not fully operational in waste management at local scale. Black-Right-Pointing-Pointer Credibility of WM LCAs is negatively affected by assumptions and lack of transparency. Black-Right-Pointing-Pointer Local technical-social-economic constraints are often not reflected by WM LCAs. Black-Right-Pointing-Pointer A participatory approach can increase acceptability and credibility of WM LCAs. Black-Right-Pointing-Pointer Results of a WM LCA can hardly ever be generalised, thus transparency is essential. - Abstract: The paper summarises the main results obtained from two extensive applications of Life Cycle Assessment (LCA) to the integrated municipal solid waste management systems of Torino and Cuneo Districts in northern Italy. Scenarios with substantial differences in terms of amount of waste, percentage of separate collection and options for the disposal of residual waste are used to discuss the credibility and acceptability of the LCA results, which are adversely affected by the large influence of methodological assumptions and the local socio-economic constraints. The use of site-specific data on full scale waste treatment facilities and the adoption of a participatory approach for the definition of the most sensible LCA assumptions are used to assist local public administrators and stakeholders showing them that LCA can be operational to waste management at local scale.

  6. Study of transparent and nontransparent regimes of implosion in star wire arrays

    SciTech Connect (OSTI)

    Ivanov, V. V.; Astanovitskiy, A. L.; Papp, D.; Altemara, S. D.; Chittenden, J. P.; Bland, S. N.; Jones, B.

    2010-10-15

    Star wire arrays were used to control the imploding plasma flows and study plasma interpenetration. These arrays consisted of linear 'rays' aligned azimuthally and extending from the vertical axis. Star arrays with two close located wires ('gates') instead of a single wire on the inner cylinder were studied for transparent and nontransparent regimes of propagation of imploding plasma through the gates. Nontransparent mode of collision is typical for regular star wire arrays and it was also observed in Al stars with gate wires of regular length and with the gate width of 0.3-2 mm. The cascade process of implosion in stars and trapping of imploding plasma in 1-2 mm gates were modeled with the three-dimensional resistive magnetohydrodynamics code. The intermediate semitransparent mode of collision was observed in Al stars with long Al 'gate' wires. A transparent mode was observed in Al stars with long stainless steel or W gate wires. Applications of wire arrays with controlled plasma flows are discussed.

  7. Transparency and damage tolerance of patternable omniphobic lubricated surfaces based on inverse colloidal monolayers

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Vogel, Nicolas; Belisle, Rebecca A.; Hatton, Benjamin; Wong, Tak-Sing; Aizenberg, Joanna

    2013-07-31

    A transparent coating that repels a wide variety of liquids, prevents staining, is capable of self-repair and is robust towards mechanical damage can have a broad technological impact, from solar cell coatings to self-cleaning optical devices. Here we employ colloidal templating to design transparent, nanoporous surface structures. A lubricant can be firmly locked into the structures and, owing to its fluidic nature, forms a defect-free, self-healing interface that eliminates the pinning of a second liquid applied to its surface, leading to efficient liquid repellency, prevention of adsorption of liquid-borne contaminants, and reduction of ice adhesion strength. We further show howmore » this method can be applied to locally pattern the repellent character of the substrate, thus opening opportunities to spatially confine any simple or complex fluids. The coating is highly defect-tolerant due to its interconnected, honeycomb wall structure, and repellency prevails after the application of strong shear forces and mechanical damage. The regularity of the coating allows us to understand and predict the stability or failure of repellency as a function of lubricant layer thickness and defect distribution based on a simple geometric model.« less

  8. Novel Iron-based ternary amorphous oxide semiconductor with very high transparency, electronic conductivity, and mobility

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Malasi, A.; Taz, H.; Farah, A.; Patel, M.; Lawrie, Benjamin; Pooser, R.; Baddorf, A.; Duscher, G.; Kalyanaraman, R.

    2015-12-16

    We report that ternary metal oxides of type (Me)2O3 with the primary metal (Me) constituent being Fe (66 atomic (at.) %) along with the two Lanthanide elements Tb (10 at.%) and Dy (24 at.%) can show excellent semiconducting transport properties. Thin films prepared by pulsed laser deposition at room temperature followed by ambient oxidation showed very high electronic conductivity (>5 × 104 S/m) and Hall mobility (>30 cm2/V-s). These films had an amorphous microstructure which was stable to at least 500 °C and large optical transparency with a direct band gap of 2.85 ± 0.14 eV. This material shows emergentmore » semiconducting behavior with significantly higher conductivity and mobility than the constituent insulating oxides. In conclusion, since these results demonstrate a new way to modify the behaviors of transition metal oxides made from unfilled d- and/or f-subshells, a new class of functional transparent conducting oxide materials could be envisioned.« less

  9. Novel Iron-based ternary amorphous oxide semiconductor with very high transparency, electronic conductivity, and mobility

    SciTech Connect (OSTI)

    Malasi, A.; Taz, H.; Farah, A.; Patel, M.; Lawrie, Benjamin; Pooser, R.; Baddorf, A.; Duscher, G.; Kalyanaraman, R.

    2015-12-16

    We report that ternary metal oxides of type (Me)2O3 with the primary metal (Me) constituent being Fe (66 atomic (at.) %) along with the two Lanthanide elements Tb (10 at.%) and Dy (24 at.%) can show excellent semiconducting transport properties. Thin films prepared by pulsed laser deposition at room temperature followed by ambient oxidation showed very high electronic conductivity (>5 × 104 S/m) and Hall mobility (>30 cm2/V-s). These films had an amorphous microstructure which was stable to at least 500 °C and large optical transparency with a direct band gap of 2.85 ± 0.14 eV. This material shows emergent semiconducting behavior with significantly higher conductivity and mobility than the constituent insulating oxides. In conclusion, since these results demonstrate a new way to modify the behaviors of transition metal oxides made from unfilled d- and/or f-subshells, a new class of functional transparent conducting oxide materials could be envisioned.

  10. Structure and chemistry of sol-gel derived transparent silica aerogel

    SciTech Connect (OSTI)

    Tewari, P.H.; Lofftus, K.D.; Hunt, A.J.

    1985-02-01

    Transparent silica aerogels are being studied because of their excellent thermal insulation properties for window glazing materials. The chemistry of the base catalyzed Si(OC/sub 2/H/sub 5/)/sub 4/ sol-gel process to produce transparent aerogels is presented. The results of a factorial design set of experiments are discussed in which five process parameters are simultaneously varied. The goal of these experiments was to optimize the process conditions and to analyze the importance of various parameters in improving the properties of the aerogel. A novel technique of ambient temperature supercritical drying of alcogels is described. In this process, supercritical drying occurs at less than or equal to40/sup 0/C instead of at greater than or equal to270/sup 0/C and greater than or equal to1700 PSI (12 MPa), by substituting CO/sub 2/ for alcohol in the alcogel. The time of drying is reduced from 2 to 3 days to 8 to 10 hours. It is shown that light scattering, microstructural properties and other characteristics of aerogels produced by this process and by the high temperature supercritical drying are similar.

  11. Correlation of anisotropy and directional conduction in β-Li3PS4 fast Li+ conductor

    SciTech Connect (OSTI)

    Chen, Yan; Cai, Lu; Liu, Zengcai; dela Cruz, Clarina R.; Liang, Chengdu; An, Ke

    2015-07-06

    Our letter reports the correlation of anisotropy and directional conduction in the fast Li+ conductor β-Li3PS4, one of the low-symmetry crystalline electrolyte candidates. The material has both high conductivity and good stability that serves well for the large-scale energy storage applications of all-solid-state lithium ion batteries. The anisotropic physical properties, demonstrated here by the thermal expansion coefficients, are crucial for compatibility in the solid-state system and battery performance. Neutron and X-ray powder diffraction measurements were done to determine the crystal structure and thermal stability. Moreover, the crystallographic b-axis was revealed as a fast expansion direction, while negligible thermal expansion was observed along the a-axis around the battery operating temperatures. The anisotropic behavior has its structural origin from the Li+ conduction channels with incomplete Li occupancy and a flexible connection of LiS4 and PS4 tetrahedra within the framework. This indicates a strong correlation in the direction of the ionic transport in the low-symmetry Li+ conductor.

  12. Perovskite Sr-doped LaCrO3 as a new p-type transparent conducting oxide

    SciTech Connect (OSTI)

    Zhang, Hongliang; Du, Yingge; Papadogianni, Alexandra; Bierwagen, Oliver; Sallis, Shawn; Piper, Louis F. J.; Bowden, Mark E.; Shutthanandan, V.; Sushko, Petr; Chambers, Scott A.

    2015-09-16

    Transparent conducting oxides (TCOs) constitute a unique class of materials which combine the seemingly mutually exclusive properties of electrical conductivity and optical transparency in a single material. TCOs are useful for a wide range of applications including solar cells, displays, light emitting diodes and transparent electronics. Simple post-transition metal oxides such as ZnO, In2O3 and SnO2 are wide gap insulators in which the ionic character generates an oxygen 2p-derived valence band (VB) and a metal s-derived conduction band (CB), resulting in large optical band gaps (>3.0 eV) and excellent n-type conductivity when donor doped. In contrast, the development of efficient p-type TCOs remains a global materials challenge. Converting n-type oxides to p-type analogs by acceptor doping is extremely difficult and these materials display poor conductivity.

  13. Thin film electronic devices with conductive and transparent gas and moisture permeation barriers

    DOE Patents [OSTI]

    Simpson, Lin Jay

    2015-07-28

    Thin film electronic devices (or stacks integrated with a substrate) that include a permeation barrier formed of a thin layer of metal that provides a light transmitting and electrically conductive layer, wherein the electrical conductive layer is formed on a surface of the substrate or device layer such as a transparent conducting material layer with pin holes or defects caused by manufacturing and the thin layer of metal is deposited on the conductive layer and formed from a self-healing metal that forms self-terminating oxides. A permeation plug or block is formed in or adjacent to the thin film of metal at or proximate to the pin holes to block further permeation of contaminants through the pin holes.

  14. Impacts of humidity and temperature on the performance of transparent conducting zinc oxide.

    SciTech Connect (OSTI)

    Granata, Jennifer E.; Yaklin, Melissa A.; Schneider, Duane Allen; Staiger, Chad Lynn; Norman, Kirsten

    2010-06-01

    The impact of humidity and temperature on a zinc oxide based transparent conducting oxide (TCO) was assessed under accelerated aging conditions. An in situ electroanalytical method was used to monitor the electrical properties for a conducting zinc oxide under controlled atmospheric (humidity, temperature and irradiation) conditions. A review of thin film photovoltaic (PV) literature has shown one major failure mode of cells/modules is associated with the ingress of water into modules in the field. Water contamination has been shown to degrade the performance of the TCO in addition to corroding interconnects and other conductive metals/materials associated with the module. Water ingress is particularly problematic in flexible thin film PV modules since traditional encapsulates such as poly(ethyl vinyl acetate) (EVA) have high water vapor transmission rates. The accelerated aging studies of the zinc oxide based TCOs will allow acceleration factors and kinetic parameters to be determined for reliability purposes.

  15. Data Mining-Aided Crystal Engineering for the Design of Transparent Conducting Oxides: Preprint

    SciTech Connect (OSTI)

    Suh, C.; Kim, K.; Berry, J. J.; Lee, J.; Jones, W. B.

    2010-12-01

    The purpose of this paper is to accelerate the pace of material discovery processes by systematically visualizing the huge search space that conventionally needs to be explored. To this end, we demonstrate not only the use of empirical- or crystal chemistry-based physical intuition for decision-making, but also to utilize knowledge-based data mining methodologies in the context of finding p-type delafossite transparent conducting oxides (TCOs). We report on examples using high-dimensional visualizations such as radial visualization combined with machine learning algorithms such as k-nearest neighbor algorithm (k-NN) to better define and visualize the search space (i.e. structure maps) of functional materials design. The vital role of search space generated from these approaches is discussed in the context of crystal chemistry of delafossite crystal structure.

  16. Thermal properties of the optically transparent pore-free nanostructured yttria-stabilized zirconia

    SciTech Connect (OSTI)

    Ghosh, S.; Teweldebrhan, D.; Morales, J. R.; Garay, J. E.; Balandin, A. A.

    2009-12-01

    The authors report results of investigation of thermal conductivity of nanocrystalline yttria-stabilized zirconia. The optically transparent pore-free bulk samples were prepared via the spark plasma sintering process to ensure homogeneity. Thermal conductivity K was measured by two different techniques. It was found that the pore-free nanostructured bulk zirconia is an excellent thermal insulator with the room-temperature Kapprox1.7-2.0 W/m K. It was also shown that the 'phonon-hopping' model can accurately describe specifics of K dependence on temperature and the grain size. The obtained results are important for optimization of zirconia properties for specific applications in advanced electronics and coatings.

  17. Coordination Between the HEU Transparency Program and the Material Protection, Control and Accountability Program

    SciTech Connect (OSTI)

    Glaser, J.; Hernandez, J.; Dougherty, D.; Bieniawski, A.; Cahalane, P.; Mastal, E.

    2000-06-30

    DOE sponsored programs such as Material Protection Control and Accountability (MPC&A) and implementation of the Highly-Enriched Uranium (HEU) Transparency Program send US personnel into Russian nuclear facilities and receive Russian representatives from these programs. While there is overlap in the Russian nuclear facilities visited by these two programs, there had not been any formal mechanism to share information between them. Recently, an MPC&A/HEU Working Group was developed to facilitate the sharing of appropriate information and to address concerns expressed by Minatom and Russian facility personnel such as US visit scheduling conflicts. This paper discusses the goals of the Working Group and ways it has helped to allow the programs to work more efficiently with the Russian facilities.

  18. Transparent electrodes in silicon heterojunction solar cells: Influence on contact passivation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tomasi, Andrea; Sahli, Florent; Seif, Johannes Peter; Fanni, Lorenzo; de Nicolas Agut, Silvia Martin; Geissbuhler, Jonas; Paviet-Salomon, Bertrand; Nicolay, Sylvain; Barraud, Loris; Niesen, Bjoern; et al

    2015-10-26

    Charge carrier collection in silicon heterojunction solar cells occurs via intrinsic/doped hydrogenated amorphous silicon layer stacks deposited on the crystalline silicon wafer surfaces. Usually, both the electron and hole collecting stacks are externally capped by an n-type transparent conductive oxide, which is primarily needed for carrier extraction. Earlier, it has been demonstrated that the mere presence of such oxides can affect the carrier recombination in the crystalline silicon absorber. Here, we present a detailed investigation of the impact of this phenomenon on both the electron and hole collecting sides, including its consequences for the operating voltages of silicon heterojunction solarmore » cells. As a result, we define guiding principles for improved passivating contact design for high-efficiency silicon solar cells.« less

  19. Transparent electrodes in silicon heterojunction solar cells: Influence on contact passivation

    SciTech Connect (OSTI)

    Tomasi, Andrea; Sahli, Florent; Seif, Johannes Peter; Fanni, Lorenzo; de Nicolas Agut, Silvia Martin; Geissbuhler, Jonas; Paviet-Salomon, Bertrand; Nicolay, Sylvain; Barraud, Loris; Niesen, Bjoern; De Wolf, Stefaan; Ballif, Christophe

    2015-10-26

    Charge carrier collection in silicon heterojunction solar cells occurs via intrinsic/doped hydrogenated amorphous silicon layer stacks deposited on the crystalline silicon wafer surfaces. Usually, both the electron and hole collecting stacks are externally capped by an n-type transparent conductive oxide, which is primarily needed for carrier extraction. Earlier, it has been demonstrated that the mere presence of such oxides can affect the carrier recombination in the crystalline silicon absorber. Here, we present a detailed investigation of the impact of this phenomenon on both the electron and hole collecting sides, including its consequences for the operating voltages of silicon heterojunction solar cells. As a result, we define guiding principles for improved passivating contact design for high-efficiency silicon solar cells.

  20. Nano-honeycomb structured transparent electrode for enhanced light extraction from organic light-emitting diodes

    SciTech Connect (OSTI)

    Shi, Xiao-Bo; Qian, Min; Wang, Zhao-Kui E-mail: lsliao@suda.edu.cn; Liao, Liang-Sheng E-mail: lsliao@suda.edu.cn

    2015-06-01

    A universal nano-sphere lithography method has been developed to fabricate nano-structured transparent electrode, such as indium tin oxide (ITO), for light extraction from organic light-emitting diodes (OLEDs). Perforated SiO{sub 2} film made from a monolayer colloidal crystal of polystyrene spheres and tetraethyl orthosilicate sol-gel is used as a template. Ordered nano-honeycomb pits on the ITO electrode surface are obtained by chemical etching. The proposed method can be utilized to form large-area nano-structured ITO electrode. More than two folds' enhancement in both current efficiency and power efficiency has been achieved in a red phosphorescent OLED which was fabricated on the nano-structured ITO substrate.

  1. Atomic Physics Effects on Convergent, Child-Langmuir Ion Flow between Nearly Transparent Electrodes

    SciTech Connect (OSTI)

    Santarius, John F.; Emmert, Gilbert A.

    2013-11-07

    Research during this project at the University of Wisconsin Fusion Technology Institute (UW FTI) on ion and neutral flow through an arbitrary, monotonic potential difference created by nearly transparent electrodes accomplished the following: (1) developed and implemented an integral equation approach for atomic physics effects in helium plasmas; (2) extended the analysis to coupled integral equations that treat atomic and molecular deuterium ions and neutrals; (3) implemented the key deuterium and helium atomic and molecular cross sections; (4) added negative ion production and related cross sections; and (5) benchmarked the code against experimental results. The analysis and codes treat the species D0, D20, D+, D2+, D3+, D and, separately at present, He0 and He+. Extensions enhanced the analysis and related computer codes to include He++ ions plus planar and cylindrical geometries.

  2. System of and method for transparent management of data objects in containers across distributed heterogenous resources

    DOE Patents [OSTI]

    Moore, Reagan W.; Rajasekar, Arcot; Wan, Michael Y.

    2007-09-11

    A system of and method for maintaining data objects in containers across a network of distributed heterogeneous resources in a manner which is transparent to a client. A client request pertaining to containers is resolved by querying meta data for the container, processing the request through one or more copies of the container maintained on the system, updating the meta data for the container to reflect any changes made to the container as a result processing the re quest, and, if a copy of the container has changed, changing the status of the copy to indicate dirty status or synchronizing the copy to one or more other copies that may be present on the system.

  3. System of and method for transparent management of data objects in containers across distributed heterogenous resources

    DOE Patents [OSTI]

    Moore, Reagan W.; Rajasekar, Arcot; Wan, Michael Y.

    2010-09-21

    A system of and method for maintaining data objects in containers across a network of distributed heterogeneous resources in a manner which is transparent to a client. A client request pertaining to containers is resolved by querying meta data for the container, processing the request through one or more copies of the container maintained on the system, updating the meta data for the container to reflect any changes made to the container as a result processing the request, and, if a copy of the container has changed, changing the status of the copy to indicate dirty status or synchronizing the copy to one or more other copies that may be present on the system.

  4. System of and method for transparent management of data objects in containers across distributed heterogenous resources

    DOE Patents [OSTI]

    Moore, Reagan W.; Rajasekar, Arcot; Wan, Michael Y.

    2004-01-13

    A system of and method for maintaining data objects in containers across a network of distributed heterogeneous resources in a manner which is transparent to a client. A client request pertaining to containers is resolved by querying meta data for the container, processing the request through one or more copies of the container maintained on the system, updating the meta data for the container to reflect any changes made to the container as a result processing the request, and, if a copy of the container has changed, changing the status of the copy to indicate dirty status or synchronizing the copy to one or more other copies that may be present on the system.

  5. The Superconductors That Magnets Really Want: What Stands in the Way? (Superconductors for Accelerator Use: What Next and How Close is the Ideal Conductor?)

    ScienceCinema (OSTI)

    Larbalestier, David [National High Magnetic Field Laboratory] [Florida State University, Tallahassee, Florida, United States

    2010-01-08

    There are over 5000 superconducting materials but only about 5 have ever been useful for applications in magnets, while HEP, which has been so vital for the development of superconducting magnet technology has made virtually every magnet out of just one, the simple bcc alloy Nb-Ti with Tc of 9 K and upper critical field ~ 14T (at 2K). Significant demonstrations of the capability of the brittle intermetallic Nb3Sn have shown that fields of more than 15 T can be generated in dipole form. But Nb-Ti and Nb3Sn are staid, conventional superconductors, far from the cutting edge of superconducting science research where cuprates like YBa2Cu3O7-x and Bi2Sr2CaCu2Ox remain at the scientific forefront and in 2008 were joined by the recently discovered Fe-As pnictide superconductors. What could it mean to have materials for magnets with 10 times the Tc of Nb-Ti (90-120 K) and 3 or more times the critical field (100-240 T)? One enormous barrier is that higher Tc so far always means more complexity and a more localized superconducting interaction which is sensitive to local loss of superconductivity. The issue that has made the cuprate high temperature superconductors so hard to apply is that grain boundaries which form a 3D network in any practical wire form, easily acquire degraded superconducting properties. But conductors can now be made with extreme texture so that grain boundaries are minimized. Moreover almost practical conductors of Bi2Sr2CaCu2Ox and YBa2Cu3O7-x are now are in production and in late 2008 we were, at the Magnet Lab, able to make small solenoids operating at high current density in fields of 32 and almost 34 T respectively. Within the HEP community, there is enthusiasm to embrace HTS conductors for new very high field machines that could, like the Muon Collider, use fields of 30-50 T. In my talk I would like to explore the underlying science controlling such potential applications.

  6. Development and experience of large conductor cable 35-kV joints at the Los Angeles Department of Water and Power

    SciTech Connect (OSTI)

    Calderon, F.; Findon, E.J. )

    1990-01-01

    The Los Angeles Department of Water and Power (LADWP) places a high priority on developing its distribution system in the most reliable and cost-effective manner. At higher distribution voltages, such as 34.5-kV, jointing systems which are easily, consistently, and quickly installed by both utility and contracted personnel offer significant economic advantages. With increasing loads and higher load densities at LADWP, the use of 34.5-kV, cross-linked polyethylene (CLP) aluminum, 1000-kcmil cable is becoming more common to meet customer load requirements. Two methods of jointing this large conductor cable were historically used, although each method had limitations. This paper provides an overview of LADWP's distribution system, past jointing techniques, the investigation and evaluation of alternate approaches, and the field experience with the joint selected for use.

  7. Development of epitaxial AlxSc1-xN for artificially structured metal/semiconductor superlattice metamaterials

    SciTech Connect (OSTI)

    Sands, Timothy D.; Stach, Eric A.; Saha, Bivas; Saber, Sammy; Naik, Gururaj V.; Boltasseva, Alexandra; Kvam, Eric P.

    2015-02-01

    Epitaxial nitride rocksalt metal/semiconductor superlattices are emerging as a novel class of artificially structured materials that have generated significant interest in recent years for their potential application in plasmonic and thermoelectric devices. Though most nitride metals are rocksalt, nitride semiconductors in general have hexagonal crystal structure. We report rocksalt aluminum scandium nitride (Al,Sc)N alloys as the semiconducting component in epitaxial rocksalt metal/semiconductor superlattices. The AlxSc1-xN alloys when deposited directly on MgO substrates are stabilized in a homogeneous rocksalt (single) phase when x < 0.51. Employing 20 nm TiN as a seed layer on MgO substrates, the homogeneity range for stabilizing the rocksalt phase has been extended to x < 0.82 for a 120 nm film. The rocksalt AlxSc1-xN alloys show moderate direct bandgap bowing with a bowing parameter, B = 1.41 0.19 eV. The direct bandgap of metastable rocksalt AlN is extrapolated to be 4.70 0.20 eV. The tunable lattice parameter, bandgap, dielectric permittivity, and electronic properties of rocksalt AlxSc1-xN alloys enable high quality epitaxial rocksalt metal/AlxSc1-xN superlattices with a wide range of accessible metamaterials properties.

  8. Development of epitaxial AlxSc1-xN for artificially structured metal/semiconductor superlattice metamaterials

    SciTech Connect (OSTI)

    Sands, Timothy D.; Stach, Eric A.; Saha, Bivas; Saber, Sammy; Naik, Gururaj V.; Boltasseva, Alexandra; Kvam, Eric P.

    2015-02-01

    Epitaxial nitride rocksalt metal/semiconductor superlattices are emerging as a novel class of artificially structured materials that have generated significant interest in recent years for their potential application in plasmonic and thermoelectric devices. Though most nitride metals are rocksalt, nitride semiconductors in general have hexagonal crystal structure. We report rocksalt aluminum scandium nitride (Al,Sc)N alloys as the semiconducting component in epitaxial rocksalt metal/semiconductor superlattices. The AlxSc1-xN alloys when deposited directly on MgO substrates are stabilized in a homogeneous rocksalt (single) phase when x < 0.51. Employing 20 nm TiN as a seed layer on MgO substrates, the homogeneity range for stabilizing the rocksalt phase has been extended to x < 0.82 for a 120 nm film. The rocksalt AlxSc1-xN alloys show moderate direct bandgap bowing with a bowing parameter, B = 1.41 ± 0.19 eV. The direct bandgap of metastable rocksalt AlN is extrapolated to be 4.70 ± 0.20 eV. The tunable lattice parameter, bandgap, dielectric permittivity, and electronic properties of rocksalt AlxSc1-xN alloys enable high quality epitaxial rocksalt metal/AlxSc1-xN superlattices with a wide range of accessible metamaterials properties.

  9. Visible-light-induced instability in amorphous metal-oxide based TFTs for transparent electronics

    SciTech Connect (OSTI)

    Ha, Tae-Jun

    2014-10-15

    We investigate the origin of visible-light-induced instability in amorphous metal-oxide based thin film transistors (oxide-TFTs) for transparent electronics by exploring the shift in threshold voltage (V{sub th}). A large hysteresis window in amorphous indium-gallium-zinc-oxide (a-IGZO) TFTs possessing large optical band-gap (≈3 eV) was observed in a visible-light illuminated condition whereas no hysteresis window was shown in a dark measuring condition. We also report the instability caused by photo irradiation and prolonged gate bias stress in oxide-TFTs. Larger V{sub th} shift was observed after photo-induced stress combined with a negative gate bias than the sum of that after only illumination stress and only negative gate bias stress. Such results can be explained by trapped charges at the interface of semiconductor/dielectric and/or in the gate dielectric which play a role in a screen effect on the electric field applied by gate voltage, for which we propose that the localized-states-assisted transitions by visible-light absorption can be responsible.

  10. A narrow window of Rabi frequency for competition between electromagnetically induced transparency and Raman absorption

    SciTech Connect (OSTI)

    Chang, Ray-Yuan; Fang, Wei-Chia; Lee, Ming-Tsung; He, Zong-Syun; Ke, Bai-Cian; Lee, Yi-Chi; Tsai, Chin-Chun

    2010-01-15

    This investigation clarifies the transition phenomenon between the electromagnetically induced transparency (EIT) and Raman absorption in a ladder-type system of Doppler-broadened cesium vapor. A competition window of this transition was found to be as narrow as 2 MHz defined by the probe Rabi frequency. For a weak probe, the spectrum of EIT associated with quantum interference suggests that the effect of the Doppler velocity on the spectrum is negligible. When the Rabi frequency of the probe becomes comparable with the effective decay rate, an electromagnetically induced absorption (EIA) dip emerges at the center of the power broadened EIT peak. While the Rabi frequency of the probe exceeds the effective decay rate, decoherence that is generated by the intensified probe field occurs and Raman absorption dominates the interaction process, yielding a pure absorption spectrum; the Doppler velocity plays an important role in the interaction. A theory that is based on density matrix simulation, with or without the Doppler effect, can qualitatively fit the experimental data. In this work, the coherence of atom-photon interactions is created or destroyed using the probe Rabi frequency as a decoherence source.

  11. Structural stability of transparent conducting films assembled from length purified single-wall carbon nanotubes

    SciTech Connect (OSTI)

    J. M. Harris; G. R. S. Iyer; D. O. Simien; J. A. Fagan; J. Y. Huh; J. Y. Chung; S. D. Hudson; J. Obrzut; J. F. Douglas; C. M. Stafford; E. K. Hobbie

    2011-01-01

    Single-wall carbon nanotube (SWCNT) films show significant promise for transparent electronics applications that demand mechanical flexibility, but durability remains an outstanding issue. In this work, thin membranes of length purified single-wall carbon nanotubes (SWCNTs) are uniaxially and isotropically compressed by depositing them on prestrained polymer substrates. Upon release of the strain, the topography, microstructure, and conductivity of the films are characterized using a combination of optical/fluorescence microscopy, light scattering, force microscopy, electron microscopy, and impedance spectroscopy. Above a critical surface mass density, films assembled from nanotubes of well-defined length exhibit a strongly nonlinear mechanical response. The measured strain dependence reveals a dramatic softening that occurs through an alignment of the SWCNTs normal to the direction of prestrain, which at small strains is also apparent as an anisotropic increase in sheet resistance along the same direction. At higher strains, the membrane conductivities increase due to a compression-induced restoration of conductive pathways. Our measurements reveal the fundamental mode of elasto-plastic deformation in these films and suggest how it might be suppressed.

  12. Improving Transparency in the Reporting of Safeguards Implementation: FY11 Update

    SciTech Connect (OSTI)

    Toomey, Christopher; Odlaug, Christopher S.; Wyse, Evan T.

    2011-09-30

    In 2008, the Standing Advisory Group on Safeguards Implementation (SAGSI) indicated that the International Atomic Energy Agency's (IAEA) Safeguards Implementation Report (SIR) has not kept pace with the evolution of safeguards and provided the IAEA with a set of recommendations for improvement. The SIR is the primary mechanism for providing an overview of safeguards implementation in a given year and reporting on the annual safeguards findings and conclusions drawn by the Secretariat. As the IAEA transitions to State-level safeguards approaches, SIR reporting must adapt to reflect these evolutionary changes. This evolved report will better reflect the IAEA's transition to a more qualitative and information-driven approach, based upon State-as-a-whole considerations. This paper applies SAGSI's recommendations to the development of multiple models for an evolved SIR and finds that an SIR repurposed as a 'safeguards portal' could significantly enhance information delivery, clarity, and transparency. In addition, this paper finds that the 'portal concept' also appears to have value as a standardized information presentation and analysis platform for use by Country Officers, for continuity of knowledge purposes, and the IAEA Secretariat in the safeguards conclusion process. Accompanying this paper is a fully functional prototype of the 'portal' concept, built using commercial software and IAEA Annual Report data and available for viewing at http://safeguardsportal.pnnl.gov.

  13. Preparation of transparent conducting B-doped ZnO films by vacuum arc plasma evaporation

    SciTech Connect (OSTI)

    Miyata, Toshihiro; Honma, Yasunori; Minami, Tadatsugu

    2007-07-15

    Highly transparent and conductive B-doped ZnO (BZO) thin films have been prepared by a newly developed vacuum arc plasma evaporation method that provided high-rate film depositions using sintered BZO pellets and fragments. The obtained electrical and optical properties of the deposited BZO thin films were considerably affected by the deposition conditions as well as the preparation method of the BZO pellets and fragments used. The lowest thin film resistivity was obtained with a B doping content [B/(B+Zn) atomic ratio] of approximately 1 at. %. A resistivity as low as 5x10{sup -4} {omega} cm and an average transmittance above about 80% in the wavelength range of 400-1300 nm were obtained in BZO films prepared with a thickness above approximately 400 nm at a substrate temperature of 200 deg. C. In addition, a low resistivity of 7.97x10{sup -4} {omega} cm and average transmittances above about 80% in the visible wavelength range were obtained in a BZO film prepared at a substrate temperature of 100 deg. C and an O{sub 2} gas flow rate of 10 SCCM (SCCM denotes cubic centimeter per minute at STP). The deposition rate of BZO films was typically 170 nm/min with a cathode plasma power of 4.5 kW.

  14. Towards more transparent and reproducible omics studies through a common metadata checklist and data publications

    SciTech Connect (OSTI)

    Kolker, Eugene; Ozdemir, Vural; Martens , Lennart; Hancock, William S.; Anderson, Gordon A.; Anderson, Nathaniel; Aynacioglu, Sukru; Baranova, Ancha; Campagna, Shawn R.; Chen, Rui; Choiniere, John; Dearth, Stephen P.; Feng, Wu-Chun; Ferguson, Lynnette; Fox, Geoffrey; Frishman, Dmitrij; Grossman, Robert; Heath, Allison; Higdon, Roger; Hutz, Mara; Janko, Imre; Jiang, Lihua; Joshi, Sanjay; Kel, Alexander; Kemnitz, Joseph W.; Kohane, Isaac; Kolker, Natali; Lancet, Doron; Lee, Elaine; Li, Weizhong; Lisitsa, Andrey; Llerena, Adrian; MacNealy-Koch, Courtney; Marhsall, Jean-Claude; Masuzzo, Paolo; May, Amanda; Mias, George; Monroe, Matthew E.; Montague, Elizabeth; Monney, Sean; Nesvizhskii, Alexey; Noronha, Santosh; Omenn, Gilbert; Rajasimha, Harsha; Ramamoorthy, Preveen; Sheehan, Jerry; Smarr, Larry; Smith, Charles V.; Smith, Todd; Snyder, Michael; Rapole, Srikanth; Srivastava, Sanjeeva; Stanberry, Larissa; Stewart, Elizabeth; Toppo, Stefano; Uetz, Peter; Verheggen, Kenneth; Voy, Brynn H.; Warnich, Louise; Wilhelm, Steven W.; Yandl, Gregory

    2014-01-01

    Biological processes are fundamentally driven by complex interactions between biomolecules. Integrated high-throughput omics studies enable multifaceted views of cells, organisms, or their communities. With the advent of new post-genomics technologies omics studies are becoming increasingly prevalent yet the full impact of these studies can only be realized through data harmonization, sharing, meta-analysis, and integrated research,. These three essential steps require consistent generation, capture, and distribution of the metadata. To ensure transparency, facilitate data harmonization, and maximize reproducibility and usability of life sciences studies, we propose a simple common omics metadata checklist. The proposed checklist is built on the rich ontologies and standards already in use by the life sciences community. The checklist will serve as a common denominator to guide experimental design, capture important parameters, and be used as a standard format for stand-alone data publications. This omics metadata checklist and data publications will create efficient linkages between omics data and knowledge-based life sciences innovation and importantly, allow for appropriate attribution to data generators and infrastructure science builders in the post-genomics era. We ask that the life sciences community test the proposed omics metadata checklist and data publications and provide feedback for their use and improvement.

  15. High performance transparent conducting films of cadmium indate prepared by RF sputtering

    SciTech Connect (OSTI)

    Coutts, T.J.; Wu, X.; Mulligan, W.P.

    1996-12-31

    The authors are examining various spinel-structured thin films (e.g., Cd{sub 2}SnO{sub 4}, Zn{sub 2}SnO{sub 4}) to develop higher-quality transparent conducting oxides (TCO) than more conventional materials such as indium tin oxide. Here, they report on cadmium indate (CdIn{sub 2}O{sub 4}, CIO), which is another member of this family. Thin films of CIO were deposited by radio-frequency (RF) magnetron sputtering, from an oxide target, onto borosilicate glass substrates. The variables included the substrate temperature, sputtering gas composition, and pressure. Film properties were measured before and after heat treatment. Characterization involved Hall effect measurements, optical and infrared spectrophotometry, X-ray diffraction, and atomic-force microscopy. Film resistivities as low as 2.3 {times} 10{sup {minus}4} {Omega}cm were achieved for a film thickness of 0.55 {micro}m. The transmittance was 90% in the visible region of the spectrum, without correction for substrate losses and without an anti-reflection coating. The plasma resonance occurred at longer wavelengths than for other materials and this, with a bandgap of approximately 3.1 eV, presents a wide window for optical transmittance. The highest mobility was 54 cm{sup 2} V{sup {minus}1} s{sup {minus}1} and the highest carrier concentration was 7.5 {times} 10{sup 20} cm{sup {minus}3}.

  16. Growth of oriented vanadium pentaoxide nanostructures on transparent conducting substrates and their applications in photocatalysis

    SciTech Connect (OSTI)

    Liu, Hongjiang; Gao, Yanfeng; Zhou, Jiadong; Liu, Xinling; Chen, Zhang; Cao, Chuanxiang; Luo, Hongjie; Kanehira, Minoru

    2014-06-01

    A novel, hydrothermal and hard-template-free method was developed for the first time to grow oriented, single-crystalline monoclinic VO{sub 2} (B) flower-like nanorod films on transparent conductive fluorine-doped tin oxide (FTO) substrates. The length and morphology of the nanorods can be tuned by changing the growth parameters, such as growth time and initial precursor concentration. The flower-like V{sub 2}O{sub 5} films were obtained after post-calcination treatment of VO{sub 2} (B) films. The photocatalytic activity of V{sub 2}O{sub 5} films was investigated by the degradation of methylene blue (MB) under UV and visible light. The prepared V{sub 2}O{sub 5} film exhibited good photocatalytic performance (74.6% and 63% under UV and visible light for 210 min, respectively) and more practical application in industry. - Graphical abstract: Flower nanostructured vanadium oxide film was prepared by hydrothermal reaction for photocatalysis application. - Highlights: Monoclinic VO{sub 2} nanorod array and flower-like nanostructure were directly grown on FTO substrate by hydrothermal reaction. The growth mechanism was analyzed by FESEM at different time. V{sub 2}O{sub 5} flower-like nanostructure film was obtained after calcining VO{sub 2} film. V{sub 2}O{sub 5} film exhibited good light activity and potential application in photocatalysis.

  17. Processing of transparent polycrystalline AlON:Ce3+ scintillators

    SciTech Connect (OSTI)

    Chen, Ching -Fong; Yang, Pin; King, Graham; Tegtmeier, Eric L.

    2015-10-23

    A new polycrystalline ceramic scintillator is reported for potential use in radiation detection and medical imaging applications. The goal was to develop cerium-activated aluminum oxynitride (AlON:Ce3+) ceramics, which can be produced using ceramic processes in comparison to the high-cost, low-yield single-crystal growth technique. A phase pure AlON:Ce3+ powder with cubic symmetry was successfully synthesized at high temperature under a reducing atmosphere to convert Ce4+ to Ce3+ in the solid solution. We explored two different activator concentrations (0.5 and 1.0 mol%). Fully dense and transparent AlON:Ce3+ ceramics were produced by a liquid-phase-assisted pressureless sintering. The crystal field splitting around the Ce3+ activator in the AlON was comparable to the splitting induced by Br₋ and the Cl₋ ligands, which produced an emission spectrum perfectly matching the maximum quantum efficiency range of the photomultiplier tube for radiation detection. Both optical excitation and radiation ionizations in AlON:Ce3+ were demonstrated. Lastly, challenges and mechanisms related to the radioluminescence efficiency are discussed.

  18. TRANSMISSION AND EMISSION OF SOLAR ENERGETIC PARTICLES IN SEMI-TRANSPARENT SHOCKS

    SciTech Connect (OSTI)

    Kocharov, Leon; Usoskin, Ilya; Laitinen, Timo; Vainio, Rami

    2014-06-01

    While major solar energetic particle (SEP) events are associated with coronal mass ejection (CME)-driven shocks in solar wind, accurate SEP measurements reveal that more than one component of energetic ions exist in the beginning of the events. Solar electromagnetic emissions, including nuclear gamma-rays, suggest that high-energy ions could also be accelerated by coronal shocks, and some of those particles could contribute to SEPs in interplanetary space. However, the CME-driven shock in solar wind is thought to shield any particle source beneath the shock because of the strong scattering required for the diffusive shock acceleration. In this Letter, we consider a shock model that allows energetic particles from the possible behind-shock source to appear in front of the shock simultaneously with SEPs accelerated by the shock itself. We model the energetic particle transport in directions parallel and perpendicular to the magnetic field in a spherical shock expanding through the highly turbulent magnetic sector with an embedded quiet magnetic tube, which makes the shock semi-transparent for energetic particles. The model energy spectra and time profiles of energetic ions escaping far upstream of the shock are similar to the profiles observed during the first hour of some gradual SEP events.

  19. High performance transparent conducting films of cadmium indate prepared by RF sputtering

    SciTech Connect (OSTI)

    Coutts, T.J.; Wu, X.; Mulligan, W.P.

    1996-04-01

    The authors are examining various spinel-structured thin films (e.g., Cd{sub 2}SnO{sub 4}, Zn{sub 2}SnO{sub 4}) to develop higher-quality transparent conducting oxides (TCO) than more conventional materials such as indium tin oxide. Here, the authors report on cadmium indate (CdIn{sub 2}O{sub 4}, CIO), which is another member of this family. Thin films of CIO were deposited by radio-frequency (RF) magnetron sputtering, from an oxide target, onto borosilicate glass substrates. The variables included the substrate temperature, sputtering gas composition, and pressure. Film properties were measured before and after heat treatment. Characterization involved Hall effect measurements, optical and infrared spectrophotometry, X-ray diffraction, and atomic-force microscopy. Film resistivities as low as 2.3 {times} 10{sup {minus}4} {Omega} cm were achieved for a film thickness of 0.55 {micro}m. The transmittance was 90% in the visible region of the spectrum, without correction for substrate losses and without an anti-reflection coating. The plasma resonance occurred at longer wavelengths than for other materials and this, with a bandgap of approximately 3.1 eV, presents a wide window for optical transmittance. The highest mobility was 54 cm{sup 2} V{sup {minus}1} s{sup {minus}1} and the highest carrier concentration was 7.5 {times} 10{sup 20} cm{sup {minus}3}.

  20. Carrier Selective, Passivated Contacts for High Efficiency Silicon Solar Cells based on Transparent Conducting Oxides

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Young, David L.; Nemeth, William; Grover, Sachit; Norman, Andrew; Yuan, Hao-Chih; Lee, Benjamin G.; LaSalvia, Vincenzo; Stradins, Paul

    2014-01-01

    We describe the design, fabrication and results of passivated contacts to n-type silicon utilizing thin SiO2 and transparent conducting oxide layers. High temperature silicon dioxide is grown on both surfaces of an n-type wafer to a thickness <50 Å, followed by deposition of tin-doped indium oxide (ITO) and a patterned metal contacting layer. As deposited, the thin-film stack has a very high J0,contact, and a non-ohmic, high contact resistance. However, after a forming gas anneal, the passivation quality and the contact resistivity improve significantly. The contacts are characterized by measuring the recombination parameter of the contact (J0,contact) and the specificmore » contact resistivity (ρcontact) using a TLM pattern. The best ITO/SiO2 passivated contact in this study has J0,contact = 92.5 fA/cm2 and ρcontact = 11.5 mOhm-cm2. These values are placed in context with other passivating contacts using an analysis that determines the ultimate efficiency and the optimal area fraction for contacts for a given set of (J0,contact, ρcontact) values. The ITO/SiO2 contacts are found to have a higher J0,contact, but a similar ρcontact compared to the best reported passivated contacts.« less

  1. A transparent Pyrex ?-reactor for combined in situ optical characterization and photocatalytic reactivity measurements

    SciTech Connect (OSTI)

    Dionigi, F.; Hansen, O.; Department of Micro- and Nanotechnology, Nanotech, Building 345 East, Technical University of Denmark, DTU, DK-2800 Kgs. Lyngby ; Nielsen, M. G.; Chorkendorff, I.; Vesborg, P. C. K.; Pedersen, T.

    2013-10-15

    A new Pyrex-based ?-reactor for photocatalytic and optical characterization experiments is presented. The reactor chamber and gas channels are microfabricated in a thin poly-silicon coated Pyrex chip that is sealed with a Pyrex lid by anodic bonding. The device is transparent to light in the UV-vis-near infrared range of wavelengths (photon energies between ?0.4 and ?4.1 eV). The absorbance of a photocatalytic film obtained with a light transmission measurement during a photocatalytic reaction is presented as a proof of concept of a photocatalytic reactivity measurement combined with in situ optical characterization. Diffuse reflectance measurements of highly scattering photocatalytic nanopowders in a sealed Pyrex ?-reactor are also possible using an integrating sphere as shown in this work. These experiments prove that a photocatalyst can be characterized with optical techniques after a photocatalytic reaction without removing the material from the reactor. The catalyst deposited in the cylindrical reactor chamber can be illuminated from both top and bottom sides and an example of application of top and bottom illumination is presented.

  2. Investigation of Some Transparent Metal Oxides as Damp Heat Protective Coating for CIGS Solar Cells: Preprint

    SciTech Connect (OSTI)

    Pern, F. J.; Yan, F.; Zaaunbrecher, B.; To, B.; Perkins, J.; Noufi, R.

    2012-10-01

    We investigated the protective effectiveness of some transparent metal oxides (TMO) on CIGS solar cell coupons against damp heat (DH) exposure at 85oC and 85% relative humidity (RH). Sputter-deposited bilayer ZnO (BZO) with up to 0.5-um Al-doped ZnO (AZO) layer and 0.2-um bilayer InZnO were used as 'inherent' part of device structure on CdS/CIGS/Mo/SLG. Sputter-deposited 0.2-um ZnSnO and atomic layer deposited (ALD) 0.1-um Al2O3 were used as overcoat on typical BZO/CdS/CIGS/Mo/SLG solar cells. The results were all negative -- all TMO-coated CIGS cells exhibited substantial degradation in DH. Combining the optical photographs, PL and EL imaging, SEM surface micro-morphology, coupled with XRD, I-V and QE measurements, the causes of the device degradations are attributed to hydrolytic corrosion, flaking, micro-cracking, and delamination induced by the DH moisture. Mechanical stress and decrease in crystallinity (grain size effect) could be additional degrading factors for thicker AZO grown on CdS/CIGS.

  3. Low-resistivity photon-transparent window attached to photo-sensitive silicon detector

    DOE Patents [OSTI]

    Holland, Stephen Edward

    2000-02-15

    The invention comprises a combination of a low resistivity, or electrically conducting, silicon layer that is transparent to long or short wavelength photons and is attached to the backside of a photon-sensitive layer of silicon, such as a silicon wafer or chip. The window is applied to photon sensitive silicon devices such as photodiodes, charge-coupled devices, active pixel sensors, low-energy x-ray sensors and other radiation detectors. The silicon window is applied to the back side of a photosensitive silicon wafer or chip so that photons can illuminate the device from the backside without interference from the circuit printed on the frontside. A voltage sufficient to fully deplete the high-resistivity photosensitive silicon volume of charge carriers is applied between the low-resistivity back window and the front, patterned, side of the device. This allows photon-induced charge created at the backside to reach the front side of the device and to be processed by any circuitry attached to the front side. Using the inventive combination, the photon sensitive silicon layer does not need to be thinned beyond standard fabrication methods in order to achieve full charge-depletion in the silicon volume. In one embodiment, the inventive backside window is applied to high resistivity silicon to allow backside illumination while maintaining charge isolation in CCD pixels.

  4. Static and dynamic behavior of ultrathin cobalt nanowires embedded in transparent matrix

    SciTech Connect (OSTI)

    Roussigné, Y.; Chérif, S. M.; Stashkevich, A. A.; Vidal, F.; Zheng, Y.

    2015-12-21

    Two self-assembly of ultrathin Co nanowires (NWs) embedded in a CeO{sub 2} matrix was grown on SrTiO{sub 3}(001) and oxidized Si(001) substrates. A common feature of the two arrays of NWs is the small diameter of the wires, falling in the 4–5 nm range. Combined with their length, the aspect ratio is large enough to ensure large magnetostatic anisotropy with an easy axis along the axis of the nanowires as revealed by magnetometry measurements. The Brillouin light scattering technique has been used to investigate the behavior of the spin waves under a field perpendicular to the NWs axes. The transparency of the matrix ensures the penetration of the probing light inside the sample. Importantly, Brillouin light scattering from the magnetic modes obeys the volume Bragg condition, which is characteristic of the configuration in which the observed modes are propagating along the nanowires and due to their very small diameter are nearly constant across the section. Both series of experimental results are satisfactorily analyzed by means of a single analytical model, based on a mean-field approach, assuming the presence at remanence of two populations of NWs with up and down magnetizations and including the dipolar coupling between the cylinders.

  5. See-through amorphous silicon solar cells with selectively transparent and conducting photonic crystal back reflectors for building integrated photovoltaics

    SciTech Connect (OSTI)

    Yang, Yang; OBrien, Paul G.; Materials Chemistry Research Group, Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario M5S 3H6 ; Ozin, Geoffrey A. E-mail: kherani@ecf.utoronto.ca; Kherani, Nazir P. E-mail: kherani@ecf.utoronto.ca

    2013-11-25

    Thin semi-transparent hydrogenated amorphous silicon (a-Si:H) solar cells with selectively transparent and conducting photonic crystal (STCPC) back-reflectors are demonstrated. Short circuit current density of a 135?nm thick a-Si:H cell with a given STCPC back-reflector is enhanced by as much as 23% in comparison to a reference cell with an ITO film functioning as its rear contact. Concurrently, solar irradiance of 295?W/m{sup 2} and illuminance of 3480 lux are transmitted through the cell with a given STCPC back reflector under AM1.5 Global tilt illumination, indicating its utility as a source of space heating and lighting, respectively, in building integrated photovoltaic applications.

  6. Infrared-optical spectroscopy of transparent conducting perovskite (La,Ba)SnO{sub 3} thin films

    SciTech Connect (OSTI)

    Seo, Dongmin; Yu, Kwangnam; Jun Chang, Young; Choi, E. J.; Sohn, Egon; Hoon Kim, Kee

    2014-01-13

    We have performed optical transmission, reflection, spectroscopic ellipsometry, and Hall effect measurements on the electron-doped La{sub x}Ba{sub 1x}SnO{sub 3} (x?=?0.04) transparent thin films. From the infrared Drude response and plasma frequency analysis we determine the effective mass of the conducting electron m*?=?0.35m{sub 0}. In the visible-UV region the optical band gap shifts to high energy in (La,Ba)SnO{sub 3} by 0.18?eV compared with undoped BaSnO{sub 3} which, in the context of the Burstein-Moss analysis, is consistent with the infrared-m*. m* of BaSnO{sub 3} is compared with other existing transparent conducting oxides (TCO), and implication on search for high-mobility TCO compounds is discussed.

  7. Transparent selective illumination means suitable for use in optically activated electrical switches and optically activated electrical switches constructed using same

    DOE Patents [OSTI]

    Wilcox, R.B.

    1991-09-10

    A planar transparent light conducting means and an improved optically activated electrical switch made using the novel light conducting means are disclosed. The light conducting means further comprise light scattering means on one or more opposite planar surfaces thereof to transmit light from the light conducting means into adjacent media and reflective means on other surfaces of the light conducting means not containing the light scattering means. The optically activated electrical switch comprises at least two stacked photoconductive wafers, each having electrodes formed on both surfaces thereof, and separated by the planar transparent light conducting means. The light scattering means on the light conducting means face surfaces of the wafers not covered by the electrodes to transmit light from the light conducting means into the photoconductive wafers to uniformly illuminate and activate the switch. 11 figures.

  8. Transparent selective illumination means suitable for use in optically activated electrical switches and optically activated electrical switches constructed using same

    DOE Patents [OSTI]

    Wilcox, Russell B.

    1991-01-01

    A planar transparent light conducting means and an improved optically activated electrical switch made using the novel light conducting means are disclosed. The light conducting means further comprise light scattering means on one or more opposite planar surfaces thereof to transmit light from the light conducting means into adjacent media and reflective means on other surfaces of the light conducting means not containing the light scattering means. The optically activated electrical switch comprises at least two stacked photoconductive wafers, each having electrodes formed on both surfaces thereof, and separated by the planar transparent light conducting means. The light scattering means on the light conducting means face surfaces of the wafers not covered by the electrodes to transmit light from the light conducting means into the photoconductive wafers to uniformly illuminate and activate the switch.

  9. Application of Single Wall Carbon Nanotubes as Transparent Electrodes in Cu(In,Ga)Se2-Based Solar Cells: Preprint

    SciTech Connect (OSTI)

    Contreras, M.; Barnes, T.; van de Lagemaat, J.; Rumbles, G.; Coutts, T. J.; Weeks, C.; Glatkowski, P.; Levitsky, I.; Peltola, J.

    2006-05-01

    We present a new thin-film solar cell structure in which the traditional transparent conductive oxide electrode (ZnO) is replaced by a transparent conductive coating consisting of a network of bundled single-wall carbon nanotubes. Optical transmission properties of these coatings are presented in relation to their electrical properties (sheet resistance), along with preliminary solar cell results from devices made using CuIn1-xGaxSe2 thin-film absorber materials. Achieving an energy conversion efficiency of >12% and a quantum efficiency of {approx}80% demonstrate the feasibility of the concept. A discussion of the device structures will be presented considering the physical properties of the new electrodes comparing current-voltage results from the new solar cell structure and those from standard ZnO/CdS/Cu(In,Ga)Se2/Mo solar cells.

  10. Optimization of transparent and reflecting electrodes for amorphous silicon solar cells. Annual subcontract report, April 1, 1994--March 31, 1995

    SciTech Connect (OSTI)

    Gordon, R.G.

    1995-10-01

    Transparent and reflecting electrodes are important parts of the structure of amorphous silicon solar cells. We report improved methods for depositing zinc oxide, deposition of tin nitride as a potential reflection-enhancing diffusion barrier between the a-Si and back metal electrodes. Highly conductive and transparent fluorine-doped zinc oxide was successfully produced on small areas by atmospheric pressure CVD from a less hazardous zinc precursor, zinc acetylacetonate. The optical properties measured for tin nitride showed that the back-reflection would be decreased if tin nitride were used instead of zinc oxide as a barrier layer over silver on aluminum. Niobium-doped titanium dioxide was produced with high enough electrical conductivity so that normal voltages and fill factors were obtained for a-Si cells made on it.

  11. A new architecture as transparent electrodes for solar and IR applications based on photonic structures via soft lithography

    SciTech Connect (OSTI)

    Kuang, Ping

    2011-05-15

    Transparent conducting electrodes with the combination of high optical transmission and good electrical conductivity are essential for solar energy harvesting and electric lighting devices. Currently, indium tin oxide (ITO) is used because ITO offers relatively high transparency (>80%) to visible light and low sheet resistance (R{sub s} = 10 ohms/square ({Omega}#2;/?)) for electrical conduction. However, ITO is costly due to limited indium reserves, and it is brittle. These disadvantages have motivated the search for other conducting electrodes with similar or better properties. There has been research on a variety of electrode structures involving carbon nanotube networks, graphene films, nanowire and nanopatterned meshes and grids. Due to their novel characteristics in light manipulation and collection, photonic crystal structures show promise for further improvement. Here, we report on a new architecture consisting of nanoscale high aspect ratio metallic photonic structures as transparent electrodes fabricated via a combination of processes. For (Au) and silver (Ag) structures, the visible light transmission can reach as high as 80%, and the sheet resistance of the structure can be as low as 3.2{Omega}#2;/?. The optical transparency of the high aspect ratio metal structures at visible wavelength range is comparable to that of ITO glass, while their sheet resistance is more than 3 times lower, which indicates a much higher electrical conductivity of the metal structures. Furthermore, the high aspect ratio metal structures have very high infrared (IR) reflection (90%) for the transverse magnetic (TM) mode, which can lead to the development of fabrication of metallic structures as IR filters for heat control applications. Investigations of interdigitated structures based on the high aspect ratio metal electrodes are ongoing to study the feasibility in smart window applications in light transmission modulation.

  12. Optically transparent and environmentally durable superhydrophobic coating based on functionalized SiO2 nanoparticles

    SciTech Connect (OSTI)

    Schaeffer, Daniel A.; Polizos, Georgios; Smith, D. Barton; Lee, Dominic F.; Hunter, Scott R.; Datskos, Panos G.

    2015-01-09

    Optical surfaces such as mirrors and windows that are exposed to outdoor environmental conditions are susceptible to dust buildup and water condensation. The application of transparent superhydrophobic coatings on optical surfaces can improve outdoor performance via a self-cleaning effect similar to the Lotus effect. The contact angle (CA) of water droplets on a typical hydrophobic flat surface varies from 100° to 120°. Adding roughness or microtexture to a hydrophobic surface leads to an enhancement of hydrophobicity and the CA can be increased to a value in the range of 16≥0° to 175°. This result is remarkable because such behavior cannot be explained using surface chemistry alone. When surface features are on the order of 100 nm or smaller, surfaces exhibit superhydrophobic behavior and maintain their optical transparency. In this work we discuss our results on transparent superhydrophobic coatings that can be applied across large surface areas. We have used functionalized silica nanoparticles to coat various optical elements and have measured the contact angle and optical transmission between 190 to 1100 nm on these elements. The functionalized silica nanoparticles were dissolved in a solution of the solvents isopropyl alcohol and 4-chlorobenzotrifluoride (PCBTF) and a proprietary ceramic binder (Cerakote ). Finally, this solution was spin-coated onto a variety of test glass substrates, and following a curing period of about 30 minutes, these coatings exhibited superhydrophobic behavior with a static CA ≥160°.

  13. Concepts and Strategies for Transparency Monitoring of Nuclear Materials at the Back End of the Fuel/Weapons Cycle

    SciTech Connect (OSTI)

    COSTIN, LAURENCE; DAVIES, PETER; PREGENZER, ARIAN L.

    1999-10-01

    Representatives of the Department of Energy, the national laboratories, the Waste Isolation Pilot Plant (WIPP), and others gathered to initiate the development of broad-based concepts and strategies for transparency monitoring of nuclear materials at the back end of the fuel/weapons cycle, including both geologic disposal and monitored retrievable storage. The workshop focused on two key questions: ''Why should we monitor?'' and ''What should we monitor?'' These questions were addressed by identifying the range of potential stakeholders, concerns that stakeholders may have, and the information needed to address those concerns. The group constructed a strategic framework for repository transparency implementation, organized around the issues of safety (both operational and environmental), diversion (assuring legitimate use and security), and viability (both political and economic). Potential concerns of the international community were recognized as the possibility of material diversion, the multinational impacts of potential radionuclide releases, and public and political perceptions of unsafe repositories. The workshop participants also identified potential roles that the WIPP may play as a monitoring technology development and demonstration test-bed facility. Concepts for WIPP'S potential test-bed role include serving as (1) an international monitoring technology and development testing facility, (2) an international demonstration facility, and (3) an education and technology exchange center on repository transparency technologies.

  14. Dielectric-wall linear accelerator with a high voltage fast rise time switch that includes a pair of electrodes between which are laminated alternating layers of isolated conductors and insulators

    DOE Patents [OSTI]

    Caporaso, George J.; Sampayan, Stephen E.; Kirbie, Hugh C.

    1998-01-01

    A dielectric-wall linear accelerator is improved by a high-voltage, fast rise-time switch that includes a pair of electrodes between which are laminated alternating layers of isolated conductors and insulators. A high voltage is placed between the electrodes sufficient to stress the voltage breakdown of the insulator on command. A light trigger, such as a laser, is focused along at least one line along the edge surface of the laminated alternating layers of isolated conductors and insulators extending between the electrodes. The laser is energized to initiate a surface breakdown by a fluence of photons, thus causing the electrical switch to close very promptly. Such insulators and lasers are incorporated in a dielectric wall linear accelerator with Blumlein modules, and phasing is controlled by adjusting the length of fiber optic cables that carry the laser light to the insulator surface.

  15. Dielectric-wall linear accelerator with a high voltage fast rise time switch that includes a pair of electrodes between which are laminated alternating layers of isolated conductors and insulators

    DOE Patents [OSTI]

    Caporaso, G.J.; Sampayan, S.E.; Kirbie, H.C.

    1998-10-13

    A dielectric-wall linear accelerator is improved by a high-voltage, fast rise-time switch that includes a pair of electrodes between which are laminated alternating layers of isolated conductors and insulators. A high voltage is placed between the electrodes sufficient to stress the voltage breakdown of the insulator on command. A light trigger, such as a laser, is focused along at least one line along the edge surface of the laminated alternating layers of isolated conductors and insulators extending between the electrodes. The laser is energized to initiate a surface breakdown by a fluence of photons, thus causing the electrical switch to close very promptly. Such insulators and lasers are incorporated in a dielectric wall linear accelerator with Blumlein modules, and phasing is controlled by adjusting the length of fiber optic cables that carry the laser light to the insulator surface. 12 figs.

  16. CKow -- A More Transparent and Reliable Model for Chemical Transfer to Meat and Milk

    SciTech Connect (OSTI)

    Rosenbaum, Ralph K.; McKone, Thomas E.; Jolliet, Olivier

    2009-03-01

    The objective of this study is to increase the understanding and transparency of chemical biotransfer modeling into meat and milk and explicitly confront the uncertainties in exposure assessments of chemicals that require such estimates. In cumulative exposure assessments that include food pathways, much of the overall uncertainty is attributable to the estimation of transfer into biota and through food webs. Currently, the most commonly used meat and milk-biotransfer models date back two decades and, in spite of their widespread use in multimedia exposure models few attempts have been made to advance or improve the outdated and highly uncertain Kow regressions used in these models. Furthermore, in the range of Kow where meat and milk become the dominant human exposure pathways, these models often provide unrealistic rates and do not reflect properly the transfer dynamics. To address these issues, we developed a dynamic three-compartment cow model (called CKow), distinguishing lactating and non-lactating cows. For chemicals without available overall removal rates in the cow, a correlation is derived from measured values reported in the literature to predict this parameter from Kow. Results on carry over rates (COR) and biotransfer factors (BTF) demonstrate that a steady-state ratio between animal intake and meat concentrations is almost never reached. For meat, empirical data collected on short term experiments need to be adjusted to provide estimates of average longer term behaviors. The performance of the new model in matching measurements is improved relative to existing models--thus reducing uncertainty. The CKow model is straight forward to apply at steady state for milk and dynamically for realistic exposure durations for meat COR.

  17. Ag-Pd-Cu alloy inserted transparent indium tin oxide electrodes for organic solar cells

    SciTech Connect (OSTI)

    Kim, Hyo-Joong; Seo, Ki-Won; Kim, Han-Ki; Noh, Yong-Jin; Na, Seok-In

    2014-09-01

    The authors report on the characteristics of Ag-Pd-Cu (APC) alloy-inserted indium tin oxide (ITO) films sputtered on a glass substrate at room temperature for application as transparent anodes in organic solar cells (OSCs). The effect of the APC interlayer thickness on the electrical, optical, structural, and morphological properties of the ITO/APC/ITO multilayer were investigated and compared to those of ITO/Ag/ITO multilayer electrodes. At the optimized APC thickness of 8 nm, the ITO/APC/ITO multilayer exhibited a resistivity of 8.55 × 10{sup −5} Ω cm, an optical transmittance of 82.63%, and a figure-of-merit value of 13.54 × 10{sup −3} Ω{sup −1}, comparable to those of the ITO/Ag/ITO multilayer. Unlike the ITO/Ag/ITO multilayer, agglomeration of the metal interlayer was effectively relieved with APC interlayer due to existence of Pd and Cu elements in the thin region of the APC interlayer. The OSCs fabricated on the ITO/APC/ITO multilayer showed higher power conversion efficiency than that of OSCs prepared on the ITO/Ag/ITO multilayer below 10 nm due to the flatness of the APC layer. The improved performance of the OSCs with ITO/APC/ITO multilayer electrodes indicates that the APC alloy interlayer prevents the agglomeration of the Ag-based metal interlayer and can decrease the thickness of the metal interlayer in the oxide-metal-oxide multilayer of high-performance OSCs.

  18. Metallographic autopsies of full-scale ITER prototype cable-in-conduit conductors after full cyclic testing in SULTAN: II. Significant reduction of strand movement and strand damage in short twist pitch CICCs

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sanabria, Charlos; Lee, Peter J.; Starch, William; Devred, Arnaud; Larbalestier, David C.

    2015-10-14

    Prototype cable in conduit conductors (CICCs) destined for use in the Toroidal Field (TF) and Central Solenoid (CS) coils of the ITER experimental fusion reactor underwent severe cyclic loading in the SULTAN facility. Their autopsies revealed significant and permanent transverse strand migration due to the large Lorentz forces of the SULTAN test. The movement resulted in a 3 7% void fraction increase on the Low Pressure (LP) side of the longer twist pitch CICCs. However, short twist pitch conductors exhibited less than 1% void fraction increase in the LP side, as well as a complete absence of the Nb3Sn filamentmore » fractures observed in the longer twist pitch conductors. We report here a detailed strand to cable analysis of short and longer “baseline” twist pitch CICCs. It was found that the use of Internal Tin strands in the longer “baseline” twist pitch CICCs can be beneficial possibly because of their superior stiffness—which better resist strand movement—while the use of Bronze Process strands showed more movement and poorer cyclic test performance. This was not the case for the short twist pitch CICC. Such conductor design seems to work well with both strand types. But it was found that despite the absence of filament fractures, the short twist pitch CICC made from the Internal Tin strands studied here developed severe strand distortion during cabling which resulted in diffusion barrier breaks and Sn contamination of the Cu stabilizer during the heat treatment. Furthermore, the short twist pitch CICC made from Bronze Process strands preserved diffusion barrier integrity.« less

  19. Nuclear Transparency and Single Particle Spectral Functions from Quasielastic A(e,e'p) Reactions up to Q2=8.1 GeV2

    SciTech Connect (OSTI)

    David McKee

    2003-05-01

    High statistics elastic and quasielastic scattering measurements were performed on hydrogen, deuterium, carbon, and iron at squared momentum transfers up to 8.1 GeV2. Both the nuclear transparency and the single particle spectral functions were extracted by means of comparison with a Plane- Wave Impulse Approximation calculation. Our data provide no evidence of the onset of color transparency within our kinematic range.

  20. Ultraviolet laser crystallized ZnO:Al films on sapphire with high Hall mobility for simultaneous enhancement of conductivity and transparency

    SciTech Connect (OSTI)

    Nian, Qiong; Zhang, Martin Y.; Schwartz, Bradley D.; Cheng, Gary J.

    2014-05-19

    One of the most challenging issues in transparent conductive oxides (TCOs) is to improve their conductivity without compromising transparency. High conductivity in TCO films often comes from a high carrier concentration, which is detrimental to transparency due to free carrier absorption. Here we show that UV laser crystallization (UVLC) of aluminum-doped ZnO (AZO) films prepared by pulsed laser deposition on sapphire results in much higher Hall mobility, allowing relaxation of the constraints of the conductivity/transparency trade-off. X-ray diffraction patterns and morphological characterizations show grain growth and crystallinity enhancement during UVLC, resulting in less film internal imperfections. Optoelectronic measurements show that UVLC dramatically improves the electron mobility, while the carrier concentration decreases which in turn simultaneously increases conductivity and transparency. AZO films under optimized UVLC achieve the highest electron mobility of 79 cm{sup 2}/V s at a low carrier concentration of 7.9 × 10{sup +19} cm{sup −3}. This is realized by a laser crystallization induced decrease of both grain boundary density and electron trap density at grain boundaries. The infrared (IR) to mid-IR range transmittance spectrum shows UVLC significantly enhances the AZO film transparency without compromising conductivity.

  1. Low-Cost, Highly Transparent Flexible low-e Coating Film to Enable Electrochromic Windows with Increased Energy Savings

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Berland, bberland@itnes.com ITN Energy Systems Low-Cost, Highly Transparent Flexible low-e Coating Film to Enable Electrochromic Windows with Increased Energy Savings 2014 Building Technologies Office Peer Review 2 Project Summary Timeline: Start date: October 1, 2013 Planned end date: September 30, 2014 Key Milestones 1.Low-e Film: 90% T,vis & R,ir (100 cm 2 ) (Q2) 2.Low-e Film: 90% T,vis & R,ir (2m long, %T,%R variation < 2% cross web) (Q3) 3.Demonstrate Low-e/EC Film (Q3) Budget:

  2. Electromagnetically induced transparency with large delay-bandwidth product induced by magnetic resonance near field coupling to electric resonance

    SciTech Connect (OSTI)

    Li, Hai-ming; Liu, Shao-bin Liu, Si-yuan; Zhang, Hai-feng; Bian, Bo-rui; Kong, Xiang-kun; Wang, Shen-yun

    2015-03-16

    In this paper, we numerically and experimentally demonstrate electromagnetically induced transparency (EIT)-like spectral response with magnetic resonance near field coupling to electric resonance. Six split-ring resonators and a cut wire are chosen as the bright and dark resonator, respectively. An EIT-like transmission peak located between two dips can be observed with incident magnetic field excitation. A large delay bandwidth product (0.39) is obtained, which has potential application in quantum optics and communications. The experimental results are in good agreement with simulated results.

  3. Novel chemically stable Ba3Ca1.18Nb1.82-xYxO9- proton conductor: improved proton conductivity through tailored cation ordering

    SciTech Connect (OSTI)

    Wang, Siwei; Chen, Yan; Fang, Shumin; Zhang, Lingling; Tang, Ming; An, Ke; Brinkman, Dr. Kyle S.; Chen, Fanglin

    2014-01-01

    Simple perovskite-structured proton conductors encounter significant challenges to simultaneously achieving excellent chemical stability and proton conductivity that are desirable for many important applications in energy conversion and storage. This work demonstrates that Y-doped complex-perovskite-structured Ba3Ca1.18Nb1.82 xYxO9 materials possess both improved proton conductivity and exceptional chemical stability. Neutron powder diffraction refinement revealed a Fm3 m perovskite-structure and increased oxygen vacancy concentration due to the Y doping. High-resolution TEM analysis confirmed the perturbation of the B site cation ordering in the structure for the Ba3Ca1.18Nb1.82 xYxO9 materials. Such combined effects led to improved proton conductivity with a value of 5.3 10 3 S cm 1 at 600 C for Ba3Ca1.18Nb1.52Y0.3O9 (BCNY0.3), a value 2.4 times higher compared with that of the undoped Ba3Ca1.18Nb1.82O9 . The Ba3Ca1.18Nb1.82 xYxO9 materials showed remarkable chemical stability toward water and demonstrated no observable reactions to CO2 exposure. Ionic transport number studies showed that BCNY0.3 had predominantly proton conduction below 600 C. Solid oxide fuel cells using BCNY0.3 as an electrolyte demonstrated cell power output of 103 mW cm 2 at 750 C. These results suggest that a doping strategy that tailors the cation ordering in complex perovskites provides a new direction in the search for novel proton conducting ceramics.

  4. R2R Production of Low-Cost Integrated OLED Substrate with Improved

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transparent Conductor and Enhanced Light Outcoupling | Department of Energy R2R Production of Low-Cost Integrated OLED Substrate with Improved Transparent Conductor and Enhanced Light Outcoupling R2R Production of Low-Cost Integrated OLED Substrate with Improved Transparent Conductor and Enhanced Light Outcoupling Lead Performer: MicroContinuum, Inc. - Cambridge, MA DOE Total Funding: $1,149,037 Project Term: April 6, 2015 - April 5, 2017 Funding Opportunity: FY2015 Phase II Release 1 SBIR

  5. Application of Developed APCVD Transparent Conducting Oxides and Undercoat Technologies for Economical OLED Lighting

    SciTech Connect (OSTI)

    Gary Silverman; Bluhm, Martin; Coffey, James; Korotkov, Roman; Polsz, Craig; Salemi, Alexandre; Smith, Robert; Smith, Ryan; Stricker, Jeff; Xu,Chen; Shirazi, Jasmine; Papakonstantopulous, George; Carson, Steve Philips Lighting GmbH Goldman, Claudia; Hartmann, Sren; Jessen, Frank; Krogmann, Bianca; Rickers, Christoph; Ruske, Manfred, Schwab, Holger; Bertram, Dietrich

    2011-01-02

    Economics is a key factor for application of organic light emitting diodes (OLED) in general lighting relative to OLED flat panel displays that can handle high cost materials such as indium tin oxide (ITO) or Indium zinc oxide (IZO) as the transparent conducting oxide (TCO) on display glass. However, for OLED lighting to penetrate into general illumination, economics and sustainable materials are critical. The issues with ITO have been documented at the DOE SSL R&D and Manufacturing workshops for the last 5 years and the issue is being exaserbated by export controls from China (one of the major sources of elemental indium). Therefore, ITO is not sustainable because of the fluctuating costs and the United States (US) dependency on other nations such as China. Numerous alternatives to ITO/IZO are being evaluated such as Ag nanoparticles/nanowires, carbon nanotubes, graphene, and other metal oxides. Of these other metal oxides, doped zinc oxide has attracted a lot of attention over the last 10 years. The volume of zinc mined is a factor of 80,000 greater than indium and the US has significant volumes of zinc mined domestically, resulting in the ability for the US to be self-sufficient for this element that can be used in optoelectonic applications. The costs of elemental zinc is over 2 orders of magnitude less than indium, reflecting the relative abundance and availablility of the elements. Arkema Inc. and an international primary glass manufacturing company, which is located in the United States, have developed doped zinc oxide technology for solar control windows. The genesis of this DOE SSL project was to determine if doped zinc oxide technology can be taken from the commodity based window market and translate the technology to OLED lighting. Thus, Arkema Inc. sought out experts, Philips Lighting, Pacific Northwest National Laboratories (PNNL) and National Renewable Research Laboratories (NREL), in OLED devices and brought them into the project. This project had a

  6. Highly transparent conductive electrode with ultra-low HAZE by grain boundary modification of aqueous solution fabricated alumina-doped zinc oxide nanocrystals

    SciTech Connect (OSTI)

    Nian, Qiong; Cheng, Gary J.; Callahan, Michael; Bailey, John; Look, David; Efstathiadis, Harry

    2015-06-01

    Commercial production of transparent conducting oxide (TCO) polycrystalline films requires high electrical conductivity with minimal degradation in optical transparency. Aqueous solution deposited TCO films would reduce production costs of TCO films but suffer from low electrical mobility, which severely degrades both electrical conductivity and optical transparency in the visible spectrum. Here, we demonstrated that grain boundary modification by ultra-violet laser crystallization (UVLC) of solution deposited aluminium-doped zinc oxide (AZO) nanocrystals results in high Hall mobility, with a corresponding dramatic improvement in AZO electrical conductance. The AZO films after laser irradiation exhibit electrical mobility up to 18.1 cm{sup 2} V{sup −1} s{sup −1} with corresponding electrical resistivity and sheet resistances as low as 1 × 10{sup −3} Ω cm and 75 Ω/sq, respectively. The high mobility also enabled a high transmittance (T) of 88%-96% at 550 nm for the UVLC films. In addition, HAZE measurement shows AZO film scattering transmittance as low as 1.8%, which is superior over most other solution deposited transparent electrode alternatives such as silver nanowires. Thus, AZO films produced by the UVLC technique have a combined figure of merit for electrical conductivity, optical transparency, and optical HAZE higher than other solution based deposition techniques and comparable to vacuumed based deposition methods.

  7. Highly efficient blue organic light emitting device using indium-free transparent anode Ga:ZnO with scalability for large area coating

    SciTech Connect (OSTI)

    Wang, Liang; Matson, Dean W.; Polikarpov, Evgueni; Swensen, James S.; Bonham, Charles C.; Cosimbescu, Lelia; Berry, J. J.; Ginley, D. S.; Gaspar, Daniel J.; Padmaperuma, Asanga B.

    2010-02-15

    The availability of economically-produced and environmentally-stable transparent conductive oxide (TCO) coatings is critical for the development of a variety of electronic devices requiring transparent electrodes. Such devices include liquid crystal display pixels and organic light emitting diodes (OLEDs),[1, 2] solar cell applications,[3, 4] and electrically heated windows.[5, 6] The materials fulfilling these requirements are usually wide band gap inorganic transparent conductive oxides (TCOs). Tin-doped indium oxide, or ITO, has traditionally been used for electronic TCO applications because of its low resistivity, high work function and transparency. Due to the increasing cost and limited supply of indium and its tendency to migrate in to the device, there has been increasing research interest to substitute ITO with an indium-free material. A number of alternative metal oxides and doped oxides have been evaluated as TCO materials with varying degrees of success.[7, 8] Among these alternatives to ITO, gallium-doped zinc oxide (GZO) [2, 9] and aluminium-doped zinc oxide (AZO) [10, 11] have drawn particular attention. These materials have been demonstrated to have resistivities and transparencies approaching those of the best ITO, low toxicity, and much lower materials cost. Although AZO is attractive as a TCO electrode material, GZO features a greater resistance to oxidation as a result of gallium’s greater electronegativity compared to Submitted to 2 aluminum.[12, 13

  8. U.S. transparency monitoring of HEU oxide conversion and blending to LEU hexafluoride at three Russian blending plants

    SciTech Connect (OSTI)

    Leich, D., LLNL

    1998-07-27

    The down-blending of Russian highly enriched uranium (HEU) takes place at three Russian gaseous centrifuge enrichment plants. The fluorination of HEU oxide and down-blending of HEU hexafluoride began in 1994, and shipments of low enriched uranium (LEU) hexafluoride product to the United States Enrichment Corporation (USEC) began in 1995 US transparency monitoring under the HEU Purchase Agreement began in 1996 and includes a permanent monitoring presence US transparency monitoring at these facilities is intended to provide confidence that HEU is received and down-blended to LEU for shipment to USEC The monitoring begins with observation of the receipt of HEU oxide shipments, including confirmation of enrichment using US nondestructive assay equipment The feeding of HEU oxide to the fluorination process and the withdrawal of HEU hexafluoride are monitored Monitoring is also conducted where the blending takes place and where shipping cylinders are filled with LEU product. A series of process and material accountancy documents are provided to US monitors.

  9. Optical and electronic properties of delafossite CuBO{sub 2}p-type transparent conducting oxide

    SciTech Connect (OSTI)

    Ruttanapun, Chesta E-mail: krchesta@kmitl.ac.th

    2013-09-21

    CuBO{sub 2} delafossite was prepared by solid state reaction and calcined/sintered at 1005?C. The optical properties of this p-type transparent conducting oxide were investigated. Its crystal structure, morphology, composition, oxygen decomposition, and optical and electronic properties were characterized by X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy, thermal gravimetric analysis (TGA), ultraviolet-visible-near-infrared (UV-VIS-NIR) and fluorescence spectroscopies, Seebeck coefficient, and electrical conductivity measurements. CuBO{sub 2} delafossite possesses a hexagonal space group R3{sup }m. TGA indicated a weight loss of 10%, which was attributed to excess oxygen. The positive Seebeck coefficient confirmed p-type behavior. Emission at 355?nm indicated a direct band type transition, and the UV-VIS-NIR spectrum indicated an optical direct gap of 3.6?eV. Activation energies for carrier production and electrical conduction were 0.147 and 0.58?eV, respectively, indicating the thermal activation of carriers. CuBO{sub 2} delafossite is a p-type transparent conducting oxide with a wide band gap and may have potential in industrial p-type electrodes.

  10. Molecular Foundry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    visible to ultraviolet spectrum, chemical sensing and separation, transparent conductors, high-power electronics and many more. Some of the synthetic tools employed include the...

  11. Nathan Guisinger | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    carbon-based nanostructures ranging from metal-organic molecules to two-dimensional graphene: synthesis, characterization, and application; advanced transparent conductors...

  12. Application of Developed APCVD Transparent Conducting Oxides and Undercoat Technologies for Economical OLED Lighting

    SciTech Connect (OSTI)

    Martin Bluhm; James Coffey; Roman Korotkov; Craig Polsz; Alexandre Salemi; Robert Smith; Ryan Smith; Jeff Stricker; Chen Xu; Jasmine Shirazi; George Papakonstantopulous; Steve Carson; Claudia Goldman; Soren Hartmann; Frank Jessen; Bianca Krogmann; Christoph Rickers; Manfred Ruske; Holger Schwab; Dietrich Bertram

    2011-01-02

    Economics is a key factor for application of organic light emitting diodes (OLED) in general lighting relative to OLED flat panel displays that can handle high cost materials such as indium tin oxide (ITO) or Indium zinc oxide (IZO) as the transparent conducting oxide (TCO) on display glass. However, for OLED lighting to penetrate into general illumination, economics and sustainable materials are critical. The issues with ITO have been documented at the DOE SSL R&D and Manufacturing workshops for the last 5 years and the issue is being exacerbated by export controls from China (one of the major sources of elemental indium). Therefore, ITO is not sustainable because of the fluctuating costs and the United States (US) dependency on other nations such as China. Numerous alternatives to ITO/IZO are being evaluated such as Ag nanoparticles/nanowires, carbon nanotubes, graphene, and other metal oxides. Of these other metal oxides, doped zinc oxide has attracted a lot of attention over the last 10 years. The volume of zinc mined is a factor of 80,000 greater than indium and the US has significant volumes of zinc mined domestically, resulting in the ability for the US to be self-sufficient for this element that can be used in optoelectronic applications. The costs of elemental zinc is over 2 orders of magnitude less than indium, reflecting the relative abundance and availability of the elements. Arkema Inc. and an international primary glass manufacturing company, which is located in the United States, have developed doped zinc oxide technology for solar control windows. The genesis of this DOE SSL project was to determine if doped zinc oxide technology can be taken from the commodity based window market and translate the technology to OLED lighting. Thus, Arkema Inc. sought out experts, Philips Lighting, Pacific Northwest National Laboratories (PNNL) and National Renewable Research Laboratories (NREL), in OLED devices and brought them into the project. This project had a

  13. Buffer layers for coated conductors

    DOE Patents [OSTI]

    Stan, Liliana; Jia, Quanxi; Foltyn, Stephen R.

    2011-08-23

    A composite structure is provided including a base substrate, an IBAD oriented material upon the base substrate, and a cubic metal oxide material selected from the group consisting of rare earth zirconates and rare earth hafnates upon the IBAD oriented material. Additionally, an article is provided including a base substrate, an IBAD oriented material upon the base substrate, a cubic metal oxide material selected from the group consisting of rare earth zirconates and rare earth hafnates upon the IBAD oriented material, and a thick film upon the cubic metal oxide material. Finally, a superconducting article is provided including a base substrate, an IBAD oriented material upon the base substrate, a cubic metal oxide material selected from the group consisting of rare earth zirconates and rare earth hafnates upon the IBAD oriented material, and an yttrium barium copper oxide material upon the cubic metal oxide material.

  14. Methods of forming aluminum oxynitride-comprising bodies, including methods of forming a sheet of transparent armor

    DOE Patents [OSTI]

    Chu, Henry Shiu-Hung [Idaho Falls, ID; Lillo, Thomas Martin [Idaho Falls, ID

    2008-12-02

    The invention includes methods of forming an aluminum oxynitride-comprising body. For example, a mixture is formed which comprises A:B:C in a respective molar ratio in the range of 9:3.6-6.2:0.1-1.1, where "A" is Al.sub.2O.sub.3, "B" is AlN, and "C" is a total of one or more of B.sub.2O.sub.3, SiO.sub.2, Si--Al--O--N, and TiO.sub.2. The mixture is sintered at a temperature of at least 1,600.degree. C. at a pressure of no greater than 500 psia effective to form an aluminum oxynitride-comprising body which is at least internally transparent and has at least 99% maximum theoretical density.

  15. Directivity patterns and pulse profiles of ultrasound emitted by laser action on interface between transparent and opaque solids: Analytical theory

    SciTech Connect (OSTI)

    Nikitin, Sergey M. E-mail: vitali.goussev@univ-lemans.fr; Tournat, Vincent; Chigarev, Nikolay; Castagnede, Bernard; Gusev, Vitalyi E-mail: vitali.goussev@univ-lemans.fr; Bulou, Alain; Zerr, Andreas

    2014-01-28

    The analytical theory for the directivity patterns of ultrasounds emitted from laser-irradiated interface between two isotropic solids is developed. It is valid for arbitrary combinations of transparent and opaque materials. The directivity patterns are derived both in two-dimensional and in three-dimensional geometries, by accounting for the specific features of the sound generation by the photo-induced mechanical stresses distributed in the volume, essential in the laser ultrasonics. In particular, the theory accounts for the contribution to the emitted propagating acoustic fields from the converted by the interface evanescent photo-generated compression-dilatation waves. The precise analytical solutions for the profiles of longitudinal and shear acoustic pulses emitted in different directions are proposed. The developed theory can be applied for dimensional scaling, optimization, and interpretation of the high-pressure laser ultrasonics experiments in diamond anvil cell.

  16. Characterization of plasmonic hole arrays as transparent electrical contacts for organic photovoltaics using high-brightness Fourier transform methods

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Camino, Fernando E.; Nam, Chang-Yong; Pang, Yutong T.; Hoy, Jessica; Eisaman, Matthew D.; Black, Charles T.; Sfeir, Matthew Y.

    2014-05-15

    Here we present a methodology for probing light-matter interactions in prototype photovoltaic devices consisting of an organic semiconductor active layer with a semitransparent metal electrical contact exhibiting surface plasmon-based enhanced optical transmission. We achieve high-spectral irradiance in a spot size of less than 100 μm using a high-brightness laser-driven light source and appropriate coupling optics. Spatially resolved Fourier transform photocurrent spectroscopy in the visible and near-infrared spectral regions allows us to measure external quantum efficiency with high sensitivity in small-area devices (<1 mm2). Lastly, this allows for rapid fabrication of variable-pitch sub-wavelength hole arrays in metal films for use asmore » transparent electrical contacts, and evaluation of the evanescent and propagating mode coupling to resonances in the active layer.« less

  17. High quality ZnO:Al transparent conducting oxide films synthesized by pulsed filtered cathodic arc deposition

    SciTech Connect (OSTI)

    Anders, Andre; Lim, Sunnie H.N.; Yu, Kin Man; Andersson, Joakim; Rosen, Johanna; McFarland, Mike; Brown, Jeff

    2009-04-24

    Aluminum-doped zinc oxide, ZnO:Al or AZO, is a well-known n-type transparent conducting oxide with great potential in a number of applications currently dominated by indium tin oxide (ITO). In this study, the optical and electrical properties of AZO thin films deposited on glass and silicon by pulsed filtered cathodic arc deposition are systematically studied. In contrast to magnetron sputtering, this technique does not produce energetic negative ions, and therefore ion damage can be minimized. The quality of the AZO films strongly depends on the growth temperature while only marginal improvements are obtained with post-deposition annealing. The best films, grown at a temperature of about 200?C, have resistivities in the low to mid 10-4 Omega cm range with a transmittance better than 85percent in the visible part of the spectrum. It is remarkable that relatively good films of small thickness (60 nm) can be fabricated using this method.

  18. Transparent Cost Database | Transparent Cost Database

    Open Energy Info (EERE)

    Hydropower 7% Hydropower 7% Ocean 7% Biopower 7% Distributed Generation 7% Fuel Cell 7% Natural Gas Combined Cycle 7% Natural Gas Combustion Turbine 7% Coal, Pulverized Coal,...

  19. Transparent Cost Database | Transparent Cost Database

    Open Energy Info (EERE)

    15 Fuel Cell 15 PHEV 15 Ethanol-Flex Fuel 15 Natural Gas 15 Propane 15 Default 15 Fuel Prices: Diesel 3.540 Electricity 3.866 Ethanol-Flex Fuel 4.600 Gasoline 3.680...

  20. active metasurfaces: metamaterials meet optoelectronics

    Office of Scientific and Technical Information (OSTI)

    ... John Reno, Mike Sinclair, Ines Montano, John Klem, Eric Shaner, Mike Wanke, Joel Wendt, Paul Clem, Jon Ihlefeld, Bruce Burckel, Jason Domingues, Andy Allerman, Jon Wierer,......

  1. Highly transparent and conductive double-layer oxide thin films as anodes for organic light-emitting diodes

    SciTech Connect (OSTI)

    Yang Yu; Wang Lian; Yan He; Jin Shu; Marks, Tobin J.; Li Shuyou

    2006-07-31

    Double-layer transparent conducting oxide thin film structures containing In-doped CdO (CIO) and Sn-doped In{sub 2}O{sub 3} (ITO) layers were grown on glass by metal-organic chemical vapor deposition and ion-assisted deposition (IAD), respectively, and used as anodes for polymer light-emitting diodes (PLEDs). These films have a very low overall In content of 16 at. %. For 180-nm-thick CIO/ITO films, the sheet resistance is 5.6 {omega}/{open_square}, and the average optical transmittance is 87.1% in the 400-700 nm region. The overall figure of merit ({phi}=T{sup 10}/R{sub sheet}) of the double-layer CIO/ITO films is significantly greater than that of single-layer CIO, IAD-ITO, and commercial ITO films. CIO/ITO-based PLEDs exhibit comparable or superior device performance versus ITO-based control devices. CIO/ITO materials have a much lower sheet resistance than ITO, rendering them promising low In content electrode materials for large-area optoelectronic devices.

  2. The RACER (risk analysis, communication, evaluation, and reduction) stakeholder environmental data transparency project for Los Alamos National Laboratory

    SciTech Connect (OSTI)

    Echohawk, John Chris; Dorries, Alison M; Eberhart, Craig F; Werdel, Nancy

    2008-01-01

    The RACER (Risk Analysis, Communication, Evaluation, and Reduction) project was created in 2003, as an effort to enhance the Los Alamos National Laboratory's ability to effectively communicate the data and processes used to evaluate environmental risks to the public and the environment. The RACER project staff consists of members of Risk Assessment Corporation, Los Alamos National Laboratory (LANL), and the New Mexico Environment Department (NMED). RACER staff worked closely with members of the community, tribal governments, and others within NMED and LANL to create innovative tools and a process that could provide information to regulators, LANL and the community about the sources of public health risk and ecological impact from LAN L operations. The RACER Data Analysis Tool (DA T) provides the public with webbased access to environmental measurement data collected in and around the LANL site. Its purpose is to provide a 'transparent' view to the public of all data collected by LANL and NMED regarding the LANL site. The DAT is available to the public at 'www.racernm.com'.

  3. Effects of alpha-zirconium phosphate on thermal degradation and flame retardancy of transparent intumescent fire protective coating

    SciTech Connect (OSTI)

    Xing, Weiyi; Zhang, Ping; Song, Lei; Wang, Xin; Hu, Yuan

    2014-01-01

    Graphical abstract: - Highlights: A transparent intumescent fire protective coating was obtained by UV-cured technology. OZrP could enhance the thermal stability and anti-oxidation of the coating. OZrP could reduce the combustion properties of the coatings. - Abstract: Organophilic alpha-zirconium phosphate (OZrP) was used to improve the thermal and fire retardant behaviors of the phenyl di(acryloyloxyethyl)phosphate (PDHA)-triglycidyl isocyanurate acrylate (TGICA)-2-phenoxyethyl acrylate (PHEA) (PDHA-TGICA-PHEA) coating. The morphology of nanocomposite coating was characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). The effect of OZrP on the flame retardancy, thermal stability, fireproofing time and char formation of the coatings was investigated by microscale combustion calorimeter (MCC), thermogravimetric analysis (TGA), X-ray photoelectron spectroscopy (XPS), laser Raman spectroscopy (LRS) and scanning electric microscope (SEM). The results showed that by adding OZrP, the peak heat release rate and total heat of combustion were significantly reduced. The highest improvement was achieved with 0.5 wt% OZrP. XPS analysis indicated that the performance of anti-oxidation of the coating was improved with the addition of OZrP, and SEM images showed that a good synergistic effect was obtained through a ceramic-like layer produced by OZrP covered on the surface of char.

  4. Cooperative Monitoring Center Occasional Paper/12: ENTNEA: A Concept for Enhancing Nuclear Transparency for Confidence Building in Northeast Asia

    SciTech Connect (OSTI)

    Nam, Man-Kwon; Shin, Sung-Tack

    1999-06-01

    Nuclear energy continues to be a strong and growing component of economic development in Northeast Asia. A broad range of nuclear energy systems already exists across the region and vigorous growth is projected. Associated with these capabilities and plans are various concerns about operational safety, environmental protection, and accumulation of spent fuel and other nuclear materials. We consider cooperative measures that might address these concerns. The confidence building measures suggested here center on the sharing of information to lessen concerns about nuclear activities or to solve technical problems. These activities are encompassed by an Enhanced Nuclear Transparency in Northeast Asia (ENTNEA) concept that would be composed of near-term, information-sharing activities and an eventual regional institution. The near-term activities would address specific concerns and build a tradition of cooperation; examples include radiation measurements for public safety and emergency response, demonstration of safe operations at facilities and in transportation, and material security in the back end of the fuel cycle. Linkages to existing efforts and organizations would be sought to maximize the benefits of cooperation. In the longer term, the new cooperative tradition might evolve into an ENTNEA institution. In institutional form, ENTNEA could combine the near-term activities and new cooperative activities, which might require an institutional basis, for the mutual benefit and security of regional parties.

  5. Fabrication and microstructure of cerium doped lutetium aluminum garnet (Ce:LuAG) transparent ceramics by solid-state reaction method

    SciTech Connect (OSTI)

    Li, Junlang; Xu, Jian; Shi, Ying; Qi, Hongfang; Xie, Jianjun; Lei, Fang

    2014-07-01

    Highlights: We fabricate Ce doped lutetium aluminum garnet ceramics by solid-state method. The raw materials include Lu{sub 2}O{sub 3} nanopowders synthesized by co-precipitation method. The density of the transparent ceramics reach 99.7% of the theoretical value. The optical transmittance of the bulk ceramic at 550 nm was 57.48%. Some scattering centers decrease the optical characteristic of the ceramic. - Abstract: Polycrystalline Ce{sup 3+} doped lutetium aluminum garnet (Ce:LuAG) transparent ceramics fabricated by one step solid-state reaction method using synthetic nano-sized Lu{sub 2}O{sub 3}, commercial ?-Al{sub 2}O{sub 3} and CeO{sub 2} powders were investigated in this paper. The green compacts shaped by the mixed powders were successfully densified into Ce:LuAG transparent ceramics after vacuum sintering at 1750 C for 10 h. The in-line optical transmittance of the Ce:LuAG ceramic made by home-made Lu{sub 2}O{sub 3} powders could reach 57.48% at 550 nm, which was higher than that of the ceramic made by commercial Lu{sub 2}O{sub 3} powders (22.96%). The microstructure observation showed that light scattering centers caused by micro-pores, aluminum segregation and refraction index inhomogeneities induced the decrease of optical transparency of the Ce:LuAG ceramics, which should be removed and optimized in the future work.

  6. Why MnIn{sub 2}O{sub 4} spinel is not a transparent conducting oxide?

    SciTech Connect (OSTI)

    Martinez-Lope, M.J.; Retuerto, M.; Calle, C. de la; Porcher, Florence

    2012-03-15

    The title compound has been synthesized by a citrate technique. The crystal structure has been investigated at room temperature from high-resolution neutron powder diffraction (NPD) data. It crystallizes in a cubic spinel structure, space group Fd3-bar m, Z=8, with a=9.0008(1) A at 295 K. It exhibits a crystallographic formula (Mn{sub 0.924(2)}In{sub 0.076(2)}){sub 8a}(In{sub 1.804(2)}Mn{sub 0.196(2)}){sub 16d}O{sub 4}, where 8a and 16d stand for the tetrahedral and octahedral sites of the spinel structure, respectively, with a slight degree of inversion, {lambda}=0.08. MnIn{sub 2}O{sub 4} shows antiferromagnetic interactions below T{sub N} Almost-Equal-To 40 K, due to the statistical distribution of Mn ions over the two available sites. Unlike the related MgIn{sub 2}O{sub 4} and CdIn{sub 2}O{sub 4} spinels, well known as transparent conducting oxides, MnIn{sub 2}O{sub 4} is not transparent and shows a poor conductivity ({sigma}=0.38 S cm{sup -1} at 1123 K): the presence of Mn ions, able to adopt mixed valence states, localizes the charges that, otherwise, would be delocalized in the spinel conduction band. - Graphical Abstract: From NPD data the crystallographic formula (Mn{sub 0.924(2)}In{sub 0.076(2)}){sub 8a}(In{sub 1.804(2)}Mn{sub 0.196(2)}){sub 16d}O{sub 4}, shows a slight degree of inversion, {lambda}=0.08 and a certain In deficiency. The presence of Mn ions, able to adopt mixed oxidation states, localize the charges that, otherwise, would be delocalized in the spinel conduction band; the presence of localized Mn{sup 2+} and Mn{sup 3+} ions provides the characteristic brown color. Highlights: Black-Right-Pointing-Pointer Accurate structural determination from NPD data: inversion degree (8%), and In deficiency. Black-Right-Pointing-Pointer Bond-valence indicates Mn{sup 2+}-Mn{sup 3+} ions; edge-sharing octahedra contain 90% In{sup 3+}+10% Mn{sup 3+} cations. Black-Right-Pointing-Pointer Conductivity several orders of magnitude lower than those of MgIn{sub 2}O

  7. A high-transparency, micro-patternable chip for X-ray diffraction analysis of microcrystals under native growth conditions

    SciTech Connect (OSTI)

    Murray, Thomas D.; Lyubimov, Artem Y.; Ogata, Craig M.; Vo, Huy; Uervirojnangkoorn, Monarin; Brunger, Axel T.; Berger, James M.

    2015-08-11

    Microcrystals present a significant impediment to the determination of macromolecular structures by X-ray diffraction methods. Although microfocus synchrotron beamlines and X-ray free-electron lasers (XFELs) can enable the collection of interpretable diffraction data from microcrystals, there is a need for efficient methods of harvesting small volumes (<2 l) of microcrystals grown under common laboratory formats and delivering them to an X-ray beam source under native growth conditions. One approach that shows promise in overcoming the challenges intrinsic to microcrystal analysis is to pair so-called `fixed-target' sample-delivery devices with microbeam-based X-ray diffraction methods. However, to record weak diffraction patterns it is necessary to fabricate devices from X-ray-transparent materials that minimize background scattering. Presented here is the design of a new micro-diffraction device consisting of three layers fabricated from silicon nitride, photoresist and polyimide film. The chip features low X-ray scattering and X-ray absorption properties, and uses a customizable blend of hydrophobic and hydrophilic surface patterns to help localize microcrystals to defined regions. Microcrystals in their native growth conditions can be loaded into the chips with a standard pipette, allowing data collection at room temperature. Diffraction data collected from hen egg-white lysozyme microcrystals (1015 m) loaded into the chips yielded a complete, high-resolution (<1.6 ) data set sufficient to determine a high-quality structure by molecular replacement. In addition, the features of the chip allow the rapid and user-friendly analysis of microcrystals grown under virtually any laboratory format at microfocus synchrotron beamlines and XFELs.

  8. A high-transparency, micro-patternable chip for X-ray diffraction analysis of microcrystals under native growth conditions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Murray, Thomas D.; Lyubimov, Artem Y.; Ogata, Craig M.; Vo, Huy; Uervirojnangkoorn, Monarin; Brunger, Axel T.; Berger, James M.

    2015-08-11

    Microcrystals present a significant impediment to the determination of macromolecular structures by X-ray diffraction methods. Although microfocus synchrotron beamlines and X-ray free-electron lasers (XFELs) can enable the collection of interpretable diffraction data from microcrystals, there is a need for efficient methods of harvesting small volumes (<2 µl) of microcrystals grown under common laboratory formats and delivering them to an X-ray beam source under native growth conditions. One approach that shows promise in overcoming the challenges intrinsic to microcrystal analysis is to pair so-called `fixed-target' sample-delivery devices with microbeam-based X-ray diffraction methods. However, to record weak diffraction patterns it is necessarymore » to fabricate devices from X-ray-transparent materials that minimize background scattering. Presented here is the design of a new micro-diffraction device consisting of three layers fabricated from silicon nitride, photoresist and polyimide film. The chip features low X-ray scattering and X-ray absorption properties, and uses a customizable blend of hydrophobic and hydrophilic surface patterns to help localize microcrystals to defined regions. Microcrystals in their native growth conditions can be loaded into the chips with a standard pipette, allowing data collection at room temperature. Diffraction data collected from hen egg-white lysozyme microcrystals (10–15 µm) loaded into the chips yielded a complete, high-resolution (<1.6 Å) data set sufficient to determine a high-quality structure by molecular replacement. In addition, the features of the chip allow the rapid and user-friendly analysis of microcrystals grown under virtually any laboratory format at microfocus synchrotron beamlines and XFELs.« less

  9. Fissile Mass Flow Monitor Implementation for Transparency in HEU Blenddown at the URAL Electrochemical Integrated Plant (UEIP) in Novouralsk

    SciTech Connect (OSTI)

    March-Leuba, J.; Mastal, E.; Powell, D.; Sumner, J.; Uckan, T.; Vines, B.

    1999-07-25

    The Oak Ridge National Laboratory (ORNL) Fissile Mass Flow Monitor (FMFM) was deployed at the Ural Electrochemical Integrated Plant (UEIP) highly enriched uranium (HEU) blending facility in January and February 1999 at Novouralsk in Russia for the DOE HEU Transparency Program. The FMFM provides unattended monitoring of the fissile mass flow of the uranium hexafluoride (UF{sub 6}) gas in the process lines of HEU, the low enriched uranium (LEU) blend stock, and the product LEU (P-LEU) of the blending tee non-intrusively. To do this, uranium-235 (U-235) fissions are induced in the UF{sub 6} by a thermalized and modulated californium-252 (Cf-252) neutron source placed on each process line. A set of detectors, located downstream of source, measure delayed gamma rays emitted by the resulting fission fragments. The observed delay in the time correlated measurement between the source and the detector signal provides the velocity of UF{sub 6} and its amplitude is related to the U- 235 content in UF{sub 6}. An on-line computer controls the source modulator, processes the collected detector data, and displays the results. The UEIP Main and the Reserved process lines were implemented with minor modifications. The FMFM monitors the HEU blending operation by measuring UF{sub 6} flows in the process blending lines, and the traceability of the HEU flow from the blend point to the P-LEU. The detail operational characteristics of the FMFM software (FM2) and the measurement methodology used are presented.

  10. Comparison of the effect of outdoor exposure on the optical properties of solar mirrors and transparent encapsulant materials

    SciTech Connect (OSTI)

    Dake, L.S.; Lind, M.A.; Maag, C.R.

    1981-09-01

    The effects of outdoor exposure on solar mirrors and transparent encapsulant materials are assessed and compared. The encapsulant materials tested included glasses, polymers and silicones. Samples of the materials were placed on stationary exposure racks in six locations that represented urban, desert, oceanside and high altitude mountain areas. Samples were removed periodically for optical characterizations. The spectral hemispherical and diffuse reflectance of the mirror samples and the spectral hemispherical transmittance and diffuse reflectance of the encapsulant materials was measured. The relative normal hemispherical transmittance of the encapsulant materials was measured. Correlations between the glass and mirror data showed that the average diffuse reflectance losses were six times larger for the mirrors than for the glass samples. The average specular reflectance losses for the mirror samples were seven times as large as the average hemispherical transmittance losses for the glass samples. These correlations may enable one to predict the performance of mirrors made using the other encapsulant materials for superstrates. It was found that the urban and oceanside sites were the dirtiest, while the desert and mountain sites were the cleanest. Average specular reflectance losses varied from 4% at the cleanest site to 50% at the dirtiest site. The range in hemispherical transmittance losses for the encapsulant materials varied between 0% and 6%. At one site, the average daily specular reflectance losses were .04% for the mirror samples and average daily hemispherical transmittance losses were about .01% for the glass samples. The polymer materials degraded somewhat more rapidly than the glasses, and the silicones irreversible degraded too rapidly and severely to be useful for either photovoltaic or solar thermal applications.

  11. Transparent conducting impurity-doped ZnO thin films prepared using oxide targets sintered by millimeter-wave heating

    SciTech Connect (OSTI)

    Minami, Tadatsugu; Okada, Kenji; Miyata, Toshihiro; Nomoto, Juni-chi; Hara, Youhei; Abe, Hiroshi

    2009-07-15

    The preparation of transparent conducting impurity-doped ZnO thin films by both pulsed laser deposition (PLD) and magnetron sputtering deposition (MSD) using impurity-doped ZnO targets sintered with a newly developed energy saving millimeter-wave (28 GHz) heating technique is described. Al-doped ZnO (AZO) and V-co-doped AZO (AZO:V) targets were prepared by sintering with various impurity contents for 30 min at a temperature of approximately 1250 degree sign C in an air or Ar gas atmosphere using the millimeter-wave heating technique. The resulting resistivity and its thickness dependence obtainable in thin films prepared by PLD using millimeter-wave-sintered AZO targets were comparable to those obtained in thin films prepared by PLD using conventional furnace-sintered AZO targets; a low resistivity on the order of 3x10{sup -4} {Omega} cm was obtained in AZO thin films prepared with an Al content [Al/(Al+Zn) atomic ratio] of 3.2 at. % and a thickness of 100 nm. In addition, the resulting resistivity and its spatial distribution on the substrate surface obtainable in thin films prepared by rf-MSD using a millimeter-wave-sintered AZO target were almost the same as those obtained in thin films prepared by rf-MSD using a conventional powder AZO target. Thin films prepared by PLD using millimeter-wave-sintered AZO:V targets exhibited an improved resistivity stability in a high humidity environment. Thin films deposited with a thickness of approximately 100 nm using an AZO:V target codoped with an Al content of 4 at. % and a V content [V/(V+Zn) atomic ratio] of 0.2 at. % were sufficiently stable when long-term tested in air at 90% relative humidity and 60 degree sign C.

  12. A sol-gel route for the development of rare-earth aluminum borate nanopowders and transparent thin films

    SciTech Connect (OSTI)

    Maia, Lauro J.Q. Mastelaro, Valmor R.; Hernandes, Antonio C.

    2007-02-15

    A new sol-gel route was applied to obtain Y{sub 0.9}Er{sub 0.1}Al{sub 3}(BO{sub 3}){sub 4} crystalline powders and amorphous thin films by using Al(acac){sub 3}, B(OPr {sup i}){sub 3}, Y(NO{sub 3}){sub 3}.6H{sub 2}O, and Er(NO{sub 3}){sub 3}.5H{sub 2}O as starting materials dissolved in propionic acid and ethyl alcohol mixtures. Our study shows that propionic acid acts as good chelant agent for yttrium and erbium ions while ethyl alcohol allows to dissolve Al(acac){sub 3}. This process makes the resulting sols very stable to obtain homogeneous gels and transparent amorphous thin films. In addition, the propionic acid prevents the sol precipitation, making easy porous- and crack-free thin film depositions. Chemical reactions involved in the complexation were discussed. As-prepared powders and films are amorphous and present a good thermal stability due to their high glass transition (746 deg. C) and crystallization temperatures (830 deg. C). This new sol-gel route showed to be adequate to obtain dense and crack-free thin films free of organic and hydroxyl groups that can be considered as promising materials to be used in integrated optical systems. - Graphical abstract: SEM micrograph of Y{sub 0.9}Er{sub 0.1}Al{sub 3}(BO{sub 3}){sub 4} powders calcined at 400 and 700 deg. C during 24 h and heat-treated at 1150 deg. C.

  13. Transparent Conductive Nanostructures

    SciTech Connect (OSTI)

    2008-06-22

    The objectives of this program between UT-Battelle, LLC (the ''Contractor'') and (Battelle Memorial Institute) (the "Participant") were directed towards achieving significant improvement: in the electrical conductivity and optical/infrared transmission of single-wall carbon nanotube (SWNT)-based composite materials. These materials will be used in coating applications that range from aircraft canopies to display applications. The goal of the project was to obtain supported mats of SWNTs with sheet conductivities approaching 10 ohms/square combined with high optical transmission (>85% transmission at 550 nm), thereby permitting their application as a replacement for indium tin oxide (ITO) in a variety of applications such as flexible displays.

  14. WIPP Nuclear Facilities Transparency

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the safety, security, and legitimate management of nuclear materials." Other Links Yucca Mountain Test Data Carlsbad Environmental Monitoring and Research Center Dimitrovograd Site ...

  15. Methods | Transparent Cost Database

    Open Energy Info (EERE)

    Efficiency and Renewable Energy (EERE) covers a wide variety of applications, so methodology necessarily varies by sector and technology specifics. EERE seeks to use a...

  16. Preparation of blue-emitting CaMgSi{sub 2}O{sub 6}:Eu{sup 2+} phosphors in reverse micellar system and their application to transparent emissive display devices

    SciTech Connect (OSTI)

    Choi, Sungho; Tae, Se-Won; Seo, Jung-Hyun; Jung, Ha-Kyun

    2011-06-15

    Blue-emitting Eu{sup 2+}-doped CaMgSi{sub 2}O{sub 6} phosphors were prepared by the reverse micelle method. The resultant particles were nanocrystalline with a grain size of about <300 nm and exhibited a characteristic blue emission spectrum centered at 445 nm induced by the oxygen coordinated Eu{sup 2+} ions. By using the corresponding nanophosphors followed by the formation of a uniform phosphor layer, we have demonstrated the mini-sized transparent plasma-discharge panels and investigated their luminance characteristics. Phosphor coated panel is properly transparent, {>=}65%, at the visible wavelength region and illuminates a characteristic blue emission under Ne/Xe plasma discharge conditions. Thus, we can obtain a fast decaying, robust blue-emitting silicate phosphor layer under excited plasma radiation for upcoming emissive display devices like as transparent and three-dimensional plasma display panels. - Graphical abstract: Blue-emitting CaMgSi{sub 2}O{sub 6}:Eu{sup 2+} nanophosphors coated transparent luminescent layers can be obtained. It illuminates the characteristic blue emission, spectrum centered at 425 nm wavelength, under the Ne-Xe mixed gas plasma discharge condition. Highlights: > Blue-emitting CaMgSi{sub 2}O{sub 6}:Eu{sup 2+} nanophosphors via reverse micelle method. > Transparent blue-emitting layer was prepared by using corresponding phosphors. > Fast decaying with degradation-free luminescent layer under plasma radiation. > Promising luminescent layer for the upcoming plasma discharged transparent displays.

  17. How the NDA Provides Transparency and Visibility of the Technical Deliverability of the R and D Programme - 13303

    SciTech Connect (OSTI)

    Seed, Ian; James, Paula; Brownridge, Melanie; McMinn, Mervin

    2013-07-01

    The Nuclear Decommissioning Authority (NDA) was created under the UK Energy Act 2004 to ensure the UK historic civil public sector nuclear legacy sites are decommissioned safely, securely, cost effectively and in ways that protect the environment. The delivery will involve carrying out many unique projects within a high hazard environment requiring the very highest standards in safety, security and environmental management. Unique problems require unique solutions and there is a substantial amount of research and development required for each project. The NDA's R and D strategic objective is to ensure that delivery of the NDA's mission is technically underpinned by sufficient and appropriate research and development. This drives a requirement to provide transparency and visibility of the technical deliverability of the programme through the technical baseline and accompanying research and development requirements. The NDA need to have confidence in the technical deliverability of the Site License Companies (SLCs) plans, provide overall visibility of R and D across the NDA Estate and ensure that appropriate R and D is being carried out in a timely manner. They need to identify where coordinated R and D programmes may be advantageous as a result of common needs, risks and opportunities and ensure key R and D needs across NDA are identified, prioritised and work programmes are costed and scheduled in the Lifetime Plans for individual sites and SLCs. Evidence of the Site License Company's approach and their corresponding technical underpinning programmes is achieved through submission of a number of outputs collectively known as TBuRDs (Technical Baseline and Underpinning Research and Development Requirements). This paper is a summary of the information generated by an independent review of those TBuRDs. It highlights some of the key messages, synergies and common R and D activities across the estate. It demonstrates the value of a consistent approach to collecting R

  18. An analysis of the pull strength behaviors of fine-pitch, flip chip solder interconnections using a Au-Pt-Pd thick film conductor on Low-Temperature, Co-fired Ceramic (LTCC) substrates.

    SciTech Connect (OSTI)

    Uribe, Fernando R.; Kilgo, Alice C.; Grazier, John Mark; Vianco, Paul Thomas; Zender, Gary L.; Hlava, Paul Frank; Rejent, Jerome Andrew

    2008-09-01

    The assembly of the BDYE detector requires the attachment of sixteen silicon (Si) processor dice (eight on the top side; eight on the bottom side) onto a low-temperature, co-fired ceramic (LTCC) substrate using 63Sn-37Pb (wt.%, Sn-Pb) in a double-reflow soldering process (nitrogen). There are 132 solder joints per die. The bond pads were gold-platinum-palladium (71Au-26Pt-3Pd, wt.%) thick film layers fired onto the LTCC in a post-process sequence. The pull strength and failure modes provided the quality metrics for the Sn-Pb solder joints. Pull strengths were measured in both the as-fabricated condition and after exposure to thermal cycling (-55/125 C; 15 min hold times; 20 cycles). Extremely low pull strengths--referred to as the low pull strength phenomenon--were observed intermittently throughout the product build, resulting in added program costs, schedule delays, and a long-term reliability concern for the detector. There was no statistically significant correlation between the low pull strength phenomenon and (1) the LTCC 'sub-floor' lot; (2) grit blasting the LTCC surfaces prior to the post-process steps; (3) the post-process parameters; (4) the conductor pad height (thickness); (5) the dice soldering assembly sequence; or (5) the dice pull test sequence. Formation of an intermetallic compound (IMC)/LTCC interface caused by thick film consumption during either the soldering process or by solid-state IMC formation was not directly responsible for the low-strength phenomenon. Metallographic cross sections of solder joints from dice that exhibited the low pull strength behavior, revealed the presence of a reaction layer resulting from an interaction between Sn from the molten Sn-Pb and the glassy phase at the TKN/LTCC interface. The thick film porosity did not contribute, explicitly, to the occurrence of reaction layer. Rather, the process of printing the very thin conductor pads was too sensitive to minor thixotropic changes to ink, which resulted in

  19. Atomistic simulation study of short pulse laser interactions with a metal target under conditions of spatial confinement by a transparent overlayer

    SciTech Connect (OSTI)

    Karim, Eaman T.; Shugaev, Maxim; Wu, Chengping; Zhigilei, Leonid V.; Lin, Zhibin; Hainsey, Robert F.

    2014-05-14

    The distinct characteristics of short pulse laser interactions with a metal target under conditions of spatial confinement by a solid transparent overlayer are investigated in a series of atomistic simulations. The simulations are performed with a computational model combining classical molecular dynamics (MD) technique with a continuum description of the laser excitation, electron-phonon equilibration, and electronic heat transfer based on two-temperature model (TTM). Two methods for incorporation of the description of a transparent overlayer into the TTM-MD model are designed and parameterized for Ag-silica system. The material response to the laser energy deposition is studied for a range of laser fluences that, in the absence of the transparent overlayer, covers the regimes of melting and resolidification, photomechanical spallation, and phase explosion of the overheated surface region. In contrast to the irradiation in vacuum, the spatial confinement by the overlayer facilitates generation of sustained high-temperature and high-pressure conditions near the metal-overlayer interface, suppresses the generation of unloading tensile wave, decreases the maximum depth of melting, and prevents the spallation and explosive disintegration of the surface region of the metal target. At high laser fluences, when the laser excitation brings the surface region of the metal target to supercritical conditions, the confinement prevents the expansion and phase decomposition characteristic for the vacuum conditions leading to a gradual cooling of the hot compressed supercritical fluid down to the liquid phase and eventual solidification. The target modification in this case is limited to the generation of crystal defects and the detachment of the metal target from the overlayer.

  20. ,"Geographic Area",,,"Voltage",,,"Capacity Rating (MVa)","In-Service Date","Electrical Connection Locations",,"Line Information",,,,"Conductor Characteristics",,,"Circuits",,"Company Information"

    U.S. Energy Information Administration (EIA) Indexed Site

    ,"Table 6. Existing and Proposed High-voltage Transmission Line Additions Filed For Calendar Year 2004, by North American Electric Reliability Council, 2004 Through 2009" ,"(Various)",,,,,,,,,,,," " ,"Geographic Area",,,"Voltage",,,"Capacity Rating (MVa)","In-Service Date","Electrical Connection Locations",,"Line Information",,,,"Conductor Characteristics",,,"Circuits",,"Company